8505_DukeBelewsCreekFGD_May2016_1stSemiAnnual_DIN26536_20160729

FGD Residue Landfill Permit No. 8505
Semiannual Groundwater
Monitoring Report
May 2016 Sampling Event
Belews Creek Steam Station
August 2, 2016

Duke Energy Carolinas, LLC | Belews Creek Steam Station
FGD Residue Landfill Semiannual Groundwater Monitoring Report
May 2016 Sampling Event
CONTENTS

1

Contents
Page
Report Verification i
Contents 1
Section 1 – Background 2
Section 2 – Methods 4
2.1 Sampling and Analysis Methods 4
2.2 Statement of Work 4
Section 3 – Results 6
3.1 Site Groundwater Flow 6
3.2 Analytical Results 6

FIGURES
1. Site Location Map
2. Sample Locations
3. Generalized Groundwater Surface Contours
TABLES
1. Well Construction Information
2. Groundwater Flow Velocities
3. Field Data Parameters
4. Field and Analytical Results
5. Analytical Results that Equal or Exceed 15A NCAC 2L Groundwater Quality Standards
6. Leachate Field and Analytical Results
APPENDICES
A. Field Sampling Forms

B. Laboratory Report and Chain-of-Custody Forms

Duke Energy Carolinas, LLC | Belews Creek Steam Station
FGD Residue Landfill Semiannual Groundwater Monitoring Report
May 2016 Sampling Event
SECTION 1 – BACKGROUND

2

Section 1 – Background
The flue gas desulfurization (FGD) residue landfill is located at the Duke Energy Carolinas, LLC
(Duke Energy) Belews Creek Steam Station, in Stokes County, North Carolina. The FGD
residue landfill is permitted to receive FGD residue (gypsum) from Belews Creek Steam Station
operations. The landfill is permitted under the North Carolina Department of Environmental
Quality (NCDEQ) Solid Waste Permit No. 8505.
The FGD residue landfill is located south of the Belews Creek plant, on land between two arms
of the Belews Lake. The West Belews Creek arm of the lake is located west of the landfill site
and the East Belews Creek arm of the lake is located east of the site. Craig Road is located to
the west of the landfill. The FGD residue landfill and nearby surrounding area are depicted on
Figure 1.
The landfill consists of four cells contained in an area of approximately 24 acres. The adjacent
stormwater basin occupies an area of approximately 2.4 acres and is used to manage leachate
and stormwater collected from the landfill. The landfill has an engineered liner system consisting
of a leachate collection system, underlain by a high-density polyethylene (HDPE) geomembrane
liner, underlain by a geo-synthetic clay liner.
The subsurface conditions in the landfill area consist of residual soils, saprolite, partially
weathered rock, and bedrock, as described in the Water Quality Monitoring Plan.1
As is typical for groundwater systems located in the Piedmont region, groundwater at the landfill
site occurs within the saprolite, partially weathered rock, and shallow fractured bedrock under
unconfined aquifer conditions. The groundwater flow in the area of the landfill is generally from
areas of higher topography, located to the east of the landfill, to the west and to the northwest of
the landfill, towards Belews Lake.

1 Water Quality Monitoring Plan FGD Scrubber Residue Landfill Belews Creek Steam Station, December
07, 2007.
Duke Energy Carolinas, LLC | Belews Creek Steam Station
FGD Residue Landfill Semiannual Groundwater Monitoring Report
May 2016 Sampling Event
SECTION 1 – BACKGROUND

3

The monitoring system for the landfill consists of the following:
Monitoring Wells2:BC-20
BC-21
BC-22
BC-23A
BC-25
BC-26
BC-27
BC-28
BC-29
BC-30
BC-31
BC-323

Observation Well: BC-7

Surface Water: SW-1

Leachate Sample: Leachate

The monitoring system for the landfill is shown on Figure 2. A summary of monitoring well
construction information is presented in Table 1. Monitoring wells BC-23A and BC-28 are
considered to represent background groundwater quality, according to the Water Quality
Monitoring Plan. The groundwater monitoring locations are sampled on a semi-annual basis and
the results compared to groundwater quality standards found in 15A NCAC .02L .0202 (g) (2L
Standards).
Observation well BC-7 is used for water level measurements only. Monitoring wells are used to
monitor groundwater quality and to measure groundwater levels.
SW-1 is a groundwater seep located to the east of well BC-28. When water is present, it
emanates from the ground just above the sampling location. SW-1 analytical results are
compared to 2L Standards. This surface water feature drains to Belews Lake.

2 BC-25 and BC-27 were converted (June 2015) to stick-up wells in an effort to reduce TDS and obtain
better samples. 3 Monitoring well BC-32 was installed in August 2013, as part of a groundwater assessment being
conducted at the landfill. The monitoring well is not included in the Water Quality Monitoring Plan, but the
analytical results from the well are included in this landfill groundwater monitoring report.
Duke Energy Carolinas, LLC | Belews Creek Steam Station
FGD Residue Landfill Semiannual Groundwater Monitoring Report
May 2016 Sampling Event
SECTION 2 – METHODS

4

Section 2 – Methods
2.1 Sampling and Analysis Methods
Groundwater sampling and documentation of sampling activities were performed by Duke
Energy personnel (Duke Energy Carolinas Field Certification #5193) in accordance with the
North Carolina Solid Waste Management Guidelines. Copies of the field sampling forms are
included in Appendix A. The parameters and constituents sampled were selected by Duke
Energy and the NCDEQ Division of Solid Waste and were analyzed by the Duke Energy
Analytical Laboratory (North Carolina Laboratory Certification #248) and provided to HDR by
Duke Energy. The laboratory report and chain-of-custody forms are included in Appendix B.
The groundwater samples were analyzed using the following analytical methods:
 Barium, boron, chromium, copper, iron, manganese, nickel, silver, and zinc using
Environmental Protection Agency (EPA) Solid Waste (SW) 8464 - Method 6010D
 Arsenic, cadmium, lead, and selenium by EPA SW 846 - Method 6020B
 Chloride, fluoride, nitrate as nitrogen, and sulfate using EPA SW 846 - Method 9056A
 Mercury using EPA SW 846 - Method 7470A
 Total Dissolved Solids using Standard Method (SM) 2540C
2.2 Statement of Work
HDR completed the following tasks:
 Received field sampling information provided by Duke Energy (performed by Duke
Energy personnel) for monitoring wells BC-20, BC-21, BC-22, BC-23A, BC-25, BC-26,
BC-27, BC-28, BC-29, BC-30, BC-31, BC-32, surface water sampling location SW-1,
and the leachate sampling location. The samples were collected on May 4, 2016 and
HDR received the data on May 25, 2016.

 Reviewed the laboratory analytical results for the samples noted above. The Electronic
Data Deliverable (EDD), provided by Duke Energy, was adapted to conform to the
format requirements of the NCDEQ EDD template. HDR added an italicized J data
qualifier (J’) to indicate a detected concentration that equals or is greater than the
laboratory’s method reporting limit (MRL), but less than the Solid Waste Section Limit5
(SWSL), and retained the laboratory-supplied qualifier J to indicate values that equal or
are greater than the laboratory’s method detection limit (MDL) but are less than the
MRL. A copy of the original EDD is retained in HDR’s files.
4 EPA Hazardous Waste Test Methods (SW-846); available online at https://www.epa.gov/hw-sw846
(Accessed July 1, 2016)
5 The Solid Waste Section Limit (SWSL) is defined by NCDEQ as the lowest amount of analyte in a
sample that can be quantitatively determined with suitable precision and accuracy. The SWSL is the
concentration below which reported results must be qualified as estimated. NCDEQ Division of Waste
Management Memorandum dated February 23, 2007.
Duke Energy Carolinas, LLC | Belews Creek Steam Station
FGD Residue Landfill Semiannual Groundwater Monitoring Report
May 2016 Sampling Event
SECTION 2 – METHODS

5

 Developed a generalized groundwater surface contour map using map data and
groundwater elevation data supplied by Duke Energy.

 Prepared and submitted this Semiannual Groundwater Monitoring Report to Duke
Energy.
Duke Energy Carolinas, LLC | Belews Creek Steam Station
FGD Residue Landfill Semiannual Groundwater Monitoring Report
May 2016 Sampling Event
SECTION 3 – RESULTS

6

Section 3 – Results
3.1 Site Groundwater Flow
Generalized groundwater surface contours and groundwater flow direction arrows for the site
are shown on Figure 3. These contours were developed using groundwater elevations
measured at the wells on the date of sampling. Calculated groundwater flow velocities are
presented on Table 2.
Based on the groundwater elevations measured at the wells on the date of sampling,
groundwater flow in the area of the landfill is generally from areas of higher topography, located
to the east of the landfill, to the west and to the northwest of the landfill, towards Belews Lake.
3.2 Analytical Results
A summary of the field data is presented in Table 3.
The field and analytical results of groundwater and surface water sampling are summarized in
Table 4. The analysis results for these locations are compared to the 2L Standards.
Concentrations with values that attain or exceed the 2L Standards are noted on Table 4 by bold
font. A summary of the analytical results that attain or exceed the 2L Standards and a
preliminary analysis of the cause and significance of the exceedances are presented in Table 5.
The field and analytical results of leachate sampling are summarized in Table 6.
Concentrations with values that equal or are greater than the SWSLs are noted on Tables 4 and
6 by gray-shaded cells.
Selected samples were diluted as is normal laboratory practice to bring samples to the
calibrated range of the analysis. Specifics regarding the samples that were diluted, including the
dilution amount, are reported in the EDD and the laboratory report.
HDR previously prepared and submitted an assessment to NCDEQ for exceedances of 2L
Standards at this landfill (Groundwater Assessment Belews Creek Steam Station FGD Residue
Landfill, Permit No. 8505. October 5, 2012).
The report assessed the exceedances of the 2L Standards at wells BC-20, BC-21, BC-23A, BC-
26, BC-27, BC-29, and BC-31 and at surface water sampling location SW-1. The assessment
report concluded for the period of analytical results reviewed that:
 the source of iron exceedances reported in BC-20, BC-21, BC-23A, BC-26, BC-27, BC-
29, and BC-31 appear to be related to turbidity introduced from naturally occurring
sources,
 the source of manganese exceedances reported in BC-27 appear to be related to
turbidity introduced from naturally occurring sources,
 the manganese results at BC-21 do not appear to be related to turbidity, and
Duke Energy Carolinas, LLC | Belews Creek Steam Station
FGD Residue Landfill Semiannual Groundwater Monitoring Report
May 2016 Sampling Event
SECTION 3 – RESULTS

7

 the iron and manganese exceedances at surface water sampling location SW-1 are from
naturally occurring sources and are not related to impacts from the landfill.
The report assessed 2L Standard exceedances for iron, sulfate, and total dissolved solids (TDS)
at monitoring well BC-25. HDR recommended installing an additional monitoring well at the
review boundary between BC-25 and the landfill to further delineate the sulfate and TDS
concentrations in this area and improve the understanding of groundwater flow and quality near
BC-25. HDR further recommended that BC-20 and BC-21 be re-sampled when the new
monitoring well was sampled.
In a letter dated November 28, 20126 to Mr. Ed Sullivan, P.E., of Duke Energy, the NCDEQ
Solid Waste Section approved the recommendations presented in the groundwater assessment
report dated October 5, 2012.
Monitoring well BC-32 was installed in August 2013, and HDR prepared and submitted a
supplemental groundwater assessment to NCDEQ (Supplemental Groundwater Assessment
Belews Creek Steam Station FGD Residue Landfill, Permit No. 8505. June 4, 2014).
The supplemental groundwater assessment report indicated:
 although it is not possible to eliminate leakage through the liner system as a cause for
2L Standard exceedances, leakage through the liner system is not the likely source of 2L
Standard exceedances, and
 increases in precipitation runoff received by non-contact stormwater basins SB-6 and
SB-7, due to the process of filling Cell 1, may have caused deposited FGD residue to be
subjected to increased infiltration into the groundwater at these basins. It appears that
an increase in surface runoff and infiltration of gypsum into the groundwater in this area
may be the source of exceedances of sulfate, TDS, and selenium.
As part of the supplemental groundwater assessment report HDR recommended:
 monitoring well BC-32 should continue to be sampled as part of the groundwater
monitoring program for the FGD Residue Landfill,
 if concentrations of sulfate and TDS decrease to below the 2L Standard in monitoring
wells BC-25 and BC-32 and remain below the 2L Standard for a minimum of two
sampling events, discontinue groundwater monitoring at BC-25 and incorporate
monitoring well BC-32 into the groundwater monitoring program for the FGD Residue
Landfill, and
 if the concentrations of sulfate and TDS remain above the 2L Standards in monitoring
wells BC-25 and BC-32 for the next three sampling events, an additional assessment
should be conducted to identify the sources of the exceedances.
6 North Carolina Department of Environment and Natural Resources, Division of Waste Management.
November 28, 2012, Groundwater Assessment Report Response. Duke Energy – Belews Creek FGD
Landfill, DOC ID 17761.
Duke Energy Carolinas, LLC | Belews Creek Steam Station
FGD Residue Landfill Semiannual Groundwater Monitoring Report
May 2016 Sampling Event
SECTION 3 – RESULTS

8

This is the fourth groundwater monitoring event since the completion of the supplemental
groundwater assessment (November 2014, May 2015, November 2015, and May 2016).
The sulfate and TDS concentrations in monitoring wells BC-25 and BC-32 have been greater
than the 2L Standards during last four sampling events, with the concentrations of these
parameters generally increasing in both of the monitoring wells.
For the last three sampling events, sulfate concentrations in BC-20 have been above the 2L
standard of 250 mg/L.
The selenium concentration in BC-21 was measured above the 2L standard in August 2013 but
below the standard in all events before and after that event.
The sulfate concentration measured in monitoring well BC-21 has been greater than the 2L
Standard during the last five sampling events.
Selenium in BC-25 has been measured at concentrations greater than the 2L standard of 20
µg/L during both May and November 2015 sampling events (at 20.3 µg/L and 21.9 µg/L,
respectively). However, as of May 2016, the selenium concentration is below 2L at 12.4 µg/L.
Based on the results of the sampling events conducted since the June 2014 Supplemental
Groundwater Assessment, Duke Energy contacted DEQ and is in the process of providing a
plan for further assessment of the groundwater exceedances at the landfill.

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o
r
i
d
e
.
5
.

P
W
R

i
n
d
i
c
a
t
e
s

p
a
r
t
i
a
l
l
y

w
e
a
t
h
e
r
e
d

r
o
c
k
.
6
.

B
R

i
n
d
i
c
a
t
e
s

b
e
d
r
o
c
k
.
7
.

H
o
r
i
z
o
n
t
a
l

d
a
t
u
m

a
s
s
u
m
e
d

t
o

b
e

N
A
D
8
3
.
8
.

E
l
e
v
a
t
i
o
n
s

b
a
s
e
d

o
n

N
V
G
D

2
9

v
e
r
t
i
c
a
l

d
a
t
u
m
.
9
.

M
o
n
i
t
o
r
i
n
g

w
e
l
l
s

B
C
-
2
5

a
n
d

B
C
-
2
7

w
e
r
e

o
r
i
g
i
n
a
l
l
y

f
l
u
s
h
-
m
o
u
n
t

m
o
n
i
t
o
r
i
n
g

w
e
l
l
s
,

b
u
t

w
e
r
e

c
o
n
v
e
r
t
e
d

t
o

s
t
i
c
k
-
u
p

w
e
l
l
s

i
n

J
u
n
e

2
0
1
5
.
10
.

B
C
-
3
2

w
a
s

o
r
i
g
i
n
a
l
l
y

s
u
r
v
e
y
e
d

i
n

N
A
V
D

8
8

v
e
r
t
i
c
a
l

d
a
t
u
m
.

E
l
e
v
a
t
i
o
n

p
r
e
s
e
n
t
e
d

i
n

t
a
b
l
e

w
a
s

c
o
n
v
e
r
t
e
d

t
o

N
V
G
D

2
9

v
e
r
t
i
c
a
l

d
a
t
u
m
.
11
.

D
e
p
t
h

t
o

g
r
o
u
n
d
w
a
t
e
r

w
a
s

m
e
a
s
u
r
e
d

o
n

M
a
y

4
,

2
0
1
6
.
12
.

I
n
f
o
r
m
a
t
i
o
n

p
r
o
v
i
d
e
d

b
y

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

o
n

M
a
y

2
5
,

2
0
1
6
.
We
l
l

S
t
i
c
k
-
u
p

He
i
g
h
t

A
b
o
v
e

Gr
o
u
n
d

S
u
r
f
a
c
e

(ft
.
)
We
l
l

I
D
We
l
l

In
s
t
a
l
l
a
t
i
o
n

Da
t
e
Co
o
r
d
i
n
a
t
e
s
TO
C

El
e
v
a
t
i
o
n

(
f
t
.
)
Gr
o
u
n
d

S
u
r
f
a
c
e

El
e
v
a
t
i
o
n
(f
t
.
)
Gr
o
u
n
d
w
a
t
e
r

Ele
v
a
t
i
o
n
(f
t
.
)
De
p
t
h

t
o

W
a
t
e
r

be
l
o
w

T
O
C
(ft
.
)
To
t
a
l

W
e
l
l

De
p
t
h

b
e
l
o
w

TO
C
(f
t
.
)
De
p
t
h

t
o

T
o
p

o
f

Sc
r
e
e
n

f
r
o
m

T
O
C
(f
t
.
)
Casing TypeWell Diameter (in.)Geology of Screened Interval
Sc
r
e
e
n
e
d

I
n
t
e
r
v
a
l

be
l
o
w

T
O
C
(f
t
.
)
Page  1  of  1
Ta
b
l
e

2

-

G
r
o
u
n
d
w
a
t
e
r

F
l
o
w

V
e
l
o
c
i
t
i
e
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s

L
L
C
/
B
e
l
e
w
s

C
r
e
e
k

S
t
e
a
m

S
t
a
t
i
o
n
FG
D

R
e
s
i
d
u
e

L
a
n
d
f
i
l
l
,

P
e
r
m
i
t

N
o
.

8
5
0
5
BC
-
7
74
5
74
0
17
9

0
.
0
2
8

0
.
3
1
0

0
.
0
0
5

1
.
7
3
BC
-
2
0
75
0
74
5
25
8

0
.
0
1
9

0
.
4
1
1

0
.
2
5
9

0
.
0
3
BC
-
2
1
75
0
74
5
10
9

0
.
0
4
6

0
.
4
1
1

0
.
2
5
9

0
.
0
7
BC
-
2
3
A

7
8
3
.
6
8
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0
16
5

0
.
0
2
2

0
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3
1
0

0
.
0
0
5

1
.
3
8
BC
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5
74
0
73
5
96

0
.
0
5
2

0
.
4
1
1

0
.
2
5
9

0
.
0
8
BC
-
2
6
74
0
73
5
16
1

0
.
0
3
1

0
.
4
1
1

0
.
2
5
9

0
.
0
5
BC
-
2
7
73
5
73
0
84

0
.
0
5
9

0
.
4
1
1

0
.
2
5
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0
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0
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BC
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2
8

7
6
7
.
3
0
76
5
21

0
.
1
0
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0
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2
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0
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1
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BC
-
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0
.
0
5
1

0
.
4
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1

0
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2
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0
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0
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5
75
0
99

0
.
0
5
1

0
.
4
1
1

0
.
2
5
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0
.
0
8
BC
-
3
1

7
5
6
.
1
3
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5
11
2

0
.
0
1
0

0
.
3
1
0

0
.
0
0
5

0
.
6
3
BC
-
3
2
74
5
74
0
23
8

0
.
0
2
1

0
.
4
1
1

0
.
2
5
9

0
.
0
3
No
t
e
s
:
1
.

L
i
n
e
a
r

d
i
s
t
a
n
c
e

m
e
a
s
u
r
e
d

t
h
r
o
u
g
h

m
o
n
i
t
o
r
i
n
g

w
e
l
l
s

i
s

a
p
p
r
o
x
i
m
a
t
e
l
y

p
e
r
p
e
n
d
i
c
u
l
a
r

t
o

g
r
o
u
n
d
w
a
t
e
r

c
o
n
t
o
u
r
s
.
2
.

A
t

m
o
n
i
t
o
r
i
n
g

w
e
l
l

l
o
c
a
t
i
o
n
s

w
h
e
r
e

d
o
w
n
g
r
a
d
i
e
n
t

c
o
n
t
o
u
r
s

a
r
e

n
o
t

p
r
e
s
e
n
t
,

t
h
e

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n

a
t

t
h
e

m
o
n
i
t
o
r
i
n
g

w
e
l
l

i
s

u
s
e
d

a
s

t
h
e

d
o
w
n
g
r
a
d
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n
.
3
.

A
t

m
o
n
i
t
o
r
i
n
g

w
e
l
l

l
o
c
a
t
i
o
n
s

w
h
e
r
e

u
p
g
r
a
d
i
e
n
t

c
o
n
t
o
u
r
s

a
r
e

n
o
t

p
r
e
s
e
n
t
,

t
h
e

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n

a
t

t
h
e

m
o
n
i
t
o
r
i
n
g

w
e
l
l

i
s

u
s
e
d

a
s

t
h
e

u
p
g
r
a
d
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n
.
4
.

M
o
n
i
t
o
r
i
n
g

w
e
l
l
s

a
r
e

n
o
t

l
i
s
t
e
d

w
h
e
r
e

i
n
s
u
f
f
i
c
i
e
n
t

i
n
f
o
r
m
a
t
i
o
n

i
s

a
v
a
i
l
a
b
l
e

t
o

c
a
l
c
u
l
a
t
e

v
e
l
o
c
i
t
y
.
5
.

H
y
d
r
a
u
l
i
c

g
r
a
d
i
e
n
t
s

a
n
d

g
r
o
u
n
d
w
a
t
e
r

v
e
l
o
c
i
t
i
e
s

a
r
e

a
p
p
r
o
x
i
m
a
t
e
.
6
.

H
y
d
r
a
u
l
i
c

c
o
n
d
u
c
t
i
v
i
t
y

p
r
e
s
e
n
t
e
d

f
o
r

t
h
e

a
l
l
u
v
i
u
m
/
s
o
i
l
/
s
a
p
r
o
l
i
t
e

h
y
d
r
o
s
t
r
a
t
i
g
r
a
p
h
i
c

l
a
y
e
r

i
s

t
h
e

g
e
o
m
e
t
r
i
c

m
e
a
n

o
f

t
h
e

c
o
n
d
u
c
t
i
v
i
t
y

d
a
t
a

i
n

t
h
e

H
D
R

C
o
n
d
u
c
t
i
v
i
t
y

D
a
t
a
b
a
s
e

(
u
n
p
u
b
l
i
s
h
e
d

d
a
t
a

f
r
o
m

P
i
e
d
m
o
n
t

C
a
r
o
l
i
n
a

s
i
t
e
s

w
i
t
h

f
o
l
i
a
t
e
d
/
l
a
y
e
r
e
d

b
e
d
r
o
c
k
)
.
7
.

H
y
d
r
a
u
l
i
c

c
o
n
d
u
c
t
i
v
i
t
y

p
r
e
s
e
n
t
e
d

f
o
r

t
h
e

b
e
d
r
o
c
k

l
a
y
e
r

i
s

t
h
e

g
e
o
m
e
t
r
i
c

m
e
a
n

o
f

t
h
e

c
o
n
d
u
c
t
i
v
i
t
y

d
a
t
a

i
n

t
h
e

H
D
R

C
o
n
d
u
c
t
i
v
i
t
y

D
a
t
a
b
a
s
e

(
u
n
p
u
b
l
i
s
h
e
d

d
a
t
a

f
r
o
m

P
i
e
d
m
o
n
t

C
a
r
o
l
i
n
a

s
i
t
e
s

w
i
t
h

f
o
l
i
a
t
e
d
/
l
a
y
e
r
e
d

b
e
d
r
o
c
k
)
.
8
.

E
f
f
e
c
t
i
v
e

p
o
r
o
s
i
t
y

p
r
e
s
e
n
t
e
d

f
o
r

t
h
e

a
l
l
u
v
i
u
m
/
s
o
i
l
/
s
a
p
r
o
l
i
t
e

h
y
d
r
o
s
t
r
a
t
i
g
r
a
p
h
i
c

l
a
y
e
r

i
s

t
h
e

m
e
a
n

v
a
l
u
e

e
s
t
i
m
a
t
e
d

f
r
o
m

g
r
a
i
n

s
i
z
e

d
a
t
a

u
s
i
n
g

F
e
t
t
e
r
/
B
e
a
r

D
i
a
g
r
a
m
s
.

9
.

E
f
f
e
c
t
i
v
e

p
o
r
o
s
i
t
y

f
o
r

t
h
e

b
e
d
r
o
c
k

l
a
y
e
r

i
s

b
a
s
e
d

o
n

p
u
b
l
i
s
h
e
d

v
a
l
u
e
s

.

10
.

H
y
d
r
a
u
l
i
c

g
r
a
d
i
e
n
t

a
n
d

g
r
o
u
n
d
w
a
t
e
r

v
e
l
o
c
i
t
i
e
s

c
a
l
c
u
l
a
t
e
d

b
a
s
e
d

o
n

g
r
o
u
n
d
w
a
t
e
r

d
e
p
t
h

m
e
a
s
u
r
e
d

o
n

M
a
y

4
,

2
0
1
6
.
Ef
f
e
c
t
i
v
e

Po
r
o
s
i
t
y

(%
/
1
0
0
)
Gr
o
u
n
d
w
a
t
e
r

Ve
l
o
c
i
t
y

(f
t
/
d
a
y
)
We
l
l

I
D

U
p
g
r
a
d
i
e
n
t

Gr
o
u
n
d
w
a
t
e
r

Co
n
t
o
u
r

El
e
v
a
t
i
o
n
(f
t
)
D
o
w
n
g
r
a
d
i
e
n
t

Gr
o
u
n
d
w
a
t
e
r

Co
n
t
o
u
r

El
e
v
a
t
i
o
n
(f
t
)
Li
n
e
a
r

Di
s
t
a
n
c
e

Be
t
w
e
e
n

Co
n
t
o
u
r
s

th
r
o
u
g
h

W
e
l
l
(f
t
)
Hy
d
r
a
u
l
i
c

Gr
a
d
i
e
n
t

(f
t
/
f
t
)
Hy
d
r
a
u
l
i
c

Co
n
d
u
c
t
i
v
i
t
y

(f
t
/
d
a
y
)
Page 1 of 1
Ta
b
l
e

3

-

F
i
e
l
d

D
a
t
a

P
a
r
a
m
e
t
e
r
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s

L
L
C
/
B
e
l
e
w
s

C
r
e
e
k

S
t
e
a
m

S
t
a
t
i
o
n
FG
D

R
e
s
i
d
u
e

L
a
n
d
f
i
l
l
,

P
e
r
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Page 1 of 1
Ta
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Ta
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Page 1 of 1

A
Appendix A
Field Sampling Forms

ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬▬►0.0 0.0 ▬/▬►0.0
SS 726.3 ▬▬►720 720.3 ▬/▬►720
SS 344.6 ▬/▬►350 346.7 ▬/▬►350
SS ▬/▬►1410 ▬/▬►1410
B (7.00)7.00 ▬▬►7.02 7.04 ▬/▬►7.02
B (4.00)3.98 ▬▬►4.00 4.03 ▬/▬►4.00
B (10.00)9.94 ▬/▬►10.06 10.01 ▬/▬►10.06
20.15 20.13
pH Check B (7.00)▬▬►7.13
Time:0.00
439 ▬▬►441 444 ▬/▬►442
N/A ▬/▬►N/A N/A ▬/▬►N/A
Zobell's 20.00 19.78
TEMP (CO)
BP (mmHg)
COND
100 % mg/L 8.87 ▬▬►8.87 8.88 ▬/▬►8.88
After Cal 8.86 99.91 8.86 99.81
LCS 8.85 99.79 8.81 99.25
LCSD 8.84 -0.11 8.82 0.11
SS 53.9 ▬/▬►56.0 54.8 ▬/▬►56.0
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 735.3 (mmHg)Ending BP 734.8
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
TURB
(ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION PASS CALIBRATION PASS
DO
(mg/L)
19.57 19.25
735.74 731.79
108
CALIBRATION PASS CALIBRATION PASS
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
After Cal % SAT After Cal % SAT
109.2
ORP Temp.ORP Temp.
ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.
CALIBRATION FAILED CALIBRATION ACCEPTED
Buffer Temp.Buffer Temp.
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
INSTRUMENT ZEROED INSTRUMENT ZEROED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Parameter Calibration Results Calibration Results
CALIBRATION BP (mmHg)735.74 CALIBRATION BP (mmHg)731.79
Calibration Date / Time 4-May-16 310 5-May-16 645
PROCEDURE #:HYDROLAB 3210.6 VALIDATED BY:
FIELD SAMPLING CALIBRATION FORM
STUDY:BELEWS CREEK STEAM STATION - FGD LANDFILL GROUNDWATER MONITORING
DATE (s):May 4, 2016 SURFACE UNIT READER:LDC
OTHER EQUIPMENT:TURBIDIMETER NO.2 - 3260-GW Partly cloudy, slight breeze, 60 to 75 deg F
COLLECTORS:LDC, PSP, HET SURFACE UNIT SERIAL #:0662
ANALYZER MODEL#:HL4 400439
ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬▬►0.0 0.0 ▬/▬►0.0
SS 731.7 ▬▬►720 715.9 ▬/▬►720
SS 342.9 ▬/▬►350 340.6 ▬/▬►350
SS ▬/▬►1410 ▬/▬►1410
B (7.00)6.98 ▬▬►7.02 7.08 ▬/▬►7.02
B (4.00)3.94 ▬▬►4.00 4.03 ▬/▬►4.00
B (10.00)10.08 ▬/▬►10.06 10.10 ▬/▬►10.06
20.04 20.10
pH Check B (7.00)▬▬►7.13
Time:0.00
440 ▬▬►441 442 ▬/▬►442
N/A ▬/▬►N/A N/A ▬/▬►N/A
Zobell's 19.93 19.76
TEMP (CO)
BP (mmHg)
COND
100 % mg/L 8.86 ▬▬►8.88 8.89 ▬/▬►8.88
After Cal 8.89 100.16 8.90 100.24
LCS 8.88 100.05 8.86 99.79
LCSD 8.86 -0.23 8.83 -0.34
SS 52.6 ▬/▬►53.5 52.7 ▬/▬►53.5
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 735.3 (mmHg)Ending BP 734.8
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
TURB
(ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION PASS CALIBRATION PASS
DO
(mg/L)
19.53 19.24
735.74 731.79
107
CALIBRATION PASS CALIBRATION PASS
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
After Cal % SAT After Cal % SAT
106.6
ORP Temp.ORP Temp.
ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.Buffer Temp.
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
INSTRUMENT ZEROED INSTRUMENT ZEROED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Parameter Calibration Results Calibration Results
CALIBRATION BP (mmHg)735.74 CALIBRATION BP (mmHg)731.79
Calibration Date / Time 4-May-16 330 5-May-16 705
PROCEDURE #:HYDROLAB 3210.6 VALIDATED BY:
FIELD SAMPLING CALIBRATION FORM
STUDY:BELEWS CREEK STEAM STATION - FGD LANDFILL GROUNDWATER MONITORING
DATE (s):May 4, 2016 SURFACE UNIT READER:PSP
OTHER EQUIPMENT:TURBIDIMETER NO.1 - 3260-GW Partly cloudy, slight breeze, 60 to 75 deg F
COLLECTORS:LDC, PSP, HET SURFACE UNIT SERIAL #:0800
ANALYZER MODEL#:HL4 400440
37.30 52.30
(psi)(sec)(sec)
(gal)
2.79 (gal)
@
QC By:
WATER LEVEL ONLY
DATE TIME
DISSOLVED
OXYGEN
5/4/2016
ORP
(ft)(YES/NO)
N/A N/A N/A N/A N/A
VOLUME EVACUATION COND.
PURGE METHOD
Level Only
DISCHARGERECHARGEPRESSURE
PUMP CONTROLLER SETTINGS
0.1631CONVERSION FACTOR
Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
2.79WELL VOLUME
FIELD CREW LDC, PSP, HET
MONITORING WELL INFORMATION
2
N/A
PROCEDURE NO 3175.3DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
FOR LEVEL ONLY
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID
PROJECT NAME FGD LANDFILL GROUNDWATER
SAMPLING DATE(s)4-May-2016
44.80
N/APUMP INTAKE DEPTH (ft TOC)52.30
TOC ELEV (ft msl)
GS ELEV (ft msl)
777.80
775.78
WELL/LOCATION NAME BC-7
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 29
WELL DEPTH (ft TOC)
WELL DIAMETER (in)MIDDLE OF WETTED SCREEN (ft toc)
WELL VOL
SCREEN INTERVAL (ft TOC)TO
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)35.21 WATER COLUMN (ft)17.09
EQUIPMENT INFORMATION
LEVEL METER SERIAL#26056 SAMPLING EQUIPMENT
TUBING DIAMETER (in)
LEVEL ONLY
PURGE COMPLETE TEMP SPECIFIC pH TURBIDITY
WATER ELEVATION (ft msl)742.59
APPEARANCE
DETECTED ODOR None
WATER LEVEL
AFTER PURGE *(recalculates on
current water
level)(deg C)(umho/cm)(SU)(NTU)(mV-NHE)(mg/L)
N/A N/A N/A
CHLORINE (mg/l)SAMPLE COLLECTED BY
HET, PSP N/A
TOTAL PURGE
VOLUME
0.00
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
Good Condition
Good Tag
WELL CASING
WELL CONDITION
PROTECTIVE CASING
WELL PAD
WELL TAG
Good Condition
Good Condition
Sample preservation verified to pH
(units)N/A
SAMPLING NOTES
ADDITIONAL WELL CONDITION NOTES
14.22 24.22
12 (psi)10 (sec)(sec)
(gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE VOLUME 0.85 (gal)LDC 5/4/2016 1245 NA
DRAW-DOWN 0.96 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.25 (gal)SAMPLE COLLECTED BY DATE TIME
N/A12:40 12.68 210 15.03 1010 5.16 4.6 368 8.54
N/A
12:35 12.68 210 15.25 1014 5.17 3.9 366 8.52 N/A
12:30 12.68 210 15.67 1012 5.23 5.0 364 8.55
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)11.72 WATER COLUMN (ft)12.50 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)745.50 WELL VOLUME 2.04
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26055 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
Target 200 mL/min.
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)757.22 MIDDLE OF WETTED SCREEN (ft toc)19.22
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)24.22 GS ELEV (ft msl)754.58 PUMP INTAKE DEPTH (ft TOC)23.22
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)4-May-2016 WELL/LOCATION NAME BC-20
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
6.77 16.77
10 (psi)10 (sec)(sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)4-May-2016 WELL/LOCATION NAME BC-21
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)756.69 MIDDLE OF WETTED SCREEN (ft toc)13.18
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)16.77 GS ELEV (ft msl)753.42 PUMP INTAKE DEPTH (ft TOC)16.27
Target 210 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 7
26055 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)9.58 WATER COLUMN (ft)7.19 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)747.11 WELL VOLUME 1.17
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
11:55 9.97 210 15.20 962 4.76 4.8 354 7.98 N/A
11:50 9.97 210 15.33 943 4.77 4.6 351 7.99
N/A12:00 9.97 210 15.51 971 4.77 4.1 355 7.89
DRAW-DOWN 0.39 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.25 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 0.85 (gal)LDC 5/4/2016 1205 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
3.00 13.00
8 (psi)5 (sec)(sec)
(gal)
1.65 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)4-May-2016 WELL/LOCATION NAME BC-22
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)765.91 MIDDLE OF WETTED SCREEN (ft toc)8.00
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)13.00 GS ELEV (ft msl)763.72 PUMP INTAKE DEPTH (ft TOC)11.50
Target 500 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26055 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)2.87 WATER COLUMN (ft)10.13 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)763.04 WELL VOLUME 1.65
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.75 NO 14.25 409 5.27 3.6 329
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
4.57
1.75 NO 14.24 427 5.26 4.4 332 4.50
1.75 NO 14.27 414 5.26 2.9 331 4.54
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
5.25 LDC 5/4/2016 1130 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
76.21 101.21
60 (psi)15 (sec)(sec)
(gal)
3.44 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)4-May-2016 WELL/LOCATION NAME BC-23A
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)863.79 MIDDLE OF WETTED SCREEN (ft toc)90.66
SCREEN LENGTH (ft)25.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)101.21 GS ELEV (ft msl)862.56 PUMP INTAKE DEPTH (ft TOC)98.71
Target 200 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 6
26055 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)80.11 WATER COLUMN (ft)21.10 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)783.68 WELL VOLUME 3.44
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
3.50 90.03 NO 15.02 44 5.66 17.8 272
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
8.05 1.82
2.00 NO 15.09 44 5.70 13.9 292 8.11
2.00 NO 15.04 44 5.70 27.7 278 8.14
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
7.50 LDC 5/4/2016 0825 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
11.15 26.15
8 (psi)10 (sec)(sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)4-May-2016 WELL/LOCATION NAME BC-25
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)748.43 MIDDLE OF WETTED SCREEN (ft toc)19.53
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)26.15 GS ELEV (ft msl)745.97 PUMP INTAKE DEPTH (ft TOC)25.65
Target 80 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)12.90 WATER COLUMN (ft)13.25 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)735.53 WELL VOLUME 2.16
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
13:20 12.28 232 18.69 1655 5.31 47.6 434 4.28 N/A
13:15 12.28 232 18.55 1667 5.32 41.9 431 4.34
N/A
13:30 12.28 232 18.41 1707 5.35 47.6 440 4.42 N/A
13:25 12.28 232 18.98 1689 5.35 47.5 435 4.41
DRAW-DOWN 0.00 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 1.00 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 1.95 (gal)HET, PSP 5/4/2016 1335 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition Originally a flush mount well, it was converted to a stick-up well by adding a riser to
the well casing during June 2015. The original well depth from TOC was 23.15 ft. June
29, 2015 the dedicated pumps were re-set by adding new tubing. Well depth from TOC
was re-measured at 26.15 ft. and updated on this blankform.
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
If well is pumped with no energy discharge (8 to 10 psi) turbidity will decrease below 10 ntu. Ash haul trucks driving by may effect samples.
8.26 23.26
13 (psi)10 (sec)(sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)4-May-2016 WELL/LOCATION NAME BC-26
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)749.32 MIDDLE OF WETTED SCREEN (ft toc)18.77
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)23.26 GS ELEV (ft msl)747.21 PUMP INTAKE DEPTH (ft TOC)22.26
Target 120 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)14.28 WATER COLUMN (ft)8.98 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)735.04 WELL VOLUME 1.46
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
12:25 15.48 300 15.61 154 4.77 8.8 476 3.45 N/A
12:20 15.48 300 15.65 157 4.75 36.0 474 3.51
N/A12:30 15.48 300 15.63 155 4.77 4.7 477 3.42
DRAW-DOWN 1.20 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 3.25 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 4.05 (gal)HET, PSP 5/4/2016 1235 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
23.33 38.33
17 (psi)10 (sec)(sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)4-May-2016 WELL/LOCATION NAME BC-27
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)764.78 MIDDLE OF WETTED SCREEN (ft toc)35.77
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)38.33 GS ELEV (ft msl)762.44 PUMP INTAKE DEPTH (ft TOC)37.83
Target 90 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)33.21 WATER COLUMN (ft)5.12 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)731.57 WELL VOLUME 0.84
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
10:55 33.44 162 17.92 208 5.83 2.9 247 1.88 N/A
10:50 33.44 162 17.53 210 5.83 3.0 234 2.14
N/A
11:05 33.44 162 16.90 194 5.74 1.8 245 1.41 N/A
11:00 33.44 162 17.62 206 5.78 3.4 206 1.79
N/A
11:15 33.44 162 17.29 193 5.73 2.5 244 1.58 N/A
11:10 33.44 162 17.08 186 5.72 2.1 246 1.48
DRAW-DOWN 0.23 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.25 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 1.35 (gal)HET, PSP 5/4/2016 1120 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition Originally a flush mount well, it was converted to a stick-up well by adding a riser to
the well casing during June 2015. The original well depth from TOC was 34.95 ft. June
29, 2015 the dedicated pumps were re-set by adding new tubing. Well depth from TOC
was re-measured at 38.33 ft. and updated on this blankform.
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
45.20 60.20
30 (psi)10 (sec)(sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)4-May-2016 WELL/LOCATION NAME BC-28
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)818.09 MIDDLE OF WETTED SCREEN (ft toc)55.50
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)60.20 GS ELEV (ft msl)816.02 PUMP INTAKE DEPTH (ft TOC)59.20
Target 150 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26055 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)50.79 WATER COLUMN (ft)9.41 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)767.30 WELL VOLUME 1.53
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
9:55 53.09 150 16.20 59 5.65 4.3 299 6.82 N/A
9:50 53.09 150 15.80 59 5.66 4.1 296 6.76
N/A10:00 53.09 150 16.26 58 5.64 8.4 301 6.95
DRAW-DOWN 2.30 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.25 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 0.65 (gal)LDC 5/4/2016 1005 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Minor Cracks
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
10.32 25.32
12 (psi)10 (sec)(sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)4-May-2016 WELL/LOCATION NAME BC-29
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)756.20 MIDDLE OF WETTED SCREEN (ft toc)21.49
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)25.32 GS ELEV (ft msl)752.28 PUMP INTAKE DEPTH (ft TOC)18.28
Target 200 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)17.66 WATER COLUMN (ft)7.66 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)738.54 WELL VOLUME 1.25
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
9:35 17.80 171 15.66 251 4.87 7.9 412 2.02 N/A
9:30 17.80 171 16.02 263 4.88 10.6 412 2.00
N/A9:40 17.80 171 15.33 256 4.85 6.5 413 1.82
DRAW-DOWN 0.14 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 1.00 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 1.50 (gal)PSP, HET 5/4/2016 0945 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
19.10 34.10
17 (psi)13 (sec)(sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)4-May-2016 WELL/LOCATION NAME BC-30
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)775.72 MIDDLE OF WETTED SCREEN (ft toc)29.40
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)34.10 GS ELEV (ft msl)773.91 PUMP INTAKE DEPTH (ft TOC)33.60
Target 200 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 7
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)24.69 WATER COLUMN (ft)9.41 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)751.03 WELL VOLUME 1.53
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
8:10 25.43 198 14.48 66 5.47 33.4 354 7.01 N/A
8:05 25.43 198 14.45 67 5.47 31.5 347 7.00
N/A
8:20 25.43 198 14.50 66 5.48 24.1 366 7.02 N/A
8:15 25.43 198 14.48 66 5.47 26.1 361 7.01
N/A
8:30 25.43 198 14.64 66 5.49 22.7 374 7.04 N/A
8:25 25.43 198 14.58 66 5.47 23.8 370 7.02
N/A
8:40 25.43 198 14.55 66 4.48 22.9 381 7.05 N/A
8:35 25.43 198 14.58 66 5.48 22.7 379 7.04
DRAW-DOWN 0.74 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 1.50 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 3.35 (gal)PSP, HET 5/4/2016 0845 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
Well located in middle of field.
63.30 83.30
30 (psi)10 (sec)(sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)4-May-2016 WELL/LOCATION NAME BC-31
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)816.40 MIDDLE OF WETTED SCREEN (ft toc)73.30
SCREEN LENGTH (ft)20.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)83.30 GS ELEV (ft msl)813.43 PUMP INTAKE DEPTH (ft TOC)82.00
Target 140 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26055 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)60.27 WATER COLUMN (ft)23.03 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)756.13 WELL VOLUME 3.76
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
8:55 64.08 130 15.53 126 5.96 6.5 247 3.50 N/A
8:50 64.08 130 15.65 148 5.98 11.9 257 3.00
N/A
9:05 64.08 130 15.68 110 5.92 5.3 256 4.07 N/A
9:00 64.08 130 15.49 116 5.93 5.7 249 3.78
N/A
9:15 64.08 130 15.86 109 5.92 3.5 265 4.40 N/A
9:10 64.08 130 15.64 109 5.91 3.2 260 4.30
DRAW-DOWN 3.81 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.25 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 1.15 (gal)LDC 5/4/2016 0920 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
18.01 33.01
15 (psi)7 (sec)(sec)
(gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE VOLUME 1.20 (gal)LDC 5/4/2016 1055 NA
DRAW-DOWN 2.00 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.50 (gal)SAMPLE COLLECTED BY DATE TIME
N/A10:50 14.62 260 16.57 1572 5.26 3.2 337 6.33
N/A
10:45 14.62 260 16.62 1579 5.24 3.6 337 6.05 N/A
10:40 14.62 260 16.62 1598 5.24 3.9 339 5.95
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
3.33
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)12.62 WATER COLUMN (ft)20.39 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)743.94 WELL VOLUME
Target 240 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 8
26055 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)756.56 MIDDLE OF WETTED SCREEN (ft toc)25.51
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)33.01 GS ELEV (ft msl)753.62 PUMP INTAKE DEPTH (ft TOC)32.01
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)4-May-2016 WELL/LOCATION NAME BC-32
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
0.00 0.00
(psi)(sec)(sec)
(gal)
(ft)=(in)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)4-May-2016 WELL/LOCATION NAME BC-SW1
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
Surface Water Location PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE
SAMPLING EQUIPMENT GRAB PURGE METHOD
TUBING DIAMETER (in)No Purge
DETECTED ODOR CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)n/a WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
HET 5/4/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 20.77 573 6.93 6.7
1425
213 8.05
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)4-May-2016 WELL/LOCATION NAME BC-LEACHATE
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)No Purge
DETECTED ODOR CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
PSP, HET 5/4/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 16.58 2829 6.40 0.8
1015
330 6.66
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
PERMIT #
BC-7 BC-20 BC-21 BC-22 BC-23A BC-25 BC-26 BC-27 BC-28 BC-29 BC-30 BC-31 BC-32 BC-SW1
SEE NOTE SEE NOTE SEE NOTE SEE NOTE SEE NOTE SEE NOTE SEE NOTE SEE NOTE SEE NOTE SEE NOTE SEE NOTE SEE NOTE SEE NOTE SEE NOTE
SEE NOTE SEE NOTE SEE NOTE SEE NOTE SEE NOTE SEE NOTE SEE NOTE SEE NOTE SEE NOTE SEE NOTE SEE NOTE SEE NOTE SEE NOTE SEE NOTE
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A
YES YES YES YES YES YES YES YES YES YES YES YES N/A
YES
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A
N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A
Lacks required information - Total well depth
Lacks required information - Depth to screen
Lacks required information - Non potable tag
NOTE:Grass needed mowing into and around all locations.
Lacks required information - Completion date
FLUSH MOUNT WELLS
Vault in good condition
Water inside vault
Vault bolt holes broken or stripped
Bolts stripped
Vault lid cracked or broken
WELL ID TAGS
Well tag in good condition
Well tag missing
Well tag damaged / illegible
Lacks required information - Driller Reg #
Replaced damaged well cap
Fire ants around concrete pad
WELL PROTECTIVE CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
Broken hinge on protective lid
Wasp nest inside protective casing
Ants inside protective casing
WELL CAPS
Well cap in good conditon
Damaged / needs replacement
Undermined / washing out
Lock in good condition
Lock rusted, difficult to open / needs replacing
Replaced damaged lock
WELL CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
CONCRETE PADS
Pad in good condition
Minor cracks
Major cracks / broken / repair required
WELL LOCK CONDITION
PAGE 1 OF 1
ACCESS TO WELLS
Access cleared into well
Access cleared around well
Tall grass or weeds - needs mowing
Road washing out / muddy / needs grading
Fallen tree blocking access
WELL SECURITY
Well found locked
Well found unlocked
SITE CONTACT Melonie Martin, Kimberly Witt, Will Harrison, Keeley McCormick FIELD CREW LDC, PSP, HET
WEATHER Partly cloudy, slight breeze, 60 to 75 deg F.
NORTH CAROLINA GROUNDWATER SAMPLING SITE CHECKLIST
LOCATION / SITE BELEWS CREEK STEAM STATION - FGD LANDFILL GROUNDWATER MONITORING 85-05 SAMPLE DATE May 4, 2016
WELL DEPTH TO WATER Purge AVG *WELL EVAC SPECIFIC
WELL DEPTH WATER ELEV.Method PMP RATE VOL VOL EVAC TEMP CONDUCTANCE pH TURBIDITY ORP DODATENO.(feet-toc)(feet-toc)(feet)APPEARANCE ODOR (ml/min)(gal)(gal)(yes/no)(deg C)(umho/cm)(units)(NTU)(mV-NHE)(mg/l)
5/4/2016 BC-7 52.30 35.21 742.59 N/A N/A LO N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
5/4/2016 BC-20 24.22 11.72 745.50 Normal None LF 210 2.04 0.85 N/A 15.03 1010 5.2 4.6 368 8.54
5/4/2016 BC-21 16.77 9.58 747.11 Normal None LF 210 1.17 0.85 N/A 15.51 971 4.8 4.1 355 7.89
5/4/2016 BC-22 13.00 2.87 763.04 Normal None C N/A 1.65 5.25 NO 14.24 427 5.3 4.4 332 4.50
5/4/2016 BC-23A 101.21 80.11 783.68 Normal None C N/A 3.44 7.50 NO 15.09 44 5.7 13.9 292 8.11
5/4/2016 BC-25 26.15 12.90 735.53 Normal None LF 232 2.16 1.95 N/A 18.41 1707 5.4 47.6 440 4.42
5/4/2016 BC-26 23.26 14.28 735.04 Normal None LF 300 1.46 4.05 N/A 15.63 155 4.8 4.7 477 3.42
5/4/2016 BC-27 38.33 33.21 731.57 Normal None LF 162 0.84 1.35 N/A 17.29 193 5.7 2.5 244 1.58
5/4/2016 BC-28 60.20 50.79 767.30 Normal None LF 150 1.53 0.65 N/A 16.26 58 5.6 8.4 301 6.95
5/4/2016 BC-29 25.32 17.66 738.54 Normal None LF 171 1.25 1.50 N/A 15.33 256 4.9 6.5 413 1.82
5/4/2016 BC-30 34.10 24.69 751.03 Normal None LF 198 1.53 3.35 N/A 14.55 66 4.5 22.9 381 7.05
5/4/2016 BC-31 83.30 60.27 756.13 Normal None LF 130 3.76 1.15 N/A 15.86 109 5.9 3.5 265 4.40
5/4/2016 BC-32 33.01 12.62 743.94 Normal None LF 260 3.33 1.20 N/A 16.57 1572 5.3 3.2 337 6.33
5/4/2016 BC-SW1 0.00 N/A N/A Normal N/A NP N/A N/A N/A N/A 20.77 573 6.9 6.7 213 8.05
5/4/2016 BC-LEACHATE 0.00 N/A N/A Normal N/A NP N/A N/A N/A N/A 16.58 2829 6.4 0.8 330 6.66
Purge Methods
LF = Low Flow
LF(M) = Low Flow (Mod.)
C = Connventional
NP = No Purge
EOP = Equip. Only Purge
LO = Level Only
* = Applicable to LF & LF(M) Purging Only
BELEWS CREEK STEAM STATION
FGD LANDFILL GROUNDWATER
GROUNDWATER MONITORING FIELD DATA
PERMIT #85-05

B
Appendix B
Laboratory Report and
Chain-of-Custody Forms

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16040356
Project Name:BELEWS - GW FGD LF
Lab Contact:Peggy Kendall
Date:5/20/2016
Customer Address:3195 Pine Hall Rd
Customer Name(s):Chuck Campbell, T. Hunsucker, Ed Sullivan
Mailcode: Belews Steam Station
Belews Creek, NC 28012
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Peggy Kendall
Page 1 of 28
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016010486 BELEWS 04-May-16 12:45 PM LDC BC-20
2016010487 BELEWS 04-May-16 12:05 PM LDC BC-21
2016010488 BELEWS 04-May-16 11:30 AM LDC BC-22
2016010489 BELEWS 04-May-16 8:25 AM LDC BC-23A
2016010490 BELEWS 04-May-16 1:35 PM HET BC-25
2016010491 BELEWS 04-May-16 12:35 PM HET BC-26
2016010492 BELEWS 04-May-16 11:20 AM HET BC-27
2016010493 BELEWS 04-May-16 10:05 AM LDC BC-28
2016010494 BELEWS 04-May-16 9:45 AM HET BC-29
2016010495 BELEWS 04-May-16 8:45 AM HET BC-30
2016010496 BELEWS 04-May-16 9:20 AM LDC BC-31
2016010497 BELEWS 04-May-16 10:55 AM LDC BC-32
2016010498 BELEWS 04-May-16 2:35 PM HET SW-1
2016010499 BELEWS 04-May-16 10:15 AM PSP, HET LEACHATE
2016010500 BELEWS 04-May-16 2:45 PM HET FIELD BLANK
15 Total Samples
Page 2 of 28
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Peggy Kendall Date:5/20/2016
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040356
2016010486
Collection Date:04-May-16 12:45 PM
Site:BC-20
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)5.4 mg/L
(CaCO3)
SM 2320B 05/07/2016 08:28 CJELLIO51
INORGANIC IONS BY IC
Chloride 4.2 mg/L EPA 9056A 05/05/2016 16:29 BGN90340.5 5
Fluoride < 0.5 mg/L EPA 9056A 05/05/2016 16:29 BGN90340.5 5
Nitrate 11 mg/L EPA 9056A 05/05/2016 16:29 BGN90340.5 5
Nitrate as N 2.4 mg-N/L EPA 9056A 05/05/2016 16:29 BGN90340.023 1
Sulfate 540 mg/L EPA 9056A 05/05/2016 16:29 BGN903410100
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 05/09/2016 13:07 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.054 mg/L SW 6010D 05/17/2016 10:27 JJMACKE0.005 1
Boron (B)0.088 mg/L SW 6010D 05/17/2016 10:27 JJMACKE0.05 1
Calcium (Ca)123 mg/L SW 6010D 05/17/2016 10:27 JJMACKE1100
Chromium (Cr)< 0.005 mg/L SW 6010D 05/17/2016 10:27 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/17/2016 10:27 JJMACKE0.005 1
Iron (Fe)0.064 mg/L SW 6010D 05/17/2016 10:27 JJMACKE0.01 1
Magnesium (Mg)51.5 mg/L SW 6010D 05/17/2016 10:27 JJMACKE0.05 10
Manganese (Mn)0.016 mg/L SW 6010D 05/17/2016 10:27 JJMACKE0.005 1
Nickel (Ni)0.014 mg/L SW 6010D 05/17/2016 10:27 JJMACKE0.005 1
Potassium (K)5.98 mg/L SW 6010D 05/17/2016 10:27 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/17/2016 10:27 JJMACKE0.005 1
Sodium (Na)24.0 mg/L SW 6010D 05/17/2016 10:27 JJMACKE0.05 1
Zinc (Zn)0.018 mg/L SW 6010D 05/17/2016 10:27 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 05/18/2016 16:09 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 05/18/2016 16:09 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 05/18/2016 16:09 JAHERMA11
Selenium (Se)3.96 ug/L SW 6020B 05/18/2016 16:09 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 820 mg/L SM2540C 05/06/2016 15:23 CJELLIO251
Page 4 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040356
2016010487
Collection Date:04-May-16 12:05 PM
Site:BC-21
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 05/07/2016 08:28 CJELLIO51
INORGANIC IONS BY IC
Chloride 6.8 mg/L EPA 9056A 05/05/2016 16:45 BGN90340.5 5
Fluoride < 0.5 mg/L EPA 9056A 05/05/2016 16:45 BGN90340.5 5
Nitrate 16 mg/L EPA 9056A 05/05/2016 16:45 BGN90340.5 5
Nitrate as N 3.5 mg-N/L EPA 9056A 05/05/2016 16:45 BGN90340.023 1
Sulfate 500 mg/L EPA 9056A 05/05/2016 16:45 BGN903410100
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 05/09/2016 12:50 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.026 mg/L SW 6010D 05/17/2016 10:15 JJMACKE0.005 1
Boron (B)0.090 mg/L SW 6010D 05/17/2016 10:15 JJMACKE0.05 1
Calcium (Ca)45.2 mg/L SW 6010D 05/17/2016 10:15 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 05/17/2016 10:15 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/17/2016 10:15 JJMACKE0.005 1
Iron (Fe)0.043 mg/L SW 6010D 05/17/2016 10:15 JJMACKE0.01 1
Magnesium (Mg)93.5 mg/L SW 6010D 05/17/2016 10:15 JJMACKE0.05 10
Manganese (Mn)0.315 mg/L SW 6010D 05/17/2016 10:15 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 05/17/2016 10:15 JJMACKE0.005 1
Potassium (K)4.82 mg/L SW 6010D 05/17/2016 10:15 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/17/2016 10:15 JJMACKE0.005 1
Sodium (Na)22.6 mg/L SW 6010D 05/17/2016 10:15 JJMACKE0.05 1
Zinc (Zn)0.010 mg/L SW 6010D 05/17/2016 10:15 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)4.00 ug/L SW 6020B 05/18/2016 16:26 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 05/18/2016 16:26 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 05/18/2016 16:26 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 05/18/2016 16:26 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 780 mg/L SM2540C 05/06/2016 15:23 CJELLIO251
Page 5 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040356
2016010488
Collection Date:04-May-16 11:30 AM
Site:BC-22
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)17 mg/L
(CaCO3)
SM 2320B 05/07/2016 08:28 CJELLIO51
INORGANIC IONS BY IC
Chloride 4.0 mg/L EPA 9056A 05/05/2016 13:53 BGN90340.5 5
Fluoride < 0.5 mg/L EPA 9056A 05/05/2016 13:53 BGN90340.5 5
Nitrate 5.0 mg/L EPA 9056A 05/05/2016 13:53 BGN90340.5 5
Nitrate as N 1.1 mg-N/L EPA 9056A 05/05/2016 13:53 BGN90340.023 1
Sulfate 160 mg/L EPA 9056A 05/05/2016 13:53 BGN9034550
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 05/09/2016 12:52 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.165 mg/L SW 6010D 05/17/2016 10:31 JJMACKE0.005 1
Boron (B)0.075 mg/L SW 6010D 05/17/2016 10:31 JJMACKE0.05 1
Calcium (Ca)37.9 mg/L SW 6010D 05/17/2016 10:31 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 05/17/2016 10:31 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/17/2016 10:31 JJMACKE0.005 1
Iron (Fe)0.067 mg/L SW 6010D 05/17/2016 10:31 JJMACKE0.01 1
Magnesium (Mg)16.1 mg/L SW 6010D 05/17/2016 10:31 JJMACKE0.005 1
Manganese (Mn)0.192 mg/L SW 6010D 05/17/2016 10:31 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 05/17/2016 10:31 JJMACKE0.005 1
Potassium (K)3.15 mg/L SW 6010D 05/17/2016 10:31 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/17/2016 10:31 JJMACKE0.005 1
Sodium (Na)10.9 mg/L SW 6010D 05/17/2016 10:31 JJMACKE0.05 1
Zinc (Zn)0.016 mg/L SW 6010D 05/17/2016 10:31 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 05/18/2016 16:50 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 05/18/2016 16:50 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 05/18/2016 16:50 JAHERMA11
Selenium (Se)1.37 ug/L SW 6020B 05/18/2016 16:50 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 290 mg/L SM2540C 05/06/2016 15:23 CJELLIO251
Page 6 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040356
2016010489
Collection Date:04-May-16 8:25 AM
Site:BC-23A
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)17 mg/L
(CaCO3)
SM 2320B 05/07/2016 08:28 CJELLIO51
INORGANIC IONS BY IC
Chloride 2.2 mg/L EPA 9056A 05/05/2016 13:38 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 05/05/2016 13:38 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 05/05/2016 13:38 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 05/05/2016 13:38 BGN90340.023 1
Sulfate 0.27 mg/L EPA 9056A 05/05/2016 13:38 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 05/09/2016 12:54 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.035 mg/L SW 6010D 05/17/2016 10:35 JJMACKE0.005 1
Boron (B)0.081 mg/L SW 6010D 05/17/2016 10:35 JJMACKE0.05 1
Calcium (Ca)1.71 mg/L SW 6010D 05/17/2016 10:35 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 05/17/2016 10:35 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/17/2016 10:35 JJMACKE0.005 1
Iron (Fe)0.318 mg/L SW 6010D 05/17/2016 10:35 JJMACKE0.01 1
Magnesium (Mg)0.898 mg/L SW 6010D 05/17/2016 10:35 JJMACKE0.005 1
Manganese (Mn)0.007 mg/L SW 6010D 05/17/2016 10:35 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 05/17/2016 10:35 JJMACKE0.005 1
Potassium (K)1.54 mg/L SW 6010D 05/17/2016 10:35 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/17/2016 10:35 JJMACKE0.005 1
Sodium (Na)6.16 mg/L SW 6010D 05/17/2016 10:35 JJMACKE0.05 1
Zinc (Zn)0.010 mg/L SW 6010D 05/17/2016 10:35 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 05/18/2016 16:55 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 05/18/2016 16:55 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 05/18/2016 16:55 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 05/18/2016 16:55 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 51 mg/L SM2540C 05/06/2016 15:23 CJELLIO251
Page 7 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040356
2016010490
Collection Date:04-May-16 1:35 PM
Site:BC-25
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)18 mg/L
(CaCO3)
SM 2320B 05/07/2016 08:28 CJELLIO51
INORGANIC IONS BY IC
Chloride 44 mg/L EPA 9056A 05/05/2016 17:00 BGN9034110
Fluoride < 1 mg/L EPA 9056A 05/05/2016 17:00 BGN9034110
Nitrate 10 mg/L EPA 9056A 05/05/2016 17:00 BGN9034110
Nitrate as N 2.3 mg-N/L EPA 9056A 05/05/2016 17:00 BGN90340.023 1
Sulfate 1000 mg/L EPA 9056A 05/05/2016 17:00 BGN903420200
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 05/09/2016 12:57 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.069 mg/L SW 6010D 05/17/2016 10:38 JJMACKE0.005 1
Boron (B)0.109 mg/L SW 6010D 05/17/2016 10:38 JJMACKE0.05 1
Calcium (Ca)240 mg/L SW 6010D 05/17/2016 10:38 JJMACKE0.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 05/17/2016 10:38 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/17/2016 10:38 JJMACKE0.005 1
Iron (Fe)2.82 mg/L SW 6010D 05/17/2016 10:38 JJMACKE0.01 1
Magnesium (Mg)102 mg/L SW 6010D 05/17/2016 10:38 JJMACKE0.05 10
Manganese (Mn)0.106 mg/L SW 6010D 05/17/2016 10:38 JJMACKE0.005 1
Nickel (Ni)0.030 mg/L SW 6010D 05/17/2016 10:38 JJMACKE0.005 1
Potassium (K)8.88 mg/L SW 6010D 05/17/2016 10:38 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/17/2016 10:38 JJMACKE0.005 1
Sodium (Na)29.7 mg/L SW 6010D 05/17/2016 10:38 JJMACKE0.05 1
Zinc (Zn)0.018 mg/L SW 6010D 05/17/2016 10:38 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 05/18/2016 17:01 JAHERMA11
Cadmium (Cd)1.14 ug/L SW 6020B 05/18/2016 17:01 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 05/18/2016 17:01 JAHERMA11
Selenium (Se)12.4 ug/L SW 6020B 05/18/2016 17:01 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 1600 mg/L SM2540C 05/06/2016 15:23 CJELLIO251
Page 8 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040356
2016010491
Collection Date:04-May-16 12:35 PM
Site:BC-26
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 05/07/2016 08:28 CJELLIO51
INORGANIC IONS BY IC
Chloride 19 mg/L EPA 9056A 05/05/2016 16:13 BGN90340.5 5
Fluoride < 0.1 mg/L EPA 9056A 05/05/2016 16:13 BGN90340.1 1
Nitrate 28 mg/L EPA 9056A 05/05/2016 16:13 BGN90340.5 5
Nitrate as N 6.3 mg-N/L EPA 9056A 05/05/2016 16:13 BGN90340.023 1
Sulfate 14 mg/L EPA 9056A 05/05/2016 16:13 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 05/09/2016 13:14 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.347 mg/L SW 6010D 05/17/2016 10:42 JJMACKE0.005 1
Boron (B)0.068 mg/L SW 6010D 05/17/2016 10:42 JJMACKE0.05 1
Calcium (Ca)2.30 mg/L SW 6010D 05/17/2016 10:42 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 05/17/2016 10:42 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/17/2016 10:42 JJMACKE0.005 1
Iron (Fe)0.086 mg/L SW 6010D 05/17/2016 10:42 JJMACKE0.01 1
Magnesium (Mg)7.71 mg/L SW 6010D 05/17/2016 10:42 JJMACKE0.005 1
Manganese (Mn)0.034 mg/L SW 6010D 05/17/2016 10:42 JJMACKE0.005 1
Nickel (Ni)0.008 mg/L SW 6010D 05/17/2016 10:42 JJMACKE0.005 1
Potassium (K)4.43 mg/L SW 6010D 05/17/2016 10:42 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/17/2016 10:42 JJMACKE0.005 1
Sodium (Na)10.7 mg/L SW 6010D 05/17/2016 10:42 JJMACKE0.05 1
Zinc (Zn)0.062 mg/L SW 6010D 05/17/2016 10:42 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 05/18/2016 17:07 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 05/18/2016 17:07 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 05/18/2016 17:07 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 05/18/2016 17:07 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 100 mg/L SM2540C 05/06/2016 15:23 CJELLIO251
Page 9 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040356
2016010492
Collection Date:04-May-16 11:20 AM
Site:BC-27
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)71 mg/L
(CaCO3)
SM 2320B 05/06/2016 08:25 CJELLIO201
INORGANIC IONS BY IC
Chloride 10 mg/L EPA 9056A 05/05/2016 15:41 BGN90340.2 2
Fluoride < 0.1 mg/L EPA 9056A 05/05/2016 15:41 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 05/05/2016 15:41 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 05/05/2016 15:41 BGN90340.023 1
Sulfate 3.8 mg/L EPA 9056A 05/05/2016 15:41 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 05/13/2016 13:30 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.020 mg/L SW 6010D 05/17/2016 11:01 JJMACKE0.005 1
Boron (B)0.071 mg/L SW 6010D 05/17/2016 11:01 JJMACKE0.05 1
Calcium (Ca)1.29 mg/L SW 6010D 05/17/2016 11:01 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 05/17/2016 11:01 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/17/2016 11:01 JJMACKE0.005 1
Iron (Fe)34.5 mg/L SW 6010D 05/17/2016 11:01 JJMACKE0.01 1
Magnesium (Mg)4.84 mg/L SW 6010D 05/17/2016 11:01 JJMACKE0.005 1
Manganese (Mn)1.20 mg/L SW 6010D 05/17/2016 11:01 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 05/17/2016 11:01 JJMACKE0.005 1
Potassium (K)1.64 mg/L SW 6010D 05/17/2016 11:01 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/17/2016 11:01 JJMACKE0.005 1
Sodium (Na)6.88 mg/L SW 6010D 05/17/2016 11:01 JJMACKE0.05 1
Zinc (Zn)0.046 mg/L SW 6010D 05/17/2016 11:01 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)1.56 ug/L SW 6020B 05/18/2016 17:13 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 05/18/2016 17:13 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 05/18/2016 17:13 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 05/18/2016 17:13 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 100 mg/L SM2540C 05/06/2016 15:23 CJELLIO251
Page 10 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040356
2016010493
Collection Date:04-May-16 10:05 AM
Site:BC-28
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)22 mg/L
(CaCO3)
SM 2320B 05/06/2016 08:25 CJELLIO201
INORGANIC IONS BY IC
Chloride 1.7 mg/L EPA 9056A 05/05/2016 14:55 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 05/05/2016 14:55 BGN90340.1 1
Nitrate 4.3 mg/L EPA 9056A 05/05/2016 14:55 BGN90340.1 1
Nitrate as N 0.97 mg-N/L EPA 9056A 05/05/2016 14:55 BGN90340.023 1
Sulfate 0.40 mg/L EPA 9056A 05/05/2016 14:55 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 05/09/2016 13:16 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.032 mg/L SW 6010D 05/17/2016 11:05 JJMACKE0.005 1
Boron (B)0.074 mg/L SW 6010D 05/17/2016 11:05 JJMACKE0.05 1
Calcium (Ca)4.14 mg/L SW 6010D 05/17/2016 11:05 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 05/17/2016 11:05 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/17/2016 11:05 JJMACKE0.005 1
Iron (Fe)0.344 mg/L SW 6010D 05/17/2016 11:05 JJMACKE0.01 1
Magnesium (Mg)1.38 mg/L SW 6010D 05/17/2016 11:05 JJMACKE0.005 1
Manganese (Mn)0.010 mg/L SW 6010D 05/17/2016 11:05 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 05/17/2016 11:05 JJMACKE0.005 1
Potassium (K)2.18 mg/L SW 6010D 05/17/2016 11:05 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/17/2016 11:05 JJMACKE0.005 1
Sodium (Na)5.10 mg/L SW 6010D 05/17/2016 11:05 JJMACKE0.05 1
Zinc (Zn)0.025 mg/L SW 6010D 05/17/2016 11:05 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 05/18/2016 17:19 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 05/18/2016 17:19 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 05/18/2016 17:19 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 05/18/2016 17:19 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 70 mg/L SM2540C 05/06/2016 15:23 CJELLIO251
Page 11 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040356
2016010494
Collection Date:04-May-16 9:45 AM
Site:BC-29
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)7.0 mg/L
(CaCO3)
SM 2320B 05/07/2016 08:28 CJELLIO51
INORGANIC IONS BY IC
Chloride 3.6 mg/L EPA 9056A 05/06/2016 09:34 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 05/06/2016 09:34 BGN90340.1 1
Nitrate 1.2 mg/L EPA 9056A 05/06/2016 09:34 BGN90340.1 1
Nitrate as N 0.28 mg-N/L EPA 9056A 05/06/2016 09:34 BGN90340.023 1
Sulfate 100 mg/L EPA 9056A 05/06/2016 09:34 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 05/09/2016 13:19 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.079 mg/L SW 6010D 05/17/2016 11:09 JJMACKE0.005 1
Boron (B)0.076 mg/L SW 6010D 05/17/2016 11:09 JJMACKE0.05 1
Calcium (Ca)4.76 mg/L SW 6010D 05/17/2016 11:09 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 05/17/2016 11:09 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/17/2016 11:09 JJMACKE0.005 1
Iron (Fe)0.328 mg/L SW 6010D 05/17/2016 11:09 JJMACKE0.01 1
Magnesium (Mg)23.5 mg/L SW 6010D 05/17/2016 11:09 JJMACKE0.05 10
Manganese (Mn)0.584 mg/L SW 6010D 05/17/2016 11:09 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 05/17/2016 11:09 JJMACKE0.005 1
Potassium (K)2.38 mg/L SW 6010D 05/17/2016 11:09 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/17/2016 11:09 JJMACKE0.005 1
Sodium (Na)4.18 mg/L SW 6010D 05/17/2016 11:09 JJMACKE0.05 1
Zinc (Zn)0.017 mg/L SW 6010D 05/17/2016 11:09 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 05/18/2016 17:24 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 05/18/2016 17:24 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 05/18/2016 17:24 JAHERMA11
Selenium (Se)1.90 ug/L SW 6020B 05/18/2016 17:24 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 170 mg/L SM2540C 05/06/2016 15:23 CJELLIO251
Page 12 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040356
2016010495
Collection Date:04-May-16 8:45 AM
Site:BC-30
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)19 mg/L
(CaCO3)
SM 2320B 05/07/2016 08:28 CJELLIO51
INORGANIC IONS BY IC
Chloride 4.4 mg/L EPA 9056A 05/05/2016 15:26 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 05/05/2016 15:26 BGN90340.1 1
Nitrate 5.3 mg/L EPA 9056A 05/05/2016 15:26 BGN90340.1 1
Nitrate as N 1.2 mg-N/L EPA 9056A 05/05/2016 15:26 BGN90340.023 1
Sulfate 1.3 mg/L EPA 9056A 05/05/2016 15:26 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 05/09/2016 13:21 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.023 mg/L SW 6010D 05/17/2016 11:13 JJMACKE0.005 1
Boron (B)0.077 mg/L SW 6010D 05/17/2016 11:13 JJMACKE0.05 1
Calcium (Ca)3.44 mg/L SW 6010D 05/17/2016 11:13 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 05/17/2016 11:13 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/17/2016 11:13 JJMACKE0.005 1
Iron (Fe)1.01 mg/L SW 6010D 05/17/2016 11:13 JJMACKE0.01 1
Magnesium (Mg)1.67 mg/L SW 6010D 05/17/2016 11:13 JJMACKE0.005 1
Manganese (Mn)0.024 mg/L SW 6010D 05/17/2016 11:13 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 05/17/2016 11:13 JJMACKE0.005 1
Potassium (K)1.25 mg/L SW 6010D 05/17/2016 11:13 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/17/2016 11:13 JJMACKE0.005 1
Sodium (Na)7.88 mg/L SW 6010D 05/17/2016 11:13 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 05/17/2016 11:13 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 05/18/2016 17:30 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 05/18/2016 17:30 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 05/18/2016 17:30 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 05/18/2016 17:30 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 74 mg/L SM2540C 05/06/2016 15:23 CJELLIO251
Page 13 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040356
2016010496
Collection Date:04-May-16 9:20 AM
Site:BC-31
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)50 mg/L
(CaCO3)
SM 2320B 05/06/2016 08:25 CJELLIO201
INORGANIC IONS BY IC
Chloride 1.9 mg/L EPA 9056A 05/05/2016 18:17 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 05/05/2016 18:17 BGN90340.1 1
Nitrate 3.4 mg/L EPA 9056A 05/05/2016 18:17 BGN90340.1 1
Nitrate as N 0.77 mg-N/L EPA 9056A 05/05/2016 18:17 BGN90340.023 1
Sulfate 1.1 mg/L EPA 9056A 05/05/2016 18:17 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 05/09/2016 13:24 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.017 mg/L SW 6010D 05/17/2016 11:16 JJMACKE0.005 1
Boron (B)0.066 mg/L SW 6010D 05/17/2016 11:16 JJMACKE0.05 1
Calcium (Ca)8.23 mg/L SW 6010D 05/17/2016 11:16 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 05/17/2016 11:16 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/17/2016 11:16 JJMACKE0.005 1
Iron (Fe)0.089 mg/L SW 6010D 05/17/2016 11:16 JJMACKE0.01 1
Magnesium (Mg)4.23 mg/L SW 6010D 05/17/2016 11:16 JJMACKE0.005 1
Manganese (Mn)0.012 mg/L SW 6010D 05/17/2016 11:16 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 05/17/2016 11:16 JJMACKE0.005 1
Potassium (K)1.68 mg/L SW 6010D 05/17/2016 11:16 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/17/2016 11:16 JJMACKE0.005 1
Sodium (Na)8.14 mg/L SW 6010D 05/17/2016 11:16 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 05/17/2016 11:16 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 05/18/2016 17:36 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 05/18/2016 17:36 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 05/18/2016 17:36 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 05/18/2016 17:36 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 81 mg/L SM2540C 05/06/2016 15:23 CJELLIO251
Page 14 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040356
2016010497
Collection Date:04-May-16 10:55 AM
Site:BC-32
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)13 mg/L
(CaCO3)
SM 2320B 05/07/2016 08:28 CJELLIO51
INORGANIC IONS BY IC
Chloride 2.4 mg/L EPA 9056A 05/05/2016 20:05 BGN90340.5 5
Fluoride < 0.5 mg/L EPA 9056A 05/05/2016 20:05 BGN90340.5 5
Nitrate 2.7 mg/L EPA 9056A 05/05/2016 20:05 BGN90340.5 5
Nitrate as N 0.60 mg-N/L EPA 9056A 05/05/2016 20:05 BGN90340.023 1
Sulfate 950 mg/L EPA 9056A 05/05/2016 20:05 BGN903420200
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 05/09/2016 13:26 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.055 mg/L SW 6010D 05/17/2016 11:20 JJMACKE0.005 1
Boron (B)0.089 mg/L SW 6010D 05/17/2016 11:20 JJMACKE0.05 1
Calcium (Ca)181 mg/L SW 6010D 05/17/2016 11:20 JJMACKE0.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 05/17/2016 11:20 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/17/2016 11:20 JJMACKE0.005 1
Iron (Fe)0.028 mg/L SW 6010D 05/17/2016 11:20 JJMACKE0.01 1
Magnesium (Mg)118 mg/L SW 6010D 05/17/2016 11:20 JJMACKE0.05 10
Manganese (Mn)0.017 mg/L SW 6010D 05/17/2016 11:20 JJMACKE0.005 1
Nickel (Ni)0.018 mg/L SW 6010D 05/17/2016 11:20 JJMACKE0.005 1
Potassium (K)7.23 mg/L SW 6010D 05/17/2016 11:20 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/17/2016 11:20 JJMACKE0.005 1
Sodium (Na)29.5 mg/L SW 6010D 05/17/2016 11:20 JJMACKE0.05 1
Zinc (Zn)0.040 mg/L SW 6010D 05/17/2016 11:20 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 05/18/2016 17:42 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 05/18/2016 17:42 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 05/18/2016 17:42 JAHERMA11
Selenium (Se)5.78 ug/L SW 6020B 05/18/2016 17:42 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 1400 mg/L SM2540C 05/06/2016 15:23 CJELLIO251
Page 15 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040356
2016010498
Collection Date:04-May-16 2:35 PM
Site:SW-1
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)25 mg/L
(CaCO3)
SM 2320B 05/06/2016 08:25 CJELLIO201
INORGANIC IONS BY IC
Chloride 0.94 mg/L EPA 9056A 05/06/2016 09:50 BGN90340.2 2
Fluoride 0.22 mg/L EPA 9056A 05/06/2016 09:50 BGN90340.2 2
Nitrate 0.29 mg/L EPA 9056A 05/06/2016 09:50 BGN90340.2 2
Nitrate as N 0.07 mg-N/L EPA 9056A 05/06/2016 09:50 BGN90340.023 1
Sulfate 270 mg/L EPA 9056A 05/06/2016 09:50 BGN9034550
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 05/09/2016 13:28 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.091 mg/L SW 6010D 05/17/2016 11:24 JJMACKE0.005 1
Boron (B)0.079 mg/L SW 6010D 05/17/2016 11:24 JJMACKE0.05 1
Calcium (Ca)110 mg/L SW 6010D 05/17/2016 11:24 JJMACKE0.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 05/17/2016 11:24 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/17/2016 11:24 JJMACKE0.005 1
Iron (Fe)3.09 mg/L SW 6010D 05/17/2016 11:24 JJMACKE0.01 1
Magnesium (Mg)4.99 mg/L SW 6010D 05/17/2016 11:24 JJMACKE0.005 1
Manganese (Mn)3.57 mg/L SW 6010D 05/17/2016 11:24 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 05/17/2016 11:24 JJMACKE0.005 1
Potassium (K)3.81 mg/L SW 6010D 05/17/2016 11:24 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/17/2016 11:24 JJMACKE0.005 1
Sodium (Na)1.46 mg/L SW 6010D 05/17/2016 11:24 JJMACKE0.05 1
Zinc (Zn)0.056 mg/L SW 6010D 05/17/2016 11:24 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 05/18/2016 18:05 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 05/18/2016 18:05 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 05/18/2016 18:05 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 05/18/2016 18:05 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 430 mg/L SM2540C 05/06/2016 15:23 CJELLIO251
Page 16 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040356
2016010499
Collection Date:04-May-16 10:15 AM
Site:LEACHATE
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)240 mg/L
(CaCO3)
SM 2320B 05/06/2016 08:25 CJELLIO201
INORGANIC IONS BY IC
Chloride 100 mg/L EPA 9056A 05/05/2016 20:20 BGN90342.5 25
Fluoride < 2.5 mg/L EPA 9056A 05/05/2016 20:20 BGN90342.5 25
Nitrate 4.8 mg/L EPA 9056A 05/05/2016 20:20 BGN90342.5 25
Nitrate as N 1.1 mg-N/L EPA 9056A 05/05/2016 20:20 BGN90340.023 1
Sulfate 1600 mg/L EPA 9056A 05/05/2016 20:20 BGN903450500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 05/09/2016 13:31 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.018 mg/L SW 6010D 05/17/2016 11:28 JJMACKE0.005 1
Boron (B)6.50 mg/L SW 6010D 05/17/2016 11:28 JJMACKE0.05 1
Calcium (Ca)657 mg/L SW 6010D 05/17/2016 11:28 JJMACKE0.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 05/17/2016 11:28 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/17/2016 11:28 JJMACKE0.005 1
Iron (Fe)0.073 mg/L SW 6010D 05/17/2016 11:28 JJMACKE0.01 1
Magnesium (Mg)82.3 mg/L SW 6010D 05/17/2016 11:28 JJMACKE0.05 10
Manganese (Mn)7.65 mg/L SW 6010D 05/17/2016 11:28 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 05/17/2016 11:28 JJMACKE0.005 1
Potassium (K)8.18 mg/L SW 6010D 05/17/2016 11:28 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/17/2016 11:28 JJMACKE0.005 1
Sodium (Na)6.76 mg/L SW 6010D 05/17/2016 11:28 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 05/17/2016 11:28 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 10 ug/L SW 6020B 05/18/2016 18:11 JAHERMA1010
Cadmium (Cd)< 10 ug/L SW 6020B 05/18/2016 18:11 JAHERMA1010
Lead (Pb)< 10 ug/L SW 6020B 05/18/2016 18:11 JAHERMA1010
Selenium (Se)2250 ug/L SW 6020B 05/18/2016 18:11 JAHERMA1010
TOTAL DISSOLVED SOLIDS
TDS 2200 mg/L SM2540C 05/06/2016 15:23 CJELLIO2501
Page 17 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040356
2016010500
Collection Date:04-May-16 2:45 PM
Site:FIELD BLANK
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 05/07/2016 08:28 CJELLIO51
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 9056A 05/05/2016 18:02 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 05/05/2016 18:02 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 05/05/2016 18:02 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 05/05/2016 18:02 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 05/05/2016 18:02 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 05/09/2016 13:33 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L SW 6010D 05/17/2016 11:32 JJMACKE0.005 1
Boron (B)0.070 mg/L SW 6010D 05/17/2016 11:32 JJMACKE0.05 1
Calcium (Ca)0.185 mg/L SW 6010D 05/17/2016 11:32 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 05/17/2016 11:32 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 05/17/2016 11:32 JJMACKE0.005 1
Iron (Fe)< 0.01 mg/L SW 6010D 05/17/2016 11:32 JJMACKE0.01 1
Magnesium (Mg)< 0.005 mg/L SW 6010D 05/17/2016 11:32 JJMACKE0.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 05/17/2016 11:32 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 05/17/2016 11:32 JJMACKE0.005 1
Potassium (K)< 0.1 mg/L SW 6010D 05/17/2016 11:32 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 05/17/2016 11:32 JJMACKE0.005 1
Sodium (Na)0.084 mg/L SW 6010D 05/17/2016 11:32 JJMACKE0.05 1
Zinc (Zn)0.018 mg/L SW 6010D 05/17/2016 11:32 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 05/18/2016 18:17 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 05/18/2016 18:17 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 05/18/2016 18:17 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 05/18/2016 18:17 JAHERMA11
Page 18 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040356
Q16050146 ALK_FIX4.5 ALKALINITY (FIXED END POINT 4.5)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16040356 -- 2016010492
Alkalinity (mg/L CaCO3)0.389mg/L
(CaCO3)
-171.4
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16050052 -- 2016012396
Alkalinity (mg/L CaCO3)0.182mg/L
(CaCO3)
-124.2
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3)44.3 106mg/L
(CaCO3)
-12080146.8
Page 19 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040356
Q16050149 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16040356 -- 2016010486
Alkalinity (mg/L CaCO3)2.43mg/L
(CaCO3)
-15.53
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3)11.08 91.4mg/L
(CaCO3)
-12080110.1
Page 20 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040356
Q16050092 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0448 mg/L -10.0448 0.1 < 1/2 RDL
Fluoride 0.037 mg/L -10.037 0.1 < 1/2 RDL
Nitrate 0.0355 mg/L -10.0355 0.1 < 1/2 RDL
Sulfate 0.0221 mg/L -10.0221 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 5.12 5 101mg/L -1208015.12
Fluoride 5.2 5 104mg/L -1208015.2
Nitrate 5.13 5 101mg/L -1208015.13
Sulfate 7.59 5 101mg/L -1208017.59
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 5.12 5 101 0.158mg/L -1208015.12
Fluoride 5.19 5 103 0.271mg/L -1208015.19
Nitrate 5.13 5 101 0.0277mg/L -1208015.13
Sulfate 7.58 5 101 0.113mg/L -1208017.58
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 6.98 5 101mg/L -1208016.98
Fluoride 5.47 5 107mg/L -1208015.47
Nitrate 8.56 5 103mg/L -1208018.56
Sulfate 6.29 5 103mg/L -1208016.29
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 6.93 5 100 0.913mg/L -1208016.93
Fluoride 5.46 5 107 0.257mg/L -1208015.46
Nitrate 8.55 5 103 0.219mg/L -1208018.55
Sulfate 6.3 5 103 0.175mg/L -1208016.3
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5 5 100mg/L -1208015
Fluoride 5.19 5 104mg/L -1208015.19
Nitrate 5.01 5 100mg/L -1208015.01
Sulfate 5.01 5 100mg/L -1208015.01
Page 21 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040356
Q16050170 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.006 ug/L -10.006 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) -0.01 ug/L -1-0.01 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 0.802 50 82.7ug/L -125755040.1
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.789 50 81.4 1.59ug/L -5039.5
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16040356 -- 2016010486
Mercury (Hg) 0.95 1 96.6ug/L -1257510.95
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16040356 -- 2016010486
Mercury (Hg) 0.95 1 96.6 0ug/L -1257510.95
Page 22 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040356
Q16050291 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.005 ug/L -10.005 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 0.918 100 94.8ug/L -1257510091.8
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.926 100 95.6 0.788ug/L -10092.6
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.01 2 100ug/L -1158512.01
Page 23 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040356
Q16050309 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) -0.000028 mg/L -1-0.000028 0.005 < 1/2 RDL
Boron (B) 0.00205 mg/L -10.00205 0.05 < 1/2 RDL
Calcium (Ca) 0.000731 mg/L -10.000731 0.01 < 1/2 RDL
Chromium (Cr) -0.000143 mg/L -1-0.000143 0.005 < 1/2 RDL
Copper (Cu) 0.000589 mg/L -10.000589 0.005 < 1/2 RDL
Iron (Fe) -0.000004 mg/L -1-0.000004 0.01 < 1/2 RDL
Magnesium (Mg) 0.000036 mg/L -10.000036 0.005 < 1/2 RDL
Manganese (Mn) 0.000099 mg/L -10.000099 0.005 < 1/2 RDL
Nickel (Ni) -0.00173 mg/L -1-0.00173 0.005 < 1/2 RDL
Potassium (K) -0.00643 mg/L -1-0.00643 0.1 < 1/2 RDL
Silver (Ag) 0.000136 mg/L -10.000136 0.005 < 1/2 RDL
Sodium (Na) -0.00345 mg/L -1-0.00345 0.05 < 1/2 RDL
Zinc (Zn) -0.000732 mg/L -1-0.000732 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 5.11 5 102mg/L -1208015.11
Boron (B) 5.09 5 102mg/L -1208015.09
Calcium (Ca) 4.92 5 98.3mg/L -1208014.92
Chromium (Cr) 5 5 100mg/L -1208015
Copper (Cu) 5.01 5 100mg/L -1208015.01
Iron (Fe) 4.95 5 99.1mg/L -1208014.95
Magnesium (Mg) 5.15 5 103mg/L -1208015.15
Manganese (Mn) 5.19 5 104mg/L -1208015.19
Nickel (Ni) 4.96 5 99.3mg/L -1208014.96
Potassium (K) 5.06 5 101mg/L -1208015.06
Silver (Ag) 0.518 0.5 104mg/L -1208010.518
Sodium (Na) 5.03 5 101mg/L -1208015.03
Zinc (Zn) 5.11 5 102mg/L -1208015.11
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16040356 -- 2016010487
Barium (Ba) 5.13 5 102mg/L -1257515.13
Boron (B) 5.21 5 102mg/L -1257515.21
Calcium (Ca) 49.8 5 93.2mg/L -12575149.8
Chromium (Cr) 4.97 5 99.5mg/L -1257514.97
Copper (Cu) 4.99 5 99.8mg/L -1257514.99
Iron (Fe) 5.04 5 100mg/L -1257515.04
Magnesium (Mg) 9.78 5 87.8mg/L -125751097.8
Manganese (Mn) 5.45 5 103mg/L -1257515.45
Page 24 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040356
Q16050309 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16040356 -- 2016010487
Nickel (Ni) 4.84 5 96.7mg/L -1257514.84
Potassium (K) 9.88 5 101mg/L -1257519.88
Silver (Ag) 0.505 0.5 101mg/L -1257510.505
Sodium (Na) 27.9 5 106mg/L -12575127.9
Zinc (Zn) 4.94 5 98.6mg/L -1257514.94
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16040356 -- 2016010487
Barium (Ba) 5.13 5 102 0.0392mg/L -1257515.13
Boron (B) 5.2 5 102 0.156mg/L -1257515.2
Calcium (Ca) 49.7 5 90.9 2.54mg/L -12575149.7
Chromium (Cr) 4.99 5 99.8 0.341mg/L -1257514.99
Copper (Cu) 5 5 100 0.28mg/L -1257515
Iron (Fe) 5.05 5 100 0.12mg/L -1257515.05
Magnesium (Mg) 9.8 5 90.4 2.95mg/L -125751098
Manganese (Mn) 5.48 5 103 0.602mg/L -1257515.48
Nickel (Ni) 4.85 5 97 0.268mg/L -1257514.85
Potassium (K) 9.89 5 101 0.158mg/L -1257519.89
Silver (Ag) 0.502 0.5 101 0.447mg/L -1257510.502
Sodium (Na) 27.8 5 104 1.77mg/L -12575127.8
Zinc (Zn) 4.97 5 99.2 0.647mg/L -1257514.97
Page 25 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040356
Q16050315 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As) 0.0159 ug/L -10.0159 1 < 1/2 RDL
Cadmium (Cd) 0.0018 ug/L -10.0018 1 < 1/2 RDL
Lead (Pb) -0.0021 ug/L -1-0.0021 1 < 1/2 RDL
Selenium (Se) -0.0092 ug/L -1-0.0092 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As) 51.6 50 103ug/L -12080151.6
Cadmium (Cd) 51.3 50 103ug/L -12080151.3
Lead (Pb) 51 50 102ug/L -12080151
Selenium (Se) 50.9 50 102ug/L -12080150.9
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16040356 -- 2016010486
Arsenic (As) 52.4 50 105ug/L -12080152.4
Arsenic (As) 52.4 50 105ug/L -12575152.4
Cadmium (Cd) 51 50 100ug/L -12575151
Cadmium (Cd) 51 50 100ug/L -12080151
Lead (Pb) 50.6 50 101ug/L -12080150.6
Lead (Pb) 50.6 50 101ug/L -12575150.6
Selenium (Se) 53.6 50 99.2ug/L -12575153.6
Selenium (Se) 53.6 50 99.2ug/L -12080153.6
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16040356 -- 2016010486
Arsenic (As) 52.8 50 105 0.628ug/L -12080152.8
Arsenic (As) 52.8 50 105 0.628ug/L -13070152.8
Cadmium (Cd) 51.1 50 100 0.169ug/L -12080151.1
Cadmium (Cd) 51.1 50 100 0.169ug/L -13070151.1
Lead (Pb) 50.5 50 101 0.365ug/L -12080150.5
Lead (Pb) 50.5 50 101 0.365ug/L -13070150.5
Selenium (Se) 53.1 50 98.3 0.938ug/L -13070153.1
Selenium (Se) 53.1 50 98.3 0.938ug/L -12080153.1
Page 26 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040356
Q16050131 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16040326 -- 2016010381
TDS 0.803mg/L -1125
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16040356 -- 2016010486
TDS 0.725mg/L -1831
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 97mg/L -11090197
Page 27 of 28
Page 28 of 28