7305_DukeMayo_April2016_1stSemiAnnual_DIN26528_20160720

SEMIANNUAL GROUNDWATER MONITORING
REPORT
APRIL 2016 SAMPLING EVENT
MAYO STEAM ELECTRIC PLANT
COAL COMBUSTION PRODUCTS LANDFILL PHASE 1
PERMIT NO. 7305
10600 BOSTON RD
ROXBORO, NORTH CAROLINA

JULY 2016
PREPARED FOR

DUKE ENERGY PROGRESS, LLC
Mayo Semiannual Groundwater Monitoring Report – April 2016 Sampling Event July 2016
Duke Energy Progress, LLC SynTerra
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TABLE OF CONTENTS
SECTION PAGE
1.0 BACKGROUND............................................................................................................... 1
2.0 METHODS ........................................................................................................................ 3
2.1 Sampling and Analysis Methods ............................................................................... 3
2.2 Statement of Work ....................................................................................................... 4
3.0 RESULTS ........................................................................................................................... 5
3.1 Site Groundwater Flow ............................................................................................... 5
3.2 Analytical Results ........................................................................................................ 5
4.0 REFERENCES ................................................................................................................... 7

LIST OF FIGURES
Figure 1 Site Location Map
Figure 2 Sample Locations
Figure 3 Generalized Groundwater Surface Contours – April 6, 2016

LIST OF TABLES
Table 1 Well Construction Information
Table 2 Groundwater Flow Velocities – April 6, 2016
Table 3 Field Data Parameters
Table 4 Groundwater Field and Analytical Results
Table 5 Field and Analytical Results that Equal or Exceed 15A NCAC 2L
Groundwater Quality Standards
Table 6 Surface Water Field and Analytical Results
Table 7 Field and Analytical Results that Equal or Exceed 15A NCAC 2B Surface
Water Quality Standards
Table 8 Leachate Field and Analytical Results

LIST OF APPENDICES
Appendix A Field Sampling Forms
Appendix B Laboratory Report and Chain-of-Custody Forms
Mayo Semiannual Groundwater Monitoring Report – April 2016 Sampling Event July 2016
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1.0 BACKGROUND
The Mayo Steam Electric Plant began coal-fired power production in 1983. The station
is owned and operated by Duke Energy Progress (Duke Energy). The North Carolina
Department of Environmental Quality (NCDEQ, formally NCDENR) issued a permit to
operate (PTO) an on-site landfill (Permit #7305) on July 10, 2014. Phase 1 of the landfill
consists of 31 acres out of a possible total 104-acre proposed landfill footprint. The
capacity of Phase 1 is 1,592,000 cubic yards. The landfill was constructed with a double
high-density polyethylene liner with leak detection, groundwater monitoring, and
leachate collection systems.
As described in the Water Quality Monitoring Plan (WQMP), the landfill is located
within the Piedmont physiographic province. The Piedmont physiographic province is
comprised of several geologic belts with areas of similar rock types and geologic
history. The landfill is located within the Milton Belt which includes metamorphosed
volcanic and sedimentary rocks.
According to the WQMP, during the field investigation for the landfill Design
Hydrogeologic Report, three hydrogeologic units were identified on site: saprolite,
partially weathered rock (PWR), and bedrock. Groundwater was generally not
encountered in the saprolite unit. Groundwater was encountered in the PWR unit over
much of the landfill site. The bedrock hydrogeologic unit is continuous across the
landfill site.
The landfill site is located on an upland area with surface water drainage features that
discharge to the east and northeast into Bowe's Branch, a tributary of the Hyco River.
The surface water features to the west of the landfill site drain to the northwest to an
un-named tributary of Bowe's Branch. The landfill location and nearby area are
presented on Figure 1. Figure 2 shows the Phase 1 landfill site, topography, and vicinity
features.
As described in the WQMP, the monitoring system for the Phase 1 portion of the
landfill consists of the following:
Monitoring Wells: MW-1
MW-2
MW-3
MW-4
MW-5
Mayo Semiannual Groundwater Monitoring Report – April 2016 Sampling Event July 2016
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Surface Water Sample Locations: SW-1
SW-2
SW-3
Leachate Sample Locations:

L-1
L-2
The monitoring wells, surface water sampling locations, and leachate sampling location
L-1 are depicted on Figure 2.
According to the WQMP, MW-1 serves as a background water quality monitoring well
and is located upgradient of the landfill. The WQMP states the monitoring network is
designed to monitor for releases to the uppermost aquifer at the landfill. The wells
were installed with screen lengths ranging from 10 feet to 20 feet in length. Table 1
presents well construction information for the landfill monitoring wells.
Surface water sampling location SW-1 is located on an un-named perennial stream
(tributary of Bowes Branch) and is southwest of Phase 1. SW-1 is located upstream of
where groundwater from the Phase 1 area would discharge into the un-named stream
or Bowes Branch. Surface water sampling location SW-2 is located on Bowes Branch to
the east of the Phase 1 landfill. Surface water sampling location SW-3 is located on
Bowes Branch downstream from SW-1 and SW-2. The surface water flow on Figure 2 is
generally from the south to the north.
Leachate sample L-1 is collected from the facility's leachate tanks located to the west of
the Phase 1 landfill. The leachate sample is collected from an in-line sampling valve
linked to each of the three leachate tanks; therefore, the sample is considered a
composite leachate sample. The facility has the ability to direct leachate through a force
main to the National Pollutant Discharge Elimination System (NPDES) permitted
scrubber blowdown pond located on the east side of NC Highway 501. Should the
facility have no leachate in the leachate tank system and be diverting leachate from the
landfill to the scrubber blowdown pond, the leachate sample will be collected from the
end of the pipe at the scrubber blowdown pond. If the leachate sample is collected from
this location, it will be identified as L-2.

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2.0 METHODS
2.1 Sampling and Analysis Methods
The collection of samples and documentation of sampling was performed by SynTerra
Corporation (SynTerra) personnel (SynTerra North Carolina Field Certification #5591)
according to the North Carolina Solid Waste Management Guidelines. Copies of the
field sampling forms are included in Appendix A. The parameters and constituents
reported were selected by Duke Energy and the NCDEQ Division of Solid Waste and
were analyzed by Duke Energy Analytical Laboratory (North Carolina Laboratory
Certification #248). The laboratory report and chain-of-custody forms are included in
Appendix B.
The groundwater and surface water samples were analyzed for the following
constituents:
Barium, boron, chromium, copper, iron, manganese, nickel, silver, and zinc
using U.S. Environmental Protection Agency (EPA) Method 200.7
Arsenic, cadmium, lead, and selenium using EPA Method 200.8
Chloride, fluoride, nitrate (as nitrogen), and sulfate using EPA Method 300.0
Mercury using EPA Method 245.1
Total dissolved solids using Standard Method (SM) 2540C
Surface water samples were analyzed for the constituents listed above and the
following additional dissolved constituents:
Cadmium, chromium III, copper, lead, nickel, silver, and zinc using EPA
Method 200.8
Chromium VI using EPA Method 218.6
Total organic carbon, biochemical oxygen demand, and chemical oxygen demand were
historically sampled up until November 2014. These constituents are not currently
required to be analyzed in the WQMP and were not analyzed for during this sampling
event.

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2.2 Statement of Work
SynTerra completed the following tasks:
Conducted groundwater sampling at Mayo landfill monitoring wells,
shipped samples to Duke Energy Laboratory, and submitted all field data to
Duke Energy.
Received April 2016 field sampling information (compiled by Duke Energy
and redistributed to SynTerra) for monitoring wells MW-1, MW-2, MW-3,
MW-4, and MW-5. Data also included surface water sample locations SW-1,
SW-2, and SW-3, and leachate sample L-1. The samples were collected on
April 6, 2016. The field and analytical data were received on May 2, 2016.
Reviewed the laboratory analytical results for the samples listed above. The
Electronic Data Deliverable (EDD) provided by Duke Energy was adapted to
conform to the format requirements of the NCDEQ EDD template. A copy of
the original EDD is retained in SynTerra's files.
Developed generalized groundwater surface contour map using map data
and groundwater elevation data. Calculated groundwater flow velocities
based on groundwater surface contours.
Prepared and submitted this Semiannual Groundwater Monitoring Report to
Duke Energy.
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3.0 RESULTS
3.1 Site Groundwater Flow
Generalized groundwater surface contours and groundwater flow direction arrows for
the site are shown on Figure 3. These contours were developed using the groundwater
elevations measured on the date of sampling. Calculated flow velocities are presented
in Table 2.
Groundwater flow in the aquifer beneath the Phase 1 footprint is from the areas of
higher topography located along the central and western portion of the Phase 1
footprint generally towards the reach of Bowes Branch located along the eastern
boundary of the landfill.
3.2 Analytical Results
A summary of the field sample collection data is presented in Table 3. The field and
analytical results of groundwater samples collected from the monitoring wells are
presented in Table 4. The analytical results for these samples are compared to the
groundwater standards established in Title 15A NCAC 02L .0202 (g) (2L Standards).
Concentrations that attain or exceed the 2L Standards are noted in Table 4 by bold font.
A summary of the field and analytical results that attain or exceed the 2L Standards and
a preliminary analysis of the cause and significance of the exceedances are presented in
Table 5.
Surface water sample location SW-1 is located on an un-named perennial stream
(tributary of Bowes Branch) and surface water sampling locations SW-2 and SW-3 are
located on Bowes Branch. Bowes Branch is classified by the NCDEQ Division of Water
Quality as a Class C water body. As a result, the field and analytical results from these
locations are compared to Title 15A NCAC Subchapter 2B Standards (2B Standards) for
Class C waters. The field and analytical results for the surface water samples are
summarized in Table 6. Concentrations with values that attain or exceed the 2B
Standards are noted in Table 6 by bold font. A summary of the field and analytical
results that equal or exceed the 2B Standards and a preliminary analysis of the cause
and significance of the exceedances are presented in Table 7.
The field and analytical results for leachate sampling are summarized in Table 8.

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Concentrations with values that equal to or greater than the Solid Waste Section Limits
(SWSLs) are noted in Tables 4, 6, and 8 by gray-shaded cells.
Select samples were diluted, as is normal laboratory practice, to bring samples within
the calibrated range of the analysis. Specifics regarding the samples that were diluted,
including the dilution amount, are reported in the EDD.

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4.0 REFERENCES
Golder Associates NC, Inc., Water Quality Monitoring Plan – Duke Energy Progress, Inc.,
Mayo CCP Landfill, Permit No. 73-05, March 2014.
Morris, Donald Arthur, and Arnold Ivan Johnson. Summary of hydrologic and physical
properties of rock and soil materials, as analyzed by the hydrologic laboratory of the US
Geological Survey, 1967, 1948-60. No. 1839-D. US Govt.
Mayo Semiannual Groundwater Monitoring Report – April 2016 Sampling Event July 2016
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FIGURES

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FIGURE 1SITE LOCATION MAPMAYO STEAM ELECTRIC PLANTROXBORO, NORTH CAROLINACCP LANDFILL, PHASE 1PERMIT NO. 7305DRAWN BY: B. YOUNGPROJECT MANAGER: J. WYLIECHECKED BY: K. DONOVAN
DATE: 07/20/2016
148 RIVER STREET, SUITE 220GREENVILLE, SOUTH CAROLINA 29601PHONE [phone]www.synterracorp.com
P:\Duke Energy Progress.1026\00 GIS BASE DATA\Mayo\Map_Docs\State_Compliance\Figure 1 - Site Location Map.mxd
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IN FEET
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PHASE ILANDFILL BOUNDARY MAYO STEAM
ELECTRIC PLANT
LEGEND
LANDFILL BOUNDARY
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NOTES:1 CONTOURS FOR PHASE I ARE FROM GRADING PLAN - TOP OF LINERDRAWING NO. IFC-27 (GOLDER ASSOCIATES, INC.)
GRAPHIC SCALE3000300 600 900
(IN FEET)
LEGEND:
PROJECT MANAGER: J. WYLIE
DRAWN BY: B. YOUNG
DATE: 07/11/2016
DATE: 07/11/2016
CHECKED BY: K. DONOVAN
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FIGURE 2SAMPLE LOCATIONSMAYO STEAM ELECTRIC PLANTROXBORO, NORTH CAROLINACCP LANDFILL, PHASE 1PERMIT NO.7305
"
MAYO STEAM ELECTRIC POWER PLANT10660 BOSTON RDROXBORO, NORTH CAROLINA 27574
148 RIVER STREET, SUITE 220GREENVILLE, SC 29601864-421-9999
&A GROUNDWATER MONITORING WELL
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470
430
4 5 0 410
480
470
5 0 0
4 3 0
4 2 0
500
5 0 0
440
510
4 1 0
480
44 0
4 6 0
490
48 0
5 10
4 60
440
500
430
480
490
440
4 9 0
5 00
4 7 0
450
4 8 0
430
500
400
480
5 2 0
44 0
460
490
440 4 2 0
400
490500
500
480
4 90
490
520
4 9 0
410
450
480
490
4 8 0
500
530
400
470
490510
480
430
4 40
4 8 0
470
450
470
4 3 0
460
4 4 0
4 9 0
490
470
530
480
48 0
510
490
400
460
4 30
4 3 0
490
450
510
4 5 0
520
500
500
490
440
4 3 0
4 5 0
4 80
540
440
4 60
450
4 8 0
5 0 0
4 5 0
4 7 0
510
4 70
480
460
500
450
5 00
51 0520
490
420
460
500
460
490
490
430
4 30
430
480
490
4 2 0
500
470
4 4 0 460
440
4 5 0
470
450
480510
460
520
4 6 0
490
4 8 0
480
500
470
4 5 0
4 4 0 480
4 8 0
5 10
460
480
4 30
480
450
480
4 5 0
470
490
460
520
440
500
4 6 0
4 0 0
4 7 0
4 40
390
490
470
450
470
470
430
5 0 0
420
440
430
4 9 0
4 70
450
470
440
490
450
470
440
490
50 0
450
420
470
430
480
4
10
410
410
480
480
460390
430
470
380380400410
440430
410
390
420
460
450
MW-1(484.5)
MW-2(423.35)
MW-3(392.85)
MW-4(389.88)
MW-5(416.65)
SW-1
SW-2
SW-3
3
9
0
'
4
2
0
'
4
1
0
'
4
0
0
'
NOTES:1 CONTOURS FOR PHASE I ARE FROM GRADING PLAN - TOP OF LINERDRAWING NO. IFC-27 (GOLDER ASSOCIATES, INC.).
2 WATER LEVELS COLLECETED BY SYNTERRA ON APRIL 6, 2016.
GRAPHIC SCALE3000300 600 900
(IN FEET)
LEGEND:
PROJECT MANAGER: J. WYLIE
DRAWN BY: B. YOUNG
DATE: 07/11/2016
DATE: 07/11/2016
CHECKED BY: K. DONOVAN
P:\DUKE ENERGY PROGRESS.1026\00 GIS BASE DATA\MAYO\MAP_DOCS\STATE_COMPLIANCE\MAYO - MONOFILL_WATER_LEVEL.MXD
FIGURE 3GENERALIZED GROUNDWATERSURFACE CONTOURSAPRIL 2016MAYO STEAM ELECTRIC PLANTROXBORO, NORTH CAROLINACCP LANDFILL, PHASE 1PERMIT NO.7305
"
MAYO STEAM ELECTRIC POWER PLANT10660 BOSTON RDROXBORO, NORTH CAROLINA 27574
148 RIVER STREET, SUITE 220GREENVILLE, SC 29601864-421-9999
&A GROUNDWATER MONITORING WELL
#SURFACE WATER SAMPLING LOCATION
LIMIT OF WASTE (APPROXIMATE)
LANDFILL REVIEW BOUNDARY (APPROXIMATE)
LANDFILL COMPLIANCE BOUNDARY (APPROXIMATE)
STREAM
GENERALIZED GROUNDWATER SURFACE CONTOUR
GENERAL GROUNDWATER FLOW DIRECTION
EXISTING GROUND SURFACE CONTOUR
PHASE I GROUND SURFACE CONTOUR
PHASE I TOP OF LINER CONTOUR
(99.99)GROUNDWATER ELEVATION (FEET)
Mayo Semiannual Groundwater Monitoring Report – April 2016 Sampling Event July 2016
Duke Energy Progress, LLC SynTerra
P:\Duke Energy Progress.1026\05.MAYO\17. 2016 Well Samping Monofill\APRIL 2016 SOLID WASTE PERMIT
REPORT\Final April 2016 Monofill Report.docx
TABLES
TA
B
L
E

1

WE
L
L

C
O
N
S
T
R
U
C
T
I
O
N

I
N
F
O
R
M
A
T
I
O
N
MA
Y
O

C
C
P

L
A
N
D
F
I
L
L

P
H
A
S
E

1

-

P
E
R
M
I
T

N
O
.

7
3
0
5
MA
Y
O

S
T
E
A
M

E
L
E
C
T
R
I
C

P
L
A
N
T
DU
K
E

E
N
E
R
G
Y

P
R
O
G
R
E
S
S
,

L
L
C
,

R
O
X
B
O
R
O
,

N
C
La
t
i
t
u
d
e

L
o
n
g
i
t
u
d
e
MW
-
1

1
1
/
1
0
/
2
0
0
9

3
6
.
5
2
4
9
6
2
4

-
7
8
.
9
2
8
5
3
0
7

5
0
0
.
1
8

4
9
7
.
8
0

2
.
3
8

4
0
.
2
6

3
0
.
2
6

3
0
.
2
6

-

4
0
.
2
6

P
W
R

2

P
V
C
MW
-
2

5
/
2
5
/
2
0
1
1

3
6
.
5
3
6
2
1
5
9

-
7
8
.
9
2
2
2
3
8
7

4
6
2
.
1
5

4
5
9
.
8
2

2
.
3
3

7
4
.
9
7

5
4
.
9
7

5
4
.
9
7

-

7
4
.
9
7

B
e
d
r
o
c
k

2

P
V
C
MW
-
3

5
/
7
/
2
0
1
3

3
6
.
5
3
5
2
4
1
6

-
7
8
.
9
2
0
5
3
1
2

4
3
6
.
1
2

4
3
3
.
8
3

2
.
2
9

5
3
.
2
6

4
3
.
2
6

4
3
.
2
6

-

5
3
.
2
6

P
W
R

2

P
V
C
MW
-
4

5
/
7
/
2
0
1
3

3
6
.
5
3
3
4
0
5
0

-
7
8
.
9
2
0
0
3
4
0

4
2
3
.
7
2

4
2
1
.
3
7

2
.
3
5

3
8
.
9
0

2
8
.
9
0

2
8
.
9
0

-

3
8
.
9
0

S
a
p
r
o
l
i
t
e
/
P
W
R

2

P
V
C
MW
-
5

5
/
2
6
/
2
0
1
1

3
6
.
5
3
1
7
7
7
9

-
7
8
.
9
2
0
9
3
6
6

4
3
2
.
8
8

4
3
0
.
5
8

2
.
3
0

5
0
.
6
0

3
5
.
6
0

3
5
.
6
0

-

5
0
.
6
0

B
e
d
r
o
c
k

2

P
V
C
No
t
e
s
:

ft
.

=

f
e
e
t
Pr
e
p
a
r
e
d

b
y
:

S
R
W
Checked by: RKD Well Diameter (in.)Casing Type
TO
C

=

t
o
p

o
f

c
a
s
i
n
g
De
p
t
h

t
o

T
o
p

of

S
c
r
e
e
n

fr
o
m

T
O
C

(f
t
.
)
Sc
r
e
e
n
e
d

In
t
e
r
v
a
l

be
l
o
w

T
O
C

(f
t
.
)
Ge
o
l
o
g
y

o
f

Sc
r
e
e
n
e
d

In
t
e
r
v
a
l
in
.

=

i
n
c
h
e
s

n
o
m
i
n
a
l

d
i
a
m
e
t
e
r
PV
C

=

p
o
l
y
v
i
n
y
l

c
h
l
o
r
i
d
e
To
t
a
l

W
e
l
l

De
p
t
h

be
l
o
w

T
O
C

(f
t
.
)
Co
o
r
d
i
n
a
t
e
s
We
l
l

I
D
We
l
l

In
s
t
a
l
l
a
t
i
o
n

Da
t
e
We
l
l

T
O
C

El
e
v
a
t
i
o
n

(f
t
.
)
Gr
o
u
n
d

Su
r
f
a
c
e

El
e
v
a
t
i
o
n

(f
t
.
)
We
l
l

S
t
i
c
k
-
u
p

He
i
g
h
t

A
b
o
v
e

Gr
o
u
n
d

S
u
r
f
a
c
e

(f
t
.
)
PW
R

=

p
a
r
t
i
a
l
l
y

w
e
a
t
h
e
r
e
d

r
o
c
k
Ho
r
i
z
o
n
t
a
l

d
a
t
u
m

N
A
D
8
3
Ve
r
t
i
c
a
l

d
a
t
u
m

i
s

N
A
V
D

8
8
De
p
t
h

t
o

g
r
o
u
n
d
w
a
t
e
r

g
a
u
g
e
d

o
n

A
p
r
i
l

6
,

2
0
1
6
.
P:
\
D
u
k
e

E
n
e
r
g
y

P
r
o
g
r
e
s
s
.
1
0
2
6
\
0
5
.
M
A
Y
O
\
1
7
.

2
0
1
6

W
e
l
l

S
a
m
p
i
n
g

M
o
n
o
f
i
l
l
\
A
P
R
I
L

2
0
1
6

S
O
L
I
D

W
A
S
T
E

P
E
R
M
I
T

R
E
P
O
R
T
\
T
a
b
l
e

1

W
e
l
l

C
o
n
s
t
r
u
c
t
i
o
n

I
n
f
o
r
m
a
t
i
o
n
.
x
l
s
x
Page 1 of 1
TABLE 2
GROUNDWATER FLOW VELOCITIES
MAYO CCP LANDFILL PHASE 1 - PERMIT NO. 7305
MAYO STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ROXBORO, NC
MW-3 400 392.85 99 0.072 0.255 0.259 0.071
MW-4 400 389.88 141 0.072 0.110 0.259 0.030
Notes:
3. At monitoring well locations where upgradient contours are not present, the groundwater elevation at the monitoring well is used as the upgradient
groundwater elevation.
4. Monitoring wells are not listed where insufficient groundwater contour information is available to calculate velocity.
5. Hydraulic gradients and groundwater velocities are approximate.
6. Hydraulic conductivity presented for MW-3 and MW-4 are measured values for the individual wells based on slug test data obtained by SynTerra on May
11, 2016.
7. Effective porosity presented for MW-3 and MW-4 were adapted from schistic material values presented in Morris and Johnson, 1967
Prepared by: RKD Checked by: AA
1. Linear distance measured through monitoring wells is generally perpendicular to groundwater contours.
2. At monitoring well locations where downgradient contours are not present, the groundwater elevation at the monitoring well is used as the downgradient
groundwater elevation.
Hydraulic
Conductivity
(ft/day)
Effective
Porosity
(%/100)
Groundwater
Velocity
(ft/day)
Well ID
Upgradient
Groundwater
Contour
Elevation
(ft)
Downgradient
Groundwater
Contour
Elevation
(ft)
Linear Distance
Between
Contours
through Well
(ft)
Hydraulic
Gradient
(ft/ft)
P:\Duke Energy Progress.1026\05.MAYO\17. 2016 Well Samping Monofill\APRIL 2016 SOLID WASTE PERMIT REPORT\Tables\Table 2 GW Flow VelocitiesPage 1 of 1
TA
B
L
E

3

FI
E
L
D

D
A
T
A

P
A
R
A
M
E
T
E
R
S
MA
Y
O

C
C
P

L
A
N
D
F
I
L
L

P
H
A
S
E

1

-

P
E
R
M
I
T

N
O
.

7
3
0
5
MA
Y
O

S
T
E
A
M

E
L
E
C
T
R
I
C

P
L
A
N
T
DU
K
E

E
N
E
R
G
Y

P
R
O
G
R
E
S
S
,

L
L
C
,

R
O
X
B
O
R
O
,

N
C
4/
6
/
2
0
1
6

M
W
-
1
Cl
e
a
r

N
o
t

N
o
t
e
d

L
F
17
4
4.
0
1

0
.
5
5

N
o

1
3
26
9

6
.
2

1
.
4

1
5
6

1
.
1
1

4
8
4
.
5

1
5
.
6
8
4/
6
/
2
0
1
6

M
W
-
2
Cl
e
a
r

N
o
t

N
o
t
e
d

L
F
11
0
6.
1
1

0
.
7
3

N
o

1
3
70
8

7

8
.
9

0

0
.
4

4
2
3
.
3
5

3
8
.
8
0
4/
6
/
2
0
1
6

M
W
-
3
Cl
e
a
r

N
o
t

N
o
t
e
d

L
F
15
0
1.
6
3

0
.
7
1

N
o

1
6
72
3

6
.
8

9
.
7

-
2
1

0
.
4
4

3
9
2
.
8
5

4
3
.
2
7
4/
6
/
2
0
1
6

M
W
-
4
Cl
e
a
r

N
o
t

N
o
t
e
d

L
F
14
8
0.
8
3

0
.
3
5

N
o

1
7
92
4

6
.
4

4
.
2

3
9

0
.
3
3

3
8
9
.
8
8

3
3
.
8
4
4/
6
/
2
0
1
6

M
W
-
5
Cl
e
a
r

N
o
t

N
o
t
e
d

L
F
93
5.
6
4

0
.
2
5

N
o

1
6
57
8

7
.
3

4
.
6

-
7
2

0
.
3
2

4
1
6
.
6
5

1
6
.
2
3
4/
6
/
2
0
1
6

S
W
-
1
Cl
e
a
r

N
o
t

N
o
t
e
d

N
/
A

N
/
A
N/
A

N
/
A

N
/
A

1
0
19
1

7
.
1

1
2
.
3

2
6
2

7
.
8
0

N
/
A
N/A
4/
6
/
2
0
1
6

S
W
-
2
Cl
e
a
r

N
o
t

N
o
t
e
d

N
/
A

N
/
A
N/
A

N
/
A

N
/
A

1
0
12
4

7
.
2

9
.
7

3
1
5

1
0
.
1
2

N
/
A
N/A
4/
6
/
2
0
1
6

S
W
-
3
N/
A

N
o
t

N
o
t
e
d

N
/
A

N
/
A
N/
A

N
/
A

N
/
A

1
0
13
0

7
.
3

N
/
A

2
7
7

9
.
4

N
/
A
N/A
4/
6
/
2
0
1
6

L
P
-
1
Cl
e
a
r

N
o
t

N
o
t
e
d

N
/
A

N
/
A
N/
A

N
/
A

N
/
A

1
4
30
5

7
.
9

1
.
9

1
8
6

7
.
5
8

N
/
A
N/A
No
t
e
s
:

9.

N
/
A

=

N
o
t

A
p
p
l
i
c
a
b
l
e
2.

E
V
A
C

i
n
d
i
c
a
t
e
s

w
h
e
t
h
e
r

t
h
e

w
a
t
e
r

l
e
v
e
l

i
n

t
h
e

w
e
l
l

w
a
s

d
r
a
w
n

d
o
w
n

t
o

t
h
e

l
e
v
e
l

o
f

th
e

p
u
m
p

d
u
r
i
n
g

p
u
r
g
i
n
g
.
3.

u
m
h
o
/
c
m

=

m
i
c
r
o

m
h
o
s

p
e
r

c
e
n
t
i
m
e
t
e
r
4.

m
L
/
m
i
n

=

m
i
l
l
i
l
i
t
e
r
s

p
e
r

m
i
n
u
t
e
5.

S
U

=

S
t
a
n
d
a
r
d

U
n
i
t
s
6.

N
T
U

=

N
e
p
h
e
l
o
m
e
t
r
i
c

T
u
r
b
i
d
i
t
y

U
n
i
t
s
7.

m
V
-
N
H
E

=

m
i
l
l
i
v
o
l
t
s
-
n
o
r
m
a
l

h
y
d
r
o
g
e
n

e
l
e
c
t
r
o
d
e
8.

u
g
/
L

=

m
i
c
r
o
g
r
a
m
s

p
e
r

l
i
t
e
r
OR
P

(m
V
)
DO*(ug/L)
Av
e
r
a
g
e

Pu
m
p

R
a
t
e

(m
L
/
m
i
n
)
We
l
l

Vo
l
u
m
e

(g
a
l
l
o
n
s
)
EV
A
C

Vo
l
u
m
e

(g
a
l
l
o
n
s
)
EV
A
C

(y
e
s
/
n
o
)
Te
m
p

(d
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10
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Page 1 of 1
TA
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4
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e
d
)
51
µg
/
L
24
8
0.
5
3
0.
4
4

J
0.
2
7

J
0.
5
10
35 100
Ch
r
o
m
i
u
m

V
I

(
d
i
s
s
o
l
v
e
d
)
-
µg
/
L
24
8
0.
0
2
5

M
1
0.
0
2
6
0.
0
4
5
0.
5
10
11 100
Ch
r
o
m
i
u
m

I
I
I

(
d
i
s
s
o
l
v
e
d
)

-
µg
/
L
24
8
<1
0
<1
0
<1
0
0.
5
10
24 100
Co
p
p
e
r
54
µg
/
L
24
8
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<5
<5
1
10
2.
7
*
1,300
Co
p
p
e
r

(
d
i
s
s
o
l
v
e
d
)
-
µg
/
L
24
8
4.
7
3.
3
2.
0
1
10
2.
7
*
1,300
Flu
o
r
i
d
e
31
2
µg
/
L
24
8
12
0
24
0
21
0
17
2,
0
0
0
1,
8
0
0
4,000
Ir
o
n
34
0
µg
/
L
24
8
70
1
96
1
96
1
1.
3
30
0
NE 300**
Le
a
d
13
1
µg
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L
24
8
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0
6
5
10
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5
4
*
15
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a
d

(
d
i
s
s
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24
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5
1
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3
5
0.
2
0.
0
6
5
10
0.
5
4
*
15
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n
g
a
n
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2
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/
L
24
8
19
1
33
12
4
0.
2
50
NE 50**
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r
c
u
r
y
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L
24
8
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0
0
1
7
6
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0
0
1
7
8
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0
0
1
6
6
0.
0
0
6
0.
2
0.
0
1
2
2
Nic
k
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l
15
2
µg
/
L
24
8
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5
50
16
*
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k
e
l

(
d
i
s
s
o
l
v
e
d
)
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µg
/
L
24
8
0.
7
1
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5
0
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.
5
0.
5
50
16
*
NE
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r
a
t
e

(
a
s

N
i
t
r
o
g
e
n
)
30
3
µg
/
L
24
8
50
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3
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3
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4
10
,
0
0
0
10
,
0
0
0
10,000
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l
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n
i
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m
18
3
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L
24
8
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0.
0
9
2
10
5 50
Si
l
v
e
r
18
4
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/
L
24
8
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0.
7
10
0.
0
6
100**
Si
l
v
e
r

(
d
i
s
s
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l
v
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d
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/
L
24
8
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5
0
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5
0
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5
0
0.
7
10
0.
0
6
100**
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l
f
a
t
e
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5
µg
/
L
24
8
4,
2
0
0
4,
80
0
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4
0
0
18
25
0
,
0
0
0
25
0
,
0
0
0

2
5
0
,
0
0
0
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*
To
t
a
l

D
i
s
s
o
l
v
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d

S
o
l
i
d
s
31
1
µg
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L
24
8
14
0
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0
0
0
78
,
0
0
0
80
,
0
0
0
16
,
7
0
0
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50
0
,
0
0
0

5
0
0
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0
0
0
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n
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2
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3
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L
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8
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6
10
36
*
5,000**
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n
c

(
d
i
s
s
o
l
v
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21
3
µg
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L
24
8
32
.
9
7.
3
6.
4
2.
6
10
36
*
5,000**
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s
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p ar
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B
y : KDB Checked B y : AA
1.

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a
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a
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t
a
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d
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10
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t
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d
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f
o
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l
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s

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w
a
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s
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a
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u
m
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t
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11
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a
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d

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p
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t
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a
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w
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g
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1
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p
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w
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12
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§ 1
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13
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(
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21
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Page 1 of 1
TABLE 8
LEACHATE FIELD AND ANALYTICAL RESULTS
MAYO CCP LANDFILL PHASE 1 - PERMIT NO. 7305
MAYO STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ROXBORO, NC
Sample Location7305 L-1
Field pH 320 SU 5,591 7.9 - NE
Specific Conductance 323 umho/cm 5,591 305 - NE
Temperature 325 °C 5,591 14 - NE
Arsenic 14 µg/L 248 14.7 1 10
Barium 15 µg/L 248 61 5 100
Boron 428 µg/L 248 1,270 50 NE
Cadmium 34 µg/L 248 < 1 1 1
Chloride 455 µg/L 248 39,000 1,000 NE
Chromium 51 µg/L 248 26 5 10
Copper 54 µg/L 248 < 5 5 10
Fluoride 312 µg/L 248 180 100 2,000
Iron 340 µg/L 248 416 10 300
Lead 131 µg/L 248 < 1 1 10
Manganese 342 µg/L 248 8 5 50
Mercury 132 µg/L 248 < 0.05 0.05 0.2
Nickel 152 µg/L 248 34 5 50
Nitrate (as Nitrogen) 303 µg/L 248 630 23 10,000
Selenium 183 µg/L 248 1.7 1 10
Silver 184 µg/L 248 < 5 5 10
Sulfate 315 µg/L 248 130,000 2,000 250,000
Total Dissolved Solids 311 µg/L 248 330,000 25,000 NE
Zinc 213 µg/L 248 204 5 10
Prepared by: BDW Checked by: TCP
Notes:
1. - Concentrations are equal to or greater than the SWSL.
2. Bold concentrations are equal to or greater than the 15A NCAC 2B Standard (for pH bold indicates a measurement outside of the range).
3. Concentrations presented in micrograms per liter (µg/L).
4. SWS ID is the Solid Waste Section Identification Number.
5. RDL is the laboratory reporting limit.
6. SWSL is the Solid Waste Section Limit. NCDEQ defines the SWSL as the lowest amount of analyte in a sample that can be quantitatively determined
with suitable precision and accuracy.
7. Grayed values indicate values that equal or are greater than the SWSL.
8. Qualifiers in non-italicized text are laboratory data qualifiers or "flags". "U" is used to identify results not detected at concentrations which equal the laboratory's method detection limit (MDL). "J" is used to identify estimated concentrations which equal or are greater than the MDL but are less than
the laboratory's method reporting limit (MRL).
9. SU indicates Standard Units.
10. M^/cm indicates micromhos per centimeter.
11. NE indicates not established.
12. According to the Constituent Look-up webpage on the NCDEQ Division of Waste Management webpage, there is no SWSL for chloride associated with CAS number 16887-08-6, which is the CAS reported by the laboratory for the analyses completed. Therefore, the SWSL listed is for the chloride
with CAS number SW301 as specified on the Constituent Look-up webpage.
13. Analytical results obtained from Electronic Data Deliverable (EDD) provided by Duke Energy on May 17, 2016.
Laboratory Certificate Codes:
SynTerra Corporation Field #5591
Duke Energy Analytical Laboratory #248
Sample Date: April 6, 2016

Field Sampling performed by SynTerra Corporation
Parameter SWS ID Units Certificate Code RDL SWSL
P:\Duke Energy Progress.1026\05.MAYO\17. 2016 Well Samping Monofill\APRIL 2016 SOLID WASTE PERMIT REPORT\Table 8 - Leachate Field and Analytical
Results.xlsx Page 1 of 1
Mayo Semiannual Groundwater Monitoring Report – April 2016 Sampling Event July 2016
Duke Energy Progress, LLC SynTerra
P:\Duke Energy Progress.1026\05.MAYO\17. 2016 Well Samping Monofill\APRIL 2016 SOLID WASTE PERMIT
REPORT\Final April 2016 Monofill Report.docx
APPENDIX A
FIELD SAMPLING FORMS

0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
SITE NAME MAYO PERMIT # NC0038377 SITE ID N/A
DUKE ENERGY PROCEDURE NPDES
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME NPDES COMPLIANCE - MONO FILL FIELD CREW RHJ, KDF, ZAC, EMY
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME LP-01
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)MIDDLE OF WETTED SCREEN (ft TOC)0.00
SCREEN LENGTH (ft)ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)1/4 OD No Purge
DETECTED ODOR CONVERSION FACTOR
APPEARANCE
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
Purge Start Date:Purged To Dryness:
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
NO RHJ, KDF 4/6/2016
LENGTH DEPTH (top) DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C) (umho/cm) (SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV -NEH)(mg/L)
NA NA NA 14 305 7.9 1.9
11:15
186 7.58
NA
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE Ferrous (mg/l)Top Weight SAMPLE COLLECTED BY DATE
QC By:
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
Field Vehicle Accessable
30.26 40.26
N/A (psi)N/A (sec)(sec)
(gal)
@
YES
Duplica
te
sample
taken
SAMPLING NOTES
Field Vehicle Accessable
PROTECTIVE CASING Good Condition Turbidity issues possible
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
QC By:EMY
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED Ferrous Iron
(mg/l)INITIAL PURGE VOLUME 0.75 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 1.35 (gal)EMY, ZAD 4/6/2016 9:20
DRAW-DOWN 0.12 (ft)
N/A9:20 15.80 174 13 269 6.2 1.4 156 1.11
N/A
9:17 15.80 174 13 270 6.3 2.0 156 1.12 N/A
9:14 15.80 174 13 270 6.2 1.7 157 1.18
N/A
9:11 15.80 174 13 269 6.2 1.5 160 1.28 N/A
9:08 15.80 174 13 271 6.2 3.1 164 1.21
(recalculates on
current water
level)(hh:mm)(ft)(ml/min) (deg C) (umho/cm) (SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
Purge Start Date:4/6/2016 Purged To Dryness:
4.01
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 15.68 WATER COLUMN (ft)24.58 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)484.50 WELL VOLUME
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
2867-T SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)1/4 OD Low Flow
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2 TOC ELEV (ft msl) 500.18 MIDDLE OF WETTED SCREEN (ft TOC)35.26
SCREEN LENGTH (ft) 10.00 ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC) 40.26 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)32.50
PROJECT NAME NPDES COMPLIANCE - MONO FILL FIELD CREW RHJ, KDF, ZAC, EMY
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME MW-01
SITE NAME MAYO PERMIT # NC0038377 SITE ID N/A
DUKE ENERGY PROCEDURE NPDES
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
56.27 76.27
N/A (psi)N/A (sec)(sec)
(gal)
@
YES
SAMPLING NOTES
Field Vehicle Accessable
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
QC By:EMY
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED Ferrous Iron
(mg/l)INITIAL PURGE VOLUME 0.50 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 1.25 (gal)EMY, ZAD 4/6/2016 10:41
DRAW-DOWN 1.81 (ft)
N/A
10:40 40.61 110 13 708 7.0 8.9 0 0.40 N/A
10:33 40.30 110 13 710 7.0 10.3 -9 0.40
N/A
10:24 40.15 110 13 710 7.0 11.9 -13 0.40 N/A
10:21 39.78 110 13 712 7.0 13.4 -13 0.47
N/A
10:18 39.48 110 13 711 7.0 15.0 5 0.55 N/A
10:15 39.34 110 13 708 6.9 17.1 7 0.69
(recalculates on
current water
level)(hh:mm)(ft)(ml/min) (deg C) (umho/cm) (SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
Purge Start Date:4/6/2016 Purged To Dryness:
6.11
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 38.80 WATER COLUMN (ft)37.47 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)423.35 WELL VOLUME
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
2867-T SAMPLING EQUIPMENT SUB PUMP PURGE METHOD
TUBING DIAMETER (in)1/4 OD Low Flow
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2 TOC ELEV (ft msl) 462.15 MIDDLE OF WETTED SCREEN (ft TOC)66.27
SCREEN LENGTH (ft) 20.00 ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC) 76.27 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)57.00
PROJECT NAME NPDES COMPLIANCE - MONO FILL FIELD CREW RHJ, KDF, ZAC, EMY
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME MW-02
SITE NAME MAYO PERMIT # NC0038377 SITE ID N/A
DUKE ENERGY PROCEDURE NPDES
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
33.25 43.25
N/A (psi)N/A (sec)(sec)
(gal)
@
YES
Well
tag
indicat
es well
screen
ed
betwee
n 41
and 51
feet,
placed
pump
intake
at 46 ft
below
TOC
Bedroc
k well
drilled
today
approxi
mately
25 feet
away.
Could
have
increas
ed
turbidit
y in this
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SAMPLING NOTES
Field Vehicle Accessable
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
QC By:ZAD
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED Ferrous Iron
(mg/l)INITIAL PURGE VOLUME 2.50 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 3.25 (gal)EMY, ZAD 4/6/2016 12:15
DRAW-DOWN 0.07 (ft)
N/A12:15 43.34 150 16 723 6.8 9.7 -21 0.44
N/A
12:12 43.31 150 16 723 6.8 11.9 -18 0.46 N/A
12:09 43.23 150 16 723 6.8 16.3 -15 0.49
N/A
12:06 43.20 150 16 723 6.8 32.2 -9 0.51 N/A
12:03 43.19 150 16 722 6.8 44.5 7 0.63
N/A
12:00 43.19 150 16 722 6.8 76.6 15 0.69 N/A
11:57 43.05 150 15 723 6.8 198.0 55 0.64
(recalculates on
current water
level)(hh:mm)(ft)(ml/min) (deg C) (umho/cm) (SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
Purge Start Date:4/6/2016 Purged To Dryness:
0.00
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 43.27 WATER COLUMN (ft)-0.02 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)392.85 WELL VOLUME
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
2867-T SAMPLING EQUIPMENT SUB PUMP PURGE METHOD
TUBING DIAMETER (in)1/4 OD Low Flow
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)436.12 MIDDLE OF WETTED SCREEN (ft TOC)43.26
SCREEN LENGTH (ft) 10.00 ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC) 43.25 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)46.00
PROJECT NAME NPDES COMPLIANCE - MONO FILL FIELD CREW RHJ, KDF, ZAC, EMY
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME MW-03
SITE NAME MAYO PERMIT # NC0038377 SITE ID N/A
DUKE ENERGY PROCEDURE NPDES
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
28.90 38.90
N/A (psi)N/A (sec)(sec)
(gal)
@
YES
CCR
well
being
drilled
while
collecti
ng
sample
.
Drilling
below
surface
casing
in
bedroc
k and
did not
effect
sample
collecti
on.
SAMPLING NOTES
Field Vehicle Accessable
PROTECTIVE CASING Good Condition Turbidity issues possible
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
QC By:EMY
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED Ferrous Iron
(mg/l)INITIAL PURGE VOLUME 1.50 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 1.90 (gal)EMY, ZAD 4/6/2016 15:01
DRAW-DOWN 1.61 (ft)
N/A
15:00 35.45 148 17 924 6.4 4.2 39 0.33 N/A
14:57 35.32 148 17 925 6.4 4.3 39 0.31
N/A
14:54 35.23 148 17 924 6.3 8.1 45 0.39 N/A
14:51 35.06 148 17 925 6.3 16.3 50 0.90
(recalculates on
current water
level)(hh:mm)(ft)(ml/min) (deg C) (umho/cm) (SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
Purge Start Date:4/6/2016 Purged To Dryness:
0.83
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 33.84 WATER COLUMN (ft)5.06 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)389.88 WELL VOLUME
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
2867-T SAMPLING EQUIPMENT SUB PUMP PURGE METHOD
TUBING DIAMETER (in)1/4 OD Low Flow
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2 TOC ELEV (ft msl) 423.72 MIDDLE OF WETTED SCREEN (ft TOC)36.37
SCREEN LENGTH (ft) 10.00 ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC) 38.90 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)37.00
PROJECT NAME NPDES COMPLIANCE - MONO FILL FIELD CREW RHJ, KDF, ZAC, EMY
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME MW-04
SITE NAME MAYO PERMIT # NC0038377 SITE ID N/A
DUKE ENERGY PROCEDURE NPDES
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
35.83 50.83
N/A (psi)N/A (sec)(sec)
(gal)
@
YES
SAMPLING NOTES
Field Vehicle Accessable
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
QC By:EMY
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED Ferrous Iron
(mg/l)INITIAL PURGE VOLUME 0.25 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 0.50 (gal)EMY, ZAD 4/6/2016 13:50
DRAW-DOWN 1.23 (ft)
N/A
14:49 17.46 87 16 578 7.3 4.6 -72 0.32 N/A
13:46 17.30 93 16 578 7.3 4.3 -69 0.36
N/A
13:43 17.04 93 16 578 7.3 5.1 -64 0.43 N/A
13:40 16.84 104 16 575 7.3 9.3 -52 0.61
(recalculates on
current water
level)(hh:mm)(ft)(ml/min) (deg C) (umho/cm) (SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
Purge Start Date:4/6/2016 Purged To Dryness:
5.64
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 16.23 WATER COLUMN (ft)34.60 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)416.65 WELL VOLUME
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
2867-T SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)1/4 OD Low Flow
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2 TOC ELEV (ft msl) 432.88 MIDDLE OF WETTED SCREEN (ft TOC)43.33
SCREEN LENGTH (ft) 15.00 ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC) 50.83 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)44.00
PROJECT NAME NPDES COMPLIANCE - MONO FILL FIELD CREW RHJ, KDF, ZAC, EMY
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME MW-05
SITE NAME MAYO PERMIT # NC0038377 SITE ID N/A
DUKE ENERGY PROCEDURE NPDES
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
SITE NAME MAYO PERMIT # NC0038377 SITE ID N/A
DUKE ENERGY PROCEDURE NPDES
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME NPDES COMPLIANCE - MONO FILL FIELD CREW RHJ, KDF, ZAC, EMY
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME SW-01
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)MIDDLE OF WETTED SCREEN (ft TOC)0.00
SCREEN LENGTH (ft)ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)1/4 OD No Purge
DETECTED ODOR CONVERSION FACTOR
APPEARANCE
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
Purge Start Date:N/A Purged To Dryness:
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
RHJ, KDF 4/6/2016
LENGTH DEPTH (top) DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C) (umho/cm) (SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV -NEH)(mg/L)
N/A N/A N/A 10 191 7.1 12.3
10.40
262 77.80
NA
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE Ferrous (mg/l)Top Weight SAMPLE COLLECTED BY DATE
Turbidity > 10 NTU - After sampling, lower tubing/pump in
attempt to redevelop well QC By:RHJ
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
Field Vehicle Accessable
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
SITE NAME MAYO PERMIT # NC0038377 SITE ID N/A
DUKE ENERGY PROCEDURE NPDES
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME NPDES COMPLIANCE - MONO FILL FIELD CREW RHJ, KDF, ZAC, EMY
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME SW-02
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)MIDDLE OF WETTED SCREEN (ft TOC)0.00
SCREEN LENGTH (ft)ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)1/4 OD No Purge
DETECTED ODOR CONVERSION FACTOR
APPEARANCE
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
Purge Start Date:N/A Purged To Dryness:
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
RHJ, KDF 4/6/2016
LENGTH DEPTH (top) DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C) (umho/cm) (SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV -NEH)(mg/L)
N/A N/A n/a 10 124 7.2 9.7
11:35
315 10.12
NA
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE Ferrous (mg/l)Top Weight SAMPLE COLLECTED BY DATE
QC By:RHJ
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
Field Vehicle Accessable
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
SITE NAME MAYO PERMIT # NC0038377 SITE ID N/A
DUKE ENERGY PROCEDURE NPDES
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME NPDES COMPLIANCE - MONO FILL FIELD CREW RHJ, KDF, ZAC, EMY
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME SW-03
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)MIDDLE OF WETTED SCREEN (ft TOC)0.00
SCREEN LENGTH (ft)ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)1/4 OD No Purge
DETECTED ODOR CONVERSION FACTOR
APPEARANCE
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
Purge Start Date:N/A Purged To Dryness:
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
RHJ, KDF 4/6/2016
LENGTH DEPTH (top) DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C) (umho/cm) (SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV -NEH)(mg/L)
N/A N/A n/a 10 130 7.3
12:05
277 9.40
NA
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE Ferrous (mg/l)Top Weight SAMPLE COLLECTED BY DATE
QC By:RHJ
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
PROTECTIVE CASING Turbidity not read. Equipment malfunction.
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
Field Vehicle Accessable
Mayo Semiannual Groundwater Monitoring Report – April 2016 Sampling Event July 2016
Duke Energy Progress, LLC SynTerra
P:\Duke Energy Progress.1026\05.MAYO\17. 2016 Well Samping Monofill\APRIL 2016 SOLID WASTE PERMIT
REPORT\Final April 2016 Monofill Report.docx
APPENDIX B
LABORATORY REPORT AND CHAIN-OF-CUSTODY
FORMS
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16030338
Project Name:MAYO STEAM - LFGW
Lab Contact:Peggy Kendall
Date:5/2/2016
Customer Address:Mayo Steam Plant
Customer Name(s):J. TOEPFER, T. HUNSUCKER
10660 Boston Road
Roxboro,North Carolina 27574
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Peggy Kendall
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016007206 MAYO STEAM 06-Apr-16 9:20 AM Synterra MW-1
2016007207 MAYO STEAM 06-Apr-16 10:41 AM Synterra MW-2
2016007208 MAYO STEAM 06-Apr-16 12:15 PM Synterra MW-3
2016007209 MAYO STEAM 06-Apr-16 3:01 PM Synterra MW-4
2016007210 MAYO STEAM 06-Apr-16 1:50 PM Synterra MW-5
2016007211 MAYO STEAM 06-Apr-16 10:40 AM Synterra SW-1
2016007212 MAYO STEAM 06-Apr-16 11:35 AM Synterra SW-2
2016007213 MAYO STEAM 06-Apr-16 12:05 PM Synterra SW-3
2016007214 MAYO STEAM 06-Apr-16 9:20 AM Synterra DUP MW-1
2016007215 MAYO STEAM 06-Apr-16 12:25 PM Synterra FIELD BLANK
2016007216 MAYO STEAM 06-Apr-16 11:48 AM Synterra Filter Blank
2016007217 MAYO STEAM 06-Apr-16 Synterra Trip Blank
2016007218 MAYO STEAM 06-Apr-16 11:15 AM Synterra Leachate
13 Total Samples
Page 2 of 49
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:4/25/2016
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 49
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030338
2016007206
Collection Date:06-Apr-16 9:20 AM
Site:MW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 13 mg/L EPA 300.0 04/08/2016 05:04 BGN90340.5 5
Fluoride < 0.1 mg/L EPA 300.0 04/08/2016 05:04 BGN90340.1 1
Nitrate 5.8 mg/L EPA 300.0 04/08/2016 05:04 BGN90340.1 1
Nitrate as N 1.3 mg-N/L EPA 300.0 04/08/2016 05:04 BGN90340.023 1
Sulfate 19 mg/L EPA 300.0 04/08/2016 05:04 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/15/2016 10:08 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.160 mg/L EPA 200.7 04/12/2016 20:38 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/12/2016 20:38 JJMACKE0.05 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/12/2016 20:38 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/12/2016 20:38 JJMACKE0.005 1
Iron (Fe)0.092 mg/L EPA 200.7 04/12/2016 20:38 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 04/12/2016 20:38 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/12/2016 20:38 JJMACKE0.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 04/12/2016 20:38 JJMACKE0.005 1
Zinc (Zn)0.010 mg/L EPA 200.7 04/12/2016 20:38 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 04/13/2016 19:32 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/13/2016 19:32 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 04/13/2016 19:32 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/13/2016 19:32 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 190 mg/L SM2540C 04/09/2016 12:58 PARMSTR251
Page 4 of 49
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030338
2016007207
Collection Date:06-Apr-16 10:41 AM
Site:MW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 51 mg/L EPA 300.0 04/08/2016 05:49 BGN9034110
Fluoride 0.21 mg/L EPA 300.0 04/08/2016 05:49 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 300.0 04/08/2016 05:49 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 04/08/2016 05:49 BGN90340.023 1
Sulfate 43 mg/L EPA 300.0 04/08/2016 05:49 BGN90340.9307 9.307
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/15/2016 10:10 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.043 mg/L EPA 200.7 04/12/2016 20:27 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/12/2016 20:27 JJMACKE0.05 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/12/2016 20:27 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/12/2016 20:27 JJMACKE0.005 1
Iron (Fe)0.452 mg/L EPA 200.7 04/12/2016 20:27 JJMACKE0.01 1
Manganese (Mn)0.697 mg/L EPA 200.7 04/12/2016 20:27 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/12/2016 20:27 JJMACKE0.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 04/12/2016 20:27 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/12/2016 20:27 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 04/13/2016 19:49 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/13/2016 19:49 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 04/13/2016 19:49 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/13/2016 19:49 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 430 mg/L SM2540C 04/09/2016 12:58 PARMSTR251
Page 5 of 49
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030338
2016007208
Collection Date:06-Apr-16 12:15 PM
Site:MW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 82 mg/L EPA 300.0 04/08/2016 22:13 BGN9034220
Fluoride 0.29 mg/L EPA 300.0 04/08/2016 22:13 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 300.0 04/08/2016 22:13 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 04/08/2016 22:13 BGN90340.023 1
Sulfate 16 mg/L EPA 300.0 04/08/2016 22:13 BGN90340.353 3.53
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/15/2016 10:13 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.161 mg/L EPA 200.7 04/12/2016 20:42 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/12/2016 20:42 JJMACKE0.05 1
Chromium (Cr)0.032 mg/L EPA 200.7 04/12/2016 20:42 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/12/2016 20:42 JJMACKE0.005 1
Iron (Fe)0.514 mg/L EPA 200.7 04/12/2016 20:42 JJMACKE0.01 1
Manganese (Mn)0.368 mg/L EPA 200.7 04/12/2016 20:42 JJMACKE0.005 1
Nickel (Ni)0.021 mg/L EPA 200.7 04/12/2016 20:42 JJMACKE0.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 04/12/2016 20:42 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/12/2016 20:42 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 04/13/2016 19:54 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/13/2016 19:54 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 04/13/2016 19:54 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/13/2016 19:54 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 410 mg/L SM2540C 04/09/2016 12:58 PARMSTR251
Page 6 of 49
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030338
2016007209
Collection Date:06-Apr-16 3:01 PM
Site:MW-4
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 61 mg/L EPA 300.0 04/07/2016 22:59 BGN9034110
Fluoride 0.16 mg/L EPA 300.0 04/07/2016 22:59 BGN90340.1 1
Nitrate 0.38 mg/L EPA 300.0 04/07/2016 22:59 BGN90340.1 1
Nitrate as N 0.08 mg-N/L EPA 300.0 04/07/2016 22:59 BGN90340.023 1
Sulfate 87 mg/L EPA 300.0 04/07/2016 22:59 BGN90341.8 18
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/15/2016 10:15 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.231 mg/L EPA 200.7 04/13/2016 09:23 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/13/2016 09:23 JJMACKE0.05 1
Chromium (Cr)0.029 mg/L EPA 200.7 04/13/2016 09:23 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/13/2016 09:23 JJMACKE0.005 1
Iron (Fe)0.245 mg/L EPA 200.7 04/13/2016 09:23 JJMACKE0.01 1
Manganese (Mn)0.169 mg/L EPA 200.7 04/13/2016 09:23 JJMACKE0.005 1
Nickel (Ni)0.018 mg/L EPA 200.7 04/13/2016 09:23 JJMACKE0.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 04/13/2016 09:23 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/13/2016 09:23 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 04/13/2016 19:59 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/13/2016 19:59 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 04/13/2016 19:59 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/13/2016 19:59 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 570 mg/L SM2540C 04/09/2016 12:58 PARMSTR251
Page 7 of 49
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030338
2016007210
Collection Date:06-Apr-16 1:50 PM
Site:MW-5
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 14 mg/L EPA 300.0 04/07/2016 23:44 BGN90340.5 5
Fluoride 0.24 mg/L EPA 300.0 04/07/2016 23:44 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 300.0 04/07/2016 23:44 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 04/07/2016 23:44 BGN90340.023 1
Sulfate 12 mg/L EPA 300.0 04/07/2016 23:44 BGN90340.263 2.63
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/15/2016 10:18 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.008 mg/L EPA 200.7 04/12/2016 20:46 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/12/2016 20:46 JJMACKE0.05 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/12/2016 20:46 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/12/2016 20:46 JJMACKE0.005 1
Iron (Fe)0.155 mg/L EPA 200.7 04/12/2016 20:46 JJMACKE0.01 1
Manganese (Mn)0.086 mg/L EPA 200.7 04/12/2016 20:46 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/12/2016 20:46 JJMACKE0.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 04/12/2016 20:46 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/12/2016 20:46 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 04/14/2016 11:33 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2016 11:33 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 04/14/2016 11:33 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/14/2016 11:33 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 340 mg/L SM2540C 04/09/2016 12:58 PARMSTR251
Page 8 of 49
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030338
2016007211
Collection Date:06-Apr-16 10:40 AM
Site:SW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 5.0 mg/L EPA 300.0 04/08/2016 02:01 BGN90340.1 1
Fluoride 0.12 mg/L EPA 300.0 04/08/2016 02:01 BGN90340.1 1
Nitrate 0.20 mg/L EPA 300.0 04/08/2016 02:01 BGN90340.1 1
Nitrate as N 0.05 mg-N/L EPA 300.0 04/08/2016 02:01 BGN90340.023 1
Sulfate 4.2 mg/L EPA 300.0 04/08/2016 02:01 BGN90340.1 1
MERCURY IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/15/2016 10:20 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.044 mg/L EPA 200.7 04/12/2016 20:50 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/12/2016 20:50 JJMACKE0.05 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/12/2016 20:50 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/12/2016 20:50 JJMACKE0.005 1
Iron (Fe)0.701 mg/L EPA 200.7 04/12/2016 20:50 JJMACKE0.01 1
Manganese (Mn)0.191 mg/L EPA 200.7 04/12/2016 20:50 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/12/2016 20:50 JJMACKE0.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 04/12/2016 20:50 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/12/2016 20:50 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 04/13/2016 20:05 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/13/2016 20:05 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 04/13/2016 20:05 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/13/2016 20:05 JAHERMA11
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 140 mg/L SM2540C 04/11/2016 16:06 PARMSTR251
Page 9 of 49
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030338
2016007212
Collection Date:06-Apr-16 11:35 AM
Site:SW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 16 mg/L EPA 300.0 04/08/2016 03:09 BGN90340.5 5
Fluoride 0.24 mg/L EPA 300.0 04/08/2016 03:09 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 300.0 04/08/2016 03:09 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 04/08/2016 03:09 BGN90340.023 1
Sulfate 4.8 mg/L EPA 300.0 04/08/2016 03:09 BGN90340.1 1
MERCURY IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/15/2016 10:22 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.020 mg/L EPA 200.7 04/12/2016 20:54 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/12/2016 20:54 JJMACKE0.05 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/12/2016 20:54 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/12/2016 20:54 JJMACKE0.005 1
Iron (Fe)0.961 mg/L EPA 200.7 04/12/2016 20:54 JJMACKE0.01 1
Manganese (Mn)0.033 mg/L EPA 200.7 04/12/2016 20:54 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/12/2016 20:54 JJMACKE0.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 04/12/2016 20:54 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/12/2016 20:54 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 04/14/2016 11:11 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2016 11:11 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 04/14/2016 11:11 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/14/2016 11:11 JAHERMA11
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 78 mg/L SM2540C 04/11/2016 16:06 PARMSTR251
Page 10 of 49
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030338
2016007213
Collection Date:06-Apr-16 12:05 PM
Site:SW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 15 mg/L EPA 300.0 04/08/2016 03:55 BGN90340.5 5
Fluoride 0.21 mg/L EPA 300.0 04/08/2016 03:55 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 300.0 04/08/2016 03:55 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 04/08/2016 03:55 BGN90340.023 1
Sulfate 5.4 mg/L EPA 300.0 04/08/2016 03:55 BGN90340.1 1
MERCURY IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/15/2016 10:25 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.025 mg/L EPA 200.7 04/12/2016 20:58 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/12/2016 20:58 JJMACKE0.05 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/12/2016 20:58 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/12/2016 20:58 JJMACKE0.005 1
Iron (Fe)0.961 mg/L EPA 200.7 04/12/2016 20:58 JJMACKE0.01 1
Manganese (Mn)0.124 mg/L EPA 200.7 04/12/2016 20:58 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/12/2016 20:58 JJMACKE0.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 04/12/2016 20:58 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/12/2016 20:58 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 04/14/2016 11:16 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2016 11:16 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 04/14/2016 11:16 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/14/2016 11:16 JAHERMA11
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 80 mg/L SM2540C 04/11/2016 16:06 PARMSTR251
Page 11 of 49
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030338
2016007214
Collection Date:06-Apr-16 9:20 AM
Site:DUP MW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 13 mg/L EPA 300.0 04/08/2016 00:30 BGN90340.5 5
Fluoride < 0.1 mg/L EPA 300.0 04/08/2016 00:30 BGN90340.1 1
Nitrate 5.9 mg/L EPA 300.0 04/08/2016 00:30 BGN90340.131 1.31
Nitrate as N 1.3 mg-N/L EPA 300.0 04/08/2016 00:30 BGN90340.023 1
Sulfate 20 mg/L EPA 300.0 04/08/2016 00:30 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/15/2016 10:27 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.160 mg/L EPA 200.7 04/12/2016 21:01 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/12/2016 21:01 JJMACKE0.05 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/12/2016 21:01 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/12/2016 21:01 JJMACKE0.005 1
Iron (Fe)0.082 mg/L EPA 200.7 04/12/2016 21:01 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 04/12/2016 21:01 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/12/2016 21:01 JJMACKE0.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 04/12/2016 21:01 JJMACKE0.005 1
Zinc (Zn)0.012 mg/L EPA 200.7 04/12/2016 21:01 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 04/14/2016 11:22 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2016 11:22 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 04/14/2016 11:22 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/14/2016 11:22 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 190 mg/L SM2540C 04/11/2016 16:06 PARMSTR251
Page 12 of 49
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030338
2016007215
Collection Date:06-Apr-16 12:25 PM
Site:FIELD BLANK
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 04/08/2016 04:41 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 04/08/2016 04:41 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 300.0 04/08/2016 04:41 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 04/08/2016 04:41 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 300.0 04/08/2016 04:41 BGN90340.1 1
MERCURY IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/15/2016 10:42 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L EPA 200.7 04/12/2016 21:05 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/12/2016 21:05 JJMACKE0.05 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/12/2016 21:05 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/12/2016 21:05 JJMACKE0.005 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/12/2016 21:05 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 04/12/2016 21:05 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/12/2016 21:05 JJMACKE0.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 04/12/2016 21:05 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/12/2016 21:05 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 04/14/2016 11:27 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2016 11:27 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 04/14/2016 11:27 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/14/2016 11:27 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 04/11/2016 16:06 PARMSTR251
Page 13 of 49
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030338
2016007216
Collection Date:06-Apr-16 11:48 AM
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 14 of 49
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030338
2016007217
Collection Date:06-Apr-16
Site:Trip Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
MERCURY IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 15 of 49
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030338
2016007218
Collection Date:06-Apr-16 11:15 AM
Site:Leachate
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 39 mg/L EPA 300.0 04/07/2016 14:01 BGN9034110
Fluoride 0.18 mg/L EPA 300.0 04/07/2016 14:01 BGN90340.1 1
Nitrate 2.8 mg/L EPA 300.0 04/07/2016 14:01 BGN90340.1 1
Nitrate as N 0.63 mg-N/L EPA 300.0 04/07/2016 14:01 BGN90340.023 1
Sulfate 130 mg/L EPA 300.0 04/07/2016 14:01 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/15/2016 10:44 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.061 mg/L EPA 200.7 04/13/2016 09:34 JJMACKE0.005 1
Boron (B)1.27 mg/L EPA 200.7 04/13/2016 09:34 JJMACKE0.05 1
Chromium (Cr)0.026 mg/L EPA 200.7 04/13/2016 09:34 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/13/2016 09:34 JJMACKE0.005 1
Iron (Fe)0.416 mg/L EPA 200.7 04/13/2016 09:34 JJMACKE0.01 1
Manganese (Mn)0.008 mg/L EPA 200.7 04/13/2016 09:34 JJMACKE0.005 1
Nickel (Ni)0.034 mg/L EPA 200.7 04/13/2016 09:34 JJMACKE0.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 04/13/2016 09:34 JJMACKE0.005 1
Zinc (Zn)0.204 mg/L EPA 200.7 04/13/2016 09:34 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)14.7 ug/L EPA 200.8 04/14/2016 11:49 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2016 11:49 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 04/14/2016 11:49 JAHERMA11
Selenium (Se)1.70 ug/L EPA 200.8 04/14/2016 11:49 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 330 mg/L SM2540C 04/11/2016 16:06 PARMSTR251
Page 16 of 49
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030338
Q16040104 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0296 mg/L -10.0296 0.1 < 1/2 RDL
Fluoride 0.0441 mg/L -10.0441 0.1 < 1/2 RDL
Nitrate 0.012 mg/L -10.012 0.1 < 1/2 RDL
Sulfate -0.0018 mg/L -1-0.0018 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 6.35 5 101mg/L -1208016.35
Fluoride 5.34 5 106mg/L -1208015.34
Nitrate 5.19 5 104mg/L -1208015.19
Sulfate 6.99 5 104mg/L -1208016.99
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 6.35 5 101 0.00197mg/L -1208016.35
Fluoride 5.38 5 107 0.65mg/L -1208015.38
Nitrate 5.21 5 104 0.359mg/L -1208015.21
Sulfate 7 5 104 0.276mg/L -1208017
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 5.85 5 95.9mg/L -1208015.85
Fluoride 5.39 5 107mg/L -1208015.39
Nitrate 5.16 5 102mg/L -1208015.16
Sulfate 8.96 5 102mg/L -1208018.96
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 5.92 5 97.3 1.46mg/L -1208015.92
Fluoride 5.4 5 107 0.112mg/L -1208015.4
Nitrate 5.15 5 102 0.0449mg/L -1208015.15
Sulfate 8.95 5 102 0.237mg/L -1208018.95
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 4.99 5 99.8mg/L -1208014.99
Fluoride 5.47 5 109mg/L -1208015.47
Nitrate 5.14 5 103mg/L -1208015.14
Sulfate 5.17 5 103mg/L -1208015.17
Page 17 of 49
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030338
Q16040192 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.027 mg/L -10.027 0.1 < 1/2 RDL
Fluoride 0 mg/L -10 0.1 < 1/2 RDL
Nitrate 0 mg/L -10 0.1 < 1/2 RDL
Sulfate 0 mg/L -10 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 8.77 5 99.5mg/L -1208018.77
Fluoride 1.02 1 100mg/L -1208011.02
Nitrate 1.03 1 95.1mg/L -1208011.03
Sulfate 1.2 1 95.4mg/L -1208011.2
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 8.74 5 99 0.463mg/L -1208018.74
Fluoride 1.02 1 100 0.0999mg/L -1208011.02
Nitrate 1.03 1 95.3 0.21mg/L -1208011.03
Sulfate 1.2 1 95.6 0.209mg/L -1208011.2
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 7.78 5 97.1mg/L -1208017.78
Fluoride 1.03 1 99.9mg/L -1208011.03
Nitrate 2.63 1 95.7mg/L -1208011.16
Sulfate 2.32 1 95.1mg/L -1208011.14
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 7.78 5 97.1 0.0165mg/L -1208017.78
Fluoride 1.03 1 99.9 0mg/L -1208011.03
Nitrate 2.63 1 95.6 0.105mg/L -1208011.15
Sulfate 2.32 1 95 0.105mg/L -1208011.14
Final QualifierDilMeasuredUnits:Parameter
IS # 3
% Recovery LCL UCLSpike
Chloride 7.5 5 99.3mg/L -1208017.5
Fluoride 5mg/L -120801Not Tested
Nitrate 5mg/L -120801Not Tested
Sulfate 5mg/L -120801Not Tested
Page 18 of 49
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030338
Q16040192 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
ISD # 3
RPD% Recovery LCL UCLSpike
Chloride 7.52 5 99.7 0.452mg/L -1208017.52
Fluoride 5mg/L -120801Not Tested
Nitrate 5mg/L -120801Not Tested
Sulfate 5mg/L -120801Not Tested
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 4.82 5 96.4mg/L -1208014.82
Fluoride 2.02 2 101mg/L -1208012.02
Nitrate 1.94 2 97.2mg/L -1208011.94
Sulfate 1.95 2 97.6mg/L -1208011.95
Page 19 of 49
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030338
Q16040317 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.004 ug/L -10.004 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1 20 100ug/L -130702020.1
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 1 20 100 0.0998ug/L -130702020.1
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.02 100 102ug/L -13070100102
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Mercury (Hg) 1.03 100 103 1.07ug/L -13070100103
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.06 2 103ug/L -1158512.06
Page 20 of 49
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030338
Q16040208 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) -0.0002 mg/L -1-0.0002 0.005 < 1/2 RDL
Boron (B) 0.00192 mg/L -10.00192 0.05 < 1/2 RDL
Chromium (Cr) -0.000756 mg/L -1-0.000756 0.005 < 1/2 RDL
Copper (Cu) 0.00089 mg/L -10.00089 0.005 < 1/2 RDL
Iron (Fe) -0.000194 mg/L -1-0.000194 0.01 < 1/2 RDL
Manganese (Mn) 0.000019 mg/L -10.000019 0.005 < 1/2 RDL
Nickel (Ni) 0.000387 mg/L -10.000387 0.005 < 1/2 RDL
Silver (Ag) 0.000008 mg/L -10.000008 0.005 < 1/2 RDL
Zinc (Zn) -0.000079 mg/L -1-0.000079 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 5.08 5 102mg/L -1158515.08
Boron (B) 5.01 5 100mg/L -1158515.01
Chromium (Cr) 4.86 5 97.1mg/L -1158514.86
Copper (Cu) 4.96 5 99.3mg/L -1158514.96
Iron (Fe) 4.82 5 96.5mg/L -1158514.82
Manganese (Mn) 4.98 5 99.6mg/L -1158514.98
Nickel (Ni) 4.77 5 95.4mg/L -1158514.77
Silver (Ag) 0.505 0.5 101mg/L -1158510.505
Zinc (Zn) 4.82 5 96.5mg/L -1158514.82
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16030338 -- 2016007207
Barium (Ba) 5.21 5 104mg/L -1307015.21
Boron (B) 5.08 5 102mg/L -1307015.08
Chromium (Cr) 4.99 5 97.9mg/L -1307014.99
Copper (Cu) 4.82 5 101mg/L -1307014.82
Iron (Fe) 5.07 5 97.1mg/L -1307015.07
Manganese (Mn) 5.2 5 98.5mg/L -1307015.2
Nickel (Ni) 4.56 5 93.9mg/L -1307014.56
Silver (Ag) 0.491 0.5 101mg/L -1307010.491
Zinc (Zn) 4.69 5 95.2mg/L -1307014.69
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16030338 -- 2016007207
Barium (Ba) 5.23 5 104 0.365mg/L -1307015.23
Boron (B) 5.08 5 102 0.549mg/L -1307015.08
Chromium (Cr) 4.98 5 98 0.184mg/L -1307014.98
Copper (Cu) 4.83 5 102 1.42mg/L -1307014.83
Page 21 of 49
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030338
Q16040208 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16030338 -- 2016007207
Iron (Fe) 5.08 5 97.4 0.35mg/L -1307015.08
Manganese (Mn) 5.21 5 98.7 0.162mg/L -1307015.21
Nickel (Ni) 4.56 5 94 0.149mg/L -1307014.56
Silver (Ag) 0.49 0.5 102 0.849mg/L -1307010.49
Zinc (Zn) 4.69 5 94.5 0.801mg/L -1307014.69
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16030338 -- 2016007209
Barium (Ba)5mg/L -130701Not Tested
Boron (B)5mg/L -130701Not Tested
Chromium (Cr)5mg/L -130701Not Tested
Copper (Cu)5mg/L -130701Not Tested
Iron (Fe)5mg/L -130701Not Tested
Manganese (Mn)5mg/L -130701Not Tested
Nickel (Ni)5mg/L -130701Not Tested
Silver (Ag)0.5mg/L -130701Not Tested
Zinc (Zn)5mg/L -130701Not Tested
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16030338 -- 2016007209
Barium (Ba)5mg/L -130701Not Tested
Boron (B)5mg/L -130701Not Tested
Chromium (Cr)5mg/L -130701Not Tested
Copper (Cu)5mg/L -130701Not Tested
Iron (Fe)5mg/L -130701Not Tested
Manganese (Mn)5mg/L -130701Not Tested
Nickel (Ni)5mg/L -130701Not Tested
Silver (Ag)0.5mg/L -130701Not Tested
Zinc (Zn)5mg/L -130701Not Tested
Page 22 of 49
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030338
Q16040213 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As) 0.0004 ug/L -10.0004 1 < 1/2 RDL
Cadmium (Cd) 0.0093 ug/L -10.0093 1 < 1/2 RDL
Lead (Pb) 0.0124 ug/L -10.0124 1 < 1/2 RDL
Selenium (Se) -0.0217 ug/L -1-0.0217 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As) 48.5 50 97ug/L -11585148.5
Cadmium (Cd) 48 50 96ug/L -11585148
Lead (Pb) 47.5 50 95ug/L -11585147.5
Selenium (Se) 47.6 50 95.3ug/L -11585147.6
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16030338 -- 2016007206
Arsenic (As) 49.9 50 99.6ug/L -13070149.9
Cadmium (Cd) 49 50 98ug/L -13070149
Lead (Pb) 48.2 50 96.3ug/L -13070148.2
Selenium (Se) 48.6 50 96.8ug/L -13070148.6
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16030338 -- 2016007206
Arsenic (As) 49.6 50 99 0.573ug/L -13070149.6
Cadmium (Cd) 48.2 50 96.4 1.64ug/L -13070148.2
Lead (Pb) 47.3 50 94.5 1.9ug/L -13070147.3
Selenium (Se) 46.9 50 93.3 3.65ug/L -13070146.9
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16030338 -- 2016007210
Arsenic (As)50ug/L -130701Not Tested
Cadmium (Cd)50ug/L -130701Not Tested
Lead (Pb)50ug/L -130701Not Tested
Selenium (Se)50ug/L -130701Not Tested
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16030338 -- 2016007210
Arsenic (As)50ug/L -130701Not Tested
Cadmium (Cd)50ug/L -130701Not Tested
Lead (Pb)50ug/L -130701Not Tested
Selenium (Se)50ug/L -130701Not Tested
Page 23 of 49
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030338
Q16040162 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16030338 -- 2016007206
TDS 1.05mg/L -1192
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16030338 -- 2016007207
TDS 0.463mg/L -1433
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 96mg/L -11090196
Page 24 of 49
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030338
Q16040187 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16030238 -- 2016006726
TDS 0.44mg/L -11130
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16030238 -- 2016006746
TDS 1.09mg/L -1926
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J16030238 -- 2016006747
TDS 0.785mg/L -12030
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 97mg/L -11090197
Page 25 of 49
#=CL#
May 02, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92292974
92292974
Project:
Pace Project No.:
RE:
Program ManagerDuke Energy13339 Hagers Ferry RoadBldg. 7405 MG30A2Huntersville, NC 28078
J16030338
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on April 07, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analytepage for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Program Manager, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 23
Page 26 of 49
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92292974
J16030338
Ormond Beach Certification IDs8 East Tower Circle, Ormond Beach, FL 32174Alabama Certification #: 41320Connecticut Certification #: PH-0216Delaware Certification: FL NELAC ReciprocityFlorida Certification #: E83079Georgia Certification #: 955Guam Certification: FL NELAC ReciprocityHawaii Certification: FL NELAC ReciprocityIllinois Certification #: 200068Indiana Certification: FL NELAC ReciprocityKansas Certification #: E-10383Louisiana Certification #: FL NELAC ReciprocityLouisiana Environmental Certificate #: 05007Maryland Certification: #346Michigan Certification #: 9911Mississippi Certification: FL NELAC ReciprocityMissouri Certification #: 236Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14Nevada Certification: FL NELAC ReciprocityNew York Certification #: 11608North Carolina Environmental Certificate #: 667North Carolina Certification #: 12710North Dakota Certification #: R-216Oklahoma Certification #: D9947Pennsylvania Certification #: 68-00547Puerto Rico Certification #: FL01264South Carolina Certification: #96042001Tennessee Certification #: TN02974Texas Certification: FL NELAC ReciprocityUS Virgin Islands Certification: FL NELAC ReciprocityVirginia Environmental Certification #: 460165Wyoming Certification: FL NELAC ReciprocityWest Virginia Certification #: 9962CWisconsin Certification #: 399079670Wyoming (EPA Region 8): FL NELAC Reciprocity
Asheville Certification IDs2225 Riverside Drive, Asheville, NC 28804Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 23
Page 27 of 49
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92292974
J16030338
Lab ID Sample ID Matrix Date Collected Date Received
92292974001 2016007215 Water 04/06/16 12:25 04/07/16 15:15
92292974002 2016007217 Water 04/06/16 12:25 04/07/16 15:15
92292974003 2016007211 Water 04/06/16 10:40 04/07/16 15:15
92292974004 2016007212 Water 04/06/16 11:35 04/07/16 15:15
92292974005 2016007213 Water 04/06/16 12:05 04/07/16 15:15
92292974006 2016007216 Water 04/06/16 11:48 04/07/16 15:15
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 23
Page 28 of 49
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92292974
J16030338
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92292974001 2016007215 EPA 1631E 1 PASI-ASH1
92292974002 2016007217 EPA 1631E 1 PASI-ASH1
92292974003 2016007211 EPA 200.8 Rev 5.4 7 PASI-AJMW
EPA 1631E 1 PASI-ASH1
Trivalent Chromium Calculation 1 PASI-AEWS
EPA 218.6 1 PASI-OTK1
92292974004 2016007212 EPA 200.8 Rev 5.4 7 PASI-AJMW
EPA 1631E 1 PASI-ASH1
Trivalent Chromium Calculation 1 PASI-AEWS
EPA 218.6 1 PASI-OTK1
92292974005 2016007213 EPA 200.8 Rev 5.4 7 PASI-AJMW
EPA 1631E 1 PASI-ASH1
Trivalent Chromium Calculation 1 PASI-AEWS
EPA 218.6 1 PASI-OTK1
92292974006 2016007216 EPA 200.8 Rev 5.4 6 PASI-AJMW
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 23
Page 29 of 49
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92292974
J16030338
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92292974001 2016007215
Mercury 0.431J ng/L 04/18/16 12:270.50EPA 1631E
92292974003 2016007211
Chromium, Dissolved 0.53 ug/L 04/19/16 19:040.50EPA 200.8 Rev 5.4
Copper, Dissolved 4.7 ug/L 04/19/16 19:040.50EPA 200.8 Rev 5.4
Lead, Dissolved 0.51 ug/L 04/19/16 19:040.10EPA 200.8 Rev 5.4
Nickel, Dissolved 0.71 ug/L 04/19/16 19:040.50EPA 200.8 Rev 5.4
Zinc, Dissolved 32.9 ug/L 04/19/16 19:045.0EPA 200.8 Rev 5.4
Mercury 1.76 ng/L 04/18/16 12:570.50EPA 1631E
Chromium, Hexavalent 0.025 ug/L 04/14/16 15:51 M10.025EPA 218.6
92292974004 2016007212
Chromium, Dissolved 0.44J ug/L 04/18/16 23:300.50EPA 200.8 Rev 5.4
Copper, Dissolved 3.3 ug/L 04/18/16 23:300.50EPA 200.8 Rev 5.4
Lead, Dissolved 0.35 ug/L 04/19/16 19:260.10EPA 200.8 Rev 5.4
Zinc, Dissolved 7.3 ug/L 04/19/16 19:265.0EPA 200.8 Rev 5.4
Mercury 1.78 ng/L 04/18/16 13:050.50EPA 1631E
Chromium, Hexavalent 0.026 ug/L 04/14/16 15:380.025EPA 218.6
92292974005 2016007213
Chromium, Dissolved 0.27J ug/L 04/19/16 19:310.50EPA 200.8 Rev 5.4
Copper, Dissolved 2.0 ug/L 04/18/16 23:340.50EPA 200.8 Rev 5.4
Lead, Dissolved 0.20 ug/L 04/19/16 19:310.10EPA 200.8 Rev 5.4
Zinc, Dissolved 6.4 ug/L 04/19/16 19:315.0EPA 200.8 Rev 5.4
Mercury 1.66 ng/L 04/18/16 13:130.50EPA 1631E
Chromium, Hexavalent 0.045 ug/L 04/14/16 15:260.025EPA 218.6
92292974006 2016007216
Copper, Dissolved 7.7 ug/L 04/18/16 23:390.50EPA 200.8 Rev 5.4
Lead, Dissolved 0.90 ug/L 04/19/16 19:350.10EPA 200.8 Rev 5.4
Zinc, Dissolved 9.9 ug/L 04/19/16 19:355.0EPA 200.8 Rev 5.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 23
Page 30 of 49
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92292974
J16030338
Method:
Client:Duke Energy
EPA 200.8 Rev 5.4
Date:May 02, 2016
Description:200.8 MET ICPMS, Dissolved
General Information:
4 samples were analyzed for EPA 200.8 Rev 5.4. All samples were received in acceptable condition with any exceptions noted below oron the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 200.8 Rev 5.4 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 23
Page 31 of 49
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92292974
J16030338
Method:
Client:Duke Energy
EPA 1631E
Date:May 02, 2016
Description:1631E Mercury,Low Level
General Information:
5 samples were analyzed for EPA 1631E. All samples were received in acceptable condition with any exceptions noted below or on thechain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 1631E with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 23
Page 32 of 49
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92292974
J16030338
Method:
Client:Duke Energy
Trivalent Chromium Calculation
Date:May 02, 2016
Description:Trivalent Chromium Calculation
General Information:
3 samples were analyzed for Trivalent Chromium Calculation. All samples were received in acceptable condition with any exceptionsnoted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 23
Page 33 of 49
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92292974
J16030338
Method:
Client:Duke Energy
EPA 218.6
Date:May 02, 2016
Description:Hexavalent Chromium 28 Day
General Information:
3 samples were analyzed for EPA 218.6. All samples were received in acceptable condition with any exceptions noted below or on thechain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WETA/56833
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92292974003
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1540471)
• Chromium, Hexavalent
• MSD (Lab ID: 1540472)
• Chromium, Hexavalent
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 23
Page 34 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92292974
J16030338
Sample: 2016007215 Lab ID: 92292974001 Collected: 04/06/16 12:25 Received: 04/07/16 15:15 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 1631E Preparation Method: EPA 1631E1631E Mercury,Low Level
Mercury 0.431J ng/L 04/18/16 12:27 7439-97-604/18/16 10:450.50 0.25 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/02/2016 08:53 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 23
Page 35 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92292974
J16030338
Sample: 2016007217 Lab ID: 92292974002 Collected: 04/06/16 12:25 Received: 04/07/16 15:15 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 1631E Preparation Method: EPA 1631E1631E Mercury,Low Level
Mercury ND ng/L 04/18/16 12:34 7439-97-604/18/16 10:450.50 0.25 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/02/2016 08:53 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 23
Page 36 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92292974
J16030338
Sample: 2016007211 Lab ID: 92292974003 Collected: 04/06/16 10:40 Received: 04/07/16 15:15 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 200.8 Rev 5.4 Preparation Method: EPA 200.8 Rev 5.4200.8 MET ICPMS, Dissolved
Cadmium, Dissolved ND ug/L 04/19/16 19:04 7440-43-904/14/16 15:150.080 0.050 1
Chromium, Dissolved 0.53 ug/L 04/19/16 19:04 7440-47-304/14/16 15:150.50 0.090 1
Copper, Dissolved 4.7 ug/L 04/19/16 19:04 7440-50-804/14/16 15:150.50 0.11 1
Lead, Dissolved 0.51 ug/L 04/19/16 19:04 7439-92-104/14/16 15:150.10 0.090 1
Nickel, Dissolved 0.71 ug/L 04/19/16 19:04 7440-02-004/14/16 15:150.50 0.44 1
Silver, Dissolved ND ug/L 04/19/16 19:04 7440-22-404/14/16 15:150.50 0.070 1
Zinc, Dissolved 32.9 ug/L 04/19/16 19:04 7440-66-604/14/16 15:155.0 2.4 1
Analytical Method: EPA 1631E Preparation Method: EPA 1631E1631E Mercury,Low Level
Mercury 1.76 ng/L 04/18/16 12:57 7439-97-604/18/16 10:450.50 0.25 1
Analytical Method: Trivalent Chromium CalculationTrivalent Chromium Calculation
Chromium, Trivalent ND mg/L 04/29/16 13:36 16065-83-10.010 0.010 1
Analytical Method: EPA 218.6Hexavalent Chromium 28 Day
Chromium, Hexavalent 0.025 ug/L 04/14/16 15:51 18540-29-9 M10.025 0.0082 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/02/2016 08:53 AM
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Page 37 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92292974
J16030338
Sample: 2016007212 Lab ID: 92292974004 Collected: 04/06/16 11:35 Received: 04/07/16 15:15 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 200.8 Rev 5.4 Preparation Method: EPA 200.8 Rev 5.4200.8 MET ICPMS, Dissolved
Cadmium, Dissolved ND ug/L 04/19/16 19:26 7440-43-904/14/16 15:150.080 0.050 1
Chromium, Dissolved 0.44J ug/L 04/18/16 23:30 7440-47-304/14/16 15:150.50 0.090 1
Copper, Dissolved 3.3 ug/L 04/18/16 23:30 7440-50-804/14/16 15:150.50 0.11 1
Lead, Dissolved 0.35 ug/L 04/19/16 19:26 7439-92-104/14/16 15:150.10 0.090 1
Nickel, Dissolved ND ug/L 04/19/16 19:26 7440-02-004/14/16 15:150.50 0.44 1
Silver, Dissolved ND ug/L 04/19/16 19:26 7440-22-404/14/16 15:150.50 0.070 1
Zinc, Dissolved 7.3 ug/L 04/19/16 19:26 7440-66-604/14/16 15:155.0 2.4 1
Analytical Method: EPA 1631E Preparation Method: EPA 1631E1631E Mercury,Low Level
Mercury 1.78 ng/L 04/18/16 13:05 7439-97-604/18/16 10:450.50 0.25 1
Analytical Method: Trivalent Chromium CalculationTrivalent Chromium Calculation
Chromium, Trivalent ND mg/L 04/29/16 13:36 16065-83-10.010 0.010 1
Analytical Method: EPA 218.6Hexavalent Chromium 28 Day
Chromium, Hexavalent 0.026 ug/L 04/14/16 15:38 18540-29-90.025 0.0082 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/02/2016 08:53 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 23
Page 38 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92292974
J16030338
Sample: 2016007213 Lab ID: 92292974005 Collected: 04/06/16 12:05 Received: 04/07/16 15:15 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 200.8 Rev 5.4 Preparation Method: EPA 200.8 Rev 5.4200.8 MET ICPMS, Dissolved
Cadmium, Dissolved ND ug/L 04/19/16 19:31 7440-43-904/14/16 15:150.080 0.050 1
Chromium, Dissolved 0.27J ug/L 04/19/16 19:31 7440-47-304/14/16 15:150.50 0.090 1
Copper, Dissolved 2.0 ug/L 04/18/16 23:34 7440-50-804/14/16 15:150.50 0.11 1
Lead, Dissolved 0.20 ug/L 04/19/16 19:31 7439-92-104/14/16 15:150.10 0.090 1
Nickel, Dissolved ND ug/L 04/19/16 19:31 7440-02-004/14/16 15:150.50 0.44 1
Silver, Dissolved ND ug/L 04/19/16 19:31 7440-22-404/14/16 15:150.50 0.070 1
Zinc, Dissolved 6.4 ug/L 04/19/16 19:31 7440-66-604/14/16 15:155.0 2.4 1
Analytical Method: EPA 1631E Preparation Method: EPA 1631E1631E Mercury,Low Level
Mercury 1.66 ng/L 04/18/16 13:13 7439-97-604/18/16 10:450.50 0.25 1
Analytical Method: Trivalent Chromium CalculationTrivalent Chromium Calculation
Chromium, Trivalent ND mg/L 04/29/16 13:36 16065-83-10.010 0.010 1
Analytical Method: EPA 218.6Hexavalent Chromium 28 Day
Chromium, Hexavalent 0.045 ug/L 04/14/16 15:26 18540-29-90.025 0.0082 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/02/2016 08:53 AM
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Huntersville, NC 28078
[phone]
Page 14 of 23
Page 39 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92292974
J16030338
Sample: 2016007216 Lab ID: 92292974006 Collected: 04/06/16 11:48 Received: 04/07/16 15:15 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 200.8 Rev 5.4 Preparation Method: EPA 200.8 Rev 5.4200.8 MET ICPMS, Dissolved
Cadmium, Dissolved ND ug/L 04/19/16 19:35 7440-43-904/14/16 15:150.080 0.050 1
Copper, Dissolved 7.7 ug/L 04/18/16 23:39 7440-50-804/14/16 15:150.50 0.11 1
Lead, Dissolved 0.90 ug/L 04/19/16 19:35 7439-92-104/14/16 15:150.10 0.090 1
Nickel, Dissolved ND ug/L 04/19/16 19:35 7440-02-004/14/16 15:150.50 0.44 1
Silver, Dissolved ND ug/L 04/19/16 19:35 7440-22-404/14/16 15:150.50 0.070 1
Zinc, Dissolved 9.9 ug/L 04/19/16 19:35 7440-66-604/14/16 15:155.0 2.4 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/02/2016 08:53 AM
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Huntersville, NC 28078
[phone]
Page 15 of 23
Page 40 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92292974
J16030338
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/9271
EPA 1631E
EPA 1631E
1631E Mercury,Low Level
Associated Lab Samples: 92292974001, 92292974002, 92292974003, 92292974004, 92292974005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1712632
Associated Lab Samples:92292974001, 92292974002, 92292974003, 92292974004, 92292974005
Matrix: Water
AnalyzedMDL
Mercury ng/L ND 0.50 04/18/16 11:440.25
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1712633
Associated Lab Samples:92292974001, 92292974002, 92292974003, 92292974004, 92292974005
Matrix: Water
AnalyzedMDL
Mercury ng/L ND 0.50 04/18/16 13:510.25
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1712634
Associated Lab Samples:92292974001, 92292974002, 92292974003, 92292974004, 92292974005
Matrix: Water
AnalyzedMDL
Mercury ng/L ND 0.50 04/18/16 15:300.25
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1712635LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ng/L 4.685 94 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1712636MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293245015
1712637
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ng/L 25 81 71-12584 1 242542.2 62.5 63.3
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1712638MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92294023002
1712639
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ng/L 25 77 71-12579 1 24251.76 21.1 21.4
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/02/2016 08:53 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 23
Page 41 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92292974
J16030338
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/21369
EPA 200.8 Rev 5.4
EPA 200.8 Rev 5.4
200.8 MET Dissolved
Associated Lab Samples: 92292974003, 92292974004, 92292974005, 92292974006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1710124
Associated Lab Samples:92292974003, 92292974004, 92292974005, 92292974006
Matrix: Water
AnalyzedMDL
Cadmium, Dissolved ug/L ND 0.080 04/19/16 18:550.050
Chromium, Dissolved ug/L ND 0.50 04/19/16 18:550.090
Copper, Dissolved ug/L ND 0.50 04/19/16 18:550.11
Lead, Dissolved ug/L ND 0.10 04/19/16 18:550.090
Nickel, Dissolved ug/L ND 0.50 04/19/16 18:550.44
Silver, Dissolved ug/L ND 0.50 04/19/16 18:550.070
Zinc, Dissolved ug/L ND 5.0 04/19/16 18:552.4
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1710125LABORATORY CONTROL SAMPLE:
LCSSpike
Cadmium, Dissolved ug/L 103100 103 85-115
Chromium, Dissolved ug/L 102100 102 85-115
Copper, Dissolved ug/L 106100 106 85-115
Lead, Dissolved ug/L 106100 106 85-115
Nickel, Dissolved ug/L 105100 105 85-115
Silver, Dissolved ug/L 102100 102 85-115
Zinc, Dissolved ug/L 101100 101 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1710126MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92292974003
1710127
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cadmium, Dissolved ug/L 100 101 70-130107 5 20100ND101 107
Chromium, Dissolved ug/L 100 101 70-130106 4 201000.53 102 106
Copper, Dissolved ug/L 100 103 70-130108 5 201004.7 108 113
Lead, Dissolved ug/L 100 105 70-130109 4 201000.51 105 110
Nickel, Dissolved ug/L 100 101 70-130106 4 201000.71 102 106
Silver, Dissolved ug/L 100 100 70-130104 4 20100ND100 104
Zinc, Dissolved ug/L 100 74 70-13078 4 2010032.9 107 111
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1710128MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293173010
1710129
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cadmium, Dissolved ug/L 100 91 70-13090 1 20100ND91.1 89.8
Chromium, Dissolved ug/L 100 91 70-13092 1 201001.9 92.9 93.6
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/02/2016 08:53 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 23
Page 42 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92292974
J16030338
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1710128MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293173010
1710129
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Copper, Dissolved ug/L 100 90 70-13089 1 201002.1 92.5 91.6
Lead, Dissolved ug/L 100 93 70-13093 0 20100ND93.4 93.0
Nickel, Dissolved ug/L 100 91 70-13091 0 201001.8 92.3 92.6
Silver, Dissolved ug/L 100 106 70-130105 1 20100ND106 105
Zinc, Dissolved ug/L 100 85 70-13084 1 201004.8J 90.1 89.2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/02/2016 08:53 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 23
Page 43 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92292974
J16030338
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/56833
EPA 218.6
EPA 218.6
Chromium, Hexavalent by IC 28 Day
Associated Lab Samples: 92292974003, 92292974004, 92292974005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1540469
Associated Lab Samples:92292974003, 92292974004, 92292974005
Matrix: Water
AnalyzedMDL
Chromium, Hexavalent ug/L ND 0.025 04/14/16 11:340.0082
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1540470LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.070.075 94 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1540471MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92292974003
1540472
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.075 146 90-110140 3 20.0750.025 0.14 0.13
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/02/2016 08:53 AM
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Huntersville, NC 28078
[phone]
Page 19 of 23
Page 44 of 49
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92292974
J16030338
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/02/2016 08:53 AM
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[phone]
Page 20 of 23
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92292974
J16030338
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92292974003 MPRP/21369 ICPM/11582016007211EPA 200.8 Rev 5.4 EPA 200.8 Rev 5.4
92292974004 MPRP/21369 ICPM/11582016007212EPA 200.8 Rev 5.4 EPA 200.8 Rev 5.4
92292974005 MPRP/21369 ICPM/11582016007213EPA 200.8 Rev 5.4 EPA 200.8 Rev 5.4
92292974006 MPRP/21369 ICPM/11582016007216EPA 200.8 Rev 5.4 EPA 200.8 Rev 5.4
92292974001 MERP/9271 MERC/89052016007215EPA 1631E EPA 1631E
92292974002 MERP/9271 MERC/89052016007217EPA 1631E EPA 1631E
92292974003 MERP/9271 MERC/89052016007211EPA 1631E EPA 1631E
92292974004 MERP/9271 MERC/89052016007212EPA 1631E EPA 1631E
92292974005 MERP/9271 MERC/89052016007213EPA 1631E EPA 1631E
92292974003 WET/445892016007211Trivalent ChromiumCalculation
92292974004 WET/445892016007212Trivalent ChromiumCalculation
92292974005 WET/445892016007213Trivalent ChromiumCalculation
92292974003 WETA/568332016007211EPA 218.6
92292974004 WETA/568332016007212EPA 218.6
92292974005 WETA/568332016007213EPA 218.6
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/02/2016 08:53 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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