41B-DEMO_WileyDavisRdLF_DIN26637_20150624

WATERS EDGE ENVIRONMENTAL, LLC
4901 WATERS EDGE DRIVE, SUITE 201  RALEIGH, NC 27606  PHONE [phone]  FAX [phone]

North Carolina Groundwater/Surface Water Exceedance Notification
(June 24th, 2015)

Well Parameter Concentration (mg/L) NCGS (mg/L)

WD-2 Barium 0.82 0.7
WD-2 Benzene 0.0017 0.001
WD-2 Chromium 0.011 0.010
WD-2 Selenium 0.029 0.02
WD-2 THF 0.100 0.0046*

WD-2D THF 0.050 0.0046*

WD-3 Barium 0.82 0.7
WD-3 THF 0.022 0.0046*

WD-4 Barium 0.79 0.7
WD-4 THF 0.016 0.0046*

WD-7 Chromium 0.072 0.01

WD-8 Cadmium 0.0067 0.002
WD-8 Chromium 0.012 0.01

WD-9 Barium 1.0 0.7
WD-9 Chromium 0.028 0.01

June 2015 Groundwater and Surface Water Sampling Report
Former Wiley Davis Landfill
Wiley Davis Road
Greensboro, North Carolina
Permit #41-B
July 13, 2015

Prepared For Submittal To

Griffin Industrial Services, LLC
Greensboro, North Carolina 27407

Prepared By

Waters Edge Environmental, LLC
Raleigh, North Carolina
WATERS EDGE ENVIRONMENTAL, LLC
4901 WATERS EDGE DRIVE, SUITE 201  RALEIGH, NC 27606  PHONE [phone]  FAX [phone]

July 13, 2015

Mr. David Griffin, Jr.
Griffin Industrial Services, LLC
4700 Hilltop Road
Greensboro, North Carolina 27407

Reference: June 2015 Groundwater and Surface Water Sampling Report
Former Wiley David Landfill
Wiley Davis Road
Greensboro, North Carolina
Permit #41-B
Waters Edge Job No. R5-34

Dear Mr. Griffin:

Waters Edge Environmental has completed the June 2015 groundwater and surface water
sampling event at the above mentioned facility.

If you have any questions regarding the information contained herein, please do not
hesitate to contact our office at 919.859.9987.

Sincerely,

WATERS EDGE ENVIRONMENTAL, LLC

Phillip L Rahn, P.G.
President

cc: Ms. Christine Ritter- NCDENR

15-064/PLR/aht

ii
Table of Contents

1 Introduction 1
2 Groundwater Sampling Activities 1
2.1 Monitor Well Sampling 1
2.2 Surface Water Sampling 1
3 Assessment Results 2
3.1 Groundwater Conditions 2
3.2 Groundwater Laboratory Analytical Results 2
3.3 Surface Water Laboratory Analytical Results 3
4 Conclusions and Recommendations 3

Figures

Figure No. Title

1 Site Location Map
2 Aerial Photograph Map
3 Groundwater Potentiometric Surface (June 2015)

Tables

Table No. Title

1 Groundwater Elevation Data
2 Hydraulic Gradient Data
3 Groundwater / Surface Water Analytical Results

Appendices

Appendix Title

A Laboratory Analytical Results

Page 1 of 4
June 2015 Ground and Surface Water Sampling Report
Former Wiley Davis Landfill
Wiley Davis Road
Greensboro, North Carolina
Permit #41-B
July 13, 2015

1 Introduction

A groundwater and surface water assessment is ongoing at the former Wiley Davis
Landfill (Permit #41-B) located on Wiley Davis Road in Greensboro, North Carolina (see
Figures 1 and 2). The purpose of this assessment is to determine the presence, extent,
and concentration of contaminants present in groundwater and/or surface water, the
horizontal and vertical extent of contamination which may originate from the landfill, the
direction and rate of migration of the contaminants in the groundwater, and the possible
source(s) of contamination detected in the groundwater and/or surface water.

This assessment is being performed in accordance with the Water Quality Monitoring
Plan (Babb & Associates, P.A. and EcoLogic Associates, P.C. - Revised August 1999)
and the Groundwater Assessment Plan (Babb & Associates, P.A. and EcoLogic
Associates, P.C. - Revised August 1999). Since 2005 the sampling responsibilities have
been contracted with Waters Edge Environmental, LLC (Waters Edge).

Herein contains an account of the field sampling, laboratory analytical results and our
conclusions and recommendations for the site.

2 Groundwater Sampling Activities

2.1 Monitoring Well Sampling

On June 24th, 2015, a Waters Edge environmental technician was mobilized to the site for
the groundwater sampling activities. Prior to the sampling event, depth-to-groundwater
measurements were made to the nearest 0.01 foot at each monitoring well using an
electric water level indicator (see Tables 1 and 2).

Groundwater samples were collected from wells WD-1, WD-2, WD-2D, WD-3, WD-3D,
WD-4, WD-4D, WD-7, WD-8, and WD-9 (WD-8 mislabeled as WD-6 and WD-9
mislabeled as WD-5 in laboratory results). Groundwater samples were analyzed for volatile
organic compounds (VOCs) and tetrahydrofuran (THF) according to EPA Method 8260B
and total RCRA metals (EPA Method 6010 and 7470- see summary of analytical results in
Table 3 and documentation in Appendix A).

2.3 Surface Water Sampling

On June 24th, 2015, both upgradient (SW-1 see Figure 2) and downgradient (SW-2 see
Figure 2) surface water samples were collected and analyzed for VOCs and THF according
June 2015 Ground & Surface Water Sampling Report
Wiley Davis Landfill
Greensboro, North Carolina
July 13, 2015
15-064

Page 2 of 4
to EPA Method 8260B and total RCRA metals (EPA Method 6010 and 7470- see summary
of analytical results in Table 3 and documentation in Appendix A).

3 Assessment Results

3.1 Groundwater Conditions

On June 24th, 2015 water level measurements collected from the shallow wells indicate
the shallow water table elevations range from 816.93 feet (WD-7) to 786.97 feet (WD-3)
above mean sea level (msl). We would add that WD-2, WD-2D, WD-8 and WD-9 have
not been surveyed to add as a data point. The groundwater elevations continue to
indicate an overall southwesterly flow direction for shallow groundwater. The horizontal
hydraulic gradient of the shallow water table has an average gradient of 0.0163 ft/ft (see
Figure 3)

The vertical gradient was calculated to be 0.0534 ft/ft downward between wells WD-3
and WD-3D and -0.0933 upward between wells WD-4 and WD-4D. We would also note
that WD-2/WD-2D have not been surveyed.

3.2 Groundwater Laboratory Analytical Results

Laboratory analysis of groundwater samples collected had the following exceedances of
North Carolina Groundwater Standards (NCGS):

WD-2 This well had the following NCGS exceedances:
 Barium at 0.82 mg/L versus a NCGS at 0.7 mg/L
 Chromium at 0.011 mg/L versus a NCGS at 0.01 mg/L
 Selenium at 0.029 mg/L versus a NCGS at 0.02 mg/L
 Benzene at 1.7 mg/L versus a NCGS at 0.001 mg/L
 THF at 0.1 mg/L versus a North Carolina Occupational and
Environmental Epidemiology Branch Recommended 2L Standard of
0.0046 mg/L (there is no codified NCGS)
WD-2D This well had the following NCGS exceedances:
 THF at 0.050 mg/L versus a North Carolina Occupational and
Environmental Epidemiology Branch Recommended 2L Standard of
0.0046 mg/L (there is no codified NCGS)
June 2015 Ground & Surface Water Sampling Report
Wiley Davis Landfill
Greensboro, North Carolina
July 13, 2015
15-064

Page 3 of 4
WD-3 This well had the following NCGS exceedances:
 Barium at 0.82 mg/L versus a NCGS at 0.7 mg/L
 THF at 0.022 mg/L versus a North Carolina Occupational and
Environmental Epidemiology Branch Recommended 2L Standard of
0.0046 mg/L (there is no codified NCGS)
WD-4 This well had the following NCGS exceedances:
 Barium at 0.79 mg/L versus a NCGS at 0.7 mg/L
 THF at 0.016 mg/L versus a North Carolina Occupational and
Environmental Epidemiology Branch Recommended 2L Standard of
0.0046 mg/L (there is no codified NCGS)
WD-7 This well had the following NCGS exceedances:
 Chromium at 0.072 mg/L versus a NCGS at 0.01 mg/L

WD-8 This well had the following NCGS exceedances:
 Cadmium at 0.0067 mg/L versus a NCGS at 0.002 mg/L
 Chromium at 0.012 mg/L versus a NCGS at 0.01 mg/L

WD-9 This well had the following NCGS exceedances:
 Barium at 1.0 mg/L versus a NCGS at 0.7 mg/L
 Chromium at 0.028 mg/L versus a NCGS at 0.01 mg/L

3.3 Surface Water Laboratory Analytical Results

Low levels of one inorganic constituent was detected in upstream sampling point SW-1
(barium at 0.01 mg/L), and the downstream sampling point SW-2 had one inorganic
(barium at 0.11 mg/L); however, no applicable Class C surface water standards were
exceeded (15A NCAC 2B .0211).

4 Conclusions and Recommendations

Information gathered during groundwater assessment activities to date indicates the
general shallow and deep groundwater flow direction (horizontal gradient) beneath the
June 2015 Ground & Surface Water Sampling Report
Wiley Davis Landfill
Greensboro, North Carolina
July 13, 2015
15-064

Page 4 of 4
site to be to the southwest. Using a horizontal hydraulic gradient of 0.0163 ft/ft and
assuming an average hydraulic conductivity in saprolite of 1E-5 cm/sec and an effective
porosity of 0.25, the rate of horizontal groundwater migration would be on the order of
0.613 ft/year.

Now that the landfill is no longer active and has been graded to shed runoff and covered,
the infiltration of rainfall should be significantly reduced. It follows that the driving head
inside the landfill will gradually decline and both the quantity and rate of leachate
production and release should decrease proportionately. Leachate strength should also
continue to decline as the waste stabilizes, with no further introduction of potential
contaminants. Based on these recent results, we would conclude that a continued positive
trend in groundwater quality downgradient of the landfill has occurred.

There were several low level NCGS exceedances for arsenic, barium, cadmium,
chromium and selenium. THF was also detected at low concentrations in four of the
wells sampled ranging from 0.016 mg/L (WD-4) to 0.1 mg/L (WD-2) which is above the
interim NCGS at 4.6 g/L. It was previously detected in downgradient well WD-9 at
0.019 mg/L but was ND during this sampling round. Based upon our research into THF
uses, it appears one major use is for PVC pipe cement which could have been mistakenly
used in the older monitoring wells. The newer monitoring wells were ND for THF
during this sampling round. The levels in the remaining wells appear to be either stable
or decreasing to below NCGS with respect to time.

There were also several inorganic constituents detected in the newly emplaced
monitoring wells WD-8 and WD-9. Based on the total absence of VOCs, we would still
conclude that these are potentially due to sediment causing false positive readings. We
believe that with continued development and sampling that the inorganic constituents will
decrease. We would conclude that the plume is adequately defined horizontally.

Only one RCRA metal was detected in surface water samples (barium) at concentrations
well below the 2B standards. As such, we conclude that no measurable impacts to
surface water by VOCs or metals have been identified during this assessment.

Given the aforementioned conclusions, it is our recommendation to Wiley Davis Landfill,
Inc. that monitoring of the current system is continued on a semiannual schedule. This
next sampling event would be conducted in November 2015. We would also recommend
that WD-2, WD-2D, WD-8, and WD-9 be surveyed for both horizontal and vertical
control.

Figures
Au
t
h
o
r

D
r
a
w
i
n
g

Q
u
a
d

D
a
t
e

T
i
t
l
e
R5
-
3
4
.
x
l
s

G
r
e
e
n
s
b
o
r
o

7
/
6
/
2
0
0
5
Jo
b

N
o
.

R
e
p
o
r
t

D
a
t
e

F
i
g
u
r
e

S
c
a
l
e
R5
-
3
4

1

a
s

s
h
o
w
n
Gr
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a
Wi
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
Pr
o
j
e
c
t

L
o
c
a
t
i
o
n

M
a
p
WA
T
E
R
S

E
D
G
E

E
N
V
I
R
O
N
M
E
N
T
A
L
,

L
L
C
Pr
o
j
e
c
t
SI
T
E
Au
t
h
o
r

D
r
a
w
i
n
g

L
a
y
e
r
s

D
a
t
e

T
i
t
l
e
R5
-
3
4
.
x
l
s

7
/
6
/
2
0
0
5
Jo
b

N
o
.

R
e
v
i
s
i
o
n

F
i
g
u
r
e

S
c
a
l
e
R5
-
3
4

2

u
n
k
n
o
w
n
Gr
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a
20
0
3
GU
I
L
F
O
R
D

C
O
U
N
T
Y

S
P
A
T
I
A
L

D
A
T
A

E
X
P
L
O
R
E
R
Wi
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
Ae
r
i
a
l

P
h
o
t
o
g
r
a
p
h

M
a
p
WA
T
E
R
S

E
D
G
E

E
N
V
I
R
O
N
M
E
N
T
A
L
,

L
L
C
Pr
o
j
e
c
t

Tables
Table 1
Monitoring Well Reference Points and Groundwater Elevaltions
Wiley Davis Landfill,
Greensboro, North Carolina
Well ID Reference Point
Elevation
Water Level
Measurement
(6.24.15)
Water Level Elevation
WD-1 836.65 32.03 804.62
WD-3 791.35 4.38 786.97
WD-3D 793.79 8.85 784.94
WD-4 793.28 4.83 788.45
WD-4D 799.11 6.32 792.79
WD-7 828.08 11.15 816.93
Table 1 GW Elevations
Table 2
Hydraulic Gradient Information
Wiley Davis Landfill
Greensboro, North Carolina
Water Level Elevation
Well I.D. 6.24.15 Gradient
(ft.) (ft.)
WD-1 804.62
0.0181
WD-3 786.97
WD-1 804.62
0.0169
WD-4 788.45
WD-7 816.93
0.0189
WD-1 804.62
WD-7 816.93
0.0218
WD-4 788.45
WD-4D 792.79
0.0176
WD-3D 784.94
WD-3 786.97
0.0534
WD-3D 784.94
WD-4 788.45
-0.0933
WD-4D 792.79
A Negative Hydraulic Gradient Indicates Greater Hydraulic Head in the Deeper Well or Upward Flow.
Waters Edge Job No. R5-34 Wiley Davis Groundwater Table.xlsx.xls, Table 2 Hydraulic Grad
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
1
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

A
u
g
-
9
0

M
a
r
-
9
1

A
p
r
-
9
1

M
a
y
-
9
3

O
c
t
-
9
3

A
p
r
-
9
4

F
e
b
-
9
6

A
u
g
-
9
6

A
p
r
-
9
7

N
o
v
-
9
7

O
c
t
-
9
8
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
bi
s
-
(
2
-
e
t
h
y
l
h
e
x
y
l
)

p
h
t
h
a
l
a
t
e
ug
/
L
3.
0
.

N
o
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
16
..
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,
8
0
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Ch
l
o
r
o
m
e
t
h
a
n
e
ug
/
L
3.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
di
-
n
-
b
u
t
y
l

p
h
t
h
a
l
a
t
e
ug
/
L
70
0

1
2
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
70
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Me
t
h
y
l

I
o
d
i
d
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
4-
(
o
-
c
r
e
s
o
l
)

M
e
t
h
y
l
p
h
e
n
o
l
ug
/
L
3.
5

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
.

.

N
A

N
A

N
A

N
A

N
A

N
A
Na
p
h
t
h
a
l
e
n
e
ug
/
L
21

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
N-
N
i
t
r
o
s
o
d
i
p
h
e
n
y
l
a
m
i
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
1
0
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
1
5

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

1
2

1
6
00
0
0
0
0
0
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5

.
No
t

S
a
m
p
l
e
d
NA.
N
A
.
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
2.
0

0
.
3
8
0
No
t

S
a
m
p
l
e
d
0.
5
8
0

0
.
3
1
4

N
A

0
.
4
5
0

0
.
3
0
0

0
.
2
7
0

0
.
2
9
1

0
.
3
2
0

0
.
2
0
0
Ca
d
m
i
u
m
mg
/
l
0.
0
0
5

.
No
t

S
a
m
p
l
e
d
NA.
N
A
.
.
.
0.
0
0
6
..
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5
0.
1
6
0
No
t

S
a
m
p
l
e
d
0.
3
6
0
0.
0
5
0

N
A
0.
0
7
0
0.
0
4
0

.
0.
1
1
0

0
.
0
7
1

0
.
0
8
4
Le
a
d
mg
/
l
0.
0
1
5

.
No
t

S
a
m
p
l
e
d
0.
0
0
6

.

N
A
..
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
1

.
No
t

S
a
m
p
l
e
d
NA.
N
A
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
5

.
No
t

S
a
m
p
l
e
d
NA.
N
A
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
1
8

.
No
t

S
a
m
p
l
e
d
NA.
N
A
.
.
.
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
1
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

M
a
r
-
0
0

S
e
p
-
0
0

M
a
y
-
0
1

D
e
c
-
0
1

J
u
l
-
0
2

J
a
n
-
0
3

M
a
y
-
0
5

M
a
r
-
0
6

M
a
y
-
0
6

N
o
v
-
0
6

J
u
n
-
0
7
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
.
.
.
.
.
.
.
bi
s
-
(
2
-
e
t
h
y
l
h
e
x
y
l
)

p
h
t
h
a
l
a
t
e
ug
/
L
3.0
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,
8
0
0
..
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
m
e
t
h
a
n
e
ug
/
L
3.
.
.
.
.
.
.
.
.
.
2
.
5
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
di
-
n
-
b
u
t
y
l

p
h
t
h
a
l
a
t
e
ug
/
L
700
.
.
.
.
.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
700
.
.
.
.
.
.
.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
.
.
.
.
Me
t
h
y
l

I
o
d
i
d
e
ug
/
L
NS
.
.
.
.
.
2
.
0
N
A
N
A
N
A
N
A
N
A
4-
(
o
-
c
r
e
s
o
l
)

M
e
t
h
y
l
p
h
e
n
o
l
ug
/
L
3.5
.
.
.
.
.
.
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
21
.
.
.
.
.
.
.
.
.
.
.
N-
N
i
t
r
o
s
o
d
i
p
h
e
n
y
l
a
m
i
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
..
.
.
.
.
.
.
.
.
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
1
0
0
..
.
.
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
1
5
..
.
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-
00
0
0
0
2
.
0
0
0
0
0
2
.
5
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5
..
.
.
.
.
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
2.
0

.

.

0
.
2
9
4

.

0
.
2
8
1

0
.
2
9
0

0
.
3
5

0
.
3
7

0
.
3
7

0
.
4
7

0
.
4
7
Ca
d
m
i
u
m
mg
/
l
0.
0
0
5

.

0
.
0
0
1
3

0
.
0
0
1
4
..
.
.
.
.
0.
0
0
2
0
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5
..
.
.
.
.
0.
0
1
4

.

.
0.
1
1
0.
0
4
1
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
.
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
1
..
.
.
.
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
5

.

.

0
.
0
1
0
5
..
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
1
8
..
.
.
.
.
.
.
.
0.
0
0
7
5

.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
1
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

N
o
v
-
0
7

M
a
y
-
0
8

N
o
v
-
0
8

M
a
y
-
0
9

N
o
v
-
0
9

J
u
n
-
1
0

N
o
v
-
1
0

M
a
y
-
1
1

N
o
v
-
1
1

M
a
y
-
1
2

D
e
c
-
1
2
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,
0
0
0
..
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
m
e
t
h
a
n
e
ug
/
L
3.
.
.
.
.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20
.
.
.
.
.
.
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
.
.
.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
..
.
.
.
.
.
.
.
.
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
0
0
0
..
.
.
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-
00
0
0
0
0
0
0
0
0
0
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1
..
.
.
.
.
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
0.
7

0
.
4
7

0
.
4
6

0
.
4
0

0
.
4
1

0
.
4
8

0
.
4
0

0
.
4
6

0
.
4
3

0
.
4
7

0
.
4
4

0
.
4
6
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2

.

0
.
0
0
1
2
..
.
.
.
.
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1
0.
0
5
2

0
.
0
9
6

0
.
0
4
4

0
.
0
2
5

0
.
0
4
0

0
.
0
2
5

0
.
0
6
1

0
.
0
2
7

0
.
0
4
1

0
.
0
2
0

0
.
0
1
4
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
.
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
..
.
.
.
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2
..
.
.
.
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
2

.

0
.
0
0
7
4
..
.
.
0.
0
0
5
8
..
.
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
1
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

J
u
n
-
1
3

D
e
c
-
1
3

D
e
c
-
1
4

J
u
n
-
1
5
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,
0
0
0
..
.
.
Ch
l
o
r
o
m
e
t
h
a
n
e
ug
/
L
3.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
..
.
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
0
0
0
..
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-
00
0
0
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1
..
.
.
Ba
r
i
u
m
mg
/
l
0.
7

0
.
5
0

0
.
5
2

0
.
4
8

0
.
4
4
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
..
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1
0.
0
2
4

0
.
0
3
3

0
.
0
1
2
0.
0
1
0
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
..
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2
..
.
.
Si
l
v
e
r
mg
/
l
0.
0
2
..
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
2
s
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

A
u
g
-
9
0

M
a
r
-
9
1

A
p
r
-
9
1

M
a
y
-
9
3

O
c
t
-
9
3

A
p
r
-
9
4

F
e
b
-
9
6

A
u
g
-
9
6

A
p
r
-
9
7

N
o
v
-
9
7

O
c
t
-
9
8
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.
0

.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
2.
2
4
..
bi
s
-
(
2
-
e
t
h
y
l
h
e
x
y
l
)

p
h
t
h
a
l
a
t
e
ug
/
L
3.
0

6

J
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
se
c
-
b
u
t
y
l
b
e
n
z
e
n
e
ug
/
L
70

.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
35
0
No
t

S
a
m
p
l
e
d
23
0

1
4
0
.
15
0

6
2

8
9

1
1
0

1
1
0

7
8
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,
8
0
0

.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
di
-
n
-
b
u
t
y
l

p
h
t
h
a
l
a
t
e
ug
/
L
70
0

2
5
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
62
No
t

S
a
m
p
l
e
d
39

1
2

.

1
3

.

.

5
.
0

.

.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
5
J
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
25
No
t

S
a
m
p
l
e
d
12.
.
5
.
0
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
70
0

.
No
t

S
a
m
p
l
e
d
20

5
.
9

.

5
.
0

.

.

1
.
1
9

.

.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70

.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
Et
h
y
l
b
e
n
z
e
n
e
ug
/
L
55
0

.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e
ug
/
L
70

.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
p-
I
s
o
p
r
o
p
y
l
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.
0

.
No
t

S
a
m
p
l
e
d
6.
0
..
.
.
.
.
.
.
Me
t
h
y
l
-
t
e
r
t

b
u
t
y
l

e
t
h
e
r
ug
/
L
20
0
.
0

.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
4-
(
o
-
c
r
e
s
o
l
)

M
e
t
h
y
l
p
h
e
n
o
l
ug
/
L
3.
5

.
No
t

S
a
m
p
l
e
d
47
.

.

N
A

N
A

N
A

N
A

N
A

N
A
Na
p
h
t
h
a
l
e
n
e
ug
/
L
21

.
No
t

S
a
m
p
l
e
d
10 J
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
To
l
u
e
n
e
ug
/
L
1,
0
0
0

.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
1,
2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
ug
/
L
35
0

.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
1,
3
,
5
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
ug
/
L
35
0

.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
1
5

.
No
t

S
a
m
p
l
e
d
16
..
.
.
.
.
.
.
Xy
l
e
n
e
s
ug
/
L
53
0

.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

4
7
3

3
8
0

1
5
7
.
9

0

1
7
3

6
2

8
9

1
1
8
.
4
3

1
1
0

7
8
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5

.
No
t

S
a
m
p
l
e
d
NA.
N
A
.
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
2.
0

0
.
8
0
0
No
t

S
a
m
p
l
e
d
1.
7
0
0

1
.
3
0
0

N
A
2.
2
0
0
1.
9
0
0
2.
4
0
0

2
.
1
2
7

2
.
4
0
0

2
.
4
0
0
Ca
d
m
i
u
m
mg
/
l
0.
0
0
5

.
No
t

S
a
m
p
l
e
d
NA

.

N
A

.

.

.

0
.
0
0
3

.

.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5

.
No
t

S
a
m
p
l
e
d
.

.

N
A

.

.

.

0
.
0
0
5

.

.
Le
a
d
mg
/
l
0.
0
1
5

.
No
t

S
a
m
p
l
e
d
.

.

N
A

.

.

.

0
.
0
0
5

.

.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
1

.
No
t

S
a
m
p
l
e
d
..
N
A
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
5

.
No
t

S
a
m
p
l
e
d
..
N
A
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
1
8

.
No
t

S
a
m
p
l
e
d
..
N
A
.
.
.
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
2
s
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

M
a
r
-
0
0

N
o
v
-
0
6

J
u
n
-
0
7

N
o
v
-
0
7

M
a
y
-
0
8

N
o
v
-
0
8

M
a
y
-
0
9

N
o
v
-
0
9

J
u
n
-
1
0

N
o
v
-
1
0

M
a
y
-
1
1
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.
0

.
1.
9

1
.
7

1
.
8

1
.
8

1
.
6

1
.
5

1
.
9

1
.
9

1
.
2

1
.
8
se
c
-
b
u
t
y
l
b
e
n
z
e
n
e
ug
/
L
70
.
0
..
.
.
2
.
0
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
94
7.3
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,
0
0
0
..
.
.
.
.
.
.
.
.
1
Ch
l
o
r
o
m
e
t
h
a
n
e
ug
/
L
3.
1
.
6
.
.
.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
205
.
0
1
.
8
.
.
.
.
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
.
.
.
.
.
.
.
Di
c
h
l
o
r
o
d
i
f
l
u
o
r
o
m
e
t
h
a
n
e

(f
r
e
o
n
)

u
g
/
L
1,
0
0
0

.
1.
9
..
.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6

.

.

1
.
5

3
.
6

1
.
6

2
.
0

.

3
.
9

.

.

.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
.
.
.
.
.
.
Et
h
y
l
b
e
n
z
e
n
e
ug
/
L
60
0

.

.

1
.
2

1
.
4

1
.
0

1
.
7

1
.
5

1
.
7

.

.

.
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e (
C
u
m
e
n
e
)

u
g
/
L
70

.

.

1
.
8

2
.
3

2
.
0

1
.
7

2
.
1

2
.
3

2
.
6

2
.
1

2
.
8
p-
I
s
o
p
r
o
p
y
l
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.1.
8
1
.
1
.
.
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
-
t
e
r
t

b
u
t
y
l

e
t
h
e
r
ug
/
L
20
.
.
1
.
2
1
.
2
.
.
1
.
1
.
.
.
.
4-
(
o
-
c
r
e
s
o
l
)

M
e
t
h
y
l
p
h
e
n
o
l
ug
/
L
40
.
.
.
.
.
N
A
N
A
N
A
N
A
N
A
N
A
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6

.

3
.
3

4
.
1

5
.
3

6
.
5

3
.
1

1
.
6

6
.
4

2
.
0

.

2
.
1
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
54

1
1
0

1
8
0

1
9
0

1
1
0

1
7

1
1

1
6
0

1
5
0

9
1

8
9
To
l
u
e
n
e
ug
/
L
60
0
.
.

2
.
1

1
.
5

1
.
1

.

.

1
.
2

.

.

.
1,
2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
ug
/
L
40
0
.
.

3
.
3

3
.
3

.

2
.
4

2
.
0

1
.
7

.

.

1
.
2
1,
3
,
5
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
ug
/
L
40
0
.
.1.
1
1
.
1
1
.
1
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
.
.
.
.
.
.
.
Xy
l
e
n
e
s
ug
/
L
50
0

.

.

5
.
6

5
.
3

4
.
8

3
.
9

4
.
1

4
.
0

2
.
3

.

2
.
9
To
t
a
l

V
O
C
s

u
g
/
L

-
-

1
5
3

1
2
9
.
6

2
0
4
.
7

2
1
6
.
8

1
3
1
.
9

3
3
.
4

2
4
.
9

1
8
3
.
1

1
5
8
.
8

9
4
.
3

1
0
0
.
8
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1

.

.
0.
0
1
4
0.
0
0
7
4

0
.
0
0
6
7

.
0.
0
1
9
0.
0
0
9
7
0.
0
2
4

0
.
0
1
5
.
Ba
r
i
u
m
mg
/
l
0.
7
2.
2
4
0.
3
4

0
.
3
6

0
.
4
7

0
.
5
3

0
.
3
1

0
.
5
2

0
.
3
7
0.
7
2
0.
4
1

0
.
3
9
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2

0
.
0
0
3
3
..
.
.
.
.
.
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1

.

0
.
0
0
9
2

0
.
0
0
8
8
0.
0
2
2

0
.
0
1
2
0.
0
0
9
8

0
.
0
0
8
5

0
.
0
1
0
0.
0
3
8
0.
0
1
0

0
.
0
0
9
1
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
.
.
.
.
0.
0
0
8
8

.

.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
..
.
.
.
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2
..
.
.
.
.
0.
0
1
2
..
.
.
Si
l
v
e
r
mg
/
l
0.
0
2

.

0
.
0
0
5
0
..
.
.
0.
0
0
5
0

0
.
0
0
5
4

0
.
0
0
5
4

.

.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
2
s
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

N
o
v
-
1
1

M
a
y
-
1
2

D
e
c
-
1
2

J
u
n
-
1
3

D
e
c
-
1
3

D
e
c
-
1
4

J
u
n
-
1
5
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.
0
2.
2

1
.
3

1
.
4

1
.
6

1
.
5

2
.
1

1
.
7
se
c
-
b
u
t
y
l
b
e
n
z
e
n
e
ug
/
L
70
.
0
..
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
.
.
.
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,
0
0
0
..
.
.
.
.
.
Ch
l
o
r
o
m
e
t
h
a
n
e
ug
/
L
3.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20
.
.
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
.
.
.
Di
c
h
l
o
r
o
d
i
f
l
u
o
r
o
m
e
t
h
a
n
e

(f
r
e
o
n
)

u
g
/
L
1,
0
0
0
..
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
.
.
Et
h
y
l
b
e
n
z
e
n
e
ug
/
L
600
.
.
.
.
.
.
.
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e (
C
u
m
e
n
e
)

u
g
/
L
70

3
.
0

2
.
7

2
.
4

2
.
1

2
.
9

4
.
5

2
.
7
p-
I
s
o
p
r
o
p
y
l
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
Me
t
h
y
l
-
t
e
r
t

b
u
t
y
l

e
t
h
e
r
ug
/
L
20
.
.
.
.
.
.
.
4-
(
o
-
c
r
e
s
o
l
)

M
e
t
h
y
l
p
h
e
n
o
l
ug
/
L
40
.
.
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6

1
.
9

.

.

1
.
3

1
.
0

.

.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
13
0

8
5

1
9
0

9
2

1
5
0

1
4
0

1
0
0
To
l
u
e
n
e
ug
/
L
600
.
.
.
.
.
.
.
1,
2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
ug
/
L
400
.
.
.
.
.
.
.
1,
3
,
5
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
ug
/
L
400
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
.
.
.
Xy
l
e
n
e
s
ug
/
L
500
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

1
3
7
.
1

8
9
.
0

1
9
3
.
8

9
7
.
0

1
5
5
.
4

1
4
6
.
6

1
0
4
.
4
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1

0
.
0
0
7
3

0
.
0
0
8
2
..
.
.
.
Ba
r
i
u
m
mg
/
l
0.
7
0.
7
1
0.
6
8
0.
8
2

0
.
7
5

0
.
8
0

0
.
7
2

0
.
8
2
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
..
.
.
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1
0.
0
1
4

0
.
0
1
1

0
.
0
1
4

0
.
0
1
2

0
.
0
1
3

0
.
0
1
2

0
.
0
1
1
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
.
.
0.
0
0
5
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
..
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2
..
.
.
.
.
0.
0
2
9
Si
l
v
e
r
mg
/
l
0.
0
2

.

.

0
.
0
0
5
1
..
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
2
d
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

A
u
g
-
9
0

M
a
r
-
9
1

A
p
r
-
9
1

M
a
y
-
9
3

O
c
t
-
9
3

A
p
r
-
9
4

F
e
b
-
9
6

A
u
g
-
9
6

A
p
r
-
9
7

N
o
v
-
9
7

O
c
t
-
9
8
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
1.
7
9
..
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

4
7
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
10
0
.
11
0

1
0
0

9
3

9
4

1
1
0

5
7
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,
8
0
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Ch
l
o
r
o
m
e
t
h
a
n
e
ug
/
L
3.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
26

.

3
4

1
2

2
2

1
5

6
.
6

1
0
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
7
.
2
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
70
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
6.
3

.

5
.
0

.

.

1
.
8
1

.

.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
4-
(
o
-
c
r
e
s
o
l
)

M
e
t
h
y
l
p
h
e
n
o
l
ug
/
L
3.
5

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
.

.

N
A

N
A

N
A

N
A

N
A

N
A
Na
p
h
t
h
a
l
e
n
e
ug
/
L
21

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
1
0
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
1
5

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

4
7

1
3
2
.
3

0

1
4
9

1
1
2

1
2
2
.
2

1
1
2
.
6
0

1
1
6
.
6

6
7
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5

.

N
A

N
A
..
.
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
2.
0

0
.
2
0
0

N
A

0
.
3
1
0

0
.
1
1
2

N
A

0
.
2
3
0

0
.
1
0
0

0
.
2
5
0

0
.
1
5
8

0
.
1
9
0

0
.
1
8
0
Ca
d
m
i
u
m
mg
/
l
0.
0
0
5

.

N
A

N
A

.

N
A

.
0.
0
0
6
..
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5

.

N
A

0
.
0
3
0

.

N
A

.

0
.
0
1
5

.

.

.
Le
a
d
mg
/
l
0.
0
1
5
0.
4
4
0
.

.

0
.
0
1
5

N
A

.

.

0
.
0
0
5

.

.

.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
1

.

N
A

N
A

.

N
A
..
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
5

.

N
A

N
A

.

N
A
..
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
1
8

.

N
A

N
A

.

N
A
..
.
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
2
d
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

M
a
r
-
0
0

N
o
v
-
0
6

J
u
n
-
0
7

N
o
v
-
0
8

M
a
y
-
0
8

N
o
v
-
0
8

M
a
y
-
0
9

N
o
v
-
0
9

J
u
n
-
1
0

N
o
v
-
1
0

M
a
y
-
1
1
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.
0

.
1.
6

2
.
4

2
.
0

2
.
3

1
.
3

1
.
2
..
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
68
.

7
.
8

8
.
8

9
.
4

4
.
6

5
.
8

5
.
5

2
.
5

4
.
5

3
.
5
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,
0
0
0

.

4
.
6
..
.
.
.
.
.
.
.
Ch
l
o
r
o
m
e
t
h
a
n
e
ug
/
L
3.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20

1
0

.

1
.
3

1
.
6

1
.
9

.

1
.
2

1
.
4

1
.
0

1
.
2

1
.
2
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
1
.
9
.
.
.
.
.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
.
.
.
.
.
.
Di
c
h
l
o
r
o
d
i
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
1,
0
0
0

.

.

1
.
9

.

1
.
1
..
.
.
.
.
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e

(c
u
m
e
n
e
)

u
g
/
L
70

.

2
.
1

1
.
8

3
.
6

3
.
1

1
.
2

1
.
6

1
.
5

1
.
5

.

1
.
0
p-
I
s
o
p
r
o
p
y
l
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.3.
9
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
2
.
3
.
.
.
.
.
Me
t
h
y
l
-
t
e
r
t

b
u
t
y
l

e
t
h
e
r
ug
/
L
20
.
0

.

1
.
3
..
.
.
.
.
.
.
.
4-
(
o
-
c
r
e
s
o
l
)

M
e
t
h
y
l
p
h
e
n
o
l
ug
/
L
40
.
.
.
.
.
N
A
N
A
N
A
N
A
N
A
N
A
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
8
.
9
1
.
2
1
.
1
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
51

1
8
0

1
7
0

1
1
0

1
3
0

1
3

1
1

1
2
0

5
1

6
2

5
5
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
0
0
0
..
.
.
.
.
.
.
.
.
.
1,
2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
ug
/
L
400
.
2
.
5
.
.
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
.
.
.
.
.
.
.
Xy
l
e
n
e
s

(t
o
t
a
l
)

u
g
/
L
500
.
4
.
3
.
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

1
2
9

2
1
1
.
1

1
8
6
.
4

1
2
7
.
1

1
4
7
.
8

2
2
.
4

2
0
.
8

1
2
8
.
4

5
6
.
0

6
7
.
7

6
0
.
7
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1

0
.
0
1
0
8

.

0
.
0
0
5
9

.

0
.
0
0
6
8

0
.
0
0
9
2

0
.
0
0
7
6

0
.
0
0
8
4

0
.
0
0
6
8

.

.
Ba
r
i
u
m
mg
/
l
0.
7

.

0
.
4
5

0
.
2
1

0
.
1
9

0
.
1
9

0
.
2
6

0
.
1
5

0
.
1
9
2.
2
0.
1
3

0
.
2
3
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2

0
.
0
0
2
0

0
.
0
0
1
6

.

.

0
.
0
0
1
9

.

.

.
0.
0
2
4
..
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1

.
0.
0
1
6

0
.
0
1
7
0.
0
0
8

0
.
0
2
1
0.
0
1
5

0
.
0
1
2

0
.
0
1
1

0
.
2
0.
0
0
5
8
0.
0
1
8
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
.
.
.
.
0.
0
6
9
..
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
..
.
.
.
0.
0
0
0
2
1
..
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2
..
.
.
.
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
2
..
.
.
.
.
.
.
0.
0
0
5
7

.

.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
2
d
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

N
o
v
-
1
1

M
a
y
-
1
2

D
e
c
-
1
2

J
u
n
-
1
3

D
e
c
-
1
3

D
e
c
-
1
4

J
u
n
-
1
5
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

4
.
4

3
.
1

3
.
5

4
.
2

4
.
8

3
.
7

4
.
7
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,
0
0
0
..
.
.
.
.
.
Ch
l
o
r
o
m
e
t
h
a
n
e
ug
/
L
3.
.
.
1
.
0
.
.
.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20

1
.
1

.

.

1
.
1

1
.
1

1
.
1

1
.
4
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
.
.
Di
c
h
l
o
r
o
d
i
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
1,
0
0
0
..
.
.
.
.
.
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e

(c
u
m
e
n
e
)

u
g
/
L
701
.
2
.
.
.
.
.
.
p-
I
s
o
p
r
o
p
y
l
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
Me
t
h
y
l
-
t
e
r
t

b
u
t
y
l

e
t
h
e
r
ug
/
L
20
.
0
..
.
.
.
.
.
4-
(
o
-
c
r
e
s
o
l
)

M
e
t
h
y
l
p
h
e
n
o
l
ug
/
L
40
.
.
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
64

4
2

3
9

5
5

3
7

3
4

5
0
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
0
0
0
..
.
.
.
.
.
1,
2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
ug
/
L
400
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
.
.
.
Xy
l
e
n
e
s

(t
o
t
a
l
)

u
g
/
L
500
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

7
0
.
7

4
5
.
1

4
2
.
5

6
1
.
3

4
2
.
9

3
8
.
8

5
6
.
1
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1
..
.
.
.
0.
0
1
4
.
Ba
r
i
u
m
mg
/
l
0.
7

0
.
0
6
5

0
.
2
0

0
.
2
7

0
.
4
5

0
.
4
2

0
.
5
7

0
.
2
7
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
..
.
.
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1

.

0
.
0
0
9
7
0.
0
1
2

0
.
0
1
7

0
.
0
1
2

0
.
0
3
1
.
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
.
0.
0
1
7
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
..
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2
..
.
.
.
.
0.
0
1
2
Si
l
v
e
r
mg
/
l
0.
0
2
..
.
.
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
3
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

A
u
g
-
9
0

M
a
r
-
9
1

A
p
r
-
9
1

M
a
y
-
9
3

O
c
t
-
9
3

A
p
r
-
9
4

F
e
b
-
9
6

A
u
g
-
9
6

A
p
r
-
9
7

N
o
v
-
9
7

O
c
t
-
9
8
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
bi
s
-
(
2
-
e
t
h
y
l
h
e
x
y
l
)

p
h
t
h
a
l
a
t
e
ug
/
L
3.0
.

N
o
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
32
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,8
0
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
di
-
n
-
b
u
t
y
l

p
h
t
h
a
l
a
t
e
ug
/
L
70
0

8

J
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
70
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
cis
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Me
t
h
y
l

I
o
d
i
d
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
4-
(
o
-
c
r
e
s
o
l
)

M
e
t
h
y
l
p
h
e
n
o
l
ug
/
L
3.5

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
.

.

N
A

N
A

N
A

N
A

N
A

N
A
Na
p
h
t
h
a
l
e
n
e
ug
/
L
21

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
N-
N
i
t
r
o
s
o
d
i
p
h
e
n
y
l
a
m
i
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,1
0
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.0
1
5

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

8
.
0
00
0
0
0
0
3
2
0
Me
t
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5

.
No
t

S
a
m
p
l
e
d
NA

.

N
A

.

.

.

0
.
0
0
4

.

.
Ba
r
i
u
m
mg
/
l
2.0

1
.
5
0
No
t

S
a
m
p
l
e
d
1.
4
0
0

0
.
6
6
9

N
A

0
.
8
4
0

0
.
7
0
0

0
.
9
5
0

0
.
7
7
8

0
.
7
4
0

0
.
4
4
0
Ca
d
m
i
u
m
mg
/
l
0.0
0
5

.
No
t

S
a
m
p
l
e
d
NA.
N
A
.
.
.
0.
0
0
6
..
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5

.
No
t

S
a
m
p
l
e
d
0.
0
3
0

.

N
A

.

0
.
0
2
0

.

0
.
0
0
7

0
.
0
1
8

0
.
0
1
8
Le
a
d
mg
/
l
0.0
1
5

.
No
t

S
a
m
p
l
e
d
0.
0
0
6

0
.
0
1
5

N
A

.

.

0
.
0
0
5

.

.

0
.
0
1
1
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
1

.
No
t

S
a
m
p
l
e
d
NA

.

N
A

.

.

0
.
0
0
0
9

0
.
0
0
0
8

.

0
.
0
0
1
1
Se
l
e
n
i
u
m
mg
/
l
0.
0
5

.
No
t

S
a
m
p
l
e
d
NA.
N
A
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.0
1
8

.
No
t

S
a
m
p
l
e
d
NA.
N
A
.
.
.
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wil
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
3
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

M
a
r
-
0
0

S
e
p
-
0
0

M
a
y
-
0
1

D
e
c
-
0
1

J
u
l
-
0
2

J
a
n
-
0
3

M
a
y
-
0
5

M
a
r
-
0
6

M
a
y
-
0
6

N
o
v
-
0
6

J
u
n
-
0
7
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
.
.
.
.
.
.
.
bi
s
-
(
2
-
e
t
h
y
l
h
e
x
y
l
)

p
h
t
h
a
l
a
t
e
ug
/
L
3.0
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,8
0
0
..
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
2
.
0
.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
700
.
.
.
.
.
.
.
.
.
.
.
cis
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
21
.
.
.
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

.
10
..
15

2
4

1
5

5
9

1
5

2
2

1
8
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,1
0
0
..
.
.
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.0
1
5
..
.
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

0

1
0

0

2
.
0

1
5

2
4

1
5

5
9

1
5

2
2

1
8
Me
t
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5

0
.
0
1
1
7
..
.
.
.
0.0
0
7
5

.

.

0
.
0
0
5
2

.
Ba
r
i
u
m
mg
/
l
2.0

0
.
6
0
2

.

0
.
3
2
5

.

0
.
2
9
7

0
.
5
0
5

1
.
5
0

0
.
9
6

0
.
2
7

0
.
8
8

0
.
8
3
Ca
d
m
i
u
m
mg
/
l
0.0
0
5

0
.
0
0
4
1

0
.
0
0
1
5

0
.
0
0
1
3
..
.
.
.
.
0.0
0
4
3

0
.
0
0
3
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5
..
.
.
.
.
0.0
0
7
3

.

0
.
0
0
2
3

0
.
0
1
7

0
.
0
0
7
9
Le
a
d
mg
/
l
0.0
1
5
..
.
.
.
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
1
..
.
.
.
.
.
.
.
.
0.
0
0
0
4
Se
l
e
n
i
u
m
mg
/
l
0.
0
5
..
.
.
.
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.0
1
8
..
.
.
.
.
.
.
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wil
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
3
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

N
o
v
-
0
7

M
a
y
-
0
8

N
o
v
-
0
8

M
a
y
-
0
9

J
u
n
-
1
0

N
o
v
-
1
0

M
a
y
-
1
1

N
o
v
-
1
1

M
a
y
-
1
2

D
e
c
-
1
2

J
u
n
-
1
3
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,0
0
0
..
.
.
.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20
.
.
.
.
.
.
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
.
.
.
.
.
.
.
cis
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
27

3
4

2
8

1
7

1
1

3
1

2
3

2
1

2
3

1
2

2
0
To
l
u
e
n
e
ug
/
L
600
.
.
.
.
.
2
3
0
.
.
.
.
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,0
0
0
..
.
.
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

2
7

3
4

2
8

1
7

1
1

2
6
1

2
3

2
1

2
3

1
2

2
0
Me
t
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1

.

0
.
0
0
7
6

0
.
0
0
6
7
0.0
1
2

0
.
0
1
3

0
.
0
1
5
.

.

0
.
0
0
6
7

.

.
Ba
r
i
u
m
mg
/
l
0.7
1.1

0
.
8
4

0
.
8
2

1
.
2

0
.
7
5

0
.
9
2

0
.
8
4

0
.
7
9
0.6
8
0.
9
0

0
.
9
5
Ca
d
m
i
u
m
mg
/
l
0.0
0
2

.
0.
0
0
5
.

.

.

0
.
0
0
3
9

.

.

0
.
0
0
1
5

.

.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1

0
.
0
0
8
9
0.
0
2
5
.

0
.
0
0
9
3

0
.
0
0
8
0.
0
2
5
0.0
0
7
9
0.0
1
2
..
.
Le
a
d
mg
/
l
0.0
1
5
..
.
.
.
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.0
0
1

0
.
0
0
0
2

.

.

0
.
0
0
0
3

.

0
.
0
0
0
3
3
..
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2

0
.
0
1
3

.

0
.
0
1
6
..
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
2
..
.
.
.
.
.
.
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wil
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
3
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

D
e
c
-
1
3

D
e
c
-
1
4

J
u
n
-
1
5
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0

.

.

.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,0
0
0

.

.

.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
20
0

.

.

.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
cis
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0

.

.

.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
14

2
3

2
2
To
l
u
e
n
e
ug
/
L
60
0

.

.

.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,0
0
0

.

.

.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3

.

.

.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

1
4

2
3

2
2
Me
t
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1

.

.

.
Ba
r
i
u
m
mg
/
l
0.7

0
.
5
6
0.9
6

0
.
8
2
Ca
d
m
i
u
m
mg
/
l
0.0
0
2

.
..
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1

.

0
.
0
0
6
7

0
.
0
0
6
0
Le
a
d
mg
/
l
0.0
1
5

.

.

.
Me
r
c
u
r
y
mg
/
l
0.0
0
1

.

.

.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2

.

.

0
.
0
1
3
Si
l
v
e
r
mg
/
l
0.
0
2

.

.

.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wil
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
3
D
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

M
a
r
-
0
0

S
e
p
-
0
0

M
a
y
-
0
1

D
e
c
-
0
1

J
u
l
-
0
2

J
a
n
-
0
3

M
a
y
-
0
5

M
a
r
-
0
6

M
a
y
-
0
6

N
o
v
-
0
6

J
u
n
-
0
7
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
.
.
.
3
.
0
.
.
.
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,
8
0
0
..
.
.
.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
.

.

.

5
.
0

3
.
0

3
.
0

1
.
8

.

1
.
0

1
.
2

1
.
2
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
700
.
.
.
.
.
.
.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
21
.
.
.
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

9
.
0
27
..
35

1
9
.
54
..
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
1
0
0
..
.
.
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
1
5
..
.
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

9
.
0

2
7

0

8
.
0

3
8

2
2

1
.
8

5
4

1
.
0

1
.
2

1
.
2
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5
..
.
.
.
.
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
2.
0

.

.

0
.
3
4
1

.

.

.

0
.
9
2

0
.
0
7
1

0
.
0
4
2

0
.
1
3

0
.
0
8
4
Ca
d
m
i
u
m
mg
/
l
0.
0
0
5

0
.
0
0
1
7

.

0
.
0
0
1
1
..
.
.
.
.
0.
0
0
1
1

.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5
..
.
.
.
.
.
0.
0
0
3
4

0
.
0
0
2
8

0
.
0
1
0

0
.
0
0
6
7
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
.
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
1
..
.
.
.
.
.
.
.
.
0.
0
0
0
2
6
Se
l
e
n
i
u
m
mg
/
l
0.
0
5

.

.

0
.
0
1
0
2

.

.

.

0
.
0
0
6
9
..
.
.
Si
l
v
e
r
mg
/
l
0.
0
1
8
..
.
.
.
.
.
.
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
3
D

(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

N
o
v
-
0
7

M
a
y
-
0
8

N
o
v
-
0
8

M
a
y
-
0
9

N
o
v
-
0
9

J
u
n
-
1
0

N
o
v
-
1
0

M
a
y
-
1
1

N
o
v
-
1
1

M
a
y
-
1
2

D
e
c
-
1
2
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

2
.
9

1
.
4

1
.
1

.

1
.
1

.

.

.

1
.
1

.

.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,
0
0
0
..
.
.
.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20

2
.
7

1
.
7

1
.
3

1
.
3

1
.
3

1
.
1

1
.
2

1
.
4

1
.
1

1
.
1

1
.
1
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
.
.
.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
20

1
6
..
10

.

1
0
1
1
1
1
..
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
0
0
0
..
.
.
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

2
5
.
6

1
9
.
1

2
.
4

1
.
3

1
2
.
4

1
.
1

1
1
.
2

1
2
.
4

1
3
.
2

1
.
1

1
.
1
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1

.

.

.

0
.
0
0
5
4

.

0
.
0
0
5
6

.

0
.
0
0
5
2

.

.

.
Ba
r
i
u
m
mg
/
l
0.
7

0

0
.
0
6
8

0
.
1
1

0
.
1
4

0
.
1
4

0
.
0
8

0
.
1
5

0
.
1
2

0
.
1
4

0
.
1
3

0
.
1
6
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
..
.
.
.
.
.
.
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1

.

0
.
0
0
5
6

0
.
0
0
7
2

0
.
0
0
9
6
0.
0
1
1
0.
0
0
9
0.
0
1
4

0
.
0
1
4

0
.
0
1
7

0
.
0
1
2

0
.
0
1
5
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
.
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
..
.
.
.
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2
..
.
.
.
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
2
..
.
.
.
.
.
.
.
.
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
3
D

(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

J
u
n
-
1
3

D
e
c
-
1
3

D
e
c
-
1
4

J
u
n
-
1
5
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,
0
0
0
..
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
..
.
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
0
0
0
..
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

0
.
0

0
.
0

0
.
0

0
.
0
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1
..
.
.
Ba
r
i
u
m
mg
/
l
0.
7

0
.
1
4

0
.
1
4

0
.
1
0

0
.
1
4
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
..
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1
0.
0
1
5

0
.
0
1
1

0
.
0
1
1
0.
0
0
7
9
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
..
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2
..
.
.
Si
l
v
e
r
mg
/
l
0.
0
2
..
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
4
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

A
u
g
-
9
0

M
a
r
-
9
1

A
p
r
-
9
1

M
a
y
-
9
3

O
c
t
-
9
3

A
p
r
-
9
4

F
e
b
-
9
6

A
u
g
-
9
6

A
p
r
-
9
7

N
o
v
-
9
7

O
c
t
-
9
8
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
2.0
9

.

.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,8
0
0

9

J
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
70
0

8
.
0
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
cis
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
21

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,1
0
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.0
1
5

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

1
7
.
0
00
0
0
0
2.0
9

0

0
Me
t
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5

.
No
t

S
a
m
p
l
e
d
NA.
N
A
.
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
2.
0

1
.
3
0
0
No
t

S
a
m
p
l
e
d
1.4
0
0

0
.
7
0
4

N
A

.

0
.
7
0
0

1
.
0
0
0

0
.
7
0
6

0
.
8
4
0

0
.
8
3
0
Ca
d
m
i
u
m
mg
/
l
0.0
0
5

.
No
t

S
a
m
p
l
e
d
NA

.

N
A
1.
0
.

.

0
.
0
0
2

.

.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5

0
.
1
1
0
No
t

S
a
m
p
l
e
d
0.1
1
0

.

N
A
..
.
.
.
.
Le
a
d
mg
/
l
0.0
1
5

0
.
0
1
0
No
t

S
a
m
p
l
e
d
0.0
0
6

0
.
0
1
8

N
A
..
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
1

.
No
t

S
a
m
p
l
e
d
NA.
N
A
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
5

.
No
t

S
a
m
p
l
e
d
NA.
N
A
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.0
1
8

.
No
t

S
a
m
p
l
e
d
NA.
N
A
.
.
.
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
4
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

M
a
r
-
0
0

S
e
p
-
0
0

M
a
y
-
0
1

D
e
c
-
0
1

J
u
l
-
0
2

J
a
n
-
0
3

M
a
y
-
0
5

M
a
r
-
0
6

M
a
y
-
0
6

N
o
v
-
0
6

J
u
n
-
0
7
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
.
1
.
0
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

.

.

.

1
.
0

1
.
0

2
.
0

.

1
.
1

1
.
3

1
.
5

1
.
4
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,8
0
0

.

.

.

2
.
0

1
.
0
..
.
.
.
.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
N
A
N
A
N
A
N
A
N
A
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
2
.
0
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
700
.
.
.
.
.
.
.
.
.
.
.
cis
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
21
.
.
.
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

.
16
..
24

2
0

1
8

6
0

1
6

1
7
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,1
0
0
..
.
.
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.0
1
5
..
.
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

0

1
6

0

3
.
0

2
6

2
5

1
8

6
1
.
1

1
7
.
3

1
8
.
5

1
.
4
Me
t
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5
..
.
.
.
.
0.0
0
6
0
..
.
.
Ba
r
i
u
m
mg
/
l
2.
0

0
.
7
6
1

0
.
7
5
2

0
.
6
8
5

0
.
7
9
7

0
.
7
7
0

0
.
7
4
1

0
.
0
7
9

0
.
8
4

0
.
7
1

0
.
7
6

0
.
7
0
Ca
d
m
i
u
m
mg
/
l
0.0
0
5

0
.
0
0
2
1

0
.
0
0
1
5

0
.
0
0
1
7
..
.
.
.
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5
..
.
.
.
.
.
.
.
0.0
1
1

.
Le
a
d
mg
/
l
0.0
1
5
..
.
.
.
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
1
..
.
.
.
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
5
..
.
.
.
.
.
0.
0
0
7
4

0
.
0
0
6
1

.

.
Si
l
v
e
r
mg
/
l
0.0
1
8

.

.

0
.
0
1
3
4
..
.
.
.
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
4
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

N
o
v
-
0
7

M
a
y
-
0
8

N
o
v
-
0
8

M
a
y
-
0
9

J
u
n
-
1
0

N
o
v
-
1
0

M
a
y
-
1
1

N
o
v
-
1
1

M
a
y
-
1
2

D
e
c
-
1
2

J
u
n
-
1
3
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

.

1
.
5

1
.
2

1
.
4

1
.
3

1
.
5

1
.
5

1
.
9

.

1
.
5

1
.
5
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,0
0
0
..
.
.
.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20
.
.
.
.
.
.
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
61.
0
.
.
.
.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
.
.
.
.
.
.
.
cis
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
18

2
2

2
0

1
7

1
6

1
7

1
9

2
1
..
20
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,0
0
0
..
.
.
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

1
9

2
3
.
5

2
1
.
2

1
8
.
4

1
7
.
3

1
8
.
5

2
0
.
5

2
2
.
9

0
.
0

1
.
5

2
1
.
5
Me
t
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1

.

.

.

0
.
0
0
9
0

0
.
0
1
3

0
.
0
0
5
3
..
.
.
.
Ba
r
i
u
m
mg
/
l
0.
7
0.
7
7

0
.
7
8
0.
6
6
0.7
8

0
.
9
5

0
.
8
3

0
.
7
5

0
.
8
2

0
.
7
2

0
.
8
6

0
.
8
1
Ca
d
m
i
u
m
mg
/
l
0.0
0
2
..
.
.
0.0
0
1
3
..
.
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1

0
.
0
2
0.
0
1
6
0.
0
0
5
9

.
0.0
1
6
0.
0
0
5
4

0
.
0
0
6
1

0
.
0
0
7
7

0
.
0
0
5
6

0
.
0
0
7
7

0
.
0
0
6
8
Le
a
d
mg
/
l
0.0
1
5
..
.
.
.
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.0
0
1
..
.
.
.
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2
..
.
.
.
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
2
..
.
.
.
.
.
0.
0
0
5
0

.

.

.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
4
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

D
e
c
-
1
3

D
e
c
-
1
4

J
u
n
-
1
5
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.
0

.

.

.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

1
.
5

1
.
6

1
.
6
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,0
0
0

.

.

.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
20
0

.

.

.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
cis
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.
0

.

.

.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
25

1
4

1
6
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,0
0
0

.

.

.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3

.

.

.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

2
7

1
5
.
6

1
7
.
6
Me
t
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1

.

.

.
Ba
r
i
u
m
mg
/
l
0.
7
0.
8
2

0
.
8
4

0
.
7
9
Ca
d
m
i
u
m
mg
/
l
0.0
0
2

.

.

.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1

0
.
0
0
6
4
0.
0
1
1
.
Le
a
d
mg
/
l
0.0
1
5

.

.

.
Me
r
c
u
r
y
mg
/
l
0.0
0
1

.

.

.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2

.

.

0
.
0
1
8
Si
l
v
e
r
mg
/
l
0.
0
2

.

.

.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
4
D
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

M
a
r
-
0
0

S
e
p
-
0
0

M
a
y
-
0
1

D
e
c
-
0
1

J
u
l
-
0
2

J
a
n
-
0
3

M
a
y
-
0
5

M
a
r
-
0
6

M
a
y
-
0
6

N
o
v
-
0
6

J
u
n
-
0
7
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,
8
0
0
..
.
.
.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
700
.
.
.
.
.
1
.
0
.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
1
.
0
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
-
t
e
r
t
-
b
u
t
y
l

e
t
h
e
r
ug
/
L
200
.
.
.
.
.
.
1
.
0
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
21
.
.
.
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

7
.
0
20
..
33

2
3

1
3

6
1
.
13
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
1
0
0
..
.
.
2
.
0
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
1
5
..
.
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

7
.
0

2
0

0

0

3
5

2
5

1
4

6
1

0

1
3

0
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5
..
.
.
.
.
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
2.0
.
.
.
.
.
.
0.
0
6
6

0
.
0
4
8

0
.
0
3
5

0
.
0
2
6

0
.
0
2
0
Ca
d
m
i
u
m
mg
/
l
0.
0
0
5

0
.
0
0
1
5

0
.
0
0
1
1
..
.
.
.
.
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5
..
.
.
.
.
0.
0
1
5
..
.
.
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
.
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
1
..
.
.
.
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
5

.

.

0
.
0
1
1
9
..
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
1
8
..
.
.
.
.
.
.
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
4
D

(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

N
o
v
-
0
7

M
a
y
-
0
8

N
o
v
-
0
8

M
a
y
-
0
9

N
o
v
-
0
9

J
u
n
-
1
0

N
o
v
-
1
0

M
a
y
-
1
1

N
o
v
-
1
1

M
a
y
-
1
2

D
e
c
-
1
2
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
.
.
.
.
.
.
.
Br
o
m
o
m
e
t
h
a
n
e
ug
/
L
NSE
.
.
.
.
.
.
3
.
1
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
.
.
.
.
.
.
.
.
.
1
.
4
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,
0
0
0
..
.
.
.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20
.
.
.
.
.
.
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
.
.
.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
1
.
0
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
-
t
e
r
t
-
b
u
t
y
l

e
t
h
e
r
ug
/
L
20
.
.
.
.
.
.
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

.
15
..
.
.
.
.
.
17

.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
0
0
0
..
.
.
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

0

1
6
00
0
0
3
.
1
0
0
18
.
4

0
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1

.

.

.

0
.
0
0
5
4
..
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
0.
7

0
.
0
4
6

0
.
0
3
8

0
.
0
3
1

0
.
0
4
2

0
.
0
4
1

0
.
0
3
7

0
.
0
3
8

0
.
0
3
3

0
.
0
5
7

0
.
0
2
9

0
.
0
3
2
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
..
.
.
.
.
.
.
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1
..
.
.
.
.
.
.
.
.
.
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
.
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
..
.
.
.
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2
..
.
.
.
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
2
..
.
.
.
.
.
.
.
.
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
4
D

(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

J
u
n
-
1
3

D
e
c
-
1
3

D
e
c
-
1
4

J
u
n
-
1
5
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
Br
o
m
o
m
e
t
h
a
n
e
ug
/
L
NSE
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,
0
0
0
..
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
Me
t
h
y
l
-
t
e
r
t
-
b
u
t
y
l

e
t
h
e
r
ug
/
L
20
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
..
.
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
0
0
0
..
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-
00
0
0
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1
..
.
.
Ba
r
i
u
m
mg
/
l
0.
7

0
.
0
3
5

0
.
0
3
1

0
.
0
3
0

0
.
0
2
9
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
..
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1
..
.
.
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
..
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2
..
.
.
Si
l
v
e
r
mg
/
l
0.
0
2
..
.
.
NS
E
-

N
o

S
t
a
n
d
a
r
d

E
x
i
s
t
s
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
5
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

A
u
g
-
9
0

M
a
r
-
9
1

A
p
r
-
9
1

M
a
y
-
9
3

O
c
t
-
9
3

A
p
r
-
9
4

F
e
b
-
9
6

A
u
g
-
9
6

A
p
r
-
9
7

N
o
v
-
9
7

O
c
t
-
9
8
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0

.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
bis
-
(
2
-
e
t
h
y
l
h
e
x
y
l
)

p
h
t
h
a
l
a
t
e
ug
/
L
3.0
.

N
o
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,
0
0
0

.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
di-
n
-
b
u
t
y
l

p
h
t
h
a
l
a
t
e
ug
/
L
70
0

6

J
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
70
0

.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
cis
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70

.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0

.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Me
t
h
y
l

I
o
d
i
d
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
4-
(
o
-
c
r
e
s
o
l
)

M
e
t
h
y
l
p
h
e
n
o
l
ug
/
L
3.5

.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
.

.

N
A

N
A

N
A

N
A

N
A

N
A
Na
p
h
t
h
a
l
e
n
e
ug
/
L
21

.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
N-
N
i
t
r
o
s
o
d
i
p
h
e
n
y
l
a
m
i
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.6
*

.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Tri
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
1
0
0

.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
1
5

.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

6
.
0
00
0
0
0
0
0
0
Me
t
a
l
s

(to
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.0
1

.
Not

S
a
m
p
l
e
d
NA.
.
.
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
0.7

0
.
4
6
0
Not

S
a
m
p
l
e
d
0.4
9
0

0
.
1
2
8

N
A

.

0
.
3
0
0

0
.
0
5
6

0
.
1
9
1

1
.
0

1
.
1
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2

.
Not

S
a
m
p
l
e
d
NA

0
.
0
3
6

N
A

.

.

.

0
.
0
0
2

.

.
Ch
r
o
m
i
u
m
mg
/
l
0.0
1

0
.
0
5
0
Not

S
a
m
p
l
e
d
0.0
9
0
.

N
A

.

0
.
0
2
0

.

0
.
0
2
1
0.1
8
0

0
.
1
9
0
Le
a
d
mg
/
l
0.
0
1
5

0
.
0
0
9
Not

S
a
m
p
l
e
d
0.0
1
1
0.0
1
7
NA

.

.

.

0
.
0
0
4
0.0
3
9

0
.
0
3
5
Me
r
c
u
r
y
mg
/
l
0.
0
0
1

.
Not

S
a
m
p
l
e
d
NA.
N
A
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.0
2

.
Not

S
a
m
p
l
e
d
NA.
N
A
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.0
2

.
Not

S
a
m
p
l
e
d
NA

0
.
0
0
6

N
A

.

.

.

0
.
0
0
4

.

.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
* -

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bla
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wil
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
7
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

M
a
r
-
9
1

A
p
r
-
9
1

M
a
r
-
0
0

S
e
p
-
0
0

M
a
y
-
0
1

D
e
c
-
0
1

J
u
l
-
0
2

J
a
n
-
0
3

M
a
y
-
0
5

M
a
r
-
0
6

M
a
y
-
0
6
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.
0

N
A

N
A

.

.

.

.

.

.

.

.

.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

.

N
A

.

.

.

.

.

.

.

.

.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,
8
0
0

.

N
A

.

.

.

.

.

.

.

.

.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
.N
A
.

.

.

.

.

.

.

.

.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.N
A
.

.

.

.

.

.

.

.

.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
.N
A
.

.

.

.

.

.

.

.

.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
70
0

.

N
A

.

.

.

.

.

.

.

.

.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70

.

N
A

.

.

.

.

.

.

.

.

.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.
0

.

N
A

.

.

.

.

.

.

.

.

.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
21

N
A

N
A

.

.

.

.

.

.

.

.

.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

.

N
A

.

.

.

.

.

.

.

.

.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
1
0
0

.

N
A

.

.

.

.

.

.

.

.

.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
1
5

N
A

N
A

.

.

.

.

.

.

.

.

.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

0

0

0

0

0

0

0

0

0

0
Me
t
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5

N
A

N
A

.

.

.

.

.

.

.

.

.
Ba
r
i
u
m
mg
/
l
2.
0

.

0
.
1
2
0

.

.

.

.

.

.

0
.
0
4
5

0
.
0
8
1

0
.
0
5
4
Ca
d
m
i
u
m
mg
/
l
0.
0
0
5

N
A

N
A

.

.

0
.
0
0
1

.

.

.

.

.

.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5

.

.

.

.

0
.
0
1
5
3

0
.
0
1
9

.

.

.

0
.
0
1
9

0
.
0
1
2
Le
a
d
mg
/
l
0.
0
1
5

.

.

.

.

.

.

.

.

.

.

.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
1

N
A

N
A

.

.

.

.

.

.

.

.

.
Se
l
e
n
i
u
m
mg
/
l
0.
0
5

N
A

N
A

.

.

.

.

.

.

.

.

.
Si
l
v
e
r
mg
/
l
0.
0
1
8

N
A

N
A

.

.

.

.

.

.

.

.

.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
7

(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

N
o
v
-
0
6

J
u
n
-
0
7

N
o
v
-
0
7

M
a
y
-
0
8

N
o
v
-
0
8

M
a
y
-
0
9

N
o
v
-
0
9

J
u
n
-
1
0

N
o
v
-
1
0

M
a
y
-
1
1

N
o
v
-
1
1
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.
0

.

.

.

.

.

.

.

.

.

.

.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

.

.

.

.

.

.

.

.

.

.

.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,
8
0
0

.

.

.

.

.

.

.

.

.

.

.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20

.

.

.

.

.

.

.

.

.

.

.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
20
0

.

.

.

.

.

.

.

.

.

.

.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
.
.
.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70

.

.

.

.

.

.

.

.

.

.

.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.
0

.

.

.

.

.

.

.

.

.

.

.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

.

.

.

.

.

.

.

.

.

.

.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
0
0
0

.

.

.

.

.

.

.

.

.

.

.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3

.

.

.

.

.

.

.

.

.

.

.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

0

0

0

0

0

0

0

0

0

0

0
Me
t
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1

.

.

.

.

.

.

.

.

.

.

.
Ba
r
i
u
m
mg
/
l
0.
7

0
.
1
4

0
.
1
2

0
.
2
9

0
.
3
3

0
.
2
0

0
.
2
2

0
.
3
6

0
.
2
3

0
.
2
4

0
.
1
5
0.
9
2
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2

.

.

.

0
.
0
0
1
2

.

.

.

.

.

.

.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1
0.
0
5
6
0.
0
4
3
0.
2
1

0
.
2
5

0
.
0
7
5

0
.
1
3

0
.
1
7

0
.
1
5

0
.
1
4

0
.
0
9
2

0
.
5
7
Le
a
d
mg
/
l
0.
0
1
5

.

.

.

.

.

.

.

.

.

.

.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1

.

.

.

.

.

.

.

.

.

.

.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2

.

.

.

.

.

.

.

.

.

.

0
.
0
1
4
Si
l
v
e
r
mg
/
l
0.
0
2

.

.

.

.

.

.

.

.

.

.

.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
7

(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

M
a
y
-
1
2

D
e
c
-
1
2

J
u
n
-
1
3

D
e
c
-
1
3

D
e
c
-
1
4

J
u
n
-
1
5
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.
0

.

.

.

.

.

.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

.

.

.

.

.

.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,
8
0
0

.

.

.

.

.

.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20

.

.

.

.

.

.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
20
0

.

.

.

.

.

.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70

.

.

.

.

.

.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.
0

.

.

.

.

.

.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

.

.

.

.

.

.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
0
0
0

.

.

.

.

.

.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3

.

.

.

.

.

.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

0

0

0

0

0

0
Me
t
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1

.

.

.

.

.

.
Ba
r
i
u
m
mg
/
l
0.
7

0
.
4
2

0
.
6
1

0
.
5
6

0
.
5
8

0
.
8
6

0
.
2
9
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2

0
.
0
0
1
3

.

.

.

.

.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1
0.
2
3

0
.
2
2

0
.
3
7

0
.
2
1

0
.
5
7

0
.
0
7
2
Le
a
d
mg
/
l
0.
0
1
5

.

.

.

.

0
.
0
1
3

.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1

.

.

.

.

.

.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2

.

.

.

.

.

.
Si
l
v
e
r
mg
/
l
0.
0
2

.

.

.

.

.

.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

1
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
8
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

O
c
t
-
1
3

D
e
c
-
1
3

D
e
c
-
1
4

J
u
n
-
1
5
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.
0

.

.

.

.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

.

.

.

.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,
8
0
0

.

.

.

.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20

.

.

.

.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
20
0

.

.

.

.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70

.

.

.

.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.
0

.

.

.

.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

.

.

.

.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
0
0
0

.

.

.

.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3

.

.

.

.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

0

0

0

0
Me
t
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1
0.
0
2
3
..
.
Ba
r
i
u
m
mg
/
l
0.
7
1.
4

2
.
0

1
.
8
0.
3
7
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
0.
0
0
3
3

0
.
0
0
4
3
.
0.
0
0
6
7
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1
0.
4
5

0
.
5
5

0
.
4
6

0
.
0
1
2
Le
a
d
mg
/
l
0.
0
1
5
0.
0
3
6

0
.
0
3
6

0
.
0
3
5
0.
0
0
7
3
Me
r
c
u
r
y
mg
/
l
0.
0
0
1

.

.

.

.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2

.

.

.

.
Si
l
v
e
r
mg
/
l
0.
0
2

.

.
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

1
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
9
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

O
c
t
-
1
3

D
e
c
-
1
3

D
e
c
-
1
4

J
u
n
-
1
5
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.
0

.

.

.

.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

.

.

1
.
4

.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,
8
0
0

.

.

.

.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20

.

.

.

.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
20
0

.

.

.

.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70

.

.

.

.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.
0

.

.

.

.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

.

.
19
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
0
0
0

.

.

.

.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3

.

.

.

.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

0

0

2
0
.
4

0
Me
t
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1

.

.

.

.
Ba
r
i
u
m
mg
/
l
0.
7
0.
7
4
0.
3
8

0
.
4
1
1.
0
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
0.
0
1
1

0
.
0
0
3
2

0
.
0
0
3
3
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1
0.
0
3

0
.
0
1
6

0
.
0
1
5

0
.
0
2
8
Le
a
d
mg
/
l
0.
0
1
5

.

.

0
.
0
0
7

0
.
0
0
8
6
Me
r
c
u
r
y
mg
/
l
0.
0
0
1

.

.

.

.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2

.

.

.

.
Si
l
v
e
r
mg
/
l
0.
0
2

.

.

.

.
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

S
u
r
f
a
c
e

W
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

SW
-
1

(
u
p
s
t
r
e
a
m
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
B

S
t
a
n
d
a
r
d

M
a
r
-
0
0

S
e
p
-
0
0

M
a
y
-
0
1

D
e
c
-
0
1

J
u
l
-
0
2

J
a
n
-
0
3

M
a
y
-
0
5

M
a
r
-
0
6

M
a
y
-
0
6

N
o
v
-
0
6

J
u
n
-
0
7
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
488
.
.
.
.
d
r
y
.
.
.
.
.
.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
d
r
y
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
4
9
0
3
*
..
.
.
d
r
y
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-
00
0
0

0
0
0
0
0
0
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5
..
.
.
d
r
y
.
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
1.0
.
.
.
.
d
r
y
.
0.
0
8
3

0
.
0
7
7

0
.
0
4
2

0
.
1
8
0

0
.
1
1
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2

.

0
.
0
0
1
6

0
.
0
0
1
1

.

d
r
y
..
.
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5
..
.
.
d
r
y
.
.
.
.
.
.
Le
a
d
mg
/
l
0.
0
2
5
..
.
.
d
r
y
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
0
0
1
2
..
.
.
d
r
y
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
0
5
..
.
.
d
r
y
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
0
0
0
6
..
.
.
d
r
y
.
.
.
.
.
.
SW
-
1

(
u
p
s
t
r
e
a
m

c
o
n
t
.
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
B

S
t
a
n
d
a
r
d

N
o
v
-
0
7

M
a
y
-
0
8

N
o
v
-
0
8

M
a
y
-
0
9

N
o
v
-
0
9

J
u
n
-
1
0

N
o
v
-
1
0

M
a
y
-
1
1

N
o
v
-
1
1

M
a
y
-
1
2

D
e
c
-
1
2
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
488
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
4
9
0
3
*
..
.
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-
00
0
0
0
0
0
0
0
0
0
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5
..
.
.
.
.
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
1.
0

0
.
1
1

0
.
1
2

0
.
0
8
5

0
.
0
9
9

0
.
1
5

0
.
0
7
9

0
.
0
7
3

0
.
0
5
4

0
.
0
8
6

0
.
2
8

0
.
0
6
0
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
..
.
.
.
.
.
.
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5
..
.
.
.
.
0.
0
0
7
5
..
.
.
Le
a
d
mg
/
l
0.
0
2
5
..
.
.
.
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
0
0
1
2
..
.
.
.
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
0
5
..
.
.
.
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
0
0
0
6
..
.
.
.
.
.
.
.
.
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

S
u
r
f
a
c
e

W
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

SW
-
1

(
u
p
s
t
r
e
a
m

c
o
n
t
.
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
B

S
t
a
n
d
a
r
d

J
u
n
-
1
3

D
e
c
-
1
3

D
e
c
-
1
4

J
u
n
-
1
5
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
488
.
.
.
.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
4
9
0
3
*
..
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-
00
0
0
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5
..
.
.
Ba
r
i
u
m
mg
/
l
1.
0

0
.
1
1

0
.
1
4

0
.
0
5
9

0
.
1
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
..
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5
..
.
.
Le
a
d
mg
/
l
0.
0
2
5
..
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
0
0
1
2
..
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
0
5
..
.
.
Si
l
v
e
r
mg
/
l
0.
0
0
0
0
6
..
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
2B

-

S
t
a
n
d
a
r
d

f
o
r

C
l
a
s
s

C

S
u
r
f
a
c
e

W
a
t
e
r
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

S
u
r
f
a
c
e

W
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

SW
-
2

(
d
o
w
n
g
r
a
d
i
e
n
t
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
B

S
t
a
n
d
a
r
d

M
a
r
-
0
0

S
e
p
-
0
0

M
a
y
-
0
1

D
e
c
-
0
1

J
u
l
-
0
2

J
a
n
-
0
3

M
a
y
-
0
5

M
a
r
-
0
6

M
a
y
-
0
6

N
o
v
-
0
6

J
u
n
-
0
7
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
488
.
.
.
1
.
0
d
r
y
2
.
0
.
.
.
.
1
.
3
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
1
.
0
d
r
y
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
4
9
0
3
*

.
6.
0
.

.

d
r
y
8.
0
..
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

0

6
.
0

0

2
.
0

1
0
00
0
0
1
.
3
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5
..
.
.
d
r
y
.
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
1.
0

.

.

0
.
1
5
0

.

d
r
y

0
.
1
1
6

0
.
0
7
7

0
.
3
3

0
.
1
0

0
.
1
1

0
.
3
0
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
..
.
.
d
r
y
.
.
.
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5
..
.
.
d
r
y
.
0.
0
0
2
6
..
.
.
Le
a
d
mg
/
l
0.
0
2
5
..
.
.
d
r
y
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
0
0
1
2
..
.
.
d
r
y
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
0
5

.

.
0.
0
1
4
8
.dr
y
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
0
0
0
6
..
.
.
d
r
y
.
0.
0
0
2
6
..
.
.
SW
-
2

(
d
o
w
n
g
r
a
d
i
e
n
t

c
o
n
t
.
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
B

S
t
a
n
d
a
r
d

N
o
v
-
0
7

M
a
y
-
0
8

N
o
v
-
0
8

M
a
y
-
0
9

N
o
v
-
0
9

J
u
n
-
1
0

N
o
v
-
1
0

M
a
y
-
1
1

N
o
v
-
1
1

M
a
y
-
1
2

D
e
c
-
1
2
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
488
.
.
1
.
1
.
.
.
.
.
.
.
.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
4
9
0
3
*
..
.
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

0

0

1
.
1
00
0
0
0
0
0
0
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5
..
.
.
.
.
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
1.
0

0
.
1
0

0
.
1
2

0
.
1
5

0
.
1
2

0
.
1
6

0
.
1
1

0
.
0
9
5

0
.
0
9
6

0
.
1
8

0
.
0
7
9

0
.
1
2
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
..
.
.
.
.
.
.
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5
..
.
.
.
.
.
.
.
.
.
Le
a
d
mg
/
l
0.
0
2
5
..
.
.
.
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
0
0
1
2
..
.
.
.
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
0
5
..
.
.
.
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
0
0
0
6
..
.
.
.
.
.
.
.
.
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

S
u
r
f
a
c
e

W
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

SW
-
2

(
d
o
w
n
g
r
a
d
i
e
n
t

c
o
n
t
.
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
B

S
t
a
n
d
a
r
d

J
u
n
-
1
3

D
e
c
-
1
3

D
e
c
-
1
4

J
u
n
-
1
5
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
48
8

.

.

1
.
0

.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
4
9
0
3
*
..
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-
00
1
0
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5
..
.
.
Ba
r
i
u
m
mg
/
l
1.
0

0
.
1
6

0
.
0
9
9

0
.
1
5

0
.
1
1
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
..
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5
..
.
.
Le
a
d
mg
/
l
0.
0
2
5
..
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
0
0
1
2
..
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
0
5
..
.
.
Si
l
v
e
r
mg
/
l
0.
0
0
0
0
6
..
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
2B

-

S
t
a
n
d
a
r
d

f
o
r

C
l
a
s
s

C

S
u
r
f
a
c
e

W
a
t
e
r
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s

Appendix A
#=CL#
July 02, 2015
LIMS USE: FR - PHIL RAHN
LIMS OBJECT ID: 92255880
92255880
Project:
Pace Project No.:
RE:
Mr. Phil Rahn
Waters Edge Environmental
4901 Water's Edge Drive
Suite 201
Raleigh, NC 27606
WILEY DAVIS LANDFILL R5-34
Dear Mr. Rahn:
Enclosed are the analytical results for sample(s) received by the laboratory on June 24, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Terri Page
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 1 of 40
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 2 of 40
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Lab ID Sample ID Matrix Date Collected Date Received
92255880001 WD-1 Water 06/24/15 14:30 06/24/15 15:40
92255880002 WD-2 Water 06/24/15 13:30 06/24/15 15:40
92255880003 WD-2D Water 06/24/15 14:00 06/24/15 15:40
92255880004 WD-3 Water 06/24/15 13:00 06/24/15 15:40
92255880005 WD-3D Water 06/24/15 12:45 06/24/15 15:40
92255880006 WD-4 Water 06/24/15 11:30 06/24/15 15:40
92255880007 WD-4D Water 06/24/15 11:00 06/24/15 15:40
92255880008 WD-5 Water 06/24/15 15:00 06/24/15 15:40
92255880009 WD-6 Water 06/24/15 15:30 06/24/15 15:40
92255880010 WD-7 Water 06/24/15 10:30 06/24/15 15:40
92255880011 SS1-UPGRADIENT Water 06/24/15 12:00 06/24/15 15:40
92255880012 SS-2 DOWNGRADIENT Water 06/24/15 12:15 06/24/15 15:40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 3 of 40
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92255880001 WD-1 EPA 6010 7 PASI-AJMW
EPA 7470 1 PASI-ASH1
EPA 8260 65 PASI-CSNP
92255880002 WD-2 EPA 6010 7 PASI-AJMW
EPA 7470 1 PASI-ASH1
EPA 8260 65 PASI-CSNP
92255880003 WD-2D EPA 6010 7 PASI-AJMW
EPA 7470 1 PASI-ASH1
EPA 8260 65 PASI-CSNP
92255880004 WD-3 EPA 6010 7 PASI-AJMW
EPA 7470 1 PASI-ASH1
EPA 8260 65 PASI-CSNP
92255880005 WD-3D EPA 6010 7 PASI-AJMW
EPA 7470 1 PASI-ASH1
EPA 8260 65 PASI-CSNP
92255880006 WD-4 EPA 6010 7 PASI-AJMW
EPA 7470 1 PASI-ASH1
EPA 8260 65 PASI-CSNP
92255880007 WD-4D EPA 6010 7 PASI-AJMW
EPA 7470 1 PASI-ASH1
EPA 8260 65 PASI-CSNP
92255880008 WD-5 EPA 6010 7 PASI-AJMW
EPA 7470 1 PASI-ASH1
EPA 8260 65 PASI-CSNP
92255880009 WD-6 EPA 6010 7 PASI-AJMW
EPA 7470 1 PASI-ASH1
EPA 8260 65 PASI-CSNP
92255880010 WD-7 EPA 6010 7 PASI-AJMW
EPA 7470 1 PASI-ASH1
EPA 8260 65 PASI-CSNP
92255880011 SS1-UPGRADIENT EPA 6010 7 PASI-AJMW
EPA 7470 1 PASI-ASH1
EPA 8260 65 PASI-CSNP
92255880012 SS-2 DOWNGRADIENT EPA 6010 7 PASI-AJMW
EPA 7470 1 PASI-ASH1
EPA 8260 65 PASI-CSNP
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 4 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Sample:WD-1 Lab ID:92255880001 Collected:06/24/15 14:30 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP
Arsenic ND mg/L 06/29/15 20:00 7440-38-206/26/15 19:150.010 0.0050 1
Barium 0.44 mg/L 06/29/15 20:00 7440-39-306/26/15 19:150.0050 0.0025 1
Cadmium ND mg/L 06/29/15 20:00 7440-43-906/26/15 19:150.0010 0.000050 1
Chromium 0.010 mg/L 06/29/15 20:00 7440-47-306/26/15 19:150.0050 0.0025 1
Lead ND mg/L 06/29/15 20:00 7439-92-106/26/15 19:150.0050 0.0025 1
Selenium ND mg/L 06/29/15 20:00 7782-49-206/26/15 19:150.010 0.0050 1
Silver ND mg/L 06/29/15 20:00 7440-22-406/26/15 19:150.0050 0.0025 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND mg/L 07/02/15 12:49 7439-97-606/30/15 17:450.00020 0.00010 1
Analytical Method: EPA 82608260 MSV Low Level
Benzene ND mg/L 06/26/15 13:05 71-43-20.0010 0.00025 1
Bromobenzene ND mg/L 06/26/15 13:05 108-86-10.0010 0.00030 1
Bromochloromethane ND mg/L 06/26/15 13:05 74-97-50.0010 0.00017 1
Bromodichloromethane ND mg/L 06/26/15 13:05 75-27-40.0010 0.00018 1
Bromoform ND mg/L 06/26/15 13:05 75-25-20.0010 0.00026 1
Bromomethane ND mg/L 06/26/15 13:05 74-83-90.0020 0.00029 1
n-Butylbenzene ND mg/L 06/26/15 13:05 104-51-80.0010 0.00041 1
sec-Butylbenzene ND mg/L 06/26/15 13:05 135-98-80.0010 0.00038 1
tert-Butylbenzene ND mg/L 06/26/15 13:05 98-06-60.0010 0.00040 1
Carbon tetrachloride ND mg/L 06/26/15 13:05 56-23-50.0010 0.00025 1
Chlorobenzene ND mg/L 06/26/15 13:05 108-90-70.0010 0.00023 1
Chloroethane ND mg/L 06/26/15 13:05 75-00-30.0010 0.00054 1
Chloroform ND mg/L 06/26/15 13:05 67-66-30.0010 0.00014 1
Chloromethane ND mg/L 06/26/15 13:05 74-87-30.0010 0.00011 1
2-Chlorotoluene ND mg/L 06/26/15 13:05 95-49-80.0010 0.00035 1
4-Chlorotoluene ND mg/L 06/26/15 13:05 106-43-40.0010 0.00031 1
Dibromochloromethane ND mg/L 06/26/15 13:05 124-48-10.0010 0.00021 1
1,2-Dibromoethane (EDB)ND mg/L 06/26/15 13:05 106-93-40.0010 0.00027 1
Dibromomethane ND mg/L 06/26/15 13:05 74-95-30.0010 0.00021 1
1,2-Dichlorobenzene ND mg/L 06/26/15 13:05 95-50-10.0010 0.00030 1
1,3-Dichlorobenzene ND mg/L 06/26/15 13:05 541-73-10.0010 0.00024 1
1,4-Dichlorobenzene ND mg/L 06/26/15 13:05 106-46-70.0010 0.00033 1
Dichlorodifluoromethane ND mg/L 06/26/15 13:05 75-71-8 M10.0010 0.00021 1
1,1-Dichloroethane ND mg/L 06/26/15 13:05 75-34-30.0010 0.00032 1
1,2-Dichloroethane ND mg/L 06/26/15 13:05 107-06-20.0010 0.00012 1
1,2-Dichloroethene (Total)ND mg/L 06/26/15 13:05 540-59-00.0010 0.00049 1
1,1-Dichloroethene ND mg/L 06/26/15 13:05 75-35-40.0010 0.00056 1
cis-1,2-Dichloroethene ND mg/L 06/26/15 13:05 156-59-20.0010 0.00019 1
trans-1,2-Dichloroethene ND mg/L 06/26/15 13:05 156-60-50.0010 0.00049 1
1,2-Dichloropropane ND mg/L 06/26/15 13:05 78-87-50.0010 0.00027 1
1,3-Dichloropropane ND mg/L 06/26/15 13:05 142-28-90.0010 0.00028 1
2,2-Dichloropropane ND mg/L 06/26/15 13:05 594-20-70.0010 0.00013 1
1,1-Dichloropropene ND mg/L 06/26/15 13:05 563-58-60.0010 0.00049 1
Diisopropyl ether ND mg/L 06/26/15 13:05 108-20-30.0010 0.00012 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 5 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Sample:WD-1 Lab ID:92255880001 Collected:06/24/15 14:30 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Ethylbenzene ND mg/L 06/26/15 13:05 100-41-40.0010 0.00030 1
Hexachloro-1,3-butadiene ND mg/L 06/26/15 13:05 87-68-30.0010 0.00071 1
Isopropylbenzene (Cumene)ND mg/L 06/26/15 13:05 98-82-80.0010 0.00040 1
p-Isopropyltoluene ND mg/L 06/26/15 13:05 99-87-60.0010 0.00031 1
Methylene Chloride ND mg/L 06/26/15 13:05 75-09-20.0020 0.00097 1
Methyl-tert-butyl ether ND mg/L 06/26/15 13:05 1634-04-40.0010 0.00021 1
Naphthalene ND mg/L 06/26/15 13:05 91-20-30.0010 0.00024 1
n-Propylbenzene ND mg/L 06/26/15 13:05 103-65-10.0010 0.00042 1
Styrene ND mg/L 06/26/15 13:05 100-42-50.0010 0.00026 1
1,1,1,2-Tetrachloroethane ND mg/L 06/26/15 13:05 630-20-60.0010 0.00033 1
1,1,2,2-Tetrachloroethane ND mg/L 06/26/15 13:05 79-34-50.0010 0.00040 1
Tetrachloroethene ND mg/L 06/26/15 13:05 127-18-40.0010 0.00046 1
Tetrahydrofuran ND mg/L 06/26/15 13:05 109-99-90.010 0.0031 1
Toluene ND mg/L 06/26/15 13:05 108-88-30.0010 0.00026 1
1,2,3-Trichlorobenzene ND mg/L 06/26/15 13:05 87-61-60.0010 0.00033 1
1,2,4-Trichlorobenzene ND mg/L 06/26/15 13:05 120-82-10.0010 0.00035 1
1,1,1-Trichloroethane ND mg/L 06/26/15 13:05 71-55-6 M10.0010 0.00048 1
1,1,2-Trichloroethane ND mg/L 06/26/15 13:05 79-00-50.0010 0.00029 1
Trichloroethene ND mg/L 06/26/15 13:05 79-01-60.0010 0.00047 1
Trichlorofluoromethane ND mg/L 06/26/15 13:05 75-69-40.0010 0.00020 1
1,2,3-Trichloropropane ND mg/L 06/26/15 13:05 96-18-40.0010 0.00041 1
1,2,4-Trimethylbenzene ND mg/L 06/26/15 13:05 95-63-60.0010 0.00031 1
1,3,5-Trimethylbenzene ND mg/L 06/26/15 13:05 108-67-80.0010 0.00036 1
Vinyl acetate ND mg/L 06/26/15 13:05 108-05-40.0020 0.00035 1
Vinyl chloride ND mg/L 06/26/15 13:05 75-01-40.0010 0.00062 1
Xylene (Total)ND mg/L 06/26/15 13:05 1330-20-70.0020 0.00066 1
m&p-Xylene ND mg/L 06/26/15 13:05 179601-23-10.0020 0.00066 1
o-Xylene ND mg/L 06/26/15 13:05 95-47-60.0010 0.00023 1
Surrogates
4-Bromofluorobenzene (S)102 %06/26/15 13:05 460-00-470-130 1
1,2-Dichloroethane-d4 (S)97 %06/26/15 13:05 17060-07-070-130 1
Toluene-d8 (S)98 %06/26/15 13:05 2037-26-570-130 1
Sample:WD-2 Lab ID:92255880002 Collected:06/24/15 13:30 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP
Arsenic ND mg/L 06/29/15 20:04 7440-38-206/26/15 19:150.010 0.0050 1
Barium 0.82 mg/L 06/29/15 20:04 7440-39-306/26/15 19:150.0050 0.0025 1
Cadmium ND mg/L 06/29/15 20:04 7440-43-906/26/15 19:150.0010 0.000050 1
Chromium 0.011 mg/L 06/29/15 20:04 7440-47-306/26/15 19:150.0050 0.0025 1
Lead 0.0050 mg/L 06/29/15 20:04 7439-92-106/26/15 19:150.0050 0.0025 1
Selenium 0.029 mg/L 06/29/15 20:04 7782-49-206/26/15 19:150.010 0.0050 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 6 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Sample:WD-2 Lab ID:92255880002 Collected:06/24/15 13:30 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP
Silver ND mg/L 06/29/15 20:04 7440-22-406/26/15 19:150.0050 0.0025 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND mg/L 07/02/15 12:52 7439-97-606/30/15 17:450.00020 0.00010 1
Analytical Method: EPA 82608260 MSV Low Level
Benzene 0.0017 mg/L 06/26/15 13:23 71-43-20.0010 0.00025 1
Bromobenzene ND mg/L 06/26/15 13:23 108-86-10.0010 0.00030 1
Bromochloromethane ND mg/L 06/26/15 13:23 74-97-50.0010 0.00017 1
Bromodichloromethane ND mg/L 06/26/15 13:23 75-27-40.0010 0.00018 1
Bromoform ND mg/L 06/26/15 13:23 75-25-20.0010 0.00026 1
Bromomethane ND mg/L 06/26/15 13:23 74-83-90.0020 0.00029 1
n-Butylbenzene ND mg/L 06/26/15 13:23 104-51-80.0010 0.00041 1
sec-Butylbenzene ND mg/L 06/26/15 13:23 135-98-80.0010 0.00038 1
tert-Butylbenzene ND mg/L 06/26/15 13:23 98-06-60.0010 0.00040 1
Carbon tetrachloride ND mg/L 06/26/15 13:23 56-23-50.0010 0.00025 1
Chlorobenzene ND mg/L 06/26/15 13:23 108-90-70.0010 0.00023 1
Chloroethane ND mg/L 06/26/15 13:23 75-00-30.0010 0.00054 1
Chloroform ND mg/L 06/26/15 13:23 67-66-30.0010 0.00014 1
Chloromethane ND mg/L 06/26/15 13:23 74-87-30.0010 0.00011 1
2-Chlorotoluene ND mg/L 06/26/15 13:23 95-49-80.0010 0.00035 1
4-Chlorotoluene ND mg/L 06/26/15 13:23 106-43-40.0010 0.00031 1
Dibromochloromethane ND mg/L 06/26/15 13:23 124-48-10.0010 0.00021 1
1,2-Dibromoethane (EDB)ND mg/L 06/26/15 13:23 106-93-40.0010 0.00027 1
Dibromomethane ND mg/L 06/26/15 13:23 74-95-30.0010 0.00021 1
1,2-Dichlorobenzene ND mg/L 06/26/15 13:23 95-50-10.0010 0.00030 1
1,3-Dichlorobenzene ND mg/L 06/26/15 13:23 541-73-10.0010 0.00024 1
1,4-Dichlorobenzene ND mg/L 06/26/15 13:23 106-46-70.0010 0.00033 1
Dichlorodifluoromethane ND mg/L 06/26/15 13:23 75-71-80.0010 0.00021 1
1,1-Dichloroethane ND mg/L 06/26/15 13:23 75-34-30.0010 0.00032 1
1,2-Dichloroethane ND mg/L 06/26/15 13:23 107-06-20.0010 0.00012 1
1,2-Dichloroethene (Total)ND mg/L 06/26/15 13:23 540-59-00.0010 0.00049 1
1,1-Dichloroethene ND mg/L 06/26/15 13:23 75-35-40.0010 0.00056 1
cis-1,2-Dichloroethene ND mg/L 06/26/15 13:23 156-59-20.0010 0.00019 1
trans-1,2-Dichloroethene ND mg/L 06/26/15 13:23 156-60-50.0010 0.00049 1
1,2-Dichloropropane ND mg/L 06/26/15 13:23 78-87-50.0010 0.00027 1
1,3-Dichloropropane ND mg/L 06/26/15 13:23 142-28-90.0010 0.00028 1
2,2-Dichloropropane ND mg/L 06/26/15 13:23 594-20-70.0010 0.00013 1
1,1-Dichloropropene ND mg/L 06/26/15 13:23 563-58-60.0010 0.00049 1
Diisopropyl ether ND mg/L 06/26/15 13:23 108-20-30.0010 0.00012 1
Ethylbenzene ND mg/L 06/26/15 13:23 100-41-40.0010 0.00030 1
Hexachloro-1,3-butadiene ND mg/L 06/26/15 13:23 87-68-30.0010 0.00071 1
Isopropylbenzene (Cumene)0.0027 mg/L 06/26/15 13:23 98-82-80.0010 0.00040 1
p-Isopropyltoluene ND mg/L 06/26/15 13:23 99-87-60.0010 0.00031 1
Methylene Chloride ND mg/L 06/26/15 13:23 75-09-20.0020 0.00097 1
Methyl-tert-butyl ether ND mg/L 06/26/15 13:23 1634-04-40.0010 0.00021 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 7 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Sample:WD-2 Lab ID:92255880002 Collected:06/24/15 13:30 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Naphthalene ND mg/L 06/26/15 13:23 91-20-30.0010 0.00024 1
n-Propylbenzene ND mg/L 06/26/15 13:23 103-65-10.0010 0.00042 1
Styrene ND mg/L 06/26/15 13:23 100-42-50.0010 0.00026 1
1,1,1,2-Tetrachloroethane ND mg/L 06/26/15 13:23 630-20-60.0010 0.00033 1
1,1,2,2-Tetrachloroethane ND mg/L 06/26/15 13:23 79-34-50.0010 0.00040 1
Tetrachloroethene ND mg/L 06/26/15 13:23 127-18-40.0010 0.00046 1
Tetrahydrofuran 0.10 mg/L 06/26/15 13:23 109-99-90.010 0.0031 1
Toluene ND mg/L 06/26/15 13:23 108-88-30.0010 0.00026 1
1,2,3-Trichlorobenzene ND mg/L 06/26/15 13:23 87-61-60.0010 0.00033 1
1,2,4-Trichlorobenzene ND mg/L 06/26/15 13:23 120-82-10.0010 0.00035 1
1,1,1-Trichloroethane ND mg/L 06/26/15 13:23 71-55-60.0010 0.00048 1
1,1,2-Trichloroethane ND mg/L 06/26/15 13:23 79-00-50.0010 0.00029 1
Trichloroethene ND mg/L 06/26/15 13:23 79-01-60.0010 0.00047 1
Trichlorofluoromethane ND mg/L 06/26/15 13:23 75-69-40.0010 0.00020 1
1,2,3-Trichloropropane ND mg/L 06/26/15 13:23 96-18-40.0010 0.00041 1
1,2,4-Trimethylbenzene ND mg/L 06/26/15 13:23 95-63-60.0010 0.00031 1
1,3,5-Trimethylbenzene ND mg/L 06/26/15 13:23 108-67-80.0010 0.00036 1
Vinyl acetate ND mg/L 06/26/15 13:23 108-05-40.0020 0.00035 1
Vinyl chloride ND mg/L 06/26/15 13:23 75-01-40.0010 0.00062 1
Xylene (Total)ND mg/L 06/26/15 13:23 1330-20-70.0020 0.00066 1
m&p-Xylene ND mg/L 06/26/15 13:23 179601-23-10.0020 0.00066 1
o-Xylene ND mg/L 06/26/15 13:23 95-47-60.0010 0.00023 1
Surrogates
4-Bromofluorobenzene (S)99 %06/26/15 13:23 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %06/26/15 13:23 17060-07-070-130 1
Toluene-d8 (S)100 %06/26/15 13:23 2037-26-570-130 1
Sample:WD-2D Lab ID:92255880003 Collected:06/24/15 14:00 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP
Arsenic ND mg/L 06/29/15 20:12 7440-38-206/26/15 19:150.010 0.0050 1
Barium 0.27 mg/L 06/29/15 20:12 7440-39-306/26/15 19:150.0050 0.0025 1
Cadmium ND mg/L 06/29/15 20:12 7440-43-906/26/15 19:150.0010 0.000050 1
Chromium ND mg/L 06/29/15 20:12 7440-47-306/26/15 19:150.0050 0.0025 1
Lead ND mg/L 06/29/15 20:12 7439-92-106/26/15 19:150.0050 0.0025 1
Selenium 0.012 mg/L 06/29/15 20:12 7782-49-206/26/15 19:150.010 0.0050 1
Silver ND mg/L 06/29/15 20:12 7440-22-406/26/15 19:150.0050 0.0025 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND mg/L 07/02/15 12:54 7439-97-606/30/15 17:450.00020 0.00010 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 8 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Sample:WD-2D Lab ID:92255880003 Collected:06/24/15 14:00 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Benzene ND mg/L 06/26/15 13:41 71-43-20.0010 0.00025 1
Bromobenzene ND mg/L 06/26/15 13:41 108-86-10.0010 0.00030 1
Bromochloromethane ND mg/L 06/26/15 13:41 74-97-50.0010 0.00017 1
Bromodichloromethane ND mg/L 06/26/15 13:41 75-27-40.0010 0.00018 1
Bromoform ND mg/L 06/26/15 13:41 75-25-20.0010 0.00026 1
Bromomethane ND mg/L 06/26/15 13:41 74-83-90.0020 0.00029 1
n-Butylbenzene ND mg/L 06/26/15 13:41 104-51-80.0010 0.00041 1
sec-Butylbenzene ND mg/L 06/26/15 13:41 135-98-80.0010 0.00038 1
tert-Butylbenzene ND mg/L 06/26/15 13:41 98-06-60.0010 0.00040 1
Carbon tetrachloride ND mg/L 06/26/15 13:41 56-23-50.0010 0.00025 1
Chlorobenzene 0.0047 mg/L 06/26/15 13:41 108-90-70.0010 0.00023 1
Chloroethane ND mg/L 06/26/15 13:41 75-00-30.0010 0.00054 1
Chloroform ND mg/L 06/26/15 13:41 67-66-30.0010 0.00014 1
Chloromethane ND mg/L 06/26/15 13:41 74-87-30.0010 0.00011 1
2-Chlorotoluene ND mg/L 06/26/15 13:41 95-49-80.0010 0.00035 1
4-Chlorotoluene ND mg/L 06/26/15 13:41 106-43-40.0010 0.00031 1
Dibromochloromethane ND mg/L 06/26/15 13:41 124-48-10.0010 0.00021 1
1,2-Dibromoethane (EDB)ND mg/L 06/26/15 13:41 106-93-40.0010 0.00027 1
Dibromomethane ND mg/L 06/26/15 13:41 74-95-30.0010 0.00021 1
1,2-Dichlorobenzene 0.0014 mg/L 06/26/15 13:41 95-50-10.0010 0.00030 1
1,3-Dichlorobenzene ND mg/L 06/26/15 13:41 541-73-10.0010 0.00024 1
1,4-Dichlorobenzene ND mg/L 06/26/15 13:41 106-46-70.0010 0.00033 1
Dichlorodifluoromethane ND mg/L 06/26/15 13:41 75-71-80.0010 0.00021 1
1,1-Dichloroethane ND mg/L 06/26/15 13:41 75-34-30.0010 0.00032 1
1,2-Dichloroethane ND mg/L 06/26/15 13:41 107-06-20.0010 0.00012 1
1,2-Dichloroethene (Total)ND mg/L 06/26/15 13:41 540-59-00.0010 0.00049 1
1,1-Dichloroethene ND mg/L 06/26/15 13:41 75-35-40.0010 0.00056 1
cis-1,2-Dichloroethene ND mg/L 06/26/15 13:41 156-59-20.0010 0.00019 1
trans-1,2-Dichloroethene ND mg/L 06/26/15 13:41 156-60-50.0010 0.00049 1
1,2-Dichloropropane ND mg/L 06/26/15 13:41 78-87-50.0010 0.00027 1
1,3-Dichloropropane ND mg/L 06/26/15 13:41 142-28-90.0010 0.00028 1
2,2-Dichloropropane ND mg/L 06/26/15 13:41 594-20-70.0010 0.00013 1
1,1-Dichloropropene ND mg/L 06/26/15 13:41 563-58-60.0010 0.00049 1
Diisopropyl ether ND mg/L 06/26/15 13:41 108-20-30.0010 0.00012 1
Ethylbenzene ND mg/L 06/26/15 13:41 100-41-40.0010 0.00030 1
Hexachloro-1,3-butadiene ND mg/L 06/26/15 13:41 87-68-30.0010 0.00071 1
Isopropylbenzene (Cumene)ND mg/L 06/26/15 13:41 98-82-80.0010 0.00040 1
p-Isopropyltoluene ND mg/L 06/26/15 13:41 99-87-60.0010 0.00031 1
Methylene Chloride ND mg/L 06/26/15 13:41 75-09-20.0020 0.00097 1
Methyl-tert-butyl ether ND mg/L 06/26/15 13:41 1634-04-40.0010 0.00021 1
Naphthalene ND mg/L 06/26/15 13:41 91-20-30.0010 0.00024 1
n-Propylbenzene ND mg/L 06/26/15 13:41 103-65-10.0010 0.00042 1
Styrene ND mg/L 06/26/15 13:41 100-42-50.0010 0.00026 1
1,1,1,2-Tetrachloroethane ND mg/L 06/26/15 13:41 630-20-60.0010 0.00033 1
1,1,2,2-Tetrachloroethane ND mg/L 06/26/15 13:41 79-34-50.0010 0.00040 1
Tetrachloroethene ND mg/L 06/26/15 13:41 127-18-40.0010 0.00046 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 9 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Sample:WD-2D Lab ID:92255880003 Collected:06/24/15 14:00 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Tetrahydrofuran 0.050 mg/L 06/26/15 13:41 109-99-90.010 0.0031 1
Toluene ND mg/L 06/26/15 13:41 108-88-30.0010 0.00026 1
1,2,3-Trichlorobenzene ND mg/L 06/26/15 13:41 87-61-60.0010 0.00033 1
1,2,4-Trichlorobenzene ND mg/L 06/26/15 13:41 120-82-10.0010 0.00035 1
1,1,1-Trichloroethane ND mg/L 06/26/15 13:41 71-55-60.0010 0.00048 1
1,1,2-Trichloroethane ND mg/L 06/26/15 13:41 79-00-50.0010 0.00029 1
Trichloroethene ND mg/L 06/26/15 13:41 79-01-60.0010 0.00047 1
Trichlorofluoromethane ND mg/L 06/26/15 13:41 75-69-40.0010 0.00020 1
1,2,3-Trichloropropane ND mg/L 06/26/15 13:41 96-18-40.0010 0.00041 1
1,2,4-Trimethylbenzene ND mg/L 06/26/15 13:41 95-63-60.0010 0.00031 1
1,3,5-Trimethylbenzene ND mg/L 06/26/15 13:41 108-67-80.0010 0.00036 1
Vinyl acetate ND mg/L 06/26/15 13:41 108-05-40.0020 0.00035 1
Vinyl chloride ND mg/L 06/26/15 13:41 75-01-40.0010 0.00062 1
Xylene (Total)ND mg/L 06/26/15 13:41 1330-20-70.0020 0.00066 1
m&p-Xylene ND mg/L 06/26/15 13:41 179601-23-10.0020 0.00066 1
o-Xylene ND mg/L 06/26/15 13:41 95-47-60.0010 0.00023 1
Surrogates
4-Bromofluorobenzene (S)99 %06/26/15 13:41 460-00-470-130 1
1,2-Dichloroethane-d4 (S)105 %06/26/15 13:41 17060-07-070-130 1
Toluene-d8 (S)106 %06/26/15 13:41 2037-26-570-130 1
Sample:WD-3 Lab ID:92255880004 Collected:06/24/15 13:00 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP
Arsenic ND mg/L 06/29/15 20:28 7440-38-206/26/15 19:150.010 0.0050 1
Barium 0.82 mg/L 06/29/15 20:28 7440-39-306/26/15 19:150.0050 0.0025 1
Cadmium ND mg/L 06/29/15 20:28 7440-43-906/26/15 19:150.0010 0.000050 1
Chromium 0.0060 mg/L 06/29/15 20:28 7440-47-306/26/15 19:150.0050 0.0025 1
Lead ND mg/L 06/29/15 20:28 7439-92-106/26/15 19:150.0050 0.0025 1
Selenium 0.013 mg/L 06/29/15 20:28 7782-49-206/26/15 19:150.010 0.0050 1
Silver ND mg/L 06/29/15 20:28 7440-22-406/26/15 19:150.0050 0.0025 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND mg/L 07/02/15 12:56 7439-97-606/30/15 17:450.00020 0.00010 1
Analytical Method: EPA 82608260 MSV Low Level
Benzene ND mg/L 06/26/15 13:59 71-43-20.0010 0.00025 1
Bromobenzene ND mg/L 06/26/15 13:59 108-86-10.0010 0.00030 1
Bromochloromethane ND mg/L 06/26/15 13:59 74-97-50.0010 0.00017 1
Bromodichloromethane ND mg/L 06/26/15 13:59 75-27-40.0010 0.00018 1
Bromoform ND mg/L 06/26/15 13:59 75-25-20.0010 0.00026 1
Bromomethane ND mg/L 06/26/15 13:59 74-83-90.0020 0.00029 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 10 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Sample:WD-3 Lab ID:92255880004 Collected:06/24/15 13:00 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
n-Butylbenzene ND mg/L 06/26/15 13:59 104-51-80.0010 0.00041 1
sec-Butylbenzene ND mg/L 06/26/15 13:59 135-98-80.0010 0.00038 1
tert-Butylbenzene ND mg/L 06/26/15 13:59 98-06-60.0010 0.00040 1
Carbon tetrachloride ND mg/L 06/26/15 13:59 56-23-50.0010 0.00025 1
Chlorobenzene ND mg/L 06/26/15 13:59 108-90-70.0010 0.00023 1
Chloroethane ND mg/L 06/26/15 13:59 75-00-30.0010 0.00054 1
Chloroform ND mg/L 06/26/15 13:59 67-66-30.0010 0.00014 1
Chloromethane ND mg/L 06/26/15 13:59 74-87-30.0010 0.00011 1
2-Chlorotoluene ND mg/L 06/26/15 13:59 95-49-80.0010 0.00035 1
4-Chlorotoluene ND mg/L 06/26/15 13:59 106-43-40.0010 0.00031 1
Dibromochloromethane ND mg/L 06/26/15 13:59 124-48-10.0010 0.00021 1
1,2-Dibromoethane (EDB)ND mg/L 06/26/15 13:59 106-93-40.0010 0.00027 1
Dibromomethane ND mg/L 06/26/15 13:59 74-95-30.0010 0.00021 1
1,2-Dichlorobenzene ND mg/L 06/26/15 13:59 95-50-10.0010 0.00030 1
1,3-Dichlorobenzene ND mg/L 06/26/15 13:59 541-73-10.0010 0.00024 1
1,4-Dichlorobenzene ND mg/L 06/26/15 13:59 106-46-70.0010 0.00033 1
Dichlorodifluoromethane ND mg/L 06/26/15 13:59 75-71-80.0010 0.00021 1
1,1-Dichloroethane ND mg/L 06/26/15 13:59 75-34-30.0010 0.00032 1
1,2-Dichloroethane ND mg/L 06/26/15 13:59 107-06-20.0010 0.00012 1
1,2-Dichloroethene (Total)ND mg/L 06/26/15 13:59 540-59-00.0010 0.00049 1
1,1-Dichloroethene ND mg/L 06/26/15 13:59 75-35-40.0010 0.00056 1
cis-1,2-Dichloroethene ND mg/L 06/26/15 13:59 156-59-20.0010 0.00019 1
trans-1,2-Dichloroethene ND mg/L 06/26/15 13:59 156-60-50.0010 0.00049 1
1,2-Dichloropropane ND mg/L 06/26/15 13:59 78-87-50.0010 0.00027 1
1,3-Dichloropropane ND mg/L 06/26/15 13:59 142-28-90.0010 0.00028 1
2,2-Dichloropropane ND mg/L 06/26/15 13:59 594-20-70.0010 0.00013 1
1,1-Dichloropropene ND mg/L 06/26/15 13:59 563-58-60.0010 0.00049 1
Diisopropyl ether ND mg/L 06/26/15 13:59 108-20-30.0010 0.00012 1
Ethylbenzene ND mg/L 06/26/15 13:59 100-41-40.0010 0.00030 1
Hexachloro-1,3-butadiene ND mg/L 06/26/15 13:59 87-68-30.0010 0.00071 1
Isopropylbenzene (Cumene)ND mg/L 06/26/15 13:59 98-82-80.0010 0.00040 1
p-Isopropyltoluene ND mg/L 06/26/15 13:59 99-87-60.0010 0.00031 1
Methylene Chloride ND mg/L 06/26/15 13:59 75-09-20.0020 0.00097 1
Methyl-tert-butyl ether ND mg/L 06/26/15 13:59 1634-04-40.0010 0.00021 1
Naphthalene ND mg/L 06/26/15 13:59 91-20-30.0010 0.00024 1
n-Propylbenzene ND mg/L 06/26/15 13:59 103-65-10.0010 0.00042 1
Styrene ND mg/L 06/26/15 13:59 100-42-50.0010 0.00026 1
1,1,1,2-Tetrachloroethane ND mg/L 06/26/15 13:59 630-20-60.0010 0.00033 1
1,1,2,2-Tetrachloroethane ND mg/L 06/26/15 13:59 79-34-50.0010 0.00040 1
Tetrachloroethene ND mg/L 06/26/15 13:59 127-18-40.0010 0.00046 1
Tetrahydrofuran 0.022 mg/L 06/26/15 13:59 109-99-90.010 0.0031 1
Toluene ND mg/L 06/26/15 13:59 108-88-30.0010 0.00026 1
1,2,3-Trichlorobenzene ND mg/L 06/26/15 13:59 87-61-60.0010 0.00033 1
1,2,4-Trichlorobenzene ND mg/L 06/26/15 13:59 120-82-10.0010 0.00035 1
1,1,1-Trichloroethane ND mg/L 06/26/15 13:59 71-55-60.0010 0.00048 1
1,1,2-Trichloroethane ND mg/L 06/26/15 13:59 79-00-50.0010 0.00029 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 11 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Sample:WD-3 Lab ID:92255880004 Collected:06/24/15 13:00 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Trichloroethene ND mg/L 06/26/15 13:59 79-01-60.0010 0.00047 1
Trichlorofluoromethane ND mg/L 06/26/15 13:59 75-69-40.0010 0.00020 1
1,2,3-Trichloropropane ND mg/L 06/26/15 13:59 96-18-40.0010 0.00041 1
1,2,4-Trimethylbenzene ND mg/L 06/26/15 13:59 95-63-60.0010 0.00031 1
1,3,5-Trimethylbenzene ND mg/L 06/26/15 13:59 108-67-80.0010 0.00036 1
Vinyl acetate ND mg/L 06/26/15 13:59 108-05-40.0020 0.00035 1
Vinyl chloride ND mg/L 06/26/15 13:59 75-01-40.0010 0.00062 1
Xylene (Total)ND mg/L 06/26/15 13:59 1330-20-70.0020 0.00066 1
m&p-Xylene ND mg/L 06/26/15 13:59 179601-23-10.0020 0.00066 1
o-Xylene ND mg/L 06/26/15 13:59 95-47-60.0010 0.00023 1
Surrogates
4-Bromofluorobenzene (S)100 %06/26/15 13:59 460-00-470-130 1
1,2-Dichloroethane-d4 (S)104 %06/26/15 13:59 17060-07-070-130 1
Toluene-d8 (S)100 %06/26/15 13:59 2037-26-570-130 1
Sample:WD-3D Lab ID:92255880005 Collected:06/24/15 12:45 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP
Arsenic ND mg/L 06/29/15 20:32 7440-38-206/26/15 19:150.010 0.0050 1
Barium 0.14 mg/L 06/29/15 20:32 7440-39-306/26/15 19:150.0050 0.0025 1
Cadmium ND mg/L 06/29/15 20:32 7440-43-906/26/15 19:150.0010 0.000050 1
Chromium 0.0079 mg/L 06/29/15 20:32 7440-47-306/26/15 19:150.0050 0.0025 1
Lead ND mg/L 06/29/15 20:32 7439-92-106/26/15 19:150.0050 0.0025 1
Selenium ND mg/L 06/29/15 20:32 7782-49-206/26/15 19:150.010 0.0050 1
Silver ND mg/L 06/29/15 20:32 7440-22-406/26/15 19:150.0050 0.0025 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND mg/L 07/02/15 12:59 7439-97-606/30/15 17:450.00020 0.00010 1
Analytical Method: EPA 82608260 MSV Low Level
Benzene ND mg/L 06/26/15 14:17 71-43-20.0010 0.00025 1
Bromobenzene ND mg/L 06/26/15 14:17 108-86-10.0010 0.00030 1
Bromochloromethane ND mg/L 06/26/15 14:17 74-97-50.0010 0.00017 1
Bromodichloromethane ND mg/L 06/26/15 14:17 75-27-40.0010 0.00018 1
Bromoform ND mg/L 06/26/15 14:17 75-25-20.0010 0.00026 1
Bromomethane ND mg/L 06/26/15 14:17 74-83-90.0020 0.00029 1
n-Butylbenzene ND mg/L 06/26/15 14:17 104-51-80.0010 0.00041 1
sec-Butylbenzene ND mg/L 06/26/15 14:17 135-98-80.0010 0.00038 1
tert-Butylbenzene ND mg/L 06/26/15 14:17 98-06-60.0010 0.00040 1
Carbon tetrachloride ND mg/L 06/26/15 14:17 56-23-50.0010 0.00025 1
Chlorobenzene ND mg/L 06/26/15 14:17 108-90-70.0010 0.00023 1
Chloroethane ND mg/L 06/26/15 14:17 75-00-30.0010 0.00054 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 12 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Sample:WD-3D Lab ID:92255880005 Collected:06/24/15 12:45 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Chloroform ND mg/L 06/26/15 14:17 67-66-30.0010 0.00014 1
Chloromethane ND mg/L 06/26/15 14:17 74-87-30.0010 0.00011 1
2-Chlorotoluene ND mg/L 06/26/15 14:17 95-49-80.0010 0.00035 1
4-Chlorotoluene ND mg/L 06/26/15 14:17 106-43-40.0010 0.00031 1
Dibromochloromethane ND mg/L 06/26/15 14:17 124-48-10.0010 0.00021 1
1,2-Dibromoethane (EDB)ND mg/L 06/26/15 14:17 106-93-40.0010 0.00027 1
Dibromomethane ND mg/L 06/26/15 14:17 74-95-30.0010 0.00021 1
1,2-Dichlorobenzene ND mg/L 06/26/15 14:17 95-50-10.0010 0.00030 1
1,3-Dichlorobenzene ND mg/L 06/26/15 14:17 541-73-10.0010 0.00024 1
1,4-Dichlorobenzene ND mg/L 06/26/15 14:17 106-46-70.0010 0.00033 1
Dichlorodifluoromethane ND mg/L 06/26/15 14:17 75-71-80.0010 0.00021 1
1,1-Dichloroethane ND mg/L 06/26/15 14:17 75-34-30.0010 0.00032 1
1,2-Dichloroethane ND mg/L 06/26/15 14:17 107-06-20.0010 0.00012 1
1,2-Dichloroethene (Total)ND mg/L 06/26/15 14:17 540-59-00.0010 0.00049 1
1,1-Dichloroethene ND mg/L 06/26/15 14:17 75-35-40.0010 0.00056 1
cis-1,2-Dichloroethene ND mg/L 06/26/15 14:17 156-59-20.0010 0.00019 1
trans-1,2-Dichloroethene ND mg/L 06/26/15 14:17 156-60-50.0010 0.00049 1
1,2-Dichloropropane ND mg/L 06/26/15 14:17 78-87-50.0010 0.00027 1
1,3-Dichloropropane ND mg/L 06/26/15 14:17 142-28-90.0010 0.00028 1
2,2-Dichloropropane ND mg/L 06/26/15 14:17 594-20-70.0010 0.00013 1
1,1-Dichloropropene ND mg/L 06/26/15 14:17 563-58-60.0010 0.00049 1
Diisopropyl ether ND mg/L 06/26/15 14:17 108-20-30.0010 0.00012 1
Ethylbenzene ND mg/L 06/26/15 14:17 100-41-40.0010 0.00030 1
Hexachloro-1,3-butadiene ND mg/L 06/26/15 14:17 87-68-30.0010 0.00071 1
Isopropylbenzene (Cumene)ND mg/L 06/26/15 14:17 98-82-80.0010 0.00040 1
p-Isopropyltoluene ND mg/L 06/26/15 14:17 99-87-60.0010 0.00031 1
Methylene Chloride ND mg/L 06/26/15 14:17 75-09-20.0020 0.00097 1
Methyl-tert-butyl ether ND mg/L 06/26/15 14:17 1634-04-40.0010 0.00021 1
Naphthalene ND mg/L 06/26/15 14:17 91-20-30.0010 0.00024 1
n-Propylbenzene ND mg/L 06/26/15 14:17 103-65-10.0010 0.00042 1
Styrene ND mg/L 06/26/15 14:17 100-42-50.0010 0.00026 1
1,1,1,2-Tetrachloroethane ND mg/L 06/26/15 14:17 630-20-60.0010 0.00033 1
1,1,2,2-Tetrachloroethane ND mg/L 06/26/15 14:17 79-34-50.0010 0.00040 1
Tetrachloroethene ND mg/L 06/26/15 14:17 127-18-40.0010 0.00046 1
Tetrahydrofuran ND mg/L 06/26/15 14:17 109-99-90.010 0.0031 1
Toluene ND mg/L 06/26/15 14:17 108-88-30.0010 0.00026 1
1,2,3-Trichlorobenzene ND mg/L 06/26/15 14:17 87-61-60.0010 0.00033 1
1,2,4-Trichlorobenzene ND mg/L 06/26/15 14:17 120-82-10.0010 0.00035 1
1,1,1-Trichloroethane ND mg/L 06/26/15 14:17 71-55-60.0010 0.00048 1
1,1,2-Trichloroethane ND mg/L 06/26/15 14:17 79-00-50.0010 0.00029 1
Trichloroethene ND mg/L 06/26/15 14:17 79-01-60.0010 0.00047 1
Trichlorofluoromethane ND mg/L 06/26/15 14:17 75-69-40.0010 0.00020 1
1,2,3-Trichloropropane ND mg/L 06/26/15 14:17 96-18-40.0010 0.00041 1
1,2,4-Trimethylbenzene ND mg/L 06/26/15 14:17 95-63-60.0010 0.00031 1
1,3,5-Trimethylbenzene ND mg/L 06/26/15 14:17 108-67-80.0010 0.00036 1
Vinyl acetate ND mg/L 06/26/15 14:17 108-05-40.0020 0.00035 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 13 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Sample:WD-3D Lab ID:92255880005 Collected:06/24/15 12:45 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Vinyl chloride ND mg/L 06/26/15 14:17 75-01-40.0010 0.00062 1
Xylene (Total)ND mg/L 06/26/15 14:17 1330-20-70.0020 0.00066 1
m&p-Xylene ND mg/L 06/26/15 14:17 179601-23-10.0020 0.00066 1
o-Xylene ND mg/L 06/26/15 14:17 95-47-60.0010 0.00023 1
Surrogates
4-Bromofluorobenzene (S)102 %06/26/15 14:17 460-00-470-130 1
1,2-Dichloroethane-d4 (S)108 %06/26/15 14:17 17060-07-070-130 1
Toluene-d8 (S)100 %06/26/15 14:17 2037-26-570-130 1
Sample:WD-4 Lab ID:92255880006 Collected:06/24/15 11:30 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP
Arsenic ND mg/L 06/29/15 20:36 7440-38-206/26/15 19:150.010 0.0050 1
Barium 0.79 mg/L 06/29/15 20:36 7440-39-306/26/15 19:150.0050 0.0025 1
Cadmium ND mg/L 06/29/15 20:36 7440-43-906/26/15 19:150.0010 0.000050 1
Chromium ND mg/L 06/29/15 20:36 7440-47-306/26/15 19:150.0050 0.0025 1
Lead ND mg/L 06/29/15 20:36 7439-92-106/26/15 19:150.0050 0.0025 1
Selenium 0.018 mg/L 06/29/15 20:36 7782-49-206/26/15 19:150.010 0.0050 1
Silver ND mg/L 06/29/15 20:36 7440-22-406/26/15 19:150.0050 0.0025 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND mg/L 07/02/15 13:01 7439-97-606/30/15 17:450.00020 0.00010 1
Analytical Method: EPA 82608260 MSV Low Level
Benzene ND mg/L 06/26/15 14:35 71-43-20.0010 0.00025 1
Bromobenzene ND mg/L 06/26/15 14:35 108-86-10.0010 0.00030 1
Bromochloromethane ND mg/L 06/26/15 14:35 74-97-50.0010 0.00017 1
Bromodichloromethane ND mg/L 06/26/15 14:35 75-27-40.0010 0.00018 1
Bromoform ND mg/L 06/26/15 14:35 75-25-20.0010 0.00026 1
Bromomethane ND mg/L 06/26/15 14:35 74-83-90.0020 0.00029 1
n-Butylbenzene ND mg/L 06/26/15 14:35 104-51-80.0010 0.00041 1
sec-Butylbenzene ND mg/L 06/26/15 14:35 135-98-80.0010 0.00038 1
tert-Butylbenzene ND mg/L 06/26/15 14:35 98-06-60.0010 0.00040 1
Carbon tetrachloride ND mg/L 06/26/15 14:35 56-23-50.0010 0.00025 1
Chlorobenzene 0.0016 mg/L 06/26/15 14:35 108-90-70.0010 0.00023 1
Chloroethane ND mg/L 06/26/15 14:35 75-00-30.0010 0.00054 1
Chloroform ND mg/L 06/26/15 14:35 67-66-30.0010 0.00014 1
Chloromethane ND mg/L 06/26/15 14:35 74-87-30.0010 0.00011 1
2-Chlorotoluene ND mg/L 06/26/15 14:35 95-49-80.0010 0.00035 1
4-Chlorotoluene ND mg/L 06/26/15 14:35 106-43-40.0010 0.00031 1
Dibromochloromethane ND mg/L 06/26/15 14:35 124-48-10.0010 0.00021 1
1,2-Dibromoethane (EDB)ND mg/L 06/26/15 14:35 106-93-40.0010 0.00027 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 14 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Sample:WD-4 Lab ID:92255880006 Collected:06/24/15 11:30 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Dibromomethane ND mg/L 06/26/15 14:35 74-95-30.0010 0.00021 1
1,2-Dichlorobenzene ND mg/L 06/26/15 14:35 95-50-10.0010 0.00030 1
1,3-Dichlorobenzene ND mg/L 06/26/15 14:35 541-73-10.0010 0.00024 1
1,4-Dichlorobenzene ND mg/L 06/26/15 14:35 106-46-70.0010 0.00033 1
Dichlorodifluoromethane ND mg/L 06/26/15 14:35 75-71-80.0010 0.00021 1
1,1-Dichloroethane ND mg/L 06/26/15 14:35 75-34-30.0010 0.00032 1
1,2-Dichloroethane ND mg/L 06/26/15 14:35 107-06-20.0010 0.00012 1
1,2-Dichloroethene (Total)ND mg/L 06/26/15 14:35 540-59-00.0010 0.00049 1
1,1-Dichloroethene ND mg/L 06/26/15 14:35 75-35-40.0010 0.00056 1
cis-1,2-Dichloroethene ND mg/L 06/26/15 14:35 156-59-20.0010 0.00019 1
trans-1,2-Dichloroethene ND mg/L 06/26/15 14:35 156-60-50.0010 0.00049 1
1,2-Dichloropropane ND mg/L 06/26/15 14:35 78-87-50.0010 0.00027 1
1,3-Dichloropropane ND mg/L 06/26/15 14:35 142-28-90.0010 0.00028 1
2,2-Dichloropropane ND mg/L 06/26/15 14:35 594-20-70.0010 0.00013 1
1,1-Dichloropropene ND mg/L 06/26/15 14:35 563-58-60.0010 0.00049 1
Diisopropyl ether ND mg/L 06/26/15 14:35 108-20-30.0010 0.00012 1
Ethylbenzene ND mg/L 06/26/15 14:35 100-41-40.0010 0.00030 1
Hexachloro-1,3-butadiene ND mg/L 06/26/15 14:35 87-68-30.0010 0.00071 1
Isopropylbenzene (Cumene)ND mg/L 06/26/15 14:35 98-82-80.0010 0.00040 1
p-Isopropyltoluene ND mg/L 06/26/15 14:35 99-87-60.0010 0.00031 1
Methylene Chloride ND mg/L 06/26/15 14:35 75-09-20.0020 0.00097 1
Methyl-tert-butyl ether ND mg/L 06/26/15 14:35 1634-04-40.0010 0.00021 1
Naphthalene ND mg/L 06/26/15 14:35 91-20-30.0010 0.00024 1
n-Propylbenzene ND mg/L 06/26/15 14:35 103-65-10.0010 0.00042 1
Styrene ND mg/L 06/26/15 14:35 100-42-50.0010 0.00026 1
1,1,1,2-Tetrachloroethane ND mg/L 06/26/15 14:35 630-20-60.0010 0.00033 1
1,1,2,2-Tetrachloroethane ND mg/L 06/26/15 14:35 79-34-50.0010 0.00040 1
Tetrachloroethene ND mg/L 06/26/15 14:35 127-18-40.0010 0.00046 1
Tetrahydrofuran 0.016 mg/L 06/26/15 14:35 109-99-90.010 0.0031 1
Toluene ND mg/L 06/26/15 14:35 108-88-30.0010 0.00026 1
1,2,3-Trichlorobenzene ND mg/L 06/26/15 14:35 87-61-60.0010 0.00033 1
1,2,4-Trichlorobenzene ND mg/L 06/26/15 14:35 120-82-10.0010 0.00035 1
1,1,1-Trichloroethane ND mg/L 06/26/15 14:35 71-55-60.0010 0.00048 1
1,1,2-Trichloroethane ND mg/L 06/26/15 14:35 79-00-50.0010 0.00029 1
Trichloroethene ND mg/L 06/26/15 14:35 79-01-60.0010 0.00047 1
Trichlorofluoromethane ND mg/L 06/26/15 14:35 75-69-40.0010 0.00020 1
1,2,3-Trichloropropane ND mg/L 06/26/15 14:35 96-18-40.0010 0.00041 1
1,2,4-Trimethylbenzene ND mg/L 06/26/15 14:35 95-63-60.0010 0.00031 1
1,3,5-Trimethylbenzene ND mg/L 06/26/15 14:35 108-67-80.0010 0.00036 1
Vinyl acetate ND mg/L 06/26/15 14:35 108-05-40.0020 0.00035 1
Vinyl chloride ND mg/L 06/26/15 14:35 75-01-40.0010 0.00062 1
Xylene (Total)ND mg/L 06/26/15 14:35 1330-20-70.0020 0.00066 1
m&p-Xylene ND mg/L 06/26/15 14:35 179601-23-10.0020 0.00066 1
o-Xylene ND mg/L 06/26/15 14:35 95-47-60.0010 0.00023 1
Surrogates
4-Bromofluorobenzene (S)104 %06/26/15 14:35 460-00-470-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 15 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Sample:WD-4 Lab ID:92255880006 Collected:06/24/15 11:30 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Surrogates
1,2-Dichloroethane-d4 (S)109 %06/26/15 14:35 17060-07-070-130 1
Toluene-d8 (S)100 %06/26/15 14:35 2037-26-570-130 1
Sample:WD-4D Lab ID:92255880007 Collected:06/24/15 11:00 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP
Arsenic ND mg/L 06/29/15 20:41 7440-38-206/26/15 19:150.010 0.0050 1
Barium 0.029 mg/L 06/29/15 20:41 7440-39-306/26/15 19:150.0050 0.0025 1
Cadmium ND mg/L 06/29/15 20:41 7440-43-906/26/15 19:150.0010 0.000050 1
Chromium ND mg/L 06/29/15 20:41 7440-47-306/26/15 19:150.0050 0.0025 1
Lead ND mg/L 06/29/15 20:41 7439-92-106/26/15 19:150.0050 0.0025 1
Selenium ND mg/L 06/29/15 20:41 7782-49-206/26/15 19:150.010 0.0050 1
Silver ND mg/L 06/29/15 20:41 7440-22-406/26/15 19:150.0050 0.0025 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND mg/L 07/02/15 13:03 7439-97-606/30/15 17:450.00020 0.00010 1
Analytical Method: EPA 82608260 MSV Low Level
Benzene ND mg/L 06/26/15 14:53 71-43-20.0010 0.00025 1
Bromobenzene ND mg/L 06/26/15 14:53 108-86-10.0010 0.00030 1
Bromochloromethane ND mg/L 06/26/15 14:53 74-97-50.0010 0.00017 1
Bromodichloromethane ND mg/L 06/26/15 14:53 75-27-40.0010 0.00018 1
Bromoform ND mg/L 06/26/15 14:53 75-25-20.0010 0.00026 1
Bromomethane ND mg/L 06/26/15 14:53 74-83-90.0020 0.00029 1
n-Butylbenzene ND mg/L 06/26/15 14:53 104-51-80.0010 0.00041 1
sec-Butylbenzene ND mg/L 06/26/15 14:53 135-98-80.0010 0.00038 1
tert-Butylbenzene ND mg/L 06/26/15 14:53 98-06-60.0010 0.00040 1
Carbon tetrachloride ND mg/L 06/26/15 14:53 56-23-50.0010 0.00025 1
Chlorobenzene ND mg/L 06/26/15 14:53 108-90-70.0010 0.00023 1
Chloroethane ND mg/L 06/26/15 14:53 75-00-30.0010 0.00054 1
Chloroform ND mg/L 06/26/15 14:53 67-66-30.0010 0.00014 1
Chloromethane ND mg/L 06/26/15 14:53 74-87-30.0010 0.00011 1
2-Chlorotoluene ND mg/L 06/26/15 14:53 95-49-80.0010 0.00035 1
4-Chlorotoluene ND mg/L 06/26/15 14:53 106-43-40.0010 0.00031 1
Dibromochloromethane ND mg/L 06/26/15 14:53 124-48-10.0010 0.00021 1
1,2-Dibromoethane (EDB)ND mg/L 06/26/15 14:53 106-93-40.0010 0.00027 1
Dibromomethane ND mg/L 06/26/15 14:53 74-95-30.0010 0.00021 1
1,2-Dichlorobenzene ND mg/L 06/26/15 14:53 95-50-10.0010 0.00030 1
1,3-Dichlorobenzene ND mg/L 06/26/15 14:53 541-73-10.0010 0.00024 1
1,4-Dichlorobenzene ND mg/L 06/26/15 14:53 106-46-70.0010 0.00033 1
Dichlorodifluoromethane ND mg/L 06/26/15 14:53 75-71-80.0010 0.00021 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 16 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Sample:WD-4D Lab ID:92255880007 Collected:06/24/15 11:00 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
1,1-Dichloroethane ND mg/L 06/26/15 14:53 75-34-30.0010 0.00032 1
1,2-Dichloroethane ND mg/L 06/26/15 14:53 107-06-20.0010 0.00012 1
1,2-Dichloroethene (Total)ND mg/L 06/26/15 14:53 540-59-00.0010 0.00049 1
1,1-Dichloroethene ND mg/L 06/26/15 14:53 75-35-40.0010 0.00056 1
cis-1,2-Dichloroethene ND mg/L 06/26/15 14:53 156-59-20.0010 0.00019 1
trans-1,2-Dichloroethene ND mg/L 06/26/15 14:53 156-60-50.0010 0.00049 1
1,2-Dichloropropane ND mg/L 06/26/15 14:53 78-87-50.0010 0.00027 1
1,3-Dichloropropane ND mg/L 06/26/15 14:53 142-28-90.0010 0.00028 1
2,2-Dichloropropane ND mg/L 06/26/15 14:53 594-20-70.0010 0.00013 1
1,1-Dichloropropene ND mg/L 06/26/15 14:53 563-58-60.0010 0.00049 1
Diisopropyl ether ND mg/L 06/26/15 14:53 108-20-30.0010 0.00012 1
Ethylbenzene ND mg/L 06/26/15 14:53 100-41-40.0010 0.00030 1
Hexachloro-1,3-butadiene ND mg/L 06/26/15 14:53 87-68-30.0010 0.00071 1
Isopropylbenzene (Cumene)ND mg/L 06/26/15 14:53 98-82-80.0010 0.00040 1
p-Isopropyltoluene ND mg/L 06/26/15 14:53 99-87-60.0010 0.00031 1
Methylene Chloride ND mg/L 06/26/15 14:53 75-09-20.0020 0.00097 1
Methyl-tert-butyl ether ND mg/L 06/26/15 14:53 1634-04-40.0010 0.00021 1
Naphthalene ND mg/L 06/26/15 14:53 91-20-30.0010 0.00024 1
n-Propylbenzene ND mg/L 06/26/15 14:53 103-65-10.0010 0.00042 1
Styrene ND mg/L 06/26/15 14:53 100-42-50.0010 0.00026 1
1,1,1,2-Tetrachloroethane ND mg/L 06/26/15 14:53 630-20-60.0010 0.00033 1
1,1,2,2-Tetrachloroethane ND mg/L 06/26/15 14:53 79-34-50.0010 0.00040 1
Tetrachloroethene ND mg/L 06/26/15 14:53 127-18-40.0010 0.00046 1
Tetrahydrofuran ND mg/L 06/26/15 14:53 109-99-90.010 0.0031 1
Toluene ND mg/L 06/26/15 14:53 108-88-30.0010 0.00026 1
1,2,3-Trichlorobenzene ND mg/L 06/26/15 14:53 87-61-60.0010 0.00033 1
1,2,4-Trichlorobenzene ND mg/L 06/26/15 14:53 120-82-10.0010 0.00035 1
1,1,1-Trichloroethane ND mg/L 06/26/15 14:53 71-55-60.0010 0.00048 1
1,1,2-Trichloroethane ND mg/L 06/26/15 14:53 79-00-50.0010 0.00029 1
Trichloroethene ND mg/L 06/26/15 14:53 79-01-60.0010 0.00047 1
Trichlorofluoromethane ND mg/L 06/26/15 14:53 75-69-40.0010 0.00020 1
1,2,3-Trichloropropane ND mg/L 06/26/15 14:53 96-18-40.0010 0.00041 1
1,2,4-Trimethylbenzene ND mg/L 06/26/15 14:53 95-63-60.0010 0.00031 1
1,3,5-Trimethylbenzene ND mg/L 06/26/15 14:53 108-67-80.0010 0.00036 1
Vinyl acetate ND mg/L 06/26/15 14:53 108-05-40.0020 0.00035 1
Vinyl chloride ND mg/L 06/26/15 14:53 75-01-40.0010 0.00062 1
Xylene (Total)ND mg/L 06/26/15 14:53 1330-20-70.0020 0.00066 1
m&p-Xylene ND mg/L 06/26/15 14:53 179601-23-10.0020 0.00066 1
o-Xylene ND mg/L 06/26/15 14:53 95-47-60.0010 0.00023 1
Surrogates
4-Bromofluorobenzene (S)102 %06/26/15 14:53 460-00-470-130 1
1,2-Dichloroethane-d4 (S)111 %06/26/15 14:53 17060-07-070-130 1
Toluene-d8 (S)102 %06/26/15 14:53 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 17 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Sample:WD-5 Lab ID:92255880008 Collected:06/24/15 15:00 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP
Arsenic ND mg/L 06/29/15 20:44 7440-38-206/26/15 19:150.010 0.0050 1
Barium 1.0 mg/L 06/29/15 20:44 7440-39-306/26/15 19:150.0050 0.0025 1
Cadmium ND mg/L 06/29/15 20:44 7440-43-906/26/15 19:150.0010 0.000050 1
Chromium 0.028 mg/L 06/29/15 20:44 7440-47-306/26/15 19:150.0050 0.0025 1
Lead 0.0086 mg/L 06/29/15 20:44 7439-92-106/26/15 19:150.0050 0.0025 1
Selenium ND mg/L 06/29/15 20:44 7782-49-206/26/15 19:150.010 0.0050 1
Silver ND mg/L 06/29/15 20:44 7440-22-406/26/15 19:150.0050 0.0025 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND mg/L 07/02/15 13:06 7439-97-606/30/15 17:450.00020 0.00010 1
Analytical Method: EPA 82608260 MSV Low Level
Benzene ND mg/L 06/26/15 15:11 71-43-20.0010 0.00025 1
Bromobenzene ND mg/L 06/26/15 15:11 108-86-10.0010 0.00030 1
Bromochloromethane ND mg/L 06/26/15 15:11 74-97-50.0010 0.00017 1
Bromodichloromethane ND mg/L 06/26/15 15:11 75-27-40.0010 0.00018 1
Bromoform ND mg/L 06/26/15 15:11 75-25-20.0010 0.00026 1
Bromomethane ND mg/L 06/26/15 15:11 74-83-90.0020 0.00029 1
n-Butylbenzene ND mg/L 06/26/15 15:11 104-51-80.0010 0.00041 1
sec-Butylbenzene ND mg/L 06/26/15 15:11 135-98-80.0010 0.00038 1
tert-Butylbenzene ND mg/L 06/26/15 15:11 98-06-60.0010 0.00040 1
Carbon tetrachloride ND mg/L 06/26/15 15:11 56-23-50.0010 0.00025 1
Chlorobenzene ND mg/L 06/26/15 15:11 108-90-70.0010 0.00023 1
Chloroethane ND mg/L 06/26/15 15:11 75-00-30.0010 0.00054 1
Chloroform ND mg/L 06/26/15 15:11 67-66-30.0010 0.00014 1
Chloromethane ND mg/L 06/26/15 15:11 74-87-30.0010 0.00011 1
2-Chlorotoluene ND mg/L 06/26/15 15:11 95-49-80.0010 0.00035 1
4-Chlorotoluene ND mg/L 06/26/15 15:11 106-43-40.0010 0.00031 1
Dibromochloromethane ND mg/L 06/26/15 15:11 124-48-10.0010 0.00021 1
1,2-Dibromoethane (EDB)ND mg/L 06/26/15 15:11 106-93-40.0010 0.00027 1
Dibromomethane ND mg/L 06/26/15 15:11 74-95-30.0010 0.00021 1
1,2-Dichlorobenzene ND mg/L 06/26/15 15:11 95-50-10.0010 0.00030 1
1,3-Dichlorobenzene ND mg/L 06/26/15 15:11 541-73-10.0010 0.00024 1
1,4-Dichlorobenzene ND mg/L 06/26/15 15:11 106-46-70.0010 0.00033 1
Dichlorodifluoromethane ND mg/L 06/26/15 15:11 75-71-80.0010 0.00021 1
1,1-Dichloroethane ND mg/L 06/26/15 15:11 75-34-30.0010 0.00032 1
1,2-Dichloroethane ND mg/L 06/26/15 15:11 107-06-20.0010 0.00012 1
1,2-Dichloroethene (Total)ND mg/L 06/26/15 15:11 540-59-00.0010 0.00049 1
1,1-Dichloroethene ND mg/L 06/26/15 15:11 75-35-40.0010 0.00056 1
cis-1,2-Dichloroethene ND mg/L 06/26/15 15:11 156-59-20.0010 0.00019 1
trans-1,2-Dichloroethene ND mg/L 06/26/15 15:11 156-60-50.0010 0.00049 1
1,2-Dichloropropane ND mg/L 06/26/15 15:11 78-87-50.0010 0.00027 1
1,3-Dichloropropane ND mg/L 06/26/15 15:11 142-28-90.0010 0.00028 1
2,2-Dichloropropane ND mg/L 06/26/15 15:11 594-20-70.0010 0.00013 1
1,1-Dichloropropene ND mg/L 06/26/15 15:11 563-58-60.0010 0.00049 1
Diisopropyl ether ND mg/L 06/26/15 15:11 108-20-30.0010 0.00012 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 18 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Sample:WD-5 Lab ID:92255880008 Collected:06/24/15 15:00 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Ethylbenzene ND mg/L 06/26/15 15:11 100-41-40.0010 0.00030 1
Hexachloro-1,3-butadiene ND mg/L 06/26/15 15:11 87-68-30.0010 0.00071 1
Isopropylbenzene (Cumene)ND mg/L 06/26/15 15:11 98-82-80.0010 0.00040 1
p-Isopropyltoluene ND mg/L 06/26/15 15:11 99-87-60.0010 0.00031 1
Methylene Chloride ND mg/L 06/26/15 15:11 75-09-20.0020 0.00097 1
Methyl-tert-butyl ether ND mg/L 06/26/15 15:11 1634-04-40.0010 0.00021 1
Naphthalene ND mg/L 06/26/15 15:11 91-20-30.0010 0.00024 1
n-Propylbenzene ND mg/L 06/26/15 15:11 103-65-10.0010 0.00042 1
Styrene ND mg/L 06/26/15 15:11 100-42-50.0010 0.00026 1
1,1,1,2-Tetrachloroethane ND mg/L 06/26/15 15:11 630-20-60.0010 0.00033 1
1,1,2,2-Tetrachloroethane ND mg/L 06/26/15 15:11 79-34-50.0010 0.00040 1
Tetrachloroethene ND mg/L 06/26/15 15:11 127-18-40.0010 0.00046 1
Tetrahydrofuran ND mg/L 06/26/15 15:11 109-99-90.010 0.0031 1
Toluene ND mg/L 06/26/15 15:11 108-88-30.0010 0.00026 1
1,2,3-Trichlorobenzene ND mg/L 06/26/15 15:11 87-61-60.0010 0.00033 1
1,2,4-Trichlorobenzene ND mg/L 06/26/15 15:11 120-82-10.0010 0.00035 1
1,1,1-Trichloroethane ND mg/L 06/26/15 15:11 71-55-60.0010 0.00048 1
1,1,2-Trichloroethane ND mg/L 06/26/15 15:11 79-00-50.0010 0.00029 1
Trichloroethene ND mg/L 06/26/15 15:11 79-01-60.0010 0.00047 1
Trichlorofluoromethane ND mg/L 06/26/15 15:11 75-69-40.0010 0.00020 1
1,2,3-Trichloropropane ND mg/L 06/26/15 15:11 96-18-40.0010 0.00041 1
1,2,4-Trimethylbenzene ND mg/L 06/26/15 15:11 95-63-60.0010 0.00031 1
1,3,5-Trimethylbenzene ND mg/L 06/26/15 15:11 108-67-80.0010 0.00036 1
Vinyl acetate ND mg/L 06/26/15 15:11 108-05-40.0020 0.00035 1
Vinyl chloride ND mg/L 06/26/15 15:11 75-01-40.0010 0.00062 1
Xylene (Total)ND mg/L 06/26/15 15:11 1330-20-70.0020 0.00066 1
m&p-Xylene ND mg/L 06/26/15 15:11 179601-23-10.0020 0.00066 1
o-Xylene ND mg/L 06/26/15 15:11 95-47-60.0010 0.00023 1
Surrogates
4-Bromofluorobenzene (S)103 %06/26/15 15:11 460-00-470-130 1
1,2-Dichloroethane-d4 (S)115 %06/26/15 15:11 17060-07-070-130 1
Toluene-d8 (S)103 %06/26/15 15:11 2037-26-570-130 1
Sample:WD-6 Lab ID:92255880009 Collected:06/24/15 15:30 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP
Arsenic ND mg/L 06/29/15 20:47 7440-38-206/26/15 19:150.010 0.0050 1
Barium 0.37 mg/L 06/29/15 20:47 7440-39-306/26/15 19:150.0050 0.0025 1
Cadmium 0.0067 mg/L 06/29/15 20:47 7440-43-906/26/15 19:150.0010 0.000050 1
Chromium 0.012 mg/L 06/29/15 20:47 7440-47-306/26/15 19:150.0050 0.0025 1
Lead 0.0073 mg/L 06/29/15 20:47 7439-92-106/26/15 19:150.0050 0.0025 1
Selenium ND mg/L 06/29/15 20:47 7782-49-206/26/15 19:150.010 0.0050 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 19 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Sample:WD-6 Lab ID:92255880009 Collected:06/24/15 15:30 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP
Silver ND mg/L 06/29/15 20:47 7440-22-406/26/15 19:150.0050 0.0025 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND mg/L 07/02/15 13:13 7439-97-606/30/15 17:450.00020 0.00010 1
Analytical Method: EPA 82608260 MSV Low Level
Benzene ND mg/L 06/26/15 15:30 71-43-20.0010 0.00025 1
Bromobenzene ND mg/L 06/26/15 15:30 108-86-10.0010 0.00030 1
Bromochloromethane ND mg/L 06/26/15 15:30 74-97-50.0010 0.00017 1
Bromodichloromethane ND mg/L 06/26/15 15:30 75-27-40.0010 0.00018 1
Bromoform ND mg/L 06/26/15 15:30 75-25-20.0010 0.00026 1
Bromomethane ND mg/L 06/26/15 15:30 74-83-90.0020 0.00029 1
n-Butylbenzene ND mg/L 06/26/15 15:30 104-51-80.0010 0.00041 1
sec-Butylbenzene ND mg/L 06/26/15 15:30 135-98-80.0010 0.00038 1
tert-Butylbenzene ND mg/L 06/26/15 15:30 98-06-60.0010 0.00040 1
Carbon tetrachloride ND mg/L 06/26/15 15:30 56-23-50.0010 0.00025 1
Chlorobenzene ND mg/L 06/26/15 15:30 108-90-70.0010 0.00023 1
Chloroethane ND mg/L 06/26/15 15:30 75-00-30.0010 0.00054 1
Chloroform ND mg/L 06/26/15 15:30 67-66-30.0010 0.00014 1
Chloromethane ND mg/L 06/26/15 15:30 74-87-30.0010 0.00011 1
2-Chlorotoluene ND mg/L 06/26/15 15:30 95-49-80.0010 0.00035 1
4-Chlorotoluene ND mg/L 06/26/15 15:30 106-43-40.0010 0.00031 1
Dibromochloromethane ND mg/L 06/26/15 15:30 124-48-10.0010 0.00021 1
1,2-Dibromoethane (EDB)ND mg/L 06/26/15 15:30 106-93-40.0010 0.00027 1
Dibromomethane ND mg/L 06/26/15 15:30 74-95-30.0010 0.00021 1
1,2-Dichlorobenzene ND mg/L 06/26/15 15:30 95-50-10.0010 0.00030 1
1,3-Dichlorobenzene ND mg/L 06/26/15 15:30 541-73-10.0010 0.00024 1
1,4-Dichlorobenzene ND mg/L 06/26/15 15:30 106-46-70.0010 0.00033 1
Dichlorodifluoromethane ND mg/L 06/26/15 15:30 75-71-80.0010 0.00021 1
1,1-Dichloroethane ND mg/L 06/26/15 15:30 75-34-30.0010 0.00032 1
1,2-Dichloroethane ND mg/L 06/26/15 15:30 107-06-20.0010 0.00012 1
1,2-Dichloroethene (Total)ND mg/L 06/26/15 15:30 540-59-00.0010 0.00049 1
1,1-Dichloroethene ND mg/L 06/26/15 15:30 75-35-40.0010 0.00056 1
cis-1,2-Dichloroethene ND mg/L 06/26/15 15:30 156-59-20.0010 0.00019 1
trans-1,2-Dichloroethene ND mg/L 06/26/15 15:30 156-60-50.0010 0.00049 1
1,2-Dichloropropane ND mg/L 06/26/15 15:30 78-87-50.0010 0.00027 1
1,3-Dichloropropane ND mg/L 06/26/15 15:30 142-28-90.0010 0.00028 1
2,2-Dichloropropane ND mg/L 06/26/15 15:30 594-20-70.0010 0.00013 1
1,1-Dichloropropene ND mg/L 06/26/15 15:30 563-58-60.0010 0.00049 1
Diisopropyl ether ND mg/L 06/26/15 15:30 108-20-30.0010 0.00012 1
Ethylbenzene ND mg/L 06/26/15 15:30 100-41-40.0010 0.00030 1
Hexachloro-1,3-butadiene ND mg/L 06/26/15 15:30 87-68-30.0010 0.00071 1
Isopropylbenzene (Cumene)ND mg/L 06/26/15 15:30 98-82-80.0010 0.00040 1
p-Isopropyltoluene ND mg/L 06/26/15 15:30 99-87-60.0010 0.00031 1
Methylene Chloride ND mg/L 06/26/15 15:30 75-09-20.0020 0.00097 1
Methyl-tert-butyl ether ND mg/L 06/26/15 15:30 1634-04-40.0010 0.00021 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 20 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Sample:WD-6 Lab ID:92255880009 Collected:06/24/15 15:30 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Naphthalene ND mg/L 06/26/15 15:30 91-20-30.0010 0.00024 1
n-Propylbenzene ND mg/L 06/26/15 15:30 103-65-10.0010 0.00042 1
Styrene ND mg/L 06/26/15 15:30 100-42-50.0010 0.00026 1
1,1,1,2-Tetrachloroethane ND mg/L 06/26/15 15:30 630-20-60.0010 0.00033 1
1,1,2,2-Tetrachloroethane ND mg/L 06/26/15 15:30 79-34-50.0010 0.00040 1
Tetrachloroethene ND mg/L 06/26/15 15:30 127-18-40.0010 0.00046 1
Tetrahydrofuran ND mg/L 06/26/15 15:30 109-99-90.010 0.0031 1
Toluene ND mg/L 06/26/15 15:30 108-88-30.0010 0.00026 1
1,2,3-Trichlorobenzene ND mg/L 06/26/15 15:30 87-61-60.0010 0.00033 1
1,2,4-Trichlorobenzene ND mg/L 06/26/15 15:30 120-82-10.0010 0.00035 1
1,1,1-Trichloroethane ND mg/L 06/26/15 15:30 71-55-60.0010 0.00048 1
1,1,2-Trichloroethane ND mg/L 06/26/15 15:30 79-00-50.0010 0.00029 1
Trichloroethene ND mg/L 06/26/15 15:30 79-01-60.0010 0.00047 1
Trichlorofluoromethane ND mg/L 06/26/15 15:30 75-69-40.0010 0.00020 1
1,2,3-Trichloropropane ND mg/L 06/26/15 15:30 96-18-40.0010 0.00041 1
1,2,4-Trimethylbenzene ND mg/L 06/26/15 15:30 95-63-60.0010 0.00031 1
1,3,5-Trimethylbenzene ND mg/L 06/26/15 15:30 108-67-80.0010 0.00036 1
Vinyl acetate ND mg/L 06/26/15 15:30 108-05-40.0020 0.00035 1
Vinyl chloride ND mg/L 06/26/15 15:30 75-01-40.0010 0.00062 1
Xylene (Total)ND mg/L 06/26/15 15:30 1330-20-70.0020 0.00066 1
m&p-Xylene ND mg/L 06/26/15 15:30 179601-23-10.0020 0.00066 1
o-Xylene ND mg/L 06/26/15 15:30 95-47-60.0010 0.00023 1
Surrogates
4-Bromofluorobenzene (S)105 %06/26/15 15:30 460-00-470-130 1
1,2-Dichloroethane-d4 (S)110 %06/26/15 15:30 17060-07-070-130 1
Toluene-d8 (S)100 %06/26/15 15:30 2037-26-570-130 1
Sample:WD-7 Lab ID:92255880010 Collected:06/24/15 10:30 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP
Arsenic ND mg/L 06/29/15 20:51 7440-38-206/26/15 19:150.010 0.0050 1
Barium 0.29 mg/L 06/29/15 20:51 7440-39-306/26/15 19:150.0050 0.0025 1
Cadmium ND mg/L 06/29/15 20:51 7440-43-906/26/15 19:150.0010 0.000050 1
Chromium 0.072 mg/L 06/29/15 20:51 7440-47-306/26/15 19:150.0050 0.0025 1
Lead ND mg/L 06/29/15 20:51 7439-92-106/26/15 19:150.0050 0.0025 1
Selenium ND mg/L 06/29/15 20:51 7782-49-206/26/15 19:150.010 0.0050 1
Silver ND mg/L 06/29/15 20:51 7440-22-406/26/15 19:150.0050 0.0025 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND mg/L 07/02/15 13:15 7439-97-606/30/15 17:450.00020 0.00010 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 21 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Sample:WD-7 Lab ID:92255880010 Collected:06/24/15 10:30 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Benzene ND mg/L 06/26/15 15:48 71-43-20.0010 0.00025 1
Bromobenzene ND mg/L 06/26/15 15:48 108-86-10.0010 0.00030 1
Bromochloromethane ND mg/L 06/26/15 15:48 74-97-50.0010 0.00017 1
Bromodichloromethane ND mg/L 06/26/15 15:48 75-27-40.0010 0.00018 1
Bromoform ND mg/L 06/26/15 15:48 75-25-20.0010 0.00026 1
Bromomethane ND mg/L 06/26/15 15:48 74-83-90.0020 0.00029 1
n-Butylbenzene ND mg/L 06/26/15 15:48 104-51-80.0010 0.00041 1
sec-Butylbenzene ND mg/L 06/26/15 15:48 135-98-80.0010 0.00038 1
tert-Butylbenzene ND mg/L 06/26/15 15:48 98-06-60.0010 0.00040 1
Carbon tetrachloride ND mg/L 06/26/15 15:48 56-23-50.0010 0.00025 1
Chlorobenzene ND mg/L 06/26/15 15:48 108-90-70.0010 0.00023 1
Chloroethane ND mg/L 06/26/15 15:48 75-00-30.0010 0.00054 1
Chloroform ND mg/L 06/26/15 15:48 67-66-30.0010 0.00014 1
Chloromethane ND mg/L 06/26/15 15:48 74-87-30.0010 0.00011 1
2-Chlorotoluene ND mg/L 06/26/15 15:48 95-49-80.0010 0.00035 1
4-Chlorotoluene ND mg/L 06/26/15 15:48 106-43-40.0010 0.00031 1
Dibromochloromethane ND mg/L 06/26/15 15:48 124-48-10.0010 0.00021 1
1,2-Dibromoethane (EDB)ND mg/L 06/26/15 15:48 106-93-40.0010 0.00027 1
Dibromomethane ND mg/L 06/26/15 15:48 74-95-30.0010 0.00021 1
1,2-Dichlorobenzene ND mg/L 06/26/15 15:48 95-50-10.0010 0.00030 1
1,3-Dichlorobenzene ND mg/L 06/26/15 15:48 541-73-10.0010 0.00024 1
1,4-Dichlorobenzene ND mg/L 06/26/15 15:48 106-46-70.0010 0.00033 1
Dichlorodifluoromethane ND mg/L 06/26/15 15:48 75-71-80.0010 0.00021 1
1,1-Dichloroethane ND mg/L 06/26/15 15:48 75-34-30.0010 0.00032 1
1,2-Dichloroethane ND mg/L 06/26/15 15:48 107-06-20.0010 0.00012 1
1,2-Dichloroethene (Total)ND mg/L 06/26/15 15:48 540-59-00.0010 0.00049 1
1,1-Dichloroethene ND mg/L 06/26/15 15:48 75-35-40.0010 0.00056 1
cis-1,2-Dichloroethene ND mg/L 06/26/15 15:48 156-59-20.0010 0.00019 1
trans-1,2-Dichloroethene ND mg/L 06/26/15 15:48 156-60-50.0010 0.00049 1
1,2-Dichloropropane ND mg/L 06/26/15 15:48 78-87-50.0010 0.00027 1
1,3-Dichloropropane ND mg/L 06/26/15 15:48 142-28-90.0010 0.00028 1
2,2-Dichloropropane ND mg/L 06/26/15 15:48 594-20-70.0010 0.00013 1
1,1-Dichloropropene ND mg/L 06/26/15 15:48 563-58-60.0010 0.00049 1
Diisopropyl ether ND mg/L 06/26/15 15:48 108-20-30.0010 0.00012 1
Ethylbenzene ND mg/L 06/26/15 15:48 100-41-40.0010 0.00030 1
Hexachloro-1,3-butadiene ND mg/L 06/26/15 15:48 87-68-30.0010 0.00071 1
Isopropylbenzene (Cumene)ND mg/L 06/26/15 15:48 98-82-80.0010 0.00040 1
p-Isopropyltoluene ND mg/L 06/26/15 15:48 99-87-60.0010 0.00031 1
Methylene Chloride ND mg/L 06/26/15 15:48 75-09-20.0020 0.00097 1
Methyl-tert-butyl ether ND mg/L 06/26/15 15:48 1634-04-40.0010 0.00021 1
Naphthalene ND mg/L 06/26/15 15:48 91-20-30.0010 0.00024 1
n-Propylbenzene ND mg/L 06/26/15 15:48 103-65-10.0010 0.00042 1
Styrene ND mg/L 06/26/15 15:48 100-42-50.0010 0.00026 1
1,1,1,2-Tetrachloroethane ND mg/L 06/26/15 15:48 630-20-60.0010 0.00033 1
1,1,2,2-Tetrachloroethane ND mg/L 06/26/15 15:48 79-34-50.0010 0.00040 1
Tetrachloroethene ND mg/L 06/26/15 15:48 127-18-40.0010 0.00046 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 22 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Sample:WD-7 Lab ID:92255880010 Collected:06/24/15 10:30 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Tetrahydrofuran ND mg/L 06/26/15 15:48 109-99-90.010 0.0031 1
Toluene ND mg/L 06/26/15 15:48 108-88-30.0010 0.00026 1
1,2,3-Trichlorobenzene ND mg/L 06/26/15 15:48 87-61-60.0010 0.00033 1
1,2,4-Trichlorobenzene ND mg/L 06/26/15 15:48 120-82-10.0010 0.00035 1
1,1,1-Trichloroethane ND mg/L 06/26/15 15:48 71-55-60.0010 0.00048 1
1,1,2-Trichloroethane ND mg/L 06/26/15 15:48 79-00-50.0010 0.00029 1
Trichloroethene ND mg/L 06/26/15 15:48 79-01-60.0010 0.00047 1
Trichlorofluoromethane ND mg/L 06/26/15 15:48 75-69-40.0010 0.00020 1
1,2,3-Trichloropropane ND mg/L 06/26/15 15:48 96-18-40.0010 0.00041 1
1,2,4-Trimethylbenzene ND mg/L 06/26/15 15:48 95-63-60.0010 0.00031 1
1,3,5-Trimethylbenzene ND mg/L 06/26/15 15:48 108-67-80.0010 0.00036 1
Vinyl acetate ND mg/L 06/26/15 15:48 108-05-40.0020 0.00035 1
Vinyl chloride ND mg/L 06/26/15 15:48 75-01-40.0010 0.00062 1
Xylene (Total)ND mg/L 06/26/15 15:48 1330-20-70.0020 0.00066 1
m&p-Xylene ND mg/L 06/26/15 15:48 179601-23-10.0020 0.00066 1
o-Xylene ND mg/L 06/26/15 15:48 95-47-60.0010 0.00023 1
Surrogates
4-Bromofluorobenzene (S)104 %06/26/15 15:48 460-00-470-130 1
1,2-Dichloroethane-d4 (S)111 %06/26/15 15:48 17060-07-070-130 1
Toluene-d8 (S)114 %06/26/15 15:48 2037-26-570-130 1
Sample:SS1-UPGRADIENT Lab ID:92255880011 Collected:06/24/15 12:00 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP
Arsenic ND mg/L 06/29/15 20:54 7440-38-206/26/15 19:150.010 0.0050 1
Barium 0.10 mg/L 06/29/15 20:54 7440-39-306/26/15 19:150.0050 0.0025 1
Cadmium ND mg/L 06/29/15 20:54 7440-43-906/26/15 19:150.0010 0.000050 1
Chromium ND mg/L 06/29/15 20:54 7440-47-306/26/15 19:150.0050 0.0025 1
Lead ND mg/L 06/29/15 20:54 7439-92-106/26/15 19:150.0050 0.0025 1
Selenium ND mg/L 06/29/15 20:54 7782-49-206/26/15 19:150.010 0.0050 1
Silver ND mg/L 06/29/15 20:54 7440-22-406/26/15 19:150.0050 0.0025 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND mg/L 07/02/15 13:18 7439-97-606/30/15 17:450.00020 0.00010 1
Analytical Method: EPA 82608260 MSV Low Level
Benzene ND mg/L 06/26/15 16:06 71-43-20.0010 0.00025 1
Bromobenzene ND mg/L 06/26/15 16:06 108-86-10.0010 0.00030 1
Bromochloromethane ND mg/L 06/26/15 16:06 74-97-50.0010 0.00017 1
Bromodichloromethane ND mg/L 06/26/15 16:06 75-27-40.0010 0.00018 1
Bromoform ND mg/L 06/26/15 16:06 75-25-20.0010 0.00026 1
Bromomethane ND mg/L 06/26/15 16:06 74-83-90.0020 0.00029 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 23 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Sample:SS1-UPGRADIENT Lab ID:92255880011 Collected:06/24/15 12:00 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
n-Butylbenzene ND mg/L 06/26/15 16:06 104-51-80.0010 0.00041 1
sec-Butylbenzene ND mg/L 06/26/15 16:06 135-98-80.0010 0.00038 1
tert-Butylbenzene ND mg/L 06/26/15 16:06 98-06-60.0010 0.00040 1
Carbon tetrachloride ND mg/L 06/26/15 16:06 56-23-50.0010 0.00025 1
Chlorobenzene ND mg/L 06/26/15 16:06 108-90-70.0010 0.00023 1
Chloroethane ND mg/L 06/26/15 16:06 75-00-30.0010 0.00054 1
Chloroform ND mg/L 06/26/15 16:06 67-66-30.0010 0.00014 1
Chloromethane ND mg/L 06/26/15 16:06 74-87-30.0010 0.00011 1
2-Chlorotoluene ND mg/L 06/26/15 16:06 95-49-80.0010 0.00035 1
4-Chlorotoluene ND mg/L 06/26/15 16:06 106-43-40.0010 0.00031 1
Dibromochloromethane ND mg/L 06/26/15 16:06 124-48-10.0010 0.00021 1
1,2-Dibromoethane (EDB)ND mg/L 06/26/15 16:06 106-93-40.0010 0.00027 1
Dibromomethane ND mg/L 06/26/15 16:06 74-95-30.0010 0.00021 1
1,2-Dichlorobenzene ND mg/L 06/26/15 16:06 95-50-10.0010 0.00030 1
1,3-Dichlorobenzene ND mg/L 06/26/15 16:06 541-73-10.0010 0.00024 1
1,4-Dichlorobenzene ND mg/L 06/26/15 16:06 106-46-70.0010 0.00033 1
Dichlorodifluoromethane ND mg/L 06/26/15 16:06 75-71-80.0010 0.00021 1
1,1-Dichloroethane ND mg/L 06/26/15 16:06 75-34-30.0010 0.00032 1
1,2-Dichloroethane ND mg/L 06/26/15 16:06 107-06-20.0010 0.00012 1
1,2-Dichloroethene (Total)ND mg/L 06/26/15 16:06 540-59-00.0010 0.00049 1
1,1-Dichloroethene ND mg/L 06/26/15 16:06 75-35-40.0010 0.00056 1
cis-1,2-Dichloroethene ND mg/L 06/26/15 16:06 156-59-20.0010 0.00019 1
trans-1,2-Dichloroethene ND mg/L 06/26/15 16:06 156-60-50.0010 0.00049 1
1,2-Dichloropropane ND mg/L 06/26/15 16:06 78-87-50.0010 0.00027 1
1,3-Dichloropropane ND mg/L 06/26/15 16:06 142-28-90.0010 0.00028 1
2,2-Dichloropropane ND mg/L 06/26/15 16:06 594-20-70.0010 0.00013 1
1,1-Dichloropropene ND mg/L 06/26/15 16:06 563-58-60.0010 0.00049 1
Diisopropyl ether ND mg/L 06/26/15 16:06 108-20-30.0010 0.00012 1
Ethylbenzene ND mg/L 06/26/15 16:06 100-41-40.0010 0.00030 1
Hexachloro-1,3-butadiene ND mg/L 06/26/15 16:06 87-68-30.0010 0.00071 1
Isopropylbenzene (Cumene)ND mg/L 06/26/15 16:06 98-82-80.0010 0.00040 1
p-Isopropyltoluene ND mg/L 06/26/15 16:06 99-87-60.0010 0.00031 1
Methylene Chloride ND mg/L 06/26/15 16:06 75-09-20.0020 0.00097 1
Methyl-tert-butyl ether ND mg/L 06/26/15 16:06 1634-04-40.0010 0.00021 1
Naphthalene ND mg/L 06/26/15 16:06 91-20-30.0010 0.00024 1
n-Propylbenzene ND mg/L 06/26/15 16:06 103-65-10.0010 0.00042 1
Styrene ND mg/L 06/26/15 16:06 100-42-50.0010 0.00026 1
1,1,1,2-Tetrachloroethane ND mg/L 06/26/15 16:06 630-20-60.0010 0.00033 1
1,1,2,2-Tetrachloroethane ND mg/L 06/26/15 16:06 79-34-50.0010 0.00040 1
Tetrachloroethene ND mg/L 06/26/15 16:06 127-18-40.0010 0.00046 1
Tetrahydrofuran ND mg/L 06/26/15 16:06 109-99-90.010 0.0031 1
Toluene ND mg/L 06/26/15 16:06 108-88-30.0010 0.00026 1
1,2,3-Trichlorobenzene ND mg/L 06/26/15 16:06 87-61-60.0010 0.00033 1
1,2,4-Trichlorobenzene ND mg/L 06/26/15 16:06 120-82-10.0010 0.00035 1
1,1,1-Trichloroethane ND mg/L 06/26/15 16:06 71-55-60.0010 0.00048 1
1,1,2-Trichloroethane ND mg/L 06/26/15 16:06 79-00-50.0010 0.00029 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 24 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Sample:SS1-UPGRADIENT Lab ID:92255880011 Collected:06/24/15 12:00 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Trichloroethene ND mg/L 06/26/15 16:06 79-01-60.0010 0.00047 1
Trichlorofluoromethane ND mg/L 06/26/15 16:06 75-69-40.0010 0.00020 1
1,2,3-Trichloropropane ND mg/L 06/26/15 16:06 96-18-40.0010 0.00041 1
1,2,4-Trimethylbenzene ND mg/L 06/26/15 16:06 95-63-60.0010 0.00031 1
1,3,5-Trimethylbenzene ND mg/L 06/26/15 16:06 108-67-80.0010 0.00036 1
Vinyl acetate ND mg/L 06/26/15 16:06 108-05-40.0020 0.00035 1
Vinyl chloride ND mg/L 06/26/15 16:06 75-01-40.0010 0.00062 1
Xylene (Total)ND mg/L 06/26/15 16:06 1330-20-70.0020 0.00066 1
m&p-Xylene ND mg/L 06/26/15 16:06 179601-23-10.0020 0.00066 1
o-Xylene ND mg/L 06/26/15 16:06 95-47-60.0010 0.00023 1
Surrogates
4-Bromofluorobenzene (S)103 %06/26/15 16:06 460-00-470-130 1
1,2-Dichloroethane-d4 (S)117 %06/26/15 16:06 17060-07-070-130 1
Toluene-d8 (S)108 %06/26/15 16:06 2037-26-570-130 1
Sample:SS-2 DOWNGRADIENT Lab ID:92255880012 Collected:06/24/15 12:15 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP
Arsenic ND mg/L 06/29/15 20:58 7440-38-206/26/15 19:150.010 0.0050 1
Barium 0.11 mg/L 06/29/15 20:58 7440-39-306/26/15 19:150.0050 0.0025 1
Cadmium ND mg/L 06/29/15 20:58 7440-43-906/26/15 19:150.0010 0.000050 1
Chromium ND mg/L 06/29/15 20:58 7440-47-306/26/15 19:150.0050 0.0025 1
Lead ND mg/L 06/29/15 20:58 7439-92-106/26/15 19:150.0050 0.0025 1
Selenium ND mg/L 06/29/15 20:58 7782-49-206/26/15 19:150.010 0.0050 1
Silver ND mg/L 06/29/15 20:58 7440-22-406/26/15 19:150.0050 0.0025 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND mg/L 07/02/15 13:20 7439-97-606/30/15 17:450.00020 0.00010 1
Analytical Method: EPA 82608260 MSV Low Level
Benzene ND mg/L 06/26/15 16:24 71-43-20.0010 0.00025 1
Bromobenzene ND mg/L 06/26/15 16:24 108-86-10.0010 0.00030 1
Bromochloromethane ND mg/L 06/26/15 16:24 74-97-50.0010 0.00017 1
Bromodichloromethane ND mg/L 06/26/15 16:24 75-27-40.0010 0.00018 1
Bromoform ND mg/L 06/26/15 16:24 75-25-20.0010 0.00026 1
Bromomethane ND mg/L 06/26/15 16:24 74-83-90.0020 0.00029 1
n-Butylbenzene ND mg/L 06/26/15 16:24 104-51-80.0010 0.00041 1
sec-Butylbenzene ND mg/L 06/26/15 16:24 135-98-80.0010 0.00038 1
tert-Butylbenzene ND mg/L 06/26/15 16:24 98-06-60.0010 0.00040 1
Carbon tetrachloride ND mg/L 06/26/15 16:24 56-23-50.0010 0.00025 1
Chlorobenzene ND mg/L 06/26/15 16:24 108-90-70.0010 0.00023 1
Chloroethane ND mg/L 06/26/15 16:24 75-00-30.0010 0.00054 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 25 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Sample:SS-2 DOWNGRADIENT Lab ID:92255880012 Collected:06/24/15 12:15 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Chloroform ND mg/L 06/26/15 16:24 67-66-30.0010 0.00014 1
Chloromethane ND mg/L 06/26/15 16:24 74-87-30.0010 0.00011 1
2-Chlorotoluene ND mg/L 06/26/15 16:24 95-49-80.0010 0.00035 1
4-Chlorotoluene ND mg/L 06/26/15 16:24 106-43-40.0010 0.00031 1
Dibromochloromethane ND mg/L 06/26/15 16:24 124-48-10.0010 0.00021 1
1,2-Dibromoethane (EDB)ND mg/L 06/26/15 16:24 106-93-40.0010 0.00027 1
Dibromomethane ND mg/L 06/26/15 16:24 74-95-30.0010 0.00021 1
1,2-Dichlorobenzene ND mg/L 06/26/15 16:24 95-50-10.0010 0.00030 1
1,3-Dichlorobenzene ND mg/L 06/26/15 16:24 541-73-10.0010 0.00024 1
1,4-Dichlorobenzene ND mg/L 06/26/15 16:24 106-46-70.0010 0.00033 1
Dichlorodifluoromethane ND mg/L 06/26/15 16:24 75-71-80.0010 0.00021 1
1,1-Dichloroethane ND mg/L 06/26/15 16:24 75-34-30.0010 0.00032 1
1,2-Dichloroethane ND mg/L 06/26/15 16:24 107-06-20.0010 0.00012 1
1,2-Dichloroethene (Total)ND mg/L 06/26/15 16:24 540-59-00.0010 0.00049 1
1,1-Dichloroethene ND mg/L 06/26/15 16:24 75-35-40.0010 0.00056 1
cis-1,2-Dichloroethene ND mg/L 06/26/15 16:24 156-59-20.0010 0.00019 1
trans-1,2-Dichloroethene ND mg/L 06/26/15 16:24 156-60-50.0010 0.00049 1
1,2-Dichloropropane ND mg/L 06/26/15 16:24 78-87-50.0010 0.00027 1
1,3-Dichloropropane ND mg/L 06/26/15 16:24 142-28-90.0010 0.00028 1
2,2-Dichloropropane ND mg/L 06/26/15 16:24 594-20-70.0010 0.00013 1
1,1-Dichloropropene ND mg/L 06/26/15 16:24 563-58-60.0010 0.00049 1
Diisopropyl ether ND mg/L 06/26/15 16:24 108-20-30.0010 0.00012 1
Ethylbenzene ND mg/L 06/26/15 16:24 100-41-40.0010 0.00030 1
Hexachloro-1,3-butadiene ND mg/L 06/26/15 16:24 87-68-30.0010 0.00071 1
Isopropylbenzene (Cumene)ND mg/L 06/26/15 16:24 98-82-80.0010 0.00040 1
p-Isopropyltoluene ND mg/L 06/26/15 16:24 99-87-60.0010 0.00031 1
Methylene Chloride ND mg/L 06/26/15 16:24 75-09-20.0020 0.00097 1
Methyl-tert-butyl ether ND mg/L 06/26/15 16:24 1634-04-40.0010 0.00021 1
Naphthalene ND mg/L 06/26/15 16:24 91-20-30.0010 0.00024 1
n-Propylbenzene ND mg/L 06/26/15 16:24 103-65-10.0010 0.00042 1
Styrene ND mg/L 06/26/15 16:24 100-42-50.0010 0.00026 1
1,1,1,2-Tetrachloroethane ND mg/L 06/26/15 16:24 630-20-60.0010 0.00033 1
1,1,2,2-Tetrachloroethane ND mg/L 06/26/15 16:24 79-34-50.0010 0.00040 1
Tetrachloroethene ND mg/L 06/26/15 16:24 127-18-40.0010 0.00046 1
Tetrahydrofuran ND mg/L 06/26/15 16:24 109-99-90.010 0.0031 1
Toluene ND mg/L 06/26/15 16:24 108-88-30.0010 0.00026 1
1,2,3-Trichlorobenzene ND mg/L 06/26/15 16:24 87-61-60.0010 0.00033 1
1,2,4-Trichlorobenzene ND mg/L 06/26/15 16:24 120-82-10.0010 0.00035 1
1,1,1-Trichloroethane ND mg/L 06/26/15 16:24 71-55-60.0010 0.00048 1
1,1,2-Trichloroethane ND mg/L 06/26/15 16:24 79-00-50.0010 0.00029 1
Trichloroethene ND mg/L 06/26/15 16:24 79-01-60.0010 0.00047 1
Trichlorofluoromethane ND mg/L 06/26/15 16:24 75-69-40.0010 0.00020 1
1,2,3-Trichloropropane ND mg/L 06/26/15 16:24 96-18-40.0010 0.00041 1
1,2,4-Trimethylbenzene ND mg/L 06/26/15 16:24 95-63-60.0010 0.00031 1
1,3,5-Trimethylbenzene ND mg/L 06/26/15 16:24 108-67-80.0010 0.00036 1
Vinyl acetate ND mg/L 06/26/15 16:24 108-05-40.0020 0.00035 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 26 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Sample:SS-2 DOWNGRADIENT Lab ID:92255880012 Collected:06/24/15 12:15 Received:06/24/15 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Vinyl chloride ND mg/L 06/26/15 16:24 75-01-40.0010 0.00062 1
Xylene (Total)ND mg/L 06/26/15 16:24 1330-20-70.0020 0.00066 1
m&p-Xylene ND mg/L 06/26/15 16:24 179601-23-10.0020 0.00066 1
o-Xylene ND mg/L 06/26/15 16:24 95-47-60.0010 0.00023 1
Surrogates
4-Bromofluorobenzene (S)102 %06/26/15 16:24 460-00-470-130 1
1,2-Dichloroethane-d4 (S)114 %06/26/15 16:24 17060-07-070-130 1
Toluene-d8 (S)100 %06/26/15 16:24 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 27 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/7990
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples:92255880001, 92255880002, 92255880003, 92255880004, 92255880005, 92255880006, 92255880007,
92255880008, 92255880009, 92255880010, 92255880011, 92255880012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1498526
Associated Lab Samples:92255880001, 92255880002, 92255880003, 92255880004, 92255880005, 92255880006, 92255880007,
92255880008, 92255880009, 92255880010, 92255880011, 92255880012
Matrix:Water
Analyzed
Mercury mg/L ND 0.00020 07/02/15 12:16
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1498527LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury mg/L 0.0026.0025 104 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1498528MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92253566005
1498529
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury mg/L .0025 102 75-125106 5 25.0025ND 0.0025 0.0027
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 28 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/18852
EPA 3010
EPA 6010
6010 MET
Associated Lab Samples:92255880001, 92255880002, 92255880003, 92255880004, 92255880005, 92255880006, 92255880007,
92255880008, 92255880009, 92255880010, 92255880011, 92255880012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1496467
Associated Lab Samples:92255880001, 92255880002, 92255880003, 92255880004, 92255880005, 92255880006, 92255880007,
92255880008, 92255880009, 92255880010, 92255880011, 92255880012
Matrix:Water
Analyzed
Arsenic mg/L ND 0.010 06/29/15 19:37
Barium mg/L ND 0.0050 06/29/15 19:37
Cadmium mg/L ND 0.0010 06/29/15 19:37
Chromium mg/L ND 0.0050 06/29/15 19:37
Lead mg/L ND 0.0050 06/29/15 19:37
Selenium mg/L ND 0.010 06/29/15 19:37
Silver mg/L ND 0.0050 06/29/15 19:37
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1496468LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic mg/L 0.46.5 93 80-120
Barium mg/L 0.47.5 93 80-120
Cadmium mg/L 0.47.5 94 80-120
Chromium mg/L 0.48.5 96 80-120
Lead mg/L 0.47.5 94 80-120
Selenium mg/L 0.45.5 90 80-120
Silver mg/L 0.24.25 95 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1496469MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92255964009
1496470
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Arsenic mg/L .5 93 75-12592 1 20.524.0 ug/L 0.49 0.48
Barium mg/L .5 93 75-12594 1 20.549.3 ug/L 0.51 0.52
Cadmium mg/L .5 91 75-12590 1 20.52.2 ug/L 0.46 0.45
Chromium mg/L .5 94 75-12595 0 20.526.4 ug/L 0.50 0.50
Lead mg/L .5 90 75-12589 2 20.5ND 0.45 0.45
Selenium mg/L .5 89 75-12588 1 20.5ND 0.44 0.44
Silver mg/L .25 94 75-12593 0 20.25ND 0.24 0.23
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 29 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/32323
EPA 8260
EPA 8260
8260 MSV Low Level
Associated Lab Samples:92255880001, 92255880002, 92255880003, 92255880004, 92255880005, 92255880006, 92255880007,
92255880008, 92255880009, 92255880010, 92255880011, 92255880012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1495645
Associated Lab Samples:92255880001, 92255880002, 92255880003, 92255880004, 92255880005, 92255880006, 92255880007,
92255880008, 92255880009, 92255880010, 92255880011, 92255880012
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane mg/L ND 0.0010 06/26/15 12:28
1,1,1-Trichloroethane mg/L ND 0.0010 06/26/15 12:28
1,1,2,2-Tetrachloroethane mg/L ND 0.0010 06/26/15 12:28
1,1,2-Trichloroethane mg/L ND 0.0010 06/26/15 12:28
1,1-Dichloroethane mg/L ND 0.0010 06/26/15 12:28
1,1-Dichloroethene mg/L ND 0.0010 06/26/15 12:28
1,1-Dichloropropene mg/L ND 0.0010 06/26/15 12:28
1,2,3-Trichlorobenzene mg/L ND 0.0010 06/26/15 12:28
1,2,3-Trichloropropane mg/L ND 0.0010 06/26/15 12:28
1,2,4-Trichlorobenzene mg/L ND 0.0010 06/26/15 12:28
1,2,4-Trimethylbenzene mg/L ND 0.0010 06/26/15 12:28
1,2-Dibromoethane (EDB)mg/L ND 0.0010 06/26/15 12:28
1,2-Dichlorobenzene mg/L ND 0.0010 06/26/15 12:28
1,2-Dichloroethane mg/L ND 0.0010 06/26/15 12:28
1,2-Dichloroethene (Total)mg/L ND 0.0010 06/26/15 12:28
1,2-Dichloropropane mg/L ND 0.0010 06/26/15 12:28
1,3,5-Trimethylbenzene mg/L ND 0.0010 06/26/15 12:28
1,3-Dichlorobenzene mg/L ND 0.0010 06/26/15 12:28
1,3-Dichloropropane mg/L ND 0.0010 06/26/15 12:28
1,4-Dichlorobenzene mg/L ND 0.0010 06/26/15 12:28
2,2-Dichloropropane mg/L ND 0.0010 06/26/15 12:28
2-Chlorotoluene mg/L ND 0.0010 06/26/15 12:28
4-Chlorotoluene mg/L ND 0.0010 06/26/15 12:28
Benzene mg/L ND 0.0010 06/26/15 12:28
Bromobenzene mg/L ND 0.0010 06/26/15 12:28
Bromochloromethane mg/L ND 0.0010 06/26/15 12:28
Bromodichloromethane mg/L ND 0.0010 06/26/15 12:28
Bromoform mg/L ND 0.0010 06/26/15 12:28
Bromomethane mg/L ND 0.0020 06/26/15 12:28
Carbon tetrachloride mg/L ND 0.0010 06/26/15 12:28
Chlorobenzene mg/L ND 0.0010 06/26/15 12:28
Chloroethane mg/L ND 0.0010 06/26/15 12:28
Chloroform mg/L ND 0.0010 06/26/15 12:28
Chloromethane mg/L ND 0.0010 06/26/15 12:28
cis-1,2-Dichloroethene mg/L ND 0.0010 06/26/15 12:28
Dibromochloromethane mg/L ND 0.0010 06/26/15 12:28
Dibromomethane mg/L ND 0.0010 06/26/15 12:28
Dichlorodifluoromethane mg/L ND 0.0010 06/26/15 12:28
Diisopropyl ether mg/L ND 0.0010 06/26/15 12:28
Ethylbenzene mg/L ND 0.0010 06/26/15 12:28
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 30 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1495645
Associated Lab Samples:92255880001, 92255880002, 92255880003, 92255880004, 92255880005, 92255880006, 92255880007,
92255880008, 92255880009, 92255880010, 92255880011, 92255880012
Matrix:Water
Analyzed
Hexachloro-1,3-butadiene mg/L ND 0.0010 06/26/15 12:28
Isopropylbenzene (Cumene)mg/L ND 0.0010 06/26/15 12:28
m&p-Xylene mg/L ND 0.0020 06/26/15 12:28
Methyl-tert-butyl ether mg/L ND 0.0010 06/26/15 12:28
Methylene Chloride mg/L ND 0.0020 06/26/15 12:28
n-Butylbenzene mg/L ND 0.0010 06/26/15 12:28
n-Propylbenzene mg/L ND 0.0010 06/26/15 12:28
Naphthalene mg/L ND 0.0010 06/26/15 12:28
o-Xylene mg/L ND 0.0010 06/26/15 12:28
p-Isopropyltoluene mg/L ND 0.0010 06/26/15 12:28
sec-Butylbenzene mg/L ND 0.0010 06/26/15 12:28
Styrene mg/L ND 0.0010 06/26/15 12:28
tert-Butylbenzene mg/L ND 0.0010 06/26/15 12:28
Tetrachloroethene mg/L ND 0.0010 06/26/15 12:28
Tetrahydrofuran mg/L ND 0.010 06/26/15 12:28
Toluene mg/L ND 0.0010 06/26/15 12:28
trans-1,2-Dichloroethene mg/L ND 0.0010 06/26/15 12:28
Trichloroethene mg/L ND 0.0010 06/26/15 12:28
Trichlorofluoromethane mg/L ND 0.0010 06/26/15 12:28
Vinyl acetate mg/L ND 0.0020 06/26/15 12:28
Vinyl chloride mg/L ND 0.0010 06/26/15 12:28
Xylene (Total)mg/L ND 0.0020 06/26/15 12:28
1,2-Dichloroethane-d4 (S)%94 70-130 06/26/15 12:28
4-Bromofluorobenzene (S)%100 70-130 06/26/15 12:28
Toluene-d8 (S)%99 70-130 06/26/15 12:28
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1495646LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane mg/L 0.046.05 92 70-130
1,1,1-Trichloroethane mg/L 0.044.05 87 70-130
1,1,2,2-Tetrachloroethane mg/L 0.048.05 97 70-130
1,1,2-Trichloroethane mg/L 0.045.05 90 70-130
1,1-Dichloroethane mg/L 0.044.05 87 70-130
1,1-Dichloroethene mg/L 0.045.05 90 70-132
1,1-Dichloropropene mg/L 0.046.05 93 70-130
1,2,3-Trichlorobenzene mg/L 0.047.05 94 70-135
1,2,3-Trichloropropane mg/L 0.047.05 95 70-130
1,2,4-Trichlorobenzene mg/L 0.047.05 94 70-134
1,2,4-Trimethylbenzene mg/L 0.046.05 93 70-130
1,2-Dibromoethane (EDB)mg/L 0.048.05 96 70-130
1,2-Dichlorobenzene mg/L 0.047.05 93 70-130
1,2-Dichloroethane mg/L 0.040.05 81 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 31 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1495646LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichloroethene (Total)mg/L 0.086.1 86 70-130
1,2-Dichloropropane mg/L 0.044.05 88 70-130
1,3,5-Trimethylbenzene mg/L 0.047.05 93 70-130
1,3-Dichlorobenzene mg/L 0.048.05 95 70-130
1,3-Dichloropropane mg/L 0.046.05 93 70-130
1,4-Dichlorobenzene mg/L 0.046.05 91 70-130
2,2-Dichloropropane mg/L 0.041.05 83 58-145
2-Chlorotoluene mg/L 0.046.05 92 70-130
4-Chlorotoluene mg/L 0.046.05 91 70-130
Benzene mg/L 0.047.05 94 70-130
Bromobenzene mg/L 0.046.05 93 70-130
Bromochloromethane mg/L 0.049.05 97 70-130
Bromodichloromethane mg/L 0.044.05 88 70-130
Bromoform mg/L 0.044.05 89 70-130
Bromomethane mg/L 0.037.05 73 54-130
Carbon tetrachloride mg/L 0.043.05 85 70-132
Chlorobenzene mg/L 0.046.05 91 70-130
Chloroethane mg/L 0.039.05 79 64-134
Chloroform mg/L 0.045.05 89 70-130
Chloromethane mg/L 0.038.05 75 64-130
cis-1,2-Dichloroethene mg/L 0.044.05 88 70-131
Dibromochloromethane mg/L 0.046.05 92 70-130
Dibromomethane mg/L 0.045.05 91 70-131
Dichlorodifluoromethane mg/L 0.046.05 93 56-130
Diisopropyl ether mg/L 0.047.05 94 70-130
Ethylbenzene mg/L 0.046.05 91 70-130
Hexachloro-1,3-butadiene mg/L 0.046.05 91 70-130
Isopropylbenzene (Cumene)mg/L 0.049.05 98 70-130
m&p-Xylene mg/L 0.093.1 93 70-130
Methyl-tert-butyl ether mg/L 0.049.05 99 70-130
Methylene Chloride mg/L 0.043.05 86 63-130
n-Butylbenzene mg/L 0.046.05 93 70-130
n-Propylbenzene mg/L 0.048.05 96 70-130
Naphthalene mg/L 0.052.05 105 70-138
o-Xylene mg/L 0.047.05 94 70-130
p-Isopropyltoluene mg/L 0.046.05 93 70-130
sec-Butylbenzene mg/L 0.049.05 98 70-130
Styrene mg/L 0.048.05 96 70-130
tert-Butylbenzene mg/L 0.041.05 82 70-130
Tetrachloroethene mg/L 0.045.05 90 70-130
Tetrahydrofuran mg/L 0.45.5 91 70-130
Toluene mg/L 0.045.05 90 70-130
trans-1,2-Dichloroethene mg/L 0.042.05 85 70-130
Trichloroethene mg/L 0.044.05 88 70-130
Trichlorofluoromethane mg/L 0.038.05 77 62-133
Vinyl acetate mg/L 0.092.1 92 66-157
Vinyl chloride mg/L 0.042.05 85 50-150
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 32 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1495646LABORATORY CONTROL SAMPLE:
LCSSpike
Xylene (Total)mg/L 0.14.15 93 70-130
1,2-Dichloroethane-d4 (S)%96 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1495647MATRIX SPIKE SAMPLE:
MSSpike
Result
92255880001
1,1,1,2-Tetrachloroethane mg/L 0.021.02 104 70-130ND
1,1,1-Trichloroethane mg/L 0.026 M1.02 132 70-130ND
1,1,2,2-Tetrachloroethane mg/L 0.020.02 98 70-130ND
1,1,2-Trichloroethane mg/L 0.020.02 99 70-130ND
1,1-Dichloroethane mg/L 0.026.02 128 70-130ND
1,1-Dichloroethene mg/L 0.025.02 125 70-166ND
1,1-Dichloropropene mg/L 0.026.02 130 70-130ND
1,2,3-Trichlorobenzene mg/L 0.017.02 87 70-130ND
1,2,3-Trichloropropane mg/L 0.020.02 98 70-130ND
1,2,4-Trichlorobenzene mg/L 0.018.02 90 70-130ND
1,2,4-Trimethylbenzene mg/L 0.021.02 105 70-130ND
1,2-Dibromoethane (EDB)mg/L 0.021.02 103 70-130ND
1,2-Dichlorobenzene mg/L 0.020.02 101 70-130ND
1,2-Dichloroethane mg/L 0.024.02 118 70-130ND
1,2-Dichloropropane mg/L 0.022.02 110 70-130ND
1,3,5-Trimethylbenzene mg/L 0.022.02 108 70-130ND
1,3-Dichlorobenzene mg/L 0.021.02 104 70-130ND
1,3-Dichloropropane mg/L 0.020.02 102 70-130ND
1,4-Dichlorobenzene mg/L 0.020.02 101 70-130ND
2,2-Dichloropropane mg/L 0.026.02 130 70-130ND
2-Chlorotoluene mg/L 0.021.02 105 70-130ND
4-Chlorotoluene mg/L 0.021.02 105 70-130ND
Benzene mg/L 0.022.02 109 70-148ND
Bromobenzene mg/L 0.022.02 108 70-130ND
Bromochloromethane mg/L 0.024.02 120 70-130ND
Bromodichloromethane mg/L 0.022.02 111 70-130ND
Bromoform mg/L 0.019.02 97 70-130ND
Bromomethane mg/L 0.019.02 93 70-130ND
Carbon tetrachloride mg/L 0.025.02 127 70-130ND
Chlorobenzene mg/L 0.021.02 106 70-146ND
Chloroethane mg/L 0.022.02 109 70-130ND
Chloroform mg/L 0.024.02 119 70-130ND
Chloromethane mg/L 0.016.02 78 70-130ND
cis-1,2-Dichloroethene mg/L 0.024.02 122 70-130ND
Dibromochloromethane mg/L 0.021.02 103 70-130ND
Dibromomethane mg/L 0.021.02 103 70-130ND
Dichlorodifluoromethane mg/L 0.013 M1.02 66 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 33 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1495647MATRIX SPIKE SAMPLE:
MSSpike
Result
92255880001
Diisopropyl ether mg/L 0.024.02 121 70-130ND
Ethylbenzene mg/L 0.023.02 113 70-130ND
Hexachloro-1,3-butadiene mg/L 0.023.02 113 70-130ND
Isopropylbenzene (Cumene)mg/L 0.025.02 125 70-130ND
m&p-Xylene mg/L 0.047.04 117 70-130ND
Methyl-tert-butyl ether mg/L 0.024.02 118 70-130ND
Methylene Chloride mg/L 0.024.02 118 70-130ND
n-Butylbenzene mg/L 0.021.02 105 70-130ND
n-Propylbenzene mg/L 0.023.02 116 70-130ND
Naphthalene mg/L 0.019.02 97 70-130ND
o-Xylene mg/L 0.023.02 116 70-130ND
p-Isopropyltoluene mg/L 0.021.02 106 70-130ND
sec-Butylbenzene mg/L 0.023.02 115 70-130ND
Styrene mg/L 0.023.02 114 70-130ND
tert-Butylbenzene mg/L 0.019.02 95 70-130ND
Tetrachloroethene mg/L 0.021.02 107 70-130ND
Tetrahydrofuran mg/L 0.23.2 114 70-130ND
Toluene mg/L 0.022.02 108 70-155ND
trans-1,2-Dichloroethene mg/L 0.025.02 125 70-130ND
Trichloroethene mg/L 0.022.02 112 69-151ND
Trichlorofluoromethane mg/L 0.024.02 121 70-130ND
Vinyl acetate mg/L 0.048.04 120 70-130ND
Vinyl chloride mg/L 0.020.02 98 70-130ND
1,2-Dichloroethane-d4 (S)%110 70-130
4-Bromofluorobenzene (S)%106 70-130
Toluene-d8 (S)%97 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92255880002
1495648SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane mg/L ND 30ND
1,1,1-Trichloroethane mg/L ND 30ND
1,1,2,2-Tetrachloroethane mg/L ND 30ND
1,1,2-Trichloroethane mg/L ND 30ND
1,1-Dichloroethane mg/L .00035J 30ND
1,1-Dichloroethene mg/L ND 30ND
1,1-Dichloropropene mg/L ND 30ND
1,2,3-Trichlorobenzene mg/L ND 30ND
1,2,3-Trichloropropane mg/L ND 30ND
1,2,4-Trichlorobenzene mg/L ND 30ND
1,2,4-Trimethylbenzene mg/L ND 30ND
1,2-Dibromoethane (EDB)mg/L ND 30ND
1,2-Dichlorobenzene mg/L ND 30ND
1,2-Dichloroethane mg/L ND 30ND
1,2-Dichloroethene (Total)mg/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 34 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92255880002
1495648SAMPLE DUPLICATE:
1,2-Dichloropropane mg/L ND 30ND
1,3,5-Trimethylbenzene mg/L ND 30ND
1,3-Dichlorobenzene mg/L ND 30ND
1,3-Dichloropropane mg/L ND 30ND
1,4-Dichlorobenzene mg/L ND 30ND
2,2-Dichloropropane mg/L ND 30ND
2-Chlorotoluene mg/L ND 30ND
4-Chlorotoluene mg/L ND 30ND
Benzene mg/L 0.0015 15 300.0017
Bromobenzene mg/L ND 30ND
Bromochloromethane mg/L ND 30ND
Bromodichloromethane mg/L ND 30ND
Bromoform mg/L ND 30ND
Bromomethane mg/L ND 30ND
Carbon tetrachloride mg/L ND 30ND
Chlorobenzene mg/L .00026J 30ND
Chloroethane mg/L ND 30ND
Chloroform mg/L ND 30ND
Chloromethane mg/L ND 30ND
cis-1,2-Dichloroethene mg/L ND 30ND
Dibromochloromethane mg/L ND 30ND
Dibromomethane mg/L ND 30ND
Dichlorodifluoromethane mg/L ND 30ND
Diisopropyl ether mg/L ND 30ND
Ethylbenzene mg/L ND 30ND
Hexachloro-1,3-butadiene mg/L ND 30ND
Isopropylbenzene (Cumene)mg/L 0.0025 11 300.0027
m&p-Xylene mg/L .00074J 30ND
Methyl-tert-butyl ether mg/L .0007J 30ND
Methylene Chloride mg/L ND 30ND
n-Butylbenzene mg/L ND 30ND
n-Propylbenzene mg/L .00056J 30ND
Naphthalene mg/L ND 30ND
o-Xylene mg/L .00053J 30ND
p-Isopropyltoluene mg/L ND 30ND
sec-Butylbenzene mg/L ND 30ND
Styrene mg/L ND 30ND
tert-Butylbenzene mg/L ND 30ND
Tetrachloroethene mg/L ND 30ND
Tetrahydrofuran mg/L 0.12 14 300.10
Toluene mg/L .0004J 30ND
trans-1,2-Dichloroethene mg/L ND 30ND
Trichloroethene mg/L ND 30ND
Trichlorofluoromethane mg/L ND 30ND
Vinyl acetate mg/L ND 30ND
Vinyl chloride mg/L ND 30ND
Xylene (Total)mg/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 35 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92255880002
1495648SAMPLE DUPLICATE:
1,2-Dichloroethane-d4 (S)%113 1399
4-Bromofluorobenzene (S)%103 499
Toluene-d8 (S)%102 2100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 36 of 40
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 37 of 40
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92255880
WILEY DAVIS LANDFILL R5-34
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92255880001 MPRP/18852 ICP/16909WD-1 EPA 3010 EPA 6010
92255880002 MPRP/18852 ICP/16909WD-2 EPA 3010 EPA 6010
92255880003 MPRP/18852 ICP/16909WD-2D EPA 3010 EPA 6010
92255880004 MPRP/18852 ICP/16909WD-3 EPA 3010 EPA 6010
92255880005 MPRP/18852 ICP/16909WD-3D EPA 3010 EPA 6010
92255880006 MPRP/18852 ICP/16909WD-4 EPA 3010 EPA 6010
92255880007 MPRP/18852 ICP/16909WD-4D EPA 3010 EPA 6010
92255880008 MPRP/18852 ICP/16909WD-5 EPA 3010 EPA 6010
92255880009 MPRP/18852 ICP/16909WD-6 EPA 3010 EPA 6010
92255880010 MPRP/18852 ICP/16909WD-7 EPA 3010 EPA 6010
92255880011 MPRP/18852 ICP/16909SS1-UPGRADIENT EPA 3010 EPA 6010
92255880012 MPRP/18852 ICP/16909SS-2 DOWNGRADIENT EPA 3010 EPA 6010
92255880001 MERP/7990 MERC/7670WD-1 EPA 7470 EPA 7470
92255880002 MERP/7990 MERC/7670WD-2 EPA 7470 EPA 7470
92255880003 MERP/7990 MERC/7670WD-2D EPA 7470 EPA 7470
92255880004 MERP/7990 MERC/7670WD-3 EPA 7470 EPA 7470
92255880005 MERP/7990 MERC/7670WD-3D EPA 7470 EPA 7470
92255880006 MERP/7990 MERC/7670WD-4 EPA 7470 EPA 7470
92255880007 MERP/7990 MERC/7670WD-4D EPA 7470 EPA 7470
92255880008 MERP/7990 MERC/7670WD-5 EPA 7470 EPA 7470
92255880009 MERP/7990 MERC/7670WD-6 EPA 7470 EPA 7470
92255880010 MERP/7990 MERC/7670WD-7 EPA 7470 EPA 7470
92255880011 MERP/7990 MERC/7670SS1-UPGRADIENT EPA 7470 EPA 7470
92255880012 MERP/7990 MERC/7670SS-2 DOWNGRADIENT EPA 7470 EPA 7470
92255880001 MSV/32323WD-1 EPA 8260
92255880002 MSV/32323WD-2 EPA 8260
92255880003 MSV/32323WD-2D EPA 8260
92255880004 MSV/32323WD-3 EPA 8260
92255880005 MSV/32323WD-3D EPA 8260
92255880006 MSV/32323WD-4 EPA 8260
92255880007 MSV/32323WD-4D EPA 8260
92255880008 MSV/32323WD-5 EPA 8260
92255880009 MSV/32323WD-6 EPA 8260
92255880010 MSV/32323WD-7 EPA 8260
92255880011 MSV/32323SS1-UPGRADIENT EPA 8260
92255880012 MSV/32323SS-2 DOWNGRADIENT EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/02/2015 04:34 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 38 of 40
Page 39 of 40
Page 40 of 40