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HomeMy WebLinkAbout4407_HaywoodCoMSWLF_GWMR_DIN26865_20160120 BLE BUNNELL-LAMMONS ENGINEERING, INC. GEOTECHNICAL, ENVIRONMENTAL AND CONSTRUCTION MATERIALS CONSULTANTS REPORT OF GROUNDWATER QUALITY RESULTS & STATISTICAL ANALYSIS SECOND SEMI-ANNUAL SAMPLING EVENT OF 2015 WHITE OAK LANDFILL PERMIT NUMBER: 44-07 HAYWOOD COUNTY, NORTH CAROLINA Prepared For: HAYWOOD COUNTY SOLID WASTE MANAGEMENT 278 Recycle Road Clyde, North Carolina 28721 Prepared By: BUNNELL-LAMMONS ENGINEERING, INC. 6004 Ponders Court Greenville, South Carolina 29615 January 20, 2016 BLE Project Number J15-1957-50 BUNNELL-LAMMONS ENGINEERING, INC. GEOTECHNICAL, ENVIRONMENTAL AND CONSTRUCTION MATERIALS CONSULTANTS 6004 PONDERS COURT PHONE (864) 288-1265 GREENVILLE, SOUTH CAROLINA 29615 FAX (864) 288-4430 January 20, 2016 Haywood County Solid Waste Management 278 Recycle Road Clyde, North Carolina 28721 Attention: Mr. David B. Francis Solid Waste and Tax Administrator Subject: Report of Groundwater Quality Results & Statistical Analysis Second Semi-Annual Sampling Event of 2015 White Oak Landfill Permit Number: 44-07 Haywood County, North Carolina BLE Project Number J15-1957-50 Dear Mr. Francis: As authorized, Bunnell-Lammons Engineering, Inc. (BLE) has performed the statistical analysis of groundwater quality data obtained during the second semi-annual sampling event of 2015 for the White Oak Municipal Solid Waste (MSW) and Construction and Demolition (C&D) Landfills. The enclosed report describes the work performed and presents the results obtained with our conclusions. The purpose of this work was to statistically compare the laboratory analytical results of groundwater samples from the background monitoring wells to the downgradient monitoring wells at the subject landfill in accordance with Title 15A NCAC 13B .1632 (g), (h), and (i). This report of the sampling and statistical analysis has been prepared for submittal to the North Carolina Division of Waste Management (NCDWM) in accordance with Rule 15A NCAC 13B .1632 (j). We appreciate the opportunity to serve as your geological consultant on this project and look forward to working with you on future projects. If you have any questions, please contact us at (864) 288-1265. Sincerely, BUNNELL-LAMMONS ENGINEERING, INC. Trevor J. Benton, L.G. Mark S. Preddy, L.G. Project Geologist Senior Geologist Licensed, North Carolina No. 2025 Licensed, North Carolina No. 1043 cc: Mr. Ervin Lane – NC DEQ Solid Waste Section, 401 Oberlin Road, Suite 150, Raleigh, North Carolina 27605 White Oak Landfill – Haywood Co., NC January 20, 2016 Second Semi-Annual Sampling Event of 2015 BLE Project Number J15-1957-50 2 PROJECT INFORMATION The White Oak Landfill site is located in Haywood County, North Carolina, approximately twelve miles north of the city of Waynesville on White Oak Road at Exit 15 off Interstate 40 (Figure 1). The Subtitle D lined MSW landfill has eleven groundwater monitoring wells consisting of two upgradient (MW-11S and MW-11D) and nine downgradient wells (MW-1A, MW-2, MW-2D, MW- 3r, MW-3Dr, MW-4A, MW-8, MW-16, and MW-17). Monitoring wells MW-5A, MW-5D, MW- 12, MW-13S, and MW-13D were abandoned in 2009 and monitoring wells MW-16 and MW-17 were installed in 2010 as related to the construction of Phase No. 3 at the facility. Additionally, there are four surface water sampling points (SW-1, SW-2, SW-3, and SW-5), and a leachate lagoon sampling point (LSP). The C&D landfill, which is located on the same property, is monitored by one upgradient (MW-14), one downgradient well (MW-15), and two locations for surface water monitoring (SW-6 and SW-7). BLE was retained by Santek Waste Services, Inc. to prepare the semi-annual sampling reports for 2015. Historical data from multiple sources and in multiple formats were gathered and synthesized into this report. Water quality data available to BLE extends back to April 1993; however, many of the currently existing wells were not present during the earlier sampling events. As a result, the statistical database in this report uses data from sampling events ranging from April 2000 to the current sampling event (October 2015). This report presents data from the second semi-annual sampling event in 2015 for the site. The water samples were collected and analyzed as required in North Carolina's regulations for operation of MSW and C&D landfills. FIELD ACTIVITIES, SAMPLING, AND ANALYSIS Groundwater and surface water samples were collected by personnel from Pace Analytical Services, Inc. (Pace) of Asheville, North Carolina on October 26 - 27, 2015. Sampling was performed in general accordance with the Operations Plan for the White Oak Landfill. Summary tables of historic and current analytical results are attached in Appendix A (groundwater) and Appendix B (surface water). Water samples were collected from the monitoring wells, surface water points, and the LSP. The collected samples were analyzed in the laboratory for North Carolina’s Appendix I list of constituents that include total metals and volatile organic compounds (VOCs) and in the field for pH, specific conductance, turbidity, and temperature. A copy of the Pace laboratory and field data is included in Appendix C. GROUNDWATER FLOW The water level data collected during the groundwater sampling is presented in Table 1. A water table surface elevation contour map is presented as Figure 2 along with generalized groundwater White Oak Landfill – Haywood Co., NC January 20, 2016 Second Semi-Annual Sampling Event of 2015 BLE Project Number J15-1957-50 3 flow directions. Flow velocity calculations are provided on Table 2. Please note, hydraulic conductivity and effective porosity values for the existing wells were obtained from prior reports prepared by other consultants. SUMMARY OF LABORATORY RESULTS Groundwater Concentrations of total barium (thirteen wells), total cadmium (two wells), total chromium (two wells), total cobalt (three wells), total copper (four wells), total lead (one well) total nickel (seven wells), total vanadium (three wells), and total zinc (five wells) were detected in the groundwater monitoring wells during the current sampling event. Total barium (MW-2 and MW-2D), total cadmium (MW-16), and total chromium (MW-11S) were detected at concentrations above the North Carolina maximum contaminant level1 (MCL). Additionally, no VOCs were detected during the sampling event. Surface Water Concentrations of total metals were detected in five of the six surface water samples and the LSP sample during the current sampling event. The detections included total antimony (LSP), total barium (five surface waters and the LSP), total chromium (LSP), total cobalt (one surface water and the LSP), total nickel (LSP), total vanadium (LSP) and total zinc (LSP). No VOCs were detected in the samples from the surface water locations. However, eight VOCs (acetone, benzene, carbon disulfide, ethylbenzene, 2-butanone, 4-methyl-2-pentanone, toluene, and total xylenes {M+P and O Xylenes}) were detected in the LSP sample. Additionally, phosphorus, nitrate, nitrite, sulfate, BOD, and COD were detected in the LSP sample. Only the laboratory detection of toluene in the LSP exceeded an established North Carolina established surface water MCL2. STATISTICAL METHODS PERFORMED The purpose of performing statistical analysis of groundwater quality data is to determine if a release of leachate has occurred from the landfill cells to the groundwater at the site. The US EPA has prepared a guidance document for evaluating groundwater quality data titled Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities – Unified Guidance (March 2009). The procedures and methodology used for data analysis of this project are consistent with this US EPA guidance document, and meet or exceed the performance criteria specified in the North Carolina solid waste management rules Title 15A NCAC 13B .1632(g-i). Four methods of statistical analysis were performed depending on the number of detected concentrations and the distribution of the data for a specific compound, as follows: 1 North Carolina Department of Environment and Natural Resources (NCDENR), Classifications of Water Quality Standards, Section 15A NCAC 2L.202, December 1, 2005. 2 North Carolina Department of Environment and Natural Resources, “Redbook”, Surface Waters and Wetlands Standards, Section 15A NCAC 02B.0100, .0200, and .0300, May 1, 2007. White Oak Landfill – Haywood Co., NC January 20, 2016 Second Semi-Annual Sampling Event of 2015 BLE Project Number J15-1957-50 4 1. If 15% to 90% of the data were not detected, the one-way non-parametric analysis of variance (ANOVA) Kruskal-Wallis rank-sum test was performed; 2. If less than 15% of the data were not detected, and if the data was normally distributed and homogeneous, then one-way parametric ANOVA was performed. If the data were not normally distributed and homogeneous, then a non-parametric type test was used (Kruskal- Wallis); 3. Alternatively, if greater than 50% of the data were not detected, Poisson Prediction Limits may be performed, or if less than 50% of the data were not detected, Normal Prediction Limits may be performed. Wilcoxon rank-sum tests were performed for those compounds that failed the initial Poisson Prediction Limits test; and 4. Intrawell comparisons were performed, if necessary, using Shewhart-CUSUM control charts or the Kendall-Mann Non-Parametric Trend Test. It is important to note that the nature of the statistical procedures applied to the data frequently leads to false positives, which result in statistically significant increases (SSI). These false positives are inherent to the statistical procedures themselves and are a result of the insufficiency of the mathematical equations to represent the multiple factors affecting the groundwater quality variability at a given site. Furthermore, a clear distinction should be made between the terms “calculated SSI” and “validated SSI.” A calculated SSI is the result of the application of mathematical equations to evaluate variability of water quality data over time by mathematical means. A validated SSI is determined when, based on a review of the data set as a whole, it can be concluded that the calculated statistical significance might be a function of a release of leachate to groundwater, and not a function of natural variability and/or other conditions. SUMMARY OF STATISTICAL RESULTS The statistical analysis was performed on constituents that have been historically detected and that were detected during the current sampling event. The statistical results summarized on Table 3 and included in Appendix D indicate that: 1. The Poisson Prediction Limit and Wilcoxon tests performed for total antimony, total arsenic, total selenium, total silver, total thallium, acetone, carbon disulfide, chloroethane, iodomethane, dichloromethane, and 2-butanone did not calculate SSIs; and 2. The Kruskal-Wallis tests and Shewhart-CUSUM control charts did not calculate SSIs for total beryllium, total cadmium, total chromium, total cobalt, total copper, total lead, total vanadium, and total zinc; however, the tests calculated SSIs for total barium (MW-2 and MW-2D) and total nickel (MW-3Dr). White Oak Landfill – Haywood Co., NC January 20, 2016 Second Semi-Annual Sampling Event of 2015 BLE Project Number J15-1957-50 5 CONCLUSION Concentrations of various total metals were detected in the groundwater monitoring wells and surface water sampling points during the current sampling event. Only the concentrations of total barium (MW-2 and MW-2D), total cadmium (MW-16), and total chromium (MW-11S), were detected at concentrations exceeding North Carolina MCLs. The remaining detected concentrations were either below North Carolina’s promulgated MCLs, or MCLs have not been established for a particular constituent. Additionally, only total barium in wells MW-2 and MW-2D and total nickel in well MW-3Dr were calculated to be statistically significant; these metals are naturally occurring elements in the soil and bedrock throughout North Carolina and are not necessarily a derivative of landfill leachate. In summary, the detected concentrations of total metals in the groundwater and surface water samples are most likely naturally occurring and related to sample turbidity. Metal cations typically adsorb to the surface of platy particles (clay and silt). Therefore, turbidity of the groundwater and surface water samples will relate to detected concentrations of the metal cations. Consequently, the metal concentrations detected should be considered natural background concentrations. We recommend that sampling continue on a semi-annual basis for the Appendix I list of VOCs and total metals constituents. TABLES TABLE 1 GROUNDWATER MONITORING WELL CONSTRUCTION AND GROUNDWATER ELEVATION DATA White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 October 26, 2015 Northing Easting Meas. Pt.Gnd. Surface *Depth to Depth to Water Total Borehole Screen Well Well Top of Rock Top of Well (feet)(feet)Elevation Elevation Water (bgs)Water (bmp)Elevation Depth (bgs)Depth (bgs)Type Monitors Depth (bgs)Rock Elev. MW-1A 721,096.30 812,481.47 2,520.02 2,517.97 19.75 21.80 2,498.22 UK 10.4 -25.4 2,507.6 -2,492.6 UK Deep Residuum UK UK MW-2 721,460.76 812,309.44 2,496.71 2,494.43 28.40 30.68 2,466.03 UK 19.9 -34.9 2,474.5 -2,459.5 UK Deep Residuum/PWR UK UK MW-2D 721,456.01 812,311.87 2,496.89 2,494.69 28.40 30.60 2,466.29 UK 44.6 -54.6 2,450.1 -2,440.1 UK Bedrock 36.9 2,457.8 MW-3r 721,943.38 812,063.70 2,462.61 2,459.53 30.37 33.45 2,429.16 41.5 26.3 -41.3 2,433.2 -2,418.2 II Deep Residuum NE NE MW-3Dr 721,940.67 812,082.82 2,461.89 2,458.42 34.03 37.50 2,424.39 65.0 49.8 -64.8 2,408.6 -2,393.6 IIIs Bedrock 44.0 2,414.4 MW-4A 721,693.04 811,976.64 2,493.85 2,491.60 42.03 44.28 2,449.57 UK 80.6 -95.6 2,411.0 -2,396.0 UK Bedrock 23.3 2,468.3 MW-8 721,704.50 812,155.03 2,477.33 2,474.84 28.56 31.05 2,446.28 UK 31.0 -41.0 2,443.8 -2,433.8 UK Deep Residuum UK UK MW-11S 719,905.88 811,642.89 2,674.58 UK UK 81.15 2,593.43 UK UK -UK UK -UK UK UK UK UK MW-11D 719,909.34 811,651.55 2,674.89 2,672.01 79.27 82.15 2,592.74 UK 118.0 -127.6 2,554.0 -2,544.4 UK Bedrock 97.0 2,575.0 MW-14 UK UK 2,711.69 UK UK 101.30 2,610.39 UK UK -UK UK -UK UK UK UK UK MW-15 UK UK 2,547.41 UK UK 9.69 2,537.72 UK UK -UK UK -UK UK UK UK UK MW-16 721,821.98 811,660.70 2,519.35 2,516.07 32.01 35.29 2,484.06 41.0 25.8 -40.8 2,490.3 -2,475.3 II Fill / Residuum 40.0 2,476.1 MW-17 721,783.47 811,219.93 2,542.55 2,539.13 53.54 56.96 2,485.59 63.0 43.0 -58.0 2,496.1 -2,481.1 II Bedrock 40.0 2,499.1 Notes: All survey data provided by McGill Associates, all units in feet. Data for MW-14 & MW-15 sourced from historical Municipal Engineering reports.Measuring Point Elevation is top of casing. *DTW from bgs values have been calculated from survey data provided by McGill Associates.II = Type II well All values shown to the nearest 0.1-ft have been rounded.IIIs = Type III screened well Water levels were measured on 10/26/15 by Pace Analytical.NE = Not encountered MW-4A was lowered 4.59 feet by Haywood County. All bgs referenced depths for MW-4A have been adjusted accordingly on this table.UK = Unknown, information is not available Screen Elevation Table 1 GWM of 1957-50 White Oak GW Stats 2nd 2015 Prepared by: IAI Checked by: DRM cm/sec ft/min ft/day MW-1A 1.50E-04 2.95E-04 4.25E-01 0.0753 0.114 0.28 102.48 MW-2 1.50E-04 2.95E-04 4.31E+00 0.0753 0.114 2.84 1,037.59 MW-4A 1.49E-04 2.93E-04 4.28E+00 0.1000 0.05 8.55 3,121.78 MW-8 1.50E-04 2.95E-04 4.31E+00 0.0753 0.114 2.84 1,037.59 MW-11S 2.40E-06 4.72E-06 6.89E-02 0.0836 0.114 0.05 18.43 MW-14 1.38E-05 2.72E-05 3.96E-01 0.0658 0.17 0.15 55.94 MW-15 2.10E-05 4.13E-05 6.03E-01 0.0658 0.17 0.23 85.13 Notes: 1. Hydraulic conductivity and effective porosity values are from prior site hydrogeologic studies performed by others. 2. Hydraulic gradients and flow velocities calculated from measurements taken during the October 26, 2015 sampling event. 3. Groundwater flow velocities calculated using the equation V = Ki/ne where 4. V = velocity 5. K = hydraulic conductivity 6. i = hydraulic gradient 7. ne = effective porosity 8. NA = information not available TABLE 2 GROUNDWATER FLOW DATA White Oak Landfill Haywood County, North Carolina Hydraulic Conductivity BLE Project Number J15-1957-50 Monitoring Well Local Hydraulic Gradient (ft/ft) Flow Velocity (ft/yr) Flow Velocity (ft/day) Effective Porosity Table 2 of 1957-50 White Oak GW Stats 2nd 2015 Prepared by: IAI Checked by: DRM TABLE 3 SUMMARY OF STATISTICAL ANALYSIS RESULTS White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Chemical/Percent Primary Primary Secondary Secondary SSI SSI Validated SSI Concentration Above MCL Compound ND Statistical Test Pass/Fail Statistical Test Pass/Fail Calculated as Leachate During Current Event Total Antimony 98%Poisson Prediction Limits Pass ----- Total Arsenic 92%Poisson Prediction Limits Pass ----- Total Barium 5%Prediction Limits Fail Shewhart-CUSUM Fail MW-2, MW-2D (3)No (3)Yes (MW-2, MW-2D) Total Beryllium 87%Kruskal-Wallis Fail Shewhart-CUSUM Pass --- Total Cadmium 87%Kruskal-Wallis Pass ----- Total Chromium 58%Kruskal-Wallis Pass ----- Total Cobalt 65%Kruskal-Wallis Fail Shewhart-CUSUM Pass --- Total Copper 63%Kruskal-Wallis Pass ----- Total Lead 77%Kruskal-Wallis Fail Shewhart-CUSUM Pass --- Total Nickel 46%Kruskal-Wallis Fail Shewhart-CUSUM Fail MW-3Dr No No Total Selenium 99%Poisson Prediction Limits Pass ----- Total Silver 99%Poisson Prediction Limits Pass ----- Total Thallium 94%Poisson Prediction Limits Pass ----- Total Vanadium 59%Kruskal-Wallis Pass ----- Total Zinc 37%Kruskal-Wallis Fail Shewhart-CUSUM Pass --- Acetone 100%Poisson Prediction Limits Pass ----- Carbon Disulfide 99%Poisson Prediction Limits Pass ----- Chloroethane 100%Poisson Prediction Limits Pass ----- Iodomethane 100%Poisson Prediction Limits Pass ----- Dichloromethane 99%Poisson Prediction Limits Pass ----- 2-Butanone 100%Poisson Prediction Limits Pass ----- Notes: 1. MCL = Maximum Contaminant Level 2. SSI = Statistically Significant Increase 3. Total barium is a naturally occuring metal throughout much of North Carolina and is likely related to sample turbidity. Table 3 of 1957-50 White Oak GW Stats 2nd 2015 Prepared by: IAI Checked by: DRM/MSP FIGURES LCID P I G E O N R I V E R FIN E S C R E E K R O A D CLOSED C & D PHASE 1 SR 1 3 3 8 MULCHING AND GRINDING TREATMENT AND PROCESSING TYPE 2 COMPOSTING MSW PHASE 2 MSW PHASE 1 CELL 3 CELL 2 PHASE 3 (8.8 ACRES) (6.7 ACRES) PHASE 4 FUTURE PHASE 1 MSWMSW (11.4 ACRES) (10.1 ACRES) (1.2 ACRES) (2.0 ACRES) (4.0 ACRES) (4.8 ACRES) PIGEON R I V E R APPENDICES APPENDIX A SUMMARY TABLES OF GROUNDWATER ANALYTICAL RESULTS White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-24-2000) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2A MW-2D MW-3A MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.9 NS NS 6.1 5.1 5.1 6.2 5.9 5.4 5.2 NS NP NP NS Specific Conductance mmhos/cm (on-site)1 NE 72 NS NS 69 55 51 89 85 89 100 NS NP NP NS Temperature °C (on-site)-NE 12 NS NS 13 14 14 12 12 13 13 NS NP NP NS Turbidity NTU (on-site)NT NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Total Antimony (Sb)mg/l 10 NE ND NS NS ND ND ND ND ND ND ND NS NP NP NS Total Arsenic (As)mg/l 10 50 ND NS NS ND ND ND ND ND ND ND NS NP NP NS Total Barium (Ba)mg/l 5 1000 250 NS NS 240 420 200 63 300 93 230 NS NP NP NS Total Beryllium (Be)mg/l 2 NE 4.4 NS NS ND 2 ND 2.2 ND ND ND NS NP NP NS Total Cadmium (Cd)mg/l 1 5 2 NS NS ND 1.3 1.2 1.3 2.1 ND 5.4 NS NP NP NS Total Chromium (Cr)mg/l 5 50 15 NS NS 18 17 11 ND 26 5.4 50 NS NP NP NS Total Cobalt (Co)mg/l 5 NE ND NS NS ND 8.2 5.4 ND 14 ND 16 NS NP NP NS Total Copper (Cu)mg/l 5 1000 12 NS NS ND ND 13 ND 27 ND 22 NS NP NP NS Total Lead (Pb)mg/l 10 15 35 NS NS ND ND ND ND 11 ND ND NS NP NP NS Total Nickel (Ni)mg/l 5 100 15 NS NS 17 12 8.3 ND 24 6.7 22 NS NP NP NS Total Selenium (Se)mg/l 20 50 ND NS NS ND ND ND ND ND ND ND NS NP NP NS Total Silver (Ag)mg/l 2 18 3.7 NS NS ND ND ND 6.9 ND ND ND NS NP NP NS Total Thallium (Tl)mg/l 2 NE 2 NS NS ND 3 2 4 ND 2 5 NS NP NP NS Total Vanadium (V)mg/l 5 NE 17 NS NS 19 32 21 ND 29 8.9 78 NS NP NP NS Total Zinc (Zn)mg/l 10 2100 150 NS NS 35 48 36 12 43 28 68 NS NP NP NS Acetone mg/l 100 700 NT NS NS NT NT NT NT NT NT NT NS NP NP NS Acrylonitrile mg/l 200 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Benzene mg/l 5 1 NT NS NS NT NT NT NT NT NT NT NS NP NP NS Bromochloromethane mg/l 5 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Bromodichloromethane mg/l 5 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Bromoform mg/l 5 0.19 NT NS NS NT NT NT NT NT NT NT NS NP NP NS Carbon Disulfide mg/l 100 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Bromomethane (Methylbromide)mg/l 10 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Carbon tetrachloride mg/l 10 0.3 NT NS NS NT NT NT NT NT NT NT NS NP NP NS Chlorobenzene (mono)mg/l 5 50 NT NS NS NT NT NT NT NT NT NT NS NP NP NS Chloroethane mg/l 10 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Chloroform mg/l 5 0.19 NT NS NS NT NT NT NT NT NT NT NS NP NP NS Chloromethane (Methylchloride)mg/l 10 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Dibromochloromethane mg/l 5 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025 NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 NT NS NS NT NT NT NT NT NT NT NS NP NP NS Dibromomethane mg/l 10 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,2-Dichlorobenzene mg/l 5 620 NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,4-Dichlorobenzene mg/l 5 75 NT NS NS NT NT NT NT NT NT NT NS NP NP NS trans-1,4-Dichloro-2-butene mg/l 100 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,1-Dichloroethane mg/l 5 700 NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,2-Dichloroethane mg/l 5 0.38 NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,1-Dichloroethene (-ethylene)mg/l 5 7 NT NS NS NT NT NT NT NT NT NT NS NP NP NS cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 NT NS NS NT NT NT NT NT NT NT NS NP NP NS trans-1,2-Dichloroethene (-ylene)mg/l 5 70 NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,2-Dichloropropane mg/l 5 0.56 NT NS NS NT NT NT NT NT NT NT NS NP NP NS cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Ethylbenzene mg/l 5 29 NT NS NS NT NT NT NT NT NT NT NS NP NP NS 2-Hexanone mg/l 50 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Iodomethane mg/l 10 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Dichloromethane (Methylene chloride)mg/l 10 5 NT NS NS NT NT NT NT NT NT NT NS NP NP NS 2-Butanone (Methyl ethyl ketone)mg/l 100 170 NT NS NS NT NT NT NT NT NT NT NS NP NP NS 4-Methyl-2-Pentanone mg/l 100 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Styrene mg/l 10 100 NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,1,2,2-Tetrachloroethane mg/l 5 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Tetrachloroethene (-ethylene)mg/l 5 0.7 NT NS NS NT NT NT NT NT NT NT NS NP NP NS Toluene mg/l 5 1000 NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,1,1-Trichloroethane mg/l 5 200 NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,1,2-Trichloroethane mg/l 5 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Trichloroethene (-ethylene)mg/l 5 2.8 NT NS NS NT NT NT NT NT NT NT NS NP NP NS Trichlorofluoromethane mg/l 5 2100 NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,2,3-Trichloropropane mg/l 15 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Vinyl acetate mg/l 50 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Vinyl chloride mg/l 10 0.015 NT NS NS NT NT NT NT NT NT NT NS NP NP NS Xylene mg/l 5 530 NT NS NS NT NT NT NT NT NT NT NS NP NP NS Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (4-24-2000) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (6-26-2000) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 5.9 6.8 NS NS NS NS NS NS NS NS NS NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 29 60 NS NS NS NS NS NS NS NS NS NP NP NT Temperature °C (on-site)-NE 14 14 NS NS NS NS NS NS NS NS NS NP NP NT Turbidity NTU (on-site)NT NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Total Antimony (Sb)mg/l 10 NE ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Arsenic (As)mg/l 10 50 ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Barium (Ba)mg/l 5 1000 300 67 NS NS NS NS NS NS NS NS NS NP NP ND Total Beryllium (Be)mg/l 2 NE ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Cadmium (Cd)mg/l 1 5 1.6 ND NS NS NS NS NS NS NS NS NS NP NP ND Total Chromium (Cr)mg/l 5 50 22 ND NS NS NS NS NS NS NS NS NS NP NP ND Total Cobalt (Co)mg/l 5 NE 10 ND NS NS NS NS NS NS NS NS NS NP NP ND Total Copper (Cu)mg/l 5 1000 17 6 NS NS NS NS NS NS NS NS NS NP NP ND Total Lead (Pb)mg/l 10 15 ND 10 NS NS NS NS NS NS NS NS NS NP NP ND Total Nickel (Ni)mg/l 5 100 15 ND NS NS NS NS NS NS NS NS NS NP NP ND Total Selenium (Se)mg/l 20 50 ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Silver (Ag)mg/l 2 18 ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Thallium (Tl)mg/l 2 NE ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Vanadium (V)mg/l 5 NE 40 6.3 NS NS NS NS NS NS NS NS NS NP NP ND Total Zinc (Zn)mg/l 10 2100 37 12 NS NS NS NS NS NS NS NS NS NP NP ND Acetone mg/l 100 700 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Acrylonitrile mg/l 200 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Benzene mg/l 5 1 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Bromochloromethane mg/l 5 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Bromodichloromethane mg/l 5 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Bromoform mg/l 5 0.19 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Carbon Disulfide mg/l 100 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Carbon tetrachloride mg/l 10 0.3 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Chlorobenzene (mono)mg/l 5 50 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Chloroethane mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Chloroform mg/l 5 0.19 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Dibromochloromethane mg/l 5 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Dibromomethane mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichlorobenzene mg/l 5 620 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,4-Dichlorobenzene mg/l 5 75 NT NT NS NS NS NS NS NS NS NS NS NP NP NT trans-1,4-Dichloro-2-butene mg/l 100 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,1-Dichloroethane mg/l 5 700 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichloroethane mg/l 5 0.38 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,1-Dichloroethene (-ethylene)mg/l 5 7 NT NT NS NS NS NS NS NS NS NS NS NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 NT NT NS NS NS NS NS NS NS NS NS NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l 5 70 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichloropropane mg/l 5 0.56 NT NT NS NS NS NS NS NS NS NS NS NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Ethylbenzene mg/l 5 29 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 2-Hexanone mg/l 50 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Iodomethane mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Dichloromethane (Methylene chloride)mg/l 10 5 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l 100 170 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Styrene mg/l 10 100 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,1,2,2-Tetrachloroethane mg/l 5 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Tetrachloroethene (-ethylene)mg/l 5 0.7 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Toluene mg/l 5 1000 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,1,1-Trichloroethane mg/l 5 200 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Trichloroethene (-ethylene)mg/l 5 2.8 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Trichlorofluoromethane mg/l 5 2100 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Vinyl acetate mg/l 50 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Vinyl chloride mg/l 10 0.015 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Xylene mg/l 5 530 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (6-26-2000) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (7-26-2000) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Specific Conductance mmhos/cm (on-site)1 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Temperature °C (on-site)-NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Turbidity NTU (on-site)NT NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Total Antimony (Sb)mg/l 10 NE ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Arsenic (As)mg/l 10 50 ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Barium (Ba)mg/l 5 1000 330 30 NS NS NS NS NS NS NS NS NS NP NP ND Total Beryllium (Be)mg/l 2 NE ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Cadmium (Cd)mg/l 1 5 1.1 3.2 NS NS NS NS NS NS NS NS NS NP NP ND Total Chromium (Cr)mg/l 5 50 29 20 NS NS NS NS NS NS NS NS NS NP NP ND Total Cobalt (Co)mg/l 5 NE 9.9 ND NS NS NS NS NS NS NS NS NS NP NP ND Total Copper (Cu)mg/l 5 1000 12 6.1 NS NS NS NS NS NS NS NS NS NP NP ND Total Lead (Pb)mg/l 10 15 ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Nickel (Ni)mg/l 5 100 16 9.7 NS NS NS NS NS NS NS NS NS NP NP ND Total Selenium (Se)mg/l 20 50 ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Silver (Ag)mg/l 2 18 ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Thallium (Tl)mg/l 2 NE ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Vanadium (V)mg/l 5 NE 45 ND NS NS NS NS NS NS NS NS NS NP NP ND Total Zinc (Zn)mg/l 10 2100 65 66 NS NS NS NS NS NS NS NS NS NP NP ND Acetone mg/l 100 700 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Acrylonitrile mg/l 200 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Benzene mg/l 5 1 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Bromochloromethane mg/l 5 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Bromodichloromethane mg/l 5 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Bromoform mg/l 5 0.19 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Carbon Disulfide mg/l 100 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Carbon tetrachloride mg/l 10 0.3 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Chlorobenzene (mono)mg/l 5 50 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Chloroethane mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Chloroform mg/l 5 0.19 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Dibromochloromethane mg/l 5 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Dibromomethane mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichlorobenzene mg/l 5 620 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,4-Dichlorobenzene mg/l 5 75 NT NT NS NS NS NS NS NS NS NS NS NP NP NT trans-1,4-Dichloro-2-butene mg/l 100 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,1-Dichloroethane mg/l 5 700 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichloroethane mg/l 5 0.38 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,1-Dichloroethene (-ethylene)mg/l 5 7 NT NT NS NS NS NS NS NS NS NS NS NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 NT NT NS NS NS NS NS NS NS NS NS NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l 5 70 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichloropropane mg/l 5 0.56 NT NT NS NS NS NS NS NS NS NS NS NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Ethylbenzene mg/l 5 29 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 2-Hexanone mg/l 50 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Iodomethane mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Dichloromethane (Methylene chloride)mg/l 10 5 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l 100 170 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Styrene mg/l 10 100 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,1,2,2-Tetrachloroethane mg/l 5 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Tetrachloroethene (-ethylene)mg/l 5 0.7 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Toluene mg/l 5 1000 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,1,1-Trichloroethane mg/l 5 200 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Trichloroethene (-ethylene)mg/l 5 2.8 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Trichlorofluoromethane mg/l 5 2100 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Vinyl acetate mg/l 50 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Vinyl chloride mg/l 10 0.015 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Xylene mg/l 5 530 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (7-26-2000) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (9-18-2000) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Specific Conductance mmhos/cm (on-site)1 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Temperature °C (on-site)-NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Turbidity NTU (on-site)NT NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Total Antimony (Sb)mg/l 30 NE NS NS NS NT NT NS NS NS NT NS NS NP NP ND Total Arsenic (As)mg/l 10 50 NS NS NS NT NT NS NS NS NT NS NS NP NP ND Total Barium (Ba)mg/l 500 1000 NS NS NS 330 92 NS NS NS NT NS NS NP NP ND Total Beryllium (Be)mg/l 2 NE NS NS NS NT NT NS NS NS NT NS NS NP NP ND Total Cadmium (Cd)mg/l 1 5 NS NS NS NT NT NS NS NS NT NS NS NP NP ND Total Chromium (Cr)mg/l 10 50 NS NS NS NT NT NS NS NS NT NS NS NP NP ND Total Cobalt (Co)mg/l 10 NE NS NS NS NT NT NS NS NS NT NS NS NP NP ND Total Copper (Cu)mg/l 200 1000 NS NS NS NT NT NS NS NS NT NS NS NP NP ND Total Lead (Pb)mg/l 10 15 NS NS NS NT NT NS NS NS ND NS NS NP NP ND Total Nickel (Ni)mg/l 50 100 NS NS NS 8.8 NT NS NS NS NT NS NS NP NP ND Total Selenium (Se)mg/l 20 50 NS NS NS NT NT NS NS NS NT NS NS NP NP ND Total Silver (Ag)mg/l 10 18 NS NS NS NT NT NS NS NS NT NS NS NP NP ND Total Thallium (Tl)mg/l 20 NE NS NS NS NT NT NS NS NS NT NS NS NP NP ND Total Vanadium (V)mg/l 40 NE NS NS NS NT NT NS NS NS NT NS NS NP NP ND Total Zinc (Zn)mg/l 50 2100 NS NS NS NT NT NS NS NS NT NS NS NP NP ND Acetone mg/l 100 700 NS NS NS NT NT NS NS NS NT NS NS NP NP NT Acrylonitrile mg/l 200 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Benzene mg/l 5 1 NS NS NS NT NT NS NS NS NT NS NS NP NP NT Bromochloromethane mg/l 5 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Bromodichloromethane mg/l 5 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Bromoform mg/l 5 0.19 NS NS NS NT NT NS NS NS NT NS NS NP NP NT Carbon Disulfide mg/l 100 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Bromomethane (Methylbromide)mg/l 10 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Carbon tetrachloride mg/l 10 0.3 NS NS NS NT NT NS NS NS NT NS NS NP NP NT Chlorobenzene (mono)mg/l 5 50 NS NS NS NT NT NS NS NS NT NS NS NP NP NT Chloroethane mg/l 10 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Chloroform mg/l 5 0.19 NS NS NS NT NT NS NS NS NT NS NS NP NP NT Chloromethane (Methylchloride)mg/l 10 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Dibromochloromethane mg/l 5 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025 NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 NS NS NS NT NT NS NS NS NT NS NS NP NP NT Dibromomethane mg/l 10 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,2-Dichlorobenzene mg/l 5 620 NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,4-Dichlorobenzene mg/l 5 75 NS NS NS NT NT NS NS NS NT NS NS NP NP NT trans-1,4-Dichloro-2-butene mg/l 100 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,1-Dichloroethane mg/l 5 700 NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,2-Dichloroethane mg/l 5 0.38 NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,1-Dichloroethene (-ethylene)mg/l 5 7 NS NS NS NT NT NS NS NS NT NS NS NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 NS NS NS NT NT NS NS NS NT NS NS NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l 5 70 NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,2-Dichloropropane mg/l 5 0.56 NS NS NS NT NT NS NS NS NT NS NS NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Ethylbenzene mg/l 5 29 NS NS NS NT NT NS NS NS NT NS NS NP NP NT 2-Hexanone mg/l 50 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Iodomethane mg/l 10 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Dichloromethane (Methylene chloride)mg/l 10 5 NS NS NS NT NT NS NS NS NT NS NS NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l 100 170 NS NS NS NT NT NS NS NS NT NS NS NP NP NT 4-Methyl-2-Pentanone mg/l 100 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Styrene mg/l 10 100 NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,1,2,2-Tetrachloroethane mg/l 5 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Tetrachloroethene (-ethylene)mg/l 5 0.7 NS NS NS NT NT NS NS NS NT NS NS NP NP NT Toluene mg/l 5 1000 NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,1,1-Trichloroethane mg/l 5 200 NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,1,2-Trichloroethane mg/l 5 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Trichloroethene (-ethylene)mg/l 5 2.8 NS NS NS NT NT NS NS NS NT NS NS NP NP NT Trichlorofluoromethane mg/l 5 2100 NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,2,3-Trichloropropane mg/l 15 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Vinyl acetate mg/l 50 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Vinyl chloride mg/l 10 0.015 NS NS NS NT NT NS NS NS NT NS NS NP NP NT Xylene mg/l 5 530 NS NS NS NT NT NS NS NS NT NS NS NP NP NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (9-18-2000) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-9-2001) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 5.9 7.3 NS 6.4 6 6.3 6 6.1 8.2 5.8 NS NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 20 60 NS 75 75 68 130 90 110 125 NS NP NP NT Temperature °C (on-site)-NE 15 15 NS 13 15 15 14 15 15 15 NS NP NP NT Turbidity NTU (on-site)NT NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Total Antimony (Sb)mg/l 10 NE ND ND NS ND ND ND ND ND ND ND NS NP NP ND Total Arsenic (As)mg/l 10 50 ND ND NS ND ND ND ND ND ND ND NS NP NP ND Total Barium (Ba)mg/l 5 1000 1300 380 NS 180 330 120 80 290 360 970 NS NP NP ND Total Beryllium (Be)mg/l 2 NE 2.3 7 NS ND ND ND ND ND 2.4 4.8 NS NP NP ND Total Cadmium (Cd)mg/l 1 5 130 2 NS ND ND ND 1.7 1.8 2.7 19 NS NP NP ND Total Chromium (Cr)mg/l 5 50 130 ND NS 11 8.4 ND ND 20 27 160 NS NP NP ND Total Cobalt (Co)mg/l 5 NE 54 ND NS ND ND ND 13 12 13 59 NS NP NP ND Total Copper (Cu)mg/l 5 1000 77 8.4 NS ND ND 5.4 ND 26 38 110 NS NP NP ND Total Lead (Pb)mg/l 10 15 ND 59 NS ND ND ND ND ND 18 2.5 NS NP NP ND Total Nickel (Ni)mg/l 5 100 76 7.2 NS 9.6 5.3 ND ND 18 28 6.1 NS NP NP ND Total Selenium (Se)mg/l 20 50 ND ND NS ND ND ND ND ND ND ND NS NP NP ND Total Silver (Ag)mg/l 2 18 ND ND NS ND ND ND ND ND ND ND NS NP NP ND Total Thallium (Tl)mg/l 2 NE 40 ND NS ND ND ND ND ND ND ND NS NP NP ND Total Vanadium (V)mg/l 5 NE 250 1.4 NS 13 19 9.3 ND 24 41 230 NS NP NP ND Total Zinc (Zn)mg/l 10 2100 230 130 NS 12 24 18 17 33 75 200 NS NP NP 24 Acetone mg/l 100 700 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Acrylonitrile mg/l 200 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Benzene mg/l 5 1 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Bromochloromethane mg/l 5 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Bromodichloromethane mg/l 5 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Bromoform mg/l 5 0.19 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Carbon Disulfide mg/l 100 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Carbon tetrachloride mg/l 10 0.3 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Chlorobenzene (mono)mg/l 5 50 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Chloroethane mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Chloroform mg/l 5 0.19 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Dibromochloromethane mg/l 5 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Dibromomethane mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,2-Dichlorobenzene mg/l 5 620 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,4-Dichlorobenzene mg/l 5 75 NT NT NS NT NT NT NT NT NT NT NS NP NP NT trans-1,4-Dichloro-2-butene mg/l 100 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,1-Dichloroethane mg/l 5 700 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,2-Dichloroethane mg/l 5 0.38 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,1-Dichloroethene (-ethylene)mg/l 5 7 NT NT NS NT NT NT NT NT NT NT NS NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 NT NT NS NT NT NT NT NT NT NT NS NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l 5 70 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,2-Dichloropropane mg/l 5 0.56 NT NT NS NT NT NT NT NT NT NT NS NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Ethylbenzene mg/l 5 29 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 2-Hexanone mg/l 50 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Iodomethane mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Dichloromethane (Methylene chloride)mg/l 10 5 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l 100 170 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Styrene mg/l 10 100 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,1,2,2-Tetrachloroethane mg/l 5 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Tetrachloroethene (-ethylene)mg/l 5 0.7 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Toluene mg/l 5 1000 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,1,1-Trichloroethane mg/l 5 200 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Trichloroethene (-ethylene)mg/l 5 2.8 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Trichlorofluoromethane mg/l 5 2100 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Vinyl acetate mg/l 50 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Vinyl chloride mg/l 10 0.015 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Xylene mg/l 5 530 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (4-9-2001) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (9-18-2001) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Specific Conductance mmhos/cm (on-site)1 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Temperature °C (on-site)-NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Turbidity NTU (on-site)NT NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Total Antimony (Sb)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Arsenic (As)mg/l 10 50 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Barium (Ba)mg/l 5 1000 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Beryllium (Be)mg/l 2 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Cadmium (Cd)mg/l 1 5 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Chromium (Cr)mg/l 5 50 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Cobalt (Co)mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Copper (Cu)mg/l 5 1000 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Lead (Pb)mg/l 10 15 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Nickel (Ni)mg/l 5 100 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Selenium (Se)mg/l 20 50 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Silver (Ag)mg/l 2 18 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Thallium (Tl)mg/l 2 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Vanadium (V)mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Zinc (Zn)mg/l 10 2100 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Acetone mg/l 100 700 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Acrylonitrile mg/l 200 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Benzene mg/l 5 1 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromochloromethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromodichloromethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromoform mg/l 5 0.19 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Carbon Disulfide mg/l 100 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromomethane (Methylbromide)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Carbon tetrachloride mg/l 10 0.3 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chlorobenzene (mono)mg/l 5 50 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chloroethane mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chloroform mg/l 5 0.19 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chloromethane (Methylchloride)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Dibromochloromethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Dibromomethane mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichlorobenzene mg/l 5 620 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,4-Dichlorobenzene mg/l 5 75 NS NS NS NS NS NS NS NS NS NS NS NP NP NT trans-1,4-Dichloro-2-butene mg/l 100 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1-Dichloroethane mg/l 5 700 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichloroethane mg/l 5 0.38 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1-Dichloroethene (-ethylene)mg/l 5 7 NS NS NS NS NS NS NS NS NS NS NS NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 NS NS NS NS NS NS NS NS NS NS NS NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l 5 70 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichloropropane mg/l 5 0.56 NS NS NS NS NS NS NS NS NS NS NS NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Ethylbenzene mg/l 5 29 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 2-Hexanone mg/l 50 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Iodomethane mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Dichloromethane (Methylene chloride)mg/l 10 5 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l 100 170 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 4-Methyl-2-Pentanone mg/l 100 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Styrene mg/l 10 100 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,2,2-Tetrachloroethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Tetrachloroethene (-ethylene)mg/l 5 0.7 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Toluene mg/l 5 1000 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,1-Trichloroethane mg/l 5 200 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,2-Trichloroethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Trichloroethene (-ethylene)mg/l 5 2.8 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Trichlorofluoromethane mg/l 5 2100 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2,3-Trichloropropane mg/l 15 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Vinyl acetate mg/l 50 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Vinyl chloride mg/l 10 0.015 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Xylene mg/l 5 530 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (9-18-2001) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-29-2001) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Specific Conductance mmhos/cm (on-site)1 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Temperature °C (on-site)-NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Turbidity NTU (on-site)NT NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Total Antimony (Sb)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Arsenic (As)mg/l 10 50 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Barium (Ba)mg/l 5 1000 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Beryllium (Be)mg/l 2 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Cadmium (Cd)mg/l 1 5 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Chromium (Cr)mg/l 5 50 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Cobalt (Co)mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Copper (Cu)mg/l 5 1000 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Lead (Pb)mg/l 10 15 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Nickel (Ni)mg/l 5 100 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Selenium (Se)mg/l 20 50 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Silver (Ag)mg/l 2 18 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Thallium (Tl)mg/l 2 NE NS NS NS NS NS NS NS NS NS NS NS NP NP 3.1 Total Vanadium (V)mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Zinc (Zn)mg/l 10 2100 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Acetone mg/l 100 700 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Acrylonitrile mg/l 200 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Benzene mg/l 5 1 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromochloromethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromodichloromethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromoform mg/l 5 0.19 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Carbon Disulfide mg/l 100 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromomethane (Methylbromide)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Carbon tetrachloride mg/l 10 0.3 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chlorobenzene (mono)mg/l 5 50 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chloroethane mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chloroform mg/l 5 0.19 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chloromethane (Methylchloride)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Dibromochloromethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Dibromomethane mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichlorobenzene mg/l 5 620 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,4-Dichlorobenzene mg/l 5 75 NS NS NS NS NS NS NS NS NS NS NS NP NP NT trans-1,4-Dichloro-2-butene mg/l 100 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1-Dichloroethane mg/l 5 700 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichloroethane mg/l 5 0.38 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1-Dichloroethene (-ethylene)mg/l 5 7 NS NS NS NS NS NS NS NS NS NS NS NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 NS NS NS NS NS NS NS NS NS NS NS NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l 5 70 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichloropropane mg/l 5 0.56 NS NS NS NS NS NS NS NS NS NS NS NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Ethylbenzene mg/l 5 29 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 2-Hexanone mg/l 50 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Iodomethane mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Dichloromethane (Methylene chloride)mg/l 10 5 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l 100 170 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 4-Methyl-2-Pentanone mg/l 100 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Styrene mg/l 10 100 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,2,2-Tetrachloroethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Tetrachloroethene (-ethylene)mg/l 5 0.7 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Toluene mg/l 5 1000 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,1-Trichloroethane mg/l 5 200 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,2-Trichloroethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Trichloroethene (-ethylene)mg/l 5 2.8 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Trichlorofluoromethane mg/l 5 2100 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2,3-Trichloropropane mg/l 15 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Vinyl acetate mg/l 50 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Vinyl chloride mg/l 10 0.015 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Xylene mg/l 5 530 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (10-29-2001) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (1-30-2002) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Specific Conductance mmhos/cm (on-site)1 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Temperature °C (on-site)-NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Turbidity NTU (on-site)NT NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Total Antimony (Sb)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Arsenic (As)mg/l 10 50 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Barium (Ba)mg/l 5 1000 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Beryllium (Be)mg/l 2 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Cadmium (Cd)mg/l 1 5 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Chromium (Cr)mg/l 5 50 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Cobalt (Co)mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Copper (Cu)mg/l 5 1000 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Lead (Pb)mg/l 10 15 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Nickel (Ni)mg/l 5 100 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Selenium (Se)mg/l 20 50 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Silver (Ag)mg/l 2 18 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Thallium (Tl)mg/l 2 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Vanadium (V)mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Zinc (Zn)mg/l 10 2100 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Acetone mg/l 100 700 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Acrylonitrile mg/l 200 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Benzene mg/l 5 1 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromochloromethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromodichloromethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromoform mg/l 5 0.19 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Carbon Disulfide mg/l 100 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromomethane (Methylbromide)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Carbon tetrachloride mg/l 10 0.3 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chlorobenzene (mono)mg/l 5 50 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chloroethane mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chloroform mg/l 5 0.19 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chloromethane (Methylchloride)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Dibromochloromethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Dibromomethane mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichlorobenzene mg/l 5 620 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,4-Dichlorobenzene mg/l 5 75 NS NS NS NS NS NS NS NS NS NS NS NP NP NT trans-1,4-Dichloro-2-butene mg/l 100 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1-Dichloroethane mg/l 5 700 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichloroethane mg/l 5 0.38 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1-Dichloroethene (-ethylene)mg/l 5 7 NS NS NS NS NS NS NS NS NS NS NS NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 NS NS NS NS NS NS NS NS NS NS NS NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l 5 70 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichloropropane mg/l 5 0.56 NS NS NS NS NS NS NS NS NS NS NS NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Ethylbenzene mg/l 5 29 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 2-Hexanone mg/l 50 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Iodomethane mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Dichloromethane (Methylene chloride)mg/l 10 5 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l 100 170 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 4-Methyl-2-Pentanone mg/l 100 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Styrene mg/l 10 100 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,2,2-Tetrachloroethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Tetrachloroethene (-ethylene)mg/l 5 0.7 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Toluene mg/l 5 1000 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,1-Trichloroethane mg/l 5 200 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,2-Trichloroethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Trichloroethene (-ethylene)mg/l 5 2.8 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Trichlorofluoromethane mg/l 5 2100 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2,3-Trichloropropane mg/l 15 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Vinyl acetate mg/l 50 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Vinyl chloride mg/l 10 0.015 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Xylene mg/l 5 530 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (1-30-2002) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (2-28-2002) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Specific Conductance mmhos/cm (on-site)1 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Temperature °C (on-site)-NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Turbidity NTU (on-site)NT NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Total Antimony (Sb)mg/l 30 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Arsenic (As)mg/l 10 50 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Barium (Ba)mg/l 500 1000 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Beryllium (Be)mg/l 2 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Cadmium (Cd)mg/l 1 5 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Chromium (Cr)mg/l 10 50 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Cobalt (Co)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Copper (Cu)mg/l 200 1000 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Lead (Pb)mg/l 10 15 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Nickel (Ni)mg/l 50 100 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Selenium (Se)mg/l 20 50 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Silver (Ag)mg/l 10 18 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Thallium (Tl)mg/l 20 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Vanadium (V)mg/l 40 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Zinc (Zn)mg/l 50 2100 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Acetone mg/l 100 700 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Acrylonitrile mg/l 200 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Benzene mg/l 5 1 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromochloromethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromodichloromethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromoform mg/l 5 0.19 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Carbon Disulfide mg/l 100 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromomethane (Methylbromide)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Carbon tetrachloride mg/l 10 0.3 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chlorobenzene (mono)mg/l 5 50 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chloroethane mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chloroform mg/l 5 0.19 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chloromethane (Methylchloride)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Dibromochloromethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Dibromomethane mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichlorobenzene mg/l 5 620 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,4-Dichlorobenzene mg/l 5 75 NS NS NS NS NS NS NS NS NS NS NS NP NP NT trans-1,4-Dichloro-2-butene mg/l 100 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1-Dichloroethane mg/l 5 700 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichloroethane mg/l 5 0.38 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1-Dichloroethene (-ethylene)mg/l 5 7 NS NS NS NS NS NS NS NS NS NS NS NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 NS NS NS NS NS NS NS NS NS NS NS NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l 5 70 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichloropropane mg/l 5 0.56 NS NS NS NS NS NS NS NS NS NS NS NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Ethylbenzene mg/l 5 29 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 2-Hexanone mg/l 50 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Iodomethane mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Dichloromethane (Methylene chloride)mg/l 10 5 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l 100 170 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 4-Methyl-2-Pentanone mg/l 100 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Styrene mg/l 10 100 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,2,2-Tetrachloroethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Tetrachloroethene (-ethylene)mg/l 5 0.7 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Toluene mg/l 5 1000 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,1-Trichloroethane mg/l 5 200 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,2-Trichloroethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Trichloroethene (-ethylene)mg/l 5 2.8 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Trichlorofluoromethane mg/l 5 2100 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2,3-Trichloropropane mg/l 15 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Vinyl acetate mg/l 50 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Vinyl chloride mg/l 10 0.015 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Xylene mg/l 5 530 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (2-28-2002) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-15-2002) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.01 6.42 NS 6.46 5.89 5.25 5.75 5.68 6.88 6.01 NS NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 21 42 NS 75 82 84 101 93 94 125 NS NP NP NT Temperature °C (on-site)-NE 15.9 17.4 NS 15.3 15.7 16.8 16.2 13.2 16.3 17.3 NS NP NP NT Turbidity NTU (on-site)NT NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Total Antimony (Sb)mg/l 10 NE 15.0 ND NS ND ND ND NT ND ND 11 NS NP NP ND Total Arsenic (As)mg/l 10 50 ND ND NS ND ND ND NT ND ND ND NS NP NP ND Total Barium (Ba)mg/l 5 1000 1300 41 NS ND ND 160 23 190 460 1400 NS NP NP ND Total Beryllium (Be)mg/l 2 NE 2.1 ND NS ND ND ND ND ND 2.5 4.5 NS NP NP ND Total Cadmium (Cd)mg/l 10 5 13 ND NS ND ND ND 4 ND 5.5 19 NS NP NP ND Total Chromium (Cr)mg/l 5 50 170 ND NS ND ND 5.7 7 10 56 180 NS NP NP ND Total Cobalt (Co)mg/l 5 NE 58 ND NS ND ND ND 18 8.2 21 82 NS NP NP ND Total Copper (Cu)mg/l 2 1000 69 ND NS ND ND ND ND 13 68 120 NS NP NP 150 Total Lead (Pb)mg/l 10 15 13 ND NS ND ND ND ND ND 13 29 NS NP NP ND Total Nickel (Ni)mg/l 5 100 74 ND NS ND ND ND 6.2 9.2 44 68 NS NP NP ND Total Selenium (Se)mg/l 20 50 ND ND NS ND ND ND ND ND ND ND NS NP NP ND Total Silver (Ag)mg/l 2 18 ND ND NS ND ND ND ND ND ND ND NS NP NP ND Total Thallium (Tl)mg/l 2 NE 40 ND NS ND ND ND ND ND ND ND NS NP NP ND Total Vanadium (V)mg/l 5 NE 240 ND NS ND ND 11 21 14 69 260 NS NP NP ND Total Zinc (Zn)mg/l 10 2100 230 16 NS ND ND 13 33 38 120 230 NS NP NP 15 Acetone mg/l 100 700 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Acrylonitrile mg/l 200 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Benzene mg/l 5 1 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Bromochloromethane mg/l 5 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Bromodichloromethane mg/l 5 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Bromoform mg/l 5 0.19 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Carbon Disulfide mg/l 100 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Carbon tetrachloride mg/l 10 0.3 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Chlorobenzene (mono)mg/l 5 50 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Chloroethane mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Chloroform mg/l 5 0.19 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Dibromochloromethane mg/l 5 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Dibromomethane mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,2-Dichlorobenzene mg/l 5 620 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,4-Dichlorobenzene mg/l 5 75 NT NT NS NT NT NT NT NT NT NT NS NP NP NT trans-1,4-Dichloro-2-butene mg/l 100 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,1-Dichloroethane mg/l 5 700 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,2-Dichloroethane mg/l 5 0.38 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,1-Dichloroethene (-ethylene)mg/l 5 7 NT NT NS NT NT NT NT NT NT NT NS NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 NT NT NS NT NT NT NT NT NT NT NS NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l 5 70 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,2-Dichloropropane mg/l 5 0.56 NT NT NS NT NT NT NT NT NT NT NS NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Ethylbenzene mg/l 5 29 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 2-Hexanone mg/l 50 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Iodomethane mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Dichloromethane (Methylene chloride)mg/l 10 5 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l 100 170 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Styrene mg/l 10 100 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,1,2,2-Tetrachloroethane mg/l 5 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Tetrachloroethene (-ethylene)mg/l 5 0.7 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Toluene mg/l 5 1000 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,1,1-Trichloroethane mg/l 5 200 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Trichloroethene (-ethylene)mg/l 5 2.8 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Trichlorofluoromethane mg/l 5 2100 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Vinyl acetate mg/l 50 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Vinyl chloride mg/l 10 0.015 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Xylene mg/l 5 530 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (4-15-2002) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (9-26-2002) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.5 7.3 7.09 6.14 6.17 6.18 5.96 5.96 7.22 6.37 6.65 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 22 59 52 71 85 82 117 101 92 130 97 NP NP NT Temperature °C (on-site)-NE 15.1 13.5 13.7 13.5 13.9 14 15.8 14.6 15.1 17.7 16.6 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 10 NE ND ND ND 12 ND ND ND ND ND ND 98 NP NP ND Total Arsenic (As)mg/l 5 50 ND 5.7 ND ND ND ND ND ND 27 ND 68 NP NP ND Total Barium (Ba)mg/l 5 1000 330 500 750 4200 120 230 93 410 910 1400 11000 NP NP ND Total Beryllium (Be)mg/l 2 NE ND 7 2.1 5.1 ND ND ND ND 8.5 4.7 95 NP NP ND Total Cadmium (Cd)mg/l 1 5 ND ND 4.2 21 ND 10 ND 2.3 4.2 19 180 NP NP ND Total Chromium (Cr)mg/l 5 50 33 5.4 33 510 ND 5.2 ND 37 36 230 770 NP NP ND Total Cobalt (Co)mg/l 5 NE 13 5.4 16 100 ND 16 7.4 21 19 85 560 NP NP ND Total Copper (Cu)mg/l 2 1000 20 10 31 220 ND ND 2.6 42 88 150 450 NP NP ND Total Lead (Pb)mg/l 10 15 ND 76 29 ND ND ND ND ND 150 20 740 NP NP ND Total Nickel (Ni)mg/l 5 100 16 6.8 31 400 ND ND ND 27 40 78 430 NP NP ND Total Selenium (Se)mg/l 20 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Silver (Ag)mg/l 2 18 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND 65 NP NP ND Total Vanadium (V)mg/l 5 NE 58 16 44 640 ND ND ND 42 50 310 1000 NP NP ND Total Zinc (Zn)mg/l 10 2100 57 120 110 580 ND 20 ND 56 250 280 4800 NP NP 2000 Acetone mg/l 100 700 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Acrylonitrile mg/l 200 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Benzene mg/l 5 1 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Bromochloromethane mg/l 5 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Bromodichloromethane mg/l 5 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Bromoform mg/l 5 0.19 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Carbon Disulfide mg/l 100 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Carbon tetrachloride mg/l 10 0.3 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Chlorobenzene (mono)mg/l 5 50 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Chloroethane mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Chloroform mg/l 5 0.19 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Dibromochloromethane mg/l 5 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Dibromomethane mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,2-Dichlorobenzene mg/l 5 620 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,4-Dichlorobenzene mg/l 5 75 NT NT NT NT NT NT NT NT NT NT NT NP NP NT trans-1,4-Dichloro-2-butene mg/l 100 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,1-Dichloroethane mg/l 5 700 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,2-Dichloroethane mg/l 5 0.38 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,1-Dichloroethene (-ethylene)mg/l 5 7 NT NT NT NT NT NT NT NT NT NT NT NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 NT NT NT NT NT NT NT NT NT NT NT NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l 5 70 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,2-Dichloropropane mg/l 5 0.56 NT NT NT NT NT NT NT NT NT NT NT NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Ethylbenzene mg/l 5 29 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 2-Hexanone mg/l 50 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Iodomethane mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Dichloromethane (Methylene chloride)mg/l 10 5 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l 100 170 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Styrene mg/l 10 100 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,1,2,2-Tetrachloroethane mg/l 5 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Tetrachloroethene (-ethylene)mg/l 5 0.7 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Toluene mg/l 5 1000 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,1,1-Trichloroethane mg/l 5 200 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Trichloroethene (-ethylene)mg/l 5 2.8 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Trichlorofluoromethane mg/l 5 2100 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Vinyl acetate mg/l 50 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Vinyl chloride mg/l 10 0.015 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Xylene mg/l 5 530 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (9-26-2002) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-28-2003) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 8.3 7.15 6.89 6.37 6.21 6.17 6.4 6.16 8.15 5.85 6.75 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 29 43 55 91 110 99 150 114 100 138 125 NP NP NT Temperature °C (on-site)-NE 16.7 15.9 15.6 15.6 16.3 15.3 13.5 14.2 17.7 14.9 18.4 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Arsenic (As)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND 24 NP NP ND Total Barium (Ba)mg/l 5 1000 600 66 220 1800 160 140 110 92 360 800 2800 NP NP ND Total Beryllium (Be)mg/l 2 NE ND ND ND ND ND ND ND ND 2 2.2 20 NP NP ND Total Cadmium (Cd)mg/l 1 5 3.6 ND ND 6 ND ND ND ND 2.9 16 20 NP NP ND Total Chromium (Cr)mg/l 5 50 ND ND ND 89 ND ND ND ND ND 110 27 NP NP ND Total Cobalt (Co)mg/l 5 NE 21 ND ND 37 ND ND 6.9 ND 17 50 81 NP NP ND Total Copper (Cu)mg/l 2 1000 24 ND 2.6 40 ND ND ND ND 28 94 71 NP NP ND Total Lead (Pb)mg/l 10 15 ND ND ND ND ND ND ND ND 25 ND 300 NP NP ND Total Nickel (Ni)mg/l 5 100 ND ND ND 90 ND ND ND ND ND 26 70 NP NP ND Total Selenium (Se)mg/l 20 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Silver (Ag)mg/l 2 18 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 1 NE ND ND ND 1.6 ND ND ND ND 1.4 ND 15 NP NP ND Total Vanadium (V)mg/l 5 NE 89 ND 9.6 170 6.8 6.8 ND ND 37 230 130 NP NP ND Total Zinc (Zn)mg/l 10 2100 86 14 31 160 16 ND ND ND 81 190 800 NP NP ND Acetone mg/l 100 700 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Acrylonitrile mg/l 200 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Benzene mg/l 5 1 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Bromochloromethane mg/l 5 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Bromodichloromethane mg/l 5 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Bromoform mg/l 5 0.19 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Carbon Disulfide mg/l 100 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Carbon tetrachloride mg/l 10 0.3 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Chlorobenzene (mono)mg/l 5 50 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Chloroethane mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Chloroform mg/l 5 0.19 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Dibromochloromethane mg/l 5 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Dibromomethane mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,2-Dichlorobenzene mg/l 5 620 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,4-Dichlorobenzene mg/l 5 75 NT NT NT NT NT NT NT NT NT NT NT NP NP NT trans-1,4-Dichloro-2-butene mg/l 100 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,1-Dichloroethane mg/l 5 700 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,2-Dichloroethane mg/l 5 0.38 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,1-Dichloroethene (-ethylene)mg/l 5 7 NT NT NT NT NT NT NT NT NT NT NT NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 NT NT NT NT NT NT NT NT NT NT NT NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l 5 70 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,2-Dichloropropane mg/l 5 0.56 NT NT NT NT NT NT NT NT NT NT NT NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Ethylbenzene mg/l 5 29 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 2-Hexanone mg/l 50 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Iodomethane mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Dichloromethane (Methylene chloride)mg/l 10 5 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l 100 170 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Styrene mg/l 10 100 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,1,2,2-Tetrachloroethane mg/l 5 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Tetrachloroethene (-ethylene)mg/l 5 0.7 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Toluene mg/l 5 1000 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,1,1-Trichloroethane mg/l 5 200 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Trichloroethene (-ethylene)mg/l 5 2.8 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Trichlorofluoromethane mg/l 5 2100 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Vinyl acetate mg/l 50 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Vinyl chloride mg/l 10 0.015 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Xylene mg/l 5 530 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (4-28-2003) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-30-2003) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.58 6.9 6.73 6.57 6.26 6.44 6.33 6.27 7.7 6.18 6.46 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 29 39 58 82 119 110 140 115 105 149 120 NP NP NT Temperature °C (on-site)-NE 15 15.1 14.9 15.8 15.9 16.7 15 14 17.5 16.3 16 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 5 NE ND ND NT ND ND ND ND ND ND ND ND NP NP ND Total Arsenic (As)mg/l 5 50 ND ND NT ND ND ND ND ND ND 5.3 81 NP NP ND Total Barium (Ba)mg/l 5 1000 320 100 NT 210 310 130 95 110 1200 270 4900 NP NP ND Total Beryllium (Be)mg/l 1 NE ND ND NT ND ND ND ND ND 2.4 ND 33 NP NP ND Total Cadmium (Cd)mg/l 1 5 ND ND NT ND ND ND ND ND ND ND ND NP NP ND Total Chromium (Cr)mg/l 2 50 30 ND NT ND 6.2 ND ND ND 31 4.6 140 NP NP ND Total Cobalt (Co)mg/l 5 NE 9 ND NT ND ND ND 5.7 ND 52 8.8 110 NP NP ND Total Copper (Cu)mg/l 2 1000 18 ND NT ND 2.3 2.6 ND 3 85 4.4 150 NP NP ND Total Lead (Pb)mg/l 5 15 8.7 12 NT ND ND ND ND ND 39 7.4 640 NP NP ND Total Nickel (Ni)mg/l 5 100 19 ND NT 6.9 6.9 ND ND ND 48 ND 190 NP NP ND Total Selenium (Se)mg/l 5 50 ND ND NT ND ND ND ND ND ND ND ND NP NP ND Total Silver (Ag)mg/l 2 18 ND ND NT ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 10 NE ND ND NT ND ND ND ND ND ND ND ND NP NP ND Total Vanadium (V)mg/l 5 NE 54 ND NT 6.6 16 ND ND ND 92 14 200 NP NP ND Total Zinc (Zn)mg/l 10 2100 55 22 NT 17 26 10 ND ND 140 26 1800 NP NP ND Acetone mg/l 10 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Acrylonitrile mg/l 25 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Benzene mg/l 5 1 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromodichloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromoform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon Disulfide mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon tetrachloride mg/l 5 0.3 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chlorobenzene (mono)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloromethane (Methylchloride)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.025 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichlorobenzene mg/l 5 620 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,4-Dichlorobenzene mg/l 5 75 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,4-Dichloro-2-butene mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethane mg/l 5 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloroethane mg/l 5 0.38 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 5 7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloropropane mg/l 5 0.56 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Ethylbenzene mg/l 5 29 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Hexanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dichloromethane (Methylene chloride)mg/l 5 5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 10 170 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 4-Methyl-2-Pentanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Styrene mg/l 5 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Tetrachloroethene (-ethylene)mg/l 5 0.7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Toluene mg/l 5 1000 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1-Trichloroethane mg/l 5 200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichloroethene (-ethylene)mg/l 5 2.8 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichlorofluoromethane mg/l 5 2100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2,3-Trichloropropane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl acetate mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl chloride mg/l 5 0.015 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Xylene mg/l 5 530 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (10-30-2003) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-20-2004) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.71 6.81 6.78 5.57 5.4 5.47 5.47 5.41 7.36 5.17 6.83 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 25 31 40 67 135 120 115 100 100 115 70 NP NP NT Temperature °C (on-site)-NE 15.8 15.6 15.5 13.5 14.6 14.4 13.5 14.1 15.3 14.9 13.8 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Arsenic (As)mg/l 5 50 ND ND ND ND ND ND ND ND ND 7.4 30 NP NP ND Total Barium (Ba)mg/l 5 1000 320 56 120 410 460 170 140 210 62 940 2000 NP NP ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND 21 NP NP ND Total Cadmium (Cd)mg/l 1 5 ND ND ND ND ND ND ND ND ND 8.8 8.9 NP NP ND Total Chromium (Cr)mg/l 2 50 33 ND 2.1 45 13 ND ND 11 3.5 190 68 NP NP ND Total Cobalt (Co)mg/l 5 NE 9.5 ND ND 7.7 5.2 ND 13 6.4 ND 43 50 NP NP ND Total Copper (Cu)mg/l 2 1000 18 ND 2.8 12 5.3 2.3 4.3 13 7.4 100 89 NP NP ND Total Lead (Pb)mg/l 5 15 7.2 7 5.2 6.4 5.4 ND ND ND 12 39 250 NP NP ND Total Nickel (Ni)mg/l 5 100 20 ND ND 30 7.3 ND ND 12 5.3 49 110 NP NP ND Total Selenium (Se)mg/l 5 50 ND ND ND ND ND 5 ND ND ND ND ND NP NP ND Total Silver (Ag)mg/l 2 18 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Vanadium (V)mg/l 5 NE 55 ND ND 45 25 ND ND 13 5.1 240 88 NP NP ND Total Zinc (Zn)mg/l 10 2100 55 10 ND 44 30 11 14 19 23 220 770 NP NP 11 Acetone mg/l 10 700 ND ND ND ND ND ND ND ND ND ND ND NP NP NT Acrylonitrile mg/l 25 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Benzene mg/l 5 1 ND ND ND ND ND ND ND ND ND ND ND NP NP NT Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Bromodichloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Bromoform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP NT Carbon Disulfide mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Carbon tetrachloride mg/l 5 0.3 ND ND ND ND ND ND ND ND ND ND ND NP NP NT Chlorobenzene (mono)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND ND NP NP NT Chloroethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Chloroform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP NT Chloromethane (Methylchloride)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.025 ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 ND ND ND ND ND ND ND ND ND ND ND NP NP NT Dibromomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,2-Dichlorobenzene mg/l 5 620 ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,4-Dichlorobenzene mg/l 5 75 ND ND ND ND ND ND ND ND ND ND ND NP NP NT trans-1,4-Dichloro-2-butene mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,1-Dichloroethane mg/l 5 700 ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,2-Dichloroethane mg/l 5 0.38 ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,1-Dichloroethene (-ethylene)mg/l 5 7 ND ND ND ND ND ND ND ND ND ND ND NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,2-Dichloropropane mg/l 5 0.56 ND ND ND ND ND ND ND ND ND ND ND NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Ethylbenzene mg/l 5 29 ND ND ND ND ND ND ND ND ND ND ND NP NP NT 2-Hexanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Iodomethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Dichloromethane (Methylene chloride)mg/l 5 5 ND ND ND ND ND ND ND ND ND ND ND NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l 10 170 ND ND ND ND ND ND ND ND ND ND ND NP NP NT 4-Methyl-2-Pentanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Styrene mg/l 5 100 ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,1,2,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Tetrachloroethene (-ethylene)mg/l 5 0.7 ND ND ND ND ND ND ND ND ND ND ND NP NP NT Toluene mg/l 5 1000 ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,1,1-Trichloroethane mg/l 5 200 ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Trichloroethene (-ethylene)mg/l 5 2.8 ND ND ND ND ND ND ND ND ND ND ND NP NP NT Trichlorofluoromethane mg/l 5 2100 ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,2,3-Trichloropropane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Vinyl acetate mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Vinyl chloride mg/l 5 0.015 ND ND ND ND ND ND ND ND ND ND ND NP NP NT Xylene mg/l 5 530 ND ND ND ND ND ND ND ND ND ND ND NP NP NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (4-20-2004) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-21-2004) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.83 6.55 6.76 6.9 5.92 6.39 5.75 6.03 7.84 5.57 7.12 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 29 49 62 96 290 302 196 148 111 198 134 NP NP NT Temperature °C (on-site)-NE 14.3 16.7 14 13 14.7 14.3 15 14.5 14.2 14.6 17 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Arsenic (As)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND 59 NP NP ND Total Barium (Ba)mg/l 5 1000 320 40 200 300 310 140 140 130 12 900 4900 NP NP ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND 1.4 28 NP NP ND Total Cadmium (Cd)mg/l 1 5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Chromium (Cr)mg/l 2 50 21 ND 2.8 16 2 ND ND ND ND 120 140 NP NP ND Total Cobalt (Co)mg/l 5 NE 6.2 ND ND ND ND ND ND ND ND 31 120 NP NP ND Total Copper (Cu)mg/l 2 1000 11 ND ND 2 ND ND ND ND ND 63 140 NP NP ND Total Lead (Pb)mg/l 5 15 7.2 5.6 5.7 ND ND ND ND ND ND 24 430 NP NP ND Total Nickel (Ni)mg/l 5 100 12 ND ND 13 ND ND ND ND ND 35 160 NP NP ND Total Selenium (Se)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Silver (Ag)mg/l 2 18 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Vanadium (V)mg/l 5 NE 41 ND ND 18 ND ND ND ND ND 160 210 NP NP ND Total Zinc (Zn)mg/l 10 2100 29 ND ND 17 ND 14 ND 12 15 70 1200 NP NP ND Acetone mg/l 10 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Acrylonitrile mg/l 25 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Benzene mg/l 5 1 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromodichloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromoform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon Disulfide mg/l 10 NE ND 24 ND ND ND ND ND ND 15 ND ND NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon tetrachloride mg/l 5 0.3 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chlorobenzene (mono)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloromethane (Methylchloride)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.025 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichlorobenzene mg/l 5 620 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,4-Dichlorobenzene mg/l 5 75 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,4-Dichloro-2-butene mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethane mg/l 5 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloroethane mg/l 5 0.38 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 5 7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloropropane mg/l 5 0.56 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Ethylbenzene mg/l 5 29 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Hexanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dichloromethane (Methylene chloride)mg/l 5 5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 10 170 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 4-Methyl-2-Pentanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Styrene mg/l 5 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Tetrachloroethene (-ethylene)mg/l 5 0.7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Toluene mg/l 5 1000 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1-Trichloroethane mg/l 5 200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichloroethene (-ethylene)mg/l 5 2.8 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichlorofluoromethane mg/l 5 2100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2,3-Trichloropropane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl acetate mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl chloride mg/l 5 0.015 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Xylene mg/l 5 530 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (10-21-2004) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-18-2005) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.95 7.44 6.15 6.2 5.58 6.04 6.02 6.18 7.46 5.6 6.85 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 25 40 42 78 330 161 171 139 95 149 138 NP NP NT Temperature °C (on-site)-NE 14.2 15.6 15 13.5 15 17.7 13 13.5 16.2 14.1 16.4 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND 12 NP NP ND Total Arsenic (As)mg/l 5 50 ND ND ND 10 ND ND ND ND ND 5.2 65 NP NP ND Total Barium (Ba)mg/l 5 1000 480 55 160 7200 610 180 160 140 12 1000 3700 NP NP ND Total Beryllium (Be)mg/l 1 NE ND ND ND 7.2 ND ND ND ND ND 3.8 26 NP NP ND Total Cadmium (Cd)mg/l 1 5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Chromium (Cr)mg/l 2 50 49 12 8.3 680 2.9 ND ND 3.2 ND 210 100 NP NP ND Total Cobalt (Co)mg/l 5 NE 12 ND ND 110 ND ND ND ND ND 36 70 NP NP ND Total Copper (Cu)mg/l 2 1000 29 ND ND 240 ND ND ND 3.8 ND 120 130 NP NP ND Total Lead (Pb)mg/l 5 15 13 8 5.2 73 ND ND ND ND ND 39 380 NP NP ND Total Nickel (Ni)mg/l 5 100 29 9.6 17 460 ND ND 5.5 5.4 ND 59 170 NP NP ND Total Selenium (Se)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Silver (Ag)mg/l 2 18 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Vanadium (V)mg/l 5 NE 85 ND ND 680 5.4 ND ND ND ND 240 110 NP NP ND Total Zinc (Zn)mg/l 10 2100 83 ND ND 780 ND 30 13 10 ND 240 1200 NP NP ND Acetone mg/l 25 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Acrylonitrile mg/l 25 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Benzene mg/l 5 1 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromodichloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromoform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon Disulfide mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon tetrachloride mg/l 5 0.3 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chlorobenzene (mono)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloromethane (Methylchloride)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.025 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichlorobenzene mg/l 5 620 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,4-Dichlorobenzene mg/l 5 75 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,4-Dichloro-2-butene mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethane mg/l 5 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloroethane mg/l 5 0.38 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 5 7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloropropane mg/l 5 0.56 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Ethylbenzene mg/l 5 29 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Hexanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dichloromethane (Methylene chloride)mg/l 5 5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 10 170 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 4-Methyl-2-Pentanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Styrene mg/l 5 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Tetrachloroethene (-ethylene)mg/l 5 0.7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Toluene mg/l 5 1000 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1-Trichloroethane mg/l 5 200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichloroethene (-ethylene)mg/l 5 2.8 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichlorofluoromethane mg/l 5 2100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2,3-Trichloropropane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl acetate mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl chloride mg/l 5 0.015 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Xylene mg/l 5 530 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (4-18-2005) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-13-2005) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 7.21 7.38 7.79 6.36 6.07 6.25 6.08 6.6 7.73 6.08 6.72 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 21 35 40 85 580 201 185 160 102 180 52 NP NP NT Temperature °C (on-site)-NE 13.2 14 13.3 13.3 14.9 14.3 16.5 15.5 15.3 16.5 16.8 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Arsenic (As)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND 44 NP NP ND Total Barium (Ba)mg/l 5 1000 770 37 160 1700 870 250 160 140 27 810 2700 NP NP ND Total Beryllium (Be)mg/l 1 NE ND ND ND 3 ND ND ND ND ND 3.4 21 NP NP ND Total Cadmium (Cd)mg/l 1 5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Chromium (Cr)mg/l 2 50 52 ND 3.7 230 4.7 ND ND ND ND 150 88 NP NP ND Total Cobalt (Co)mg/l 5 NE 21 ND ND 32 ND ND 5.1 ND ND 29 56 NP NP ND Total Copper (Cu)mg/l 2 1000 31 2.6 3.5 70 ND ND ND ND 3 82 96 NP NP ND Total Lead (Pb)mg/l 5 15 14 6.9 ND 20 ND ND ND ND ND 29 290 NP NP ND Total Nickel (Ni)mg/l 5 100 29 ND ND 160 6.8 ND ND 6.1 ND 46 100 NP NP ND Total Selenium (Se)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Silver (Ag)mg/l 2 18 2.9 ND ND ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 10 NE 22 ND ND ND ND ND ND ND ND ND ND NP NP ND Total Vanadium (V)mg/l 5 NE 82 ND ND 210 8.9 ND ND ND ND 170 82 NP NP ND Total Zinc (Zn)mg/l 10 2100 92 13 12 230 19 25 ND ND 14 170 800 NP NP ND Acetone mg/l 25 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Acrylonitrile mg/l 25 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Benzene mg/l 5 1 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromodichloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromoform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon Disulfide mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon tetrachloride mg/l 5 0.3 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chlorobenzene (mono)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloromethane (Methylchloride)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.025 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichlorobenzene mg/l 5 620 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,4-Dichlorobenzene mg/l 5 75 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,4-Dichloro-2-butene mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethane mg/l 5 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloroethane mg/l 5 0.38 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 5 7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloropropane mg/l 5 0.56 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Ethylbenzene mg/l 5 29 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Hexanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dichloromethane (Methylene chloride)mg/l 5 5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 10 170 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 4-Methyl-2-Pentanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Styrene mg/l 5 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Tetrachloroethene (-ethylene)mg/l 5 0.7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Toluene mg/l 5 1000 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1-Trichloroethane mg/l 5 200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichloroethene (-ethylene)mg/l 5 2.8 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichlorofluoromethane mg/l 5 2100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2,3-Trichloropropane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl acetate mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl chloride mg/l 5 0.015 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Xylene mg/l 5 530 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (10-13-2005) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-25-2006) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.33 7.06 6.61 6.07 5.45 6.16 5.63 5.62 7.7 5.56 5.83 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 53 48 52 106 105 383 301 236 136 251 70 NP NP NT Temperature °C (on-site)-NE 18.1 19.2 16.1 13.7 19.5 20.6 12.4 13.8 14.6 14.8 12.9 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 30 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Arsenic (As)mg/l 10 50 ND ND ND ND ND ND ND ND ND ND 42 NP NP ND Total Barium (Ba)mg/l 500 2000 650 ND ND ND 1100 ND ND ND ND 750 2700 NP NP ND Total Beryllium (Be)mg/l 2 NE ND ND ND ND ND ND ND ND 2.1 ND 17 NP NP ND Total Cadmium (Cd)mg/l 1 1.75 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Chromium (Cr)mg/l 10 50 65 ND 16 ND ND ND ND ND 16 100 93 NP NP ND Total Cobalt (Co)mg/l 10 NE 16 ND ND ND ND ND ND ND ND 25 57 NP NP ND Total Copper (Cu)mg/l 200 1000 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Lead (Pb)mg/l 10 15 15 ND ND ND ND ND ND ND 53 19 300 NP NP ND Total Nickel (Ni)mg/l 50 100 ND ND ND ND ND ND ND ND ND ND 88 NP NP ND Total Selenium (Se)mg/l 20 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Silver (Ag)mg/l 10 17.5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Vanadium (V)mg/l 40 NE 110 ND ND ND ND ND ND ND ND 120 85 NP NP ND Total Zinc (Zn)mg/l 50 1050 130 ND 88 ND ND ND ND ND 110 120 780 NP NP ND Acetone mg/l 25 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Acrylonitrile mg/l 25 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Benzene mg/l 5 1 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromodichloromethane mg/l 5 0.56 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromoform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon Disulfide mg/l 10 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon tetrachloride mg/l 5 0.269 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chlorobenzene (mono)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroethane mg/l 10 2800 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroform mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloromethane (Methylchloride)mg/l 5 2.6 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.025 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.00047 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichlorobenzene mg/l 5 24 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,4-Dichlorobenzene mg/l 5 1.4 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,4-Dichloro-2-butene mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethane mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloroethane mg/l 5 0.38 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 5 7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 5 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloropropane mg/l 5 0.51 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Ethylbenzene mg/l 5 550 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Hexanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dichloromethane (Methylene chloride)mg/l 5 4.6 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 10 4200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 4-Methyl-2-Pentanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Styrene mg/l 5 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Tetrachloroethene (-ethylene)mg/l 5 0.7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Toluene mg/l 5 1000 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1-Trichloroethane mg/l 5 200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichloroethene (-ethylene)mg/l 5 2.8 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichlorofluoromethane mg/l 5 2100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2,3-Trichloropropane mg/l 5 0.005 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl acetate mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl chloride mg/l 5 0.015 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Xylene mg/l 5 530 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (4-25-2006) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-20-2006) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.47 6.81 6.51 6.74 5.56 6.14 5.87 5.74 8.2 5.61 5.97 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 229 48 53 108 876 564 149 200 12.8 330 33 NP NP NT Temperature °C (on-site)-NE 12.2 11.9 12.8 12.5 12.7 12.9 14.9 13.7 13.5 13.3 14.9 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Arsenic (As)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND 13 NP NP ND Total Barium (Ba)mg/l 5 2000 410 22 180 470 1100 ND ND ND 160 ND 650 NP NP ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND 5.7 NP NP ND Total Cadmium (Cd)mg/l 1 1.75 3.8 ND ND ND ND ND ND ND 1.5 ND 5.2 NP NP ND Total Chromium (Cr)mg/l 5 50 50 ND 11 24 ND ND ND ND 17 ND 27 NP NP ND Total Cobalt (Co)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Copper (Cu)mg/l 5 1000 26 ND ND 9.6 ND ND ND ND 20 ND 25 NP NP ND Total Lead (Pb)mg/l 5 15 20 ND ND ND ND ND ND ND 32 ND 89 NP NP ND Total Nickel (Ni)mg/l 5 100 22 ND 8.3 25 ND ND ND ND 13 ND 24 NP NP ND Total Selenium (Se)mg/l 10 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Silver (Ag)mg/l 5 17.5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Vanadium (V)mg/l 5 NE 79 ND ND 28 ND ND ND ND 23 ND 30 NP NP ND Total Zinc (Zn)mg/l 10 1050 74 ND 20 37 ND ND ND ND 55 ND 200 NP NP ND Acetone mg/l 25 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Acrylonitrile mg/l 25 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Benzene mg/l 5 1 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromodichloromethane mg/l 5 0.56 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromoform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon Disulfide mg/l 10 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon tetrachloride mg/l 5 0.269 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chlorobenzene (mono)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroethane mg/l 10 2800 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroform mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloromethane (Methylchloride)mg/l 5 2.6 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.025 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.00047 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichlorobenzene mg/l 5 24 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,4-Dichlorobenzene mg/l 5 1.4 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,4-Dichloro-2-butene mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethane mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloroethane mg/l 5 0.38 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 5 7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 5 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloropropane mg/l 5 0.51 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Ethylbenzene mg/l 5 550 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Hexanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dichloromethane (Methylene chloride)mg/l 5 4.6 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 10 4200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 4-Methyl-2-Pentanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Styrene mg/l 5 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Tetrachloroethene (-ethylene)mg/l 5 0.7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Toluene mg/l 5 1000 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1-Trichloroethane mg/l 5 200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichloroethene (-ethylene)mg/l 5 2.8 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichlorofluoromethane mg/l 10 2100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2,3-Trichloropropane mg/l 5 0.005 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl acetate mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl chloride mg/l 5 0.015 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Xylene mg/l 5 530 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (10-20-2006) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-25-2007) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.04 7.08 6.27 6.25 5.36 5.83 5.7 5.73 8.02 5.54 9.08 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 31 50 54 105 1540 757 391 312 134 336 46 NP NP NT Temperature °C (on-site)-NE 13.4 14.2 14 13 14 14.6 14 13 15.7 15.4 12.5 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 6 NE ND ND ND ND ND 20 ND ND ND ND ND NP NP ND Total Arsenic (As)mg/l 5 50 ND ND ND ND ND 280 ND ND ND ND 12 NP NP ND Total Barium (Ba)mg/l 100 2000 290 ND 200 240 1300 1500 130 180 ND ND 600 NP NP ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND 14 ND ND ND ND 4.9 NP NP ND Total Cadmium (Cd)mg/l 1 1.75 ND ND ND ND ND 2.2 ND ND ND ND ND NP NP ND Total Chromium (Cr)mg/l 10 50 20 ND ND 16 ND 410 ND ND ND ND 17 NP NP ND Total Cobalt (Co)mg/l 10 NE ND ND ND ND ND 260 ND ND ND ND ND NP NP ND Total Copper (Cu)mg/l 10 1000 15 ND ND ND ND 330 ND ND ND ND 26 NP NP ND Total Lead (Pb)mg/l 10 15 ND ND ND ND ND 96 ND ND ND ND 69 NP NP ND Total Nickel (Ni)mg/l 50 100 ND ND ND ND ND 330 ND ND ND ND ND NP NP ND Total Selenium (Se)mg/l 10 50 12 ND ND ND ND 460 ND ND ND ND 18 NP NP ND Total Silver (Ag)mg/l 10 17.5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 5.5 NE ND ND ND ND ND 35 ND ND ND ND ND NP NP ND Total Vanadium (V)mg/l 25 NE 43 ND ND ND ND 300 ND ND ND ND 26 NP NP ND Total Zinc (Zn)mg/l 10 1050 55 21 30 30 22 830 22 15 10 12 200 NP NP 12 Acetone mg/l 25 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Acrylonitrile mg/l 25 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Benzene mg/l 5 1 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromodichloromethane mg/l 5 0.56 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromoform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon Disulfide mg/l 10 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon tetrachloride mg/l 5 0.269 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chlorobenzene (mono)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroethane mg/l 10 2800 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroform mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloromethane (Methylchloride)mg/l 5 2.6 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.025 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.00047 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichlorobenzene mg/l 5 24 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,4-Dichlorobenzene mg/l 5 1.4 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,4-Dichloro-2-butene mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethane mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloroethane mg/l 5 0.38 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 5 7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 5 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloropropane mg/l 5 0.51 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Ethylbenzene mg/l 5 550 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Hexanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dichloromethane (Methylene chloride)mg/l 5 4.6 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 10 4200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 4-Methyl-2-Pentanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Styrene mg/l 5 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Tetrachloroethene (-ethylene)mg/l 5 0.7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Toluene mg/l 5 1000 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1-Trichloroethane mg/l 5 200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichloroethene (-ethylene)mg/l 5 2.8 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichlorofluoromethane mg/l 10 2100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2,3-Trichloropropane mg/l 5 0.005 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl acetate mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl chloride mg/l 5 0.015 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Xylene mg/l 5 530 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (4-25-2007) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-31-2007) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.6 6.8 6.3 6.22 5.9 6 5.5 5.9 7.99 5.5 5.9 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 28 61 45 94 1475 911 346 300 132 543 36 NP NP NT Temperature °C (on-site)-NE 13.8 16 16.1 14.8 17.5 17.6 17.5 17.2 14.8 15.6 17.2 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Arsenic (As)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND 21.4 NP NP ND Total Barium (Ba)mg/l 5 2000 501 31.5 223 198 1350 591 184 208 62.4 516 872 NP NP ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND 6 NP NP ND Total Cadmium (Cd)mg/l 1 1.75 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Chromium (Cr)mg/l 5 50 40.9 ND 11.9 10.9 7.8 ND ND ND 5.1 75.5 33.7 NP NP ND Total Cobalt (Co)mg/l 5 NE 16.8 ND ND ND 10.6 ND ND ND ND ND 17.6 NP NP ND Total Copper (Cu)mg/l 5 1000 29.2 ND ND ND ND ND ND ND 6.3 40.3 47.4 NP NP ND Total Lead (Pb)mg/l 5 15 17.5 8.1 ND ND ND ND ND ND ND 12.3 123 NP NP ND Total Nickel (Ni)mg/l 5 100 24 ND 8 8.4 13.8 ND 5.8 9.8 ND 20.2 36.2 NP NP ND Total Selenium (Se)mg/l 10 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Silver (Ag)mg/l 5 17.5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 5.5 NE 11.6 ND ND ND ND ND ND ND ND 9.5 ND NP NP ND Total Vanadium (V)mg/l 5 NE 89 ND 8.8 14.7 20 ND ND ND 8.6 103 48.2 NP NP ND Total Zinc (Zn)mg/l 10 1050 86 ND 66.2 14 37.4 33.3 12 ND 11.6 91.1 336 NP NP ND Acetone mg/l 25 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromodichloromethane mg/l 1 0.56 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromoform mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon tetrachloride mg/l 1 0.269 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroethane mg/l 1 2800 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloromethane (Methylchloride)mg/l 1 2.6 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 0.025 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.00047 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichlorobenzene mg/l 1 24 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,4-Dichlorobenzene mg/l 1 1.4 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethane mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloroethane mg/l 1 0.38 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloropropane mg/l 1 0.51 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Ethylbenzene mg/l 1 550 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dichloromethane (Methylene chloride)mg/l 2 4.6 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Styrene mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Toluene mg/l 1 1000 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichloroethene (-ethylene)mg/l 1 2.8 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichlorofluoromethane mg/l 1 2100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl chloride mg/l 1 0.015 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Xylenes mg/l 2 530 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (10-31-2007) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (04-23-2008) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.59 7.22 6.58 6.33 5.71 6.05 5.66 5.65 8.13 5.56 6.69 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 25 49 49 102 1546 946 411 318 124 481 33 NP NP NT Temperature °C (on-site)-NE 13.9 14.2 14.2 13.2 14.6 14.4 13.4 14.7 17.4 14.8 14.1 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Arsenic (As)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND 10.2 NP NP ND Total Barium (Ba)mg/l 5 2000 194 30.8 253 168 1230 661 216 202 61.8 151 361 NP NP ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND 3 NP NP ND Total Cadmium (Cd)mg/l 1 1.75 ND ND ND ND ND ND ND ND ND ND 1.6 NP NP ND Total Chromium (Cr)mg/l 5 50 10.7 ND 16.8 7.8 ND ND ND ND 7.6 7.3 14.9 NP NP ND Total Cobalt (Co)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND 22.3 NP NP ND Total Copper (Cu)mg/l 5 1000 7.2 ND ND ND ND ND ND ND 7.2 ND 17 NP NP ND Total Lead (Pb)mg/l 5 15 ND ND 8.4 ND ND ND ND ND 5.8 ND 50.2 NP NP ND Total Nickel (Ni)mg/l 5 100 7.3 ND 12.9 6.3 10.8 5.7 ND 11.3 5.3 ND 19 NP NP ND Total Selenium (Se)mg/l 10 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Silver (Ag)mg/l 5 17.5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 5.5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Vanadium (V)mg/l 5 NE 26.1 ND 11.4 9.7 10.1 ND ND 5.1 9.7 10 23.1 NP NP ND Total Zinc (Zn)mg/l 10 1050 27.3 ND 50.3 12.2 24.4 36.9 ND 10.3 17.5 38.8 138 NP NP ND Acetone mg/l 25 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromodichloromethane mg/l 1 0.56 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromoform mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon tetrachloride mg/l 1 0.269 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroethane mg/l 1 2800 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloromethane (Methylchloride)mg/l 1 2.6 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 0.025 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.00047 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichlorobenzene mg/l 1 24 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,4-Dichlorobenzene mg/l 1 1.4 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethane mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloroethane mg/l 1 0.38 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloropropane mg/l 1 0.51 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Ethylbenzene mg/l 1 550 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dichloromethane (Methylene chloride)mg/l 2 4.6 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Styrene mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Toluene mg/l 1 1000 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichloroethene (-ethylene)mg/l 1 2.8 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichlorofluoromethane mg/l 1 2100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl chloride mg/l 1 0.015 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Xylenes mg/l 2 530 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (04-23-2008) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-20-2008) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 5.7 6.7 6.2 6.1 5.9 6.0 5.9 5.8 7.9 5.6 5.5 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 28.0 54.0 44.0 104 1420 1111 320 350.0 129.0 621.0 41.0 NP NP NT Temperature °C (on-site)-NE 13.8 14.2 12.0 13.2 14.3 15.4 14.9 14.6 15.2 14.5 16.5 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Arsenic (As)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND 6.6 NP NP ND Total Barium (Ba)mg/l 5 2000 474 66.0 313 224 1210 894 164 216 41.1 182 245 NP NP ND Total Beryllium (Be)mg/l 1 NE ND 1.2 ND ND ND ND ND ND ND ND 1.9 NP NP ND Total Cadmium (Cd)mg/l 1 1.75 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Chromium (Cr)mg/l 5 50 38.6 ND 29.4 12.7 ND ND ND ND ND ND 6.8 NP NP ND Total Cobalt (Co)mg/l 5 NE 27.0 10.4 19.5 9.4 7.7 ND 12.6 5.3 7.1 ND 18.4 NP NP ND Total Copper (Cu)mg/l 5 1000 26.5 ND 8.3 ND ND ND ND ND ND ND 9.7 NP NP ND Total Lead (Pb)mg/l 5 15 ND 13.5 7.6 ND ND ND ND ND ND ND 25.9 NP NP ND Total Nickel (Ni)mg/l 5 100 23.0 ND 21.0 11.1 10.7 7.5 ND 14.0 ND ND 8.5 NP NP ND Total Selenium (Se)mg/l 10 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Silver (Ag)mg/l 5 17.5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 5.4 NE 7.2 ND ND ND ND ND ND 6.1 ND ND ND NP NP ND Total Vanadium (V)mg/l 5 NE 79.0 ND 15.1 15.8 ND ND ND ND 5.4 ND 14.8 NP NP ND Total Zinc (Zn)mg/l 10 1050 66.5 19.9 59.2 15.3 10.6 29.1 ND 12.4 ND 17.4 71.5 NP NP ND Acetone mg/l 25 700 ND ND ND ND ND ND ND ND ND ND 140 NP NP ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromodichloromethane mg/l 1 0.56 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromoform mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon tetrachloride mg/l 1 0.269 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroethane mg/l 1 2800 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloromethane (Methylchloride)mg/l 1 2.6 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 0.025 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.00047 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichlorobenzene mg/l 1 24 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,4-Dichlorobenzene mg/l 1 1.4 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethane mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloroethane mg/l 1 0.38 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloropropane mg/l 1 0.51 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Ethylbenzene mg/l 1 550 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dichloromethane (Methylene chloride)mg/l 2 4.6 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4200 ND ND ND ND ND ND ND ND ND ND 54.4 NP NP ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Styrene mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Toluene mg/l 1 1000 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichloroethene (-ethylene)mg/l 1 2.8 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichlorofluoromethane mg/l 1 2100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl chloride mg/l 1 0.015 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Xylenes mg/l 2 530 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (10-20-2008) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-22-2009) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 5.64 6.89 6.32 5.83 5.74 5.92 5.75 5.72 7.56 5.47 NS NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 28.0 53.0 12.0 131 1427 1109 398 358 131 536.0 NS NP NP NT Temperature °C (on-site)-NE 13.3 13.1 47 13.4 12.8 13.1 11.7 12.1 14.4 15.1 NS NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NS NP NP NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND Total Arsenic (As)mg/l 5 50 ND ND 5.4 ND ND 5.6 ND ND ND ND NS NP NP ND Total Barium (Ba)mg/l 5 2000 126 47.2 591 309 1300 817 230 216 77.0 163 NS NP NP ND Total Beryllium (Be)mg/l 1 NE ND ND 1.5 ND ND ND ND ND ND ND NS NP NP ND Total Cadmium (Cd)mg/l 1 1.75 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Total Chromium (Cr)mg/l 5 50 12.3 ND 28.9 19.7 5.1 ND ND ND 7.3 ND NS NP NP ND Total Cobalt (Co)mg/l 5 NE 5.0 6.3 17.1 8.5 5.7 ND 7.0 ND 6.4 ND NS NP NP ND Total Copper (Cu)mg/l 5 1000 5.1 ND 22.6 6.0 ND ND ND ND 8.8 ND NS NP NP ND Total Lead (Pb)mg/l 5 15 ND 8.7 24.4 ND ND ND ND ND 9.8 ND NS NP NP ND Total Nickel (Ni)mg/l 5 100 5.6 7.2 19.7 16.7 10.9 6.0 5.1 14.0 6.0 ND NS NP NP ND Total Selenium (Se)mg/l 10 50 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Total Silver (Ag)mg/l 5 17.5 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND Total Vanadium (V)mg/l 5 NE 16.0 ND 32.7 19.8 7.7 ND ND ND 13.3 ND NS NP NP ND Total Zinc (Zn)mg/l 10 1050 23.1 43.5 99.9 25.3 17.9 17.6 10.5 ND 35.2 ND NS NP NP ND Acetone mg/l 25 700 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND Bromodichloromethane mg/l 1 0.56 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Bromoform mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND 4.5 ND NS NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND Carbon tetrachloride mg/l 1 0.269 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Chloroethane mg/l 1 2800 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Chloromethane (Methylchloride)mg/l 1 2.6 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 0.025 ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.00047 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,2-Dichlorobenzene mg/l 1 24 ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,4-Dichlorobenzene mg/l 1 1.4 ND ND ND ND ND ND ND ND ND ND NS NP NP ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,1-Dichloroethane mg/l 1 70 ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,2-Dichloroethane mg/l 1 0.38 ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND NS NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND NS NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,2-Dichloropropane mg/l 1 0.51 ND ND ND ND ND ND ND ND ND ND NS NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND NS NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Ethylbenzene mg/l 1 550 ND ND ND ND ND ND ND ND ND ND NS NP NP ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND Dichloromethane (Methylene chloride)mg/l 2 4.6 ND ND ND ND ND ND ND ND ND ND NS NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4200 ND ND ND ND ND ND ND ND ND ND NS NP NP ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND Styrene mg/l 1 100 ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Toluene mg/l 1 1000 ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND Trichloroethene (-ethylene)mg/l 1 2.8 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Trichlorofluoromethane mg/l 1 2100 ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND Vinyl chloride mg/l 1 0.015 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Xylenes mg/l 2 530 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (4-22-2009) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-26-2009) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 5.88 6.35 6.0 5.76 5.78 5.95 NS NS NS 5.32 5.30 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 29 50 37.0 127 1532 1120 NS NS NS 637 39 NP NP NT Temperature °C (on-site)-NE 13.4 13.2 14.4 14.6 14.7 15.9 NS NS NS 14.5 15.3 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NS NS NS NT NT NP NP NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND Total Arsenic (As)mg/l 5 50 ND ND ND ND 6.0 ND NS NS NS ND ND NP NP ND Total Barium (Ba)mg/l 5 2000 131 16.8 144 188 1720 987 NS NS NS 209 178 NP NP ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND NS NS NS ND 1.7 NP NP ND Total Cadmium (Cd)mg/l 1 1.75 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Total Chromium (Cr)mg/l 5 50 10.0 ND 8.1 ND 18.7 ND NS NS NS 10.9 8.1 NP NP ND Total Cobalt (Co)mg/l 5 NE ND ND ND ND 6.0 ND NS NS NS ND 6.0 NP NP ND Total Copper (Cu)mg/l 5 1000 5.8 ND ND ND 6.4 ND NS NS NS ND 7.1 NP NP ND Total Lead (Pb)mg/l 5 15 ND ND ND ND ND ND NS NS NS ND 24.7 NP NP ND Total Nickel (Ni)mg/l 5 100 6.7 ND 5.2 6.0 18.0 7.5 NS NS NS 6.0 8.4 NP NP ND Total Selenium (Se)mg/l 10 50 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Total Silver (Ag)mg/l 5 17.5 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND Total Vanadium (V)mg/l 5 NE 17.9 ND ND 5.3 33.6 ND NS NS NS 12.2 11.9 NP NP ND Total Zinc (Zn)mg/l 10 1050 19.6 ND 14.8 ND 37.8 ND NS NS NS ND 63.8 NP NP ND Acetone mg/l 25 700 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND Benzene mg/l 1 1 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND Bromodichloromethane mg/l 1 0.56 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Bromoform mg/l 1 0.19 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND Carbon tetrachloride mg/l 1 0.269 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Chloroethane mg/l 1 2800 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Chloroform mg/l 1 70 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Chloromethane (Methylchloride)mg/l 1 2.6 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 0.025 ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.00047 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,2-Dichlorobenzene mg/l 1 24 ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,4-Dichlorobenzene mg/l 1 1.4 ND ND ND ND ND ND NS NS NS ND ND NP NP ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,1-Dichloroethane mg/l 1 70 ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,2-Dichloroethane mg/l 1 0.38 ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND NS NS NS ND ND NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND NS NS NS ND ND NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,2-Dichloropropane mg/l 1 0.51 ND ND ND ND ND ND NS NS NS ND ND NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND NS NS NS ND ND NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Ethylbenzene mg/l 1 550 ND ND ND ND ND ND NS NS NS ND ND NP NP ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND Iodomethane mg/l 5 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND Dichloromethane (Methylene chloride)mg/l 2 4.6 ND ND ND ND ND ND NS NS NS ND ND NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4200 ND ND ND ND ND ND NS NS NS ND ND NP NP ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND Styrene mg/l 1 100 ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Toluene mg/l 1 1000 ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND Trichloroethene (-ethylene)mg/l 1 2.8 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Trichlorofluoromethane mg/l 1 2100 ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND Vinyl chloride mg/l 1 0.015 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Xylenes mg/l 2 530 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (10-26-2009) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-22-2010) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.05 6.54 6.33 6.06 5.90 5.94 NS NS 7.04 5.50 5.69 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 65 96 8.2 161 1987 1812 NS NS 1727 659 83 NP NP NT Temperature °C (on-site)-NE 13.5 13.8 13.9 13.5 13.3 13.4 NS NS 14.9 14.6 12.7 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NS NS NT NT NT NP NP NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND Total Arsenic (As)mg/l 5 50 ND ND ND ND 7.4 9.8 NS NS ND ND ND NP NP ND Total Barium (Ba)mg/l 5 2000 208 43.5 153 157 1920 1380 NS NS 20.9 150 74.8 NP NP ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND Total Cadmium (Cd)mg/l 1 1.75 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Total Chromium (Cr)mg/l 5 50 14.3 10.9 13.1 ND ND ND NS NS ND ND ND NP NP ND Total Cobalt (Co)mg/l 5 NE 5.6 ND ND ND ND ND NS NS ND ND ND NP NP ND Total Copper (Cu)mg/l 5 1000 9.9 ND ND ND ND 5.9 NS NS ND ND ND NP NP ND Total Lead (Pb)mg/l 5 15 ND 10.5 ND ND ND ND NS NS ND ND 9.2 NP NP ND Total Nickel (Ni)mg/l 5 100 8.6 9.6 7.6 ND 6.2 ND NS NS ND ND ND NP NP ND Total Selenium (Se)mg/l 10 50 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Total Silver (Ag)mg/l 5 17.5 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND Total Vanadium (V)mg/l 5 NE 27.9 ND ND ND ND ND NS NS ND ND ND NP NP ND Total Zinc (Zn)mg/l 10 1050 22.2 14.2 ND ND ND ND NS NS ND ND 24.6 NP NP ND Acetone mg/l 25 700 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND Benzene mg/l 1 1 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND Bromodichloromethane mg/l 1 0.56 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Bromoform mg/l 1 0.19 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND Carbon tetrachloride mg/l 1 0.269 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Chloroethane mg/l 1 2800 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Chloroform mg/l 1 70 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Chloromethane (Methylchloride)mg/l 1 2.6 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 0.025 ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.00047 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,2-Dichlorobenzene mg/l 1 24 ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,4-Dichlorobenzene mg/l 1 1.4 ND ND ND ND ND ND NS NS ND ND ND NP NP ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,1-Dichloroethane mg/l 1 70 ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,2-Dichloroethane mg/l 1 0.38 ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND NS NS ND ND ND NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND NS NS ND ND ND NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,2-Dichloropropane mg/l 1 0.51 ND ND ND ND ND ND NS NS ND ND ND NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND NS NS ND ND ND NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Ethylbenzene mg/l 1 550 ND ND ND ND ND ND NS NS ND ND ND NP NP ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND Iodomethane mg/l 5 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND Dichloromethane (Methylene chloride)mg/l 2 4.6 ND ND ND ND ND ND NS NS ND ND ND NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4200 ND ND ND ND ND ND NS NS ND ND ND NP NP ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND Styrene mg/l 1 100 ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Toluene mg/l 1 1000 ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND Trichloroethene (-ethylene)mg/l 1 2.8 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Trichlorofluoromethane mg/l 1 2100 ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND Vinyl chloride mg/l 1 0.015 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Xylenes mg/l 2 530 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (4-22-2010) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-27-2010) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3R MW-3DR MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 5.33 6.38 6.06 5.69 5.72 5.96 5.43 5.65 7.36 5.29 5.44 5.65 5.82 NT Specific Conductance mmhos/cm (on-site)1 NE 35 52 54 113 189 177 418 317 140 772 46 221 90 NT Temperature °C (on-site)-NE 13.7 14.1 14.1 13.9 13.9 14.7 15.2 15.0 15.7 14.7 16.5 15.9 15.0 NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 5 50 ND ND ND ND 5.4 5.9 ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 2000 147 15.8 162 178 1760 1550 531 234 20.0 190 111 191 84.4 ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 1.75 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 10.1 ND 6.6 7.1 ND ND 12.0 9.2 ND ND 5.2 ND ND ND Total Cobalt (Co)mg/l 5 NE ND ND ND ND ND ND 17.3 5.6 ND ND 7.8 29.6 ND ND Total Copper (Cu)mg/l 5 1000 6.7 ND ND ND ND ND ND 12.4 ND ND 53.9 ND ND ND Total Lead (Pb)mg/l 5 15 ND ND ND ND ND ND ND ND ND ND 16.0 ND ND ND Total Nickel (Ni)mg/l 5 100 7.0 ND ND ND 7.4 ND 21.5 19.0 ND ND 7.5 10.8 ND ND Total Selenium (Se)mg/l 10 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 17.5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE 17.4 ND ND 6.9 ND ND 14.2 7.1 ND ND 5.9 ND ND ND Total Zinc (Zn)mg/l 10 1050 19.1 ND 12.3 15.0 ND ND 32.4 16.3 ND ND 60.7 ND ND ND Acetone mg/l 25 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 0.56 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 0.269 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1 2800 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 2.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.025 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.00047 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 24 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 1.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 0.38 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 0.51 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1 550 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 4.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene mg/l 1 1000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 2.8 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 2100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1 0.015 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Xylenes mg/l 2 530 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (10-27-2010) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-29-2011) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3R MW-3DR MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.00 6.50 6.50 6.10 5.80 6.00 5.60 5.60 6.20 5.40 5.70 5.60 5.60 NT Specific Conductance mmhos/cm (on-site)1 NE 29 50 53 127 1770 1593 491 290 135 762 90 197 125 NT Temperature °C (on-site)-NE 14.3 14.6 13.7 13.2 14.5 14.7 15.3 14.5 14.8 14.4 13.2 15.2 14.8 NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 700 191 16.3 188 182 1620 1390 428 173 13.6 196 125 201 133.0 ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND 1.1 ND ND ND Total Cadmium (Cd)mg/l 1 2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 10 8.0 ND 8.6 ND ND ND ND ND ND ND ND ND ND ND Total Cobalt (Co)mg/l 5 NE ND ND ND ND 6.9 ND 8.9 ND ND ND ND 26.3 ND ND Total Copper (Cu)mg/l 5 1000 6.4 ND ND ND 6.7 6.1 ND ND ND ND 5.2 ND ND ND Total Lead (Pb)mg/l 5 15 ND ND ND ND ND ND ND ND ND ND 11.0 ND ND ND Total Nickel (Ni)mg/l 5 100 ND ND ND ND 10.5 8.6 19.5 15.2 ND ND ND 10.3 ND ND Total Selenium (Se)mg/l 10 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE 15.8 ND 5.1 ND ND ND ND ND ND ND 5.5 7.3 ND ND Total Zinc (Zn)mg/l 10 1000 25.7 ND 21.9 ND 11.8 23.9 13.7 ND ND ND 42.9 20.5 21.5 ND Acetone mg/l 25 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1 4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 0.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1 3000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.02 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 2000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1 0.03 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Xylenes mg/l 2 500 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (4-29-2011) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-25-2011) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3R MW-3DR MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.50 6.20 6.40 6.10 5.60 5.40 5.40 5.30 7.00 5.20 5.60 5.60 5.80 NT Specific Conductance mmhos/cm (on-site)1 NE 32 47 46 108 1275 1450 395 297 137 802 52 245 145 NT Temperature °C (on-site)-NE 14.2 13.5 15.3 12.4 13.2 13.7 15.8 15.1 15.7 16.2 16.9 16.3 15.6 NT Turbidity NTU (on-site)NT NE 96.5 8.09 17.7 9.06 9.22 1.78 8.72 5.24 1.91 80.5 154.0 4.62 1.77 NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 700 185 19.7 120 332 1200 1300 945 205 8.2 238 123 161 154 ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND 1.6 ND ND ND Total Cadmium (Cd)mg/l 1 2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 10 15.0 ND ND 21.1 ND ND 8.1 ND ND 9.2 5.1 ND ND ND Total Cobalt (Co)mg/l 5 NE 5.3 ND ND 6.4 6.3 ND 21.0 ND ND ND ND 42.4 ND ND Total Copper (Cu)mg/l 5 1000 9.6 ND ND 9.4 6.8 11.2 7.6 ND ND 5.1 6.9 ND ND ND Total Lead (Pb)mg/l 5 15 ND ND ND ND ND ND 6.3 ND ND ND 14.6 ND ND ND Total Nickel (Ni)mg/l 5 100 6.9 ND ND 14.7 8.8 7.5 20.8 19.9 ND ND ND 8.0 ND ND Total Selenium (Se)mg/l 10 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE 25.6 ND ND 23.0 ND ND 15.1 ND ND 9.7 6.3 ND ND ND Total Zinc (Zn)mg/l 10 1000 34.5 ND 11.6 23.7 12.8 10.1 32.5 ND ND 17.7 49.9 15.1 ND ND Acetone mg/l 25 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1 4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 0.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1 3000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.02 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 2000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1 0.03 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Xylenes mg/l 2 500 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (10-25-2011) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-20-2012) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3R MW-3DR MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.4 6.9 6.6 6.3 6.2 6.1 5.7 5.8 8.3 5.5 5.8 6.0 6.0 NT Specific Conductance mmhos/cm (on-site)1 NE 29.1 48.1 45.5 112.2 1339 1397 508 341 140 845 61.4 284.3 165.9 NT Temperature °C (on-site)-NE 13.5 13.9 13.6 14.0 14.9 14.7 15.9 14.2 15.1 15.2 14.0 15.9 14.9 NT Turbidity NTU (on-site)NT NE 90 48.1 11.5 4.28 3.53 2.50 14.70 3.63 4.36 2.21 70.0 21.10 1.75 NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 700 304 17.5 129 153 1020 1140 442 215 9.5 232 64.8 249 169 ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 2 ND ND ND ND ND ND ND ND ND ND ND 4.8 ND ND Total Chromium (Cr)mg/l 5 10 24.5 ND ND 5.1 ND ND 7.9 ND ND ND ND 12.3 ND ND Total Cobalt (Co)mg/l 5 NE 6.9 ND ND ND ND ND 6.4 ND ND ND ND 134.0 ND ND Total Copper (Cu)mg/l 5 1000 15.6 ND ND ND 5.8 5.2 ND ND ND ND ND 6.5 ND ND Total Lead (Pb)mg/l 5 15 ND ND ND ND ND ND ND ND ND ND 6.4 ND ND ND Total Nickel (Ni)mg/l 5 100 12.2 ND ND ND 9.4 9.4 23.8 24.6 ND ND ND 19.3 ND ND Total Selenium (Se)mg/l 10 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE 44.3 ND ND ND ND ND 10.0 ND ND ND ND 15.0 ND ND Total Zinc (Zn)mg/l 10 1000 47.6 ND 12.5 ND 11.6 10.1 21.1 ND ND 11.1 30.7 50.8 ND ND Acetone mg/l 25 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1 4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 0.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1 3000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.02 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 2000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1 0.03 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Xylenes mg/l 2 500 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (4-20-2012) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-24-2012) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3R MW-3DR MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.3 6.8 6.3 6.3 6.1 6.0 5.6 5.7 8.1 5.3 5.6 5.9 5.8 NT Specific Conductance mmhos/cm (on-site)1 NE 28.0 49.0 49.0 122.0 1200 1332 540 395 140 867 50.0 260.0 171.0 NT Temperature °C (on-site)-NE 14.4 13.3 12.5 16.5 15.3 15.2 15.6 15.2 15.3 15.4 16.1 15.9 15.7 NT Turbidity NTU (on-site)NT NE 921 3.2 9.2 8.64 5.54 2.67 6.39 4.52 10.31 2.50 56.0 2.82 2.23 NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 700 389 19.0 124 167 889 1030 393 229 26.1 235 43.2 177 181 ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 2 ND ND ND ND ND ND ND ND ND ND ND 1.0 ND ND Total Chromium (Cr)mg/l 5 10 30.4 6.0 ND 6.4 ND ND ND ND ND ND ND ND ND ND Total Cobalt (Co)mg/l 5 NE 15.7 ND ND ND 5.6 ND 6.5 ND ND ND ND 48.5 ND ND Total Copper (Cu)mg/l 5 1000 22.7 ND ND ND 6.0 ND ND ND 5.1 ND ND ND ND ND Total Lead (Pb)mg/l 5 15 5.9 ND ND ND ND ND ND ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 100 18.5 ND ND ND 10.1 8.9 20.0 25.3 ND ND ND 9.6 ND ND Total Selenium (Se)mg/l 10 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE 59.0 ND ND 5.9 ND ND ND ND ND ND ND ND ND ND Total Zinc (Zn)mg/l 10 1000 93.4 10.4 11.3 22.4 23.8 ND 10.3 16.1 14.9 12.2 15.7 15.8 ND ND Acetone mg/l 25 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1 4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 0.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1 3000 ND ND ND ND 4.4 ND ND ND ND ND ND ND ND ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.02 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 2000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1 0.03 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Xylenes mg/l 2 500 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (10-24-2012) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-24-2013) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3R MW-3DR MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.5 6.8 6.3 6.2 6.3 6.2 5.7 5.7 8.1 5.6 5.9 6.0 5.8 NT Specific Conductance mmhos/cm (on-site)1 NE 22.0 46.0 44.0 121.0 1205 1328 516 387 144 887 72.0 247 190 NT Temperature °C (on-site)-NE 15.2 13.9 13.7 13.2 14.3 14.4 14.3 14.1 15.6 16.0 13.6 15.7 14.3 NT Turbidity NTU (on-site)NT NE 100 1.21 6.28 282 4.84 0.30 1.76 1.61 0.55 1.57 60.0 1.01 0.11 NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 700 241 16.8 100 164 842 964 344 226 9.3 218 96.5 116 190 ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND 1.2 ND ND ND Total Cadmium (Cd)mg/l 1 2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 10 19.0 ND ND 8.8 6.8 ND ND ND ND ND ND ND ND ND Total Cobalt (Co)mg/l 5 NE 16.5 ND ND ND 10.8 ND 5.6 ND ND ND 8.9 115 ND ND Total Copper (Cu)mg/l 5 1000 13.4 ND ND ND 9.3 6.0 ND ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 15 ND ND ND ND ND ND ND ND ND ND 10.4 ND ND ND Total Nickel (Ni)mg/l 5 100 10.0 ND ND ND 12.0 8.6 21.8 32.8 ND ND ND 9.2 ND ND Total Selenium (Se)mg/l 10 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE 33.5 ND ND 7.7 9.6 ND ND ND ND ND 5.4 ND ND ND Total Zinc (Zn)mg/l 10 1000 56.3 ND ND ND 18.6 14.9 ND ND ND ND 33.2 ND ND ND Acetone mg/l 25 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1 4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 0.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1 3000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.02 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 2000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1 0.03 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Xylenes mg/l 2 500 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (4-24-2013) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-24-2013) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3R MW-3DR MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.6 6.9 11.9 6.5 6.5 6.4 5.9 6.0 8.0 5.8 6.1 6.2 6.1 NT Specific Conductance mmhos/cm (on-site)1 NE 31.0 47.0 67.0 117.0 1191 1390 536 402 142 897 53.0 301 212 NT Temperature °C (on-site)-NE 12.5 12.5 11.9 12.5 13.7 13.6 13.1 13.9 13.4 13.7 13.9 13.6 13.0 NT Turbidity NTU (on-site)NT NE 55 2.23 9.29 3.02 3.17 0.61 3.01 2.27 0.36 0.55 100.0 0.53 0.66 NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 700 255 18.1 156 166 839 1160 510 256 9.1 250 55.2 171 218 ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 10 14.5 ND 12.1 ND ND ND ND ND ND ND ND ND ND ND Total Cobalt (Co)mg/l 5 NE 11.8 ND ND ND 8.0 ND 7.5 ND ND ND ND 84.5 ND ND Total Copper (Cu)mg/l 5 1000 12.6 ND ND ND 7.5 5.8 ND ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 100 7.9 ND 8.3 ND 7.5 7.0 30.2 29.9 ND ND ND 12.1 ND ND Total Selenium (Se)mg/l 10 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE 30.4 ND ND ND ND ND ND ND ND ND ND ND ND ND Total Zinc (Zn)mg/l 10 1000 30.6 ND ND ND ND ND 28.1 ND ND 28.8 39.6 14.9 ND 12 Acetone mg/l 25 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1 4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 0.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1 3000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.02 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 2000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1 0.03 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Xylenes mg/l 2 500 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (10-24-2013) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-24-2014) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3R MW-3DR MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.8 7.0 6.6 6.3 6.5 6.4 5.8 5.8 8.3 5.6 5.8 6.1 5.8 NT Specific Conductance mmhos/cm (on-site)1 NE 30.0 48.0 50.0 126.0 1364 1652 517 418 147 919 57.0 240 187 NT Temperature °C (on-site)-NE 12.9 13.8 14.9 14.5 15.5 15.3 15.8 14.2 16.0 15.6 12.8 16.5 16.5 NT Turbidity NTU (on-site)NT NE 39 1.43 4.85 1.82 1.49 2.86 2.25 1.24 1.51 2.38 9.39 1.95 2.24 NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND 6.1 ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 700 174 17.7 127 148 941 1290 378 248 8.3 238 27.5 148 189 ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 2 ND ND ND ND ND ND ND ND ND ND ND 1.2 ND ND Total Chromium (Cr)mg/l 5 10 12.8 ND ND ND ND ND ND ND ND ND ND 5.1 ND ND Total Cobalt (Co)mg/l 5 NE ND ND ND ND 5.7 ND ND ND ND ND ND 65.1 ND ND Total Copper (Cu)mg/l 5 1000 7.9 ND ND ND ND ND ND ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 100 7.0 ND ND ND 9.3 10.1 23.6 33.9 ND ND ND 12.5 ND ND Total Selenium (Se)mg/l 10 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND ND 5.6 ND ND Total Vanadium (V)mg/l 5 NE 22.8 ND ND ND ND ND ND ND ND ND ND ND ND ND Total Zinc (Zn)mg/l 10 1000 25.8 ND ND ND ND ND 18.9 ND ND ND ND 14.9 10.1 ND Acetone mg/l 25 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1 4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 0.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1 3000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.02 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 5 ND ND ND ND ND 2 ND ND ND 2.2 ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 2000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1 0.03 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Xylenes mg/l 2 500 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (4-24-2014) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-27-2014) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3R MW-3DR MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.55 8.52 6.50 6.27 6.18 6.13 5.71 5.25 7.70 5.81 6.50 5.92 5.89 NT Specific Conductance mmhos/cm (on-site)1 NE 21.7 108.1 32.4 115.1 1468.0 1646.0 466.3 353.0 163.1 698.0 50.9 223.7 172.0 NT Temperature °C (on-site)-NE 14.8 13.7 17.1 16.7 16.6 14.9 18.3 20.7 16.1 16.7 15.6 17.2 15.4 NT Turbidity NTU (on-site)NT NE >50 >50 30.00 2.68 3.09 2.99 30.00 3.92 30.00 6.01 4.35 3.17 1.44 NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 700 117 16.1 102 136 1280 1410 363 224 8.6 228 23.2 156 180 ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 10 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Cobalt (Co)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND 24.2 ND ND Total Copper (Cu)mg/l 5 1000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 100 ND ND ND ND 10.7 10.1 29.5 31.4 ND ND ND 9.1 ND ND Total Selenium (Se)mg/l 10 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Zinc (Zn)mg/l 10 1000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acetone mg/l 25 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1 4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 0.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1 3000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 2 0.04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.02 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 2000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1 0.03 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Xylenes mg/l 2 500 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (10-27-2014) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-28-2015) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3R MW-3DR MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.60 6.50 7.50 6.40 6.00 6.10 6.50 6.20 6.30 6.10 6.30 6.10 6.10 NT Specific Conductance mmhos/cm (on-site)1 NE 26.0 44.0 53.0 112.7 1601.0 1621.0 464.0 387.0 236.0 843.0 66.0 253.0 169.0 NT Temperature °C (on-site)-NE 13.5 13.2 12.5 13.9 16.9 15.5 14.1 14.2 16.5 15.8 13.5 16.6 14.8 NT Turbidity NTU (on-site)NT NE 39.5 4.82 9.58 4.46 7.43 3.78 4.84 4.94 3.80 4.37 18.40 4.49 3.49 NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 700 119 16.0 109 199 1330 1380 345 260 9.0 218 30.2 156 190 ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 2 ND ND ND ND ND ND ND ND ND ND ND 2.3 ND ND Total Chromium (Cr)mg/l 5 10 10.3 ND 8.2 7.9 ND ND ND ND ND ND ND ND ND ND Total Cobalt (Co)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND 29.3 ND ND Total Copper (Cu)mg/l 5 1000 7.4 ND ND ND ND ND ND ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 100 6.3 ND 5.6 6.8 11.7 11.2 25.1 35.4 ND ND ND 8.3 5.1 ND Total Selenium (Se)mg/l 10 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE 15.5 ND ND 8.0 ND ND ND ND ND ND ND 7.0 ND ND Total Zinc (Zn)mg/l 10 1000 51.7 ND 14.2 19.0 13.6 ND 14.8 12.9 ND ND 11.3 13.3 ND ND Acetone mg/l 25 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1 4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 0.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1 3000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 2 0.04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.02 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND 10.2 ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 5 ND ND ND ND ND ND ND ND ND ND 2.2 ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 2000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1 0.03 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Xylenes mg/l 2 500 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (4-28-2015) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-27-15) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3R MW-3DR MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.70 6.60 6.60 6.30 5.90 6.20 6.00 5.80 6.80 6.40 6.70 6.30 5.90 NT Specific Conductance mmhos/cm (on-site)1 NE 27.0 44.0 104.0 118.0 1478.0 1566.0 429.0 357.0 162.0 816.0 48.0 248.0 169.0 NT Temperature °C (on-site)-NE 12.1 12.4 12.4 12.5 13.0 13.0 13.5 13.7 13.2 13.5 14.3 14.5 13.4 NT Turbidity NTU (on-site)NT NE 5.5 4.35 28.00 1.88 2.52 1.27 4.05 7.82 8.68 5.50 16.56 11.09 5.11 NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 700 346 16.0 95.7 164 1190 1400 352 247 13.8 279 18.8 188 191 ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 2 1.9 ND ND ND ND ND ND ND ND ND ND 3.1 ND ND Total Chromium (Cr)mg/l 5 10 31.4 ND ND ND ND ND ND ND ND 7.7 ND ND ND ND Total Cobalt (Co)mg/l 5 NE 6.2 ND ND ND 5.6 ND ND ND ND ND ND 39.0 ND ND Total Copper (Cu)mg/l 5 1000 19.1 ND ND ND 5.4 7.3 ND ND ND ND ND 6.0 ND ND Total Lead (Pb)mg/l 5 15 7.7 ND ND ND ND ND ND ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 100 21.3 ND ND ND 12.6 12.6 24.4 33.4 ND 5.9 ND 8.7 ND ND Total Selenium (Se)mg/l 10 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE 44.5 ND ND ND ND ND ND ND ND 7.4 ND 9.8 ND ND Total Zinc (Zn)mg/l 10 1000 69.8 ND ND ND 14.3 ND ND 11.8 ND 22.1 ND 36.4 ND ND Acetone mg/l 25 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1 4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 0.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1 3000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 2 0.04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.02 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 2000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1 0.03 ND ND ND ND ND ND ND ND ND ND ND ND ND ND total Xylenes mg/l 2 500 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-50 White Oak GW Stats 2nd 2015.xlsm (10-27-15) APPENDIX B SUMMARY TABLES OF SURFACE WATER ANALYTICAL RESULTS White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-24-2000) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-4 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.4 6.3 6.7 6.4 NS NS NS 7.8 Specific Conductance mmhos/cm (on-site)1 NE 65 65 59 65 NS NS NS 2600 Temperature °C (on-site)-29 11 11 14 11 NS NS NS 11 Turbidity NTU (on-site)NT 50 NT NT NT NT NS NS NS NT Nitrate as N mg/l 0.1 NE NT NT NT NT NS NS NS NT Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NS NS NS 300 Nitrite as N mg/l 0.1 NE NT NT NT NT NS NS NS NT Nitrogen mg/l 0.2 NE NT NT NT NT NS NS NS 95 Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NS NS NS 95 Sulfate mg/l 500 NE NT NT NT NT NS NS NS NT Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NS NS NS 190 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NS NS NS 670 Total Dissolved Solids mg/l 20 NE NT NT NT NT NS NS NS 2700 Cyanide mg/l 2 5 NT NT NT NT NS NS NS 13 Total Antimony (Sb)mg/l 30 NE ND ND ND 25 NS NS NS NT Total Arsenic (As)mg/l 10 10 ND ND ND ND NS NS NS NT Total Barium (Ba)mg/l 500 NE 91 70 29 62 NS NS NS NT Total Beryllium (Be)mg/l 2 6.5 ND 2 ND ND NS NS NS NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND NS NS NS NT Total Chromium (Cr)mg/l 10 50 ND ND ND ND NS NS NS 13 Total Cobalt (Co)mg/l 10 NE ND ND ND 16 NS NS NS NT Total Copper (Cu)mg/l 200 7 ND ND ND ND NS NS NS NT Total Lead (Pb)mg/l 10 25 ND ND ND ND NS NS NS ND Total Nickel (Ni)mg/l 50 88 ND ND ND ND NS NS NS NT Total Selenium (Se)mg/l 20 5 ND ND ND ND NS NS NS ND Total Silver (Ag)mg/l 10 0.06 ND ND ND 3.8 NS NS NS NT Total Thallium (Tl)mg/l 10 NE ND ND ND ND NS NS NS 2 Total Vanadium (V)mg/l 40 NE ND ND ND ND NS NS NS NT Total Zinc (Zn)mg/l 50 50 13 26 14 ND NS NS NS NT Mercury mg/l 0.2 0.012 NT NT NT NT NS NS NS 0.3 Acetone mg/l 100 NE NT NT NT NT NS NS NS NT Acrylonitrile mg/l 200 NE NT NT NT NT NS NS NS NT Benzene mg/l 5 51 NT NT NT NT NS NS NS NT Bromochloromethane mg/l 5 NE NT NT NT NT NS NS NS NT Bromodichloromethane mg/l 5 NE NT NT NT NT NS NS NS NT Bromoform mg/l 5 NE NT NT NT NT NS NS NS NT Carbon Disulfide mg/l 100 NE NT NT NT NT NS NS NS NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NT NT NS NS NS NT Carbon tetrachloride mg/l 10 1.6 NT NT NT NT NS NS NS NT Chlorobenzene (mono)mg/l 5 NE NT NT NT NT NS NS NS NT Chloroethane mg/l 10 NE NT NT NT NT NS NS NS NT Chloroform mg/l 5 NE NT NT NT NT NS NS NS NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NT NT NS NS NS NT Dibromochloromethane mg/l 5 NE NT NT NT NT NS NS NS NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE NT NT NT NT NS NS NS NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE NT NT NT NT NS NS NS NT Dibromomethane mg/l 10 NE NT NT NT NT NS NS NS NT 1,2-Dichlorobenzene mg/l 5 NE NT NT NT NT NS NS NS NT 1,4-Dichlorobenzene mg/l 5 NE NT NT NT NT NS NS NS NT trans-1,4-Dichloro-2butene mg/l 100 NE NT NT NT NT NS NS NS NT 1,1-Dichloroethane mg/l 5 NE NT NT NT NT NS NS NS NT 1,2-Dichloroethane mg/l 5 NE NT NT NT NT NS NS NS NT 1,1-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT NT NS NS NS NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT NT NS NS NS NT trans-1,2-Dichloroethene (-ylene)mg/l 5 NE NT NT NT NT NS NS NS NT 1,2-Dichloropropane mg/l 5 NE NT NT NT NT NS NS NS NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NT NS NS NS NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NT NS NS NS NT Ethylbenzene mg/l 5 NE NT NT NT NT NS NS NS NT 2-Hexanone mg/l 50 NE NT NT NT NT NS NS NS NT Iodomethane mg/l 10 NE NT NT NT NT NS NS NS NT Dichloromethane (Methylene chloride)mg/l 10 NE NT NT NT NT NS NS NS NT 2-Butanone (Methyl ethyl ketone)mg/l 100 NE NT NT NT NT NS NS NS NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NT NT NS NS NS NT Styrene mg/l 10 NE NT NT NT NT NS NS NS NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NT NT NS NS NS NT 1,1,2,2-Tetrachloroethane mg/l 5 4 NT NT NT NT NS NS NS NT Tetrachloroethene (-ethylene)mg/l 5 3.3 NT NT NT NT NS NS NS NT Toluene mg/l 5 0.36 NT NT NT NT NS NS NS NT 1,1,1-Trichloroethane mg/l 5 NE NT NT NT NT NS NS NS NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NT NT NS NS NS NT Trichloroethene (-ethylene)mg/l 5 30 NT NT NT NT NS NS NS NT Trichlorofluoromethane mg/l 5 NE NT NT NT NT NS NS NS NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NT NT NS NS NS NT Vinyl acetate mg/l 50 NE NT NT NT NT NS NS NS NT Vinyl chloride mg/l 10 2.4 NT NT NT NT NS NS NS NT Xylene mg/l 5 NE NT NT NT NT NS NS NS NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (4-24-2000) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-9-2001) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7 7.1 7.1 NS NS NS 8.1 Specific Conductance mmhos/cm (on-site)1 NE 73 80 75 NS NS NS 3600 Temperature °C (on-site)-29 11 13 18 NS NS NS 15 Turbidity NTU (on-site)NT 50 NT NT NT NS NS NS NT Nitrate as N mg/l 0.1 NE NT NT NT NS NS NS NT Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NS NS NS ND Nitrite as N mg/l 0.1 NE NT NT NT NS NS NS NT Nitrogen mg/l 0.2 NE NT NT NT NS NS NS 120 Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NS NS NS 120 Sulfate mg/l 500 NE NT NT NT NS NS NS NT Biochemical Oxygen Demand mg/l 2 NE NT NT NT NS NS NS 240 Chemical Oxygen Demand mg/l 25 NE NT NT NT NS NS NS 430 Total Dissolved Solids mg/l 20 NE NT NT NT NS NS NS 5000 Cyanide mg/l 2 5 NT NT NT NS NS NS ND Total Antimony (Sb)mg/l 30 NE ND ND ND NS NS NS NT Total Arsenic (As)mg/l 10 10 ND ND ND NS NS NS NT Total Barium (Ba)mg/l 500 NE 99 81 55 NS NS NS NT Total Beryllium (Be)mg/l 2 6.5 ND ND ND NS NS NS NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND NS NS NS NT Total Chromium (Cr)mg/l 10 50 ND ND ND NS NS NS 10 Total Cobalt (Co)mg/l 10 NE ND ND ND NS NS NS NT Total Copper (Cu)mg/l 200 7 ND ND ND NS NS NS NT Total Lead (Pb)mg/l 10 25 ND ND ND NS NS NS ND Total Nickel (Ni)mg/l 50 88 ND ND ND NS NS NS NT Total Selenium (Se)mg/l 20 5 ND ND ND NS NS NS 210 Total Silver (Ag)mg/l 10 0.06 ND ND ND NS NS NS NT Total Thallium (Tl)mg/l 10 NE ND ND ND NS NS NS ND Total Vanadium (V)mg/l 40 NE ND ND ND NS NS NS NT Total Zinc (Zn)mg/l 50 50 15 31 20 NS NS NS NT Mercury mg/l 0.2 0.012 NT NT NT NS NS NS ND Acetone mg/l 100 NE NT NT NT NS NS NS NT Acrylonitrile mg/l 200 NE NT NT NT NS NS NS NT Benzene mg/l 5 51 NT NT NT NS NS NS NT Bromochloromethane mg/l 5 NE NT NT NT NS NS NS NT Bromodichloromethane mg/l 5 NE NT NT NT NS NS NS NT Bromoform mg/l 5 NE NT NT NT NS NS NS NT Carbon Disulfide mg/l 100 NE NT NT NT NS NS NS NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NT NS NS NS NT Carbon tetrachloride mg/l 10 1.6 NT NT NT NS NS NS NT Chlorobenzene (mono)mg/l 5 NE NT NT NT NS NS NS NT Chloroethane mg/l 10 NE NT NT NT NS NS NS NT Chloroform mg/l 5 NE NT NT NT NS NS NS NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NT NS NS NS NT Dibromochloromethane mg/l 5 NE NT NT NT NS NS NS NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE NT NT NT NS NS NS NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE NT NT NT NS NS NS NT Dibromomethane mg/l 10 NE NT NT NT NS NS NS NT 1,2-Dichlorobenzene mg/l 5 NE NT NT NT NS NS NS NT 1,4-Dichlorobenzene mg/l 5 NE NT NT NT NS NS NS NT trans-1,4-Dichloro-2butene mg/l 100 NE NT NT NT NS NS NS NT 1,1-Dichloroethane mg/l 5 NE NT NT NT NS NS NS NT 1,2-Dichloroethane mg/l 5 NE NT NT NT NS NS NS NT 1,1-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT NS NS NS NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT NS NS NS NT trans-1,2-Dichloroethene (-ylene)mg/l 5 NE NT NT NT NS NS NS NT 1,2-Dichloropropane mg/l 5 NE NT NT NT NS NS NS NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NS NS NS NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NS NS NS NT Ethylbenzene mg/l 5 NE NT NT NT NS NS NS NT 2-Hexanone mg/l 50 NE NT NT NT NS NS NS NT Iodomethane mg/l 10 NE NT NT NT NS NS NS NT Dichloromethane (Methylene chloride)mg/l 10 NE NT NT NT NS NS NS NT 2-Butanone (Methyl ethyl ketone)mg/l 100 NE NT NT NT NS NS NS NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NT NS NS NS NT Styrene mg/l 10 NE NT NT NT NS NS NS NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NT NS NS NS NT 1,1,2,2-Tetrachloroethane mg/l 5 4 NT NT NT NS NS NS NT Tetrachloroethene (-ethylene)mg/l 5 3.3 NT NT NT NS NS NS NT Toluene mg/l 5 0.36 NT NT NT NS NS NS NT 1,1,1-Trichloroethane mg/l 5 NE NT NT NT NS NS NS NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NT NS NS NS NT Trichloroethene (-ethylene)mg/l 5 30 NT NT NT NS NS NS NT Trichlorofluoromethane mg/l 5 NE NT NT NT NS NS NS NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NT NS NS NS NT Vinyl acetate mg/l 50 NE NT NT NT NS NS NS NT Vinyl chloride mg/l 10 2.4 NT NT NT NS NS NS NT Xylene mg/l 5 NE NT NT NT NS NS NS NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (4-9-2001) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (9-18-2001) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 NS NS NS 7.48 NS NS NS Specific Conductance mmhos/cm (on-site)1 NE NS NS NS 160 NS NS NS Temperature °C (on-site)-29 NS NS NS 20 NS NS NS Turbidity NTU (on-site)NT 50 NS NS NS NT NS NS NS Nitrate as N mg/l 0.1 NE NS NS NS NT NS NS NS Nitrate/Nitrite as N mg/l 0.1 NE NS NS NS NT NS NS NS Nitrite as N mg/l 0.1 NE NS NS NS NT NS NS NS Nitrogen mg/l 0.2 NE NS NS NS NT NS NS NS Total Nitrogen, Kjeldahl mg/l 100 NE NS NS NS NT NS NS NS Sulfate mg/l 500 NE NS NS NS NT NS NS NS Biochemical Oxygen Demand mg/l 2 NE NS NS NS NT NS NS NS Chemical Oxygen Demand mg/l 25 NE NS NS NS NT NS NS NS Total Dissolved Solids mg/l 20 NE NS NS NS NT NS NS NS Cyanide mg/l 2 5 NS NS NS NT NS NS NS Total Antimony (Sb)mg/l 30 NE NS NS NS ND NS NS NS Total Arsenic (As)mg/l 10 10 NS NS NS ND NS NS NS Total Barium (Ba)mg/l 500 NE NS NS NS 71 NS NS NS Total Beryllium (Be)mg/l 2 6.5 NS NS NS ND NS NS NS Total Cadmium (Cd)mg/l 1 0.4 NS NS NS ND NS NS NS Total Chromium (Cr)mg/l 10 50 NS NS NS ND NS NS NS Total Cobalt (Co)mg/l 10 NE NS NS NS 7.2 NS NS NS Total Copper (Cu)mg/l 200 7 NS NS NS ND NS NS NS Total Lead (Pb)mg/l 10 25 NS NS NS ND NS NS NS Total Nickel (Ni)mg/l 50 88 NS NS NS 9.4 NS NS NS Total Selenium (Se)mg/l 20 5 NS NS NS ND NS NS NS Total Silver (Ag)mg/l 10 0.06 NS NS NS ND NS NS NS Total Thallium (Tl)mg/l 10 NE NS NS NS ND NS NS NS Total Vanadium (V)mg/l 40 NE NS NS NS ND NS NS NS Total Zinc (Zn)mg/l 50 50 NS NS NS 11 NS NS NS Mercury mg/l 0.2 0.012 NS NS NS NT NS NS NS Acetone mg/l 100 NE NS NS NS NT NS NS NS Acrylonitrile mg/l 200 NE NS NS NS NT NS NS NS Benzene mg/l 5 51 NS NS NS NT NS NS NS Bromochloromethane mg/l 5 NE NS NS NS NT NS NS NS Bromodichloromethane mg/l 5 NE NS NS NS NT NS NS NS Bromoform mg/l 5 NE NS NS NS NT NS NS NS Carbon Disulfide mg/l 100 NE NS NS NS NT NS NS NS Bromomethane (Methylbromide)mg/l 10 NE NS NS NS NT NS NS NS Carbon tetrachloride mg/l 10 1.6 NS NS NS NT NS NS NS Chlorobenzene (mono)mg/l 5 NE NS NS NS NT NS NS NS Chloroethane mg/l 10 NE NS NS NS NT NS NS NS Chloroform mg/l 5 NE NS NS NS NT NS NS NS Chloromethane (Methylchloride)mg/l 10 NE NS NS NS NT NS NS NS Dibromochloromethane mg/l 5 NE NS NS NS NT NS NS NS 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE NS NS NS NT NS NS NS 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE NS NS NS NT NS NS NS Dibromomethane mg/l 10 NE NS NS NS NT NS NS NS 1,2-Dichlorobenzene mg/l 5 NE NS NS NS NT NS NS NS 1,4-Dichlorobenzene mg/l 5 NE NS NS NS NT NS NS NS trans-1,4-Dichloro-2butene mg/l 100 NE NS NS NS NT NS NS NS 1,1-Dichloroethane mg/l 5 NE NS NS NS NT NS NS NS 1,2-Dichloroethane mg/l 5 NE NS NS NS NT NS NS NS 1,1-Dichloroethene (-ethylene)mg/l 5 NE NS NS NS NT NS NS NS cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE NS NS NS NT NS NS NS trans-1,2-Dichloroethene (-ylene)mg/l 5 NE NS NS NS NT NS NS NS 1,2-Dichloropropane mg/l 5 NE NS NS NS NT NS NS NS cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NS NS NS NT NS NS NS trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NS NS NS NT NS NS NS Ethylbenzene mg/l 5 NE NS NS NS NT NS NS NS 2-Hexanone mg/l 50 NE NS NS NS NT NS NS NS Iodomethane mg/l 10 NE NS NS NS NT NS NS NS Dichloromethane (Methylene chloride)mg/l 10 NE NS NS NS NT NS NS NS 2-Butanone (Methyl ethyl ketone)mg/l 100 NE NS NS NS NT NS NS NS 4-Methyl-2-Pentanone mg/l 100 NE NS NS NS NT NS NS NS Styrene mg/l 10 NE NS NS NS NT NS NS NS 1,1,1,2-Tetrachloroethane mg/l 5 NE NS NS NS NT NS NS NS 1,1,2,2-Tetrachloroethane mg/l 5 4 NS NS NS NT NS NS NS Tetrachloroethene (-ethylene)mg/l 5 3.3 NS NS NS NT NS NS NS Toluene mg/l 5 0.36 NS NS NS NT NS NS NS 1,1,1-Trichloroethane mg/l 5 NE NS NS NS NT NS NS NS 1,1,2-Trichloroethane mg/l 5 NE NS NS NS NT NS NS NS Trichloroethene (-ethylene)mg/l 5 30 NS NS NS NT NS NS NS Trichlorofluoromethane mg/l 5 NE NS NS NS NT NS NS NS 1,2,3-Trichloropropane mg/l 15 NE NS NS NS NT NS NS NS Vinyl acetate mg/l 50 NE NS NS NS NT NS NS NS Vinyl chloride mg/l 10 2.4 NS NS NS NT NS NS NS Xylene mg/l 5 NE NS NS NS NT NS NS NS Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (9-18-2001) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-15-2002) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.67 6.08 6.46 7 NS NS 6.71 Specific Conductance mmhos/cm (on-site)1 NE 78 78 80 170 NS NS 265 Temperature °C (on-site)-29 17.8 13.3 19.4 20 NS NS 20.1 Turbidity NTU (on-site)NT 50 NT NT NT NT NS NS NT Nitrate as N mg/l 0.1 NE NT NT NT NT NS NS NT Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NS NS 0.3 Nitrite as N mg/l 0.1 NE NT NT NT NT NS NS NT Nitrogen mg/l 0.2 NE NT NT NT NT NS NS 96 Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NS NS 96 Sulfate mg/l 500 NE NT NT NT NT NS NS NT Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NS NS 740 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NS NS 1400 Total Dissolved Solids mg/l 20 NE NT NT NT NT NS NS 2300 Cyanide mg/l 2 5 NT NT NT NT NS NS 0.006 Total Antimony (Sb)mg/l 30 NE ND ND ND ND NS NS NT Total Arsenic (As)mg/l 10 10 ND ND ND ND NS NS NT Total Barium (Ba)mg/l 500 NE 92 91 40 140 NS NS NT Total Beryllium (Be)mg/l 2 6.5 ND ND ND ND NS NS NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND NS NS NT Total Chromium (Cr)mg/l 10 50 ND ND ND ND NS NS 34 Total Cobalt (Co)mg/l 10 NE ND ND ND 7.7 NS NS NT Total Copper (Cu)mg/l 200 7 ND ND ND ND NS NS NT Total Lead (Pb)mg/l 10 25 ND ND ND ND NS NS ND Total Nickel (Ni)mg/l 50 88 ND ND ND 9 NS NS NT Total Selenium (Se)mg/l 20 5 ND ND ND ND NS NS ND Total Silver (Ag)mg/l 10 0.06 ND ND ND ND NS NS NT Total Thallium (Tl)mg/l 10 NE ND ND ND ND NS NS ND Total Vanadium (V)mg/l 40 NE ND ND ND 6.5 NS NS NT Total Zinc (Zn)mg/l 50 50 ND 37 32 60 NS NS NT Mercury mg/l 0.2 0.012 NT NT NT NT NS NS ND Acetone mg/l 100 NE NT NT NT NT NS NS NT Acrylonitrile mg/l 200 NE NT NT NT NT NS NS NT Benzene mg/l 5 51 NT NT NT NT NS NS NT Bromochloromethane mg/l 5 NE NT NT NT NT NS NS NT Bromodichloromethane mg/l 5 NE NT NT NT NT NS NS NT Bromoform mg/l 5 NE NT NT NT NT NS NS NT Carbon Disulfide mg/l 100 NE NT NT NT NT NS NS NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NT NT NS NS NT Carbon tetrachloride mg/l 10 1.6 NT NT NT NT NS NS NT Chlorobenzene (mono)mg/l 5 NE NT NT NT NT NS NS NT Chloroethane mg/l 10 NE NT NT NT NT NS NS NT Chloroform mg/l 5 NE NT NT NT NT NS NS NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NT NT NS NS NT Dibromochloromethane mg/l 5 NE NT NT NT NT NS NS NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE NT NT NT NT NS NS NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE NT NT NT NT NS NS NT Dibromomethane mg/l 10 NE NT NT NT NT NS NS NT 1,2-Dichlorobenzene mg/l 5 NE NT NT NT NT NS NS NT 1,4-Dichlorobenzene mg/l 5 NE NT NT NT NT NS NS NT trans-1,4-Dichloro-2butene mg/l 100 NE NT NT NT NT NS NS NT 1,1-Dichloroethane mg/l 5 NE NT NT NT NT NS NS NT 1,2-Dichloroethane mg/l 5 NE NT NT NT NT NS NS NT 1,1-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT NT NS NS NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT NT NS NS NT trans-1,2-Dichloroethene (-ylene)mg/l 5 NE NT NT NT NT NS NS NT 1,2-Dichloropropane mg/l 5 NE NT NT NT NT NS NS NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NT NS NS NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NT NS NS NT Ethylbenzene mg/l 5 NE NT NT NT NT NS NS NT 2-Hexanone mg/l 50 NE NT NT NT NT NS NS NT Iodomethane mg/l 10 NE NT NT NT NT NS NS NT Dichloromethane (Methylene chloride)mg/l 10 NE NT NT NT NT NS NS NT 2-Butanone (Methyl ethyl ketone)mg/l 100 NE NT NT NT NT NS NS NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NT NT NS NS NT Styrene mg/l 10 NE NT NT NT NT NS NS NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NT NT NS NS NT 1,1,2,2-Tetrachloroethane mg/l 5 4 NT NT NT NT NS NS NT Tetrachloroethene (-ethylene)mg/l 5 3.3 NT NT NT NT NS NS NT Toluene mg/l 5 0.36 NT NT NT NT NS NS NT 1,1,1-Trichloroethane mg/l 5 NE NT NT NT NT NS NS NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NT NT NS NS NT Trichloroethene (-ethylene)mg/l 5 30 NT NT NT NT NS NS NT Trichlorofluoromethane mg/l 5 NE NT NT NT NT NS NS NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NT NT NS NS NT Vinyl acetate mg/l 50 NE NT NT NT NT NS NS NT Vinyl chloride mg/l 10 2.4 NT NT NT NT NS NS NT Xylene mg/l 5 NE NT NT NT NT NS NS NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (4-15-2002) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (9-26-2002) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.9 6.88 7.01 NS NS NS 7.48 Specific Conductance mmhos/cm (on-site)1 NE 102 151 115 NS NS NS 3700 Temperature °C (on-site)-29 16.5 17.2 17.5 NS NS NS 18.4 Turbidity NTU (on-site)NT 50 NT NT NT NS NS NS NT Nitrate as N mg/l 0.1 NE NT NT NT NS NS NS NT Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NS NS NS ND Nitrite as N mg/l 0.1 NE NT NT NT NS NS NS NT Nitrogen mg/l 0.2 NE NT NT NT NS NS NS ND Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NS NS NS 130 Sulfate mg/l 500 NE NT NT NT NS NS NS NT Biochemical Oxygen Demand mg/l 2 NE NT NT NT NS NS NS 210 Chemical Oxygen Demand mg/l 25 NE NT NT NT NS NS NS 1300 Total Dissolved Solids mg/l 20 NE NT NT NT NS NS NS 3000 Cyanide mg/l 2 5 NT NT NT NS NS NS 2.5 Total Antimony (Sb)mg/l 30 NE ND ND ND NS NS NS NT Total Arsenic (As)mg/l 10 10 ND ND ND NS NS NS NT Total Barium (Ba)mg/l 500 NE 150 160 80 NS NS NS NT Total Beryllium (Be)mg/l 2 6.5 ND ND ND NS NS NS NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND NS NS NS NT Total Chromium (Cr)mg/l 10 50 ND ND ND NS NS NS 34 Total Cobalt (Co)mg/l 10 NE 7.2 ND ND NS NS NS NT Total Copper (Cu)mg/l 200 7 ND 4.5 2.7 NS NS NS NT Total Lead (Pb)mg/l 10 25 ND ND ND NS NS NS ND Total Nickel (Ni)mg/l 50 88 ND ND ND NS NS NS NT Total Selenium (Se)mg/l 20 5 ND ND ND NS NS NS ND Total Silver (Ag)mg/l 10 0.06 ND ND ND NS NS NS NT Total Thallium (Tl)mg/l 10 NE ND ND ND NS NS NS ND Total Vanadium (V)mg/l 40 NE ND 6.4 ND NS NS NS NT Total Zinc (Zn)mg/l 50 50 19 100 41 NS NS NS NT Mercury mg/l 0.2 0.012 NT NT NT NS NS NS ND Acetone mg/l 100 NE NT NT NT NS NS NS NT Acrylonitrile mg/l 200 NE NT NT NT NS NS NS NT Benzene mg/l 5 51 NT NT NT NS NS NS NT Bromochloromethane mg/l 5 NE NT NT NT NS NS NS NT Bromodichloromethane mg/l 5 NE NT NT NT NS NS NS NT Bromoform mg/l 5 NE NT NT NT NS NS NS NT Carbon Disulfide mg/l 100 NE NT NT NT NS NS NS NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NT NS NS NS NT Carbon tetrachloride mg/l 10 1.6 NT NT NT NS NS NS NT Chlorobenzene (mono)mg/l 5 NE NT NT NT NS NS NS NT Chloroethane mg/l 10 NE NT NT NT NS NS NS NT Chloroform mg/l 5 NE NT NT NT NS NS NS NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NT NS NS NS NT Dibromochloromethane mg/l 5 NE NT NT NT NS NS NS NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE NT NT NT NS NS NS NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE NT NT NT NS NS NS NT Dibromomethane mg/l 10 NE NT NT NT NS NS NS NT 1,2-Dichlorobenzene mg/l 5 NE NT NT NT NS NS NS NT 1,4-Dichlorobenzene mg/l 5 NE NT NT NT NS NS NS NT trans-1,4-Dichloro-2butene mg/l 100 NE NT NT NT NS NS NS NT 1,1-Dichloroethane mg/l 5 NE NT NT NT NS NS NS NT 1,2-Dichloroethane mg/l 5 NE NT NT NT NS NS NS NT 1,1-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT NS NS NS NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT NS NS NS NT trans-1,2-Dichloroethene (-ylene)mg/l 5 NE NT NT NT NS NS NS NT 1,2-Dichloropropane mg/l 5 NE NT NT NT NS NS NS NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NS NS NS NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NS NS NS NT Ethylbenzene mg/l 5 NE NT NT NT NS NS NS NT 2-Hexanone mg/l 50 NE NT NT NT NS NS NS NT Iodomethane mg/l 10 NE NT NT NT NS NS NS NT Dichloromethane (Methylene chloride)mg/l 10 NE NT NT NT NS NS NS NT 2-Butanone (Methyl ethyl ketone)mg/l 100 NE NT NT NT NS NS NS NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NT NS NS NS NT Styrene mg/l 10 NE NT NT NT NS NS NS NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NT NS NS NS NT 1,1,2,2-Tetrachloroethane mg/l 5 4 NT NT NT NS NS NS NT Tetrachloroethene (-ethylene)mg/l 5 3.3 NT NT NT NS NS NS NT Toluene mg/l 5 0.36 NT NT NT NS NS NS NT 1,1,1-Trichloroethane mg/l 5 NE NT NT NT NS NS NS NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NT NS NS NS NT Trichloroethene (-ethylene)mg/l 5 30 NT NT NT NS NS NS NT Trichlorofluoromethane mg/l 5 NE NT NT NT NS NS NS NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NT NS NS NS NT Vinyl acetate mg/l 50 NE NT NT NT NS NS NS NT Vinyl chloride mg/l 10 2.4 NT NT NT NS NS NS NT Xylene mg/l 5 NE NT NT NT NS NS NS NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (9-26-2002) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-29-2003) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.91 6.42 7.17 NS 6.41 6.71 NT Specific Conductance mmhos/cm (on-site)1 NE 77 75 101 NS 19 29 NT Temperature °C (on-site)-29 11.8 13 16 NS 15.6 14.9 NT Turbidity NTU (on-site)NT 50 NT NT NT NS NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NS NT NT NT Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NS NT NT ND Nitrite as N mg/l 0.1 NE NT NT NT NS NT NT NT Nitrogen mg/l 0.2 NE NT NT NT NS NT NT 220 Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NS NT NT 220 Sulfate mg/l 500 NE NT NT NT NS NT NT NT Biochemical Oxygen Demand mg/l 2 NE NT NT NT NS NT NT 2500 Chemical Oxygen Demand mg/l 25 NE NT NT NT NS NT NT 1100 Total Dissolved Solids mg/l 20 NE NT NT NT NS NT NT 120 Cyanide mg/l 2 5 NT NT NT NS NT NT 110 Total Antimony (Sb)mg/l 30 NE ND ND ND NS ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND NS ND ND 15 Total Barium (Ba)mg/l 500 NE 90 82 64 NS 27 27 270 Total Beryllium (Be)mg/l 2 6.5 ND ND ND NS ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND NS ND ND 2.5 Total Chromium (Cr)mg/l 10 50 ND ND ND NS ND ND ND Total Cobalt (Co)mg/l 10 NE ND ND ND NS ND ND 16 Total Copper (Cu)mg/l 200 7 ND ND ND NS ND ND ND Total Lead (Pb)mg/l 10 25 ND ND ND NS ND ND ND Total Nickel (Ni)mg/l 50 88 ND ND ND NS ND ND ND Total Selenium (Se)mg/l 20 5 ND ND ND NS ND ND ND Total Silver (Ag)mg/l 10 0.06 ND ND ND NS ND ND 2.4 Total Thallium (Tl)mg/l 10 NE ND ND ND NS ND ND ND Total Vanadium (V)mg/l 40 NE ND ND ND NS ND ND 19 Total Zinc (Zn)mg/l 50 50 ND 45 20 NS ND ND 1000 Mercury mg/l 0.2 0.012 NT NT NT NS NT NT NT Acetone mg/l 100 NE NT NT NT NS NT NT NT Acrylonitrile mg/l 200 NE NT NT NT NS NT NT NT Benzene mg/l 5 51 NT NT NT NS NT NT NT Bromochloromethane mg/l 5 NE NT NT NT NS NT NT NT Bromodichloromethane mg/l 5 NE NT NT NT NS NT NT NT Bromoform mg/l 5 NE NT NT NT NS NT NT NT Carbon Disulfide mg/l 100 NE NT NT NT NS NT NT NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NT NS NT NT NT Carbon tetrachloride mg/l 10 1.6 NT NT NT NS NT NT NT Chlorobenzene (mono)mg/l 5 NE NT NT NT NS NT NT NT Chloroethane mg/l 10 NE NT NT NT NS NT NT NT Chloroform mg/l 5 NE NT NT NT NS NT NT NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NT NS NT NT NT Dibromochloromethane mg/l 5 NE NT NT NT NS NT NT NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE NT NT NT NS NT NT NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE NT NT NT NS NT NT NT Dibromomethane mg/l 10 NE NT NT NT NS NT NT NT 1,2-Dichlorobenzene mg/l 5 NE NT NT NT NS NT NT NT 1,4-Dichlorobenzene mg/l 5 NE NT NT NT NS NT NT NT trans-1,4-Dichloro-2butene mg/l 100 NE NT NT NT NS NT NT NT 1,1-Dichloroethane mg/l 5 NE NT NT NT NS NT NT NT 1,2-Dichloroethane mg/l 5 NE NT NT NT NS NT NT NT 1,1-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT NS NT NT NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT NS NT NT NT trans-1,2-Dichloroethene (-ylene)mg/l 5 NE NT NT NT NS NT NT NT 1,2-Dichloropropane mg/l 5 NE NT NT NT NS NT NT NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NS NT NT NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NS NT NT NT Ethylbenzene mg/l 5 NE NT NT NT NS NT NT NT 2-Hexanone mg/l 50 NE NT NT NT NS NT NT NT Iodomethane mg/l 10 NE NT NT NT NS NT NT NT Dichloromethane (Methylene chloride)mg/l 10 NE NT NT NT NS NT NT NT 2-Butanone (Methyl ethyl ketone)mg/l 100 NE NT NT NT NS NT NT NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NT NS NT NT NT Styrene mg/l 10 NE NT NT NT NS NT NT NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NT NS NT NT NT 1,1,2,2-Tetrachloroethane mg/l 5 4 NT NT NT NS NT NT NT Tetrachloroethene (-ethylene)mg/l 5 3.3 NT NT NT NS NT NT NT Toluene mg/l 5 0.36 NT NT NT NS NT NT NT 1,1,1-Trichloroethane mg/l 5 NE NT NT NT NS NT NT NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NT NS NT NT NT Trichloroethene (-ethylene)mg/l 5 30 NT NT NT NS NT NT NT Trichlorofluoromethane mg/l 5 NE NT NT NT NS NT NT NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NT NS NT NT NT Vinyl acetate mg/l 50 NE NT NT NT NS NT NT NT Vinyl chloride mg/l 10 2.4 NT NT NT NS NT NT NT Xylene mg/l 5 NE NT NT NT NS NT NT NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (4-29-2003) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-30-2003) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.41 7.38 7.42 NS 5.87 7.14 8.37 Specific Conductance mmhos/cm (on-site)1 NE 80 80 80 NS 19 29 3500 Temperature °C (on-site)-29 12 12 12 NS 14.2 15.1 19.3 Turbidity NTU (on-site)NT 50 NT NT NT NS NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NS NT NT 3.4 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NS NT NT 3.4 Nitrite as N mg/l 0.1 NE NT NT NT NS NT NT NT Nitrogen mg/l 0.2 NE NT NT NT NS NT NT 72 Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NS NT NT 69 Sulfate mg/l 500 NE NT NT NT NS NT NT NT Biochemical Oxygen Demand mg/l 2 NE NT NT NT NS NT NT ND Chemical Oxygen Demand mg/l 25 NE NT NT NT NS NT NT 250 Total Dissolved Solids mg/l 20 NE NT NT NT NS NT NT 2500 Cyanide mg/l 2 5 NT NT NT NS NT NT NT Total Antimony (Sb)mg/l 30 NE ND ND ND NS ND ND NT Total Arsenic (As)mg/l 10 10 ND ND ND NS 5.5 ND NT Total Barium (Ba)mg/l 500 NE 110 130 84 NS 24 27 NT Total Beryllium (Be)mg/l 2 6.5 ND ND ND NS ND ND NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND NS ND ND NT Total Chromium (Cr)mg/l 10 50 ND ND ND NS ND ND 10 Total Cobalt (Co)mg/l 10 NE ND ND ND NS ND ND NT Total Copper (Cu)mg/l 200 7 ND 2.7 2.2 NS 2.2 ND NT Total Lead (Pb)mg/l 10 25 ND ND ND NS ND ND ND Total Nickel (Ni)mg/l 50 88 ND ND ND NS ND ND NT Total Selenium (Se)mg/l 20 5 ND ND ND NS ND ND ND Total Silver (Ag)mg/l 10 0.06 ND ND ND NS ND ND NT Total Thallium (Tl)mg/l 10 NE ND ND ND NS ND ND ND Total Vanadium (V)mg/l 40 NE ND 5.3 ND NS ND ND NT Total Zinc (Zn)mg/l 50 50 ND 80 40 NS 14 ND NT Mercury mg/l 0.2 0.012 NT NT NT NS NT NT ND Acetone mg/l 100 NE ND ND ND NS ND ND NT Acrylonitrile mg/l 200 NE ND ND ND NS ND ND NT Benzene mg/l 5 51 ND ND ND NS ND ND NT Bromochloromethane mg/l 5 NE ND ND ND NS ND ND NT Bromodichloromethane mg/l 5 NE ND ND ND NS ND ND NT Bromoform mg/l 5 NE ND ND ND NS ND ND NT Carbon Disulfide mg/l 100 NE ND ND ND NS ND 11 NT Bromomethane (Methylbromide)mg/l 10 NE ND ND ND NS ND ND NT Carbon tetrachloride mg/l 10 1.6 ND ND ND NS ND ND NT Chlorobenzene (mono)mg/l 5 NE ND ND ND NS ND ND NT Chloroethane mg/l 10 NE ND ND ND NS ND ND NT Chloroform mg/l 5 NE ND ND ND NS ND ND NT Chloromethane (Methylchloride)mg/l 10 NE ND ND ND NS ND ND NT Dibromochloromethane mg/l 5 NE ND ND ND NS ND ND NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE ND ND ND NS ND ND NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE ND ND ND NS ND ND NT Dibromomethane mg/l 10 NE ND ND ND NS ND ND NT 1,2-Dichlorobenzene mg/l 5 NE ND ND ND NS ND ND NT 1,4-Dichlorobenzene mg/l 5 NE ND ND ND NS ND ND NT trans-1,4-Dichloro-2butene mg/l 100 NE ND ND ND NS ND ND NT 1,1-Dichloroethane mg/l 5 NE ND ND ND NS ND ND NT 1,2-Dichloroethane mg/l 5 NE ND ND ND NS ND ND NT 1,1-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND NS ND ND NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND NS ND ND NT trans-1,2-Dichloroethene (-ylene)mg/l 5 NE ND ND ND NS ND ND NT 1,2-Dichloropropane mg/l 5 NE ND ND ND NS ND ND NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND NS ND ND NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND NS ND ND NT Ethylbenzene mg/l 5 NE ND ND ND NS ND ND NT 2-Hexanone mg/l 50 NE ND ND ND NS ND ND NT Iodomethane mg/l 10 NE ND ND ND NS ND ND NT Dichloromethane (Methylene chloride)mg/l 10 NE ND ND ND NS ND ND NT 2-Butanone (Methyl ethyl ketone)mg/l 100 NE ND ND ND NS ND ND NT 4-Methyl-2-Pentanone mg/l 100 NE ND ND ND NS ND ND NT Styrene mg/l 10 NE ND ND ND NS ND ND NT 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND NS ND ND NT 1,1,2,2-Tetrachloroethane mg/l 5 4 ND ND ND NS ND ND NT Tetrachloroethene (-ethylene)mg/l 5 3.3 ND ND ND NS ND ND NT Toluene mg/l 5 0.36 ND ND ND NS ND ND NT 1,1,1-Trichloroethane mg/l 5 NE ND ND ND NS ND ND NT 1,1,2-Trichloroethane mg/l 5 NE ND ND ND NS ND ND NT Trichloroethene (-ethylene)mg/l 5 30 ND ND ND NS ND ND NT Trichlorofluoromethane mg/l 5 NE ND ND ND NS ND ND NT 1,2,3-Trichloropropane mg/l 15 NE ND ND ND NS ND ND NT Vinyl acetate mg/l 50 NE ND ND ND NS ND ND NT Vinyl chloride mg/l 10 2.4 ND ND ND NS ND ND NT Xylene mg/l 5 NE ND ND ND NS ND ND NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (10-30-2003) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-20-2004) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.8 7.05 7.19 8.05 6.19 6.35 8.37 Specific Conductance mmhos/cm (on-site)1 NE 74 73 142 1790 19 29 4050 Temperature °C (on-site)-29 13 13 15 17 17 16 28.4 Turbidity NTU (on-site)NT 50 NT NT NT NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 0.11 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.11 Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT NT Nitrogen mg/l 0.2 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 500 NE NT NT NT NT NT NT 640 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 470 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 1100 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 30 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND 16 Total Barium (Ba)mg/l 500 NE 120 95 83 260 18 26 140 Total Beryllium (Be)mg/l 2 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 10 50 ND ND ND ND ND ND 28 Total Cobalt (Co)mg/l 10 NE ND ND ND 26 ND ND 17 Total Copper (Cu)mg/l 200 7 ND ND 3.1 ND ND ND ND Total Lead (Pb)mg/l 10 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 50 88 ND ND ND 12 ND ND 45 Total Selenium (Se)mg/l 20 5 ND ND ND 6 ND ND 8 Total Silver (Ag)mg/l 10 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 10 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 40 NE ND ND ND ND ND ND 12 Total Zinc (Zn)mg/l 50 50 ND 48 31 310 15 ND 62 Mercury mg/l 0.2 0.012 NT NT NT ND NT NT ND Acetone mg/l 100 NE ND ND ND ND ND ND 490 Acrylonitrile mg/l 200 NE ND ND ND ND ND ND ND Benzene mg/l 5 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 5 NE ND ND ND ND ND ND ND Bromoform mg/l 5 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 100 NE ND ND ND ND ND ND 14 Bromomethane (Methylbromide)mg/l 10 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 10 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 5 NE ND ND ND ND ND ND ND Chloroethane mg/l 10 NE ND ND ND ND ND ND ND Chloroform mg/l 5 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 10 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE ND ND ND ND ND ND ND Dibromomethane mg/l 10 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 5 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 5 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2butene mg/l 100 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 5 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 5 NE ND ND ND ND ND ND ND 2-Hexanone mg/l 50 NE ND ND ND ND ND ND ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 10 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 100 NE ND ND ND ND ND ND 300 4-Methyl-2-Pentanone mg/l 100 NE ND ND ND ND ND ND ND Styrene mg/l 10 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 5 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 5 3.3 ND ND ND ND ND ND ND Toluene mg/l 5 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 5 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 5 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 15 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 50 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 10 2.4 ND ND ND ND ND ND ND Xylene mg/l 5 NE ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (4-20-2004) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-21-2004) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.06 6.62 NS 7.16 7.42 6.41 7.89 Specific Conductance mmhos/cm (on-site)1 NE 103 103 NS 129 26 38 3270 Temperature °C (on-site)-29 14 14.5 NS 15 15 16 23.4 Turbidity NTU (on-site)NT 50 NT NT NS NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NS NT NT NT ND Nitrate/Nitrite as N mg/l 0.1 NE NT NT NS NT NT NT ND Nitrite as N mg/l 0.1 NE NT NT NS NT NT NT NT Nitrogen mg/l 0.2 NE NT NT NS NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NS NT NT NT NT Sulfate mg/l 500 NE NT NT NS NT NT NT 34 Biochemical Oxygen Demand mg/l 2 NE NT NT NS NT NT NT 640 Chemical Oxygen Demand mg/l 25 NE NT NT NS NT NT NT 1300 Total Dissolved Solids mg/l 20 NE NT NT NS NT NT NT NT Cyanide mg/l 2 5 NT NT NS NT NT NT NT Total Antimony (Sb)mg/l 30 NE ND ND NS ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND NS ND ND ND 10 Total Barium (Ba)mg/l 500 NE 100 100 NS 87 24 31 160 Total Beryllium (Be)mg/l 2 6.5 ND ND NS ND 2.6 ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND NS ND 2.1 ND ND Total Chromium (Cr)mg/l 10 50 ND ND NS ND 3.7 2.3 26 Total Cobalt (Co)mg/l 10 NE ND ND NS 6.5 ND ND ND Total Copper (Cu)mg/l 200 7 ND ND NS ND ND ND ND Total Lead (Pb)mg/l 10 25 ND ND NS ND ND ND ND Total Nickel (Ni)mg/l 50 88 ND ND NS ND ND ND 24 Total Selenium (Se)mg/l 20 5 ND ND NS ND ND ND 6.2 Total Silver (Ag)mg/l 10 0.06 ND ND NS ND ND ND ND Total Thallium (Tl)mg/l 10 NE ND ND NS ND ND ND ND Total Vanadium (V)mg/l 40 NE ND ND NS ND ND ND 8.2 Total Zinc (Zn)mg/l 50 50 ND 44 NS 17 12 13 43 Mercury mg/l 0.2 0.012 NT NT NS NT NT NT NT Acetone mg/l 100 NE ND ND NS ND ND ND 290 Acrylonitrile mg/l 200 NE ND ND NS ND ND ND ND Benzene mg/l 5 51 ND ND NS ND ND ND ND Bromochloromethane mg/l 5 NE ND ND NS ND ND ND ND Bromodichloromethane mg/l 5 NE ND ND NS ND ND ND ND Bromoform mg/l 5 NE ND ND NS ND ND ND ND Carbon Disulfide mg/l 100 NE ND ND NS ND 39 32 ND Bromomethane (Methylbromide)mg/l 10 NE ND ND NS ND ND ND ND Carbon tetrachloride mg/l 10 1.6 ND ND NS ND ND ND ND Chlorobenzene (mono)mg/l 5 NE ND ND NS ND ND ND ND Chloroethane mg/l 10 NE ND ND NS ND ND ND ND Chloroform mg/l 5 NE ND ND NS ND ND ND ND Chloromethane (Methylchloride)mg/l 10 NE ND ND NS ND ND ND ND Dibromochloromethane mg/l 5 NE ND ND NS ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE ND ND NS ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE ND ND NS ND ND ND ND Dibromomethane mg/l 10 NE ND ND NS ND ND ND ND 1,2-Dichlorobenzene mg/l 5 NE ND ND NS ND ND ND ND 1,4-Dichlorobenzene mg/l 5 NE ND ND NS ND ND ND ND trans-1,4-Dichloro-2butene mg/l 100 NE ND ND NS ND ND ND ND 1,1-Dichloroethane mg/l 5 NE ND ND NS ND ND ND ND 1,2-Dichloroethane mg/l 5 NE ND ND NS ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 5 NE ND ND NS ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE ND ND NS ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 5 NE ND ND NS ND ND ND ND 1,2-Dichloropropane mg/l 5 NE ND ND NS ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND NS ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND NS ND ND ND ND Ethylbenzene mg/l 5 NE ND ND NS ND ND ND ND 2-Hexanone mg/l 50 NE ND ND NS ND ND ND ND Iodomethane mg/l 10 NE ND ND NS ND ND ND ND Dichloromethane (Methylene chloride)mg/l 10 NE ND ND NS ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 100 NE ND ND NS ND ND ND 260 4-Methyl-2-Pentanone mg/l 100 NE ND ND NS ND ND ND ND Styrene mg/l 10 NE ND ND NS ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND NS ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 5 4 ND ND NS ND ND ND ND Tetrachloroethene (-ethylene)mg/l 5 3.3 ND ND NS ND ND ND ND Toluene mg/l 5 0.36 ND ND NS ND ND ND ND 1,1,1-Trichloroethane mg/l 5 NE ND ND NS ND ND ND ND 1,1,2-Trichloroethane mg/l 5 NE ND ND NS ND ND ND ND Trichloroethene (-ethylene)mg/l 5 30 ND ND NS ND ND ND ND Trichlorofluoromethane mg/l 5 NE ND ND NS ND ND ND ND 1,2,3-Trichloropropane mg/l 15 NE ND ND NS ND ND ND ND Vinyl acetate mg/l 50 NE ND ND NS ND ND ND ND Vinyl chloride mg/l 10 2.4 ND ND NS ND ND ND ND Xylene mg/l 5 NE ND ND NS ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (10-21-2004) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-18-2005) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.49 5.99 6.21 7.05 7.08 7.27 7.28 Specific Conductance mmhos/cm (on-site)1 NE 79 88 151 120 21 28 6500 Temperature °C (on-site)-29 13 123 13.5 16 14.1 13 19 Turbidity NTU (on-site)NT 50 NT NT NT NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT ND Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT ND Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT NT Nitrogen mg/l 0.2 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 500 NE NT NT NT NT NT NT 1300 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 300 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 760 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 30 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND 22 Total Barium (Ba)mg/l 500 NE 100 120 98 79 24 28 390 Total Beryllium (Be)mg/l 2 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 10 50 ND ND ND ND ND ND 31 Total Cobalt (Co)mg/l 10 NE ND ND ND ND ND ND 14 Total Copper (Cu)mg/l 200 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 10 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 50 88 ND ND ND ND ND ND 50 Total Selenium (Se)mg/l 20 5 ND ND ND ND ND ND 7.4 Total Silver (Ag)mg/l 10 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 10 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 40 NE ND ND ND ND ND ND 17 Total Zinc (Zn)mg/l 50 50 ND 50 22 34 ND ND 150 Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 100 NE ND ND ND ND ND ND 240 Acrylonitrile mg/l 200 NE ND ND ND ND ND ND ND Benzene mg/l 5 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 5 NE ND ND ND ND ND ND ND Bromoform mg/l 5 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 100 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 10 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 10 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 5 NE ND ND ND ND ND ND ND Chloroethane mg/l 10 NE ND ND ND ND ND ND ND Chloroform mg/l 5 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 10 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE ND ND ND ND ND ND ND Dibromomethane mg/l 10 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 5 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 5 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2butene mg/l 100 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND ND ND ND 11 trans-1,2-Dichloroethene (-ylene)mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 5 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 5 NE ND ND ND ND ND ND 11 2-Hexanone mg/l 50 NE ND ND ND ND ND ND ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 10 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 100 NE ND ND ND ND ND ND 410 4-Methyl-2-Pentanone mg/l 100 NE ND ND ND ND ND ND 40 Styrene mg/l 10 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 5 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 5 3.3 ND ND ND ND ND ND ND Toluene mg/l 5 0.36 ND ND ND ND ND ND 63 1,1,1-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 5 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 5 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 15 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 50 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 10 2.4 ND ND ND ND ND ND ND Xylene mg/l 5 NE ND ND ND ND ND ND 43 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (4-18-2005) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-13-2005) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.11 6.72 7.18 6.28 6.76 8.13 8.01 Specific Conductance mmhos/cm (on-site)1 NE 89 90 240 340 91 31 6500 Temperature °C (on-site)-29 15.7 16.9 16.9 18.9 18.7 15.2 21.1 Turbidity NTU (on-site)NT 50 NT NT NT NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT ND Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT ND Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT ND Nitrogen mg/l 0.2 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 500 NE NT NT NT NT NT NT 1300 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 720 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 920 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 30 NE NT NT NT ND NT NT NT Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND 16 Total Barium (Ba)mg/l 500 NE 120 96 140 90 86 36 430 Total Beryllium (Be)mg/l 2 6.5 NT NT NT ND NT NT NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 10 50 ND ND ND 4.2 ND ND 50 Total Cobalt (Co)mg/l 10 NE NT NT NT 6.8 NT NT NT Total Copper (Cu)mg/l 200 7 NT NT NT 2.4 NT NT NT Total Lead (Pb)mg/l 10 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 50 88 NT NT NT ND NT NT NT Total Selenium (Se)mg/l 20 5 ND ND ND ND ND ND 9.2 Total Silver (Ag)mg/l 10 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 10 NE NT NT NT ND NT NT NT Total Vanadium (V)mg/l 40 NE NT NT NT ND NT NT NT Total Zinc (Zn)mg/l 50 50 NT NT NT 33 NT NT NT Mercury mg/l 0.2 0.012 NT NT NT NT NT NT ND Acetone mg/l 100 NE ND ND ND ND ND ND ND Acrylonitrile mg/l 200 NE ND ND ND ND ND ND ND Benzene mg/l 5 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 5 NE ND ND ND ND ND ND ND Bromoform mg/l 5 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 100 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 10 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 10 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 5 NE ND ND ND ND ND ND ND Chloroethane mg/l 10 NE ND ND ND ND ND ND ND Chloroform mg/l 5 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 10 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE ND ND ND ND ND ND ND Dibromomethane mg/l 10 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 5 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 5 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2butene mg/l 100 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 5 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 5 NE ND ND ND ND ND ND ND 2-Hexanone mg/l 50 NE ND ND ND ND ND ND ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 10 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 100 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 100 NE ND ND ND ND ND ND ND Styrene mg/l 10 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 5 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 5 3.3 ND ND ND ND ND ND ND Toluene mg/l 5 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 5 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 5 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 15 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 50 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 10 2.4 ND ND ND ND ND ND ND Xylene mg/l 5 NE ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (10-13-2005) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-25-2006) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.07 7.11 7.18 6.73 6.45 6.28 7.55 Specific Conductance mmhos/cm (on-site)1 NE 107 138 340 201 45 53 8660 Temperature °C (on-site)-29 14.1 13.8 15.6 18.6 14.8 14.3 17.1 Turbidity NTU (on-site)NT 50 NT NT NT NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 2.4 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 2.4 Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT NT Nitrogen mg/l 0.2 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 500 NE NT NT NT NT NT NT 2400 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 51 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 700 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 30 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND 18 Total Barium (Ba)mg/l 500 NE ND ND ND ND ND ND 580 Total Beryllium (Be)mg/l 2 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 10 50 ND ND ND ND ND ND 40 Total Cobalt (Co)mg/l 10 NE ND ND ND ND ND ND 15 Total Copper (Cu)mg/l 200 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 10 25 ND ND ND 11 ND ND ND Total Nickel (Ni)mg/l 50 88 ND ND ND ND ND ND 56 Total Selenium (Se)mg/l 20 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 10 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 10 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 40 NE ND ND ND ND ND ND ND Total Zinc (Zn)mg/l 50 50 ND ND ND ND ND ND 130 Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 100 NE ND ND ND ND ND ND ND Acrylonitrile mg/l 200 NE ND ND ND ND ND ND ND Benzene mg/l 5 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 5 NE ND ND ND ND ND ND ND Bromoform mg/l 5 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 100 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 10 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 10 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 5 NE ND ND ND ND ND ND ND Chloroethane mg/l 10 NE ND ND ND ND ND ND ND Chloroform mg/l 5 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 10 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE ND ND ND ND ND ND ND Dibromomethane mg/l 10 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 5 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 5 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2butene mg/l 100 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 5 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 5 NE ND ND ND ND ND ND 6.2 2-Hexanone mg/l 50 NE ND ND ND ND ND ND ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 10 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 100 NE ND ND ND ND ND ND 24 4-Methyl-2-Pentanone mg/l 100 NE ND ND ND ND ND ND 15 Styrene mg/l 10 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 5 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 5 3.3 ND ND ND ND ND ND ND Toluene mg/l 5 0.36 ND ND ND ND ND ND 12 1,1,1-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 5 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 5 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 15 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 50 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 10 2.4 ND ND ND ND ND ND ND Xylene mg/l 5 NE ND ND ND ND ND ND 16.1 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (4-25-2006) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-16-2006) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.53 7.1 NT 7.14 6.64 7.13 8.11 Specific Conductance mmhos/cm (on-site)1 NE 123 139 NT 200 46 40 9800 Temperature °C (on-site)-29 11.9 10.9 NT 11.9 13.4 11.3 19.6 Turbidity NTU (on-site)NT 50 NT NT NT NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 0.58 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT ND Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT ND Nitrogen mg/l 0.2 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 500 NE NT NT NT NT NT NT 2100 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 61 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 780 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 30 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND 18 Total Barium (Ba)mg/l 500 NE 120 140 120 240 54 33 430 Total Beryllium (Be)mg/l 2 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND 5.8 ND ND ND Total Chromium (Cr)mg/l 10 50 ND ND ND 21 ND ND 54 Total Cobalt (Co)mg/l 10 NE ND ND ND ND 7.4 ND 14 Total Copper (Cu)mg/l 200 7 ND ND ND 23 ND ND ND Total Lead (Pb)mg/l 10 25 ND ND ND 18 ND ND ND Total Nickel (Ni)mg/l 50 88 ND ND ND 8.4 ND ND 68 Total Selenium (Se)mg/l 20 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 10 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 10 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 40 NE ND ND ND 62 ND ND 18 Total Zinc (Zn)mg/l 50 50 ND 39 22 130 ND ND 63 Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 100 NE ND ND ND ND ND ND ND Acrylonitrile mg/l 200 NE ND ND ND ND ND ND ND Benzene mg/l 5 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 5 NE ND ND ND ND ND ND ND Bromoform mg/l 5 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 100 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 10 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 10 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 5 NE ND ND ND ND ND ND ND Chloroethane mg/l 10 NE ND ND ND ND ND ND ND Chloroform mg/l 5 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 10 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE ND ND ND ND ND ND ND Dibromomethane mg/l 10 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 5 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 5 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2butene mg/l 100 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 5 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 5 NE ND ND ND ND ND ND ND 2-Hexanone mg/l 50 NE ND ND ND ND ND ND ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 10 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 100 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 100 NE ND ND ND ND ND ND ND Styrene mg/l 10 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 5 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 5 3.3 ND ND ND ND ND ND ND Toluene mg/l 5 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 5 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 5 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 15 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 50 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 10 2.4 ND ND ND ND ND ND ND Xylene mg/l 5 NE ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (10-16-2006) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-23-2007) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 NT NT NT NT NT NT NT Specific Conductance mmhos/cm (on-site)1 NE NT NT NT NT NT NT NT Temperature °C (on-site)-29 NT NT NT NT NT NT NT Turbidity NTU (on-site)NT 50 NT NT NT NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 0.38 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT NT Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT ND Nitrogen mg/l 0.2 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 500 NE NT NT NT NT NT NT 2400 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 89 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 1000 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 30 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND 16 Total Barium (Ba)mg/l 500 NE 100 120 250 ND ND ND 380 Total Beryllium (Be)mg/l 2 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 10 50 ND ND ND ND ND ND 46 Total Cobalt (Co)mg/l 10 NE ND ND ND ND ND ND ND Total Copper (Cu)mg/l 200 7 ND ND ND 38 ND ND ND Total Lead (Pb)mg/l 10 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 50 88 ND ND ND ND ND ND 50 Total Selenium (Se)mg/l 20 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 10 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 10 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 40 NE ND ND ND ND ND ND ND Total Zinc (Zn)mg/l 50 50 13 37 130 91 15 11 80 Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 100 NE ND ND ND ND ND ND ND Acrylonitrile mg/l 200 NE ND ND ND ND ND ND ND Benzene mg/l 5 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 5 NE ND ND ND ND ND ND ND Bromoform mg/l 5 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 100 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 10 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 10 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 5 NE ND ND ND ND ND ND ND Chloroethane mg/l 10 NE ND ND ND ND ND ND ND Chloroform mg/l 5 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 10 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE ND ND ND ND ND ND ND Dibromomethane mg/l 10 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 5 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 5 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2butene mg/l 100 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 5 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 5 NE ND ND ND ND ND ND 10 2-Hexanone mg/l 50 NE ND ND ND ND ND ND ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 10 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 100 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 100 NE ND ND ND ND ND ND ND Styrene mg/l 10 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 5 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 5 3.3 ND ND ND ND ND ND ND Toluene mg/l 5 0.36 ND ND ND ND ND ND 46 1,1,1-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 5 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 5 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 15 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 50 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 10 2.4 ND ND ND ND ND ND ND Xylene mg/l 5 NE ND ND ND ND ND ND 31.3 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (4-23-2007) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-31-07) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.04 7.11 6.8 7.5 6.35 6.74 8.03 Specific Conductance mmhos/cm (on-site)1 NE 156 150 266 320 61 40 1282 Temperature °C (on-site)-29 16.5 13.4 12.7 17.2 11.5 9 14.3 Turbidity NTU (on-site)NT 50 NT NT NT NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT NT Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT NT Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT NT Nitrogen mg/l 0.1 NE NT NT NT NT NT NT 0.53 Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 500 NE NT NT NT NT NT NT 3010 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 221 Chemical Oxygen Demand mg/l 100 NE NT NT NT NT NT NT 968 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND 24.6 Total Barium (Ba)mg/l 5 NE 583 154 162 85 111 30.3 436 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 25.7 ND ND ND ND ND 74.1 Total Cobalt (Co)mg/l 5 NE 10.5 ND ND ND ND ND 12 Total Copper (Cu)mg/l 5 7 18.4 ND ND ND 8.3 ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 18.1 ND ND ND ND ND 81.2 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.5 NE 6.3 ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE 56.2 ND ND 6.8 11.4 ND 23.9 Total Zinc (Zn)mg/l 10 50 135 71.9 60 41.3 20.4 ND 76.7 Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND Benzene mg/l 1 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2butene mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Xylene mg/l 2 NE ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (10-31-07) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (04-23-08) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.8 7.32 7.06 7.2 7.56 7 8.56 Specific Conductance mmhos/cm (on-site)1 NE 124 162 234 426 48 42 8140 Temperature °C (on-site)-29 13.1 14.5 14.3 16.9 15.2 15.6 21.4 Turbidity NTU (on-site)NT 50 NT NT NT NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT ND Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT NT Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT ND Nitrogen mg/l 0.1 NE NT NT NT NT NT NT ND Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 500 NE NT NT NT NT NT NT 1940 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 741 Chemical Oxygen Demand mg/l 100 NE NT NT NT NT NT NT 1620 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND 9.5 Total Barium (Ba)mg/l 5 NE 111 145 133 184 34.4 24.9 247 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND 1.5 ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND 6.5 ND ND 28.9 Total Cobalt (Co)mg/l 5 NE ND ND ND 11.2 ND ND 9 Total Copper (Cu)mg/l 5 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND 7.6 ND ND 51.3 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.5 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND 14.4 ND ND 9.1 Total Zinc (Zn)mg/l 10 50 ND 52.3 50.1 124 ND ND 52.3 Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND 34.1 Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND Benzene mg/l 1 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2butene mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Xylene mg/l 2 NE ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (04-23-08) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-21-08) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.51 6.75 6.84 6.54 6.08 6.45 8.63 Specific Conductance mmhos/cm (on-site)1 NE 202 171 296 205.6 56.1 41 10780 Temperature °C (on-site)-29 11.3 10.2 7.9 12.5 10.8 9.6 22.2 Turbidity NTU (on-site)NT 50 NT NT NT NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT ND Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT NT Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.14 Nitrogen mg/l 0.1 NE NT NT NT NT NT NT 0.14 Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 500 NE NT NT NT NT NT NT 58.3 Biochemical Oxygen Dema mg/l 2 NE NT NT NT NT NT NT 198 Chemical Oxygen Dema mg/l 100 NE NT NT NT NT NT NT 1190 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND 6 6.7 ND ND Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND 11.4 Total Barium (Ba)mg/l 5 NE 285 126 137 289 145 25.2 317 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND 17.9 ND ND 34.5 Total Cobalt (Co)mg/l 5 NE 7.9 5 6.4 34.4 21.1 ND 14.4 Total Copper (Cu)mg/l 5 7 ND ND ND 15.8 10.1 ND ND Total Lead (Pb)mg/l 5 25 ND ND ND 5.4 ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND 12.1 6 ND 57.6 Total Selenium (Se)mg/l 10 5 ND ND ND 14 13.2 ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND 7.2 ND ND ND Total Vanadium (V)mg/l 5 NE 9.9 ND ND 43.5 17.5 ND 12 Total Zinc (Zn)mg/l 10 50 19 75.4 39.4 116 29.5 16.7 27.6 Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND 37.2 Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND Benzene mg/l 1 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2butene mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Xylene mg/l 2 NE ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters a Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (10-21-08) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-22-09) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.29 6.47 6.79 6.75 5.83 5.97 8.24 Specific Conductance mmhos/cm (on-site)1 NE 139 208 319 366 40 52 7620 Temperature °C (on-site)-29 11.1 10.8 9.8 12.2 11.9 12.6 19.6 Turbidity NTU (on-site)NT 50 NT NT NT NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 0.16 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.29 Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.12 Nitrogen mg/l 0.1 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 500 NE NT NT NT NT NT NT 1570 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 55.8 Chemical Oxygen Demand mg/l 100 NE NT NT NT NT NT NT 694 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND 11.3 Total Barium (Ba)mg/l 5 NE 108 167 133 70.1 35.9 41.1 181 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND ND ND ND 16.7 Total Cobalt (Co)mg/l 5 NE ND ND ND 14.9 6.5 6.6 9.8 Total Copper (Cu)mg/l 5 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND 5.6 ND ND 48.2 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND 8.1 ND ND 11.2 Total Zinc (Zn)mg/l 10 50 ND 50 36.6 80 ND ND 10.9 Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND 38.4 Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND Benzene mg/l 1 51 ND ND ND ND ND ND 5.2 Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND 13.7 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND 11.3 Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND 7.3 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND 65.1 Methyl-tert-butyl-ether (MTBE)mg/l 1 NE NT NT NT NT NT NT 9.0 Naphthalene mg/l 1 NE NT NT NT NT NT NT 6.7 Phosphorus mg/l 0.1 NE NT NT NT NT NT NT 0.75 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters a Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (4-22-09) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-26-09) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.41 Dry 6.49 Dry 6.07 6.26 7.8 Specific Conductance mmhos/cm (on-site)1 NE 192 Dry 291 Dry 60 58 NT Temperature °C (on-site)-29 11.5 Dry 11.0 Dry 13.6 12.4 NT Turbidity NTU (on-site)NT 50 NT Dry NT Dry NT NT NT Nitrate as N mg/l 0.1 NE NT Dry NT Dry NT NT NT Nitrate/Nitrite as N mg/l 0.1 NE NT Dry NT Dry NT NT NT Nitrite as N mg/l 0.1 NE NT Dry NT Dry NT NT NT Nitrogen mg/l 0.1 NE NT Dry NT Dry NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT Dry NT Dry NT NT NT Sulfate mg/l 500 NE NT Dry NT Dry NT NT NT Biochemical Oxygen Demand mg/l 2 NE NT Dry NT Dry NT NT 4.8 Chemical Oxygen Demand mg/l 100 NE NT Dry NT Dry NT NT 212 Total Dissolved Solids mg/l 20 NE NT Dry NT Dry NT NT NT Cyanide mg/l 2 5 NT Dry NT Dry NT NT NT Total Antimony (Sb)mg/l 5 NE ND Dry ND Dry ND ND ND Total Arsenic (As)mg/l 5 10 ND Dry ND Dry ND ND ND Total Barium (Ba)mg/l 5 NE 228 Dry 285 Dry 48.4 30.9 305 Total Beryllium (Be)mg/l 1 6.5 ND Dry ND Dry ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND Dry ND Dry ND ND ND Total Chromium (Cr)mg/l 5 50 ND Dry 8.9 Dry ND ND ND Total Cobalt (Co)mg/l 5 NE ND Dry 5.7 Dry 6.5 ND 12.5 Total Copper (Cu)mg/l 5 7 ND Dry 5.5 Dry ND ND ND Total Lead (Pb)mg/l 5 25 ND Dry ND Dry ND ND ND Total Nickel (Ni)mg/l 5 88 ND Dry 10.1 Dry ND ND 20.4 Total Selenium (Se)mg/l 10 5 ND Dry ND Dry ND ND ND Total Silver (Ag)mg/l 5 0.06 ND Dry ND Dry ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND Dry ND Dry ND ND ND Total Vanadium (V)mg/l 5 NE ND Dry 16.0 Dry ND ND 8.5 Total Zinc (Zn)mg/l 10 50 ND Dry 151 Dry ND ND 48.1 Mercury mg/l 0.2 0.012 NT Dry NT Dry NT NT NT Acetone mg/l 25 NE ND Dry ND Dry ND ND ND Acrylonitrile mg/l 10 NE ND Dry ND Dry ND ND ND Benzene mg/l 1 51 ND Dry ND Dry ND ND ND Bromochloromethane mg/l 1 NE ND Dry ND Dry ND ND ND Bromodichloromethane mg/l 1 NE ND Dry ND Dry ND ND ND Bromoform mg/l 1 NE ND Dry ND Dry ND ND ND Carbon Disulfide mg/l 2 NE ND Dry ND Dry ND ND ND Bromomethane (Methylbromide)mg/l 5 NE ND Dry ND Dry ND ND ND Carbon tetrachloride mg/l 1 1.6 ND Dry ND Dry ND ND ND Chlorobenzene (mono)mg/l 1 NE ND Dry ND Dry ND ND ND Chloroethane mg/l 1 NE ND Dry ND Dry ND ND ND Chloroform mg/l 1 NE ND Dry ND Dry ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND Dry ND Dry ND ND ND Dibromochloromethane mg/l 1 NE ND Dry ND Dry ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 NE ND Dry ND Dry ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND Dry ND Dry ND ND ND Dibromomethane mg/l 1 NE ND Dry ND Dry ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND Dry ND Dry ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND Dry ND Dry ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND Dry ND Dry ND ND ND 1,1-Dichloroethane mg/l 1 NE ND Dry ND Dry ND ND ND 1,2-Dichloroethane mg/l 1 NE ND Dry ND Dry ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND Dry ND Dry ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND Dry ND Dry ND ND ND trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND Dry ND Dry ND ND ND 1,2-Dichloropropane mg/l 1 NE ND Dry ND Dry ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND Dry ND Dry ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND Dry ND Dry ND ND ND Ethylbenzene mg/l 1 NE ND Dry ND Dry ND ND ND 2-Hexanone mg/l 5 NE ND Dry ND Dry ND ND ND Iodomethane mg/l 5 NE ND Dry ND Dry ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND Dry ND Dry ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND Dry ND Dry ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND Dry ND Dry ND ND ND Styrene mg/l 1 NE ND Dry ND Dry ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND Dry ND Dry ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND Dry ND Dry ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND Dry ND Dry ND ND ND Toluene mg/l 1 0.36 ND Dry ND Dry ND ND ND 1,1,1-Trichloroethane mg/l 1 NE ND Dry ND Dry ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND Dry ND Dry ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND Dry ND Dry ND ND ND Trichlorofluoromethane mg/l 1 NE ND Dry ND Dry ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND Dry ND Dry ND ND ND Vinyl acetate mg/l 2 NE ND Dry ND Dry ND ND ND Vinyl chloride mg/l 1 2.4 ND Dry ND Dry ND ND ND Total Xylenes mg/l 2 NE ND Dry ND Dry ND ND ND Methyl-tert-butyl-ether (MTBE)mg/l 5 NE NT Dry NT Dry NT NT ND Naphthalene mg/l 5 NE NT Dry NT Dry NT NT ND Phosphorus mg/l 0.1 NE NT Dry NT Dry NT NT NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters a Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (10-26-09) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-21-10) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.72 7.29 7.14 NP 6.06 6.04 7.69 Specific Conductance mmhos/cm (on-site)1 NE 189 213 273 NP 94 106 310 Temperature °C (on-site)-29 13.9 12.3 15.9 NP 15.7 14 13.3 Turbidity NTU (on-site)NT 50 NT NT NT NP NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NP NT NT ND Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NP NT NT ND Nitrite as N mg/l 0.1 NE NT NT NT NP NT NT ND Nitrogen mg/l 0.1 NE NT NT NT NP NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NP NT NT NT Sulfate mg/l 75 NE NT NT NT NP NT NT 477 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NP NT NT 54 Chemical Oxygen Demand mg/l 25 NE NT NT NT NP NT NT 203 Total Dissolved Solids mg/l 20 NE NT NT NT NP NT NT NT Cyanide mg/l 2 5 NT NT NT NP NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND NP ND ND ND Total Arsenic (As)mg/l 5 10 ND ND ND NP ND ND 8.6 Total Barium (Ba)mg/l 5 NE 123 178 172 NP 34.3 41.4 124 Total Beryllium (Be)mg/l 1 6.5 ND ND ND NP ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND NP ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND NP ND ND 8 Total Cobalt (Co)mg/l 5 NE ND ND ND NP ND ND 11.7 Total Copper (Cu)mg/l 5 7 ND ND ND NP ND ND 6.8 Total Lead (Pb)mg/l 5 25 ND ND ND NP ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND NP ND ND 35.3 Total Selenium (Se)mg/l 10 5 ND ND ND NP ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND NP ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND NP ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND NP ND ND 6.8 Total Zinc (Zn)mg/l 10 50 ND 49.8 32.9 NP ND ND 12.1 Mercury mg/l 0.2 0.012 NT NT NT NP NT NT NT Acetone mg/l 25 NE ND ND ND NP ND ND ND Acrylonitrile mg/l 10 NE ND ND ND NP ND ND NT Benzene mg/l 1 51 ND ND ND NP ND ND ND Bromochloromethane mg/l 1 NE ND ND ND NP ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND NP ND ND ND Bromoform mg/l 1 NE ND ND ND NP ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND NP ND ND NT Bromomethane (Methylbromide)mg/l 5 NE ND ND ND NP ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND NP ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND NP ND ND ND Chloroethane mg/l 1 NE ND ND ND NP ND ND ND Chloroform mg/l 1 NE ND ND ND NP ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND NP ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND NP ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 NE ND ND ND NP ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND NP ND ND ND Dibromomethane mg/l 1 NE ND ND ND NP ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND NP ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND NP ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND NP ND ND NT 1,1-Dichloroethane mg/l 1 NE ND ND ND NP ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND NP ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND NP ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND NP ND ND 2 trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND NP ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND NP ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND NP ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND NP ND ND ND Ethylbenzene mg/l 1 NE ND ND ND NP ND ND ND 2-Hexanone mg/l 5 NE ND ND ND NP ND ND ND Iodomethane mg/l 5 NE ND ND ND NP ND ND NT Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND NP ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND NP ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND NP ND ND ND Styrene mg/l 1 NE ND ND ND NP ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND NP ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND NP ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND NP ND ND ND Toluene mg/l 1 0.36 ND ND ND NP ND ND 1.1 1,1,1-Trichloroethane mg/l 1 NE ND ND ND NP ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND NP ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND NP ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND NP ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND NP ND ND ND Vinyl acetate mg/l 2 NE ND ND ND NP ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND NP ND ND ND Total Xylenes mg/l 2 NE ND ND ND NP ND ND NT Methyl-tert-butyl-ether (MTBE)mg/l 1 NE NT NT NT NP NT NT ND Naphthalene mg/l 1 NE NT NT NT NP NT NT ND Phosphorus mg/l 0.1 NE NT NT NT NP NT NT 0.26 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters a Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (4-21-10) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-26-10) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.31 6.14 7.15 6.11 5.7 6.39 7.31 Specific Conductance mmhos/cm (on-site)1 NE 203 250 287 158 50 53 20400 Temperature °C (on-site)-29 15.8 15.2 16.6 17.5 14.7 13.4 18.2 Turbidity NTU (on-site)NT 50 NT NT NT NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 5.5 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 6 Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.51 Nitrogen mg/l 0.1 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 75 NE NT NT NT NT NT NT 7670 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 40 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 96 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND 13.9 Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND 29.4 Total Barium (Ba)mg/l 5 NE 209 180 350 126 40.1 32.9 172 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND 1.3 Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND 13.2 ND ND ND 10.7 Total Cobalt (Co)mg/l 5 NE ND ND 17.7 48.8 ND ND ND Total Copper (Cu)mg/l 5 7 ND ND 9 ND ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND 9 5 ND ND 44.4 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND 29.6 Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND 27.9 ND ND ND 21 Total Zinc (Zn)mg/l 10 50 ND 31.2 60.6 ND ND ND ND Mercury mg/l 0.2 0.012 NT NT NT ND NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND NT Benzene mg/l 1 51 ND ND ND ND ND ND 1 Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND NT Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND 3.4 trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND NT 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND 1.2 trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND 6.8 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND NT Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND 8.4 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND NT m&p-Xylenes mg/l 2 NE ND ND ND ND ND ND 10.9 o-Xylenes mg/l 1 NE ND ND ND ND ND ND 5.7 Methyl-tert-butyl-ether (MTBE)mg/l 1 NE NT NT NT NT NT NT 2.9 Naphthalene mg/l 1 NE NT NT NT NT NT NT 6.5 p-isopropyltoluene mg/l 1 NE NT NT NT NT NT NT 2.9 Phosphorus mg/l 0.1 NE NT NT NT NT NT NT 1.40 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters a Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (10-26-10) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-28-11) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.3 6.2 6.8 6 5.8 6.1 7.4 Specific Conductance mmhos/cm (on-site)1 NE 174 225 304 212 45 65 14,320 Temperature °C (on-site)-29 15.9 14.9 18.5 13.5 15.1 13.3 18.3 Turbidity NTU (on-site)NT 50 NT NT NT NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 8.5 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 9.6 Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 1.1 Nitrogen mg/l 0.1 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 75 NE NT NT NT NT NT NT 4360 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 55.2 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 762 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND 13.5 Total Barium (Ba)mg/l 5 NE 238 204 130 156 38.7 43.6 243 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 5.2 ND ND ND ND ND 27.1 Total Cobalt (Co)mg/l 5 NE ND 5.4 ND 22.6 ND ND 32.6 Total Copper (Cu)mg/l 5 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND ND ND ND 159 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE 11 ND ND ND ND ND 9.4 Total Zinc (Zn)mg/l 10 50 15.8 46.1 61.7 ND ND ND 32.1 Mercury mg/l 0.2 0.012 NT NT NT ND NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND 40.6 Acrylonitrile mg/l 10 NE ND ND ND ND ND ND NT Benzene mg/l 1 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND NT Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND 2.7 trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND NT 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND 6 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND NT Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND 1.2 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND 4.5 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND NT m&p-Xylenes mg/l 2 NE ND ND ND ND ND ND 3.5 o-Xylenes mg/l 1 NE ND ND ND ND ND ND 3.8 Methyl-tert-butyl-ether (MTBE)mg/l 1 NE NT NT NT NT NT NT 1.6 Naphthalene mg/l 1 NE NT NT NT NT NT NT 5.3 p-isopropyltoluene mg/l 1 NE NT NT NT NT NT NT 1.8 Phosphorus mg/l 0.05 NE NT NT NT NT NT NT 0.85 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters a Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (4-28-11) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-25-11) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.2 6.7 7.2 6 5.7 6.2 6.9 Specific Conductance mmhos/cm (on-site)1 NE 207 208 275 241 42 17 272 Temperature °C (on-site)-29 10.4 11.9 11.7 17.2 15.8 13 11.7 Turbidity NTU (on-site)NT 50 7.92 19.0 8.08 15.5 5.52 6.19 6.35 Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 0.85 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT NT Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.17 Nitrogen mg/l 0.1 NE NT NT NT NT NT NT 1 Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 75 NE NT NT NT NT NT NT 5170 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 63.9 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 908 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND 7.2 Total Barium (Ba)mg/l 5 NE 170 168 126 140 32.7 30.7 261 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND ND ND ND 35.4 Total Cobalt (Co)mg/l 5 NE ND 5 5 28.8 ND ND 19.7 Total Copper (Cu)mg/l 5 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND ND ND ND 170 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND ND ND ND 14.0 Total Zinc (Zn)mg/l 10 50 ND 33.6 56.1 ND ND ND 18.0 Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND 43.9 Acrylonitrile mg/l 10 NE ND ND ND ND ND ND NT Benzene mg/l 1 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND NT Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND NT 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND 1.0 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND NT Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND 1.5 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND NT m&p-Xylenes mg/l 2 NE ND ND ND ND ND ND 3.5 o-Xylenes mg/l 1 NE ND ND ND ND ND ND 2.3 Methyl-tert-butyl-ether (MTBE)mg/l 1 NE NT NT NT NT NT NT 1.5 Naphthalene mg/l 1 NE NT NT NT NT NT NT 1.6 p-isopropyltoluene mg/l 1 NE NT NT NT NT NT NT ND Phosphorus mg/l 0.05 NE NT NT NT NT NT NT 1.20 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters a Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (10-25-11) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-20-12) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.0 6.8 7.8 6.3 6.4 7.0 7.6 Specific Conductance mmhos/cm (on-site)1 NE 146 218.4 261.2 111 41.3 65.8 260.4 Temperature °C (on-site)-29 15.1 14.2 16.8 15.3 14.9 13.5 16.5 Turbidity NTU (on-site)NT 50 12.5 6.1 15.9 4.84 4.06 6.43 5.71 Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 8.6 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT NT Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.52 Nitrogen mg/l 0.1 NE NT NT NT NT NT NT 8.6 Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 75 NE NT NT NT NT NT NT 299 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 20.5 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 154 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 NE 103 177 90.8 121 35.2 40.5 85.2 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND ND ND ND 6 Total Cobalt (Co)mg/l 5 NE ND ND ND 14.4 ND ND 7.6 Total Copper (Cu)mg/l 5 7 ND ND ND ND ND ND 7.7 Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND ND ND ND 33.3 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND ND ND ND ND Total Zinc (Zn)mg/l 10 50 ND 37.6 15 ND ND ND 21.5 Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND NT Benzene mg/l 1 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND NT Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND NT 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND NT Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND NT m&p-Xylenes mg/l 2 NE ND ND ND ND ND ND ND o-Xylenes mg/l 1 NE ND ND ND ND ND ND ND Methyl-tert-butyl-ether (MTBE)mg/l NT NE NT NT NT NT NT NT NT Naphthalene mg/l NT NE NT NT NT NT NT NT NT p-isopropyltoluene mg/l NT NE NT NT NT NT NT NT NT Phosphorus mg/l 0.05 NE NT NT NT NT NT NT 0.28 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters a Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (4-20-12) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-24-12) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.1 6.9 7.9 6.2 6.1 7.2 7.5 Specific Conductance mmhos/cm (on-site)1 NE 217 272 329 227 39 54 16,940.0 Temperature °C (on-site)-29 13.6 14.5 13.9 17.5 13.1 11.9 19.9 Turbidity NTU (on-site)NT 50 7.38 3.6 6.16 30.5 1.97 3.39 19.6 Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 0.18 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT NT Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.075 Nitrogen mg/l 0.1 NE NT NT NT NT NT NT 0.26 Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 75 NE NT NT NT NT NT NT 5100 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 53.3 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 860 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND 14 Total Barium (Ba)mg/l 5 NE 172 175 124 164 38.7 31.2 390 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND ND ND ND 32.6 Total Cobalt (Co)mg/l 5 NE ND ND ND 20.2 ND ND 19 Total Copper (Cu)mg/l 5 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND ND ND ND 166 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND ND ND ND 16.0 Total Zinc (Zn)mg/l 10 50 ND 28.5 10.7 ND ND ND ND Mercury mg/l 0.2 0.012 ND ND ND ND ND ND ND Acetone mg/l 25 NE ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND Benzene mg/l 1 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND 1.8 trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND 3.1 m&p-Xylenes mg/l 2 NE ND ND ND ND ND ND ND o-Xylenes mg/l 1 NE NT NT NT NT NT NT 1.4 Methyl-tert-butyl-ether (MTBE)mg/l NT NE NT NT NT NT NT NT NT Naphthalene mg/l NT NE NT NT NT NT NT NT NT p-isopropyltoluene mg/l NT NE NT NT NT NT NT NT NT Phosphorus mg/l 0.05 NE NT NT NT NT NT NT 0.87 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters a Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (10-24-12) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-24-13) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.1 7.5 7.4 6.3 6.5 6.8 7.6 Specific Conductance mmhos/cm (on-site)1 NE 180 183 274 249 42 63 15,320 Temperature °C (on-site)-29 13.6 13 14.1 15.4 15.2 13.2 15.1 Turbidity NTU (on-site)NT 50 7.06 6.9 4.23 5.06 0.37 2.11 15 Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 0.098 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.15 Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.056 Nitrogen mg/l 0.1 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 75 NE NT NT NT NT NT NT 3830 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 107 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 866 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 NE 159 146 148 114 34.8 33 436 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND ND ND ND 27.3 Total Cobalt (Co)mg/l 5 NE ND ND 5.8 29.3 ND ND 17.8 Total Copper (Cu)mg/l 5 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND ND ND ND 130 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND ND ND ND 13.0 Total Zinc (Zn)mg/l 10 50 ND 46.2 19 ND ND ND ND Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND 150 Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND Benzene mg/l 1 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND 2.5 trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND 2.0 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND 157 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND 5 m&p-Xylenes mg/l 2 NE ND ND ND ND ND ND 3 o-Xylenes mg/l 1 NE ND ND ND ND ND ND 2 Methyl-tert-butyl-ether (MTBE)mg/l NT NE NT NT NT NT NT NT NT Naphthalene mg/l NT NE NT NT NT NT NT NT NT p-isopropyltoluene mg/l NT NE NT NT NT NT NT NT NT Phosphorus mg/l 0.05 NE NT NT NT NT NT NT 1.1 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (4-24-13) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-24-13) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.4 6.9 7.5 6.3 6.3 6.8 7.6 Specific Conductance mmhos/cm (on-site)1 NE 238 280.6 329.7 281.7 38 67 14,800 Temperature °C (on-site)-29 11.2 11.7 10.8 16.7 11.1 9.6 15 Turbidity NTU (on-site)NT 50 25.2 2.05 2.96 3.28 1.19 2.24 200 Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 0.2 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.25 Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.044 Nitrogen mg/l 0.1 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 75 NE NT NT NT NT NT NT 4.1 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 52.8 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 920 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 NE 205 209 161 138 36.7 31 438 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND ND ND ND 32.4 Total Cobalt (Co)mg/l 5 NE 5.1 7.9 ND 37.8 ND ND 27.8 Total Copper (Cu)mg/l 5 7 ND ND ND 5.7 ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND ND ND ND 140 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE 7.3 ND ND ND ND ND 12.8 Total Zinc (Zn)mg/l 10 50 ND 33.2 13.3 ND ND ND ND Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND Benzene mg/l 1 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND 1.9 trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND 1.1 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND 2.6 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND 5.7 m&p-Xylenes mg/l 2 NE ND ND ND ND ND ND 3.5 o-Xylenes mg/l 1 NE ND ND ND ND ND ND 2.2 Methyl-tert-butyl-ether (MTBE)mg/l NT NE NT NT NT NT NT NT NT Naphthalene mg/l NT NE NT NT NT NT NT NT NT p-isopropyltoluene mg/l NT NE NT NT NT NT NT NT NT Phosphorus mg/l 0.05 NE NT NT NT NT NT NT 1.4 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (10-24-13) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-24-14) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.3 6.4 7.7 6.2 6.6 6.8 7.3 Specific Conductance mmhos/cm (on-site)1 NE 183 285 294 262 42 6.6 9,040 Temperature °C (on-site)-29 14.6 14.1 17.9 15.9 13.8 12.1 16.9 Turbidity NTU (on-site)NT 50 3.64 2.67 5.1 4.46 3.74 3.07 36.3 Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 0.84 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 1.3 Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.43 Nitrogen mg/l 0.1 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 75 NE NT NT NT NT NT NT 4450 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 53.3 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 964 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND 14.3 Total Barium (Ba)mg/l 5 NE 142 187 133 125 38.5 35.5 376 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND 1.8 Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND ND ND ND 14.6 Total Cobalt (Co)mg/l 5 NE ND 6.4 ND 9.7 ND ND 24.8 Total Copper (Cu)mg/l 5 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND 5.5 ND ND ND ND 157 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND ND ND ND 15.9 Total Zinc (Zn)mg/l 10 50 ND 23.8 10.8 ND ND ND ND Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND Benzene mg/l 1 51 ND ND ND ND ND ND 2 Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND 3.1 Chloroethane mg/l 1 NE ND ND ND ND ND ND 5.9 Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND 3.6 trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND 15.6 2-Hexanone mg/l 5 NE ND ND ND ND ND ND 34.8 Iodomethane mg/l 5 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND 2.6 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND 41.4 m&p-Xylenes mg/l 2 NE ND ND ND ND ND ND 29.7 o-Xylenes mg/l 1 NE ND ND ND ND ND ND 11.7 Methyl-tert-butyl-ether (MTBE)mg/l NT NE NT NT NT NT NT NT NT Naphthalene mg/l NT NE NT NT NT NT NT NT NT p-isopropyltoluene mg/l NT NE NT NT NT NT NT NT NT Phosphorus mg/l 0.05 NE NT NT NT NT NT NT 1.7 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (4-24-14) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-28-14) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.3 7.7 7.8 6.0 6.8 6.9 7.5 Specific Conductance mmhos/cm (on-site)1 NE 236 232 356 206 43 57 15,110 Temperature °C (on-site)-29 12.9 12.5 12.1 18.2 12.4 11.3 19.4 Turbidity NTU (on-site)NT 50 4.43 3.73 5.52 11.3 4.3 1.45 4.71 Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 0.12 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.2 Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.08 Nitrogen mg/l 0.1 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 75 NE NT NT NT NT NT NT 3070 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 48.9 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 1010 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT 0.0075 Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND 56.7 Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 NE 181 155 132 147 31.4 28 360 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND ND ND ND 27.1 Total Cobalt (Co)mg/l 5 NE ND ND ND 9.7 ND ND 14.5 Total Copper (Cu)mg/l 5 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND ND ND ND 135 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND ND ND ND 24.0 Total Zinc (Zn)mg/l 10 50 ND 75.8 ND ND ND ND ND Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND Benzene mg/l 1 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 2 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND 2.8 trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND 1.1 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND ND m&p-Xylenes mg/l 2 NE ND ND ND ND ND ND ND o-Xylenes mg/l 1 NE ND ND ND ND ND ND 1.2 Methyl-tert-butyl-ether (MTBE)mg/l NT NE NT NT NT NT NT NT 1.7 Naphthalene mg/l NT NE NT NT NT NT NT NT 2.1 p-isopropyltoluene mg/l NT NE NT NT NT NT NT NT NT Phosphorus mg/l 0.05 NE NT NT NT NT NT NT 1.7 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (10-28-14) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-28-15) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.3 7.6 8.3 6.1 7.3 7.1 8.1 Specific Conductance mmhos/cm (on-site)1 NE 201 217 330 181 41 81 6,309 Temperature °C (on-site)-29 13.8 11.5 16.8 18.2 12.3 10.7 22.1 Turbidity NTU (on-site)NT 50 4.62 6.77 3.6 6.7 5.76 4.76 5.43 Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.031 Nitrogen mg/l 0.1 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 75 NE NT NT NT NT NT NT 712 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 24.6 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 503 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND 23.4 Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 NE 175 152 145 133 34.5 33.3 119 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND ND ND ND 9.5 Total Cobalt (Co)mg/l 5 NE ND ND ND 7.4 ND ND 7.3 Total Copper (Cu)mg/l 5 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND ND ND ND 64.5 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND ND ND ND 19.3 Total Zinc (Zn)mg/l 10 50 ND 43.4 20.4 ND ND ND ND Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND 32.3 Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND Benzene mg/l 1 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 2 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND ND m&p-Xylenes mg/l 2 NE ND ND ND ND ND ND ND o-Xylenes mg/l 1 NE ND ND ND ND ND ND ND Methyl-tert-butyl-ether (MTBE)mg/l NT NE NT NT NT NT NT NT ND Naphthalene mg/l NT NE NT NT NT NT NT NT ND p-isopropyltoluene mg/l NT NE NT NT NT NT NT NT NT Phosphorus mg/l 0.05 NE NT NT NT NT NT NT 0.34 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (4-28-15) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-27-15) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.8 7.4 7.2 7.7 6.8 6.8 6.4 Specific Conductance mmhos/cm (on-site)1 NE 222 226 360 307 72 61 6,509 Temperature °C (on-site)-29 13.5 13.3 13.4 17.8 14.3 13.0 15.5 Turbidity NTU (on-site)NT 50 10.18 18.30 9.92 24.52 8.05 3.92 66.79 Nitrate as N mg/l 0.02 NE NT NT NT NT NT NT ND Nitrate/Nitrite as N mg/l 0.02 NE NT NT NT NT NT NT 0.042 Nitrite as N mg/l 0.02 NE NT NT NT NT NT NT 0.066 Nitrogen mg/l NT NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l NT NE NT NT NT NT NT NT NT Sulfate mg/l 400 NE NT NT NT NT NT NT 837 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 73.3 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 442 Total Dissolved Solids mg/l NT NE NT NT NT NT NT NT NT Cyanide mg/l 0.008 5 NT NT NT NT NT NT ND Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND 23.4 Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 NE 187 ND 164 139 35 31.4 285 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND ND ND ND 9.8 Total Cobalt (Co)mg/l 5 NE ND ND ND 5.9 ND ND 5.7 Total Copper (Cu)mg/l 5 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND ND ND ND 61.7 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND ND ND ND 18.2 Total Zinc (Zn)mg/l 10 50 ND ND ND ND ND ND 13.7 Mercury mg/l NT 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND 162 Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND Benzene mg/l 1 51 ND ND ND ND ND ND 2 Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND 7.1 Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 2 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND 2.2 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND 168 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND 7.1 Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND 14.6 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND 3.7 m&p-Xylenes mg/l 2 NE ND ND ND ND ND ND 2.5 o-Xylenes mg/l 1 NE ND ND ND ND ND ND 1.2 Methyl-tert-butyl-ether (MTBE)mg/l NT NE NT NT NT NT NT NT ND Naphthalene mg/l NT NE NT NT NT NT NT NT ND p-isopropyltoluene mg/l NT NE NT NT NT NT NT NT NT Phosphorus mg/l 0.05 NE NT NT NT NT NT NT 0.26 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL Shaded cells indicate exceedances of MCLs. 1957-50 White Oak SW 2nd 2015.xlsx (10-27-15) APPENDIX C LABORATORY ANALYTICAL RESULTS #=CL# November 16, 2015 LIMS USE: FR - RON VAIL LIMS OBJECT ID: 92273406 92273406 Project: Pace Project No.: RE: Mr. Ron Vail Santek Environmental Inc. 650 25th St, NW Suite 100 Cleveland, TN 37311 White Oak LF 10/26 Dear Mr. Vail: Enclosed are the analytical results for sample(s) received by the laboratory between October 26, 2015 and October 27, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Chris Derouen christopher.derouen@pacelabs.com Project Manager Enclosures cc:Robert Hudson, Santek Waste Services Ron Vail, Santek Environmental REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 1 of 83 #=CP# CERTIFICATIONS Pace Project No.: Project: 92273406 White Oak LF 10/26 Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84 West Virginia Certification #: 357Virginia/VELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 2 of 83 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92273406 White Oak LF 10/26 Lab ID Sample ID Matrix Date Collected Date Received 92273406001 SW-1 Water 10/26/15 12:20 10/26/15 17:15 92273406002 SW-2 Water 10/26/15 13:45 10/26/15 17:15 92273406003 SW-3 Water 10/26/15 14:00 10/26/15 17:15 92273406004 SW-5 Water 10/26/15 13:30 10/26/15 17:15 92273406005 SW-6 Water 10/26/15 09:45 10/26/15 17:15 92273406006 SW-7 Water 10/26/15 09:30 10/26/15 17:15 92273406007 Leachate Water 10/26/15 13:10 10/26/15 17:15 92273406008 MW-1A Water 10/27/15 12:15 10/27/15 15:50 92273406009 MW-2 Water 10/27/15 12:35 10/27/15 15:50 92273406010 MW-2D Water 10/27/15 12:45 10/27/15 15:50 92273406011 MW-3R Water 10/27/15 13:25 10/27/15 15:50 92273406012 MW-3DR Water 10/27/15 13:35 10/27/15 15:50 92273406013 MW-4A Water 10/27/15 14:00 10/27/15 15:50 92273406014 MW-8 Water 10/27/15 13:00 10/27/15 15:50 92273406015 MW-11s Water 10/27/15 11:40 10/27/15 15:50 92273406016 MW-11D Water 10/27/15 11:50 10/27/15 15:50 92273406017 MW-14 Water 10/27/15 10:45 10/27/15 15:50 92273406018 MW-15 Water 10/27/15 11:00 10/27/15 15:50 92273406019 MW-16 Water 10/27/15 14:20 10/27/15 15:50 92273406020 MW-17 Water 10/27/15 14:35 10/27/15 15:50 92273406021 TVL BLK Water 10/26/15 08:00 10/27/15 15:50 92273406022 Equip Blk Water 10/27/15 08:30 10/27/15 15:50 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 3 of 83 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92273406 White Oak LF 10/26 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92273406001 SW-1 EPA 6010 15 PASI-AJMW EPA 8260 52 PASI-CNB 92273406002 SW-2 EPA 6010 15 PASI-AJMW EPA 8260 52 PASI-CNB 92273406003 SW-3 EPA 6010 15 PASI-AJMW EPA 8260 52 PASI-CNB 92273406004 SW-5 EPA 6010 15 PASI-AJMW EPA 8260 52 PASI-CNB 92273406005 SW-6 EPA 6010 15 PASI-ACDF EPA 8260 52 PASI-CNB 92273406006 SW-7 EPA 6010 15 PASI-ACDF EPA 8260 52 PASI-CNB 92273406007 Leachate EPA 6010 15 PASI-ACDF EPA 8260 52 PASI-CNB SM 5210B 1 PASI-AEWS EPA 300.0 1 PASI-AMDW EPA 353.2 3 PASI-ADMN EPA 365.1 1 PASI-ASER SM 4500-CN-E 1 PASI-AAES2 SM 5220D 1 PASI-AWRC 92273406008 MW-1A EPA 6010 15 PASI-ACDF EPA 8260 52 PASI-CNB 92273406009 MW-2 EPA 6010 15 PASI-ACDF EPA 8260 52 PASI-CNB 92273406010 MW-2D EPA 6010 15 PASI-ACDF EPA 8260 52 PASI-CNB 92273406011 MW-3R EPA 6010 15 PASI-ACDF EPA 8260 52 PASI-CNB 92273406012 MW-3DR EPA 6010 15 PASI-ACDF EPA 8260 52 PASI-CNB 92273406013 MW-4A EPA 6010 15 PASI-ACDF EPA 8260 52 PASI-CNB 92273406014 MW-8 EPA 6010 15 PASI-ACDF EPA 8260 52 PASI-CNB 92273406015 MW-11s EPA 6010 15 PASI-ACDF EPA 8260 52 PASI-CNB 92273406016 MW-11D EPA 6010 15 PASI-ACDF REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 4 of 83 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92273406 White Oak LF 10/26 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts EPA 8260 52 PASI-CNB 92273406017 MW-14 EPA 6010 15 PASI-ACDF EPA 8260 52 PASI-CNB 92273406018 MW-15 EPA 6010 15 PASI-ACDF EPA 8260 52 PASI-CNB 92273406019 MW-16 EPA 6010 15 PASI-ACDF EPA 8260 52 PASI-CNB 92273406020 MW-17 EPA 6010 15 PASI-ACDF EPA 8260 52 PASI-CNB 92273406021 TVL BLK EPA 8260 52 PASI-CNB 92273406022 Equip Blk EPA 6010 15 PASI-ACDF EPA 8260 52 PASI-CNB REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 5 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:SW-1 Lab ID:92273406001 Collected:10/26/15 12:20 Received:10/26/15 17:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method:Monitoring Well Data Collected By Mark Swann 11/16/15 09:071 Collected Date 10/26/15 11/16/15 09:071 Collected Time 12:20 11/16/15 09:071 Field pH 6.8 Std. Units 11/16/15 09:070.10 0.10 1 Field Temperature 13.5 deg C 11/16/15 09:070.50 0.50 1 Field Specific Conductance 222 umhos/cm 11/16/15 09:071.0 1.0 1 Turbidity 10.18 NTU 11/16/15 09:071.0 1.0 1 Appearance Low, Clear 11/16/15 09:071 Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 10/30/15 23:50 7440-36-010/28/15 20:005.0 3.8 1 Arsenic ND ug/L 10/30/15 23:50 7440-38-210/28/15 20:0010.0 2.5 1 Barium 187 ug/L 10/30/15 23:50 7440-39-310/28/15 20:005.0 2.5 1 Beryllium ND ug/L 10/30/15 23:50 7440-41-710/28/15 20:001.0 0.50 1 Cadmium ND ug/L 10/30/15 23:50 7440-43-910/28/15 20:001.0 0.50 1 Chromium ND ug/L 10/30/15 23:50 7440-47-310/28/15 20:005.0 2.5 1 Cobalt ND ug/L 10/30/15 23:50 7440-48-410/28/15 20:005.0 2.5 1 Copper ND ug/L 10/30/15 23:50 7440-50-810/28/15 20:005.0 2.5 1 Lead ND ug/L 10/30/15 23:50 7439-92-110/28/15 20:005.0 2.5 1 Nickel ND ug/L 10/30/15 23:50 7440-02-010/28/15 20:005.0 2.5 1 Selenium ND ug/L 10/30/15 23:50 7782-49-210/28/15 20:0010.0 5.0 1 Silver ND ug/L 10/30/15 23:50 7440-22-410/28/15 20:005.0 2.5 1 Thallium ND ug/L 10/30/15 23:50 7440-28-010/28/15 20:005.4 5.0 1 Vanadium ND ug/L 10/30/15 23:50 7440-62-210/28/15 20:005.0 2.5 1 Zinc ND ug/L 10/30/15 23:50 7440-66-610/28/15 20:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 10/31/15 05:52 67-64-125.0 10.0 1 Acrylonitrile ND ug/L 10/31/15 05:52 107-13-1 M110.0 1.9 1 Benzene ND ug/L 10/31/15 05:52 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/31/15 05:52 74-97-5 M11.0 0.17 1 Bromodichloromethane ND ug/L 10/31/15 05:52 75-27-41.0 0.18 1 Bromoform ND ug/L 10/31/15 05:52 75-25-21.0 0.26 1 Bromomethane ND ug/L 10/31/15 05:52 74-83-92.0 0.29 1 2-Butanone (MEK)ND ug/L 10/31/15 05:52 78-93-3 M15.0 0.96 1 Carbon disulfide ND ug/L 10/31/15 05:52 75-15-02.0 1.2 1 Carbon tetrachloride ND ug/L 10/31/15 05:52 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/31/15 05:52 108-90-71.0 0.23 1 Chloroethane ND ug/L 10/31/15 05:52 75-00-3 L21.0 0.54 1 Chloroform ND ug/L 10/31/15 05:52 67-66-31.0 0.14 1 Chloromethane ND ug/L 10/31/15 05:52 74-87-3 M11.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 05:52 96-12-82.0 2.0 1 Dibromochloromethane ND ug/L 10/31/15 05:52 124-48-11.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/31/15 05:52 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/31/15 05:52 74-95-31.0 0.21 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 6 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:SW-1 Lab ID:92273406001 Collected:10/26/15 12:20 Received:10/26/15 17:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level 1,2-Dichlorobenzene ND ug/L 10/31/15 05:52 95-50-11.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/31/15 05:52 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 05:52 110-57-61.0 1.0 1 1,1-Dichloroethane ND ug/L 10/31/15 05:52 75-34-3 M11.0 0.32 1 1,2-Dichloroethane ND ug/L 10/31/15 05:52 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/31/15 05:52 75-35-41.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/31/15 05:52 156-59-2 M11.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/31/15 05:52 156-60-5 M11.0 0.49 1 1,2-Dichloropropane ND ug/L 10/31/15 05:52 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/31/15 05:52 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/31/15 05:52 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/31/15 05:52 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/31/15 05:52 591-78-65.0 0.46 1 Iodomethane ND ug/L 10/31/15 05:52 74-88-45.0 0.32 1 Methylene Chloride ND ug/L 10/31/15 05:52 75-09-22.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 05:52 108-10-15.0 0.33 1 Styrene ND ug/L 10/31/15 05:52 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 05:52 630-20-61.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 05:52 79-34-51.0 0.40 1 Tetrachloroethene ND ug/L 10/31/15 05:52 127-18-41.0 0.46 1 Toluene ND ug/L 10/31/15 05:52 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/31/15 05:52 71-55-6 M11.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/31/15 05:52 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/31/15 05:52 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/31/15 05:52 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/31/15 05:52 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/31/15 05:52 108-05-42.0 0.35 1 Vinyl chloride ND ug/L 10/31/15 05:52 75-01-4 M11.0 0.62 1 Xylene (Total)ND ug/L 10/31/15 05:52 1330-20-72.0 0.66 1 m&p-Xylene ND ug/L 10/31/15 05:52 179601-23-12.0 0.66 1 o-Xylene ND ug/L 10/31/15 05:52 95-47-61.0 0.23 1 Surrogates 4-Bromofluorobenzene (S)98 %10/31/15 05:52 460-00-470-130 1 1,2-Dichloroethane-d4 (S)106 %10/31/15 05:52 17060-07-070-130 1 Toluene-d8 (S)101 %10/31/15 05:52 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 7 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:SW-2 Lab ID:92273406002 Collected:10/26/15 13:45 Received:10/26/15 17:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method:Monitoring Well Data Collected By Mark Swann 11/16/15 09:121 Collected Date 10/26/16 11/16/15 09:121 Collected Time 13:45 11/16/15 09:121 Field pH 7.4 Std. Units 11/16/15 09:120.10 0.10 1 Field Temperature 13.3 deg C 11/16/15 09:120.50 0.50 1 Field Specific Conductance 226 umhos/cm 11/16/15 09:121.0 1.0 1 Turbidity 18.3 NTU 11/16/15 09:121.0 1.0 1 Appearance Low, OrgaincDebris 11/16/15 09:121 Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 10/31/15 00:02 7440-36-010/28/15 20:005.0 3.8 1 Arsenic ND ug/L 10/31/15 00:02 7440-38-210/28/15 20:0010.0 2.5 1 Barium ND ug/L 10/31/15 00:02 7440-39-310/28/15 20:005.0 2.5 1 Beryllium ND ug/L 10/31/15 00:02 7440-41-710/28/15 20:001.0 0.50 1 Cadmium ND ug/L 10/31/15 00:02 7440-43-910/28/15 20:001.0 0.50 1 Chromium ND ug/L 10/31/15 00:02 7440-47-310/28/15 20:005.0 2.5 1 Cobalt ND ug/L 10/31/15 00:02 7440-48-410/28/15 20:005.0 2.5 1 Copper ND ug/L 10/31/15 00:02 7440-50-810/28/15 20:005.0 2.5 1 Lead ND ug/L 10/31/15 00:02 7439-92-110/28/15 20:005.0 2.5 1 Nickel ND ug/L 10/31/15 00:02 7440-02-010/28/15 20:005.0 2.5 1 Selenium ND ug/L 10/31/15 00:02 7782-49-210/28/15 20:0010.0 5.0 1 Silver ND ug/L 10/31/15 00:02 7440-22-410/28/15 20:005.0 2.5 1 Thallium ND ug/L 10/31/15 00:02 7440-28-010/28/15 20:005.4 5.0 1 Vanadium ND ug/L 10/31/15 00:02 7440-62-210/28/15 20:005.0 2.5 1 Zinc ND ug/L 10/31/15 00:02 7440-66-610/28/15 20:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 10/31/15 06:09 67-64-125.0 10.0 1 Acrylonitrile ND ug/L 10/31/15 06:09 107-13-110.0 1.9 1 Benzene ND ug/L 10/31/15 06:09 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/31/15 06:09 74-97-51.0 0.17 1 Bromodichloromethane ND ug/L 10/31/15 06:09 75-27-41.0 0.18 1 Bromoform ND ug/L 10/31/15 06:09 75-25-21.0 0.26 1 Bromomethane ND ug/L 10/31/15 06:09 74-83-92.0 0.29 1 2-Butanone (MEK)ND ug/L 10/31/15 06:09 78-93-35.0 0.96 1 Carbon disulfide ND ug/L 10/31/15 06:09 75-15-02.0 1.2 1 Carbon tetrachloride ND ug/L 10/31/15 06:09 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/31/15 06:09 108-90-71.0 0.23 1 Chloroethane ND ug/L 10/31/15 06:09 75-00-3 L21.0 0.54 1 Chloroform ND ug/L 10/31/15 06:09 67-66-31.0 0.14 1 Chloromethane ND ug/L 10/31/15 06:09 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 06:09 96-12-82.0 2.0 1 Dibromochloromethane ND ug/L 10/31/15 06:09 124-48-11.0 0.21 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 8 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:SW-2 Lab ID:92273406002 Collected:10/26/15 13:45 Received:10/26/15 17:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level 1,2-Dibromoethane (EDB)ND ug/L 10/31/15 06:09 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/31/15 06:09 74-95-31.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/31/15 06:09 95-50-11.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/31/15 06:09 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 06:09 110-57-61.0 1.0 1 1,1-Dichloroethane ND ug/L 10/31/15 06:09 75-34-31.0 0.32 1 1,2-Dichloroethane ND ug/L 10/31/15 06:09 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/31/15 06:09 75-35-41.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/31/15 06:09 156-59-21.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/31/15 06:09 156-60-51.0 0.49 1 1,2-Dichloropropane ND ug/L 10/31/15 06:09 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/31/15 06:09 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/31/15 06:09 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/31/15 06:09 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/31/15 06:09 591-78-65.0 0.46 1 Iodomethane ND ug/L 10/31/15 06:09 74-88-45.0 0.32 1 Methylene Chloride ND ug/L 10/31/15 06:09 75-09-22.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 06:09 108-10-15.0 0.33 1 Styrene ND ug/L 10/31/15 06:09 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 06:09 630-20-61.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 06:09 79-34-51.0 0.40 1 Tetrachloroethene ND ug/L 10/31/15 06:09 127-18-41.0 0.46 1 Toluene ND ug/L 10/31/15 06:09 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/31/15 06:09 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/31/15 06:09 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/31/15 06:09 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/31/15 06:09 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/31/15 06:09 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/31/15 06:09 108-05-42.0 0.35 1 Vinyl chloride ND ug/L 10/31/15 06:09 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/31/15 06:09 1330-20-72.0 0.66 1 m&p-Xylene ND ug/L 10/31/15 06:09 179601-23-12.0 0.66 1 o-Xylene ND ug/L 10/31/15 06:09 95-47-61.0 0.23 1 Surrogates 4-Bromofluorobenzene (S)98 %10/31/15 06:09 460-00-470-130 1 1,2-Dichloroethane-d4 (S)106 %10/31/15 06:09 17060-07-070-130 1 Toluene-d8 (S)101 %10/31/15 06:09 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 9 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:SW-3 Lab ID:92273406003 Collected:10/26/15 14:00 Received:10/26/15 17:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method:Monitoring Well Data Collected By Mark Swann 11/16/15 09:151 Collected Date 10/26/15 11/16/15 09:151 Collected Time 14:00 11/16/15 09:151 Field pH 7.2 Std. Units 11/16/15 09:150.10 0.10 1 Field Temperature 13.4 deg C 11/16/15 09:150.50 0.50 1 Field Specific Conductance 360 umhos/cm 11/16/15 09:151.0 1.0 1 Turbidity 9.92 NTU 11/16/15 09:151.0 1.0 1 Appearance Low, Clean 11/16/15 09:151 Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 10/31/15 00:05 7440-36-010/28/15 20:005.0 3.8 1 Arsenic ND ug/L 10/31/15 00:05 7440-38-210/28/15 20:0010.0 2.5 1 Barium 164 ug/L 10/31/15 00:05 7440-39-310/28/15 20:005.0 2.5 1 Beryllium ND ug/L 10/31/15 00:05 7440-41-710/28/15 20:001.0 0.50 1 Cadmium ND ug/L 10/31/15 00:05 7440-43-910/28/15 20:001.0 0.50 1 Chromium ND ug/L 10/31/15 00:05 7440-47-310/28/15 20:005.0 2.5 1 Cobalt ND ug/L 10/31/15 00:05 7440-48-410/28/15 20:005.0 2.5 1 Copper ND ug/L 10/31/15 00:05 7440-50-810/28/15 20:005.0 2.5 1 Lead ND ug/L 10/31/15 00:05 7439-92-110/28/15 20:005.0 2.5 1 Nickel ND ug/L 10/31/15 00:05 7440-02-010/28/15 20:005.0 2.5 1 Selenium ND ug/L 10/31/15 00:05 7782-49-210/28/15 20:0010.0 5.0 1 Silver ND ug/L 10/31/15 00:05 7440-22-410/28/15 20:005.0 2.5 1 Thallium ND ug/L 10/31/15 00:05 7440-28-010/28/15 20:005.4 5.0 1 Vanadium ND ug/L 10/31/15 00:05 7440-62-210/28/15 20:005.0 2.5 1 Zinc ND ug/L 10/31/15 00:05 7440-66-610/28/15 20:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 10/31/15 06:27 67-64-125.0 10.0 1 Acrylonitrile ND ug/L 10/31/15 06:27 107-13-110.0 1.9 1 Benzene ND ug/L 10/31/15 06:27 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/31/15 06:27 74-97-51.0 0.17 1 Bromodichloromethane ND ug/L 10/31/15 06:27 75-27-41.0 0.18 1 Bromoform ND ug/L 10/31/15 06:27 75-25-21.0 0.26 1 Bromomethane ND ug/L 10/31/15 06:27 74-83-92.0 0.29 1 2-Butanone (MEK)ND ug/L 10/31/15 06:27 78-93-35.0 0.96 1 Carbon disulfide ND ug/L 10/31/15 06:27 75-15-02.0 1.2 1 Carbon tetrachloride ND ug/L 10/31/15 06:27 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/31/15 06:27 108-90-71.0 0.23 1 Chloroethane ND ug/L 10/31/15 06:27 75-00-3 L21.0 0.54 1 Chloroform ND ug/L 10/31/15 06:27 67-66-31.0 0.14 1 Chloromethane ND ug/L 10/31/15 06:27 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 06:27 96-12-82.0 2.0 1 Dibromochloromethane ND ug/L 10/31/15 06:27 124-48-11.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/31/15 06:27 106-93-41.0 0.27 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 10 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:SW-3 Lab ID:92273406003 Collected:10/26/15 14:00 Received:10/26/15 17:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Dibromomethane ND ug/L 10/31/15 06:27 74-95-31.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/31/15 06:27 95-50-11.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/31/15 06:27 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 06:27 110-57-61.0 1.0 1 1,1-Dichloroethane ND ug/L 10/31/15 06:27 75-34-31.0 0.32 1 1,2-Dichloroethane ND ug/L 10/31/15 06:27 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/31/15 06:27 75-35-41.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/31/15 06:27 156-59-21.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/31/15 06:27 156-60-51.0 0.49 1 1,2-Dichloropropane ND ug/L 10/31/15 06:27 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/31/15 06:27 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/31/15 06:27 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/31/15 06:27 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/31/15 06:27 591-78-65.0 0.46 1 Iodomethane ND ug/L 10/31/15 06:27 74-88-45.0 0.32 1 Methylene Chloride ND ug/L 10/31/15 06:27 75-09-22.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 06:27 108-10-15.0 0.33 1 Styrene ND ug/L 10/31/15 06:27 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 06:27 630-20-61.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 06:27 79-34-51.0 0.40 1 Tetrachloroethene ND ug/L 10/31/15 06:27 127-18-41.0 0.46 1 Toluene ND ug/L 10/31/15 06:27 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/31/15 06:27 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/31/15 06:27 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/31/15 06:27 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/31/15 06:27 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/31/15 06:27 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/31/15 06:27 108-05-42.0 0.35 1 Vinyl chloride ND ug/L 10/31/15 06:27 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/31/15 06:27 1330-20-72.0 0.66 1 m&p-Xylene ND ug/L 10/31/15 06:27 179601-23-12.0 0.66 1 o-Xylene ND ug/L 10/31/15 06:27 95-47-61.0 0.23 1 Surrogates 4-Bromofluorobenzene (S)100 %10/31/15 06:27 460-00-470-130 1 1,2-Dichloroethane-d4 (S)106 %10/31/15 06:27 17060-07-070-130 1 Toluene-d8 (S)101 %10/31/15 06:27 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 11 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:SW-5 Lab ID:92273406004 Collected:10/26/15 13:30 Received:10/26/15 17:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method:Monitoring Well Data Collected By Mark Swann 11/16/15 09:171 Collected Date 10/26/15 11/16/15 09:171 Collected Time 13:30 11/16/15 09:171 Field pH 7.7 Std. Units 11/16/15 09:170.10 0.10 1 Field Temperature 17.8 deg C 11/16/15 09:170.50 0.50 1 Field Specific Conductance 307 umhos/cm 11/16/15 09:171.0 1.0 1 Turbidity 24.52 NTU 11/16/15 09:171.0 1.0 1 Appearance Rusty SedimentLow Flow 11/16/15 09:171 Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 10/31/15 00:08 7440-36-010/28/15 20:005.0 3.8 1 Arsenic ND ug/L 10/31/15 00:08 7440-38-210/28/15 20:0010.0 2.5 1 Barium 139 ug/L 10/31/15 00:08 7440-39-310/28/15 20:005.0 2.5 1 Beryllium ND ug/L 10/31/15 00:08 7440-41-710/28/15 20:001.0 0.50 1 Cadmium ND ug/L 10/31/15 00:08 7440-43-910/28/15 20:001.0 0.50 1 Chromium ND ug/L 10/31/15 00:08 7440-47-310/28/15 20:005.0 2.5 1 Cobalt 5.9 ug/L 10/31/15 00:08 7440-48-410/28/15 20:005.0 2.5 1 Copper ND ug/L 10/31/15 00:08 7440-50-810/28/15 20:005.0 2.5 1 Lead ND ug/L 10/31/15 00:08 7439-92-110/28/15 20:005.0 2.5 1 Nickel ND ug/L 10/31/15 00:08 7440-02-010/28/15 20:005.0 2.5 1 Selenium ND ug/L 10/31/15 00:08 7782-49-210/28/15 20:0010.0 5.0 1 Silver ND ug/L 10/31/15 00:08 7440-22-410/28/15 20:005.0 2.5 1 Thallium ND ug/L 10/31/15 00:08 7440-28-010/28/15 20:005.4 5.0 1 Vanadium ND ug/L 10/31/15 00:08 7440-62-210/28/15 20:005.0 2.5 1 Zinc ND ug/L 10/31/15 00:08 7440-66-610/28/15 20:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 10/31/15 06:44 67-64-125.0 10.0 1 Acrylonitrile ND ug/L 10/31/15 06:44 107-13-110.0 1.9 1 Benzene ND ug/L 10/31/15 06:44 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/31/15 06:44 74-97-51.0 0.17 1 Bromodichloromethane ND ug/L 10/31/15 06:44 75-27-41.0 0.18 1 Bromoform ND ug/L 10/31/15 06:44 75-25-21.0 0.26 1 Bromomethane ND ug/L 10/31/15 06:44 74-83-92.0 0.29 1 2-Butanone (MEK)ND ug/L 10/31/15 06:44 78-93-35.0 0.96 1 Carbon disulfide ND ug/L 10/31/15 06:44 75-15-02.0 1.2 1 Carbon tetrachloride ND ug/L 10/31/15 06:44 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/31/15 06:44 108-90-71.0 0.23 1 Chloroethane ND ug/L 10/31/15 06:44 75-00-3 L21.0 0.54 1 Chloroform ND ug/L 10/31/15 06:44 67-66-31.0 0.14 1 Chloromethane ND ug/L 10/31/15 06:44 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 06:44 96-12-82.0 2.0 1 Dibromochloromethane ND ug/L 10/31/15 06:44 124-48-11.0 0.21 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 12 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:SW-5 Lab ID:92273406004 Collected:10/26/15 13:30 Received:10/26/15 17:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level 1,2-Dibromoethane (EDB)ND ug/L 10/31/15 06:44 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/31/15 06:44 74-95-31.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/31/15 06:44 95-50-11.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/31/15 06:44 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 06:44 110-57-61.0 1.0 1 1,1-Dichloroethane ND ug/L 10/31/15 06:44 75-34-31.0 0.32 1 1,2-Dichloroethane ND ug/L 10/31/15 06:44 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/31/15 06:44 75-35-41.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/31/15 06:44 156-59-21.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/31/15 06:44 156-60-51.0 0.49 1 1,2-Dichloropropane ND ug/L 10/31/15 06:44 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/31/15 06:44 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/31/15 06:44 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/31/15 06:44 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/31/15 06:44 591-78-65.0 0.46 1 Iodomethane ND ug/L 10/31/15 06:44 74-88-45.0 0.32 1 Methylene Chloride ND ug/L 10/31/15 06:44 75-09-22.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 06:44 108-10-15.0 0.33 1 Styrene ND ug/L 10/31/15 06:44 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 06:44 630-20-61.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 06:44 79-34-51.0 0.40 1 Tetrachloroethene ND ug/L 10/31/15 06:44 127-18-41.0 0.46 1 Toluene ND ug/L 10/31/15 06:44 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/31/15 06:44 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/31/15 06:44 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/31/15 06:44 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/31/15 06:44 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/31/15 06:44 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/31/15 06:44 108-05-42.0 0.35 1 Vinyl chloride ND ug/L 10/31/15 06:44 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/31/15 06:44 1330-20-72.0 0.66 1 m&p-Xylene ND ug/L 10/31/15 06:44 179601-23-12.0 0.66 1 o-Xylene ND ug/L 10/31/15 06:44 95-47-61.0 0.23 1 Surrogates 4-Bromofluorobenzene (S)99 %10/31/15 06:44 460-00-470-130 1 1,2-Dichloroethane-d4 (S)107 %10/31/15 06:44 17060-07-070-130 1 Toluene-d8 (S)101 %10/31/15 06:44 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 13 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:SW-6 Lab ID:92273406005 Collected:10/26/15 09:45 Received:10/26/15 17:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method:Monitoring Well Data Collected By Mark Swann 11/16/15 09:221 Collected Date 10/26/15 11/16/15 09:221 Collected Time 09.45 11/16/15 09:221 Field pH 6.8 Std. Units 11/16/15 09:220.10 0.10 1 Field Temperature 14.3 deg C 11/16/15 09:220.50 0.50 1 Field Specific Conductance 72 umhos/cm 11/16/15 09:221.0 1.0 1 Turbidity 8.05 NTU 11/16/15 09:221.0 1.0 1 Appearance Clear, Low Flow, RustSediment 11/16/15 09:221 Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/04/15 20:02 7440-36-010/28/15 19:005.0 3.8 1 Arsenic ND ug/L 11/04/15 20:02 7440-38-210/28/15 19:0010.0 2.5 1 Barium 35.0 ug/L 11/04/15 20:02 7440-39-310/28/15 19:005.0 2.5 1 Beryllium ND ug/L 11/04/15 20:02 7440-41-710/28/15 19:001.0 0.50 1 Cadmium ND ug/L 11/04/15 20:02 7440-43-910/28/15 19:001.0 0.50 1 Chromium ND ug/L 11/04/15 20:02 7440-47-310/28/15 19:005.0 2.5 1 Cobalt ND ug/L 11/04/15 20:02 7440-48-410/28/15 19:005.0 2.5 1 Copper ND ug/L 11/04/15 20:02 7440-50-810/28/15 19:005.0 2.5 1 Lead ND ug/L 11/04/15 20:02 7439-92-110/28/15 19:005.0 2.5 1 Nickel ND ug/L 11/04/15 20:02 7440-02-010/28/15 19:005.0 2.5 1 Selenium ND ug/L 11/04/15 20:02 7782-49-210/28/15 19:0010.0 5.0 1 Silver ND ug/L 11/04/15 20:02 7440-22-410/28/15 19:005.0 2.5 1 Thallium ND ug/L 11/04/15 20:02 7440-28-010/28/15 19:005.4 5.0 1 Vanadium ND ug/L 11/04/15 20:02 7440-62-210/28/15 19:005.0 2.5 1 Zinc ND ug/L 11/04/15 20:02 7440-66-610/28/15 19:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 10/31/15 07:01 67-64-125.0 10.0 1 Acrylonitrile ND ug/L 10/31/15 07:01 107-13-110.0 1.9 1 Benzene ND ug/L 10/31/15 07:01 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/31/15 07:01 74-97-51.0 0.17 1 Bromodichloromethane ND ug/L 10/31/15 07:01 75-27-41.0 0.18 1 Bromoform ND ug/L 10/31/15 07:01 75-25-21.0 0.26 1 Bromomethane ND ug/L 10/31/15 07:01 74-83-92.0 0.29 1 2-Butanone (MEK)ND ug/L 10/31/15 07:01 78-93-35.0 0.96 1 Carbon disulfide ND ug/L 10/31/15 07:01 75-15-02.0 1.2 1 Carbon tetrachloride ND ug/L 10/31/15 07:01 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/31/15 07:01 108-90-71.0 0.23 1 Chloroethane ND ug/L 10/31/15 07:01 75-00-3 L21.0 0.54 1 Chloroform ND ug/L 10/31/15 07:01 67-66-31.0 0.14 1 Chloromethane ND ug/L 10/31/15 07:01 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 07:01 96-12-82.0 2.0 1 Dibromochloromethane ND ug/L 10/31/15 07:01 124-48-11.0 0.21 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 14 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:SW-6 Lab ID:92273406005 Collected:10/26/15 09:45 Received:10/26/15 17:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level 1,2-Dibromoethane (EDB)ND ug/L 10/31/15 07:01 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/31/15 07:01 74-95-31.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/31/15 07:01 95-50-11.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/31/15 07:01 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 07:01 110-57-61.0 1.0 1 1,1-Dichloroethane ND ug/L 10/31/15 07:01 75-34-31.0 0.32 1 1,2-Dichloroethane ND ug/L 10/31/15 07:01 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/31/15 07:01 75-35-41.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/31/15 07:01 156-59-21.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/31/15 07:01 156-60-51.0 0.49 1 1,2-Dichloropropane ND ug/L 10/31/15 07:01 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/31/15 07:01 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/31/15 07:01 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/31/15 07:01 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/31/15 07:01 591-78-65.0 0.46 1 Iodomethane ND ug/L 10/31/15 07:01 74-88-45.0 0.32 1 Methylene Chloride ND ug/L 10/31/15 07:01 75-09-22.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 07:01 108-10-15.0 0.33 1 Styrene ND ug/L 10/31/15 07:01 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 07:01 630-20-61.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 07:01 79-34-51.0 0.40 1 Tetrachloroethene ND ug/L 10/31/15 07:01 127-18-41.0 0.46 1 Toluene ND ug/L 10/31/15 07:01 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/31/15 07:01 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/31/15 07:01 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/31/15 07:01 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/31/15 07:01 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/31/15 07:01 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/31/15 07:01 108-05-42.0 0.35 1 Vinyl chloride ND ug/L 10/31/15 07:01 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/31/15 07:01 1330-20-72.0 0.66 1 m&p-Xylene ND ug/L 10/31/15 07:01 179601-23-12.0 0.66 1 o-Xylene ND ug/L 10/31/15 07:01 95-47-61.0 0.23 1 Surrogates 4-Bromofluorobenzene (S)97 %10/31/15 07:01 460-00-470-130 1 1,2-Dichloroethane-d4 (S)107 %10/31/15 07:01 17060-07-070-130 1 Toluene-d8 (S)101 %10/31/15 07:01 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 15 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:SW-7 Lab ID:92273406006 Collected:10/26/15 09:30 Received:10/26/15 17:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method:Monitoring Well Data Collected By Mark Swann 11/16/15 09:261 Collected Date 10/26/15 11/16/15 09:261 Collected Time 09:30 11/16/15 09:261 Field pH 6.8 Std. Units 11/16/15 09:260.10 0.10 1 Field Temperature 13.0 deg C 11/16/15 09:260.50 0.50 1 Field Specific Conductance 61 umhos/cm 11/16/15 09:261.0 1.0 1 Turbidity 3.92 NTU 11/16/15 09:261.0 1.0 1 Appearance Clear Low Flow 11/16/15 09:261 Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/05/15 00:36 7440-36-010/29/15 20:005.0 3.8 1 Arsenic ND ug/L 11/05/15 00:36 7440-38-210/29/15 20:0010.0 2.5 1 Barium 31.4 ug/L 11/05/15 00:36 7440-39-310/29/15 20:005.0 2.5 1 Beryllium ND ug/L 11/05/15 00:36 7440-41-710/29/15 20:001.0 0.50 1 Cadmium ND ug/L 11/05/15 00:36 7440-43-910/29/15 20:001.0 0.50 1 Chromium ND ug/L 11/05/15 00:36 7440-47-310/29/15 20:005.0 2.5 1 Cobalt ND ug/L 11/05/15 00:36 7440-48-410/29/15 20:005.0 2.5 1 Copper ND ug/L 11/05/15 00:36 7440-50-810/29/15 20:005.0 2.5 1 Lead ND ug/L 11/05/15 00:36 7439-92-110/29/15 20:005.0 2.5 1 Nickel ND ug/L 11/05/15 00:36 7440-02-010/29/15 20:005.0 2.5 1 Selenium ND ug/L 11/05/15 00:36 7782-49-210/29/15 20:0010.0 5.0 1 Silver ND ug/L 11/05/15 00:36 7440-22-410/29/15 20:005.0 2.5 1 Thallium ND ug/L 11/05/15 00:36 7440-28-010/29/15 20:005.4 5.0 1 Vanadium ND ug/L 11/05/15 00:36 7440-62-210/29/15 20:005.0 2.5 1 Zinc ND ug/L 11/05/15 00:36 7440-66-610/29/15 20:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 10/31/15 07:18 67-64-125.0 10.0 1 Acrylonitrile ND ug/L 10/31/15 07:18 107-13-110.0 1.9 1 Benzene ND ug/L 10/31/15 07:18 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/31/15 07:18 74-97-51.0 0.17 1 Bromodichloromethane ND ug/L 10/31/15 07:18 75-27-41.0 0.18 1 Bromoform ND ug/L 10/31/15 07:18 75-25-21.0 0.26 1 Bromomethane ND ug/L 10/31/15 07:18 74-83-92.0 0.29 1 2-Butanone (MEK)ND ug/L 10/31/15 07:18 78-93-35.0 0.96 1 Carbon disulfide ND ug/L 10/31/15 07:18 75-15-02.0 1.2 1 Carbon tetrachloride ND ug/L 10/31/15 07:18 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/31/15 07:18 108-90-71.0 0.23 1 Chloroethane ND ug/L 10/31/15 07:18 75-00-3 L21.0 0.54 1 Chloroform ND ug/L 10/31/15 07:18 67-66-31.0 0.14 1 Chloromethane ND ug/L 10/31/15 07:18 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 07:18 96-12-82.0 2.0 1 Dibromochloromethane ND ug/L 10/31/15 07:18 124-48-11.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/31/15 07:18 106-93-41.0 0.27 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 16 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:SW-7 Lab ID:92273406006 Collected:10/26/15 09:30 Received:10/26/15 17:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Dibromomethane ND ug/L 10/31/15 07:18 74-95-31.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/31/15 07:18 95-50-11.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/31/15 07:18 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 07:18 110-57-61.0 1.0 1 1,1-Dichloroethane ND ug/L 10/31/15 07:18 75-34-31.0 0.32 1 1,2-Dichloroethane ND ug/L 10/31/15 07:18 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/31/15 07:18 75-35-41.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/31/15 07:18 156-59-21.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/31/15 07:18 156-60-51.0 0.49 1 1,2-Dichloropropane ND ug/L 10/31/15 07:18 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/31/15 07:18 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/31/15 07:18 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/31/15 07:18 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/31/15 07:18 591-78-65.0 0.46 1 Iodomethane ND ug/L 10/31/15 07:18 74-88-45.0 0.32 1 Methylene Chloride ND ug/L 10/31/15 07:18 75-09-22.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 07:18 108-10-15.0 0.33 1 Styrene ND ug/L 10/31/15 07:18 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 07:18 630-20-61.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 07:18 79-34-51.0 0.40 1 Tetrachloroethene ND ug/L 10/31/15 07:18 127-18-41.0 0.46 1 Toluene ND ug/L 10/31/15 07:18 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/31/15 07:18 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/31/15 07:18 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/31/15 07:18 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/31/15 07:18 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/31/15 07:18 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/31/15 07:18 108-05-42.0 0.35 1 Vinyl chloride ND ug/L 10/31/15 07:18 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/31/15 07:18 1330-20-72.0 0.66 1 m&p-Xylene ND ug/L 10/31/15 07:18 179601-23-12.0 0.66 1 o-Xylene ND ug/L 10/31/15 07:18 95-47-61.0 0.23 1 Surrogates 4-Bromofluorobenzene (S)100 %10/31/15 07:18 460-00-470-130 1 1,2-Dichloroethane-d4 (S)107 %10/31/15 07:18 17060-07-070-130 1 Toluene-d8 (S)103 %10/31/15 07:18 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 17 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:Leachate Lab ID:92273406007 Collected:10/26/15 13:10 Received:10/26/15 17:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method:Monitoring Well Data Collected By Mark Swann 11/16/15 09:361 Collected Date 10/26/15 11/16/15 09:361 Collected Time 13:10 11/16/15 09:361 Field pH 6.4 Std. Units 11/16/15 09:360.10 0.10 1 Field Temperature 15.5 deg C 11/16/15 09:360.50 0.50 1 Field Specific Conductance 6509 umhos/cm 11/16/15 09:361.0 1.0 1 Turbidity 66.79 NTU 11/16/15 09:361.0 1.0 1 Odor Organic Oder 11/16/15 09:361 Appearance Opaque Dark 11/16/15 09:361 Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony 23.4 ug/L 11/04/15 20:05 7440-36-010/28/15 19:005.0 3.8 1 Arsenic ND ug/L 11/04/15 20:05 7440-38-210/28/15 19:0010.0 2.5 1 Barium 285 ug/L 11/04/15 20:05 7440-39-310/28/15 19:005.0 2.5 1 Beryllium ND ug/L 11/04/15 20:05 7440-41-710/28/15 19:001.0 0.50 1 Cadmium ND ug/L 11/04/15 20:05 7440-43-910/28/15 19:001.0 0.50 1 Chromium 9.8 ug/L 11/04/15 20:05 7440-47-310/28/15 19:005.0 2.5 1 Cobalt 5.7 ug/L 11/04/15 20:05 7440-48-410/28/15 19:005.0 2.5 1 Copper ND ug/L 11/04/15 20:05 7440-50-810/28/15 19:005.0 2.5 1 Lead ND ug/L 11/04/15 20:05 7439-92-110/28/15 19:005.0 2.5 1 Nickel 61.7 ug/L 11/04/15 20:05 7440-02-010/28/15 19:005.0 2.5 1 Selenium ND ug/L 11/04/15 20:05 7782-49-210/28/15 19:0010.0 5.0 1 Silver ND ug/L 11/04/15 20:05 7440-22-410/28/15 19:005.0 2.5 1 Thallium ND ug/L 11/04/15 20:05 7440-28-010/28/15 19:005.4 5.0 1 Vanadium 18.2 ug/L 11/04/15 20:05 7440-62-210/28/15 19:005.0 2.5 1 Zinc 13.7 ug/L 11/04/15 20:05 7440-66-610/28/15 19:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone 162 ug/L 10/31/15 07:36 67-64-125.0 10.0 1 Acrylonitrile ND ug/L 10/31/15 07:36 107-13-110.0 1.9 1 Benzene 2.0 ug/L 10/31/15 07:36 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/31/15 07:36 74-97-51.0 0.17 1 Bromodichloromethane ND ug/L 10/31/15 07:36 75-27-41.0 0.18 1 Bromoform ND ug/L 10/31/15 07:36 75-25-21.0 0.26 1 Bromomethane ND ug/L 10/31/15 07:36 74-83-92.0 0.29 1 2-Butanone (MEK)168 ug/L 10/31/15 07:36 78-93-35.0 0.96 1 Carbon disulfide 7.1 ug/L 10/31/15 07:36 75-15-02.0 1.2 1 Carbon tetrachloride ND ug/L 10/31/15 07:36 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/31/15 07:36 108-90-71.0 0.23 1 Chloroethane ND ug/L 10/31/15 07:36 75-00-3 L21.0 0.54 1 Chloroform ND ug/L 10/31/15 07:36 67-66-31.0 0.14 1 Chloromethane ND ug/L 10/31/15 07:36 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 07:36 96-12-82.0 2.0 1 Dibromochloromethane ND ug/L 10/31/15 07:36 124-48-11.0 0.21 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 18 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:Leachate Lab ID:92273406007 Collected:10/26/15 13:10 Received:10/26/15 17:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level 1,2-Dibromoethane (EDB)ND ug/L 10/31/15 07:36 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/31/15 07:36 74-95-31.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/31/15 07:36 95-50-11.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/31/15 07:36 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 07:36 110-57-61.0 1.0 1 1,1-Dichloroethane ND ug/L 10/31/15 07:36 75-34-31.0 0.32 1 1,2-Dichloroethane ND ug/L 10/31/15 07:36 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/31/15 07:36 75-35-41.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/31/15 07:36 156-59-21.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/31/15 07:36 156-60-51.0 0.49 1 1,2-Dichloropropane ND ug/L 10/31/15 07:36 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/31/15 07:36 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/31/15 07:36 10061-02-61.0 0.26 1 Ethylbenzene 2.2 ug/L 10/31/15 07:36 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/31/15 07:36 591-78-65.0 0.46 1 Iodomethane ND ug/L 10/31/15 07:36 74-88-45.0 0.32 1 Methylene Chloride ND ug/L 10/31/15 07:36 75-09-22.0 0.97 1 4-Methyl-2-pentanone (MIBK)7.1 ug/L 10/31/15 07:36 108-10-15.0 0.33 1 Styrene ND ug/L 10/31/15 07:36 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 07:36 630-20-61.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 07:36 79-34-51.0 0.40 1 Tetrachloroethene ND ug/L 10/31/15 07:36 127-18-41.0 0.46 1 Toluene 14.6 ug/L 10/31/15 07:36 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/31/15 07:36 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/31/15 07:36 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/31/15 07:36 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/31/15 07:36 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/31/15 07:36 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/31/15 07:36 108-05-42.0 0.35 1 Vinyl chloride ND ug/L 10/31/15 07:36 75-01-41.0 0.62 1 Xylene (Total)3.7 ug/L 10/31/15 07:36 1330-20-72.0 0.66 1 m&p-Xylene 2.5 ug/L 10/31/15 07:36 179601-23-12.0 0.66 1 o-Xylene 1.2 ug/L 10/31/15 07:36 95-47-61.0 0.23 1 Surrogates 4-Bromofluorobenzene (S)97 %10/31/15 07:36 460-00-470-130 1 1,2-Dichloroethane-d4 (S)107 %10/31/15 07:36 17060-07-070-130 1 Toluene-d8 (S)101 %10/31/15 07:36 2037-26-570-130 1 Analytical Method: SM 5210B5210B BOD, 5 day BOD, 5 day 73.3 mg/L 11/02/15 10:40 L110/28/15 05:002.0 2.0 1 Analytical Method: EPA 300.0300.0 IC Anions 28 Days Sulfate 837 mg/L 11/02/15 21:27 14808-79-8400200200 Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate ND mg/L 10/27/15 20:210.020 0.010 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 19 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:Leachate Lab ID:92273406007 Collected:10/26/15 13:10 Received:10/26/15 17:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrite 0.066 mg/L 10/27/15 20:210.020 0.010 1 Nitrogen, NO2 plus NO3 0.042 mg/L 10/27/15 20:210.020 0.010 1 Analytical Method: EPA 365.1365.1 Phosphorus, Total Phosphorus 0.26 mg/L 11/03/15 03:49 7723-14-00.050 0.025 1 Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total Cyanide ND mg/L 10/30/15 16:44 57-12-50.0080 0.0040 1 Analytical Method: SM 5220D5220D COD Chemical Oxygen Demand 442 mg/L 10/29/15 13:4025.0 12.5 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 20 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-1A Lab ID:92273406008 Collected:10/27/15 12:15 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method:Monitoring Well Data Collected By Mark Swann 11/16/15 09:561 Collected Date 10/27/15 11/16/15 09:561 Collected Time 12:15 11/16/15 09:561 Field pH 6.3 Std. Units 11/16/15 09:560.10 0.10 1 Field Temperature 12.5 deg C 11/16/15 09:560.50 0.50 1 Static Water Level 21.80 feet 11/16/15 09:561 Field Specific Conductance 118 umhos/cm 11/16/15 09:561.0 1.0 1 Turbidity 1.88 NTU 11/16/15 09:561.0 1.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/04/15 20:18 7440-36-010/28/15 19:005.0 3.8 1 Arsenic ND ug/L 11/04/15 20:18 7440-38-210/28/15 19:0010.0 2.5 1 Barium 164 ug/L 11/04/15 20:18 7440-39-310/28/15 19:005.0 2.5 1 Beryllium ND ug/L 11/04/15 20:18 7440-41-710/28/15 19:001.0 0.50 1 Cadmium ND ug/L 11/04/15 20:18 7440-43-910/28/15 19:001.0 0.50 1 Chromium ND ug/L 11/04/15 20:18 7440-47-310/28/15 19:005.0 2.5 1 Cobalt ND ug/L 11/04/15 20:18 7440-48-410/28/15 19:005.0 2.5 1 Copper ND ug/L 11/04/15 20:18 7440-50-810/28/15 19:005.0 2.5 1 Lead ND ug/L 11/04/15 20:18 7439-92-110/28/15 19:005.0 2.5 1 Nickel ND ug/L 11/04/15 20:18 7440-02-010/28/15 19:005.0 2.5 1 Selenium ND ug/L 11/04/15 20:18 7782-49-210/28/15 19:0010.0 5.0 1 Silver ND ug/L 11/04/15 20:18 7440-22-410/28/15 19:005.0 2.5 1 Thallium ND ug/L 11/04/15 20:18 7440-28-010/28/15 19:005.4 5.0 1 Vanadium ND ug/L 11/04/15 20:18 7440-62-210/28/15 19:005.0 2.5 1 Zinc ND ug/L 11/04/15 20:18 7440-66-610/28/15 19:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 10/31/15 07:53 67-64-125.0 10.0 1 Acrylonitrile ND ug/L 10/31/15 07:53 107-13-110.0 1.9 1 Benzene ND ug/L 10/31/15 07:53 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/31/15 07:53 74-97-51.0 0.17 1 Bromodichloromethane ND ug/L 10/31/15 07:53 75-27-41.0 0.18 1 Bromoform ND ug/L 10/31/15 07:53 75-25-21.0 0.26 1 Bromomethane ND ug/L 10/31/15 07:53 74-83-92.0 0.29 1 2-Butanone (MEK)ND ug/L 10/31/15 07:53 78-93-35.0 0.96 1 Carbon disulfide ND ug/L 10/31/15 07:53 75-15-02.0 1.2 1 Carbon tetrachloride ND ug/L 10/31/15 07:53 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/31/15 07:53 108-90-71.0 0.23 1 Chloroethane ND ug/L 10/31/15 07:53 75-00-3 L21.0 0.54 1 Chloroform ND ug/L 10/31/15 07:53 67-66-31.0 0.14 1 Chloromethane ND ug/L 10/31/15 07:53 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 07:53 96-12-82.0 2.0 1 Dibromochloromethane ND ug/L 10/31/15 07:53 124-48-11.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/31/15 07:53 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/31/15 07:53 74-95-31.0 0.21 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 21 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-1A Lab ID:92273406008 Collected:10/27/15 12:15 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level 1,2-Dichlorobenzene ND ug/L 10/31/15 07:53 95-50-11.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/31/15 07:53 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 07:53 110-57-61.0 1.0 1 1,1-Dichloroethane ND ug/L 10/31/15 07:53 75-34-31.0 0.32 1 1,2-Dichloroethane ND ug/L 10/31/15 07:53 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/31/15 07:53 75-35-41.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/31/15 07:53 156-59-21.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/31/15 07:53 156-60-51.0 0.49 1 1,2-Dichloropropane ND ug/L 10/31/15 07:53 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/31/15 07:53 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/31/15 07:53 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/31/15 07:53 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/31/15 07:53 591-78-65.0 0.46 1 Iodomethane ND ug/L 10/31/15 07:53 74-88-45.0 0.32 1 Methylene Chloride ND ug/L 10/31/15 07:53 75-09-22.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 07:53 108-10-15.0 0.33 1 Styrene ND ug/L 10/31/15 07:53 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 07:53 630-20-61.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 07:53 79-34-51.0 0.40 1 Tetrachloroethene ND ug/L 10/31/15 07:53 127-18-41.0 0.46 1 Toluene ND ug/L 10/31/15 07:53 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/31/15 07:53 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/31/15 07:53 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/31/15 07:53 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/31/15 07:53 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/31/15 07:53 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/31/15 07:53 108-05-42.0 0.35 1 Vinyl chloride ND ug/L 10/31/15 07:53 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/31/15 07:53 1330-20-72.0 0.66 1 m&p-Xylene ND ug/L 10/31/15 07:53 179601-23-12.0 0.66 1 o-Xylene ND ug/L 10/31/15 07:53 95-47-61.0 0.23 1 Surrogates 4-Bromofluorobenzene (S)99 %10/31/15 07:53 460-00-470-130 1 1,2-Dichloroethane-d4 (S)109 %10/31/15 07:53 17060-07-070-130 1 Toluene-d8 (S)102 %10/31/15 07:53 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 22 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-2 Lab ID:92273406009 Collected:10/27/15 12:35 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method:Monitoring Well Data Collected By Mark Swann 11/16/15 09:581 Collected Date 10/27/15 11/16/15 09:581 Collected Time 12:35 11/16/15 09:581 Field pH 5.9 Std. Units 11/16/15 09:580.10 0.10 1 Field Temperature 13.0 deg C 11/16/15 09:580.50 0.50 1 Static Water Level 30.68 feet 11/16/15 09:581 Field Specific Conductance 1478 umhos/cm 11/16/15 09:581.0 1.0 1 Turbidity 2.52 NTU 11/16/15 09:581.0 1.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/04/15 20:21 7440-36-010/28/15 19:005.0 3.8 1 Arsenic ND ug/L 11/04/15 20:21 7440-38-210/28/15 19:0010.0 2.5 1 Barium 1190 ug/L 11/04/15 20:21 7440-39-310/28/15 19:005.0 2.5 1 Beryllium ND ug/L 11/04/15 20:21 7440-41-710/28/15 19:001.0 0.50 1 Cadmium ND ug/L 11/04/15 20:21 7440-43-910/28/15 19:001.0 0.50 1 Chromium ND ug/L 11/04/15 20:21 7440-47-310/28/15 19:005.0 2.5 1 Cobalt 5.6 ug/L 11/04/15 20:21 7440-48-410/28/15 19:005.0 2.5 1 Copper 5.4 ug/L 11/04/15 20:21 7440-50-810/28/15 19:005.0 2.5 1 Lead ND ug/L 11/04/15 20:21 7439-92-110/28/15 19:005.0 2.5 1 Nickel 12.6 ug/L 11/04/15 20:21 7440-02-010/28/15 19:005.0 2.5 1 Selenium ND ug/L 11/04/15 20:21 7782-49-210/28/15 19:0010.0 5.0 1 Silver ND ug/L 11/04/15 20:21 7440-22-410/28/15 19:005.0 2.5 1 Thallium ND ug/L 11/04/15 20:21 7440-28-010/28/15 19:005.4 5.0 1 Vanadium ND ug/L 11/04/15 20:21 7440-62-210/28/15 19:005.0 2.5 1 Zinc 14.3 ug/L 11/04/15 20:21 7440-66-610/28/15 19:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 10/31/15 08:10 67-64-125.0 10.0 1 Acrylonitrile ND ug/L 10/31/15 08:10 107-13-110.0 1.9 1 Benzene ND ug/L 10/31/15 08:10 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/31/15 08:10 74-97-51.0 0.17 1 Bromodichloromethane ND ug/L 10/31/15 08:10 75-27-41.0 0.18 1 Bromoform ND ug/L 10/31/15 08:10 75-25-21.0 0.26 1 Bromomethane ND ug/L 10/31/15 08:10 74-83-92.0 0.29 1 2-Butanone (MEK)ND ug/L 10/31/15 08:10 78-93-35.0 0.96 1 Carbon disulfide ND ug/L 10/31/15 08:10 75-15-02.0 1.2 1 Carbon tetrachloride ND ug/L 10/31/15 08:10 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/31/15 08:10 108-90-71.0 0.23 1 Chloroethane ND ug/L 10/31/15 08:10 75-00-3 L21.0 0.54 1 Chloroform ND ug/L 10/31/15 08:10 67-66-31.0 0.14 1 Chloromethane ND ug/L 10/31/15 08:10 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 08:10 96-12-82.0 2.0 1 Dibromochloromethane ND ug/L 10/31/15 08:10 124-48-11.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/31/15 08:10 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/31/15 08:10 74-95-31.0 0.21 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 23 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-2 Lab ID:92273406009 Collected:10/27/15 12:35 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level 1,2-Dichlorobenzene ND ug/L 10/31/15 08:10 95-50-11.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/31/15 08:10 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 08:10 110-57-61.0 1.0 1 1,1-Dichloroethane ND ug/L 10/31/15 08:10 75-34-31.0 0.32 1 1,2-Dichloroethane ND ug/L 10/31/15 08:10 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/31/15 08:10 75-35-41.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/31/15 08:10 156-59-21.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/31/15 08:10 156-60-51.0 0.49 1 1,2-Dichloropropane ND ug/L 10/31/15 08:10 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/31/15 08:10 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/31/15 08:10 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/31/15 08:10 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/31/15 08:10 591-78-65.0 0.46 1 Iodomethane ND ug/L 10/31/15 08:10 74-88-45.0 0.32 1 Methylene Chloride ND ug/L 10/31/15 08:10 75-09-22.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 08:10 108-10-15.0 0.33 1 Styrene ND ug/L 10/31/15 08:10 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 08:10 630-20-61.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 08:10 79-34-51.0 0.40 1 Tetrachloroethene ND ug/L 10/31/15 08:10 127-18-41.0 0.46 1 Toluene ND ug/L 10/31/15 08:10 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/31/15 08:10 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/31/15 08:10 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/31/15 08:10 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/31/15 08:10 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/31/15 08:10 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/31/15 08:10 108-05-42.0 0.35 1 Vinyl chloride ND ug/L 10/31/15 08:10 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/31/15 08:10 1330-20-72.0 0.66 1 m&p-Xylene ND ug/L 10/31/15 08:10 179601-23-12.0 0.66 1 o-Xylene ND ug/L 10/31/15 08:10 95-47-61.0 0.23 1 Surrogates 4-Bromofluorobenzene (S)98 %10/31/15 08:10 460-00-470-130 1 1,2-Dichloroethane-d4 (S)109 %10/31/15 08:10 17060-07-070-130 1 Toluene-d8 (S)101 %10/31/15 08:10 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 24 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-2D Lab ID:92273406010 Collected:10/27/15 12:45 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method:Monitoring Well Data Collected By Mark Swann 11/16/15 10:011 Collected Date 10/27/15 11/16/15 10:011 Collected Time 12:45 11/16/15 10:011 Field pH 6.2 Std. Units 11/16/15 10:010.10 0.10 1 Field Temperature 13.0 deg C 11/16/15 10:010.50 0.50 1 Static Water Level 30.60 feet 11/16/15 10:011 Field Specific Conductance 1566 umhos/cm 11/16/15 10:011.0 1.0 1 Turbidity 1.27 NTU 11/16/15 10:011.0 1.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/04/15 20:24 7440-36-010/28/15 19:005.0 3.8 1 Arsenic ND ug/L 11/04/15 20:24 7440-38-210/28/15 19:0010.0 2.5 1 Barium 1400 ug/L 11/04/15 20:24 7440-39-310/28/15 19:005.0 2.5 1 Beryllium ND ug/L 11/04/15 20:24 7440-41-710/28/15 19:001.0 0.50 1 Cadmium ND ug/L 11/04/15 20:24 7440-43-910/28/15 19:001.0 0.50 1 Chromium ND ug/L 11/04/15 20:24 7440-47-310/28/15 19:005.0 2.5 1 Cobalt ND ug/L 11/04/15 20:24 7440-48-410/28/15 19:005.0 2.5 1 Copper 7.3 ug/L 11/04/15 20:24 7440-50-810/28/15 19:005.0 2.5 1 Lead ND ug/L 11/04/15 20:24 7439-92-110/28/15 19:005.0 2.5 1 Nickel 12.6 ug/L 11/04/15 20:24 7440-02-010/28/15 19:005.0 2.5 1 Selenium ND ug/L 11/04/15 20:24 7782-49-210/28/15 19:0010.0 5.0 1 Silver ND ug/L 11/04/15 20:24 7440-22-410/28/15 19:005.0 2.5 1 Thallium ND ug/L 11/04/15 20:24 7440-28-010/28/15 19:005.4 5.0 1 Vanadium ND ug/L 11/04/15 20:24 7440-62-210/28/15 19:005.0 2.5 1 Zinc ND ug/L 11/04/15 20:24 7440-66-610/28/15 19:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 10/31/15 08:28 67-64-125.0 10.0 1 Acrylonitrile ND ug/L 10/31/15 08:28 107-13-110.0 1.9 1 Benzene ND ug/L 10/31/15 08:28 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/31/15 08:28 74-97-51.0 0.17 1 Bromodichloromethane ND ug/L 10/31/15 08:28 75-27-41.0 0.18 1 Bromoform ND ug/L 10/31/15 08:28 75-25-21.0 0.26 1 Bromomethane ND ug/L 10/31/15 08:28 74-83-92.0 0.29 1 2-Butanone (MEK)ND ug/L 10/31/15 08:28 78-93-35.0 0.96 1 Carbon disulfide ND ug/L 10/31/15 08:28 75-15-02.0 1.2 1 Carbon tetrachloride ND ug/L 10/31/15 08:28 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/31/15 08:28 108-90-71.0 0.23 1 Chloroethane ND ug/L 10/31/15 08:28 75-00-3 L21.0 0.54 1 Chloroform ND ug/L 10/31/15 08:28 67-66-31.0 0.14 1 Chloromethane ND ug/L 10/31/15 08:28 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 08:28 96-12-82.0 2.0 1 Dibromochloromethane ND ug/L 10/31/15 08:28 124-48-11.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/31/15 08:28 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/31/15 08:28 74-95-31.0 0.21 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 25 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-2D Lab ID:92273406010 Collected:10/27/15 12:45 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level 1,2-Dichlorobenzene ND ug/L 10/31/15 08:28 95-50-11.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/31/15 08:28 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 08:28 110-57-61.0 1.0 1 1,1-Dichloroethane ND ug/L 10/31/15 08:28 75-34-31.0 0.32 1 1,2-Dichloroethane ND ug/L 10/31/15 08:28 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/31/15 08:28 75-35-41.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/31/15 08:28 156-59-21.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/31/15 08:28 156-60-51.0 0.49 1 1,2-Dichloropropane ND ug/L 10/31/15 08:28 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/31/15 08:28 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/31/15 08:28 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/31/15 08:28 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/31/15 08:28 591-78-65.0 0.46 1 Iodomethane ND ug/L 10/31/15 08:28 74-88-45.0 0.32 1 Methylene Chloride ND ug/L 10/31/15 08:28 75-09-22.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 08:28 108-10-15.0 0.33 1 Styrene ND ug/L 10/31/15 08:28 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 08:28 630-20-61.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 08:28 79-34-51.0 0.40 1 Tetrachloroethene ND ug/L 10/31/15 08:28 127-18-41.0 0.46 1 Toluene ND ug/L 10/31/15 08:28 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/31/15 08:28 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/31/15 08:28 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/31/15 08:28 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/31/15 08:28 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/31/15 08:28 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/31/15 08:28 108-05-42.0 0.35 1 Vinyl chloride ND ug/L 10/31/15 08:28 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/31/15 08:28 1330-20-72.0 0.66 1 m&p-Xylene ND ug/L 10/31/15 08:28 179601-23-12.0 0.66 1 o-Xylene ND ug/L 10/31/15 08:28 95-47-61.0 0.23 1 Surrogates 4-Bromofluorobenzene (S)99 %10/31/15 08:28 460-00-470-130 1 1,2-Dichloroethane-d4 (S)108 %10/31/15 08:28 17060-07-070-130 1 Toluene-d8 (S)101 %10/31/15 08:28 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 26 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-3R Lab ID:92273406011 Collected:10/27/15 13:25 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method:Monitoring Well Data Collected By Mark Swann 11/16/15 10:041 Collected Date 10/27/15 11/16/15 10:041 Collected Time 13:25 11/16/15 10:041 Field pH 6.0 Std. Units 11/16/15 10:040.10 0.10 1 Field Temperature 13.5 deg C 11/16/15 10:040.50 0.50 1 Static Water Level 33.45 feet 11/16/15 10:041 Field Specific Conductance 429 umhos/cm 11/16/15 10:041.0 1.0 1 Turbidity 4.05 NTU 11/16/15 10:041.0 1.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/04/15 20:27 7440-36-010/28/15 19:005.0 3.8 1 Arsenic ND ug/L 11/04/15 20:27 7440-38-210/28/15 19:0010.0 2.5 1 Barium 352 ug/L 11/04/15 20:27 7440-39-310/28/15 19:005.0 2.5 1 Beryllium ND ug/L 11/04/15 20:27 7440-41-710/28/15 19:001.0 0.50 1 Cadmium ND ug/L 11/04/15 20:27 7440-43-910/28/15 19:001.0 0.50 1 Chromium ND ug/L 11/04/15 20:27 7440-47-310/28/15 19:005.0 2.5 1 Cobalt ND ug/L 11/04/15 20:27 7440-48-410/28/15 19:005.0 2.5 1 Copper ND ug/L 11/04/15 20:27 7440-50-810/28/15 19:005.0 2.5 1 Lead ND ug/L 11/04/15 20:27 7439-92-110/28/15 19:005.0 2.5 1 Nickel 24.4 ug/L 11/04/15 20:27 7440-02-010/28/15 19:005.0 2.5 1 Selenium ND ug/L 11/04/15 20:27 7782-49-210/28/15 19:0010.0 5.0 1 Silver ND ug/L 11/04/15 20:27 7440-22-410/28/15 19:005.0 2.5 1 Thallium ND ug/L 11/04/15 20:27 7440-28-010/28/15 19:005.4 5.0 1 Vanadium ND ug/L 11/04/15 20:27 7440-62-210/28/15 19:005.0 2.5 1 Zinc ND ug/L 11/04/15 20:27 7440-66-610/28/15 19:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 10/31/15 08:45 67-64-125.0 10.0 1 Acrylonitrile ND ug/L 10/31/15 08:45 107-13-110.0 1.9 1 Benzene ND ug/L 10/31/15 08:45 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/31/15 08:45 74-97-51.0 0.17 1 Bromodichloromethane ND ug/L 10/31/15 08:45 75-27-41.0 0.18 1 Bromoform ND ug/L 10/31/15 08:45 75-25-21.0 0.26 1 Bromomethane ND ug/L 10/31/15 08:45 74-83-92.0 0.29 1 2-Butanone (MEK)ND ug/L 10/31/15 08:45 78-93-35.0 0.96 1 Carbon disulfide ND ug/L 10/31/15 08:45 75-15-02.0 1.2 1 Carbon tetrachloride ND ug/L 10/31/15 08:45 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/31/15 08:45 108-90-71.0 0.23 1 Chloroethane ND ug/L 10/31/15 08:45 75-00-3 L21.0 0.54 1 Chloroform ND ug/L 10/31/15 08:45 67-66-31.0 0.14 1 Chloromethane ND ug/L 10/31/15 08:45 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 08:45 96-12-82.0 2.0 1 Dibromochloromethane ND ug/L 10/31/15 08:45 124-48-11.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/31/15 08:45 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/31/15 08:45 74-95-31.0 0.21 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 27 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-3R Lab ID:92273406011 Collected:10/27/15 13:25 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level 1,2-Dichlorobenzene ND ug/L 10/31/15 08:45 95-50-11.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/31/15 08:45 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 08:45 110-57-61.0 1.0 1 1,1-Dichloroethane ND ug/L 10/31/15 08:45 75-34-31.0 0.32 1 1,2-Dichloroethane ND ug/L 10/31/15 08:45 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/31/15 08:45 75-35-41.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/31/15 08:45 156-59-21.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/31/15 08:45 156-60-51.0 0.49 1 1,2-Dichloropropane ND ug/L 10/31/15 08:45 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/31/15 08:45 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/31/15 08:45 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/31/15 08:45 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/31/15 08:45 591-78-65.0 0.46 1 Iodomethane ND ug/L 10/31/15 08:45 74-88-45.0 0.32 1 Methylene Chloride ND ug/L 10/31/15 08:45 75-09-22.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 08:45 108-10-15.0 0.33 1 Styrene ND ug/L 10/31/15 08:45 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 08:45 630-20-61.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 08:45 79-34-51.0 0.40 1 Tetrachloroethene ND ug/L 10/31/15 08:45 127-18-41.0 0.46 1 Toluene ND ug/L 10/31/15 08:45 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/31/15 08:45 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/31/15 08:45 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/31/15 08:45 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/31/15 08:45 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/31/15 08:45 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/31/15 08:45 108-05-42.0 0.35 1 Vinyl chloride ND ug/L 10/31/15 08:45 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/31/15 08:45 1330-20-72.0 0.66 1 m&p-Xylene ND ug/L 10/31/15 08:45 179601-23-12.0 0.66 1 o-Xylene ND ug/L 10/31/15 08:45 95-47-61.0 0.23 1 Surrogates 4-Bromofluorobenzene (S)96 %10/31/15 08:45 460-00-470-130 1 1,2-Dichloroethane-d4 (S)109 %10/31/15 08:45 17060-07-070-130 1 Toluene-d8 (S)101 %10/31/15 08:45 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 28 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-3DR Lab ID:92273406012 Collected:10/27/15 13:35 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method:Monitoring Well Data Collected By Mark Swann 11/16/15 10:061 Collected Date 10/27/15 11/16/15 10:061 Collected Time 13:35 11/16/15 10:061 Field pH 5.8 Std. Units 11/16/15 10:060.10 0.10 1 Field Temperature 13.7 deg C 11/16/15 10:060.50 0.50 1 Static Water Level 37.50 feet 11/16/15 10:061 Field Specific Conductance 357 umhos/cm 11/16/15 10:061.0 1.0 1 Turbidity 7.82 NTU 11/16/15 10:061.0 1.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/04/15 20:30 7440-36-010/28/15 19:005.0 3.8 1 Arsenic ND ug/L 11/04/15 20:30 7440-38-210/28/15 19:0010.0 2.5 1 Barium 247 ug/L 11/04/15 20:30 7440-39-310/28/15 19:005.0 2.5 1 Beryllium ND ug/L 11/04/15 20:30 7440-41-710/28/15 19:001.0 0.50 1 Cadmium ND ug/L 11/04/15 20:30 7440-43-910/28/15 19:001.0 0.50 1 Chromium ND ug/L 11/04/15 20:30 7440-47-310/28/15 19:005.0 2.5 1 Cobalt ND ug/L 11/04/15 20:30 7440-48-410/28/15 19:005.0 2.5 1 Copper ND ug/L 11/04/15 20:30 7440-50-810/28/15 19:005.0 2.5 1 Lead ND ug/L 11/04/15 20:30 7439-92-110/28/15 19:005.0 2.5 1 Nickel 33.4 ug/L 11/04/15 20:30 7440-02-010/28/15 19:005.0 2.5 1 Selenium ND ug/L 11/04/15 20:30 7782-49-210/28/15 19:0010.0 5.0 1 Silver ND ug/L 11/04/15 20:30 7440-22-410/28/15 19:005.0 2.5 1 Thallium ND ug/L 11/04/15 20:30 7440-28-010/28/15 19:005.4 5.0 1 Vanadium ND ug/L 11/04/15 20:30 7440-62-210/28/15 19:005.0 2.5 1 Zinc 11.8 ug/L 11/04/15 20:30 7440-66-610/28/15 19:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 10/31/15 09:02 67-64-125.0 10.0 1 Acrylonitrile ND ug/L 10/31/15 09:02 107-13-110.0 1.9 1 Benzene ND ug/L 10/31/15 09:02 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/31/15 09:02 74-97-51.0 0.17 1 Bromodichloromethane ND ug/L 10/31/15 09:02 75-27-41.0 0.18 1 Bromoform ND ug/L 10/31/15 09:02 75-25-21.0 0.26 1 Bromomethane ND ug/L 10/31/15 09:02 74-83-92.0 0.29 1 2-Butanone (MEK)ND ug/L 10/31/15 09:02 78-93-35.0 0.96 1 Carbon disulfide ND ug/L 10/31/15 09:02 75-15-02.0 1.2 1 Carbon tetrachloride ND ug/L 10/31/15 09:02 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/31/15 09:02 108-90-71.0 0.23 1 Chloroethane ND ug/L 10/31/15 09:02 75-00-3 L21.0 0.54 1 Chloroform ND ug/L 10/31/15 09:02 67-66-31.0 0.14 1 Chloromethane ND ug/L 10/31/15 09:02 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 09:02 96-12-82.0 2.0 1 Dibromochloromethane ND ug/L 10/31/15 09:02 124-48-11.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/31/15 09:02 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/31/15 09:02 74-95-31.0 0.21 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 29 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-3DR Lab ID:92273406012 Collected:10/27/15 13:35 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level 1,2-Dichlorobenzene ND ug/L 10/31/15 09:02 95-50-11.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/31/15 09:02 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 09:02 110-57-61.0 1.0 1 1,1-Dichloroethane ND ug/L 10/31/15 09:02 75-34-31.0 0.32 1 1,2-Dichloroethane ND ug/L 10/31/15 09:02 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/31/15 09:02 75-35-41.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/31/15 09:02 156-59-21.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/31/15 09:02 156-60-51.0 0.49 1 1,2-Dichloropropane ND ug/L 10/31/15 09:02 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/31/15 09:02 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/31/15 09:02 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/31/15 09:02 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/31/15 09:02 591-78-65.0 0.46 1 Iodomethane ND ug/L 10/31/15 09:02 74-88-45.0 0.32 1 Methylene Chloride ND ug/L 10/31/15 09:02 75-09-22.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 09:02 108-10-15.0 0.33 1 Styrene ND ug/L 10/31/15 09:02 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 09:02 630-20-61.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 09:02 79-34-51.0 0.40 1 Tetrachloroethene ND ug/L 10/31/15 09:02 127-18-41.0 0.46 1 Toluene ND ug/L 10/31/15 09:02 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/31/15 09:02 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/31/15 09:02 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/31/15 09:02 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/31/15 09:02 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/31/15 09:02 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/31/15 09:02 108-05-42.0 0.35 1 Vinyl chloride ND ug/L 10/31/15 09:02 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/31/15 09:02 1330-20-72.0 0.66 1 m&p-Xylene ND ug/L 10/31/15 09:02 179601-23-12.0 0.66 1 o-Xylene ND ug/L 10/31/15 09:02 95-47-61.0 0.23 1 Surrogates 4-Bromofluorobenzene (S)99 %10/31/15 09:02 460-00-470-130 1 1,2-Dichloroethane-d4 (S)109 %10/31/15 09:02 17060-07-070-130 1 Toluene-d8 (S)102 %10/31/15 09:02 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 30 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-4A Lab ID:92273406013 Collected:10/27/15 14:00 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method:Monitoring Well Data Collected By Mark Swann 11/16/15 10:081 Collected Date 10/27/15 11/16/15 10:081 Collected Time 14:00 11/16/15 10:081 Field pH 6.8 Std. Units 11/16/15 10:080.10 0.10 1 Field Temperature 13.2 deg C 11/16/15 10:080.50 0.50 1 Static Water Level 44.28 feet 11/16/15 10:081 Field Specific Conductance 162 umhos/cm 11/16/15 10:081.0 1.0 1 Turbidity 8.68 NTU 11/16/15 10:081.0 1.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/04/15 20:34 7440-36-010/28/15 19:005.0 3.8 1 Arsenic ND ug/L 11/04/15 20:34 7440-38-210/28/15 19:0010.0 2.5 1 Barium 13.8 ug/L 11/04/15 20:34 7440-39-310/28/15 19:005.0 2.5 1 Beryllium ND ug/L 11/04/15 20:34 7440-41-710/28/15 19:001.0 0.50 1 Cadmium ND ug/L 11/04/15 20:34 7440-43-910/28/15 19:001.0 0.50 1 Chromium ND ug/L 11/04/15 20:34 7440-47-310/28/15 19:005.0 2.5 1 Cobalt ND ug/L 11/04/15 20:34 7440-48-410/28/15 19:005.0 2.5 1 Copper ND ug/L 11/04/15 20:34 7440-50-810/28/15 19:005.0 2.5 1 Lead ND ug/L 11/04/15 20:34 7439-92-110/28/15 19:005.0 2.5 1 Nickel ND ug/L 11/04/15 20:34 7440-02-010/28/15 19:005.0 2.5 1 Selenium ND ug/L 11/04/15 20:34 7782-49-210/28/15 19:0010.0 5.0 1 Silver ND ug/L 11/04/15 20:34 7440-22-410/28/15 19:005.0 2.5 1 Thallium ND ug/L 11/04/15 20:34 7440-28-010/28/15 19:005.4 5.0 1 Vanadium ND ug/L 11/04/15 20:34 7440-62-210/28/15 19:005.0 2.5 1 Zinc ND ug/L 11/04/15 20:34 7440-66-610/28/15 19:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 10/31/15 09:20 67-64-125.0 10.0 1 Acrylonitrile ND ug/L 10/31/15 09:20 107-13-110.0 1.9 1 Benzene ND ug/L 10/31/15 09:20 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/31/15 09:20 74-97-51.0 0.17 1 Bromodichloromethane ND ug/L 10/31/15 09:20 75-27-41.0 0.18 1 Bromoform ND ug/L 10/31/15 09:20 75-25-21.0 0.26 1 Bromomethane ND ug/L 10/31/15 09:20 74-83-92.0 0.29 1 2-Butanone (MEK)ND ug/L 10/31/15 09:20 78-93-35.0 0.96 1 Carbon disulfide ND ug/L 10/31/15 09:20 75-15-02.0 1.2 1 Carbon tetrachloride ND ug/L 10/31/15 09:20 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/31/15 09:20 108-90-71.0 0.23 1 Chloroethane ND ug/L 10/31/15 09:20 75-00-3 L21.0 0.54 1 Chloroform ND ug/L 10/31/15 09:20 67-66-31.0 0.14 1 Chloromethane ND ug/L 10/31/15 09:20 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 09:20 96-12-82.0 2.0 1 Dibromochloromethane ND ug/L 10/31/15 09:20 124-48-11.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/31/15 09:20 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/31/15 09:20 74-95-31.0 0.21 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 31 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-4A Lab ID:92273406013 Collected:10/27/15 14:00 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level 1,2-Dichlorobenzene ND ug/L 10/31/15 09:20 95-50-11.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/31/15 09:20 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 09:20 110-57-61.0 1.0 1 1,1-Dichloroethane ND ug/L 10/31/15 09:20 75-34-31.0 0.32 1 1,2-Dichloroethane ND ug/L 10/31/15 09:20 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/31/15 09:20 75-35-41.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/31/15 09:20 156-59-21.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/31/15 09:20 156-60-51.0 0.49 1 1,2-Dichloropropane ND ug/L 10/31/15 09:20 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/31/15 09:20 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/31/15 09:20 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/31/15 09:20 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/31/15 09:20 591-78-65.0 0.46 1 Iodomethane ND ug/L 10/31/15 09:20 74-88-45.0 0.32 1 Methylene Chloride ND ug/L 10/31/15 09:20 75-09-22.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 09:20 108-10-15.0 0.33 1 Styrene ND ug/L 10/31/15 09:20 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 09:20 630-20-61.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 09:20 79-34-51.0 0.40 1 Tetrachloroethene ND ug/L 10/31/15 09:20 127-18-41.0 0.46 1 Toluene ND ug/L 10/31/15 09:20 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/31/15 09:20 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/31/15 09:20 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/31/15 09:20 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/31/15 09:20 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/31/15 09:20 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/31/15 09:20 108-05-42.0 0.35 1 Vinyl chloride ND ug/L 10/31/15 09:20 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/31/15 09:20 1330-20-72.0 0.66 1 m&p-Xylene ND ug/L 10/31/15 09:20 179601-23-12.0 0.66 1 o-Xylene ND ug/L 10/31/15 09:20 95-47-61.0 0.23 1 Surrogates 4-Bromofluorobenzene (S)97 %10/31/15 09:20 460-00-470-130 1 1,2-Dichloroethane-d4 (S)110 %10/31/15 09:20 17060-07-070-130 1 Toluene-d8 (S)101 %10/31/15 09:20 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 32 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-8 Lab ID:92273406014 Collected:10/27/15 13:00 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method:Monitoring Well Data Collected By Mark Swann 11/16/15 10:111 Collected Date 10/27/15 11/16/15 10:111 Collected Time 13:00 11/16/15 10:111 Field pH 6.4 Std. Units 11/16/15 10:110.10 0.10 1 Field Temperature 13.5 deg C 11/16/15 10:110.50 0.50 1 Static Water Level 31.05 feet 11/16/15 10:111 Field Specific Conductance 816 umhos/cm 11/16/15 10:111.0 1.0 1 Turbidity 5.50 NTU 11/16/15 10:111.0 1.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/04/15 20:37 7440-36-010/28/15 19:005.0 3.8 1 Arsenic ND ug/L 11/04/15 20:37 7440-38-210/28/15 19:0010.0 2.5 1 Barium 279 ug/L 11/04/15 20:37 7440-39-310/28/15 19:005.0 2.5 1 Beryllium ND ug/L 11/04/15 20:37 7440-41-710/28/15 19:001.0 0.50 1 Cadmium ND ug/L 11/04/15 20:37 7440-43-910/28/15 19:001.0 0.50 1 Chromium 7.7 ug/L 11/04/15 20:37 7440-47-310/28/15 19:005.0 2.5 1 Cobalt ND ug/L 11/04/15 20:37 7440-48-410/28/15 19:005.0 2.5 1 Copper ND ug/L 11/04/15 20:37 7440-50-810/28/15 19:005.0 2.5 1 Lead ND ug/L 11/04/15 20:37 7439-92-110/28/15 19:005.0 2.5 1 Nickel 5.9 ug/L 11/04/15 20:37 7440-02-010/28/15 19:005.0 2.5 1 Selenium ND ug/L 11/04/15 20:37 7782-49-210/28/15 19:0010.0 5.0 1 Silver ND ug/L 11/04/15 20:37 7440-22-410/28/15 19:005.0 2.5 1 Thallium ND ug/L 11/04/15 20:37 7440-28-010/28/15 19:005.4 5.0 1 Vanadium 7.4 ug/L 11/04/15 20:37 7440-62-210/28/15 19:005.0 2.5 1 Zinc 22.1 ug/L 11/04/15 20:37 7440-66-610/28/15 19:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 10/31/15 09:37 67-64-125.0 10.0 1 Acrylonitrile ND ug/L 10/31/15 09:37 107-13-110.0 1.9 1 Benzene ND ug/L 10/31/15 09:37 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/31/15 09:37 74-97-51.0 0.17 1 Bromodichloromethane ND ug/L 10/31/15 09:37 75-27-41.0 0.18 1 Bromoform ND ug/L 10/31/15 09:37 75-25-21.0 0.26 1 Bromomethane ND ug/L 10/31/15 09:37 74-83-92.0 0.29 1 2-Butanone (MEK)ND ug/L 10/31/15 09:37 78-93-35.0 0.96 1 Carbon disulfide ND ug/L 10/31/15 09:37 75-15-02.0 1.2 1 Carbon tetrachloride ND ug/L 10/31/15 09:37 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/31/15 09:37 108-90-71.0 0.23 1 Chloroethane ND ug/L 10/31/15 09:37 75-00-3 L21.0 0.54 1 Chloroform ND ug/L 10/31/15 09:37 67-66-31.0 0.14 1 Chloromethane ND ug/L 10/31/15 09:37 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 09:37 96-12-82.0 2.0 1 Dibromochloromethane ND ug/L 10/31/15 09:37 124-48-11.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/31/15 09:37 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/31/15 09:37 74-95-31.0 0.21 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 33 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-8 Lab ID:92273406014 Collected:10/27/15 13:00 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level 1,2-Dichlorobenzene ND ug/L 10/31/15 09:37 95-50-11.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/31/15 09:37 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 09:37 110-57-61.0 1.0 1 1,1-Dichloroethane ND ug/L 10/31/15 09:37 75-34-31.0 0.32 1 1,2-Dichloroethane ND ug/L 10/31/15 09:37 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/31/15 09:37 75-35-41.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/31/15 09:37 156-59-21.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/31/15 09:37 156-60-51.0 0.49 1 1,2-Dichloropropane ND ug/L 10/31/15 09:37 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/31/15 09:37 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/31/15 09:37 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/31/15 09:37 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/31/15 09:37 591-78-65.0 0.46 1 Iodomethane ND ug/L 10/31/15 09:37 74-88-45.0 0.32 1 Methylene Chloride ND ug/L 10/31/15 09:37 75-09-22.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 09:37 108-10-15.0 0.33 1 Styrene ND ug/L 10/31/15 09:37 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 09:37 630-20-61.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 09:37 79-34-51.0 0.40 1 Tetrachloroethene ND ug/L 10/31/15 09:37 127-18-41.0 0.46 1 Toluene ND ug/L 10/31/15 09:37 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/31/15 09:37 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/31/15 09:37 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/31/15 09:37 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/31/15 09:37 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/31/15 09:37 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/31/15 09:37 108-05-42.0 0.35 1 Vinyl chloride ND ug/L 10/31/15 09:37 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/31/15 09:37 1330-20-72.0 0.66 1 m&p-Xylene ND ug/L 10/31/15 09:37 179601-23-12.0 0.66 1 o-Xylene ND ug/L 10/31/15 09:37 95-47-61.0 0.23 1 Surrogates 4-Bromofluorobenzene (S)99 %10/31/15 09:37 460-00-470-130 1 1,2-Dichloroethane-d4 (S)109 %10/31/15 09:37 17060-07-070-130 1 Toluene-d8 (S)101 %10/31/15 09:37 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 34 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-11s Lab ID:92273406015 Collected:10/27/15 11:40 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method:Monitoring Well Data Collected By Mark Swann 11/16/15 10:131 Collected Date 10/27/15 11/16/15 10:131 Collected Time 11:40 11/16/15 10:131 Field pH 6.7 Std. Units 11/16/15 10:130.10 0.10 1 Field Temperature 12..1 deg C 11/16/15 10:130.50 0.50 1 Static Water Level 81.15 feet 11/16/15 10:131 Field Specific Conductance 27 umhos/cm 11/16/15 10:131.0 1.0 1 Turbidity 5.50 NTU 11/16/15 10:131.0 1.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/04/15 20:40 7440-36-010/28/15 19:005.0 3.8 1 Arsenic ND ug/L 11/04/15 20:40 7440-38-210/28/15 19:0010.0 2.5 1 Barium 346 ug/L 11/04/15 20:40 7440-39-310/28/15 19:005.0 2.5 1 Beryllium ND ug/L 11/04/15 20:40 7440-41-710/28/15 19:001.0 0.50 1 Cadmium 1.9 ug/L 11/04/15 20:40 7440-43-910/28/15 19:001.0 0.50 1 Chromium 31.4 ug/L 11/04/15 20:40 7440-47-310/28/15 19:005.0 2.5 1 Cobalt 6.2 ug/L 11/04/15 20:40 7440-48-410/28/15 19:005.0 2.5 1 Copper 19.1 ug/L 11/04/15 20:40 7440-50-810/28/15 19:005.0 2.5 1 Lead 7.7 ug/L 11/04/15 20:40 7439-92-110/28/15 19:005.0 2.5 1 Nickel 21.3 ug/L 11/04/15 20:40 7440-02-010/28/15 19:005.0 2.5 1 Selenium ND ug/L 11/04/15 20:40 7782-49-210/28/15 19:0010.0 5.0 1 Silver ND ug/L 11/04/15 20:40 7440-22-410/28/15 19:005.0 2.5 1 Thallium ND ug/L 11/04/15 20:40 7440-28-010/28/15 19:005.4 5.0 1 Vanadium 44.5 ug/L 11/04/15 20:40 7440-62-210/28/15 19:005.0 2.5 1 Zinc 69.8 ug/L 11/04/15 20:40 7440-66-610/28/15 19:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 10/31/15 09:54 67-64-125.0 10.0 1 Acrylonitrile ND ug/L 10/31/15 09:54 107-13-1 M110.0 1.9 1 Benzene ND ug/L 10/31/15 09:54 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/31/15 09:54 74-97-5 M11.0 0.17 1 Bromodichloromethane ND ug/L 10/31/15 09:54 75-27-41.0 0.18 1 Bromoform ND ug/L 10/31/15 09:54 75-25-21.0 0.26 1 Bromomethane ND ug/L 10/31/15 09:54 74-83-92.0 0.29 1 2-Butanone (MEK)ND ug/L 10/31/15 09:54 78-93-3 M15.0 0.96 1 Carbon disulfide ND ug/L 10/31/15 09:54 75-15-02.0 1.2 1 Carbon tetrachloride ND ug/L 10/31/15 09:54 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/31/15 09:54 108-90-71.0 0.23 1 Chloroethane ND ug/L 10/31/15 09:54 75-00-3 L21.0 0.54 1 Chloroform ND ug/L 10/31/15 09:54 67-66-3 M11.0 0.14 1 Chloromethane ND ug/L 10/31/15 09:54 74-87-3 M11.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 09:54 96-12-82.0 2.0 1 Dibromochloromethane ND ug/L 10/31/15 09:54 124-48-11.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/31/15 09:54 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/31/15 09:54 74-95-31.0 0.21 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 35 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-11s Lab ID:92273406015 Collected:10/27/15 11:40 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level 1,2-Dichlorobenzene ND ug/L 10/31/15 09:54 95-50-11.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/31/15 09:54 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 09:54 110-57-61.0 1.0 1 1,1-Dichloroethane ND ug/L 10/31/15 09:54 75-34-3 M11.0 0.32 1 1,2-Dichloroethane ND ug/L 10/31/15 09:54 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/31/15 09:54 75-35-41.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/31/15 09:54 156-59-2 M11.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/31/15 09:54 156-60-5 M11.0 0.49 1 1,2-Dichloropropane ND ug/L 10/31/15 09:54 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/31/15 09:54 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/31/15 09:54 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/31/15 09:54 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/31/15 09:54 591-78-65.0 0.46 1 Iodomethane ND ug/L 10/31/15 09:54 74-88-45.0 0.32 1 Methylene Chloride ND ug/L 10/31/15 09:54 75-09-22.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 09:54 108-10-15.0 0.33 1 Styrene ND ug/L 10/31/15 09:54 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 09:54 630-20-61.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 09:54 79-34-51.0 0.40 1 Tetrachloroethene ND ug/L 10/31/15 09:54 127-18-41.0 0.46 1 Toluene ND ug/L 10/31/15 09:54 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/31/15 09:54 71-55-6 M11.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/31/15 09:54 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/31/15 09:54 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/31/15 09:54 75-69-4 M11.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/31/15 09:54 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/31/15 09:54 108-05-42.0 0.35 1 Vinyl chloride ND ug/L 10/31/15 09:54 75-01-4 M11.0 0.62 1 Xylene (Total)ND ug/L 10/31/15 09:54 1330-20-72.0 0.66 1 m&p-Xylene ND ug/L 10/31/15 09:54 179601-23-12.0 0.66 1 o-Xylene ND ug/L 10/31/15 09:54 95-47-61.0 0.23 1 Surrogates 4-Bromofluorobenzene (S)99 %10/31/15 09:54 460-00-470-130 1 1,2-Dichloroethane-d4 (S)110 %10/31/15 09:54 17060-07-070-130 1 Toluene-d8 (S)101 %10/31/15 09:54 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 36 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-11D Lab ID:92273406016 Collected:10/27/15 11:50 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method:Monitoring Well Data Collected By Mark Swann 11/16/15 10:271 Collected Date 10/27/15 11/16/15 10:271 Collected Time 11:50 11/16/15 10:271 Field pH 6.6 Std. Units 11/16/15 10:270.10 0.10 1 Field Temperature 12.4 deg C 11/16/15 10:270.50 0.50 1 Static Water Level 82.15 feet 11/16/15 10:271 Field Specific Conductance 44 umhos/cm 11/16/15 10:271.0 1.0 1 Turbidity 4.35 NTU 11/16/15 10:271.0 1.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/05/15 00:44 7440-36-010/29/15 20:005.0 3.8 1 Arsenic ND ug/L 11/05/15 00:44 7440-38-210/29/15 20:0010.0 2.5 1 Barium 16.0 ug/L 11/05/15 00:44 7440-39-310/29/15 20:005.0 2.5 1 Beryllium ND ug/L 11/05/15 00:44 7440-41-710/29/15 20:001.0 0.50 1 Cadmium ND ug/L 11/05/15 00:44 7440-43-910/29/15 20:001.0 0.50 1 Chromium ND ug/L 11/05/15 00:44 7440-47-310/29/15 20:005.0 2.5 1 Cobalt ND ug/L 11/05/15 00:44 7440-48-410/29/15 20:005.0 2.5 1 Copper ND ug/L 11/05/15 00:44 7440-50-810/29/15 20:005.0 2.5 1 Lead ND ug/L 11/05/15 00:44 7439-92-110/29/15 20:005.0 2.5 1 Nickel ND ug/L 11/05/15 00:44 7440-02-010/29/15 20:005.0 2.5 1 Selenium ND ug/L 11/05/15 00:44 7782-49-210/29/15 20:0010.0 5.0 1 Silver ND ug/L 11/05/15 00:44 7440-22-410/29/15 20:005.0 2.5 1 Thallium ND ug/L 11/05/15 00:44 7440-28-010/29/15 20:005.4 5.0 1 Vanadium ND ug/L 11/05/15 00:44 7440-62-210/29/15 20:005.0 2.5 1 Zinc ND ug/L 11/05/15 00:44 7440-66-610/29/15 20:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 10/31/15 10:11 67-64-125.0 10.0 1 Acrylonitrile ND ug/L 10/31/15 10:11 107-13-110.0 1.9 1 Benzene ND ug/L 10/31/15 10:11 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/31/15 10:11 74-97-51.0 0.17 1 Bromodichloromethane ND ug/L 10/31/15 10:11 75-27-41.0 0.18 1 Bromoform ND ug/L 10/31/15 10:11 75-25-21.0 0.26 1 Bromomethane ND ug/L 10/31/15 10:11 74-83-92.0 0.29 1 2-Butanone (MEK)ND ug/L 10/31/15 10:11 78-93-35.0 0.96 1 Carbon disulfide ND ug/L 10/31/15 10:11 75-15-02.0 1.2 1 Carbon tetrachloride ND ug/L 10/31/15 10:11 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/31/15 10:11 108-90-71.0 0.23 1 Chloroethane ND ug/L 10/31/15 10:11 75-00-3 L21.0 0.54 1 Chloroform ND ug/L 10/31/15 10:11 67-66-31.0 0.14 1 Chloromethane ND ug/L 10/31/15 10:11 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 10:11 96-12-82.0 2.0 1 Dibromochloromethane ND ug/L 10/31/15 10:11 124-48-11.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/31/15 10:11 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/31/15 10:11 74-95-31.0 0.21 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 37 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-11D Lab ID:92273406016 Collected:10/27/15 11:50 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level 1,2-Dichlorobenzene ND ug/L 10/31/15 10:11 95-50-11.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/31/15 10:11 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 10:11 110-57-61.0 1.0 1 1,1-Dichloroethane ND ug/L 10/31/15 10:11 75-34-31.0 0.32 1 1,2-Dichloroethane ND ug/L 10/31/15 10:11 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/31/15 10:11 75-35-41.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/31/15 10:11 156-59-21.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/31/15 10:11 156-60-51.0 0.49 1 1,2-Dichloropropane ND ug/L 10/31/15 10:11 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/31/15 10:11 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/31/15 10:11 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/31/15 10:11 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/31/15 10:11 591-78-65.0 0.46 1 Iodomethane ND ug/L 10/31/15 10:11 74-88-45.0 0.32 1 Methylene Chloride ND ug/L 10/31/15 10:11 75-09-22.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 10:11 108-10-15.0 0.33 1 Styrene ND ug/L 10/31/15 10:11 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 10:11 630-20-61.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 10:11 79-34-51.0 0.40 1 Tetrachloroethene ND ug/L 10/31/15 10:11 127-18-41.0 0.46 1 Toluene ND ug/L 10/31/15 10:11 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/31/15 10:11 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/31/15 10:11 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/31/15 10:11 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/31/15 10:11 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/31/15 10:11 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/31/15 10:11 108-05-42.0 0.35 1 Vinyl chloride ND ug/L 10/31/15 10:11 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/31/15 10:11 1330-20-72.0 0.66 1 m&p-Xylene ND ug/L 10/31/15 10:11 179601-23-12.0 0.66 1 o-Xylene ND ug/L 10/31/15 10:11 95-47-61.0 0.23 1 Surrogates 4-Bromofluorobenzene (S)98 %10/31/15 10:11 460-00-470-130 1 1,2-Dichloroethane-d4 (S)111 %10/31/15 10:11 17060-07-070-130 1 Toluene-d8 (S)101 %10/31/15 10:11 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 38 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-14 Lab ID:92273406017 Collected:10/27/15 10:45 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method:Monitoring Well Data Collected By Mark Swann 11/16/15 10:521 Collected Date 10/27/15 11/16/15 10:521 Collected Time 10:45 11/16/15 10:521 Field pH 6.6 Std. Units 11/16/15 10:520.10 0.10 1 Field Temperature 12.4 deg C 11/16/15 10:520.50 0.50 1 Static Water Level 101.30 feet 11/16/15 10:521 Field Specific Conductance 104 umhos/cm 11/16/15 10:521.0 1.0 1 Turbidity 28.0 NTU 11/16/15 10:521.0 1.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/05/15 00:48 7440-36-010/29/15 20:005.0 3.8 1 Arsenic ND ug/L 11/05/15 00:48 7440-38-210/29/15 20:0010.0 2.5 1 Barium 95.7 ug/L 11/05/15 00:48 7440-39-310/29/15 20:005.0 2.5 1 Beryllium ND ug/L 11/05/15 00:48 7440-41-710/29/15 20:001.0 0.50 1 Cadmium ND ug/L 11/05/15 00:48 7440-43-910/29/15 20:001.0 0.50 1 Chromium ND ug/L 11/05/15 00:48 7440-47-310/29/15 20:005.0 2.5 1 Cobalt ND ug/L 11/05/15 00:48 7440-48-410/29/15 20:005.0 2.5 1 Copper ND ug/L 11/05/15 00:48 7440-50-810/29/15 20:005.0 2.5 1 Lead ND ug/L 11/05/15 00:48 7439-92-110/29/15 20:005.0 2.5 1 Nickel ND ug/L 11/05/15 00:48 7440-02-010/29/15 20:005.0 2.5 1 Selenium ND ug/L 11/05/15 00:48 7782-49-210/29/15 20:0010.0 5.0 1 Silver ND ug/L 11/05/15 00:48 7440-22-410/29/15 20:005.0 2.5 1 Thallium ND ug/L 11/05/15 00:48 7440-28-010/29/15 20:005.4 5.0 1 Vanadium ND ug/L 11/05/15 00:48 7440-62-210/29/15 20:005.0 2.5 1 Zinc ND ug/L 11/05/15 00:48 7440-66-610/29/15 20:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 10/31/15 10:29 67-64-125.0 10.0 1 Acrylonitrile ND ug/L 10/31/15 10:29 107-13-110.0 1.9 1 Benzene ND ug/L 10/31/15 10:29 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/31/15 10:29 74-97-51.0 0.17 1 Bromodichloromethane ND ug/L 10/31/15 10:29 75-27-41.0 0.18 1 Bromoform ND ug/L 10/31/15 10:29 75-25-21.0 0.26 1 Bromomethane ND ug/L 10/31/15 10:29 74-83-92.0 0.29 1 2-Butanone (MEK)ND ug/L 10/31/15 10:29 78-93-35.0 0.96 1 Carbon disulfide ND ug/L 10/31/15 10:29 75-15-02.0 1.2 1 Carbon tetrachloride ND ug/L 10/31/15 10:29 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/31/15 10:29 108-90-71.0 0.23 1 Chloroethane ND ug/L 10/31/15 10:29 75-00-3 L21.0 0.54 1 Chloroform ND ug/L 10/31/15 10:29 67-66-31.0 0.14 1 Chloromethane ND ug/L 10/31/15 10:29 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 10:29 96-12-82.0 2.0 1 Dibromochloromethane ND ug/L 10/31/15 10:29 124-48-11.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/31/15 10:29 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/31/15 10:29 74-95-31.0 0.21 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 39 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-14 Lab ID:92273406017 Collected:10/27/15 10:45 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level 1,2-Dichlorobenzene ND ug/L 10/31/15 10:29 95-50-11.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/31/15 10:29 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 10:29 110-57-61.0 1.0 1 1,1-Dichloroethane ND ug/L 10/31/15 10:29 75-34-31.0 0.32 1 1,2-Dichloroethane ND ug/L 10/31/15 10:29 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/31/15 10:29 75-35-41.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/31/15 10:29 156-59-21.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/31/15 10:29 156-60-51.0 0.49 1 1,2-Dichloropropane ND ug/L 10/31/15 10:29 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/31/15 10:29 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/31/15 10:29 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/31/15 10:29 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/31/15 10:29 591-78-65.0 0.46 1 Iodomethane ND ug/L 10/31/15 10:29 74-88-45.0 0.32 1 Methylene Chloride ND ug/L 10/31/15 10:29 75-09-22.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 10:29 108-10-15.0 0.33 1 Styrene ND ug/L 10/31/15 10:29 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 10:29 630-20-61.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 10:29 79-34-51.0 0.40 1 Tetrachloroethene ND ug/L 10/31/15 10:29 127-18-41.0 0.46 1 Toluene ND ug/L 10/31/15 10:29 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/31/15 10:29 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/31/15 10:29 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/31/15 10:29 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/31/15 10:29 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/31/15 10:29 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/31/15 10:29 108-05-42.0 0.35 1 Vinyl chloride ND ug/L 10/31/15 10:29 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/31/15 10:29 1330-20-72.0 0.66 1 m&p-Xylene ND ug/L 10/31/15 10:29 179601-23-12.0 0.66 1 o-Xylene ND ug/L 10/31/15 10:29 95-47-61.0 0.23 1 Surrogates 4-Bromofluorobenzene (S)100 %10/31/15 10:29 460-00-470-130 1 1,2-Dichloroethane-d4 (S)111 %10/31/15 10:29 17060-07-070-130 1 Toluene-d8 (S)101 %10/31/15 10:29 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 40 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-15 Lab ID:92273406018 Collected:10/27/15 11:00 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method:Monitoring Well Data Collected By Mark Swann 11/16/15 10:541 Collected Date 10/27/15 11/16/15 10:541 Collected Time 11:00 11/16/15 10:541 Field pH 6.7 Std. Units 11/16/15 10:540.10 0.10 1 Field Temperature 14.3 deg C 11/16/15 10:540.50 0.50 1 Static Water Level 9.69 feet 11/16/15 10:541 Field Specific Conductance 48 umhos/cm 11/16/15 10:541.0 1.0 1 Turbidity 16.56 NTU 11/16/15 10:541.0 1.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/05/15 01:00 7440-36-010/29/15 20:005.0 3.8 1 Arsenic ND ug/L 11/05/15 01:00 7440-38-210/29/15 20:0010.0 2.5 1 Barium 18.8 ug/L 11/05/15 01:00 7440-39-310/29/15 20:005.0 2.5 1 Beryllium ND ug/L 11/05/15 01:00 7440-41-710/29/15 20:001.0 0.50 1 Cadmium ND ug/L 11/05/15 01:00 7440-43-910/29/15 20:001.0 0.50 1 Chromium ND ug/L 11/05/15 01:00 7440-47-310/29/15 20:005.0 2.5 1 Cobalt ND ug/L 11/05/15 01:00 7440-48-410/29/15 20:005.0 2.5 1 Copper ND ug/L 11/05/15 01:00 7440-50-810/29/15 20:005.0 2.5 1 Lead ND ug/L 11/05/15 01:00 7439-92-110/29/15 20:005.0 2.5 1 Nickel ND ug/L 11/05/15 01:00 7440-02-010/29/15 20:005.0 2.5 1 Selenium ND ug/L 11/05/15 01:00 7782-49-210/29/15 20:0010.0 5.0 1 Silver ND ug/L 11/05/15 01:00 7440-22-410/29/15 20:005.0 2.5 1 Thallium ND ug/L 11/05/15 01:00 7440-28-010/29/15 20:005.4 5.0 1 Vanadium ND ug/L 11/05/15 01:00 7440-62-210/29/15 20:005.0 2.5 1 Zinc ND ug/L 11/05/15 01:00 7440-66-610/29/15 20:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 10/31/15 10:46 67-64-125.0 10.0 1 Acrylonitrile ND ug/L 10/31/15 10:46 107-13-110.0 1.9 1 Benzene ND ug/L 10/31/15 10:46 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/31/15 10:46 74-97-51.0 0.17 1 Bromodichloromethane ND ug/L 10/31/15 10:46 75-27-41.0 0.18 1 Bromoform ND ug/L 10/31/15 10:46 75-25-21.0 0.26 1 Bromomethane ND ug/L 10/31/15 10:46 74-83-92.0 0.29 1 2-Butanone (MEK)ND ug/L 10/31/15 10:46 78-93-35.0 0.96 1 Carbon disulfide ND ug/L 10/31/15 10:46 75-15-02.0 1.2 1 Carbon tetrachloride ND ug/L 10/31/15 10:46 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/31/15 10:46 108-90-71.0 0.23 1 Chloroethane ND ug/L 10/31/15 10:46 75-00-3 L21.0 0.54 1 Chloroform ND ug/L 10/31/15 10:46 67-66-31.0 0.14 1 Chloromethane ND ug/L 10/31/15 10:46 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 10:46 96-12-82.0 2.0 1 Dibromochloromethane ND ug/L 10/31/15 10:46 124-48-11.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/31/15 10:46 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/31/15 10:46 74-95-31.0 0.21 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 41 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-15 Lab ID:92273406018 Collected:10/27/15 11:00 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level 1,2-Dichlorobenzene ND ug/L 10/31/15 10:46 95-50-11.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/31/15 10:46 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 10:46 110-57-61.0 1.0 1 1,1-Dichloroethane ND ug/L 10/31/15 10:46 75-34-31.0 0.32 1 1,2-Dichloroethane ND ug/L 10/31/15 10:46 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/31/15 10:46 75-35-41.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/31/15 10:46 156-59-21.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/31/15 10:46 156-60-51.0 0.49 1 1,2-Dichloropropane ND ug/L 10/31/15 10:46 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/31/15 10:46 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/31/15 10:46 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/31/15 10:46 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/31/15 10:46 591-78-65.0 0.46 1 Iodomethane ND ug/L 10/31/15 10:46 74-88-45.0 0.32 1 Methylene Chloride ND ug/L 10/31/15 10:46 75-09-22.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 10:46 108-10-15.0 0.33 1 Styrene ND ug/L 10/31/15 10:46 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 10:46 630-20-61.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 10:46 79-34-51.0 0.40 1 Tetrachloroethene ND ug/L 10/31/15 10:46 127-18-41.0 0.46 1 Toluene ND ug/L 10/31/15 10:46 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/31/15 10:46 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/31/15 10:46 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/31/15 10:46 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/31/15 10:46 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/31/15 10:46 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/31/15 10:46 108-05-42.0 0.35 1 Vinyl chloride ND ug/L 10/31/15 10:46 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/31/15 10:46 1330-20-72.0 0.66 1 m&p-Xylene ND ug/L 10/31/15 10:46 179601-23-12.0 0.66 1 o-Xylene ND ug/L 10/31/15 10:46 95-47-61.0 0.23 1 Surrogates 4-Bromofluorobenzene (S)98 %10/31/15 10:46 460-00-470-130 1 1,2-Dichloroethane-d4 (S)108 %10/31/15 10:46 17060-07-070-130 1 Toluene-d8 (S)102 %10/31/15 10:46 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 42 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-16 Lab ID:92273406019 Collected:10/27/15 14:20 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method:Monitoring Well Data Collected By Mark Swann 11/16/15 10:551 Collected Date 10/27/15 11/16/15 10:551 Collected Time 14:20 11/16/15 10:551 Field pH 6.3 Std. Units 11/16/15 10:550.10 0.10 1 Field Temperature 14.5 deg C 11/16/15 10:550.50 0.50 1 Static Water Level 35.29 feet 11/16/15 10:551 Field Specific Conductance 248 umhos/cm 11/16/15 10:551.0 1.0 1 Turbidity 11.09 NTU 11/16/15 10:551.0 1.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/05/15 01:03 7440-36-010/29/15 20:005.0 3.8 1 Arsenic ND ug/L 11/05/15 01:03 7440-38-210/29/15 20:0010.0 2.5 1 Barium 188 ug/L 11/05/15 01:03 7440-39-310/29/15 20:005.0 2.5 1 Beryllium ND ug/L 11/05/15 01:03 7440-41-710/29/15 20:001.0 0.50 1 Cadmium 3.1 ug/L 11/05/15 01:03 7440-43-910/29/15 20:001.0 0.50 1 Chromium ND ug/L 11/05/15 01:03 7440-47-310/29/15 20:005.0 2.5 1 Cobalt 39.0 ug/L 11/05/15 01:03 7440-48-410/29/15 20:005.0 2.5 1 Copper 6.0 ug/L 11/05/15 01:03 7440-50-810/29/15 20:005.0 2.5 1 Lead ND ug/L 11/05/15 01:03 7439-92-110/29/15 20:005.0 2.5 1 Nickel 8.7 ug/L 11/05/15 01:03 7440-02-010/29/15 20:005.0 2.5 1 Selenium ND ug/L 11/05/15 01:03 7782-49-210/29/15 20:0010.0 5.0 1 Silver ND ug/L 11/05/15 01:03 7440-22-410/29/15 20:005.0 2.5 1 Thallium ND ug/L 11/05/15 01:03 7440-28-010/29/15 20:005.4 5.0 1 Vanadium 9.8 ug/L 11/05/15 01:03 7440-62-210/29/15 20:005.0 2.5 1 Zinc 36.4 ug/L 11/05/15 01:03 7440-66-610/29/15 20:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 10/31/15 11:38 67-64-125.0 10.0 1 Acrylonitrile ND ug/L 10/31/15 11:38 107-13-110.0 1.9 1 Benzene ND ug/L 10/31/15 11:38 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/31/15 11:38 74-97-51.0 0.17 1 Bromodichloromethane ND ug/L 10/31/15 11:38 75-27-41.0 0.18 1 Bromoform ND ug/L 10/31/15 11:38 75-25-21.0 0.26 1 Bromomethane ND ug/L 10/31/15 11:38 74-83-92.0 0.29 1 2-Butanone (MEK)ND ug/L 10/31/15 11:38 78-93-35.0 0.96 1 Carbon disulfide ND ug/L 10/31/15 11:38 75-15-02.0 1.2 1 Carbon tetrachloride ND ug/L 10/31/15 11:38 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/31/15 11:38 108-90-71.0 0.23 1 Chloroethane ND ug/L 10/31/15 11:38 75-00-3 L21.0 0.54 1 Chloroform ND ug/L 10/31/15 11:38 67-66-31.0 0.14 1 Chloromethane ND ug/L 10/31/15 11:38 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 11:38 96-12-82.0 2.0 1 Dibromochloromethane ND ug/L 10/31/15 11:38 124-48-11.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/31/15 11:38 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/31/15 11:38 74-95-31.0 0.21 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 43 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-16 Lab ID:92273406019 Collected:10/27/15 14:20 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level 1,2-Dichlorobenzene ND ug/L 10/31/15 11:38 95-50-11.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/31/15 11:38 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 11:38 110-57-61.0 1.0 1 1,1-Dichloroethane ND ug/L 10/31/15 11:38 75-34-31.0 0.32 1 1,2-Dichloroethane ND ug/L 10/31/15 11:38 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/31/15 11:38 75-35-41.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/31/15 11:38 156-59-21.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/31/15 11:38 156-60-51.0 0.49 1 1,2-Dichloropropane ND ug/L 10/31/15 11:38 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/31/15 11:38 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/31/15 11:38 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/31/15 11:38 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/31/15 11:38 591-78-65.0 0.46 1 Iodomethane ND ug/L 10/31/15 11:38 74-88-45.0 0.32 1 Methylene Chloride ND ug/L 10/31/15 11:38 75-09-22.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 11:38 108-10-15.0 0.33 1 Styrene ND ug/L 10/31/15 11:38 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 11:38 630-20-61.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 11:38 79-34-51.0 0.40 1 Tetrachloroethene ND ug/L 10/31/15 11:38 127-18-41.0 0.46 1 Toluene ND ug/L 10/31/15 11:38 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/31/15 11:38 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/31/15 11:38 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/31/15 11:38 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/31/15 11:38 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/31/15 11:38 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/31/15 11:38 108-05-42.0 0.35 1 Vinyl chloride ND ug/L 10/31/15 11:38 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/31/15 11:38 1330-20-72.0 0.66 1 m&p-Xylene ND ug/L 10/31/15 11:38 179601-23-12.0 0.66 1 o-Xylene ND ug/L 10/31/15 11:38 95-47-61.0 0.23 1 Surrogates 4-Bromofluorobenzene (S)99 %10/31/15 11:38 460-00-470-130 1 1,2-Dichloroethane-d4 (S)110 %10/31/15 11:38 17060-07-070-130 1 Toluene-d8 (S)101 %10/31/15 11:38 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 44 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-17 Lab ID:92273406020 Collected:10/27/15 14:35 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method:Monitoring Well Data Collected By Mark Swann 11/16/15 10:561 Collected Date 10/27/15 11/16/15 10:561 Collected Time 14:35 11/16/15 10:561 Field pH 5.9 Std. Units 11/16/15 10:560.10 0.10 1 Field Temperature 13.4 deg C 11/16/15 10:560.50 0.50 1 Static Water Level 56.98 feet 11/16/15 10:561 Field Specific Conductance 169 umhos/cm 11/16/15 10:561.0 1.0 1 Turbidity 5.11 NTU 11/16/15 10:561.0 1.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/05/15 01:06 7440-36-010/29/15 20:005.0 3.8 1 Arsenic ND ug/L 11/05/15 01:06 7440-38-210/29/15 20:0010.0 2.5 1 Barium 191 ug/L 11/05/15 01:06 7440-39-310/29/15 20:005.0 2.5 1 Beryllium ND ug/L 11/05/15 01:06 7440-41-710/29/15 20:001.0 0.50 1 Cadmium ND ug/L 11/05/15 01:06 7440-43-910/29/15 20:001.0 0.50 1 Chromium ND ug/L 11/05/15 01:06 7440-47-310/29/15 20:005.0 2.5 1 Cobalt ND ug/L 11/05/15 01:06 7440-48-410/29/15 20:005.0 2.5 1 Copper ND ug/L 11/05/15 01:06 7440-50-810/29/15 20:005.0 2.5 1 Lead ND ug/L 11/05/15 01:06 7439-92-110/29/15 20:005.0 2.5 1 Nickel ND ug/L 11/05/15 01:06 7440-02-010/29/15 20:005.0 2.5 1 Selenium ND ug/L 11/05/15 01:06 7782-49-210/29/15 20:0010.0 5.0 1 Silver ND ug/L 11/05/15 01:06 7440-22-410/29/15 20:005.0 2.5 1 Thallium ND ug/L 11/05/15 01:06 7440-28-010/29/15 20:005.4 5.0 1 Vanadium ND ug/L 11/05/15 01:06 7440-62-210/29/15 20:005.0 2.5 1 Zinc ND ug/L 11/05/15 01:06 7440-66-610/29/15 20:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 10/31/15 11:55 67-64-125.0 10.0 1 Acrylonitrile ND ug/L 10/31/15 11:55 107-13-110.0 1.9 1 Benzene ND ug/L 10/31/15 11:55 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/31/15 11:55 74-97-51.0 0.17 1 Bromodichloromethane ND ug/L 10/31/15 11:55 75-27-41.0 0.18 1 Bromoform ND ug/L 10/31/15 11:55 75-25-21.0 0.26 1 Bromomethane ND ug/L 10/31/15 11:55 74-83-92.0 0.29 1 2-Butanone (MEK)ND ug/L 10/31/15 11:55 78-93-35.0 0.96 1 Carbon disulfide ND ug/L 10/31/15 11:55 75-15-02.0 1.2 1 Carbon tetrachloride ND ug/L 10/31/15 11:55 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/31/15 11:55 108-90-71.0 0.23 1 Chloroethane ND ug/L 10/31/15 11:55 75-00-3 L21.0 0.54 1 Chloroform ND ug/L 10/31/15 11:55 67-66-31.0 0.14 1 Chloromethane ND ug/L 10/31/15 11:55 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 11:55 96-12-82.0 2.0 1 Dibromochloromethane ND ug/L 10/31/15 11:55 124-48-11.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/31/15 11:55 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/31/15 11:55 74-95-31.0 0.21 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 45 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:MW-17 Lab ID:92273406020 Collected:10/27/15 14:35 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level 1,2-Dichlorobenzene ND ug/L 10/31/15 11:55 95-50-11.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/31/15 11:55 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 11:55 110-57-61.0 1.0 1 1,1-Dichloroethane ND ug/L 10/31/15 11:55 75-34-31.0 0.32 1 1,2-Dichloroethane ND ug/L 10/31/15 11:55 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/31/15 11:55 75-35-41.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/31/15 11:55 156-59-21.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/31/15 11:55 156-60-51.0 0.49 1 1,2-Dichloropropane ND ug/L 10/31/15 11:55 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/31/15 11:55 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/31/15 11:55 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/31/15 11:55 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/31/15 11:55 591-78-65.0 0.46 1 Iodomethane ND ug/L 10/31/15 11:55 74-88-45.0 0.32 1 Methylene Chloride ND ug/L 10/31/15 11:55 75-09-22.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 11:55 108-10-15.0 0.33 1 Styrene ND ug/L 10/31/15 11:55 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 11:55 630-20-61.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 11:55 79-34-51.0 0.40 1 Tetrachloroethene ND ug/L 10/31/15 11:55 127-18-41.0 0.46 1 Toluene ND ug/L 10/31/15 11:55 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/31/15 11:55 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/31/15 11:55 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/31/15 11:55 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/31/15 11:55 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/31/15 11:55 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/31/15 11:55 108-05-42.0 0.35 1 Vinyl chloride ND ug/L 10/31/15 11:55 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/31/15 11:55 1330-20-72.0 0.66 1 m&p-Xylene ND ug/L 10/31/15 11:55 179601-23-12.0 0.66 1 o-Xylene ND ug/L 10/31/15 11:55 95-47-61.0 0.23 1 Surrogates 4-Bromofluorobenzene (S)98 %10/31/15 11:55 460-00-470-130 1 1,2-Dichloroethane-d4 (S)111 %10/31/15 11:55 17060-07-070-130 1 Toluene-d8 (S)102 %10/31/15 11:55 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 46 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:TVL BLK Lab ID:92273406021 Collected:10/26/15 08:00 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 10/31/15 04:25 67-64-125.0 10.0 1 Acrylonitrile ND ug/L 10/31/15 04:25 107-13-110.0 1.9 1 Benzene ND ug/L 10/31/15 04:25 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/31/15 04:25 74-97-51.0 0.17 1 Bromodichloromethane ND ug/L 10/31/15 04:25 75-27-41.0 0.18 1 Bromoform ND ug/L 10/31/15 04:25 75-25-21.0 0.26 1 Bromomethane ND ug/L 10/31/15 04:25 74-83-92.0 0.29 1 2-Butanone (MEK)ND ug/L 10/31/15 04:25 78-93-35.0 0.96 1 Carbon disulfide ND ug/L 10/31/15 04:25 75-15-02.0 1.2 1 Carbon tetrachloride ND ug/L 10/31/15 04:25 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/31/15 04:25 108-90-71.0 0.23 1 Chloroethane ND ug/L 10/31/15 04:25 75-00-3 L21.0 0.54 1 Chloroform ND ug/L 10/31/15 04:25 67-66-31.0 0.14 1 Chloromethane ND ug/L 10/31/15 04:25 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 04:25 96-12-82.0 2.0 1 Dibromochloromethane ND ug/L 10/31/15 04:25 124-48-11.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/31/15 04:25 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/31/15 04:25 74-95-31.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/31/15 04:25 95-50-11.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/31/15 04:25 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 04:25 110-57-61.0 1.0 1 1,1-Dichloroethane ND ug/L 10/31/15 04:25 75-34-31.0 0.32 1 1,2-Dichloroethane ND ug/L 10/31/15 04:25 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/31/15 04:25 75-35-41.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/31/15 04:25 156-59-21.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/31/15 04:25 156-60-51.0 0.49 1 1,2-Dichloropropane ND ug/L 10/31/15 04:25 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/31/15 04:25 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/31/15 04:25 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/31/15 04:25 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/31/15 04:25 591-78-65.0 0.46 1 Iodomethane ND ug/L 10/31/15 04:25 74-88-45.0 0.32 1 Methylene Chloride ND ug/L 10/31/15 04:25 75-09-22.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 04:25 108-10-15.0 0.33 1 Styrene ND ug/L 10/31/15 04:25 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 04:25 630-20-61.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 04:25 79-34-51.0 0.40 1 Tetrachloroethene ND ug/L 10/31/15 04:25 127-18-41.0 0.46 1 Toluene ND ug/L 10/31/15 04:25 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/31/15 04:25 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/31/15 04:25 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/31/15 04:25 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/31/15 04:25 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/31/15 04:25 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/31/15 04:25 108-05-42.0 0.35 1 Vinyl chloride ND ug/L 10/31/15 04:25 75-01-41.0 0.62 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 47 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:TVL BLK Lab ID:92273406021 Collected:10/26/15 08:00 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Xylene (Total)ND ug/L 10/31/15 04:25 1330-20-72.0 0.66 1 m&p-Xylene ND ug/L 10/31/15 04:25 179601-23-12.0 0.66 1 o-Xylene ND ug/L 10/31/15 04:25 95-47-61.0 0.23 1 Surrogates 4-Bromofluorobenzene (S)99 %10/31/15 04:25 460-00-470-130 1 1,2-Dichloroethane-d4 (S)104 %10/31/15 04:25 17060-07-070-130 1 Toluene-d8 (S)100 %10/31/15 04:25 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 48 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:Equip Blk Lab ID:92273406022 Collected:10/27/15 08:30 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/05/15 01:09 7440-36-010/29/15 20:005.0 3.8 1 Arsenic ND ug/L 11/05/15 01:09 7440-38-210/29/15 20:0010.0 2.5 1 Barium ND ug/L 11/05/15 01:09 7440-39-310/29/15 20:005.0 2.5 1 Beryllium ND ug/L 11/05/15 01:09 7440-41-710/29/15 20:001.0 0.50 1 Cadmium ND ug/L 11/05/15 01:09 7440-43-910/29/15 20:001.0 0.50 1 Chromium ND ug/L 11/05/15 01:09 7440-47-310/29/15 20:005.0 2.5 1 Cobalt ND ug/L 11/05/15 01:09 7440-48-410/29/15 20:005.0 2.5 1 Copper ND ug/L 11/05/15 01:09 7440-50-810/29/15 20:005.0 2.5 1 Lead ND ug/L 11/05/15 01:09 7439-92-110/29/15 20:005.0 2.5 1 Nickel ND ug/L 11/05/15 01:09 7440-02-010/29/15 20:005.0 2.5 1 Selenium ND ug/L 11/05/15 01:09 7782-49-210/29/15 20:0010.0 5.0 1 Silver ND ug/L 11/05/15 01:09 7440-22-410/29/15 20:005.0 2.5 1 Thallium ND ug/L 11/05/15 01:09 7440-28-010/29/15 20:005.4 5.0 1 Vanadium ND ug/L 11/05/15 01:09 7440-62-210/29/15 20:005.0 2.5 1 Zinc ND ug/L 11/05/15 01:09 7440-66-610/29/15 20:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 10/31/15 05:00 67-64-125.0 10.0 1 Acrylonitrile ND ug/L 10/31/15 05:00 107-13-110.0 1.9 1 Benzene ND ug/L 10/31/15 05:00 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/31/15 05:00 74-97-51.0 0.17 1 Bromodichloromethane ND ug/L 10/31/15 05:00 75-27-41.0 0.18 1 Bromoform ND ug/L 10/31/15 05:00 75-25-21.0 0.26 1 Bromomethane ND ug/L 10/31/15 05:00 74-83-92.0 0.29 1 2-Butanone (MEK)ND ug/L 10/31/15 05:00 78-93-35.0 0.96 1 Carbon disulfide ND ug/L 10/31/15 05:00 75-15-02.0 1.2 1 Carbon tetrachloride ND ug/L 10/31/15 05:00 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/31/15 05:00 108-90-71.0 0.23 1 Chloroethane ND ug/L 10/31/15 05:00 75-00-3 L21.0 0.54 1 Chloroform ND ug/L 10/31/15 05:00 67-66-31.0 0.14 1 Chloromethane ND ug/L 10/31/15 05:00 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 05:00 96-12-82.0 2.0 1 Dibromochloromethane ND ug/L 10/31/15 05:00 124-48-11.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/31/15 05:00 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/31/15 05:00 74-95-31.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/31/15 05:00 95-50-11.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/31/15 05:00 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 05:00 110-57-61.0 1.0 1 1,1-Dichloroethane ND ug/L 10/31/15 05:00 75-34-31.0 0.32 1 1,2-Dichloroethane ND ug/L 10/31/15 05:00 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/31/15 05:00 75-35-41.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/31/15 05:00 156-59-21.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/31/15 05:00 156-60-51.0 0.49 1 1,2-Dichloropropane ND ug/L 10/31/15 05:00 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/31/15 05:00 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/31/15 05:00 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 49 of 83 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92273406 White Oak LF 10/26 Sample:Equip Blk Lab ID:92273406022 Collected:10/27/15 08:30 Received:10/27/15 15:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Ethylbenzene ND ug/L 10/31/15 05:00 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/31/15 05:00 591-78-65.0 0.46 1 Iodomethane ND ug/L 10/31/15 05:00 74-88-45.0 0.32 1 Methylene Chloride ND ug/L 10/31/15 05:00 75-09-22.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 05:00 108-10-15.0 0.33 1 Styrene ND ug/L 10/31/15 05:00 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 05:00 630-20-61.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 05:00 79-34-51.0 0.40 1 Tetrachloroethene ND ug/L 10/31/15 05:00 127-18-41.0 0.46 1 Toluene ND ug/L 10/31/15 05:00 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/31/15 05:00 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/31/15 05:00 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/31/15 05:00 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/31/15 05:00 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/31/15 05:00 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/31/15 05:00 108-05-42.0 0.35 1 Vinyl chloride ND ug/L 10/31/15 05:00 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/31/15 05:00 1330-20-72.0 0.66 1 m&p-Xylene ND ug/L 10/31/15 05:00 179601-23-12.0 0.66 1 o-Xylene ND ug/L 10/31/15 05:00 95-47-61.0 0.23 1 Surrogates 4-Bromofluorobenzene (S)98 %10/31/15 05:00 460-00-470-130 1 1,2-Dichloroethane-d4 (S)105 %10/31/15 05:00 17060-07-070-130 1 Toluene-d8 (S)101 %10/31/15 05:00 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 50 of 83 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92273406 White Oak LF 10/26 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/19905 EPA 3010 EPA 6010 6010 MET NC Groundwater Associated Lab Samples:92273406001, 92273406002, 92273406003, 92273406004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1593024 Associated Lab Samples:92273406001, 92273406002, 92273406003, 92273406004 Matrix:Water AnalyzedMDL Antimony ug/L ND 5.0 10/30/15 22:423.8 Arsenic ug/L ND 10.0 10/30/15 22:422.5 Barium ug/L ND 5.0 10/30/15 22:422.5 Beryllium ug/L ND 1.0 10/30/15 22:420.50 Cadmium ug/L ND 1.0 10/30/15 22:420.50 Chromium ug/L ND 5.0 10/30/15 22:422.5 Cobalt ug/L ND 5.0 10/30/15 22:422.5 Copper ug/L ND 5.0 10/30/15 22:422.5 Lead ug/L ND 5.0 10/30/15 22:422.5 Nickel ug/L ND 5.0 10/30/15 22:422.5 Selenium ug/L ND 10.0 10/30/15 22:425.0 Silver ug/L ND 5.0 10/30/15 22:422.5 Thallium ug/L ND 5.4 10/30/15 22:425.0 Vanadium ug/L ND 5.0 10/30/15 22:422.5 Zinc ug/L ND 10.0 10/30/15 22:425.0 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1593025LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 491500 98 80-120 Arsenic ug/L 464500 93 80-120 Barium ug/L 479500 96 80-120 Beryllium ug/L 487500 97 80-120 Cadmium ug/L 482500 96 80-120 Chromium ug/L 474500 95 80-120 Cobalt ug/L 467500 93 80-120 Copper ug/L 494500 99 80-120 Lead ug/L 471500 94 80-120 Nickel ug/L 469500 94 80-120 Selenium ug/L 466500 93 80-120 Silver ug/L 237250 95 80-120 Thallium ug/L 465500 93 80-120 Vanadium ug/L 481500 96 80-120 Zinc ug/L 445500 89 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 51 of 83 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92273406 White Oak LF 10/26 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1593026MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92273337001 1593027 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony ug/L 500 106 75-12592 13 25500ND530464 Arsenic ug/L 500 101 75-12588 13 25500ND504441 Barium ug/L 500 107 75-12593 12 2550074.1J 607 539 Beryllium ug/L 500 109 75-12595 13 25500ND543475 Cadmium ug/L 500 105 75-12592 13 25500ND527461 Chromium ug/L 500 105 75-12593 13 25500ND528465 Cobalt ug/L 500 103 75-12591 13 25500ND517453 Copper ug/L 500 109 75-12594 15 25500ND544469 Lead ug/L 500 104 75-12590 13 25500ND518452 Nickel ug/L 500 104 75-12591 13 25500ND522457 Selenium ug/L 500 101 75-12588 14 25500ND505441 Silver ug/L 250 105 75-12591 14 25250ND262228 Thallium ug/L 500 102 75-12589 13 25500ND509446 Vanadium ug/L 500 108 75-12595 13 25500ND538473 Zinc ug/L 500 101 75-12588 13 25500ND506443 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 52 of 83 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92273406 White Oak LF 10/26 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/19918 EPA 3010 EPA 6010 6010 MET NC Groundwater Associated Lab Samples:92273406005, 92273406007, 92273406008, 92273406009, 92273406010, 92273406011, 92273406012, 92273406013, 92273406014, 92273406015 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1594175 Associated Lab Samples:92273406005, 92273406007, 92273406008, 92273406009, 92273406010, 92273406011, 92273406012, 92273406013, 92273406014, 92273406015 Matrix:Water AnalyzedMDL Antimony ug/L ND 5.0 11/04/15 19:093.8 Arsenic ug/L ND 10.0 11/04/15 19:092.5 Barium ug/L ND 5.0 11/04/15 19:092.5 Beryllium ug/L ND 1.0 11/04/15 19:090.50 Cadmium ug/L ND 1.0 11/04/15 19:090.50 Chromium ug/L ND 5.0 11/04/15 19:092.5 Cobalt ug/L ND 5.0 11/04/15 19:092.5 Copper ug/L ND 5.0 11/04/15 19:092.5 Lead ug/L ND 5.0 11/04/15 19:092.5 Nickel ug/L ND 5.0 11/04/15 19:092.5 Selenium ug/L ND 10.0 11/04/15 19:095.0 Silver ug/L ND 5.0 11/04/15 19:092.5 Thallium ug/L ND 5.4 11/04/15 19:095.0 Vanadium ug/L ND 5.0 11/04/15 19:092.5 Zinc ug/L ND 10.0 11/04/15 19:095.0 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1594176LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 452500 90 80-120 Arsenic ug/L 485500 97 80-120 Barium ug/L 471500 94 80-120 Beryllium ug/L 455500 91 80-120 Cadmium ug/L 469500 94 80-120 Chromium ug/L 478500 96 80-120 Cobalt ug/L 487500 97 80-120 Copper ug/L 493500 99 80-120 Lead ug/L 485500 97 80-120 Nickel ug/L 471500 94 80-120 Selenium ug/L 475500 95 80-120 Silver ug/L 218250 87 80-120 Thallium ug/L 445500 89 80-120 Vanadium ug/L 461500 92 80-120 Zinc ug/L 501500 100 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 53 of 83 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92273406 White Oak LF 10/26 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1594177MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92273330003 1594178 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony ug/L 500 91 75-125105 14 25500ND459530 Arsenic ug/L 500 98 75-125115 15 25500ND493573 Barium ug/L 500 97 75-125116 7 2550083713201420 Beryllium ug/L 500 92 75-125108 15 25500ND461538 Cadmium ug/L 500 95 75-125109 14 25500ND474547 Chromium ug/L 500 94 75-125110 16 255003.4J 473 555 Cobalt ug/L 500 93 75-125108 15 2550011.7 477 553 Copper ug/L 500 99 75-125114 14 25500ND496572 Lead ug/L 500 92 75-125107 15 25500ND463537 Nickel ug/L 500 90 75-125104 15 255008.4J 458 531 Selenium ug/L 500 96 75-125110 14 25500ND479551 Silver ug/L 250 88 75-125101 15 25250ND220255 Thallium ug/L 500 82 75-12595 16 25500ND408477 Vanadium ug/L 500 93 75-125109 16 255005.9J 470 549 Zinc ug/L 500 95 75-125112 16 25500ND478562 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 54 of 83 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92273406 White Oak LF 10/26 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/19926 EPA 3010 EPA 6010 6010 MET NC Groundwater Associated Lab Samples:92273406006, 92273406016, 92273406017, 92273406018, 92273406019, 92273406020, 92273406022 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1595304 Associated Lab Samples:92273406006, 92273406016, 92273406017, 92273406018, 92273406019, 92273406020, 92273406022 Matrix:Water AnalyzedMDL Antimony ug/L ND 5.0 11/05/15 00:303.8 Arsenic ug/L ND 10.0 11/05/15 00:302.5 Barium ug/L ND 5.0 11/05/15 00:302.5 Beryllium ug/L ND 1.0 11/05/15 00:300.50 Cadmium ug/L ND 1.0 11/05/15 00:300.50 Chromium ug/L ND 5.0 11/05/15 00:302.5 Cobalt ug/L ND 5.0 11/05/15 00:302.5 Copper ug/L ND 5.0 11/05/15 00:302.5 Lead ug/L ND 5.0 11/05/15 00:302.5 Nickel ug/L ND 5.0 11/05/15 00:302.5 Selenium ug/L ND 10.0 11/05/15 00:305.0 Silver ug/L ND 5.0 11/05/15 00:302.5 Thallium ug/L ND 5.4 11/05/15 00:305.0 Vanadium ug/L ND 5.0 11/05/15 00:302.5 Zinc ug/L ND 10.0 11/05/15 00:305.0 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1595305LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 442500 88 80-120 Arsenic ug/L 452500 90 80-120 Barium ug/L 426500 85 80-120 Beryllium ug/L 412500 82 80-120 Cadmium ug/L 444500 89 80-120 Chromium ug/L 443500 89 80-120 Cobalt ug/L 453500 91 80-120 Copper ug/L 446500 89 80-120 Lead ug/L 455500 91 80-120 Nickel ug/L 440500 88 80-120 Selenium ug/L 448500 90 80-120 Silver ug/L 218250 87 80-120 Thallium ug/L 473500 95 80-120 Vanadium ug/L 436500 87 80-120 Zinc ug/L 463500 93 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 55 of 83 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92273406 White Oak LF 10/26 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1595306MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92273406006 1595307 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony ug/L 500 87 75-12588 1 25500ND435441 Arsenic ug/L 500 89 75-12590 1 25500ND444449 Barium ug/L 500 85 75-12584 2 2550031.4 457 450 Beryllium ug/L 500 83 75-12581 2 25500ND414404 Cadmium ug/L 500 88 75-12588 0 25500ND439440 Chromium ug/L 500 88 75-12586 2 25500ND441431 Cobalt ug/L 500 89 75-12589 0 25500ND447446 Copper ug/L 500 89 75-12589 0 25500ND445444 Lead ug/L 500 90 75-12589 0 25500ND449447 Nickel ug/L 500 87 75-12587 0 25500ND437435 Selenium ug/L 500 88 75-12589 1 25500ND438444 Silver ug/L 250 86 75-12584 1 25250ND215212 Thallium ug/L 500 93 75-12593 0 25500ND465465 Vanadium ug/L 500 87 75-12585 3 25500ND436425 Zinc ug/L 500 92 75-12590 2 25500ND466458 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 56 of 83 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92273406 White Oak LF 10/26 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MSV/34071 EPA 8260 EPA 8260 8260 MSV Low Level Associated Lab Samples:92273406001, 92273406002, 92273406003, 92273406004, 92273406005, 92273406006, 92273406007, 92273406008, 92273406009, 92273406010, 92273406011, 92273406012, 92273406013, 92273406014, 92273406021, 92273406022 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1596108 Associated Lab Samples:92273406001, 92273406002, 92273406003, 92273406004, 92273406005, 92273406006, 92273406007, 92273406008, 92273406009, 92273406010, 92273406011, 92273406012, 92273406013, 92273406014, 92273406021, 92273406022 Matrix:Water AnalyzedMDL 1,1,1,2-Tetrachloroethane ug/L ND 1.0 10/31/15 03:340.33 1,1,1-Trichloroethane ug/L ND 1.0 10/31/15 03:340.48 1,1,2,2-Tetrachloroethane ug/L ND 1.0 10/31/15 03:340.40 1,1,2-Trichloroethane ug/L ND 1.0 10/31/15 03:340.29 1,1-Dichloroethane ug/L ND 1.0 10/31/15 03:340.32 1,1-Dichloroethene ug/L ND 1.0 10/31/15 03:340.56 1,2,3-Trichloropropane ug/L ND 1.0 10/31/15 03:340.41 1,2-Dibromo-3-chloropropane ug/L ND 2.0 10/31/15 03:342.0 1,2-Dibromoethane (EDB)ug/L ND 1.0 10/31/15 03:340.27 1,2-Dichlorobenzene ug/L ND 1.0 10/31/15 03:340.30 1,2-Dichloroethane ug/L ND 1.0 10/31/15 03:340.24 1,2-Dichloropropane ug/L ND 1.0 10/31/15 03:340.27 1,4-Dichlorobenzene ug/L ND 1.0 10/31/15 03:340.33 2-Butanone (MEK)ug/L ND 5.0 10/31/15 03:340.96 2-Hexanone ug/L ND 5.0 10/31/15 03:340.46 4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 10/31/15 03:340.33 Acetone ug/L ND 25.0 10/31/15 03:3410.0 Acrylonitrile ug/L ND 10.0 10/31/15 03:341.9 Benzene ug/L ND 1.0 10/31/15 03:340.25 Bromochloromethane ug/L ND 1.0 10/31/15 03:340.17 Bromodichloromethane ug/L ND 1.0 10/31/15 03:340.18 Bromoform ug/L ND 1.0 10/31/15 03:340.26 Bromomethane ug/L ND 2.0 10/31/15 03:340.29 Carbon disulfide ug/L ND 2.0 10/31/15 03:341.2 Carbon tetrachloride ug/L ND 1.0 10/31/15 03:340.25 Chlorobenzene ug/L ND 1.0 10/31/15 03:340.23 Chloroethane ug/L ND 1.0 10/31/15 03:340.54 Chloroform ug/L ND 1.0 10/31/15 03:340.14 Chloromethane ug/L ND 1.0 10/31/15 03:340.11 cis-1,2-Dichloroethene ug/L ND 1.0 10/31/15 03:340.19 cis-1,3-Dichloropropene ug/L ND 1.0 10/31/15 03:340.13 Dibromochloromethane ug/L ND 1.0 10/31/15 03:340.21 Dibromomethane ug/L ND 1.0 10/31/15 03:340.21 Ethylbenzene ug/L ND 1.0 10/31/15 03:340.30 Iodomethane ug/L ND 5.0 10/31/15 03:340.32 m&p-Xylene ug/L ND 2.0 10/31/15 03:340.66 Methylene Chloride ug/L ND 2.0 10/31/15 03:340.97 o-Xylene ug/L ND 1.0 10/31/15 03:340.23 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 57 of 83 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92273406 White Oak LF 10/26 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1596108 Associated Lab Samples:92273406001, 92273406002, 92273406003, 92273406004, 92273406005, 92273406006, 92273406007, 92273406008, 92273406009, 92273406010, 92273406011, 92273406012, 92273406013, 92273406014, 92273406021, 92273406022 Matrix:Water AnalyzedMDL Styrene ug/L ND 1.0 10/31/15 03:340.26 Tetrachloroethene ug/L ND 1.0 10/31/15 03:340.46 Toluene ug/L ND 1.0 10/31/15 03:340.26 trans-1,2-Dichloroethene ug/L ND 1.0 10/31/15 03:340.49 trans-1,3-Dichloropropene ug/L ND 1.0 10/31/15 03:340.26 trans-1,4-Dichloro-2-butene ug/L ND 1.0 10/31/15 03:341.0 Trichloroethene ug/L ND 1.0 10/31/15 03:340.47 Trichlorofluoromethane ug/L ND 1.0 10/31/15 03:340.20 Vinyl acetate ug/L ND 2.0 10/31/15 03:340.35 Vinyl chloride ug/L ND 1.0 10/31/15 03:340.62 Xylene (Total)ug/L ND 2.0 10/31/15 03:340.66 1,2-Dichloroethane-d4 (S)%102 70-130 10/31/15 03:34 4-Bromofluorobenzene (S)%99 70-130 10/31/15 03:34 Toluene-d8 (S)%101 70-130 10/31/15 03:34 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596109LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 47.950 96 70-130 1,1,1-Trichloroethane ug/L 57.050 114 70-130 1,1,2,2-Tetrachloroethane ug/L 56.450 113 70-130 1,1,2-Trichloroethane ug/L 54.050 108 70-130 1,1-Dichloroethane ug/L 55.050 110 70-130 1,1-Dichloroethene ug/L 55.350 111 70-132 1,2,3-Trichloropropane ug/L 55.750 111 70-130 1,2-Dibromo-3-chloropropane ug/L 51.550 103 70-130 1,2-Dibromoethane (EDB)ug/L 59.050 118 70-130 1,2-Dichlorobenzene ug/L 55.250 110 70-130 1,2-Dichloroethane ug/L 50.650 101 70-130 1,2-Dichloropropane ug/L 54.850 110 70-130 1,4-Dichlorobenzene ug/L 52.450 105 70-130 2-Butanone (MEK)ug/L 124100 124 70-145 2-Hexanone ug/L 124100 124 70-144 4-Methyl-2-pentanone (MIBK)ug/L 120100 120 70-140 Acetone ug/L 115100 115 50-175 Acrylonitrile ug/L 294250 118 70-143 Benzene ug/L 54.850 110 70-130 Bromochloromethane ug/L 57.250 114 70-130 Bromodichloromethane ug/L 47.550 95 70-130 Bromoform ug/L 45.850 92 70-130 Bromomethane ug/L 37.150 74 54-130 Carbon disulfide ug/L 44.250 88 70-131 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 58 of 83 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92273406 White Oak LF 10/26 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596109LABORATORY CONTROL SAMPLE: LCSSpike Carbon tetrachloride ug/L 47.050 94 70-132 Chlorobenzene ug/L 53.250 106 70-130 Chloroethane ug/L 28.3 L0505764-134 Chloroform ug/L 54.650 109 70-130 Chloromethane ug/L 55.650 111 64-130 cis-1,2-Dichloroethene ug/L 55.350 111 70-131 cis-1,3-Dichloropropene ug/L 49.250 98 70-130 Dibromochloromethane ug/L 44.950 90 70-130 Dibromomethane ug/L 54.850 110 70-131 Ethylbenzene ug/L 55.050 110 70-130 Iodomethane ug/L 101100 101 49-180 m&p-Xylene ug/L 110100 110 70-130 Methylene Chloride ug/L 53.450 107 63-130 o-Xylene ug/L 56.750 113 70-130 Styrene ug/L 51.050 102 70-130 Tetrachloroethene ug/L 51.750 103 70-130 Toluene ug/L 53.650 107 70-130 trans-1,2-Dichloroethene ug/L 56.450 113 70-130 trans-1,3-Dichloropropene ug/L 48.150 96 70-132 trans-1,4-Dichloro-2-butene ug/L 57.550 115 70-141 Trichloroethene ug/L 51.250 102 70-130 Trichlorofluoromethane ug/L 45.550 91 62-133 Vinyl acetate ug/L 110100 110 66-157 Vinyl chloride ug/L 57.650 115 50-150 Xylene (Total)ug/L 167150 111 70-130 1,2-Dichloroethane-d4 (S)%99 70-130 4-Bromofluorobenzene (S)%101 70-130 Toluene-d8 (S)%100 70-130 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1596110MATRIX SPIKE SAMPLE: MSSpike Result 92273406001 1,1,1,2-Tetrachloroethane ug/L 23.120 116 70-130ND 1,1,1-Trichloroethane ug/L 28.0 M12014070-130ND 1,1,2,2-Tetrachloroethane ug/L 23.720 119 70-130ND 1,1,2-Trichloroethane ug/L 23.720 118 70-130ND 1,1-Dichloroethane ug/L 26.2 M12013170-130ND 1,1-Dichloroethene ug/L 27.920 140 70-166ND 1,2,3-Trichloropropane ug/L 23.420 117 70-130ND 1,2-Dibromo-3-chloropropane ug/L 20.920 105 70-130ND 1,2-Dibromoethane (EDB)ug/L 25.020 125 70-130ND 1,2-Dichlorobenzene ug/L 24.420 122 70-130ND 1,2-Dichloroethane ug/L 23.920 119 70-130ND 1,2-Dichloropropane ug/L 24.820 124 70-130ND 1,4-Dichlorobenzene ug/L 23.920 119 70-130ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 59 of 83 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92273406 White Oak LF 10/26 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1596110MATRIX SPIKE SAMPLE: MSSpike Result 92273406001 2-Butanone (MEK)ug/L 55.3 M14013870-130ND 2-Hexanone ug/L 51.440 128 70-130ND 4-Methyl-2-pentanone (MIBK)ug/L 51.840 129 70-130ND Acetone ug/L 49.940 125 70-130ND Acrylonitrile ug/L 135 M110013570-130ND Benzene ug/L 25.620 128 70-148ND Bromochloromethane ug/L 26.4 M12013270-130ND Bromodichloromethane ug/L 23.220 116 70-130ND Bromoform ug/L 19.820 99 70-130ND Bromomethane ug/L 22.020 110 70-130ND Carbon disulfide ug/L 23.820 119 70-130ND Carbon tetrachloride ug/L 25.420 127 70-130ND Chlorobenzene ug/L 24.520 122 70-146ND Chloroethane ug/L 18.520 92 70-130ND Chloroform ug/L 25.320 127 70-130ND Chloromethane ug/L 27.9 M12014070-130ND cis-1,2-Dichloroethene ug/L 26.3 M12013170-130ND cis-1,3-Dichloropropene ug/L 23.520 117 70-130ND Dibromochloromethane ug/L 21.620 108 70-130ND Dibromomethane ug/L 24.020 120 70-130ND Ethylbenzene ug/L 25.720 128 70-130ND Iodomethane ug/L 43.640 109 70-130ND m&p-Xylene ug/L 50.640 127 70-130ND Methylene Chloride ug/L 25.520 128 70-130ND o-Xylene ug/L 24.920 124 70-130ND Styrene ug/L 24.220 121 70-130ND Tetrachloroethene ug/L 24.620 123 70-130ND Toluene ug/L 24.920 124 70-155ND trans-1,2-Dichloroethene ug/L 27.5 M12013770-130ND trans-1,3-Dichloropropene ug/L 23.720 118 70-130ND trans-1,4-Dichloro-2-butene ug/L 25.720 128 70-130ND Trichloroethene ug/L 24.020 120 69-151ND Trichlorofluoromethane ug/L 26.020 130 70-130ND Vinyl acetate ug/L 51.240 128 70-130ND Vinyl chloride ug/L 28.1 M12014170-130ND 1,2-Dichloroethane-d4 (S)%104 70-130 4-Bromofluorobenzene (S)%98 70-130 Toluene-d8 (S)%99 70-130 Parameter Units Dup Result Max RPD QualifiersRPDResult 92273406002 1596111SAMPLE DUPLICATE: 1,1,1,2-Tetrachloroethane ug/L ND 30ND 1,1,1-Trichloroethane ug/L ND 30ND 1,1,2,2-Tetrachloroethane ug/L ND 30ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 60 of 83 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92273406 White Oak LF 10/26 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result Max RPD QualifiersRPDResult 92273406002 1596111SAMPLE DUPLICATE: 1,1,2-Trichloroethane ug/L ND 30ND 1,1-Dichloroethane ug/L ND 30ND 1,1-Dichloroethene ug/L ND 30ND 1,2,3-Trichloropropane ug/L ND 30ND 1,2-Dibromo-3-chloropropane ug/L ND 30ND 1,2-Dibromoethane (EDB)ug/L ND 30ND 1,2-Dichlorobenzene ug/L ND 30ND 1,2-Dichloroethane ug/L ND 30ND 1,2-Dichloropropane ug/L ND 30ND 1,4-Dichlorobenzene ug/L ND 30ND 2-Butanone (MEK)ug/L ND 30ND 2-Hexanone ug/L ND 30ND 4-Methyl-2-pentanone (MIBK)ug/L ND 30ND Acetone ug/L ND 30ND Acrylonitrile ug/L ND 30ND Benzene ug/L ND 30ND Bromochloromethane ug/L ND 30ND Bromodichloromethane ug/L ND 30ND Bromoform ug/L ND 30ND Bromomethane ug/L ND 30ND Carbon disulfide ug/L 5.4 30ND Carbon tetrachloride ug/L ND 30ND Chlorobenzene ug/L ND 30ND Chloroethane ug/L ND 30ND Chloroform ug/L ND 30ND Chloromethane ug/L ND 30ND cis-1,2-Dichloroethene ug/L ND 30ND cis-1,3-Dichloropropene ug/L ND 30ND Dibromochloromethane ug/L ND 30ND Dibromomethane ug/L ND 30ND Ethylbenzene ug/L ND 30ND Iodomethane ug/L ND 30ND m&p-Xylene ug/L ND 30ND Methylene Chloride ug/L ND 30ND o-Xylene ug/L ND 30ND Styrene ug/L ND 30ND Tetrachloroethene ug/L ND 30ND Toluene ug/L ND 30ND trans-1,2-Dichloroethene ug/L ND 30ND trans-1,3-Dichloropropene ug/L ND 30ND trans-1,4-Dichloro-2-butene ug/L ND 30ND Trichloroethene ug/L ND 30ND Trichlorofluoromethane ug/L ND 30ND Vinyl acetate ug/L ND 30ND Vinyl chloride ug/L ND 30ND Xylene (Total)ug/L ND 30ND 1,2-Dichloroethane-d4 (S)%109 3106 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 61 of 83 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92273406 White Oak LF 10/26 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result Max RPD QualifiersRPDResult 92273406002 1596111SAMPLE DUPLICATE: 4-Bromofluorobenzene (S)%97 198 Toluene-d8 (S)%101 1101 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 62 of 83 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92273406 White Oak LF 10/26 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MSV/34073 EPA 8260 EPA 8260 8260 MSV Low Level Associated Lab Samples:92273406015, 92273406016, 92273406017, 92273406018, 92273406019, 92273406020 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1596124 Associated Lab Samples:92273406015, 92273406016, 92273406017, 92273406018, 92273406019, 92273406020 Matrix:Water AnalyzedMDL 1,1,1,2-Tetrachloroethane ug/L ND 1.0 10/31/15 03:510.33 1,1,1-Trichloroethane ug/L ND 1.0 10/31/15 03:510.48 1,1,2,2-Tetrachloroethane ug/L ND 1.0 10/31/15 03:510.40 1,1,2-Trichloroethane ug/L ND 1.0 10/31/15 03:510.29 1,1-Dichloroethane ug/L ND 1.0 10/31/15 03:510.32 1,1-Dichloroethene ug/L ND 1.0 10/31/15 03:510.56 1,2,3-Trichloropropane ug/L ND 1.0 10/31/15 03:510.41 1,2-Dibromo-3-chloropropane ug/L ND 2.0 10/31/15 03:512.0 1,2-Dibromoethane (EDB)ug/L ND 1.0 10/31/15 03:510.27 1,2-Dichlorobenzene ug/L ND 1.0 10/31/15 03:510.30 1,2-Dichloroethane ug/L ND 1.0 10/31/15 03:510.24 1,2-Dichloropropane ug/L ND 1.0 10/31/15 03:510.27 1,4-Dichlorobenzene ug/L ND 1.0 10/31/15 03:510.33 2-Butanone (MEK)ug/L ND 5.0 10/31/15 03:510.96 2-Hexanone ug/L ND 5.0 10/31/15 03:510.46 4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 10/31/15 03:510.33 Acetone ug/L ND 25.0 10/31/15 03:5110.0 Acrylonitrile ug/L ND 10.0 10/31/15 03:511.9 Benzene ug/L ND 1.0 10/31/15 03:510.25 Bromochloromethane ug/L ND 1.0 10/31/15 03:510.17 Bromodichloromethane ug/L ND 1.0 10/31/15 03:510.18 Bromoform ug/L ND 1.0 10/31/15 03:510.26 Bromomethane ug/L ND 2.0 10/31/15 03:510.29 Carbon disulfide ug/L ND 2.0 10/31/15 03:511.2 Carbon tetrachloride ug/L ND 1.0 10/31/15 03:510.25 Chlorobenzene ug/L ND 1.0 10/31/15 03:510.23 Chloroethane ug/L ND 1.0 10/31/15 03:510.54 Chloroform ug/L ND 1.0 10/31/15 03:510.14 Chloromethane ug/L ND 1.0 10/31/15 03:510.11 cis-1,2-Dichloroethene ug/L ND 1.0 10/31/15 03:510.19 cis-1,3-Dichloropropene ug/L ND 1.0 10/31/15 03:510.13 Dibromochloromethane ug/L ND 1.0 10/31/15 03:510.21 Dibromomethane ug/L ND 1.0 10/31/15 03:510.21 Ethylbenzene ug/L ND 1.0 10/31/15 03:510.30 Iodomethane ug/L ND 5.0 10/31/15 03:510.32 m&p-Xylene ug/L ND 2.0 10/31/15 03:510.66 Methylene Chloride ug/L ND 2.0 10/31/15 03:510.97 o-Xylene ug/L ND 1.0 10/31/15 03:510.23 Styrene ug/L ND 1.0 10/31/15 03:510.26 Tetrachloroethene ug/L ND 1.0 10/31/15 03:510.46 Toluene ug/L ND 1.0 10/31/15 03:510.26 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 63 of 83 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92273406 White Oak LF 10/26 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1596124 Associated Lab Samples:92273406015, 92273406016, 92273406017, 92273406018, 92273406019, 92273406020 Matrix:Water AnalyzedMDL trans-1,2-Dichloroethene ug/L ND 1.0 10/31/15 03:510.49 trans-1,3-Dichloropropene ug/L ND 1.0 10/31/15 03:510.26 trans-1,4-Dichloro-2-butene ug/L ND 1.0 10/31/15 03:511.0 Trichloroethene ug/L ND 1.0 10/31/15 03:510.47 Trichlorofluoromethane ug/L ND 1.0 10/31/15 03:510.20 Vinyl acetate ug/L ND 2.0 10/31/15 03:510.35 Vinyl chloride ug/L ND 1.0 10/31/15 03:510.62 Xylene (Total)ug/L ND 2.0 10/31/15 03:510.66 1,2-Dichloroethane-d4 (S)%103 70-130 10/31/15 03:51 4-Bromofluorobenzene (S)%99 70-130 10/31/15 03:51 Toluene-d8 (S)%101 70-130 10/31/15 03:51 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596125LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 47.350 95 70-130 1,1,1-Trichloroethane ug/L 53.450 107 70-130 1,1,2,2-Tetrachloroethane ug/L 56.650 113 70-130 1,1,2-Trichloroethane ug/L 53.050 106 70-130 1,1-Dichloroethane ug/L 52.050 104 70-130 1,1-Dichloroethene ug/L 50.650 101 70-132 1,2,3-Trichloropropane ug/L 55.950 112 70-130 1,2-Dibromo-3-chloropropane ug/L 52.150 104 70-130 1,2-Dibromoethane (EDB)ug/L 58.650 117 70-130 1,2-Dichlorobenzene ug/L 54.850 110 70-130 1,2-Dichloroethane ug/L 49.150 98 70-130 1,2-Dichloropropane ug/L 52.950 106 70-130 1,4-Dichlorobenzene ug/L 52.950 106 70-130 2-Butanone (MEK)ug/L 120100 120 70-145 2-Hexanone ug/L 121100 121 70-144 4-Methyl-2-pentanone (MIBK)ug/L 118100 118 70-140 Acetone ug/L 110100 110 50-175 Acrylonitrile ug/L 289250 116 70-143 Benzene ug/L 52.150 104 70-130 Bromochloromethane ug/L 55.750 111 70-130 Bromodichloromethane ug/L 46.550 93 70-130 Bromoform ug/L 46.550 93 70-130 Bromomethane ug/L 36.750 73 54-130 Carbon disulfide ug/L 42.350 85 70-131 Carbon tetrachloride ug/L 44.850 90 70-132 Chlorobenzene ug/L 51.650 103 70-130 Chloroethane ug/L 26.6 L0505364-134 Chloroform ug/L 52.350 105 70-130 Chloromethane ug/L 53.850 108 64-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 64 of 83 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92273406 White Oak LF 10/26 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596125LABORATORY CONTROL SAMPLE: LCSSpike cis-1,2-Dichloroethene ug/L 52.950 106 70-131 cis-1,3-Dichloropropene ug/L 48.450 97 70-130 Dibromochloromethane ug/L 44.150 88 70-130 Dibromomethane ug/L 53.950 108 70-131 Ethylbenzene ug/L 52.650 105 70-130 Iodomethane ug/L 96.3100 96 49-180 m&p-Xylene ug/L 106100 106 70-130 Methylene Chloride ug/L 51.650 103 63-130 o-Xylene ug/L 54.650 109 70-130 Styrene ug/L 49.750 99 70-130 Tetrachloroethene ug/L 48.650 97 70-130 Toluene ug/L 50.850 102 70-130 trans-1,2-Dichloroethene ug/L 52.550 105 70-130 trans-1,3-Dichloropropene ug/L 48.050 96 70-132 trans-1,4-Dichloro-2-butene ug/L 58.050 116 70-141 Trichloroethene ug/L 48.250 96 70-130 Trichlorofluoromethane ug/L 42.550 85 62-133 Vinyl acetate ug/L 108100 108 66-157 Vinyl chloride ug/L 53.050 106 50-150 Xylene (Total)ug/L 160150 107 70-130 1,2-Dichloroethane-d4 (S)%99 70-130 4-Bromofluorobenzene (S)%101 70-130 Toluene-d8 (S)%100 70-130 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1596126MATRIX SPIKE SAMPLE: MSSpike Result 92273406015 1,1,1,2-Tetrachloroethane ug/L 23.320 117 70-130ND 1,1,1-Trichloroethane ug/L 28.1 M12014070-130ND 1,1,2,2-Tetrachloroethane ug/L 23.220 116 70-130ND 1,1,2-Trichloroethane ug/L 23.820 119 70-130ND 1,1-Dichloroethane ug/L 26.5 M12013370-130ND 1,1-Dichloroethene ug/L 27.920 140 70-166ND 1,2,3-Trichloropropane ug/L 23.320 116 70-130ND 1,2-Dibromo-3-chloropropane ug/L 20.920 104 70-130ND 1,2-Dibromoethane (EDB)ug/L 25.220 126 70-130ND 1,2-Dichlorobenzene ug/L 23.720 118 70-130ND 1,2-Dichloroethane ug/L 23.820 118 70-130ND 1,2-Dichloropropane ug/L 24.920 124 70-130ND 1,4-Dichlorobenzene ug/L 24.120 120 70-130ND 2-Butanone (MEK)ug/L 53.7 M14013470-130ND 2-Hexanone ug/L 50.040 125 70-130ND 4-Methyl-2-pentanone (MIBK)ug/L 50.340 126 70-130ND Acetone ug/L 46.840 117 70-130ND Acrylonitrile ug/L 132 M110013270-130ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 65 of 83 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92273406 White Oak LF 10/26 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1596126MATRIX SPIKE SAMPLE: MSSpike Result 92273406015 Benzene ug/L 25.620 128 70-148ND Bromochloromethane ug/L 26.3 M12013270-130ND Bromodichloromethane ug/L 23.220 116 70-130ND Bromoform ug/L 19.520 98 70-130ND Bromomethane ug/L 21.920 110 70-130ND Carbon disulfide ug/L 23.420 117 70-130ND Carbon tetrachloride ug/L 25.320 127 70-130ND Chlorobenzene ug/L 24.420 122 70-146ND Chloroethane ug/L 19.220 96 70-130ND Chloroform ug/L 26.2 M12013170-130ND Chloromethane ug/L 28.0 M12014070-130ND cis-1,2-Dichloroethene ug/L 26.2 M12013170-130ND cis-1,3-Dichloropropene ug/L 23.320 116 70-130ND Dibromochloromethane ug/L 21.320 106 70-130ND Dibromomethane ug/L 23.920 120 70-130ND Ethylbenzene ug/L 25.120 126 70-130ND Iodomethane ug/L 44.240 111 70-130ND m&p-Xylene ug/L 49.840 124 70-130ND Methylene Chloride ug/L 25.220 126 70-130ND o-Xylene ug/L 24.620 123 70-130ND Styrene ug/L 23.720 119 70-130ND Tetrachloroethene ug/L 24.220 121 70-130ND Toluene ug/L 24.720 124 70-155ND trans-1,2-Dichloroethene ug/L 27.6 M12013870-130ND trans-1,3-Dichloropropene ug/L 23.620 118 70-130ND trans-1,4-Dichloro-2-butene ug/L 25.520 127 70-130ND Trichloroethene ug/L 24.020 120 69-151ND Trichlorofluoromethane ug/L 26.4 M12013270-130ND Vinyl acetate ug/L 51.140 128 70-130ND Vinyl chloride ug/L 27.8 M12013970-130ND 1,2-Dichloroethane-d4 (S)%106 70-130 4-Bromofluorobenzene (S)%98 70-130 Toluene-d8 (S)%100 70-130 Parameter Units Dup Result Max RPD QualifiersRPDResult 92273406016 1596127SAMPLE DUPLICATE: 1,1,1,2-Tetrachloroethane ug/L ND 30ND 1,1,1-Trichloroethane ug/L ND 30ND 1,1,2,2-Tetrachloroethane ug/L ND 30ND 1,1,2-Trichloroethane ug/L ND 30ND 1,1-Dichloroethane ug/L ND 30ND 1,1-Dichloroethene ug/L ND 30ND 1,2,3-Trichloropropane ug/L ND 30ND 1,2-Dibromo-3-chloropropane ug/L ND 30ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 66 of 83 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92273406 White Oak LF 10/26 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result Max RPD QualifiersRPDResult 92273406016 1596127SAMPLE DUPLICATE: 1,2-Dibromoethane (EDB)ug/L ND 30ND 1,2-Dichlorobenzene ug/L ND 30ND 1,2-Dichloroethane ug/L ND 30ND 1,2-Dichloropropane ug/L ND 30ND 1,4-Dichlorobenzene ug/L ND 30ND 2-Butanone (MEK)ug/L ND 30ND 2-Hexanone ug/L ND 30ND 4-Methyl-2-pentanone (MIBK)ug/L ND 30ND Acetone ug/L ND 30ND Acrylonitrile ug/L ND 30ND Benzene ug/L ND 30ND Bromochloromethane ug/L ND 30ND Bromodichloromethane ug/L ND 30ND Bromoform ug/L ND 30ND Bromomethane ug/L ND 30ND Carbon disulfide ug/L ND 30ND Carbon tetrachloride ug/L ND 30ND Chlorobenzene ug/L ND 30ND Chloroethane ug/L ND 30ND Chloroform ug/L ND 30ND Chloromethane ug/L ND 30ND cis-1,2-Dichloroethene ug/L ND 30ND cis-1,3-Dichloropropene ug/L ND 30ND Dibromochloromethane ug/L ND 30ND Dibromomethane ug/L ND 30ND Ethylbenzene ug/L ND 30ND Iodomethane ug/L ND 30ND m&p-Xylene ug/L ND 30ND Methylene Chloride ug/L ND 30ND o-Xylene ug/L ND 30ND Styrene ug/L ND 30ND Tetrachloroethene ug/L ND 30ND Toluene ug/L ND 30ND trans-1,2-Dichloroethene ug/L ND 30ND trans-1,3-Dichloropropene ug/L ND 30ND trans-1,4-Dichloro-2-butene ug/L ND 30ND Trichloroethene ug/L ND 30ND Trichlorofluoromethane ug/L ND 30ND Vinyl acetate ug/L ND 30ND Vinyl chloride ug/L ND 30ND Xylene (Total)ug/L ND 30ND 1,2-Dichloroethane-d4 (S)%110 1111 4-Bromofluorobenzene (S)%97 198 Toluene-d8 (S)%101 0101 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 67 of 83 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92273406 White Oak LF 10/26 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/41079 SM 5210B SM 5210B 5210B BOD, 5 day Associated Lab Samples:92273406007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1593055 Associated Lab Samples:92273406007 Matrix:Water AnalyzedMDL BOD, 5 day mg/L ND 2.0 11/02/15 10:402.0 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1593056LABORATORY CONTROL SAMPLE: LCSSpike BOD, 5 day mg/L 232 L019811784.6-115.4 Parameter Units Dup Result Max RPD QualifiersRPDResult 92273406007 1593057SAMPLE DUPLICATE: BOD, 5 day mg/L 73.0 0 1073.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 68 of 83 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92273406 White Oak LF 10/26 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/25222 EPA 300.0 EPA 300.0 300.0 IC Anions Associated Lab Samples:92273406007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1596867 Associated Lab Samples:92273406007 Matrix:Water AnalyzedMDL Sulfate mg/L ND 2.0 11/02/15 18:581.0 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596868LABORATORY CONTROL SAMPLE: LCSSpike Sulfate mg/L 20.120 100 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1596869MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92273860001 1596870 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate mg/L 20 95 90-11097 2 1020ND20.3 20.8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 69 of 83 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92273406 White Oak LF 10/26 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/25144 EPA 353.2 EPA 353.2 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples:92273406007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1593010 Associated Lab Samples:92273406007 Matrix:Water AnalyzedMDL Nitrogen, Nitrate mg/L ND 0.020 10/27/15 20:180.010 Nitrogen, Nitrite mg/L ND 0.020 10/27/15 20:180.010 Nitrogen, NO2 plus NO3 mg/L ND 0.020 10/27/15 20:180.010 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1593011LABORATORY CONTROL SAMPLE: LCSSpike Nitrogen, Nitrate mg/L 2.42.5 98 90-110 Nitrogen, Nitrite mg/L 0.971 97 90-110 Nitrogen, NO2 plus NO3 mg/L 2.42.5 98 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1593012MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92273406007 1593013 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L 2.5 97 90-11098 1 102.5ND 2.4 2.4 Nitrogen, Nitrite mg/L 1 99 90-11099 0 1010.066 1.1 1.1 Nitrogen, NO2 plus NO3 mg/L 2.5 95 90-11096 1 102.50.042 2.4 2.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 70 of 83 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92273406 White Oak LF 10/26 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/25184 EPA 365.1 EPA 365.1 365.1 Phosphorus, Total Associated Lab Samples:92273406007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1595324 Associated Lab Samples:92273406007 Matrix:Water AnalyzedMDL Phosphorus mg/L ND 0.050 11/03/15 03:330.025 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1595325LABORATORY CONTROL SAMPLE: LCSSpike Phosphorus mg/L 2.52.5 100 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1595326MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92272773001 1595327 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Phosphorus mg/L 2.5 100 90-110101 1 102.50.70 3.2 3.2 Parameter Units MS Result % Rec Limits Qual% RecConc. 1595328MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92273203004 1595329 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Phosphorus mg/L M12.5 114 90-110108 2 102.56.4 9.2 9.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 71 of 83 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92273406 White Oak LF 10/26 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/25198 SM 4500-CN-E SM 4500-CN-E 4500CNE Cyanide, Total Associated Lab Samples:92273406007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1595456 Associated Lab Samples:92273406007 Matrix:Water AnalyzedMDL Cyanide mg/L ND 0.0080 10/30/15 16:300.0040 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1595457LABORATORY CONTROL SAMPLE: LCSSpike Cyanide mg/L 0.097.1 97 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1595458MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92273608001 1595459 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Cyanide mg/L .1 86 75-12582 4 10.10.018 0.10 0.10 Parameter Units MS Result % Rec Limits Qual% RecConc. 1595460MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92273762001 1595461 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Cyanide mg/L M1.1 0 75-1250 10.1ND ND ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 72 of 83 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92273406 White Oak LF 10/26 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/25178 SM 5220D SM 5220D 5220D COD Associated Lab Samples:92273406007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1594813 Associated Lab Samples:92273406007 Matrix:Water AnalyzedMDL Chemical Oxygen Demand mg/L ND 25.0 10/29/15 13:4012.5 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1594814LABORATORY CONTROL SAMPLE: LCSSpike Chemical Oxygen Demand mg/L 726750 97 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1594815MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92273906001 1594816 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chemical Oxygen Demand mg/L 750 96 90-11096 0 375096.0 816 816 Parameter Units MS Result % Rec Limits Qual% RecConc. 1594817MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92273906002 1594818 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chemical Oxygen Demand mg/L M17508690-11086 0 3750137782782 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 73 of 83 #=QL# QUALIFIERS Pace Project No.: Project: 92273406 White Oak LF 10/26 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - CharlottePASI-C ANALYTE QUALIFIERS Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high.L1 Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated samples may be biased low.L2 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 74 of 83 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92273406 White Oak LF 10/26 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92273406001 FLD/SW-1 92273406002 FLD/SW-2 92273406003 FLD/SW-3 92273406004 FLD/SW-5 92273406005 FLD/SW-6 92273406006 FLD/SW-7 92273406007 FLD/Leachate 92273406008 FLD/MW-1A 92273406009 FLD/MW-2 92273406010 FLD/MW-2D 92273406011 FLD/MW-3R 92273406012 FLD/MW-3DR 92273406013 FLD/MW-4A 92273406014 FLD/MW-8 92273406015 FLD/MW-11s 92273406016 FLD/MW-11D 92273406017 FLD/MW-14 92273406018 FLD/MW-15 92273406019 FLD/MW-16 92273406020 FLD/MW-17 92273406001 MPRP/19905 ICP/17945SW-1 EPA 3010 EPA 6010 92273406002 MPRP/19905 ICP/17945SW-2 EPA 3010 EPA 6010 92273406003 MPRP/19905 ICP/17945SW-3 EPA 3010 EPA 6010 92273406004 MPRP/19905 ICP/17945SW-5 EPA 3010 EPA 6010 92273406005 MPRP/19918 ICP/17958SW-6 EPA 3010 EPA 6010 92273406006 MPRP/19926 ICP/17968SW-7 EPA 3010 EPA 6010 92273406007 MPRP/19918 ICP/17958LeachateEPA 3010 EPA 6010 92273406008 MPRP/19918 ICP/17958MW-1A EPA 3010 EPA 6010 92273406009 MPRP/19918 ICP/17958MW-2 EPA 3010 EPA 6010 92273406010 MPRP/19918 ICP/17958MW-2D EPA 3010 EPA 6010 92273406011 MPRP/19918 ICP/17958MW-3R EPA 3010 EPA 6010 92273406012 MPRP/19918 ICP/17958MW-3DR EPA 3010 EPA 6010 92273406013 MPRP/19918 ICP/17958MW-4A EPA 3010 EPA 6010 92273406014 MPRP/19918 ICP/17958MW-8 EPA 3010 EPA 6010 92273406015 MPRP/19918 ICP/17958MW-11s EPA 3010 EPA 6010 92273406016 MPRP/19926 ICP/17968MW-11D EPA 3010 EPA 6010 92273406017 MPRP/19926 ICP/17968MW-14 EPA 3010 EPA 6010 92273406018 MPRP/19926 ICP/17968MW-15 EPA 3010 EPA 6010 92273406019 MPRP/19926 ICP/17968MW-16 EPA 3010 EPA 6010 92273406020 MPRP/19926 ICP/17968MW-17 EPA 3010 EPA 6010 92273406022 MPRP/19926 ICP/17968Equip Blk EPA 3010 EPA 6010 92273406001 MSV/34071SW-1 EPA 8260 92273406002 MSV/34071SW-2 EPA 8260 92273406003 MSV/34071SW-3 EPA 8260 92273406004 MSV/34071SW-5 EPA 8260 92273406005 MSV/34071SW-6 EPA 8260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 75 of 83 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92273406 White Oak LF 10/26 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92273406006 MSV/34071SW-7 EPA 8260 92273406007 MSV/34071LeachateEPA 8260 92273406008 MSV/34071MW-1A EPA 8260 92273406009 MSV/34071MW-2 EPA 8260 92273406010 MSV/34071MW-2D EPA 8260 92273406011 MSV/34071MW-3R EPA 8260 92273406012 MSV/34071MW-3DR EPA 8260 92273406013 MSV/34071MW-4A EPA 8260 92273406014 MSV/34071MW-8 EPA 8260 92273406015 MSV/34073MW-11s EPA 8260 92273406016 MSV/34073MW-11D EPA 8260 92273406017 MSV/34073MW-14 EPA 8260 92273406018 MSV/34073MW-15 EPA 8260 92273406019 MSV/34073MW-16 EPA 8260 92273406020 MSV/34073MW-17 EPA 8260 92273406021 MSV/34071TVL BLK EPA 8260 92273406022 MSV/34071Equip Blk EPA 8260 92273406007 WET/41079 WET/41080LeachateSM 5210B SM 5210B 92273406007 WETA/25222LeachateEPA 300.0 92273406007 WETA/25144LeachateEPA 353.2 92273406007 WETA/25184LeachateEPA 365.1 92273406007 WETA/25198LeachateSM 4500-CN-E 92273406007 WETA/25178LeachateSM 5220D REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/16/2015 11:11 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 76 of 83 Page 77 of 83 Page 78 of 83 Page 79 of 83 Page 80 of 83 Page 81 of 83 Page 82 of 83 Page 83 of 83 APPENDIX D STATISTICAL CALCULATIONS White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 COMPOUND TOTAL ND DETECTED %ND STATISTICAL TEST Total Antimony 341 334 7 97.9%Poisson Prediction Limits Total Arsenic 341 314 27 92.1%Poisson Prediction Limits Total Barium 344 16 328 4.7%Prediction Limits Total Beryllium 342 298 44 87.1%Kruskal-Wallis Total Cadmium 342 298 44 87.1%Kruskal-Wallis Total Chromium 342 199 143 58.2%Kruskal-Wallis Total Cobalt 342 224 118 65.5%Kruskal-Wallis Total Copper 342 217 125 63.5%Kruskal-Wallis Total Lead 343 265 78 77.3%Kruskal-Wallis Total Nickel 343 159 184 46.4%Kruskal-Wallis Total Selenium 342 338 4 98.8%Poisson Prediction Limits Total Silver 342 339 3 99.1%Poisson Prediction Limits Total Thallium 342 323 19 94.4%Poisson Prediction Limits Total Vanadium 342 203 139 59.4%Kruskal-Wallis Total Zinc 342 125 217 36.5%Kruskal-Wallis Acetone 291 290 1 99.7%Poisson Prediction Limits Carbon Disulfide 291 288 3 99.0%Poisson Prediction Limits Chloroethane 291 290 1 99.7%Poisson Prediction Limits Iodomethane 291 290 1 99.7%Poisson Prediction Limits Dichloromethane 291 288 3 99.0%Poisson Prediction Limits 2-Butanone 239 238 1 99.6%Poisson Prediction Limits Sampling Event # Detected LEGEND FOR THE FOLLOWING PAGES: N 1 64 ND = Not Detected at the method detection limit N 2 13 MCL = Maximum Contaminant Level ; NCAC 2L Standard N 3 14 NE = Not Established ; NC has not established a MCL N 4 3 NP = Not Present during sampling event N 5 64 NS = Not Sampled N 6 0 NT = Not Tested N 7 0 NA = information Not Available N 8 0 MDL = Method Detection Limit N 9 0 N 10 53 N 11 88 N 12 59 N 13 55 N 14 74 N 15 49 N 16 61 N 17 60 N 18 28 Methods 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 1 of 2 N 19 38 N 20 43 N 21 57 N 22 52 N 23 58 N 24 55 N 25 37 N 26 27 N 27 46 N 28 41 N 29 54 N 30 43 N 31 45 N 32 40 N 33 35 N 34 34 N 35 19 N 36 41 N 37 40 Total Detected Concentrations (per compound) = 1490 Total Detected Concentrations (per event) = 1490 Are all accounted for ?Yes Statistical Package Prepared By: IAI Statistical Package Checked By: MSP Methods 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 2 of 2 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Antimony MCL (mg/l):Not Established Method:Poisson Prediction Limits Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 ND NS NS ND ND ND ND ND ND ND NS NP NP 10 06/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 10 07/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 10 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 30 04/09/01 ND ND NS ND ND ND ND ND ND ND NS NP NP 10 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 30 04/15/02 15 ND NS ND ND ND NT ND ND 11 NS NP NP 10 09/26/02 ND ND ND 12 ND ND ND ND ND ND 98 NP NP 10 04/28/03 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/30/03 ND ND NT ND ND ND ND ND ND ND ND NP NP 5 04/20/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 10/21/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/18/05 ND ND ND ND ND ND ND ND ND ND 12 NP NP 5 10/13/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/25/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 30 10/20/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/25/07 ND ND ND ND ND 20 ND ND ND ND ND NP NP 6 10/31/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/23/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 10/20/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/22/09 ND ND ND ND ND ND ND ND ND ND NS NP NP 5 10/26/09 ND ND ND ND ND ND NS NS NS ND ND NP NP 5 04/22/10 ND ND ND ND ND ND NS NS ND ND ND NP NP 5 10/27/10 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/29/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/25/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/20/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/24/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/24/14 ND ND ND ND ND ND ND ND ND ND ND 6.1 ND 5 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/28/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/27/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 31. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 86 Tn1 = 301.5 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =86 Tn1 = 301.5 t [85,.01] =2.3767 c =0.0116 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Tn2 = 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 T*k =8.0 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Antimony (PPL) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 1 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Arsenic MCL (mg/l):10 Method:Poisson Prediction Limits Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 ND NS NS ND ND ND ND ND ND ND NS NP NP 10 06/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 10 07/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 10 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 10 04/09/01 ND ND NS ND ND ND ND ND ND ND NS NP NP 10 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 04/15/02 ND ND NS ND ND ND NT ND ND ND NS NP NP 10 09/26/02 ND 5.7 ND ND ND ND ND ND 27 ND 68 NP NP 5 04/28/03 ND ND ND ND ND ND ND ND ND ND 24 NP NP 5 10/30/03 ND ND NT ND ND ND ND ND ND 5.3 81 NP NP 5 04/20/04 ND ND ND ND ND ND ND ND ND 7.4 30 NP NP 5 10/21/04 ND ND ND ND ND ND ND ND ND ND 59 NP NP 5 04/18/05 ND ND ND 10 ND ND ND ND ND 5.2 65 NP NP 5 10/13/05 ND ND ND ND ND ND ND ND ND ND 44 NP NP 5 04/25/06 ND ND ND ND ND ND ND ND ND ND 42 NP NP 10 10/20/06 ND ND ND ND ND ND ND ND ND ND 13 NP NP 5 04/25/07 ND ND ND ND ND 280 ND ND ND ND 12 NP NP 5 10/31/07 ND ND ND ND ND ND ND ND ND ND 21.4 NP NP 5 04/23/08 ND ND ND ND ND ND ND ND ND ND 10.2 NP NP 5 10/20/08 ND ND ND ND ND ND ND ND ND ND 6.6 NP NP 5 04/22/09 ND ND 5.4 ND ND 5.6 ND ND ND ND NS NP NP 5 10/26/09 ND ND ND ND 6 ND NS NS NS ND ND NP NP 5 04/22/10 ND ND ND ND 7.4 9.8 NS NS ND ND ND NP NP 5 10/27/10 ND ND ND ND 5.4 5.9 ND ND ND ND ND ND ND 5 04/29/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/25/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/20/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/24/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 04/24/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 04/28/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 10/27/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 31. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 86 Tn1 = 288.6 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =86 Tn1 = 288.6 t [85,.01] =2.3767 c =0.0116 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Tn2 = 5 5 5 5 5 5 5 5 5 5 T*k =7.8 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Arsenic (PPL) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 2 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Barium NC MCL (mg/l):700 Method:Prediction Limits BACKGROUND WELLS DETECTION WELLS MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 4/24/00 250 NS NS 240 420 200 63 300 93 230 NS NP NP 5 6/26/00 300 67 NS NS NS NS NS NS NS NS NS NP NP 5 7/26/00 330 30 NS NS NS NS NS NS NS NS NS NP NP 5 9/18/00 NS NS NS 330 92 NS NS NS NT NS NS NP NP 500 4/9/01 1300 380 NS 180 330 120 80 290 360 970 NS NP NP 5 9/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 1/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 2/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 500 4/15/02 1300 41 NS ND ND 160 23 190 460 1400 NS NP NP 5 9/26/02 330 500 750 4200 120 230 93 410 910 1400 11000 NP NP 5 4/28/03 600 66 220 1800 160 140 110 92 360 800 2800 NP NP 5 10/30/03 320 100 NT 210 310 130 95 110 1200 270 4900 NP NP 5 4/20/04 320 56 120 410 460 170 140 210 62 940 2000 NP NP 5 10/21/04 320 40 200 300 310 140 140 130 12 900 4900 NP NP 5 4/18/05 480 55 160 7200 610 180 160 140 12 1000 3700 NP NP 5 10/13/05 770 37 160 1700 870 250 160 140 27 810 2700 NP NP 5 4/25/06 650 ND ND ND 1100 ND ND ND ND 750 2700 NP NP 500 10/20/06 410 22 180 470 1100 ND ND ND 160 ND 650 NP NP 5 4/25/07 290 ND 200 240 1300 1500 130 180 ND ND 600 NP NP 100 10/31/07 501 31.5 223 198 1350 591 184 208 62.4 516 872 NP NP 5 4/23/08 194 30.8 253 168 1230 661 216 202 61.8 151 361 NP NP 5 10/20/08 474 66 313 224 1210 894 164 216 41.1 182 245 NP NP 5 4/22/09 126 47.2 591 309 1300 817 230 216 77 163 NS NP NP 5 10/26/09 131 16.8 144 188 1720 987 NS NS NS 209 178 NP NP 5 4/22/10 208 43.5 153 157 1920 1380 NS NS 20.9 150 74.8 NP NP 5 10/27/10 147 15.8 162 178 1760 1550 531 234 20 190 111 191 84.4 5 4/29/11 191 16.3 188 182 1620 1390 428 173 13.6 196 125 201 133 5 10/25/11 185 19.7 120 332 1200 1300 945 205 8.2 238 123 161 154 5 4/20/12 304 17.5 129 153 1020 1140 442 215 9.5 232 64.8 249 169 5 10/24/12 389 19 124 167 889 1030 393 229 26.1 235 43.2 177 181 5 4/24/13 241 16.8 100 164 842 964 344 226 9.3 218 96.5 116 190 5 10/24/13 255 18.1 156 166 839 1160 510 256 9.1 250 55.2 171 218 5 4/24/14 174 17.7 127 148 941 1290 378 248 8.3 238 27.5 148 189 5 10/27/14 117 16.1 102 136 1280 1410 363 224 8.6 228 23.2 156 180 5 4/28/15 119 16 109 199 1330 1380 345 260 9 218 30.2 156 190 5 10/27/15 346 16 95.7 164 1190 1400 352 247 13.8 279 18.8 188 191 5 1) Use the data above as-is for testing: 2) Calculate the Upper Prediction limit (T): T = xbar + t[n-1, 1-a*/k]s [1+1/n)]-0.5 where: n =86 Number of background concentrations n0 =3 Number of ND background concentrations n1 =83 Number of detected background concentrations n0/n =0.0349 Ratio of ND to all background values xbar =215.27 Average background concentration x'bar =223.05 Average detected background concentration a* =0.05 Sitewide error rate k =10 Number of Comparisons during the Current Sampling Event s' =244.63 Standard deviation of detected background concentrations s =240.24 Standard deviation of background concentrations a*/k =0.005 t [85, 0.005] =2.6421 Upper percentage point of Student's t-distribution (Table 6 of the IFG) Tn = 1400 Maximum concentration detected during current sampling event T =853.7 Upper Prediction Limit 1957-50 White Oak GW Stats 2nd 2015.xlsm Barium (PL)Page 3 of 66 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Current Concentration = 164 1190 1400 352 247 13.8 279 18.8 188 191 Statistical Significance ?No Yes Yes No No No No No No No If SSI, is current event above MCL?-Yes Yes ------- 2) Compare the Upper Prediction Limit (T) to the Maximum Concentration Detected (Tn) in the wells during the most recent sampling event. Since the Prediction Limit was exceeded, there is evidence that the detected concentrations during the current sampling event that the detected concentrations are statistically significant. 1957-50 White Oak GW Stats 2nd 2015.xlsm Barium (PL)Page 4 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Barium NC MCL (mg/l):700 Method:Shewhart-CUSUM Control Chart Part 1: Check for Normality MW - 2 MD L 9/26/02 120 5 4/28/03 160 5 10/30/03 310 5 4/20/04 460 5 10/21/04 310 5 4/18/05 610 5 10/13/05 870 5 4/25/06 1100 500 10/20/06 1100 5 4/25/07 1300 100 10/31/07 1350 5 4/23/08 1230 5 10/20/08 1210 5 4/22/09 1300 5 10/26/09 1720 5 4/22/10 1920 5 10/27/10 1760 5 4/29/11 1620 5 10/25/11 1200 5 4/20/12 1020 5 10/24/12 889 5 4/24/13 842 5 10/24/13 839 5 4/24/14 941 5 10/27/14 1280 5 4/28/15 1330 5 10/27/15 1190 5 If not detected (ND), use half of the detection limit. Xbar =1036.3333 SD =477.73279 N =27 1/NSi(Xi-Xbar)3 =-29098538 g1=0.282424 Since the Coefficient of Skewness of 0.28 is less than 1.0, the data appear not to be significantly skewed. Proceed with further statistical tests using the real detected values shown above. Xbar =6.7719148 SD =0.7029294 N =27 1/NSi(Xi-Xbar)3 =-0.494068 g1=1.505349 Use the real values (not log-transformed) indicated in the previous section. Ba (S-C MW-2) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 5 of 66 Part 2: Shewhart-CUSUM Control Chart Compute the mean and standard deviation of the historical data: 492.5 = xmean (Mean of N1-N8 historical data) 346.89438 = s (Standard Deviation of N1-N8 historical data) 1 = k (constant, reference value) 5 = h (constant, upper control limit for the CUSUM scheme) 4.5 = SCL (Constant, upper Shewhart Control Limit) Compute the standardized mean (Zi) and the cumulative sum (Si) for each concentration. Date xi Zi Si h SCL 0 10/20/06 1100 1.7512535 0.7512535 5 4.5 4/25/07 1300 2.3277978 2.0790513 5 4.5 10/31/07 1350 2.4719339 3.5509853 5 4.5 4/23/08 1230 2.1260073 4.6769926 5 4.5 10/20/08 1210 2.0683529 5.7453454 5 4.5 4/22/09 1300 2.3277978 7.0731433 5 4.5 10/26/09 1720 3.538541 9.6116843 5 4.5 4/22/10 1920 4.1150853 12.72677 5 4.5 10/27/10 1760 3.6538499 15.380619 5 4.5 4/29/11 1620 3.2502688 17.630888 5 4.5 10/25/11 1200 2.0395257 18.670414 5 4.5 4/20/12 1020 1.5206357 19.19105 5 4.5 10/24/12 889 1.1429992 19.334049 5 4.5 4/24/13 842 1.0075113 19.34156 5 4.5 10/24/13 839 0.9988631 19.340423 5 4.5 4/24/14 941 1.2929007 19.633324 5 4.5 10/27/14 1280 2.2701434 20.903467 5 4.5 4/28/15 1330 2.4142795 22.317747 5 4.5 10/27/15 1190 2.0106984 23.328445 5 4.5 Plot Zi and Si versus time: Compare the Zi and Si values to their respective control limits of SCL and h. One, or both, of the control limits was exceeded. Therefore, there is statistically significant evidence of contamination in this well at the concentrations indicated above. 0 5 10 15 20 25 5/ 2 8 / 0 5 10 / 1 0 / 0 6 2/ 2 2 / 0 8 7/ 6 / 0 9 11 / 1 8 / 1 0 4/ 1 / 1 2 8/ 1 4 / 1 3 12 / 2 7 / 1 4 5/ 1 0 / 1 6 St a n d a r d i z e d U n i t s Combined Shewart-CUSUM Control Chart Zi SCL Si h Ba (S-C MW-2) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 6 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Barium NC MCL (mg/l):700 Method:Shewhart-CUSUM Control Chart Part 1: Check for Normality MW - 2 D MD L 9/26/02 230 5 4/28/03 140 5 10/30/03 130 5 4/20/04 170 5 10/21/04 140 5 4/18/05 180 5 10/13/05 250 5 4/25/06 ND 500 10/20/06 ND 5 4/25/07 1500 100 10/31/07 591 5 4/23/08 661 5 10/20/08 894 5 4/22/09 817 5 10/26/09 987 5 4/22/10 1380 5 10/27/10 1550 5 4/29/11 1390 5 10/25/11 1300 5 4/20/12 1140 5 10/24/12 1030 5 4/24/13 964 5 10/24/13 1160 5 4/24/14 1290 5 10/27/14 1410 5 4/28/15 1380 5 10/27/15 1400 5 If not detected (ND), use half of the detection limit. Xbar =827.27778 SD =532.58832 N =27 1/NSi(Xi-Xbar)3 =-31449764 g1=0.2203069 Since the Coefficient of Skewness of 0.22 is less than 1.0, the data appear not to be significantly skewed. Proceed with further statistical tests using the real detected values shown above. Xbar =6.2531804 SD =1.3851822 N =27 1/NSi(Xi-Xbar)3 =-5.6369777 g1=2.2444566 Use the real values (not log-transformed) indicated in the previous section. Ba (S-C MW-2D) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 7 of 66 Part 2: Shewhart-CUSUM Control Chart Compute the mean and standard deviation of the historical data: 186.25 = xmean (Mean of N1-N8 historical data) 50.409041 = s (Standard Deviation of N1-N8 historical data) 1 = k (constant, reference value) 5 = h (constant, upper control limit for the CUSUM scheme) 4.5 = SCL (Constant, upper Shewhart Control Limit) Compute the standardized mean (Zi) and the cumulative sum (Si) for each concentration. Date xi Zi Si h SCL 0 10/20/06 2.5 -3.6451794 0 5 4.5 4/25/07 1500 26.061793 25.061793 5 4.5 10/31/07 591 8.0293136 32.091107 5 4.5 4/23/08 661 9.4179534 40.50906 5 4.5 10/20/08 894 14.04014 53.5492 5 4.5 4/22/09 817 12.512636 65.061837 5 4.5 10/26/09 987 15.885047 79.946884 5 4.5 4/22/10 1380 23.681268 102.62815 5 4.5 10/27/10 1550 27.053679 128.68183 5 4.5 4/29/11 1390 23.879645 151.56148 5 4.5 10/25/11 1300 22.094251 172.65573 5 4.5 4/20/12 1140 18.920217 190.57594 5 4.5 10/24/12 1030 16.738069 206.31401 5 4.5 4/24/13 964 15.42878 220.74279 5 4.5 10/24/13 1160 19.316971 239.05976 5 4.5 4/24/14 1290 21.895874 259.95564 5 4.5 10/27/14 1410 24.276399 283.23204 5 4.5 4/28/15 1380 23.681268 305.9133 5 4.5 10/27/15 1400 24.078022 328.99133 5 4.5 Plot Zi and Si versus time: Compare the Zi and Si values to their respective control limits of SCL and h. One, or both, of the control limits was exceeded. Therefore, there is statistically significant evidence of contamination in this well at the concentrations indicated above. -50 0 50 100 150 200 250 300 350 5/ 2 8 / 0 5 10 / 1 0 / 0 6 2/ 2 2 / 0 8 7/ 6 / 0 9 11 / 1 8 / 1 0 4/ 1 / 1 2 8/ 1 4 / 1 3 12 / 2 7 / 1 4 5/ 1 0 / 1 6 St a n d a r d i z e d U n i t s Combined Shewart-CUSUM Control Chart Zi SCL Si h Ba (S-C MW-2D) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 8 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Beryllium NC MCL (mg/l):Not Established Method:Kruskal-Wallis Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 4.4 NS NS ND 2 ND 2.2 ND ND ND NS NP NP 2 06/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 2 07/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 2 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 2 04/09/01 2.3 7 NS ND ND ND ND ND 2.4 4.8 NS NP NP 2 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 2 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 2 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 2 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 2 04/15/02 2.1 ND NS ND ND ND ND ND 2.5 5 NS NP NP 2 09/26/02 ND 7 2.1 5.1 ND ND ND ND 8.5 4.7 95 NP NP 2 04/28/03 ND ND ND ND ND ND ND ND 2 2.2 20 NP NP 2 10/30/03 ND ND NT ND ND ND ND ND 2.4 ND 33 NP NP 1 04/20/04 ND ND ND ND ND ND ND ND ND ND 21 NP NP 1 10/21/04 ND ND ND ND ND ND ND ND ND 1.4 28 NP NP 1 04/18/05 ND ND ND 7.2 ND ND ND ND ND 3.8 26 NP NP 1 10/13/05 ND ND ND 3 ND ND ND ND ND 3.4 21 NP NP 1 04/25/06 ND ND ND ND ND ND ND ND 2.1 ND 17 NP NP 2 10/20/06 ND ND ND ND ND ND ND ND ND ND 5.7 NP NP 1 04/25/07 ND ND ND ND ND 14 ND ND ND ND 4.9 NP NP 1 10/31/07 ND ND ND ND ND ND ND ND ND ND 6 NP NP 1 04/23/08 ND ND ND ND ND ND ND ND ND ND 3 NP NP 1 10/20/08 ND 1.2 ND ND ND ND ND ND ND ND 1.9 NP NP 1 04/22/09 ND ND 1.5 ND ND ND ND ND ND ND NS NP NP 1 10/26/09 ND ND ND ND ND ND NS NS NS ND 1.7 NP NP 1 04/22/10 ND ND ND ND ND ND NS NS ND ND ND NP NP 1 10/27/10 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/29/11 ND ND ND ND ND ND ND ND ND ND 1.1 ND ND 1 10/25/11 ND ND ND ND ND ND ND ND ND ND 1.6 ND ND 1 04/20/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 10/24/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/24/13 ND ND ND ND ND ND ND ND ND ND 1.2 ND ND 1 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/24/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/28/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 10/27/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 Ni 32 31 26 30 30 30 28 28 29 30 26 11 11 sum of rank values (Ri)5281.5 5147.5 4201.0 5014.0 4643.0 4669.5 4349.0 4186.0 5337.0 5666.0 6869.5 1644.5 1644.5 avg rank value (Rbar)165.0 166.0 161.6 167.1 154.8 155.7 155.3 149.5 184.0 188.9 264.2 149.5 149.5 Number of each rank value Rank Value rank value of NDs =29 28 24 27 29 29 27 28 23 23 9 11 11 149.5 rank value of 1.1s =0 0 0 0 0 0 0 0 0 0 1 0 0 299 rank value of 1.2s =0 1 0 0 0 0 0 0 0 0 1 0 0 300.5 Beryllium (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 9 of 66 rank value of 1.4s =0 0 0 0 0 0 0 0 0 1 0 0 0 302 rank value of 1.5s =0 0 1 0 0 0 0 0 0 0 0 0 0 303 rank value of 1.6s =0 0 0 0 0 0 0 0 0 0 1 0 0 304 rank value of 1.7s =0 0 0 0 0 0 0 0 0 0 1 0 0 305 rank value of 1.9s =0 0 0 0 0 0 0 0 0 0 1 0 0 306 rank value of 2s =0 0 0 0 1 0 0 0 1 0 0 0 0 307.5 rank value of 2.1s =1 0 1 0 0 0 0 0 1 0 0 0 0 310 rank value of 2.2s =0 0 0 0 0 0 1 0 0 1 0 0 0 312.5 rank value of 2.3s =1 0 0 0 0 0 0 0 0 0 0 0 0 314 rank value of 2.4s =0 0 0 0 0 0 0 0 2 0 0 0 0 315.5 rank value of 2.5s =0 0 0 0 0 0 0 0 1 0 0 0 0 317 rank value of 3s =0 0 0 1 0 0 0 0 0 0 1 0 0 318.5 rank value of 3.4s =0 0 0 0 0 0 0 0 0 1 0 0 0 320 rank value of 3.8s =0 0 0 0 0 0 0 0 0 1 0 0 0 321 rank value of 4.4s =1 0 0 0 0 0 0 0 0 0 0 0 0 322 rank value of 4.5s =0 0 0 0 0 0 0 0 0 1 0 0 0 323 rank value of 4.7s =0 0 0 0 0 0 0 0 0 1 0 0 0 324 rank value of 4.8s =0 0 0 0 0 0 0 0 0 1 0 0 0 325 rank value of 4.9s =0 0 0 0 0 0 0 0 0 0 1 0 0 326 rank value of 5.1s =0 0 0 1 0 0 0 0 0 0 0 0 0 327 rank value of 5.7s =0 0 0 0 0 0 0 0 0 0 1 0 0 328 rank value of 6s =0 0 0 0 0 0 0 0 0 0 1 0 0 329 rank value of 7s =0 2 0 0 0 0 0 0 0 0 0 0 0 330.5 rank value of 7.2s =0 0 0 1 0 0 0 0 0 0 0 0 0 332 rank value of 8.5s =0 0 0 0 0 0 0 0 1 0 0 0 0 333 rank value of 14s =0 0 0 0 0 1 0 0 0 0 0 0 0 334 rank value of 17s =0 0 0 0 0 0 0 0 0 0 1 0 0 335 rank value of 20s =0 0 0 0 0 0 0 0 0 0 1 0 0 336 rank value of 21s =0 0 0 0 0 0 0 0 0 0 2 0 0 337.5 rank value of 26s =0 0 0 0 0 0 0 0 0 0 1 0 0 339 rank value of 28s =0 0 0 0 0 0 0 0 0 0 1 0 0 340 rank value of 33s =0 0 0 0 0 0 0 0 0 0 1 0 0 341 rank value of 95s =0 0 0 0 0 0 0 0 0 0 1 0 0 342 n =32 31 26 30 30 30 28 28 29 30 26 11 11 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SK i=1 (Ri 2)/Ni]} -3(N+1) Well = Background MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Ri2/Ni = 2404909.0 838007 718582 726808 675493 625807 982192 1E+06 2E+06 245853 245853 Ni bg = 89 N = 342 Beryllium (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 10 of 66 H = 29.63 Adjust H for ties: Ti =3E+07 sum of T1..T9 H' = H/(1-(Ti/(N3-N))) H' =87.54 Chi-square =18.31 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 17df at the 5% significance level from Table 1 of the IFG. The value is 18.31 which is less than H' =87.54. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Rbar (well x) = 167.1 154.8 155.7 155.3 149.5 184.0 188.9 264.2 149.5 149.5 avg Rbar (background) = 164.4 164.4 164.4 164.4 164.4 164.4 164.4 164.4 164.4 164.4 Dx = 2.8 -9.6 -8.7 -9.1 -14.9 19.7 24.5 99.8 -14.9 -14.9 Cx = 48.6 48.6 48.6 49.9 49.9 49.3 48.6 51.4 73.6 73.6 Statistical Significance ? No No No No No No No Yes No No If SSI, is current event above MCL?-------NE -- Compare each difference (Dx) with the corresponding critical value (Cx). The Dx value for the above indicated wells do exceed the corresponding Cx value. Therefore, we conclude that the concentration of Total Beryllium averaged over these compliance wells are significantly greater than that of the background wells. Shewart-CUSUM Control Charts should be performed for each failing well to check for statistical significance. Beryllium (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 11 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Beryllium NC MCL (mg/l):Not Established Method:Shewhart-CUSUM Control Chart Part 1: Check for Normality MW - 1 5 MD L 9/26/02 95 2 4/28/03 20 2 10/30/03 33 1 4/20/04 21 1 10/21/04 28 1 4/18/05 26 1 10/13/05 21 1 4/25/06 17 2 10/20/06 5.7 1 4/25/07 4.9 1 10/31/07 6 1 4/23/08 3 1 10/20/08 1.9 1 4/22/09 NS 1 10/26/09 1.7 1 4/22/10 ND 1 10/27/10 ND 1 4/29/11 1.1 1 10/25/11 1.6 1 4/20/12 ND 1 10/24/12 ND 1 4/24/13 1.2 1 10/24/13 ND 1 4/24/14 ND 1 10/27/14 ND 1 4/28/15 ND 1 10/27/15 ND 1 If not detected (ND), use half of the detection limit. Xbar =11.253846 SD =19.967558 N =26 1/NSi(Xi-Xbar)3 =22740.861 g1=3.0295773 Since the Coefficient of Skewness of 3.03 is greater than 1.0, the real data appear to be significantly skewed. Do not assume that the data follow a Normal distribution. Perform the Skewness Test on the natural log of the values. Xbar =1.0946362 SD =1.724193 N =26 1/NSi(Xi-Xbar)3 =1.9447077 g1=0.4023896 Since the Coefficient of Skewness of 0.40 is less than 1.0, the data appear not to be significantly skewed. Be (S-C MW-15) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 12 of 66 Proceed with further statistical tests using the log-transformed values shown above. Part 2: Shewhart-CUSUM Control Chart Compute the mean and standard deviation of the historical data: 3.3198345 = xmean (Mean of N1-N8 historical data) 0.5413573 = s (Standard Deviation of N1-N8 historical data) 1 = k (constant, reference value) 5 = h (constant, upper control limit for the CUSUM scheme) 4.5 = SCL (Constant, upper Shewhart Control Limit) Compute the standardized mean (Zi) and the cumulative sum (Si) for each concentration. Date xi Zi Si h SCL 0 10/20/06 1.7404662 -2.9174229 0 5 4.5 4/25/07 1.5892352 -3.1967781 0 5 4.5 10/31/07 1.7917595 -2.8226735 0 5 4.5 4/23/08 1.0986123 -4.103061 0 5 4.5 10/20/08 0.6418539 -4.9467891 0 5 4.5 10/26/09 0.5306283 -5.152246 0 5 4.5 4/22/10 -0.693147 -7.4128146 0 5 4.5 10/27/10 -0.693147 -7.4128146 0 5 4.5 4/29/11 0.0953102 -5.9563693 0 5 4.5 10/25/11 0.4700036 -5.2642324 0 5 4.5 4/20/12 -0.693147 -7.4128146 0 5 4.5 10/24/12 -0.693147 -7.4128146 0 5 4.5 4/24/13 0.1823216 -5.7956412 0 5 4.5 10/24/13 -0.693147 -7.4128146 0 5 4.5 4/24/14 -0.693147 -7.4128146 0 5 4.5 10/27/14 -0.693147 -7.4128146 0 5 4.5 4/28/15 -0.693147 -7.4128146 0 5 4.5 10/27/15 -0.693147 -7.4128146 0 5 4.5 Plot Zi and Si versus time: Compare the Zi and Si values to their respective control limits of SCL and h. The limits were not exceeded and do not indicate statistically significant evidence of contamination at the site. -10 -8 -6 -4 -2 0 2 4 6 5/ 2 8 / 0 5 10 / 1 0 / 0 6 2/ 2 2 / 0 8 7/ 6 / 0 9 11 / 1 8 / 1 0 4/ 1 / 1 2 8/ 1 4 / 1 3 12 / 2 7 / 1 4 5/ 1 0 / 1 6 St a n d a r d i z e d U n i t s Combined Shewart-CUSUM Control Chart Zi SCL Si h Be (S-C MW-15) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 13 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Cadmium NC MCL (mg/l):2 Method:Kruskal-Wallis Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 2 NS NS ND 1.3 1.2 1.3 2.1 ND 5.4 NS NP NP 1 06/26/00 1.6 ND NS NS NS NS NS NS NS NS NS NP NP 1 07/26/00 1.1 3.2 NS NS NS NS NS NS NS NS NS NP NP 1 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 1 04/09/01 130 2 NS ND ND ND 1.7 1.8 2.7 19 NS NP NP 1 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 1 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 1 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 1 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 1 04/15/02 13 ND NS ND ND ND 4 ND 5.5 19 NS NP NP 10 09/26/02 ND ND 4.2 21 ND 10 ND 2.3 4.2 19 180 NP NP 1 04/28/03 3.6 ND ND 6 ND ND ND ND 2.9 16 20 NP NP 1 10/30/03 ND ND NT ND ND ND ND ND ND ND ND NP NP 1 04/20/04 ND ND ND ND ND ND ND ND ND 8.8 8.9 NP NP 1 10/21/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 1 04/18/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 1 10/13/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 1 04/25/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 1 10/20/06 3.8 ND ND ND ND ND ND ND 1.5 ND 5.2 NP NP 1 04/25/07 ND ND ND ND ND 2.2 ND ND ND ND ND NP NP 1 10/31/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 1 04/23/08 ND ND ND ND ND ND ND ND ND ND 1.6 NP NP 1 10/20/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 1 04/22/09 ND ND ND ND ND ND ND ND ND ND NS NP NP 1 10/26/09 ND ND ND ND ND ND NS NS NS ND ND NP NP 1 04/22/10 ND ND ND ND ND ND NS NS ND ND ND NP NP 1 10/27/10 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/29/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 10/25/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/20/12 ND ND ND ND ND ND ND ND ND ND ND 4.8 ND 1 10/24/12 ND ND ND ND ND ND ND ND ND ND ND 1 ND 1 04/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/24/14 ND ND ND ND ND ND ND ND ND ND ND 1.2 ND 1 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/28/15 ND ND ND ND ND ND ND ND ND ND ND 2.3 ND 1 10/27/15 1.9 ND ND ND ND ND ND ND ND ND ND 3.1 ND 1 Ni 32 31 26 30 30 30 28 28 29 30 26 11 11 sum of rank values (Ri)6134.0 4967.0 4062.0 4856.0 4639.0 4985.0 4672.0 4675.0 5181.5 5593.0 4786.0 2458.0 1644.5 avg rank value (Rbar)191.7 160.2 156.2 161.9 154.6 166.2 166.9 167.0 178.7 186.4 184.1 223.5 149.5 Number of each rank value Rank Value rank value of NDs =24 29 25 28 29 27 25 25 24 24 21 6 11 149.5 rank value of 1s =0 0 0 0 0 0 0 0 0 0 0 1 0 299 rank value of 1.1s =1 0 0 0 0 0 0 0 0 0 0 0 0 300 Cadmium (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 14 of 66 rank value of 1.2s =0 0 0 0 0 1 0 0 0 0 0 1 0 301.5 rank value of 1.3s =0 0 0 0 1 0 1 0 0 0 0 0 0 303.5 rank value of 1.5s =0 0 0 0 0 0 0 0 1 0 0 0 0 305 rank value of 1.6s =1 0 0 0 0 0 0 0 0 0 1 0 0 306.5 rank value of 1.7s =0 0 0 0 0 0 1 0 0 0 0 0 0 308 rank value of 1.8s =0 0 0 0 0 0 0 1 0 0 0 0 0 309 rank value of 1.9s =1 0 0 0 0 0 0 0 0 0 0 0 0 310 rank value of 2s =1 1 0 0 0 0 0 0 0 0 0 0 0 311.5 rank value of 2.1s =0 0 0 0 0 0 0 1 0 0 0 0 0 313 rank value of 2.2s =0 0 0 0 0 1 0 0 0 0 0 0 0 314 rank value of 2.3s =0 0 0 0 0 0 0 1 0 0 0 1 0 315.5 rank value of 2.7s =0 0 0 0 0 0 0 0 1 0 0 0 0 317 rank value of 2.9s =0 0 0 0 0 0 0 0 1 0 0 0 0 318 rank value of 3.1s =0 0 0 0 0 0 0 0 0 0 0 1 0 319 rank value of 3.2s =0 1 0 0 0 0 0 0 0 0 0 0 0 320 rank value of 3.6s =1 0 0 0 0 0 0 0 0 0 0 0 0 321 rank value of 3.8s =1 0 0 0 0 0 0 0 0 0 0 0 0 322 rank value of 4s =0 0 0 0 0 0 1 0 0 0 0 0 0 323 rank value of 4.2s =0 0 1 0 0 0 0 0 1 0 0 0 0 324.5 rank value of 4.8s =0 0 0 0 0 0 0 0 0 0 0 1 0 326 rank value of 5.2s =0 0 0 0 0 0 0 0 0 0 1 0 0 327 rank value of 5.4s =0 0 0 0 0 0 0 0 0 1 0 0 0 328 rank value of 5.5s =0 0 0 0 0 0 0 0 1 0 0 0 0 329 rank value of 6s =0 0 0 1 0 0 0 0 0 0 0 0 0 330 rank value of 8.8s =0 0 0 0 0 0 0 0 0 1 0 0 0 331 rank value of 8.9s =0 0 0 0 0 0 0 0 0 0 1 0 0 332 rank value of 10s =0 0 0 0 0 1 0 0 0 0 0 0 0 333 rank value of 13s =1 0 0 0 0 0 0 0 0 0 0 0 0 334 rank value of 16s =0 0 0 0 0 0 0 0 0 1 0 0 0 335 rank value of 19s =0 0 0 0 0 0 0 0 0 3 0 0 0 337 rank value of 20s =0 0 0 0 0 0 0 0 0 0 1 0 0 339 rank value of 21s =0 0 0 1 0 0 0 0 0 0 0 0 0 340 rank value of 130s =1 0 0 0 0 0 0 0 0 0 0 0 0 341 rank value of 180s =0 0 0 0 0 0 0 0 0 0 1 0 0 342 n =32 31 26 30 30 30 28 28 29 30 26 11 11 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SKi=1 (Ri2)/Ni]} -3(N+1) Well = Background MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Ri2/Ni = 2583332.2 786025 717344 828341 779557 780558 925791 1E+06 880992 549251 245853 Ni bg = 89 N = 342 H = 6.22 Cadmium (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 15 of 66 Adjust H for ties: Ti =3E+07 sum of T1..T8 H' = H/(1-(Ti/(N3-N))) H' =18.37 Chi-square =18.31 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 17df at the 5% significance level from Table 1 of the IFG. The value is 18.31 which is less than H' =18.37. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Rbar (well x) = 161.9 154.6 166.2 166.9 167.0 178.7 186.4 184.1 223.5 149.5 avg Rbar (background) = 170.4 170.4 170.4 170.4 170.4 170.4 170.4 170.4 170.4 170.4 Dx = -8.5 -15.7 -4.2 -3.5 -3.4 8.3 16.1 13.7 53.1 -20.9 Cx = 48.6 48.6 48.6 49.9 49.9 49.3 48.6 51.4 73.6 73.6 Statistical Significance ? No No No No No No No No No No If SSI, is current event above MCL?---------- Compare each difference (Dx) with the corresponding critical value (Cx). No compliance well's difference between average ranks exceeded its corresponding critical value at a 5% significance level. Therefore, we conclude that significant evidence of contamination does not exist at the 5% significance level. Cadmium (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 16 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Chromium NC MCL (mg/l):10 Method:Kruskal-Wallis Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 15 NS NS 18 17 11 ND 26 5.4 50 NS NP NP 5 06/26/00 22 ND NS NS NS NS NS NS NS NS NS NP NP 5 07/26/00 29 20 NS NS NS NS NS NS NS NS NS NP NP 5 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 10 04/09/01 130 ND NS 11 8.4 ND ND 20 27 160 NS NP NP 5 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 04/15/02 170 ND NS ND ND 5.7 7 10 56 180 NS NP NP 5 09/26/02 33 5.4 33 510 ND 5.2 ND 37 36 230 770 NP NP 5 04/28/03 ND ND ND 89 ND ND ND ND ND 110 27 NP NP 5 10/30/03 30 ND NT ND 6.2 ND ND ND 31 4.6 140 NP NP 2 04/20/04 33 ND 2.1 45 13 ND ND 11 3.5 190 68 NP NP 2 10/21/04 21 ND 2.8 16 2 ND ND ND ND 120 140 NP NP 2 04/18/05 49 12 8.3 680 2.9 ND ND 3.2 ND 210 100 NP NP 2 10/13/05 52 ND 3.7 230 4.7 ND ND ND ND 150 88 NP NP 2 04/25/06 65 ND 16 ND ND ND ND ND 16 100 93 NP NP 10 10/20/06 50 ND 11 24 ND ND ND ND 17 ND 27 NP NP 5 04/25/07 20 ND ND 16 ND 410 ND ND ND ND 17 NP NP 10 10/31/07 40.9 ND 11.9 10.9 7.8 ND ND ND 5.1 75.5 33.7 NP NP 5 04/23/08 10.7 ND 16.8 7.8 ND ND ND ND 7.6 7.3 14.9 NP NP 5 10/20/08 38.6 ND 29.4 12.7 ND ND ND ND ND ND 6.8 NP NP 5 04/22/09 12.3 ND 28.9 19.7 5.1 ND ND ND 7.3 ND NS NP NP 5 10/26/09 10 ND 8.1 ND 18.7 ND NS NS NS 10.9 8.1 NP NP 5 04/22/10 14.3 10.9 13.1 ND ND ND NS NS ND ND ND NP NP 5 10/27/10 10.1 ND 6.6 7.1 ND ND 12 9.2 ND ND 5.2 ND ND 5 04/29/11 8 ND 8.6 ND ND ND ND ND ND ND ND ND ND 5 10/25/11 15 ND ND 21.1 ND ND 8.1 ND ND 9.2 5.1 ND ND 5 04/20/12 24.5 ND ND 5.1 ND ND 7.9 ND ND ND ND 12.3 ND 5 10/24/12 30.4 6 ND 6.4 ND ND ND ND ND ND ND ND ND 5 04/24/13 19 ND ND 8.8 6.8 ND ND ND ND ND ND ND ND 5 10/24/13 14.5 ND 12.1 ND ND ND ND ND ND ND ND ND ND 5 04/24/14 12.8 ND ND ND ND ND ND ND ND ND ND 5.1 ND 5 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/28/15 10.3 ND 8.2 7.9 ND ND ND ND ND ND ND ND ND 5 10/27/15 31.4 ND ND ND ND ND ND ND ND 7.7 ND ND ND 5 Ni 32 31 26 30 30 30 28 28 29 30 26 11 11 sum of rank values (Ri)8830.5 3833.0 5183.0 6484.0 4465.0 3627.0 3355.0 3938.5 4664.5 6178.5 5620.5 1373.5 1100.0 avg rank value (Rbar)276.0 123.6 199.3 216.1 148.8 120.9 119.8 140.7 160.8 206.0 216.2 124.9 100.0 Number of each rank value Rank Value rank value of NDs =2 26 9 10 19 26 24 21 18 14 10 9 11 100 rank value of 2s =0 0 0 0 1 0 0 0 0 0 0 0 0 200 rank value of 2.1s =0 0 1 0 0 0 0 0 0 0 0 0 0 201 Chromium (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 17 of 66 rank value of 2.8s =0 0 1 0 0 0 0 0 0 0 0 0 0 202 rank value of 2.9s =0 0 0 0 1 0 0 0 0 0 0 0 0 203 rank value of 3.2s =0 0 0 0 0 0 0 1 0 0 0 0 0 204 rank value of 3.5s =0 0 0 0 0 0 0 0 1 0 0 0 0 205 rank value of 3.7s =0 0 1 0 0 0 0 0 0 0 0 0 0 206 rank value of 4.6s =0 0 0 0 0 0 0 0 0 1 0 0 0 207 rank value of 4.7s =0 0 0 0 1 0 0 0 0 0 0 0 0 208 rank value of 5.1s =0 0 0 1 1 0 0 0 1 0 1 1 0 211 rank value of 5.2s =0 0 0 0 0 1 0 0 0 0 1 0 0 214.5 rank value of 5.4s =0 1 0 0 0 0 0 0 1 0 0 0 0 216.5 rank value of 5.7s =0 0 0 0 0 1 0 0 0 0 0 0 0 218 rank value of 6s =0 1 0 0 0 0 0 0 0 0 0 0 0 219 rank value of 6.2s =0 0 0 0 1 0 0 0 0 0 0 0 0 220 rank value of 6.4s =0 0 0 1 0 0 0 0 0 0 0 0 0 221 rank value of 6.6s =0 0 1 0 0 0 0 0 0 0 0 0 0 222 rank value of 6.8s =0 0 0 0 1 0 0 0 0 0 1 0 0 223.5 rank value of 7s =0 0 0 0 0 0 1 0 0 0 0 0 0 225 rank value of 7.1s =0 0 0 1 0 0 0 0 0 0 0 0 0 226 rank value of 7.3s =0 0 0 0 0 0 0 0 1 1 0 0 0 227.5 rank value of 7.6s =0 0 0 0 0 0 0 0 1 0 0 0 0 229 rank value of 7.7s =0 0 0 0 0 0 0 0 0 1 0 0 0 230 rank value of 7.8s =0 0 0 1 1 0 0 0 0 0 0 0 0 231.5 rank value of 7.9s =0 0 0 1 0 0 1 0 0 0 0 0 0 233.5 rank value of 8s =1 0 0 0 0 0 0 0 0 0 0 0 0 235 rank value of 8.1s =0 0 1 0 0 0 1 0 0 0 1 0 0 237 rank value of 8.2s =0 0 1 0 0 0 0 0 0 0 0 0 0 239 rank value of 8.3s =0 0 1 0 0 0 0 0 0 0 0 0 0 240 rank value of 8.4s =0 0 0 0 1 0 0 0 0 0 0 0 0 241 rank value of 8.6s =0 0 1 0 0 0 0 0 0 0 0 0 0 242 rank value of 8.8s =0 0 0 1 0 0 0 0 0 0 0 0 0 243 rank value of 9.2s =0 0 0 0 0 0 0 1 0 1 0 0 0 244.5 rank value of 10s =1 0 0 0 0 0 0 1 0 0 0 0 0 246.5 rank value of 10.1s =1 0 0 0 0 0 0 0 0 0 0 0 0 248 rank value of 10.3s =1 0 0 0 0 0 0 0 0 0 0 0 0 249 rank value of 10.7s =1 0 0 0 0 0 0 0 0 0 0 0 0 250 rank value of 10.9s =0 1 0 1 0 0 0 0 0 1 0 0 0 252 rank value of 11s =0 0 1 1 0 1 0 1 0 0 0 0 0 255.5 rank value of 11.9s =0 0 1 0 0 0 0 0 0 0 0 0 0 258 rank value of 12s =0 1 0 0 0 0 1 0 0 0 0 0 0 259.5 rank value of 12.1s =0 0 1 0 0 0 0 0 0 0 0 0 0 261 rank value of 12.3s =1 0 0 0 0 0 0 0 0 0 0 1 0 262.5 rank value of 12.7s =0 0 0 1 0 0 0 0 0 0 0 0 0 264 rank value of 12.8s =1 0 0 0 0 0 0 0 0 0 0 0 0 265 rank value of 13s =0 0 0 0 1 0 0 0 0 0 0 0 0 266 rank value of 13.1s =0 0 1 0 0 0 0 0 0 0 0 0 0 267 rank value of 14.3s =1 0 0 0 0 0 0 0 0 0 0 0 0 268 rank value of 14.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 269 rank value of 14.9s =0 0 0 0 0 0 0 0 0 0 1 0 0 270 rank value of 15s =2 0 0 0 0 0 0 0 0 0 0 0 0 271.5 rank value of 16s =0 0 1 2 0 0 0 0 1 0 0 0 0 274.5 rank value of 16.8s =0 0 1 0 0 0 0 0 0 0 0 0 0 277 rank value of 17s =0 0 0 0 1 0 0 0 1 0 1 0 0 279 rank value of 18s =0 0 0 1 0 0 0 0 0 0 0 0 0 281 rank value of 18.7s =0 0 0 0 1 0 0 0 0 0 0 0 0 282 rank value of 19s =1 0 0 0 0 0 0 0 0 0 0 0 0 283 rank value of 19.7s =0 0 0 1 0 0 0 0 0 0 0 0 0 284 rank value of 20s =1 1 0 0 0 0 0 1 0 0 0 0 0 286 rank value of 21s =1 0 0 0 0 0 0 0 0 0 0 0 0 288 Chromium (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 18 of 66 rank value of 21.1s =0 0 0 1 0 0 0 0 0 0 0 0 0 289 rank value of 22s =1 0 0 0 0 0 0 0 0 0 0 0 0 290 rank value of 24s =0 0 0 1 0 0 0 0 0 0 0 0 0 291 rank value of 24.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 292 rank value of 26s =0 0 0 0 0 0 0 1 0 0 0 0 0 293 rank value of 27s =0 0 0 0 0 0 0 0 1 0 2 0 0 295 rank value of 28.9s =0 0 1 0 0 0 0 0 0 0 0 0 0 297 rank value of 29s =1 0 0 0 0 0 0 0 0 0 0 0 0 298 rank value of 29.4s =0 0 1 0 0 0 0 0 0 0 0 0 0 299 rank value of 30s =1 0 0 0 0 0 0 0 0 0 0 0 0 300 rank value of 30.4s =1 0 0 0 0 0 0 0 0 0 0 0 0 301 rank value of 31s =0 0 0 0 0 0 0 0 1 0 0 0 0 302 rank value of 31.4s =1 0 0 0 0 0 0 0 0 0 0 0 0 303 rank value of 33s =2 0 1 0 0 0 0 0 0 0 0 0 0 305 rank value of 33.7s =0 0 0 0 0 0 0 0 0 0 1 0 0 307 rank value of 36s =0 0 0 0 0 0 0 0 1 0 0 0 0 308 rank value of 37s =0 0 0 0 0 0 0 1 0 0 0 0 0 309 rank value of 38.6s =1 0 0 0 0 0 0 0 0 0 0 0 0 310 rank value of 40.9s =1 0 0 0 0 0 0 0 0 0 0 0 0 311 rank value of 45s =0 0 0 1 0 0 0 0 0 0 0 0 0 312 rank value of 49s =1 0 0 0 0 0 0 0 0 0 0 0 0 313 rank value of 50s =1 0 0 0 0 0 0 0 0 1 0 0 0 314.5 rank value of 52s =1 0 0 0 0 0 0 0 0 0 0 0 0 316 rank value of 56s =0 0 0 0 0 0 0 0 1 0 0 0 0 317 rank value of 65s =1 0 0 0 0 0 0 0 0 0 0 0 0 318 rank value of 68s =0 0 0 0 0 0 0 0 0 0 1 0 0 319 rank value of 75.5s =0 0 0 0 0 0 0 0 0 1 0 0 0 320 rank value of 88s =0 0 0 0 0 0 0 0 0 0 1 0 0 321 rank value of 89s =0 0 0 1 0 0 0 0 0 0 0 0 0 322 rank value of 93s =0 0 0 0 0 0 0 0 0 0 1 0 0 323 rank value of 100s =0 0 0 0 0 0 0 0 0 1 1 0 0 324.5 rank value of 110s =0 0 0 0 0 0 0 0 0 1 0 0 0 326 rank value of 120s =0 0 0 0 0 0 0 0 0 1 0 0 0 327 rank value of 130s =1 0 0 0 0 0 0 0 0 0 0 0 0 328 rank value of 140s =0 0 0 0 0 0 0 0 0 0 2 0 0 329.5 rank value of 150s =0 0 0 0 0 0 0 0 0 1 0 0 0 331 rank value of 160s =0 0 0 0 0 0 0 0 0 1 0 0 0 332 rank value of 170s =1 0 0 0 0 0 0 0 0 0 0 0 0 333 rank value of 180s =0 0 0 0 0 0 0 0 0 1 0 0 0 334 rank value of 190s =0 0 0 0 0 0 0 0 0 1 0 0 0 335 rank value of 210s =0 0 0 0 0 0 0 0 0 1 0 0 0 336 rank value of 230s =0 0 0 1 0 0 0 0 0 1 0 0 0 337.5 rank value of 410s =0 0 0 0 0 1 0 0 0 0 0 0 0 339 rank value of 510s =0 0 0 1 0 0 0 0 0 0 0 0 0 340 rank value of 680s =0 0 0 1 0 0 0 0 0 0 0 0 0 341 rank value of 770s =0 0 0 0 0 0 0 0 0 0 1 0 0 342 n =32 31 26 30 30 30 28 28 29 30 26 11 11 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SK i=1 (Ri 2)/Ni]} -3(N+1) Well = Background MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Ri2/Ni = 3578624.3 1E+06 664541 438504 402001 553992 750261 1E+06 1E+06 171500 110000 Chromium (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 19 of 66 Ni bg = 89 N = 342 H = 51.08 Adjust H for ties: Ti =8E+06 sum of T1..T25 H' = H/(1-(Ti/(N3-N))) H' =63.61 Chi-square =18.31 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 17df at the 5% significance level from Table 1 of the IFG. The value is 18.31 which is less than H' =63.61. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Rbar (well x) = 216.1 148.8 120.9 119.8 140.7 160.8 206.0 216.2 124.9 100.0 avg Rbar (background) = 200.5 200.5 200.5 200.5 200.5 200.5 200.5 200.5 200.5 200.5 Dx = 15.6 -51.7 -79.6 -80.7 -59.9 -39.7 5.4 15.7 -75.7 -100.5 Cx = 48.6 48.6 48.6 49.9 49.9 49.3 48.6 51.4 73.6 73.6 Statistical Significance ? No No No No No No No No No No If SSI, is current event above MCL?---------- Compare each difference (Dx) with the corresponding critical value (Cx). No compliance well's difference between average ranks exceeded its corresponding critical value at a 5% significance level. Therefore, we conclude that significant evidence of contamination does not exist at the 5% significance level. Chromium (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 20 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Cobalt NC MCL (mg/l):Not Established Method:Kruskal-Wallis Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 ND NS NS ND 8.2 5.4 ND 14 ND 16 NS NP NP 5 06/26/00 10 ND NS NS NS NS NS NS NS NS NS NP NP 5 07/26/00 9.9 ND NS NS NS NS NS NS NS NS NS NP NP 5 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 10 04/09/01 54 ND NS ND ND ND 13 12 13 59 NS NP NP 5 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 04/15/02 58 ND NS ND ND ND 18 8 21 82 NS NP NP 5 09/26/02 13 5.4 16 100 ND 16 7.4 21 19 85 560 NP NP 5 04/28/03 21 ND ND 37 ND ND 6.9 ND 17 50 81 NP NP 5 10/30/03 9 ND NT ND ND ND 5.7 ND 52 8.8 110 NP NP 5 04/20/04 9.5 ND ND 7.7 5.2 ND 13 6.4 ND 43 50 NP NP 5 10/21/04 6.2 ND ND ND ND ND ND ND ND 31 120 NP NP 5 04/18/05 12 ND ND 110 ND ND ND ND ND 36 70 NP NP 5 10/13/05 21 ND ND 32 ND ND 5.1 ND ND 29 56 NP NP 5 04/25/06 16 ND ND ND ND ND ND ND ND 25 57 NP NP 10 10/20/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/25/07 ND ND ND ND ND 260 ND ND ND ND ND NP NP 10 10/31/07 16.8 ND ND ND 10.6 ND ND ND ND ND 17.6 NP NP 5 04/23/08 ND ND ND ND ND ND ND ND ND ND 22.3 NP NP 5 10/20/08 27 10.4 19.5 9.4 7.7 ND 12.6 5.3 7.1 ND 18.4 NP NP 5 04/22/09 5 6.3 17.1 8.5 5.7 ND 7 ND 6.4 ND NS NP NP 5 10/26/09 ND ND ND ND 6 ND NS NS NS ND 6 NP NP 5 04/22/10 5.6 ND ND ND ND ND NS NS ND ND ND NP NP 5 10/27/10 ND ND ND ND ND ND 17.3 5.6 ND ND 7.8 29.6 ND 5 04/29/11 ND ND ND ND 6.9 ND 8.9 ND ND ND ND 26.3 ND 5 10/25/11 5.3 ND ND 6.4 6.3 ND 21 ND ND ND ND 42.4 ND 5 04/20/12 6.9 ND ND ND ND ND 6.4 ND ND ND ND 134 ND 5 10/24/12 15.7 ND ND ND 5.6 ND 6.5 ND ND ND ND 48.5 ND 5 04/24/13 16.5 ND ND ND 10.8 ND 5.6 ND ND ND 8.9 115 ND 5 10/24/13 11.8 ND ND ND 8 ND 7.5 ND ND ND ND 84.5 ND 5 04/24/14 ND ND ND ND 5.7 ND ND ND ND ND ND 65.1 ND 5 10/27/14 ND ND ND ND ND ND ND ND ND ND ND 24.2 ND 5 04/28/15 ND ND ND ND ND ND ND ND ND ND ND 29.3 ND 5 10/27/15 6.2 ND ND ND 5.6 ND ND ND ND ND ND 39 ND 5 Ni 32 31 26 30 30 30 28 28 29 30 26 11 11 sum of rank values (Ri)7183.0 3898.0 3467.0 4815.5 5151.5 3896.5 5565.0 4198.5 4474.0 5569.5 5665.0 3532.0 1237.5 avg rank value (Rbar)224.5 125.7 133.3 160.5 171.7 129.9 198.8 149.9 154.3 185.7 217.9 321.1 112.5 Number of each rank value Rank Value rank value of NDs =10 28 23 22 17 27 12 21 22 19 12 0 11 112.5 rank value of 5s =1 0 0 0 0 0 0 0 0 0 0 0 0 225 rank value of 5.1s =0 0 0 0 0 0 1 0 0 0 0 0 0 226 Cobalt (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 21 of 66 rank value of 5.2s =0 0 0 0 1 0 0 0 0 0 0 0 0 227 rank value of 5.3s =1 0 0 0 0 0 0 1 0 0 0 0 0 228.5 rank value of 5.4s =0 1 0 0 0 1 0 0 0 0 0 0 0 230.5 rank value of 5.6s =1 0 0 0 2 0 1 1 0 0 0 0 0 234 rank value of 5.7s =0 0 0 0 2 0 1 0 0 0 0 0 0 238 rank value of 6s =0 0 0 0 1 0 0 0 0 0 1 0 0 240.5 rank value of 6.2s =2 0 0 0 0 0 0 0 0 0 0 0 0 242.5 rank value of 6.3s =0 1 0 0 1 0 0 0 0 0 0 0 0 244.5 rank value of 6.4s =0 0 0 1 0 0 1 1 1 0 0 0 0 247.5 rank value of 6.5s =0 0 0 0 0 0 1 0 0 0 0 0 0 250 rank value of 6.9s =1 0 0 0 1 0 1 0 0 0 0 0 0 252 rank value of 7s =0 0 0 0 0 0 1 0 0 0 0 0 0 254 rank value of 7.1s =0 0 0 0 0 0 0 0 1 0 0 0 0 255 rank value of 7.4s =0 0 0 0 0 0 1 0 0 0 0 0 0 256 rank value of 7.5s =0 0 0 0 0 0 1 0 0 0 0 0 0 257 rank value of 7.7s =0 0 0 1 1 0 0 0 0 0 0 0 0 258.5 rank value of 7.8s =0 0 0 0 0 0 0 0 0 0 1 0 0 260 rank value of 8s =0 0 0 0 1 0 0 0 0 0 0 0 0 261 rank value of 8.2s =0 0 0 0 1 0 0 1 0 0 0 0 0 262.5 rank value of 8.5s =0 0 0 1 0 0 0 0 0 0 0 0 0 264 rank value of 8.8s =0 0 0 0 0 0 0 0 0 1 0 0 0 265 rank value of 8.9s =0 0 0 0 0 0 1 0 0 0 1 0 0 266.5 rank value of 9s =1 0 0 0 0 0 0 0 0 0 0 0 0 268 rank value of 9.4s =0 0 0 1 0 0 0 0 0 0 0 0 0 269 rank value of 9.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 270 rank value of 9.9s =1 0 0 0 0 0 0 0 0 0 0 0 0 271 rank value of 10s =1 0 0 0 0 0 0 0 0 0 0 0 0 272 rank value of 10.4s =0 1 0 0 0 0 0 0 0 0 0 0 0 273 rank value of 10.6s =0 0 0 0 1 0 0 0 0 0 0 0 0 274 rank value of 10.8s =0 0 0 0 1 0 0 0 0 0 0 0 0 275 rank value of 11.8s =1 0 0 0 0 0 0 0 0 0 0 0 0 276 rank value of 12s =1 0 0 0 0 0 0 1 0 0 0 0 0 277.5 rank value of 12.6s =0 0 0 0 0 0 1 0 0 0 0 0 0 279 rank value of 13s =1 0 0 0 0 0 2 0 1 0 0 0 0 281.5 rank value of 14s =0 0 0 0 0 0 0 1 0 0 0 0 0 284 rank value of 15.7s =1 0 0 0 0 0 0 0 0 0 0 0 0 285 rank value of 16s =1 0 1 0 0 1 0 0 0 1 0 0 0 287.5 rank value of 16.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 290 rank value of 16.8s =1 0 0 0 0 0 0 0 0 0 0 0 0 291 rank value of 17s =0 0 0 0 0 0 0 0 1 0 0 0 0 292 rank value of 17.1s =0 0 1 0 0 0 0 0 0 0 0 0 0 293 rank value of 17.3s =0 0 0 0 0 0 1 0 0 0 0 0 0 294 rank value of 17.6s =0 0 0 0 0 0 0 0 0 0 1 0 0 295 rank value of 18s =0 0 0 0 0 0 1 0 0 0 0 0 0 296 rank value of 18.4s =0 0 0 0 0 0 0 0 0 0 1 0 0 297 rank value of 19s =0 0 0 0 0 0 0 0 1 0 0 0 0 298 rank value of 19.5s =0 0 1 0 0 0 0 0 0 0 0 0 0 299 rank value of 21s =2 0 0 0 0 0 1 1 1 0 0 0 0 302 rank value of 22.3s =0 0 0 0 0 0 0 0 0 0 1 0 0 305 rank value of 24.2s =0 0 0 0 0 0 0 0 0 0 0 1 0 306 rank value of 25s =0 0 0 0 0 0 0 0 0 1 0 0 0 307 rank value of 26.3s =0 0 0 0 0 0 0 0 0 0 0 1 0 308 rank value of 27s =1 0 0 0 0 0 0 0 0 0 0 0 0 309 rank value of 29s =0 0 0 0 0 0 0 0 0 1 0 0 0 310 rank value of 29.3s =0 0 0 0 0 0 0 0 0 0 0 1 0 311 rank value of 29.6s =0 0 0 0 0 0 0 0 0 0 0 1 0 312 rank value of 31s =0 0 0 0 0 0 0 0 0 1 0 0 0 313 rank value of 32s =0 0 0 1 0 0 0 0 0 0 0 0 0 314 Cobalt (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 22 of 66 rank value of 36s =0 0 0 0 0 0 0 0 0 1 0 0 0 315 rank value of 37s =0 0 0 1 0 0 0 0 0 0 0 0 0 316 rank value of 39s =0 0 0 0 0 0 0 0 0 0 0 1 0 317 rank value of 42.4s =0 0 0 0 0 0 0 0 0 0 0 1 0 318 rank value of 43s =0 0 0 0 0 0 0 0 0 1 0 0 0 319 rank value of 48.5s =0 0 0 0 0 0 0 0 0 0 0 1 0 320 rank value of 50s =0 0 0 0 0 0 0 0 0 1 1 0 0 321.5 rank value of 52s =0 0 0 0 0 0 0 0 1 0 0 0 0 323 rank value of 54s =1 0 0 0 0 0 0 0 0 0 0 0 0 324 rank value of 56s =0 0 0 0 0 0 0 0 0 0 1 0 0 325 rank value of 57s =0 0 0 0 0 0 0 0 0 0 1 0 0 326 rank value of 58s =1 0 0 0 0 0 0 0 0 0 0 0 0 327 rank value of 59s =0 0 0 0 0 0 0 0 0 1 0 0 0 328 rank value of 65.1s =0 0 0 0 0 0 0 0 0 0 0 1 0 329 rank value of 70s =0 0 0 0 0 0 0 0 0 0 1 0 0 330 rank value of 81s =0 0 0 0 0 0 0 0 0 0 1 0 0 331 rank value of 82s =0 0 0 0 0 0 0 0 0 1 0 0 0 332 rank value of 84.5s =0 0 0 0 0 0 0 0 0 0 0 1 0 333 rank value of 85s =0 0 0 0 0 0 0 0 0 1 0 0 0 334 rank value of 100s =0 0 0 1 0 0 0 0 0 0 0 0 0 335 rank value of 110s =0 0 0 1 0 0 0 0 0 0 1 0 0 336.5 rank value of 115s =0 0 0 0 0 0 0 0 0 0 0 1 0 338 rank value of 120s =0 0 0 0 0 0 0 0 0 0 1 0 0 339 rank value of 134s =0 0 0 0 0 0 0 0 0 0 0 1 0 340 rank value of 260s =0 0 0 0 0 1 0 0 0 0 0 0 0 341 rank value of 560s =0 0 0 0 0 0 0 0 0 0 1 0 0 342 n =32 31 26 30 30 30 28 28 29 30 26 11 11 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SK i=1 (Ri 2)/Ni]} -3(N+1) Well = Background MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Ri2/Ni = 2378025.9 772968 884598 506090 1E+06 629550 690230 1E+06 1E+06 1E+06 139219 Ni bg = 89 N = 342 H = 46.05 Adjust H for ties: Ti =1E+07 sum of T1..T19 H' = H/(1-(Ti/(N3-N))) H' =64.04 Chi-square =18.31 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 17df at the 5% significance level from Table 1 of the IFG. The value is 18.31 which is less than H' =64.04. Cobalt (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 23 of 66 Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Rbar (well x) = 160.5 171.7 129.9 198.8 149.9 154.3 185.7 217.9 321.1 112.5 avg Rbar (background) = 163.5 163.5 163.5 163.5 163.5 163.5 163.5 163.5 163.5 163.5 Dx = -2.9 8.3 -33.6 35.3 -13.5 -9.2 22.2 54.4 157.6 -51.0 Cx = 48.6 48.6 48.6 49.9 49.9 49.3 48.6 51.4 73.6 73.6 Statistical Significance ? No No No No No No No Yes Yes No If SSI, is current event above MCL?-------NE NE - Compare each difference (Dx) with the corresponding critical value (Cx). The Dx value for the above indicated wells do exceed the corresponding Cx value. Therefore, we conclude that the concentration of Total Cobalt averaged over these compliance wells are significantly greater than that of the background wells. Shewart-CUSUM Control Charts should be performed for each failing well to check for statistical significance. Cobalt (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 24 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Cobalt NC MCL (mg/l):Not Established Method:Shewhart-CUSUM Control Chart Part 1: Check for Normality MW - 1 5 MD L 9/26/02 560 5 4/28/03 81 5 10/30/03 110 5 4/20/04 50 5 10/21/04 120 5 4/18/05 70 5 10/13/05 56 5 4/25/06 57 10 10/20/06 ND 5 4/25/07 ND 10 10/31/07 17.6 5 4/23/08 22.3 5 10/20/08 18.4 5 4/22/09 NS 5 10/26/09 6 5 4/22/10 ND 5 10/27/10 7.8 5 4/29/11 ND 5 10/25/11 ND 5 4/20/12 ND 5 10/24/12 ND 5 4/24/13 8.9 5 10/24/13 ND 5 4/24/14 ND 5 10/27/14 ND 5 4/28/15 ND 5 10/27/15 ND 5 If not detected (ND), use half of the detection limit. Xbar =46.826923 SD =110.42638 N =26 1/NSi(Xi-Xbar)3 =5175558.3 g1=4.0765119 Since the Coefficient of Skewness of 4.08 is greater than 1.0, the real data appear to be significantly skewed. Do not assume that the data follow a Normal distribution. Perform the Skewness Test on the natural log of the values. Xbar =2.4247956 SD =1.6465836 N =26 1/NSi(Xi-Xbar)3 =2.7564623 g1=0.6548634 Since the Coefficient of Skewness of 0.65 is less than 1.0, the data appear not to be significantly skewed. Co (S-C MW-15) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 25 of 66 Proceed with further statistical tests using the log-transformed values shown above. Part 2: Shewhart-CUSUM Control Chart Compute the mean and standard deviation of the historical data: 4.5549099 = xmean (Mean of N1-N8 historical data) 0.7832425 = s (Standard Deviation of N1-N8 historical data) 1 = k (constant, reference value) 5 = h (constant, upper control limit for the CUSUM scheme) 4.5 = SCL (Constant, upper Shewhart Control Limit) Compute the standardized mean (Zi) and the cumulative sum (Si) for each concentration. Date xi Zi Si h SCL 0 10/20/06 0.9162907 -4.6455844 0 5 4.5 4/25/07 1.6094379 -3.7606131 0 5 4.5 10/31/07 2.8678989 -2.1538808 0 5 4.5 4/23/08 3.1045867 -1.8516912 0 5 4.5 10/20/08 2.9123507 -2.0971273 0 5 4.5 10/26/09 1.7917595 -3.5278352 0 5 4.5 4/22/10 0.9162907 -4.6455844 0 5 4.5 10/27/10 2.0541237 -3.1928632 0 5 4.5 4/29/11 0.9162907 -4.6455844 0 5 4.5 10/25/11 0.9162907 -4.6455844 0 5 4.5 4/20/12 0.9162907 -4.6455844 0 5 4.5 10/24/12 0.9162907 -4.6455844 0 5 4.5 4/24/13 2.1860513 -3.0244255 0 5 4.5 10/24/13 0.9162907 -4.6455844 0 5 4.5 4/24/14 0.9162907 -4.6455844 0 5 4.5 10/27/14 0.9162907 -4.6455844 0 5 4.5 4/28/15 0.9162907 -4.6455844 0 5 4.5 10/27/15 0.9162907 -4.6455844 0 5 4.5 Plot Zi and Si versus time: Compare the Zi and Si values to their respective control limits of SCL and h. The limits were not exceeded and do not indicate statistically significant evidence of contamination at the site. -6 -4 -2 0 2 4 6 5/ 2 8 / 0 5 10 / 1 0 / 0 6 2/ 2 2 / 0 8 7/ 6 / 0 9 11 / 1 8 / 1 0 4/ 1 / 1 2 8/ 1 4 / 1 3 12 / 2 7 / 1 4 5/ 1 0 / 1 6 St a n d a r d i z e d U n i t s Combined Shewart-CUSUM Control Chart Zi SCL Si h Co (S-C MW-15) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 26 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Cobalt NC MCL (mg/l):Not Established Method:Shewhart-CUSUM Control Chart Part 1: Check for Normality MW - 1 6 MD L 9/26/02 NP 5 4/28/03 NP 5 10/30/03 NP 5 4/20/04 NP 5 10/21/04 NP 5 4/18/05 NP 5 10/13/05 NP 5 4/25/06 NP 10 10/20/06 NP 5 4/25/07 NP 10 10/31/07 NP 5 4/23/08 NP 5 10/20/08 NP 5 4/22/09 NP 5 10/26/09 NP 5 4/22/10 NP 5 10/27/10 29.6 5 4/29/11 26.3 5 10/25/11 42.4 5 4/20/12 134 5 10/24/12 48.5 5 4/24/13 115 5 10/24/13 84.5 5 4/24/14 65.1 5 10/27/14 24.2 5 4/28/15 29.3 5 10/27/15 39 5 If not detected (ND), use half of the detection limit. Xbar =57.990909 SD =37.748972 N =11 1/NSi(Xi-Xbar)3 =46817.88 g1=1.0041194 Since the Coefficient of Skewness of 1.00 is greater than 1.0, the real data appear to be significantly skewed. Do not assume that the data follow a Normal distribution. Perform the Skewness Test on the natural log of the values. Xbar =3.8880914 SD =0.5994917 N =11 Co (S-C MW-16) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 27 of 66 1/NSi(Xi-Xbar)3 =0.0902745 g1=0.4833975 Since the Coefficient of Skewness of 0.48 is less than 1.0, the data appear not to be significantly skewed. Proceed with further statistical tests using the log-transformed values shown above. Part 2: Shewhart-CUSUM Control Chart Compute the mean and standard deviation of the historical data: 4.0676879 = xmean (Mean of N1-N8 historical data) 0.6014743 = s (Standard Deviation of N1-N8 historical data) 1 = k (constant, reference value) 5 = h (constant, upper control limit for the CUSUM scheme) 4.5 = SCL (Constant, upper Shewhart Control Limit) Compute the standardized mean (Zi) and the cumulative sum (Si) for each concentration. Date xi Zi Si h SCL 0 10/27/14 3.1863526 -1.4652918 0 5 4.5 4/28/15 3.3775875 -1.1473482 0 5 4.5 10/27/15 3.6635616 -0.6718929 0 5 4.5 Plot Zi and Si versus time: Compare the Zi and Si values to their respective control limits of SCL and h. The limits were not exceeded and do not indicate statistically significant evidence of contamination at the site. -2 -1 0 1 2 3 4 5 6 9/ 1 8 / 1 4 11 / 7 / 1 4 12 / 2 7 / 1 4 2/ 1 5 / 1 5 4/ 6 / 1 5 5/ 2 6 / 1 5 7/ 1 5 / 1 5 9/ 3 / 1 5 10 / 2 3 / 1 5 12 / 1 2 / 1 5 St a n d a r d i z e d U n i t s Combined Shewart-CUSUM Control Chart Zi SCL Si h Co (S-C MW-16) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 28 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Copper NC MCL (mg/l):1000 Method:Kruskal-Wallis Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 12 NS NS ND ND 13 ND 27 ND 22 NS NP NP 5 06/26/00 17 6 NS NS NS NS NS NS NS NS NS NP NP 5 07/26/00 12 6.1 NS NS NS NS NS NS NS NS NS NP NP 5 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 200 04/09/01 77 8.4 NS ND ND 5.4 ND 26 38 110 NS NP NP 5 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 200 04/15/02 69 ND NS ND ND ND ND 13 68 120 NS NP NP 2 09/26/02 20 10 31 220 ND ND 2.6 42 88 150 450 NP NP 2 04/28/03 24 ND 2.6 40 ND ND ND ND 28 94 71 NP NP 2 10/30/03 18 ND NT ND 2.3 2.6 ND 3 85 4.4 150 NP NP 2 04/20/04 18 ND 2.8 12 5.3 2.3 4.3 13 7.4 100 89 NP NP 2 10/21/04 11 ND ND 2 ND ND ND ND ND 63 140 NP NP 2 04/18/05 29 ND ND 240 ND ND ND 3.8 ND 120 130 NP NP 2 10/13/05 31 2.6 3.5 70 ND ND ND ND 3 82 96 NP NP 2 04/25/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 200 10/20/06 26 ND ND 9.6 ND ND ND ND 20 ND 25 NP NP 5 04/25/07 15 ND ND ND ND 330 ND ND ND ND 26 NP NP 10 10/31/07 29.2 ND ND ND ND ND ND ND 6.3 40.3 47.4 NP NP 5 04/23/08 7.2 ND ND ND ND ND ND ND 7.2 ND 17 NP NP 5 10/20/08 26.5 ND 8.3 ND ND ND ND ND ND ND 9.7 NP NP 5 04/22/09 5.1 ND 22.6 6 ND ND ND ND 8.8 ND NS NP NP 5 10/26/09 5.8 ND ND ND 6.4 ND NS NS NS ND 7.1 NP NP 5 04/22/10 9.9 ND ND ND ND 5.9 NS NS ND ND ND NP NP 5 10/27/10 6.7 ND ND ND ND ND ND 12.4 ND ND 53.9 ND ND 5 04/29/11 6.4 ND ND ND 6.7 6.1 ND ND ND ND 5.2 ND ND 5 10/25/11 9.6 ND ND 9.4 6.8 11.2 7.6 ND ND 5.1 6.9 ND ND 5 04/20/12 15.6 ND ND ND 5.8 5.2 ND ND ND ND ND 6.5 ND 5 10/24/12 22.7 ND ND ND 6 ND ND ND 5.1 ND ND ND ND 5 04/24/13 13.4 ND ND ND 9.3 6 ND ND ND ND ND ND ND 5 10/24/13 12.6 ND ND ND 7.5 5.8 ND ND ND ND ND ND ND 5 04/24/14 7.9 ND ND ND ND ND ND ND ND ND ND ND ND 5 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/28/15 7.4 ND ND ND ND ND ND ND ND ND ND ND ND 5 10/27/15 19.1 ND ND ND 5.4 7.3 ND ND ND ND ND 6 ND 5 Ni 32 31 26 30 30 30 28 28 29 30 26 11 11 sum of rank values (Ri)8788.0 4098.0 3734.0 4894.5 4663.0 5025.5 3443.5 4417.5 5248.0 5679.5 5981.5 1481.0 1199.0 avg rank value (Rbar)274.6 132.2 143.6 163.2 155.4 167.5 123.0 157.8 181.0 189.3 230.1 134.6 109.0 Number of each rank value Rank Value rank value of NDs =2 26 20 21 20 18 25 20 17 18 10 9 11 109 rank value of 2s =0 0 0 1 0 0 0 0 0 0 0 0 0 218 rank value of 2.3s =0 0 0 0 1 1 0 0 0 0 0 0 0 219.5 Copper (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 29 of 66 rank value of 2.6s =0 1 1 0 0 1 1 0 0 0 0 0 0 222.5 rank value of 2.8s =0 0 1 0 0 0 0 0 0 0 0 0 0 225 rank value of 3s =0 0 0 0 0 0 0 1 1 0 0 0 0 226.5 rank value of 3.5s =0 0 1 0 0 0 0 0 0 0 0 0 0 228 rank value of 3.8s =0 0 0 0 0 0 0 1 0 0 0 0 0 229 rank value of 4.3s =0 0 0 0 0 0 1 0 0 0 0 0 0 230 rank value of 4.4s =0 0 0 0 0 0 0 0 0 1 0 0 0 231 rank value of 5.1s =1 0 0 0 0 0 0 0 1 1 0 0 0 233 rank value of 5.2s =0 0 0 0 0 1 0 0 0 0 1 0 0 235.5 rank value of 5.3s =0 0 0 0 1 0 0 0 0 0 0 0 0 237 rank value of 5.4s =0 0 0 0 1 1 0 0 0 0 0 0 0 238.5 rank value of 5.8s =1 0 0 0 1 1 0 0 0 0 0 0 0 241 rank value of 5.9s =0 0 0 0 0 1 0 0 0 0 0 0 0 243 rank value of 6s =0 1 0 1 1 1 0 0 0 0 0 1 0 246 rank value of 6.1s =0 1 0 0 0 1 0 0 0 0 0 0 0 249.5 rank value of 6.3s =0 0 0 0 0 0 0 0 1 0 0 0 0 251 rank value of 6.4s =1 0 0 0 1 0 0 0 0 0 0 0 0 252.5 rank value of 6.5s =0 0 0 0 0 0 0 0 0 0 0 1 0 254 rank value of 6.7s =1 0 0 0 1 0 0 0 0 0 0 0 0 255.5 rank value of 6.8s =0 0 0 0 1 0 0 0 0 0 0 0 0 257 rank value of 6.9s =0 0 0 0 0 0 0 0 0 0 1 0 0 258 rank value of 7.1s =0 0 0 0 0 0 0 0 0 0 1 0 0 259 rank value of 7.2s =1 0 0 0 0 0 0 0 1 0 0 0 0 260.5 rank value of 7.3s =0 0 0 0 0 1 0 0 0 0 0 0 0 262 rank value of 7.4s =1 0 0 0 0 0 0 0 1 0 0 0 0 263.5 rank value of 7.5s =0 0 0 0 1 0 0 0 0 0 0 0 0 265 rank value of 7.6s =0 0 0 0 0 0 1 0 0 0 0 0 0 266 rank value of 7.9s =1 0 0 0 0 0 0 0 0 0 0 0 0 267 rank value of 8.3s =0 0 1 0 0 0 0 0 0 0 0 0 0 268 rank value of 8.4s =0 1 0 0 0 0 0 0 0 0 0 0 0 269 rank value of 8.8s =0 0 0 0 0 0 0 0 1 0 0 0 0 270 rank value of 9.3s =0 0 0 0 1 0 0 0 0 0 0 0 0 271 rank value of 9.4s =0 0 0 1 0 0 0 0 0 0 0 0 0 272 rank value of 9.6s =1 0 0 1 0 0 0 0 0 0 0 0 0 273.5 rank value of 9.7s =0 0 0 0 0 0 0 0 0 0 1 0 0 275 rank value of 9.9s =1 0 0 0 0 0 0 0 0 0 0 0 0 276 rank value of 10s =0 1 0 0 0 0 0 0 0 0 0 0 0 277 rank value of 11s =1 0 0 0 0 0 0 0 0 0 0 0 0 278 rank value of 11.2s =0 0 0 0 0 1 0 0 0 0 0 0 0 279 rank value of 12s =2 0 0 1 0 0 0 0 0 0 0 0 0 281 rank value of 12.4s =0 0 0 0 0 0 0 1 0 0 0 0 0 283 rank value of 12.6s =1 0 0 0 0 0 0 0 0 0 0 0 0 284 rank value of 13s =0 0 0 0 0 1 0 2 0 0 0 0 0 286 rank value of 13.4s =1 0 0 0 0 0 0 0 0 0 0 0 0 288 rank value of 15s =1 0 0 0 0 0 0 0 0 0 0 0 0 289 rank value of 15.6s =1 0 0 0 0 0 0 0 0 0 0 0 0 290 rank value of 17s =1 0 0 0 0 0 0 0 0 0 1 0 0 291.5 rank value of 18s =2 0 0 0 0 0 0 0 0 0 0 0 0 293.5 rank value of 19.1s =1 0 0 0 0 0 0 0 0 0 0 0 0 295 rank value of 20s =1 0 0 0 0 0 0 0 1 0 0 0 0 296.5 rank value of 22s =0 0 0 0 0 0 0 0 0 1 0 0 0 298 rank value of 22.6s =0 0 1 0 0 0 0 0 0 0 0 0 0 299 rank value of 22.7s =1 0 0 0 0 0 0 0 0 0 0 0 0 300 rank value of 24s =1 0 0 0 0 0 0 0 0 0 0 0 0 301 rank value of 25s =0 0 0 0 0 0 0 0 0 0 1 0 0 302 rank value of 26s =1 0 0 0 0 0 0 1 0 0 1 0 0 304 rank value of 26.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 306 rank value of 27s =0 0 0 0 0 0 0 1 0 0 0 0 0 307 Copper (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 30 of 66 rank value of 28s =0 0 0 0 0 0 0 0 1 0 0 0 0 308 rank value of 29s =1 0 0 0 0 0 0 0 0 0 0 0 0 309 rank value of 29.2s =1 0 0 0 0 0 0 0 0 0 0 0 0 310 rank value of 31s =1 0 1 0 0 0 0 0 0 0 0 0 0 311.5 rank value of 38s =0 0 0 0 0 0 0 0 1 0 0 0 0 313 rank value of 40s =0 0 0 1 0 0 0 0 0 0 0 0 0 314 rank value of 40.3s =0 0 0 0 0 0 0 0 0 1 0 0 0 315 rank value of 42s =0 0 0 0 0 0 0 1 0 0 0 0 0 316 rank value of 47.4s =0 0 0 0 0 0 0 0 0 0 1 0 0 317 rank value of 53.9s =0 0 0 0 0 0 0 0 0 0 1 0 0 318 rank value of 63s =0 0 0 0 0 0 0 0 0 1 0 0 0 319 rank value of 68s =0 0 0 0 0 0 0 0 1 0 0 0 0 320 rank value of 69s =1 0 0 0 0 0 0 0 0 0 0 0 0 321 rank value of 70s =0 0 0 1 0 0 0 0 0 0 0 0 0 322 rank value of 71s =0 0 0 0 0 0 0 0 0 0 1 0 0 323 rank value of 77s =1 0 0 0 0 0 0 0 0 0 0 0 0 324 rank value of 82s =0 0 0 0 0 0 0 0 0 1 0 0 0 325 rank value of 85s =0 0 0 0 0 0 0 0 1 0 0 0 0 326 rank value of 88s =0 0 0 0 0 0 0 0 1 0 0 0 0 327 rank value of 89s =0 0 0 0 0 0 0 0 0 0 1 0 0 328 rank value of 94s =0 0 0 0 0 0 0 0 0 1 0 0 0 329 rank value of 96s =0 0 0 0 0 0 0 0 0 0 1 0 0 330 rank value of 100s =0 0 0 0 0 0 0 0 0 1 0 0 0 331 rank value of 110s =0 0 0 0 0 0 0 0 0 1 0 0 0 332 rank value of 120s =0 0 0 0 0 0 0 0 0 2 0 0 0 333.5 rank value of 130s =0 0 0 0 0 0 0 0 0 0 1 0 0 335 rank value of 140s =0 0 0 0 0 0 0 0 0 0 1 0 0 336 rank value of 150s =0 0 0 0 0 0 0 0 0 1 1 0 0 337.5 rank value of 220s =0 0 0 1 0 0 0 0 0 0 0 0 0 339 rank value of 240s =0 0 0 1 0 0 0 0 0 0 0 0 0 340 rank value of 330s =0 0 0 0 0 1 0 0 0 0 0 0 0 341 rank value of 450s =0 0 0 0 0 0 0 0 0 0 1 0 0 342 n =32 31 26 30 30 30 28 28 29 30 26 11 11 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SK i=1 (Ri 2)/Ni]} -3(N+1) Well = Background MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Ri2/Ni = 3103644.9 798538 724786 841855 423489 696940 949707 1E+06 1E+06 199396 130691 Ni bg = 89 N = 342 H = 26.74 Adjust H for ties: Ti =1E+07 sum of T1..T24 H' = H/(1-(Ti/(N3-N))) H' =35.91 Chi-square =18.31 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 17df at the 5% significance level from Table 1 of the IFG. The value is 18.31 which is less than H' =35.91. Copper (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 31 of 66 Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Rbar (well x) = 163.2 155.4 167.5 123.0 157.8 181.0 189.3 230.1 134.6 109.0 avg Rbar (background) = 186.7 186.7 186.7 186.7 186.7 186.7 186.7 186.7 186.7 186.7 Dx = -23.6 -31.3 -19.2 -63.8 -29.0 -5.8 2.6 43.3 -52.1 -77.7 Cx = 48.6 48.6 48.6 49.9 49.9 49.3 48.6 51.4 73.6 73.6 Statistical Significance ? No No No No No No No No No No If SSI, is current event above MCL?---------- Compare each difference (Dx) with the corresponding critical value (Cx). No compliance well's difference between average ranks exceeded its corresponding critical value at a 5% significance level. Therefore, we conclude that significant evidence of contamination does not exist at the 5% significance level. Copper (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 32 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Lead NC MCL (mg/l):15 Method:Kruskal-Wallis Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 35 NS NS ND ND ND ND 11 ND ND NS NP NP 10 06/26/00 ND 10 NS NS NS NS NS NS NS NS NS NP NP 10 07/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 10 09/18/00 NS NS NS NT NT NS NS NS ND NS NS NP NP 10 04/09/01 ND 59 NS ND ND ND ND ND 18 2.5 NS NP NP 10 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 04/15/02 13 ND NS ND ND ND ND ND 13 29 NS NP NP 10 09/26/02 ND 76 29 ND ND ND ND ND 150 20 740 NP NP 10 04/28/03 ND ND ND ND ND ND ND ND 25 ND 300 NP NP 10 10/30/03 8.7 12 NT ND ND ND ND ND 39 7.4 640 NP NP 5 04/20/04 7.2 7 5.2 6.4 5.4 ND ND ND 12 39 250 NP NP 5 10/21/04 7.2 5.6 5.7 ND ND ND ND ND ND 24 430 NP NP 5 04/18/05 13 8 5.2 73 ND ND ND ND ND 39 380 NP NP 5 10/13/05 14 6.9 ND 20 ND ND ND ND ND 29 290 NP NP 5 04/25/06 15 ND ND ND ND ND ND ND 53 19 300 NP NP 10 10/20/06 20 ND ND ND ND ND ND ND 32 ND 89 NP NP 5 04/25/07 ND ND ND ND ND 96 ND ND ND ND 69 NP NP 10 10/31/07 17.5 8.1 ND ND ND ND ND ND ND 12.3 123 NP NP 5 04/23/08 ND ND 8.4 ND ND ND ND ND 5.8 ND 50.2 NP NP 5 10/20/08 ND 13.5 7.6 ND ND ND ND ND ND ND 25.9 NP NP 5 04/22/09 ND 8.7 24.4 ND ND ND ND ND 9.8 ND NS NP NP 5 10/26/09 ND ND ND ND ND ND NS NS NS ND 24.7 NP NP 5 04/22/10 ND 10.5 ND ND ND ND NS NS ND ND 9.2 NP NP 5 10/27/10 ND ND ND ND ND ND ND ND ND ND 16 ND ND 5 04/29/11 ND ND ND ND ND ND ND ND ND ND 11 ND ND 5 10/25/11 ND ND ND ND ND ND 6.3 ND ND ND 14.6 ND ND 5 04/20/12 ND ND ND ND ND ND ND ND ND ND 6.4 ND ND 5 10/24/12 5.9 ND ND ND ND ND ND ND ND ND ND ND ND 5 04/24/13 ND ND ND ND ND ND ND ND ND ND 10.4 ND ND 5 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/24/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/28/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/27/15 7.7 ND ND ND ND ND ND ND ND ND ND ND ND 5 Ni 32 31 26 30 30 30 28 28 30 30 26 11 11 sum of rank values (Ri)6210.5 6050.0 4534.0 4507.5 4126.0 4190.0 3865.0 3885.5 5749.5 5724.0 7228.0 1463.0 1463.0 avg rank value (Rbar)194.1 195.2 174.4 150.3 137.5 139.7 138.0 138.8 191.7 190.8 278.0 133.0 133.0 Number of each rank value Rank Value rank value of NDs =20 19 19 27 29 29 27 27 20 20 6 11 11 133 rank value of 2.5s =0 0 0 0 0 0 0 0 0 1 0 0 0 266 rank value of 5.2s =0 0 2 0 0 0 0 0 0 0 0 0 0 267.5 rank value of 5.4s =0 0 0 0 1 0 0 0 0 0 0 0 0 269 rank value of 5.6s =0 1 0 0 0 0 0 0 0 0 0 0 0 270 rank value of 5.7s =0 0 1 0 0 0 0 0 0 0 0 0 0 271 Lead (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 33 of 66 rank value of 5.8s =0 0 0 0 0 0 0 0 1 0 0 0 0 272 rank value of 5.9s =1 0 0 0 0 0 0 0 0 0 0 0 0 273 rank value of 6.3s =0 0 0 0 0 0 1 0 0 0 0 0 0 274 rank value of 6.4s =0 0 0 1 0 0 0 0 0 0 1 0 0 275.5 rank value of 6.9s =0 1 0 0 0 0 0 0 0 0 0 0 0 277 rank value of 7s =0 1 0 0 0 0 0 0 0 0 0 0 0 278 rank value of 7.2s =2 0 0 0 0 0 0 0 0 0 0 0 0 279.5 rank value of 7.4s =0 0 0 0 0 0 0 0 0 1 0 0 0 281 rank value of 7.6s =0 0 1 0 0 0 0 0 0 0 0 0 0 282 rank value of 7.7s =1 0 0 0 0 0 0 0 0 0 0 0 0 283 rank value of 8s =0 1 0 0 0 0 0 0 0 0 0 0 0 284 rank value of 8.1s =0 1 0 0 0 0 0 0 0 0 0 0 0 285 rank value of 8.4s =0 0 1 0 0 0 0 0 0 0 0 0 0 286 rank value of 8.7s =1 1 0 0 0 0 0 0 0 0 0 0 0 287.5 rank value of 9.2s =0 0 0 0 0 0 0 0 0 0 1 0 0 289 rank value of 9.8s =0 0 0 0 0 0 0 0 1 0 0 0 0 290 rank value of 10s =0 1 0 0 0 0 0 0 0 0 0 0 0 291 rank value of 10.4s =0 0 0 0 0 0 0 0 0 0 1 0 0 292 rank value of 10.5s =0 1 0 0 0 0 0 0 0 0 0 0 0 293 rank value of 11s =0 0 0 0 0 0 0 1 0 0 1 0 0 294.5 rank value of 12s =0 1 0 0 0 0 0 0 1 0 0 0 0 296.5 rank value of 12.3s =0 0 0 0 0 0 0 0 0 1 0 0 0 298 rank value of 13s =2 0 0 0 0 0 0 0 1 0 0 0 0 300 rank value of 13.5s =0 1 0 0 0 0 0 0 0 0 0 0 0 302 rank value of 14s =1 0 0 0 0 0 0 0 0 0 0 0 0 303 rank value of 14.6s =0 0 0 0 0 0 0 0 0 0 1 0 0 304 rank value of 15s =1 0 0 0 0 0 0 0 0 0 0 0 0 305 rank value of 16s =0 0 0 0 0 0 0 0 0 0 1 0 0 306 rank value of 17.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 307 rank value of 18s =0 0 0 0 0 0 0 0 1 0 0 0 0 308 rank value of 19s =0 0 0 0 0 0 0 0 0 1 0 0 0 309 rank value of 20s =1 0 0 1 0 0 0 0 0 1 0 0 0 311 rank value of 24s =0 0 0 0 0 0 0 0 0 1 0 0 0 313 rank value of 24.4s =0 0 1 0 0 0 0 0 0 0 0 0 0 314 rank value of 24.7s =0 0 0 0 0 0 0 0 0 0 1 0 0 315 rank value of 25s =0 0 0 0 0 0 0 0 1 0 0 0 0 316 rank value of 25.9s =0 0 0 0 0 0 0 0 0 0 1 0 0 317 rank value of 29s =0 0 1 0 0 0 0 0 0 2 0 0 0 319 rank value of 32s =0 0 0 0 0 0 0 0 1 0 0 0 0 321 rank value of 35s =1 0 0 0 0 0 0 0 0 0 0 0 0 322 rank value of 39s =0 0 0 0 0 0 0 0 1 2 0 0 0 324 rank value of 50.2s =0 0 0 0 0 0 0 0 0 0 1 0 0 326 rank value of 53s =0 0 0 0 0 0 0 0 1 0 0 0 0 327 rank value of 59s =0 1 0 0 0 0 0 0 0 0 0 0 0 328 rank value of 69s =0 0 0 0 0 0 0 0 0 0 1 0 0 329 rank value of 73s =0 0 0 1 0 0 0 0 0 0 0 0 0 330 rank value of 76s =0 1 0 0 0 0 0 0 0 0 0 0 0 331 rank value of 89s =0 0 0 0 0 0 0 0 0 0 1 0 0 332 rank value of 96s =0 0 0 0 0 1 0 0 0 0 0 0 0 333 rank value of 123s =0 0 0 0 0 0 0 0 0 0 1 0 0 334 rank value of 150s =0 0 0 0 0 0 0 0 1 0 0 0 0 335 rank value of 250s =0 0 0 0 0 0 0 0 0 0 1 0 0 336 rank value of 290s =0 0 0 0 0 0 0 0 0 0 1 0 0 337 rank value of 300s =0 0 0 0 0 0 0 0 0 0 2 0 0 338.5 rank value of 380s =0 0 0 0 0 0 0 0 0 0 1 0 0 340 rank value of 430s =0 0 0 0 0 0 0 0 0 0 1 0 0 341 rank value of 640s =0 0 0 0 0 0 0 0 0 0 1 0 0 342 rank value of 740s =0 0 0 0 0 0 0 0 0 0 1 0 0 343 Lead (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 34 of 66 n =32 31 26 30 30 30 28 28 30 30 26 11 11 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SK i=1 (Ri 2)/Ni]} -3(N+1) Well = Background MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Ri2/Ni = 3169159.9 677252 567463 585203 533508 539183 1E+06 1E+06 2E+06 194579 194579 Ni bg = 89 N = 343 H = 52.58 Adjust H for ties: Ti =2E+07 sum of T1..T12 H' = H/(1-(Ti/(N3-N))) H' =97.59 Chi-square =18.31 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 17df at the 5% significance level from Table 1 of the IFG. The value is 18.31 which is less than H' =97.59. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Rbar (well x) = 150.3 137.5 139.7 138.0 138.8 191.7 190.8 278.0 133.0 133.0 avg Rbar (background) = 188.7 188.7 188.7 188.7 188.7 188.7 188.7 188.7 188.7 188.7 Dx = -38.5 -51.2 -49.0 -50.7 -49.9 2.9 2.1 89.3 -55.7 -55.7 Cx = 48.8 48.8 48.8 50.1 50.1 48.8 48.8 51.5 73.8 73.8 Statistical Significance ? No No No No No No No Yes No No If SSI, is current event above MCL?-------No -- Compare each difference (Dx) with the corresponding critical value (Cx). The Dx value for the above indicated wells do exceed the corresponding Cx value. Therefore, we conclude that the concentration of Total Lead averaged over these compliance wells are significantly greater than that of the background wells. Shewart-CUSUM Control Charts should be performed for each failing well to check for statistical significance. Lead (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 35 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Lead NC MCL (mg/l):15 Method:Shewhart-CUSUM Control Chart Part 1: Check for Normality MW - 1 5 MD L 9/26/02 740 10 4/28/03 300 10 10/30/03 640 5 4/20/04 250 5 10/21/04 430 5 4/18/05 380 5 10/13/05 290 5 4/25/06 300 10 10/20/06 89 5 4/25/07 69 10 10/31/07 123 5 4/23/08 50.2 5 10/20/08 25.9 5 4/22/09 NS 5 10/26/09 24.7 5 4/22/10 9.2 5 10/27/10 16 5 4/29/11 11 5 10/25/11 14.6 5 4/20/12 6.4 5 10/24/12 ND 5 4/24/13 10.4 5 10/24/13 ND 5 4/24/14 ND 5 10/27/14 ND 5 4/28/15 ND 5 10/27/15 ND 5 If not detected (ND), use half of the detection limit. Xbar =145.93846 SD =208.98081 N =26 1/NSi(Xi-Xbar)3 =13076703 g1=1.5195992 Since the Coefficient of Skewness of 1.52 is greater than 1.0, the real data appear to be significantly skewed. Do not assume that the data follow a Normal distribution. Perform the Skewness Test on the natural log of the values. Xbar =3.5134434 SD =2.0115794 N =26 1/NSi(Xi-Xbar)3 =0.4976688 g1=0.0648454 Since the Coefficient of Skewness of 0.06 is less than 1.0, the data appear not to be significantly skewed. Pb (S-C MW-15) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 36 of 66 Proceed with further statistical tests using the log-transformed values shown above. Part 2: Shewhart-CUSUM Control Chart Compute the mean and standard deviation of the historical data: 5.9588727 = xmean (Mean of N1-N8 historical data) 0.394346 = s (Standard Deviation of N1-N8 historical data) 1 = k (constant, reference value) 5 = h (constant, upper control limit for the CUSUM scheme) 4.5 = SCL (Constant, upper Shewhart Control Limit) Compute the standardized mean (Zi) and the cumulative sum (Si) for each concentration. Date xi Zi Si h SCL 0 10/20/06 4.4886364 -3.7282898 0 5 4.5 4/25/07 4.2341065 -4.3737378 0 5 4.5 10/31/07 4.8121844 -2.9078226 0 5 4.5 4/23/08 3.916015 -5.1803681 0 5 4.5 10/20/08 3.254243 -6.8585187 0 5 4.5 10/26/09 3.2068032 -6.9788185 0 5 4.5 4/22/10 2.2192035 -9.4832172 0 5 4.5 10/27/10 2.7725887 -8.0799187 0 5 4.5 4/29/11 2.3978953 -9.0300828 0 5 4.5 10/25/11 2.6810215 -8.3121188 0 5 4.5 4/20/12 1.856298 -10.403489 0 5 4.5 10/24/12 0.9162907 -12.787201 0 5 4.5 4/24/13 2.3418058 -9.1723169 0 5 4.5 10/24/13 0.9162907 -12.787201 0 5 4.5 4/24/14 0.9162907 -12.787201 0 5 4.5 10/27/14 0.9162907 -12.787201 0 5 4.5 4/28/15 0.9162907 -12.787201 0 5 4.5 10/27/15 0.9162907 -12.787201 0 5 4.5 Plot Zi and Si versus time: Compare the Zi and Si values to their respective control limits of SCL and h. The limits were not exceeded and do not indicate statistically significant evidence of contamination at the site. -14 -12 -10 -8 -6 -4 -2 0 2 4 6 5/ 2 8 / 0 5 10 / 1 0 / 0 6 2/ 2 2 / 0 8 7/ 6 / 0 9 11 / 1 8 / 1 0 4/ 1 / 1 2 8/ 1 4 / 1 3 12 / 2 7 / 1 4 5/ 1 0 / 1 6 St a n d a r d i z e d U n i t s Combined Shewart-CUSUM Control Chart Zi SCL Si h Pb (S-C MW-15) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 37 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Nickel NC MCL (mg/l):100 Method:Kruskal-Wallis Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D r MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 15 NS NS 17 12 8.3 ND 24 6.7 22 NS NP NP 5 06/26/00 15 ND NS NS NS NS NS NS NS NS NS NP NP 5 07/26/00 16 9.7 NS NS NS NS NS NS NS NS NS NP NP 5 09/18/00 NS NS NS 8.8 NT NS NS NS NT NS NS NP NP 50 04/09/01 76 7.2 NS 9.6 5.3 ND ND 18 28 6.1 NS NP NP 5 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 50 04/15/02 74 ND NS ND ND ND 6 9 44 68 NS NP NP 5 09/26/02 16 6.8 31 400 ND ND ND 27 40 78 430 NP NP 5 04/28/03 ND ND ND 90 ND ND ND ND ND 26 70 NP NP 5 10/30/03 19 ND NT 6.9 6.9 ND ND ND 48 ND 190 NP NP 5 04/20/04 20 ND ND 30 7.3 ND ND 12 5.3 49 110 NP NP 5 10/21/04 12 ND ND 13 ND ND ND ND ND 35 160 NP NP 5 04/18/05 29 9.6 17 460 ND ND 5.5 5.4 ND 59 170 NP NP 5 10/13/05 29 ND ND 160 6.8 ND ND 6.1 ND 46 100 NP NP 5 04/25/06 ND ND ND ND ND ND ND ND ND ND 88 NP NP 50 10/20/06 22 ND 8.3 25 ND ND ND ND 13 ND 24 NP NP 5 04/25/07 ND ND ND ND ND 330 ND ND ND ND ND NP NP 50 10/31/07 24 ND 8 8.4 13.8 ND 5.8 9.8 ND 20.2 36.2 NP NP 5 04/23/08 7.3 ND 12.9 6.3 10.8 5.7 ND 11.3 5.3 ND 19 NP NP 5 10/20/08 23 ND 21 11.1 10.7 7.5 ND 14 ND ND 8.5 NP NP 5 04/22/09 5.6 7.2 19.7 16.7 10.9 6 5.1 14 6 ND NS NP NP 5 10/26/09 6.7 ND 5.2 6 18 7.5 NS NS NS 6 8.4 NP NP 5 04/22/10 8.6 9.6 7.6 ND 6.2 ND NS NS ND ND ND NP NP 5 10/27/10 7 ND ND ND 7.4 ND 21.5 19 ND ND 7.5 10.8 ND 5 04/29/11 ND ND ND ND 10.5 8.6 19.5 15.2 ND ND ND 10.3 ND 5 10/25/11 6.9 ND ND 14.7 8.8 7.5 20.8 19.9 ND ND ND 8 ND 5 04/20/12 12.2 ND ND ND 9.4 9.4 23.8 24.6 ND ND ND 19.3 ND 5 10/24/12 18.5 ND ND ND 10.1 8.9 20 25.3 ND ND ND 9.6 ND 5 04/24/13 10 ND ND ND 12 8.6 21.8 32.8 ND ND ND 9.2 ND 5 10/24/13 7.9 ND 8.3 ND 7.5 7 30.2 29.9 ND ND ND 12.1 ND 5 04/24/14 7 ND ND ND 9.3 10.1 23.6 33.9 ND ND ND 12.5 ND 5 10/27/14 ND ND ND ND 10.7 10.1 29.5 31.4 ND ND ND 9.1 ND 5 04/28/15 6.3 ND 5.6 6.8 11.7 11.2 25.1 35.4 ND ND ND 8.3 5.1 5 10/27/15 21.3 ND ND ND 12.6 12.6 24.4 33.4 ND 5.9 ND 8.7 ND 5 Ni 32 31 26 31 30 30 28 28 29 30 26 11 11 sum of rank values (Ri)7209.5 3266.0 3770.5 5708.0 5607.5 4663.0 4957.5 6498.0 3818.5 4794.5 5166.0 2576.5 960.5 avg rank value (Rbar)225.3 105.4 145.0 184.1 186.9 155.4 177.1 232.1 131.7 159.8 198.7 234.2 87.3 Number of each rank value Rank Value rank value of NDs =5 25 15 13 8 14 13 6 20 18 12 0 10 80 rank value of 5.1s =0 0 0 0 0 0 1 0 0 0 0 0 1 160.5 rank value of 5.2s =0 0 1 0 0 0 0 0 0 0 0 0 0 162 rank value of 5.3s =0 0 0 0 1 0 0 0 2 0 0 0 0 164 rank value of 5.4s =0 0 0 0 0 0 0 1 0 0 0 0 0 166 Nickel (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 38 of 66 rank value of 5.5s =0 0 0 0 0 0 1 0 0 0 0 0 0 167 rank value of 5.6s =1 0 1 0 0 0 0 0 0 0 0 0 0 168.5 rank value of 5.7s =0 0 0 0 0 1 0 0 0 0 0 0 0 170 rank value of 5.8s =0 0 0 0 0 0 1 0 0 0 0 0 0 171 rank value of 5.9s =0 0 0 0 0 0 0 0 0 1 0 0 0 172 rank value of 6s =0 0 0 1 0 1 0 0 1 1 0 0 0 174.5 rank value of 6.1s =0 0 0 0 0 0 0 1 0 1 0 0 0 177.5 rank value of 6.2s =0 0 0 0 1 0 1 0 0 0 0 0 0 179.5 rank value of 6.3s =1 0 0 1 0 0 0 0 0 0 0 0 0 181.5 rank value of 6.7s =1 0 0 0 0 0 0 0 1 0 0 0 0 183.5 rank value of 6.8s =0 1 0 1 1 0 0 0 0 0 0 0 0 186 rank value of 6.9s =1 0 0 1 1 0 0 0 0 0 0 0 0 189 rank value of 7s =2 0 0 0 0 1 0 0 0 0 0 0 0 192 rank value of 7.2s =0 2 0 0 0 0 0 0 0 0 0 0 0 194.5 rank value of 7.3s =1 0 0 0 1 0 0 0 0 0 0 0 0 196.5 rank value of 7.4s =0 0 0 0 1 0 0 0 0 0 0 0 0 198 rank value of 7.5s =0 0 0 0 1 3 0 0 0 0 1 0 0 201 rank value of 7.6s =0 0 1 0 0 0 0 0 0 0 0 0 0 204 rank value of 7.9s =1 0 0 0 0 0 0 0 0 0 0 0 0 205 rank value of 8s =0 0 1 0 0 0 0 0 0 0 0 1 0 206.5 rank value of 8.3s =0 0 2 0 0 1 0 0 0 0 0 1 0 209.5 rank value of 8.4s =0 0 0 1 0 0 0 0 0 0 1 0 0 212.5 rank value of 8.5s =0 0 0 0 0 0 0 0 0 0 1 0 0 214 rank value of 8.6s =1 0 0 0 0 2 0 0 0 0 0 0 0 216 rank value of 8.7s =0 0 0 0 0 0 0 0 0 0 0 1 0 218 rank value of 8.8s =0 0 0 1 1 0 0 0 0 0 0 0 0 219.5 rank value of 8.9s =0 0 0 0 0 1 0 0 0 0 0 0 0 221 rank value of 9.1s =0 0 0 0 0 0 0 0 0 0 0 1 0 222 rank value of 9.2s =0 0 0 0 0 0 0 1 0 0 0 1 0 223.5 rank value of 9.3s =0 0 0 0 1 0 0 0 0 0 0 0 0 225 rank value of 9.4s =0 0 0 0 1 1 0 0 0 0 0 0 0 226.5 rank value of 9.6s =0 2 0 1 0 0 0 0 0 0 0 1 0 229.5 rank value of 9.7s =0 1 0 0 0 0 0 0 0 0 0 0 0 232 rank value of 9.8s =0 0 0 0 0 0 0 1 0 0 0 0 0 233 rank value of 10s =1 0 0 0 0 0 0 0 0 0 0 0 0 234 rank value of 10.1s =0 0 0 0 1 2 0 0 0 0 0 0 0 236 rank value of 10.3s =0 0 0 0 0 0 0 0 0 0 0 1 0 238 rank value of 10.5s =0 0 0 0 1 0 0 0 0 0 0 0 0 239 rank value of 10.7s =0 0 0 0 2 0 0 0 0 0 0 0 0 240.5 rank value of 10.8s =0 0 0 0 1 0 0 0 0 0 0 1 0 242.5 rank value of 10.9s =0 0 0 0 1 0 0 0 0 0 0 0 0 244 rank value of 11.1s =0 0 0 1 0 0 0 0 0 0 0 0 0 245 rank value of 11.2s =0 0 0 0 0 1 0 0 0 0 0 0 0 246 rank value of 11.3s =0 0 0 0 0 0 0 1 0 0 0 0 0 247 rank value of 11.7s =0 0 0 0 1 0 0 0 0 0 0 0 0 248 rank value of 12s =1 0 0 0 2 0 0 1 0 0 0 0 0 250.5 rank value of 12.1s =0 0 0 0 0 0 0 0 0 0 0 1 0 253 rank value of 12.2s =1 0 0 0 0 0 0 0 0 0 0 0 0 254 rank value of 12.5s =0 0 0 0 0 0 0 0 0 0 0 1 0 255 rank value of 12.6s =0 0 0 0 1 1 0 0 0 0 0 0 0 256.5 rank value of 12.9s =0 0 1 0 0 0 0 0 0 0 0 0 0 258 rank value of 13s =0 0 0 1 0 0 0 0 1 0 0 0 0 259.5 rank value of 13.8s =0 0 0 0 1 0 0 0 0 0 0 0 0 261 rank value of 14s =0 0 0 0 0 0 0 2 0 0 0 0 0 262.5 rank value of 14.7s =0 0 0 1 0 0 0 0 0 0 0 0 0 264 rank value of 15s =2 0 0 0 0 0 0 0 0 0 0 0 0 265.5 rank value of 15.2s =0 0 0 0 0 0 0 1 0 0 0 0 0 267 rank value of 16s =2 0 0 0 0 0 0 0 0 0 0 0 0 268.5 rank value of 16.7s =0 0 0 1 0 0 0 0 0 0 0 0 0 270 Nickel (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 39 of 66 rank value of 17s =0 0 1 1 0 0 0 0 0 0 0 0 0 271.5 rank value of 18s =0 0 0 0 1 0 0 1 0 0 0 0 0 273.5 rank value of 18.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 275 rank value of 19s =1 0 0 0 0 0 0 1 0 0 1 0 0 277 rank value of 19.3s =0 0 0 0 0 0 0 0 0 0 0 1 0 279 rank value of 19.5s =0 0 0 0 0 0 1 0 0 0 0 0 0 280 rank value of 19.7s =0 0 1 0 0 0 0 0 0 0 0 0 0 281 rank value of 19.9s =0 0 0 0 0 0 0 1 0 0 0 0 0 282 rank value of 20s =1 0 0 0 0 0 1 0 0 0 0 0 0 283.5 rank value of 20.2s =0 0 0 0 0 0 0 0 0 1 0 0 0 285 rank value of 20.8s =0 0 0 0 0 0 1 0 0 0 0 0 0 286 rank value of 21s =0 0 1 0 0 0 0 0 0 0 0 0 0 287 rank value of 21.3s =1 0 0 0 0 0 0 0 0 0 0 0 0 288 rank value of 21.5s =0 0 0 0 0 0 1 0 0 0 0 0 0 289 rank value of 21.8s =0 0 0 0 0 0 1 0 0 0 0 0 0 290 rank value of 22s =1 0 0 0 0 0 0 0 0 1 0 0 0 291.5 rank value of 23s =1 0 0 0 0 0 0 0 0 0 0 0 0 293 rank value of 23.6s =0 0 0 0 0 0 1 0 0 0 0 0 0 294 rank value of 23.8s =0 0 0 0 0 0 1 0 0 0 0 0 0 295 rank value of 24s =1 0 0 0 0 0 0 1 0 0 1 0 0 297 rank value of 24.4s =0 0 0 0 0 0 1 0 0 0 0 0 0 299 rank value of 24.6s =0 0 0 0 0 0 0 1 0 0 0 0 0 300 rank value of 25s =0 0 0 1 0 0 0 0 0 0 0 0 0 301 rank value of 25.1s =0 0 0 0 0 0 1 0 0 0 0 0 0 302 rank value of 25.3s =0 0 0 0 0 0 0 1 0 0 0 0 0 303 rank value of 26s =0 0 0 0 0 0 0 0 0 1 0 0 0 304 rank value of 27s =0 0 0 0 0 0 0 1 0 0 0 0 0 305 rank value of 28s =0 0 0 0 0 0 0 0 1 0 0 0 0 306 rank value of 29s =2 0 0 0 0 0 0 0 0 0 0 0 0 307.5 rank value of 29.5s =0 0 0 0 0 0 1 0 0 0 0 0 0 309 rank value of 29.9s =0 0 0 0 0 0 0 1 0 0 0 0 0 310 rank value of 30s =0 0 0 1 0 0 0 0 0 0 0 0 0 311 rank value of 30.2s =0 0 0 0 0 0 1 0 0 0 0 0 0 312 rank value of 31s =0 0 1 0 0 0 0 0 0 0 0 0 0 313 rank value of 31.4s =0 0 0 0 0 0 0 1 0 0 0 0 0 314 rank value of 32.8s =0 0 0 0 0 0 0 1 0 0 0 0 0 315 rank value of 33.4s =0 0 0 0 0 0 0 1 0 0 0 0 0 316 rank value of 33.9s =0 0 0 0 0 0 0 1 0 0 0 0 0 317 rank value of 35s =0 0 0 0 0 0 0 0 0 1 0 0 0 318 rank value of 35.4s =0 0 0 0 0 0 0 1 0 0 0 0 0 319 rank value of 36.2s =0 0 0 0 0 0 0 0 0 0 1 0 0 320 rank value of 40s =0 0 0 0 0 0 0 0 1 0 0 0 0 321 rank value of 44s =0 0 0 0 0 0 0 0 1 0 0 0 0 322 rank value of 46s =0 0 0 0 0 0 0 0 0 1 0 0 0 323 rank value of 48s =0 0 0 0 0 0 0 0 1 0 0 0 0 324 rank value of 49s =0 0 0 0 0 0 0 0 0 1 0 0 0 325 rank value of 59s =0 0 0 0 0 0 0 0 0 1 0 0 0 326 rank value of 68s =0 0 0 0 0 0 0 0 0 1 0 0 0 327 rank value of 70s =0 0 0 0 0 0 0 0 0 0 1 0 0 328 rank value of 74s =1 0 0 0 0 0 0 0 0 0 0 0 0 329 rank value of 76s =1 0 0 0 0 0 0 0 0 0 0 0 0 330 rank value of 78s =0 0 0 0 0 0 0 0 0 1 0 0 0 331 rank value of 88s =0 0 0 0 0 0 0 0 0 0 1 0 0 332 rank value of 90s =0 0 0 1 0 0 0 0 0 0 0 0 0 333 rank value of 100s =0 0 0 0 0 0 0 0 0 0 1 0 0 334 rank value of 110s =0 0 0 0 0 0 0 0 0 0 1 0 0 335 rank value of 160s =0 0 0 1 0 0 0 0 0 0 1 0 0 336.5 rank value of 170s =0 0 0 0 0 0 0 0 0 0 1 0 0 338 rank value of 190s =0 0 0 0 0 0 0 0 0 0 1 0 0 339 Nickel (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 40 of 66 rank value of 330s =0 0 0 0 0 1 0 0 0 0 0 0 0 340 rank value of 400s =0 0 0 1 0 0 0 0 0 0 0 0 0 341 rank value of 430s =0 0 0 0 0 0 0 0 0 0 1 0 0 342 rank value of 460s =0 0 0 1 0 0 0 0 0 0 0 0 0 343 n =32 31 26 31 30 30 28 28 29 30 26 11 11 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SK i=1 (Ri 2)/Ni]} -3(N+1) Well = Background MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D r MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Ri2/Ni = 2280320.4 1E+06 1E+06 724786 877743 2E+06 502791 766241 1E+06 603487 83869 Ni bg = 89 N = 343 H = 33.11 Adjust H for ties: Ti =4E+06 sum of T1..T40 H' = H/(1-(Ti/(N3-N))) H' =36.77 Chi-square =18.31 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 17df at the 5% significance level from Table 1 of the IFG. The value is 18.31 which is less than H' =36.77. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D r MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Rbar (well x) = 184.1 186.9 155.4 177.1 232.1 131.7 159.8 198.7 234.2 87.3 avg Rbar (background) = 160.1 160.1 160.1 160.1 160.1 160.1 160.1 160.1 160.1 160.1 Dx = 24.1 26.8 -4.6 17.0 72.0 -28.4 -0.3 38.6 74.2 -72.7 Cx = 48.2 48.8 48.8 50.1 50.1 49.4 48.8 51.5 73.8 73.8 Statistical Significance ? No No No No Yes No No No Yes No If SSI, is current event above MCL?----No ---No - Compare each difference (Dx) with the corresponding critical value (Cx). The Dx value for the above indicated wells do exceed the corresponding Cx value. Therefore, we conclude that the concentration of Total Nickel averaged over these compliance wells are significantly greater than that of the background wells. Shewart-CUSUM Control Charts should be performed for each failing well to check for statistical significance. Nickel (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 41 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Nickel NC MCL (mg/l):100 Method:Shewhart-CUSUM Control Chart Part 1: Check for Normality MW - 3 D MD L 4/24/00 24 5 6/26/00 NS 5 7/26/00 NS 5 9/18/00 NS 50 4/9/01 18 5 9/18/01 NS 5 10/29/01 NS 5 1/30/02 NS 5 2/28/02 NS 50 4/15/02 9.2 5 9/26/02 27 5 4/28/03 ND 5 10/30/03 ND 5 4/20/04 12 5 10/21/04 ND 5 4/18/05 5.4 5 10/13/05 6.1 5 4/25/06 ND 50 10/20/06 ND 5 4/25/07 ND 50 10/31/07 9.8 5 4/23/08 11.3 5 10/20/08 14 5 4/22/09 14 5 10/26/09 NS 5 4/22/10 NS 5 10/27/10 19 5 4/29/11 15.2 5 10/25/11 19.9 5 4/20/12 24.6 5 10/24/12 25.3 5 4/24/13 32.8 5 10/24/13 29.9 5 4/24/14 33.9 5 10/27/14 31.4 5 4/28/15 35.4 5 10/27/15 33.4 5 If not detected (ND), use half of the detection limit. Xbar =18.271429 SD =10.842504 N =28 1/NSi(Xi-Xbar)3 =-17.04979 g1=0.0141261 Since the Coefficient of Skewness of 0.01 is less than 1.0, the data appear not to be significantly skewed. Proceed with further statistical tests using the real detected values shown above. Xbar =2.631252 SD =0.8722392 N =28 Ni (S-C) MW-3Dr 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 42 of 66 1/NSi(Xi-Xbar)3 =-0.589615 g1=0.9383241 Use the real values (not log-transformed) indicated in the previous section. Part 2: Shewhart-CUSUM Control Chart Compute the mean and standard deviation of the historical data: 12.2125 = xmean (Mean of N1-N8 historical data) 9.8794791 = s (Standard Deviation of N1-N8 historical data) 1 = k (constant, reference value) 5 = h (constant, upper control limit for the CUSUM scheme) 4.5 = SCL (Constant, upper Shewhart Control Limit) Compute the standardized mean (Zi) and the cumulative sum (Si) for each concentration. Date xi Zi Si h SCL 0 4/18/05 5.4 -0.6895606 0 5 4.5 10/13/05 6.1 -0.6187067 0 5 4.5 4/25/06 25 1.2943496 0.2943496 5 4.5 10/20/06 2.5 -0.9830984 0 5 4.5 4/25/07 25 1.2943496 0.2943496 5 4.5 10/31/07 9.8 -0.244193 0 5 4.5 4/23/08 11.3 -0.0923632 0 5 4.5 10/20/08 14 0.1809306 0 5 4.5 4/22/09 14 0.1809306 0 5 4.5 10/27/10 19 0.6870301 0 5 4.5 4/29/11 15.2 0.3023945 0 5 4.5 10/25/11 19.9 0.7781281 0 5 4.5 4/20/12 24.6 1.2538617 0.2538617 5 4.5 10/24/12 25.3 1.3247156 0.5785772 5 4.5 4/24/13 32.8 2.0838649 1.6624422 5 4.5 10/24/13 29.9 1.7903272 2.4527694 5 4.5 4/24/14 33.9 2.1952068 3.6479762 5 4.5 10/27/14 31.4 1.9421571 4.5901332 5 4.5 4/28/15 35.4 2.3470367 5.9371699 5 4.5 10/27/15 33.4 2.1445969 7.0817668 5 4.5 Plot Zi and Si versus time: Compare the Zi and Si values to their respective control limits of SCL and h. One, or both, of the control limits was exceeded. Therefore, there is statistically significant evidence of contamination in this well at the concentrations indicated above. -2 -1 0 1 2 3 4 5 6 7 8 1/ 1 4 / 0 4 5/ 2 8 / 0 5 10 / 1 0 / 0 6 2/ 2 2 / 0 8 7/ 6 / 0 9 11 / 1 8 / 1 0 4/ 1 / 1 2 8/ 1 4 / 1 3 12 / 2 7 / 1 4 5/ 1 0 / 1 6 St a n d a r d i z e d U n i t s Combined Shewart-CUSUM Control Chart Zi SCL Si h Ni (S-C) MW-3Dr 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 43 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Nickel NC MCL (mg/l):100 Method:Shewhart-CUSUM Control Chart Part 1: Check for Normality MW - 1 6 MD L 4/24/00 NP 5 6/26/00 NP 5 7/26/00 NP 5 9/18/00 NP 50 4/9/01 NP 5 9/18/01 NP 5 10/29/01 NP 5 1/30/02 NP 5 2/28/02 NP 50 4/15/02 NP 5 9/26/02 NP 5 4/28/03 NP 5 10/30/03 NP 5 4/20/04 NP 5 10/21/04 NP 5 4/18/05 NP 5 10/13/05 NP 5 4/25/06 NP 50 10/20/06 NP 5 4/25/07 NP 50 10/31/07 NP 5 4/23/08 NP 5 10/20/08 NP 5 4/22/09 NP 5 10/26/09 NP 5 4/22/10 NP 5 10/27/10 10.8 5 4/29/11 10.3 5 10/25/11 8 5 4/20/12 19.3 5 10/24/12 9.6 5 4/24/13 9.2 5 10/24/13 12.1 5 4/24/14 12.5 5 10/27/14 9.1 5 4/28/15 8.3 5 10/27/15 8.7 5 If not detected (ND), use half of the detection limit. Xbar =10.718182 SD =3.1999432 N =11 Ni (S-C) MW-16 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 44 of 66 1/NSi(Xi-Xbar)3 =53.51588 g1=1.8842776 Since the Coefficient of Skewness of 1.88 is greater than 1.0, the real data appear to be significantly skewed. Do not assume that the data follow a Normal distribution. Perform the Skewness Test on the natural log of the values. Xbar =2.3399082 SD =0.2512677 N =11 1/NSi(Xi-Xbar)3 =0.0190686 g1=1.3867494 Since the Coefficient of Skewness of 1.39 is greater than 1.0, the data appear to be significantly skewed. Do not assume that the data follow a Normal distribution. A non-parametric testing procedure should be used on the data set. Ni (S-C) MW-16 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 45 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Nickel GA MCL (ug/l):100 Method:Kendall-Mann Non-Parametric Trend Test (Concentration vs. Time) Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 15 NS NS 17 12 8.3 ND 24 6.7 22 NS NP NP 5 06/26/00 15 ND NS NS NS NS NS NS NS NS NS NP NP 5 07/26/00 16 9.7 NS NS NS NS NS NS NS NS NS NP NP 5 09/18/00 NS NS NS 8.8 NT NS NS NS NT NS NS NP NP 50 04/09/01 76 7.2 NS 9.6 5.3 ND ND 18 28 6.1 NS NP NP 5 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 50 04/15/02 74 ND NS ND ND ND 6.2 9.2 44 68 NS NP NP 5 09/26/02 16 6.8 31 400 ND ND ND 27 40 78 430 NP NP 5 04/28/03 ND ND ND 90 ND ND ND ND ND 26 70 NP NP 5 10/30/03 19 ND NT 6.9 6.9 ND ND ND 48 ND 190 NP NP 5 04/20/04 20 ND ND 30 7.3 ND ND 12 5.3 49 110 NP NP 5 10/21/04 12 ND ND 13 ND ND ND ND ND 35 160 NP NP 5 04/18/05 29 9.6 17 460 ND ND 5.5 5.4 ND 59 170 NP NP 5 10/13/05 29 ND ND 160 6.8 ND ND 6.1 ND 46 100 NP NP 5 04/25/06 ND ND ND ND ND ND ND ND ND ND 88 NP NP 50 10/20/06 22 ND 8.3 25 ND ND ND ND 13 ND 24 NP NP 5 04/25/07 ND ND ND ND ND 330 ND ND ND ND ND NP NP 50 10/31/07 24 ND 8 8.4 13.8 ND 5.8 9.8 ND 20.2 36.2 NP NP 5 04/23/08 7.3 ND 12.9 6.3 10.8 5.7 ND 11.3 5.3 ND 19 NP NP 5 10/20/08 23 ND 21 11.1 10.7 7.5 ND 14 ND ND 8.5 NP NP 5 04/22/09 5.6 7.2 19.7 16.7 10.9 6 5.1 14 6 ND NS NP NP 5 10/26/09 6.7 ND 5.2 6 18 7.5 NS NS NS 6 8.4 NP NP 5 04/22/10 8.6 9.6 7.6 ND 6.2 ND NS NS ND ND ND NP NP 5 10/27/10 7 ND ND ND 7.4 ND 21.5 19 ND ND 7.5 10.8 ND 5 04/29/11 ND ND ND ND 10.5 8.6 19.5 15.2 ND ND ND 10.3 ND 5 10/25/11 6.9 ND ND 14.7 8.8 7.5 20.8 19.9 ND ND ND 8 ND 5 04/20/12 12.2 ND ND ND 9.4 9.4 23.8 24.6 ND ND ND 19.3 ND 5 10/24/12 18.5 ND ND ND 10.1 8.9 20 25.3 ND ND ND 9.6 ND 5 04/24/13 10 ND ND ND 12 8.6 21.8 32.8 ND ND ND 9.2 ND 5 10/24/13 7.9 ND 8.3 ND 7.5 7 30.2 29.9 ND ND ND 12.1 ND 5 04/24/14 7 ND ND ND 9.3 10.1 23.6 33.9 ND ND ND 12.5 ND 5 10/27/14 ND ND ND ND 10.7 10.1 29.5 31.4 ND ND ND 9.1 ND 5 04/28/15 6.3 ND 5.6 6.8 11.7 11.2 25.1 35.4 ND ND ND 8.3 5.1 5 10/27/15 21.3 ND ND ND 12.6 12.6 24.4 33.4 ND 5.9 ND 8.7 ND 5 If not detected (ND), use half of the detection limit. Trendline Slope =---------0.001 - Standard Deviation =--------3.1999 - number of observations n =--------11 - S =---------15 - uncorrected for ties t =---------0.27 - U =--------0 - corrected for ties t =---------0.27 - Concentration Trend --------de c r e a s e - Nickel (K-M Trend) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 46 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Selenium MCL (mg/l):20 Method:Poisson Prediction Limits Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 ND NS NS ND ND ND ND ND ND ND NS NP NP 20 06/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 20 07/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 20 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 20 04/09/01 ND ND NS ND ND ND ND ND ND ND NS NP NP 20 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 20 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 20 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 20 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 20 04/15/02 ND ND NS ND ND ND ND ND ND ND NS NP NP 20 09/26/02 ND ND ND ND ND ND ND ND ND ND ND NP NP 20 04/28/03 ND ND ND ND ND ND ND ND ND ND ND NP NP 20 10/30/03 ND ND NT ND ND ND ND ND ND ND ND NP NP 5 04/20/04 ND ND ND ND ND 5 ND ND ND ND ND NP NP 5 10/21/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/18/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 10/13/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/25/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 20 10/20/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/25/07 12 ND ND ND ND 460 ND ND ND ND 18 NP NP 10 10/31/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/23/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/20/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/22/09 ND ND ND ND ND ND ND ND ND ND NS NP NP 10 10/26/09 ND ND ND ND ND ND NS NS NS ND ND NP NP 10 04/22/10 ND ND ND ND ND ND NS NS ND ND ND NP NP 10 10/27/10 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 04/29/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 10/25/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 04/20/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 10/24/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 04/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 04/24/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 04/28/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 10/27/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 31. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 86 Tn1 = 492 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =86 Tn1 = 492 t [85,.01] =2.3767 c =0.0116 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Tn2 = 5 5 5 5 5 5 5 5 5 5 T*k =11.5 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Selenium (PPL) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 47 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Silver MCL (mg/l):20 Method:Poisson Prediction Limits Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 3.7 NS NS ND ND ND 6.9 ND ND ND NS NP NP 2 06/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 2 07/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 2 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 10 04/09/01 ND ND NS ND ND ND ND ND ND ND NS NP NP 2 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 2 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 2 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 2 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 04/15/02 ND ND NS ND ND ND ND ND ND ND NS NP NP 2 09/26/02 ND ND ND ND ND ND ND ND ND ND ND NP NP 2 04/28/03 ND ND ND ND ND ND ND ND ND ND ND NP NP 2 10/30/03 ND ND NT ND ND ND ND ND ND ND ND NP NP 2 04/20/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 2 10/21/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 2 04/18/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 2 10/13/05 2.9 ND ND ND ND ND ND ND ND ND ND NP NP 2 04/25/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/20/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/25/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/31/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/23/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 10/20/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/22/09 ND ND ND ND ND ND ND ND ND ND NS NP NP 5 10/26/09 ND ND ND ND ND ND NS NS NS ND ND NP NP 5 04/22/10 ND ND ND ND ND ND NS NS ND ND ND NP NP 5 10/27/10 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/29/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/25/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/20/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/24/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/24/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/28/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/27/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 31. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 86 Tn1 = 191.1 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =86 Tn1 = 191.1 t [85,.01] =2.3767 c =0.0116 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Tn2 = 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 T*k =5.8 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Silver (PPL) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 48 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Thallium MCL (mg/l):Not Established Method:Poisson Prediction Limits Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 2 NS NS ND 3 2 4 ND 2 5 NS NP NP 2 06/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 2 07/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 2 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 20 04/09/01 40 ND NS ND ND ND ND ND ND ND NS NP NP 2 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 2 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 2 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 2 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 20 04/15/02 40 ND NS ND ND ND ND ND ND ND NS NP NP 2 09/26/02 ND ND ND ND ND ND ND ND ND ND 65 NP NP 2 04/28/03 ND ND ND 1.6 ND ND ND ND 1.4 ND 15 NP NP 1 10/30/03 ND ND NT ND ND ND ND ND ND ND ND NP NP 10 04/20/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/21/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/18/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/13/05 22 ND ND ND ND ND ND ND ND ND ND NP NP 10 04/25/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/20/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/25/07 ND ND ND ND ND 35 ND ND ND ND ND NP NP 5.5 10/31/07 11.6 ND ND ND ND ND ND ND ND 9.5 ND NP NP 5.5 04/23/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 5.5 10/20/08 7.2 ND ND ND ND ND ND 6.1 ND ND ND NP NP 5.4 04/22/09 ND ND ND ND ND ND ND ND ND ND NS NP NP 5.4 10/26/09 ND ND ND ND ND ND NS NS NS ND ND NP NP 5.4 04/22/10 ND ND ND ND ND ND NS NS ND ND ND NP NP 5.4 10/27/10 ND ND ND ND ND ND ND ND ND ND ND ND ND 5.4 04/29/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 5.4 10/25/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 5.4 04/20/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 5.4 10/24/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 5.4 04/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 5.4 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 5.4 04/24/14 ND ND ND ND ND ND ND ND ND ND ND 5.6 ND 5.4 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5.4 04/28/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 5.4 10/27/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 5.4 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 31. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 86 Tn1 = 361 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =86 Tn1 = 361 t [85,.01] =2.3767 c =0.0116 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Tn2 = 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 T*k =9.1 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Thallium (PPL) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 49 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Vanadium NC MCL (mg/l):Not Established Method:Kruskal-Wallis Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 17 NS NS 19 32 21 ND 29 8.9 78 NS NP NP 5 06/26/00 40 6.3 NS NS NS NS NS NS NS NS NS NP NP 5 07/26/00 45 ND NS NS NS NS NS NS NS NS NS NP NP 5 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 40 04/09/01 250 1.4 NS 13 19 9.3 ND 24 41 230 NS NP NP 5 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 40 04/15/02 240 ND NS ND ND 11 21 14 69 260 NS NP NP 5 09/26/02 58 16 44 640 ND ND ND 42 50 310 1000 NP NP 5 04/28/03 89 ND 9.6 170 6.8 6.8 ND ND 37 230 130 NP NP 5 10/30/03 54 ND NT 6.6 16 ND ND ND 92 14 200 NP NP 5 04/20/04 55 ND ND 45 25 ND ND 13 5.1 240 88 NP NP 5 10/21/04 41 ND ND 18 ND ND ND ND ND 160 210 NP NP 5 04/18/05 85 ND ND 680 5.4 ND ND ND ND 240 110 NP NP 5 10/13/05 82 ND ND 210 8.9 ND ND ND ND 170 82 NP NP 5 04/25/06 110 ND ND ND ND ND ND ND ND 120 85 NP NP 40 10/20/06 79 ND ND 28 ND ND ND ND 23 ND 30 NP NP 5 04/25/07 43 ND ND ND ND 300 ND ND ND ND 26 NP NP 25 10/31/07 89 ND 8.8 14.7 20 ND ND ND 8.6 103 48.2 NP NP 5 04/23/08 26.1 ND 11.4 9.7 10.1 ND ND 5.1 9.7 10 23.1 NP NP 5 10/20/08 79 ND 15.1 15.8 ND ND ND ND 5.4 ND 14.8 NP NP 5 04/22/09 16 ND 32.7 19.8 7.7 ND ND ND 13.3 ND NS NP NP 5 10/26/09 17.9 ND ND 5.3 33.6 ND NS NS NS 12.2 11.9 NP NP 5 04/22/10 27.9 ND ND ND ND ND NS NS ND ND ND NP NP 5 10/27/10 17.4 ND ND 6.9 ND ND 14.2 7.1 ND ND 5.9 ND ND 5 04/29/11 15.8 ND 5.1 ND ND ND ND ND ND ND 5.5 7.3 ND 5 10/25/11 25.6 ND ND 23 ND ND 15.1 ND ND 9.7 6.3 ND ND 5 04/20/12 44.3 ND ND ND ND ND 10 ND ND ND ND 15 ND 5 10/24/12 59 ND ND 5.9 ND ND ND ND ND ND ND ND ND 5 04/24/13 33.5 ND ND 7.7 9.6 ND ND ND ND ND 5.4 ND ND 5 10/24/13 30.4 ND ND ND ND ND ND ND ND ND ND ND ND 5 04/24/14 22.8 ND ND ND ND ND ND ND ND ND ND ND ND 5 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/28/15 15.5 ND ND 8 ND ND ND ND ND ND ND 7 ND 5 10/27/15 44.5 ND ND ND ND ND ND ND ND 7.4 ND 9.8 ND 5 Ni 32 31 26 30 30 30 28 28 29 30 26 11 11 sum of rank values (Ri)9236.0 3536.5 3690.0 6321.5 4848.5 3852.0 3465.5 3922.0 4881.5 6232.5 5895.0 1650.0 1122.0 avg rank value (Rbar)288.6 114.1 141.9 210.7 161.6 128.4 123.8 140.1 168.3 207.8 226.7 150.0 102.0 Number of each rank value Rank Value rank value of NDs =1 28 19 10 18 25 24 21 17 14 8 7 11 102 rank value of 1.4s =0 1 0 0 0 0 0 0 0 0 0 0 0 204 rank value of 5.1s =0 0 1 0 0 0 0 1 1 0 0 0 0 206 Vanadium (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 50 of 66 rank value of 5.3s =0 0 0 1 0 0 0 0 0 0 0 0 0 208 rank value of 5.4s =0 0 0 0 1 0 0 0 1 0 1 0 0 210 rank value of 5.5s =0 0 0 0 0 0 0 0 0 0 1 0 0 212 rank value of 5.9s =0 0 0 1 0 0 0 0 0 0 1 0 0 213.5 rank value of 6.3s =0 1 0 0 0 0 0 0 0 0 1 0 0 215.5 rank value of 6.6s =0 0 0 1 0 0 0 0 0 0 0 0 0 217 rank value of 6.8s =0 0 0 0 1 1 0 0 0 0 0 0 0 218.5 rank value of 6.9s =0 0 0 1 0 0 0 0 0 0 0 0 0 220 rank value of 7s =0 0 0 0 0 0 0 0 0 0 0 1 0 221 rank value of 7.1s =0 0 0 0 0 0 0 1 0 0 0 0 0 222 rank value of 7.3s =0 0 0 0 0 0 0 0 0 0 0 1 0 223 rank value of 7.4s =0 0 0 0 0 0 0 0 0 1 0 0 0 224 rank value of 7.7s =0 0 0 1 1 0 0 0 0 0 0 0 0 225.5 rank value of 8s =0 0 0 1 0 0 0 0 0 0 0 0 0 227 rank value of 8.6s =0 0 0 0 0 0 0 0 1 0 0 0 0 228 rank value of 8.8s =0 0 1 0 0 0 0 0 0 0 0 0 0 229 rank value of 8.9s =0 0 0 0 1 0 0 0 1 0 0 0 0 230.5 rank value of 9.3s =0 0 0 0 0 1 0 0 0 0 0 0 0 232 rank value of 9.6s =0 0 1 0 1 0 0 0 0 0 0 0 0 233.5 rank value of 9.7s =0 0 0 1 0 0 0 0 1 1 0 0 0 236 rank value of 9.8s =0 0 0 0 0 0 0 0 0 0 0 1 0 238 rank value of 10s =0 0 0 0 0 0 1 0 0 1 0 0 0 239.5 rank value of 10.1s =0 0 0 0 1 0 0 0 0 0 0 0 0 241 rank value of 11s =0 0 0 0 0 1 0 0 0 0 0 0 0 242 rank value of 11.4s =0 0 1 0 0 0 0 0 0 0 0 0 0 243 rank value of 11.9s =0 0 0 0 0 0 0 0 0 0 1 0 0 244 rank value of 12.2s =0 0 0 0 0 0 0 0 0 1 0 0 0 245 rank value of 13s =0 0 0 1 0 0 0 1 0 0 0 0 0 246.5 rank value of 13.3s =0 0 0 0 0 0 0 0 1 0 0 0 0 248 rank value of 14s =0 0 0 0 0 0 0 1 0 1 0 0 0 249.5 rank value of 14.2s =0 0 0 0 0 0 1 0 0 0 0 0 0 251 rank value of 14.7s =0 0 0 1 0 0 0 0 0 0 0 0 0 252 rank value of 14.8s =0 0 0 0 0 0 0 0 0 0 1 0 0 253 rank value of 15s =0 0 0 0 0 0 0 0 0 0 0 1 0 254 rank value of 15.1s =0 0 1 0 0 0 1 0 0 0 0 0 0 255.5 rank value of 15.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 257 rank value of 15.8s =1 0 0 1 0 0 0 0 0 0 0 0 0 258.5 rank value of 16s =1 1 0 0 1 0 0 0 0 0 0 0 0 261 rank value of 17s =1 0 0 0 0 0 0 0 0 0 0 0 0 263 rank value of 17.4s =1 0 0 0 0 0 0 0 0 0 0 0 0 264 rank value of 17.9s =1 0 0 0 0 0 0 0 0 0 0 0 0 265 rank value of 18s =0 0 0 1 0 0 0 0 0 0 0 0 0 266 rank value of 19s =0 0 0 1 1 0 0 0 0 0 0 0 0 267.5 rank value of 19.8s =0 0 0 1 0 0 0 0 0 0 0 0 0 269 rank value of 20s =0 0 0 0 1 0 0 0 0 0 0 0 0 270 rank value of 21s =0 0 0 0 0 1 1 0 0 0 0 0 0 271.5 rank value of 22.8s =1 0 0 0 0 0 0 0 0 0 0 0 0 273 rank value of 23s =0 0 0 1 0 0 0 0 1 0 0 0 0 274.5 rank value of 23.1s =0 0 0 0 0 0 0 0 0 0 1 0 0 276 rank value of 24s =0 0 0 0 0 0 0 1 0 0 0 0 0 277 rank value of 25s =0 0 0 0 1 0 0 0 0 0 0 0 0 278 rank value of 25.6s =1 0 0 0 0 0 0 0 0 0 0 0 0 279 rank value of 26s =0 0 0 0 0 0 0 0 0 0 1 0 0 280 rank value of 26.1s =1 0 0 0 0 0 0 0 0 0 0 0 0 281 rank value of 27.9s =1 0 0 0 0 0 0 0 0 0 0 0 0 282 rank value of 28s =0 0 0 1 0 0 0 0 0 0 0 0 0 283 rank value of 29s =0 0 0 0 0 0 0 1 0 0 0 0 0 284 rank value of 30s =0 0 0 0 0 0 0 0 0 0 1 0 0 285 Vanadium (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 51 of 66 rank value of 30.4s =1 0 0 0 0 0 0 0 0 0 0 0 0 286 rank value of 32s =0 0 0 0 1 0 0 0 0 0 0 0 0 287 rank value of 32.7s =0 0 1 0 0 0 0 0 0 0 0 0 0 288 rank value of 33.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 289 rank value of 33.6s =0 0 0 0 1 0 0 0 0 0 0 0 0 290 rank value of 37s =0 0 0 0 0 0 0 0 1 0 0 0 0 291 rank value of 40s =1 0 0 0 0 0 0 0 0 0 0 0 0 292 rank value of 41s =1 0 0 0 0 0 0 0 1 0 0 0 0 293.5 rank value of 42s =0 0 0 0 0 0 0 1 0 0 0 0 0 295 rank value of 43s =1 0 0 0 0 0 0 0 0 0 0 0 0 296 rank value of 44s =0 0 1 0 0 0 0 0 0 0 0 0 0 297 rank value of 44.3s =1 0 0 0 0 0 0 0 0 0 0 0 0 298 rank value of 44.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 299 rank value of 45s =1 0 0 1 0 0 0 0 0 0 0 0 0 300.5 rank value of 48.2s =0 0 0 0 0 0 0 0 0 0 1 0 0 302 rank value of 50s =0 0 0 0 0 0 0 0 1 0 0 0 0 303 rank value of 54s =1 0 0 0 0 0 0 0 0 0 0 0 0 304 rank value of 55s =1 0 0 0 0 0 0 0 0 0 0 0 0 305 rank value of 58s =1 0 0 0 0 0 0 0 0 0 0 0 0 306 rank value of 59s =1 0 0 0 0 0 0 0 0 0 0 0 0 307 rank value of 69s =0 0 0 0 0 0 0 0 1 0 0 0 0 308 rank value of 78s =0 0 0 0 0 0 0 0 0 1 0 0 0 309 rank value of 79s =2 0 0 0 0 0 0 0 0 0 0 0 0 310.5 rank value of 82s =1 0 0 0 0 0 0 0 0 0 1 0 0 312.5 rank value of 85s =1 0 0 0 0 0 0 0 0 0 1 0 0 314.5 rank value of 88s =0 0 0 0 0 0 0 0 0 0 1 0 0 316 rank value of 89s =2 0 0 0 0 0 0 0 0 0 0 0 0 317.5 rank value of 92s =0 0 0 0 0 0 0 0 1 0 0 0 0 319 rank value of 103s =0 0 0 0 0 0 0 0 0 1 0 0 0 320 rank value of 110s =1 0 0 0 0 0 0 0 0 0 1 0 0 321.5 rank value of 120s =0 0 0 0 0 0 0 0 0 1 0 0 0 323 rank value of 130s =0 0 0 0 0 0 0 0 0 0 1 0 0 324 rank value of 160s =0 0 0 0 0 0 0 0 0 1 0 0 0 325 rank value of 170s =0 0 0 1 0 0 0 0 0 1 0 0 0 326.5 rank value of 200s =0 0 0 0 0 0 0 0 0 0 1 0 0 328 rank value of 210s =0 0 0 1 0 0 0 0 0 0 1 0 0 329.5 rank value of 230s =0 0 0 0 0 0 0 0 0 2 0 0 0 331.5 rank value of 240s =1 0 0 0 0 0 0 0 0 2 0 0 0 334 rank value of 250s =1 0 0 0 0 0 0 0 0 0 0 0 0 336 rank value of 260s =0 0 0 0 0 0 0 0 0 1 0 0 0 337 rank value of 300s =0 0 0 0 0 1 0 0 0 0 0 0 0 338 rank value of 310s =0 0 0 0 0 0 0 0 0 1 0 0 0 339 rank value of 640s =0 0 0 1 0 0 0 0 0 0 0 0 0 340 rank value of 680s =0 0 0 1 0 0 0 0 0 0 0 0 0 341 rank value of 1000s =0 0 0 0 0 0 0 0 0 0 1 0 0 342 n =32 31 26 30 30 30 28 28 29 30 26 11 11 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SK i=1 (Ri 2)/Ni]} -3(N+1) Well = Background MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Ri2/Ni = 3045100.1 1E+06 783598 494597 428918 549360 821691 1E+06 1E+06 247500 114444 Ni bg = 89 Vanadium (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 52 of 66 N = 342 H = 39.86 Adjust H for ties: Ti =8E+06 sum of T1..T30 H' = H/(1-(Ti/(N3-N))) H' =50.40 Chi-square =18.31 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 17df at the 5% significance level from Table 1 of the IFG. The value is 18.31 which is less than H' =50.40. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Rbar (well x) = 210.7 161.6 128.4 123.8 140.1 168.3 207.8 226.7 150.0 102.0 avg Rbar (background) = 185.0 185.0 185.0 185.0 185.0 185.0 185.0 185.0 185.0 185.0 Dx = 25.7 -23.4 -56.6 -61.2 -44.9 -16.6 22.8 41.8 -35.0 -83.0 Cx = 48.6 48.6 48.6 49.9 49.9 49.3 48.6 51.4 73.6 73.6 Statistical Significance ? No No No No No No No No No No If SSI, is current event above MCL?---------- Compare each difference (Dx) with the corresponding critical value (Cx). No compliance well's difference between average ranks exceeded its corresponding critical value at a 5% significance level. Therefore, we conclude that significant evidence of contamination does not exist at the 5% significance level. Vanadium (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 53 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Zinc NC MCL (mg/l):1000 Method:Kruskal-Wallis Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 150 NS NS 35 48 36 12 43 28 68 NS NP NP 10 06/26/00 37 12 NS NS NS NS NS NS NS NS NS NP NP 10 07/26/00 65 66 NS NS NS NS NS NS NS NS NS NP NP 10 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 50 04/09/01 230 130 NS 12 24 18 17 33 75 200 NS NP NP 10 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 50 04/15/02 230 16 NS ND ND 13 33 38 120 230 NS NP NP 10 09/26/02 57 120 110 580 ND 20 ND 56 250 280 4800 NP NP 10 04/28/03 86 14 31 160 16 ND ND ND 81 190 800 NP NP 10 10/30/03 55 22 NT 17 26 10 ND ND 140 26 1800 NP NP 10 04/20/04 55 10 ND 44 30 11 14 19 23 220 770 NP NP 10 10/21/04 29 ND ND 17 ND 14 ND 12 15 70 1200 NP NP 10 04/18/05 83 ND ND 780 ND 30 13 10 ND 240 1200 NP NP 10 10/13/05 92 13 12 230 19 25 ND ND 14 170 800 NP NP 10 04/25/06 130 ND 88 ND ND ND ND ND 110 120 780 NP NP 50 10/20/06 74 ND 20 37 ND ND ND ND 55 ND 200 NP NP 10 04/25/07 55 21 30 30 22 830 22 15 10 12 200 NP NP 10 10/31/07 86 ND 66.2 14 37.4 33.3 12 ND 11.6 91.1 336 NP NP 10 04/23/08 27.3 ND 50.3 12.2 24.4 36.9 ND 10.3 17.5 38.8 138 NP NP 10 10/20/08 66.5 19.9 59.2 15.3 10.6 29.1 ND 12.4 ND 17.4 71.5 NP NP 10 04/22/09 23.1 43.5 99.9 25.3 17.9 17.6 10.5 ND 35.2 ND NS NP NP 10 10/26/09 19.6 ND 14.8 ND 37.8 ND NS NS NS ND 63.8 NP NP 10 04/22/10 22.2 14.2 ND ND ND ND NS NS ND ND 24.6 NP NP 10 10/27/10 19.1 ND 12.3 15 ND ND 32.4 16.3 ND ND 60.7 ND ND 10 04/29/11 25.7 ND 21.9 ND 11.8 23.9 13.7 ND ND ND 42.9 20.5 21.5 10 10/25/11 34.5 ND 11.6 23.7 12.8 10.1 32.5 ND ND 17.7 49.9 15.1 ND 10 04/20/12 47.6 ND 12.5 ND 11.6 10.1 21.1 ND ND 11.1 30.7 50.8 ND 10 10/24/12 93.4 10.4 11.3 22.4 23.8 ND 10.3 16.1 14.9 12.2 15.7 15.8 ND 10 04/24/13 56.3 ND ND ND 18.6 14.9 ND ND ND ND 33.2 ND ND 10 10/24/13 30.6 ND ND ND ND ND 28.1 ND ND 28.8 39.6 14.9 ND 10 04/24/14 25.8 ND ND ND ND ND 18.9 ND ND ND ND 14.9 10.1 10 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 04/28/15 51.7 ND 14.2 19 13.6 ND 14.8 12.9 ND ND 11.3 13.3 ND 10 10/27/15 69.8 ND ND ND 14.3 ND ND 11.8 ND 22.1 ND 36.4 ND 10 Ni 32 31 26 30 30 30 28 28 29 30 26 11 11 sum of rank values (Ri)8533.5 3994.0 4344.0 5140.5 4584.0 4450.0 3811.5 3590.0 4667.0 5888.5 6911.0 1827.0 912.0 avg rank value (Rbar)266.7 128.8 167.1 171.4 152.8 148.3 136.1 128.2 160.9 196.3 265.8 166.1 82.9 Number of each rank value Rank Value rank value of NDs =1 17 9 11 11 12 12 14 13 10 3 3 9 63 rank value of 10s =0 1 0 0 0 1 0 1 1 0 0 0 0 127.5 rank value of 10.1s =0 0 0 0 0 2 0 0 0 0 0 0 1 131 Zinc (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 54 of 66 rank value of 10.3s =0 0 0 0 0 0 1 1 0 0 0 0 0 133.5 rank value of 10.4s =0 1 0 0 0 0 0 0 0 0 0 0 0 135 rank value of 10.5s =0 0 0 0 0 0 1 0 0 0 0 0 0 136 rank value of 10.6s =0 0 0 0 1 0 0 0 0 0 0 0 0 137 rank value of 11s =0 0 0 0 0 1 0 0 0 0 0 0 0 138 rank value of 11.1s =0 0 0 0 0 0 0 0 0 1 0 0 0 139 rank value of 11.3s =0 0 1 0 0 0 0 0 0 0 1 0 0 140.5 rank value of 11.6s =0 0 1 0 1 0 0 0 1 0 0 0 0 143 rank value of 11.8s =0 0 0 0 1 0 0 1 0 0 0 0 0 145.5 rank value of 12s =0 1 1 1 0 0 2 1 0 1 0 0 0 150 rank value of 12.2s =0 0 0 1 0 0 0 0 0 1 0 0 0 154.5 rank value of 12.3s =0 0 1 0 0 0 0 0 0 0 0 0 0 156 rank value of 12.4s =0 0 0 0 0 0 0 1 0 0 0 0 0 157 rank value of 12.5s =0 0 1 0 0 0 0 0 0 0 0 0 0 158 rank value of 12.8s =0 0 0 0 1 0 0 0 0 0 0 0 0 159 rank value of 12.9s =0 0 0 0 0 0 0 1 0 0 0 0 0 160 rank value of 13s =0 1 0 0 0 1 1 0 0 0 0 0 0 162 rank value of 13.3s =0 0 0 0 0 0 0 0 0 0 0 1 0 164 rank value of 13.6s =0 0 0 0 1 0 0 0 0 0 0 0 0 165 rank value of 13.7s =0 0 0 0 0 0 1 0 0 0 0 0 0 166 rank value of 14s =0 1 0 1 0 1 1 0 1 0 0 0 0 169 rank value of 14.2s =0 1 1 0 0 0 0 0 0 0 0 0 0 172.5 rank value of 14.3s =0 0 0 0 1 0 0 0 0 0 0 0 0 174 rank value of 14.8s =0 0 1 0 0 0 1 0 0 0 0 0 0 175.5 rank value of 14.9s =0 0 0 0 0 1 0 0 1 0 0 2 0 178.5 rank value of 15s =0 0 0 1 0 0 0 1 1 0 0 0 0 182 rank value of 15.1s =0 0 0 0 0 0 0 0 0 0 0 1 0 184 rank value of 15.3s =0 0 0 1 0 0 0 0 0 0 0 0 0 185 rank value of 15.7s =0 0 0 0 0 0 0 0 0 0 1 0 0 186 rank value of 15.8s =0 0 0 0 0 0 0 0 0 0 0 1 0 187 rank value of 16s =0 1 0 0 1 0 0 0 0 0 0 0 0 188.5 rank value of 16.1s =0 0 0 0 0 0 0 1 0 0 0 0 0 190 rank value of 16.3s =0 0 0 0 0 0 0 1 0 0 0 0 0 191 rank value of 17s =0 0 0 2 0 0 1 0 0 0 0 0 0 193 rank value of 17.4s =0 0 0 0 0 0 0 0 0 1 0 0 0 195 rank value of 17.5s =0 0 0 0 0 0 0 0 1 0 0 0 0 196 rank value of 17.6s =0 0 0 0 0 1 0 0 0 0 0 0 0 197 rank value of 17.7s =0 0 0 0 0 0 0 0 0 1 0 0 0 198 rank value of 17.9s =0 0 0 0 1 0 0 0 0 0 0 0 0 199 rank value of 18s =0 0 0 0 0 1 0 0 0 0 0 0 0 200 rank value of 18.6s =0 0 0 0 1 0 0 0 0 0 0 0 0 201 rank value of 18.9s =0 0 0 0 0 0 1 0 0 0 0 0 0 202 rank value of 19s =0 0 0 1 1 0 0 1 0 0 0 0 0 204 rank value of 19.1s =1 0 0 0 0 0 0 0 0 0 0 0 0 206 rank value of 19.6s =1 0 0 0 0 0 0 0 0 0 0 0 0 207 rank value of 19.9s =0 1 0 0 0 0 0 0 0 0 0 0 0 208 rank value of 20s =0 0 1 0 0 1 0 0 0 0 0 0 0 209.5 rank value of 20.5s =0 0 0 0 0 0 0 0 0 0 0 1 0 211 rank value of 21s =0 1 0 0 0 0 0 0 0 0 0 0 0 212 rank value of 21.1s =0 0 0 0 0 0 1 0 0 0 0 0 0 213 rank value of 21.5s =0 0 0 0 0 0 0 0 0 0 0 0 1 214 rank value of 21.9s =0 0 1 0 0 0 0 0 0 0 0 0 0 215 rank value of 22s =0 1 0 0 1 0 1 0 0 0 0 0 0 217 rank value of 22.1s =0 0 0 0 0 0 0 0 0 1 0 0 0 219 rank value of 22.2s =1 0 0 0 0 0 0 0 0 0 0 0 0 220 rank value of 22.4s =0 0 0 1 0 0 0 0 0 0 0 0 0 221 rank value of 23s =0 0 0 0 0 0 0 0 1 0 0 0 0 222 rank value of 23.1s =1 0 0 0 0 0 0 0 0 0 0 0 0 223 Zinc (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 55 of 66 rank value of 23.7s =0 0 0 1 0 0 0 0 0 0 0 0 0 224 rank value of 23.8s =0 0 0 0 1 0 0 0 0 0 0 0 0 225 rank value of 23.9s =0 0 0 0 0 1 0 0 0 0 0 0 0 226 rank value of 24s =0 0 0 0 1 0 0 0 0 0 0 0 0 227 rank value of 24.4s =0 0 0 0 1 0 0 0 0 0 0 0 0 228 rank value of 24.6s =0 0 0 0 0 0 0 0 0 0 1 0 0 229 rank value of 25s =0 0 0 0 0 1 0 0 0 0 0 0 0 230 rank value of 25.3s =0 0 0 1 0 0 0 0 0 0 0 0 0 231 rank value of 25.7s =1 0 0 0 0 0 0 0 0 0 0 0 0 232 rank value of 25.8s =1 0 0 0 0 0 0 0 0 0 0 0 0 233 rank value of 26s =0 0 0 0 1 0 0 0 0 1 0 0 0 234.5 rank value of 27.3s =1 0 0 0 0 0 0 0 0 0 0 0 0 236 rank value of 28s =0 0 0 0 0 0 0 0 1 0 0 0 0 237 rank value of 28.1s =0 0 0 0 0 0 1 0 0 0 0 0 0 238 rank value of 28.8s =0 0 0 0 0 0 0 0 0 1 0 0 0 239 rank value of 29s =1 0 0 0 0 0 0 0 0 0 0 0 0 240 rank value of 29.1s =0 0 0 0 0 1 0 0 0 0 0 0 0 241 rank value of 30s =0 0 1 1 1 1 0 0 0 0 0 0 0 243.5 rank value of 30.6s =1 0 0 0 0 0 0 0 0 0 0 0 0 246 rank value of 30.7s =0 0 0 0 0 0 0 0 0 0 1 0 0 247 rank value of 31s =0 0 1 0 0 0 0 0 0 0 0 0 0 248 rank value of 32.4s =0 0 0 0 0 0 1 0 0 0 0 0 0 249 rank value of 32.5s =0 0 0 0 0 0 1 0 0 0 0 0 0 250 rank value of 33s =0 0 0 0 0 0 1 1 0 0 0 0 0 251.5 rank value of 33.2s =0 0 0 0 0 0 0 0 0 0 1 0 0 253 rank value of 33.3s =0 0 0 0 0 1 0 0 0 0 0 0 0 254 rank value of 34.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 255 rank value of 35s =0 0 0 1 0 0 0 0 0 0 0 0 0 256 rank value of 35.2s =0 0 0 0 0 0 0 0 1 0 0 0 0 257 rank value of 36s =0 0 0 0 0 1 0 0 0 0 0 0 0 258 rank value of 36.4s =0 0 0 0 0 0 0 0 0 0 0 1 0 259 rank value of 36.9s =0 0 0 0 0 1 0 0 0 0 0 0 0 260 rank value of 37s =1 0 0 1 0 0 0 0 0 0 0 0 0 261.5 rank value of 37.4s =0 0 0 0 1 0 0 0 0 0 0 0 0 263 rank value of 37.8s =0 0 0 0 1 0 0 0 0 0 0 0 0 264 rank value of 38s =0 0 0 0 0 0 0 1 0 0 0 0 0 265 rank value of 38.8s =0 0 0 0 0 0 0 0 0 1 0 0 0 266 rank value of 39.6s =0 0 0 0 0 0 0 0 0 0 1 0 0 267 rank value of 42.9s =0 0 0 0 0 0 0 0 0 0 1 0 0 268 rank value of 43s =0 0 0 0 0 0 0 1 0 0 0 0 0 269 rank value of 43.5s =0 1 0 0 0 0 0 0 0 0 0 0 0 270 rank value of 44s =0 0 0 1 0 0 0 0 0 0 0 0 0 271 rank value of 47.6s =1 0 0 0 0 0 0 0 0 0 0 0 0 272 rank value of 48s =0 0 0 0 1 0 0 0 0 0 0 0 0 273 rank value of 49.9s =0 0 0 0 0 0 0 0 0 0 1 0 0 274 rank value of 50.3s =0 0 1 0 0 0 0 0 0 0 0 0 0 275 rank value of 50.8s =0 0 0 0 0 0 0 0 0 0 0 1 0 276 rank value of 51.7s =1 0 0 0 0 0 0 0 0 0 0 0 0 277 rank value of 55s =3 0 0 0 0 0 0 0 1 0 0 0 0 279.5 rank value of 56s =0 0 0 0 0 0 0 1 0 0 0 0 0 282 rank value of 56.3s =1 0 0 0 0 0 0 0 0 0 0 0 0 283 rank value of 57s =1 0 0 0 0 0 0 0 0 0 0 0 0 284 rank value of 59.2s =0 0 1 0 0 0 0 0 0 0 0 0 0 285 rank value of 60.7s =0 0 0 0 0 0 0 0 0 0 1 0 0 286 rank value of 63.8s =0 0 0 0 0 0 0 0 0 0 1 0 0 287 rank value of 65s =1 0 0 0 0 0 0 0 0 0 0 0 0 288 rank value of 66s =0 1 0 0 0 0 0 0 0 0 0 0 0 289 rank value of 66.2s =0 0 1 0 0 0 0 0 0 0 0 0 0 290 Zinc (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 56 of 66 rank value of 66.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 291 rank value of 68s =0 0 0 0 0 0 0 0 0 1 0 0 0 292 rank value of 69.8s =1 0 0 0 0 0 0 0 0 0 0 0 0 293 rank value of 70s =0 0 0 0 0 0 0 0 0 1 0 0 0 294 rank value of 71.5s =0 0 0 0 0 0 0 0 0 0 1 0 0 295 rank value of 74s =1 0 0 0 0 0 0 0 0 0 0 0 0 296 rank value of 75s =0 0 0 0 0 0 0 0 1 0 0 0 0 297 rank value of 81s =0 0 0 0 0 0 0 0 1 0 0 0 0 298 rank value of 83s =1 0 0 0 0 0 0 0 0 0 0 0 0 299 rank value of 86s =2 0 0 0 0 0 0 0 0 0 0 0 0 300.5 rank value of 88s =0 0 1 0 0 0 0 0 0 0 0 0 0 302 rank value of 91.1s =0 0 0 0 0 0 0 0 0 1 0 0 0 303 rank value of 92s =1 0 0 0 0 0 0 0 0 0 0 0 0 304 rank value of 93.4s =1 0 0 0 0 0 0 0 0 0 0 0 0 305 rank value of 99.9s =0 0 1 0 0 0 0 0 0 0 0 0 0 306 rank value of 110s =0 0 1 0 0 0 0 0 1 0 0 0 0 307.5 rank value of 120s =0 1 0 0 0 0 0 0 1 1 0 0 0 310 rank value of 130s =1 1 0 0 0 0 0 0 0 0 0 0 0 312.5 rank value of 138s =0 0 0 0 0 0 0 0 0 0 1 0 0 314 rank value of 140s =0 0 0 0 0 0 0 0 1 0 0 0 0 315 rank value of 150s =1 0 0 0 0 0 0 0 0 0 0 0 0 316 rank value of 160s =0 0 0 1 0 0 0 0 0 0 0 0 0 317 rank value of 170s =0 0 0 0 0 0 0 0 0 1 0 0 0 318 rank value of 190s =0 0 0 0 0 0 0 0 0 1 0 0 0 319 rank value of 200s =0 0 0 0 0 0 0 0 0 1 2 0 0 321 rank value of 220s =0 0 0 0 0 0 0 0 0 1 0 0 0 323 rank value of 230s =2 0 0 1 0 0 0 0 0 1 0 0 0 325.5 rank value of 240s =0 0 0 0 0 0 0 0 0 1 0 0 0 328 rank value of 250s =0 0 0 0 0 0 0 0 1 0 0 0 0 329 rank value of 280s =0 0 0 0 0 0 0 0 0 1 0 0 0 330 rank value of 336s =0 0 0 0 0 0 0 0 0 0 1 0 0 331 rank value of 580s =0 0 0 1 0 0 0 0 0 0 0 0 0 332 rank value of 770s =0 0 0 0 0 0 0 0 0 0 1 0 0 333 rank value of 780s =0 0 0 1 0 0 0 0 0 0 1 0 0 334.5 rank value of 800s =0 0 0 0 0 0 0 0 0 0 2 0 0 336.5 rank value of 830s =0 0 0 0 0 1 0 0 0 0 0 0 0 338 rank value of 1200s =0 0 0 0 0 0 0 0 0 0 2 0 0 339.5 rank value of 1800s =0 0 0 0 0 0 0 0 0 0 1 0 0 341 rank value of 4800s =0 0 0 0 0 0 0 0 0 0 1 0 0 342 n =32 31 26 30 30 30 28 28 29 30 26 11 11 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SK i=1 (Ri 2)/Ni]} -3(N+1) Well = Background MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Ri2/Ni = 3198286.7 880825 700435 660083 518840 460289 751065 1E+06 2E+06 303448 75613 Ni bg = 89 N = 342 H = 49.38 Adjust H for ties: Ti =2E+06 sum of T1..T34 Zinc (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 57 of 66 H' = H/(1-(Ti/(N3-N))) H' =51.92 Chi-square =18.31 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 17df at the 5% significance level from Table 1 of the IFG. The value is 18.31 which is less than H' =51.92. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Rbar (well x) = 171.4 152.8 148.3 136.1 128.2 160.9 196.3 265.8 166.1 82.9 avg Rbar (background) = 189.6 189.6 189.6 189.6 189.6 189.6 189.6 189.6 189.6 189.6 Dx = -18.2 -36.8 -41.2 -53.4 -61.4 -28.6 6.7 76.2 -23.5 -106.7 Cx = 48.6 48.6 48.6 49.9 49.9 49.3 48.6 51.4 73.6 73.6 Statistical Significance ? No No No No No No No Yes No No If SSI, is current event above MCL?-------No -- Compare each difference (Dx) with the corresponding critical value (Cx). The Dx value for the above indicated wells do exceed the corresponding Cx value. Therefore, we conclude that the concentration of Total Zinc averaged over these compliance wells are significantly greater than that of the background wells. Shewart-CUSUM Control Charts should be performed for each failing well to check for statistical significance. Zinc (K-W) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 58 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Total Zinc NC MCL (mg/l):1000 Method:Shewhart-CUSUM Control Chart Part 1: Check for Normality MW - 1 5 MD L 9/26/02 4800 10 4/28/03 800 10 10/30/03 1800 10 4/20/04 770 10 10/21/04 1200 10 4/18/05 1200 10 10/13/05 800 10 4/25/06 780 50 10/20/06 200 10 4/25/07 200 10 10/31/07 336 10 4/23/08 138 10 10/20/08 71.5 10 4/22/09 NS 10 10/26/09 63.8 10 4/22/10 24.6 10 10/27/10 60.7 10 4/29/11 42.9 10 10/25/11 49.9 10 4/20/12 30.7 10 10/24/12 15.7 10 4/24/13 33.2 10 10/24/13 39.6 10 4/24/14 ND 10 10/27/14 ND 10 4/28/15 11.3 10 10/27/15 ND 10 If not detected (ND), use half of the detection limit. Xbar =518.5730769 SD =997.6619847 N =26 1/NSi(Xi-Xbar)3 =3059835493 g1=3.268118647 Since the Coefficient of Skewness of 3.27 is greater than 1.0, the real data appear to be significantly skewed. Do not assume that the data follow a Normal distribution. Perform the Skewness Test on the natural log of the values. Xbar =4.699362566 SD =1.973125765 N =26 1/NSi(Xi-Xbar)3 =0.686761745 g1=0.094818221 Since the Coefficient of Skewness of 0.09 is less than 1.0, the data appear not to be significantly skewed. Zn (S-C MW-15) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 59 of 66 Proceed with further statistical tests using the log-transformed values shown above. Part 2: Shewhart-CUSUM Control Chart Compute the mean and standard deviation of the historical data: 7.103371838 = xmean (Mean of N1-N8 historical data) 0.63200761 = s (Standard Deviation of N1-N8 historical data) 1 = k (constant, reference value) 5 = h (constant, upper control limit for the CUSUM scheme) 4.5 = SCL (Constant, upper Shewhart Control Limit) Compute the standardized mean (Zi) and the cumulative sum (Si) for each concentration. Date xi Zi Si h SCL 0 10/20/06 5.298317367 -2.8560645 0 5 4.5 4/25/07 5.298317367 -2.8560645 0 5 4.5 10/31/07 5.81711116 -2.0351981 0 5 4.5 4/23/08 4.927253685 -3.4431835 0 5 4.5 10/20/08 4.26969745 -4.483608 0 5 4.5 10/26/09 4.15575319 -4.6638974 0 5 4.5 4/22/10 3.202746443 -6.1718013 0 5 4.5 10/27/10 4.105943698 -4.7427089 0 5 4.5 4/29/11 3.758871826 -5.2918667 0 5 4.5 10/25/11 3.910021003 -5.0527095 0 5 4.5 4/20/12 3.424262655 -5.8213052 0 5 4.5 10/24/12 2.753660712 -6.8823714 0 5 4.5 4/24/13 3.502549876 -5.6974345 0 5 4.5 10/24/13 3.678829118 -5.418515 0 5 4.5 4/24/14 1.609437912 -8.6928288 0 5 4.5 10/27/14 1.609437912 -8.6928288 0 5 4.5 4/28/15 2.424802726 -7.4027101 0 5 4.5 10/27/15 1.609437912 -8.6928288 0 5 4.5 Plot Zi and Si versus time: Compare the Zi and Si values to their respective control limits of SCL and h. The limits were not exceeded and do not indicate statistically significant evidence of contamination at the site. -10 -8 -6 -4 -2 0 2 4 6 5/ 2 8 / 0 5 10 / 1 0 / 0 6 2/ 2 2 / 0 8 7/ 6 / 0 9 11 / 1 8 / 1 0 4/ 1 / 1 2 8/ 1 4 / 1 3 12 / 2 7 / 1 4 5/ 1 0 / 1 6 St a n d a r d i z e d U n i t s Combined Shewart-CUSUM Control Chart Zi SCL Si h Zn (S-C MW-15) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 60 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Acetone MCL (mg/l):6000 Method:Poisson Prediction Limits Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 NT NS NS NT NT NT NT NT NT NT NS NP NP 100 06/26/00 NT NT NS NS NS NS NS NS NS NS NS NP NP 100 07/26/00 NT NT NS NS NS NS NS NS NS NS NS NP NP 100 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 100 04/09/01 NT NT NS NT NT NT NT NT NT NT NS NP NP 100 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 100 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 100 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 100 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 100 04/15/02 NT NT NS NT NT NT NT NT NT NT NS NP NP 100 09/26/02 NT NT NT NT NT NT NT NT NT NT NT NP NP 100 04/28/03 NT NT NT NT NT NT NT NT NT NT NT NP NP 100 10/30/03 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/20/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/21/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/18/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 25 10/13/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 25 04/25/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 25 10/20/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 25 04/25/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 25 10/31/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 25 04/23/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 25 10/20/08 ND ND ND ND ND ND ND ND ND ND 140 NP NP 25 04/22/09 ND ND ND ND ND ND ND ND ND ND NS NP NP 25 10/26/09 ND ND ND ND ND ND NS NS NS ND ND NP NP 25 04/22/10 ND ND ND ND ND ND NS NS ND ND ND NP NP 25 10/27/10 ND ND ND ND ND ND ND ND ND ND ND ND ND 25 04/29/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 25 10/25/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 25 04/20/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 25 10/24/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 25 04/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 25 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 25 04/24/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 25 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 25 04/28/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 25 10/27/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 25 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 24. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 72 Tn1 = 832.5 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =72 Tn1 = 832.5 t [71,.01] =2.3841 c =0.0139 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Tn2 = 12.5 12.5 12.5 12.5 12.5 12.5 12.5 12.5 12.5 12.5 T*k =19.8 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Acetone (PPL) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 61 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Carbon Disulfide MCL (mg/l):700 Method:Poisson Prediction Limits Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 NT NS NS NT NT NT NT NT NT NT NS NP NP 100 06/26/00 NT NT NS NS NS NS NS NS NS NS NS NP NP 100 07/26/00 NT NT NS NS NS NS NS NS NS NS NS NP NP 100 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 100 04/09/01 NT NT NS NT NT NT NT NT NT NT NS NP NP 100 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 100 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 100 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 100 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 100 04/15/02 NT NT NS NT NT NT NT NT NT NT NS NP NP 100 09/26/02 NT NT NT NT NT NT NT NT NT NT NT NP NP 100 04/28/03 NT NT NT NT NT NT NT NT NT NT NT NP NP 100 10/30/03 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/20/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/21/04 ND 24 ND ND ND ND ND ND 15 ND ND NP NP 10 04/18/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/13/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/25/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/20/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/25/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/31/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 2 04/23/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 2 10/20/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 2 04/22/09 ND ND ND ND ND ND ND ND 4.5 ND NS NP NP 2 10/26/09 ND ND ND ND ND ND NS NS NS ND ND NP NP 2 04/22/10 ND ND ND ND ND ND NS NS ND ND ND NP NP 2 10/27/10 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 04/29/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 10/25/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 04/20/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 10/24/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 04/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 04/24/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 04/28/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 10/27/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 24. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 72 Tn1 = 187 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =72 Tn1 = 187 t [71,.01] =2.3841 c =0.0139 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Tn2 = 1 1 1 1 1 1 1 1 1 1 T*k =6.5 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Carbon Disulfide (PPL) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 62 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Chloroethane MCL (mg/l):3000 Method:Poisson Prediction Limits Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 NT NS NS NT NT NT NT NT NT NT NS NP NP 10 06/26/00 NT NT NS NS NS NS NS NS NS NS NS NP NP 10 07/26/00 NT NT NS NS NS NS NS NS NS NS NS NP NP 10 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 10 04/09/01 NT NT NS NT NT NT NT NT NT NT NS NP NP 10 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 04/15/02 NT NT NS NT NT NT NT NT NT NT NS NP NP 10 09/26/02 NT NT NT NT NT NT NT NT NT NT NT NP NP 10 04/28/03 NT NT NT NT NT NT NT NT NT NT NT NP NP 10 10/30/03 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/20/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/21/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/18/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/13/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/25/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/20/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/25/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/31/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 1 04/23/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 1 10/20/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 1 04/22/09 ND ND ND ND ND ND ND ND ND ND NS NP NP 1 10/26/09 ND ND ND ND ND ND NS NS NS ND ND NP NP 1 04/22/10 ND ND ND ND ND ND NS NS ND ND ND NP NP 1 10/27/10 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/29/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 10/25/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/20/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 10/24/12 ND ND ND ND 4.4 ND ND ND ND ND ND ND ND 1 04/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/24/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/28/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 10/27/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 24. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 72 Tn1 = 144 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =72 Tn1 = 144 t [71,.01] =2.3841 c =0.0139 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Tn2 = 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 T*k =5.4 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Chloroethane (PPL) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 63 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Iodomethane MCL (mg/l):Not Established Method:Poisson Prediction Limits Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 NT NS NS NT NT NT NT NT NT NT NS NP NP 10 06/26/00 NT NT NS NS NS NS NS NS NS NS NS NP NP 10 07/26/00 NT NT NS NS NS NS NS NS NS NS NS NP NP 10 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 10 04/09/01 NT NT NS NT NT NT NT NT NT NT NS NP NP 10 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 04/15/02 NT NT NS NT NT NT NT NT NT NT NS NP NP 10 09/26/02 NT NT NT NT NT NT NT NT NT NT NT NP NP 10 04/28/03 NT NT NT NT NT NT NT NT NT NT NT NP NP 10 10/30/03 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/20/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/21/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/18/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/13/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/25/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/20/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/25/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/31/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/23/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 10/20/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/22/09 ND ND ND ND ND ND ND ND ND ND NS NP NP 5 10/26/09 ND ND ND ND ND ND NS NS NS ND ND NP NP 5 04/22/10 ND ND ND ND ND ND NS NS ND ND ND NP NP 5 10/27/10 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/29/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/25/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/20/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/24/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/24/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/28/15 ND ND ND 10.2 ND ND ND ND ND ND ND ND ND 5 10/27/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 24. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 72 Tn1 = 240 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =72 Tn1 = 240 t [71,.01] =2.3841 c =0.0139 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Tn2 = 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 T*k =7.8 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Iodomethane (PPL) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 64 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:Dichloromethane (Methylene chloride) MCL (mg/l):5 Method:Poisson Prediction Limits Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 NT NS NS NT NT NT NT NT NT NT NS NP NP 10 06/26/00 NT NT NS NS NS NS NS NS NS NS NS NP NP 10 07/26/00 NT NT NS NS NS NS NS NS NS NS NS NP NP 10 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 10 04/09/01 NT NT NS NT NT NT NT NT NT NT NS NP NP 10 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 04/15/02 NT NT NS NT NT NT NT NT NT NT NS NP NP 10 09/26/02 NT NT NT NT NT NT NT NT NT NT NT NP NP 10 04/28/03 NT NT NT NT NT NT NT NT NT NT NT NP NP 10 10/30/03 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/20/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 10/21/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/18/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 10/13/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/25/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 10/20/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/25/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 10/31/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 2 04/23/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 2 10/20/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 2 04/22/09 ND ND ND ND ND ND ND ND ND ND NS NP NP 2 10/26/09 ND ND ND ND ND ND NS NS NS ND ND NP NP 2 04/22/10 ND ND ND ND ND ND NS NS ND ND ND NP NP 2 10/27/10 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 04/29/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 10/25/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 04/20/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 10/24/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 04/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 04/24/14 ND ND ND ND ND 2 ND ND ND 2.2 ND ND ND 2 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 04/28/15 ND ND ND ND ND ND ND ND ND ND 2.2 ND ND 2 10/27/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 24. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 72 Tn1 = 108 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =72 Tn1 = 108 t [71,.01] =2.3841 c =0.0139 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Tn2 = 1 1 1 1 1 1 1 1 1 1 T*k =4.5 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Dichloromethane (PPL) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 65 of 66 White Oak Landfill Haywood County, North Carolina BLE Project Number J15-1957-50 Compound:2-Butanone MCL (mg/l):4000 Method:Poisson Prediction Limits Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 NT NS NS NT NT NT NT NT NT NT NS NP NP 100 06/26/00 NT NT NS NS NS NS NS NS NS NS NS NP NP 100 07/26/00 NT NT NS NS NS NS NS NS NS NS NS NP NP 100 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 100 04/09/01 NT NT NS NT NT NT NT NT NT NT NS NP NP 100 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 100 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 100 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 100 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 100 04/15/02 NT NT NS NT NT NT NT NT NT NT NS NP NP 100 09/26/02 NT NT NT NT NT NT NT NT NT NT NT NP NP 100 04/28/03 NT NT NT NT NT NT NT NT NT NT NT NP NP 100 10/30/03 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/20/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/21/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/18/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/13/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/25/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/20/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/25/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/31/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/23/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 10/20/08 ND ND ND ND ND ND ND ND ND ND 54.4 NP NP 5 04/22/09 ND ND ND ND ND ND ND ND ND ND NS NP NP 5 10/26/09 ND ND ND ND ND ND NS NS NS ND ND NP NP 5 04/22/10 ND ND ND ND ND ND NS NS ND ND ND NP NP 5 10/27/10 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/29/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/25/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/20/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/24/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/24/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/28/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/27/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 24. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 72 Tn1 = 240 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =72 Tn1 = 240 t [71,.01] =2.3841 c =0.0139 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Tn2 = 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 T*k =7.8 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. 2-Butanone (PPL) 1957-50 White Oak GW Stats 2nd 2015.xlsm Page 66 of 66