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HomeMy WebLinkAbout1203_BurkeCountyJohnsRiver_CorrectiveActionEvaluationReport_DIN25976_20160404 PREPARED FOR: BOARD OF COMMISSIONERS COUNTY OF BURKE P.O. BOX 1486 MORGANTON, NORTH CAROLINA 28680 JOHN’S RIVER WASTE MANAGEMENT FACILITY PERMIT NO. 12-03 C&D-OVER-MSW LANDFILL CORRECTIVE ACTION EVALUATION REPORT APRIL 2016 PREPARED BY: 2211 WEST MEADOWVIEW ROAD, SUITE 101 GREENSBORO, NORTH CAROLINA 27407 NC LICENSE NUMBER C-0782 PHONE: (336) 323-0092 FAX: (336) 323-0093 JOYCE PROJECT NO. 277.1601.12 Corrective Action Evaluation Report (CAER) Joyce Engineering John’s River Waste Management Facility, Permit No. 12-03 April 2016 i Corrective Action Evaluation Report John’s River Waste Management Facility – Permit No. 12-03 Burke County, North Carolina TABLE OF CONTENTS 1.0 INTRODUCTION..............................................................................................................1  1.1 Site Information ........................................................................................................................1  1.2 Site Geology .............................................................................................................................1  1.3 Regulatory Status .....................................................................................................................2  1.4 Groundwater Monitoring History .............................................................................................2  2.0 FACILITY MONITORING PROGRAM .......................................................................3  2.1 Groundwater Monitoring Program ...........................................................................................3  2.2 Surface Water Monitoring Program .........................................................................................5  3.0 SEMIANNUAL SAMPLING EVENTS FOR THIS CAER PERIOD ..........................6  4.0 HYDROGEOLOGICAL CONDITIONS ........................................................................7  5.0 CORRECTIVE ACTION SUMMARY ...........................................................................8  5.1 Description of Corrective Action Remedy ...............................................................................8  5.1.1 MNA plus Phytoremediation .................................................................................. 8  5.1.2 Control of Landfill Gas ........................................................................................... 8  5.2 Physical & Chemical Changes in Aquifer Characteristics .......................................................9  5.3 Physical & Chemical Changes in Plume Characteristics .......................................................10  5.4 Refining the Site Conceptual Model ......................................................................................11  5.5 Impacts of Corrective Action - MNA and Phytoremediation ................................................11  5.5.1 MNA Parameters and Biodegradation Screening Matrix ..................................... 11  5.5.2 Biochlor Modeling and Mass-Balance Assessment .............................................. 13  5.5.3 Trend Charts and Plume Stability ......................................................................... 14  5.5.4 Plume Maps and Cross-Sections ........................................................................... 14  5.6 Phytoremediation ....................................................................................................................15  5.7 Off-site Migration of COCs ...................................................................................................15  5.8 Methane Migration and Control of Landfill Gas ....................................................................15  6.0 CONCLUSIONS ..............................................................................................................16  7.0 REFERENCES .................................................................................................................17  8.0 ACRONYMS ....................................................................................................................19  Corrective Action Evaluation Report (CAER) Joyce Engineering John’s River Waste Management Facility, Permit No. 12-03 April 2016 ii TABLE OF CONTENTS (CONTINUED) Tables: Table 1 Historical Detected Inorganic Constituents in Compliance Wells Table 2 Historical Detected Organic Constituents in Compliance Wells Table 3 Historical Detected Constituents in Performance and Sentinel Wells Table 4 Historical Detected Constituents in Surface Water Table 5 Historical Groundwater Elevation Data Table 6 Estimated Hydraulic Gradients and Flow Velocities Table 7 Historical MNA Parameters Table 8 Biodegradation Screening Matrix Table 9 COCs and LFG Parameters in Northeast Area Table 10 Methane Gas in Northeast Area Charts: Chart 1 Benzene Concentrations vs. Time Chart 2 1,4-Dichlorobenzene (1,4-DCB) Concentrations vs. Time Chart 3 1,1-Dichloroethane (1,1-DCA) Concentrations vs. Time Chart 4 1,2-Dichloroethane (1,2-DCA) Concentrations vs. Time Chart 5 Tetrachloroethylene (PCE) Concentrations vs. Time Chart 6 Trichloroethylene (TCE) Concentrations vs. Time Chart 7 Vinyl Chloride (VC) Concentrations vs. Time Chart 8 Methylene Chloride Concentrations vs. Time Chart 9 alpha-BHC Concentrations vs. Time Chart 10 beta-BHC Concentrations vs. Time Chart 11 Methane Gas vs. Time Figure: Figure 1 Site Location Map Drawings: Drawing 1 Groundwater Surface Map Drawing 2 Benzene Isoconcentration Map Drawing 3 1,4-Dichlorobenzene (1,4-DCB) Isoconcentration Map Drawing 4 1,1-Dichloroethane (1,1-DCA) Isoconcentration Map Drawing 5 1,2-Dichloroethane (1,2-DCA) Isoconcentration Map Drawing 6 Tetrachloroethylene (PCE) Isoconcentration Map Drawing 7 Trichloroethylene (TCE) Isoconcentration Map Drawing 8 Vinyl Chloride Isoconcentration Map Drawing 9 Methylene Chloride Isoconcentration Map Drawing 10 beta-BHC Isoconcentration Map Drawing 11 Total VOCs Isoconcentration Map Drawing 12 Total VOCs Cross-Sections Drawing 13 Methane Gas Plume Map Appendix: Appendix A Biochlor Modeling Input and Output Corrective Action Evaluation Report (CAER) Joyce Engineering John’s River Waste Management Facility, Permit No. 12-03 April 2016 1 1.0 INTRODUCTION 1.1 Site Information The Johns River Waste Management Facility (JRWMF) is located in the north-central portion of Burke County, north of Morganton, North Carolina. The 318-acre landfill property is bounded by Lower Creek to the north and east, and the Catawba River to the south. The Catawba River forms Lake Rhodhiss along the southeastern property line (Figure 1). Lake Rhodhiss is a long, narrow lake formed by the Rhodhiss Hydroelectric Dam located approximately 12 miles downstream of the landfill. The John’s River flows into the Catawba River near the southwest corner of the landfill property. The site has rolling topography with elevations ranging from 975 feet to 1,150 feet above mean sea level (MSL). The central portion is generally gently sloping and contains the higher elevations; relatively steep slopes and significant drainage features are located around the perimeter. The 100-year flood boundary extends onto the landfill property. The adjacent property to the west of the Johns River Waste Management Facility consists of undeveloped, heavily wooded land. Properties within 2,000 feet of the landfill boundary are covered by surface water or are heavily wooded. The unlined waste disposal unit consists of 28 acres in the southwest corner of the landfill property. The municipal solid waste (MSW) landfill began operation in April 1988, but was closed to comply with Rule .1627(c)(10)(A) of the NCSWMR, a regulation governing MSW Landfills units that were not designed with a base liner and leachate collection system. Burke County has operated a permitted Construction and Demolition (C&D) disposal area on top of the closed portions of the MSW landfill since 1998. A MSW transfer facility is located in the eastern half of the property. In 2014, Phase 1A of the C&D expansion was constructed northeast of the C&D over MSW landfill. Results of groundwater monitoring for Phase 1A will be presented in a separate report. A site plan showing all the pertinent features of the facility is provided in Drawing 1. 1.2 Site Geology The John’s River Waste Management Facility is in close proximity to the Brevard Shear Zone, and is underlain by highly metamorphosed rocks including gneiss, schist, as well as calc-silicate rocks, felsic rocks, and metavolcanic rocks. The dominant rock type at the facility is biotite- muscovite schist, as seen in outcrops, boulders, and rock cores located on site. The structures within limited outcrops indicate that these rocks are complexly-folded, with attitudes that vary from vertical to horizontal in most outcrops. The site regolith is typical of the inner piedmont and consists mostly of silty sand, clayey sand, and sandy silt. The regolith is up to 100 feet thick and varies in thickness with topography. An abundance of rounded gravel, cobble, and boulder-sized alluvial deposits are exposed along the banks of the Catawba River, which borders the site. The greatest accumulation of these deposits is along the southwestern site boundary. These river deposits are 40 feet or more above the current river elevation and have been described as ancient river terrace deposits. Corrective Action Evaluation Report (CAER) Joyce Engineering John’s River Waste Management Facility, Permit No. 12-03 April 2016 2 1.3 Regulatory Status The following report of groundwater monitoring data from the JRWMF has been prepared in accordance with the North Carolina Solid Waste Management Rules (NCSWMR) 15A NCAC 13B §.1632 (Groundwater Sampling & Analysis Requirements) §.1633 (Detection Monitoring Program), and §.1634 (Assessment Monitoring Program). The facility has operated under these programs under the auspices the North Carolina Department of Environment and Natural Resources (NCDENR), which is now the Department of Environmental Quality (NCDEQ). To avoid confusion, NCDEQ will be used in reference to this department throughout this report even in reference to past events or documents when it was the NCDENR. The C&D over MSW landfill has been in the Assessment Monitoring Program since August 1995. In January 2000, Burke County submitted a Water Quality Assessment Report (WQAR), for the landfill to the NCDEQ. The WQAR determined that the constituents-of-concern (COCs) at the landfill were several volatile organic compounds (VOCs), specifically: benzene; 1,4- dichlorobenzene; methylene chloride; tetrachloroethylene; and trichloroethylene. The JRWMF entered the Corrective Action Program following the correspondence received from the NCDEQ Solid Waste Section (SWS) dated August 18, 2003. An Assessment of Corrective Measures (ACM) was submitted to NCDEQ in February 2005. A public meeting was held on May 16, 2006 in order to receive public comments regarding the ACM as required by NCSWMR §.1635 (d). A Corrective Action Plan (CAP) was submitted to NCDEQ in June 2008 and revised in November 2008. The CAP was approved by NCDEQ in a letter dated January 29, 2009. An addendum to the facility’s CAP was submitted to the NCDEQ in August 2013, adding control of landfill gas as a remedy for groundwater impacts on the northeastern side of the landfill between the old landfill and the new C&D expansion area. 1.4 Groundwater Monitoring History  April 1988: Facility began operations as an MSW landfill.  August 1995: Assessment Monitoring began.  January 1998: Facility closed as an MSW landfill, but began operating a C&D landfill on top of the former MSW landfill.  January 2000: Water Quality Assessment Report (JOYCE, 2000).  October 2004: Update on Water Quality Assessment Report (JOYCE, 2004).  February 2005: Assessment of Corrective Measures (ACM) (JOYCE, 2005a) and Quantitative Risk Assessment (JOYCE, 2005b).  May 2006: Public Meeting for ACM.  June 2008: Corrective Action Plan (CAP) submitted to NCDEQ-SWS.  November 2008: CAP Revised per comments from NCDEQ-SWS & resubmitted.  January 2009: CAP Approved by NCDEQ-SWS.  June 2009: First Monitored Natural Attenuation (MNA) baseline sampling event.  May 2011: First Corrective Action Evaluation Report (CAER). Corrective Action Evaluation Report (CAER) Joyce Engineering John’s River Waste Management Facility, Permit No. 12-03 April 2016 3  April 2012: Alternate Source Demonstration (ASD) for iron and manganese approved by NCDEQ.  August 2013: Addendum to the CAP to add control of landfill gas as a remedy. 2.0 FACILITY MONITORING PROGRAM 2.1 Groundwater Monitoring Program Groundwater monitoring at the C&D over MSW landfill is performed in accordance with NCSWMR §.1634, the site’s Transition Plan (JOYCE, April 1994), and the sites Corrective Action Monitoring Plan (CAMP) (Joyce, 2008) Groundwater samples are collected semiannually and analyzed for constituents according to the sampling plan submitted to the SWS on October 29, 1999. Following is a summary of the compliance monitoring wells and other wells in the immediate vicinity of the landfill. Well ID Date Installed Classification Monitoring Program Total Depth of Well (ft) Lithology of Screened Interval Constituent List MW-8 9-15-87 not used - 39.5 Saprolite - MW-9 8-31-94 Abandoned/ Former Bkgnd. - - - - MW-10 9-02-94 Compliance Assessment 23.0 Saprolite Comp. MW-11 9-02-94 Compliance/ Performance Assessment/ Cor. Act. 43.0 Saprolite Comp., MNA* MW-12 9-01-94 Compliance/ Performance Assessment/ Cor. Act. 51.5 Bedrock Comp., MNA* MW-13 8-31-94 Compliance Assessment 58.0 Bedrock Comp. MW-14 6-07-96 not used - 21.5 Saprolite - MW-15S 6-04-96 not used - 54.0 Saprolite - MW-15D 6-04-96 not used -118.5 Bedrock - MW-16S 3-08-99 Compliance/ Performance Assessment/ Cor. Act. 20.0 Saprolite Comp., MNA* MW-16D 3-10-99 Compliance Detection 120.0 Bedrock Comp. MW-17 3-08-99 Not used/ Former Bkgnd. - 52.0 Bedrock - MW-18 4-07-09 Sentinel** Corrective Action 12.0 Alluvial Soil COCs, MNA* MW-19 4-07-09 Sentinel** Corrective Action 13.0 Alluvial Soil COCs, MNA* MW-20 5-18-95 Former Bkgnd./ Phase 1A Compliance Assessment 67.0 Saprolite Comp. MW-21 5-18-95 Background Assessment/ Cor. Act. 45.0 Saprolite Comp., MNA* MW-36 5-08-11 Performance*** Corrective Action 43.0 Bedrock COCs, LFG MW-38 5-09-11 Phase 1A Compliance/ Performance*** Corrective Action 71.0 Bedrock COCs, LFG Corrective Action Evaluation Report (CAER) Joyce Engineering John’s River Waste Management Facility, Permit No. 12-03 April 2016 4 Notes: Comp. = Compliance Parameters: NCSWMR Appendix I and/or Appendix II organics and inorganics plus C&D parameters, as required for routine assessment or detection monitoring. COCs = Constituents of Concern. MNA = Monitored Natural Attenuation Parameters: Temperature, pH, specific conductance, oxidation reduction potential, dissolved oxygen, nitrate, sulfate, chloride, dissolved hydrogen, sulfide, alkalinity, TOC, methane, ethane, ethene, volatile fatty acids, carbon dioxide, ferrous iron, and turbidity. LFG = Landfill Gas Indicators: Dissolved CH4 and dissolved CO2. * After the baseline period, the NCDEQ approved alternate frequencies for carbon dioxide, sulfide, volatile fatty acids, ethane, and ethylene. These parameters will be monitored during both semiannual events every third year. ** After the baseline period, sampling frequency for sentinel wells was changed to annual. *** Performance wells (MW-36& MW-38) for the control of landfill gas remedy were added in the August 2013 CAP Addendum. MW-38 is also a compliance well for Phase 1A. The current compliance groundwater monitoring network at the facility consists of one upgradient well (MW-21), and six downgradient wells (MW-10, MW-11, MW-12 MW-13, MW-16S, and MW-16D). In March 1999, monitoring wells MW-16S and MW-16D were installed as downgradient monitoring wells and well MW-17 was installed as a replacement for upgradient background well MW-9. These wells were incorporated into the compliance monitoring network during the second semiannual groundwater monitoring event of 2005 after receiving approval from the SWS in a letter dated August 1, 2005. The letter also gave approval to drop MW-9 from the compliance monitoring network. MW-9 was abandoned in July 2006. There are several other monitoring wells at the facility (including MW-8, MW-14, MW-15S, and MW-15D) and several piezometers that have been used in the past to collect groundwater data to supplement the data from the compliance monitoring wells. Sentinel wells MW-18 and MW-19 were installed on April 7, 2009 in accordance with the facility’s Corrective Action Plan. Due to organic detections in MW-17, a request was submitted in August 2010 to replace MW-17 with MW-20 as the facility background well. MW-20 (originally named PZ-4) was installed as a piezometer in 1995 for site characterization. The NCDEQ-SWS requested that we sample both MW-17 and MW-20 for the next 2 sampling events (November 2010 and June 2011), and then submit a revised Water Quality Monitoring Plan to incorporate MW-20 into the compliance network as the new background well. MW-20 served as the background well until August 2014 when the new Permit to Operate for Phase 1A C&D Landfill expansion was issued by the North Carolina Department of Environment and Natural Resources. MW-20 was replaced by MW-21, (formerly PZ-1). MW-21 will serve as the new background monitoring well for both Phase 1A and the old C&D over MSW landfills. The former background well for the old C&D over MSW landfill, MW-20, which is located side-gradient of and to the northeast of Phase 1A, will continue to be sampled as a compliance well for Phase 1A. The wells in assessment monitoring (MW-10, MW-11, MW-12, MW-13, MW-16S, and MW-20) are analyzed for the NCSWMR Appendix I list of constituents plus additional detected Appendix II constituents and additional required C&D parameters during the first semiannual event, and for all constituents listed in NCSWMR Appendix II plus additional required C&D parameters during the second semiannual monitoring event. Monitoring well MW-16D is analyzed for the Corrective Action Evaluation Report (CAER) Joyce Engineering John’s River Waste Management Facility, Permit No. 12-03 April 2016 5 NCSWMR Appendix I plus additional required C&D parameters list during both events. Monitoring wells MW-11, MW-12, MW-16S, and MW-21 are also sampled for MNA parameters during each sampling event. In accordance with the CAP for the facility, MNA baseline sampling was initiated with the June 2009 sampling event and continued through the November 2010 sampling event. The baseline data were evaluated in a CAER dated May 2011. After reviewing the CAER, in a letter dated July 12, 2011, the NCDEQ agreed to a reduced frequency for monitoring carbon dioxide, sulfide, volatile fatty acids, ethane, and ethylene. These parameters will be sampled during both semiannual sampling events every third year. The next time these parameters will be monitored will be during the two semiannual events of 2016. The Corrective Action Monitoring Plan (CAMP) for the facility requires samples from sentinel wells MW-18 and MW-19 to be analyzed for the facility’s Constituents of Concern (COC’s). The COC list included the following constituents in 2015:  Benzene;  1,4-Dichlorobenzene;  Methylene chloride;  Tetrachloroethylene (PCE);  Trichloroethylene (TCE);  1,1-Dichloroethane;  1,2-Dichloroethane;  Vinyl chloride.  Alpha-BHC After the 2011 CAER, the NCDEQ agreed that sentinel wells MW-18 and MW-19 need only be sampled annually. MW-18 and MW-19 were last sampled during the May 2015 event. During future events, MW-18 and MW-19 will be monitored for the above COC list plus required MNA parameters annually. An addendum to the facility’s CAP was submitted to the NCDEQ in August 2013, adding control of landfill gas as a remedy for groundwater impacts on the northeastern side of the landfill between the old landfill and the new C&D expansion area. In accordance with the CAP addendum, piezometers PZ-36 and PZ-38 were converted to permanent monitoring wells MW-36 and MW-38 to act as performance wells for the control of LFG remedy. MW-36 and MW-38 are to be sampled semiannually for the current COC list, plus dissolved methane and dissolved carbon dioxide. 2.2 Surface Water Monitoring Program The current surface water monitoring points are SMP-5, SMP-6, and SMP-7. Surface water monitoring point SMP-5 (located at the southwestern property line) and SMP-6 (located at the southeastern property line) are both located downstream from existing sediment basins. Surface water monitoring point SMP-7 is located downstream from the new Phase 1A expansion. Corrective Action Evaluation Report (CAER) Joyce Engineering John’s River Waste Management Facility, Permit No. 12-03 April 2016 6 Surface water samples are analyzed for the NCSWMR Appendix I list of constituents plus detected Appendix II constituents during both semiannual events. Surface Point Classification Monitoring Program Location SMP-5 Compliance Surface Water Creek on west side of old landfill, downstream of sediment basin. SMP-6 Compliance Surface Water Creek on east side of old landfill, downstream of sediment basin. SMP-7 Compliance Surface Water Creek southeast of Phase 1A and east of sediment basin SB-2A. Downstream of PZ-12. 3.0 SEMIANNUAL SAMPLING EVENTS FOR THIS CAER PERIOD Ten semiannual water quality sampling events have been conducted at the JRWMF during this CARE period (2011-2015). The sampling events we conducted on the following dates: Semiannual Events Resample Events June 1-2, 2011 July 6-7, 2011 December 19-21, 2011 May 30, 2012 December 4-5, 2012 June 11-12, 2013 October 28-30, 2013 December 10, 2013 May 6-8, 2014 October 22-23, 2014 December 22, 2014 May 18-21, 2015 December 8-9, 2015 February 4, 2016 The results from these events, including associated resampling events, were presented in Semiannual Water Quality Monitoring Reports (WQMRs). The WQMRs included all field sampling data logs, laboratory analytical reports, and chains-of-custody for all compliance monitoring wells, corrective action wells, and surface water samples collected during each event. The WQMRs also included statistical analyses, evaluation of MNA data, Biochlor modeling (annually), review of the groundwater elevations and flow regime, trend charts for each COC, and a discussion of the results. The WQMR for the December 2015 semiannual event is being submitted concurrently with this CAER. For details of each sampling event, please refer to the associated WQMR. The historical analytical data are included in this report as Tables 1 through 4. The groundwater map (Drawing 1), plume maps (Drawings 2-11), and cross-sections (Drawing 12) presented and discussed in this report are based on the most recent data (December 2015 and February 2016), except for MW-18 and MW-19, for which the most recent data are from May 2015. Corrective Action Evaluation Report (CAER) Joyce Engineering John’s River Waste Management Facility, Permit No. 12-03 April 2016 7 4.0 HYDROGEOLOGICAL CONDITIONS Based on outcrop and drilling information, the water table appears to occur within regolith everywhere across the site. This regolith consists of alluvium, residual soils, saprolite, and variably fractured and weathered layered metamorphic rock. Inspection of drill cuttings and site outcrops indicates that water in the regolith is transmitted largely through fractures. In this regard, regolith behaves similar to unweathered bedrock, except that fractures are more numerous and better connected in the regolith, and will tend to have more isotropic hydraulic properties. Along the low-lying areas of the Catawba River and its tributaries, the water table occurs within surficial alluvial deposits overlying the residual soils and weathered bedrock. Groundwater discharges into creeks to the east and west of the landfill and to the Catawba River to the south. A groundwater potentiometric surface map, developed from static water level data obtained in December 2015, is presented as Drawing 1. The potentiometric surface map depicts groundwater flow primarily to the south. Depth to groundwater was measured in the compliance monitoring wells at the site prior to sampling. The December 2015 and historical groundwater elevations are provided in Table 5. The groundwater elevations were calculated relative to the surveyed measuring point (top of casing) for each monitoring well. Horizontal groundwater gradients along representative flow paths were estimated from the December 2015 groundwater contours shown on Drawing 1 and calculated gradients and flow velocities are summarized in Table 6. Horizontal gradients across the site ranged from 0.039 to 0.055 ft/ft, with an average of approximately 0.048 ft/ft. This is consistent with previous estimates. Linear groundwater flow velocities for wells screened in saprolite were computed using the modified Darcy equation: V = Ki/ne, where V = average linear velocity, K = hydraulic conductivity, i = horizontal hydraulic gradient, and ne = effective porosity. The mean of hydraulic conductivities from slug-tests conducted in 1995 and 2015 (K = 3.28 ft/day) was used in these calculations, along with an estimated effective porosity of ne = 0.40 (40%) for saprolite based on laboratory porosities for soil samples from the site. The estimated linear groundwater flow velocity under the facility ranged from 140-164 feet/year, with an average flow velocity of approximately 144 feet/year (Table 6). The modified Darcy equation makes the simplifying assumptions of a homogeneous and isotropic aquifer, which may yield inaccurate results when applied to heterogeneous and/or anisotropic conditions such as are believed to exist at this site. The groundwater flow direction and rate have shown no significant seasonal variations over several years of monitoring. The groundwater flow regime on this site is well constrained and predictable. Migration of groundwater contaminants are expected to follow the general groundwater flow paths and there are no known preferred pathways or barriers to groundwater flow that could significantly affect plume migration or the effectiveness of the groundwater monitoring network to monitoring plume migration. The current groundwater monitoring network remains sufficient for monitoring the groundwater at this facility. Corrective Action Evaluation Report (CAER) Joyce Engineering John’s River Waste Management Facility, Permit No. 12-03 April 2016 8 5.0 CORRECTIVE ACTION SUMMARY 5.1 Description of Corrective Action Remedy 5.1.1 MNA plus Phytoremediation The ACM for the John’s River Landfill facility (JOYCE, 2005a) examined multiple potential remedies for the groundwater impacts at the facility. Of the potential remedies, Monitored Natural Attenuation (MNA) plus phytoremediation was determined be the most cost-effective remedy that meets the requirements set forth in 15A NCAC 13B.1636. The CAP for the facility (JOYCE, 2008), as approved by NCDEQ in January 2009, presented MNA plus phytoremediation as the remedy to be implemented. The CAP also included a contingency plan in the event that MNA plus phytoremediation is shown to be ineffective at controlling migration of the contaminant plume. The contingency plan consists of in situ treatment of the groundwater to enhance biodegradation by the injection of proprietary materials (hydrogen-releasing compounds or oxygen-releasing compounds) or other technologies subject to NCDEQ approval. The CAP stipulated that after the four baseline sampling events are completed, the MNA data should be evaluated to determine the effectiveness of each of the MNA parameters in evaluating the MNA process on this site. The baseline period was completed with the December 2010 sampling event and reported in the 2011 CAER. The primary component to the primary selected remedy (MNA plus phytoremediation) is the monitoring. Monitoring requirements are similar for both MNA and phytoremediation, so the monitoring program is designed to evaluate both together. The CAP included a Corrective Action Monitoring Plan (CAMP) which established a program for semiannual monitoring of a network of compliance, performance, and sentinel wells for COCs and a list of natural attenuation indicator parameters. The specifications of the performance and Sentinel wells are included in the table presented in Section 2.1 of this report. The sentinel wells (MW-18 and MW-19) function to monitor for migration of the COC plumes toward the Catawba River. Samples collected from sentinel wells were obtained semiannually during the baseline sampling period for both COCs and MNA parameters; however, after the baseline period, the frequency was reduced to annual. 5.1.2 Control of Landfill Gas An addendum to the facility’s CAP was submitted to the NCDEQ in August 2013, adding control of landfill gas (LFG) as a remedy for groundwater impacts on the northeastern side of the old landfill between the old landfill and the new C&D expansion area (the “northeast area”). Typically, LFG is made up of approximately 55% methane, 44% carbon dioxide, and 1% other VOC’s, including vinyl chloride and benzene. Numerous studies have established that VOC’s present in LFG can readily partition into groundwater. Transfer of VOC’s from gas to groundwater can occur both in the monitor well and/or outside the monitor well. LFG is the most likely source of VOC detections in groundwater located upgradient or cross-gradient from the landfill. Corrective Action Evaluation Report (CAER) Joyce Engineering John’s River Waste Management Facility, Permit No. 12-03 April 2016 9 The 2005 ACM for this facility concluded that control of decomposition gas (LFG) was an appropriate and viable remedy for groundwater impacts at the John’s River Facility. It is likely that VOC exceedances in the northeast area are related to LFG; therefore, control of LFG migration is an appropriate remedy to address groundwater impacts for this area. The proposed mechanism for control of LFG was installation of passive gas vents in the MSW waste along the northeastern side of the MSW portion of the C&D-over-MSW landfill. In November 2013, JOYCE installed seven passive gas vents at the locations shown on Drawing 13. The following table summarizes the total depths (in feet below grade) for each of the gas vents: Gas Vent: GV-1 GV-2 GV-3 GV-4 GV-5 GV-6 GV-7 Total Depth: 25.5’ 35.0’ 43.0’ 43.0’ 45.0’ 47.0’ 36.0’ In September 2015, four additional passive gas vents were installed along the top of the landfill. The locations of these vents are also shown on Drawing 13, and their total depths are summarized below: Gas Vent: GV-8 GV-9 GV-10 GV-11 Total Depth: 34.0’ 24.0’ 24.0’ 24.0’ In accordance with the 2013 CAP addendum, piezometers PZ-36 and PZ-38 were converted to permanent monitoring wells MW-36 and MW-38 to act as performance wells for the control of LFG remedy. MW-36 and MW-38 are sampled semiannually for the current COC list, plus dissolved methane (CH4) and dissolved carbon dioxide (CO2) (although due to an oversight, MW-38 has not been monitored for CO2 – this will be corrected). There are also several additional wells and piezometers in the northeast area, which although not required by the CAP, have been sampled for the COC list plus dissolved CH4 and CO2. These include MW-15S, PZ-12, PZ-30S, PZ-31, PZ-34, and PZ-35. In addition to groundwater monitoring, several gas vents, gas probes, temporary probes, monitoring wells, and piezometers have been regularly monitored for methane gas to document the extent of landfill gas migration in the northeast area. These data are also relevant to evaluating the control of landfill gas as a groundwater remedy. 5.2 Physical & Chemical Changes in Aquifer Characteristics Field parameters such as temperature, pH, conductivity, and turbidity, have fluctuated; however, they have generally stayed in the normal range for fractured metamorphic rock aquifers in the North Carolina Piedmont and have not changed significantly over the CAER period. Historical data for these parameters are presented in Table 7. MW-13, the well with the highest concentrations of several of the COCs, has consistently shown low pH and low specific conductance, which are likely a result of ongoing biodegradation in the central part of the plume. Corrective Action Evaluation Report (CAER) Joyce Engineering John’s River Waste Management Facility, Permit No. 12-03 April 2016 10 5.3 Physical & Chemical Changes in Plume Characteristics The contaminant plume described in the facility’s Water Quality Assessment Report (WQAR) (JOYCE, 2000) listed the following COCs:  Benzene  1,4-dichlorobenzene (1,4-DCB)  Methylene chloride (dichloromethane)  Tetrachloroethylene (PCE)  Trichloroethylene (TCE) Between the 2000 WQAR and the 2011 CAER, the following three other constituents have had detections above their respective NC2L standards and were added to the COC list:  1,1-Dichloroethane (1,1-DCA)  1,2-Dichloroethane (1,2-DCA)  Vinyl chloride (VC) These additional NC2L exceedances did not represent increases in concentrations in the groundwater; rather, they represent changes in reporting requirements, laboratory reporting limits, or NC2L standards. There have been no significant changes in the chemical characteristics of the down-gradient portion of the plume. During the present CAER period (2011-2015), two additional constituents have been detected above their respective NC2L Standard: alpha-BHC and beta-BHC. Alpha-BHC was added to the COC list after the December 2012 sampling event, and beta-BHC had a confirmed NC2L exceedance for the first time in the December 2015 sampling event. These constituents are both pesticides, which have appeared sporadically in various wells at the site. They both have very low NC2L standards, so that any quantified detection is an exceedance; however, the highest concentrations of alpha-BHC and beta-BHC to date have been 0.19 and 0.33 µg/L, respectively. Drawings 2 through 10 depict isoconcentration maps (plume maps) for each of the constituents with recent exceedance of the NC2L standards. The isoconcentration maps are based primarily on the analytical results from the December 2015 sampling event; however, since MW-18 and MW-19 were not be sampled during that event, the data from the May 2015 event are used. Drawing 11 shows the Total VOC isoconcentration map, which depicts the sum of the concentrations of all detected volatile organic compounds (VOCs) on the site (both COCs and non-COCs). Drawing 12 shows two vertical cross-sections through the contaminant plume, and includes Total VOC contours. In general, the COC plumes appear to be stable or decreasing in both vertical and horizontal extent. The benzene plume seems to be slowly increasing in the vicinity of MW-10; however, it is decreasing in concentration everywhere else. Benzene concentrations in MW-10 exceeded the NC2L standard for the first time in June 2013. No other constituent plumes appear to be expanding in this direction. Since the John’s River constitutes a hydraulic barrier along the eastern property boundary, and since there have been no detections in the nearby surface water Corrective Action Evaluation Report (CAER) Joyce Engineering John’s River Waste Management Facility, Permit No. 12-03 April 2016 11 sampling point SMP-5, there is no reason to believe the benzene plume is migrating off site in this area. Since there have been no NC2L exceedances in MW-18, MW-19, the downgradient extent of the plume appears to be stable and remains constrained to the facility property. Since no COCs have been detected in the deep well, MW-16D, the vertical extent of the plume is also well constrained and shows no significant changes. 5.4 Refining the Site Conceptual Model There is no data indicating any need to modify the site conceptual model governing groundwater flow and migration of the contaminant plume at this time; however, one addition to the site conceptual model relates to the role of landfill gas migration. Typically, LFG is made up of approximately 55% methane, 44% carbon dioxide, and 1% other VOC’s, including vinyl chloride, benzene, and other COCs (Allen, et al, 1997; Deipser and Stegmann, 1994; Cowie, 2004). Numerous studies have established that VOC’s present in LFG can readily partition into groundwater. Transfer of VOC’s from gas to groundwater can occur both in the monitor well and/or outside the monitor well as water percolates through the vadose zone. LFG is the most likely source of VOC detections in groundwater located upgradient or cross-gradient from the landfill. It is likely VOC exceedances north and northeast of the C&D-over-MSW landfill are related to LFG; therefore, control of LFG migration is an appropriate remedy to address groundwater impacts for this area. 5.5 Impacts of Corrective Action - MNA and Phytoremediation Monitoring requirements are similar for both MNA and phytoremediation, so the monitoring program is designed to evaluate both together. The emphasis in this section will be on evaluation of MNA; however, the impacts of MNA and phytoremediation are linked. 5.5.1 MNA Parameters and Biodegradation Screening Matrix In accordance with the CAP for the facility, MNA baseline sampling was initiated with the June 2009 sampling event and continued through the November 2010 sampling event. The baseline data were evaluated in a CAER dated May 2011. The December 2015 sampling event was the tenth post-baseline event. MNA parameter data were obtained for the following wells: the site background well (MW-21); and downgradient compliance/performance wells MW-11, MW-12, and MW-16S. MNA field parameters included temperature, pH, specific conductance, oxidation-reduction potential (ORP), turbidity, dissolved oxygen, dissolved carbon dioxide and ferrous iron. MNA laboratory parameters included dissolved hydrogen, alkalinity, TOC, dissolved methane, nitrate, sulfate, and chloride. Table 7 summarizes the MNA data for the December 2015 event, and historical MNA data are presented in Appendix H. Field data logs and laboratory reports are included in Appendices A and B, respectively. The MNA parameter data were evaluated in general accordance with the United States Environmental Protection Agency’s (EPA’s) Technical Protocol Manual (EPA, 1998) to determine whether the conditions are conducive to, or whether there is evidence for anaerobic Corrective Action Evaluation Report (CAER) Joyce Engineering John’s River Waste Management Facility, Permit No. 12-03 April 2016 12 degradation of the chlorinated hydrocarbons. Specifically, the results were evaluated according to the weighted system presented in Table 2.3 of the Technical Protocol Manual, referred to hereafter as the Biodegradation Screening Matrix. According to this manual, a score less than 5 indicates that there is inadequate evidence for anaerobic natural attenuation, a score of 6 to 14 indicates that there is limited evidence for anaerobic natural attenuation, a score of 15 to 20 indicates that there is adequate evidence for anaerobic natural attenuation, and a score greater than 20 indicates that there is strong evidence that anaerobic natural attenuation is occurring. The MNA evaluation was performed based on the results from the December 2015 sampling event for downgradient wells within the contaminant plume, compared where appropriate to the background well (MW-21). The Biodegradation Screening Matrix is presented in Table 8 of this report. One difficulty in evaluation of the Screening Matrix is that the matrix assumes some compounds (such as, but not limited to methane and vinyl chloride) are daughter products of biodegradation within the plume; however, at a landfill we cannot eliminate the possibility that they may be contaminants released directly from the landfill. If we include the scores for these potential daughter products, our total score could be artificially high; on the other hand, if we exclude them, the score might be artificially low. Table 8 presents scoring results both with and without the questionable daughter product scores. The fact that we are past the baseline sampling period and the sampling frequencies for some parameters have been reduced creates another difficulty. How should we score parameters that were not monitored during the December 2015 sampling event? We have historical data for these parameters indicating that some would likely contribute points and some would not. To ignore the historical data and treat all unmonitored parameters as if they were negative results would give an artificially low score; however, using data from previous events may not give an accurate result. Table 8 presents scoring results both with and without points based on historical rather than current data. The following table summarizes the scoring results from Table 8 for all four options for interpreting the data. The scores ranged from 14 (limited evidence of natural attenuation) to 30 (strong evidence of natural attenuation). In reality, the best score is probably in the middle of this range, indicating good evidence of natural attenuation. DP = Points for possible daughter products. HD = Points based on historical data. Points Awarded including DP Points Awarded excluding DP Points Awarded excluding HD 27 14 Points Awarded including HD 28 14 Corrective Action Evaluation Report (CAER) Joyce Engineering John’s River Waste Management Facility, Permit No. 12-03 April 2016 13 5.5.2 Biochlor Modeling and Mass-Balance Assessment Anaerobic degradation of organic constituents, specifically chlorinated ethenes and ethanes, was modeled using the EPA Biochlor System. The Biochlor model was set up to model flow, dispersion, advection, adsorption, and biotransformation along a generalized flow line running from the waste unit south toward the river. The concentration in the source area was set equal to the December 2015 sampling results from MW-13. Wells MW-11, MW-12, and MW-16S were included in the modeling based on their respective distances from the southern edge of waste as summarized below: WELL: MW-13 MW-11 MW-12 MW-16S MW-18 MW-19 MODELED DISTANCE FROM THE SOURCE (feet): 0 20 60 135 210 430 Modeling was done for both ethenes (a.k.a. - ethylenes) and ethanes. The ethene degradation sequence goes from tetrachloroethylene (PCE) to trichloroethylene (TCE), to dichloroethylenes (DCE), to vinyl chloride (VC). The ethane degradation sequence goes from trichloroethane (TCA) to dichloroethanes (DCA) to chloroethane (CA). Note that DCE is the sum of detected cis-1,2-dichloroethylene, trans-1,2-dichlorotheylene, and 1,1-dichloroethylene. Similarly, DCA is the sum of 1,1-dichloroethane and 1,2-dichloroethane. The plume was assumed to be 1600 feet wide and 500 feet long, based on the width of the plume at the southern edge of waste and the average distance from the southern edge of waste to the river. Simulation time was 17 years, based on the time between closure of the MSW landfill and the October 2014 sampling event. A seepage velocity of 144.0 feet/year was used based on groundwater flow rate calculations for the December 2015 event as presented in Table 6 of this report. The input and output of the Biochlor modeling are presented in Appendix A. The results of the Biochlor modeling indicate reasonable agreement between the modeled plume degradation and the analytical results for both ethenes and ethanes. In general, the observed down-gradient concentrations were less than or equal modeled concentrations except for VC and CA, which are the final daughter products. The fact that VC and CA are higher downgradient is evidence that reductive dehalogenation is occurring. This supports the contention that biodegradation is proceeding at an acceptable rate. The mass rate calculations from the Biochlor modeling are summarized below. Cells labeled “indeterminate” in the following tables indicate that the data were insufficient for the software to calculate the values. The results indicate a large percentage of the contaminants are being removed by Biotransformation. Ethenes PCE TCE DCE VC Mass Removed 2.4 Kg 3.7 Kg 8.3 Kg indeterminate % Biotransformed 80.8% 73.0% 60.9% indeterminate % Change in Mass Rate 99.5% 98.2% 92.3% indeterminate Ethanes DCA Mass Removed 14.6 Kg % Biotransformed 79.6% % Change in Mass Rate 99.3% Corrective Action Evaluation Report (CAER) Joyce Engineering John’s River Waste Management Facility, Permit No. 12-03 April 2016 14 5.5.3 Trend Charts and Plume Stability Charts 1-10 show the concentration of key constituents versus time for the wells MW-10, MW-11, MW-12, MW-13, and MW-16S from the earliest recorded detections through December 2015. In general, most constituents in most wells show decreasing or stable trends, especially over the last 3-5 years. The clearest long-term increasing trend is for benzene and MW-13; however, the benzene trend appears to have stabilized in the last few years. 1,4-dichlorobenzene also shows a clear upward trend in MW-13. MW-13 is located farther north (upgradient) than the other downgradient wells and is representative of the central part of the plume whereas MW-11, MW-12, and MW-16S are located nearer the southern leading edge of the plume, and MW-10 is located near the western edge of the plume. The fact that the concentrations in the central part of the plume appear to be stable or increasing while the concentrations near the leading edge seem to be stable or decreasing supports the contention that natural attenuation is adequately controlling the plume. Alpha-BHC has had sporadic detections in MW-13 over the last several sampling events, and beta-BHC had a confirmed detection in MW-11 for the first time during the December 2016 event. There is not enough consistent data for these constituents to establish any trends. 5.5.4 Plume Maps and Cross-Sections Drawings 2-9 depict the extent of the plumes for the eight VOCs with NC2L exceedances during the December 2015 sampling event. These include: benzene; 1,4-dichlorobenzene (1,4-DCB); 1,1-dichloroethane (1,1-DCA); 1,2-dichloroethane (1,2-DCA); tetrachloroethylene (PCE); trichloroethylene (TCE); vinyl chloride; and methylene chloride. These eight VOCs represent the primary COCs. Alpha-BHC and beta-BHC have only been detected sporadically, and generally not in more than one well at a time. The beta-BHC plume is shown in Drawing 10, but there is no plume map for alpha-BHC because it was not detected in any wells during the December 2015 event. Drawing 11 depicts the total VOC plume, which is the sum of all detected VOCs, including estimated detections below the SWSL and VOCs that are not COCs. Drawing 12 shows two vertical cross-sections (profiles) through the C&D-over-MSW landfill area showing the vertical extent of the total VOC plume. In general, the COC plumes appear to be stable or decreasing in both vertical and horizontal extent. The benzene plume seems to be slowly increasing in the vicinity of MW-10; however, it is decreasing in concentration everywhere else. Benzene concentrations in MW 10 exceeded the NC2L standard for the first time in June 2013. No other constituent plumes appear to be expanding in this direction. Since the John’s River constitutes a hydraulic barrier along the eastern property boundary, and since there have been no detections in the nearby surface water sampling point SMP-5, there is no reason to believe the benzene plume is migrating off site in this area. The PCE, TCE, and methylene chloride plumes have decreased to below the GPS in all wells except MW-13, which is in the central part of the plume. PCE and TCE degrade to vinyl chloride under reductive dehalogenation. The fact that PCE and TCE are decreasing at the Corrective Action Evaluation Report (CAER) Joyce Engineering John’s River Waste Management Facility, Permit No. 12-03 April 2016 15 downgradient edge of the plume, coupled with the fact that vinyl chloride is found only near the downgradient edge of the plume, is strong evidence that natural attenuation is occurring and effectively controlling the migration of VOCs. 5.6 Phytoremediation The subject property between the contaminant plume and the Catawba River is heavily wooded and largely wetland. The existing flora are ideal for phytoremediation of groundwater contaminated by VOCs; therefore, no additional planting or maintenance of the flora has been needed. The trees and other flora remain healthy and thriving. There is no way to quantify the impact of phytoremediation in this setting except through monitoring the contaminant plume. The above discussion of monitoring for MNA largely covers monitoring for phytoremediation as well, especially the trend analyses and plume stability discussions. 5.7 Off-site Migration of COCs The benzene plume seems to be slowly increasing in the vicinity of MW-10; however, it is decreasing in concentration everywhere else. Benzene concentrations in MW 10 exceeded the NC2L standard for the first time in June 2013. No other constituent plumes appear to be expanding in this direction. Since the John’s River constitutes a hydraulic barrier along the eastern property boundary, and since there have been no detections in the nearby surface water sampling point SMP-5, there is no reason to believe the benzene plume is migrating off site in this area. There have been no quantified detections of COCs or exceedances of NC2L standards at sentinel wells MW-18 and MW-19 during this CAER period; however, there have been some estimated detections of 1,1-DCA and 1,2-DCA below the Solid Waste Section Reporting Limit (SWSL). The concentrations of most COCs in the downgradient wells appear to be either stable of decreasing. Even if impacted groundwater impinges on the Catawba River, dilution will immediately reduce constituents to undetectable levels. There are no other areas where the plume is close to a property boundary. 5.8 Methane Migration and Control of Landfill Gas There are three primary sources of data relevant to evaluating the effectiveness of control of landfill gas as a groundwater remedy for the northeast area. These include: 1) changes in concentrations of COCs and/or the extent of the COC plumes in the groundwater; 2) concentrations of dissolved gases (methane and carbon dioxide) in the groundwater; and 3) concentrations and extent of migrating methane gas in the vadose zone. MW-36 and MW-38 act as performance wells for the control of LFG remedy. MW-36 and MW-38 are sampled semiannually for the current COC list, plus dissolved methane (CH4) and dissolved carbon dioxide (CO2) (although due to an oversight, MW-38 has not been monitored for CO2 – this will be corrected). There are also several additional wells and piezometers in the northeast area, which although not required by the CAP, have been sampled for the COC list plus dissolved CH4 and CO2. These include MW-15S, PZ-12, PZ-30S, PZ-31, PZ-34, and PZ-35. Corrective Action Evaluation Report (CAER) Joyce Engineering John’s River Waste Management Facility, Permit No. 12-03 April 2016 16 Table 9 presents the analytical results for all the wells in the northeast area, including dissolved CH4 and CO2. These data are also included in all of the COC plume maps (Drawings 2-11) and cross-sections (Drawing 12), and were used to constrain the northeast portions of the plumes. In addition to groundwater monitoring, several gas vents, gas probes, temporary probes, monitoring wells, and piezometers have been regularly monitored for methane gas to document the extent of landfill gas migration in the northeast area. Table 10 summarizes the methane gas monitoring data for the northeast area from February 2012 through February 2016. Chart 11 shows methane gas concentrations vs. time. Drawing 13 depicts the methane gas plume in the northeast area based on the most recent (February 2016) data. The COC plume maps for most constituents show the northeastern extent of the groundwater plumes roughly coincide with the extent of gas migration. A few of the COC plumes (1,2-DCA, PCE, methylene chloride, and vinyl chloride) do not extend as far northeast as the methane gas plume, and beta-BHC has only been detected in MW-11. The correlation of the edge of the VOC plume with the edge of the methane gas migration zone strongly supports the contention that the exceedances in the northeast area are due to partitioning of VOCs from landfill gas. There has been no significant change (either increase or decrease) in either the extent of the COC plumes in this area, or the extent of the methane gas plume since the installation of gas vents in November 2013. Chart 11 shows the concentrations of methane gas in the northeast area versus time. Methane concentrations have fluctuated significantly in some probes, wells, etc.; however, there are no indications of trends or significant changes in concentrations since the installation of gas vents in November 2013. Similarly, concentrations of dissolved CH4 and CO2 in the groundwater (Table 9) have fluctuated, but there is not sufficient data to determine if there are any long-term trends. Although we had hoped to see significant reductions in the methane gas plume as a result of the installation of the passive gas vents, and at least some evidence of decreasing impact of LFG on the groundwater in the northeast area, it may still be too soon to tell how effective the remedy will be in the long-term. 6.0 CONCLUSIONS During this CAER period (2011-2015), several organic constituents continue to exceed their respective NC2L Groundwater Standards at the John’s River Landfill; however, these exceedances are generally consistent with previous sampling events and are being addressed by the CAP for the facility. During this CAER period, two additional constituents have been detected above their respective NC2L Standard: alpha-BHC and beta-BHC. Alpha-BHC was added to the COC list after the December 2012 sampling event, and beta-BHC had a confirmed NC2L exceedance for the first time in the December 2015 sampling event. Based on evaluation of MNA data, Biochlor modeling, trends of key constituents, and the lateral and vertical extend of the plumes for all exceeding constituents, JOYCE concludes that the selected remedy of natural attenuation plus phytoremediation is adequately controlling the Corrective Action Evaluation Report (CAER) Joyce Engineering John’s River Waste Management Facility, Permit No. 12-03 April 2016 17 contaminant plume downgradient of the old C&D-over-MSW landfill. The contaminant plumes appear to remain fully contained within the facility boundary. A new remedy, control of landfill gas, was approved in August 2013 for the area northeast (upgradient to side-gradient) of the C&D-over-MSW landfill. In November 2013, seven gas vents were installed on the northeast slope of the landfill. Review of COC plumes, dissolved methane and carbon dioxide, and methane gas migration data from this area support the contention that the COC exceedances in the northeast area are due to partitioning of VOCs from migrating landfill gas. Since the gas vents were installed in late 2013, there has been no obvious reduction of the methane gas plume or of the concentrations of VOCs in the northeast area; however, there has also been no increase in either the gas or groundwater plumes. It may be too early to evaluate the long-term effectiveness of this remedy. The primary purpose of the remedy in the northeast area is to keep gas impacts from extending to the expansion landfill area, and the remedy appears to be adequately fulfilling that purpose. JOYCE recommends that beta-BHC be added to the COC list for this facility. The COC list will now include:  Benzene  1,4-dichlorobenzene (1,4-DCB)  Methylene chloride (dichloromethane)  Tetrachloroethylene (PCE)  Trichloroethylene (TCE)  1,1-Dichloroethane (1,1-DCA)  1,2-Dichloroethane (1,2-DCA)  Vinyl chloride (VC)  alpha-BHC  beta-BHC Overall, the current Corrective Action Program is effective in controlling groundwater contaminant migration and is protective of human health and the environment. JOYCE does not recommend any additional remedies or any changes in the Corrective Action Program for the facility at this time. The next CAER will be due 120 days after the second semiannual sampling event of 2020. 7.0 REFERENCES Allen, M.R., Braithwaite, A., and Hills, C.C. (1997). Trace Organic Compounds in Landfill Gas at Seven U.K. Waste Disposal Sites. Environmental Science and Technology. v. 31, p. 1054-1061. Cowie, S. (2004). Emission of Non-methane Organic Compounds (NMOCs) and hazardous air Pollutants (HAPs) from Decomposing Refuse and Individual Waste Components and Under Different Conditions. Master’s Thesis, North Carolina State University. Corrective Action Evaluation Report (CAER) Joyce Engineering John’s River Waste Management Facility, Permit No. 12-03 April 2016 18 Deisper, A. and Stegmann, R. (1994). The Origin and Fate of Volatile Trace Components in Municipal Solid Waste Landfills. Waste Management & Research. v. 12, p. 129-139. Hinchee, R.E., A. Leeson, L. Semprini, and S.K. Ong. 1994. Bioremediation of Chlorinated and Polycyclic Aromatic Hydrocarbon Compounds. Lewis Publishers, Boca Raton. Interstate Technology and Regulatory Cooperation Work Group (ITRC). September 1999. Natural Attenuation of Chlorinated Solvents in Groundwater: Principles and Practices. Technical/Regulatory Guidelines. Interstate Technical Regulatory Council (ITRC). 2003. Technical and Regulatory Guidance Document for Constucted Treatment Wetlands. Joyce Engineering, Inc. (JOYCE), 1994. Transition Plan, Johns River Waste Management Facility. April 1994. JOYCE, 2000. Water Quality Assessment Report, Johns River Waste Management Facility. January 2000. JOYCE, 2004. Update on Groundwater Assessment Activities, Johns River Waste Management Facility. October 2004. JOYCE, 2005a. Assessment of Corrective Measures Report, Johns River Waste Management Facility. February 2005. JOYCE, 2005b. Quantitative Risk Assessment, Johns River Waste Management Facility. February 2005. JOYCE, 2008. Corrective Action Plan, Johns River Waste Management Facility. June 2008. JOYCE, 2011. Corrective Action Evaluation Report, Johns River Waste Management Facility. May 2011. JOYCE, 2013. Addendum to the Corrective Action Plan, Johns River Waste Management Facility. August 2013. National Research Council (NRC), 2000. Natural Attenuation for Groundwater Remediation. National Academy Press, Washington, D.C. pp. 108-111. North Carolina Department of Environmental Quality (NC-NCDEQ), 1997. North Carolina Solid Waste Management Rules. 15 NCAC 13B. January 1, 1997; amended April 2011. NCDEQ, 2007. North Carolina Solid Waste Section Guidelines for Corrective Action at Solid Waste Management Facilities. March 2007. Corrective Action Evaluation Report (CAER) Joyce Engineering John’s River Waste Management Facility, Permit No. 12-03 April 2016 19 Sumsion, C.T., and Laney, R.L., 1967, Geology and Ground-water Resources of the Morganton area North Carolina. N.C. Department of Water Resources, Ground Water Bulletin No. 12, 119 p. U.S. Department of Energy (USDE). May 1999. Decision-Making Framework Guide for the Evaluation and Selection of Monitored Natural Attenuation Remedies at Department of Energy Sites. U.S. Environmental Protection Agency (USEPA), 1992. Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance. July 1992. USEPA. October 1988. Interim Final Guidance for Conducting Remedial Investigations and Feasibility Studies under CERCLA. Office of Solid Waste and Emergency Response (OSWER) Directive 9355.3-01, EPA/540/G-89/004. USEPA. February 1991. Conducting Remedial Investigations/Feasibility Studies for CERCLA Municipal Landfill Sites. OSWER Directive 9355.3-11, EPA/540/P-91/001. USEPA. May 1995. How to Evaluate Alternative Cleanup Technologies for Underground Storage Tank Sites: A Guide for Corrective Action Plan Reviewers. Chapters 2 (Soil Vapor Extraction) and 10 (In-Situ Groundwater Bioremediation). USEPA. May 1996. Seminars on Bioremediation of Hazardous Waste Sites: Practical Approaches to Implementation. ORD,EPA/625/K-96/001. Chapters 15 (Natural Attenuation of Groundwater) and 17 (Natural Attenuation of Landfills). USEPA and U.S. Air Force (USAF). July 1993. Remediation Technologies Screening Matrix Reference Guide, Version I. Joint Project of OSWER and Environics Directorate, PB93- 2118212. 8.0 ACRONYMS ACM Assessment of Corrective Measures (Report) AMSL Above Mean Sea Level AOC Area of Concern BGS Below Ground Surface C&D Construction and Demolition Waste CAP Corrective Action Plan (Report) CAER Corrective Action Evaluation Report (Report) CAMP Corrective Action Monitoring Plan (Report) CAS Chemical Abstracts Service CFR Code of Federal Regulations CPVC Chlorinated Poly Vinyl Chloride COC Contaminant of Concern (for corrective action) COC Chain of Custody (for sampling and lab reports) Corrective Action Evaluation Report (CAER) Joyce Engineering John’s River Waste Management Facility, Permit No. 12-03 April 2016 20 DL Detection Limit (for laboratory data) DO Dissolved Oxygen EPA United States Environmental Protection Agency (or USEPA) GWPS Groundwater Protection Standards (Established by DENR-SWS) JOYCE Joyce Engineering, Inc. LFG Landfill Gas MNA Monitored Natural Attenuation MSW Municipal Solid Waste MW Monitoring Well NC2B North Carolina Surface Water Standards found in 15A NCAC 2B NC2L North Carolina Groundwater Standards found in 15A NCAC 2L NCAC North Carolina Administrative Code NCDENR North Carolina Dept. of Environment and Natural Resources (now the NCDEQ) NCDEQ North Carolina Dept. of Environmental Quality (formerly the NCDENR) NCGS North Carolina Geological Survey NCSWMR North Carolina Solid Waste Management Regulations (15A NCAC 13B.1600) ND Not Detected (for laboratory data) NES Nature and Extent Study (Report) O&M Operations and Maintenance QL Quantitation Limit (for laboratory data) QRA Quantitative Risk Assessment (Report) RL Reporting Limit (for laboratory data) RQD Rock Quality Designation SPT Standard Penetration Test SSI Statistically Significant Increase (above background concentrations) SWQS Surface Water Quality Standards SWS Solid Waste Section (of DENR-Division of Waste Management) SWSL North Carolina Solid Waste Section Reporting Limits TOC Top of Casing (Well) USCS Unified Soil Classification System USEPA United States Environmental Protection Agency (or EPA) USGS United States Geological Survey VOC Volatile Organic Compound WQMP Water Quality Monitoring Plan (Report) TABLES Table 1 Historical Detected Inorganic Constituents in Compliance Wells Table 2 Historical Detected Organic Constituents in Compliance Wells Table 3 Historical Detected Constituents in Performance and Sentinel Wells Table 4 Historical Detected Constituents in Surface Water Table 5 Historical Groundwater Elevation Data Table 6 Estimated Hydraulic Gradients and Flow Velocities Table 7 Historical MNA Parameters Table 8 Biodegradation Screening Matrix Table 9 COCs and LFG Parameters in Northeast Area Table 10 Methane Gas in Northeast Area Zone TABLE 1: HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Inorganic Compounds Antimony 30-May-07 --- 6 --- ND --- --- ND ND 1.09 J ND ND ND ND GWPS = 1.4 µg/L (10/23/07)29-Nov-07 --- 6 --- ND --- --- ND ND 1.94 J ND ND ND ND 29-May-08 2.6 6.0 --- ND --- --- ND ND ND ND ND ND ND 6-Nov-08 2.6 6.0 --- ND --- --- ND ND 2.7 J ND 5.9 J ND ND 3-Jun-09 2.6 6.0 --- ND --- --- ND ND ND ND ND 3.2 J ND 18-Nov-09 2.6 6.0 --- ND --- --- ND ND ND ND ND ND ND 16-Jun-10 2.6 6.0 --- ND --- --- ND ND 2.8 J ND ND ND ND GWPS = 1 µg/L (8/1/10) 1-Dec-10 2.6 6.0 --- ND ND --- ND 3.5 J 2.9 J ND ND ND ND 1-Jun-11 2.6 6.0 --- ND ND --- ND ND ND ND ND 2.9 J ND 20-Dec-11 5.0 6.0 --- --- ND --- ND ND ND ND ND ND ND 30-May-12 5.0 6.0 --- --- ND --- ND ND ND ND ND ND ND 5-Dec-12 5.0 6.0 --- --- ND --- ND ND ND ND ND ND ND 12-Jun-13 5.0 6.0 --- --- ND --- ND ND ND ND ND ND ND 28-Oct-13 5.0 6.0 --- --- ND --- ND ND ND ND ND ND ND 6-May-14 5.0 6.0 --- --- ND --- ND ND ND ND ND ND ND 23-Oct-14 5.0 6.0 --- --- * ND ND ND ND ND ND ND ND 20-May-15 3.8 6.0 --- --- --- ND ND ND ND ND ND ND ND 8-Dec-15 3.8 6.0 --- --- --- ND ND ND 6.3 ND ND ND ND Lab Re-run Analyses> 8-Dec-15 3.8 6.0 --- --- --- --- --- ---6.2 --- --- --- --- Resample> 4-Feb-16 3.8 6.0 --- --- --- --- --- --- ND --- --- --- ND Arsenic 30-May-07 --- 10 --- ND --- --- ND 2.2 B ND 3.6 B ND 2.1 B 2.6 J NC 2L = 50 µg/L (10/23/07) 29-Nov-07 --- 10 --- 2.5 J --- --- ND ND ND ND 2.1 J ND ND 29-May-08 2.7 10.0 --- ND --- --- ND ND ND ND ND ND ND 6-Nov-08 2.7 10.0 --- ND --- --- ND 3.1 B ND 3.2 B 3 B ND 4.1 J 3-Jun-09 2.7 10.0 --- ND --- --- ND ND ND ND ND 3.2 J ND 18-Nov-09 2.7 10.0 --- ND --- --- 3.0 J ND ND ND ND ND ND NC 2L = 10 µg/L (01/01/10) 16-Jun-10 2.7 10.0 --- ND --- --- ND 4.6 J ND ND 3.0 J ND ND 1-Dec-10 2.7 10.0 --- ND ND --- ND ND ND ND ND ND ND 1-Jun-11 2.7 10.0 --- ND ND --- ND ND ND ND ND ND ND 20-Dec-11 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 30-May-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 5-Dec-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 12-Jun-13 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 28-Oct-13 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 6-May-14 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 23-Oct-14 5.0 10.0 --- --- * ND ND ND ND ND ND ND ND 20-May-15 2.5 10.0 --- --- --- ND ND ND ND ND ND ND ND 8-Dec-15 2.5 10.0 --- --- --- ND ND ND ND ND ND ND ND Barium 15-Sep-94 --- 100 1320 NI NI NI 194 5580 ND 584 NI NI ND 1-Oct-94 --- 100 --- NI NI NI --- 1030 --- --- NI NI ND 18-Jan-95 --- 100 981 NI NI NI 122 1490 ND 355 NI NI ND 6-Feb-95 --- 100 435 NI NI NI 124 350 ND 311 NI NI ND 1-Mar-95 --- 100 556 NI NI NI 260 732 196 528 NI NI ND 1-Aug-95 --- 100 199 NI --- --- 250 688 ND 408 NI NI ND 1-Jan-96 --- 100 455 NI --- --- 228 734 196 ND NI NI ND 1-Feb-96 --- 100 306 NI --- --- 211 321 288 ND NI NI ND 1-May-96 --- 100 170 NI --- --- ND 453 319 ND NI NI ND 1-Oct-96 --- 100 302 NI --- --- 234 447 102 ND NI NI ND 1-May-97 --- 100 330 NI --- --- 170 360 400 ND NI NI ND 1-Nov-97 --- 100 800 NI --- --- 200 600 800 100 NI NI ND 1-May-98 --- 100 400 NI --- --- 200 400 1200 200 NI NI ND 1-Nov-98 --- 100 140 NI --- --- 270 310 880 ND NI NI ND 11-May-99 --- 5 240 200 --- --- 70 130 200 60 220 16 ND 18-Oct-99 --- 500 1900 ND --- --- ND ND 1400 ND ND ND ND 3-May-00 --- 500 ND ND --- --- ND ND ND ND 730 ND ND 7-Nov-00 --- 500 ND ND --- --- ND ND ND ND ND ND ND 31-May-01 --- 500 ND ND --- --- ND ND ND ND ND ND ND 7-Nov-01 --- 500 ND ND --- --- ND ND ND ND ND ND ND 22-May-02 --- 500 ND ND --- --- ND ND ND ND ND ND ND 14-Nov-02 --- 500 ND ND --- --- ND ND ND ND ND ND ND 14-May-03 --- 500 ND ND --- --- ND ND ND ND ND ND ND 20-Nov-03 --- 500 ND ND --- --- ND ND ND ND ND ND ND 6-May-04 --- 500 ND ND --- --- ND ND ND ND ND ND ND 10-Nov-04 --- 500 ND ND --- --- ND ND ND ND ND ND ND 5-May-05 --- 500 ND ND --- --- ND ND ND ND ND ND ND 3-Nov-05 --- 500 --- ND --- --- ND ND ND ND ND ND ND 25-May-06 --- 500 --- ND --- --- ND ND ND ND ND ND ND 2-Nov-06 --- 500 --- ND --- --- ND ND ND ND ND ND ND 30-May-07 --- 100 --- 52.0 J --- --- 48.1 J 132 88.4 J 66.9 J 50.9 J 8.0 J 0.20 J NC 2L = 2,000 µg/L (10/23/07) 29-Nov-07 --- 100 --- 214 --- --- 54.8 J 232 97.0 J 75.3 J 57.9 J 8.6 J 0.50 J 29-May-08 0.20 100 --- 67.9 J --- --- 41.5 J 148 71.0 J 77.0 J 43.7 J 7.9 J ND 6-Nov-08 0.20 100 --- 82.3 J --- --- 45.5 B 118 81.2 J 90.6 J 66.7 J 7.1 B 9.6 J 3-Jun-09 0.20 100 --- 34.2 B --- --- 26.9 B 119 67.6 B 66.9 B 49.5 B 9.8 B 15.9 J 18-Nov-09 0.20 100 --- 78.9 B --- --- 36.3 B 116 88.6 B 81.0 B 46.6 B 7.8 B 20.1 J NC 2L = 700 µg/L (01/01/10) 16-Jun-10 0.20 100 --- 58.1 J --- --- 50.5 J 296 103 73.4 J 47.0 J 8.6 J 0.77 J 1-Dec-10 0.20 100 --- 60.1 J 376 --- 59.6 J 134 94.1 J 78.7 J 37.5 J 16.3 J ND 1-Jun-11 0.20 100 --- 55.6 J 164 --- 43.3 J 154 74.3 J 74.4 J 44.7 J 12.3 J ND 20-Dec-11 5.0 100 --- --- 119 --- 50.9 J 138 76.6 J 78.3 J 46.7 J 10.5 J ND 30-May-12 5.0 100 --- --- 96.7 J --- 40.6 J 137 77.7 J 74.5 J 67.8 J 9.1 J ND 5-Dec-12 5.0 100 --- --- 63.0 J --- 53.3 J 148 89.8 J 81.4 J 43.6 J 10.5 J ND 12-Jun-13 5.0 100 --- --- 59.6 B --- 28.3 B 167 82.3 J 83.6 J 48.1 B 13.2 B 13.6 J 28-Oct-13 5.0 100 --- --- 47.9 J --- 47.4 J 194 93.8 J 70.7 J 49.4 J 9.6 J ND 6-May-14 5.0 100 --- --- 73.6 J --- 37.3 J 129 89.9 J 73.9 J 45.5 J 8.2 J ND 23-Oct-14 5.0 100 --- --- * 20.3 J 53.4 J 127 74.6 J 76.0 J 46.3 J 13.3 J ND 20-May-15 2.5 100 --- --- --- 17.9 47.5 J 145 75.5 J 76.9 J 44.6 J 8.4 J ND 8-Dec-15 2.5 100 --- --- --- 17.6 J 45.6 J 140 132 82.6 J 50.6 J 8.0 J ND Background Downgradient Burke County - John's River C and D over MSW Landfill Permit 12-03 Page 1 of 11 Joyce Engineering TABLE 1: HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Background Downgradient Beryllium 1-May-97 --- 1 ND NI --- --- ND ND 1.0 ND NI NI ND 1-Nov-97 --- 1 1.0 NI --- --- ND 3.0 ND ND NI NI ND 1-May-98 --- 1 ND NI --- --- ND ND 3.0 ND NI NI ND 1-Nov-98 --- 1 ND NI --- --- ND ND 1 ND NI NI ND 11-May-99 --- 2 ND ND --- --- ND ND ND ND 4.3 ND ND 18-Oct-99 --- 2 8.0 3.0 J --- --- 2.0 J 2.0 J 13.0 ND ND ND ND 3-May-00 --- 2 ND ND --- --- ND ND ND ND 8.0 ND ND 7-Nov-00 --- 2 ND 2.0 --- --- ND ND ND ND ND ND ND 31-May-01 --- 2 ND ND --- --- ND ND ND ND ND ND ND 7-Nov-01 --- 2 ND ND --- --- ND ND ND ND ND ND ND 22-May-02 --- 2 ND ND --- --- ND ND ND ND ND ND ND 14-Nov-02 --- 2 ND ND --- --- ND ND ND ND ND ND 2.1 14-May-03 --- 2 ND ND --- --- ND ND ND ND ND ND ND 20-Nov-03 --- 2 ND ND --- --- ND ND ND ND ND ND ND 6-May-04 --- 2 ND ND --- --- ND ND ND ND ND ND ND 10-Nov-04 --- 2 ND ND --- --- ND ND ND ND ND ND ND 5-May-05 --- 2 ND ND --- --- ND ND ND ND ND ND ND 3-Nov-05 --- 2 --- ND --- --- ND ND ND ND ND ND ND 25-May-06 --- 2 --- ND --- --- ND ND ND ND ND ND ND 2-Nov-06 --- 2 --- ND --- --- ND ND ND ND ND ND ND 30-May-07 --- 1 --- ND --- --- ND ND ND ND ND ND ND GWPS = 4 µg/L (10/23/07)29-Nov-07 --- 1 --- ND --- --- ND ND ND ND ND ND ND 29-May-08 0.10 1.0 --- ND --- --- 0.18 J ND ND ND ND ND ND 6-Nov-08 0.10 1.0 --- 0.49 B --- --- 0.65 B 0.32 B 0.42 B 0.61 B 0.53 B 0.27 B 0.29 J 3-Jun-09 0.10 1.0 --- ND --- --- ND ND ND 0.25 J 0.23 J 2.2 ND 18-Nov-09 0.10 1.0 --- ND --- --- ND ND ND 0.25 J ND ND ND 16-Jun-10 0.10 1.0 --- ND --- --- 0.24 J 0.94 J ND 0.11 J ND ND ND 1-Dec-10 0.10 1.0 --- ND 1.7 --- 0.14 J ND ND ND ND ND ND 1-Jun-11 0.10 1.0 --- ND 0.44 J --- J ND ND ND ND ND ND ND 20-Dec-11 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND 30-May-12 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND 5-Dec-12 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND 12-Jun-13 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND 28-Oct-13 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND 6-May-14 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND 23-Oct-14 1.0 1.0 --- --- * ND ND ND ND ND ND ND ND 20-May-15 0.5 1.0 --- --- --- ND ND ND ND ND ND ND ND 8-Dec-15 0.5 1.0 --- --- --- ND ND ND ND ND ND ND ND Cadmium 1-May-97 --- 1 ND NI --- --- ND ND 1.0 ND NI NI ND 1-Nov-97 --- 1 ND NI --- --- ND ND ND ND NI NI ND 1-May-98 --- 1 ND NI --- --- ND ND 1.0 ND NI NI ND 1-Nov-98 --- 1 ND NI --- --- ND ND 2.0 ND NI NI ND 11-May-99 --- 1 ND ND --- --- ND ND ND ND ND ND ND 18-Oct-99 --- 1 24.0 6.0 --- --- 6.0 3.0 J 30.0 2.0 J 2.0 J ND ND 3-May-00 --- 1 ND ND --- --- ND 1.0 J 1.0 J ND 5.0 ND ND 7-Nov-00 --- 1 2.0 5.0 --- --- ND ND 1.0 ND 1.0 ND ND 31-May-01 --- 1 ND ND --- --- ND ND 1.0 J ND 1.0 J ND ND 7-Nov-01 --- 1 ND ND --- --- ND ND ND ND ND ND ND 22-May-02 --- 1 ND ND --- --- ND ND ND 2.0 B ND ND 1.3 14-Nov-02 --- 1 ND ND --- --- ND ND 1.2 ND 3.7 ND ND 14-May-03 --- 1 ND ND --- --- 1.1 ND ND ND 2.5 ND ND 20-Nov-03 --- 1 2.0 1.3 --- --- ND ND 1.2 ND ND ND ND 6-May-04 --- 1 ND ND --- --- ND ND ND ND ND ND ND 10-Nov-04 --- 1 ND ND --- --- 1.5 ND ND ND 2.2 ND ND 5-May-05 --- 1 ND ND --- --- ND ND ND ND ND ND ND 3-Nov-05 --- 1 --- ND --- --- ND ND ND ND ND ND ND 25-May-06 --- 1 --- ND --- --- ND ND ND ND ND ND ND 2-Nov-06 --- 1 --- ND --- --- ND ND ND ND ND ND ND 30-May-07 --- 1 --- ND --- --- ND ND ND ND ND ND ND NC 2L = 1.75 µg/L (10/23/07)29-Nov-07 --- 1 --- ND --- --- ND ND 0.60 J ND ND ND ND 29-May-08 0.50 1.0 --- ND --- --- ND ND ND ND ND ND ND 6-Nov-08 0.50 1.0 --- ND --- --- ND ND ND ND 0.94 J ND ND 3-Jun-09 0.50 1.0 --- ND --- --- ND ND ND ND ND 1.9 ND 18-Nov-09 0.50 1.0 --- ND --- --- ND ND ND ND ND ND ND NC 2L = 2 µg/L (01/01/10)16-Jun-10 0.50 1.0 --- ND --- --- ND 6.0 ND ND ND ND ND Resample> 5-Aug-10 0.50 1.0 --- --- --- --- --- 1.2 --- --- ------ ND 1-Dec-10 0.50 1.0 --- ND ND --- ND ND ND ND ND ND ND 1-Jun-11 0.50 1.0 --- ND ND --- ND ND ND ND ND ND ND 20-Dec-11 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND 30-May-12 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND 5-Dec-12 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND 12-Jun-13 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND 28-Oct-13 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND 6-May-14 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND 23-Oct-14 1.0 1.0 --- --- * ND ND ND ND ND ND ND ND 20-May-15 0.5 1.0 --- --- --- ND ND 0.85 J ND ND ND ND ND 8-Dec-15 0.5 1.0 --- --- --- ND ND ND ND ND ND ND ND Burke County - John's River C and D over MSW Landfill Permit 12-03 Page 2 of 11 Joyce Engineering TABLE 1: HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Background Downgradient Chromium 1-Mar-95 --- 5 ND NI NI NI ND ND 11.0 ND NI NI ND 1-Aug-95 --- 5 ND NI --- --- ND ND ND ND NI NI ND 1-Jan-96 --- 5 ND NI --- --- ND ND 7.0 ND NI NI ND 1-Feb-96 --- 5 ND NI --- --- ND ND 6.0 ND NI NI ND 1-May-96 --- 5 ND NI --- --- ND ND 16.0 ND NI NI ND 1-Oct-96 --- 5 ND NI --- --- ND ND 6.0 ND NI NI ND 1-May-97 --- 1 4.0 NI --- --- 2.0 3.0 18.0 3.0 NI NI ND 1-Nov-97 --- 1 6.0 NI --- --- 1.0 1.0 108 2.0 NI NI ND 1-May-98 --- 1 8.0 NI --- --- 4.0 6.0 66.0 6.0 NI NI ND 1-Nov-98 --- 1 3.0 NI --- --- 1.0 3.0 180 3.0 NI NI ND 11-May-99 --- 5 26.0 24.0 --- --- 8.4 6.5 44.0 11.0 46.0 ND ND 18-Oct-99 --- 10 290 58.0 --- --- 44.0 36.0 410 21.0 ND ND ND 3-May-00 --- 10 ND ND --- --- ND ND 12.0 ND 92.0 ND ND 7-Nov-00 --- 10 11.0 30.0 --- --- ND ND ND ND ND ND ND 31-May-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND 7-Nov-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND 22-May-02 --- 10 ND ND --- --- ND ND ND ND 10.0 ND ND 14-Nov-02 --- 10 ND ND --- --- ND ND ND ND ND ND ND 14-May-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND 20-Nov-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND 6-May-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND 10-Nov-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND 5-May-05 --- 10 12.0 ND --- --- ND ND ND ND ND ND ND 3-Nov-05 --- 10 --- ND --- --- ND ND ND ND ND ND ND 25-May-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND 2-Nov-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND 30-May-07 --- 10 --- ND --- --- ND ND ND ND ND ND ND NC 2L = 50 µg/L (10/23/07)29-Nov-07 --- 10 --- ND --- --- ND ND ND ND ND ND ND 29-May-08 0.40 10.0 --- ND --- --- ND 1.9 B 1 B 1.4 B ND ND 0.85 J 6-Nov-08 0.40 10.0 --- 0.59 J --- --- 1 J 0.83 J 2.8 J 3.4 J 2.5 J ND ND 3-Jun-09 0.40 10.0 --- ND --- --- ND 2.1 J ND 1.1 J 0.66 J 2.1 J ND 18-Nov-09 0.40 10.0 --- ND --- --- ND ND 2.2 J 2.2 J ND ND ND NC 2L = 10 µg/L (01/01/10)16-Jun-10 0.40 10.0 --- 0.43 B --- --- 1.0 B 13.9 4.7 J 1.0 B ND ND 0.74 J Resample> 5-Aug-10 0.40 10.0 --- --- --- --- --- 0.88 B --- --- ------ 0.51 J 1-Dec-10 0.40 10.0 --- 0.60 B 39.6 --- 1.8 B 1.3 B 5.5 J 1.2 B ND ND 0.51 J Resample> 13-Jan-11 0.40 10.0 --- --- ND --- --- --- --- --- ------ ND 1-Jun-11 0.40 10.0 --- ND 11.2 --- ND 1.2 B 0.72 B ND ND ND 0.73 J Resample> 7-Jul-11 0.40 10.0 --- --- 7.8 J --- --- --- --- --- ------ ND 20-Dec-11 5.0 10.0 --- --- 8.2 J --- ND ND ND ND ND ND ND 30-May-12 5.0 10.0 --- --- 5.3 J --- ND ND ND ND 5.4 J ND ND 5-Dec-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 12-Jun-13 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 28-Oct-13 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 6-May-14 5.0 10.0 --- --- 6.1 J --- ND ND ND ND ND ND ND 23-Oct-14 5.0 10.0 --- --- * ND ND ND ND ND ND ND ND 20-May-15 2.5 10.0 --- --- --- ND ND 3.9 J ND ND ND 4.7 J ND 8-Dec-15 2.5 10.0 --- --- --- ND ND ND 13.8 ND ND ND ND Lab Re-run Analyses> 8-Dec-15 2.5 10.0 --- --- --- --- --- ---14.7 --- ------ --- Resample> 4-Feb-16 2.5 10.0 --- --- --- --- --- --- ND --- ------ ND Burke County - John's River C and D over MSW Landfill Permit 12-03 Page 3 of 11 Joyce Engineering TABLE 1: HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Background Downgradient Cobalt 18-Jan-95 --- 10 35.0 NI NI NI 35.0 14.0 52.0 14.0 NI NI ND 6-Feb-95 --- 10 16.0 NI NI NI 43.0 ND 66.0 ND NI NI ND Mar-95 --- 10 28.0 NI NI NI 57.0 ND 78.0 20.0 NI NI ND Aug-95 --- 10 ND NI --- --- 58.0 ND 30.0 32.0 NI NI ND Jan-96 --- 10 17.0 NI --- --- 37.0 ND 23.0 ND NI NI ND Feb-96 --- 10 37.0 NI --- --- 41.0 ND 24.0 ND NI NI ND May-96 --- 10 11.0 NI --- --- 26.0 ND 24.0 ND NI NI ND Oct-96 --- 10 16.0 NI --- --- 52.0 ND 16.0 ND NI NI ND May-97 --- 6 33.0 NI --- --- 120 5.0 J 32.0 6.0 NI NI ND Nov-97 --- 5 29.0 NI --- --- 99.0 11.0 48.0 14.0 NI NI ND May-98 --- 1 28.0 NI --- --- 120 8.0 76.0 32.0 NI NI ND Nov-98 --- 1 10.0 NI --- --- 140 6.0 47.0 1.0 NI NI ND 11-May-99 --- 5 20.0 26.0 --- --- 48.0 13.0 34.0 17.0 59.0 ND ND 18-Oct-99 --- 10 120 37.0 --- --- 85.0 20.0 220 16.0 40.0 ND ND 3-May-00 --- 10 ND ND --- --- 54.0 ND 31.0 13.0 89.0 ND ND 7-Nov-00 --- 10 ND 20.0 --- --- 40.0 ND 18.0 ND 32.0 ND ND 31-May-01 --- 10 ND ND --- --- 53.0 ND 30.0 11.0 32.0 ND ND 7-Nov-01 --- 10 ND ND --- --- 29.0 ND 23.0 ND 26.0 ND ND 22-May-02 --- 10 14.0 B 14.0 B --- --- 68.0 16.0 B 51.0 B 17.0 B 39.0 B 12.0 B 11.0 14-Nov-02 --- 10 ND ND --- --- 90.0 ND 41.0 11.0 34.0 ND ND 14-May-03 --- 10 19.0 ND --- --- 280 ND 46.0 53.0 24.0 ND ND 20-Nov-03 --- 10 26.0 10.0 J --- --- 340 18.0 56.0 58.0 30.0 ND ND 6-May-04 --- 10 ND ND --- --- 140 ND 46.0 47.0 29.0 ND ND 10-Nov-04 --- 10 10.0 ND --- --- 170 21.0 50.0 46.0 29.0 ND ND 5-May-05 --- 10 12.0 ND --- --- 130 16.0 46.0 60.0 26.0 ND ND 3-Nov-05 --- 10 --- ND --- --- 66.0 15.0 42.0 45.0 25.0 ND ND 25-May-06 --- 10 --- ND --- --- 80.3 21.7 42.7 43.2 24.9 ND ND 2-Nov-06 --- 10 --- ND --- --- 131 30.8 37.0 28.3 26.6 ND ND 30-May-07 --- 10 --- 4.1 J --- --- 87.2 20.7 44.0 36.9 26.6 ND ND GWPS = 70 µg/L (10/23/07)29-Nov-07 --- 10 --- 7.3 J --- ---67.2 55.5 47.9 J 23.4 30.7 ND ND 29-May-08 0.60 10.0 --- 5.4 J --- ---71.9 54.6 34.8 35.3 ND ND ND 6-Nov-08 0.60 10.0 --- 9.2 J --- ---71.9 60.0 47.9 44.1 24.3 2.2 B 1.6 J 3-Jun-09 0.60 10.0 --- 22.8 B --- ---139 78.6 53.5 49.3 54.7 7.6 B 7.6 J Resample> 27-Aug-09 0.60 10.0 --- --- --- --- 60.0 --- --- --- ------ --- 18-Nov-09 0.60 10.0 --- 14.9 --- ---126 84.5 50.3 44.1 31.8 ND ND 16-Jun-10 0.60 10.0 --- 19.1 --- ---96.1 103 70.9 38.0 48.6 ND ND Resample> 5-Aug-10 0.60 10.0 --- --- --- --- ---85.5 --- --- ------ ND GWPS = 1 µg/L (10/1/10)1-Dec-10 0.60 10.0 --- 9.8 J 22.1 ---72.7 151 111 43.1 33.3 ND ND Resample> 13-Jan-11 0.60 10.0 --- --- ND --- ---84.2 --- --- ------ ND 1-Jun-11 0.60 10.0 --- 7.8 J 2.6 J --- J 76.4 99.3 72.9 41.7 38.6 ND ND 20-Dec-11 5.0 10.0 --- --- ND ---92.8 75.6 62.7 36.5 25.5 ND ND 30-May-12 5.0 10.0 --- --- ND ---90.2 108 78.8 42.3 46.2 ND ND 5-Dec-12 5.0 10.0 --- --- ND ---46.6 27.9 101 45.8 51.4 ND ND 12-Jun-13 5.0 10.0 --- --- ND ---243 150 118 92.2 66.0 ND ND 28-Oct-13 5.0 10.0 --- --- ND ---200 128 124 117 75.7 ND ND Resample> 10-Dec-13 5.0 10.0 --- --- --- --- --- --- ---40.4 ------ ND 6-May-14 5.0 10.0 --- --- ND ---138 33.4 68.9 65.9 26.6 ND ND 22-Oct-14 5.0 10.0 --- --- * ND 126 37.1 82.0 74.9 32.1 ND ND 20-May-15 2.5 10.0 --- --- --- ND 116 34.8 77.8 90.0 34.0 ND ND 8-Dec-15 2.5 10.0 --- --- --- ND 175 61.0 84.8 49.7 32.8 ND ND Burke County - John's River C and D over MSW Landfill Permit 12-03 Page 4 of 11 Joyce Engineering TABLE 1: HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Background Downgradient Copper 18-Jan-95 --- 10 16.0 NI NI NI ND ND ND 14.0 NI NI ND 6-Feb-95 --- 10 ND NI NI NI ND ND ND ND NI NI ND 1-Mar-95 --- 10 ND NI NI NI ND ND ND 20.0 NI NI ND 1-Aug-95 --- 10 ND NI --- --- ND ND ND 18.0 NI NI ND 1-Jan-96 --- 10 ND NI --- --- ND ND ND ND NI NI ND 1-Feb-96 --- 10 21.0 NI --- --- ND ND ND ND NI NI ND 1-May-96 --- 10 14.0 NI --- --- 13.0 11.0 ND 11.0 NI NI ND 1-Oct-96 --- 10 ND NI --- --- ND ND ND ND NI NI ND 1-May-97 --- 10 ND NI --- --- 30.0 ND ND ND NI NI ND 1-Nov-97 --- 10 ND NI --- --- ND ND ND ND NI NI ND 1-May-98 --- 10 20.0 NI --- --- ND 10.0 70.0 20.0 NI NI ND 1-Nov-98 --- 10 ND NI --- --- 13.0 ND 28.0 ND NI NI ND 11-May-99 --- 5 28.0 49.0 --- --- 14.0 ND 9.3 28.0 37.0 ND ND 18-Oct-99 --- 200 380 ND --- --- ND ND 240 ND ND ND ND 3-May-00 --- 200 ND ND --- --- ND ND ND ND ND ND ND 7-Nov-00 --- 200 ND ND --- --- ND ND ND ND ND ND ND 31-May-01 --- 200 ND ND --- --- ND ND ND ND ND ND ND 7-Nov-01 --- 200 ND ND --- --- ND ND ND ND ND ND ND 22-May-02 --- 200 ND ND --- --- ND ND ND ND ND ND ND 14-Nov-02 --- 200 ND ND --- --- ND ND ND ND ND ND ND 14-May-03 --- 200 ND ND --- --- ND ND ND ND ND ND ND 20-Nov-03 --- 200 ND ND --- --- ND ND ND ND ND ND ND 6-May-04 --- 200 ND ND --- --- ND ND ND ND ND ND ND 10-Nov-04 --- 200 ND ND --- --- ND ND ND ND ND ND ND 5-May-05 --- 200 ND ND --- --- ND ND ND ND ND ND ND 3-Nov-05 --- 200 --- ND --- --- ND ND ND ND ND ND ND 25-May-06 --- 200 --- ND --- --- ND ND ND ND ND ND ND 2-Nov-06 --- 200 --- ND --- --- ND ND ND ND ND ND ND 30-May-07 --- 10 --- 0.7 B --- --- ND ND ND 3.2 B ND ND 1.3 J NC 2L = 1,000 µg/L (10/23/07) 29-Nov-07 --- 10 --- 8.30 J --- --- ND ND ND 6.10 J ND ND ND 29-May-08 0.30 10.0 --- 0.42 B --- --- 0.99 B 1.5 B 1.0 B 14.9 0.89 B ND 0.37 J 6-Nov-08 0.30 10.0 --- 2.0 B --- --- 1.8 B 0.7 B 2.4 B 16.6 4.2 J 0.46 B 0.65 J 3-Jun-09 0.30 10.0 --- 0.83 J --- --- ND 1 J ND 6.7 J 0.61 J 3.5 J ND 18-Nov-09 0.30 10.0 --- 0.34 J --- --- ND ND 1.2 J 10.7 0.38 J ND ND 16-Jun-10 0.30 10.0 --- 0.37 B --- --- 2.6 B 9.0 J 3.2 B 3.4 B ND ND 0.77 J 1-Dec-10 0.30 10.0 --- 1.3 J 36.1 --- 3.8 J 1.2 J 1.8 J 3.9 J 2.1 J ND ND 1-Jun-11 0.30 10.0 --- 0.54 J 12.9 --- 0.94 J 2.3 J 0.79 J 4.8 J 0.66 J ND ND 20-Dec-11 5.0 10.0 --- --- 9.0 J --- ND ND ND ND ND ND ND 30-May-12 5.0 10.0 --- --- 7.0 J --- ND ND ND ND 5.6 J ND ND 5-Dec-12 5.0 10.0 --- --- ND --- ND ND ND 5.6 J ND ND ND 12-Jun-13 5.0 10.0 --- --- 34.0 B --- ND ND ND 11.1 B ND ND 9.8 J 28-Oct-13 5.0 10.0 --- --- ND --- ND 6.1 J ND ND ND ND ND 6-May-14 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 23-Oct-14 5.0 10.0 --- --- * ND ND ND ND ND ND ND ND 20-May-15 2.5 10.0 --- --- --- ND ND ND ND 4.6 J ND ND ND 8-Dec-15 2.5 10.0 --- --- --- ND 8.1 J 6.4 J 9.7 J ND 5.9 J ND ND Cyanide 1-Nov-98 --- 2 6.0 NI --- --- 2.0 ND 7.0 ND NI NI ND 11-May-99 --- 2 ND ND --- --- ND ND ND ND ND ND ND 18-Oct-99 --- 50 ND ND --- --- --- ND ND ND ND ND ND 7-Nov-00 --- 50 ND --- --- --- ND ND ND ND ND --- ND 31-May-01 --- 50 ND --- --- --- ND ND ND ND ND --- ND 7-Nov-01 --- 50 ND --- --- --- ND ND ND ND ND --- ND 14-Nov-02 --- 50 ND --- --- --- ND ND ND ND ND --- ND 20-Nov-03 --- 50 ND --- --- --- ND ND ND ND ND --- ND 10-Nov-04 --- 10 ND --- --- --- ND ND ND ND ND --- ND 3-Nov-05 --- --- --- ND --- --- ND ND ND ND ND --- ND 2-Nov-06 --- 50 --- ND --- --- ND ND ND ND ND --- ND NC 2L = 70 µg/L (10/23/07)29-Nov-07 --- 10 --- ND --- --- ND ND ND ND ND --- ND 6-Nov-08 5.0 10.0 --- ND --- --- ND ND ND ND ND --- ND 18-Nov-09 5.0 10.0 --- ND --- --- ND ND ND ND ND --- ND 1-Dec-10 5.0 10.0 --- ND 5.9 J --- ND ND 5.2 J 5.8 J 6.5 J --- ND Resample> 13-Jan-11 5.0 10.0 --- --- ND --- --- --- 5.0 J ND 5.8 J --- ND 5-Dec-12 5.0 10.0 --- --- ND --- ND ND ND ND 7.0 J --- ND 28-Oct-13 5.0 10.0 --- --- ND --- 12.4 5.6 J 10.0 ND 6.5 J ND ND Resample> 10-Dec-13 5.0 10.0 --- --- --- --- 10.8 --- 9.0 J --- ------ ND 6-May-14 0.0 0.0 --- --- ND --- ND ND ND ND ND --- ND 23-Oct-14 2.5 10.0 --- --- * ND 3.6 J 4.7 J 4.2 J ND 5.2 J --- ND 20-May-15 0.0 10.0 --- --- --- ND ND ND ND ND ND --- ND 8-Dec-15 4.0 10.0 --- --- --- ND ND ND ND ND ND --- ND Iron 1-Jun-11 14.0 300 ---308 11,000 ---20,500 29,200 16,300 886 22,200 413 ND NC 2L = 300 µg/L (01/01/10) Resample>7-Jul-11 50.0 300 --- ---7,150 --- --- --- --- --- --- --- ND 20-Dec-11 50.0 300 --- ---8,010 ---26,300 36,700 22,900 1,160 22,200 93.5 J ND 30-May-12 50.0 300 --- ---5,940 ---24,500 45,700 21,700 1,300 24,500 ND ND 5-Dec-12 50.0 300 --- ---2,970 ---7,010 8,730 28,200 393 21,700 159 J ND 12-Jun-13 50.0 300 --- ---2,460 ---55,300 55,300 34,800 4,650 26,700 522 81.2 J 28-Oct-13 50.0 300 --- ---883 ---28,700 49,700 29,800 1,730 24,300 ND ND 6-May-14 50.0 300 --- ---4,240 ---47,300 46,800 29,700 1,200 24,600 ND ND 23-Oct-14 50.0 300 --- --- *2,340 33,600 29,200 31,200 528 27,700 171 J ND 20-May-15 25.0 300 --- --- ---350 22,400 22,600 33,800 672 25,800 63.5 J ND 8-Dec-15 25.0 300 --- --- ---1,380 102,000 74,200 50,200 1,460 27,400 43.7 J ND Burke County - John's River C and D over MSW Landfill Permit 12-03 Page 5 of 11 Joyce Engineering TABLE 1: HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Background Downgradient Lead 15-Sep-94 --- 5 41.0 NI NI NI 12.0 49.0 7.0 43.0 NI NI ND 1-Oct-94 --- 5 --- NI NI NI --- 9.0 --- --- NI NI ND 18-Jan-95 --- 5 35.0 NI NI NI 9.0 17.0 10.0 30.0 NI NI ND 6-Feb-95 --- 5 15.0 NI NI NI 7.0 ND ND 26.0 NI NI ND 1-Mar-95 --- 5 26.0 NI NI NI 16.0 12.0 9.0 43.0 NI NI ND 1-Aug-95 --- 5 11.0 NI --- --- 25.0 16.0 6.0 48.0 NI NI ND 1-Jan-96 --- 5 22.0 NI --- --- 18.0 12.0 10.0 7.0 NI NI ND 1-Feb-96 --- 5 16.0 NI --- --- 15.0 6.0 9.0 10.0 NI NI ND 1-May-96 --- 5 7.0 NI --- --- 8.0 9.0 15.0 ND NI NI ND 1-Oct-96 --- 5 15.0 NI --- --- 24.0 10.0 7.0 6.0 NI NI ND 1-May-97 --- 5 16.0 NI --- --- 23.0 10.0 22.0 16.0 NI NI ND 1-Nov-97 --- 5 40.0 NI --- --- 27.0 14.0 30.0 24.0 NI NI ND 1-May-98 --- 5 18.0 NI --- --- 9.0 ND 10.0 6.0 NI NI ND 1-Nov-98 --- 5 7.0 NI --- --- 39.0 9.0 47.0 14.0 NI NI ND 11-May-99 --- 10 14.0 18.0 --- --- ND ND ND ND ND ND ND 18-Oct-99 --- 10 160 54.0 --- --- 56.0 27.0 140 23.0 ND ND ND 3-May-00 --- 10 ND ND --- --- ND ND ND ND 11.0 J ND ND 7-Nov-00 --- 10 ND 20.0 --- --- ND ND ND ND ND ND ND 31-May-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND 7-Nov-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND 22-May-02 --- 10 ND ND --- --- ND ND ND ND ND ND ND 14-Nov-02 --- 10 ND ND --- --- ND ND ND ND ND ND ND 14-May-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND 20-Nov-03 --- 10 ND 19.0 --- --- ND ND ND 20.0 ND ND ND 6-May-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND 10-Nov-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND 5-May-05 --- 10 ND ND --- --- ND ND ND ND ND ND ND 3-Nov-05 --- 10 --- ND --- --- ND ND ND ND ND ND ND 25-May-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND 2-Nov-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND 30-May-07 --- 10 --- 2.5 J --- --- ND ND ND 2.3 J ND ND ND NC 2L = 15 µg/L (10/23/07)29-Nov-07 --- 10 --- 7.5 J --- --- ND 6.1 J ND 5.1 J ND ND ND 29-May-08 4.0 10.0 --- ND --- --- ND ND ND 6.8 ND ND ND 6-Nov-08 4.0 10.0 --- ND --- --- ND ND ND 8.8 J ND ND ND 3-Jun-09 4.0 10.0 --- ND --- --- ND ND ND ND ND ND ND 18-Nov-09 4.0 10.0 --- ND --- --- ND ND ND 5.5 J ND ND ND 16-Jun-10 4.0 10.0 --- ND --- --- 4.4 J 13.9 ND ND ND ND ND 1-Dec-10 4.0 10.0 --- ND 16.8 --- ND ND ND ND ND ND ND Resample> 13-Jan-11 4.0 10.0 --- ND ND --- --- --- --- --- ------ ND 1-Jun-11 4.0 10.0 --- ND 5.9 J --- ND ND ND ND ND ND ND 20-Dec-11 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 30-May-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 5-Dec-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 12-Jun-13 5.0 10.0 --- --- ND --- ND 5.5 J ND 5.6 J ND ND ND 28-Oct-13 5.0 10.0 --- --- ND --- ND 5.2 J ND ND ND ND ND 6-May-14 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 23-Oct-14 5.0 10.0 --- --- * ND ND ND ND ND ND ND ND 20-May-15 2.5 10.0 --- --- --- ND 4.9 J 4.3 J ND ND 2.7 J ND ND 8-Dec-15 2.5 10.0 --- --- --- ND 7.8 J 6.3 J 9.8 J ND ND ND ND Manganese 1-Jun-11 0.30 50.0 ---385 209 ---5,770 14,500 9,330 1,160 8,460 123 0.36 J NC 2L = 50 µg/L (01/01/10) Resample>7-Jul-11 5.0 50.0 --- --- 143 --- --- --- --- --- ------ ND 20-Dec-11 5.0 50.0 --- ---136 ---6,670 15,500 D 9,480 1,030 8,540 119 ND 30-May-12 5.0 50.0 --- ---104 ---6,700 14,300 9,370 1,170 8,790 119 ND 5-Dec-12 5.0 50.0 --- ---54.5 ---2,650 8,930 9,150 1,230 9,180 122 ND 12-Jun-13 5.0 50.0 --- --- 49.3 J ---16,800 15,400 11,700 2,060 8,150 130 ND 28-Oct-13 5.0 50.0 --- ---80.0 ---8,420 15,000 9,910 2,500 9,680 124 ND 6-May-14 50.0 500.0 --- ---83.5 ---12,300 18,300 9,950 1,600 9,720 119 ND 23-Oct-14 50.0 500.0 --- --- *73.6 9,400 23,200 11,000 1,740 11,500 115 ND 20-May-15 2.5 50.0 --- --- --- 27.4 9,070 29,800 10,800 2,010 12,400 121 ND 8-Dec-15 12.5 50.0 --- --- --- 50.0 J 15,000 18,100 10,800 1,500 8,440 124 ND Burke County - John's River C and D over MSW Landfill Permit 12-03 Page 6 of 11 Joyce Engineering TABLE 1: HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Background Downgradient Mercury 16-Aug-95 --- 0.2 0.30 B NI --- --- 0.30 B 0.30 B 0.20 B 0.30 B NI NI 0.2 25-Jan-96 --- 0.2 1.6 NI --- --- 0.40 0.70 ND 1.3 NI NI ND 28-Feb-96 --- 0.2 ND NI --- --- 2.4 ND ND 0.20 NI NI ND 1-May-96 --- 0.2 1.4 NI --- --- 1.7 1.5 2.1 2.3 NI NI ND 1-Oct-96 --- 0.5 ND NI --- --- ND ND ND ND NI NI ND 1-May-97 --- --- --- NI --- --- NS NS NS NS NI NI NS 1-Nov-97 --- 0.2 ND NI --- --- 0.80 ND ND ND NI NI ND 1-May-98 --- 0.2 ND NI --- --- 0.80 ND ND 0.40 NI NI ND 1-Nov-98 --- 0.2 ND NI --- --- 1.3 ND ND 0.49 NI NI ND 11-May-99 --- 0.2 --- ND --- --- --- --- --- --- ND ND --- 18-Oct-99 --- 0.5 ND ND --- --- --- ND ND 0.55 ND ND ND 3-May-00 --- 0.5 --- --- --- --- --- --- --- --- ------ --- 7-Nov-00 --- 0.5 ND --- --- --- ND ND ND ND ND --- ND 31-May-01 --- 0.5 ND --- --- --- 0.70 ND ND 0.90 ND --- ND 7-Nov-01 --- 0.5 ND --- --- --- ND ND ND 1.0 ND --- ND 22-May-02 --- 0.5 ND --- --- --- 0.62 ND ND ND ND --- ND 14-Nov-02 --- 0.5 ND --- --- --- ND ND ND ND ND --- ND 14-May-03 --- 0.5 ND --- --- --- ND ND ND ND ND --- ND 20-Nov-03 --- 0.5 ND --- --- --- 0.80 ND ND 0.73 ND --- ND 6-May-04 --- 0.5 ND --- --- --- 0.71 ND ND 0.52 ND --- ND 10-Nov-04 --- 0.5 ND --- --- --- ND ND ND 0.74 ND --- ND 5-May-05 --- 0.5 ND --- --- --- ND ND ND ND ND --- ND 3-Nov-05 --- 0.5 --- ND --- --- 1.0 ND ND ND ND --- ND 25-May-06 --- 2 --- --- --- --- ND ND ND ND ND --- ND 2-Nov-06 --- 0.5 --- ND --- --- ND ND ND ND ND ND ND 30-May-07 --- 0.2 --- --- --- --- 0.12 J ND ND 0.13 J ND --- --- NC 2L = 1.05 µg/L (10/23/07)29-Nov-07 --- 0.2 --- ND --- --- 0.88 ND ND 0.50 ND ND ND 29-May-08 0.090 0.20 --- --- --- --- 0.12 B ND 0.13 B 0.66 0.12 B --- 0.1 J 6-Nov-08 0.090 0.20 --- ND --- --- ND ND ND 0.41 ND ND ND 3-Jun-09 0.070 0.20 --- ND --- --- ND ND ND 0.14 J ND --- ND 18-Nov-09 0.070 0.20 --- ND --- --- ND ND ND 0.43 ND ND ND NC 2L = 1 µg/L (01/01/10)16-Jun-10 0.070 0.20 --- ND --- --- 0.17 J ND ND 0.077 J ------ ND 1-Dec-10 0.070 0.20 --- 0.089 J ND --- 0.62 ND ND 0.21 ND ND ND 1-Jun-11 0.10 0.20 --- ND ND --- 0.19 J ND ND 0.19 J ND --- ND 20-Dec-11 0.10 0.20 --- --- ND --- 0.14 J ND ND 0.15 J ND ND ND 30-May-12 0.10 0.10 --- --- ND --- 0.13 J ND ND 0.10 J ND ND ND 5-Dec-12 0.10 0.20 --- --- ND --- 0.11 J ND ND 0.27 ND --- ND 12-Jun-13 0.10 0.20 --- --- ND --- ND ND ND 0.56 ND ND ND 28-Oct-13 0.10 0.20 --- --- ND --- 0.15 J ND ND 0.11 J ND ND ND 6-May-14 0.10 0.20 --- --- ND --- 0.15 J ND ND ND ND ND ND 23-Oct-14 0.10 0.20 --- --- * ND ND ND ND 0.38 ND ND ND 20-May-15 0.10 0.20 --- --- --- ND 0.13 J ND ND 0.45 ND ND ND 8-Dec-15 0.10 0.20 --- --- --- ND ND ND ND ND ND ND ND Nickel 15-Sep-94 --- 50 ND NI NI NI ND ND 100 ND NI NI ND 1-Oct-94 --- 50 --- NI NI NI --- ND --- --- NI NI ND 18-Jan-95 --- 50 ND NI NI NI ND ND ND ND NI NI ND 6-Feb-95 --- 50 ND NI NI NI ND ND 71.0 ND NI NI ND 1-Mar-95 --- 50 ND NI NI NI ND ND ND ND NI NI ND 1-Aug-95 --- 50 ND NI --- --- ND ND ND ND NI NI ND 1-Jan-96 --- 50 ND NI --- --- ND ND ND ND NI NI ND 1-Feb-96 --- 50 ND NI --- --- ND ND ND ND NI NI ND 1-May-96 --- 50 ND NI --- --- ND ND ND ND NI NI ND 1-Oct-96 --- 50 ND NI --- --- ND ND ND ND NI NI ND 1-May-97 --- 50 ND NI --- --- ND ND ND ND NI NI ND 1-Nov-97 --- 50 ND NI --- --- ND ND 80.0 ND NI NI ND 1-May-98 --- 50 ND NI --- --- ND ND 90.0 ND NI NI ND 1-Nov-98 --- 50 ND NI --- --- ND ND 74.0 ND NI NI ND 11-May-99 --- 5 21.0 33.0 --- --- 16.0 11.0 63.0 14.0 53.0 ND ND 18-Oct-99 --- 50 180 67.0 --- --- 55.0 ND 570 ND ND ND ND 3-May-00 --- 50 ND ND --- --- ND ND ND ND 71.0 ND ND 7-Nov-00 --- 50 ND ND --- --- ND ND ND ND ND ND ND 31-May-01 --- 50 ND ND --- --- ND ND ND ND ND ND ND 7-Nov-01 --- 50 ND ND --- --- ND ND ND ND ND ND ND 22-May-02 --- 50 ND ND --- --- ND ND ND ND ND ND ND 14-Nov-02 --- 50 ND ND --- --- ND ND ND ND ND ND ND 14-May-03 --- 50 ND ND --- --- ND ND ND ND ND ND ND 20-Nov-03 --- 50 ND ND --- --- ND ND ND ND ND ND ND 6-May-04 --- 50 ND ND --- --- ND ND ND ND ND ND ND 10-Nov-04 --- 50 ND ND --- --- ND ND ND ND ND ND ND 5-May-05 --- 50 ND ND --- --- ND ND ND ND ND ND ND 3-Nov-05 --- 50 --- ND --- --- ND ND ND ND ND ND ND 25-May-06 --- 50 --- ND --- --- ND ND ND ND ND ND ND 2-Nov-06 --- 50 --- ND --- --- ND ND ND ND ND ND ND 30-May-07 --- 50 --- 2.2 J --- --- 2.1 J 2.2 J 3.7 J 4.1 J ND ND ND NC 2L = 100 µg/L (10/23/07)29-Nov-07 --- 50 --- 3.9 J --- --- ND 7.3 J 8.0 J 2.2 J ND ND ND 29-May-08 1.7 50.0 --- 3.6 J --- --- 3.1 J 5.6 J 3.0 J 4.3 J 2.5 J ND ND 6-Nov-08 1.7 50.0 --- 2.2 J --- --- 2.9 J 5.6 J 6.8 J 5.1 J 5.6 J ND ND 3-Jun-09 1.7 50.0 --- 3.1 B --- --- 2.6 B 8.5 B ND 4.1 B 2.8 B 2.2 B 1.7 J 18-Nov-09 1.7 50.0 --- 2.4 J --- --- 3.2 J 5.9 J 4.9 J 4.9 J 1.8 J ND ND 16-Jun-10 1.7 50.0 --- 1.7 J --- --- 4.5 J 13.1 J 8.2 J 3.4 J 1.7 J ND ND 1-Dec-10 1.7 50.0 --- ND 19.0 J --- 3.1 J 4.1 J 7.8 J 3.7 J ND ND ND 1-Jun-11 1.7 50.0 --- ND 4.7 B --- 2.2 B 3.5 B 2.2 B 3.0 B ND ND 2.3 J 20-Dec-11 5.0 50.0 --- --- ND --- ND ND ND ND ND ND ND 30-May-12 5.0 50.0 --- --- ND --- ND ND ND ND 5.2 J ND ND 5-Dec-12 5.0 50.0 --- --- ND --- ND ND 6.7 J ND ND ND ND 12-Jun-13 5.0 50.0 --- --- ND --- ND ND 5.2 J 5.4 J ND ND ND 28-Oct-13 5.0 50.0 --- --- ND --- ND ND ND ND ND ND ND 6-May-14 5.0 50.0 --- --- ND --- ND ND ND ND ND ND ND 23-Oct-14 5.0 50.0 --- --- * ND 6.0 J ND ND ND ND ND ND 20-May-15 2.5 50.0 --- --- --- ND 5.3 J 4.6 J 3.1 J 4.4 J ND ND ND 8-Dec-15 2.5 50.0 --- --- --- ND 5.5 J 3.4 J 17.7 J 4.2 J ND ND ND Burke County - John's River C and D over MSW Landfill Permit 12-03 Page 7 of 11 Joyce Engineering TABLE 1: HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Background Downgradient Selenium 29-May-08 3.8 10.0 --- ND --- --- ND 6.1 J ND ND 5.8 J ND ND 6-Nov-08 3.8 10.0 --- ND --- --- 13.2 6.4 J 6.7 J ND 5.8 J ND ND 3-Jun-09 3.8 10.0 --- ND --- --- ND 5.4 J ND ND ND ND ND 18-Nov-09 3.8 10.0 --- ND --- --- ND 4.3 J 4.7 J 4.4 J 5.0 J ND ND NC 2L = 20 µg/L (01/01/10)16-Jun-10 3.8 10.0 --- ND --- --- 3.8 J ND 6.9 J ND ND ND ND 1-Dec-10 3.8 10.0 --- ND ND --- ND ND ND ND ND ND ND 1-Jun-11 3.8 10.0 --- ND ND --- ND ND ND ND ND ND ND 20-Dec-11 10.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 30-May-12 10.0 10.0 --- --- ND --- 11.7 11.3 ND ND ND ND ND 5-Dec-12 10.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 12-Jun-13 10.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 28-Oct-13 10.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 6-May-14 10.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 23-Oct-14 10.0 10.0 --- --- * ND ND ND ND ND ND ND ND 20-May-15 5.0 10.0 --- --- --- ND ND ND ND ND ND ND ND 8-Dec-15 5.0 10.0 --- --- --- ND ND ND ND ND ND ND ND Silver 6-Feb-95 --- 10 ND NI NI NI 11.0 ND 11.0 ND NI NI ND 1-Mar-95 --- 10 ND NI NI NI ND ND ND ND NI NI ND 1-Aug-95 --- 1 ND NI --- --- ND ND ND ND NI NI ND 1-Jan-96 --- 1 ND NI --- --- ND ND ND ND NI NI ND 1-Feb-96 --- 1 ND NI --- --- ND ND ND ND NI NI ND 1-May-96 --- 1 ND NI --- --- ND ND ND ND NI NI ND 1-Oct-96 --- 1 ND NI --- --- ND ND ND ND NI NI ND 1-May-97 --- 5 ND NI --- --- 6.0 ND ND ND NI NI ND 1-Nov-97 --- 1 ND NI --- --- ND ND ND ND NI NI ND 1-May-98 --- 1 ND NI --- --- ND ND ND ND NI NI ND 1-Nov-98 --- 1 ND NI --- --- ND ND ND ND NI NI ND 11-May-99 --- 2 ND ND --- --- ND ND ND ND ND ND ND 18-Oct-99 --- 10 ND ND --- --- ND ND ND ND ND ND ND 3-May-00 --- 10 ND ND --- --- ND ND ND ND ND ND ND 7-Nov-00 --- 10 ND ND --- --- ND ND ND ND ND ND ND 31-May-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND 7-Nov-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND 22-May-02 --- 10 15.0 B 15.0 B --- --- 14.0 B 15.0 B 14.0 B 12.0 B 16.0 B 16.0 B 15.0 14-Nov-02 --- 10 ND ND --- --- ND ND ND ND ND ND ND 14-May-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND 20-Nov-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND 6-May-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND 10-Nov-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND 5-May-05 --- 10 ND ND --- --- ND ND ND ND ND ND ND 3-Nov-05 --- 10 --- ND --- --- ND ND ND ND ND ND ND 25-May-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND 2-Nov-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND 30-May-07 --- 10 --- ND --- --- ND ND ND ND ND ND ND NC 2L = 17.5 µg/L (10/23/07)29-Nov-07 --- 10 --- ND --- --- ND ND ND ND ND ND ND 29-May-08 0.10 10.0 --- 0.14 J --- --- 0.59 J 1.1 J 0.45 J ND 0.57 J ND ND 6-Nov-08 0.10 10.0 --- 0.25 B --- --- 1.1 B 2.1 J 1.3 J 0.26 B 1.1 B 0.22 B 0.23 J 3-Jun-09 0.10 10.0 --- 0.68 B --- --- 1.0 B 1.4 B 0.73 B 0.13 B 0.76 B 1.0 B 0.31 J 18-Nov-09 0.10 10.0 --- 0.28 B --- --- 0.72 B 1.0 B 0.61 B 0.19 B 0.57 B 0.19 B 0.23 J NC 2L = 20 µg/L (01/01/10)16-Jun-10 0.10 10.0 --- ND --- --- ND ND ND ND ND ND ND 1-Dec-10 0.10 10.0 --- ND ND --- ND 0.24 J ND ND ND ND ND 1-Jun-11 0.10 10.0 --- 0.39 B 0.16 B --- 0.22 B 0.60 B 0.32 B 0.29 B 0.22 B 0.23 B 0.17 J 20-Dec-11 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 30-May-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 5-Dec-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 12-Jun-13 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 28-Oct-13 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 6-May-14 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND 23-Oct-14 5.0 10.0 --- --- * ND ND ND ND ND ND ND ND 20-May-15 2.5 10.0 --- --- --- ND ND 3.6 J ND ND ND ND ND 8-Dec-15 2.5 10.0 --- --- --- ND ND ND ND ND ND ND ND Burke County - John's River C and D over MSW Landfill Permit 12-03 Page 8 of 11 Joyce Engineering TABLE 1: HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Background Downgradient Sulfide 1-Aug-95 --- 100 900 NI --- --- ND 600 ND 100 NI NI ND 1-Jan-96 --- 100 ND NI --- --- ND 300 ND ND NI NI ND 1-Feb-96 --- 100 ND NI --- --- ND 100 ND ND NI NI ND 1-May-96 --- 100 200 NI --- --- ND 900 700 300 NI NI ND 1-Oct-96 --- 100 2800 NI --- --- ND 200 3000 7500 NI NI ND 1-May-97 --- 50 ND NI --- --- ND ND ND ND NI NI ND 1-Nov-97 --- 50 ND NI --- --- ND ND ND ND NI NI ND 1-May-98 --- 50 50 NI --- --- ND ND ND ND NI NI ND 1-Nov-98 --- 50 ND NI --- --- 130 ND 80.0 110 NI NI ND 11-May-99 --- 50 ND ND --- --- ND ND ND ND --- ND ND 18-Oct-99 --- 1000 ND ND --- --- --- ND ND ND ND ND ND 7-Nov-00 --- 1000 ND --- --- --- ND ND ND ND ND --- ND 31-May-01 --- 1000 ND --- --- --- ND ND ND ND ND --- ND 7-Nov-01 --- 1000 ND --- --- --- ND ND ND ND ND --- ND 14-Nov-02 --- 1000 ND --- --- --- ND ND ND ND ND --- ND 20-Nov-03 --- 1000 ND --- --- --- ND ND ND ND ND --- ND 10-Nov-04 --- 1000 ND --- --- --- ND ND ND ND ND ---6 3-Nov-05 --- --- --- ND --- --- ND ND 1800 ND ND --- ND 2-Nov-06 --- 1000 --- ND --- --- ND ND ND ND ND --- ND NC 2L = NE (10/23/07)29-Nov-07 --- 1000 --- ND --- --- ND ND ND ND ND --- ND 6-Nov-08 100 1000 --- ND --- --- ND ND ND ND ND --- ND 3-Jun-09 100 1000 --- ND --- --- --- ND ND --- ND --- ND 18-Nov-09 100 1000 --- ND --- --- ND ND ND ND ND --- ND 16-Jun-10 100 1000 --- ND --- --- --- ND ND --- ND --- ND 1-Dec-10 100 1000 --- ND ND --- ND ND ND ND ND --- ND 5-Dec-12 100 1000 --- --- ND --- ND ND ND ND ND --- ND 12-Jun-13 100 1000 --- --- ND --- ND ND ND ND ND --- ND 28-Oct-13 100 1000 --- --- ND --- ND ND ND ND ND ND ND 23-Oct-14 100 1000 --- --- * ND ND ND ND ND ND --- ND 8-Dec-15 100 1000 --- --- --- ND ND ND ND ND ND --- ND Thallium 1-Nov-97 --- 1 2.0 B NI --- --- 2.0 B 2.0 B 3.0 B 1.0 B NI NI 2.0 1-May-98 --- 1 ND NI --- --- ND ND ND 1.0 NI NI ND 1-Nov-98 --- 1 ND NI --- --- ND ND ND 1.0 NI NI ND 11-May-99 --- 2 2.0 3.0 --- --- 4.0 3.0 4.0 ND 3 2.0 ND 18-Oct-99 --- 10 ND ND --- --- ND ND ND ND ND ND ND 3-May-00 --- 10 ND ND --- --- ND ND ND ND ND ND ND 7-Nov-00 --- 10 ND ND --- --- ND ND ND ND ND ND ND 31-May-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND 7-Nov-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND 22-May-02 --- 10 ND ND --- --- ND ND ND ND ND ND ND 14-Nov-02 --- 10 ND ND --- --- ND ND ND ND ND ND ND 14-May-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND 20-Nov-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND 6-May-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND 10-Nov-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND 5-May-05 --- 10 16.0 ND --- --- 41.0 23.0 25.0 14.0 26.0 ND ND 3-Nov-05 --- 10 --- ND --- --- 19.0 17.0 15.0 ND 13.0 ND ND 25-May-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND 2-Nov-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND 30-May-07 --- 5.5 --- ND --- --- 0.169 J 0.29 J 0.221 J 0.131 J 0.078 J ND ND GWPS = 0.28 µg/L (10/23/07)29-Nov-07 --- 5.5 --- 0.042 J --- --- 0.118 J 0.321 J 0.199 J 0.150 J 0.065 J ND ND 29-May-08 3.0 5.5 --- ND --- --- ND ND ND ND ND ND ND 6-Nov-08 3.0 5.5 --- ND --- ---8.9 ND ND ND ND ND ND 3-Jun-09 3.0 5.5 --- ND --- --- ND ND ND ND ND 14.8 ND 18-Nov-09 3.0 5.5 --- ND --- --- ND ND ND ND ND ND 4.2 J 16-Jun-10 3.0 5.5 --- ND --- --- 5.3 J 7.7 4.1 J ND 4.0 J ND ND Resample> 5-Aug-10 3.0 5.5 --- --- --- --- ---20.4 --- --- ------ 3.2 J GWPS = 0.2 µg/L (10/1/1)1-Dec-10 3.0 5.5 --- 3.3 B ND --- 3.3 B 9.1 B 5.1 B ND 7.8 B ND 3.1 J 1-Jun-11 3.0 5.5 --- ND ND --- ND ND ND ND ND ND ND 20-Dec-11 5.4 5.5 --- --- ND --- ND ND ND ND ND ND ND 30-May-12 5.4 5.5 --- --- ND --- ND ND ND ND ND ND ND 5-Dec-12 5.4 5.5 --- --- ND --- ND ND ND ND ND ND 6.8 12-Jun-13 5.4 5.5 --- --- ND --- ND ND ND ND ND ND ND 28-Oct-13 5.4 5.5 --- --- ND --- ND ND ND ND ND ND ND 6-May-14 5.4 5.5 --- --- ND --- ND ND ND ND ND ND ND 23-Oct-14 5.4 5.5 --- --- * ND ND ND ND ND ND ND ND 20-May-15 5.0 5.5 --- --- --- ND ND 6.4 ND ND ND ND ND 8-Dec-15 5.0 5.5 --- --- --- ND ND ND ND ND ND ND ND Tin 6-Nov-08 1.8 100 --- ND --- --- 2.3 J 3.8 J 2.1 J ND 2.9 J --- ND GWPS = 0.28 µg/L (10/23/07)3-Jun-09 --- --- --- --- --- --- --- --- --- --- ------ --- 18-Nov-09 1.8 100 --- ND --- --- ND ND ND ND ND ND ND GWPS =2,100 µg/L (01/01/10)16-Jun-10 1.8 100 --- ND --- --- ND ND ND ND ------ ND GWPS =2,000 µg/L (10/1/10)1-Dec-10 1.8 100 --- ND ND --- ND ND ND ND ND --- ND 1-Jun-11 1.8 100 --- ND ND --- ND ND ND ND ND ND ND 20-Dec-11 5.0 100 --- --- ND --- ND ND ND ND ND ND ND 30-May-12 5.0 100 --- --- ND --- ND ND ND ND ND ND ND 5-Dec-12 5.0 100 --- --- ND --- ND ND ND ND ND --- ND 12-Jun-13 5.0 100 --- --- ND --- ND ND ND ND ND ND ND 28-Oct-13 5.0 100 --- --- ND --- ND 5.1 J ND ND ND --- ND 6-May-14 5.0 100 --- --- ND --- ND ND ND ND ND --- ND 23-Oct-14 5.0 100 --- --- * ND ND ND ND ND ND --- ND 20-May-15 2.5 100 --- --- --- ND ND ND ND ND ND --- ND 8-Dec-15 2.5 100 --- --- --- ND ND ND ND ND ND --- ND Burke County - John's River C and D over MSW Landfill Permit 12-03 Page 9 of 11 Joyce Engineering TABLE 1: HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Background Downgradient Vanadium 1-May-97 --- 5 12.0 NI --- --- 5.0 ND 66.0 9.0 NI NI ND 1-Nov-97 --- 40 ND NI --- --- ND ND 180 ND NI NI ND 1-May-98 --- 5 14.0 NI --- --- 6.0 7.0 159 22.0 NI NI ND 1-Nov-98 --- 5 15.0 NI --- --- 12.0 8.0 110 14.0 NI NI ND 11-May-99 --- 5 55.0 58.0 --- --- 25.0 16.0 72.0 31.0 71.0 100 ND 18-Oct-99 --- 40 630 150 --- --- 150 79.0 690 62.0 ND ND ND 3-May-00 --- 40 ND ND --- --- ND ND ND ND 140 ND ND 7-Nov-00 --- 40 ND 66.0 --- --- ND ND ND ND ND ND ND 31-May-01 --- 40 ND ND --- --- ND ND ND ND ND ND ND 7-Nov-01 --- 40 ND ND --- --- ND ND ND ND ND ND ND 22-May-02 --- 40 ND ND --- --- ND ND ND ND ND ND ND 14-Nov-02 --- 40 ND ND --- --- ND ND ND ND ND ND ND 14-May-03 --- 40 ND ND --- --- ND ND ND ND ND ND ND 20-Nov-03 --- 40 ND ND --- --- ND ND ND ND ND ND ND 6-May-04 --- 40 ND ND --- --- ND ND ND ND ND ND ND 10-Nov-04 --- 40 ND ND --- --- ND ND ND ND ND ND ND 5-May-05 --- 40 ND ND --- --- ND ND ND ND ND ND ND 3-Nov-05 --- 40 --- ND --- --- ND ND ND ND ND ND ND 25-May-06 --- 40 --- ND --- --- ND ND ND ND ND ND ND 2-Nov-06 --- 40 --- ND --- --- ND ND ND ND ND ND ND 30-May-07 --- 25 --- ND --- --- ND ND ND ND ND ND 1.3 J GWPS = 3.5 µg/L (10/23/07)29-Nov-07 --- 25 --- 7.3 J --- --- ND ND ND ND ND ND ND 29-May-08 0.2 25.0 --- 0.43 J --- --- ND 2.4 J 1.3 J 3.7 J ND ND ND 6-Nov-08 0.2 25.0 --- 3.0 B --- --- 2.2 B 0.53 B 5.5 B 11.1 J 6.2 B 1.4 B 2.1 J 3-Jun-09 0.2 25.0 --- 0.94 B --- --- 0.47 B 0.91 B 0.66 B 5.2 J 1.8 B 2.7 B 1.0 J 18-Nov-09 0.20 25.0 --- 0.82 B --- --- 0.43 B 0.66 B 4.1 J 5.4 J 1.3 B 0.29 B 0.56 J 16-Jun-10 0.20 25.0 --- 1.1 B --- --- 4.5 B 28.5 8.3 J 2.0 B 1.3 B 0.66 B 0.98 J Resample> 5-Aug-10 0.20 25.0 --- --- --- --- --- 1.5 B --- --- ------ 0.62 J GWPS = 0.3 µg/L (10/1/10)1-Dec-10 0.20 25.0 --- 0.48 J 55.2 --- 3.2 J 0.63 J 5.7 J 0.33 J 2.9 J 2.4 J ND Resample> 13-Jan-11 0.20 25.0 --- --- 0.55 B --- --- --- --- --- ------ 0.33 J 1-Jun-11 0.20 25.0 --- 0.69 J 17.2 J --- 0.34 J 1.5 J 0.32 J 0.37 J ND 5.5 J ND 20-Dec-11 5.0 25.0 --- --- 10.7 J --- ND ND ND ND ND ND ND 30-May-12 5.0 25.0 --- --- 9.2 J --- ND ND ND ND 7.9 J ND ND 5-Dec-12 5.0 25.0 --- --- ND --- ND ND 6.1 J ND ND ND ND 12-Jun-13 5.0 25.0 --- --- ND --- ND ND ND 5.6 J ND ND ND 28-Oct-13 5.0 25.0 --- --- ND --- ND 8.3 J ND ND ND ND ND 6-May-14 5.0 25.0 --- --- 6.7 J --- ND ND ND ND ND ND ND 22-Oct-14 5.0 25.0 --- --- * 9.6 J ND ND ND ND ND ND ND 20-May-15 2.5 25.0 --- --- --- ND 9.1 J 20.1 J 10.7 J 2.6 J 11.3 J ND ND 8-Dec-15 2.5 25.0 --- --- --- 6.6 J 20.4 J 23.5 J 36.9 3.0 J 11.5 J ND ND Lab Re-run analyses> 8-Dec-15 2.5 25.0 --- --- --- --- --- --- 19.8 J --- ------ --- Zinc 15-Sep-94 --- 10 36.0 NI NI NI ND 27.0 ND ND NI NI ND 1-Oct-94 --- 10 --- NI NI NI --- 52.0 --- --- NI NI ND 18-Jan-95 --- 10 21.0 NI NI NI ND 27.0 21.0 ND NI NI ND 6-Feb-95 --- 10 21.0 NI NI NI ND 18.0 37.0 14.0 NI NI ND 1-Mar-95 --- 10 27.0 NI NI NI 14.0 24.0 29.0 29.0 NI NI ND 1-Aug-95 --- 10 ND NI --- --- ND 29.0 23.0 27.0 NI NI ND 1-Jan-96 --- 10 28.0 NI --- --- 22.0 37.0 49.0 21.0 NI NI ND 1-Feb-96 --- 10 48.0 NI --- --- 27.0 24.0 31.0 26.0 NI NI ND 1-May-96 --- 10 46.0 NI --- --- 46.0 48.0 56.0 55.0 NI NI ND 1-Oct-96 --- 10 23.0 NI --- --- 16.0 30.0 20.0 16.0 NI NI ND 1-May-97 --- 10 50.0 NI --- --- 50.0 50.0 80.0 50.0 NI NI ND 1-Nov-97 --- 10 60.0 NI --- --- 20.0 30.0 80.0 ND NI NI ND 1-May-98 --- 10 40.0 NI --- --- 30.0 40.0 110 30.0 NI NI ND 1-Nov-98 --- 10 29.0 NI --- --- 24.0 23.0 150 ND NI NI ND 11-May-99 --- 20 64.0 43.0 --- --- 150 28.0 68.0 61.0 69.0 210 ND 18-Oct-99 --- 50 570 89.0 --- --- 160 140 700 75.0 J ND 99.0 ND 3-May-00 --- 50 ND ND --- --- ND ND ND 62.0 J 160 63.0 J ND 7-Nov-00 --- 50 130 150 --- --- ND 110 60.0 70.0 ND ND ND 31-May-01 --- 50 ND ND --- --- ND ND 79.0 ND ND ND ND 7-Nov-01 --- 50 ND ND --- --- ND ND ND ND ND ND ND 22-May-02 --- 50 ND ND --- --- ND ND ND ND ND ND ND 14-Nov-02 --- 50 ND ND --- --- ND ND ND ND ND ND ND 14-May-03 --- 50 ND ND --- --- ND ND ND ND ND ND ND 20-Nov-03 --- 50 ND 100 --- --- 50.0 ND ND ND ND ND ND 6-May-04 --- 50 ND ND --- --- 78.0 ND ND ND ND ND ND 10-Nov-04 --- 50 ND ND --- --- ND ND ND ND ND ND ND 5-May-05 --- 50 ND ND --- --- ND ND ND ND ND ND ND 3-Nov-05 --- 50 --- ND --- --- ND ND ND ND ND ND ND 25-May-06 --- 50 --- ND --- --- ND ND ND ND ND ND ND 2-Nov-06 --- 50 --- ND --- --- ND ND ND ND ND ND ND 30-May-07 --- 10 --- 5.9 B --- --- 7.6 B 11.4 19.3 14.0 46.5 1.3 1.6 J NC 2L = 1,050 µg/L (10/23/07) 29-Nov-07 --- 10 --- 20.4 --- --- 10.9 B 62.0 30.2 16.4 44.5 35.6 3.1 J 29-May-08 0.40 10.0 --- 2.9 B --- --- 20.4 44.3 27.9 25.7 35.2 25.0 3.0 J 6-Nov-08 0.40 10.0 --- 12.1 B --- --- 10.2 B 16.6 18.6 27.1 76.7 30.9 2.7 J 3-Jun-09 0.40 10.0 --- 3.9 B --- --- 4.6 B 40.5 B 7.0 B 20.0 B 19.2 B 6.6 B 82.0 18-Nov-09 0.40 10.0 --- 4.2 B --- --- 7.2 B 21.4 18.6 22.1 13.6 B 2.5 B 3.1 J NC 2L = 1,000 µg/L (01/01/10) 16-Jun-10 0.40 10.0 --- ND --- --- 6.0 J 56.2 20.5 10.1 24.0 ND ND 1-Dec-10 0.40 10.0 --- 6.5 J 76.5 --- 14.1 33.4 25.6 16.2 119 5.4 J 0.62 J 1-Jun-11 0.40 10.0 --- 8.3 B 31.6 B --- 14.3 B 40.8 B 27.2 B 20.1 B 24.9 B 44.7 B 13.7 20-Dec-11 10.0 10.0 --- --- 19.6 --- 13.3 40.8 20.2 17.6 30.5 15.8 ND 30-May-12 10.0 10.0 --- --- 11.5 --- ND 39.2 16.6 13.3 48.8 ND ND 5-Dec-12 10.0 10.0 --- --- ND --- 12.1 17.8 24.4 17.8 ND 11.2 ND 12-Jun-13 10.0 10.0 --- --- 31.4 --- ND 38.9 B ND 23.7 B ND 32.2 B 76.5 28-Oct-13 10.0 10.0 --- --- 15.9 --- ND 68.9 14.3 22.0 18.2 ND ND 6-May-14 10.0 10.0 --- --- 13.7 --- ND 23.4 12.2 17.2 11.7 ND ND 23-Oct-14 10.0 10.0 --- --- * ND ND 17.8 11.2 18.5 32.2 13.9 ND 20-May-15 5.0 10.0 --- --- --- 26.4 9.6 J 24.2 15.6 19.8 20.4 ND ND 8-Dec-15 5.0 10.0 --- --- --- ND 9.0 J 20.0 65.1 19.0 47.3 8.2 J ND Burke County - John's River C and D over MSW Landfill Permit 12-03 Page 10 of 11 Joyce Engineering TABLE 1: HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Background Downgradient Alkalinity, Total as CaCO3 1-Jun-11 5,000 5,000 --- 45,100 --- --- --- 177,000 70,700 --- 109,000 --- ND NC 2L = NE (01/01/10)20-Dec-11 5,000 5,000 --- --- 8,580 --- 53,600 189,000 70,800 ND 77,200 47,200 ND 30-May-12 1,000 1,000 --- --- 8,140 --- 64,700 200,000 76,700 8,360 104,000 44,400 ND 5-Dec-12 1,000 5,000 --- --- 7,690 --- 22,600 178,000 76,600 ND 106,000 46,500 ND 12-Jun-13 1,000 5,000 --- --- 7,950 --- 138,000 202,000 111,000 7,020 99,700 51,700 ND 28-Oct-13 1,000 5,000 --- --- 8,140 --- 69,900 197,000 91,300 9,520 116,000 45,000 ND 6-May-14 1,000 5,000 --- --- 8,060 --- 85,900 208,000 90,600 5,520 119,000 45,700 ND 23-Oct-14 1,000 5,000 --- --- * 1,360 J 88,100 215,000 96,100 7,500 122,000 52,000 --- 20-May-15 1,000 5,000 --- --- --- ND 67,300 153,000 67,500 8,780 92,100 41,600 --- 8-Dec-15 1,000 NE --- --- --- 1,030 J 98,400 202,000 88,800 9,130 95,900 46,200 --- Chloride 1-Jun-11 5,000 5,000 --- ND --- --- --- 17,000 6,330 --- 7,870 --- ND NC 2L = 250,000 µg/L (01/01/10) 20-Dec-11 5,000 5,000 --- --- ND --- 6,320 20,200 6,400 ND 6,530 ND ND 30-May-12 1,000 1,000 --- --- 1,480 --- 6,190 20,000 ND 2,100 5,840 ND ND 5-Dec-12 1,000 1,000 --- --- 2,130 --- 5,970 19,500 7,290 2,060 7,430 1,130 ND 12-Jun-13 1,000 1,000 --- --- 1,380 --- 13,300 19,500 7,500 2,260 5,100 ND ND 28-Oct-13 1,000 1,000 --- --- 1,120 --- 11,400 18,100 7,750 2,210 8,490 ND ND 6-May-14 1,000 1,000 --- --- ND --- 17,300 18,200 8,140 1,890 8,920 ND ND 23-Oct-14 500 1,000 --- --- * ND 19,200 20,800 9,050 1,570 8,120 642 J ND 20-May-15 500 1,000 --- --- --- --- 14,000 25,300 9,680 1,720 10,400 572 J --- 8-Dec-15 500 NE --- --- --- 859 J 26,500 30,800 9,400 1,910 4,190 945 J --- Sulfate 1-Jun-11 5,000 5,000 --- ND --- --- --- ND ND --- ND --- ND NC 2L = 250,000 µg/L (01/01/10) 20-Dec-11 5,000 5,000 --- --- ND --- 5,150 ND ND ND ND 8,630 ND 30-May-12 2,000 250,000 --- --- ND --- 5,380 J ND ND ND ND 8,860 J ND 5-Dec-12 2,000 250,000 --- --- ND --- 2,880 J 2,920 J 4,400 J ND 2,320 J 8,910 J ND 12-Jun-13 2,000 250,000 --- --- ND --- 11,200 J 3,080 J 2,910 J 6,940 J ND 9,310 J ND 28-Oct-13 2,000 250,000 --- --- ND --- 4,420 J ND 2,940 J ND ND 8,150 J ND 6-May-14 2,000 250,000 --- --- ND --- 10,500 J 2,300 J 3,720 J ND 2,070 J 8,780 J ND 23-Oct-14 1,000 250,000 --- --- * ND 7,270 J 2,280 J 3,740 J 1,240 J 1,940 J 9,710 J ND 20-May-15 1,000 250,000 --- --- --- ND 5,620 J 2,310 J 3,440 J ND 2,150 J 8,780 J --- 8-Dec-15 1,000 250,000 --- --- --- ND 10,200 J 1,530 J 2,020 J ND ND 9,260 J --- Total Dissolved Solids, Dissolved 1-Jun-11 25,000 25,000 --- 62,000 --- --- --- 200,000 93,000 --- 127,000 --- ND NC 2L = 500,000 µg/L (01/01/10) 20-Dec-11 25,000 25,000 --- --- ND --- 59,000 196,000 82,000 ND 103,000 78,000 ND 30-May-12 25,000 25,000 --- --- 37,000 --- 85,000 12,500 J 109,000 ND 136,000 90,000 ND 5-Dec-12 25,000 25,000 --- --- 35,000 --- 50,000 219,000 109,000 28,000 134,000 97,000 ND 12-Jun-13 25,000 25,000 --- --- 34,000 --- 177,000 225,000 136,000 ND 111,000 107,000 ND 28-Oct-13 25,000 25,000 --- --- 49,000 --- 109,000 227,000 134,000 ND 138,000 112,000 ND 6-May-14 25,000 25,000 --- --- 34,000 --- 136,000 234,000 115,000 32,000 126,000 102,000 ND 23-Oct-14 25,000 25,000 --- --- * ND 126,000 238,000 119,000 ND 129,000 98,000 ND 20-May-15 25,000 25,000 --- --- --- ND 112,000 252,000 122,000 30,000 135,000 88,000 --- 8-Dec-15 25,000 NE --- --- --- ND 182,000 280,000 117,000 ND 106,000 93,000 --- Notes: (Abbreviations and Referrences) All concentrations in micrograms per liter (µg/L) = parts per billion. --- = Not sampled for this parameter or not reported. AB = Monitoring well abandoned. B = Blank-Qualified (Concentration suspected to reflect laboratory or field contamination based on similar concentrations detected in field, trip, or method blanks). D = Sample was diluted when analyzed. DL = Laboratory Detection Limit. GWPS = Groundwater Protection Standard set by NC-DENR-SWS for constituents with no listed NC 2L standard. When the NC 2L Groundwater Standard has not been established, the GWPS will be used. J = Estimated value - concentration is less than the RL but greater than the DL. NC 2L = Groundwater Standard from 15A NCAC 2L. ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006). NE = No NC 2L or GWPS established. NI = Not Installed; monitoring was not yet installed. RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present). Values above the NC2L Standard or GWPS are bold. Notes: (Event Narratives) Volatile organics (8260) for MW-9 for November 10, 2004 sampling event were unable to be analyzed and were resampled on December 1, 2004. There was a resamplinging event on August 2, 2007 for MW-16D because the prevoius samples from the May 2007 were analyzed out of hold time. There were no detects in the resample. * MW-21 replaced MW-20 as the background well starting with the Fall 2014 sampling event; however MW-20 continues to be sampled as a compliance well for the C&D Expansion (Phase 1A). See the Water Quality Monitrong Report for the C&D Expansion Area for current results for MW-20. The dates on the table above reflect the last samples were collected during the semiannual monitoring event. Individual collection dates are preserved in the Lab Reports (Appendix B). Pace Analytical Re-ran the analysis for Antimony, Chromium, and Vanadium in MW-12 on January 19, 2016 from the samples collected in December 2016, and the results are included in the table. A Verification Sampling Event was performed for beta-BHC in MW-11 and Antimony and Chromium in MW-12 on February 4, 2016, for the December 2015 event and results are included. Burke County - John's River C and D over MSW Landfill Permit 12-03 Page 11 of 11 Joyce Engineering TABLE 2: HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample EPA Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Organic Compounds Acetone 30-May-07 --- 100.0 --- 2.7 B --- --- ND ND ND ND ND ND 2.1 JNC 2L = 700 µg/L (10/23/07)29-Nov-07 --- 100.0 --- 8.1 B --- --- 3 B ND 2.8 B 8.1 B 13 B 2.6 B 5.1 J 29-May-08 20.0 100.0 --- ND --- --- ND ND ND ND ND ND ND 6-Nov-08 20.0 100.0 --- 26.8 J --- --- ND ND ND ND ND ND ND 3-Jun-09 2.2 100.0 --- 48.3 J --- --- 6.5 J ND ND ND 18.5 J ND ND 18-Nov-09 2.2 100.0 --- ND ND --- ND ND ND ND ND ND ND NC 2L = 6,000 µg/L (01/01/10)16-Jun-10 2.2 100.0 --- 5.3 B --- --- ND 3.1 B ND ND ND ND 7.2 J 1-Dec-10 2.2 100.0 --- ND ND --- 8.4 B ND ND ND 56.6 J ND 3.7 J 1-Jun-11 2.2 100.0 --- 3.5 B ND --- 3.4 B 8.1 B 7.7 B ND 80 J ND 3.9 J20-Dec-11 2.2 100.0 --- --- ND --- ND ND ND ND ND ND ND 30-May-12 2.2 100.0 --- --- ND --- ND ND ND ND ND ND ND 5-Dec-12 10.0 100.0 --- --- ND --- ND ND ND ND ND ND ND 12-Jun-13 10.0 100.0 --- --- ND --- 33 J ND ND ND 20.5 J ND ND 28-Oct-13 10.0 100.0 --- --- ND --- ND ND ND ND ND ND ND 6-May-14 EPA 8260 10.0 100.0 --- --- ND --- ND ND ND ND ND ND ND 22-Oct-14 EPA 8260 10.0 100.0 --- ---* ND ND ND 10.4 J ND ND ND ND 21-May-15 EPA 8260 10.0 100.0 --- --- --- ND ND ND ND ND ND ND ND8-Dec-15 EPA 8260 10.0 100.0 --- --- --- ND ND ND ND ND 16.5 J ND ND Acrolein 8-Dec-15 EPA 8260 1.6 53.0 --- --- --- 1.6 B ND ND ND ND ND --- 2.8 J NC 2L = 6,000 µg/L (01/01/10) Benzene 1-Oct-96 --- 5.0 --- NI --- --- ND 6 ND ND NI NI --- 1-May-97 ---5.0 ND NI --- ---ND 6.8 2.7 J ND NI NI --- 1-Nov-97 ---1.0 ND NI --- ---ND 9 ND ND NI NI ---1-May-98 --- 5.0 ND NI --- ---ND 10 9.4 ND NI NI ---24-Nov-98 --- 2.0 ND NI --- ---ND 11.6 ND ND NI NI --- 10-May-99 --- 5.0 ND ND --- ---ND 13 ND ND 5.3 ND ND 18-Oct-99 --- 5.0 ND ND --- ---ND 12 ND ND 5.4 ND ND 3-May-00 --- 5.0 ND ND --- ---ND 10 ND ND 6.3 ND ND 7-Nov-00 --- 5.0 ND ND --- ---ND 9.2 ND ND ND ND ND 31-May-01 --- 5.0 ND ND --- ---ND 7.7 ND ND 5.8 ND ND 7-Nov-01 --- 5.0 ND ND --- ---ND 8.1 5.2 ND 6.7 ND ND22-May-02 --- 5.0 ND ND --- ---ND 8.2 8.1 ND 8.0 ND ND14-Nov-02 --- 5.0 ND ND --- --- ND 5.1 7.7 ND 9.4 ND ND 14-May-03 --- 5.0 ND ND --- --- ND 8 5.4 7 13 ND ND 20-Nov-03 --- 5.0 ND ND --- --- ND 7.3 5.7 7.5 9.2 ND ND 6-May-04 --- 5.0 ND ND --- --- ND 7.3 7.2 9.3 9.6 ND ND 10-Nov-04 --- 5.0 ND ND --- --- ND 7.5 6 8.5 10 ND ND 27-May-05 --- 5.0 ND ND --- --- ND 8 9 11 9 ND ND 3-Nov-05 --- 5.0 --- ND --- --- ND ND 58 6ND ND 25-May-06 --- 5.0 --- ND --- --- ND ND 6.1 8.5 5.3 ND ND2-Nov-06 --- 5.0 --- ND --- --- ND 5.3 5.3 11 7.6 ND ND30-May-07 --- 1.0 --- 0.22 J --- --- 0.87 J 7.3 7.4 13 6.6 ND ND NC 2L = 1 µg/L (10/23/07) 29-Nov-07 --- 1.0 --- 0.6 J --- --- 0.79 J 3.6 2.8 12 3.3 ND ND 29-May-08 0.3 1.0 --- 0.49 J --- --- 0.88 J 4.6 4.6 13.5 4.1 ND ND 6-Nov-08 0.3 1.0 --- 0.53 J --- --- 0.81 J 4.3 4.4 12 3.1 ND ND 3-Jun-09 0.3 1.0 --- 0.67 J --- ---1.2 4.5 5.4 15.3 4.1 ND ND 18-Nov-09 0.3 1.0 --- 1.3 --- --- 0.81 J 4 5.6 14.9 3.3 ND ND 16-Jun-10 0.3 1.0 --- 0.59 J --- --- 0.81 J 5.9 5 14.3 2.4 ND ND1-Dec-10 0.3 1.0 --- ND ND --- 0.96 J 5 3 11.5 4 ND ND1-Jun-11 0.3 1.0 --- 0.99 J ND ---1 5.4 3.9 16.1 1.2 ND ND20-Dec-11 0.3 1.0 --- --- ND ---1 J 4.2 3.1 12.9 D 2 ND ND 30-May-12 0.3 1.0 --- --- ND --- ND 4.4 2.8 14.7 2 ND ND 5-Dec-12 0.3 1.0 --- --- ND --- 0.83 J 4.1 2.8 14.9 1.6 ND ND 12-Jun-13 0.3 1.0 --- --- ND ---1.5 3.5 4.2 15.9 2.9 ND ND 28-Oct-13 0.3 1.0 --- --- ND ---1 4.1 4.1 15.6 2 ND ND 6-May-14 EPA 8260 0.3 1.0 --- --- ND ---1.6 3.9 3.8 17.2 2.1 ND ND 22-Oct-14 EPA 8260 0.3 1.0 --- ---* ND 1.8 2.8 3.0 14.9 1.8 ND ND21-May-15 EPA 8260 0.3 1.0 --- --- ND ND 1.3 2.8 2.8 12.3 1.2 ND ND8-Dec-15 EPA 8260 0.3 1.0 --- ---* ND 1.6 2.2 2.3 13.8 1.7 ND ND Bromodichloromethane 30-May-07 --- 1.0 --- ND --- --- 0.54 J ND 0.63 J ND ND ND ND NC 2L = 0.56 µg/L (10/23/07)29-Nov-07 --- 1.0 --- ND --- --- ND ND ND ND ND ND ND 29-May-08 0.2 1.0 --- ND --- --- ND ND ND ND ND ND ND 6-Nov-08 0.2 1.0 --- ND --- --- ND ND ND ND ND ND ND 3-Jun-09 0.2 1.0 --- ND --- --- ND ND ND ND ND ND ND18-Nov-09 0.2 1.0 --- ND --- --- ND ND ND ND ND ND ND NC 2L = 0.6 µg/L (01/01/10)16-Jun-10 0.2 1.0 ---ND --- ---ND ND ND ND ND ND ND 1-Dec-10 0.2 1.0 ---ND ND ---ND ND ND ND ND ND ND 1-Jun-11 0.2 1.0 ---ND ND ---ND ND ND ND ND ND ND 20-Dec-11 0.2 1.0 --- --- ND --- ND ND ND ND ND ND ND 30-May-12 0.2 1.0 --- ---ND ---ND ND ND ND ND ND ND 5-Dec-12 0.2 1.0 --- ---ND ---ND ND ND ND ND ND ND 12-Jun-13 0.2 1.0 --- ---ND ---ND ND ND ND ND ND 18.6028-Oct-13 0.18 1.0 --- ---ND ---ND ND ND ND ND ND ND6-May-14 EPA 8260 0.18 1.0 --- ---ND ---ND ND ND ND ND ND ND 22-Oct-14 EPA 8260 0.18 1.0 --- ---*NDND ND ND ND ND ND ND 21-May-15 EPA 8260 0.18 1.0 --- ------ ND ND ND ND ND ND ND ND 8-Dec-15 EPA 8260 0.18 1.0 --- ------ ND ND ND ND ND ND ND ND Bromomethane 12-Jun-13 0.29 10.0 --- ---ND ---1.4 J ND ND ND ND ND ND NC 2L = NE (10/23/07)28-Oct-13 0.29 10.0 --- ---ND ---ND ND ND ND ND ND ND6-May-14 EPA 8260 0.29 10.0 --- ---ND ---ND ND ND ND ND ND ND22-Oct-14 EPA 8260 0.29 10.0 --- ---*NDND ND ND ND ND ND ND 21-May-15 EPA 8260 0.29 10.0 --- ------ ND ND ND ND ND ND ND ND 8-Dec-15 EPA 8260 0.29 10.0 --- ------ ND ND ND ND ND ND ND ND 2-Butanone (MEK) 20-Dec-11 1.0 100.0 --- --- ND --- ND ND ND 5.6 J D ND ND ND NC 2L = 4000 µg/L (10/23/07)30-May-12 1.0 100.0 --- ---ND ---ND ND ND ND ND ND ND 5-Dec-12 1.0 100.0 --- --- ND --- ND ND ND ND ND ND ND 12-Jun-13 1.0 100.0 --- --- ND --- ND ND ND ND ND ND ND 28-Oct-13 1.0 100.0 --- --- ND --- ND ND ND ND ND ND ND 6-May-14 EPA 8260 1.0 100.0 --- --- ND --- ND ND ND ND ND ND ND 22-Oct-14 EPA 8260 1.0 100.0 --- --- * NDNDNDNDND ND ND ND 21-May-15 EPA 8260 1.0 100.0 --- --- --- ND ND ND ND ND ND ND ND 8-Dec-15 EPA 8260 1.0 100.0 --- --- --- ND ND ND ND ND ND ND ND Background Downgradient Burke County John's River C and D over MSW Landfill Permit 12-03 Page 1 of 14 Joyce Engineering TABLE 2: HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample EPA Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Background Downgradient Carbon Disulfide 1-Nov-97 --- 1.0 8 NI --- --- ND ND ND ND NI NI --- 1-May-98 --- 5.0 ND NI --- --- ND ND ND ND NI NI ---24-Nov-98 --- 2.0 6.2 NI --- --- ND ND 8.9 ND NI NI ---10-May-99 --- 5.0 ND ND --- --- ND ND 6.7 9 ND 100 ND 18-Oct-99 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND 3-May-00 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND 7-Nov-00 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND 31-May-01 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND 7-Nov-01 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND 22-May-02 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND14-Nov-02 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND14-May-03 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND 20-Nov-03 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND 6-May-04 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND 10-Nov-04 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND 27-May-05 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND 3-Nov-05 ---100.0 ---ND --- ---ND ND ND ND ND ND ND25-May-06 ---100.0 ---ND --- ---ND ND ND ND ND ND ND2-Nov-06 ---100.0 ---ND --- ---ND ND ND ND ND ND ND30-May-07 --- 100.0 --- ND --- --- ND ND ND ND ND ND ND NC 2L = 700 µg/L (10/23/07)29-Nov-07 ---100.0 ---ND --- ---ND ND ND ND ND ND ND 29-May-08 1.2 100.0 ---ND --- ---ND ND ND ND ND ND ND 6-Nov-08 1.2 100.0 ---ND --- ---ND ND ND ND ND ND ND 3-Jun-09 1.20 100.0 ---ND --- ---ND ND ND ND ND ND ND 18-Nov-09 1.20 100.0 ---ND --- ---ND ND ND ND ND ND ND 16-Jun-10 1.20 100.0 ---ND --- ---ND ND ND ND ND ND ND1-Dec-10 1.20 100.0 ---ND ND ---ND ND ND ND ND ND ND1-Jun-11 1.20 100.0 ---ND ND ---ND ND ND ND ND ND ND 20-Dec-11 1.20 100.0 --- ---ND ---ND ND ND ND ND ND ND 30-May-12 1.20 100.0 --- ---ND ---ND ND ND ND ND ND ND 5-Dec-12 1.2 100.0 --- ---ND ---ND ND ND ND ND ND ND 12-Jun-13 1.2 100.0 --- ---ND ---ND ND ND ND ND ND ND 28-Oct-13 1.2 100.0 --- --- ND --- ND ND ND ND ND ND ND 6-May-14 EPA 8260 1.2 100.0 --- --- ND --- ND ND ND ND ND ND ND 22-Oct-14 EPA 8260 1.2 100.0 --- --- * ND ND ND ND ND ND ND 1.4 J21-May-15 EPA 8260 1.2 100.0 --- --- --- ND ND ND ND ND ND ND ND 8-Dec-15 EPA 8260 1.2 100.0 --- --- --- ND ND ND ND ND ND ND ND Chlorobenzene 30-May-07 --- 3.0 --- ND --- --- ND 0.63 J 1.1 J 0.3 J 0.61 J ND ND NC 2L = 50 µg/L (10/23/07)29-Nov-07 --- 3.0 --- ND --- --- ND ND ND ND ND ND ND 29-May-08 0.2 3.0 --- ND --- --- ND 0.48 J 0.7 J 0.32 J 0.59 J ND ND 6-Nov-08 0.2 3.0 --- ND --- --- ND 0.53 J 0.8 J 0.3 J 0.59 J ND ND 3-Jun-09 0.2 3.0 --- ND --- --- 0.26 J 0.47 J 0.73 J 0.39 J 0.76 J ND ND18-Nov-09 0.2 3.0 --- ND --- --- ND 0.51 J 1.0 J 0.39 J 0.71 J ND ND16-Jun-10 0.2 3.0 --- ND --- --- ND 0.9 J 1.2 J 0.41 J 0.79 J ND ND 1-Dec-10 0.2 3.0 --- ND ND --- ND 0.74 J 0.63 J ND 0.72 J ND ND 1-Jun-11 0.2 3.0 --- ND ND --- ND 0.8 J 1.0 J 0.5 J 0.4 J ND ND 20-Dec-11 0.2 3.0 --- --- ND --- ND 0.7 J 0.7 J ND 0.7 J ND ND 30-May-12 0.2 3.0 --- --- ND --- 0.24 J 0.73 J 0.7 J 0.47 J 0.7 J ND ND 5-Dec-12 0.2 3.0 --- --- ND --- ND 0.7 J 0.6 J 0.54 J 0.7 J ND ND 12-Jun-13 0.2 3.0 --- --- ND --- 0.88 J 0.57 J 0.86 J 0.57 J 0.65 J ND ND28-Oct-13 0.2 3.0 --- --- ND --- 0.35 J 0.93 J 0.94 J 0.6 J 0.91 J ND ND6-May-14 EPA 8260 0.2 3.0 --- --- ND --- 0.7 J 0.93 J 0.9 J 0.79 J 0.91 J ND ND22-Oct-14 EPA 8260 0.2 3.0 --- --- * ND 0.84 J 0.77 J 0.79 J 0.80 J 0.78 J ND ND 21-May-15 EPA 8260 0.2 3.0 --- --- --- ND 0.67 J 0.84 J 0.74 J 0.72 J 0.58 J ND ND 8-Dec-15 EPA 8260 0.2 3.0 --- --- --- ND 1.5 J 0.61 J 0.73 J 0.86 J 0.82 J ND ND Burke County John's River C and D over MSW Landfill Permit 12-03 Page 2 of 14 Joyce Engineering TABLE 2: HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample EPA Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Background Downgradient Chloroethane 1-Sep-94 --- 10.0 ND NI NI NI ND 29 ND ND NI NI --- 1-Jan-95 --- 10.0 --- NI NI NI ND 16 ND ND NI NI ---1-Feb-95 ---10.0 ---NI NI NI ND32ND ND NI NI --- 1-Mar-95 ---10.0 ND NI NI NI ND34 11ND NI NI --- 1-Aug-95 ---10.0 ND NI --- ---ND47ND ND NI NI --- 1-Jan-96 --- 10.0 --- NI --- --- ND ND ND ND NI NI --- 1-Feb-96 ---10.0 ---NI --- ---ND28ND ND NI NI --- 1-May-96 ---10.0 ---NI --- ---ND34 11ND NI NI --- 1-Oct-96 ---10.0 ---NI --- ---ND 23 11.00 ND NI NI ---1-May-97 --- 5.0 3.8 J NI --- ---15 33 11 ND NI NI ---1-Nov-97 --- 1.0 3 NI --- ---10 ND7ND NI NI --- 1-May-98 --- 10.0 ND NI --- ---ND302810NI NI --- 24-Nov-98 --- 2.0 ND NI --- ---ND ND ND ND NI NI --- 10-May-99 --- 10.0 ND ND --- ---ND 10.0 ND ND17ND ND 18-Oct-99 --- 10.0 ND ND --- ---ND12ND ND21ND ND 3-May-00 --- 10.0 ND ND --- ---ND ND 6.1 6.7 19 ND ND 7-Nov-00 --- 10.0 ND ND --- ---ND ND ND ND13ND ND31-May-01 --- 10.0 ND ND --- ---ND ND ND ND12ND ND7-Nov-01 --- 10.0 ND ND --- ---ND ND ND ND ND ND ND 22-May-02 --- 10.0 12 ND --- --- ND ND ND ND 12 ND ND 14-Nov-02 --- 10.0 10 ND --- --- ND ND ND ND ND ND ND 14-May-03 --- 10.0 ND ND --- --- ND ND ND ND ND ND ND 20-Nov-03 --- 10.0 ND ND --- --- ND ND 10 ND ND ND ND 6-May-04 --- 10.0 ND ND --- --- ND ND ND ND ND ND ND 10-Nov-04 --- 10.0 ND ND --- --- ND ND 10 ND ND ND ND 27-May-05 --- 10.0 ND ND --- --- ND ND 10.0 ND ND ND ND3-Nov-05 --- 10.0 --- ND --- --- ND ND ND ND ND ND ND25-May-06 --- 10.0 --- ND --- --- ND ND ND ND ND ND ND2-Nov-06 --- 10.0 --- ND --- --- ND ND ND ND ND ND ND 30-May-07 --- 10.0 --- ND --- --- ND ND 9.8 J 8.9 J ND ND ND NC 2L = 2,800 µg/L (10/23/07) 29-Nov-07 --- 10.0 --- 1.4 J --- --- ND ND 4.3 J 5.7 JD 4.3 J ND ND 29-May-08 0.5 10.0 --- 1.2 J --- --- 1.1 J ND 1.5 J 6.0 J 2.6 J ND ND 6-Nov-08 0.5 10.0 --- 2 J --- --- ND 0.9 J 3.5 J 5.6 J 4.3 J ND ND 3-Jun-09 0.5 10.0 --- 1.1 J --- --- ND ND ND 4.0 J 4.4 J ND ND 18-Nov-09 0.5 10.0 --- 3.1 J --- --- 0.8 J 0.6 J 5.5 J 5.1 J 3.5 J ND NDNC 2L = 3,000 µg/L (01/01/10) 16-Jun-10 0.5 10.0 --- 1.7 J --- --- 0.72 J 0.88 J 3.1 J 4.5 J 2.2 J ND ND1-Dec-10 0.5 10.0 --- ND ND --- ND ND ND ND ND ND ND 1-Jun-11 0.5 10.0 --- 1.5 J ND --- 0.71 J ND 2.7 J 3.8 J ND ND ND 20-Dec-11 0.5 10.0 --- --- ND --- 0.64 J ND 2.1 J ND 2.9 J ND ND 30-May-12 0.5 10.0 --- --- ND --- ND ND 1.5 J 2.4 J ND ND ND 5-Dec-12 0.5 10.0 --- --- ND --- ND ND 1.8 J 2.7 J 1.9 J ND ND 12-Jun-13 0.5 10.0 --- --- ND --- ND ND 0.63 J 0.84 J 1.5 J ND ND 28-Oct-13 0.5 10.0 --- --- ND --- ND ND 1.9 J 2.3 J ND ND ND6-May-14 EPA 8260 0.5 10.0 --- --- ND --- ND ND 1.6 J 1.7 J 1.3 J ND ND22-Oct-14 EPA 8260 0.5 10.0 --- --- * ND 0.75 J ND ND 2.1 J 1.6 J ND ND 21-May-15 EPA 8260 0.5 10.0 --- --- --- ND ND ND ND ND ND ND ND 8-Dec-15 EPA 8260 0.5 10.0 --- --- --- ND ND ND ND ND ND ND ND Chloromethane 18-Nov-09 0.1 1.0 --- ND --- ---ND ND ND 0.45 J ND ND ND NC 2L = 3 µg/L (01/01/10)16-Jun-10 0.1 1.0 ---ND --- --- 0.14 J ND ND 0.48 J ND ND ND 1-Dec-10 0.1 1.0 ---ND ND ---ND ND ND ND ND ND ND1-Jun-11 0.1 1.0 ---ND ND ---ND ND ND ND ND ND ND20-Dec-11 0.1 1.0 --- ---ND ---ND ND ND ND ND ND ND 30-May-12 0.1 1.0 --- ---ND ---ND ND ND ND ND ND ND 5-Dec-12 0.1 1.0 --- ---ND ---ND ND ND ND ND ND ND 12-Jun-13 0.1 1.0 --- ---ND ---ND ND ND ND ND ND ND 28-Oct-13 0.11 1.0 --- ---ND ---ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.11 1.0 --- ---ND ---ND ND ND ND ND ND ND 22-Oct-14 EPA 8260 0.11 1.0 --- ---*NDND ND ND ND ND ND ND 21-May-15 EPA 8260 0.11 1.0 --- ------ ND ND ND ND ND ND ND ND8-Dec-15 EPA 8260 0.11 1.0 --- ------ ND ND ND ND ND ND ND ND Chloroform 30-May-07 --- 5.0 ---ND --- ---0.92 B 1.2 B 0.99 B 1.4 B 1 B ND 0.98 J NC 2L = 70 µg/L (10/23/07)29-Nov-07 --- 5.0 ---ND --- ---ND ND ND ND ND ND ND 29-May-08 0.14 5.0 ---ND --- ---ND ND ND ND ND ND ND 6-Nov-08 0.14 5.0 ---ND --- ---ND ND ND ND ND ND ND 3-Jun-09 0.14 5.0 ---ND --- ---ND ND ND ND ND ND ND18-Nov-09 0.14 5.0 ---ND --- ---ND ND ND ND ND ND ND16-Jun-10 0.14 5.0 ---ND --- ---ND ND ND 0.2 B ND ND 0.29 J 1-Dec-10 0.1 5.0 ---ND ND ---ND ND ND ND ND ND ND 1-Jun-11 0.1 5.0 ---ND ND ---ND ND ND 0.36 B ND ND 0.63 J 20-Dec-11 0.1 5.0 --- --- ND --- ND ND ND ND ND ND ND 30-May-12 0.1 5.0 --- --- ND --- ND ND ND ND ND ND ND 5-Dec-12 0.1 5.0 --- --- ND --- ND ND ND 0.14 J ND ND ND 12-Jun-13 0.1 5.0 --- --- ND --- ND ND ND ND ND ND 46 28-Oct-13 0.1 5.0 --- --- ND --- ND ND ND ND ND ND ND6-May-14 EPA 8260 0.1 5.0 --- --- ND --- ND ND ND ND ND ND ND22-Oct-14 EPA 8260 0.1 5.0 --- --- * ND ND ND ND ND ND ND ND21-May-15 EPA 8260 0.1 5.0 --- --- --- ND ND ND ND ND ND ND ND 8-Dec-15 EPA 8260 0.1 5.0 --- --- --- ND ND ND ND ND ND ND ND Dibromochloromethane 30-May-07 --- 1.0 --- ND --- --- 1.7 ND ND ND 1.7 ND ND GWPS = 0.41 µg/L (10/23/07) Nov-07 --- 3.0 --- ND --- --- ND ND ND ND ND ND ND May-08 0.2 3.0 --- ND --- --- ND ND ND ND ND ND ND Nov-08 0.2 3.0 --- ND --- --- ND ND ND ND ND ND NDJun-09 0.2 3.0 --- ND --- --- ND ND ND ND ND ND NDNov-09 0.2 3.0 --- ND --- --- ND ND ND ND ND ND ND NC 2L = 0.4 µg/L (01/01/10) Jun-10 0.2 3.0 --- ND --- --- ND ND ND ND ND ND ND Dec-10 0.2 3.0 --- ND ND --- ND ND ND ND ND ND ND Jun-11 0.2 3.0 --- ND ND --- ND ND ND ND ND ND ND Dec-11 0.2 3.0 --- --- ND --- ND ND ND ND ND ND ND May-12 0.2 3.0 --- --- ND --- ND ND ND ND ND ND ND 5-Dec-12 0.2 3.0 --- --- ND --- ND ND ND ND ND ND ND12-Jun-13 0.2 3.0 --- --- ND --- ND ND ND ND ND ND 9.228-Oct-13 0.2 3.0 --- --- ND --- ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.2 3.0 --- --- ND --- ND ND ND ND ND ND ND 22-Oct-14 EPA 8260 0.2 3.0 --- --- * ND ND ND ND ND ND ND ND 21-May-15 EPA 8260 0.2 3.0 --- --- --- ND ND ND ND ND ND ND ND 8-Dec-15 EPA 8260 0.2 3.0 --- --- --- ND ND ND ND ND ND ND ND Burke County John's River C and D over MSW Landfill Permit 12-03 Page 3 of 14 Joyce Engineering TABLE 2: HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample EPA Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Background Downgradient 1,2-Dichlorobenzene 3-Jun-09 0.3 5.0 --- ND --- --- ND ND ND 0.4 J ND ND ND NC 2L = 24 µg/L (10/23/07)18-Nov-09 0.3 5.0 --- ND --- --- ND ND ND 0.4 J ND ND NDNC 2L = 20 µg/L (01/01/10)16-Jun-10 0.3 5.0 --- ND --- --- ND 0.39 J ND 0.4 J ND ND ND1-Dec-10 0.3 5.0 --- ND ND --- ND 0.49 J ND 0.5 J ND ND ND 1-Jun-11 0.3 5.0 --- ND ND --- ND 0.5 J ND 0.5 J ND ND ND 20-Dec-11 0.3 5.0 --- --- ND --- ND 0.4 J ND ND ND ND ND 30-May-12 0.3 5.0 --- ---ND ---ND 0.4 J ND 0.6 J ND ND ND 5-Dec-12 0.3 5.0 --- ---ND ---ND 0.4 J ND 0.6 J ND ND ND 12-Jun-13 0.3 5.0 --- ---ND ---ND 0.4 J ND 0.6 J ND ND ND28-Oct-13 0.3 5.0 --- --- ND --- ND 0.39 J ND 0.54 J ND ND ND6-May-14 EPA 8260 0.3 5.0 --- ---ND ---ND 0.46 J ND 0.55 J ND ND ND 22-Oct-14 EPA 8260 0.3 5.0 --- ---*NDND 0.45 J ND ND ND ND ND 21-May-15 EPA 8260 0.3 5.0 --- ------ ND ND 0.45 J ND 0.58 J ND ND ND 8-Dec-15 EPA 8260 0.3 5.0 --- ------ ND ND 0.39 J ND 0.45 J ND ND ND 1,4-Dichlorobenzene 1-Sep-94 ---5.0 ND NI NI NI ND 6.5 ND ND NI NI --- 1-Oct-94 --- 5.0 ---NI NI NI ---8 --- ---NI NI ---1-Jan-95 --- 5.0 ---NI NI NI ND ND ND ND NI NI ---1-Feb-95 --- 5.0 ---NI NI NI ND 9.8 ND ND NI NI --- 1-Mar-95 --- 5.0 ND NI NI NI ND 12.0 ND ND NI NI --- 1-Aug-95 --- 5.0 ND NI --- ---ND 14.0 ND ND NI NI --- 1-Jan-96 --- 5.0 ---NI --- ---ND 20 ND ND NI NI --- 1-Feb-96 --- 5.0 ---NI --- ---ND 19.0 ND ND NI NI --- 1-May-96 --- 5.0 ---NI --- ---ND 18 ND ND NI NI --- 1-Oct-96 --- 5.0 ---NI --- ---ND 16.0 ND ND NI NI --- 1-May-97 --- 5.0 ND NI --- ---ND 14.0 ND ND NI NI ---1-Nov-97 --- 1.0 ND NI --- ---ND ND ND ND NI NI ---1-May-98 --- 5.0 ND NI --- ---ND ND ND ND NI NI --- 24-Nov-98 --- 2.0 ND NI --- --- ND 4 ND ND NI NI --- 10-May-99 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND 18-Oct-99 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND 3-May-00 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND 7-Nov-00 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND 31-May-01 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND 7-Nov-01 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND22-May-02 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND14-Nov-02 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND 14-May-03 --- 5.0 ND ND --- --- ND 7.2 ND ND 6.5 ND ND 20-Nov-03 --- 5.0 ND ND --- --- ND 12 ND ND 5.7 ND ND 6-May-04 --- 5.0 ND ND --- --- ND 14 ND ND 5.2 ND ND 10-Nov-04 --- 5.0 ND ND --- --- ND 17 ND ND 6.7 ND ND 27-May-05 --- 5.0 ND ND --- --- ND 20.0 ND ND 6.0 ND ND 3-Nov-05 --- 5.0 --- ND --- --- ND 21 ND ND 6.0 ND ND25-May-06 --- 5.0 --- ND --- --- ND 16.5 ND ND 5.4 ND ND2-Nov-06 --- 5.0 --- ND --- --- ND 16 ND ND 7.2 ND ND 30-May-07 --- 1.0 --- ND --- --- ND 23.0 5.2 4.4 7.2 ND ND NC 2L = 1.4 µg/L (10/23/07)29-Nov-07 --- 1.0 --- ND --- --- ND 11 2.3 4.5 5.2 ND ND 29-May-08 0.3 1.0 --- ND --- --- ND 13.5 3.1 5.2 6.0 ND ND 6-Nov-08 0.3 1.0 --- ND --- --- ND 9.7 Q 3.7 4.3 5.5 ND ND 3-Jun-09 0.3 1.0 --- ND --- --- ND 14.3 4.2 7.3 8.0 ND ND 18-Nov-09 0.3 1.0 --- ND --- --- ND 12.2 4.5 6.4 6.8 ND 0.55 JNC 2L = 6 µg/L (01/01/10)16-Jun-10 0.3 1.0 --- ND --- --- ND 19.8 4.7 6.8 5.7 ND ND1-Dec-10 0.3 1.0 --- ND ND --- 0.43 J 18.5 3.5 7.5 7.5 ND ND1-Jun-11 0.3 1.0 --- ND ND --- ND 19.2 4.5 8.4 3.4 ND ND 20-Dec-11 0.3 1.0 --- --- ND --- 0.37 J 13.9 4 7.8 D 6.5 ND ND 30-May-12 0.3 1.0 --- --- ND --- ND 16.4 4.2 9.9 7.0 ND ND 5-Dec-12 0.3 1.0 --- --- ND --- ND 15 4.4 9.7 6.0 ND ND 12-Jun-13 0.3 1.0 --- --- ND --- 0.48 J 12.4 4.9 9.7 7.5 ND ND 28-Oct-13 0.3 1.0 --- ---0.63 J ---0.45 J 16.7 5 10.1 8.3 ND ND6-May-14 EPA 8260 0.3 1.0 --- ---ND ---0.63 J 18 5.2 12.3 8.9 ND ND22-Oct-14 EPA 8260 0.3 1.0 --- ---*ND0.73 J 16.1 4.8 11.9 7.5 ND ND 21-May-15 EPA 8260 0.3 1.0 --- ------ ND 0.7 J 17.1 5.0 12.0 7.1 ND ND 8-Dec-15 EPA 8260 0.3 1.0 --- ------ ND 0.98 J 12.6 4.8 13.2 9.1 ND ND Burke County John's River C and D over MSW Landfill Permit 12-03 Page 4 of 14 Joyce Engineering TABLE 2: HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample EPA Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Background Downgradient Dichlorodifluoromethane 1-Aug-95 --- 5.0 ND NI --- --- ND 26 ND 22 NI NI --- #1-Jan-96 ---5.0 ---NI --- ---ND ND ND ND NI NI ---1-Feb-96 ---10.0 ---NI --- ---ND ND ND ND NI NI --- 1-May-96 ---10.0 ---NI --- ---ND35 25ND NI NI --- 1-Oct-96 --- 5.0 ---NI --- ---ND ND ND ND NI NI --- 1-May-97 --- 5.0 6.4 NI --- ---ND 16 20.0 42.0 NI NI --- 1-Nov-97 --- 5.0 14 NI --- ---ND ND 31.0 90.0 NI NI --- 24-Nov-98 --- 2.0 ND NI --- ---ND ND ND ND NI NI --- 10-May-99 --- 10.0 ND ND --- ---ND ND 19.0 27.0 ND ND ND18-Oct-99 --- 5.0 ND ND --- ------ 14.0 50.0 130.0 25 ND ND3-May-00 --- 5.0 --- ------ ------ND 16.00 36.0 8.9 ---ND 7-Nov-00 --- 5.0 ND ------ ---ND ND 9.40 30.0 7.9 ---ND 31-May-01 --- 5.0 ND ------ ---ND ND 13 25 6.2 ---ND 7-Nov-01 --- 5.0 ND --- --- --- ND 5.5 ND 34 12 --- ND 22-May-02 --- 5.0 ND --- --- --- ND 5 15 24 11 --- ND 14-Nov-02 --- 5.0 ND --- --- --- ND ND ND 20 ND --- ND 14-May-03 --- 5.0 ND --- --- --- ND ND 8.7 12 ND --- ND 20-Nov-03 --- 5.0 ND ND --- --- ND ND 6.3 10 ND ND ND6-May-04 --- 5.0 ND --- --- --- ND ND ND 9.2 ND --- ND10-Nov-04 --- 5.0 ND --- --- --- ND ND 7.6 10 ND ND ND 27-May-05 --- 5.0 ND --- --- --- ND ND 14 22 ND --- ND 3-Nov-05 --- 5.0 --- ND --- --- ND ND 9 12 ND ND ND 25-May-06 --- 5.0 --- --- --- --- ND ND ND 5.4 ND --- ND 2-Nov-06 --- 5.0 --- ND --- --- ND ND 8.2 6.6 ND ND ND 30-May-07 --- 5.0 --- --- --- --- ND ND 7.1 7.6 ND --- --- NC 2L = 1,400 µg/L (10/23/07) 29-Nov-07 --- 5.0 --- ND --- --- ND ND 1.1 J 1.8 JD ND ND ND29-May-08 0.2 1.0 --- --- --- --- ND 0.35 J 2.9 3.6 ND --- ND6-Nov-08 0.2 5.0 --- 0.62 J --- ---ND 0.33 J 1.9 J 2.2 J 0.69 J ND ND 3-Jun-09 0.2 5.0 --- 0.45 J --- ---0.96 J ND 2.5 J 1.9 J 0.72 J ND ND 18-Nov-09 0.2 5.0 ---ND --- ---ND ND 1.2 J 1.9 J 0.47 J ND ND NC 2L = 1,000 µg/L (01/01/10)16-Jun-10 0.2 5.0 ---ND --- ---ND ND 0.81 J 1.4 J ND ND ND 1-Dec-10 0.2 5.0 --- 0.26 J ND ---ND ND 0.69 J 1.1 J 0.55 J ND ND 1-Jun-11 0.2 5.0 --- 0.42 J ND ---ND ND ND 1.2 J ND ND ND 20-Dec-11 0.2 5.0 --- --- ND --- ND ND ND 0.76 JD ND ND ND 30-May-12 0.2 5.0 --- ---ND ---ND ND ND ND ND ND ND 5-Dec-12 0.2 5.0 --- --- ND --- ND ND ND ND ND --- ND 12-Jun-13 0.2 5.0 --- --- ND ---0.34 J ND ND ND ND ND ND 28-Oct-13 0.2 5.0 --- --- ND ---ND ND ND 1.1 J ND ND ND 6-May-14 EPA 8260 0.2 5.0 --- --- ND ---ND ND ND ND ND ---ND 22-Oct-14 EPA 8260 0.2 5.0 --- ---* ND ND ND ND ND ND ---ND21-May-15 EPA 8260 0.2 5.0 --- --- --- ND ND ND ND ND ND ---ND 8-Dec-15 EPA 8260 0.2 5.0 --- --- --- ND ND ND ND ND ND ---ND 1,1-Dichloroethane 1-Sep-94 --- 5.0 ND NI NI NI ND 50 7.5 ND NI NI --- 1-Jan-95 --- 5.0 ---NI NI NI ND35 33ND NI NI --- 1-Feb-95 --- 5.0 ---NI NI NI ND66 34ND NI NI --- 1-Mar-95 --- 5.0 ND NI NI NI ND 72 34 ND NI NI --- 1-Aug-95 --- 5.0 ND NI --- ---ND 96 ND ND NI NI ---1-Jan-96 --- 5.0 --- NI --- --- 13 120 54 ND NI NI ---1-Feb-96 --- 5.0 --- NI --- --- 11 ND ND ND NI NI --- 1-May-96 --- 5.0 --- NI --- --- 12 110 68 ND NI NI --- 1-Oct-96 --- 5.0 --- NI --- --- 17 140 86 ND NI NI --- 1-May-97 --- 5.0 ND NI --- --- 39 170 100 4 J NI NI --- 1-Nov-97 --- 1.0 2 NI --- ---22 200 69.0 8 NI NI --- 1-May-98 --- 5.0 5.5 NI --- --- 22.0 250.0 250.0 45.0 NI NI --- 24-Nov-98 --- 2.0 3.8 NI --- --- 14 150.0 57 19.9 NI NI --- 10-May-99 --- 5.0 7.7 ND --- --- 9.7 180.0 64.0 30.0 120 ND ND18-Oct-99 --- 5.0 11.0 J ND --- --- 9.3 J 200 59 30.0 120 ND ND3-May-00 --- 5.0 9.3 J ND --- --- 6.2 J 120.0 61.0 38.0 120 ND ND 7-Nov-00 --- 5.0 9.5 ND --- --- 5.0 110.0 60.0 44.0 92 ND ND 31-May-01 --- 5.0 7.9 6 --- --- ND 80.0 75.0 45.0 79 ND ND 7-Nov-01 --- 5.0 14.0 5.3 --- --- ND 84.0 100.0 42.0 95 ND ND 22-May-02 --- 5.0 19.0 ND --- --- ND 75.0 110.0 57 100 ND ND 14-Nov-02 --- 5.0 21.0 ND --- --- ND 41.0 90.0 50.0 82 ND ND 14-May-03 --- 5.0 27.0 ND --- --- ND 48.0 60.0 69.0 82 ND ND20-Nov-03 --- 5.0 25.0 ND --- --- ND 34.0 48.0 62.0 59 ND ND6-May-04 --- 5.0 33.0 ND --- --- ND 33 58.0 72.0 58 ND ND 10-Nov-04 --- 5.0 38.0 ND --- --- ND 22.0 37.0 50.0 42 ND ND 27-May-05 --- 5.0 68.0 ND --- --- ND 25 48 66 44.0 ND ND 3-Nov-05 --- 5.0 --- ND --- --- ND 18.0 34 54.0 38 ND ND 25-May-06 --- 5.0 --- ND --- --- ND 10.9 27 37.6 25.3 ND ND 2-Nov-06 --- 5.0 --- ND --- --- ND 12 34 47 33 ND ND 30-May-07 --- 5.0 --- 5.3 --- --- 3.3 J 16 48 59 41 ND NDNC 2L = 70 µg/L (10/23/07)29-Nov-07 --- 5.0 --- 6.1 --- --- 2.2 J 7.7 39 44 34 ND ND29-May-08 0.3 5.0 --- 1.7 J --- --- 1.7 J 8.7 38.8 ND 29.7 ND ND6-Nov-08 0.3 5.0 --- 5.7 --- --- 1.9 J 8.1 34.6 52.3 26.2 ND ND 3-Jun-09 0.3 5.0 --- 6.3 --- --- 1.3 J 8.2 47.8 53.1 32 ND ND 18-Nov-09 0.3 5.0 --- 10.8 --- --- 1.2 J 6.7 41.9 52.0 29.4 ND ND NC 2L = 6 µg/L (01/01/10)16-Jun-10 0.3 5.0 --- 3.9 J --- --- 1.2 J 5.7 35.7 43.1 32.1 ND ND 1-Dec-10 0.3 5.0 ---6.8 ND ---1.7 J 5.4 41.3 37.9 16.9 ND ND 1-Jun-11 0.3 5.0 ---9.3 ND ---2J6.8 45.5 53.3 19.1 ND ND20-Dec-11 0.3 5.0 --- ---ND ---1.9 J 5.1 39.7 39.7 D 26.2 ND ND30-May-12 0.3 5.0 --- --- ND --- 1.5 J 5.9 38.2 45.8 24.1 ND ND 5-Dec-12 0.3 5.0 --- ---ND ---1.7 J 4.6 J 39.3 39.3 26.5 ND ND 12-Jun-13 0.3 5.0 --- ---ND ---0.73 J 5.3 37.1 41.6 21.4 ND ND 28-Oct-13 0.3 5.0 --- ---ND ---1 J 4.9 J 43.2 41.8 26.2 ND ND 6-May-14 EPA 8260 0.3 5.0 --- ---ND ---1J4J43.4 39.5 21.5 ND ND 22-Oct-14 EPA 8260 0.3 5.0 --- ---*ND1.3 J 3.6 J 34.4 33.2 25.3 ND ND 21-May-15 EPA 8260 0.3 5.0 --- ------ ND 0.75 J 2.8 J 26.7 23.1 17.3 ND ND8-Dec-15 EPA 8260 0.3 5.0 --- ------ ND 0.95 J 3.2 J 31.7 33.7 10.3 ND ND Burke County John's River C and D over MSW Landfill Permit 12-03 Page 5 of 14 Joyce Engineering TABLE 2: HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample EPA Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Background Downgradient 1,2-Dichloroethane 3-Nov-05 --- 5.0 ---ND --- ---ND 13 ND ND ND ND ND25-May-06 --- 5.0 ---ND --- ---ND ND ND ND ND ND ND2-Nov-06 --- 5.0 ---ND --- ---ND ND ND ND ND ND ND 30-May-07 --- 1.0 ---ND --- ---ND 2.4 ND 1.6 ND ND ND NC 2L = 0.38 µg/L (10/23/07)29-Nov-07 --- 1.0 ---ND --- ---ND ND ND ND ND ND ND 29-May-08 0.1 1.0 ---ND --- ---ND 1.2 0.64 J 1.5 1.1 ND ND 6-Nov-08 0.1 1.0 ---ND --- ---ND 0.65 B 0.27 B 1.8 B 0.46 B ND1J 3-Jun-09 0.1 1.0 ---ND --- ---ND 0.78 J 0.8 J 1.9 0.98 J ND ND 18-Nov-09 0.1 1.0 --- ND --- --- ND 0.98 J 1.0 1.8 0.97 J ND ND NC 2L = 0.4 µg/L (01/01/10)16-Jun-10 0.1 1.0 --- ND --- --- ND 1.2 1.1 1.8 1.0 ND ND1-Dec-10 0.1 1.0 --- ND ND --- ND 0.94 J 0.58 J 1.5 0.18 J ND ND 1-Jun-11 0.1 1.0 --- ND ND --- ND ND 1.1 2.1 1.0 ND ND 20-Dec-11 0.1 1.0 --- --- ND --- ND 0.8 J 0.92 J 1.8 J 1.0 ND ND 30-May-12 0.1 1.0 --- ---ND ---ND 0.75 J 0.97 J 2 1 ND ND 5-Dec-12 0.12 1.0 ------ND ---ND 0.7 J 0.8 J 1.7 1.3 ND ND 12-Jun-13 0.1 1.0 --- ---ND ---ND 0.6 J 1.3 1.7 1.0 ND ND 28-Oct-13 0.1 1.0 --- ---ND ---ND 0.9 J 1.4 1.7 1.4 ND ND6-May-14 EPA 8260 0.1 1.0 --- ---ND ---ND 0.8 J 1.2 1.6 1.2 ND ND22-Oct-14 EPA 8260 0.1 1.0 --- --- *ND ND 0.51 J 0.85 J 1.5 1.2 ND ND 21-May-15 EPA 8260 0.1 1.0 --- --- ---ND ND ND 0.71 J ND ND ND ND 8-Dec-15 EPA 8260 0.2 1.0 --- --- ---ND ND 0.65 J ND 1.3 1.3 ND ND 1,1-Dichloroethene 1-May-97 --- 5.0 ND NI --- ---ND 3 J ND 4 J NI NI --- 1-Nov-97 --- 1.0 ND NI --- --- ND ND ND ND NI NI --- 1-May-98 --- 5.0 ND NI --- --- ND ND ND ND NI NI --- 24-Nov-98 --- 2.0 ND NI --- --- ND ND ND ND NI NI ---10-May-99 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND18-Oct-99 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND3-May-00 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND 7-Nov-00 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND 31-May-01 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND 7-Nov-01 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND 22-May-02 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND 14-Nov-02 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND 14-May-03 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND20-Nov-03 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND6-May-04 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND 10-Nov-04 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND 27-May-05 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND 3-Nov-05 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND 25-May-06 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND 2-Nov-06 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND 30-May-07 --- 5.0 --- ND --- --- ND ND 0.93 J 1.8 J 0.42 J ND NDNC 2L = 7 µg/L (10/23/07)29-Nov-07 --- 5.0 --- ND --- --- ND ND 0.8 J 1.2 JD 0.59 J ND ND29-May-08 0.6 1.0 --- ND --- --- ND ND 0.75 J 1.3 ND ND ND 6-Nov-08 0.6 5.0 --- ND --- --- ND ND 0.64 J 1.1 J ND ND ND 3-Jun-09 0.6 5.0 --- ND --- --- ND ND 0.95 J 1.1 J ND ND ND 18-Nov-09 0.6 5.0 ---ND --- ---ND ND 0.78 J 1.1 J ND ND ND 16-Jun-10 0.6 5.0 ---ND --- ---0.98 J ND 0.68 J 1.2 J ND ND ND 1-Dec-10 0.6 5.0 ---ND ND ---ND ND ND ND ND ND ND 1-Jun-11 0.6 5.0 --- ND ND --- ND ND 0.68 J 0.82 J ND ND ND 20-Dec-11 0.6 5.0 --- ---ND ---ND ND 0.59 J ND ND ND ND30-May-12 0.6 5.0 --- ---ND ---ND ND 0.62 J 0.58 J ND ND ND 5-Dec-12 0.6 5.0 --- ---ND ---ND ND 0.66 J 0.58 J ND ND ND NC 2L = 350 µg/L (04/01/2013)12-Jun-13 0.560 5.0 --- ---ND ---ND ND ND ND ND ND ND 28-Oct-13 0.560 5.0 --- ---ND ---ND ND 0.6 J ND ND ND ND 6-May-14 EPA 8260 0.560 5.0 --- ---ND ---ND ND 0.59 J ND ND ND ND 22-Oct-14 EPA 8260 0.560 5.0 --- ---*NDND ND ND ND ND ND ND 21-May-15 EPA 8260 0.560 5.0 --- ------ ND ND ND ND ND ND ND ND8-Dec-15 EPA 8260 0.560 5.0 --- ------ ND ND ND ND ND ND ND ND Burke County John's River C and D over MSW Landfill Permit 12-03 Page 6 of 14 Joyce Engineering TABLE 2: HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample EPA Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Background Downgradient cis-1,2-Dichloroethene 1-Feb-96 --- 5.0 ---NI --- ---11 89 35 ND NI NI ---1-May-96 --- 5.0 ---NI --- ---ND ND ND ND NI NI ---1-Oct-96 --- 5.0 ---NI --- ---ND ND ND ND NI NI --- 1-May-97 --- 5.0 ND NI --- ---ND 2.1 J ND ND NI NI --- 1-Nov-97 --- 1.0 ND NI --- ---ND ND ND ND NI NI --- 1-May-98 --- 5.0 ND NI --- --- ND ND ND ND NI NI --- 24-Nov-98 --- 2.0 ND NI --- --- ND 2.8 ND ND NI NI --- 10-May-99 --- 5.0 ND ND --- --- ND ND ND ND 7 ND ND 18-Oct-99 --- 5.0 ND ND --- --- ND 6.3 ND ND 14 ND ND 3-May-00 --- 5.0 ND ND --- --- ND ND ND ND 13 ND ND7-Nov-00 --- 5.0 ND ND --- --- ND ND ND ND 13 ND ND31-May-01 --- 5.0 ND ND --- --- ND ND ND ND 14 ND ND 7-Nov-01 --- 5.0 ND ND --- --- ND 5.9 6.5 ND 18 ND ND 22-May-02 --- 5.0 ND ND --- --- ND 8 11 ND 24 ND ND 14-Nov-02 --- 5.0 ND ND --- --- 5 7 13.0 ND 28 ND ND 14-May-03 --- 5.0 ND ND --- --- 7 11 8 5 36 ND ND 20-Nov-03 --- 5.0 ND ND --- --- 5 14 13 6 27 ND ND 6-May-04 --- 5.0 ND ND --- --- ND 16 17 7.2 32 ND ND10-Nov-04 --- 5.0 ND ND --- --- ND 14 13 5.8 29 ND ND27-May-05 --- 5.0 ND ND --- --- ND 16 23 8 23 ND ND 3-Nov-05 --- 5.0 --- ND --- --- ND 5 6 ND 9 ND ND 25-May-06 --- 5.0 --- ND --- --- ND 8.2 9.3 5.2 7.7 ND ND 2-Nov-06 --- 5.0 --- ND --- --- ND 16 12.0 12 17 ND ND 30-May-07 --- 5.0 --- ND --- --- 4.9 J 20 21.0 17 15 ND ND NC 2L = 70 µg/L (10/23/07) 29-Nov-07 --- 5.0 --- ND --- --- 2.9 J 8.6 7.2 13 9.1 ND ND 29-May-08 0.2 5.0 --- ND --- --- 2.8 J 13.4 10.9 18.4 10.4 ND ND6-Nov-08 0.2 5.0 --- 0.5 J --- --- 2.8 J 12.7 10 20.4 7.6 ND ND3-Jun-09 0.2 5.0 --- 0.71 J --- --- 2.5 J 13.1 11.9 25.3 10.4 ND ND18-Nov-09 0.2 5.0 --- 2.8 B --- --- 2.5 B 12.2 B 20 25.9 10.8 B ND 2.6 J 16-Jun-10 0.2 5.0 --- 1.7 J --- --- 2.3 J 14.8 15.6 22.2 9.7 ND ND 1-Dec-10 0.2 5.0 --- 0.66 J ND --- 3.1 J 11.3 9.2 19.7 7.1 ND ND 1-Jun-11 0.2 5.0 --- 0.89 J ND --- 3.7 J 14.5 13.8 28.8 5.7 ND ND 20-Dec-11 0.2 5.0 --- --- ND --- 3.7 J 9.5 9.7 21.4 D 6.5 ND ND 30-May-12 0.2 5.0 --- --- ND --- 3.1 J 11.8 11.2 26.5 6.8 ND ND 5-Dec-12 0.2 5.0 --- --- ND --- 3.3 J 9.1 9.4 25.4 6.6 ND ND12-Jun-13 0.2 5.0 --- --- ND --- 2.5 J 9 12.8 26.2 6.2 ND ND 28-Oct-13 0.2 5.0 --- ---ND ---3 J 11.2 14 29.1 7.7 ND ND 6-May-14 EPA 8260 0.2 5.0 --- ---ND ---3.4 J 9.5 13 27.1 7.7 ND ND 22-Oct-14 EPA 8260 0.2 5.0 --- ---*ND4.3 J 8.0 10.1 25 7.1 ND ND 21-May-15 EPA 8260 0.2 5.0 --- ------ ND 2.8 J 6.7 7.6 17.0 4.2 J ND ND 8-Dec-15 EPA 8260 0.2 5.0 --- ------ ND 3.9 J 6.9 9.9 25.8 4.4 J ND ND trans-1,2-Dichloroethene 5-Dec-13 0.5 5.0 --- --- ND --- ND ND 0.67 J 0.59 J ND ND NDNC 2L = 100 µg/L (10/23/07)12-Jun-13 0.5 5.0 --- ---ND ---ND ND ND ND ND ND ND 28-Oct-13 0.5 5.0 --- ---ND ---ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.5 5.0 --- ---ND ---ND ND ND ND ND ND ND 22-Oct-14 EPA 8260 0.5 5.0 --- ---*NDND ND ND ND ND ND ND 21-May-15 EPA 8260 0.5 5.0 --- ------ ND ND ND ND ND ND ND ND 8-Dec-15 EPA 8260 0.5 5.0 --- ------ ND ND ND ND ND ND ND ND 1,2-Dichloropropane 30-May-07 --- 1.0 ---ND --- ---ND ND ND 2.2 2.5 ND NDNC 2L = 0.51 µg/L (10/23/07)29-Nov-07 --- 1.0 ---ND --- ---ND ND ND ND 0.7 J ND ND29-May-08 0.3 1.0 ---ND --- ---ND ND 0.4 J 0.72 J 0.85 J ND ND 6-Nov-08 0.3 1.0 ---ND --- ---ND 0.32 J 0.5 J 0.68 J 0.67 J ND ND 3-Jun-09 0.3 1.0 ---ND --- ---ND ND ND 0.88 J 0.9 J ND ND 18-Nov-09 0.3 1.0 ---ND --- ---ND ND 0.5 J 0.7 J 0.84 J ND ND NC 2L = 0.6 µg/L (01/01/10)16-Jun-10 0.3 1.0 ---ND --- ---ND ND 0.5 J 0.7 J 0.67 J ND ND 1-Dec-10 0.3 1.0 ---ND ND ---ND 0.33 J 0.29 J 0.55 J 0.72 J ND ND 1-Jun-11 0.3 1.0 --- ND ND --- ND ND ND 0.88 J ND ND ND 20-Dec-11 0.3 1.0 --- --- ND --- ND ND 0.35 J 0.57 JD 0.48 J ND ND30-May-12 0.3 1.0 --- --- ND --- ND ND ND ND ND ND ND 5-Dec-12 0.3 1.0 --- --- ND --- ND ND 0.37 J 0.65 J 0.59 J ND ND 12-Jun-13 0.3 1.0 --- --- ND --- ND ND 0.35 J 0.6 J 0.59 J ND ND 28-Oct-13 0.3 1.0 --- --- ND --- ND ND ND ND 0.47 J ND ND 6-May-14 EPA 8260 0.3 1.0 --- ---ND ---ND ND 0.33 J 0.54 J 0.58 J ND ND 22-Oct-14 EPA 8260 0.3 1.0 --- ---*NDND ND ND ND 0.49 J ND ND 21-May-15 EPA 8260 0.3 1.0 --- ------ ND ND ND ND ND ND ND ND8-Dec-15 EPA 8260 0.3 1.0 --- ------ ND ND ND ND ND ND ND ND Burke County John's River C and D over MSW Landfill Permit 12-03 Page 7 of 14 Joyce Engineering TABLE 2: HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample EPA Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Background Downgradient Ethylbenzene 1-May-98 --- 5.0 ND NI --- ---ND ND 6.4 ND NI NI ---24-Nov-98 --- 2.0 ND NI --- ---ND ND ND ND NI NI ---10-May-99 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND 18-Oct-99 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND 3-May-00 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND 7-Nov-00 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND 31-May-01 --- 5.0 ND ND --- ---ND ND 6.4 ND ND ND ND 7-Nov-01 --- 5.0 ND ND --- --- ND ND 5 ND ND ND ND 22-May-02 --- 5.0 ND ND --- --- ND ND 14 ND ND ND ND 14-Nov-02 --- 5.0 ND ND --- --- ND ND 14 ND ND ND ND14-May-03 --- 5.0 ND ND --- --- ND ND 11 8.8 ND ND ND 20-Nov-03 --- 5.0 ND ND --- --- ND ND 15 8.3 ND ND ND 6-May-04 --- 5.0 ND ND --- --- ND ND 21 7.6 ND ND ND 10-Nov-04 --- 5.0 ND ND --- --- ND ND 11.0 ND ND ND ND 27-May-05 --- 5.0 ND ND --- --- ND ND 23 8 ND ND ND 3-Nov-05 --- 5.0 --- ND --- --- ND ND 14 9 ND ND ND 25-May-06 --- 5.0 --- ND --- --- ND ND 17 5.8 ND ND ND 2-Nov-06 --- 5.0 --- ND --- --- ND ND 8.4 ND ND ND ND30-May-07 --- 1.0 --- ND --- --- ND ND 18 4.1 ND ND NDNC 2L = 550 µg/L (10/23/07) 29-Nov-07 --- 1.0 --- ND --- --- ND ND 0.54 J 2 ND ND ND 29-May-08 0.3 1.0 --- ND --- --- ND ND 2.6 2.6 ND ND ND 6-Nov-08 0.3 1.0 --- ND --- --- ND ND 2 3.5 ND ND ND 3-Jun-09 0.3 1.0 --- ND --- --- ND ND 6 8 ND ND ND 18-Nov-09 0.3 1.0 --- ND --- --- ND ND 3.3 4.1 ND ND ND NC 2L = 600 µg/L (01/01/10) 16-Jun-10 0.3 1.0 --- ND --- --- ND ND 6.5 5 ND ND ND 1-Dec-10 0.3 1.0 --- ND ND --- ND ND 2.9 3 ND ND ND1-Jun-11 0.3 1.0 --- ND ND --- ND ND 1.3 3 ND ND ND20-Dec-11 0.3 1.0 --- --- ND --- ND ND 0.59 J 1.2 JD ND ND ND30-May-12 0.3 1.0 --- --- ND --- ND 0.38 J 0.77 J 7 ND ND ND 5-Dec-12 0.3 1.0 --- --- ND --- ND 0.32 J 1.1 2.1 ND ND ND 12-Jun-13 0.3 1.0 --- --- ND --- ND 0.4 J 2.3 5.1 ND ND ND 28-Oct-13 0.3 1.0 --- --- ND --- ND 0.35 J 1 5.9 ND ND ND 6-May-14 EPA 8260 0.3 1.0 --- --- ND --- ND ND ND 1.6 ND ND ND 22-Oct-14 EPA 8260 0.3 1.0 --- --- * ND ND ND 0.32 J 1.5 ND ND ND 21-May-15 EPA 8260 0.3 1.0 --- --- --- ND ND ND 0.86 J 1.3 ND ND ND8-Dec-15 EPA 8260 0.3 1.0 --- --- --- ND ND ND 1.2 2.7 ND ND ND Methylene Chloride 1-Sep-94 --- 5.0 ND NI NI NI ND 360 ND ND NI NI --- 1-Oct-94 ---5.0 ---NI NI NI ---430 --- ---NI NI --- 1-Jan-95 ---5.0 ---NI NI NI ND 290 ND ND NI NI --- 1-Feb-95 ---5.0 ---NI NI NI ND 560 ND ND NI NI --- 1-Mar-95 ---5.0 ND NI NI NI ND 610 ND ND NI NI ---1-Aug-95 ---5.0 ND NI --- ---ND 810 ND ND NI NI ---1-Jan-96 ---5.0 ---NI --- ---ND 380 ND ND NI NI --- 1-Feb-96 ---5.0 ---NI --- ---ND ND ND ND NI NI --- 1-May-96 --- 5.0 ---NI --- ---ND 330 5.3 ND NI NI --- 1-Oct-96 --- 5.0 ---NI --- ------68 19 ND NI NI --- 1-May-97 --- 5.0 ND NI --- ---2.4 J 280 11 ND NI NI --- 1-Nov-97 --- 5.0 ND NI --- ---ND ND ND ND NI NI --- 1-May-98 --- 5.0 ND NI --- ---ND 420 450 61 NI NI --- 24-Nov-98 --- 10.0 ND NI --- ---ND 92.5 B ND ND NI NI ---10-May-99 --- 5.0 ND ND --- ---ND 120.00 ND 37 ND ND ND18-Oct-99 --- 10.0 ND ND --- ---ND 78.00 B ND34BND ND21 3-May-00 --- 10.0 ND ND --- ---ND 98 ND 68 ND ND ND 7-Nov-00 --- 10.0 ND ND --- --- ND ND ND 56 ND ND ND 31-May-01 --- 10.0 ND ND --- --- ND 18 ND 96 ND ND ND 7-Nov-01 --- 10.0 ND ND --- --- ND ND ND 88 ND ND ND 22-May-02 --- 10.0 ND ND --- --- ND ND 11 130 ND ND ND 14-Nov-02 --- 10.0 ND ND --- --- ND ND 20 130 ND ND ND 14-May-03 --- 10.0 ND ND --- ---ND 18 ND 320 ND ND ND20-Nov-03 --- 10.0 ND ND --- --- ND ND ND 570 ND ND ND6-May-04 --- 10.0 12 ND --- --- ND ND 10 420 ND ND ND 10-Nov-04 --- 10.0 12 ND --- --- ND ND ND 360 ND ND ND 27-May-05 --- 10.0 40 ND --- --- ND ND ND 480 ND ND ND 3-Nov-05 --- 10.0 --- ND --- --- ND ND ND 510 ND ND ND 25-May-06 --- 10.0 --- ND --- --- ND ND ND 375 ND ND ND 2-Nov-06 --- 10.0 --- ND --- --- ND ND ND 210 ND ND ND 30-May-07 --- 1.0 --- 2.3 B --- --- ND ND ND 310 ND ND 3.2NC 2L = 4.6 µg/L (10/23/07) 29-Nov-07 --- 1.0 ---4.8 --- --- 0.89 J ND ND 220 ND ND ND29-May-08 1.0 2.0 --- 2.2 B --- --- ND ND ND 285 ND ND 1.5 J 6-Nov-08 1.0 2.0 --- 2.6 B --- --- 1.1 B ND ND 831 ND ND 3.2 J 3-Jun-09 1.0 2.0 --- ND --- --- ND ND ND 278 ND ND 19.1 18-Nov-09 1.0 2.0 ---11.1 --- --- ND ND ND 241 ND ND ND NC 2L = 5 µg/L (01/01/10) 16-Jun-10 1.0 2.0 --- ND --- --- ND ND ND 234 ND ND ND 1-Dec-10 1.0 1.0 --- 2.2 ND --- ND ND ND 174 ND ND ND 1-Jun-11 1.0 1.0 --- 2.3 ND --- ND ND ND 232 ND ND ND20-Dec-11 1.0 1.0 --- ---ND ---ND ND ND 196 D ND ND 1.930-May-12 1.0 1.0 --- ---ND ---ND ND ND 185 ND ND ND 5-Dec-12 1.0 1.0 --- ---ND ---ND ND ND 174 ND ND ND 12-Jun-13 1.0 1.0 --- ---ND ---ND ND ND 77.9 ND ND ND 28-Oct-13 1 1.0 --- ---ND ---ND ND ND 128 ND ND ND 6-May-14 EPA 8260 1 1.0 --- ---ND ---ND ND ND 154 ND ND 2.2 22-Oct-14 EPA 8260 1 1.0 --- ---*NDND ND ND 130 ND ND ND 21-May-15 EPA 8260 1 1.0 --- ------ ND ND ND ND 82.8 ND ND 1.78-Dec-15 EPA 8260 1 1.0 --- ------ ND ND ND ND 113 ND ND 2.0 Burke County John's River C and D over MSW Landfill Permit 12-03 Page 8 of 14 Joyce Engineering TABLE 2: HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample EPA Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Background Downgradient Iodomethane 29-May-08 0 10.0 --- 0.35 J --- ---ND ND ND ND ND ND NDNC 2L = NE (10/23/07)6-Nov-08 0 10.0 ---ND --- ---ND ND ND ND ND ND ND3-Jun-09 0 10.0 --- ND --- --- ND ND ND ND ND ND ND 18-Nov-09 0 10.0 --- ND --- --- ND ND ND ND ND ND ND 16-Jun-10 0 10.0 --- ND --- --- ND ND ND ND ND ND ND 1-Dec-10 0 10.0 --- ND ND --- 5 J ND ND ND ND ND ND 1-Jun-11 0.3 10.0 ---ND ND ---ND ND ND ND ND ND ND 20-Dec-11 0.3 10.0 --- --- ND --- ND ND ND ND ND ND ND 30-May-12 0.3 10.0 --- --- ND --- ND ND ND ND ND ND ND 5-Dec-12 0.3 10.0 --- --- ND --- ND ND ND ND ND ND ND12-Jun-13 0.3 10.0 --- --- ND --- 8.6 J ND ND ND ND ND ND28-Oct-13 0.3 10.0 --- --- ND --- ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.3 10.0 --- --- ND --- ND ND ND ND ND ND ND 22-Oct-14 EPA 8260 0.3 10.0 --- --- * ND ND ND ND ND ND ND ND 21-May-15 EPA 8260 0.3 10.0 --- --- --- ND ND ND ND ND ND ND ND 8-Dec-15 EPA 8260 0.3 10.0 --- --- --- ND ND ND ND ND ND ND ND Styrene 3-Jun-09 0.3 1.0 --- ND --- --- ND 2 ND ND ND ND NDNC 2L = 100 µg/L (10/23/07) 18-Nov-09 0.3 1.0 --- ND --- --- ND ND ND ND ND ND NDNC 2L = 70 µg/L (01/01/10) 16-Jun-10 0.3 1.0 --- ND --- --- ND ND ND ND ND ND ND 1-Dec-10 0.3 1.0 --- ND ND --- ND ND ND ND ND ND ND 1-Jun-11 0.3 1.0 --- ND ND --- ND ND ND ND ND ND ND 20-Dec-11 0.3 1.0 --- --- ND --- ND ND ND ND ND ND ND 30-May-12 0.3 1.0 --- --- ND --- ND ND ND ND ND ND ND 5-Dec-12 0.3 1.0 --- ---ND ---ND ND ND ND ND ND ND 12-Jun-13 0.3 1.0 --- ---ND ---ND ND ND ND ND ND ND28-Oct-13 0.3 1.0 --- ---ND ---ND ND ND ND ND ND ND6-May-14 EPA 8260 0.3 1.0 --- ---ND ---ND ND ND ND ND ND ND 22-Oct-14 EPA 8260 0.3 1.0 --- ---*NDND ND ND ND ND ND ND 21-May-15 EPA 8260 0.3 1.0 --- ------ ND ND ND ND ND ND ND ND 8-Dec-15 EPA 8260 0.3 1.0 --- ------ ND ND ND ND ND ND ND ND Tetrachloroethene 1-May-97 --- 5.0 5.6 NI --- ---ND 6.3 3.6 J ND NI NI --- 1-Nov-97 --- 1.0 2 NI --- ---ND ND ND ND NI NI ---1-May-98 --- 5.0 ND NI --- ---ND ND ND ND NI NI ---24-Nov-98 --- 2.0 6.7 NI --- ---ND 7.8 3.2 ND NI NI --- 10-May-99 --- 5.0 8.5 ND --- ---ND 9.3 ND ND ND ND ND 18-Oct-99 --- 5.0 5.3 ND --- ---ND 7.3 ND ND ND ND ND 3-May-00 --- 5.0 7 ND --- ---ND 6.4 ND ND ND ND ND 7-Nov-00 --- 5.0 6.6 ND --- ---ND 5.3 ND ND ND ND ND 31-May-01 --- 5.0 9.6 ND --- ---ND 7.1 ND ND ND ND ND 7-Nov-01 --- 5.0 9.5 ND --- ---ND 5.6 5 ND ND ND ND22-May-02 --- 5.0 10 ND --- ---ND 5.7 5.5 ND ND ND ND14-Nov-02 --- 5.0 8 ND --- ---ND ND ND ND ND ND ND 14-May-03 --- 5.0 10 ND --- --- ND 5.5 ND ND ND ND ND 20-Nov-03 --- 5.0 8.8 ND --- --- ND 6.6 ND ND ND ND ND 6-May-04 --- 5.0 8.9 ND --- --- ND ND ND ND ND ND ND 10-Nov-04 --- 5.0 12 ND --- --- ND ND ND 5.1 ND ND ND 27-May-05 --- 5.0 10 ND --- --- ND ND ND ND ND ND ND 3-Nov-05 --- 5.0 ---ND --- ---ND ND ND 12 ND ND ND 25-May-06 --- 5.0 ---ND --- ---ND ND ND ND ND ND ND2-Nov-06 --- 5.0 ---ND --- ---ND ND ND 5.8 ND ND ND30-May-07 --- 1.0 ---1.6 --- ---ND 0.44 J 1.6 5.9 ND ND NDNC 2L = 0.7 µg/L (10/23/07)29-Nov-07 --- 1.0 ---1.7 --- ---ND ND 1.1 4.9 ND ND ND 29-May-08 0.5 1.0 ---2.2 --- ---ND ND 1.1 6.6 ND ND ND 6-Nov-08 0.5 1.0 ---2.7 --- ---ND ND 1.3 6.2 ND ND ND 3-Jun-09 0.5 1.0 ---2.1 --- ---ND ND 0.7 J 7.5 ND ND ND 18-Nov-09 0.5 1.0 ---2.6 --- ---ND ND 0.49 J 6.3 ND ND ND 16-Jun-10 0.5 1.0 ---1.2 --- --- ND ND 0.46 J 6.7 ND ND ND 1-Dec-10 0.5 1.0 ---3 ND --- ND ND ND 5.8 ND ND ND1-Jun-11 0.5 1.0 ---3.6 ND --- ND ND ND 7.7 ND ND ND 20-Dec-11 0.5 1.0 --- --- ND --- ND 0.59 B 0.7 B 5.7 D ND ND 1 J 30-May-12 0.5 1.0 --- --- ND --- ND ND ND 7.7 ND ND ND 5-Dec-12 0.5 1.0 --- ---ND ---ND ND ND 7.3 ND ND ND 12-Jun-13 0.5 1.0 --- --- ND --- ND ND ND 6.4 ND ND ND 28-Oct-13 0.5 1.0 --- --- ND --- ND ND ND 5.7 ND ND ND 6-May-14 EPA 8260 0.5 1.0 --- --- ND --- ND ND ND 7.3 ND ND ND 22-Oct-14 EPA 8260 0.5 1.0 --- --- * ND ND ND ND 7.0 ND ND ND21-May-15 EPA 8260 0.5 1.0 --- --- --- ND ND ND ND 6.4 ND ND ND8-Dec-15 EPA 8260 0.5 1.0 --- --- --- ND ND ND ND 5.6 ND ND ND Tetrahydrofuran 1-Dec-10 3.1 10.0 --- ND ND --- ND ND ND 10.1 ND ND ND NC 2L = NE (01/01/10) 1-Jun-11 3.1 10.0 --- ND ND --- ND ND ND ND ND ND ND 20-Dec-11 3.1 10.0 --- --- ND --- ND ND ND 9.3 JD ND ND ND 30-May-12 3.1 10.0 --- --- ND --- ND ND ND 8.9 J ND ND ND 5-Dec-12 3.1 10.0 --- --- ND --- ND ND ND 6.9 J ND ND ND12-Jun-13 3.1 10.0 --- --- ND --- ND ND ND 6.3 J ND ND ND28-Oct-13 3.1 10.0 --- --- ND --- ND ND ND 8.6 J ND ND ND6-May-14 EPA 8260 3.1 10.0 --- --- ND --- ND ND ND 10.2 ND ND ND 22-Oct-14 EPA 8260 3.1 10.0 --- --- * ND ND ND ND 7.4 J ND ND ND 21-May-15 EPA 8260 3.1 NE --- --- --- ND ND ND ND 6.3 J ND ND ND 8-Dec-15 EPA 8260 3.1 NE --- --- --- ND ND ND ND 9.7 J ND ND ND Burke County John's River C and D over MSW Landfill Permit 12-03 Page 9 of 14 Joyce Engineering TABLE 2: HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample EPA Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Background Downgradient Toluene 1-Jan-95 --- 5.0 --- NI NI NI ND ND 19 ND NI NI --- 1-Feb-95 --- 5.0 --- NI NI NI ND ND ND ND NI NI ---1-Mar-95 ---5.0 ND NI NI NI ND ND ND ND NI NI --- 1-Aug-95 ---5.0 ND NI --- ---ND ND ND ND NI NI --- 1-Jan-96 ---5.0 ---NI --- ---ND ND ND ND NI NI --- 1-Feb-96 ---5.0 ---NI --- ---ND ND ND ND NI NI --- 1-May-96 ---5.0 ---NI --- ---ND ND ND ND NI NI --- 1-Oct-96 ---5.0 ---NI --- ---ND ND5ND NI NI --- 1-May-97 ---5.0 ND NI --- ---ND ND 2 J 3.4 J NI NI ---1-Nov-97 --- 1.0 ND NI --- ---ND ND ND ND NI NI ---1-May-98 --- 5.0 ND NI --- ---ND ND ND ND NI NI --- 24-Nov-98 --- 2.0 ND NI --- ---ND ND ND ND NI NI --- 10-May-99 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND 18-Oct-99 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND 3-May-00 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND 7-Nov-00 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND 31-May-01 --- 5.0 ND ND --- ---ND ND 22 15.00 ND ND ND7-Nov-01 --- 5.0 ND ND --- ---ND ND 11 7.20 ND ND ND22-May-02 --- 5.0 ND ND --- ---ND ND 11 17.00 ND ND ND 14-Nov-02 --- 5.0 ND ND --- ---ND ND21ND ND ND ND 14-May-03 --- 5.0 ND ND --- --- ND ND 8.4 86 ND ND ND 20-Nov-03 --- 5.0 ND ND --- --- ND ND 14 77 ND ND ND 6-May-04 --- 5.0 ND ND --- --- ND ND 22 54 ND ND ND 10-Nov-04 --- 5.0 ND ND --- --- ND ND ND 35 ND ND ND 27-May-05 --- 5.0 ND ND --- --- ND ND ND 100 ND ND ND 3-Nov-05 --- 5.0 ---ND --- ---ND ND20 80ND ND ND25-May-06 --- 5.0 --- ND --- --- ND ND 30.4 35.6 ND ND ND2-Nov-06 --- 5.0 --- ND --- --- ND ND ND 22 ND ND ND30-May-07 --- 1.0 --- ND --- --- 0.22 B 0.3 B 27.0 30 0.58 B ND 0.44 J NC 2L = 1,000 µg/L (10/23/07) 29-Nov-07 --- 1.0 --- ND --- --- ND ND 1.5 12.0 ND ND ND 29-May-08 0.3 1.0 --- ND --- --- ND ND 3.1 12.8 5.9 ND ND 6-Nov-08 0.3 1.0 --- ND --- --- ND ND 0.7 J 23.5 0.76 J ND ND 3-Jun-09 0.3 1.0 --- ND --- --- ND ND 0.4 J 52.6 0.85 J ND ND 18-Nov-09 0.3 1.0 --- ND --- --- ND ND ND 27.2 0.55 J ND ND NC 2L = 600 µg/L (01/01/10) 16-Jun-10 0.3 1.0 --- ND --- --- ND ND 2.5 34.8 0.38 J ND ND1-Dec-10 0.3 1.0 --- ND ND --- ND ND 4.1 17.5 ND ND ND1-Jun-11 0.3 1.0 --- ND ND --- ND ND ND 24.7 1.1 ND ND 20-Dec-11 0.3 1.0 --- --- ND --- ND ND ND 4.9 D 0.53 J ND ND 30-May-12 0.3 1.0 --- --- ND --- ND ND ND 46.8 0.67 J ND ND 5-Dec-12 0.3 1.0 --- --- ND --- ND ND 0.33 J 10.7 0.45 J ND ND 12-Jun-13 0.3 1.0 --- --- ND --- ND ND ND 27.6 0.7 J ND ND 28-Oct-13 0.3 1.0 --- --- ND --- ND ND ND 14.6 0.5 J ND ND 6-May-14 EPA 8260 0.3 1.0 --- --- ND --- ND ND ND 3.9 0.48 J ND ND22-Oct-14 EPA 8260 0.3 1.0 --- --- * ND ND ND ND 4.3 0.28 J ND ND21-May-15 EPA 8260 0.3 1.0 --- --- --- ND ND ND ND 4.1 ND ND ND 8-Dec-15 EPA 8260 0.3 1.0 --- --- --- ND ND ND ND 6.0 0.31 J ND ND 1,1,1-Trichloroethane 1-Sep-94 --- 5.0 ND NI NI NI ND 26 ND ND NI NI --- 1-Oct-94 --- 5.0 --- NI NI NI --- ND --- --- NI NI --- 1-Jan-95 --- 5.0 --- NI NI NI ND 23 ND ND NI NI --- 1-Feb-95 --- 5.0 --- NI NI NI ND 27 ND ND NI NI ---1-Mar-95 --- 5.0 ND NI NI NI ND 28 6.5 ND NI NI ---1-Aug-95 --- 5.0 ND NI --- --- ND 42 ND 5 NI NI ---1-Jan-96 --- 5.0 --- NI --- --- ND 44 6 9 NI NI --- 1-Feb-96 ---5.0 ---NI --- ---ND 31 6.7 ND NI NI --- 1-May-96 ---5.0 ---NI --- ---ND 30 6.7 9.2 NI NI --- 1-Oct-96 ---5.0 ---NI --- ---ND22 5 9 NI NI --- 1-May-97 --- 5.0 16 NI --- --- 2.4 J 19 5.3 17 NI NI --- 1-Nov-97 ---1.0 14 NI --- ---ND ND ND14 NI NI ---1-May-98 ---5.0 15 NI --- ---ND 9.3 9.3 22.0 NI NI ---24-Nov-98 ---2.0 10.1 NI --- ---ND 4.9 3 9.3 NI NI --- 10-May-99 --- 5.0 15 ND --- ---ND ND ND 8.7 ND ND ND 18-Oct-99 --- 5.0 11 ND --- ---ND ND ND 9.2 ND ND ND 3-May-00 --- 5.0 12 ND --- ---ND ND ND 8.5 ND ND ND 7-Nov-00 --- 5.0 10 ND --- ---ND ND ND 7.3 ND ND ND 31-May-01 --- 5.0 9.8 ND --- ---ND ND ND 6.0 ND ND ND 7-Nov-01 --- 5.0 14 ND --- ---ND ND ND 7.9 ND ND ND22-May-02 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND14-Nov-02 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND 14-May-03 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND 20-Nov-03 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND 6-May-04 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND 10-Nov-04 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND 27-May-05 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND 3-Nov-05 --- 5.0 --- ND --- --- ND ND ND 5.0 ND ND ND 25-May-06 --- 5.0 ---ND --- ---ND ND ND ND ND ND ND2-Nov-06 --- 5.0 ---ND --- ---ND ND ND ND ND ND ND30-May-07 --- 1.0 ---ND --- ---ND ND ND3ND ND ND NC 2L = 200 µg/L (10/23/07)29-Nov-07 --- 1.0 ---ND --- ---ND ND ND ND ND ND ND 29-May-08 0 1.0 --- ND --- --- ND ND ND 1 J ND ND ND 6-Nov-08 0 1.0 --- ND --- --- ND ND ND 1 J ND ND ND 3-Jun-09 0 1.0 --- ND --- --- ND ND ND 1 J ND ND ND 18-Nov-09 0 1.0 --- ND --- --- ND ND ND ND ND ND ND 16-Jun-10 0 1.0 --- ND --- --- ND ND ND ND ND ND ND 1-Dec-10 0 1.0 ---ND ND ---ND ND ND ND ND ND ND1-Jun-11 0 1.0 ---ND ND ---ND ND ND ND ND ND ND 20-Dec-11 0 1.0 --- ---ND ---ND ND ND ND ND ND ND 30-May-12 0 1.0 --- ---ND ---ND ND ND ND ND ND ND 5-Dec-12 0 1.0 --- --- ND --- ND ND ND ND ND ND ND 12-Jun-13 0 1.0 --- --- ND --- ND ND ND ND ND ND ND 28-Oct-13 0 1.0 --- --- ND --- ND ND ND ND ND ND ND 6-May-14 EPA 8260 0 1.0 --- --- ND --- ND ND ND ND ND ND ND 22-Oct-14 EPA 8260 0 1.0 --- --- * NDNDNDNDND ND ND ND21-May-15 EPA 8260 0 1.0 --- --- --- ND ND ND ND ND ND ND ND 8-Dec-15 EPA 8260 0 1.0 --- --- --- ND ND ND ND ND ND ND ND Burke County John's River C and D over MSW Landfill Permit 12-03 Page 10 of 14 Joyce Engineering TABLE 2: HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample EPA Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Background Downgradient Trichloroethene 1-Sep-94 --- 5.0 ND NI NI NI ND 9 ND ND NI NI ---1-Oct-94 --- 5.0 ---NI NI NI ---11 --- ---NI NI ---1-Jan-95 --- 5.0 ---NI NI NI ND 6 ND ND NI NI --- 1-Feb-95 --- 5.0 ---NI NI NI ND 10 ND ND NI NI --- 1-Mar-95 --- 5.0 ND NI NI NI ND 12 ND ND NI NI --- 1-Aug-95 --- 5.0 ND NI --- --- ND 13 ND ND NI NI --- 1-Jan-96 --- 5.0 --- NI --- --- ND 13 ND ND NI NI --- 1-Feb-96 --- 5.0 --- NI --- --- ND 14 ND ND NI NI --- 1-May-96 --- 5.0 --- NI --- --- ND 14 ND ND NI NI --- 1-Oct-96 --- 5.0 --- NI --- --- ND 14 ND ND NI NI ---1-May-97 --- 5.0 2 J NI --- ---ND 13 5JND NI NI --- 1-Nov-97 --- 1.0 2 NI --- ---ND16JND ND NI NI --- 1-May-98 --- 5.0 ND NI --- ---ND 14 13 ND NI NI --- 24-Nov-98 --- 2.0 4 NI --- ---ND 16 4 ND NI NI --- 10-May-99 --- 5.0 6 ND --- --- ND 19 5 ND ND ND ND 18-Oct-99 --- 5.0 ND ND --- --- ND 15 ND ND 5 ND ND 3-May-00 --- 5.0 5.4 ND --- --- ND 14 6 ND 6 ND ND 7-Nov-00 --- 5.0 ND ND --- --- ND 12 ND ND ND ND ND31-May-01 --- 5.0 ND ND --- --- ND 12 7 6 5 ND ND7-Nov-01 --- 5.0 ND ND --- --- ND 12 8 7 5 ND ND 22-May-02 --- 5.0 ND ND --- --- ND 10 9 8 ND ND ND 14-Nov-02 --- 5.0 ND ND --- --- ND 5.5 7.6 6.5 ND ND ND 14-May-03 --- 5.0 ND ND --- --- ND 11 7 12 6.8 ND ND 20-Nov-03 --- 5.0 ND ND --- --- ND 9.5 6.6 12 ND ND ND 6-May-04 --- 5.0 ND ND --- --- ND 9.1 5.8 12 ND ND ND 10-Nov-04 --- 5.0 ND ND --- --- ND 8.6 ND 11 ND ND ND27-May-05 --- 5.0 5 ND --- --- ND 11 ND 12 ND ND ND3-Nov-05 --- 5.0 --- ND --- --- ND 9 ND 14 ND ND ND25-May-06 --- 5.0 --- ND --- --- ND 8.6 ND 10 ND ND ND 2-Nov-06 --- 5.0 --- ND --- --- ND 7 ND 12 ND ND ND 30-May-07 --- 1.0 --- 2 --- --- 1.9 8.5 4.6 12 2.8 ND ND NC 2L = 2.8 µg/L (10/23/07) 29-Nov-07 --- 1.0 --- 1 --- --- 0.45 J 3.5 2.5 9.7 1.6 ND ND 29-May-08 0.47 1.0 --- ND --- --- ND 3.5 2.9 11.9 1.4 ND ND 6-Nov-08 0.47 1.0 --- 1.3 --- --- 0.53 J 3.7 3.3 11.6 1.3 ND ND 3-Jun-09 0.47 1.0 --- 1.8 --- --- ND 3.6 4.3 12.1 1.4 ND ND18-Nov-09 0.47 1.0 --- 1.9 --- --- 0.58 J 3.3 3.3 11.2 1.2 ND NDNC 2L = 3 µg/L (01/01/10)16-Jun-10 0.47 1.0 --- 0.6 J --- --- ND 5.1 3.3 11.2 1.4 ND ND 1-Dec-10 0.47 1.0 --- 1.9 ND --- 0.76 J 3.7 3.3 9.3 ND ND ND 1-Jun-11 0.47 1.0 ---2 ND --- 0.51 J 2.8 3.2 11.4 ND ND ND 20-Dec-11 0.47 1.0 --- --- ND --- 0.6 J 2.5 3.5 10 D 1.1 ND ND 30-May-12 0.47 1.0 --- --- ND --- ND 2.5 2.6 11.1 0.55 J ND ND 5-Dec-12 0.47 1.0 --- --- ND --- 0.53 J 2.3 3.3 11.2 0.67 J ND ND 12-Jun-13 0.47 1.0 --- --- ND --- 0.66 J 2.1 1.8 11.5 0.76 J ND ND28-Oct-13 0.47 1.0 --- --- ND --- ND 3.1 2.5 10.7 0.76 J ND ND6-May-14 EPA 8260 0.47 1.0 --- --- ND --- ND 2 2.6 11.9 0.6 J ND ND 22-Oct-14 EPA 8260 0.47 1.0 --- ---* ND 0.61 J 1.3 2.2 11.4 0.86 J ND ND 21-May-15 EPA 8260 0.47 1.0 --- --- --- ND ND 0.9 J 2.3 10.1 ND ND ND 8-Dec-15 EPA 8260 0.47 1.0 --- --- --- ND ND 0.71 J 1.4 9.7 ND ND ND Trichlorofluoromethane 1-Oct-94 --- 5.0 --- NI NI NI --- 60 --- ---NI NI --- 1-Jan-95 --- 5.0 --- NI NI NI ND 37 ND ND NI NI ---1-Feb-95 --- 5.0 --- NI NI NI ND 40 ND ND NI NI ---1-Mar-95 --- 5.0 ND NI NI NI ND 48 ND ND NI NI ---1-Aug-95 --- 5.0 ND NI --- --- ND 51 ND 9 NI NI --- 1-Jan-96 --- 5.0 --- NI --- --- ND 20 5 11 NI NI --- 1-Feb-96 --- 5.0 --- NI --- --- ND 11 6.2 7.9 NI NI --- 1-May-96 --- 5.0 --- NI --- --- ND 8.8 ND 9.1 NI NI --- 1-Oct-96 --- 5.0 --- NI --- --- ND ND ND 9 NI NI --- 1-May-97 --- 5.0 4.2 J NI --- --- ND 2.1 J 3.4 J 11 NI NI --- 1-Nov-97 --- 1.0 4 NI --- --- ND ND ND 11 NI NI ---1-May-98 --- 5.0 ND NI --- --- ND ND ND 5 NI NI ---24-Nov-98 --- 2.0 ND NI --- --- ND ND ND 7.6 NI NI --- 10-May-99 --- 10.0 ND ND --- --- ND ND ND ND ND ND ND 18-Oct-99 --- 5.0 ND ND --- --- ND ND ND 12 ND ND ND 3-May-00 --- 5.0 ND ND --- --- ND ND ND 9.4 ND ND ND 7-Nov-00 --- 5.0 ND ND --- --- ND ND ND 10 ND ND ND 31-May-01 --- 5.0 ND ND --- --- ND ND ND 6.5 ND ND ND 7-Nov-01 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND22-May-02 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND14-Nov-02 --- 5.0 ND ND --- --- ND ND ND 6.5 ND ND ND 14-May-03 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND 20-Nov-03 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND 6-May-04 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND 10-Nov-04 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND 27-May-05 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND 3-Nov-05 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND25-May-06 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND2-Nov-06 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND30-May-07 --- 1.0 --- ND --- --- ND ND ND 4.2 ND ND ND NC 2L = 2,100 µg/L (10/23/07)29-Nov-07 --- 1.0 --- 0.74 J --- --- ND ND ND ND ND ND ND 29-May-08 0.2 1.0 --- 0.42 J --- --- ND ND ND ND ND ND ND 6-Nov-08 0.2 1.0 --- 0.71 J --- --- ND ND 0.24 J 1.1 ND ND ND 3-Jun-09 0.2 1.0 --- 0.38 J --- --- ND ND ND ND ND ND ND 18-Nov-09 0.2 1.0 --- 1.9 --- --- ND ND 1.6 2.1 ND ND ND NC 2L = 2,000 µg/L (01/01/10)16-Jun-10 0.2 1.0 --- ND --- --- ND ND ND ND ND ND ND1-Dec-10 0.2 1.0 --- 0.34 J ND --- ND ND ND 0.58 J ND ND ND1-Jun-11 0.2 1.0 --- 0.5 J ND --- ND ND ND 0.79 J ND ND ND 20-Dec-11 0.2 1.0 --- --- ND --- ND ND ND ND ND ND ND 30-May-12 0.2 1.0 --- --- ND --- ND ND ND ND ND ND ND 5-Dec-12 0.2 1.0 --- --- ND --- ND ND ND 0.65 J ND ND ND 12-Jun-13 0.2 1.0 --- --- ND --- ND ND ND ND ND ND ND 28-Oct-13 0.2 1.0 --- --- ND --- ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.2 1.0 --- --- ND --- ND ND ND 0.3 J ND ND ND22-Oct-14 EPA 8260 0.2 1.0 --- ---* ND ND ND ND ND ND ND ND21-May-15 EPA 8260 0.2 1.0 --- --- --- ND ND ND ND ND ND ND ND 8-Dec-15 EPA 8260 0.2 1.0 --- --- --- ND ND ND ND ND ND ND ND Burke County John's River C and D over MSW Landfill Permit 12-03 Page 11 of 14 Joyce Engineering TABLE 2: HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample EPA Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Background Downgradient Vinyl Chloride 30-May-07 0.62 1.0 --- ND --- --- ND 0.46 J 1.6 ND 3.1 ND ND NC 2L = 0.015 µg/L (10/23/07)29-Nov-07 0.62 1.0 --- 0.42 J --- --- ND ND 1.4 ND 1.9 ND ND29-May-08 0.62 1.0 --- ND --- --- ND ND 1.2 ND 2.2 ND ND6-Nov-08 0.62 1.0 --- 0.63 J --- --- ND 0.68 J 1.1 ND 1.8 ND ND 3-Jun-09 0.62 1.0 --- ND --- --- ND ND 0.95 J ND 2 ND ND 18-Nov-09 0.62 1.0 --- 0.69 J --- --- ND 0.66 J 1.6 ND 2.5 ND ND NC 2L = 0.03 µg/L (01/01/10)16-Jun-10 0.62 1.0 --- ND --- --- ND ND 1.1 ND 2.1 ND ND 1-Dec-10 0.62 1.0 --- ND ND --- ND 0.65 J 0.93 J ND 3.5 ND ND 1-Jun-11 0.62 1.0 --- ND ND --- ND 0.87 J 1.1 ND 1.8 ND ND 20-Dec-11 0.62 1.0 --- --- ND --- ND 0.63 J ND ND 1.4 ND ND30-May-12 0.62 1.0 --- --- ND --- ND ND ND ND 1.6 ND ND5-Dec-12 0.62 1.0 --- --- ND --- ND ND ND ND ND ND ND 12-Jun-13 0.62 1.0 --- --- ND --- ND ND 0.96 J ND 2.1 ND ND 28-Oct-13 0.62 1.0 --- --- ND --- ND ND 0.74 J ND 1.3 ND ND 6-May-14 EPA 8260 0.62 1.0 --- --- ND --- ND ND 0.77 J ND 1.8 ND ND 22-Oct-14 EPA 8260 0.62 1.0 --- ---* ND ND ND ND ND 1.3 ND ND 21-May-15 EPA 8260 0.62 1.0 --- --- --- ND ND ND ND ND 1.1 ND ND 8-Dec-15 EPA 8260 0.62 1.0 --- --- --- ND ND 0.72 J ND ND 1.4 ND ND Xylene (Total)1-Sep-94 --- 5.0 ND NI NI NI ND 12 ND ND NI NI --- 1-Oct-94 --- 5.0 --- NI NI NI --- 22 --- ---NI NI --- 1-Jan-95 --- 5.0 --- NI NI NI ND 7.6 ND ND NI NI --- 1-Feb-95 --- 5.0 --- NI NI NI ND 20 ND ND NI NI --- 1-Mar-95 --- 5.0 ND NI NI NI ND 24 ND ND NI NI --- 1-Aug-95 --- 5.0 ND NI NI NI ND 5 ND ND NI NI --- 1-Jan-96 --- 5.0 --- NI --- --- ND ND ND ND NI NI ---1-Feb-96 --- 5.0 --- NI --- --- ND ND ND ND NI NI ---1-May-96 --- 5.0 --- NI --- --- ND ND ND ND NI NI ---1-Oct-96 --- 5.0 --- NI --- --- ND 6 ND ND NI NI --- 1-May-97 --- 5.0 ND NI --- --- ND 9.2 4.3 J ND NI NI --- 1-Nov-97 --- 2.0 ND NI --- --- ND ND ND ND NI NI --- 1-May-98 --- 5.0 ND NI --- --- ND 5.6 ND ND NI NI --- 24-Nov-98 --- 2.0 ND NI --- --- ND 14.8 ND ND NI NI --- 10-May-99 --- 5.0 ND ND --- --- ND 13 ND ND ND ND ND 18-Oct-99 --- 5.0 ND ND --- --- ND 14 ND ND ND ND ND3-May-00 --- 5.0 ND ND --- --- ND 17.5 ND ND ND ND ND7-Nov-00 --- 5.0 ND ND --- --- ND 11 ND ND ND ND ND 31-May-01 --- 5.0 ND ND --- --- ND 10 9 10 ND ND ND 7-Nov-01 --- 5.0 ND ND --- --- ND 7.9 5.3 7.6 ND ND ND 22-May-02 --- 5.0 ND ND --- --- ND 5.3 8.5 14 ND ND ND 14-Nov-02 --- 5.0 ND ND --- --- ND ND 21.3 12 ND ND ND 14-May-03 --- 5.0 ND ND --- --- ND 5.4 6.6 48 ND ND ND 20-Nov-03 --- 5.0 ND ND --- --- ND ND 7.4 50 ND ND ND6-May-04 --- 5.0 ND ND --- --- ND ND 18.9 58 ND ND ND10-Nov-04 --- 5.0 ND ND --- --- ND ND ND 54 ND ND ND 27-May-05 --- 5.0 11 ND --- --- ND ND 7 58 ND ND ND 3-Nov-05 --- 5.0 --- ND --- --- ND ND 26 119 ND ND ND 25-May-06 --- 5.0 --- ND --- --- ND ND 17.4 38.7 ND ND ND 2-Nov-06 --- 10.0 --- ND --- --- ND ND ND 31 ND ND ND 30-May-07 --- 4.0 --- 1.1 J --- --- ND 2 J 24 34 1.2 J ND ND NC 2L = 530 µg/L (10/23/07)29-Nov-07 --- 5.0 --- 2.7 J --- --- ND ND 3.9 J 24 ND ND ND29-May-08 0.89 10.0 --- 1.7 J --- --- ND 0.92 J 6.2 J 29.6 ND ND ND6-Nov-08 0.66 2.0 --- 2.3 --- --- ND 0.78 J 2.8 28.7 ND ND ND 3-Jun-09 0.66 2.0 --- 1.6 J --- --- ND ND 4.7 46.5 ND ND ND 18-Nov-09 0.66 2.0 --- 5.7 --- --- ND ND 3.1 40.3 ND ND ND NC 2L = 500 µg/L (01/01/10)16-Jun-10 0.66 2.0 --- 1.8 J --- --- ND 1 J 5.2 40.3 ND ND ND 1-Dec-10 0.66 2.0 --- 2.3 ND --- ND ND 5.6 42.9 ND ND ND 1-Jun-11 0.66 2.0 --- 3.6 ND --- ND ND 0.88 J 44.1 ND ND ND 20-Dec-11 0.66 2.0 --- --- ND --- ND ND 0.94 J 26.8 D ND ND ND 30-May-12 0.66 2.0 --- --- ND --- ND ND 0.7 J 53.5 ND ND ND5-Dec-12 0.66 5.0 --- --- ND --- ND ND 2.4 J 43.6 ND ND ND12-Jun-13 0.66 5.0 --- --- ND --- ND ND ND 48.3 ND ND ND 28-Oct-13 0.66 5.0 --- --- ND --- ND ND ND 49.3 ND ND ND 6-May-14 EPA 8260 0.66 5.0 --- --- ND --- ND ND ND 40.7 ND ND ND 22-Oct-14 EPA 8260 0.66 5.0 --- --- * ND ND ND ND 46.6 ND ND ND 21-May-15 EPA 8260 0.66 5.0 --- --- --- ND ND ND ND 43.6 ND ND ND 8-Dec-15 EPA 8260 0.66 5.0 --- --- --- ND ND ND ND 45.4 ND ND ND Diethyl phthalate 29-Nov-07 --- 10.0 --- ND --- --- 1.7 J 2.3 J 2 J ND 1.3 J --- NDNC 2L = 5,000 µg/L (10/23/07) 6-Nov-08 2.5 10.0 --- ND --- --- ND ND ND ND ND ND ND 18-Nov-09 4 10.0 --- ND --- --- ND ND ND ND ND --- ND 1-Dec-10 2.7 10.0 --- ND ND --- ND ND ND ND ND --- ND 20-Dec-11 0.58 10.0 --- --- ND --- ND ND ND ND ND --- ND 5-Dec-12 0.58 6000 --- --- ND --- ND ND ND ND ND --- ND 28-Oct-13 0.58 6000 --- --- ND --- ND ND ND ND ND --- ND 22-Oct-14 0.91 6000 --- --- * ND ND ND ND ND ND --- ND8-Dec-15 1.3 6000 --- --- --- ND ND ND ND ND ND --- ND Naphthalene 29-Nov-07 --- 10.0 --- ND --- --- ND ND ND 1.3 JD ND --- ND NC 2L = 21 µg/L (10/23/07) 6-Nov-08 0.24 10.0 --- ND --- --- ND ND ND ND ND --- 0.67 J 18-Nov-09 0.24 10.0 --- ND --- --- ND ND ND 0.77 JD ND --- ND 1-Dec-10 4 10.0 --- ND ND --- ND ND ND 0.96 J ND --- ND 20-Dec-11 0.34 10.0 --- --- ND --- ND ND ND 0.84 JD ND --- ND 5-Dec-12 0.34 10.0 --- --- ND --- ND ND ND 1.5 B ND --- 0.46 J 28-Oct-13 0.24 10.0 --- --- ND --- ND ND ND 1.6 J ND --- ND22-Oct-14 EPA 8260 0.24 10.0 --- --- * ND ND ND ND 1.9 J ND --- ND8-Dec-15 EPA 8260 0.24 10.0 --- --- --- ND ND ND ND 2.2 J ND --- ND Pentachlorophenol 29-Nov-07 --- 25.0 --- ND --- --- ND ND ND 0.42 JD ND --- ND NC 2L = 0.29 µg/L (10/23/07) 6-Nov-08 1.7 25.0 --- ND --- --- ND ND ND ND ND --- ND 18-Nov-09 5 50.0 --- ND --- --- ND ND ND ND ND --- ND 1-Dec-10 18 25.0 --- ND ND --- ND ND ND ND ND --- ND 20-Dec-11 4.6 25.0 --- --- ND --- ND ND ND ND ND --- ND5-Dec-12 4.6 25.0 --- --- ND --- ND ND ND ND ND --- ND28-Oct-13 4.6 25.0 --- --- ND --- ND ND ND ND ND --- ND 22-Oct-14 EPA 8270 1.2 25.0 --- --- * ND ND ND ND ND ND --- ND 8-Dec-15 EPA 8270 2.3 25.0 --- --- --- ND ND ND ND ND ND --- ND Burke County John's River C and D over MSW Landfill Permit 12-03 Page 12 of 14 Joyce Engineering TABLE 2: HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample EPA Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Background Downgradient alpha-BHC 1-Oct-96 --- 0.050 --- NI --- --- ND 0.07 ND ND NI NI --- 1-May-97 --- 0.050 ND NI --- --- ND ND ND ND NI NI ---1-Nov-97 --- 0.100 ND NI --- --- ND ND ND ND NI NI ---1-May-98 --- 0.050 ND NI --- --- ND ND ND ND NI NI --- 24-Nov-98 --- 0.050 ND NI --- --- ND ND ND ND NI NI --- 10-May-99 --- 0.050 ND ND --- ---0.061 ND ND ND ND ND ND 18-Oct-99 --- 0.050 ND ND --- --- --- ND ND ND ND ND ND 3-May-00 --- 0.050 ND --- --- --- ND ND --- --------- ND 7-Nov-00 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND 7-Nov-01 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND14-Nov-02 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND20-Nov-03 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND 10-Nov-04 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND 3-Nov-05 --- 0.050 --- ND --- --- ND ND ND ND ND --- ND 2-Nov-06 --- 0.050 --- ND --- --- ND ND ND ND ND --- ND GWPS = 0.006 µg/L (10/23/07)29-Nov-07 --- 0.050 --- ND --- --- ND ND ND ND ND --- ND 6-Nov-08 0.05 0.050 --- ND --- --- ND ND ND ND ND --- ND 18-Nov-09 0.00031 0.010 --- ND --- --- ND ND ND ND ND --- ND1-Dec-10 0.0003 0.050 --- ND ND --- ND ND ND ND ND --- ND20-Dec-11 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND 5-Dec-12 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND 28-Oct-13 0.05 0.050 --- --- ND --- ND ND ND 0.19 ND --- ND Resample >10-Dec-13 0.05 0.050 --- --- --- --- --- --- ---0.085 ------ ND 6-May-14 EPA 8081 0.05 0.050 --- --- ND --- ND ND ND 0.07 ND ------ 22-Oct-14 EPA 8081 0.05 0.050 --- ---* ND ND ND ND ND ND --- ND 21-May-15 EPA 8081 0.05 0.050 --- --- --- ND ND ND ND 0.12 ND --- ND8-Dec-15 EPA 8081 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ND beta-BHC 1-Dec-10 0.0005 0.050 --- ND ND --- ND ND 0.019 J ND ND --- ND Resample >13-Jan-11 0.0005 0.050 --- --- --- --- --- --- ND --------- ND GWPS = 0.019 µg/L (10/23/07)20-Dec-11 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND 5-Dec-12 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND 28-Oct-13 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND 22-Oct-14 EPA 8081 0.05 0.050 --- ---* ND ND ND ND ND ND --- ND 8-Dec-15 EPA 8081 0.05 0.050 --- --- --- ND ND 0.16 ND ND ND --- NDResample >4-Feb-16 EPA 8081 0.05 0.050 --- --- --- --- ---0.33 --- --------- ND Delta-BHC 18-Oct-99 --- 0.050 ND ND --- --- --- 0.06 J ND ND ND ND ND 3-May-00 --- 0.050 ND --- --- --- ND ND --- --------- ND 7-Nov-00 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND 7-Nov-01 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND 14-Nov-02 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND 20-Nov-03 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND10-Nov-04 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND3-Nov-05 --- 0.050 --- ND --- --- ND ND ND ND ND --- ND 2-Nov-06 --- 0.050 --- ND --- --- ND ND ND ND ND --- ND GWPS = 0.019 µg/L (10/23/07)29-Nov-07 --- 0.050 --- ND --- --- ND ND ND ND ND --- ND 6-Nov-08 0.05 0.050 --- ND --- --- ND ND ND ND ND --- ND 18-Nov-09 0.00041 0.010 --- ND --- --- ND ND ND ND ND --- ND 1-Dec-10 0.0004 0.050 --- ND ND --- ND ND ND ND ND --- ND 20-Dec-11 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND5-Dec-12 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND28-Oct-13 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND 22-Oct-14 EPA 8081 0.05 0.050 --- ---* ND ND ND ND ND ND --- ND 8-Dec-15 EPA 8081 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ND Gamma-BHC 18-Oct-99 --- 0.050 ND ND --- --- --- 0.08 J ND ND ND ND ND (Lindane)3-May-00 --- 0.050 ND --- --- --- ND ND --- --------- ND 7-Nov-00 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND 7-Nov-01 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND14-Nov-02 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND20-Nov-03 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND 10-Nov-04 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND 3-Nov-05 --- 0.050 --- ND --- --- ND ND ND ND ND --- ND 2-Nov-06 --- 0.050 --- ND --- --- ND ND ND ND ND --- ND NC 2L = 0.2 µg/L (10/23/07)29-Nov-07 --- 0.050 --- ND --- --- ND ND ND ND ND --- ND 6-Nov-08 0.05 0.050 --- ND --- --- ND ND ND ND ND --- ND 18-Nov-09 0.00021 0.010 --- 0.032 --- --- ND ND ND ND ND --- NDResample >19-Jan-10 0.00021 0.010 --- ND --- --- --- --- --- --------- ND1-Dec-10 0.0002 0.050 --- ND ND --- ND ND 0.034 J ND ND --- ND Resample >13-Jan-11 0.0002 0.050 --- --- --- --- --- --- 0.048 J --------- ND 20-Dec-11 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND 5-Dec-12 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND 28-Oct-13 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND 22-Oct-14 0.05 0.050 --- ---* ND ND ND ND ND ND --- ND 8-Dec-15 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ND Heptachlor 18-Oct-99 --- 0.050 ND ND --- --- --- 0.11 J ND ND ND ND ND 3-May-00 --- 0.050 ND --- --- --- ND ND --- --------- ND 7-Nov-01 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND 14-Nov-02 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND 20-Nov-03 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND 10-Nov-04 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND 3-Nov-05 --- 0.050 --- ND --- --- ND ND ND ND ND --- ND 2-Nov-06 --- 0.050 --- ND --- --- ND ND ND ND ND --- NDNC 2L = 0.0078 µg/L (10/23/07)29-Nov-07 --- 0.050 --- ND --- --- ND ND ND ND ND --- ND6-Nov-08 0.05 0.050 --- ND --- --- ND ND ND ND ND --- ND 18-Nov-09 0.0015 0.010 --- ND --- --- ND ND ND ND ND --- ND 1-Dec-10 0.0015 0.050 --- ND ND --- ND ND ND ND ND --- ND 20-Dec-11 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND 5-Dec-12 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND 28-Oct-13 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND 22-Oct-14 EPA 8081 0.05 0.050 --- ---* ND ND ND ND ND ND --- ND8-Dec-15 EPA 8081 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ND N-Nitroso-di-n-butylamine 22-Oct-14 EPA 8270 1.3 10.0 --- --- --- --- 4.0 J ND ND 11.2 ND --- ND Resample >22-Dec-14 1.3 10.0 --- --- --- --- --- --- --- ND --------- NC 2L = NE (01/01/10)8-Dec-15 EPA 8270 2.2 10.0 --- --- --- ND ND ND ND ND ND --- ND Burke County John's River C and D over MSW Landfill Permit 12-03 Page 13 of 14 Joyce Engineering TABLE 2: HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS Sample EPA Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks Background Downgradient PCB-1232 18-Oct-99 --- 2.0 4.7 ND --- ------ ND ND ND ND ND ND 3-May-00 --- 2.0 ND --- --- --- ND ND --- --------- ND 7-Nov-00 --- 2.0 ND --- --- --- ND ND ND ND ND --- ND 7-Nov-00 --- 2.0 ND --- --- --- ND ND ND ND ND --- ND 31-May-01 --- 2.0 ND --- --- --- --- --- --- --------- ND 7-Nov-01 --- 2.0 ND --- --- --- ND ND ND ND ND --- ND 14-Nov-02 --- 2.0 ND --- --- --- ND ND ND ND ND --- ND20-Nov-03 --- 2.0 ND --- --- --- ND ND ND ND ND --- ND10-Nov-04 --- 1.0 ND --- --- --- ND ND ND ND ND --- ND 6-May-05 --- 1.0 --- --- --- --- --- --- --- ------------ 3-Nov-05 --- 1.0 --- ND --- --- ND ND ND ND ND --- ND 2-Nov-06 --- 1.0 --- ND --- --- ND ND ND ND ND --- ND GWPS = 0.5 µg/L (10/23/07)29-Nov-07 --- 2.0 --- ND --- --- ND ND ND ND ND --- ND 6-Nov-08 1 NE --- ND --- --- ND ND ND ND ND --- ND 18-Nov-09 0.12 0.5 --- ND --- --- ND ND ND ND ND --- NDGWPS = 0.09 µg/L (10/01/10)1-Dec-10 0.5 0.5 --- ND ND --- ND ND ND ND ND --- ND20-Dec-11 0.5 0.5 --- --- ND --- ND ND ND ND ND --- ND 5-Dec-12 0.5 0.5 --- --- ND --- ND ND ND ND ND --- ND 28-Oct-13 0.5 0.5 --- --- ND --- ND ND ND ND ND --- ND 22-Oct-14 0.5 0.5 --- ---* ND ND ND ND ND ND --- ND 8-Dec-15 0.5 0.5 --- --- --- ND ND ND ND ND ND --- ND 2,4-D 1-Aug-95 --- 0.3 ND NI --- --- ND 0.478 ND ND NI NI ---1-Jan-96 --- 2.0 --- NI --- --- ND ND ND ND NI NI ---1-Feb-96 --- 2.0 --- NI --- --- ND ND ND ND NI NI ---1-May-96 --- 2.0 --- NI --- --- ND ND ND ND NI NI --- 1-Oct-96 --- 0.5 --- NI --- --- ND ND ND ND NI NI --- 1-Nov-97 --- 0.4 ND NI --- --- ND ND ND ND NI NI --- 24-Nov-98 --- 2.0 ND NI --- --- ND ND ND ND NI NI --- 18-Oct-99 --- 2.0 ND ND --- --- --- ND ND ND ND ND ND 7-Nov-01 --- 2.0 ND --- --- --- ND ND ND ND ND --- ND 14-Nov-02 --- 2.0 ND --- --- --- ND ND ND ND ND --- ND20-Nov-03 --- 2.0 ND --- --- --- ND ND ND ND ND --- ND10-Nov-04 --- 2.0 ND --- --- --- ND ND ND ND ND --- ND 3-Nov-05 --- 2.0 --- ND --- --- ND ND ND ND ND --- ND 2-Nov-06 --- 2.0 --- ND --- --- ND ND ND ND ND --- ND NC 2L = 70 µg/L (10/23/07)29-Nov-07 --- 2.0 --- ND --- --- ND 1.4 J ND ND ND --- ND 6-Nov-08 1 2.0 --- ND --- --- ND ND ND ND ND --- ND 18-Nov-09 0.22 2.0 --- ND --- --- ND ND ND ND ND --- ND Resample >19-Jan-10 0.23 1.0 --- ND --- --- --- --- --- ND ------ ND1-Dec-10 0.22 2.0 --- ND ND --- ND ND ND ND ND --- ND20-Dec-11 0.22 2.0 --- --- ND --- ND ND ND ND ND --- ND 5-Dec-12 0.22 2.0 --- --- ND --- ND ND ND ND ND --- ND 28-Oct-13 0.22 2.0 --- --- ND --- ND ND ND ND ND --- ND 22-Oct-14 EPA 8151 0.23 0.96 --- ---* ND ND ND ND ND ND ------ 8-Dec-15 EPA 8151 0.22 2.00 --- --- --- ND ND ND ND ND ND --- ND 4,4'-DDD 1-Dec-10 0.0019 0.10 --- ND ND --- ND 0.019 J ND ND ND --- NDResample >13-Jan-11 0.0019 0.10 --- --- --- --- --- ND --- --------- NDNC 2L = 0.1 µg/L (01/01/10)20-Dec-11 0.05 0.05 --- --- ND --- ND ND ND ND ND --- ND 5-Dec-12 0.05 0.10 --- --- ND --- ND ND ND ND ND --- ND 28-Oct-13 0.05 0.10 --- --- ND --- ND ND ND ND ND --- ND 22-Oct-14 EPA 8081 0.05 0.10 --- ---* ND ND ND ND ND ND ------ 8-Dec-15 EPA 8081 0.05 0.10 --- --- --- ND ND ND ND ND ND --- ND 4,4'-DDE 1-Dec-10 0.0009 0.10 --- ND ND --- ND ND ND 0.019 J ND --- ND Resample >13-Jan-11 0.0009 0.10 --- --- --- --- --- --- --- 0.027 J ------ NDNC 2L = NE (01/01/10)20-Dec-11 0.05 0.05 --- --- ND --- ND ND ND ND ND --- ND5-Dec-12 0.05 0.10 --- --- ND --- ND ND ND ND ND --- ND 28-Oct-13 0.05 0.10 --- --- ND --- ND ND ND ND ND --- ND 22-Oct-14 EPA 8081 0.05 0.10 --- ---* ND ND ND ND ND ND ------ 8-Dec-15 EPA 8081 0.05 0.10 --- --- --- ND ND ND ND ND ND --- ND Notes: (Abbreviations and Referrences) All concentrations in micrograms per liter (µg/L) = parts per billion. # = Constituent is included on the NC Appendix II list but not on the NC Appendix I list.--- = Not sampled for this parameter or Not reportedAB = Monitoring well abandoned. B = Blank-Qualified (Concentration suspected to reflect laboratory or field contamination based on similar concentrations detected in field, trip, or method blanks). D = Sample was diluted when analyzed. DL = Laboratory Detection Limit. GWPS = Groundwater Protection Standard set by NC-DENR-SWS for constituents with no listed NC 2L standard. When the NC 2L Groundwater Standard has not been established, the GWPS will be used. J = Estimated value - concentration is less than the RL but greater than the DL. NC 2L = Groundwater Standard from 15A NCAC 2L.0202.ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006).NE = No NC 2L or GWPS established. NI = Not Installed. Monitoring well not yet installed. RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present). Values above the NC2L Standard or GWPS are bold. Notes: (Event Narratives) Volatile organics (8260) for MW-9 for November 10, 2004 sampling event were unable to be analyzed and were resampled on December 1, 2004. There was a resamplinging event on August 2, 2007 for MW-16D because the prevoius samples from the May 2007 were analyzed out of hold time. There were no detects in the resample.* MW-21 replaced MW-20 as the background well starting with the Fall 2014 sampling event; however MW-20 continues to be sampled as a compliance well for the C&D Expansion (Phase 1A). See the Water Quality Monitrong Report for the C&D Expansion Area for current results for MW-20. Sample Collection Date Column displays the last day of the Respective Semiannaul Monitoring Event that samples were collected. Each individual sampling point date is preserved in the Lab Reports (Appendix A). Burke County John's River C and D over MSW Landfill Permit 12-03 Page 14 of 14 Joyce Engineering TABLE 3: HISTORICAL DETECTED CONSTITUENTS IN PERFORMANCE AND SENTINEL WELLS Sample Analyte Collection Date DL RL MW-18 MW-19 MW-36 MW-38 Blanks Organic Compounds Benzene 18-Feb-13 0.25 1.0 --- ---8.0 3.8 ND 18-Jul-13 0.25 1.0 --- --- --- --- ND 28-Oct-13 0.25 1.0 ND ND --- --- ND NC 2L = 1 µg/L (10/23/07) 6-May-14 0.25 1.0 ND ND 8.7 6.5 ND 22-Oct-14 0.25 1.0 ND ND 8.3 5.9 ND 21-May-15 0.25 1.0 ND ND 5.8 4.9 ND 18-Jul-13 0.33 1.0 --- --- --- --- ND 28-Oct-13 0.33 1.0 ND ND --- --- ND NC 2L = 6 µg/L (01/01/10) 6-May-14 0.33 1.0 ND ND 10.0 13.5 ND 22-Oct-14 0.33 1.0 ND ND 15.2 12.9 ND 21-May-15 0.33 1.0 ND ND 18.7 12.3 ND 8-Dec-15 0.33 1.0 --- --- 5.8 4.4 ND 1,1-Dichloroethane 3-Jun-09 0.3 5.0 3.9 J 2.8 J --- ---ND 18-Nov-09 0.3 5.0 6.7 3.7 J --- ---ND 16-Jun-10 0.3 5.0 4.4 J 2.3 J --- ---ND 1-Dec-10 0.3 5.0 --- ------ ---ND 1-Jun-11 0.3 5.0 2.8 J 2.6 J --- ---ND 20-Dec-11 0.3 5.0 --- ------ ---ND 30-May-12 0.3 5.0 1.6 J 2.7 J --- ---ND 5-Dec-12 0.3 5.0 --- ------ ---ND 18-Feb-13 0.32 5.0 --- ---7.9 9.1 ND 12-Jun-13 0.3 5.0 --- ------ ---ND 18-Jul-13 0.32 5.0 --- --- --- --- ND 28-Oct-13 0.3 5.0 0.93 J 3.0 J ------ND NC 2L = 6 µg/L (01/01/10)6-May-14 0.32 5.0 1.2 J 2.9 J 11.6 8.1 ND 22-Oct-14 0.32 5.0 ------9.0 6.9 ND 21-May-15 0.32 5.0 ND 1.7 J 4.8 J 5.5 ND 8-Dec-15 0.32 5.0 --- --- 5.9 7.2 ND 1,2-Dichloroethane 3-Jun-09 0.1 1.0 0.33 J ND ------ND 18-Nov-09 0.1 1.0 0.56 J ND ------ND 16-Jun-10 0.1 1.0 0.37 J ND ------ND 1-Dec-10 0.1 1.0 ------------ND 1-Jun-11 0.1 1.0 0.34 J ND ------ND 20-Dec-11 0.1 1.0 ------------ND 30-May-12 0.1 1.0 ND ND ------ND 5-Dec-12 0.1 1.0 ------------ND 18-Feb-13 0.12 1.0 ------1.0 0.59 J ND 12-Jun-13 0.1 1.0 ------------ND 18-Jul-13 0.12 1.0 ------------ND 28-Oct-13 0.1 1.0 ND ND ------ND NC 2L = 0.4 µg/L (01/01/10)6-May-14 0.12 1.0 ND ND 0.78 J ND ND 22-Oct-14 0.12 1.0 ------0.92 J 0.63 J ND 21-May-15 0.12 1.0 ND ND ND ND ND 8-Dec-15 0.12 1.0 ------0.66 J 0.70 J ND Methylene Chloride 18-Feb-13 0.97 1.0 ------17.9 ND ND 18-Jul-13 0.97 1.0 ------------ND 28-Oct-13 0.97 1.0 ND ND ------ND NC 2L = 5 µg/L (01/01/10)6-May-14 0.97 1.0 ------24.1 1.7 B 2.20 22-Oct-14 0.97 1.0 ------15.7 ND ND 21-May-15 0.97 1.0 ND ND 9.5 B ND 1.7 8-Dec-15 0.97 1.0 ------11.2 B ND 2.0 Sentinel Performance Burke County - John's River C+D-over-MSW Landfill Permit 12-03 Page 1 of 2 Joyce Engineering TABLE 3: HISTORICAL DETECTED CONSTITUENTS IN PERFORMANCE AND SENTINEL WELLS Tetrachloroethene 18-Feb-13 0.46 1.0 --- ---5.5 ND ND 18-Jul-13 0.46 1.0 --- --- --- --- ND 28-Oct-13 0.46 1.0 ND ND --- --- ND NC 2L = 0.7 µg/L (10/23/07) 6-May-14 0.46 1.0 --- ---7.9 ND ND 22-Oct-14 0.46 1.0 --- ---7.3 ND ND 21-May-15 0.46 1.0 ND ND 6.0 ND ND 8-Dec-15 0.46 1.0 --- ---5.0 ND ND Trichloroethene 18-Feb-13 0.47 1.0 --- ---3.6 2.7 ND 18-Jul-13 0.47 1.0 --- --- --- --- ND 28-Oct-13 0.47 1.0 ND ND --- --- ND NC 2L = 3 µg/L (01/01/10) 6-May-14 0.47 1.0 --- ---6.0 2.1 ND 22-Oct-14 0.47 1.0 --- ---5.1 1.8 ND 21-May-15 0.47 1.0 ND ND 3.5 0.92 J ND 8-Dec-15 0.47 1.0 --- --- 2.9 2.1 ND Vinyl chloride 18-Feb-13 0.62 1.0 --- ---1.2 ND ND 18-Jul-13 0.62 1.0 --- --- --- --- ND 28-Oct-13 0.62 1.0 ND ND --- --- ND NC 2L = 0.03 µg/L (01/01/10) 6-May-14 0.62 1.0 --- ---1.1 ND ND 22-Oct-14 0.62 1.0 --- --- 0.87 J ND ND 21-May-15 0.62 1.0 ND ND ND ND ND 8-Dec-15 0.62 1.0 --- --- 0.80 J ND ND Notes: All concentrations in micrograms per liter (µg/L) = parts per billion. DL = Laboratory Detection Limit. RL = SWSL = Solid Waste Section Reporting Limit. NC 2L = Groundwater Standard from 15A NCAC 2L.0202. GWPS = Groundwater Protection Standard set by NC-DENR-SWS for constituents with no listed NC 2L. nle = No longer exists (MW-34 was accidentaly destroyed during construciton activties). --- = Not reported or not monitored. Italics = Constituent of Concern (COC). For MW-36 and MW-38, only COC's are reported in this Appendix. Additional constituents required for the Phase 1A area are included in the Semiannual Groundwater Monitoring Report for Phase 1A. Burke County - John's River C+D-over-MSW Landfill Permit 12-03 Page 2 of 2 Joyce Engineering TABLE 4: HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER Sample Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks Inorganic Compounds Antimony 6-Nov-08 2.6 6.0 ND 8.4 ---ND 3-Jun-09 2.6 6.0 ND ND --- ND 18-Nov-09 2.6 6.0 ND ND --- ND NC 2B = NE (05/01/07) 15-Jun-10 2.6 6.0 ND ND --- ND 1-Dec-10 2.6 6.0 ND ND --- ND 1-Jun-11 2.6 6.0 ND ND --- ND 20-Dec-11 5.0 6.0 ND ND --- ND 30-May-12 5.0 6.0 ND ND --- ND 5-Dec-12 5.0 6.0 ND ND --- ND 12-Jun-13 5.0 6.0 ND ND --- ND 28-Oct-13 5.0 6.0 ND ND --- ND 6-May-14 5.0 6.0 ND ND --- ND 22-Oct-14 5.0 6.0 --- ND ND ND 21-May-15 3.8 6.0 ND ND ND ND 9-Dec-15 3.8 6.0 ND ND ND ND Arsenic 6-Nov-08 2.7 10.0 2.9 B 4.5 B ---4.1 J 3-Jun-09 2.7 10.0 ND 4.5 J --- ND 18-Nov-09 2.7 10.0 ND ND --- ND NC 2B = 10 µg/L (05/01/07) 15-Jun-10 2.7 10.0 ND ND --- ND 1-Dec-10 2.7 10.0 ND ND --- ND 1-Jun-11 2.7 10.0 ND ND --- ND 20-Dec-11 5.0 10.0 ND ND --- ND 30-May-12 5.0 10.0 ND ND --- ND 5-Dec-12 5.0 10.0 ND ND --- ND 12-Jun-13 5.0 10.0 ND ND --- ND 28-Oct-13 5.0 10.0 ND ND --- ND 6-May-14 5.0 10.0 ND ND --- ND 22-Oct-14 5.0 10.0 --- ND ND ND 21-May-15 2.5 10.0 ND ND ND ND 9-Dec-15 2.5 10.0 ND ND ND ND Barium 30-May-07 --- 100 81.3 J 23.8 J ---0.2 J 29-Nov-07 --- 100 116 27.5 J --- 0.50 J 29-May-08 0.2 100 71.9 J 19.6 J --- ND 6-Nov-08 0.20 100 82.5 J 40.2 B --- 9.6 J 3-Jun-09 0.20 100 104 36.2 B --- 15.9 J 18-Nov-09 0.20 100 49.9 B 15.7 B --- 20.1 J NC 2B = 1,000 µg/L (05/01/07) 15-Jun-10 0.20 100 47.6 J 20.7 J --- 0.77 J 1-Dec-10 0.20 100 39.8 J 46.8 J --- ND 1-Jun-11 0.20 100 51.6 J 19.9 J --- ND 20-Dec-11 5.0 100 63.7 J 13.9 J --- ND 30-May-12 5.0 100 16.9 J 22.0 J --- ND 5-Dec-12 5.0 100 69.9 J 24.8 J --- ND 12-Jun-13 5.0 100 54.9 B 40.0 B ---13.6 J 28-Oct-13 5.0 100 35.4 J 20.8 J --- ND 6-May-14 5.0 100 37.0 J 17.8 J --- ND 22-Oct-14 5.0 100 --- 25.5 J 19.8 J ND 21-May-15 2.5 100 53.0 J 14.6 J 21.6 J ND 9-Dec-15 2.5 100 26.1 J 23.4 J 27.8 J ND Burke County John's River Landfill - Phase 1A Permit 12-03 Page 1 of 9 Joyce Engineering TABLE 4: HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER Sample Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks Beryllium 14-Nov-02 --- 2 2.0 B 2.2 B ---2.1 14-May-03 --- 2 ND ND ---ND 20-Nov-03 --- 2 ND ND ---ND 6-May-04 --- 2 ND ND ---ND 10-Nov-04 --- 2 ND ND ---ND 5-May-05 --- 2 ND ND ---ND 3-Nov-05 --- 2 ND ND ---ND 25-May-06 --- 2 ND ND ---ND 2-Nov-06 --- 2 ND ND ---ND 30-May-07 --- 1 ND ND ---ND 29-Nov-07 --- 1 ND ND ---ND 29-May-08 0.10 1.0 ND ND ---ND 6-Nov-08 0.10 1.0 0.24 B 0.37 B ---0.29 J 3-Jun-09 0.10 1.0 0.64 J 0.21 J ---ND 18-Nov-09 0.10 1.0 ND ND ---ND NC 2B = 6.5 µg/L (05/01/07)15-Jun-10 0.10 1.0 ND ND ---ND 1-Dec-10 0.10 1.0 ND ND ---ND 1-Jun-11 0.10 1.0 ND ND ---ND 20-Dec-11 1.0 1.0 ND ND ---ND 30-May-12 1.0 1.0 ND ND ---ND 5-Dec-12 1.0 1.0 ND ND ---ND 12-Jun-13 1.0 1.0 ND ND ---ND 28-Oct-13 1.0 1.0 ND ND ---ND 6-May-14 1.0 1.0 ND ND ---ND 22-Oct-14 1.0 1.0 --- ND ND ND 21-May-15 0.5 1.0 ND ND ND ND 9-Dec-15 0.5 1.0 ND ND ND ND Burke County John's River Landfill - Phase 1A Permit 12-03 Page 2 of 9 Joyce Engineering TABLE 4: HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER Sample Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks Cadmium 7-Nov-01 --- 1 ND 1.0 ---ND 22-May-02 --- 1 ND 1.7 B ---1.3 14-Nov-02 --- 1 ND ND ---ND 14-May-03 --- 1 ND ND ---ND 20-Nov-03 --- 1 ND ND ---ND 6-May-04 --- 1 ND ND ---ND 10-Nov-04 --- 1 ND ND ---ND 5-May-05 --- 1 ND ND ---ND 3-Nov-05 --- 1 ND ND ---ND 25-May-06 --- 1 ND ND ---ND 2-Nov-06 --- 1 ND ND ---ND 30-May-07 --- 1 ND ND ---ND 29-Nov-07 --- 1 ND ND ---ND 29-May-08 0.5 1.0 ND ND ---ND 6-Nov-08 0.50 1.0 ND ND ---ND 3-Jun-09 0.50 1.0 ND ND ---ND 18-Nov-09 0.50 1.0 ND ND ---ND NC 2B = 2 µg/L (05/01/07)15-Jun-10 0.50 1.0 ND ND ---ND 1-Dec-10 0.50 1.0 ND ND ---ND 1-Jun-11 0.50 1.0 ND ND ---ND 20-Dec-11 1.0 1.0 ND ND ---ND 30-May-12 1.0 1.0 ND ND ---ND 5-Dec-12 1.0 1.0 ND ND ---ND 12-Jun-13 1.0 1.0 ND ND ---ND 28-Oct-13 1.0 1.0 ND ND ---ND 6-May-14 1.0 1.0 ND ND ---ND 22-Oct-14 1.0 1.0 --- ND ND ND 21-May-15 0.5 1.0 ND ND ND ND 9-Dec-15 0.5 1.0 ND ND ND ND Chromium 6-Nov-08 0.40 10.0 ND 0.47 J ---ND 3-Jun-09 0.40 10.0 7.5 J 3.2 J ---ND 18-Nov-09 0.40 10.0 ND ND ---ND NC 2B = 50 µg/L (05/01/07)15-Jun-10 0.40 10.0 1.2 B 0.48 B --- 0.74 J 1-Dec-10 0.40 10.0 0.68 B 5.1 J --- 0.51 J 1-Jun-11 0.40 10.0 0.59 B 0.59 B --- 0.73 J 20-Dec-11 5.0 10.0 ND ND ---ND 30-May-12 5.0 10.0 ND ND ---ND 5-Dec-12 5.0 10.0 ND ND ---ND 12-Jun-13 5.0 10.0 ND ND ---ND 28-Oct-13 5.0 10.0 ND ND ---ND 6-May-14 5.0 10.0 ND ND ---ND 22-Oct-14 5.0 10.0 --- ND 9.7 J ND 21-May-15 2.5 10.0 ND ND ND ND 9-Dec-15 2.5 10.0 ND ND ND ND Burke County John's River Landfill - Phase 1A Permit 12-03 Page 3 of 9 Joyce Engineering TABLE 4: HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER Sample Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks Cobalt 22-May-02 --- 10 14.0 17.0 --- 11.0 14-Nov-02 --- 10 ND ND ---ND 14-May-03 --- 10 ND 10.0 ---ND 20-Nov-03 --- 10 14.0 ND ---ND 6-May-04 --- 10 ND ND ---ND 10-Nov-04 --- 10 10.0 ND ---ND 5-May-05 --- 10 10.0 ND ---ND 3-Nov-05 --- 10 16.0 ND ---ND 25-May-06 --- 10 12 ND ---ND 2-Nov-06 --- 10 13.6 ND ---ND 30-May-07 --- 10 12.3 8.8 J ---ND 29-Nov-07 --- 10 19.0 2.1 J ---ND 29-May-08 0.60 10.0 13.7 ND ---ND 6-Nov-08 0.60 10.0 12.6 ND --- 0.65 J 3-Jun-09 0.60 10.0 11.9 B 6.6 B ---7.6 J 18-Nov-09 0.60 10.0 3.6 J 4.6 J ---ND NC 2B = NE (05/01/07)15-Jun-10 0.60 10.0 6.4 J 22.3 ---ND 1-Dec-10 0.60 10.0 0.76 J 4.1 J ---ND 1-Jun-11 0.60 10.0 2.0 J 1.7 J ---ND 20-Dec-11 5.0 10.0 ND ND ---ND 30-May-12 5.0 10.0 ND ND ---ND 5-Dec-12 5.0 10.0 29.0 7.7 J ---ND 12-Jun-13 5.0 10.0 ND 9.1 J ---ND 28-Oct-13 5.0 10.0 11.5 12.4 ---ND 6-May-14 5.0 10.0 ND ND ---ND 22-Oct-14 5.0 10.0 --- ND ND ND 21-May-15 2.5 10.0 6.3 J ND ND ND 9-Dec-15 2.5 10.0 ND ND ND ND Copper 29-May-08 0.30 10.0 ND 1.3 B --- 0.37 J 6-Nov-08 4.0 10.0 0.45 B 3.4 J --- 0.65 J 3-Jun-09 0.30 10.0 6.6 J 2.1 J ---ND 18-Nov-09 0.30 10.0 ND ND ---ND NC 2B = 7 µg/L (05/01/07)15-Jun-10 0.30 10.0 0.56 B ND --- 0.77 J 1-Dec-10 0.30 10.0 3.6 J 5.9 J ---ND 1-Jun-11 0.30 10.0 1.8 J 0.35 J ---ND 20-Dec-11 5.0 10.0 ND ND ---ND 30-May-12 5.0 10.0 ND ND ---ND 5-Dec-12 5.0 10.0 ND ND ---ND 12-Jun-13 5.0 10.0 5.2 B ND ---9.8 J 28-Oct-13 5.0 10.0 ND ND ---ND 6-May-14 5.0 10.0 ND ND ---ND 22-Oct-14 5.0 10.0 --- ND ND ND 21-May-15 2.5 10.0 ND ND ND ND 9-Dec-15 2.5 10.0 ND ND ND ND Burke County John's River Landfill - Phase 1A Permit 12-03 Page 4 of 9 Joyce Engineering TABLE 4: HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER Sample Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks Lead 3-Jun-09 4.0 10.0 7.3 J ND ---ND 18-Nov-09 4.0 10.0 ND ND ---ND NC 2B = 25 µg/L (05/01/07)15-Jun-10 4.0 10.0 ND ND ---ND 1-Dec-10 4.0 10.0 ND 4.6 J ---ND 1-Jun-11 4.0 10.0 ND ND ---ND 20-Dec-11 5.0 10.0 ND ND ---ND 30-May-12 5.0 10.0 ND ND ---ND 5-Dec-12 5.0 10.0 ND ND ---ND 12-Jun-13 5.0 10.0 ND ND ---ND 28-Oct-13 5.0 10.0 ND ND ---ND 6-May-14 5.0 10.0 ND ND ---ND 22-Oct-14 5.0 10.0 --- ND ND ND 21-May-15 2.5 10.0 ND ND ND ND 9-Dec-15 2.5 10.0 ND ND ND ND Nickel 3-Jun-09 1.7 50.0 5.5 B ND ---1.7 J 18-Nov-09 1.7 50.0 ND ND ---ND NC 2B = 25 µg/L (05/01/07)15-Jun-10 1.7 50.0 ND ND ---ND 1-Dec-10 1.7 50.0 2.8 J 2.8 J ---ND 1-Jun-11 1.7 50.0 ND ND ---2.3 J 20-Dec-11 5.0 50.0 ND ND ---ND 30-May-12 5.0 50.0 ND ND ---ND 5-Dec-12 5.0 50.0 ND ND ---ND 12-Jun-13 5.0 50.0 ND ND ---ND 28-Oct-13 5.0 50.0 ND ND ---ND 6-May-14 5.0 50.0 ND ND ---ND 22-Oct-14 5.0 50.0 --- ND ND ND 21-May-15 2.5 50.0 ND ND ND ND 9-Dec-15 2.5 50.0 ND ND ND ND Selenium 6-Nov-08 3.8 10 ND 10.9 ---ND 3-Jun-09 3.8 10.0 ND ND ---ND 18-Nov-09 3.8 10.0 ND ND ---ND NC 2B = 5 µg/L (05/01/07)15-Jun-10 3.8 10.0 ND ND ---ND 1-Dec-10 3.8 10.0 ND ND ---ND 1-Jun-11 3.8 10.0 ND ND ---ND 20-Dec-11 10.0 10.0 ND ND ---ND 30-May-12 10.0 10.0 ND ND ---ND 5-Dec-12 10.0 10.0 ND ND ---ND 12-Jun-13 10.0 10.0 ND ND ---ND 28-Oct-13 10.0 10.0 ND ND ---ND 6-May-14 10.0 10.0 ND ND ---ND 22-Oct-14 10.0 10.0 --- ND ND ND 21-May-15 5.0 10.0 ND ND ND ND 9-Dec-15 5.0 10.0 ND ND ND ND Burke County John's River Landfill - Phase 1A Permit 12-03 Page 5 of 9 Joyce Engineering TABLE 4: HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER Sample Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks Silver 22-May-02 --- 10 16.0 B 15.0 B --- 15.0 14-Nov-02 --- 10 ND ND ---ND 14-May-03 --- 10 ND ND ---ND 20-Nov-03 --- 10 ND ND ---ND 6-May-04 --- 10 ND ND ---ND 10-Nov-04 --- 10 ND ND ---ND 5-May-05 --- 10 ND ND ---ND 3-Nov-05 --- 10 ND ND ---ND 25-May-06 --- 10 ND ND ---ND 2-Nov-06 --- 10 ND ND ---ND 30-May-07 --- 10 ND ND ---ND 29-Nov-07 --- 10 ND ND ---ND 29-May-08 0.10 10.0 0.29 J 0.13 J ---ND 6-Nov-08 0.10 10.0 0.72 B 0.38 B --- 0.23 J 3-Jun-09 0.10 10.0 0.18 B ND --- 0.31 J 18-Nov-09 0.10 10.0 0.27 B 0.23 B --- 0.23 J NC 2B = 0.06 µg/L (05/01/07)15-Jun-10 0.10 10.0 ND ND ---ND 1-Dec-10 0.10 10.0 ND ND ---ND 1-Jun-11 0.10 10.0 ND 0.22 J ---ND 20-Dec-11 5.0 10.0 ND ND ---ND 30-May-12 5.0 10.0 ND ND ---ND 5-Dec-12 5.0 10.0 ND ND ---ND 12-Jun-13 5.0 10.0 ND ND ---ND 28-Oct-13 5.0 10.0 ND ND ---ND 6-May-14 5.0 10.0 ND ND ---ND 22-Oct-14 5.0 10.0 --- ND ND ND 21-May-15 2.5 10.0 ND ND ND ND 9-Dec-15 2.5 10.0 ND ND ND ND Thallium 5-May-05 --- 10 22.0 11.0 ---ND 3-Nov-05 --- 10 20.0 ND ---ND 25-May-06 --- 10 ND ND ---ND 2-Nov-06 --- 10 ND ND ---ND 30-May-07 --- 5.5 0.053 J ND ---ND 29-Nov-07 --- 5.5 0.055 J ND ---ND 29-May-08 3.0 5.5 ND ND ---ND 6-Nov-08 3.0 5.5 ND ND ---ND 3-Jun-09 3.0 5.5 ND ND ---ND 18-Nov-09 3.0 5.5 ND ND ---4.2 J NC 2B = NE (05/01/07)15-Jun-10 3.0 5.5 3.2 J ND ---ND 1-Dec-10 3.0 5.5 ND ND ---4.0 J 1-Jun-11 3.0 5.5 ND ND ---ND 20-Dec-11 5.4 5.5 ND ND ---ND 30-May-12 5.4 5.5 ND ND ---ND 5-Dec-12 5.4 5.5 ND ND ---ND 12-Jun-13 5.4 5.5 ND ND ---ND 28-Oct-13 5.4 5.5 ND ND ---ND 6-May-14 5.4 5.5 ND ND ---ND 22-Oct-14 5.4 5.5 --- ND ND ND 21-May-15 5.0 5.5 ND ND ND ND 9-Dec-15 5.0 5.5 ND ND ND ND Burke County John's River Landfill - Phase 1A Permit 12-03 Page 6 of 9 Joyce Engineering TABLE 4: HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER Sample Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks Vanadium 6-Nov-08 0.20 25.0 0.90 B 8.9 B ---2.1 J 3-Jun-09 0.20 25.0 17.4 J 7.5 J ---1.0 J 18-Nov-09 0.20 25.0 0.26 B 0.30 B --- 0.56 J NC 2B = NE (05/01/07)15-Jun-10 0.20 25.0 1.5 B 1.0 B --- 0.98 J 1-Dec-10 0.20 25.0 1.1 J 13.7 J ---ND 1-Jun-11 0.20 25.0 1.1 J 0.74 J ---ND 20-Dec-11 5.0 25.0 ND ND ---ND 30-May-12 5.0 25.0 ND ND ---ND 5-Dec-12 5.0 25.0 ND ND ---ND 12-Jun-13 5.0 25.0 7.6 J ND ---ND 28-Oct-13 5.0 25.0 ND ND ---ND 6-May-14 5.0 25.0 ND ND ---ND 22-Oct-14 5.0 25.0 --- ND ND ND 21-May-15 2.5 25.0 7.5 J ND 4.1 J ND 9-Dec-15 2.5 25.0 ND ND 3.9 J ND Zinc 30-May-07 --- 10 1.8 B ND ---1.6 J 29-Nov-07 --- 10 9.6 B ND ---3.1 J 29-May-08 0.40 10.0 6.0 B ND ---3.0 J 6-Nov-08 0.40 10.0 0.82 B 1.4 B ---2.7 J 3-Jun-09 0.40 10.0 33.7 B 9.6 B --- 82.0 18-Nov-09 0.40 10.0 2.2 B 2.5 B ---3.1 J NC 2B = 50 µg/L (05/01/07)15-Jun-10 0.40 10.0 ND ND ---ND 1-Dec-10 0.40 10.0 8.8 J 6.6 J --- 0.62 J 1-Jun-11 0.40 10.0 15.1 B 21.5 B --- 13.7 20-Dec-11 10.0 10.0 ND ND ---ND 30-May-12 10.0 10.0 ND ND ---ND 5-Dec-12 10.0 10.0 ND ND ---ND 12-Jun-13 10.0 10.0 ND ND --- 76.5 28-Oct-13 10.0 10.0 ND ND ---ND 6-May-14 10.0 10.0 ND ND ---ND 22-Oct-14 10.0 10.0 --- ND ND ND 21-May-15 5.0 10.0 ND 5.8 J ND ND 9-Dec-15 5.0 10.0 ND ND ND ND Burke County John's River Landfill - Phase 1A Permit 12-03 Page 7 of 9 Joyce Engineering TABLE 4: HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER Sample Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks Organic Compounds Acetone 29-Nov-07 --- 100 3.6 B ND --- 5.1 J 29-May-08 20 100 ND ND --- ND 6-Nov-08 20 100 ND ND --- ND 3-Jun-09 2.2 100 5.7 J ND --- ND 18-Nov-09 2.2 100 ND ND --- ND NC 2B = NE (05/01/07) 15-Jun-10 2.2 100 2.2 B 2.3 B --- 7.2 J 1-Dec-10 2.2 100 ND ND --- 3.7 J 1-Jun-11 2.2 100 5.4 B 2.9 B --- 3.9 J 20-Dec-11 2.2 100 ND ND --- ND 30-May-12 2.2 100 ND ND --- ND 5-Dec-12 10.0 100 ND ND --- ND 12-Jun-13 10.0 100 ND ND --- ND 28-Oct-13 10.0 100 ND ND --- ND 6-May-14 10.0 100 ND ND --- ND 22-Oct-14 10.0 100 --- ND ND ND 21-May-15 10.0 100 ND ND ND ND 9-Dec-15 10.0 100 ND ND ND ND Chloromethane 15-Jun-10 0.11 1.0 ND 0.11 J --- ND NC 2B = NE (05/01/07) 1-Dec-10 0.11 1.0 ND ND --- ND 1-Jun-11 0.11 1.0 ND ND --- ND 20-Dec-11 0.11 1.0 ND ND --- ND 30-May-12 0.11 1.0 ND ND --- ND 5-Dec-12 0.11 1.0 ND ND --- ND 12-Jun-13 0.11 1.0 ND ND --- ND 28-Oct-13 0.11 1.0 ND ND --- ND 6-May-14 0.11 1.0 ND ND --- ND 22-Oct-14 0.11 1.0 --- ND ND ND 21-May-15 0.11 1.0 ND ND ND ND 9-Dec-15 0.11 1.0 ND ND ND ND 1,1-Dichloroethane 1-Jun-11 0.32 5.0 ND 0.41 J --- ND NC 2B = NE (05/01/07) 20-Dec-11 0.32 5.0 ND ND --- ND 30-May-12 0.32 5.0 ND ND --- ND 5-Dec-12 0.32 5.0 ND 1.6 J --- ND 12-Jun-13 0.32 5.0 ND ND --- ND 28-Oct-13 0.32 5.0 ND 0.96 J --- ND 6-May-14 0.32 5.0 ND ND --- ND 22-Oct-14 0.32 5.0 --- 1.5 J ND ND 21-May-15 0.32 5.0 ND ND ND ND 9-Dec-15 0.32 5.0 ND ND ND ND Burke County John's River Landfill - Phase 1A Permit 12-03 Page 8 of 9 Joyce Engineering TABLE 4: HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER Sample Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks cis-1,2-Dichloroethene 22-Oct-14 0.2 5.0 --- 0.20 J ND ND 21-May-15 0.2 5.0 ND ND ND ND NC 2B = NE (05/15/13)9-Dec-15 0.2 5.0 ND ND ND ND Notes: All concentrations in micrograms per liter (µg/L) = parts per billion. RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present). DL = Laboratory Detection Limit. NI = Monitoring well not yet installed. AB = Monitoring well abandoned. --- = Not sampled for this parameter or Not reported ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006). J = Estimated value - concentration is less than the RL but greater than the DL. B = Blank-Qualified (Concentration suspected to reflect laboratory or field contamination based on similar concentrations detected in field, trip, or method blanks). D = Sample was diluted when analyzed. NC 2B = Groundwater Standard from 15A NCAC 2B. NE = No NC 2B established. Values above the NC 2B Standard are bold. Surface waters classified as WS-IV (water supply IV, highly developed), B (primary recreation, fresh water), and CA (critical area). Burke County John's River Landfill - Phase 1A Permit 12-03 Page 9 of 9 Joyce Engineering TA B L E 5 : H i s t o r i c a l G r o u n d w a t e r E l e v a t i o n s MW - 9 M W - 1 7 M W - 2 0 M W - 2 1 M W - 8 M W - 1 0 M W - 1 1 M W - 1 2 M W - 1 3 M W - 1 4 M W - 1 5 S M W - 1 5 D M W - 1 6 S M W - 1 6 D M W - 1 8 M W - 1 9 M W - 3 6 M W - 3 8 TO C E l e v a t i o n 11 4 5 . 9 7 1 1 2 1 . 7 7 1 1 1 5 . 0 4 1 0 9 9 . 8 6 1 0 7 2 . 5 5 1 0 1 2 . 2 3 1 0 2 8 . 5 8 1 0 3 4 . 2 2 1 0 5 9 . 4 0 1 0 1 7 . 9 6 1 0 6 9 . 0 4 1 0 6 9 . 0 6 1 0 0 7 . 6 7 1 0 0 7 . 8 7 9 9 8 . 4 9 9 9 9 . 9 5 1 0 9 9 . 5 2 1 0 8 7 . 7 6 We l l D e p t h 67 . 6 3 4 3 . 3 5 6 7 . 0 0 4 1 . 0 0 3 9 . 3 5 2 4 . 1 6 4 4 . 2 0 5 3 . 0 0 5 9 . 0 0 2 3 . 2 0 5 6 . 1 6 1 2 1 . 3 9 2 1 . 4 5 9 0 . 5 0 1 2 . 0 0 1 5 . 0 0 4 5 . 0 0 7 3 . 1 3 Ju l - 9 5 10 8 9 . 4 8 N I N M N M 1 0 4 0 . 8 8 9 9 8 . 4 0 9 9 4 . 1 3 9 9 3 . 6 5 1 0 0 9 . 6 7 N I N I N I N I N I N I N I N I N I Se p - 9 5 10 9 0 . 6 0 N I N M N M 1 0 4 0 . 8 0 9 9 7 . 7 3 9 9 3 . 1 0 9 9 3 . 5 4 1 0 0 8 . 8 8 N I N I N I N I N I N I N I N I N I Oc t - 9 5 10 9 0 . 3 2 N I N M N M 1 0 4 1 . 1 6 9 9 8 . 7 5 9 9 4 . 3 8 9 9 4 . 3 2 1 0 0 9 . 4 6 N I N I N I N I N I N I N I N I N I Ap r - 9 6 10 9 0 . 6 6 N I N M N M 1 0 4 1 . 0 8 9 9 8 . 7 8 9 9 3 . 3 0 9 9 3 . 8 4 1 0 1 0 . 4 0 N I N I N I N I N I N I N I N I N I Ju n - 9 6 10 8 9 . 4 0 N I N M N M 1 0 4 0 . 7 8 9 9 8 . 4 1 9 9 2 . 8 0 9 9 4 . 5 0 1 0 1 0 . 0 3 1 0 0 7 . 0 1 1 0 2 2 . 7 0 1 0 2 3 . 3 8 N I N I N I N I N I N I De c - 9 6 10 8 7 . 2 8 N I N M N M N M N M N M 9 9 4 . 6 6 1 0 0 9 . 1 7 1 0 0 7 . 1 4 1 0 2 1 . 3 0 1 0 2 1 . 8 0 N I N I N I N I N I N I Ma y - 9 7 10 8 7 . 0 7 N I N M N M N M 9 9 8 . 6 6 9 9 3 . 0 4 9 9 3 . 5 4 1 0 0 9 . 5 2 N M N M N M N I N I N I N I N I N I No v - 9 7 10 9 1 . 4 9 N I N M N M N M 9 9 9 . 0 0 9 9 3 . 5 8 9 9 3 . 9 8 1 0 1 0 . 4 0 N M N M N M N I N I N I N I N I N I Ma y - 9 8 10 9 0 . 9 7 N I N M N M N M 9 9 9 . 0 8 9 9 3 . 5 8 9 9 4 . 5 2 1 0 1 1 . 5 7 N M N M N M N I N I N I N I N I N I No v - 9 8 10 8 6 . 6 5 N I N M N M N M 9 9 8 . 6 6 9 9 2 . 8 3 9 9 3 . 4 2 1 0 1 0 . 0 1 N M N M N M N I N I N I N I N I N I Ap r - 9 9 10 8 6 . 3 5 N M N M N M 1 0 3 9 . 8 7 9 9 8 . 1 9 9 9 2 . 7 3 9 9 3 . 1 2 1 0 0 9 . 4 0 N M 1 0 2 3 . 2 6 1 0 2 3 . 4 0 N M N M N I N I N I N I Ma y - 9 9 10 8 7 . 7 0 N M N M N M N M 9 9 8 . 9 8 1 0 0 3 . 3 5 9 9 3 . 7 8 1 0 1 0 . 5 4 N M N M N M N M N M N I N I N I N I Oc t - 9 9 10 8 5 . 8 7 1 0 7 9 . 4 3 N M N M N M 9 9 8 . 8 4 9 9 2 . 8 6 9 9 3 . 4 3 1 0 0 9 . 6 5 N M N M N M 9 9 2 . 1 5 9 9 3 . 9 4 N I N I N I N I Ma y - 0 0 10 8 5 . 0 9 1 0 7 6 . 5 5 N M N M N M 9 9 9 . 3 8 9 9 3 . 7 1 9 9 4 . 0 1 1 0 0 9 . 7 5 N M N M N M 9 9 2 . 5 9 9 9 4 . 0 9 N I N I N I N I No v - 0 0 10 8 5 . 2 2 1 0 7 6 . 6 0 N M N M N M 9 9 8 . 6 0 9 9 2 . 2 1 9 9 2 . 4 6 1 0 0 8 . 8 9 N M N M N M 9 9 1 . 0 7 9 9 2 . 6 2 N I N I N I N I Ma y - 0 1 10 8 5 . 7 6 1 0 7 7 . 0 6 N M N M N M 9 9 7 . 8 5 9 9 2 . 7 5 9 9 3 . 4 1 1 0 0 9 . 6 2 N M N M N M 9 9 2 . 0 7 9 9 3 . 5 9 N I N I N I N I No v - 0 1 10 8 5 . 8 4 1 0 7 9 . 0 7 N M N M N M 9 9 8 . 4 3 9 9 2 . 2 2 9 9 2 . 9 0 1 0 0 8 . 7 9 N M N M N M 9 9 1 . 3 6 9 9 2 . 8 4 N I N I N I N I Ma y - 0 2 10 8 6 . 2 9 1 0 8 0 . 3 6 N M N M N M 9 9 8 . 5 8 9 9 2 . 8 3 9 9 3 . 4 8 1 0 0 9 . 5 0 N M 1 0 2 1 . 9 4 1 0 2 2 . 3 0 9 9 2 . 0 2 9 9 3 . 4 7 N I N I N I N I No v - 0 2 10 8 5 . 1 9 1 0 7 9 . 7 1 N M N M N M 9 9 9 . 0 4 9 9 3 . 6 3 9 9 3 . 9 3 1 0 0 9 . 2 4 N M 1 0 2 1 . 2 5 1 0 2 1 . 5 9 9 9 2 . 6 6 9 9 3 . 6 0 N I N I N I N I Ma y - 0 3 10 9 4 . 2 5 1 0 9 2 . 3 5 N M N M N M 9 9 9 . 5 3 9 9 4 . 1 6 9 9 4 . 9 6 1 0 1 2 . 9 5 N M N M N M 9 9 3 . 0 3 9 9 4 . 2 2 N I N I N I N I No v - 0 3 10 8 9 . 4 9 1 0 8 7 . 0 2 N M N M 1 0 4 1 . 0 5 9 9 9 . 4 3 9 9 3 . 7 8 9 9 4 . 6 7 1 0 1 1 . 6 0 1 0 0 8 . 0 6 1 0 2 7 . 0 8 1 0 2 8 . 2 9 9 9 2 . 8 4 9 9 4 . 1 9 N I N I N I N I Ma y - 0 4 10 8 6 . 8 1 1 0 8 2 . 5 4 N M N M 1 0 4 0 . 2 8 9 9 9 . 2 2 9 9 3 . 2 5 9 9 3 . 8 5 1 0 1 1 . 4 0 1 0 0 7 . 9 6 1 0 2 5 . 7 1 1 0 2 6 . 5 9 9 9 2 . 1 8 9 9 3 . 8 7 N I N I N I N I No v - 0 4 10 8 5 . 9 2 1 0 8 0 . 3 8 N M N M N M 9 9 9 . 2 6 9 9 3 . 5 8 9 9 3 . 7 2 1 0 1 0 . 7 8 N M N M N M 9 9 2 . 5 7 9 9 3 . 6 7 N I N I N I N I Ma y - 0 5 10 8 7 . 8 2 1 0 8 3 . 3 5 N M N M N M 9 9 9 . 0 1 9 9 3 . 1 7 9 9 3 . 8 7 1 0 1 1 . 2 6 N M N M N M 9 9 2 . 3 0 9 9 3 . 7 2 N I N I N I N I No v - 0 5 AB 1 0 8 2 . 6 6 N M N M N M 9 9 8 . 9 1 9 9 2 . 7 6 9 9 3 . 5 0 1 0 1 0 . 5 9 N M N M N M 9 9 1 . 9 2 9 9 3 . 1 9 N I N I N I N I 25 - M a y - 0 6 AB 1 0 8 1 . 1 3 N M N M N M 9 9 8 . 7 9 9 9 2 . 8 9 9 9 3 . 5 2 1 0 1 0 . 4 8 N M N M N M 9 9 1 . 9 7 9 9 3 . 4 2 N I N I N I N I 01 - N o v - 0 6 AB 1 0 8 1 . 1 9 N M N M N M 9 9 9 . 3 5 9 9 3 . 4 2 9 9 4 . 0 2 1 0 1 0 . 5 8 1 0 0 8 . 4 6 1 0 2 3 . 2 8 N M 9 9 2 . 5 9 9 9 3 . 7 3 N I N I N I N I 30 - M a y - 0 7 AB 1 0 8 3 . 4 2 N M N M N M 9 9 8 . 8 9 9 9 2 . 6 5 9 9 3 . 4 2 1 0 1 0 . 8 0 N M N M N M 9 9 1 . 8 4 9 9 3 . 4 7 N I N I N I N I 02 - A u g - 0 7 AB N M N M N M N M N M N M N M N M N M N M N M N M 9 9 3 . 2 8 N I N I N I N I 28 - N o v - 0 7 AB 1 0 7 7 . 8 5 N M N M N M 9 9 8 . 0 2 9 8 9 . 4 6 9 9 0 . 5 2 1 0 0 9 . 0 1 N M N M N M 9 8 8 . 8 4 9 9 0 . 3 0 N I N I N I N I 29 - M a y - 0 8 AB 1 0 7 8 . 5 2 N M N M N M 9 9 8 . 6 4 9 9 2 . 5 0 9 9 3 . 2 2 1 0 1 0 . 0 2 N M N M N M 9 9 1 . 7 4 9 9 3 . 1 3 N I N I N I N I 06 - N o v - 0 8 AB 1 0 7 8 . 7 7 N M N M N M 9 9 8 . 8 3 9 9 3 . 3 6 9 9 3 . 7 8 1 0 0 9 . 1 0 N M N M N M 9 9 2 . 4 2 9 9 3 . 6 7 N I N I N I N I 02 - J u n - 0 9 AB 1 0 8 3 . 3 3 N M N M N M 1 0 0 0 . 6 3 9 9 4 . 1 7 9 9 4 . 8 6 1 0 1 1 . 2 0 N M N M N M 9 9 3 . 8 9 9 9 4 . 7 0 9 9 3 . 4 8 9 9 4 . 7 5 N I N I 16 - N o v - 0 9 AB 1 0 8 2 . 2 9 N M N M N M 9 9 9 . 6 0 9 9 4 . 4 3 9 9 4 . 9 8 1 0 1 0 . 4 3 N M N M N M 9 9 3 . 5 3 1 0 0 4 . 5 6 9 9 4 . 2 8 9 9 3 . 6 9 N I N I Lo c a t i o n Do w n g r a d i e n t Ba c k g r o u n d Performance Sentinel Bu r k e C o . J o h n ' s R i v e r W a s t e M a n a g e m e n t F a c i l i t y , P e r m i t 1 2 - 0 3 C+ D - o v e r - M S W L a n d f i l l Pa g e 1 o f 2 Joyce Engineering TA B L E 5 : H i s t o r i c a l G r o u n d w a t e r E l e v a t i o n s MW - 9 M W - 1 7 M W - 2 0 M W - 2 1 M W - 8 M W - 1 0 M W - 1 1 M W - 1 2 M W - 1 3 M W - 1 4 M W - 1 5 S M W - 1 5 D M W - 1 6 S M W - 1 6 D M W - 1 8 M W - 1 9 M W - 3 6 M W - 3 8 TO C E l e v a t i o n 11 4 5 . 9 7 1 1 2 1 . 7 7 1 1 1 5 . 0 4 1 0 9 9 . 8 6 1 0 7 2 . 5 5 1 0 1 2 . 2 3 1 0 2 8 . 5 8 1 0 3 4 . 2 2 1 0 5 9 . 4 0 1 0 1 7 . 9 6 1 0 6 9 . 0 4 1 0 6 9 . 0 6 1 0 0 7 . 6 7 1 0 0 7 . 8 7 9 9 8 . 4 9 9 9 9 . 9 5 1 0 9 9 . 5 2 1 0 8 7 . 7 6 We l l D e p t h 67 . 6 3 4 3 . 3 5 6 7 . 0 0 4 1 . 0 0 3 9 . 3 5 2 4 . 1 6 4 4 . 2 0 5 3 . 0 0 5 9 . 0 0 2 3 . 2 0 5 6 . 1 6 1 2 1 . 3 9 2 1 . 4 5 9 0 . 5 0 1 2 . 0 0 1 5 . 0 0 4 5 . 0 0 7 3 . 1 3 Lo c a t i o n Do w n g r a d i e n t Ba c k g r o u n d Performance Sentinel 15 - J u n - 1 0 AB 1 0 8 4 . 8 1 N M N M N M 9 9 9 . 0 9 9 9 2 . 9 0 9 9 3 . 7 1 1 0 1 1 . 3 2 N M N M N M 9 9 2 . 1 0 9 9 3 . 5 6 9 9 2 . 6 7 9 9 2 . 6 0 N I N I 30 - N o v - 1 0 AB 1 0 7 9 . 7 6 1 0 5 6 . 1 0 N M N M 9 9 9 . 2 4 9 9 3 . 1 4 9 9 3 . 5 6 1 0 1 0 . 2 5 N M N M N M 9 9 2 . 2 5 9 9 2 . 9 0 9 9 2 . 1 4 9 9 2 . 1 3 N I N I 01 - J u n - 1 1 AB 1 0 8 0 . 6 6 1 0 5 3 . 9 3 N M N M 9 9 9 . 2 2 9 9 3 . 3 6 9 9 3 . 9 2 1 0 1 0 . 6 2 N M N M N M 9 9 2 . 4 8 9 9 3 . 7 4 9 9 2 . 9 8 9 9 2 . 8 1 N M N M 20 - D e c - 1 1 AB 1 0 7 7 . 4 7 1 0 5 2 . 2 7 N M N M 9 9 9 . 2 7 9 9 3 . 6 6 9 9 4 . 0 0 1 0 0 9 . 5 6 N M N M N M 9 9 2 . 6 7 9 9 3 . 8 8 N M N M N M N M 30 - M a y - 1 2 AB N M 1 0 5 2 . 6 3 N M N M 1 0 0 0 . 3 2 9 9 3 . 3 7 9 9 3 . 9 3 1 0 0 9 . 5 2 N M N M N M 9 9 2 . 4 6 9 9 3 . 7 6 9 9 3 . 0 9 9 9 3 . 1 5 N M N M 11 - D e c - 1 2 AB N M 1 0 5 3 . 5 1 N M N M 9 9 9 . 0 4 9 9 2 . 9 4 9 9 3 . 4 6 1 0 0 9 . 5 2 N M N M N M 9 9 2 . 0 5 9 9 3 . 4 3 N M N M N M N M 11 - J u n - 1 3 AB N M 1 0 5 5 . 8 0 N M N M 1 0 0 1 . 2 5 9 9 6 . 3 9 9 9 6 . 6 0 1 0 1 1 . 0 0 N M N M N M 9 9 5 . 4 7 9 9 6 . 5 1 N M N M N M N M 28 - O c t - 1 3 AB N M 1 0 6 0 . 4 4 N M N M 9 9 9 . 4 2 9 9 3 . 1 3 9 9 3 . 8 0 1 0 1 0 . 6 8 N M N M N M 9 9 2 . 5 5 9 9 3 . 7 2 9 9 3 . 6 3 9 9 2 . 9 5 N M N M 06 - M a y - 1 4 AB N M 1 0 5 8 . 2 4 N M N M 9 9 9 . 7 1 9 9 0 . 6 3 9 9 4 . 2 2 1 0 1 0 . 8 4 N M N M N M 9 9 2 . 7 3 9 9 4 . 0 2 9 9 3 . 3 1 9 9 3 . 1 7 1 0 6 9 . 1 7 1 0 4 2 . 1 8 21 - O c t - 1 4 AB N M 1 0 5 6 . 4 2 1 0 6 3 . 4 8 N M 9 9 9 . 4 9 9 9 3 . 9 3 9 9 4 . 2 7 1 0 0 9 . 9 8 N M 1 0 2 4 . 6 4 N M 9 9 2 . 9 7 9 9 4 . 4 0 N M N M 1 0 6 6 . 5 2 1 0 4 5 . 1 8 21 - M a y - 1 5 AB N M 1 0 5 3 . 6 9 1 0 6 2 . 1 8 N M 9 9 9 . 2 2 9 9 3 . 0 3 9 9 3 . 6 2 1 0 1 0 . 1 8 N M 1 0 2 5 . 1 7 N M 9 9 2 . 1 1 9 9 3 . 3 6 9 9 2 . 5 4 9 9 2 . 6 0 1 0 6 6 . 0 3 1 0 4 4 . 6 8 08 - D e c - 1 5 AB N M 1 0 5 1 . 6 5 1 0 6 1 . 7 1 N M 9 9 9 . 4 9 9 9 2 . 2 5 9 9 3 . 4 2 1 0 0 9 . 6 4 N M 1 0 2 5 . 1 9 N M 9 9 4 . 4 7 9 9 5 . 1 7 N M N M 1 0 6 6 . 7 2 1 0 4 6 . 2 4 No t e s : Al l e l e v a t i o n s a r e i n f e e t a b o v e m e a n s e a l e v e l . N I = M o n i t o r i n g w e l l n o t y e t i n s t a l l e d . N M = G r o u n d w a t e r l e v e l n o t m e a s u r e d . A B = M o n i t o r i n g w e l l a b a n d o n e d . Bu r k e C o . J o h n ' s R i v e r W a s t e M a n a g e m e n t F a c i l i t y , P e r m i t 1 2 - 0 3 C+ D - o v e r - M S W L a n d f i l l Pa g e 2 o f 2 Joyce Engineering TA B L E 6 : H y d r a u l i c G r a d i e n t s a n d G r o u n d w a t e r F l o w V e l o c i t i e s GR A D I E N T CA L C U L A T I O N SE G M E N T FL O W L I N E LE N G T H (f e e t ) FL O W DI R E C T I O N GR O U N D W A T E R EL E V A T I O N (f e e t ) HO R I Z O N T A L GR A D I E N T i (ft / f t ) HY D R A U L I C CO N D U C T I V I T Y K (f t / d a y ) EF F E C T I V E PO R O S I T Y n e LINEAR VELOCITY V (ft/y ear ) 10 7 0 10 2 0 10 7 0 10 0 0 10 7 0 10 1 0 10 6 0 10 3 0 AV E R A G E : 0 . 0 4 8 0 AV E R A G E : 1 4 3 . 8 No t e s : Hy d r a u l i c c o n d u c t i v i t y ( K =3 . 2 8 f t / d a y ) i s b a s e d o n t h e a r i t h m e t r i c m e a n s o f K f r o m i n d i v i d u a l s l u g t e s t s i n s a p r o l i t e w e l l s a t t h e f a c i l i t y . Ef f e c t i v e P o r o s i t y ( n e = 0 . 4 0 ) i s a s s u m m e d t o b e s l i g h t l y l e s s t h a n t h e a v e r a g e l a b o r a t o r y p o r o s i t y f o r s i t e s o i l s a m p l e s ( s a p r o l i t e ) = 4 4 % ( 0 . 4 4 ) . Gr a d i e n t s e g m e n t s a r e b a s e d o n t h e D e c e m b e r 2 0 1 5 g r o u n d w a t e r p o t e n t i o m e t r i c s u r f a c e m a p ( s e e D r a w i n g 1 ) . V = K i / n e ; a s s u m e s h o m o g e n e o u s i s o t r o p i c p o r o u s a q u i f e r . De c e m b e r 2 0 1 5 i 1 96 7 SS W 0. 0 5 1 7 3 . 2 8 E + 0 0 0 . 4 0 1 5 4 . 8 0. 0 3 9 0 116.6 0. 4 0 i 4 0. 4 0 3. 2 8 E + 0 0 77 0 S E 140.1 i 3 0. 4 0 3. 2 8 E + 0 0 1, 0 9 8 S S E 0 . 0 5 4 6 1 6 3 . 6 3. 2 8 E + 0 0 1, 4 9 5 S 0. 0 4 6 8 i 2 Bu r k e C o u n t y Jo h n ' s R i v e r L a n d f i l l , P e r m i t 1 2 - 0 3 Joyce Engineering TABLE 7: HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-14 MW-15S MW-16S MW-18 MW-19 Temperature (FP)11/3/2006 oC 14.90 NS NS 15.25 15.25 16.97 14.22 10.38 14.77 16.52 NI NI 6/3/2009 oC 15.90 NS NS 19.10 19.10 19.40 16.90 NS NS 14.50 16.20 16.30 11/17/2009 oC 12.0 NS NS 13.9 13.9 15.9 15.6 NS NS 13.7 13.8 12.0 6/16/2010 oC 16.06 NS NS 17.65 17.65 17.8 15.5 NS NS 17.69 18.83 16.3 12/1/2010 oC 13.43 NU NS 11.17 11.17 12.27 11.24 NS NS 14.1 14.4 14.6 6/1/2011 oC 17.21 NU NS 17.20 18.39 17.59 19.00 NS NS 21.68 15.04 16.57 12/20/2011 oC NS 14.30 NS 15.40 14.52 14.30 15.00 NS NS 14.69 NS NS 5/30/2012 oC NS 18.18 NS 16.80 21.70 20.80 17.50 NS NS 16.90 16.99 17.26 12/5/2012 oC NS 15.40 NS 16.30 15.00 15.50 15.60 NS NS 16.90 NS NS 6/12/2013 oC NS 18.10 NS 18.10 18.70 18.20 16.20 NS NS 16.30 NS NS 10/28/2013 oC NS 17.70 NS 16.90 18.40 18.20 16.10 NS NS 17.50 17.40 17.10 5/6/2014 oC NS 16.90 NS 20.00 22.40 21.00 16.80 NS NS 18.00 14.90 14.50 10/23/2014 oC NS * 17.20 16.00 13.00 11.50 14.80 NS 14.90 9.80 NS NS 5/21/2015 oC NS 17.80 19.80 16.80 18.70 22.20 17.70 NS 16.60 18.60 18.10 25.50 12/8/2015 oC NS 16.20 15.20 15.80 15.40 16.10 15.30 NS 15.10 16.90 NS NS pH (FP)11/3/2006 S.U. 5.34 NS NS 5.32 5.32 5.40 4.41 5.20 4.80 5.68 NI NI 6/3/2009 S.U. 5.79 NS NS 5.74 5.74 5.62 4.58 NS NS 5.96 6.20 6.28 11/17/2009 S.U. 6.03 NS NS 5.92 5.92 5.49 4.53 NS NS 6.08 5.84 6.24 6/16/2010 S.U. 6.23 NS NS 6.37 6.37 6.28 4.46 NS NS 5.64 6.28 6.05 12/1/2010 S.U. 5.40 NU NS 6.10 6.10 6.10 4.67 NS NS 6.05 6.52 6.36 6/1/2011 S.U. 5.83 NU NS 5.50 6.01 5.96 4.64 NS NS 5.87 6.25 6.24 12/20/2011 S.U. NS 6.12 NS 5.62 5.98 5.90 4.81 NS NS 6.01 NS NS 5/30/2012 S.U. NS 6.61 NS 5.41 5.74 5.57 4.63 NS NS 5.61 5.84 5.76 12/5/2012 S.U. NS 5.41 NS 5.25 6.12 5.93 4.83 NS NS 5.75 NS NS 6/12/2013 S.U. NS 5.92 NS 5.88 6.00 5.32 4.51 NS NS 5.57 NS NS 10/28/2013 S.U. NS 6.89 NS 5.90 5.85 5.88 4.53 NS NS 5.76 6.12 6.22 5/6/2014 S.U. NS 5.37 NS 6.25 5.46 5.69 5.34 NS NS 5.74 5.41 5.74 10/23/2014 S.U. NS * 5.52 5.38 5.80 5.64 4.35 NS 4.99 5.41 NS NS 5/21/2015 S.U. NS 6.18 5.29 5.60 6.03 6.25 4.80 NS 4.75 5.88 6.09 6.19 12/8/2015 S.U. NS 6.09 5.13 5.88 6.06 5.81 4.48 NS 5.11 5.66 NS NS Conductivity (FP)11/3/2006 µS/cm 59 NS NS 133 133 95 30 13 50 207 NI NI 6/3/2009 µS/cm 139.5 NS NS 258 258 146.2 46.5 NS NS 286 220 329 11/17/2009 µS/cm 182.7 NS NS 279 279 146.9 55.4 NS NS 245 218 330 6/16/2010 µS/cm 124 NS NS 310 310 214 47.2 NS NS 213 216 309 12/1/2010 µS/cm 143 NU NS 235 235 133 39 NS NS 160 292 310 6/1/2011 µS/cm 69 NU NS 157.3 384 175 44.9 NS NS 293 241 392 12/20/2011 µS/cm NS 26 NS 168 314 152 44.3 NS NS 229 NS NS 5/30/2012 µS/cm NS 26.0 NS 167.1 392.0 177.0 48.9 NS NS 229.0 227.0 256.0 12/5/2012 µS/cm NS 19.5 NS 92.6 370.1 148.8 45.9 NS NS 197.4 NS NS 6/12/2013 µS/cm NS 29.8 NS 242.7 345.2 201.7 32.4 NS NS 201.7 NS NS 10/28/2013 µS/cm NS 24.5 NS 236.1 430.0 189.5 36.8 NS NS 229.9 215.6 295.2 5/6/2014 µS/cm NS 30.1 NS 234 460.7 208.5 41.2 NS NS 230.4 179.0 276.9 10/23/2014 µS/cm NS * 68.1 216.0 311.0 170.2 44.8 NS 78.1 103.8 NS NS 5/21/2015 µS/cm NS 19.8 27.2 158.7 435.4 221.5 45.0 NS 73.0 231.2 262.0 412.2 12/8/2015 µS/cm NS 24.1 15.5 20.0 400.6 203.4 45.0 NS 51.5 208.5 NS NS ORP (FP)11/3/2006 mV 93.8 NS NS 143.9 143.9 90.5 166.3 133.2 -3.6 43.2 NI NI 6/3/2009 mV 195.0 NS NS 150.0 150.0 130.0 NS NS NS 138.0 132.0 113.0 11/17/2009 mV 167.0 NS NS 133.0 133.0 162.0 NS NS NS 132.0 158.0 128.0 6/16/2010 mV 13.8 NS NS -12.5 -12.5 -58.6 NS NS NS -73.4 -36.8 -63.5 12/1/2010 mV 31.6 NU NS -49.1 -49.1 -74.7 NS NS NS -105.9 NS NS 6/1/2011 mV 73.2 NU NS NS 28.6 -7.2 NS NS NS 40.1 10.3 -2.6 12/20/2011 mV NS 56.8 NS NS 18.7 30.3 NS NS NS 3.9 NS NS 5/30/2012 mV NS 7.1 NS NS -14.8 38.9 NS NS NS 21.7 26.70 20.10 12/5/2012 mV NS 227.2 NS NS -6.9 46.0 NS NS NS 23.4 NS NS 6/12/2013 mV NS 104.7 NS 8.2 -38.0 29.6 NS NS NS 86.4 NS NS 10/28/2013 mV NS 21.7 NS 18.8 -10.5 53.2 NS NS NS 47.3 -7.20 5.40 5/6/2014 mV NS 116.5 NS NS 21.0 29.7 NS NS NS 228.0 94.20 33.90 10/23/2014 mV NS * 104.6 NS -2.3 -3.8 NS NS NS 36.6 NS NS 5/21/2015 mV NS 61.80 136.8 NS 21.9 66.0 NS NS NS 46.9 66.00 12.50 12/8/2015 mV NS 148.80 269.9 NS -21.4 -6.2 NS NS NS 25.7 NS NS Turbidity (FP)11/3/2006 ntu 10.4 NS NS 7.97 7.97 64.0 14.2 26.7 37.1 16.3 NI NI 6/3/2009 ntu 154 NS NS 20.6 20.6 7.54 8.84 NS NS 39.1 390 125 11/17/2009 ntu 318 NS NS 19.65 19.65 7.89 5.80 NS NS 23.0 <100 22.2 6/16/2010 ntu 44.8 NS NS NS 165 95.9 81.20 NS NS 43.2 14.9 9.29 12/1/2010 ntu 20.2 NU NS NS 31 46.4 10.68 NS NS 43.1 >1000 463 6/1/2011 ntu 7.58 NU NS 15 19.06 13.14 13.52 NS NS 5.74 33.4 59.6 12/20/2011 ntu NS 80.4 NS 24.9 46.30 36.70 10.43 NS NS 24.80 NS NS 5/30/2012 ntu NS 14.0 NS 31.9 19.80 33.50 28.90 NS NS 15.90 20.60 27.30 12/5/2012 ntu NS 631 NS 329 19.50 23.50 35.50 NS NS 7.14 NS NS 6/12/2013 ntu NS 21.3 NS 8.24 10.82 15.80 32.40 NS NS 8.11 NS NS 10/28/2013 ntu NS 7.39 NS 9.42 8.30 6.41 11.10 NS NS 4.31 4.62 14.30 5/6/2014 ntu NS 37.1 NS 12.50 12.95 6.05 7.04 NS NS 4.29 37.00 9.20 10/23/2014 ntu NS * 8.15 7.45 21.7 10.04 7.50 NS 6.50 7.55 NS NS 5/21/2015 ntu NS 27.10 8.15 11.01 12.6 17.50 7.55 NS 8.52 7.72 9.10 11.13 12/8/2015 ntu NS 55.60 25.5 17.50 16.7 35.40 NS NS 21.40 30.50 NS NS Background Downgradient Sentinel Burke County John's River C and D over MSW Landfill Permit No. 12-03 Page 1 of 6 Joyce Engineering TABLE 7: HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-14 MW-15S MW-16S MW-18 MW-19 Background Downgradient Sentinel Dissolved Oxygen (FP)11/3/2006 mg/L 4.01 NS NS NS 0.95 1.21 1.29 2.01 2.50 1.10 NI NI 6/3/2009 mg/L 1.21 NS NS NS 0.84 0.57 NS NS NS 0.99 1.38 0.60 11/17/2009 mg/L NS NS NS NS 2.35 4.12 NS NS NS 3.50 2.23 3.20 6/16/2010 mg/L 4.61 NS NS NS 2.49 2.86 NS NS NS 2.10 3.59 4.16 12/1/2010 mg/L 7.94 NU NS NS 1.29 1.29 NS NS NS 5.15 NS NS 6/1/2011 mg/L 4.76 NU NS NS 2.46 1.77 NS NS NS 1.64 3.80 3.27 12/20/2011 mg/L NS 8.18 NS NS 1.87 2.17 NS NS NS 2.17 NS NS 5/30/2012 mg/L NS 6.24 NS NS 3.67 6.33 NS NS NS 1.98 8.47 8.11 12/5/2012 mg/L NS 7.29 NS NS 2.09 3.57 NS NS NS 0.99 NS NS 6/12/2013 mg/L NS 8.68 NS 0.81 1.53 1.25 NS NS NS 1.75 NS NS 10/28/2013 mg/L NS 7.14 NS 1.24 3.42 2.47 NS NS NS 2.82 3.62 3.21 5/6/2014 mg/L NS 7.83 NS NS 1.89 1.47 NS NS NS 1.33 2.25 1.86 10/23/2014 mg/L NS * 5.74 NS 2.78 1.36 NS NS NS 2.75 NS NS 5/21/2015 mg/L NS 0.10 5.66 NS 1.01 1.79 NS NS NS 0.01 1.01 0.10 12/8/2015 mg/L NS 7.53 7.59 NS 4.62 2.47 NS NS NS 1.49 NS NS Carbon Dioxide (FP)11/3/2006 mg/L NS NS NS NS NS NS NS NS NS NS NI NI 6/3/2009 mg/L 170 NS NS NS 295 255 NS NS NS 325 185 315.00 11/17/2009 mg/L 220 NS NS NS 355 335 NS NS NS 385 NS 280 6/16/2010 mg/L 220 NS NS NS 510 395 NS NS NS 430 185 280 12/1/2010 mg/L 25 NU NS NS 440 285 NS NS NS 230 NS NS 6/1/2011 mg/L NS NU NS NS NS NS NS NS NS NS NS NS 12/20/2011 mg/L NS NS NS NS NS NS NS NS NS NS NS NS 5/30/2012 mg/L NS NS NS NS NS NS NS NS NS NS NS NS 12/5/2012 mg/L NS NS NS NS NS NS NS NS NS NS NS NS 6/12/2013 mg/L NS 25.0 NS NS 80 95 NS NS NS 90 NS NS 10/28/2013 mg/L NS 25.0 NS NS 335 240 NS NS NS 130 160 130 5/6/2014 mg/L NS NS NS NS NS NS NS NS NS NS NS NS 10/23/2014 mg/L NS * NS NS NS NS NS NS 105 NS NS NS 5/21/2015 mg/L NS NS NS NS NS NS NS NS 170 NS NS NS 12/8/2015 mg/L NS NS NS NS NS NS NS NS 110 NS NS NS Iron II (ferrous iron) (FP)11/3/2006 mg/L NS NS NS NS 0.5 6.4 2.0 0.0 1.2 7.5 NI NI 6/3/2009 mg/L 0.0 NS NS NS 5.9 9.5 NS NS NS 9.4 7.2 9.4 11/17/2009 mg/L 0.0 NS NS NS 5.0 6.8 NS NS NS 4.0 4.0 6.0 6/16/2010 mg/L 6.5 NS NS NS 8.0 6.5 NS NS NS 4.0 5.0 8.8 12/1/2010 mg/L 0.0 NU NS NS 6.2 4.6 NS NS NS 10.0 NS NS 6/1/2011 mg/L NS NU NS NS NS NS NS NS NS NS NS NS 12/20/2011 mg/L NS 0.0 NS NS 6.1 4.5 NS NS NS 5.6 NS NS 5/30/2012 mg/L NS 0.0 NS NS 5.6 3.8 NS NS NS 5.2 3.20 3.30 12/5/2012 mg/L NS 0.0 NS NS 5.2 4.0 NS NS NS 6.3 NS NS 6/12/2013 mg/L NS 0.0 NS NS 6.0 4.2 NS NS NS 3.0 NS NS 10/28/2013 mg/L NS 0.0 NS NS 5.5 9.0 NS NS NS 4.8 6.5 6.0 5/6/2014 mg/L NS 0.0 NS NS 7.3 4.3 NS NS NS 5.8 5.0 5.8 10/23/2014 mg/L NS * 0.0 NS 4.5 7.0 NS NS NS 3.75 NS NS 5/21/2015 mg/L NS NS 0.0 NS 5.8 7.0 NS NS NS 7.0 4.7 5.8 12/8/2015 mg/L NS NS 0.0 NS 3.5 2.0 NS NS NS 3.2 NS NS Nitrate 11/3/2006 mg/L NS NS NS NS <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 NI NI 6/3/2009 mg/L <0.1 NS NS NS <0.1 <0.1 NS NS NS <0.1 <0.1 0.26 11/17/2009 mg/L <0.1 NS NS NS <0.1 <0.1 NS NS NS <0.1 <0.1 <0.1 6/16/2010 mg/L <0.1 NS NS NS <0.1 <0.1 NS NS NS <0.1 <0.1 <0.1 12/1/2010 mg/L <0.1 NU NS NS <0.1 <0.1 NS NS NS <0.1 NS NS 6/1/2011 mg/L <0.1 NU NS NS <0.1 <0.1 NS NS NS <0.1 <0.1 <0.1 12/20/2011 mg/L NS <0.1 NS NS <0.1 <0.1 NS NS NS <0.1 NS NS 5/30/2012 mg/L NS .207 J NS NS <0.1 <0.1 NS NS NS <0.1 <0.1 <0.1 12/5/2012 mg/L NS .294 J NS NS <0.1 <0.1 NS NS NS <0.1 NS NS 6/12/2013 mg/L NS .384 J NS NS <0.1 <0.1 NS NS NS <0.1 NS NS 10/28/2013 mg/L NS .333 J NS NS <0.1 <0.1 NS NS NS <0.1 <0.1 <0.1 5/6/2014 mg/L NS .282 J NS NS <0.1 <0.1 NS NS NS <0.1 <0.1 <0.1 10/23/2014 mg/L NS * <0.1 NS <0.1 <0.1 NS NS NS <0.1 NS NS 5/21/2015 mg/L NS <0.1 <0.1 NS <0.1 <0.1 NS NS NS <0.1 <0.1 <0.1 12/8/2016 mg/L NS NS .256 J NS <0.1 <0.1 NS NS NS <0.1 NS NS Alkalinity 11/3/2006 mg/L NS NS NS NS 47 36 ND 5 24 106 NI NI 6/3/2009 mg/L 163 NS NS NS 112 62.5 NS NS NS 76.6 80.8 128 11/17/2009 mg/L 70.8 NS NS NS 121 50.0 NS NS NS 83.3 81.2 115 6/16/2010 mg/L 61.2 NS NS NS 154 59.1 NS NS NS 111 74.7 185 12/1/2010 mg/L 35.2 NU NS NS 156 86.9 NS NS NS 64.4 NS NS 6/1/2011 mg/L 45.1 NU NS NS 177 70.7 NS NS NS 109 84.6 132 12/20/2011 mg/L NS 8.58 NS NS 189 70.8 NS NS NS 77.2 NS NS 5/30/2012 mg/L NS 8.14 NS 64.70 200 76.7 8.36 NS NS 104 107.0 150.0 12/5/2012 mg/L NS 7.69 NS 22.60 178 76.6 ND NS NS 106 NS NS 6/12/2013 mg/L NS 7.95 NS 138 202 111 7.02 NS NS 99.7 NS NS 10/28/2013 mg/L NS 8.14 NS 69.9 197 91.3 9.52 NS NS 116 NS NS 5/6/2014 mg/L NS 8.06 NS 85.9 208 90.6 5.52 NS NS 119 68.90 113.0 10/23/2014 mg/L NS * 1.36 J 88.1 215 96.1 75.0 NS NS 122 NS NS 5/21/2015 mg/L NS 6.54 ND 67.300 153.000 67.500 8.780 NS NS 92.100 51.300 154.000 12/8/2015 mg/L NS 8.280 1.030 J 98.400 202.000 88.800 9.130 NS NS 95.900 NS NS Burke County John's River C and D over MSW Landfill Permit No. 12-03 Page 2 of 6 Joyce Engineering TABLE 7: HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-14 MW-15S MW-16S MW-18 MW-19 Background Downgradient Sentinel Chloride 11/3/2006 mg/L NS NS NS NS 9.30 1.69 <1 <1 1.15 2.49 NI NI 6/3/2009 mg/L <5.0 NS NS NS 16.1 <5.0 NS NS NS 6.7 5.9 <5.0 11/17/2009 mg/L <5.0 NS NS NS 16.8 <5.0 NS NS NS <5.0 6.8 <5.0 6/16/2010 mg/L <5.0 NS NS NS 5.45 6.29 NS NS NS 8.55 8.23 <5.0 12/1/2010 mg/L <5.0 NU NS NS 15.1 6.84 NS NS NS <5.0 NS NS 6/1/2011 mg/L <5.0 NU NS NS 17.0 6.33 NS NS NS 7.87 9.45 <5.0 12/20/2011 mg/L NS <5.0 NS NS 20.2 6.40 NS NS NS 6.53 NS NS 5/30/2012 mg/L NS 1.48 NS 6.19 20.0 6.32 2.10 NS NS 5.84 133.0 2.79 12/5/2012 mg/L NS 2.13 NS 5.97 19.5 7.29 2.06 NS NS 7.43 NS NS 6/12/2013 mg/L NS 1.38 NS 13.3 19.5 7.50 2.26 NS NS 5.1 NS NS 10/28/2013 mg/L NS 1.12 NS 11.4 18.1 7.75 2.21 NS NS 8.49 NS NS 5/6/2014 mg/L NS ND NS 17.3 18.2 8.14 1.89 NS NS 8.92 13.50 2.41 10/23/2014 mg/L NS * ND 19.2 20.8 9.05 1.57 NS NS 8.12 NS NS 5/21/2015 mg/L NS 1.550 ND 14.000 25.300 9.680 1.720 NS NS 10.400 12.400 2.500 12/8/2015 mg/L NS 1.840 0.859 J 26.500 30.800 9.400 1.910 NS NS 4.190 NS NS Sulfate 11/3/2006 mg/L NS NS NS NS 3.72 <2 <2 <2 <2 <2 NI NI 6/3/2009 mg/L <5.1 NS NS NS <5.0 <5.0 NS NS NS <5.0 5.8 ND 11/17/2009 mg/L <5.0 NS NS NS <5.0 <5.0 NS NS NS <5.0 <5.0 <5.0 6/16/2010 mg/L <5.0 NS NS NS <5.0 <5.0 NS NS NS <5.0 <5.0 <5.0 12/1/2010 mg/L <2.5 NU NS NS <12.5 <12.5 NS NS NS <12.5 NS NS 6/1/2011 mg/L <5.0 NU NS NS <5.0 <5.0 NS NS NS <5.0 <5.0 <5.0 12/20/2011 mg/L NS <5.0 NS NS <5.0 <5.0 NS NS NS <5.0 NS NS 5/30/2012 mg/L NS <5.0 NS 5.38 <5.0 <5.0 ND NS NS <5.0 <5.0 <5.0 12/5/2012 mg/L NS ND NS 2.88 ND 4.4 J ND NS NS ND NS NS 6/12/2013 mg/L NS ND NS 11.2 J 3.08 J 2.91 J 6.94 J NS NS ND NS NS 10/28/2013 mg/L NS ND NS 4.42 J ND 2.94 J ND NS NS ND NS NS 5/6/2014 mg/L NS ND NS 10.5 J 2.30 J 3.72 J ND NS NS 2.07 J ND 2.49 J 10/23/2014 mg/L NS * ND 7.27 J 2.28 J 3.74 J 1.24 J NS NS 1.94 J NS NS 5/21/2015 mg/L NS ND ND 5.620 J 2.310 J 3.440 J ND NS NS 2.750 J 1.700 J 1.980 J 12/8/2015 mg/L NS ND ND 10.200 J 1.530 J 2.020 J ND NS NS 9.260 J NS NS Sulfide 11/3/2006 mg/L NS NS NS NS 3.72 <2 <2 <2 <2 <2 NI NI 6/3/2009 mg/L <0.10 NS NS NS <0.10 <0.10 NS NS NS <0.10 <0.10 ND 11/17/2009 mg/L <0.10 NS NS NS <0.10 <0.10 NS NS NS <0.10 NS NS 6/16/2010 mg/L <0.10 NS NS NS <0.10 <0.10 NS NS NS <0.10 <0.10 <0.10 12/1/2010 mg/L <0.10 NU NS NS <0.10 <0.10 NS NS NS <0.10 NS NS 6/1/2011 mg/L NS NU NS NS NS NS NS NS NS NS NS NS 12/20/2011 mg/L NS NS NS NS NS NS NS NS NS NS NS NS 5/30/2012 mg/L NS NS NS NS NS NS NS NS NS NS NS NS 12/5/2012 mg/L NS ND NS NS ND ND ND NS NS ND NS NS 6/12/2013 mg/L NS ND NS NS ND ND NS NS NS ND NS NS 10/28/2013 mg/L NS ND NS NS ND ND NS NS NS ND ND ND 5/6/2014 mg/L NS NS NS NS NS NS NS NS NS NS NS NS 10/23/2014 mg/L NS * ND ND ND ND ND NS NS ND NS NS 5/21/2015 mg/L NS NS NS NS NS NS NS NS NS NS NS NS 12/8/2015 mg/L NS NS ND ND ND ND ND NS NS ND NS NS Methane 11/3/2006 mg/L NS NS NS NS 2.23 2.50 3.99 0.36 4.38 2.92 NI NI 6/3/2009 mg/L 0.340 NS NS NS 0.111 8.61 NS NS NS 8.26 0.494 0.814 11/17/2009 mg/L 2.580 NS NS NS 4.310 0.147 NS NS NS 10.300 1.200 0.271 Resample 1/19/2010 mg/L NS NS NS NS NS 2.120 NS NS NS NS NS NS 6/16/2010 mg/L 0.750 NS NS NS 4.600 6.000 NS NS NS 6.200 1.000 1.100 12/1/2010 mg/L 1.35 NU NS NS 3.04 6.0 NS NS NS 6.65 NS NS 6/1/2011 mg/L 2.1 NU NS NS 0.157 0.0128 NS NS NS <0.010 0.899 2.64 12/20/2011 mg/L NS <0.005 NS NS 1.460 6.300 NS NS NS 5.650 NS NS 5/30/2012 mg/L NS 0.0061 NS NS 0.883 6.130 NS NS NS 3.760 0.46 0.718 12/5/2012 mg/L NS ND NS NS 2.070 2.050 NS NS NS 4.910 NS NS 6/12/2013 mg/L NS 0.0063 NS NS 0.964 8.900 NS NS NS 11.400 NS NS 10/28/2013 mg/L NS ND NS NS .0033 J 2.610 NS NS NS 0.173 0.0581 0.0085 5/6/2014 mg/L NS ND NS NS 2.040 6.190 NS NS NS 4.360 0.3850 1.5900 10/23/2014 mg/L NS * 5.93 NS 2.21 ND NS NS NS 5.61 NS NS 5/21/2015 mg/L NS 0.0018 J 0.0012 J NS 2.270 6.700 NS NS 4.68 4.940 0.136 3.060 12/8/2015 mg/L NS NS 2.0 J NS 0.959 0.796 NS NS 8.550 7.510 NS NS Ethane 11/3/2006 mg/L NS NS NS NS <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 NI NI 6/3/2009 mg/L <0.005 NS NS NS <0.005 <0.005 NS NS NS <0.005 <0.005 <0.005 11/17/2009 mg/L <0.005 NS NS NS <0.005 <0.005 NS NS NS <0.005 <0.005 <0.005 Resample 1/19/2010 mg/L NS NS NS NS NS <0.005 NS NS NS NS NS NS 6/16/2010 mg/L <0.013 NS NS NS <0.013 <0.011 NS NS NS <0.011 <0.013 <0.013 12/1/2010 mg/L <0.0022 NU NS NS <0.0022 <0.0022 NS NS NS <0.0022 NS NS 6/1/2011 mg/L NS NU NS NS NS NS NS NS NS NS NS NS 12/20/2011 mg/L NS NS NS NS NS NS NS NS NS NS NS NS 5/30/2012 mg/L NS NS NS NS NS NS NS NS NS NS NS NS 12/5/2012 mg/L NS NS NS NS NS NS NS NS NS NS NS NS 6/12/2013 mg/L NS ND NS NS ND ND NS NS NS ND NS NS 10/28/2013 mg/L NS ND NS NS .0016 J ND NS NS NS ND ND ND 5/6/2014 mg/L NS NS NS NS NS NS NS NS NS NS NS NS 10/23/2014 mg/L NS * NS NS NS NS NS NS NS NS NS NS 5/21/2015 mg/L NS NS NS NS NS NS NS NS NS NS NS NS 12/8/2016 mg/L NS NS NS NS NS NS NS NS NS NS NS NS Burke County John's River C and D over MSW Landfill Permit No. 12-03 Page 3 of 6 Joyce Engineering TABLE 7: HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-14 MW-15S MW-16S MW-18 MW-19 Background Downgradient Sentinel Ethylene (Ethene)11/3/2006 mg/L NS NS NS NS <0.002 <0.002 <0.002 1.93 <0.002 <0.002 NI NI 6/3/2009 mg/L <0.005 NS NS NS <0.005 <0.005 NS NS NS <0.005 <0.005 <0.005 11/17/2009 mg/L <0.005 NS NS NS <0.005 <0.005 NS NS NS <0.005 <0.005 <0.005 Resample 1/19/2010 mg/L NS NS NS NS NS <0.005 NS NS NS NS NS NS 6/16/2010 mg/L <0.013 NS NS NS <0.013 <0.011 NS NS NS <0.011 <0.013 <0.013 12/1/2010 mg/L <0.0018 NU NS NS <0.0018 <0.0018 NS NS NS <0.0018 NS NS 6/1/2011 mg/L NS NU NS NS NS NS NS NS NS NS NS NS 12/20/2011 mg/L NS NS NS NS NS NS NS NS NS NS NS NS 5/30/2012 mg/L NS NS NS NS NS NS NS NS NS NS NS NS 12/5/2012 mg/L NS NS NS NS NS NS NS NS NS NS NS NS 6/12/2013 mg/L NS ND NS NS ND ND NS NS NS ND NS NS 10/28/2013 mg/L NS ND NS NS .0017 J ND NS NS NS ND ND ND 5/6/2014 mg/L NS NS NS NS NS NS NS NS NS NS NS NS 10/23/2014 mg/L NS * NS NS NS NS NS NS NS NS NS NS 5/21/2015 mg/L NS NS NS NS NS NS NS NS NS NS NS NS 12/8/2015 mg/L NS NS NS NS NS NS NS NS NS NS NS NS Dissolved Hydrogen 11/3/2006 nM NS NS NS NS NS NS NS NS NS NS NI NI 6/3/2009 nM 0.480 J NS NS NS 0.720 <0.600 NS NS NS 0.350 J 0.580 J 0.790 11/17/2009 nM 0.780 NS NS NS 0.850 0.690 NS NS NS 1.000 1.200 0.630 6/16/2010 nM 4.800 NS NS NS 3.400 2.800 NS NS NS 2.200 2.800 3.300 12/1/2010 nM 1.500 NU NS NS 0.850 0.740 NS NS NS 0.950 NS NS 6/1/2011 nM 2.300 NU NS NS 2.400 1.900 NS NS NS 2.200 2.100 2.000 12/20/2011 nM NS 21 NS NS 19 6.3 NS NS NS 7.0 NS NS 5/30/2012 nM NS 0.74 NS NS 2.0 1.1 NS NS NS 0.84 0.79 0.76 12/5/2012 nM NS 1.7 NS NS 0.5 J 0.35 J NS NS NS 0.57 J NS NS 6/12/2013 nM NS 1.1 NS NS 1.1 0.83 NS NS NS 1.60 NS NS 10/28/2013 nM NS 0.61 NS NS 0.61 0.55 J NS NS NS 0.52 J 0.56 J 0.68 5/6/2014 nM NS 0.61 NS NS 0.82 1.1 J NS NS NS 1.1 J 0.61 3.50 10/23/2014 nM NS * 0.75 NS 0.86 0.85 NS NS NS 1.2 NS NS 5/21/2015 nM NS NS 1.7 NS 1.3 1.1 NS NS NS 1.6 1.6 1.2 12/8/2016 nM NS NS 2.0 NS 1.6 2.3 NS NS NS 1.9 NS NS Volatile Fatty Acids 11/3/2006 mg/L NS NS NS NS NS NS NS NS NS NS NI NI 6/3/2009 mg/L 10.9 NS NS NS 0.5 J ND NS NS NS ND ND ND 11/17/2009 mg/L 0.9 J NS NS NS ND 0.6 J NS NS NS ND 0.9 J ND 6/16/2010 mg/L ND NS NS NS 32.0 ND NS NS NS 1.3 0.8 J 5.2 12/1/2010 mg/L ND NU NS NS ND ND NS NS NS 6.4 J NS NS 6/1/2011 mg/L NS NU NS NS NS NS NS NS NS NS NS NS 12/20/2011 mg/L NS NS NS NS NS NS NS NS NS NS NS NS 5/30/2012 mg/L NS NS NS NS NS NS NS NS NS NS NS NS 12/5/2012 mg/L NS NS NS NS NS NS NS NS NS NS NS NS 6/12/2013 mg/L NS ND NS NS ND ND NS NS NS ND NS NS 10/28/2013 mg/L NS ND NS NS ND ND NS NS NS ND ND ND 5/6/2014 mg/L NS NS NS NS NS NS NS NS NS NS NS NS 10/23/2014 mg/L NS * NS NS NS NS NS NS NS NS NS NS 5/21/2015 mg/L NS NS NS NS NS NS NS NS NS NS NS NS 12/8/2015 mg/L NS NS NS NS NS NS NS NS NS NS NS NS TOC 11/3/2006 mg/L NS NS NS NS NS NS NS NS NS NS NI NI 6/3/2009 mg/L 9.4 NS NS NS 11.1 10.1 NS NS NS 17.8 8.6 14.2 11/17/2009 mg/L 2.1 NS NS NS 13.1 12.6 NS NS NS 14.6 3.9 11.4 6/16/2010 mg/L 24.9 NS NS NS 12.9 8.66 NS NS NS 11.1 6.4 16.8 12/1/2010 mg/L 17.6 NU NS NS 29.3 23.4 NS NS NS 43.8 NS NS 6/1/2011 mg/L NS NU NS NS NS NS NS NS NS NS NS NS 12/20/2011 mg/L NS 6.53 NS NS 13.6 12.2 NS NS NS 16.1 NS NS 5/30/2012 mg/L NS 6.49 NS NS 12.5 12.1 NS NS NS 14.5 6.55 10.90 12/5/2012 mg/L NS ND NS NS 13.1 13.1 NS NS NS 16.0 NS NS 6/12/2013 mg/L NS ND NS NS 13.3 12.9 NS NS NS 18.3 NS NS 10/28/2013 mg/L NS ND NS NS 15.3 12.9 NS NS NS 15.2 7.5 14.7 5/6/2014 mg/L NS ND NS NS 17.6 12.0 NS NS NS 19.9 9.54 11.3 10/23/2014 mg/L NS * 27.0 NS 35.7 66.4 NS NS NS 33.2 NS NS 5/21/2015 mg/L NS ND ND NS 4.410 4.580 NS NS NS 3.880 2.530 8.580 12/8/2016 mg/L NS ND ND NS 5.320 -- NS NS NS 6.070 NS NS Tetrachloroethene (PCE) 11/3/2006 µg/L ND NS NS App E ND ND 5.80 ND 5.70 ND NI NI 6/3/2009 µg/L 2.1 NS NS App E ND 0.70 J 7.5 NS NS ND ND ND 11/17/2009 µg/L 2.6 NS NS App E ND 0.49 J 6.3 NS NS ND ND ND 6/16/2010 µg/L 1.2 NS NS App E ND 0.46 J 6.7 NS NS ND ND ND 12/1/2010 µg/L 3.0 NU NS App E ND ND 5.8 NS NS ND NS NS 6/1/2011 µg/L 3.6 NU NS App E ND ND 7.7 NS NS ND ND ND 12/20/2011 µg/L NS ND NS App E 0.59 J 0.70 J 5.7 NS NS ND NS NS 5/30/2012 µg/L NS ND NS App E ND ND 7.7 NS NS ND ND ND 12/5/2012 µg/L NS ND NS App E ND ND 7.3 NS NS ND NS NS 6/12/2013 µg/L NS ND NS App E ND ND 6.4 NS NS ND NS NS 10/28/2013 µg/L NS ND NS App E ND ND 5.7 NS NS ND ND ND 5/6/2014 µg/L NS ND NS App E ND ND 7.3 NS NS ND ND ND 10/23/2014 µg/L NS * ND App E ND ND 7.0 NS 5.2 ND NS NS 5/21/2015 µg/L NS ND ND App E ND ND 6.4 NS 3.3 ND ND ND 12/8/2016 µg/L NS ND ND App E ND ND 5.6 NS 2.1 ND NS NS Burke County John's River C and D over MSW Landfill Permit No. 12-03 Page 4 of 6 Joyce Engineering TABLE 7: HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-14 MW-15S MW-16S MW-18 MW-19 Background Downgradient Sentinel Trichloroethene (TCE) 11/3/2006 µg/L ND NS NS App E ND ND 12.00 ND 5.40 ND NI NI 6/3/2009 µg/L 1.8 NS NS App E 3.6 4.3 12.1 NS NS 1.4 ND ND 11/17/2009 µg/L 1.9 NS NS App E 3.3 3.3 11.2 NS NS 1.2 ND ND 6/16/2010 µg/L 0.61 J NS NS App E 5.1 3.3 11.2 NS NS 1.4 ND ND 12/1/2010 µg/L 1.9 NU NS App E 3.7 3.3 9.3 NS NS ND NS NS 6/1/2011 µg/L 2.0 NU NS App E 2.8 3.2 11.4 NS NS ND ND ND 12/20/2011 µg/L NS ND NS App E 2.5 3.5 10.0 NS NS 1.1 NS NS 5/30/2012 µg/L NS ND NS App E 2.5 2.6 11.1 NS NS 0.55 J ND ND 12/5/2012 µg/L NS ND NS App E 2.3 3.3 11.2 NS NS 0.67 J NS NS 6/12/2013 µg/L NS ND NS App E 2.1 1.8 11.5 NS NS 0.76 J NS NS 10/28/2013 µg/L NS ND NS App E 3.1 2.5 10.7 NS NS 0.76 J ND ND 5/6/2014 µg/L NS ND NS App E 2.0 2.6 11.9 NS NS 0.60 J ND ND 10/23/2014 µg/L NS * ND App E 1.3 2.2 11.4 NS 3.4 0.86 J NS NS 5/21/2015 µg/L NS ND ND App E 0.9 J 2.3 10.1 NS 2.1 ND ND ND 12/8/2016 µg/L NS ND ND App E 0.71 J 1.4 9.7 NS 1.1 ND NS NS 1,2-Dichloroethene (Total) 11/3/2006 µg/L ND NS NS App E 16 12 12 ND ND 17 NI NI 6/3/2009 µg/L 0.71 J NS NS App E 13.3 12.1 25.6 NS NS 10.6 3.9 J ND 11/17/2009 µg/L 2.8 J NS NS App E 12.5 20.3 26.3 NS NS 11.1 NS NS 6/16/2010 µg/L 1.7 J NS NS App E 14.9 15.6 22.5 NS NS 9.9 4.5 J ND 12/1/2010 µg/L 0.66 J NU NS App E 11.5 9.3 20.0 NS NS 7.4 NS NS 6/1/2011 µg/L 0.66 J NU NS App E 14.6 13.9 29.1 NS NS 5.7 4.6 J ND 12/20/2011 µg/L NS ND NS App E 9.7 9.8 21.7 NS NS 6.6 NS NS 5/30/2012 µg/L NS ND NS App E 11.8 11.2 26.5 NS NS 6.8 ND ND 12/5/2012 µg/L NS ND NS App E 9.1 10.07 25.99 NS NS 6.6 NS NS 6/12/2013 µg/L NS ND NS App E 9.0 12.8 26.2 NS NS 6.2 NS NS 10/28/2013 µg/L NS ND NS App E 11.2 14.0 29.1 NS NS 7.7 NS NS 5/6/2014 µg/L NS ND NS App E 9.5 13.0 27.1 NS NS 7.7 NS NS 10/23/2014 µg/L NS * ND App E 8.0 10.1 25.0 NS ND 7.1 NS NS 5/21/2015 µg/L NS ND ND App E 6.7 7.6 17.0 NS ND 4.2 NS NS 12/8/2015 µg/L NS ND ND App E 0.65 J ND 1.3 NS ND 1.3 NS NS cis-1,2-Dichloroethene 11/3/2006 µg/L ND NS NS App E 16 12 12 ND ND 17 NI NI 6/3/2009 µg/L 0.71 J NS NS App E 13.1 11.9 25.3 NS NS 10.4 3.9 J ND 11/17/2009 µg/L 2.8 J NS NS App E 12.2 20.0 25.9 NS NS 10.8 5.7 ND 6/16/2010 µg/L 1.7 J NS NS App E 14.8 15.6 22.2 NS NS 9.7 4.5 J ND 12/1/2010 µg/L 0.66 J NU NS App E 11.3 9.2 19.7 NS NS 7.1 NS NS 6/1/2011 µg/L 0.66 J NU NS App E 14.5 13.8 28.8 NS NS 5.7 4.6 J ND 12/20/2011 µg/L NS ND NS App E 9.5 9.7 21.4 NS NS 6.5 NS NS 5/30/2012 µg/L NS ND NS App E 11.8 11.2 26.5 NS NS 6.8 ND ND 12/5/2012 µg/L NS ND NS App E 9.1 9.4 25.4 NS NS 6.6 NS NS 6/12/2013 µg/L NS ND NS App E 9.0 12.8 26.2 NS NS 6.2 NS NS 10/28/2013 µg/L NS ND NS App E 11.2 14.0 29.1 NS NS 7.7 NS NS 5/6/2014 µg/L NS ND NS App E 9.5 13.0 27.1 NS NS 7.7 NS NS 10/23/2014 µg/L NS * ND App E 8.0 10.1 25.0 NS ND 7.1 NS NS 5/21/2015 µg/L NS ND ND App E 6.7 7.6 17.0 NS NS 4.2 NS NS 12/8/2015 µg/L NS ND ND App E 6.9 9.9 25.8 NS NS 4.4 J NS NS Vinyl Chloride 11/3/2006 µg/L ND NS NS App E ND ND ND ND ND ND NI NI 6/3/2009 µg/L ND NS NS App E ND 0.95 J ND NS NS 2.0 ND ND 11/17/2009 µg/L 0.69 J NS NS App E 0.66 J 1.6 ND NS NS 2.5 ND ND 6/16/2010 µg/L ND NS NS App E ND 1.1 ND NS NS 2.1 ND ND 12/1/2010 µg/L ND NU NS App E 0.65 J 0.93 J ND NS NS 3.5 NS NS 6/1/2011 µg/L ND NU NS App E 0.87 J 1.1 ND NS NS 1.8 ND ND 12/20/2011 µg/L NS ND NS App E 0.63 J ND ND NS NS 1.4 NS NS 5/30/2012 µg/L NS ND NS App E ND ND ND NS NS 1.6 ND ND 12/5/2012 µg/L NS ND NS App E ND ND ND NS NS ND NS NS 6/12/2013 µg/L NS ND NS App E ND 0.96 J ND NS NS 2.10 NS NS 10/28/2013 µg/L NS ND NS App E ND 0.74 J ND NS NS 1.3 ND ND 5/6/2014 µg/L NS ND NS App E ND 0.77 J ND NS NS 1.8 ND ND 10/23/2014 µg/L NS * ND App E ND ND ND NS ND 1.3 NS NS 5/21/2015 µg/L NS ND ND App E ND ND ND NS ND 1.1 ND ND 12/8/2015 µg/L NS 0.72 J ND App E ND ND ND NS ND 1.4 NS NS 1,1,1-Trichloroethane 11/3/2006 µg/L ND NS NS App E ND ND ND ND ND ND NI NI 6/3/2009 µg/L ND NS NS App E ND ND 0.54 J NS NS ND ND ND 11/17/2009 µg/L ND NS NS App E ND ND ND NS NS ND ND ND 6/16/2010 µg/L ND NS NS App E ND ND ND NS NS ND ND ND 12/1/2010 µg/L ND NU NS App E ND ND ND NS NS ND NS NS 6/1/2011 µg/L ND NU NS App E ND ND ND NS NS ND ND ND 12/20/2011 µg/L NS ND NS App E ND ND ND NS NS ND NS NS 5/30/2012 µg/L NS ND NS App E ND ND ND NS NS ND ND ND 12/5/2012 µg/L NS ND NS App E ND ND ND NS NS ND NS NS 6/12/2013 µg/L NS ND NS App E ND ND ND NS NS ND NS NS 10/28/2013 µg/L NS ND NS App E ND ND ND NS NS ND NS NS 5/6/2014 µg/L NS ND NS App E ND ND ND NS NS ND NS NS 10/23/2014 µg/L NS * ND App E ND ND ND NS NS ND NS NS 5/21/2015 µg/L NS ND ND App E ND ND ND NS NS ND NS NS 12/8/2015 µg/L NS ND ND App E ND ND ND NS NS ND NS NS Burke County John's River C and D over MSW Landfill Permit No. 12-03 Page 5 of 6 Joyce Engineering TABLE 7: HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-14 MW-15S MW-16S MW-18 MW-19 Background Downgradient Sentinel 1,1-Dichloroethane 11/3/2006 µg/L ND NS NS App E 12 34 47 ND 35 33 NI NI 6/3/2009 µg/L 6.3 NS NS App E 8.2 47.8 53.1 NS NS 32.0 3.9 J 2.8 J 11/17/2009 µg/L 10.8 NS NS App E 6.7 41.9 52.0 NS NS 29.4 6.7 3.7 J 6/16/2010 µg/L 3.9 J NS NS App E 5.7 35.7 43.1 NS NS 32.1 4.4 J 2.3 J 12/1/2010 µg/L 6.8 NU NS App E 5.4 41.3 37.9 NS NS 16.9 NS NS 6/1/2011 µg/L 9.3 NU NS App E 6.8 45.5 53.3 NS NS 19.1 2.8 J 2.6 J 12/20/2011 µg/L NS ND NS App E 5.1 39.7 39.7 NS NS 26.2 NS NS 5/30/2012 µg/L NS ND NS App E 5.9 38.2 45.8 NS NS 24.1 1.6 J 2.7 J 12/5/2012 µg/L NS ND NS App E 4.6 J 39.3 39.3 NS NS 26.5 NS NS 6/12/2013 µg/L NS ND NS App E 5.3 37.1 41.6 NS NS 21.4 NS NS 10/28/2013 µg/L NS ND NS App E 4.6 J 43.2 41.8 NS NS 26.2 0.93 J 3.0 J 5/6/2014 µg/L NS ND NS App E 4.0 J 43.4 35.9 NS NS 21.5 1.2 J 2.9 J 10/23/2014 µg/L NS * ND App E 3.6 J 34.4 33.2 NS 4.9 J 25.3 NS NS 5/21/2015 µg/L NS ND ND App E 2.8 J 26.7 23.1 NS 2.4 J 17.3 ND 1.7 J 12/8/2015 µg/L NS ND ND App E 3.2 J 31.7 33.7 NS 2.2 J 10.3 NS NS Chloroethane 11/3/2006 µg/L ND NS NS App E ND ND ND ND 11.00 ND NI NI 6/3/2009 µg/L 1.1 J NS NS App E ND ND 4.0 J NS NS 4.4 J 4.3 J ND 11/17/2009 µg/L 3.1 J NS NS App E 0.63 J 5.5 J 5.1 J NS NS 3.5 J 2.9 J 0.90 J 6/16/2010 µg/L 1.7 J NS NS App E 0.88 J 3.1 J 4.5 J NS NS 2.2 J 2.6 J 0.80 J 12/1/2010 µg/L ND NU NS App E ND ND ND NS NS ND NS NS 6/1/2011 µg/L 1.5 J NU NS App E ND 2.7 J 3.8 J NS NS ND 3.6 J 0.85 J 12/20/2011 µg/L NS ND NS App E ND 2.1 J ND NS NS 2.9 J NS NS 5/30/2012 µg/L NS ND NS App E ND 1.5 J 2.4 J NS NS ND ND ND 12/5/2012 µg/L NS ND NS App E ND 1.8 J 2.7 J NS NS 1.9 J NS NS 6/12/2013 µg/L NS ND NS App E ND 0.63 J 0.84 J NS NS 1.5 J NS NS 10/28/2013 µg/L NS ND NS App E ND 1.9 J 2.3 J NS NS ND NS NS 5/6/2014 µg/L NS ND NS App E ND 1.6 J 1.7 J NS NS 1.3 J NS NS 10/23/2014 µg/L NS * ND App E ND ND 2.1 J NS ND 1.6 J NS NS 5/21/2015 µg/L NS ND ND App E ND ND 2.1 J NS NS 1.6 J NS NS 12/8/2015 µg/L NS ND ND App E ND ND ND NS NS ND NS NS Chloroform 11/3/2006 µg/L ND NS NS App E ND ND ND ND ND ND NI NI 6/3/2009 µg/L ND NS NS App E ND ND ND NS NS ND ND ND 11/17/2009 µg/L ND NS NS App E ND ND ND NS NS ND ND ND 6/16/2010 µg/L ND NS NS App E ND ND 0.21 J NS NS ND ND ND 12/1/2010 µg/L ND NU NS App E ND ND ND NS NS ND NS NS 6/1/2011 µg/L ND NU NS App E ND ND 0.36 J NS NS ND ND ND 12/20/2011 µg/L NS ND NS App E ND ND ND NS NS ND NS NS 5/30/2012 µg/L NS ND NS App E ND ND ND NS NS ND ND ND 12/5/2012 µg/L NS ND NS App E ND ND 0.14 J NS NS ND NS NS 6/12/2013 µg/L NS ND NS App E ND ND ND NS NS ND NS NS 10/28/2013 µg/L NS ND NS App E ND ND ND NS NS ND NS NS 5/6/2014 µg/L NS ND NS App E ND ND ND NS NS ND NS NS 10/23/2014 µg/L NS * ND App E ND ND ND NS ND ND NS NS 5/21/2015 µg/L NS ND ND App E ND ND ND NS NS ND NS NS 12/8/2015 µg/L NS ND ND App E ND ND ND NS NS ND NS NS Methylene Chloride 11/3/2006 µg/L ND NS NS App E ND ND 210.00 ND 100.00 ND NI NI 6/3/2009 µg/L ND NS NS App E ND ND 278 NS NS ND ND ND 11/17/2009 µg/L 11.1 NS NS App E ND ND 241 NS NS ND ND ND 6/16/2010 µg/L ND NS NS App E ND ND 234 NS NS ND ND ND 12/1/2010 µg/L 2.2 NU NS App E ND ND 174 NS NS ND NS NS 6/1/2011 µg/L 2.3 NU NS App E ND ND 232 NS NS ND ND ND 12/20/2011 µg/L NS ND NS App E ND ND 196 NS NS ND NS NS 5/30/2012 µg/L NS ND NS App E ND ND 185 NS NS ND ND ND 12/5/2012 µg/L NS ND NS App E ND ND 174 NS NS ND NS NS 6/12/2013 µg/L NS ND NS App E ND ND 77.9 NS NS ND NS NS 10/28/2013 µg/L NS ND NS App E ND ND 128 NS NS ND ND ND 5/6/2014 µg/L NS ND NS App E ND ND 154 NS NS ND ND ND 10/23/2014 µg/L NS * ND App E ND ND 130 NS ND ND NS NS 5/21/2015 µg/L NS ND ND App E ND ND 83 NS 4.4 ND ND ND 12/8/2015 µg/L NS ND ND App E ND ND 113 NS 2.6 B ND NS NS Notes: (FP) = Field Parameter ND = Not Detected NS = Not Sampled mV = millivolts S.U. = standard units oC = degrees Celcius mS/cm = microsiemens per centimeter mg/L = milligrams per liter (parts per million) µg/L = micrograms per liter (parts per billion NU = Not Used as background data until approved * MW-21 replaced MW-20 as the background well starting with the Fall 2014 sampling event; however MW-20 continues to be sampled as a compliance well for the C&D Expansion (Phase 1A). May 20, 2015: Shaded dissolved oxygen results are suspect. The DO Sensor began reading very low, re-calibration attempts did not appear to correct the issue. A short in the DO probe was diagnosed after the field event.-- MW-12 TOC sample for 12/08/15 was broken in transit to the laboratory and could not be analyzed. Burke County John's River C and D over MSW Landfill Permit No. 12-03 Page 6 of 6 Joyce Engineering TABLE 8: Biodegradation Screening Matrix Parameter Concentration Interpretation Possible Points Awarded Points Awarded in Plume Points with DP points without DP points Oxygen < 0.5 mg/L Tolerated, suppresses the reductive pathway at higher 3 0 0 concentrations > 5 mg/L Not tolerated; however, vinyl chloride may be oxidized -3 0 0 aerobically Nitrate < 1 mg/L At higher concentrations may compete with reductive 2 2 2 pathway Iron II (Ferrous Iron)> 1 mg/L Reductive pathway possible; vinyl chloride may be 3 3 3 oxidized under Fe (III) - reducing conditions Sulfate < 20 mg/L At higher concentrations may compete with reductive 2 2 2 pathway Sulfide > 1 mg/L Reductive pathway possible 3 NS (0)NS (0) Methane < 0.5 mg/L Vinyl chloride oxidizes 0 > 0.5 mg/L Ultimate reductive daughter product, vinyl chloride 3 3 0 accumulates Oxidation Reduction < 50 mV Reductive pathway possible 1 1 1 Potential < -100 mV Reductive pathway likely 2 pH 5 < pH < 9 Optimal range for reductive pathway 0 0 0 5 > pH > 9 Outside optimal range for reductive pathway -2 0 0 TOC > 20 mg/L Carbon and energy source; drives dechlorination; can 2 0 0 be natural or anthropogenic Temperature >20o C At T > 20 oC biochemical process is accelerated 10 0 Carbon Dioxide > 2x background Ultimate oxidative daughter product 1 NS (1)0 Alkalinity > 2x background Results from interaction between CO2 and 11 1 aquifer minerals Chloride > 2x background Daughter product of organic chlorine 2 2 2 Hydrogen > 1 nM Reductive pathway possible 3 3 3 < 1 nM Vinyl chloride oxidizes 0 Volatile Fatty Acids > 0.1 mg/L Intermediates resulting from biodegradation of more 2 NS (0)NS (0) complex compounds; carbon and energy source BTEX > 0.1 mg/L Carbon and energy source; drives dechlorination 2 0 0 Tetrachloroethene (PCE)--- Material released 0 0 0 Trichloroethene (TCE)--- Material released 0 0 0 --- Daughter product of PCE 2 2 0 Dichloroethenes (DCE)--- Material released 0 0 0 Daughter product of TCE 2 2 0 Dichloroethene, cis-1,2,--- Material released 0 0 0 --- Daughter product of trichlorethene 2 2 0 Vinyl Chloride (VC)--- Material released 0 0 0 --- Daughter product of DCE 2 2 0 1,1,1-Trichloroethane (TCA) --- Material released 0 0 0 1,1-Dichloroethane (DCA) --- Material released 0 0 0 Daughter product of TCA 2 2 0 Chloroethane --- Daughter product of dichloroethane or vinyl chloride under reducing conditions 2 0 0 Ethene/Ethane > 0.01 mg/L Daughter products of vinyl chloride/ethene 2 NS (0)NS (0) > 0.1 mg/L 3 NS (0)NS (0) Chloroform --- Material released 0 0 0 --- Daughter product of carbon tetrachloride 2 0 0 Dichloromethane (MC)--- Material released 0 0 0 (Methylene Chloride)--- Daughter product of chloroform 2 0 0 Based on samples collected on December 8, 2015.Total Points Awarded Excluding Historical Data: 27 14 Total Points Awarded Including Historical Data: 28 14 mg/L = miligrams per liter mV = millivolts NOTE: Chloroethane, Methane, TCE, DCE, cis-1,2-DCE, MC, VC, DCA, and CO2 are all present in the plume; however, nM = Nanometer it is uncertain whether these are primary leachate constituents or daughter products (DPs); therefore, we C = Celcius have two calculation columns. The first column assumes all of these are daughter products, and the NA = Not Analyzed second column assumes none of them are. The true score is probably between the two. BTEX = Sum of Benzene, Toluene, Ethylbenzene, and Total Xylenes NS (0) = Not sampled for this parameter, value in parenthsis is a score based on historical data.SCORE: Evid. of Nat. Atten. < 5 inadequate This screening matrix is prepared in general accordance with the United Stated Environmental Protection Agency's 6-14 limited (EPA's) Table 2.3 Analytical Parameters and Weighted for Preliminary Screening for Anaerobic Biodegradation 15-19 adequate Process presented in the EPA's Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents > 20 strong in Groundwater, September 1988. Burke Co. John's River Waste management Facility, Permit 12-03 C+D-over-MSW Landfill Joyce Engineering TABLE 9: COCs and LFG Parameters in Northeast Area Analyte Date MW-36 MW-38 MW-15S PZ-12 PZ-30S PZ-31 PZ-34 PZ-35 Benzene 18-Feb-13 8.0 3.8 ------ND ------ND 18-Jul-13 ---------------7.6 ND --- 10-Apr-14 ---6.6 ------------------ NC 2L = 1 µg/L (10/23/07)6-May-14 8.7 6.5 4.6 ---ND ND nle ND 20-Jun-14 ---5.5 ------------nle --- 17-Jul-14 ---4.6 ------------nle --- 22-Oct-14 8.3 5.9 3.3 ND ND ND nle ND 21-May-15 5.8 4.9 2.0 ND ND ND nle ND 8-Dec-15 ND 4.4 ND ND ND ND nle ND 1,4-Dichlorobenzene 18-Feb-13 18.0 7.8 ------ND ------ND 18-Jul-13 ---------------6.5 ND --- 10-Apr-14 ---13.9 ------------------ NC 2L = 6 µg/L (01/01/10)6-May-14 10.0 13.5 2.3 ---ND ND nle ND 20-Jun-14 ---9.9 ------------nle --- 17-Jul-14 ---13.0 ------------nle --- 22-Oct-14 15.2 12.9 1.6 ND ND ND nle ND 21-May-15 18.7 12.3 1.4 ND ND ND nle ND 8-Dec-15 ND 12.2 ND ND ND ND nle ND 1,1-Dichloroethane 18-Feb-13 7.9 9.1 ------ND ------ND 18-Jul-13 ---------------11.3 ND --- 10-Apr-14 ---8.6 ------------------ NC 2L = 6 µg/L (01/01/10)6-May-14 11.6 8.1 7.1 ---ND ND nle ND 20-Jun-14 ---8.0 ------------nle --- 17-Jul-14 ---5.7 ------------nle --- 22-Oct-14 9.0 6.9 4.9 J ND ND ND nle ND 21-May-15 4.8 J 5.5 2.4 J ND ND ND nle ND 8-Dec-15 ND 7.2 ND ND ND ND nle ND 1,2-Dichloroethane 18-Feb-13 1.0 0.59 J ------ND ------ND 18-Jul-13 ---------------0.54 J ND --- 10-Apr-14 ---0.77 J ---'--------------- NC 2L = 0.4 µg/L (01/01/10)6-May-14 0.78 J ND ND ---ND ND nle ND 20-Jun-14 ---0.63 J ------------nle --- 17-Jul-14 ---0.79 J ------------nle --- 22-Oct-14 0.92 J 0.63 J ND ND ND ND nle ND 21-May-15 ND ND ND ND ND ND nle ND 8-Dec-15 ND 0.70 J ND ND ND ND nle ND Tetrachloroethene 18-Feb-13 5.5 ND ------ND ------ND 18-Jul-13 ---------------7.8 ND --- 10-Apr-14 ---ND ------------------ NC 2L = 0.7 µg/L (10/23/07)6-May-14 7.9 ND 6.9 ---ND ND nle ND 20-Jun-14 ---ND ------------nle --- 17-Jul-14 ---ND ------------nle --- 22-Oct-14 7.3 ND 5.2 ND ND ND nle ND 21-May-15 6.0 ND 3.3 ND ND ND nle ND 8-Dec-15 ND ND ND ND ND ND nle ND Trichloroethene 18-Feb-13 3.6 2.7 ------ND ------ND 18-Jul-13 ---------------5.8 ND --- 10-Apr-14 ---2.7 ------------------ NC 2L = 3 µg/L (01/01/10)6-May-14 6.0 2.1 4.3 ---ND ND nle ND 20-Jun-14 ---2.2 ------------nle --- 17-Jul-14 ---2.5 ------------nle --- 22-Oct-14 5.1 1.8 3.4 ND ND ND nle ND 21-May-15 3.5 0.92 J 2.1 ND ND ND nle ND 8-Dec-15 ND 2.1 ND ND ND ND nle ND Vinyl chloride 18-Feb-13 1.2 ND ------ND ------ND 18-Jul-13 ---------------ND ND --- 10-Apr-14 ---ND ------------------ NC 2L = 0.03 µg/L (01/01/10)6-May-14 1.1 ND ND ---ND ND nle ND 20-Jun-14 ------------------nle --- 17-Jul-14 ------------------nle --- 22-Oct-14 0.87 J ND ND ND ND ND nle ND 21-May-15 ND ND ND ND ND ND nle ND 8-Dec-15 ND ND ND ND ND ND nle ND Methylene Chloride 18-Feb-13 17.9 ND ------ND ------ND 18-Jul-13 ---------------16.4 ND --- 10-Apr-14 '---ND ---'--------------- NC 2L = 5 µg/L (01/01/10)6-May-14 24.1 ND 16.7 ---ND ND nle ND 20-Jun-14 ---ND ------------nle --- 17-Jul-14 ---ND ------------nle --- 22-Oct-14 15.7 ND 1.6 ND ND ND nle ND 21-May-15 9.5 B ND 4.4 B ND ND ND nle ND 8-Dec-15 ND ND ND ND ND ND nle ND Methane 18-Feb-13 ------------------------ (Dissolved Methane)18-Jul-13 ------------------------ 10-Apr-14 ------------------------ 6-May-14 348 4,150 9,940 ---ND ND nle ND 20-Jun-14 ------------------nle --- 17-Jul-14 ------------------nle --- 22-Oct-14 8,450 6,820 13,000 ND ND ND nle ND 21-May-15 173 4,900 4,680 2.0 J 1.5 J 1.7 J nle 2.0 J 8-Dec-15 3,780 3,120 8,550 3.0 J 2.5 J 4.8 J nle 2.7 J Dissolved CO2 18-Feb-13 ------------------------ (Field Parameter)18-Jul-13 ------------------------ (Units are mg/L)10-Apr-14 ------------------------ 6-May-14 ------------------nle --- 20-Jun-14 ------------------nle --- 17-Jul-14 ------------------nle --- 22-Oct-14 180 ---105 20 20 20 nle 85 21-May-15 265 ---170 30 ---25 nle 35 8-Dec-15 235 ---110 25 10 5 nle 10 Notes: All concentrations in micrograms per liter (µg/L); except Dissolved CO2, which is in milligrams per liter (mg/L). DL = Laboratory Detection Limit. RL = SWSL = Solid Waste Section Reporting Limit.ND = Not Detected above the DL. NC 2L = Groundwater Standard from 15A NCAC 2L.0202.J = Estimated value (Concentration is less than the SWSL but greater than the DL). Values above the NC 2L Standard are bold.B = Blank-qualified (Analyte detected at similar concentration in field, trip, or method blank). MW-36 was converted from PZ-36. --- = Not reported or not sampled. MW-38 was converted from PZ-38. nle = No longer exists (MW-34 was destroyed during construciton activties). Burke Co., John's River C+D-over-MSW Landfill Permit # 12-03 Joyce Engineering TA B L E 1 0 : M e t h a n e G a s C o n c e n t r a t i o n s i n N o r t h e a s t A r e a Pr o b e / W e l l I D : GV - 1 G V - 2 G V - 3 G V - 4 G V - 5 G V - 6 G V - 7 G P - 2 S G P - 2 I G P - 2 D G P - 4 T G P - 0 1 T G P - 0 2 T G P - 0 3 T G P - 0 4 Sc r e e n e d I n t e r v a l ( F t - B G S ) : 5 - 2 5 . 5 5 - 3 5 5 - 4 3 5 - 4 3 5 - 4 5 5 - 4 7 5 - 3 6 4 - 1 3 1 4 - 2 8 2 9 - 3 5 5 - 2 5 9 . 0 - 2 9 . 0 7 . 0 - 2 7 . 0 7 . 5 - 2 7 . 5 6 . 0 - 3 6 . 0 De p t h t o G r o u n d w a t e r ( F t - B G S ) : Da t e 6- F e b - 1 2 ny i n y i n y i n y i n y i n y i n y i 70 . 0 6 9 . 0 7 3 . 0 ny i - - - - - - - - - - - - 31 - M a y - 1 2 ny i n y i n y i n y i n y i n y i n y i 77 . 0 7 3 . 0 7 7 . 0 ny i - - - - - - - - - - - - 30 - N o v - 1 2 n y i n y i n y i n y i n y i n y i n y i 6 0 . 4 6 0 . 2 6 0 . 6 n y i 1 6 . 3 2 2 . 3 8 . 3 3 4 . 2 18 - F e b - 1 3 n y i n y i n y i n y i n y i n y i n y i 4 6 . 0 4 9 . 0 4 9 . 0 n y i - - - - - - - - - - - - 11 - J u n - 1 3 n y i n y i n y i n y i n y i n y i n y i 4 3 . 0 4 3 . 0 4 3 . 0 n y i - - - - - - - - - - - - 21 - A u g - 1 3 n y i n y i n y i n y i n y i n y i n y i 6 0 . 9 6 0 . 2 6 0 . 8 n y i - - - - - - - - - - - - 30 - O c t - 1 3 n y i n y i n y i n y i n y i n y i n y i 5 6 . 4 5 7 . 7 5 7 . 1 n y i - - - - - - - - - - - - 10 - D e c - 1 3 5 7 . 2 6 2 . 3 6 5 . 8 5 9 . 3 5 3 . 7 - - - - - - 5 9 . 9 5 8 . 7 5 9 . 4 n y i 0 . 0 1 9 . 7 2 6 . 1 5 4 . 2 10 - F e b - 1 4 5 9 . 1 6 3 . 2 6 4 . 7 6 0 . 8 5 5 . 2 5 8 . 1 5 6 . 9 5 7 . 1 6 0 . 2 5 9 . 8 n y i - - - - - - - - - - - - 9- A p r - 1 4 5 8 . 0 5 7 . 9 5 7 . 9 6 2 . 5 5 9 . 9 2 7 . 9 1 . 1 5 8 . 2 5 8 . 2 5 8 . 0 n y i 4 5 . 6 3 3 . 7 3 3 . 8 3 3 . 3 27 - A u g - 1 4 5 7 . 7 5 9 . 1 5 8 . 5 6 2 . 3 6 0 . 0 5 9 . 3 4 0 . 5 5 6 . 9 5 8 . 1 5 8 . 3 n y i 3 1 . 5 1 6 . 8 n l e 6 7 . 8 22 - O c t - 1 4 6 3 . 3 6 5 . 1 6 4 . 8 6 6 . 1 6 0 . 4 6 5 . 6 2 8 . 5 6 2 . 5 6 2 . 8 6 3 . 0 6 2 . 2 2 3 . 9 9 . 8 n l e 5 0 . 9 30 - M a r - 1 5 6 1 . 4 6 2 . 9 6 2 . 8 6 2 . 9 6 2 . 0 6 3 . 1 1 6 . 2 6 2 . 0 6 1 . 7 6 1 . 6 4 1 . 7 3 6 . 4 2 7 . 7 n l e 5 4 . 2 21 - M a y - 1 5 5 6 . 4 5 7 . 4 5 7 . 3 5 9 . 8 5 7 . 3 5 6 . 8 3 4 . 4 5 5 . 2 5 5 . 8 5 5 . 9 5 5 . 4 3 6 . 0 2 2 . 8 n l e 6 2 . 2 16 - J u l - 1 5 5 8 . 4 6 0 . 5 6 0 . 4 6 2 . 8 6 0 . 8 6 0 . 2 3 1 . 1 5 6 . 2 5 7 . 9 5 8 . 1 5 6 . 2 1 9 . 1 6 . 8 n l e 3 6 . 1 9- D e c - 1 5 5 9 . 6 6 0 . 3 6 0 . 1 6 1 . 8 5 9 . 0 6 0 . 8 4 0 . 1 5 9 . 9 5 8 . 5 5 7 . 9 5 7 . 7 2 8 . 7 6 . 8 n l e 8 3 . 6 19 - F e b - 1 6 6 0 . 0 6 0 . 1 6 0 . 2 6 1 . 2 5 9 . 4 6 0 . 2 4 1 . 1 60 . 1 5 8 . 6 5 8 . 1 5 2 . 1 45 . 2 1 6 . 1 n l e 3 0 . 3 Pr o b e / W e l l I D : TG P - 0 5 T G P - 0 6 T G P - 0 7 T G P - 0 8 T G P - 0 9 T G P - 1 0 M W - 1 5 S M W - 1 7 M W - 3 6 M W - 3 8 P Z - 1 7 P Z - 3 0 S P Z - 3 1 P Z - 3 4 P Z - 3 5 Sc r e e n e d I n t e r v a l ( F t - B G S ) : 7 . 0 - 3 2 . 0 5 . 5 - 2 5 . 5 8 . 0 - 2 8 . 0 8 . 5 - 2 8 . 5 5 . 0 - 3 5 . 0 6 . 0 - 3 6 . 0 3 9 - 5 4 3 7 - 4 2 2 8 - 4 3 4 0 - 7 0 2 0 - 3 5 3 7 - 5 2 2 5 - 4 0 2 7 - 4 7 1 5 - 3 5 De p t h t o G r o u n d w a t e r ( F t - B G S ) : 43 . 7 4 4 0 . 1 6 3 1 . 1 0 4 0 . 6 7 3 3 . 0 0 4 1 . 0 0 2 7 . 5 9 3 4 . 9 0 2 1 . 7 0 Da t e 6- F e b - 1 2 -- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 31 - M a y - 1 2 -- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 30 - N o v - 1 2 0 . 1 1 1 . 0 0 . 0 0 . 0 5 . 9 0 . 0 1 9 . 9 0 . 5 4 4 . 3 4 8 . 2 - - - - - - 0 . 1 0 . 1 - - - 18 - F e b - 1 3 - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 11 - J u n - 1 3 - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 21 - A u g - 1 3 - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 30 - O c t - 1 3 - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 10 - D e c - 1 3 0 . 0 0 . 0 0 . 0 0 . 0 2 7 . 2 0 . 0 0 . 0 0 . 4 1 2 . 0 0 . 0 0 . 0 0 . 0 0 . 0 0 . 0 10 - F e b - 1 4 - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 9- A p r - 1 4 0 . 0 2 9 . 5 0 . 0 0 . 0 1 0 . 0 0 . 1 - - - - - - 0 . 4 0 . 5 0 . 0 0 . 0 0 . 0 n l e 0 . 0 27 - A u g - 1 4 0 . 0 2 1 . 7 0 . 0 0 . 0 1 8 . 7 0 . 0 - - - - - - 5 7 . 6 0 . 0 3 . 8 0 . 0 0 . 0 n l e 0 . 0 22 - O c t - 1 4 0 . 0 0 . 0 0 . 0 0 . 0 0 . 0 0 . 0 - - - - - - 4 2 . 6 2 . 2 - - - 0 . 0 0 . 0 n l e 0 . 0 30 - M a r - 1 5 0 . 0 n l e 0 . 0 0 . 0 1 4 . 9 0 . 0 - - - - - - 5 1 . 9 0 . 0 - - - 0 . 0 0 . 0 n l e 1 . 0 21 - M a y - 1 5 0 . 1 n l e 0 . 1 0 . 0 1 7 . 6 0 . 0 - - - - - - 4 2 . 3 5 . 0 - - - 0 . 0 0 . 0 n l e 0 . 0 16 - J u l - 1 5 0 . 0 n l e 0 . 1 5 . 2 0 . 0 0 . 0 - - - - - - 4 8 . 5 1 0 . 7 - - - 0 . 0 0 . 0 n l e 0 . 0 9- D e c - 1 5 0 . 0 n l e 0 . 1 0 . 0 1 8 . 3 0 . 0 - - - - - - 5 7 . 3 8 . 7 - - - 0 . 0 0 . 0 n l e 0 . 0 19 - F e b - 1 6 0 . 0 n l e 0 . 1 0 . 0 6 . 1 0 . 0 - - - - - - 1 6 . 8 4 3 . 8 - - - 0 . 0 0 . 0 n l e 0 . 0 NO T E S : GV = G a s V e n t . ny i = N o t y e t i n s t a l l e d . GP = P e r m a n e n t G a s M o n i t o r i n g P r o b e . n l e = N o l o n g e r e x i s t s . TG P = T e m p o r a r y G a s M o n i t o r i n g P r o b e . - - - = n o t m o n i t o r e d . MW = M o n i t o r i n g W e l l . Ft - B G S = F e e t b e l o w g r o u n d s u r f a c e . PZ = P i e z o m e t e r . Me t h a n e ( C H 4 ) C o n c e n t r a t i o n ( % b y V o l u m e ) Me t h a n e ( C H 4 ) C o n c e n t r a t i o n ( % b y V o l u m e ) Bu r k e C o . , J o h n ' s R i v e r C + D - o v e r - M S W L a n d f i l l Pe r m i t # 1 2 - 0 3 P: \ B u r k e  Co u n t y \ J o h n ' s  Ri v e r  Wa s t e  Ma n a g e m e n t  Fa c i l i t y \ G r o u n d w a t e r \ C A E R \ 2 0 1 6  CA E R \ T a b l e s \ H i s t r o i c a l  Me t h a n e  in  NE  Ar e a . x l s x Joyce Engineering CHARTS Chart 1 Benzene Concentrations vs. Time Chart 2 1,4-Dichlorobenzene (1,4-DCB) Concentrations vs. Time Chart 3 1,1-Dichloroethane (1,1-DCA) Concentrations vs. Time Chart 4 1,2-Dichloroethane (1,2-DCA) Concentrations vs. Time Chart 5 Tetrachloroethylene (PCE) Concentrations vs. Time Chart 6 Trichloroethylene (TCE) Concentrations vs. Time Chart 7 Vinyl Chloride (VC) Concentrations vs. Time Chart 8 Methylene Chloride Concentrations vs. Time Chart 9 alpha-BHC Concentrations vs. Time Chart 10 beta-BHC Concentrations vs. Time Chart 11 Methane Gas vs. Time Jo h n ' s  Ri v e r  La n d f i l l ,  Bu r k e  Co . Pe r m i t  12 ‐03 Joyce  Engineering 024681012141618 M a y ‐ 9 6 N o v ‐ 9 6 M a y ‐ 9 7 N o v ‐ 9 7 M a y ‐ 9 8 N o v ‐ 9 8 M a y ‐ 9 9 N o v ‐ 9 9 M a y ‐ 0 0 N o v ‐ 0 0 M a y ‐ 0 1 N o v ‐ 0 1 M a y ‐ 0 2 N o v ‐ 0 2 M a y ‐ 0 3 N o v ‐ 0 3 M a y ‐ 0 4 N o v ‐ 0 4 M a y ‐ 0 5 N o v ‐ 0 5 M a y ‐ 0 6 N o v ‐ 0 6 M a y ‐ 0 7 N o v ‐ 0 7 M a y ‐ 0 8 N o v ‐ 0 8 M a y ‐ 0 9 N o v ‐ 0 9 M a y ‐ 1 0 N o v ‐ 1 0 M a y ‐ 1 1 N o v ‐ 1 1 M a y ‐ 1 2 N o v ‐ 1 2 M a y ‐ 1 3 Nov‐13 May‐14 Nov‐14 May‐15 Nov‐15 C o n c e n t r a t i o n     ( µ g / l ) Ch a r t  1:    Be n z e n e  Co n c e n t r a t i o n  vs .  Ti m e  in  Do w n g r a d i e n t  We l l s MW ‐10 MW ‐11 MW ‐12 MW ‐13 MW ‐16S GPS Jo h n ' s  Ri v e r  La n d f i l l ,  Bu r k e  Co . Pe r m i t  12 ‐03 Joyce  Engineeirng 0510152025 M a y ‐ 9 4 N o v ‐ 9 4 M a y ‐ 9 5 N o v ‐ 9 5 M a y ‐ 9 6 N o v ‐ 9 6 M a y ‐ 9 7 N o v ‐ 9 7 M a y ‐ 9 8 N o v ‐ 9 8 M a y ‐ 9 9 N o v ‐ 9 9 M a y ‐ 0 0 N o v ‐ 0 0 M a y ‐ 0 1 N o v ‐ 0 1 M a y ‐ 0 2 N o v ‐ 0 2 M a y ‐ 0 3 N o v ‐ 0 3 M a y ‐ 0 4 N o v ‐ 0 4 M a y ‐ 0 5 N o v ‐ 0 5 M a y ‐ 0 6 N o v ‐ 0 6 M a y ‐ 0 7 N o v ‐ 0 7 M a y ‐ 0 8 N o v ‐ 0 8 M a y ‐ 0 9 N o v ‐ 0 9 M a y ‐ 1 0 N o v ‐ 1 0 M a y ‐ 1 1 N o v ‐ 1 1 M a y ‐ 1 2 N o v ‐ 1 2 M a y ‐ 1 3 Nov‐13 May‐14 Nov‐14 May‐15 Nov‐15 C o n c e n t r a t i o n     ( µ g / l ) Ch a r t  2:    1, 4 ‐Di c h l o r o b e n z e n e  Co n c e n t r a t i o n  vs .  Ti m e  in  Do w n g r a d i e n t  We l l s MW ‐10 MW ‐11 MW ‐12 MW ‐13 MW ‐16S GPS Jo h n ' s  Ri v e r  La n d f i l l ,  Bu r k e  Co . Pe r m i t  12 ‐03 Joyce  Engineering 050 10 0 15 0 20 0 25 0 30 0 M a y ‐ 9 4 N o v ‐ 9 4 M a y ‐ 9 5 N o v ‐ 9 5 M a y ‐ 9 6 N o v ‐ 9 6 M a y ‐ 9 7 N o v ‐ 9 7 M a y ‐ 9 8 N o v ‐ 9 8 M a y ‐ 9 9 N o v ‐ 9 9 M a y ‐ 0 0 N o v ‐ 0 0 M a y ‐ 0 1 N o v ‐ 0 1 M a y ‐ 0 2 N o v ‐ 0 2 M a y ‐ 0 3 N o v ‐ 0 3 M a y ‐ 0 4 N o v ‐ 0 4 M a y ‐ 0 5 N o v ‐ 0 5 M a y ‐ 0 6 N o v ‐ 0 6 M a y ‐ 0 7 N o v ‐ 0 7 M a y ‐ 0 8 N o v ‐ 0 8 M a y ‐ 0 9 N o v ‐ 0 9 M a y ‐ 1 0 N o v ‐ 1 0 M a y ‐ 1 1 N o v ‐ 1 1 M a y ‐ 1 2 N o v ‐ 1 2 M a y ‐ 1 3 Nov‐13 May‐14 Nov‐14 May‐15 Nov‐15 C o n c e n t r a t i o n     ( µ g / l ) Ch a r t  3:    1, 1 ‐Di c h l o r o e t h a n e  vs .  Ti m e  in  Do w n g r a d i e n t  We l l s MW ‐10 MW ‐11 MW ‐12 MW ‐13 MW ‐16S GPS Jo h n ' s  Ri v e r  La n d f i l l ,  Bu r k e  Co . Pe r m i t  12 ‐03 Joyce  Engineering 02468101214 N o v ‐ 0 5 M a y ‐ 0 6 N o v ‐ 0 6 M a y ‐ 0 7 N o v ‐ 0 7 M a y ‐ 0 8 N o v ‐ 0 8 M a y ‐ 0 9 N o v ‐ 0 9 M a y ‐ 1 0 N o v ‐ 1 0 M a y ‐ 1 1 N o v ‐ 1 1 M a y ‐ 1 2 N o v ‐ 1 2 M a y ‐ 1 3 N o v ‐ 1 3 M a y ‐ 1 4 Nov‐14 May‐15 Nov‐15 C o n c e n t r a t i o n     ( µ g / l ) Ch a r t  4:    1, 2 ‐Di c h l o r o e t h a n e  vs .  Ti m e  in  Do w n g r a d i e n t  We l l s MW ‐10 MW ‐11 MW ‐12 MW ‐13 MW ‐16S GPS Jo h n ' s  Ri v e r  La n d f i l l ,  Bu r k e  Co . Pe r m i t  12 ‐03 Joyce  Engineering 02468101214 M a y ‐ 9 7 N o v ‐ 9 7 M a y ‐ 9 8 N o v ‐ 9 8 M a y ‐ 9 9 N o v ‐ 9 9 M a y ‐ 0 0 N o v ‐ 0 0 M a y ‐ 0 1 N o v ‐ 0 1 M a y ‐ 0 2 N o v ‐ 0 2 M a y ‐ 0 3 N o v ‐ 0 3 M a y ‐ 0 4 N o v ‐ 0 4 M a y ‐ 0 5 N o v ‐ 0 5 M a y ‐ 0 6 N o v ‐ 0 6 M a y ‐ 0 7 N o v ‐ 0 7 M a y ‐ 0 8 N o v ‐ 0 8 M a y ‐ 0 9 N o v ‐ 0 9 M a y ‐ 1 0 N o v ‐ 1 0 M a y ‐ 1 1 N o v ‐ 1 1 M a y ‐ 1 2 N o v ‐ 1 2 M a y ‐ 1 3 N o v ‐ 1 3 May‐14 Nov‐14 May‐15 Nov‐15 C o n c e n t r a t i o n     ( µ g / l ) Ch a r t  5:    Te t r a c h l o r o e t h e n e  vs .  Ti m e  in  Do w n g r a d i e n t  We l l s MW ‐10 MW ‐11 MW ‐12 MW ‐13 MW ‐16S GPS Jo h n ' s  Ri v e r  La n d f i l l ,  Bu r k e  Co . Pe r m i t  12 ‐03 Joyce  Engineering 02468101214161820 M a y ‐ 9 4 N o v ‐ 9 4 M a y ‐ 9 5 N o v ‐ 9 5 M a y ‐ 9 6 N o v ‐ 9 6 M a y ‐ 9 7 N o v ‐ 9 7 M a y ‐ 9 8 N o v ‐ 9 8 M a y ‐ 9 9 N o v ‐ 9 9 M a y ‐ 0 0 N o v ‐ 0 0 M a y ‐ 0 1 N o v ‐ 0 1 M a y ‐ 0 2 N o v ‐ 0 2 M a y ‐ 0 3 N o v ‐ 0 3 M a y ‐ 0 4 N o v ‐ 0 4 M a y ‐ 0 5 N o v ‐ 0 5 M a y ‐ 0 6 N o v ‐ 0 6 M a y ‐ 0 7 N o v ‐ 0 7 M a y ‐ 0 8 N o v ‐ 0 8 M a y ‐ 0 9 N o v ‐ 0 9 M a y ‐ 1 0 N o v ‐ 1 0 M a y ‐ 1 1 N o v ‐ 1 1 M a y ‐ 1 2 N o v ‐ 1 2 M a y ‐ 1 3 Nov‐13 May‐14 Nov‐14 May‐15 Nov‐15 C o n c e n t r a t i o n     ( µ g / l ) Ch a r t  6:    Tr i c h l o r o e t h e n e  vs .  Ti m e  in  Do w n g r a d i e n t  We l l s MW ‐10 MW ‐11 MW ‐12 MW ‐13 MW ‐16S GPS Jo h n ' s  Ri v e r  La n d f i l l ,  Bu r k e  Co . Pe r m i t  12 ‐03 Joyce  Engineering 0 0. 5 1 1. 5 2 2. 5 3 3. 5 4 M a y ‐ 0 7 N o v ‐ 0 7 M a y ‐ 0 8 N o v ‐ 0 8 M a y ‐ 0 9 N o v ‐ 0 9 M a y ‐ 1 0 N o v ‐ 1 0 M a y ‐ 1 1 N o v ‐ 1 1 M a y ‐ 1 2 N o v ‐ 1 2 M a y ‐ 1 3 N o v ‐ 1 3 M a y ‐ 1 4 N o v ‐ 1 4 May‐15 Nov‐15 C o n c e n t r a t i o n     ( µ g / l ) Ch a r t  7:    Vi n y l  Ch l o r i d e  vs .  Ti m e  in  Do w n g r a d i e n t  We l l s MW ‐10 MW ‐11 MW ‐12 MW ‐13 MW ‐16S GPS Jo h n ' s  Ri v e r  La n d f i l l ,  Bu r k e  Co . Pe r m i t  12 ‐03 Joyce  Engineering 0 10 0 20 0 30 0 40 0 50 0 60 0 70 0 80 0 90 0 M a y ‐ 9 4 N o v ‐ 9 4 M a y ‐ 9 5 N o v ‐ 9 5 M a y ‐ 9 6 N o v ‐ 9 6 M a y ‐ 9 7 N o v ‐ 9 7 M a y ‐ 9 8 N o v ‐ 9 8 M a y ‐ 9 9 N o v ‐ 9 9 M a y ‐ 0 0 N o v ‐ 0 0 M a y ‐ 0 1 N o v ‐ 0 1 M a y ‐ 0 2 N o v ‐ 0 2 M a y ‐ 0 3 N o v ‐ 0 3 M a y ‐ 0 4 N o v ‐ 0 4 M a y ‐ 0 5 N o v ‐ 0 5 M a y ‐ 0 6 N o v ‐ 0 6 M a y ‐ 0 7 N o v ‐ 0 7 M a y ‐ 0 8 N o v ‐ 0 8 M a y ‐ 0 9 N o v ‐ 0 9 M a y ‐ 1 0 N o v ‐ 1 0 M a y ‐ 1 1 N o v ‐ 1 1 M a y ‐ 1 2 N o v ‐ 1 2 M a y ‐ 1 3 Nov‐13 May‐14 Nov‐14 May‐15 Nov‐15 C o n c e n t r a t i o n     ( µ g / l ) Ch a r t  8:    Me t h y l e n e  Ch l o r i d e  vs .  Ti m e  in  Do w n g r a d i e n t  We l l s MW ‐10 MW ‐11 MW ‐12 MW ‐13 MW ‐16S GPS Jo h n ' s  Ri v e r  La n d f i l l ,  Bu r k e  Co . Pe r m i t  12 ‐03   Joyce  Engineering 0 0. 0 2 0. 0 4 0. 0 6 0. 0 8 0. 1 0. 1 2 0. 1 4 0. 1 6 0. 1 8 0. 2 M a y ‐ 9 6 N o v ‐ 9 6 M a y ‐ 9 7 N o v ‐ 9 7 M a y ‐ 9 8 N o v ‐ 9 8 M a y ‐ 9 9 N o v ‐ 9 9 M a y ‐ 0 0 N o v ‐ 0 0 M a y ‐ 0 1 N o v ‐ 0 1 M a y ‐ 0 2 N o v ‐ 0 2 M a y ‐ 0 3 N o v ‐ 0 3 M a y ‐ 0 4 N o v ‐ 0 4 M a y ‐ 0 5 N o v ‐ 0 5 M a y ‐ 0 6 N o v ‐ 0 6 M a y ‐ 0 7 N o v ‐ 0 7 M a y ‐ 0 8 N o v ‐ 0 8 M a y ‐ 0 9 N o v ‐ 0 9 M a y ‐ 1 0 N o v ‐ 1 0 M a y ‐ 1 1 N o v ‐ 1 1 M a y ‐ 1 2 N o v ‐ 1 2 M a y ‐ 1 3 N o v ‐ 1 3 May‐14 Nov‐14 May‐15 Nov‐15 C o n c e n t r a t i o n     ( µ g / l ) Ch a r t  9:    al p h a ‐BH C  vs .  Ti m e  in  Do w n g r a d i e n t  We l l s MW ‐10 MW ‐11 MW ‐12 MW ‐13 MW ‐16S GPS Jo h n ' s  Ri v e r  La n d f i l l ,  Bu r k e  Co . Pe r m i t  12 ‐03 Joyce  Engineering 0 0. 0 5 0. 1 0. 1 5 0. 2 0. 2 5 0. 3 0. 3 5 N o v ‐ 1 0 M a y ‐ 1 1 N o v ‐ 1 1 M a y ‐ 1 2 N o v ‐ 1 2 M a y ‐ 1 3 N o v ‐ 1 3 M a y ‐ 1 4 N o v ‐ 1 4 M a y ‐ 1 5 Nov‐15 C o n c e n t r a t i o n     ( µ g / l ) Ch a r t  10 :    be t a ‐BH C  vs .  Ti m e  in  Do w n g r a d i e n t  We l l s MW ‐10 MW ‐11 MW ‐12 MW ‐13 MW ‐16S GPS Bu r k e  Co . ,  Jo h n ' s  Ri v e r  C+ D ‐ov e r ‐MS W  La n d f i l l Pe r m i t  # 12 ‐03 Joyce  Engineering 0. 0 10 . 0 20 . 0 30 . 0 40 . 0 50 . 0 60 . 0 70 . 0 80 . 0 90 . 0 J a n ‐ 1 0 M a r ‐ 1 0 M a y ‐ 1 0 J u l ‐ 1 0 S e p ‐ 1 0 N o v ‐ 1 0 J a n ‐ 1 1 M a r ‐ 1 1 M a y ‐ 1 1 J u l ‐ 1 1 S e p ‐ 1 1 N o v ‐ 1 1 J a n ‐ 1 2 M a r ‐ 1 2 M a y ‐ 1 2 J u l ‐ 1 2 S e p ‐ 1 2 N o v ‐ 1 2 J a n ‐ 1 3 M a r ‐ 1 3 M a y ‐ 1 3 J u l ‐ 1 3 S e p ‐ 1 3 N o v ‐ 1 3 J a n ‐ 1 4 M a r ‐ 1 4 M a y ‐ 1 4 J u l ‐ 1 4 S e p ‐ 1 4 N o v ‐ 1 4 J a n ‐ 1 5 M a r ‐ 1 5 M a y ‐ 1 5 Jul‐15 Sep‐15 Nov‐15 Jan‐16 M e t h a n e   C o n c e n t r a t i o n     ( %   b y   V o l u m e ) Ch a r t  11 :      Me t h a n e  Ga s  Co n c e n t r a t i o n s  vs .  Ti m e GP ‐2S GP ‐2I GP ‐2D GP ‐4 MW ‐15S MW ‐36 MW ‐38 TGP ‐01 TGP ‐02 TGP ‐03 TGP ‐04 TGP ‐06 TGP ‐08 TGP ‐09 Ga s  Ve n t s  In s t a l l e d No v e m b e r    20 1 3 GP  = Ga s  Pr o b e MW  = Mo n i t o r i n g  We l l TG P  = Te m p o r a r y  Ga s  Pr o b e FIGURE Figure 1: Site Location Map DRAWINGS Drawing 1 Groundwater Surface Map Drawing 2 Benzene Isoconcentration Map Drawing 3 1,4-Dichlorobenzene (1,4-DCB) Isoconcentration Map Drawing 4 1,1-Dichloroethane (1,1-DCA) Isoconcentration Map Drawing 5 1,2-Dichloroethane (1,2-DCA) Isoconcentration Map Drawing 6 Tetrachloroethylene (PCE) Isoconcentration Map Drawing 7 Trichloroethylene (TCE) Isoconcentration Map Drawing 8 Vinyl Chloride Isoconcentration Map Drawing 9 Methylene Chloride Isoconcentration Map Drawing 10 beta-BHC Isoconcentration Map Drawing 11 Total VOCs Isoconcentration Map Drawing 12 Total VOCs Cross-Sections Drawing 13 Methane Gas Plume Map SMP-5 SURFACE MONITORING POINT LOCATION AND IDENTIFICATION NOT MEASURED LEGEND PROPERTY LINE EXISTING ROAD EXISTING 25' TOPOGRAPHIC CONTOUR EXISTING 2' TOPOGRAPHIC CONTOUR GROUNDWATER SURFACE CONTOUR [FEET ABOVE MEAN SEA LEVEL (AMSL)] APPROXIMATE LIMITS OF WASTE CENTERLINE OF STREAM GAS PROBE LOCATION AND IDENTIFICATION PIEZOMETER LOCATION AND IDENTIFICATION COMPLIANCE WELL LOCATION AND IDENTIFICATION WITH STATIC WATER LEVEL ELEVATION (FEET AMSL) (NM) GP 1050 1020 MW-13 1009.64 PZ-9D GMP-3 TOPOGRAPHIC CONTOUR INTERVAL = 2 AND 10 FEET. GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET. STATIC WATER LEVELS WERE MEASURED ON DECEMBER 9,2015. GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION BETWEEN AND EXTRAPOLATION FROM KNOWN DATA, TOPOGRAPHIC CONTOURS, AND KNOWN FIELD CONDITIONS. MW-16D GROUNDWATER ELEVATION WAS NOT USED IN CALCULATING GROUNDWATER CONTOURS. NOTES EXISTING 5' TOPOGRAPHIC CONTOUR EXISTING 10' TOPOGRAPHIC CONTOUR1080 T1 TEMPORARY WELL APPROXIMATE LOCATION OF SPRING HEAD 1. 2. 3. 4. 5. JE-0020 CONTROL POINT LOCATION AND IDENTIFICATION SENTINEL WELL LOCATION AND IDENTIFICATION WITH STATIC WATER LEVEL ELEVATION (FEET AMSL) MW-18 GROUNDWATER FLOW PATHWAY USED TO CALCULATE HYDRAULIC GRADIENT 1 SEGMENT USED FOR GRADIENT CALCULATION ABANDONED OR UNUSED MONITORING WELL i i i FLOW PATH LENGTH 967 LF 1,495 LF 1,098 LF 770 LFi 1 0 0 0 1 0 1 0 1 0 2 0 1 0 3 0 1 0 4 0 1 0 5 0 1 0 6 0 1 0 7 0 1 0 8 0 1 0 9 0 1 1 0 0 1 1 1 0 1 1 2 0 1 1 3 0 1 1 4 0 1 1 5 0 1 1 6 0 1 1 5 0 1 1 4 0 1 1 3 0 1 1 2 0 1 1 1 0 1 1 0 0 1 0 9 0 1 0 8 0 1 1 7 0 108 0 1 0 7 0 1 0 6 0 1 0 5 0 1 0 4 0 105 0 10 0 0 10 6 0 10 5 0 10 4 0 10 3 0 10 2 0 1010 1000 10 7 0 4 (ABANDONED) PZ-2S (ABANDONED) PZ-2D (NM) PZ-23 (NM) PZ-15 (NM) PZ-22D 1042.60 PZ-22S (NM) PZ-16S 1017.69 PZ-12 (NM)PZ-27 (NM) PZ-14 (NM) PZ-13 (ND)PZ-9D (NM) PZ-9S1009.64 MW-13 SMP-6 993.42 MW-12 992.25 MW-11 995.17 MW-16D 994.47 MW-16S 999.49 MW-10 SMP-5 MW-9 (NM)MW-14 1025.19 MW-15S (NM) MW-15D (NM)MW-8 (NM) MW-1 (FORMERLY PZ-4) MW-20 NM MW-17 SHOOTING RANGE MULCHING AREA L O W E R C R E E K JOH N S R I V E R CATAW B A R I V E R WETLAND EXISTING TRAIL TRANSFER FACILITY EXISTING SEDIMENT BASIN EXISTING C&D DISPOSAL AREA CURRENT BACKGROUND WELL FORMER MW-18 MW-19 OFFICE AND GARAGE MW-38 1046.24 MW-36 1066.72 PZ-30S 1045.57 PZ-30D PZ-31 1058.70 PZ-35 1063.39 BACKGROUND WELL CURRENT PHASE 1A LIMITS PROJECT NO. AP P R O V E D CH E C K E D DR A W N DE S I G N E D DA T E DA T E RE V I S I O N S A N D R E C O R D O F I S S U E BY N O A P P C K SCALE A l l r i g h t s r e s e r v e d . ” J o y c e E n g i n e e r i n g , I n c . DRAWING NO. L: \ B u r k e C o u n t y \ 2 0 1 6 c o n s t i t u e n t s m a p s \ 1 - G W - E V E N T 1 2 - 1 5 . D W G L a y o u t = S H T 0 1 22 1 1 W . M E A D O W V I E W R O A D GR E E N S B O R O , N C 2 7 4 0 7 PH O N E : ( 3 3 6 ) 3 2 3 - 0 0 9 2 277 JO H N S R I V E R , W A S T E M A N A G E M E N T F A C I L I T Y BU R K E C O U N T Y , N O R T H C A R O L I N A 20 1 6 1 AS NOTED GR O U N D W A T E R P O T E N T I O M E T R I C S U R F A C E M A P DE C E M B E R 9 , 2 0 1 5 PE R M I T N O . 1 2 - 0 3 GE RW H VB VB 01 / 1 3 / 1 6 0 (FEET) GRAPHIC SCALE 400200100 J O H N S R I V E R CATA W B A R I V E R ( L A K E R H O D H I S S ) ~ STREAM S-2 WETLAND W1 EXISTING SEDIMENT BASIN PROTECTED AREA STREAM S-4 WETLAND W3 CEMETERY OFFICE AND GARAGE STREAM S-3 100 YR FLOOD LIMIT ELEV. 1005.0 PREVIOUS LANDFILL DISPOSAL AREA (CURRENTLY BEING CLOSED) EXISTING WASTE LIMITS ~ PROTECTED AREA SHOOTING RANGE JE-0018 JE-0024 JE-0020 JE-0019 HV-1 JE-0023 FACILITY BOUNDARY / PROPERTY LINE (TYP WEST AND SOUTH EDGES) MW-10 MW-11 MW-12 MW-13 MW-15S PZ-6 MW-22S PZ-16D PZ-16S PZ-23 NLE MW-21 MW-7 GMP-7A MW-16S MW-16D PZ-30S PZ-31 PZ-35 MW-38 MW-20 MW-14 FACILITY LIMIT CEMETERY HV-2 MW-19 MW-18 STREAM S1 BORROW AREA TRANSFER STATION WETLAND W2 PHASE 1A 1 0 1 0 1 0 2 0 1 0 3 0 1 0 4 0 1 0 5 0 1 0 6 0 1 0 8 0 1 0 9 0 1 1 0 0 1 1 1 0 1 1 2 0 1 1 3 0 1 1 4 0 1 1 6 0 1 1 8 0 1 1 8 0 1 1 6 0 1 1 4 0 1 1 2 0 1 1 0 0 1 0 8 0 1010 10 1 0 1000 1000 1020 1040 1050 1070 1090 1110 1130 1150 10 3 0 104 0 105 0 106 0 1070 1 0 4 0 1 0 5 0 10 6 0 107 0 1080 1080 1070 1060 1050 10401040 1050 10 7 0 1 0 6 0 1 0 6 0 1 0 5 0 10 4 0 10 3 0 10 2 0 10 1 0 10 1 0 10 2 0 103 0 10 4 0 1050 1 0 1 0 1 0 1 0 10 4 0 10 3 0 10 2 0 1020 103 0 104 0 10 5 0 10 5 0 10 6 0 10 4 0 10 3 010 2 0 10 2 010 3 0 10 4 0 105 0 106 0 1 0 7 0 107 0108 0 108 0 109 0110 0111 0 1120 1130 1120 1110 1100 109 0 108 0 1110 1110 11 0 0 1 1 1 0 1 1 2 0 112 0 112 01110 11 0 0 10 9 010 7 0 10 6 0 10 5 0 109 0 1120 11 1 0 1070 1080 1090 1100 10 0 0 10 5 0 1 0 6 0 1 0 0 0 100 0 ND ND ND 1.2 4.4 ND ND ND 13.8 2.3 ND 1.7 NS (ND) NS (ND) 0.95J 2.2 MW-36 5.8 N D N D ND 5 10 10 5 MW-15D MW-22D PZ-12 MW-17 PZ-34 (NLE) PZ-30D SMP-6 SMP-7 SMP-5 ND ND ND ND SMP-5 SURFACE MONITORING POINT LOCATION AND IDENTIFICATION NOT MEASURED LEGEND PROPERTY LINE EXISTING ROAD EXISTING 25' TOPOGRAPHIC CONTOUR EXISTING 2' TOPOGRAPHIC CONTOUR BENZENE CONTOUR (mg/ L) APPROXIMATE LIMITS OF WASTE CENTERLINE OF STREAM GAS PROBE LOCATION AND IDENTIFICATION PIEZOMETER LOCATION AND IDENTIFICATION NM GP 1050 MW-13 PZ-9D GMP-3 TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET. GPS = 1.0 (mg/ L) NOTES EXISTING 5' TOPOGRAPHIC CONTOUR EXISTING 10' TOPOGRAPHIC CONTOUR1080 T1 TEMPORARY WELL APPROXIMATE LOCATION OF SPRING HEAD 1. 2. SENTINEL WELL LOCATION AND IDENTIFICATION OF BENZENE (mg/ L)MW-18 MW-9 ABANDONED OR UNUSED MONITORING WELL NOT DETECTEDND NOT SAMPLED IN DEC.2015 (RESULTS FROM JUNE 2015) ESTIMATED CONCENTRATION NS(ND) COMPLIANCE WELL LOCATION & IDENTIFICATION OF BENZENE (mg/ L) J 0 (FEET) GRAPHIC SCALE 400200100 22 1 1 W . M E A D O W V I E W R O A D GR E E N S B O R O , N C 2 7 4 0 7 PH O N E : ( 3 3 6 ) 3 2 3 - 0 0 9 2 NC C O R P L I C : C - 0 7 8 2 PROJECT NO. AP P R O V E D CH E C K E D DR A W N DE S I G N E D DA T E DA T E RE V I S I O N S A N D R E C O R D O F I S S U E BY N O A P P C K SCALE A l l r i g h t s r e s e r v e d . Ó J o y c e E n g i n e e r i n g , I n c . DRAWING NO. L: \ B u r k e C o u n t y \ 2 0 1 6 c o n s t i t u e n t s m a p s \ 2 - B E N Z E N E . d w g L a y o u t = L a y o u t 1 277 JO H N ' S R I V E R W A S T E M A N A G E M E N T F A C I L I T Y BU R K E C O U N T Y , N O R T H C A R O L I N A 20 1 6 2 AS SHOWN BE N Z E N E I S O C O N C E N T R A T I O N M A P DE C E M B E R 2 0 1 5 VB RW H VB VB 3/ 2 9 / 1 6 J O H N S R I V E R CATA W B A R I V E R ( L A K E R H O D H I S S ) ~ STREAM S-2 WETLAND W1 EXISTING SEDIMENT BASIN PROTECTED AREA STREAM S-4 WETLAND W3 CEMETERY OFFICE AND GARAGE STREAM S-3 100 YR FLOOD LIMIT ELEV. 1005.0 PREVIOUS LANDFILL DISPOSAL AREA (CURRENTLY BEING CLOSED) EXISTING WASTE LIMITS ~ PROTECTED AREA SHOOTING RANGE JE-0018 JE-0024 JE-0020 HV-1 JE-0023 FACILITY BOUNDARY / PROPERTY LINE (TYP WEST AND SOUTH EDGES) MW-10 MW-11 MW-12 MW-13 MW-15S PZ-6 PZ-16D PZ-16S PZ-23 NLE MW-21 MW-7 MW-16S MW-16D PZ-30S PZ-31 PZ-35 MW-38 MW-20 MW-14 FACILITY LIMIT CEMETERY HV-2 MW-19 MW-18 STREAM S1 BORROW AREA TRANSFER STATION WETLAND W2 PHASE 1A 1 0 1 0 1 0 2 0 1 0 3 0 1 0 4 0 1 0 5 0 1 0 6 0 1 0 8 0 1 0 9 0 1 1 0 0 1 1 1 0 1 1 2 0 1 1 3 0 1 1 4 0 1 1 6 0 1 1 8 0 1 1 8 0 1 1 6 0 1 1 4 0 1 1 2 0 1 1 0 0 1 0 8 0 1010 10 1 0 1000 1000 1020 1040 1050 1070 1090 1110 1130 1150 10 3 0 104 0 105 0 106 0 1070 1 0 4 0 1 0 5 0 10 6 0 107 0 1080 1080 1070 1060 1050 10401040 1050 10 7 0 1 0 6 0 1 0 6 0 10 5 0 10 4 0 10 3 0 10 2 0 10 1 0 10 1 0 10 2 0 103 0 10 4 0 1050 1 0 1 0 1 0 1 0 10 4 0 10 3 0 10 2 0 1020 103 0 104 0 10 5 0 10 5 0 10 6 0 10 4 0 10 3 010 2 0 10 2 010 3 0 104 0 105 0 106 0 1 0 7 0 107 0108 0 108 0 109 0110 0111 0 1120 1130 1120 1110 1100 109 0 108 0 1110 1110 11 0 0 1 1 1 0 1 1 2 0 112 0 112 01110 11 0 0 10 9 010 7 0 10 6 0 10 5 0 109 0 1120 11 1 0 1070 1080 1090 1100 10 0 0 10 5 0 1 0 6 0 1 0 0 0 100 0 ND ND ND 1.0 12.2 ND ND ND 13.2 4.8 ND 9.1 NS (ND) NS(ND) 0.98J 12.6 MW-36 19.6 N D N D ND 1 0 10 20 MW-15D MW-22D PZ-12 ND MW-17 PZ-34 (NLE) PZ-30D SMP-6 SMP-7 SMP-5 ND ND ND SMP-5 SURFACE MONITORING POINT LOCATION AND IDENTIFICATION NOT MEASURED LEGEND PROPERTY LINE EXISTING ROAD EXISTING 25' TOPOGRAPHIC CONTOUR EXISTING 2' TOPOGRAPHIC CONTOUR 1,4 DICHLOROBENZENE CONTOUR (mg/ L) APPROXIMATE LIMITS OF WASTE CENTERLINE OF STREAM GAS PROBE LOCATION AND IDENTIFICATION PIEZOMETER LOCATION AND IDENTIFICATION NM GP 1050 MW-13 PZ-9D GMP-3 TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET. 1,4 - DCB GPS = 6.0 (mg/ L) NOTES EXISTING 5' TOPOGRAPHIC CONTOUR EXISTING 10' TOPOGRAPHIC CONTOUR1080 T1 TEMPORARY WELL APPROXIMATE LOCATION OF SPRING HEAD 1. 2. SENTINEL WELL LOCATION AND IDENTIFICATION OF 1,4-DCB (mg/ L)MW-18 MW-9 ABANDONED OR UNUSED MONITORING WELL NOT DETECTEDND NOT SAMPLED IN DEC.2015 (RESULTS FROM JUNE 2015) ESTIMATED CONCENTRATION NS(ND) COMPLIANCE WELL LOCATION & IDENTIFICATION OF 1,4-DCB (mg/ L) J 0 (FEET) GRAPHIC SCALE 400200100 22 1 1 W . M E A D O W V I E W R O A D GR E E N S B O R O , N C 2 7 4 0 7 PH O N E : ( 3 3 6 ) 3 2 3 - 0 0 9 2 NC C O R P L I C : C - 0 7 8 2 PROJECT NO. AP P R O V E D CH E C K E D DR A W N DE S I G N E D DA T E DA T E RE V I S I O N S A N D R E C O R D O F I S S U E BY N O A P P C K SCALE A l l r i g h t s r e s e r v e d . Ó J o y c e E n g i n e e r i n g , I n c . DRAWING NO. L: \ B u r k e C o u n t y \ 2 0 1 6 c o n s t i t u e n t s m a p s \ 3 - 1 4 D I C H L O R O B E N Z E N E . d w g L a y o u t = L a y o u t 1 277 JO H N ' S R I V E R W A S T E M A N A G E M E N T F A C I L I T Y BU R K E C O U N T Y , N O R T H C A R O L I N A 20 1 6 3 AS SHOWN 1, 4 - D I C H L O R O B E N Z E N E I S O C O N C E N T R A T I O N M A P DE C E M B E R 2 0 1 5 VB RW H VB VB 20 1 6 J O H N S R I V E R CATA W B A R I V E R ( L A K E R H O D H I S S ) ~ STREAM S-2 WETLAND W1 EXISTING SEDIMENT BASIN PROTECTED AREA STREAM S-4 WETLAND W3 CEMETERY OFFICE AND GARAGE STREAM S-3 100 YR FLOOD LIMIT ELEV. 1005.0 PREVIOUS LANDFILL DISPOSAL AREA (CURRENTLY BEING CLOSED) EXISTING WASTE LIMITS ~ PROTECTED AREA SHOOTING RANGE JE-0018 JE-0024 JE-0020 HV-1 JE-0023 FACILITY BOUNDARY / PROPERTY LINE (TYP WEST AND SOUTH EDGES) MW-10 MW-11 MW-12 MW-13 MW-15S PZ-6 PZ-16D PZ-16S PZ-23 NLE MW-21 MW-7 GMP-4 MW-16S MW-16D PZ-30S PZ-31 PZ-35 MW-38 MW-20 MW-14 FACILITY LIMIT CEMETERY HV-2 MW-19 MW-18 STREAM S1 BORROW AREA TRANSFER STATION WETLAND W2 PHASE 1A 1 0 1 0 1 0 2 0 1 0 3 0 1 0 4 0 1 0 5 0 1 0 6 0 1 0 8 0 1 0 9 0 1 1 0 0 1 1 1 0 1 1 2 0 1 1 3 0 1 1 4 0 1 1 6 0 1 1 8 0 1 1 8 0 1 1 6 0 1 1 4 0 1 1 2 0 1 1 0 0 1 0 8 0 1010 10 1 0 1000 1000 1020 1040 1050 1070 1090 1110 1130 1150 10 3 0 104 0 105 0 106 0 1070 1 0 4 0 1 0 5 0 10 6 0 107 0 1080 1080 1070 1060 1050 10401040 1050 10 7 0 1 0 6 0 1 0 6 0 10 5 0 10 4 0 10 3 0 10 2 0 10 1 0 10 1 0 10 2 0 103 0 10 4 0 1050 1 0 1 0 1 0 1 0 10 4 0 10 3 0 10 2 0 1020 103 0 104 0 10 5 0 10 5 0 10 6 0 10 4 0 10 3 010 2 0 10 2 010 3 0 104 0 105 0 106 0 1 0 7 0 107 0108 0 108 0 109 0110 0111 0 1120 1130 1120 1110 1100 109 0 108 0 1110 1110 11 0 0 1 1 1 0 1 1 2 0 112 0 112 01110 11 0 0 10 9 010 7 0 10 6 0 10 5 0 109 0 1120 11 1 0 1070 1080 1090 1100 10 0 0 10 5 0 1 0 6 0 1 0 0 0 100 0 ND ND ND 2.2 7.2 ND ND ND 33.7 31.7 ND 10.2 NS (1.7J) NS (ND) 0.95J 3.2 MW-365.9 N D N D ND 1 0 2 0 3 0 MW-15D MW-22D PZ-12 MW-17 PZ-34 (NLE) PZ-30D SMP-6 SMP-7 SMP-5 ND ND ND ND SMP-5 SURFACE MONITORING POINT LOCATION AND IDENTIFICATION NOT MEASURED LEGEND PROPERTY LINE EXISTING ROAD EXISTING 25' TOPOGRAPHIC CONTOUR EXISTING 2' TOPOGRAPHIC CONTOUR 1,1 DICHLOROETHANE CONTOUR (mg/ L) APPROXIMATE LIMITS OF WASTE CENTERLINE OF STREAM PIEZOMETER LOCATION AND IDENTIFICATION NM 1050 MW-13 PZ-9D TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET. 1,1-DCA GPS = 6.0 (mg/ L) NOTES EXISTING 5' TOPOGRAPHIC CONTOUR EXISTING 10' TOPOGRAPHIC CONTOUR1080 APPROXIMATE LOCATION OF SPRING HEAD 1. 2. SENTINEL WELL LOCATION AND IDENTIFICATION OF 1,1-DCA (mg/ L)MW-18 MW-9 ABANDONED OR UNUSED MONITORING WELL NOT DETECTEDND NOT SAMPLED IN DEC.2015 (RESULTS FROM JUNE 2015) ESTIMATED CONCENTRATION NS(ND) COMPLIANCE WELL LOCATION & IDENTIFICATION OF 1,1-DCA (mg/ L) J 0 (FEET) GRAPHIC SCALE 400200100 22 1 1 W . M E A D O W V I E W R O A D GR E E N S B O R O , N C 2 7 4 0 7 PH O N E : ( 3 3 6 ) 3 2 3 - 0 0 9 2 NC C O R P L I C : C - 0 7 8 2 PROJECT NO. AP P R O V E D CH E C K E D DR A W N DE S I G N E D DA T E DA T E RE V I S I O N S A N D R E C O R D O F I S S U E BY N O A P P C K SCALE A l l r i g h t s r e s e r v e d . Ó J o y c e E n g i n e e r i n g , I n c . DRAWING NO. L: \ B u r k e C o u n t y \ 2 0 1 6 c o n s t i t u e n t s m a p s \ 4 - 1 1 D I C H L O R O E T H A N E . d w g L a y o u t = L a y o u t 1 277 JO H N ' S R I V E R W A S T E M A N A G E M E N T F A C I L I T Y BU R K E C O U N T Y , N O R T H C A R O L I N A 20 1 6 4 AS SHOWN 1, 1 - D I C H L O R O E T H A N E I S O C O N C E N T R A T I O N M A P DE C E M B E R 2 0 1 5 VB RW H VB VB 3/ 2 9 / 1 6 J O H N S R I V E R CATA W B A R I V E R ( L A K E R H O D H I S S ) ~ STREAM S-2 WETLAND W1 EXISTING SEDIMENT BASIN PROTECTED AREA STREAM S-4 WETLAND W3 CEMETERY OFFICE AND GARAGE STREAM S-3 100 YR FLOOD LIMIT ELEV. 1005.0 PREVIOUS LANDFILL DISPOSAL AREA (CURRENTLY BEING CLOSED) EXISTING WASTE LIMITS ~ PROTECTED AREA SHOOTING RANGE JE-0018 JE-0024 JE-0020 HV-1 JE-0023 FACILITY BOUNDARY / PROPERTY LINE (TYP WEST AND SOUTH EDGES) MW-10 MW-11 MW-12 MW-13 MW-15S PZ-6 PZ-16D PZ-16S PZ-23 NLE MW-21 MW-7 MW-16S MW-16D PZ-30S PZ-31 PZ-35 MW-38 MW-20 MW-14 FACILITY LIMIT CEMETERY HV-2 MW-19MW-18 STREAM S1 BORROW AREA TRANSFER STATION WETLAND W2 PHASE 1A 1 0 1 0 1 0 2 0 1 0 3 0 1 0 4 0 1 0 5 0 1 0 6 0 1 0 8 0 1 0 9 0 1 1 0 0 1 1 1 0 1 1 2 0 1 1 3 0 1 1 4 0 1 1 6 0 1 1 8 0 1 1 8 0 1 1 6 0 1 1 4 0 1 1 2 0 1 1 0 0 1 0 8 0 1010 10 1 0 1000 1000 1020 1040 1050 1070 1090 1110 1130 1150 10 3 0 104 0 105 0 106 0 1070 1 0 4 0 1 0 5 0 10 6 0 107 0 1080 1080 1070 1060 1050 10401040 1050 10 7 0 1 0 6 0 1 0 6 0 1 0 5 0 10 4 0 10 3 0 10 2 0 10 1 0 10 1 0 10 2 0 103 0 10 4 0 1050 1 0 1 0 1 0 1 0 10 4 0 10 3 0 10 2 0 1020 103 0 104 0 10 5 0 10 5 0 10 6 0 10 4 0 10 3 010 2 0 10 2 010 3 0 10 4 0 105 0 106 0 1 0 7 0 107 0108 0 108 0 109 0110 0111 0 1120 1130 1120 1110 1100 109 0 108 0 1110 1110 11 0 0 1 1 1 0 1 1 2 0 112 0 112 01110 11 0 0 10 9 010 7 0 10 6 0 10 5 0 109 0 1120 11 1 0 1070 1080 1090 1100 10 0 0 10 5 0 1 0 6 0 1 0 0 0 100 0 ND ND ND ND 0.70J ND ND ND 1.3 ND ND 1.3 NS (1.7J)NS (ND) ND 0.65J MW-360.66J N D N D MW-15D MW-22D PZ-12 MW-17 PZ-34 (NLE) PZ-30D SMP-6 SMP-7 SMP-5 ND ND ND ND SMP-5 SURFACE MONITORING POINT LOCATION AND IDENTIFICATION NOT MEASURED LEGEND PROPERTY LINE EXISTING ROAD EXISTING 25' TOPOGRAPHIC CONTOUR EXISTING 2' TOPOGRAPHIC CONTOUR 1,2 DICHLOROETHANE CONTOUR (mg/ L) APPROXIMATE LIMITS OF WASTE CENTERLINE OF STREAM PIEZOMETER LOCATION AND IDENTIFICATION NM 1050 MW-13 PZ-9D TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET. 1,2-DCA GPS = 0.4 (mg/ L) NOTES EXISTING 5' TOPOGRAPHIC CONTOUR EXISTING 10' TOPOGRAPHIC CONTOUR1080 T1 TEMPORARY WELL APPROXIMATE LOCATION OF SPRING HEAD 1. 2. SENTINEL WELL LOCATION AND IDENTIFICATION OF VINYL CHLORIDE (mg/ L)MW-18 MW-9 ABANDONED OR UNUSED MONITORING WELL NOT DETECTEDND NOT SAMPLED IN DEC.2015 (RESULTS FROM JUNE 2015) ESTIMATED CONCENTRATION NS(ND) COMPLIANCE WELL LOCATION & IDENTIFICATION OF VINYL CHLORIDE (mg/ L) J 0 (FEET) GRAPHIC SCALE 400200100 22 1 1 W . M E A D O W V I E W R O A D GR E E N S B O R O , N C 2 7 4 0 7 PH O N E : ( 3 3 6 ) 3 2 3 - 0 0 9 2 NC C O R P L I C : C - 0 7 8 2 PROJECT NO. AP P R O V E D CH E C K E D DR A W N DE S I G N E D DA T E DA T E RE V I S I O N S A N D R E C O R D O F I S S U E BY N O A P P C K SCALE A l l r i g h t s r e s e r v e d . Ó J o y c e E n g i n e e r i n g , I n c . DRAWING NO. L: \ B u r k e C o u n t y \ 2 0 1 6 c o n s t i t u e n t s m a p s \ 5 - 1 2 D I C H L O R O E T H A N E . d w g L a y o u t = L a y o u t 1 277 JO H N ' S R I V E R W A S T E M A N A G E M E N T F A C I L I T Y BU R K E C O U N T Y , N O R T H C A R O L I N A 20 1 6 5 AS SHOWN 1, 2 - D I C H L O R O E T H A N E I S O C O N C E N T R A T I O N M A P DE C E M B E R 2 0 1 5 VB RW H VB VB 3/ 2 9 / 1 6 J O H N S R I V E R CATA W B A R I V E R ( L A K E R H O D H I S S ) ~ STREAM S-2 WETLAND W1 EXISTING SEDIMENT BASIN PROTECTED AREA STREAM S-4 WETLAND W3 CEMETERY OFFICE AND GARAGE STREAM S-3 100 YR FLOOD LIMIT ELEV. 1005.0 PREVIOUS LANDFILL DISPOSAL AREA (CURRENTLY BEING CLOSED) EXISTING WASTE LIMITS ~ PROTECTED AREA SHOOTING RANGE JE-0018 JE-0024 JE-0020 HV-1 JE-0023 FACILITY BOUNDARY / PROPERTY LINE (TYP WEST AND SOUTH EDGES) MW-10 MW-11 MW-12 MW-13 MW-15S PZ-6 PZ-16D PZ-16S PZ-23 NLE MW-21 MW-7 MW-16S MW-16D PZ-30S PZ-31 PZ-35 MW-38 MW-20 MW-14 FACILITY LIMIT CEMETERY HV-2 MW-19MW-18 STREAM S1 BORROW AREA TRANSFER STATION WETLAND W2 PHASE 1A 1 0 1 0 1 0 2 0 1 0 3 0 1 0 4 0 1 0 5 0 1 0 6 0 1 0 8 0 1 0 9 0 1 1 0 0 1 1 1 0 1 1 2 0 1 1 3 0 1 1 4 0 1 1 6 0 1 1 8 0 1 1 8 0 1 1 6 0 1 1 4 0 1 1 2 0 1 1 0 0 1 0 8 0 1010 10 1 0 1000 1000 1020 1040 1050 1070 1090 1110 1130 1150 10 3 0 104 0 105 0 106 0 1070 1 0 4 0 1 0 5 0 10 6 0 107 0 1080 1080 1070 1060 1050 10401040 1050 10 7 0 1 0 6 0 1 0 6 0 10 5 0 10 4 0 10 3 0 10 2 0 10 1 0 10 1 0 10 2 0 103 0 10 4 0 1050 1 0 1 0 1 0 1 0 10 4 0 10 3 0 10 2 0 1020 103 0 104 0 10 5 0 10 5 0 10 6 0 10 4 0 10 3 010 2 0 10 2 010 3 0 104 0 105 0 106 0 1 0 7 0 107 0108 0 108 0 109 0110 0111 0 1120 1130 1120 1110 1100 109 0 108 0 1110 1110 11 0 0 1 1 1 0 1 1 2 0 112 0 112 01110 11 0 0 10 9 010 7 0 10 6 0 10 5 0 109 0 1120 11 1 0 1070 1080 1090 1100 10 0 0 10 5 0 1 0 6 0 1 0 0 0 100 0 ND ND ND 2.1 ND ND ND ND 5.6 NDND ND NS (ND)NS (ND) ND ND MW-36 5.0 N D N D 5 5 MW-15D MW-22D PZ-12 MW-17 PZ-34 (NLE) PZ-30D SMP-6 SMP-7 SMP-5ND ND ND ND SMP-5 SURFACE MONITORING POINT LOCATION AND IDENTIFICATION NOT MEASURED LEGEND PROPERTY LINE EXISTING ROAD EXISTING 25' TOPOGRAPHIC CONTOUR EXISTING 2' TOPOGRAPHIC CONTOUR TETRACHLOROETHENE CONTOUR (mg/ L) APPROXIMATE LIMITS OF WASTE CENTERLINE OF STREAM PIEZOMETER LOCATION AND IDENTIFICATION NM 1050 MW-13 PZ-9D TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET. PCE GPS = 0.7 (mg/ L) NOTES EXISTING 5' TOPOGRAPHIC CONTOUR EXISTING 10' TOPOGRAPHIC CONTOUR1080 T1 TEMPORARY WELL ESTIMATED CONCENTRATION APPROXIMATE LOCATION OF SPRING HEAD 1. 2. SENTINEL WELL LOCATION AND IDENTIFICATION OF TETRACHLOROETHENE (mg/ L)MW-18 MW-9 ABANDONED OR UNUSED MONITORING WELL NOT DETECTEDND NOT SAMPLED IN DEC.2010 (RESULTS FROM JUNE 2010) NS(ND) COMPLIANCE WELL LOCATION & IDENTIFICATION OF TETRACHLOROETHENE (mg/ L) J 0 (FEET) GRAPHIC SCALE 400200100 22 1 1 W . M E A D O W V I E W R O A D GR E E N S B O R O , N C 2 7 4 0 7 PH O N E : ( 3 3 6 ) 3 2 3 - 0 0 9 2 NC C O R P L I C : C - 0 7 8 2 PROJECT NO. AP P R O V E D CH E C K E D DR A W N DE S I G N E D DA T E DA T E RE V I S I O N S A N D R E C O R D O F I S S U E BY N O A P P C K SCALE A l l r i g h t s r e s e r v e d . Ó J o y c e E n g i n e e r i n g , I n c . DRAWING NO. L: \ B u r k e C o u n t y \ 2 0 1 6 c o n s t i t u e n t s m a p s \ 6 - T E T R A C H L O R O E T H E N E . d w g L a y o u t = L a y o u t 1 277 JO H N ' S R I V E R W A S T E M A N A G E M E N T F A C I L I T Y BU R K E C O U N T Y , N O R T H C A R O L I N A 20 1 6 6 AS SHOWN TE T R A C H L O R O E T H E N E I S O C O N C E N T R A T I O N M A P DE C E M B E R 2 0 1 5 VB RW H VB VB 3/ 2 9 / 1 6 J O H N S R I V E R CATA W B A R I V E R ( L A K E R H O D H I S S ) ~ STREAM S-2 WETLAND W1 EXISTING SEDIMENT BASIN PROTECTED AREA STREAM S-4 WETLAND W3 CEMETERY OFFICE AND GARAGE STREAM S-3 100 YR FLOOD LIMIT ELEV. 1005.0 PREVIOUS LANDFILL DISPOSAL AREA (CURRENTLY BEING CLOSED) EXISTING WASTE LIMITS ~ PROTECTED AREA SHOOTING RANGE JE-0018 JE-0024 JE-0020 HV-1 JE-0023 FACILITY BOUNDARY / PROPERTY LINE (TYP WEST AND SOUTH EDGES) MW-10 MW-11 MW-12 MW-13 MW-15S PZ-6 PZ-16D PZ-16S PZ-23 NLE MW-21 MW-7 MW-16S MW-16D PZ-30S PZ-31 PZ-35 MW-38 MW-20 MW-14 FACILITY LIMIT CEMETERY HV-2 MW-19MW-18 STREAM S1 BORROW AREA TRANSFER STATION WETLAND W2 PHASE 1A 1 0 1 0 1 0 2 0 1 0 3 0 1 0 4 0 1 0 5 0 1 0 6 0 1 0 8 0 1 0 9 0 1 1 0 0 1 1 1 0 1 1 2 0 1 1 3 0 1 1 4 0 1 1 6 0 1 1 8 0 1 1 8 0 1 1 6 0 1 1 4 0 1 1 2 0 1 1 0 0 1 0 8 0 1010 10 1 0 1000 1000 1020 1040 1050 1070 1090 1110 1130 1150 10 3 0 104 0 105 0 106 0 1070 1 0 4 0 1 0 5 0 10 6 0 107 0 1080 1080 1070 1060 1050 10401040 1050 10 7 0 1 0 6 0 1 0 6 0 1 0 5 0 10 4 0 10 3 0 10 2 0 10 1 0 10 1 0 10 2 0 103 0 10 4 0 1050 1 0 1 0 1 0 1 0 10 4 0 10 3 0 10 2 0 1020 103 0 104 0 10 5 0 10 5 0 10 6 0 10 4 0 10 3 010 2 0 10 2 010 3 0 10 4 0 105 0 106 0 1 0 7 0 107 0108 0 108 0 109 0110 0111 0 1120 1130 1120 1110 1100 109 0 108 0 1110 1110 11 0 0 1 1 1 0 1 1 2 0 112 0 112 01110 11 0 0 10 9 010 7 0 10 6 0 10 5 0 109 0 1120 11 1 0 1070 1080 1090 1100 10 0 0 10 5 0 1 0 6 0 1 0 0 0 100 0 ND ND ND 1.1 2.1 ND ND ND 9.7 ND ND ND NS (ND)NS (ND) ND 0.71J ND N D ND MW-36 2.9 5 MW-15D MW-22D PZ-12 MW-17 PZ-34 (NLE) PZ-30D SMP-6 SMP-7 SMP-5 ND ND ND ND SMP-5 SURFACE MONITORING POINT LOCATION AND IDENTIFICATION NOT MEASURED LEGEND PROPERTY LINE EXISTING ROAD EXISTING 25' TOPOGRAPHIC CONTOUR EXISTING 2' TOPOGRAPHIC CONTOUR TRICHLOROETHENE CONTOUR (mg/ L) APPROXIMATE LIMITS OF WASTE CENTERLINE OF STREAM PIEZOMETER LOCATION AND IDENTIFICATION NM 1050 MW-13 PZ-9D TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET. TCE GPS = 3 (mg/ L) NOTES EXISTING 5' TOPOGRAPHIC CONTOUR EXISTING 10' TOPOGRAPHIC CONTOUR1080 T1 TEMPORARY WELL ESTIMATED CONCENTRATION APPROXIMATE LOCATION OF SPRING HEAD 1. 2. SENTINEL WELL LOCATION AND IDENTIFICATION OF TRICHLOROETHENE (mg/ L)MW-18 MW-9 ABANDONED OR UNUSED MONITORING WELL NOT DETECTEDND NOT SAMPLED IN DEC.2015 (RESULTS FROM JUNE 2015) NS(ND) COMPLIANCE WELL LOCATION & IDENTIFICATION OF TRICHLOROETHENE (mg/ L) J 0 (FEET) GRAPHIC SCALE 400200100 22 1 1 W . M E A D O W V I E W R O A D GR E E N S B O R O , N C 2 7 4 0 7 PH O N E : ( 3 3 6 ) 3 2 3 - 0 0 9 2 NC C O R P L I C : C - 0 7 8 2 PROJECT NO. AP P R O V E D CH E C K E D DR A W N DE S I G N E D DA T E DA T E RE V I S I O N S A N D R E C O R D O F I S S U E BY N O A P P C K SCALE A l l r i g h t s r e s e r v e d . Ó J o y c e E n g i n e e r i n g , I n c . DRAWING NO. L: \ B u r k e C o u n t y \ 2 0 1 6 c o n s t i t u e n t s m a p s \ 7 - T R I C H L O R O E T H E N E . d w g L a y o u t = L a y o u t 1 277 JO H N ' S R I V E R W A S T E M A N A G E M E N T F A C I L I T Y BU R K E C O U N T Y , N O R T H C A R O L I N A 20 1 6 7 AS SHOWN TR I C H L O R O E T H E N E I S O C O N C E N T R A T I O N M A P DE C E M B E R 2 0 1 5 VB RW H VB VB 3/ 2 9 / 1 6 J O H N S R I V E R CATA W B A R I V E R ( L A K E R H O D H I S S ) ~ STREAM S-2 WETLAND W1 EXISTING SEDIMENT BASIN PROTECTED AREA STREAM S-4 WETLAND W3 CEMETERY OFFICE AND GARAGE STREAM S-3 100 YR FLOOD LIMIT ELEV. 1005.0 PREVIOUS LANDFILL DISPOSAL AREA (CURRENTLY BEING CLOSED) EXISTING WASTE LIMITS ~ PROTECTED AREA SHOOTING RANGE JE-0018 JE-0024 JE-0020 HV-1 JE-0023 FACILITY BOUNDARY / PROPERTY LINE (TYP WEST AND SOUTH EDGES) MW-10 MW-11 MW-12 MW-13 MW-15S PZ-6 PZ-15 NLE PZ-16D PZ-16S PZ-23 NLE MW-21 MW-7 MW-16S MW-16D PZ-30S PZ-31 PZ-34 NLE MW-36 PZ-35 MW-38 MW-20 MW-14 FACILITY LIMIT CEMETERY HV-2 MW-19MW-18 STREAM S1 BORROW AREA TRANSFER STATION WETLAND W2 PHASE 1A 1 0 1 0 1 0 2 0 1 0 3 0 1 0 4 0 1 0 5 0 1 0 6 0 1 0 8 0 1 0 9 0 1 1 0 0 1 1 1 0 1 1 2 0 1 1 3 0 1 1 4 0 1 1 6 0 1 1 8 0 1 1 8 0 1 1 6 0 1 1 4 0 1 1 2 0 1 1 0 0 1 0 8 0 1010 10 1 0 1000 1000 1020 1040 1050 1070 1090 1110 1130 1150 10 3 0 104 0 105 0 106 0 1070 1 0 4 0 1 0 5 0 10 6 0 107 0 1080 1080 1070 1060 1050 10401040 1050 10 7 0 1 0 6 0 1 0 6 0 10 5 0 10 4 0 10 3 0 10 2 0 10 1 0 10 1 0 10 2 0 103 0 10 4 0 1050 1 0 1 0 1 0 1 0 10 4 0 10 3 0 10 2 0 1020 103 0 104 0 10 5 0 10 5 0 10 6 0 10 4 0 10 3 010 2 0 10 2 010 3 0 104 0 105 0 106 0 1 0 7 0 107 0108 0 108 0 109 0110 0111 0 1120 1130 1120 1110 1100 109 0 108 0 1110 1110 11 0 0 1 1 1 0 1 1 2 0 112 0 112 01110 11 0 0 10 9 010 7 0 10 6 0 10 5 0 109 0 1120 11 1 0 1070 1080 1090 1100 10 0 0 10 5 0 1 0 6 0 1 0 0 0 100 0 ND ND ND ND ND 0.80J ND ND ND ND ND ND 1.4 NS (ND)NS (ND) ND 0.72J ND N D ND MW-15D MW-22D PZ-12 MW-17 PZ-30D SMP-6 SMP-7 SMP-5 ND ND ND ND SMP-5 SURFACE MONITORING POINT LOCATION AND IDENTIFICATION NOT MEASURED LEGEND PROPERTY LINE EXISTING ROAD EXISTING 25' TOPOGRAPHIC CONTOUR EXISTING 2' TOPOGRAPHIC CONTOUR VINYL CHLORIDE CONTOUR (mg/ L) APPROXIMATE LIMITS OF WASTE CENTERLINE OF STREAM PIEZOMETER LOCATION AND IDENTIFICATION NM 1050 MW-13 PZ-9D TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET. VINYL CHLORIDE GPS = 0.03 (mg/ L) NOTES EXISTING 5' TOPOGRAPHIC CONTOUR EXISTING 10' TOPOGRAPHIC CONTOUR1080 T1 TEMPORARY WELL ESTIMATED CONCENTRATION APPROXIMATE LOCATION OF SPRING HEAD 1. 2. SENTINEL WELL LOCATION AND IDENTIFICATION OF VINYL CHLORIDE (mg/ L)MW-18 MW-9 ABANDONED OR UNUSED MONITORING WELL NOT DETECTEDND NOT SAMPLED IN DEC.2015 (RESULTS FROM JUNE 2015) NS(ND) COMPLIANCE WELL LOCATION & IDENTIFICATION OF VINYL CHLORIDE (mg/ L) J 0 (FEET) GRAPHIC SCALE 400200100 22 1 1 W . M E A D O W V I E W R O A D GR E E N S B O R O , N C 2 7 4 0 7 PH O N E : ( 3 3 6 ) 3 2 3 - 0 0 9 2 NC C O R P L I C : C - 0 7 8 2 PROJECT NO. AP P R O V E D CH E C K E D DR A W N DE S I G N E D DA T E DA T E RE V I S I O N S A N D R E C O R D O F I S S U E BY N O A P P C K SCALE A l l r i g h t s r e s e r v e d . Ó J o y c e E n g i n e e r i n g , I n c . DRAWING NO. L: \ B u r k e C o u n t y \ 2 0 1 6 c o n s t i t u e n t s m a p s \ 8 - V I N Y L C H L O R I D E . d w g L a y o u t = L a y o u t 1 277 JO H N ' S R I V E R W A S T E M A N A G E M E N T F A C I L I T Y BU R K E C O U N T Y , N O R T H C A R O L I N A 20 1 6 8 AS SHOWN VI N Y L C H L O R I D E I S O C O N C E N T R A T I O N M A P DE C E M B E R 2 0 1 5 VB RW H VB VB 20 1 6 JOHNS RIVER C A T A W B A R I V E R ( L A K E R H O D H I S S ) ~ S T R E A M S - 2 W E T L A N D W 1 E X I S T I N G S E D I M E N T B A S I N P R O T E C T E D A R E A S T R E A M S - 4 W E T L A N D W 3 C E M E T E R Y O F F I C E A N D G A R A G E S T R E A M S - 3 1 0 0 Y R F L O O D L I M I T E L E V . 1 0 0 5 . 0 PREVIOUS LANDFILLDISPOSAL AREA(CURRENTLY BEING CLOSED) E X I S T I N G W A S T E L I M I T S ~ P R O T E C T E D A R E A S H O O T I N G R A N G E JE-0018 J E - 0 0 2 4 J E - 0 0 2 0 HV - 1 FACILITY BOUNDARY /PROPERTY LINE (TYPWEST AND SOUTH EDGES)MW-10MW-11 M W - 1 2 MW-13 MW-15 S P Z - 6 P Z - 1 5 N L E P Z - 1 6 D P Z - 1 6 S P Z - 2 3 N L E MW-21 MW-7GP-2MW-16S MW-16D PZ-30SPZ-31PZ-34NLEMW-36 P Z - 3 5 MW-38 M W - 2 0 M W - 1 4 F A C I L I T Y L I M I T C E M E T E R Y HV-2 M W - 1 9 MW-18 STREAM S1 BORROW AREA T R A N S F E R S T A T I O N W E T L A N D W 2 PHASE 1 A 10101020 1030 1040 1050 1060 1080 1090 1100 1110 1120 1130 1140 1160 1180 1180 1160 1140 1120 1100 1080101010101000100010201040105010701090111011301150 103 0 104 0 105 0 10 6 0 1 0 7 0 1 0 4 0 1 0 5 0 1 0 6 0 1 0 7 0 1 0 8 0 1 0 8 0 1 0 7 0 1 0 6 0 1 0 5 0 1 0 4 0 1 0 4 0 1 0 5 0 1 0 7 0 1 0 6 0 1 0 6 0 1 0 5 0 1 0 4 0 1 0 3 0 1 0 2 0 1 0 1 0 1 0 1 0 1 0 2 0 1 0 3 0 1 0 4 0 1 0 5 0 1 0 1 0 1 0 1 0 1 0 4 0 1 0 3 0 1 0 2 0 1 0 2 0 1 0 3 0 1 0 4 0 1 0 5 0 1050 1060 1040 1030 1020 1020 1030 104 0 1050 10601070 10701080 108 0 1090110011101120 1130 1120 1110 1100 1090 1080 1 1 1 0 1 1 1 0 1100 1110 1120 1120 1120111011001090107010601050 1090 11201110 1 0 7 0 1 0 8 0 1 0 9 0 1 1 0 0 1000 1050 1 0 6 0 1 0 0 0 1 0 0 0 N D N D N D 2 . 6 B ND 11.2 B ND ND ND113 N D ND ND N S ( N D ) NS (ND)ND0.16 1 0 0 ND NDND100MW-15 D M W - 2 2 D P Z - 1 2 MW-17 P Z - 3 0 D S M P - 6 S M P - 7 SMP-5ND N D N D N D S M P - 5 S U R F A C E M O N I T O R I N G P O I N T L O C A T I O N A N D I D E N T I F I C A T I O N N O T M E A S U R E D L E G E N D P R O P E R T Y L I N E E X I S T I N G R O A D E X I S T I N G 2 5 ' T O P O G R A P H I C C O N T O U R E X I S T I N G 2 ' T O P O G R A P H I C C O N T O U R M E T H Y L E N E C H L O R I D E C O N T O U R ( m g / L ) A P P R O X I M A T E L I M I T S O F W A S T E C E N T E R L I N E O F S T R E A M P I E Z O M E T E R L O C A T I O N A N D I D E N T I F I C A T I O N N M 1 0 5 0 M W - 1 3 P Z - 9 D T O P O G R A P H I C C O N T O U R I N T E R V A L = 2 F E E T . M E T H Y L E N E C H L O R I D E G P S = 5 ( m g / L ) N O T E S E X I S T I N G 5 ' T O P O G R A P H I C C O N T O U R E X I S T I N G 1 0 ' T O P O G R A P H I C C O N T O U R 1 0 8 0 T 1 T E M P O R A R Y W E L L E S T I M A T E D C O N C E N T R A T I O N B L A N K Q U A L I F I E D A P P R O X I M A T E L O C A T I O N O F S P R I N G H E A D 1 . 2 . S E N T I N E L W E L L L O C A T I O N A N D I D E N T I F I C A T I O N O F M E T H Y L E N E C H L O R I D E ( m g / L ) M W - 1 8 M W - 9 A B A N D O N E D O R U N U S E D M O N I T O R I N G W E L L N O T D E T E C T E D N D N O T S A M P L E D I N D E C . 2 0 1 0 ( R E S U L T S F R O M J U N E 2 0 1 0 ) N S ( N D ) C O M P L I A N C E W E L L L O C A T I O N & I D E N T I F I C A T I O N O F M E T H Y L E N E C H L O R I D E ( m g / L ) J B 0 ( F E E T ) G R A P H I C S C A L E 4 0 0 2 0 0 1 0 0 2211 W. MEADOWVIEW ROAD GREENSBORO, NC 27407 PHONE: (336) 323-0092 NC CORP LIC: C-0782 P R O J E C T N O . APPROVED CHECKED DRAWN DESIGNED DATE DATE REVISIONS AND RECORD OF ISSUE BYNO APPCK S C A L E All rights reserved. Ó Joyce Engineering, Inc. D R A W I N G N O . L:\Burke County\2016 constituents maps\9- METHYLENE CHLORIDE.dwg Layout=Layout1 2 7 7 JOHN'S RIVER WASTE MANAGEMENT FACILITY BURKE COUNTY, NORTH CAROLINA 2016 9 A S S H O W N METHYLENE CHLORIDE ISOCONCENTRATION MAP DECEMBER 2015 VB RWH VB VB 3/29/16 J O H N S R I V E R CATA W B A R I V E R ( L A K E R H O D H I S S ) ~ STREAM S-2 WETLAND W1 EXISTING SEDIMENT BASIN PROTECTED AREA STREAM S-4 WETLAND W3 CEMETERY OFFICE AND GARAGE STREAM S-3 100 YR FLOOD LIMIT ELEV. 1005.0 PREVIOUS LANDFILL DISPOSAL AREA (CURRENTLY BEING CLOSED) EXISTING WASTE LIMITS ~ PROTECTED AREA SHOOTING RANGE JE-0018 JE-0024 JE-0020 HV-1 JE-0023 FACILITY BOUNDARY / PROPERTY LINE (TYP WEST AND SOUTH EDGES) MW-10 MW-11 MW-12 MW-13 MW-15S PZ-6 PZ-15 NLE PZ-16D PZ-16S PZ-23 NLE MW-21 MW-7 GMP-4 GP-2 MW-16S MW-16D PZ-30S PZ-31 PZ-34 NLE MW-36 PZ-35 MW-38 MW-20 MW-14 FACILITY LIMIT CEMETERY HV-2 MW-19MW-18 STREAM S1 BORROW AREA TRANSFER STATION WETLAND W2 PHASE 1A 1 0 1 0 1 0 2 0 1 0 3 0 1 0 4 0 1 0 5 0 1 0 6 0 1 0 8 0 1 0 9 0 1 1 0 0 1 1 1 0 1 1 2 0 1 1 3 0 1 1 4 0 1 1 6 0 1 1 8 0 1 1 8 0 1 1 6 0 1 1 4 0 1 1 2 0 1 1 0 0 1 0 8 0 1010 10 1 0 1000 1000 1020 1040 1050 1070 1090 1110 1130 1150 10 3 0 104 0 105 0 106 0 107 0 1 0 4 0 1 0 5 0 106 0 107 0 1080 1080 1070 1060 1050 10401040 1050 10 7 0 1 0 6 0 1 0 6 0 10 5 0 10 4 0 10 3 0 10 2 0 10 1 0 10 1 0 10 2 0 10 3 0 10 4 0 1050 1 0 1 0 1 0 1 0 10 4 0 10 3 0 10 2 0 1020 103 0 104 0 10 5 0 10 5 0 10 6 0 10 4 0 10 3 010 2 0 10 2 010 3 0 104 0 105 0 106 0 1 0 7 0 107 0108 0 108 0 109 0110 0111 0 1120 1130 1120 1110 1100 109 0 108 0 1110 1110 11 0 0 1 1 1 0 1 1 2 0 112 0 112 01110 11 0 0 10 9 010 7 0 10 6 0 10 5 0 109 0 1120 11 1 0 1070 1080 1090 1100 10 0 0 10 5 0 1 0 6 0 1 0 0 0 100 0 ND ND ND ND ND ND ND ND ND ND ND ND ND ND NS (ND)NS (ND) ND 0.16 MW-15D MW-22D PZ-12 MW-17 PZ-30D SMP-6 SMP-7 SMP-5ND ND ND ND SMP-5 SURFACE MONITORING POINT LOCATION AND IDENTIFICATION NOT MEASURED LEGEND PROPERTY LINE EXISTING ROAD EXISTING 25' TOPOGRAPHIC CONTOUR EXISTING 2' TOPOGRAPHIC CONTOUR beta BHC CONTOUR (mg/ L) APPROXIMATE LIMITS OF WASTE CENTERLINE OF STREAM PIEZOMETER LOCATION AND IDENTIFICATION NM 1050 MW-13 PZ-9D TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET. beta-BHD GPS = 0.019 (mg/ L) NOTES EXISTING 5' TOPOGRAPHIC CONTOUR EXISTING 10' TOPOGRAPHIC CONTOUR1080 T1 TEMPORARY WELL ESTIMATED CONCENTRATION APPROXIMATE LOCATION OF SPRING HEAD 1. 2. SENTINEL WELL LOCATION AND IDENTIFICATION OF beta-BHD (mg/ L)MW-18 MW-9 ABANDONED OR UNUSED MONITORING WELL NOT DETECTEDND NOT SAMPLED IN DEC.2010 (RESULTS FROM JUNE 2010) NS(ND) COMPLIANCE WELL LOCATION & IDENTIFICATION OF beta-BHD (mg/ L) J 0 (FEET) GRAPHIC SCALE 400200100 22 1 1 W . M E A D O W V I E W R O A D GR E E N S B O R O , N C 2 7 4 0 7 PH O N E : ( 3 3 6 ) 3 2 3 - 0 0 9 2 NC C O R P L I C : C - 0 7 8 2 PROJECT NO. AP P R O V E D CH E C K E D DR A W N DE S I G N E D DA T E DA T E RE V I S I O N S A N D R E C O R D O F I S S U E BY N O A P P C K SCALE A l l r i g h t s r e s e r v e d . Ó J o y c e E n g i n e e r i n g , I n c . DRAWING NO. L: \ B u r k e C o u n t y \ 2 0 1 6 c o n s t i t u e n t s m a p s \ 1 0 - B E T A - B H C . d w g L a y o u t = L a y o u t 1 277 JO H N ' S R I V E R W A S T E M A N A G E M E N T F A C I L I T Y BU R K E C O U N T Y , N O R T H C A R O L I N A 20 1 6 10 AS SHOWN be t a - B H C I S O C O N C E N T R A T I O N M A P DE C E M B E R 2 0 1 5 VB RW H VB VB 3/ 2 9 / 1 6 J O H N S R I V E R CATA W B A R I V E R ( L A K E R H O D H I S S ) ~ STREAM S-2 WETLAND W1 EXISTING SEDIMENT BASIN PROTECTED AREA STREAM S-4 WETLAND W3 CEMETERY OFFICE AND GARAGE STREAM S-3 100 YR FLOOD LIMIT ELEV. 1005.0 PREVIOUS LANDFILL DISPOSAL AREA (CURRENTLY BEING CLOSED) EXISTING WASTE LIMITS ~ PROTECTED AREA SHOOTING RANGE JE-0018 JE-0024 JE-0020 HV-1 FACILITY BOUNDARY / PROPERTY LINE (TYP WEST AND SOUTH EDGES) MW-10 MW-11 MW-12 MW-15S PZ-6 PZ-15 NLE PZ-16D PZ-16S PZ-23 NLE MW-21 MW-7 MW-16S MW-16D PZ-30S PZ-31 PZ-34 NLE MW-36 PZ-35 MW-38 MW-20 MW-14 FACILITY LIMIT CEMETERY HV-2 MW-19MW-18 STREAM S1 BORROW AREA TRANSFER STATION WETLAND W2 PHASE 1A 1 0 1 0 1 0 2 0 1 0 3 0 1 0 4 0 1 0 5 0 1 0 6 0 1 0 8 0 1 0 9 0 1 1 0 0 1 1 1 0 1 1 2 0 1 1 3 0 1 1 4 0 1 1 6 0 1 1 8 0 1 1 8 0 1 1 6 0 1 1 4 0 1 1 2 0 1 1 0 0 1 0 8 0 1010 10 1 0 1000 1000 1020 1040 1050 1070 1090 1110 1130 1150 10 3 0 104 0 105 0 106 0 107 0 1 0 4 0 1 0 5 0 106 0 107 0 1080 1080 1070 1060 1050 10401040 1050 10 7 0 1 0 6 0 1 0 6 0 10 5 0 10 4 0 10 3 0 10 2 0 10 1 0 10 1 0 10 2 0 10 3 0 10 4 0 1050 1 0 1 0 1 0 1 0 10 4 0 10 3 0 10 2 0 1020 103 0 104 0 10 5 0 10 5 0 10 6 0 10 4 0 10 3 010 2 0 10 2 010 3 0 104 0 105 0 106 0 1 0 7 0 107 0108 0 108 0 109 0110 0111 0 1120 1130 1120 1110 1100 109 0 108 0 1110 1110 11 0 0 1 1 1 0 1 1 2 0 112 0 112 01110 11 0 0 10 9 010 7 0 10 6 0 10 5 0 109 0 1120 11 1 0 1070 1080 1090 1100 10 0 0 10 5 0 1 0 6 0 1 0 0 0 100 0 ND ND ND 10.2 82.5 51.9 ND ND ND 52.0 ND 45.8 NS (1.7) NS (ND) 8.9 28.0 0+00 1+00 2+00 3+00 4+0 0 5+00 6+0 0 7+0 0 8+00 9+00 10+00 11+00 12+00 13+00 14 + 0 0 15 + 0 0 16 + 0 0 17 + 0 0 18+0 0 19+0 0 20+0 0 21+0 0 22+0 0 22+8 0 200 100 100 ND B 12 B 12 A 1 2 A 12 MW-13 283.4 MW-15D MW-22D PZ-12 MW-17 PZ-30D SMP-6 SMP-7 SMP-5 ND ND ND ND 30+50 0+00 1+00 2+00 3+00 4+00 5+00 6+0 0 7+ 0 0 8+00 9+ 0 0 10 + 0 0 11 + 0 0 12 + 0 0 13 + 0 0 1 4 + 0 0 1 5 + 0 0 1 6 + 0 0 1 7 + 0 0 1 8 + 0 0 1 9 + 0 0 2 0 + 0 0 2 1 + 0 0 2 2 + 0 0 2 3 + 0 0 2 4 + 0 0 2 5 + 0 0 2 6 + 0 0 2 7 + 0 0 2 8 + 0 0 2 9 + 0 0 3 0 + 0 0 SMP-5 SURFACE MONITORING POINT LOCATION AND IDENTIFICATION NOT MEASURED LEGEND PROPERTY LINE EXISTING ROAD EXISTING 25' TOPOGRAPHIC CONTOUR EXISTING 2' TOPOGRAPHIC CONTOUR TOTAL VOC'S CONTOUR (mg/ L) APPROXIMATE LIMITS OF WASTE CENTERLINE OF STREAM PIEZOMETER LOCATION AND IDENTIFICATION NM 1050 MW-13 PZ-9D TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET. TOTAL VOC'S CONTOUR INTERVAL = 100 (mg/ L). NOTES EXISTING 5' TOPOGRAPHIC CONTOUR EXISTING 10' TOPOGRAPHIC CONTOUR1080 T1 TEMPORARY WELL ESTIMATED CONCENTRATION APPROXIMATE LOCATION OF SPRING HEAD 1. 2. SENTINEL WELL LOCATION AND IDENTIFICATION OF TOTAL VOC'S (mg/ L)MW-18 MW-9 ABANDONED OR UNUSED MONITORING WELL NOT DETECTEDND NOT SAMPLED IN DEC.2010 (RESULTS FROM JUNE 2010) NS(ND) COMPLIANCE WELL LOCATION & IDENTIFICATION OF TOTAL VOC'S (mg/ L) J 0 (FEET) GRAPHIC SCALE 400200100 22 1 1 W . M E A D O W V I E W R O A D GR E E N S B O R O , N C 2 7 4 0 7 PH O N E : ( 3 3 6 ) 3 2 3 - 0 0 9 2 NC C O R P L I C : C - 0 7 8 2 PROJECT NO. AP P R O V E D CH E C K E D DR A W N DE S I G N E D DA T E DA T E RE V I S I O N S A N D R E C O R D O F I S S U E BY N O A P P C K SCALE A l l r i g h t s r e s e r v e d . Ó J o y c e E n g i n e e r i n g , I n c . DRAWING NO. L: \ B u r k e C o u n t y \ 2 0 1 6 c o n s t i t u e n t s m a p s \ 1 1 - T O T A L V O C ' S . d w g L a y o u t = L a y o u t 1 277 JO H N ' S R I V E R W A S T E M A N A G E M E N T F A C I L I T Y BU R K E C O U N T Y , N O R T H C A R O L I N A 20 1 6 11 AS SHOWN TO T A L V O C ' S I S O C O N C E N T R A T I O N M A P DE C E M B E R 2 0 1 5 VB RW H VB VB 3/ 2 9 / 1 6 900 910 920 930 940 950 960 970 980 990 1000 1010 1020 1030 1040 1050 1060 1070 900 910 920 930 940 950 960 970 980 990 1000 1010 1020 1030 1040 1050 1060 1070 0+00 1+00 2+00 3+00 4+00 5+00 6+00 7+00 8+00 9+00 10+00 11+00 12+00 13+00 14+00 15+00 16+00 17+00 18+00 19+00 20+00 21+00 22+00 22+80.02 MW-10 MW-11 MW-19 SCREENED INTERVAL (TYP) APPROXIMATE LIMITS OF WASTE JOHNS RIVER APPROXIMATE LIMITS OF WASTE FLOW GROUNDWATER SURFACE 8.9 28.0 NS (1.7) APPROXIMATE BEDROCK SURFACE GROUND SURFACE FLOW 900 910 920 930 940 950 960 970 980 990 1000 1010 1020 1030 1040 1050 1060 1070 1080 1090 1100 1110 1120 1130 900 910 920 930 940 950 960 970 980 990 1000 1010 1020 1030 1040 1050 1060 1070 1080 1090 1100 1110 1120 1130 0+00 1+00 2+00 3+00 4+00 5+00 6+00 7+00 8+00 9+00 10+00 11+00 12+00 13+00 14+00 15+00 16+00 17+00 18+00 19+00 20+00 21+00 22+00 23+00 24+00 25+00 26+00 27+00 28+00 29+00 30+00 30+50 CATAWBA RIVER MW-18 (ND) CATAWBA RIVER MW-16D/16S ND 45.8 MW-12 SCREENED INTERVAL (TYP) 52.0 MW-13 283.4 MW-17 NS MW-21 ND MW-36 51.9 MW-36 82.5 MW-15D/15S NS 10.2FLOW APPROXIMATE BEDROCK SURFACE GROUNDWATER SURFACE ND ND 100 200 ND ND FLOW ND 45.8 MW-16D/16S BEDROCK SURFACE TOTAL VOC ISOCONCENTRATION (mg/ L) (SUM OF CONCENTRATIONS OF ALL DETECTED VOLATILE ORGANIC COMPOUNDS) GROUND SURFACE LEGEND GROUNDWATER SURFACE (DECEMBER 9, 2015) 17.76 (3.10)TOTAL VOC CONCENTRATION FROM MAY 21, 2015 TOTAL VOC CONCENTRATION FROM DECEMBER 9, 2015 PROJECT NO. AP P R O V E D CH E C K E D DR A W N DE S I G N E D DA T E DA T E RE V I S I O N S A N D R E C O R D O F I S S U E BY N O A P P C K SCALE A l l r i g h t s r e s e r v e d . Ó J o y c e E n g i n e e r i n g , I n c . DRAWING NO. L: \ B u r k e C o u n t y \ 2 0 1 6 c o n s t i t u e n t s m a p s \ S H - 1 2 X - S C T . d w g L a y o u t = 1 2 x s e c t 0 (FEET) GRAPHIC SCALE 0 (F E E T ) VERTICAL EXAGGERATION = 50 100 200 25 50 100 2:1 277 JO H N S R I V E R , W A S T E M A N A G E M E N T F A C I L I T Y BU R K E C O U N T Y , N O R T H C A R O L I N A 20 1 0 12 AS SHOWN TO T A L V O C I S O C O N C E N T R A T I O N C R O S S S E C T I O N DE C E M B E R 2 0 1 5 PE R M I T N O . 1 2 - 0 3 22 1 1 W . M E A D O W V I E W R O A D GR E E N S B O R O , N C 2 7 4 0 7 PH O N E : ( 3 3 6 ) 3 2 3 - 0 0 9 2 NC C O R P L I C : C - 0 7 8 2 VB RW H VB VB 3/ 2 9 / 1 6 SECTION A SECTION B APPENDIX A Biochlor Modeling Input and Output BI O C H L O R N a t u r a l A t t e n u a t i o n D e c i s i o n S u p p o r t S y s t e m Bu r k e C o . Da t a I n p u t I n s t r u c t i o n s : Ve r s i o n 2 . 2 Jo h n ' s R i v e r 11 5 1 . E n t e r v a l u e d i r e c t l y . . . . o r Ex c e l 2 0 0 0 Ru n N a m e 2 . C a l c u l a t e b y f i l l i n g i n g r a y T Y P E O F C H L O R I N A T E D S O L V E N T : Et h e n e s 5. G E N E R A L 0. 0 2 c e l l s . P r e s s E n t e r , t h e n Et h a n e s S i m u l a t i o n T i m e * 1 7 ( y r ) (T o r e s t o r e f o r m u l a s , h i t " R e s t o r e F o r m u l a s " b u t t o n ) 1. A D V E C T I O N Mo d e l e d A r e a W i d t h * 1 6 0 0 ( f t ) V a r i a b l e * D a t a u s e d d i r e c t l y i n m o d e l . Se e p a g e V e l o c i t y * Vs 14 4 . 0 (f t / y r ) Mo d e l e d A r e a L e n g t h * 5 0 0 ( f t ) Te s t i f or Zo n e 1 L e n g t h * 50 0 ( f t ) Bi o t r a n s f o r m a t i o n Hy d r a u l i c C o n d u c t i v i t y K 1. 2 E - 0 3 (c m / s e c ) Zo n e 2 L e n g t h * 0 ( f t ) is O c c u r r i n g Hy d r a u l i c G r a d i e n t i 0. 0 5 (f t / f t ) Ef f e c t i v e P o r o s i t y n 0. 2 (- ) 6. S O U R C E D A T A TY P E : C o n t i n u o u s 2. D I S P E R S I O N Si n g l e P l a n a r Al p h a x * 5 0 ( f t ) (A l p h a y ) / ( A l p h a x ) * 0 . 3 3 ( - ) S o u r c e T h i c k n e s s i n S a t . Z o n e * 4 0 ( f t ) (A l p h a z ) / ( A l p h a x ) * 1 . E - 9 9 ( - ) Y1 3. A D S O R P T I O N Wi d t h * ( f t ) 16 0 0 Re t a r d a t i o n F a c t o r * R k s * or Co n c . ( m g / L ) * C1 (1 / y r ) So i l B u l k D e n s i t y , r h o 1. 6 ( k g / L ) PC E 0. 0 0 5 6 0 Fr a c t i o n O r g a n i c C a r b o n , f o c 1. 8 E - 3 (- ) TC E 0. 0 0 9 7 0 Vi e w o f P l u m e L o o k i n g D o w n Pa r t i t i o n C o e f f i c i e n t Ko c DC E 0. 0 2 5 8 0 PC E 42 6 ( L / k g ) 7 . 1 3 ( - ) V C 0. 0 0 0 0 0 Ob s e r v e d C e n t e r l i n e C o n c . a t M o n i t o r i n g W e l l s TC E 13 0 ( L / k g ) 2 . 8 7 ( - ) E T H 0 DC E 12 5 ( L / k g ) 2 . 8 0 ( - ) VC 30 ( L / k g ) (- ) 7. F I E L D D A T A F O R C O M P A R I S O N ET H 30 2 ( L / k g ) (- ) PC E C o n c . ( m g / L ) 0. 0 0 5 6 0 . 0 0 0 0 0 . 0 0 0 0 0 . 0 0 0 0 0 . 0 0 0 0 0 . 0 0 0 0 Co m m o n R ( u s e d i n m o d e l ) * = 2 . 8 7 TC E C o n c . ( m g / L ) 0. 0 0 9 7 0 . 0 0 7 1 0 . 0 0 1 4 0 . 0 0 0 0 0 . 0 0 0 0 0 . 0 0 0 0 4. B I O T R A N S F O R M A T I O N -1 s t O r d e r D e c a y C o e f f i c i e n t * D C E C o n c . ( m g / L ) 0. 0 2 5 8 0 . 0 0 6 9 0 . 0 0 9 9 0 . 0 0 4 4 0 . 0 0 0 0 0 . 0 0 0 0 Zo n e 1  ( 1 / y r ) ha l f - l i f e ( y r s ) Y i e l d VC C o n c . ( m g / L ) 0. 0 0 0 0 0 . 0 0 7 2 0 . 0 0 0 0 0 . 0 0 1 4 0 . 0 0 0 0 0 . 0 0 0 0 PC E T C E 2. 3 0 0 0. 7 9 ET H C o n c . ( m g / L ) TC E D C E 2. 1 0 0 0. 7 4 Di s t a n c e f r o m S o u r c e ( f t ) 0 2 0 6 0 1 3 5 2 1 0 4 3 0 DC E V C 1. 2 0 0 0. 6 4 Da t e D a t a C o l l e c t e d 20 1 5 - 1 2 VC E T H 0. 0 0 0 0. 4 5 8. C H O O S E T Y P E O F O U T P U T T O S E E : Zo n e 2  ( 1 / y r ) ha l f - l i f e ( y r s ) PC E T C E 2. 3 0 0 TC E D C E 2. 1 0 0 DC E V C 1. 2 0 0 VC E T H 0. 0 0 0 Ve r t i c a l P l a n e S o u r c e : D e t e r m i n e S o u r c e W e l l Lo c a t i o n a n d I n p u t S o l v e n t C o n c e n t r a t i o n s L W or Zo n e 2 = L - Z o n e 1  HE L P Paste Restore RU N CE N T E R L I N E He l p Natural Attenuation RU N A R R A Y C RESE So u r c e O p t i o n s SE E Ca l c . Ce n t e r l i n e O u t p u t Pa g e 1 0. 0 0 0 0 0. 0 0 0 1 0. 0 0 1 0 0. 0 1 0 0 0. 1 0 0 0 1. 0 0 0 0 0 1 0 0 2 0 0 3 0 0 4 0 0 5 0 0 6 0 0 C o n c e n t r a t i o n ( m g / L ) Di s t a n c e F r o m S o u r c e ( f t ) No D e g r a d a t i o n , T o t a l E t h e n e s PC E P r e d i c t i o n TC E P r e d i c t i o n DC E P r e d i c t i o n VC P r e d i c t i o n ET H P r e d i c t i o n PC E F i e l d D a t a TC E F i e l d D a t a DC E F i e l d D a t a VC F i e l d D a t a ET H F i e l d D a t a St a r t H e r e PCE DI S S O L V E D S O L V E N T C O N C E N T R A T I O N S I N P L U M E TCE Tr a n s v e r s e DCE Di s t a n c e ( f t ) D i s t a n c e f r o m S o u r c e ( f t ) VC 0 5 0 1 0 0 1 5 0 2 0 0 2 5 0 3 0 0 3 5 0 4 0 0 4 5 0 5 0 0 ETH 64 0 0. 0 0 5 6 0 . 0 0 3 3 0 . 0 0 2 0 0 . 0 0 1 1 0 . 0 0 0 7 0 . 0 0 0 4 0 . 0 0 0 2 0 . 0 0 0 1 0 . 0 0 0 1 0 . 0 0 0 0 0 . 0 0 0 0 32 0 0. 0 0 5 6 0 . 0 0 3 3 0 . 0 0 2 0 0 . 0 0 1 2 0 . 0 0 0 7 0 . 0 0 0 4 0 . 0 0 0 2 0 . 0 0 0 1 0 . 0 0 0 1 0 . 0 0 0 1 0 . 0 0 0 0 0 0. 0 0 5 6 0 . 0 0 3 3 0 . 0 0 2 0 0 . 0 0 1 2 0 . 0 0 0 7 0 . 0 0 0 4 0 . 0 0 0 2 0 . 0 0 0 1 0 . 0 0 0 1 0 . 0 0 0 1 0 . 0 0 0 0 -3 2 0 0. 0 0 5 6 0 . 0 0 3 3 0 . 0 0 2 0 0 . 0 0 1 2 0 . 0 0 0 7 0 . 0 0 0 4 0 . 0 0 0 2 0 . 0 0 0 1 0 . 0 0 0 1 0 . 0 0 0 1 0 . 0 0 0 0 -6 4 0 0. 0 0 5 6 0 . 0 0 3 3 0 . 0 0 2 0 0 . 0 0 1 1 0 . 0 0 0 7 0 . 0 0 0 4 0 . 0 0 0 2 0 . 0 0 0 1 0 . 0 0 0 1 0 . 0 0 0 0 0 . 0 0 0 0 98 . 5 0 0 0 MA S S 8. 0 E + 2 4 . 7 E + 2 2 . 8 E + 2 1 . 7 E + 2 9 . 7 E + 1 5 . 7 E +1 3 . 4 E + 1 2 . 0 E + 1 1 . 2 E + 1 6 . 9 E + 0 4 . 1 E + 0 RA T E Displayed Compound (m g / d a y ) Ti m e : 17 y r T a r g e t L e v e l : 0. 0 0 5 mg / L D i s p l a y e d M o d e l : Bi o t r a n s f o r m a t i o n P C E Pl u m e M a s s ( O r d e r - o f - M a g n i t u d e A c c u r a c y ) P l u m e M a s s I f N o D e g r a d a t i o n 2.9 (Kg) - P l u m e M a s s I f B i o t r a n s f o r m a t i o n / P r o d u c t i o n 0.6 (Kg) M a s s R e m o v e d 2.4 (Kg) % B i o t r a n s f o r m e d = +80.8%  % C h a n g e i n M a s s R a t e = 99.5 % C u r r e n t V o l u m e o f G r o u n d W a t e r i n P l u m e 4.79 MGal F l o w R a t e o f W a t e r T h r o u g h S o u r c e A r e a 0.038 MGD Pu m p i n g R a t e (gpm) # P o r e V o l u m e s R e m o v e d P e r Y r . 0 . 0 0 # P o r e V o l u m e s t o C l e a n - U p Cl e a n - U p T i m e (yr) If " C a n ' t C a l c . " , ma k e m o d e l a r e a lo n g e r 64 0 0. 0 0 0 0 0 1 -6 4 0 0. 0 0 0 0 0. 0 0 1 0 0. 0 0 2 0 0. 0 0 3 0 0. 0 0 4 0 0. 0 0 5 0 0. 0 0 6 0 0 5 0 1 0 0 1 5 0 2 0 0 2 5 0 3 0 0 3 5 0 4 0 0 4 5 0 5 0 0 ft . C o n c e n t r a t i o n ( m g / L ) Di s t a n c e f r o m S o u r c e ( f t . ) Co m p a r e t o P u m p a n d T r e a t (source to ed g e ) Se e ac r e - f t Return to Input Pl o t A l l D a t a Plo t D a t a > T a r g e t Ma s s H E L P Se e Ga l l o n Show No Show To C e n t e r l i n e St a r t H e r e PCE DI S S O L V E D S O L V E N T C O N C E N T R A T I O N S I N P L U M E TCE Tr a n s v e r s e DCE Di s t a n c e ( f t ) D i s t a n c e f r o m S o u r c e ( f t ) VC 0 5 0 1 0 0 1 5 0 2 0 0 2 5 0 3 0 0 3 5 0 4 0 0 4 5 0 5 0 0 ETH 64 0 0. 0 0 9 7 0 . 0 0 7 0 0 . 0 0 4 9 0 . 0 0 3 4 0 . 0 0 2 2 0 . 0 0 1 5 0 . 0 0 1 0 0 . 0 0 0 6 0 . 0 0 0 4 0 . 0 0 0 3 0 . 0 0 0 2 32 0 0. 0 0 9 7 0 . 0 0 7 0 0 . 0 0 4 9 0 . 0 0 3 4 0 . 0 0 2 3 0 . 0 0 1 5 0 . 0 0 1 0 0 . 0 0 0 7 0 . 0 0 0 4 0 . 0 0 0 3 0 . 0 0 0 2 0 0. 0 0 9 7 0 . 0 0 7 0 0 . 0 0 4 9 0 . 0 0 3 4 0 . 0 0 2 3 0 . 0 0 1 5 0 . 0 0 1 0 0 . 0 0 0 7 0 . 0 0 0 4 0 . 0 0 0 3 0 . 0 0 0 2 -3 2 0 0. 0 0 9 7 0 . 0 0 7 0 0 . 0 0 4 9 0 . 0 0 3 4 0 . 0 0 2 3 0 . 0 0 1 5 0 . 0 0 1 0 0 . 0 0 0 7 0 . 0 0 0 4 0 . 0 0 0 3 0 . 0 0 0 2 -6 4 0 0. 0 0 9 7 0 . 0 0 7 0 0 . 0 0 4 9 0 . 0 0 3 4 0 . 0 0 2 2 0 . 0 0 1 5 0 . 0 0 1 0 0 . 0 0 0 6 0 . 0 0 0 4 0 . 0 0 0 3 0 . 0 0 0 2 98 . 5 0 0 0 MA S S 1. 4 E + 3 1 . 0 E + 3 7 . 0 E + 2 4 . 8 E + 2 3 . 3 E + 2 2 . 2 E +2 1 . 4 E + 2 9 . 3 E + 1 6 . 1 E + 1 3 . 9 E + 1 2 . 5 E + 1 RA T E Displayed Compound (m g / d a y ) Ti m e : 17 y r T a r g e t L e v e l : 0. 0 0 5 mg / L D i s p l a y e d M o d e l : Bi o t r a n s f o r m a t i o n T C E Pl u m e M a s s ( O r d e r - o f - M a g n i t u d e A c c u r a c y ) P l u m e M a s s I f N o D e g r a d a t i o n 5.1 (Kg) - P l u m e M a s s I f B i o t r a n s f o r m a t i o n / P r o d u c t i o n 1.4 (Kg) M a s s R e m o v e d 3.7 (Kg) % B i o t r a n s f o r m e d = +73.0%  % C h a n g e i n M a s s R a t e = 98.2 % C u r r e n t V o l u m e o f G r o u n d W a t e r i n P l u m e 9.57 MGal F l o w R a t e o f W a t e r T h r o u g h S o u r c e A r e a 0.038 MGD Pu m p i n g R a t e (gpm) # P o r e V o l u m e s R e m o v e d P e r Y r . 0 . 0 0 # P o r e V o l u m e s t o C l e a n - U p Cl e a n - U p T i m e (yr) If " C a n ' t C a l c . " , ma k e m o d e l a r e a lo n g e r 64 0 0. 0 0 0 0 0 1 -6 4 0 0. 0 0 0 0 0. 0 0 1 0 0. 0 0 2 0 0. 0 0 3 0 0. 0 0 4 0 0. 0 0 5 0 0. 0 0 6 0 0. 0 0 7 0 0. 0 0 8 0 0. 0 0 9 0 0. 0 1 0 0 0 5 0 1 0 0 1 5 0 2 0 0 2 5 0 3 0 0 3 5 0 4 0 0 4 5 0 5 0 0 ft . C o n c e n t r a t i o n ( m g / L ) Di s t a n c e f r o m S o u r c e ( f t . ) Co m p a r e t o P u m p a n d T r e a t (source to ed g e ) Se e ac r e - f t Return to Input Pl o t A l l D a t a Plo t D a t a > T a r g e t Ma s s H E L P Se e Ga l l o n Show No Show To C e n t e r l i n e St a r t H e r e PCE DI S S O L V E D S O L V E N T C O N C E N T R A T I O N S I N P L U M E TCE Tr a n s v e r s e DCE Di s t a n c e ( f t ) D i s t a n c e f r o m S o u r c e ( f t ) VC 0 5 0 1 0 0 1 5 0 2 0 0 2 5 0 3 0 0 3 5 0 4 0 0 4 5 0 5 0 0 ETH 64 0 0. 0 2 5 8 0 . 0 2 1 1 0 . 0 1 6 9 0 . 0 1 3 3 0 . 0 1 0 3 0 . 0 0 7 9 0 . 0 0 6 0 0 . 0 0 4 5 0 . 0 0 3 4 0 . 0 0 2 5 0 . 0 0 1 8 32 0 0. 0 2 5 8 0 . 0 2 1 1 0 . 0 1 7 0 0 . 0 1 3 5 0 . 0 1 0 6 0 . 0 0 8 2 0 . 0 0 6 3 0 . 0 0 4 8 0 . 0 0 3 7 0 . 0 0 2 8 0 . 0 0 2 1 0 0. 0 2 5 8 0 . 0 2 1 1 0 . 0 1 7 0 0 . 0 1 3 5 0 . 0 1 0 6 0 . 0 0 8 2 0 . 0 0 6 3 0 . 0 0 4 8 0 . 0 0 3 7 0 . 0 0 2 8 0 . 0 0 2 1 -3 2 0 0. 0 2 5 8 0 . 0 2 1 1 0 . 0 1 7 0 0 . 0 1 3 5 0 . 0 1 0 6 0 . 0 0 8 2 0 . 0 0 6 3 0 . 0 0 4 8 0 . 0 0 3 7 0 . 0 0 2 8 0 . 0 0 2 1 -6 4 0 0. 0 2 5 8 0 . 0 2 1 1 0 . 0 1 6 9 0 . 0 1 3 3 0 . 0 1 0 3 0 . 0 0 7 9 0 . 0 0 6 0 0 . 0 0 4 5 0 . 0 0 3 4 0 . 0 0 2 5 0 . 0 0 1 8 98 . 5 0 0 0 MA S S 3. 7 E + 3 3 . 0 E + 3 2 . 4 E + 3 1 . 9 E + 3 1 . 5 E + 3 1 . 2 E +3 8 . 8 E + 2 6 . 7 E + 2 5 . 0 E + 2 3 . 8 E + 2 2 . 8 E + 2 RA T E Displayed Compound (m g / d a y ) Ti m e : 17 y r T a r g e t L e v e l : 0. 0 7 0 mg / L D i s p l a y e d M o d e l : Bi o t r a n s f o r m a t i o n D C E Pl u m e M a s s ( O r d e r - o f - M a g n i t u d e A c c u r a c y ) P l u m e M a s s I f N o D e g r a d a t i o n 13.6 (Kg) - P l u m e M a s s I f B i o t r a n s f o r m a t i o n / P r o d u c t i o n 5.3 (Kg) M a s s R e m o v e d 8.3 (Kg) % B i o t r a n s f o r m e d = +60.9%  % C h a n g e i n M a s s R a t e = 92.3 % C u r r e n t V o l u m e o f G r o u n d W a t e r i n P l u m e 33.51 MGal F l o w R a t e o f W a t e r T h r o u g h S o u r c e A r e a 0.038 MGD Pu m p i n g R a t e (gpm) # P o r e V o l u m e s R e m o v e d P e r Y r . 0 . 0 0 # P o r e V o l u m e s t o C l e a n - U p Cl e a n - U p T i m e (yr) If " C a n ' t C a l c . " , ma k e m o d e l a r e a lo n g e r 64 0 0. 0 0 0 0 0 1 -6 4 0 0. 0 0 0 0 0. 0 0 5 0 0. 0 1 0 0 0. 0 1 5 0 0. 0 2 0 0 0. 0 2 5 0 0. 0 3 0 0 0 5 0 1 0 0 1 5 0 2 0 0 2 5 0 3 0 0 3 5 0 4 0 0 4 5 0 5 0 0 ft . C o n c e n t r a t i o n ( m g / L ) Di s t a n c e f r o m S o u r c e ( f t . ) Co m p a r e t o P u m p a n d T r e a t (source to ed g e ) Se e ac r e - f t Return to Input Pl o t A l l D a t a Plo t D a t a > T a r g e t Ma s s H E L P Se e Ga l l o n Show No Show To C e n t e r l i n e St a r t H e r e PCE DI S S O L V E D S O L V E N T C O N C E N T R A T I O N S I N P L U M E TCE Tr a n s v e r s e DCE Di s t a n c e ( f t ) D i s t a n c e f r o m S o u r c e ( f t ) VC 0 5 0 1 0 0 1 5 0 2 0 0 2 5 0 3 0 0 3 5 0 4 0 0 4 5 0 5 0 0 ETH 64 0 0. 0 0 0 0 0 . 0 0 5 2 0 . 0 0 9 3 0 . 0 1 2 4 0 . 0 1 4 7 0 . 0 1 6 3 0 . 0 1 7 4 0 . 0 1 8 1 0 . 0 1 8 3 0 . 0 1 8 3 0 . 0 1 8 1 32 0 0. 0 0 0 0 0 . 0 0 5 2 0 . 0 0 9 3 0 . 0 1 2 6 0 . 0 1 5 1 0 . 0 1 7 0 0 . 0 1 8 4 0 . 0 1 9 4 0 . 0 2 0 0 0 . 0 2 0 3 0 . 0 2 0 2 0 0. 0 0 0 0 0 . 0 0 5 2 0 . 0 0 9 3 0 . 0 1 2 6 0 . 0 1 5 1 0 . 0 1 7 0 0 . 0 1 8 4 0 . 0 1 9 4 0 . 0 2 0 0 0 . 0 2 0 3 0 . 0 2 0 2 -3 2 0 0. 0 0 0 0 0 . 0 0 5 2 0 . 0 0 9 3 0 . 0 1 2 6 0 . 0 1 5 1 0 . 0 1 7 0 0 . 0 1 8 4 0 . 0 1 9 4 0 . 0 2 0 0 0 . 0 2 0 3 0 . 0 2 0 2 -6 4 0 0. 0 0 0 0 0 . 0 0 5 2 0 . 0 0 9 3 0 . 0 1 2 4 0 . 0 1 4 7 0 . 0 1 6 3 0 . 0 1 7 4 0 . 0 1 8 1 0 . 0 1 8 3 0 . 0 1 8 3 0 . 0 1 8 1 98 . 5 0 0 0 MA S S 1. 6 E - 4 7 . 4 E + 2 1 . 3 E + 3 1 . 8 E + 3 2 . 1 E + 3 2 . 4 E +3 2 . 6 E + 3 2 . 7 E + 3 2 . 8 E + 3 2 . 8 E + 3 2 . 8 E + 3 RA T E Displayed Compound (m g / d a y ) Ti m e : 17 y r T a r g e t L e v e l : 0. 0 0 2 mg / L D i s p l a y e d M o d e l : Bi o t r a n s f o r m a t i o n V C Pl u m e M a s s ( O r d e r - o f - M a g n i t u d e A c c u r a c y ) P l u m e M a s s I f N o D e g r a d a t i o n 0.0 (Kg) - P l u m e M a s s I f B i o t r a n s f o r m a t i o n / P r o d u c t i o n 8.0 (Kg) M a s s R e m o v e d -8.0 (Kg) % B i o t r a n s f o r m e d =  % C h a n g e i n M a s s R a t e = ########### C u r r e n t V o l u m e o f G r o u n d W a t e r i n P l u m e Can't Calc.MGal F l o w R a t e o f W a t e r T h r o u g h S o u r c e A r e a 0.038 MGD Pu m p i n g R a t e (gpm) # P o r e V o l u m e s R e m o v e d P e r Y r . # P o r e V o l u m e s t o C l e a n - U p Cl e a n - U p T i m e (yr) If " C a n ' t C a l c . " , ma k e m o d e l a r e a lo n g e r 64 0 0. 0 0 0 0 0 1 -6 4 0 0. 0 0 0 0 0. 0 0 5 0 0. 0 1 0 0 0. 0 1 5 0 0. 0 2 0 0 0. 0 2 5 0 0 5 0 1 0 0 1 5 0 2 0 0 2 5 0 3 0 0 3 5 0 4 0 0 4 5 0 5 0 0 ft . C o n c e n t r a t i o n ( m g / L ) Di s t a n c e f r o m S o u r c e ( f t . ) Co m p a r e t o P u m p a n d T r e a t (source to ed g e ) Se e ac r e - f t Return to Input Pl o t A l l D a t a Plo t D a t a > T a r g e t Ma s s H E L P Se e Ga l l o n Show No Show To C e n t e r l i n e BI O C H L O R N a t u r a l A t t e n u a t i o n D e c i s i o n S u p p o r t S y s t e m Bu r k e C o . Da t a I n p u t I n s t r u c t i o n s : Ve r s i o n 2 . 2 Jo h n ' s R i v e r 11 5 1 . E n t e r v a l u e d i r e c t l y . . . . o r Ex c e l 2 0 0 0 Ru n N a m e 2 . C a l c u l a t e b y f i l l i n g i n g r a y T Y P E O F C H L O R I N A T E D S O L V E N T : Et h e n e s 5. G E N E R A L 0. 0 2 c e l l s . P r e s s E n t e r , t h e n Et h a n e s S i m u l a t i o n T i m e * 1 7 ( y r ) (T o r e s t o r e f o r m u l a s , h i t " R e s t o r e F o r m u l a s " b u t t o n ) 1. A D V E C T I O N Mo d e l e d A r e a W i d t h * 1 6 0 0 ( f t ) V a r i a b l e * D a t a u s e d d i r e c t l y i n m o d e l . Se e p a g e V e l o c i t y * Vs 14 4 . 0 (f t / y r ) Mo d e l e d A r e a L e n g t h * 5 0 0 ( f t ) Te s t i f or Zo n e 1 L e n g t h * 50 0 ( f t ) Bi o t r a n s f o r m a t i o n Hy d r a u l i c C o n d u c t i v i t y K 1. 2 E - 0 3 (c m / s e c ) Zo n e 2 L e n g t h * 0 ( f t ) is O c c u r r i n g Hy d r a u l i c G r a d i e n t i 0. 0 5 (f t / f t ) Ef f e c t i v e P o r o s i t y n 0. 2 (- ) 6. S O U R C E D A T A TY P E : C o n t i n u o u s 2. D I S P E R S I O N Si n g l e P l a n a r Al p h a x * 5 0 ( f t ) (A l p h a y ) / ( A l p h a x ) * 0 . 3 3 ( - ) S o u r c e T h i c k n e s s i n S a t . Z o n e * 4 0 ( f t ) (A l p h a z ) / ( A l p h a x ) * 1 . E - 9 9 ( - ) Y1 3. A D S O R P T I O N Wi d t h * ( f t ) 16 0 0 Re t a r d a t i o n F a c t o r * R k s * or Co n c . ( m g / L ) * C1 (1 / y r ) So i l B u l k D e n s i t y , r h o 1. 6 ( k g / L ) TC A .0 0 Fr a c t i o n O r g a n i c C a r b o n , f o c 1. 8 E - 3 (- ) DC A .0 3 5 0 Vi e w o f P l u m e L o o k i n g D o w n Pa r t i t i o n C o e f f i c i e n t Ko c CA .0 0 TC A 42 6 ( L / k g ) 7 . 1 3 ( - ) 0 Ob s e r v e d C e n t e r l i n e C o n c . a t M o n i t o r i n g W e l l s DC A 13 0 ( L / k g ) 2 . 8 7 ( - ) 0 CA 12 5 ( L / k g ) 2 . 8 0 ( - ) 7. F I E L D D A T A F O R C O M P A R I S O N TC A C o n c . ( m g / L ) 0. 0 0 0 0 0 . 0 0 0 0 0 . 0 0 0 0 0 . 0 0 0 0 0 . 0 0 0 0 0 . 0 0 0 0 Co m m o n R ( u s e d i n m o d e l ) * = 2 . 8 7 DC A C o n c . ( m g / L ) 0. 0 3 5 0 0 . 0 0 3 9 0 . 0 3 1 7 0 . 0 1 1 6 0 . 0 0 0 0 0 . 0 0 1 7 4. B I O T R A N S F O R M A T I O N -1 s t O r d e r D e c a y C o e f f i c i e n t * C A C o n c . ( m g / L ) 0. 0 0 0 0 0 . 0 0 0 0 0 . 0 0 0 0 0 . 0 0 0 0 0 . 0 0 0 0 0 . 0 0 0 0 Zo n e 1  ( 1 / y r ) ha l f - l i f e ( y r s ) Y i e l d TC A D C A 2. 3 0 0 0. 7 4 DC A C A 2. 1 0 0 0. 6 5 Di s t a n c e f r o m S o u r c e ( f t ) 0 2 0 6 0 1 3 5 2 1 0 4 3 0 C A E t h a n e 1. 2 0 0 0. 4 7 Da t e D a t a C o l l e c t e d 20 1 5 - 1 2 0. 0 0 0 0. 0 0 8. C H O O S E T Y P E O F O U T P U T T O S E E : Zo n e 2  ( 1 / y r ) ha l f - l i f e ( y r s ) TC A D C A 2. 3 0 0 DC A C A 2. 1 0 0 C A E t h a n e 1. 2 0 0 0. 0 0 0 Ve r t i c a l P l a n e S o u r c e : D e t e r m i n e S o u r c e W e l l Lo c a t i o n a n d I n p u t S o l v e n t C o n c e n t r a t i o n s L W or Zo n e 2 = L - Z o n e 1  HE L P Paste Restore RU N CE N T E R L I N E He l p Natural Attenuation RU N A R R A Y C RESE So u r c e O p t i o n s SE E Ca l c . Ce n t e r l i n e O u t p u t Pa g e 1 0. 0 0 0 0 0. 0 0 0 1 0. 0 0 1 0 0. 0 1 0 0 0. 1 0 0 0 1. 0 0 0 0 0 1 0 0 2 0 0 3 0 0 4 0 0 5 0 0 6 0 0 C o n c e n t r a t i o n ( m g / L ) Di s t a n c e F r o m S o u r c e ( f t ) No D e g r a d a t i o n , T o t a l E t h a n e s TC A P r e d i c t i o n DC A P r e d i c t i o n CA P r e d i c t i o n TC A F i e l d D a t a DC A F i e l d D a t a CA F i e l d D a t a St a r t H e r e TCA DI S S O L V E D S O L V E N T C O N C E N T R A T I O N S I N P L U M E DCA Tr a n s v e r s e CA Di s t a n c e ( f t ) D i s t a n c e f r o m S o u r c e ( f t ) 0 5 0 1 0 0 1 5 0 2 0 0 2 5 0 3 0 0 3 5 0 4 0 0 4 5 0 5 0 0 64 0 0. 0 3 5 0 0 . 0 2 1 5 0 . 0 1 3 1 0 . 0 0 8 0 0 . 0 0 4 8 0 . 0 0 2 9 0 . 0 0 1 8 0 . 0 0 1 1 0 . 0 0 0 6 0 . 0 0 0 4 0 . 0 0 0 2 32 0 0. 0 3 5 0 0 . 0 2 1 5 0 . 0 1 3 1 0 . 0 0 8 1 0 . 0 0 4 9 0 . 0 0 3 0 0 . 0 0 1 9 0 . 0 0 1 1 0 . 0 0 0 7 0 . 0 0 0 4 0 . 0 0 0 3 0 0. 0 3 5 0 0 . 0 2 1 5 0 . 0 1 3 1 0 . 0 0 8 1 0 . 0 0 4 9 0 . 0 0 3 0 0 . 0 0 1 9 0 . 0 0 1 1 0 . 0 0 0 7 0 . 0 0 0 4 0 . 0 0 0 3 -3 2 0 0. 0 3 5 0 0 . 0 2 1 5 0 . 0 1 3 1 0 . 0 0 8 1 0 . 0 0 4 9 0 . 0 0 3 0 0 . 0 0 1 9 0 . 0 0 1 1 0 . 0 0 0 7 0 . 0 0 0 4 0 . 0 0 0 3 -6 4 0 0. 0 3 5 0 0 . 0 2 1 5 0 . 0 1 3 1 0 . 0 0 8 0 0 . 0 0 4 8 0 . 0 0 2 9 0 . 0 0 1 8 0 . 0 0 1 1 0 . 0 0 0 6 0 . 0 0 0 4 0 . 0 0 0 2 98 . 5 0 0 MA S S 5. 0 E + 3 3 . 1 E + 3 1 . 9 E + 3 1 . 1 E + 3 7 . 0 E + 2 4 . 3 E +2 2 . 6 E + 2 1 . 6 E + 2 9 . 6 E + 1 5 . 9 E + 1 3 . 6 E + 1 RA T E Displayed Compound (m g / d a y ) Ti m e : 17 y r T a r g e t L e v e l : m g / L D i s p l a y e d M o d e l : Bi o t r a n s f o r m a t i o n D C A Pl u m e M a s s ( O r d e r - o f - M a g n i t u d e A c c u r a c y ) P l u m e M a s s I f N o D e g r a d a t i o n 18.4 (Kg) - P l u m e M a s s I f B i o t r a n s f o r m a t i o n / P r o d u c t i o n 3.8 (Kg) M a s s R e m o v e d 14.6 (Kg) % B i o t r a n s f o r m e d = +79.6%  % C h a n g e i n M a s s R a t e = 99.3 % C u r r e n t V o l u m e o f G r o u n d W a t e r i n P l u m e 19.15 MGal F l o w R a t e o f W a t e r T h r o u g h S o u r c e A r e a 0.038 MGD Pu m p i n g R a t e (gpm) # P o r e V o l u m e s R e m o v e d P e r Y r . 0 . 0 0 # P o r e V o l u m e s t o C l e a n - U p Cl e a n - U p T i m e (yr) If " C a n ' t C a l c . " , ma k e m o d e l a r e a lo n g e r 64 0 0. 0 0 0 0 0 1 -6 4 0 0. 0 0 0. 0 1 0. 0 1 0. 0 2 0. 0 2 0. 0 3 0. 0 3 0. 0 4 0 5 0 1 0 0 1 5 0 2 0 0 2 5 0 3 0 0 3 5 0 4 0 0 4 5 0 5 0 0 ft . C o n c e n t r a t i o n ( m g / L ) Di s t a n c e f r o m S o u r c e ( f t . ) Co m p a r e t o P u m p a n d T r e a t (source to ed g e ) Se e ac r e - f t Return to Input Pl o t A l l D a t a Plo t D a t a > T a r g e t Ma s s H E L P Se e Ga l l o n Show No Show To C e n t e r l i n e