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0603-CDLF-1996_AveryCountyCDLF_GWMReport_DIN26445_20160420
This page intentionally left blank. April 2016 Semi-Annual Groundwater Monitoring Report Avery County C&D Landfill Spruce Pine, North Carolina NC Solid Waste Permit No. 06-03 Prepared for: Avery County Solid Waste 175 Linville Street Newland, North Carolina 28657 Prepared by: June 2016 © 2016 Smith Gardner, Inc. This document is intended for the sole use of the client for which it was prepared and for the purpose agreed on by the client and Smith Gardner, Inc. This page intentionally left blank. This page intentionally left blank. Avery County C&D Landfill April 2016 Semi-Annual Report June 2016 Table of Contents Page i Avery County C&D Landfill NC Solid Waste Permit No. 06-03 April 2016 Semi-Annual Groundwater Monitoring Report Table of Contents Page 1.0 INTRODUCTION ......................................................................................................... 1 2.0 SITE GEOLOGY AND HYDROGEOLOGY ....................................................................... 1 3.0 SAMPLING PROCEDURES ......................................................................................... 2 4.0 FIELD AND LABORATORY RESULTS .......................................................................... 3 4.1 Field Measurements ................................................................................................. 3 4.2 Laboratory Analysis ................................................................................................... 3 4.3 Laboratory Results .................................................................................................... 3 4.4 On-Site Potable Well ................................................................................................. 3 5.0 GROUNDWATER CHARACTERIZATION ...................................................................... 4 6.0 CONCLUSIONS .......................................................................................................... 4 FIGURES Figure 1 Potentiometric Surface Map TABLES Table 1 Groundwater Elevation Data Table 2 Field Parameters Table 3 Inorganic and Organic Detections Table 4 Indicator Parameters Table 5 Groundwater Velocity Calculation APPENDICES Appendix A Monitoring Well Information Appendix B Laboratory Analytical Report This page intentionally left blank. Avery County C&D Landfill April 2016 Semi-Annual Report June 2016 Page 1 1.0 INTRODUCTION Avery County C&D Landfill, currently operating under Solid Waste Permit # 06-03 (C&D) and 15A NCAC 13B.0544, is required to submit semi-annual groundwater monitoring reports. This report presents the semi-annual sampling results for the event conducted on April 19&20, 2016. The monitoring network for the C&D landfill includes four groundwater monitoring wells, a potable well, and two surface water points. This report includes a field parameter summary, laboratory analyses, a hydrogeologic evaluation, and groundwater velocity calculations. 2.0 SITE GEOLOGY AND HYDROGEOLOGY The Avery County C&D Landfill is located in the North Carolina Blue Ridge province, along the eastern limb of the Blue Ridge anticlinorium. Published geologic mapping1 places the site approximately twelve miles west of the Brevard Zone (measured perpendicular to strike), which is the boundary between the Blue Ridge Belt and the Piedmont. Local rock types comprise medium to high-grade metamorphic species of sedimentary origin, and plutonic rocks of mid Proterozoic age (>1000 MY) to Devonian age (390 MY). The rocks in the region tend to be highly jointed, due to the mechanical stresses imposed, with the older rocks typically exhibiting more complex jointing. The NC Geologic Map presents Alligator Back amphibolite underlying the higher, northern portion, surrounded by Alligator Back gneiss, including the lower, southern portion, with Grenville-age biotite gneiss existing close by to the east and Devonian quartz diorite further south. The surface topography reflects the underlying geology e.g., the southern, gentler slopes near Brushy Creek are probably indicative of the more deeply weathered micaceous gneiss and schist, whereas the steeper northern terrain likely results from the more resistant amphibolite. Test borings confirmed the gneiss and amphibolite contact. Hydrogeologic data from site permitting activities (2008-2009) established hydraulic conductivity for piezometers installed during that investigation. The following table illustrates hydraulic conductivity values from site piezometers, grouped relative to principal hydrogeologic units defined on the basis of material density. The field hydraulic conductivity values relative to each hydrogeologic unit vary as follows: 1 North Carolina Geologic Survey at http://www.geology.enr.state.nc.us Avery County C&D Landfill April 2016 Semi-Annual Report June 2016 Page 2 Hydro Unit Unit Description Conductivity (cm/sec) Maximum Minimum Average Conductivity (ft/day) Maximum Minimum Average 1A Saprolite <100 bpf 7.67 E-4 PZ-13i 3.42 E-4 PZ-12 4.92 E-4 2.17 PZ-13i 0.968 PZ-12 1.40 1B Saprolite <100 bpf 1.60 E-3 PZ-9 8.19 E-6 MW-3d 7.24 E-4 4.53 PZ-9 0.002 MW-3d 2.05 2 Bedrock 2.66 E-3 MW-1d 5.64 E-4 B-6 1.61 E-3 7.53 MW-1d 1.60 B-6 4.65 Conductivity data indicates a slight increasing trend with depth, potentially due to higher clay content in the upper soils, more sand-like conditions and fracturing at depth, as indicated by low Rock Quality Data (RQD) values gathered during bedrock drilling at the site. 3.0 SAMPLING PROCEDURES Smith Gardner, Inc. (S+G) personnel performed the sampling event in April 2016 in accordance with the approved Sampling and Analysis Plan2. Samples were collected from four groundwater wells (CDMW-1a, CDMW-2s, CDMW-3s and CDMW-4s), a potable well, and two surface water monitoring locations (SW-1 and SW-2). Sampling methods followed the protocol outlined in the North Carolina Water Quality Monitoring Guidance Document for Solid Waste Facilities3. The depth to water in each well was gauged prior to purging and sampling. Field measurements for pH, specific conductivity, turbidity and temperature were recorded at each sampling location. Samples from monitoring wells were collected using new factory sealed teflon bailers. The samples were placed in laboratory prepared containers for the specified analytical procedures. Groundwater samples were properly preserved, placed on ice and transported to a NC certified laboratory facility within the specified hold times for each analysis. Sampling locations are shown on Figure 1. Water table elevation data is presented in Table 1. Monitoring well information is provided in Appendix A. 2 Richardson Smith Gardner & Associates, Inc. Water Quality Monitoring Plan Avery County C&D Landfill Ingalls, North Carolina, February 2009. 3 Solid Waste Section Guidelines for Groundwater, Soil, and Surface Water Sampling, NCDENR, DWM, SWS, Rev. 4- 08. Avery County C&D Landfill April 2016 Semi-Annual Report June 2016 Page 3 4.0 FIELD AND LABORATORY RESULTS 4.1 Field Measurements Following purging, field parameters for temperature, pH, turbidity and specific conductance were measured. These results are summarized in Table 2. In general these measurements were consistent with data from previous events. 4.2 Laboratory Analysis Ground and surface water samples were transported to the Shealy Environmental Services, Inc. facility in West Columbia, SC for metals analysis via EPA Test Method 6020A and organics via EPA Test Method 8260B; alkalinity, total suspended solids, sulfate and chloride were analyzed via Solid Waste Section (SWS) approved methods. Samples were transported under proper chain of custody and analyzed at the specified Division of Waste Management (DWM) Solid Waste Quantitation Limits (SWSLs)4 for Appendix I and C&D landfill mandated constituents. The laboratory report is attached as Appendix B. 4.3 Laboratory Results No inorganic constituents were reported at concentrations above their 2L or GWP Standards in well samples collected this event. Vinyl Chloride was reported at a concentration above its 2L Standard in the sample collected from CDMW-3S this event. No inorganic or organic constituents were detected in surface water samples above the 2B Standard for Class C Waters. Detected constituents are presented in Table 3. Groundwater chemistry parameters are summarized in Table 4. 4.4 On-Site Potable Well In accordance with the Water Quality Monitoring Plan, the on site potable well was sampled this event. No constituents were detected above their 2L or GWP Standard for this event. 4 New Guidelines for Electronic Submittal of Environmental Monitoring Data Memo, NCDENR – Solid Waste Section, October 27, 2006 Avery County C&D Landfill April 2016 Semi-Annual Report June 2016 Page 4 5.0 GROUNDWATER CHARACTERIZATION A potentiometric surface map was prepared from groundwater data from this sampling event. The data indicates that groundwater is flowing generally in a southerly direction across the site. Hydraulic conductivity data is not available for these wells however; an average hydraulic conductivity and effective porosity from shallow wells across the site were used to evaluate groundwater velocities. Groundwater velocity ranges from 0.005 ft/day (CDMW-1A and CDMW- 3S) to 0.019 ft/day (CDMW-4S); average groundwater velocity for the site is 0.009 ft/day. The potentiometric surface map is included as Figure 1. 6.0 CONCLUSIONS Laboratory results indicate the water quality at the Avery County C&D Landfill is generally consistent with historically reported results. Only vinyl choride was reported above its 2L Standard in the sample collected from CDMW-3S this event. This is the first vinyl chloride detection as far back as data is available (2007). The next groundwater monitoring event is scheduled for October 2016. A report summarizing that event will be submitted to NCDEQ with laboratory analyses. FIGURE April 2016 Semi-Annual Groundwater Report Avery County C&D Landfill NC Solid Waste Permit No. 06-03 This page intentionally left blank. CDMW-2S TOC=2869.16 DTW=6.83 GWE=2862.33 CDMW-3S TOC=2914.76 DTW=8.17 GWE=2906.59 CDMW-1A TOC=2874.13 DTW=7.86 GWE=2866.27 CDMW-4S TOC=3035.85 DTW=14.77 GWE=3021.08 2890 2870 2910 2930 2950 3010 2970 2990 PHASE 1 APPROXIMATE FACILITY PROPERTY BOUNDARY (SEE REFERENCE 2) AVERY COUNTY TRANSFER STATION 0 200'400' PHASE 2 G: \ C A D \ A v e r y C o u n t y \ A v e r y 1 5 - 2 \ s h e e t s \ A V E R Y - B 0 2 6 2 . d w g - 5/ 2 7 / 2 0 1 6 1 2 : 0 6 P M SM I T H 14 N . B o y l a n A v e n u e , R a l e i g h N C 2 7 6 0 3 NC L I C . N O . C - 0 8 2 8 ( E N G I N E E R I N G ) 91 9 . 8 2 8 . 0 5 7 7 GA R D N E R + DR A W N : AP P R O V E D : PR O J E C T N O : SC A L E : FI L E N A M E : DA T E : FIG U R E N O . PR E P A R E D B Y : PR E P A R E D F O R : © 2016 Smith Gardner, Inc. AV E R Y C O U N T Y C & D L A N D F I L L PO T E N T I O M E T R I C S U R F A C E M A P AP R I L 2 0 1 6 T. R . S . M. M . G . AS S H O W N 1 Ma y 2 0 1 6 AV E R Y 1 4 - 2 AV E R Y - B 0 2 6 2 PHASE 3 MW-4D MW-1 TOC= DTW= GWE= Th i s p a g e i n t e n t i o n a l l y l e f t b l a n k . TABLES April 2016 Semi-Annual Groundwater Report Avery County C&D Landfill NC Solid Waste Permit No. 06-03 This page intentionally left blank. Ta b l e 1 Gr o u n d w a t e r E l e v a t i o n s Av e r y C o u n t y C & D L a n d f i l l Ap r i l 1 9 & 2 0 , 2 0 1 6 By: MG Date: 5/18/2016 We l l We l l In s t a l l a t i o n Da t e La t i t u d e L o n g i t u d e We l l Di a m e t e r (i n c h e s ) To t a l W e l l De p t h ( f t . bg s ) Gr o u n d Su r f a c e El e v a t i o n (f t . a m s l ) TO C El e v a t i o n (f t . a m s l ) De p t h t o Wa t e r ( f t . bg s ) Gr o u n d w a t e r El e v a t i o n ( f t . am s l ) Screen Interval (ft. bgs)Screen Geology CD M W - 1 a 1 0 / 2 9 / 2 0 0 9 3 5 . 9 5 9 1 9 8 1 . 9 6 9 5 6 2 1 3 . 0 0 2 8 7 0 . 3 2 2 8 7 4 . 1 3 7 . 8 6 2 8 6 6 . 2 7 4 ' - 1 2 c l a y e y s a n d y s i l t CD M W - 2 s N A 3 5 . 9 5 9 1 7 8 1 . 9 7 0 5 3 2 2 2 . 6 5 2 8 6 6 . 5 4 2 8 6 9 . 1 6 6 . 8 3 2 8 6 2 . 3 3 1 0 ' - 2 0 N A CD M W - 3 s N A 3 5 . 9 6 0 6 0 8 1 . 9 7 1 5 3 2 2 3 . 0 0 2 9 1 2 . 7 7 2 9 1 4 . 7 6 8 . 1 7 2 9 0 6 . 5 9 1 0 ' - 2 0 N A CD M W - 4 s 1 1 / 1 9 / 2 0 0 7 3 5 . 9 6 2 5 6 8 1 . 9 7 0 5 0 2 32 . 0 0 30 3 3 . 0 3 3 0 3 5 . 8 5 1 4 . 7 7 3 0 2 1 . 0 8 2 2 ' - 3 2 ' s a p r o l i t e No t e : 2. D e p t h t o W a t e r m e a s u r e d f r o m T o p o f C a s i n g 3. D a t a f o r C D M W - 1 a a n d C D M W - 4 s i s f r o m b o r i n g l o g s ( A p p e n d i x A ) 4. N o b o r i n g l o g s a v a i l a b l e f o r C D M W - 2 s a n d C D M W - 3 s 5. S c r e e n e d i n t e r v a l f o r C D M W - 2 s a n d C D M W - 3 s a s s u m e d b a s e d o n d e p t h t o b o t t o m m e a s u r e m e n t s . 1. S u r v e y d a t a f r o m 9 / 2 0 0 7 a n d 1 / 1 4 / 2 0 0 8 b y S u r v e y i n g S o l u t i o n s , P . C . a n d 1 / 1 1 / 2 0 1 0 b y Ap p a l a c h i a n P r o f e s s i o n a l L a n d S u r v e y o r s , a n d C o n s u l t a n t s , P A . H:\ P r o j e c t s \ G r o u n d w a t e r M o n i t o r i n g \ 2 . G r o u n d w a t e r M o n i t o r i n g R e p o r t s \ A v e r y c o u n t y \ A v e r y C & D R e p o r t \ 1 8 . A p r i l 2 0 1 6 \ a p r i l 1 6 A v e r y C & D t a b l e s . x l s Ta b l e 2 Fi e l d P a r a m e t e r s Av e r y C o u n t y C & D L a n d f i l l Ap r i l 1 9 & 2 0 , 2 0 1 6 By: MG Date:5/18/2016 We l l Te m p e r a t u r e (° C e l s i u s ) Tu r b i d i t y ( N T U ) Sp e c i f i c Co n d u c t i v i t y (M S / c m ) pH CD M W - 1 a 1 2 . 4 2 4 . 8 0 . 0 9 5 . 9 2 CD M W - 2 s 1 2 . 5 5 . 3 8 0 . 1 6 5 . 4 4 CD M W - 3 s 1 1 . 8 1 . 7 4 0 . 5 3 6 . 1 1 CD M W - 4 s 1 2 . 8 6 . 7 6 0 . 0 4 5 . 6 3 SW - 1 1 2 . 3 3 . 6 1 0 . 0 5 6 . 5 4 SW - 2 11 . 6 4 . 7 7 0 . 0 7 6 . 9 8 No t e : 1. p H m e a s u r e d w i t h a ' H a n n a " p H / E C / T D S M e t e r , t y p e H I 9 8 1 1 2. T e m p e r a t u r e m e a s u r e d w i t h a l a b o r a t o r y g r a d e t h e r m o m e t e r . 3. D a t a C o l l e c t e d b y S m i t h G a r d n e r , I n c . p e r s o n n e l A p r i l 2 0 , 2 0 1 6 . H:\ P r o j e c t s \ G r o u n d w a t e r M o n i t o r i n g \ 2 . G r o u n d w a t e r M o n i t o r i n g R e p o r t s \ A v e r y c o u n t y \ A v e r y C & D R e p o r t \ 1 8 . A p r i l 2 0 1 6 \ a p r i l 1 6 A v e r y C & D t a b l e s . x l s Ta b l e 3 In o r g a n i c a n d O r g a n i c D e t e c t i o n s Av e r y C o u n t y C & D L a n d f i l l Ap r i l 1 9 & 2 0 , 2 0 1 6 By: FH Date: 10/02/2015 Co n s t i t u e n t s M D L P Q L S W S L 2L o r G W P * St a n d a r d s MC L 2 B S t a n d a r d C D M W - 1 a C D M W - 2 s C D M W - 3 s C D M W - 4 s On-Site Potable WellSW-1 S W - 2 Ba r i u m 0 . 5 3 5 1 0 0 7 0 0 2 0 0 0 2 0 0 0 0 0 0 3 8 9 6 2 2 1 3 3 5 9 . 3 1 0 Be r y l l i u m 0 . 1 2 0 . 4 1 4 * 4 6 . 5 < 0 . 1 2 0 . 1 6 J < 0 . 1 2 0 . 1 3 J < 0 . 1 2 < 0 . 1 2 0 . 3 6 J Ca d m i u m 0 . 0 4 4 0 . 1 1 2 5 2 < 0 . 0 4 4 0 . 2 2 0 . 0 6 7 J < 0 . 0 4 4 < 0 . 0 4 4 < 0 . 0 4 4 < 0 . 0 4 4 Ch r o m i u m 0 . 6 3 5 1 0 1 0 N E 5 0 1 . 7 J < 0 . 6 3 1 . 5 J < 0 . 6 3 < 0 . 6 3 1 . 1 J < 0 . 6 3 Co b a l t 0 . 2 6 5 1 0 1 * 1 3 0 0 4 0 . 6 5 J 0 . 4 7 J 1 . 3 J < 0 . 2 6 < 0 . 2 6 0 . 4 1 J 0 . 3 6 J Co p p e r 0 . 1 5 1 1 0 1 0 0 0 1 3 0 0 7 1 . 6 0 . 7 5 J 1 . 9 0 . 4 1 J 2 1 . 5 1 . 1 Le a d 0 . 1 5 1 1 0 1 5 1 5 2 5 0 . 6 1 J < 0 . 1 5 0 . 3 0 J < 0 . 1 5 < 0 . 1 5 0 . 4 2 J 0 . 2 1 J Ni c k e l 0 . 6 3 5 5 0 1 0 0 N E 8 8 1 . 4 J 0 . 7 7 J 2 . 9 J < 0 . 6 3 < 0 . 6 3 0 . 6 8 J < 0 . 6 3 Va n a d i u m 1 5 2 5 0 . 3 * N E N E 3 . 1 J 1 . 5 J 4 . 1 J 1 J 1 . 1 J 2 . 6 J 2 J Zi n c 1 . 6 0 1 0 1 0 1 0 0 0 5 0 0 0 * * 5 0 1 0 5 . 3 J 1 3 3 . 8 J 6 J 1 6 9 . 2 J 1, 1 - D i c h l o r o e t h a n e 0 . 1 9 1 5 6 N E 1 0 0 < 0 . 1 9 0 . 4 5 J < 0 . 1 9 < 0 . 1 9 < 0 . 1 9 < 0 . 1 9 < 0 . 1 9 ci s - 1 , 2 - D i c h l o r o e t h e n e 0 . 2 1 5 7 0 N E 7 2 0 < 0 . 2 0 . 7 1 J < 0 . 2 < 0 . 2 < 0 . 2 < 0 . 2 < 0 . 2 Vi n y l C h l o r i d e 0 . 5 1 1 0 . 0 3 2 2 . 4 < 0 . 5 < 0 . 5 1. 4 <0 . 5 < 0 . 5 < 0 . 5 < 0 . 5 No t e : MD L - M e t h o d D e t e c t i o n L i m i t PQ L - P r a c t i c a l Q u a n t i t a l t i o n L i m i t SW S L - S o l i d W a s t e S e c t i o n Q u a n t i t a t i o n L i m i t 2L - Gr o u n d w a t e r S t a n d a r d ( 1 5 A N C A C 2 L 0 2 0 0 ) GW P - G r o u n d w a t e r P r o t e c t i o n S t a n d a r d ( n o t e d b y * ) MC L - Fe d e r a l M a x i m u m C o n t a m i n a n t L i m i t 2B - NC A C 2 B S t a n d a r d f o r C l a s s C w a t e r s < B R L - N o t d e t e c t e d a t o r a b o v e t h e R L Bo l d - L e v e l s a b o v e 2 L o r 2 B S t a n d a r d J - D e f i n e d b y t h e l a b o r a t o r y a s a n e s t i m a t e d r e s u l t < P Q L a n d ≥ M D L ** - N a t i o n a l S e c o n d a r y D r i n k i n g W a t e r S t a n d a r d s Re s u l t s a r e p r e s e n t e d i n u g / l . Da t a f r o m 5 / 4 / 1 6 S h e a l y E n v i r o n m e n t a l S e r v i c e s , I n c . , L o t N u m b e r R D 2 1 0 4 3 Or g a n i c In o r g a n i c H:\ P r o j e c t s \ G r o u n d w a t e r M o n i t o r i n g \ 2 . G r o u n d w a t e r M o n i t o r i n g R e p o r t s \ A v e r y c o u n t y \ A v e r y C & D R e p o r t \ 1 8 . A p r i l 2 0 1 6 \ a p r i l 1 6 A v e r y C & D t a b l e s . x l s Ta b l e 4 Gr o u n d w a t e r C h e m i s t r y P a r a m e t e r s Av e r y C o u n t y C & D L a n d f i l l Ap r i l 1 9 & 2 0 , 2 0 1 6 By: MG Date: 5/23/2016 Pa r a m e t e r M D L P Q L S W S L 2 L C D M W - 1 a C D M W - 2 s C D M W - 3 s C D M W - 4 s To t a l A l k a l i n i t y 1. 2 1 0 NE N E 3 1 2 9 1 6 0 9 . 5 J To t a l S u s p en d e d S o l i d s 0 . 3 4 1 NE N E 1 2 0 1 2 4 6 5 Ch l o r i d e 0 . 0 3 3 1 NE 2 5 0 1 . 1 7 6 . 6 0 . 7 6 J Su l f a t e 0 . 2 8 1 25 0 2 5 0 0 . 6 2 J 1 9 4 4 0 . 4 9 J No t e : 1. T a b l e d a t a a r e p re s e n t e d i n m g /l . 2. P Q L i s t h e l a b o r a t o r y p r a c t i c a l q u a n t i t a t i o n l i m i t 3. M D L = M e t h o d D e t e c t i o n L i m i t 4. S W S L = S o l i d W a s t e S e c t i o n L i m i t 5. 2 L = G r o u n d w a t e r S t a n d a r d ( 1 5 A N C A C 2 L 0 2 0 0 ) 6. J = D e f i n e d b y t h e l a b o r a t o r y a s a n e s t i m a t e d r e s u l t < P Q L a n d ≥ M D L 7. B R L = N o t d e t e c t e d a b o v e t h e l a b o r a t o r y e s t a b l i s h e d r e p o r t i n g l i m i t f o r t h i s p a r a m e t e r Da t a f r o m 5 / 4 / 1 6 S h e a l y E n v i r o n m e n t a l S e r v i c e s , I n c . , L o t N u m b e r R D 2 1 0 4 3 H:\ P r o j e c t s \ G r o u n d w a t e r M o n i t o r i n g \ 2 . G r o u n d w a t e r M o n i t o r i n g R e p o r t s \ A v e r y c o u n t y \ A v e r y C & D R e p o r t \ 1 8 . A p r i l 2 0 1 6 \ a p r i l 1 6 A v e r y C & D t a b l e s . x l s Ta b l e 5 Gr o u n d w a t e r V e l o c i t y C a l c u l a t i o n Av e r y C o u n t y C & D L a n d f i l l Ap r i l 1 9 & 2 0 , 2 0 1 6 By:MG Date: 5/31/2016 We l l Gr o u n d w a t e r El e v a t i o n ( f e e t ) Hy d r a u l i c Co n d u c t i v i t y (f t / d a y ) Po r o s i t y (% ) Gr a d i e n t ( f t / f t ) Ve l o c i t y (f t / d a y ) CD M W - 1 a 2 8 6 6 . 2 7 2 . 2 6 1 9 0 . 0 3 9 0 . 0 0 5 CD M W - 2 s 2 8 6 2 . 3 3 2 . 2 6 1 9 0 . 0 5 5 0 . 0 0 7 CD M W - 3 s 2 9 0 6 . 5 9 2 . 2 6 1 9 0 . 0 4 3 0 . 0 0 5 CD M W - 4 s 3 0 2 1 . 0 8 2 . 2 6 1 9 0 . 1 5 8 0 . 0 1 9 Av g V ( f t / d a y ) 0. 0 0 9 No t e : 2) H y d r a u l i c c o n d u c t i v i t y v a l u e s a r e a n a v e r a g e o f v a l u e s m e a s u r e d i n p i e z o m e t e r s d u r i n g P h a s e 3 P e r m i t t o Co n s t r u c t i n v e s t i g a t i o n 1) S u r v e y d a t a f r o m 9 / 2 0 0 7 a n d 1 / 1 4 / 2 0 0 8 b y S u r v e y i n g S o l u t i o n s , P . C . a n d 1 / 1 1 / 2 0 1 0 b y A p p a l a c h i a n P r o f e s s i o n a l La n d S u r v e y o r s , a n d C o n s u l t a n t s , P A . H:\ P r o j e c t s \ G r o u n d w a t e r M o n i t o r i n g \ 2 . G r o u n d w a t e r M o n i t o r i n g R e p o r t s \ A v e r y c o u n t y \ A v e r y C & D R e p o r t \ 1 8 . A p r i l 2 0 1 6 \ a p r i l 1 6 A v e r y C & D t a b l e s . x l s Th i s p a g e i n t e n t i o n a l l y l e f t b l a n k . Appendix A Monitoring Well Information April 2016 Semi-Annual Groundwater Report Avery County C&D Landfill NC Solid Waste Permit No. 06-03 This page intentionally left blank. FIELD BOREHOLE LOG BOREHOLE NUMBER PROJECT NAME: LOCATION: DRILLING CO: DRILLING METHOD: FIELD PARTY: GEOLOGIST: DATE BEGUN: COMPLETED: TOTAL DEPTH: TOP OF CASING ELEV.: Depth (ft) Time Date STATIC WATER LEVEL (BLS) DE P T H BL O W C O U N T SA M P L I N G M E T H O D RE C O V E R Y DR I L L M E T H O D DESCRIPTION LI T H O L O G Y WE L L IN S T A L L A T I O N 0.0 5.0 10.0 0.0 5.0 10.0 DE P T H Richardson Smith Gardner & Assoc 14 North Boylan Avenue, Raleigh NC 27603 (919) 828-0577 Page 1 of 1 GROUND ELEV.: NORTHING:EASTING:0 0 Pe r 6 " Fe e t In c h e s Fe e t MW-1a Geoprobe/HSA Avery County C&D Landfill Ingalls, NC Mad Dawg Drilling Inc Tom Whitehead Joan Smyth 10/26/09 10/26/09 13 Grab Grab Grab GP/HSA SANDY SILT: Dry micaceous brown sandy silt CLAYEY SANDY SILT: Dry brown micaceous clayey sandy silt. CLAYEY SANDY SILT: Clayey sandy silt to sandy clayey silt with relict structure. Wet at bottom of borehole. Auger refusal at 13'. (This was the deepest auger refusal of three attempted borings in this area). -- -- -- -- -- -- Appendix B Laboratory Analytical Report April 2016 Semi-Annual Groundwater Report Avery County C&D Landfill NC Solid Waste Permit No. 06-03 This page intentionally left blank. SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Smith Gardner, Inc. 14 North Boylan Avenue Raleigh, NC 27603 Attention: Madeline German RD21043Lot Number: Avery County C&DProject Name: 05/04/2016Date Completed: Kelly M. Nance Project Manager This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. Page: 1 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. Case Narrative Smith Gardner, Inc. Lot Number: RD21043 SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329 Project Name: Avery County C&D Project Number: This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. Inorganic Metals The method blank associated with batch 11519 had copper detected at a concentration that was above the MDL but below ½ the PQL. All samples associated with this method blank that have detections for copper have been flagged with a "B". Inorganic Non-Metals The method blank associated with batch 12419 had sulfate detected at a concentration that was above the MDL but below ½ the PQL. All samples associated with this method blank that have detections for sulfate have been flagged with a "B". Page: 2 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Smith Gardner, Inc. Lot Number: RD21043 Project Name: Avery County C&D Project Number: Sample Number Sample ID Matrix Date Sampled Date Received 001 04/20/2016 0945CDMW-1A Aqueous 04/21/2016 002 04/20/2016 1010CDMW-2S Aqueous 04/21/2016 003 04/20/2016 0920CDMW-3S Aqueous 04/21/2016 004 04/20/2016 0830CDMW-4S Aqueous 04/21/2016 005 04/20/2016 0855SW-1 Aqueous 04/21/2016 006 04/20/2016 1035SW-2 Aqueous 04/21/2016 007 04/20/2016 1100OfficeAqueous 04/21/2016 (7 samples) Page: 3 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Smith Gardner, Inc. Lot Number: RD21043 Project Name: Avery County C&D Project Number: Sample Sample ID Matrix Parameter Method Result Q Units Page 001 CDMW-1A Aqueous Alkalinity SM 2320B-31 mg/L 6 001 CDMW-1A Aqueous Chloride 9056A 1.1 mg/L 6 001 CDMW-1A Aqueous Sulfate 9056A 0.62 BJ mg/L 6 001 CDMW-1A Aqueous TSS SM 2540D-120 mg/L 6 001 CDMW-1A Aqueous Barium 6020A 38 ug/L 9 001 CDMW-1A Aqueous Chromium 6020A 1.7 J ug/L 9 001 CDMW-1A Aqueous Cobalt 6020A 0.65 J ug/L 9 001 CDMW-1A Aqueous Copper 6020A 1.6 B ug/L 9 001 CDMW-1A Aqueous Lead 6020A 0.61 J ug/L 9 001 CDMW-1A Aqueous Nickel 6020A 1.4 J ug/L 9 001 CDMW-1A Aqueous Vanadium 6020A 3.1 J ug/L 9 001 CDMW-1A Aqueous Zinc 6020A 10 ug/L 9 002 CDMW-2S Aqueous Alkalinity SM 2320B-29 mg/L 10 002 CDMW-2S Aqueous Chloride 9056A 7.0 mg/L 10 002 CDMW-2S Aqueous Sulfate 9056A 19 B mg/L 10 002 CDMW-2S Aqueous TSS SM 2540D-12 mg/L 10 002 CDMW-2S Aqueous 1,1-Dichloroethane 8260B 0.45 J ug/L 11 002 CDMW-2S Aqueous cis-1,2-Dichloroethene 8260B 0.71 J ug/L 11 002 CDMW-2S Aqueous Barium 6020A 96 ug/L 13 002 CDMW-2S Aqueous Beryllium 6020A 0.16 J ug/L 13 002 CDMW-2S Aqueous Cadmium 6020A 0.22 ug/L 13 002 CDMW-2S Aqueous Cobalt 6020A 0.47 J ug/L 13 002 CDMW-2S Aqueous Copper 6020A 0.75 BJ ug/L 13 002 CDMW-2S Aqueous Nickel 6020A 0.77 J ug/L 13 002 CDMW-2S Aqueous Vanadium 6020A 1.5 J ug/L 13 002 CDMW-2S Aqueous Zinc 6020A 5.3 J ug/L 13 003 CDMW-3S Aqueous Alkalinity SM 2320B-160 mg/L 14 003 CDMW-3S Aqueous Chloride 9056A 6.6 mg/L 14 003 CDMW-3S Aqueous Sulfate 9056A 44 B mg/L 14 003 CDMW-3S Aqueous TSS SM 2540D-46 mg/L 14 003 CDMW-3S Aqueous Vinyl chloride 8260B 1.4 ug/L 16 003 CDMW-3S Aqueous Barium 6020A 22 ug/L 17 003 CDMW-3S Aqueous Cadmium 6020A 0.067 J ug/L 17 003 CDMW-3S Aqueous Chromium 6020A 1.5 J ug/L 17 003 CDMW-3S Aqueous Cobalt 6020A 1.3 J ug/L 17 003 CDMW-3S Aqueous Copper 6020A 1.9 B ug/L 17 003 CDMW-3S Aqueous Lead 6020A 0.30 J ug/L 17 003 CDMW-3S Aqueous Nickel 6020A 2.9 J ug/L 17 003 CDMW-3S Aqueous Vanadium 6020A 4.1 J ug/L 17 003 CDMW-3S Aqueous Zinc 6020A 13 ug/L 17 004 CDMW-4S Aqueous Alkalinity SM 2320B-9.5 J mg/L 18 004 CDMW-4S Aqueous Chloride 9056A 0.76 J mg/L 18 004 CDMW-4S Aqueous Sulfate 9056A 0.49 BJ mg/L 18 Page: 4 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Executive Summary (Continued) Lot Number: RD21043 Sample Sample ID Matrix Parameter Method Result Q Units Page 004 CDMW-4S Aqueous TSS SM 2540D-5.0 mg/L 18 004 CDMW-4S Aqueous Barium 6020A 13 ug/L 21 004 CDMW-4S Aqueous Beryllium 6020A 0.13 J ug/L 21 004 CDMW-4S Aqueous Copper 6020A 0.41 BJ ug/L 21 004 CDMW-4S Aqueous Vanadium 6020A 1.0 J ug/L 21 004 CDMW-4S Aqueous Zinc 6020A 3.8 J ug/L 21 005 SW-1 Aqueous Barium 6020A 9.3 ug/L 24 005 SW-1 Aqueous Chromium 6020A 1.1 J ug/L 24 005 SW-1 Aqueous Cobalt 6020A 0.41 J ug/L 24 005 SW-1 Aqueous Copper 6020A 1.5 B ug/L 24 005 SW-1 Aqueous Lead 6020A 0.42 J ug/L 24 005 SW-1 Aqueous Nickel 6020A 0.68 J ug/L 24 005 SW-1 Aqueous Vanadium 6020A 2.6 J ug/L 24 005 SW-1 Aqueous Zinc 6020A 16 ug/L 24 006 SW-2 Aqueous Barium 6020A 10 ug/L 27 006 SW-2 Aqueous Cobalt 6020A 0.36 J ug/L 27 006 SW-2 Aqueous Copper 6020A 1.1 B ug/L 27 006 SW-2 Aqueous Lead 6020A 0.21 J ug/L 27 006 SW-2 Aqueous Vanadium 6020A 2.0 J ug/L 27 006 SW-2 Aqueous Zinc 6020A 9.2 J ug/L 27 007 Office Aqueous Barium 6020A 35 ug/L 30 007 Office Aqueous Copper 6020A 2.0 B ug/L 30 007 Office Aqueous Vanadium 6020A 1.1 J ug/L 30 007 Office Aqueous Zinc 6020A 6.0 J ug/L 30 (67 detections) Page: 5 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. CDMW-1A RD21043-001 04/20/2016 0945 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/28/2016 2028 MJI 12065 2 (Chloride) 9056A 1 05/03/2016 1746 SLU 12303 2 (Sulfate) 9056A 1 05/03/2016 0045 SLU 12419 1 (TSS) SM 2540D-2011 1 04/25/2016 0902 AMM1 11649 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Alkalinity SM 2320B-20 31 1mg/L1.210 Chloride 9056A 1.1 2mg/L0.0331.0 Sulfate 9056A 0.62 BJ 2mg/L0.281.0 TSS SM 2540D-20 120 1mg/L0.347.4 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 6 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. CDMW-1A RD21043-001 04/20/2016 0945 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 04/26/2016 1243 RAG 11786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Acetone 67-64-1 8260B ND 1ug/L1.620 Acrylonitrile 107-13-1 8260B ND 1ug/L0.6220 Benzene 71-43-2 8260B ND 1ug/L0.211.0 Bromochloromethane 74-97-5 8260B ND 1ug/L0.451.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L0.231.0 Bromoform 75-25-2 8260B ND 1ug/L0.351.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L0.192.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L1.810 Carbon disulfide 75-15-0 8260B ND 1ug/L0.451.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L0.311.0 Chlorobenzene 108-90-7 8260B ND 1ug/L0.201.0 Chloroethane 75-00-3 8260B ND 1ug/L0.282.0 Chloroform 67-66-3 8260B ND 1ug/L0.211.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L0.191.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L0.571.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L0.231.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L0.171.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L0.261.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L1.42.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L0.461.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L0.191.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L0.191.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L0.231.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L0.311.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L0.201.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L0.331.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L0.291.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L0.301.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L0.221.0 Ethylbenzene 100-41-4 8260B ND 1ug/L0.211.0 2-Hexanone 591-78-6 8260B ND 1ug/L0.2610 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L0.285.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L0.2910 Methylene chloride 75-09-2 8260B ND 1ug/L0.421.0 Styrene 100-42-5 8260B ND 1ug/L0.131.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L0.191.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L0.131.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L0.221.0 Tetrahydrofuran 109-99-9 8260B ND 1ug/L0.575.0 Toluene 108-88-3 8260B ND 1ug/L0.241.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L0.241.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L0.221.0 Trichloroethene 79-01-6 8260B ND 1ug/L0.161.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L0.741.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 7 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. CDMW-1A RD21043-001 04/20/2016 0945 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 04/26/2016 1243 RAG 11786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L0.351.0 Vinyl acetate 108-05-4 8260B ND 1ug/L1.05.0 Vinyl chloride 75-01-4 8260B ND 1ug/L0.501.0 Xylenes (total)1330-20-7 8260B ND 1ug/L0.321.0 m+p - Xylenes 179601-23-1 8260B ND 1ug/L0.191.0 o - Xylenes 95-47-6 8260B ND 1ug/L0.141.0 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 103 70-130 Bromofluorobenzene 100 70-130 Toluene-d8 102 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 8 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. CDMW-1A RD21043-001 04/20/2016 0945 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020A 1 04/25/2016 1630 BNW 04/22/2016 0841 11519 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Antimony 7440-36-0 6020A ND 1ug/L0.171.0 Arsenic 7440-38-2 6020A ND 1ug/L0.261.0 Barium 7440-39-3 6020A 38 1ug/L0.535.0 Beryllium 7440-41-7 6020A ND 1ug/L0.120.40 Cadmium 7440-43-9 6020A ND 1ug/L0.0440.10 Chromium 7440-47-3 6020A 1.7 J 1ug/L0.635.0 Cobalt 7440-48-4 6020A 0.65 J 1ug/L0.265.0 Copper 7440-50-8 6020A 1.6 B 1ug/L0.151.0 Lead 7439-92-1 6020A 0.61 J 1ug/L0.151.0 Nickel 7440-02-0 6020A 1.4 J 1ug/L0.635.0 Selenium 7782-49-2 6020A ND 1ug/L0.951.0 Silver 7440-22-4 6020A ND 1ug/L0.171.0 Thallium 7440-28-0 6020A ND 1ug/L0.0750.50 Vanadium 7440-62-2 6020A 3.1 J 1ug/L1.05.0 Zinc 7440-66-6 6020A 10 1ug/L1.610 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 9 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. CDMW-2S RD21043-002 04/20/2016 1010 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/28/2016 2032 MJI 12065 2 (Chloride) 9056A 1 05/03/2016 1810 SLU 12303 2 (Sulfate) 9056A 1 05/03/2016 0057 SLU 12419 1 (TSS) SM 2540D-2011 1 04/25/2016 0902 AMM1 11649 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Alkalinity SM 2320B-20 29 1mg/L1.210 Chloride 9056A 7.0 2mg/L0.0331.0 Sulfate 9056A 19 B 2mg/L0.281.0 TSS SM 2540D-20 12 1mg/L0.341.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 10 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. CDMW-2S RD21043-002 04/20/2016 1010 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 04/26/2016 1306 RAG 11786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Acetone 67-64-1 8260B ND 1ug/L1.620 Acrylonitrile 107-13-1 8260B ND 1ug/L0.6220 Benzene 71-43-2 8260B ND 1ug/L0.211.0 Bromochloromethane 74-97-5 8260B ND 1ug/L0.451.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L0.231.0 Bromoform 75-25-2 8260B ND 1ug/L0.351.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L0.192.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L1.810 Carbon disulfide 75-15-0 8260B ND 1ug/L0.451.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L0.311.0 Chlorobenzene 108-90-7 8260B ND 1ug/L0.201.0 Chloroethane 75-00-3 8260B ND 1ug/L0.282.0 Chloroform 67-66-3 8260B ND 1ug/L0.211.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L0.191.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L0.571.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L0.231.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L0.171.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L0.261.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L1.42.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L0.461.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L0.191.0 1,1-Dichloroethane 75-34-3 8260B 0.45 J 1ug/L0.191.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L0.231.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L0.311.0 cis-1,2-Dichloroethene 156-59-2 8260B 0.71 J 1ug/L0.201.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L0.331.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L0.291.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L0.301.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L0.221.0 Ethylbenzene 100-41-4 8260B ND 1ug/L0.211.0 2-Hexanone 591-78-6 8260B ND 1ug/L0.2610 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L0.285.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L0.2910 Methylene chloride 75-09-2 8260B ND 1ug/L0.421.0 Styrene 100-42-5 8260B ND 1ug/L0.131.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L0.191.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L0.131.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L0.221.0 Tetrahydrofuran 109-99-9 8260B ND 1ug/L0.575.0 Toluene 108-88-3 8260B ND 1ug/L0.241.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L0.241.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L0.221.0 Trichloroethene 79-01-6 8260B ND 1ug/L0.161.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L0.741.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 11 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. CDMW-2S RD21043-002 04/20/2016 1010 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 04/26/2016 1306 RAG 11786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L0.351.0 Vinyl acetate 108-05-4 8260B ND 1ug/L1.05.0 Vinyl chloride 75-01-4 8260B ND 1ug/L0.501.0 Xylenes (total)1330-20-7 8260B ND 1ug/L0.321.0 m+p - Xylenes 179601-23-1 8260B ND 1ug/L0.191.0 o - Xylenes 95-47-6 8260B ND 1ug/L0.141.0 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 102 70-130 Bromofluorobenzene 94 70-130 Toluene-d8 100 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 12 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. CDMW-2S RD21043-002 04/20/2016 1010 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020A 1 04/25/2016 1635 BNW 04/22/2016 0841 11519 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Antimony 7440-36-0 6020A ND 1ug/L0.171.0 Arsenic 7440-38-2 6020A ND 1ug/L0.261.0 Barium 7440-39-3 6020A 96 1ug/L0.535.0 Beryllium 7440-41-7 6020A 0.16 J 1ug/L0.120.40 Cadmium 7440-43-9 6020A 0.22 1ug/L0.0440.10 Chromium 7440-47-3 6020A ND 1ug/L0.635.0 Cobalt 7440-48-4 6020A 0.47 J 1ug/L0.265.0 Copper 7440-50-8 6020A 0.75 BJ 1ug/L0.151.0 Lead 7439-92-1 6020A ND 1ug/L0.151.0 Nickel 7440-02-0 6020A 0.77 J 1ug/L0.635.0 Selenium 7782-49-2 6020A ND 1ug/L0.951.0 Silver 7440-22-4 6020A ND 1ug/L0.171.0 Thallium 7440-28-0 6020A ND 1ug/L0.0750.50 Vanadium 7440-62-2 6020A 1.5 J 1ug/L1.05.0 Zinc 7440-66-6 6020A 5.3 J 1ug/L1.610 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 13 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. CDMW-3S RD21043-003 04/20/2016 0920 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/28/2016 2038 MJI 12065 2 (Chloride) 9056A 1 05/03/2016 1834 SLU 12303 2 (Sulfate) 9056A 1 05/03/2016 0134 SLU 12419 1 (TSS) SM 2540D-2011 1 04/25/2016 0902 AMM1 11649 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Alkalinity SM 2320B-20 160 1mg/L1.210 Chloride 9056A 6.6 2mg/L0.0331.0 Sulfate 9056A 44 B 2mg/L0.281.0 TSS SM 2540D-20 46 1mg/L0.342.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 14 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. CDMW-3S RD21043-003 04/20/2016 0920 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 04/26/2016 1329 RAG 11786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Acetone 67-64-1 8260B ND 1ug/L1.620 Acrylonitrile 107-13-1 8260B ND 1ug/L0.6220 Benzene 71-43-2 8260B ND 1ug/L0.211.0 Bromochloromethane 74-97-5 8260B ND 1ug/L0.451.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L0.231.0 Bromoform 75-25-2 8260B ND 1ug/L0.351.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L0.192.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L1.810 Carbon disulfide 75-15-0 8260B ND 1ug/L0.451.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L0.311.0 Chlorobenzene 108-90-7 8260B ND 1ug/L0.201.0 Chloroethane 75-00-3 8260B ND 1ug/L0.282.0 Chloroform 67-66-3 8260B ND 1ug/L0.211.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L0.191.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L0.571.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L0.231.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L0.171.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L0.261.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L1.42.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L0.461.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L0.191.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L0.191.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L0.231.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L0.311.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L0.201.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L0.331.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L0.291.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L0.301.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L0.221.0 Ethylbenzene 100-41-4 8260B ND 1ug/L0.211.0 2-Hexanone 591-78-6 8260B ND 1ug/L0.2610 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L0.285.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L0.2910 Methylene chloride 75-09-2 8260B ND 1ug/L0.421.0 Styrene 100-42-5 8260B ND 1ug/L0.131.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L0.191.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L0.131.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L0.221.0 Tetrahydrofuran 109-99-9 8260B ND 1ug/L0.575.0 Toluene 108-88-3 8260B ND 1ug/L0.241.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L0.241.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L0.221.0 Trichloroethene 79-01-6 8260B ND 1ug/L0.161.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L0.741.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 15 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. CDMW-3S RD21043-003 04/20/2016 0920 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 04/26/2016 1329 RAG 11786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L0.351.0 Vinyl acetate 108-05-4 8260B ND 1ug/L1.05.0 Vinyl chloride 75-01-4 8260B 1.4 1ug/L0.501.0 Xylenes (total)1330-20-7 8260B ND 1ug/L0.321.0 m+p - Xylenes 179601-23-1 8260B ND 1ug/L0.191.0 o - Xylenes 95-47-6 8260B ND 1ug/L0.141.0 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 102 70-130 Bromofluorobenzene 97 70-130 Toluene-d8 102 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 16 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. CDMW-3S RD21043-003 04/20/2016 0920 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020A 1 04/25/2016 1640 BNW 04/22/2016 0841 11519 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Antimony 7440-36-0 6020A ND 1ug/L0.171.0 Arsenic 7440-38-2 6020A ND 1ug/L0.261.0 Barium 7440-39-3 6020A 22 1ug/L0.535.0 Beryllium 7440-41-7 6020A ND 1ug/L0.120.40 Cadmium 7440-43-9 6020A 0.067 J 1ug/L0.0440.10 Chromium 7440-47-3 6020A 1.5 J 1ug/L0.635.0 Cobalt 7440-48-4 6020A 1.3 J 1ug/L0.265.0 Copper 7440-50-8 6020A 1.9 B 1ug/L0.151.0 Lead 7439-92-1 6020A 0.30 J 1ug/L0.151.0 Nickel 7440-02-0 6020A 2.9 J 1ug/L0.635.0 Selenium 7782-49-2 6020A ND 1ug/L0.951.0 Silver 7440-22-4 6020A ND 1ug/L0.171.0 Thallium 7440-28-0 6020A ND 1ug/L0.0750.50 Vanadium 7440-62-2 6020A 4.1 J 1ug/L1.05.0 Zinc 7440-66-6 6020A 13 1ug/L1.610 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 17 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. CDMW-4S RD21043-004 04/20/2016 0830 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/28/2016 2042 MJI 12065 2 (Chloride) 9056A 1 05/03/2016 1858 SLU 12303 2 (Sulfate) 9056A 1 05/03/2016 0146 SLU 12419 1 (TSS) SM 2540D-2011 1 04/25/2016 0902 AMM1 11649 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Alkalinity SM 2320B-20 9.5 J 1mg/L1.210 Chloride 9056A 0.76 J 2mg/L0.0331.0 Sulfate 9056A 0.49 BJ 2mg/L0.281.0 TSS SM 2540D-20 5.0 1mg/L0.341.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 18 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. CDMW-4S RD21043-004 04/20/2016 0830 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 04/26/2016 1351 RAG 11786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Acetone 67-64-1 8260B ND 1ug/L1.620 Acrylonitrile 107-13-1 8260B ND 1ug/L0.6220 Benzene 71-43-2 8260B ND 1ug/L0.211.0 Bromochloromethane 74-97-5 8260B ND 1ug/L0.451.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L0.231.0 Bromoform 75-25-2 8260B ND 1ug/L0.351.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L0.192.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L1.810 Carbon disulfide 75-15-0 8260B ND 1ug/L0.451.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L0.311.0 Chlorobenzene 108-90-7 8260B ND 1ug/L0.201.0 Chloroethane 75-00-3 8260B ND 1ug/L0.282.0 Chloroform 67-66-3 8260B ND 1ug/L0.211.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L0.191.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L0.571.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L0.231.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L0.171.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L0.261.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L1.42.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L0.461.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L0.191.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L0.191.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L0.231.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L0.311.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L0.201.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L0.331.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L0.291.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L0.301.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L0.221.0 Ethylbenzene 100-41-4 8260B ND 1ug/L0.211.0 2-Hexanone 591-78-6 8260B ND 1ug/L0.2610 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L0.285.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L0.2910 Methylene chloride 75-09-2 8260B ND 1ug/L0.421.0 Styrene 100-42-5 8260B ND 1ug/L0.131.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L0.191.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L0.131.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L0.221.0 Tetrahydrofuran 109-99-9 8260B ND 1ug/L0.575.0 Toluene 108-88-3 8260B ND 1ug/L0.241.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L0.241.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L0.221.0 Trichloroethene 79-01-6 8260B ND 1ug/L0.161.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L0.741.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 19 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. CDMW-4S RD21043-004 04/20/2016 0830 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 04/26/2016 1351 RAG 11786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L0.351.0 Vinyl acetate 108-05-4 8260B ND 1ug/L1.05.0 Vinyl chloride 75-01-4 8260B ND 1ug/L0.501.0 Xylenes (total)1330-20-7 8260B ND 1ug/L0.321.0 m+p - Xylenes 179601-23-1 8260B ND 1ug/L0.191.0 o - Xylenes 95-47-6 8260B ND 1ug/L0.141.0 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 103 70-130 Bromofluorobenzene 98 70-130 Toluene-d8 102 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 20 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. CDMW-4S RD21043-004 04/20/2016 0830 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020A 1 04/25/2016 1645 BNW 04/22/2016 0841 11519 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Antimony 7440-36-0 6020A ND 1ug/L0.171.0 Arsenic 7440-38-2 6020A ND 1ug/L0.261.0 Barium 7440-39-3 6020A 13 1ug/L0.535.0 Beryllium 7440-41-7 6020A 0.13 J 1ug/L0.120.40 Cadmium 7440-43-9 6020A ND 1ug/L0.0440.10 Chromium 7440-47-3 6020A ND 1ug/L0.635.0 Cobalt 7440-48-4 6020A ND 1ug/L0.265.0 Copper 7440-50-8 6020A 0.41 BJ 1ug/L0.151.0 Lead 7439-92-1 6020A ND 1ug/L0.151.0 Nickel 7440-02-0 6020A ND 1ug/L0.635.0 Selenium 7782-49-2 6020A ND 1ug/L0.951.0 Silver 7440-22-4 6020A ND 1ug/L0.171.0 Thallium 7440-28-0 6020A ND 1ug/L0.0750.50 Vanadium 7440-62-2 6020A 1.0 J 1ug/L1.05.0 Zinc 7440-66-6 6020A 3.8 J 1ug/L1.610 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 21 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. SW-1 RD21043-005 04/20/2016 0855 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 04/26/2016 1414 RAG 11786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Acetone 67-64-1 8260B ND 1ug/L1.620 Acrylonitrile 107-13-1 8260B ND 1ug/L0.6220 Benzene 71-43-2 8260B ND 1ug/L0.211.0 Bromochloromethane 74-97-5 8260B ND 1ug/L0.451.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L0.231.0 Bromoform 75-25-2 8260B ND 1ug/L0.351.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L0.192.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L1.810 Carbon disulfide 75-15-0 8260B ND 1ug/L0.451.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L0.311.0 Chlorobenzene 108-90-7 8260B ND 1ug/L0.201.0 Chloroethane 75-00-3 8260B ND 1ug/L0.282.0 Chloroform 67-66-3 8260B ND 1ug/L0.211.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L0.191.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L0.571.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L0.231.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L0.171.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L0.261.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L1.42.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L0.461.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L0.191.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L0.191.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L0.231.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L0.311.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L0.201.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L0.331.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L0.291.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L0.301.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L0.221.0 Ethylbenzene 100-41-4 8260B ND 1ug/L0.211.0 2-Hexanone 591-78-6 8260B ND 1ug/L0.2610 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L0.285.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L0.2910 Methylene chloride 75-09-2 8260B ND 1ug/L0.421.0 Styrene 100-42-5 8260B ND 1ug/L0.131.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L0.191.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L0.131.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L0.221.0 Tetrahydrofuran 109-99-9 8260B ND 1ug/L0.575.0 Toluene 108-88-3 8260B ND 1ug/L0.241.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L0.241.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L0.221.0 Trichloroethene 79-01-6 8260B ND 1ug/L0.161.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L0.741.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 22 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. SW-1 RD21043-005 04/20/2016 0855 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 04/26/2016 1414 RAG 11786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L0.351.0 Vinyl acetate 108-05-4 8260B ND 1ug/L1.05.0 Vinyl chloride 75-01-4 8260B ND 1ug/L0.501.0 Xylenes (total)1330-20-7 8260B ND 1ug/L0.321.0 m+p - Xylenes 179601-23-1 8260B ND 1ug/L0.191.0 o - Xylenes 95-47-6 8260B ND 1ug/L0.141.0 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 102 70-130 Bromofluorobenzene 97 70-130 Toluene-d8 100 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 23 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. SW-1 RD21043-005 04/20/2016 0855 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020A 1 04/25/2016 1651 BNW 04/22/2016 0841 11519 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Antimony 7440-36-0 6020A ND 1ug/L0.171.0 Arsenic 7440-38-2 6020A ND 1ug/L0.261.0 Barium 7440-39-3 6020A 9.3 1ug/L0.535.0 Beryllium 7440-41-7 6020A ND 1ug/L0.120.40 Cadmium 7440-43-9 6020A ND 1ug/L0.0440.10 Chromium 7440-47-3 6020A 1.1 J 1ug/L0.635.0 Cobalt 7440-48-4 6020A 0.41 J 1ug/L0.265.0 Copper 7440-50-8 6020A 1.5 B 1ug/L0.151.0 Lead 7439-92-1 6020A 0.42 J 1ug/L0.151.0 Nickel 7440-02-0 6020A 0.68 J 1ug/L0.635.0 Selenium 7782-49-2 6020A ND 1ug/L0.951.0 Silver 7440-22-4 6020A ND 1ug/L0.171.0 Thallium 7440-28-0 6020A ND 1ug/L0.0750.50 Vanadium 7440-62-2 6020A 2.6 J 1ug/L1.05.0 Zinc 7440-66-6 6020A 16 1ug/L1.610 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 24 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. SW-2 RD21043-006 04/20/2016 1035 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 04/26/2016 1437 RAG 11786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Acetone 67-64-1 8260B ND 1ug/L1.620 Acrylonitrile 107-13-1 8260B ND 1ug/L0.6220 Benzene 71-43-2 8260B ND 1ug/L0.211.0 Bromochloromethane 74-97-5 8260B ND 1ug/L0.451.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L0.231.0 Bromoform 75-25-2 8260B ND 1ug/L0.351.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L0.192.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L1.810 Carbon disulfide 75-15-0 8260B ND 1ug/L0.451.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L0.311.0 Chlorobenzene 108-90-7 8260B ND 1ug/L0.201.0 Chloroethane 75-00-3 8260B ND 1ug/L0.282.0 Chloroform 67-66-3 8260B ND 1ug/L0.211.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L0.191.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L0.571.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L0.231.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L0.171.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L0.261.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L1.42.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L0.461.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L0.191.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L0.191.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L0.231.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L0.311.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L0.201.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L0.331.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L0.291.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L0.301.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L0.221.0 Ethylbenzene 100-41-4 8260B ND 1ug/L0.211.0 2-Hexanone 591-78-6 8260B ND 1ug/L0.2610 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L0.285.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L0.2910 Methylene chloride 75-09-2 8260B ND 1ug/L0.421.0 Styrene 100-42-5 8260B ND 1ug/L0.131.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L0.191.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L0.131.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L0.221.0 Tetrahydrofuran 109-99-9 8260B ND 1ug/L0.575.0 Toluene 108-88-3 8260B ND 1ug/L0.241.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L0.241.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L0.221.0 Trichloroethene 79-01-6 8260B ND 1ug/L0.161.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L0.741.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 25 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. SW-2 RD21043-006 04/20/2016 1035 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 04/26/2016 1437 RAG 11786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L0.351.0 Vinyl acetate 108-05-4 8260B ND 1ug/L1.05.0 Vinyl chloride 75-01-4 8260B ND 1ug/L0.501.0 Xylenes (total)1330-20-7 8260B ND 1ug/L0.321.0 m+p - Xylenes 179601-23-1 8260B ND 1ug/L0.191.0 o - Xylenes 95-47-6 8260B ND 1ug/L0.141.0 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 101 70-130 Bromofluorobenzene 96 70-130 Toluene-d8 99 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 26 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. SW-2 RD21043-006 04/20/2016 1035 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020A 1 04/25/2016 1656 BNW 04/22/2016 0841 11519 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Antimony 7440-36-0 6020A ND 1ug/L0.171.0 Arsenic 7440-38-2 6020A ND 1ug/L0.261.0 Barium 7440-39-3 6020A 10 1ug/L0.535.0 Beryllium 7440-41-7 6020A ND 1ug/L0.120.40 Cadmium 7440-43-9 6020A ND 1ug/L0.0440.10 Chromium 7440-47-3 6020A ND 1ug/L0.635.0 Cobalt 7440-48-4 6020A 0.36 J 1ug/L0.265.0 Copper 7440-50-8 6020A 1.1 B 1ug/L0.151.0 Lead 7439-92-1 6020A 0.21 J 1ug/L0.151.0 Nickel 7440-02-0 6020A ND 1ug/L0.635.0 Selenium 7782-49-2 6020A ND 1ug/L0.951.0 Silver 7440-22-4 6020A ND 1ug/L0.171.0 Thallium 7440-28-0 6020A ND 1ug/L0.0750.50 Vanadium 7440-62-2 6020A 2.0 J 1ug/L1.05.0 Zinc 7440-66-6 6020A 9.2 J 1ug/L1.610 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 27 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. Office RD21043-007 04/20/2016 1100 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 04/26/2016 1459 RAG 11786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Acetone 67-64-1 8260B ND 1ug/L1.620 Acrylonitrile 107-13-1 8260B ND 1ug/L0.6220 Benzene 71-43-2 8260B ND 1ug/L0.211.0 Bromochloromethane 74-97-5 8260B ND 1ug/L0.451.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L0.231.0 Bromoform 75-25-2 8260B ND 1ug/L0.351.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L0.192.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L1.810 Carbon disulfide 75-15-0 8260B ND 1ug/L0.451.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L0.311.0 Chlorobenzene 108-90-7 8260B ND 1ug/L0.201.0 Chloroethane 75-00-3 8260B ND 1ug/L0.282.0 Chloroform 67-66-3 8260B ND 1ug/L0.211.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L0.191.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L0.571.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L0.231.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L0.171.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L0.261.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L1.42.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L0.461.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L0.191.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L0.191.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L0.231.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L0.311.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L0.201.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L0.331.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L0.291.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L0.301.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L0.221.0 Ethylbenzene 100-41-4 8260B ND 1ug/L0.211.0 2-Hexanone 591-78-6 8260B ND 1ug/L0.2610 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L0.285.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L0.2910 Methylene chloride 75-09-2 8260B ND 1ug/L0.421.0 Styrene 100-42-5 8260B ND 1ug/L0.131.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L0.191.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L0.131.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L0.221.0 Tetrahydrofuran 109-99-9 8260B ND 1ug/L0.575.0 Toluene 108-88-3 8260B ND 1ug/L0.241.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L0.241.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L0.221.0 Trichloroethene 79-01-6 8260B ND 1ug/L0.161.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L0.741.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 28 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. Office RD21043-007 04/20/2016 1100 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 04/26/2016 1459 RAG 11786 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L0.351.0 Vinyl acetate 108-05-4 8260B ND 1ug/L1.05.0 Vinyl chloride 75-01-4 8260B ND 1ug/L0.501.0 Xylenes (total)1330-20-7 8260B ND 1ug/L0.321.0 m+p - Xylenes 179601-23-1 8260B ND 1ug/L0.191.0 o - Xylenes 95-47-6 8260B ND 1ug/L0.141.0 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 101 70-130 Bromofluorobenzene 96 70-130 Toluene-d8 100 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 29 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Smith Gardner, Inc. Office RD21043-007 04/20/2016 1100 04/21/2016 Aqueous Project Name: Avery County C&D Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020A 1 04/25/2016 1701 BNW 04/22/2016 0841 11519 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Antimony 7440-36-0 6020A ND 1ug/L0.171.0 Arsenic 7440-38-2 6020A ND 1ug/L0.261.0 Barium 7440-39-3 6020A 35 1ug/L0.535.0 Beryllium 7440-41-7 6020A ND 1ug/L0.120.40 Cadmium 7440-43-9 6020A ND 1ug/L0.0440.10 Chromium 7440-47-3 6020A ND 1ug/L0.635.0 Cobalt 7440-48-4 6020A ND 1ug/L0.265.0 Copper 7440-50-8 6020A 2.0 B 1ug/L0.151.0 Lead 7439-92-1 6020A ND 1ug/L0.151.0 Nickel 7440-02-0 6020A ND 1ug/L0.635.0 Selenium 7782-49-2 6020A ND 1ug/L0.951.0 Silver 7440-22-4 6020A ND 1ug/L0.171.0 Thallium 7440-28-0 6020A ND 1ug/L0.0750.50 Vanadium 7440-62-2 6020A 1.1 J 1ug/L1.05.0 Zinc 7440-66-6 6020A 6.0 J 1ug/L1.610 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 30 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. QC Summary QC Data for Lot Number: RD21043 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - MB Batch: Sample ID:RQ11649-001 11649 Analytical Method:SM 2540D-2011 Matrix:Aqueous Parameter Result Q PQL MDL Units Analysis DateDil TSS ND 04/25/2016 09021.0 0.34 mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: RD21043 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - LCS Batch: Sample ID:RQ11649-002 11649 Analytical Method:SM 2540D-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) TSS 250 04/25/2016 090210025090-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: RD21043 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - MB Batch: Sample ID:RQ12065-001 12065 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q PQL MDL Units Analysis DateDil Alkalinity ND 04/28/2016 2009101.2 mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: RD21043 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - LCS Batch: Sample ID:RQ12065-002 12065 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Alkalinity 110 04/28/2016 201410810090-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: RD21043 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - MB Batch: Sample ID:RQ12303-001 12303 Analytical Method:9056A Matrix:Aqueous Parameter Result Q PQL MDL Units Analysis DateDil Chloride ND 05/03/2016 14501.0 0.033 mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: RD21043 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - LCS Batch: Sample ID:RQ12303-002 12303 Analytical Method:9056A Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Chloride 20 05/03/2016 1514982080-1201 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: RD21043 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - MS Batch: Sample ID:RD21043-002MS 12303 Analytical Method:9056A Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Chloride 26 05/03/2016 1922972080-1207.0 1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: RD21043 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - MSD Batch: Sample ID:RD21043-002MD 12303 Analytical Method:9056A Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Chloride 26 05/03/2016 1947962080-1200.68 207.0 1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: RD21043 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - MB Batch: Sample ID:RQ12419-001 12419 Analytical Method:9056A Matrix:Aqueous Parameter Result Q PQL MDL Units Analysis DateDil Sulfate 0.47 05/03/2016 0021J1.0 0.28 mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: RD21043 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - LCS Batch: Sample ID:RQ12419-002 12419 Analytical Method:9056A Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Sulfate 20 05/03/2016 00331022080-1201 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: RD21043 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - MS Batch: Sample ID:RD21043-002MS 12419 Analytical Method:9056A Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Sulfate 39 05/03/2016 01091002080-120191 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: RD21043 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - MSD Batch: Sample ID:RD21043-002MD 12419 Analytical Method:9056A Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Sulfate 39 05/03/2016 0121992080-1200.30 20191 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: RD21043 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - MB Batch:Prep Method: Sample ID:RQ11786-001 11786 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q PQL MDL Units Analysis DateDil Acetone ND 04/26/2016 1020201.6 ug/L1 Acrylonitrile ND 04/26/2016 1020200.62 ug/L1 Benzene ND 04/26/2016 10201.0 0.21 ug/L1 Bromochloromethane ND 04/26/2016 10201.0 0.45 ug/L1 Bromodichloromethane ND 04/26/2016 10201.0 0.23 ug/L1 Bromoform ND 04/26/2016 10201.0 0.35 ug/L1 Bromomethane (Methyl bromide)ND 04/26/2016 10202.0 0.19 ug/L1 2-Butanone (MEK)ND 04/26/2016 1020101.8 ug/L1 Carbon disulfide ND 04/26/2016 10201.0 0.45 ug/L1 Carbon tetrachloride ND 04/26/2016 10201.0 0.31 ug/L1 Chlorobenzene ND 04/26/2016 10201.0 0.20 ug/L1 Chloroethane ND 04/26/2016 10202.0 0.28 ug/L1 Chloroform ND 04/26/2016 10201.0 0.21 ug/L1 Chloromethane (Methyl chloride)ND 04/26/2016 10201.0 0.19 ug/L1 1,2-Dibromo-3-chloropropane (DBCP)ND 04/26/2016 10201.0 0.57 ug/L1 Dibromochloromethane ND 04/26/2016 10201.0 0.23 ug/L1 1,2-Dibromoethane (EDB)ND 04/26/2016 10201.0 0.17 ug/L1 Dibromomethane (Methylene bromide)ND 04/26/2016 10201.0 0.26 ug/L1 trans-1,4-Dichloro-2-butene ND 04/26/2016 10202.0 1.4 ug/L1 1,2-Dichlorobenzene ND 04/26/2016 10201.0 0.46 ug/L1 1,4-Dichlorobenzene ND 04/26/2016 10201.0 0.19 ug/L1 1,1-Dichloroethane ND 04/26/2016 10201.0 0.19 ug/L1 1,2-Dichloroethane ND 04/26/2016 10201.0 0.23 ug/L1 1,1-Dichloroethene ND 04/26/2016 10201.0 0.31 ug/L1 cis-1,2-Dichloroethene ND 04/26/2016 10201.0 0.20 ug/L1 trans-1,2-Dichloroethene ND 04/26/2016 10201.0 0.33 ug/L1 1,2-Dichloropropane ND 04/26/2016 10201.0 0.29 ug/L1 cis-1,3-Dichloropropene ND 04/26/2016 10201.0 0.30 ug/L1 trans-1,3-Dichloropropene ND 04/26/2016 10201.0 0.22 ug/L1 Ethylbenzene ND 04/26/2016 10201.0 0.21 ug/L1 2-Hexanone ND 04/26/2016 1020100.26 ug/L1 Methyl iodide (Iodomethane)ND 04/26/2016 10205.0 0.28 ug/L1 4-Methyl-2-pentanone ND 04/26/2016 1020100.29 ug/L1 Methylene chloride ND 04/26/2016 10201.0 0.42 ug/L1 Styrene ND 04/26/2016 10201.0 0.13 ug/L1 1,1,1,2-Tetrachloroethane ND 04/26/2016 10201.0 0.19 ug/L1 1,1,2,2-Tetrachloroethane ND 04/26/2016 10201.0 0.13 ug/L1 Tetrachloroethene ND 04/26/2016 10201.0 0.22 ug/L1 Tetrahydrofuran ND 04/26/2016 10205.0 0.57 ug/L1 Toluene ND 04/26/2016 10201.0 0.24 ug/L1 1,1,1-Trichloroethane ND 04/26/2016 10201.0 0.24 ug/L1 1,1,2-Trichloroethane ND 04/26/2016 10201.0 0.22 ug/L1 Trichloroethene ND 04/26/2016 10201.0 0.16 ug/L1 Trichlorofluoromethane ND 04/26/2016 10201.0 0.74 ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: RD21043 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - MB Batch:Prep Method: Sample ID:RQ11786-001 11786 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q PQL MDL Units Analysis DateDil 1,2,3-Trichloropropane ND 04/26/2016 10201.0 0.35 ug/L1 Vinyl acetate ND 04/26/2016 10205.0 1.0 ug/L1 Vinyl chloride ND 04/26/2016 10201.0 0.50 ug/L1 m+p - Xylenes ND 04/26/2016 10201.0 0.19 ug/L1 o - Xylenes ND 04/26/2016 10201.0 0.14 ug/L1 Xylenes (total)ND 04/26/2016 10201.0 0.32 ug/L1 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 99 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 104 70-130 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: RD21043 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - LCS Batch:Prep Method: Sample ID:RQ11786-002 11786 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Acetone 67 04/26/2016 08476710060-1401 Acrylonitrile 99 04/26/2016 08479910070-1301 Benzene 48 04/26/2016 0847975070-1301 Bromochloromethane 52 04/26/2016 08471055070-1301 Bromodichloromethane 52 04/26/2016 08471035070-1301 Bromoform 49 04/26/2016 0847975070-1301 Bromomethane (Methyl bromide)52 04/26/2016 08471045060-1401 2-Butanone (MEK)85 04/26/2016 08478510060-1401 Carbon disulfide 54 04/26/2016 08471085060-1401 Carbon tetrachloride 57 04/26/2016 08471135070-1301 Chlorobenzene 49 04/26/2016 0847975070-1301 Chloroethane 53 04/26/2016 08471055060-1401 Chloroform 52 04/26/2016 08471035070-1301 Chloromethane (Methyl chloride)46 04/26/2016 0847925060-1401 1,2-Dibromo-3-chloropropane (DBCP)41 04/26/2016 0847825070-1301 Dibromochloromethane 51 04/26/2016 08471025070-1301 1,2-Dibromoethane (EDB)47 04/26/2016 0847935070-1301 Dibromomethane (Methylene bromide)49 04/26/2016 0847975070-1301 trans-1,4-Dichloro-2-butene 57 04/26/2016 08471145034-1421 1,2-Dichlorobenzene 49 04/26/2016 0847985070-1301 1,4-Dichlorobenzene 46 04/26/2016 0847935070-1301 1,1-Dichloroethane 53 04/26/2016 08471065070-1301 1,2-Dichloroethane 48 04/26/2016 0847975070-1301 1,1-Dichloroethene 53 04/26/2016 08471055070-1301 cis-1,2-Dichloroethene 50 04/26/2016 0847995070-1301 trans-1,2-Dichloroethene 51 04/26/2016 08471035070-1301 1,2-Dichloropropane 49 04/26/2016 0847985070-1301 cis-1,3-Dichloropropene 51 04/26/2016 08471035070-1301 trans-1,3-Dichloropropene 50 04/26/2016 08471005070-1301 Ethylbenzene 49 04/26/2016 0847985070-1301 2-Hexanone 99 04/26/2016 08479910060-1401 Methyl iodide (Iodomethane)50 04/26/2016 08471015070-1301 4-Methyl-2-pentanone 96 04/26/2016 08479610060-1401 Methylene chloride 52 04/26/2016 08471035070-1301 Styrene 50 04/26/2016 08471005070-1301 1,1,1,2-Tetrachloroethane 51 04/26/2016 08471025070-1301 1,1,2,2-Tetrachloroethane 45 04/26/2016 0847905060-1401 Tetrachloroethene 51 04/26/2016 08471035070-1301 Tetrahydrofuran 44 04/26/2016 0847895070-1301 Toluene 50 04/26/2016 08471005070-1301 1,1,1-Trichloroethane 53 04/26/2016 08471065070-1301 1,1,2-Trichloroethane 46 04/26/2016 0847925070-1301 Trichloroethene 49 04/26/2016 0847995070-1301 Trichlorofluoromethane 57 04/26/2016 08471145070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: RD21043 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - LCS Batch:Prep Method: Sample ID:RQ11786-002 11786 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) 1,2,3-Trichloropropane 45 04/26/2016 0847895070-1301 Vinyl acetate 49 04/26/2016 0847985060-1401 Vinyl chloride 57 04/26/2016 08471135070-1301 m+p - Xylenes 52 04/26/2016 08471045070-1301 o - Xylenes 50 04/26/2016 08471015070-1301 Xylenes (total)100 04/26/2016 084710210070-1301 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 99 70-130 1,2-Dichloroethane-d4 100 70-130 Toluene-d8 104 70-130 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: RD21043 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS - MB Batch:Prep Method: Prep Date: Sample ID:RQ11519-001 11519 3005A 04/22/2016 841Analytical Method:6020A Matrix:Aqueous Parameter Result Q PQL MDL Units Analysis DateDil Antimony ND 04/25/2016 15161.0 0.17 ug/L1 Arsenic ND 04/25/2016 15161.0 0.26 ug/L1 Barium ND 04/25/2016 15165.0 0.53 ug/L1 Beryllium ND 04/25/2016 15160.40 0.12 ug/L1 Cadmium ND 04/25/2016 15160.10 0.044 ug/L1 Chromium ND 04/25/2016 15165.0 0.63 ug/L1 Cobalt ND 04/25/2016 15165.0 0.26 ug/L1 Copper 0.25 04/25/2016 1516J1.0 0.15 ug/L1 Lead ND 04/25/2016 15161.0 0.15 ug/L1 Nickel ND 04/25/2016 15165.0 0.63 ug/L1 Selenium ND 04/25/2016 15161.0 0.95 ug/L1 Silver ND 04/25/2016 15161.0 0.17 ug/L1 Thallium ND 04/25/2016 15160.50 0.075 ug/L1 Vanadium ND 04/25/2016 15165.0 1.0 ug/L1 Zinc ND 04/25/2016 1516101.6 ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: RD21043 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-MS - LCS Batch:Prep Method: Prep Date: Sample ID:RQ11519-002 11519 3005A 04/22/2016 841Analytical Method:6020A Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Antimony 100 04/25/2016 152210010080-1201 Arsenic 100 04/25/2016 152210110080-1201 Barium 100 04/25/2016 152210310080-1201 Beryllium 100 04/25/2016 152210210080-1201 Cadmium 99 04/25/2016 15229910080-1201 Chromium 99 04/25/2016 15229910080-1201 Cobalt 100 04/25/2016 152210110080-1201 Copper 100 04/25/2016 152210210080-1201 Lead 100 04/25/2016 152210110080-1201 Nickel 100 04/25/2016 152210010080-1201 Selenium 100 04/25/2016 152210510080-1201 Silver 100 04/25/2016 152210410080-1201 Thallium 100 04/25/2016 152210210080-1201 Vanadium 99 04/25/2016 15229910080-1201 Zinc 100 04/25/2016 152210110080-1201 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: RD21043 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Chain of Custody and Miscellaneous Documents 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc.