8503_DukeBelewsCreekPineHall_April2016_1stSemiAnnual_DIN26542_20160715

Pine Hall Road Ash Landfill
Permit No. 8503
Semiannual Groundwater
Monitoring Report
April 2016 Sampling Event
Belews Creek Steam Station
July 15, 2016

Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Pine Hall Road Ash Landfill, Permit No.8503
April 2016 Sampling Event
Contents

i
Contents
Page
Section 1 – Background ................................................................................................................ 1
Section 2 – Methods ..................................................................................................................... 3
2.1 Sampling and Analysis Methods .................................................................................... 3
2.2 Statement of Work .......................................................................................................... 3
Section 3 – Results ...................................................................................................................... 5
3.1 Site Groundwater Flow ................................................................................................... 5
3.2 Analytical Results ........................................................................................................... 5

Figures
1. Site Location Map
2. Sample Locations
3. Generalized Groundwater Surface Contours
Tables
1. Well Construction Information
2. Groundwater Flow Velocities
3. Field Data Parameters
4. Field and Analytical Results
5. 15A NCAC 2L Groundwater Quality Standard Exceedances for Wells within the Review
Boundary
6. 15A NCAC 2L Groundwater Quality Standard Exceedances at or Beyond Review
Boundary
Appendices
Appendix A – Field Sampling Forms
Appendix B – Laboratory Report and Chain-of-Custody Forms
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Pine Hall Road Ash Landfill, Permit No.8503
April 2016 Sampling Event
Section 1 – Background

1
Section 1 – Background
The Pine Hall Road Ash Landfill is located at the Duke Energy Carolinas, LLC (Duke Energy)
Belews Creek Steam Station in Stokes County, North Carolina. The landfill is permitted under
the North Carolina Department of Environmental Quality (NCDEQ) Solid Waste Permit No. 8503
and was closed in December 2008. The ash landfill was permitted to accept only fly ash from
Belews Creek Steam Station operations. The ash landfill and nearby surrounding area are
portrayed on Figure 1.
The landfill was originally permitted in 1983. The original landfill was unlined and was permitted
with a soil cap 1 foot thick on the side slopes and 2 feet thick on flatter areas. A subsequent
expansion (Phase I Expansion) was permitted in 2003. This phase was also unlined but was
permitted with a synthetic cap system to be applied at closure.
After groundwater exceedances were observed in wells installed near the landfill, the placement
of additional ash in the Phase I Expansion was halted. The closure design was changed to
utilize an engineered cover system for the portion of the landfill indicated on Figure 2. The
engineered cover system consists of a 40-mil linear low density polyethylene geomembrane, a
geonet composite, 18 inches of compacted soil, and 6 inches of vegetative soil cover. The
engineered cover system was installed over a 37.9 acre area, indicated on Figure 2 as
“Approximate Limits of Engineered Cover System.” An adjacent 14.5 acre area, located to the
northeast, had additional soil cover applied and was graded to improve surface drainage. This
area is indicated on Figure 2 as “Limits of Soil Cap.” The construction of the engineered cover
system and additional soil cover on the 14.5 acre area was completed in December 2008.
The ash landfill is located to the north of the surface water divide that runs along Pine Hall Road
and to the east of a surface water divide that runs along Middleton Loop Road. These surface
water divides appear to mimic the shallow groundwater divides in the area near the landfill. Two
surface water features are located in the area near the landfill. One surface water drainage
feature drains along the eastern side of the landfill to the Ash Basin. The second surface water
drainage feature is located on the western side of the landfill and drains to the Ash Basin. The
surface water sample locations in these features are groundwater seeps and are believed to be
representative of groundwater. Samples collected from these locations are compared to 15A
North Carolina Administrative Code (NCAC) 2L groundwater quality standards (2L Standards).
Groundwater flow beneath the landfill is from Pine Hall Road, generally northward, toward the
Ash Basin. The Ash Basin is operated as a water treatment facility and is permitted by the
National Pollutant Discharge Elimination System (NPDES) program (NPDES Permit
#NC0024406).

Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Pine Hall Road Ash Landfill, Permit No.8503
April 2016 Sampling Event
Section 1 – Background

2
The groundwater monitoring system at the landfill consists of the following sample locations as
listed below.
Monitoring Wells: MW-1 MW-1D
MW-2 MW-3
MW-4 MW-5
MW-6 MW-7
MW2-7 MW2-9
OB-4 OB-5
OB-9

Surface Water Locations: SW-1A SW-2

The locations of the monitoring wells and surface water sample locations are shown on
Figure 2. A summary of monitoring well construction information is presented in Table 1. As
defined by the Groundwater Monitoring, Sampling and Analysis Plan (SAP) for the Pine Hall
Road Ash Landfill (prepared by S&ME, Inc. dated November 8, 2010, and approved by NCDEQ
on November 23, 2010), monitoring well MW-3 is considered to represent “background”
groundwater quality conditions.
The groundwater and surface water sampling was conducted by Duke Energy according to
North Carolina Solid Waste Management Guidelines. The constituents sampled and analyzed
were selected by Duke Energy and the NCDEQ Division of Solid Waste and are listed in the
SAP. The samples were analyzed by a North Carolina certified laboratory.
During previous sampling events the groundwater samples were also analyzed for Part 40 Code
of Federal Regulations (CFR) Part 258, Appendix I constituents, in addition to the constituents
listed in the SAP. Appendix I sampling and analysis was performed as part of the requirements
contained in the Closure Plan Approval letter dated December 7, 2007, Document ID RC03425.
Sampling of Appendix I constituents has been discontinued as per a June 8, 2015 electronic
mail correspondence from Elizabeth Werner of the NCDEQ Solid Waste Section. A copy of this
correspondence is retained in Duke Energy’s operating record.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Pine Hall Road Ash Landfill, Permit No.8503
April 2016 Sampling Event
Section 2 – Methods

3
Section 2 – Methods
2.1 Sampling and Analysis Methods
Groundwater sampling and documentation of sampling activities were performed by Duke
Energy personnel (Duke Energy Carolinas Field Certification #5193). Copies of the field
sampling forms are included in Appendix A. The groundwater samples were analyzed by the
Duke Energy Analytical Laboratory (North Carolina Laboratory Certification #248) and provided
to HDR by Duke Energy. The laboratory report and chain-of-custody forms are included in
Appendix B.
The groundwater samples were analyzed for the following constituents and/or parameters:
 Barium, beryllium, boron, chromium, copper, iron, manganese, nickel, silver, and zinc
using Solid Waste (SW) Method 6010D
 Antimony, arsenic, cadmium, cobalt, lead, selenium, thallium, and vanadium using SW
Method 6020B
 Mercury using United States Environmental Protection Agency (EPA) Method 7470A
 Chloride, fluoride, nitrate as nitrogen, and sulfate using EPA Method 9056A
 Total dissolved solids using Standard Method (SM) 2540C
2.2 Statement of Work
HDR completed the following tasks:
 Received field sampling information provided by Duke Energy for monitoring wells MW-
1D, MW-3, MW-4, MW-5, MW-6, MW-7, MW2-7, MW2-9, OB-4, OB-5, and OB-9 and
surface water sampling locations SW-1A and SW-2. Monitoring well MW-1 was
inaccessible due to well drilling activities in the vicinity of the well; therefore a
groundwater sample and water level measurement could not be collected. A
groundwater sample was not collected from MW-2 due to insufficient water volume in the
well and possible clogged tubing in the well. However, a groundwater level
measurement was able to be collected from MW-2. The samples were collected by Duke
Energy personnel on April 25, 2016, and HDR received the data on May 17, 2016.
 Reviewed the laboratory analytical results for samples. The Electronic Data Deliverable
(EDD) provided by Duke Energy was adapted to conform to the format requirements of
the NCDEQ EDD template. HDR added an italicized J data qualifier (J’) to indicate a
detected concentration that equals or is greater than the laboratory’s method reporting
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Pine Hall Road Ash Landfill, Permit No.8503
April 2016 Sampling Event
Section 2 – Methods

4
limit (MRL), but is less than the Solid Waste Section Limit1 (SWSL). A copy of the
original EDD is retained in HDR’s files.
 Developed a generalized groundwater surface contour map using map data and
groundwater elevation data supplied by Duke Energy. Calculated groundwater flow
velocities based on groundwater contours.
 Prepared this Semiannual Groundwater Monitoring Report and submitted it to Duke
Energy.

1 The Solid Waste Section Limit (SWSL) is defined by NCDEQ as the lowest amount of analyte in a
sample that can be quantitatively determined with suitable precision and accuracy. The SWSL is the
concentration below which reported results must be qualified as estimated. NCDEQ Division of Waste
Management Memorandum dated February 23, 2007.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Pine Hall Road Ash Landfill, Permit No.8503
April 2016 Sampling Event
Section 3 – Results

5
Section 3 – Results
3.1 Site Groundwater Flow
Generalized groundwater surface contours and groundwater flow direction arrows for the site
are shown on Figure 3. These contours were developed using the measured groundwater
elevations in the wells on the date of sampling. Calculated groundwater flow velocities are
presented in Table 2.
Pine Hall Road is located generally along a surface water divide that also appears to be a
groundwater divide. Groundwater flow at the landfill site is from areas of higher topography
along Pine Hall Road, generally northward, toward the Ash Basin.
3.2 Analytical Results
A summary of the field data is presented in Table 3.
The field and analytical results of groundwater and surface water sampling are summarized in
Table 4. The analytical results are compared to the groundwater standards found in Title 15A
NCAC 02L .0202 (g) (2L Standards). Concentrations that attain or exceed the 2L Standards are
noted in Table 4 by bold font. Concentrations that equal or are greater than the SWSLs are
noted in Table 4 by gray-shaded cells.
A summary of the 2L Standard exceedances and a preliminary analysis of the cause and
significance of the exceedances is presented in Table 5 for sampling locations located within the
review boundary and in Table 6 for sampling locations located at or beyond the review
boundary.
Select samples were diluted as is normal laboratory practice to bring samples to the calibrated
range of the analysis. Specifics regarding the samples that were diluted, including the dilution
factor, are reported in the EDD.
HDR previously prepared and submitted an assessment to the NCDEQ for exceedances of 2L
Standards at this landfill (Groundwater Assessment Belews Creek Steam Station Pine Hall
Road Ash Landfill, Permit No. 8503, dated October 1, 2012). The report assessed 2L Standard
exceedances at wells MW-3 and MW-6 and found those exceedances to be attributed to
naturally occurring conditions.
The assessment report reviewed the location of wells and surface water sample locations with
exceedances of 2L Standards (MW-4, MW-7, MW2-7, MW2-9, SW-1A, and SW-2) and found
that the hydrologic boundaries and the groundwater flow at the site was such that the
groundwater at these locations was discharging to the ash basin. The report also concluded that
with the reduced infiltration, due to the engineered cover system installed in 2008, the
groundwater concentration of constituents attributable to fly ash in these wells will likely
continue to decrease over time.

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n
e
a
r
b
y

d
r
i
l
l
i
n
g
o
p
e
r
a
t
i
o
n
s

p
r
e
v
e
n
t
e
d

s
a
f
e

a
c
c
e
s
s

t
o

t
h
e

w
e
l
l
.
Well Diameter (in.)Casing Type
Gr
o
u
n
d
w
a
t
e
r

El
e
v
a
t
i
o
n

(
f
t
.
)
De
p
t
h

t
o

W
a
t
e
r

be
l
o
w

T
O
C
(f
t
.
)
To
t
a
l

W
e
l
l

De
p
t
h

b
e
l
o
w

TO
C
(ft
.
)
De
p
t
h

t
o

T
o
p

o
f

Sc
r
e
e
n

f
r
o
m

T
O
C
(f
t
.
)
Sc
r
e
e
n
e
d

I
n
t
e
r
v
a
l

be
l
o
w

T
O
C
(f
t
.
)

G
e
o
l
o
g
y

o
f

S
c
r
e
e
n
e
d

I
n
t
e
r
v
a
l
We
l
l

I
D
We
l
l

I
n
s
t
a
l
l
a
t
i
o
n

Da
t
e
TO
C

Ele
v
a
t
i
o
n

(
f
t
.
)
Gr
o
u
n
d

S
u
r
f
a
c
e

Ele
v
a
t
i
o
n
(f
t
.
)
We
l
l

S
t
i
c
k
-
u
p

He
i
g
h
t

A
b
o
v
e

Gr
o
u
n
d

S
u
r
f
a
c
e

(f
t
.
)
Co
o
r
d
i
n
a
t
e
s
Ta
b
l
e

2

-

G
r
o
u
n
d
w
a
t
e
r

F
l
o
w

V
e
l
o
c
i
t
i
e
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C
/
B
e
l
e
w
s

C
r
e
e
k

S
t
e
a
m

S
t
a
t
i
o
n
Pi
n
e

H
a
l
l

R
o
a
d

A
s
h

L
a
n
d
f
i
l
l

-

P
e
r
m
i
t

N
o
.

8
5
0
3
OB
-
9

7
6
5

7
6
0

9
1

0
.
0
5
5

0
.
4
1
1

0
.
2
5
9

0
.
0
8
7
MW
-
4

7
6
0

7
5
5
.
2
9

1
4
9

0
.
0
3
2

0
.
4
1
1

0
.
2
5
9

0
.
0
5
0
OB
-
4

7
6
0

7
5
5
.
2
8

6
2

0
.
0
7
6

0
.
4
1
1

0
.
2
5
9

0
.
1
2
0
OB
-
5

7
6
0

7
5
5
.
6
0

1
1
8

0
.
0
3
7

0
.
4
1
1

0
.
2
5
9

0
.
0
5
9
MW
-
7

8
0
8
.
5
9

8
0
5

9
3

0
.
0
3
8

0
.
4
1
1

0
.
2
5
9

0
.
0
6
1
MW
2
-
7

7
6
5

7
6
0

4
8

0
.
1
0
4

0
.
4
1
1

0
.
2
5
9

0
.
1
6
4
MW
2
-
9

7
9
5

7
9
0

3
0

0
.
1
6
8

0
.
4
1
1

0
.
2
5
9

0
.
2
6
6
No
t
e
s
:
1
.

L
i
n
e
a
r

d
i
s
t
a
n
c
e

m
e
a
s
u
r
e
d

t
h
r
o
u
g
h

m
o
n
i
t
o
r
i
n
g

w
e
l
l
s

i
s

g
e
n
e
r
a
l
l
y

p
e
r
p
e
n
d
i
c
u
l
a
r

t
o

g
r
o
u
n
d
w
a
t
e
r

c
o
n
t
o
u
r
s
.
2
.

A
t

m
o
n
i
t
o
r
i
n
g

w
e
l
l

l
o
c
a
t
i
o
n
s

w
h
e
r
e

d
o
w
n
g
r
a
d
i
e
n
t

c
o
n
t
o
u
r
s

a
r
e

n
o
t

p
r
e
s
e
n
t
,

t
h
e

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n

a
t

t
h
e

m
o
n
i
t
o
r
i
n
g

w
e
l
l

i
s

u
s
e
d

a
s

t
h
e

d
o
w
n
g
r
a
d
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n
.
3
.

A
t

m
o
n
i
t
o
r
i
n
g

w
e
l
l

l
o
c
a
t
i
o
n
s

w
h
e
r
e

u
p
g
r
a
d
i
e
n
t

c
o
n
t
o
u
r
s

a
r
e

n
o
t

p
r
e
s
e
n
t
,

t
h
e

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n

a
t

t
h
e

m
o
n
i
t
o
r
i
n
g

w
e
l
l

i
s

u
s
e
d

a
s

t
h
e

u
p
g
r
a
d
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n
.
4
.

M
o
n
i
t
o
r
i
n
g

w
e
l
l
s

a
r
e

n
o
t

l
i
s
t
e
d

w
h
e
r
e

i
n
s
u
f
f
i
c
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

c
o
n
t
o
u
r

i
n
f
o
r
m
a
t
i
o
n

i
s

a
v
a
i
l
a
b
l
e

t
o

c
a
l
c
u
l
a
t
e

v
e
l
o
c
i
t
y
.
5
.

H
y
d
r
a
u
l
i
c

g
r
a
d
i
e
n
t

i
s

a
p
p
r
o
x
i
m
a
t
e
.
6
.

H
y
d
r
a
u
l
i
c

c
o
n
d
u
c
t
i
v
i
t
y

p
r
e
s
e
n
t
e
d

i
s

t
h
e

g
e
o
m
e
t
r
i
c

m
e
a
n

o
f

t
h
e

c
o
n
d
u
c
t
i
v
i
t
y

d
a
t
a

f
o
r

t
h
e

a
l
l
u
v
i
u
m
/
s
o
i
l
/
s
a
p
r
o
l
i
t
e

h
y
d
r
o
s
t
r
a
t
i
gr
a
p
h
i
c

l
a
y
e
r

i
n

t
h
e

H
D
R

C
o
n
d
u
c
t
i
v
i
t
y

D
a
t
a
b
a
s
e

(
u
n
p
u
b
l
i
s
h
e
d

d
a
t
a

f
r
o
m

C
a
r
o
l
i
n
a

s
i
t
e
s

w
i
t
h

f
o
l
i
a
t
e
d
/
l
a
y
e
r
e
d

b
e
d
r
o
c
k
)
.
7
.

E
f
f
e
c
t
i
v
e

p
o
r
o
s
i
t
y

p
r
e
s
e
n
t
e
d

i
s

t
h
e

m
e
a
n

v
a
l
u
e

o
f

t
h
e

a
l
l
u
v
i
u
m
/
s
o
i
l
/
s
a
p
r
o
l
i
t
e

h
y
d
r
o
s
t
r
a
t
i
g
r
a
p
h
i
c

l
a
y
e
r

e
s
t
i
m
a
t
e
d

f
r
o
m

s
o
i
l

te
s
t
i
n
g

u
s
i
n
g

F
e
t
t
e
r
/
B
e
a
r

D
i
a
g
r
a
m
s
.

8
.

H
y
d
r
a
u
l
i
c

g
r
a
d
i
e
n
t
s

a
n
d

g
r
o
u
n
d
w
a
t
e
r

v
e
l
o
c
i
t
i
e
s

c
a
l
c
u
l
a
t
e
d

b
a
s
e
d

o
n

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n

m
e
a
s
u
r
e
m
e
n
t
s

o
n

A
p
r
i
l

2
5
,

2
0
1
6
.
Hy
d
r
a
u
l
i
c

Co
n
d
u
c
t
i
v
i
t
y

(f
t
/
d
a
y
)
Ef
f
e
c
t
i
v
e

Po
r
o
s
i
t
y

(%
/
1
0
0
)
Gr
o
u
n
d
w
a
t
e
r

Ve
l
o
c
i
t
y

(f
t
/
d
a
y
)
We
l
l

I
D
Up
g
r
a
d
i
e
n
t

Gr
o
u
n
d
w
a
t
e
r

Co
n
t
o
u
r

El
e
v
a
t
i
o
n

(
f
t
)
D
o
w
n
g
r
a
d
i
e
n
t

Gr
o
u
n
d
w
a
t
e
r

Co
n
t
o
u
r

El
e
v
a
t
i
o
n
(f
t
)
Li
n
e
a
r

D
i
s
t
a
n
c
e

Be
t
w
e
e
n

Co
n
t
o
u
r
s

th
r
o
u
g
h

W
e
l
l
(f
t
)
Hy
d
r
a
u
l
i
c

Gr
a
d
i
e
n
t

(f
t
/
f
t
)
Page 1 of 1
Ta
b
l
e

3

-

F
i
e
l
d

D
a
t
a

P
a
r
a
m
e
t
e
r
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C
/
B
e
l
e
w
s

C
r
e
e
k

S
t
e
a
m

S
t
a
t
i
o
n
Pi
n
e

H
a
l
l

R
o
a
d

A
s
h

L
a
n
d
f
i
l
l

-

P
e
r
m
i
t

N
o
.

8
5
0
3
4/
2
5
/
2
0
1
6

M
W
-
1

4
7
.
2
0

N
S

N
S

N
S

N
S

N
S

N
S

N
S

N
S

N
S

N
S

N
S

N
S

N
S

N
S

N
S
4/
2
5
/
2
0
1
6

M
W
-
1
D

9
0
.
5
3

4
2
.
1
1

8
1
2
.
0
4

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

7
.
9
0

1
4
.
5
0

N
O

1
4
.
2
6

1
2
0

6
.
4

2
.
4

3
3
9

4
.
2
0
4/
2
5
/
2
0
1
6

M
W
-
2

5
0
.
0
0

4
5
.
8
8

8
1
2
.
1
7

N
o
r
m
a
l

N
o
n
e

E
O
P

N
/
A

0
.
6
7

0
.
4
1

N
/
A

N
S

N
S

N
S

N
S

N
S

N
S
4/
2
5
/
2
0
1
6

M
W
-
3

4
9
.
5
0

3
9
.
8
3

8
0
2
.
9
8

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
5
8

1
.
7
5

Y
E
S

1
4
.
1
2

5
4

5
.
2

1
7
.
6

3
9
8

8
.
7
9
4/
2
5
/
2
0
1
6

M
W
-
4

4
0
.
2
0

1
2
.
2
9

7
5
5
.
2
9

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

4
.
5
5

9
.
7
5

N
O

1
4
.
5
6

2
3
5

6
.
0

8
.
7

3
6
2

2
.
9
0
4/
2
5
/
2
0
1
6

M
W
-
5

6
0
.
2
0

2
4
.
4
3

7
6
2
.
3
4

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

5
.
8
3

9
.
7
5

N
O

1
4
.
7
4

3
7

5
.
5

7
.
1

3
9
8

7
.
0
2
4/
2
5
/
2
0
1
6

M
W
-
6

3
6
.
8
4

3
2
.
1
5

8
0
4
.
7
6

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

0
.
7
6

2
.
5
0

N
O

1
5
.
5
1

5
3

5
.
3

4
.
2

3
9
3

4
.
4
4
4/
2
5
/
2
0
1
6

M
W
-
7

1
4
.
2
6

6
.
9
8

8
0
8
.
5
9

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
1
9

6
.
0
0

N
O

1
4
.
8
2

3
6
0

5
.
2

6
5
.
3

3
8
0

6
.
4
4
4/
2
5
/
2
0
1
6

M
W
2
-
7

3
0
.
6
2

1
3
.
9
3

7
6
3
.
7
1

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

2
.
7
2

1
4
.
2
5

N
O

1
4
.
2
7

2
,
0
9
9

5
.
1

3
.
9

4
0
6

1
.
9
8
4/
2
5
/
2
0
1
6

M
W
2
-
9

1
4
.
6
1

6
.
5
4

7
9
0
.
8
4

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
3
2

2
.
0
0

Y
E
S

1
5
.
3
3

2
3
0

6
.
4

8
5
.
7

2
8
0

8
.
9
6
4/
2
5
/
2
0
1
6

O
B
-
4

3
0
.
0
3

2
2
.
3
2

7
5
5
.
2
8

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
2
6

4
.
7
5

N
O

1
5
.
5
0

2
,
7
4
3

7
.
0

3
.
9

3
0
7

0
.
0
0
4/
2
5
/
2
0
1
6

O
B
-
5

3
6
.
6
0

2
5
.
3
3

7
5
5
.
6
0

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
8
4

6
.
0
0

N
O

1
5
.
3
9

2
6
.
0

5
.
2

4
.
2

3
9
7

5
.
8
5
4/
2
5
/
2
0
1
6

O
B
-
9

4
8
.
5
7

3
7
.
3
5

7
6
2
.
2
4

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
8
3

8
.
0
0

N
O

1
4
.
9
0

1
,
7
1
4

5
.
0

1
.
9

3
5
8

0
.
1
6
4/
2
5
/
2
0
1
6

S
W
-
1
A

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

1
4
.
5
5

1
,
2
9
9

5
.
8

5
.
3

3
5
6

6
.
3
5
4/
2
5
/
2
0
1
6

S
W
-
2

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

1
6
.
0
3

1
4
1

6
.
1

1
2
.
4

2
9
9

8
.
4
3
No
t
e
s
:
1
.

P
u
r
g
e

M
e
t
h
o
d
s
;

L
F
=
L
o
w

F
l
o
w
,

L
F
(
M
)
=

L
o
w

F
l
o
w

(
M
o
d
i
f
i
e
d
)
,

C
P
=
C
o
n
v
e
n
t
i
o
n
a
l

P
u
r
g
e

(
3
-
5

w
e
l
l

v
o
l
u
m
e
s
)
,

E
O
P
=
E
q
u
i
p
m
e
n
t

O
n
l
y

P
u
r
g
e,
N
P
=
N
o

P
u
r
g
e

(
H
y
d
r
a
S
l
e
e
v
e
)
.

A
v
e
r
a
g
e

p
u
m
p

r
a
t
e

a
p
p
l
i
c
a
b
l
e

t
o

L
F

a
n
d

L
F
(
M
)

p
u
r
g
i
n
g

o
n
l
y
.
2
.

F
i
e
l
d

s
a
m
p
l
i
n
g

p
e
r
f
o
r
m
e
d

b
y

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

p
e
r
s
o
n
n
e
l
.
3
.

E
V
A
C

i
n
d
i
c
a
t
e
s

w
h
e
t
h
e
r

t
h
e

w
a
t
e
r

l
e
v
e
l

i
n

t
h
e

w
e
l
l

w
a
s

d
r
a
w
n

d
o
w
n

t
o

t
h
e

l
e
v
e
l

o
f

t
h
e

p
u
m
p

d
u
r
i
n
g

p
u
r
g
i
n
g
.
4
.

µƱ /cm

i
n
d
i
c
a
t
e
s

m
i
c
r
o
o
h
m
s

p
e
r

c
e
n
t
i
m
e
t
e
r
.
5
.

S
U

i
n
d
i
c
a
t
e
s

S
t
a
n
d
a
r
d

U
n
i
t
s
.
6
.

N
T
U

i
n
d
i
c
a
t
e
s

N
e
p
h
e
l
o
m
e
t
r
i
c

T
u
r
b
i
d
i
t
y

U
n
i
t
s
.
7
.

m
V
-
N
H
E

i
n
d
i
c
a
t
e
s

m
i
l
l
i
v
o
l
t
s
-
N
o
r
m
a
l

H
y
d
r
o
g
e
n

E
l
e
c
t
r
o
d
e
.
8
.

m
g
/
L

i
n
d
i
c
a
t
e
s

m
i
l
l
i
g
r
a
m
s

p
e
r

l
i
t
e
r
.
9
.

N
/
A

i
n
d
i
c
a
t
e
s

n
o
t

a
p
p
l
i
c
a
b
l
e
.
10
.

N
S

i
n
d
i
c
a
t
e
s

n
o

s
a
m
p
l
e

w
a
s

c
o
l
l
e
c
t
e
d
.
11
.

A

g
r
o
u
n
d
w
a
t
e
r

s
a
m
p
l
e

w
a
s

n
o
t

c
o
l
l
e
c
t
e
d

f
r
o
m

M
W
-
1

a
s

n
e
a
r
b
y

d
r
i
l
l
i
n
g

o
p
e
r
a
t
i
o
n
s

p
r
e
v
e
n
t
e
d

s
a
f
e

a
c
c
e
s
s

t
o

t
h
e

w
e
l
l
.
12
.

A

g
r
o
u
n
d
w
a
t
e
r

s
a
m
p
l
e

w
a
s

n
o
t

c
o
l
l
e
c
t
e
d

f
r
o
m

M
W
-
2

a
s

i
t
s

b
l
a
d
d
e
r

p
u
m
p

t
u
b
i
n
g

i
s

s
u
s
p
e
c
t
e
d

t
o

b
e

c
l
o
g
g
e
d
.
13
.

I
n
f
o
r
m
a
t
i
o
n

p
r
o
v
i
d
e
d

b
y

T
i
m

H
u
n
s
u
c
k
e
r

o
f

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

o
n

M
A
y

4
,

2
0
1
6
.
AP
P
E
A
R
A
N
C
E
DA
T
E

S
A
M
P
L
E

I
D
WE
L
L
DE
P
T
H
(f
e
e
t
)
DE
P
T
H

T
O
WA
T
E
R
(f
e
e
t
)
WA
T
E
R
EL
E
V
.
(f
e
e
t
)
DO (mg/L)
OD
O
R
PU
R
G
E
ME
T
H
O
D

AV
E
R
A
G
E
PU
M
P

RA
T
E
(m
l
/
m
i
n
)
WE
L
L
VO
L
U
M
E
(g
a
l
)
EV
A
C
VO
L
U
M
E
(g
a
l
)
EV
A
C
(Y
E
S
/
N
O
)
TE
M
P
(d
e
g

C
)
SP
E
C
I
F
I
C
CO
N
D
U
C
T
A
N
C
E
(µ
Ʊ /c
m
)
pH
(S
U
)
TURBIDITY (NTU)ORP (mV-NHE)Page 1 of 1
Ta
b
l
e

4

-

F
i
e
l
d

a
n
d

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s

f
o
r

S
e
m
i
a
n
n
u
a
l

C
o
n
s
t
i
t
u
e
n
t
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C
/
B
e
l
e
w
s

C
r
e
e
k

S
t
e
a
m

S
t
a
t
i
o
n
Pi
n
e

H
a
l
l

R
o
a
d

A
s
h

L
a
n
d
f
i
l
l

-

P
e
r
m
i
t

N
o
.

8
5
0
3
Fie
l
d

p
H

3
2
0

S
U

5
1
9
3
-

N
E

6
.
5
-
8
.
5

6
.
5
-
8
.
5
*
Fie
l
d

S
p
e
c
i
f
i
c

C
o
n
d
u
c
t
a
n
c
e

3
2
3

µ
Ʊ /cm

5
1
9
3
-N
E

N
E

N
E
Te
m
p
e
r
a
t
u
r
e

3
2
5

°
C

5
1
9
3
-N
E

N
E

N
E
To
p

C
a
s
i
n
g
32
8

f
e
e
t

-
-N
E

N
E

N
E
De
p
t
h

t
o

W
a
t
e
r
31
8

f
e
e
t

-
-N
E

N
E

N
E
Wa
t
e
r

E
l
e
v
a
t
i
o
n

3
1
9

f
e
e
t

-
-N
E

N
E

N
E
We
l
l

D
e
p
t
h

4
1
1

f
e
e
t

-
-N
E

N
E

N
E
Ar
s
e
n
i
c

1
4

µ
g
/
L

2
4
8

0
.
0
7
8

U

0
.
3
5
3
J
0.
1
2
1

J

0
.
7
9
2
J
0.0
7
8

1
0

1
0

1
0
Ba
r
i
u
m

1
5

µ
g
/
L

2
4
8

2
.
0
3
J
79
.
8
J '
4.1
7

J

3
5
.
5
J '
0.
1

1
0
0

7
0
0

2
,
0
0
0
Bo
r
o
n

4
2
8

µ
g
/
L

2
4
8

6
9
.
4

5
8
.
5
70
3
71
.
2
3.
3

N
E

7
0
0

N
E
Ca
d
m
i
u
m

3
4

µ
g
/
L

2
4
8

0
.
1
0
1

U

0
.
1
0
1

U

0
.
1
0
1

U

0
.
1
0
1

U
0.1
0
1

1

2

5
Ch
l
o
r
i
d
e

4
5
5

µ
g
/
L

2
4
8

8
,
4
5
0

1
0
,
1
0
0

2
,
5
6
0

2
,
0
3
0
22

N
E

2
5
0
,
0
0
0

2
5
0
,
0
0
0
*
Ch
r
o
m
i
u
m

5
1

µ
g
/
L

2
4
8

0
.
5

U

2
.
9
6
J
14
1.9
J
0.
5

1
0

1
0

1
0
0
Co
p
p
e
r
54

µ
g
/
L

2
4
8

1

U

1

U

1

U

1
0
5
1

1
0

1
,
0
0
0

1
,
3
0
0
Fl
u
o
r
i
d
e

3
1
2

µ
g
/
L

2
4
8

8
6
.
1
J
17

U

1
7

U

1
7

U
17

2
,
0
0
0

2
,
0
0
0

4
,
0
0
0
Ir
o
n

3
4
0

µ
g
/
L

2
4
8

5
.
0
6
J
85
4

4
5
5

4
5
5
1.
3

3
0
0

3
0
0

3
0
0
*
Le
a
d

1
3
1

µ
g
/
L

2
4
8

0
.
0
6
5

U

0
.
4
5
2
J
0.0
7
0
8

J

8
.
5
7
J '
0.0
6
5

1
0

1
5

1
5
Ma
n
g
a
n
e
s
e

3
4
2

µ
g
/
L

2
4
8

4
.
0
8
J
16
.
4
J '
7.2
7
J '
13
J '
0.
2

5
0

5
0

5
0
*
Me
r
c
u
r
y

1
3
2

µ
g
/
L

2
4
8

0
.
0
3
3
4

U

0
.
0
3
3
4

U

0
.
0
3
3
4

U

0
.
0
3
3
4

U
0.
0
3
3
4

0
.
2

1

2
Ni
c
k
e
l

1
5
2

µ
g
/
L

2
4
8

0
.
5

U

0
.
5

U

0
.
5
0
6

J

0
.
5

U
0.
5

5
0

1
0
0

N
E
Nit
r
a
t
e

(
a
s

N
i
t
r
o
g
e
n
)

3
0
3

µ
g
/
L

2
4
8

1
,
8
8
0
J '
5.
4

U

9
4
7
J '
63
2
J '
5.
4

1
0
,
0
0
0

1
0
,
0
0
0

1
0
,
0
0
0
Se
l
e
n
i
u
m

1
8
3

µ
g
/
L

2
4
8

0
.
1
5
J
0.
0
9
2

U

1
5
.
4

0
.
0
9
2

U
0.0
9
2

1
0

2
0

5
0
Sil
v
e
r

1
8
4

µ
g
/
L

2
4
8

0
.
7

U

0
.
7

U

0
.
7

U

0
.
7

U
0.
7

1
0

2
0

1
0
0
*
Su
l
f
a
t
e

3
1
5

µ
g
/
L

2
4
8

9
6
5
J '
14
6
J '
74
,
8
0
0
J '
16
9
J '
18

2
5
0
,
0
0
0

2
5
0
,
0
0
0

2
5
0
,
0
0
0
*
To
t
a
l

D
i
s
s
o
l
v
e
d

S
o
l
i
d
s
31
1

µ
g
/
L

2
4
8

8
4
,
0
0
0

4
6
,
0
0
0

1
7
9
,
0
0
0

3
7
,
0
0
0
16
,
7
0
0

N
E

5
0
0
,
0
0
0

5
0
0
,
0
0
0
*
Zin
c

2
1
3

µ
g
/
L

2
4
8

2
.
6
U
5.2
3
J '
2.
6

U

6
2
.
2
2.
6

1
0

1
,
0
0
0

5
,
0
0
0
*
No
t
e
s
:
1
.

C
o
n
c
e
n
t
r
a
t
i
o
n
s

p
r
e
s
e
n
t
e
d

i
n

m
i
c
r
o
g
r
a
m
s

p
e
r

l
i
t
e
r

(
µ
g
/
L
)
.
2
.

S
W
S

I
D

i
s

t
h
e

S
o
l
i
d

W
a
s
t
e

S
e
c
t
i
o
n

I
d
e
n
t
i
f
i
c
a
t
i
o
n

N
u
m
b
e
r
.
3
.

M
D
L

i
s

t
h
e

l
a
b
o
r
a
t
o
r
y

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
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m
e
a
s
u
r
e
d

a
t

2
0
.
5

N
T
U.
Ch
r
o
m
i
u
m

M
W
-
4

1
4

µ
g
/
L

1
0

5
.
8

-

2
9

C
h
r
o
m
i
u
m

i
n

M
W
-
4

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
a
d
i
n
g
s

a
t

w
e
l
l
.

T
u
r
b
i
d
i
t
y

i
s

m
e
a
s
u
r
e
d

a
t

3
6

N
T
U
.
MW
-
4

4
5
5

µ
g
/
L

2
6

-

8
,
5
1
6

I
r
o
n

i
n

M
W
-
4

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
a
d
i
n
g
s

a
t

w
e
l
l
.

T
u
r
b
i
d
i
t
y

i
s

m
e
a
s
u
r
e
d

a
t

3
6

N
T
U
.
MW
2
-
7

5
1
5

7
0
.
9
6

-

4
6
9

M
a
n
g
a
n
e
s
e

i
n

M
W
2
-
7

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
a
d
i
n
g
s

a
t

w
e
l
l
.

T
u
r
b
i
d
i
t
y

i
s

m
e
a
s
u
r
e
d

a
t

1
1
.
8

N
T
U
.
OB
-
4

1
1
6

4
5

-

5
,
7
7
9

M
a
n
g
a
n
e
s
e

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n

O
B
-
4

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s

c
o
n
s
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s
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e
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t

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h
i
s
t
o
r
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c
a
l

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a
d
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n
g
s

a
t

w
e
l
l
.

T
u
r
b
i
d
i
t
y

i
s

m
e
a
s
u
r
e
d

a
t

1
7

N
T
U
.
OB
-
9

1
,
6
0
0

1
,
0
1
0

-

3
,
7
6
6

M
a
n
g
a
n
e
s
e

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n

O
B
-
9

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s

c
o
n
s
i
s
t
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n
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w
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t
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h
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s
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o
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c
a
l

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a
d
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n
g
s

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t

w
e
l
l
.

T
u
r
b
i
d
i
t
y

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s

m
e
a
s
u
r
e
d

a
t

2
0
.
5

N
T
U
.
Ni
t
r
a
t
e

a
s

N

M
W
2
-
7

3
7
,
0
0
0

µ
g
/
L

1
0
,
0
0
0

4
,
1
8
0

-

4
3
,
9
0
0

N
i
t
r
a
t
e

a
s

N

i
n

M
W
2
-
7

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
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c
a
l

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a
d
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n
g
s

a
t

w
e
l
l
.

T
u
r
b
i
d
i
t
y

is

m
e
a
s
u
r
e
d

a
t

1
1
.
8

N
T
U
.
MW
2
-
7

1
5
6

6
6
.
3
2

-

2
0
4

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e
l
e
n
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m

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n

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W
2
-
7

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s

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o
n
s
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s
t
e
n
t

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h
i
s
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o
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c
a
l

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a
d
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n
g
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a
t

w
e
l
l
.

T
u
r
b
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d
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t
y

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s

m
e
a
s
u
r
e
d

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t

1
1
.
8

N
T
U
.
OB
-
4

1
3
5

1
0
.
6
3

-

3
5
0
.
4

S
e
l
e
n
i
u
m

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n

O
B
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4

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s

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o
n
s
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s
t
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n
t

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t
h

h
i
s
t
o
r
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c
a
l

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a
d
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n
g
s

a
t

w
e
l
l
.

T
u
r
b
i
d
i
t
y

i
s

m
e
a
s
u
r
e
d

a
t

1
7

N
T
U
.
OB
-
9

2
6
2

1
2
5
.
6

-

4
0
1

S
e
l
e
n
i
u
m

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n

O
B
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9

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s

c
o
n
s
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s
t
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n
t

w
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t
h

h
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s
t
o
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c
a
l

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e
a
d
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n
g
s

a
t

w
e
l
l
.

T
u
r
b
i
d
i
t
y

i
s

m
e
a
s
u
r
e
d

a
t

2
0
.
5

N
T
U
.
MW
2
-
7

1
,
3
0
0
,
0
0
0

1
9
0
,
4
0
0

-

1
,
2
7
0
,
0
0
0

S
u
l
f
a
t
e

i
n

M
W
2
-
7

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s

c
o
n
s
i
s
t
e
n
t

w
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t
h

h
i
s
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o
r
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c
a
l

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a
d
i
n
g
s

a
t

w
e
l
l
.

T
u
r
b
i
d
i
t
y

i
s

m
e
a
s
u
r
e
d

a
t

1
1
.
8
NTU.
OB
-
4

1
,
5
2
0
,
0
0
0

2
6
,
0
0
0

-

1
,
7
4
6
,
5
5
0

S
u
l
f
a
t
e

i
n

O
B
-
4

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s

c
o
n
s
i
s
t
e
n
t

w
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t
h

h
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s
t
o
r
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c
a
l

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a
d
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n
g
s

a
t

w
e
l
l
.

T
u
r
b
i
d
i
t
y

i
s

m
e
a
s
u
r
e
d

a
t

1
7

N
T
U
.
OB
-
9

9
4
2
,
0
0
0

4
4
,
7
9
0

-

1
,
3
1
1
,
0
0
0

S
u
l
f
a
t
e

i
n

O
B
-
9

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s

c
o
n
s
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s
t
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n
t

w
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t
h

h
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s
t
o
r
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c
a
l

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a
d
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n
g
s

a
t

w
e
l
l
.

T
u
r
b
i
d
i
t
y

i
s

m
e
a
s
u
r
e
d

a
t

2
0
.
5

N
T
U
.
MW
2
-
7

1
,
8
6
0
,
0
0
0

5
3
6
,
0
0
0

-

2
1
3
,
0
0
0
0

T
o
t
a
l

D
i
s
s
o
l
v
e
d

S
o
l
i
d
s

i
n

M
W
2
-
7

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s

c
o
n
s
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s
t
e
n
t

w
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t
h

h
i
s
t
o
r
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c
a
l

r
e
a
d
i
n
g
s

a
t

w
e
l
l
.

T
u
r
b
i
d
i
t
y

i
s

m
e
asured at 11.8 NTU.
OB
-
4

2
,
5
9
0
,
0
0
0

1
,
9
5
0
,
0
0
0

-

2
,
9
0
0
,
0
0
0

T
o
t
a
l

D
i
s
s
o
l
v
e
d

S
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l
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d
s

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n

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B
-
4

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s

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n
s
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s
t
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n
t

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t
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h
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s
t
o
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c
a
l

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a
d
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n
g
s

a
t

w
e
l
l
.

T
u
r
b
i
d
i
t
y

i
s

m
easured at 17 NTU.
OB
-
9

1
,
4
0
0
,
0
0
0

1
,
5
3
0
,
0
0
0

-

2
,
1
7
0
,
0
0
0

T
o
t
a
l

D
i
s
s
o
l
v
e
d

S
o
l
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d
s

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n

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B
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9

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s

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n
s
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s
t
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t

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t
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h
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s
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d
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n
g
s

a
t

w
e
l
l
.

T
u
r
b
i
d
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t
y

i
s

m
easured at 20.5 NTU.
No
t
e
s
:
1
.

1
5
A

N
C
A
C

2
L

S
t
a
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r
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t
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l
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s

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A

S
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a
n
d
a
r
d
s

a
s

f
o
u
n
d

i
n

1
5
A

N
C
A
C

0
2
L

.
0
2
0
2

G
r
o
u
n
d
w
a
t
e
r

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a
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d
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r
d
s
,

l
a
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t

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m
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n
d
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d

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n

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p
ri
l

1
,

2
0
1
3

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A
p
p
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n
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r
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v
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d

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p
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l

1
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)
.
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.

µ
g
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L

i
n
d
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c
a
t
e
s

m
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c
r
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g
r
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m
s

p
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l
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t
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r
.
3
.

S
U

i
n
d
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c
a
t
e
s

S
t
a
n
d
a
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d

U
n
i
t
s
.
4
.

N
T
U

i
n
d
i
c
a
t
e
s

N
e
p
h
e
l
o
m
e
t
r
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c

T
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r
b
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d
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t
y

U
n
i
t
s
.
5
.

H
i
s
t
o
r
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c
a
l

c
o
n
c
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n
t
r
a
t
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o
n
s

b
a
s
e
d

o
n

d
a
t
a

i
n

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

a
n
a
l
y
t
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l

r
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s
u
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t
s

d
a
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a
b
a
s
e
.
6
.

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t
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n
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t

d
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c
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w
h
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e
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t
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l
a
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m
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l
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(
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)

a
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p
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M
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.
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.

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l

c
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r
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t
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c
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r
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q
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t
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b
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a
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t
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Gr
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r

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A
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r

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n
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a

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)

p
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l
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,

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n

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a
y

2
5
,

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1
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.
Se
l
e
n
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u
m

2
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µg
/
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Sa
m
p
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e
:

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n
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.
5
µg
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To
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a
l

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s
o
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v
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l
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s
µg
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5
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0
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Su
l
f
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µ
g
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L

2
5
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5
0
Page 1 of 1
Ta
b
l
e

6

-

S
e
m
i
a
n
n
u
a
l

C
o
n
s
t
i
t
u
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n
t
s

1
5
A

N
C
A
C

2
L

G
r
o
u
n
d
w
a
t
e
r

Q
u
a
l
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E
x
c
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d
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s
at

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r

B
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y
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R
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B
o
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Du
k
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E
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C
a
r
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l
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a
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,

L
L
C
/
B
e
l
e
w
s

C
r
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e
k

S
t
e
a
m

S
t
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l
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R
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s
h

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a
n
d
f
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l
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-

P
e
r
m
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t

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8
5
0
3
Pa
r
a
m
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t
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r

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a
m
p
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e

I
D

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e
s
u
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t

U
n
i
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15
A

N
C
A
C
2L

S
t
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His
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a
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3

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Page 1 of 1

A
Appendix A
Field Sampling Forms

ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬▬►0.0 0.0 ▬/▬►0.0
SS 226.2 ▬▬►227 222.3 ▬/▬►227
SS 73.6 ▬/▬►75 75.7 ▬/▬►75
SS 2182.4 ▬/▬►2200 2193.4 ▬/▬►2200
B (7.00)6.97 ▬▬►7.02 7.11 ▬/▬►7.02
B (4.00)3.96 ▬▬►4.00 4.04 ▬/▬►4.00
B (10.00)10.23 ▬/▬►10.06 10.21 ▬/▬►10.06
20.26 19.67
pH Check B (7.00)▬▬►7.13
Time:0.00
437 ▬▬►441 438 ▬/▬►441
N/A ▬/▬►N/A N/A ▬/▬►N/A
Zobell's 20.20 19.89
TEMP (CO)
BP (mmHg)
COND
100 % mg/L 8.99 ▬▬►8.93 8.97 ▬/▬►8.95
After Cal 8.92 99.84 8.98 100.31
LCS 8.93 99.96 8.98 100.31
LCSD 8.89 -0.45 8.92 -0.67
SS 54.3 ▬/▬►56.0 54.6 ▬/▬►56.0
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
FIELD SAMPLING CALIBRATION FORM
STUDY:BELEWS CREEK STEAM STATION - PINE HALL LANDFILL GROUNDWATER MONITORING
DATE (s):April 25, 2016 SURFACE UNIT READER:LDC
OTHER EQUIPMENT:TURBIDIMETER NO.2 - 3260-GW Clear, calm, 60 to 80 deg F.
COLLECTORS:LDC, PSP, HET SURFACE UNIT SERIAL #:0662
ANALYZER MODEL#:HL4 400437
Calibration Date / Time 25-Apr-16 400 26-Apr-16 650
PROCEDURE #:HYDROLAB 3210.5 VALIDATED BY:
Parameter Calibration Results Calibration Results
CALIBRATION BP (mmHg)742.66 CALIBRATION BP (mmHg)740.19
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
INSTRUMENT ZEROED INSTRUMENT ZEROED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
SPEC. COND.
(uS/cm)
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION FAILED CALIBRATION FAILED
Buffer Temp.Buffer Temp.
ORP Temp.ORP Temp.
ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.
107.8
CALIBRATION PASS CALIBRATION PASS
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
After Cal % SAT After Cal % SAT
TURB
(ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION PASS CALIBRATION PASS
DO
(mg/L)
19.68 19.41
742.66 740.19
106
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 744.0 (mmHg)Ending BP 742.7
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬▬►0.0 0.0 ▬/▬►0.0
SS 222.6 ▬▬►227 223.5 ▬/▬►227
SS 75.4 ▬/▬►75 76.2 ▬/▬►75
SS 2258.4 ▬/▬►2200 2262.2 ▬/▬►2200
B (7.00)7.00 ▬▬►7.02 7.04 ▬/▬►7.02
B (4.00)3.98 ▬▬►4.00 3.98 ▬/▬►4.00
B (10.00)10.05 ▬/▬►10.06 10.07 ▬/▬►10.06
20.20 20.11
pH Check B (7.00)▬▬►7.13
Time:0.00
437 ▬▬►441 441 ▬/▬►441
N/A ▬/▬►N/A N/A ▬/▬►N/A
Zobell's 20.17 19.95
TEMP (CO)
BP (mmHg)
COND
100 % mg/L 8.95 ▬▬►8.93 8.97 ▬/▬►8.92
After Cal 8.95 100.20 8.98 100.66
LCS 8.94 100.09 8.97 100.54
LCSD 8.91 -0.34 8.94 -0.34
SS 53.0 ▬/▬►53.5 53.1 ▬/▬►53.5
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
FIELD SAMPLING CALIBRATION FORM
STUDY:BELEWS CREEK STEAM STATION - PINE HALL LANDFILL GROUNDWATER MONITORING
DATE (s):April 25, 2016 SURFACE UNIT READER:PSP
OTHER EQUIPMENT:TURBIDIMETER NO.1 - 3260-GW Clear, calm, 60 to 80 deg F.
COLLECTORS:LDC, PSP, HET SURFACE UNIT SERIAL #:0730
ANALYZER MODEL#:HL4 400440
Calibration Date / Time 25-Apr-16 430 26-Apr-16 520
PROCEDURE #:HYDROLAB 3210.5 VALIDATED BY:
Parameter Calibration Results Calibration Results
CALIBRATION BP (mmHg)742.66 CALIBRATION BP (mmHg)740.19
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
INSTRUMENT ZEROED INSTRUMENT ZEROED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
SPEC. COND.
(uS/cm)
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.Buffer Temp.
ORP Temp.ORP Temp.
ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.
106.9
CALIBRATION PASS CALIBRATION PASS
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
After Cal % SAT After Cal % SAT
TURB
(ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION PASS CALIBRATION PASS
DO
(mg/L)
19.69 19.58
742.66 740.19
108
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 744.0 (mmHg)Ending BP 742.7
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
37.20 47.20
25 (psi)8 (sec)(sec)
(gal)
(gal)
@
QC By:
SAMPLING NOTES
ADDITIONAL WELL CONDITION NOTES
Good Tag
WELL CONDITION
PROTECTIVE CASING
WELL PAD
WELL TAG
Good Condition
Good Condition
Good ConditionWELL CASING
N/A
TOTAL PURGE
VOLUME
0.00
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
CHLORINE (mg/l)SAMPLE COLLECTED BY
(recalculates on
current water
level)(deg C)(umho/cm)(SU)(NTU)(mV-NHE)(mg/L)
SAMPLING EQUIPMENT
TUBING DIAMETER (in)1/2 OD
QED T1200
PURGE COMPLETE TEMP SPECIFIC pH TURBIDITY
WATER ELEVATION (ft msl)
APPEARANCE
DETECTED ODOR None
Normal
WATER LEVEL
AFTER PURGE *
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88
WELL DEPTH (ft TOC)
WELL DIAMETER (in)MIDDLE OF WETTED SCREEN (ft toc)
WELL VOL
SCREEN INTERVAL (ft TOC)TO
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)WATER COLUMN (ft)
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
46.20PUMP INTAKE DEPTH (ft TOC)47.20
TOC ELEV (ft msl)
GS ELEV (ft msl)
852.69
850.55
WELL/LOCATION NAME MW-1
FIELD CREW LDC, PSP, HET
MONITORING WELL INFORMATION
2
N/A
PROCEDURE NO 3175.3DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID
PROJECT NAME PINE HALL LANDFILL
SAMPLING DATE(s)25-Apr-2016
42.20
PURGE METHOD
Conventional
DISCHARGERECHARGEPRESSURE 12
PUMP CONTROLLER SETTINGS
0.1631CONVERSION FACTOR
Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WELL VOLUME
(gal)
ORP
(ft)(YES/NO)
VOLUME EVACUATION COND.
4/25/2016
Sample preservation verified to pH
(units)
No sample - drilling beside well.
DATE TIME
DISSOLVED
OXYGEN
85.53 90.53
60 (psi)9 (sec)(sec)
(gal)
7.90 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)25-Apr-2016 WELL/LOCATION NAME MW-1D
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)854.15 MIDDLE OF WETTED SCREEN (ft toc)88.03
SCREEN LENGTH (ft)5.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)90.53 GS ELEV (ft msl)850.99 PUMP INTAKE DEPTH (ft TOC)89.50
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 6
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
See note below
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)42.11 WATER COLUMN (ft)48.42 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)812.04 WELL VOLUME 7.90
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
8.00 70.71 NO 14.19 115 6.32 2.9 339
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
4.27 3.23
3.25 NO 14.26 120 6.39 2.4 339 4.20
3.25 NO 14.26 120 6.37 2.4 340 4.15
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
14.50 LDC 4/25/2016 1055 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
After initial well is removed, recalculate well volume for subsequent readings. WL drawdown appears to stabilize around 64 ft.
40.00 50.00
30 (psi)5 (sec)(sec)
(gal)
1075 (ml)
495 (ml)
1570 (ml)=0.41 (gal)@
QC By:
SAMPLING NOTES
4/24/12 - Replaced pump and tubing in well and set intake to 49.5 ft (six inches from well bottom). Could not get pump to discharge regardless of settings - ants inside air line -
suspect clogged tubing. No sample.
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
SAMPLE COLLECTED BY DATE TIME
Total Purge Volume 4/25/2016
Sample preservation verified to pH
(units)
N/A
Tubing Volume EQUIPMENT PURGE ONLY SAMPLE CHLORINE
(mg/l)Pump (Bladder) Volume
(ft)(ml/min)(ft)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
WATER LEVEL RATE WATER LEVEL COND.OXYGEN
INITIAL FLOW FINAL TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)45.88 WATER COLUMN (ft)4.12 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)812.17 WELL VOLUME 0.67
See note below - No sample PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Equip. Only Purge
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)858.05 MIDDLE OF WETTED SCREEN (ft toc)47.94
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)50.00 GS ELEV (ft msl)855.44 PUMP INTAKE DEPTH (ft TOC)49.50
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)25-Apr-2016 WELL/LOCATION NAME MW-2
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR EQUIPMENT PURGE ONLY SAMPLING
39.50 49.50
25 (psi)14 (sec)(sec)
(gal)
1.58 (gal)
@
QC By:
SAMPLING NOTES
Evacuated 4/25/16 at 1125 hrs
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
1.75 LDC 4/25/2016 1130 N/A
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.75 YES 14.12 54 5.23 17.6 398
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
8.79
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)39.83 WATER COLUMN (ft)9.67 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)802.98 WELL VOLUME 1.58
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 6
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)842.81 MIDDLE OF WETTED SCREEN (ft toc)44.67
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)49.50 GS ELEV (ft msl)840.57 PUMP INTAKE DEPTH (ft TOC)48.50
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)25-Apr-2016 WELL/LOCATION NAME MW-3
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
30.20 40.20
22 (psi)10 (sec)(sec)
(gal)
4.55 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
9.75 LDC 4/25/2016 0935 N/A
2.16
2.25 NO 14.56 235 5.97 8.7 362 2.90
2.75 26.94 NO 14.51 238 6.00 14.0 362 3.27
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
4.75 23.93 NO 14.44 233 6.03 20.4 363
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
4.31 2.65
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)12.29 WATER COLUMN (ft)27.91 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)755.29 WELL VOLUME 4.55
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)767.58 MIDDLE OF WETTED SCREEN (ft toc)35.20
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)40.20 GS ELEV (ft msl)766.10 PUMP INTAKE DEPTH (ft TOC)39.20
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)25-Apr-2016 WELL/LOCATION NAME MW-4
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
50.20 60.20
30 (psi)6 (sec)(sec)
(gal)
5.83 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
9.75 PSP, HET 4/25/2016 1455 N/A
1.74
1.75 NO 14.74 37 5.54 7.1 398 7.02
2.00 49.56 NO 14.79 37 5.52 8.3 403 7.04
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
6.00 49.37 NO 14.77 37 5.51 8.2 410
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
7.14 1.77
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)24.43 WATER COLUMN (ft)35.77 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)762.34 WELL VOLUME 5.83
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 9
28652 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)786.77 MIDDLE OF WETTED SCREEN (ft toc)55.20
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)60.20 GS ELEV (ft msl)785.39 PUMP INTAKE DEPTH (ft TOC)59.20
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)25-Apr-2016 WELL/LOCATION NAME MW-5
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
26.84 36.84
25 (psi)6 (sec)(sec)
(gal)
0.76 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
2.50 LDC 4/25/2016 1220 N/A
0.75 NO 15.51 53 5.32 4.2 393 4.44
0.75 NO 15.47 53 5.32 5.0 393 4.41
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.00 32.73 NO 15.28 52 5.34 7.0 393
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
4.68 0.67
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)32.15 WATER COLUMN (ft)4.69 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)804.76 WELL VOLUME 0.76
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 4
26054 SAMPLING EQUIPMENT QED T1250 PURGE METHOD
TUBING DIAMETER (in)1/4 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)836.91 MIDDLE OF WETTED SCREEN (ft toc)34.50
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)36.84 GS ELEV (ft msl)834.40 PUMP INTAKE DEPTH (ft TOC)35.84
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)25-Apr-2016 WELL/LOCATION NAME MW-6
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
4.26 14.26
20 (psi)10 (sec)(sec)
(gal)
1.19 (gal)
@
QC By:
SAMPLING NOTES
Changed above settings for last reading to 10 psi 10 recharge and 10 discharge to try to reduce turbidity, Turbidity was 131 NTU's before changing settings. Tried to reduce
turbidity by continuing purging, which would not reduce below 65 for two readings in a row.
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
6.00 HET, PSP 4/25/2016 0935 N/A
0.56
1.50 NO 14.82 360 5.17 65.3 380 6.44
0.75 10.83 NO 13.74 371 5.21 24.6 362 5.89
0.72
0.75 10.52 NO 13.63 388 5.25 21.6 360 5.82 0.61
1.00 9.86 NO 13.59 387 5.22 23.3 358 5.62
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
2.00 8.92 NO 13.88 380 5.24 38.1 249
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
5.63 0.87
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)6.98 WATER COLUMN (ft)7.28 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)808.59 WELL VOLUME 1.19
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
28652 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)815.57 MIDDLE OF WETTED SCREEN (ft toc)10.62
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)14.26 GS ELEV (ft msl)812.52 PUMP INTAKE DEPTH (ft TOC)13.26
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)25-Apr-2016 WELL/LOCATION NAME MW-7
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
20.62 30.62
25 (psi)5 (sec)(sec)
(gal)
2.72 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
14.25 HET, PSP 4/25/2016 1100 N/A
2.75 NO 14.27 2099 5.05 3.9 406 1.98
3.25 NO 14.21 1996 4.99 4.4 402 0.01
2.75 NO 14.25 2003 5.00 2.9 399 0.00
2.75 NO 14.20 1865 5.03 6.1 398 0.54
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
2.75 NO 14.15 1265 5.00 5.1 389
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
0.00
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)13.93 WATER COLUMN (ft)16.69 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)763.71 WELL VOLUME 2.72
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 7
28652 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)777.64 MIDDLE OF WETTED SCREEN (ft toc)25.62
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)30.62 GS ELEV (ft msl)775.45 PUMP INTAKE DEPTH (ft TOC)29.62
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)25-Apr-2016 WELL/LOCATION NAME MW2-7
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
4.61 14.61
10 (psi)5 (sec)(sec)
(gal)
1.32 (gal)
@
QC By:
SAMPLING NOTES
Water level at 1350 was 10.81 feet below TOC.
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
2.00 PSP, HET, LDC 4/25/2016 1355 N/A
0.50 YES 15.33 230 6.40 85.7 280 8.96
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.50 12.42 NO 13.00 150 5.94 83.7 251
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
0.03 0.36
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)6.54 WATER COLUMN (ft)8.07 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)790.84 WELL VOLUME 1.32
04/25/2016 evacuated at 0830 hrs.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
28652 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)797.38 MIDDLE OF WETTED SCREEN (ft toc)10.58
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)14.61 GS ELEV (ft msl)794.75 PUMP INTAKE DEPTH (ft TOC)13.61
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)25-Apr-2016 WELL/LOCATION NAME MW2-9
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
15.03 30.03
15 (psi)5 (sec)(sec)
(gal)
1.26 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
4.75 HET, PSP 4/25/2016 1150 N/A
1.75 NO 15.50 2743 7.00 3.9 307 0.00
1.50 NO 15.56 2774 7.00 5.0 314 0.00
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.50 NO 15.61 2794 7.01 7.8 322
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
0.15
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)22.32 WATER COLUMN (ft)7.71 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)755.28 WELL VOLUME 1.26
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
28652 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)777.60 MIDDLE OF WETTED SCREEN (ft toc)26.18
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)30.03 GS ELEV (ft msl)774.72 PUMP INTAKE DEPTH (ft TOC)29.10
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)25-Apr-2016 WELL/LOCATION NAME OB-4
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
21.60 36.60
18 (psi)8 (sec)(sec)
(gal)
1.84 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
6.00 LDC 4/25/2016 0830 N/A
2.00 NO 15.39 26 5.17 4.2 397 5.85
2.00 NO 15.37 25 5.16 3.8 377 5.49
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
2.00 NO 15.37 24 5.17 3.7 372
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
5.10
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)25.33 WATER COLUMN (ft)11.27 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)755.60 WELL VOLUME 1.84
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 7
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)780.93 MIDDLE OF WETTED SCREEN (ft toc)30.97
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)36.60 GS ELEV (ft msl)778.13 PUMP INTAKE DEPTH (ft TOC)35.50
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)25-Apr-2016 WELL/LOCATION NAME OB-5
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
39.17 48.57
25 (psi)10 (sec)(sec)
(gal)
1.83 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)25-Apr-2016 WELL/LOCATION NAME OB-9
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)799.59 MIDDLE OF WETTED SCREEN (ft toc)43.87
SCREEN LENGTH (ft)9.40 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)48.57 GS ELEV (ft msl)797.11 PUMP INTAKE DEPTH (ft TOC)46.00
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
28652 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
1.83
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)37.35 WATER COLUMN (ft)11.22 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)762.24 WELL VOLUME
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
2.00 NO 14.92 1765 5.38 3.4 284
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
0.00
2.00 NO 14.97 1745 5.00 1.9 347 0.13
2.00 NO 14.90 1768 4.97 1.9 328 0.00
2.00 NO 14.90 1714 4.97 1.9 358 0.16
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
8.00 HET, PSP 4/25/2016 1250 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
N/A
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)25-Apr-2016 WELL/LOCATION NAME SW-1A
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)N/A
SCREEN LENGTH (ft)N/A ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)N/A GS ELEV (ft msl)762.27 PUMP INTAKE DEPTH (ft TOC)N/A
Surface Water Location PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
N/A
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)N/A Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)N/A WELL VOLUME
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
HET, PSP 4/25/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 14.55 1299 5.78 5.3
1010
356 6.35
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
N/A
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)25-Apr-2016 WELL/LOCATION NAME SW-2
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)N/A
SCREEN LENGTH (ft)N/A ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)N/A GS ELEV (ft msl)775.30 PUMP INTAKE DEPTH (ft TOC)N/A
Surface Water Location PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
N/A
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)N/A Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)N/A WELL VOLUME
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
HET, PSP 4/25/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 16.03 141 6.14 12.4
1315
299 8.43
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
PERMIT #
MW-1 MW-1D MW-2 MW-3 MW-4 MW-5 MW-6 MW-7 MW2-7 MW2-9 OB-4 OB-5 OB-9 SW-1 SW-2
YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A N/A
N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A N/A
NORTH CAROLINA GROUNDWATER SAMPLING SITE CHECKLIST
LOCATION / SITE 85-03 SAMPLE DATE April 25, 2016BELEWS CREEK STEAM STATION - PINE HALL LANDFILL GROUNDWATER MONITORING
SITE CONTACT FIELD CREW LDC, PSP, HET
WEATHER Clear, calm, 60 to 80 deg F.
Melonie Martin, Kimberly Witt, Will Harrison
WELL LOCK CONDITION
PAGE 1 OF 1
ACCESS TO WELLS
Access cleared into well
Access cleared around well
Tall grass or weeds - needs mowing
Road washing out / muddy / needs grading
Fallen tree blocking access
WELL SECURITY
Well found locked
Well found unlocked
Undermined / washing out
Lock in good condition
Lock rusted, difficult to open / needs replacing
Replaced damaged lock
WELL CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
CONCRETE PADS
Pad in good condition
Minor cracks
Major cracks / broken / repair required
Replaced damaged well cap
Fire ants around concrete pad
WELL PROTECTIVE CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
Broken hinge on protective lid
Wasp nest inside protective casing
Ants inside protective casing
WELL CAPS
Well cap in good conditon
Damaged / needs replacement
Lacks required information - Completion date
FLUSH MOUNT WELLS
Vault in good condition
Water inside vault
Vault bolt holes broken or stripped
Bolts stripped
Vault lid cracked or broken
WELL ID TAGS
Well tag in good condition
Well tag missing
Well tag damaged / illegible
Lacks required information - Driller Reg #
Lacks required information - Total well depth
Lacks required information - Depth to screen
Lacks required information - Non potable tag
NOTE:
WELL DEPTH TO WATER Purge AVG *WELL EVAC SPECIFIC
WELL DEPTH WATER ELEV.Method PMP RATE VOL VOL EVAC TEMP CONDUCTANCE pH TURBIDITY ORP DO
DATE NO.(feet-toc)(feet-toc)(feet)APPEARANCE ODOR (ml/min)(gal)(gal)(yes/no)(deg C)(umho/cm)(units)(NTU)(mV-NHE)(mg/l)
4/25/2016 MW-1 47.20 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
4/25/2016 MW-1D 90.53 42.11 812.04 Normal None C N/A 7.90 14.50 NO 14.26 120 6.4 2.4 339 4.20
4/25/2016 MW-2 50.00 45.88 812.17 Normal None EOP N/A 0.67 0.41 N/A 0.00 0 0.0 0.0 0 0.00
4/25/2016 MW-3 49.50 39.83 802.98 Normal None C N/A 1.58 1.75 YES 14.12 54 5.2 17.6 398 8.79
4/25/2016 MW-4 40.20 12.29 755.29 Normal None C N/A 4.55 9.75 NO 14.56 235 6.0 8.7 362 2.90
4/25/2016 MW-5 60.20 24.43 762.34 Normal None C N/A 5.83 9.75 NO 14.74 37 5.5 7.1 398 7.02
4/25/2016 MW-6 36.84 32.15 804.76 Normal None C N/A 0.76 2.50 NO 15.51 53 5.3 4.2 393 4.44
4/25/2016 MW-7 14.26 6.98 808.59 Normal None C N/A 1.19 6.00 NO 14.82 360 5.2 65.3 380 6.44
4/25/2016 MW2-7 30.62 13.93 763.71 Normal None C N/A 2.72 14.25 NO 14.27 2099 5.1 3.9 406 1.98
4/25/2016 MW2-9 14.61 6.54 790.84 Normal None C N/A 1.32 2.00 YES 15.33 230 6.4 85.7 280 8.96
4/25/2016 OB-4 30.03 22.32 755.28 Normal None C N/A 1.26 4.75 NO 15.50 2743 7.0 3.9 307 0.00
4/25/2016 OB-5 36.60 25.33 755.60 Normal None C N/A 1.84 6.00 NO 15.39 26 5.2 4.2 397 5.85
4/25/2016 OB-9 48.57 37.35 762.24 Normal None C N/A 1.83 8.00 NO 14.90 1714 5.0 1.9 358 0.16
4/25/2016 SW-1A N/A N/A N/A Normal None NP N/A N/A N/A N/A 14.55 1299 5.8 5.3 356 6.35
4/25/2016 SW-2 N/A N/A N/A Normal None NP N/A N/A N/A N/A 16.03 141 6.1 12.4 299 8.43
Purge Methods
LF = Low Flow
LF(M) = Low Flow (Mod.)
C = Connventional
NP = No Purge
EOP = Equip. Only Purge
LO = Level Only
NS = Not Sampled - MW-1 was not sampled due to well drilling activity adjacent to the well
* = Applicable to LF & LF(M) Purging Only
BELEWS CREEK STEAM STATION
PINE HALL LANDFILL
GROUNDWATER MONITORING FIELD DATA
PERMIT #85-03

B
Appendix B
Laboratory Report and
Chain-of-Custody Forms

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16040004
Project Name:BELEWS - GW PINE HALL LF
Lab Contact:Peggy Kendall
Date:5/12/2016
Customer Address:3195 Pine Hall Rd
Customer Name(s):Chuck Campbell, T. Hunsucker, Ed Sullivan
Mailcode: Belews Steam Station
Belews Creek, NC 28012
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Peggy Kendall
Page 1 of 27
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016009103 BELEWS 25-Apr-16 10:55 AM LDC MW-1D
2016009105 BELEWS 25-Apr-16 11:30 AM LDC MW-3
2016009106 BELEWS 25-Apr-16 9:35 AM LDC MW-4
2016009107 BELEWS 25-Apr-16 2:55 PM PSP, HET MW-5
2016009108 BELEWS 25-Apr-16 12:20 PM LDC MW-6
2016009109 BELEWS 25-Apr-16 9:35 AM PSP, HET MW-7
2016009110 BELEWS 25-Apr-16 11:00 AM HET MW2-7
2016009111 BELEWS 25-Apr-16 1:55 PM LDC MW2-9
2016009112 BELEWS 25-Apr-16 11:50 AM HET OB-4
2016009113 BELEWS 25-Apr-16 2:55 PM HET OB-5
2016009114 BELEWS 25-Apr-16 12:50 PM HET OB-9
2016009115 BELEWS 25-Apr-16 10:10 AM PSP, HET SW-1A
2016009116 BELEWS 25-Apr-16 1:15 PM PSP, HET SW-2
2016009117 BELEWS 25-Apr-16 3:25 PM PSP FIELD BLANK
14 Total Samples
Page 2 of 27
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Peggy Kendall Date:5/12/2016
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040004
2016009103
Collection Date:25-Apr-16 10:55 AM
Site:MW-1D
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)39 mg/L
(CaCO3)
SM 2320B 04/29/2016 10:24 CJELLIO201
INORGANIC IONS BY IC
Chloride 8.4 mg/L EPA 9056A 04/26/2016 16:48 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/26/2016 16:48 BGN90340.1 1
Nitrate 8.3 mg/L EPA 9056A 04/26/2016 16:48 BGN90340.1 1
Nitrate as N 1.9 mg-N/L EPA 9056A 04/26/2016 16:48 BGN90340.023 1
Sulfate 0.96 mg/L EPA 9056A 04/26/2016 16:48 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/28/2016 13:41 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L SW 6010D 05/03/2016 09:31 JJMACKE0.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 05/03/2016 09:31 JJMACKE0.005 1
Boron (B)0.069 mg/L SW 6010D 05/03/2016 09:31 JJMACKE0.05 1
Calcium (Ca)5.63 mg/L SW 6010D 05/03/2016 09:31 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 05/03/2016 09:31 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/03/2016 09:31 JJMACKE0.005 1
Iron (Fe)< 0.01 mg/L SW 6010D 05/03/2016 09:31 JJMACKE0.01 1
Magnesium (Mg)5.20 mg/L SW 6010D 05/03/2016 09:31 JJMACKE0.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 05/03/2016 09:31 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 05/03/2016 09:31 JJMACKE0.005 1
Potassium (K)1.87 mg/L SW 6010D 05/03/2016 09:31 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/03/2016 09:31 JJMACKE0.005 1
Sodium (Na)9.82 mg/L SW 6010D 05/03/2016 09:31 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 05/03/2016 09:31 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 05/09/2016 18:38 MHALL311
Arsenic (As)< 1 ug/L SW 6020B 05/09/2016 18:38 MHALL311
Cadmium (Cd)< 1 ug/L SW 6020B 05/09/2016 18:38 MHALL311
Cobalt (Co)< 1 ug/L SW 6020B 05/09/2016 18:38 MHALL311
Lead (Pb)< 1 ug/L SW 6020B 05/09/2016 18:38 MHALL311
Selenium (Se)< 1 ug/L SW 6020B 05/09/2016 18:38 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 05/09/2016 18:38 MHALL30.2 1
Vanadium (V)< 1 ug/L SW 6020B 05/09/2016 18:38 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 84 mg/L SM2540C 04/26/2016 14:46 PARMSTR251
Page 4 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040004
2016009105
Collection Date:25-Apr-16 11:30 AM
Site:MW-3
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)6.2 mg/L
(CaCO3)
SM 2320B 04/29/2016 12:59 CJELLIO51
INORGANIC IONS BY IC
Chloride 10 mg/L EPA 9056A 04/27/2016 08:46 BGN90340.2 2
Fluoride < 0.1 mg/L EPA 9056A 04/27/2016 08:46 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 04/27/2016 08:46 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 04/27/2016 08:46 BGN90340.023 1
Sulfate 0.15 mg/L EPA 9056A 04/27/2016 08:46 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/28/2016 13:43 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.080 mg/L SW 6010D 05/03/2016 09:42 JJMACKE0.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 05/03/2016 09:42 JJMACKE0.005 1
Boron (B)0.058 mg/L SW 6010D 05/03/2016 09:42 JJMACKE0.05 1
Calcium (Ca)2.87 mg/L SW 6010D 05/03/2016 09:42 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 05/03/2016 09:42 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/03/2016 09:42 JJMACKE0.005 1
Iron (Fe)0.854 mg/L SW 6010D 05/03/2016 09:42 JJMACKE0.01 1
Magnesium (Mg)1.08 mg/L SW 6010D 05/03/2016 09:42 JJMACKE0.005 1
Manganese (Mn)0.016 mg/L SW 6010D 05/03/2016 09:42 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 05/03/2016 09:42 JJMACKE0.005 1
Potassium (K)2.93 mg/L SW 6010D 05/03/2016 09:42 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/03/2016 09:42 JJMACKE0.005 1
Sodium (Na)3.13 mg/L SW 6010D 05/03/2016 09:42 JJMACKE0.05 1
Zinc (Zn)0.005 mg/L SW 6010D 05/03/2016 09:42 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 05/09/2016 18:44 MHALL311
Arsenic (As)< 1 ug/L SW 6020B 05/09/2016 18:44 MHALL311
Cadmium (Cd)< 1 ug/L SW 6020B 05/09/2016 18:44 MHALL311
Cobalt (Co)< 1 ug/L SW 6020B 05/09/2016 18:44 MHALL311
Lead (Pb)< 1 ug/L SW 6020B 05/09/2016 18:44 MHALL311
Selenium (Se)< 1 ug/L SW 6020B 05/09/2016 18:44 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 05/09/2016 18:44 MHALL30.2 1
Vanadium (V)1.93 ug/L SW 6020B 05/09/2016 18:44 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 46 mg/L SM2540C 04/26/2016 14:46 PARMSTR251
Page 5 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040004
2016009106
Collection Date:25-Apr-16 9:35 AM
Site:MW-4
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)33 mg/L
(CaCO3)
SM 2320B 04/29/2016 10:24 CJELLIO201
INORGANIC IONS BY IC
Chloride 2.6 mg/L EPA 9056A 04/26/2016 18:55 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/26/2016 18:55 BGN90340.1 1
Nitrate 4.2 mg/L EPA 9056A 04/26/2016 18:55 BGN90340.1 1
Nitrate as N 0.95 mg-N/L EPA 9056A 04/26/2016 18:55 BGN90340.023 1
Sulfate 75 mg/L EPA 9056A 04/26/2016 18:55 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/28/2016 13:46 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L SW 6010D 05/03/2016 09:46 JJMACKE0.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 05/03/2016 09:46 JJMACKE0.005 1
Boron (B)0.703 mg/L SW 6010D 05/03/2016 09:46 JJMACKE0.05 1
Calcium (Ca)19.8 mg/L SW 6010D 05/03/2016 09:46 JJMACKE0.01 1
Chromium (Cr)0.014 mg/L SW 6010D 05/03/2016 09:46 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/03/2016 09:46 JJMACKE0.005 1
Iron (Fe)0.455 mg/L SW 6010D 05/03/2016 09:46 JJMACKE0.01 1
Magnesium (Mg)11.2 mg/L SW 6010D 05/03/2016 09:46 JJMACKE0.005 1
Manganese (Mn)0.007 mg/L SW 6010D 05/03/2016 09:46 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 05/03/2016 09:46 JJMACKE0.005 1
Potassium (K)1.11 mg/L SW 6010D 05/03/2016 09:46 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/03/2016 09:46 JJMACKE0.005 1
Sodium (Na)7.73 mg/L SW 6010D 05/03/2016 09:46 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 05/03/2016 09:46 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 05/09/2016 18:15 MHALL311
Arsenic (As)< 1 ug/L SW 6020B 05/09/2016 18:15 MHALL311
Cadmium (Cd)< 1 ug/L SW 6020B 05/09/2016 18:15 MHALL311
Cobalt (Co)< 1 ug/L SW 6020B 05/09/2016 18:15 MHALL311
Lead (Pb)< 1 ug/L SW 6020B 05/09/2016 18:15 MHALL311
Selenium (Se)15.4 ug/L SW 6020B 05/09/2016 18:15 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 05/09/2016 18:15 MHALL30.2 1
Vanadium (V)2.81 ug/L SW 6020B 05/09/2016 18:15 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 180 mg/L SM2540C 04/26/2016 14:46 PARMSTR251
Page 6 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040004
2016009107
Collection Date:25-Apr-16 2:55 PM
Site:MW-5
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)11 mg/L
(CaCO3)
SM 2320B 04/29/2016 12:59 CJELLIO51
INORGANIC IONS BY IC
Chloride 2.0 mg/L EPA 9056A 04/26/2016 17:20 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/26/2016 17:20 BGN90340.1 1
Nitrate 2.8 mg/L EPA 9056A 04/26/2016 17:20 BGN90340.1 1
Nitrate as N 0.63 mg-N/L EPA 9056A 04/26/2016 17:20 BGN90340.023 1
Sulfate 0.17 mg/L EPA 9056A 04/26/2016 17:20 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/28/2016 13:48 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.035 mg/L SW 6010D 05/03/2016 09:50 JJMACKE0.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 05/03/2016 09:50 JJMACKE0.005 1
Boron (B)0.071 mg/L SW 6010D 05/03/2016 09:50 JJMACKE0.05 1
Calcium (Ca)1.61 mg/L SW 6010D 05/03/2016 09:50 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 05/03/2016 09:50 JJMACKE0.005 1
Copper (Cu)0.105 mg/L SW 6010D 05/03/2016 09:50 JJMACKE0.005 1
Iron (Fe)0.455 mg/L SW 6010D 05/03/2016 09:50 JJMACKE0.01 1
Magnesium (Mg)0.630 mg/L SW 6010D 05/03/2016 09:50 JJMACKE0.005 1
Manganese (Mn)0.013 mg/L SW 6010D 05/03/2016 09:50 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 05/03/2016 09:50 JJMACKE0.005 1
Potassium (K)2.56 mg/L SW 6010D 05/03/2016 09:50 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/03/2016 09:50 JJMACKE0.005 1
Sodium (Na)3.78 mg/L SW 6010D 05/03/2016 09:50 JJMACKE0.05 1
Zinc (Zn)0.062 mg/L SW 6010D 05/03/2016 09:50 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 05/09/2016 18:49 MHALL311
Arsenic (As)< 1 ug/L SW 6020B 05/09/2016 18:49 MHALL311
Cadmium (Cd)< 1 ug/L SW 6020B 05/09/2016 18:49 MHALL311
Cobalt (Co)< 1 ug/L SW 6020B 05/09/2016 18:49 MHALL311
Lead (Pb)8.57 ug/L SW 6020B 05/09/2016 18:49 MHALL311
Selenium (Se)< 1 ug/L SW 6020B 05/09/2016 18:49 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 05/09/2016 18:49 MHALL30.2 1
Vanadium (V)< 1 ug/L SW 6020B 05/09/2016 18:49 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 37 mg/L SM2540C 04/26/2016 14:46 PARMSTR251
Page 7 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040004
2016009108
Collection Date:25-Apr-16 12:20 PM
Site:MW-6
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)12 mg/L
(CaCO3)
SM 2320B 04/29/2016 12:59 CJELLIO51
INORGANIC IONS BY IC
Chloride 7.7 mg/L EPA 9056A 04/26/2016 17:36 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/26/2016 17:36 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 04/26/2016 17:36 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 04/26/2016 17:36 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 04/26/2016 17:36 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/28/2016 13:51 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.062 mg/L SW 6010D 05/03/2016 09:54 JJMACKE0.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 05/03/2016 09:54 JJMACKE0.005 1
Boron (B)0.072 mg/L SW 6010D 05/03/2016 09:54 JJMACKE0.05 1
Calcium (Ca)1.91 mg/L SW 6010D 05/03/2016 09:54 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 05/03/2016 09:54 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/03/2016 09:54 JJMACKE0.005 1
Iron (Fe)0.037 mg/L SW 6010D 05/03/2016 09:54 JJMACKE0.01 1
Magnesium (Mg)0.761 mg/L SW 6010D 05/03/2016 09:54 JJMACKE0.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 05/03/2016 09:54 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 05/03/2016 09:54 JJMACKE0.005 1
Potassium (K)0.924 mg/L SW 6010D 05/03/2016 09:54 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/03/2016 09:54 JJMACKE0.005 1
Sodium (Na)7.19 mg/L SW 6010D 05/03/2016 09:54 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 05/03/2016 09:54 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 05/09/2016 18:55 MHALL311
Arsenic (As)< 1 ug/L SW 6020B 05/09/2016 18:55 MHALL311
Cadmium (Cd)< 1 ug/L SW 6020B 05/09/2016 18:55 MHALL311
Cobalt (Co)< 1 ug/L SW 6020B 05/09/2016 18:55 MHALL311
Lead (Pb)< 1 ug/L SW 6020B 05/09/2016 18:55 MHALL311
Selenium (Se)< 1 ug/L SW 6020B 05/09/2016 18:55 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 05/09/2016 18:55 MHALL30.2 1
Vanadium (V)< 1 ug/L SW 6020B 05/09/2016 18:55 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 57 mg/L SM2540C 04/26/2016 14:46 PARMSTR251
Page 8 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040004
2016009109
Collection Date:25-Apr-16 9:35 AM
Site:MW-7
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)8.5 mg/L
(CaCO3)
SM 2320B 04/29/2016 12:59 CJELLIO51
INORGANIC IONS BY IC
Chloride 8.5 mg/L EPA 9056A 04/26/2016 20:15 BGN90340.2 2
Fluoride < 0.2 mg/L EPA 9056A 04/26/2016 20:15 BGN90340.2 2
Nitrate 16 mg/L EPA 9056A 04/26/2016 20:15 BGN90340.2 2
Nitrate as N 3.7 mg-N/L EPA 9056A 04/26/2016 20:15 BGN90340.023 1
Sulfate 150 mg/L EPA 9056A 04/26/2016 20:15 BGN90342.5 25
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/28/2016 13:53 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.051 mg/L SW 6010D 05/03/2016 09:58 JJMACKE0.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 05/03/2016 09:58 JJMACKE0.005 1
Boron (B)2.40 mg/L SW 6010D 05/03/2016 09:58 JJMACKE0.05 1
Calcium (Ca)27.9 mg/L SW 6010D 05/03/2016 09:58 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 05/03/2016 09:58 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/03/2016 09:58 JJMACKE0.005 1
Iron (Fe)1.99 mg/L SW 6010D 05/03/2016 09:58 JJMACKE0.01 1
Magnesium (Mg)14.1 mg/L SW 6010D 05/03/2016 09:58 JJMACKE0.005 1
Manganese (Mn)0.051 mg/L SW 6010D 05/03/2016 09:58 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 05/03/2016 09:58 JJMACKE0.005 1
Potassium (K)2.62 mg/L SW 6010D 05/03/2016 09:58 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/03/2016 09:58 JJMACKE0.005 1
Sodium (Na)16.4 mg/L SW 6010D 05/03/2016 09:58 JJMACKE0.05 1
Zinc (Zn)0.018 mg/L SW 6010D 05/03/2016 09:58 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 05/09/2016 19:01 MHALL311
Arsenic (As)< 1 ug/L SW 6020B 05/09/2016 19:01 MHALL311
Cadmium (Cd)< 1 ug/L SW 6020B 05/09/2016 19:01 MHALL311
Cobalt (Co)< 1 ug/L SW 6020B 05/09/2016 19:01 MHALL311
Lead (Pb)< 1 ug/L SW 6020B 05/09/2016 19:01 MHALL311
Selenium (Se)23.5 ug/L SW 6020B 05/09/2016 19:01 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 05/09/2016 19:01 MHALL30.2 1
Vanadium (V)1.88 ug/L SW 6020B 05/09/2016 19:01 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 290 mg/L SM2540C 04/26/2016 14:46 PARMSTR251
Page 9 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040004
2016009110
Collection Date:25-Apr-16 11:00 AM
Site:MW2-7
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)22 mg/L
(CaCO3)
SM 2320B 04/29/2016 10:24 CJELLIO201
INORGANIC IONS BY IC
Chloride 14 mg/L EPA 9056A 04/26/2016 19:27 BGN9034220
Fluoride < 2 mg/L EPA 9056A 04/26/2016 19:27 BGN9034220
Nitrate 160 mg/L EPA 9056A 04/26/2016 19:27 BGN9034220
Nitrate as N 37 mg-N/L EPA 9056A 04/26/2016 19:27 BGN90340.023 1
Sulfate 1300 mg/L EPA 9056A 04/26/2016 19:27 BGN903420200
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)0.17 ug/L EPA 7470A 04/28/2016 13:55 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.033 mg/L SW 6010D 05/03/2016 10:01 JJMACKE0.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 05/03/2016 10:01 JJMACKE0.005 1
Boron (B)20.9 mg/L SW 6010D 05/03/2016 10:01 JJMACKE0.5 10
Calcium (Ca)240 mg/L SW 6010D 05/03/2016 10:01 JJMACKE0.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 05/03/2016 10:01 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/03/2016 10:01 JJMACKE0.005 1
Iron (Fe)0.131 mg/L SW 6010D 05/03/2016 10:01 JJMACKE0.01 1
Magnesium (Mg)113 mg/L SW 6010D 05/03/2016 10:01 JJMACKE0.05 10
Manganese (Mn)0.515 mg/L SW 6010D 05/03/2016 10:01 JJMACKE0.005 1
Nickel (Ni)0.014 mg/L SW 6010D 05/03/2016 10:01 JJMACKE0.005 1
Potassium (K)4.04 mg/L SW 6010D 05/03/2016 10:01 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/03/2016 10:01 JJMACKE0.005 1
Sodium (Na)70.3 mg/L SW 6010D 05/03/2016 10:01 JJMACKE0.05 1
Zinc (Zn)0.028 mg/L SW 6010D 05/03/2016 10:01 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 05/09/2016 19:07 MHALL311
Arsenic (As)< 1 ug/L SW 6020B 05/09/2016 19:07 MHALL311
Cadmium (Cd)1.14 ug/L SW 6020B 05/09/2016 19:07 MHALL311
Cobalt (Co)< 1 ug/L SW 6020B 05/09/2016 19:07 MHALL311
Lead (Pb)< 1 ug/L SW 6020B 05/09/2016 19:07 MHALL311
Selenium (Se)156 ug/L SW 6020B 05/09/2016 19:07 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 05/09/2016 19:07 MHALL30.2 1
Vanadium (V)< 1 ug/L SW 6020B 05/09/2016 19:07 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 1900 mg/L SM2540C 04/26/2016 14:46 PARMSTR251
Page 10 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040004
2016009111
Collection Date:25-Apr-16 1:55 PM
Site:MW2-9
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)110 mg/L
(CaCO3)
SM 2320B 04/29/2016 10:24 CJELLIO201
INORGANIC IONS BY IC
Chloride 4.2 mg/L EPA 9056A 04/26/2016 19:43 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/26/2016 19:43 BGN90340.1 1
Nitrate 0.26 mg/L EPA 9056A 04/26/2016 19:43 BGN90340.1 1
Nitrate as N 0.06 mg-N/L EPA 9056A 04/26/2016 19:43 BGN90340.023 1
Sulfate 65 mg/L EPA 9056A 04/26/2016 19:43 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/28/2016 13:58 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.068 mg/L SW 6010D 05/03/2016 10:05 JJMACKE0.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 05/03/2016 10:05 JJMACKE0.005 1
Boron (B)0.369 mg/L SW 6010D 05/03/2016 10:05 JJMACKE0.05 1
Calcium (Ca)26.0 mg/L SW 6010D 05/03/2016 10:05 JJMACKE0.01 1
Chromium (Cr)0.006 mg/L SW 6010D 05/03/2016 10:05 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/03/2016 10:05 JJMACKE0.005 1
Iron (Fe)1.91 mg/L SW 6010D 05/03/2016 10:05 JJMACKE0.01 1
Magnesium (Mg)10.8 mg/L SW 6010D 05/03/2016 10:05 JJMACKE0.005 1
Manganese (Mn)0.653 mg/L SW 6010D 05/03/2016 10:05 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 05/03/2016 10:05 JJMACKE0.005 1
Potassium (K)4.98 mg/L SW 6010D 05/03/2016 10:05 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/03/2016 10:05 JJMACKE0.005 1
Sodium (Na)21.5 mg/L SW 6010D 05/03/2016 10:05 JJMACKE0.05 1
Zinc (Zn)0.008 mg/L SW 6010D 05/03/2016 10:05 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 05/09/2016 19:30 MHALL311
Arsenic (As)< 1 ug/L SW 6020B 05/09/2016 19:30 MHALL311
Cadmium (Cd)< 1 ug/L SW 6020B 05/09/2016 19:30 MHALL311
Cobalt (Co)1.70 ug/L SW 6020B 05/09/2016 19:30 MHALL311
Lead (Pb)< 1 ug/L SW 6020B 05/09/2016 19:30 MHALL311
Selenium (Se)< 1 ug/L SW 6020B 05/09/2016 19:30 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 05/09/2016 19:30 MHALL30.2 1
Vanadium (V)2.82 ug/L SW 6020B 05/09/2016 19:30 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 210 mg/L SM2540C 04/26/2016 14:46 PARMSTR251
Page 11 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040004
2016009112
Collection Date:25-Apr-16 11:50 AM
Site:OB-4
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)310 mg/L
(CaCO3)
SM 2320B 04/29/2016 10:24 CJELLIO201
INORGANIC IONS BY IC
Chloride 6.1 mg/L EPA 9056A 04/26/2016 19:59 BGN9034110
Fluoride < 1 mg/L EPA 9056A 04/26/2016 19:59 BGN9034110
Nitrate 13 mg/L EPA 9056A 04/26/2016 19:59 BGN9034110
Nitrate as N 3.0 mg-N/L EPA 9056A 04/26/2016 19:59 BGN90340.023 1
Sulfate 1500 mg/L EPA 9056A 04/26/2016 19:59 BGN903450500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/28/2016 14:00 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.036 mg/L SW 6010D 05/03/2016 10:09 JJMACKE0.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 05/03/2016 10:09 JJMACKE0.005 1
Boron (B)15.4 mg/L SW 6010D 05/03/2016 10:09 JJMACKE0.05 1
Calcium (Ca)598 mg/L SW 6010D 05/03/2016 10:09 JJMACKE0.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 05/03/2016 10:09 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/03/2016 10:09 JJMACKE0.005 1
Iron (Fe)0.165 mg/L SW 6010D 05/03/2016 10:09 JJMACKE0.01 1
Magnesium (Mg)46.1 mg/L SW 6010D 05/03/2016 10:09 JJMACKE0.05 10
Manganese (Mn)0.116 mg/L SW 6010D 05/03/2016 10:09 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 05/03/2016 10:09 JJMACKE0.005 1
Potassium (K)42.3 mg/L SW 6010D 05/03/2016 10:09 JJMACKE110
Silver (Ag)< 0.005 mg/L SW 6010D 05/03/2016 10:09 JJMACKE0.005 1
Sodium (Na)9.38 mg/L SW 6010D 05/03/2016 10:09 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 05/03/2016 10:09 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)30.3 ug/L SW 6020B 05/09/2016 19:41 MHALL311
Arsenic (As)35.5 ug/L SW 6020B 05/09/2016 19:41 MHALL311
Cadmium (Cd)< 1 ug/L SW 6020B 05/09/2016 19:41 MHALL311
Cobalt (Co)1.50 ug/L SW 6020B 05/09/2016 19:41 MHALL311
Lead (Pb)< 1 ug/L SW 6020B 05/09/2016 19:41 MHALL311
Selenium (Se)135 ug/L SW 6020B 05/09/2016 19:41 MHALL311
Thallium (Tl) Low Level 6.98 ug/L SW 6020B 05/09/2016 19:41 MHALL30.2 1
Vanadium (V)213 ug/L SW 6020B 05/09/2016 19:41 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 2600 mg/L SM2540C 04/26/2016 14:46 PARMSTR501
Page 12 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040004
2016009113
Collection Date:25-Apr-16 2:55 PM
Site:OB-5
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 04/29/2016 12:59 CJELLIO51
INORGANIC IONS BY IC
Chloride 3.9 mg/L EPA 9056A 04/26/2016 21:19 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/26/2016 21:19 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 04/26/2016 21:19 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 04/26/2016 21:19 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 04/26/2016 21:19 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/28/2016 14:12 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.107 mg/L SW 6010D 05/03/2016 10:13 JJMACKE0.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 05/03/2016 10:13 JJMACKE0.005 1
Boron (B)0.062 mg/L SW 6010D 05/03/2016 10:13 JJMACKE0.05 1
Calcium (Ca)0.918 mg/L SW 6010D 05/03/2016 10:13 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 05/03/2016 10:13 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/03/2016 10:13 JJMACKE0.005 1
Iron (Fe)0.100 mg/L SW 6010D 05/03/2016 10:13 JJMACKE0.01 1
Magnesium (Mg)0.482 mg/L SW 6010D 05/03/2016 10:13 JJMACKE0.005 1
Manganese (Mn)0.022 mg/L SW 6010D 05/03/2016 10:13 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 05/03/2016 10:13 JJMACKE0.005 1
Potassium (K)2.50 mg/L SW 6010D 05/03/2016 10:13 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/03/2016 10:13 JJMACKE0.005 1
Sodium (Na)1.47 mg/L SW 6010D 05/03/2016 10:13 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 05/03/2016 10:13 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 05/09/2016 19:47 MHALL311
Arsenic (As)< 1 ug/L SW 6020B 05/09/2016 19:47 MHALL311
Cadmium (Cd)< 1 ug/L SW 6020B 05/09/2016 19:47 MHALL311
Cobalt (Co)< 1 ug/L SW 6020B 05/09/2016 19:47 MHALL311
Lead (Pb)< 1 ug/L SW 6020B 05/09/2016 19:47 MHALL311
Selenium (Se)< 1 ug/L SW 6020B 05/09/2016 19:47 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 05/09/2016 19:47 MHALL30.2 1
Vanadium (V)< 1 ug/L SW 6020B 05/09/2016 19:47 MHALL311
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 04/26/2016 14:46 PARMSTR251
Page 13 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040004
2016009114
Collection Date:25-Apr-16 12:50 PM
Site:OB-9
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)8.4 mg/L
(CaCO3)
SM 2320B 04/29/2016 12:59 CJELLIO51
INORGANIC IONS BY IC
Chloride 10 mg/L EPA 9056A 04/26/2016 23:10 BGN9034110
Fluoride < 1 mg/L EPA 9056A 04/26/2016 23:10 BGN9034110
Nitrate 20 mg/L EPA 9056A 04/26/2016 23:10 BGN9034110
Nitrate as N 4.5 mg-N/L EPA 9056A 04/26/2016 23:10 BGN90340.023 1
Sulfate 940 mg/L EPA 9056A 04/26/2016 23:10 BGN903420200
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)0.07 ug/L EPA 7470A 04/28/2016 14:20 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.013 mg/L SW 6010D 05/03/2016 10:24 JJMACKE0.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 05/03/2016 10:24 JJMACKE0.005 1
Boron (B)23.4 mg/L SW 6010D 05/03/2016 10:24 JJMACKE0.5 10
Calcium (Ca)176 mg/L SW 6010D 05/03/2016 10:24 JJMACKE0.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 05/03/2016 10:24 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/03/2016 10:24 JJMACKE0.005 1
Iron (Fe)< 0.01 mg/L SW 6010D 05/03/2016 10:24 JJMACKE0.01 1
Magnesium (Mg)78.6 mg/L SW 6010D 05/03/2016 10:24 JJMACKE0.05 10
Manganese (Mn)1.60 mg/L SW 6010D 05/03/2016 10:24 JJMACKE0.005 1
Nickel (Ni)0.007 mg/L SW 6010D 05/03/2016 10:24 JJMACKE0.005 1
Potassium (K)7.17 mg/L SW 6010D 05/03/2016 10:24 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/03/2016 10:24 JJMACKE0.005 1
Sodium (Na)90.5 mg/L SW 6010D 05/03/2016 10:24 JJMACKE0.05 1
Zinc (Zn)0.038 mg/L SW 6010D 05/03/2016 10:24 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 05/09/2016 19:53 MHALL311
Arsenic (As)< 1 ug/L SW 6020B 05/09/2016 19:53 MHALL311
Cadmium (Cd)2.27 ug/L SW 6020B 05/09/2016 19:53 MHALL311
Cobalt (Co)< 1 ug/L SW 6020B 05/09/2016 19:53 MHALL311
Lead (Pb)< 1 ug/L SW 6020B 05/09/2016 19:53 MHALL311
Selenium (Se)262 ug/L SW 6020B 05/09/2016 19:53 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 05/09/2016 19:53 MHALL30.2 1
Vanadium (V)< 1 ug/L SW 6020B 05/09/2016 19:53 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 1400 mg/L SM2540C 04/26/2016 14:46 PARMSTR251
Page 14 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040004
2016009115
Collection Date:25-Apr-16 10:10 AM
Site:SW-1A
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)37 mg/L
(CaCO3)
SM 2320B 04/29/2016 10:24 CJELLIO201
INORGANIC IONS BY IC
Chloride 11 mg/L EPA 9056A 04/26/2016 23:26 BGN9034110
Fluoride < 1 mg/L EPA 9056A 04/26/2016 23:26 BGN9034110
Nitrate 63 mg/L EPA 9056A 04/26/2016 23:26 BGN9034110
Nitrate as N 14 mg-N/L EPA 9056A 04/26/2016 23:26 BGN90340.023 1
Sulfate 640 mg/L EPA 9056A 04/26/2016 23:26 BGN903410100
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/28/2016 14:22 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.050 mg/L SW 6010D 05/03/2016 10:28 JJMACKE0.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 05/03/2016 10:28 JJMACKE0.005 1
Boron (B)10.8 mg/L SW 6010D 05/03/2016 10:28 JJMACKE0.05 1
Calcium (Ca)143 mg/L SW 6010D 05/03/2016 10:28 JJMACKE0.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 05/03/2016 10:28 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/03/2016 10:28 JJMACKE0.005 1
Iron (Fe)0.068 mg/L SW 6010D 05/03/2016 10:28 JJMACKE0.01 1
Magnesium (Mg)65.7 mg/L SW 6010D 05/03/2016 10:28 JJMACKE0.05 10
Manganese (Mn)0.237 mg/L SW 6010D 05/03/2016 10:28 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 05/03/2016 10:28 JJMACKE0.005 1
Potassium (K)4.32 mg/L SW 6010D 05/03/2016 10:28 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/03/2016 10:28 JJMACKE0.005 1
Sodium (Na)40.1 mg/L SW 6010D 05/03/2016 10:28 JJMACKE0.05 1
Zinc (Zn)0.006 mg/L SW 6010D 05/03/2016 10:28 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 05/09/2016 19:59 MHALL311
Arsenic (As)< 1 ug/L SW 6020B 05/09/2016 19:59 MHALL311
Cadmium (Cd)< 1 ug/L SW 6020B 05/09/2016 19:59 MHALL311
Cobalt (Co)< 1 ug/L SW 6020B 05/09/2016 19:59 MHALL311
Lead (Pb)< 1 ug/L SW 6020B 05/09/2016 19:59 MHALL311
Selenium (Se)73.8 ug/L SW 6020B 05/09/2016 19:59 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 05/09/2016 19:59 MHALL30.2 1
Vanadium (V)< 1 ug/L SW 6020B 05/09/2016 19:59 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 1000 mg/L SM2540C 04/26/2016 14:46 PARMSTR251
Page 15 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040004
2016009116
Collection Date:25-Apr-16 1:15 PM
Site:SW-2
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)11 mg/L
(CaCO3)
SM 2320B 04/29/2016 12:59 CJELLIO51
INORGANIC IONS BY IC
Chloride 5.2 mg/L EPA 9056A 04/26/2016 22:54 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/26/2016 22:54 BGN90340.1 1
Nitrate 1.9 mg/L EPA 9056A 04/26/2016 22:54 BGN90340.1 1
Nitrate as N 0.42 mg-N/L EPA 9056A 04/26/2016 22:54 BGN90340.023 1
Sulfate 42 mg/L EPA 9056A 04/26/2016 22:54 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/28/2016 14:24 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.032 mg/L SW 6010D 05/03/2016 10:32 JJMACKE0.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 05/03/2016 10:32 JJMACKE0.005 1
Boron (B)1.20 mg/L SW 6010D 05/03/2016 10:32 JJMACKE0.05 1
Calcium (Ca)6.55 mg/L SW 6010D 05/03/2016 10:32 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 05/03/2016 10:32 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/03/2016 10:32 JJMACKE0.005 1
Iron (Fe)0.842 mg/L SW 6010D 05/03/2016 10:32 JJMACKE0.01 1
Magnesium (Mg)5.01 mg/L SW 6010D 05/03/2016 10:32 JJMACKE0.005 1
Manganese (Mn)0.029 mg/L SW 6010D 05/03/2016 10:32 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 05/03/2016 10:32 JJMACKE0.005 1
Potassium (K)1.82 mg/L SW 6010D 05/03/2016 10:32 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/03/2016 10:32 JJMACKE0.005 1
Sodium (Na)10.7 mg/L SW 6010D 05/03/2016 10:32 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 05/03/2016 10:32 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 05/09/2016 20:04 MHALL311
Arsenic (As)< 1 ug/L SW 6020B 05/09/2016 20:04 MHALL311
Cadmium (Cd)< 1 ug/L SW 6020B 05/09/2016 20:04 MHALL311
Cobalt (Co)< 1 ug/L SW 6020B 05/09/2016 20:04 MHALL311
Lead (Pb)< 1 ug/L SW 6020B 05/09/2016 20:04 MHALL311
Selenium (Se)6.70 ug/L SW 6020B 05/09/2016 20:04 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 05/09/2016 20:04 MHALL30.2 1
Vanadium (V)< 1 ug/L SW 6020B 05/09/2016 20:04 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 110 mg/L SM2540C 04/26/2016 14:46 PARMSTR251
Page 16 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040004
2016009117
Collection Date:25-Apr-16 3:25 PM
Site:FIELD BLANK
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 04/29/2016 12:59 CJELLIO51
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 9056A 04/26/2016 15:45 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/26/2016 15:45 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 04/26/2016 15:45 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 04/26/2016 15:45 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 04/26/2016 15:45 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/28/2016 14:27 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L SW 6010D 05/03/2016 10:36 JJMACKE0.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 05/03/2016 10:36 JJMACKE0.005 1
Boron (B)0.065 mg/L SW 6010D 05/03/2016 10:36 JJMACKE0.05 1
Calcium (Ca)< 0.01 mg/L SW 6010D 05/03/2016 10:36 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 05/03/2016 10:36 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/03/2016 10:36 JJMACKE0.005 1
Iron (Fe)< 0.01 mg/L SW 6010D 05/03/2016 10:36 JJMACKE0.01 1
Magnesium (Mg)< 0.005 mg/L SW 6010D 05/03/2016 10:36 JJMACKE0.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 05/03/2016 10:36 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 05/03/2016 10:36 JJMACKE0.005 1
Potassium (K)< 0.1 mg/L SW 6010D 05/03/2016 10:36 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/03/2016 10:36 JJMACKE0.005 1
Sodium (Na)0.077 mg/L SW 6010D 05/03/2016 10:36 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 05/03/2016 10:36 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 05/09/2016 20:10 MHALL311
Arsenic (As)< 1 ug/L SW 6020B 05/09/2016 20:10 MHALL311
Cadmium (Cd)< 1 ug/L SW 6020B 05/09/2016 20:10 MHALL311
Cobalt (Co)< 1 ug/L SW 6020B 05/09/2016 20:10 MHALL311
Lead (Pb)< 1 ug/L SW 6020B 05/09/2016 20:10 MHALL311
Selenium (Se)< 1 ug/L SW 6020B 05/09/2016 20:10 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 05/09/2016 20:10 MHALL30.2 1
Vanadium (V)< 1 ug/L SW 6020B 05/09/2016 20:10 MHALL311
Page 17 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040004
Q16040582 ALK_FIX4.5 ALKALINITY (FIXED END POINT 4.5)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16040004 -- 2016009103
Alkalinity (mg/L CaCO3)0.463mg/L
(CaCO3)
-139.4
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3)44.3 96.2mg/L
(CaCO3)
-12080142.6
Page 18 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040004
Q16050004 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16040004 -- 2016009105
Alkalinity (mg/L CaCO3)2.79mg/L
(CaCO3)
-16.33
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3)11.08 88.2mg/L
(CaCO3)
-1208019.77
Page 19 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040004
Q16040476 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0214 mg/L -10.0214 0.1 < 1/2 RDL
Fluoride 0.0366 mg/L -10.0366 0.1 < 1/2 RDL
Nitrate 0.0117 mg/L -10.0117 0.1 < 1/2 RDL
Sulfate 0.0011 mg/L -10.0011 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 5.12 5 99.3mg/L -1208015.12
Fluoride 4.92 5 98mg/L -1208014.92
Nitrate 5.12 5 98.2mg/L -1208015.12
Sulfate 8.3 5 91.2mg/L -1208018.3
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 5.13 5 99.5 0.219mg/L -1208015.13
Fluoride 4.94 5 98.2 0.232mg/L -1208014.94
Nitrate 5.13 5 98.3 0.144mg/L -1208015.13
Sulfate 8.31 5 91.3 0.14mg/L -1208018.31
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 8.94 5 100mg/L -1208018.94
Fluoride 5 5 99.5mg/L -1208015
Nitrate 4.99 5 99.7mg/L -1208014.99
Sulfate 5.04 5 99.3mg/L -1208015.04
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 8.8 5 97.5 2.77mg/L -1208018.8
Fluoride 4.99 5 99.3 0.229mg/L -1208014.99
Nitrate 4.9 5 97.9 1.88mg/L -1208014.9
Sulfate 4.99 5 98.4 0.856mg/L -1208014.99
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.02 5 100mg/L -1208015.02
Fluoride 5.07 5 101mg/L -1208015.07
Nitrate 5.03 5 101mg/L -1208015.03
Sulfate 4.99 5 99.8mg/L -1208014.99
Page 20 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040004
Q16040558 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) -0.006 ug/L -1-0.006 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) -0.007 ug/L -1-0.007 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Mercury (Hg) -0.002 ug/L -1-0.002 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 0.97 100 98.3ug/L -1257510097
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.961 100 97.3 0.951ug/L -10096.1
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.93 2 96.3ug/L -1158511.93
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.88 2 94.2ug/L -1158511.88
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16040004 -- 2016009113
Mercury (Hg) 0.948 1 95.8ug/L -1257510.948
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16040004 -- 2016009113
Mercury (Hg) 0.963 1 97.3 1.55ug/L -1257510.963
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16040644 -- 2016011626
Mercury (Hg) 0.859 1 77.7ug/L -1257510.859
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16040644 -- 2016011626
Mercury (Hg) 0.856 1 77.4 0.387ug/L -1257510.856
Page 21 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040004
Q16050013 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) 0.000114 mg/L -10.000114 0.005 < 1/2 RDL
Beryllium (Be) -0.000029 mg/L -1-0.000029 0.005 < 1/2 RDL
Boron (B) 0.000803 mg/L -10.000803 0.05 < 1/2 RDL
Calcium (Ca) 0.00456 mg/L -10.00456 0.01 < 1/2 RDL
Chromium (Cr) 0.000026 mg/L -10.000026 0.005 < 1/2 RDL
Copper (Cu) -0.000102 mg/L -1-0.000102 0.005 < 1/2 RDL
Iron (Fe) -0.000389 mg/L -1-0.000389 0.01 < 1/2 RDL
Magnesium (Mg) 0.000941 mg/L -10.000941 0.005 < 1/2 RDL
Manganese (Mn) 0.000026 mg/L -10.000026 0.005 < 1/2 RDL
Nickel (Ni) -0.00139 mg/L -1-0.00139 0.005 < 1/2 RDL
Potassium (K) 0.00406 mg/L -10.00406 0.1 < 1/2 RDL
Silver (Ag) -0.000107 mg/L -1-0.000107 0.005 < 1/2 RDL
Sodium (Na) -0.0115 mg/L -1-0.0115 0.05 < 1/2 RDL
Zinc (Zn) -0.00107 mg/L -1-0.00107 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 4.96 5 99.2mg/L -1208014.96
Beryllium (Be) 4.8 5 96.1mg/L -1208014.8
Boron (B) 4.91 5 98.1mg/L -1208014.91
Calcium (Ca) 4.71 5 94.3mg/L -1208014.71
Chromium (Cr) 4.85 5 97mg/L -1208014.85
Copper (Cu) 4.85 5 97.1mg/L -1208014.85
Iron (Fe) 4.79 5 95.9mg/L -1208014.79
Magnesium (Mg) 4.98 5 99.7mg/L -1208014.98
Manganese (Mn) 5.05 5 101mg/L -1208015.05
Nickel (Ni) 4.88 5 97.6mg/L -1208014.88
Potassium (K) 4.88 5 97.6mg/L -1208014.88
Silver (Ag) 0.498 0.5 99.6mg/L -1208010.498
Sodium (Na) 4.9 5 97.9mg/L -1208014.9
Zinc (Zn) 4.94 5 98.9mg/L -1208014.94
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16040004 -- 2016009103
Barium (Ba) 5 5 99.9mg/L -1257515
Beryllium (Be) 4.83 5 96.7mg/L -1257514.83
Boron (B) 4.98 5 98.2mg/L -1257514.98
Calcium (Ca) 10.6 5 99.7mg/L -12575110.6
Chromium (Cr) 4.88 5 97.6mg/L -1257514.88
Copper (Cu) 4.87 5 97.4mg/L -1257514.87
Page 22 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040004
Q16050013 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16040004 -- 2016009103
Iron (Fe) 4.85 5 96.8mg/L -1257514.85
Magnesium (Mg) 9.99 5 95.8mg/L -1257519.99
Manganese (Mn) 5.08 5 101mg/L -1257515.08
Nickel (Ni) 4.87 5 97.4mg/L -1257514.87
Potassium (K) 6.77 5 97.9mg/L -1257516.77
Silver (Ag) 0.497 0.5 99.4mg/L -1257510.497
Sodium (Na) 14.1 5 86.5mg/L -12575114.1
Zinc (Zn) 4.92 5 98.5mg/L -1257514.92
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16040004 -- 2016009103
Barium (Ba) 4.95 5 99 0.945mg/L -1257514.95
Beryllium (Be) 4.79 5 95.9 0.831mg/L -1257514.79
Boron (B) 4.96 5 97.7 0.49mg/L -1257514.96
Calcium (Ca) 10.5 5 97.3 2.46mg/L -12575110.5
Chromium (Cr) 4.83 5 96.6 1.09mg/L -1257514.83
Copper (Cu) 4.81 5 96.2 1.26mg/L -1257514.81
Iron (Fe) 4.79 5 95.6 1.27mg/L -1257514.79
Magnesium (Mg) 9.91 5 94.2 1.75mg/L -1257519.91
Manganese (Mn) 5.02 5 100 1.15mg/L -1257515.02
Nickel (Ni) 4.82 5 96.4 0.97mg/L -1257514.82
Potassium (K) 6.7 5 96.5 1.4mg/L -1257516.7
Silver (Ag) 0.494 0.5 98.7 0.662mg/L -1257510.494
Sodium (Na) 14 5 84.2 2.72mg/L -12575114
Zinc (Zn) 4.87 5 97.4 1.06mg/L -1257514.87
Page 23 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040004
Q16050008 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) 0.159 ug/L -10.159 1 < 1/2 RDL
Arsenic (As) 0.0115 ug/L -10.0115 1 < 1/2 RDL
Cadmium (Cd) 0.0024 ug/L -10.0024 1 < 1/2 RDL
Cobalt (Co) -0.0058 ug/L -1-0.0058 1 < 1/2 RDL
Lead (Pb) 0.004 ug/L -10.004 1 < 1/2 RDL
Selenium (Se) 0.0747 ug/L -10.0747 1 < 1/2 RDL
Thallium (Tl) Low Level -0.0047 ug/L -1-0.0047 0.2 < 1/2 RDL
Vanadium (V) 0.0279 ug/L -10.0279 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 56.3 50 113ug/L -12080156.3
Arsenic (As) 52.5 50 105ug/L -12080152.5
Cadmium (Cd) 48.6 50 97.2ug/L -12080148.6
Cobalt (Co) 52.1 50 104ug/L -12080152.1
Lead (Pb) 48.6 50 97.1ug/L -12080148.6
Selenium (Se) 49.6 50 99.3ug/L -12080149.6
Thallium (Tl) Low Level 42.1 50 84.2ug/L -12080142.1
Vanadium (V) 48.1 50 96.1ug/L -12080148.1
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16040004 -- 2016009106
Antimony (Sb) 55.9 50 111ug/L -12080155.9
Antimony (Sb) 55.9 50 111ug/L -12575155.9
Arsenic (As) 52.8 50 105ug/L -12080152.8
Arsenic (As) 52.8 50 105ug/L -12575152.8
Cadmium (Cd) 48.6 50 97.1ug/L -12575148.6
Cadmium (Cd) 48.6 50 97.1ug/L -12080148.6
Cobalt (Co) 51.8 50 103ug/L -12080151.8
Cobalt (Co) 51.8 50 103ug/L -12575151.8
Lead (Pb) 48.4 50 96.7ug/L -12080148.4
Lead (Pb) 48.4 50 96.7ug/L -12575148.4
Selenium (Se) 66.2 50 102ug/L -12080166.2
Selenium (Se) 66.2 50 102ug/L -12575166.2
Thallium (Tl) Low Level 41.5 50 82.9ug/L -12575141.5
Vanadium (V) 51.7 50 97.7ug/L -12080151.7
Vanadium (V) 51.7 50 97.7ug/L -12575151.7
Page 24 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040004
Q16050008 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16040004 -- 2016009106
Antimony (Sb) 56.5 50 112 1.17ug/L -13070156.5
Antimony (Sb) 56.5 50 112 1.17ug/L -12080156.5
Arsenic (As) 53.3 50 106 0.988ug/L -12080153.3
Arsenic (As) 53.3 50 106 0.988ug/L -13070153.3
Cadmium (Cd) 49.6 50 99.2 2.16ug/L -13070149.6
Cadmium (Cd) 49.6 50 99.2 2.16ug/L -12080149.6
Cobalt (Co) 52.3 50 104 0.912ug/L -12080152.3
Cobalt (Co) 52.3 50 104 0.912ug/L -13070152.3
Lead (Pb) 49.2 50 98.3 1.6ug/L -12080149.2
Lead (Pb) 49.2 50 98.3 1.6ug/L -13070149.2
Selenium (Se) 66.1 50 101 0.258ug/L -12080166.1
Selenium (Se) 66.1 50 101 0.258ug/L -13070166.1
Thallium (Tl) Low Level 43 50 85.9 3.46ug/L -13070143
Vanadium (V) 52 50 98.4 0.675ug/L -13070152
Vanadium (V) 52 50 98.4 0.675ug/L -12080152
Page 25 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040004
Q16040480 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16040004 -- 2016009103
TDS 5.78mg/L -189
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16040004 -- 2016009105
TDS 9.09mg/L -142
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 96mg/L -11090196
Page 26 of 27
Page 27 of 27