1203_BurkeCounty_GWMReport_DIN26408_20160204

PREPARED FOR:
BOARD OF COMMISSIONERS
COUNTY OF BURKE
P.O. BOX 1486
MORGANTON, NORTH CAROLINA 28680

JOHN’S RIVER WASTE MANAGEMENT FACILITY
PERMIT NO. 12-03
C&D-OVER-MSW LANDFILL

SECOND SEMIANNUAL WATER QUALITY
MONITORING REPORT OF 2015

APRIL 2016

PREPARED BY:

2211 WEST MEADOWVIEW ROAD, SUITE 101
GREENSBORO, NORTH CAROLINA 27407
NC LICENSE NUMBER C-0782
PHONE: [phone]
FAX: [phone]
JOYCE PROJECT NO. 277.1601.12

Second Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering
Burke County – John’s River C&D Over MSW Landfill, Permit No. 12-03 April 2016
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Second Semiannual Water Quality Monitoring Report of 2015
John’s River Waste Management Facility – Permit No. 12-03
C&D-over-MSW Landfill
Burke County, North Carolina

TABLE OF CONTENTS

1.0 INTRODUCTION..............................................................................................................1 
1.1 Site Information ........................................................................................................................1 
1.2 Site Geology .............................................................................................................................1 
1.3 Regulatory Status .....................................................................................................................2 
1.4 Groundwater Monitoring History .............................................................................................2 
2.0 FACILITY MONITORING PROGRAM .......................................................................3 
2.1 Groundwater Monitoring Program ...........................................................................................3 
2.2 Surface Water Monitoring Program .........................................................................................5 
3.0 SECOND SEMIANNUAL SAMPLING EVENT OF 2015 ............................................6 
3.1 Field Work ................................................................................................................................6 
3.2 Laboratory Analysis and JOYCE Quality Control ...................................................................7 
4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSIS .....................................8 
4.1 Analytical Results for Inorganic Constituents ..........................................................................8 
4.2 Analytical Results for Organic Constituents ............................................................................9 
4.3 Statistical Analyses ...................................................................................................................9 
4.3.1 Statistical Methods and Background .................................................................................. 9 
4.3.2 Statistical Analyses of Inorganic Constituents ................................................................. 10 
4.4 Analytical Results for Surface Water .....................................................................................10 
5.0 EVALUATION OF MONITORED NATURAL ATTENUATION (MNA) ..............10 
5.1 MNA Parameters and Biodegradation Screening Matrix .......................................................10 
5.2 Biochlor Modeling and Mass-Balance Assessment ...............................................................12 
5.3 Trend Analysis and Plume Stability .......................................................................................13 
6.0 HYDROGEOLOGICAL CONDITIONS ......................................................................13 
7.0 CONCLUSIONS ..............................................................................................................14 
8.0 REFERENCES .................................................................................................................15 
9.0 ACRONYMS ....................................................................................................................16 

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TABLE OF CONTENTS (CONTINUED)

Tables:
Table 1 Historical Groundwater Elevation Data
Table 2 Field Parameters (December 2015) Table 3 Quantified Detections of Groundwater Constituents (December 2015)
Table 4 Exceedances of Groundwater Standards (December 2015) Table 5 Statistical Background Analyses
Table 6 MNA Parameters (December 2015)
Table 7 Biodegradation Screening Matrix Table 8 Hydraulic Gradients and Groundwater Flow Velocities

Charts:
Chart 1 Benzene Concentrations vs. Time
Chart 2 1,4-Dichlorobenzene Concentrations vs. Time
Chart 3 1,1-Dichloroethane Concentrations vs. Time
Chart 4 1,2-Dichloroethane Concentrations vs. Time
Chart 5 Tetrachloroethylene (PCE) Concentrations vs. Time
Chart 6 Trichloroethylene (TCE) Concentrations vs. Time
Chart 7 Vinyl Chloride Concentrations vs. Time
Chart 8 Methylene Chloride Concentrations vs. Time
Chart 9 alpha-BHC Concentrations vs. Time
Chart 10 beta-BHC Concentrations vs. Time
Figure:
Figure 1 Site Location Map

Drawing:
Drawing 1 Groundwater Potentiometric Surface Map

Appendices:
Appendix A Field Data Logs
Appendix B Laboratory Analytical Reports
Appendix C Statistical Analyses Worksheets
Appendix D Historical Detected Inorganic Groundwater Constituents
Appendix E Historical Detected Organic Groundwater Constituents
Appendix F Historical Detected Constituents in Performance & Sentinel Wells
Appendix G Historical Detected Surface Water Constituents
Appendix H Historical MNA Parameters
Appendix I Biochlor Modeling Input & Output

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1.0 INTRODUCTION
1.1 Site Information
The Johns River Waste Management Facility (JRWMF) is located in the north-central portion of
Burke County, north of Morganton, North Carolina. The 318-acre landfill property is bounded
by Lower Creek to the north and east, and the Catawba River to the south. The Catawba River
forms Lake Rhodhiss along the southeastern property line (Figure 1). Lake Rhodhiss is a long,
narrow lake formed by the Rhodhiss Hydroelectric Dam located approximately 12 miles
downstream of the landfill. The John’s River flows into the Catawba River near the southwest
corner of the landfill property.

The site has rolling topography with elevations ranging from 975 feet to 1,150 feet above mean
sea level (MSL). The central portion is generally gently sloping and contains the higher
elevations; relatively steep slopes and significant drainage features are located around the
perimeter. The 100-year flood boundary extends onto the landfill property. The adjacent
property to the west of the Johns River Waste Management Facility consists of undeveloped,
heavily wooded land. Properties within 2,000 feet of the landfill boundary are covered by
surface water or are heavily wooded.

The unlined waste disposal unit consists of 28 acres in the southwest corner of the landfill
property. The municipal solid waste (MSW) landfill began operation in April 1988, but was
closed to comply with Rule .1627(c)(10)(A) of the NCSWMR, a regulation governing MSW
Landfills units that were not designed with a base liner and leachate collection system. Burke
County has operated a permitted Construction and Demolition (C&D) disposal area on top of the
closed portions of the MSW landfill since 1998. A MSW transfer facility is located in the
eastern half of the property. In 2014, Phase 1A of the C&D expansion was constructed
northeast of the C&D over MSW landfill. Results of groundwater monitoring for Phase 1A will
be presented in a separate report. A site plan showing all the pertinent features of the facility is
provided in Drawing 1.

1.2 Site Geology
The John’s River Waste Management Facility is in close proximity to the Brevard Shear Zone,
and is underlain by highly metamorphosed rocks including gneiss, schist, as well as calc-silicate
rocks, felsic rocks, and metavolcanic rocks. The dominant rock type at the facility is biotite-
muscovite schist, as seen in outcrops, boulders, and rock cores located on site. The structures
within limited outcrops indicate that these rocks are complexly-folded, with attitudes that vary
from vertical to horizontal in most outcrops. The site regolith is typical of the inner piedmont
and consists mostly of silty sand, clayey sand, and sandy silt. The regolith is up to 100 feet thick
and varies in thickness with topography.

An abundance of rounded gravel, cobble, and boulder-sized alluvial deposits are exposed along
the banks of the Catawba River, which borders the site. The greatest accumulation of these
deposits is along the southwestern site boundary. These river deposits are 40 feet or more above
the current river elevation and have been described as ancient river terrace deposits.

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1.3 Regulatory Status
The following report of groundwater monitoring data from the JRWMF has been prepared in
accordance with the North Carolina Solid Waste Management Rules (NCSWMR) 15A NCAC
13B §.1632 (Groundwater Sampling & Analysis Requirements) §.1633 (Detection Monitoring
Program), and §.1634 (Assessment Monitoring Program). The facility has operated under these
programs under the auspices the North Carolina Department of Environment and Natural
Resources (NCDENR), which is now the Department of Environmental Quality (NCDEQ). To
avoid confusion, NCDEQ will be used in reference to this department throughout this report
even in reference to past events or documents when it was the NCDENR.

The C&D over MSW landfill has been in the Assessment Monitoring Program since August
1995. In January 2000, Burke County submitted a Water Quality Assessment Report (WQAR),
for the landfill to the NCDEQ. The WQAR determined that the constituents-of-concern (COCs)
at the landfill were several volatile organic compounds (VOCs), specifically: benzene; 1,4-
dichlorobenzene; methylene chloride; tetrachloroethylene; and trichloroethylene.

The JRWMF entered the Corrective Action Program following the correspondence received
from the NCDEQ Solid Waste Section (SWS) dated August 18, 2003. An Assessment of
Corrective Measures (ACM) was submitted to NCDEQ in February 2005. A public meeting was
held on May 16, 2006 in order to receive public comments regarding the ACM as required by
NCSWMR §.1635 (d). A Corrective Action Plan (CAP) was submitted to NCDEQ in June 2008
and revised in November 2008. The CAP was approved by NCDEQ in a letter dated January 29,
2009. An addendum to the facility’s CAP was submitted to the NCDEQ in August 2013, adding
control of landfill gas as a remedy for groundwater impacts on the northeastern side of the
landfill between the old landfill and the new C&D expansion area.

1.4 Groundwater Monitoring History
 April 1988: Facility began operations as an MSW landfill.
 August 1995: Assessment Monitoring began.
 January 1998: Facility closed as an MSW landfill, but began operating a C&D landfill
on top of the former MSW landfill.
 January 2000: Water Quality Assessment Report (JOYCE, 2000).
 October 2004: Update on Water Quality Assessment Report (JOYCE, 2004).
 February 2005: Assessment of Corrective Measures (ACM) (JOYCE, 2005a) and
Quantitative Risk Assessment (JOYCE, 2005b).
 May 2006: Public Meeting for ACM.
 June 2008: Corrective Action Plan (CAP) submitted to NCDEQ-SWS.
 November 2008: CAP Revised per comments from NCDEQ-SWS & resubmitted.
 January 2009: CAP Approved by NCDEQ-SWS.
 June 2009: First Monitored Natural Attenuation (MNA) baseline sampling event.
 May 2011: First Corrective Action Evaluation Report (CAER).

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 April 2012: Alternate Source Demonstration (ASD) for iron and manganese approved
by NCDEQ.
 August 2013: Addendum to the CAP to add control of landfill gas as a remedy.

2.0 FACILITY MONITORING PROGRAM
2.1 Groundwater Monitoring Program
Groundwater monitoring at the C&D over MSW landfill is performed in accordance with
NCSWMR §.1634, the site’s Transition Plan (JOYCE, April 1994), and the sites Corrective
Action Monitoring Plan (CAMP) (Joyce, 2008) Groundwater samples are collected
semiannually and analyzed for constituents according to the sampling plan submitted to the SWS
on October 29, 1999. Following is a summary of the compliance monitoring wells and other
wells in the immediate vicinity of the landfill.

Well ID Date
Installed Classification Monitoring
Program
Total Depth
of Well (ft)
Lithology of
Screened
Interval
Constituent
List
MW-8 9-15-87 not used - 39.5 Saprolite -
MW-9 8-31-94 Abandoned/
Former Bkgnd. - - - -
MW-10 9-02-94 Compliance Assessment 23.0 Saprolite Comp.
MW-11 9-02-94 Compliance/
Performance
Assessment/
Cor. Act. 43.0 Saprolite Comp., MNA*
MW-12 9-01-94 Compliance/
Performance
Assessment/
Cor. Act. 51.5 Bedrock Comp., MNA*
MW-13 8-31-94 Compliance Assessment 58.0 Bedrock Comp.
MW-14 6-07-96 not used - 21.5 Saprolite -
MW-15S 6-04-96 not used - 54.0 Saprolite -
MW-15D 6-04-96 not used -118.5 Bedrock -
MW-16S 3-08-99 Compliance/
Performance
Assessment/
Cor. Act. 20.0 Saprolite Comp., MNA*
MW-16D 3-10-99 Compliance Detection 120.0 Bedrock Comp.
MW-17 3-08-99 Not used/
Former Bkgnd. - 52.0 Bedrock -
MW-18 4-07-09 Sentinel** Corrective
Action 12.0 Alluvial Soil COCs, MNA*
MW-19 4-07-09 Sentinel** Corrective
Action 13.0 Alluvial Soil COCs, MNA*
MW-20 5-18-95
Former Bkgnd./
Phase 1A
Compliance
Assessment 67.0 Saprolite Comp.
MW-21 5-18-95 Background Assessment/
Cor. Act. 45.0 Saprolite Comp., MNA*
MW-36 5-08-11 Performance*** Corrective
Action 43.0 Bedrock COCs, LFG
MW-38 5-09-11
Phase 1A
Compliance/
Performance***
Corrective
Action 71.0 Bedrock COCs, LFG

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Notes: Comp. = Compliance Parameters: NCSWMR Appendix I and/or Appendix II organics and inorganics
plus C&D parameters, as required for routine assessment or detection monitoring.
COCs = Constituents of Concern.
MNA = Monitored Natural Attenuation Parameters: Temperature, pH, specific conductance, oxidation
reduction potential, dissolved oxygen, nitrate, sulfate, chloride, dissolved hydrogen, sulfide, alkalinity,
TOC, methane, ethane, ethene, volatile fatty acids, carbon dioxide, ferrous iron, and turbidity.
LFG = Landfill Gas Indicators: Dissolved CH4 and dissolved CO2.
* After the baseline period, the NCDEQ approved alternate frequencies for carbon dioxide, sulfide,
volatile fatty acids, ethane, and ethylene. These parameters will be monitored during both semiannual
events every third year.
** After the baseline period, sampling frequency for sentinel wells was changed to annual.
*** Performance wells (MW-36& MW-38) for the control of landfill gas remedy were added in the
August 2013 CAP Addendum. MW-38 is also a compliance well for Phase 1A.

The current compliance groundwater monitoring network at the facility consists of one
upgradient well (MW-21), and six downgradient wells (MW-10, MW-11, MW-12 MW-13,
MW-16S, and MW-16D). In March 1999, monitoring wells MW-16S and MW-16D were
installed as downgradient monitoring wells and well MW-17 was installed as a replacement for
upgradient background well MW-9. These wells were incorporated into the compliance
monitoring network during the second semiannual groundwater monitoring event of 2005 after
receiving approval from the SWS in a letter dated August 1, 2005. The letter also gave approval
to drop MW-9 from the compliance monitoring network. MW-9 was abandoned in July 2006.
There are several other monitoring wells at the facility (including MW-8, MW-14, MW-15S, and
MW-15D) and several piezometers that have been used in the past to collect groundwater data to
supplement the data from the compliance monitoring wells. Sentinel wells MW-18 and MW-19
were installed on April 7, 2009 in accordance with the facility’s Corrective Action Plan.

Due to organic detections in MW-17, a request was submitted in August 2010 to replace MW-17
with MW-20 as the facility background well. MW-20 (originally named PZ-4) was installed as a
piezometer in 1995 for site characterization. The NCDEQ-SWS requested that we sample both
MW-17 and MW-20 for the next 2 sampling events (November 2010 and June 2011), and then
submit a revised Water Quality Monitoring Plan to incorporate MW-20 into the compliance
network as the new background well. MW-20 served as the background well until August 2014
when the new Permit to Operate for Phase 1A C&D Landfill expansion was issued by the North
Carolina Department of Environment and Natural Resources. MW-20 was replaced by MW-21,
(formerly PZ-1). MW-21 will serve as the new background monitoring well for both Phase 1A
and the old C&D over MSW landfills. The former background well for the old C&D over MSW
landfill, MW-20, which is located side-gradient of and to the northeast of Phase 1A, will
continue to be sampled as a compliance well for Phase 1A.

The wells in assessment monitoring (MW-10, MW-11, MW-12, MW-13, MW-16S, and MW-20)
are analyzed for the NCSWMR Appendix I list of constituents plus additional detected Appendix
II constituents and additional required C&D parameters during the first semiannual event, and
for all constituents listed in NCSWMR Appendix II plus additional required C&D parameters
during the second semiannual monitoring event. Monitoring well MW-16D is analyzed for the

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NCSWMR Appendix I plus additional required C&D parameters list during both events.
Monitoring wells MW-11, MW-12, MW-16S, and MW-21 are also sampled for MNA
parameters during each sampling event.

In accordance with the CAP for the facility, MNA baseline sampling was initiated with the June
2009 sampling event and continued through the November 2010 sampling event. The baseline
data were evaluated in a CAER dated May 2011. After reviewing the CAER, in a letter dated
July 12, 2011, the NCDEQ agreed to a reduced frequency for monitoring carbon dioxide, sulfide,
volatile fatty acids, ethane, and ethylene. These parameters will be sampled during both
semiannual sampling events every third year. The next time these parameters will be monitored
will be during the two semiannual events of 2016.

The Corrective Action Monitoring Plan (CAMP) for the facility requires samples from sentinel
wells MW-18 and MW-19 to be analyzed for the facility’s Constituents of Concern (COC’s).
The COC list included the following constituents in 2015:

 Benzene;
 1,4-Dichlorobenzene;
 Methylene chloride;
 Tetrachloroethylene (PCE);
 Trichloroethylene (TCE);
 1,1-Dichloroethane;
 1,2-Dichloroethane;
 Vinyl chloride.
 Alpha-BHC

After the 2011 CAER, the NCDEQ agreed that sentinel wells MW-18 and MW-19 need only be
sampled annually. MW-18 and MW-19 were last sampled during the May 2015 event. During
future events, MW-18 and MW-19 will be monitored for the above COC list plus required MNA
parameters annually.

An addendum to the facility’s CAP was submitted to the NCDEQ in August 2013, adding
control of landfill gas as a remedy for groundwater impacts on the northeastern side of the
landfill between the old landfill and the new C&D expansion area. In accordance with the CAP
addendum, piezometers PZ-36 and PZ-38 were converted to permanent monitoring wells
MW-36 and MW-38 to act as performance wells for the control of LFG remedy. MW-36 and
MW-38 are to be sampled semiannually for the current COC list, plus dissolved methane and
dissolved carbon dioxide.

2.2 Surface Water Monitoring Program
The current surface water monitoring points are SMP-5, SMP-6, and SMP-7. Surface water
monitoring point SMP-5 (located at the southwestern property line) and SMP-6 (located at the
southeastern property line) are both located downstream from existing sediment basins. Surface
water monitoring point SMP-7 is located downstream from the new Phase 1A expansion.

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Surface water samples are analyzed for the NCSWMR Appendix I list of constituents plus
detected Appendix II constituents during both semiannual events.

Surface Point Classification Monitoring
Program Location
SMP-5 Compliance Surface Water Creek on west side of landfill,
downstream of sediment basin.
SMP-6 Compliance Surface Water Creek on east side of landfill,
downstream of sediment basin.
SMP-7 Compliance Surface Water
Creek southeast of Phase 1A
and east of sediment basin
SB-2A. Downstream of PZ-12.

3.0 SECOND SEMIANNUAL SAMPLING EVENT OF 2015
3.1 Field Work
In order to detect potential releases of leachate and/or landfill gas migration in a timely manner,
a visual inspection program has been implemented at the John’s River Waste Management
Facility. This inspection program involves field personnel making the following observations:
 Indications of stress on the biological community (e.g., dead or dying vegetation);
 Indications of leachate impact (e.g., seeps, impacted surface water);
 Observations of erosion;
 Condition of monitoring wells; and
 Negative changes around the waste facility.

On December 7-9, 2015, personnel from JOYCE visited John’s River Waste Management
Facility to purge and sample monitoring wells MW-10, MW-11, MW-12, MW-13, MW-16S,
MW-16D, MW-20, MW-21 MW-36, and MW-38. Surface monitoring points SMP-5, SMP-6,
and SMP-7 were also sampled during the December 2015 event.

Depth-to-water measurements were obtained to the nearest 0.01 foot using an electronic water
level indicator for all monitoring wells in the compliance network prior to purging. Current and
historical groundwater elevation data are presented in Table 1. Monitoring wells were purged
and sampled using disposable bailers. Measurements of temperature, pH, specific conductivity,
and turbidity were recorded in the site log book as well as on field data logs prior to purging,
after each purge volume, and during sampling. Field data logs for the December 2015 event are
provided in Appendix A. Field parameter data are presented in Table 2.

Laboratory-supplied containers were prepared and labeled (either by the laboratory or in the
field, as indicated) with the following information:
 Monitoring well number (completed by field personnel),
 Date and time of sample collection (completed by field personnel),
 Initials of sampling personnel (completed by field personnel),
 Project name and number (completed by the laboratory),

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 Chemical preservative (completed by the laboratory); and
 Requested chemical analysis (completed by the laboratory).

Groundwater samples from each monitoring well were dispensed directly from the disposable
bailers into the provided laboratory containers either immediately after purging or within 24
hours of the final purge volume. Immediately after collection, the samples were placed in a
laboratory-provided cooler and chilled with ice.

Surface water samples were collected directly from stream flow by lowering the prepared sample
containers into the stream flow. Care was taken not the overflow the sample containers (which
could lead to preservative loss) and avoid sample-induced turbidity. At the time of sampling,
surface water was also measured for temperature, pH, specific conductivity, and turbidity and
recorded in the site log book. After sample collection, the samples were placed in a laboratory
provided cooler and chilled on ice. Field data logs are provided in Appendix A.

On February 4, 2016, personnel from JOYCE visited John’s River Waste Management Facility
to purge and sample monitoring wells for verification of detections above groundwater standards
for beta-BHC in MW-11; and Antimony and Chromium in MW-12 in accordance with the
sampling procedures described above for the semiannual event.

3.2 Laboratory Analysis and JOYCE Quality Control
The December 2015 groundwater and surface water samples were submitted to Pace Analytical
Services, Inc. of Huntersville, North Carolina under chain-of-custody control for analysis. The
groundwater samples from the wells in assessment monitoring were analyzed for the NC
Appendix I, plus previously detected Appendix II list of constituents, plus additional required
C&D parameters. Groundwater from MW-16D was analyzed for the NC Appendix I list of
constituents plus additional required C&D parameters. In addition, samples from corrective
action wells were analyzed for the COC list plus MNA or LFG parameters as described in
Section 2.1. Surface water samples were analyzed for the NC Appendix I list of constituents
plus additional detected Appendix II constituents. JOYCE requested a Level II data report for
the final laboratory report. The samples were received by the laboratory in good condition,
properly preserved, and within required hold times.

In addition to samples collected for compliance monitoring at the John’s River Waste
Management Facility, a Field Blank was collected by JOYCE personnel as part of the December
2015 sampling event. Also, a Trip Blank prepared by the laboratory accompanied the volatile
sampling containers from and to the laboratory. The Field Blank was analyzed for the NC
Appendix I, plus previously detected Appendix II list of constituents, plus iron, manganese and
tetrahydrofuran, and the Trip Blank was analyzed for Appendix I list of constituents plus
additional detected Appendix II volatile organic compounds and tetrahydrofuran.

Upon receipt of the laboratory data package, JOYCE personnel reviewed the data package for
quality assurance/quality control (QA/QC) purposes and for possible regulatory issues. If any
QA/QC or regulatory issues were found, the laboratory would be contacted to resolve the issue,

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and a resampling event might be scheduled, if needed. The laboratory analytical packages can
be found in Appendix B of this report. The data package was reviewed for the following:

 General typographical errors;
 Correct analyses performed and within method specified hold times;
 Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate,
and Laboratory Control Samples;
 Blank-qualified data (B-flags);
 Detections exceeding the North Carolina 15A NCAC 2L .0202 Groundwater Standards
(NC2L), NCDEQ-SWS Groundwater Water Protection Standards (GWPS), and North
Carolina 15A NCAC 2B Surface Water Standards (NC2B); and
 Detections that are above historical levels.

4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSIS
4.1 Analytical Results for Inorganic Constituents
Eight metal constituents and three inorganic indicators were detected above the SWSL in one or
more monitoring wells during the December 2015 sampling event. Of these, six inorganic metal
constituents were initially detected above an NC 2L/GWPS in one or more monitoring wells.
Antimony and vanadium were detected above the relevant GWPS and chromium was detected
above the NC 2L standard in MW-12. The results were not consistent with historically data for
MW-12, so a confirmation was requested from Pace Analytical for antimony, vanadium and
chromium in MW-12. Pace reran the requested analysis and appended them to the laboratory
report. The results confirmed the quantified detections of antimony and chromium, but not
vanadium. These results were still suspect based on historical data and higher turbidity in the
samples, so Joyce performed a verification (resample) event on February 4, 2016 for antimony
and chromium in MW-12; the exceedence of the NC 2L standard for chromium and GWPS for
antimony were not verified; therefore, these are not considered to be valid exceedances.

Cobalt was detected above the GWPS in all wells except MW-16D and MW-21. The cobalt
detections were not above the calculated background concentrations (see Section 4.3.2);
therefore, these detections do not constitute Groundwater Protection Standards (GPS)
exceedances per rule .1634(g)(5) of the NCSWMR. Iron and manganese were in exceedance of
the NC 2L standards in all wells with the exception of iron in monitoring well MW-16D. An
ASD was approved for iron and manganese by NCDEQ on April 12, 2012; therefore, these are
not considered exceedances.

Table 3 presents the constituents with quantified detections during the December 2015 sampling
event, and Table 4 presents a summary of the exceedances of groundwater standards. Both
tables include the results from laboratory confirmation re-analysis and the verification sampling
event. In general, the inorganic detections and concentrations are consistent with historical data
except for the initial exceedances in MW-12, which were later refuted. Historical data for
inorganic constituents are summarized in Appendix D.

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4.2 Analytical Results for Organic Constituents
Eight organic constituents were detected above the NC 2L/GWPS in one or more monitoring
wells during the December 2015 sampling event, including benzene, 1,4-dichlorobenzene,
1,1-dichloroethane, 1,2-dichloroethane, methylene chloride, tetrachloroethene, vinyl chloride,
and beta-BHC. The first time detection of beta-BHC in MW-11 was not historically consistent,
so a verification sample was collected from MW-11 on February 4, 2016; the results confirmed
the detection and exceedence of beta-BHC in MW-11. Acrolein was reported at an estimated
concentration in MW-21, but was blank qualified from the Trip Blank. Table 3 presents the
constituents with quantified detections during the December 2015 sampling event, and Table 4
presents a summary of the exceedances of groundwater standards. In general, the detections and
concentrations are consistent with historical data. Historical data for organic constituents in
compliance wells are summarized in Appendix E, and historical data for organic constituents in
performance and sentinel wells are summarized in Appendix F.

4.3 Statistical Analyses
4.3.1 Statistical Methods and Background
MW-9 was the facility background well from 1994 until May 2005, when it was abandoned.
MW-17 was the facility background well from May 1999 until June 2011. Both MW-9 and
MW-17 were sampled between May 1998 and May 2005. Due to gas related impacts to MW-17,
MW-20 became the facility background well in December 2010. Both MW-17 and MW-20
were sampled between December 2010 and June 2011. With the opening of Phase 1A of the
C&D expansion in August 2014, MW-21 (formerly PZ-1) became the facility background well
and MW-20 became a compliance well for Phase 1A.

Facility background data used to evaluate the December 2015 groundwater monitoring data
include all data collected for wells MW-9, MW-17, and MW-20 from September 1994 through
the May 2014 event plus the October 2014 through December 2015 data from MW-21.
Alternatively, intrawell statistics may be used to evaluate the statistical background for a specific
well. Data used for intrawell statistics will use all available data for that well, excluding the last
eight sampling events.

The background data for inorganic constituents were evaluated using the Shapiro-Wilk Test,
Parametric Prediction Limits, Parametric Tolerance Intervals, Aitchison’s Adjustment, Non-
Parametric Prediction Limits, and/or Poisson Prediction Limits as appropriate. Background data,
tests for normality, outliers, Aitchison’s adjustment, tolerance interval, or prediction limits are
used, as appropriate based on the background data. The statistical test by which downgradient
data are compared to facility background data is based upon the nature of the data and the
number of data values that are below the laboratory limit of detection. All statistical tests are
evaluated at the 0.05 level of significance, 95% confidence level, and are conducted as one-tailed
tests.

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4.3.2 Statistical Analyses of Inorganic Constituents
The inorganic constituents detected at quantifiable concentrations (excluding blank-qualified
data) above the North Carolina SWSL in down gradient monitoring wells in the December 2015
sampling event were barium, cobalt, iron, manganese, vanadium, and zinc. Since barium,
vanadium, and zinc were not detected in exceedance of NC2L/GWPS standards, there is no need
to calculate statistical background for these constituents. Iron and manganese were addressed in
an ASD approved by NCDEQ in April 2012.

Interwell statistics were used to determine background values of 96.6 µg/L for cobalt and 630
µg/L for vanadium. A summary of the statistical analyses is presented in Table 5, and the
detailed statistical analyses worksheets are included in Appendix C.

Since the background concentrations of cobalt, thallium, and vanadium are greater than their
respective GWPS, the background values will be considered the applicable GPS for these
constituents per rule .1634(g)(5) of the NCSWMR; therefore, there were no GPS exceedances
for any inorganic constituents.

4.4 Analytical Results for Surface Water
Surface monitoring points SMP-5, SMP-6, and SMP-7 were sampled during the December 2015
event. There were no constituents detected above the NC 2B Surface Water Standards (NC2B)
in any of the samples during the December 2015 event. Barium, and vanadium, were detected in
one or more surface water samples at estimated concentrations below their respective SWSL.
No organic constituents were detected in any of the surface water samples. The December 2015
surface water results are consistent with the historical data. Current and historical surface water
data can be found in Appendix G.

5.0 EVALUATION OF MONITORED NATURAL ATTENUATION (MNA)
5.1 MNA Parameters and Biodegradation Screening Matrix
In accordance with the CAP for the facility, MNA baseline sampling was initiated with the June
2009 sampling event and continued through the November 2010 sampling event. The baseline
data were evaluated in a CAER dated May 2011. The December 2015 sampling event was the
tenth post-baseline event. MNA parameter data were obtained for the following wells: the site
background well (MW-21); and downgradient compliance/performance wells MW-11, MW-12,
and MW-16S. MNA field parameters included temperature, pH, specific conductance,
oxidation-reduction potential (ORP), turbidity, dissolved oxygen, dissolved carbon dioxide and
ferrous iron. MNA laboratory parameters included dissolved hydrogen, alkalinity, TOC,
dissolved methane, nitrate, sulfate, and chloride. Table 6 summarizes the MNA data for the
December 2015 event, and historical MNA data are presented in Appendix H. Field data logs
and laboratory reports are included in Appendices A and B, respectively.

The MNA parameter data were evaluated in general accordance with the United States
Environmental Protection Agency’s (EPA’s) Technical Protocol Manual (EPA, 1998) to

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determine whether the conditions are conducive to, or whether there is evidence for anaerobic
degradation of the chlorinated hydrocarbons. Specifically, the results were evaluated according
to the weighted system presented in Table 2.3 of the Technical Protocol Manual, referred to
hereafter as the Biodegradation Screening Matrix. According to this manual, a score less than 5
indicates that there is inadequate evidence for anaerobic natural attenuation, a score of 6 to 14
indicates that there is limited evidence for anaerobic natural attenuation, a score of 15 to 20
indicates that there is adequate evidence for anaerobic natural attenuation, and a score greater
than 20 indicates that there is strong evidence that anaerobic natural attenuation is occurring.

The MNA evaluation was performed based on the results from the December 2015 sampling
event for downgradient wells within the contaminant plume, compared where appropriate to the
background well (MW-21). The Biodegradation Screening Matrix is presented in Table 7 of this
report.

One difficulty in evaluation of the Screening Matrix is that the matrix assumes some compounds
(such as, but not limited to methane and vinyl chloride) are daughter products of biodegradation
within the plume; however, at a landfill we cannot eliminate the possibility that they may be
contaminants released directly from the landfill. If we include the scores for these potential
daughter products, our total score could be artificially high; on the other hand, if we exclude
them, the score might be artificially low. Table 7 presents scoring results both with and without
the questionable daughter product scores.

The fact that we are past the baseline sampling period and the sampling frequencies for some
parameters have been reduced creates another difficulty. How should we score parameters that
were not monitored during the December 2015 sampling event? We have historical data for
these parameters indicating that some would likely contribute points and some would not. To
ignore the historical data and treat all unmonitored parameters as if they were negative results
would give an artificially low score; however, using data from previous events may not give an
accurate result. Table 7 presents scoring results both with and without points based on historical
rather than current data.

The following table summarizes the scoring results from Table 7 for all four options for
interpreting the data. The scores ranged from 14 (limited evidence of natural attenuation) to 30
(strong evidence of natural attenuation). In reality, the best score is probably in the middle of
this range, indicating good evidence of natural attenuation.

DP = Points for possible daughter products.
HD = Points based on historical data.

Points Awarded
including DP
Points Awarded
excluding DP
Points Awarded
excluding HD 27 14
Points Awarded
including HD 28 14

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5.2 Biochlor Modeling and Mass-Balance Assessment
Anaerobic degradation of organic constituents, specifically chlorinated ethenes and ethanes, was
modeled using the EPA Biochlor System. The Biochlor model was set up to model flow,
dispersion, advection, adsorption, and biotransformation along a generalized flow line running
from the waste unit south toward the river. The concentration in the source area was set equal to
the December 2015 sampling results from MW-13. Wells MW-11, MW-12, and MW-16S were
included in the modeling based on their respective distances from the southern edge of waste as
summarized below:

WELL: MW-13 MW-11 MW-12 MW-16S MW-18 MW-19
MODELED DISTANCE
FROM THE SOURCE (feet): 0 20 60 135 210 430

Modeling was done for both ethenes (a.k.a. - ethylenes) and ethanes. The ethene degradation
sequence goes from tetrachloroethylene (PCE) to trichloroethylene (TCE), to dichloroethylenes
(DCE), to vinyl chloride (VC). The ethane degradation sequence goes from trichloroethane
(TCA) to dichloroethanes (DCA) to chloroethane (CA). Note that DCE is the sum of detected
cis-1,2-dichloroethylene, trans-1,2-dichlorotheylene, and 1,1-dichloroethylene. Similarly, DCA
is the sum of 1,1-dichloroethane and 1,2-dichloroethane.

The plume was assumed to be 1600 feet wide and 500 feet long, based on the width of the plume
at the southern edge of waste and the average distance from the southern edge of waste to the
river. Simulation time was 17 years, based on the time between closure of the MSW landfill and
the October 2014 sampling event. A seepage velocity of 144.0 feet/year was used based on
groundwater flow rate calculations for the December 2015 event as presented in Section 6.0 of
this report. The input and output of the Biochlor modeling are presented in Appendix D.

The results of the Biochlor modeling indicate reasonable agreement between the modeled plume
degradation and the analytical results for both ethenes and ethanes. In general, the observed
down-gradient concentrations were less than or equal modeled concentrations except for VC and
CA, which are the final daughter products. The fact that VC and CA are higher downgradient is
evidence that reductive dehalogenation is occurring. This supports the contention that
biodegradation is proceeding at an acceptable rate. The mass rate calculations from the Biochlor
modeling are summarized below. Cells labeled “indeterminate” in the following tables indicate
that the data were insufficient for the software to calculate the values. The results indicate a
large percentage of the contaminants are being removed by Biotransformation.

Ethenes PCE TCE DCE VC
Mass Removed 2.4 Kg 1.4 Kg 8.3 Kg indeterminate
% Biotransformed 80.8% 73.0% 60.9% indeterminate
% Change in Mass Rate 99.5% 98.2% 92.3% indeterminate

Ethanes DCA
Mass Removed 14.6 Kg
% Biotransformed 79.6%
% Change in Mass Rate 99.3%

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5.3 Trend Analysis and Plume Stability
Charts 1-10 show the concentration of key constituents versus time for the wells MW-10,
MW-11, MW-12, MW-13, and MW-16S from the earliest recorded detections through December
2015. In general, most constituents in most wells show decreasing or stable trends, especially
over the last 3-5 years. The clearest long-term increasing trend is for benzene and MW-13;
however, the benzene trend appears to have stabilized in the last few years. 1,4-dichlorobenzene
also shows a clear upward trend in MW-13. MW-13 is located farther north (upgradient) than
the other downgradient wells and is representative of the central part of the plume whereas
MW-11, MW-12, and MW-16S are located nearer the southern leading edge of the plume, and
MW-10 is located near the western edge of the plume. The fact that the concentrations in the
central part of the plume appear to be stable or increasing while the concentrations near the
leading edge seem to be stable or decreasing supports the contention that natural attenuation is
adequately controlling the plume.

Alpha-BHC has had sporadic detections in MW-13 over the last several sampling events, and
beta-BHC had a confirmed detection in MW-11 for the first time during the December 2016
event. There is not enough consistent data for these constituents to establish any trends.

6.0 HYDROGEOLOGICAL CONDITIONS
Based on outcrop and drilling information, the water table appears to occur within regolith
everywhere across the site. This regolith consists of alluvium, residual soils, saprolite, and
variably fractured and weathered layered metamorphic rock. Inspection of drill cuttings and site
outcrops indicates that water in the regolith is transmitted largely through fractures. In this
regard, regolith behaves similar to unweathered bedrock, except that fractures are more
numerous and better connected in the regolith, and will tend to have more isotropic hydraulic
properties. Along the low-lying areas of the Catawba River and its tributaries, the water table
occurs within surficial alluvial deposits overlying the residual soils and weathered bedrock.

Groundwater discharges into creeks to the east and west of the landfill and to the Catawba River
to the south. A groundwater potentiometric surface map, developed from static water level data
obtained in December 2015, is presented as Drawing 1. The potentiometric surface map depicts
groundwater flow primarily to the south.

Depth to groundwater was measured in the compliance monitoring wells at the site prior to
sampling. The December 2015 and historical groundwater elevations are provided in Table 1.
The groundwater elevations were calculated relative to the surveyed measuring point (top of
casing) for each monitoring well. Horizontal groundwater gradients along representative flow
paths were estimated from the December 2015 groundwater contours shown on Drawing 1 and
calculated gradients and flow velocities are summarized in Table 8. Horizontal gradients across
the site ranged from 0.039 to 0.055 ft/ft, with an average of approximately 0.048 ft/ft. This is
consistent with previous estimates.

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Linear groundwater flow velocities for wells screened in saprolite were computed using the
modified Darcy equation: V = Ki/ne, where V = average linear velocity, K = hydraulic
conductivity, i = horizontal hydraulic gradient, and ne = effective porosity. The mean of
hydraulic conductivities from slug-tests conducted in 1995 and 2015 (K = 3.28 ft/day) was used
in these calculations, along with an estimated effective porosity of ne = 0.40 (40%) for saprolite
based on laboratory porosities for soil samples from the site.

The estimated linear groundwater flow velocity under the facility ranged from 140-164 feet/year,
with an average flow velocity of approximately 144 feet/year (Table 8). The modified Darcy
equation makes the simplifying assumptions of a homogeneous and isotropic aquifer, which may
yield inaccurate results when applied to heterogeneous and/or anisotropic conditions such as are
believed to exist at this site.

The groundwater flow direction and rate have shown no significant seasonal variations over
several years of monitoring. The groundwater flow regime on this site is well constrained and
predictable. Migration of groundwater contaminants are expected to follow the general
groundwater flow paths and there are no known preferred pathways or barriers to groundwater
flow that could significantly affect plume migration or the effectiveness of the groundwater
monitoring network to monitoring plume migration. The current groundwater monitoring
network remains sufficient for monitoring the groundwater at this facility.

7.0 CONCLUSIONS
There were several organic constituents detected above the NC 2L Groundwater Standards at the
John’s River Landfill during the December 2015 sampling event. With the exception of the new
exceedance for beta-BHC in MW-11, these results are generally consistent with previous
sampling events and are being addressed by the Corrective Action Plan for the facility. Beta-
BHC will be added to the Constituents of Concern list for the site.

Evaluation of MNA data, Bioplume modeling, and trends of key constituents all indicate that
natural attenuation is actively occurring on the site and that it is adequately controlling the
constituent plume. A complete Corrective Action Evaluation Report (CAER) will be submitted
concurrently with this WQMR.

Cobalt was detected above the GWPS; however it was not detected above the calculated
background concentrations; therefore, the background is the appropriate ground water protection
standards for cobalt and thallium per rule .1635 (g) of the NCSWMR. An ASD was approved
for iron and manganese by NCDEQ on April 12, 2012. Anomalous detections of several metals
in MW-12 were refuted either by laboratory re-run of analyses or by the results of a verification
sampling event. Otherwise, the inorganic results from the December 2015 are consistent with
historical data.

There were no organic or inorganic detections above the NC 2B Surface Water Standards for
surface water samples from the December 2015 sampling event.

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The groundwater flow regime is consistent with previous events and the groundwater monitoring
network remains adequate to monitor the site. Based on analytical results from the December
2015 sampling event, John’s River Landfill will remain in Assessment Monitoring and
Corrective Action. The next semiannual sampling event is scheduled for the second quarter of
2016.

8.0 REFERENCES
Hinchee, R.E., A. Leeson, L. Semprini, and S.K. Ong. 1994. Bioremediation of Chlorinated and
Polycyclic Aromatic Hydrocarbon Compounds. Lewis Publishers, Boca Raton.

Interstate Technology and Regulatory Cooperation Work Group (ITRC). September 1999.
Natural Attenuation of Chlorinated Solvents in Groundwater: Principles and Practices.
Technical/Regulatory Guidelines.

Interstate Technical Regulatory Council (ITRC). 2003. Technical and Regulatory Guidance
Document for Constucted Treatment Wetlands.

Joyce Engineering (JOYCE), 1994. Transition Plan, Johns River Waste Management Facility.
April 1994.

JOYCE, 2000. Water Quality Assessment Report, Johns River Waste Management Facility.
January 2000.

JOYCE, 2004. Update on Groundwater Assessment Activities, Johns River Waste Management
Facility. October 2004.

JOYCE, 2005a. Assessment of Corrective Measures Report, Johns River Waste Management
Facility. February 2005.

JOYCE, 2005b. Quantitative Risk Assessment, Johns River Waste Management Facility.
February 2005.

JOYCE, 2008. Corrective Action Plan, Johns River Waste Management Facility. June 2008.

JOYCE, 2011. Corrective Action Evaluation Report, Johns River Waste Management Facility.
May 2011.

JOYCE, 2013. Addendum to the Corrective Action Plan, Johns River Waste Management
Facility. August 2013.

National Research Council (NRC), 2000. Natural Attenuation for Groundwater Remediation.
National Academy Press, Washington, D.C. pp. 108-111.

Second Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering
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North Carolina Department of Environmental Quality (NCDEQ), 1997. North Carolina Solid
Waste Management Rules. 15 NCAC 13B. January 1, 1997.

NCDEQ, 2007. North Carolina Solid Waste Section Guidelines for Corrective Action at Solid
Waste Management Facilities. March 2007.

Sumsion, C.T., and Laney, R.L., 1967, Geology and Ground-water Resources of the Morganton
area North Carolina. N.C. Department of Water Resources, Ground Water Bulletin No.
12, 119 p.

U.S. Department of Energy (USDE). May 1999. Decision-Making Framework Guide for the
Evaluation and Selection of Monitored Natural Attenuation Remedies at Department of
Energy Sites.

U.S. Environmental Protection Agency (USEPA), 1992. Statistical Analysis of Groundwater
Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance. July 1992.

USEPA. October 1988. Interim Final Guidance for Conducting Remedial Investigations and
Feasibility Studies under CERCLA. Office of Solid Waste and Emergency Response
(OSWER) Directive 9355.3-01, EPA/540/G-89/004.

USEPA. February 1991. Conducting Remedial Investigations/Feasibility Studies for CERCLA
Municipal Landfill Sites. OSWER Directive 9355.3-11, EPA/540/P-91/001.

USEPA. May 1995. How to Evaluate Alternative Cleanup Technologies for Underground
Storage Tank Sites: A Guide for Corrective Action Plan Reviewers. Chapters 2 (Soil
Vapor Extraction) and 10 (In-Situ Groundwater Bioremediation).

USEPA. May 1996. Seminars on Bioremediation of Hazardous Waste Sites: Practical
Approaches to Implementation. ORD,EPA/625/K-96/001. Chapters 15 (Natural
Attenuation of Groundwater) and 17 (Natural Attenuation of Landfills).

USEPA and U.S. Air Force (USAF). July 1993. Remediation Technologies Screening Matrix
Reference Guide, Version I. Joint Project of OSWER and Environics Directorate, PB93-
2118212.

9.0 ACRONYMS
ACM Assessment of Corrective Measures (Report)
AMSL Above Mean Sea Level
AOC Area of Concern
BGS Below Ground Surface
C&D Construction and Demolition Waste
CAP Corrective Action Plan (Report)
CAER Corrective Action Evaluation Report (Report)

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CAMP Corrective Action Monitoring Plan (Report)
CAS Chemical Abstracts Service
CFR Code of Federal Regulations
CPVC Chlorinated Poly Vinyl Chloride
COC Contaminant of Concern (for corrective action)
COC Chain of Custody (for sampling and lab reports)
DL Detection Limit (for laboratory data)
DO Dissolved Oxygen
EPA United States Environmental Protection Agency (or USEPA)
GWPS Groundwater Protection Standards (Established by NCDEQ-SWS)
JOYCE Joyce Engineering
LFG Landfill Gas
MNA Monitored Natural Attenuation
MSW Municipal Solid Waste
MW Monitoring Well
NC2B North Carolina Surface Water Standards found in 15A NCAC 2B
NC2L North Carolina Groundwater Standards found in 15A NCAC 2L
NCAC North Carolina Administrative Code
NCDENR North Carolina Dept. of Environment and Natural Resources (now the NCDEQ)
NCDEQ North Carolina Dept. of Environmental Quality (formerly the NCDENR)
NCGS North Carolina Geological Survey
NCSWMR North Carolina Solid Waste Management Regulations (15A NCAC 13B.1600)
ND Not Detected (for laboratory data)
NES Nature and Extent Study (Report)
O&M Operations and Maintenance
QL Quantitation Limit (for laboratory data)
QRA Quantitative Risk Assessment (Report)
RL Reporting Limit (for laboratory data)
RQD Rock Quality Designation
SPT Standard Penetration Test
SSI Statistically Significant Increase (above background concentrations)
SWQS Surface Water Quality Standards
SWS Solid Waste Section (of NCDEQ-Division of Waste Management)
SWSL North Carolina Solid Waste Section Reporting Limits
TOC Top of Casing (Well)
USCS Unified Soil Classification System
USEPA United States Environmental Protection Agency (or EPA)
USGS United States Geological Survey
VOC Volatile Organic Compound
WQMP Water Quality Monitoring Plan (Report)

TABLES

Table 1 Historical Groundwater Elevation Data
Table 2 Field Parameters (May 2015)
Table 3 Quantified Detections of Groundwater Constituents (May 2015)
Table 4 Exceedances of Groundwater Standards (May 2015)
Table 5 Statistical Background Analyses Table 6 MNA Parameters (May 2015)
Table 7 Biodegradation Screening Matrix
Table 8 Hydraulic Gradients and Groundwater Flow Velocities

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Joyce Engineering
TABLE 2: Field Parameters (December 2015)
WELL ID PARAMETER RESULT UNITS COLLECT DATE
MW-10 pH 5.88 S.U. 12/8/2015
MW-10 Temperature 15.8 ºC 12/8/2015
MW-10 Turbidity 17.5 NTU 12/8/2015
MW-10 Conductivity 20.0 µS 12/8/2015
MW-10 Static Water Level 12.74 ft 12/8/2015
MW-10 Well Depth 24.16 ft 12/8/2015
MW-11 pH 6.06 S.U. 12/8/2015
MW-11 Temperature 15.4 ºC 12/8/2015
MW-11 Turbidity 16.7 NTU 12/8/2015
MW-11 ORP -21.4 mV 12/8/2015
MW-11 DO 4.62 mg/L 12/8/2015
MW-11 Ferrous Iron 3.5 mg/L 12/8/2015
MW-11 Conductivity 400.6 µS 12/8/2015
MW-11 Static Water Level 36.33 ft 12/8/2015
MW-11 Well Depth 44.2 ft 12/8/2015
MW-11 pH 5.91 S.U. 2/4/2016
MW-11 Temperature 16.1 ºC 2/4/2016
MW-11 Turbidity 10.5 NTU 2/4/2016
MW-11 ORP -37.9 mV 2/4/2016
MW-11 DO 1.38 mg/L 2/4/2016
MW-11 Conductivity 451.5 µS 2/4/2016
MW-11 Static Water Level 35.8 ft 2/4/2016
MW-11 Well Depth 44.2 ft 2/4/2016
MW-12 pH 5.81 S.U. 12/8/2015
MW-12 Temperature 16.1 ºC 12/8/2015
MW-12 Conductivity 203.4 µS 12/8/2015
MW-12 ORP -6.2 mV 12/8/2015
MW-12 DO 2.47 mg/L 12/8/2015
MW-12 Ferrous Iron 2 mg/L 12/8/2015
MW-12 Turbidity 35.4 NTU 12/8/2015
MW-12 Static Water Level 40.80 ft 12/8/2015
MW-12 Well Depth 53.00 ft 12/8/2015
MW-12 pH 5.82 S.U. 2/4/2016
MW-12 Temperature 15.6 ºC 2/4/2016
MW-12 Conductivity 225.5 µS 2/4/2016
MW-12 ORP 12.4 mV 2/4/2016
MW-12 DO 2.76 mg/L 2/4/2016
MW-12 Turbidity 7.06 NTU 2/4/2016
MW-12 Static Water Level 40.72 ft 2/4/2016
MW-12 Well Depth 53.00 ft 2/4/2016
Burke Co. John's River Waste Management Facility, Permit No 12-03
C+D-over-MSW Landfill 1 of 3
Joyce Engineering
TABLE 2: Field Parameters (December 2015)
WELL ID PARAMETER RESULT UNITS COLLECT DATE
MW-13 pH 4.48 S.U. 12/8/2015
MW-13 Temperature 15.3 ºC 12/8/2015
MW-13 Conductivity 45 µS 12/8/2015
MW-13 Turbidity - NTU 12/8/2015
MW-13 Static Water Level 49.76 ft 12/8/2015
MW-13 Well Depth 59.00 ft 12/8/2015
MW-15S pH 5.11 S.U. 12/9/2015
MW-15S Temperature 15.1 ºC 12/9/2015
MW-15S Conductivity 51.5 µS 12/9/2015
MW-15S Dissolved CO2 110 mg/L 12/9/2015
MW-15S Turbidity 21.4 NTU 12/9/2015
MW-15S Static Water Level 43.85 ft 12/9/2015
MW-15S Well Depth 58.27 ft 12/9/2015
MW-16S pH 5.66 S.U. 12/8/2015
MW-16S Temperature 16.9 ºC 12/8/2015
MW-16S Conductivity 208.5 µS 12/8/2015
MW-16S Turbidity 30.5 NTU 12/8/2015
MW-16S ORP 208.5 mV 12/8/2015
MW-16S Ferrous Iron 3.2 mg/L 12/8/2015
MW-16S DO 1.49 mg/L 12/8/2015
MW-16S Static Water Level 13.2 ft 12/8/2015
MW-16S Well Depth 21.45 ft 12/8/2015
MW-16D pH 7.95 S.U. 12/8/2015
MW-16D Temperature 16 ºC 12/8/2015
MW-16D Turbidity 6.8 NTU 12/8/2015
MW-16D Conductivity 125 µS 12/8/2015
MW-16D Static Water Level 12.7 ft 12/8/2015
MW-16D Well Depth 90.5 ft 12/8/2015
MW-21 pH 5.13 S.U. 12/8/2015
MW-21 Temperature 15.2 ºC 12/8/2015
MW-21 Turbidity 8.15 NTU 12/8/2015
MW-21 Conductivity 15.5 µS 12/8/2015
MW-21 Dissolved Oxygen 7.59 mg/L 12/8/2015
MW-21 Oxygen Reduction Potential 269.9 mV 12/8/2015
MW-21 Ferrous Iron 0 mg/L 12/8/2015
MW-21 Turbidity 25.5 NTU 12/8/2015
MW-21 Static Water Level 38.15 ft 12/8/2015
MW-21 Well Depth 46.8 ft 12/8/2015
Burke Co. John's River Waste Management Facility, Permit No 12-03
C+D-over-MSW Landfill 2 of 3
Joyce Engineering
TABLE 2: Field Parameters (December 2015)
WELL ID PARAMETER RESULT UNITS COLLECT DATE
SMP-5 pH 5.93 S.U. 12/9/2015
SMP-5 Temperature 8.0 ºC 12/9/2015
SMP-5 Conductivity 59 µS 12/9/2015
SMP-5 Turbidity 6.61 NTU 12/9/2015
SMP-6 pH 6.18 S.U. 12/9/2015
SMP-6 Temperature 6.3 ºC 12/9/2015
SMP-6 Conductivity 39 µS 12/9/2015
SMP-6 Turbidity 6.07 NTU 12/9/2015
SMP-7 pH 5.46 S.U. 12/9/2015
SMP-7 Temperature 8.5 ºC 12/9/2015
SMP-7 Conductivity 38 µS 12/9/2015
SMP-7 Turbidity 4.33 NTU 12/9/2015
Notes: ºC= degrees Centigrade
S.U.= Standard Units
µS = microsemens
NTU = Nephelometric Turbidity Units
mg/L = milligrams per liter
mV = millivolts
ft = feet
Verification (resample) event performed 2-04-2016 parameters included.
Burke Co. John's River Waste Management Facility, Permit No 12-03
C+D-over-MSW Landfill 3 of 3
Joyce Engineering
TABLE 3: Quantified Detections of Groundwater Constituents
WELL ID PARAMETER RESULT UNITS SWSL COLLECT DATE
1203-MW10 Benzene 1.6 µg/L 1 12/8/2015
1203-MW10 Cobalt 175 µg/L 10 12/8/2015
1203-MW10 Iron 102,000 µg/L 300 12/8/2015
1203-MW10 Manganese 15,000 µg/L 50 12/8/2015
1203-MW10 Alkalinity, Total as CaCO3 98,400 µg/L NE 12/8/2015
1203-MW10 Chloride 26,500 µg/L NE 12/8/2015
1203-MW10 Total Dissolved Solids 182,000 µg/L NE 12/8/2015
1203-MW11 Barium 140 µg/L 100 12/8/2015
1203-MW11 Benzene 2.2 µg/L 1 12/8/2015
1203-MW11 Cobalt 61.0 µg/L 10 12/8/2015
1203-MW11 Iron 74,200 µg/L 300 12/8/2015
1203-MW11 Manganese 18,100 µg/L 50 12/8/2015
1203-MW11 Zinc 20.0 µg/L 10 12/8/2015
1203-MW11 1,4-Dichlorobenzene 12.6 µg/L 1 12/8/2015
1203-MW11 cis-1,2-Dichloroethene 6.9 µg/L 5 12/8/2015
1203-MW11 beta-BHC 0.16 µg/L 0.05 12/8/2015
1203-MW11 beta-BHC (Resample) 0.33 µg/L 0.05 2/4/2016
1203-MW11 Alkalinity, Total as CaCO3 202,000 µg/L NE 12/8/2015
1203-MW11 Chloride 30,800 µg/L NE 12/8/2015
1203-MW11 Total Dissolved Solids 280,000 µg/L NE 12/8/2015
1203-MW12 Antimony 6.3 µg/L 6 12/8/2015
1203-MW12 Antimony (Rerun) 6.2 µg/L 6 12/8/2015
1203-MW12 Antimony (Resample) ND µg/L 6 2/4/2016
1203-MW12 Barium 132 µg/L 100 12/8/2015
1203-MW12 Benzene 2.3 µg/L 1 12/8/2015
1203-MW12 Chromium 13.8 µg/L 10 12/8/2015
1203-MW12 Chromium (Rerun) 14.7 µg/L 10 12/8/2015
1203-MW12 Chromium (Resample) ND µg/L 10 2/4/2016
1203-MW12 Cobalt 84.8 µg/L 10 12/8/2015
1203-MW12 Iron 50,200 µg/L 300 12/8/2015
1203-MW12 Manganese 10,800 µg/L 50 12/8/2015
1203-MW12 Vanadium 36.9 µg/L 25 12/8/2015
1203-MW12 Vanadium (Rerun) 19.8 J µg/L 25 12/8/2015
1203-MW12 Zinc 65.1 µg/L 10 12/8/2015
1203-MW12 1,1-Dichloroethane 31.7 µg/L 5 12/8/2015
1203-MW12 1,4-Dichlorobenzene 4.8 µg/L 1 12/8/2015
1203-MW12 cis-1,2-Dichloroethene 9.9 µg/L 5 12/8/2015
1203-MW12 Ethylbenzene 1.2 µg/L 1 12/8/2015
1203-MW12 Trichloroethene 1.4 µg/L 1 12/8/2015
1203-MW12 Alkalinity, Total as CaCO3 88,800 µg/L NE 12/8/2015
1203-MW12 Chloride 9,400 µg/L NE 12/8/2015
1203-MW12 Total Dissolved Solids 117,000 µg/L NE 12/8/2015
Burke Co. John's River Waste Management Facility, Permit No. 12-03
C+D-over-MSW Landfill 1 of 2
Joyce Engineering
TABLE 3: Quantified Detections of Groundwater Constituents
WELL ID PARAMETER RESULT UNITS SWSL COLLECT DATE
1203-MW13 Benzene 13.8 µg/L 1 12/8/2015
1203-MW13 Cobalt 49.7 µg/L 10 12/8/2015
1203-MW13 Iron 1,460 µg/L 300 12/8/2015
1203-MW13 Manganese 1,500 µg/L 50 12/8/2015
1203-MW13 Zinc 19.0 µg/L 10 12/8/2015
1203-MW13 1,1-Dichloroethane 33.7 µg/L 5 12/8/2015
1203-MW13 1,2-Dichloroethane 1.3 µg/L 1 12/8/2015
1203-MW13 1,4-Dichlorobenzene 13.2 µg/L 1 12/8/2015
1203-MW13 cis-1,2-Dichloroethene 25.8 µg/L 5 12/8/2015
1203-MW13 Ethylbenzene 2.7 µg/L 1 12/8/2015
1203-MW13 Methylene Chloride 113 µg/L 1 12/8/2015
1203-MW13 Tetrachloroethene 5.6 µg/L 1 12/8/2015
1203-MW13 Toluene 6.0 µg/L 1 12/8/2015
1203-MW13 Trichloroethene 9.7 µg/L 1 12/8/2015
1203-MW13 Xylene (Total) 45.4 µg/L 5 12/8/2015
1203-MW13 Alkalinity, Total as CaCO3 9,130 µg/L NE 12/8/2015
1203-MW13 Chloride 1,910 µg/L NE 12/8/2015
1203-MW16D Manganese 124 µg/L 50 12/8/2015
1203-MW16D Alkalinity, Total as CaCO3 46,200 µg/L NE 12/8/2015
1203-MW16D Total Dissolved Solids 93,000 µg/L NE 12/8/2015
1203-MW16S Benzene 1.7 µg/L 1 12/8/2015
1203-MW16S Cobalt 32.8 µg/L 10 12/8/2015
1203-MW16S Iron 27,400 µg/L 300 12/8/2015
1203-MW16S Manganese 8,440 µg/L 50 12/8/2015
1203-MW16S Zinc 47.3 µg/L 10 12/8/2015
1203-MW16S 1,1-Dichloroethane 10.3 µg/L 5 12/8/2015
1203-MW16S 1,2-Dichloroethane 1.3 µg/L 1 12/8/2015
1203-MW16S 1,4-Dichlorobenzene 9.1 µg/L 1 12/8/2015
1203-MW16S Vinyl chloride 1.4 µg/L 1 12/8/2015
1203-MW16S Alkalinity, Total as CaCO3 95,900 µg/L NE 12/8/2015
1203-MW16S Chloride 4,190 µg/L NE 12/8/2015
1203-MW16S Total Dissolved Solids 106,000 µg/L NE 12/8/2015
Notes: µg/L = Micrograms per liter
ND = Not detected
J = Estimated concentration below the SWSL
B = Blank-qualified detection.
SWSL = NC Solid Waste Section Reporting Limit
NE = SWSL not established.
Laboratory Reporting limit used when SWSL has not been established
Rerun = Results from a laboratory reanalysis of the original sample.
Resample = Results from a resampling (verification) event performed on February 4, 2016.
Burke Co. John's River Waste Management Facility, Permit No. 12-03
C+D-over-MSW Landfill 2 of 2
Joyce Engineering
TABLE 4: Exceedances of Groundwater Standards (December 2015)
WELL ID PARAMETER RESULT UNITS
NC2L/
*GWPS GPS SWSL COLLECT DATE
1203-MW10 Cobalt 175 µg/L 1* 266 10 12/8/2015
1203-MW10 Iron 102,000 µg/L 300 300 300 12/8/2015
1203-MW10 Manganese 15,000 µg/L 50 50 50 12/8/2015
1203-MW10 Benzene 1.6 µg/L 111 12/8/2015
1203-MW11 Cobalt 61 µg/L 1* 96.6 10 12/8/2015
1203-MW11 Iron 74,200 µg/L 300 300 300 12/8/2015
1203-MW11 Manganese 18,100 µg/L 50 50 50 12/8/2015
1203-MW11 Benzene 2.2 µg/L 111 12/8/2015
1203-MW11 1,4-Dichlorobenzene 12.6 µg/L 661 12/8/2015
1203-MW11 beta-BHC 0.16 µg/L 0.019 0.019 0.05 12/8/2015
1203-MW11 beta-BHC (resample) 0.33 µg/L 0.019 0.019 0.05 2/4/2016
1203-MW12 Antimony 6.3 µg/L 1 1 6 12/8/2015
1203-MW12 Antimony (Rerun) 6.2 µg/L 1 1 6 12/8/2015
1203-MW12 Antimony (Resample) ND µg/L 1 1 6 2/4/2016
1203-MW12 Chromium 13.8 µg/L 10 10 10 12/8/2015
1203-MW12 Chromium (Rerun) 14.7 µg/L 10 10 10 12/8/2015
1203-MW12 Chromium (Resample) ND µg/L 10 10 10 2/4/2016
1203-MW12 Vanadium 36.9 µg/L 0.3 630 25 12/8/2015
1203-MW12 Vanadium (Rerun) 19.8 J µg/L 0.3 630 25 12/8/2015
1203-MW12 Cobalt 84.8 µg/L 1* 96.6 10 12/8/2015
1203-MW12 Iron 50,200 µg/L 300 300 300 12/8/2015
1203-MW12 Manganese 10,800 µg/L 50 50 50 12/8/2015
1203-MW12 Benzene 2.3 µg/L 111 12/8/2015
1203-MW12 1,1-Dichloroethane 31.7 µg/L 115 12/8/2015
1203-MW13 Cobalt 49.7 µg/L 1* 96.6 10 12/8/2015
1203-MW13 Iron 1,460 µg/L 300 300 300 12/8/2015
1203-MW13 Manganese 1,500 µg/L 50 50 50 12/8/2015
1203-MW13 Benzene 13.8 µg/L 111 12/8/2015
1203-MW13 1,4-Dichlorobenzene 13.2 µg/L 661 12/8/2015
1203-MW13 1,1-Dichloroethane 33.7 µg/L 115 12/8/2015
1203-MW13 1,2-Dichloroethane 1.3 µg/L 0.4 0.4 1 12/8/2015
1203-MW13 Methylene Chloride 113 µg/L 551 12/8/2015
1203-MW13 Tetrachloroethene 5.6 µg/L 0.7 0.7 1 12/8/2015
1203-MW16S Cobalt 32.8 µg/L 1* 96.6 10 12/8/2015
1203-MW16S Iron 27,400 µg/L 300 300 300 12/8/2015
1203-MW16S Manganese 8,440 µg/L 50 50 50 12/8/2015
1203-MW16S Benzene 1.7 µg/L 111 12/8/2015
1203-MW16S 1,4-Dichlorobenzene 9.1 µg/L 661 12/8/2015
1203-MW16S 1,1-Dichloroethane 10.3 µg/L 115 12/8/2015
1203-MW16S 1,2-Dichloroethane 1.3 µg/L 0.4 0.4 1 12/8/2015
1203-MW16S Vinyl chloride 1.4 µg/L 0.03 0.03 1 12/8/2015
Notes: µg/L = Micrograms per liter
SWSL = NC Solid Waste Section Reporting Limit
Laboratory Reporting limit used when SWSL has not been established
B = Blank-qualified detection.
NC2L = NC Groundwater Standard from 15A NCAC 2L.0202
*GWPS = NC Solid Waste Section Groundwater Protection Standard (for constituents with no NC2L)
GPS = Groundwater Protection Standard as defined by 15A NCAC 13B.1634(g)
GPS for cobalt & vanadium are based on statistical background - see Table5.
For MW-10, the cobalt background is based on intrawell statistics.
An ASD for iron and manganese was approved by the DENR, so these are not considered GPS exceedances.
Rerun = Results from a laboratory reanalysis of the original sample.
Resample = Results from a resampling (verification) event performed on February 4, 2016.
BOLD lines indicate GPS exceedances after considering resample results and approved ASDs.
Burke Co. John's River Waste Management Facility, Permit No. 12-03
C+D-over-MSW Landfill
Joyce Engineering
TA
B
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TABLE 6: MNA Parameters (Dec. 2015)
Upgradient
Analyte/Parameter Date Units MW-21 MW-11 MW-12 MW-16S
Temperature (FP)12/8/2015 oC 15.20 15.40 16.10 16.90
pH (FP)12/8/2015 S.U. 5.13 6.06 5.81 5.66
Specific Conductance (FP)12/8/2015 µS/cm 15.5 400.6 203.4 208.5
ORP (FP)12/8/2015 mV 269.9 -21.4 -6.2 25.7
Turbidity (FP)12/8/2015 ntu 25.5 16.7 35.40 30.50
Dissolved Oxygen (FP)12/8/2015 mg/L 7.59 4.62 2.47 1.49
Iron II (ferrous iron) (FP)12/8/2015 mg/L 0.0 3.5 2.0 3.2
Nitrate 12/8/2016 mg/L .256 J <0.1 <0.1 <0.1
Alkalinity 12/8/2015 mg/L 1.030 J 202.000 88.800 95.900
Chloride 12/8/2015 mg/L 0.859 J 30.800 9.400 4.190
Sulfate 12/8/2015 mg/L ND 1.530 J 2.020 J 9.260 J
Sulfide 12/8/2015 mg/L ND ND ND ND
Methane 12/8/2015 mg/L 2.0 J 0.959 0.796 7.510
Dissolved Hydrogen 12/8/2016 nM 2.0 1.6 2.3 1.9
TOC 12/8/2016 mg/L ND 5.320 -- 6.070
Notes: (FP) = Field Parameter
ND = Not Detected
J = Estimated concentration
ORP = Oxidation-Reduction Potential
TOC = Total Organic Carbon
mV = millivolts
S.U. = standard units
oC = degrees Celcius
mS/cm = microsiemens per centimeter
mg/L = milligrams per liter (parts per million)
µg/L = micrograms per liter (parts per billion)
-- MW-12 TOC sample for 12/08/15 was broken in transit to the laboratory and could not be analyzed.
Downgradient
Burke Co. John's River Waste Managment Facility, Permit 12-03
C+D-over-MSW Landfill
Joyce Engineering
TABLE 7: Biodegradation Screening Matrix
Parameter Concentration Interpretation Possible Points Awarded Points Awarded
in Plume Points with DP points without DP points
Oxygen < 0.5 mg/L Tolerated, suppresses the reductive pathway at higher 3 0 0
concentrations
> 5 mg/L Not tolerated; however, vinyl chloride may be oxidized -3 0 0
aerobically
Nitrate < 1 mg/L At higher concentrations may compete with reductive 2 2 2
pathway
Iron II (Ferrous Iron) > 1 mg/L Reductive pathway possible; vinyl chloride may be 3 3 3
oxidized under Fe (III) - reducing conditions
Sulfate < 20 mg/L At higher concentrations may compete with reductive 2 2 2
pathway
Sulfide > 1 mg/L Reductive pathway possible 3 NS (0) NS (0)
Methane < 0.5 mg/L Vinyl chloride oxidizes 0
> 0.5 mg/L Ultimate reductive daughter product, vinyl chloride 3 3 0
accumulates
Oxidation Reduction < 50 mV Reductive pathway possible 1 1 1
Potential < -100 mV Reductive pathway likely 2
pH 5 < pH < 9 Optimal range for reductive pathway 0 0 0
5 > pH > 9 Outside optimal range for reductive pathway -2 0 0
TOC > 20 mg/L Carbon and energy source; drives dechlorination; can 2 0 0
be natural or anthropogenic
Temperature >20o C At T > 20
oC biochemical process is accelerated 10 0
Carbon Dioxide > 2x background Ultimate oxidative daughter product 1 NS (1) 0
Alkalinity > 2x background Results from interaction between CO2 and 11 1
aquifer minerals
Chloride > 2x background Daughter product of organic chlorine 2 2 2
Hydrogen > 1 nM Reductive pathway possible 3 3 3
< 1 nM Vinyl chloride oxidizes 0
Volatile Fatty Acids > 0.1 mg/L Intermediates resulting from biodegradation of more 2 NS (0) NS (0)
complex compounds; carbon and energy source
BTEX > 0.1 mg/L Carbon and energy source; drives dechlorination 2 0 0
Tetrachloroethene (PCE) --- Material released 0 0 0
Trichloroethene (TCE) --- Material released 0 0 0
--- Daughter product of PCE 2 2 0
Dichloroethenes (DCE) --- Material released 0 0 0
Daughter product of TCE 2 2 0
Dichloroethene, cis-1,2, --- Material released 0 0 0
--- Daughter product of trichlorethene 2 2 0
Vinyl Chloride (VC) --- Material released 0 0 0
--- Daughter product of DCE 2 2 0
1,1,1-Trichloroethane (TCA) --- Material released 0 0 0
1,1-Dichloroethane (DCA) --- Material released 0 0 0
Daughter product of TCA 2 2 0
Chloroethane --- Daughter product of dichloroethane or vinyl chloride
under reducing conditions 2 0 0
Ethene/Ethane > 0.01 mg/L Daughter products of vinyl chloride/ethene 2 NS (0) NS (0)
> 0.1 mg/L 3 NS (0) NS (0)
Chloroform --- Material released 0 0 0
--- Daughter product of carbon tetrachloride 2 0 0
Dichloromethane (MC) --- Material released 0 0 0
(Methylene Chloride) --- Daughter product of chloroform 2 0 0
Based on samples collected on December 8, 2015. Total Points Awarded Excluding Historical Data: 27 14
Total Points Awarded Including Historical Data: 28 14
mg/L = miligrams per liter
mV = millivolts NOTE: Chloroethane, Methane, TCE, DCE, cis-1,2-DCE, MC, VC, DCA, and CO2 are all present in the plume; however,
nM = Nanometer it is uncertain whether these are primary leachate constituents or daughter products (DPs); therefore, we
C = Celcius have two calculation columns. The first column assumes all of these are daughter products, and the
NA = Not Analyzed second column assumes none of them are. The true score is probably between the two.
BTEX = Sum of Benzene, Toluene, Ethylbenzene, and Total Xylenes
NS (0) = Not sampled for this parameter, value in parenthsis is a score based on historical data.SCORE: Evid. of Nat. Atten.
< 5 inadequate
This screening matrix is prepared in general accordance with the United Stated Environmental Protection Agency's 6-14 limited
(EPA's) Table 2.3 Analytical Parameters and Weighted for Preliminary Screening for Anaerobic Biodegradation 15-19 adequate
Process presented in the EPA's Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents > 20 strong
in Groundwater, September 1988.
Burke Co. John's River Waste management Facility, Permit 12-03
C+D-over-MSW Landfill
Joyce Engineering
TA
B
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Joyce Engineering

CHARTS

Chart 1: Benzene Concentrations vs. Time
Chart 2: 1,4-Dichlorobenzene Concentrations vs. Time
Chart 3: 1,1-Dichloroethane Concentrations vs. Time
Chart 4: 1,2-Dichloroethane Concentrations vs. Time
Chart 5: Tetrachloroethylene (PCE) Concentrations vs. Time
Chart 6: Trichloroethylene (TCE) Concentrations vs. Time
Chart 7: Vinyl Chloride Concentrations vs. Time
Chart 8: Methylene Chloride Concentrations vs. Time
Chart 9 alpha-BHC Concentrations vs. Time
Chart 10: beta-BHC Concentrations vs. Time

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Joyce  Engineering
024681012141618
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l
)
Ch
a
r
t
 1:

Be
n
z
e
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 Co
n
c
e
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t
r
a
t
i
o
n
 vs
.
 Ti
m
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 in
 Do
w
n
g
r
a
d
i
e
n
t
 We
l
l
s
MW ‐10 MW ‐11 MW ‐12 MW ‐13 MW ‐16S GPS
Jo
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'
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 La
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f
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l
l
,
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k
e
 Co
.
Pe
r
m
i
t
 12
‐03
Joyce  Engineeirng
0510152025
M
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‐
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4
N
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M
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Nov‐13 May‐14 Nov‐14 May‐15 Nov‐15
C
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r
a
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n

(
µ
g
/
l
)
Ch
a
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t
 2:

1,
4
‐Di
c
h
l
o
r
o
b
e
n
z
e
n
e
 Co
n
c
e
n
t
r
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t
i
o
n
 vs
.
 Ti
m
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 in
 Do
w
n
g
r
a
d
i
e
n
t
 We
l
l
s
MW ‐10 MW ‐11 MW ‐12 MW ‐13 MW ‐16S GPS
Jo
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,
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 Co
.
Pe
r
m
i
t
 12
‐03
Joyce  Engineering
050
10
0
15
0
20
0
25
0
30
0
M
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‐
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N
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M
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M
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M
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M
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‐
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N
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‐
1
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M
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‐
1
3
Nov‐13 May‐14 Nov‐14 May‐15 Nov‐15
C
o
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c
e
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t
r
a
t
i
o
n

(
µ
g
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Ch
a
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t
 3:

1,
1
‐Di
c
h
l
o
r
o
e
t
h
a
n
e
 vs
.
 Ti
m
e
 in
 Do
w
n
g
r
a
d
i
e
n
t
 We
l
l
s
MW ‐10 MW ‐11 MW ‐12 MW ‐13 MW ‐16S GPS
Jo
h
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'
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v
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r
 La
n
d
f
i
l
l
,
 Bu
r
k
e
 Co
.
Pe
r
m
i
t
 12
‐03
Joyce  Engineering
02468101214
N
o
v
‐
0
5
M
a
y
‐
0
6
N
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‐
0
6
M
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‐
0
7
N
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‐
0
7
M
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‐
0
8
N
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‐
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M
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‐
0
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N
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M
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1
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M
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‐
1
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M
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‐
1
2
N
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‐
1
2
M
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‐
1
3
N
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v
‐
1
3
M
a
y
‐
1
4
Nov‐14 May‐15 Nov‐15
C
o
n
c
e
n
t
r
a
t
i
o
n

(
µ
g
/
l
)
Ch
a
r
t
 4:

1,
2
‐Di
c
h
l
o
r
o
e
t
h
a
n
e
 vs
.
 Ti
m
e
 in
 Do
w
n
g
r
a
d
i
e
n
t
 We
l
l
s
MW ‐10 MW ‐11 MW ‐12 MW ‐13 MW ‐16S GPS
Jo
h
n
'
s
 Ri
v
e
r
 La
n
d
f
i
l
l
,
 Bu
r
k
e
 Co
.
Pe
r
m
i
t
 12
‐03
Joyce  Engineering
02468101214
M
a
y
‐
9
7
N
o
v
‐
9
7
M
a
y
‐
9
8
N
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‐
9
8
M
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‐
9
9
N
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‐
9
9
M
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0
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N
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M
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N
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M
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2
M
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‐
0
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M
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‐
0
4
N
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‐
0
4
M
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‐
0
5
N
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‐
0
5
M
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‐
0
6
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‐
0
6
M
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‐
0
7
N
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‐
0
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M
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‐
0
8
N
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‐
0
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M
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‐
0
9
N
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‐
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M
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‐
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M
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‐
1
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N
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‐
1
2
M
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‐
1
3
N
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v
‐
1
3
May‐14 Nov‐14 May‐15 Nov‐15
C
o
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c
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n
t
r
a
t
i
o
n

(
µ
g
/
l
)
Ch
a
r
t
 5:

Te
t
r
a
c
h
l
o
r
o
e
t
h
e
n
e
 vs
.
 Ti
m
e
 in
 Do
w
n
g
r
a
d
i
e
n
t
 We
l
l
s
MW ‐10 MW ‐11 MW ‐12 MW ‐13 MW ‐16S GPS
Jo
h
n
'
s
 Ri
v
e
r
 La
n
d
f
i
l
l
,
 Bu
r
k
e
 Co
.
Pe
r
m
i
t
 12
‐03
Joyce  Engineering
02468101214161820
M
a
y
‐
9
4
N
o
v
‐
9
4
M
a
y
‐
9
5
N
o
v
‐
9
5
M
a
y
‐
9
6
N
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‐
9
6
M
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‐
9
7
N
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‐
9
7
M
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‐
9
8
N
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‐
9
8
M
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‐
9
9
N
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‐
9
9
M
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‐
0
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N
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‐
0
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M
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‐
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M
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0
2
N
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‐
0
2
M
a
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‐
0
3
N
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‐
0
3
M
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‐
0
4
N
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‐
0
4
M
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‐
0
5
N
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‐
0
5
M
a
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‐
0
6
N
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‐
0
6
M
a
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‐
0
7
N
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‐
0
7
M
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‐
0
8
N
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‐
0
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M
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‐
0
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N
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M
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1
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‐
1
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M
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1
2
M
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‐
1
3
Nov‐13 May‐14 Nov‐14 May‐15 Nov‐15
C
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n
c
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t
r
a
t
i
o
n

(
µ
g
/
l
)
Ch
a
r
t
 6:

Tr
i
c
h
l
o
r
o
e
t
h
e
n
e
 vs
.
 Ti
m
e
 in
 Do
w
n
g
r
a
d
i
e
n
t
 We
l
l
s
MW ‐10 MW ‐11 MW ‐12 MW ‐13 MW ‐16S GPS
Jo
h
n
'
s
 Ri
v
e
r
 La
n
d
f
i
l
l
,
 Bu
r
k
e
 Co
.
Pe
r
m
i
t
 12
‐03
Joyce  Engineering
0
0.
5
1
1.
5
2
2.
5
3
3.
5
4
M
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‐
0
7
N
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‐
0
7
M
a
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‐
0
8
N
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‐
0
8
M
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‐
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M
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1
3
N
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1
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M
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‐
1
4
N
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‐
1
4
May‐15 Nov‐15
C
o
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c
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n
t
r
a
t
i
o
n

(
µ
g
/
l
)
Ch
a
r
t
 7:

Vi
n
y
l
 Ch
l
o
r
i
d
e
 vs
.
 Ti
m
e
 in
 Do
w
n
g
r
a
d
i
e
n
t
 We
l
l
s
MW ‐10 MW ‐11 MW ‐12 MW ‐13 MW ‐16S GPS
Jo
h
n
'
s
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v
e
r
 La
n
d
f
i
l
l
,
 Bu
r
k
e
 Co
.
Pe
r
m
i
t
 12
‐03
Joyce  Engineering
0
10
0
20
0
30
0
40
0
50
0
60
0
70
0
80
0
90
0
M
a
y
‐
9
4
N
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v
‐
9
4
M
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‐
9
5
N
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‐
9
5
M
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‐
9
6
N
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‐
9
6
M
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9
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9
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M
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9
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9
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9
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0
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a
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0
3
N
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‐
0
3
M
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‐
0
4
N
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‐
0
4
M
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0
5
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0
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0
6
N
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‐
0
6
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‐
0
7
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0
8
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0
8
M
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M
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M
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M
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1
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N
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1
2
M
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‐
1
3
Nov‐13 May‐14 Nov‐14 May‐15 Nov‐15
C
o
n
c
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n
t
r
a
t
i
o
n

(
µ
g
/
l
)
Ch
a
r
t
 8:

Me
t
h
y
l
e
n
e
 Ch
l
o
r
i
d
e
 vs
.
 Ti
m
e
 in
 Do
w
n
g
r
a
d
i
e
n
t
 We
l
l
s
MW ‐10 MW ‐11 MW ‐12 MW ‐13 MW ‐16S GPS
Jo
h
n
'
s
 Ri
v
e
r
 La
n
d
f
i
l
l
,
 Bu
r
k
e
 Co
.
Pe
r
m
i
t
 12
‐03

Joyce  Engineering
0
0.
0
2
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0
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0.
0
6
0.
0
8
0.
1
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1
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4
0.
1
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0.
1
8
0.
2
M
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‐
9
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N
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7
N
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9
7
M
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9
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‐
9
8
M
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‐
9
9
N
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9
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M
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0
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N
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M
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‐
0
2
M
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0
3
N
o
v
‐
0
3
M
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‐
0
4
N
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0
4
M
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‐
0
5
N
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‐
0
5
M
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0
6
N
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‐
0
6
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N
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M
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0
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1
2
M
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3
N
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v
‐
1
3
May‐14 Nov‐14 May‐15 Nov‐15
C
o
n
c
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t
r
a
t
i
o
n

(
µ
g
/
l
)
Ch
a
r
t
 9:

al
p
h
a
‐BH
C
 vs
.
 Ti
m
e
 in
 Do
w
n
g
r
a
d
i
e
n
t
 We
l
l
s
MW ‐10 MW ‐11 MW ‐12 MW ‐13 MW ‐16S GPS
Jo
h
n
'
s
 Ri
v
e
r
 La
n
d
f
i
l
l
,
 Bu
r
k
e
 Co
.
Pe
r
m
i
t
 12
‐03
Joyce  Engineering
0
0.
0
5
0.
1
0.
1
5
0.
2
0.
2
5
0.
3
0.
3
5
N
o
v
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1
0
M
a
y
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1
1
N
o
v
‐
1
1
M
a
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1
2
N
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v
‐
1
2
M
a
y
‐
1
3
N
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v
‐
1
3
M
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y
‐
1
4
N
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v
‐
1
4
M
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‐
1
5
Nov‐15
C
o
n
c
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t
r
a
t
i
o
n

(
µ
g
/
l
)
Ch
a
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 10
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 Ti
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 in
 Do
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MW ‐10 MW ‐11 MW ‐12 MW ‐13 MW ‐16S GPS

FIGURE

Figure 1: Site Location Map

DRAWING

Drawing 1: Groundwater Potentiometric Surface Map

SMP-5 SURFACE MONITORING POINT LOCATION AND IDENTIFICATION
NOT MEASURED
LEGEND
PROPERTY LINE
EXISTING ROAD
EXISTING 25' TOPOGRAPHIC CONTOUR
EXISTING 2' TOPOGRAPHIC CONTOUR
GROUNDWATER SURFACE CONTOUR [FEET
ABOVE MEAN SEA LEVEL (AMSL)]
APPROXIMATE LIMITS OF WASTE
CENTERLINE OF STREAM
GAS PROBE LOCATION AND IDENTIFICATION
PIEZOMETER LOCATION AND IDENTIFICATION
COMPLIANCE WELL LOCATION AND IDENTIFICATION WITH STATIC
WATER LEVEL ELEVATION (FEET AMSL)
(NM)
GP
1050
1020
MW-13
1009.64
PZ-9D
GMP-3
TOPOGRAPHIC CONTOUR INTERVAL = 2 AND 10 FEET.
GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET.
STATIC WATER LEVELS WERE MEASURED ON DECEMBER 9,2015.
GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION BETWEEN AND
EXTRAPOLATION FROM KNOWN DATA, TOPOGRAPHIC CONTOURS, AND KNOWN
FIELD CONDITIONS.
MW-16D GROUNDWATER ELEVATION WAS NOT USED IN CALCULATING
GROUNDWATER CONTOURS.
NOTES
EXISTING 5' TOPOGRAPHIC CONTOUR
EXISTING 10' TOPOGRAPHIC CONTOUR1080
T1 TEMPORARY WELL
APPROXIMATE LOCATION OF SPRING HEAD
1.
2.
3.
4.
5.
JE-0020 CONTROL POINT LOCATION AND IDENTIFICATION
SENTINEL WELL LOCATION AND IDENTIFICATION WITH STATIC
WATER LEVEL ELEVATION (FEET AMSL)
MW-18
GROUNDWATER FLOW PATHWAY USED TO
CALCULATE HYDRAULIC GRADIENT
1
SEGMENT USED FOR GRADIENT CALCULATION
ABANDONED OR UNUSED MONITORING WELL
i
i
i
FLOW PATH LENGTH
967 LF
1,495 LF
1,098 LF
770 LFi
1
0
0
0
1
0
1
0
1
0
2
0
1
0
3
0
1
0
4
0
1
0
5
0
1
0
6
0
1
0
7
0
1
0
8
0
1
0
9
0
1
1
0
0
1
1
1
0
1
1
2
0
1
1
3
0
1
1
4
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5
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6
0
1
1
5
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4
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1
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3
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108
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0
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6
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1
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5
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1
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4
0
105
0
10
0
0
10
6
0
10
5
0
10
4
0
10
3
0
10
2
0
1010
1000
10
7
0
4
(ABANDONED)
PZ-2S
(ABANDONED)
PZ-2D
(NM)
PZ-23
(NM)
PZ-15
(NM)
PZ-22D
1042.60
PZ-22S
(NM)
PZ-16S
1017.69
PZ-12
(NM)PZ-27
(NM)
PZ-14
(NM)
PZ-13
(ND)PZ-9D
(NM)
PZ-9S1009.64
MW-13
SMP-6
993.42
MW-12
992.25
MW-11
995.17
MW-16D 994.47
MW-16S
999.49
MW-10
SMP-5
MW-9
(NM)MW-14
1025.19
MW-15S
(NM)
MW-15D
(NM)MW-8
(NM)
MW-1
(FORMERLY PZ-4)
MW-20
NM
MW-17
SHOOTING
RANGE
MULCHING
AREA
L
O
W
E
R

C
R
E
E
K
JOH
N
S

R
I
V
E
R
CATAW
B
A

R
I
V
E
R
WETLAND
EXISTING TRAIL
TRANSFER FACILITY
EXISTING
SEDIMENT
BASIN
EXISTING C&D
DISPOSAL AREA
CURRENT BACKGROUND WELL
FORMER
MW-18 MW-19
OFFICE
AND
GARAGE
MW-38
1046.24
MW-36
1066.72
PZ-30S
1045.57
PZ-30D
PZ-31
1058.70
PZ-35
1063.39
BACKGROUND WELL
CURRENT PHASE 1A LIMITS
PROJECT NO.
AP
P
R
O
V
E
D
CH
E
C
K
E
D
DR
A
W
N
DE
S
I
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A
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F

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E
BY
NO
AP
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SCALE

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DRAWING NO.
L:
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AS NOTED
GR
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1
2
-
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GE
RW
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VB VB
01
/
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/
1
6
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(FEET)
GRAPHIC SCALE
400200100

APPENDICES

Appendix A Field Data Logs
Appendix B Laboratory Analytical Reports
Appendix C Statistical Analyses Worksheets
Appendix D Historical Detected Inorganic Groundwater Constituents
Appendix E Historical Detected Organic Groundwater Constituents
Appendix F Historical Detected Constituents in Performance & Sentinel Wells
Appendix G Historical Detected Surface Water Constituents
Appendix H Historical MNA Parameters
Appendix I Biochlor Modeling Input & Output

Appendix A

Field Data Logs

Appendix B

Laboratory Analytical Reports

#=CL#
January 21, 2016
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92279395
92279395
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
BURKE-JOHN'S R. C&D/MSWLF-COMP
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on December 10, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc:Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 83
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Ormond Beach Certification IDs8 East Tower Circle, Ormond Beach, FL 32174Alabama Certification #: 41320
Connecticut Certification #: PH-0216Delaware Certification: FL NELAC ReciprocityFlorida Certification #: E83079Georgia Certification #: 955Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC ReciprocityIllinois Certification #: 200068Indiana Certification: FL NELAC ReciprocityKansas Certification #: E-10383Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC ReciprocityLouisiana Environmental Certificate #: 05007Maryland Certification: #346Michigan Certification #: 9911Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958New York Certification #: 11608North Carolina Environmental Certificate #: 667North Carolina Certification #: 12710North Dakota Certification #: R-216
Oklahoma Certification #: D9947Pennsylvania Certification #: 68-00547Puerto Rico Certification #: FL01264South Carolina Certification: #96042001Tennessee Certification #: TN02974
Texas Certification: FL NELAC ReciprocityUS Virgin Islands Certification: FL NELAC ReciprocityVirginia Environmental Certification #: 460165West Virginia Certification #: 9962CWisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 83
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Lab ID Sample ID Matrix Date Collected Date Received
92279395001 1203-MW10 Water 12/08/15 11:40 12/10/15 10:48
92279395002 1203-MW11 Water 12/08/15 12:05 12/10/15 10:48
92279395003 1203-MW12 Water 12/08/15 12:51 12/10/15 10:48
92279395004 1203-MW13 Water 12/08/15 15:50 12/10/15 10:48
92279395005 1203-MW16S Water 12/08/15 13:30 12/10/15 10:48
92279395006 1203-MW16D Water 12/08/15 14:32 12/10/15 10:48
92279395007 1203-MW12 Re-run Sb,Cr,V Water 12/08/15 12:51 12/10/15 10:48
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 83
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92279395001 1203-MW10 EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 18 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8270 111 PASI-CBPJ
EPA 8260 68 PASI-CGAW
SM 2320B 1 PASI-AMLS
SM 2540C 1 PASI-AMJP
SM 4500-S2D 1 PASI-AMJP
EPA 300.0 1 PASI-AMDW
SM 4500-Cl-E 1 PASI-AWRC
SM 4500-CN-E 1 PASI-AAES2
92279395002 1203-MW11 EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 18 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8270 111 PASI-CBPJ
EPA 8260 68 PASI-CGAW
SM 2320B 1 PASI-AMLS
SM 2540C 1 PASI-AMJP
SM 4500-S2D 1 PASI-AMJP
EPA 300.0 1 PASI-AMDW
SM 4500-Cl-E 1 PASI-AWRC
SM 4500-CN-E 1 PASI-AAES2
92279395003 1203-MW12 EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 18 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8270 111 PASI-CBPJ
EPA 8260 68 PASI-CGAW
SM 2320B 1 PASI-AMLS
SM 2540C 1 PASI-AMJP
SM 4500-S2D 1 PASI-AMJP
EPA 300.0 1 PASI-AMDW
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 83
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
SM 4500-Cl-E 1 PASI-AWRC
SM 4500-CN-E 1 PASI-AAES2
92279395004 1203-MW13 EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 18 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8270 111 PASI-CBPJ
EPA 8260 68 PASI-CGAW
SM 2320B 1 PASI-AMLS
SM 2540C 1 PASI-AMJP
SM 4500-S2D 1 PASI-AMJP
EPA 300.0 1 PASI-AMDW
SM 4500-Cl-E 1 PASI-AWRC
SM 4500-CN-E 1 PASI-AAES2
92279395005 1203-MW16S EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 18 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8270 111 PASI-CBPJ
EPA 8260 68 PASI-CGAW
SM 2320B 1 PASI-AMLS
SM 2540C 1 PASI-AMJP
SM 4500-S2D 1 PASI-AMJP
EPA 300.0 1 PASI-AMDW
SM 4500-Cl-E 1 PASI-AWRC
SM 4500-CN-E 1 PASI-AAES2
92279395006 1203-MW16D EPA 6010 17 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8260 51 PASI-CGAW
SM 2320B 1 PASI-AMLS
SM 2540C 1 PASI-AMJP
EPA 300.0 1 PASI-AMDW
SM 4500-Cl-E 1 PASI-AWRC
92279395007 1203-MW12 Re-run Sb,Cr,V EPA 6010 3 PASI-ACDF
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 83
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92279395001 1203-MW10
Barium 45.6J ug/L 12/17/15 03:12100EPA 6010
Cobalt 175 ug/L 12/17/15 03:1210.0EPA 6010
Copper 8.1J ug/L 12/17/15 03:1210.0EPA 6010
Iron 102000 ug/L 12/17/15 16:511500EPA 6010
Lead 7.8J ug/L 12/17/15 03:1210.0EPA 6010
Manganese 15000 ug/L 12/17/15 16:51250EPA 6010
Nickel 5.5J ug/L 12/17/15 03:1250.0EPA 6010
Vanadium 20.4J ug/L 12/17/15 03:1225.0EPA 6010
Zinc 9.0J ug/L 12/17/15 03:1210.0EPA 6010
Benzene 1.6 ug/L 12/19/15 14:161.0EPA 8260
Chlorobenzene 1.5J ug/L 12/19/15 14:163.0EPA 8260
1,4-Dichlorobenzene 0.98J ug/L 12/19/15 14:161.0EPA 8260
1,1-Dichloroethane 0.95J ug/L 12/19/15 14:165.0EPA 8260
cis-1,2-Dichloroethene 3.9J ug/L 12/19/15 14:165.0EPA 8260
Alkalinity, Total as CaCO3 98400 ug/L 12/14/15 15:175000SM 2320B
Total Dissolved Solids 182000 ug/L 12/11/15 10:4125000SM 2540C
Sulfate 10200J ug/L 12/11/15 14:06250000EPA 300.0
Chloride 26500 ug/L 12/17/15 16:561000SM 4500-Cl-E
92279395002 1203-MW11
beta-BHC 0.16 ug/L 12/14/15 21:190.050EPA 8081
Barium 140 ug/L 12/17/15 03:25100EPA 6010
Cobalt 61.0 ug/L 12/17/15 03:2510.0EPA 6010
Copper 6.4J ug/L 12/17/15 03:2510.0EPA 6010
Iron 74200 ug/L 12/17/15 03:25300EPA 6010
Lead 6.3J ug/L 12/17/15 03:2510.0EPA 6010
Manganese 18100 ug/L 12/17/15 16:54250EPA 6010
Nickel 3.4J ug/L 12/17/15 03:2550.0EPA 6010
Vanadium 23.5J ug/L 12/17/15 03:2525.0EPA 6010
Zinc 20.0 ug/L 12/17/15 03:2510.0EPA 6010
Benzene 2.2 ug/L 12/19/15 14:331.0EPA 8260
Chlorobenzene 0.61J ug/L 12/19/15 14:333.0EPA 8260
1,2-Dichlorobenzene 0.39J ug/L 12/19/15 14:335.0EPA 8260
1,4-Dichlorobenzene 12.6 ug/L 12/19/15 14:331.0EPA 8260
1,1-Dichloroethane 3.2J ug/L 12/19/15 14:335.0EPA 8260
1,2-Dichloroethane 0.65J ug/L 12/19/15 14:331.0EPA 8260
cis-1,2-Dichloroethene 6.9 ug/L 12/19/15 14:335.0EPA 8260
Trichloroethene 0.71J ug/L 12/19/15 14:331.0EPA 8260
Vinyl chloride 0.72J ug/L 12/19/15 14:331.0EPA 8260
Alkalinity, Total as CaCO3 202000 ug/L 12/14/15 15:305000SM 2320B
Total Dissolved Solids 280000 ug/L 12/11/15 10:4125000SM 2540C
Sulfate 1530J ug/L 12/11/15 14:06250000EPA 300.0
Chloride 30800 ug/L 12/17/15 16:571000SM 4500-Cl-E
92279395003 1203-MW12
Antimony 6.3 ug/L 12/17/15 03:286.0EPA 6010
Barium 132 ug/L 12/17/15 03:28100EPA 6010
Chromium 13.8 ug/L 12/17/15 03:2810.0EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 83
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92279395003 1203-MW12
Cobalt 84.8 ug/L 12/17/15 03:2810.0EPA 6010
Copper 9.7J ug/L 12/17/15 03:2810.0EPA 6010
Iron 50200 ug/L 12/17/15 03:28300EPA 6010
Lead 9.8J ug/L 12/17/15 03:2810.0EPA 6010
Manganese 10800 ug/L 12/17/15 16:57250EPA 6010
Nickel 17.7J ug/L 12/17/15 03:2850.0EPA 6010
Vanadium 36.9 ug/L 12/17/15 03:2825.0EPA 6010
Zinc 65.1 ug/L 12/17/15 03:2810.0EPA 6010
Benzene 2.3 ug/L 12/19/15 14:491.0EPA 8260
Chlorobenzene 0.73J ug/L 12/19/15 14:493.0EPA 8260
1,4-Dichlorobenzene 4.8 ug/L 12/19/15 14:491.0EPA 8260
1,1-Dichloroethane 31.7 ug/L 12/19/15 14:495.0EPA 8260
cis-1,2-Dichloroethene 9.9 ug/L 12/19/15 14:495.0EPA 8260
Ethylbenzene 1.2 ug/L 12/19/15 14:491.0EPA 8260
Trichloroethene 1.4 ug/L 12/19/15 14:491.0EPA 8260
Alkalinity, Total as CaCO3 88800 ug/L 12/14/15 16:045000SM 2320B
Total Dissolved Solids 117000 ug/L 12/11/15 10:4225000SM 2540C
Sulfate 2020J ug/L 12/11/15 14:06250000EPA 300.0
Chloride 9400 ug/L 12/17/15 16:581000SM 4500-Cl-E
92279395004 1203-MW13
Barium 82.6J ug/L 12/17/15 03:32100EPA 6010
Cobalt 49.7 ug/L 12/17/15 03:3210.0EPA 6010
Iron 1460 ug/L 12/17/15 03:32300EPA 6010
Manganese 1500 ug/L 12/17/15 03:3250.0EPA 6010
Nickel 4.2J ug/L 12/17/15 03:3250.0EPA 6010
Vanadium 3.0J ug/L 12/17/15 03:3225.0EPA 6010
Zinc 19.0 ug/L 12/17/15 03:3210.0EPA 6010
Benzene 13.8 ug/L 12/19/15 15:061.0EPA 8260
Chlorobenzene 0.86J ug/L 12/19/15 15:063.0EPA 8260
1,2-Dichlorobenzene 0.45J ug/L 12/19/15 15:065.0EPA 8260
1,4-Dichlorobenzene 13.2 ug/L 12/19/15 15:061.0EPA 8260
1,1-Dichloroethane 33.7 ug/L 12/19/15 15:065.0EPA 8260
1,2-Dichloroethane 1.3 ug/L 12/19/15 15:061.0EPA 8260
cis-1,2-Dichloroethene 25.8 ug/L 12/19/15 15:065.0EPA 8260
Ethylbenzene 2.7 ug/L 12/19/15 15:061.0EPA 8260
Methylene Chloride 113 ug/L 12/19/15 15:061.0EPA 8260
Naphthalene 2.2J ug/L 12/19/15 15:0610.0EPA 8260
Tetrachloroethene 5.6 ug/L 12/19/15 15:061.0EPA 8260
Tetrahydrofuran 9.7J ug/L 12/19/15 15:0610.0EPA 8260
Toluene 6.0 ug/L 12/19/15 15:061.0EPA 8260
Trichloroethene 9.7 ug/L 12/19/15 15:061.0EPA 8260
Xylene (Total)45.4 ug/L 12/19/15 15:065.0EPA 8260
Alkalinity, Total as CaCO3 9130 ug/L 12/14/15 16:165000SM 2320B
Chloride 1910 ug/L 12/17/15 16:591000SM 4500-Cl-E
92279395005 1203-MW16S
Barium 50.6J ug/L 12/17/15 03:35100EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 83
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92279395005 1203-MW16S
Cobalt 32.8 ug/L 12/17/15 03:3510.0EPA 6010
Copper 5.9J ug/L 12/17/15 03:3510.0EPA 6010
Iron 27400 ug/L 12/17/15 03:35300EPA 6010
Manganese 8440 ug/L 12/17/15 03:3550.0EPA 6010
Vanadium 11.5J ug/L 12/17/15 03:3525.0EPA 6010
Zinc 47.3 ug/L 12/17/15 03:3510.0EPA 6010
Acetone 16.5J ug/L 12/20/15 19:06100EPA 8260
Benzene 1.7 ug/L 12/20/15 19:061.0EPA 8260
Chlorobenzene 0.82J ug/L 12/20/15 19:063.0EPA 8260
1,4-Dichlorobenzene 9.1 ug/L 12/20/15 19:061.0EPA 8260
1,1-Dichloroethane 10.3 ug/L 12/20/15 19:065.0EPA 8260
1,2-Dichloroethane 1.3 ug/L 12/20/15 19:061.0EPA 8260
cis-1,2-Dichloroethene 4.4J ug/L 12/20/15 19:065.0EPA 8260
Toluene 0.31J ug/L 12/20/15 19:061.0EPA 8260
Vinyl chloride 1.4 ug/L 12/20/15 19:061.0EPA 8260
Alkalinity, Total as CaCO3 95900 ug/L 12/14/15 16:275000SM 2320B
Total Dissolved Solids 106000 ug/L 12/11/15 10:4325000SM 2540C
Chloride 4190 ug/L 12/17/15 17:031000SM 4500-Cl-E
92279395006 1203-MW16D
Barium 8.0J ug/L 12/17/15 03:38100EPA 6010
Iron 43.7J ug/L 12/17/15 03:38300EPA 6010
Manganese 124 ug/L 12/17/15 03:3850.0EPA 6010
Zinc 8.2J ug/L 12/17/15 03:3810.0EPA 6010
Alkalinity, Total as CaCO3 46200 ug/L 12/14/15 16:395000SM 2320B
Total Dissolved Solids 93000 ug/L 12/11/15 10:4325000SM 2540C
Sulfate 9260J ug/L 12/11/15 14:06250000EPA 300.0
Chloride 945J ug/L 12/17/15 17:041000SM 4500-Cl-E
92279395007 1203-MW12 Re-run Sb,Cr,V
Antimony 6.2 ug/L 01/19/16 11:576.0EPA 6010
Chromium 14.7 ug/L 01/19/16 11:5710.0EPA 6010
Vanadium 19.8J ug/L 01/19/16 11:5725.0EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW10 Lab ID:92279395001 Collected:12/08/15 11:40 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 12/14/15 20:44 309-00-212/11/15 16:000.050 0.050 1
alpha-BHC ND ug/L 12/14/15 20:44 319-84-612/11/15 16:000.050 0.050 1
beta-BHC ND ug/L 12/14/15 20:44 319-85-712/11/15 16:000.050 0.050 1
delta-BHC ND ug/L 12/14/15 20:44 319-86-812/11/15 16:000.050 0.050 1
gamma-BHC (Lindane)ND ug/L 12/14/15 20:44 58-89-912/11/15 16:000.050 0.050 1
Chlordane (Technical)ND ug/L 12/14/15 20:44 57-74-912/11/15 16:000.50 0.20 1
4,4'-DDD ND ug/L 12/14/15 20:44 72-54-812/11/15 16:000.10 0.050 1
4,4'-DDE ND ug/L 12/14/15 20:44 72-55-912/11/15 16:000.10 0.050 1
4,4'-DDT ND ug/L 12/14/15 20:44 50-29-312/11/15 16:000.10 0.050 1
Dieldrin ND ug/L 12/14/15 20:44 60-57-112/11/15 16:000.075 0.050 1
Endosulfan I ND ug/L 12/14/15 20:44 959-98-812/11/15 16:000.10 0.050 1
Endosulfan II ND ug/L 12/14/15 20:44 33213-65-912/11/15 16:000.10 0.050 1
Endosulfan sulfate ND ug/L 12/14/15 20:44 1031-07-812/11/15 16:000.10 0.050 1
Endrin ND ug/L 12/14/15 20:44 72-20-812/11/15 16:000.10 0.050 1
Endrin aldehyde ND ug/L 12/14/15 20:44 7421-93-4 M112/11/15 16:000.10 0.050 1
Heptachlor ND ug/L 12/14/15 20:44 76-44-812/11/15 16:000.050 0.050 1
Heptachlor epoxide ND ug/L 12/14/15 20:44 1024-57-312/11/15 16:000.075 0.050 1
Methoxychlor ND ug/L 12/14/15 20:44 72-43-512/11/15 16:001.0 0.15 1
Toxaphene ND ug/L 12/14/15 20:44 8001-35-212/11/15 16:001.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)53 %12/14/15 20:44 877-09-812/11/15 16:0020-130 1
Decachlorobiphenyl (S)58 %12/14/15 20:44 2051-24-312/11/15 16:0020-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 12/14/15 18:25 12674-11-212/11/15 16:000.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 12/14/15 18:25 11104-28-212/11/15 16:000.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 12/14/15 18:25 11141-16-512/11/15 16:000.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 12/14/15 18:25 53469-21-912/11/15 16:000.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 12/14/15 18:25 12672-29-612/11/15 16:000.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 12/14/15 18:25 11097-69-112/11/15 16:000.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 12/14/15 18:25 11096-82-512/11/15 16:000.50 0.50 1
Surrogates
Decachlorobiphenyl (S)63 %12/14/15 18:25 2051-24-312/11/15 16:0010-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 12/18/15 11:47 94-75-712/15/15 20:150.94 0.22 1
Dinoseb ND ug/L 12/18/15 11:47 88-85-712/15/15 20:150.19 0.057 1
2,4,5-T ND ug/L 12/18/15 11:47 93-76-512/15/15 20:150.19 0.042 1
2,4,5-TP (Silvex)ND ug/L 12/18/15 11:47 93-72-112/15/15 20:150.19 0.049 1
Surrogates
2,4-DCAA (S)90 %12/18/15 11:47 19719-28-912/15/15 20:1536-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/17/15 03:12 7440-36-012/12/15 00:006.0 3.8 1
Arsenic ND ug/L 12/17/15 03:12 7440-38-212/12/15 00:0010.0 2.5 1
Barium 45.6J ug/L 12/17/15 03:12 7440-39-312/12/15 00:001002.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW10 Lab ID:92279395001 Collected:12/08/15 11:40 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Beryllium ND ug/L 12/17/15 03:12 7440-41-712/12/15 00:001.0 0.50 1
Cadmium ND ug/L 12/17/15 03:12 7440-43-912/12/15 00:001.0 0.50 1
Chromium ND ug/L 12/17/15 03:12 7440-47-312/12/15 00:0010.0 2.5 1
Cobalt 175 ug/L 12/17/15 03:12 7440-48-412/12/15 00:0010.0 2.5 1
Copper 8.1J ug/L 12/17/15 03:12 7440-50-812/12/15 00:0010.0 2.5 1
Iron 102000 ug/L 12/17/15 16:51 7439-89-612/12/15 00:0015001255
Lead 7.8J ug/L 12/17/15 03:12 7439-92-112/12/15 00:0010.0 2.5 1
Manganese 15000 ug/L 12/17/15 16:51 7439-96-512/12/15 00:0025012.5 5
Nickel 5.5J ug/L 12/17/15 03:12 7440-02-012/12/15 00:0050.0 2.5 1
Selenium ND ug/L 12/17/15 03:12 7782-49-212/12/15 00:0010.0 5.0 1
Silver ND ug/L 12/17/15 03:12 7440-22-412/12/15 00:0010.0 2.5 1
Thallium ND ug/L 12/17/15 03:12 7440-28-012/12/15 00:005.5 5.0 1
Tin ND ug/L 12/17/15 03:12 7440-31-512/12/15 00:001002.5 1
Vanadium 20.4J ug/L 12/17/15 03:12 7440-62-212/12/15 00:0025.0 2.5 1
Zinc 9.0J ug/L 12/17/15 03:12 7440-66-612/12/15 00:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/17/15 18:32 7439-97-612/17/15 14:050.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 12/22/15 19:09 83-32-912/15/15 17:2810.0 0.25 1
Acenaphthylene ND ug/L 12/22/15 19:09 208-96-812/15/15 17:2810.0 0.21 1
Acetophenone ND ug/L 12/22/15 19:09 98-86-212/15/15 17:2810.0 2.0 1
2-Acetylaminofluorene ND ug/L 12/22/15 19:09 53-96-312/15/15 17:2820.0 0.84 1
4-Aminobiphenyl ND ug/L 12/22/15 19:09 92-67-112/15/15 17:2820.0 0.92 1
Anthracene ND ug/L 12/22/15 19:09 120-12-712/15/15 17:2810.0 0.14 1
Benzo(a)anthracene ND ug/L 12/22/15 19:09 56-55-312/15/15 17:2810.0 0.33 1
Benzo(a)pyrene ND ug/L 12/22/15 19:09 50-32-812/15/15 17:2810.0 0.30 1
Benzo(b)fluoranthene ND ug/L 12/22/15 19:09 205-99-212/15/15 17:2810.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 12/22/15 19:09 191-24-212/15/15 17:2810.0 0.38 1
Benzo(k)fluoranthene ND ug/L 12/22/15 19:09 207-08-912/15/15 17:2810.0 0.43 1
Benzyl alcohol ND ug/L 12/22/15 19:09 100-51-612/15/15 17:2820.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 12/22/15 19:09 101-55-312/15/15 17:2810.0 1.3 1
Butylbenzylphthalate ND ug/L 12/22/15 19:09 85-68-712/15/15 17:2810.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 12/22/15 19:09 59-50-712/15/15 17:2820.0 4.2 1
4-Chloroaniline ND ug/L 12/22/15 19:09 106-47-812/15/15 17:2820.0 3.4 1
Chlorobenzilate ND ug/L 12/22/15 19:09 510-15-612/15/15 17:2810.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 12/22/15 19:09 111-91-112/15/15 17:2810.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 12/22/15 19:09 111-44-412/15/15 17:2810.0 1.5 1
bis(2-Chloroisopropyl) ether ND ug/L 12/22/15 19:09 108-60-112/15/15 17:2810.0 1.6 1
2-Chloronaphthalene ND ug/L 12/22/15 19:09 91-58-712/15/15 17:2810.0 2.2 1
2-Chlorophenol ND ug/L 12/22/15 19:09 95-57-812/15/15 17:2810.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 12/22/15 19:09 7005-72-312/15/15 17:2810.0 2.1 1
Chrysene ND ug/L 12/22/15 19:09 218-01-912/15/15 17:2810.0 0.21 1
Diallate ND ug/L 12/22/15 19:09 2303-16-412/15/15 17:2810.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 12/22/15 19:09 53-70-312/15/15 17:2810.0 0.55 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW10 Lab ID:92279395001 Collected:12/08/15 11:40 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Dibenzofuran ND ug/L 12/22/15 19:09 132-64-912/15/15 17:2810.0 1.8 1
3,3'-Dichlorobenzidine ND ug/L 12/22/15 19:09 91-94-112/15/15 17:2820.0 1.4 1
2,4-Dichlorophenol ND ug/L 12/22/15 19:09 120-83-212/15/15 17:2810.0 1.7 1
2,6-Dichlorophenol ND ug/L 12/22/15 19:09 87-65-012/15/15 17:2810.0 1.8 1
Diethylphthalate ND ug/L 12/22/15 19:09 84-66-212/15/15 17:2860001.3 1
Dimethoate ND ug/L 12/22/15 19:09 60-51-512/15/15 17:2820.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 12/22/15 19:09 60-11-712/15/15 17:2810.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 12/22/15 19:09 57-97-612/15/15 17:2810.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 12/22/15 19:09 119-93-712/15/15 17:2810.0 2.1 1
2,4-Dimethylphenol ND ug/L 12/22/15 19:09 105-67-912/15/15 17:2810.0 2.2 1
Dimethylphthalate ND ug/L 12/22/15 19:09 131-11-312/15/15 17:2810.0 1.5 1
Di-n-butylphthalate ND ug/L 12/22/15 19:09 84-74-212/15/15 17:2810.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 12/22/15 19:09 534-52-112/15/15 17:2850.0 1.7 1
1,3-Dinitrobenzene ND ug/L 12/22/15 19:09 99-65-012/15/15 17:2820.0 1.5 1
2,4-Dinitrophenol ND ug/L 12/22/15 19:09 51-28-512/15/15 17:2850.0 6.5 1
2,4-Dinitrotoluene ND ug/L 12/22/15 19:09 121-14-212/15/15 17:2810.0 1.2 1
2,6-Dinitrotoluene ND ug/L 12/22/15 19:09 606-20-212/15/15 17:2810.0 1.7 1
Di-n-octylphthalate ND ug/L 12/22/15 19:09 117-84-012/15/15 17:2810.0 0.86 1
Diphenylamine ND ug/L 12/22/15 19:09 122-39-412/15/15 17:2810.0 1.3 1
Disulfoton ND ug/L 12/22/15 19:09 298-04-412/15/15 17:2810.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 12/22/15 19:09 117-81-712/15/15 17:2815.0 0.85 1
Ethyl methanesulfonate ND ug/L 12/22/15 19:09 62-50-012/15/15 17:2820.0 1.8 1
Famphur ND ug/L 12/22/15 19:09 52-85-712/15/15 17:2820.0 1.7 1
Fluoranthene ND ug/L 12/22/15 19:09 206-44-0 L312/15/15 17:2810.0 0.21 1
Fluorene ND ug/L 12/22/15 19:09 86-73-712/15/15 17:2810.0 0.21 1
Hexachlorobenzene ND ug/L 12/22/15 19:09 118-74-112/15/15 17:2810.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 12/22/15 19:09 77-47-412/15/15 17:2810.0 1.8 1
Hexachloroethane ND ug/L 12/22/15 19:09 67-72-112/15/15 17:2810.0 1.5 1
Hexachloropropene ND ug/L 12/22/15 19:09 1888-71-712/15/15 17:2810.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 12/22/15 19:09 193-39-512/15/15 17:2810.0 0.29 1
Isodrin ND ug/L 12/22/15 19:09 465-73-6 L312/15/15 17:2820.0 2.0 1
Isophorone ND ug/L 12/22/15 19:09 78-59-112/15/15 17:2810.0 1.8 1
Isosafrole ND ug/L 12/22/15 19:09 120-58-112/15/15 17:2810.0 1.8 1
Kepone ND ug/L 12/22/15 19:09 143-50-012/15/15 17:2820.0 3.1 1
Methapyrilene ND ug/L 12/22/15 19:09 91-80-5 L212/15/15 17:281002.7 1
3-Methylcholanthrene ND ug/L 12/22/15 19:09 56-49-512/15/15 17:2810.0 0.82 1
Methyl methanesulfonate ND ug/L 12/22/15 19:09 66-27-312/15/15 17:2810.0 1.3 1
2-Methylnaphthalene ND ug/L 12/22/15 19:09 91-57-612/15/15 17:2810.0 0.28 1
Methyl parathion ND ug/L 12/22/15 19:09 298-00-012/15/15 17:2810.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 12/22/15 19:09 95-48-712/15/15 17:2810.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 12/22/15 19:0912/15/15 17:2810.0 1.7 1
1-Naphthalenamine ND ug/L 12/22/15 19:09 134-32-712/15/15 17:2810.0 0.96 1
2-Naphthalenamine ND ug/L 12/22/15 19:09 91-59-812/15/15 17:2810.0 0.98 1
1,4-Naphthoquinone ND ug/L 12/22/15 19:09 130-15-412/15/15 17:2810.0 1.8 1
2-Nitroaniline ND ug/L 12/22/15 19:09 88-74-412/15/15 17:2850.0 2.8 1
3-Nitroaniline ND ug/L 12/22/15 19:09 99-09-212/15/15 17:2850.0 2.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW10 Lab ID:92279395001 Collected:12/08/15 11:40 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
4-Nitroaniline ND ug/L 12/22/15 19:09 100-01-612/15/15 17:2820.0 2.5 1
Nitrobenzene ND ug/L 12/22/15 19:09 98-95-312/15/15 17:2810.0 1.7 1
2-Nitrophenol ND ug/L 12/22/15 19:09 88-75-512/15/15 17:2810.0 1.7 1
4-Nitrophenol ND ug/L 12/22/15 19:09 100-02-712/15/15 17:2850.0 5.8 1
5-Nitro-o-toluidine ND ug/L 12/22/15 19:09 99-55-812/15/15 17:2810.0 1.2 1
N-Nitrosodiethylamine ND ug/L 12/22/15 19:09 55-18-512/15/15 17:2820.0 1.8 1
N-Nitrosodimethylamine ND ug/L 12/22/15 19:09 62-75-912/15/15 17:2810.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 12/22/15 19:09 924-16-312/15/15 17:2810.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 12/22/15 19:09 621-64-712/15/15 17:2810.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 12/22/15 19:09 86-30-612/15/15 17:2810.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 12/22/15 19:09 10595-95-612/15/15 17:2810.0 1.8 1
N-Nitrosopiperidine ND ug/L 12/22/15 19:09 100-75-412/15/15 17:2820.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 12/22/15 19:09 930-55-212/15/15 17:2810.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 12/22/15 19:09 126-68-112/15/15 17:2810.0 1.8 1
Parathion (Ethyl parathion)ND ug/L 12/22/15 19:09 56-38-212/15/15 17:2810.0 1.1 1
Pentachlorobenzene ND ug/L 12/22/15 19:09 608-93-512/15/15 17:2810.0 2.0 1
Pentachloronitrobenzene ND ug/L 12/22/15 19:09 82-68-812/15/15 17:2820.0 1.0 1
Pentachlorophenol ND ug/L 12/22/15 19:09 87-86-512/15/15 17:2825.0 2.3 1
Phenacetin ND ug/L 12/22/15 19:09 62-44-212/15/15 17:2820.0 0.97 1
Phenanthrene ND ug/L 12/22/15 19:09 85-01-812/15/15 17:2810.0 0.22 1
Phenol ND ug/L 12/22/15 19:09 108-95-212/15/15 17:2810.0 1.7 1
p-Phenylenediamine ND ug/L 12/22/15 19:09 106-50-312/15/15 17:2810.0 0.96 1
Phorate ND ug/L 12/22/15 19:09 298-02-2 L312/15/15 17:2810.0 1.1 1
Pronamide ND ug/L 12/22/15 19:09 23950-58-512/15/15 17:2810.0 0.97 1
Pyrene ND ug/L 12/22/15 19:09 129-00-012/15/15 17:2810.0 0.19 1
Safrole ND ug/L 12/22/15 19:09 94-59-712/15/15 17:2810.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 12/22/15 19:09 95-94-312/15/15 17:2810.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 12/22/15 19:09 58-90-212/15/15 17:2810.0 2.3 1
Thionazin ND ug/L 12/22/15 19:09 297-97-212/15/15 17:2820.0 1.2 1
O-Toluidine ND ug/L 12/22/15 19:09 95-53-412/15/15 17:2810.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 12/22/15 19:09 95-95-412/15/15 17:2810.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 12/22/15 19:09 88-06-212/15/15 17:2810.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 12/22/15 19:09 99-35-4 L312/15/15 17:2810.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)81 %12/22/15 19:09 4165-60-012/15/15 17:2821-110 1
2-Fluorobiphenyl (S)83 %12/22/15 19:09 321-60-812/15/15 17:2827-110 1
Terphenyl-d14 (S)87 %12/22/15 19:09 1718-51-012/15/15 17:2831-107 1
Phenol-d6 (S)32 %12/22/15 19:09 13127-88-312/15/15 17:2810-110 1
2-Fluorophenol (S)43 %12/22/15 19:09 367-12-412/15/15 17:2812-110 1
2,4,6-Tribromophenol (S)111 %12/22/15 19:09 118-79-6 S312/15/15 17:2827-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/19/15 14:16 67-64-110010.0 1
Acetonitrile ND ug/L 12/19/15 14:16 75-05-855.0 2.2 1
Acrolein ND ug/L 12/19/15 14:16 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 12/19/15 14:16 107-13-12001.9 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW10 Lab ID:92279395001 Collected:12/08/15 11:40 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Allyl chloride ND ug/L 12/19/15 14:16 107-05-110.0 1.5 1
Benzene 1.6 ug/L 12/19/15 14:16 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/19/15 14:16 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/19/15 14:16 75-27-41.0 0.18 1
Bromoform ND ug/L 12/19/15 14:16 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/19/15 14:16 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/19/15 14:16 78-93-31000.96 1
Carbon disulfide ND ug/L 12/19/15 14:16 75-15-01001.2 1
Carbon tetrachloride ND ug/L 12/19/15 14:16 56-23-51.0 0.25 1
Chlorobenzene 1.5J ug/L 12/19/15 14:16 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/19/15 14:16 75-00-310.0 0.54 1
Chloroform ND ug/L 12/19/15 14:16 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/19/15 14:16 74-87-31.0 0.11 1
Chloroprene ND ug/L 12/19/15 14:16 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 12/19/15 14:16 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/19/15 14:16 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/19/15 14:16 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/19/15 14:16 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/19/15 14:16 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 12/19/15 14:16 541-73-15.0 0.24 1
1,4-Dichlorobenzene 0.98J ug/L 12/19/15 14:16 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/19/15 14:16 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 12/19/15 14:16 75-71-85.0 0.21 1
1,1-Dichloroethane 0.95J ug/L 12/19/15 14:16 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/19/15 14:16 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/19/15 14:16 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 3.9J ug/L 12/19/15 14:16 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/19/15 14:16 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/19/15 14:16 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 12/19/15 14:16 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 12/19/15 14:16 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 12/19/15 14:16 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 12/19/15 14:16 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/19/15 14:16 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/19/15 14:16 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 12/19/15 14:16 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 12/19/15 14:16 87-68-310.0 0.71 1
2-Hexanone ND ug/L 12/19/15 14:16 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/19/15 14:16 74-88-410.0 0.32 1
Isobutanol ND ug/L 12/19/15 14:16 78-83-110035.0 1
Methacrylonitrile ND ug/L 12/19/15 14:16 126-98-71000.93 1
Methylene Chloride ND ug/L 12/19/15 14:16 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 12/19/15 14:16 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/19/15 14:16 108-10-11000.33 1
Naphthalene ND ug/L 12/19/15 14:16 91-20-310.0 0.24 1
Propionitrile ND ug/L 12/19/15 14:16 107-12-01503.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW10 Lab ID:92279395001 Collected:12/08/15 11:40 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Styrene ND ug/L 12/19/15 14:16 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/19/15 14:16 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/19/15 14:16 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/19/15 14:16 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/19/15 14:16 109-99-910.0 3.1 1
Toluene ND ug/L 12/19/15 14:16 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 12/19/15 14:16 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 12/19/15 14:16 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/19/15 14:16 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/19/15 14:16 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/19/15 14:16 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/19/15 14:16 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/19/15 14:16 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/19/15 14:16 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/19/15 14:16 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)106 %12/19/15 14:16 460-00-470-130 1
1,2-Dichloroethane-d4 (S)92 %12/19/15 14:16 17060-07-070-130 1
Toluene-d8 (S)107 %12/19/15 14:16 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 98400 ug/L 12/14/15 15:17500010001
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 182000 ug/L 12/11/15 10:4125000250001
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/11/15 15:00 18496-25-810001001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 10200J ug/L 12/11/15 14:06 14808-79-825000010001
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 26500 ug/L 12/17/15 16:56 16887-00-610005001
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 12/16/15 11:11 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW11 Lab ID:92279395002 Collected:12/08/15 12:05 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 12/14/15 21:19 309-00-212/11/15 16:000.050 0.050 1
alpha-BHC ND ug/L 12/14/15 21:19 319-84-612/11/15 16:000.050 0.050 1
beta-BHC 0.16 ug/L 12/14/15 21:19 319-85-712/11/15 16:000.050 0.050 1
delta-BHC ND ug/L 12/14/15 21:19 319-86-812/11/15 16:000.050 0.050 1
gamma-BHC (Lindane)ND ug/L 12/14/15 21:19 58-89-912/11/15 16:000.050 0.050 1
Chlordane (Technical)ND ug/L 12/14/15 21:19 57-74-912/11/15 16:000.50 0.20 1
4,4'-DDD ND ug/L 12/14/15 21:19 72-54-812/11/15 16:000.10 0.050 1
4,4'-DDE ND ug/L 12/14/15 21:19 72-55-912/11/15 16:000.10 0.050 1
4,4'-DDT ND ug/L 12/14/15 21:19 50-29-312/11/15 16:000.10 0.050 1
Dieldrin ND ug/L 12/14/15 21:19 60-57-112/11/15 16:000.075 0.050 1
Endosulfan I ND ug/L 12/14/15 21:19 959-98-812/11/15 16:000.10 0.050 1
Endosulfan II ND ug/L 12/14/15 21:19 33213-65-912/11/15 16:000.10 0.050 1
Endosulfan sulfate ND ug/L 12/14/15 21:19 1031-07-812/11/15 16:000.10 0.050 1
Endrin ND ug/L 12/14/15 21:19 72-20-812/11/15 16:000.10 0.050 1
Endrin aldehyde ND ug/L 12/14/15 21:19 7421-93-412/11/15 16:000.10 0.050 1
Heptachlor ND ug/L 12/14/15 21:19 76-44-812/11/15 16:000.050 0.050 1
Heptachlor epoxide ND ug/L 12/14/15 21:19 1024-57-312/11/15 16:000.075 0.050 1
Methoxychlor ND ug/L 12/14/15 21:19 72-43-512/11/15 16:001.0 0.15 1
Toxaphene ND ug/L 12/14/15 21:19 8001-35-212/11/15 16:001.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)52 %12/14/15 21:19 877-09-812/11/15 16:0020-130 1
Decachlorobiphenyl (S)42 %12/14/15 21:19 2051-24-312/11/15 16:0020-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 12/14/15 18:46 12674-11-212/11/15 16:000.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 12/14/15 18:46 11104-28-212/11/15 16:000.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 12/14/15 18:46 11141-16-512/11/15 16:000.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 12/14/15 18:46 53469-21-912/11/15 16:000.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 12/14/15 18:46 12672-29-612/11/15 16:000.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 12/14/15 18:46 11097-69-112/11/15 16:000.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 12/14/15 18:46 11096-82-512/11/15 16:000.50 0.50 1
Surrogates
Decachlorobiphenyl (S)40 %12/14/15 18:46 2051-24-312/11/15 16:0010-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 12/18/15 12:17 94-75-712/15/15 20:150.94 0.22 1
Dinoseb ND ug/L 12/18/15 12:17 88-85-712/15/15 20:150.19 0.057 1
2,4,5-T ND ug/L 12/18/15 12:17 93-76-512/15/15 20:150.19 0.042 1
2,4,5-TP (Silvex)ND ug/L 12/18/15 12:17 93-72-112/15/15 20:150.19 0.049 1
Surrogates
2,4-DCAA (S)109 %12/18/15 12:17 19719-28-912/15/15 20:1536-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/17/15 03:25 7440-36-012/12/15 00:006.0 3.8 1
Arsenic ND ug/L 12/17/15 03:25 7440-38-212/12/15 00:0010.0 2.5 1
Barium 140 ug/L 12/17/15 03:25 7440-39-312/12/15 00:001002.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW11 Lab ID:92279395002 Collected:12/08/15 12:05 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Beryllium ND ug/L 12/17/15 03:25 7440-41-712/12/15 00:001.0 0.50 1
Cadmium ND ug/L 12/17/15 03:25 7440-43-912/12/15 00:001.0 0.50 1
Chromium ND ug/L 12/17/15 03:25 7440-47-312/12/15 00:0010.0 2.5 1
Cobalt 61.0 ug/L 12/17/15 03:25 7440-48-412/12/15 00:0010.0 2.5 1
Copper 6.4J ug/L 12/17/15 03:25 7440-50-812/12/15 00:0010.0 2.5 1
Iron 74200 ug/L 12/17/15 03:25 7439-89-612/12/15 00:0030025.0 1
Lead 6.3J ug/L 12/17/15 03:25 7439-92-112/12/15 00:0010.0 2.5 1
Manganese 18100 ug/L 12/17/15 16:54 7439-96-512/12/15 00:0025012.5 5
Nickel 3.4J ug/L 12/17/15 03:25 7440-02-012/12/15 00:0050.0 2.5 1
Selenium ND ug/L 12/17/15 03:25 7782-49-212/12/15 00:0010.0 5.0 1
Silver ND ug/L 12/17/15 03:25 7440-22-412/12/15 00:0010.0 2.5 1
Thallium ND ug/L 12/17/15 03:25 7440-28-012/12/15 00:005.5 5.0 1
Tin ND ug/L 12/17/15 03:25 7440-31-512/12/15 00:001002.5 1
Vanadium 23.5J ug/L 12/17/15 03:25 7440-62-212/12/15 00:0025.0 2.5 1
Zinc 20.0 ug/L 12/17/15 03:25 7440-66-612/12/15 00:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/17/15 18:39 7439-97-612/17/15 14:050.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 12/22/15 19:37 83-32-912/15/15 17:2810.0 0.25 1
Acenaphthylene ND ug/L 12/22/15 19:37 208-96-812/15/15 17:2810.0 0.21 1
Acetophenone ND ug/L 12/22/15 19:37 98-86-212/15/15 17:2810.0 2.0 1
2-Acetylaminofluorene ND ug/L 12/22/15 19:37 53-96-312/15/15 17:2820.0 0.84 1
4-Aminobiphenyl ND ug/L 12/22/15 19:37 92-67-112/15/15 17:2820.0 0.92 1
Anthracene ND ug/L 12/22/15 19:37 120-12-712/15/15 17:2810.0 0.14 1
Benzo(a)anthracene ND ug/L 12/22/15 19:37 56-55-312/15/15 17:2810.0 0.33 1
Benzo(a)pyrene ND ug/L 12/22/15 19:37 50-32-812/15/15 17:2810.0 0.30 1
Benzo(b)fluoranthene ND ug/L 12/22/15 19:37 205-99-212/15/15 17:2810.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 12/22/15 19:37 191-24-212/15/15 17:2810.0 0.38 1
Benzo(k)fluoranthene ND ug/L 12/22/15 19:37 207-08-912/15/15 17:2810.0 0.43 1
Benzyl alcohol ND ug/L 12/22/15 19:37 100-51-612/15/15 17:2820.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 12/22/15 19:37 101-55-312/15/15 17:2810.0 1.3 1
Butylbenzylphthalate ND ug/L 12/22/15 19:37 85-68-712/15/15 17:2810.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 12/22/15 19:37 59-50-712/15/15 17:2820.0 4.2 1
4-Chloroaniline ND ug/L 12/22/15 19:37 106-47-812/15/15 17:2820.0 3.4 1
Chlorobenzilate ND ug/L 12/22/15 19:37 510-15-612/15/15 17:2810.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 12/22/15 19:37 111-91-112/15/15 17:2810.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 12/22/15 19:37 111-44-412/15/15 17:2810.0 1.5 1
bis(2-Chloroisopropyl) ether ND ug/L 12/22/15 19:37 108-60-112/15/15 17:2810.0 1.6 1
2-Chloronaphthalene ND ug/L 12/22/15 19:37 91-58-712/15/15 17:2810.0 2.2 1
2-Chlorophenol ND ug/L 12/22/15 19:37 95-57-812/15/15 17:2810.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 12/22/15 19:37 7005-72-312/15/15 17:2810.0 2.1 1
Chrysene ND ug/L 12/22/15 19:37 218-01-912/15/15 17:2810.0 0.21 1
Diallate ND ug/L 12/22/15 19:37 2303-16-412/15/15 17:2810.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 12/22/15 19:37 53-70-312/15/15 17:2810.0 0.55 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW11 Lab ID:92279395002 Collected:12/08/15 12:05 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Dibenzofuran ND ug/L 12/22/15 19:37 132-64-912/15/15 17:2810.0 1.8 1
3,3'-Dichlorobenzidine ND ug/L 12/22/15 19:37 91-94-112/15/15 17:2820.0 1.4 1
2,4-Dichlorophenol ND ug/L 12/22/15 19:37 120-83-212/15/15 17:2810.0 1.7 1
2,6-Dichlorophenol ND ug/L 12/22/15 19:37 87-65-012/15/15 17:2810.0 1.8 1
Diethylphthalate ND ug/L 12/22/15 19:37 84-66-212/15/15 17:2860001.3 1
Dimethoate ND ug/L 12/22/15 19:37 60-51-512/15/15 17:2820.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 12/22/15 19:37 60-11-712/15/15 17:2810.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 12/22/15 19:37 57-97-612/15/15 17:2810.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 12/22/15 19:37 119-93-712/15/15 17:2810.0 2.1 1
2,4-Dimethylphenol ND ug/L 12/22/15 19:37 105-67-912/15/15 17:2810.0 2.2 1
Dimethylphthalate ND ug/L 12/22/15 19:37 131-11-312/15/15 17:2810.0 1.5 1
Di-n-butylphthalate ND ug/L 12/22/15 19:37 84-74-212/15/15 17:2810.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 12/22/15 19:37 534-52-112/15/15 17:2850.0 1.7 1
1,3-Dinitrobenzene ND ug/L 12/22/15 19:37 99-65-012/15/15 17:2820.0 1.5 1
2,4-Dinitrophenol ND ug/L 12/22/15 19:37 51-28-512/15/15 17:2850.0 6.5 1
2,4-Dinitrotoluene ND ug/L 12/22/15 19:37 121-14-212/15/15 17:2810.0 1.2 1
2,6-Dinitrotoluene ND ug/L 12/22/15 19:37 606-20-212/15/15 17:2810.0 1.7 1
Di-n-octylphthalate ND ug/L 12/22/15 19:37 117-84-012/15/15 17:2810.0 0.86 1
Diphenylamine ND ug/L 12/22/15 19:37 122-39-412/15/15 17:2810.0 1.3 1
Disulfoton ND ug/L 12/22/15 19:37 298-04-412/15/15 17:2810.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 12/22/15 19:37 117-81-712/15/15 17:2815.0 0.85 1
Ethyl methanesulfonate ND ug/L 12/22/15 19:37 62-50-012/15/15 17:2820.0 1.8 1
Famphur ND ug/L 12/22/15 19:37 52-85-712/15/15 17:2820.0 1.7 1
Fluoranthene ND ug/L 12/22/15 19:37 206-44-0 L312/15/15 17:2810.0 0.21 1
Fluorene ND ug/L 12/22/15 19:37 86-73-712/15/15 17:2810.0 0.21 1
Hexachlorobenzene ND ug/L 12/22/15 19:37 118-74-112/15/15 17:2810.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 12/22/15 19:37 77-47-412/15/15 17:2810.0 1.8 1
Hexachloroethane ND ug/L 12/22/15 19:37 67-72-112/15/15 17:2810.0 1.5 1
Hexachloropropene ND ug/L 12/22/15 19:37 1888-71-712/15/15 17:2810.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 12/22/15 19:37 193-39-512/15/15 17:2810.0 0.29 1
Isodrin ND ug/L 12/22/15 19:37 465-73-6 L312/15/15 17:2820.0 2.0 1
Isophorone ND ug/L 12/22/15 19:37 78-59-112/15/15 17:2810.0 1.8 1
Isosafrole ND ug/L 12/22/15 19:37 120-58-112/15/15 17:2810.0 1.8 1
Kepone ND ug/L 12/22/15 19:37 143-50-012/15/15 17:2820.0 3.1 1
Methapyrilene ND ug/L 12/22/15 19:37 91-80-5 L212/15/15 17:281002.7 1
3-Methylcholanthrene ND ug/L 12/22/15 19:37 56-49-512/15/15 17:2810.0 0.82 1
Methyl methanesulfonate ND ug/L 12/22/15 19:37 66-27-312/15/15 17:2810.0 1.3 1
2-Methylnaphthalene ND ug/L 12/22/15 19:37 91-57-612/15/15 17:2810.0 0.28 1
Methyl parathion ND ug/L 12/22/15 19:37 298-00-012/15/15 17:2810.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 12/22/15 19:37 95-48-712/15/15 17:2810.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 12/22/15 19:3712/15/15 17:2810.0 1.7 1
1-Naphthalenamine ND ug/L 12/22/15 19:37 134-32-712/15/15 17:2810.0 0.96 1
2-Naphthalenamine ND ug/L 12/22/15 19:37 91-59-812/15/15 17:2810.0 0.98 1
1,4-Naphthoquinone ND ug/L 12/22/15 19:37 130-15-412/15/15 17:2810.0 1.8 1
2-Nitroaniline ND ug/L 12/22/15 19:37 88-74-412/15/15 17:2850.0 2.8 1
3-Nitroaniline ND ug/L 12/22/15 19:37 99-09-212/15/15 17:2850.0 2.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
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Page 17 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW11 Lab ID:92279395002 Collected:12/08/15 12:05 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
4-Nitroaniline ND ug/L 12/22/15 19:37 100-01-612/15/15 17:2820.0 2.5 1
Nitrobenzene ND ug/L 12/22/15 19:37 98-95-312/15/15 17:2810.0 1.7 1
2-Nitrophenol ND ug/L 12/22/15 19:37 88-75-512/15/15 17:2810.0 1.7 1
4-Nitrophenol ND ug/L 12/22/15 19:37 100-02-712/15/15 17:2850.0 5.8 1
5-Nitro-o-toluidine ND ug/L 12/22/15 19:37 99-55-812/15/15 17:2810.0 1.2 1
N-Nitrosodiethylamine ND ug/L 12/22/15 19:37 55-18-512/15/15 17:2820.0 1.8 1
N-Nitrosodimethylamine ND ug/L 12/22/15 19:37 62-75-912/15/15 17:2810.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 12/22/15 19:37 924-16-312/15/15 17:2810.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 12/22/15 19:37 621-64-712/15/15 17:2810.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 12/22/15 19:37 86-30-612/15/15 17:2810.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 12/22/15 19:37 10595-95-612/15/15 17:2810.0 1.8 1
N-Nitrosopiperidine ND ug/L 12/22/15 19:37 100-75-412/15/15 17:2820.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 12/22/15 19:37 930-55-212/15/15 17:2810.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 12/22/15 19:37 126-68-112/15/15 17:2810.0 1.8 1
Parathion (Ethyl parathion)ND ug/L 12/22/15 19:37 56-38-212/15/15 17:2810.0 1.1 1
Pentachlorobenzene ND ug/L 12/22/15 19:37 608-93-512/15/15 17:2810.0 2.0 1
Pentachloronitrobenzene ND ug/L 12/22/15 19:37 82-68-812/15/15 17:2820.0 1.0 1
Pentachlorophenol ND ug/L 12/22/15 19:37 87-86-512/15/15 17:2825.0 2.3 1
Phenacetin ND ug/L 12/22/15 19:37 62-44-212/15/15 17:2820.0 0.97 1
Phenanthrene ND ug/L 12/22/15 19:37 85-01-812/15/15 17:2810.0 0.22 1
Phenol ND ug/L 12/22/15 19:37 108-95-212/15/15 17:2810.0 1.7 1
p-Phenylenediamine ND ug/L 12/22/15 19:37 106-50-312/15/15 17:2810.0 0.96 1
Phorate ND ug/L 12/22/15 19:37 298-02-2 L312/15/15 17:2810.0 1.1 1
Pronamide ND ug/L 12/22/15 19:37 23950-58-512/15/15 17:2810.0 0.97 1
Pyrene ND ug/L 12/22/15 19:37 129-00-012/15/15 17:2810.0 0.19 1
Safrole ND ug/L 12/22/15 19:37 94-59-712/15/15 17:2810.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 12/22/15 19:37 95-94-312/15/15 17:2810.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 12/22/15 19:37 58-90-212/15/15 17:2810.0 2.3 1
Thionazin ND ug/L 12/22/15 19:37 297-97-212/15/15 17:2820.0 1.2 1
O-Toluidine ND ug/L 12/22/15 19:37 95-53-412/15/15 17:2810.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 12/22/15 19:37 95-95-412/15/15 17:2810.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 12/22/15 19:37 88-06-212/15/15 17:2810.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 12/22/15 19:37 99-35-4 L312/15/15 17:2810.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)86 %12/22/15 19:37 4165-60-012/15/15 17:2821-110 1
2-Fluorobiphenyl (S)77 %12/22/15 19:37 321-60-812/15/15 17:2827-110 1
Terphenyl-d14 (S)94 %12/22/15 19:37 1718-51-012/15/15 17:2831-107 1
Phenol-d6 (S)24 %12/22/15 19:37 13127-88-312/15/15 17:2810-110 1
2-Fluorophenol (S)35 %12/22/15 19:37 367-12-412/15/15 17:2812-110 1
2,4,6-Tribromophenol (S)100 %12/22/15 19:37 118-79-612/15/15 17:2827-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/19/15 14:33 67-64-110010.0 1
Acetonitrile ND ug/L 12/19/15 14:33 75-05-855.0 2.2 1
Acrolein ND ug/L 12/19/15 14:33 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 12/19/15 14:33 107-13-12001.9 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW11 Lab ID:92279395002 Collected:12/08/15 12:05 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Allyl chloride ND ug/L 12/19/15 14:33 107-05-110.0 1.5 1
Benzene 2.2 ug/L 12/19/15 14:33 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/19/15 14:33 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/19/15 14:33 75-27-41.0 0.18 1
Bromoform ND ug/L 12/19/15 14:33 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/19/15 14:33 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/19/15 14:33 78-93-31000.96 1
Carbon disulfide ND ug/L 12/19/15 14:33 75-15-01001.2 1
Carbon tetrachloride ND ug/L 12/19/15 14:33 56-23-51.0 0.25 1
Chlorobenzene 0.61J ug/L 12/19/15 14:33 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/19/15 14:33 75-00-310.0 0.54 1
Chloroform ND ug/L 12/19/15 14:33 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/19/15 14:33 74-87-31.0 0.11 1
Chloroprene ND ug/L 12/19/15 14:33 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 12/19/15 14:33 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/19/15 14:33 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/19/15 14:33 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/19/15 14:33 74-95-310.0 0.21 1
1,2-Dichlorobenzene 0.39J ug/L 12/19/15 14:33 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 12/19/15 14:33 541-73-15.0 0.24 1
1,4-Dichlorobenzene 12.6 ug/L 12/19/15 14:33 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/19/15 14:33 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 12/19/15 14:33 75-71-85.0 0.21 1
1,1-Dichloroethane 3.2J ug/L 12/19/15 14:33 75-34-35.0 0.32 1
1,2-Dichloroethane 0.65J ug/L 12/19/15 14:33 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/19/15 14:33 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 6.9 ug/L 12/19/15 14:33 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/19/15 14:33 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/19/15 14:33 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 12/19/15 14:33 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 12/19/15 14:33 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 12/19/15 14:33 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 12/19/15 14:33 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/19/15 14:33 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/19/15 14:33 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 12/19/15 14:33 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 12/19/15 14:33 87-68-310.0 0.71 1
2-Hexanone ND ug/L 12/19/15 14:33 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/19/15 14:33 74-88-410.0 0.32 1
Isobutanol ND ug/L 12/19/15 14:33 78-83-110035.0 1
Methacrylonitrile ND ug/L 12/19/15 14:33 126-98-71000.93 1
Methylene Chloride ND ug/L 12/19/15 14:33 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 12/19/15 14:33 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/19/15 14:33 108-10-11000.33 1
Naphthalene ND ug/L 12/19/15 14:33 91-20-310.0 0.24 1
Propionitrile ND ug/L 12/19/15 14:33 107-12-01503.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW11 Lab ID:92279395002 Collected:12/08/15 12:05 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Styrene ND ug/L 12/19/15 14:33 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/19/15 14:33 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/19/15 14:33 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/19/15 14:33 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/19/15 14:33 109-99-910.0 3.1 1
Toluene ND ug/L 12/19/15 14:33 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 12/19/15 14:33 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 12/19/15 14:33 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/19/15 14:33 79-00-51.0 0.29 1
Trichloroethene 0.71J ug/L 12/19/15 14:33 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/19/15 14:33 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/19/15 14:33 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/19/15 14:33 108-05-450.0 0.35 1
Vinyl chloride 0.72J ug/L 12/19/15 14:33 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/19/15 14:33 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)109 %12/19/15 14:33 460-00-470-130 1
1,2-Dichloroethane-d4 (S)98 %12/19/15 14:33 17060-07-070-130 1
Toluene-d8 (S)107 %12/19/15 14:33 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 202000 ug/L 12/14/15 15:30500010001
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 280000 ug/L 12/11/15 10:4125000250001
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/11/15 15:00 18496-25-810001001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 1530J ug/L 12/11/15 14:06 14808-79-825000010001
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 30800 ug/L 12/17/15 16:57 16887-00-610005001
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 12/16/15 11:12 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW12 Lab ID:92279395003 Collected:12/08/15 12:51 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 12/14/15 21:37 309-00-212/11/15 16:000.050 0.050 1
alpha-BHC ND ug/L 12/14/15 21:37 319-84-612/11/15 16:000.050 0.050 1
beta-BHC ND ug/L 12/14/15 21:37 319-85-712/11/15 16:000.050 0.050 1
delta-BHC ND ug/L 12/14/15 21:37 319-86-812/11/15 16:000.050 0.050 1
gamma-BHC (Lindane)ND ug/L 12/14/15 21:37 58-89-912/11/15 16:000.050 0.050 1
Chlordane (Technical)ND ug/L 12/14/15 21:37 57-74-912/11/15 16:000.50 0.20 1
4,4'-DDD ND ug/L 12/14/15 21:37 72-54-812/11/15 16:000.10 0.050 1
4,4'-DDE ND ug/L 12/14/15 21:37 72-55-912/11/15 16:000.10 0.050 1
4,4'-DDT ND ug/L 12/14/15 21:37 50-29-312/11/15 16:000.10 0.050 1
Dieldrin ND ug/L 12/14/15 21:37 60-57-112/11/15 16:000.075 0.050 1
Endosulfan I ND ug/L 12/14/15 21:37 959-98-812/11/15 16:000.10 0.050 1
Endosulfan II ND ug/L 12/14/15 21:37 33213-65-912/11/15 16:000.10 0.050 1
Endosulfan sulfate ND ug/L 12/14/15 21:37 1031-07-812/11/15 16:000.10 0.050 1
Endrin ND ug/L 12/14/15 21:37 72-20-812/11/15 16:000.10 0.050 1
Endrin aldehyde ND ug/L 12/14/15 21:37 7421-93-412/11/15 16:000.10 0.050 1
Heptachlor ND ug/L 12/14/15 21:37 76-44-812/11/15 16:000.050 0.050 1
Heptachlor epoxide ND ug/L 12/14/15 21:37 1024-57-312/11/15 16:000.075 0.050 1
Methoxychlor ND ug/L 12/14/15 21:37 72-43-512/11/15 16:001.0 0.15 1
Toxaphene ND ug/L 12/14/15 21:37 8001-35-212/11/15 16:001.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)61 %12/14/15 21:37 877-09-812/11/15 16:0020-130 1
Decachlorobiphenyl (S)55 %12/14/15 21:37 2051-24-312/11/15 16:0020-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 12/14/15 19:06 12674-11-212/11/15 16:000.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 12/14/15 19:06 11104-28-212/11/15 16:000.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 12/14/15 19:06 11141-16-512/11/15 16:000.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 12/14/15 19:06 53469-21-912/11/15 16:000.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 12/14/15 19:06 12672-29-612/11/15 16:000.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 12/14/15 19:06 11097-69-112/11/15 16:000.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 12/14/15 19:06 11096-82-512/11/15 16:000.50 0.50 1
Surrogates
Decachlorobiphenyl (S)59 %12/14/15 19:06 2051-24-312/11/15 16:0010-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 12/18/15 12:48 94-75-712/15/15 20:150.94 0.22 1
Dinoseb ND ug/L 12/18/15 12:48 88-85-712/15/15 20:150.19 0.057 1
2,4,5-T ND ug/L 12/18/15 12:48 93-76-512/15/15 20:150.19 0.042 1
2,4,5-TP (Silvex)ND ug/L 12/18/15 12:48 93-72-112/15/15 20:150.19 0.049 1
Surrogates
2,4-DCAA (S)99 %12/18/15 12:48 19719-28-912/15/15 20:1536-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony 6.3 ug/L 12/17/15 03:28 7440-36-012/12/15 00:006.0 3.8 1
Arsenic ND ug/L 12/17/15 03:28 7440-38-212/12/15 00:0010.0 2.5 1
Barium 132 ug/L 12/17/15 03:28 7440-39-312/12/15 00:001002.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW12 Lab ID:92279395003 Collected:12/08/15 12:51 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Beryllium ND ug/L 12/17/15 03:28 7440-41-712/12/15 00:001.0 0.50 1
Cadmium ND ug/L 12/17/15 03:28 7440-43-912/12/15 00:001.0 0.50 1
Chromium 13.8 ug/L 12/17/15 03:28 7440-47-312/12/15 00:0010.0 2.5 1
Cobalt 84.8 ug/L 12/17/15 03:28 7440-48-412/12/15 00:0010.0 2.5 1
Copper 9.7J ug/L 12/17/15 03:28 7440-50-812/12/15 00:0010.0 2.5 1
Iron 50200 ug/L 12/17/15 03:28 7439-89-612/12/15 00:0030025.0 1
Lead 9.8J ug/L 12/17/15 03:28 7439-92-112/12/15 00:0010.0 2.5 1
Manganese 10800 ug/L 12/17/15 16:57 7439-96-512/12/15 00:0025012.5 5
Nickel 17.7J ug/L 12/17/15 03:28 7440-02-012/12/15 00:0050.0 2.5 1
Selenium ND ug/L 12/17/15 03:28 7782-49-212/12/15 00:0010.0 5.0 1
Silver ND ug/L 12/17/15 03:28 7440-22-412/12/15 00:0010.0 2.5 1
Thallium ND ug/L 12/17/15 03:28 7440-28-012/12/15 00:005.5 5.0 1
Tin ND ug/L 12/17/15 03:28 7440-31-512/12/15 00:001002.5 1
Vanadium 36.9 ug/L 12/17/15 03:28 7440-62-212/12/15 00:0025.0 2.5 1
Zinc 65.1 ug/L 12/17/15 03:28 7440-66-612/12/15 00:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/17/15 18:41 7439-97-612/17/15 14:050.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 12/22/15 20:04 83-32-912/15/15 17:2810.0 0.25 1
Acenaphthylene ND ug/L 12/22/15 20:04 208-96-812/15/15 17:2810.0 0.21 1
Acetophenone ND ug/L 12/22/15 20:04 98-86-212/15/15 17:2810.0 2.0 1
2-Acetylaminofluorene ND ug/L 12/22/15 20:04 53-96-312/15/15 17:2820.0 0.84 1
4-Aminobiphenyl ND ug/L 12/22/15 20:04 92-67-112/15/15 17:2820.0 0.92 1
Anthracene ND ug/L 12/22/15 20:04 120-12-712/15/15 17:2810.0 0.14 1
Benzo(a)anthracene ND ug/L 12/22/15 20:04 56-55-312/15/15 17:2810.0 0.33 1
Benzo(a)pyrene ND ug/L 12/22/15 20:04 50-32-812/15/15 17:2810.0 0.30 1
Benzo(b)fluoranthene ND ug/L 12/22/15 20:04 205-99-212/15/15 17:2810.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 12/22/15 20:04 191-24-212/15/15 17:2810.0 0.38 1
Benzo(k)fluoranthene ND ug/L 12/22/15 20:04 207-08-912/15/15 17:2810.0 0.43 1
Benzyl alcohol ND ug/L 12/22/15 20:04 100-51-612/15/15 17:2820.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 12/22/15 20:04 101-55-312/15/15 17:2810.0 1.3 1
Butylbenzylphthalate ND ug/L 12/22/15 20:04 85-68-712/15/15 17:2810.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 12/22/15 20:04 59-50-712/15/15 17:2820.0 4.2 1
4-Chloroaniline ND ug/L 12/22/15 20:04 106-47-812/15/15 17:2820.0 3.4 1
Chlorobenzilate ND ug/L 12/22/15 20:04 510-15-612/15/15 17:2810.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 12/22/15 20:04 111-91-112/15/15 17:2810.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 12/22/15 20:04 111-44-412/15/15 17:2810.0 1.5 1
bis(2-Chloroisopropyl) ether ND ug/L 12/22/15 20:04 108-60-112/15/15 17:2810.0 1.6 1
2-Chloronaphthalene ND ug/L 12/22/15 20:04 91-58-712/15/15 17:2810.0 2.2 1
2-Chlorophenol ND ug/L 12/22/15 20:04 95-57-812/15/15 17:2810.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 12/22/15 20:04 7005-72-312/15/15 17:2810.0 2.1 1
Chrysene ND ug/L 12/22/15 20:04 218-01-912/15/15 17:2810.0 0.21 1
Diallate ND ug/L 12/22/15 20:04 2303-16-412/15/15 17:2810.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 12/22/15 20:04 53-70-312/15/15 17:2810.0 0.55 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW12 Lab ID:92279395003 Collected:12/08/15 12:51 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Dibenzofuran ND ug/L 12/22/15 20:04 132-64-912/15/15 17:2810.0 1.8 1
3,3'-Dichlorobenzidine ND ug/L 12/22/15 20:04 91-94-112/15/15 17:2820.0 1.4 1
2,4-Dichlorophenol ND ug/L 12/22/15 20:04 120-83-212/15/15 17:2810.0 1.7 1
2,6-Dichlorophenol ND ug/L 12/22/15 20:04 87-65-012/15/15 17:2810.0 1.8 1
Diethylphthalate ND ug/L 12/22/15 20:04 84-66-212/15/15 17:2860001.3 1
Dimethoate ND ug/L 12/22/15 20:04 60-51-512/15/15 17:2820.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 12/22/15 20:04 60-11-712/15/15 17:2810.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 12/22/15 20:04 57-97-612/15/15 17:2810.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 12/22/15 20:04 119-93-712/15/15 17:2810.0 2.1 1
2,4-Dimethylphenol ND ug/L 12/22/15 20:04 105-67-912/15/15 17:2810.0 2.2 1
Dimethylphthalate ND ug/L 12/22/15 20:04 131-11-312/15/15 17:2810.0 1.5 1
Di-n-butylphthalate ND ug/L 12/22/15 20:04 84-74-212/15/15 17:2810.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 12/22/15 20:04 534-52-112/15/15 17:2850.0 1.7 1
1,3-Dinitrobenzene ND ug/L 12/22/15 20:04 99-65-012/15/15 17:2820.0 1.5 1
2,4-Dinitrophenol ND ug/L 12/22/15 20:04 51-28-512/15/15 17:2850.0 6.5 1
2,4-Dinitrotoluene ND ug/L 12/22/15 20:04 121-14-212/15/15 17:2810.0 1.2 1
2,6-Dinitrotoluene ND ug/L 12/22/15 20:04 606-20-212/15/15 17:2810.0 1.7 1
Di-n-octylphthalate ND ug/L 12/22/15 20:04 117-84-012/15/15 17:2810.0 0.86 1
Diphenylamine ND ug/L 12/22/15 20:04 122-39-412/15/15 17:2810.0 1.3 1
Disulfoton ND ug/L 12/22/15 20:04 298-04-412/15/15 17:2810.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 12/22/15 20:04 117-81-712/15/15 17:2815.0 0.85 1
Ethyl methanesulfonate ND ug/L 12/22/15 20:04 62-50-012/15/15 17:2820.0 1.8 1
Famphur ND ug/L 12/22/15 20:04 52-85-712/15/15 17:2820.0 1.7 1
Fluoranthene ND ug/L 12/22/15 20:04 206-44-0 L312/15/15 17:2810.0 0.21 1
Fluorene ND ug/L 12/22/15 20:04 86-73-712/15/15 17:2810.0 0.21 1
Hexachlorobenzene ND ug/L 12/22/15 20:04 118-74-112/15/15 17:2810.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 12/22/15 20:04 77-47-412/15/15 17:2810.0 1.8 1
Hexachloroethane ND ug/L 12/22/15 20:04 67-72-112/15/15 17:2810.0 1.5 1
Hexachloropropene ND ug/L 12/22/15 20:04 1888-71-712/15/15 17:2810.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 12/22/15 20:04 193-39-512/15/15 17:2810.0 0.29 1
Isodrin ND ug/L 12/22/15 20:04 465-73-6 L312/15/15 17:2820.0 2.0 1
Isophorone ND ug/L 12/22/15 20:04 78-59-112/15/15 17:2810.0 1.8 1
Isosafrole ND ug/L 12/22/15 20:04 120-58-112/15/15 17:2810.0 1.8 1
Kepone ND ug/L 12/22/15 20:04 143-50-012/15/15 17:2820.0 3.1 1
Methapyrilene ND ug/L 12/22/15 20:04 91-80-5 L212/15/15 17:281002.7 1
3-Methylcholanthrene ND ug/L 12/22/15 20:04 56-49-512/15/15 17:2810.0 0.82 1
Methyl methanesulfonate ND ug/L 12/22/15 20:04 66-27-312/15/15 17:2810.0 1.3 1
2-Methylnaphthalene ND ug/L 12/22/15 20:04 91-57-612/15/15 17:2810.0 0.28 1
Methyl parathion ND ug/L 12/22/15 20:04 298-00-012/15/15 17:2810.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 12/22/15 20:04 95-48-712/15/15 17:2810.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 12/22/15 20:0412/15/15 17:2810.0 1.7 1
1-Naphthalenamine ND ug/L 12/22/15 20:04 134-32-712/15/15 17:2810.0 0.96 1
2-Naphthalenamine ND ug/L 12/22/15 20:04 91-59-812/15/15 17:2810.0 0.98 1
1,4-Naphthoquinone ND ug/L 12/22/15 20:04 130-15-412/15/15 17:2810.0 1.8 1
2-Nitroaniline ND ug/L 12/22/15 20:04 88-74-412/15/15 17:2850.0 2.8 1
3-Nitroaniline ND ug/L 12/22/15 20:04 99-09-212/15/15 17:2850.0 2.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW12 Lab ID:92279395003 Collected:12/08/15 12:51 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
4-Nitroaniline ND ug/L 12/22/15 20:04 100-01-612/15/15 17:2820.0 2.5 1
Nitrobenzene ND ug/L 12/22/15 20:04 98-95-312/15/15 17:2810.0 1.7 1
2-Nitrophenol ND ug/L 12/22/15 20:04 88-75-512/15/15 17:2810.0 1.7 1
4-Nitrophenol ND ug/L 12/22/15 20:04 100-02-712/15/15 17:2850.0 5.8 1
5-Nitro-o-toluidine ND ug/L 12/22/15 20:04 99-55-812/15/15 17:2810.0 1.2 1
N-Nitrosodiethylamine ND ug/L 12/22/15 20:04 55-18-512/15/15 17:2820.0 1.8 1
N-Nitrosodimethylamine ND ug/L 12/22/15 20:04 62-75-912/15/15 17:2810.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 12/22/15 20:04 924-16-312/15/15 17:2810.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 12/22/15 20:04 621-64-712/15/15 17:2810.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 12/22/15 20:04 86-30-612/15/15 17:2810.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 12/22/15 20:04 10595-95-612/15/15 17:2810.0 1.8 1
N-Nitrosopiperidine ND ug/L 12/22/15 20:04 100-75-412/15/15 17:2820.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 12/22/15 20:04 930-55-212/15/15 17:2810.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 12/22/15 20:04 126-68-112/15/15 17:2810.0 1.8 1
Parathion (Ethyl parathion)ND ug/L 12/22/15 20:04 56-38-212/15/15 17:2810.0 1.1 1
Pentachlorobenzene ND ug/L 12/22/15 20:04 608-93-512/15/15 17:2810.0 2.0 1
Pentachloronitrobenzene ND ug/L 12/22/15 20:04 82-68-812/15/15 17:2820.0 1.0 1
Pentachlorophenol ND ug/L 12/22/15 20:04 87-86-512/15/15 17:2825.0 2.3 1
Phenacetin ND ug/L 12/22/15 20:04 62-44-212/15/15 17:2820.0 0.97 1
Phenanthrene ND ug/L 12/22/15 20:04 85-01-812/15/15 17:2810.0 0.22 1
Phenol ND ug/L 12/22/15 20:04 108-95-212/15/15 17:2810.0 1.7 1
p-Phenylenediamine ND ug/L 12/22/15 20:04 106-50-312/15/15 17:2810.0 0.96 1
Phorate ND ug/L 12/22/15 20:04 298-02-2 L312/15/15 17:2810.0 1.1 1
Pronamide ND ug/L 12/22/15 20:04 23950-58-512/15/15 17:2810.0 0.97 1
Pyrene ND ug/L 12/22/15 20:04 129-00-012/15/15 17:2810.0 0.19 1
Safrole ND ug/L 12/22/15 20:04 94-59-712/15/15 17:2810.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 12/22/15 20:04 95-94-312/15/15 17:2810.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 12/22/15 20:04 58-90-212/15/15 17:2810.0 2.3 1
Thionazin ND ug/L 12/22/15 20:04 297-97-212/15/15 17:2820.0 1.2 1
O-Toluidine ND ug/L 12/22/15 20:04 95-53-412/15/15 17:2810.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 12/22/15 20:04 95-95-412/15/15 17:2810.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 12/22/15 20:04 88-06-212/15/15 17:2810.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 12/22/15 20:04 99-35-4 L312/15/15 17:2810.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)90 %12/22/15 20:04 4165-60-012/15/15 17:2821-110 1
2-Fluorobiphenyl (S)77 %12/22/15 20:04 321-60-812/15/15 17:2827-110 1
Terphenyl-d14 (S)94 %12/22/15 20:04 1718-51-012/15/15 17:2831-107 1
Phenol-d6 (S)24 %12/22/15 20:04 13127-88-312/15/15 17:2810-110 1
2-Fluorophenol (S)34 %12/22/15 20:04 367-12-412/15/15 17:2812-110 1
2,4,6-Tribromophenol (S)101 %12/22/15 20:04 118-79-612/15/15 17:2827-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/19/15 14:49 67-64-110010.0 1
Acetonitrile ND ug/L 12/19/15 14:49 75-05-855.0 2.2 1
Acrolein ND ug/L 12/19/15 14:49 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 12/19/15 14:49 107-13-12001.9 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW12 Lab ID:92279395003 Collected:12/08/15 12:51 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Allyl chloride ND ug/L 12/19/15 14:49 107-05-110.0 1.5 1
Benzene 2.3 ug/L 12/19/15 14:49 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/19/15 14:49 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/19/15 14:49 75-27-41.0 0.18 1
Bromoform ND ug/L 12/19/15 14:49 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/19/15 14:49 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/19/15 14:49 78-93-31000.96 1
Carbon disulfide ND ug/L 12/19/15 14:49 75-15-01001.2 1
Carbon tetrachloride ND ug/L 12/19/15 14:49 56-23-51.0 0.25 1
Chlorobenzene 0.73J ug/L 12/19/15 14:49 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/19/15 14:49 75-00-310.0 0.54 1
Chloroform ND ug/L 12/19/15 14:49 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/19/15 14:49 74-87-31.0 0.11 1
Chloroprene ND ug/L 12/19/15 14:49 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 12/19/15 14:49 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/19/15 14:49 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/19/15 14:49 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/19/15 14:49 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/19/15 14:49 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 12/19/15 14:49 541-73-15.0 0.24 1
1,4-Dichlorobenzene 4.8 ug/L 12/19/15 14:49 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/19/15 14:49 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 12/19/15 14:49 75-71-85.0 0.21 1
1,1-Dichloroethane 31.7 ug/L 12/19/15 14:49 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/19/15 14:49 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/19/15 14:49 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 9.9 ug/L 12/19/15 14:49 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/19/15 14:49 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/19/15 14:49 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 12/19/15 14:49 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 12/19/15 14:49 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 12/19/15 14:49 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 12/19/15 14:49 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/19/15 14:49 10061-02-61.0 0.26 1
Ethylbenzene 1.2 ug/L 12/19/15 14:49 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 12/19/15 14:49 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 12/19/15 14:49 87-68-310.0 0.71 1
2-Hexanone ND ug/L 12/19/15 14:49 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/19/15 14:49 74-88-410.0 0.32 1
Isobutanol ND ug/L 12/19/15 14:49 78-83-110035.0 1
Methacrylonitrile ND ug/L 12/19/15 14:49 126-98-71000.93 1
Methylene Chloride ND ug/L 12/19/15 14:49 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 12/19/15 14:49 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/19/15 14:49 108-10-11000.33 1
Naphthalene ND ug/L 12/19/15 14:49 91-20-310.0 0.24 1
Propionitrile ND ug/L 12/19/15 14:49 107-12-01503.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW12 Lab ID:92279395003 Collected:12/08/15 12:51 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Styrene ND ug/L 12/19/15 14:49 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/19/15 14:49 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/19/15 14:49 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/19/15 14:49 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/19/15 14:49 109-99-910.0 3.1 1
Toluene ND ug/L 12/19/15 14:49 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 12/19/15 14:49 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 12/19/15 14:49 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/19/15 14:49 79-00-51.0 0.29 1
Trichloroethene 1.4 ug/L 12/19/15 14:49 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/19/15 14:49 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/19/15 14:49 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/19/15 14:49 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/19/15 14:49 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/19/15 14:49 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)106 %12/19/15 14:49 460-00-470-130 1
1,2-Dichloroethane-d4 (S)103 %12/19/15 14:49 17060-07-070-130 1
Toluene-d8 (S)107 %12/19/15 14:49 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 88800 ug/L 12/14/15 16:04500010001
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 117000 ug/L 12/11/15 10:4225000250001
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/11/15 15:00 18496-25-810001001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 2020J ug/L 12/11/15 14:06 14808-79-825000010001
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 9400 ug/L 12/17/15 16:58 16887-00-610005001
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 12/16/15 11:13 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW13 Lab ID:92279395004 Collected:12/08/15 15:50 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 12/14/15 21:55 309-00-212/11/15 16:000.050 0.050 1
alpha-BHC ND ug/L 12/14/15 21:55 319-84-612/11/15 16:000.050 0.050 1
beta-BHC ND ug/L 12/14/15 21:55 319-85-712/11/15 16:000.050 0.050 1
delta-BHC ND ug/L 12/14/15 21:55 319-86-812/11/15 16:000.050 0.050 1
gamma-BHC (Lindane)ND ug/L 12/14/15 21:55 58-89-912/11/15 16:000.050 0.050 1
Chlordane (Technical)ND ug/L 12/14/15 21:55 57-74-912/11/15 16:000.50 0.20 1
4,4'-DDD ND ug/L 12/14/15 21:55 72-54-812/11/15 16:000.10 0.050 1
4,4'-DDE ND ug/L 12/14/15 21:55 72-55-912/11/15 16:000.10 0.050 1
4,4'-DDT ND ug/L 12/14/15 21:55 50-29-312/11/15 16:000.10 0.050 1
Dieldrin ND ug/L 12/14/15 21:55 60-57-112/11/15 16:000.075 0.050 1
Endosulfan I ND ug/L 12/14/15 21:55 959-98-812/11/15 16:000.10 0.050 1
Endosulfan II ND ug/L 12/14/15 21:55 33213-65-912/11/15 16:000.10 0.050 1
Endosulfan sulfate ND ug/L 12/14/15 21:55 1031-07-812/11/15 16:000.10 0.050 1
Endrin ND ug/L 12/14/15 21:55 72-20-812/11/15 16:000.10 0.050 1
Endrin aldehyde ND ug/L 12/14/15 21:55 7421-93-412/11/15 16:000.10 0.050 1
Heptachlor ND ug/L 12/14/15 21:55 76-44-812/11/15 16:000.050 0.050 1
Heptachlor epoxide ND ug/L 12/14/15 21:55 1024-57-312/11/15 16:000.075 0.050 1
Methoxychlor ND ug/L 12/14/15 21:55 72-43-512/11/15 16:001.0 0.15 1
Toxaphene ND ug/L 12/14/15 21:55 8001-35-212/11/15 16:001.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)19 %12/14/15 21:55 877-09-8 1g,S012/11/15 16:0020-130 1
Decachlorobiphenyl (S)36 %12/14/15 21:55 2051-24-312/11/15 16:0020-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 12/14/15 19:48 12674-11-212/11/15 16:000.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 12/14/15 19:48 11104-28-212/11/15 16:000.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 12/14/15 19:48 11141-16-512/11/15 16:000.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 12/14/15 19:48 53469-21-912/11/15 16:000.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 12/14/15 19:48 12672-29-612/11/15 16:000.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 12/14/15 19:48 11097-69-112/11/15 16:000.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 12/14/15 19:48 11096-82-512/11/15 16:000.50 0.50 1
Surrogates
Decachlorobiphenyl (S)43 %12/14/15 19:48 2051-24-312/11/15 16:0010-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 12/18/15 13:18 94-75-712/15/15 20:150.94 0.22 1
Dinoseb ND ug/L 12/18/15 13:18 88-85-712/15/15 20:150.19 0.057 1
2,4,5-T ND ug/L 12/18/15 13:18 93-76-512/15/15 20:150.19 0.042 1
2,4,5-TP (Silvex)ND ug/L 12/18/15 13:18 93-72-112/15/15 20:150.19 0.049 1
Surrogates
2,4-DCAA (S)91 %12/18/15 13:18 19719-28-912/15/15 20:1536-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/17/15 03:32 7440-36-012/12/15 00:006.0 3.8 1
Arsenic ND ug/L 12/17/15 03:32 7440-38-212/12/15 00:0010.0 2.5 1
Barium 82.6J ug/L 12/17/15 03:32 7440-39-312/12/15 00:001002.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW13 Lab ID:92279395004 Collected:12/08/15 15:50 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Beryllium ND ug/L 12/17/15 03:32 7440-41-712/12/15 00:001.0 0.50 1
Cadmium ND ug/L 12/17/15 03:32 7440-43-912/12/15 00:001.0 0.50 1
Chromium ND ug/L 12/17/15 03:32 7440-47-312/12/15 00:0010.0 2.5 1
Cobalt 49.7 ug/L 12/17/15 03:32 7440-48-412/12/15 00:0010.0 2.5 1
Copper ND ug/L 12/17/15 03:32 7440-50-812/12/15 00:0010.0 2.5 1
Iron 1460 ug/L 12/17/15 03:32 7439-89-612/12/15 00:0030025.0 1
Lead ND ug/L 12/17/15 03:32 7439-92-112/12/15 00:0010.0 2.5 1
Manganese 1500 ug/L 12/17/15 03:32 7439-96-512/12/15 00:0050.0 2.5 1
Nickel 4.2J ug/L 12/17/15 03:32 7440-02-012/12/15 00:0050.0 2.5 1
Selenium ND ug/L 12/17/15 03:32 7782-49-212/12/15 00:0010.0 5.0 1
Silver ND ug/L 12/17/15 03:32 7440-22-412/12/15 00:0010.0 2.5 1
Thallium ND ug/L 12/17/15 03:32 7440-28-012/12/15 00:005.5 5.0 1
Tin ND ug/L 12/17/15 03:32 7440-31-512/12/15 00:001002.5 1
Vanadium 3.0J ug/L 12/17/15 03:32 7440-62-212/12/15 00:0025.0 2.5 1
Zinc 19.0 ug/L 12/17/15 03:32 7440-66-612/12/15 00:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/17/15 18:44 7439-97-612/17/15 14:050.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 12/22/15 20:31 83-32-912/15/15 17:2810.0 0.25 1
Acenaphthylene ND ug/L 12/22/15 20:31 208-96-812/15/15 17:2810.0 0.21 1
Acetophenone ND ug/L 12/22/15 20:31 98-86-212/15/15 17:2810.0 2.0 1
2-Acetylaminofluorene ND ug/L 12/22/15 20:31 53-96-312/15/15 17:2820.0 0.84 1
4-Aminobiphenyl ND ug/L 12/22/15 20:31 92-67-112/15/15 17:2820.0 0.92 1
Anthracene ND ug/L 12/22/15 20:31 120-12-712/15/15 17:2810.0 0.14 1
Benzo(a)anthracene ND ug/L 12/22/15 20:31 56-55-312/15/15 17:2810.0 0.33 1
Benzo(a)pyrene ND ug/L 12/22/15 20:31 50-32-812/15/15 17:2810.0 0.30 1
Benzo(b)fluoranthene ND ug/L 12/22/15 20:31 205-99-212/15/15 17:2810.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 12/22/15 20:31 191-24-212/15/15 17:2810.0 0.38 1
Benzo(k)fluoranthene ND ug/L 12/22/15 20:31 207-08-912/15/15 17:2810.0 0.43 1
Benzyl alcohol ND ug/L 12/22/15 20:31 100-51-612/15/15 17:2820.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 12/22/15 20:31 101-55-312/15/15 17:2810.0 1.3 1
Butylbenzylphthalate ND ug/L 12/22/15 20:31 85-68-712/15/15 17:2810.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 12/22/15 20:31 59-50-712/15/15 17:2820.0 4.2 1
4-Chloroaniline ND ug/L 12/22/15 20:31 106-47-812/15/15 17:2820.0 3.4 1
Chlorobenzilate ND ug/L 12/22/15 20:31 510-15-612/15/15 17:2810.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 12/22/15 20:31 111-91-112/15/15 17:2810.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 12/22/15 20:31 111-44-412/15/15 17:2810.0 1.5 1
bis(2-Chloroisopropyl) ether ND ug/L 12/22/15 20:31 108-60-112/15/15 17:2810.0 1.6 1
2-Chloronaphthalene ND ug/L 12/22/15 20:31 91-58-712/15/15 17:2810.0 2.2 1
2-Chlorophenol ND ug/L 12/22/15 20:31 95-57-812/15/15 17:2810.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 12/22/15 20:31 7005-72-312/15/15 17:2810.0 2.1 1
Chrysene ND ug/L 12/22/15 20:31 218-01-912/15/15 17:2810.0 0.21 1
Diallate ND ug/L 12/22/15 20:31 2303-16-412/15/15 17:2810.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 12/22/15 20:31 53-70-312/15/15 17:2810.0 0.55 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW13 Lab ID:92279395004 Collected:12/08/15 15:50 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Dibenzofuran ND ug/L 12/22/15 20:31 132-64-912/15/15 17:2810.0 1.8 1
3,3'-Dichlorobenzidine ND ug/L 12/22/15 20:31 91-94-112/15/15 17:2820.0 1.4 1
2,4-Dichlorophenol ND ug/L 12/22/15 20:31 120-83-212/15/15 17:2810.0 1.7 1
2,6-Dichlorophenol ND ug/L 12/22/15 20:31 87-65-012/15/15 17:2810.0 1.8 1
Diethylphthalate ND ug/L 12/22/15 20:31 84-66-212/15/15 17:2860001.3 1
Dimethoate ND ug/L 12/22/15 20:31 60-51-512/15/15 17:2820.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 12/22/15 20:31 60-11-712/15/15 17:2810.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 12/22/15 20:31 57-97-612/15/15 17:2810.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 12/22/15 20:31 119-93-712/15/15 17:2810.0 2.1 1
2,4-Dimethylphenol ND ug/L 12/22/15 20:31 105-67-912/15/15 17:2810.0 2.2 1
Dimethylphthalate ND ug/L 12/22/15 20:31 131-11-312/15/15 17:2810.0 1.5 1
Di-n-butylphthalate ND ug/L 12/22/15 20:31 84-74-212/15/15 17:2810.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 12/22/15 20:31 534-52-112/15/15 17:2850.0 1.7 1
1,3-Dinitrobenzene ND ug/L 12/22/15 20:31 99-65-012/15/15 17:2820.0 1.5 1
2,4-Dinitrophenol ND ug/L 12/22/15 20:31 51-28-512/15/15 17:2850.0 6.5 1
2,4-Dinitrotoluene ND ug/L 12/22/15 20:31 121-14-212/15/15 17:2810.0 1.2 1
2,6-Dinitrotoluene ND ug/L 12/22/15 20:31 606-20-212/15/15 17:2810.0 1.7 1
Di-n-octylphthalate ND ug/L 12/22/15 20:31 117-84-012/15/15 17:2810.0 0.86 1
Diphenylamine ND ug/L 12/22/15 20:31 122-39-412/15/15 17:2810.0 1.3 1
Disulfoton ND ug/L 12/22/15 20:31 298-04-412/15/15 17:2810.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 12/22/15 20:31 117-81-712/15/15 17:2815.0 0.85 1
Ethyl methanesulfonate ND ug/L 12/22/15 20:31 62-50-012/15/15 17:2820.0 1.8 1
Famphur ND ug/L 12/22/15 20:31 52-85-712/15/15 17:2820.0 1.7 1
Fluoranthene ND ug/L 12/22/15 20:31 206-44-0 L312/15/15 17:2810.0 0.21 1
Fluorene ND ug/L 12/22/15 20:31 86-73-712/15/15 17:2810.0 0.21 1
Hexachlorobenzene ND ug/L 12/22/15 20:31 118-74-112/15/15 17:2810.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 12/22/15 20:31 77-47-412/15/15 17:2810.0 1.8 1
Hexachloroethane ND ug/L 12/22/15 20:31 67-72-112/15/15 17:2810.0 1.5 1
Hexachloropropene ND ug/L 12/22/15 20:31 1888-71-712/15/15 17:2810.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 12/22/15 20:31 193-39-512/15/15 17:2810.0 0.29 1
Isodrin ND ug/L 12/22/15 20:31 465-73-6 L312/15/15 17:2820.0 2.0 1
Isophorone ND ug/L 12/22/15 20:31 78-59-112/15/15 17:2810.0 1.8 1
Isosafrole ND ug/L 12/22/15 20:31 120-58-112/15/15 17:2810.0 1.8 1
Kepone ND ug/L 12/22/15 20:31 143-50-012/15/15 17:2820.0 3.1 1
Methapyrilene ND ug/L 12/22/15 20:31 91-80-5 L212/15/15 17:281002.7 1
3-Methylcholanthrene ND ug/L 12/22/15 20:31 56-49-512/15/15 17:2810.0 0.82 1
Methyl methanesulfonate ND ug/L 12/22/15 20:31 66-27-312/15/15 17:2810.0 1.3 1
2-Methylnaphthalene ND ug/L 12/22/15 20:31 91-57-612/15/15 17:2810.0 0.28 1
Methyl parathion ND ug/L 12/22/15 20:31 298-00-012/15/15 17:2810.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 12/22/15 20:31 95-48-712/15/15 17:2810.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 12/22/15 20:3112/15/15 17:2810.0 1.7 1
1-Naphthalenamine ND ug/L 12/22/15 20:31 134-32-712/15/15 17:2810.0 0.96 1
2-Naphthalenamine ND ug/L 12/22/15 20:31 91-59-812/15/15 17:2810.0 0.98 1
1,4-Naphthoquinone ND ug/L 12/22/15 20:31 130-15-412/15/15 17:2810.0 1.8 1
2-Nitroaniline ND ug/L 12/22/15 20:31 88-74-412/15/15 17:2850.0 2.8 1
3-Nitroaniline ND ug/L 12/22/15 20:31 99-09-212/15/15 17:2850.0 2.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW13 Lab ID:92279395004 Collected:12/08/15 15:50 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
4-Nitroaniline ND ug/L 12/22/15 20:31 100-01-612/15/15 17:2820.0 2.5 1
Nitrobenzene ND ug/L 12/22/15 20:31 98-95-312/15/15 17:2810.0 1.7 1
2-Nitrophenol ND ug/L 12/22/15 20:31 88-75-512/15/15 17:2810.0 1.7 1
4-Nitrophenol ND ug/L 12/22/15 20:31 100-02-712/15/15 17:2850.0 5.8 1
5-Nitro-o-toluidine ND ug/L 12/22/15 20:31 99-55-812/15/15 17:2810.0 1.2 1
N-Nitrosodiethylamine ND ug/L 12/22/15 20:31 55-18-512/15/15 17:2820.0 1.8 1
N-Nitrosodimethylamine ND ug/L 12/22/15 20:31 62-75-912/15/15 17:2810.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 12/22/15 20:31 924-16-312/15/15 17:2810.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 12/22/15 20:31 621-64-712/15/15 17:2810.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 12/22/15 20:31 86-30-612/15/15 17:2810.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 12/22/15 20:31 10595-95-612/15/15 17:2810.0 1.8 1
N-Nitrosopiperidine ND ug/L 12/22/15 20:31 100-75-412/15/15 17:2820.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 12/22/15 20:31 930-55-212/15/15 17:2810.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 12/22/15 20:31 126-68-112/15/15 17:2810.0 1.8 1
Parathion (Ethyl parathion)ND ug/L 12/22/15 20:31 56-38-212/15/15 17:2810.0 1.1 1
Pentachlorobenzene ND ug/L 12/22/15 20:31 608-93-512/15/15 17:2810.0 2.0 1
Pentachloronitrobenzene ND ug/L 12/22/15 20:31 82-68-812/15/15 17:2820.0 1.0 1
Pentachlorophenol ND ug/L 12/22/15 20:31 87-86-512/15/15 17:2825.0 2.3 1
Phenacetin ND ug/L 12/22/15 20:31 62-44-212/15/15 17:2820.0 0.97 1
Phenanthrene ND ug/L 12/22/15 20:31 85-01-812/15/15 17:2810.0 0.22 1
Phenol ND ug/L 12/22/15 20:31 108-95-212/15/15 17:2810.0 1.7 1
p-Phenylenediamine ND ug/L 12/22/15 20:31 106-50-312/15/15 17:2810.0 0.96 1
Phorate ND ug/L 12/22/15 20:31 298-02-2 L312/15/15 17:2810.0 1.1 1
Pronamide ND ug/L 12/22/15 20:31 23950-58-512/15/15 17:2810.0 0.97 1
Pyrene ND ug/L 12/22/15 20:31 129-00-012/15/15 17:2810.0 0.19 1
Safrole ND ug/L 12/22/15 20:31 94-59-712/15/15 17:2810.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 12/22/15 20:31 95-94-312/15/15 17:2810.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 12/22/15 20:31 58-90-212/15/15 17:2810.0 2.3 1
Thionazin ND ug/L 12/22/15 20:31 297-97-212/15/15 17:2820.0 1.2 1
O-Toluidine ND ug/L 12/22/15 20:31 95-53-412/15/15 17:2810.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 12/22/15 20:31 95-95-412/15/15 17:2810.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 12/22/15 20:31 88-06-212/15/15 17:2810.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 12/22/15 20:31 99-35-4 L312/15/15 17:2810.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)85 %12/22/15 20:31 4165-60-012/15/15 17:2821-110 1
2-Fluorobiphenyl (S)76 %12/22/15 20:31 321-60-812/15/15 17:2827-110 1
Terphenyl-d14 (S)89 %12/22/15 20:31 1718-51-012/15/15 17:2831-107 1
Phenol-d6 (S)23 %12/22/15 20:31 13127-88-312/15/15 17:2810-110 1
2-Fluorophenol (S)33 %12/22/15 20:31 367-12-412/15/15 17:2812-110 1
2,4,6-Tribromophenol (S)95 %12/22/15 20:31 118-79-612/15/15 17:2827-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/19/15 15:06 67-64-110010.0 1
Acetonitrile ND ug/L 12/19/15 15:06 75-05-855.0 2.2 1
Acrolein ND ug/L 12/19/15 15:06 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 12/19/15 15:06 107-13-12001.9 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW13 Lab ID:92279395004 Collected:12/08/15 15:50 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Allyl chloride ND ug/L 12/19/15 15:06 107-05-110.0 1.5 1
Benzene 13.8 ug/L 12/19/15 15:06 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/19/15 15:06 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/19/15 15:06 75-27-41.0 0.18 1
Bromoform ND ug/L 12/19/15 15:06 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/19/15 15:06 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/19/15 15:06 78-93-31000.96 1
Carbon disulfide ND ug/L 12/19/15 15:06 75-15-01001.2 1
Carbon tetrachloride ND ug/L 12/19/15 15:06 56-23-51.0 0.25 1
Chlorobenzene 0.86J ug/L 12/19/15 15:06 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/19/15 15:06 75-00-310.0 0.54 1
Chloroform ND ug/L 12/19/15 15:06 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/19/15 15:06 74-87-31.0 0.11 1
Chloroprene ND ug/L 12/19/15 15:06 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 12/19/15 15:06 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/19/15 15:06 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/19/15 15:06 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/19/15 15:06 74-95-310.0 0.21 1
1,2-Dichlorobenzene 0.45J ug/L 12/19/15 15:06 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 12/19/15 15:06 541-73-15.0 0.24 1
1,4-Dichlorobenzene 13.2 ug/L 12/19/15 15:06 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/19/15 15:06 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 12/19/15 15:06 75-71-85.0 0.21 1
1,1-Dichloroethane 33.7 ug/L 12/19/15 15:06 75-34-35.0 0.32 1
1,2-Dichloroethane 1.3 ug/L 12/19/15 15:06 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/19/15 15:06 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 25.8 ug/L 12/19/15 15:06 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/19/15 15:06 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/19/15 15:06 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 12/19/15 15:06 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 12/19/15 15:06 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 12/19/15 15:06 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 12/19/15 15:06 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/19/15 15:06 10061-02-61.0 0.26 1
Ethylbenzene 2.7 ug/L 12/19/15 15:06 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 12/19/15 15:06 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 12/19/15 15:06 87-68-310.0 0.71 1
2-Hexanone ND ug/L 12/19/15 15:06 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/19/15 15:06 74-88-410.0 0.32 1
Isobutanol ND ug/L 12/19/15 15:06 78-83-110035.0 1
Methacrylonitrile ND ug/L 12/19/15 15:06 126-98-71000.93 1
Methylene Chloride 113 ug/L 12/19/15 15:06 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 12/19/15 15:06 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/19/15 15:06 108-10-11000.33 1
Naphthalene 2.2J ug/L 12/19/15 15:06 91-20-310.0 0.24 1
Propionitrile ND ug/L 12/19/15 15:06 107-12-01503.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW13 Lab ID:92279395004 Collected:12/08/15 15:50 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Styrene ND ug/L 12/19/15 15:06 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/19/15 15:06 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/19/15 15:06 79-34-53.0 0.40 1
Tetrachloroethene 5.6 ug/L 12/19/15 15:06 127-18-41.0 0.46 1
Tetrahydrofuran 9.7J ug/L 12/19/15 15:06 109-99-910.0 3.1 1
Toluene 6.0 ug/L 12/19/15 15:06 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 12/19/15 15:06 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 12/19/15 15:06 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/19/15 15:06 79-00-51.0 0.29 1
Trichloroethene 9.7 ug/L 12/19/15 15:06 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/19/15 15:06 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/19/15 15:06 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/19/15 15:06 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/19/15 15:06 75-01-41.0 0.62 1
Xylene (Total)45.4 ug/L 12/19/15 15:06 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)105 %12/19/15 15:06 460-00-470-130 1
1,2-Dichloroethane-d4 (S)106 %12/19/15 15:06 17060-07-070-130 1
Toluene-d8 (S)102 %12/19/15 15:06 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 9130 ug/L 12/14/15 16:16500010001
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids ND ug/L 12/11/15 10:4225000250001
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/11/15 15:00 18496-25-810001001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate ND ug/L 12/11/15 14:06 14808-79-825000010001
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 1910 ug/L 12/17/15 16:59 16887-00-610005001
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 12/16/15 11:14 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW16S Lab ID:92279395005 Collected:12/08/15 13:30 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 12/14/15 22:13 309-00-212/11/15 16:000.050 0.050 1
alpha-BHC ND ug/L 12/14/15 22:13 319-84-612/11/15 16:000.050 0.050 1
beta-BHC ND ug/L 12/14/15 22:13 319-85-712/11/15 16:000.050 0.050 1
delta-BHC ND ug/L 12/14/15 22:13 319-86-812/11/15 16:000.050 0.050 1
gamma-BHC (Lindane)ND ug/L 12/14/15 22:13 58-89-912/11/15 16:000.050 0.050 1
Chlordane (Technical)ND ug/L 12/14/15 22:13 57-74-912/11/15 16:000.50 0.20 1
4,4'-DDD ND ug/L 12/14/15 22:13 72-54-812/11/15 16:000.10 0.050 1
4,4'-DDE ND ug/L 12/14/15 22:13 72-55-912/11/15 16:000.10 0.050 1
4,4'-DDT ND ug/L 12/14/15 22:13 50-29-312/11/15 16:000.10 0.050 1
Dieldrin ND ug/L 12/14/15 22:13 60-57-112/11/15 16:000.075 0.050 1
Endosulfan I ND ug/L 12/14/15 22:13 959-98-812/11/15 16:000.10 0.050 1
Endosulfan II ND ug/L 12/14/15 22:13 33213-65-912/11/15 16:000.10 0.050 1
Endosulfan sulfate ND ug/L 12/14/15 22:13 1031-07-812/11/15 16:000.10 0.050 1
Endrin ND ug/L 12/14/15 22:13 72-20-812/11/15 16:000.10 0.050 1
Endrin aldehyde ND ug/L 12/14/15 22:13 7421-93-412/11/15 16:000.10 0.050 1
Heptachlor ND ug/L 12/14/15 22:13 76-44-812/11/15 16:000.050 0.050 1
Heptachlor epoxide ND ug/L 12/14/15 22:13 1024-57-312/11/15 16:000.075 0.050 1
Methoxychlor ND ug/L 12/14/15 22:13 72-43-512/11/15 16:001.0 0.15 1
Toxaphene ND ug/L 12/14/15 22:13 8001-35-212/11/15 16:001.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)56 %12/14/15 22:13 877-09-812/11/15 16:0020-130 1
Decachlorobiphenyl (S)62 %12/14/15 22:13 2051-24-312/11/15 16:0020-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 12/14/15 20:08 12674-11-212/11/15 16:000.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 12/14/15 20:08 11104-28-212/11/15 16:000.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 12/14/15 20:08 11141-16-512/11/15 16:000.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 12/14/15 20:08 53469-21-912/11/15 16:000.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 12/14/15 20:08 12672-29-612/11/15 16:000.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 12/14/15 20:08 11097-69-112/11/15 16:000.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 12/14/15 20:08 11096-82-512/11/15 16:000.50 0.50 1
Surrogates
Decachlorobiphenyl (S)74 %12/14/15 20:08 2051-24-312/11/15 16:0010-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 12/18/15 13:48 94-75-712/15/15 20:150.94 0.22 1
Dinoseb ND ug/L 12/18/15 13:48 88-85-712/15/15 20:150.19 0.057 1
2,4,5-T ND ug/L 12/18/15 13:48 93-76-512/15/15 20:150.19 0.042 1
2,4,5-TP (Silvex)ND ug/L 12/18/15 13:48 93-72-112/15/15 20:150.19 0.049 1
Surrogates
2,4-DCAA (S)90 %12/18/15 13:48 19719-28-912/15/15 20:1536-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/17/15 03:35 7440-36-012/12/15 00:006.0 3.8 1
Arsenic ND ug/L 12/17/15 03:35 7440-38-212/12/15 00:0010.0 2.5 1
Barium 50.6J ug/L 12/17/15 03:35 7440-39-312/12/15 00:001002.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW16S Lab ID:92279395005 Collected:12/08/15 13:30 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Beryllium ND ug/L 12/17/15 03:35 7440-41-712/12/15 00:001.0 0.50 1
Cadmium ND ug/L 12/17/15 03:35 7440-43-912/12/15 00:001.0 0.50 1
Chromium ND ug/L 12/17/15 03:35 7440-47-312/12/15 00:0010.0 2.5 1
Cobalt 32.8 ug/L 12/17/15 03:35 7440-48-412/12/15 00:0010.0 2.5 1
Copper 5.9J ug/L 12/17/15 03:35 7440-50-812/12/15 00:0010.0 2.5 1
Iron 27400 ug/L 12/17/15 03:35 7439-89-612/12/15 00:0030025.0 1
Lead ND ug/L 12/17/15 03:35 7439-92-112/12/15 00:0010.0 2.5 1
Manganese 8440 ug/L 12/17/15 03:35 7439-96-512/12/15 00:0050.0 2.5 1
Nickel ND ug/L 12/17/15 03:35 7440-02-012/12/15 00:0050.0 2.5 1
Selenium ND ug/L 12/17/15 03:35 7782-49-212/12/15 00:0010.0 5.0 1
Silver ND ug/L 12/17/15 03:35 7440-22-412/12/15 00:0010.0 2.5 1
Thallium ND ug/L 12/17/15 03:35 7440-28-012/12/15 00:005.5 5.0 1
Tin ND ug/L 12/17/15 03:35 7440-31-512/12/15 00:001002.5 1
Vanadium 11.5J ug/L 12/17/15 03:35 7440-62-212/12/15 00:0025.0 2.5 1
Zinc 47.3 ug/L 12/17/15 03:35 7440-66-612/12/15 00:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/17/15 18:46 7439-97-612/17/15 14:050.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 12/22/15 20:59 83-32-912/15/15 17:2810.0 0.25 1
Acenaphthylene ND ug/L 12/22/15 20:59 208-96-812/15/15 17:2810.0 0.21 1
Acetophenone ND ug/L 12/22/15 20:59 98-86-212/15/15 17:2810.0 2.0 1
2-Acetylaminofluorene ND ug/L 12/22/15 20:59 53-96-312/15/15 17:2820.0 0.84 1
4-Aminobiphenyl ND ug/L 12/22/15 20:59 92-67-112/15/15 17:2820.0 0.92 1
Anthracene ND ug/L 12/22/15 20:59 120-12-712/15/15 17:2810.0 0.14 1
Benzo(a)anthracene ND ug/L 12/22/15 20:59 56-55-312/15/15 17:2810.0 0.33 1
Benzo(a)pyrene ND ug/L 12/22/15 20:59 50-32-812/15/15 17:2810.0 0.30 1
Benzo(b)fluoranthene ND ug/L 12/22/15 20:59 205-99-212/15/15 17:2810.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 12/22/15 20:59 191-24-212/15/15 17:2810.0 0.38 1
Benzo(k)fluoranthene ND ug/L 12/22/15 20:59 207-08-912/15/15 17:2810.0 0.43 1
Benzyl alcohol ND ug/L 12/22/15 20:59 100-51-612/15/15 17:2820.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 12/22/15 20:59 101-55-312/15/15 17:2810.0 1.3 1
Butylbenzylphthalate ND ug/L 12/22/15 20:59 85-68-712/15/15 17:2810.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 12/22/15 20:59 59-50-712/15/15 17:2820.0 4.2 1
4-Chloroaniline ND ug/L 12/22/15 20:59 106-47-812/15/15 17:2820.0 3.4 1
Chlorobenzilate ND ug/L 12/22/15 20:59 510-15-612/15/15 17:2810.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 12/22/15 20:59 111-91-112/15/15 17:2810.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 12/22/15 20:59 111-44-412/15/15 17:2810.0 1.5 1
bis(2-Chloroisopropyl) ether ND ug/L 12/22/15 20:59 108-60-112/15/15 17:2810.0 1.6 1
2-Chloronaphthalene ND ug/L 12/22/15 20:59 91-58-712/15/15 17:2810.0 2.2 1
2-Chlorophenol ND ug/L 12/22/15 20:59 95-57-812/15/15 17:2810.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 12/22/15 20:59 7005-72-312/15/15 17:2810.0 2.1 1
Chrysene ND ug/L 12/22/15 20:59 218-01-912/15/15 17:2810.0 0.21 1
Diallate ND ug/L 12/22/15 20:59 2303-16-412/15/15 17:2810.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 12/22/15 20:59 53-70-312/15/15 17:2810.0 0.55 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW16S Lab ID:92279395005 Collected:12/08/15 13:30 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Dibenzofuran ND ug/L 12/22/15 20:59 132-64-912/15/15 17:2810.0 1.8 1
3,3'-Dichlorobenzidine ND ug/L 12/22/15 20:59 91-94-112/15/15 17:2820.0 1.4 1
2,4-Dichlorophenol ND ug/L 12/22/15 20:59 120-83-212/15/15 17:2810.0 1.7 1
2,6-Dichlorophenol ND ug/L 12/22/15 20:59 87-65-012/15/15 17:2810.0 1.8 1
Diethylphthalate ND ug/L 12/22/15 20:59 84-66-212/15/15 17:2860001.3 1
Dimethoate ND ug/L 12/22/15 20:59 60-51-512/15/15 17:2820.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 12/22/15 20:59 60-11-712/15/15 17:2810.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 12/22/15 20:59 57-97-612/15/15 17:2810.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 12/22/15 20:59 119-93-712/15/15 17:2810.0 2.1 1
2,4-Dimethylphenol ND ug/L 12/22/15 20:59 105-67-912/15/15 17:2810.0 2.2 1
Dimethylphthalate ND ug/L 12/22/15 20:59 131-11-312/15/15 17:2810.0 1.5 1
Di-n-butylphthalate ND ug/L 12/22/15 20:59 84-74-212/15/15 17:2810.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 12/22/15 20:59 534-52-112/15/15 17:2850.0 1.7 1
1,3-Dinitrobenzene ND ug/L 12/22/15 20:59 99-65-012/15/15 17:2820.0 1.5 1
2,4-Dinitrophenol ND ug/L 12/22/15 20:59 51-28-512/15/15 17:2850.0 6.5 1
2,4-Dinitrotoluene ND ug/L 12/22/15 20:59 121-14-212/15/15 17:2810.0 1.2 1
2,6-Dinitrotoluene ND ug/L 12/22/15 20:59 606-20-212/15/15 17:2810.0 1.7 1
Di-n-octylphthalate ND ug/L 12/22/15 20:59 117-84-012/15/15 17:2810.0 0.86 1
Diphenylamine ND ug/L 12/22/15 20:59 122-39-412/15/15 17:2810.0 1.3 1
Disulfoton ND ug/L 12/22/15 20:59 298-04-412/15/15 17:2810.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 12/22/15 20:59 117-81-712/15/15 17:2815.0 0.85 1
Ethyl methanesulfonate ND ug/L 12/22/15 20:59 62-50-012/15/15 17:2820.0 1.8 1
Famphur ND ug/L 12/22/15 20:59 52-85-712/15/15 17:2820.0 1.7 1
Fluoranthene ND ug/L 12/22/15 20:59 206-44-0 L312/15/15 17:2810.0 0.21 1
Fluorene ND ug/L 12/22/15 20:59 86-73-712/15/15 17:2810.0 0.21 1
Hexachlorobenzene ND ug/L 12/22/15 20:59 118-74-112/15/15 17:2810.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 12/22/15 20:59 77-47-412/15/15 17:2810.0 1.8 1
Hexachloroethane ND ug/L 12/22/15 20:59 67-72-112/15/15 17:2810.0 1.5 1
Hexachloropropene ND ug/L 12/22/15 20:59 1888-71-712/15/15 17:2810.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 12/22/15 20:59 193-39-512/15/15 17:2810.0 0.29 1
Isodrin ND ug/L 12/22/15 20:59 465-73-6 L312/15/15 17:2820.0 2.0 1
Isophorone ND ug/L 12/22/15 20:59 78-59-112/15/15 17:2810.0 1.8 1
Isosafrole ND ug/L 12/22/15 20:59 120-58-112/15/15 17:2810.0 1.8 1
Kepone ND ug/L 12/22/15 20:59 143-50-012/15/15 17:2820.0 3.1 1
Methapyrilene ND ug/L 12/22/15 20:59 91-80-5 L212/15/15 17:281002.7 1
3-Methylcholanthrene ND ug/L 12/22/15 20:59 56-49-512/15/15 17:2810.0 0.82 1
Methyl methanesulfonate ND ug/L 12/22/15 20:59 66-27-312/15/15 17:2810.0 1.3 1
2-Methylnaphthalene ND ug/L 12/22/15 20:59 91-57-612/15/15 17:2810.0 0.28 1
Methyl parathion ND ug/L 12/22/15 20:59 298-00-012/15/15 17:2810.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 12/22/15 20:59 95-48-712/15/15 17:2810.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 12/22/15 20:5912/15/15 17:2810.0 1.7 1
1-Naphthalenamine ND ug/L 12/22/15 20:59 134-32-712/15/15 17:2810.0 0.96 1
2-Naphthalenamine ND ug/L 12/22/15 20:59 91-59-812/15/15 17:2810.0 0.98 1
1,4-Naphthoquinone ND ug/L 12/22/15 20:59 130-15-412/15/15 17:2810.0 1.8 1
2-Nitroaniline ND ug/L 12/22/15 20:59 88-74-412/15/15 17:2850.0 2.8 1
3-Nitroaniline ND ug/L 12/22/15 20:59 99-09-212/15/15 17:2850.0 2.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW16S Lab ID:92279395005 Collected:12/08/15 13:30 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
4-Nitroaniline ND ug/L 12/22/15 20:59 100-01-612/15/15 17:2820.0 2.5 1
Nitrobenzene ND ug/L 12/22/15 20:59 98-95-312/15/15 17:2810.0 1.7 1
2-Nitrophenol ND ug/L 12/22/15 20:59 88-75-512/15/15 17:2810.0 1.7 1
4-Nitrophenol ND ug/L 12/22/15 20:59 100-02-712/15/15 17:2850.0 5.8 1
5-Nitro-o-toluidine ND ug/L 12/22/15 20:59 99-55-812/15/15 17:2810.0 1.2 1
N-Nitrosodiethylamine ND ug/L 12/22/15 20:59 55-18-512/15/15 17:2820.0 1.8 1
N-Nitrosodimethylamine ND ug/L 12/22/15 20:59 62-75-912/15/15 17:2810.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 12/22/15 20:59 924-16-312/15/15 17:2810.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 12/22/15 20:59 621-64-712/15/15 17:2810.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 12/22/15 20:59 86-30-612/15/15 17:2810.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 12/22/15 20:59 10595-95-612/15/15 17:2810.0 1.8 1
N-Nitrosopiperidine ND ug/L 12/22/15 20:59 100-75-412/15/15 17:2820.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 12/22/15 20:59 930-55-212/15/15 17:2810.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 12/22/15 20:59 126-68-112/15/15 17:2810.0 1.8 1
Parathion (Ethyl parathion)ND ug/L 12/22/15 20:59 56-38-212/15/15 17:2810.0 1.1 1
Pentachlorobenzene ND ug/L 12/22/15 20:59 608-93-512/15/15 17:2810.0 2.0 1
Pentachloronitrobenzene ND ug/L 12/22/15 20:59 82-68-812/15/15 17:2820.0 1.0 1
Pentachlorophenol ND ug/L 12/22/15 20:59 87-86-512/15/15 17:2825.0 2.3 1
Phenacetin ND ug/L 12/22/15 20:59 62-44-212/15/15 17:2820.0 0.97 1
Phenanthrene ND ug/L 12/22/15 20:59 85-01-812/15/15 17:2810.0 0.22 1
Phenol ND ug/L 12/22/15 20:59 108-95-212/15/15 17:2810.0 1.7 1
p-Phenylenediamine ND ug/L 12/22/15 20:59 106-50-312/15/15 17:2810.0 0.96 1
Phorate ND ug/L 12/22/15 20:59 298-02-2 L312/15/15 17:2810.0 1.1 1
Pronamide ND ug/L 12/22/15 20:59 23950-58-512/15/15 17:2810.0 0.97 1
Pyrene ND ug/L 12/22/15 20:59 129-00-012/15/15 17:2810.0 0.19 1
Safrole ND ug/L 12/22/15 20:59 94-59-712/15/15 17:2810.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 12/22/15 20:59 95-94-312/15/15 17:2810.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 12/22/15 20:59 58-90-212/15/15 17:2810.0 2.3 1
Thionazin ND ug/L 12/22/15 20:59 297-97-212/15/15 17:2820.0 1.2 1
O-Toluidine ND ug/L 12/22/15 20:59 95-53-412/15/15 17:2810.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 12/22/15 20:59 95-95-412/15/15 17:2810.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 12/22/15 20:59 88-06-212/15/15 17:2810.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 12/22/15 20:59 99-35-4 L312/15/15 17:2810.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)77 %12/22/15 20:59 4165-60-012/15/15 17:2821-110 1
2-Fluorobiphenyl (S)67 %12/22/15 20:59 321-60-812/15/15 17:2827-110 1
Terphenyl-d14 (S)71 %12/22/15 20:59 1718-51-012/15/15 17:2831-107 1
Phenol-d6 (S)22 %12/22/15 20:59 13127-88-312/15/15 17:2810-110 1
2-Fluorophenol (S)32 %12/22/15 20:59 367-12-412/15/15 17:2812-110 1
2,4,6-Tribromophenol (S)86 %12/22/15 20:59 118-79-612/15/15 17:2827-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone 16.5J ug/L 12/20/15 19:06 67-64-110010.0 1
Acetonitrile ND ug/L 12/20/15 19:06 75-05-855.0 2.2 1
Acrolein ND ug/L 12/20/15 19:06 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 12/20/15 19:06 107-13-12001.9 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW16S Lab ID:92279395005 Collected:12/08/15 13:30 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Allyl chloride ND ug/L 12/20/15 19:06 107-05-110.0 1.5 1
Benzene 1.7 ug/L 12/20/15 19:06 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/20/15 19:06 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/20/15 19:06 75-27-41.0 0.18 1
Bromoform ND ug/L 12/20/15 19:06 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/20/15 19:06 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/20/15 19:06 78-93-31000.96 1
Carbon disulfide ND ug/L 12/20/15 19:06 75-15-01001.2 1
Carbon tetrachloride ND ug/L 12/20/15 19:06 56-23-51.0 0.25 1
Chlorobenzene 0.82J ug/L 12/20/15 19:06 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/20/15 19:06 75-00-310.0 0.54 1
Chloroform ND ug/L 12/20/15 19:06 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/20/15 19:06 74-87-31.0 0.11 1
Chloroprene ND ug/L 12/20/15 19:06 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 12/20/15 19:06 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/20/15 19:06 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/20/15 19:06 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/20/15 19:06 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/20/15 19:06 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 12/20/15 19:06 541-73-15.0 0.24 1
1,4-Dichlorobenzene 9.1 ug/L 12/20/15 19:06 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/20/15 19:06 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 12/20/15 19:06 75-71-85.0 0.21 1
1,1-Dichloroethane 10.3 ug/L 12/20/15 19:06 75-34-35.0 0.32 1
1,2-Dichloroethane 1.3 ug/L 12/20/15 19:06 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/20/15 19:06 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 4.4J ug/L 12/20/15 19:06 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/20/15 19:06 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/20/15 19:06 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 12/20/15 19:06 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 12/20/15 19:06 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 12/20/15 19:06 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 12/20/15 19:06 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/20/15 19:06 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/20/15 19:06 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 12/20/15 19:06 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 12/20/15 19:06 87-68-310.0 0.71 1
2-Hexanone ND ug/L 12/20/15 19:06 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/20/15 19:06 74-88-410.0 0.32 1
Isobutanol ND ug/L 12/20/15 19:06 78-83-110035.0 1
Methacrylonitrile ND ug/L 12/20/15 19:06 126-98-71000.93 1
Methylene Chloride ND ug/L 12/20/15 19:06 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 12/20/15 19:06 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/20/15 19:06 108-10-11000.33 1
Naphthalene ND ug/L 12/20/15 19:06 91-20-310.0 0.24 1
Propionitrile ND ug/L 12/20/15 19:06 107-12-01503.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW16S Lab ID:92279395005 Collected:12/08/15 13:30 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Styrene ND ug/L 12/20/15 19:06 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/20/15 19:06 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/20/15 19:06 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/20/15 19:06 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/20/15 19:06 109-99-910.0 3.1 1
Toluene 0.31J ug/L 12/20/15 19:06 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 12/20/15 19:06 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 12/20/15 19:06 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/20/15 19:06 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/20/15 19:06 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/20/15 19:06 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/20/15 19:06 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/20/15 19:06 108-05-450.0 0.35 1
Vinyl chloride 1.4 ug/L 12/20/15 19:06 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/20/15 19:06 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)102 %12/20/15 19:06 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %12/20/15 19:06 17060-07-070-130 1
Toluene-d8 (S)108 %12/20/15 19:06 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 95900 ug/L 12/14/15 16:27500010001
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 106000 ug/L 12/11/15 10:4325000250001
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/11/15 15:00 18496-25-810001001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate ND ug/L 12/11/15 14:06 14808-79-825000010001
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 4190 ug/L 12/17/15 17:03 16887-00-610005001
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 12/16/15 11:14 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW16D Lab ID:92279395006 Collected:12/08/15 14:32 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/17/15 03:38 7440-36-012/12/15 00:006.0 3.8 1
Arsenic ND ug/L 12/17/15 03:38 7440-38-212/12/15 00:0010.0 2.5 1
Barium 8.0J ug/L 12/17/15 03:38 7440-39-312/12/15 00:001002.5 1
Beryllium ND ug/L 12/17/15 03:38 7440-41-712/12/15 00:001.0 0.50 1
Cadmium ND ug/L 12/17/15 03:38 7440-43-912/12/15 00:001.0 0.50 1
Chromium ND ug/L 12/17/15 03:38 7440-47-312/12/15 00:0010.0 2.5 1
Cobalt ND ug/L 12/17/15 03:38 7440-48-412/12/15 00:0010.0 2.5 1
Copper ND ug/L 12/17/15 03:38 7440-50-812/12/15 00:0010.0 2.5 1
Iron 43.7J ug/L 12/17/15 03:38 7439-89-612/12/15 00:0030025.0 1
Lead ND ug/L 12/17/15 03:38 7439-92-112/12/15 00:0010.0 2.5 1
Manganese 124 ug/L 12/17/15 03:38 7439-96-512/12/15 00:0050.0 2.5 1
Nickel ND ug/L 12/17/15 03:38 7440-02-012/12/15 00:0050.0 2.5 1
Selenium ND ug/L 12/17/15 03:38 7782-49-212/12/15 00:0010.0 5.0 1
Silver ND ug/L 12/17/15 03:38 7440-22-412/12/15 00:0010.0 2.5 1
Thallium ND ug/L 12/17/15 03:38 7440-28-012/12/15 00:005.5 5.0 1
Vanadium ND ug/L 12/17/15 03:38 7440-62-212/12/15 00:0025.0 2.5 1
Zinc 8.2J ug/L 12/17/15 03:38 7440-66-612/12/15 00:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/19/15 14:36 7439-97-612/17/15 16:150.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/19/15 15:40 67-64-110010.0 1
Acrylonitrile ND ug/L 12/19/15 15:40 107-13-12001.9 1
Benzene ND ug/L 12/19/15 15:40 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/19/15 15:40 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/19/15 15:40 75-27-41.0 0.18 1
Bromoform ND ug/L 12/19/15 15:40 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/19/15 15:40 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/19/15 15:40 78-93-31000.96 1
Carbon disulfide ND ug/L 12/19/15 15:40 75-15-01001.2 1
Carbon tetrachloride ND ug/L 12/19/15 15:40 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/19/15 15:40 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/19/15 15:40 75-00-310.0 0.54 1
Chloroform ND ug/L 12/19/15 15:40 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/19/15 15:40 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/19/15 15:40 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/19/15 15:40 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/19/15 15:40 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/19/15 15:40 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/19/15 15:40 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 12/19/15 15:40 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/19/15 15:40 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 12/19/15 15:40 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/19/15 15:40 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/19/15 15:40 75-35-45.0 0.56 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW16D Lab ID:92279395006 Collected:12/08/15 14:32 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,2-Dichloroethene ND ug/L 12/19/15 15:40 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/19/15 15:40 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/19/15 15:40 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/19/15 15:40 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/19/15 15:40 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/19/15 15:40 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/19/15 15:40 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/19/15 15:40 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 12/19/15 15:40 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/19/15 15:40 108-10-11000.33 1
Styrene ND ug/L 12/19/15 15:40 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/19/15 15:40 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/19/15 15:40 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/19/15 15:40 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/19/15 15:40 109-99-910.0 3.1 1
Toluene ND ug/L 12/19/15 15:40 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/19/15 15:40 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/19/15 15:40 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/19/15 15:40 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/19/15 15:40 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/19/15 15:40 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/19/15 15:40 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/19/15 15:40 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/19/15 15:40 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)103 %12/19/15 15:40 460-00-470-130 1
1,2-Dichloroethane-d4 (S)96 %12/19/15 15:40 17060-07-070-130 1
Toluene-d8 (S)107 %12/19/15 15:40 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 46200 ug/L 12/14/15 16:39500010001
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 93000 ug/L 12/11/15 10:4325000250001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 9260J ug/L 12/11/15 14:06 14808-79-825000010001
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 945J ug/L 12/17/15 17:04 16887-00-610005001
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Sample:1203-MW12 Re-run Sb,Cr,V Lab ID:92279395007 Collected:12/08/15 12:51 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony 6.2 ug/L 01/19/16 11:57 7440-36-001/15/16 18:006.0 3.8 1
Chromium 14.7 ug/L 01/19/16 11:57 7440-47-301/15/16 18:0010.0 2.5 1
Vanadium 19.8J ug/L 01/19/16 11:57 7440-62-201/15/16 18:0025.0 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/8788
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1629746
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005
Matrix:Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/17/15 17:420.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1629747LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.42.5 96 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1629748MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279275008
1629749
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 96 75-12599 3 252.5ND 2.4 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/8789
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples:92279395006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1629752
Associated Lab Samples:92279395006
Matrix:Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/19/15 14:310.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1629753LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1629754MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279395006
1629755
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 100 75-12596 3 252.5ND 2.5 2.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20262
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005, 92279395006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1627237
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005, 92279395006
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 12/17/15 02:173.8
Arsenic ug/L ND 10.0 12/17/15 02:172.5
Barium ug/L ND 100 12/17/15 02:172.5
Beryllium ug/L ND 1.0 12/17/15 02:170.50
Cadmium ug/L ND 1.0 12/17/15 02:170.50
Chromium ug/L ND 10.0 12/17/15 02:172.5
Cobalt ug/L ND 10.0 12/17/15 02:172.5
Copper ug/L ND 10.0 12/17/15 02:172.5
Iron ug/L ND 300 12/17/15 02:1725.0
Lead ug/L ND 10.0 12/17/15 02:172.5
Manganese ug/L ND 50.0 12/17/15 02:172.5
Nickel ug/L ND 50.0 12/17/15 02:172.5
Selenium ug/L ND 10.0 12/17/15 02:175.0
Silver ug/L ND 10.0 12/17/15 02:172.5
Thallium ug/L ND 5.5 12/17/15 02:175.0
Tin ug/L ND 100 12/17/15 02:172.5
Vanadium ug/L ND 25.0 12/17/15 02:172.5
Zinc ug/L ND 10.0 12/17/15 02:175.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1627238LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 587500 117 80-120
Arsenic ug/L 523500 105 80-120
Barium ug/L 532500 106 80-120
Beryllium ug/L 525500 105 80-120
Cadmium ug/L 542500 108 80-120
Chromium ug/L 514500 103 80-120
Cobalt ug/L 546500 109 80-120
Copper ug/L 524500 105 80-120
Iron ug/L 54205000 108 80-120
Lead ug/L 539500 108 80-120
Manganese ug/L 562500 112 80-120
Nickel ug/L 542500 108 80-120
Selenium ug/L 541500 108 80-120
Silver ug/L 275250 110 80-120
Thallium ug/L 516500 103 80-120
Tin ug/L 592500 118 80-120
Vanadium ug/L 570500 114 80-120
Zinc ug/L 550500 110 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 44 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1627239MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279385001
1627240
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 107 75-125109 2 25500ND537545
Arsenic ug/L 500 95 75-12598 2 25500ND479490
Barium ug/L 500 99 75-125100 0 25500109605608
Beryllium ug/L 500 98 75-12599 1 25500ND490494
Cadmium ug/L 500 99 75-125101 2 25500ND496504
Chromium ug/L 500 94 75-12595 1 25500ND471478
Cobalt ug/L 500 101 75-125102 1 2550052.0 555 560
Copper ug/L 500 99 75-125100 2 255007.9J 501 510
Iron ug/L 5000 124 75-12585 3 255000558006200060000
Lead ug/L 500 98 75-125100 2 255004.6J 494 502
Manganese ug/L 500 117 75-12594 3 25500347040603940
Nickel ug/L 500 99 75-125101 1 255002.6J 499 505
Selenium ug/L 500 99 75-125101 2 25500ND496505
Silver ug/L 250 102 75-125103 1 25250ND255258
Thallium ug/L 500 92 75-12596 4 255006.9 469 486
Tin ug/L 500 108 75-125110 2 25500ND542551
Vanadium ug/L 500 107 75-125107 1 255008.3J 541 544
Zinc ug/L 500 102 75-125103 0 255006.5J 517 520
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 45 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20488
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92279395007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1648385
Associated Lab Samples:92279395007
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 01/19/16 11:173.8
Chromium ug/L ND 10.0 01/19/16 11:172.5
Vanadium ug/L ND 25.0 01/19/16 11:172.5
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1648386LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 514500 103 80-120
Chromium ug/L 502500 100 80-120
Vanadium ug/L 507500 101 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1648387MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92277140008
1648388
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 106 75-125109 3 255009.4 537 552
Chromium ug/L 500 99 75-125101 2 255007.9 504 515
Vanadium ug/L 500 103 75-125106 3 25500ND516533
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 46 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34799
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1633901
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395006
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 12/19/15 13:250.33
1,1,1-Trichloroethane ug/L ND 1.0 12/19/15 13:250.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 12/19/15 13:250.40
1,1,2-Trichloroethane ug/L ND 1.0 12/19/15 13:250.29
1,1-Dichloroethane ug/L ND 5.0 12/19/15 13:250.32
1,1-Dichloroethene ug/L ND 5.0 12/19/15 13:250.56
1,1-Dichloropropene ug/L ND 5.0 12/19/15 13:250.49
1,2,3-Trichloropropane ug/L ND 1.0 12/19/15 13:250.41
1,2,4-Trichlorobenzene ug/L ND 10.0 12/19/15 13:250.35
1,2-Dibromo-3-chloropropane ug/L ND 13.0 12/19/15 13:252.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/19/15 13:250.27
1,2-Dichlorobenzene ug/L ND 5.0 12/19/15 13:250.30
1,2-Dichloroethane ug/L ND 1.0 12/19/15 13:250.24
1,2-Dichloropropane ug/L ND 1.0 12/19/15 13:250.27
1,3-Dichlorobenzene ug/L ND 5.0 12/19/15 13:250.24
1,3-Dichloropropane ug/L ND 1.0 12/19/15 13:250.28
1,4-Dichlorobenzene ug/L ND 1.0 12/19/15 13:250.33
2,2-Dichloropropane ug/L ND 15.0 12/19/15 13:250.13
2-Butanone (MEK)ug/L ND 100 12/19/15 13:250.96
2-Hexanone ug/L ND 50.0 12/19/15 13:250.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 12/19/15 13:250.33
Acetone ug/L ND 100 12/19/15 13:2510.0
Acetonitrile ug/L ND 55.0 12/19/15 13:252.2
Acrolein ug/L ND 53.0 12/19/15 13:251.6
Acrylonitrile ug/L ND 200 12/19/15 13:251.9
Allyl chloride ug/L ND 10.0 12/19/15 13:251.5
Benzene ug/L ND 1.0 12/19/15 13:250.25
Bromochloromethane ug/L ND 3.0 12/19/15 13:250.17
Bromodichloromethane ug/L ND 1.0 12/19/15 13:250.18
Bromoform ug/L ND 3.0 12/19/15 13:250.26
Bromomethane ug/L ND 10.0 12/19/15 13:250.29
Carbon disulfide ug/L ND 100 12/19/15 13:251.2
Carbon tetrachloride ug/L ND 1.0 12/19/15 13:250.25
Chlorobenzene ug/L ND 3.0 12/19/15 13:250.23
Chloroethane ug/L ND 10.0 12/19/15 13:250.54
Chloroform ug/L ND 5.0 12/19/15 13:250.14
Chloromethane ug/L ND 1.0 12/19/15 13:250.11
Chloroprene ug/L ND 20.0 12/19/15 13:250.27
cis-1,2-Dichloroethene ug/L ND 5.0 12/19/15 13:250.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/19/15 13:250.13
Dibromochloromethane ug/L ND 3.0 12/19/15 13:250.21
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 47 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1633901
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395006
Matrix:Water
AnalyzedMDL
Dibromomethane ug/L ND 10.0 12/19/15 13:250.21
Dichlorodifluoromethane ug/L ND 5.0 12/19/15 13:250.21
Ethyl methacrylate ug/L ND 10.0 12/19/15 13:250.20
Ethylbenzene ug/L ND 1.0 12/19/15 13:250.30
Hexachloro-1,3-butadiene ug/L ND 10.0 12/19/15 13:250.71
Iodomethane ug/L ND 10.0 12/19/15 13:250.32
Isobutanol ug/L ND 100 12/19/15 13:2535.0
Methacrylonitrile ug/L ND 100 12/19/15 13:250.93
Methyl methacrylate ug/L ND 30.0 12/19/15 13:252.0
Methylene Chloride ug/L ND 1.0 12/19/15 13:250.97
Naphthalene ug/L ND 10.0 12/19/15 13:250.24
Propionitrile ug/L ND 150 12/19/15 13:253.6
Styrene ug/L ND 1.0 12/19/15 13:250.26
Tetrachloroethene ug/L ND 1.0 12/19/15 13:250.46
Tetrahydrofuran ug/L ND 10.0 12/19/15 13:253.1
Toluene ug/L ND 1.0 12/19/15 13:250.26
trans-1,2-Dichloroethene ug/L ND 5.0 12/19/15 13:250.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/19/15 13:250.26
trans-1,4-Dichloro-2-butene ug/L ND 100 12/19/15 13:251.0
Trichloroethene ug/L ND 1.0 12/19/15 13:250.47
Trichlorofluoromethane ug/L ND 1.0 12/19/15 13:250.20
Vinyl acetate ug/L ND 50.0 12/19/15 13:250.35
Vinyl chloride ug/L ND 1.0 12/19/15 13:250.62
Xylene (Total)ug/L ND 5.0 12/19/15 13:250.66
1,2-Dichloroethane-d4 (S)%102 70-130 12/19/15 13:25
4-Bromofluorobenzene (S)%102 70-130 12/19/15 13:25
Toluene-d8 (S)%110 70-130 12/19/15 13:25
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1633902LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 52.650 105 80-125
1,1,1-Trichloroethane ug/L 55.250 110 71-129
1,1,2,2-Tetrachloroethane ug/L 52.850 106 79-124
1,1,2-Trichloroethane ug/L 53.550 107 85-125
1,1-Dichloroethane ug/L 49.350 99 73-126
1,1-Dichloroethene ug/L 54.250 108 66-135
1,1-Dichloropropene ug/L 53.550 107 74-135
1,2,3-Trichloropropane ug/L 50.950 102 75-130
1,2,4-Trichlorobenzene ug/L 49.850 100 75-134
1,2-Dibromo-3-chloropropane ug/L 50.950 102 71-133
1,2-Dibromoethane (EDB)ug/L 55.650 111 83-124
1,2-Dichlorobenzene ug/L 51.650 103 80-133
1,2-Dichloroethane ug/L 50.150 100 67-128
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 48 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1633902LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichloropropane ug/L 49.050 98 75-132
1,3-Dichlorobenzene ug/L 51.450 103 77-130
1,3-Dichloropropane ug/L 52.550 105 76-131
1,4-Dichlorobenzene ug/L 53.050 106 78-130
2,2-Dichloropropane ug/L 54.150 108 40-160
2-Butanone (MEK)ug/L 109100 109 61-144
2-Hexanone ug/L 104100 104 68-143
4-Methyl-2-pentanone (MIBK)ug/L 99.9J100 100 72-135
Acetone ug/L 107100 107 48-146
Acetonitrile ug/L 546500 109 62-150
Acrolein ug/L 305250 122 24-160
Acrylonitrile ug/L 263250 105 40-160
Allyl chloride ug/L 53.750 107 66-137
Benzene ug/L 52.150 104 80-125
Bromochloromethane ug/L 59.350 119 71-125
Bromodichloromethane ug/L 54.550 109 78-124
Bromoform ug/L 44.150 88 71-128
Bromomethane ug/L 45.450 91 40-160
Carbon disulfide ug/L 55.0J50 110 50-160
Carbon tetrachloride ug/L 53.350 107 69-131
Chlorobenzene ug/L 53.950 108 81-122
Chloroethane ug/L 48.350 97 39-148
Chloroform ug/L 55.350 111 73-127
Chloromethane ug/L 55.950 112 44-146
Chloroprene ug/L 59.150 118 75-145
cis-1,2-Dichloroethene ug/L 51.550 103 74-124
cis-1,3-Dichloropropene ug/L 56.550 113 72-132
Dibromochloromethane ug/L 54.550 109 78-125
Dibromomethane ug/L 53.250 106 82-120
Dichlorodifluoromethane ug/L 46.650 93 34-157
Ethyl methacrylate ug/L 47.950 96 82-121
Ethylbenzene ug/L 52.950 106 79-121
Hexachloro-1,3-butadiene ug/L 61.650 123 72-131
Iodomethane ug/L 88.7100 89 39-154
Isobutanol ug/L 9921000 99 34-160
Methacrylonitrile ug/L 558500 112 74-134
Methyl methacrylate ug/L 47.850 96 84-124
Methylene Chloride ug/L 59.250 118 64-133
Naphthalene ug/L 49.150 98 73-133
Propionitrile ug/L 535500 107 73-140
Styrene ug/L 53.250 106 84-126
Tetrachloroethene ug/L 53.650 107 78-122
Tetrahydrofuran ug/L 549500 110 69-148
Toluene ug/L 49.950 100 80-121
trans-1,2-Dichloroethene ug/L 51.550 103 71-127
trans-1,3-Dichloropropene ug/L 52.150 104 69-141
trans-1,4-Dichloro-2-butene ug/L 54.8J50 110 40-160
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 49 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1633902LABORATORY CONTROL SAMPLE:
LCSSpike
Trichloroethene ug/L 55.350 111 78-122
Trichlorofluoromethane ug/L 50.850 102 53-137
Vinyl acetate ug/L 104100 104 40-160
Vinyl chloride ug/L 55.350 111 58-137
Xylene (Total)ug/L 158150 106 81-126
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%104 70-130
Toluene-d8 (S)%96 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1633904MATRIX SPIKE SAMPLE:
MSSpike
Result
92279300003
1,1,1,2-Tetrachloroethane ug/L 15.420 77 70-130ND
1,1,1-Trichloroethane ug/L 19.820 99 70-130ND
1,1,2,2-Tetrachloroethane ug/L 16.820 84 70-130ND
1,1,2-Trichloroethane ug/L 16.820 84 70-130ND
1,1-Dichloroethane ug/L 19.420 97 70-130ND
1,1-Dichloroethene ug/L 18.920 94 70-166ND
1,1-Dichloropropene ug/L 18.720 94 70-130ND
1,2,3-Trichloropropane ug/L 17.620 88 70-130ND
1,2,4-Trichlorobenzene ug/L 15.620 78 70-130ND
1,2-Dibromo-3-chloropropane ug/L 15.820 79 70-130ND
1,2-Dibromoethane (EDB)ug/L 16.520 82 70-130ND
1,2-Dichlorobenzene ug/L 17.620 88 70-130ND
1,2-Dichloroethane ug/L 17.420 87 70-130ND
1,2-Dichloropropane ug/L 17.620 88 70-130ND
1,3-Dichlorobenzene ug/L 17.520 88 70-130ND
1,3-Dichloropropane ug/L 16.020 80 70-130ND
1,4-Dichlorobenzene ug/L 17.220 86 70-130ND
2,2-Dichloropropane ug/L 17.120 86 70-130ND
2-Butanone (MEK)ug/L 36.4J40 91 70-130ND
2-Hexanone ug/L 33.6J40 84 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 36.3J40 91 70-130ND
Acetone ug/L 39.6J40 99 70-130ND
Acetonitrile ug/L 214200 107 70-130ND
Acrolein ug/L 97.8100 96 70-1301.9J
Acrylonitrile ug/L 95.0J100 95 70-130ND
Allyl chloride ug/L 19.320 97 70-130ND
Benzene ug/L 18.620 93 70-148ND
Bromochloromethane ug/L 22.420 112 70-130ND
Bromodichloromethane ug/L 17.520 87 70-130ND
Bromoform ug/L 15.420 77 70-130ND
Bromomethane ug/L 16.920 84 70-130ND
Carbon disulfide ug/L 19.8J20 99 70-130ND
Carbon tetrachloride ug/L 18.320 91 70-130ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
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Huntersville, NC 28078
[phone]
Page 50 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1633904MATRIX SPIKE SAMPLE:
MSSpike
Result
92279300003
Chlorobenzene ug/L 18.120 90 70-146ND
Chloroethane ug/L 16.220 81 70-130ND
Chloroform ug/L 19.820 99 70-130ND
Chloromethane ug/L 23.020 115 70-130ND
Chloroprene ug/L 19.6J20 98 70-130ND
cis-1,2-Dichloroethene ug/L 18.720 94 70-130ND
cis-1,3-Dichloropropene ug/L 17.420 87 70-130ND
Dibromochloromethane ug/L 15.320 77 70-130ND
Dibromomethane ug/L 19.720 98 70-130ND
Dichlorodifluoromethane ug/L 17.520 88 70-130ND
Ethyl methacrylate ug/L 16.820 84 70-130ND
Ethylbenzene ug/L 17.520 87 70-130ND
Hexachloro-1,3-butadiene ug/L 23.520 117 70-130ND
Iodomethane ug/L 28.340 71 70-130ND
Isobutanol ug/L 327400 82 70-130ND
Methacrylonitrile ug/L 186200 93 70-130ND
Methyl methacrylate ug/L 17.1J20 86 70-130ND
Methylene Chloride ug/L 20.820 104 70-130ND
Naphthalene ug/L 15.220 76 70-130ND
Propionitrile ug/L 187200 94 70-130ND
Styrene ug/L 17.220 86 70-130ND
Tetrachloroethene ug/L 16.920 85 70-130ND
Tetrahydrofuran ug/L 186200 93 70-130ND
Toluene ug/L 19.220 96 70-155ND
trans-1,2-Dichloroethene ug/L 20.020 100 70-130ND
trans-1,3-Dichloropropene ug/L 15.620 78 70-130ND
trans-1,4-Dichloro-2-butene ug/L 16.1J20 81 70-130ND
Trichloroethene ug/L 18.120 91 69-151ND
Trichlorofluoromethane ug/L 17.420 87 70-130ND
Vinyl acetate ug/L 28.9J40 72 70-130ND
Vinyl chloride ug/L 20.320 102 70-130ND
1,2-Dichloroethane-d4 (S)%109 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%107 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92279300002
1633903SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,1-Dichloropropene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 51 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92279300002
1633903SAMPLE DUPLICATE:
1,2,3-Trichloropropane ug/L ND 30ND
1,2,4-Trichlorobenzene ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichlorobenzene ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2,2-Dichloropropane ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acetonitrile ug/L ND 30ND
Acrolein ug/L 1.9J 303.1J
Acrylonitrile ug/L ND 30ND
Allyl chloride ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
Chloroprene ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Dichlorodifluoromethane ug/L ND 30ND
Ethyl methacrylate ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Hexachloro-1,3-butadiene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Isobutanol ug/L ND 30ND
Methacrylonitrile ug/L ND 30ND
Methyl methacrylate ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Naphthalene ug/L ND 30ND
Propionitrile ug/L ND 30ND
Styrene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 52 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92279300002
1633903SAMPLE DUPLICATE:
Tetrachloroethene ug/L ND 30ND
Tetrahydrofuran ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%98 395
4-Bromofluorobenzene (S)%106 1104
Toluene-d8 (S)%109 2111
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 53 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34820
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92279395005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1634031
Associated Lab Samples:92279395005
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 12/20/15 18:490.33
1,1,1-Trichloroethane ug/L ND 1.0 12/20/15 18:490.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 12/20/15 18:490.40
1,1,2-Trichloroethane ug/L ND 1.0 12/20/15 18:490.29
1,1-Dichloroethane ug/L ND 5.0 12/20/15 18:490.32
1,1-Dichloroethene ug/L ND 5.0 12/20/15 18:490.56
1,1-Dichloropropene ug/L ND 5.0 12/20/15 18:490.49
1,2,3-Trichloropropane ug/L ND 1.0 12/20/15 18:490.41
1,2,4-Trichlorobenzene ug/L ND 10.0 12/20/15 18:490.35
1,2-Dibromo-3-chloropropane ug/L ND 13.0 12/20/15 18:492.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/20/15 18:490.27
1,2-Dichlorobenzene ug/L ND 5.0 12/20/15 18:490.30
1,2-Dichloroethane ug/L ND 1.0 12/20/15 18:490.24
1,2-Dichloropropane ug/L ND 1.0 12/20/15 18:490.27
1,3-Dichlorobenzene ug/L ND 5.0 12/20/15 18:490.24
1,3-Dichloropropane ug/L ND 1.0 12/20/15 18:490.28
1,4-Dichlorobenzene ug/L ND 1.0 12/20/15 18:490.33
2,2-Dichloropropane ug/L ND 15.0 12/20/15 18:490.13
2-Butanone (MEK)ug/L ND 100 12/20/15 18:490.96
2-Hexanone ug/L ND 50.0 12/20/15 18:490.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 12/20/15 18:490.33
Acetone ug/L ND 100 12/20/15 18:4910.0
Acetonitrile ug/L ND 55.0 12/20/15 18:492.2
Acrolein ug/L ND 53.0 12/20/15 18:491.6
Acrylonitrile ug/L ND 200 12/20/15 18:491.9
Allyl chloride ug/L ND 10.0 12/20/15 18:491.5
Benzene ug/L ND 1.0 12/20/15 18:490.25
Bromochloromethane ug/L ND 3.0 12/20/15 18:490.17
Bromodichloromethane ug/L ND 1.0 12/20/15 18:490.18
Bromoform ug/L ND 3.0 12/20/15 18:490.26
Bromomethane ug/L ND 10.0 12/20/15 18:490.29
Carbon disulfide ug/L ND 100 12/20/15 18:491.2
Carbon tetrachloride ug/L ND 1.0 12/20/15 18:490.25
Chlorobenzene ug/L ND 3.0 12/20/15 18:490.23
Chloroethane ug/L ND 10.0 12/20/15 18:490.54
Chloroform ug/L ND 5.0 12/20/15 18:490.14
Chloromethane ug/L ND 1.0 12/20/15 18:490.11
Chloroprene ug/L ND 20.0 12/20/15 18:490.27
cis-1,2-Dichloroethene ug/L ND 5.0 12/20/15 18:490.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/20/15 18:490.13
Dibromochloromethane ug/L ND 3.0 12/20/15 18:490.21
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 54 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1634031
Associated Lab Samples:92279395005
Matrix:Water
AnalyzedMDL
Dibromomethane ug/L ND 10.0 12/20/15 18:490.21
Dichlorodifluoromethane ug/L ND 5.0 12/20/15 18:490.21
Ethyl methacrylate ug/L ND 10.0 12/20/15 18:490.20
Ethylbenzene ug/L ND 1.0 12/20/15 18:490.30
Hexachloro-1,3-butadiene ug/L ND 10.0 12/20/15 18:490.71
Iodomethane ug/L ND 10.0 12/20/15 18:490.32
Isobutanol ug/L ND 100 12/20/15 18:4935.0
Methacrylonitrile ug/L ND 100 12/20/15 18:490.93
Methyl methacrylate ug/L ND 30.0 12/20/15 18:492.0
Methylene Chloride ug/L ND 1.0 12/20/15 18:490.97
Naphthalene ug/L ND 10.0 12/20/15 18:490.24
Propionitrile ug/L ND 150 12/20/15 18:493.6
Styrene ug/L ND 1.0 12/20/15 18:490.26
Tetrachloroethene ug/L ND 1.0 12/20/15 18:490.46
Tetrahydrofuran ug/L ND 10.0 12/20/15 18:493.1
Toluene ug/L ND 1.0 12/20/15 18:490.26
trans-1,2-Dichloroethene ug/L ND 5.0 12/20/15 18:490.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/20/15 18:490.26
trans-1,4-Dichloro-2-butene ug/L ND 100 12/20/15 18:491.0
Trichloroethene ug/L ND 1.0 12/20/15 18:490.47
Trichlorofluoromethane ug/L ND 1.0 12/20/15 18:490.20
Vinyl acetate ug/L ND 50.0 12/20/15 18:490.35
Vinyl chloride ug/L ND 1.0 12/20/15 18:490.62
Xylene (Total)ug/L ND 5.0 12/20/15 18:490.66
1,2-Dichloroethane-d4 (S)%92 70-130 12/20/15 18:49
4-Bromofluorobenzene (S)%102 70-130 12/20/15 18:49
Toluene-d8 (S)%111 70-130 12/20/15 18:49
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1634032LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.050 100 80-125
1,1,1-Trichloroethane ug/L 52.550 105 71-129
1,1,2,2-Tetrachloroethane ug/L 50.050 100 79-124
1,1,2-Trichloroethane ug/L 52.350 105 85-125
1,1-Dichloroethane ug/L 47.950 96 73-126
1,1-Dichloroethene ug/L 48.150 96 66-135
1,1-Dichloropropene ug/L 50.950 102 74-135
1,2,3-Trichloropropane ug/L 51.150 102 75-130
1,2,4-Trichlorobenzene ug/L 46.250 92 75-134
1,2-Dibromo-3-chloropropane ug/L 47.950 96 71-133
1,2-Dibromoethane (EDB)ug/L 53.950 108 83-124
1,2-Dichlorobenzene ug/L 47.150 94 80-133
1,2-Dichloroethane ug/L 45.250 90 67-128
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 55 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1634032LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichloropropane ug/L 48.250 96 75-132
1,3-Dichlorobenzene ug/L 48.250 96 77-130
1,3-Dichloropropane ug/L 51.550 103 76-131
1,4-Dichlorobenzene ug/L 49.650 99 78-130
2,2-Dichloropropane ug/L 48.650 97 40-160
2-Butanone (MEK)ug/L 109100 109 61-144
2-Hexanone ug/L 99.3100 99 68-143
4-Methyl-2-pentanone (MIBK)ug/L 101100 101 72-135
Acetone ug/L 104100 104 48-146
Acetonitrile ug/L 549500 110 62-150
Acrolein ug/L 305250 122 24-160
Acrylonitrile ug/L 260250 104 40-160
Allyl chloride ug/L 52.450 105 66-137
Benzene ug/L 53.550 107 80-125
Bromochloromethane ug/L 53.350 107 71-125
Bromodichloromethane ug/L 49.450 99 78-124
Bromoform ug/L 40.350 81 71-128
Bromomethane ug/L 40.050 80 40-160
Carbon disulfide ug/L 50.5J50 101 50-160
Carbon tetrachloride ug/L 50.350 101 69-131
Chlorobenzene ug/L 49.350 99 81-122
Chloroethane ug/L 43.650 87 39-148
Chloroform ug/L 49.850 100 73-127
Chloromethane ug/L 50.050 100 44-146
Chloroprene ug/L 55.750 111 75-145
cis-1,2-Dichloroethene ug/L 48.350 97 74-124
cis-1,3-Dichloropropene ug/L 52.650 105 72-132
Dibromochloromethane ug/L 51.250 102 78-125
Dibromomethane ug/L 52.250 104 82-120
Dichlorodifluoromethane ug/L 42.450 85 34-157
Ethyl methacrylate ug/L 45.750 91 82-121
Ethylbenzene ug/L 48.950 98 79-121
Hexachloro-1,3-butadiene ug/L 54.550 109 72-131
Iodomethane ug/L 78.3100 78 39-154
Isobutanol ug/L 9731000 97 34-160
Methacrylonitrile ug/L 541500 108 74-134
Methyl methacrylate ug/L 45.850 92 84-124
Methylene Chloride ug/L 58.350 117 64-133
Naphthalene ug/L 44.750 89 73-133
Propionitrile ug/L 525500 105 73-140
Styrene ug/L 49.450 99 84-126
Tetrachloroethene ug/L 48.950 98 78-122
Tetrahydrofuran ug/L 540500 108 69-148
Toluene ug/L 48.650 97 80-121
trans-1,2-Dichloroethene ug/L 50.150 100 71-127
trans-1,3-Dichloropropene ug/L 49.850 100 69-141
trans-1,4-Dichloro-2-butene ug/L 46.0J50 92 40-160
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 56 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1634032LABORATORY CONTROL SAMPLE:
LCSSpike
Trichloroethene ug/L 52.950 106 78-122
Trichlorofluoromethane ug/L 46.350 93 53-137
Vinyl acetate ug/L 101100 101 40-160
Vinyl chloride ug/L 50.050 100 58-137
Xylene (Total)ug/L 144150 96 81-126
1,2-Dichloroethane-d4 (S)%102 70-130
4-Bromofluorobenzene (S)%105 70-130
Toluene-d8 (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 57 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/39664
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1627217
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005
Matrix:Water
AnalyzedMDL
4,4'-DDD ug/L ND 0.10 12/14/15 22:310.050
4,4'-DDE ug/L ND 0.10 12/14/15 22:310.050
4,4'-DDT ug/L ND 0.10 12/14/15 22:310.050
Aldrin ug/L ND 0.050 12/14/15 22:310.050
alpha-BHC ug/L ND 0.050 12/14/15 22:310.050
beta-BHC ug/L ND 0.050 12/14/15 22:310.050
Chlordane (Technical)ug/L ND 0.50 12/14/15 22:310.20
delta-BHC ug/L ND 0.050 12/14/15 22:310.050
Dieldrin ug/L ND 0.075 12/14/15 22:310.050
Endosulfan I ug/L ND 0.10 12/14/15 22:310.050
Endosulfan II ug/L ND 0.10 12/14/15 22:310.050
Endosulfan sulfate ug/L ND 0.10 12/14/15 22:310.050
Endrin ug/L ND 0.10 12/14/15 22:310.050
Endrin aldehyde ug/L ND 0.10 12/14/15 22:310.050
gamma-BHC (Lindane)ug/L ND 0.050 12/14/15 22:310.050
Heptachlor ug/L ND 0.050 12/14/15 22:310.050
Heptachlor epoxide ug/L ND 0.075 12/14/15 22:310.050
Methoxychlor ug/L ND 1.0 12/14/15 22:310.15
Toxaphene ug/L ND 1.5 12/14/15 22:310.20
Decachlorobiphenyl (S)%47 20-130 12/14/15 22:31
Tetrachloro-m-xylene (S)%62 20-130 12/14/15 22:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1627218LABORATORY CONTROL SAMPLE:
LCSSpike
4,4'-DDD ug/L 0.20.25 81 20-150
4,4'-DDE ug/L 0.19.25 79 20-150
4,4'-DDT ug/L 0.21.25 84 20-150
Aldrin ug/L 0.17.25 71 20-150
alpha-BHC ug/L 0.18.25 74 20-150
beta-BHC ug/L 0.20.25 79 20-150
delta-BHC ug/L 0.20.25 83 20-150
Dieldrin ug/L 0.19.25 75 20-150
Endosulfan I ug/L 0.20.25 79 20-150
Endosulfan II ug/L 0.20.25 82 20-150
Endosulfan sulfate ug/L 0.21.25 84 20-150
Endrin ug/L 0.21.25 85 20-150
Endrin aldehyde ug/L 0.19.25 76 20-150
gamma-BHC (Lindane)ug/L 0.19.25 77 20-150
Heptachlor ug/L 0.17.25 69 20-150
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 58 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1627218LABORATORY CONTROL SAMPLE:
LCSSpike
Heptachlor epoxide ug/L 0.19.25 76 20-150
Methoxychlor ug/L 0.62J.74 84 20-150
Decachlorobiphenyl (S)%47 20-130
Tetrachloro-m-xylene (S)%72 20-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1627219MATRIX SPIKE SAMPLE:
MSSpike
Result
92279395001
4,4'-DDD ug/L 0.22.25 87 20-150ND
4,4'-DDE ug/L 0.20.25 82 20-150ND
4,4'-DDT ug/L 0.24.25 96 20-150ND
Aldrin ug/L 0.16.25 66 20-150ND
alpha-BHC ug/L 0.18.25 72 20-150ND
beta-BHC ug/L 0.22.25 88 20-150ND
delta-BHC ug/L 0.19.25 75 20-150ND
Dieldrin ug/L 0.20.25 82 20-150ND
Endosulfan I ug/L 0.19.25 78 20-150ND
Endosulfan II ug/L 0.23.25 91 20-150ND
Endosulfan sulfate ug/L 0.24.25 96 20-150ND
Endrin ug/L 0.23.25 91 20-150ND
Endrin aldehyde ug/L 0.70 M1.25 282 20-150ND
gamma-BHC (Lindane)ug/L 0.17.25 67 20-150ND
Heptachlor ug/L 0.16.25 63 20-150ND
Heptachlor epoxide ug/L 0.23.25 92 20-150ND
Methoxychlor ug/L 0.70J.74 94 20-150ND
Decachlorobiphenyl (S)%67 20-130
Tetrachloro-m-xylene (S)%63 20-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
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Page 59 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/39666
EPA 3510
EPA 8082
8082 GCS PCB
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1627232
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005
Matrix:Water
AnalyzedMDL
PCB-1016 (Aroclor 1016)ug/L ND 0.50 12/14/15 21:300.50
PCB-1221 (Aroclor 1221)ug/L ND 0.50 12/14/15 21:300.50
PCB-1232 (Aroclor 1232)ug/L ND 0.50 12/14/15 21:300.50
PCB-1242 (Aroclor 1242)ug/L ND 0.50 12/14/15 21:300.50
PCB-1248 (Aroclor 1248)ug/L ND 0.50 12/14/15 21:300.50
PCB-1254 (Aroclor 1254)ug/L ND 0.50 12/14/15 21:300.50
PCB-1260 (Aroclor 1260)ug/L ND 0.50 12/14/15 21:300.50
Decachlorobiphenyl (S)%58 10-132 12/14/15 21:30
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1627233LABORATORY CONTROL SAMPLE:
LCSSpike
PCB-1016 (Aroclor 1016)ug/L 3.75 75 50-150
PCB-1260 (Aroclor 1260)ug/L 3.85 76 50-150
Decachlorobiphenyl (S)%59 10-132
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1627235MATRIX SPIKE SAMPLE:
MSSpike
Result
92279395003
PCB-1016 (Aroclor 1016)ug/L 3.65 71 50-150ND
PCB-1260 (Aroclor 1260)ug/L 3.25 63 50-150ND
Decachlorobiphenyl (S)%64 10-132
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 60 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/25723
EPA 8151
EPA 8151
8151A GCS Herbicides
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1420527
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005
Matrix:Water
AnalyzedMDL
2,4,5-T ug/L ND 0.19 12/17/15 17:070.042
2,4,5-TP (Silvex)ug/L ND 0.19 12/17/15 17:070.049
2,4-D ug/L ND 0.94 12/17/15 17:070.22
Dinoseb ug/L ND 0.19 12/17/15 17:070.057
2,4-DCAA (S)%53 36-130 12/17/15 17:07
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1420528LABORATORY CONTROL SAMPLE:
LCSSpike
2,4,5-T ug/L 0.791.2 66 40-130
2,4,5-TP (Silvex)ug/L 1.11.2 94 58-130
2,4-D ug/L 3.76 62 42-134
Dinoseb ug/L 0.841.2 70 10-157
2,4-DCAA (S)%77 36-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1424270MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279201003
1424271
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2,4,5-T ug/L 1.2 88 40-13062 35 401.2ND 1.1 0.74
2,4,5-TP (Silvex)ug/L 1.2 104 58-13069 40 401.2ND 1.2 0.83
2,4-D ug/L 6 88 42-13459 39 406ND5.3 3.6
Dinoseb ug/L R11.2 73 10-15748 41 401.2ND 0.88 0.58
2,4-DCAA (S)%81 36-13058 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 61 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/39746
EPA 3510
EPA 8270
8270 Water MSSV
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1629825
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005
Matrix:Water
AnalyzedMDL
1,2,4,5-Tetrachlorobenzene ug/L ND 10.0 12/21/15 16:141.7
1,3,5-Trinitrobenzene ug/L ND 10.0 12/21/15 16:141.1
1,3-Dinitrobenzene ug/L ND 20.0 12/21/15 16:141.5
1,4-Naphthoquinone ug/L ND 10.0 12/21/15 16:141.8
1-Naphthalenamine ug/L ND 10.0 12/21/15 16:140.96
2,3,4,6-Tetrachlorophenol ug/L ND 10.0 12/21/15 16:142.3
2,4,5-Trichlorophenol ug/L ND 10.0 12/21/15 16:142.2
2,4,6-Trichlorophenol ug/L ND 10.0 12/21/15 16:141.9
2,4-Dichlorophenol ug/L ND 10.0 12/21/15 16:141.7
2,4-Dimethylphenol ug/L ND 10.0 12/21/15 16:142.2
2,4-Dinitrophenol ug/L ND 50.0 12/21/15 16:146.5
2,4-Dinitrotoluene ug/L ND 10.0 12/21/15 16:141.2
2,6-Dichlorophenol ug/L ND 10.0 12/21/15 16:141.8
2,6-Dinitrotoluene ug/L ND 10.0 12/21/15 16:141.7
2-Acetylaminofluorene ug/L ND 20.0 12/21/15 16:140.84
2-Chloronaphthalene ug/L ND 10.0 12/21/15 16:142.2
2-Chlorophenol ug/L ND 10.0 12/21/15 16:141.5
2-Methylnaphthalene ug/L ND 10.0 12/21/15 16:140.28
2-Methylphenol(o-Cresol)ug/L ND 10.0 12/21/15 16:141.7
2-Naphthalenamine ug/L ND 10.0 12/21/15 16:140.98
2-Nitroaniline ug/L ND 50.0 12/21/15 16:142.8
2-Nitrophenol ug/L ND 10.0 12/21/15 16:141.7
3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 12/21/15 16:141.7
3,3'-Dichlorobenzidine ug/L ND 20.0 12/21/15 16:141.4
3,3'-Dimethylbenzidine ug/L ND 10.0 12/21/15 16:142.1
3-Methylcholanthrene ug/L ND 10.0 12/21/15 16:140.82
3-Nitroaniline ug/L ND 50.0 12/21/15 16:142.4
4,6-Dinitro-2-methylphenol ug/L ND 50.0 12/21/15 16:141.7
4-Aminobiphenyl ug/L ND 20.0 12/21/15 16:140.92
4-Bromophenylphenyl ether ug/L ND 10.0 12/21/15 16:141.3
4-Chloro-3-methylphenol ug/L ND 20.0 12/21/15 16:144.2
4-Chloroaniline ug/L ND 20.0 12/21/15 16:143.4
4-Chlorophenylphenyl ether ug/L ND 10.0 12/21/15 16:142.1
4-Nitroaniline ug/L ND 20.0 12/21/15 16:142.5
4-Nitrophenol ug/L ND 50.0 12/21/15 16:145.8
5-Nitro-o-toluidine ug/L ND 10.0 12/21/15 16:141.2
7,12-Dimethylbenz(a)anthracene ug/L ND 10.0 12/21/15 16:140.77
Acenaphthene ug/L ND 10.0 12/21/15 16:140.25
Acenaphthylene ug/L ND 10.0 12/21/15 16:140.21
Acetophenone ug/L ND 10.0 12/21/15 16:142.0
Anthracene ug/L ND 10.0 12/21/15 16:140.14
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 62 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1629825
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005
Matrix:Water
AnalyzedMDL
Benzo(a)anthracene ug/L ND 10.0 12/21/15 16:140.33
Benzo(a)pyrene ug/L ND 10.0 12/21/15 16:140.30
Benzo(b)fluoranthene ug/L ND 10.0 12/21/15 16:140.28
Benzo(g,h,i)perylene ug/L ND 10.0 12/21/15 16:140.38
Benzo(k)fluoranthene ug/L ND 10.0 12/21/15 16:140.43
Benzyl alcohol ug/L ND 20.0 12/21/15 16:143.4
bis(2-Chloroethoxy)methane ug/L ND 10.0 12/21/15 16:141.7
bis(2-Chloroethyl) ether ug/L ND 10.0 12/21/15 16:141.5
bis(2-Chloroisopropyl) ether ug/L ND 10.0 12/21/15 16:141.6
bis(2-Ethylhexyl)phthalate ug/L ND 15.0 12/21/15 16:140.85
Butylbenzylphthalate ug/L ND 10.0 12/21/15 16:140.75
Chlorobenzilate ug/L ND 10.0 12/21/15 16:140.72
Chrysene ug/L ND 10.0 12/21/15 16:140.21
Di-n-butylphthalate ug/L ND 10.0 12/21/15 16:141.1
Di-n-octylphthalate ug/L ND 10.0 12/21/15 16:140.86
Diallate ug/L ND 10.0 12/21/15 16:141.3
Dibenz(a,h)anthracene ug/L ND 10.0 12/21/15 16:140.55
Dibenzofuran ug/L ND 10.0 12/21/15 16:141.8
Diethylphthalate ug/L ND 6000 12/21/15 16:141.3
Dimethoate ug/L ND 20.0 12/21/15 16:140.92
Dimethylphthalate ug/L ND 10.0 12/21/15 16:141.5
Diphenylamine ug/L ND 10.0 12/21/15 16:141.3
Disulfoton ug/L ND 10.0 12/21/15 16:141.4
Ethyl methanesulfonate ug/L ND 20.0 12/21/15 16:141.8
Famphur ug/L ND 20.0 12/21/15 16:141.7
Fluoranthene ug/L ND 10.0 12/21/15 16:140.21
Fluorene ug/L ND 10.0 12/21/15 16:140.21
Hexachlorobenzene ug/L ND 10.0 12/21/15 16:141.1
Hexachlorocyclopentadiene ug/L ND 10.0 12/21/15 16:141.8
Hexachloroethane ug/L ND 10.0 12/21/15 16:141.5
Hexachloropropene ug/L ND 10.0 12/21/15 16:141.6
Indeno(1,2,3-cd)pyrene ug/L ND 10.0 12/21/15 16:140.29
Isodrin ug/L ND 20.0 12/21/15 16:142.0
Isophorone ug/L ND 10.0 12/21/15 16:141.8
Isosafrole ug/L ND 10.0 12/21/15 16:141.8
Kepone ug/L ND 20.0 12/21/15 16:143.1
Methapyrilene ug/L ND 100 12/21/15 16:142.7
Methyl methanesulfonate ug/L ND 10.0 12/21/15 16:141.3
Methyl parathion ug/L ND 10.0 12/21/15 16:141.1
N-Nitroso-di-n-butylamine ug/L ND 10.0 12/21/15 16:142.2
N-Nitroso-di-n-propylamine ug/L ND 10.0 12/21/15 16:142.1
N-Nitrosodiethylamine ug/L ND 20.0 12/21/15 16:141.8
N-Nitrosodimethylamine ug/L ND 10.0 12/21/15 16:141.3
N-Nitrosodiphenylamine ug/L ND 10.0 12/21/15 16:141.3
N-Nitrosomethylethylamine ug/L ND 10.0 12/21/15 16:141.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 63 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1629825
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005
Matrix:Water
AnalyzedMDL
N-Nitrosopiperidine ug/L ND 20.0 12/21/15 16:141.9
N-Nitrosopyrrolidine ug/L ND 10.0 12/21/15 16:142.5
Nitrobenzene ug/L ND 10.0 12/21/15 16:141.7
O,O,O-Triethylphosphorothioate ug/L ND 10.0 12/21/15 16:141.8
O-Toluidine ug/L ND 10.0 12/21/15 16:141.6
P-Dimethylaminoazobenzene ug/L ND 10.0 12/21/15 16:140.35
p-Phenylenediamine ug/L ND 10.0 12/21/15 16:140.96
Parathion (Ethyl parathion)ug/L ND 10.0 12/21/15 16:141.1
Pentachlorobenzene ug/L ND 10.0 12/21/15 16:142.0
Pentachloronitrobenzene ug/L ND 20.0 12/21/15 16:141.0
Pentachlorophenol ug/L ND 25.0 12/21/15 16:142.3
Phenacetin ug/L ND 20.0 12/21/15 16:140.97
Phenanthrene ug/L ND 10.0 12/21/15 16:140.22
Phenol ug/L ND 10.0 12/21/15 16:141.7
Phorate ug/L ND 10.0 12/21/15 16:141.1
Pronamide ug/L ND 10.0 12/21/15 16:140.97
Pyrene ug/L ND 10.0 12/21/15 16:140.19
Safrole ug/L ND 10.0 12/21/15 16:141.5
Thionazin ug/L ND 20.0 12/21/15 16:141.2
2,4,6-Tribromophenol (S)%94 27-110 12/21/15 16:14
2-Fluorobiphenyl (S)%73 27-110 12/21/15 16:14
2-Fluorophenol (S)%38 12-110 12/21/15 16:14
Nitrobenzene-d5 (S)%84 21-110 12/21/15 16:14
Phenol-d6 (S)%21 10-110 12/21/15 16:14
Terphenyl-d14 (S)%97 31-107 12/21/15 16:14
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1629826LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4,5-Tetrachlorobenzene ug/L 28.650 57 16-129
1,3,5-Trinitrobenzene ug/L 64.1 L05012855-125
1,3-Dinitrobenzene ug/L 42.850 86 30-122
1,4-Naphthoquinone ug/L 35.650 71 31-120
1-Naphthalenamine ug/L 31.150 62 37-126
2,3,4,6-Tetrachlorophenol ug/L 91.350 183 54-276
2,4,5-Trichlorophenol ug/L 34.750 69 43-113
2,4,6-Trichlorophenol ug/L 35.850 72 42-120
2,4-Dichlorophenol ug/L 51.450 103 30-120
2,4-Dimethylphenol ug/L 41.850 84 29-111
2,4-Dinitrophenol ug/L 263250 105 19-132
2,4-Dinitrotoluene ug/L 51.250 102 58-128
2,6-Dichlorophenol ug/L 45.750 91 54-128
2,6-Dinitrotoluene ug/L 41.450 83 54-129
2-Acetylaminofluorene ug/L 49.050 98 81-160
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 64 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1629826LABORATORY CONTROL SAMPLE:
LCSSpike
2-Chloronaphthalene ug/L 34.750 69 43-117
2-Chlorophenol ug/L 34.450 69 37-120
2-Methylnaphthalene ug/L 35.850 72 33-120
2-Methylphenol(o-Cresol)ug/L 21.850 44 31-120
2-Naphthalenamine ug/L 36.050 72 41-136
2-Nitroaniline ug/L 51.0100 51 48-121
2-Nitrophenol ug/L 48.250 96 25-116
3&4-Methylphenol(m&p Cresol)ug/L 51.250 102 23-120
3,3'-Dichlorobenzidine ug/L 89.4250 36 10-154
3,3'-Dimethylbenzidine ug/L 10.4100 10 10-157
3-Methylcholanthrene ug/L 42.250 84 65-130
3-Nitroaniline ug/L 95.2100 95 43-115
4,6-Dinitro-2-methylphenol ug/L 101100 101 44-124
4-Aminobiphenyl ug/L 33.050 66 21-125
4-Bromophenylphenyl ether ug/L 46.250 92 34-113
4-Chloro-3-methylphenol ug/L 80.9100 81 31-110
4-Chloroaniline ug/L 68.3100 68 20-120
4-Chlorophenylphenyl ether ug/L 32.550 65 34-116
4-Nitroaniline ug/L 73.8100 74 46-128
4-Nitrophenol ug/L 104250 42 11-120
5-Nitro-o-toluidine ug/L 44.350 89 78-160
7,12-Dimethylbenz(a)anthracene ug/L 47.350 95 47-124
Acenaphthene ug/L 43.650 87 48-114
Acenaphthylene ug/L 40.850 82 48-112
Acetophenone ug/L 27.950 56 24-120
Anthracene ug/L 48.450 97 57-118
Benzo(a)anthracene ug/L 49.550 99 56-121
Benzo(a)pyrene ug/L 46.850 94 55-127
Benzo(b)fluoranthene ug/L 42.450 85 53-128
Benzo(g,h,i)perylene ug/L 37.150 74 54-125
Benzo(k)fluoranthene ug/L 51.950 104 51-123
Benzyl alcohol ug/L 60.9100 61 27-120
bis(2-Chloroethoxy)methane ug/L 48.250 96 32-120
bis(2-Chloroethyl) ether ug/L 29.750 59 33-111
bis(2-Chloroisopropyl) ether ug/L 11.650 23 15-120
bis(2-Ethylhexyl)phthalate ug/L 58.750 117 50-145
Butylbenzylphthalate ug/L 58.250 116 54-138
Chlorobenzilate ug/L 55.950 112 65-132
Chrysene ug/L 48.950 98 58-127
Di-n-butylphthalate ug/L 59.550 119 56-125
Di-n-octylphthalate ug/L 52.250 104 50-134
Diallate ug/L 47.450 95 47-123
Dibenz(a,h)anthracene ug/L 36.950 74 53-129
Dibenzofuran ug/L 43.250 86 45-120
Diethylphthalate ug/L 41.6J50 83 53-120
Dimethoate ug/L 46.250 92 57-139
Dimethylphthalate ug/L 37.050 74 55-116
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 65 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1629826LABORATORY CONTROL SAMPLE:
LCSSpike
Diphenylamine ug/L 47.050 94 42-120
Disulfoton ug/L 45.550 91 49-156
Ethyl methanesulfonate ug/L 42.250 84 43-120
Famphur ug/L 73.0100 73 40-160
Fluoranthene ug/L 64.6 L05012957-125
Fluorene ug/L 36.650 73 53-118
Hexachlorobenzene ug/L 51.250 102 49-116
Hexachlorocyclopentadiene ug/L 16.950 34 26-158
Hexachloroethane ug/L 32.050 64 30-114
Hexachloropropene ug/L 30.850 62 13-137
Indeno(1,2,3-cd)pyrene ug/L 37.350 75 55-128
Isodrin ug/L 66.4 L05013368-129
Isophorone ug/L 42.050 84 31-118
Isosafrole ug/L 34.050 68 48-107
Kepone ug/L 39.2100 39 10-124
Methapyrilene ug/L 3.6J L050740-160
Methyl methanesulfonate ug/L 23.650 47 25-114
Methyl parathion ug/L 52.750 105 58-137
N-Nitroso-di-n-butylamine ug/L 32.550 65 36-115
N-Nitroso-di-n-propylamine ug/L 24.850 50 32-119
N-Nitrosodiethylamine ug/L 40.350 81 47-115
N-Nitrosodimethylamine ug/L 19.250 38 13-120
N-Nitrosodiphenylamine ug/L 47.050 94 43-120
N-Nitrosomethylethylamine ug/L 31.750 63 39-120
N-Nitrosopiperidine ug/L 55.250 110 43-113
N-Nitrosopyrrolidine ug/L 32.150 64 32-110
Nitrobenzene ug/L 40.750 81 33-110
O,O,O-Triethylphosphorothioate ug/L 49.450 99 51-127
O-Toluidine ug/L 31.050 62 27-120
P-Dimethylaminoazobenzene ug/L 27.3100 27 10-120
p-Phenylenediamine ug/L 50.450 101 72-143
Parathion (Ethyl parathion)ug/L 51.550 103 56-140
Pentachlorobenzene ug/L 42.650 85 30-137
Pentachloronitrobenzene ug/L 55.550 111 70-124
Pentachlorophenol ug/L 92.5250 37 10-137
Phenacetin ug/L 51.350 103 60-130
Phenanthrene ug/L 46.450 93 57-117
Phenol ug/L 15.250 30 10-120
Phorate ug/L 63.4 L05012755-126
Pronamide ug/L 60.450 121 75-124
Pyrene ug/L 56.250 112 55-122
Safrole ug/L 39.050 78 41-120
Thionazin ug/L 36.750 73 63-137
2,4,6-Tribromophenol (S)%S011527-110
2-Fluorobiphenyl (S)%62 27-110
2-Fluorophenol (S)%38 12-110
Nitrobenzene-d5 (S)%95 21-110
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 66 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1629826LABORATORY CONTROL SAMPLE:
LCSSpike
Phenol-d6 (S)%26 10-110
Terphenyl-d14 (S)%104 31-107
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1629827MATRIX SPIKE SAMPLE:
MSSpike
Result
92278963015
1,2,4,5-Tetrachlorobenzene ug/L 28.450 57 50-150ND
1,3,5-Trinitrobenzene ug/L 57.150 114 50-150ND
1,3-Dinitrobenzene ug/L 45.450 91 50-150ND
1,4-Naphthoquinone ug/L 35.950 72 50-150ND
1-Naphthalenamine ug/L 27.550 55 50-150ND
2,3,4,6-Tetrachlorophenol ug/L 66.050 132 50-150ND
2,4,5-Trichlorophenol ug/L 30.150 60 19-105ND
2,4,6-Trichlorophenol ug/L 30.750 61 13-108ND
2,4-Dichlorophenol ug/L 32.650 65 29-111ND
2,4-Dimethylphenol ug/L 28.050 56 21-103ND
2,4-Dinitrophenol ug/L 126250 50 10-109ND
2,4-Dinitrotoluene ug/L 42.850 86 27-104ND
2,6-Dichlorophenol ug/L 43.350 87 50-150ND
2,6-Dinitrotoluene ug/L 43.850 88 28-101ND
2-Acetylaminofluorene ug/L 45.350 91 50-150ND
2-Chloronaphthalene ug/L 32.950 66 14-102ND
2-Chlorophenol ug/L 37.050 74 16-110ND
2-Methylnaphthalene ug/L 29.850 60 13-110ND
2-Methylphenol(o-Cresol)ug/L 32.950 66 19-110ND
2-Naphthalenamine ug/L 29.750 59 50-150ND
2-Nitroaniline ug/L 44.5J100 45 26-103ND
2-Nitrophenol ug/L 32.250 64 20-110ND
3&4-Methylphenol(m&p Cresol)ug/L 67.1 M15013420-110ND
3,3'-Dichlorobenzidine ug/L 88.3250 35 25-112ND
3,3'-Dimethylbenzidine ug/L 58.1100 58 50-150ND
3-Methylcholanthrene ug/L 44.250 77 50-1505.4J
3-Nitroaniline ug/L 79.0100 79 29-110ND
4,6-Dinitro-2-methylphenol ug/L 84.3100 84 10-117ND
4-Aminobiphenyl ug/L 41.850 84 50-150ND
4-Bromophenylphenyl ether ug/L 40.650 81 20-105ND
4-Chloro-3-methylphenol ug/L 64.6100 65 22-110ND
4-Chloroaniline ug/L 71.4100 71 20-100ND
4-Chlorophenylphenyl ether ug/L 30.850 62 19-102ND
4-Nitroaniline ug/L 67.3100 67 29-110ND
4-Nitrophenol ug/L 62.9250 25 10-110ND
5-Nitro-o-toluidine ug/L 39.050 78 50-150ND
7,12-Dimethylbenz(a)anthracene ug/L 49.950 100 50-150ND
Acenaphthene ug/L 41.350 83 17-100ND
Acenaphthylene ug/L 41.350 83 21-100ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 67 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1629827MATRIX SPIKE SAMPLE:
MSSpike
Result
92278963015
Acetophenone ug/L 41.650 83 50-150ND
Anthracene ug/L 44.450 89 24-109ND
Benzo(a)anthracene ug/L 45.850 92 22-117ND
Benzo(a)pyrene ug/L 45.050 90 23-104ND
Benzo(b)fluoranthene ug/L 45.850 92 23-103ND
Benzo(g,h,i)perylene ug/L 38.750 77 18-111ND
Benzo(k)fluoranthene ug/L 53.250 106 22-113ND
Benzyl alcohol ug/L 64.2100 64 19-101ND
bis(2-Chloroethoxy)methane ug/L 24.750 49 22-110ND
bis(2-Chloroethyl) ether ug/L 29.850 60 16-110ND
bis(2-Chloroisopropyl) ether ug/L 23.650 47 14-110ND
bis(2-Ethylhexyl)phthalate ug/L 58.8 M15011823-102ND
Butylbenzylphthalate ug/L 60.3 M15012125-110ND
Chlorobenzilate ug/L 54.950 110 50-150ND
Chrysene ug/L 44.350 89 23-115ND
Di-n-butylphthalate ug/L 59.4 M15011926-110ND
Di-n-octylphthalate ug/L 42.450 85 22-110ND
Diallate ug/L 39.150 78 50-150ND
Dibenz(a,h)anthracene ug/L 45.750 91 21-112ND
Dibenzofuran ug/L 37.950 76 19-102ND
Diethylphthalate ug/L 34.5J50 69 29-110ND
Dimethoate ug/L 40.450 81 50-150ND
Dimethylphthalate ug/L 41.650 83 27-110ND
Diphenylamine ug/L 48.350 97 50-150ND
Disulfoton ug/L 43.150 86 50-150ND
Ethyl methanesulfonate ug/L 28.850 58 50-150ND
Famphur ug/L 35.6 M11003650-150ND
Fluoranthene ug/L 63.2 M05012623-112ND
Fluorene ug/L 33.350 67 22-104ND
Hexachlorobenzene ug/L 46.950 94 21-116ND
Hexachlorocyclopentadiene ug/L 16.550 33 10-110ND
Hexachloroethane ug/L 33.850 68 10-110ND
Hexachloropropene ug/L 32.050 64 50-150ND
Indeno(1,2,3-cd)pyrene ug/L 47.050 94 20-113ND
Isodrin ug/L 66.050 132 50-150ND
Isophorone ug/L 24.6 M1504950-150ND
Isosafrole ug/L 33.950 68 50-150ND
Kepone ug/L 44.0 M11004450-150ND
Methapyrilene ug/L 42.3J50 85 50-150ND
Methyl methanesulfonate ug/L 27.450 55 50-150ND
Methyl parathion ug/L 47.650 95 50-150ND
N-Nitroso-di-n-butylamine ug/L 24.0 M1504850-150ND
N-Nitroso-di-n-propylamine ug/L 38.950 78 21-105ND
N-Nitrosodiethylamine ug/L 30.550 61 50-150ND
N-Nitrosodimethylamine ug/L 19.550 39 10-110ND
N-Nitrosodiphenylamine ug/L 48.350 97 23-107ND
N-Nitrosomethylethylamine ug/L 31.850 64 50-150ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 68 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1629827MATRIX SPIKE SAMPLE:
MSSpike
Result
92278963015
N-Nitrosopiperidine ug/L 32.150 64 50-150ND
N-Nitrosopyrrolidine ug/L 46.750 93 50-150ND
Nitrobenzene ug/L 22.650 45 20-110ND
O,O,O-Triethylphosphorothioate ug/L 33.150 66 50-150ND
O-Toluidine ug/L 41.450 83 50-150ND
P-Dimethylaminoazobenzene ug/L 25.8 M11002650-150ND
p-Phenylenediamine ug/L 38.550 77 50-150ND
Parathion (Ethyl parathion)ug/L 63.650 127 50-150ND
Pentachlorobenzene ug/L 37.750 75 50-150ND
Pentachloronitrobenzene ug/L 50.850 102 50-150ND
Pentachlorophenol ug/L 80.7250 32 10-118ND
Phenacetin ug/L 47.450 95 50-150ND
Phenanthrene ug/L 43.150 86 24-106ND
Phenol ug/L 13.050 26 12-110ND
Phorate ug/L 56.550 113 50-150ND
Pronamide ug/L 55.750 111 50-150ND
Pyrene ug/L 53.050 106 24-114ND
Safrole ug/L 33.150 66 50-150ND
Thionazin ug/L 34.350 69 50-150ND
2,4,6-Tribromophenol (S)%99 27-110
2-Fluorobiphenyl (S)%57 27-110
2-Fluorophenol (S)%26 12-110
Nitrobenzene-d5 (S)%49 21-110
Phenol-d6 (S)%21 10-110
Terphenyl-d14 (S)%90 31-107
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278963016
1629828SAMPLE DUPLICATE:
1,2,4,5-Tetrachlorobenzene ug/L ND 30ND
1,3,5-Trinitrobenzene ug/L ND 30ND
1,3-Dinitrobenzene ug/L ND 30ND
1,4-Naphthoquinone ug/L ND 30ND
1-Naphthalenamine ug/L ND 30ND
2,3,4,6-Tetrachlorophenol ug/L ND 30ND
2,4,5-Trichlorophenol ug/L ND 30ND
2,4,6-Trichlorophenol ug/L ND 30ND
2,4-Dichlorophenol ug/L ND 30ND
2,4-Dimethylphenol ug/L ND 30ND
2,4-Dinitrophenol ug/L ND 30ND
2,4-Dinitrotoluene ug/L ND 30ND
2,6-Dichlorophenol ug/L ND 30ND
2,6-Dinitrotoluene ug/L ND 30ND
2-Acetylaminofluorene ug/L ND 30ND
2-Chloronaphthalene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 69 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278963016
1629828SAMPLE DUPLICATE:
2-Chlorophenol ug/L ND 30ND
2-Methylnaphthalene ug/L ND 30ND
2-Methylphenol(o-Cresol)ug/L ND 30ND
2-Naphthalenamine ug/L ND 30ND
2-Nitroaniline ug/L ND 30ND
2-Nitrophenol ug/L ND 30ND
3&4-Methylphenol(m&p Cresol)ug/L ND 30ND
3,3'-Dichlorobenzidine ug/L ND 30ND
3,3'-Dimethylbenzidine ug/L ND 30ND
3-Methylcholanthrene ug/L ND 30ND
3-Nitroaniline ug/L ND 30ND
4,6-Dinitro-2-methylphenol ug/L ND 30ND
4-Aminobiphenyl ug/L ND 30ND
4-Bromophenylphenyl ether ug/L ND 30ND
4-Chloro-3-methylphenol ug/L ND 30ND
4-Chloroaniline ug/L ND 30ND
4-Chlorophenylphenyl ether ug/L ND 30ND
4-Nitroaniline ug/L ND 30ND
4-Nitrophenol ug/L ND 30ND
5-Nitro-o-toluidine ug/L NDND
7,12-Dimethylbenz(a)anthracene ug/L ND 30ND
Acenaphthene ug/L ND 30ND
Acenaphthylene ug/L ND 30ND
Acetophenone ug/L ND 30ND
Anthracene ug/L ND 30ND
Benzo(a)anthracene ug/L ND 30ND
Benzo(a)pyrene ug/L ND 30ND
Benzo(b)fluoranthene ug/L ND 30ND
Benzo(g,h,i)perylene ug/L ND 30ND
Benzo(k)fluoranthene ug/L ND 30ND
Benzyl alcohol ug/L ND 30ND
bis(2-Chloroethoxy)methane ug/L ND 30ND
bis(2-Chloroethyl) ether ug/L ND 30ND
bis(2-Chloroisopropyl) ether ug/L ND 30ND
bis(2-Ethylhexyl)phthalate ug/L ND 30ND
Butylbenzylphthalate ug/L ND 30ND
Chlorobenzilate ug/L ND 30ND
Chrysene ug/L ND 30ND
Di-n-butylphthalate ug/L ND 30ND
Di-n-octylphthalate ug/L ND 30ND
Diallate ug/L ND 30ND
Dibenz(a,h)anthracene ug/L ND 30ND
Dibenzofuran ug/L ND 30ND
Diethylphthalate ug/L ND 30ND
Dimethoate ug/L ND 30ND
Dimethylphthalate ug/L ND 30ND
Diphenylamine ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 70 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278963016
1629828SAMPLE DUPLICATE:
Disulfoton ug/L ND 30ND
Ethyl methanesulfonate ug/L ND 30ND
Famphur ug/L ND 30ND
Fluoranthene ug/L ND 30ND
Fluorene ug/L ND 30ND
Hexachlorobenzene ug/L ND 30ND
Hexachlorocyclopentadiene ug/L ND 30ND
Hexachloroethane ug/L ND 30ND
Hexachloropropene ug/L ND 30ND
Indeno(1,2,3-cd)pyrene ug/L ND 30ND
Isodrin ug/L ND 30ND
Isophorone ug/L ND 30ND
Isosafrole ug/L ND 30ND
Kepone ug/L ND 30ND
Methapyrilene ug/L ND 30ND
Methyl methanesulfonate ug/L ND 30ND
Methyl parathion ug/L ND 30ND
N-Nitroso-di-n-butylamine ug/L ND 30ND
N-Nitroso-di-n-propylamine ug/L ND 30ND
N-Nitrosodiethylamine ug/L ND 30ND
N-Nitrosodimethylamine ug/L ND 30ND
N-Nitrosodiphenylamine ug/L ND 30ND
N-Nitrosomethylethylamine ug/L ND 30ND
N-Nitrosopiperidine ug/L ND 30ND
N-Nitrosopyrrolidine ug/L ND 30ND
Nitrobenzene ug/L ND 30ND
O,O,O-Triethylphosphorothioate ug/L ND 30ND
O-Toluidine ug/L ND 30ND
P-Dimethylaminoazobenzene ug/L ND 30ND
p-Phenylenediamine ug/L ND 30ND
Parathion (Ethyl parathion)ug/L ND 30ND
Pentachlorobenzene ug/L ND 30ND
Pentachloronitrobenzene ug/L ND 30ND
Pentachlorophenol ug/L ND 30ND
Phenacetin ug/L ND 30ND
Phenanthrene ug/L ND 30ND
Phenol ug/L ND 30ND
Phorate ug/L ND 30ND
Pronamide ug/L ND 30ND
Pyrene ug/L ND 30ND
Safrole ug/L ND 30ND
Thionazin ug/L ND 30ND
2,4,6-Tribromophenol (S)%64 1070
2-Fluorobiphenyl (S)%65 971
2-Fluorophenol (S)%31 1235
Nitrobenzene-d5 (S)%68 1277
Phenol-d6 (S)%18 1722
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 71 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278963016
1629828SAMPLE DUPLICATE:
Terphenyl-d14 (S)%83 778
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 72 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/41955
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005, 92279395006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1628049
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005, 92279395006
Matrix:Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 12/14/15 13:291000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1628050LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 4850050000 97 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1628051MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278963003
1628052
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L M1,R1500009980-12012 25 2550000150 mg/L 200000 156000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1628053MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278963011
1628054
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L M1500007480-120131 4 2550000596 mg/L 633000 662000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 73 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/41916
SM 2540C
SM 2540C
2540C Total Dissolved Solids
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005, 92279395006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1626642
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005, 92279395006
Matrix:Water
AnalyzedMDL
Total Dissolved Solids ug/L ND 25000 12/11/15 10:3925000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1626643LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids ug/L 246000250000 98 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92279178001
1626644SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 316000 4 5330 mg/L
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278979001
1626645SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 320000 D675299 mg/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 74 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/41914
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1626491
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005
Matrix:Water
AnalyzedMDL
Sulfide ug/L ND 1000 12/11/15 15:00100
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1626492LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide ug/L 504J500 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1626493MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279262001
1626494
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 91 90-11091 0 10500ND457J457J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1626495MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279262011
1626496
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 94 90-11094 0 10500ND470J470J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 75 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/25748
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005, 92279395006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1626618
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005, 92279395006
Matrix:Water
AnalyzedMDL
Sulfate ug/L ND 250000 12/11/15 14:061000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1626619LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 21000J20000 105 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1626620MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278963003
1626621
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 103 90-110103 1 102000010.1 mg/L 30600J 30800J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1626622MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279395006
1626623
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 102 90-110104 1 10200009260J29800J30100J
REPORT OF LABORATORY ANALYSIS
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Page 76 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/25837
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005, 92279395006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1631601
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005, 92279395006
Matrix:Water
AnalyzedMDL
Chloride ug/L ND 1000 12/17/15 16:33500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1631602LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 2060020000 103 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1631603MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279294028
1631604
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L 20000 103 90-110102 1 102000010.4 mg/L 30900 30700
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1631605MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279294038
1631606
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L 20000 104 90-110104 0 10200004.1 mg/L 25000 24900
REPORT OF LABORATORY ANALYSIS
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Page 77 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/25788
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1628959
Associated Lab Samples:92279395001, 92279395002, 92279395003, 92279395004, 92279395005
Matrix:Water
AnalyzedMDL
Cyanide ug/L ND 10.0 12/16/15 10:524.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1628960LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 90.6100 91 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1628961MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279059001
1628962
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 115 75-125116 1 10100ND120121
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1628963MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278760008
1628964
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 102 75-12598 3 101000.0096
mg/L 112 108
REPORT OF LABORATORY ANALYSIS
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Page 78 of 83
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Sample re-extracted outside method hold time. Results of re-analysis confirmed original analysis performed within hold
time.1g
The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.D6
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.L2
Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples. Results unaffected by high bias.L3
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
Surrogate recovery outside laboratory control limits.S0
Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated samples.
Results unaffected by high bias.S3
REPORT OF LABORATORY ANALYSIS
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Page 79 of 83
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92279395001 OEXT/39664 GCSV/235411203-MW10 EPA 3510 EPA 8081
92279395002 OEXT/39664 GCSV/235411203-MW11 EPA 3510 EPA 8081
92279395003 OEXT/39664 GCSV/235411203-MW12 EPA 3510 EPA 8081
92279395004 OEXT/39664 GCSV/235411203-MW13 EPA 3510 EPA 8081
92279395005 OEXT/39664 GCSV/235411203-MW16S EPA 3510 EPA 8081
92279395001 OEXT/39666 GCSV/235421203-MW10 EPA 3510 EPA 8082
92279395002 OEXT/39666 GCSV/235421203-MW11 EPA 3510 EPA 8082
92279395003 OEXT/39666 GCSV/235421203-MW12 EPA 3510 EPA 8082
92279395004 OEXT/39666 GCSV/235421203-MW13 EPA 3510 EPA 8082
92279395005 OEXT/39666 GCSV/235421203-MW16S EPA 3510 EPA 8082
92279395001 OEXT/25723 GCSV/167651203-MW10 EPA 8151 EPA 8151
92279395002 OEXT/25723 GCSV/167651203-MW11 EPA 8151 EPA 8151
92279395003 OEXT/25723 GCSV/167651203-MW12 EPA 8151 EPA 8151
92279395004 OEXT/25723 GCSV/167651203-MW13 EPA 8151 EPA 8151
92279395005 OEXT/25723 GCSV/167651203-MW16S EPA 8151 EPA 8151
92279395001 MPRP/20262 ICP/182921203-MW10 EPA 3010A EPA 6010
92279395002 MPRP/20262 ICP/182921203-MW11 EPA 3010A EPA 6010
92279395003 MPRP/20262 ICP/182921203-MW12 EPA 3010A EPA 6010
92279395004 MPRP/20262 ICP/182921203-MW13 EPA 3010A EPA 6010
92279395005 MPRP/20262 ICP/182921203-MW16S EPA 3010A EPA 6010
92279395006 MPRP/20262 ICP/182921203-MW16D EPA 3010A EPA 6010
92279395007 MPRP/20488 ICP/184871203-MW12 Re-run Sb,Cr,V EPA 3010A EPA 6010
92279395001 MERP/8788 MERC/84421203-MW10 EPA 7470 EPA 7470
92279395002 MERP/8788 MERC/84421203-MW11 EPA 7470 EPA 7470
92279395003 MERP/8788 MERC/84421203-MW12 EPA 7470 EPA 7470
92279395004 MERP/8788 MERC/84421203-MW13 EPA 7470 EPA 7470
92279395005 MERP/8788 MERC/84421203-MW16S EPA 7470 EPA 7470
92279395006 MERP/8789 MERC/84441203-MW16D EPA 7470 EPA 7470
92279395001 OEXT/39746 MSSV/116701203-MW10 EPA 3510 EPA 8270
92279395002 OEXT/39746 MSSV/116701203-MW11 EPA 3510 EPA 8270
92279395003 OEXT/39746 MSSV/116701203-MW12 EPA 3510 EPA 8270
92279395004 OEXT/39746 MSSV/116701203-MW13 EPA 3510 EPA 8270
92279395005 OEXT/39746 MSSV/116701203-MW16S EPA 3510 EPA 8270
92279395001 MSV/347991203-MW10 EPA 8260
92279395002 MSV/347991203-MW11 EPA 8260
92279395003 MSV/347991203-MW12 EPA 8260
92279395004 MSV/347991203-MW13 EPA 8260
92279395005 MSV/348201203-MW16S EPA 8260
92279395006 MSV/347991203-MW16D EPA 8260
92279395001 WET/419551203-MW10 SM 2320B
92279395002 WET/419551203-MW11 SM 2320B
92279395003 WET/419551203-MW12 SM 2320B
92279395004 WET/419551203-MW13 SM 2320B
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 80 of 83
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92279395
BURKE-JOHN'S R. C&D/MSWLF-COMP
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92279395005 WET/419551203-MW16S SM 2320B
92279395006 WET/419551203-MW16D SM 2320B
92279395001 WET/419161203-MW10 SM 2540C
92279395002 WET/419161203-MW11 SM 2540C
92279395003 WET/419161203-MW12 SM 2540C
92279395004 WET/419161203-MW13 SM 2540C
92279395005 WET/419161203-MW16S SM 2540C
92279395006 WET/419161203-MW16D SM 2540C
92279395001 WET/419141203-MW10 SM 4500-S2D
92279395002 WET/419141203-MW11 SM 4500-S2D
92279395003 WET/419141203-MW12 SM 4500-S2D
92279395004 WET/419141203-MW13 SM 4500-S2D
92279395005 WET/419141203-MW16S SM 4500-S2D
92279395001 WETA/257481203-MW10 EPA 300.0
92279395002 WETA/257481203-MW11 EPA 300.0
92279395003 WETA/257481203-MW12 EPA 300.0
92279395004 WETA/257481203-MW13 EPA 300.0
92279395005 WETA/257481203-MW16S EPA 300.0
92279395006 WETA/257481203-MW16D EPA 300.0
92279395001 WETA/258371203-MW10 SM 4500-Cl-E
92279395002 WETA/258371203-MW11 SM 4500-Cl-E
92279395003 WETA/258371203-MW12 SM 4500-Cl-E
92279395004 WETA/258371203-MW13 SM 4500-Cl-E
92279395005 WETA/258371203-MW16S SM 4500-Cl-E
92279395006 WETA/258371203-MW16D SM 4500-Cl-E
92279395001 WETA/257881203-MW10 SM 4500-CN-E
92279395002 WETA/257881203-MW11 SM 4500-CN-E
92279395003 WETA/257881203-MW12 SM 4500-CN-E
92279395004 WETA/257881203-MW13 SM 4500-CN-E
92279395005 WETA/257881203-MW16S SM 4500-CN-E
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/21/2016 04:02 PM
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Page 81 of 83
Page 82 of 83
Page 83 of 83
#=CL#
December 29, 2015
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92279347
92279347
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
BURKE CO. JOHN'S R-BG & BLANKS
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on December 10, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc:Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 1 of 58
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Ormond Beach Certification IDs8 East Tower Circle, Ormond Beach, FL 32174Alabama Certification #: 41320
Connecticut Certification #: PH-0216Delaware Certification: FL NELAC ReciprocityFlorida Certification #: E83079Georgia Certification #: 955Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC ReciprocityIllinois Certification #: 200068Indiana Certification: FL NELAC ReciprocityKansas Certification #: E-10383Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC ReciprocityLouisiana Environmental Certificate #: 05007Maryland Certification: #346Michigan Certification #: 9911Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958New York Certification #: 11608North Carolina Environmental Certificate #: 667North Carolina Certification #: 12710North Dakota Certification #: R-216
Oklahoma Certification #: D9947Pennsylvania Certification #: 68-00547Puerto Rico Certification #: FL01264South Carolina Certification: #96042001Tennessee Certification #: TN02974
Texas Certification: FL NELAC ReciprocityUS Virgin Islands Certification: FL NELAC ReciprocityVirginia Environmental Certification #: 460165West Virginia Certification #: 9962CWisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Lab ID Sample ID Matrix Date Collected Date Received
92279347001 1203-MW21 Water 12/08/15 11:20 12/10/15 10:45
92279347002 1203-FIELD BLANK Water 12/09/15 15:30 12/10/15 10:45
92279347003 1203-TRIP BLANK Water 12/08/15 00:00 12/10/15 10:45
REPORT OF LABORATORY ANALYSIS
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Page 3 of 58
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92279347001 1203-MW21 EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 18 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8270 111 PASI-CBPJ
EPA 8260 68 PASI-CGAW
SM 2320B 1 PASI-AMLS
SM 2540C 1 PASI-AMJP
SM 4500-S2D 1 PASI-AMJP
EPA 300.0 1 PASI-AMDW
SM 4500-Cl-E 1 PASI-AWRC
SM 4500-CN-E 1 PASI-AAES2
92279347002 1203-FIELD BLANK EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 18 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8270 111 PASI-CBPJ
EPA 8260 68 PASI-CGAW
SM 4500-S2D 1 PASI-ASAM
SM 4500-CN-E 1 PASI-AAES2
92279347003 1203-TRIP BLANK EPA 8260 68 PASI-CGAW
REPORT OF LABORATORY ANALYSIS
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Page 4 of 58
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92279347001 1203-MW21
Barium 17.6J ug/L 12/17/15 02:08100EPA 6010
Iron 1380 ug/L 12/17/15 02:08300EPA 6010
Manganese 50.0J ug/L 12/17/15 02:0850.0EPA 6010
Vanadium 6.6J ug/L 12/17/15 02:0825.0EPA 6010
Acrolein 1.6J ug/L 12/19/15 09:4553.0EPA 8260
Alkalinity, Total as CaCO3 1030J ug/L 12/14/15 15:095000SM 2320B
Chloride 859J ug/L 12/18/15 17:561000SM 4500-Cl-E
92279347002 1203-FIELD BLANK
Methylene Chloride 2.0 ug/L 12/20/15 21:21 C91.0EPA 8260
92279347003 1203-TRIP BLANK
Acrolein 2.8J ug/L 12/19/15 10:0253.0EPA 8260
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-MW21 Lab ID:92279347001 Collected:12/08/15 11:20 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 12/17/15 15:49 309-00-212/15/15 12:150.050 0.050 1
alpha-BHC ND ug/L 12/17/15 15:49 319-84-612/15/15 12:150.050 0.050 1
beta-BHC ND ug/L 12/17/15 15:49 319-85-712/15/15 12:150.050 0.050 1
delta-BHC ND ug/L 12/17/15 15:49 319-86-812/15/15 12:150.050 0.050 1
gamma-BHC (Lindane)ND ug/L 12/17/15 15:49 58-89-912/15/15 12:150.050 0.050 1
Chlordane (Technical)ND ug/L 12/17/15 15:49 57-74-912/15/15 12:150.50 0.20 1
4,4'-DDD ND ug/L 12/17/15 15:49 72-54-812/15/15 12:150.10 0.050 1
4,4'-DDE ND ug/L 12/17/15 15:49 72-55-912/15/15 12:150.10 0.050 1
4,4'-DDT ND ug/L 12/17/15 15:49 50-29-312/15/15 12:150.10 0.050 1
Dieldrin ND ug/L 12/17/15 15:49 60-57-112/15/15 12:150.075 0.050 1
Endosulfan I ND ug/L 12/17/15 15:49 959-98-812/15/15 12:150.10 0.050 1
Endosulfan II ND ug/L 12/17/15 15:49 33213-65-912/15/15 12:150.10 0.050 1
Endosulfan sulfate ND ug/L 12/17/15 15:49 1031-07-812/15/15 12:150.10 0.050 1
Endrin ND ug/L 12/17/15 15:49 72-20-812/15/15 12:150.10 0.050 1
Endrin aldehyde ND ug/L 12/17/15 15:49 7421-93-412/15/15 12:150.10 0.050 1
Heptachlor ND ug/L 12/17/15 15:49 76-44-812/15/15 12:150.050 0.050 1
Heptachlor epoxide ND ug/L 12/17/15 15:49 1024-57-312/15/15 12:150.075 0.050 1
Methoxychlor ND ug/L 12/17/15 15:49 72-43-512/15/15 12:151.0 0.15 1
Toxaphene ND ug/L 12/17/15 15:49 8001-35-212/15/15 12:151.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)74 %12/17/15 15:49 877-09-812/15/15 12:1520-130 1
Decachlorobiphenyl (S)62 %12/17/15 15:49 2051-24-312/15/15 12:1520-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 12/15/15 03:41 12674-11-212/13/15 12:530.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 12/15/15 03:41 11104-28-212/13/15 12:530.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 12/15/15 03:41 11141-16-512/13/15 12:530.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 12/15/15 03:41 53469-21-912/13/15 12:530.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 12/15/15 03:41 12672-29-612/13/15 12:530.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 12/15/15 03:41 11097-69-112/13/15 12:530.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 12/15/15 03:41 11096-82-512/13/15 12:530.50 0.50 1
Surrogates
Decachlorobiphenyl (S)73 %12/15/15 03:41 2051-24-312/13/15 12:5310-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 12/18/15 10:47 94-75-712/15/15 20:150.94 0.22 1
Dinoseb ND ug/L 12/18/15 10:47 88-85-712/15/15 20:150.19 0.057 1
2,4,5-T ND ug/L 12/18/15 10:47 93-76-512/15/15 20:150.19 0.042 1
2,4,5-TP (Silvex)ND ug/L 12/18/15 10:47 93-72-112/15/15 20:150.19 0.049 1
Surrogates
2,4-DCAA (S)87 %12/18/15 10:47 19719-28-912/15/15 20:1536-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/17/15 02:08 7440-36-012/12/15 00:006.0 3.8 1
Arsenic ND ug/L 12/17/15 02:08 7440-38-212/12/15 00:0010.0 2.5 1
Barium 17.6J ug/L 12/17/15 02:08 7440-39-312/12/15 00:001002.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 6 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-MW21 Lab ID:92279347001 Collected:12/08/15 11:20 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Beryllium ND ug/L 12/17/15 02:08 7440-41-712/12/15 00:001.0 0.50 1
Cadmium ND ug/L 12/17/15 02:08 7440-43-912/12/15 00:001.0 0.50 1
Chromium ND ug/L 12/17/15 02:08 7440-47-312/12/15 00:0010.0 2.5 1
Cobalt ND ug/L 12/17/15 02:08 7440-48-412/12/15 00:0010.0 2.5 1
Copper ND ug/L 12/17/15 02:08 7440-50-812/12/15 00:0010.0 2.5 1
Iron 1380 ug/L 12/17/15 02:08 7439-89-612/12/15 00:0030025.0 1
Lead ND ug/L 12/17/15 02:08 7439-92-112/12/15 00:0010.0 2.5 1
Manganese 50.0J ug/L 12/17/15 02:08 7439-96-512/12/15 00:0050.0 2.5 1
Nickel ND ug/L 12/17/15 02:08 7440-02-012/12/15 00:0050.0 2.5 1
Selenium ND ug/L 12/17/15 02:08 7782-49-212/12/15 00:0010.0 5.0 1
Silver ND ug/L 12/17/15 02:08 7440-22-412/12/15 00:0010.0 2.5 1
Thallium ND ug/L 12/17/15 02:08 7440-28-012/12/15 00:005.5 5.0 1
Tin ND ug/L 12/17/15 02:08 7440-31-512/12/15 00:001002.5 1
Vanadium 6.6J ug/L 12/17/15 02:08 7440-62-212/12/15 00:0025.0 2.5 1
Zinc ND ug/L 12/17/15 02:08 7440-66-612/12/15 00:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/17/15 18:27 7439-97-612/17/15 14:050.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 12/21/15 20:51 83-32-912/15/15 17:2810.0 0.25 1
Acenaphthylene ND ug/L 12/21/15 20:51 208-96-812/15/15 17:2810.0 0.21 1
Acetophenone ND ug/L 12/21/15 20:51 98-86-212/15/15 17:2810.0 2.0 1
2-Acetylaminofluorene ND ug/L 12/21/15 20:51 53-96-312/15/15 17:2820.0 0.84 1
4-Aminobiphenyl ND ug/L 12/21/15 20:51 92-67-112/15/15 17:2820.0 0.92 1
Anthracene ND ug/L 12/21/15 20:51 120-12-712/15/15 17:2810.0 0.14 1
Benzo(a)anthracene ND ug/L 12/21/15 20:51 56-55-312/15/15 17:2810.0 0.33 1
Benzo(a)pyrene ND ug/L 12/21/15 20:51 50-32-812/15/15 17:2810.0 0.30 1
Benzo(b)fluoranthene ND ug/L 12/21/15 20:51 205-99-212/15/15 17:2810.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 12/21/15 20:51 191-24-212/15/15 17:2810.0 0.38 1
Benzo(k)fluoranthene ND ug/L 12/21/15 20:51 207-08-912/15/15 17:2810.0 0.43 1
Benzyl alcohol ND ug/L 12/21/15 20:51 100-51-612/15/15 17:2820.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 12/21/15 20:51 101-55-312/15/15 17:2810.0 1.3 1
Butylbenzylphthalate ND ug/L 12/21/15 20:51 85-68-712/15/15 17:2810.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 12/21/15 20:51 59-50-712/15/15 17:2820.0 4.2 1
4-Chloroaniline ND ug/L 12/21/15 20:51 106-47-812/15/15 17:2820.0 3.4 1
Chlorobenzilate ND ug/L 12/21/15 20:51 510-15-612/15/15 17:2810.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 12/21/15 20:51 111-91-112/15/15 17:2810.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 12/21/15 20:51 111-44-412/15/15 17:2810.0 1.5 1
bis(2-Chloroisopropyl) ether ND ug/L 12/21/15 20:51 108-60-112/15/15 17:2810.0 1.6 1
2-Chloronaphthalene ND ug/L 12/21/15 20:51 91-58-712/15/15 17:2810.0 2.2 1
2-Chlorophenol ND ug/L 12/21/15 20:51 95-57-812/15/15 17:2810.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 12/21/15 20:51 7005-72-312/15/15 17:2810.0 2.1 1
Chrysene ND ug/L 12/21/15 20:51 218-01-912/15/15 17:2810.0 0.21 1
Diallate ND ug/L 12/21/15 20:51 2303-16-412/15/15 17:2810.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 12/21/15 20:51 53-70-312/15/15 17:2810.0 0.55 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
Page 7 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-MW21 Lab ID:92279347001 Collected:12/08/15 11:20 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Dibenzofuran ND ug/L 12/21/15 20:51 132-64-912/15/15 17:2810.0 1.8 1
3,3'-Dichlorobenzidine ND ug/L 12/21/15 20:51 91-94-112/15/15 17:2820.0 1.4 1
2,4-Dichlorophenol ND ug/L 12/21/15 20:51 120-83-212/15/15 17:2810.0 1.7 1
2,6-Dichlorophenol ND ug/L 12/21/15 20:51 87-65-012/15/15 17:2810.0 1.8 1
Diethylphthalate ND ug/L 12/21/15 20:51 84-66-212/15/15 17:2860001.3 1
Dimethoate ND ug/L 12/21/15 20:51 60-51-512/15/15 17:2820.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 12/21/15 20:51 60-11-712/15/15 17:2810.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 12/21/15 20:51 57-97-612/15/15 17:2810.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 12/21/15 20:51 119-93-712/15/15 17:2810.0 2.1 1
2,4-Dimethylphenol ND ug/L 12/21/15 20:51 105-67-912/15/15 17:2810.0 2.2 1
Dimethylphthalate ND ug/L 12/21/15 20:51 131-11-312/15/15 17:2810.0 1.5 1
Di-n-butylphthalate ND ug/L 12/21/15 20:51 84-74-212/15/15 17:2810.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 12/21/15 20:51 534-52-112/15/15 17:2850.0 1.7 1
1,3-Dinitrobenzene ND ug/L 12/21/15 20:51 99-65-012/15/15 17:2820.0 1.5 1
2,4-Dinitrophenol ND ug/L 12/21/15 20:51 51-28-512/15/15 17:2850.0 6.5 1
2,4-Dinitrotoluene ND ug/L 12/21/15 20:51 121-14-212/15/15 17:2810.0 1.2 1
2,6-Dinitrotoluene ND ug/L 12/21/15 20:51 606-20-212/15/15 17:2810.0 1.7 1
Di-n-octylphthalate ND ug/L 12/21/15 20:51 117-84-012/15/15 17:2810.0 0.86 1
Diphenylamine ND ug/L 12/21/15 20:51 122-39-412/15/15 17:2810.0 1.3 1
Disulfoton ND ug/L 12/21/15 20:51 298-04-412/15/15 17:2810.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 12/21/15 20:51 117-81-712/15/15 17:2815.0 0.85 1
Ethyl methanesulfonate ND ug/L 12/21/15 20:51 62-50-012/15/15 17:2820.0 1.8 1
Famphur ND ug/L 12/21/15 20:51 52-85-712/15/15 17:2820.0 1.7 1
Fluoranthene ND ug/L 12/21/15 20:51 206-44-0 L312/15/15 17:2810.0 0.21 1
Fluorene ND ug/L 12/21/15 20:51 86-73-712/15/15 17:2810.0 0.21 1
Hexachlorobenzene ND ug/L 12/21/15 20:51 118-74-112/15/15 17:2810.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 12/21/15 20:51 77-47-412/15/15 17:2810.0 1.8 1
Hexachloroethane ND ug/L 12/21/15 20:51 67-72-112/15/15 17:2810.0 1.5 1
Hexachloropropene ND ug/L 12/21/15 20:51 1888-71-712/15/15 17:2810.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 12/21/15 20:51 193-39-512/15/15 17:2810.0 0.29 1
Isodrin ND ug/L 12/21/15 20:51 465-73-6 L312/15/15 17:2820.0 2.0 1
Isophorone ND ug/L 12/21/15 20:51 78-59-112/15/15 17:2810.0 1.8 1
Isosafrole ND ug/L 12/21/15 20:51 120-58-112/15/15 17:2810.0 1.8 1
Kepone ND ug/L 12/21/15 20:51 143-50-012/15/15 17:2820.0 3.1 1
Methapyrilene ND ug/L 12/21/15 20:51 91-80-5 L212/15/15 17:281002.7 1
3-Methylcholanthrene ND ug/L 12/21/15 20:51 56-49-512/15/15 17:2810.0 0.82 1
Methyl methanesulfonate ND ug/L 12/21/15 20:51 66-27-312/15/15 17:2810.0 1.3 1
2-Methylnaphthalene ND ug/L 12/21/15 20:51 91-57-612/15/15 17:2810.0 0.28 1
Methyl parathion ND ug/L 12/21/15 20:51 298-00-012/15/15 17:2810.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 12/21/15 20:51 95-48-712/15/15 17:2810.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 12/21/15 20:5112/15/15 17:2810.0 1.7 1
1-Naphthalenamine ND ug/L 12/21/15 20:51 134-32-712/15/15 17:2810.0 0.96 1
2-Naphthalenamine ND ug/L 12/21/15 20:51 91-59-812/15/15 17:2810.0 0.98 1
1,4-Naphthoquinone ND ug/L 12/21/15 20:51 130-15-412/15/15 17:2810.0 1.8 1
2-Nitroaniline ND ug/L 12/21/15 20:51 88-74-412/15/15 17:2850.0 2.8 1
3-Nitroaniline ND ug/L 12/21/15 20:51 99-09-212/15/15 17:2850.0 2.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-MW21 Lab ID:92279347001 Collected:12/08/15 11:20 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
4-Nitroaniline ND ug/L 12/21/15 20:51 100-01-612/15/15 17:2820.0 2.5 1
Nitrobenzene ND ug/L 12/21/15 20:51 98-95-312/15/15 17:2810.0 1.7 1
2-Nitrophenol ND ug/L 12/21/15 20:51 88-75-512/15/15 17:2810.0 1.7 1
4-Nitrophenol ND ug/L 12/21/15 20:51 100-02-712/15/15 17:2850.0 5.8 1
5-Nitro-o-toluidine ND ug/L 12/21/15 20:51 99-55-812/15/15 17:2810.0 1.2 1
N-Nitrosodiethylamine ND ug/L 12/21/15 20:51 55-18-512/15/15 17:2820.0 1.8 1
N-Nitrosodimethylamine ND ug/L 12/21/15 20:51 62-75-912/15/15 17:2810.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 12/21/15 20:51 924-16-312/15/15 17:2810.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 12/21/15 20:51 621-64-712/15/15 17:2810.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 12/21/15 20:51 86-30-612/15/15 17:2810.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 12/21/15 20:51 10595-95-612/15/15 17:2810.0 1.8 1
N-Nitrosopiperidine ND ug/L 12/21/15 20:51 100-75-412/15/15 17:2820.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 12/21/15 20:51 930-55-212/15/15 17:2810.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 12/21/15 20:51 126-68-112/15/15 17:2810.0 1.8 1
Parathion (Ethyl parathion)ND ug/L 12/21/15 20:51 56-38-212/15/15 17:2810.0 1.1 1
Pentachlorobenzene ND ug/L 12/21/15 20:51 608-93-512/15/15 17:2810.0 2.0 1
Pentachloronitrobenzene ND ug/L 12/21/15 20:51 82-68-812/15/15 17:2820.0 1.0 1
Pentachlorophenol ND ug/L 12/21/15 20:51 87-86-512/15/15 17:2825.0 2.3 1
Phenacetin ND ug/L 12/21/15 20:51 62-44-212/15/15 17:2820.0 0.97 1
Phenanthrene ND ug/L 12/21/15 20:51 85-01-812/15/15 17:2810.0 0.22 1
Phenol ND ug/L 12/21/15 20:51 108-95-212/15/15 17:2810.0 1.7 1
p-Phenylenediamine ND ug/L 12/21/15 20:51 106-50-312/15/15 17:2810.0 0.96 1
Phorate ND ug/L 12/21/15 20:51 298-02-2 L312/15/15 17:2810.0 1.1 1
Pronamide ND ug/L 12/21/15 20:51 23950-58-512/15/15 17:2810.0 0.97 1
Pyrene ND ug/L 12/21/15 20:51 129-00-012/15/15 17:2810.0 0.19 1
Safrole ND ug/L 12/21/15 20:51 94-59-712/15/15 17:2810.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 12/21/15 20:51 95-94-312/15/15 17:2810.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 12/21/15 20:51 58-90-212/15/15 17:2810.0 2.3 1
Thionazin ND ug/L 12/21/15 20:51 297-97-212/15/15 17:2820.0 1.2 1
O-Toluidine ND ug/L 12/21/15 20:51 95-53-412/15/15 17:2810.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 12/21/15 20:51 95-95-412/15/15 17:2810.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 12/21/15 20:51 88-06-212/15/15 17:2810.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 12/21/15 20:51 99-35-4 L312/15/15 17:2810.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)79 %12/21/15 20:51 4165-60-012/15/15 17:2821-110 1
2-Fluorobiphenyl (S)76 %12/21/15 20:51 321-60-812/15/15 17:2827-110 1
Terphenyl-d14 (S)97 %12/21/15 20:51 1718-51-012/15/15 17:2831-107 1
Phenol-d6 (S)22 %12/21/15 20:51 13127-88-312/15/15 17:2810-110 1
2-Fluorophenol (S)34 %12/21/15 20:51 367-12-412/15/15 17:2812-110 1
2,4,6-Tribromophenol (S)98 %12/21/15 20:51 118-79-612/15/15 17:2827-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/19/15 09:45 67-64-110010.0 1
Acetonitrile ND ug/L 12/19/15 09:45 75-05-855.0 2.2 1
Acrolein 1.6J ug/L 12/19/15 09:45 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 12/19/15 09:45 107-13-12001.9 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-MW21 Lab ID:92279347001 Collected:12/08/15 11:20 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Allyl chloride ND ug/L 12/19/15 09:45 107-05-110.0 1.5 1
Benzene ND ug/L 12/19/15 09:45 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/19/15 09:45 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/19/15 09:45 75-27-41.0 0.18 1
Bromoform ND ug/L 12/19/15 09:45 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/19/15 09:45 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/19/15 09:45 78-93-31000.96 1
Carbon disulfide ND ug/L 12/19/15 09:45 75-15-01001.2 1
Carbon tetrachloride ND ug/L 12/19/15 09:45 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/19/15 09:45 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/19/15 09:45 75-00-310.0 0.54 1
Chloroform ND ug/L 12/19/15 09:45 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/19/15 09:45 74-87-31.0 0.11 1
Chloroprene ND ug/L 12/19/15 09:45 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 12/19/15 09:45 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/19/15 09:45 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/19/15 09:45 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/19/15 09:45 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/19/15 09:45 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 12/19/15 09:45 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 12/19/15 09:45 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/19/15 09:45 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 12/19/15 09:45 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 12/19/15 09:45 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/19/15 09:45 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/19/15 09:45 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/19/15 09:45 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/19/15 09:45 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/19/15 09:45 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 12/19/15 09:45 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 12/19/15 09:45 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 12/19/15 09:45 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 12/19/15 09:45 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/19/15 09:45 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/19/15 09:45 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 12/19/15 09:45 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 12/19/15 09:45 87-68-310.0 0.71 1
2-Hexanone ND ug/L 12/19/15 09:45 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/19/15 09:45 74-88-410.0 0.32 1
Isobutanol ND ug/L 12/19/15 09:45 78-83-110035.0 1
Methacrylonitrile ND ug/L 12/19/15 09:45 126-98-71000.93 1
Methylene Chloride ND ug/L 12/19/15 09:45 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 12/19/15 09:45 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/19/15 09:45 108-10-11000.33 1
Naphthalene ND ug/L 12/19/15 09:45 91-20-310.0 0.24 1
Propionitrile ND ug/L 12/19/15 09:45 107-12-01503.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-MW21 Lab ID:92279347001 Collected:12/08/15 11:20 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Styrene ND ug/L 12/19/15 09:45 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/19/15 09:45 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/19/15 09:45 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/19/15 09:45 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/19/15 09:45 109-99-910.0 3.1 1
Toluene ND ug/L 12/19/15 09:45 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 12/19/15 09:45 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 12/19/15 09:45 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/19/15 09:45 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/19/15 09:45 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/19/15 09:45 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/19/15 09:45 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/19/15 09:45 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/19/15 09:45 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/19/15 09:45 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)105 %12/19/15 09:45 460-00-470-130 1
1,2-Dichloroethane-d4 (S)98 %12/19/15 09:45 17060-07-070-130 1
Toluene-d8 (S)111 %12/19/15 09:45 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 1030J ug/L 12/14/15 15:09500010001
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids ND ug/L 12/11/15 10:4125000250001
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/11/15 15:00 18496-25-810001001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate ND ug/L 12/11/15 14:06 14808-79-825000010001
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 859J ug/L 12/18/15 17:56 16887-00-610005001
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 12/16/15 11:10 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-FIELD BLANK Lab ID:92279347002 Collected:12/09/15 15:30 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 12/17/15 18:48 309-00-212/15/15 12:150.050 0.050 1
alpha-BHC ND ug/L 12/17/15 18:48 319-84-612/15/15 12:150.050 0.050 1
beta-BHC ND ug/L 12/17/15 18:48 319-85-712/15/15 12:150.050 0.050 1
delta-BHC ND ug/L 12/17/15 18:48 319-86-812/15/15 12:150.050 0.050 1
gamma-BHC (Lindane)ND ug/L 12/17/15 18:48 58-89-912/15/15 12:150.050 0.050 1
Chlordane (Technical)ND ug/L 12/17/15 18:48 57-74-912/15/15 12:150.50 0.20 1
4,4'-DDD ND ug/L 12/17/15 18:48 72-54-812/15/15 12:150.10 0.050 1
4,4'-DDE ND ug/L 12/17/15 18:48 72-55-912/15/15 12:150.10 0.050 1
4,4'-DDT ND ug/L 12/17/15 18:48 50-29-312/15/15 12:150.10 0.050 1
Dieldrin ND ug/L 12/17/15 18:48 60-57-112/15/15 12:150.075 0.050 1
Endosulfan I ND ug/L 12/17/15 18:48 959-98-812/15/15 12:150.10 0.050 1
Endosulfan II ND ug/L 12/17/15 18:48 33213-65-912/15/15 12:150.10 0.050 1
Endosulfan sulfate ND ug/L 12/17/15 18:48 1031-07-812/15/15 12:150.10 0.050 1
Endrin ND ug/L 12/17/15 18:48 72-20-812/15/15 12:150.10 0.050 1
Endrin aldehyde ND ug/L 12/17/15 18:48 7421-93-412/15/15 12:150.10 0.050 1
Heptachlor ND ug/L 12/17/15 18:48 76-44-812/15/15 12:150.050 0.050 1
Heptachlor epoxide ND ug/L 12/17/15 18:48 1024-57-312/15/15 12:150.075 0.050 1
Methoxychlor ND ug/L 12/17/15 18:48 72-43-512/15/15 12:151.0 0.15 1
Toxaphene ND ug/L 12/17/15 18:48 8001-35-212/15/15 12:151.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)74 %12/17/15 18:48 877-09-812/15/15 12:1520-130 1
Decachlorobiphenyl (S)64 %12/17/15 18:48 2051-24-312/15/15 12:1520-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 12/15/15 04:23 12674-11-212/13/15 12:530.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 12/15/15 04:23 11104-28-212/13/15 12:530.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 12/15/15 04:23 11141-16-512/13/15 12:530.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 12/15/15 04:23 53469-21-912/13/15 12:530.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 12/15/15 04:23 12672-29-612/13/15 12:530.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 12/15/15 04:23 11097-69-112/13/15 12:530.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 12/15/15 04:23 11096-82-512/13/15 12:530.50 0.50 1
Surrogates
Decachlorobiphenyl (S)57 %12/15/15 04:23 2051-24-312/13/15 12:5310-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 12/18/15 11:17 94-75-712/15/15 20:150.94 0.22 1
Dinoseb ND ug/L 12/18/15 11:17 88-85-712/15/15 20:150.19 0.057 1
2,4,5-T ND ug/L 12/18/15 11:17 93-76-512/15/15 20:150.19 0.042 1
2,4,5-TP (Silvex)ND ug/L 12/18/15 11:17 93-72-112/15/15 20:150.19 0.049 1
Surrogates
2,4-DCAA (S)85 %12/18/15 11:17 19719-28-912/15/15 20:1536-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/17/15 02:11 7440-36-012/12/15 00:006.0 3.8 1
Arsenic ND ug/L 12/17/15 02:11 7440-38-212/12/15 00:0010.0 2.5 1
Barium ND ug/L 12/17/15 02:11 7440-39-312/12/15 00:001002.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-FIELD BLANK Lab ID:92279347002 Collected:12/09/15 15:30 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Beryllium ND ug/L 12/17/15 02:11 7440-41-712/12/15 00:001.0 0.50 1
Cadmium ND ug/L 12/17/15 02:11 7440-43-912/12/15 00:001.0 0.50 1
Chromium ND ug/L 12/17/15 02:11 7440-47-312/12/15 00:0010.0 2.5 1
Cobalt ND ug/L 12/17/15 02:11 7440-48-412/12/15 00:0010.0 2.5 1
Copper ND ug/L 12/17/15 02:11 7440-50-812/12/15 00:0010.0 2.5 1
Iron ND ug/L 12/17/15 02:11 7439-89-612/12/15 00:0030025.0 1
Lead ND ug/L 12/17/15 02:11 7439-92-112/12/15 00:0010.0 2.5 1
Manganese ND ug/L 12/17/15 02:11 7439-96-512/12/15 00:0050.0 2.5 1
Nickel ND ug/L 12/17/15 02:11 7440-02-012/12/15 00:0050.0 2.5 1
Selenium ND ug/L 12/17/15 02:11 7782-49-212/12/15 00:0010.0 5.0 1
Silver ND ug/L 12/17/15 02:11 7440-22-412/12/15 00:0010.0 2.5 1
Thallium ND ug/L 12/17/15 02:11 7440-28-012/12/15 00:005.5 5.0 1
Tin ND ug/L 12/17/15 02:11 7440-31-512/12/15 00:001002.5 1
Vanadium ND ug/L 12/17/15 02:11 7440-62-212/12/15 00:0025.0 2.5 1
Zinc ND ug/L 12/17/15 02:11 7440-66-612/12/15 00:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/17/15 18:29 7439-97-612/17/15 14:050.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 12/29/15 11:19 83-32-912/15/15 17:2810.0 0.25 1
Acenaphthylene ND ug/L 12/29/15 11:19 208-96-812/15/15 17:2810.0 0.21 1
Acetophenone ND ug/L 12/29/15 11:19 98-86-212/15/15 17:2810.0 2.0 1
2-Acetylaminofluorene ND ug/L 12/29/15 11:19 53-96-312/15/15 17:2820.0 0.84 1
4-Aminobiphenyl ND ug/L 12/29/15 11:19 92-67-112/15/15 17:2820.0 0.92 1
Anthracene ND ug/L 12/29/15 11:19 120-12-712/15/15 17:2810.0 0.14 1
Benzo(a)anthracene ND ug/L 12/29/15 11:19 56-55-312/15/15 17:2810.0 0.33 1
Benzo(a)pyrene ND ug/L 12/29/15 11:19 50-32-812/15/15 17:2810.0 0.30 1
Benzo(b)fluoranthene ND ug/L 12/29/15 11:19 205-99-212/15/15 17:2810.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 12/29/15 11:19 191-24-212/15/15 17:2810.0 0.38 1
Benzo(k)fluoranthene ND ug/L 12/29/15 11:19 207-08-912/15/15 17:2810.0 0.43 1
Benzyl alcohol ND ug/L 12/29/15 11:19 100-51-612/15/15 17:2820.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 12/29/15 11:19 101-55-312/15/15 17:2810.0 1.3 1
Butylbenzylphthalate ND ug/L 12/29/15 11:19 85-68-712/15/15 17:2810.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 12/29/15 11:19 59-50-712/15/15 17:2820.0 4.2 1
4-Chloroaniline ND ug/L 12/29/15 11:19 106-47-812/15/15 17:2820.0 3.4 1
Chlorobenzilate ND ug/L 12/29/15 11:19 510-15-612/15/15 17:2810.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 12/29/15 11:19 111-91-112/15/15 17:2810.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 12/29/15 11:19 111-44-412/15/15 17:2810.0 1.5 1
bis(2-Chloroisopropyl) ether ND ug/L 12/29/15 11:19 108-60-112/15/15 17:2810.0 1.6 1
2-Chloronaphthalene ND ug/L 12/29/15 11:19 91-58-712/15/15 17:2810.0 2.2 1
2-Chlorophenol ND ug/L 12/29/15 11:19 95-57-812/15/15 17:2810.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 12/29/15 11:19 7005-72-312/15/15 17:2810.0 2.1 1
Chrysene ND ug/L 12/29/15 11:19 218-01-912/15/15 17:2810.0 0.21 1
Diallate ND ug/L 12/29/15 11:19 2303-16-412/15/15 17:2810.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 12/29/15 11:19 53-70-312/15/15 17:2810.0 0.55 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-FIELD BLANK Lab ID:92279347002 Collected:12/09/15 15:30 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Dibenzofuran ND ug/L 12/29/15 11:19 132-64-912/15/15 17:2810.0 1.8 1
3,3'-Dichlorobenzidine ND ug/L 12/29/15 11:19 91-94-112/15/15 17:2820.0 1.4 1
2,4-Dichlorophenol ND ug/L 12/29/15 11:19 120-83-212/15/15 17:2810.0 1.7 1
2,6-Dichlorophenol ND ug/L 12/29/15 11:19 87-65-012/15/15 17:2810.0 1.8 1
Diethylphthalate ND ug/L 12/29/15 11:19 84-66-212/15/15 17:2860001.3 1
Dimethoate ND ug/L 12/29/15 11:19 60-51-512/15/15 17:2820.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 12/29/15 11:19 60-11-712/15/15 17:2810.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 12/29/15 11:19 57-97-612/15/15 17:2810.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 12/29/15 11:19 119-93-712/15/15 17:2810.0 2.1 1
2,4-Dimethylphenol ND ug/L 12/29/15 11:19 105-67-912/15/15 17:2810.0 2.2 1
Dimethylphthalate ND ug/L 12/29/15 11:19 131-11-312/15/15 17:2810.0 1.5 1
Di-n-butylphthalate ND ug/L 12/29/15 11:19 84-74-212/15/15 17:2810.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 12/29/15 11:19 534-52-112/15/15 17:2850.0 1.7 1
1,3-Dinitrobenzene ND ug/L 12/29/15 11:19 99-65-012/15/15 17:2820.0 1.5 1
2,4-Dinitrophenol ND ug/L 12/29/15 11:19 51-28-512/15/15 17:2850.0 6.5 1
2,4-Dinitrotoluene ND ug/L 12/29/15 11:19 121-14-212/15/15 17:2810.0 1.2 1
2,6-Dinitrotoluene ND ug/L 12/29/15 11:19 606-20-212/15/15 17:2810.0 1.7 1
Di-n-octylphthalate ND ug/L 12/29/15 11:19 117-84-012/15/15 17:2810.0 0.86 1
Diphenylamine ND ug/L 12/29/15 11:19 122-39-412/15/15 17:2810.0 1.3 1
Disulfoton ND ug/L 12/29/15 11:19 298-04-412/15/15 17:2810.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 12/29/15 11:19 117-81-712/15/15 17:2815.0 0.85 1
Ethyl methanesulfonate ND ug/L 12/29/15 11:19 62-50-012/15/15 17:2820.0 1.8 1
Famphur ND ug/L 12/29/15 11:19 52-85-712/15/15 17:2820.0 1.7 1
Fluoranthene ND ug/L 12/29/15 11:19 206-44-0 L312/15/15 17:2810.0 0.21 1
Fluorene ND ug/L 12/29/15 11:19 86-73-712/15/15 17:2810.0 0.21 1
Hexachlorobenzene ND ug/L 12/29/15 11:19 118-74-112/15/15 17:2810.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 12/29/15 11:19 77-47-412/15/15 17:2810.0 1.8 1
Hexachloroethane ND ug/L 12/29/15 11:19 67-72-112/15/15 17:2810.0 1.5 1
Hexachloropropene ND ug/L 12/29/15 11:19 1888-71-712/15/15 17:2810.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 12/29/15 11:19 193-39-512/15/15 17:2810.0 0.29 1
Isodrin ND ug/L 12/29/15 11:19 465-73-6 L312/15/15 17:2820.0 2.0 1
Isophorone ND ug/L 12/29/15 11:19 78-59-112/15/15 17:2810.0 1.8 1
Isosafrole ND ug/L 12/29/15 11:19 120-58-112/15/15 17:2810.0 1.8 1
Kepone ND ug/L 12/29/15 11:19 143-50-012/15/15 17:2820.0 3.1 1
Methapyrilene ND ug/L 12/29/15 11:19 91-80-5 L212/15/15 17:281002.7 1
3-Methylcholanthrene ND ug/L 12/29/15 11:19 56-49-512/15/15 17:2810.0 0.82 1
Methyl methanesulfonate ND ug/L 12/29/15 11:19 66-27-312/15/15 17:2810.0 1.3 1
2-Methylnaphthalene ND ug/L 12/29/15 11:19 91-57-612/15/15 17:2810.0 0.28 1
Methyl parathion ND ug/L 12/29/15 11:19 298-00-012/15/15 17:2810.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 12/29/15 11:19 95-48-712/15/15 17:2810.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 12/29/15 11:1912/15/15 17:2810.0 1.7 1
1-Naphthalenamine ND ug/L 12/29/15 11:19 134-32-712/15/15 17:2810.0 0.96 1
2-Naphthalenamine ND ug/L 12/29/15 11:19 91-59-812/15/15 17:2810.0 0.98 1
1,4-Naphthoquinone ND ug/L 12/29/15 11:19 130-15-412/15/15 17:2810.0 1.8 1
2-Nitroaniline ND ug/L 12/29/15 11:19 88-74-412/15/15 17:2850.0 2.8 1
3-Nitroaniline ND ug/L 12/29/15 11:19 99-09-212/15/15 17:2850.0 2.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-FIELD BLANK Lab ID:92279347002 Collected:12/09/15 15:30 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
4-Nitroaniline ND ug/L 12/29/15 11:19 100-01-612/15/15 17:2820.0 2.5 1
Nitrobenzene ND ug/L 12/29/15 11:19 98-95-312/15/15 17:2810.0 1.7 1
2-Nitrophenol ND ug/L 12/29/15 11:19 88-75-512/15/15 17:2810.0 1.7 1
4-Nitrophenol ND ug/L 12/29/15 11:19 100-02-712/15/15 17:2850.0 5.8 1
5-Nitro-o-toluidine ND ug/L 12/29/15 11:19 99-55-812/15/15 17:2810.0 1.2 1
N-Nitrosodiethylamine ND ug/L 12/29/15 11:19 55-18-512/15/15 17:2820.0 1.8 1
N-Nitrosodimethylamine ND ug/L 12/29/15 11:19 62-75-912/15/15 17:2810.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 12/29/15 11:19 924-16-312/15/15 17:2810.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 12/29/15 11:19 621-64-712/15/15 17:2810.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 12/29/15 11:19 86-30-612/15/15 17:2810.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 12/29/15 11:19 10595-95-612/15/15 17:2810.0 1.8 1
N-Nitrosopiperidine ND ug/L 12/29/15 11:19 100-75-412/15/15 17:2820.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 12/29/15 11:19 930-55-212/15/15 17:2810.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 12/29/15 11:19 126-68-112/15/15 17:2810.0 1.8 1
Parathion (Ethyl parathion)ND ug/L 12/29/15 11:19 56-38-212/15/15 17:2810.0 1.1 1
Pentachlorobenzene ND ug/L 12/29/15 11:19 608-93-512/15/15 17:2810.0 2.0 1
Pentachloronitrobenzene ND ug/L 12/29/15 11:19 82-68-812/15/15 17:2820.0 1.0 1
Pentachlorophenol ND ug/L 12/29/15 11:19 87-86-512/15/15 17:2825.0 2.3 1
Phenacetin ND ug/L 12/29/15 11:19 62-44-212/15/15 17:2820.0 0.97 1
Phenanthrene ND ug/L 12/29/15 11:19 85-01-812/15/15 17:2810.0 0.22 1
Phenol ND ug/L 12/29/15 11:19 108-95-212/15/15 17:2810.0 1.7 1
p-Phenylenediamine ND ug/L 12/29/15 11:19 106-50-312/15/15 17:2810.0 0.96 1
Phorate ND ug/L 12/29/15 11:19 298-02-2 L312/15/15 17:2810.0 1.1 1
Pronamide ND ug/L 12/29/15 11:19 23950-58-512/15/15 17:2810.0 0.97 1
Pyrene ND ug/L 12/29/15 11:19 129-00-012/15/15 17:2810.0 0.19 1
Safrole ND ug/L 12/29/15 11:19 94-59-712/15/15 17:2810.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 12/29/15 11:19 95-94-312/15/15 17:2810.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 12/29/15 11:19 58-90-212/15/15 17:2810.0 2.3 1
Thionazin ND ug/L 12/29/15 11:19 297-97-212/15/15 17:2820.0 1.2 1
O-Toluidine ND ug/L 12/29/15 11:19 95-53-412/15/15 17:2810.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 12/29/15 11:19 95-95-412/15/15 17:2810.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 12/29/15 11:19 88-06-212/15/15 17:2810.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 12/29/15 11:19 99-35-4 L312/15/15 17:2810.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)65 %12/29/15 11:19 4165-60-012/15/15 17:2821-110 1
2-Fluorobiphenyl (S)65 %12/29/15 11:19 321-60-812/15/15 17:2827-110 1
Terphenyl-d14 (S)82 %12/29/15 11:19 1718-51-012/15/15 17:2831-107 1
Phenol-d6 (S)21 %12/29/15 11:19 13127-88-312/15/15 17:2810-110 1
2-Fluorophenol (S)33 %12/29/15 11:19 367-12-412/15/15 17:2812-110 1
2,4,6-Tribromophenol (S)64 %12/29/15 11:19 118-79-612/15/15 17:2827-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/20/15 21:21 67-64-110010.0 1
Acetonitrile ND ug/L 12/20/15 21:21 75-05-855.0 2.2 1
Acrolein ND ug/L 12/20/15 21:21 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 12/20/15 21:21 107-13-12001.9 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
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Page 15 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-FIELD BLANK Lab ID:92279347002 Collected:12/09/15 15:30 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Allyl chloride ND ug/L 12/20/15 21:21 107-05-110.0 1.5 1
Benzene ND ug/L 12/20/15 21:21 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/20/15 21:21 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/20/15 21:21 75-27-41.0 0.18 1
Bromoform ND ug/L 12/20/15 21:21 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/20/15 21:21 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/20/15 21:21 78-93-31000.96 1
Carbon disulfide ND ug/L 12/20/15 21:21 75-15-01001.2 1
Carbon tetrachloride ND ug/L 12/20/15 21:21 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/20/15 21:21 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/20/15 21:21 75-00-310.0 0.54 1
Chloroform ND ug/L 12/20/15 21:21 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/20/15 21:21 74-87-31.0 0.11 1
Chloroprene ND ug/L 12/20/15 21:21 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 12/20/15 21:21 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/20/15 21:21 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/20/15 21:21 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/20/15 21:21 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/20/15 21:21 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 12/20/15 21:21 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 12/20/15 21:21 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/20/15 21:21 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 12/20/15 21:21 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 12/20/15 21:21 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/20/15 21:21 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/20/15 21:21 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/20/15 21:21 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/20/15 21:21 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/20/15 21:21 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 12/20/15 21:21 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 12/20/15 21:21 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 12/20/15 21:21 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 12/20/15 21:21 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/20/15 21:21 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/20/15 21:21 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 12/20/15 21:21 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 12/20/15 21:21 87-68-310.0 0.71 1
2-Hexanone ND ug/L 12/20/15 21:21 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/20/15 21:21 74-88-410.0 0.32 1
Isobutanol ND ug/L 12/20/15 21:21 78-83-110035.0 1
Methacrylonitrile ND ug/L 12/20/15 21:21 126-98-71000.93 1
Methylene Chloride 2.0 ug/L 12/20/15 21:21 75-09-2 C91.0 0.97 1
Methyl methacrylate ND ug/L 12/20/15 21:21 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/20/15 21:21 108-10-11000.33 1
Naphthalene ND ug/L 12/20/15 21:21 91-20-310.0 0.24 1
Propionitrile ND ug/L 12/20/15 21:21 107-12-01503.6 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
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Page 16 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-FIELD BLANK Lab ID:92279347002 Collected:12/09/15 15:30 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Styrene ND ug/L 12/20/15 21:21 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/20/15 21:21 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/20/15 21:21 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/20/15 21:21 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/20/15 21:21 109-99-910.0 3.1 1
Toluene ND ug/L 12/20/15 21:21 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 12/20/15 21:21 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 12/20/15 21:21 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/20/15 21:21 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/20/15 21:21 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/20/15 21:21 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/20/15 21:21 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/20/15 21:21 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/20/15 21:21 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/20/15 21:21 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)103 %12/20/15 21:21 460-00-470-130 1
1,2-Dichloroethane-d4 (S)95 %12/20/15 21:21 17060-07-070-130 1
Toluene-d8 (S)108 %12/20/15 21:21 2037-26-570-130 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/14/15 12:30 18496-25-810001001
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 12/16/15 11:30 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
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Page 17 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-TRIP BLANK Lab ID:92279347003 Collected:12/08/15 00:00 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/19/15 10:02 67-64-110010.0 1
Acetonitrile ND ug/L 12/19/15 10:02 75-05-855.0 2.2 1
Acrolein 2.8J ug/L 12/19/15 10:02 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 12/19/15 10:02 107-13-12001.9 1
Allyl chloride ND ug/L 12/19/15 10:02 107-05-110.0 1.5 1
Benzene ND ug/L 12/19/15 10:02 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/19/15 10:02 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/19/15 10:02 75-27-41.0 0.18 1
Bromoform ND ug/L 12/19/15 10:02 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/19/15 10:02 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/19/15 10:02 78-93-31000.96 1
Carbon disulfide ND ug/L 12/19/15 10:02 75-15-01001.2 1
Carbon tetrachloride ND ug/L 12/19/15 10:02 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/19/15 10:02 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/19/15 10:02 75-00-310.0 0.54 1
Chloroform ND ug/L 12/19/15 10:02 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/19/15 10:02 74-87-31.0 0.11 1
Chloroprene ND ug/L 12/19/15 10:02 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 12/19/15 10:02 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/19/15 10:02 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/19/15 10:02 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/19/15 10:02 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/19/15 10:02 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 12/19/15 10:02 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 12/19/15 10:02 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/19/15 10:02 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 12/19/15 10:02 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 12/19/15 10:02 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/19/15 10:02 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/19/15 10:02 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/19/15 10:02 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/19/15 10:02 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/19/15 10:02 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 12/19/15 10:02 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 12/19/15 10:02 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 12/19/15 10:02 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 12/19/15 10:02 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/19/15 10:02 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/19/15 10:02 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 12/19/15 10:02 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 12/19/15 10:02 87-68-310.0 0.71 1
2-Hexanone ND ug/L 12/19/15 10:02 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/19/15 10:02 74-88-410.0 0.32 1
Isobutanol ND ug/L 12/19/15 10:02 78-83-110035.0 1
Methacrylonitrile ND ug/L 12/19/15 10:02 126-98-71000.93 1
Methylene Chloride ND ug/L 12/19/15 10:02 75-09-21.0 0.97 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
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Page 18 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-TRIP BLANK Lab ID:92279347003 Collected:12/08/15 00:00 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Methyl methacrylate ND ug/L 12/19/15 10:02 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/19/15 10:02 108-10-11000.33 1
Naphthalene ND ug/L 12/19/15 10:02 91-20-310.0 0.24 1
Propionitrile ND ug/L 12/19/15 10:02 107-12-01503.6 1
Styrene ND ug/L 12/19/15 10:02 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/19/15 10:02 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/19/15 10:02 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/19/15 10:02 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/19/15 10:02 109-99-910.0 3.1 1
Toluene ND ug/L 12/19/15 10:02 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 12/19/15 10:02 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 12/19/15 10:02 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/19/15 10:02 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/19/15 10:02 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/19/15 10:02 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/19/15 10:02 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/19/15 10:02 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/19/15 10:02 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/19/15 10:02 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)110 %12/19/15 10:02 460-00-470-130 1
1,2-Dichloroethane-d4 (S)98 %12/19/15 10:02 17060-07-070-130 1
Toluene-d8 (S)114 %12/19/15 10:02 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
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Page 19 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/8788
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples:92279347001, 92279347002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1629746
Associated Lab Samples:92279347001, 92279347002
Matrix:Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/17/15 17:420.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1629747LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.42.5 96 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1629748MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279275008
1629749
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 96 75-12599 3 252.5ND 2.4 2.5
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
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Page 20 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20260
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92279347001, 92279347002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1627221
Associated Lab Samples:92279347001, 92279347002
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 12/17/15 00:323.8
Arsenic ug/L ND 10.0 12/17/15 00:322.5
Barium ug/L ND 100 12/17/15 00:322.5
Beryllium ug/L ND 1.0 12/17/15 00:320.50
Cadmium ug/L ND 1.0 12/17/15 00:320.50
Chromium ug/L ND 10.0 12/17/15 00:322.5
Cobalt ug/L ND 10.0 12/17/15 00:322.5
Copper ug/L ND 10.0 12/17/15 00:322.5
Iron ug/L ND 300 12/17/15 00:3225.0
Lead ug/L ND 10.0 12/17/15 00:322.5
Manganese ug/L ND 50.0 12/17/15 00:322.5
Nickel ug/L ND 50.0 12/17/15 00:322.5
Selenium ug/L ND 10.0 12/17/15 00:325.0
Silver ug/L ND 10.0 12/17/15 00:322.5
Thallium ug/L ND 5.5 12/17/15 00:325.0
Tin ug/L ND 100 12/17/15 00:322.5
Vanadium ug/L ND 25.0 12/17/15 00:322.5
Zinc ug/L ND 10.0 12/17/15 00:325.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1627222LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 547500 109 80-120
Arsenic ug/L 489500 98 80-120
Barium ug/L 479500 96 80-120
Beryllium ug/L 472500 94 80-120
Cadmium ug/L 497500 99 80-120
Chromium ug/L 464500 93 80-120
Cobalt ug/L 507500 101 80-120
Copper ug/L 490500 98 80-120
Iron ug/L 48505000 97 80-120
Lead ug/L 500500 100 80-120
Manganese ug/L 511500 102 80-120
Nickel ug/L 500500 100 80-120
Selenium ug/L 506500 101 80-120
Silver ug/L 254250 102 80-120
Thallium ug/L 476500 95 80-120
Tin ug/L 550500 110 80-120
Vanadium ug/L 520500 104 80-120
Zinc ug/L 515500 103 80-120
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1627223MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279296001
1627224
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 79 75-12575 4 25500ND395379
Arsenic ug/L 500 92 75-12591 2 25500ND464454
Barium ug/L 500 94 75-12595 0 25500151621624
Beryllium ug/L 500 92 75-12592 0 255002.8 462 461
Cadmium ug/L 500 95 75-12593 2 25500ND475467
Chromium ug/L 500 91 75-12590 1 255006.9 464 458
Cobalt ug/L 500 96 75-12595 2 2550012.0 493 484
Copper ug/L 500 96 75-12595 1 2550014.9 496 492
Iron ug/L M1500023575-125267 7 255000101002180023400
Lead ug/L 500 94 75-12592 2 255008.6 476 469
Manganese ug/L 500 103 75-125102 1 25500133648642
Nickel ug/L 500 95 75-12594 1 2550015.6 491 484
Selenium ug/L 500 94 75-12593 2 25500ND472465
Silver ug/L 250 98 75-12597 1 25250ND245242
Thallium ug/L 500 88 75-12587 1 255005.1J 443 440
Tin ug/L 500 103 75-125100 2 25500ND515503
Vanadium ug/L 500 103 75-125102 1 2550016.8 532 525
Zinc ug/L 500 101 75-125101 1 2550035.2 542 538
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34786
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92279347001, 92279347003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1633238
Associated Lab Samples:92279347001, 92279347003
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 12/19/15 01:260.33
1,1,1-Trichloroethane ug/L ND 1.0 12/19/15 01:260.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 12/19/15 01:260.40
1,1,2-Trichloroethane ug/L ND 1.0 12/19/15 01:260.29
1,1-Dichloroethane ug/L ND 5.0 12/19/15 01:260.32
1,1-Dichloroethene ug/L ND 5.0 12/19/15 01:260.56
1,1-Dichloropropene ug/L ND 5.0 12/19/15 01:260.49
1,2,3-Trichloropropane ug/L ND 1.0 12/19/15 01:260.41
1,2,4-Trichlorobenzene ug/L ND 10.0 12/19/15 01:260.35
1,2-Dibromo-3-chloropropane ug/L ND 13.0 12/19/15 01:262.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/19/15 01:260.27
1,2-Dichlorobenzene ug/L ND 5.0 12/19/15 01:260.30
1,2-Dichloroethane ug/L ND 1.0 12/19/15 01:260.24
1,2-Dichloropropane ug/L ND 1.0 12/19/15 01:260.27
1,3-Dichlorobenzene ug/L ND 5.0 12/19/15 01:260.24
1,3-Dichloropropane ug/L ND 1.0 12/19/15 01:260.28
1,4-Dichlorobenzene ug/L ND 1.0 12/19/15 01:260.33
2,2-Dichloropropane ug/L ND 15.0 12/19/15 01:260.13
2-Butanone (MEK)ug/L ND 100 12/19/15 01:260.96
2-Hexanone ug/L ND 50.0 12/19/15 01:260.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 12/19/15 01:260.33
Acetone ug/L ND 100 12/19/15 01:2610.0
Acetonitrile ug/L ND 55.0 12/19/15 01:262.2
Acrolein ug/L ND 53.0 12/19/15 01:261.6
Acrylonitrile ug/L ND 200 12/19/15 01:261.9
Allyl chloride ug/L ND 10.0 12/19/15 01:261.5
Benzene ug/L ND 1.0 12/19/15 01:260.25
Bromochloromethane ug/L ND 3.0 12/19/15 01:260.17
Bromodichloromethane ug/L ND 1.0 12/19/15 01:260.18
Bromoform ug/L ND 3.0 12/19/15 01:260.26
Bromomethane ug/L ND 10.0 12/19/15 01:260.29
Carbon disulfide ug/L ND 100 12/19/15 01:261.2
Carbon tetrachloride ug/L ND 1.0 12/19/15 01:260.25
Chlorobenzene ug/L ND 3.0 12/19/15 01:260.23
Chloroethane ug/L ND 10.0 12/19/15 01:260.54
Chloroform ug/L ND 5.0 12/19/15 01:260.14
Chloromethane ug/L ND 1.0 12/19/15 01:260.11
Chloroprene ug/L ND 20.0 12/19/15 01:260.27
cis-1,2-Dichloroethene ug/L ND 5.0 12/19/15 01:260.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/19/15 01:260.13
Dibromochloromethane ug/L ND 3.0 12/19/15 01:260.21
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
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Page 23 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1633238
Associated Lab Samples:92279347001, 92279347003
Matrix:Water
AnalyzedMDL
Dibromomethane ug/L ND 10.0 12/19/15 01:260.21
Dichlorodifluoromethane ug/L ND 5.0 12/19/15 01:260.21
Ethyl methacrylate ug/L ND 10.0 12/19/15 01:260.20
Ethylbenzene ug/L ND 1.0 12/19/15 01:260.30
Hexachloro-1,3-butadiene ug/L ND 10.0 12/19/15 01:260.71
Iodomethane ug/L ND 10.0 12/19/15 01:260.32
Isobutanol ug/L ND 100 12/19/15 01:2635.0
Methacrylonitrile ug/L ND 100 12/19/15 01:260.93
Methyl methacrylate ug/L ND 30.0 12/19/15 01:262.0
Methylene Chloride ug/L ND 1.0 12/19/15 01:260.97
Naphthalene ug/L ND 10.0 12/19/15 01:260.24
Propionitrile ug/L ND 150 12/19/15 01:263.6
Styrene ug/L ND 1.0 12/19/15 01:260.26
Tetrachloroethene ug/L 1.2 1.0 12/19/15 01:260.46
Tetrahydrofuran ug/L ND 10.0 12/19/15 01:263.1
Toluene ug/L ND 1.0 12/19/15 01:260.26
trans-1,2-Dichloroethene ug/L ND 5.0 12/19/15 01:260.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/19/15 01:260.26
trans-1,4-Dichloro-2-butene ug/L ND 100 12/19/15 01:261.0
Trichloroethene ug/L ND 1.0 12/19/15 01:260.47
Trichlorofluoromethane ug/L ND 1.0 12/19/15 01:260.20
Vinyl acetate ug/L ND 50.0 12/19/15 01:260.35
Vinyl chloride ug/L ND 1.0 12/19/15 01:260.62
Xylene (Total)ug/L ND 5.0 12/19/15 01:260.66
1,2-Dichloroethane-d4 (S)%94 70-130 12/19/15 01:26
4-Bromofluorobenzene (S)%101 70-130 12/19/15 01:26
Toluene-d8 (S)%105 70-130 12/19/15 01:26
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1633239LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 49.450 99 80-125
1,1,1-Trichloroethane ug/L 49.350 99 71-129
1,1,2,2-Tetrachloroethane ug/L 48.950 98 79-124
1,1,2-Trichloroethane ug/L 48.950 98 85-125
1,1-Dichloroethane ug/L 47.450 95 73-126
1,1-Dichloroethene ug/L 45.850 92 66-135
1,1-Dichloropropene ug/L 48.050 96 74-135
1,2,3-Trichloropropane ug/L 48.850 98 75-130
1,2,4-Trichlorobenzene ug/L 45.050 90 75-134
1,2-Dibromo-3-chloropropane ug/L 47.450 95 71-133
1,2-Dibromoethane (EDB)ug/L 52.250 104 83-124
1,2-Dichlorobenzene ug/L 47.550 95 80-133
1,2-Dichloroethane ug/L 45.350 91 67-128
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1633239LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichloropropane ug/L 48.950 98 75-132
1,3-Dichlorobenzene ug/L 47.750 95 77-130
1,3-Dichloropropane ug/L 50.150 100 76-131
1,4-Dichlorobenzene ug/L 48.450 97 78-130
2,2-Dichloropropane ug/L 42.150 84 40-160
2-Butanone (MEK)ug/L 112100 112 61-144
2-Hexanone ug/L 105100 105 68-143
4-Methyl-2-pentanone (MIBK)ug/L 102100 102 72-135
Acetone ug/L 107100 107 48-146
Acetonitrile ug/L 529500 106 62-150
Acrolein ug/L 298250 119 24-160
Acrylonitrile ug/L 254250 101 40-160
Allyl chloride ug/L 49.150 98 66-137
Benzene ug/L 50.150 100 80-125
Bromochloromethane ug/L 50.750 101 71-125
Bromodichloromethane ug/L 46.050 92 78-124
Bromoform ug/L 39.550 79 71-128
Bromomethane ug/L 35.250 70 40-160
Carbon disulfide ug/L 46.7J50 93 50-160
Carbon tetrachloride ug/L 47.350 95 69-131
Chlorobenzene ug/L 48.450 97 81-122
Chloroethane ug/L 36.650 73 39-148
Chloroform ug/L 49.950 100 73-127
Chloromethane ug/L 48.150 96 44-146
Chloroprene ug/L 55.250 110 75-145
cis-1,2-Dichloroethene ug/L 47.150 94 74-124
cis-1,3-Dichloropropene ug/L 49.850 100 72-132
Dibromochloromethane ug/L 50.050 100 78-125
Dibromomethane ug/L 49.550 99 82-120
Dichlorodifluoromethane ug/L 42.250 84 34-157
Ethyl methacrylate ug/L 47.350 95 82-121
Ethylbenzene ug/L 47.150 94 79-121
Hexachloro-1,3-butadiene ug/L 53.650 107 72-131
Iodomethane ug/L 56.4100 56 39-154
Isobutanol ug/L 11101000 111 34-160
Methacrylonitrile ug/L 560500 112 74-134
Methyl methacrylate ug/L 48.250 96 84-124
Methylene Chloride ug/L 55.350 111 64-133
Naphthalene ug/L 45.650 91 73-133
Propionitrile ug/L 524500 105 73-140
Styrene ug/L 46.650 93 84-126
Tetrachloroethene ug/L 48.850 98 78-122
Tetrahydrofuran ug/L 546500 109 69-148
Toluene ug/L 47.350 95 80-121
trans-1,2-Dichloroethene ug/L 48.550 97 71-127
trans-1,3-Dichloropropene ug/L 47.250 94 69-141
trans-1,4-Dichloro-2-butene ug/L 48.6J50 97 40-160
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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[phone]
Page 25 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1633239LABORATORY CONTROL SAMPLE:
LCSSpike
Trichloroethene ug/L 50.650 101 78-122
Trichlorofluoromethane ug/L 42.850 86 53-137
Vinyl acetate ug/L 100100 100 40-160
Vinyl chloride ug/L 49.450 99 58-137
Xylene (Total)ug/L 138150 92 81-126
1,2-Dichloroethane-d4 (S)%92 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%97 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34820
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92279347002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1634031
Associated Lab Samples:92279347002
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 12/20/15 18:490.33
1,1,1-Trichloroethane ug/L ND 1.0 12/20/15 18:490.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 12/20/15 18:490.40
1,1,2-Trichloroethane ug/L ND 1.0 12/20/15 18:490.29
1,1-Dichloroethane ug/L ND 5.0 12/20/15 18:490.32
1,1-Dichloroethene ug/L ND 5.0 12/20/15 18:490.56
1,1-Dichloropropene ug/L ND 5.0 12/20/15 18:490.49
1,2,3-Trichloropropane ug/L ND 1.0 12/20/15 18:490.41
1,2,4-Trichlorobenzene ug/L ND 10.0 12/20/15 18:490.35
1,2-Dibromo-3-chloropropane ug/L ND 13.0 12/20/15 18:492.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/20/15 18:490.27
1,2-Dichlorobenzene ug/L ND 5.0 12/20/15 18:490.30
1,2-Dichloroethane ug/L ND 1.0 12/20/15 18:490.24
1,2-Dichloropropane ug/L ND 1.0 12/20/15 18:490.27
1,3-Dichlorobenzene ug/L ND 5.0 12/20/15 18:490.24
1,3-Dichloropropane ug/L ND 1.0 12/20/15 18:490.28
1,4-Dichlorobenzene ug/L ND 1.0 12/20/15 18:490.33
2,2-Dichloropropane ug/L ND 15.0 12/20/15 18:490.13
2-Butanone (MEK)ug/L ND 100 12/20/15 18:490.96
2-Hexanone ug/L ND 50.0 12/20/15 18:490.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 12/20/15 18:490.33
Acetone ug/L ND 100 12/20/15 18:4910.0
Acetonitrile ug/L ND 55.0 12/20/15 18:492.2
Acrolein ug/L ND 53.0 12/20/15 18:491.6
Acrylonitrile ug/L ND 200 12/20/15 18:491.9
Allyl chloride ug/L ND 10.0 12/20/15 18:491.5
Benzene ug/L ND 1.0 12/20/15 18:490.25
Bromochloromethane ug/L ND 3.0 12/20/15 18:490.17
Bromodichloromethane ug/L ND 1.0 12/20/15 18:490.18
Bromoform ug/L ND 3.0 12/20/15 18:490.26
Bromomethane ug/L ND 10.0 12/20/15 18:490.29
Carbon disulfide ug/L ND 100 12/20/15 18:491.2
Carbon tetrachloride ug/L ND 1.0 12/20/15 18:490.25
Chlorobenzene ug/L ND 3.0 12/20/15 18:490.23
Chloroethane ug/L ND 10.0 12/20/15 18:490.54
Chloroform ug/L ND 5.0 12/20/15 18:490.14
Chloromethane ug/L ND 1.0 12/20/15 18:490.11
Chloroprene ug/L ND 20.0 12/20/15 18:490.27
cis-1,2-Dichloroethene ug/L ND 5.0 12/20/15 18:490.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/20/15 18:490.13
Dibromochloromethane ug/L ND 3.0 12/20/15 18:490.21
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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[phone]
Page 27 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1634031
Associated Lab Samples:92279347002
Matrix:Water
AnalyzedMDL
Dibromomethane ug/L ND 10.0 12/20/15 18:490.21
Dichlorodifluoromethane ug/L ND 5.0 12/20/15 18:490.21
Ethyl methacrylate ug/L ND 10.0 12/20/15 18:490.20
Ethylbenzene ug/L ND 1.0 12/20/15 18:490.30
Hexachloro-1,3-butadiene ug/L ND 10.0 12/20/15 18:490.71
Iodomethane ug/L ND 10.0 12/20/15 18:490.32
Isobutanol ug/L ND 100 12/20/15 18:4935.0
Methacrylonitrile ug/L ND 100 12/20/15 18:490.93
Methyl methacrylate ug/L ND 30.0 12/20/15 18:492.0
Methylene Chloride ug/L ND 1.0 12/20/15 18:490.97
Naphthalene ug/L ND 10.0 12/20/15 18:490.24
Propionitrile ug/L ND 150 12/20/15 18:493.6
Styrene ug/L ND 1.0 12/20/15 18:490.26
Tetrachloroethene ug/L ND 1.0 12/20/15 18:490.46
Tetrahydrofuran ug/L ND 10.0 12/20/15 18:493.1
Toluene ug/L ND 1.0 12/20/15 18:490.26
trans-1,2-Dichloroethene ug/L ND 5.0 12/20/15 18:490.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/20/15 18:490.26
trans-1,4-Dichloro-2-butene ug/L ND 100 12/20/15 18:491.0
Trichloroethene ug/L ND 1.0 12/20/15 18:490.47
Trichlorofluoromethane ug/L ND 1.0 12/20/15 18:490.20
Vinyl acetate ug/L ND 50.0 12/20/15 18:490.35
Vinyl chloride ug/L ND 1.0 12/20/15 18:490.62
Xylene (Total)ug/L ND 5.0 12/20/15 18:490.66
1,2-Dichloroethane-d4 (S)%92 70-130 12/20/15 18:49
4-Bromofluorobenzene (S)%102 70-130 12/20/15 18:49
Toluene-d8 (S)%111 70-130 12/20/15 18:49
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1634032LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.050 100 80-125
1,1,1-Trichloroethane ug/L 52.550 105 71-129
1,1,2,2-Tetrachloroethane ug/L 50.050 100 79-124
1,1,2-Trichloroethane ug/L 52.350 105 85-125
1,1-Dichloroethane ug/L 47.950 96 73-126
1,1-Dichloroethene ug/L 48.150 96 66-135
1,1-Dichloropropene ug/L 50.950 102 74-135
1,2,3-Trichloropropane ug/L 51.150 102 75-130
1,2,4-Trichlorobenzene ug/L 46.250 92 75-134
1,2-Dibromo-3-chloropropane ug/L 47.950 96 71-133
1,2-Dibromoethane (EDB)ug/L 53.950 108 83-124
1,2-Dichlorobenzene ug/L 47.150 94 80-133
1,2-Dichloroethane ug/L 45.250 90 67-128
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
Page 28 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1634032LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichloropropane ug/L 48.250 96 75-132
1,3-Dichlorobenzene ug/L 48.250 96 77-130
1,3-Dichloropropane ug/L 51.550 103 76-131
1,4-Dichlorobenzene ug/L 49.650 99 78-130
2,2-Dichloropropane ug/L 48.650 97 40-160
2-Butanone (MEK)ug/L 109100 109 61-144
2-Hexanone ug/L 99.3100 99 68-143
4-Methyl-2-pentanone (MIBK)ug/L 101100 101 72-135
Acetone ug/L 104100 104 48-146
Acetonitrile ug/L 549500 110 62-150
Acrolein ug/L 305250 122 24-160
Acrylonitrile ug/L 260250 104 40-160
Allyl chloride ug/L 52.450 105 66-137
Benzene ug/L 53.550 107 80-125
Bromochloromethane ug/L 53.350 107 71-125
Bromodichloromethane ug/L 49.450 99 78-124
Bromoform ug/L 40.350 81 71-128
Bromomethane ug/L 40.050 80 40-160
Carbon disulfide ug/L 50.5J50 101 50-160
Carbon tetrachloride ug/L 50.350 101 69-131
Chlorobenzene ug/L 49.350 99 81-122
Chloroethane ug/L 43.650 87 39-148
Chloroform ug/L 49.850 100 73-127
Chloromethane ug/L 50.050 100 44-146
Chloroprene ug/L 55.750 111 75-145
cis-1,2-Dichloroethene ug/L 48.350 97 74-124
cis-1,3-Dichloropropene ug/L 52.650 105 72-132
Dibromochloromethane ug/L 51.250 102 78-125
Dibromomethane ug/L 52.250 104 82-120
Dichlorodifluoromethane ug/L 42.450 85 34-157
Ethyl methacrylate ug/L 45.750 91 82-121
Ethylbenzene ug/L 48.950 98 79-121
Hexachloro-1,3-butadiene ug/L 54.550 109 72-131
Iodomethane ug/L 78.3100 78 39-154
Isobutanol ug/L 9731000 97 34-160
Methacrylonitrile ug/L 541500 108 74-134
Methyl methacrylate ug/L 45.850 92 84-124
Methylene Chloride ug/L 58.350 117 64-133
Naphthalene ug/L 44.750 89 73-133
Propionitrile ug/L 525500 105 73-140
Styrene ug/L 49.450 99 84-126
Tetrachloroethene ug/L 48.950 98 78-122
Tetrahydrofuran ug/L 540500 108 69-148
Toluene ug/L 48.650 97 80-121
trans-1,2-Dichloroethene ug/L 50.150 100 71-127
trans-1,3-Dichloropropene ug/L 49.850 100 69-141
trans-1,4-Dichloro-2-butene ug/L 46.0J50 92 40-160
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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[phone]
Page 29 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1634032LABORATORY CONTROL SAMPLE:
LCSSpike
Trichloroethene ug/L 52.950 106 78-122
Trichlorofluoromethane ug/L 46.350 93 53-137
Vinyl acetate ug/L 101100 101 40-160
Vinyl chloride ug/L 50.050 100 58-137
Xylene (Total)ug/L 144150 96 81-126
1,2-Dichloroethane-d4 (S)%102 70-130
4-Bromofluorobenzene (S)%105 70-130
Toluene-d8 (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/39722
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples:92279347001, 92279347002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1628876
Associated Lab Samples:92279347001, 92279347002
Matrix:Water
AnalyzedMDL
4,4'-DDD ug/L ND 0.10 12/15/15 13:320.050
4,4'-DDE ug/L ND 0.10 12/15/15 13:320.050
4,4'-DDT ug/L ND 0.10 12/15/15 13:320.050
Aldrin ug/L ND 0.050 12/15/15 13:320.050
alpha-BHC ug/L ND 0.050 12/15/15 13:320.050
beta-BHC ug/L ND 0.050 12/15/15 13:320.050
Chlordane (Technical)ug/L ND 0.50 12/15/15 13:320.20
delta-BHC ug/L ND 0.050 12/15/15 13:320.050
Dieldrin ug/L ND 0.075 12/15/15 13:320.050
Endosulfan I ug/L ND 0.10 12/15/15 13:320.050
Endosulfan II ug/L ND 0.10 12/15/15 13:320.050
Endosulfan sulfate ug/L ND 0.10 12/15/15 13:320.050
Endrin ug/L ND 0.10 12/15/15 13:320.050
Endrin aldehyde ug/L ND 0.10 12/15/15 13:320.050
gamma-BHC (Lindane)ug/L ND 0.050 12/15/15 13:320.050
Heptachlor ug/L ND 0.050 12/15/15 13:320.050
Heptachlor epoxide ug/L ND 0.075 12/15/15 13:320.050
Methoxychlor ug/L ND 1.0 12/15/15 13:320.15
Toxaphene ug/L ND 1.5 12/15/15 13:320.20
Decachlorobiphenyl (S)%67 20-130 12/15/15 13:32
Tetrachloro-m-xylene (S)%83 20-130 12/15/15 13:32
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1628877LABORATORY CONTROL SAMPLE:
LCSSpike
4,4'-DDD ug/L 0.24.25 98 20-150
4,4'-DDE ug/L 0.24.25 95 20-150
4,4'-DDT ug/L 0.26.25 104 20-150
Aldrin ug/L 0.22.25 88 20-150
alpha-BHC ug/L 0.23.25 92 20-150
beta-BHC ug/L 0.24.25 95 20-150
delta-BHC ug/L 0.25.25 99 20-150
Dieldrin ug/L 0.24.25 98 20-150
Endosulfan I ug/L 0.24.25 96 20-150
Endosulfan II ug/L 0.25.25 99 20-150
Endosulfan sulfate ug/L 0.25.25 101 20-150
Endrin ug/L 0.25.25 102 20-150
Endrin aldehyde ug/L 0.23.25 94 20-150
gamma-BHC (Lindane)ug/L 0.23.25 94 20-150
Heptachlor ug/L 0.22.25 88 20-150
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
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Page 31 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1628877LABORATORY CONTROL SAMPLE:
LCSSpike
Heptachlor epoxide ug/L 0.23.25 95 20-150
Methoxychlor ug/L 0.75J.74 101 20-150
Decachlorobiphenyl (S)%78 20-130
Tetrachloro-m-xylene (S)%90 20-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1628878MATRIX SPIKE SAMPLE:
MSSpike
Result
92279302002
4,4'-DDD ug/L 0.20.25 81 20-150ND
4,4'-DDE ug/L 0.20.25 80 20-150ND
4,4'-DDT ug/L 0.21.25 83 20-150ND
Aldrin ug/L 0.18.25 71 20-150ND
alpha-BHC ug/L 0.20.25 79 20-150ND
beta-BHC ug/L 0.21.25 84 20-150ND
delta-BHC ug/L 0.21.25 86 20-150ND
Dieldrin ug/L 0.20.25 81 20-150ND
Endosulfan I ug/L 0.20.25 79 20-150ND
Endosulfan II ug/L 0.21.25 84 20-150ND
Endosulfan sulfate ug/L 0.21.25 83 20-150ND
Endrin ug/L 0.20.25 81 20-150ND
Endrin aldehyde ug/L 0.19.25 79 20-150ND
gamma-BHC (Lindane)ug/L 0.20.25 81 20-150ND
Heptachlor ug/L 0.18.25 71 20-150ND
Heptachlor epoxide ug/L 0.19.25 78 20-150ND
Methoxychlor ug/L 0.61J.74 82 20-150ND
Decachlorobiphenyl (S)%77 20-130
Tetrachloro-m-xylene (S)%72 20-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92279304003
1628879SAMPLE DUPLICATE:
4,4'-DDD ug/L ND 30ND
4,4'-DDE ug/L ND 30ND
4,4'-DDT ug/L ND 30ND
Aldrin ug/L ND 30ND
alpha-BHC ug/L ND 30ND
beta-BHC ug/L ND 30ND
Chlordane (Technical)ug/L ND 30ND
delta-BHC ug/L ND 30ND
Dieldrin ug/L ND 30ND
Endosulfan I ug/L ND 30ND
Endosulfan II ug/L ND 30ND
Endosulfan sulfate ug/L ND 30ND
Endrin ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
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[phone]
Page 32 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92279304003
1628879SAMPLE DUPLICATE:
Endrin aldehyde ug/L ND 30ND
gamma-BHC (Lindane)ug/L ND 30ND
Heptachlor ug/L ND 30ND
Heptachlor epoxide ug/L ND 30ND
Methoxychlor ug/L ND 30ND
Toxaphene ug/L ND 30ND
Decachlorobiphenyl (S)%84 1671
Tetrachloro-m-xylene (S)%50 552
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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[phone]
Page 33 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/39678
EPA 3510
EPA 8082
8082 GCS PCB
Associated Lab Samples:92279347001, 92279347002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1627957
Associated Lab Samples:92279347001, 92279347002
Matrix:Water
AnalyzedMDL
PCB-1016 (Aroclor 1016)ug/L ND 0.50 12/15/15 05:040.50
PCB-1221 (Aroclor 1221)ug/L ND 0.50 12/15/15 05:040.50
PCB-1232 (Aroclor 1232)ug/L ND 0.50 12/15/15 05:040.50
PCB-1242 (Aroclor 1242)ug/L ND 0.50 12/15/15 05:040.50
PCB-1248 (Aroclor 1248)ug/L ND 0.50 12/15/15 05:040.50
PCB-1254 (Aroclor 1254)ug/L ND 0.50 12/15/15 05:040.50
PCB-1260 (Aroclor 1260)ug/L ND 0.50 12/15/15 05:040.50
Decachlorobiphenyl (S)%85 10-132 12/15/15 05:04
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1627958LABORATORY CONTROL SAMPLE:
LCSSpike
PCB-1016 (Aroclor 1016)ug/L 4.25 83 50-150
PCB-1260 (Aroclor 1260)ug/L 4.55 90 50-150
Decachlorobiphenyl (S)%90 10-132
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1627959MATRIX SPIKE SAMPLE:
MSSpike
Result
92279347001
PCB-1016 (Aroclor 1016)ug/L 3.45 67 50-150ND
PCB-1260 (Aroclor 1260)ug/L 3.65 72 50-150ND
Decachlorobiphenyl (S)%79 10-132
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92279347002
1627960SAMPLE DUPLICATE:
PCB-1016 (Aroclor 1016)ug/L ND 30ND
PCB-1221 (Aroclor 1221)ug/L ND 30ND
PCB-1232 (Aroclor 1232)ug/L ND 30ND
PCB-1242 (Aroclor 1242)ug/L ND 30ND
PCB-1248 (Aroclor 1248)ug/L ND 30ND
PCB-1254 (Aroclor 1254)ug/L ND 30ND
PCB-1260 (Aroclor 1260)ug/L ND 30ND
Decachlorobiphenyl (S)%66 1457
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/25723
EPA 8151
EPA 8151
8151A GCS Herbicides
Associated Lab Samples:92279347001, 92279347002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1420527
Associated Lab Samples:92279347001, 92279347002
Matrix:Water
AnalyzedMDL
2,4,5-T ug/L ND 0.19 12/17/15 17:070.042
2,4,5-TP (Silvex)ug/L ND 0.19 12/17/15 17:070.049
2,4-D ug/L ND 0.94 12/17/15 17:070.22
Dinoseb ug/L ND 0.19 12/17/15 17:070.057
2,4-DCAA (S)%53 36-130 12/17/15 17:07
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1420528LABORATORY CONTROL SAMPLE:
LCSSpike
2,4,5-T ug/L 0.791.2 66 40-130
2,4,5-TP (Silvex)ug/L 1.11.2 94 58-130
2,4-D ug/L 3.76 62 42-134
Dinoseb ug/L 0.841.2 70 10-157
2,4-DCAA (S)%77 36-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1424270MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279201003
1424271
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2,4,5-T ug/L 1.2 88 40-13062 35 401.2ND 1.1 0.74
2,4,5-TP (Silvex)ug/L 1.2 104 58-13069 40 401.2ND 1.2 0.83
2,4-D ug/L 6 88 42-13459 39 406ND5.3 3.6
Dinoseb ug/L R11.2 73 10-15748 41 401.2ND 0.88 0.58
2,4-DCAA (S)%81 36-13058 40
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/39746
EPA 3510
EPA 8270
8270 Water MSSV
Associated Lab Samples:92279347001, 92279347002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1629825
Associated Lab Samples:92279347001, 92279347002
Matrix:Water
AnalyzedMDL
1,2,4,5-Tetrachlorobenzene ug/L ND 10.0 12/21/15 16:141.7
1,3,5-Trinitrobenzene ug/L ND 10.0 12/21/15 16:141.1
1,3-Dinitrobenzene ug/L ND 20.0 12/21/15 16:141.5
1,4-Naphthoquinone ug/L ND 10.0 12/21/15 16:141.8
1-Naphthalenamine ug/L ND 10.0 12/21/15 16:140.96
2,3,4,6-Tetrachlorophenol ug/L ND 10.0 12/21/15 16:142.3
2,4,5-Trichlorophenol ug/L ND 10.0 12/21/15 16:142.2
2,4,6-Trichlorophenol ug/L ND 10.0 12/21/15 16:141.9
2,4-Dichlorophenol ug/L ND 10.0 12/21/15 16:141.7
2,4-Dimethylphenol ug/L ND 10.0 12/21/15 16:142.2
2,4-Dinitrophenol ug/L ND 50.0 12/21/15 16:146.5
2,4-Dinitrotoluene ug/L ND 10.0 12/21/15 16:141.2
2,6-Dichlorophenol ug/L ND 10.0 12/21/15 16:141.8
2,6-Dinitrotoluene ug/L ND 10.0 12/21/15 16:141.7
2-Acetylaminofluorene ug/L ND 20.0 12/21/15 16:140.84
2-Chloronaphthalene ug/L ND 10.0 12/21/15 16:142.2
2-Chlorophenol ug/L ND 10.0 12/21/15 16:141.5
2-Methylnaphthalene ug/L ND 10.0 12/21/15 16:140.28
2-Methylphenol(o-Cresol)ug/L ND 10.0 12/21/15 16:141.7
2-Naphthalenamine ug/L ND 10.0 12/21/15 16:140.98
2-Nitroaniline ug/L ND 50.0 12/21/15 16:142.8
2-Nitrophenol ug/L ND 10.0 12/21/15 16:141.7
3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 12/21/15 16:141.7
3,3'-Dichlorobenzidine ug/L ND 20.0 12/21/15 16:141.4
3,3'-Dimethylbenzidine ug/L ND 10.0 12/21/15 16:142.1
3-Methylcholanthrene ug/L ND 10.0 12/21/15 16:140.82
3-Nitroaniline ug/L ND 50.0 12/21/15 16:142.4
4,6-Dinitro-2-methylphenol ug/L ND 50.0 12/21/15 16:141.7
4-Aminobiphenyl ug/L ND 20.0 12/21/15 16:140.92
4-Bromophenylphenyl ether ug/L ND 10.0 12/21/15 16:141.3
4-Chloro-3-methylphenol ug/L ND 20.0 12/21/15 16:144.2
4-Chloroaniline ug/L ND 20.0 12/21/15 16:143.4
4-Chlorophenylphenyl ether ug/L ND 10.0 12/21/15 16:142.1
4-Nitroaniline ug/L ND 20.0 12/21/15 16:142.5
4-Nitrophenol ug/L ND 50.0 12/21/15 16:145.8
5-Nitro-o-toluidine ug/L ND 10.0 12/21/15 16:141.2
7,12-Dimethylbenz(a)anthracene ug/L ND 10.0 12/21/15 16:140.77
Acenaphthene ug/L ND 10.0 12/21/15 16:140.25
Acenaphthylene ug/L ND 10.0 12/21/15 16:140.21
Acetophenone ug/L ND 10.0 12/21/15 16:142.0
Anthracene ug/L ND 10.0 12/21/15 16:140.14
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
Page 36 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1629825
Associated Lab Samples:92279347001, 92279347002
Matrix:Water
AnalyzedMDL
Benzo(a)anthracene ug/L ND 10.0 12/21/15 16:140.33
Benzo(a)pyrene ug/L ND 10.0 12/21/15 16:140.30
Benzo(b)fluoranthene ug/L ND 10.0 12/21/15 16:140.28
Benzo(g,h,i)perylene ug/L ND 10.0 12/21/15 16:140.38
Benzo(k)fluoranthene ug/L ND 10.0 12/21/15 16:140.43
Benzyl alcohol ug/L ND 20.0 12/21/15 16:143.4
bis(2-Chloroethoxy)methane ug/L ND 10.0 12/21/15 16:141.7
bis(2-Chloroethyl) ether ug/L ND 10.0 12/21/15 16:141.5
bis(2-Chloroisopropyl) ether ug/L ND 10.0 12/21/15 16:141.6
bis(2-Ethylhexyl)phthalate ug/L ND 15.0 12/21/15 16:140.85
Butylbenzylphthalate ug/L ND 10.0 12/21/15 16:140.75
Chlorobenzilate ug/L ND 10.0 12/21/15 16:140.72
Chrysene ug/L ND 10.0 12/21/15 16:140.21
Di-n-butylphthalate ug/L ND 10.0 12/21/15 16:141.1
Di-n-octylphthalate ug/L ND 10.0 12/21/15 16:140.86
Diallate ug/L ND 10.0 12/21/15 16:141.3
Dibenz(a,h)anthracene ug/L ND 10.0 12/21/15 16:140.55
Dibenzofuran ug/L ND 10.0 12/21/15 16:141.8
Diethylphthalate ug/L ND 6000 12/21/15 16:141.3
Dimethoate ug/L ND 20.0 12/21/15 16:140.92
Dimethylphthalate ug/L ND 10.0 12/21/15 16:141.5
Diphenylamine ug/L ND 10.0 12/21/15 16:141.3
Disulfoton ug/L ND 10.0 12/21/15 16:141.4
Ethyl methanesulfonate ug/L ND 20.0 12/21/15 16:141.8
Famphur ug/L ND 20.0 12/21/15 16:141.7
Fluoranthene ug/L ND 10.0 12/21/15 16:140.21
Fluorene ug/L ND 10.0 12/21/15 16:140.21
Hexachlorobenzene ug/L ND 10.0 12/21/15 16:141.1
Hexachlorocyclopentadiene ug/L ND 10.0 12/21/15 16:141.8
Hexachloroethane ug/L ND 10.0 12/21/15 16:141.5
Hexachloropropene ug/L ND 10.0 12/21/15 16:141.6
Indeno(1,2,3-cd)pyrene ug/L ND 10.0 12/21/15 16:140.29
Isodrin ug/L ND 20.0 12/21/15 16:142.0
Isophorone ug/L ND 10.0 12/21/15 16:141.8
Isosafrole ug/L ND 10.0 12/21/15 16:141.8
Kepone ug/L ND 20.0 12/21/15 16:143.1
Methapyrilene ug/L ND 100 12/21/15 16:142.7
Methyl methanesulfonate ug/L ND 10.0 12/21/15 16:141.3
Methyl parathion ug/L ND 10.0 12/21/15 16:141.1
N-Nitroso-di-n-butylamine ug/L ND 10.0 12/21/15 16:142.2
N-Nitroso-di-n-propylamine ug/L ND 10.0 12/21/15 16:142.1
N-Nitrosodiethylamine ug/L ND 20.0 12/21/15 16:141.8
N-Nitrosodimethylamine ug/L ND 10.0 12/21/15 16:141.3
N-Nitrosodiphenylamine ug/L ND 10.0 12/21/15 16:141.3
N-Nitrosomethylethylamine ug/L ND 10.0 12/21/15 16:141.8
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
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Page 37 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1629825
Associated Lab Samples:92279347001, 92279347002
Matrix:Water
AnalyzedMDL
N-Nitrosopiperidine ug/L ND 20.0 12/21/15 16:141.9
N-Nitrosopyrrolidine ug/L ND 10.0 12/21/15 16:142.5
Nitrobenzene ug/L ND 10.0 12/21/15 16:141.7
O,O,O-Triethylphosphorothioate ug/L ND 10.0 12/21/15 16:141.8
O-Toluidine ug/L ND 10.0 12/21/15 16:141.6
P-Dimethylaminoazobenzene ug/L ND 10.0 12/21/15 16:140.35
p-Phenylenediamine ug/L ND 10.0 12/21/15 16:140.96
Parathion (Ethyl parathion)ug/L ND 10.0 12/21/15 16:141.1
Pentachlorobenzene ug/L ND 10.0 12/21/15 16:142.0
Pentachloronitrobenzene ug/L ND 20.0 12/21/15 16:141.0
Pentachlorophenol ug/L ND 25.0 12/21/15 16:142.3
Phenacetin ug/L ND 20.0 12/21/15 16:140.97
Phenanthrene ug/L ND 10.0 12/21/15 16:140.22
Phenol ug/L ND 10.0 12/21/15 16:141.7
Phorate ug/L ND 10.0 12/21/15 16:141.1
Pronamide ug/L ND 10.0 12/21/15 16:140.97
Pyrene ug/L ND 10.0 12/21/15 16:140.19
Safrole ug/L ND 10.0 12/21/15 16:141.5
Thionazin ug/L ND 20.0 12/21/15 16:141.2
2,4,6-Tribromophenol (S)%94 27-110 12/21/15 16:14
2-Fluorobiphenyl (S)%73 27-110 12/21/15 16:14
2-Fluorophenol (S)%38 12-110 12/21/15 16:14
Nitrobenzene-d5 (S)%84 21-110 12/21/15 16:14
Phenol-d6 (S)%21 10-110 12/21/15 16:14
Terphenyl-d14 (S)%97 31-107 12/21/15 16:14
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1629826LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4,5-Tetrachlorobenzene ug/L 28.650 57 16-129
1,3,5-Trinitrobenzene ug/L 64.1 L05012855-125
1,3-Dinitrobenzene ug/L 42.850 86 30-122
1,4-Naphthoquinone ug/L 35.650 71 31-120
1-Naphthalenamine ug/L 31.150 62 37-126
2,3,4,6-Tetrachlorophenol ug/L 91.350 183 54-276
2,4,5-Trichlorophenol ug/L 34.750 69 43-113
2,4,6-Trichlorophenol ug/L 35.850 72 42-120
2,4-Dichlorophenol ug/L 51.450 103 30-120
2,4-Dimethylphenol ug/L 41.850 84 29-111
2,4-Dinitrophenol ug/L 263250 105 19-132
2,4-Dinitrotoluene ug/L 51.250 102 58-128
2,6-Dichlorophenol ug/L 45.750 91 54-128
2,6-Dinitrotoluene ug/L 41.450 83 54-129
2-Acetylaminofluorene ug/L 49.050 98 81-160
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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[phone]
Page 38 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1629826LABORATORY CONTROL SAMPLE:
LCSSpike
2-Chloronaphthalene ug/L 34.750 69 43-117
2-Chlorophenol ug/L 34.450 69 37-120
2-Methylnaphthalene ug/L 35.850 72 33-120
2-Methylphenol(o-Cresol)ug/L 21.850 44 31-120
2-Naphthalenamine ug/L 36.050 72 41-136
2-Nitroaniline ug/L 51.0100 51 48-121
2-Nitrophenol ug/L 48.250 96 25-116
3&4-Methylphenol(m&p Cresol)ug/L 51.250 102 23-120
3,3'-Dichlorobenzidine ug/L 89.4250 36 10-154
3,3'-Dimethylbenzidine ug/L 10.4100 10 10-157
3-Methylcholanthrene ug/L 42.250 84 65-130
3-Nitroaniline ug/L 95.2100 95 43-115
4,6-Dinitro-2-methylphenol ug/L 101100 101 44-124
4-Aminobiphenyl ug/L 33.050 66 21-125
4-Bromophenylphenyl ether ug/L 46.250 92 34-113
4-Chloro-3-methylphenol ug/L 80.9100 81 31-110
4-Chloroaniline ug/L 68.3100 68 20-120
4-Chlorophenylphenyl ether ug/L 32.550 65 34-116
4-Nitroaniline ug/L 73.8100 74 46-128
4-Nitrophenol ug/L 104250 42 11-120
5-Nitro-o-toluidine ug/L 44.350 89 78-160
7,12-Dimethylbenz(a)anthracene ug/L 47.350 95 47-124
Acenaphthene ug/L 43.650 87 48-114
Acenaphthylene ug/L 40.850 82 48-112
Acetophenone ug/L 27.950 56 24-120
Anthracene ug/L 48.450 97 57-118
Benzo(a)anthracene ug/L 49.550 99 56-121
Benzo(a)pyrene ug/L 46.850 94 55-127
Benzo(b)fluoranthene ug/L 42.450 85 53-128
Benzo(g,h,i)perylene ug/L 37.150 74 54-125
Benzo(k)fluoranthene ug/L 51.950 104 51-123
Benzyl alcohol ug/L 60.9100 61 27-120
bis(2-Chloroethoxy)methane ug/L 48.250 96 32-120
bis(2-Chloroethyl) ether ug/L 29.750 59 33-111
bis(2-Chloroisopropyl) ether ug/L 11.650 23 15-120
bis(2-Ethylhexyl)phthalate ug/L 58.750 117 50-145
Butylbenzylphthalate ug/L 58.250 116 54-138
Chlorobenzilate ug/L 55.950 112 65-132
Chrysene ug/L 48.950 98 58-127
Di-n-butylphthalate ug/L 59.550 119 56-125
Di-n-octylphthalate ug/L 52.250 104 50-134
Diallate ug/L 47.450 95 47-123
Dibenz(a,h)anthracene ug/L 36.950 74 53-129
Dibenzofuran ug/L 43.250 86 45-120
Diethylphthalate ug/L 41.6J50 83 53-120
Dimethoate ug/L 46.250 92 57-139
Dimethylphthalate ug/L 37.050 74 55-116
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
Page 39 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1629826LABORATORY CONTROL SAMPLE:
LCSSpike
Diphenylamine ug/L 47.050 94 42-120
Disulfoton ug/L 45.550 91 49-156
Ethyl methanesulfonate ug/L 42.250 84 43-120
Famphur ug/L 73.0100 73 40-160
Fluoranthene ug/L 64.6 L05012957-125
Fluorene ug/L 36.650 73 53-118
Hexachlorobenzene ug/L 51.250 102 49-116
Hexachlorocyclopentadiene ug/L 16.950 34 26-158
Hexachloroethane ug/L 32.050 64 30-114
Hexachloropropene ug/L 30.850 62 13-137
Indeno(1,2,3-cd)pyrene ug/L 37.350 75 55-128
Isodrin ug/L 66.4 L05013368-129
Isophorone ug/L 42.050 84 31-118
Isosafrole ug/L 34.050 68 48-107
Kepone ug/L 39.2100 39 10-124
Methapyrilene ug/L 3.6J L050740-160
Methyl methanesulfonate ug/L 23.650 47 25-114
Methyl parathion ug/L 52.750 105 58-137
N-Nitroso-di-n-butylamine ug/L 32.550 65 36-115
N-Nitroso-di-n-propylamine ug/L 24.850 50 32-119
N-Nitrosodiethylamine ug/L 40.350 81 47-115
N-Nitrosodimethylamine ug/L 19.250 38 13-120
N-Nitrosodiphenylamine ug/L 47.050 94 43-120
N-Nitrosomethylethylamine ug/L 31.750 63 39-120
N-Nitrosopiperidine ug/L 55.250 110 43-113
N-Nitrosopyrrolidine ug/L 32.150 64 32-110
Nitrobenzene ug/L 40.750 81 33-110
O,O,O-Triethylphosphorothioate ug/L 49.450 99 51-127
O-Toluidine ug/L 31.050 62 27-120
P-Dimethylaminoazobenzene ug/L 27.3100 27 10-120
p-Phenylenediamine ug/L 50.450 101 72-143
Parathion (Ethyl parathion)ug/L 51.550 103 56-140
Pentachlorobenzene ug/L 42.650 85 30-137
Pentachloronitrobenzene ug/L 55.550 111 70-124
Pentachlorophenol ug/L 92.5250 37 10-137
Phenacetin ug/L 51.350 103 60-130
Phenanthrene ug/L 46.450 93 57-117
Phenol ug/L 15.250 30 10-120
Phorate ug/L 63.4 L05012755-126
Pronamide ug/L 60.450 121 75-124
Pyrene ug/L 56.250 112 55-122
Safrole ug/L 39.050 78 41-120
Thionazin ug/L 36.750 73 63-137
2,4,6-Tribromophenol (S)%S011527-110
2-Fluorobiphenyl (S)%62 27-110
2-Fluorophenol (S)%38 12-110
Nitrobenzene-d5 (S)%95 21-110
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
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9800 Kincey Ave. Suite 100
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[phone]
Page 40 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1629826LABORATORY CONTROL SAMPLE:
LCSSpike
Phenol-d6 (S)%26 10-110
Terphenyl-d14 (S)%104 31-107
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1629827MATRIX SPIKE SAMPLE:
MSSpike
Result
92278963015
1,2,4,5-Tetrachlorobenzene ug/L 28.450 57 50-150ND
1,3,5-Trinitrobenzene ug/L 57.150 114 50-150ND
1,3-Dinitrobenzene ug/L 45.450 91 50-150ND
1,4-Naphthoquinone ug/L 35.950 72 50-150ND
1-Naphthalenamine ug/L 27.550 55 50-150ND
2,3,4,6-Tetrachlorophenol ug/L 66.050 132 50-150ND
2,4,5-Trichlorophenol ug/L 30.150 60 19-105ND
2,4,6-Trichlorophenol ug/L 30.750 61 13-108ND
2,4-Dichlorophenol ug/L 32.650 65 29-111ND
2,4-Dimethylphenol ug/L 28.050 56 21-103ND
2,4-Dinitrophenol ug/L 126250 50 10-109ND
2,4-Dinitrotoluene ug/L 42.850 86 27-104ND
2,6-Dichlorophenol ug/L 43.350 87 50-150ND
2,6-Dinitrotoluene ug/L 43.850 88 28-101ND
2-Acetylaminofluorene ug/L 45.350 91 50-150ND
2-Chloronaphthalene ug/L 32.950 66 14-102ND
2-Chlorophenol ug/L 37.050 74 16-110ND
2-Methylnaphthalene ug/L 29.850 60 13-110ND
2-Methylphenol(o-Cresol)ug/L 32.950 66 19-110ND
2-Naphthalenamine ug/L 29.750 59 50-150ND
2-Nitroaniline ug/L 44.5J100 45 26-103ND
2-Nitrophenol ug/L 32.250 64 20-110ND
3&4-Methylphenol(m&p Cresol)ug/L 67.1 M15013420-110ND
3,3'-Dichlorobenzidine ug/L 88.3250 35 25-112ND
3,3'-Dimethylbenzidine ug/L 58.1100 58 50-150ND
3-Methylcholanthrene ug/L 44.250 77 50-1505.4J
3-Nitroaniline ug/L 79.0100 79 29-110ND
4,6-Dinitro-2-methylphenol ug/L 84.3100 84 10-117ND
4-Aminobiphenyl ug/L 41.850 84 50-150ND
4-Bromophenylphenyl ether ug/L 40.650 81 20-105ND
4-Chloro-3-methylphenol ug/L 64.6100 65 22-110ND
4-Chloroaniline ug/L 71.4100 71 20-100ND
4-Chlorophenylphenyl ether ug/L 30.850 62 19-102ND
4-Nitroaniline ug/L 67.3100 67 29-110ND
4-Nitrophenol ug/L 62.9250 25 10-110ND
5-Nitro-o-toluidine ug/L 39.050 78 50-150ND
7,12-Dimethylbenz(a)anthracene ug/L 49.950 100 50-150ND
Acenaphthene ug/L 41.350 83 17-100ND
Acenaphthylene ug/L 41.350 83 21-100ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1629827MATRIX SPIKE SAMPLE:
MSSpike
Result
92278963015
Acetophenone ug/L 41.650 83 50-150ND
Anthracene ug/L 44.450 89 24-109ND
Benzo(a)anthracene ug/L 45.850 92 22-117ND
Benzo(a)pyrene ug/L 45.050 90 23-104ND
Benzo(b)fluoranthene ug/L 45.850 92 23-103ND
Benzo(g,h,i)perylene ug/L 38.750 77 18-111ND
Benzo(k)fluoranthene ug/L 53.250 106 22-113ND
Benzyl alcohol ug/L 64.2100 64 19-101ND
bis(2-Chloroethoxy)methane ug/L 24.750 49 22-110ND
bis(2-Chloroethyl) ether ug/L 29.850 60 16-110ND
bis(2-Chloroisopropyl) ether ug/L 23.650 47 14-110ND
bis(2-Ethylhexyl)phthalate ug/L 58.8 M15011823-102ND
Butylbenzylphthalate ug/L 60.3 M15012125-110ND
Chlorobenzilate ug/L 54.950 110 50-150ND
Chrysene ug/L 44.350 89 23-115ND
Di-n-butylphthalate ug/L 59.4 M15011926-110ND
Di-n-octylphthalate ug/L 42.450 85 22-110ND
Diallate ug/L 39.150 78 50-150ND
Dibenz(a,h)anthracene ug/L 45.750 91 21-112ND
Dibenzofuran ug/L 37.950 76 19-102ND
Diethylphthalate ug/L 34.5J50 69 29-110ND
Dimethoate ug/L 40.450 81 50-150ND
Dimethylphthalate ug/L 41.650 83 27-110ND
Diphenylamine ug/L 48.350 97 50-150ND
Disulfoton ug/L 43.150 86 50-150ND
Ethyl methanesulfonate ug/L 28.850 58 50-150ND
Famphur ug/L 35.6 M11003650-150ND
Fluoranthene ug/L 63.2 M05012623-112ND
Fluorene ug/L 33.350 67 22-104ND
Hexachlorobenzene ug/L 46.950 94 21-116ND
Hexachlorocyclopentadiene ug/L 16.550 33 10-110ND
Hexachloroethane ug/L 33.850 68 10-110ND
Hexachloropropene ug/L 32.050 64 50-150ND
Indeno(1,2,3-cd)pyrene ug/L 47.050 94 20-113ND
Isodrin ug/L 66.050 132 50-150ND
Isophorone ug/L 24.6 M1504950-150ND
Isosafrole ug/L 33.950 68 50-150ND
Kepone ug/L 44.0 M11004450-150ND
Methapyrilene ug/L 42.3J50 85 50-150ND
Methyl methanesulfonate ug/L 27.450 55 50-150ND
Methyl parathion ug/L 47.650 95 50-150ND
N-Nitroso-di-n-butylamine ug/L 24.0 M1504850-150ND
N-Nitroso-di-n-propylamine ug/L 38.950 78 21-105ND
N-Nitrosodiethylamine ug/L 30.550 61 50-150ND
N-Nitrosodimethylamine ug/L 19.550 39 10-110ND
N-Nitrosodiphenylamine ug/L 48.350 97 23-107ND
N-Nitrosomethylethylamine ug/L 31.850 64 50-150ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1629827MATRIX SPIKE SAMPLE:
MSSpike
Result
92278963015
N-Nitrosopiperidine ug/L 32.150 64 50-150ND
N-Nitrosopyrrolidine ug/L 46.750 93 50-150ND
Nitrobenzene ug/L 22.650 45 20-110ND
O,O,O-Triethylphosphorothioate ug/L 33.150 66 50-150ND
O-Toluidine ug/L 41.450 83 50-150ND
P-Dimethylaminoazobenzene ug/L 25.8 M11002650-150ND
p-Phenylenediamine ug/L 38.550 77 50-150ND
Parathion (Ethyl parathion)ug/L 63.650 127 50-150ND
Pentachlorobenzene ug/L 37.750 75 50-150ND
Pentachloronitrobenzene ug/L 50.850 102 50-150ND
Pentachlorophenol ug/L 80.7250 32 10-118ND
Phenacetin ug/L 47.450 95 50-150ND
Phenanthrene ug/L 43.150 86 24-106ND
Phenol ug/L 13.050 26 12-110ND
Phorate ug/L 56.550 113 50-150ND
Pronamide ug/L 55.750 111 50-150ND
Pyrene ug/L 53.050 106 24-114ND
Safrole ug/L 33.150 66 50-150ND
Thionazin ug/L 34.350 69 50-150ND
2,4,6-Tribromophenol (S)%99 27-110
2-Fluorobiphenyl (S)%57 27-110
2-Fluorophenol (S)%26 12-110
Nitrobenzene-d5 (S)%49 21-110
Phenol-d6 (S)%21 10-110
Terphenyl-d14 (S)%90 31-107
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278963016
1629828SAMPLE DUPLICATE:
1,2,4,5-Tetrachlorobenzene ug/L ND 30ND
1,3,5-Trinitrobenzene ug/L ND 30ND
1,3-Dinitrobenzene ug/L ND 30ND
1,4-Naphthoquinone ug/L ND 30ND
1-Naphthalenamine ug/L ND 30ND
2,3,4,6-Tetrachlorophenol ug/L ND 30ND
2,4,5-Trichlorophenol ug/L ND 30ND
2,4,6-Trichlorophenol ug/L ND 30ND
2,4-Dichlorophenol ug/L ND 30ND
2,4-Dimethylphenol ug/L ND 30ND
2,4-Dinitrophenol ug/L ND 30ND
2,4-Dinitrotoluene ug/L ND 30ND
2,6-Dichlorophenol ug/L ND 30ND
2,6-Dinitrotoluene ug/L ND 30ND
2-Acetylaminofluorene ug/L ND 30ND
2-Chloronaphthalene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278963016
1629828SAMPLE DUPLICATE:
2-Chlorophenol ug/L ND 30ND
2-Methylnaphthalene ug/L ND 30ND
2-Methylphenol(o-Cresol)ug/L ND 30ND
2-Naphthalenamine ug/L ND 30ND
2-Nitroaniline ug/L ND 30ND
2-Nitrophenol ug/L ND 30ND
3&4-Methylphenol(m&p Cresol)ug/L ND 30ND
3,3'-Dichlorobenzidine ug/L ND 30ND
3,3'-Dimethylbenzidine ug/L ND 30ND
3-Methylcholanthrene ug/L ND 30ND
3-Nitroaniline ug/L ND 30ND
4,6-Dinitro-2-methylphenol ug/L ND 30ND
4-Aminobiphenyl ug/L ND 30ND
4-Bromophenylphenyl ether ug/L ND 30ND
4-Chloro-3-methylphenol ug/L ND 30ND
4-Chloroaniline ug/L ND 30ND
4-Chlorophenylphenyl ether ug/L ND 30ND
4-Nitroaniline ug/L ND 30ND
4-Nitrophenol ug/L ND 30ND
5-Nitro-o-toluidine ug/L NDND
7,12-Dimethylbenz(a)anthracene ug/L ND 30ND
Acenaphthene ug/L ND 30ND
Acenaphthylene ug/L ND 30ND
Acetophenone ug/L ND 30ND
Anthracene ug/L ND 30ND
Benzo(a)anthracene ug/L ND 30ND
Benzo(a)pyrene ug/L ND 30ND
Benzo(b)fluoranthene ug/L ND 30ND
Benzo(g,h,i)perylene ug/L ND 30ND
Benzo(k)fluoranthene ug/L ND 30ND
Benzyl alcohol ug/L ND 30ND
bis(2-Chloroethoxy)methane ug/L ND 30ND
bis(2-Chloroethyl) ether ug/L ND 30ND
bis(2-Chloroisopropyl) ether ug/L ND 30ND
bis(2-Ethylhexyl)phthalate ug/L ND 30ND
Butylbenzylphthalate ug/L ND 30ND
Chlorobenzilate ug/L ND 30ND
Chrysene ug/L ND 30ND
Di-n-butylphthalate ug/L ND 30ND
Di-n-octylphthalate ug/L ND 30ND
Diallate ug/L ND 30ND
Dibenz(a,h)anthracene ug/L ND 30ND
Dibenzofuran ug/L ND 30ND
Diethylphthalate ug/L ND 30ND
Dimethoate ug/L ND 30ND
Dimethylphthalate ug/L ND 30ND
Diphenylamine ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 44 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278963016
1629828SAMPLE DUPLICATE:
Disulfoton ug/L ND 30ND
Ethyl methanesulfonate ug/L ND 30ND
Famphur ug/L ND 30ND
Fluoranthene ug/L ND 30ND
Fluorene ug/L ND 30ND
Hexachlorobenzene ug/L ND 30ND
Hexachlorocyclopentadiene ug/L ND 30ND
Hexachloroethane ug/L ND 30ND
Hexachloropropene ug/L ND 30ND
Indeno(1,2,3-cd)pyrene ug/L ND 30ND
Isodrin ug/L ND 30ND
Isophorone ug/L ND 30ND
Isosafrole ug/L ND 30ND
Kepone ug/L ND 30ND
Methapyrilene ug/L ND 30ND
Methyl methanesulfonate ug/L ND 30ND
Methyl parathion ug/L ND 30ND
N-Nitroso-di-n-butylamine ug/L ND 30ND
N-Nitroso-di-n-propylamine ug/L ND 30ND
N-Nitrosodiethylamine ug/L ND 30ND
N-Nitrosodimethylamine ug/L ND 30ND
N-Nitrosodiphenylamine ug/L ND 30ND
N-Nitrosomethylethylamine ug/L ND 30ND
N-Nitrosopiperidine ug/L ND 30ND
N-Nitrosopyrrolidine ug/L ND 30ND
Nitrobenzene ug/L ND 30ND
O,O,O-Triethylphosphorothioate ug/L ND 30ND
O-Toluidine ug/L ND 30ND
P-Dimethylaminoazobenzene ug/L ND 30ND
p-Phenylenediamine ug/L ND 30ND
Parathion (Ethyl parathion)ug/L ND 30ND
Pentachlorobenzene ug/L ND 30ND
Pentachloronitrobenzene ug/L ND 30ND
Pentachlorophenol ug/L ND 30ND
Phenacetin ug/L ND 30ND
Phenanthrene ug/L ND 30ND
Phenol ug/L ND 30ND
Phorate ug/L ND 30ND
Pronamide ug/L ND 30ND
Pyrene ug/L ND 30ND
Safrole ug/L ND 30ND
Thionazin ug/L ND 30ND
2,4,6-Tribromophenol (S)%64 1070
2-Fluorobiphenyl (S)%65 971
2-Fluorophenol (S)%31 1235
Nitrobenzene-d5 (S)%68 1277
Phenol-d6 (S)%18 1722
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 45 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278963016
1629828SAMPLE DUPLICATE:
Terphenyl-d14 (S)%83 778
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 46 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/41955
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92279347001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1628049
Associated Lab Samples:92279347001
Matrix:Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 12/14/15 13:291000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1628050LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 4850050000 97 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1628051MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278963003
1628052
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L M1,R1500009980-12012 25 2550000150 mg/L 200000 156000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1628053MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278963011
1628054
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L M1500007480-120131 4 2550000596 mg/L 633000 662000
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 47 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/41916
SM 2540C
SM 2540C
2540C Total Dissolved Solids
Associated Lab Samples:92279347001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1626642
Associated Lab Samples:92279347001
Matrix:Water
AnalyzedMDL
Total Dissolved Solids ug/L ND 25000 12/11/15 10:3925000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1626643LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids ug/L 246000250000 98 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92279178001
1626644SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 316000 4 5330 mg/L
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278979001
1626645SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 320000 D675299 mg/L
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
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Page 48 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/41914
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92279347001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1626491
Associated Lab Samples:92279347001
Matrix:Water
AnalyzedMDL
Sulfide ug/L ND 1000 12/11/15 15:00100
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1626492LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide ug/L 504J500 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1626493MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279262001
1626494
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 91 90-11091 0 10500ND457J457J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1626495MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279262011
1626496
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 94 90-11094 0 10500ND470J470J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
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Huntersville, NC 28078
[phone]
Page 49 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/41938
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92279347002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1627829
Associated Lab Samples:92279347002
Matrix:Water
AnalyzedMDL
Sulfide ug/L ND 1000 12/14/15 12:30100
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1627830LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide ug/L 506J500 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1627831MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279347002
1627832
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 92 90-11092 0 10500ND462J462J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1627833MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279409003
1627834
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L M15008990-11089 0 10500ND444J444J
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
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[phone]
Page 50 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/25748
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples:92279347001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1626618
Associated Lab Samples:92279347001
Matrix:Water
AnalyzedMDL
Sulfate ug/L ND 250000 12/11/15 14:061000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1626619LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 21000J20000 105 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1626620MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278963003
1626621
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 103 90-110103 1 102000010.1 mg/L 30600J 30800J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1626622MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279395006
1626623
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 102 90-110104 1 10200009260J29800J30100J
REPORT OF LABORATORY ANALYSIS
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Page 51 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/25851
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples:92279347001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1633380
Associated Lab Samples:92279347001
Matrix:Water
AnalyzedMDL
Chloride ug/L ND 1000 12/18/15 17:52500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1633381LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 1990020000 99 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1633382MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92280333001
1633383
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L 20000 101 90-110101 0 10200003.0 mg/L 23300 23200
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1633384MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279763005
1633385
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M11000006890-11068 0 1010000063.2 mg/L 132000 131000
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
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[phone]
Page 52 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/25788
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples:92279347001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1628959
Associated Lab Samples:92279347001
Matrix:Water
AnalyzedMDL
Cyanide ug/L ND 10.0 12/16/15 10:524.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1628960LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 90.6100 91 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1628961MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279059001
1628962
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 115 75-125116 1 10100ND120121
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1628963MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278760008
1628964
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 102 75-12598 3 101000.0096
mg/L 112 108
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
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Page 53 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/25789
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples:92279347002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1628965
Associated Lab Samples:92279347002
Matrix:Water
AnalyzedMDL
Cyanide ug/L ND 10.0 12/16/15 11:204.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1628966LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 95.2100 95 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1628967MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279219001
1628968
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 109 75-125113 4 10100ND112116
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1628969MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279489002
1628970
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 99 75-125106 7 10100ND102109
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
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Page 54 of 58
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Common Laboratory Contaminant.C9
The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.D6
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.L2
Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples. Results unaffected by high bias.L3
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
Surrogate recovery outside laboratory control limits.S0
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
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Page 55 of 58
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92279347001 OEXT/39722 GCSV/235551203-MW21 EPA 3510 EPA 8081
92279347002 OEXT/39722 GCSV/235551203-FIELD BLANK EPA 3510 EPA 8081
92279347001 OEXT/39678 GCSV/235231203-MW21 EPA 3510 EPA 8082
92279347002 OEXT/39678 GCSV/235231203-FIELD BLANK EPA 3510 EPA 8082
92279347001 OEXT/25723 GCSV/167651203-MW21 EPA 8151 EPA 8151
92279347002 OEXT/25723 GCSV/167651203-FIELD BLANK EPA 8151 EPA 8151
92279347001 MPRP/20260 ICP/182841203-MW21 EPA 3010A EPA 6010
92279347002 MPRP/20260 ICP/182841203-FIELD BLANK EPA 3010A EPA 6010
92279347001 MERP/8788 MERC/84421203-MW21 EPA 7470 EPA 7470
92279347002 MERP/8788 MERC/84421203-FIELD BLANK EPA 7470 EPA 7470
92279347001 OEXT/39746 MSSV/116701203-MW21 EPA 3510 EPA 8270
92279347002 OEXT/39746 MSSV/116701203-FIELD BLANK EPA 3510 EPA 8270
92279347001 MSV/347861203-MW21 EPA 8260
92279347002 MSV/348201203-FIELD BLANK EPA 8260
92279347003 MSV/347861203-TRIP BLANK EPA 8260
92279347001 WET/419551203-MW21 SM 2320B
92279347001 WET/419161203-MW21 SM 2540C
92279347001 WET/419141203-MW21 SM 4500-S2D
92279347002 WET/419381203-FIELD BLANK SM 4500-S2D
92279347001 WETA/257481203-MW21 EPA 300.0
92279347001 WETA/258511203-MW21 SM 4500-Cl-E
92279347001 WETA/257881203-MW21 SM 4500-CN-E
92279347002 WETA/257891203-FIELD BLANK SM 4500-CN-E
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
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Page 56 of 58
Page 57 of 58
Page 58 of 58
#=CL#
February 12, 2016
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92285610
92285610
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
Burke-John's R. Resample
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on February 05, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc:Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
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Page 1 of 15
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92285610
Burke-John's R. Resample
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84Virginia/VELAP Certification #: 460221
Asheville Certification IDs2225 Riverside Drive, Asheville, NC 28804Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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Page 2 of 15
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92285610
Burke-John's R. Resample
Lab ID Sample ID Matrix Date Collected Date Received
92285610001 1203-MW11 Water 02/04/16 12:05 02/05/16 13:35
92285610002 1203-MW12 Water 02/04/16 13:02 02/05/16 13:35
92285610003 1203-FIELD BLANK Water 02/04/16 13:55 02/05/16 13:35
REPORT OF LABORATORY ANALYSIS
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Page 3 of 15
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92285610
Burke-John's R. Resample
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92285610001 1203-MW11 EPA 8081 3 PASI-CSWB
92285610002 1203-MW12 EPA 6010 2 PASI-ACDF
92285610003 1203-FIELD BLANK EPA 8081 3 PASI-CSWB
EPA 6010 17 PASI-ACDF
REPORT OF LABORATORY ANALYSIS
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Page 4 of 15
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92285610
Burke-John's R. Resample
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92285610001 1203-MW11
beta-BHC 0.33 ug/L 02/09/16 00:470.050EPA 8081
REPORT OF LABORATORY ANALYSIS
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Page 5 of 15
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92285610
Burke-John's R. Resample
Sample:1203-MW11 Lab ID:92285610001 Collected:02/04/16 12:05 Received:02/05/16 13:35 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
beta-BHC 0.33 ug/L 02/09/16 00:47 319-85-702/08/16 11:100.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)80 %02/09/16 00:47 877-09-802/08/16 11:1020-130 1
Decachlorobiphenyl (S)62 %02/09/16 00:47 2051-24-302/08/16 11:1020-130 1
REPORT OF LABORATORY ANALYSIS
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Page 6 of 15
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92285610
Burke-John's R. Resample
Sample:1203-MW12 Lab ID:92285610002 Collected:02/04/16 13:02 Received:02/05/16 13:35 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 02/10/16 22:15 7440-36-002/09/16 16:006.0 3.8 1
Chromium ND ug/L 02/10/16 22:15 7440-47-302/09/16 16:0010.0 2.5 1
REPORT OF LABORATORY ANALYSIS
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Page 7 of 15
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92285610
Burke-John's R. Resample
Sample:1203-FIELD BLANK Lab ID:92285610003 Collected:02/04/16 13:55 Received:02/05/16 13:35 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
beta-BHC ND ug/L 02/09/16 01:04 319-85-702/08/16 11:100.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)94 %02/09/16 01:04 877-09-802/08/16 11:1020-130 1
Decachlorobiphenyl (S)80 %02/09/16 01:04 2051-24-302/08/16 11:1020-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 02/10/16 22:18 7440-36-002/09/16 16:006.0 3.8 1
Arsenic ND ug/L 02/10/16 22:18 7440-38-202/09/16 16:0010.0 2.5 1
Barium ND ug/L 02/10/16 22:18 7440-39-302/09/16 16:001002.5 1
Beryllium ND ug/L 02/10/16 22:18 7440-41-702/09/16 16:001.0 0.50 1
Cadmium ND ug/L 02/10/16 22:18 7440-43-902/09/16 16:001.0 0.50 1
Chromium ND ug/L 02/10/16 22:18 7440-47-302/09/16 16:0010.0 2.5 1
Cobalt ND ug/L 02/10/16 22:18 7440-48-402/09/16 16:0010.0 2.5 1
Copper ND ug/L 02/10/16 22:18 7440-50-802/09/16 16:0010.0 2.5 1
Iron ND ug/L 02/10/16 22:18 7439-89-602/09/16 16:0030025.0 1
Lead ND ug/L 02/10/16 22:18 7439-92-102/09/16 16:0010.0 2.5 1
Manganese ND ug/L 02/10/16 22:18 7439-96-502/09/16 16:0050.0 2.5 1
Nickel ND ug/L 02/10/16 22:18 7440-02-002/09/16 16:0050.0 2.5 1
Selenium ND ug/L 02/10/16 22:18 7782-49-202/09/16 16:0010.0 5.0 1
Silver ND ug/L 02/10/16 22:18 7440-22-402/09/16 16:0010.0 2.5 1
Thallium ND ug/L 02/11/16 17:27 7440-28-002/09/16 16:005.5 5.0 1
Vanadium ND ug/L 02/10/16 22:18 7440-62-202/09/16 16:0025.0 2.5 1
Zinc ND ug/L 02/10/16 22:18 7440-66-602/09/16 16:0010.0 5.0 1
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92285610
Burke-John's R. Resample
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20650
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92285610002, 92285610003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1662251
Associated Lab Samples:92285610002, 92285610003
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 02/10/16 21:383.8
Arsenic ug/L ND 10.0 02/10/16 21:382.5
Barium ug/L ND 100 02/10/16 21:382.5
Beryllium ug/L ND 1.0 02/10/16 21:380.50
Cadmium ug/L ND 1.0 02/10/16 21:380.50
Chromium ug/L ND 10.0 02/10/16 21:382.5
Cobalt ug/L ND 10.0 02/10/16 21:382.5
Copper ug/L ND 10.0 02/10/16 21:382.5
Iron ug/L ND 300 02/10/16 21:3825.0
Lead ug/L ND 10.0 02/11/16 17:092.5
Manganese ug/L ND 50.0 02/10/16 21:382.5
Nickel ug/L ND 50.0 02/10/16 21:382.5
Selenium ug/L ND 10.0 02/10/16 21:385.0
Silver ug/L ND 10.0 02/10/16 21:382.5
Thallium ug/L ND 5.5 02/10/16 21:385.0
Vanadium ug/L ND 25.0 02/10/16 21:382.5
Zinc ug/L ND 10.0 02/10/16 21:385.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1662252LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 514500 103 80-120
Arsenic ug/L 496500 99 80-120
Barium ug/L 497500 99 80-120
Beryllium ug/L 488500 98 80-120
Cadmium ug/L 504500 101 80-120
Chromium ug/L 494500 99 80-120
Cobalt ug/L 506500 101 80-120
Copper ug/L 508500 102 80-120
Iron ug/L 49005000 98 80-120
Lead ug/L 500500 100 80-120
Manganese ug/L 492500 98 80-120
Nickel ug/L 502500 100 80-120
Selenium ug/L 501500 100 80-120
Silver ug/L 248250 99 80-120
Thallium ug/L 508500 102 80-120
Vanadium ug/L 501500 100 80-120
Zinc ug/L 498500 100 80-120
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 02/12/2016 04:43 PM
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92285610
Burke-John's R. Resample
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1662253MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92285299001
1662254
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 99 75-12598 1 25500ND497494
Arsenic ug/L 500 92 75-12591 1 255007.3J 466 464
Barium ug/L 500 93 75-12594 1 2550038.0 505 508
Beryllium ug/L 500 93 75-12594 1 25500ND466469
Cadmium ug/L 500 96 75-12595 1 25500ND479476
Chromium ug/L 500 90 75-12589 1 25500ND450446
Cobalt ug/L 500 94 75-12593 0 25500ND469467
Copper ug/L 500 96 75-12595 1 25500ND478474
Iron ug/L M150005675-12572 1 255000700007280073600
Lead ug/L 500 92 75-12591 1 255008.1 467 462
Manganese ug/L 500 91 75-12591 0 25500207664663
Nickel ug/L 500 92 75-12592 1 25500ND462459
Selenium ug/L 500 96 75-12595 1 25500ND482477
Silver ug/L 250 91 75-12590 1 25250ND228225
Thallium ug/L 500 100 75-125102 2 2550010.9 512 521
Vanadium ug/L 500 96 75-12595 0 25500ND481480
Zinc ug/L 500 93 75-12593 0 255006.8J 473 472
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 02/12/2016 04:43 PM
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[phone]
Page 10 of 15
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92285610
Burke-John's R. Resample
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/40641
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples:92285610001, 92285610003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1661659
Associated Lab Samples:92285610001, 92285610003
Matrix:Water
AnalyzedMDL
beta-BHC ug/L ND 0.050 02/09/16 01:220.050
Decachlorobiphenyl (S)%95 20-130 02/09/16 01:22
Tetrachloro-m-xylene (S)%84 20-130 02/09/16 01:22
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1661660LABORATORY CONTROL SAMPLE:
LCSSpike
beta-BHC ug/L 0.26.25 106 20-150
Decachlorobiphenyl (S)%96 20-130
Tetrachloro-m-xylene (S)%98 20-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1661661MATRIX SPIKE SAMPLE:
MSSpike
Result
92285559001
beta-BHC ug/L 0.21.25 86 20-150ND
Decachlorobiphenyl (S)%92 20-130
Tetrachloro-m-xylene (S)%75 20-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92285559002
1661662SAMPLE DUPLICATE:
beta-BHC ug/L ND 30ND
Decachlorobiphenyl (S)%69 77155
Tetrachloro-m-xylene (S)%64 70132
REPORT OF LABORATORY ANALYSIS
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[phone]
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92285610
Burke-John's R. Resample
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92285610
Burke-John's R. Resample
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92285610001 OEXT/40641 GCSV/240491203-MW11 EPA 3510 EPA 8081
92285610003 OEXT/40641 GCSV/240491203-FIELD BLANK EPA 3510 EPA 8081
92285610002 MPRP/20650 ICP/186211203-MW12 EPA 3010A EPA 6010
92285610003 MPRP/20650 ICP/186211203-FIELD BLANK EPA 3010A EPA 6010
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 02/12/2016 04:43 PM
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Huntersville, NC 28078
[phone]
Page 13 of 15
Page 14 of 15
Page 15 of 15

Appendix C

Statistical Analyses Worksheets

Appendix D

Historical Detected Inorganic Groundwater Constituents

APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Inorganic Compounds
Antimony 30-May-07 --- 6 --- ND --- --- ND ND 1.09 J ND ND ND ND
GWPS = 1.4 µg/L (10/23/07) 29-Nov-07 --- 6 --- ND --- --- ND ND 1.94 J ND ND ND ND
29-May-08 2.6 6.0 --- ND --- --- ND ND ND ND ND ND ND
6-Nov-08 2.6 6.0 --- ND --- --- ND ND 2.7 J ND 5.9 J ND ND
3-Jun-09 2.6 6.0 --- ND --- --- ND ND ND ND ND 3.2 J ND
18-Nov-09 2.6 6.0 --- ND --- --- ND ND ND ND ND ND ND
16-Jun-10 2.6 6.0 --- ND --- --- ND ND 2.8 J ND ND ND ND
GWPS = 1 µg/L (8/1/10) 1-Dec-10 2.6 6.0 --- ND ND --- ND 3.5 J 2.9 J ND ND ND ND
1-Jun-11 2.6 6.0 --- ND ND --- ND ND ND ND ND 2.9 J ND
20-Dec-11 5.0 6.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 5.0 6.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 5.0 6.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 5.0 6.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 5.0 6.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 5.0 6.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 5.0 6.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 3.8 6.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 3.8 6.0 --- --- --- ND ND ND 6.3 ND ND ND ND
Lab Re-run Analyses> 8-Dec-15 3.8 6.0 --- --- --- --- --- ---6.2 --- --- --- ---
Resample> 4-Feb-16 3.8 6.0 --- --- --- --- --- --- ND --- --- --- ND
Arsenic 30-May-07 --- 10 --- ND --- --- ND 2.2 B ND 3.6 B ND 2.1 B 2.6 J
NC 2L = 50 µg/L (10/23/07) 29-Nov-07 --- 10 --- 2.5 J --- --- ND ND ND ND 2.1 J ND ND
29-May-08 2.7 10.0 --- ND --- --- ND ND ND ND ND ND ND
6-Nov-08 2.7 10.0 --- ND --- --- ND 3.1 B ND 3.2 B 3 B ND 4.1 J
3-Jun-09 2.7 10.0 --- ND --- --- ND ND ND ND ND 3.2 J ND
18-Nov-09 2.7 10.0 --- ND --- --- 3.0 J ND ND ND ND ND ND
NC 2L = 10 µg/L (01/01/10) 16-Jun-10 2.7 10.0 --- ND --- --- ND 4.6 J ND ND 3.0 J ND ND
1-Dec-10 2.7 10.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 2.7 10.0 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 5.0 10.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 2.5 10.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 2.5 10.0 --- --- --- ND ND ND ND ND ND ND ND
Barium 15-Sep-94 --- 100 1320 NI NI NI 194 5580 ND 584 NI NI ND
1-Oct-94 --- 100 --- NI NI NI --- 1030 --- --- NI NI ND
18-Jan-95 --- 100 981 NI NI NI 122 1490 ND 355 NI NI ND
6-Feb-95 --- 100 435 NI NI NI 124 350 ND 311 NI NI ND
1-Mar-95 --- 100 556 NI NI NI 260 732 196 528 NI NI ND
1-Aug-95 --- 100 199 NI --- --- 250 688 ND 408 NI NI ND
1-Jan-96 --- 100 455 NI --- --- 228 734 196 ND NI NI ND
1-Feb-96 --- 100 306 NI --- --- 211 321 288 ND NI NI ND
1-May-96 --- 100 170 NI --- --- ND 453 319 ND NI NI ND
1-Oct-96 --- 100 302 NI --- --- 234 447 102 ND NI NI ND
1-May-97 --- 100 330 NI --- --- 170 360 400 ND NI NI ND
1-Nov-97 --- 100 800 NI --- --- 200 600 800 100 NI NI ND
1-May-98 --- 100 400 NI --- --- 200 400 1200 200 NI NI ND
1-Nov-98 --- 100 140 NI --- --- 270 310 880 ND NI NI ND
11-May-99 --- 5 240 200 --- --- 70 130 200 60 220 16 ND
18-Oct-99 --- 500 1900 ND --- --- ND ND 1400 ND ND ND ND
3-May-00 --- 500 ND ND --- --- ND ND ND ND 730 ND ND
7-Nov-00 --- 500 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 500 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 500 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 500 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 500 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 500 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 500 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 500 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 500 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 500 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 500 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 500 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 500 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 100 --- 52.0 J --- --- 48.1 J 132 88.4 J 66.9 J 50.9 J 8.0 J 0.20 J
NC 2L = 2,000 µg/L (10/23/07) 29-Nov-07 --- 100 --- 214 --- --- 54.8 J 232 97.0 J 75.3 J 57.9 J 8.6 J 0.50 J
29-May-08 0.20 100 --- 67.9 J --- --- 41.5 J 148 71.0 J 77.0 J 43.7 J 7.9 J ND
6-Nov-08 0.20 100 --- 82.3 J --- --- 45.5 B 118 81.2 J 90.6 J 66.7 J 7.1 B 9.6 J
3-Jun-09 0.20 100 --- 34.2 B --- --- 26.9 B 119 67.6 B 66.9 B 49.5 B 9.8 B 15.9 J
18-Nov-09 0.20 100 --- 78.9 B --- --- 36.3 B 116 88.6 B 81.0 B 46.6 B 7.8 B 20.1 J
NC 2L = 700 µg/L (01/01/10) 16-Jun-10 0.20 100 --- 58.1 J --- --- 50.5 J 296 103 73.4 J 47.0 J 8.6 J 0.77 J
1-Dec-10 0.20 100 --- 60.1 J 376 --- 59.6 J 134 94.1 J 78.7 J 37.5 J 16.3 J ND
1-Jun-11 0.20 100 --- 55.6 J 164 --- 43.3 J 154 74.3 J 74.4 J 44.7 J 12.3 J ND
20-Dec-11 5.0 100 --- --- 119 --- 50.9 J 138 76.6 J 78.3 J 46.7 J 10.5 J ND
30-May-12 5.0 100 --- --- 96.7 J --- 40.6 J 137 77.7 J 74.5 J 67.8 J 9.1 J ND
5-Dec-12 5.0 100 --- --- 63.0 J --- 53.3 J 148 89.8 J 81.4 J 43.6 J 10.5 J ND
12-Jun-13 5.0 100 --- --- 59.6 B --- 28.3 B 167 82.3 J 83.6 J 48.1 B 13.2 B 13.6 J
28-Oct-13 5.0 100 --- --- 47.9 J --- 47.4 J 194 93.8 J 70.7 J 49.4 J 9.6 J ND
6-May-14 5.0 100 --- --- 73.6 J --- 37.3 J 129 89.9 J 73.9 J 45.5 J 8.2 J ND
23-Oct-14 5.0 100 --- --- * 20.3 J 53.4 J 127 74.6 J 76.0 J 46.3 J 13.3 J ND
20-May-15 2.5 100 --- --- --- 17.9 47.5 J 145 75.5 J 76.9 J 44.6 J 8.4 J ND
8-Dec-15 2.5 100 --- --- --- 17.6 J 45.6 J 140 132 82.6 J 50.6 J 8.0 J ND
DowngradientBackground
Burke County - John's River C and D over MSW Landfill
Permit 12-03 Page 1 of 11 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
DowngradientBackground
Beryllium 1-May-97 --- 1 ND NI --- --- ND ND 1.0 ND NI NI ND
1-Nov-97 --- 1 1.0 NI --- --- ND 3.0 ND ND NI NI ND
1-May-98 --- 1 ND NI --- --- ND ND 3.0 ND NI NI ND
1-Nov-98 --- 1 ND NI --- --- ND ND 1 ND NI NI ND
11-May-99---2NDND --- --- NDNDNDND 4.3 ND ND
18-Oct-99 --- 2 8.0 3.0 J --- --- 2.0 J 2.0 J 13.0 ND ND ND ND
3-May-00---2NDND --- --- NDNDNDND 8.0 ND ND
7-Nov-00 --- 2 ND 2.0 --- --- ND ND ND ND ND ND ND
31-May-01---2NDND --- --- NDNDNDND ND ND ND
7-Nov-01---2NDND --- --- NDNDNDND ND ND ND
22-May-02---2NDND --- --- NDNDNDND ND ND ND
14-Nov-02---2NDND --- --- NDNDNDND ND ND 2.1
14-May-03---2NDND --- --- NDNDNDND ND ND ND
20-Nov-03---2NDND --- --- NDNDNDND ND ND ND
6-May-04---2NDND --- --- NDNDNDND ND ND ND
10-Nov-04---2NDND --- ---NDNDNDND ND ND ND
5-May-05---2NDND --- ---NDNDNDND ND ND ND
3-Nov-05 --- 2 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 2 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 2 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 1 --- ND --- --- ND ND ND ND ND ND ND
GWPS = 4 µg/L (10/23/07) 29-Nov-07 --- 1 --- ND --- --- ND ND ND ND ND ND ND
29-May-08 0.10 1.0 --- ND --- --- 0.18 J ND ND ND ND ND ND
6-Nov-08 0.10 1.0 --- 0.49 B --- --- 0.65 B 0.32 B 0.42 B 0.61 B 0.53 B 0.27 B 0.29 J
3-Jun-09 0.10 1.0 --- ND --- --- ND ND ND 0.25 J 0.23 J 2.2 ND
18-Nov-09 0.10 1.0 --- ND --- --- ND ND ND 0.25 J ND ND ND
16-Jun-10 0.10 1.0 --- ND --- --- 0.24 J 0.94 J ND 0.11 J ND ND ND
1-Dec-10 0.10 1.0 --- ND 1.7 --- 0.14 J ND ND ND ND ND ND
1-Jun-11 0.10 1.0 --- ND 0.44 J --- J ND ND ND ND ND ND ND
20-Dec-11 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 1.0 1.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 0.5 1.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.5 1.0 --- --- --- ND ND ND ND ND ND ND ND
Cadmium 1-May-97 --- 1 ND NI --- --- ND ND 1.0 ND NI NI ND
1-Nov-97 --- 1 ND NI --- --- ND ND ND ND NI NI ND
1-May-98 --- 1 ND NI --- --- ND ND 1.0 ND NI NI ND
1-Nov-98 --- 1 ND NI --- --- ND ND 2.0 ND NI NI ND
11-May-99---1NDND --- --- NDNDNDND ND ND ND
18-Oct-99 --- 1 24.0 6.0 --- --- 6.0 3.0 J 30.0 2.0 J 2.0 J ND ND
3-May-00 --- 1 ND ND --- --- ND 1.0 J 1.0 J ND 5.0 ND ND
7-Nov-00 --- 1 2.0 5.0 --- --- ND ND 1.0 ND 1.0 ND ND
31-May-01 --- 1 ND ND --- --- ND ND 1.0 J ND 1.0 J ND ND
7-Nov-01---1NDND --- --- NDNDNDND ND ND ND
22-May-02 --- 1 ND ND --- --- ND ND ND 2.0 B ND ND 1.3
14-Nov-02 --- 1 ND ND --- --- ND ND 1.2 ND 3.7 ND ND
14-May-03 --- 1 ND ND --- --- 1.1 ND ND ND 2.5 ND ND
20-Nov-03 --- 1 2.0 1.3 --- --- ND ND 1.2 ND ND ND ND
6-May-04---1NDND --- --- NDNDNDND ND ND ND
10-Nov-04 --- 1 ND ND --- --- 1.5 ND ND ND 2.2 ND ND
5-May-05---1NDND --- ---NDNDNDND ND ND ND
3-Nov-05 --- 1 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 1 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 1 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 1 --- ND --- --- ND ND ND ND ND ND ND
NC 2L = 1.75 µg/L (10/23/07) 29-Nov-07 --- 1 --- ND --- --- ND ND 0.60 J ND ND ND ND
29-May-08 0.50 1.0 --- ND --- --- ND ND ND ND ND ND ND
6-Nov-08 0.50 1.0 --- ND --- --- ND ND ND ND 0.94 J ND ND
3-Jun-09 0.50 1.0 --- ND --- --- ND ND ND ND ND 1.9 ND
18-Nov-09 0.50 1.0 --- ND --- --- ND ND ND ND ND ND ND
NC 2L = 2 µg/L (01/01/10) 16-Jun-10 0.50 1.0 --- ND --- --- ND 6.0 ND ND ND ND ND
Resample> 5-Aug-10 0.50 1.0 --- --- --- --- --- 1.2 --- --- --- --- ND
1-Dec-10 0.50 1.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 0.50 1.0 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 1.0 1.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 0.5 1.0 --- --- --- ND ND 0.85 J ND ND ND ND ND
8-Dec-15 0.5 1.0 --- --- --- ND ND ND ND ND ND ND ND
Burke County - John's River C and D over MSW Landfill
Permit 12-03 Page 2 of 11 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
DowngradientBackground
Chromium 1-Mar-95 --- 5 ND NI NI NI ND ND 11.0 ND NI NI ND
1-Aug-95 --- 5 ND NI --- --- ND ND ND ND NI NI ND
1-Jan-96 --- 5 ND NI --- --- ND ND 7.0 ND NI NI ND
1-Feb-96 --- 5 ND NI --- --- ND ND 6.0 ND NI NI ND
1-May-96 --- 5 ND NI --- --- ND ND 16.0 ND NI NI ND
1-Oct-96 --- 5 ND NI --- --- ND ND 6.0 ND NI NI ND
1-May-97 --- 1 4.0 NI --- --- 2.0 3.0 18.0 3.0 NI NI ND
1-Nov-97 --- 1 6.0 NI --- --- 1.0 1.0 108 2.0 NI NI ND
1-May-98 --- 1 8.0 NI --- --- 4.0 6.0 66.0 6.0 NI NI ND
1-Nov-98 --- 1 3.0 NI --- --- 1.0 3.0 180 3.0 NI NI ND
11-May-99 --- 5 26.0 24.0 --- --- 8.4 6.5 44.0 11.0 46.0 ND ND
18-Oct-99 --- 10 290 58.0 --- --- 44.0 36.0 410 21.0 ND ND ND
3-May-00 --- 10 ND ND --- --- ND ND 12.0 ND 92.0 ND ND
7-Nov-00 --- 10 11.0 30.0 --- --- ND ND ND ND ND ND ND
31-May-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 10 ND ND --- --- ND ND ND ND 10.0 ND ND
14-Nov-02 --- 10 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 10 12.0 ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 10 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 10 --- ND --- --- ND ND ND ND ND ND ND
NC 2L = 50 µg/L (10/23/07) 29-Nov-07 --- 10 --- ND --- --- ND ND ND ND ND ND ND
29-May-08 0.40 10.0 --- ND --- --- ND 1.9 B 1 B 1.4 B ND ND 0.85 J
6-Nov-08 0.40 10.0 --- 0.59 J --- --- 1 J 0.83 J 2.8 J 3.4 J 2.5 J ND ND
3-Jun-09 0.40 10.0 --- ND --- --- ND 2.1 J ND 1.1 J 0.66 J 2.1 J ND
18-Nov-09 0.40 10.0 --- ND --- --- ND ND 2.2 J 2.2 J ND ND ND
NC 2L = 10 µg/L (01/01/10) 16-Jun-10 0.40 10.0 --- 0.43 B --- --- 1.0 B 13.9 4.7 J 1.0 B ND ND 0.74 J
Resample> 5-Aug-10 0.40 10.0 --- --- --- --- --- 0.88 B --- --- --- --- 0.51 J
1-Dec-10 0.40 10.0 --- 0.60 B 39.6 --- 1.8 B 1.3 B 5.5 J 1.2 B ND ND 0.51 J
Resample> 13-Jan-11 0.40 10.0 --- --- ND --- --- --- --- --- --- --- ND
1-Jun-11 0.40 10.0 --- ND 11.2 --- ND 1.2 B 0.72 B ND ND ND 0.73 J
Resample> 7-Jul-11 0.40 10.0 --- --- 7.8 J --- --- --- --- --- --- --- ND
20-Dec-11 5.0 10.0 --- --- 8.2 J --- ND ND ND ND ND ND ND
30-May-12 5.0 10.0 --- --- 5.3 J --- ND ND ND ND 5.4 J ND ND
5-Dec-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 5.0 10.0 --- --- 6.1 J --- ND ND ND ND ND ND ND
23-Oct-14 5.0 10.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 2.5 10.0 --- --- --- ND ND 3.9 J ND ND ND 4.7 J ND
8-Dec-15 2.5 10.0 --- --- --- ND ND ND 13.8 ND ND ND ND
Lab Re-run Analyses> 8-Dec-15 2.5 10.0 --- --- --- --- --- ---14.7 --- --- --- ---
Resample> 4-Feb-16 2.5 10.0 --- --- --- --- --- --- ND --- --- --- ND
Burke County - John's River C and D over MSW Landfill
Permit 12-03 Page 3 of 11 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
DowngradientBackground
Cobalt 18-Jan-95 --- 10 35.0 NI NI NI 35.0 14.0 52.0 14.0 NI NI ND
6-Feb-95 --- 10 16.0 NI NI NI 43.0 ND 66.0 ND NI NI ND
Mar-95 --- 10 28.0 NI NI NI 57.0 ND 78.0 20.0 NI NI ND
Aug-95 --- 10 ND NI --- --- 58.0 ND 30.0 32.0 NI NI ND
Jan-96 --- 10 17.0 NI --- --- 37.0 ND 23.0 ND NI NI ND
Feb-96 --- 10 37.0 NI --- --- 41.0 ND 24.0 ND NI NI ND
May-96 --- 10 11.0 NI --- --- 26.0 ND 24.0 ND NI NI ND
Oct-96 --- 10 16.0 NI --- --- 52.0 ND 16.0 ND NI NI ND
May-97 --- 6 33.0 NI --- --- 120 5.0 J 32.0 6.0 NI NI ND
Nov-97 --- 5 29.0 NI --- --- 99.0 11.0 48.0 14.0 NI NI ND
May-98 --- 1 28.0 NI --- --- 120 8.0 76.0 32.0 NI NI ND
Nov-98 --- 1 10.0 NI --- --- 140 6.0 47.0 1.0 NI NI ND
11-May-99 --- 5 20.0 26.0 --- --- 48.0 13.0 34.0 17.0 59.0 ND ND
18-Oct-99 --- 10 120 37.0 --- --- 85.0 20.0 220 16.0 40.0 ND ND
3-May-00 --- 10 ND ND --- --- 54.0 ND 31.0 13.0 89.0 ND ND
7-Nov-00 --- 10 ND 20.0 --- --- 40.0 ND 18.0 ND 32.0 ND ND
31-May-01 --- 10 ND ND --- --- 53.0 ND 30.0 11.0 32.0 ND ND
7-Nov-01 --- 10 ND ND --- --- 29.0 ND 23.0 ND 26.0 ND ND
22-May-02 --- 10 14.0 B 14.0 B --- --- 68.0 16.0 B 51.0 B 17.0 B 39.0 B 12.0 B 11.0
14-Nov-02 --- 10 ND ND --- --- 90.0 ND 41.0 11.0 34.0 ND ND
14-May-03 --- 10 19.0 ND --- --- 280 ND 46.0 53.0 24.0 ND ND
20-Nov-03 --- 10 26.0 10.0 J --- --- 340 18.0 56.0 58.0 30.0 ND ND
6-May-04 --- 10 ND ND --- --- 140 ND 46.0 47.0 29.0 ND ND
10-Nov-04 --- 10 10.0 ND --- --- 170 21.0 50.0 46.0 29.0 ND ND
5-May-05 --- 10 12.0 ND --- --- 130 16.0 46.0 60.0 26.0 ND ND
3-Nov-05 --- 10 --- ND --- --- 66.0 15.0 42.0 45.0 25.0 ND ND
25-May-06 --- 10 --- ND --- --- 80.3 21.7 42.7 43.2 24.9 ND ND
2-Nov-06 --- 10 --- ND --- --- 131 30.8 37.0 28.3 26.6 ND ND
30-May-07 --- 10 --- 4.1 J --- --- 87.2 20.7 44.0 36.9 26.6 ND ND
GWPS = 70 µg/L (10/23/07) 29-Nov-07 --- 10 --- 7.3 J --- ---67.2 55.5 47.9 J 23.4 30.7 ND ND
29-May-08 0.60 10.0 --- 5.4 J --- ---71.9 54.6 34.8 35.3 ND ND ND
6-Nov-08 0.60 10.0 --- 9.2 J --- ---71.9 60.0 47.9 44.1 24.3 2.2 B 1.6 J
3-Jun-09 0.60 10.0 --- 22.8 B --- ---139 78.6 53.5 49.3 54.7 7.6 B 7.6 J
Resample> 27-Aug-09 0.60 10.0 --- --- --- --- 60.0 --- --- --- --- --- ---
18-Nov-09 0.60 10.0 --- 14.9 --- ---126 84.5 50.3 44.1 31.8 ND ND
16-Jun-10 0.60 10.0 --- 19.1 --- ---96.1 103 70.9 38.0 48.6 ND ND
Resample> 5-Aug-10 0.60 10.0 --- --- --- --- ---85.5 --- --- --- --- ND
GWPS = 1 µg/L (10/1/10) 1-Dec-10 0.60 10.0 --- 9.8 J 22.1 ---72.7 151 111 43.1 33.3 ND ND
Resample> 13-Jan-11 0.60 10.0 --- --- ND --- ---84.2 --- --- --- --- ND
1-Jun-11 0.60 10.0 --- 7.8 J 2.6 J --- J 76.4 99.3 72.9 41.7 38.6 ND ND
20-Dec-11 5.0 10.0 --- --- ND ---92.8 75.6 62.7 36.5 25.5 ND ND
30-May-12 5.0 10.0 --- --- ND ---90.2 108 78.8 42.3 46.2 ND ND
5-Dec-12 5.0 10.0 --- --- ND ---46.6 27.9 101 45.8 51.4 ND ND
12-Jun-13 5.0 10.0 --- --- ND ---243 150 118 92.2 66.0 ND ND
28-Oct-13 5.0 10.0 --- --- ND ---200 128 124 117 75.7 ND ND
Resample> 10-Dec-13 5.0 10.0 --- --- --- --- --- --- ---40.4 --- --- ND
6-May-14 5.0 10.0 --- --- ND ---138 33.4 68.9 65.9 26.6 ND ND
22-Oct-14 5.0 10.0 --- --- * ND 126 37.1 82.0 74.9 32.1 ND ND
20-May-15 2.5 10.0 --- --- --- ND 116 34.8 77.8 90.0 34.0 ND ND
8-Dec-15 2.5 10.0 --- --- --- ND 175 61.0 84.8 49.7 32.8 ND ND
Burke County - John's River C and D over MSW Landfill
Permit 12-03 Page 4 of 11 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
DowngradientBackground
Copper 18-Jan-95 --- 10 16.0 NI NI NI ND ND ND 14.0 NI NI ND
6-Feb-95 --- 10 ND NI NI NI ND ND ND ND NI NI ND
1-Mar-95 --- 10 ND NI NI NI ND ND ND 20.0 NI NI ND
1-Aug-95 --- 10 ND NI --- --- ND ND ND 18.0 NI NI ND
1-Jan-96 --- 10 ND NI --- --- ND ND ND ND NI NI ND
1-Feb-96 --- 10 21.0 NI --- --- ND ND ND ND NI NI ND
1-May-96 --- 10 14.0 NI --- --- 13.0 11.0 ND 11.0 NI NI ND
1-Oct-96 --- 10 ND NI --- --- ND ND ND ND NI NI ND
1-May-97 --- 10 ND NI --- --- 30.0 ND ND ND NI NI ND
1-Nov-97 --- 10 ND NI --- --- ND ND ND ND NI NI ND
1-May-98 --- 10 20.0 NI --- --- ND 10.0 70.0 20.0 NI NI ND
1-Nov-98 --- 10 ND NI --- --- 13.0 ND 28.0 ND NI NI ND
11-May-99 --- 5 28.0 49.0 --- --- 14.0 ND 9.3 28.0 37.0 ND ND
18-Oct-99 --- 200 380 ND --- --- ND ND 240 ND ND ND ND
3-May-00 --- 200 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-00 --- 200 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 200 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 200 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 200 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 200 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 200 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 200 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 200 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 200 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 200 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 200 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 200 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 200 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 10 --- 0.7 B --- --- ND ND ND 3.2 B ND ND 1.3 J
NC 2L = 1,000 µg/L (10/23/07) 29-Nov-07 --- 10 --- 8.30 J --- --- ND ND ND 6.10 J ND ND ND
29-May-08 0.30 10.0 --- 0.42 B --- --- 0.99 B 1.5 B 1.0 B 14.9 0.89 B ND 0.37 J
6-Nov-08 0.30 10.0 --- 2.0 B --- --- 1.8 B 0.7 B 2.4 B 16.6 4.2 J 0.46 B 0.65 J
3-Jun-09 0.30 10.0 --- 0.83 J --- --- ND 1 J ND 6.7 J 0.61 J 3.5 J ND
18-Nov-09 0.30 10.0 --- 0.34 J --- --- ND ND 1.2 J 10.7 0.38 J ND ND
16-Jun-10 0.30 10.0 --- 0.37 B --- --- 2.6 B 9.0 J 3.2 B 3.4 B ND ND 0.77 J
1-Dec-10 0.30 10.0 --- 1.3 J 36.1 --- 3.8 J 1.2 J 1.8 J 3.9 J 2.1 J ND ND
1-Jun-11 0.30 10.0 --- 0.54 J 12.9 --- 0.94 J 2.3 J 0.79 J 4.8 J 0.66 J ND ND
20-Dec-11 5.0 10.0 --- --- 9.0 J --- ND ND ND ND ND ND ND
30-May-12 5.0 10.0 --- --- 7.0 J --- ND ND ND ND 5.6 J ND ND
5-Dec-12 5.0 10.0 --- --- ND --- ND ND ND 5.6 J ND ND ND
12-Jun-13 5.0 10.0 --- --- 34.0 B --- ND ND ND 11.1 B ND ND 9.8 J
28-Oct-13 5.0 10.0 --- --- ND --- ND 6.1 J ND ND ND ND ND
6-May-14 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 5.0 10.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 2.5 10.0 --- --- --- ND ND ND ND 4.6 J ND ND ND
8-Dec-15 2.5 10.0 --- --- --- ND 8.1 J 6.4 J 9.7 J ND 5.9 J ND ND
Cyanide 1-Nov-98 --- 2 6.0 NI --- --- 2.0 ND 7.0 ND NI NI ND
11-May-99---2NDND --- --- NDNDNDND ND ND ND
18-Oct-99 --- 50 ND ND --- --- --- ND ND ND ND ND ND
7-Nov-00 --- 50 ND --- --- --- ND ND ND ND ND --- ND
31-May-01 --- 50 ND --- --- --- ND ND ND ND ND --- ND
7-Nov-01 --- 50 ND --- --- --- ND ND ND ND ND --- ND
14-Nov-02 --- 50 ND --- --- --- ND ND ND ND ND --- ND
20-Nov-03 --- 50 ND --- --- --- ND ND ND ND ND --- ND
10-Nov-04 --- 10 ND --- --- --- ND ND ND ND ND --- ND
3-Nov-05 --- --- --- ND --- --- ND ND ND ND ND --- ND
2-Nov-06 --- 50 --- ND --- --- ND ND ND ND ND --- ND
NC 2L = 70 µg/L (10/23/07) 29-Nov-07 --- 10 --- ND --- --- ND ND ND ND ND --- ND
6-Nov-08 5.0 10.0 --- ND --- --- ND ND ND ND ND --- ND
18-Nov-09 5.0 10.0 --- ND --- --- ND ND ND ND ND --- ND
1-Dec-10 5.0 10.0 --- ND 5.9 J --- ND ND 5.2 J 5.8 J 6.5 J --- ND
Resample> 13-Jan-11 5.0 10.0 --- --- ND --- --- --- 5.0 J ND 5.8 J --- ND
5-Dec-12 5.0 10.0 --- --- ND --- ND ND ND ND 7.0 J --- ND
28-Oct-13 5.0 10.0 --- --- ND --- 12.4 5.6 J 10.0 ND 6.5 J ND ND
Resample> 10-Dec-13 5.0 10.0 --- --- --- --- 10.8 --- 9.0 J --- --- --- ND
6-May-14 0.0 0.0 --- --- ND --- ND ND ND ND ND --- ND
23-Oct-14 2.5 10.0 --- --- * ND 3.6 J 4.7 J 4.2 J ND 5.2 J --- ND
20-May-15 0.0 10.0 --- --- --- ND ND ND ND ND ND --- ND
8-Dec-15 4.0 10.0 --- --- --- ND ND ND ND ND ND --- ND
Iron 1-Jun-11 14.0 300 ---308 11,000 ---20,500 29,200 16,300 886 22,200 413 ND
NC 2L = 300 µg/L (01/01/10) Resample>7-Jul-11 50.0 300 --- ---7,150 --- --- --- --- --- --- --- ND
20-Dec-11 50.0 300 --- ---8,010 ---26,300 36,700 22,900 1,160 22,200 93.5 J ND
30-May-12 50.0 300 --- ---5,940 ---24,500 45,700 21,700 1,300 24,500 ND ND
5-Dec-12 50.0 300 --- ---2,970 ---7,010 8,730 28,200 393 21,700 159 J ND
12-Jun-13 50.0 300 --- ---2,460 ---55,300 55,300 34,800 4,650 26,700 522 81.2 J
28-Oct-13 50.0 300 --- ---883 ---28,700 49,700 29,800 1,730 24,300 ND ND
6-May-14 50.0 300 --- ---4,240 ---47,300 46,800 29,700 1,200 24,600 ND ND
23-Oct-14 50.0 300 --- --- *2,340 33,600 29,200 31,200 528 27,700 171 J ND
20-May-15 25.0 300 --- --- ---350 22,400 22,600 33,800 672 25,800 63.5 J ND
8-Dec-15 25.0 300 --- --- ---1,380 102,000 74,200 50,200 1,460 27,400 43.7 J ND
Burke County - John's River C and D over MSW Landfill
Permit 12-03 Page 5 of 11 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
DowngradientBackground
Lead 15-Sep-94 --- 5 41.0 NI NI NI 12.0 49.0 7.0 43.0 NI NI ND
1-Oct-94 --- 5 --- NI NI NI --- 9.0 --- --- NI NI ND
18-Jan-95 --- 5 35.0 NI NI NI 9.0 17.0 10.0 30.0 NI NI ND
6-Feb-95 --- 5 15.0 NI NI NI 7.0 ND ND 26.0 NI NI ND
1-Mar-95 --- 5 26.0 NI NI NI 16.0 12.0 9.0 43.0 NI NI ND
1-Aug-95 --- 5 11.0 NI --- --- 25.0 16.0 6.0 48.0 NI NI ND
1-Jan-96 --- 5 22.0 NI --- --- 18.0 12.0 10.0 7.0 NI NI ND
1-Feb-96 --- 5 16.0 NI --- --- 15.0 6.0 9.0 10.0 NI NI ND
1-May-96 --- 5 7.0 NI --- --- 8.0 9.0 15.0 ND NI NI ND
1-Oct-96 --- 5 15.0 NI --- --- 24.0 10.0 7.0 6.0 NI NI ND
1-May-97 --- 5 16.0 NI --- --- 23.0 10.0 22.0 16.0 NI NI ND
1-Nov-97 --- 5 40.0 NI --- --- 27.0 14.0 30.0 24.0 NI NI ND
1-May-98 --- 5 18.0 NI --- --- 9.0 ND 10.0 6.0 NI NI ND
1-Nov-98 --- 5 7.0 NI --- --- 39.0 9.0 47.0 14.0 NI NI ND
11-May-99 --- 10 14.0 18.0 --- --- ND ND ND ND ND ND ND
18-Oct-99 --- 10 160 54.0 --- --- 56.0 27.0 140 23.0 ND ND ND
3-May-00 --- 10 ND ND --- --- ND ND ND ND 11.0 J ND ND
7-Nov-00 --- 10 ND 20.0 --- --- ND ND ND ND ND ND ND
31-May-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 10 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 10 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 10 ND 19.0 --- --- ND ND ND 20.0 ND ND ND
6-May-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 10 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 10 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 10 --- 2.5 J --- --- ND ND ND 2.3 J ND ND ND
NC 2L = 15 µg/L (10/23/07) 29-Nov-07 --- 10 --- 7.5 J --- --- ND 6.1 J ND 5.1 J ND ND ND
29-May-08 4.0 10.0 --- ND --- --- ND ND ND 6.8 ND ND ND
6-Nov-08 4.0 10.0 --- ND --- --- ND ND ND 8.8 J ND ND ND
3-Jun-09 4.0 10.0 --- ND --- --- ND ND ND ND ND ND ND
18-Nov-09 4.0 10.0 --- ND --- --- ND ND ND 5.5 J ND ND ND
16-Jun-10 4.0 10.0 --- ND --- --- 4.4 J 13.9 ND ND ND ND ND
1-Dec-10 4.0 10.0 --- ND 16.8 ---NDNDNDND ND ND ND
Resample> 13-Jan-11 4.0 10.0 --- ND ND --- --- --- --- --- --- --- ND
1-Jun-11 4.0 10.0 --- ND 5.9 J --- ND ND ND ND ND ND ND
20-Dec-11 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 5.0 10.0 --- --- ND --- ND 5.5 J ND 5.6 J ND ND ND
28-Oct-13 5.0 10.0 --- --- ND --- ND 5.2 J ND ND ND ND ND
6-May-14 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 5.0 10.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 2.5 10.0 --- --- --- ND 4.9 J 4.3 J ND ND 2.7 J ND ND
8-Dec-15 2.5 10.0 --- --- --- ND 7.8 J 6.3 J 9.8 J ND ND ND ND
Manganese 1-Jun-11 0.30 50.0 ---385 209 ---5,770 14,500 9,330 1,160 8,460 123 0.36 J
NC 2L = 50 µg/L (01/01/10) Resample>7-Jul-11 5.0 50.0 --- --- 143 --- --- --- --- --- --- --- ND
20-Dec-11 5.0 50.0 --- ---136 ---6,670 15,500 D 9,480 1,030 8,540 119 ND
30-May-12 5.0 50.0 --- ---104 ---6,700 14,300 9,370 1,170 8,790 119 ND
5-Dec-12 5.0 50.0 --- ---54.5 ---2,650 8,930 9,150 1,230 9,180 122 ND
12-Jun-13 5.0 50.0 --- --- 49.3 J ---16,800 15,400 11,700 2,060 8,150 130 ND
28-Oct-13 5.0 50.0 --- ---80.0 ---8,420 15,000 9,910 2,500 9,680 124 ND
6-May-14 50.0 500.0 --- ---83.5 ---12,300 18,300 9,950 1,600 9,720 119 ND
23-Oct-14 50.0 500.0 --- --- *73.6 9,400 23,200 11,000 1,740 11,500 115 ND
20-May-15 2.5 50.0 --- --- --- 27.4 9,070 29,800 10,800 2,010 12,400 121 ND
8-Dec-15 12.5 50.0 --- --- --- 50.0 J 15,000 18,100 10,800 1,500 8,440 124 ND
Burke County - John's River C and D over MSW Landfill
Permit 12-03 Page 6 of 11 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
DowngradientBackground
Mercury 16-Aug-95 --- 0.2 0.30 B NI --- --- 0.30 B 0.30 B 0.20 B 0.30 B NI NI 0.2
25-Jan-96 --- 0.2 1.6 NI --- --- 0.40 0.70 ND 1.3 NI NI ND
28-Feb-96 --- 0.2 ND NI --- --- 2.4 ND ND 0.20 NI NI ND
1-May-96 --- 0.2 1.4 NI --- --- 1.7 1.5 2.1 2.3 NI NI ND
1-Oct-96 --- 0.5 ND NI --- --- ND ND ND ND NI NI ND
1-May-97 --- --- --- NI --- --- NS NS NS NS NI NI NS
1-Nov-97 --- 0.2 ND NI --- --- 0.80 ND ND ND NI NI ND
1-May-98 --- 0.2 ND NI --- --- 0.80 ND ND 0.40 NI NI ND
1-Nov-98 --- 0.2 ND NI --- --- 1.3 ND ND 0.49 NI NI ND
11-May-99 --- 0.2 --- ND --- --- --- --- --- --- ND ND ---
18-Oct-99 --- 0.5 ND ND --- --- --- ND ND 0.55 ND ND ND
3-May-00 --- 0.5 --- --- --- --- --- --- --- --- --- --- ---
7-Nov-00 --- 0.5 ND --- --- --- ND ND ND ND ND --- ND
31-May-01 --- 0.5 ND --- --- --- 0.70 ND ND 0.90 ND --- ND
7-Nov-01 --- 0.5 ND --- --- --- ND ND ND 1.0 ND --- ND
22-May-02 --- 0.5 ND --- --- --- 0.62 ND ND ND ND --- ND
14-Nov-02 --- 0.5 ND --- --- --- ND ND ND ND ND --- ND
14-May-03 --- 0.5 ND --- --- --- ND ND ND ND ND --- ND
20-Nov-03 --- 0.5 ND --- --- --- 0.80 ND ND 0.73 ND --- ND
6-May-04 --- 0.5 ND --- --- --- 0.71 ND ND 0.52 ND --- ND
10-Nov-04 --- 0.5 ND --- --- --- ND ND ND 0.74 ND --- ND
5-May-05 --- 0.5 ND --- --- --- ND ND ND ND ND --- ND
3-Nov-05 --- 0.5 --- ND --- --- 1.0 ND ND ND ND --- ND
25-May-06 --- 2 --- --- --- --- ND ND ND ND ND --- ND
2-Nov-06 --- 0.5 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 0.2 --- --- --- --- 0.12 J ND ND 0.13 J ND --- ---
NC 2L = 1.05 µg/L (10/23/07) 29-Nov-07 --- 0.2 --- ND --- --- 0.88 ND ND 0.50 ND ND ND
29-May-08 0.090 0.20 --- --- --- --- 0.12 B ND 0.13 B 0.66 0.12 B --- 0.1 J
6-Nov-08 0.090 0.20 --- ND --- --- ND ND ND 0.41 ND ND ND
3-Jun-09 0.070 0.20 --- ND --- --- ND ND ND 0.14 J ND --- ND
18-Nov-09 0.070 0.20 --- ND --- --- ND ND ND 0.43 ND ND ND
NC 2L = 1 µg/L (01/01/10) 16-Jun-10 0.070 0.20 --- ND --- --- 0.17 J ND ND 0.077 J --- --- ND
1-Dec-10 0.070 0.20 --- 0.089 J ND --- 0.62 ND ND 0.21 ND ND ND
1-Jun-11 0.10 0.20 --- ND ND --- 0.19 J ND ND 0.19 J ND --- ND
20-Dec-11 0.10 0.20 --- --- ND --- 0.14 J ND ND 0.15 J ND ND ND
30-May-12 0.10 0.10 --- --- ND --- 0.13 J ND ND 0.10 J ND ND ND
5-Dec-12 0.10 0.20 --- --- ND --- 0.11 J ND ND 0.27 ND --- ND
12-Jun-13 0.10 0.20 --- --- ND --- ND ND ND 0.56 ND ND ND
28-Oct-13 0.10 0.20 --- --- ND --- 0.15 J ND ND 0.11 J ND ND ND
6-May-14 0.10 0.20 --- --- ND --- 0.15 J ND ND ND ND ND ND
23-Oct-14 0.10 0.20 --- --- * ND ND ND ND 0.38 ND ND ND
20-May-15 0.10 0.20 --- --- --- ND 0.13 J ND ND 0.45 ND ND ND
8-Dec-15 0.10 0.20 --- --- --- ND ND ND ND ND ND ND ND
Nickel 15-Sep-94 --- 50 ND NI NI NI ND ND 100 ND NI NI ND
1-Oct-94 --- 50 --- NI NI NI --- ND --- --- NI NI ND
18-Jan-95 --- 50 ND NI NI NI ND ND ND ND NI NI ND
6-Feb-95 --- 50 ND NI NI NI ND ND 71.0 ND NI NI ND
1-Mar-95 --- 50 ND NI NI NI ND ND ND ND NI NI ND
1-Aug-95 --- 50 ND NI --- --- ND ND ND ND NI NI ND
1-Jan-96 --- 50 ND NI --- --- ND ND ND ND NI NI ND
1-Feb-96 --- 50 ND NI --- --- ND ND ND ND NI NI ND
1-May-96 --- 50 ND NI --- --- ND ND ND ND NI NI ND
1-Oct-96 --- 50 ND NI --- --- ND ND ND ND NI NI ND
1-May-97 --- 50 ND NI --- --- ND ND ND ND NI NI ND
1-Nov-97 --- 50 ND NI --- --- ND ND 80.0 ND NI NI ND
1-May-98 --- 50 ND NI --- --- ND ND 90.0 ND NI NI ND
1-Nov-98 --- 50 ND NI --- --- ND ND 74.0 ND NI NI ND
11-May-99 --- 5 21.0 33.0 --- --- 16.0 11.0 63.0 14.0 53.0 ND ND
18-Oct-99 --- 50 180 67.0 --- --- 55.0 ND 570 ND ND ND ND
3-May-00 --- 50 ND ND --- --- ND ND ND ND 71.0 ND ND
7-Nov-00 --- 50 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 50 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 50 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 50 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 50 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 50 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 50 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 50 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04---50NDND --- ---NDNDNDND ND ND ND
5-May-05---50NDND --- ---NDNDNDND ND ND ND
3-Nov-05 --- 50 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 50 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 50 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 50 --- 2.2 J --- --- 2.1 J 2.2 J 3.7 J 4.1 J ND ND ND
NC 2L = 100 µg/L (10/23/07) 29-Nov-07 --- 50 --- 3.9 J --- --- ND 7.3 J 8.0 J 2.2 J ND ND ND
29-May-08 1.7 50.0 --- 3.6 J --- --- 3.1 J 5.6 J 3.0 J 4.3 J 2.5 J ND ND
6-Nov-08 1.7 50.0 --- 2.2 J --- --- 2.9 J 5.6 J 6.8 J 5.1 J 5.6 J ND ND
3-Jun-09 1.7 50.0 --- 3.1 B --- --- 2.6 B 8.5 B ND 4.1 B 2.8 B 2.2 B 1.7 J
18-Nov-09 1.7 50.0 --- 2.4 J --- --- 3.2 J 5.9 J 4.9 J 4.9 J 1.8 J ND ND
16-Jun-10 1.7 50.0 --- 1.7 J --- --- 4.5 J 13.1 J 8.2 J 3.4 J 1.7 J ND ND
1-Dec-10 1.7 50.0 --- ND 19.0 J --- 3.1 J 4.1 J 7.8 J 3.7 J ND ND ND
1-Jun-11 1.7 50.0 --- ND 4.7 B --- 2.2 B 3.5 B 2.2 B 3.0 B ND ND 2.3 J
20-Dec-11 5.0 50.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 5.0 50.0 --- --- ND --- ND ND ND ND 5.2 J ND ND
5-Dec-12 5.0 50.0 --- --- ND --- ND ND 6.7 J ND ND ND ND
12-Jun-13 5.0 50.0 --- --- ND --- ND ND 5.2 J 5.4 J ND ND ND
28-Oct-13 5.0 50.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 5.0 50.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 5.0 50.0 --- --- * ND 6.0 J ND ND ND ND ND ND
20-May-15 2.5 50.0 --- --- --- ND 5.3 J 4.6 J 3.1 J 4.4 J ND ND ND
8-Dec-15 2.5 50.0 --- --- --- ND 5.5 J 3.4 J 17.7 J 4.2 J ND ND ND
Burke County - John's River C and D over MSW Landfill
Permit 12-03 Page 7 of 11 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
DowngradientBackground
Selenium 29-May-08 3.8 10.0 --- ND --- --- ND 6.1 J ND ND 5.8 J ND ND
6-Nov-08 3.8 10.0 --- ND --- --- 13.2 6.4 J 6.7 J ND 5.8 J ND ND
3-Jun-09 3.8 10.0 --- ND --- --- ND 5.4 J ND ND ND ND ND
18-Nov-09 3.8 10.0 --- ND --- --- ND 4.3 J 4.7 J 4.4 J 5.0 J ND ND
NC 2L = 20 µg/L (01/01/10) 16-Jun-10 3.8 10.0 --- ND --- --- 3.8 J ND 6.9 J ND ND ND ND
1-Dec-10 3.8 10.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 3.8 10.0 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 10.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 10.0 10.0 --- --- ND --- 11.7 11.3 ND ND ND ND ND
5-Dec-12 10.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 10.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 10.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 10.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 10.0 10.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 5.0 10.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 5.0 10.0 --- --- --- ND ND ND ND ND ND ND ND
Silver 6-Feb-95 --- 10 ND NI NI NI 11.0 ND 11.0 ND NI NI ND
1-Mar-95 --- 10 ND NI NI NI ND ND ND ND NI NI ND
1-Aug-95 --- 1 ND NI --- --- ND ND ND ND NI NI ND
1-Jan-96 --- 1 ND NI --- --- ND ND ND ND NI NI ND
1-Feb-96 --- 1 ND NI --- --- ND ND ND ND NI NI ND
1-May-96 --- 1 ND NI --- --- ND ND ND ND NI NI ND
1-Oct-96 --- 1 ND NI --- --- ND ND ND ND NI NI ND
1-May-97 --- 5 ND NI --- --- 6.0 ND ND ND NI NI ND
1-Nov-97 --- 1 ND NI --- --- ND ND ND ND NI NI ND
1-May-98 --- 1 ND NI --- --- ND ND ND ND NI NI ND
1-Nov-98 --- 1 ND NI --- --- ND ND ND ND NI NI ND
11-May-99---2NDND --- --- NDNDNDND ND ND ND
18-Oct-99 --- 10 ND ND --- --- ND ND ND ND ND ND ND
3-May-00 --- 10 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-00 --- 10 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 10 15.0 B 15.0 B --- --- 14.0 B 15.0 B 14.0 B 12.0 B 16.0 B 16.0 B 15.0
14-Nov-02 --- 10 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 10 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 10 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 10 --- ND --- --- ND ND ND ND ND ND ND
NC 2L = 17.5 µg/L (10/23/07) 29-Nov-07 --- 10 --- ND --- --- ND ND ND ND ND ND ND
29-May-08 0.10 10.0 --- 0.14 J --- --- 0.59 J 1.1 J 0.45 J ND 0.57 J ND ND
6-Nov-08 0.10 10.0 --- 0.25 B --- --- 1.1 B 2.1 J 1.3 J 0.26 B 1.1 B 0.22 B 0.23 J
3-Jun-09 0.10 10.0 --- 0.68 B --- --- 1.0 B 1.4 B 0.73 B 0.13 B 0.76 B 1.0 B 0.31 J
18-Nov-09 0.10 10.0 --- 0.28 B --- --- 0.72 B 1.0 B 0.61 B 0.19 B 0.57 B 0.19 B 0.23 J
NC 2L = 20 µg/L (01/01/10) 16-Jun-10 0.10 10.0 --- ND --- --- ND ND ND ND ND ND ND
1-Dec-10 0.10 10.0 --- ND ND --- ND 0.24 J ND ND ND ND ND
1-Jun-11 0.10 10.0 --- 0.39 B 0.16 B --- 0.22 B 0.60 B 0.32 B 0.29 B 0.22 B 0.23 B 0.17 J
20-Dec-11 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 5.0 10.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 2.5 10.0 --- --- --- ND ND 3.6 J ND ND ND ND ND
8-Dec-15 2.5 10.0 --- --- --- ND ND ND ND ND ND ND ND
Burke County - John's River C and D over MSW Landfill
Permit 12-03 Page 8 of 11 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
DowngradientBackground
Sulfide 1-Aug-95 --- 100 900 NI --- --- ND 600 ND 100 NI NI ND
1-Jan-96 --- 100 ND NI --- --- ND 300 ND ND NI NI ND
1-Feb-96 --- 100 ND NI --- --- ND 100 ND ND NI NI ND
1-May-96 --- 100 200 NI --- --- ND 900 700 300 NI NI ND
1-Oct-96 --- 100 2800 NI --- --- ND 200 3000 7500 NI NI ND
1-May-97 --- 50 ND NI --- --- ND ND ND ND NI NI ND
1-Nov-97 --- 50 ND NI --- --- ND ND ND ND NI NI ND
1-May-98 --- 50 50 NI --- --- ND ND ND ND NI NI ND
1-Nov-98 --- 50 ND NI --- --- 130 ND 80.0 110 NI NI ND
11-May-99 --- 50 ND ND --- --- ND ND ND ND --- ND ND
18-Oct-99 --- 1000 ND ND --- --- --- ND ND ND ND ND ND
7-Nov-00 --- 1000 ND --- --- --- ND ND ND ND ND --- ND
31-May-01 --- 1000 ND --- --- --- ND ND ND ND ND --- ND
7-Nov-01 --- 1000 ND --- --- --- ND ND ND ND ND --- ND
14-Nov-02 --- 1000 ND --- --- --- ND ND ND ND ND --- ND
20-Nov-03 --- 1000 ND --- --- --- ND ND ND ND ND --- ND
10-Nov-04 --- 1000 ND --- --- --- ND ND ND ND ND --- 6
3-Nov-05 --- --- --- ND --- --- ND ND 1800 ND ND --- ND
2-Nov-06 --- 1000 --- ND --- --- ND ND ND ND ND --- ND
NC 2L = NE (10/23/07) 29-Nov-07 --- 1000 --- ND --- --- ND ND ND ND ND --- ND
6-Nov-08 100 1000 --- ND --- --- ND ND ND ND ND --- ND
3-Jun-09 100 1000 --- ND --- --- --- ND ND --- ND --- ND
18-Nov-09 100 1000 --- ND --- --- ND ND ND ND ND --- ND
16-Jun-10 100 1000 --- ND --- --- --- ND ND --- ND --- ND
1-Dec-10 100 1000 --- ND ND --- ND ND ND ND ND --- ND
5-Dec-12 100 1000 --- --- ND --- ND ND ND ND ND --- ND
12-Jun-13 100 1000 --- --- ND --- ND ND ND ND ND --- ND
28-Oct-13 100 1000 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 100 1000 --- --- * ND ND ND ND ND ND --- ND
8-Dec-15 100 1000 --- --- --- ND ND ND ND ND ND --- ND
Thallium 1-Nov-97 --- 1 2.0 B NI --- --- 2.0 B 2.0 B 3.0 B 1.0 B NI NI 2.0
1-May-98 --- 1 ND NI --- --- ND ND ND 1.0 NI NI ND
1-Nov-98 --- 1 ND NI --- --- ND ND ND 1.0 NI NI ND
11-May-99 --- 2 2.0 3.0 --- --- 4.0 3.0 4.0 ND 3 2.0 ND
18-Oct-99 --- 10 ND ND --- --- ND ND ND ND ND ND ND
3-May-00 --- 10 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-00 --- 10 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 10 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 10 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04---10NDND --- ---NDNDNDND ND ND ND
5-May-05 --- 10 16.0 ND --- --- 41.0 23.0 25.0 14.0 26.0 ND ND
3-Nov-05 --- 10 --- ND --- --- 19.0 17.0 15.0 ND 13.0 ND ND
25-May-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 5.5 --- ND --- --- 0.169 J 0.29 J 0.221 J 0.131 J 0.078 J ND ND
GWPS = 0.28 µg/L (10/23/07) 29-Nov-07 --- 5.5 --- 0.042 J --- --- 0.118 J 0.321 J 0.199 J 0.150 J 0.065 J ND ND
29-May-08 3.0 5.5 --- ND --- --- ND ND ND ND ND ND ND
6-Nov-08 3.0 5.5 --- ND --- ---8.9 ND ND ND ND ND ND
3-Jun-09 3.0 5.5 --- ND --- --- ND ND ND ND ND 14.8 ND
18-Nov-09 3.0 5.5 --- ND --- --- ND ND ND ND ND ND 4.2 J
16-Jun-10 3.0 5.5 --- ND --- --- 5.3 J 7.7 4.1 J ND 4.0 J ND ND
Resample> 5-Aug-10 3.0 5.5 --- --- --- --- ---20.4 --- --- --- --- 3.2 J
GWPS = 0.2 µg/L (10/1/1) 1-Dec-10 3.0 5.5 --- 3.3 B ND --- 3.3 B 9.1 B 5.1 B ND 7.8 B ND 3.1 J
1-Jun-11 3.0 5.5 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 5.4 5.5 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 5.4 5.5 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 5.4 5.5 --- --- ND --- ND ND ND ND ND ND 6.8
12-Jun-13 5.4 5.5 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 5.4 5.5 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 5.4 5.5 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 5.4 5.5 --- --- * ND ND ND ND ND ND ND ND
20-May-15 5.0 5.5 --- --- --- ND ND 6.4 ND ND ND ND ND
8-Dec-15 5.0 5.5 --- --- --- ND ND ND ND ND ND ND ND
Tin 6-Nov-08 1.8 100 --- ND --- --- 2.3 J 3.8 J 2.1 J ND 2.9 J --- ND
GWPS = 0.28 µg/L (10/23/07) 3-Jun-09 --- --- --- --- --- --- --- --- --- --- --- --- ---
18-Nov-09 1.8 100 --- ND --- --- ND ND ND ND ND ND ND
GWPS =2,100 µg/L (01/01/10) 16-Jun-10 1.8 100 --- ND --- --- ND ND ND ND --- --- ND
GWPS =2,000 µg/L (10/1/10) 1-Dec-10 1.8 100 --- ND ND --- ND ND ND ND ND --- ND
1-Jun-11 1.8 100 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 5.0 100 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 5.0 100 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 5.0 100 --- --- ND --- ND ND ND ND ND --- ND
12-Jun-13 5.0 100 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 5.0 100 --- --- ND --- ND 5.1 J ND ND ND --- ND
6-May-14 5.0 100 --- --- ND --- ND ND ND ND ND --- ND
23-Oct-14 5.0 100 --- --- * ND ND ND ND ND ND --- ND
20-May-15 2.5 100 --- --- --- ND ND ND ND ND ND --- ND
8-Dec-15 2.5 100 --- --- --- ND ND ND ND ND ND --- ND
Burke County - John's River C and D over MSW Landfill
Permit 12-03 Page 9 of 11 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
DowngradientBackground
Vanadium 1-May-97 --- 5 12.0 NI --- --- 5.0 ND 66.0 9.0 NI NI ND
1-Nov-97 --- 40 ND NI --- --- ND ND 180 ND NI NI ND
1-May-98 --- 5 14.0 NI --- --- 6.0 7.0 159 22.0 NI NI ND
1-Nov-98 --- 5 15.0 NI --- --- 12.0 8.0 110 14.0 NI NI ND
11-May-99 --- 5 55.0 58.0 --- --- 25.0 16.0 72.0 31.0 71.0 100 ND
18-Oct-99 --- 40 630 150 --- --- 150 79.0 690 62.0 ND ND ND
3-May-00 --- 40 ND ND --- --- ND ND ND ND 140 ND ND
7-Nov-00 --- 40 ND 66.0 --- --- ND ND ND ND ND ND ND
31-May-01 --- 40 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 40 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 40 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 40 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 40 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 40 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 40 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 40 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 40 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 40 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 40 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 40 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 25 --- ND --- --- ND ND ND ND ND ND 1.3 J
GWPS = 3.5 µg/L (10/23/07) 29-Nov-07 --- 25 --- 7.3 J --- --- ND ND ND ND ND ND ND
29-May-08 0.2 25.0 --- 0.43 J --- --- ND 2.4 J 1.3 J 3.7 J ND ND ND
6-Nov-08 0.2 25.0 --- 3.0 B --- --- 2.2 B 0.53 B 5.5 B 11.1 J 6.2 B 1.4 B 2.1 J
3-Jun-09 0.2 25.0 --- 0.94 B --- --- 0.47 B 0.91 B 0.66 B 5.2 J 1.8 B 2.7 B 1.0 J
18-Nov-09 0.20 25.0 --- 0.82 B --- --- 0.43 B 0.66 B 4.1 J 5.4 J 1.3 B 0.29 B 0.56 J
16-Jun-10 0.20 25.0 --- 1.1 B --- --- 4.5 B 28.5 8.3 J 2.0 B 1.3 B 0.66 B 0.98 J
Resample> 5-Aug-10 0.20 25.0 --- --- --- --- --- 1.5 B --- --- --- --- 0.62 J
GWPS = 0.3 µg/L (10/1/10) 1-Dec-10 0.20 25.0 --- 0.48 J 55.2 --- 3.2 J 0.63 J 5.7 J 0.33 J 2.9 J 2.4 J ND
Resample> 13-Jan-11 0.20 25.0 --- --- 0.55 B --- --- --- --- --- --- --- 0.33 J
1-Jun-11 0.20 25.0 --- 0.69 J 17.2 J --- 0.34 J 1.5 J 0.32 J 0.37 J ND 5.5 J ND
20-Dec-11 5.0 25.0 --- --- 10.7 J --- ND ND ND ND ND ND ND
30-May-12 5.0 25.0 --- --- 9.2 J --- ND ND ND ND 7.9 J ND ND
5-Dec-12 5.0 25.0 --- --- ND --- ND ND 6.1 J ND ND ND ND
12-Jun-13 5.0 25.0 --- --- ND --- ND ND ND 5.6 J ND ND ND
28-Oct-13 5.0 25.0 --- --- ND --- ND 8.3 J ND ND ND ND ND
6-May-14 5.0 25.0 --- --- 6.7 J --- ND ND ND ND ND ND ND
22-Oct-14 5.0 25.0 --- --- * 9.6 J ND ND ND ND ND ND ND
20-May-15 2.5 25.0 --- --- --- ND 9.1 J 20.1 J 10.7 J 2.6 J 11.3 J ND ND
8-Dec-15 2.5 25.0 --- --- --- 6.6 J 20.4 J 23.5 J 36.9 3.0 J 11.5 J ND ND
Lab Re-run analyses> 8-Dec-15 2.5 25.0 --- --- --- --- --- --- 19.8 J --- --- --- ---
Zinc 15-Sep-94 --- 10 36.0 NI NI NI ND 27.0 ND ND NI NI ND
1-Oct-94 --- 10 --- NI NI NI --- 52.0 --- --- NI NI ND
18-Jan-95 --- 10 21.0 NI NI NI ND 27.0 21.0 ND NI NI ND
6-Feb-95 --- 10 21.0 NI NI NI ND 18.0 37.0 14.0 NI NI ND
1-Mar-95 --- 10 27.0 NI NI NI 14.0 24.0 29.0 29.0 NI NI ND
1-Aug-95 --- 10 ND NI --- --- ND 29.0 23.0 27.0 NI NI ND
1-Jan-96 --- 10 28.0 NI --- --- 22.0 37.0 49.0 21.0 NI NI ND
1-Feb-96 --- 10 48.0 NI --- --- 27.0 24.0 31.0 26.0 NI NI ND
1-May-96 --- 10 46.0 NI --- --- 46.0 48.0 56.0 55.0 NI NI ND
1-Oct-96 --- 10 23.0 NI --- --- 16.0 30.0 20.0 16.0 NI NI ND
1-May-97 --- 10 50.0 NI --- --- 50.0 50.0 80.0 50.0 NI NI ND
1-Nov-97 --- 10 60.0 NI --- --- 20.0 30.0 80.0 ND NI NI ND
1-May-98 --- 10 40.0 NI --- --- 30.0 40.0 110 30.0 NI NI ND
1-Nov-98 --- 10 29.0 NI --- --- 24.0 23.0 150 ND NI NI ND
11-May-99 --- 20 64.0 43.0 --- --- 150 28.0 68.0 61.0 69.0 210 ND
18-Oct-99 --- 50 570 89.0 --- --- 160 140 700 75.0 J ND 99.0 ND
3-May-00 --- 50 ND ND --- --- ND ND ND 62.0 J 160 63.0 J ND
7-Nov-00 --- 50 130 150 --- --- ND 110 60.0 70.0 ND ND ND
31-May-01 --- 50 ND ND --- --- ND ND 79.0 ND ND ND ND
7-Nov-01 --- 50 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 50 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 50 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 50 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 50 ND 100 --- --- 50.0 ND ND ND ND ND ND
6-May-04 --- 50 ND ND --- --- 78.0 ND ND ND ND ND ND
10-Nov-04 --- 50 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 50 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 50 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 50 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 50 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 10 --- 5.9 B --- --- 7.6 B 11.4 19.3 14.0 46.5 1.3 1.6 J
NC 2L = 1,050 µg/L (10/23/07) 29-Nov-07 --- 10 --- 20.4 --- --- 10.9 B 62.0 30.2 16.4 44.5 35.6 3.1 J
29-May-08 0.40 10.0 --- 2.9 B --- --- 20.4 44.3 27.9 25.7 35.2 25.0 3.0 J
6-Nov-08 0.40 10.0 --- 12.1 B --- --- 10.2 B 16.6 18.6 27.1 76.7 30.9 2.7 J
3-Jun-09 0.40 10.0 --- 3.9 B --- --- 4.6 B 40.5 B 7.0 B 20.0 B 19.2 B 6.6 B 82.0
18-Nov-09 0.40 10.0 --- 4.2 B --- --- 7.2 B 21.4 18.6 22.1 13.6 B 2.5 B 3.1 J
NC 2L = 1,000 µg/L (01/01/10) 16-Jun-10 0.40 10.0 --- ND --- --- 6.0 J 56.2 20.5 10.1 24.0 ND ND
1-Dec-10 0.40 10.0 --- 6.5 J 76.5 --- 14.1 33.4 25.6 16.2 119 5.4 J 0.62 J
1-Jun-11 0.40 10.0 --- 8.3 B 31.6 B --- 14.3 B 40.8 B 27.2 B 20.1 B 24.9 B 44.7 B 13.7
20-Dec-11 10.0 10.0 --- --- 19.6 --- 13.3 40.8 20.2 17.6 30.5 15.8 ND
30-May-12 10.0 10.0 --- --- 11.5 --- ND 39.2 16.6 13.3 48.8 ND ND
5-Dec-12 10.0 10.0 --- --- ND --- 12.1 17.8 24.4 17.8 ND 11.2 ND
12-Jun-13 10.0 10.0 --- --- 31.4 --- ND 38.9 B ND 23.7 B ND 32.2 B 76.5
28-Oct-13 10.0 10.0 --- --- 15.9 --- ND 68.9 14.3 22.0 18.2 ND ND
6-May-14 10.0 10.0 --- --- 13.7 --- ND 23.4 12.2 17.2 11.7 ND ND
23-Oct-14 10.0 10.0 --- --- * ND ND 17.8 11.2 18.5 32.2 13.9 ND
20-May-15 5.0 10.0 --- --- --- 26.4 9.6 J 24.2 15.6 19.8 20.4 ND ND
8-Dec-15 5.0 10.0 --- --- --- ND 9.0 J 20.0 65.1 19.0 47.3 8.2 J ND
Burke County - John's River C and D over MSW Landfill
Permit 12-03 Page 10 of 11 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
DowngradientBackground
Alkalinity, Total as CaCO3 1-Jun-11 5,000 5,000 --- 45,100 --- --- --- 177,000 70,700 --- 109,000 --- ND
NC 2L = NE (01/01/10) 20-Dec-11 5,000 5,000 --- --- 8,580 --- 53,600 189,000 70,800 ND 77,200 47,200 ND
30-May-12 1,000 1,000 --- --- 8,140 --- 64,700 200,000 76,700 8,360 104,000 44,400 ND
5-Dec-12 1,000 5,000 --- --- 7,690 --- 22,600 178,000 76,600 ND 106,000 46,500 ND
12-Jun-13 1,000 5,000 --- --- 7,950 --- 138,000 202,000 111,000 7,020 99,700 51,700 ND
28-Oct-13 1,000 5,000 --- --- 8,140 --- 69,900 197,000 91,300 9,520 116,000 45,000 ND
6-May-14 1,000 5,000 --- --- 8,060 --- 85,900 208,000 90,600 5,520 119,000 45,700 ND
23-Oct-14 1,000 5,000 --- --- * 1,360 J 88,100 215,000 96,100 7,500 122,000 52,000 ---
20-May-15 1,000 5,000 --- --- --- ND 67,300 153,000 67,500 8,780 92,100 41,600 ---
8-Dec-15 1,000 NE --- --- --- 1,030 J 98,400 202,000 88,800 9,130 95,900 46,200 ---
Chloride 1-Jun-11 5,000 5,000 --- ND --- --- --- 17,000 6,330 --- 7,870 --- ND
NC 2L = 250,000 µg/L (01/01/10) 20-Dec-11 5,000 5,000 --- --- ND --- 6,320 20,200 6,400 ND 6,530 ND ND
30-May-12 1,000 1,000 --- --- 1,480 --- 6,190 20,000 ND 2,100 5,840 ND ND
5-Dec-12 1,000 1,000 --- --- 2,130 --- 5,970 19,500 7,290 2,060 7,430 1,130 ND
12-Jun-13 1,000 1,000 --- --- 1,380 --- 13,300 19,500 7,500 2,260 5,100 ND ND
28-Oct-13 1,000 1,000 --- --- 1,120 --- 11,400 18,100 7,750 2,210 8,490 ND ND
6-May-14 1,000 1,000 --- --- ND --- 17,300 18,200 8,140 1,890 8,920 ND ND
23-Oct-14 500 1,000 --- --- * ND 19,200 20,800 9,050 1,570 8,120 642 J ND
20-May-15 500 1,000 --- --- --- --- 14,000 25,300 9,680 1,720 10,400 572 J ---
8-Dec-15 500 NE --- --- --- 859 J 26,500 30,800 9,400 1,910 4,190 945 J ---
Sulfate 1-Jun-11 5,000 5,000 --- ND --- --- --- ND ND --- ND --- ND
NC 2L = 250,000 µg/L (01/01/10) 20-Dec-11 5,000 5,000 --- --- ND --- 5,150 ND ND ND ND 8,630 ND
30-May-12 2,000 250,000 --- --- ND --- 5,380 J ND ND ND ND 8,860 J ND
5-Dec-12 2,000 250,000 --- --- ND --- 2,880 J 2,920 J 4,400 J ND 2,320 J 8,910 J ND
12-Jun-13 2,000 250,000 --- --- ND --- 11,200 J 3,080 J 2,910 J 6,940 J ND 9,310 J ND
28-Oct-13 2,000 250,000 --- --- ND --- 4,420 J ND 2,940 J ND ND 8,150 J ND
6-May-14 2,000 250,000 --- --- ND --- 10,500 J 2,300 J 3,720 J ND 2,070 J 8,780 J ND
23-Oct-14 1,000 250,000 --- --- * ND 7,270 J 2,280 J 3,740 J 1,240 J 1,940 J 9,710 J ND
20-May-15 1,000 250,000 --- --- --- ND 5,620 J 2,310 J 3,440 J ND 2,150 J 8,780 J ---
8-Dec-15 1,000 250,000 --- --- --- ND 10,200 J 1,530 J 2,020 J ND ND 9,260 J ---
Total Dissolved Solids, Dissolved 1-Jun-11 25,000 25,000 --- 62,000 --- --- --- 200,000 93,000 --- 127,000 --- ND
NC 2L = 500,000 µg/L (01/01/10) 20-Dec-11 25,000 25,000 --- --- ND --- 59,000 196,000 82,000 ND 103,000 78,000 ND
30-May-12 25,000 25,000 --- --- 37,000 --- 85,000 12,500 J 109,000 ND 136,000 90,000 ND
5-Dec-12 25,000 25,000 --- --- 35,000 --- 50,000 219,000 109,000 28,000 134,000 97,000 ND
12-Jun-13 25,000 25,000 --- --- 34,000 --- 177,000 225,000 136,000 ND 111,000 107,000 ND
28-Oct-13 25,000 25,000 --- --- 49,000 --- 109,000 227,000 134,000 ND 138,000 112,000 ND
6-May-14 25,000 25,000 --- --- 34,000 --- 136,000 234,000 115,000 32,000 126,000 102,000 ND
23-Oct-14 25,000 25,000 --- --- * ND 126,000 238,000 119,000 ND 129,000 98,000 ND
20-May-15 25,000 25,000 --- --- --- ND 112,000 252,000 122,000 30,000 135,000 88,000 ---
8-Dec-15 25,000 NE --- --- --- ND 182,000 280,000 117,000 ND 106,000 93,000 ---
Notes:
(Abbreviations and Referrences)
All concentrations in micrograms per liter (µg/L) = parts per billion.
--- = Not sampled for this parameter or not reported.
AB = Monitoring well abandoned.
B = Blank-Qualified (Concentration suspected to reflect laboratory or field contamination based on similar concentrations detected in field, trip, or method blanks).
D = Sample was diluted when analyzed.
DL = Laboratory Detection Limit.
GWPS = Groundwater Protection Standard set by NC-DENR-SWS for constituents with no listed NC 2L standard.
When the NC 2L Groundwater Standard has not been established, the GWPS will be used.
J = Estimated value - concentration is less than the RL but greater than the DL.
NC 2L = Groundwater Standard from 15A NCAC 2L.
ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006).
NE = No NC 2L or GWPS established.
NI = Not Installed; monitoring was not yet installed.
RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present).
Values above the NC2L Standard or GWPS are bold.
Notes: (Event Narratives)
Volatile organics (8260) for MW-9 for November 10, 2004 sampling event were unable to be analyzed and were resampled on December 1, 2004.
There was a resamplinging event on August 2, 2007 for MW-16D because the prevoius samples from the May 2007 were analyzed out of hold time. There were no detects in the resample.
* MW-21 replaced MW-20 as the background well starting with the Fall 2014 sampling event; however MW-20 continues to be sampled as a compliance well for the C&D Expansion (Phase 1A).
See the Water Quality Monitrong Report for the C&D Expansion Area for current results for MW-20.
The dates on the table above reflect the last samples were collected during the semiannual monitoring event. Individual collection dates are preserved in the Lab Reports (Appendix B).
Pace Analytical Re-ran the analysis for Antimony, Chromium, and Vanadium in MW-12 on January 19, 2016 from the samples collected in December 2016, and the results are included in the table.
A Verification Sampling Event was performed for beta-BHC in MW-11 and Antimony and Chromium in MW-12 on February 4, 2016, for the December 2015 event and results are included.
Burke County - John's River C and D over MSW Landfill
Permit 12-03 Page 11 of 11 Joyce Engineering

Appendix E

Historical Detected Organic Groundwater Constituents

APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample EPA
Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Organic Compounds
Acetone 30-May-07 --- 100.0 --- 2.7 B --- --- ND ND ND ND ND ND 2.1 JNC 2L = 700 µg/L (10/23/07)29-Nov-07 --- 100.0 --- 8.1 B --- --- 3 B ND 2.8 B 8.1 B 13 B 2.6 B 5.1 J
29-May-08 20.0 100.0 --- ND --- --- ND ND ND ND ND ND ND
6-Nov-08 20.0 100.0 --- 26.8 J --- --- ND ND ND ND ND ND ND
3-Jun-09 2.2 100.0 --- 48.3 J --- --- 6.5 J ND ND ND 18.5 J ND ND
18-Nov-09 2.2 100.0 --- ND ND --- ND ND ND ND ND ND ND
NC 2L = 6,000 µg/L (01/01/10) 16-Jun-10 2.2 100.0 --- 5.3 B --- --- ND 3.1 B ND ND ND ND 7.2 J
1-Dec-10 2.2 100.0 --- ND ND --- 8.4 B ND ND ND 56.6 J ND 3.7 J
1-Jun-11 2.2 100.0 --- 3.5 B ND --- 3.4 B 8.1 B 7.7 B ND 80 J ND 3.9 J20-Dec-11 2.2 100.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 2.2 100.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 10.0 100.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 10.0 100.0 --- --- ND --- 33 J ND ND ND 20.5 J ND ND
28-Oct-13 10.0 100.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 EPA 8260 10.0 100.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 EPA 8260 10.0 100.0 --- --- * ND ND ND 10.4 J ND ND ND ND
21-May-15 EPA 8260 10.0 100.0 --- --- --- ND ND ND ND ND ND ND ND8-Dec-15 EPA 8260 10.0 100.0 --- --- --- ND ND ND ND ND 16.5 J ND ND
Acrolein 8-Dec-15 EPA 8260 1.6 53.0 --- --- --- 1.6 B ND ND ND ND ND --- 2.8 J
NC 2L = 6,000 µg/L (01/01/10)
Benzene 1-Oct-96 --- 5.0 --- NI --- --- ND 6 ND ND NI NI ---
1-May-97 ---5.0 ND NI --- ---ND 6.8 2.7 J ND NI NI ---
1-Nov-97 ---1.0 ND NI --- ---ND 9 ND ND NI NI ---1-May-98 --- 5.0 ND NI --- ---ND 10 9.4 ND NI NI ---24-Nov-98 --- 2.0 ND NI --- ---ND 11.6 ND ND NI NI ---
10-May-99 --- 5.0 ND ND --- ---ND 13 ND ND 5.3 ND ND
18-Oct-99 --- 5.0 ND ND --- ---ND 12 ND ND 5.4 ND ND
3-May-00 --- 5.0 ND ND --- ---ND 10 ND ND 6.3 ND ND
7-Nov-00 --- 5.0 ND ND --- ---ND 9.2 ND ND ND ND ND
31-May-01 --- 5.0 ND ND --- ---ND 7.7 ND ND 5.8 ND ND
7-Nov-01 --- 5.0 ND ND --- ---ND 8.1 5.2 ND 6.7 ND ND22-May-02 --- 5.0 ND ND --- ---ND 8.2 8.1 ND 8.0 ND ND14-Nov-02 --- 5.0 ND ND --- --- ND 5.1 7.7 ND 9.4 ND ND
14-May-03 --- 5.0 ND ND --- --- ND 8 5.4 7 13 ND ND
20-Nov-03 --- 5.0 ND ND --- --- ND 7.3 5.7 7.5 9.2 ND ND
6-May-04 --- 5.0 ND ND --- --- ND 7.3 7.2 9.3 9.6 ND ND
10-Nov-04 --- 5.0 ND ND --- --- ND 7.5 6 8.5 10 ND ND
27-May-05 --- 5.0 ND ND --- --- ND 8 9 11 9 ND ND
3-Nov-05 --- 5.0 --- ND --- --- ND ND 58 6ND ND
25-May-06 --- 5.0 --- ND --- --- ND ND 6.1 8.5 5.3 ND ND2-Nov-06 --- 5.0 --- ND --- --- ND 5.3 5.3 11 7.6 ND ND30-May-07 --- 1.0 --- 0.22 J --- --- 0.87 J 7.3 7.4 13 6.6 ND ND
NC 2L = 1 µg/L (10/23/07) 29-Nov-07 --- 1.0 --- 0.6 J --- --- 0.79 J 3.6 2.8 12 3.3 ND ND
29-May-08 0.3 1.0 --- 0.49 J --- --- 0.88 J 4.6 4.6 13.5 4.1 ND ND
6-Nov-08 0.3 1.0 --- 0.53 J --- --- 0.81 J 4.3 4.4 12 3.1 ND ND
3-Jun-09 0.3 1.0 --- 0.67 J --- ---1.2 4.5 5.4 15.3 4.1 ND ND
18-Nov-09 0.3 1.0 --- 1.3 --- --- 0.81 J 4 5.6 14.9 3.3 ND ND
16-Jun-10 0.3 1.0 --- 0.59 J --- --- 0.81 J 5.9 5 14.3 2.4 ND ND
1-Dec-10 0.3 1.0 --- ND ND --- 0.96 J 5 3 11.5 4 ND ND1-Jun-11 0.3 1.0 --- 0.99 J ND --- 1 5.4 3.9 16.1 1.2 ND ND20-Dec-11 0.3 1.0 --- --- ND --- 1 J 4.2 3.1 12.9 D 2 ND ND
30-May-12 0.3 1.0 --- --- ND --- ND 4.4 2.8 14.7 2 ND ND
5-Dec-12 0.3 1.0 --- --- ND --- 0.83 J 4.1 2.8 14.9 1.6 ND ND
12-Jun-13 0.3 1.0 --- --- ND ---1.5 3.5 4.2 15.9 2.9 ND ND
28-Oct-13 0.3 1.0 --- --- ND --- 1 4.1 4.1 15.6 2 ND ND
6-May-14 EPA 8260 0.3 1.0 --- --- ND ---1.6 3.9 3.8 17.2 2.1 ND ND
22-Oct-14 EPA 8260 0.3 1.0 --- --- * ND 1.8 2.8 3.0 14.9 1.8 ND ND21-May-15 EPA 8260 0.3 1.0 --- --- ND ND 1.3 2.8 2.8 12.3 1.2 ND ND8-Dec-15 EPA 8260 0.3 1.0 --- --- * ND 1.6 2.2 2.3 13.8 1.7 ND ND
Bromodichloromethane 30-May-07 --- 1.0 --- ND --- --- 0.54 J ND 0.63 J ND ND ND ND
NC 2L = 0.56 µg/L (10/23/07) 29-Nov-07 --- 1.0 --- ND --- --- ND ND ND ND ND ND ND
29-May-08 0.2 1.0 --- ND --- --- ND ND ND ND ND ND ND
6-Nov-08 0.2 1.0 --- ND --- --- ND ND ND ND ND ND ND
3-Jun-09 0.2 1.0 --- ND --- --- ND ND ND ND ND ND ND18-Nov-09 0.2 1.0 --- ND --- --- ND ND ND ND ND ND ND
NC 2L = 0.6 µg/L (01/01/10)16-Jun-10 0.2 1.0 ---ND --- ---ND ND ND ND ND ND ND
1-Dec-10 0.2 1.0 ---ND ND ---ND ND ND ND ND ND ND
1-Jun-11 0.2 1.0 ---ND ND ---ND ND ND ND ND ND ND
20-Dec-11 0.2 1.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 0.2 1.0 --- ---ND ---ND ND ND ND ND ND ND
5-Dec-12 0.2 1.0 --- ---ND ---ND ND ND ND ND ND ND
12-Jun-13 0.2 1.0 --- ---ND ---ND ND ND ND ND ND 18.6028-Oct-13 0.18 1.0 --- ---ND ---ND ND ND ND ND ND ND6-May-14 EPA 8260 0.18 1.0 --- ---ND ---ND ND ND ND ND ND ND
22-Oct-14 EPA 8260 0.18 1.0 --- ---*NDND ND ND ND ND ND ND
21-May-15 EPA 8260 0.18 1.0 --- ------ ND ND ND ND ND ND ND ND
8-Dec-15 EPA 8260 0.18 1.0 --- ------ ND ND ND ND ND ND ND ND
Bromomethane 12-Jun-13 0.29 10.0 --- ---ND ---1.4 J ND ND ND ND ND ND
NC 2L = NE (10/23/07) 28-Oct-13 0.29 10.0 --- ---ND ---ND ND ND ND ND ND ND6-May-14 EPA 8260 0.29 10.0 --- ---ND ---ND ND ND ND ND ND ND22-Oct-14 EPA 8260 0.29 10.0 --- ---*NDND ND ND ND ND ND ND
21-May-15 EPA 8260 0.29 10.0 --- ------ ND ND ND ND ND ND ND ND
8-Dec-15 EPA 8260 0.29 10.0 --- ------ ND ND ND ND ND ND ND ND
2-Butanone (MEK) 20-Dec-11 1.0 100.0 --- --- ND --- ND ND ND 5.6
J
D ND ND ND
NC 2L = 4000 µg/L (10/23/07) 30-May-12 1.0 100.0 --- ---ND ---ND ND ND ND ND ND ND
5-Dec-12 1.0 100.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 1.0 100.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 1.0 100.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 EPA 8260 1.0 100.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 EPA 8260 1.0 100.0 --- --- * NDNDNDNDND ND ND ND
21-May-15 EPA 8260 1.0 100.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 EPA 8260 1.0 100.0 --- --- --- ND ND ND ND ND ND ND ND
Background Downgradient
Burke County
John's River C and D over MSW Landfill
Permit 12-03 Page 1 of 14 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample EPA
Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Background Downgradient
Carbon Disulfide 1-Nov-97 --- 1.0 8 NI --- --- ND ND ND ND NI NI ---
1-May-98 --- 5.0 ND NI --- --- ND ND ND ND NI NI ---24-Nov-98 --- 2.0 6.2 NI --- --- ND ND 8.9 ND NI NI ---10-May-99 --- 5.0 ND ND --- --- ND ND 6.7 9 ND 100 ND
18-Oct-99 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
3-May-00 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-00 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND14-Nov-02 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND14-May-03 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
27-May-05 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 ---100.0 ---ND --- ---ND ND ND ND ND ND ND25-May-06 ---100.0 ---ND --- ---ND ND ND ND ND ND ND2-Nov-06 ---100.0 ---ND --- ---ND ND ND ND ND ND ND30-May-07 --- 100.0 --- ND --- --- ND ND ND ND ND ND ND
NC 2L = 700 µg/L (10/23/07) 29-Nov-07 ---100.0 ---ND --- ---ND ND ND ND ND ND ND
29-May-08 1.2 100.0 ---ND --- ---ND ND ND ND ND ND ND
6-Nov-08 1.2 100.0 ---ND --- ---ND ND ND ND ND ND ND
3-Jun-09 1.20 100.0 ---ND --- ---ND ND ND ND ND ND ND
18-Nov-09 1.20 100.0 ---ND --- ---ND ND ND ND ND ND ND
16-Jun-10 1.20 100.0 ---ND --- ---ND ND ND ND ND ND ND1-Dec-10 1.20 100.0 ---ND ND ---ND ND ND ND ND ND ND1-Jun-11 1.20 100.0 ---ND ND ---ND ND ND ND ND ND ND
20-Dec-11 1.20 100.0 --- ---ND ---ND ND ND ND ND ND ND
30-May-12 1.20 100.0 --- ---ND ---ND ND ND ND ND ND ND
5-Dec-12 1.2 100.0 --- ---ND ---ND ND ND ND ND ND ND
12-Jun-13 1.2 100.0 --- ---ND ---ND ND ND ND ND ND ND
28-Oct-13 1.2 100.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 EPA 8260 1.2 100.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 EPA 8260 1.2 100.0 --- --- * ND ND ND ND ND ND ND 1.4 J21-May-15 EPA 8260 1.2 100.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 EPA 8260 1.2 100.0 --- --- --- ND ND ND ND ND ND ND ND
Chlorobenzene 30-May-07 --- 3.0 --- ND --- --- ND 0.63 J 1.1 J 0.3 J 0.61 J ND ND
NC 2L = 50 µg/L (10/23/07)29-Nov-07 --- 3.0 --- ND --- --- ND ND ND ND ND ND ND
29-May-08 0.2 3.0 --- ND --- --- ND 0.48 J 0.7 J 0.32 J 0.59 J ND ND
6-Nov-08 0.2 3.0 --- ND --- --- ND 0.53 J 0.8 J 0.3 J 0.59 J ND ND
3-Jun-09 0.2 3.0 --- ND --- --- 0.26 J 0.47 J 0.73 J 0.39 J 0.76 J ND ND18-Nov-09 0.2 3.0 --- ND --- --- ND 0.51 J 1.0 J 0.39 J 0.71 J ND ND16-Jun-10 0.2 3.0 --- ND --- --- ND 0.9 J 1.2 J 0.41 J 0.79 J ND ND
1-Dec-10 0.2 3.0 --- ND ND --- ND 0.74 J 0.63 J ND 0.72 J ND ND
1-Jun-11 0.2 3.0 --- ND ND --- ND 0.8 J 1.0 J 0.5 J 0.4 J ND ND
20-Dec-11 0.2 3.0 --- --- ND --- ND 0.7 J 0.7 J ND 0.7 J ND ND
30-May-12 0.2 3.0 --- --- ND --- 0.24 J 0.73 J 0.7 J 0.47 J 0.7 J ND ND
5-Dec-12 0.2 3.0 --- --- ND --- ND 0.7 J 0.6 J 0.54 J 0.7 J ND ND
12-Jun-13 0.2 3.0 --- --- ND --- 0.88 J 0.57 J 0.86 J 0.57 J 0.65 J ND ND
28-Oct-13 0.2 3.0 --- --- ND --- 0.35 J 0.93 J 0.94 J 0.6 J 0.91 J ND ND6-May-14 EPA 8260 0.2 3.0 --- --- ND --- 0.7 J 0.93 J 0.9 J 0.79 J 0.91 J ND ND22-Oct-14 EPA 8260 0.2 3.0 --- --- * ND 0.84 J 0.77 J 0.79 J 0.80 J 0.78 J ND ND
21-May-15 EPA 8260 0.2 3.0 --- --- --- ND 0.67 J 0.84 J 0.74 J 0.72 J 0.58 J ND ND
8-Dec-15 EPA 8260 0.2 3.0 --- --- --- ND 1.5 J 0.61 J 0.73 J 0.86 J 0.82 J ND ND
Burke County
John's River C and D over MSW Landfill
Permit 12-03 Page 2 of 14 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample EPA
Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Background Downgradient
Chloroethane 1-Sep-94 --- 10.0 ND NI NI NI ND 29 ND ND NI NI ---
1-Jan-95 --- 10.0 --- NI NI NI ND 16 ND ND NI NI ---1-Feb-95 ---10.0 ---NI NI NI ND32ND ND NI NI ---
1-Mar-95 ---10.0 ND NI NI NI ND34 11ND NI NI ---
1-Aug-95 ---10.0 ND NI --- ---ND47ND ND NI NI ---
1-Jan-96 --- 10.0 --- NI --- --- ND ND ND ND NI NI ---
1-Feb-96 ---10.0 ---NI --- ---ND28ND ND NI NI ---
1-May-96 ---10.0 ---NI --- ---ND34 11ND NI NI ---
1-Oct-96 ---10.0 ---NI --- ---ND 23 11.00 ND NI NI ---1-May-97 --- 5.0 3.8 J NI --- ---15 33 11 ND NI NI ---1-Nov-97 --- 1.0 3 NI --- ---10 ND7ND NI NI ---
1-May-98 --- 10.0 ND NI --- ---ND302810NI NI ---
24-Nov-98 --- 2.0 ND NI --- ---ND ND ND ND NI NI ---
10-May-99 --- 10.0 ND ND --- ---ND 10.0 ND ND17ND ND
18-Oct-99 --- 10.0 ND ND --- ---ND12ND ND21ND ND
3-May-00 --- 10.0 ND ND --- ---ND ND 6.1 6.7 19 ND ND
7-Nov-00 --- 10.0 ND ND --- ---ND ND ND ND13ND ND31-May-01 --- 10.0 ND ND --- ---ND ND ND ND12ND ND7-Nov-01 --- 10.0 ND ND --- ---ND ND ND ND ND ND ND
22-May-02 --- 10.0 12 ND --- --- ND ND ND ND 12 ND ND
14-Nov-02 --- 10.0 10 ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 10.0 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 10.0 ND ND --- --- ND ND 10 ND ND ND ND
6-May-04 --- 10.0 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 10.0 ND ND --- --- ND ND 10 ND ND ND ND
27-May-05 --- 10.0 ND ND --- --- ND ND 10.0 ND ND ND ND
3-Nov-05 --- 10.0 --- ND --- --- ND ND ND ND ND ND ND25-May-06 --- 10.0 --- ND --- --- ND ND ND ND ND ND ND2-Nov-06 --- 10.0 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 10.0 --- ND --- --- ND ND 9.8 J 8.9 J ND ND ND
NC 2L = 2,800 µg/L (10/23/07) 29-Nov-07 --- 10.0 --- 1.4 J --- --- ND ND 4.3 J 5.7 JD 4.3 J ND ND
29-May-08 0.5 10.0 --- 1.2 J --- --- 1.1 J ND 1.5 J 6.0 J 2.6 J ND ND
6-Nov-08 0.5 10.0 --- 2 J --- --- ND 0.9 J 3.5 J 5.6 J 4.3 J ND ND
3-Jun-09 0.5 10.0 --- 1.1 J --- --- ND ND ND 4.0 J 4.4 J ND ND
18-Nov-09 0.5 10.0 --- 3.1 J --- --- 0.8 J 0.6 J 5.5 J 5.1 J 3.5 J ND NDNC 2L = 3,000 µg/L (01/01/10) 16-Jun-10 0.5 10.0 --- 1.7 J --- --- 0.72 J 0.88 J 3.1 J 4.5 J 2.2 J ND ND1-Dec-10 0.5 10.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 0.5 10.0 --- 1.5 J ND --- 0.71 J ND 2.7 J 3.8 J ND ND ND
20-Dec-11 0.5 10.0 --- --- ND --- 0.64 J ND 2.1 J ND 2.9 J ND ND
30-May-12 0.5 10.0 --- --- ND --- ND ND 1.5 J 2.4 J ND ND ND
5-Dec-12 0.5 10.0 --- --- ND --- ND ND 1.8 J 2.7 J 1.9 J ND ND
12-Jun-13 0.5 10.0 --- --- ND --- ND ND 0.63 J 0.84 J 1.5 J ND ND
28-Oct-13 0.5 10.0 --- --- ND --- ND ND 1.9 J 2.3 J ND ND ND6-May-14 EPA 8260 0.5 10.0 --- --- ND --- ND ND 1.6 J 1.7 J 1.3 J ND ND22-Oct-14 EPA 8260 0.5 10.0 --- --- * ND 0.75 J ND ND 2.1 J 1.6 J ND ND
21-May-15 EPA 8260 0.5 10.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 EPA 8260 0.5 10.0 --- --- --- ND ND ND ND ND ND ND ND
Chloromethane 18-Nov-09 0.1 1.0 --- ND --- ---ND ND ND 0.45 J ND ND ND
NC 2L = 3 µg/L (01/01/10)16-Jun-10 0.1 1.0 ---ND --- --- 0.14 J ND ND 0.48 J ND ND ND
1-Dec-10 0.1 1.0 ---ND ND ---ND ND ND ND ND ND ND1-Jun-11 0.1 1.0 ---ND ND ---ND ND ND ND ND ND ND20-Dec-11 0.1 1.0 --- ---ND ---ND ND ND ND ND ND ND
30-May-12 0.1 1.0 --- ---ND ---ND ND ND ND ND ND ND
5-Dec-12 0.1 1.0 --- ---ND ---ND ND ND ND ND ND ND
12-Jun-13 0.1 1.0 --- ---ND ---ND ND ND ND ND ND ND
28-Oct-13 0.11 1.0 --- ---ND ---ND ND ND ND ND ND ND
6-May-14 EPA 8260 0.11 1.0 --- ---ND ---ND ND ND ND ND ND ND
22-Oct-14 EPA 8260 0.11 1.0 --- ---*NDND ND ND ND ND ND ND
21-May-15 EPA 8260 0.11 1.0 --- ------ ND ND ND ND ND ND ND ND8-Dec-15 EPA 8260 0.11 1.0 --- ------ ND ND ND ND ND ND ND ND
Chloroform 30-May-07 --- 5.0 ---ND --- ---0.92 B 1.2 B 0.99 B 1.4 B 1 B ND 0.98 J
NC 2L = 70 µg/L (10/23/07) 29-Nov-07 --- 5.0 ---ND --- ---ND ND ND ND ND ND ND
29-May-08 0.14 5.0 ---ND --- ---ND ND ND ND ND ND ND
6-Nov-08 0.14 5.0 ---ND --- ---ND ND ND ND ND ND ND
3-Jun-09 0.14 5.0 ---ND --- ---ND ND ND ND ND ND ND18-Nov-09 0.14 5.0 ---ND --- ---ND ND ND ND ND ND ND16-Jun-10 0.14 5.0 ---ND --- ---ND ND ND 0.2 B ND ND 0.29 J
1-Dec-10 0.1 5.0 ---ND ND ---ND ND ND ND ND ND ND
1-Jun-11 0.1 5.0 ---ND ND ---ND ND ND 0.36 B ND ND 0.63 J
20-Dec-11 0.1 5.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 0.1 5.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 0.1 5.0 --- --- ND --- ND ND ND 0.14 J ND ND ND
12-Jun-13 0.1 5.0 --- --- ND --- ND ND ND ND ND ND 46
28-Oct-13 0.1 5.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 EPA 8260 0.1 5.0 --- --- ND --- ND ND ND ND ND ND ND22-Oct-14 EPA 8260 0.1 5.0 --- --- * ND ND ND ND ND ND ND ND21-May-15 EPA 8260 0.1 5.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 EPA 8260 0.1 5.0 --- --- --- ND ND ND ND ND ND ND ND
Dibromochloromethane 30-May-07 --- 1.0 --- ND --- --- 1.7 ND ND ND 1.7 ND ND
GWPS = 0.41 µg/L (10/23/07) Nov-07 --- 3.0 --- ND --- --- ND ND ND ND ND ND ND
May-08 0.2 3.0 --- ND --- --- ND ND ND ND ND ND ND
Nov-08 0.2 3.0 --- ND --- --- ND ND ND ND ND ND NDJun-09 0.2 3.0 --- ND --- --- ND ND ND ND ND ND NDNov-09 0.2 3.0 --- ND --- --- ND ND ND ND ND ND ND
NC 2L = 0.4 µg/L (01/01/10) Jun-10 0.2 3.0 --- ND --- --- ND ND ND ND ND ND ND
Dec-10 0.2 3.0 --- ND ND --- ND ND ND ND ND ND ND
Jun-11 0.2 3.0 --- ND ND --- ND ND ND ND ND ND ND
Dec-11 0.2 3.0 --- --- ND --- ND ND ND ND ND ND ND
May-12 0.2 3.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 0.2 3.0 --- --- ND --- ND ND ND ND ND ND ND12-Jun-13 0.2 3.0 --- --- ND --- ND ND ND ND ND ND 9.228-Oct-13 0.2 3.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 EPA 8260 0.2 3.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 EPA 8260 0.2 3.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 EPA 8260 0.2 3.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 EPA 8260 0.2 3.0 --- --- --- ND ND ND ND ND ND ND ND
Burke County
John's River C and D over MSW Landfill
Permit 12-03 Page 3 of 14 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample EPA
Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Background Downgradient
1,2-Dichlorobenzene 3-Jun-09 0.3 5.0 --- ND --- --- ND ND ND 0.4 J ND ND ND
NC 2L = 24 µg/L (10/23/07) 18-Nov-09 0.3 5.0 --- ND --- --- ND ND ND 0.4 J ND ND NDNC 2L = 20 µg/L (01/01/10) 16-Jun-10 0.3 5.0 --- ND --- --- ND 0.39 J ND 0.4 J ND ND ND1-Dec-10 0.3 5.0 --- ND ND --- ND 0.49 J ND 0.5 J ND ND ND
1-Jun-11 0.3 5.0 --- ND ND --- ND 0.5 J ND 0.5 J ND ND ND
20-Dec-11 0.3 5.0 --- --- ND --- ND 0.4 J ND ND ND ND ND
30-May-12 0.3 5.0 --- ---ND ---ND 0.4 J ND 0.6 J ND ND ND
5-Dec-12 0.3 5.0 --- ---ND ---ND 0.4 J ND 0.6 J ND ND ND
12-Jun-13 0.3 5.0 --- ---ND ---ND 0.4 J ND 0.6 J ND ND ND28-Oct-13 0.3 5.0 --- --- ND --- ND 0.39 J ND 0.54 J ND ND ND6-May-14 EPA 8260 0.3 5.0 --- ---ND ---ND 0.46 J ND 0.55 J ND ND ND
22-Oct-14 EPA 8260 0.3 5.0 --- ---*NDND 0.45 J ND ND ND ND ND
21-May-15 EPA 8260 0.3 5.0 --- ------ ND ND 0.45 J ND 0.58 J ND ND ND
8-Dec-15 EPA 8260 0.3 5.0 --- ------ ND ND 0.39 J ND 0.45 J ND ND ND
1,4-Dichlorobenzene 1-Sep-94 ---5.0 ND NI NI NI ND 6.5 ND ND NI NI ---
1-Oct-94 --- 5.0 ---NI NI NI ---8 --- ---NI NI ---1-Jan-95 --- 5.0 ---NI NI NI ND ND ND ND NI NI ---1-Feb-95 --- 5.0 ---NI NI NI ND 9.8 ND ND NI NI ---
1-Mar-95 --- 5.0 ND NI NI NI ND 12.0 ND ND NI NI ---
1-Aug-95 --- 5.0 ND NI --- ---ND 14.0 ND ND NI NI ---
1-Jan-96 --- 5.0 ---NI --- ---ND 20 ND ND NI NI ---
1-Feb-96 --- 5.0 ---NI --- ---ND 19.0 ND ND NI NI ---
1-May-96 --- 5.0 ---NI --- ---ND 18 ND ND NI NI ---
1-Oct-96 --- 5.0 ---NI --- ---ND 16.0 ND ND NI NI ---
1-May-97 --- 5.0 ND NI --- ---ND 14.0 ND ND NI NI ---1-Nov-97 --- 1.0 ND NI --- ---ND ND ND ND NI NI ---1-May-98 --- 5.0 ND NI --- ---ND ND ND ND NI NI ---
24-Nov-98 --- 2.0 ND NI --- --- ND 4 ND ND NI NI ---
10-May-99 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
18-Oct-99 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
3-May-00 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-00 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND22-May-02 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND14-Nov-02 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 5.0 ND ND --- --- ND 7.2 ND ND 6.5 ND ND
20-Nov-03 --- 5.0 ND ND --- --- ND 12 ND ND 5.7 ND ND
6-May-04 --- 5.0 ND ND --- --- ND 14 ND ND 5.2 ND ND
10-Nov-04 --- 5.0 ND ND --- --- ND 17 ND ND 6.7 ND ND
27-May-05 --- 5.0 ND ND --- --- ND 20.0 ND ND 6.0 ND ND
3-Nov-05 --- 5.0 --- ND --- --- ND 21 ND ND 6.0 ND ND25-May-06 --- 5.0 --- ND --- --- ND 16.5 ND ND 5.4 ND ND2-Nov-06 --- 5.0 --- ND --- --- ND 16 ND ND 7.2 ND ND
30-May-07 --- 1.0 --- ND --- --- ND 23.0 5.2 4.4 7.2 ND ND
NC 2L = 1.4 µg/L (10/23/07) 29-Nov-07 --- 1.0 --- ND --- --- ND 11 2.3 4.5 5.2 ND ND
29-May-08 0.3 1.0 --- ND --- --- ND 13.5 3.1 5.2 6.0 ND ND
6-Nov-08 0.3 1.0 --- ND --- --- ND 9.7 Q 3.7 4.3 5.5 ND ND
3-Jun-09 0.3 1.0 --- ND --- --- ND 14.3 4.2 7.3 8.0 ND ND
18-Nov-09 0.3 1.0 --- ND --- --- ND 12.2 4.5 6.4 6.8 ND 0.55 J
NC 2L = 6 µg/L (01/01/10) 16-Jun-10 0.3 1.0 --- ND --- --- ND 19.8 4.7 6.8 5.7 ND ND1-Dec-10 0.3 1.0 --- ND ND --- 0.43 J 18.5 3.5 7.5 7.5 ND ND1-Jun-11 0.3 1.0 --- ND ND --- ND 19.2 4.5 8.4 3.4 ND ND
20-Dec-11 0.3 1.0 --- --- ND --- 0.37 J 13.9 4 7.8 D 6.5 ND ND
30-May-12 0.3 1.0 --- --- ND --- ND 16.4 4.2 9.9 7.0 ND ND
5-Dec-12 0.3 1.0 --- --- ND --- ND 15 4.4 9.7 6.0 ND ND
12-Jun-13 0.3 1.0 --- --- ND --- 0.48 J 12.4 4.9 9.7 7.5 ND ND
28-Oct-13 0.3 1.0 --- ---0.63 J ---0.45 J 16.7 5 10.1 8.3 ND ND6-May-14 EPA 8260 0.3 1.0 --- ---ND ---0.63 J 18 5.2 12.3 8.9 ND ND22-Oct-14 EPA 8260 0.3 1.0 --- ---*ND0.73 J 16.1 4.8 11.9 7.5 ND ND
21-May-15 EPA 8260 0.3 1.0 --- ------ ND 0.7 J 17.1 5.0 12.0 7.1 ND ND
8-Dec-15 EPA 8260 0.3 1.0 --- ------ ND 0.98 J 12.6 4.8 13.2 9.1 ND ND
Burke County
John's River C and D over MSW Landfill
Permit 12-03 Page 4 of 14 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample EPA
Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Background Downgradient
Dichlorodifluoromethane 1-Aug-95 --- 5.0 ND NI --- --- ND 26 ND 22 NI NI ---
# 1-Jan-96 ---5.0 ---NI --- ---ND ND ND ND NI NI ---1-Feb-96 ---10.0 ---NI --- ---ND ND ND ND NI NI ---
1-May-96 ---10.0 ---NI --- ---ND35 25ND NI NI ---
1-Oct-96 --- 5.0 ---NI --- ---ND ND ND ND NI NI ---
1-May-97 --- 5.0 6.4 NI --- ---ND 16 20.0 42.0 NI NI ---
1-Nov-97 --- 5.0 14 NI --- ---ND ND 31.0 90.0 NI NI ---
24-Nov-98 --- 2.0 ND NI --- ---ND ND ND ND NI NI ---
10-May-99 --- 10.0 ND ND --- ---ND ND 19.0 27.0 ND ND ND18-Oct-99 --- 5.0 ND ND --- ------ 14.0 50.0 130.0 25 ND ND3-May-00 --- 5.0 --- ------ ------ND 16.00 36.0 8.9 ---ND
7-Nov-00 --- 5.0 ND ------ ---ND ND 9.40 30.0 7.9 ---ND
31-May-01 --- 5.0 ND ------ ---ND ND 13 25 6.2 ---ND
7-Nov-01 --- 5.0 ND --- --- --- ND 5.5 ND 34 12 --- ND
22-May-02 --- 5.0 ND --- --- --- ND 5 15 24 11 --- ND
14-Nov-02 --- 5.0 ND --- --- --- ND ND ND 20 ND --- ND
14-May-03 --- 5.0 ND --- --- --- ND ND 8.7 12 ND --- ND
20-Nov-03 --- 5.0 ND ND --- --- ND ND 6.3 10 ND ND ND6-May-04 --- 5.0 ND --- --- --- ND ND ND 9.2 ND --- ND10-Nov-04 --- 5.0 ND --- --- --- ND ND 7.6 10 ND ND ND
27-May-05 --- 5.0 ND --- --- --- ND ND 14 22 ND --- ND
3-Nov-05 --- 5.0 --- ND --- --- ND ND 9 12 ND ND ND
25-May-06 --- 5.0 --- --- --- --- ND ND ND 5.4 ND --- ND
2-Nov-06 --- 5.0 --- ND --- --- ND ND 8.2 6.6 ND ND ND
30-May-07 --- 5.0 --- --- --- --- ND ND 7.1 7.6 ND --- ---
NC 2L = 1,400 µg/L (10/23/07) 29-Nov-07 --- 5.0 --- ND --- --- ND ND 1.1 J 1.8 JD ND ND ND
29-May-08 0.2 1.0 --- --- --- --- ND 0.35 J 2.9 3.6 ND --- ND6-Nov-08 0.2 5.0 --- 0.62 J --- ---ND 0.33 J 1.9 J 2.2 J 0.69 J ND ND
3-Jun-09 0.2 5.0 --- 0.45 J --- ---0.96 J ND 2.5 J 1.9 J 0.72 J ND ND
18-Nov-09 0.2 5.0 ---ND --- ---ND ND 1.2 J 1.9 J 0.47 J ND ND
NC 2L = 1,000 µg/L (01/01/10)16-Jun-10 0.2 5.0 ---ND --- ---ND ND 0.81 J 1.4 J ND ND ND
1-Dec-10 0.2 5.0 --- 0.26 J ND ---ND ND 0.69 J 1.1 J 0.55 J ND ND
1-Jun-11 0.2 5.0 --- 0.42 J ND ---ND ND ND 1.2 J ND ND ND
20-Dec-11 0.2 5.0 --- --- ND --- ND ND ND 0.76
JD ND ND ND
30-May-12 0.2 5.0 --- ---ND ---ND ND ND ND ND ND ND
5-Dec-12 0.2 5.0 --- --- ND --- ND ND ND ND ND --- ND
12-Jun-13 0.2 5.0 --- --- ND ---0.34 J ND ND ND ND ND ND
28-Oct-13 0.2 5.0 --- --- ND ---ND ND ND 1.1 J ND ND ND
6-May-14 EPA 8260 0.2 5.0 --- --- ND ---ND ND ND ND ND ---ND
22-Oct-14 EPA 8260 0.2 5.0 --- --- * ND ND ND ND ND ND ---ND21-May-15 EPA 8260 0.2 5.0 --- --- --- ND ND ND ND ND ND ---ND
8-Dec-15 EPA 8260 0.2 5.0 --- --- --- ND ND ND ND ND ND ---ND
1,1-Dichloroethane 1-Sep-94 --- 5.0 ND NI NI NI ND 50 7.5 ND NI NI ---
1-Jan-95 --- 5.0 ---NI NI NI ND35 33ND NI NI ---
1-Feb-95 --- 5.0 ---NI NI NI ND66 34ND NI NI ---
1-Mar-95 --- 5.0 ND NI NI NI ND 72 34 ND NI NI ---
1-Aug-95 --- 5.0 ND NI --- ---ND 96 ND ND NI NI ---1-Jan-96 --- 5.0 --- NI --- --- 13 120 54 ND NI NI ---1-Feb-96 --- 5.0 --- NI --- --- 11 ND ND ND NI NI ---
1-May-96 --- 5.0 --- NI --- --- 12 110 68 ND NI NI ---
1-Oct-96 --- 5.0 --- NI --- --- 17 140 86 ND NI NI ---
1-May-97 --- 5.0 ND NI --- --- 39 170 100 4 J NI NI ---
1-Nov-97 --- 1.0 2 NI --- ---22 200 69.0 8 NI NI ---
1-May-98 --- 5.0 5.5 NI --- --- 22.0 250.0 250.0 45.0 NI NI ---
24-Nov-98 --- 2.0 3.8 NI --- --- 14 150.0 57 19.9 NI NI ---
10-May-99 --- 5.0 7.7 ND --- --- 9.7 180.0 64.0 30.0 120 ND ND18-Oct-99 --- 5.0 11.0 J ND --- --- 9.3 J 200 59 30.0 120 ND ND3-May-00 --- 5.0 9.3 J ND --- --- 6.2 J 120.0 61.0 38.0 120 ND ND
7-Nov-00 --- 5.0 9.5 ND --- --- 5.0 110.0 60.0 44.0 92 ND ND
31-May-01 --- 5.0 7.9 6 --- --- ND 80.0 75.0 45.0 79 ND ND
7-Nov-01 --- 5.0 14.0 5.3 --- --- ND 84.0 100.0 42.0 95 ND ND
22-May-02 --- 5.0 19.0 ND --- --- ND 75.0 110.0 57 100 ND ND
14-Nov-02 --- 5.0 21.0 ND --- --- ND 41.0 90.0 50.0 82 ND ND
14-May-03 --- 5.0 27.0 ND --- --- ND 48.0 60.0 69.0 82 ND ND20-Nov-03 --- 5.0 25.0 ND --- --- ND 34.0 48.0 62.0 59 ND ND6-May-04 --- 5.0 33.0 ND --- --- ND 33 58.0 72.0 58 ND ND
10-Nov-04 --- 5.0 38.0 ND --- --- ND 22.0 37.0 50.0 42 ND ND
27-May-05 --- 5.0 68.0 ND --- --- ND 25 48 66 44.0 ND ND
3-Nov-05 --- 5.0 --- ND --- --- ND 18.0 34 54.0 38 ND ND
25-May-06 --- 5.0 --- ND --- --- ND 10.9 27 37.6 25.3 ND ND
2-Nov-06 --- 5.0 --- ND --- --- ND 12 34 47 33 ND ND
30-May-07 --- 5.0 --- 5.3 --- --- 3.3 J 16 48 59 41 ND ND
NC 2L = 70 µg/L (10/23/07) 29-Nov-07 --- 5.0 --- 6.1 --- --- 2.2 J 7.7 39 44 34 ND ND29-May-08 0.3 5.0 --- 1.7 J --- --- 1.7 J 8.7 38.8 ND 29.7 ND ND6-Nov-08 0.3 5.0 --- 5.7 --- --- 1.9 J 8.1 34.6 52.3 26.2 ND ND
3-Jun-09 0.3 5.0 --- 6.3 --- --- 1.3 J 8.2 47.8 53.1 32 ND ND
18-Nov-09 0.3 5.0 --- 10.8 --- --- 1.2 J 6.7 41.9 52.0 29.4 ND ND
NC 2L = 6 µg/L (01/01/10) 16-Jun-10 0.3 5.0 --- 3.9 J --- --- 1.2 J 5.7 35.7 43.1 32.1 ND ND
1-Dec-10 0.3 5.0 ---6.8 ND ---1.7 J 5.4 41.3 37.9 16.9 ND ND
1-Jun-11 0.3 5.0 ---9.3 ND ---2J6.8 45.5 53.3 19.1 ND ND20-Dec-11 0.3 5.0 --- ---ND ---1.9 J 5.1 39.7 39.7 D 26.2 ND ND30-May-12 0.3 5.0 --- --- ND --- 1.5 J 5.9 38.2 45.8 24.1 ND ND
5-Dec-12 0.3 5.0 --- ---ND ---1.7 J 4.6 J 39.3 39.3 26.5 ND ND
12-Jun-13 0.3 5.0 --- ---ND ---0.73 J 5.3 37.1 41.6 21.4 ND ND
28-Oct-13 0.3 5.0 --- ---ND ---1 J 4.9 J 43.2 41.8 26.2 ND ND
6-May-14 EPA 8260 0.3 5.0 --- ---ND ---1J4J43.4 39.5 21.5 ND ND
22-Oct-14 EPA 8260 0.3 5.0 --- ---*ND1.3 J 3.6 J 34.4 33.2 25.3 ND ND
21-May-15 EPA 8260 0.3 5.0 --- ------ ND 0.75 J 2.8 J 26.7 23.1 17.3 ND ND8-Dec-15 EPA 8260 0.3 5.0 --- ------ ND 0.95 J 3.2 J 31.7 33.7 10.3 ND ND
Burke County
John's River C and D over MSW Landfill
Permit 12-03 Page 5 of 14 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample EPA
Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Background Downgradient
1,2-Dichloroethane 3-Nov-05 --- 5.0 ---ND --- ---ND 13 ND ND ND ND ND25-May-06 --- 5.0 ---ND --- ---ND ND ND ND ND ND ND2-Nov-06 --- 5.0 ---ND --- ---ND ND ND ND ND ND ND
30-May-07 --- 1.0 ---ND --- ---ND 2.4 ND 1.6 ND ND ND
NC 2L = 0.38 µg/L (10/23/07) 29-Nov-07 --- 1.0 ---ND --- ---ND ND ND ND ND ND ND
29-May-08 0.1 1.0 ---ND --- ---ND 1.2 0.64 J 1.5 1.1 ND ND
6-Nov-08 0.1 1.0 ---ND --- ---ND 0.65 B 0.27 B 1.8 B 0.46 B ND1J
3-Jun-09 0.1 1.0 ---ND --- ---ND 0.78 J 0.8 J 1.9 0.98 J ND ND
18-Nov-09 0.1 1.0 --- ND --- --- ND 0.98 J 1.0 1.8 0.97 J ND ND
NC 2L = 0.4 µg/L (01/01/10)16-Jun-10 0.1 1.0 --- ND --- --- ND 1.2 1.1 1.8 1.0 ND ND1-Dec-10 0.1 1.0 --- ND ND --- ND 0.94 J 0.58 J 1.5 0.18 J ND ND
1-Jun-11 0.1 1.0 --- ND ND --- ND ND 1.1 2.1 1.0 ND ND
20-Dec-11 0.1 1.0 --- --- ND --- ND 0.8 J 0.92 J 1.8 J 1.0 ND ND
30-May-12 0.1 1.0 --- ---ND ---ND 0.75 J 0.97 J 2 1 ND ND
5-Dec-12 0.12 1.0 ------ND ---ND 0.7 J 0.8 J 1.7 1.3 ND ND
12-Jun-13 0.1 1.0 --- ---ND ---ND 0.6 J 1.3 1.7 1.0 ND ND
28-Oct-13 0.1 1.0 --- ---ND ---ND 0.9 J 1.4 1.7 1.4 ND ND6-May-14 EPA 8260 0.1 1.0 --- ---ND ---ND 0.8 J 1.2 1.6 1.2 ND ND22-Oct-14 EPA 8260 0.1 1.0 --- --- *ND ND 0.51 J 0.85 J 1.5 1.2 ND ND
21-May-15 EPA 8260 0.1 1.0 --- --- ---ND ND ND 0.71 J ND ND ND ND
8-Dec-15 EPA 8260 0.2 1.0 --- --- ---ND ND 0.65 J ND 1.3 1.3 ND ND
1,1-Dichloroethene 1-May-97 --- 5.0 ND NI --- ---ND 3 J ND 4 J NI NI ---
1-Nov-97 --- 1.0 ND NI --- --- ND ND ND ND NI NI ---
1-May-98 --- 5.0 ND NI --- --- ND ND ND ND NI NI ---
24-Nov-98 --- 2.0 ND NI --- --- ND ND ND ND NI NI ---
10-May-99 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND18-Oct-99 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND3-May-00 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-00 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND20-Nov-03 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND6-May-04 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
27-May-05 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 5.0 --- ND --- --- ND ND 0.93 J 1.8 J 0.42 J ND NDNC 2L = 7 µg/L (10/23/07) 29-Nov-07 --- 5.0 --- ND --- --- ND ND 0.8 J 1.2 JD 0.59 J ND ND29-May-08 0.6 1.0 --- ND --- --- ND ND 0.75 J 1.3 ND ND ND
6-Nov-08 0.6 5.0 --- ND --- --- ND ND 0.64 J 1.1 J ND ND ND
3-Jun-09 0.6 5.0 --- ND --- --- ND ND 0.95 J 1.1 J ND ND ND
18-Nov-09 0.6 5.0 ---ND --- ---ND ND 0.78 J 1.1 J ND ND ND
16-Jun-10 0.6 5.0 ---ND --- ---0.98 J ND 0.68 J 1.2 J ND ND ND
1-Dec-10 0.6 5.0 ---ND ND ---ND ND ND ND ND ND ND
1-Jun-11 0.6 5.0 --- ND ND --- ND ND 0.68 J 0.82 J ND ND ND
20-Dec-11 0.6 5.0 --- ---ND ---ND ND 0.59 J ND ND ND ND30-May-12 0.6 5.0 --- ---ND ---ND ND 0.62 J 0.58 J ND ND ND
5-Dec-12 0.6 5.0 --- ---ND ---ND ND 0.66 J 0.58 J ND ND ND
NC 2L = 350 µg/L (04/01/2013) 12-Jun-13 0.560 5.0 --- ---ND ---ND ND ND ND ND ND ND
28-Oct-13 0.560 5.0 --- ---ND ---ND ND 0.6 J ND ND ND ND
6-May-14 EPA 8260 0.560 5.0 --- ---ND ---ND ND 0.59 J ND ND ND ND
22-Oct-14 EPA 8260 0.560 5.0 --- ---*NDND ND ND ND ND ND ND
21-May-15 EPA 8260 0.560 5.0 --- ------ ND ND ND ND ND ND ND ND8-Dec-15 EPA 8260 0.560 5.0 --- ------ ND ND ND ND ND ND ND ND
Burke County
John's River C and D over MSW Landfill
Permit 12-03 Page 6 of 14 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample EPA
Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Background Downgradient
cis-1,2-Dichloroethene 1-Feb-96 --- 5.0 ---NI --- ---11 89 35 ND NI NI ---1-May-96 --- 5.0 ---NI --- ---ND ND ND ND NI NI ---1-Oct-96 --- 5.0 ---NI --- ---ND ND ND ND NI NI ---
1-May-97 --- 5.0 ND NI --- ---ND 2.1 J ND ND NI NI ---
1-Nov-97 --- 1.0 ND NI --- ---ND ND ND ND NI NI ---
1-May-98 --- 5.0 ND NI --- --- ND ND ND ND NI NI ---
24-Nov-98 --- 2.0 ND NI --- --- ND 2.8 ND ND NI NI ---
10-May-99 --- 5.0 ND ND --- --- ND ND ND ND 7 ND ND
18-Oct-99 --- 5.0 ND ND --- --- ND 6.3 ND ND 14 ND ND
3-May-00 --- 5.0 ND ND --- --- ND ND ND ND 13 ND ND7-Nov-00 --- 5.0 ND ND --- --- ND ND ND ND 13 ND ND31-May-01 --- 5.0 ND ND --- --- ND ND ND ND 14 ND ND
7-Nov-01 --- 5.0 ND ND --- --- ND 5.9 6.5 ND 18 ND ND
22-May-02 --- 5.0 ND ND --- --- ND 8 11 ND 24 ND ND
14-Nov-02 --- 5.0 ND ND --- --- 5 7 13.0 ND 28 ND ND
14-May-03 --- 5.0 ND ND --- --- 7 11 8 5 36 ND ND
20-Nov-03 --- 5.0 ND ND --- --- 5 14 13 6 27 ND ND
6-May-04 --- 5.0 ND ND --- --- ND 16 17 7.2 32 ND ND10-Nov-04 --- 5.0 ND ND --- --- ND 14 13 5.8 29 ND ND27-May-05 --- 5.0 ND ND --- --- ND 16 23 8 23 ND ND
3-Nov-05 --- 5.0 --- ND --- --- ND 5 6 ND 9 ND ND
25-May-06 --- 5.0 --- ND --- --- ND 8.2 9.3 5.2 7.7 ND ND
2-Nov-06 --- 5.0 --- ND --- --- ND 16 12.0 12 17 ND ND
30-May-07 --- 5.0 --- ND --- --- 4.9 J 20 21.0 17 15 ND ND
NC 2L = 70 µg/L (10/23/07) 29-Nov-07 --- 5.0 --- ND --- --- 2.9 J 8.6 7.2 13 9.1 ND ND
29-May-08 0.2 5.0 --- ND --- --- 2.8 J 13.4 10.9 18.4 10.4 ND ND
6-Nov-08 0.2 5.0 --- 0.5 J --- --- 2.8 J 12.7 10 20.4 7.6 ND ND3-Jun-09 0.2 5.0 --- 0.71 J --- --- 2.5 J 13.1 11.9 25.3 10.4 ND ND18-Nov-09 0.2 5.0 --- 2.8 B --- --- 2.5 B 12.2 B 20 25.9 10.8 B ND 2.6 J
16-Jun-10 0.2 5.0 --- 1.7 J --- --- 2.3 J 14.8 15.6 22.2 9.7 ND ND
1-Dec-10 0.2 5.0 --- 0.66 J ND --- 3.1 J 11.3 9.2 19.7 7.1 ND ND
1-Jun-11 0.2 5.0 --- 0.89 J ND --- 3.7 J 14.5 13.8 28.8 5.7 ND ND
20-Dec-11 0.2 5.0 --- --- ND --- 3.7 J 9.5 9.7 21.4 D 6.5 ND ND
30-May-12 0.2 5.0 --- --- ND --- 3.1 J 11.8 11.2 26.5 6.8 ND ND
5-Dec-12 0.2 5.0 --- --- ND --- 3.3 J 9.1 9.4 25.4 6.6 ND ND12-Jun-13 0.2 5.0 --- --- ND --- 2.5 J 9 12.8 26.2 6.2 ND ND
28-Oct-13 0.2 5.0 --- ---ND ---3 J 11.2 14 29.1 7.7 ND ND
6-May-14 EPA 8260 0.2 5.0 --- ---ND ---3.4 J 9.5 13 27.1 7.7 ND ND
22-Oct-14 EPA 8260 0.2 5.0 --- ---*ND4.3 J 8.0 10.1 25 7.1 ND ND
21-May-15 EPA 8260 0.2 5.0 --- ------ ND 2.8 J 6.7 7.6 17.0 4.2 J ND ND
8-Dec-15 EPA 8260 0.2 5.0 --- ------ ND 3.9 J 6.9 9.9 25.8 4.4 J ND ND
trans-1,2-Dichloroethene 5-Dec-13 0.5 5.0 --- --- ND --- ND ND 0.67 J 0.59 J ND ND NDNC 2L = 100 µg/L (10/23/07) 12-Jun-13 0.5 5.0 --- ---ND ---ND ND ND ND ND ND ND
28-Oct-13 0.5 5.0 --- ---ND ---ND ND ND ND ND ND ND
6-May-14 EPA 8260 0.5 5.0 --- ---ND ---ND ND ND ND ND ND ND
22-Oct-14 EPA 8260 0.5 5.0 --- ---*NDND ND ND ND ND ND ND
21-May-15 EPA 8260 0.5 5.0 --- ------ ND ND ND ND ND ND ND ND
8-Dec-15 EPA 8260 0.5 5.0 --- ------ ND ND ND ND ND ND ND ND
1,2-Dichloropropane 30-May-07 --- 1.0 ---ND --- ---ND ND ND 2.2 2.5 ND NDNC 2L = 0.51 µg/L (10/23/07) 29-Nov-07 --- 1.0 ---ND --- ---ND ND ND ND 0.7 J ND ND29-May-08 0.3 1.0 ---ND --- ---ND ND 0.4 J 0.72 J 0.85 J ND ND
6-Nov-08 0.3 1.0 ---ND --- ---ND 0.32 J 0.5 J 0.68 J 0.67 J ND ND
3-Jun-09 0.3 1.0 ---ND --- ---ND ND ND 0.88 J 0.9 J ND ND
18-Nov-09 0.3 1.0 ---ND --- ---ND ND 0.5 J 0.7 J 0.84 J ND ND
NC 2L = 0.6 µg/L (01/01/10)16-Jun-10 0.3 1.0 ---ND --- ---ND ND 0.5 J 0.7 J 0.67 J ND ND
1-Dec-10 0.3 1.0 ---ND ND ---ND 0.33 J 0.29 J 0.55 J 0.72 J ND ND
1-Jun-11 0.3 1.0 --- ND ND --- ND ND ND 0.88 J ND ND ND
20-Dec-11 0.3 1.0 --- --- ND --- ND ND 0.35 J 0.57 JD 0.48 J ND ND30-May-12 0.3 1.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 0.3 1.0 --- --- ND --- ND ND 0.37 J 0.65 J 0.59 J ND ND
12-Jun-13 0.3 1.0 --- --- ND --- ND ND 0.35 J 0.6 J 0.59 J ND ND
28-Oct-13 0.3 1.0 --- --- ND --- ND ND ND ND 0.47 J ND ND
6-May-14 EPA 8260 0.3 1.0 --- ---ND ---ND ND 0.33 J 0.54 J 0.58 J ND ND
22-Oct-14 EPA 8260 0.3 1.0 --- ---*NDND ND ND ND 0.49 J ND ND
21-May-15 EPA 8260 0.3 1.0 --- ------ ND ND ND ND ND ND ND ND8-Dec-15 EPA 8260 0.3 1.0 --- ------ ND ND ND ND ND ND ND ND
Burke County
John's River C and D over MSW Landfill
Permit 12-03 Page 7 of 14 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample EPA
Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Background Downgradient
Ethylbenzene 1-May-98 --- 5.0 ND NI --- ---ND ND 6.4 ND NI NI ---24-Nov-98 --- 2.0 ND NI --- ---ND ND ND ND NI NI ---10-May-99 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND
18-Oct-99 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND
3-May-00 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND
7-Nov-00 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND
31-May-01 --- 5.0 ND ND --- ---ND ND 6.4 ND ND ND ND
7-Nov-01 --- 5.0 ND ND --- --- ND ND 5 ND ND ND ND
22-May-02 --- 5.0 ND ND --- --- ND ND 14 ND ND ND ND
14-Nov-02 --- 5.0 ND ND --- --- ND ND 14 ND ND ND ND14-May-03 --- 5.0 ND ND --- --- ND ND 11 8.8 ND ND ND
20-Nov-03 --- 5.0 ND ND --- --- ND ND 15 8.3 ND ND ND
6-May-04 --- 5.0 ND ND --- --- ND ND 21 7.6 ND ND ND
10-Nov-04 --- 5.0 ND ND --- --- ND ND 11.0 ND ND ND ND
27-May-05 --- 5.0 ND ND --- --- ND ND 23 8 ND ND ND
3-Nov-05 --- 5.0 --- ND --- --- ND ND 14 9 ND ND ND
25-May-06 --- 5.0 --- ND --- --- ND ND 17 5.8 ND ND ND
2-Nov-06 --- 5.0 --- ND --- --- ND ND 8.4 ND ND ND ND30-May-07 --- 1.0 --- ND --- --- ND ND 18 4.1 ND ND NDNC 2L = 550 µg/L (10/23/07) 29-Nov-07 --- 1.0 --- ND --- --- ND ND 0.54 J 2 ND ND ND
29-May-08 0.3 1.0 --- ND --- --- ND ND 2.6 2.6 ND ND ND
6-Nov-08 0.3 1.0 --- ND --- --- ND ND 2 3.5 ND ND ND
3-Jun-09 0.3 1.0 --- ND --- --- ND ND 6 8 ND ND ND
18-Nov-09 0.3 1.0 --- ND --- --- ND ND 3.3 4.1 ND ND ND
NC 2L = 600 µg/L (01/01/10) 16-Jun-10 0.3 1.0 --- ND --- --- ND ND 6.5 5 ND ND ND
1-Dec-10 0.3 1.0 --- ND ND --- ND ND 2.9 3 ND ND ND
1-Jun-11 0.3 1.0 --- ND ND --- ND ND 1.3 3 ND ND ND20-Dec-11 0.3 1.0 --- --- ND --- ND ND 0.59 J 1.2 JD ND ND ND30-May-12 0.3 1.0 --- --- ND --- ND 0.38 J 0.77 J 7 ND ND ND
5-Dec-12 0.3 1.0 --- --- ND --- ND 0.32 J 1.1 2.1 ND ND ND
12-Jun-13 0.3 1.0 --- --- ND --- ND 0.4 J 2.3 5.1 ND ND ND
28-Oct-13 0.3 1.0 --- --- ND --- ND 0.35 J 1 5.9 ND ND ND
6-May-14 EPA 8260 0.3 1.0 --- --- ND --- ND ND ND 1.6 ND ND ND
22-Oct-14 EPA 8260 0.3 1.0 --- --- * ND ND ND 0.32 J 1.5 ND ND ND
21-May-15 EPA 8260 0.3 1.0 --- --- --- ND ND ND 0.86 J 1.3 ND ND ND8-Dec-15 EPA 8260 0.3 1.0 --- --- --- ND ND ND 1.2 2.7 ND ND ND
Methylene Chloride 1-Sep-94 --- 5.0 ND NI NI NI ND 360 ND ND NI NI ---
1-Oct-94 ---5.0 ---NI NI NI ---430 --- ---NI NI ---
1-Jan-95 ---5.0 ---NI NI NI ND 290 ND ND NI NI ---
1-Feb-95 ---5.0 ---NI NI NI ND 560 ND ND NI NI ---
1-Mar-95 ---5.0 ND NI NI NI ND 610 ND ND NI NI ---1-Aug-95 ---5.0 ND NI --- ---ND 810 ND ND NI NI ---1-Jan-96 ---5.0 ---NI --- ---ND 380 ND ND NI NI ---
1-Feb-96 ---5.0 ---NI --- ---ND ND ND ND NI NI ---
1-May-96 --- 5.0 ---NI --- ---ND 330 5.3 ND NI NI ---
1-Oct-96 --- 5.0 ---NI --- ------68 19 ND NI NI ---
1-May-97 --- 5.0 ND NI --- ---2.4 J 280 11 ND NI NI ---
1-Nov-97 --- 5.0 ND NI --- ---ND ND ND ND NI NI ---
1-May-98 --- 5.0 ND NI --- ---ND 420 450 61 NI NI ---
24-Nov-98 --- 10.0 ND NI --- ---ND 92.5 B ND ND NI NI ---10-May-99 --- 5.0 ND ND --- ---ND 120.00 ND 37 ND ND ND18-Oct-99 --- 10.0 ND ND --- ---ND 78.00 B ND34BND ND21
3-May-00 --- 10.0 ND ND --- ---ND 98 ND 68 ND ND ND
7-Nov-00 --- 10.0 ND ND --- --- ND ND ND 56 ND ND ND
31-May-01 --- 10.0 ND ND --- --- ND 18 ND 96 ND ND ND
7-Nov-01 --- 10.0 ND ND --- --- ND ND ND 88 ND ND ND
22-May-02 --- 10.0 ND ND --- --- ND ND 11 130 ND ND ND
14-Nov-02 --- 10.0 ND ND --- --- ND ND 20 130 ND ND ND
14-May-03 --- 10.0 ND ND --- ---ND 18 ND 320 ND ND ND20-Nov-03 --- 10.0 ND ND --- --- ND ND ND 570 ND ND ND6-May-04 --- 10.0 12 ND --- --- ND ND 10 420 ND ND ND
10-Nov-04 --- 10.0 12 ND --- --- ND ND ND 360 ND ND ND
27-May-05 --- 10.0 40 ND --- --- ND ND ND 480 ND ND ND
3-Nov-05 --- 10.0 --- ND --- --- ND ND ND 510 ND ND ND
25-May-06 --- 10.0 --- ND --- --- ND ND ND 375 ND ND ND
2-Nov-06 --- 10.0 --- ND --- --- ND ND ND 210 ND ND ND
30-May-07 --- 1.0 --- 2.3 B --- --- ND ND ND 310 ND ND 3.2NC 2L = 4.6 µg/L (10/23/07) 29-Nov-07 --- 1.0 ---4.8 --- --- 0.89 J ND ND 220 ND ND ND29-May-08 1.0 2.0 --- 2.2 B --- --- ND ND ND 285 ND ND 1.5 J
6-Nov-08 1.0 2.0 --- 2.6 B --- --- 1.1 B ND ND 831 ND ND 3.2 J
3-Jun-09 1.0 2.0 --- ND --- --- ND ND ND 278 ND ND 19.1
18-Nov-09 1.0 2.0 ---11.1 --- --- ND ND ND 241 ND ND ND
NC 2L = 5 µg/L (01/01/10) 16-Jun-10 1.0 2.0 --- ND --- --- ND ND ND 234 ND ND ND
1-Dec-10 1.0 1.0 --- 2.2 ND --- ND ND ND 174 ND ND ND
1-Jun-11 1.0 1.0 --- 2.3 ND --- ND ND ND 232 ND ND ND
20-Dec-11 1.0 1.0 --- ---ND ---ND ND ND 196 D ND ND 1.930-May-12 1.0 1.0 --- ---ND ---ND ND ND 185 ND ND ND
5-Dec-12 1.0 1.0 --- ---ND ---ND ND ND 174 ND ND ND
12-Jun-13 1.0 1.0 --- ---ND ---ND ND ND 77.9 ND ND ND
28-Oct-13 1 1.0 --- ---ND ---ND ND ND 128 ND ND ND
6-May-14 EPA 8260 1 1.0 --- ---ND ---ND ND ND 154 ND ND 2.2
22-Oct-14 EPA 8260 1 1.0 --- ---*NDND ND ND 130 ND ND ND
21-May-15 EPA 8260 1 1.0 --- ------ ND ND ND ND 82.8 ND ND 1.78-Dec-15 EPA 8260 1 1.0 --- ------ ND ND ND ND 113 ND ND 2.0
Burke County
John's River C and D over MSW Landfill
Permit 12-03 Page 8 of 14 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample EPA
Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Background Downgradient
Iodomethane 29-May-08 0 10.0 --- 0.35 J --- ---ND ND ND ND ND ND NDNC 2L = NE (10/23/07) 6-Nov-08 0 10.0 ---ND --- ---ND ND ND ND ND ND ND3-Jun-09 0 10.0 --- ND --- --- ND ND ND ND ND ND ND
18-Nov-09 0 10.0 --- ND --- --- ND ND ND ND ND ND ND
16-Jun-10 0 10.0 --- ND --- --- ND ND ND ND ND ND ND
1-Dec-10 0 10.0 --- ND ND --- 5 J ND ND ND ND ND ND
1-Jun-11 0.3 10.0 ---ND ND ---ND ND ND ND ND ND ND
20-Dec-11 0.3 10.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 0.3 10.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 0.3 10.0 --- --- ND --- ND ND ND ND ND ND ND12-Jun-13 0.3 10.0 --- --- ND --- 8.6 J ND ND ND ND ND ND28-Oct-13 0.3 10.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 EPA 8260 0.3 10.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 EPA 8260 0.3 10.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 EPA 8260 0.3 10.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 EPA 8260 0.3 10.0 --- --- --- ND ND ND ND ND ND ND ND
Styrene 3-Jun-09 0.3 1.0 --- ND --- --- ND 2 ND ND ND ND NDNC 2L = 100 µg/L (10/23/07) 18-Nov-09 0.3 1.0 --- ND --- --- ND ND ND ND ND ND NDNC 2L = 70 µg/L (01/01/10) 16-Jun-10 0.3 1.0 --- ND --- --- ND ND ND ND ND ND ND
1-Dec-10 0.3 1.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 0.3 1.0 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 0.3 1.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 0.3 1.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 0.3 1.0 --- ---ND ---ND ND ND ND ND ND ND
12-Jun-13 0.3 1.0 --- ---ND ---ND ND ND ND ND ND ND28-Oct-13 0.3 1.0 --- ---ND ---ND ND ND ND ND ND ND6-May-14 EPA 8260 0.3 1.0 --- ---ND ---ND ND ND ND ND ND ND
22-Oct-14 EPA 8260 0.3 1.0 --- ---*NDND ND ND ND ND ND ND
21-May-15 EPA 8260 0.3 1.0 --- ------ ND ND ND ND ND ND ND ND
8-Dec-15 EPA 8260 0.3 1.0 --- ------ ND ND ND ND ND ND ND ND
Tetrachloroethene 1-May-97 --- 5.0 5.6 NI --- ---ND 6.3 3.6 J ND NI NI ---
1-Nov-97 --- 1.0 2 NI --- ---ND ND ND ND NI NI ---1-May-98 --- 5.0 ND NI --- ---ND ND ND ND NI NI ---24-Nov-98 --- 2.0 6.7 NI --- ---ND 7.8 3.2 ND NI NI ---
10-May-99 --- 5.0 8.5 ND --- ---ND 9.3 ND ND ND ND ND
18-Oct-99 --- 5.0 5.3 ND --- ---ND 7.3 ND ND ND ND ND
3-May-00 --- 5.0 7 ND --- ---ND 6.4 ND ND ND ND ND
7-Nov-00 --- 5.0 6.6 ND --- ---ND 5.3 ND ND ND ND ND
31-May-01 --- 5.0 9.6 ND --- ---ND 7.1 ND ND ND ND ND
7-Nov-01 --- 5.0 9.5 ND --- ---ND 5.6 5 ND ND ND ND22-May-02 --- 5.0 10 ND --- ---ND 5.7 5.5 ND ND ND ND14-Nov-02 --- 5.0 8 ND --- ---ND ND ND ND ND ND ND
14-May-03 --- 5.0 10 ND --- --- ND 5.5 ND ND ND ND ND
20-Nov-03 --- 5.0 8.8 ND --- --- ND 6.6 ND ND ND ND ND
6-May-04 --- 5.0 8.9 ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 5.0 12 ND --- --- ND ND ND 5.1 ND ND ND
27-May-05 --- 5.0 10 ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 5.0 ---ND --- ---ND ND ND 12 ND ND ND
25-May-06 --- 5.0 ---ND --- ---ND ND ND ND ND ND ND2-Nov-06 --- 5.0 ---ND --- ---ND ND ND 5.8 ND ND ND30-May-07 --- 1.0 ---1.6 --- ---ND 0.44 J 1.6 5.9 ND ND NDNC 2L = 0.7 µg/L (10/23/07)29-Nov-07 --- 1.0 ---1.7 --- ---ND ND 1.1 4.9 ND ND ND
29-May-08 0.5 1.0 ---2.2 --- ---ND ND 1.1 6.6 ND ND ND
6-Nov-08 0.5 1.0 ---2.7 --- ---ND ND 1.3 6.2 ND ND ND
3-Jun-09 0.5 1.0 ---2.1 --- ---ND ND 0.7 J 7.5 ND ND ND
18-Nov-09 0.5 1.0 ---2.6 --- ---ND ND 0.49 J 6.3 ND ND ND
16-Jun-10 0.5 1.0 ---1.2 --- --- ND ND 0.46 J 6.7 ND ND ND
1-Dec-10 0.5 1.0 ---3 ND --- ND ND ND 5.8 ND ND ND1-Jun-11 0.5 1.0 ---3.6 ND --- ND ND ND 7.7 ND ND ND
20-Dec-11 0.5 1.0 --- --- ND --- ND 0.59 B 0.7 B 5.7 D ND ND 1 J
30-May-12 0.5 1.0 --- --- ND --- ND ND ND 7.7 ND ND ND
5-Dec-12 0.5 1.0 --- ---ND ---ND ND ND 7.3 ND ND ND
12-Jun-13 0.5 1.0 --- --- ND --- ND ND ND 6.4 ND ND ND
28-Oct-13 0.5 1.0 --- --- ND --- ND ND ND 5.7 ND ND ND
6-May-14 EPA 8260 0.5 1.0 --- --- ND --- ND ND ND 7.3 ND ND ND
22-Oct-14 EPA 8260 0.5 1.0 --- --- * ND ND ND ND 7.0 ND ND ND21-May-15 EPA 8260 0.5 1.0 --- --- --- ND ND ND ND 6.4 ND ND ND8-Dec-15 EPA 8260 0.5 1.0 --- --- --- ND ND ND ND 5.6 ND ND ND
Tetrahydrofuran 1-Dec-10 3.1 10.0 --- ND ND --- ND ND ND 10.1 ND ND ND
NC 2L = NE (01/01/10) 1-Jun-11 3.1 10.0 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 3.1 10.0 --- --- ND --- ND ND ND 9.3 JD ND ND ND
30-May-12 3.1 10.0 --- --- ND --- ND ND ND 8.9 J ND ND ND
5-Dec-12 3.1 10.0 --- --- ND --- ND ND ND 6.9 J ND ND ND
12-Jun-13 3.1 10.0 --- --- ND --- ND ND ND 6.3 J ND ND ND28-Oct-13 3.1 10.0 --- --- ND --- ND ND ND 8.6 J ND ND ND6-May-14 EPA 8260 3.1 10.0 --- --- ND --- ND ND ND 10.2 ND ND ND
22-Oct-14 EPA 8260 3.1 10.0 --- --- * ND ND ND ND 7.4 J ND ND ND
21-May-15 EPA 8260 3.1 NE --- --- --- ND ND ND ND 6.3 J ND ND ND
8-Dec-15 EPA 8260 3.1 NE --- --- --- ND ND ND ND 9.7 J ND ND ND
Burke County
John's River C and D over MSW Landfill
Permit 12-03 Page 9 of 14 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample EPA
Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Background Downgradient
Toluene 1-Jan-95 --- 5.0 --- NI NI NI ND ND 19 ND NI NI ---
1-Feb-95 --- 5.0 --- NI NI NI ND ND ND ND NI NI ---1-Mar-95 ---5.0 ND NI NI NI ND ND ND ND NI NI ---
1-Aug-95 ---5.0 ND NI --- ---ND ND ND ND NI NI ---
1-Jan-96 ---5.0 ---NI --- ---ND ND ND ND NI NI ---
1-Feb-96 ---5.0 ---NI --- ---ND ND ND ND NI NI ---
1-May-96 ---5.0 ---NI --- ---ND ND ND ND NI NI ---
1-Oct-96 ---5.0 ---NI --- ---ND ND5ND NI NI ---
1-May-97 ---5.0 ND NI --- ---ND ND 2 J 3.4 J NI NI ---1-Nov-97 --- 1.0 ND NI --- ---ND ND ND ND NI NI ---1-May-98 --- 5.0 ND NI --- ---ND ND ND ND NI NI ---
24-Nov-98 --- 2.0 ND NI --- ---ND ND ND ND NI NI ---
10-May-99 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND
18-Oct-99 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND
3-May-00 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND
7-Nov-00 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND
31-May-01 --- 5.0 ND ND --- ---ND ND 22 15.00 ND ND ND7-Nov-01 --- 5.0 ND ND --- ---ND ND 11 7.20 ND ND ND22-May-02 --- 5.0 ND ND --- ---ND ND 11 17.00 ND ND ND
14-Nov-02 --- 5.0 ND ND --- ---ND ND21ND ND ND ND
14-May-03 --- 5.0 ND ND --- --- ND ND 8.4 86 ND ND ND
20-Nov-03 --- 5.0 ND ND --- --- ND ND 14 77 ND ND ND
6-May-04 --- 5.0 ND ND --- --- ND ND 22 54 ND ND ND
10-Nov-04 --- 5.0 ND ND --- --- ND ND ND 35 ND ND ND
27-May-05 --- 5.0 ND ND --- --- ND ND ND 100 ND ND ND
3-Nov-05 --- 5.0 ---ND --- ---ND ND20 80ND ND ND25-May-06 --- 5.0 --- ND --- --- ND ND 30.4 35.6 ND ND ND2-Nov-06 --- 5.0 --- ND --- --- ND ND ND 22 ND ND ND30-May-07 --- 1.0 --- ND --- --- 0.22 B 0.3 B 27.0 30 0.58 B ND 0.44 J
NC 2L = 1,000 µg/L (10/23/07) 29-Nov-07 --- 1.0 --- ND --- --- ND ND 1.5 12.0 ND ND ND
29-May-08 0.3 1.0 --- ND --- --- ND ND 3.1 12.8 5.9 ND ND
6-Nov-08 0.3 1.0 --- ND --- --- ND ND 0.7 J 23.5 0.76 J ND ND
3-Jun-09 0.3 1.0 --- ND --- --- ND ND 0.4 J 52.6 0.85 J ND ND
18-Nov-09 0.3 1.0 --- ND --- --- ND ND ND 27.2 0.55 J ND ND
NC 2L = 600 µg/L (01/01/10) 16-Jun-10 0.3 1.0 --- ND --- --- ND ND 2.5 34.8 0.38 J ND ND1-Dec-10 0.3 1.0 --- ND ND --- ND ND 4.1 17.5 ND ND ND1-Jun-11 0.3 1.0 --- ND ND --- ND ND ND 24.7 1.1 ND ND
20-Dec-11 0.3 1.0 --- --- ND --- ND ND ND 4.9 D 0.53 J ND ND
30-May-12 0.3 1.0 --- --- ND --- ND ND ND 46.8 0.67 J ND ND
5-Dec-12 0.3 1.0 --- --- ND --- ND ND 0.33 J 10.7 0.45 J ND ND
12-Jun-13 0.3 1.0 --- --- ND --- ND ND ND 27.6 0.7 J ND ND
28-Oct-13 0.3 1.0 --- --- ND --- ND ND ND 14.6 0.5 J ND ND
6-May-14 EPA 8260 0.3 1.0 --- --- ND --- ND ND ND 3.9 0.48 J ND ND22-Oct-14 EPA 8260 0.3 1.0 --- --- * ND ND ND ND 4.3 0.28 J ND ND21-May-15 EPA 8260 0.3 1.0 --- --- --- ND ND ND ND 4.1 ND ND ND
8-Dec-15 EPA 8260 0.3 1.0 --- --- --- ND ND ND ND 6.0 0.31 J ND ND
1,1,1-Trichloroethane 1-Sep-94 --- 5.0 ND NI NI NI ND 26 ND ND NI NI ---
1-Oct-94 --- 5.0 --- NI NI NI --- ND --- --- NI NI ---
1-Jan-95 --- 5.0 --- NI NI NI ND 23 ND ND NI NI ---
1-Feb-95 --- 5.0 --- NI NI NI ND 27 ND ND NI NI ---
1-Mar-95 --- 5.0 ND NI NI NI ND 28 6.5 ND NI NI ---1-Aug-95 --- 5.0 ND NI --- --- ND 42 ND 5 NI NI ---1-Jan-96 --- 5.0 --- NI --- --- ND 44 6 9 NI NI ---
1-Feb-96 ---5.0 ---NI --- ---ND 31 6.7 ND NI NI ---
1-May-96 ---5.0 ---NI --- ---ND 30 6.7 9.2 NI NI ---
1-Oct-96 ---5.0 ---NI --- ---ND22 5 9 NI NI ---
1-May-97 --- 5.0 16 NI --- --- 2.4 J 19 5.3 17 NI NI ---
1-Nov-97 ---1.0 14 NI --- ---ND ND ND14 NI NI ---1-May-98 ---5.0 15 NI --- ---ND 9.3 9.3 22.0 NI NI ---24-Nov-98 ---2.0 10.1 NI --- ---ND 4.9 3 9.3 NI NI ---
10-May-99 --- 5.0 15 ND --- ---ND ND ND 8.7 ND ND ND
18-Oct-99 --- 5.0 11 ND --- ---ND ND ND 9.2 ND ND ND
3-May-00 --- 5.0 12 ND --- ---ND ND ND 8.5 ND ND ND
7-Nov-00 --- 5.0 10 ND --- ---ND ND ND 7.3 ND ND ND
31-May-01 --- 5.0 9.8 ND --- ---ND ND ND 6.0 ND ND ND
7-Nov-01 --- 5.0 14 ND --- ---ND ND ND 7.9 ND ND ND22-May-02 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND14-Nov-02 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND
14-May-03 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND
20-Nov-03 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
27-May-05 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 5.0 --- ND --- --- ND ND ND 5.0 ND ND ND
25-May-06 --- 5.0 ---ND --- ---ND ND ND ND ND ND ND2-Nov-06 --- 5.0 ---ND --- ---ND ND ND ND ND ND ND30-May-07 --- 1.0 ---ND --- ---ND ND ND3ND ND ND
NC 2L = 200 µg/L (10/23/07) 29-Nov-07 --- 1.0 ---ND --- ---ND ND ND ND ND ND ND
29-May-08 0 1.0 --- ND --- --- ND ND ND 1 J ND ND ND
6-Nov-08 0 1.0 --- ND --- --- ND ND ND 1 J ND ND ND
3-Jun-09 0 1.0 --- ND --- --- ND ND ND 1 J ND ND ND
18-Nov-09 0 1.0 --- ND --- --- ND ND ND ND ND ND ND
16-Jun-10 0 1.0 --- ND --- --- ND ND ND ND ND ND ND
1-Dec-10 0 1.0 ---ND ND ---ND ND ND ND ND ND ND1-Jun-11 0 1.0 ---ND ND ---ND ND ND ND ND ND ND
20-Dec-11 0 1.0 --- ---ND ---ND ND ND ND ND ND ND
30-May-12 0 1.0 --- ---ND ---ND ND ND ND ND ND ND
5-Dec-12 0 1.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 0 1.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 0 1.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 EPA 8260 0 1.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 EPA 8260 0 1.0 --- --- * NDNDNDNDND ND ND ND21-May-15 EPA 8260 0 1.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 EPA 8260 0 1.0 --- --- --- ND ND ND ND ND ND ND ND
Burke County
John's River C and D over MSW Landfill
Permit 12-03 Page 10 of 14 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample EPA
Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Background Downgradient
Trichloroethene 1-Sep-94 --- 5.0 ND NI NI NI ND 9 ND ND NI NI ---1-Oct-94 --- 5.0 ---NI NI NI ---11 --- ---NI NI ---1-Jan-95 --- 5.0 ---NI NI NI ND 6 ND ND NI NI ---
1-Feb-95 --- 5.0 ---NI NI NI ND 10 ND ND NI NI ---
1-Mar-95 --- 5.0 ND NI NI NI ND 12 ND ND NI NI ---
1-Aug-95 --- 5.0 ND NI --- --- ND 13 ND ND NI NI ---
1-Jan-96 --- 5.0 --- NI --- --- ND 13 ND ND NI NI ---
1-Feb-96 --- 5.0 --- NI --- --- ND 14 ND ND NI NI ---
1-May-96 --- 5.0 --- NI --- --- ND 14 ND ND NI NI ---
1-Oct-96 --- 5.0 --- NI --- --- ND 14 ND ND NI NI ---1-May-97 --- 5.0 2 J NI --- ---ND 13 5JND NI NI ---
1-Nov-97 --- 1.0 2 NI --- ---ND16JND ND NI NI ---
1-May-98 --- 5.0 ND NI --- ---ND 14 13 ND NI NI ---
24-Nov-98 --- 2.0 4 NI --- ---ND 16 4 ND NI NI ---
10-May-99 --- 5.0 6 ND --- --- ND 19 5 ND ND ND ND
18-Oct-99 --- 5.0 ND ND --- --- ND 15 ND ND 5 ND ND
3-May-00 --- 5.0 5.4 ND --- --- ND 14 6 ND 6 ND ND
7-Nov-00 --- 5.0 ND ND --- --- ND 12 ND ND ND ND ND31-May-01 --- 5.0 ND ND --- --- ND 12 7 6 5 ND ND7-Nov-01 --- 5.0 ND ND --- --- ND 12 8 7 5 ND ND
22-May-02 --- 5.0 ND ND --- --- ND 10 9 8 ND ND ND
14-Nov-02 --- 5.0 ND ND --- --- ND 5.5 7.6 6.5 ND ND ND
14-May-03 --- 5.0 ND ND --- --- ND 11 7 12 6.8 ND ND
20-Nov-03 --- 5.0 ND ND --- --- ND 9.5 6.6 12 ND ND ND
6-May-04 --- 5.0 ND ND --- --- ND 9.1 5.8 12 ND ND ND
10-Nov-04 --- 5.0 ND ND --- --- ND 8.6 ND 11 ND ND ND
27-May-05 --- 5.0 5 ND --- --- ND 11 ND 12 ND ND ND3-Nov-05 --- 5.0 --- ND --- --- ND 9 ND 14 ND ND ND25-May-06 --- 5.0 --- ND --- --- ND 8.6 ND 10 ND ND ND
2-Nov-06 --- 5.0 --- ND --- --- ND 7 ND 12 ND ND ND
30-May-07 --- 1.0 --- 2 --- --- 1.9 8.5 4.6 12 2.8 ND ND
NC 2L = 2.8 µg/L (10/23/07) 29-Nov-07 --- 1.0 --- 1 --- --- 0.45 J 3.5 2.5 9.7 1.6 ND ND
29-May-08 0.47 1.0 --- ND --- --- ND 3.5 2.9 11.9 1.4 ND ND
6-Nov-08 0.47 1.0 --- 1.3 --- --- 0.53 J 3.7 3.3 11.6 1.3 ND ND
3-Jun-09 0.47 1.0 --- 1.8 --- --- ND 3.6 4.3 12.1 1.4 ND ND18-Nov-09 0.47 1.0 --- 1.9 --- --- 0.58 J 3.3 3.3 11.2 1.2 ND NDNC 2L = 3 µg/L (01/01/10) 16-Jun-10 0.47 1.0 --- 0.6 J --- --- ND 5.1 3.3 11.2 1.4 ND ND
1-Dec-10 0.47 1.0 --- 1.9 ND --- 0.76 J 3.7 3.3 9.3 ND ND ND
1-Jun-11 0.47 1.0 --- 2 ND --- 0.51 J 2.8 3.2 11.4 ND ND ND
20-Dec-11 0.47 1.0 --- --- ND --- 0.6 J 2.5 3.5 10 D 1.1 ND ND
30-May-12 0.47 1.0 --- --- ND --- ND 2.5 2.6 11.1 0.55 J ND ND
5-Dec-12 0.47 1.0 --- --- ND --- 0.53 J 2.3 3.3 11.2 0.67 J ND ND
12-Jun-13 0.47 1.0 --- --- ND --- 0.66 J 2.1 1.8 11.5 0.76 J ND ND28-Oct-13 0.47 1.0 --- --- ND --- ND 3.1 2.5 10.7 0.76 J ND ND6-May-14 EPA 8260 0.47 1.0 --- --- ND --- ND 2 2.6 11.9 0.6 J ND ND
22-Oct-14 EPA 8260 0.47 1.0 --- --- * ND 0.61 J 1.3 2.2 11.4 0.86 J ND ND
21-May-15 EPA 8260 0.47 1.0 --- --- --- ND ND 0.9 J 2.3 10.1 ND ND ND
8-Dec-15 EPA 8260 0.47 1.0 --- --- --- ND ND 0.71 J 1.4 9.7 ND ND ND
Trichlorofluoromethane 1-Oct-94 --- 5.0 --- NI NI NI --- 60 --- --- NI NI ---
1-Jan-95 --- 5.0 --- NI NI NI ND 37 ND ND NI NI ---
1-Feb-95 --- 5.0 --- NI NI NI ND 40 ND ND NI NI ---1-Mar-95 --- 5.0 ND NI NI NI ND 48 ND ND NI NI ---1-Aug-95 --- 5.0 ND NI --- --- ND 51 ND 9 NI NI ---
1-Jan-96 --- 5.0 --- NI --- --- ND 20 5 11 NI NI ---
1-Feb-96 --- 5.0 --- NI --- --- ND 11 6.2 7.9 NI NI ---
1-May-96 --- 5.0 --- NI --- --- ND 8.8 ND 9.1 NI NI ---
1-Oct-96 --- 5.0 --- NI --- --- ND ND ND 9 NI NI ---
1-May-97 --- 5.0 4.2 J NI --- --- ND 2.1 J 3.4 J 11 NI NI ---
1-Nov-97 --- 1.0 4 NI --- --- ND ND ND 11 NI NI ---1-May-98 --- 5.0 ND NI --- --- ND ND ND 5 NI NI ---24-Nov-98 --- 2.0 ND NI --- --- ND ND ND 7.6 NI NI ---
10-May-99 --- 10.0 ND ND --- --- ND ND ND ND ND ND ND
18-Oct-99 --- 5.0 ND ND --- --- ND ND ND 12 ND ND ND
3-May-00 --- 5.0 ND ND --- --- ND ND ND 9.4 ND ND ND
7-Nov-00 --- 5.0 ND ND --- --- ND ND ND 10 ND ND ND
31-May-01 --- 5.0 ND ND --- --- ND ND ND 6.5 ND ND ND
7-Nov-01 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND22-May-02 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND14-Nov-02 --- 5.0 ND ND --- --- ND ND ND 6.5 ND ND ND
14-May-03 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
27-May-05 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND2-Nov-06 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND30-May-07 --- 1.0 --- ND --- --- ND ND ND 4.2 ND ND ND
NC 2L = 2,100 µg/L (10/23/07) 29-Nov-07 --- 1.0 --- 0.74 J --- --- ND ND ND ND ND ND ND
29-May-08 0.2 1.0 --- 0.42 J --- --- ND ND ND ND ND ND ND
6-Nov-08 0.2 1.0 --- 0.71 J --- --- ND ND 0.24 J 1.1 ND ND ND
3-Jun-09 0.2 1.0 --- 0.38 J --- --- ND ND ND ND ND ND ND
18-Nov-09 0.2 1.0 --- 1.9 --- --- ND ND 1.6 2.1 ND ND ND
NC 2L = 2,000 µg/L (01/01/10) 16-Jun-10 0.2 1.0 --- ND --- --- ND ND ND ND ND ND ND1-Dec-10 0.2 1.0 --- 0.34 J ND --- ND ND ND 0.58 J ND ND ND1-Jun-11 0.2 1.0 --- 0.5 J ND --- ND ND ND 0.79 J ND ND ND
20-Dec-11 0.2 1.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 0.2 1.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 0.2 1.0 --- --- ND --- ND ND ND 0.65 J ND ND ND
12-Jun-13 0.2 1.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 0.2 1.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 EPA 8260 0.2 1.0 --- --- ND --- ND ND ND 0.3 J ND ND ND22-Oct-14 EPA 8260 0.2 1.0 --- --- * ND ND ND ND ND ND ND ND21-May-15 EPA 8260 0.2 1.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 EPA 8260 0.2 1.0 --- --- --- ND ND ND ND ND ND ND ND
Burke County
John's River C and D over MSW Landfill
Permit 12-03 Page 11 of 14 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample EPA
Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Background Downgradient
Vinyl Chloride 30-May-07 0.62 1.0 --- ND --- --- ND 0.46 J 1.6 ND 3.1 ND ND
NC 2L = 0.015 µg/L (10/23/07) 29-Nov-07 0.62 1.0 --- 0.42 J --- --- ND ND 1.4 ND 1.9 ND ND29-May-08 0.62 1.0 --- ND --- --- ND ND 1.2 ND 2.2 ND ND6-Nov-08 0.62 1.0 --- 0.63 J --- --- ND 0.68 J 1.1 ND 1.8 ND ND
3-Jun-09 0.62 1.0 --- ND --- --- ND ND 0.95 J ND 2 ND ND
18-Nov-09 0.62 1.0 --- 0.69 J --- --- ND 0.66 J 1.6 ND 2.5 ND ND
NC 2L = 0.03 µg/L (01/01/10) 16-Jun-10 0.62 1.0 --- ND --- --- ND ND 1.1 ND 2.1 ND ND
1-Dec-10 0.62 1.0 --- ND ND --- ND 0.65 J 0.93 J ND 3.5 ND ND
1-Jun-11 0.62 1.0 --- ND ND --- ND 0.87 J 1.1 ND 1.8 ND ND
20-Dec-11 0.62 1.0 --- --- ND --- ND 0.63 J ND ND 1.4 ND ND30-May-12 0.62 1.0 --- --- ND --- ND ND ND ND 1.6 ND ND5-Dec-12 0.62 1.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 0.62 1.0 --- --- ND --- ND ND 0.96 J ND 2.1 ND ND
28-Oct-13 0.62 1.0 --- --- ND --- ND ND 0.74 J ND 1.3 ND ND
6-May-14 EPA 8260 0.62 1.0 --- --- ND --- ND ND 0.77 J ND 1.8 ND ND
22-Oct-14 EPA 8260 0.62 1.0 --- --- * ND ND ND ND ND 1.3 ND ND
21-May-15 EPA 8260 0.62 1.0 --- --- --- ND ND ND ND ND 1.1 ND ND
8-Dec-15 EPA 8260 0.62 1.0 --- --- --- ND ND 0.72 J ND ND 1.4 ND ND
Xylene (Total) 1-Sep-94 --- 5.0 ND NI NI NI ND 12 ND ND NI NI ---
1-Oct-94 --- 5.0 --- NI NI NI --- 22 --- --- NI NI ---
1-Jan-95 --- 5.0 --- NI NI NI ND 7.6 ND ND NI NI ---
1-Feb-95 --- 5.0 --- NI NI NI ND 20 ND ND NI NI ---
1-Mar-95 --- 5.0 ND NI NI NI ND 24 ND ND NI NI ---
1-Aug-95 --- 5.0 ND NI NI NI ND 5 ND ND NI NI ---
1-Jan-96 --- 5.0 --- NI --- --- ND ND ND ND NI NI ---
1-Feb-96 --- 5.0 --- NI --- --- ND ND ND ND NI NI ---1-May-96 --- 5.0 --- NI --- --- ND ND ND ND NI NI ---1-Oct-96 --- 5.0 --- NI --- --- ND 6 ND ND NI NI ---
1-May-97 --- 5.0 ND NI --- --- ND 9.2 4.3 J ND NI NI ---
1-Nov-97 --- 2.0 ND NI --- --- ND ND ND ND NI NI ---
1-May-98 --- 5.0 ND NI --- --- ND 5.6 ND ND NI NI ---
24-Nov-98 --- 2.0 ND NI --- --- ND 14.8 ND ND NI NI ---
10-May-99 --- 5.0 ND ND --- --- ND 13 ND ND ND ND ND
18-Oct-99 --- 5.0 ND ND --- --- ND 14 ND ND ND ND ND3-May-00 --- 5.0 ND ND --- --- ND 17.5 ND ND ND ND ND7-Nov-00 --- 5.0 ND ND --- --- ND 11 ND ND ND ND ND
31-May-01 --- 5.0 ND ND --- --- ND 10 9 10 ND ND ND
7-Nov-01 --- 5.0 ND ND --- --- ND 7.9 5.3 7.6 ND ND ND
22-May-02 --- 5.0 ND ND --- --- ND 5.3 8.5 14 ND ND ND
14-Nov-02 --- 5.0 ND ND --- --- ND ND 21.3 12 ND ND ND
14-May-03 --- 5.0 ND ND --- --- ND 5.4 6.6 48 ND ND ND
20-Nov-03 --- 5.0 ND ND --- --- ND ND 7.4 50 ND ND ND6-May-04 --- 5.0 ND ND --- --- ND ND 18.9 58 ND ND ND10-Nov-04 --- 5.0 ND ND --- --- ND ND ND 54 ND ND ND
27-May-05 --- 5.0 11 ND --- --- ND ND 7 58 ND ND ND
3-Nov-05 --- 5.0 --- ND --- --- ND ND 26 119 ND ND ND
25-May-06 --- 5.0 --- ND --- --- ND ND 17.4 38.7 ND ND ND
2-Nov-06 --- 10.0 --- ND --- --- ND ND ND 31 ND ND ND
30-May-07 --- 4.0 --- 1.1 J --- --- ND 2 J 24 34 1.2 J ND ND
NC 2L = 530 µg/L (10/23/07) 29-Nov-07 --- 5.0 --- 2.7 J --- --- ND ND 3.9 J 24 ND ND ND
29-May-08 0.89 10.0 --- 1.7 J --- --- ND 0.92 J 6.2 J 29.6 ND ND ND6-Nov-08 0.66 2.0 --- 2.3 --- --- ND 0.78 J 2.8 28.7 ND ND ND3-Jun-09 0.66 2.0 --- 1.6 J --- --- ND ND 4.7 46.5 ND ND ND
18-Nov-09 0.66 2.0 --- 5.7 --- --- ND ND 3.1 40.3 ND ND ND
NC 2L = 500 µg/L (01/01/10) 16-Jun-10 0.66 2.0 --- 1.8 J --- --- ND 1 J 5.2 40.3 ND ND ND
1-Dec-10 0.66 2.0 --- 2.3 ND --- ND ND 5.6 42.9 ND ND ND
1-Jun-11 0.66 2.0 --- 3.6 ND --- ND ND 0.88 J 44.1 ND ND ND
20-Dec-11 0.66 2.0 --- --- ND --- ND ND 0.94 J 26.8 D ND ND ND
30-May-12 0.66 2.0 --- --- ND --- ND ND 0.7 J 53.5 ND ND ND5-Dec-12 0.66 5.0 --- --- ND --- ND ND 2.4 J 43.6 ND ND ND12-Jun-13 0.66 5.0 --- --- ND --- ND ND ND 48.3 ND ND ND
28-Oct-13 0.66 5.0 --- --- ND --- ND ND ND 49.3 ND ND ND
6-May-14 EPA 8260 0.66 5.0 --- --- ND --- ND ND ND 40.7 ND ND ND
22-Oct-14 EPA 8260 0.66 5.0 --- --- * ND ND ND ND 46.6 ND ND ND
21-May-15 EPA 8260 0.66 5.0 --- --- --- ND ND ND ND 43.6 ND ND ND
8-Dec-15 EPA 8260 0.66 5.0 --- --- --- ND ND ND ND 45.4 ND ND ND
Diethyl phthalate 29-Nov-07 --- 10.0 --- ND --- --- 1.7 J 2.3 J 2 J ND 1.3 J --- NDNC 2L = 5,000 µg/L (10/23/07) 6-Nov-08 2.5 10.0 --- ND --- --- ND ND ND ND ND ND ND
18-Nov-09 4 10.0 --- ND --- --- ND ND ND ND ND --- ND
1-Dec-10 2.7 10.0 --- ND ND --- ND ND ND ND ND --- ND
20-Dec-11 0.58 10.0 --- --- ND --- ND ND ND ND ND --- ND
5-Dec-12 0.58 6000 --- --- ND --- ND ND ND ND ND --- ND
28-Oct-13 0.58 6000 --- --- ND --- ND ND ND ND ND --- ND
22-Oct-14 0.91 6000 --- --- * ND ND ND ND ND ND --- ND
8-Dec-15 1.3 6000 --- --- --- ND ND ND ND ND ND --- ND
Naphthalene 29-Nov-07 --- 10.0 --- ND --- --- ND ND ND 1.3 JD ND --- ND
NC 2L = 21 µg/L (10/23/07) 6-Nov-08 0.24 10.0 --- ND --- --- ND ND ND ND ND --- 0.67 J
18-Nov-09 0.24 10.0 --- ND --- --- ND ND ND 0.77 JD ND --- ND
1-Dec-10 4 10.0 --- ND ND --- ND ND ND 0.96 J ND --- ND
20-Dec-11 0.34 10.0 --- --- ND --- ND ND ND 0.84 JD ND --- ND
5-Dec-12 0.34 10.0 --- --- ND --- ND ND ND 1.5 B ND --- 0.46 J
28-Oct-13 0.24 10.0 --- --- ND --- ND ND ND 1.6 J ND --- ND22-Oct-14 EPA 8260 0.24 10.0 --- --- * ND ND ND ND 1.9 J ND --- ND8-Dec-15 EPA 8260 0.24 10.0 --- --- --- ND ND ND ND 2.2 J ND --- ND
Pentachlorophenol 29-Nov-07 --- 25.0 --- ND --- --- ND ND ND 0.42 JD ND --- ND
NC 2L = 0.29 µg/L (10/23/07) 6-Nov-08 1.7 25.0 --- ND --- --- ND ND ND ND ND --- ND
18-Nov-09 5 50.0 --- ND --- --- ND ND ND ND ND --- ND
1-Dec-10 18 25.0 --- ND ND --- ND ND ND ND ND --- ND
20-Dec-11 4.6 25.0 --- --- ND --- ND ND ND ND ND --- ND5-Dec-12 4.6 25.0 --- --- ND --- ND ND ND ND ND --- ND28-Oct-13 4.6 25.0 --- --- ND --- ND ND ND ND ND --- ND
22-Oct-14 EPA 8270 1.2 25.0 --- --- * ND ND ND ND ND ND --- ND
8-Dec-15 EPA 8270 2.3 25.0 --- --- --- ND ND ND ND ND ND --- ND
Burke County
John's River C and D over MSW Landfill
Permit 12-03 Page 12 of 14 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample EPA
Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Background Downgradient
alpha-BHC 1-Oct-96 --- 0.050 --- NI --- --- ND 0.07 ND ND NI NI ---
1-May-97 --- 0.050 ND NI --- --- ND ND ND ND NI NI ---1-Nov-97 --- 0.100 ND NI --- --- ND ND ND ND NI NI ---1-May-98 --- 0.050 ND NI --- --- ND ND ND ND NI NI ---
24-Nov-98 --- 0.050 ND NI --- --- ND ND ND ND NI NI ---
10-May-99 --- 0.050 ND ND --- ---0.061 ND ND ND ND ND ND
18-Oct-99 --- 0.050 ND ND --- --- --- ND ND ND ND ND ND
3-May-00 --- 0.050 ND --- --- --- ND ND --- --- --- --- ND
7-Nov-00 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND
7-Nov-01 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND14-Nov-02 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND20-Nov-03 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND
10-Nov-04 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND
3-Nov-05 --- 0.050 --- ND --- --- ND ND ND ND ND --- ND
2-Nov-06 --- 0.050 --- ND --- --- ND ND ND ND ND --- ND
GWPS = 0.006 µg/L (10/23/07) 29-Nov-07 --- 0.050 --- ND --- --- ND ND ND ND ND --- ND
6-Nov-08 0.05 0.050 --- ND --- --- ND ND ND ND ND --- ND
18-Nov-09 0.00031 0.010 --- ND --- --- ND ND ND ND ND --- ND1-Dec-10 0.0003 0.050 --- ND ND --- ND ND ND ND ND --- ND20-Dec-11 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND
5-Dec-12 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND
28-Oct-13 0.05 0.050 --- --- ND --- ND ND ND 0.19 ND --- ND
Resample >10-Dec-13 0.05 0.050 --- --- --- --- --- --- ---0.085 --- --- ND
6-May-14 EPA 8081 0.05 0.050 --- --- ND --- ND ND ND 0.07 ND --- ---
22-Oct-14 EPA 8081 0.05 0.050 --- --- * ND ND ND ND ND ND --- ND
21-May-15 EPA 8081 0.05 0.050 --- --- --- ND ND ND ND 0.12 ND --- ND
8-Dec-15 EPA 8081 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ND
beta-BHC 1-Dec-10 0.0005 0.050 --- ND ND --- ND ND 0.019 J ND ND --- ND
Resample >13-Jan-11 0.0005 0.050 --- --- --- --- --- --- ND --- --- --- ND
GWPS = 0.019 µg/L (10/23/07) 20-Dec-11 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND
5-Dec-12 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND
28-Oct-13 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND
22-Oct-14 EPA 8081 0.05 0.050 --- --- * ND ND ND ND ND ND --- ND
8-Dec-15 EPA 8081 0.05 0.050 --- --- --- ND ND 0.16 ND ND ND --- NDResample >4-Feb-16 EPA 8081 0.05 0.050 --- --- --- --- ---0.33 --- --- --- --- ND
Delta-BHC 18-Oct-99 --- 0.050 ND ND --- --- --- 0.06 J ND ND ND ND ND
3-May-00 --- 0.050 ND --- --- --- ND ND --- --- --- --- ND
7-Nov-00 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND
7-Nov-01 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND
14-Nov-02 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND
20-Nov-03 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND10-Nov-04 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND3-Nov-05 --- 0.050 --- ND --- --- ND ND ND ND ND --- ND
2-Nov-06 --- 0.050 --- ND --- --- ND ND ND ND ND --- ND
GWPS = 0.019 µg/L (10/23/07) 29-Nov-07 --- 0.050 --- ND --- --- ND ND ND ND ND --- ND
6-Nov-08 0.05 0.050 --- ND --- --- ND ND ND ND ND --- ND
18-Nov-09 0.00041 0.010 --- ND --- --- ND ND ND ND ND --- ND
1-Dec-10 0.0004 0.050 --- ND ND --- ND ND ND ND ND --- ND
20-Dec-11 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND
5-Dec-12 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND28-Oct-13 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND22-Oct-14 EPA 8081 0.05 0.050 --- --- * ND ND ND ND ND ND --- ND
8-Dec-15 EPA 8081 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ND
Gamma-BHC 18-Oct-99 --- 0.050 ND ND --- --- --- 0.08 J ND ND ND ND ND
(Lindane) 3-May-00 --- 0.050 ND --- --- --- ND ND --- --- --- --- ND
7-Nov-00 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND
7-Nov-01 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND14-Nov-02 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND20-Nov-03 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND
10-Nov-04 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND
3-Nov-05 --- 0.050 --- ND --- --- ND ND ND ND ND --- ND
2-Nov-06 --- 0.050 --- ND --- --- ND ND ND ND ND --- ND
NC 2L = 0.2 µg/L (10/23/07) 29-Nov-07 --- 0.050 --- ND --- --- ND ND ND ND ND --- ND
6-Nov-08 0.05 0.050 --- ND --- --- ND ND ND ND ND --- ND
18-Nov-09 0.00021 0.010 --- 0.032 --- --- ND ND ND ND ND --- NDResample >19-Jan-10 0.00021 0.010 --- ND --- --- --- --- --- --- --- --- ND1-Dec-10 0.0002 0.050 --- ND ND --- ND ND 0.034 J ND ND --- ND
Resample >13-Jan-11 0.0002 0.050 --- --- --- --- --- --- 0.048 J --- --- --- ND
20-Dec-11 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND
5-Dec-12 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND
28-Oct-13 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND
22-Oct-14 0.05 0.050 --- --- * ND ND ND ND ND ND --- ND
8-Dec-15 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ND
Heptachlor 18-Oct-99 --- 0.050 ND ND --- --- --- 0.11 J ND ND ND ND ND3-May-00 --- 0.050 ND --- --- --- ND ND --- --- --- --- ND
7-Nov-01 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND
14-Nov-02 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND
20-Nov-03 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND
10-Nov-04 --- 0.050 ND --- --- --- ND ND ND ND ND --- ND
3-Nov-05 --- 0.050 --- ND --- --- ND ND ND ND ND --- ND
2-Nov-06 --- 0.050 --- ND --- --- ND ND ND ND ND --- NDNC 2L = 0.0078 µg/L (10/23/07) 29-Nov-07 --- 0.050 --- ND --- --- ND ND ND ND ND --- ND6-Nov-08 0.05 0.050 --- ND --- --- ND ND ND ND ND --- ND
18-Nov-09 0.0015 0.010 --- ND --- --- ND ND ND ND ND --- ND
1-Dec-10 0.0015 0.050 --- ND ND --- ND ND ND ND ND --- ND
20-Dec-11 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND
5-Dec-12 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND
28-Oct-13 0.05 0.050 --- --- ND --- ND ND ND ND ND --- ND
22-Oct-14 EPA 8081 0.05 0.050 --- --- * ND ND ND ND ND ND --- ND8-Dec-15 EPA 8081 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ND
N-Nitroso-di-n-butylamine 22-Oct-14 EPA 8270 1.3 10.0 --- --- --- --- 4.0 J ND ND 11.2 ND --- ND
Resample >22-Dec-14 1.3 10.0 --- --- --- --- --- --- --- ND --- --- ---
NC 2L = NE (01/01/10) 8-Dec-15 EPA 8270 2.2 10.0 --- --- --- ND ND ND ND ND ND --- ND
Burke County
John's River C and D over MSW Landfill
Permit 12-03 Page 13 of 14 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample EPA
Analyte Collection Date Method DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Background Downgradient
PCB-1232 18-Oct-99 --- 2.0 4.7 ND --- ------ ND ND ND ND ND ND
3-May-00 --- 2.0 ND --- --- --- ND ND --- --- --- --- ND
7-Nov-00 --- 2.0 ND --- --- --- ND ND ND ND ND --- ND
7-Nov-00 --- 2.0 ND --- --- --- ND ND ND ND ND --- ND
31-May-01 --- 2.0 ND --- --- --- --- --- --- --- --- --- ND
7-Nov-01 --- 2.0 ND --- --- --- ND ND ND ND ND --- ND
14-Nov-02 --- 2.0 ND --- --- --- ND ND ND ND ND --- ND20-Nov-03 --- 2.0 ND --- --- --- ND ND ND ND ND --- ND10-Nov-04 --- 1.0 ND --- --- --- ND ND ND ND ND --- ND
6-May-05 --- 1.0 --- --- --- --- --- --- --- --- --- --- ---
3-Nov-05 --- 1.0 --- ND --- --- ND ND ND ND ND --- ND
2-Nov-06 --- 1.0 --- ND --- --- ND ND ND ND ND --- ND
GWPS = 0.5 µg/L (10/23/07) 29-Nov-07 --- 2.0 --- ND --- --- ND ND ND ND ND --- ND
6-Nov-08 1 NE --- ND --- --- ND ND ND ND ND --- ND
18-Nov-09 0.12 0.5 --- ND --- --- ND ND ND ND ND --- NDGWPS = 0.09 µg/L (10/01/10) 1-Dec-10 0.5 0.5 --- ND ND --- ND ND ND ND ND --- ND20-Dec-11 0.5 0.5 --- --- ND --- ND ND ND ND ND --- ND
5-Dec-12 0.5 0.5 --- --- ND --- ND ND ND ND ND --- ND
28-Oct-13 0.5 0.5 --- --- ND --- ND ND ND ND ND --- ND
22-Oct-14 0.5 0.5 --- --- * ND ND ND ND ND ND --- ND
8-Dec-15 0.5 0.5 --- --- --- ND ND ND ND ND ND --- ND
2,4-D 1-Aug-95 --- 0.3 ND NI --- --- ND 0.478 ND ND NI NI ---
1-Jan-96 --- 2.0 --- NI --- --- ND ND ND ND NI NI ---1-Feb-96 --- 2.0 --- NI --- --- ND ND ND ND NI NI ---1-May-96 --- 2.0 --- NI --- --- ND ND ND ND NI NI ---
1-Oct-96 --- 0.5 --- NI --- --- ND ND ND ND NI NI ---
1-Nov-97 --- 0.4 ND NI --- --- ND ND ND ND NI NI ---
24-Nov-98 --- 2.0 ND NI --- --- ND ND ND ND NI NI ---
18-Oct-99 --- 2.0 ND ND --- --- --- ND ND ND ND ND ND
7-Nov-01 --- 2.0 ND --- --- --- ND ND ND ND ND --- ND
14-Nov-02 --- 2.0 ND --- --- --- ND ND ND ND ND --- ND20-Nov-03 --- 2.0 ND --- --- --- ND ND ND ND ND --- ND10-Nov-04 --- 2.0 ND --- --- --- ND ND ND ND ND --- ND
3-Nov-05 --- 2.0 --- ND --- --- ND ND ND ND ND --- ND
2-Nov-06 --- 2.0 --- ND --- --- ND ND ND ND ND --- ND
NC 2L = 70 µg/L (10/23/07) 29-Nov-07 --- 2.0 --- ND --- --- ND 1.4 J ND ND ND --- ND
6-Nov-08 1 2.0 --- ND --- --- ND ND ND ND ND --- ND
18-Nov-09 0.22 2.0 --- ND --- --- ND ND ND ND ND --- ND
Resample >19-Jan-10 0.23 1.0 --- ND --- --- --- --- --- ND --- --- ND1-Dec-10 0.22 2.0 --- ND ND --- ND ND ND ND ND --- ND20-Dec-11 0.22 2.0 --- --- ND --- ND ND ND ND ND --- ND
5-Dec-12 0.22 2.0 --- --- ND --- ND ND ND ND ND --- ND
28-Oct-13 0.22 2.0 --- --- ND --- ND ND ND ND ND --- ND
22-Oct-14 EPA 8151 0.23 0.96 --- --- * ND ND ND ND ND ND --- ---
8-Dec-15 EPA 8151 0.22 2.00 --- --- --- ND ND ND ND ND ND --- ND
4,4'-DDD 1-Dec-10 0.0019 0.10 --- ND ND --- ND 0.019 J ND ND ND --- ND
Resample >13-Jan-11 0.0019 0.10 --- --- --- --- --- ND --- --- --- --- NDNC 2L = 0.1 µg/L (01/01/10) 20-Dec-11 0.05 0.05 --- --- ND --- ND ND ND ND ND --- ND5-Dec-12 0.05 0.10 --- --- ND --- ND ND ND ND ND --- ND
28-Oct-13 0.05 0.10 --- --- ND --- ND ND ND ND ND --- ND
22-Oct-14 EPA 8081 0.05 0.10 --- --- * ND ND ND ND ND ND --- ---
8-Dec-15 EPA 8081 0.05 0.10 --- --- --- ND ND ND ND ND ND --- ND
4,4'-DDE 1-Dec-10 0.0009 0.10 --- ND ND --- ND ND ND 0.019 J ND --- ND
Resample >13-Jan-11 0.0009 0.10 --- --- --- --- --- --- --- 0.027 J --- --- NDNC 2L = NE (01/01/10) 20-Dec-11 0.05 0.05 --- --- ND --- ND ND ND ND ND --- ND5-Dec-12 0.05 0.10 --- --- ND --- ND ND ND ND ND --- ND
28-Oct-13 0.05 0.10 --- --- ND --- ND ND ND ND ND --- ND
22-Oct-14 EPA 8081 0.05 0.10 --- --- * ND ND ND ND ND ND --- ---
8-Dec-15 EPA 8081 0.05 0.10 --- --- --- ND ND ND ND ND ND --- ND
Notes: (Abbreviations and Referrences)
All concentrations in micrograms per liter (µg/L) = parts per billion.
# = Constituent is included on the NC Appendix II list but not on the NC Appendix I list.
--- = Not sampled for this parameter or Not reportedAB = Monitoring well abandoned.B = Blank-Qualified (Concentration suspected to reflect laboratory or field contamination based on similar concentrations detected in field, trip, or method blanks).
D = Sample was diluted when analyzed.
DL = Laboratory Detection Limit.
GWPS = Groundwater Protection Standard set by NC-DENR-SWS for constituents with no listed NC 2L standard.
When the NC 2L Groundwater Standard has not been established, the GWPS will be used.
J = Estimated value - concentration is less than the RL but greater than the DL.
NC 2L = Groundwater Standard from 15A NCAC 2L.0202.ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006).NE = No NC 2L or GWPS established.
NI = Not Installed. Monitoring well not yet installed.
RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present).
Values above the NC2L Standard or GWPS are bold.
Notes: (Event Narratives)
Volatile organics (8260) for MW-9 for November 10, 2004 sampling event were unable to be analyzed and were resampled on December 1, 2004. There was a resamplinging event on August 2, 2007 for MW-16D because the prevoius samples from the May 2007 were analyzed out of hold time. There were no detects in the resample.* MW-21 replaced MW-20 as the background well starting with the Fall 2014 sampling event; however MW-20 continues to be sampled as a compliance well for the C&D Expansion (Phase 1A).
See the Water Quality Monitrong Report for the C&D Expansion Area for current results for MW-20.
Sample Collection Date Column displays the last day of the Respective Semiannaul Monitoring Event that samples were collected. Each individual sampling point date is preserved in the Lab Reports (Appendix A).
Burke County
John's River C and D over MSW Landfill
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Appendix F

Historical Detected Constituents in Performance & Sentinel Wells

APPENDIX F:
CONSTITUENTS OF CONCERN DETECTIONS
IN PERFORMANCE AND SENTINEL WELLS
Sample
Analyte Collection Date DL RL MW-18 MW-19 MW-36 MW-38 Blanks
Organic Compounds
Benzene 18-Feb-13 0.25 1.0 --- ---8.0 3.8 ND
18-Jul-13 0.25 1.0 --- --- --- --- ND
28-Oct-13 0.25 1.0 ND ND --- --- ND
NC 2L = 1 µg/L (10/23/07) 6-May-14 0.25 1.0 ND ND 8.7 6.5 ND
22-Oct-14 0.25 1.0 ND ND 8.3 5.9 ND
21-May-15 0.25 1.0 ND ND 5.8 4.9 ND
18-Jul-13 0.33 1.0 --- --- --- --- ND
28-Oct-13 0.33 1.0 ND ND --- --- ND
NC 2L = 6 µg/L (01/01/10) 6-May-14 0.33 1.0 ND ND 10.0 13.5 ND
22-Oct-14 0.33 1.0 ND ND 15.2 12.9 ND
21-May-15 0.33 1.0 ND ND 18.7 12.3 ND
8-Dec-15 0.33 1.0 --- --- 5.8 4.4 ND
1,1-Dichloroethane 3-Jun-09 0.3 5.0 3.9 J 2.8 J --- ---ND
18-Nov-09 0.3 5.0 6.7 3.7 J --- ---ND
16-Jun-10 0.3 5.0 4.4 J 2.3 J --- ---ND
1-Dec-10 0.3 5.0 --- ------ ---ND
1-Jun-11 0.3 5.0 2.8 J 2.6 J --- ---ND
20-Dec-11 0.3 5.0 --- ------ ---ND
30-May-12 0.3 5.0 1.6 J 2.7 J --- ---ND
5-Dec-12 0.3 5.0 --- ------ ---ND
18-Feb-13 0.32 5.0 --- ---7.9 9.1 ND
12-Jun-13 0.3 5.0 --- ------ ---ND
18-Jul-13 0.32 5.0 --- --- --- --- ND
28-Oct-13 0.3 5.0 0.93 J 3.0 J --- --- ND
NC 2L = 6 µg/L (01/01/10) 6-May-14 0.32 5.0 1.2 J 2.9 J 11.6 8.1 ND
22-Oct-14 0.32 5.0 --- ---9.0 6.9 ND
21-May-15 0.32 5.0 ND 1.7 J 4.8 J 5.5 ND
8-Dec-15 0.32 5.0 --- --- 5.9 7.2 ND
1,2-Dichloroethane 3-Jun-09 0.1 1.0 0.33 J ND --- ---ND
18-Nov-09 0.1 1.0 0.56 J ND --- ---ND
16-Jun-10 0.1 1.0 0.37 J ND --- ---ND
1-Dec-10 0.1 1.0 --- ------ ---ND
1-Jun-11 0.1 1.0 0.34 J ND --- ---ND
20-Dec-11 0.1 1.0 --- ------ ---ND
30-May-12 0.1 1.0 ND ND --- ---ND
5-Dec-12 0.1 1.0 --- ------ ---ND
18-Feb-13 0.12 1.0 --- ---1.0 0.59 J ND
12-Jun-13 0.1 1.0 --- ------ ---ND
18-Jul-13 0.12 1.0 --- --- --- --- ND
28-Oct-13 0.1 1.0 ND ND --- --- ND
NC 2L = 0.4 µg/L (01/01/10) 6-May-14 0.12 1.0 ND ND 0.78 J ND ND
22-Oct-14 0.12 1.0 --- --- 0.92 J 0.63 J ND
21-May-15 0.12 1.0 ND ND ND ND ND
8-Dec-15 0.12 1.0 --- --- 0.66 J 0.70 J ND
Methylene Chloride 18-Feb-13 0.97 1.0 --- ---17.9 ND ND
18-Jul-13 0.97 1.0 --- --- --- --- ND
28-Oct-13 0.97 1.0 ND ND --- --- ND
NC 2L = 5 µg/L (01/01/10) 6-May-14 0.97 1.0 --- ---24.1 1.7 2.20
22-Oct-14 0.97 1.0 --- ---15.7 ND ND
21-May-15 0.97 1.0 ND ND 9.5 B ND 1.7
8-Dec-15 0.97 1.0 --- --- 11.2 B ND 2.0
Sentinel Performance
Burke County - John's River C+D-over-MSW Landfill
Permit 12-03
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APPENDIX F:
CONSTITUENTS OF CONCERN DETECTIONS
IN PERFORMANCE AND SENTINEL WELLS
Tetrachloroethene 18-Feb-13 0.46 1.0 --- ---5.5 ND ND
18-Jul-13 0.46 1.0 --- --- --- --- ND
28-Oct-13 0.46 1.0 ND ND --- --- ND
NC 2L = 0.7 µg/L (10/23/07) 6-May-14 0.46 1.0 --- ---7.9 ND ND
22-Oct-14 0.46 1.0 --- ---7.3 ND ND
21-May-15 0.46 1.0 ND ND 6.0 ND ND
8-Dec-15 0.46 1.0 --- ---5.0 ND ND
Trichloroethene 18-Feb-13 0.47 1.0 --- ---3.6 2.7 ND
18-Jul-13 0.47 1.0 --- --- --- --- ND
28-Oct-13 0.47 1.0 ND ND --- --- ND
NC 2L = 3 µg/L (01/01/10) 6-May-14 0.47 1.0 --- ---6.0 2.1 ND
22-Oct-14 0.47 1.0 --- ---5.1 1.8 ND
21-May-15 0.47 1.0 ND ND 3.5 0.9 J ND
8-Dec-15 0.47 1.0 --- --- 2.9 2.1 ND
Vinyl chloride 18-Feb-13 0.62 1.0 --- ---1.2 ND ND
18-Jul-13 0.62 1.0 --- --- --- --- ND
28-Oct-13 0.62 1.0 ND ND --- --- ND
NC 2L = 0.03 µg/L (01/01/10) 6-May-14 0.62 1.0 --- ---1.1 ND ND
22-Oct-14 0.62 1.0 --- --- 0.9 J ND ND
21-May-15 0.62 1.0 ND ND ND ND ND
8-Dec-15 0.62 1.0 --- --- 0.80 J ND ND
Notes:
All concentrations in micrograms per liter (µg/L) = parts per billion.
DL = Laboratory Detection Limit.
RL = SWSL = Solid Waste Section Reporting Limit.
NC 2L = Groundwater Standard from 15A NCAC 2L.0202.
GWPS = Groundwater Protection Standard set by NC-DENR-SWS for constituents with no listed NC 2L.
nle = No longer exists (MW-34 was accidentaly destroyed during construciton activties).
--- = Not reported or not monitored.
Italics = Constituent of Concern (COC).
For MW-36 and MW-38, only COC's are reported in this Appendix. Additional constituents required for the Phase 1A area are included in the Semiannual Groundwater
Monitoring Report for Phase 1A.
Burke County - John's River C+D-over-MSW Landfill
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Joyce Engineering

Appendix G

Historical Detected Surface Water Constituents

APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Inorganic Compounds
Antimony 6-Nov-08 2.6 6.0 ND 8.4 ---ND
3-Jun-09 2.6 6.0 ND ND --- ND
18-Nov-09 2.6 6.0 ND ND --- ND
NC 2B = NE (05/01/07) 15-Jun-10 2.6 6.0 ND ND --- ND
1-Dec-10 2.6 6.0 ND ND --- ND
1-Jun-11 2.6 6.0 ND ND --- ND
20-Dec-11 5.0 6.0 ND ND --- ND
30-May-12 5.0 6.0 ND ND --- ND
5-Dec-12 5.0 6.0 ND ND --- ND
12-Jun-13 5.0 6.0 ND ND --- ND
28-Oct-13 5.0 6.0 ND ND --- ND
6-May-14 5.0 6.0 ND ND --- ND
22-Oct-14 5.0 6.0 --- ND ND ND
21-May-15 3.8 6.0 ND ND ND ND
9-Dec-15 3.8 6.0 ND ND ND ND
Arsenic 6-Nov-08 2.7 10.0 2.9 B 4.5 B ---4.1 J
3-Jun-09 2.7 10.0 ND 4.5 J --- ND
18-Nov-09 2.7 10.0 ND ND --- ND
NC 2B = 10 µg/L (05/01/07) 15-Jun-10 2.7 10.0 ND ND --- ND
1-Dec-10 2.7 10.0 ND ND --- ND
1-Jun-11 2.7 10.0 ND ND --- ND
20-Dec-11 5.0 10.0 ND ND --- ND
30-May-12 5.0 10.0 ND ND --- ND
5-Dec-12 5.0 10.0 ND ND --- ND
12-Jun-13 5.0 10.0 ND ND --- ND
28-Oct-13 5.0 10.0 ND ND --- ND
6-May-14 5.0 10.0 ND ND --- ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
Barium 30-May-07 --- 100 81.3 J 23.8 J ---0.2 J
29-Nov-07 --- 100 116 27.5 J --- 0.50 J
29-May-08 0.2 100 71.9 J 19.6 J --- ND
6-Nov-08 0.20 100 82.5 J 40.2 B --- 9.6 J
3-Jun-09 0.20 100 104 36.2 B --- 15.9 J
18-Nov-09 0.20 100 49.9 B 15.7 B --- 20.1 J
NC 2B = 1,000 µg/L (05/01/07) 15-Jun-10 0.20 100 47.6 J 20.7 J --- 0.77 J
1-Dec-10 0.20 100 39.8 J 46.8 J --- ND
1-Jun-11 0.20 100 51.6 J 19.9 J --- ND
20-Dec-11 5.0 100 63.7 J 13.9 J --- ND
30-May-12 5.0 100 16.9 J 22.0 J --- ND
5-Dec-12 5.0 100 69.9 J 24.8 J --- ND
12-Jun-13 5.0 100 54.9 B 40.0 B ---13.6 J
28-Oct-13 5.0 100 35.4 J 20.8 J --- ND
6-May-14 5.0 100 37.0 J 17.8 J --- ND
22-Oct-14 5.0 100 --- 25.5 J 19.8 J ND
21-May-15 2.5 100 53.0 J 14.6 J 21.6 J ND
9-Dec-15 2.5 100 26.1 J 23.4 J 27.8 J ND
Burke County John's River Landfill - Phase 1A
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APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Beryllium 14-Nov-02 --- 2 2.0 B 2.2 B ---2.1
14-May-03 --- 2 ND ND --- ND
20-Nov-03 --- 2 ND ND --- ND
6-May-04 --- 2 ND ND --- ND
10-Nov-04 --- 2 ND ND --- ND
5-May-05 --- 2 ND ND --- ND
3-Nov-05 --- 2 ND ND --- ND
25-May-06 --- 2 ND ND --- ND
2-Nov-06 --- 2 ND ND --- ND
30-May-07 --- 1 ND ND --- ND
29-Nov-07 --- 1 ND ND --- ND
29-May-08 0.10 1.0 ND ND --- ND
6-Nov-08 0.10 1.0 0.24 B 0.37 B ---0.29 J
3-Jun-09 0.10 1.0 0.64 J 0.21 J --- ND
18-Nov-09 0.10 1.0 ND ND --- ND
NC 2B = 6.5 µg/L (05/01/07) 15-Jun-10 0.10 1.0 ND ND ---ND
1-Dec-10 0.10 1.0 ND ND --- ND
1-Jun-11 0.10 1.0 ND ND --- ND
20-Dec-11 1.0 1.0 ND ND --- ND
30-May-12 1.0 1.0 ND ND --- ND
5-Dec-12 1.0 1.0 ND ND --- ND
12-Jun-13 1.0 1.0 ND ND --- ND
28-Oct-13 1.0 1.0 ND ND --- ND
6-May-14 1.0 1.0 ND ND --- ND
22-Oct-14 1.0 1.0 --- ND ND ND
21-May-15 0.5 1.0 ND ND ND ND
9-Dec-15 0.5 1.0 ND ND ND ND
Burke County John's River Landfill - Phase 1A
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Joyce Engineering
APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Cadmium 7-Nov-01 --- 1 ND 1.0 --- ND
22-May-02 --- 1 ND 1.7 B --- 1.3
14-Nov-02 --- 1 ND ND --- ND
14-May-03 --- 1 ND ND --- ND
20-Nov-03 --- 1 ND ND --- ND
6-May-04 --- 1 ND ND --- ND
10-Nov-04 --- 1 ND ND --- ND
5-May-05 --- 1 ND ND --- ND
3-Nov-05 --- 1 ND ND --- ND
25-May-06 --- 1 ND ND --- ND
2-Nov-06 --- 1 ND ND --- ND
30-May-07 --- 1 ND ND --- ND
29-Nov-07 --- 1 ND ND ---ND
29-May-08 0.5 1.0 ND ND --- ND
6-Nov-08 0.50 1.0 ND ND --- ND
3-Jun-09 0.50 1.0 ND ND ---ND
18-Nov-09 0.50 1.0 ND ND --- ND
NC 2B = 2 µg/L (05/01/07) 15-Jun-10 0.50 1.0 ND ND --- ND
1-Dec-10 0.50 1.0 ND ND --- ND
1-Jun-11 0.50 1.0 ND ND --- ND
20-Dec-11 1.0 1.0 ND ND --- ND
30-May-12 1.0 1.0 ND ND --- ND
5-Dec-12 1.0 1.0 ND ND --- ND
12-Jun-13 1.0 1.0 ND ND --- ND
28-Oct-13 1.0 1.0 ND ND --- ND
6-May-14 1.0 1.0 ND ND --- ND
22-Oct-14 1.0 1.0 --- ND ND ND
21-May-15 0.5 1.0 ND ND ND ND
9-Dec-15 0.5 1.0 ND ND ND ND
Chromium 6-Nov-08 0.40 10.0 ND 0.47 J --- ND
3-Jun-09 0.40 10.0 7.5 J 3.2 J --- ND
18-Nov-09 0.40 10.0 ND ND --- ND
NC 2B = 50 µg/L (05/01/07) 15-Jun-10 0.40 10.0 1.2 B 0.48 B --- 0.74 J
1-Dec-10 0.40 10.0 0.68 B 5.1 J --- 0.51 J
1-Jun-11 0.40 10.0 0.59 B 0.59 B --- 0.73 J
20-Dec-11 5.0 10.0 ND ND --- ND
30-May-12 5.0 10.0 ND ND --- ND
5-Dec-12 5.0 10.0 ND ND --- ND
12-Jun-13 5.0 10.0 ND ND --- ND
28-Oct-13 5.0 10.0 ND ND --- ND
6-May-14 5.0 10.0 ND ND --- ND
22-Oct-14 5.0 10.0 --- ND 9.7 J ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
Burke County John's River Landfill - Phase 1A
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APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Cobalt 22-May-02 --- 10 14.0 17.0 --- 11.0
14-Nov-02 --- 10 ND ND --- ND
14-May-03 --- 10 ND 10.0 --- ND
20-Nov-03 --- 10 14.0 ND --- ND
6-May-04 --- 10 ND ND --- ND
10-Nov-04 --- 10 10.0 ND --- ND
5-May-05 --- 10 10.0 ND --- ND
3-Nov-05 --- 10 16.0 ND --- ND
25-May-06 --- 10 12 ND --- ND
2-Nov-06 --- 10 13.6 ND --- ND
30-May-07 --- 10 12.3 8.8 J --- ND
29-Nov-07 --- 10 19.0 2.1 J --- ND
29-May-08 0.60 10.0 13.7 ND --- ND
6-Nov-08 0.60 10.0 12.6 ND --- 0.65 J
3-Jun-09 0.60 10.0 11.9 B 6.6 B --- 7.6 J
18-Nov-09 0.60 10.0 3.6 J 4.6 J --- ND
NC 2B = NE (05/01/07) 15-Jun-10 0.60 10.0 6.4 J 22.3 --- ND
1-Dec-10 0.60 10.0 0.76 J 4.1 J --- ND
1-Jun-11 0.60 10.0 2.0 J 1.7 J --- ND
20-Dec-11 5.0 10.0 ND ND --- ND
30-May-12 5.0 10.0 ND ND --- ND
5-Dec-12 5.0 10.0 29.0 7.7 J --- ND
12-Jun-13 5.0 10.0 ND 9.1 J --- ND
28-Oct-13 5.0 10.0 11.5 12.4 --- ND
6-May-14 5.0 10.0 ND ND --- ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 6.3 J ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
Copper 29-May-08 0.30 10.0 ND 1.3 B --- 0.37 J
6-Nov-08 4.0 10.0 0.45 B 3.4 J --- 0.65 J
3-Jun-09 0.30 10.0 6.6 J 2.1 J --- ND
18-Nov-09 0.30 10.0 ND ND --- ND
NC 2B = 7 µg/L (05/01/07) 15-Jun-10 0.30 10.0 0.56 B ND --- 0.77 J
1-Dec-10 0.30 10.0 3.6 J 5.9 J --- ND
1-Jun-11 0.30 10.0 1.8 J 0.35 J --- ND
20-Dec-11 5.0 10.0 ND ND --- ND
30-May-12 5.0 10.0 ND ND --- ND
5-Dec-12 5.0 10.0 ND ND --- ND
12-Jun-13 5.0 10.0 5.2 B ND --- 9.8 J
28-Oct-13 5.0 10.0 ND ND --- ND
6-May-14 5.0 10.0 ND ND --- ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
Burke County John's River Landfill - Phase 1A
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APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Lead 3-Jun-09 4.0 10.0 7.3 J ND --- ND
18-Nov-09 4.0 10.0 ND ND --- ND
NC 2B = 25 µg/L (05/01/07) 15-Jun-10 4.0 10.0 ND ND --- ND
1-Dec-10 4.0 10.0 ND 4.6 J --- ND
1-Jun-11 4.0 10.0 ND ND --- ND
20-Dec-11 5.0 10.0 ND ND --- ND
30-May-12 5.0 10.0 ND ND --- ND
5-Dec-12 5.0 10.0 ND ND --- ND
12-Jun-13 5.0 10.0 ND ND --- ND
28-Oct-13 5.0 10.0 ND ND --- ND
6-May-14 5.0 10.0 ND ND --- ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
Nickel 3-Jun-09 1.7 50.0 5.5 B ND --- 1.7 J
18-Nov-09 1.7 50.0 ND ND --- ND
NC 2B = 25 µg/L (05/01/07) 15-Jun-10 1.7 50.0 ND ND --- ND
1-Dec-10 1.7 50.0 2.8 J 2.8 J --- ND
1-Jun-11 1.7 50.0 ND ND --- 2.3 J
20-Dec-11 5.0 50.0 ND ND --- ND
30-May-12 5.0 50.0 ND ND --- ND
5-Dec-12 5.0 50.0 ND ND --- ND
12-Jun-13 5.0 50.0 ND ND --- ND
28-Oct-13 5.0 50.0 ND ND --- ND
6-May-14 5.0 50.0 ND ND --- ND
22-Oct-14 5.0 50.0 --- ND ND ND
21-May-15 2.5 50.0 ND ND ND ND
9-Dec-15 2.5 50.0 ND ND ND ND
Selenium 6-Nov-08 3.8 10 ND 10.9 --- ND
3-Jun-09 3.8 10.0 ND ND --- ND
18-Nov-09 3.8 10.0 ND ND --- ND
NC 2B = 5 µg/L (05/01/07) 15-Jun-10 3.8 10.0 ND ND --- ND
1-Dec-10 3.8 10.0 ND ND --- ND
1-Jun-11 3.8 10.0 ND ND --- ND
20-Dec-11 10.0 10.0 ND ND --- ND
30-May-12 10.0 10.0 ND ND --- ND
5-Dec-12 10.0 10.0 ND ND --- ND
12-Jun-13 10.0 10.0 ND ND --- ND
28-Oct-13 10.0 10.0 ND ND --- ND
6-May-14 10.0 10.0 ND ND --- ND
22-Oct-14 10.0 10.0 --- ND ND ND
21-May-15 5.0 10.0 ND ND ND ND
9-Dec-15 5.0 10.0 ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 5 of 9
Joyce Engineering
APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Silver 22-May-02 --- 10 16.0 B 15.0 B --- 15.0
14-Nov-02 --- 10 ND ND --- ND
14-May-03 --- 10 ND ND --- ND
20-Nov-03 --- 10 ND ND --- ND
6-May-04 --- 10 ND ND --- ND
10-Nov-04 --- 10 ND ND --- ND
5-May-05 --- 10 ND ND --- ND
3-Nov-05 --- 10 ND ND --- ND
25-May-06 --- 10 ND ND --- ND
2-Nov-06 --- 10 ND ND --- ND
30-May-07 --- 10 ND ND --- ND
29-Nov-07 --- 10 ND ND --- ND
29-May-08 0.10 10.0 0.29 J 0.13 J --- ND
6-Nov-08 0.10 10.0 0.72 B 0.38 B --- 0.23 J
3-Jun-09 0.10 10.0 0.18 B ND --- 0.31 J
18-Nov-09 0.10 10.0 0.27 B 0.23 B --- 0.23 J
NC 2B = 0.06 µg/L (05/01/07) 15-Jun-10 0.10 10.0 ND ND --- ND
1-Dec-10 0.10 10.0 ND ND --- ND
1-Jun-11 0.10 10.0 ND 0.22 J --- ND
20-Dec-11 5.0 10.0 ND ND --- ND
30-May-12 5.0 10.0 ND ND --- ND
5-Dec-12 5.0 10.0 ND ND --- ND
12-Jun-13 5.0 10.0 ND ND --- ND
28-Oct-13 5.0 10.0 ND ND --- ND
6-May-14 5.0 10.0 ND ND --- ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
Thallium 5-May-05 --- 10 22.0 11.0 --- ND
3-Nov-05 --- 10 20.0 ND --- ND
25-May-06 --- 10 ND ND --- ND
2-Nov-06 --- 10 ND ND --- ND
30-May-07 --- 5.5 0.053 J ND --- ND
29-Nov-07 --- 5.5 0.055 J ND --- ND
29-May-08 3.0 5.5 ND ND --- ND
6-Nov-08 3.0 5.5 ND ND --- ND
3-Jun-09 3.0 5.5 ND ND --- ND
18-Nov-09 3.0 5.5 ND ND --- 4.2 J
NC 2B = NE (05/01/07) 15-Jun-10 3.0 5.5 3.2 J ND --- ND
1-Dec-10 3.0 5.5 ND ND --- 4.0 J
1-Jun-11 3.0 5.5 ND ND --- ND
20-Dec-11 5.4 5.5 ND ND --- ND
30-May-12 5.4 5.5 ND ND --- ND
5-Dec-12 5.4 5.5 ND ND --- ND
12-Jun-13 5.4 5.5 ND ND --- ND
28-Oct-13 5.4 5.5 ND ND --- ND
6-May-14 5.4 5.5 ND ND --- ND
22-Oct-14 5.4 5.5 --- ND ND ND
21-May-15 5.0 5.5 ND ND ND ND
9-Dec-15 5.0 5.5 ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 6 of 9
Joyce Engineering
APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Vanadium 6-Nov-08 0.20 25.0 0.90 B 8.9 B --- 2.1 J
3-Jun-09 0.20 25.0 17.4 J 7.5 J --- 1.0 J
18-Nov-09 0.20 25.0 0.26 B 0.30 B --- 0.56 J
NC 2B = NE (05/01/07) 15-Jun-10 0.20 25.0 1.5 B 1.0 B --- 0.98 J
1-Dec-10 0.20 25.0 1.1 J 13.7 J --- ND
1-Jun-11 0.20 25.0 1.1 J 0.74 J --- ND
20-Dec-11 5.0 25.0 ND ND --- ND
30-May-12 5.0 25.0 ND ND --- ND
5-Dec-12 5.0 25.0 ND ND --- ND
12-Jun-13 5.0 25.0 7.6 J ND --- ND
28-Oct-13 5.0 25.0 ND ND --- ND
6-May-14 5.0 25.0 ND ND --- ND
22-Oct-14 5.0 25.0 --- ND ND ND
21-May-15 2.5 25.0 7.5 J ND 4.1 J ND
9-Dec-15 2.5 25.0 ND ND 3.9 J ND
Zinc 30-May-07 --- 10 1.8 B ND --- 1.6 J
29-Nov-07 --- 10 9.6 B ND --- 3.1 J
29-May-08 0.40 10.0 6.0 B ND --- 3.0 J
6-Nov-08 0.40 10.0 0.82 B 1.4 B --- 2.7 J
3-Jun-09 0.40 10.0 33.7 B 9.6 B --- 82.0
18-Nov-09 0.40 10.0 2.2 B 2.5 B --- 3.1 J
NC 2B = 50 µg/L (05/01/07) 15-Jun-10 0.40 10.0 ND ND --- ND
1-Dec-10 0.40 10.0 8.8 J 6.6 J --- 0.62 J
1-Jun-11 0.40 10.0 15.1 B 21.5 B --- 13.7
20-Dec-11 10.0 10.0 ND ND --- ND
30-May-12 10.0 10.0 ND ND --- ND
5-Dec-12 10.0 10.0 ND ND --- ND
12-Jun-13 10.0 10.0 ND ND --- 76.5
28-Oct-13 10.0 10.0 ND ND --- ND
6-May-14 10.0 10.0 ND ND --- ND
22-Oct-14 10.0 10.0 --- ND ND ND
21-May-15 5.0 10.0 ND 5.8 J ND ND
9-Dec-15 5.0 10.0 ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 7 of 9
Joyce Engineering
APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Organic Compounds
Acetone 29-Nov-07 --- 100 3.6 B ND --- 5.1 J
29-May-08 20 100 ND ND --- ND
6-Nov-08 20 100 ND ND --- ND
3-Jun-09 2.2 100 5.7 J ND --- ND
18-Nov-09 2.2 100 ND ND --- ND
NC 2B = NE (05/01/07) 15-Jun-10 2.2 100 2.2 B 2.3 B --- 7.2 J
1-Dec-10 2.2 100 ND ND --- 3.7 J
1-Jun-11 2.2 100 5.4 B 2.9 B --- 3.9 J
20-Dec-11 2.2 100 ND ND --- ND
30-May-12 2.2 100 ND ND --- ND
5-Dec-12 10.0 100 ND ND --- ND
12-Jun-13 10.0 100 ND ND --- ND
28-Oct-13 10.0 100 ND ND --- ND
6-May-14 10.0 100 ND ND --- ND
22-Oct-14 10.0 100 --- ND ND ND
21-May-15 10.0 100 ND ND ND ND
9-Dec-15 10.0 100 ND ND ND ND
Chloromethane 15-Jun-10 0.11 1.0 ND 0.11 J --- ND
NC 2B = NE (05/01/07) 1-Dec-10 0.11 1.0 ND ND --- ND
1-Jun-11 0.11 1.0 ND ND --- ND
20-Dec-11 0.11 1.0 ND ND --- ND
30-May-12 0.11 1.0 ND ND --- ND
5-Dec-12 0.11 1.0 ND ND --- ND
12-Jun-13 0.11 1.0 ND ND --- ND
28-Oct-13 0.11 1.0 ND ND --- ND
6-May-14 0.11 1.0 ND ND --- ND
22-Oct-14 0.11 1.0 --- ND ND ND
21-May-15 0.11 1.0 ND ND ND ND
9-Dec-15 0.11 1.0 ND ND ND ND
1,1-Dichloroethane 1-Jun-11 0.32 5.0 ND 0.41 J --- ND
NC 2B = NE (05/01/07) 20-Dec-11 0.32 5.0 ND ND --- ND
30-May-12 0.32 5.0 ND ND --- ND
5-Dec-12 0.32 5.0 ND 1.6 J --- ND
12-Jun-13 0.32 5.0 ND ND --- ND
28-Oct-13 0.32 5.0 ND 0.96 J --- ND
6-May-14 0.32 5.0 ND ND --- ND
22-Oct-14 0.32 5.0 --- 1.5 J ND ND
21-May-15 0.32 5.0 ND ND ND ND
9-Dec-15 0.32 5.0 ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 8 of 9
Joyce Engineering
APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
cis-1,2-Dichloroethene 22-Oct-14 0.2 5.0 --- 0.20 J ND ND
21-May-15 0.2 5.0 ND ND ND ND
NC 2B = NE (05/15/13)9-Dec-15 0.2 5.0 ND ND ND ND
Notes:
All concentrations in micrograms per liter (µg/L) = parts per billion.
RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006;
and SWSL for December 2006 - present).
DL = Laboratory Detection Limit.
NI = Monitoring well not yet installed.
AB = Monitoring well abandoned.
--- = Not sampled for this parameter or Not reported
ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006).
J = Estimated value - concentration is less than the RL but greater than the DL.
B = Blank-Qualified (Concentration suspected to reflect laboratory or field contamination based on
similar concentrations detected in field, trip, or method blanks).
D = Sample was diluted when analyzed.
NC 2B = Groundwater Standard from 15A NCAC 2B.
NE = No NC 2B established.
Values above the NC 2B Standard are bold.
Surface waters classified as WS-IV (water supply IV, highly developed), B (primary recreation, fresh water), and CA (critical area).
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 9 of 9
Joyce Engineering

Appendix H

Historical MNA Parameters

APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
Temperature (FP)11/3/2006 oC 14.90 NS NS 15.25 16.97 16.52 NI NI
6/3/2009 oC 15.90 NS NS 19.10 19.40 14.50 16.20 16.30
11/17/2009 oC 12.0 NS NS 13.9 15.9 13.7 13.8 12.0
6/16/2010 oC 16.06 NS NS 17.65 17.8 17.69 18.83 16.3
12/1/2010 oC 13.43 NU NS 11.17 12.27 14.1 14.4 14.6
6/1/2011 oC 17.21 NU NS 18.39 17.59 21.68 15.04 16.57
12/20/2011 oC NS 14.30 NS 14.52 14.30 14.69 NS NS
5/30/2012 oC NS 18.18 NS 21.70 20.80 16.90 16.99 17.26
12/5/2012 oC NS 15.40 NS 15.00 15.50 16.90 NS NS
6/12/2013 oC NS 18.10 NS 18.70 18.20 16.30 NS NS
10/28/2013 oC NS 17.70 NS 18.40 18.20 17.50 17.40 17.10
5/6/2014 oC NS 16.90 NS 22.40 21.00 18.00 14.90 14.50
10/23/2014 oC NS * 17.20 13.00 11.50 9.80 NS NS
5/21/2015 oC NS 17.80 19.80 18.70 22.20 18.60 18.10 25.50
12/8/2015 oC NS 16.20 15.20 15.40 16.10 16.90 NS NS
pH (FP)11/3/2006 S.U. 5.34 NS NS 5.32 5.40 5.68 NI NI
6/3/2009 S.U. 5.79 NS NS 5.74 5.62 5.96 6.20 6.28
11/17/2009 S.U. 6.03 NS NS 5.92 5.49 6.08 5.84 6.24
6/16/2010 S.U. 6.23 NS NS 6.37 6.28 5.64 6.28 6.05
12/1/2010 S.U. 5.40 NU NS 6.10 6.10 6.05 6.52 6.36
6/1/2011 S.U. 5.83 NU NS 6.01 5.96 5.87 6.25 6.24
12/20/2011 S.U. NS 6.12 NS 5.98 5.90 6.01 NS NS
5/30/2012 S.U. NS 6.61 NS 5.74 5.57 5.61 5.84 5.76
12/5/2012 S.U. NS 5.41 NS 6.12 5.93 5.75 NS NS
6/12/2013 S.U. NS 5.92 NS 6.00 5.32 5.57 NS NS
10/28/2013 S.U. NS 6.89 NS 5.85 5.88 5.76 6.12 6.22
5/6/2014 S.U. NS 5.37 NS 5.46 5.69 5.74 5.41 5.74
10/23/2014 S.U. NS * 5.52 5.80 5.64 5.41 NS NS
5/21/2015 S.U. NS 6.18 5.29 6.03 6.25 5.88 6.09 6.19
12/8/2015 S.U. NS 6.09 5.13 6.06 5.81 5.66 NS NS
Specific Conductance (FP)11/3/2006 µS/cm 59 NS NS 133 95 207 NI NI
6/3/2009 µS/cm 139.5 NS NS 258 146.2 286 220 329
11/17/2009 µS/cm 182.7 NS NS 279 146.9 245 218 330
6/16/2010 µS/cm 124 NS NS 310 214 213 216 309
12/1/2010 µS/cm 143 NU NS 235 133 160 292 310
6/1/2011 µS/cm 69 NU NS 384 175 293 241 392
12/20/2011 µS/cm NS 26 NS 314 152 229 NS NS
5/30/2012 µS/cm NS 26.0 NS 392.0 177.0 229.0 227.0 256.0
12/5/2012 µS/cm NS 19.5 NS 370.1 148.8 197.4 NS NS
6/12/2013 µS/cm NS 29.8 NS 345.2 201.7 201.7 NS NS
10/28/2013 µS/cm NS 24.5 NS 430.0 189.5 229.9 215.6 295.2
5/6/2014 µS/cm NS 30.1 NS 460.7 208.5 230.4 179.0 276.9
10/23/2014 µS/cm NS * 68.1 311.0 170.2 103.8 NS NS
5/21/2015 µS/cm NS 19.8 27.2 435.4 221.5 231.2 262.0 412.2
12/8/2015 µS/cm NS 24.1 15.5 400.6 203.4 208.5 NS NS
ORP (FP)11/3/2006 mV 93.8 NS NS 143.9 90.5 43.2 NI NI
6/3/2009 mV 195.0 NS NS 150.0 130.0 138.0 132.0 113.0
11/17/2009 mV 167.0 NS NS 133.0 162.0 132.0 158.0 128.0
6/16/2010 mV 13.8 NS NS -12.5 -58.6 -73.4 -36.8 -63.5
12/1/2010 mV 31.6 NU NS -49.1 -74.7 -105.9 NS NS
6/1/2011 mV 73.2 NU NS 28.6 -7.2 40.1 10.3 -2.6
12/20/2011 mV NS 56.8 NS 18.7 30.3 3.9 NS NS
5/30/2012 mV NS 7.1 NS -14.8 38.9 21.7 26.70 20.10
12/5/2012 mV NS 227.2 NS -6.9 46.0 23.4 NS NS
6/12/2013 mV NS 104.7 NS -38.0 29.6 86.4 NS NS
10/28/2013 mV NS 21.7 NS -10.5 53.2 47.3 -7.20 5.40
5/6/2014 mV NS 116.5 NS 21.0 29.7 228.0 94.20 33.90
10/23/2014 mV NS * 104.6 -2.3 -3.8 36.6 NS NS
5/21/2015 mV NS 61.80 136.8 21.9 66.0 46.9 66.00 12.50
12/8/2015 mV NS 148.80 269.9 -21.4 -6.2 25.7 NS NS
Background Downgradient Sentinel
Burke County John's River C and D over MSW Landfill
Permit No. 12-03 Page 1 of 8
Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
Turbidity (FP)11/3/2006 ntu 10.4 NS NS 7.97 64.0 16.3 NI NI
6/3/2009 ntu 154 NS NS 20.6 7.54 39.1 390 125
11/17/2009 ntu 318 NS NS 19.65 7.89 23.0 <100 22.2
6/16/2010 ntu 44.8 NS NS 165 95.9 43.2 14.9 9.29
12/1/2010 ntu 20.2 NU NS 31 46.4 43.1 >1000 463
6/1/2011 ntu 7.58 NU NS 19.06 13.14 5.74 33.4 59.6
12/20/2011 ntu NS 80.4 NS 46.30 36.70 24.80 NS NS
5/30/2012 ntu NS 14.0 NS 19.80 33.50 15.90 20.60 27.30
12/5/2012 ntu NS 631 NS 19.50 23.50 7.14 NS NS
6/12/2013 ntu NS 21.3 NS 10.82 15.80 8.11 NS NS
10/28/2013 ntu NS 7.39 NS 8.30 6.41 4.31 4.62 14.30
5/6/2014 ntu NS 37.1 NS 12.95 6.05 4.29 37.00 9.20
10/23/2014 ntu NS * 8.15 21.7 10.04 7.55 NS NS
5/21/2015 ntu NS 27.10 8.15 12.6 17.50 7.72 9.10 11.13
12/8/2015 ntu NS 55.60 25.5 16.7 35.40 30.50 NS NS
Dissolved Oxygen (FP)11/3/2006 mg/L 4.01 NS NS 0.95 1.21 1.10 NI NI
6/3/2009 mg/L 1.21 NS NS 0.84 0.57 0.99 1.38 0.60
11/17/2009 mg/L NS NS NS 2.35 4.12 3.50 2.23 3.20
6/16/2010 mg/L 4.61 NS NS 2.49 2.86 2.10 3.59 4.16
12/1/2010 mg/L 7.94 NU NS 1.29 1.29 5.15 NS NS
6/1/2011 mg/L 4.76 NU NS 2.46 1.77 1.64 3.80 3.27
12/20/2011 mg/L NS 8.18 NS 1.87 2.17 2.17 NS NS
5/30/2012 mg/L NS 6.24 NS 3.67 6.33 1.98 8.47 8.11
12/5/2012 mg/L NS 7.29 NS 2.09 3.57 0.99 NS NS
6/12/2013 mg/L NS 8.68 NS 1.53 1.25 1.75 NS NS
10/28/2013 mg/L NS 7.14 NS 3.42 2.47 2.82 3.62 3.21
5/6/2014 mg/L NS 7.83 NS 1.89 1.47 1.33 2.25 1.86
10/23/2014 mg/L NS * 5.74 2.78 1.36 2.75 NS NS
5/21/2015 mg/L NS 0.10 5.66 1.01 1.79 0.01 1.01 0.10
12/8/2015 mg/L NS 7.53 7.59 4.62 2.47 1.49 NS NS
Carbon Dioxide (FP)11/3/2006 mg/L NS NS NS NS NS NS NI NI
6/3/2009 mg/L 170 NS NS 295 255 325 185 315.00
11/17/2009 mg/L 220 NS NS 355 335 385 NS 280
6/16/2010 mg/L 220 NS NS 510 395 430 185 280
12/1/2010 mg/L 25 NU NS 440 285 230 NS NS
6/1/2011 mg/L NS NU NS NS NS NS NS NS
12/20/2011 mg/L NS NS NS NS NS NS NS NS
5/30/2012 mg/L NS NS NS NS NS NS NS NS
12/5/2012 mg/L NS NS NS NS NS NS NS NS
6/12/2013 mg/L NS 25.0 NS 80 95 90 NS NS
10/28/2013 mg/L NS 25.0 NS 335 240 130 160 130
5/6/2014 mg/L NS NS NS NS NS NS NS NS
10/23/2014 mg/L NS * NS NS NS NS NS NS
5/21/2015 mg/L NS NS NS NS NS NS NS NS
12/8/2015 mg/L NS NS NS NS NS NS NS NS
Iron II (ferrous iron) (FP)11/3/2006 mg/L NS NS NS 0.5 6.4 7.5 NI NI
6/3/2009 mg/L 0.0 NS NS 5.9 9.5 9.4 7.2 9.4
11/17/2009 mg/L 0.0 NS NS 5.0 6.8 4.0 4.0 6.0
6/16/2010 mg/L 6.5 NS NS 8.0 6.5 4.0 5.0 8.8
12/1/2010 mg/L 0.0 NU NS 6.2 4.6 10.0 NS NS
6/1/2011 mg/L NS NU NS NS NS NS NS NS
12/20/2011 mg/L NS 0.0 NS 6.1 4.5 5.6 NS NS
5/30/2012 mg/L NS 0.0 NS 5.6 3.8 5.2 3.20 3.30
12/5/2012 mg/L NS 0.0 NS 5.2 4.0 6.3 NS NS
6/12/2013 mg/L NS 0.0 NS 6.0 4.2 3.0 NS NS
10/28/2013 mg/L NS 0.0 NS 5.5 9.0 4.8 6.5 6.0
5/6/2014 mg/L NS 0.0 NS 7.3 4.3 5.8 5.0 5.8
10/23/2014 mg/L NS * 0.0 4.5 7.0 3.75 NS NS
5/21/2015 mg/L NS NS 0.0 5.8 7.0 7.0 4.7 5.8
12/8/2015 mg/L NS NS 0.0 3.5 2.0 3.2 NS NS
Burke County John's River C and D over MSW Landfill
Permit No. 12-03 Page 2 of 8
Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
Nitrate 11/3/2006 mg/L NS NS NS <0.5 <0.5 <0.5 NI NI
6/3/2009 mg/L <0.1 NS NS <0.1 <0.1 <0.1 <0.1 0.26
11/17/2009 mg/L <0.1 NS NS <0.1 <0.1 <0.1 <0.1 <0.1
6/16/2010 mg/L <0.1 NS NS <0.1 <0.1 <0.1 <0.1 <0.1
12/1/2010 mg/L <0.1 NU NS <0.1 <0.1 <0.1 NS NS
6/1/2011 mg/L <0.1 NU NS <0.1 <0.1 <0.1 <0.1 <0.1
12/20/2011 mg/L NS <0.1 NS <0.1 <0.1 <0.1 NS NS
5/30/2012 mg/L NS .207 J NS <0.1 <0.1 <0.1 <0.1 <0.1
12/5/2012 mg/L NS .294 J NS <0.1 <0.1 <0.1 NS NS
6/12/2013 mg/L NS .384 J NS <0.1 <0.1 <0.1 NS NS
10/28/2013 mg/L NS .333 J NS <0.1 <0.1 <0.1 <0.1 <0.1
5/6/2014 mg/L NS .282 J NS <0.1 <0.1 <0.1 <0.1 <0.1
10/23/2014 mg/L NS * <0.1 <0.1 <0.1 <0.1 NS NS
5/21/2015 mg/L NS <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
12/8/2016 mg/L NS NS .256 J <0.1 <0.1 <0.1 NS NS
Alkalinity 11/3/2006 mg/L NS NS NS 47 36 106 NI NI
6/3/2009 mg/L 163 NS NS 112 62.5 76.6 80.8 128
11/17/2009 mg/L 70.8 NS NS 121 50.0 83.3 81.2 115
6/16/2010 mg/L 61.2 NS NS 154 59.1 111 74.7 185
12/1/2010 mg/L 35.2 NU NS 156 86.9 64.4 NS NS
6/1/2011 mg/L 45.1 NU NS 177 70.7 109 84.6 132
12/20/2011 mg/L NS 8.58 NS 189 70.8 77.2 NS NS
5/30/2012 mg/L NS 8.14 NS 200 76.7 104 107.0 150.0
12/5/2012 mg/L NS 7.69 NS 178 76.6 106 NS NS
6/12/2013 mg/L NS 7.95 NS 202 111 99.7 NS NS
10/28/2013 mg/L NS 8.14 NS 197 91.3 116 NS NS
5/6/2014 mg/L NS 8.06 NS 208 90.6 119 68.90 113.0
10/23/2014 mg/L NS * 1.36 J 215 96.1 122 NS NS
5/21/2015 mg/L NS 6.54 ND 153.000 67.500 92.100 51.300 154.000
12/8/2015 mg/L NS 8.280 1.030 J 202.000 88.800 95.900 NS NS
Chloride 11/3/2006 mg/L NS NS NS 9.30 1.69 2.49 NI NI
6/3/2009 mg/L <5.0 NS NS 16.1 <5.0 6.7 5.9 <5.0
11/17/2009 mg/L <5.0 NS NS 16.8 <5.0 <5.0 6.8 <5.0
6/16/2010 mg/L <5.0 NS NS 5.45 6.29 8.55 8.23 <5.0
12/1/2010 mg/L <5.0 NU NS 15.1 6.84 <5.0 NS NS
6/1/2011 mg/L <5.0 NU NS 17.0 6.33 7.87 9.45 <5.0
12/20/2011 mg/L NS <5.0 NS 20.2 6.40 6.53 NS NS
5/30/2012 mg/L NS 1.48 NS 20.0 6.32 5.84 133.0 2.79
12/5/2012 mg/L NS 2.13 NS 19.5 7.29 7.43 NS NS
6/12/2013 mg/L NS 1.38 NS 19.5 7.50 5.1 NS NS
10/28/2013 mg/L NS 1.12 NS 18.1 7.75 8.49 NS NS
5/6/2014 mg/L NS ND NS 18.2 8.14 8.92 13.50 2.41
10/23/2014 mg/L NS * ND 20.8 9.05 8.12 NS NS
5/21/2015 mg/L NS 1.550 ND 25.300 9.680 10.400 12.400 2.500
12/8/2015 mg/L NS 1.840 0.859 J 30.800 9.400 4.190 NS NS
Sulfate 11/3/2006 mg/L NS NS NS 3.72 <2 <2 NI NI
6/3/2009 mg/L <5.1 NS NS <5.0 <5.0 <5.0 5.8 ND
11/17/2009 mg/L <5.0 NS NS <5.0 <5.0 <5.0 <5.0 <5.0
6/16/2010 mg/L <5.0 NS NS <5.0 <5.0 <5.0 <5.0 <5.0
12/1/2010 mg/L <2.5 NU NS <12.5 <12.5 <12.5 NS NS
6/1/2011 mg/L <5.0 NU NS <5.0 <5.0 <5.0 <5.0 <5.0
12/20/2011 mg/L NS <5.0 NS <5.0 <5.0 <5.0 NS NS
5/30/2012 mg/L NS <5.0 NS <5.0 <5.0 <5.0 <5.0 <5.0
12/5/2012 mg/L NS ND NS ND 4.4 J ND NS NS
6/12/2013 mg/L NS ND NS 3.08 J 2.91 J ND NS NS
10/28/2013 mg/L NS ND NS ND 2.94 J ND NS NS
5/6/2014 mg/L NS ND NS 2.30 J 3.72 J 2.07 J ND 2.49 J
10/23/2014 mg/L NS * ND 2.28 J 3.74 J 1.94 J NS NS
5/21/2015 mg/L NS ND ND 2.310 J 3.440 J 2.750 J 1.700 J 1.980 J
12/8/2015 mg/L NS ND ND 1.530 J 2.020 J 9.260 J NS NS
Burke County John's River C and D over MSW Landfill
Permit No. 12-03 Page 3 of 8
Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
Sulfide 11/3/2006 mg/L NS NS NS 3.72 <2 <2 NI NI
6/3/2009 mg/L <0.10 NS NS <0.10 <0.10 <0.10 <0.10 ND
11/17/2009 mg/L <0.10 NS NS <0.10 <0.10 <0.10 NS NS
6/16/2010 mg/L <0.10 NS NS <0.10 <0.10 <0.10 <0.10 <0.10
12/1/2010 mg/L <0.10 NU NS <0.10 <0.10 <0.10 NS NS
6/1/2011 mg/L NS NU NS NS NS NS NS NS
12/20/2011 mg/L NS NS NS NS NS NS NS NS
5/30/2012 mg/L NS NS NS NS NS NS NS NS
12/5/2012 mg/L NS ND NS ND ND ND NS NS
6/12/2013 mg/L NS ND NS ND ND ND NS NS
10/28/2013 mg/L NS ND NS ND ND ND ND ND
5/6/2014 mg/L NS NS NS NS NS NS NS NS
10/23/2014 mg/L NS * ND ND ND ND NS NS
5/21/2015 mg/L NS NS NS NS NS NS NS NS
12/8/2015 mg/L NS NS ND ND ND ND NS NS
Methane 11/3/2006 mg/L NS NS NS 2.23 2.50 2.92 NI NI
6/3/2009 mg/L 0.340 NS NS 0.111 8.61 8.26 0.494 0.814
11/17/2009 mg/L 2.580 NS NS 4.310 0.147 10.300 1.200 0.271
Resample 1/19/2010 mg/L NS NS NS NS 2.120 NS NS NS
6/16/2010 mg/L 0.750 NS NS 4.600 6.000 6.200 1.000 1.100
12/1/2010 mg/L 1.35 NU NS 3.04 6.0 6.65 NS NS
6/1/2011 mg/L 2.1 NU NS 0.157 0.0128 <0.010 0.899 2.64
12/20/2011 mg/L NS <0.005 NS 1.460 6.300 5.650 NS NS
5/30/2012 mg/L NS 0.0061 NS 0.883 6.130 3.760 0.46 0.718
12/5/2012 mg/L NS ND NS 2.070 2.050 4.910 NS NS
6/12/2013 mg/L NS 0.0063 NS 0.964 8.900 11.400 NS NS
10/28/2013 mg/L NS ND NS .0033 J 2.610 0.173 0.0581 0.0085
5/6/2014 mg/L NS ND NS 2.040 6.190 4.360 0.3850 1.5900
10/23/2014 mg/L NS * 5.93 2.21 ND 5.61 NS NS
5/21/2015 mg/L NS 0.0018 J 0.0012 J 2.270 6.700 4.940 0.136 3.060
12/8/2015 mg/L NS NS 2.0 J 0.959 0.796 7.510 NS NS
Ethane 11/3/2006 mg/L NS NS NS <0.002 <0.002 <0.002 NI NI
6/3/2009 mg/L <0.005 NS NS <0.005 <0.005 <0.005 <0.005 <0.005
11/17/2009 mg/L <0.005 NS NS <0.005 <0.005 <0.005 <0.005 <0.005
Resample 1/19/2010 mg/L NS NS NS NS <0.005 NS NS NS
6/16/2010 mg/L <0.013 NS NS <0.013 <0.011 <0.011 <0.013 <0.013
12/1/2010 mg/L <0.0022 NU NS <0.0022 <0.0022 <0.0022 NS NS
6/1/2011 mg/L NS NU NS NS NS NS NS NS
12/20/2011 mg/L NS NS NS NS NS NS NS NS
5/30/2012 mg/L NS NS NS NS NS NS NS NS
12/5/2012 mg/L NS NS NS NS NS NS NS NS
6/12/2013 mg/L NS ND NS ND ND ND NS NS
10/28/2013 mg/L NS ND NS .0016 J ND ND ND ND
5/6/2014 mg/L NS NS NS NS NS NS NS NS
10/23/2014 mg/L NS * NS NS NS NS NS NS
5/21/2015 mg/L NS NS NS NS NS NS NS NS
12/8/2016 mg/L NS NS NS NS NS NS NS NS
Ethylene (Ethene) 11/3/2006 mg/L NS NS NS <0.002 <0.002 <0.002 NI NI
6/3/2009 mg/L <0.005 NS NS <0.005 <0.005 <0.005 <0.005 <0.005
11/17/2009 mg/L <0.005 NS NS <0.005 <0.005 <0.005 <0.005 <0.005
Resample 1/19/2010 mg/L NS NS NS NS <0.005 NS NS NS
6/16/2010 mg/L <0.013 NS NS <0.013 <0.011 <0.011 <0.013 <0.013
12/1/2010 mg/L <0.0018 NU NS <0.0018 <0.0018 <0.0018 NS NS
6/1/2011 mg/L NS NU NS NS NS NS NS NS
12/20/2011 mg/L NS NS NS NS NS NS NS NS
5/30/2012 mg/L NS NS NS NS NS NS NS NS
12/5/2012 mg/L NS NS NS NS NS NS NS NS
6/12/2013 mg/L NS ND NS ND ND ND NS NS
10/28/2013 mg/L NS ND NS .0017 J ND ND ND ND
5/6/2014 mg/L NS NS NS NS NS NS NS NS
10/23/2014 mg/L NS * NS NS NS NS NS NS
5/21/2015 mg/L NS NS NS NS NS NS NS NS
12/8/2015 mg/L NS NS NS NS NS NS NS NS
Burke County John's River C and D over MSW Landfill
Permit No. 12-03 Page 4 of 8
Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
Dissolved Hydrogen 11/3/2006 nM NS NS NS NS NS NS NI NI
6/3/2009 nM 0.480 J NS NS 0.720 <0.600 0.350 J 0.580 J 0.790
11/17/2009 nM 0.780 NS NS 0.850 0.690 1.000 1.200 0.630
6/16/2010 nM 4.800 NS NS 3.400 2.800 2.200 2.800 3.300
12/1/2010 nM 1.500 NU NS 0.850 0.740 0.950 NS NS
6/1/2011 nM 2.300 NU NS 2.400 1.900 2.200 2.100 2.000
12/20/2011 nM NS 21 NS 19 6.3 7.0 NS NS
5/30/2012 nM NS 0.74 NS 2.0 1.1 0.84 0.79 0.76
12/5/2012 nM NS 1.7 NS 0.5 J 0.35 J 0.57 J NS NS
6/12/2013 nM NS 1.1 NS 1.1 0.83 1.60 NS NS
10/28/2013 nM NS 0.61 NS 0.61 0.55 J 0.52 J 0.56 J 0.68
5/6/2014 nM NS 0.61 NS 0.82 1.1 J 1.1 J 0.61 3.50
10/23/2014 nM NS * 0.75 0.86 0.85 1.2 NS NS
5/21/2015 nM NS NS 1.7 1.3 1.1 1.6 1.6 1.2
12/8/2016 nM NS NS 2.0 1.6 2.3 1.9 NS NS
Volatile Fatty Acids 11/3/2006 mg/L NS NS NS NS NS NS NI NI
6/3/2009 mg/L 10.9 NS NS 0.5 J ND ND ND ND
11/17/2009 mg/L 0.9 J NS NS ND 0.6 J ND 0.9 J ND
6/16/2010 mg/L ND NS NS 32.0 ND 1.3 0.8 J 5.2
12/1/2010 mg/L ND NU NS ND ND 6.4 J NS NS
6/1/2011 mg/L NS NU NS NS NS NS NS NS
12/20/2011 mg/L NS NS NS NS NS NS NS NS
5/30/2012 mg/L NS NS NS NS NS NS NS NS
12/5/2012 mg/L NS NS NS NS NS NS NS NS
6/12/2013 mg/L NS ND NS ND ND ND NS NS
10/28/2013 mg/L NS ND NS ND ND ND ND ND
5/6/2014 mg/L NS NS NS NS NS NS NS NS
10/23/2014 mg/L NS * NS NS NS NS NS NS
5/21/2015 mg/L NS NS NS NS NS NS NS NS
12/8/2015 mg/L NS NS NS NS NS NS NS NS
TOC 11/3/2006 mg/L NS NS NS NS NS NS NI NI
6/3/2009 mg/L 9.4 NS NS 11.1 10.1 17.8 8.6 14.2
11/17/2009 mg/L 2.1 NS NS 13.1 12.6 14.6 3.9 11.4
6/16/2010 mg/L 24.9 NS NS 12.9 8.66 11.1 6.4 16.8
12/1/2010 mg/L 17.6 NU NS 29.3 23.4 43.8 NS NS
6/1/2011 mg/L NS NU NS NS NS NS NS NS
12/20/2011 mg/L NS 6.53 NS 13.6 12.2 16.1 NS NS
5/30/2012 mg/L NS 6.49 NS 12.5 12.1 14.5 6.55 10.90
12/5/2012 mg/L NS ND NS 13.1 13.1 16.0 NS NS
6/12/2013 mg/L NS ND NS 13.3 12.9 18.3 NS NS
10/28/2013 mg/L NS ND NS 15.3 12.9 15.2 7.5 14.7
5/6/2014 mg/L NS ND NS 17.6 12.0 19.9 9.54 11.3
10/23/2014 mg/L NS * 27.0 35.7 66.4 33.2 NS NS
5/21/2015 mg/L NS ND ND 4.410 4.580 3.880 2.530 8.580
12/8/2016 mg/L NS ND ND 5.320 -- 6.070 NS NS
Tetrachloroethene (PCE) 11/3/2006 µg/L ND NS NS ND ND ND NI NI
6/3/2009 µg/L 2.1 NS NS ND 0.70 J ND ND ND
11/17/2009 µg/L 2.6 NS NS ND 0.49 J ND ND ND
6/16/2010 µg/L 1.2 NS NS ND 0.46 J ND ND ND
12/1/2010 µg/L 3.0 NU NS ND ND ND NS NS
6/1/2011 µg/L 3.6 NU NS ND ND ND ND ND
12/20/2011 µg/L NS ND NS 0.59 J 0.70 J ND NS NS
5/30/2012 µg/L NS ND NS ND ND ND ND ND
12/5/2012 µg/L NS ND NS ND ND ND NS NS
6/12/2013 µg/L NS ND NS ND ND ND NS NS
10/28/2013 µg/L NS ND NS ND ND ND ND ND
5/6/2014 µg/L NS ND NS ND ND ND ND ND
10/23/2014 µg/L NS * ND ND ND ND NS NS
5/21/2015 µg/L NS ND ND ND ND ND ND ND
12/8/2016 µg/L NS ND ND ND ND ND NS NS
Burke County John's River C and D over MSW Landfill
Permit No. 12-03 Page 5 of 8
Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
Trichloroethene (TCE) 11/3/2006 µg/L ND NS NS ND ND ND NI NI
6/3/2009 µg/L 1.8 NS NS 3.6 4.3 1.4 ND ND
11/17/2009 µg/L 1.9 NS NS 3.3 3.3 1.2 ND ND
6/16/2010 µg/L 0.61 J NS NS 5.1 3.3 1.4 ND ND
12/1/2010 µg/L 1.9 NU NS 3.7 3.3 ND NS NS
6/1/2011 µg/L 2.0 NU NS 2.8 3.2 ND ND ND
12/20/2011 µg/L NS ND NS 2.5 3.5 1.1 NS NS
5/30/2012 µg/L NS ND NS 2.5 2.6 0.55 J ND ND
12/5/2012 µg/L NS ND NS 2.3 3.3 0.67 J NS NS
6/12/2013 µg/L NS ND NS 2.1 1.8 0.76 J NS NS
10/28/2013 µg/L NS ND NS 3.1 2.5 0.76 J ND ND
5/6/2014 µg/L NS ND NS 2.0 2.6 0.60 J ND ND
10/23/2014 µg/L NS * ND 1.3 2.2 0.86 J NS NS
5/21/2015 µg/L NS ND ND 0.9 J 2.3 ND ND ND
12/8/2016 µg/L NS ND ND 0.71 J 1.4 ND NS NS
1,2-Dichloroethene (Total) 11/3/2006 µg/L ND NS NS 16 12 17 NI NI
6/3/2009 µg/L 0.71 J NS NS 13.3 12.1 10.6 3.9 J ND
11/17/2009 µg/L 2.8 J NS NS 12.5 20.3 11.1 NS NS
6/16/2010 µg/L 1.7 J NS NS 14.9 15.6 9.9 4.5 J ND
12/1/2010 µg/L 0.66 J NU NS 11.5 9.3 7.4 NS NS
6/1/2011 µg/L 0.66 J NU NS 14.6 13.9 5.7 4.6 J ND
12/20/2011 µg/L NS ND NS 9.7 9.8 6.6 NS NS
5/30/2012 µg/L NS ND NS 11.8 11.2 6.8 ND ND
12/5/2012 µg/L NS ND NS 9.1 10.07 6.6 NS NS
6/12/2013 µg/L NS ND NS 9.0 12.8 6.2 NS NS
10/28/2013 µg/L NS ND NS 11.2 14.0 7.7 NS NS
5/6/2014 µg/L NS ND NS 9.5 13.0 7.7 NS NS
10/23/2014 µg/L NS * ND 8.0 10.1 7.1 NS NS
5/21/2015 µg/L NS ND ND 6.7 7.6 4.2 NS NS
12/8/2015 µg/L NS ND ND 0.65 J ND 1.3 NS NS
cis-1,2-Dichloroethene 11/3/2006 µg/L ND NS NS 16 12 17 NI NI
6/3/2009 µg/L 0.71 J NS NS 13.1 11.9 10.4 3.9 J ND
11/17/2009 µg/L 2.8 J NS NS 12.2 20.0 10.8 5.7 ND
6/16/2010 µg/L 1.7 J NS NS 14.8 15.6 9.7 4.5 J ND
12/1/2010 µg/L 0.66 J NU NS 11.3 9.2 7.1 NS NS
6/1/2011 µg/L 0.66 J NU NS 14.5 13.8 5.7 4.6 J ND
12/20/2011 µg/L NS ND NS 9.5 9.7 6.5 NS NS
5/30/2012 µg/L NS ND NS 11.8 11.2 6.8 ND ND
12/5/2012 µg/L NS ND NS 9.1 9.4 6.6 NS NS
6/12/2013 µg/L NS ND NS 9.0 12.8 6.2 NS NS
10/28/2013 µg/L NS ND NS 11.2 14.0 7.7 NS NS
5/6/2014 µg/L NS ND NS 9.5 13.0 7.7 NS NS
10/23/2014 µg/L NS * ND 8.0 10.1 7.1 NS NS
5/21/2015 µg/L NS ND ND 6.7 7.6 4.2 NS NS
12/8/2015 µg/L NS ND ND 6.9 9.9 4.4 J NS NS
Vinyl Chloride 11/3/2006 µg/L ND NS NS ND ND ND NI NI
6/3/2009 µg/L ND NS NS ND 0.95 J 2.0 ND ND
11/17/2009 µg/L 0.69 J NS NS 0.66 J 1.6 2.5 ND ND
6/16/2010 µg/L ND NS NS ND 1.1 2.1 ND ND
12/1/2010 µg/L ND NU NS 0.65 J 0.93 J 3.5 NS NS
6/1/2011 µg/L ND NU NS 0.87 J 1.1 1.8 ND ND
12/20/2011 µg/L NS ND NS 0.63 J ND 1.4 NS NS
5/30/2012 µg/L NS ND NS ND ND 1.6 ND ND
12/5/2012 µg/L NS ND NS ND ND ND NS NS
6/12/2013 µg/L NS ND NS ND 0.96 J 2.10 NS NS
10/28/2013 µg/L NS ND NS ND 0.74 J 1.3 ND ND
5/6/2014 µg/L NS ND NS ND 0.77 J 1.8 ND ND
10/23/2014 µg/L NS * ND ND ND 1.3 NS NS
5/21/2015 µg/L NS ND ND ND ND 1.1 ND ND
12/8/2015 µg/L NS 0.72 J ND ND ND 1.4 NS NS
Burke County John's River C and D over MSW Landfill
Permit No. 12-03 Page 6 of 8
Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
1,1,1-Trichloroethane 11/3/2006 µg/L ND NS NS ND ND ND NI NI
6/3/2009 µg/L ND NS NS ND ND ND ND ND
11/17/2009 µg/L ND NS NS ND ND ND ND ND
6/16/2010 µg/L ND NS NS ND ND ND ND ND
12/1/2010 µg/L ND NU NS ND ND ND NS NS
6/1/2011 µg/L ND NU NS ND ND ND ND ND
12/20/2011 µg/L NS ND NS ND ND ND NS NS
5/30/2012 µg/L NS ND NS ND ND ND ND ND
12/5/2012 µg/L NS ND NS ND ND ND NS NS
6/12/2013 µg/L NS ND NS ND ND ND NS NS
10/28/2013 µg/L NS ND NS ND ND ND NS NS
5/6/2014 µg/L NS ND NS ND ND ND NS NS
10/23/2014 µg/L NS * ND ND ND ND NS NS
5/21/2015 µg/L NS ND ND ND ND ND NS NS
12/8/2015 µg/L NS ND ND ND ND ND NS NS
1,1-Dichloroethane 11/3/2006 µg/L ND NS NS 12 34 33 NI NI
6/3/2009 µg/L 6.3 NS NS 8.2 47.8 32.0 3.9 J 2.8 J
11/17/2009 µg/L 10.8 NS NS 6.7 41.9 29.4 6.7 3.7 J
6/16/2010 µg/L 3.9 J NS NS 5.7 35.7 32.1 4.4 J 2.3 J
12/1/2010 µg/L 6.8 NU NS 5.4 41.3 16.9 NS NS
6/1/2011 µg/L 9.3 NU NS 6.8 45.5 19.1 2.8 J 2.6 J
12/20/2011 µg/L NS ND NS 5.1 39.7 26.2 NS NS
5/30/2012 µg/L NS ND NS 5.9 38.2 24.1 1.6 J 2.7 J
12/5/2012 µg/L NS ND NS 4.6 J 39.3 26.5 NS NS
6/12/2013 µg/L NS ND NS 5.3 37.1 21.4 NS NS
10/28/2013 µg/L NS ND NS 4.6 J 43.2 26.2 0.93 J 3.0 J
5/6/2014 µg/L NS ND NS 4.0 J 43.4 21.5 1.2 J 2.9 J
10/23/2014 µg/L NS * ND 3.6 J 34.4 25.3 NS NS
5/21/2015 µg/L NS ND ND 2.8 J 26.7 17.3 ND 1.7 J
12/8/2015 µg/L NS ND ND 3.2 J 31.7 10.3 NS NS
Chloroethane 11/3/2006 µg/L ND NS NS ND ND ND NI NI
6/3/2009 µg/L 1.1 J NS NS ND ND 4.4 J 4.3 J ND
11/17/2009 µg/L 3.1 J NS NS 0.63 J 5.5 J 3.5 J 2.9 J 0.90 J
6/16/2010 µg/L 1.7 J NS NS 0.88 J 3.1 J 2.2 J 2.6 J 0.80 J
12/1/2010 µg/L ND NU NS ND ND ND NS NS
6/1/2011 µg/L 1.5 J NU NS ND 2.7 J ND 3.6 J 0.85 J
12/20/2011 µg/L NS ND NS ND 2.1 J 2.9 J NS NS
5/30/2012 µg/L NS ND NS ND 1.5 J ND ND ND
12/5/2012 µg/L NS ND NS ND 1.8 J 1.9 J NS NS
6/12/2013 µg/L NS ND NS ND 0.63 J 1.5 J NS NS
10/28/2013 µg/L NS ND NS ND 1.9 J ND NS NS
5/6/2014 µg/L NS ND NS ND 1.6 J 1.3 J NS NS
10/23/2014 µg/L NS * ND ND ND 1.6 J NS NS
5/21/2015 µg/L NS ND ND ND ND 1.6 J NS NS
12/8/2015 µg/L NS ND ND ND ND ND NS NS
Chloroform 11/3/2006 µg/L ND NS NS ND ND ND NI NI
6/3/2009 µg/L ND NS NS ND ND ND ND ND
11/17/2009 µg/L ND NS NS ND ND ND ND ND
6/16/2010 µg/L ND NS NS ND ND ND ND ND
12/1/2010 µg/L ND NU NS ND ND ND NS NS
6/1/2011 µg/L ND NU NS ND ND ND ND ND
12/20/2011 µg/L NS ND NS ND ND ND NS NS
5/30/2012 µg/L NS ND NS ND ND ND ND ND
12/5/2012 µg/L NS ND NS ND ND ND NS NS
6/12/2013 µg/L NS ND NS ND ND ND NS NS
10/28/2013 µg/L NS ND NS ND ND ND NS NS
5/6/2014 µg/L NS ND NS ND ND ND NS NS
10/23/2014 µg/L NS * ND ND ND ND NS NS
5/21/2015 µg/L NS ND ND ND ND ND NS NS
12/8/2015 µg/L NS ND ND ND ND ND NS NS
Burke County John's River C and D over MSW Landfill
Permit No. 12-03 Page 7 of 8
Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
Methylene Chloride 11/3/2006 µg/L ND NS NS ND ND ND NI NI
6/3/2009 µg/L ND NS NS ND ND ND ND ND
11/17/2009 µg/L 11.1 NS NS ND ND ND ND ND
6/16/2010 µg/L ND NS NS ND ND ND ND ND
12/1/2010 µg/L 2.2 NU NS ND ND ND NS NS
6/1/2011 µg/L 2.3 NU NS ND ND ND ND ND
12/20/2011 µg/L NS ND NS ND ND ND NS NS
5/30/2012 µg/L NS ND NS ND ND ND ND ND
12/5/2012 µg/L NS ND NS ND ND ND NS NS
6/12/2013 µg/L NS ND NS ND ND ND NS NS
10/28/2013 µg/L NS ND NS ND ND ND ND ND
5/6/2014 µg/L NS ND NS ND ND ND ND ND
10/23/2014 µg/L NS * ND ND ND ND NS NS
5/21/2015 µg/L NS ND ND ND ND ND ND ND
12/8/2015 µg/L NS ND ND ND ND ND NS NS
Notes:
(FP) = Field Parameter
ND = Not Detected
NS = Not Sampled
mV = millivolts
S.U. = standard units
oC = degrees Celcius
mS/cm = microsiemens per centimeter
mg/L = milligrams per liter (parts per million)
µg/L = micrograms per liter (parts per billion)
NU = Not Used as background data until approved
* MW-21 replaced MW-20 as the background well starting with the Fall 2014 sampling event; however MW-20 continues to be sampled as a compliance well
for the C&D Expansion (Phase 1A).
May 20, 2015: Shaded dissolved oxygen results are suspect. The DO Sensor began reading very low, re-calibration attempts did not appear to correct the issue.
A short in the DO probe was diagnosed after the field event.
-- MW-12 TOC sample for 12/08/15 was broken in transit to the laboratory and could not be analyzed.
Burke County John's River C and D over MSW Landfill
Permit No. 12-03 Page 8 of 8
Joyce Engineering

Appendix I

Biochlor Modeling Input & Output

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RA
T
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Displayed Compound
(m
g
/
d
a
y
)
Ti
m
e
:
17

y
r

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a
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t

L
e
v
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l
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0.
0
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5
mg
/
L

D
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s
p
l
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d

M
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l
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Bi
o
t
r
a
n
s
f
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m
a
t
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n

P
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a
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c
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-
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/
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0.6 (Kg)

M
a
s
s

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m
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v
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d

2.4 (Kg)
%
B
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o
t
r
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s
f
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m
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d

=
+80.8%
 %

C
h
a
n
g
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i
n

M
a
s
s

R
a
t
e

=

99.5 %
C
u
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V
o
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o
f

G
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m
p
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#
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Return to Input
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D
a
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a
Plo
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D
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T
a
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H
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Ga
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Show No Show
To

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17

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-
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a
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s

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f

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M
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m
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v
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d

3.7 (Kg)
%
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t
r
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s
f
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m
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d

=
+73.0%
 %

C
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M
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s

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=

98.2 %
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g
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Ti
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17

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t

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0.
0
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L

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p
l
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d

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l
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m
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-
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M
a
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M
a
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R
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m
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d

8.3 (Kg)
%
B
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t
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s
f
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m
e
d

=
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 %

C
h
a
n
g
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i
n

M
a
s
s

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=

92.3 %
C
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Return to Input
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A
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l

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a
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a
Plo
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D
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>

T
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