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HomeMy WebLinkAbout8803_TransylvaniaCoMSWLF_GWMR_DIN26643_20160119 2211 West Meadowview Rd. Greensboro, NC 27407 tel: 336/323-0092 fax: 336/323-0093 www.JoyceEngineering.com January 19, 2015 Mr. Ervin Lane Compliance Hydrogeologist Division of Waste Management/Solid Waste Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 RE: Second Semiannual Groundwater Monitoring Report of 2015 Calvert Landfill, Permit No. 88-03 Transylvania County, North Carolina JOYCE Project No. 00336.1601.12, Task No. 01 Dear Ervin: On behalf of Transylvania County, Joyce Engineering is submitting the enclosed Second Semiannual Monitoring Report of 2015 in electronic format, plus a copy of the Environmental Monitoring Form for the Calvert Landfill, Permit No. 88-03. This report completes the second semiannual compliance monitoring event of 2015 as required by the North Carolina Division of Waste Management, Solid Waste Section. Please feel free to contact Alex Everhart or me at (336) 323-0092 if you have any questions regarding this submittal. Sincerely, JOYCE ENGINEERING Hannu Kemppinen P.G. Senior Project Consultant Enclosures C: Jeff Brookshire – Transylvania County PREPARED FOR: TRANSYLVANIA COUNTY SOLID WASTE 500 HOWELL ROAD BREVARD, NORTH CAROLINA 28712 TRANSYLVANIA COUNTY CALVERT LANDFILL PERMIT NO. 88-03 SECOND SEMIANNUAL GROUNDWATER MONITORING REPORT OF 2015 DECEMBER 2015 PREPARED BY: 2211 WEST MEADOWVIEW ROAD, SUITE 101 GREENSBORO, NORTH CAROLINA 27407 NC LICENSE NUMBER C-0782 PHONE: (336) 323-0092 FAX: (336) 323-0093 JOYCE PROJECT NO. 00336.1601.12 Second Semiannual Groundwater Monitoring Report of 2015 Joyce Engineering Transylvania County Calvert Landfill, Permit No. 88-03 December 2015 i Second Semiannual Groundwater Monitoring Report of 2015 Calvert Landfill Transylvania County, North Carolina TABLE OF CONTENTS 1.0 INTRODUCTION..............................................................................................................1 1.1 Site Information .................................................................................................................1 1.2 Site Geology ........................................................................................................................1 1.3 Regulatory Status ...............................................................................................................1 2.0 FACILITY MONITORING PROGRAM .......................................................................1 2.1 Groundwater Monitoring Program .................................................................................1 2.2 Surface Water Monitoring Program ................................................................................2 3.0 SECOND SEMIANNUAL SAMPLING EVENT OF 2015 ............................................2 3.1 Field Work and Visual Inspection ....................................................................................2 3.2 Laboratory Analysis and JOYCE Quality Control ........................................................3 4.0 DATA ANALYSIS .............................................................................................................4 4.1 Inorganic Analytical Results and Comparisons to Standards .......................................4 4.2 Organic Analytical Results and Comparisons to Standards..........................................4 5.0 CONCLUSION ..................................................................................................................5 6.0 REFERENCES ...................................................................................................................6 Tables Table 1 Summary of Historical Groundwater Elevations Table 2 Summary of Historical Inorganic Constituents Table 3 Summary of Historical Organic Constituents Table 4 Horizontal Groundwater Flow Velocities Figure Figure No. 1 Site Location Map Drawing Drawing No. 1 Groundwater Surface Map Appendices Appendix 1 Laboratory Analytical Report and Field Forms Appendix 2 Summary of Detections and Summary of Exceedances Appendix 3 Summary of Field Parameters Appendix 4 Summary of Monitoring Well Construction Second Semiannual Groundwater Monitoring Report of 2015 Joyce Engineering Transylvania County Calvert Landfill, Permit No. 88-03 December 2015 1 1.0 INTRODUCTION 1.1 Site Information Transylvania County’s closed Calvert Landfill (Permit #88-03) is located north of Rosman, North Carolina between U.S. Highway 64 and Old U.S. Highway 64 (Figure No. 1). The unlined landfill operated between 1973 and May 1992. 1.2 Site Geology The Calvert Landfill is located in the Inner Piedmont physiographic province within the Chauga Belt, just southeast of the Brevard Fault Zone. The unit within the Chauga Belt that underlies the site is the Henderson Gneiss, which consists of augen gneisses. The mineralogy consists of microcline, oligoclase, quartz, biotite, muscovite, epidote, and sphene. 1.3 Regulatory Status The current groundwater monitoring at Calvert Landfill is in accordance with criteria set forth in Rule .0500 of the North Carolina Solid Waste Management Rules (NCSWMR) for municipal solid waste landfills (MSWLF) closed prior to April 9, 1993. Surface water will be monitored in accordance with criteria set forth in Rule .0602 of the NCSWMR. 2.0 FACILITY MONITORING PROGRAM 2.1 Groundwater Monitoring Program Groundwater monitoring at the Calvert Landfill is completed in accordance with the Detection Monitoring Program for Rule .0500 sites. Groundwater samples are collected semiannually. Eleven active groundwater monitoring wells and one homeowner well comprise the groundwater monitoring network at the Calvert Landfill. The current compliance network consists of monitoring wells MW-1, MW-2, MW-3, MW-4, MW-105S, MW-105D, MW-106S, MW-106D, MW-107S, MW-107D, and MW-108, plus homeowner well HW-1. A site plan indicating the facility and waste boundaries in addition to monitoring well locations can be found in Drawing No. 1. Four monitoring wells (MW-1, MW-2, MW-3, and MW-4) are monitored for RCRA metals and NC Appendix I list of volatile organics. The eight remaining wells (MW-105S, MW-105D, MW-106S, MW-106D, MW-107S, MW-107D, MW-108, and HW-1) are analyzed for NC Appendix I list of volatile organics only. Monitoring wells MW-105S and MW-105D are also analyzed for dichlorodifluoromethane. Monitoring Well Date Installed Classification Monitoring Program Total Depth from TOC (ft) Lithology of Screened Interval MW-1 9/91 Background Detection (.0500) 72.64 Bedrock MW-2 9/91 Compliance Detection (.0500) 83.30 Bedrock MW-3 8/89 Compliance Detection (.0500) 19.80 Saprolite Continued Next Page Second Semiannual Groundwater Monitoring Report of 2015 Joyce Engineering Transylvania County Calvert Landfill, Permit No. 88-03 December 2015 2 Monitoring Well Date Installed Classification Monitoring Program Total Depth from TOC (ft) Lithology of Screened Interval MW-4 8/89 Compliance Detection (.0500) 70.80 Bedrock MW-105S 7/97 Compliance Detection (.0500) 55.37 Saprolite MW-105D 7/97 Compliance Detection (.0500) 87.10 Bedrock MW-106S 3/10-11/99 Compliance Detection (.0500) 22.58 Saprolite MW-106D 3/10-11/99 Compliance Detection (.0500) 75.38 Bedrock MW-107S 3/10-11/99 Compliance Detection (.0500) 58.84 Saprolite MW-107D 3/10-11/99 Compliance Detection (.0500) 90.30 Bedrock MW-108 3/10-11/99 Compliance Detection (.0500) 108.44 Bedrock HW-1 Not Avail. Compliance Detection (.0500) Not Avail. Bedrock (Estimated) 2.2 Surface Water Monitoring Program Surface water monitoring at the Calvert Landfill is completed in accordance with Rule .0602 and samples are collected semiannually. The one surface water monitoring point comprises the surface water monitoring program for the Calvert Landfill and includes analysis for RCRA metals and NC Appendix I list of volatile organics. Surface water point SMP-1 is located to monitor water quality shortly before it enters Galloway Creek offsite. Surface Point Classification Monitoring Program SMP-1 Compliance Surface Water 3.0 SECOND SEMIANNUAL SAMPLING EVENT OF 2015 3.1 Field Work and Visual Inspection In order to detect potential releases of leachate and/or landfill gas migration in a timely manner, a visual inspection program has been implemented at the Calvert Landfill. This inspection program involves field personnel making the following observations of negative changes around the waste facility:  Observation of stress induced on the biological community (i.e., dead or dying vegetation),  Indications of leachate impact (i.e., seeps, impacted surface water), and  Observations of erosion. On October 19, 2015 personnel from Joyce Engineering (JOYCE) visited Calvert Landfill to purge and sample monitoring wells MW-1, MW-2, MW-3, MW-105S, MW-105D, MW-106S, MW-106D, MW-107S, MW-107D, and MW-108, including homeowner well HW-1. The area around MW-4 was flooded and was not sampled. SMP-1 was dry and was not sampled during the October 2015 sampling event. Depth-to-water measurements were obtained to the nearest 0.01 foot using an electronic water level indicator for all monitoring wells in the compliance network prior to purging. Groundwater elevations can be found in Table 1. Monitoring wells were purged and sampled using either a 12 volt pump or disposable bailers while the homeowner well was purged by spigot for 15 minutes. Measurements of temperature, pH, specific conductivity, and turbidity were recorded in the site specific log book prior to Second Semiannual Groundwater Monitoring Report of 2015 Joyce Engineering Transylvania County Calvert Landfill, Permit No. 88-03 December 2015 3 purging, after each purge volume, and during sampling. Prior to sampling, laboratory-supplied containers were prepared with the following information:  Monitoring well number (completed by field personnel),  Date and time of sample collection (completed by field personnel),  Initials of sampling personnel (completed by field personnel),  Project name and number (completed by the laboratory),  Chemical preservative (completed by the laboratory); and  Requested chemical analysis (completed by the laboratory). Groundwater samples from each monitoring well were collected directly from the 12 volt pump or disposable bailers in the provided laboratory containers either immediately after purging or within 24 hours of the final purge volume. Immediately after collection, the samples were placed on ice in a laboratory provided cooler. Field forms are provided in the Appendix 1. When not dry, a surface water sample (SMP-1), is collected directly from stream by lowering the prepared sample containers into the stream flow with the opening facing into the current. Care is taken not to overflow the sample containers (which could lead to preservative loss) and to avoid sample-induced turbidity. At the time of sampling, surface water is also measured for temperature, pH, specific conductivity, and turbidity and the readings were recorded in the site specific log book. After sample collection, the sample was placed on ice in a laboratory provided cooler. 3.2 Laboratory Analysis and JOYCE Quality Control The October 2015 groundwater samples were submitted to Pace Analytical Services, Inc. of Asheville, North Carolina under chain-of-custody control for analysis. JOYCE requested a Level II data report for the final laboratory report. The samples were received by the laboratory on October 21, 2015 in good condition, properly preserved, and within analysis hold times. In addition to samples collected for compliance monitoring at the Calvert Landfill, a Field Blank was collected by JOYCE personnel as part of the October 2015 sampling event. A Trip Blank prepared by the laboratory was to accompany the volatile sampling containers from the laboratory to the field and back to the laboratory. The Field Blank was analyzed for the eight RCRA metals and NC Appendix I list of volatile organic compounds plus dichloro- difluoromethane while the Trip Blank was analyzed for NC Appendix I volatile organic compounds plus dichlorodifluoromethane. Upon receipt of the laboratory data packages, the data was reviewed by JOYCE personnel for the following:  Typographical errors,  Correct analyses performed and within method specified hold times,  Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate, and Laboratory Control Samples,  Blank qualified data (B-flags), Second Semiannual Groundwater Monitoring Report of 2015 Joyce Engineering Transylvania County Calvert Landfill, Permit No. 88-03 December 2015 4  Detections above the NC 2L Groundwater Standards (NC2L), Groundwater Water Protection Standards (GWPS), NC 2B Surface Water Standards, and  Detections that are above historical levels. No questions or problems were discovered based on the review to warrant laboratory notification. 4.0 DATA ANALYSIS Final results from the October 2015 sampling event were received November 2, 2015, from Pace Analytical Services, Inc. and are found in Appendix 1. There were five quantified detections above the NC 2L or GWPS in compliance monitoring wells. 4.1 Inorganic Analytical Results and Comparisons to Standards As presented in Table 2, and Appendix was detected above its Solid Waste Section Reporting Limit (SWSL); however it was not above the Groundwater Protection Standard (GPS). No inorganic constituents were detected in samples from the compliance monitoring wells at quantified concentrations above their respective SWSLs or GPS during the October 2015 sampling event. Historical inorganic constituent data can be found in Table 2. 4.2 Organic Analytical Results and Comparisons to Standards The following organic constituents were detected at quantified concentrations during the October 2015 sampling event. All concentrations are reported in micrograms per liter (µg/L). Concentrations with a “J” are considered to be estimated. Concentrations with a “B” are considered to be attributed to lab or field contamination. Highlighted data are concentrations reported above the NC 2L. Constituent NC 2L/ {NC 2B} Background Downgradient MW-1 MW-2 MW-3 MW-4 MW- 105S MW- 105D MW- 106S Benzene 1 {51} ND 0.68 J 1.1 NS 0.80 J 2.2 ND Chlorobenzene 50 {488} ND 0.59 J 10.8 NS 2.6 J 12.2 ND 1,4-Dichlorobenzene 6 {488} ND 0.61 J 13.1 NS 2.4 6.7 ND Cis-1,2-Dichloroethylene 70 {NE} ND 0.95 J 0.90 J NS 0.65 J 13.4 0.91 J Trichloroethene 3 {30} ND ND ND NS ND 1.1 ND Constituent NC 2L/ {NC 2B} Downgradient HW-1 SMP-1 Blanks MW- 106D MW- 107S MW- 107D MW- 108 Benzene 1 {51} 0.40 J ND 0.49 J 0.39 J ND Dry ND Chlorobenzene 50 {488} 6.3 ND 0.61 J 0.56 J ND Dry ND 1,4-Dichlorobenzene 6 {488} 5.7 ND 1.1 1.1 ND Dry ND Cis-1,2-Dichloroethylene 70 {NE} 2.5 J ND 0.75 J 1.4 J ND Dry ND Trichloroethene 3 {30} ND ND ND ND ND Dry ND 1. ND = Not detected above laboratory detection limits. 2. NC 2B are surface water standards. 3. NE = Not established. 4. NS = Not sampled 5. Dry = Dry and not sampled Second Semiannual Groundwater Monitoring Report of 2015 Joyce Engineering Transylvania County Calvert Landfill, Permit No. 88-03 December 2015 5 There were four quantified organic detection above the NC2L. Benzene and 1,4- dichlorobenzene in MW-3 and MW-105D was detected above its NC2L in MW-3 during the October 2015 monitoring event. No other organic constituents were detected above their NC 2L. In general, the results are consistent with historical data. Historical volatile organic data can be found in Table 3. 5.0 CONCLUSION Based on a comparison to historical groundwater data, the October 2015 sampling event results are generally consistent with previous events. The Transylvania County Calvert Landfill will continue monitoring groundwater in accordance with Detection Monitoring Program for Rule .0500 sites, while surface water will be monitored in accordance with Rule .0602. The next semiannual monitoring event is tentatively scheduled for April 2016. 6.0 REFERENCES Joyce Engineering, Inc., November 3, 1997. Monitoring Well Installation and Analysis. Prepared for Transylvania County Solid Waste. Joyce Engineering, Inc., March 13, 1998. Water Quality Assessment Plan. Prepared for Transylvania County Solid Waste. Joyce Engineering, Inc., December 13, 1999. Water Quality Assessment Plan. Prepared for Transylvania County Solid Waste. Horton, J.W., 1982, Geologic Map and Mineral Resources Summary of the Rosman Quadrangle, North Carolina; North Carolina Geological Survey Geologic Map 185-NE, North Carolina Department of Natural Resources and Community Development/Division of Land Resources. North Carolina Dept. Environment, Health, and Natural Resources (NCDEHNR), 1995, N.C. Water Quality Monitoring Guidance Document for Solid Waste Facilities. North Carolina Department of Environment and Natural Resources, 1990-2011, Solid Waste Management Regulations. RCRA Ground Water Monitoring Technical Enforcement Guidance Document (TEGD), 1986. U.S. Geological Survey. 1990 photo revision. Rosman, North Carolina Quadrangle, 7.5-minute series (topographic); scale 1:24,000. Tables Table 1 Summary of Historical Groundwater Elevations Table 2 Summary of Historical Inorganic Constituents Table 3 Summary of Historical Organic Constituents Table 4 Horizontal Groundwater Flow Velocities TABLE 1 SUMMARY OF HISTORICAL GROUNDWATER ELEVATIONS Transylvania County Calvert Landfill Joyce Engineering Background MW-1 MW-2 MW-3 MW-4 MW-105S MW-105D MW-106S MW-106D MW-107S MW-107D MW-108 TOC Elevation 2306.09 2282.67 2210.21 2327.55 2270.55 2270.76 2197.12 2197.62 2272.79 2273.57 2334.28 Well Depth 72.64 83.30 19.80 70.80 55.37 87.10 22.58 75.38 58.84 90.30 108.44 Apr-04 2247.91 2222.67 2206.71 2262.90 2221.10 2213.05 2189.04 2195.45 2226.79 2220.72 2241.45 Oct-04 2249.13 2223.92 2206.56 2263.54 2220.87 2213.52 2188.37 2195.53 2230.31 2222.54 2242.48 12-Apr-05 2249.57 2224.20 2206.98 2263.64 2221.25 2213.74 2188.27 2195.80 2229.03 2222.32 2243.18 12-Oct-05 2246.09 2223.55 2206.37 2263.36 2224.84 2214.42 2187.93 2190.04 2225.76 2219.39 2241.49 19-Apr-06 2244.98 2219.75 2205.99 2262.41 2221.94 2213.06 2187.89 2194.01 2225.45 2219.82 2238.59 18-Oct-06 2242.96 2214.17 2206.11 2257.55 2217.79 2210.70 2188.18 2194.79 2219.28 2218.08 2227.28 24-Apr-07 2249.70 2220.75 2206.24 2263.33 2219.77 2212.41 2188.22 2195.08 2227.87 2220.06 2240.83 16-Oct-07 2237.99 2212.65 2203.92 2257.88 2216.54 2209.01 2187.64 2193.21 2217.58 2216.78 2231.38 22-Apr-08 2249.09 2215.83 2205.90 2262.48 2218.19 2210.90 2188.09 2195.02 2227.05 2219.87 2233.70 22-Oct-08 2238.71 2211.72 2203.79 2257.83 2216.49 2208.42 2187.66 2193.07 2216.98 2216.75 2231.52 15-Apr-09 2253.04 2214.58 2206.25 2257.60 Dry 2210.39 2188.39 2194.67 2222.71 2219.28 2231.53 13-Oct-09 2251.18 2217.12 2206.31 2260.81 2218.47 2211.71 2188.14 2190.57 2222.66 2220.27 2234.87 21-Apr-10 2253.34 2227.89 2207.06 2265.05 2224.69 2215.03 2188.36 2196.17 2232.68 2223.82 2246.63 27-Oct-10 2239.70 2218.56 2206.00 2259.86 2220.57 2212.24 2188.20 2194.54 2219.88 2218.33 2232.70 18-Apr-11 2253.12 2222.40 2207.27 2263.37 2220.62 2213.59 2188.84 2196.32 2232.54 2222.49 2238.39 03-Oct-11 2242.75 2217.72 2205.56 2259.72 2219.14 2211.59 2188.31 2194.25 2213.95 2218.42 2232.28 02-Apr-12 2249.85 2218.27 2207.26 2262.91 2220.30 2213.66 2188.52 2195.67 2228.54 2221.02 2236.69 01-Oct-12 2248.51 2219.12 2206.92 2260.37 2219.67 2213.17 2188.43 2194.38 2222.36 2219.54 2233.75 22-Apr-13 2251.88 2223.13 2207.41 2263.20 2223.05 2217.26 2188.72 2195.30 2230.89 2222.07 2239.78 21-Oct-13 2249.19 2225.45 2207.31 2263.20 2222.97 2215.48 2188.36 2195.17 2228.24 2221.60 2241.73 21-Apr-14 2250.79 2225.63 2207.73 2263.37 2222.83 2216.06 2189.22 2195.62 2230.26 2222.20 2241.31 06-Oct-14 2239.05 2219.67 2206.39 2260.41 2220.35 2213.86 2188.52 2193.93 2221.51 2218.87 2233.28 20-Apr-15 2240.91 2219.07 2207.45 ---2220.53 2214.01 2189.43 2193.52 2226.63 2220.42 2232.67 19-Oct-15 2242.29 2215.32 2206.46 ---2219.40 2213.11 2188.92 2194.92 2220.95 2219.02 2231.78 Notes: 1. All elevations are referenced as feet above mean sea level. 2. All depths measured in feet (ft). 3. Dry = Monitoring well considered to be dry with no measureable water. Well I.D.Downgradient TABLE 2 SUMMARY OF HISTORICAL INORGANIC CONSTITUENTS Transylvania County Calvert Landfill Page 1 of 3 Joyce Engineering Sample Analyte Collection Date DL QL MW-1 MW-2 MW-3 MW-4 SMP-1 Field Blank INORGANICS Arsenic 04/22/10 2.7 10.0 3.40 B 7.40 B 9 B 5.8 B 3.20 B 4.00 J NC 2L = 10 µg/L (01/01/10)10/27/10 2.7 10.0 3.00 J 10.2 4.9 J ND ND ND NC 2B = 10 µg/L (05/01/07)04/18/11 2.7 10.0 ND ND ND ND ND ND 10/03/11 5.0 10.0 ND ND ND ND ---ND 04/02/12 5.0 10.0 ND 7.20 J ND ND ND ND 10/01/12 5.0 10.0 ND 6.70 J ND ND ND ND 04/22/13 5.0 10.0 ND ND ND ND ND ND 10/21/13 5.0 10.0 ND ND ND ND ND ND 04/21/14 5.0 10.0 ND ND ND ND ND ND 10/06/14 5.0 10.0 ND 18.7 ND ND ---ND 04/20/15 5.0 10.0 ND 9.0 J ND ---ND ND 10/19/15 2.5 10.0 ND ND ND ------ND Barium 04/22/10 0.2 100.0 77.9 B 148 67.8 B 31.4 B 150.0 25.50 J NC 2L = 700 µg/L (01/01/10)10/27/10 0.2 100.0 83.4 J 88.1 J 71 J 32 J 44.2 J ND NC 2B = NE µg/L (05/01/07)04/18/11 0.2 100.0 78.3 J 88.8 J 72.8 J 19.1 B 130.0 13.40 J 10/03/11 5.0 100.0 91.0 J 95.6 J 80.7 J 33.5 J ---ND 04/02/12 5.0 100.0 102 109 75.7 J 20 J 178.0 ND 10/01/12 5.0 100.0 73.5 J 83.8 J 91.9 J 30.8 J 122.0 ND 04/22/13 5.0 100.0 67.7 J 92.3 J 79.5 J 27.7 J 93.3 J ND 10/21/13 5.0 100.0 67.0 J 125 97.5 J 34.2 J ---ND 04/21/14 5.0 100.0 67.5 J 126 88.6 J 22.5 J 68.9 J 36.10 J 10/06/14 5.0 100.0 51.9 J 165 80.3 J 18.8 J ---ND 04/20/15 5.0 100.0 53.8 J 90.8 J 80.0 J ---39.3 J ND 10/19/15 2.5 100.0 76.7 J 80.8 J 80.5 J ------ND Cadmium 04/22/10 0.5 1.0 ND ND ND ND ND ND NC 2L = 2 µg/L (01/01/10)10/27/10 0.5 1.0 ND ND ND ND ND ND NC 2B = 2 µg/L (05/01/07)04/18/11 0.5 1.0 0.70 J ND ND ND ND ND 10/03/11 1.0 1.0 1.50 ND ND ND ---ND 04/02/12 1.0 1.0 ND 2.20 ND ND ND ND 10/01/12 1.0 1.0 ND ND ND ND ND ND 04/22/13 1.0 1.0 ND ND ND ND ND ND 10/21/13 1.0 1.0 ND ND 1.5 ND ND ND 04/21/14 1.0 1.0 ND ND ND ND ND ND 10/06/14 1.0 1.0 ND ND ND ND ---ND 04/20/15 1.0 1.0 0.68 J 0.57 J ND ---ND ND 10/19/15 0.5 1.0 1.9 ND ND ------ND Chromium 04/22/10 0.4 10.0 ND 2.90 J 0.75 J ND ND ND NC 2L = 10 µg/L (01/01/10)10/27/10 0.4 10.0 1.50 J ND 0.71 J ND ND ND NC 2B = 50 µg/L (05/01/07)04/18/11 0.4 10.0 ND ND 1.2 J ND ND ND 10/03/11 5.0 10.0 ND ND ND ND ---ND 04/02/12 5.0 10.0 ND ND ND ND ND ND 10/01/12 5.0 10.0 ND ND ND ND ND ND 04/22/13 5.0 10.0 ND ND ND ND ND ND 10/21/13 5.0 10.0 ND ND ND ND ND ND 04/21/14 5.0 10.0 ND ND ND ND ND ND 10/06/14 5.0 10.0 ND ND ND ND ---ND 04/20/15 5.0 10.0 ND ND ND ---ND ND 10/19/15 2.5 10.0 4.7 J 3.4 J 3.0 J ------ND TABLE 2 SUMMARY OF HISTORICAL INORGANIC CONSTITUENTS Transylvania County Calvert Landfill Page 2 of 3 Joyce Engineering Sample Analyte Collection Date DL QL MW-1 MW-2 MW-3 MW-4 SMP-1 Field Blank Lead 04/22/10 4.0 10.0 ND ND ND 8.6 J ND ND NC 2L = 15 µg/L (10/23/07)10/27/10 4.0 10.0 7.9 J ND ND 6 J ND ND NC 2B = 25 µg/L (05/01/07)04/18/11 4.0 10.0 ND 4.10 J ND ND ND ND 10/03/11 5.0 10.0 5.9 J ND ND 20.7 ---ND 04/02/12 5.0 10.0 9.4 J 9.10 J ND ND ND ND 10/01/12 5.0 10.0 ND 5.10 J 5.4 J 17.8 ND ND 04/22/13 5.0 10.0 ND ND ND ND ND ND 10/21/13 5.0 10.0 ND ND ND 7.9 J ND ND 04/21/14 5.0 10.0 ND ND 5.8 J ND ND ND 10/06/14 5.0 10.0 ND ND ND ND ---ND 04/20/15 5.0 10.0 ND 4.5 J ND ---ND ND 10/19/15 2.5 10.0 7.5 J 3.9 J ND ------ND Mercury 04/22/10 0.07 0.20 ND ND ND ND ND ND NC 2L = 1 µg/L (01/01/10)10/27/10 0.07 0.20 ND ND ND ND ND ND NC 2B = 0.012 µg/L (05/01/07)04/18/11 0.10 0.20 ND ND ND ND ND ND 10/03/11 0.10 0.20 ND ND ND ND ---ND 04/02/12 0.10 0.20 ND ND ND ND ND ND 10/01/12 0.10 0.20 ND ND ND ND ND ND 04/22/13 0.10 0.20 ND ND ND ND ND ND 10/21/13 0.10 0.20 ND ND ND ND ND 0.16 J 04/21/14 0.10 0.20 ND ND ND ND ND ND 10/06/14 0.10 0.20 ND ND ND ND ---ND 04/20/15 0.10 0.20 ND ND ND ---ND 10/19/15 0.10 0.20 ND ND ND ------ND Selenium 04/22/10 3.8 10.0 5.30 J ND ND ND ND ND NC 2L = 20 µg/L (01/01/10)10/27/10 3.8 10.0 ND ND ND ND ND 4.60 J NC 2B = 5 µg/L (05/01/07)04/18/11 3.8 10.0 ND ND ND ND ND ND 10/03/11 10.0 10.0 ND ND ND ND ---ND 04/02/12 10.0 10.0 ND ND ND ND ND ND 10/01/12 10.0 10.0 ND ND ND ND ND ND 04/22/13 10.0 10.0 ND ND ND ND ND ND 10/21/13 10.0 10.0 ND ND ND ND ND ND 04/21/14 10.0 10.0 ND ND ND ND ND ND 10/06/14 10.0 10.0 ND ND ND ND ---ND 04/20/15 10.0 10.0 ND ND ND ---ND ND 10/19/15 5.0 10.0 ND ND ND ------ND TABLE 2 SUMMARY OF HISTORICAL INORGANIC CONSTITUENTS Transylvania County Calvert Landfill Page 3 of 3 Joyce Engineering Sample Analyte Collection Date DL QL MW-1 MW-2 MW-3 MW-4 SMP-1 Field Blank Silver 04/22/10 0.1 10.0 ND ND ND ND ND ND NC 2L = 20 µg/L (01/01/10)10/27/10 0.1 10.0 ND ND ND ND ND ND NC 2B = 0.06 µg/L (05/01/07)04/18/11 0.1 10.0 ND ND ND ND ND ND 10/03/11 5.0 10.0 ND ND ND ND ---ND 04/02/12 5.0 10.0 ND ND ND ND ND ND 10/01/12 5.0 10.0 ND ND ND ND ND ND 04/22/13 5.0 10.0 ND ND ND ND ND ND 10/21/13 5.0 10.0 ND ND ND ND ND ND 04/21/14 5.0 10.0 ND ND ND ND ND ND 10/06/14 5.0 10.0 ND ND ND ND ---ND 04/20/15 5.0 10.0 ND ND ND ---ND ND 10/19/15 2.5 10.0 ND 4.3 J ND ------ND Notes: QL = Quantiation Limit ND = Not detected at or above the detection or reporting limit. J = Estimated value since the concentration is between the DL and the SWSL. --- = Not sampled and or Not Reported DL = Laboratory detection limit. NC 2L = North Carolina's groundwater quality standard established under 15A NCAC 2L, .0202. NC 2B = North Carolina 2B Surface Water Standards. The surface water at the sampling location is classified as Class C. NC 2B Standard is used to define concentration limits for surface water constituents. Bold concentrations are greater than the NC 2L for groundwater or NC 2B for surface water. NE = Not established. NV= Values considered to be not valid due to laboratory exceeding hold times for analysis All historical data prior to April 2010 is avaliable upon request TA B L E 3 SU M M A R Y O F H I S T O R I C A L O R G A N I C C O N S T I T U E N T S Sa m p l e An a l y t e Co l l e c t i o n D a t e D L Q L M W - 1 M W - 2 M W - 3 M W - 4 M W - 1 0 5 S M W - 1 0 5 D M W - 1 0 6 S M W - 1 0 6 D M W - 1 0 7 S M W - 1 0 7 D M W - 1 0 8 H W - 1 S M P - 1 F i e l d B l a n k Or g a n i c C o m p o u n d s Ac e t o n e 0 4 / 2 2 / 1 0 2 . 2 1 0 0 N D N D N D 1 3 . 9 J 1 3 . 9 0 J N D N D N D 1 1 . 3 0 J N D 4 4 . 3 J N D N D N D NC 2 L = 6 , 0 0 0 µ g / L ( 0 1 / 0 1 / 1 0 ) 1 0 / 2 7 / 1 0 2 . 2 1 0 0 3 . 0 0 B 2 . 4 0 B N D 2 4 8 5 . 9 0 B 9 . 7 0 B N D 2 . 5 B 8 . 1 0 B 4 . 2 0 B 2 8 . 7 B N D 2 . 9 0 B 4 . 5 0 J NC 2 B = N E µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 2 . 2 1 0 0 3 . 0 0 B N D N D 4 . 7 B 3 . 0 0 B N D N D N D 6 . 7 0 B 2 . 3 0 B 1 1 . 5 B N D 3 . 5 0 B 3 . 3 0 J 10 / 0 3 / 1 1 2 . 2 1 0 0 N D N D N D 6 1 2 N D N D N D N D 5 . 0 0 J 4 . 1 0 J N D N D - - - N D 04 / 0 2 / 1 2 2 . 2 1 0 0 N D N D N D 5 2 6 N D N D N D N D 1 1 . 1 0 J N D N D N D N D N D 10 / 0 1 / 1 2 1 0 1 0 0 N D N D N D 4 6 . 1 J N D N D N D N D N D N D N D N D N D N D 04 / 2 2 / 1 3 1 0 1 0 0 N D N D N D N D N D N D N D N D N D N D 2 1 . 5 B N D N D 3 8 . 6 J 10 / 2 1 / 1 3 1 0 1 0 0 N D N D N D N D N D N D N D N D N D N D 7 1 . 6 J N D N D N D 04 / 2 1 / 1 4 1 0 1 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 6 / 1 4 1 0 1 0 0 N D N D N D 2 9 . 8 J N D N D N D N D N D N D N D N D - - - N D 04 / 2 0 / 1 5 1 0 1 0 0 N D N D N D - - - N D N D N D N D N D N D N D N D N D 1 0 . 0 J 10 / 1 9 / 1 5 1 0 1 0 0 N D N D N D - - - N D N D N D N D N D N D 1 9 . 8 J N D - - - N D Be n z e n e 0 4 / 2 2 / 1 0 0 . 2 5 1 . 0 N D 0 . 6 4 J 1.7 1 . 3 1 . 2 0 1.0 0 N D 0 . 4 8 J N D 0 . 9 7 J 0 . 6 9 J N D N D N D NC 2 L = 1 µ g / L ( 1 0 / 2 3 / 0 7 ) 1 0 / 2 7 / 1 0 0 . 2 5 1 . 0 N D 0 . 7 5 J 1.3 0. 8 5 J 0 . 9 3 J N D N D 0 . 4 5 J N D 0 . 4 6 J 0 . 5 1 J N D N D N D NC 2 B = 5 1 µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 0 . 2 5 1 . 0 N D 0 . 6 6 J 1.5 0. 9 5 J 0 . 8 9 J 1.1 ND 0 . 4 7 J N D 0 . 6 4 J 0 . 4 7 J N D N D N D 10 / 0 3 / 1 1 0 . 2 5 1 . 0 N D 1.1 0 1 . 1 ND 0 . 8 9 J 1.3 ND 0 . 5 1 J N D 0 . 4 9 J 0 . 5 3 J N D - - - N D 04 / 0 2 / 1 2 0 . 2 5 1 . 0 N D 0 . 5 9 J 1.2 1 . 2 0.8 1 J 1.3 ND N D N D N D N D N D N D N D 10 / 0 1 / 1 2 0 . 2 5 1 . 0 N D 0 . 8 5 J 1.1 0.7 J 0 . 8 7 J 1.4 ND 0 . 4 4 J N D 0 . 5 1 J 0 . 4 7 J N D N D N D 04 / 2 2 / 1 3 0 . 2 5 1 . 0 N D 0 . 7 1 J 1.3 1 . 1 1 . 1 1 . 6 ND 0 . 4 J N D 0 . 9 4 J 0 . 6 6 J N D N D N D 10 / 2 1 / 1 3 0 . 2 5 1 . 0 N D 0 . 7 0 J 0 . 8 J 1.1 1. 0 1.8 ND 0 . 3 1 J N D 0 . 6 4 J 0 . 5 2 J N D N D N D 04 / 2 1 / 1 4 0 . 2 5 1 . 0 N D 0 . 6 4 J 0 . 8 8 J 1.1 1. 0 1.9 ND 0 . 3 3 J N D 0 . 7 1 J 0 . 5 2 J N D N D N D 10 / 0 6 / 1 4 0 . 2 5 1 . 0 N D 0 . 4 8 J 0 . 6 8 J 0 . 9 8 J 0 . 8 3 J 1.9 ND 0 . 4 2 J N D 0 . 6 1 J N D N D - - - N D 04 / 2 0 / 1 5 0 . 2 5 1 . 0 N D 0 . 5 3 J 0 . 9 2 J - - - 0 . 5 7 J 0 . 9 2 J N D N D N D 0 . 4 1 J N D N D N D N D 10 / 1 9 / 1 5 0 . 2 5 1 . 0 N D 0 . 6 8 J 1.1 --- 0 . 8 0 J 2.2 ND 0 . 4 0 J N D 0 . 4 9 J 0 . 3 9 J N D - - - N D Ca r b o n D i s u l f i d e 0 4 / 0 2 / 1 2 1 . 2 1 0 0 . 0 N D N D N D N D N D N D N D N D 1 . 8 0 J N D N D N D N D N D NC 2 L = 7 0 0 µ g / L ( 1 0 / 2 3 / 0 7 ) 1 0 / 0 1 / 1 2 1 . 2 1 0 0 . 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D NC 2 B = N E µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 2 2 / 1 3 1 . 2 1 0 0 . 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 2 1 / 1 3 1 . 2 1 0 0 . 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 04 / 2 1 / 1 4 1 . 2 1 0 0 . 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 6 / 1 4 1 . 2 1 0 0 . 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - N D 04 / 2 0 / 1 5 1 . 2 1 0 0 . 0 N D N D N D - - - N D N D N D N D N D N D N D N D N D N D 10 / 1 9 / 1 5 1 . 2 1 0 0 . 0 N D N D N D - - - N D N D N D N D N D N D N D N D - - - N D Ch l o r o b e n z e n e 0 4 / 2 2 / 1 0 0 . 2 3 3 . 0 0 N D 0 . 3 7 J 1 0 . 2 3 . 9 3 . 0 0 1 0 . 6 0 0 . 7 6 J 5 . 2 N D 1 . 4 0 J N D N D N D N D NC 2 L = 5 0 µ g / L ( 1 0 / 2 3 / 0 7 ) 1 0 / 2 7 / 1 0 0 . 2 3 3 . 0 0 N D 0 . 9 2 J 1 0 . 6 5 . 2 2 . 6 0 J 2 . 4 0 J 1 . 7 J 6 . 9 N D 0 . 8 9 J 0 . 5 9 J N D N D N D NC 2 B = 4 8 8 µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 0 . 2 3 3 . 0 0 N D 0 . 6 3 J 1 1 3 . 2 2 . 4 0 J 8 . 6 0 0 . 4 2 J 6 . 3 0 . 2 7 J 1 . 1 0 J 0 . 4 J N D N D N D 10 / 0 3 / 1 1 0 . 2 3 3 . 0 0 N D 1 . 1 0 J 1 2 . 1 4 . 7 2 . 6 0 J 8 . 3 0 0 . 7 6 J 7 . 9 N D 0 . 7 7 J 0 . 6 3 J N D - - - N D 04 / 0 2 / 1 2 0 . 2 3 3 . 0 0 N D 0 . 5 0 J 1 0 . 6 3 . 3 2 . 6 0 J 8 . 0 0 0 . 2 4 J 5 . 9 N D 0 . 8 9 J 0 . 7 5 J N D N D N D 10 / 0 1 / 1 2 0 . 2 3 3 . 0 0 N D 0 . 8 7 J 1 1 . 5 2 . 8 J 2 . 6 0 J 7 . 8 0 N D 7 . 1 N D 0 . 8 3 J 0 . 6 2 J N D N D N D 04 / 2 2 / 1 3 0 . 2 3 . 0 N D 0 . 5 2 J 1 1 . 4 2 . 6 J 2 . 7 0 J 8 . 5 0 0 . 5 5 J 6 . 6 N D 1 . 2 0 0 . 5 J N D N D N D 10 / 2 1 / 1 3 0 . 2 3 . 0 N D 0 . 5 5 J 1 1 . 9 3 . 1 2 . 9 0 J 1 0 . 1 0 N D 4 . 9 N D 0 . 9 2 J 0 . 3 J N D N D N D 04 / 2 1 / 1 4 0 . 2 3 . 0 N D 0 . 5 1 J 1 3 . 7 3 . 5 2 . 7 J 1 0 . 0 N D 5 . 5 N D 1 . 0 J 0 . 3 4 J N D N D N D 10 / 0 6 / 1 4 0 . 2 3 . 0 N D 0 . 4 9 J 1 2 . 1 3 . 1 2 . 8 J 8 . 0 0 . 2 6 J 6 . 8 N D 0 . 8 8 J 0 . 5 8 J N D - - - N D 04 / 2 0 / 1 5 0 . 2 3 . 0 N D 0 . 5 9 J 1 0 . 7 - - - 2 . 3 J 6 . 0 N D N D N D 0 . 7 4 J 0 . 6 6 J N D N D N D 10 / 1 9 / 1 5 0 . 2 3 . 0 N D 0 . 5 9 J 1 0 . 8 - - - 2 . 6 J 1 2 . 2 N D 6 . 3 N D 0 . 6 1 J 0 . 5 6 J N D - - - N D Ch l o r o e t h a n e 0 4 / 2 2 / 1 0 0 . 5 4 1 0 . 0 N D N D N D N D N D N D N D N D N D 1 . 9 0 J N D N D N D N D NC 2 L = 3 , 0 0 0 µ g / L ( 0 1 / 0 1 / 1 0 ) 1 0 / 2 7 / 1 0 0 . 5 4 1 0 . 0 N D N D N D 1 . 9 J N D N D N D N D N D N D 1 . 1 J N D N D N D NC 2 B = N E µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 0 . 5 4 1 0 . 0 N D N D N D 2 . 4 J N D N D N D N D N D 1 . 2 0 J 1 . 7 J N D N D N D 10 / 0 3 / 1 1 0 . 5 4 1 0 . 0 N D N D N D 1 . 9 J N D N D N D N D N D 0 . 9 5 J 1 . 3 J N D - - - N D 04 / 0 2 / 1 2 0 . 5 4 1 0 . 0 N D N D N D 2 . 9 J N D N D N D N D N D N D 2 . 3 J N D N D N D 10 / 0 1 / 1 2 0 . 5 4 1 0 . 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 04 / 2 2 / 1 3 0 . 5 4 1 0 . 0 N D N D N D N D N D N D N D N D N D N D 0 . 9 8 J N D N D N D 10 / 2 1 / 1 3 0 . 5 4 1 0 . 0 N D N D N D 1 . 1 J N D N D N D N D N D 0 . 7 1 J 0 . 6 6 J N D N D N D 04 / 2 1 / 1 4 0 . 5 4 1 0 . 0 N D N D N D 1 . 6 J N D N D N D N D N D 0 . 9 2 J N D N D N D N D 10 / 0 6 / 1 4 0 . 5 4 1 0 . 0 N D N D N D 1 . 5 J N D N D N D N D N D N D 0 . 9 6 J N D - - - N D 04 / 2 0 / 1 5 0 . 5 4 1 0 . 0 N D N D N D - - - N D N D N D N D N D 0 . 8 0 J N D N D N D N D 10 / 1 9 / 1 5 0 . 5 4 1 0 . 0 N D N D N D - - - N D N D N D N D N D 0 . 7 5 J 1 . 2 J N D - - - N D Tr a n s y l v a n i a C o u n t y C a l v e r t L a n d f i l l P a g e 1 o f 6 J o y c e E n g i n e e r i n g TA B L E 3 SU M M A R Y O F H I S T O R I C A L O R G A N I C C O N S T I T U E N T S Sa m p l e An a l y t e Co l l e c t i o n D a t e D L Q L M W - 1 M W - 2 M W - 3 M W - 4 M W - 1 0 5 S M W - 1 0 5 D M W - 1 0 6 S M W - 1 0 6 D M W - 1 0 7 S M W - 1 0 7 D M W - 1 0 8 H W - 1 S M P - 1 F i e l d B l a n k Ch l o r o f o r m 0 4 / 2 2 / 1 0 0 . 1 4 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D 1 . 6 J N D N D NC 2 L = 7 0 µ g / L ( 1 0 / 2 3 / 0 7 ) 1 0 / 2 7 / 1 0 0 . 1 4 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D 0 . 5 2 J N D N D NC 2 B = N E µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 0 . 1 4 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D 3 . 2 J N D N D 10 / 0 3 / 1 1 0 . 1 4 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - N D 04 / 0 2 / 1 2 0 . 1 4 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D 1 . 8 J N D N D 10 / 0 1 / 1 2 0 . 1 4 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D 0 . 9 7 J N D N D 04 / 2 2 / 1 3 0 . 1 4 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D 2 . 7 J N D N D 10 / 2 1 / 1 3 0 . 1 4 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D 1 . 1 J N D N D 04 / 2 1 / 1 4 0 . 1 4 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D 0 . 7 2 J N D N D 10 / 0 6 / 1 4 0 . 1 4 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - N D 04 / 2 0 / 1 5 0 . 1 4 5 . 0 0 N D N D N D - - - N D N D N D N D N D N D N D N D N D N D 10 / 1 9 / 1 5 0 . 1 4 5 . 0 0 N D N D N D - - - N D N D N D N D N D N D N D 0 . 5 6 J - - - N D Ch l o r o m e t h a n e 0 4 / 2 2 / 1 0 0 . 1 1 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D NC 2 L = 3 µ g / L ( 0 1 / 0 1 / 1 0 ) 1 0 / 2 7 / 1 0 0 . 1 1 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D 0 . 1 3 B N D 0 . 1 9 J NC 2 B = N E µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 0 . 1 1 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 3 / 1 1 0 . 1 1 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - N D 04 / 0 2 / 1 2 0 . 1 1 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 1 / 1 2 0 . 1 1 1 . 0 0 . 1 9 J N D N D N D N D N D N D N D N D N D N D N D N D N D 04 / 2 2 / 1 3 0 . 1 1 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 2 1 / 1 3 0 . 1 1 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 04 / 2 1 / 1 4 0 . 1 1 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 6 / 1 4 0 . 1 1 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - N D 04 / 2 0 / 1 5 0 . 1 1 1 . 0 0 N D N D N D - - - N D N D N D N D N D N D N D N D N D N D 10 / 1 9 / 1 5 0 . 1 1 1 . 0 0 N D N D N D - - - N D N D N D N D N D N D N D N D - - - N D 1,2 - D i c h l o r o b e n z e n e 0 4 / 2 2 / 1 0 0 . 3 5 . 0 0 N D N D 0 . 7 9 J N D N D N D N D 0 . 3 9 J N D N D N D N D N D N D NC 2 L = 2 0 µ g / L ( 0 1 / 0 1 / 1 0 ) 1 0 / 2 7 / 1 0 0 . 3 5 . 0 0 N D N D 0 . 8 J N D N D N D N D 0 . 4 6 J N D N D N D N D N D N D NC 2 B = 4 8 8 µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 0 . 3 5 . 0 0 N D N D 0 . 7 4 J N D N D N D N D 0 . 4 1 J N D N D N D N D N D N D 10 / 0 3 / 1 1 0 . 3 5 . 0 0 N D N D 0 . 9 5 J N D N D N D N D 0 . 4 8 J N D N D N D N D - - - N D 04 / 0 2 / 1 2 0 . 3 5 . 0 0 N D N D 0 . 7 5 J N D N D N D N D N D N D N D N D N D N D N D 10 / 0 1 / 1 2 0 . 3 5 . 0 0 N D N D 0 . 7 9 J N D N D N D N D 0 . 3 8 J N D N D N D N D N D N D 04 / 2 2 / 1 3 0 . 3 5 . 0 0 N D N D 0 . 7 9 J N D N D N D N D 0 . 4 1 J N D N D N D N D N D N D 10 / 2 1 / 1 3 0 . 3 5 . 0 0 N D N D 0 . 8 2 J N D N D N D N D N D N D N D N D N D N D N D 04 / 2 1 / 1 4 0 . 3 5 . 0 0 N D N D 0 . 8 9 J N D N D N D N D 0 . 3 0 J N D N D N D N D N D N D 10 / 0 6 / 1 4 0 . 3 5 . 0 0 N D N D 0 . 8 2 J N D N D N D N D 0 . 3 6 J N D N D N D N D - - - N D 04 / 2 0 / 1 5 0 . 3 5 . 0 0 N D N D 0 . 7 3 J - - - N D N D N D N D N D N D N D N D N D N D 10 / 1 9 / 1 5 0 . 3 5 . 0 0 N D N D 0 . 7 5 J - - - N D N D N D 0 . 3 7 J N D N D N D N D - - - N D 1,4 - D i c h l o r o b e n z e n e 0 4 / 2 2 / 1 0 0 . 3 1 . 0 N D 0 . 3 4 J 15 . 2 2.2 4 . 3 6.1 1. 2 6. 2 ND 1 . 8 1 . 6 N D N D N D NC 2 L = 6 µ g / L ( 0 1 / 0 1 / 1 0 ) 1 0 / 2 7 / 1 0 0 . 3 1 . 0 N D 1 . 1 0 15 . 3 2.9 4 . 0 1 . 9 2 . 4 7. 7 ND 1 . 5 1 . 3 N D N D N D NC 2 B = 4 8 8 µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 0 . 3 1 . 0 N D 0 . 6 2 J 14 . 5 3.2 2 . 7 5 . 8 0 . 7 1 J 6. 5 ND 1 . 5 1 . 9 N D N D N D 10 / 0 3 / 1 1 0 . 3 1 . 0 N D 1 . 3 0 14 . 7 2.6 3 . 1 5 . 9 1 . 2 7. 8 ND 1 . 3 0 1 . 7 N D - - - N D 04 / 0 2 / 1 2 0 . 3 1 . 0 N D N D 13 . 8 3 2 . 9 5 . 4 0 . 5 8 J 6. 3 ND 1 . 3 0 2 . 1 N D N D N D 10 / 0 1 / 1 2 0 . 3 1 . 0 N D 0 . 9 J 14 . 2 2.3 2 . 7 5 . 6 0 . 7 2 J 7. 1 ND 1 . 2 0 1 . 6 N D N D N D 04 / 2 2 / 1 3 0 . 3 1 . 0 N D 0 . 5 J 13 . 8 2.9 2 . 3 5 . 0 0 . 9 3 J 7. 0 ND 1 . 4 0 3 . 2 N D N D N D 10 / 2 1 / 1 3 0 . 3 1 . 0 N D 0 . 5 J 13 . 5 2.1 2 . 5 5 . 8 0 . 3 5 J 5 . 1 N D 1 . 2 0 1 . 8 N D N D N D 04 / 2 1 / 1 4 0 . 3 1 . 0 N D 0 . 5 J 14 . 1 2.2 2 . 5 5 . 1 0 . 3 7 J 5 . 5 N D 1 . 2 0 1 . 2 N D N D N D 10 / 0 6 / 1 4 0 . 3 1 . 0 N D 0 . 5 7 J 12 . 5 2.7 2 . 7 4 . 1 0 . 3 5 J 6. 1 ND 1 . 2 0 1 . 1 N D - - - N D 04 / 2 0 / 1 5 0 . 3 1 . 0 N D 0 . 5 6 J 12 . 6 --- 2 . 2 3 . 4 N D N D N D 0 . 9 6 J 0 . 7 7 J N D N D N D 10 / 1 9 / 1 5 0 . 3 1 . 0 N D 0 . 6 1 J 13 . 1 --- 2 . 4 6 . 7 N D 5 . 7 N D 1 . 1 1 . 1 N D - - - N D Dic h l o r o d i f l u o r o m e t h a n e 0 4 / 2 2 / 1 0 0 . 2 1 5 . 0 0 - - - - - - - - - - - - 0 . 7 2 J 1 . 4 0 J - - - - - - - - - - - - - - - - - - - - - N D NC 2 L = 1 , 0 0 0 µ g / L ( 0 1 / 0 1 / 1 0 ) 1 0 / 2 7 / 1 0 0 . 2 1 5 . 0 0 - - - - - - - - - - - - 1 . 0 0 J N D - - - - - - - - - - - - - - - - - - - - - N D NC 2 B = N E µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 0 . 2 1 5 . 0 0 - - - - - - - - - - - - 1 . 1 0 J 0 . 6 4 J - - - - - - - - - - - - - - - - - - - - - N D 10 / 0 3 / 1 1 0 . 2 1 5 . 0 0 - - - - - - - - - - - - 1 . 2 0 J 0 . 7 0 J - - - - - - - - - - - - - - - - - - - - - N D 04 / 0 2 / 1 2 0 . 2 1 5 . 0 0 - - - - - - - - - - - - N D N D - - - - - - - - - - - - - - - - - - - - - N D 10 / 0 1 / 1 2 0 . 2 1 5 . 0 0 - - - - - - - - - - - - 2 . 0 J 0 . 5 2 J - - - - - - - - - - - - - - - - - - - - - N D 04 / 2 2 / 1 3 0 . 2 1 5 . 0 - - - - - - - - - - - - 2 . 6 J N D - - - - - - - - - - - - - - - - - - - - - N D 10 / 2 1 / 1 3 0 . 2 1 5 . 0 0 - - - - - - - - - - - - 2 . 0 J N D - - - - - - - - - - - - - - - N D - - - N D 04 / 2 1 / 1 4 0 . 2 1 5 . 0 0 - - - - - - - - - - - - 2 . 7 J 0 . 4 7 J - - - - - - - - - - - - - - - - - - - - - N D 10 / 0 6 / 1 4 0 . 2 1 5 . 0 0 - - - - - - - - - - - - 1 . 7 J N D - - - - - - - - - - - - - - - - - - - - - N D 04 / 2 0 / 1 5 0 . 2 1 5 . 0 0 - - - - - - - - - - - - 1 . 3 J N D - - - - - - - - - - - - - - - - - - - - - N D 10 / 1 9 / 1 5 0 . 2 1 5 . 0 0 - - - - - - - - - - - - 1 . 5 J 0 . 8 2 J - - - - - - - - - - - - - - - - - - - - - N D Tr a n s y l v a n i a C o u n t y C a l v e r t L a n d f i l l P a g e 2 o f 6 J o y c e E n g i n e e r i n g TA B L E 3 SU M M A R Y O F H I S T O R I C A L O R G A N I C C O N S T I T U E N T S Sa m p l e An a l y t e Co l l e c t i o n D a t e D L Q L M W - 1 M W - 2 M W - 3 M W - 4 M W - 1 0 5 S M W - 1 0 5 D M W - 1 0 6 S M W - 1 0 6 D M W - 1 0 7 S M W - 1 0 7 D M W - 1 0 8 H W - 1 S M P - 1 F i e l d B l a n k 1,1 - D i c h l o r o e t h a n e 0 4 / 2 2 / 1 0 0 . 3 2 5 . 0 N D N D N D 15 . 5 ND 0 . 3 7 J N D 0 . 3 7 J N D 2 . 5 0 J 1 . 4 J N D N D N D NC 2 L = 6 µ g / L ( 0 1 / 0 1 / 1 0 ) 1 0 / 2 7 / 1 0 0 . 3 2 5 . 0 N D N D 0 . 3 9 J 13 . 3 ND N D 0 . 4 2 J 0 . 4 J N D 1 . 7 0 J 3 . 7 J N D N D N D NC 2 B = N E µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 0 . 3 2 5 . 0 N D N D N D 10 . 0 ND 0 . 4 1 J N D 0 . 3 6 J N D 1 . 9 0 J 3 . 8 J N D N D N D 10 / 0 3 / 1 1 0 . 3 2 5 . 0 N D N D N D 10 . 8 ND 0 . 5 6 J N D N D N D 1 . 7 0 J 3 J N D - - - N D 04 / 0 2 / 1 2 0 . 3 2 5 . 0 N D N D N D 6.6 ND N D N D N D N D 1 . 3 0 J 3 . 2 J N D N D N D 10 / 0 1 / 1 2 0 . 3 2 5 . 0 N D N D 0 . 3 5 J 6.7 ND 0 . 3 7 J N D 0 . 3 9 J N D 1 . 2 0 J 2 . 6 J N D N D N D 04 / 2 2 / 1 3 0 . 3 2 5 . 0 N D N D N D 9.4 ND N D N D 0 . 3 8 J N D 1 . 6 0 J 2 . 7 J N D N D N D 10 / 2 1 / 1 3 0 . 3 2 5 . 0 N D N D N D 5 . 9 N D N D N D N D N D 1 . 0 0 J 0 . 6 1 J N D N D N D 04 / 2 1 / 1 4 0 . 3 2 5 . 0 N D N D N D 6.2 ND N D N D N D N D 0 . 9 9 J 0 . 8 1 J N D N D N D 10 / 0 6 / 1 4 0 . 3 2 5 . 0 N D N D N D 4 . 7 J N D N D N D N D N D 0 . 6 7 J 1 . 5 J N D N D N D 04 / 2 0 / 1 5 0 . 3 2 5 . 0 N D N D N D - - - N D N D N D N D N D 0 . 7 8 J 2 . 3 J N D N D N D 10 / 1 9 / 1 5 0 . 3 2 5 . 0 N D N D N D - - - N D N D N D N D N D 0 . 7 4 J 1 . 6 J N D - - - N D 1,2 - D i c h l o r o e t h a n e 0 4 / 2 2 / 1 0 0 . 1 2 1 . 0 0 N D N D N D N D N D 0 . 4 9 J N D 0 . 2 6 J N D N D N D N D N D N D NC 2 L = 0 . 4 µ g / L ( 0 1 / 0 1 / 1 0 ) 1 0 / 2 7 / 1 0 0 . 1 2 1 . 0 0 N D N D N D N D N D N D N D 0 . 2 9 J N D N D N D N D N D N D NC 2 B = N E µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 0 . 1 2 1 . 0 0 N D N D 0 . 3 4 J N D N D N D N D N D 0 . 4 9 J N D N D N D N D N D 10 / 0 3 / 1 1 0 . 1 2 1 . 0 0 N D N D N D N D N D 0 . 3 4 J N D N D N D N D N D N D - - - N D 04 / 0 2 / 1 2 0 . 1 2 1 . 0 0 0 . 1 8 J N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 1 / 1 2 0 . 1 2 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 04 / 2 2 / 1 3 0 . 1 2 1 . 0 0 N D N D N D N D N D 0 . 2 9 J N D N D N D N D N D N D N D N D 10 / 2 1 / 1 3 0 . 1 2 1 . 0 0 N D N D N D N D N D 0 . 2 5 J N D N D N D N D N D N D N D N D 04 / 2 1 / 1 4 0 . 1 2 1 . 0 0 N D N D N D N D N D 0 . 3 2 J N D 0 . 1 7 J N D N D N D N D N D N D 10 / 0 6 / 1 4 0 . 1 2 1 . 0 0 N D N D N D N D N D 0 . 1 5 J N D N D N D N D N D N D - - - N D 04 / 2 0 / 1 5 0 . 1 2 1 . 0 0 N D N D N D - - - N D N D N D N D N D N D N D N D N D N D 10 / 1 9 / 1 5 0 . 2 4 1 . 0 0 N D N D N D - - - N D 0 . 5 0 J N D 0 . 2 9 J N D N D N D N D - - - N D 1,1 - D i c h l o r o e t h e n e 0 4 / 2 2 / 1 0 0 . 5 6 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D NC 2 L = 7 µ g / L ( 1 0 / 2 3 / 0 7 ) 1 0 / 2 7 / 1 0 0 . 5 6 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D NC 2 B = N E µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 0 . 5 6 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 3 / 1 1 0 . 5 6 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - N D 04 / 0 2 / 1 2 0 . 5 6 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 1 / 1 2 0 . 5 6 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D NC 2 L = 3 5 0 µ g / L ( 0 4 / 0 1 / 2 0 1 3 ) 0 4 / 2 2 / 1 3 0 . 5 6 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 2 1 / 1 3 0 . 5 6 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 04 / 2 1 / 1 4 0 . 5 6 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 6 / 1 4 0 . 5 6 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - N D 04 / 2 0 / 1 5 0 . 5 6 5 . 0 0 N D N D N D - - - N D N D N D N D N D N D N D N D N D N D 10 / 1 9 / 1 5 0 . 5 6 5 . 0 0 N D N D N D - - - N D N D N D N D N D N D N D N D - - - N D Cis - 1 , 2 - D i c h l o r o e t h e n e 0 4 / 2 2 / 1 0 0 . 1 9 5 . 0 0 N D 1 . 6 0 J 1 . 2 J 1 0 . 6 2 . 5 0 J 1 6 . 9 0 1 . 9 J 4 . 1 J N D 1 . 2 0 J 3 . 6 J N D N D N D NC 2 L = 7 0 µ g / L ( 1 0 / 2 3 / 0 7 ) 1 0 / 2 7 / 1 0 0 . 1 9 5 . 0 0 N D 2 . 2 0 J 1 . 5 J 1 1 . 1 2 . 4 0 J 5 . 4 3 . 1 J 4 . 1 J N D 1 . 1 0 J 2 . 9 J N D N D N D NC 2 B = N E µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 0 . 1 9 5 . 0 0 N D 1 . 5 0 J 1 . 4 J 9 . 5 1 . 6 0 J 1 8 . 6 1 . 4 J 4 J N D 1 . 1 0 J 4 . 6 J N D N D N D 10 / 0 3 / 1 1 0 . 1 9 5 . 0 0 N D 2 . 4 0 J 1 . 4 J 1 0 . 4 1 . 7 0 J 1 8 . 4 2 . 1 J 4 . 5 J N D 1 . 0 0 J 3 . 5 J N D - - - N D 04 / 0 2 / 1 2 0 . 1 9 5 . 0 0 N D 1 . 3 0 J 0 . 9 9 J 7 . 4 1 . 2 0 J 1 5 . 8 1 . 1 J 3 . 9 J N D 0 . 6 9 J 4 . 8 J N D N D N D 10 / 0 1 / 1 2 0 . 1 9 5 . 0 0 N D 1 . 8 0 J 1 J 5 . 7 1 . 0 0 J 1 5 . 0 1 J 3 . 7 J N D 0 . 8 0 J 3 . 3 J N D N D N D 04 / 2 2 / 1 3 0 . 1 9 5 . 0 0 N D 1 . 4 0 J 1 . 1 J 8 . 6 0 . 9 7 J 1 5 . 1 1 . 7 J 4 . 1 J N D 0 . 7 6 J 8 N D N D N D 10 / 2 1 / 1 3 0 . 1 9 5 . 0 0 N D 1 . 1 0 J 0 . 9 7 J 4 . 7 J 0 . 8 3 J 1 2 . 1 0 . 9 3 J 2 . 6 J N D 0 . 7 1 J 2 . 2 J N D N D N D 04 / 2 1 / 1 4 0 . 1 9 5 . 0 0 N D 1 . 1 0 J 1 . 3 J 4 . 9 J 0 . 7 9 J 1 2 . 6 1 . 0 J 2 . 8 J N D 0 . 6 7 J 2 . 1 J N D N D N D 10 / 0 6 / 1 4 0 . 1 9 5 . 0 0 N D 0 . 9 4 J 1 . 2 J 4 . 4 J 0 . 8 7 J 1 2 . 3 1 . 0 J 3 . 0 J N D 0 . 5 8 J 1 . 2 J N D - - - N D 04 / 2 0 / 1 5 0 . 1 9 5 . 0 0 N D 0 . 8 9 J 0 . 9 9 J - - - 0 . 7 8 J 8 . 9 0 . 8 0 2 . 7 N D 0 . 5 8 J 1 . 2 J N D N D N D 10 / 1 9 / 1 5 0 . 1 9 5 . 0 0 N D 0 . 9 5 J 0 . 9 0 J - - - 0 . 6 5 J 1 3 . 4 0 . 9 1 J 2 . 5 J N D 0 . 7 5 J 1 . 4 J N D - - - N D Tr a n s - 1 , 2 - D i c h l o r o e t h e n e 0 4 / 2 2 / 1 0 0 . 4 9 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D NC 2 L = 1 0 0 µ g / L ( 1 0 / 2 3 / 0 7 ) 1 0 / 2 7 / 1 0 0 . 4 9 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D NC 2 B = N E µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 0 . 4 9 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 3 / 1 1 0 . 4 9 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - N D 04 / 0 2 / 1 2 0 . 4 9 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 1 / 1 2 0 . 4 9 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 04 / 2 2 / 1 3 0 . 4 9 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 2 1 / 1 3 0 . 4 9 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 04 / 2 1 / 1 4 0 . 4 9 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 6 / 1 4 0 . 4 9 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - N D 04 / 2 0 / 1 5 0 . 4 9 5 . 0 0 N D N D N D - - - N D N D N D N D N D N D N D N D N D N D 10 / 1 9 / 1 5 0 . 4 9 5 . 0 0 N D N D N D - - - N D N D N D N D N D N D N D N D - - - N D Tr a n s y l v a n i a C o u n t y C a l v e r t L a n d f i l l P a g e 3 o f 6 J o y c e E n g i n e e r i n g TA B L E 3 SU M M A R Y O F H I S T O R I C A L O R G A N I C C O N S T I T U E N T S Sa m p l e An a l y t e Co l l e c t i o n D a t e D L Q L M W - 1 M W - 2 M W - 3 M W - 4 M W - 1 0 5 S M W - 1 0 5 D M W - 1 0 6 S M W - 1 0 6 D M W - 1 0 7 S M W - 1 0 7 D M W - 1 0 8 H W - 1 S M P - 1 F i e l d B l a n k 1,2 - D i c h l o r o p r o p a n e 0 4 / 2 2 / 1 0 0 . 2 7 1 . 0 0 N D N D 0 . 4 1 J N D 0 . 9 9 J 1.2 0 ND 0 . 5 8 J N D N D N D N D N D N D NC 2 L = 0 . 6 µ g / L ( 0 1 / 0 1 / 1 0 ) 1 0 / 2 7 / 1 0 0 . 2 7 1 . 0 0 N D N D N D N D 0 . 6 1 J N D 0 . 2 7 J 0 . 5 6 J N D N D N D N D N D N D NC 2 B = N E µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 0 . 2 7 1 . 0 0 N D N D N D N D 0 . 4 3 J 1.3 0 ND 0 . 5 4 J N D N D N D N D N D N D 10 / 0 3 / 1 1 0 . 2 7 1 . 0 0 N D N D N D N D N D 1.1 0 ND 0 . 5 8 J N D N D N D N D - - - N D 04 / 0 2 / 1 2 0 . 2 7 1 . 0 0 N D N D N D N D N D 1.0 0 ND N D N D N D N D N D N D N D 10 / 0 1 / 1 2 0 . 2 7 1 . 0 0 N D N D 0 . 4 1 J N D N D 1.1 0 ND 0 . 5 8 J N D N D N D N D N D N D 04 / 2 2 / 1 3 0 . 2 7 1 . 0 0 N D N D N D N D N D 0 . 9 2 J N D 0 . 5 J N D N D N D N D N D N D 10 / 2 1 / 1 3 0 . 2 7 1 . 0 0 N D N D 0 . 3 9 J N D N D 0 . 9 2 J N D 0 . 4 1 J N D N D N D N D N D N D 04 / 2 1 / 1 4 0 . 2 7 1 . 0 0 N D N D N D N D N D 0 . 8 6 J N D N D N D N D N D N D N D N D 10 / 0 6 / 1 4 0 . 2 7 1 . 0 0 N D N D N D N D N D 0 . 9 4 J N D N D N D N D N D N D - - - N D 04 / 2 0 / 1 5 0 . 2 7 1 . 0 0 N D N D N D - - - N D 0 . 5 5 J N D N D N D N D N D N D N D N D 10 / 1 9 / 1 5 0 . 2 7 1 . 0 0 N D N D N D - - - N D 0 . 9 9 J N D 0 . 3 7 J N D N D N D N D - - - N D Et h y l b e n z e n e 0 4 / 2 2 / 1 0 0 . 3 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D NC 2 L = 6 0 0 µ g / L ( 0 1 / 0 1 / 1 0 ) 1 0 / 2 7 / 1 0 0 . 3 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D NC 2 B = N E µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 0 . 3 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 3 / 1 1 0 . 3 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - N D 04 / 0 2 / 1 2 0 . 3 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 1 / 1 2 0 . 3 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 04 / 2 2 / 1 3 0 . 3 1 . 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 2 1 / 1 3 0 . 3 1 . 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 04 / 2 1 / 1 4 0 . 3 1 . 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 6 / 1 4 0 . 3 1 . 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - N D 04 / 2 0 / 1 5 0 . 3 1 . 0 N D N D N D - - - N D N D N D N D N D N D N D N D N D N D 10 / 1 9 / 1 5 0 . 3 1 . 0 N D N D N D - - - N D N D N D N D N D N D N D N D - - - N D 2-H e x a n o n e 0 4 / 2 2 / 1 0 0 . 4 6 5 0 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D GW P S = 2 8 0 µ g / L ( 1 0 / 2 3 / 0 7 ) 1 0 / 2 7 / 1 0 0 . 4 6 5 0 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D NC 2 B = N E µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 0 . 4 6 5 0 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 3 / 1 1 0 . 4 6 5 0 . 0 0 0 4 . 2 0 J N D N D N D N D N D N D N D 1 2 . 1 0 J N D N D N D - - - N D 04 / 0 2 / 1 2 0 . 4 6 5 0 . 0 0 0 N D N D N D N D N D N D 0 . 9 5 J N D N D N D N D N D N D N D 10 / 0 1 / 1 2 0 . 4 6 5 0 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 04 / 2 2 / 1 3 0 . 4 6 5 0 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 2 1 / 1 3 0 . 4 6 5 0 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 04 / 2 1 / 1 4 0 . 4 6 5 0 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 6 / 1 4 0 . 4 6 5 0 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - N D 04 / 2 0 / 1 5 0 . 4 6 5 0 . 0 0 0 N D N D N D - - - N D N D N D N D N D N D N D N D N D N D 10 / 1 9 / 1 5 0 . 4 6 5 0 . 0 0 0 N D N D N D - - - N D N D N D N D 0 . 7 1 J N D N D N D - - - N D Io d o m e t h a n e 0 4 / 1 8 / 1 1 0 . 3 2 1 0 . 0 0 0 N D N D 1 6 . 1 N D N D N D N D N D N D N D N D N D N D N D NC 2 L = N E µ g / L ( 0 1 / 0 1 / 1 0 ) 1 0 / 0 3 / 1 1 0 . 3 2 1 0 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - N D NC 2 B = N E µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 0 2 / 1 2 0 . 3 2 1 0 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 1 / 1 2 0 . 3 2 1 0 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 04 / 2 2 / 1 3 0 . 3 2 1 0 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 2 1 / 1 3 0 . 3 2 1 0 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 04 / 2 1 / 1 4 0 . 3 2 1 0 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 6 / 1 4 0 . 3 2 1 0 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - N D 04 / 2 0 / 1 5 0 . 3 2 1 0 . 0 0 0 N D N D N D - - - N D N D N D N D N D N D N D N D N D N D 10 / 1 9 / 1 5 0 . 3 2 1 0 . 0 0 0 N D N D N D - - - N D N D N D N D N D N D N D N D - - - N D Me t h y l e n e C h l o r i d e 0 4 / 2 2 / 1 0 0 . 9 7 2 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D 2 . 0 0 NC 2 L = 5 µ g / L ( 0 1 / 0 1 / 1 0 ) 1 0 / 2 7 / 1 0 0 . 9 7 1 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D NC 2 B = N E µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 0 . 9 7 1 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 3 / 1 1 0 . 9 7 1 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - 2 . 6 0 04 / 0 2 / 1 2 0 . 9 7 1 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 1 / 1 2 0 . 9 7 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 04 / 2 2 / 1 3 0 . 9 7 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D 2 . 6 0 10 / 2 1 / 1 3 0 . 9 7 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 04 / 2 1 / 1 4 0 . 9 7 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 6 / 1 4 0 . 9 7 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - 2 . 9 0 04 / 2 0 / 1 5 0 . 9 7 1 . 0 0 N D N D N D - - - N D N D N D N D N D N D N D N D N D N D 10 / 1 9 / 1 5 0 . 9 7 1 . 0 0 N D N D N D - - - N D N D N D N D N D N D N D N D - - - N D Tr a n s y l v a n i a C o u n t y C a l v e r t L a n d f i l l P a g e 4 o f 6 J o y c e E n g i n e e r i n g TA B L E 3 SU M M A R Y O F H I S T O R I C A L O R G A N I C C O N S T I T U E N T S Sa m p l e An a l y t e Co l l e c t i o n D a t e D L Q L M W - 1 M W - 2 M W - 3 M W - 4 M W - 1 0 5 S M W - 1 0 5 D M W - 1 0 6 S M W - 1 0 6 D M W - 1 0 7 S M W - 1 0 7 D M W - 1 0 8 H W - 1 S M P - 1 F i e l d B l a n k 2-B u t a n o n e ( M E K ) 0 4 / 2 2 / 1 0 0 . 9 6 1 0 0 . 0 0 0 N D N D N D N D N D N D N D N D N D N D 3 . 6 J N D N D N D (M e t h y l E t h y l K e y t o n e ) 1 0 / 2 7 / 1 0 0 . 9 6 1 0 0 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D NC 2 L = 4 , 0 0 0 µ g / L ( 0 1 / 0 1 / 1 0 ) 0 4 / 1 8 / 1 1 0 . 9 6 1 0 0 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D NC 2 B = N E µ g / L ( 0 5 / 0 1 / 0 7 ) 1 0 / 0 3 / 1 1 0 . 9 6 1 0 0 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - N D 04 / 0 2 / 1 2 0 . 9 6 1 0 0 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 1 / 1 2 0 . 9 6 1 0 0 . 0 0 N D N D N D N D N D N D N D N D 5 . 3 0 J N D N D N D N D N D 04 / 2 2 / 1 3 0 . 9 6 1 0 0 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 2 1 / 1 3 0 . 9 6 1 0 0 . 0 0 N D N D N D N D N D N D N D N D N D N D 7 . 8 J N D N D N D 04 / 2 1 / 1 4 0 . 9 6 1 0 0 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 6 / 1 4 0 . 9 6 1 0 0 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - N D 04 / 2 0 / 1 5 0 . 9 6 1 0 0 . 0 0 N D N D N D - - - N D N D N D N D N D N D N D N D N D N D 10 / 1 9 / 1 5 0 . 9 6 1 0 0 . 0 0 N D N D N D - - - N D N D N D N D N D N D N D N D - - - N D Te t r a c h l o r o e t h e n e 0 4 / 2 2 / 1 0 0 . 4 6 1 . 0 0 N D N D N D N D N D 0 . 5 5 J 0 . 6 2 J N D N D N D N D N D N D N D NC 2 L = 0 . 7 µ g / L ( 1 0 / 2 3 / 0 7 ) 1 0 / 2 7 / 1 0 0 . 4 6 1 . 0 0 N D N D N D N D N D N D 0 . 8 7 J N D N D N D N D N D N D N D NC 2 B = 3 . 3 µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 0 . 4 6 1 . 0 0 N D N D N D N D N D 0 . 5 2 J 0 . 4 9 J N D N D N D N D N D N D N D 10 / 0 3 / 1 1 0 . 4 6 1 . 0 0 N D N D N D N D N D 0 . 4 7 J 0 . 5 1 J N D N D N D N D N D - - - N D 04 / 0 2 / 1 2 0 . 4 6 1 . 0 0 N D N D N D N D N D 0 . 6 3 J N D N D N D N D N D N D N D N D 10 / 0 1 / 1 2 0 . 4 6 1 . 0 N D N D N D N D N D 0 . 5 4 J N D N D N D N D N D N D N D N D 04 / 2 2 / 1 3 0 . 4 6 1 . 0 N D N D N D N D N D 0 . 6 4 J N D N D N D N D N D N D N D N D 10 / 2 1 / 1 3 0 . 4 6 1 . 0 N D N D N D N D N D 0 . 8 2 J N D N D N D N D N D N D N D N D 04 / 2 1 / 1 4 0 . 4 6 1 . 0 N D N D N D N D N D 0 . 6 4 J N D N D N D N D N D N D N D N D 10 / 0 6 / 1 4 0 . 4 6 1 . 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - N D 04 / 2 0 / 1 5 0 . 4 6 1 . 0 N D N D N D - - - N D N D N D N D N D N D N D N D N D N D 10 / 1 9 / 1 5 0 . 4 6 1 . 0 N D N D N D - - - N D 0 . 6 0 J N D N D N D N D N D N D - - - N D To l u e n e 0 4 / 2 2 / 1 0 0 . 2 6 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D NC 2 L = 6 0 0 µ g / L ( 0 1 / 0 1 / 1 0 ) 1 0 / 2 7 / 1 0 0 . 2 6 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D NC 2 B = 1 1 µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 0 . 2 6 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 3 / 1 1 0 . 2 6 1 . 0 0 N D N D N D 1 . 3 N D N D N D N D 0 . 3 1 J N D N D N D - - - N D 04 / 0 2 / 1 2 0 . 2 6 1 . 0 0 N D N D N D 0 . 3 J N D N D N D N D N D N D N D N D N D N D 10 / 0 1 / 1 2 0 . 2 6 1 . 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 04 / 2 2 / 1 3 0 . 2 6 1 . 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 2 1 / 1 3 0 . 2 6 1 . 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 04 / 2 1 / 1 4 0 . 2 6 1 . 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 6 / 1 4 0 . 2 6 1 . 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - N D 04 / 2 0 / 1 5 0 . 2 6 1 . 0 N D N D N D - - - N D N D N D N D N D N D N D N D N D N D 10 / 1 9 / 1 5 0 . 2 6 1 . 0 N D N D N D - - - N D N D N D N D N D N D N D N D - - - N D 1,1 , 1 - T r i c h l o r o e t h a n e 0 4 / 2 2 / 1 0 0 . 4 8 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D NC 2 L = 2 0 0 µ g / L ( 1 0 / 2 3 / 0 7 ) 1 0 / 2 7 / 1 0 0 . 4 8 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D NC 2 B = N E µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 0 . 4 8 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 3 / 1 1 0 . 4 8 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - N D 04 / 0 2 / 1 2 0 . 4 8 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 1 / 1 2 0 . 4 8 1 . 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 04 / 2 2 / 1 3 0 . 4 8 1 . 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 2 1 / 1 3 0 . 4 8 1 . 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 04 / 2 1 / 1 4 0 . 4 8 1 . 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 6 / 1 4 0 . 4 8 1 . 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - N D 04 / 2 0 / 1 5 0 . 4 8 1 . 0 N D N D N D - - - N D N D N D N D N D N D N D N D N D N D 10 / 1 9 / 1 5 0 . 4 8 1 . 0 N D N D N D - - - N D N D N D N D N D N D N D N D - - - N D Tr i c h l o r o e t h e n e 0 4 / 2 2 / 1 0 0 . 4 7 1 . 0 0 N D N D N D 0 . 4 7 J N D 1 . 6 0 N D 0 . 4 7 J N D N D N D N D N D N D NC 2 L = 3 µ g / L ( 0 1 / 0 1 / 1 0 ) 1 0 / 2 7 / 1 0 0 . 4 7 1 . 0 0 N D N D N D N D N D N D 0 . 5 3 J N D N D N D N D N D N D N D NC 2 B = 3 0 µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 0 . 4 7 1 . 0 0 N D N D N D 0 . 4 5 J N D 1 . 7 0 N D N D N D N D N D N D N D N D 10 / 0 3 / 1 1 0 . 4 7 1 . 0 0 N D N D N D N D N D 1 . 4 0 N D N D N D N D N D N D - - - N D 04 / 0 2 / 1 2 0 . 4 7 1 . 0 0 N D N D N D N D N D 1 . 2 0 N D N D N D N D N D N D N D N D 10 / 0 1 / 1 2 0 . 4 7 1 . 0 N D N D N D N D N D 1 . 1 0 N D N D N D N D N D N D N D N D 04 / 2 2 / 1 3 0 . 4 7 1 . 0 N D N D N D 0 . 5 4 J N D 0 . 9 7 J N D N D N D N D N D N D N D N D 10 / 2 1 / 1 3 0 . 4 7 1 . 0 N D N D N D N D N D 1 . 0 0 N D N D N D N D N D N D N D N D 04 / 2 1 / 1 4 0 . 4 7 1 . 0 N D N D N D N D N D 0 . 9 5 J N D N D N D N D N D N D N D N D 10 / 0 6 / 1 4 0 . 4 7 1 . 0 N D N D N D N D N D 0 . 8 0 J N D N D N D N D N D N D - - - N D 04 / 2 0 / 1 5 0 . 4 7 1 . 0 N D N D N D - - - N D 0 . 5 9 J N D N D N D N D N D N D N D N D 10 / 1 9 / 1 5 0 . 4 7 1 . 0 N D N D N D - - - N D 1 . 1 N D N D N D N D N D N D - - - N D Tr a n s y l v a n i a C o u n t y C a l v e r t L a n d f i l l P a g e 5 o f 6 J o y c e E n g i n e e r i n g TA B L E 3 SU M M A R Y O F H I S T O R I C A L O R G A N I C C O N S T I T U E N T S Sa m p l e An a l y t e Co l l e c t i o n D a t e D L Q L M W - 1 M W - 2 M W - 3 M W - 4 M W - 1 0 5 S M W - 1 0 5 D M W - 1 0 6 S M W - 1 0 6 D M W - 1 0 7 S M W - 1 0 7 D M W - 1 0 8 H W - 1 S M P - 1 F i e l d B l a n k Tr i c h l o r o f l u o r o m e t h a n e 0 4 / 2 2 / 1 0 0 . 2 1 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D NC 2 L = 2 , 0 0 0 µ g / L ( 0 1 / 0 1 / 1 0 ) 1 0 / 2 7 / 1 0 0 . 2 1 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D NC 2 B = N E µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 0 . 2 1 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 3 / 1 1 0 . 2 1 . 0 0 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - N D 04 / 0 2 / 1 2 0 . 2 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 1 / 1 2 0 . 2 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 04 / 2 2 / 1 3 0 . 2 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 2 1 / 1 3 0 . 2 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 04 / 2 1 / 1 4 0 . 2 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 6 / 1 4 0 . 2 1 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - N D 04 / 2 0 / 1 5 0 . 2 1 . 0 0 N D N D N D - - - N D N D N D N D N D N D N D N D N D N D 10 / 1 9 / 1 5 0 . 2 1 . 0 0 N D N D N D - - - N D N D N D N D N D N D N D N D - - - N D Vin y l C h l o r i d e 0 4 / 2 2 / 1 0 0 . 6 2 1 . 0 0 N D N D 1.8 0. 7 2 J N D 1.6 0 ND N D N D 1. 1 0 ND N D N D N D NC 2 L = 0 . 0 3 µ g / L ( 0 1 / 0 1 / 1 0 ) 1 0 / 2 7 / 1 0 0 . 6 2 1 . 0 0 N D N D 1.3 0.7J N D N D N D N D N D N D N D N D N D N D NC 2 B = 2 . 4 µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 0 . 6 2 1 . 0 0 N D N D 1.0 N D N D 1.5 ND N D N D 0 . 6 3 J N D N D N D N D 10 / 0 3 / 1 1 0 . 6 2 1 . 0 0 N D N D 1.1 0. 9 6 J N D 1.7 ND N D N D N D N D N D - - - N D 04 / 0 2 / 1 2 0 . 6 2 1 . 0 0 N D N D 1.0 0. 7 8 J N D 1.3 ND N D N D N D N D N D N D N D 10 / 0 1 / 1 2 0 . 6 2 1 . 0 N D N D 1.0 ND N D 1.1 ND N D N D N D N D N D N D N D 04 / 2 2 / 1 3 0 . 6 2 1 . 0 N D N D 0 . 7 8 J N D N D 0 . 8 3 J N D N D N D N D N D N D N D N D 10 / 2 1 / 1 3 0 . 6 2 1 . 0 N D N D N D N D N D 0 . 9 2 J N D N D N D N D N D N D N D N D 04 / 2 1 / 1 4 0 . 6 2 1 . 0 N D N D N D 0 . 6 4 J N D 1.0 ND N D N D N D N D N D N D N D 10 / 0 6 / 1 4 0 . 6 2 1 . 0 N D N D N D N D N D 0 . 9 9 J N D N D N D N D N D N D - - - N D 04 / 2 0 / 1 5 0 . 6 2 1 . 0 N D N D 0 . 8 8 J - - - N D N D N D N D N D N D N D N D N D N D 10 / 1 9 / 1 5 0 . 6 2 1 . 0 N D N D 0 . 9 1 J - - - N D 1 . 0 J N D N D N D N D N D N D - - - N D Xy l e n e ( T o t a l ) 0 4 / 2 2 / 1 0 0 . 6 6 2 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D NC 2 L = 5 0 0 µ g / L ( 0 1 / 0 1 / 1 0 ) 1 0 / 2 7 / 1 0 0 . 6 6 2 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D NC 2 B = N E µ g / L ( 0 5 / 0 1 / 0 7 ) 0 4 / 1 8 / 1 1 0 . 6 6 2 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 3 / 1 1 0 . 6 6 2 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - N D 04 / 0 2 / 1 2 0 . 6 6 2 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 1 / 1 2 0 . 6 6 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 04 / 2 2 / 1 3 0 . 6 6 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 2 1 / 1 3 0 . 6 6 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 04 / 2 1 / 1 4 0 . 6 6 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D N D N D 10 / 0 6 / 1 4 0 . 6 6 5 . 0 0 N D N D N D N D N D N D N D N D N D N D N D N D - - - N D 04 / 2 0 / 1 5 0 . 6 6 5 . 0 0 N D N D N D - - - N D N D N D N D N D N D N D N D N D N D 10 / 1 9 / 1 5 0 . 6 6 5 . 0 0 N D N D N D - - - N D N D N D N D N D N D N D N D - - - N D No t e s : QL = Q u a n t i a t i o n L i m i t ND = N o t d e t e c t e d a t o r a b o v e t h e d e t e c t i o n o r r e p o r t i n g l i m i t . J = E s t i m a t e d v a l u e s i n c e t h e c o n c e n t r a t i o n i s b e t w e e n t h e D L a n d t h e S W S L . -- - = N o t s a m p l e d a n d o r N o t R e p o r t e d DL = L a b o r a t o r y d e t e c t i o n l i m i t . 9. D r y = M o n i t o r i n g w e l l / s u r f a c e w a t e r m o n i t o r i n g p o i n t i s c o n s i d e r e d t o b e d r y a n d n o s a m p l e c o l l e c t e d . NC 2 L = N o r t h C a r o l i n a ' s g r o u n d w a t e r q u a l i t y s t a n d a r d e s t a b l i s h e d u n d e r 1 5 A N C A C 2 L , . 0 2 0 2 . N C 2 B = N o r t h C a r o l i n a 2 B S u r f a c e W a t e r S t a n d a r d s . T h e s u r f a c e w a t e r a t t h e s a m p l i n g l o c a t i o n i s c l a s s i f i e d a s C l a s s C . NC 2 B S t a n d a r d i s u s e d t o d e f i n e c o n c e n t r a t i o n l i m i t s f o r s u r f a c e w a t e r c o n s t i t u e n t s . NC S W S L = N o r t h C a r o l i n a S o l i d W a s t e S e c t i o n L i m i t s . Bo l d co n c e n t r a t i o n s a r e g r e a t e r t h a n t h e N C 2 L f o r g r o u n d w a t e r o r N C 2 B f o r s u r f a c e w a t e r . NE = N o t e s t a b l i s h e d . NV = V a l u e s c o n s i d e r e d t o b e n o t v a l i d d u e t o l a b o r a t o r y e x c e e d i n g h o l d t i m e s f o r a n a l y s i s Tr a n s y l v a n i a C o u n t y C a l v e r t L a n d f i l l P a g e 6 o f 6 J o y c e E n g i n e e r i n g TABLE 4: Horizontal Groundwater Flow Velocities Date of Water Table Measurements: April 20, 2015 SEGMENT HORIZ.HYDRAULIC EFFECTIVE LINEAR FLOW BEGIN & END GRADIENT CONDUCTIVITY POROSITY VELOCITY DIRECTION GW ELEVATION i K n e V (feet-AMSL)(ft/ft) (ft/day)(ft/year) 2,250 2,220 2,250 2,210 2,250 2,220 .0.0793 Average 250.27 Notes: Linear flow velocity: V = Ki/n e (modified Darcy equation). Hydraulic conductivity (K ) is based on the arithmetic mean of values from slug tests conducted at the facility by Joyce Engineering in April, 1999. Assumed effective porosity (n) of 0.20 for porous regolith Refer to Drawing 1 for flow line segments. 0.20 259.501.73E+00 FLOW LINE SEGMENT SEGMENT LENGTH (feet) i 3 365 NE 0.0822 238.73 i 1 375 S 0.0800 0.20 252.58 0.20 1.73E+00 1.73E+00i2529SE0.0756 Transylvania Co. Calvert Landfill Permit No. 88-03 Joyce Engineering Figure Figure 1 Site Location Map Drawing Drawing No. 1 Groundwater Surface Map Appendices Appendix 1 Laboratory Analytical Report and Field Forms Appendix 2 Summary of Detections and Summary of Exceedances Appendix 3 Summary of Field Parameters Appendix 4 Summary of Monitoring Well Construction Appendix 1 Laboratory Analytical Report and Field Forms #=CL# November 02, 2015 LIMS USE: FR - ALEX EVERHART LIMS OBJECT ID: 92272834 92272834 Project: Pace Project No.: RE: Mr. Alex Everhart Joyce Engineering-NC 2211 W. Meadowview Road Suite 101 Greensboro, NC 27407 TRANSYLVANIA-CALVERT Dear Mr. Everhart: Enclosed are the analytical results for sample(s) received by the laboratory on October 21, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Godwin kevin.godwin@pacelabs.com Project Manager Enclosures cc:Mr. Van Burbach, Joyce Engineering-NC Alex Everhart, Joyce Engineering-NC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 45 #=CP# CERTIFICATIONS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84 West Virginia Certification #: 357Virginia/VELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 45 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Lab ID Sample ID Matrix Date Collected Date Received 92272834001 8803-MW1 Water 10/19/15 11:08 10/21/15 14:45 92272834002 8803-MW2 Water 10/19/15 12:36 10/21/15 14:45 92272834003 8803-MW3 Water 10/19/15 17:43 10/21/15 14:45 92272834004 8803-MW105S Water 10/19/15 15:48 10/21/15 14:45 92272834005 8803-MW105D Water 10/19/15 14:05 10/21/15 14:45 92272834006 8803-MW106S Water 10/19/15 17:45 10/21/15 14:45 92272834007 8803-MW106D Water 10/19/15 17:35 10/21/15 14:45 92272834008 8803-MW107S Water 10/19/15 13:00 10/21/15 14:45 92272834009 8803-MW107D Water 10/19/15 12:15 10/21/15 14:45 92272834010 8803-MW108 Water 10/19/15 10:14 10/21/15 14:45 92272834011 8803-HW-1 Water 10/19/15 17:50 10/21/15 14:45 92272834012 8803-FIELD BLANK Water 10/19/15 16:10 10/21/15 14:45 92272834013 8803-TRIP BLANK Water 10/19/15 05:30 10/21/15 14:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 45 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92272834001 8803-MW1 EPA 6010 7 PASI-ACDF EPA 7470 1 PASI-AHVK EPA 8260 50 PASI-CCAH 92272834002 8803-MW2 EPA 6010 7 PASI-ACDF EPA 7470 1 PASI-AHVK EPA 8260 50 PASI-CCAH 92272834003 8803-MW3 EPA 6010 7 PASI-ACDF EPA 7470 1 PASI-AHVK EPA 8260 50 PASI-CCAH 92272834004 8803-MW105S EPA 8260 51 PASI-CCAH 92272834005 8803-MW105D EPA 8260 51 PASI-CCAH 92272834006 8803-MW106S EPA 8260 50 PASI-CCAH 92272834007 8803-MW106D EPA 8260 50 PASI-CCAH 92272834008 8803-MW107S EPA 8260 50 PASI-CCAH 92272834009 8803-MW107D EPA 8260 50 PASI-CCAH 92272834010 8803-MW108 EPA 8260 50 PASI-CCAH 92272834011 8803-HW-1 EPA 8260 50 PASI-CCAH 92272834012 8803-FIELD BLANK EPA 6010 7 PASI-ACDF EPA 7470 1 PASI-AHVK EPA 8260 51 PASI-CCAH 92272834013 8803-TRIP BLANK EPA 8260 51 PASI-CCAH REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 45 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92272834001 8803-MW1 Barium 76.7J ug/L 10/29/15 02:11100EPA 6010 Cadmium 1.9 ug/L 10/29/15 02:111.0EPA 6010 Chromium 4.7J ug/L 10/29/15 02:1110.0EPA 6010 Lead 7.5J ug/L 10/29/15 02:1110.0EPA 6010 92272834002 8803-MW2 Barium 80.8J ug/L 10/29/15 02:15100EPA 6010 Chromium 3.4J ug/L 10/29/15 02:1510.0EPA 6010 Lead 3.9J ug/L 10/29/15 02:1510.0EPA 6010 Silver 4.3J ug/L 10/29/15 02:1510.0EPA 6010 Benzene 0.68J ug/L 10/30/15 17:521.0EPA 8260 Chlorobenzene 0.59J ug/L 10/30/15 17:523.0EPA 8260 1,4-Dichlorobenzene 0.61J ug/L 10/30/15 17:521.0EPA 8260 cis-1,2-Dichloroethene 0.95J ug/L 10/30/15 17:525.0EPA 8260 92272834003 8803-MW3 Barium 80.5J ug/L 10/29/15 02:18100EPA 6010 Chromium 3.0J ug/L 10/29/15 02:1810.0EPA 6010 Benzene 1.1 ug/L 10/30/15 18:261.0EPA 8260 Chlorobenzene 10.8 ug/L 10/30/15 18:263.0EPA 8260 1,2-Dichlorobenzene 0.75J ug/L 10/30/15 18:265.0EPA 8260 1,4-Dichlorobenzene 13.1 ug/L 10/30/15 18:261.0EPA 8260 cis-1,2-Dichloroethene 0.90J ug/L 10/30/15 18:265.0EPA 8260 Vinyl chloride 0.91J ug/L 10/30/15 18:261.0EPA 8260 92272834004 8803-MW105S Benzene 0.80J ug/L 10/30/15 18:421.0EPA 8260 Chlorobenzene 2.6J ug/L 10/30/15 18:423.0EPA 8260 1,4-Dichlorobenzene 2.4 ug/L 10/30/15 18:421.0EPA 8260 Dichlorodifluoromethane 1.5J ug/L 10/30/15 18:425.0EPA 8260 cis-1,2-Dichloroethene 0.65J ug/L 10/30/15 18:425.0EPA 8260 92272834005 8803-MW105D Benzene 2.2 ug/L 10/30/15 18:591.0EPA 8260 Chlorobenzene 12.2 ug/L 10/30/15 18:593.0EPA 8260 1,4-Dichlorobenzene 6.7 ug/L 10/30/15 18:591.0EPA 8260 Dichlorodifluoromethane 0.82J ug/L 10/30/15 18:595.0EPA 8260 1,2-Dichloroethane 0.50J ug/L 10/30/15 18:591.0EPA 8260 cis-1,2-Dichloroethene 13.4 ug/L 10/30/15 18:595.0EPA 8260 1,2-Dichloropropane 0.99J ug/L 10/30/15 18:591.0EPA 8260 Tetrachloroethene 0.60J ug/L 10/30/15 18:591.0EPA 8260 Trichloroethene 1.1 ug/L 10/30/15 18:591.0EPA 8260 Vinyl chloride 1.0J ug/L 10/30/15 18:591.0EPA 8260 92272834006 8803-MW106S cis-1,2-Dichloroethene 0.91J ug/L 10/30/15 19:165.0EPA 8260 92272834007 8803-MW106D Benzene 0.40J ug/L 10/30/15 19:321.0EPA 8260 Chlorobenzene 6.3 ug/L 10/30/15 19:323.0EPA 8260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 45 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92272834007 8803-MW106D 1,2-Dichlorobenzene 0.37J ug/L 10/30/15 19:325.0EPA 8260 1,4-Dichlorobenzene 5.7 ug/L 10/30/15 19:321.0EPA 8260 1,2-Dichloroethane 0.29J ug/L 10/30/15 19:321.0EPA 8260 cis-1,2-Dichloroethene 2.5J ug/L 10/30/15 19:325.0EPA 8260 1,2-Dichloropropane 0.37J ug/L 10/30/15 19:321.0EPA 8260 92272834008 8803-MW107S 2-Hexanone 0.71J ug/L 10/30/15 19:4950.0EPA 8260 92272834009 8803-MW107D Benzene 0.49J ug/L 10/30/15 20:061.0EPA 8260 Chlorobenzene 0.61J ug/L 10/30/15 20:063.0EPA 8260 Chloroethane 0.75J ug/L 10/30/15 20:0610.0EPA 8260 1,4-Dichlorobenzene 1.1 ug/L 10/30/15 20:061.0EPA 8260 1,1-Dichloroethane 0.74J ug/L 10/30/15 20:065.0EPA 8260 cis-1,2-Dichloroethene 0.75J ug/L 10/30/15 20:065.0EPA 8260 92272834010 8803-MW108 Acetone 19.8J ug/L 10/30/15 20:23100EPA 8260 Benzene 0.39J ug/L 10/30/15 20:231.0EPA 8260 Chlorobenzene 0.56J ug/L 10/30/15 20:233.0EPA 8260 Chloroethane 1.2J ug/L 10/30/15 20:2310.0EPA 8260 1,4-Dichlorobenzene 1.1 ug/L 10/30/15 20:231.0EPA 8260 1,1-Dichloroethane 1.6J ug/L 10/30/15 20:235.0EPA 8260 cis-1,2-Dichloroethene 1.4J ug/L 10/30/15 20:235.0EPA 8260 92272834011 8803-HW-1 Chloroform 0.56J ug/L 10/30/15 20:395.0EPA 8260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW1 Lab ID:92272834001 Collected:10/19/15 11:08 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Arsenic ND ug/L 10/29/15 02:11 7440-38-210/22/15 18:3010.0 2.5 1 Barium 76.7J ug/L 10/29/15 02:11 7440-39-310/22/15 18:301002.5 1 Cadmium 1.9 ug/L 10/29/15 02:11 7440-43-910/22/15 18:301.0 0.50 1 Chromium 4.7J ug/L 10/29/15 02:11 7440-47-310/22/15 18:3010.0 2.5 1 Lead 7.5J ug/L 10/29/15 02:11 7439-92-110/22/15 18:3010.0 2.5 1 Selenium ND ug/L 10/29/15 02:11 7782-49-210/22/15 18:3010.0 5.0 1 Silver ND ug/L 10/29/15 02:11 7440-22-410/22/15 18:3010.0 2.5 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 10/30/15 14:18 7439-97-610/22/15 17:000.20 0.10 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 10/30/15 17:36 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 17:36 107-13-12001.9 1 Benzene ND ug/L 10/30/15 17:36 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 17:36 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 17:36 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 17:36 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 17:36 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 17:36 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 17:36 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 17:36 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/30/15 17:36 108-90-73.0 0.23 1 Chloroethane ND ug/L 10/30/15 17:36 75-00-310.0 0.54 1 Chloroform ND ug/L 10/30/15 17:36 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 17:36 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 17:36 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 17:36 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 17:36 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 17:36 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/30/15 17:36 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/30/15 17:36 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 17:36 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 10/30/15 17:36 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 10/30/15 17:36 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 17:36 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/30/15 17:36 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 17:36 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 10/30/15 17:36 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 17:36 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 17:36 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 17:36 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/30/15 17:36 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 17:36 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 17:36 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 17:36 108-10-11000.33 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW1 Lab ID:92272834001 Collected:10/19/15 11:08 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Styrene ND ug/L 10/30/15 17:36 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 17:36 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 17:36 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 10/30/15 17:36 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 17:36 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 17:36 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 17:36 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/30/15 17:36 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 17:36 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 17:36 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 17:36 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 10/30/15 17:36 75-01-4 M11.0 0.62 1 Xylene (Total)ND ug/L 10/30/15 17:36 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %10/30/15 17:36 460-00-470-130 1 1,2-Dichloroethane-d4 (S)102 %10/30/15 17:36 17060-07-070-130 1 Toluene-d8 (S)101 %10/30/15 17:36 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW2 Lab ID:92272834002 Collected:10/19/15 12:36 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Arsenic ND ug/L 10/29/15 02:15 7440-38-210/22/15 18:3010.0 2.5 1 Barium 80.8J ug/L 10/29/15 02:15 7440-39-310/22/15 18:301002.5 1 Cadmium ND ug/L 10/29/15 02:15 7440-43-910/22/15 18:301.0 0.50 1 Chromium 3.4J ug/L 10/29/15 02:15 7440-47-310/22/15 18:3010.0 2.5 1 Lead 3.9J ug/L 10/29/15 02:15 7439-92-110/22/15 18:3010.0 2.5 1 Selenium ND ug/L 10/29/15 02:15 7782-49-210/22/15 18:3010.0 5.0 1 Silver 4.3J ug/L 10/29/15 02:15 7440-22-410/22/15 18:3010.0 2.5 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 10/30/15 14:20 7439-97-610/22/15 17:000.20 0.10 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 10/30/15 17:52 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 17:52 107-13-12001.9 1 Benzene 0.68J ug/L 10/30/15 17:52 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 17:52 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 17:52 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 17:52 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 17:52 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 17:52 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 17:52 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 17:52 56-23-51.0 0.25 1 Chlorobenzene 0.59J ug/L 10/30/15 17:52 108-90-73.0 0.23 1 Chloroethane ND ug/L 10/30/15 17:52 75-00-310.0 0.54 1 Chloroform ND ug/L 10/30/15 17:52 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 17:52 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 17:52 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 17:52 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 17:52 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 17:52 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/30/15 17:52 95-50-15.0 0.30 1 1,4-Dichlorobenzene 0.61J ug/L 10/30/15 17:52 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 17:52 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 10/30/15 17:52 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 10/30/15 17:52 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 17:52 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 0.95J ug/L 10/30/15 17:52 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 17:52 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 10/30/15 17:52 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 17:52 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 17:52 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 17:52 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/30/15 17:52 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 17:52 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 17:52 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 17:52 108-10-11000.33 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW2 Lab ID:92272834002 Collected:10/19/15 12:36 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Styrene ND ug/L 10/30/15 17:52 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 17:52 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 17:52 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 10/30/15 17:52 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 17:52 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 17:52 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 17:52 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/30/15 17:52 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 17:52 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 17:52 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 17:52 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 10/30/15 17:52 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/30/15 17:52 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %10/30/15 17:52 460-00-470-130 1 1,2-Dichloroethane-d4 (S)102 %10/30/15 17:52 17060-07-070-130 1 Toluene-d8 (S)100 %10/30/15 17:52 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW3 Lab ID:92272834003 Collected:10/19/15 17:43 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Arsenic ND ug/L 10/29/15 02:18 7440-38-210/22/15 18:3010.0 2.5 1 Barium 80.5J ug/L 10/29/15 02:18 7440-39-310/22/15 18:301002.5 1 Cadmium ND ug/L 10/29/15 02:18 7440-43-910/22/15 18:301.0 0.50 1 Chromium 3.0J ug/L 10/29/15 02:18 7440-47-310/22/15 18:3010.0 2.5 1 Lead ND ug/L 10/29/15 02:18 7439-92-110/22/15 18:3010.0 2.5 1 Selenium ND ug/L 10/29/15 02:18 7782-49-210/22/15 18:3010.0 5.0 1 Silver ND ug/L 10/29/15 02:18 7440-22-410/22/15 18:3010.0 2.5 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 10/30/15 14:22 7439-97-610/22/15 17:000.20 0.10 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 10/30/15 18:26 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 18:26 107-13-12001.9 1 Benzene 1.1 ug/L 10/30/15 18:26 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 18:26 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 18:26 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 18:26 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 18:26 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 18:26 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 18:26 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 18:26 56-23-51.0 0.25 1 Chlorobenzene 10.8 ug/L 10/30/15 18:26 108-90-73.0 0.23 1 Chloroethane ND ug/L 10/30/15 18:26 75-00-310.0 0.54 1 Chloroform ND ug/L 10/30/15 18:26 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 18:26 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 18:26 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 18:26 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 18:26 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 18:26 74-95-310.0 0.21 1 1,2-Dichlorobenzene 0.75J ug/L 10/30/15 18:26 95-50-15.0 0.30 1 1,4-Dichlorobenzene 13.1 ug/L 10/30/15 18:26 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 18:26 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 10/30/15 18:26 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 10/30/15 18:26 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 18:26 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 0.90J ug/L 10/30/15 18:26 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 18:26 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 10/30/15 18:26 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 18:26 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 18:26 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 18:26 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/30/15 18:26 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 18:26 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 18:26 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 18:26 108-10-11000.33 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW3 Lab ID:92272834003 Collected:10/19/15 17:43 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Styrene ND ug/L 10/30/15 18:26 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 18:26 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 18:26 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 10/30/15 18:26 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 18:26 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 18:26 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 18:26 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/30/15 18:26 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 18:26 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 18:26 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 18:26 108-05-450.0 0.35 1 Vinyl chloride 0.91J ug/L 10/30/15 18:26 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/30/15 18:26 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %10/30/15 18:26 460-00-470-130 1 1,2-Dichloroethane-d4 (S)103 %10/30/15 18:26 17060-07-070-130 1 Toluene-d8 (S)99 %10/30/15 18:26 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW105S Lab ID:92272834004 Collected:10/19/15 15:48 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 10/30/15 18:42 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 18:42 107-13-12001.9 1 Benzene 0.80J ug/L 10/30/15 18:42 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 18:42 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 18:42 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 18:42 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 18:42 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 18:42 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 18:42 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 18:42 56-23-51.0 0.25 1 Chlorobenzene 2.6J ug/L 10/30/15 18:42 108-90-73.0 0.23 1 Chloroethane ND ug/L 10/30/15 18:42 75-00-310.0 0.54 1 Chloroform ND ug/L 10/30/15 18:42 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 18:42 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 18:42 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 18:42 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 18:42 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 18:42 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/30/15 18:42 95-50-15.0 0.30 1 1,4-Dichlorobenzene 2.4 ug/L 10/30/15 18:42 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 18:42 110-57-61001.0 1 Dichlorodifluoromethane 1.5J ug/L 10/30/15 18:42 75-71-85.0 0.21 1 1,1-Dichloroethane ND ug/L 10/30/15 18:42 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 10/30/15 18:42 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 18:42 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 0.65J ug/L 10/30/15 18:42 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 18:42 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 10/30/15 18:42 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 18:42 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 18:42 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 18:42 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/30/15 18:42 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 18:42 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 18:42 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 18:42 108-10-11000.33 1 Styrene ND ug/L 10/30/15 18:42 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 18:42 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 18:42 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 10/30/15 18:42 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 18:42 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 18:42 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 18:42 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/30/15 18:42 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 18:42 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 18:42 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 18:42 108-05-450.0 0.35 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW105S Lab ID:92272834004 Collected:10/19/15 15:48 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Vinyl chloride ND ug/L 10/30/15 18:42 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/30/15 18:42 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)99 %10/30/15 18:42 460-00-470-130 1 1,2-Dichloroethane-d4 (S)102 %10/30/15 18:42 17060-07-070-130 1 Toluene-d8 (S)100 %10/30/15 18:42 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW105D Lab ID:92272834005 Collected:10/19/15 14:05 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 10/30/15 18:59 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 18:59 107-13-12001.9 1 Benzene 2.2 ug/L 10/30/15 18:59 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 18:59 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 18:59 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 18:59 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 18:59 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 18:59 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 18:59 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 18:59 56-23-51.0 0.25 1 Chlorobenzene 12.2 ug/L 10/30/15 18:59 108-90-73.0 0.23 1 Chloroethane ND ug/L 10/30/15 18:59 75-00-310.0 0.54 1 Chloroform ND ug/L 10/30/15 18:59 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 18:59 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 18:59 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 18:59 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 18:59 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 18:59 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/30/15 18:59 95-50-15.0 0.30 1 1,4-Dichlorobenzene 6.7 ug/L 10/30/15 18:59 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 18:59 110-57-61001.0 1 Dichlorodifluoromethane 0.82J ug/L 10/30/15 18:59 75-71-85.0 0.21 1 1,1-Dichloroethane ND ug/L 10/30/15 18:59 75-34-35.0 0.32 1 1,2-Dichloroethane 0.50J ug/L 10/30/15 18:59 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 18:59 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 13.4 ug/L 10/30/15 18:59 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 18:59 156-60-55.0 0.49 1 1,2-Dichloropropane 0.99J ug/L 10/30/15 18:59 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 18:59 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 18:59 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 18:59 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/30/15 18:59 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 18:59 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 18:59 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 18:59 108-10-11000.33 1 Styrene ND ug/L 10/30/15 18:59 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 18:59 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 18:59 79-34-53.0 0.40 1 Tetrachloroethene 0.60J ug/L 10/30/15 18:59 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 18:59 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 18:59 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 18:59 79-00-51.0 0.29 1 Trichloroethene 1.1 ug/L 10/30/15 18:59 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 18:59 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 18:59 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 18:59 108-05-450.0 0.35 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW105D Lab ID:92272834005 Collected:10/19/15 14:05 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Vinyl chloride 1.0J ug/L 10/30/15 18:59 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/30/15 18:59 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %10/30/15 18:59 460-00-470-130 1 1,2-Dichloroethane-d4 (S)100 %10/30/15 18:59 17060-07-070-130 1 Toluene-d8 (S)100 %10/30/15 18:59 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW106S Lab ID:92272834006 Collected:10/19/15 17:45 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 10/30/15 19:16 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 19:16 107-13-12001.9 1 Benzene ND ug/L 10/30/15 19:16 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 19:16 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 19:16 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 19:16 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 19:16 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 19:16 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 19:16 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 19:16 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/30/15 19:16 108-90-73.0 0.23 1 Chloroethane ND ug/L 10/30/15 19:16 75-00-310.0 0.54 1 Chloroform ND ug/L 10/30/15 19:16 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 19:16 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 19:16 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 19:16 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 19:16 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 19:16 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/30/15 19:16 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/30/15 19:16 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 19:16 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 10/30/15 19:16 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 10/30/15 19:16 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 19:16 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 0.91J ug/L 10/30/15 19:16 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 19:16 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 10/30/15 19:16 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 19:16 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 19:16 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 19:16 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/30/15 19:16 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 19:16 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 19:16 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 19:16 108-10-11000.33 1 Styrene ND ug/L 10/30/15 19:16 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 19:16 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 19:16 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 10/30/15 19:16 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 19:16 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 19:16 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 19:16 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/30/15 19:16 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 19:16 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 19:16 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 19:16 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 10/30/15 19:16 75-01-41.0 0.62 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW106S Lab ID:92272834006 Collected:10/19/15 17:45 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Xylene (Total)ND ug/L 10/30/15 19:16 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %10/30/15 19:16 460-00-470-130 1 1,2-Dichloroethane-d4 (S)105 %10/30/15 19:16 17060-07-070-130 1 Toluene-d8 (S)98 %10/30/15 19:16 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW106D Lab ID:92272834007 Collected:10/19/15 17:35 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 10/30/15 19:32 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 19:32 107-13-12001.9 1 Benzene 0.40J ug/L 10/30/15 19:32 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 19:32 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 19:32 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 19:32 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 19:32 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 19:32 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 19:32 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 19:32 56-23-51.0 0.25 1 Chlorobenzene 6.3 ug/L 10/30/15 19:32 108-90-73.0 0.23 1 Chloroethane ND ug/L 10/30/15 19:32 75-00-310.0 0.54 1 Chloroform ND ug/L 10/30/15 19:32 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 19:32 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 19:32 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 19:32 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 19:32 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 19:32 74-95-310.0 0.21 1 1,2-Dichlorobenzene 0.37J ug/L 10/30/15 19:32 95-50-15.0 0.30 1 1,4-Dichlorobenzene 5.7 ug/L 10/30/15 19:32 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 19:32 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 10/30/15 19:32 75-34-35.0 0.32 1 1,2-Dichloroethane 0.29J ug/L 10/30/15 19:32 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 19:32 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 2.5J ug/L 10/30/15 19:32 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 19:32 156-60-55.0 0.49 1 1,2-Dichloropropane 0.37J ug/L 10/30/15 19:32 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 19:32 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 19:32 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 19:32 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/30/15 19:32 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 19:32 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 19:32 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 19:32 108-10-11000.33 1 Styrene ND ug/L 10/30/15 19:32 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 19:32 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 19:32 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 10/30/15 19:32 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 19:32 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 19:32 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 19:32 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/30/15 19:32 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 19:32 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 19:32 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 19:32 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 10/30/15 19:32 75-01-41.0 0.62 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW106D Lab ID:92272834007 Collected:10/19/15 17:35 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Xylene (Total)ND ug/L 10/30/15 19:32 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)101 %10/30/15 19:32 460-00-470-130 1 1,2-Dichloroethane-d4 (S)103 %10/30/15 19:32 17060-07-070-130 1 Toluene-d8 (S)100 %10/30/15 19:32 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW107S Lab ID:92272834008 Collected:10/19/15 13:00 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 10/30/15 19:49 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 19:49 107-13-12001.9 1 Benzene ND ug/L 10/30/15 19:49 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 19:49 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 19:49 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 19:49 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 19:49 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 19:49 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 19:49 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 19:49 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/30/15 19:49 108-90-73.0 0.23 1 Chloroethane ND ug/L 10/30/15 19:49 75-00-310.0 0.54 1 Chloroform ND ug/L 10/30/15 19:49 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 19:49 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 19:49 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 19:49 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 19:49 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 19:49 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/30/15 19:49 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/30/15 19:49 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 19:49 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 10/30/15 19:49 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 10/30/15 19:49 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 19:49 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/30/15 19:49 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 19:49 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 10/30/15 19:49 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 19:49 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 19:49 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 19:49 100-41-41.0 0.30 1 2-Hexanone 0.71J ug/L 10/30/15 19:49 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 19:49 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 19:49 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 19:49 108-10-11000.33 1 Styrene ND ug/L 10/30/15 19:49 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 19:49 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 19:49 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 10/30/15 19:49 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 19:49 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 19:49 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 19:49 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/30/15 19:49 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 19:49 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 19:49 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 19:49 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 10/30/15 19:49 75-01-41.0 0.62 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW107S Lab ID:92272834008 Collected:10/19/15 13:00 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Xylene (Total)ND ug/L 10/30/15 19:49 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %10/30/15 19:49 460-00-470-130 1 1,2-Dichloroethane-d4 (S)103 %10/30/15 19:49 17060-07-070-130 1 Toluene-d8 (S)101 %10/30/15 19:49 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW107D Lab ID:92272834009 Collected:10/19/15 12:15 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 10/30/15 20:06 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 20:06 107-13-12001.9 1 Benzene 0.49J ug/L 10/30/15 20:06 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 20:06 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 20:06 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 20:06 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 20:06 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 20:06 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 20:06 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 20:06 56-23-51.0 0.25 1 Chlorobenzene 0.61J ug/L 10/30/15 20:06 108-90-73.0 0.23 1 Chloroethane 0.75J ug/L 10/30/15 20:06 75-00-310.0 0.54 1 Chloroform ND ug/L 10/30/15 20:06 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 20:06 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 20:06 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 20:06 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 20:06 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 20:06 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/30/15 20:06 95-50-15.0 0.30 1 1,4-Dichlorobenzene 1.1 ug/L 10/30/15 20:06 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 20:06 110-57-61001.0 1 1,1-Dichloroethane 0.74J ug/L 10/30/15 20:06 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 10/30/15 20:06 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 20:06 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 0.75J ug/L 10/30/15 20:06 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 20:06 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 10/30/15 20:06 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 20:06 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 20:06 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 20:06 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/30/15 20:06 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 20:06 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 20:06 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 20:06 108-10-11000.33 1 Styrene ND ug/L 10/30/15 20:06 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 20:06 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 20:06 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 10/30/15 20:06 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 20:06 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 20:06 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 20:06 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/30/15 20:06 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 20:06 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 20:06 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 20:06 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 10/30/15 20:06 75-01-41.0 0.62 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW107D Lab ID:92272834009 Collected:10/19/15 12:15 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Xylene (Total)ND ug/L 10/30/15 20:06 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)99 %10/30/15 20:06 460-00-470-130 1 1,2-Dichloroethane-d4 (S)101 %10/30/15 20:06 17060-07-070-130 1 Toluene-d8 (S)99 %10/30/15 20:06 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW108 Lab ID:92272834010 Collected:10/19/15 10:14 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone 19.8J ug/L 10/30/15 20:23 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 20:23 107-13-12001.9 1 Benzene 0.39J ug/L 10/30/15 20:23 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 20:23 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 20:23 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 20:23 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 20:23 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 20:23 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 20:23 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 20:23 56-23-51.0 0.25 1 Chlorobenzene 0.56J ug/L 10/30/15 20:23 108-90-73.0 0.23 1 Chloroethane 1.2J ug/L 10/30/15 20:23 75-00-310.0 0.54 1 Chloroform ND ug/L 10/30/15 20:23 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 20:23 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 20:23 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 20:23 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 20:23 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 20:23 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/30/15 20:23 95-50-15.0 0.30 1 1,4-Dichlorobenzene 1.1 ug/L 10/30/15 20:23 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 20:23 110-57-61001.0 1 1,1-Dichloroethane 1.6J ug/L 10/30/15 20:23 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 10/30/15 20:23 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 20:23 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 1.4J ug/L 10/30/15 20:23 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 20:23 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 10/30/15 20:23 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 20:23 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 20:23 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 20:23 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/30/15 20:23 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 20:23 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 20:23 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 20:23 108-10-11000.33 1 Styrene ND ug/L 10/30/15 20:23 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 20:23 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 20:23 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 10/30/15 20:23 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 20:23 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 20:23 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 20:23 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/30/15 20:23 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 20:23 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 20:23 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 20:23 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 10/30/15 20:23 75-01-41.0 0.62 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW108 Lab ID:92272834010 Collected:10/19/15 10:14 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Xylene (Total)ND ug/L 10/30/15 20:23 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)98 %10/30/15 20:23 460-00-470-130 1 1,2-Dichloroethane-d4 (S)99 %10/30/15 20:23 17060-07-070-130 1 Toluene-d8 (S)99 %10/30/15 20:23 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-HW-1 Lab ID:92272834011 Collected:10/19/15 17:50 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 10/30/15 20:39 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 20:39 107-13-12001.9 1 Benzene ND ug/L 10/30/15 20:39 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 20:39 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 20:39 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 20:39 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 20:39 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 20:39 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 20:39 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 20:39 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/30/15 20:39 108-90-73.0 0.23 1 Chloroethane ND ug/L 10/30/15 20:39 75-00-310.0 0.54 1 Chloroform 0.56J ug/L 10/30/15 20:39 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 20:39 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 20:39 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 20:39 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 20:39 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 20:39 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/30/15 20:39 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/30/15 20:39 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 20:39 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 10/30/15 20:39 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 10/30/15 20:39 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 20:39 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/30/15 20:39 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 20:39 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 10/30/15 20:39 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 20:39 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 20:39 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 20:39 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/30/15 20:39 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 20:39 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 20:39 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 20:39 108-10-11000.33 1 Styrene ND ug/L 10/30/15 20:39 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 20:39 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 20:39 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 10/30/15 20:39 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 20:39 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 20:39 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 20:39 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/30/15 20:39 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 20:39 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 20:39 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 20:39 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 10/30/15 20:39 75-01-41.0 0.62 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-HW-1 Lab ID:92272834011 Collected:10/19/15 17:50 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Xylene (Total)ND ug/L 10/30/15 20:39 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %10/30/15 20:39 460-00-470-130 1 1,2-Dichloroethane-d4 (S)101 %10/30/15 20:39 17060-07-070-130 1 Toluene-d8 (S)99 %10/30/15 20:39 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-FIELD BLANK Lab ID:92272834012 Collected:10/19/15 16:10 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Arsenic ND ug/L 10/29/15 02:21 7440-38-210/22/15 18:3010.0 2.5 1 Barium ND ug/L 10/29/15 02:21 7440-39-310/22/15 18:301002.5 1 Cadmium ND ug/L 10/29/15 02:21 7440-43-910/22/15 18:301.0 0.50 1 Chromium ND ug/L 10/29/15 02:21 7440-47-310/22/15 18:3010.0 2.5 1 Lead ND ug/L 10/29/15 02:21 7439-92-110/22/15 18:3010.0 2.5 1 Selenium ND ug/L 10/29/15 02:21 7782-49-210/22/15 18:3010.0 5.0 1 Silver ND ug/L 10/29/15 02:21 7440-22-410/22/15 18:3010.0 2.5 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 10/30/15 14:25 7439-97-610/22/15 17:000.20 0.10 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 10/30/15 20:56 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 20:56 107-13-12001.9 1 Benzene ND ug/L 10/30/15 20:56 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 20:56 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 20:56 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 20:56 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 20:56 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 20:56 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 20:56 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 20:56 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/30/15 20:56 108-90-73.0 0.23 1 Chloroethane ND ug/L 10/30/15 20:56 75-00-310.0 0.54 1 Chloroform ND ug/L 10/30/15 20:56 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 20:56 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 20:56 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 20:56 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 20:56 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 20:56 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/30/15 20:56 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/30/15 20:56 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 20:56 110-57-61001.0 1 Dichlorodifluoromethane ND ug/L 10/30/15 20:56 75-71-85.0 0.21 1 1,1-Dichloroethane ND ug/L 10/30/15 20:56 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 10/30/15 20:56 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 20:56 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/30/15 20:56 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 20:56 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 10/30/15 20:56 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 20:56 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 20:56 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 20:56 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/30/15 20:56 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 20:56 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 20:56 75-09-21.0 0.97 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-FIELD BLANK Lab ID:92272834012 Collected:10/19/15 16:10 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 20:56 108-10-11000.33 1 Styrene ND ug/L 10/30/15 20:56 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 20:56 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 20:56 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 10/30/15 20:56 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 20:56 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 20:56 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 20:56 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/30/15 20:56 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 20:56 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 20:56 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 20:56 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 10/30/15 20:56 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/30/15 20:56 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %10/30/15 20:56 460-00-470-130 1 1,2-Dichloroethane-d4 (S)103 %10/30/15 20:56 17060-07-070-130 1 Toluene-d8 (S)100 %10/30/15 20:56 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-TRIP BLANK Lab ID:92272834013 Collected:10/19/15 05:30 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 10/30/15 21:13 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 21:13 107-13-12001.9 1 Benzene ND ug/L 10/30/15 21:13 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 21:13 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 21:13 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 21:13 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 21:13 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 21:13 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 21:13 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 21:13 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/30/15 21:13 108-90-73.0 0.23 1 Chloroethane ND ug/L 10/30/15 21:13 75-00-310.0 0.54 1 Chloroform ND ug/L 10/30/15 21:13 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 21:13 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 21:13 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 21:13 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 21:13 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 21:13 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/30/15 21:13 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/30/15 21:13 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 21:13 110-57-61001.0 1 Dichlorodifluoromethane ND ug/L 10/30/15 21:13 75-71-85.0 0.21 1 1,1-Dichloroethane ND ug/L 10/30/15 21:13 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 10/30/15 21:13 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 21:13 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/30/15 21:13 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 21:13 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 10/30/15 21:13 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 21:13 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 21:13 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 21:13 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/30/15 21:13 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 21:13 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 21:13 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 21:13 108-10-11000.33 1 Styrene ND ug/L 10/30/15 21:13 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 21:13 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 21:13 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 10/30/15 21:13 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 21:13 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 21:13 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 21:13 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/30/15 21:13 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 21:13 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 21:13 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 21:13 108-05-450.0 0.35 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-TRIP BLANK Lab ID:92272834013 Collected:10/19/15 05:30 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Vinyl chloride ND ug/L 10/30/15 21:13 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/30/15 21:13 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)99 %10/30/15 21:13 460-00-470-130 1 1,2-Dichloroethane-d4 (S)103 %10/30/15 21:13 17060-07-070-130 1 Toluene-d8 (S)98 %10/30/15 21:13 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 45 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/8575 EPA 7470 EPA 7470 7470 Mercury Associated Lab Samples:92272834001, 92272834002, 92272834003, 92272834012 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1589279 Associated Lab Samples:92272834001, 92272834002, 92272834003, 92272834012 Matrix:Water AnalyzedMDL Mercury ug/L ND 0.20 10/30/15 14:030.10 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1589280LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 2.12.5 85 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1589283MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92272855003 1589284 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 2.5 99 75-12591 8 252.5ND 2.5 2.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 45 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/19873 EPA 3010 EPA 6010 6010 MET NC Groundwater Associated Lab Samples:92272834001, 92272834002, 92272834003, 92272834012 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1589142 Associated Lab Samples:92272834001, 92272834002, 92272834003, 92272834012 Matrix:Water AnalyzedMDL Arsenic ug/L ND 10.0 10/29/15 01:472.5 Barium ug/L ND 100 10/29/15 01:472.5 Cadmium ug/L ND 1.0 10/29/15 01:470.50 Chromium ug/L ND 10.0 10/29/15 01:472.5 Lead ug/L ND 10.0 10/29/15 01:472.5 Selenium ug/L ND 10.0 10/29/15 01:475.0 Silver ug/L ND 10.0 10/29/15 01:472.5 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1589143LABORATORY CONTROL SAMPLE: LCSSpike Arsenic ug/L 479500 96 80-120 Barium ug/L 479500 96 80-120 Cadmium ug/L 480500 96 80-120 Chromium ug/L 479500 96 80-120 Lead ug/L 478500 96 80-120 Selenium ug/L 466500 93 80-120 Silver ug/L 239250 96 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1589145MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92272822014 1589146 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Arsenic ug/L 500 94 75-12594 1 25500ND471468 Barium ug/L 500 94 75-12593 1 25500ND471466 Cadmium ug/L 500 95 75-12594 1 25500ND476470 Chromium ug/L 500 94 75-12593 1 255002.9J 473 469 Lead ug/L 500 95 75-12593 2 25500ND476468 Selenium ug/L 500 92 75-12591 2 25500ND461454 Silver ug/L 250 94 75-12594 0 25250ND234234 Parameter Units MS Result % Rec Limits Qual% RecConc. 1589147MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92272855003 1589148 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Arsenic ug/L 500 96 75-12592 5 25500ND481460 Barium ug/L 500 96 75-12593 3 2550078.4 560 542 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 45 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1589147MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92272855003 1589148 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Cadmium ug/L 500 97 75-12593 4 25500ND487468 Chromium ug/L 500 97 75-12594 3 25500ND487471 Lead ug/L 500 96 75-12593 3 25500ND483466 Selenium ug/L 500 94 75-12590 4 25500ND470449 Silver ug/L 250 97 75-12593 4 25250ND242233 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 45 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MSV/34057 EPA 8260 EPA 8260 8260 MSV Low Level Landfill Associated Lab Samples:92272834001, 92272834002, 92272834003, 92272834004, 92272834005, 92272834006, 92272834007, 92272834008, 92272834009, 92272834010, 92272834011, 92272834012, 92272834013 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1595566 Associated Lab Samples:92272834001, 92272834002, 92272834003, 92272834004, 92272834005, 92272834006, 92272834007, 92272834008, 92272834009, 92272834010, 92272834011, 92272834012, 92272834013 Matrix:Water AnalyzedMDL 1,1,1,2-Tetrachloroethane ug/L ND 5.0 10/30/15 12:010.33 1,1,1-Trichloroethane ug/L ND 1.0 10/30/15 12:010.48 1,1,2,2-Tetrachloroethane ug/L ND 3.0 10/30/15 12:010.40 1,1,2-Trichloroethane ug/L ND 1.0 10/30/15 12:010.29 1,1-Dichloroethane ug/L ND 5.0 10/30/15 12:010.32 1,1-Dichloroethene ug/L ND 5.0 10/30/15 12:010.56 1,2,3-Trichloropropane ug/L ND 1.0 10/30/15 12:010.41 1,2-Dibromo-3-chloropropane ug/L ND 13.0 10/30/15 12:012.0 1,2-Dibromoethane (EDB)ug/L ND 1.0 10/30/15 12:010.27 1,2-Dichlorobenzene ug/L ND 5.0 10/30/15 12:010.30 1,2-Dichloroethane ug/L ND 1.0 10/30/15 12:010.24 1,2-Dichloropropane ug/L ND 1.0 10/30/15 12:010.27 1,4-Dichlorobenzene ug/L ND 1.0 10/30/15 12:010.33 2-Butanone (MEK)ug/L ND 100 10/30/15 12:010.96 2-Hexanone ug/L ND 50.0 10/30/15 12:010.46 4-Methyl-2-pentanone (MIBK)ug/L ND 100 10/30/15 12:010.33 Acetone ug/L ND 100 10/30/15 12:0110.0 Acrylonitrile ug/L ND 200 10/30/15 12:011.9 Benzene ug/L ND 1.0 10/30/15 12:010.25 Bromochloromethane ug/L ND 3.0 10/30/15 12:010.17 Bromodichloromethane ug/L ND 1.0 10/30/15 12:010.18 Bromoform ug/L ND 3.0 10/30/15 12:010.26 Bromomethane ug/L ND 10.0 10/30/15 12:010.29 Carbon disulfide ug/L ND 100 10/30/15 12:011.2 Carbon tetrachloride ug/L ND 1.0 10/30/15 12:010.25 Chlorobenzene ug/L ND 3.0 10/30/15 12:010.23 Chloroethane ug/L ND 10.0 10/30/15 12:010.54 Chloroform ug/L ND 5.0 10/30/15 12:010.14 Chloromethane ug/L ND 1.0 10/30/15 12:010.11 cis-1,2-Dichloroethene ug/L ND 5.0 10/30/15 12:010.19 cis-1,3-Dichloropropene ug/L ND 1.0 10/30/15 12:010.13 Dibromochloromethane ug/L ND 3.0 10/30/15 12:010.21 Dibromomethane ug/L ND 10.0 10/30/15 12:010.21 Dichlorodifluoromethane ug/L ND 5.0 10/30/15 12:010.21 Ethylbenzene ug/L ND 1.0 10/30/15 12:010.30 Iodomethane ug/L ND 10.0 10/30/15 12:010.32 Methylene Chloride ug/L ND 1.0 10/30/15 12:010.97 Styrene ug/L ND 1.0 10/30/15 12:010.26 Tetrachloroethene ug/L ND 1.0 10/30/15 12:010.46 Toluene ug/L ND 1.0 10/30/15 12:010.26 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 36 of 45 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1595566 Associated Lab Samples:92272834001, 92272834002, 92272834003, 92272834004, 92272834005, 92272834006, 92272834007, 92272834008, 92272834009, 92272834010, 92272834011, 92272834012, 92272834013 Matrix:Water AnalyzedMDL trans-1,2-Dichloroethene ug/L ND 5.0 10/30/15 12:010.49 trans-1,3-Dichloropropene ug/L ND 1.0 10/30/15 12:010.26 trans-1,4-Dichloro-2-butene ug/L ND 100 10/30/15 12:011.0 Trichloroethene ug/L ND 1.0 10/30/15 12:010.47 Trichlorofluoromethane ug/L ND 1.0 10/30/15 12:010.20 Vinyl acetate ug/L ND 50.0 10/30/15 12:010.35 Vinyl chloride ug/L ND 1.0 10/30/15 12:010.62 Xylene (Total)ug/L ND 5.0 10/30/15 12:010.66 1,2-Dichloroethane-d4 (S)%101 70-130 10/30/15 12:01 4-Bromofluorobenzene (S)%101 70-130 10/30/15 12:01 Toluene-d8 (S)%100 70-130 10/30/15 12:01 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1595567LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 50.350 101 80-125 1,1,1-Trichloroethane ug/L 54.450 109 71-129 1,1,2,2-Tetrachloroethane ug/L 51.150 102 79-124 1,1,2-Trichloroethane ug/L 48.450 97 85-125 1,1-Dichloroethane ug/L 51.650 103 73-126 1,1-Dichloroethene ug/L 54.750 109 66-135 1,2,3-Trichloropropane ug/L 48.950 98 75-130 1,2-Dibromo-3-chloropropane ug/L 52.150 104 71-133 1,2-Dibromoethane (EDB)ug/L 50.750 101 83-124 1,2-Dichlorobenzene ug/L 50.950 102 80-133 1,2-Dichloroethane ug/L 46.150 92 67-128 1,2-Dichloropropane ug/L 48.950 98 75-132 1,4-Dichlorobenzene ug/L 50.450 101 78-130 2-Butanone (MEK)ug/L 97.4J100 97 61-144 2-Hexanone ug/L 102100 102 68-143 4-Methyl-2-pentanone (MIBK)ug/L 101100 101 72-135 Acetone ug/L 96.2J100 96 48-146 Acrylonitrile ug/L 247250 99 40-160 Benzene ug/L 51.350 103 80-125 Bromochloromethane ug/L 51.550 103 71-125 Bromodichloromethane ug/L 51.950 104 78-124 Bromoform ug/L 50.950 102 71-128 Bromomethane ug/L 50.750 101 40-160 Carbon disulfide ug/L 53.7J50 107 50-160 Carbon tetrachloride ug/L 54.950 110 69-131 Chlorobenzene ug/L 49.650 99 81-122 Chloroethane ug/L 47.250 94 39-148 Chloroform ug/L 51.050 102 73-127 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 37 of 45 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1595567LABORATORY CONTROL SAMPLE: LCSSpike Chloromethane ug/L 45.950 92 44-146 cis-1,2-Dichloroethene ug/L 49.650 99 74-124 cis-1,3-Dichloropropene ug/L 52.850 106 72-132 Dibromochloromethane ug/L 52.950 106 78-125 Dibromomethane ug/L 50.350 101 82-120 Dichlorodifluoromethane ug/L 47.050 94 34-157 Ethylbenzene ug/L 51.550 103 79-121 Iodomethane ug/L 100100 100 39-154 Methylene Chloride ug/L 52.850 106 64-133 Styrene ug/L 51.550 103 84-126 Tetrachloroethene ug/L 53.150 106 78-122 Toluene ug/L 51.050 102 80-121 trans-1,2-Dichloroethene ug/L 51.350 103 71-127 trans-1,3-Dichloropropene ug/L 51.750 103 69-141 trans-1,4-Dichloro-2-butene ug/L 49.0J50 98 40-160 Trichloroethene ug/L 49.950 100 78-122 Trichlorofluoromethane ug/L 52.350 105 53-137 Vinyl acetate ug/L 104100 104 40-160 Vinyl chloride ug/L 56.250 112 58-137 Xylene (Total)ug/L 155150 103 81-126 1,2-Dichloroethane-d4 (S)%97 70-130 4-Bromofluorobenzene (S)%103 70-130 Toluene-d8 (S)%100 70-130 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1595568MATRIX SPIKE SAMPLE: MSSpike Result 92272834001 1,1,1,2-Tetrachloroethane ug/L 21.520 107 70-130ND 1,1,1-Trichloroethane ug/L 24.520 123 70-130ND 1,1,2,2-Tetrachloroethane ug/L 22.120 111 70-130ND 1,1,2-Trichloroethane ug/L 21.120 106 70-130ND 1,1-Dichloroethane ug/L 23.420 117 70-130ND 1,1-Dichloroethene ug/L 25.520 128 70-166ND 1,2,3-Trichloropropane ug/L 21.820 109 70-130ND 1,2-Dibromo-3-chloropropane ug/L 21.120 106 70-130ND 1,2-Dibromoethane (EDB)ug/L 22.020 110 70-130ND 1,2-Dichlorobenzene ug/L 22.020 110 70-130ND 1,2-Dichloroethane ug/L 20.520 102 70-130ND 1,2-Dichloropropane ug/L 22.120 111 70-130ND 1,4-Dichlorobenzene ug/L 22.220 110 70-130ND 2-Butanone (MEK)ug/L 42.5J40 106 70-130ND 2-Hexanone ug/L 44.6J40 112 70-130ND 4-Methyl-2-pentanone (MIBK)ug/L 43.4J40 109 70-130ND Acetone ug/L 43.4J40 103 70-130ND Acrylonitrile ug/L 108J100 108 70-130ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 38 of 45 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1595568MATRIX SPIKE SAMPLE: MSSpike Result 92272834001 Benzene ug/L 23.120 115 70-148ND Bromochloromethane ug/L 23.620 118 70-130ND Bromodichloromethane ug/L 22.620 113 70-130ND Bromoform ug/L 19.720 99 70-130ND Bromomethane ug/L 18.320 91 70-130ND Carbon disulfide ug/L 24.2J20 121 70-130ND Carbon tetrachloride ug/L 24.720 124 70-130ND Chlorobenzene ug/L 22.220 111 70-146ND Chloroethane ug/L 23.720 119 70-130ND Chloroform ug/L 22.920 115 70-130ND Chloromethane ug/L 23.520 117 70-130ND cis-1,2-Dichloroethene ug/L 22.220 111 70-130ND cis-1,3-Dichloropropene ug/L 21.520 108 70-130ND Dibromochloromethane ug/L 21.520 108 70-130ND Dibromomethane ug/L 21.620 108 70-130ND Dichlorodifluoromethane ug/L 26.020 130 70-130ND Ethylbenzene ug/L 22.820 114 70-130ND Iodomethane ug/L 40.640 101 70-130ND Methylene Chloride ug/L 23.020 115 70-130ND Styrene ug/L 21.320 106 70-130ND Tetrachloroethene ug/L 23.120 115 70-130ND Toluene ug/L 22.520 112 70-155ND trans-1,2-Dichloroethene ug/L 23.920 120 70-130ND trans-1,3-Dichloropropene ug/L 21.120 105 70-130ND trans-1,4-Dichloro-2-butene ug/L 20.4J20 102 70-130ND Trichloroethene ug/L 22.220 111 69-151ND Trichlorofluoromethane ug/L 25.820 129 70-130ND Vinyl acetate ug/L 42.8J40 107 70-130ND Vinyl chloride ug/L 27.4 M12013770-130ND 1,2-Dichloroethane-d4 (S)%98 70-130 4-Bromofluorobenzene (S)%103 70-130 Toluene-d8 (S)%100 70-130 Parameter Units Dup Result Max RPD QualifiersRPDResult 92272834002 1595569SAMPLE DUPLICATE: 1,1,1,2-Tetrachloroethane ug/L ND 30ND 1,1,1-Trichloroethane ug/L ND 30ND 1,1,2,2-Tetrachloroethane ug/L ND 30ND 1,1,2-Trichloroethane ug/L ND 30ND 1,1-Dichloroethane ug/L ND 30ND 1,1-Dichloroethene ug/L ND 30ND 1,2,3-Trichloropropane ug/L ND 30ND 1,2-Dibromo-3-chloropropane ug/L ND 30ND 1,2-Dibromoethane (EDB)ug/L ND 30ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 39 of 45 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result Max RPD QualifiersRPDResult 92272834002 1595569SAMPLE DUPLICATE: 1,2-Dichlorobenzene ug/L ND 30ND 1,2-Dichloroethane ug/L ND 30ND 1,2-Dichloropropane ug/L ND 30ND 1,4-Dichlorobenzene ug/L 0.65J 300.61J 2-Butanone (MEK)ug/L ND 30ND 2-Hexanone ug/L ND 30ND 4-Methyl-2-pentanone (MIBK)ug/L ND 30ND Acetone ug/L ND 30ND Acrylonitrile ug/L ND 30ND Benzene ug/L 0.67J 300.68J Bromochloromethane ug/L ND 30ND Bromodichloromethane ug/L ND 30ND Bromoform ug/L ND 30ND Bromomethane ug/L ND 30ND Carbon disulfide ug/L ND 30ND Carbon tetrachloride ug/L ND 30ND Chlorobenzene ug/L 0.61J 300.59J Chloroethane ug/L ND 30ND Chloroform ug/L ND 30ND Chloromethane ug/L ND 30ND cis-1,2-Dichloroethene ug/L 0.93J 300.95J cis-1,3-Dichloropropene ug/L ND 30ND Dibromochloromethane ug/L ND 30ND Dibromomethane ug/L ND 30ND Dichlorodifluoromethane ug/L ND 30ND Ethylbenzene ug/L ND 30ND Iodomethane ug/L ND 30ND Methylene Chloride ug/L ND 30ND Styrene ug/L ND 30ND Tetrachloroethene ug/L ND 30ND Toluene ug/L ND 30ND trans-1,2-Dichloroethene ug/L ND 30ND trans-1,3-Dichloropropene ug/L ND 30ND trans-1,4-Dichloro-2-butene ug/L ND 30ND Trichloroethene ug/L ND 30ND Trichlorofluoromethane ug/L ND 30ND Vinyl acetate ug/L ND 30ND Vinyl chloride ug/L ND 30ND Xylene (Total)ug/L ND 30ND 1,2-Dichloroethane-d4 (S)%101 1102 4-Bromofluorobenzene (S)%101 0100 Toluene-d8 (S)%100 1100 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 40 of 45 #=QL# QUALIFIERS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - CharlottePASI-C ANALYTE QUALIFIERS Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 41 of 45 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92272834001 MPRP/19873 ICP/179218803-MW1 EPA 3010 EPA 6010 92272834002 MPRP/19873 ICP/179218803-MW2 EPA 3010 EPA 6010 92272834003 MPRP/19873 ICP/179218803-MW3 EPA 3010 EPA 6010 92272834012 MPRP/19873 ICP/179218803-FIELD BLANK EPA 3010 EPA 6010 92272834001 MERP/8575 MERC/82378803-MW1 EPA 7470 EPA 7470 92272834002 MERP/8575 MERC/82378803-MW2 EPA 7470 EPA 7470 92272834003 MERP/8575 MERC/82378803-MW3 EPA 7470 EPA 7470 92272834012 MERP/8575 MERC/82378803-FIELD BLANK EPA 7470 EPA 7470 92272834001 MSV/340578803-MW1 EPA 8260 92272834002 MSV/340578803-MW2 EPA 8260 92272834003 MSV/340578803-MW3 EPA 8260 92272834004 MSV/340578803-MW105S EPA 8260 92272834005 MSV/340578803-MW105D EPA 8260 92272834006 MSV/340578803-MW106S EPA 8260 92272834007 MSV/340578803-MW106D EPA 8260 92272834008 MSV/340578803-MW107S EPA 8260 92272834009 MSV/340578803-MW107D EPA 8260 92272834010 MSV/340578803-MW108 EPA 8260 92272834011 MSV/340578803-HW-1 EPA 8260 92272834012 MSV/340578803-FIELD BLANK EPA 8260 92272834013 MSV/340578803-TRIP BLANK EPA 8260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 42 of 45 Page 43 of 45 Page 44 of 45 Page 45 of 45 #=CL# November 02, 2015 LIMS USE: FR - ALEX EVERHART LIMS OBJECT ID: 92272834 92272834 Project: Pace Project No.: RE: Mr. Alex Everhart Joyce Engineering-NC 2211 W. Meadowview Road Suite 101 Greensboro, NC 27407 TRANSYLVANIA-CALVERT Dear Mr. Everhart: Enclosed are the analytical results for sample(s) received by the laboratory on October 21, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Godwin kevin.godwin@pacelabs.com Project Manager Enclosures cc:Mr. Van Burbach, Joyce Engineering-NC Alex Everhart, Joyce Engineering-NC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 45 #=CP# CERTIFICATIONS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84 West Virginia Certification #: 357Virginia/VELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 45 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Lab ID Sample ID Matrix Date Collected Date Received 92272834001 8803-MW1 Water 10/19/15 11:08 10/21/15 14:45 92272834002 8803-MW2 Water 10/19/15 12:36 10/21/15 14:45 92272834003 8803-MW3 Water 10/19/15 17:43 10/21/15 14:45 92272834004 8803-MW105S Water 10/19/15 15:48 10/21/15 14:45 92272834005 8803-MW105D Water 10/19/15 14:05 10/21/15 14:45 92272834006 8803-MW106S Water 10/19/15 17:45 10/21/15 14:45 92272834007 8803-MW106D Water 10/19/15 17:35 10/21/15 14:45 92272834008 8803-MW107S Water 10/19/15 13:00 10/21/15 14:45 92272834009 8803-MW107D Water 10/19/15 12:15 10/21/15 14:45 92272834010 8803-MW108 Water 10/19/15 10:14 10/21/15 14:45 92272834011 8803-HW-1 Water 10/19/15 17:50 10/21/15 14:45 92272834012 8803-FIELD BLANK Water 10/19/15 16:10 10/21/15 14:45 92272834013 8803-TRIP BLANK Water 10/19/15 05:30 10/21/15 14:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 45 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92272834001 8803-MW1 EPA 6010 7 PASI-ACDF EPA 7470 1 PASI-AHVK EPA 8260 50 PASI-CCAH 92272834002 8803-MW2 EPA 6010 7 PASI-ACDF EPA 7470 1 PASI-AHVK EPA 8260 50 PASI-CCAH 92272834003 8803-MW3 EPA 6010 7 PASI-ACDF EPA 7470 1 PASI-AHVK EPA 8260 50 PASI-CCAH 92272834004 8803-MW105S EPA 8260 51 PASI-CCAH 92272834005 8803-MW105D EPA 8260 51 PASI-CCAH 92272834006 8803-MW106S EPA 8260 50 PASI-CCAH 92272834007 8803-MW106D EPA 8260 50 PASI-CCAH 92272834008 8803-MW107S EPA 8260 50 PASI-CCAH 92272834009 8803-MW107D EPA 8260 50 PASI-CCAH 92272834010 8803-MW108 EPA 8260 50 PASI-CCAH 92272834011 8803-HW-1 EPA 8260 50 PASI-CCAH 92272834012 8803-FIELD BLANK EPA 6010 7 PASI-ACDF EPA 7470 1 PASI-AHVK EPA 8260 51 PASI-CCAH 92272834013 8803-TRIP BLANK EPA 8260 51 PASI-CCAH REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 45 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92272834001 8803-MW1 Barium 76.7J ug/L 10/29/15 02:11100EPA 6010 Cadmium 1.9 ug/L 10/29/15 02:111.0EPA 6010 Chromium 4.7J ug/L 10/29/15 02:1110.0EPA 6010 Lead 7.5J ug/L 10/29/15 02:1110.0EPA 6010 92272834002 8803-MW2 Barium 80.8J ug/L 10/29/15 02:15100EPA 6010 Chromium 3.4J ug/L 10/29/15 02:1510.0EPA 6010 Lead 3.9J ug/L 10/29/15 02:1510.0EPA 6010 Silver 4.3J ug/L 10/29/15 02:1510.0EPA 6010 Benzene 0.68J ug/L 10/30/15 17:521.0EPA 8260 Chlorobenzene 0.59J ug/L 10/30/15 17:523.0EPA 8260 1,4-Dichlorobenzene 0.61J ug/L 10/30/15 17:521.0EPA 8260 cis-1,2-Dichloroethene 0.95J ug/L 10/30/15 17:525.0EPA 8260 92272834003 8803-MW3 Barium 80.5J ug/L 10/29/15 02:18100EPA 6010 Chromium 3.0J ug/L 10/29/15 02:1810.0EPA 6010 Benzene 1.1 ug/L 10/30/15 18:261.0EPA 8260 Chlorobenzene 10.8 ug/L 10/30/15 18:263.0EPA 8260 1,2-Dichlorobenzene 0.75J ug/L 10/30/15 18:265.0EPA 8260 1,4-Dichlorobenzene 13.1 ug/L 10/30/15 18:261.0EPA 8260 cis-1,2-Dichloroethene 0.90J ug/L 10/30/15 18:265.0EPA 8260 Vinyl chloride 0.91J ug/L 10/30/15 18:261.0EPA 8260 92272834004 8803-MW105S Benzene 0.80J ug/L 10/30/15 18:421.0EPA 8260 Chlorobenzene 2.6J ug/L 10/30/15 18:423.0EPA 8260 1,4-Dichlorobenzene 2.4 ug/L 10/30/15 18:421.0EPA 8260 Dichlorodifluoromethane 1.5J ug/L 10/30/15 18:425.0EPA 8260 cis-1,2-Dichloroethene 0.65J ug/L 10/30/15 18:425.0EPA 8260 92272834005 8803-MW105D Benzene 2.2 ug/L 10/30/15 18:591.0EPA 8260 Chlorobenzene 12.2 ug/L 10/30/15 18:593.0EPA 8260 1,4-Dichlorobenzene 6.7 ug/L 10/30/15 18:591.0EPA 8260 Dichlorodifluoromethane 0.82J ug/L 10/30/15 18:595.0EPA 8260 1,2-Dichloroethane 0.50J ug/L 10/30/15 18:591.0EPA 8260 cis-1,2-Dichloroethene 13.4 ug/L 10/30/15 18:595.0EPA 8260 1,2-Dichloropropane 0.99J ug/L 10/30/15 18:591.0EPA 8260 Tetrachloroethene 0.60J ug/L 10/30/15 18:591.0EPA 8260 Trichloroethene 1.1 ug/L 10/30/15 18:591.0EPA 8260 Vinyl chloride 1.0J ug/L 10/30/15 18:591.0EPA 8260 92272834006 8803-MW106S cis-1,2-Dichloroethene 0.91J ug/L 10/30/15 19:165.0EPA 8260 92272834007 8803-MW106D Benzene 0.40J ug/L 10/30/15 19:321.0EPA 8260 Chlorobenzene 6.3 ug/L 10/30/15 19:323.0EPA 8260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 45 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92272834007 8803-MW106D 1,2-Dichlorobenzene 0.37J ug/L 10/30/15 19:325.0EPA 8260 1,4-Dichlorobenzene 5.7 ug/L 10/30/15 19:321.0EPA 8260 1,2-Dichloroethane 0.29J ug/L 10/30/15 19:321.0EPA 8260 cis-1,2-Dichloroethene 2.5J ug/L 10/30/15 19:325.0EPA 8260 1,2-Dichloropropane 0.37J ug/L 10/30/15 19:321.0EPA 8260 92272834008 8803-MW107S 2-Hexanone 0.71J ug/L 10/30/15 19:4950.0EPA 8260 92272834009 8803-MW107D Benzene 0.49J ug/L 10/30/15 20:061.0EPA 8260 Chlorobenzene 0.61J ug/L 10/30/15 20:063.0EPA 8260 Chloroethane 0.75J ug/L 10/30/15 20:0610.0EPA 8260 1,4-Dichlorobenzene 1.1 ug/L 10/30/15 20:061.0EPA 8260 1,1-Dichloroethane 0.74J ug/L 10/30/15 20:065.0EPA 8260 cis-1,2-Dichloroethene 0.75J ug/L 10/30/15 20:065.0EPA 8260 92272834010 8803-MW108 Acetone 19.8J ug/L 10/30/15 20:23100EPA 8260 Benzene 0.39J ug/L 10/30/15 20:231.0EPA 8260 Chlorobenzene 0.56J ug/L 10/30/15 20:233.0EPA 8260 Chloroethane 1.2J ug/L 10/30/15 20:2310.0EPA 8260 1,4-Dichlorobenzene 1.1 ug/L 10/30/15 20:231.0EPA 8260 1,1-Dichloroethane 1.6J ug/L 10/30/15 20:235.0EPA 8260 cis-1,2-Dichloroethene 1.4J ug/L 10/30/15 20:235.0EPA 8260 92272834011 8803-HW-1 Chloroform 0.56J ug/L 10/30/15 20:395.0EPA 8260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW1 Lab ID:92272834001 Collected:10/19/15 11:08 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Arsenic ND ug/L 10/29/15 02:11 7440-38-210/22/15 18:3010.0 2.5 1 Barium 76.7J ug/L 10/29/15 02:11 7440-39-310/22/15 18:301002.5 1 Cadmium 1.9 ug/L 10/29/15 02:11 7440-43-910/22/15 18:301.0 0.50 1 Chromium 4.7J ug/L 10/29/15 02:11 7440-47-310/22/15 18:3010.0 2.5 1 Lead 7.5J ug/L 10/29/15 02:11 7439-92-110/22/15 18:3010.0 2.5 1 Selenium ND ug/L 10/29/15 02:11 7782-49-210/22/15 18:3010.0 5.0 1 Silver ND ug/L 10/29/15 02:11 7440-22-410/22/15 18:3010.0 2.5 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 10/30/15 14:18 7439-97-610/22/15 17:000.20 0.10 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 10/30/15 17:36 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 17:36 107-13-12001.9 1 Benzene ND ug/L 10/30/15 17:36 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 17:36 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 17:36 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 17:36 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 17:36 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 17:36 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 17:36 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 17:36 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/30/15 17:36 108-90-73.0 0.23 1 Chloroethane ND ug/L 10/30/15 17:36 75-00-310.0 0.54 1 Chloroform ND ug/L 10/30/15 17:36 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 17:36 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 17:36 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 17:36 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 17:36 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 17:36 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/30/15 17:36 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/30/15 17:36 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 17:36 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 10/30/15 17:36 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 10/30/15 17:36 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 17:36 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/30/15 17:36 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 17:36 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 10/30/15 17:36 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 17:36 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 17:36 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 17:36 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/30/15 17:36 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 17:36 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 17:36 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 17:36 108-10-11000.33 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW1 Lab ID:92272834001 Collected:10/19/15 11:08 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Styrene ND ug/L 10/30/15 17:36 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 17:36 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 17:36 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 10/30/15 17:36 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 17:36 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 17:36 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 17:36 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/30/15 17:36 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 17:36 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 17:36 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 17:36 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 10/30/15 17:36 75-01-4 M11.0 0.62 1 Xylene (Total)ND ug/L 10/30/15 17:36 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %10/30/15 17:36 460-00-470-130 1 1,2-Dichloroethane-d4 (S)102 %10/30/15 17:36 17060-07-070-130 1 Toluene-d8 (S)101 %10/30/15 17:36 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW2 Lab ID:92272834002 Collected:10/19/15 12:36 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Arsenic ND ug/L 10/29/15 02:15 7440-38-210/22/15 18:3010.0 2.5 1 Barium 80.8J ug/L 10/29/15 02:15 7440-39-310/22/15 18:301002.5 1 Cadmium ND ug/L 10/29/15 02:15 7440-43-910/22/15 18:301.0 0.50 1 Chromium 3.4J ug/L 10/29/15 02:15 7440-47-310/22/15 18:3010.0 2.5 1 Lead 3.9J ug/L 10/29/15 02:15 7439-92-110/22/15 18:3010.0 2.5 1 Selenium ND ug/L 10/29/15 02:15 7782-49-210/22/15 18:3010.0 5.0 1 Silver 4.3J ug/L 10/29/15 02:15 7440-22-410/22/15 18:3010.0 2.5 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 10/30/15 14:20 7439-97-610/22/15 17:000.20 0.10 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 10/30/15 17:52 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 17:52 107-13-12001.9 1 Benzene 0.68J ug/L 10/30/15 17:52 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 17:52 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 17:52 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 17:52 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 17:52 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 17:52 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 17:52 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 17:52 56-23-51.0 0.25 1 Chlorobenzene 0.59J ug/L 10/30/15 17:52 108-90-73.0 0.23 1 Chloroethane ND ug/L 10/30/15 17:52 75-00-310.0 0.54 1 Chloroform ND ug/L 10/30/15 17:52 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 17:52 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 17:52 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 17:52 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 17:52 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 17:52 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/30/15 17:52 95-50-15.0 0.30 1 1,4-Dichlorobenzene 0.61J ug/L 10/30/15 17:52 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 17:52 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 10/30/15 17:52 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 10/30/15 17:52 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 17:52 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 0.95J ug/L 10/30/15 17:52 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 17:52 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 10/30/15 17:52 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 17:52 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 17:52 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 17:52 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/30/15 17:52 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 17:52 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 17:52 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 17:52 108-10-11000.33 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW2 Lab ID:92272834002 Collected:10/19/15 12:36 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Styrene ND ug/L 10/30/15 17:52 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 17:52 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 17:52 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 10/30/15 17:52 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 17:52 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 17:52 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 17:52 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/30/15 17:52 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 17:52 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 17:52 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 17:52 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 10/30/15 17:52 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/30/15 17:52 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %10/30/15 17:52 460-00-470-130 1 1,2-Dichloroethane-d4 (S)102 %10/30/15 17:52 17060-07-070-130 1 Toluene-d8 (S)100 %10/30/15 17:52 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW3 Lab ID:92272834003 Collected:10/19/15 17:43 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Arsenic ND ug/L 10/29/15 02:18 7440-38-210/22/15 18:3010.0 2.5 1 Barium 80.5J ug/L 10/29/15 02:18 7440-39-310/22/15 18:301002.5 1 Cadmium ND ug/L 10/29/15 02:18 7440-43-910/22/15 18:301.0 0.50 1 Chromium 3.0J ug/L 10/29/15 02:18 7440-47-310/22/15 18:3010.0 2.5 1 Lead ND ug/L 10/29/15 02:18 7439-92-110/22/15 18:3010.0 2.5 1 Selenium ND ug/L 10/29/15 02:18 7782-49-210/22/15 18:3010.0 5.0 1 Silver ND ug/L 10/29/15 02:18 7440-22-410/22/15 18:3010.0 2.5 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 10/30/15 14:22 7439-97-610/22/15 17:000.20 0.10 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 10/30/15 18:26 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 18:26 107-13-12001.9 1 Benzene 1.1 ug/L 10/30/15 18:26 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 18:26 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 18:26 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 18:26 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 18:26 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 18:26 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 18:26 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 18:26 56-23-51.0 0.25 1 Chlorobenzene 10.8 ug/L 10/30/15 18:26 108-90-73.0 0.23 1 Chloroethane ND ug/L 10/30/15 18:26 75-00-310.0 0.54 1 Chloroform ND ug/L 10/30/15 18:26 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 18:26 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 18:26 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 18:26 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 18:26 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 18:26 74-95-310.0 0.21 1 1,2-Dichlorobenzene 0.75J ug/L 10/30/15 18:26 95-50-15.0 0.30 1 1,4-Dichlorobenzene 13.1 ug/L 10/30/15 18:26 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 18:26 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 10/30/15 18:26 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 10/30/15 18:26 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 18:26 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 0.90J ug/L 10/30/15 18:26 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 18:26 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 10/30/15 18:26 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 18:26 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 18:26 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 18:26 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/30/15 18:26 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 18:26 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 18:26 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 18:26 108-10-11000.33 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW3 Lab ID:92272834003 Collected:10/19/15 17:43 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Styrene ND ug/L 10/30/15 18:26 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 18:26 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 18:26 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 10/30/15 18:26 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 18:26 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 18:26 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 18:26 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/30/15 18:26 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 18:26 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 18:26 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 18:26 108-05-450.0 0.35 1 Vinyl chloride 0.91J ug/L 10/30/15 18:26 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/30/15 18:26 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %10/30/15 18:26 460-00-470-130 1 1,2-Dichloroethane-d4 (S)103 %10/30/15 18:26 17060-07-070-130 1 Toluene-d8 (S)99 %10/30/15 18:26 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW105S Lab ID:92272834004 Collected:10/19/15 15:48 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 10/30/15 18:42 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 18:42 107-13-12001.9 1 Benzene 0.80J ug/L 10/30/15 18:42 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 18:42 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 18:42 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 18:42 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 18:42 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 18:42 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 18:42 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 18:42 56-23-51.0 0.25 1 Chlorobenzene 2.6J ug/L 10/30/15 18:42 108-90-73.0 0.23 1 Chloroethane ND ug/L 10/30/15 18:42 75-00-310.0 0.54 1 Chloroform ND ug/L 10/30/15 18:42 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 18:42 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 18:42 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 18:42 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 18:42 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 18:42 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/30/15 18:42 95-50-15.0 0.30 1 1,4-Dichlorobenzene 2.4 ug/L 10/30/15 18:42 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 18:42 110-57-61001.0 1 Dichlorodifluoromethane 1.5J ug/L 10/30/15 18:42 75-71-85.0 0.21 1 1,1-Dichloroethane ND ug/L 10/30/15 18:42 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 10/30/15 18:42 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 18:42 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 0.65J ug/L 10/30/15 18:42 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 18:42 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 10/30/15 18:42 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 18:42 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 18:42 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 18:42 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/30/15 18:42 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 18:42 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 18:42 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 18:42 108-10-11000.33 1 Styrene ND ug/L 10/30/15 18:42 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 18:42 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 18:42 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 10/30/15 18:42 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 18:42 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 18:42 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 18:42 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/30/15 18:42 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 18:42 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 18:42 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 18:42 108-05-450.0 0.35 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW105S Lab ID:92272834004 Collected:10/19/15 15:48 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Vinyl chloride ND ug/L 10/30/15 18:42 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/30/15 18:42 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)99 %10/30/15 18:42 460-00-470-130 1 1,2-Dichloroethane-d4 (S)102 %10/30/15 18:42 17060-07-070-130 1 Toluene-d8 (S)100 %10/30/15 18:42 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW105D Lab ID:92272834005 Collected:10/19/15 14:05 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 10/30/15 18:59 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 18:59 107-13-12001.9 1 Benzene 2.2 ug/L 10/30/15 18:59 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 18:59 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 18:59 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 18:59 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 18:59 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 18:59 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 18:59 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 18:59 56-23-51.0 0.25 1 Chlorobenzene 12.2 ug/L 10/30/15 18:59 108-90-73.0 0.23 1 Chloroethane ND ug/L 10/30/15 18:59 75-00-310.0 0.54 1 Chloroform ND ug/L 10/30/15 18:59 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 18:59 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 18:59 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 18:59 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 18:59 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 18:59 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/30/15 18:59 95-50-15.0 0.30 1 1,4-Dichlorobenzene 6.7 ug/L 10/30/15 18:59 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 18:59 110-57-61001.0 1 Dichlorodifluoromethane 0.82J ug/L 10/30/15 18:59 75-71-85.0 0.21 1 1,1-Dichloroethane ND ug/L 10/30/15 18:59 75-34-35.0 0.32 1 1,2-Dichloroethane 0.50J ug/L 10/30/15 18:59 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 18:59 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 13.4 ug/L 10/30/15 18:59 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 18:59 156-60-55.0 0.49 1 1,2-Dichloropropane 0.99J ug/L 10/30/15 18:59 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 18:59 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 18:59 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 18:59 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/30/15 18:59 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 18:59 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 18:59 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 18:59 108-10-11000.33 1 Styrene ND ug/L 10/30/15 18:59 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 18:59 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 18:59 79-34-53.0 0.40 1 Tetrachloroethene 0.60J ug/L 10/30/15 18:59 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 18:59 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 18:59 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 18:59 79-00-51.0 0.29 1 Trichloroethene 1.1 ug/L 10/30/15 18:59 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 18:59 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 18:59 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 18:59 108-05-450.0 0.35 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW105D Lab ID:92272834005 Collected:10/19/15 14:05 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Vinyl chloride 1.0J ug/L 10/30/15 18:59 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/30/15 18:59 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %10/30/15 18:59 460-00-470-130 1 1,2-Dichloroethane-d4 (S)100 %10/30/15 18:59 17060-07-070-130 1 Toluene-d8 (S)100 %10/30/15 18:59 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW106S Lab ID:92272834006 Collected:10/19/15 17:45 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 10/30/15 19:16 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 19:16 107-13-12001.9 1 Benzene ND ug/L 10/30/15 19:16 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 19:16 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 19:16 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 19:16 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 19:16 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 19:16 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 19:16 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 19:16 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/30/15 19:16 108-90-73.0 0.23 1 Chloroethane ND ug/L 10/30/15 19:16 75-00-310.0 0.54 1 Chloroform ND ug/L 10/30/15 19:16 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 19:16 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 19:16 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 19:16 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 19:16 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 19:16 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/30/15 19:16 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/30/15 19:16 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 19:16 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 10/30/15 19:16 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 10/30/15 19:16 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 19:16 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 0.91J ug/L 10/30/15 19:16 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 19:16 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 10/30/15 19:16 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 19:16 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 19:16 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 19:16 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/30/15 19:16 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 19:16 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 19:16 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 19:16 108-10-11000.33 1 Styrene ND ug/L 10/30/15 19:16 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 19:16 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 19:16 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 10/30/15 19:16 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 19:16 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 19:16 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 19:16 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/30/15 19:16 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 19:16 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 19:16 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 19:16 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 10/30/15 19:16 75-01-41.0 0.62 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW106S Lab ID:92272834006 Collected:10/19/15 17:45 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Xylene (Total)ND ug/L 10/30/15 19:16 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %10/30/15 19:16 460-00-470-130 1 1,2-Dichloroethane-d4 (S)105 %10/30/15 19:16 17060-07-070-130 1 Toluene-d8 (S)98 %10/30/15 19:16 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW106D Lab ID:92272834007 Collected:10/19/15 17:35 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 10/30/15 19:32 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 19:32 107-13-12001.9 1 Benzene 0.40J ug/L 10/30/15 19:32 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 19:32 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 19:32 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 19:32 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 19:32 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 19:32 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 19:32 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 19:32 56-23-51.0 0.25 1 Chlorobenzene 6.3 ug/L 10/30/15 19:32 108-90-73.0 0.23 1 Chloroethane ND ug/L 10/30/15 19:32 75-00-310.0 0.54 1 Chloroform ND ug/L 10/30/15 19:32 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 19:32 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 19:32 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 19:32 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 19:32 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 19:32 74-95-310.0 0.21 1 1,2-Dichlorobenzene 0.37J ug/L 10/30/15 19:32 95-50-15.0 0.30 1 1,4-Dichlorobenzene 5.7 ug/L 10/30/15 19:32 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 19:32 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 10/30/15 19:32 75-34-35.0 0.32 1 1,2-Dichloroethane 0.29J ug/L 10/30/15 19:32 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 19:32 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 2.5J ug/L 10/30/15 19:32 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 19:32 156-60-55.0 0.49 1 1,2-Dichloropropane 0.37J ug/L 10/30/15 19:32 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 19:32 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 19:32 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 19:32 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/30/15 19:32 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 19:32 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 19:32 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 19:32 108-10-11000.33 1 Styrene ND ug/L 10/30/15 19:32 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 19:32 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 19:32 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 10/30/15 19:32 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 19:32 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 19:32 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 19:32 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/30/15 19:32 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 19:32 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 19:32 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 19:32 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 10/30/15 19:32 75-01-41.0 0.62 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW106D Lab ID:92272834007 Collected:10/19/15 17:35 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Xylene (Total)ND ug/L 10/30/15 19:32 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)101 %10/30/15 19:32 460-00-470-130 1 1,2-Dichloroethane-d4 (S)103 %10/30/15 19:32 17060-07-070-130 1 Toluene-d8 (S)100 %10/30/15 19:32 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW107S Lab ID:92272834008 Collected:10/19/15 13:00 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 10/30/15 19:49 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 19:49 107-13-12001.9 1 Benzene ND ug/L 10/30/15 19:49 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 19:49 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 19:49 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 19:49 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 19:49 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 19:49 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 19:49 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 19:49 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/30/15 19:49 108-90-73.0 0.23 1 Chloroethane ND ug/L 10/30/15 19:49 75-00-310.0 0.54 1 Chloroform ND ug/L 10/30/15 19:49 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 19:49 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 19:49 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 19:49 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 19:49 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 19:49 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/30/15 19:49 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/30/15 19:49 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 19:49 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 10/30/15 19:49 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 10/30/15 19:49 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 19:49 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/30/15 19:49 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 19:49 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 10/30/15 19:49 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 19:49 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 19:49 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 19:49 100-41-41.0 0.30 1 2-Hexanone 0.71J ug/L 10/30/15 19:49 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 19:49 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 19:49 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 19:49 108-10-11000.33 1 Styrene ND ug/L 10/30/15 19:49 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 19:49 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 19:49 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 10/30/15 19:49 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 19:49 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 19:49 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 19:49 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/30/15 19:49 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 19:49 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 19:49 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 19:49 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 10/30/15 19:49 75-01-41.0 0.62 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW107S Lab ID:92272834008 Collected:10/19/15 13:00 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Xylene (Total)ND ug/L 10/30/15 19:49 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %10/30/15 19:49 460-00-470-130 1 1,2-Dichloroethane-d4 (S)103 %10/30/15 19:49 17060-07-070-130 1 Toluene-d8 (S)101 %10/30/15 19:49 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW107D Lab ID:92272834009 Collected:10/19/15 12:15 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 10/30/15 20:06 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 20:06 107-13-12001.9 1 Benzene 0.49J ug/L 10/30/15 20:06 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 20:06 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 20:06 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 20:06 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 20:06 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 20:06 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 20:06 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 20:06 56-23-51.0 0.25 1 Chlorobenzene 0.61J ug/L 10/30/15 20:06 108-90-73.0 0.23 1 Chloroethane 0.75J ug/L 10/30/15 20:06 75-00-310.0 0.54 1 Chloroform ND ug/L 10/30/15 20:06 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 20:06 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 20:06 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 20:06 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 20:06 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 20:06 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/30/15 20:06 95-50-15.0 0.30 1 1,4-Dichlorobenzene 1.1 ug/L 10/30/15 20:06 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 20:06 110-57-61001.0 1 1,1-Dichloroethane 0.74J ug/L 10/30/15 20:06 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 10/30/15 20:06 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 20:06 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 0.75J ug/L 10/30/15 20:06 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 20:06 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 10/30/15 20:06 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 20:06 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 20:06 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 20:06 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/30/15 20:06 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 20:06 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 20:06 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 20:06 108-10-11000.33 1 Styrene ND ug/L 10/30/15 20:06 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 20:06 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 20:06 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 10/30/15 20:06 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 20:06 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 20:06 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 20:06 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/30/15 20:06 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 20:06 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 20:06 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 20:06 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 10/30/15 20:06 75-01-41.0 0.62 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW107D Lab ID:92272834009 Collected:10/19/15 12:15 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Xylene (Total)ND ug/L 10/30/15 20:06 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)99 %10/30/15 20:06 460-00-470-130 1 1,2-Dichloroethane-d4 (S)101 %10/30/15 20:06 17060-07-070-130 1 Toluene-d8 (S)99 %10/30/15 20:06 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW108 Lab ID:92272834010 Collected:10/19/15 10:14 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone 19.8J ug/L 10/30/15 20:23 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 20:23 107-13-12001.9 1 Benzene 0.39J ug/L 10/30/15 20:23 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 20:23 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 20:23 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 20:23 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 20:23 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 20:23 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 20:23 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 20:23 56-23-51.0 0.25 1 Chlorobenzene 0.56J ug/L 10/30/15 20:23 108-90-73.0 0.23 1 Chloroethane 1.2J ug/L 10/30/15 20:23 75-00-310.0 0.54 1 Chloroform ND ug/L 10/30/15 20:23 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 20:23 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 20:23 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 20:23 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 20:23 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 20:23 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/30/15 20:23 95-50-15.0 0.30 1 1,4-Dichlorobenzene 1.1 ug/L 10/30/15 20:23 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 20:23 110-57-61001.0 1 1,1-Dichloroethane 1.6J ug/L 10/30/15 20:23 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 10/30/15 20:23 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 20:23 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 1.4J ug/L 10/30/15 20:23 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 20:23 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 10/30/15 20:23 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 20:23 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 20:23 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 20:23 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/30/15 20:23 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 20:23 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 20:23 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 20:23 108-10-11000.33 1 Styrene ND ug/L 10/30/15 20:23 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 20:23 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 20:23 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 10/30/15 20:23 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 20:23 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 20:23 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 20:23 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/30/15 20:23 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 20:23 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 20:23 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 20:23 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 10/30/15 20:23 75-01-41.0 0.62 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-MW108 Lab ID:92272834010 Collected:10/19/15 10:14 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Xylene (Total)ND ug/L 10/30/15 20:23 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)98 %10/30/15 20:23 460-00-470-130 1 1,2-Dichloroethane-d4 (S)99 %10/30/15 20:23 17060-07-070-130 1 Toluene-d8 (S)99 %10/30/15 20:23 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-HW-1 Lab ID:92272834011 Collected:10/19/15 17:50 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 10/30/15 20:39 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 20:39 107-13-12001.9 1 Benzene ND ug/L 10/30/15 20:39 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 20:39 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 20:39 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 20:39 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 20:39 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 20:39 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 20:39 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 20:39 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/30/15 20:39 108-90-73.0 0.23 1 Chloroethane ND ug/L 10/30/15 20:39 75-00-310.0 0.54 1 Chloroform 0.56J ug/L 10/30/15 20:39 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 20:39 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 20:39 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 20:39 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 20:39 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 20:39 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/30/15 20:39 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/30/15 20:39 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 20:39 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 10/30/15 20:39 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 10/30/15 20:39 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 20:39 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/30/15 20:39 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 20:39 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 10/30/15 20:39 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 20:39 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 20:39 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 20:39 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/30/15 20:39 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 20:39 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 20:39 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 20:39 108-10-11000.33 1 Styrene ND ug/L 10/30/15 20:39 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 20:39 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 20:39 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 10/30/15 20:39 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 20:39 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 20:39 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 20:39 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/30/15 20:39 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 20:39 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 20:39 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 20:39 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 10/30/15 20:39 75-01-41.0 0.62 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-HW-1 Lab ID:92272834011 Collected:10/19/15 17:50 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Xylene (Total)ND ug/L 10/30/15 20:39 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %10/30/15 20:39 460-00-470-130 1 1,2-Dichloroethane-d4 (S)101 %10/30/15 20:39 17060-07-070-130 1 Toluene-d8 (S)99 %10/30/15 20:39 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-FIELD BLANK Lab ID:92272834012 Collected:10/19/15 16:10 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Arsenic ND ug/L 10/29/15 02:21 7440-38-210/22/15 18:3010.0 2.5 1 Barium ND ug/L 10/29/15 02:21 7440-39-310/22/15 18:301002.5 1 Cadmium ND ug/L 10/29/15 02:21 7440-43-910/22/15 18:301.0 0.50 1 Chromium ND ug/L 10/29/15 02:21 7440-47-310/22/15 18:3010.0 2.5 1 Lead ND ug/L 10/29/15 02:21 7439-92-110/22/15 18:3010.0 2.5 1 Selenium ND ug/L 10/29/15 02:21 7782-49-210/22/15 18:3010.0 5.0 1 Silver ND ug/L 10/29/15 02:21 7440-22-410/22/15 18:3010.0 2.5 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 10/30/15 14:25 7439-97-610/22/15 17:000.20 0.10 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 10/30/15 20:56 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 20:56 107-13-12001.9 1 Benzene ND ug/L 10/30/15 20:56 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 20:56 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 20:56 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 20:56 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 20:56 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 20:56 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 20:56 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 20:56 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/30/15 20:56 108-90-73.0 0.23 1 Chloroethane ND ug/L 10/30/15 20:56 75-00-310.0 0.54 1 Chloroform ND ug/L 10/30/15 20:56 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 20:56 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 20:56 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 20:56 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 20:56 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 20:56 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/30/15 20:56 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/30/15 20:56 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 20:56 110-57-61001.0 1 Dichlorodifluoromethane ND ug/L 10/30/15 20:56 75-71-85.0 0.21 1 1,1-Dichloroethane ND ug/L 10/30/15 20:56 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 10/30/15 20:56 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 20:56 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/30/15 20:56 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 20:56 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 10/30/15 20:56 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 20:56 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 20:56 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 20:56 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/30/15 20:56 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 20:56 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 20:56 75-09-21.0 0.97 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-FIELD BLANK Lab ID:92272834012 Collected:10/19/15 16:10 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 20:56 108-10-11000.33 1 Styrene ND ug/L 10/30/15 20:56 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 20:56 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 20:56 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 10/30/15 20:56 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 20:56 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 20:56 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 20:56 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/30/15 20:56 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 20:56 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 20:56 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 20:56 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 10/30/15 20:56 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/30/15 20:56 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %10/30/15 20:56 460-00-470-130 1 1,2-Dichloroethane-d4 (S)103 %10/30/15 20:56 17060-07-070-130 1 Toluene-d8 (S)100 %10/30/15 20:56 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-TRIP BLANK Lab ID:92272834013 Collected:10/19/15 05:30 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 10/30/15 21:13 67-64-110010.0 1 Acrylonitrile ND ug/L 10/30/15 21:13 107-13-12001.9 1 Benzene ND ug/L 10/30/15 21:13 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 10/30/15 21:13 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 10/30/15 21:13 75-27-41.0 0.18 1 Bromoform ND ug/L 10/30/15 21:13 75-25-23.0 0.26 1 Bromomethane ND ug/L 10/30/15 21:13 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 10/30/15 21:13 78-93-31000.96 1 Carbon disulfide ND ug/L 10/30/15 21:13 75-15-01001.2 1 Carbon tetrachloride ND ug/L 10/30/15 21:13 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 10/30/15 21:13 108-90-73.0 0.23 1 Chloroethane ND ug/L 10/30/15 21:13 75-00-310.0 0.54 1 Chloroform ND ug/L 10/30/15 21:13 67-66-35.0 0.14 1 Chloromethane ND ug/L 10/30/15 21:13 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 10/30/15 21:13 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 10/30/15 21:13 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 10/30/15 21:13 106-93-41.0 0.27 1 Dibromomethane ND ug/L 10/30/15 21:13 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 10/30/15 21:13 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 10/30/15 21:13 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 10/30/15 21:13 110-57-61001.0 1 Dichlorodifluoromethane ND ug/L 10/30/15 21:13 75-71-85.0 0.21 1 1,1-Dichloroethane ND ug/L 10/30/15 21:13 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 10/30/15 21:13 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 10/30/15 21:13 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 10/30/15 21:13 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 10/30/15 21:13 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 10/30/15 21:13 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 10/30/15 21:13 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 10/30/15 21:13 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 10/30/15 21:13 100-41-41.0 0.30 1 2-Hexanone ND ug/L 10/30/15 21:13 591-78-650.0 0.46 1 Iodomethane ND ug/L 10/30/15 21:13 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 10/30/15 21:13 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 10/30/15 21:13 108-10-11000.33 1 Styrene ND ug/L 10/30/15 21:13 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 10/30/15 21:13 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 10/30/15 21:13 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 10/30/15 21:13 127-18-41.0 0.46 1 Toluene ND ug/L 10/30/15 21:13 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 10/30/15 21:13 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 10/30/15 21:13 79-00-51.0 0.29 1 Trichloroethene ND ug/L 10/30/15 21:13 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 10/30/15 21:13 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 10/30/15 21:13 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 10/30/15 21:13 108-05-450.0 0.35 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 45 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Sample:8803-TRIP BLANK Lab ID:92272834013 Collected:10/19/15 05:30 Received:10/21/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Vinyl chloride ND ug/L 10/30/15 21:13 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 10/30/15 21:13 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)99 %10/30/15 21:13 460-00-470-130 1 1,2-Dichloroethane-d4 (S)103 %10/30/15 21:13 17060-07-070-130 1 Toluene-d8 (S)98 %10/30/15 21:13 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 45 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/8575 EPA 7470 EPA 7470 7470 Mercury Associated Lab Samples:92272834001, 92272834002, 92272834003, 92272834012 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1589279 Associated Lab Samples:92272834001, 92272834002, 92272834003, 92272834012 Matrix:Water AnalyzedMDL Mercury ug/L ND 0.20 10/30/15 14:030.10 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1589280LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 2.12.5 85 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1589283MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92272855003 1589284 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 2.5 99 75-12591 8 252.5ND 2.5 2.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 45 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/19873 EPA 3010 EPA 6010 6010 MET NC Groundwater Associated Lab Samples:92272834001, 92272834002, 92272834003, 92272834012 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1589142 Associated Lab Samples:92272834001, 92272834002, 92272834003, 92272834012 Matrix:Water AnalyzedMDL Arsenic ug/L ND 10.0 10/29/15 01:472.5 Barium ug/L ND 100 10/29/15 01:472.5 Cadmium ug/L ND 1.0 10/29/15 01:470.50 Chromium ug/L ND 10.0 10/29/15 01:472.5 Lead ug/L ND 10.0 10/29/15 01:472.5 Selenium ug/L ND 10.0 10/29/15 01:475.0 Silver ug/L ND 10.0 10/29/15 01:472.5 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1589143LABORATORY CONTROL SAMPLE: LCSSpike Arsenic ug/L 479500 96 80-120 Barium ug/L 479500 96 80-120 Cadmium ug/L 480500 96 80-120 Chromium ug/L 479500 96 80-120 Lead ug/L 478500 96 80-120 Selenium ug/L 466500 93 80-120 Silver ug/L 239250 96 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1589145MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92272822014 1589146 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Arsenic ug/L 500 94 75-12594 1 25500ND471468 Barium ug/L 500 94 75-12593 1 25500ND471466 Cadmium ug/L 500 95 75-12594 1 25500ND476470 Chromium ug/L 500 94 75-12593 1 255002.9J 473 469 Lead ug/L 500 95 75-12593 2 25500ND476468 Selenium ug/L 500 92 75-12591 2 25500ND461454 Silver ug/L 250 94 75-12594 0 25250ND234234 Parameter Units MS Result % Rec Limits Qual% RecConc. 1589147MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92272855003 1589148 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Arsenic ug/L 500 96 75-12592 5 25500ND481460 Barium ug/L 500 96 75-12593 3 2550078.4 560 542 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 45 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1589147MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92272855003 1589148 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Cadmium ug/L 500 97 75-12593 4 25500ND487468 Chromium ug/L 500 97 75-12594 3 25500ND487471 Lead ug/L 500 96 75-12593 3 25500ND483466 Selenium ug/L 500 94 75-12590 4 25500ND470449 Silver ug/L 250 97 75-12593 4 25250ND242233 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 45 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MSV/34057 EPA 8260 EPA 8260 8260 MSV Low Level Landfill Associated Lab Samples:92272834001, 92272834002, 92272834003, 92272834004, 92272834005, 92272834006, 92272834007, 92272834008, 92272834009, 92272834010, 92272834011, 92272834012, 92272834013 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1595566 Associated Lab Samples:92272834001, 92272834002, 92272834003, 92272834004, 92272834005, 92272834006, 92272834007, 92272834008, 92272834009, 92272834010, 92272834011, 92272834012, 92272834013 Matrix:Water AnalyzedMDL 1,1,1,2-Tetrachloroethane ug/L ND 5.0 10/30/15 12:010.33 1,1,1-Trichloroethane ug/L ND 1.0 10/30/15 12:010.48 1,1,2,2-Tetrachloroethane ug/L ND 3.0 10/30/15 12:010.40 1,1,2-Trichloroethane ug/L ND 1.0 10/30/15 12:010.29 1,1-Dichloroethane ug/L ND 5.0 10/30/15 12:010.32 1,1-Dichloroethene ug/L ND 5.0 10/30/15 12:010.56 1,2,3-Trichloropropane ug/L ND 1.0 10/30/15 12:010.41 1,2-Dibromo-3-chloropropane ug/L ND 13.0 10/30/15 12:012.0 1,2-Dibromoethane (EDB)ug/L ND 1.0 10/30/15 12:010.27 1,2-Dichlorobenzene ug/L ND 5.0 10/30/15 12:010.30 1,2-Dichloroethane ug/L ND 1.0 10/30/15 12:010.24 1,2-Dichloropropane ug/L ND 1.0 10/30/15 12:010.27 1,4-Dichlorobenzene ug/L ND 1.0 10/30/15 12:010.33 2-Butanone (MEK)ug/L ND 100 10/30/15 12:010.96 2-Hexanone ug/L ND 50.0 10/30/15 12:010.46 4-Methyl-2-pentanone (MIBK)ug/L ND 100 10/30/15 12:010.33 Acetone ug/L ND 100 10/30/15 12:0110.0 Acrylonitrile ug/L ND 200 10/30/15 12:011.9 Benzene ug/L ND 1.0 10/30/15 12:010.25 Bromochloromethane ug/L ND 3.0 10/30/15 12:010.17 Bromodichloromethane ug/L ND 1.0 10/30/15 12:010.18 Bromoform ug/L ND 3.0 10/30/15 12:010.26 Bromomethane ug/L ND 10.0 10/30/15 12:010.29 Carbon disulfide ug/L ND 100 10/30/15 12:011.2 Carbon tetrachloride ug/L ND 1.0 10/30/15 12:010.25 Chlorobenzene ug/L ND 3.0 10/30/15 12:010.23 Chloroethane ug/L ND 10.0 10/30/15 12:010.54 Chloroform ug/L ND 5.0 10/30/15 12:010.14 Chloromethane ug/L ND 1.0 10/30/15 12:010.11 cis-1,2-Dichloroethene ug/L ND 5.0 10/30/15 12:010.19 cis-1,3-Dichloropropene ug/L ND 1.0 10/30/15 12:010.13 Dibromochloromethane ug/L ND 3.0 10/30/15 12:010.21 Dibromomethane ug/L ND 10.0 10/30/15 12:010.21 Dichlorodifluoromethane ug/L ND 5.0 10/30/15 12:010.21 Ethylbenzene ug/L ND 1.0 10/30/15 12:010.30 Iodomethane ug/L ND 10.0 10/30/15 12:010.32 Methylene Chloride ug/L ND 1.0 10/30/15 12:010.97 Styrene ug/L ND 1.0 10/30/15 12:010.26 Tetrachloroethene ug/L ND 1.0 10/30/15 12:010.46 Toluene ug/L ND 1.0 10/30/15 12:010.26 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 36 of 45 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1595566 Associated Lab Samples:92272834001, 92272834002, 92272834003, 92272834004, 92272834005, 92272834006, 92272834007, 92272834008, 92272834009, 92272834010, 92272834011, 92272834012, 92272834013 Matrix:Water AnalyzedMDL trans-1,2-Dichloroethene ug/L ND 5.0 10/30/15 12:010.49 trans-1,3-Dichloropropene ug/L ND 1.0 10/30/15 12:010.26 trans-1,4-Dichloro-2-butene ug/L ND 100 10/30/15 12:011.0 Trichloroethene ug/L ND 1.0 10/30/15 12:010.47 Trichlorofluoromethane ug/L ND 1.0 10/30/15 12:010.20 Vinyl acetate ug/L ND 50.0 10/30/15 12:010.35 Vinyl chloride ug/L ND 1.0 10/30/15 12:010.62 Xylene (Total)ug/L ND 5.0 10/30/15 12:010.66 1,2-Dichloroethane-d4 (S)%101 70-130 10/30/15 12:01 4-Bromofluorobenzene (S)%101 70-130 10/30/15 12:01 Toluene-d8 (S)%100 70-130 10/30/15 12:01 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1595567LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 50.350 101 80-125 1,1,1-Trichloroethane ug/L 54.450 109 71-129 1,1,2,2-Tetrachloroethane ug/L 51.150 102 79-124 1,1,2-Trichloroethane ug/L 48.450 97 85-125 1,1-Dichloroethane ug/L 51.650 103 73-126 1,1-Dichloroethene ug/L 54.750 109 66-135 1,2,3-Trichloropropane ug/L 48.950 98 75-130 1,2-Dibromo-3-chloropropane ug/L 52.150 104 71-133 1,2-Dibromoethane (EDB)ug/L 50.750 101 83-124 1,2-Dichlorobenzene ug/L 50.950 102 80-133 1,2-Dichloroethane ug/L 46.150 92 67-128 1,2-Dichloropropane ug/L 48.950 98 75-132 1,4-Dichlorobenzene ug/L 50.450 101 78-130 2-Butanone (MEK)ug/L 97.4J100 97 61-144 2-Hexanone ug/L 102100 102 68-143 4-Methyl-2-pentanone (MIBK)ug/L 101100 101 72-135 Acetone ug/L 96.2J100 96 48-146 Acrylonitrile ug/L 247250 99 40-160 Benzene ug/L 51.350 103 80-125 Bromochloromethane ug/L 51.550 103 71-125 Bromodichloromethane ug/L 51.950 104 78-124 Bromoform ug/L 50.950 102 71-128 Bromomethane ug/L 50.750 101 40-160 Carbon disulfide ug/L 53.7J50 107 50-160 Carbon tetrachloride ug/L 54.950 110 69-131 Chlorobenzene ug/L 49.650 99 81-122 Chloroethane ug/L 47.250 94 39-148 Chloroform ug/L 51.050 102 73-127 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 37 of 45 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1595567LABORATORY CONTROL SAMPLE: LCSSpike Chloromethane ug/L 45.950 92 44-146 cis-1,2-Dichloroethene ug/L 49.650 99 74-124 cis-1,3-Dichloropropene ug/L 52.850 106 72-132 Dibromochloromethane ug/L 52.950 106 78-125 Dibromomethane ug/L 50.350 101 82-120 Dichlorodifluoromethane ug/L 47.050 94 34-157 Ethylbenzene ug/L 51.550 103 79-121 Iodomethane ug/L 100100 100 39-154 Methylene Chloride ug/L 52.850 106 64-133 Styrene ug/L 51.550 103 84-126 Tetrachloroethene ug/L 53.150 106 78-122 Toluene ug/L 51.050 102 80-121 trans-1,2-Dichloroethene ug/L 51.350 103 71-127 trans-1,3-Dichloropropene ug/L 51.750 103 69-141 trans-1,4-Dichloro-2-butene ug/L 49.0J50 98 40-160 Trichloroethene ug/L 49.950 100 78-122 Trichlorofluoromethane ug/L 52.350 105 53-137 Vinyl acetate ug/L 104100 104 40-160 Vinyl chloride ug/L 56.250 112 58-137 Xylene (Total)ug/L 155150 103 81-126 1,2-Dichloroethane-d4 (S)%97 70-130 4-Bromofluorobenzene (S)%103 70-130 Toluene-d8 (S)%100 70-130 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1595568MATRIX SPIKE SAMPLE: MSSpike Result 92272834001 1,1,1,2-Tetrachloroethane ug/L 21.520 107 70-130ND 1,1,1-Trichloroethane ug/L 24.520 123 70-130ND 1,1,2,2-Tetrachloroethane ug/L 22.120 111 70-130ND 1,1,2-Trichloroethane ug/L 21.120 106 70-130ND 1,1-Dichloroethane ug/L 23.420 117 70-130ND 1,1-Dichloroethene ug/L 25.520 128 70-166ND 1,2,3-Trichloropropane ug/L 21.820 109 70-130ND 1,2-Dibromo-3-chloropropane ug/L 21.120 106 70-130ND 1,2-Dibromoethane (EDB)ug/L 22.020 110 70-130ND 1,2-Dichlorobenzene ug/L 22.020 110 70-130ND 1,2-Dichloroethane ug/L 20.520 102 70-130ND 1,2-Dichloropropane ug/L 22.120 111 70-130ND 1,4-Dichlorobenzene ug/L 22.220 110 70-130ND 2-Butanone (MEK)ug/L 42.5J40 106 70-130ND 2-Hexanone ug/L 44.6J40 112 70-130ND 4-Methyl-2-pentanone (MIBK)ug/L 43.4J40 109 70-130ND Acetone ug/L 43.4J40 103 70-130ND Acrylonitrile ug/L 108J100 108 70-130ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 38 of 45 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1595568MATRIX SPIKE SAMPLE: MSSpike Result 92272834001 Benzene ug/L 23.120 115 70-148ND Bromochloromethane ug/L 23.620 118 70-130ND Bromodichloromethane ug/L 22.620 113 70-130ND Bromoform ug/L 19.720 99 70-130ND Bromomethane ug/L 18.320 91 70-130ND Carbon disulfide ug/L 24.2J20 121 70-130ND Carbon tetrachloride ug/L 24.720 124 70-130ND Chlorobenzene ug/L 22.220 111 70-146ND Chloroethane ug/L 23.720 119 70-130ND Chloroform ug/L 22.920 115 70-130ND Chloromethane ug/L 23.520 117 70-130ND cis-1,2-Dichloroethene ug/L 22.220 111 70-130ND cis-1,3-Dichloropropene ug/L 21.520 108 70-130ND Dibromochloromethane ug/L 21.520 108 70-130ND Dibromomethane ug/L 21.620 108 70-130ND Dichlorodifluoromethane ug/L 26.020 130 70-130ND Ethylbenzene ug/L 22.820 114 70-130ND Iodomethane ug/L 40.640 101 70-130ND Methylene Chloride ug/L 23.020 115 70-130ND Styrene ug/L 21.320 106 70-130ND Tetrachloroethene ug/L 23.120 115 70-130ND Toluene ug/L 22.520 112 70-155ND trans-1,2-Dichloroethene ug/L 23.920 120 70-130ND trans-1,3-Dichloropropene ug/L 21.120 105 70-130ND trans-1,4-Dichloro-2-butene ug/L 20.4J20 102 70-130ND Trichloroethene ug/L 22.220 111 69-151ND Trichlorofluoromethane ug/L 25.820 129 70-130ND Vinyl acetate ug/L 42.8J40 107 70-130ND Vinyl chloride ug/L 27.4 M12013770-130ND 1,2-Dichloroethane-d4 (S)%98 70-130 4-Bromofluorobenzene (S)%103 70-130 Toluene-d8 (S)%100 70-130 Parameter Units Dup Result Max RPD QualifiersRPDResult 92272834002 1595569SAMPLE DUPLICATE: 1,1,1,2-Tetrachloroethane ug/L ND 30ND 1,1,1-Trichloroethane ug/L ND 30ND 1,1,2,2-Tetrachloroethane ug/L ND 30ND 1,1,2-Trichloroethane ug/L ND 30ND 1,1-Dichloroethane ug/L ND 30ND 1,1-Dichloroethene ug/L ND 30ND 1,2,3-Trichloropropane ug/L ND 30ND 1,2-Dibromo-3-chloropropane ug/L ND 30ND 1,2-Dibromoethane (EDB)ug/L ND 30ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 39 of 45 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result Max RPD QualifiersRPDResult 92272834002 1595569SAMPLE DUPLICATE: 1,2-Dichlorobenzene ug/L ND 30ND 1,2-Dichloroethane ug/L ND 30ND 1,2-Dichloropropane ug/L ND 30ND 1,4-Dichlorobenzene ug/L 0.65J 300.61J 2-Butanone (MEK)ug/L ND 30ND 2-Hexanone ug/L ND 30ND 4-Methyl-2-pentanone (MIBK)ug/L ND 30ND Acetone ug/L ND 30ND Acrylonitrile ug/L ND 30ND Benzene ug/L 0.67J 300.68J Bromochloromethane ug/L ND 30ND Bromodichloromethane ug/L ND 30ND Bromoform ug/L ND 30ND Bromomethane ug/L ND 30ND Carbon disulfide ug/L ND 30ND Carbon tetrachloride ug/L ND 30ND Chlorobenzene ug/L 0.61J 300.59J Chloroethane ug/L ND 30ND Chloroform ug/L ND 30ND Chloromethane ug/L ND 30ND cis-1,2-Dichloroethene ug/L 0.93J 300.95J cis-1,3-Dichloropropene ug/L ND 30ND Dibromochloromethane ug/L ND 30ND Dibromomethane ug/L ND 30ND Dichlorodifluoromethane ug/L ND 30ND Ethylbenzene ug/L ND 30ND Iodomethane ug/L ND 30ND Methylene Chloride ug/L ND 30ND Styrene ug/L ND 30ND Tetrachloroethene ug/L ND 30ND Toluene ug/L ND 30ND trans-1,2-Dichloroethene ug/L ND 30ND trans-1,3-Dichloropropene ug/L ND 30ND trans-1,4-Dichloro-2-butene ug/L ND 30ND Trichloroethene ug/L ND 30ND Trichlorofluoromethane ug/L ND 30ND Vinyl acetate ug/L ND 30ND Vinyl chloride ug/L ND 30ND Xylene (Total)ug/L ND 30ND 1,2-Dichloroethane-d4 (S)%101 1102 4-Bromofluorobenzene (S)%101 0100 Toluene-d8 (S)%100 1100 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 40 of 45 #=QL# QUALIFIERS Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - CharlottePASI-C ANALYTE QUALIFIERS Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 41 of 45 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92272834 TRANSYLVANIA-CALVERT Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92272834001 MPRP/19873 ICP/179218803-MW1 EPA 3010 EPA 6010 92272834002 MPRP/19873 ICP/179218803-MW2 EPA 3010 EPA 6010 92272834003 MPRP/19873 ICP/179218803-MW3 EPA 3010 EPA 6010 92272834012 MPRP/19873 ICP/179218803-FIELD BLANK EPA 3010 EPA 6010 92272834001 MERP/8575 MERC/82378803-MW1 EPA 7470 EPA 7470 92272834002 MERP/8575 MERC/82378803-MW2 EPA 7470 EPA 7470 92272834003 MERP/8575 MERC/82378803-MW3 EPA 7470 EPA 7470 92272834012 MERP/8575 MERC/82378803-FIELD BLANK EPA 7470 EPA 7470 92272834001 MSV/340578803-MW1 EPA 8260 92272834002 MSV/340578803-MW2 EPA 8260 92272834003 MSV/340578803-MW3 EPA 8260 92272834004 MSV/340578803-MW105S EPA 8260 92272834005 MSV/340578803-MW105D EPA 8260 92272834006 MSV/340578803-MW106S EPA 8260 92272834007 MSV/340578803-MW106D EPA 8260 92272834008 MSV/340578803-MW107S EPA 8260 92272834009 MSV/340578803-MW107D EPA 8260 92272834010 MSV/340578803-MW108 EPA 8260 92272834011 MSV/340578803-HW-1 EPA 8260 92272834012 MSV/340578803-FIELD BLANK EPA 8260 92272834013 MSV/340578803-TRIP BLANK EPA 8260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:14 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 42 of 45 Page 43 of 45 Page 44 of 45 Page 45 of 45 D A T E : 1 0 / 1 9 / 1 5 J O Y C E _ _ _ _ _ _ _ _ _ i i r ’ j c G R O U N D W A T E R S A M P L I N G L O G P r o j e c t N a m e : T r a n s y l v a n i a C o . - C a l v e r t P r o j e c t N o . / T a s k N o . : 3 3 6 . 1 6 0 1 . 1 2 . 0 1 W e l l I D : M W - i S a m p l e r ( s ) : G . E l l e n H . S e a t o n Y e H L o c a t i o n : S t r a i g h t u p h i l l , p a s t o l d m a i n t e n a n c e b u i l d i n g b e f o r e t u r n i n g o n a c c e s s r o a d W e l l D i a m e t e r : _ _ _ _ _ _ _ _ _ _ _ _ _ _ I n i t i a l D e p t h t o W a t e r ( D T W ) : _ _ _ _ _ _ _ _ _ _ _ _ _ _ D e p t h t o B o t t o m ( D T B ) : _ _ _ _ _ _ _ _ _ _ _ _ W a t e r C o l u m n T h i c k n e s s ( W C T ) : _ _ _ _ _ _ _ _ _ _ _ _ C a l c u l a t i o n f o r O n e W e l l V o l u m e ( W V ) : F o r 2 ” W e l l : W C T X 0 . 1 6 3 = 1 . 4 g a l l o n s F o r 4 ” W e l l : W C T X 0 . 6 5 3 = - F o r T H R E E W e l l V o l u m e s : W V X 3 = 4 . 2 A c t u a l A m o u n t P u r g e d / B a i l e d : P u r g e d w i t h : D i s p o s a b l e B a i l e r S a m p l e d w i t h : D i s p o s a b l e B a i l e r D e p t h t o W a t e r b e f o r e S a m p l i n g : - f e e t G a l l o n s T i m e T e m p ( ° C ) p H C o n d . ( t S ) T u r b . ( n t u ) I n i t i a l s 0 1 0 4 6 1 4 . 7 6 . 0 1 1 2 7 2 . 8 1 H S 1 . 4 1 0 5 0 1 5 . 1 5 . 6 6 1 0 5 8 . 9 7 i - i s 2 . 8 1 0 5 3 1 4 . 7 5 . 8 3 1 2 4 1 4 . 9 2 H S 4 . 2 1 1 0 $ 1 7 . 0 6 . 1 7 1 8 6 1 5 . 8 0 H S B e f o r e S a m p l i n g 1 1 0 8 1 7 . 0 6 . 1 7 1 8 6 1 5 . 8 0 H S C o m m e n t s ( w e a t h e r c o n d i t i o n s , o d o r , c o l o r , s i l t , e t c . ) : T h e w c t h r w a s s u n n y w i t h t e m n e r a t u r e s i n t h e 6 0 ’ s o n 1 0 / 1 9 / 1 1 r - S i g n a t u r e : C r f 6 f q % D a t e : i t / , ’ / / 5 Q A / Q C S i g n o f f : _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ D a t e : _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 2 i n c h e s 6 3 . 8 0 f e e t 7 2 . 6 4 f e e t 8 . 8 4 f e e t [ D T B - D T W ] _ _ _ _ _ _ _ _ _ _ _ _ _ _ g a l l o n s _ _ _ _ _ _ _ _ _ _ _ _ _ _ g a l l o n s 4 . 2 g a l l o n s D A T E : 1 0 / 1 9 / 1 5 J O Y C E _ _ _ _ _ _ _ _ _ s r J c I r J s s R I r \ J c 9 G R O U N D W A T E R S A M P L I N G L O G P r o j e c t N a m e : T r a n s y l v a n i a C o . - C a l v e r t P r o j e c t N o . / T a s k N o . : 3 3 6 . 1 6 0 1 . 1 2 . 0 1 W e l l I D : M W - 2 S a m p l e r ( s ) : G . E l l e n H . S e a t o n V e 1 l L o c a t i o n : P a s t g a t e t u r n l e f t n e x t t o p o n d , s a m p l e f r o m o n e w i t h r o u n d c a s i n g W e l l D i a m e t e r : 2 i n c h e s I n i t i a l D e p t h t o W a t e r ( D T W ) : 6 7 . 3 5 f e e t D e p t h t o B o t t o m ( D T B ) : 8 3 . 3 0 f e e t W a t e r C o l u m n T h i c k n e s s ( W C T ) : 1 5 . 9 5 f e e t [ D T B - D T W ] C a l c u l a t i o n f o r O n e W e l l V o l u m e ( W V ) : f o r 2 ” W e l l : W C T X 0 . 1 6 3 = 2 . 6 g a l l o n s f o r 4 ” W e l l : W C T X 0 . 6 5 3 = - g a l l o n s F o r T H R E E W e l l V o l u m e s : W V X 3 = 7 . 8 g a l l o n s A c t u a l A m o u n t P u r g e d / B a i l e d : 7 . 8 g a l l o n s P u r g e d w i t h : D i s p o s a b l e B a i l e r S a m p l e d w i t h : D i s p o s a b l e B a i l e r / D e p t h t o W a t e r b e f o r e S a m p l i n g : - f e e t G a l l o n s T i m e T e m p ( ° C ) p H C o n d . ( . t S ) T u r b . ( n t u ) I n i t i a l s 0 1 2 1 6 1 1 . 3 6 . 6 0 6 0 3 6 . 6 3 U S 2 . 6 1 2 2 2 1 1 . 9 6 . 6 1 6 3 8 6 . 7 7 U S 5 . 2 1 2 3 1 1 2 . 1 6 . 6 3 6 4 8 7 . 7 8 H S 7 . 8 1 2 3 6 1 2 . 2 6 . 6 2 6 5 2 7 . 5 8 H S B e f o r e S a m p l i n g C o m m e n t s ( w e a t h e r c o n d i t i o n s , o d o r , c o l o r , s i l t , e t c . ) : T h e w e a t h e r w a s s u n n y w i t h t e m p e r a t u r e s i n t h e 6 0 ’ s o n 1 0 / 1 9 / 1 5 . 1 2 3 6 1 2 . 2 6 . 6 2 6 5 2 7 . 5 8 H S S i g n a t u r e : Q A / Q C S i g n O f f . / D A T E : 1 0 / 1 9 / 1 5 2 i n c h e s 3 . 7 5 f e e t 1 9 . 8 0 f e e t 1 6 . 0 5 f e e t { D T B - D T W ] = 2 . 6 g a l l o n s = - g a l l o n s = 7 . 8 g a l l o n s 7 . 8 a l 1 o n s 9 / z ; — J O Y C E E r ’ i G I r ’ J s 8 , q l r \ J G G R O U N D W A T E R S A M P L I N G L O G P r o j e c t N a m e : T r a n s y l v a n i a C o . - C a l v e r t P r o j e c t N o . / T a s k N o . : 3 3 6 . 1 6 0 1 . 1 2 . 0 1 W e l l I D : M W - 3 S a m p l e r ( s ) : G . E l l e n H . S e a t o n W e l l L o c a t i o n : B a c k l o w e r c o r n e r o f l a n d f i l l , n e a r c r e e k W e l l D i a m e t e r : I n i t i a l D e p t h t o W a t e r ( D T W ) : D e p t h t o B o t t o m ( D T B ) : W a t e r C o l u m n T h i c k n e s s ( W C T ) : C a l c u l a t i o n f o r O n e W e l l V o l u m e ( W V ) : F o r 2 ” W e l l : W C T X 0 . 1 6 3 F o r 4 ” W e l l : W C T X 0 . 6 5 3 f o r T H R E E W e l l V o l u m e s : W V X 3 A c t u a l A m o u n t P u r g e d / B a i l e d : P u r g e d w i t h : D i s p o s a b l e B a i l e r S a m p l e d w i t h : D i s p o s a b l e B a i l e r D e p t h t o W a t e r b e f o r e S a m p l i n g : 3 . 7 5 f e e t G a l l o n s T i m e T e m p ( ° C ) p H C o n d . ( t S ) T u r b . ( n t u ) I n i t i a l s 0 1 4 4 4 1 6 . 4 6 . 3 8 9 8 4 6 . 0 4 H S 2 . 6 1 4 4 6 1 5 . 4 6 . 4 1 1 0 3 6 9 1 . 9 H S 5 . 2 1 4 4 8 1 4 . 9 6 . 5 3 1 0 2 4 1 6 6 H S 7 . 8 1 4 5 0 1 4 . 2 6 . 6 2 1 0 3 2 2 4 2 H S B e f o r e S a m p l i n g 1 7 4 3 1 4 . 3 6 . 3 9 9 9 8 1 0 . 2 1 H S C o m m e n t s ( w e a t h e r c o n d i t i o n s , o d o r , c o l o r , s i l t , e t c T h e w e a t h e r w a s s u n n y w i t h t e m p e r a t u r e s i n t h e 6 0 ’ s o n 1 0 / 1 9 / 1 5 . S i g n a t u r e : Q A / Q C S i g n O f f : / i 2 , / D a t e : D a t e : / o / i ’ i 1 1 ’ c 6 ’ 7 ( ( D A T E : 1 0 / 1 9 / 1 5 J O Y C E _ _ _ _ _ _ _ _ _ s I r ’ . J s s R I r ] c G R O U N D W A T E R S A M P L I N G L O G P r o j e c t N a m e : T r a n s y l v a n i a C o . - C a l v e r t P r o j e c t N o . / T a s k N o . : 3 3 6 . 1 6 0 1 . 1 2 . 0 1 W e l l I D : M W - 4 S a m p l e r ( s ) : G . E l l e r / H . S e a t o n W e l l L o c a t i o n : B a c k s i d e o f l a n d f i l l , n e a r M W - l 0 $ W e l l D i a m e t e r : 2 i n c h e s I n i t i a l D e p t h t o W a t e r ( D T W ) : - f e e t D e p t h t o B o t t o m ( D T B ) : 7 0 . 8 0 f e e t W a t e r C o l u m n T h i c k n e s s ( W C T ) : - f e e t E D T B - D T W ] C a l c u l a t i o n f o r O n e W e l l V o l u m e ( W V ) : f o r 2 ” W e l l : W C T X 0 . 1 6 3 = - g a l l o n s f o r 4 ” W e l l : W C T X 0 . 6 5 3 = - g a l l o n s F o r T H R E E W e l l V o L u m e s : W V X 3 = - g a l l o n s A c t u a l A m o u n t P u r g e d / B a i l e d : - g a l l o n s P u r g e d w i t h : D i s p o s a b l e B a i l e r S a m p l e d w i t h : D i s p o s a b l e B a i l e r D e p t h t o W a t e r b e f o r e S a m p l i n g : - f e e t G a l l o n s T i m e T e m p ( ° C ) p 1 1 C o n d . ( i S ) T u r b . ( n t u ) I n i t i a l s N o t S a m p l e d C o m m e n t s ( w e a t h e r c o n d i t i o n s , o d o r , c o l o r , s i l t , e t c . ) : T h e w e a t h e r w a s s u n n y w i t h t e m p e r a t u r e s i n t h e 6 0 ’ s o n 1 0 / 1 9 / 2 0 1 5 . 2 + f e e t o f w a t e r , u n a b l e t o r e a c h t o s a m p l e . s i n a t u r e : / L & . j - D a t e : _ _ _ _ _ _ _ _ _ _ _ _ Q A / Q C S i g n O f f : , / J A J / J j \ D a t e : l & / z l r - I t J O Y C E s I \ J c I r \ I s s R I r J G W e l l L o c a t i o n : f l u s h m o u n t e d o n D O T p r o p e r t y . W e l l D i a m e t e r : I n i t i a l D e p t h t o W a t e r ( D T W ) : D e p t h t o B o t t o m ( D T B ) : W a t e r C o l u m n T h i c k n e s s ( W C T ) : C a l c u l a t i o n f o r O n e W e l l V o l u m e ( W V ) : F o r 2 ” W e l l : W C T X 0 . 1 6 3 F o r 4 ” W e l l : W C T X 0 . 6 5 3 F o r T H R E E W e l l V o l u m e s : W V X 3 A c t u a l A m o u n t P u r g e d / B a i l e d : P u r g e d w i t h : D i s p o s a b l e B a i l e r S a m p l e d w i t h : D i s p o s a b l e B a i l e r D e p t h t o W a t e r b e f o r e S a m p l i n g : - f e e t B e f o r e S a m p l i n g 1 4 0 5 1 6 . 1 5 . 9 6 6 7 5 S i g n a t u r e : . / J ? . ? & . s r - i Q A / Q C S i g n O f f : D A T E : 1 0 / 1 9 / 1 5 G R O U N D W A T E R S A M P L I N G L O G P r o j e c t N a m e : T r a n s y l v a n i a C o . - C a l v e r t P r o j e c t N o . / T a s k N o . : 3 3 6 . 1 6 0 1 . 1 2 . 0 1 W e l l I D : M W - 1 0 5 D S a m p l e r ( s ) : G . E l l e r / H . S e a t o n b e h i n d D O T s a n d b u i l d i n g 2 i n c h e s 5 7 . 6 5 f e e t 8 7 . 1 0 f e e t 2 9 . 4 5 f e e t [ D T B - D T W ] = 4 . 8 g a l l o n s = - g a l l o n s = 1 4 . 4 g a l l o n s 1 4 . 4 g a l l o n s G a l l o n s T i m e T e m p ( ° C ) p H C o n d . ( j i S ) T u r b . ( n t u ) I n i t i a l s 0 1 3 4 3 1 4 . 4 6 . 6 5 6 0 0 1 2 . 2 2 H S 4 . 8 1 3 5 1 1 5 . 6 6 . 1 8 6 5 5 9 . 8 8 H S 9 . 6 1 3 5 8 1 5 . 8 6 . 0 6 6 5 7 5 . 9 9 H S 1 4 . 4 1 4 0 5 1 6 . 1 5 . 9 6 6 7 5 5 . 8 0 H S C o m m e n t s ( w e a t h e r c o n d i t i o n s , o d o r , c o l o r , s i l t , e t c . ) : T h e w e a t h e r w a s s u n n y w i t h t e m n e r a t u r e s i n t h e 6 0 ’ s o n 1 0 / 1 9 / 1 5 5 . 8 0 H S I - - - D a t e : t I / J j A J 2 D a t e : i / i Q J / c I D A T E : 1 0 / 1 9 / 1 5 J O Y C E _ _ _ _ _ _ _ _ _ s I r J s E F ? I r \ J G G R O U N D W A T E R S A M P L I N G L O G P r o j e c t N a m e : T r a n s y l v a n i a C o . - C a l v e r t P r o j e c t N o . / T a s k N o . : 3 3 6 . 1 6 0 1 . 1 2 . 0 1 W e l l I D : M W - 1 0 5 S S a m p l e r ( s ) : G . E l l e r H . S e a t o n W e l l L o c a t i o n : F l u s h m o u n t e d o n D O T p r o p e y , b e h i n d D O T s a n d b u i l d i n g W e l l D i a m e t e r : 2 i n c h e s I n i t i a l D e p t h t o W a t e r ( D T W ) : 5 1 . 1 5 f e e t D e p t h t o B o t t o m ( D T B ) : 5 5 . 3 7 f e e t W a t e r C o l u m n T h i c k n e s s ( W C T ) : 4 . 2 2 f e e t [ D T B - D T W ] C a l c u l a t i o n f o r O n e W e l l V o l u m e ( W V ) : F o r 2 ” W e l l : W C T X 0 . 1 6 3 = 0 . 7 g a l l o n s F o r 4 ” W e l l : W C T X 0 . 6 5 3 = - g a l l o n s F o r T H R E E W e l l V o l u m e s : W V X 3 2 . 1 g a l l o n s A c t u a l A m o u n t P u r g e d / B a i l e d : 1 . 2 g a l l o n s P u r g e d w i t h : D i s p o s a b l e B a i l e r S a m p l e d w i t h : D i s p o s a b l e B a i l e r D e p t h t o W a t e r b e f o r e S a m p l i n g : 5 2 . 5 5 f e e t G a l l o n s T i m e T e m p ( ° C ) p H C o n d . ( j i S ) T u r b . ( n t u ) I n i t i a l s 0 1 3 4 9 1 5 . 4 5 . 6 4 1 9 4 6 . 2 4 H S 0 . 7 1 3 5 3 1 6 . 2 5 . 6 5 2 0 9 1 5 . 2 9 H S D r y @ 1 . 2 g a l B e f o r e S a m p l i n g 1 5 4 0 1 5 . 7 5 . 5 8 1 8 7 6 . 5 2 H S C o m m e n t s ( w e a t h e r c o n d i t i o n s , o d o r , c o l o r , s i l t , e t c . ) : T h e w e a t h e r w a s s u n n y w i t h t e m p e r a t u r e s i n t h e 6 0 ’ s o n 1 0 / 1 9 / 1 5 . S i g n a t u r e : D a t e : Q A J Q C S i g n O f f : D a t e : 7 I D A T E : 1 0 / 1 9 / 1 5 2 i n c h e s 2 . 7 f e e t 7 5 . 3 8 f e e t 7 2 . 6 $ f e e t [ D T B - D T W ] = 1 1 . 8 g a l l o n s = - g a l l o n s = 3 5 . 4 g a l l o n s 3 5 . 4 g a l l o n s 1 2 1 0 5 . 7 9 1 1 5 S i g n a t u r e : _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Q A I Q C S i g n O f f : _ _ _ _ _ _ _ _ 1 D a t e : _ _ _ _ _ _ _ _ _ D a t e : I I J O Y C E _ _ _ _ _ _ _ _ _ s r \ J G I r ] s R I r ] G G R O U N D W A T E R S A M P L I N G L O G P r o j e c t N a m e : T r a n s y l v a n i a C o . - C a l v e r t P r o j e c t N o . / T a s k N o . : 3 3 6 . 1 6 0 1 . 1 2 . 0 1 W e l l I D : M W - 1 0 6 D S a m p l e r ( s ) : G . E l l e r / H . S e a t o n V e 1 1 L o c a t i o n : N e a r 2 b i g t r e e s a t t h e b e n d i n t h e r o a d n e a r c r e e k & g a t e . f l u s h m o u n t e d W e l l D i a m e t e r : I n i t i a l D e p t h t o W a t e r ( D T W ) : D e p t h t o B o t t o m ( D T B ) : W a t e r C o l u m n T h i c k n e s s ( W C T ) : C a l c u l a t i o n f o r O n e W e l l V o l u m e ( W V ) : f o r 2 ” W e l l : W C T X 0 . 1 6 3 F o r 4 ” W e l l : W C T X 0 . 6 5 3 F o r T H R E E W e l l V o l u m e s : W V X 3 A c t u a l A m o u n t P u r g e d ! B a i l e d : P u r g e d w i t h : 1 2 V o l t P u m p S a m p l e d w i t h : 1 2 V o l t P u m p D e p t h t o W a t e r b e f o r e S a m p l i n g : f e e t G a l l o n s T i m e T e m p ( ° C ) p H C o n d . ( p S ) T u r b . ( n t u ) I n i t i a l s 0 1 7 1 5 1 7 . 2 7 . 4 8 1 7 3 2 6 . 4 9 H S 1 1 . 8 1 7 2 2 1 6 . 0 7 . 2 3 1 8 0 8 3 . 9 4 H S 2 3 . 6 1 7 3 0 1 4 . 0 7 . 1 3 1 7 6 7 8 . 6 5 1 1 5 3 5 . 4 1 7 3 5 1 3 . 3 6 . 1 3 1 2 1 0 5 . 7 9 H S B e f o r e S a m p l i n g 1 7 3 5 1 3 . 3 6 . 1 3 C o m m e n t s ( w e a t h e r c o n d i t i o n s , o d o r , c o l o r , s i l t , e t c . ) : T h e w a s s u n n y w i t h t e m p e r a t u r e s i n t h e 6 0 ’ s o n 1 0 / 1 9 / 1 5 . D A T E : 1 0 / 1 9 / 1 5 2 i n c h e s 8 . 2 f e e t 2 2 . 5 8 f e e t 1 4 . 3 $ f e e t [ D T B - D T W ] 2 . 3 g a l l o n s - g a l l o n s 6 . 9 g a l l o n s 6 . 9 g a l l o n s 2 2 . 8 4 H S S i g n a t u r e : Q I Z J c t I & . . 4 Q A I Q C S i g n O f f : _ _ _ _ _ _ _ D a t e : i t j A ” 4 ’ / J 5 I t e : / 1 7 7 / z 4 / / 5 J O Y C E 8 P J G I r . J 8 s R I t ’ J G G R O U N D W A T E R S A M P L I N G L O G P r o j e c t N a m e : T r a n s y l v a n i a C o . - C a l v e r t P r o j e c t N o . / T a s k N o . : 3 3 6 . 1 6 0 1 . 1 2 . 0 1 W e l l I D : M W - 1 0 6 S S a m p l e r ( s ) : G . E l l e r / H . S e a t o n W e l l L o c a t i o n : N e a r 2 b i g t r e e s a t t h e b e n d i n t h e r o a d n e a r c r e e k & g a t e , f l u s h m o u n t e d W e l l D i a m e t e r : _ _ _ _ _ _ _ _ _ _ _ _ _ _ I n i t i a l D e p t h t o W a t e r ( D T W ) : _ _ _ _ _ _ _ _ _ _ _ _ _ _ D e p t h t o B o t t o m ( D T B ) : _ _ _ _ _ _ _ _ _ _ _ W a t e r C o l u m n T h i c k n e s s ( W C T ) : _ _ _ _ _ _ _ _ _ _ _ _ C a l c u l a t i o n f o r O n e W e l l V o l u m e ( W V ) : f o r 2 ” W e l l : W C T X 0 . 1 6 3 = _ _ _ _ _ _ _ _ _ _ _ _ f o r 4 ” W e l l : W C T X 0 . 6 5 3 = _ _ _ _ _ _ _ _ _ _ _ _ _ F o r T H R E E W e l l V o l u m e s : W V X 3 = _ _ _ _ _ _ _ _ _ A c t u a l A m o u n t P u r g e d / B a i l e d : _ _ _ _ _ _ _ _ _ _ _ _ P u r g e d w i t h : 1 2 V o l t P u m p S a m p l e d w i t h : _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ D e p t h t o W a t e r b e f o r e S a m p l i n g : 1 2 V o l t P u m o 8 . 4 0 f e e t G a l l o n s T i m e T e m p ( ° C ) p H C o n d . ( j i S ) T u r b . ( n t u ) I n i t i a l s 0 1 7 1 8 1 3 . 9 6 . 7 3 5 9 2 1 8 . 3 2 H S 2 . 3 1 7 2 3 1 4 . 6 6 . 6 7 4 2 9 1 7 8 H S 4 . 6 1 7 2 6 1 4 . 2 6 . 6 9 4 2 0 > 1 0 0 0 H S 6 . 9 1 7 2 9 1 4 . 2 7 . 1 1 5 5 2 > 1 0 0 0 H S B e f o r e S a m p l i n g 1 7 4 5 1 3 . 3 6 . 0 9 3 1 3 C o m m e n t s ( w e a t h e r c o n d i t i o n s , o d o r , c o l o r , s i l t , e t c . ) : T h e w e a t h e r w a s s u n n y w i t h t e m p e r a t u r e s i n t h e 6 0 ’ s o n 1 0 / 1 9 / 1 5 . D A T E : 1 0 / 1 9 / 1 5 J O Y C E _ _ _ _ _ _ _ _ _ S [ \ 1 G I r . J 8 8 F ? I r \ J G G R O U N D W A T E R S A M P L I N G L O G P r o j e c t N a m e : T r a n s y l v a n i a C o . - C a l v e r t P r o j e c t N o . / T a s k N o . : 3 3 6 . 1 6 0 1 . 1 2 . 0 1 W e l l I D : M W - 1 0 7 S S a m p l e r ( s ) : G . E l l e n H . S e a t o n W e l l L o c a t i o n : B a c k s i d e o f l a n d f i l l , n e a r r o a d t o H W - 1 W e l l D i a m e t e r : 2 i n c h e s I n i t i a l D e p t h t o W a t e r ( D T W ) : 5 1 . 8 5 f e e t D e p t h t o B o t t o m ( D T B ) : 5 8 . 8 4 f e e t W a t e r C o l u m n T h i c k n e s s ( W C T ) : 6 . 9 9 f e e t [ D T B - D T W ] C a l c u l a t i o n f o r O n e W e l l V o l u m e ( W V ) : F o r 2 ” W e l l : W C T X 0 . 1 6 3 = 1 . 2 g a l l o n s F o r 4 ” W e l l : W C T X 0 . 6 5 3 = - g a l l o n s F o r T H R E E W e l l V o l u m e s : W V X 3 = 3 . 6 g a l l o n s A c t u a l A m o u n t P u r g e d / B a i l e d : 1 . 6 g a l l o n s P u r g e d w i t h : D i s p o s a b l e B a i l e r S a m p l e d w i t h : D i s p o s a b l e B a i l e r D e p t h t o W a t e r b e f o r e S a m p l i n g : 5 7 . 4 0 f e e t G a l l o n s T i m e T e m p ( ° C ) p 1 1 C o n d . ( t S ) T u r b . ( n t u ) I n i t i a l s 0 1 1 4 1 1 2 . 8 6 . 4 0 3 9 1 9 . 7 6 H S 1 . 2 1 1 4 5 1 2 . 9 6 . 1 6 4 0 9 7 . 5 4 H S D r y 1 . 6 g a l B e f o r e S a m p l i n g 1 3 0 0 1 2 . 3 6 . 6 5 4 3 2 1 6 . 5 0 C o m m e n t s ( w e a t h e r c o n d i t i o n s , o d o r , c o l o r , s i l t , e t c . ) : T h e w e a t h e r w a s s u n n y w i t h f t m t i r a t u r e s i n t h e 6 0 ’ s o n 4 / 2 0 / 1 1 H S - - - - , I - ’ - - S i g n a t u r e : D a t e : _ _ _ _ _ _ _ _ _ Q A I Q C S i g n O f f : D a t e : J f ) r D a t e : D a t e : 2 i n c h e s 5 4 . 5 5 f e e t 9 0 . 3 0 f e e t 3 5 . 7 5 f e e t [ D T B - D T W ] 5 . 8 g a l l o n s - g a l l o n s 1 7 . . 4 g a l l o n s 1 7 . 4 g a l l o n s J O Y C E E r J G I t J 8 8 R ! t \ ] G D A T E : 1 0 / 1 9 / 1 5 G R O U N D W A T E R S A M P L I N G L O G P r o j e c t N a m e : T r a n s y l v a n i a C o . - C a l v e r t P r o j e c t N o . / T a s k N o . : 3 3 6 . 1 6 0 1 . 1 2 . 0 1 W e l l I D : M W - l 0 7 D S a m p l e r ( s ) : G . E l l e r / H . S e a t o n W e l l L o c a t i o n : B a c k s i d e o f l a n d f i l l , n e a r r o a d t o H W - 1 W e l l D i a m e t e r : I n i t i a l D e p t h t o W a t e r ( D T W ) : D e p t h t o B o t t o m ( D T B ) : W a t e r C o l u m n T h i c k n e s s ( W C T ) : C a l c u l a t i o n f o r O n e W e l l V o l u m e ( W V ) : F o r 2 ” W e l l : W C T X 0 . 1 6 3 = F o r 4 ” W e l l : W C T X 0 . 6 5 3 F o r T H R E E W e l l V o l u m e s : W V X 3 = A c t u a l A m o u n t P u r g e d / B a i l e d : P u r g e d w i t h : D i s p o s a b l e B a i l e r S a m p l e d w i t h : D i s p o s a b l e B a i l e r D e p t h t o W a t e r b e f o r e S a m p l i n g : - f e e t G a l l o n s l i m e T e m p ( ° C ) p H C o n d . Q i S ) T u r b . ( n t u ) I n i t i a l s 0 1 1 3 4 1 3 . 9 6 . 4 2 4 2 1 1 4 . 6 2 H S 5 . 8 1 1 4 6 1 3 . 3 6 . 3 6 4 3 9 1 5 . 4 6 H S 1 1 . 6 1 2 0 0 1 3 . 5 6 . 2 8 4 2 7 1 0 . 0 9 U S 1 7 . 4 1 2 1 5 1 2 . 6 6 . 5 4 4 1 3 1 6 . 6 9 H S B e f o r e S a m p l i n g 1 2 1 5 1 2 . 6 6 . 5 4 4 1 3 1 6 . 6 9 U S C o m m e n t s ( w e a t h e r c o n d i t i o n s , o d o r , c o l o r , s i l t , e t c . ) : T h e w e a t h e r w a s s u n n y w i t h t e m p e r a t u r e s i n t h e 6 0 ’ s o n 1 0 / 1 9 / 1 5 . S i g n a t u r e : Q A / Q C S i g n O f f : / J J - / t w ’ q / C — D A T E : 1 0 / 1 9 / 1 5 J O Y C E _ _ _ _ _ _ _ _ _ s ! \ J G I 1 \ I s R ! r ’ J G G R O U N D W A T E R S A M P L I N G L O G P r o j e c t N a m e : T r a n s y l v a n i a C o . - C a l v e r t P r o j e c t N o . / T a s k N o . : 3 3 6 . 1 6 0 1 . 1 2 . 0 1 W e l l I D : M W - 1 0 8 S a m p l e r ( s ) : G . E l l e r / H . S e a t o n W e l l L o c a t i o n : U p h i l l f r o m M W - 4 W e l l D i a m e t e r : I n i t i a l D e p t h t o W a t e r ( D T W ) : D e p t h t o B o t t o m ( D T B ) : W a t e r C o l u m n T h i c k n e s s ( W C T ) : C a l c u l a t i o n f o r O n e W e l l V o l u m e ( W V ) : f o r 2 ” W e l l : W C T X 0 . 1 6 3 = F o r 4 ” W e l l : W C T X 0 . 6 5 3 = F o r T H R E E W e l l V o l u m e s : W V X 3 = A c t u a l A m o u n t P u r g e d / B a i l e d : P u r g e d w i t h : D i s p o s a b l e B a i l e r S a m p l e d w i t h : D i s p o s a b l e B a i l e r D e p t h t o W a t e r b e f o r e S a m p l i n g : - 0 . 3 0 g a l l o n s - g a l l o n s 0 . 9 0 g a l l o n s 0 . 9 0 g a l l o n s G a l l o n s T i m e T e m p ( ° C ) p H C o n d . ( t S ) T u r b . ( n t u ) I n i t i a l s 0 1 0 0 7 1 1 . 7 6 . 3 0 5 2 0 3 . 1 0 H S 0 . 3 0 1 0 1 0 1 2 . 3 6 . 4 9 5 3 3 4 . 3 1 H S 0 . 6 0 1 0 1 1 1 2 . 4 6 . 5 8 5 3 0 4 . 8 3 H S 0 . 9 0 1 0 1 4 1 2 . 3 6 . 6 2 5 1 7 4 . 1 7 H S B e f o r e S a m p l i n g 1 0 1 4 1 2 . 3 6 . 6 2 5 1 7 4 . 1 7 H S C o m m e n t s ( w e a t h e r c o n d i t i o n s , o d o r , c o l o r , s i l t , e t c . ) : T h e w e a t h e r w a s s u n n y w i t h t e m n e r a t u r e s i n t h e 6 0 ’ s o n 1 0 / 1 9 / 1 5 . F i e l d b l a n k 1 7 5 0 S i g n a t u r e : Q A / Q C S i g n O f f : 1 f ; j 4 A — 2 i n c h e s 1 0 2 . 5 0 f e e t 1 0 5 . 0 0 f e e t 2 . 1 0 f e e t [ D T B - D T W ] f e e t D a t e : D a t e : i L 2 J 7 % / / D A T E : 1 0 / 1 9 / 1 5 J O Y C E _ _ _ _ _ _ _ _ _ _ I ( \ J 8 8 I t \ . j C 9 S U R F A C E W A T E R M O N I T O R I N G L O G P r o j e c t N a m e : T r a n s y l v a n i a C o . - C a l v e r t P r o j e c t / T a s k N o . : 3 3 6 . 1 6 0 1 . 1 2 . 0 1 S u r f a c e P o i n t I D : S M P - 1 S a m p l e r ( s ) : G . E l l e r / H . S e a t o n L o c a t i o n : B e h i n d M W - 3 F i e l d P a r a m e t e r s : T i m e o f S a m p l i n g : _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ p 1 1 : T e m p e r a t u r e : _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ ( ° C ) C o n d u c t i v i t y : _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ ( u S ) T u r b i d i t y : _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ ( n t u ) C o m m e n t s / S a m p l e D e s c r i p t i o n ( w e a t h e r c o n d i t i o n s , o d o r , c o l o r , s i l t , e t c . ) : T h e w e a t h e r w a s s u n n y w i t h t e m p e r a t u r e s i n t h e 6 0 ’ s o n 1 0 / 1 9 / 1 5 . T h e s u r f a c e p o i n t w a s d r y a n d w a s n o t s a m p l e d . S k e t c h o f S a m p l e L o c a t i o n ( i n c l u d e f l o w d i r e c t i o n , d r a i n a g e p a t h w a y s , e t c . ) : A A W C L c 1 l t ) S i g n a t u r e : / ( 6 U L ) D a t e : _ _ _ _ _ _ _ _ _ _ _ _ _ Q A I Q C S i g n O f f : _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ D a t e : - J O Y C E E P J G I I \ J 8 8 I = ? I r ’ J G P r o j e c t N a m e : T r a n s y l v a n i a C o . - C a l v e r t W e l l I D : H W - 1 D A T E : 1 0 / 1 9 / 1 5 G R O U N D W A T E R S A M P L I N G L O G P r o j e c t N o . / T a s k N o . : 3 3 6 . 1 6 0 1 . 1 2 . 0 1 S a m p l e r ( s ) : G . E l l e n H . S e a t o n W e l l L o c a t i o n : H o m e a t t h e e n d o f t h e r o a d b e h i n d l a n d f i l l W e l l D i a m e t e r : _ _ _ _ _ _ _ _ _ _ _ _ _ _ I n i t i a l D e p t h t o W a t e r ( D T W ) : _ _ _ _ _ _ _ _ _ _ _ _ _ _ D e p t h t o B o t t o m ( D T B ) : _ _ _ _ _ _ _ _ _ _ _ W a t e r C o l u m n T h i c k n e s s ( W C T ) : _ _ _ _ _ _ _ _ _ _ _ _ C a l c u l a t i o n f o r O n e W e l l V o l u m e ( W V ) : F o r 2 ” W e l l : W C T X 0 . 1 6 3 = _ _ _ _ _ _ _ _ _ _ _ F o r 4 ” W e l l : W C T X 0 . 6 5 3 = _ _ _ _ _ _ _ _ _ _ _ _ F o r T H R E E W e l l V o l u m e s : W V X 3 = _ _ _ _ _ _ _ _ _ A c t u a l A m o u n t P u r g e d / B a i l e d : _ _ _ _ _ _ _ _ _ _ _ _ P u r g e d w i t h : O p e n s p i g o t r u n n i n g f o r 1 5 m i n u t e s S a m p l e d w i t h : D i r e c t l y f r o m s p i g o t D e p t h t o W a t e r b e f o r e S a m p l i n g : - f e e t S i g n a t u r e : Q A / Q C S i g n O f f : / O / / c / / , ; / ‘ / 7 6 / 1 4 / - i n c h e s - f e e t - f e e t - f e e t [ D T B - D T W ] - g a l l o n s - g a l l o n s - g a l l o n s - a 1 1 o n s G a l l o n s T i m e T e m p ( ° C ) p H C o n d . ( r S ) T u r b . ( n t u ) I n i t i a l s - 1 5 5 5 1 5 . 4 6 . 9 1 8 5 5 . 6 4 H S - 1 6 0 0 1 4 . 8 6 . 5 4 5 3 5 . 7 9 H S - 1 6 0 5 1 4 . 3 6 . 2 2 4 7 4 . 2 7 H S - 1 6 1 0 1 4 . 5 6 . 1 4 4 6 4 . 4 9 H S B e f o r e S a m p l i n g 1 6 1 0 1 4 . 5 6 . 1 4 4 6 4 . 4 9 H S C o m m e n t s ( w e a t h e r c o n d i t i o n s , o d o r , c o l o r , s i l t , e t c . ) : T h e w e a t h e r w a s s u n n y w i t h t e m p e r a t u r e s i n t h e 6 0 ’ s o n 1 0 / 1 9 / 1 5 . I Appendix 2 Summary of Detections and Summary of Exceedances Su m m a r y o f D e t e c t i o n s WE L L I D P A R A M E T E R R E S U L T U N I T S S W S L C O L L E C T D A T E 88 0 3 - M W 1 C a d m i u m 1 . 9 µ g / L 1 1 0 / 1 9 / 2 0 1 5 88 0 3 - M W 1 0 5 D 1 , 4 - D i c h l o r o b e n z e n e 6 . 7 µ g / L 1 1 0 / 1 9 / 2 0 1 5 88 0 3 - M W 1 0 5 D B e n z e n e 2 . 2 µ g / L 1 1 0 / 1 9 / 2 0 1 5 88 0 3 - M W 1 0 5 D C h l o r o b e n z e n e 1 2 . 2 µ g / L 3 1 0 / 1 9 / 2 0 1 5 88 0 3 - M W 1 0 5 D T r i c h l o r o e t h e n e 1 . 1 µ g / L 1 1 0 / 1 9 / 2 0 1 5 88 0 3 - M W 1 0 5 D c i s - 1 , 2 - D i c h l o r o e t h e n e 1 3 . 4 µ g / L 5 1 0 / 1 9 / 2 0 1 5 88 0 3 - M W 1 0 5 S 1 , 4 - D i c h l o r o b e n z e n e 2 . 4 µ g / L 1 1 0 / 1 9 / 2 0 1 5 88 0 3 - M W 1 0 6 D 1 , 4 - D i c h l o r o b e n z e n e 5 . 7 µ g / L 1 1 0 / 1 9 / 2 0 1 5 88 0 3 - M W 1 0 6 D C h l o r o b e n z e n e 6 . 3 µ g / L 3 1 0 / 1 9 / 2 0 1 5 88 0 3 - M W 1 0 7 D 1 , 4 - D i c h l o r o b e n z e n e 1 . 1 µ g / L 1 1 0 / 1 9 / 2 0 1 5 88 0 3 - M W 1 0 8 1 , 4 - D i c h l o r o b e n z e n e 1 . 1 µ g / L 1 1 0 / 1 9 / 2 0 1 5 88 0 3 - M W 3 1 , 4 - D i c h l o r o b e n z e n e 1 3 . 1 µ g / L 1 1 0 / 1 9 / 2 0 1 5 88 0 3 - M W 3 B e n z e n e 1 . 1 µ g / L 1 1 0 / 1 9 / 2 0 1 5 88 0 3 - M W 3 C h l o r o b e n z e n e 1 0 . 8 µ g / L 3 1 0 / 1 9 / 2 0 1 5 No t e s : µ g / L = M i c o r g r a m s p e r l i t e r SW S L = N C S o i l d W a s t e S e c t i o n R e p o r t i n g L i m i t La b o r a t o r y R e p o r t i n g l i m i t u s e d w h e n S W S L h a s n o t b e e n e s t a b l i s h e d Tr a n s y l v a n i a C o . C a l v e r t L a n d f i l l Pe r m i t N o . 8 8 - 0 3 Pa g e 1 o f 1 Joyce Engineering Summary of Exceedances Transylvania Co. Calvert Landfill Permit No. 88-03 Page 1 of 1 Joyce Engineering WELL ID PARAMETER RESULT UNITS SWSL NC 2L GPS COLLECT DATE 8803-MW3 Benzene 1.1 µg/L 1 1 1 10/19/2015 8803-MW3 1,4-Dichlorobenzene 13.1 µg/L 1 6 6 10/19/2015 8803-MW105D Benzene 2.2 µg/L 1 1 1 10/19/2015 8803-MW105D 1,4-Dichlorobenzene 6.7 µg/L 1 6 6 10/19/2015 Notes:µg/L = Micorgrams per liter SWSL = NC Soild Waste Section Reporting Limit Laboratory Reporting limit used when SWSL has not been established NC2L = NC Groundwater Standard from 15A NCAC 2L.0202 GPS = Groundwater Protection Standard as defined by 15A NCAC 13B.1634(g) Appendix 3 Summary of Field Parameters Summary of Field Parameters Transylvania Co. Calvert Landfill Permit No. 88-03 Page 1 of 2 Joyce Engineering WELL ID PARAMETER RESULT UNITS COLLECT DATE 8803-HW1 pH 6.14 s.u 10/19/2015 8803-HW1 Temperature 14.5 C 10/19/2015 8803-HW1 Conductivity 46 u.s 10/19/2015 8803-HW1 Turbidity 4.49 ntu 10/19/2015 8803-MW1 pH 6.17 s.u 10/19/2015 8803-MW1 Temperature 17 C 10/19/2015 8803-MW1 Conductivity 186 u.s 10/19/2015 8803-MW1 Turbidity 15.8 ntu 10/19/2015 8803-MW1 Static Water Level 63.8 ft 10/19/2015 8803-MW1 Well Depth 72.64 ft 10/19/2015 8803-MW105D pH 5.96 s.u 10/19/2015 8803-MW105D Temperature 16.1 C 10/19/2015 8803-MW105D Conductivity 675 u.s 10/19/2015 8803-MW105D Turbidity 5.8 ntu 10/19/2015 8803-MW105D Static Water Level 57.65 ft 10/19/2015 8803-MW105D Well Depth 87.1 ft 10/19/2015 8803-MW105S pH 5.58 s.u 10/19/2015 8803-MW105S Temperature 15.7 C 10/19/2015 8803-MW105S Conductivity 187 u.s 10/19/2015 8803-MW105S Turbidity 6.52 ntu 10/19/2015 8803-MW105S Static Water Level 51.15 ft 10/19/2015 8803-MW105S Well Depth 55.37 ft 10/19/2015 8803-MW106D pH 6.13 s.u 10/19/2015 8803-MW106D Temperature 13.3 C 10/19/2015 8803-MW106D Conductivity 1210 u.s 10/19/2015 8803-MW106D Turbidity 5.79 ntu 10/19/2015 8803-MW106D Static Water Level 2.7 ft 10/19/2015 8803-MW106D Well Depth 75.38 ft 10/19/2015 8803-MW106S pH 6.09 s.u 10/19/2015 8803-MW106S Temperature 13.3 C 10/19/2015 8803-MW106S Conductivity 313 u.s 10/19/2015 8803-MW106S Turbidity 22.84 ntu 10/19/2015 8803-MW106S Static Water Level 8.2 ft 10/19/2015 8803-MW106S Well Depth 22.58 ft 10/19/2015 8803-MW107D pH 6.54 s.u 10/19/2015 8803-MW107D Temperature 12.6 C 10/19/2015 8803-MW107D Conductivity 413 u.s 10/19/2015 8803-MW107D Turbidity 16.69 ntu 10/19/2015 8803-MW107D Static Water Level 54.55 ft 10/19/2015 8803-MW107D Well Depth 90.3 ft 10/19/2015 8803-MW107S pH 6.21 s.u 10/19/2015 8803-MW107S Temperature 12.3 C 10/19/2015 8803-MW107S Conductivity 432 u.s 10/19/2015 8803-MW107S Turbidity 16.5 ntu 10/19/2015 8803-MW107S Static Water Level 51.85 ft 10/19/2015 8803-MW107S Well Depth 58.84 ft 10/19/2015 8803-MW108 pH 6.62 s.u 10/19/2015 8803-MW108 Temperature 12.3 C 10/19/2015 8803-MW108 Conductivity 517 u.s 10/19/2015 8803-MW108 Turbidity 4.17 ntu 10/19/2015 8803-MW108 Static Water Level 102.5 ft 10/19/2015 8803-MW108 Well Depth 105 ft 10/19/2015 Summary of Field Parameters Transylvania Co. Calvert Landfill Permit No. 88-03 Page 1 of 2 Joyce Engineering WELL ID PARAMETER RESULT UNITS COLLECT DATE 8803-MW2 pH 6.62 s.u 10/19/2015 8803-MW2 Temperature 12.2 C 10/19/2015 8803-MW2 Conductivity 652 u.s 10/19/2015 8803-MW2 Turbidity 7.58 ntu 10/19/2015 8803-MW2 Static Water Level 67.35 ft 10/19/2015 8803-MW2 Well Depth 83.3 ft 10/19/2015 8803-MW3 pH 6.39 s.u 10/19/2015 8803-MW3 Temperature 14.3 C 10/19/2015 8803-MW3 Conductivity 998 u.s 10/19/2015 8803-MW3 Turbidity 10.21 ntu 10/19/2015 8803-MW3 Static Water Level 3.75 ft 10/19/2015 8803-MW3 Well Depth 19.8 ft 10/19/2015 Notes:ºC= degrees Centigrade S.U.= Standard Units µS = microsemens NTU= Nephelometric Turbidity Units ft = feet Appendix 4 Summary of Monitoring Well Construction SUMMARY OF MONITORING WELL CONSTRUCTION Transylvania Co. Calvert Landfill Permit No. 88-03 Page 1 of 1 Joyce Engineering GROUND TOP OF WELL DEPTH (ft.)SCREENED INTERVAL (ft.)SCREENED INTERVAL WELL SURFACE CASING Below Below Ground Surface Elevation LITHOLOGY NO.Elevation (ft.)Elevation (ft.)Ground Surface From:To:Top:Bottom: MW-1 2303 2306.09 70 55 70 2248 2233 Bedrock MW-2 2280 2282.67 80 65 80 2215 2200 Bedrock MW-3 2208 2210.21 20 10 20 2198 2188 Saprolite MW-4 2326 2327.55 70 60 70 2266 2256 Bedrock MW-105S 2271 2270.55 55 40 55 2231 2216 Saprolite; Paired with MW-105D MW-105D 2271 2270.76 87 82 87 2189 2184 Bedrock; Paired with MW-105S MW-106S 2198 2197.12 22 7 22 2191 2176 Saprolite; Paired with MW-106D MW-106D 2198 2197.62 75 65 75 2133 2123 Bedrock; Paired with MW-106S MW-107S 2271 2272.79 57 42 57 2229 2214 Saprolite; Paired with MW-107D MW-107D 2271 2273.57 87 77 87 2194 2184 Bedrock; Paired with MW-107S MW-108 2332 2334.28 102 85 102 2247 2230 Bedrock Notes: Wells MW-1 and MW-2 were installed by Westinghouse Environmental and Geotechnical Services, Inc. in September 1991. Wells MW-3 and MW-4 were installed by Merrill Well and Pump Co., Inc. in August 1989. Wells MW-105S and MW-105D were installed by Joyce Engineering, Inc. in July 1997 Wells MW-106S, -106D, -107S, -107D, and 108 were installed by Joyce Engineering, Inc. in March 1999 All elevations are referenced to mean sea level. Top of casing elevations were surveyed by Clarence A. Jenkins on August 15, 1997 and May 26, 1999. All wells were constructed using 2-inch (inside diameter) casing.