7302_DukeRoxboro_April2016_1stSemiAnnual_DIN26535_20160729

SEMIANNUAL GROUNDWATER MONITORING
REPORT
APRIL 2016 SAMPLING EVENT
ROXBORO STEAM ELECTRIC PLANT
INDUSTRIAL WASTE LANDFILL
PERMIT NO. 7302
1700 DUNNAWAY ROAD
SEMORA, NORTH CAROLINA

JULY 2016
PREPARED FOR

DUKE ENERGY PROGRESS, LLC
Roxboro Semiannual Groundwater Monitoring Report – April 2016 Sampling Event July 2016
Duke Energy Progress, LLC SynTerra
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TABLE OF CONTENTS
SECTION PAGE
1.0 BACKGROUND............................................................................................................... 1
2.0 METHODS ........................................................................................................................ 3
2.1 Sampling and Analysis Methods ............................................................................... 3
2.2 Statement of Work ....................................................................................................... 3
3.0 RESULTS ........................................................................................................................... 5
3.1 Site Groundwater Flow ............................................................................................... 5
3.2 Analytical Results ........................................................................................................ 5
4.0 REFERENCES ................................................................................................................... 6

LIST OF FIGURES
Figure 1 Site Location Map
Figure 2 Sample Locations
Figure 3 Generalized Groundwater Surface Contours – April 6, 2016

LIST OF TABLES
Table 1 Well Construction Information
Table 2 Groundwater Flow Velocities – April 6, 2016
Table 3 Field Data Parameters
Table 4 Groundwater Field and Analytical Results
Table 5 Field and Analytical Results that Equal or Exceed 15A NCAC 2L
Groundwater Quality Standards
Table 6 Surface Water Field and Analytical Results
Table 7 Field and Analytical Results that Equal or Exceed 15A NCAC 2B Surface
Water Quality Standards
Table 8 Leachate Field and Analytical Results

LIST OF APPENDICES
Appendix A Field Sampling Forms
Appendix B Laboratory Report and Chain-of-Custody Forms
Roxboro Semiannual Groundwater Monitoring Report – April 2016 Sampling Event July 2016
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1.0 BACKGROUND
Roxboro Steam Electric Plant (Roxboro) is owned and operated by Duke Energy
Progress (Duke Energy). The Roxboro Plant generates electricity by the combustion of
coal. The plant is located on Hyco Lake in northeastern Person County near Semora,
North Carolina.
The Roxboro Industrial Waste Landfill and nearby area are portrayed on Figure 1. The
lined landfill is located to the east and southeast of the power plant and is constructed
over a former ash basin (the East Ash Pond), an unlined ash impoundment. The highest
topographic relief on the landfill site occurs along the eastern portion of the landfill.
The Roxboro Industrial Waste Landfill is a lined landfill permitted to receive coal
combustion by-products (CCBs) and incidental amounts of other wastes generated at
the Roxboro Steam Electric Plant and other Duke Energy plants. Over 90 percent of the
CCBs managed at the Roxboro Industrial Waste Landfill consist of fly ash, bottom ash,
and off-spec flue gas desulfurization (FGD) residue (gypsum). Other wastes include
plant sump sludges from cleanouts, coal pile runoff, pond sludge, coal mill rejects,
gypsum settling pond and flush pond sludge cleanout, cooling tower debris from
cleanouts, abrasive blast media, and leachate from the landfill site.
Phases 1-5 of the Roxboro landfill were constructed with an engineered liner system
and are contained within an area of approximately 70.4 acres. Phase 6 was constructed
with a double engineered liner system and is contained in an area of approximately 23.4
acres. Phase 1 initial waste placement began in 2004. Waste placement is currently
occurring in Phase 6.
Groundwater sampling is performed on a semi-annual basis. The sampling includes
measurement of groundwater field parameters and water levels as well as collection of
groundwater samples from six groundwater monitoring wells. Water levels are also
measured in two piezometers, and leachate samples are collected at six locations. As
described in the Water Quality Monitoring Plan (Attachment 6) contained in the Permit
to Construct Application, the monitoring system at the landfill consists of the following:
Monitoring Wells: GMW-6
GMW-7
GMW-8
GMW-9
GMW-10
GMW-11
Roxboro Semiannual Groundwater Monitoring Report – April 2016 Sampling Event July 2016
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Piezometers: PZ-12
PZ-14

Leachate Sample Locations:

LP-1
LP-2
LP-3
LP-4
LP-5
LP-6
The sampling locations are depicted on Figure 2. A summary of monitoring well
construction information is presented in Table 1. According to the Water Quality
Monitoring Plan, most of the groundwater monitoring system was in service in 2002
with the exceptions of PZ-14 which was installed in December 2009, and GMW-7 and
GMW-11 which were installed in 2010 and 2011, respectively, as replacement wells.
Monitoring well GMW-9 is identified as the upgradient background well in the Water
Quality Monitoring Plan.
Roxboro Semiannual Groundwater Monitoring Report – April 2016 Sampling Event July 2016
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2.0 METHODS
2.1 Sampling and Analysis Methods
The collection of samples and documentation of sampling was performed by SynTerra
Corporation (SynTerra) personnel (SynTerra Field Certification #5591) according to the
North Carolina Solid Waste Management Guidelines. Copies of the field sampling
forms are included in Appendix A. The parameters and constituents reported were
selected by Duke Energy and the NCDEQ Division of Solid Waste and were analyzed
by Duke Energy Analytical Laboratory (North Carolina Laboratory Certification #248).
The laboratory report and chain-of-custody forms are included in Appendix B.
The groundwater and leachate samples were analyzed for the following constituents:
Barium, boron, chromium, copper, iron, manganese, nickel, silver, and zinc
using U.S. Environmental Protection Agency (EPA) Method 200.7
Arsenic, cadmium, lead, thallium, and selenium using EPA Method 200.8
Chloride, fluoride, nitrate (as nitrogen), and sulfate using EPA Method 300.0
Mercury using EPA Method 245.1
Total dissolved solids using Standard Method (SM) 2540C
Total organic carbon, biochemical oxygen demand, and chemical oxygen demand were
historically sampled up until April 2015; these constituents are not currently required to
be analyzed in the WQMP and were not analyzed for during this sampling event.
2.2 Statement of Work
SynTerra completed the following tasks:
Conducted groundwater and leachate sampling at Roxboro landfill monitoring
wells, shipped samples to Duke Energy Laboratory, and submitted all field
data to Duke Energy.
Received April and July 2016 field sampling information (compiled by Duke
Energy and redistributed to SynTerra) for monitoring wells GMW-6, GMW-7,
GMW-8, GMW-9, GMW-10, and GMW-11. Depth to groundwater
measurements were also received for piezometers PZ-12 and PZ-14. Leachate
sample data was included for locations LP-1, LP-2, LP-3, LP-4, LP-5, and LP-6.
Groundwater and leachate samples were collected and depth to groundwater
Roxboro Semiannual Groundwater Monitoring Report – April 2016 Sampling Event July 2016
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in the piezometers measured on April 6, 2016; SynTerra received the data on
April 28, 2016 and July 26, 2016.
Reviewed the laboratory analytical results for the samples listed above. The
Electronic Data Deliverable (EDD) provided by Duke Energy was adapted to
conform to the format requirements of the NCDEQ EDD template. Copies of
the original EDDs are retained in SynTerra's files.
Developed generalized groundwater surface contour map using map data and
groundwater elevation data supplied by Duke Energy.
Calculated groundwater flow velocities based on groundwater elevations on
wells perpendicular to groundwater flow.
Prepared and submitted this Semiannual Groundwater Monitoring Report to
Duke Energy.
Roxboro Semiannual Groundwater Monitoring Report – April 2016 Sampling Event July 2016
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3.0 RESULTS
3.1 Site Groundwater Flow
Generalized groundwater surface contours and groundwater flow direction arrows for
the site are shown on Figure 3. These contours were developed using the groundwater
elevations measured on the date of sampling. Calculated flow velocities are presented
in Table 2.
Groundwater at the landfill flows north-northwest from areas of higher topography
located along the southern portion of the landfill.
3.2 Analytical Results
A summary of the field data is presented in Table 3. The field and analytical results of
groundwater samples collected from the monitoring wells are presented in Table 4. The
analytical results for these samples are compared to the groundwater standards
established in Title 15A NCAC 02L .0202 (g) (2L Standards). Concentrations that attain
or exceed the 2L Standards are noted in Table 4 by bold font. A summary of the field
and analytical results that attain or exceed the 2L Standards and a preliminary analysis
of the cause and significance of the exceedances are presented in Table 5.
The field and analytical results for leachate sampling are summarized in Table 6.
Concentrations with values that are equal to or greater than Solid Waste Section Limits
(SWSLs) are noted in Table 4 and Table 6 by gray shaded cells.
Select samples were diluted, as is normal laboratory practice, to bring samples within
the calibrated range of analysis. Specifics regarding the samples that were diluted,
including the dilution factor, are reported in the EDD and in the laboratory analytical
report. The laboratory analytical report is included as Appendix B.
Roxboro Semiannual Groundwater Monitoring Report – April 2016 Sampling Event July 2016
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4.0 REFERENCES
Golder Associates NC, Inc., Water Quality Monitoring Plan – Duke Energy Progress, Inc.,
Roxboro Industrial Waste Landfill, Permit No. 7302, March 2014.
Morris, Donald Arthur, and Arnold Ivan Johnson. Summary of hydrologic and physical
properties of rock and soil materials, as analyzed by the hydrologic laboratory of the US
Geological Survey, 1967, 1948-60. No. 1839-D. US Gov.
SynTerra. Comprehensive Site Assessment Report. September 2, 2015
Roxboro Semiannual Groundwater Monitoring Report – April 2016 Sampling Event July 2016
Duke Energy Progress, LLC SynTerra
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Monitoring\7302_20160406.docx
FIGURES

APPROXIMATE LANDFILLPHASE 1-5 LIMIT OF WASTE
APPROXIMATE LANDFILLPHASE 6 LIMIT OF WASTE
HYCORESERVOIR
ROXBORO STEAMELECTRIC PLANT
SHORE RDSTATE RD 1316
DUNNAWAY RD
S
TA
T
E R
D 1377
STATE HWY 57
SEMORA RD
S T A T E R D 1 3 3 6
M C G H E E S
M I L L R D
SCALE (FEET)1,000 0 1,000 2,000
PROJECT MANAGER: J. WYLIE
DRAWN BY: B. YOUNG
DATE: 07/27/2016
DATE: 07/27/2016
CHECKED BY: K. DONOVAN
P:\DUKE ENERGY PROGRESS.1026\00 GIS BASE DATA\ROXBORO\MAP_DOCS\STATE_COMPLIANCE\ROXBORO - FIGURE 1 - SITE_LOCATION_MAP.MXD
FIGURE 1SITE LOCATION MAPROXBORO STEAM ELECTRIC PLANTINDUSTRIAL WASTE LANDFILLPERMIT NO. 7302
"
148 RIVER STREET, SUITE 220GREENVILLE, SC 29601864-421-9999
LEGEND
LANDFILL BOUNDARY
&<
&<
&<
&<
&<
&<
#
#
#
#
&<
&<
##
##
APPROXIMATE LANDFILLPHASE 1-6 LIMIT OF WASTE
HYCO LAKE(Approx. Pond Elev = 410')FLY ASHSTRUCTURAL FILL
GMW-06
GMW-07
GMW-08 GMW-09
GMW-10
GMW-11
LP-01
LP-02
LP-03
LP-04
PZ-12
PZ-14
CL-02
CL-02S
LP-06
LP-05
SCALE (FEET)300 0 300 600
PROJECT MANAGER: J. WYLIE
DRAWN BY: B. YOUNG
DATE: 07/27/2016
DATE: 07/27/2016
CHECKED BY: K. DONOVAN
P:\DUKE ENERGY PROGRESS.1026\00 GIS BASE DATA\ROXBORO\MAP_DOCS\STATE_COMPLIANCE\ROXBORO - FIGURE 2 - SAMPLE_LOCATIONS.MXD
FIGURE 2SAMPLE LOCATIONSROXBORO STEAM ELECTRIC PLANTINDUSTRIAL WASTE LANDFILLPERMIT NO. 7302
"
148 RIVER STREET, SUITE 220GREENVILLE, SC 29601864-421-9999
NOTES:1 10ft CONTOUR INTERVALS FROM NCDOT LIDAR DATED 2007https://connect.ncdot.gov/resources/gis/pages/cont-elev_v2.aspx
2 CONTOUR LINES ARE USED FOR REPRESENTATIVE PURPOSES ONLY ANDARE NOT TO BE USED FOR DESIGN OR CONSTRUCTION PURPOSES.
3 2014 AERIAL ORTHOPHOTOGRAPHY OBTAINED FROM USDA NRCSGEOSPATIAL DATA GATEWAY (https://gdg.sc.egov.usda.gov/GDGOrder.aspx).
&<GROUNDWATER MONITORING WELL
&<PIEZOMETER (WATER ELEVATION ONLY)
#LEACHATE SAMPLING LOCATION
APPROXIMATE LINED LANDFILL LIMIT OF WASTE
APPROXIMATE UNLINED LANDFILL LIMIT OF WASTE ASH BASIN WASTE BOUNDARY
ASH BASIN COMPLIANCE BOUNDARY
LEGEND:
##
#
#
#
#
&<
&<
&<
&<
&<
&<
&<
&<
APPROXIMATE LANDFILLPHASE 1-6 LIMIT OF WASTE
HYCO LAKE(Approx. Pond Elev = 410')FLY ASHSTRUCTURAL FILL
4 2 5
4 3 5415
4 4 5
4 5 54 6 0
4
7
5
510
505
500
495
4 6 5
490
485
475
4 7 0GMW-06(460.84)
GMW-07(477.11)
GMW-08(484.40)GMW-09(517.01)
GMW-10(469.14)GMW-11(482.12)
PZ-12(472.41)
PZ-14(457.26)
LP-01
LP-02
LP-03
LP-04
5 1 0
5 0 5
5 0 0495
4 6 5
4 7 0
4
9
0
4
8
5
4
8
0
475
LP-06
LP-05
SCALE (FEET)300 0 300 600
PROJECT MANAGER: J. WYLIE
DRAWN BY: B. YOUNG
DATE: 07/27/2016
DATE: 07/27/2016
CHECKED BY: K. DONOVAN
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FIGURE 3GENERALIZED GROUNDWATERSURFACE CONTOURSROXBORO STEAM ELECTRIC PLANTINDUSTRIAL WASTE LANDFILLPERMIT NO. 7302
"
148 RIVER STREET, SUITE 220GREENVILLE, SC 29601864-421-9999
NOTES:1 10ft CONTOUR INTERVALS FROM NCDOT LIDAR DATED 2007https://connect.ncdot.gov/resources/gis/pages/cont-elev_v2.aspx
2 CONTOUR LINES ARE USED FOR REPRESENTATIVE PURPOSES ONLY ANDARE NOT TO BE USED FOR DESIGN OR CONSTRUCTION PURPOSES.
3 2014 AERIAL ORTHOPHOTOGRAPHY OBTAINED FROM USDA NRCSGEOSPATIAL DATA GATEWAY (https://gdg.sc.egov.usda.gov/GDGOrder.aspx).
&<GROUNDWATER MONITORING WELL
&<PIEZOMETER (WATER ELEVATION ONLY)
#LEACHATE SAMPLING LOCATION
GROUNDWATER SURFACE CONTOUR
APPROXIMATE LINED LANDFILL LIMIT OF WASTE APPROXIMATE UNLINED LANDFILL LIMIT OF WASTE
ASH BASIN WASTE BOUNDARY
ASH BASIN COMPLIANCE BOUNDARY
GENERAL GROUNDWATER FLOW DIRECTION
LEGEND:
Roxboro Semiannual Groundwater Monitoring Report – April 2016 Sampling Event July 2016
Duke Energy Progress, LLC SynTerra
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TABLES
TABLE 1
WELL CONSTRUCTION INFORMATION
ROXBORO INDUSTRIAL WASTE LANDFILL - PERMIT NO. 7302
ROXBORO STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, SEMORA, NC
Latitude Longitude
GMW-6 3/14/2002 36.4812210 -79.0648371 481.46 479.99 1.47 46.47 31.47 31.47 - 46.47 Saprolite 2 PVC
GMW-7 6/28/2010 36.4763616 -79.0646926 500.59 497.21 3.38 57.38 42.38 42.38 - 57.38 Bedrock 2 PVC
GMW-8 3/13/2002 36.4747493 -79.0610383 529.78 525.90 3.88 66.88 56.88 56.88 - 66.88 Bedrock 2 PVC
GMW-9 3/13/2002 36.4744875 -79.0578763 537.46 533.73 3.73 48.73 33.73 33.73 - 48.73 Bedrock 2 PVC
GMW-10 9/25/2002 36.4818523 -79.0634291 495.19 455.64 3.55 48.55 33.55 33.55 - 48.55 Bedrock 2 PVC
GMW-11 2/28/2011 36.4817950 -79.0622715 497.23 493.19 4.04 49.04 34.04 34.04 - 49.04 Bedrock 2 PVC
PZ-12 5/6/2003 36.4779790 -79.0575623 515.30 512.68 2.62 55.95 35.95 35.95 - 55.95 Fly Ash 2 PVC
PZ-14 Not Available 36.4804433 -79.0670853 472.78 469.75 3.03 22.70 12.70 12.70 - 22.70 Not Available 2 PVC
1. TOC indicates top of casing.
2. ft. indicates feet.
3. in. indicates inches nominal diameter.
4. PVC indicates polyvinyl chloride.
5. Horizontal datum NAD27.
6. Elevations based on NAVD 29.
Prepared by: BDW Checked by: TCP
Notes:
Total Well
Depth
below TOC
(ft.)
Coordinates
Well ID Well Installation
Date
Well TOC Elevation
(ft.)
Ground
Surface
Elevation
(ft.)
Well Stick-up
Height Above
Ground Surface
(ft.)
Well Diameter
(in.)
Casing
Type
Depth to Top
of Screen
from TOC
(ft.)
Screened
Interval
below TOC
(ft.)
Geology of Screened
Interval
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TABLE 2
GROUNDWATER FLOW VELOCITIES
ROXBORO INDUSTRIAL WASTE LANDFILL - PERMIT NO. 7302
ROXBORO STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, SEMORA, NC
GMW-9 to GMW-8 517.01 484.4 934 0.035 1.04 0.26 0.140
GMW-9 to GMW-6*517.01 460.84 3193 0.018 2.10 0.26 0.142
GMW-11 to GMW-10 482.12 469.14 361 0.036 1.04 0.26 0.144
Notes:
Prepared by:RKD Checked by:AA
Hydraulic
Conductivity
(ft/day)
Effective
Porosity
(%/100)
Groundwater
Velocity
(ft/day)
Well IDs
Upgradient
Groundwater
Elevation (ft)
Downgradient
Groundwater
Elevation (ft)
Linear Distance
Between
Elevations (ft)
Hydraulic
Gradient
(ft/ft)
1. Monitoring wells are not listed where insufficient groundwater contour information is unavailable to calculate velocity.
2. Hydraulic gradients, effective porosties, and groundwater velocities are approximate.
3. Hydraulic conductivites presented for all wells are adapted from geomeans of various wells in the same aquifers. These values are published in SynTerra's
Comprehensive Site Assessment for Roxboro (CSA Report, Roxboro, September, 2015).
4. Effective porosities for all wells adapted from Morris and Johnson, 1967.
* GMW-9 is screened in bedrock and GMW-6 is screened in saprolite, therefore hydraulic conductivities and porosities are a combination of both aquifers
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TABLE 3
FIELD DATA PARAMETERS
ROXBORO INDUSTRIAL WASTE LANDFILL - PERMIT NO. 7302
ROXBORO STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, SEMORA, NC
4/6/2016 GMW-6 Clear None LF 100 4.22 0.75 No 16 1487 6.9 1.3 89 5.15 460.84 20.62
4/6/2016 GMW-7 Clear None LF 130 5.53 0.45 No 16 1297 6.6 3.5 215 2.48 477.11 23.48
4/6/2016 GMW-8 Clear None LF 100 3.51 0.5 No 17 2602 6.5 4.9 227 0.28 484.40 45.38
4/6/2016 GMW-9 Clear None LF 190 4.61 0.6 No 16 230 6.2 0.5 266 6.12 517.01 20.45
4/6/2016 GMW-10 Clear None LF 210 3.67 1 No 16 236 6.0 1.1 152 4.03 469.14 26.05
4/6/2016 GMW-11 Clear None LF 160 5.53 0.55 No 15 852 6.6 2.3 216 1.89 482.12 15.11
4/6/2016 LP-1 Not Noted Not Noted N/A N/A N/A N/A N/A 18 4081 7.0 8.8 105 5.24 472.41 42.89
4/6/2016 LP-2 Not Noted Not Noted N/A N/A N/A N/A N/A 18 4600 7.1 7.5 40 5.96 457.26 15.22
4/6/2016 LP-3 Not Noted Not Noted N/A N/A N/A N/A N/A 19 5152 7.0 12.8 67 4.84 N/A N/A
4/6/2016 LP-4 Not Noted Not Noted N/A N/A N/A N/A N/A 18 5320 6.6 7.8 196 2 N/A N/A
7/14/2016 LP-5 Not Noted Not Noted N/A N/A N/A N/A N/A 22 5168 6.7 0.54 40 2.58 N/A N/A
7/14/2016 LP-6 Not Noted Not Noted N/A N/A N/A N/A N/A 21 4999 6.6 0.76 43 1.66 N/A N/A
Notes:
10. N/A = Not Applicable
3. EVAC indicates wheter the water level in the well was drawn down to the level of the
pump during purging.
4. µmhos/cm = micromhos per centimeter
5. mL/min = milliliters per minute
6. SU = Standard Units
7. NTU = Nephelometric Turbidity Units
8. mV-NHE = millivolts
9. ug/L = micrograms per liter
ORP
(mV)
DO*
(ug/L)
Average
Pump Rate
(mL/min)
Well
Volume
(gallons)
EVAC
Volume
(gallons)
EVAC
(yes/no)
Temp
(deg C)
Groundwater
Elevation (ft.)
Depth to
Water
below TOC
(ft.)
Prepared by: BDW Checked by: TCP
11 *SynTerra Corporation is not NC-certified for these parameters. Data collected for
information purposes only.
12. Depth to water measurements taken on April 6, 2016
Specific
Conductance
(µmho/cm)
pH
(SU)
Turbidity
(NTU)
1. Purge Methods; LF=Low Flow, LF(M)=Low Flow Modified, CP=Conventional Purge (3-5
well volumes), NP=No Purge (HydraSleeve), EOP = Equipment Only Purge. Average pump rate applicable to LF and LF(M) purging only.
2. Field sampling performed by SynTerra Corporation personnel.
Appearance Odor Purge
Method
Sample
Date Sample ID
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TABLE 4
GROUNDWATER FIELD AND ANALYTICAL RESULTS
ROXBORO INDUSTRIAL WASTE LANDFILL - PERMIT NO. 7302
ROXBORO STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, SEMORA, NC
7302-
GMW-6
7302-
GMW-7
7302-
GMW-8
7302-
GMW-9
7302-
GMW-10
7302-
GMW-11
Field pH 320 S.U.5591 6.9 6.6 6.5 6.2 6.0 6.6 -NE 6.5-8.5 6.5-8.5*
Specific Conductance 323 µƱ/cm 5591 1487 1297 2602 230 236 852 -NE NE NE
Temperature 325 °C 5591 16 16 17 16 16 15 -NE NE NE
Arsenic 14 µg/L 248 < 1 < 1 < 1 < 1 < 1 < 1 0.078 10 10 10
Barium 15 µg/L 248 54 294 62 67 65 49 0.1 100 700 2,000
Boron 428 µg/L 248 736 1,330 5,350 < 50 < 50 1,390 3.3 NE 700 NE
Cadmium 34 µg/L 248 < 1 < 1 < 1 < 1 < 1 < 1 0.101 1 2 5
Chloride 455 µg/L 248 110,000 110,000 270,000 4,300 21,000 33,000 22 NE 250,000 250,000*
Chromium 51 µg/L 248 < 5 < 5 < 5 < 5 < 5 < 5 0.5 10 10 100
Copper 54 µg/L 248 < 5 < 5 < 5 < 5 < 5 < 5 1 10 1,000 1,300
Fluoride 312 µg/L 248 < 1,000 170 < 1,000 130 140 < 500 17 2,000 2,000 4,000
Iron 340 µg/L 248 < 10 142 70 33 28 87 1.3 300 300 300*
Lead 131 µg/L 248 < 1 < 1 < 1 < 1 < 1 < 1 0.065 10 15 15
Manganese 342 µg/L 248 < 5 < 5 61 < 5 < 5 < 5 0.2 50 50 50*
Mercury 132 µg/L 248 < 0.05 < 0.05 < 0.05 < 0.05 < 0.05 < 0.05 0.006 0.2 1 2
Nickel 152 µg/L 248 < 5 < 5 < 5 < 5 < 5 < 5 0.5 50 100 NE
Nitrate (as Nitrogen)303 mg*N/L 248 1,000 1,100 110 340 370 750 5.4 10,000 10,000 10,000
Selenium 183 µg/L 248 68.3 11.6 < 1 < 1 < 1 41.2 0.092 10 20 50
Silver 184 µg/L 248 < 5 < 5 < 5 < 5 < 5 < 5 0.7 10 20 100*
Sulfate 315 µg/L 248 380,000 370,000 770,000 55,000 16,000 230,000 18 250,000 250,000 250,000*
Total Dissolved Solids 311 µg/L 248 1,100,000 920,000 2,000,000 200,000 190,000 610,000 16,700 NE 500,000 500,000*
Thallium 194 µg/L 248 0.215 < 0.2 < 0.2 < 0.2 < 0.2 < 0.2 0.133 5.5 0.2**2
Zinc 213 µg/L 248 < 5 < 5 8 < 5 < 5 < 5 2.6 10 1,000 5,000*
Notes:Prepared By: BDW Checked By: TCP
Bold Concentrations are equal to or greater than the 15A NCAC 2L Standard (for pH bold indicates a measurement outside of the range).
Samplles collected by SynTerra Corporation on April 6, 2016.
MDL = the laboratory Method Detection Limit. The MDL values presented are for samples not diluted by the laboratory during analysis.
SWSL = the Solid Waste Section Limit. NCDENR defines the SWSL as the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy.
15A NCAC 2L Standard refers to Class GA Standards as found in 15A NCAC 02L. 0202 Groundwater Quality Standards, last amended on April 1, 2013 (Appendix I amended April 1, 2013).
MCL = Federal Maximum Contaminant Level as found in 40 CFR, Subpart G § 141.62.
7302 = Industrial Waste Landfill - Permit No. 7302
S.U. = Standard Units
µƱ/cm = micromhos per centimeter
µg/L = micrograms per liter
A blank cell means there is no relevant information.* Concentration listed is a secondary maximum contaminant level (SMCL). SMCLs are established by EPA in the National Secondary Drinking Water Regulations as found in 40 CFR §143.3.
** Interim Maximum Allowable Concentration (IMAC).
Parameter SWS ID Units Certificate Code
NE = Not Established
MDL SWSL 15A NCAC 2L Standard Federal MCL
All concentrations are presented in µg/L.
SWS ID = the Solid Waste Section Identification Number.
Monitoring Wells
- Concentrations are equal to or greater than the SWSL.
P:\Duke Energy Progress.1026\07.ROXBORO PLANT\17.April 2016 Landfill Solid Waste GW Compliance and Monitoring\Table 4 Groundwater Field and Analytical ResultsTable 4 Groundwater Field and Analytical Resultstable 4 Page 1 of 1
TABLE 5
FIELD AND ANALYTICAL RESULTS THAT EQUAL OR EXCEED 15A NCAC 2L GROUNDWATER QUALITY STANDARDS
ROXBORO INDUSTRIAL WASTE LANDFILL - PERMIT NO. 7302
ROXBORO STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, SEMORA, NC
Parameter Sample ID Result Units
15A NCAC
2L
Standard Historical Concentrations Cause and Significance
GMW-9 6.2 5.4 - 6.9 pH in GMW-9 is consistent with historical readings at well. GMW-9 is the site background water quality monitoring well.
GMW-10 6.0 5.5 - 7.2 pH in GMW-10 is consistent with historical readings at well.
GMW-6 736 736 - 3,920 Boron concentration in GMW-6 is the lowest detected exceedance at well over period of monitoring.
GMW-7 1,330 < 50 - 1,560 Boron concentration in GMW-7 is consistent with historical readings at well.
GMW-8 5,350 1,680 - 5,350 Boron concentration in GMW-8 is the highest measured over the period of monitoring. The boron concentration in GMW-8 has been increasing over the last 6 sampling events.
GMW-11 1,390 388 - 2,340 Boron concentration in GMW-11 is consistent with historical readings at well.
Chloride GMW-8 270,000 µg/L 250,000 66,200 - 300,000 Chloride concentration in GMW-8 is consistent with the previous three readings, but higher than readings prior to April 21, 2015.
Manganese GMW-8 61 µg/L 50 25.8 - 449 Manganese concentration in GMW-8 is consistent with historical readings at well.
GMW-6 68.3 56.6 - 105 Selenium concentration in GMW-6 is consistent with historical readings at well.
GMW-11 41.2 5.1 - 264 Selenium concentration in GMW-11 is consistent with historical readings at well.
GMW-6 380,000 < 5,000 - 1,108,000 Sulfate concentration in GMW-6 is consistent with historical readings at well.
GMW-7 370,000 16,000 - 549,000 The sulfate concentration in GMW-7 is the second highest reading at well over period of monitoring.
GMW-8 770,000 231,000 - 820,000 Sulfate in GMW-8 is consistent with historical readings at well.
GMW-6 1,100,000 1,100,000 - 2,050,000 Total Dissolved Solids concentration in GMW-6 is consistent with historical readings at well.
GMW-7 920,000 330,000 - 920,000 Total Dissolved Solids concentration in GMW-7 is the highest measured over the period of monitoring.
GMW-8 2,000,000 975,000 - 2,100,000 Total Dissolved Solids concentration in GMW-8 is consistent with historical readings at well.
GMW-11 610,000 378,000 - 1,660,000 Total Dissolved Solids concentration in GMW-11 is consistent with historical readings at well.
Prepared by: BDW Checked by: TCP
Notes:
1. 15A NCAC 2L Standard refers to Class GA Standards as found in 15A NCAC 02L .0202 Groundwater Quality Standards, last amended on April 1, 2013.
2. Analytical results obtained from Electonic Data Deliverable (EDD) provided by Duke Energy on April 28, 2015
3. µg/L indicates micrograms per liter.
4. SU indicates Standard Units.
5. Historical concentrations based on data in Duke Energy analytical results database.
6. Field sampling performed by SynTerra Corporation, Sample Date: April 6, 2016.
Sulfate µg/L 250,000
Total Dissolved
Solids µg/L 500,000
Selenium µg/L 20
SU 6.5-8.5Field pH
Boron µg/L 700
TABLE 6
LEACHATE FIELD AND ANALYTICAL RESULTS
ROXBORO INDUSTRIAL WASTE LANDFILL - PERMIT NO. 7302
ROXBORO STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, SEMORA, NC
7302-
LP-1
7302-
LP-2
7302
LP-3
7302-
LP-4
7302-
LP-5
7302-
LP-6
Field pH 320 S.U.5591 7.0 7.1 7.0 6.6 6.7 6.6 -NESpecific Conductance 323 µƱ/cm 5591 4,081 4,600 5,152 5,320 5,168 4,999 -NE
Temperature 325 °C 5591 18 18 19 18 21.6 20.6 -NEArsenic14µg/L 248 7.23 4.37 2.44 2.63 1.24 < 1 0.078 10
Barium 15 µg/L 248 37 32 32 32 62 66 0.1 100Boron428µg/L 248 43,400 50,500 49,600 51,000 20,200 15,500 3.3 NECadmium34µg/L 248 < 1 1.11 1.33 1.47 1.64 1.28 0.101 1Chloride455µg/L 248 43,000 150,000 330,000 230,000 644,700 632,900 22 NEChromium 51 µg/L 248 < 5 < 5 < 5 < 5 109 137 0.5 10
Copper 54 µg/L 248 < 5 < 5 < 5 < 5 < 5 < 5 1 10Fluoride312µg/L 248 < 2,500 < 2,500 < 5,000 < 5,000 < 1,000 < 1,000 17 2,000
Iron 340 µg/L 248 369 2,090 1,540 73 315 224 1.3 300Lead131µg/L 248 < 1 < 1 < 1 < 1 < 1 < 1 0.065 10
Manganese 342 µg/L 248 1,740 1.11 1,160 2,160 1,050 1,860 0.2 50Mercury132µg/L 248 < 0.05 < 0.05 < 0.05 < 0.05 < 0.05 < 0.05 0.006 0.2Nickel152µg/L 248 121 107 34 133 15 12 0.5 50Nitrate (as Nitrogen)303 µg/L 248 11,000 16,000 11,000 12,000 582 598 5.4 10,000Selenium183µg/L 248 796 639 561 373 126 54.1 0.092 10
Silver 184 µg/L 248 < 5 < 5 < 5 < 5 < 5 < 5 0.7 10Sulfate315µg/L 248 2,200,000 2,500,000 2,600,000 2,900,000 1,789,000 1,931,000 18 250,000
Thallium 194 µg/L 248 0.625 0.289 0.355 0.648 < 0.2 0.249 0.133 5.5Total Dissolved Solids 311 µg/L 248 3,600,000 4,100,000 4,600,000 4,500,000 4,000,000 4,200,000 16,700 NEZinc 213 µg/L 248 19 34 34 125 9 7 2.6 10
Notes:
Samples collected by SynTerra Corporation on April 6, 2016 and July 14, 2016
MDL = laboratory Method Detection Limit.
SWSL = the Solid Waste Section Limit. NCDENR defines the SWSL as the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy.
7302 = Roxboro Industrial Waste Landfill - Permit No. 7302
S.U. = Standard Units
µƱ/cm = micromhos per centimeter
- Concentrations are equal to or greater than the SWSL.
SWSL
All concentrations are presented in µg/L.
SWS ID = the Solid Waste Section Identification Number.
NE = Not Established
Parameter SWS ID Units Certificate Code MDL
Prepared by: BDW Checked by: TCP
Sample Location
P:\Duke Energy Progress.1026\07.ROXBORO PLANT\17.April 2016 Landfill Solid Waste GW Compliance and Monitoring\Table 6 Leachate Field and Analytical ResultsTable 6 Leachate Field and Analytical Resultstable 4 Page 1 of 1
Roxboro Semiannual Groundwater Monitoring Report – April 2016 Sampling Event July 2016
Duke Energy Progress, LLC SynTerra
P:\Duke Energy Progress.1026\07.ROXBORO PLANT\17.April 2016 Landfill Solid Waste GW Compliance and
Monitoring\7302_20160406.docx
APPENDIX A
FIELD SAMPLING FORMS

31.47 46.47
N/A (psi)N/A (sec)(sec)
(gal)
@
YES
SITE NAME ROXBORO PERMIT #73-02 SITE ID N/A
DUKE ENERGY PROCEDURE NPDES
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME SOLID WASTE COMPLIANCE - LANDFILL GW FIELD CREW RHJ, KDB, KDF, EMY, ZAD
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME GMW-6
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)481.46 MIDDLE OF WETTED SCREEN (ft TOC)38.97
SCREEN LENGTH (ft)15.00 ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)46.47 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)34.00
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)1/4 OD Low Flow
4.22
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)20.62 WATER COLUMN (ft)25.85 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)460.84 WELL VOLUME
Purge Start Date:Purged To Dryness:
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
16:39 20.93 100 16 1486 6.9 0.8 86 5.33 N/A
16:36 20.87 100 16 1486 7.0 1.6 84 5.48
N/A
16:45 20.95 100 16 1487 6.9 1.3 89 5.15 N/A
16:42 20.95 100 16 1488 6.9 0.9 87 5.36
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED Ferrous Iron
(mg/l)INITIAL PURGE VOLUME 0.50 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 0.75 (gal)EMY, ZAD 4/6/2016 16:48
DRAW-DOWN 0.33 (ft)
QC By:EMY
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
Field Vehicle Accessable
42.38 57.38
N/A (psi)N/A (sec)(sec)
(gal)
@
NO
Ditch and fence. Monsoon wasn't needed so we walked from the road.
SITE NAME ROXBORO PERMIT #73-02 SITE ID N/A
DUKE ENERGY PROCEDURE NPDES
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME SOLID WASTE COMPLIANCE - LANDFILL GW FIELD CREW RHJ, KDB, KDF, EMY, ZAD
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME GMW-7
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)500.59 MIDDLE OF WETTED SCREEN (ft TOC)49.88
SCREEN LENGTH (ft)15.00 ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)57.38 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)44.00
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
5519 SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)1/4 OD Low Flow
5.53
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Clear
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)23.48 WATER COLUMN (ft)33.90 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)477.11 WELL VOLUME
Purge Start Date:4/6/2016 Purged To Dryness:
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
16:44 24.57 128 16 1309 6.5 3.8 223 2.70 N/A
16:41 24.57 128 16 1307 6.5 2.1 227 2.34
N/A
16:50 24.57 128 16 1303 6.6 3.4 216 2.39 N/A
16:47 24.57 128 16 1308 6.6 3.3 219 2.52
N/A16:53 24.57 128 16 1297 6.6 3.5 215 2.48
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED Ferrous Iron
(mg/l)INITIAL PURGE VOLUME (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 0.45 (gal)KDB, KDF 4/6/2016 16:53
DRAW-DOWN 1.09 (ft)
QC By:KDF
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
Field Vehicle Accessable
56.88 66.88
N/A (psi)N/A (sec)(sec)
(gal)
@
YES Hard to get the monsoon pump to settle around 125 so we landed on 96. The water level was relatively stable at 96.
SITE NAME ROXBORO PERMIT #73-02 SITE ID N/A
DUKE ENERGY PROCEDURE NPDES
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME SOLID WASTE COMPLIANCE - LANDFILL GW FIELD CREW RHJ, KDB, KDF, EMY, ZAD
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME GMW-8
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)529.78 MIDDLE OF WETTED SCREEN (ft TOC)61.88
SCREEN LENGTH (ft)10.00 ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)66.88 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)59.00
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
5519 SAMPLING EQUIPMENT SUB PUMP PURGE METHOD
TUBING DIAMETER (in)1/4 OD Low Flow
3.51
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Clear
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)45.38 WATER COLUMN (ft)21.50 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)484.40 WELL VOLUME
Purge Start Date:4/6/2016 Purged To Dryness:
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
15:35 47.05 96 17 2607 6.5 13.7 239 0.33 N/A
15:32 46.60 300 17 2608 6.5 17.3 244 0.39
N/A
15:41 47.22 96 17 2610 6.6 5.2 229 0.32 N/A
15:38 47.16 96 18 2603 6.6 8.9 234 0.29
N/A15:44 47.30 96 17 2602 6.5 4.9 227 0.28
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED Ferrous Iron
(mg/l)INITIAL PURGE VOLUME (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 0.50 (gal)KDF, KDB 4/6/2016 15:44
DRAW-DOWN 1.92 (ft)
QC By:KDF
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
Field Vehicle Accessable
33.73 48.73
N/A (psi)N/A (sec)(sec)
(gal)
@
YES New gravel road put in by GMW-08, easy to get to in dry conditions. DUP taken here
SITE NAME ROXBORO PERMIT #73-02 SITE ID N/A
DUKE ENERGY PROCEDURE NPDES
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME SOLID WASTE COMPLIANCE - LANDFILL GW FIELD CREW RHJ, KDB, KDF, EMY, ZAD
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME GMW-9
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)537.46 MIDDLE OF WETTED SCREEN (ft TOC)41.23
SCREEN LENGTH (ft)15.00 ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)48.73 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)35.50
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
1738 SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)1/4 OD Low Flow
4.61
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Clear
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)20.45 WATER COLUMN (ft)28.28 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)517.01 WELL VOLUME
Purge Start Date:4/6/2016 Purged To Dryness:
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
14:30 20.46 188 16 223 6.3 2.0 275 6.11 N/A
14:27 20.45 188 16 200 6.3 1.8 282 6.42
N/A
14:36 20.46 188 16 241 6.2 0.7 269 5.93 N/A
14:33 20.46 188 16 247 6.2 1.4 273 5.98
N/A14:39 20.46 188 16 230 6.2 0.5 266 6.12
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED Ferrous Iron
(mg/l)INITIAL PURGE VOLUME (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 0.60 (gal)KDB, KDF 4/6/2016 14:39
DRAW-DOWN 0.01 (ft)
QC By:KDF
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
Field Vehicle Accessable
33.55 48.55
N/A (psi)N/A (sec)(sec)
(gal)
@
YES
MAY BE ABLE TO USE PERISTALTIC PUMP
RUN PUMP FOR 4 MINUTES BEFORE FIRST READING
SITE NAME ROXBORO PERMIT #73-02 SITE ID N/A
DUKE ENERGY PROCEDURE NPDES
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME SOLID WASTE COMPLIANCE - LANDFILL GW FIELD CREW RHJ, KDB, KDF, EMY, ZAD
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME GMW-10
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)495.19 MIDDLE OF WETTED SCREEN (ft TOC)41.05
SCREEN LENGTH (ft)15.00 ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)48.55 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)36.00
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
2867-T SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)1/4 OD Low Flow
3.67
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)26.05 WATER COLUMN (ft)22.50 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)469.14 WELL VOLUME
Purge Start Date:4/6/2016 Purged To Dryness:
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
17:16 26.68 210 16 237 6.1 1.9 144 4.09 N/A
17:13 26.48 210 16 245 6.3 2.1 134 4.25
N/A
17:22 26.94 210 16 236 6.0 1.1 152 4.03 N/A
17:19 26.88 210 16 236 6.0 1.1 150 4.04
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED Ferrous Iron
(mg/l)INITIAL PURGE VOLUME 0.50 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 1.00 (gal)EMY 4/6/2016 17:22
DRAW-DOWN 0.89 (ft)
QC By:
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
Field Vehicle Accessable
34.04 49.04
N/A (psi)N/A (sec)(sec)
(gal)
@
YES
SITE NAME ROXBORO PERMIT #73-02 SITE ID N/A
DUKE ENERGY PROCEDURE NPDES
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME SOLID WASTE COMPLIANCE - LANDFILL GW FIELD CREW RHJ, KDB, KDF, EMY, ZAD
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME GMW-11
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)497.23 MIDDLE OF WETTED SCREEN (ft TOC)41.54
SCREEN LENGTH (ft)15.00 ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)49.04 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)36.00
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
5519 SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)1/4 OD Low Flow
5.53
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)15.11 WATER COLUMN (ft)33.93 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)482.12 WELL VOLUME
Purge Start Date:Purged To Dryness:
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
17:32 15.28 160 15 859 6.6 4.4 229 2.12 N/A
17:29 15.26 160 15 864 6.7 7.8 236 2.48
N/A
17:38 15.28 160 15 857 6.6 1.9 219 2.00 N/A
17:35 15.28 160 15 858 6.6 8.2 221 2.03
N/A17:41 15.28 160 15 852 6.6 2.3 216 1.89
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED Ferrous Iron
(mg/l)INITIAL PURGE VOLUME (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 0.55 (gal)KDB, KDF 4/6/2016 17:41
DRAW-DOWN 0.17 (ft)
QC By:KDF
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
Field Vehicle Accessable
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
LEACHATE POINT 1
SITE NAME ROXBORO PERMIT #73-02 SITE ID N/A
DUKE ENERGY PROCEDURE NPDES
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME SOLID WASTE COMPLIANCE - LANDFILL GW FIELD CREW RHJ, KDB, KDF, EMY, ZAD
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME LP1
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)MIDDLE OF WETTED SCREEN (ft TOC)0.00
SCREEN LENGTH (ft)ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
SAMPLING EQUIPMENT PURGE METHOD
TUBING DIAMETER (in)No Purge
DETECTED ODOR CONVERSION FACTOR
APPEARANCE
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
Purge Start Date:N/A Purged To Dryness:
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
RHJ 4/6/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV -NEH)(mg/L)
N/A N/A N/A 18 4081 7.0 8.8
15:05
105 5.24
NA
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE Ferrous Fe
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
QC By:
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
Field Vehicle Accessable
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
LEACHATE POINT 2
SITE NAME ROXBORO PERMIT #73-02 SITE ID N/A
DUKE ENERGY PROCEDURE NPDES
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME SOLID WASTE COMPLIANCE - LANDFILL GW FIELD CREW RHJ, KDB, KDF, EMY, ZAD
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME LP2
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)MIDDLE OF WETTED SCREEN (ft TOC)0.00
SCREEN LENGTH (ft)ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
SAMPLING EQUIPMENT PURGE METHOD
TUBING DIAMETER (in)No Purge
DETECTED ODOR CONVERSION FACTOR
APPEARANCE
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
Purge Start Date:N/A Purged To Dryness:
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
RHJ 4/6/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV -NEH)(mg/L)
N/A N/A N/A 18 4600 7.1 7.5
15:30
40 5.96
NA
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE Ferrous Fe
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
QC By:
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
Field Vehicle Accessable
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
LEACHATE POINT 3
SITE NAME ROXBORO PERMIT #73-02 SITE ID N/A
DUKE ENERGY PROCEDURE NPDES
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME SOLID WASTE COMPLIANCE - LANDFILL GW FIELD CREW RHJ, KDB, KDF, EMY, ZAD
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME LP3
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)MIDDLE OF WETTED SCREEN (ft TOC)0.00
SCREEN LENGTH (ft)ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
SAMPLING EQUIPMENT PURGE METHOD
TUBING DIAMETER (in)No Purge
DETECTED ODOR CONVERSION FACTOR
APPEARANCE
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
Purge Start Date:N/A Purged To Dryness:
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
RHJ 4/6/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV -NEH)(mg/L)
N/A N/A N/A 19 5152 7.0 12.8
15:48
67 4.84
NA
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE Ferrous Fe
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
Turbidity > 10 NTU - After sampling, lower tubing/pump in
attempt to redevelop well QC By:
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
Field Vehicle Accessable
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
SITE NAME ROXBORO PERMIT #73-02 SITE ID N/A
DUKE ENERGY PROCEDURE NPDES
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME SOLID WASTE COMPLIANCE - LANDFILL GW FIELD CREW RHJ, KDB, KDF, EMY, ZAD
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME LP4
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)MIDDLE OF WETTED SCREEN (ft TOC)0.00
SCREEN LENGTH (ft)ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
SAMPLING EQUIPMENT PURGE METHOD
TUBING DIAMETER (in)No Purge
DETECTED ODOR CONVERSION FACTOR
APPEARANCE
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
Purge Start Date:N/A Purged To Dryness:
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
RHJ 4/6/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV -NEH)(mg/L)
N/A N/A N/A 18 5320 6.6 7.8
16:10
196 2.00
NA
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE Ferrous Fe
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
QC By:
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
Field Vehicle Accessable
55.00 55.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
WATER LEVEL ONLY
SITE NAME ROXBORO PERMIT #73-02 SITE ID N/A
DUKE ENERGY PROCEDURE NPDES
GROUNDWATER MONITORING DATA SHEET
FOR LEVEL ONLY
PROJECT NAME SOLID WASTE COMPLIANCE - LANDFILL GW FIELD CREW RHJ, KDB, KDF, EMY, ZAD
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME PZ-12
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)MIDDLE OF WETTED SCREEN (ft TOC)55.00
SCREEN LENGTH (ft)ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)55.00 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
1738 SAMPLING EQUIPMENT LEVEL ONLY PURGE METHOD
TUBING DIAMETER (in)Level Only
DETECTED ODOR CONVERSION FACTOR
APPEARANCE
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)42.89 WATER COLUMN (ft)12.11 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)-42.89 WELL VOLUME
Purge Start Date:N/A Purged To Dryness:
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
4/6/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV -NEH)(mg/L)
N/A N/A N/A N/A N/A N/A N/A N/A N/A
NA
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE Ferrous Fe
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
Turbidity > 10 NTU - After sampling, lower tubing/pump in
attempt to redevelop well QC By:
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
Field Vehicle Accessable
46.60 46.60
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
WATER LEVEL ONLY
SITE NAME ROXBORO PERMIT #73-02 SITE ID N/A
DUKE ENERGY PROCEDURE NPDES
GROUNDWATER MONITORING DATA SHEET
FOR LEVEL ONLY
PROJECT NAME SOLID WASTE COMPLIANCE - LANDFILL GW FIELD CREW RHJ, KDB, KDF, EMY, ZAD
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME PZ-14
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)MIDDLE OF WETTED SCREEN (ft TOC)46.60
SCREEN LENGTH (ft)ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)46.60 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
SAMPLING EQUIPMENT LEVEL ONLY PURGE METHOD
TUBING DIAMETER (in)Level Only
5.12
DETECTED ODOR CONVERSION FACTOR 0.1631
APPEARANCE
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)15.22 WATER COLUMN (ft)31.38 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)-15.22 WELL VOLUME
Purge Start Date:N/A Purged To Dryness:
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
4/6/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV -NEH)(mg/L)
N/A N/A N/A N/A N/A N/A N/A N/A N/A
NA
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE Ferrous Fe
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
Turbidity > 10 NTU - After sampling, lower tubing/pump in
attempt to redevelop well QC By:
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
Field Vehicle Accessable
Roxboro Semiannual Groundwater Monitoring Report – April 2016 Sampling Event July 2016
Duke Energy Progress, LLC SynTerra
P:\Duke Energy Progress.1026\07.ROXBORO PLANT\17.April 2016 Landfill Solid Waste GW Compliance and
Monitoring\7302_20160406.docx
APPENDIX B
LABORATORY REPORT AND
CHAIN-OF-CUSTODY FORMS
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16030238
Project Name:ROXBORO - LFGW
Lab Contact:Peggy Kendall
Date:4/28/2016
Customer Address:Roxboro Steam Station
Customer Name(s):Tim Hunsucker, John Toepfer
1700 Dunnaway Road
Semora,NC 27343
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Peggy Kendall
Page 1 of 23
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016006726 Roxboro 06-Apr-16 4:48 PM Synterra GMW-6
2016006746 Roxboro 06-Apr-16 4:53 PM Synterra GMW-7
2016006747 Roxboro 06-Apr-16 3:44 PM Synterra GMW-8
2016006748 Roxboro 06-Apr-16 2:39 PM Synterra GMW-9
2016006749 Roxboro 06-Apr-16 5:22 PM Synterra GMW-10
2016006750 Roxboro 06-Apr-16 5:41 PM Synterra GMW-11
2016006751 Roxboro 06-Apr-16 3:05 PM Synterra LP-1
2016006752 Roxboro 06-Apr-16 3:30 PM Synterra LP-2
2016006753 Roxboro 06-Apr-16 3:48 PM Synterra LP-3
2016006754 Roxboro 06-Apr-16 4:10 PM Synterra LP-4
2016006755 Roxboro 06-Apr-16 2:39 PM Synterra DUP GMW-9
2016006756 Roxboro 06-Apr-16 3:13 PM Synterra FIELD BLANK
12 Total Samples
Page 2 of 23
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:4/28/2016
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030238
2016006726
Collection Date:06-Apr-16 4:48 PM
Site:GMW-6
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 110 mg/L EPA 9056A 04/07/2016 19:39 BGN903410100
Fluoride < 1 mg/L EPA 9056A 04/07/2016 19:39 BGN9034110
Nitrate 4.5 mg/L EPA 9056A 04/07/2016 19:39 BGN9034110
Nitrate as N 1.0 mg-N/L EPA 9056A 04/07/2016 19:39 BGN90340.023 1
Sulfate 380 mg/L EPA 9056A 04/07/2016 19:39 BGN903410100
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/13/2016 09:29 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.054 mg/L SW 6010D 04/12/2016 18:48 JJMACKE0.005 1
Boron (B)0.736 mg/L SW 6010D 04/12/2016 18:48 JJMACKE0.05 1
Chromium (Cr)< 0.005 mg/L SW 6010D 04/12/2016 18:48 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/12/2016 18:48 JJMACKE0.005 1
Iron (Fe)< 0.01 mg/L SW 6010D 04/12/2016 18:48 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L SW 6010D 04/12/2016 18:48 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/12/2016 18:48 JJMACKE0.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/12/2016 18:48 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/12/2016 18:48 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 04/12/2016 14:31 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 04/12/2016 14:31 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/12/2016 14:31 JAHERMA11
Selenium (Se)68.3 ug/L SW 6020B 04/12/2016 14:31 JAHERMA11
Thallium (Tl) Low Level 0.215 ug/L SW 6020B 04/12/2016 14:31 JAHERMA0.2 1
TOTAL DISSOLVED SOLIDS
TDS 1100 mg/L SM2540C 04/11/2016 16:06 PARMSTR251
Page 4 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030238
2016006746
Collection Date:06-Apr-16 4:53 PM
Site:GMW-7
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 110 mg/L EPA 9056A 04/08/2016 22:19 BGN9034550
Fluoride 0.17 mg/L EPA 9056A 04/08/2016 22:19 BGN90340.1 1
Nitrate 4.9 mg/L EPA 9056A 04/08/2016 22:19 BGN90340.1 1
Nitrate as N 1.1 mg-N/L EPA 9056A 04/08/2016 22:19 BGN90340.023 1
Sulfate 370 mg/L EPA 9056A 04/08/2016 22:19 BGN9034550
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/13/2016 09:36 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.294 mg/L SW 6010D 04/12/2016 19:00 JJMACKE0.005 1
Boron (B)1.33 mg/L SW 6010D 04/12/2016 19:00 JJMACKE0.05 1
Chromium (Cr)< 0.005 mg/L SW 6010D 04/12/2016 19:00 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/12/2016 19:00 JJMACKE0.005 1
Iron (Fe)0.142 mg/L SW 6010D 04/12/2016 19:00 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L SW 6010D 04/12/2016 19:00 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/12/2016 19:00 JJMACKE0.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/12/2016 19:00 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/12/2016 19:00 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 04/12/2016 14:09 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 04/12/2016 14:09 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/12/2016 14:09 JAHERMA11
Selenium (Se)11.6 ug/L SW 6020B 04/12/2016 14:09 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/12/2016 14:09 JAHERMA0.2 1
TOTAL DISSOLVED SOLIDS
TDS 920 mg/L SM2540C 04/11/2016 16:06 PARMSTR251
Page 5 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030238
2016006747
Collection Date:06-Apr-16 3:44 PM
Site:GMW-8
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 270 mg/L EPA 9056A 04/07/2016 19:56 BGN903410100
Fluoride < 1 mg/L EPA 9056A 04/07/2016 19:56 BGN9034110
Nitrate < 1 mg/L EPA 9056A 04/07/2016 19:56 BGN9034110
Nitrate as N 0.11 mg-N/L EPA 9056A 04/07/2016 19:56 BGN90340.023 1
Sulfate 770 mg/L EPA 9056A 04/07/2016 19:56 BGN903410100
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/13/2016 09:38 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.062 mg/L SW 6010D 04/12/2016 19:04 JJMACKE0.005 1
Boron (B)5.35 mg/L SW 6010D 04/12/2016 19:04 JJMACKE0.05 1
Chromium (Cr)< 0.005 mg/L SW 6010D 04/12/2016 19:04 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/12/2016 19:04 JJMACKE0.005 1
Iron (Fe)0.070 mg/L SW 6010D 04/12/2016 19:04 JJMACKE0.01 1
Manganese (Mn)0.061 mg/L SW 6010D 04/12/2016 19:04 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/12/2016 19:04 JJMACKE0.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/12/2016 19:04 JJMACKE0.005 1
Zinc (Zn)0.008 mg/L SW 6010D 04/12/2016 19:04 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 04/12/2016 14:36 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 04/12/2016 14:36 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/12/2016 14:36 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 04/12/2016 14:36 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/12/2016 14:36 JAHERMA0.2 1
TOTAL DISSOLVED SOLIDS
TDS 2000 mg/L SM2540C 04/11/2016 16:06 PARMSTR251
Page 6 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030238
2016006748
Collection Date:06-Apr-16 2:39 PM
Site:GMW-9
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 4.3 mg/L EPA 9056A 04/07/2016 21:41 BGN90340.1 1
Fluoride 0.13 mg/L EPA 9056A 04/07/2016 21:41 BGN90340.1 1
Nitrate 1.5 mg/L EPA 9056A 04/07/2016 21:41 BGN90340.1 1
Nitrate as N 0.34 mg-N/L EPA 9056A 04/07/2016 21:41 BGN90340.023 1
Sulfate 55 mg/L EPA 9056A 04/07/2016 21:41 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/13/2016 09:41 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.067 mg/L SW 6010D 04/12/2016 19:08 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/12/2016 19:08 JJMACKE0.05 1
Chromium (Cr)< 0.005 mg/L SW 6010D 04/12/2016 19:08 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/12/2016 19:08 JJMACKE0.005 1
Iron (Fe)0.023 mg/L SW 6010D 04/12/2016 19:08 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L SW 6010D 04/12/2016 19:08 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/12/2016 19:08 JJMACKE0.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/12/2016 19:08 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/12/2016 19:08 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 04/12/2016 14:42 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 04/12/2016 14:42 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/12/2016 14:42 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 04/12/2016 14:42 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/12/2016 14:42 JAHERMA0.2 1
TOTAL DISSOLVED SOLIDS
TDS 200 mg/L SM2540C 04/11/2016 16:06 PARMSTR251
Page 7 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030238
2016006749
Collection Date:06-Apr-16 5:22 PM
Site:GMW-10
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 21 mg/L EPA 9056A 04/07/2016 19:22 BGN9034110
Fluoride 0.14 mg/L EPA 9056A 04/07/2016 19:22 BGN90340.1 1
Nitrate 1.7 mg/L EPA 9056A 04/07/2016 19:22 BGN90340.1 1
Nitrate as N 0.37 mg-N/L EPA 9056A 04/07/2016 19:22 BGN90340.023 1
Sulfate 16 mg/L EPA 9056A 04/07/2016 19:22 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/13/2016 09:43 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.065 mg/L SW 6010D 04/12/2016 19:12 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/12/2016 19:12 JJMACKE0.05 1
Chromium (Cr)< 0.005 mg/L SW 6010D 04/12/2016 19:12 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/12/2016 19:12 JJMACKE0.005 1
Iron (Fe)0.028 mg/L SW 6010D 04/12/2016 19:12 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L SW 6010D 04/12/2016 19:12 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/12/2016 19:12 JJMACKE0.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/12/2016 19:12 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/12/2016 19:12 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 04/12/2016 14:47 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 04/12/2016 14:47 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/12/2016 14:47 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 04/12/2016 14:47 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/12/2016 14:47 JAHERMA0.2 1
TOTAL DISSOLVED SOLIDS
TDS 190 mg/L SM2540C 04/11/2016 16:06 PARMSTR251
Page 8 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030238
2016006750
Collection Date:06-Apr-16 5:41 PM
Site:GMW-11
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 33 mg/L EPA 9056A 04/07/2016 20:13 BGN90342.5 25
Fluoride < 0.5 mg/L EPA 9056A 04/07/2016 20:13 BGN90340.5 5
Nitrate 3.3 mg/L EPA 9056A 04/07/2016 20:13 BGN90340.5 5
Nitrate as N 0.75 mg-N/L EPA 9056A 04/07/2016 20:13 BGN90340.023 1
Sulfate 230 mg/L EPA 9056A 04/07/2016 20:13 BGN90342.5 25
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/13/2016 09:45 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.049 mg/L SW 6010D 04/12/2016 19:15 JJMACKE0.005 1
Boron (B)1.39 mg/L SW 6010D 04/12/2016 19:15 JJMACKE0.05 1
Chromium (Cr)< 0.005 mg/L SW 6010D 04/12/2016 19:15 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/12/2016 19:15 JJMACKE0.005 1
Iron (Fe)0.087 mg/L SW 6010D 04/12/2016 19:15 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L SW 6010D 04/12/2016 19:15 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/12/2016 19:15 JJMACKE0.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/12/2016 19:15 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/12/2016 19:15 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 04/12/2016 14:52 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 04/12/2016 14:52 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/12/2016 14:52 JAHERMA11
Selenium (Se)41.2 ug/L SW 6020B 04/12/2016 14:52 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/12/2016 14:52 JAHERMA0.2 1
TOTAL DISSOLVED SOLIDS
TDS 610 mg/L SM2540C 04/11/2016 16:06 PARMSTR251
Page 9 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030238
2016006751
Collection Date:06-Apr-16 3:05 PM
Site:LP-1
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 43 mg/L EPA 9056A 04/07/2016 20:30 BGN90342.5 25
Fluoride < 2.5 mg/L EPA 9056A 04/07/2016 20:30 BGN90342.5 25
Nitrate 51 mg/L EPA 9056A 04/07/2016 20:30 BGN90342.5 25
Nitrate as N 11 mg-N/L EPA 9056A 04/07/2016 20:30 BGN90340.023 1
Sulfate 2200 mg/L EPA 9056A 04/07/2016 20:30 BGN903450500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/13/2016 09:48 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.037 mg/L SW 6010D 04/12/2016 19:19 JJMACKE0.005 1
Boron (B)43.4 mg/L SW 6010D 04/12/2016 19:19 JJMACKE0.5 10
Chromium (Cr)< 0.005 mg/L SW 6010D 04/12/2016 19:19 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/12/2016 19:19 JJMACKE0.005 1
Iron (Fe)0.369 mg/L SW 6010D 04/12/2016 19:19 JJMACKE0.01 1
Manganese (Mn)1.74 mg/L SW 6010D 04/12/2016 19:19 JJMACKE0.005 1
Nickel (Ni)0.121 mg/L SW 6010D 04/12/2016 19:19 JJMACKE0.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/12/2016 19:19 JJMACKE0.005 1
Zinc (Zn)0.019 mg/L SW 6010D 04/12/2016 19:19 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)7.23 ug/L SW 6020B 04/12/2016 14:58 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 04/12/2016 14:58 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/12/2016 14:58 JAHERMA11
Selenium (Se)796 ug/L SW 6020B 04/12/2016 14:58 JAHERMA1010
Thallium (Tl) Low Level 0.625 ug/L SW 6020B 04/12/2016 14:58 JAHERMA0.2 1
TOTAL DISSOLVED SOLIDS
TDS 3600 mg/L SM2540C 04/11/2016 16:06 PARMSTR2501
Page 10 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030238
2016006752
Collection Date:06-Apr-16 3:30 PM
Site:LP-2
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 150 mg/L EPA 9056A 04/07/2016 20:47 BGN90342.5 25
Fluoride < 2.5 mg/L EPA 9056A 04/07/2016 20:47 BGN90342.5 25
Nitrate 70 mg/L EPA 9056A 04/07/2016 20:47 BGN90342.5 25
Nitrate as N 16 mg-N/L EPA 9056A 04/07/2016 20:47 BGN90340.023 1
Sulfate 2500 mg/L EPA 9056A 04/07/2016 20:47 BGN903450500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/13/2016 09:50 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.032 mg/L SW 6010D 04/12/2016 19:23 JJMACKE0.005 1
Boron (B)50.5 mg/L SW 6010D 04/12/2016 19:23 JJMACKE0.5 10
Chromium (Cr)< 0.005 mg/L SW 6010D 04/12/2016 19:23 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/12/2016 19:23 JJMACKE0.005 1
Iron (Fe)2.09 mg/L SW 6010D 04/12/2016 19:23 JJMACKE0.01 1
Manganese (Mn)1.11 mg/L SW 6010D 04/12/2016 19:23 JJMACKE0.005 1
Nickel (Ni)0.107 mg/L SW 6010D 04/12/2016 19:23 JJMACKE0.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/12/2016 19:23 JJMACKE0.005 1
Zinc (Zn)0.034 mg/L SW 6010D 04/12/2016 19:23 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)4.37 ug/L SW 6020B 04/12/2016 15:03 JAHERMA11
Cadmium (Cd)1.11 ug/L SW 6020B 04/12/2016 15:03 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/12/2016 15:03 JAHERMA11
Selenium (Se)639 ug/L SW 6020B 04/12/2016 15:03 JAHERMA1010
Thallium (Tl) Low Level 0.289 ug/L SW 6020B 04/12/2016 15:03 JAHERMA0.2 1
TOTAL DISSOLVED SOLIDS
TDS 4100 mg/L SM2540C 04/11/2016 16:06 PARMSTR2501
Page 11 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030238
2016006753
Collection Date:06-Apr-16 3:48 PM
Site:LP-3
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 330 mg/L EPA 9056A 04/07/2016 21:09 BGN9034550
Fluoride < 5 mg/L EPA 9056A 04/07/2016 21:09 BGN9034550
Nitrate 49 mg/L EPA 9056A 04/07/2016 21:09 BGN9034550
Nitrate as N 11 mg-N/L EPA 9056A 04/07/2016 21:09 BGN90340.023 1
Sulfate 2600 mg/L EPA 9056A 04/07/2016 21:09 BGN903450500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/13/2016 09:53 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.032 mg/L SW 6010D 04/12/2016 19:27 JJMACKE0.005 1
Boron (B)49.6 mg/L SW 6010D 04/12/2016 19:27 JJMACKE0.5 10
Chromium (Cr)< 0.005 mg/L SW 6010D 04/12/2016 19:27 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/12/2016 19:27 JJMACKE0.005 1
Iron (Fe)1.54 mg/L SW 6010D 04/12/2016 19:27 JJMACKE0.01 1
Manganese (Mn)1.16 mg/L SW 6010D 04/12/2016 19:27 JJMACKE0.005 1
Nickel (Ni)0.034 mg/L SW 6010D 04/12/2016 19:27 JJMACKE0.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/12/2016 19:27 JJMACKE0.005 1
Zinc (Zn)0.034 mg/L SW 6010D 04/12/2016 19:27 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)2.44 ug/L SW 6020B 04/12/2016 15:09 JAHERMA11
Cadmium (Cd)1.33 ug/L SW 6020B 04/12/2016 15:09 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/12/2016 15:09 JAHERMA11
Selenium (Se)561 ug/L SW 6020B 04/12/2016 15:09 JAHERMA1010
Thallium (Tl) Low Level 0.355 ug/L SW 6020B 04/12/2016 15:09 JAHERMA0.2 1
TOTAL DISSOLVED SOLIDS
TDS 4600 mg/L SM2540C 04/11/2016 16:06 PARMSTR2501
Page 12 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030238
2016006754
Collection Date:06-Apr-16 4:10 PM
Site:LP-4
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 230 mg/L EPA 9056A 04/07/2016 21:25 BGN9034550
Fluoride < 5 mg/L EPA 9056A 04/07/2016 21:25 BGN9034550
Nitrate 51 mg/L EPA 9056A 04/07/2016 21:25 BGN9034550
Nitrate as N 12 mg-N/L EPA 9056A 04/07/2016 21:25 BGN90340.023 1
Sulfate 2900 mg/L EPA 9056A 04/07/2016 21:25 BGN903450500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/15/2016 11:32 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.032 mg/L SW 6010D 04/12/2016 19:31 JJMACKE0.005 1
Boron (B)51.0 mg/L SW 6010D 04/12/2016 19:31 JJMACKE0.5 10
Chromium (Cr)< 0.005 mg/L SW 6010D 04/12/2016 19:31 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/12/2016 19:31 JJMACKE0.005 1
Iron (Fe)0.073 mg/L SW 6010D 04/12/2016 19:31 JJMACKE0.01 1
Manganese (Mn)2.16 mg/L SW 6010D 04/12/2016 19:31 JJMACKE0.005 1
Nickel (Ni)0.133 mg/L SW 6010D 04/12/2016 19:31 JJMACKE0.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/12/2016 19:31 JJMACKE0.005 1
Zinc (Zn)0.125 mg/L SW 6010D 04/12/2016 19:31 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)2.63 ug/L SW 6020B 04/12/2016 15:14 JAHERMA11
Cadmium (Cd)1.47 ug/L SW 6020B 04/12/2016 15:14 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/12/2016 15:14 JAHERMA11
Selenium (Se)373 ug/L SW 6020B 04/12/2016 15:14 JAHERMA11
Thallium (Tl) Low Level 0.648 ug/L SW 6020B 04/12/2016 15:14 JAHERMA0.2 1
TOTAL DISSOLVED SOLIDS
TDS 4500 mg/L SM2540C 04/11/2016 16:06 PARMSTR2501
Page 13 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030238
2016006755
Collection Date:06-Apr-16 2:39 PM
Site:DUP GMW-9
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 4.5 mg/L EPA 9056A 04/07/2016 14:18 BGN90340.1 1
Fluoride 0.13 mg/L EPA 9056A 04/07/2016 14:18 BGN90340.1 1
Nitrate 1.5 mg/L EPA 9056A 04/07/2016 14:18 BGN90340.1 1
Nitrate as N 0.34 mg-N/L EPA 9056A 04/07/2016 14:18 BGN90340.023 1
Sulfate 55 mg/L EPA 9056A 04/07/2016 14:18 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/13/2016 09:55 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.068 mg/L SW 6010D 04/12/2016 19:50 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/12/2016 19:50 JJMACKE0.05 1
Chromium (Cr)< 0.005 mg/L SW 6010D 04/12/2016 19:50 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/12/2016 19:50 JJMACKE0.005 1
Iron (Fe)0.033 mg/L SW 6010D 04/12/2016 19:50 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L SW 6010D 04/12/2016 19:50 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/12/2016 19:50 JJMACKE0.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/12/2016 19:50 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/12/2016 19:50 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 04/12/2016 15:35 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 04/12/2016 15:35 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/12/2016 15:35 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 04/12/2016 15:35 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/12/2016 15:35 JAHERMA0.2 1
TOTAL DISSOLVED SOLIDS
TDS 200 mg/L SM2540C 04/11/2016 16:06 PARMSTR251
Page 14 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030238
2016006756
Collection Date:06-Apr-16 3:13 PM
Site:FIELD BLANK
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 9056A 04/07/2016 09:15 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/07/2016 09:15 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 04/07/2016 09:15 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 04/07/2016 09:15 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 04/07/2016 09:15 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/15/2016 11:35 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L SW 6010D 04/12/2016 19:54 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/12/2016 19:54 JJMACKE0.05 1
Chromium (Cr)< 0.005 mg/L SW 6010D 04/12/2016 19:54 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/12/2016 19:54 JJMACKE0.005 1
Iron (Fe)< 0.01 mg/L SW 6010D 04/12/2016 19:54 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L SW 6010D 04/12/2016 19:54 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/12/2016 19:54 JJMACKE0.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/12/2016 19:54 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/12/2016 19:54 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 04/12/2016 15:41 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 04/12/2016 15:41 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/12/2016 15:41 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 04/12/2016 15:41 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/12/2016 15:41 JAHERMA0.2 1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 04/11/2016 16:06 PARMSTR251
Page 15 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030238
Q16040104 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0296 mg/L -10.0296 0.1 < 1/2 RDL
Fluoride 0.0441 mg/L -10.0441 0.1 < 1/2 RDL
Nitrate 0.012 mg/L -10.012 0.1 < 1/2 RDL
Sulfate -0.0018 mg/L -1-0.0018 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 6.35 5 101mg/L -1208016.35
Fluoride 5.34 5 106mg/L -1208015.34
Nitrate 5.19 5 104mg/L -1208015.19
Sulfate 6.99 5 104mg/L -1208016.99
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 6.35 5 101 0.00197mg/L -1208016.35
Fluoride 5.38 5 107 0.65mg/L -1208015.38
Nitrate 5.21 5 104 0.359mg/L -1208015.21
Sulfate 7 5 104 0.276mg/L -1208017
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 5.85 5 95.9mg/L -1208015.85
Fluoride 5.39 5 107mg/L -1208015.39
Nitrate 5.16 5 102mg/L -1208015.16
Sulfate 8.96 5 102mg/L -1208018.96
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 5.92 5 97.3 1.46mg/L -1208015.92
Fluoride 5.4 5 107 0.112mg/L -1208015.4
Nitrate 5.15 5 102 0.0449mg/L -1208015.15
Sulfate 8.95 5 102 0.237mg/L -1208018.95
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 4.99 5 99.8mg/L -1208014.99
Fluoride 5.47 5 109mg/L -1208015.47
Nitrate 5.14 5 103mg/L -1208015.14
Sulfate 5.17 5 103mg/L -1208015.17
Page 16 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030238
Q16040261 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.011 ug/L -10.011 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.04 2 102ug/L -1158512.04
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16030238 -- 2016006726
Mercury (Hg) 0.981 1 99.3ug/L -1257510.981
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16030238 -- 2016006726
Mercury (Hg) 1.01 1 102 2.98ug/L -1257511.01
Page 17 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030238
Q16040319 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.007 ug/L -10.007 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.002 ug/L -10.002 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Mercury (Hg) 0.004 ug/L -10.004 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.08 1 107ug/L -1257511.08
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 1.06 1 105 2.07ug/L -11.06
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.03 2 102ug/L -1158512.03
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 2 2 99.9ug/L -1158512
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16030484 -- 2016007825
Mercury (Hg) 1.04 1 104ug/L -1257511.04
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16030484 -- 2016007825
Mercury (Hg) 1.02 1 102 2.05ug/L -1257511.02
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16030484 -- 2016007832
Mercury (Hg) 1 1 100ug/L -1257511
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16030484 -- 2016007832
Mercury (Hg) 0.999 1 99.7 0.5ug/L -1257510.999
Page 18 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030238
Q16040206 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) -0.000135 mg/L -1-0.000135 0.005 < 1/2 RDL
Boron (B) -0.00166 mg/L -1-0.00166 0.05 < 1/2 RDL
Chromium (Cr) -0.000916 mg/L -1-0.000916 0.005 < 1/2 RDL
Copper (Cu) 0.00116 mg/L -10.00116 0.005 < 1/2 RDL
Iron (Fe) -0.000014 mg/L -1-0.000014 0.01 < 1/2 RDL
Manganese (Mn) 0.00004 mg/L -10.00004 0.005 < 1/2 RDL
Nickel (Ni) -0.000339 mg/L -1-0.000339 0.005 < 1/2 RDL
Silver (Ag) 0.000156 mg/L -10.000156 0.005 < 1/2 RDL
Zinc (Zn) 0.00125 mg/L -10.00125 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 5.11 5 102mg/L -1208015.11
Boron (B) 5.04 5 101mg/L -1208015.04
Chromium (Cr) 4.9 5 98mg/L -1208014.9
Copper (Cu) 4.97 5 99.4mg/L -1208014.97
Iron (Fe) 4.86 5 97.3mg/L -1208014.86
Manganese (Mn) 5.04 5 101mg/L -1208015.04
Nickel (Ni) 4.8 5 96.1mg/L -1208014.8
Silver (Ag) 0.512 0.5 102mg/L -1208010.512
Zinc (Zn) 4.88 5 97.6mg/L -1208014.88
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16030238 -- 2016006726
Barium (Ba) 5.18 5 103mg/L -1257515.18
Boron (B) 5.72 5 99.7mg/L -1257515.72
Chromium (Cr) 4.81 5 96.1mg/L -1257514.81
Copper (Cu) 4.95 5 99mg/L -1257514.95
Iron (Fe) 4.82 5 96.3mg/L -1257514.82
Manganese (Mn) 4.93 5 98.7mg/L -1257514.93
Nickel (Ni) 4.57 5 91.4mg/L -1257514.57
Silver (Ag) 0.493 0.5 98.6mg/L -1257510.493
Zinc (Zn) 4.62 5 92.5mg/L -1257514.62
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16030238 -- 2016006726
Barium (Ba) 5.23 5 103 0.796mg/L -1257515.23
Boron (B) 5.69 5 99 0.704mg/L -1257515.69
Chromium (Cr) 4.75 5 94.9 1.24mg/L -1257514.75
Copper (Cu) 4.98 5 99.7 0.745mg/L -1257514.98
Page 19 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030238
Q16040206 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16030238 -- 2016006726
Iron (Fe) 4.78 5 95.5 0.792mg/L -1257514.78
Manganese (Mn) 4.88 5 97.6 1.08mg/L -1257514.88
Nickel (Ni) 4.51 5 90.2 1.28mg/L -1257514.51
Silver (Ag) 0.495 0.5 99.1 0.555mg/L -1257510.495
Zinc (Zn) 4.53 5 90.6 2.05mg/L -1257514.53
Page 20 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030238
Q16040210 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As) -0.0039 ug/L -1-0.0039 1 < 1/2 RDL
Cadmium (Cd) -0.0028 ug/L -1-0.0028 1 < 1/2 RDL
Lead (Pb) -0.0065 ug/L -1-0.0065 1 < 1/2 RDL
Selenium (Se) -0.025 ug/L -1-0.025 1 < 1/2 RDL
Thallium (Tl) Low Level 0.0253 ug/L -10.0253 0.2 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As) 49.1 50 98.2ug/L -12080149.1
Cadmium (Cd) 50.1 50 100ug/L -12080150.1
Lead (Pb) 49.5 50 98.9ug/L -12080149.5
Selenium (Se) 49.2 50 98.3ug/L -12080149.2
Thallium (Tl) Low Level 49.4 50 98.8ug/L -149.4
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16030238 -- 2016006746
Arsenic (As) 52.1 50 104ug/L -12080152.1
Cadmium (Cd) 49.9 50 99.7ug/L -12080149.9
Lead (Pb) 50.2 50 100ug/L -12080150.2
Selenium (Se) 60 50 96.9ug/L -12080160
Thallium (Tl) Low Level 45.9 50 91.8ug/L -145.9
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16030238 -- 2016006746
Arsenic (As) 51.4 50 103 1.35ug/L -12080151.4
Cadmium (Cd) 49.3 50 98.5 1.25ug/L -12080149.3
Lead (Pb) 49.7 50 99.4 0.984ug/L -12080149.7
Selenium (Se) 58.9 50 94.6 2.32ug/L -12080158.9
Thallium (Tl) Low Level 46.6 50 93.1 1.45ug/L -146.6
Page 21 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030238
Q16040187 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16030238 -- 2016006726
TDS 0.44mg/L -11130
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16030238 -- 2016006746
TDS 1.09mg/L -1926
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J16030238 -- 2016006747
TDS 0.785mg/L -12030
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 97mg/L -11090197
Page 22 of 23
Page 23 of 23
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16070392
Project Name:ROXBORO -
Lab Contact:Anne Pridgeon
Date:7/26/2016
Customer Address:Roxboro Steam Station
Customer Name(s):John Toepfer, Tim Hunsucker
1700 Dunnaway Road
Semora,NC 27343
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pridgeon) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pridgeon
Duke Energy Analytical Lab
Page 1 of 12
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016021820 Roxboro 14-Jul-16 3:20 PM Kyle Donovan LP-5
2016021821 Roxboro 14-Jul-16 3:15 PM Kyle Donovan LP-6
2 Total Samples
Duke Energy Analytical Lab
Page 2 of 12
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Anne Pridgeon Date:7/26/2016
Electronic Data Deliverable (EDD) Sent Separatel
Duke Energy Analytical Lab
Page 3 of 12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070392
2016021820
Collection Date:14-Jul-16 3:20 PM
Site:LP-5
Matrix:OTHER
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 644.7 mg/L EPA 300.0 07/16/2016 11:03 BGN903410100
Fluoride < 1 mg/L EPA 300.0 07/16/2016 11:03 BGN9034110
Nitrate 2.577 mg/L EPA 300.0 07/16/2016 11:03B2 BGN9034110
Nitrate as N 0.5817 mg-N/L EPA 300.0 07/16/2016 11:03 BGN90340.023 1
Sulfate 1789 mg/L EPA 300.0 07/16/2016 11:03 BGN903450500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/21/2016 13:58 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.062 mg/L EPA 200.7 07/25/2016 09:42 MHH71310.005 1
Boron (B)20.2 mg/L EPA 200.7 07/25/2016 09:42 MHH71310.25 5
Chromium (Cr)0.109 mg/L EPA 200.7 07/25/2016 09:42 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 07/25/2016 09:42 MHH71310.005 1
Iron (Fe)0.315 mg/L EPA 200.7 07/25/2016 09:42 MHH71310.01 1
Manganese (Mn)1.05 mg/L EPA 200.7 07/25/2016 09:42 MHH71310.005 1
Nickel (Ni)0.015 mg/L EPA 200.7 07/25/2016 09:42 MHH71310.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 07/25/2016 09:42 MHH71310.005 1
Zinc (Zn)0.009 mg/L EPA 200.7 07/25/2016 09:42 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)1.24 ug/L EPA 200.8 07/21/2016 22:43M1 CWSPEN311
Cadmium (Cd)1.64 ug/L EPA 200.8 07/21/2016 22:43 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/21/2016 22:43 CWSPEN311
Selenium (Se)126 ug/L EPA 200.8 07/21/2016 22:43M4 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/21/2016 22:43 CWSPEN30.2 1
TOTAL DISSOLVED SOLIDS
TDS 4000 mg/L SM2540C 07/19/2016 14:50 PARMSTR251
Duke Energy Analytical Lab
Page 4 of 12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070392
2016021821
Collection Date:14-Jul-16 3:15 PM
Site:LP-6
Matrix:OTHER
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 632.9 mg/L EPA 300.0 07/16/2016 11:18 BGN903410100
Fluoride < 1 mg/L EPA 300.0 07/16/2016 11:18 BGN9034110
Nitrate 2.651 mg/L EPA 300.0 07/16/2016 11:18B2 BGN9034110
Nitrate as N 0.5984 mg-N/L EPA 300.0 07/16/2016 11:18 BGN90340.023 1
Sulfate 1931 mg/L EPA 300.0 07/16/2016 11:18 BGN903450500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/21/2016 14:01 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.066 mg/L EPA 200.7 07/25/2016 09:38R1 MHH71310.005 1
Boron (B)15.5 mg/L EPA 200.7 07/25/2016 09:38 MHH71310.05 1
Chromium (Cr)0.137 mg/L EPA 200.7 07/25/2016 09:38 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 07/25/2016 09:38 MHH71310.005 1
Iron (Fe)0.224 mg/L EPA 200.7 07/25/2016 09:38 MHH71310.01 1
Manganese (Mn)1.86 mg/L EPA 200.7 07/25/2016 09:38 MHH71310.005 1
Nickel (Ni)0.012 mg/L EPA 200.7 07/25/2016 09:38 MHH71310.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 07/25/2016 09:38 MHH71310.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 07/25/2016 09:38 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 07/21/2016 23:09 CWSPEN311
Cadmium (Cd)1.28 ug/L EPA 200.8 07/21/2016 23:09 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/21/2016 23:09 CWSPEN311
Selenium (Se)54.1 ug/L EPA 200.8 07/21/2016 23:09 CWSPEN311
Thallium (Tl) Low Level 0.249 ug/L EPA 200.8 07/21/2016 23:09 CWSPEN30.2 1
TOTAL DISSOLVED SOLIDS
TDS 4200 mg/L SM2540C 07/19/2016 14:50 PARMSTR251
Qualifiers:
B2 Target analyte was detected in blank(s) at a concentration greater than ½ the reporting limit but less than the
reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.
M1 Matrix spike recovery was High: the associated Laboratory Control Spike (LCS) was acceptable.
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate
to the spike level. The associated Laboratory Control Spike recovery was acceptable.
R1 Relative Percent Difference exceeded method acceptance limits, see additional notes.
Duke Energy Analytical Lab
Page 5 of 12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070392
Q16070352 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0034 mg/L -10.0034 0.1 < 1/2 RDL
Fluoride 0.0238 mg/L -10.0238 0.1 < 1/2 RDL
Nitrate 0.0674 mg/L -10.0674 0.1 > 1/2 RDL
Sulfate -0.0366 mg/L -1-0.0366 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 9.56 5 95.8mg/L -1208019.56
Fluoride 5.02 5 99.9mg/L -1208015.02
Nitrate 4.98 5 98.8mg/L -1208014.98
Sulfate 6.7 5 95.8mg/L -1208016.7
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 9.55 5 95.7 0.153mg/L -1208019.55
Fluoride 5.03 5 100 0.172mg/L -1208015.03
Nitrate 4.94 5 97.9 0.846mg/L -1208014.94
Sulfate 6.7 5 95.8 0.00835mg/L -1208016.7
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.24 5 105mg/L -1109015.24
Fluoride 5.15 5 103mg/L -1109015.15
Nitrate 5.23 5 105mg/L -1109015.23
Sulfate 5.22 5 104mg/L -1109015.22
Duke Energy Analytical Lab
Page 6 of 12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070392
Q16070552 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.021 ug/L -10.021 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 0.953 20 86ug/L -130702019.1
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.951 20 85.9 0.175ug/L -130702019
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 0.941 20 92.4ug/L -130702018.8
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.949 20 93.1 0.809ug/L -130702019
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.97 2 98.3ug/L -1158511.97
Duke Energy Analytical Lab
Page 7 of 12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070392
Q16070519 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) 0.0001 mg/L -10.0001 0.005 < 1/2 RDL
Boron (B) 0.00102 mg/L -10.00102 0.05 < 1/2 RDL
Chromium (Cr) 0.000069 mg/L -10.000069 0.005 < 1/2 RDL
Copper (Cu) 0.000779 mg/L -10.000779 0.005 < 1/2 RDL
Iron (Fe) 0.000841 mg/L -10.000841 0.01 < 1/2 RDL
Manganese (Mn) -0.000049 mg/L -1-0.000049 0.005 < 1/2 RDL
Nickel (Ni) 0.00005 mg/L -10.00005 0.005 < 1/2 RDL
Silver (Ag) 0.000471 mg/L -10.000471 0.005 < 1/2 RDL
Zinc (Zn) 0.000723 mg/L -10.000723 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 5.07 5 101mg/L -1158515.07
Boron (B) 4.91 5 98.3mg/L -1158514.91
Chromium (Cr) 4.92 5 98.5mg/L -1158514.92
Copper (Cu) 4.91 5 98.1mg/L -1158514.91
Iron (Fe) 4.99 5 99.8mg/L -1158514.99
Manganese (Mn) 4.99 5 99.8mg/L -1158514.99
Nickel (Ni) 4.97 5 99.3mg/L -1158514.97
Silver (Ag) 0.467 0.5 93.5mg/L -1158510.467
Zinc (Zn) 4.95 5 99mg/L -1158514.95
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070392 -- 2016021821
Barium (Ba) 4.85 5 95.7mg/L -1307014.85
Boron (B) 20.3 5 97mg/L -13070120.3
Chromium (Cr) 4.87 5 94.7mg/L -1307014.87
Copper (Cu) 4.99 5 100mg/L -1307014.99
Iron (Fe) 5.14 5 98.2mg/L -1307015.14
Manganese (Mn) 6.64 5 95.5mg/L -1307016.64
Nickel (Ni) 4.69 5 93.6mg/L -1307014.69
Silver (Ag) 0.465 0.5 92.9mg/L -1307010.465
Zinc (Zn) 4.5 5 89.8mg/L -1307014.5
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070392 -- 2016021821
Barium (Ba) 3.46 5 67.9 34mg/L -1307013.46
Boron (B) 20.5 5 102 4.61mg/L -13070120.5
Chromium (Cr) 4.88 5 94.8 0.148mg/L -1307014.88
Copper (Cu) 4.98 5 99.9 0.12mg/L -1307014.98
Duke Energy Analytical Lab
Page 8 of 12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070392
Q16070519 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070392 -- 2016021821
Iron (Fe) 5.15 5 98.5 0.285mg/L -1307015.15
Manganese (Mn) 6.7 5 96.7 1.23mg/L -1307016.7
Nickel (Ni) 4.7 5 93.7 0.0854mg/L -1307014.7
Silver (Ag) 0.463 0.5 92.5 0.35mg/L -1307010.463
Zinc (Zn) 4.51 5 90.1 0.267mg/L -1307014.51
Duke Energy Analytical Lab
Page 9 of 12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070392
Q16070525 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As) -0.0186 ug/L -1-0.0186 1 < 1/2 RDL
Cadmium (Cd) 0.004 ug/L -10.004 1 < 1/2 RDL
Lead (Pb) 0.302 ug/L -10.302 1 < 1/2 RDL
Selenium (Se) -0.165 ug/L -1-0.165 1 < 1/2 RDL
Thallium (Tl) Low Level 0.0635 ug/L -10.0635 0.2 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As) 52.7 50 105ug/L -11585152.7
Cadmium (Cd) 52.4 50 105ug/L -11585152.4
Lead (Pb) 53 50 106ug/L -11585153
Selenium (Se) 51.6 50 103ug/L -11585151.6
Thallium (Tl) Low Level 52.1 50 104ug/L -11585152.1
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070392 -- 2016021820
Arsenic (As) 61 50 120ug/L -13070161
Cadmium (Cd) 52.5 50 102ug/L -13070152.5
Lead (Pb) 52.8 50 106ug/L -13070152.8
Selenium (Se) 186 50 121ug/L -130701186
Thallium (Tl) Low Level 43.5 50 86.7ug/L -13070143.5
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070392 -- 2016021820
Arsenic (As) 78.1 50 154 24.9ug/L -13070178.1
Cadmium (Cd) 53.2 50 103 1.36ug/L -13070153.2
Lead (Pb) 51.4 50 103 2.6ug/L -13070151.4
Selenium (Se) 191 50 131 7.66ug/L -130701191
Thallium (Tl) Low Level 36.5 50 72.7 17.6ug/L -13070136.5
Duke Energy Analytical Lab
Page 10 of 12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070392
Q16070446 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -1-1 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16060373 -- 2016017136
TDS 1.34mg/L -1375
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16060373 -- 2016017137
TDS 4.69mg/L -1218
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J16060373 -- 2016017138
TDS 0mg/L -11
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 103mg/L -110901103
Duke Energy Analytical Lab
Page 11 of 12
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