1203_BurkeCounty_GWMReport_DIN26407_20160204

PREPARED FOR:
BOARD OF COMMISSIONERS
COUNTY OF BURKE
P.O. BOX 1486
MORGANTON, NORTH CAROLINA 28680

JOHN’S RIVER WASTE MANAGEMENT FACILITY
PERMIT NO. 12-03
C&D EXPANSION - PHASE 1A

SECOND SEMIANNUAL WATER QUALITY MONITORING
REPORT OF 2015

APRIL 2016

PREPARED BY:

2211 WEST MEADOWVIEW ROAD, SUITE 101
GREENSBORO, NORTH CAROLINA 27407
NC LICENSE NUMBER C-0782
PHONE: [phone]
FAX: [phone]
JOYCE PROJECT NO. 277.1501.12

2nd Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering
Burke County – John’s River Landfill, Phase 1A, Permit No. 12-03 April 2016
i

Second Semiannual Water Quality Monitoring Report of 2015
John’s River Waste Management Facility – Permit No. 12-03
C&D Expansion - Phase 1A
Burke County, North Carolina

TABLE OF CONTENTS

1.0 INTRODUCTION..............................................................................................................1 
1.1 Site Information ........................................................................................................................1 
1.2 Site Geology .............................................................................................................................1 
1.3 Regulatory Status .....................................................................................................................2 
2.0 FACILITY MONITORING PROGRAM .......................................................................2 
2.1 Groundwater Monitoring Program ...........................................................................................2 
2.2 Surface Water Monitoring Program .........................................................................................3 
3.0 SECOND SEMIANNUAL SAMPLING EVENT OF 2015 ............................................4 
3.1 Field Work ................................................................................................................................4 
3.2 Laboratory Analysis and JOYCE Quality Control ...................................................................5 
4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSIS .....................................5 
4.1 Analytical Results for Inorganic Constituents ..........................................................................6 
4.2 Analytical Results for Organic Constituents ............................................................................6 
4.3 Statistical Analyses ...................................................................................................................6 
4.3.1 Statistical Methods and Background .................................................................................. 6 
4.3.2 Inorganic Constituents ........................................................................................................ 7 
4.4 Analytical Results for Surface Water .......................................................................................7 
5.0 HYDROGEOLOGICAL CONDITIONS ........................................................................8 
6.0 CONCLUSION ..................................................................................................................9 
7.0 REFERENCES ...................................................................................................................9 
9.0 ACRONYMS ....................................................................................................................11 

2nd Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering
Burke County – John’s River Landfill, Phase 1A, Permit No. 12-03 April 2016
ii

Second Semiannual Water Quality Monitoring Report of 2015
John’s River Waste Management Facility – Permit No. 12-03
C&D Expansion - Phase 1A
Burke County, North Carolina

TABLE OF CONTENTS (CONTINUED)

Tables:
Table 1 Historical Groundwater Elevation Data Table 2 Field Parameters
Table 3 Quantified Detections of Groundwater Constituents (December 2015)
Table 4 Exceedances of Groundwater Standards (December 2015) Table 5 Quantified Detections in Additional Wells/Piezometers (December 2015)
Table 6 Exceedances in Additional Wells/Piezometers (December 2015)
Table 7 Statistical Background Analyses Table 8 Hydraulic Gradients and Groundwater Flow Velocities

Figure:
Figure 1 Site Location Map

Drawing:
Drawing 1 Groundwater Surface Map

Appendices:
Appendix A Field Data Logs
Appendix B Laboratory Analytical Reports
Appendix C Statistical Analyses Worksheets
Appendix D Historical Detected Groundwater Constituents
Appendix E Historical Detected Constituents in Additional Wells/ Piezometers
Appendix F Historical Detected Surface Water Constituents

2nd Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering
Burke County – John’s River Landfill, Phase 1A, Permit No. 12-03 April 2016
1
1.0 INTRODUCTION
1.1 Site Information
The Johns River Waste Management Facility (JRWMF) is located in the north-central portion of
Burke County, north of Morganton, North Carolina. The 318-acre landfill property is bounded
by Lower Creek to the north and east, and the Catawba River to the south. The Catawba River
forms Lake Rhodhiss along the southeastern property line (Figure 1). Lake Rhodhiss is a long,
narrow lake formed by the Rhodhiss Hydroelectric Dam located approximately 12 miles
downstream of the landfill. The John’s River flows into the Catawba River near the southwest
corner of the landfill property. A MSW transfer facility is located in the eastern half of the
property. A site plan showing all the pertinent features of the facility is provided in Drawing 1.

The site has rolling topography with elevations ranging from 975 feet to 1,150 feet above mean
sea level (MSL). The central portion is generally gently sloping and contains the higher
elevations; relatively steep slopes and significant drainage features are located around the
perimeter. The 100-year flood boundary extends onto the landfill property. The adjacent
property to the west of the Johns River Waste Management Facility consists of undeveloped,
heavily wooded land. Properties within 2,000 feet of the landfill boundary are covered by
surface water or are heavily wooded.

The C&D over MSW waste disposal unit consists of 28 acres in the southwest corner of the
landfill property. The municipal solid waste (MSW) landfill began operation in April 1988, but
was closed in 1997 to comply with Rule .1627(c)(10)(A) of the NCSWMR, a regulation
governing MSW Landfills units that were not designed with a base liner and leachate collection
system. Burke County has operated a permitted Construction and Demolition (C&D) disposal
area on top of the closed portions of the MSW landfill since 1998. The results of the second
semiannual sampling event for the old C&D over MSW landfill will be presented in a separate
report.

A Permit to Construct for Phase 1A was issued in March 2014 and Burke County completed
construction of Phase 1A of the C&D landfill expansion in July 2014. A Permit to Operate for
Phase 1A was issued by the North Carolina Department of Environment and Natural Resources
(DENR) on August 14, 2014. In accordance with the approved Water Quality Monitoring Plan
(WQMP) for the facility (dated August 2012), there are four groundwater monitoring wells
designated as compliance wells for Phase 1A: MW-21(background), MW-20, MW-22S, and
MW-38.

1.2 Site Geology
The John’s River Waste Management Facility is in close proximity to the Brevard Shear Zone,
and is underlain by highly metamorphosed rocks including gneiss, schist, as well as calc-silicate
rocks, felsic rocks, and metavolcanic rocks. The dominant rock type at the facility is biotite-
muscovite schist, as seen in outcrops, boulders, and rock cores located on site. The structures
within limited outcrops indicate that these rocks are complexly-folded, with attitudes that vary

2nd Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering
Burke County – John’s River Landfill, Phase 1A, Permit No. 12-03 April 2016
2
from vertical to horizontal in most outcrops. The site regolith is typical of the inner piedmont
and consists mostly of silty sand, clayey sand, and sandy silt. The regolith is up to 100 feet thick
and varies in thickness with topography.

An abundance of rounded gravel, cobble, and boulder-sized alluvial deposits are exposed along
the banks of the Catawba River, which borders the site. The greatest accumulation of these
deposits is along the southwestern site boundary. These river deposits are 40 feet or more above
the current river elevation and have been described as ancient river terrace deposits.

1.3 Regulatory Status
The following report of groundwater monitoring data from the JRWMF Phase 1A C&D
expansion has been prepared in accordance with the North Carolina Solid Waste Management
Rules (NCSWMR) 15A NCAC 13B §.0544 (Monitoring Plans and Requirements for C&D
Landfill Facilities). The Phase 1A expansion is currently operating under the Detection
Monitoring Program.

2.0 FACILITY MONITORING PROGRAM
2.1 Groundwater Monitoring Program
Groundwater monitoring at the JRWMF Phase 1A is performed in accordance with NCSWMR
§.0544. Groundwater samples are collected semiannually and analyzed for constituents
according to the approved Water Quality Monitoring Plan (WQMP) for the facility dated August
2012. Following is a summary of the compliance monitoring wells.

Well ID Date
Installed Classification Monitoring
Program
Total Depth
of Well (ft)
Lithology of
Screened
Interval
Constituent
List
MW-20 5-18-95 Compliance Detection 67.0 Saprolite Comp.
MW-21 5-18-95 Background Detection 45.0 Saprolite Comp.
MW-22s 6-1-96 Compliance Detection 25.0 Saprolite Comp.
MW-38 5-09-11 Compliance/
Performance* Detection 71.0 Bedrock Comp., LFG
Notes: Comp. = Compliance Parameters: NCSWMR Appendix I and/or Appendix II organics and inorganics
plus C&D parameters, as required for routine assessment or detection monitoring.
LFG = Landfill Gas Indicators: Dissolved CH4 and dissolved CO2.
*MW-38 is also a performance well for the C&D over MSW Landfill.

The current compliance groundwater monitoring network at the facility consists of one
upgradient well (MW-21), and three downgradient wells (MW-20, MW-22S and MW-38).

In January 2014, in response to the County’s permit application for the C&D expansion area, the
DENR requested that the County sample several additional wells and/or piezometers in the
vicinity of Phases 1 and 2 of the expansion. The County agreed to sample PZ-31, PZ-30S,

2nd Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering
Burke County – John’s River Landfill, Phase 1A, Permit No. 12-03 April 2016
3
PZ-34, MW-36(PZ-36), PZ-12, and MW-15S semiannually beginning with the spring 2014
sampling event. The County also agreed to sample the following other wells/piezometers in the
event of GPS exceedances, as follows:

 PZ-30D will be added in the event that there are GPS exceedances at PZ-30S;
 PZ-35 will be added in the event that there are GPS exceedances at PZ-34;
 MW-15D will be added in the event that there are GPS exceedances at MW-15S;
 PZ-16S will be added in the event that there are GPS exceedances at PZ-35 or PZ-12;
and
 PZ-16D will be added in the event that there are GPS exceedances at PZ-16S.
 PZ-34 was inadvertently destroyed during the spring of 2014; therefore, PZ-35 is now
sampled instead.

The additional piezometers/wells are to be sampled for the facility’s COCs (excluding alpha-
BHC). Sampling of the additional piezometers/wells will be conducted for two years (four
sampling events), after which the DENR will reevaluate the need for continued sampling of the
additional piezometers/wells.

2.2 Surface Water Monitoring Program
The current surface water monitoring points are SMP-5, SMP-6, and SMP-7. Surface water
monitoring point SMP-5 (located at the southwestern property line) and SMP-6 (located at the
southeastern property line) are both located downstream from existing sediment basins. Surface
water monitoring point SMP-7 is located downstream from the Phase 1A expansion area. The
surface water monitoring program is designed to monitor for possible impacts from both the
C&D over MSW Landfill and the Phase 1A C&D Landfill; surface water samples are analyzed
for the NCSWMR Appendix I list of constituents plus detected Appendix II constituents during
both semiannual events.

Surface Point Classification Monitoring
Program Location
SMP-5 Compliance Surface Water Creek on west side of landfill,
downstream of sediment basin.
SMP-6 Compliance Surface Water Creek on east side of landfill,
downstream of sediment basin.
SMP-7 Compliance Surface Water
Creek southeast of Phase 1A and
east of sediment basin SB-2A.
Downstream of PZ-12.

2nd Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering
Burke County – John’s River Landfill, Phase 1A, Permit No. 12-03 April 2016
4
3.0 SECOND SEMIANNUAL SAMPLING EVENT OF 2015
3.1 Field Work
In order to detect potential releases of leachate and/or landfill gas migration in a timely manner,
a visual inspection program has been implemented at the John’s River Waste Management
Facility. This inspection program involves field personnel making the following observations:
 Indications of stress on the biological community (e.g., dead or dying vegetation);
 Indications of leachate impact (e.g., seeps, impacted surface water);
 Observations of erosion;
 Condition of monitoring wells; and
 Negative changes around the waste facility.

On December 7-9, 2015, personnel from JOYCE visited John’s River Waste Management
Facility to purge and sample monitoring wells MW-20, MW-21, MW-22S, and MW-38.
Additional wells/piezometers MW-15S, PZ-12, PZ-30S, PZ-31, PZ-35, and PZ-36 were also
sampled. Surface monitoring points SMP-5, SMP-6, and SMP-7 were also sampled during the
December 2015 event. The usual inspections indicated no unusual issues or concerns.

Depth-to-water measurements were obtained to the nearest 0.01 foot using an electronic water
level indicator for all monitoring wells in the compliance network prior to purging. Table 1
presents current and historical groundwater elevation data. Monitoring wells were purged and
sampled using disposable bailers. Measurements of temperature, pH, specific conductivity, and
turbidity were recorded in the site log book as well as on field data logs prior to purging, after
each purge volume, and during sampling. Field data logs for the December 2015 event are
provided in Appendix A, and the field parameters are summarized in Table 2.

Laboratory-supplied containers were prepared and labeled (either by the laboratory or in the
field, as indicated) with the following information:
 Monitoring well number (completed by field personnel),
 Date and time of sample collection (completed by field personnel),
 Initials of sampling personnel (completed by field personnel),
 Project name and number (completed by the laboratory),
 Chemical preservative (completed by the laboratory); and
 Requested chemical analysis (completed by the laboratory).

Groundwater samples from each monitoring well were dispensed directly from the disposable
bailers into the provided laboratory containers either immediately after purging or within 24
hours of the final purge volume. Immediately after collection, the samples were placed in a
laboratory-provided cooler and chilled with ice.

Surface water samples were collected directly from stream flow by lowering the prepared sample
containers into the stream flow. Care was taken not the overflow the sample containers (which
could lead to preservative loss) and avoid sample-induced turbidity. At the time of sampling,
surface water was also measured for temperature, pH, specific conductivity, and turbidity and

2nd Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering
Burke County – John’s River Landfill, Phase 1A, Permit No. 12-03 April 2016
5
recorded in the site log book. After sample collection, the samples were placed in a laboratory
provided cooler and chilled on ice. Field data logs are provided in Appendix A, and the field
parameters are summarized in Table 2.

3.2 Laboratory Analysis and JOYCE Quality Control
The Second Semiannual (December 2015) groundwater and surface water samples were
submitted to Pace Analytical Services, Inc. of Huntersville, North Carolina under chain-of-
custody control for analysis. The groundwater samples were analyzed for the NC Appendix I list
of constituents, plus additional required C&D parameters. Surface water samples were analyzed
for the NC Appendix I list of constituents (plus detected Appendix II constituents form the old
C&D-over-MSW landfill) during both semiannual events. JOYCE requested a Level II data
report for the final laboratory report. The samples were received by the laboratory in good
condition, properly preserved, and within required hold times.

In addition to samples collected for compliance monitoring at the John’s River Waste
Management Facility, a Field Blank was collected by JOYCE personnel as part of the December
2015 sampling event. Also, a Trip Blank prepared by the laboratory accompanied the volatile
sampling containers from and to the laboratory. The Field Blank was analyzed for the NC
Appendix I, plus previously detected Appendix II list of constituents, plus iron, manganese and
tetrahydrofuran, and the Trip Blank was analyzed for Appendix I list of constituents plus
additional detected Appendix II volatile organic compounds and tetrahydrofuran.

Upon receipt of the laboratory data package, JOYCE personnel reviewed the data package for
quality assurance/quality control (QA/QC) purposes and for possible regulatory issues. If any
QA/QC or regulatory issues were found, the laboratory would be contacted to resolve the issue,
and a resampling event might be scheduled, if needed. The laboratory analytical packages can
be found in Appendix B of this report. The data package was reviewed for the following:
 General typographical errors;
 Correct analyses performed and within method specified hold times;
 Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate,
and Laboratory Control Samples;
 Blank-qualified data (B-flags);
 Detections exceeding the North Carolina 15A NCAC 2L .0202 Groundwater Standards
(NC2L), DENR-SWS Groundwater Water Protection Standards (GWPS), and North
Carolina 15A NCAC 2B Surface Water Standards (NC2B); and
 Detections that are above historical levels.

After the initial data review, a verification (resample) event for the metals in MW-22S was
performed on February 4, 2016.
4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSIS
The constituents with quantified detections above the SWSL in one or more compliance
monitoring wells are presented in Table 3 and the constituents with exceedances of the NC 2L

2nd Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering
Burke County – John’s River Landfill, Phase 1A, Permit No. 12-03 April 2016
6
Standards or GWPS in one or more compliance monitoring wells are presented in Table 4. The
constituents with quantified detections above the SWSL in one or more of the additional
wells/piezometers are presented in Table 5 and the constituents with exceedances of the NC 2L
Standards or GWPS in one or more additional wells/piezometers are presented in Table 6. The
complete laboratory reports and chains of custody are included in Appendix B. Historical data
are presented in Appendices D, E, and F.

4.1 Analytical Results for Inorganic Constituents
Eight inorganic constituents, were detected above the NC 2L/GWPS in one or more monitoring
wells during the December 2015 sampling event. Initial data review demonstrated that the metal
detections and concentrations reported in MW-22S were historically inconsistent and possibly
the result of higher turbidity in the sample at the time of collection; therefore a verification
sampling for metal constituents in MW-22S was conducted on February 4, 2016. The results of
the verification sampling event reported only thallium, iron, and manganese above their
respective NC 2L or GWPS. Thallium was not detected above the calculated background (see
Section 4.3.2). Iron and manganese were reported above the NC 2L Standards in MW-20,
MW-22S and MW-38, however; an ASD was approved for iron and manganese by DENR for
the John’s River facility on April 12, 2012. In general, the detections and concentrations are
consistent with historical data.

4.2 Analytical Results for Organic Constituents
Three organic constituents, benzene, 1,1-dichloroethane, and 1,4-dichlorobenzene, were detected
above the NC 2L Standards in compliance monitoring well MW-38 during the December 2015
sampling event. In addition, results from the additional wells/piezometers indicated NC 2L
exceedances of benzene and tetrachloroethylene in MW-15S, and of benzene,
1,4-dichlorobenzene, and tetrachloroethene in MW-36. (Methylene chloride detected in MW-36
was blank qualified by a detection in the Trip Blank.) No other exceedances were noted in any of
the other wells/piezometers.

The exceedances noted in MW-15S, MW-36, and MW-38 are believed to be due to landfill gas
migration from the C&D-over-MSW Landfill and are being addressed in the Corrective Action
Plan for that landfill. In general, the detections and concentrations are consistent with
historical data.

4.3 Statistical Analyses
4.3.1 Statistical Methods and Background
MW-9 was the facility background well from 1994 until May 2005, when it was abandoned.
MW-17 the facility background well from May 1999 until June 2011. Both MW-9 and MW-17
were sampled between May 1999 and May 2005. Due to gas related impacts to MW-17, MW-20
became the facility background well in December 2010. Both MW-17 and MW-20 were
sampled between December 2010 and June 2011. With the opening of Phase 1A of the C&D

2nd Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering
Burke County – John’s River Landfill, Phase 1A, Permit No. 12-03 April 2016
7
expansion in August 2014, MW-21 (formerly PZ-1) became the facility background well and
MW-20 became a compliance well for Phase 1A.

Facility background data used to evaluate the December 2015 groundwater monitoring data
include all data collected for wells MW-9, MW-17, and MW-20 from September 1994 through
the December 2015 event, plus the May 2015 results from MW-21.

The background data for inorganic constituents were evaluated using the Shapiro-Wilk Test,
Parametric Prediction Limits, Parametric Tolerance Intervals, Aitchison’s Adjustment, Non-
Parametric Prediction Limits, and/or Poisson Prediction Limits as appropriate. Background data,
tests for normality, outliers, Aitchison’s adjustment, tolerance interval, or prediction limits are
used, as appropriate based on the background data. The statistical test by which downgradient
data are compared to facility background data is based upon the nature of the data and the
number of data values that are less than the laboratory limit of detection. All statistical tests are
evaluated at the 0.05 level of significance, 95% confidence level, and are conducted as one-tailed
tests.

4.3.2 Inorganic Constituents
The inorganic constituents detected at quantifiable concentrations (excluding blank-qualified
data) above the North Carolina SWSL in down gradient monitoring wells in the December 2015
sampling event initially included arsenic, barium, beryllium, chromium, cobalt, iron, manganese,
thallium, vanadium, and zinc, primarily in MW-22S; however, since the detections in MW-22S
were historically unusual, a verification sample was collected for the metals on February 4, 2016.
The results of the verification sample were that only thallium, iron, and manganese
concentrations were detected above their respective NC 2L or SWS GWP Standard. Iron and
manganese were addressed in an ASD approved by DENR in April 2012. Details of the
statistical analyses of background data for thallium can be found in Appendix C. A summary of
the statistical analyses is given below and in Table 7.

Constituent Data
Distribution
Statistical Method used to Establish
Background
Background
Concentration
NC2L or
GWPS*
Thallium 92% ND Upper Poisson Prediction Limit 36.8 µg/L 0.28 µg/L*
ND = Not Detected (truncated data).

4.4 Analytical Results for Surface Water
There were no constituents detected at quantified concentrations or above the NC 2B Surface
Water Standards (NC2B) during the December 2015 event. In general, the December 2015
surface water results are consistent with the historical data. Current and historical surface water
data can be found in Appendix F.

2nd Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering
Burke County – John’s River Landfill, Phase 1A, Permit No. 12-03 April 2016
8
5.0 HYDROGEOLOGICAL CONDITIONS
Based on outcrop and drilling information, the water table appears to occur within regolith
everywhere across the site. This regolith consists of alluvium, residual soils, saprolite, and
variably fractured and weathered layered metamorphic rock. Inspection of drill cuttings and site
outcrops indicates that water in the regolith is transmitted largely through fractures. In this
regard, regolith behaves similar to unweathered bedrock, except that fractures are more
numerous and better connected in the regolith, and will tend to have more isotropic hydraulic
properties. Along the low-lying areas of the Catawba River and its tributaries, the water table
occurs within surficial alluvial deposits overlying the residual soils and weathered bedrock.

Groundwater discharges into creeks to the east and west of the landfill and to the Catawba River
to the south. A groundwater potentiometric surface map, developed from static water level data
obtained in December 2015, is presented as Drawing 1. The potentiometric surface map depicts
groundwater flow primarily to the south.

Depth to groundwater was measured in the compliance monitoring wells at the site prior to
sampling. The December 2015 and historical groundwater elevations are provided in Table 1.
The groundwater elevations were calculated relative to the surveyed measuring point (top of
casing) for each monitoring well. Horizontal groundwater gradients along representative flow
paths were estimated from the December 2015 groundwater contours shown on Drawing 1 and
are summarized in Table 8. Horizontal gradients across the site ranged from 0.0390 to 0.0546
ft/ft, with an average of approximately 0.0480 ft/ft. This is consistent with previous estimates.

Linear groundwater flow velocities for wells screened in saprolite were computed using the
modified Darcy equation: V = Ki/n, where V = average linear velocity, K = hydraulic
conductivity, i = horizontal hydraulic gradient, and n = effective porosity. The average of
hydraulic conductivities from slug-tests conducted at the facility (K = 3.28 ft/day) was used in
these calculations, along with an effective porosity of n = 0.40 (40%) based on laboratory
porosities for soil samples from the facility.

The estimated linear groundwater flow velocity under the facility ranged from 117-164 feet/year,
with an average flow velocity of approximately 144 feet/year (Table 8). Because of our
conservative estimate of effective porosity, actual groundwater velocities may be significantly
less than those calculated. Also, the modified Darcy equation makes the simplified assumptions
of a homogeneous and isotropic aquifer, which may yield inaccurate results when applied to
heterogeneous and/or anisotropic conditions such as are believed to exist at this site.

The groundwater flow direction and rate have shown no significant seasonal variations over
several years of monitoring. The groundwater flow regime on this site is well constrained and
predictable. Migration of groundwater contaminants are expected to follow the general
groundwater flow paths and there are no known preferred pathways or barriers to groundwater
flow that could significantly affect plume migration or the effectiveness of the groundwater
monitoring network to monitoring plume migration. The current groundwater monitoring
network remains sufficient for monitoring the groundwater at this facility

2nd Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering
Burke County – John’s River Landfill, Phase 1A, Permit No. 12-03 April 2016
9

6.0 CONCLUSION
There were several organic constituents detected above the NC 2L Groundwater Standards at the
John’s River Landfill during the December 2015 sampling event. These exceedances are
generally consistent with previous sampling events, are attributed to the old C&D-over-MSW
Landfill covered by a separate report, and are being addressed by the Corrective Action Plan for
the facility.

Thallium was detected in MW-22S above the GWPS; however, thallium was not detected above
the calculated background concentration. An ASD was approved for iron and manganese by
DENR on April 12, 2012. The inorganic results from the December 2015 are consistent with
historical data.

There were no organic or inorganic detections above the NC 2B Surface Water Standards for
surface water samples from the December 2015 sampling event.

The groundwater flow regime is consistent with previous events and the groundwater monitoring
network remains adequate to monitor the site. Based on analytical results from the December
2015 sampling event, Phase 1A of the John’s River Landfill will remain in Detection
Monitoring. The next semiannual sampling event is scheduled for the second quarter of 2016.

7.0 REFERENCES

Hinchee, R.E., A. Leeson, L. Semprini, and S.K. Ong. 1994. Bioremediation of Chlorinated and
Polycyclic Aromatic Hydrocarbon Compounds. Lewis Publishers, Boca Raton.

Interstate Technology and Regulatory Cooperation Work Group (ITRC). September 1999.
Natural Attenuation of Chlorinated Solvents in Groundwater: Principles and Practices.
Technical/Regulatory Guidelines.

Interstate Technical Regulatory Council (ITRC). 2003. Technical and Regulatory Guidance
Document for Constructed Treatment Wetlands.

Joyce Engineering (JOYCE), 1994. Transition Plan, Johns River Waste Management Facility.
April 1994.

JOYCE, 2000. Water Quality Assessment Report, Johns River Waste Management Facility.
January 2000.

JOYCE, 2004. Update on Groundwater Assessment Activities, Johns River Waste Management
Facility. October 2004.

2nd Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering
Burke County – John’s River Landfill, Phase 1A, Permit No. 12-03 April 2016
10
JOYCE, 2005a. Assessment of Corrective Measures Report, Johns River Waste Management
Facility. February 2005.

JOYCE, 2005b. Quantitative Risk Assessment, Johns River Waste Management Facility.
February 2005.

JOYCE, 2008. Corrective Action Plan, Johns River Waste Management Facility. June 2008.

JOYCE, 2011. Corrective Action Evaluation Report, Johns River Waste Management Facility.
May 2011.

JOYCE, 2013. Addendum to the Corrective Action Plan, Johns River Waste Management
Facility. August 2013.

National Research Council (NRC), 2000. Natural Attenuation for Groundwater Remediation.
National Academy Press, Washington, D.C. pp. 108-111.

North Carolina Department of Environment, Health, and Natural Resources (NC-DENR), 1997.
North Carolina Solid Waste Management Rules. 15 NCAC 13B. January 1, 1997.

NC-DENR, 2007. North Carolina Solid Waste Section Guidelines for Corrective Action at Solid
Waste Management Facilities. March 2007.

Sumsion, C.T., and Laney, R.L., 1967, Geology and Ground-water Resources of the Morganton
area North Carolina. N.C. Department of Water Resources, Ground Water Bulletin No.
12, 119 p.

U.S. Department of Energy (USDE). May 1999. Decision-Making Framework Guide for the
Evaluation and Selection of Monitored Natural Attenuation Remedies at Department of
Energy Sites.

U.S. Environmental Protection Agency (USEPA), 1992. Statistical Analysis of Groundwater
Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance. July 1992.

USEPA. October 1988. Interim Final Guidance for Conducting Remedial Investigations and
Feasibility Studies under CERCLA. Office of Solid Waste and Emergency Response
(OSWER) Directive 9355.3-01, EPA/540/G-89/004.

USEPA. February 1991. Conducting Remedial Investigations/Feasibility Studies for CERCLA
Municipal Landfill Sites. OSWER Directive 9355.3-11, EPA/540/P-91/001.

USEPA. May 1995. How to Evaluate Alternative Cleanup Technologies for Underground
Storage Tank Sites: A Guide for Corrective Action Plan Reviewers. Chapters 2 (Soil
Vapor Extraction) and 10 (In-Situ Groundwater Bioremediation).

2nd Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering
Burke County – John’s River Landfill, Phase 1A, Permit No. 12-03 April 2016
11

USEPA. May 1996. Seminars on Bioremediation of Hazardous Waste Sites: Practical
Approaches to Implementation. ORD, EPA/625/K-96/001. Chapters 15 (Natural
Attenuation of Groundwater) and 17 (Natural Attenuation of Landfills).

USEPA and U.S. Air Force (USAF). July 1993. Remediation Technologies Screening Matrix
Reference Guide, Version I. Joint Project of OSWER and Environics Directorate, PB93-
2118212.

9.0 ACRONYMS
ACM Assessment of Corrective Measures (Report)
AMSL Above Mean Sea Level
AOC Area of Concern
BGS Below Ground Surface
C&D Construction and Demolition Waste
CAP Corrective Action Plan (Report)
CAER Corrective Action Evaluation Report (Report)
CAMP Corrective Action Monitoring Plan (Report)
CAS Chemical Abstracts Service
CFR Code of Federal Regulations
CPVC Chlorinated Poly Vinyl Chloride
COC Contaminant of Concern (for corrective action)
COC Chain of Custody (for sampling and lab reports)
DENR North Carolina Department of Environment and Natural Resources
DL Detection Limit (for laboratory data)
DO Dissolved Oxygen
EPA United States Environmental Protection Agency (or USEPA)
GWPS Groundwater Protection Standards (Established by DENR-SWS)
JOYCE Joyce Engineering
LFG Landfill Gas
MNA Monitored Natural Attenuation
MSW Municipal Solid Waste
MW Monitoring Well
NC2B North Carolina Surface Water Standards found in 15A NCAC 2B
NC2L North Carolina Groundwater Standards found in 15A NCAC 2L
NCAC North Carolina Administrative Code
NCGS North Carolina Geological Survey
NCSWMR North Carolina Solid Waste Management Regulations (15A NCAC 13B.1600)
ND Not Detected (for laboratory data)
NES Nature and Extent Study (Report)
O&M Operations and Maintenance
QL Quantitation Limit (for laboratory data)
QRA Quantitative Risk Assessment (Report)

2nd Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering
Burke County – John’s River Landfill, Phase 1A, Permit No. 12-03 April 2016
12
RL Reporting Limit (for laboratory data)
RQD Rock Quality Designation
SPT Standard Penetration Test
SSI Statistically Significant Increase (above background concentrations)
SWQS Surface Water Quality Standards
SWS Solid Waste Section (of DENR-Division of Waste Management)
SWSL North Carolina Solid Waste Section Reporting Limits
TOC Top of Casing (Well)
USCS Unified Soil Classification System
USEPA United States Environmental Protection Agency (or EPA)
USGS United States Geological Survey
VOC Volatile Organic Compound
WQMP Water Quality Monitoring Plan (Report)

TABLES

Table 1 Historical Groundwater Elevation Data
Table 2 Field Parameters
Table 3 Quantified Detections of Groundwater Constituents (May 2015)
Table 4 Exceedances of Groundwater Standards (May 2015)
Table 5 Quantified Detections in Additional Wells/Piezometers (May 2015) Table 6 Exceedances in Additional Wells/Piezometers (May 2015)
Table 7 Statistical Background Analyses
Table 8 Hydraulic Gradients and Groundwater Flow Velocities

TA
B
L
E

1
:

H
I
S
T
O
R
I
C
A
L

G
R
O
U
N
D
W
A
T
E
R

E
L
E
V
A
T
I
O
N
S
Cl
a
s
s
i
f
i
c
a
t
i
o
n
:

B
a
c
k
g
r
o
u
n
d
We
l
l

N
o
.
MW
-
2
1

(P
Z
-
1
)
MW
-
2
0

(P
Z
-
4
)
MW
-
2
2
S

(P
Z
-
2
2
S
)
MW
-
3
8

(P
Z
-
3
8
)
MW
-
3
6

(P
Z
-
3
6
)
MW
-
1
5
S

P
Z
-
1
2

P
Z
-
3
0
S

P
Z
-
3
1
TO
C

E
l
e
v
a
t
i
o
n
10
9
9
.
8
6

1
1
1
5
.
0
4

1
0
6
1
.
2
0

1
0
8
7
.
7
6

1
0
9
9
.
5
2

1
0
6
9
.
0
4

1
0
2
5
.
6
4

1
0
8
8
.
9
2

1
0
8
9
.
8
1
We
l
l

D
e
p
t
h
41
.
0
0

6
7
.
0
0

2
7
.
6
3

7
3
.
1
3

4
5
.
0
0

5
6
.
1
6

1
5
.
0
9

5
5
.
2
5

4
3
.
1
3
06
/
1
8
/
9
6
NM

N
M

1
0
4
9
.
8
8

N
I

N
I

1
0
2
2
.
7
0

1
0
1
7
.
9
2

N
I

N
I
12
/
0
4
/
9
6
NM

N
M

1
0
4
6
.
7
5

N
I

N
I

1
0
2
1
.
3
0

1
0
1
7
.
9
1

N
I

N
I
05
/
0
6
/
1
4
10
6
6
.
0
6

1
0
5
8
.
2
4

1
0
4
8
.
7
0

1
0
4
2
.
1
8

1
0
6
9
.
1
7

1
0
2
5
.
7
4

1
0
1
8
.
1
4

1
0
4
1
.
9
2

1
0
6
4
.
1
4
10
/
2
1
/
1
4
10
6
3
.
4
8

1
0
5
6
.
4
2

1
0
4
5
.
7
6

1
0
4
5
.
1
8

1
0
6
6
.
5
2

1
0
2
4
.
6
4

1
0
1
7
.
6
8

1
0
4
8
.
9
2

1
0
6
1
.
0
4
05
/
2
1
/
1
5
10
6
2
.
1
8

1
0
5
3
.
6
9

1
0
4
3
.
6
5

1
0
4
4
.
6
8

1
0
6
6
.
0
3

1
0
2
5
.
1
7

1
0
1
7
.
6
0

1
0
4
7
.
2
2

1
0
6
0
.
1
7
12
/
0
9
/
1
5
10
6
1
.
7
1

1
0
5
1
.
6
5

1
0
4
2
.
6
0

1
0
4
6
.
2
4

1
0
6
6
.
7
2

1
0
2
5
.
1
9

1
0
1
7
.
6
9

1
0
4
5
.
5
7

1
0
5
8
.
7
0
No
t
e
s
:

Al
l

e
l
e
v
a
t
i
o
n
s

a
r
e

i
n

f
e
e
t

a
b
o
v
e

m
e
a
n

s
e
a

l
e
v
e
l
.
NM

=

G
r
o
u
n
d
w
a
t
e
r

l
e
v
e
l

n
o
t

m
e
a
s
u
r
e
d
.
NI

=

w
e
l
l

n
o
t

y
e
t

i
n
s
t
a
l
l
e
d
.
Ph
a
s
e

1
A

C
o
m
p
l
i
a
n
c
e

A
d
d
i
t
i
o
n
a
l

W
e
l
l
s

&

P
i
e
z
o
m
e
t
e
r
s
Bu
r
k
e

C
o
u
n
t
y

J
o
h
n
'
s

R
i
v
e
r

L
a
n
d
f
i
l
l

-

P
h
a
s
e

1

Pe
r
m
i
t

1
2
-
0
3

Joyce Engineering
TABLE 2: Field Parameters
WELL ID PARAMETER RESULT UNITS COLLECT DATE
MW-15S pH 5.11 S.U. 12/9/2015
MW-15S Temperature 15.1 ºC 12/9/2015
MW-15S Turbidity 21.4 NTU 12/9/2015
MW-15S Conductivity 51.5 µS 12/9/2015
MW-15S Static Water Level 43.85 ft 12/9/2015
MW-15S Well Depth 58.27 ft 12/9/2015
MW-15S Dissolved CO2 110 mg/L 12/9/2015
MW-20 pH 6.09 S.U. 12/8/2015
MW-20 Temperature 16.2 ºC 12/8/2015
MW-20 Dissolved Oxygen 7.53 mg/L 12/8/2015
MW-20 Oxygen Reduction Potential 148.8 mg/L 12/8/2015
MW-20 Turbidity 55.6 NTU 12/8/2015
MW-20 Static Water Level 63.39 ft 12/8/2015
MW-20 Well Depth 67.00 ft 12/8/2015
MW-21 pH 5.13 S.U. 12/8/2015
MW-21 Temperature 15.2 ºC 12/8/2015
MW-21 Conductivity 15.5 µS 12/8/2015
MW-21 Dissolved Oxygen 7.78 mg/L 12/8/2015
MW-21 Oxygen Reduction Potential 269.9 mg/L 12/8/2015
MW-21 Ferrous Iron 0 mg/L 12/8/2015
MW-21 Turbidity 25.5 NTU 12/8/2015
MW-21 Static Water Level 38.15 ft 12/8/2015
MW-21 Well Depth 46.80 ft 12/8/2015
MW-22S pH 5.48 S.U. 12/9/2015
MW-22S Temperature 15.9 ºC 12/9/2015
MW-22S Conductivity 15.9 µS 12/9/2015
MW-22S Turbidity 48.3 NTU 12/9/2015
MW-22S Static Water Level 18.60 ft 12/9/2015
MW-22S Well Depth 26.40 ft 12/9/2015
MW-22S pH 5.93 S.U. 2/4/2016
MW-22S Temperature 15.0 ºC 2/4/2016
MW-22S Conductivity 24.3 µS 2/4/2016
MW-22S Turbidity 16.3 NTU 2/4/2016
MW-22S Static Water Level 17.89 ft 2/4/2016
MW-22S Well Depth 26.40 ft 2/4/2016
MW-36 pH 5.38 S.U. 12/9/2015
MW-36 Temperature 15.5 ºC 12/9/2015
MW-36 Conductivity 232 µS 12/9/2015
MW-36 Dissolved CO2 235 mg/L 12/9/2015
MW-36 Turbidity 17.41 NTU 12/9/2015
MW-36 Static Water Level 32.80 ft 12/9/2015
MW-36 Well Depth 45.58 ft 12/9/2015
MW-38 pH 6.19 S.U. 12/9/2015
MW-38 Temperature 15.6 ºC 12/9/2015
MW-38 Conductivity 493.0 µS 12/9/2015
MW-38 Static Water Level 41.52 ft 12/9/2015
MW-38 Well Depth 74.5 ft 12/9/2015
Burke Co. John's River Landfill - Phase 1A
Permit No. 12-03 Page 1 of 2
Joyce Engineering
TABLE 2: Field Parameters
WELL ID PARAMETER RESULT UNITS COLLECT DATE
PZ-12 pH 5.14 S.U. 12/9/2015
PZ-12 Temperature 11.7 ºC 12/9/2015
PZ-12 Conductivity 27 µS 12/9/2015
PZ-12 Dissolved CO2 25 mg/L 12/9/2015
PZ-12 Turbidity 33.6 NTU 12/9/2015
PZ-12 Static Water Level 7.95 ft 12/9/2015
PZ-12 Well Depth 6.86 ft 12/9/2015
PZ-30S pH 5.47 S.U. 12/8/2015
PZ-30S Temperature 15.5 ºC 12/8/2015
PZ-30S Conductivity 30 µS 12/8/2015
PZ-30S Turbidity 7.55 NTU 12/8/2015
PZ-30S Static Water Level 43.35 ft 12/8/2015
PZ-30S Well Depth 55.30 ft 12/8/2015
PZ-31 pH 5.69 S.U. 12/8/2015
PZ-31 Temperature 15.4 ºC 12/8/2015
PZ-31 Conductivity 29 µS 12/8/2015
PZ-31 Dissolved CO2 5 mg/L 12/8/2015
PZ-31 Turbidity 8.25 NTU 12/8/2015
PZ-31 Static Water Level 31.11 ft 12/8/2015
PZ-31 Well Depth 45.60 ft 12/8/2015
PZ-35 pH 5.42 S.U. 12/9/2015
PZ-35 Temperature 15.9 ºC 12/9/2015
PZ-35 Conductivity 29 µS 12/9/2015
PZ-35 Turbidity 25.1 NTU 12/9/2015
PZ-35 Static Water Level 21.55 ft 12/9/2015
PZ-35 Well Depth 39.05 ft 12/9/2015
SMP-5 pH 5.93 S.U. 12/9/2015
SMP-5 Temperature 8 ºC 12/9/2015
SMP-5 Conductivity 59 µS 12/9/2015
SMP-5 Turbidity 6.61 NTU 12/9/2015
SMP-6 pH 6.18 S.U. 12/9/2015
SMP-6 Temperature 6.3 ºC 12/9/2015
SMP-6 Conductivity 39 µS 12/9/2015
SMP-6 Turbidity 6.07 NTU 12/9/2015
SMP-7 pH 5.46 S.U. 12/9/2015
SMP-7 Temperature 8.5 ºC 12/9/2015
SMP-7 Conductivity 38 µS 12/9/2015
SMP-7 Turbidity 4.33 NTU 12/9/2015
Notes:ºC= degrees Centigrade
S.U.= Standard Units
µS = microsemens
NTU = Nephelometric Turbidity Units
mg/L = milligrams per liter
ft = feet
MW-22S Verification/Resample Parameters from February 4, 2016 Included on this table.
Burke Co. John's River Landfill - Phase 1A
Permit No. 12-03 Page 2 of 2
Joyce Engineering
TABLE 3: Quantified Detections of Groundwater Constituents
WELL ID PARAMETER RESULT UNITS SWSL COLLECT DATE
1203-MW20 Iron 3,590 µg/L 300 12/8/2015
1203-MW20 Manganese 68.5 µg/L 50 12/8/2015
1203-MW20 Zinc 10.3 µg/L 10 12/8/2015
1203-MW20 Alkalinity, Total as CaCO3 8,280 µg/L NE 12/8/2015
1203-MW20 Chloride 1,840 µg/L NE 12/8/2015
1203-MW20 Total Dissolved Solids, Dissolved 31,000 µg/L NE 12/8/2015
1203-MW21 Iron 1,380 µg/L 300 12/8/2015
1203-MW22S Arsenic 12.7 µg/L 10 12/9/2015
1203-MW22S Arsenic (resample)5.8 J µg/L 10 2/4/2016
1203-MW22S Barium 1,110 µg/L 100 12/9/2015
1203-MW22S Barium (resample)264 µg/L 100 2/4/2016
1203-MW22S Beryllium 3.4 µg/L 1 12/9/2015
1203-MW22S Beryllium (resample)0.83 J µg/L 1 2/4/2016
1203-MW22S Chromium 16.8 µg/L 10 12/9/2015
1203-MW22S Chromium (resample)6.6 J µg/L 10 2/4/2016
1203-MW22S Cobalt 11.2 µg/L 10 12/9/2015
1203-MW22S Cobalt (resample)3.2 J µg/L 10 2/4/2016
1203-MW22S Copper 30 µg/L 10 12/9/2015
1203-MW22S Copper (resample)10.4 µg/L 10 2/4/2016
1203-MW22S Iron 29,700 µg/L 300 12/9/2015
1203-MW22S Iron (resample)9,840 µg/L 300 2/4/2016
1203-MW22S Lead 39.4 µg/L 10 12/9/2015
1203-MW22S Lead (resample)10.5 µg/L 10 2/4/2016
1203-MW22S Manganese 462 µg/L 50 12/9/2015
1203-MW22S Manganese (resample)124 µg/L 50 2/4/2016
1203-MW22S Thallium ND µg/L 5.5 12/9/2015
1203-MW22S Thallium (resample)9.1 µg/L 5.5 2/4/2016
1203-MW22S Vanadium 44.8 µg/L 25 12/9/2015
1203-MW22S Vanadium (resample)16.0 J µg/L 25 2/4/2016
1203-MW22S Zinc 127 µg/L 10 12/9/2015
1203-MW22S Zinc (resample)36.5 µg/L 10 2/4/2016
1203-MW22S Alkalinity, Total as CaCO3 6,670 µg/L NE 12/9/2015
1203-MW22S Chloride 4,200 µg/L NE 12/9/2015
1203-MW22S Total Dissolved Solids, Dissolved 96,000 µg/L NE 12/9/2015
1203-MW38 Iron 27,800 µg/L 300 12/9/2015
1203-MW38 Manganese 3,220 µg/L 50 12/9/2015
1203-MW38 1,1-Dichloroethane 7.2 µg/L 5 12/9/2015
1203-MW38 1,4-Dichlorobenzene 12.2 µg/L 1 12/9/2015
1203-MW38 Benzene 4.4 µg/L 1 12/9/2015
1203-MW38 cis-1,2-Dichloroethene 14.7 µg/L 5 12/9/2015
1203-MW38 Tetrahydrofuran 39.1 µg/L NE 12/9/2015
1203-MW38 Trichloroethene 2.1 µg/L 1 12/9/2015
1203-MW38 Alkalinity, Total as CaCO3 234,000 µg/L NE 12/9/2015
1203-MW38 Chloride 4,390 µg/L NE 12/9/2015
1203-MW38 Total Dissolved Solids, Dissolved 311,000 µg/L NE 12/9/2015
Notes: µg/L = micorgrams per liter.
J = Estimated conentration belwo the SWSL.ND= Not detected.
SWSL = NC Soild Waste Section Reporting Limit.NE = Not established.
Laboratory Reporting limit used when SWSL has not been established.
MW-22S Verification/Resample Results from February 4, 2016, are shaded.
Burke County - John's River Landfill, Phase 1A
Permit 12-03
Joyce Engineering
TABLE 4: Exceedences of Groundwater Standards
WELL ID PARAMETER RESULT UNITS SWSL
NC 2L/
*GWPS GPS COLLECT DATE
1203-MW20 Iron 3,590 µg/L 300 300 ASD 12/8/20151203-MW20 Manganese 68.5 µg/L 50 50 ASD 12/8/2015
1203-MW21 Iron 1,380 µg/L 300 300 ASD 12/8/2015
1203-MW22S Arsenic 12.7 µg/L 10 10 10 12/9/2015
1203-MW22S Arsenic (resample)5.8 J µg/L 10 10 10 2/4/2016
1203-MW22S Barium 1,110 µg/L 100 700 700 12/9/2015
1203-MW22S Barium (resample)264 µg/L 100 700 700 2/4/2016
1203-MW22S Beryllium 3.4 µg/L 1 4* 4 12/9/2015
1203-MW22S Beryllium (resample)0.83 J µg/L 1 4* 4 2/4/2016
1203-MW22S Chromium 16.8 µg/L 10 10 10 12/9/2015
1203-MW22S Chromium (resample)6.6 J µg/L 10 10 10 2/4/2016
1203-MW22S Cobalt 11.2 µg/L 10 1* 96.6 12/9/2015
1203-MW22S Cobalt (resample)3.2 J µg/L 10 1* 96.6 2/4/2016
1203-MW22S Copper 30 µg/L 10 1000 1000 12/9/2015
1203-MW22S Copper (resample)10.4 µg/L 10 1000 1000 2/4/2016
1203-MW22S Iron 29,700 µg/L 300 300 ASD 12/9/2015
1203-MW22S Iron (resample)9,840 µg/L 300 300 ASD 2/4/2016
1203-MW22S Lead 39.4 µg/L 10 15 15 12/9/2015
1203-MW22S Lead (resample)10.5 µg/L 10 15 15 2/4/2016
1203-MW22S Manganese 462 µg/L 50 50 ASD 12/9/2015
1203-MW22S Manganese (resample)124 µg/L 50 50 ASD 2/4/2016
1203-MW22S Thallium ND µg/L 5.5 0.28* 36.8 12/9/2015
1203-MW22S Thallium (resample)9.1 µg/L 5.5 0.28* 36.8 2/4/2016
1203-MW22S Vanadium 44.8 µg/L 25 0.3* 630 12/9/20151203-MW22S Vanadium (resample)16.0 J µg/L 25 0.3* 630 2/4/2016
1203-MW38 Iron 27,800 µg/L 300 300 ASD 12/9/2015
1203-MW38 Manganese 3,220 µg/L 50 50 ASD 12/9/2015
1203-MW38 1,1-Dichloroethane 7.2 µg/L 5 6 6 12/9/2015
1203-MW38 1,4-Dichlorobenzene 12.2 µg/L 1 6 6 12/9/2015
1203-MW38 Benzene 4.4 µg/L 1 1 1 12/9/2015
Notes: µg/L = Micorgrams per liter.
J = Estimated conentration belwo the SWSL. ND= Not detected.
SWSL = NC Soild Waste Section Reporting Limit.
NC2L = NC Groundwater Standard from 15A NCAC 2L.0202.
GWPS = NC Solid Waste Section Groundwater Protection Standard (for constituents with no NC2L).
GPS = Groundwater Protection Standard as defined by 15A NCAC 13B.1634(g).
Cobalt & thallium GPS are based on statistical background.
ASD = Approved Alternate Source Demonstration on record.
GPS Exceedances are bold.
MW-22S Verification/Resample Results from February 4, 2016, are shaded
THERE WERE NO EXCEEDANCES OF SURFACE WATER STANDARDS.
MW-38 Exceedences are impacts from the old C&D-over-MSWLF and not from new Phase 1A cell.
Burke County - John's River Landfill, Phase 1A
Permit 12-03
Joyce Engineering
TA
B
L
E

5
:

Q
u
a
n
t
i
f
i
e
d

D
e
t
e
c
t
i
o
n
s

i
n

A
d
d
i
t
i
o
n
a
l

W
e
l
l
s

a
n
d

P
i
e
z
o
m
e
t
e
r
s

WE
L
L

I
D

P
A
R
A
M
E
T
E
R

R
E
S
U
L
T

U
N
I
T
S

S
W
S
L

C
O
L
L
E
C
T

D
A
T
E
12
0
3
-
M
W
1
5
S

1
,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

1

µ
g
/
L

1

1
2
/
9
/
2
0
1
5
12
0
3
-
M
W
1
5
S

B
e
n
z
e
n
e

1
.
2

µ
g
/
L

1

1
2
/
9
/
2
0
1
5
12
0
3
-
M
W
1
5
S

M
e
t
h
a
n
e

8
,
5
5
0

µ
g
/
L

N
E

1
2
/
9
/
2
0
1
5
12
0
3
-
M
W
1
5
S

T
e
t
r
a
c
h
l
o
r
o
e
t
h
e
n
e

2
.
1

µ
g
/
L

1

1
2
/
9
/
2
0
1
5
12
0
3
-
M
W
1
5
S

T
r
i
c
h
l
o
r
o
e
t
h
e
n
e

1
.
1

µ
g
/
L

1

1
2
/
9
/
2
0
1
5
12
0
3
-
M
W
3
8

M
e
t
h
a
n
e

3
,
1
2
0

µ
g
/
L

N
E

1
2
/
9
/
2
0
1
5
12
0
3
-
P
Z
3
6

1
,
1
-
D
i
c
h
l
o
r
o
e
t
h
a
n
e

5
.
9

µ
g
/
L

5

1
2
/
9
/
2
0
1
5
12
0
3
-
P
Z
3
6

1
,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

1
9
.
6

µ
g
/
L

1

1
2
/
9
/
2
0
1
5
12
0
3
-
P
Z
3
6

B
e
n
z
e
n
e

5
.
8

µ
g
/
L

1

1
2
/
9
/
2
0
1
5
12
0
3
-
P
Z
3
6

M
e
t
h
a
n
e

3
,
7
8
0

µ
g
/
L

N
E

1
2
/
9
/
2
0
1
5
12
0
3
-
P
Z
3
6

M
e
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e

1
1
.
2

µ
g
/
L

1

1
2
/
9
/
2
0
1
5
12
0
3
-
P
Z
3
6

T
e
t
r
a
c
h
l
o
r
o
e
t
h
e
n
e

5

µ
g
/
L

1

1
2
/
9
/
2
0
1
5
12
0
3
-
P
Z
3
6

T
r
i
c
h
l
o
r
o
e
t
h
e
n
e

2
.
9

µ
g
/
L

1

1
2
/
9
/
2
0
1
5
No
t
e
s
:

µ
g
/
L

=

m
i
c
o
r
g
r
a
m
s

p
e
r

l
i
t
e
r
SW
S
L

=

N
C

S
o
i
l
d

W
a
s
t
e

S
e
c
t
i
o
n

R
e
p
o
r
t
i
n
g

L
i
m
i
t

La
b
o
r
a
t
o
r
y

R
e
p
o
r
t
i
n
g

l
i
m
i
t

u
s
e
d

w
h
e
n

S
W
S
L

h
a
s

n
o
t

b
e
e
n

e
s
t
a
b
l
i
s
h
e
d
B
=

B
l
a
n
k
-
q
u
a
l
i
f
i
e
d

d
e
t
e
c
t
i
o
n
.
Bu
r
k
e

C
o
.

J
o
h
n
'
s

R
i
v
e
r

L
a
n
d
f
i
l
l

-

P
h
a
s
e

1
A
Pe
r
m
i
t

N
o
.

1
2
-
0
3
Joyce Engineering
TA
B
L
E

6
:

E
x
c
e
e
d
a
n
c
e
s

i
n

A
d
d
i
t
i
o
n
a
l

W
e
l
l
s
/
P
i
e
z
o
m
e
t
e
r
s
WE
L
L

I
D

P
A
R
A
M
E
T
E
R

R
E
S
U
L
T

U
N
I
T
S

S
W
S
L

N
C
2
L
/
*
G
W
P
S

G
P
S

C
O
L
L
E
C
T

D
A
T
E
12
0
3
-
M
W
1
5
S

B
e
n
z
e
n
e

1
.
2

µ
g
/
L

1

1

1

1
2
/
9
/
2
0
1
5
12
0
3
-
M
W
1
5
S

T
e
t
r
a
c
h
l
o
r
o
e
t
h
e
n
e

2
.
1

µ
g
/
L

1

0
.
7

0
.
7

1
2
/
9
/
2
0
1
5
12
0
3
-
P
Z
3
6

1
,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

1
9
.
6

µ
g
/
L

1

6

6

1
2
/
9
/
2
0
1
5
12
0
3
-
P
Z
3
6

B
e
n
z
e
n
e

5
.
8

µ
g
/
L

1

1

1

1
2
/
9
/
2
0
1
5
12
0
3
-
P
Z
3
6

T
e
t
r
a
c
h
l
o
r
o
e
t
h
e
n
e

5

µ
g
/
L

1

0
.
7

0
.
7

1
2
/
9
/
2
0
1
5
No
t
e
s
:

µ
g
/
L

=

m
i
c
o
r
g
r
a
m
s

p
e
r

l
i
t
e
r
SW
S
L

=

N
C

S
o
i
l
d

W
a
s
t
e

S
e
c
t
i
o
n

R
e
p
o
r
t
i
n
g

L
i
m
i
t

La
b
o
r
a
t
o
r
y

R
e
p
o
r
t
i
n
g

l
i
m
i
t

u
s
e
d

w
h
e
n

S
W
S
L

h
a
s

n
o
t

b
e
e
n

e
s
t
a
b
l
i
s
h
e
d
NC
2
L

=

N
C

G
r
o
u
n
d
w
a
t
e
r

S
t
a
n
d
a
r
d

f
r
o
m

1
5
A

N
C
A
C

2
L
.
0
2
0
2

GW
P
S

=

N
C

S
o
l
i
d

W
a
s
t
e

S
e
c
t
i
o
n

G
r
o
u
n
d
w
a
t
e
r

P
r
o
t
e
c
t
i
o
n

S
t
a
n
d
a
r
d

(
f
o
r

c
o
n
s
t
i
t
u
e
n
t
s

w
i
t
h

n
o

N
C
2
L
)
GP
S

=

G
r
o
u
n
d
w
a
t
e
r

P
r
o
t
e
c
t
i
o
n

S
t
a
n
d
a
r
d

a
s

d
e
f
i
n
e
d

b
y

1
5
A

N
C
A
C

1
3
B
.
1
6
3
4
(
g
)
GP
S

E
x
c
e
e
d
a
n
c
e
s

a
r
e

b
o
l
d
.
Bu
r
k
e

C
o
.

J
o
h
n
'
s

R
i
v
e
r

l
a
n
d
f
i
l
l

-

P
h
a
s
e

1
A
Pe
r
m
i
t

N
o
.

1
2
-
0
3
Joyce Engineering
TA
B
L
E

7
:

S
t
a
t
i
s
t
i
c
a
l

B
a
c
k
g
r
o
u
n
d

A
n
a
l
y
s
e
s

An
a
l
y
t
e

D
a
t
a

D
i
s
t
r
i
b
u
t
i
o
n

S
t
a
t
i
s
t
i
c
a
l

M
e
t
h
o
d

u
s
e
d

t
o

E
s
t
a
b
l
i
s
h

B
a
c
k
g
r
o
u
n
d
Ba
c
k
g ro
u
n
d

(µ
g
/
L
)
SW
S
L

(µ
g
/
L
)
NC
2
L

or

*GW
P
S

(µ
g
/
L
)
GP
S
#

(µ
g
/
L
)
Sampling Result (µg/L)GPS Exceedances
Th
a
l
l
i
u
m

9
2
%

N
D
Po
i
s
s
o
n

P
r
e
d
i
c
t
i
o
n

L
i
m
i
t
:

I
n
t
e
r
w
e
l
l
.
37
.
0

5
.
5

0
.
2
*

2
5

9
.
1

N
o
n
e
No
t
e
s
:

SW
S
L

=

N
C

S
o
l
i
d

W
a
s
t
e

S
e
c
t
i
o
n

L
i
m
i
t
s
NC

2
L

=

N
C

G
r
o
u
n
d
w
a
t
e
r

S
t
a
n
d
a
r
d
s

(
1
5
A

N
C
A
C

2
L
.
0
2
0
2
)
GW
P
S

=

S
o
l
i
d

W
a
s
t
e

S
e
c
t
i
o
n

G
r
o
u
n
d
w
a
t
e
r

P
r
o
t
e
c
t
i
o
n

S
t
a
n
d
a
r
d
s

f
o
r

C
o
n
s
t
i
t
u
e
n
t
s

w
i
t
h

n
o

N
C

2
L

(
i
n
d
i
c
a
t
e
d

b
y

*
)
%N
D

=

p
e
r
c
e
n
t
a
g
e

o
f

d
a
t
a

t
h
a
t

w
e
r
e

n
o
n
-
d
e
t
e
c
t

(
i
.
e
.
,

t
r
u
n
c
a
t
e
d
)
.
On
l
y

c
o
n
s
t
i
t
u
e
n
t
s

w
i
t
h

q
u
a
n
t
i
f
i
e
d

d
e
t
e
c
t
i
o
n
s

a
b
o
v
e

t
h
e

S
W
S
L

i
n

d
o
w
n
-
g
r
a
d
i
e
n
t

w
e
l
l
s

a
r
e

i
n
c
l
u
d
e
d

i
n

s
t
a
t
i
s
t
i
c
a
l

a
n
a
l
y
s
e
s
.
GP
S

=

G
r
o
u
n
d
w
a
t
e
r

P
r
o
t
e
c
t
i
o
n

S
t
a
n
d
a
r
d

p
e
r

1
5
A

N
C
A
C

.
1
6
3
4
(
g
)

Bu
r
k
e

C
o
u
n
t
y

Jo
h
n
'
s

R
i
v
e
r

W
a
s
t
e

M
a
n
a
g
e
m
e
n
t

F
a
c
i
l
i
t
y
Joyce Engineering
TA
B
L
E

8
:

H
y
d
r
a
u
l
i
c

G
r
a
d
i
e
n
t
s

a
n
d

G
r
o
u
n
d
w
a
t
e
r

F
l
o
w

V
e
l
o
c
i
t
i
e
s
GR
A
D
I
E
N
T

CA
L
C
U
L
A
T
I
O
N

SE
G
M
E
N
T
FL
O
W

L
I
N
E

LE
N
G
T
H

(f
e
e
t
)
FL
O
W

DI
R
E
C
T
I
O
N
GR
O
U
N
D
W
A
T
E
R

EL
E
V
A
T
I
O
N

(f
e
e
t
)
HO
R
I
Z
O
N
T
A
L

GR
A
D
I
E
N
T

i

(ft
/
f
t
)
HY
D
R
A
U
L
I
C

CO
N
D
U
C
T
I
V
I
T
Y

K

(f
t
/
d
a
y
)
EF
F
E
C
T
I
V
E

PO
R
O
S
I
T
Y

n e
LINEAR VELOCITY V (ft/y ear )
10
7
0
10
2
0
10
7
0
10
0
0
10
7
0
10
1
0
10
6
0
10
3
0
AV
E
R
A
G
E
:

0
.
0
4
8
0

A
V
E
R
A
G
E
:

1
4
3
.
8
No
t
e
s
:
Hy
d
r
a
u
l
i
c

c
o
n
d
u
c
t
i
v
i
t
y

(
K =3
.
2
8

f
t
/
d
a
y
)

i
s

b
a
s
e
d

o
n

t
h
e

a
r
i
t
h
m
e
t
r
i
c

m
e
a
n
s

o
f

K f
r
o
m

i
n
d
i
v
i
d
u
a
l

s
l
u
g

t
e
s
t
s

i
n

s
a
p
r
o
l
i
t
e

w
e
l
l
s

a
t

t
h
e

f
a
c
i
l
i
t
y
.
Ef
f
e
c
t
i
v
e

P
o
r
o
s
i
t
y

(
n e =
0
.
4
0
)

i
s

a
s
s
u
m
m
e
d

t
o

b
e

s
l
i
g
h
t
l
y

l
e
s
s

t
h
a
n

t
h
e

a
v
e
r
a
g
e

l
a
b
o
r
a
t
o
r
y

p
o
r
o
s
i
t
y

f
o
r

s
i
t
e

s
o
i
l

s
a
m
p
l
e
s

(
s
a
p
r
o
l
i
t
e
)

=

4
4
%

(
0
.
4
4
)
.
Gr
a
d
i
e
n
t

s
e
g
m
e
n
t
s

a
r
e

b
a
s
e
d

o
n

t
h
e

D
e
c
e
m
b
e
r

2
0
1
5

g
r
o
u
n
d
w
a
t
e
r

p
o
t
e
n
t
i
o
m
e
t
r
i
c

s
u
r
f
a
c
e

m
a
p

(
s
e
e

D
r
a
w
i
n
g

1
)
.
V
=

K
i
/
n
e
;

a
s
s
u
m
e
s

h
o
m
o
g
e
n
e
o
u
s

i
s
o
t
r
o
p
i
c

p
o
r
o
u
s

a
q
u
i
f
e
r
.
De
c
e
m
b
e
r

2
0
1
5
i
1
96
7

S
S
W

0
.
0
5
1
7

3
.
2
8
E
+
0
0

0
.
4
0

1
5
4
.
8
0.
0
3
9
0

1
1
6
.
6
0.
4
0
i
4
0.
4
0
3.
2
8
E
+
0
0
77
0

S
E
140.1
i
3
0.
4
0
3.
2
8
E
+
0
0
1,
0
9
8

S
S
E

0
.
0
5
4
6

1
6
3
.
6
3.
2
8
E
+
0
0
1,
4
9
5

S

0
.
0
4
6
8
i
2
Bu
r
k
e

C
o
u
n
t
y

Jo
h
n
'
s

R
i
v
e
r

L
a
n
d
f
i
l
l
,

P
e
r
m
i
t

1
2
-
0
3
Joyce Engineering

FIGURE

Figure 1: Site Location Map

APPROXIMATE LOCATION
OF EXISTING LANDFILL
APPROXIMATE LOCATION
OF PROPERTY LINE
SOURCE: U.S.G.S. TOPOGRAPHIC MAP
FOR MORGANTON NORTH, N.C.
0
(FEET)
GRAPHIC SCALE
400020001000
2211 W. MEADOWVIEW ROAD
GREENSBORO, NC 27407
PHONE: [phone]
PROJECT NO.
FIGURE NO.APPROVED
CHECKED
DRAWN
DESIGNED
DATE
All rights reserved.
Ó Joyce Engineering, Inc.
SCALE
NC CORP LIC: C-0782
JOHN'S RIVER LANDFILL
BURKE COUNTY, NORTH CAROLINA
SITE LOCATION MAP
277
1
AS SHOWN
2016
ACE
HRW
ACE
ACE
2016

DRAWING

Drawing 1: Groundwater Potentiometric Surface Map

SMP-5 SURFACE MONITORING POINT LOCATION AND IDENTIFICATION
NOT MEASURED
LEGEND
PROPERTY LINE
EXISTING ROAD
EXISTING 25' TOPOGRAPHIC CONTOUR
EXISTING 2' TOPOGRAPHIC CONTOUR
GROUNDWATER SURFACE CONTOUR [FEET
ABOVE MEAN SEA LEVEL (AMSL)]
APPROXIMATE LIMITS OF WASTE
CENTERLINE OF STREAM
GAS PROBE LOCATION AND IDENTIFICATION
PIEZOMETER LOCATION AND IDENTIFICATION
COMPLIANCE WELL LOCATION AND IDENTIFICATION WITH STATIC
WATER LEVEL ELEVATION (FEET AMSL)
(NM)
GP
1050
1020
MW-13
1009.64
PZ-9D
GMP-3
TOPOGRAPHIC CONTOUR INTERVAL = 2 AND 10 FEET.
GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET.
STATIC WATER LEVELS WERE MEASURED ON DECEMBER 9,2015.
GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION BETWEEN AND
EXTRAPOLATION FROM KNOWN DATA, TOPOGRAPHIC CONTOURS, AND KNOWN
FIELD CONDITIONS.
MW-16D GROUNDWATER ELEVATION WAS NOT USED IN CALCULATING
GROUNDWATER CONTOURS.
NOTES
EXISTING 5' TOPOGRAPHIC CONTOUR
EXISTING 10' TOPOGRAPHIC CONTOUR1080
T1 TEMPORARY WELL
APPROXIMATE LOCATION OF SPRING HEAD
1.
2.
3.
4.
5.
JE-0020 CONTROL POINT LOCATION AND IDENTIFICATION
SENTINEL WELL LOCATION AND IDENTIFICATION WITH STATIC
WATER LEVEL ELEVATION (FEET AMSL)
MW-18
GROUNDWATER FLOW PATHWAY USED TO
CALCULATE HYDRAULIC GRADIENT
1
SEGMENT USED FOR GRADIENT CALCULATION
ABANDONED OR UNUSED MONITORING WELL
i
i
i
FLOW PATH LENGTH
967 LF
1,495 LF
1,098 LF
770 LFi
1
0
0
0
1
0
1
0
1
0
2
0
1
0
3
0
1
0
4
0
1
0
5
0
1
0
6
0
1
0
7
0
1
0
8
0
1
0
9
0
1
1
0
0
1
1
1
0
1
1
2
0
1
1
3
0
1
1
4
0
1
1
5
0
1
1
6
0
1
1
5
0
1
1
4
0
1
1
3
0
1
1
2
0
1
1
1
0
1
1
0
0
1
0
9
0
1
0
8
0
1
1
7
0
108
0
1
0
7
0
1
0
6
0
1
0
5
0
1
0
4
0
105
0
10
0
0
10
6
0
10
5
0
10
4
0
10
3
0
10
2
0
1010
1000
10
7
0
4
(ABANDONED)
PZ-2S
(ABANDONED)
PZ-2D
(NM)
PZ-23
(NM)
PZ-15
(NM)
PZ-22D
1042.60
PZ-22S
(NM)
PZ-16S
1017.69
PZ-12
(NM)PZ-27
(NM)
PZ-14
(NM)
PZ-13
(ND)PZ-9D
(NM)
PZ-9S1009.64
MW-13
SMP-6
993.42
MW-12
992.25
MW-11
995.17
MW-16D 994.47
MW-16S
999.49
MW-10
SMP-5
MW-9
(NM)MW-14
1025.19
MW-15S
(NM)
MW-15D
(NM)MW-8
(NM)
MW-1
(FORMERLY PZ-4)
MW-20
NM
MW-17
SHOOTING
RANGE
MULCHING
AREA
L
O
W
E
R

C
R
E
E
K
JOH
N
S

R
I
V
E
R
CATAW
B
A

R
I
V
E
R
WETLAND
EXISTING TRAIL
TRANSFER FACILITY
EXISTING
SEDIMENT
BASIN
EXISTING C&D
DISPOSAL AREA
CURRENT BACKGROUND WELL
FORMER
MW-18 MW-19
OFFICE
AND
GARAGE
MW-38
1046.24
MW-36
1066.72
PZ-30S
1045.57
PZ-30D
PZ-31
1058.70
PZ-35
1063.39
BACKGROUND WELL
CURRENT PHASE 1A LIMITS
PROJECT NO.
AP
P
R
O
V
E
D
CH
E
C
K
E
D
DR
A
W
N
DE
S
I
G
N
E
D
DA
T
E
DA
T
E
RE
V
I
S
I
O
N
S

A
N
D

R
E
C
O
R
D

O
F

I
S
S
U
E
BY
NO
AP
P
CK
SCALE

A
l
l

r
i
g
h
t
s

r
e
s
e
r
v
e
d
.
”

J
o
y
c
e

E
n
g
i
n
e
e
r
i
n
g
,

I
n
c
.
DRAWING NO.
L:
\
B
u
r
k
e

C
o
u
n
t
y
\
2
0
1
6

c
o
n
s
t
i
t
u
e
n
t
s

m
a
p
s
\
1
-

G
W
-
E
V
E
N
T

1
2
-
1
5
.
D
W
G

L
a
y
o
u
t
=
S
H
T

0
1
22
1
1

W
.

M
E
A
D
O
W
V
I
E
W

R
O
A
D
GR
E
E
N
S
B
O
R
O
,

N
C

2
7
4
0
7
PH
O
N
E
:

(
3
3
6
)

3
2
3
-
0
0
9
2
277
JO
H
N
S

R
I
V
E
R
,

W
A
S
T
E

M
A
N
A
G
E
M
E
N
T

F
A
C
I
L
I
T
Y
BU
R
K
E

C
O
U
N
T
Y
,

N
O
R
T
H

C
A
R
O
L
I
N
A
20
1
6
1
AS NOTED
GR
O
U
N
D
W
A
T
E
R

P
O
T
E
N
T
I
O
M
E
T
R
I
C

S
U
R
F
A
C
E

M
A
P
DE
C
E
M
B
E
R

9
,

2
0
1
5
PE
R
M
I
T

N
O
.

1
2
-
0
3
GE
RW
H
VB VB
01
/
1
3
/
1
6
0
(FEET)
GRAPHIC SCALE
400200100

APPENDICES

Appendix A: Field Data Logs
Appendix B: Laboratory Analytical Reports
Appendix C: Statistical Analyses Worksheets
Appendix D: Historical Detected Groundwater Constituents
Appendix E: Historical Detected Constituents in Additional Wells and Piezometers
Appendix F: Historical Detected Surface Water Constituents

Appendix A

Field Data Logs

Appendix B

Laboratory Analytical Reports

#=CL#
December 22, 2015
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92279397
92279397
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
BURKE-JOHN'S R.-PHASE 1A COMPL
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on December 10, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc:Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 33
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 33
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Lab ID Sample ID Matrix Date Collected Date Received
92279397001 1203-MW20 Water 12/08/15 15:30 12/10/15 10:48
92279397002 1203-MW22S Water 12/09/15 15:00 12/10/15 10:48
92279397003 1203-MW38 Water 12/09/15 14:30 12/10/15 10:48
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 33
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92279397001 1203-MW20 EPA 6010 17 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8260 51 PASI-CGAW
SM 2320B 1 PASI-AMLS
SM 2540C 1 PASI-AMJP
EPA 300.0 1 PASI-AMDW
SM 4500-Cl-E 1 PASI-AWRC
92279397002 1203-MW22S EPA 6010 17 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8260 51 PASI-CGAW
SM 2320B 1 PASI-AMLS
SM 2540C 1 PASI-ASAM
EPA 300.0 1 PASI-AMDW
SM 4500-Cl-E 1 PASI-AWRC
92279397003 1203-MW38 EPA 6010 17 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8260 51 PASI-CGAW
SM 2320B 1 PASI-AMLS
SM 2540C 1 PASI-ASAM
EPA 300.0 1 PASI-AMDW
SM 4500-Cl-E 1 PASI-AWRC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 33
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92279397001 1203-MW20
Barium 67.3J ug/L 12/17/15 03:41100EPA 6010
Chromium 4.7J ug/L 12/17/15 03:4110.0EPA 6010
Copper 3.9J ug/L 12/17/15 03:4110.0EPA 6010
Iron 3590 ug/L 12/17/15 03:41300EPA 6010
Lead 3.0J ug/L 12/17/15 03:4110.0EPA 6010
Manganese 68.5 ug/L 12/17/15 03:4150.0EPA 6010
Nickel 2.5J ug/L 12/17/15 03:4150.0EPA 6010
Vanadium 6.9J ug/L 12/17/15 03:4125.0EPA 6010
Zinc 10.3 ug/L 12/17/15 03:4110.0EPA 6010
Alkalinity, Total as CaCO3 8280 ug/L 12/14/15 23:435000SM 2320B
Total Dissolved Solids 31000 ug/L 12/11/15 10:4425000SM 2540C
Chloride 1840 ug/L 12/18/15 17:571000SM 4500-Cl-E
92279397002 1203-MW22S
Arsenic 12.7 ug/L 12/17/15 03:4410.0EPA 6010
Barium 1110 ug/L 12/17/15 03:44100EPA 6010
Beryllium 3.4 ug/L 12/17/15 03:441.0EPA 6010
Chromium 16.8 ug/L 12/17/15 03:4410.0EPA 6010
Cobalt 11.2 ug/L 12/17/15 03:4410.0EPA 6010
Copper 30.0 ug/L 12/17/15 03:4410.0EPA 6010
Iron 29700 ug/L 12/17/15 03:44300EPA 6010
Lead 39.4 ug/L 12/17/15 03:4410.0EPA 6010
Manganese 462 ug/L 12/17/15 03:4450.0EPA 6010
Nickel 18.7J ug/L 12/17/15 03:4450.0EPA 6010
Vanadium 44.8 ug/L 12/17/15 03:4425.0EPA 6010
Zinc 127 ug/L 12/17/15 03:4410.0EPA 6010
Alkalinity, Total as CaCO3 6670 ug/L 12/20/15 22:145000SM 2320B
Total Dissolved Solids 96000 ug/L 12/14/15 08:3150000SM 2540C
Chloride 4200 ug/L 12/18/15 17:581000SM 4500-Cl-E
92279397003 1203-MW38
Arsenic 4.9J ug/L 12/17/15 03:4710.0EPA 6010
Barium 83.5J ug/L 12/17/15 03:47100EPA 6010
Cobalt 4.1J ug/L 12/17/15 03:4710.0EPA 6010
Copper 3.3J ug/L 12/17/15 03:4710.0EPA 6010
Iron 27800 ug/L 12/17/15 03:47300EPA 6010
Lead 3.2J ug/L 12/17/15 03:4710.0EPA 6010
Manganese 3220 ug/L 12/17/15 03:4750.0EPA 6010
Nickel 3.0J ug/L 12/17/15 03:4750.0EPA 6010
Vanadium 8.5J ug/L 12/17/15 03:4725.0EPA 6010
Zinc 8.7J ug/L 12/17/15 03:4710.0EPA 6010
Benzene 4.4 ug/L 12/20/15 23:031.0EPA 8260
Chlorobenzene 0.49J ug/L 12/20/15 23:033.0EPA 8260
1,4-Dichlorobenzene 12.2 ug/L 12/20/15 23:031.0EPA 8260
1,1-Dichloroethane 7.2 ug/L 12/20/15 23:035.0EPA 8260
1,2-Dichloroethane 0.70J ug/L 12/20/15 23:031.0EPA 8260
cis-1,2-Dichloroethene 14.7 ug/L 12/20/15 23:035.0EPA 8260
Tetrahydrofuran 39.1 ug/L 12/20/15 23:0310.0EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 33
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92279397003 1203-MW38
Trichloroethene 2.1 ug/L 12/20/15 23:031.0EPA 8260
Xylene (Total)1.6J ug/L 12/20/15 23:035.0EPA 8260
Alkalinity, Total as CaCO3 234000 ug/L 12/20/15 22:235000SM 2320B
Total Dissolved Solids 311000 ug/L 12/14/15 08:3125000SM 2540C
Sulfate 4640J ug/L 12/11/15 14:06250000EPA 300.0
Chloride 4390 ug/L 12/18/15 17:581000SM 4500-Cl-E
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Sample:1203-MW20 Lab ID:92279397001 Collected:12/08/15 15:30 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/17/15 03:41 7440-36-012/12/15 00:006.0 3.8 1
Arsenic ND ug/L 12/17/15 03:41 7440-38-212/12/15 00:0010.0 2.5 1
Barium 67.3J ug/L 12/17/15 03:41 7440-39-312/12/15 00:001002.5 1
Beryllium ND ug/L 12/17/15 03:41 7440-41-712/12/15 00:001.0 0.50 1
Cadmium ND ug/L 12/17/15 03:41 7440-43-912/12/15 00:001.0 0.50 1
Chromium 4.7J ug/L 12/17/15 03:41 7440-47-312/12/15 00:0010.0 2.5 1
Cobalt ND ug/L 12/17/15 03:41 7440-48-412/12/15 00:0010.0 2.5 1
Copper 3.9J ug/L 12/17/15 03:41 7440-50-812/12/15 00:0010.0 2.5 1
Iron 3590 ug/L 12/17/15 03:41 7439-89-612/12/15 00:0030025.0 1
Lead 3.0J ug/L 12/17/15 03:41 7439-92-112/12/15 00:0010.0 2.5 1
Manganese 68.5 ug/L 12/17/15 03:41 7439-96-512/12/15 00:0050.0 2.5 1
Nickel 2.5J ug/L 12/17/15 03:41 7440-02-012/12/15 00:0050.0 2.5 1
Selenium ND ug/L 12/17/15 03:41 7782-49-212/12/15 00:0010.0 5.0 1
Silver ND ug/L 12/17/15 03:41 7440-22-412/12/15 00:0010.0 2.5 1
Thallium ND ug/L 12/17/15 03:41 7440-28-012/12/15 00:005.5 5.0 1
Vanadium 6.9J ug/L 12/17/15 03:41 7440-62-212/12/15 00:0025.0 2.5 1
Zinc 10.3 ug/L 12/17/15 03:41 7440-66-612/12/15 00:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/19/15 14:43 7439-97-612/17/15 16:150.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/19/15 15:57 67-64-110010.0 1
Acrylonitrile ND ug/L 12/19/15 15:57 107-13-12001.9 1
Benzene ND ug/L 12/19/15 15:57 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/19/15 15:57 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/19/15 15:57 75-27-41.0 0.18 1
Bromoform ND ug/L 12/19/15 15:57 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/19/15 15:57 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/19/15 15:57 78-93-31000.96 1
Carbon disulfide ND ug/L 12/19/15 15:57 75-15-01001.2 1
Carbon tetrachloride ND ug/L 12/19/15 15:57 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/19/15 15:57 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/19/15 15:57 75-00-310.0 0.54 1
Chloroform ND ug/L 12/19/15 15:57 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/19/15 15:57 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/19/15 15:57 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/19/15 15:57 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/19/15 15:57 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/19/15 15:57 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/19/15 15:57 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 12/19/15 15:57 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/19/15 15:57 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 12/19/15 15:57 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/19/15 15:57 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/19/15 15:57 75-35-45.0 0.56 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Sample:1203-MW20 Lab ID:92279397001 Collected:12/08/15 15:30 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,2-Dichloroethene ND ug/L 12/19/15 15:57 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/19/15 15:57 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/19/15 15:57 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/19/15 15:57 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/19/15 15:57 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/19/15 15:57 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/19/15 15:57 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/19/15 15:57 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 12/19/15 15:57 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/19/15 15:57 108-10-11000.33 1
Styrene ND ug/L 12/19/15 15:57 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/19/15 15:57 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/19/15 15:57 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/19/15 15:57 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/19/15 15:57 109-99-910.0 3.1 1
Toluene ND ug/L 12/19/15 15:57 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/19/15 15:57 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/19/15 15:57 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/19/15 15:57 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/19/15 15:57 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/19/15 15:57 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/19/15 15:57 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/19/15 15:57 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/19/15 15:57 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)103 %12/19/15 15:57 460-00-470-130 1
1,2-Dichloroethane-d4 (S)93 %12/19/15 15:57 17060-07-070-130 1
Toluene-d8 (S)108 %12/19/15 15:57 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 8280 ug/L 12/14/15 23:43500010001
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 31000 ug/L 12/11/15 10:4425000250001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate ND ug/L 12/11/15 14:06 14808-79-825000010001
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 1840 ug/L 12/18/15 17:57 16887-00-610005001
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Sample:1203-MW22S Lab ID:92279397002 Collected:12/09/15 15:00 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/17/15 03:44 7440-36-012/12/15 00:006.0 3.8 1
Arsenic 12.7 ug/L 12/17/15 03:44 7440-38-212/12/15 00:0010.0 2.5 1
Barium 1110 ug/L 12/17/15 03:44 7440-39-312/12/15 00:001002.5 1
Beryllium 3.4 ug/L 12/17/15 03:44 7440-41-712/12/15 00:001.0 0.50 1
Cadmium ND ug/L 12/17/15 03:44 7440-43-912/12/15 00:001.0 0.50 1
Chromium 16.8 ug/L 12/17/15 03:44 7440-47-312/12/15 00:0010.0 2.5 1
Cobalt 11.2 ug/L 12/17/15 03:44 7440-48-412/12/15 00:0010.0 2.5 1
Copper 30.0 ug/L 12/17/15 03:44 7440-50-812/12/15 00:0010.0 2.5 1
Iron 29700 ug/L 12/17/15 03:44 7439-89-612/12/15 00:0030025.0 1
Lead 39.4 ug/L 12/17/15 03:44 7439-92-112/12/15 00:0010.0 2.5 1
Manganese 462 ug/L 12/17/15 03:44 7439-96-512/12/15 00:0050.0 2.5 1
Nickel 18.7J ug/L 12/17/15 03:44 7440-02-012/12/15 00:0050.0 2.5 1
Selenium ND ug/L 12/17/15 03:44 7782-49-212/12/15 00:0010.0 5.0 1
Silver ND ug/L 12/17/15 03:44 7440-22-412/12/15 00:0010.0 2.5 1
Thallium ND ug/L 12/17/15 03:44 7440-28-012/12/15 00:005.5 5.0 1
Vanadium 44.8 ug/L 12/17/15 03:44 7440-62-212/12/15 00:0025.0 2.5 1
Zinc 127 ug/L 12/17/15 03:44 7440-66-612/12/15 00:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/19/15 14:45 7439-97-612/17/15 16:150.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/20/15 22:46 67-64-110010.0 1
Acrylonitrile ND ug/L 12/20/15 22:46 107-13-12001.9 1
Benzene ND ug/L 12/20/15 22:46 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/20/15 22:46 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/20/15 22:46 75-27-41.0 0.18 1
Bromoform ND ug/L 12/20/15 22:46 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/20/15 22:46 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/20/15 22:46 78-93-31000.96 1
Carbon disulfide ND ug/L 12/20/15 22:46 75-15-01001.2 1
Carbon tetrachloride ND ug/L 12/20/15 22:46 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/20/15 22:46 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/20/15 22:46 75-00-310.0 0.54 1
Chloroform ND ug/L 12/20/15 22:46 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/20/15 22:46 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/20/15 22:46 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/20/15 22:46 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/20/15 22:46 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/20/15 22:46 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/20/15 22:46 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 12/20/15 22:46 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/20/15 22:46 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 12/20/15 22:46 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/20/15 22:46 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/20/15 22:46 75-35-45.0 0.56 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Sample:1203-MW22S Lab ID:92279397002 Collected:12/09/15 15:00 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,2-Dichloroethene ND ug/L 12/20/15 22:46 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/20/15 22:46 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/20/15 22:46 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/20/15 22:46 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/20/15 22:46 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/20/15 22:46 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/20/15 22:46 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/20/15 22:46 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 12/20/15 22:46 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/20/15 22:46 108-10-11000.33 1
Styrene ND ug/L 12/20/15 22:46 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/20/15 22:46 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/20/15 22:46 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/20/15 22:46 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/20/15 22:46 109-99-910.0 3.1 1
Toluene ND ug/L 12/20/15 22:46 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/20/15 22:46 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/20/15 22:46 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/20/15 22:46 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/20/15 22:46 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/20/15 22:46 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/20/15 22:46 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/20/15 22:46 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/20/15 22:46 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %12/20/15 22:46 460-00-470-130 1
1,2-Dichloroethane-d4 (S)97 %12/20/15 22:46 17060-07-070-130 1
Toluene-d8 (S)106 %12/20/15 22:46 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 6670 ug/L 12/20/15 22:14500010001
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 96000 ug/L 12/14/15 08:3150000500001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate ND ug/L 12/11/15 14:06 14808-79-825000010001
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 4200 ug/L 12/18/15 17:58 16887-00-610005001
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Sample:1203-MW38 Lab ID:92279397003 Collected:12/09/15 14:30 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/17/15 03:47 7440-36-012/12/15 00:006.0 3.8 1
Arsenic 4.9J ug/L 12/17/15 03:47 7440-38-212/12/15 00:0010.0 2.5 1
Barium 83.5J ug/L 12/17/15 03:47 7440-39-312/12/15 00:001002.5 1
Beryllium ND ug/L 12/17/15 03:47 7440-41-712/12/15 00:001.0 0.50 1
Cadmium ND ug/L 12/17/15 03:47 7440-43-912/12/15 00:001.0 0.50 1
Chromium ND ug/L 12/17/15 03:47 7440-47-312/12/15 00:0010.0 2.5 1
Cobalt 4.1J ug/L 12/17/15 03:47 7440-48-412/12/15 00:0010.0 2.5 1
Copper 3.3J ug/L 12/17/15 03:47 7440-50-812/12/15 00:0010.0 2.5 1
Iron 27800 ug/L 12/17/15 03:47 7439-89-612/12/15 00:0030025.0 1
Lead 3.2J ug/L 12/17/15 03:47 7439-92-112/12/15 00:0010.0 2.5 1
Manganese 3220 ug/L 12/17/15 03:47 7439-96-512/12/15 00:0050.0 2.5 1
Nickel 3.0J ug/L 12/17/15 03:47 7440-02-012/12/15 00:0050.0 2.5 1
Selenium ND ug/L 12/17/15 03:47 7782-49-212/12/15 00:0010.0 5.0 1
Silver ND ug/L 12/17/15 03:47 7440-22-412/12/15 00:0010.0 2.5 1
Thallium ND ug/L 12/17/15 03:47 7440-28-012/12/15 00:005.5 5.0 1
Vanadium 8.5J ug/L 12/17/15 03:47 7440-62-212/12/15 00:0025.0 2.5 1
Zinc 8.7J ug/L 12/17/15 03:47 7440-66-612/12/15 00:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/19/15 14:48 7439-97-612/17/15 16:150.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/20/15 23:03 67-64-110010.0 1
Acrylonitrile ND ug/L 12/20/15 23:03 107-13-12001.9 1
Benzene 4.4 ug/L 12/20/15 23:03 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/20/15 23:03 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/20/15 23:03 75-27-41.0 0.18 1
Bromoform ND ug/L 12/20/15 23:03 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/20/15 23:03 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/20/15 23:03 78-93-31000.96 1
Carbon disulfide ND ug/L 12/20/15 23:03 75-15-01001.2 1
Carbon tetrachloride ND ug/L 12/20/15 23:03 56-23-51.0 0.25 1
Chlorobenzene 0.49J ug/L 12/20/15 23:03 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/20/15 23:03 75-00-310.0 0.54 1
Chloroform ND ug/L 12/20/15 23:03 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/20/15 23:03 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/20/15 23:03 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/20/15 23:03 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/20/15 23:03 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/20/15 23:03 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/20/15 23:03 95-50-15.0 0.30 1
1,4-Dichlorobenzene 12.2 ug/L 12/20/15 23:03 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/20/15 23:03 110-57-61001.0 1
1,1-Dichloroethane 7.2 ug/L 12/20/15 23:03 75-34-35.0 0.32 1
1,2-Dichloroethane 0.70J ug/L 12/20/15 23:03 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/20/15 23:03 75-35-45.0 0.56 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Sample:1203-MW38 Lab ID:92279397003 Collected:12/09/15 14:30 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,2-Dichloroethene 14.7 ug/L 12/20/15 23:03 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/20/15 23:03 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/20/15 23:03 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/20/15 23:03 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/20/15 23:03 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/20/15 23:03 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/20/15 23:03 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/20/15 23:03 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 12/20/15 23:03 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/20/15 23:03 108-10-11000.33 1
Styrene ND ug/L 12/20/15 23:03 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/20/15 23:03 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/20/15 23:03 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/20/15 23:03 127-18-41.0 0.46 1
Tetrahydrofuran 39.1 ug/L 12/20/15 23:03 109-99-910.0 3.1 1
Toluene ND ug/L 12/20/15 23:03 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/20/15 23:03 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/20/15 23:03 79-00-51.0 0.29 1
Trichloroethene 2.1 ug/L 12/20/15 23:03 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/20/15 23:03 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/20/15 23:03 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/20/15 23:03 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/20/15 23:03 75-01-41.0 0.62 1
Xylene (Total)1.6J ug/L 12/20/15 23:03 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)102 %12/20/15 23:03 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %12/20/15 23:03 17060-07-070-130 1
Toluene-d8 (S)107 %12/20/15 23:03 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 234000 ug/L 12/20/15 22:23500010001
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 311000 ug/L 12/14/15 08:3125000250001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 4640J ug/L 12/11/15 14:06 14808-79-825000010001
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 4390 ug/L 12/18/15 17:58 16887-00-610005001
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/8789
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples:92279397001, 92279397002, 92279397003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1629752
Associated Lab Samples:92279397001, 92279397002, 92279397003
Matrix:Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/19/15 14:310.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1629753LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1629754MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279395006
1629755
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 100 75-12596 3 252.5ND 2.5 2.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20262
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92279397001, 92279397002, 92279397003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1627237
Associated Lab Samples:92279397001, 92279397002, 92279397003
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 12/17/15 02:173.8
Arsenic ug/L ND 10.0 12/17/15 02:172.5
Barium ug/L ND 100 12/17/15 02:172.5
Beryllium ug/L ND 1.0 12/17/15 02:170.50
Cadmium ug/L ND 1.0 12/17/15 02:170.50
Chromium ug/L ND 10.0 12/17/15 02:172.5
Cobalt ug/L ND 10.0 12/17/15 02:172.5
Copper ug/L ND 10.0 12/17/15 02:172.5
Iron ug/L ND 300 12/17/15 02:1725.0
Lead ug/L ND 10.0 12/17/15 02:172.5
Manganese ug/L ND 50.0 12/17/15 02:172.5
Nickel ug/L ND 50.0 12/17/15 02:172.5
Selenium ug/L ND 10.0 12/17/15 02:175.0
Silver ug/L ND 10.0 12/17/15 02:172.5
Thallium ug/L ND 5.5 12/17/15 02:175.0
Vanadium ug/L ND 25.0 12/17/15 02:172.5
Zinc ug/L ND 10.0 12/17/15 02:175.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1627238LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 587500 117 80-120
Arsenic ug/L 523500 105 80-120
Barium ug/L 532500 106 80-120
Beryllium ug/L 525500 105 80-120
Cadmium ug/L 542500 108 80-120
Chromium ug/L 514500 103 80-120
Cobalt ug/L 546500 109 80-120
Copper ug/L 524500 105 80-120
Iron ug/L 54205000 108 80-120
Lead ug/L 539500 108 80-120
Manganese ug/L 562500 112 80-120
Nickel ug/L 542500 108 80-120
Selenium ug/L 541500 108 80-120
Silver ug/L 275250 110 80-120
Thallium ug/L 516500 103 80-120
Vanadium ug/L 570500 114 80-120
Zinc ug/L 550500 110 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1627239MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279385001
1627240
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 107 75-125109 2 25500ND537545
Arsenic ug/L 500 95 75-12598 2 25500ND479490
Barium ug/L 500 99 75-125100 0 25500109605608
Beryllium ug/L 500 98 75-12599 1 25500ND490494
Cadmium ug/L 500 99 75-125101 2 25500ND496504
Chromium ug/L 500 94 75-12595 1 25500ND471478
Cobalt ug/L 500 101 75-125102 1 2550052.0 555 560
Copper ug/L 500 99 75-125100 2 255007.9J 501 510
Iron ug/L 5000 124 75-12585 3 255000558006200060000
Lead ug/L 500 98 75-125100 2 255004.6J 494 502
Manganese ug/L 500 117 75-12594 3 25500347040603940
Nickel ug/L 500 99 75-125101 1 255002.6J 499 505
Selenium ug/L 500 99 75-125101 2 25500ND496505
Silver ug/L 250 102 75-125103 1 25250ND255258
Thallium ug/L 500 92 75-12596 4 255006.9 469 486
Vanadium ug/L 500 107 75-125107 1 255008.3J 541 544
Zinc ug/L 500 102 75-125103 0 255006.5J 517 520
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34799
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92279397001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1633901
Associated Lab Samples:92279397001
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 12/19/15 13:250.33
1,1,1-Trichloroethane ug/L ND 1.0 12/19/15 13:250.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 12/19/15 13:250.40
1,1,2-Trichloroethane ug/L ND 1.0 12/19/15 13:250.29
1,1-Dichloroethane ug/L ND 5.0 12/19/15 13:250.32
1,1-Dichloroethene ug/L ND 5.0 12/19/15 13:250.56
1,2,3-Trichloropropane ug/L ND 1.0 12/19/15 13:250.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 12/19/15 13:252.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/19/15 13:250.27
1,2-Dichlorobenzene ug/L ND 5.0 12/19/15 13:250.30
1,2-Dichloroethane ug/L ND 1.0 12/19/15 13:250.24
1,2-Dichloropropane ug/L ND 1.0 12/19/15 13:250.27
1,4-Dichlorobenzene ug/L ND 1.0 12/19/15 13:250.33
2-Butanone (MEK)ug/L ND 100 12/19/15 13:250.96
2-Hexanone ug/L ND 50.0 12/19/15 13:250.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 12/19/15 13:250.33
Acetone ug/L ND 100 12/19/15 13:2510.0
Acrylonitrile ug/L ND 200 12/19/15 13:251.9
Benzene ug/L ND 1.0 12/19/15 13:250.25
Bromochloromethane ug/L ND 3.0 12/19/15 13:250.17
Bromodichloromethane ug/L ND 1.0 12/19/15 13:250.18
Bromoform ug/L ND 3.0 12/19/15 13:250.26
Bromomethane ug/L ND 10.0 12/19/15 13:250.29
Carbon disulfide ug/L ND 100 12/19/15 13:251.2
Carbon tetrachloride ug/L ND 1.0 12/19/15 13:250.25
Chlorobenzene ug/L ND 3.0 12/19/15 13:250.23
Chloroethane ug/L ND 10.0 12/19/15 13:250.54
Chloroform ug/L ND 5.0 12/19/15 13:250.14
Chloromethane ug/L ND 1.0 12/19/15 13:250.11
cis-1,2-Dichloroethene ug/L ND 5.0 12/19/15 13:250.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/19/15 13:250.13
Dibromochloromethane ug/L ND 3.0 12/19/15 13:250.21
Dibromomethane ug/L ND 10.0 12/19/15 13:250.21
Ethylbenzene ug/L ND 1.0 12/19/15 13:250.30
Iodomethane ug/L ND 10.0 12/19/15 13:250.32
Methylene Chloride ug/L ND 1.0 12/19/15 13:250.97
Styrene ug/L ND 1.0 12/19/15 13:250.26
Tetrachloroethene ug/L ND 1.0 12/19/15 13:250.46
Tetrahydrofuran ug/L ND 10.0 12/19/15 13:253.1
Toluene ug/L ND 1.0 12/19/15 13:250.26
trans-1,2-Dichloroethene ug/L ND 5.0 12/19/15 13:250.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1633901
Associated Lab Samples:92279397001
Matrix:Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 12/19/15 13:250.26
trans-1,4-Dichloro-2-butene ug/L ND 100 12/19/15 13:251.0
Trichloroethene ug/L ND 1.0 12/19/15 13:250.47
Trichlorofluoromethane ug/L ND 1.0 12/19/15 13:250.20
Vinyl acetate ug/L ND 50.0 12/19/15 13:250.35
Vinyl chloride ug/L ND 1.0 12/19/15 13:250.62
Xylene (Total)ug/L ND 5.0 12/19/15 13:250.66
1,2-Dichloroethane-d4 (S)%102 70-130 12/19/15 13:25
4-Bromofluorobenzene (S)%102 70-130 12/19/15 13:25
Toluene-d8 (S)%110 70-130 12/19/15 13:25
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1633902LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 52.650 105 80-125
1,1,1-Trichloroethane ug/L 55.250 110 71-129
1,1,2,2-Tetrachloroethane ug/L 52.850 106 79-124
1,1,2-Trichloroethane ug/L 53.550 107 85-125
1,1-Dichloroethane ug/L 49.350 99 73-126
1,1-Dichloroethene ug/L 54.250 108 66-135
1,2,3-Trichloropropane ug/L 50.950 102 75-130
1,2-Dibromo-3-chloropropane ug/L 50.950 102 71-133
1,2-Dibromoethane (EDB)ug/L 55.650 111 83-124
1,2-Dichlorobenzene ug/L 51.650 103 80-133
1,2-Dichloroethane ug/L 50.150 100 67-128
1,2-Dichloropropane ug/L 49.050 98 75-132
1,4-Dichlorobenzene ug/L 53.050 106 78-130
2-Butanone (MEK)ug/L 109100 109 61-144
2-Hexanone ug/L 104100 104 68-143
4-Methyl-2-pentanone (MIBK)ug/L 99.9J100 100 72-135
Acetone ug/L 107100 107 48-146
Acrylonitrile ug/L 263250 105 40-160
Benzene ug/L 52.150 104 80-125
Bromochloromethane ug/L 59.350 119 71-125
Bromodichloromethane ug/L 54.550 109 78-124
Bromoform ug/L 44.150 88 71-128
Bromomethane ug/L 45.450 91 40-160
Carbon disulfide ug/L 55.0J50 110 50-160
Carbon tetrachloride ug/L 53.350 107 69-131
Chlorobenzene ug/L 53.950 108 81-122
Chloroethane ug/L 48.350 97 39-148
Chloroform ug/L 55.350 111 73-127
Chloromethane ug/L 55.950 112 44-146
cis-1,2-Dichloroethene ug/L 51.550 103 74-124
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1633902LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,3-Dichloropropene ug/L 56.550 113 72-132
Dibromochloromethane ug/L 54.550 109 78-125
Dibromomethane ug/L 53.250 106 82-120
Ethylbenzene ug/L 52.950 106 79-121
Iodomethane ug/L 88.7100 89 39-154
Methylene Chloride ug/L 59.250 118 64-133
Styrene ug/L 53.250 106 84-126
Tetrachloroethene ug/L 53.650 107 78-122
Tetrahydrofuran ug/L 549500 110 69-148
Toluene ug/L 49.950 100 80-121
trans-1,2-Dichloroethene ug/L 51.550 103 71-127
trans-1,3-Dichloropropene ug/L 52.150 104 69-141
trans-1,4-Dichloro-2-butene ug/L 54.8J50 110 40-160
Trichloroethene ug/L 55.350 111 78-122
Trichlorofluoromethane ug/L 50.850 102 53-137
Vinyl acetate ug/L 104100 104 40-160
Vinyl chloride ug/L 55.350 111 58-137
Xylene (Total)ug/L 158150 106 81-126
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%104 70-130
Toluene-d8 (S)%96 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1633904MATRIX SPIKE SAMPLE:
MSSpike
Result
92279300003
1,1,1,2-Tetrachloroethane ug/L 15.420 77 70-130ND
1,1,1-Trichloroethane ug/L 19.820 99 70-130ND
1,1,2,2-Tetrachloroethane ug/L 16.820 84 70-130ND
1,1,2-Trichloroethane ug/L 16.820 84 70-130ND
1,1-Dichloroethane ug/L 19.420 97 70-130ND
1,1-Dichloroethene ug/L 18.920 94 70-166ND
1,2,3-Trichloropropane ug/L 17.620 88 70-130ND
1,2-Dibromo-3-chloropropane ug/L 15.820 79 70-130ND
1,2-Dibromoethane (EDB)ug/L 16.520 82 70-130ND
1,2-Dichlorobenzene ug/L 17.620 88 70-130ND
1,2-Dichloroethane ug/L 17.420 87 70-130ND
1,2-Dichloropropane ug/L 17.620 88 70-130ND
1,4-Dichlorobenzene ug/L 17.220 86 70-130ND
2-Butanone (MEK)ug/L 36.4J40 91 70-130ND
2-Hexanone ug/L 33.6J40 84 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 36.3J40 91 70-130ND
Acetone ug/L 39.6J40 99 70-130ND
Acrylonitrile ug/L 95.0J100 95 70-130ND
Benzene ug/L 18.620 93 70-148ND
Bromochloromethane ug/L 22.420 112 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1633904MATRIX SPIKE SAMPLE:
MSSpike
Result
92279300003
Bromodichloromethane ug/L 17.520 87 70-130ND
Bromoform ug/L 15.420 77 70-130ND
Bromomethane ug/L 16.920 84 70-130ND
Carbon disulfide ug/L 19.8J20 99 70-130ND
Carbon tetrachloride ug/L 18.320 91 70-130ND
Chlorobenzene ug/L 18.120 90 70-146ND
Chloroethane ug/L 16.220 81 70-130ND
Chloroform ug/L 19.820 99 70-130ND
Chloromethane ug/L 23.020 115 70-130ND
cis-1,2-Dichloroethene ug/L 18.720 94 70-130ND
cis-1,3-Dichloropropene ug/L 17.420 87 70-130ND
Dibromochloromethane ug/L 15.320 77 70-130ND
Dibromomethane ug/L 19.720 98 70-130ND
Ethylbenzene ug/L 17.520 87 70-130ND
Iodomethane ug/L 28.340 71 70-130ND
Methylene Chloride ug/L 20.820 104 70-130ND
Styrene ug/L 17.220 86 70-130ND
Tetrachloroethene ug/L 16.920 85 70-130ND
Tetrahydrofuran ug/L 186200 93 70-130ND
Toluene ug/L 19.220 96 70-155ND
trans-1,2-Dichloroethene ug/L 20.020 100 70-130ND
trans-1,3-Dichloropropene ug/L 15.620 78 70-130ND
trans-1,4-Dichloro-2-butene ug/L 16.1J20 81 70-130ND
Trichloroethene ug/L 18.120 91 69-151ND
Trichlorofluoromethane ug/L 17.420 87 70-130ND
Vinyl acetate ug/L 28.9J40 72 70-130ND
Vinyl chloride ug/L 20.320 102 70-130ND
1,2-Dichloroethane-d4 (S)%109 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%107 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92279300002
1633903SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92279300002
1633903SAMPLE DUPLICATE:
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Tetrahydrofuran ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%98 395
4-Bromofluorobenzene (S)%106 1104
Toluene-d8 (S)%109 2111
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34820
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92279397002, 92279397003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1634031
Associated Lab Samples:92279397002, 92279397003
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 12/20/15 18:490.33
1,1,1-Trichloroethane ug/L ND 1.0 12/20/15 18:490.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 12/20/15 18:490.40
1,1,2-Trichloroethane ug/L ND 1.0 12/20/15 18:490.29
1,1-Dichloroethane ug/L ND 5.0 12/20/15 18:490.32
1,1-Dichloroethene ug/L ND 5.0 12/20/15 18:490.56
1,2,3-Trichloropropane ug/L ND 1.0 12/20/15 18:490.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 12/20/15 18:492.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/20/15 18:490.27
1,2-Dichlorobenzene ug/L ND 5.0 12/20/15 18:490.30
1,2-Dichloroethane ug/L ND 1.0 12/20/15 18:490.24
1,2-Dichloropropane ug/L ND 1.0 12/20/15 18:490.27
1,4-Dichlorobenzene ug/L ND 1.0 12/20/15 18:490.33
2-Butanone (MEK)ug/L ND 100 12/20/15 18:490.96
2-Hexanone ug/L ND 50.0 12/20/15 18:490.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 12/20/15 18:490.33
Acetone ug/L ND 100 12/20/15 18:4910.0
Acrylonitrile ug/L ND 200 12/20/15 18:491.9
Benzene ug/L ND 1.0 12/20/15 18:490.25
Bromochloromethane ug/L ND 3.0 12/20/15 18:490.17
Bromodichloromethane ug/L ND 1.0 12/20/15 18:490.18
Bromoform ug/L ND 3.0 12/20/15 18:490.26
Bromomethane ug/L ND 10.0 12/20/15 18:490.29
Carbon disulfide ug/L ND 100 12/20/15 18:491.2
Carbon tetrachloride ug/L ND 1.0 12/20/15 18:490.25
Chlorobenzene ug/L ND 3.0 12/20/15 18:490.23
Chloroethane ug/L ND 10.0 12/20/15 18:490.54
Chloroform ug/L ND 5.0 12/20/15 18:490.14
Chloromethane ug/L ND 1.0 12/20/15 18:490.11
cis-1,2-Dichloroethene ug/L ND 5.0 12/20/15 18:490.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/20/15 18:490.13
Dibromochloromethane ug/L ND 3.0 12/20/15 18:490.21
Dibromomethane ug/L ND 10.0 12/20/15 18:490.21
Ethylbenzene ug/L ND 1.0 12/20/15 18:490.30
Iodomethane ug/L ND 10.0 12/20/15 18:490.32
Methylene Chloride ug/L ND 1.0 12/20/15 18:490.97
Styrene ug/L ND 1.0 12/20/15 18:490.26
Tetrachloroethene ug/L ND 1.0 12/20/15 18:490.46
Tetrahydrofuran ug/L ND 10.0 12/20/15 18:493.1
Toluene ug/L ND 1.0 12/20/15 18:490.26
trans-1,2-Dichloroethene ug/L ND 5.0 12/20/15 18:490.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1634031
Associated Lab Samples:92279397002, 92279397003
Matrix:Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 12/20/15 18:490.26
trans-1,4-Dichloro-2-butene ug/L ND 100 12/20/15 18:491.0
Trichloroethene ug/L ND 1.0 12/20/15 18:490.47
Trichlorofluoromethane ug/L ND 1.0 12/20/15 18:490.20
Vinyl acetate ug/L ND 50.0 12/20/15 18:490.35
Vinyl chloride ug/L ND 1.0 12/20/15 18:490.62
Xylene (Total)ug/L ND 5.0 12/20/15 18:490.66
1,2-Dichloroethane-d4 (S)%92 70-130 12/20/15 18:49
4-Bromofluorobenzene (S)%102 70-130 12/20/15 18:49
Toluene-d8 (S)%111 70-130 12/20/15 18:49
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1634032LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.050 100 80-125
1,1,1-Trichloroethane ug/L 52.550 105 71-129
1,1,2,2-Tetrachloroethane ug/L 50.050 100 79-124
1,1,2-Trichloroethane ug/L 52.350 105 85-125
1,1-Dichloroethane ug/L 47.950 96 73-126
1,1-Dichloroethene ug/L 48.150 96 66-135
1,2,3-Trichloropropane ug/L 51.150 102 75-130
1,2-Dibromo-3-chloropropane ug/L 47.950 96 71-133
1,2-Dibromoethane (EDB)ug/L 53.950 108 83-124
1,2-Dichlorobenzene ug/L 47.150 94 80-133
1,2-Dichloroethane ug/L 45.250 90 67-128
1,2-Dichloropropane ug/L 48.250 96 75-132
1,4-Dichlorobenzene ug/L 49.650 99 78-130
2-Butanone (MEK)ug/L 109100 109 61-144
2-Hexanone ug/L 99.3100 99 68-143
4-Methyl-2-pentanone (MIBK)ug/L 101100 101 72-135
Acetone ug/L 104100 104 48-146
Acrylonitrile ug/L 260250 104 40-160
Benzene ug/L 53.550 107 80-125
Bromochloromethane ug/L 53.350 107 71-125
Bromodichloromethane ug/L 49.450 99 78-124
Bromoform ug/L 40.350 81 71-128
Bromomethane ug/L 40.050 80 40-160
Carbon disulfide ug/L 50.5J50 101 50-160
Carbon tetrachloride ug/L 50.350 101 69-131
Chlorobenzene ug/L 49.350 99 81-122
Chloroethane ug/L 43.650 87 39-148
Chloroform ug/L 49.850 100 73-127
Chloromethane ug/L 50.050 100 44-146
cis-1,2-Dichloroethene ug/L 48.350 97 74-124
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1634032LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,3-Dichloropropene ug/L 52.650 105 72-132
Dibromochloromethane ug/L 51.250 102 78-125
Dibromomethane ug/L 52.250 104 82-120
Ethylbenzene ug/L 48.950 98 79-121
Iodomethane ug/L 78.3100 78 39-154
Methylene Chloride ug/L 58.350 117 64-133
Styrene ug/L 49.450 99 84-126
Tetrachloroethene ug/L 48.950 98 78-122
Tetrahydrofuran ug/L 540500 108 69-148
Toluene ug/L 48.650 97 80-121
trans-1,2-Dichloroethene ug/L 50.150 100 71-127
trans-1,3-Dichloropropene ug/L 49.850 100 69-141
trans-1,4-Dichloro-2-butene ug/L 46.0J50 92 40-160
Trichloroethene ug/L 52.950 106 78-122
Trichlorofluoromethane ug/L 46.350 93 53-137
Vinyl acetate ug/L 101100 101 40-160
Vinyl chloride ug/L 50.050 100 58-137
Xylene (Total)ug/L 144150 96 81-126
1,2-Dichloroethane-d4 (S)%102 70-130
4-Bromofluorobenzene (S)%105 70-130
Toluene-d8 (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/41954
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92279397001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1628043
Associated Lab Samples:92279397001
Matrix:Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 12/14/15 18:561000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1628044LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 4940050000 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1628045MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279416001
1628046
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 103 80-12099 2 255000048.1 mg/L 99300 97700
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1628047MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279423004
1628048
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 100 80-12099 1 2550000ND5000049400
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/42069
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92279397002, 92279397003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1633336
Associated Lab Samples:92279397002, 92279397003
Matrix:Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 12/20/15 16:531000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1633337LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 4700050000 94 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1633338MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279931011
1633339
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 95 80-12096 0 255000093.5 mg/L 141000 141000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1633340MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279294036
1633341
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 96 80-12097 1 255000030.2 mg/L 78100 78900
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/41916
SM 2540C
SM 2540C
2540C Total Dissolved Solids
Associated Lab Samples:92279397001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1626642
Associated Lab Samples:92279397001
Matrix:Water
AnalyzedMDL
Total Dissolved Solids ug/L ND 25000 12/11/15 10:3925000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1626643LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids ug/L 246000250000 98 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92279178001
1626644SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 316000 4 5330 mg/L
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278979001
1626645SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 320000 D675299 mg/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/41951
SM 2540C
SM 2540C
2540C Total Dissolved Solids
Associated Lab Samples:92279397002, 92279397003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1628031
Associated Lab Samples:92279397002, 92279397003
Matrix:Water
AnalyzedMDL
Total Dissolved Solids ug/L ND 25000 12/14/15 08:2725000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1628032LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids ug/L 240000250000 96 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92279196004
1628033SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 66000 3 568.0 mg/L
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92279407001
1628034SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 69000 D68564.0 mg/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/25748
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples:92279397001, 92279397002, 92279397003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1626618
Associated Lab Samples:92279397001, 92279397002, 92279397003
Matrix:Water
AnalyzedMDL
Sulfate ug/L ND 250000 12/11/15 14:061000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1626619LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 21000J20000 105 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1626620MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278963003
1626621
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 103 90-110103 1 102000010.1 mg/L 30600J 30800J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1626622MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279395006
1626623
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 102 90-110104 1 10200009260J29800J30100J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/25851
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples:92279397001, 92279397002, 92279397003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1633380
Associated Lab Samples:92279397001, 92279397002, 92279397003
Matrix:Water
AnalyzedMDL
Chloride ug/L ND 1000 12/18/15 17:52500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1633381LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 1990020000 99 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1633382MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92280333001
1633383
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L 20000 101 90-110101 0 10200003.0 mg/L 23300 23200
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1633384MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279763005
1633385
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M11000006890-11068 0 1010000063.2 mg/L 132000 131000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 33
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.D6
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 33
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92279397
BURKE-JOHN'S R.-PHASE 1A COMPL
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92279397001 MPRP/20262 ICP/182921203-MW20 EPA 3010A EPA 6010
92279397002 MPRP/20262 ICP/182921203-MW22S EPA 3010A EPA 6010
92279397003 MPRP/20262 ICP/182921203-MW38 EPA 3010A EPA 6010
92279397001 MERP/8789 MERC/84441203-MW20 EPA 7470 EPA 7470
92279397002 MERP/8789 MERC/84441203-MW22S EPA 7470 EPA 7470
92279397003 MERP/8789 MERC/84441203-MW38 EPA 7470 EPA 7470
92279397001 MSV/347991203-MW20 EPA 8260
92279397002 MSV/348201203-MW22S EPA 8260
92279397003 MSV/348201203-MW38 EPA 8260
92279397001 WET/419541203-MW20 SM 2320B
92279397002 WET/420691203-MW22S SM 2320B
92279397003 WET/420691203-MW38 SM 2320B
92279397001 WET/419161203-MW20 SM 2540C
92279397002 WET/419511203-MW22S SM 2540C
92279397003 WET/419511203-MW38 SM 2540C
92279397001 WETA/257481203-MW20 EPA 300.0
92279397002 WETA/257481203-MW22S EPA 300.0
92279397003 WETA/257481203-MW38 EPA 300.0
92279397001 WETA/258511203-MW20 SM 4500-Cl-E
92279397002 WETA/258511203-MW22S SM 4500-Cl-E
92279397003 WETA/258511203-MW38 SM 4500-Cl-E
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 33
Page 32 of 33
Page 33 of 33
#=CL#
February 12, 2016
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92285595
92285595
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
JOHN'S R PH 1A RESAMPLE
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on February 05, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc:Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 12
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92285595
JOHN'S R PH 1A RESAMPLE
Asheville Certification IDs2225 Riverside Drive, Asheville, NC 28804Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 12
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92285595
JOHN'S R PH 1A RESAMPLE
Lab ID Sample ID Matrix Date Collected Date Received
92285595001 1203-MW22S Water 02/04/16 13:42 02/05/16 13:35
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 12
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92285595
JOHN'S R PH 1A RESAMPLE
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92285595001 1203-MW22S EPA 6010 17 PASI-ACDF
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 12
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92285595
JOHN'S R PH 1A RESAMPLE
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92285595001 1203-MW22S
Arsenic 5.8J ug/L 02/10/16 22:1110.0EPA 6010
Barium 264 ug/L 02/10/16 22:11100EPA 6010
Beryllium 0.83J ug/L 02/10/16 22:111.0EPA 6010
Chromium 6.6J ug/L 02/10/16 22:1110.0EPA 6010
Cobalt 3.2J ug/L 02/10/16 22:1110.0EPA 6010
Copper 10.4 ug/L 02/10/16 22:1110.0EPA 6010
Iron 9840 ug/L 02/10/16 22:11300EPA 6010
Lead 10.5 ug/L 02/10/16 22:1110.0EPA 6010
Manganese 124 ug/L 02/10/16 22:1150.0EPA 6010
Nickel 5.7J ug/L 02/10/16 22:1150.0EPA 6010
Thallium 9.1 ug/L 02/11/16 17:245.5EPA 6010
Vanadium 16.0J ug/L 02/10/16 22:1125.0EPA 6010
Zinc 36.5 ug/L 02/10/16 22:1110.0EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 12
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92285595
JOHN'S R PH 1A RESAMPLE
Sample:1203-MW22S Lab ID:92285595001 Collected:02/04/16 13:42 Received:02/05/16 13:35 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 02/10/16 22:11 7440-36-002/09/16 16:006.0 3.8 1
Arsenic 5.8J ug/L 02/10/16 22:11 7440-38-202/09/16 16:0010.0 2.5 1
Barium 264 ug/L 02/10/16 22:11 7440-39-302/09/16 16:001002.5 1
Beryllium 0.83J ug/L 02/10/16 22:11 7440-41-702/09/16 16:001.0 0.50 1
Cadmium ND ug/L 02/10/16 22:11 7440-43-902/09/16 16:001.0 0.50 1
Chromium 6.6J ug/L 02/10/16 22:11 7440-47-302/09/16 16:0010.0 2.5 1
Cobalt 3.2J ug/L 02/10/16 22:11 7440-48-402/09/16 16:0010.0 2.5 1
Copper 10.4 ug/L 02/10/16 22:11 7440-50-802/09/16 16:0010.0 2.5 1
Iron 9840 ug/L 02/10/16 22:11 7439-89-602/09/16 16:0030025.0 1
Lead 10.5 ug/L 02/10/16 22:11 7439-92-102/09/16 16:0010.0 2.5 1
Manganese 124 ug/L 02/10/16 22:11 7439-96-502/09/16 16:0050.0 2.5 1
Nickel 5.7J ug/L 02/10/16 22:11 7440-02-002/09/16 16:0050.0 2.5 1
Selenium ND ug/L 02/10/16 22:11 7782-49-202/09/16 16:0010.0 5.0 1
Silver ND ug/L 02/10/16 22:11 7440-22-402/09/16 16:0010.0 2.5 1
Thallium 9.1 ug/L 02/11/16 17:24 7440-28-002/09/16 16:005.5 5.0 1
Vanadium 16.0J ug/L 02/10/16 22:11 7440-62-202/09/16 16:0025.0 2.5 1
Zinc 36.5 ug/L 02/10/16 22:11 7440-66-602/09/16 16:0010.0 5.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/12/2016 04:42 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 12
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92285595
JOHN'S R PH 1A RESAMPLE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20650
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92285595001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1662251
Associated Lab Samples:92285595001
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 02/10/16 21:383.8
Arsenic ug/L ND 10.0 02/10/16 21:382.5
Barium ug/L ND 100 02/10/16 21:382.5
Beryllium ug/L ND 1.0 02/10/16 21:380.50
Cadmium ug/L ND 1.0 02/10/16 21:380.50
Chromium ug/L ND 10.0 02/10/16 21:382.5
Cobalt ug/L ND 10.0 02/10/16 21:382.5
Copper ug/L ND 10.0 02/10/16 21:382.5
Iron ug/L ND 300 02/10/16 21:3825.0
Lead ug/L ND 10.0 02/11/16 17:092.5
Manganese ug/L ND 50.0 02/10/16 21:382.5
Nickel ug/L ND 50.0 02/10/16 21:382.5
Selenium ug/L ND 10.0 02/10/16 21:385.0
Silver ug/L ND 10.0 02/10/16 21:382.5
Thallium ug/L ND 5.5 02/10/16 21:385.0
Vanadium ug/L ND 25.0 02/10/16 21:382.5
Zinc ug/L ND 10.0 02/10/16 21:385.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1662252LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 514500 103 80-120
Arsenic ug/L 496500 99 80-120
Barium ug/L 497500 99 80-120
Beryllium ug/L 488500 98 80-120
Cadmium ug/L 504500 101 80-120
Chromium ug/L 494500 99 80-120
Cobalt ug/L 506500 101 80-120
Copper ug/L 508500 102 80-120
Iron ug/L 49005000 98 80-120
Lead ug/L 500500 100 80-120
Manganese ug/L 492500 98 80-120
Nickel ug/L 502500 100 80-120
Selenium ug/L 501500 100 80-120
Silver ug/L 248250 99 80-120
Thallium ug/L 508500 102 80-120
Vanadium ug/L 501500 100 80-120
Zinc ug/L 498500 100 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/12/2016 04:42 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 12
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92285595
JOHN'S R PH 1A RESAMPLE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1662253MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92285299001
1662254
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 99 75-12598 1 25500ND497494
Arsenic ug/L 500 92 75-12591 1 255007.3J 466 464
Barium ug/L 500 93 75-12594 1 2550038.0 505 508
Beryllium ug/L 500 93 75-12594 1 25500ND466469
Cadmium ug/L 500 96 75-12595 1 25500ND479476
Chromium ug/L 500 90 75-12589 1 25500ND450446
Cobalt ug/L 500 94 75-12593 0 25500ND469467
Copper ug/L 500 96 75-12595 1 25500ND478474
Iron ug/L M150005675-12572 1 255000700007280073600
Lead ug/L 500 92 75-12591 1 255008.1 467 462
Manganese ug/L 500 91 75-12591 0 25500207664663
Nickel ug/L 500 92 75-12592 1 25500ND462459
Selenium ug/L 500 96 75-12595 1 25500ND482477
Silver ug/L 250 91 75-12590 1 25250ND228225
Thallium ug/L 500 100 75-125102 2 2550010.9 512 521
Vanadium ug/L 500 96 75-12595 0 25500ND481480
Zinc ug/L 500 93 75-12593 0 255006.8J 473 472
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/12/2016 04:42 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 12
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92285595
JOHN'S R PH 1A RESAMPLE
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/12/2016 04:42 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 12
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92285595
JOHN'S R PH 1A RESAMPLE
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92285595001 MPRP/20650 ICP/186211203-MW22S EPA 3010A EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/12/2016 04:42 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 12
Page 11 of 12
Page 12 of 12
#=CL#
December 29, 2015
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92279347
92279347
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
BURKE CO. JOHN'S R-BG & BLANKS
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on December 10, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc:Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 58
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Ormond Beach Certification IDs8 East Tower Circle, Ormond Beach, FL 32174Alabama Certification #: 41320
Connecticut Certification #: PH-0216Delaware Certification: FL NELAC ReciprocityFlorida Certification #: E83079Georgia Certification #: 955Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC ReciprocityIllinois Certification #: 200068Indiana Certification: FL NELAC ReciprocityKansas Certification #: E-10383Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC ReciprocityLouisiana Environmental Certificate #: 05007Maryland Certification: #346Michigan Certification #: 9911Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958New York Certification #: 11608North Carolina Environmental Certificate #: 667North Carolina Certification #: 12710North Dakota Certification #: R-216
Oklahoma Certification #: D9947Pennsylvania Certification #: 68-00547Puerto Rico Certification #: FL01264South Carolina Certification: #96042001Tennessee Certification #: TN02974
Texas Certification: FL NELAC ReciprocityUS Virgin Islands Certification: FL NELAC ReciprocityVirginia Environmental Certification #: 460165West Virginia Certification #: 9962CWisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 58
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Lab ID Sample ID Matrix Date Collected Date Received
92279347001 1203-MW21 Water 12/08/15 11:20 12/10/15 10:45
92279347002 1203-FIELD BLANK Water 12/09/15 15:30 12/10/15 10:45
92279347003 1203-TRIP BLANK Water 12/08/15 00:00 12/10/15 10:45
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 58
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92279347001 1203-MW21 EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 18 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8270 111 PASI-CBPJ
EPA 8260 68 PASI-CGAW
SM 2320B 1 PASI-AMLS
SM 2540C 1 PASI-AMJP
SM 4500-S2D 1 PASI-AMJP
EPA 300.0 1 PASI-AMDW
SM 4500-Cl-E 1 PASI-AWRC
SM 4500-CN-E 1 PASI-AAES2
92279347002 1203-FIELD BLANK EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 18 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8270 111 PASI-CBPJ
EPA 8260 68 PASI-CGAW
SM 4500-S2D 1 PASI-ASAM
SM 4500-CN-E 1 PASI-AAES2
92279347003 1203-TRIP BLANK EPA 8260 68 PASI-CGAW
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 58
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92279347001 1203-MW21
Barium 17.6J ug/L 12/17/15 02:08100EPA 6010
Iron 1380 ug/L 12/17/15 02:08300EPA 6010
Manganese 50.0J ug/L 12/17/15 02:0850.0EPA 6010
Vanadium 6.6J ug/L 12/17/15 02:0825.0EPA 6010
Acrolein 1.6J ug/L 12/19/15 09:4553.0EPA 8260
Alkalinity, Total as CaCO3 1030J ug/L 12/14/15 15:095000SM 2320B
Chloride 859J ug/L 12/18/15 17:561000SM 4500-Cl-E
92279347002 1203-FIELD BLANK
Methylene Chloride 2.0 ug/L 12/20/15 21:21 C91.0EPA 8260
92279347003 1203-TRIP BLANK
Acrolein 2.8J ug/L 12/19/15 10:0253.0EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-MW21 Lab ID:92279347001 Collected:12/08/15 11:20 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 12/17/15 15:49 309-00-212/15/15 12:150.050 0.050 1
alpha-BHC ND ug/L 12/17/15 15:49 319-84-612/15/15 12:150.050 0.050 1
beta-BHC ND ug/L 12/17/15 15:49 319-85-712/15/15 12:150.050 0.050 1
delta-BHC ND ug/L 12/17/15 15:49 319-86-812/15/15 12:150.050 0.050 1
gamma-BHC (Lindane)ND ug/L 12/17/15 15:49 58-89-912/15/15 12:150.050 0.050 1
Chlordane (Technical)ND ug/L 12/17/15 15:49 57-74-912/15/15 12:150.50 0.20 1
4,4'-DDD ND ug/L 12/17/15 15:49 72-54-812/15/15 12:150.10 0.050 1
4,4'-DDE ND ug/L 12/17/15 15:49 72-55-912/15/15 12:150.10 0.050 1
4,4'-DDT ND ug/L 12/17/15 15:49 50-29-312/15/15 12:150.10 0.050 1
Dieldrin ND ug/L 12/17/15 15:49 60-57-112/15/15 12:150.075 0.050 1
Endosulfan I ND ug/L 12/17/15 15:49 959-98-812/15/15 12:150.10 0.050 1
Endosulfan II ND ug/L 12/17/15 15:49 33213-65-912/15/15 12:150.10 0.050 1
Endosulfan sulfate ND ug/L 12/17/15 15:49 1031-07-812/15/15 12:150.10 0.050 1
Endrin ND ug/L 12/17/15 15:49 72-20-812/15/15 12:150.10 0.050 1
Endrin aldehyde ND ug/L 12/17/15 15:49 7421-93-412/15/15 12:150.10 0.050 1
Heptachlor ND ug/L 12/17/15 15:49 76-44-812/15/15 12:150.050 0.050 1
Heptachlor epoxide ND ug/L 12/17/15 15:49 1024-57-312/15/15 12:150.075 0.050 1
Methoxychlor ND ug/L 12/17/15 15:49 72-43-512/15/15 12:151.0 0.15 1
Toxaphene ND ug/L 12/17/15 15:49 8001-35-212/15/15 12:151.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)74 %12/17/15 15:49 877-09-812/15/15 12:1520-130 1
Decachlorobiphenyl (S)62 %12/17/15 15:49 2051-24-312/15/15 12:1520-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 12/15/15 03:41 12674-11-212/13/15 12:530.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 12/15/15 03:41 11104-28-212/13/15 12:530.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 12/15/15 03:41 11141-16-512/13/15 12:530.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 12/15/15 03:41 53469-21-912/13/15 12:530.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 12/15/15 03:41 12672-29-612/13/15 12:530.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 12/15/15 03:41 11097-69-112/13/15 12:530.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 12/15/15 03:41 11096-82-512/13/15 12:530.50 0.50 1
Surrogates
Decachlorobiphenyl (S)73 %12/15/15 03:41 2051-24-312/13/15 12:5310-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 12/18/15 10:47 94-75-712/15/15 20:150.94 0.22 1
Dinoseb ND ug/L 12/18/15 10:47 88-85-712/15/15 20:150.19 0.057 1
2,4,5-T ND ug/L 12/18/15 10:47 93-76-512/15/15 20:150.19 0.042 1
2,4,5-TP (Silvex)ND ug/L 12/18/15 10:47 93-72-112/15/15 20:150.19 0.049 1
Surrogates
2,4-DCAA (S)87 %12/18/15 10:47 19719-28-912/15/15 20:1536-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/17/15 02:08 7440-36-012/12/15 00:006.0 3.8 1
Arsenic ND ug/L 12/17/15 02:08 7440-38-212/12/15 00:0010.0 2.5 1
Barium 17.6J ug/L 12/17/15 02:08 7440-39-312/12/15 00:001002.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-MW21 Lab ID:92279347001 Collected:12/08/15 11:20 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Beryllium ND ug/L 12/17/15 02:08 7440-41-712/12/15 00:001.0 0.50 1
Cadmium ND ug/L 12/17/15 02:08 7440-43-912/12/15 00:001.0 0.50 1
Chromium ND ug/L 12/17/15 02:08 7440-47-312/12/15 00:0010.0 2.5 1
Cobalt ND ug/L 12/17/15 02:08 7440-48-412/12/15 00:0010.0 2.5 1
Copper ND ug/L 12/17/15 02:08 7440-50-812/12/15 00:0010.0 2.5 1
Iron 1380 ug/L 12/17/15 02:08 7439-89-612/12/15 00:0030025.0 1
Lead ND ug/L 12/17/15 02:08 7439-92-112/12/15 00:0010.0 2.5 1
Manganese 50.0J ug/L 12/17/15 02:08 7439-96-512/12/15 00:0050.0 2.5 1
Nickel ND ug/L 12/17/15 02:08 7440-02-012/12/15 00:0050.0 2.5 1
Selenium ND ug/L 12/17/15 02:08 7782-49-212/12/15 00:0010.0 5.0 1
Silver ND ug/L 12/17/15 02:08 7440-22-412/12/15 00:0010.0 2.5 1
Thallium ND ug/L 12/17/15 02:08 7440-28-012/12/15 00:005.5 5.0 1
Tin ND ug/L 12/17/15 02:08 7440-31-512/12/15 00:001002.5 1
Vanadium 6.6J ug/L 12/17/15 02:08 7440-62-212/12/15 00:0025.0 2.5 1
Zinc ND ug/L 12/17/15 02:08 7440-66-612/12/15 00:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/17/15 18:27 7439-97-612/17/15 14:050.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 12/21/15 20:51 83-32-912/15/15 17:2810.0 0.25 1
Acenaphthylene ND ug/L 12/21/15 20:51 208-96-812/15/15 17:2810.0 0.21 1
Acetophenone ND ug/L 12/21/15 20:51 98-86-212/15/15 17:2810.0 2.0 1
2-Acetylaminofluorene ND ug/L 12/21/15 20:51 53-96-312/15/15 17:2820.0 0.84 1
4-Aminobiphenyl ND ug/L 12/21/15 20:51 92-67-112/15/15 17:2820.0 0.92 1
Anthracene ND ug/L 12/21/15 20:51 120-12-712/15/15 17:2810.0 0.14 1
Benzo(a)anthracene ND ug/L 12/21/15 20:51 56-55-312/15/15 17:2810.0 0.33 1
Benzo(a)pyrene ND ug/L 12/21/15 20:51 50-32-812/15/15 17:2810.0 0.30 1
Benzo(b)fluoranthene ND ug/L 12/21/15 20:51 205-99-212/15/15 17:2810.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 12/21/15 20:51 191-24-212/15/15 17:2810.0 0.38 1
Benzo(k)fluoranthene ND ug/L 12/21/15 20:51 207-08-912/15/15 17:2810.0 0.43 1
Benzyl alcohol ND ug/L 12/21/15 20:51 100-51-612/15/15 17:2820.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 12/21/15 20:51 101-55-312/15/15 17:2810.0 1.3 1
Butylbenzylphthalate ND ug/L 12/21/15 20:51 85-68-712/15/15 17:2810.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 12/21/15 20:51 59-50-712/15/15 17:2820.0 4.2 1
4-Chloroaniline ND ug/L 12/21/15 20:51 106-47-812/15/15 17:2820.0 3.4 1
Chlorobenzilate ND ug/L 12/21/15 20:51 510-15-612/15/15 17:2810.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 12/21/15 20:51 111-91-112/15/15 17:2810.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 12/21/15 20:51 111-44-412/15/15 17:2810.0 1.5 1
bis(2-Chloroisopropyl) ether ND ug/L 12/21/15 20:51 108-60-112/15/15 17:2810.0 1.6 1
2-Chloronaphthalene ND ug/L 12/21/15 20:51 91-58-712/15/15 17:2810.0 2.2 1
2-Chlorophenol ND ug/L 12/21/15 20:51 95-57-812/15/15 17:2810.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 12/21/15 20:51 7005-72-312/15/15 17:2810.0 2.1 1
Chrysene ND ug/L 12/21/15 20:51 218-01-912/15/15 17:2810.0 0.21 1
Diallate ND ug/L 12/21/15 20:51 2303-16-412/15/15 17:2810.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 12/21/15 20:51 53-70-312/15/15 17:2810.0 0.55 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-MW21 Lab ID:92279347001 Collected:12/08/15 11:20 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Dibenzofuran ND ug/L 12/21/15 20:51 132-64-912/15/15 17:2810.0 1.8 1
3,3'-Dichlorobenzidine ND ug/L 12/21/15 20:51 91-94-112/15/15 17:2820.0 1.4 1
2,4-Dichlorophenol ND ug/L 12/21/15 20:51 120-83-212/15/15 17:2810.0 1.7 1
2,6-Dichlorophenol ND ug/L 12/21/15 20:51 87-65-012/15/15 17:2810.0 1.8 1
Diethylphthalate ND ug/L 12/21/15 20:51 84-66-212/15/15 17:2860001.3 1
Dimethoate ND ug/L 12/21/15 20:51 60-51-512/15/15 17:2820.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 12/21/15 20:51 60-11-712/15/15 17:2810.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 12/21/15 20:51 57-97-612/15/15 17:2810.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 12/21/15 20:51 119-93-712/15/15 17:2810.0 2.1 1
2,4-Dimethylphenol ND ug/L 12/21/15 20:51 105-67-912/15/15 17:2810.0 2.2 1
Dimethylphthalate ND ug/L 12/21/15 20:51 131-11-312/15/15 17:2810.0 1.5 1
Di-n-butylphthalate ND ug/L 12/21/15 20:51 84-74-212/15/15 17:2810.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 12/21/15 20:51 534-52-112/15/15 17:2850.0 1.7 1
1,3-Dinitrobenzene ND ug/L 12/21/15 20:51 99-65-012/15/15 17:2820.0 1.5 1
2,4-Dinitrophenol ND ug/L 12/21/15 20:51 51-28-512/15/15 17:2850.0 6.5 1
2,4-Dinitrotoluene ND ug/L 12/21/15 20:51 121-14-212/15/15 17:2810.0 1.2 1
2,6-Dinitrotoluene ND ug/L 12/21/15 20:51 606-20-212/15/15 17:2810.0 1.7 1
Di-n-octylphthalate ND ug/L 12/21/15 20:51 117-84-012/15/15 17:2810.0 0.86 1
Diphenylamine ND ug/L 12/21/15 20:51 122-39-412/15/15 17:2810.0 1.3 1
Disulfoton ND ug/L 12/21/15 20:51 298-04-412/15/15 17:2810.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 12/21/15 20:51 117-81-712/15/15 17:2815.0 0.85 1
Ethyl methanesulfonate ND ug/L 12/21/15 20:51 62-50-012/15/15 17:2820.0 1.8 1
Famphur ND ug/L 12/21/15 20:51 52-85-712/15/15 17:2820.0 1.7 1
Fluoranthene ND ug/L 12/21/15 20:51 206-44-0 L312/15/15 17:2810.0 0.21 1
Fluorene ND ug/L 12/21/15 20:51 86-73-712/15/15 17:2810.0 0.21 1
Hexachlorobenzene ND ug/L 12/21/15 20:51 118-74-112/15/15 17:2810.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 12/21/15 20:51 77-47-412/15/15 17:2810.0 1.8 1
Hexachloroethane ND ug/L 12/21/15 20:51 67-72-112/15/15 17:2810.0 1.5 1
Hexachloropropene ND ug/L 12/21/15 20:51 1888-71-712/15/15 17:2810.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 12/21/15 20:51 193-39-512/15/15 17:2810.0 0.29 1
Isodrin ND ug/L 12/21/15 20:51 465-73-6 L312/15/15 17:2820.0 2.0 1
Isophorone ND ug/L 12/21/15 20:51 78-59-112/15/15 17:2810.0 1.8 1
Isosafrole ND ug/L 12/21/15 20:51 120-58-112/15/15 17:2810.0 1.8 1
Kepone ND ug/L 12/21/15 20:51 143-50-012/15/15 17:2820.0 3.1 1
Methapyrilene ND ug/L 12/21/15 20:51 91-80-5 L212/15/15 17:281002.7 1
3-Methylcholanthrene ND ug/L 12/21/15 20:51 56-49-512/15/15 17:2810.0 0.82 1
Methyl methanesulfonate ND ug/L 12/21/15 20:51 66-27-312/15/15 17:2810.0 1.3 1
2-Methylnaphthalene ND ug/L 12/21/15 20:51 91-57-612/15/15 17:2810.0 0.28 1
Methyl parathion ND ug/L 12/21/15 20:51 298-00-012/15/15 17:2810.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 12/21/15 20:51 95-48-712/15/15 17:2810.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 12/21/15 20:5112/15/15 17:2810.0 1.7 1
1-Naphthalenamine ND ug/L 12/21/15 20:51 134-32-712/15/15 17:2810.0 0.96 1
2-Naphthalenamine ND ug/L 12/21/15 20:51 91-59-812/15/15 17:2810.0 0.98 1
1,4-Naphthoquinone ND ug/L 12/21/15 20:51 130-15-412/15/15 17:2810.0 1.8 1
2-Nitroaniline ND ug/L 12/21/15 20:51 88-74-412/15/15 17:2850.0 2.8 1
3-Nitroaniline ND ug/L 12/21/15 20:51 99-09-212/15/15 17:2850.0 2.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-MW21 Lab ID:92279347001 Collected:12/08/15 11:20 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
4-Nitroaniline ND ug/L 12/21/15 20:51 100-01-612/15/15 17:2820.0 2.5 1
Nitrobenzene ND ug/L 12/21/15 20:51 98-95-312/15/15 17:2810.0 1.7 1
2-Nitrophenol ND ug/L 12/21/15 20:51 88-75-512/15/15 17:2810.0 1.7 1
4-Nitrophenol ND ug/L 12/21/15 20:51 100-02-712/15/15 17:2850.0 5.8 1
5-Nitro-o-toluidine ND ug/L 12/21/15 20:51 99-55-812/15/15 17:2810.0 1.2 1
N-Nitrosodiethylamine ND ug/L 12/21/15 20:51 55-18-512/15/15 17:2820.0 1.8 1
N-Nitrosodimethylamine ND ug/L 12/21/15 20:51 62-75-912/15/15 17:2810.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 12/21/15 20:51 924-16-312/15/15 17:2810.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 12/21/15 20:51 621-64-712/15/15 17:2810.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 12/21/15 20:51 86-30-612/15/15 17:2810.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 12/21/15 20:51 10595-95-612/15/15 17:2810.0 1.8 1
N-Nitrosopiperidine ND ug/L 12/21/15 20:51 100-75-412/15/15 17:2820.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 12/21/15 20:51 930-55-212/15/15 17:2810.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 12/21/15 20:51 126-68-112/15/15 17:2810.0 1.8 1
Parathion (Ethyl parathion)ND ug/L 12/21/15 20:51 56-38-212/15/15 17:2810.0 1.1 1
Pentachlorobenzene ND ug/L 12/21/15 20:51 608-93-512/15/15 17:2810.0 2.0 1
Pentachloronitrobenzene ND ug/L 12/21/15 20:51 82-68-812/15/15 17:2820.0 1.0 1
Pentachlorophenol ND ug/L 12/21/15 20:51 87-86-512/15/15 17:2825.0 2.3 1
Phenacetin ND ug/L 12/21/15 20:51 62-44-212/15/15 17:2820.0 0.97 1
Phenanthrene ND ug/L 12/21/15 20:51 85-01-812/15/15 17:2810.0 0.22 1
Phenol ND ug/L 12/21/15 20:51 108-95-212/15/15 17:2810.0 1.7 1
p-Phenylenediamine ND ug/L 12/21/15 20:51 106-50-312/15/15 17:2810.0 0.96 1
Phorate ND ug/L 12/21/15 20:51 298-02-2 L312/15/15 17:2810.0 1.1 1
Pronamide ND ug/L 12/21/15 20:51 23950-58-512/15/15 17:2810.0 0.97 1
Pyrene ND ug/L 12/21/15 20:51 129-00-012/15/15 17:2810.0 0.19 1
Safrole ND ug/L 12/21/15 20:51 94-59-712/15/15 17:2810.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 12/21/15 20:51 95-94-312/15/15 17:2810.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 12/21/15 20:51 58-90-212/15/15 17:2810.0 2.3 1
Thionazin ND ug/L 12/21/15 20:51 297-97-212/15/15 17:2820.0 1.2 1
O-Toluidine ND ug/L 12/21/15 20:51 95-53-412/15/15 17:2810.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 12/21/15 20:51 95-95-412/15/15 17:2810.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 12/21/15 20:51 88-06-212/15/15 17:2810.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 12/21/15 20:51 99-35-4 L312/15/15 17:2810.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)79 %12/21/15 20:51 4165-60-012/15/15 17:2821-110 1
2-Fluorobiphenyl (S)76 %12/21/15 20:51 321-60-812/15/15 17:2827-110 1
Terphenyl-d14 (S)97 %12/21/15 20:51 1718-51-012/15/15 17:2831-107 1
Phenol-d6 (S)22 %12/21/15 20:51 13127-88-312/15/15 17:2810-110 1
2-Fluorophenol (S)34 %12/21/15 20:51 367-12-412/15/15 17:2812-110 1
2,4,6-Tribromophenol (S)98 %12/21/15 20:51 118-79-612/15/15 17:2827-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/19/15 09:45 67-64-110010.0 1
Acetonitrile ND ug/L 12/19/15 09:45 75-05-855.0 2.2 1
Acrolein 1.6J ug/L 12/19/15 09:45 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 12/19/15 09:45 107-13-12001.9 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-MW21 Lab ID:92279347001 Collected:12/08/15 11:20 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Allyl chloride ND ug/L 12/19/15 09:45 107-05-110.0 1.5 1
Benzene ND ug/L 12/19/15 09:45 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/19/15 09:45 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/19/15 09:45 75-27-41.0 0.18 1
Bromoform ND ug/L 12/19/15 09:45 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/19/15 09:45 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/19/15 09:45 78-93-31000.96 1
Carbon disulfide ND ug/L 12/19/15 09:45 75-15-01001.2 1
Carbon tetrachloride ND ug/L 12/19/15 09:45 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/19/15 09:45 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/19/15 09:45 75-00-310.0 0.54 1
Chloroform ND ug/L 12/19/15 09:45 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/19/15 09:45 74-87-31.0 0.11 1
Chloroprene ND ug/L 12/19/15 09:45 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 12/19/15 09:45 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/19/15 09:45 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/19/15 09:45 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/19/15 09:45 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/19/15 09:45 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 12/19/15 09:45 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 12/19/15 09:45 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/19/15 09:45 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 12/19/15 09:45 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 12/19/15 09:45 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/19/15 09:45 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/19/15 09:45 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/19/15 09:45 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/19/15 09:45 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/19/15 09:45 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 12/19/15 09:45 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 12/19/15 09:45 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 12/19/15 09:45 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 12/19/15 09:45 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/19/15 09:45 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/19/15 09:45 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 12/19/15 09:45 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 12/19/15 09:45 87-68-310.0 0.71 1
2-Hexanone ND ug/L 12/19/15 09:45 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/19/15 09:45 74-88-410.0 0.32 1
Isobutanol ND ug/L 12/19/15 09:45 78-83-110035.0 1
Methacrylonitrile ND ug/L 12/19/15 09:45 126-98-71000.93 1
Methylene Chloride ND ug/L 12/19/15 09:45 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 12/19/15 09:45 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/19/15 09:45 108-10-11000.33 1
Naphthalene ND ug/L 12/19/15 09:45 91-20-310.0 0.24 1
Propionitrile ND ug/L 12/19/15 09:45 107-12-01503.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-MW21 Lab ID:92279347001 Collected:12/08/15 11:20 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Styrene ND ug/L 12/19/15 09:45 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/19/15 09:45 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/19/15 09:45 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/19/15 09:45 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/19/15 09:45 109-99-910.0 3.1 1
Toluene ND ug/L 12/19/15 09:45 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 12/19/15 09:45 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 12/19/15 09:45 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/19/15 09:45 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/19/15 09:45 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/19/15 09:45 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/19/15 09:45 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/19/15 09:45 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/19/15 09:45 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/19/15 09:45 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)105 %12/19/15 09:45 460-00-470-130 1
1,2-Dichloroethane-d4 (S)98 %12/19/15 09:45 17060-07-070-130 1
Toluene-d8 (S)111 %12/19/15 09:45 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 1030J ug/L 12/14/15 15:09500010001
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids ND ug/L 12/11/15 10:4125000250001
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/11/15 15:00 18496-25-810001001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate ND ug/L 12/11/15 14:06 14808-79-825000010001
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 859J ug/L 12/18/15 17:56 16887-00-610005001
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 12/16/15 11:10 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-FIELD BLANK Lab ID:92279347002 Collected:12/09/15 15:30 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 12/17/15 18:48 309-00-212/15/15 12:150.050 0.050 1
alpha-BHC ND ug/L 12/17/15 18:48 319-84-612/15/15 12:150.050 0.050 1
beta-BHC ND ug/L 12/17/15 18:48 319-85-712/15/15 12:150.050 0.050 1
delta-BHC ND ug/L 12/17/15 18:48 319-86-812/15/15 12:150.050 0.050 1
gamma-BHC (Lindane)ND ug/L 12/17/15 18:48 58-89-912/15/15 12:150.050 0.050 1
Chlordane (Technical)ND ug/L 12/17/15 18:48 57-74-912/15/15 12:150.50 0.20 1
4,4'-DDD ND ug/L 12/17/15 18:48 72-54-812/15/15 12:150.10 0.050 1
4,4'-DDE ND ug/L 12/17/15 18:48 72-55-912/15/15 12:150.10 0.050 1
4,4'-DDT ND ug/L 12/17/15 18:48 50-29-312/15/15 12:150.10 0.050 1
Dieldrin ND ug/L 12/17/15 18:48 60-57-112/15/15 12:150.075 0.050 1
Endosulfan I ND ug/L 12/17/15 18:48 959-98-812/15/15 12:150.10 0.050 1
Endosulfan II ND ug/L 12/17/15 18:48 33213-65-912/15/15 12:150.10 0.050 1
Endosulfan sulfate ND ug/L 12/17/15 18:48 1031-07-812/15/15 12:150.10 0.050 1
Endrin ND ug/L 12/17/15 18:48 72-20-812/15/15 12:150.10 0.050 1
Endrin aldehyde ND ug/L 12/17/15 18:48 7421-93-412/15/15 12:150.10 0.050 1
Heptachlor ND ug/L 12/17/15 18:48 76-44-812/15/15 12:150.050 0.050 1
Heptachlor epoxide ND ug/L 12/17/15 18:48 1024-57-312/15/15 12:150.075 0.050 1
Methoxychlor ND ug/L 12/17/15 18:48 72-43-512/15/15 12:151.0 0.15 1
Toxaphene ND ug/L 12/17/15 18:48 8001-35-212/15/15 12:151.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)74 %12/17/15 18:48 877-09-812/15/15 12:1520-130 1
Decachlorobiphenyl (S)64 %12/17/15 18:48 2051-24-312/15/15 12:1520-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 12/15/15 04:23 12674-11-212/13/15 12:530.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 12/15/15 04:23 11104-28-212/13/15 12:530.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 12/15/15 04:23 11141-16-512/13/15 12:530.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 12/15/15 04:23 53469-21-912/13/15 12:530.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 12/15/15 04:23 12672-29-612/13/15 12:530.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 12/15/15 04:23 11097-69-112/13/15 12:530.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 12/15/15 04:23 11096-82-512/13/15 12:530.50 0.50 1
Surrogates
Decachlorobiphenyl (S)57 %12/15/15 04:23 2051-24-312/13/15 12:5310-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 12/18/15 11:17 94-75-712/15/15 20:150.94 0.22 1
Dinoseb ND ug/L 12/18/15 11:17 88-85-712/15/15 20:150.19 0.057 1
2,4,5-T ND ug/L 12/18/15 11:17 93-76-512/15/15 20:150.19 0.042 1
2,4,5-TP (Silvex)ND ug/L 12/18/15 11:17 93-72-112/15/15 20:150.19 0.049 1
Surrogates
2,4-DCAA (S)85 %12/18/15 11:17 19719-28-912/15/15 20:1536-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/17/15 02:11 7440-36-012/12/15 00:006.0 3.8 1
Arsenic ND ug/L 12/17/15 02:11 7440-38-212/12/15 00:0010.0 2.5 1
Barium ND ug/L 12/17/15 02:11 7440-39-312/12/15 00:001002.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-FIELD BLANK Lab ID:92279347002 Collected:12/09/15 15:30 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Beryllium ND ug/L 12/17/15 02:11 7440-41-712/12/15 00:001.0 0.50 1
Cadmium ND ug/L 12/17/15 02:11 7440-43-912/12/15 00:001.0 0.50 1
Chromium ND ug/L 12/17/15 02:11 7440-47-312/12/15 00:0010.0 2.5 1
Cobalt ND ug/L 12/17/15 02:11 7440-48-412/12/15 00:0010.0 2.5 1
Copper ND ug/L 12/17/15 02:11 7440-50-812/12/15 00:0010.0 2.5 1
Iron ND ug/L 12/17/15 02:11 7439-89-612/12/15 00:0030025.0 1
Lead ND ug/L 12/17/15 02:11 7439-92-112/12/15 00:0010.0 2.5 1
Manganese ND ug/L 12/17/15 02:11 7439-96-512/12/15 00:0050.0 2.5 1
Nickel ND ug/L 12/17/15 02:11 7440-02-012/12/15 00:0050.0 2.5 1
Selenium ND ug/L 12/17/15 02:11 7782-49-212/12/15 00:0010.0 5.0 1
Silver ND ug/L 12/17/15 02:11 7440-22-412/12/15 00:0010.0 2.5 1
Thallium ND ug/L 12/17/15 02:11 7440-28-012/12/15 00:005.5 5.0 1
Tin ND ug/L 12/17/15 02:11 7440-31-512/12/15 00:001002.5 1
Vanadium ND ug/L 12/17/15 02:11 7440-62-212/12/15 00:0025.0 2.5 1
Zinc ND ug/L 12/17/15 02:11 7440-66-612/12/15 00:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/17/15 18:29 7439-97-612/17/15 14:050.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 12/29/15 11:19 83-32-912/15/15 17:2810.0 0.25 1
Acenaphthylene ND ug/L 12/29/15 11:19 208-96-812/15/15 17:2810.0 0.21 1
Acetophenone ND ug/L 12/29/15 11:19 98-86-212/15/15 17:2810.0 2.0 1
2-Acetylaminofluorene ND ug/L 12/29/15 11:19 53-96-312/15/15 17:2820.0 0.84 1
4-Aminobiphenyl ND ug/L 12/29/15 11:19 92-67-112/15/15 17:2820.0 0.92 1
Anthracene ND ug/L 12/29/15 11:19 120-12-712/15/15 17:2810.0 0.14 1
Benzo(a)anthracene ND ug/L 12/29/15 11:19 56-55-312/15/15 17:2810.0 0.33 1
Benzo(a)pyrene ND ug/L 12/29/15 11:19 50-32-812/15/15 17:2810.0 0.30 1
Benzo(b)fluoranthene ND ug/L 12/29/15 11:19 205-99-212/15/15 17:2810.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 12/29/15 11:19 191-24-212/15/15 17:2810.0 0.38 1
Benzo(k)fluoranthene ND ug/L 12/29/15 11:19 207-08-912/15/15 17:2810.0 0.43 1
Benzyl alcohol ND ug/L 12/29/15 11:19 100-51-612/15/15 17:2820.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 12/29/15 11:19 101-55-312/15/15 17:2810.0 1.3 1
Butylbenzylphthalate ND ug/L 12/29/15 11:19 85-68-712/15/15 17:2810.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 12/29/15 11:19 59-50-712/15/15 17:2820.0 4.2 1
4-Chloroaniline ND ug/L 12/29/15 11:19 106-47-812/15/15 17:2820.0 3.4 1
Chlorobenzilate ND ug/L 12/29/15 11:19 510-15-612/15/15 17:2810.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 12/29/15 11:19 111-91-112/15/15 17:2810.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 12/29/15 11:19 111-44-412/15/15 17:2810.0 1.5 1
bis(2-Chloroisopropyl) ether ND ug/L 12/29/15 11:19 108-60-112/15/15 17:2810.0 1.6 1
2-Chloronaphthalene ND ug/L 12/29/15 11:19 91-58-712/15/15 17:2810.0 2.2 1
2-Chlorophenol ND ug/L 12/29/15 11:19 95-57-812/15/15 17:2810.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 12/29/15 11:19 7005-72-312/15/15 17:2810.0 2.1 1
Chrysene ND ug/L 12/29/15 11:19 218-01-912/15/15 17:2810.0 0.21 1
Diallate ND ug/L 12/29/15 11:19 2303-16-412/15/15 17:2810.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 12/29/15 11:19 53-70-312/15/15 17:2810.0 0.55 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-FIELD BLANK Lab ID:92279347002 Collected:12/09/15 15:30 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Dibenzofuran ND ug/L 12/29/15 11:19 132-64-912/15/15 17:2810.0 1.8 1
3,3'-Dichlorobenzidine ND ug/L 12/29/15 11:19 91-94-112/15/15 17:2820.0 1.4 1
2,4-Dichlorophenol ND ug/L 12/29/15 11:19 120-83-212/15/15 17:2810.0 1.7 1
2,6-Dichlorophenol ND ug/L 12/29/15 11:19 87-65-012/15/15 17:2810.0 1.8 1
Diethylphthalate ND ug/L 12/29/15 11:19 84-66-212/15/15 17:2860001.3 1
Dimethoate ND ug/L 12/29/15 11:19 60-51-512/15/15 17:2820.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 12/29/15 11:19 60-11-712/15/15 17:2810.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 12/29/15 11:19 57-97-612/15/15 17:2810.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 12/29/15 11:19 119-93-712/15/15 17:2810.0 2.1 1
2,4-Dimethylphenol ND ug/L 12/29/15 11:19 105-67-912/15/15 17:2810.0 2.2 1
Dimethylphthalate ND ug/L 12/29/15 11:19 131-11-312/15/15 17:2810.0 1.5 1
Di-n-butylphthalate ND ug/L 12/29/15 11:19 84-74-212/15/15 17:2810.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 12/29/15 11:19 534-52-112/15/15 17:2850.0 1.7 1
1,3-Dinitrobenzene ND ug/L 12/29/15 11:19 99-65-012/15/15 17:2820.0 1.5 1
2,4-Dinitrophenol ND ug/L 12/29/15 11:19 51-28-512/15/15 17:2850.0 6.5 1
2,4-Dinitrotoluene ND ug/L 12/29/15 11:19 121-14-212/15/15 17:2810.0 1.2 1
2,6-Dinitrotoluene ND ug/L 12/29/15 11:19 606-20-212/15/15 17:2810.0 1.7 1
Di-n-octylphthalate ND ug/L 12/29/15 11:19 117-84-012/15/15 17:2810.0 0.86 1
Diphenylamine ND ug/L 12/29/15 11:19 122-39-412/15/15 17:2810.0 1.3 1
Disulfoton ND ug/L 12/29/15 11:19 298-04-412/15/15 17:2810.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 12/29/15 11:19 117-81-712/15/15 17:2815.0 0.85 1
Ethyl methanesulfonate ND ug/L 12/29/15 11:19 62-50-012/15/15 17:2820.0 1.8 1
Famphur ND ug/L 12/29/15 11:19 52-85-712/15/15 17:2820.0 1.7 1
Fluoranthene ND ug/L 12/29/15 11:19 206-44-0 L312/15/15 17:2810.0 0.21 1
Fluorene ND ug/L 12/29/15 11:19 86-73-712/15/15 17:2810.0 0.21 1
Hexachlorobenzene ND ug/L 12/29/15 11:19 118-74-112/15/15 17:2810.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 12/29/15 11:19 77-47-412/15/15 17:2810.0 1.8 1
Hexachloroethane ND ug/L 12/29/15 11:19 67-72-112/15/15 17:2810.0 1.5 1
Hexachloropropene ND ug/L 12/29/15 11:19 1888-71-712/15/15 17:2810.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 12/29/15 11:19 193-39-512/15/15 17:2810.0 0.29 1
Isodrin ND ug/L 12/29/15 11:19 465-73-6 L312/15/15 17:2820.0 2.0 1
Isophorone ND ug/L 12/29/15 11:19 78-59-112/15/15 17:2810.0 1.8 1
Isosafrole ND ug/L 12/29/15 11:19 120-58-112/15/15 17:2810.0 1.8 1
Kepone ND ug/L 12/29/15 11:19 143-50-012/15/15 17:2820.0 3.1 1
Methapyrilene ND ug/L 12/29/15 11:19 91-80-5 L212/15/15 17:281002.7 1
3-Methylcholanthrene ND ug/L 12/29/15 11:19 56-49-512/15/15 17:2810.0 0.82 1
Methyl methanesulfonate ND ug/L 12/29/15 11:19 66-27-312/15/15 17:2810.0 1.3 1
2-Methylnaphthalene ND ug/L 12/29/15 11:19 91-57-612/15/15 17:2810.0 0.28 1
Methyl parathion ND ug/L 12/29/15 11:19 298-00-012/15/15 17:2810.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 12/29/15 11:19 95-48-712/15/15 17:2810.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 12/29/15 11:1912/15/15 17:2810.0 1.7 1
1-Naphthalenamine ND ug/L 12/29/15 11:19 134-32-712/15/15 17:2810.0 0.96 1
2-Naphthalenamine ND ug/L 12/29/15 11:19 91-59-812/15/15 17:2810.0 0.98 1
1,4-Naphthoquinone ND ug/L 12/29/15 11:19 130-15-412/15/15 17:2810.0 1.8 1
2-Nitroaniline ND ug/L 12/29/15 11:19 88-74-412/15/15 17:2850.0 2.8 1
3-Nitroaniline ND ug/L 12/29/15 11:19 99-09-212/15/15 17:2850.0 2.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-FIELD BLANK Lab ID:92279347002 Collected:12/09/15 15:30 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
4-Nitroaniline ND ug/L 12/29/15 11:19 100-01-612/15/15 17:2820.0 2.5 1
Nitrobenzene ND ug/L 12/29/15 11:19 98-95-312/15/15 17:2810.0 1.7 1
2-Nitrophenol ND ug/L 12/29/15 11:19 88-75-512/15/15 17:2810.0 1.7 1
4-Nitrophenol ND ug/L 12/29/15 11:19 100-02-712/15/15 17:2850.0 5.8 1
5-Nitro-o-toluidine ND ug/L 12/29/15 11:19 99-55-812/15/15 17:2810.0 1.2 1
N-Nitrosodiethylamine ND ug/L 12/29/15 11:19 55-18-512/15/15 17:2820.0 1.8 1
N-Nitrosodimethylamine ND ug/L 12/29/15 11:19 62-75-912/15/15 17:2810.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 12/29/15 11:19 924-16-312/15/15 17:2810.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 12/29/15 11:19 621-64-712/15/15 17:2810.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 12/29/15 11:19 86-30-612/15/15 17:2810.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 12/29/15 11:19 10595-95-612/15/15 17:2810.0 1.8 1
N-Nitrosopiperidine ND ug/L 12/29/15 11:19 100-75-412/15/15 17:2820.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 12/29/15 11:19 930-55-212/15/15 17:2810.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 12/29/15 11:19 126-68-112/15/15 17:2810.0 1.8 1
Parathion (Ethyl parathion)ND ug/L 12/29/15 11:19 56-38-212/15/15 17:2810.0 1.1 1
Pentachlorobenzene ND ug/L 12/29/15 11:19 608-93-512/15/15 17:2810.0 2.0 1
Pentachloronitrobenzene ND ug/L 12/29/15 11:19 82-68-812/15/15 17:2820.0 1.0 1
Pentachlorophenol ND ug/L 12/29/15 11:19 87-86-512/15/15 17:2825.0 2.3 1
Phenacetin ND ug/L 12/29/15 11:19 62-44-212/15/15 17:2820.0 0.97 1
Phenanthrene ND ug/L 12/29/15 11:19 85-01-812/15/15 17:2810.0 0.22 1
Phenol ND ug/L 12/29/15 11:19 108-95-212/15/15 17:2810.0 1.7 1
p-Phenylenediamine ND ug/L 12/29/15 11:19 106-50-312/15/15 17:2810.0 0.96 1
Phorate ND ug/L 12/29/15 11:19 298-02-2 L312/15/15 17:2810.0 1.1 1
Pronamide ND ug/L 12/29/15 11:19 23950-58-512/15/15 17:2810.0 0.97 1
Pyrene ND ug/L 12/29/15 11:19 129-00-012/15/15 17:2810.0 0.19 1
Safrole ND ug/L 12/29/15 11:19 94-59-712/15/15 17:2810.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 12/29/15 11:19 95-94-312/15/15 17:2810.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 12/29/15 11:19 58-90-212/15/15 17:2810.0 2.3 1
Thionazin ND ug/L 12/29/15 11:19 297-97-212/15/15 17:2820.0 1.2 1
O-Toluidine ND ug/L 12/29/15 11:19 95-53-412/15/15 17:2810.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 12/29/15 11:19 95-95-412/15/15 17:2810.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 12/29/15 11:19 88-06-212/15/15 17:2810.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 12/29/15 11:19 99-35-4 L312/15/15 17:2810.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)65 %12/29/15 11:19 4165-60-012/15/15 17:2821-110 1
2-Fluorobiphenyl (S)65 %12/29/15 11:19 321-60-812/15/15 17:2827-110 1
Terphenyl-d14 (S)82 %12/29/15 11:19 1718-51-012/15/15 17:2831-107 1
Phenol-d6 (S)21 %12/29/15 11:19 13127-88-312/15/15 17:2810-110 1
2-Fluorophenol (S)33 %12/29/15 11:19 367-12-412/15/15 17:2812-110 1
2,4,6-Tribromophenol (S)64 %12/29/15 11:19 118-79-612/15/15 17:2827-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/20/15 21:21 67-64-110010.0 1
Acetonitrile ND ug/L 12/20/15 21:21 75-05-855.0 2.2 1
Acrolein ND ug/L 12/20/15 21:21 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 12/20/15 21:21 107-13-12001.9 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-FIELD BLANK Lab ID:92279347002 Collected:12/09/15 15:30 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Allyl chloride ND ug/L 12/20/15 21:21 107-05-110.0 1.5 1
Benzene ND ug/L 12/20/15 21:21 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/20/15 21:21 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/20/15 21:21 75-27-41.0 0.18 1
Bromoform ND ug/L 12/20/15 21:21 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/20/15 21:21 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/20/15 21:21 78-93-31000.96 1
Carbon disulfide ND ug/L 12/20/15 21:21 75-15-01001.2 1
Carbon tetrachloride ND ug/L 12/20/15 21:21 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/20/15 21:21 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/20/15 21:21 75-00-310.0 0.54 1
Chloroform ND ug/L 12/20/15 21:21 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/20/15 21:21 74-87-31.0 0.11 1
Chloroprene ND ug/L 12/20/15 21:21 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 12/20/15 21:21 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/20/15 21:21 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/20/15 21:21 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/20/15 21:21 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/20/15 21:21 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 12/20/15 21:21 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 12/20/15 21:21 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/20/15 21:21 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 12/20/15 21:21 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 12/20/15 21:21 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/20/15 21:21 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/20/15 21:21 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/20/15 21:21 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/20/15 21:21 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/20/15 21:21 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 12/20/15 21:21 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 12/20/15 21:21 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 12/20/15 21:21 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 12/20/15 21:21 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/20/15 21:21 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/20/15 21:21 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 12/20/15 21:21 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 12/20/15 21:21 87-68-310.0 0.71 1
2-Hexanone ND ug/L 12/20/15 21:21 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/20/15 21:21 74-88-410.0 0.32 1
Isobutanol ND ug/L 12/20/15 21:21 78-83-110035.0 1
Methacrylonitrile ND ug/L 12/20/15 21:21 126-98-71000.93 1
Methylene Chloride 2.0 ug/L 12/20/15 21:21 75-09-2 C91.0 0.97 1
Methyl methacrylate ND ug/L 12/20/15 21:21 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/20/15 21:21 108-10-11000.33 1
Naphthalene ND ug/L 12/20/15 21:21 91-20-310.0 0.24 1
Propionitrile ND ug/L 12/20/15 21:21 107-12-01503.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-FIELD BLANK Lab ID:92279347002 Collected:12/09/15 15:30 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Styrene ND ug/L 12/20/15 21:21 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/20/15 21:21 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/20/15 21:21 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/20/15 21:21 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/20/15 21:21 109-99-910.0 3.1 1
Toluene ND ug/L 12/20/15 21:21 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 12/20/15 21:21 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 12/20/15 21:21 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/20/15 21:21 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/20/15 21:21 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/20/15 21:21 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/20/15 21:21 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/20/15 21:21 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/20/15 21:21 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/20/15 21:21 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)103 %12/20/15 21:21 460-00-470-130 1
1,2-Dichloroethane-d4 (S)95 %12/20/15 21:21 17060-07-070-130 1
Toluene-d8 (S)108 %12/20/15 21:21 2037-26-570-130 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/14/15 12:30 18496-25-810001001
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 12/16/15 11:30 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-TRIP BLANK Lab ID:92279347003 Collected:12/08/15 00:00 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/19/15 10:02 67-64-110010.0 1
Acetonitrile ND ug/L 12/19/15 10:02 75-05-855.0 2.2 1
Acrolein 2.8J ug/L 12/19/15 10:02 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 12/19/15 10:02 107-13-12001.9 1
Allyl chloride ND ug/L 12/19/15 10:02 107-05-110.0 1.5 1
Benzene ND ug/L 12/19/15 10:02 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/19/15 10:02 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/19/15 10:02 75-27-41.0 0.18 1
Bromoform ND ug/L 12/19/15 10:02 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/19/15 10:02 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/19/15 10:02 78-93-31000.96 1
Carbon disulfide ND ug/L 12/19/15 10:02 75-15-01001.2 1
Carbon tetrachloride ND ug/L 12/19/15 10:02 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/19/15 10:02 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/19/15 10:02 75-00-310.0 0.54 1
Chloroform ND ug/L 12/19/15 10:02 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/19/15 10:02 74-87-31.0 0.11 1
Chloroprene ND ug/L 12/19/15 10:02 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 12/19/15 10:02 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/19/15 10:02 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/19/15 10:02 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/19/15 10:02 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/19/15 10:02 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 12/19/15 10:02 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 12/19/15 10:02 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/19/15 10:02 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 12/19/15 10:02 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 12/19/15 10:02 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/19/15 10:02 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/19/15 10:02 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/19/15 10:02 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/19/15 10:02 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/19/15 10:02 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 12/19/15 10:02 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 12/19/15 10:02 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 12/19/15 10:02 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 12/19/15 10:02 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/19/15 10:02 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/19/15 10:02 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 12/19/15 10:02 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 12/19/15 10:02 87-68-310.0 0.71 1
2-Hexanone ND ug/L 12/19/15 10:02 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/19/15 10:02 74-88-410.0 0.32 1
Isobutanol ND ug/L 12/19/15 10:02 78-83-110035.0 1
Methacrylonitrile ND ug/L 12/19/15 10:02 126-98-71000.93 1
Methylene Chloride ND ug/L 12/19/15 10:02 75-09-21.0 0.97 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Sample:1203-TRIP BLANK Lab ID:92279347003 Collected:12/08/15 00:00 Received:12/10/15 10:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Methyl methacrylate ND ug/L 12/19/15 10:02 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/19/15 10:02 108-10-11000.33 1
Naphthalene ND ug/L 12/19/15 10:02 91-20-310.0 0.24 1
Propionitrile ND ug/L 12/19/15 10:02 107-12-01503.6 1
Styrene ND ug/L 12/19/15 10:02 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/19/15 10:02 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/19/15 10:02 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/19/15 10:02 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/19/15 10:02 109-99-910.0 3.1 1
Toluene ND ug/L 12/19/15 10:02 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 12/19/15 10:02 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 12/19/15 10:02 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/19/15 10:02 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/19/15 10:02 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/19/15 10:02 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/19/15 10:02 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/19/15 10:02 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/19/15 10:02 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/19/15 10:02 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)110 %12/19/15 10:02 460-00-470-130 1
1,2-Dichloroethane-d4 (S)98 %12/19/15 10:02 17060-07-070-130 1
Toluene-d8 (S)114 %12/19/15 10:02 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/8788
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples:92279347001, 92279347002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1629746
Associated Lab Samples:92279347001, 92279347002
Matrix:Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/17/15 17:420.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1629747LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.42.5 96 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1629748MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279275008
1629749
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 96 75-12599 3 252.5ND 2.4 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20260
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92279347001, 92279347002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1627221
Associated Lab Samples:92279347001, 92279347002
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 12/17/15 00:323.8
Arsenic ug/L ND 10.0 12/17/15 00:322.5
Barium ug/L ND 100 12/17/15 00:322.5
Beryllium ug/L ND 1.0 12/17/15 00:320.50
Cadmium ug/L ND 1.0 12/17/15 00:320.50
Chromium ug/L ND 10.0 12/17/15 00:322.5
Cobalt ug/L ND 10.0 12/17/15 00:322.5
Copper ug/L ND 10.0 12/17/15 00:322.5
Iron ug/L ND 300 12/17/15 00:3225.0
Lead ug/L ND 10.0 12/17/15 00:322.5
Manganese ug/L ND 50.0 12/17/15 00:322.5
Nickel ug/L ND 50.0 12/17/15 00:322.5
Selenium ug/L ND 10.0 12/17/15 00:325.0
Silver ug/L ND 10.0 12/17/15 00:322.5
Thallium ug/L ND 5.5 12/17/15 00:325.0
Tin ug/L ND 100 12/17/15 00:322.5
Vanadium ug/L ND 25.0 12/17/15 00:322.5
Zinc ug/L ND 10.0 12/17/15 00:325.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1627222LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 547500 109 80-120
Arsenic ug/L 489500 98 80-120
Barium ug/L 479500 96 80-120
Beryllium ug/L 472500 94 80-120
Cadmium ug/L 497500 99 80-120
Chromium ug/L 464500 93 80-120
Cobalt ug/L 507500 101 80-120
Copper ug/L 490500 98 80-120
Iron ug/L 48505000 97 80-120
Lead ug/L 500500 100 80-120
Manganese ug/L 511500 102 80-120
Nickel ug/L 500500 100 80-120
Selenium ug/L 506500 101 80-120
Silver ug/L 254250 102 80-120
Thallium ug/L 476500 95 80-120
Tin ug/L 550500 110 80-120
Vanadium ug/L 520500 104 80-120
Zinc ug/L 515500 103 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1627223MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279296001
1627224
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 79 75-12575 4 25500ND395379
Arsenic ug/L 500 92 75-12591 2 25500ND464454
Barium ug/L 500 94 75-12595 0 25500151621624
Beryllium ug/L 500 92 75-12592 0 255002.8 462 461
Cadmium ug/L 500 95 75-12593 2 25500ND475467
Chromium ug/L 500 91 75-12590 1 255006.9 464 458
Cobalt ug/L 500 96 75-12595 2 2550012.0 493 484
Copper ug/L 500 96 75-12595 1 2550014.9 496 492
Iron ug/L M1500023575-125267 7 255000101002180023400
Lead ug/L 500 94 75-12592 2 255008.6 476 469
Manganese ug/L 500 103 75-125102 1 25500133648642
Nickel ug/L 500 95 75-12594 1 2550015.6 491 484
Selenium ug/L 500 94 75-12593 2 25500ND472465
Silver ug/L 250 98 75-12597 1 25250ND245242
Thallium ug/L 500 88 75-12587 1 255005.1J 443 440
Tin ug/L 500 103 75-125100 2 25500ND515503
Vanadium ug/L 500 103 75-125102 1 2550016.8 532 525
Zinc ug/L 500 101 75-125101 1 2550035.2 542 538
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34786
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92279347001, 92279347003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1633238
Associated Lab Samples:92279347001, 92279347003
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 12/19/15 01:260.33
1,1,1-Trichloroethane ug/L ND 1.0 12/19/15 01:260.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 12/19/15 01:260.40
1,1,2-Trichloroethane ug/L ND 1.0 12/19/15 01:260.29
1,1-Dichloroethane ug/L ND 5.0 12/19/15 01:260.32
1,1-Dichloroethene ug/L ND 5.0 12/19/15 01:260.56
1,1-Dichloropropene ug/L ND 5.0 12/19/15 01:260.49
1,2,3-Trichloropropane ug/L ND 1.0 12/19/15 01:260.41
1,2,4-Trichlorobenzene ug/L ND 10.0 12/19/15 01:260.35
1,2-Dibromo-3-chloropropane ug/L ND 13.0 12/19/15 01:262.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/19/15 01:260.27
1,2-Dichlorobenzene ug/L ND 5.0 12/19/15 01:260.30
1,2-Dichloroethane ug/L ND 1.0 12/19/15 01:260.24
1,2-Dichloropropane ug/L ND 1.0 12/19/15 01:260.27
1,3-Dichlorobenzene ug/L ND 5.0 12/19/15 01:260.24
1,3-Dichloropropane ug/L ND 1.0 12/19/15 01:260.28
1,4-Dichlorobenzene ug/L ND 1.0 12/19/15 01:260.33
2,2-Dichloropropane ug/L ND 15.0 12/19/15 01:260.13
2-Butanone (MEK)ug/L ND 100 12/19/15 01:260.96
2-Hexanone ug/L ND 50.0 12/19/15 01:260.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 12/19/15 01:260.33
Acetone ug/L ND 100 12/19/15 01:2610.0
Acetonitrile ug/L ND 55.0 12/19/15 01:262.2
Acrolein ug/L ND 53.0 12/19/15 01:261.6
Acrylonitrile ug/L ND 200 12/19/15 01:261.9
Allyl chloride ug/L ND 10.0 12/19/15 01:261.5
Benzene ug/L ND 1.0 12/19/15 01:260.25
Bromochloromethane ug/L ND 3.0 12/19/15 01:260.17
Bromodichloromethane ug/L ND 1.0 12/19/15 01:260.18
Bromoform ug/L ND 3.0 12/19/15 01:260.26
Bromomethane ug/L ND 10.0 12/19/15 01:260.29
Carbon disulfide ug/L ND 100 12/19/15 01:261.2
Carbon tetrachloride ug/L ND 1.0 12/19/15 01:260.25
Chlorobenzene ug/L ND 3.0 12/19/15 01:260.23
Chloroethane ug/L ND 10.0 12/19/15 01:260.54
Chloroform ug/L ND 5.0 12/19/15 01:260.14
Chloromethane ug/L ND 1.0 12/19/15 01:260.11
Chloroprene ug/L ND 20.0 12/19/15 01:260.27
cis-1,2-Dichloroethene ug/L ND 5.0 12/19/15 01:260.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/19/15 01:260.13
Dibromochloromethane ug/L ND 3.0 12/19/15 01:260.21
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1633238
Associated Lab Samples:92279347001, 92279347003
Matrix:Water
AnalyzedMDL
Dibromomethane ug/L ND 10.0 12/19/15 01:260.21
Dichlorodifluoromethane ug/L ND 5.0 12/19/15 01:260.21
Ethyl methacrylate ug/L ND 10.0 12/19/15 01:260.20
Ethylbenzene ug/L ND 1.0 12/19/15 01:260.30
Hexachloro-1,3-butadiene ug/L ND 10.0 12/19/15 01:260.71
Iodomethane ug/L ND 10.0 12/19/15 01:260.32
Isobutanol ug/L ND 100 12/19/15 01:2635.0
Methacrylonitrile ug/L ND 100 12/19/15 01:260.93
Methyl methacrylate ug/L ND 30.0 12/19/15 01:262.0
Methylene Chloride ug/L ND 1.0 12/19/15 01:260.97
Naphthalene ug/L ND 10.0 12/19/15 01:260.24
Propionitrile ug/L ND 150 12/19/15 01:263.6
Styrene ug/L ND 1.0 12/19/15 01:260.26
Tetrachloroethene ug/L 1.2 1.0 12/19/15 01:260.46
Tetrahydrofuran ug/L ND 10.0 12/19/15 01:263.1
Toluene ug/L ND 1.0 12/19/15 01:260.26
trans-1,2-Dichloroethene ug/L ND 5.0 12/19/15 01:260.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/19/15 01:260.26
trans-1,4-Dichloro-2-butene ug/L ND 100 12/19/15 01:261.0
Trichloroethene ug/L ND 1.0 12/19/15 01:260.47
Trichlorofluoromethane ug/L ND 1.0 12/19/15 01:260.20
Vinyl acetate ug/L ND 50.0 12/19/15 01:260.35
Vinyl chloride ug/L ND 1.0 12/19/15 01:260.62
Xylene (Total)ug/L ND 5.0 12/19/15 01:260.66
1,2-Dichloroethane-d4 (S)%94 70-130 12/19/15 01:26
4-Bromofluorobenzene (S)%101 70-130 12/19/15 01:26
Toluene-d8 (S)%105 70-130 12/19/15 01:26
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1633239LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 49.450 99 80-125
1,1,1-Trichloroethane ug/L 49.350 99 71-129
1,1,2,2-Tetrachloroethane ug/L 48.950 98 79-124
1,1,2-Trichloroethane ug/L 48.950 98 85-125
1,1-Dichloroethane ug/L 47.450 95 73-126
1,1-Dichloroethene ug/L 45.850 92 66-135
1,1-Dichloropropene ug/L 48.050 96 74-135
1,2,3-Trichloropropane ug/L 48.850 98 75-130
1,2,4-Trichlorobenzene ug/L 45.050 90 75-134
1,2-Dibromo-3-chloropropane ug/L 47.450 95 71-133
1,2-Dibromoethane (EDB)ug/L 52.250 104 83-124
1,2-Dichlorobenzene ug/L 47.550 95 80-133
1,2-Dichloroethane ug/L 45.350 91 67-128
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1633239LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichloropropane ug/L 48.950 98 75-132
1,3-Dichlorobenzene ug/L 47.750 95 77-130
1,3-Dichloropropane ug/L 50.150 100 76-131
1,4-Dichlorobenzene ug/L 48.450 97 78-130
2,2-Dichloropropane ug/L 42.150 84 40-160
2-Butanone (MEK)ug/L 112100 112 61-144
2-Hexanone ug/L 105100 105 68-143
4-Methyl-2-pentanone (MIBK)ug/L 102100 102 72-135
Acetone ug/L 107100 107 48-146
Acetonitrile ug/L 529500 106 62-150
Acrolein ug/L 298250 119 24-160
Acrylonitrile ug/L 254250 101 40-160
Allyl chloride ug/L 49.150 98 66-137
Benzene ug/L 50.150 100 80-125
Bromochloromethane ug/L 50.750 101 71-125
Bromodichloromethane ug/L 46.050 92 78-124
Bromoform ug/L 39.550 79 71-128
Bromomethane ug/L 35.250 70 40-160
Carbon disulfide ug/L 46.7J50 93 50-160
Carbon tetrachloride ug/L 47.350 95 69-131
Chlorobenzene ug/L 48.450 97 81-122
Chloroethane ug/L 36.650 73 39-148
Chloroform ug/L 49.950 100 73-127
Chloromethane ug/L 48.150 96 44-146
Chloroprene ug/L 55.250 110 75-145
cis-1,2-Dichloroethene ug/L 47.150 94 74-124
cis-1,3-Dichloropropene ug/L 49.850 100 72-132
Dibromochloromethane ug/L 50.050 100 78-125
Dibromomethane ug/L 49.550 99 82-120
Dichlorodifluoromethane ug/L 42.250 84 34-157
Ethyl methacrylate ug/L 47.350 95 82-121
Ethylbenzene ug/L 47.150 94 79-121
Hexachloro-1,3-butadiene ug/L 53.650 107 72-131
Iodomethane ug/L 56.4100 56 39-154
Isobutanol ug/L 11101000 111 34-160
Methacrylonitrile ug/L 560500 112 74-134
Methyl methacrylate ug/L 48.250 96 84-124
Methylene Chloride ug/L 55.350 111 64-133
Naphthalene ug/L 45.650 91 73-133
Propionitrile ug/L 524500 105 73-140
Styrene ug/L 46.650 93 84-126
Tetrachloroethene ug/L 48.850 98 78-122
Tetrahydrofuran ug/L 546500 109 69-148
Toluene ug/L 47.350 95 80-121
trans-1,2-Dichloroethene ug/L 48.550 97 71-127
trans-1,3-Dichloropropene ug/L 47.250 94 69-141
trans-1,4-Dichloro-2-butene ug/L 48.6J50 97 40-160
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1633239LABORATORY CONTROL SAMPLE:
LCSSpike
Trichloroethene ug/L 50.650 101 78-122
Trichlorofluoromethane ug/L 42.850 86 53-137
Vinyl acetate ug/L 100100 100 40-160
Vinyl chloride ug/L 49.450 99 58-137
Xylene (Total)ug/L 138150 92 81-126
1,2-Dichloroethane-d4 (S)%92 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%97 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34820
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92279347002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1634031
Associated Lab Samples:92279347002
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 12/20/15 18:490.33
1,1,1-Trichloroethane ug/L ND 1.0 12/20/15 18:490.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 12/20/15 18:490.40
1,1,2-Trichloroethane ug/L ND 1.0 12/20/15 18:490.29
1,1-Dichloroethane ug/L ND 5.0 12/20/15 18:490.32
1,1-Dichloroethene ug/L ND 5.0 12/20/15 18:490.56
1,1-Dichloropropene ug/L ND 5.0 12/20/15 18:490.49
1,2,3-Trichloropropane ug/L ND 1.0 12/20/15 18:490.41
1,2,4-Trichlorobenzene ug/L ND 10.0 12/20/15 18:490.35
1,2-Dibromo-3-chloropropane ug/L ND 13.0 12/20/15 18:492.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/20/15 18:490.27
1,2-Dichlorobenzene ug/L ND 5.0 12/20/15 18:490.30
1,2-Dichloroethane ug/L ND 1.0 12/20/15 18:490.24
1,2-Dichloropropane ug/L ND 1.0 12/20/15 18:490.27
1,3-Dichlorobenzene ug/L ND 5.0 12/20/15 18:490.24
1,3-Dichloropropane ug/L ND 1.0 12/20/15 18:490.28
1,4-Dichlorobenzene ug/L ND 1.0 12/20/15 18:490.33
2,2-Dichloropropane ug/L ND 15.0 12/20/15 18:490.13
2-Butanone (MEK)ug/L ND 100 12/20/15 18:490.96
2-Hexanone ug/L ND 50.0 12/20/15 18:490.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 12/20/15 18:490.33
Acetone ug/L ND 100 12/20/15 18:4910.0
Acetonitrile ug/L ND 55.0 12/20/15 18:492.2
Acrolein ug/L ND 53.0 12/20/15 18:491.6
Acrylonitrile ug/L ND 200 12/20/15 18:491.9
Allyl chloride ug/L ND 10.0 12/20/15 18:491.5
Benzene ug/L ND 1.0 12/20/15 18:490.25
Bromochloromethane ug/L ND 3.0 12/20/15 18:490.17
Bromodichloromethane ug/L ND 1.0 12/20/15 18:490.18
Bromoform ug/L ND 3.0 12/20/15 18:490.26
Bromomethane ug/L ND 10.0 12/20/15 18:490.29
Carbon disulfide ug/L ND 100 12/20/15 18:491.2
Carbon tetrachloride ug/L ND 1.0 12/20/15 18:490.25
Chlorobenzene ug/L ND 3.0 12/20/15 18:490.23
Chloroethane ug/L ND 10.0 12/20/15 18:490.54
Chloroform ug/L ND 5.0 12/20/15 18:490.14
Chloromethane ug/L ND 1.0 12/20/15 18:490.11
Chloroprene ug/L ND 20.0 12/20/15 18:490.27
cis-1,2-Dichloroethene ug/L ND 5.0 12/20/15 18:490.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/20/15 18:490.13
Dibromochloromethane ug/L ND 3.0 12/20/15 18:490.21
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1634031
Associated Lab Samples:92279347002
Matrix:Water
AnalyzedMDL
Dibromomethane ug/L ND 10.0 12/20/15 18:490.21
Dichlorodifluoromethane ug/L ND 5.0 12/20/15 18:490.21
Ethyl methacrylate ug/L ND 10.0 12/20/15 18:490.20
Ethylbenzene ug/L ND 1.0 12/20/15 18:490.30
Hexachloro-1,3-butadiene ug/L ND 10.0 12/20/15 18:490.71
Iodomethane ug/L ND 10.0 12/20/15 18:490.32
Isobutanol ug/L ND 100 12/20/15 18:4935.0
Methacrylonitrile ug/L ND 100 12/20/15 18:490.93
Methyl methacrylate ug/L ND 30.0 12/20/15 18:492.0
Methylene Chloride ug/L ND 1.0 12/20/15 18:490.97
Naphthalene ug/L ND 10.0 12/20/15 18:490.24
Propionitrile ug/L ND 150 12/20/15 18:493.6
Styrene ug/L ND 1.0 12/20/15 18:490.26
Tetrachloroethene ug/L ND 1.0 12/20/15 18:490.46
Tetrahydrofuran ug/L ND 10.0 12/20/15 18:493.1
Toluene ug/L ND 1.0 12/20/15 18:490.26
trans-1,2-Dichloroethene ug/L ND 5.0 12/20/15 18:490.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/20/15 18:490.26
trans-1,4-Dichloro-2-butene ug/L ND 100 12/20/15 18:491.0
Trichloroethene ug/L ND 1.0 12/20/15 18:490.47
Trichlorofluoromethane ug/L ND 1.0 12/20/15 18:490.20
Vinyl acetate ug/L ND 50.0 12/20/15 18:490.35
Vinyl chloride ug/L ND 1.0 12/20/15 18:490.62
Xylene (Total)ug/L ND 5.0 12/20/15 18:490.66
1,2-Dichloroethane-d4 (S)%92 70-130 12/20/15 18:49
4-Bromofluorobenzene (S)%102 70-130 12/20/15 18:49
Toluene-d8 (S)%111 70-130 12/20/15 18:49
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1634032LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.050 100 80-125
1,1,1-Trichloroethane ug/L 52.550 105 71-129
1,1,2,2-Tetrachloroethane ug/L 50.050 100 79-124
1,1,2-Trichloroethane ug/L 52.350 105 85-125
1,1-Dichloroethane ug/L 47.950 96 73-126
1,1-Dichloroethene ug/L 48.150 96 66-135
1,1-Dichloropropene ug/L 50.950 102 74-135
1,2,3-Trichloropropane ug/L 51.150 102 75-130
1,2,4-Trichlorobenzene ug/L 46.250 92 75-134
1,2-Dibromo-3-chloropropane ug/L 47.950 96 71-133
1,2-Dibromoethane (EDB)ug/L 53.950 108 83-124
1,2-Dichlorobenzene ug/L 47.150 94 80-133
1,2-Dichloroethane ug/L 45.250 90 67-128
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1634032LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichloropropane ug/L 48.250 96 75-132
1,3-Dichlorobenzene ug/L 48.250 96 77-130
1,3-Dichloropropane ug/L 51.550 103 76-131
1,4-Dichlorobenzene ug/L 49.650 99 78-130
2,2-Dichloropropane ug/L 48.650 97 40-160
2-Butanone (MEK)ug/L 109100 109 61-144
2-Hexanone ug/L 99.3100 99 68-143
4-Methyl-2-pentanone (MIBK)ug/L 101100 101 72-135
Acetone ug/L 104100 104 48-146
Acetonitrile ug/L 549500 110 62-150
Acrolein ug/L 305250 122 24-160
Acrylonitrile ug/L 260250 104 40-160
Allyl chloride ug/L 52.450 105 66-137
Benzene ug/L 53.550 107 80-125
Bromochloromethane ug/L 53.350 107 71-125
Bromodichloromethane ug/L 49.450 99 78-124
Bromoform ug/L 40.350 81 71-128
Bromomethane ug/L 40.050 80 40-160
Carbon disulfide ug/L 50.5J50 101 50-160
Carbon tetrachloride ug/L 50.350 101 69-131
Chlorobenzene ug/L 49.350 99 81-122
Chloroethane ug/L 43.650 87 39-148
Chloroform ug/L 49.850 100 73-127
Chloromethane ug/L 50.050 100 44-146
Chloroprene ug/L 55.750 111 75-145
cis-1,2-Dichloroethene ug/L 48.350 97 74-124
cis-1,3-Dichloropropene ug/L 52.650 105 72-132
Dibromochloromethane ug/L 51.250 102 78-125
Dibromomethane ug/L 52.250 104 82-120
Dichlorodifluoromethane ug/L 42.450 85 34-157
Ethyl methacrylate ug/L 45.750 91 82-121
Ethylbenzene ug/L 48.950 98 79-121
Hexachloro-1,3-butadiene ug/L 54.550 109 72-131
Iodomethane ug/L 78.3100 78 39-154
Isobutanol ug/L 9731000 97 34-160
Methacrylonitrile ug/L 541500 108 74-134
Methyl methacrylate ug/L 45.850 92 84-124
Methylene Chloride ug/L 58.350 117 64-133
Naphthalene ug/L 44.750 89 73-133
Propionitrile ug/L 525500 105 73-140
Styrene ug/L 49.450 99 84-126
Tetrachloroethene ug/L 48.950 98 78-122
Tetrahydrofuran ug/L 540500 108 69-148
Toluene ug/L 48.650 97 80-121
trans-1,2-Dichloroethene ug/L 50.150 100 71-127
trans-1,3-Dichloropropene ug/L 49.850 100 69-141
trans-1,4-Dichloro-2-butene ug/L 46.0J50 92 40-160
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1634032LABORATORY CONTROL SAMPLE:
LCSSpike
Trichloroethene ug/L 52.950 106 78-122
Trichlorofluoromethane ug/L 46.350 93 53-137
Vinyl acetate ug/L 101100 101 40-160
Vinyl chloride ug/L 50.050 100 58-137
Xylene (Total)ug/L 144150 96 81-126
1,2-Dichloroethane-d4 (S)%102 70-130
4-Bromofluorobenzene (S)%105 70-130
Toluene-d8 (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/39722
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples:92279347001, 92279347002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1628876
Associated Lab Samples:92279347001, 92279347002
Matrix:Water
AnalyzedMDL
4,4'-DDD ug/L ND 0.10 12/15/15 13:320.050
4,4'-DDE ug/L ND 0.10 12/15/15 13:320.050
4,4'-DDT ug/L ND 0.10 12/15/15 13:320.050
Aldrin ug/L ND 0.050 12/15/15 13:320.050
alpha-BHC ug/L ND 0.050 12/15/15 13:320.050
beta-BHC ug/L ND 0.050 12/15/15 13:320.050
Chlordane (Technical)ug/L ND 0.50 12/15/15 13:320.20
delta-BHC ug/L ND 0.050 12/15/15 13:320.050
Dieldrin ug/L ND 0.075 12/15/15 13:320.050
Endosulfan I ug/L ND 0.10 12/15/15 13:320.050
Endosulfan II ug/L ND 0.10 12/15/15 13:320.050
Endosulfan sulfate ug/L ND 0.10 12/15/15 13:320.050
Endrin ug/L ND 0.10 12/15/15 13:320.050
Endrin aldehyde ug/L ND 0.10 12/15/15 13:320.050
gamma-BHC (Lindane)ug/L ND 0.050 12/15/15 13:320.050
Heptachlor ug/L ND 0.050 12/15/15 13:320.050
Heptachlor epoxide ug/L ND 0.075 12/15/15 13:320.050
Methoxychlor ug/L ND 1.0 12/15/15 13:320.15
Toxaphene ug/L ND 1.5 12/15/15 13:320.20
Decachlorobiphenyl (S)%67 20-130 12/15/15 13:32
Tetrachloro-m-xylene (S)%83 20-130 12/15/15 13:32
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1628877LABORATORY CONTROL SAMPLE:
LCSSpike
4,4'-DDD ug/L 0.24.25 98 20-150
4,4'-DDE ug/L 0.24.25 95 20-150
4,4'-DDT ug/L 0.26.25 104 20-150
Aldrin ug/L 0.22.25 88 20-150
alpha-BHC ug/L 0.23.25 92 20-150
beta-BHC ug/L 0.24.25 95 20-150
delta-BHC ug/L 0.25.25 99 20-150
Dieldrin ug/L 0.24.25 98 20-150
Endosulfan I ug/L 0.24.25 96 20-150
Endosulfan II ug/L 0.25.25 99 20-150
Endosulfan sulfate ug/L 0.25.25 101 20-150
Endrin ug/L 0.25.25 102 20-150
Endrin aldehyde ug/L 0.23.25 94 20-150
gamma-BHC (Lindane)ug/L 0.23.25 94 20-150
Heptachlor ug/L 0.22.25 88 20-150
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1628877LABORATORY CONTROL SAMPLE:
LCSSpike
Heptachlor epoxide ug/L 0.23.25 95 20-150
Methoxychlor ug/L 0.75J.74 101 20-150
Decachlorobiphenyl (S)%78 20-130
Tetrachloro-m-xylene (S)%90 20-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1628878MATRIX SPIKE SAMPLE:
MSSpike
Result
92279302002
4,4'-DDD ug/L 0.20.25 81 20-150ND
4,4'-DDE ug/L 0.20.25 80 20-150ND
4,4'-DDT ug/L 0.21.25 83 20-150ND
Aldrin ug/L 0.18.25 71 20-150ND
alpha-BHC ug/L 0.20.25 79 20-150ND
beta-BHC ug/L 0.21.25 84 20-150ND
delta-BHC ug/L 0.21.25 86 20-150ND
Dieldrin ug/L 0.20.25 81 20-150ND
Endosulfan I ug/L 0.20.25 79 20-150ND
Endosulfan II ug/L 0.21.25 84 20-150ND
Endosulfan sulfate ug/L 0.21.25 83 20-150ND
Endrin ug/L 0.20.25 81 20-150ND
Endrin aldehyde ug/L 0.19.25 79 20-150ND
gamma-BHC (Lindane)ug/L 0.20.25 81 20-150ND
Heptachlor ug/L 0.18.25 71 20-150ND
Heptachlor epoxide ug/L 0.19.25 78 20-150ND
Methoxychlor ug/L 0.61J.74 82 20-150ND
Decachlorobiphenyl (S)%77 20-130
Tetrachloro-m-xylene (S)%72 20-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92279304003
1628879SAMPLE DUPLICATE:
4,4'-DDD ug/L ND 30ND
4,4'-DDE ug/L ND 30ND
4,4'-DDT ug/L ND 30ND
Aldrin ug/L ND 30ND
alpha-BHC ug/L ND 30ND
beta-BHC ug/L ND 30ND
Chlordane (Technical)ug/L ND 30ND
delta-BHC ug/L ND 30ND
Dieldrin ug/L ND 30ND
Endosulfan I ug/L ND 30ND
Endosulfan II ug/L ND 30ND
Endosulfan sulfate ug/L ND 30ND
Endrin ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92279304003
1628879SAMPLE DUPLICATE:
Endrin aldehyde ug/L ND 30ND
gamma-BHC (Lindane)ug/L ND 30ND
Heptachlor ug/L ND 30ND
Heptachlor epoxide ug/L ND 30ND
Methoxychlor ug/L ND 30ND
Toxaphene ug/L ND 30ND
Decachlorobiphenyl (S)%84 1671
Tetrachloro-m-xylene (S)%50 552
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/39678
EPA 3510
EPA 8082
8082 GCS PCB
Associated Lab Samples:92279347001, 92279347002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1627957
Associated Lab Samples:92279347001, 92279347002
Matrix:Water
AnalyzedMDL
PCB-1016 (Aroclor 1016)ug/L ND 0.50 12/15/15 05:040.50
PCB-1221 (Aroclor 1221)ug/L ND 0.50 12/15/15 05:040.50
PCB-1232 (Aroclor 1232)ug/L ND 0.50 12/15/15 05:040.50
PCB-1242 (Aroclor 1242)ug/L ND 0.50 12/15/15 05:040.50
PCB-1248 (Aroclor 1248)ug/L ND 0.50 12/15/15 05:040.50
PCB-1254 (Aroclor 1254)ug/L ND 0.50 12/15/15 05:040.50
PCB-1260 (Aroclor 1260)ug/L ND 0.50 12/15/15 05:040.50
Decachlorobiphenyl (S)%85 10-132 12/15/15 05:04
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1627958LABORATORY CONTROL SAMPLE:
LCSSpike
PCB-1016 (Aroclor 1016)ug/L 4.25 83 50-150
PCB-1260 (Aroclor 1260)ug/L 4.55 90 50-150
Decachlorobiphenyl (S)%90 10-132
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1627959MATRIX SPIKE SAMPLE:
MSSpike
Result
92279347001
PCB-1016 (Aroclor 1016)ug/L 3.45 67 50-150ND
PCB-1260 (Aroclor 1260)ug/L 3.65 72 50-150ND
Decachlorobiphenyl (S)%79 10-132
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92279347002
1627960SAMPLE DUPLICATE:
PCB-1016 (Aroclor 1016)ug/L ND 30ND
PCB-1221 (Aroclor 1221)ug/L ND 30ND
PCB-1232 (Aroclor 1232)ug/L ND 30ND
PCB-1242 (Aroclor 1242)ug/L ND 30ND
PCB-1248 (Aroclor 1248)ug/L ND 30ND
PCB-1254 (Aroclor 1254)ug/L ND 30ND
PCB-1260 (Aroclor 1260)ug/L ND 30ND
Decachlorobiphenyl (S)%66 1457
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/25723
EPA 8151
EPA 8151
8151A GCS Herbicides
Associated Lab Samples:92279347001, 92279347002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1420527
Associated Lab Samples:92279347001, 92279347002
Matrix:Water
AnalyzedMDL
2,4,5-T ug/L ND 0.19 12/17/15 17:070.042
2,4,5-TP (Silvex)ug/L ND 0.19 12/17/15 17:070.049
2,4-D ug/L ND 0.94 12/17/15 17:070.22
Dinoseb ug/L ND 0.19 12/17/15 17:070.057
2,4-DCAA (S)%53 36-130 12/17/15 17:07
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1420528LABORATORY CONTROL SAMPLE:
LCSSpike
2,4,5-T ug/L 0.791.2 66 40-130
2,4,5-TP (Silvex)ug/L 1.11.2 94 58-130
2,4-D ug/L 3.76 62 42-134
Dinoseb ug/L 0.841.2 70 10-157
2,4-DCAA (S)%77 36-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1424270MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279201003
1424271
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2,4,5-T ug/L 1.2 88 40-13062 35 401.2ND 1.1 0.74
2,4,5-TP (Silvex)ug/L 1.2 104 58-13069 40 401.2ND 1.2 0.83
2,4-D ug/L 6 88 42-13459 39 406ND5.3 3.6
Dinoseb ug/L R11.2 73 10-15748 41 401.2ND 0.88 0.58
2,4-DCAA (S)%81 36-13058 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/39746
EPA 3510
EPA 8270
8270 Water MSSV
Associated Lab Samples:92279347001, 92279347002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1629825
Associated Lab Samples:92279347001, 92279347002
Matrix:Water
AnalyzedMDL
1,2,4,5-Tetrachlorobenzene ug/L ND 10.0 12/21/15 16:141.7
1,3,5-Trinitrobenzene ug/L ND 10.0 12/21/15 16:141.1
1,3-Dinitrobenzene ug/L ND 20.0 12/21/15 16:141.5
1,4-Naphthoquinone ug/L ND 10.0 12/21/15 16:141.8
1-Naphthalenamine ug/L ND 10.0 12/21/15 16:140.96
2,3,4,6-Tetrachlorophenol ug/L ND 10.0 12/21/15 16:142.3
2,4,5-Trichlorophenol ug/L ND 10.0 12/21/15 16:142.2
2,4,6-Trichlorophenol ug/L ND 10.0 12/21/15 16:141.9
2,4-Dichlorophenol ug/L ND 10.0 12/21/15 16:141.7
2,4-Dimethylphenol ug/L ND 10.0 12/21/15 16:142.2
2,4-Dinitrophenol ug/L ND 50.0 12/21/15 16:146.5
2,4-Dinitrotoluene ug/L ND 10.0 12/21/15 16:141.2
2,6-Dichlorophenol ug/L ND 10.0 12/21/15 16:141.8
2,6-Dinitrotoluene ug/L ND 10.0 12/21/15 16:141.7
2-Acetylaminofluorene ug/L ND 20.0 12/21/15 16:140.84
2-Chloronaphthalene ug/L ND 10.0 12/21/15 16:142.2
2-Chlorophenol ug/L ND 10.0 12/21/15 16:141.5
2-Methylnaphthalene ug/L ND 10.0 12/21/15 16:140.28
2-Methylphenol(o-Cresol)ug/L ND 10.0 12/21/15 16:141.7
2-Naphthalenamine ug/L ND 10.0 12/21/15 16:140.98
2-Nitroaniline ug/L ND 50.0 12/21/15 16:142.8
2-Nitrophenol ug/L ND 10.0 12/21/15 16:141.7
3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 12/21/15 16:141.7
3,3'-Dichlorobenzidine ug/L ND 20.0 12/21/15 16:141.4
3,3'-Dimethylbenzidine ug/L ND 10.0 12/21/15 16:142.1
3-Methylcholanthrene ug/L ND 10.0 12/21/15 16:140.82
3-Nitroaniline ug/L ND 50.0 12/21/15 16:142.4
4,6-Dinitro-2-methylphenol ug/L ND 50.0 12/21/15 16:141.7
4-Aminobiphenyl ug/L ND 20.0 12/21/15 16:140.92
4-Bromophenylphenyl ether ug/L ND 10.0 12/21/15 16:141.3
4-Chloro-3-methylphenol ug/L ND 20.0 12/21/15 16:144.2
4-Chloroaniline ug/L ND 20.0 12/21/15 16:143.4
4-Chlorophenylphenyl ether ug/L ND 10.0 12/21/15 16:142.1
4-Nitroaniline ug/L ND 20.0 12/21/15 16:142.5
4-Nitrophenol ug/L ND 50.0 12/21/15 16:145.8
5-Nitro-o-toluidine ug/L ND 10.0 12/21/15 16:141.2
7,12-Dimethylbenz(a)anthracene ug/L ND 10.0 12/21/15 16:140.77
Acenaphthene ug/L ND 10.0 12/21/15 16:140.25
Acenaphthylene ug/L ND 10.0 12/21/15 16:140.21
Acetophenone ug/L ND 10.0 12/21/15 16:142.0
Anthracene ug/L ND 10.0 12/21/15 16:140.14
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1629825
Associated Lab Samples:92279347001, 92279347002
Matrix:Water
AnalyzedMDL
Benzo(a)anthracene ug/L ND 10.0 12/21/15 16:140.33
Benzo(a)pyrene ug/L ND 10.0 12/21/15 16:140.30
Benzo(b)fluoranthene ug/L ND 10.0 12/21/15 16:140.28
Benzo(g,h,i)perylene ug/L ND 10.0 12/21/15 16:140.38
Benzo(k)fluoranthene ug/L ND 10.0 12/21/15 16:140.43
Benzyl alcohol ug/L ND 20.0 12/21/15 16:143.4
bis(2-Chloroethoxy)methane ug/L ND 10.0 12/21/15 16:141.7
bis(2-Chloroethyl) ether ug/L ND 10.0 12/21/15 16:141.5
bis(2-Chloroisopropyl) ether ug/L ND 10.0 12/21/15 16:141.6
bis(2-Ethylhexyl)phthalate ug/L ND 15.0 12/21/15 16:140.85
Butylbenzylphthalate ug/L ND 10.0 12/21/15 16:140.75
Chlorobenzilate ug/L ND 10.0 12/21/15 16:140.72
Chrysene ug/L ND 10.0 12/21/15 16:140.21
Di-n-butylphthalate ug/L ND 10.0 12/21/15 16:141.1
Di-n-octylphthalate ug/L ND 10.0 12/21/15 16:140.86
Diallate ug/L ND 10.0 12/21/15 16:141.3
Dibenz(a,h)anthracene ug/L ND 10.0 12/21/15 16:140.55
Dibenzofuran ug/L ND 10.0 12/21/15 16:141.8
Diethylphthalate ug/L ND 6000 12/21/15 16:141.3
Dimethoate ug/L ND 20.0 12/21/15 16:140.92
Dimethylphthalate ug/L ND 10.0 12/21/15 16:141.5
Diphenylamine ug/L ND 10.0 12/21/15 16:141.3
Disulfoton ug/L ND 10.0 12/21/15 16:141.4
Ethyl methanesulfonate ug/L ND 20.0 12/21/15 16:141.8
Famphur ug/L ND 20.0 12/21/15 16:141.7
Fluoranthene ug/L ND 10.0 12/21/15 16:140.21
Fluorene ug/L ND 10.0 12/21/15 16:140.21
Hexachlorobenzene ug/L ND 10.0 12/21/15 16:141.1
Hexachlorocyclopentadiene ug/L ND 10.0 12/21/15 16:141.8
Hexachloroethane ug/L ND 10.0 12/21/15 16:141.5
Hexachloropropene ug/L ND 10.0 12/21/15 16:141.6
Indeno(1,2,3-cd)pyrene ug/L ND 10.0 12/21/15 16:140.29
Isodrin ug/L ND 20.0 12/21/15 16:142.0
Isophorone ug/L ND 10.0 12/21/15 16:141.8
Isosafrole ug/L ND 10.0 12/21/15 16:141.8
Kepone ug/L ND 20.0 12/21/15 16:143.1
Methapyrilene ug/L ND 100 12/21/15 16:142.7
Methyl methanesulfonate ug/L ND 10.0 12/21/15 16:141.3
Methyl parathion ug/L ND 10.0 12/21/15 16:141.1
N-Nitroso-di-n-butylamine ug/L ND 10.0 12/21/15 16:142.2
N-Nitroso-di-n-propylamine ug/L ND 10.0 12/21/15 16:142.1
N-Nitrosodiethylamine ug/L ND 20.0 12/21/15 16:141.8
N-Nitrosodimethylamine ug/L ND 10.0 12/21/15 16:141.3
N-Nitrosodiphenylamine ug/L ND 10.0 12/21/15 16:141.3
N-Nitrosomethylethylamine ug/L ND 10.0 12/21/15 16:141.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1629825
Associated Lab Samples:92279347001, 92279347002
Matrix:Water
AnalyzedMDL
N-Nitrosopiperidine ug/L ND 20.0 12/21/15 16:141.9
N-Nitrosopyrrolidine ug/L ND 10.0 12/21/15 16:142.5
Nitrobenzene ug/L ND 10.0 12/21/15 16:141.7
O,O,O-Triethylphosphorothioate ug/L ND 10.0 12/21/15 16:141.8
O-Toluidine ug/L ND 10.0 12/21/15 16:141.6
P-Dimethylaminoazobenzene ug/L ND 10.0 12/21/15 16:140.35
p-Phenylenediamine ug/L ND 10.0 12/21/15 16:140.96
Parathion (Ethyl parathion)ug/L ND 10.0 12/21/15 16:141.1
Pentachlorobenzene ug/L ND 10.0 12/21/15 16:142.0
Pentachloronitrobenzene ug/L ND 20.0 12/21/15 16:141.0
Pentachlorophenol ug/L ND 25.0 12/21/15 16:142.3
Phenacetin ug/L ND 20.0 12/21/15 16:140.97
Phenanthrene ug/L ND 10.0 12/21/15 16:140.22
Phenol ug/L ND 10.0 12/21/15 16:141.7
Phorate ug/L ND 10.0 12/21/15 16:141.1
Pronamide ug/L ND 10.0 12/21/15 16:140.97
Pyrene ug/L ND 10.0 12/21/15 16:140.19
Safrole ug/L ND 10.0 12/21/15 16:141.5
Thionazin ug/L ND 20.0 12/21/15 16:141.2
2,4,6-Tribromophenol (S)%94 27-110 12/21/15 16:14
2-Fluorobiphenyl (S)%73 27-110 12/21/15 16:14
2-Fluorophenol (S)%38 12-110 12/21/15 16:14
Nitrobenzene-d5 (S)%84 21-110 12/21/15 16:14
Phenol-d6 (S)%21 10-110 12/21/15 16:14
Terphenyl-d14 (S)%97 31-107 12/21/15 16:14
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1629826LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4,5-Tetrachlorobenzene ug/L 28.650 57 16-129
1,3,5-Trinitrobenzene ug/L 64.1 L05012855-125
1,3-Dinitrobenzene ug/L 42.850 86 30-122
1,4-Naphthoquinone ug/L 35.650 71 31-120
1-Naphthalenamine ug/L 31.150 62 37-126
2,3,4,6-Tetrachlorophenol ug/L 91.350 183 54-276
2,4,5-Trichlorophenol ug/L 34.750 69 43-113
2,4,6-Trichlorophenol ug/L 35.850 72 42-120
2,4-Dichlorophenol ug/L 51.450 103 30-120
2,4-Dimethylphenol ug/L 41.850 84 29-111
2,4-Dinitrophenol ug/L 263250 105 19-132
2,4-Dinitrotoluene ug/L 51.250 102 58-128
2,6-Dichlorophenol ug/L 45.750 91 54-128
2,6-Dinitrotoluene ug/L 41.450 83 54-129
2-Acetylaminofluorene ug/L 49.050 98 81-160
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1629826LABORATORY CONTROL SAMPLE:
LCSSpike
2-Chloronaphthalene ug/L 34.750 69 43-117
2-Chlorophenol ug/L 34.450 69 37-120
2-Methylnaphthalene ug/L 35.850 72 33-120
2-Methylphenol(o-Cresol)ug/L 21.850 44 31-120
2-Naphthalenamine ug/L 36.050 72 41-136
2-Nitroaniline ug/L 51.0100 51 48-121
2-Nitrophenol ug/L 48.250 96 25-116
3&4-Methylphenol(m&p Cresol)ug/L 51.250 102 23-120
3,3'-Dichlorobenzidine ug/L 89.4250 36 10-154
3,3'-Dimethylbenzidine ug/L 10.4100 10 10-157
3-Methylcholanthrene ug/L 42.250 84 65-130
3-Nitroaniline ug/L 95.2100 95 43-115
4,6-Dinitro-2-methylphenol ug/L 101100 101 44-124
4-Aminobiphenyl ug/L 33.050 66 21-125
4-Bromophenylphenyl ether ug/L 46.250 92 34-113
4-Chloro-3-methylphenol ug/L 80.9100 81 31-110
4-Chloroaniline ug/L 68.3100 68 20-120
4-Chlorophenylphenyl ether ug/L 32.550 65 34-116
4-Nitroaniline ug/L 73.8100 74 46-128
4-Nitrophenol ug/L 104250 42 11-120
5-Nitro-o-toluidine ug/L 44.350 89 78-160
7,12-Dimethylbenz(a)anthracene ug/L 47.350 95 47-124
Acenaphthene ug/L 43.650 87 48-114
Acenaphthylene ug/L 40.850 82 48-112
Acetophenone ug/L 27.950 56 24-120
Anthracene ug/L 48.450 97 57-118
Benzo(a)anthracene ug/L 49.550 99 56-121
Benzo(a)pyrene ug/L 46.850 94 55-127
Benzo(b)fluoranthene ug/L 42.450 85 53-128
Benzo(g,h,i)perylene ug/L 37.150 74 54-125
Benzo(k)fluoranthene ug/L 51.950 104 51-123
Benzyl alcohol ug/L 60.9100 61 27-120
bis(2-Chloroethoxy)methane ug/L 48.250 96 32-120
bis(2-Chloroethyl) ether ug/L 29.750 59 33-111
bis(2-Chloroisopropyl) ether ug/L 11.650 23 15-120
bis(2-Ethylhexyl)phthalate ug/L 58.750 117 50-145
Butylbenzylphthalate ug/L 58.250 116 54-138
Chlorobenzilate ug/L 55.950 112 65-132
Chrysene ug/L 48.950 98 58-127
Di-n-butylphthalate ug/L 59.550 119 56-125
Di-n-octylphthalate ug/L 52.250 104 50-134
Diallate ug/L 47.450 95 47-123
Dibenz(a,h)anthracene ug/L 36.950 74 53-129
Dibenzofuran ug/L 43.250 86 45-120
Diethylphthalate ug/L 41.6J50 83 53-120
Dimethoate ug/L 46.250 92 57-139
Dimethylphthalate ug/L 37.050 74 55-116
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1629826LABORATORY CONTROL SAMPLE:
LCSSpike
Diphenylamine ug/L 47.050 94 42-120
Disulfoton ug/L 45.550 91 49-156
Ethyl methanesulfonate ug/L 42.250 84 43-120
Famphur ug/L 73.0100 73 40-160
Fluoranthene ug/L 64.6 L05012957-125
Fluorene ug/L 36.650 73 53-118
Hexachlorobenzene ug/L 51.250 102 49-116
Hexachlorocyclopentadiene ug/L 16.950 34 26-158
Hexachloroethane ug/L 32.050 64 30-114
Hexachloropropene ug/L 30.850 62 13-137
Indeno(1,2,3-cd)pyrene ug/L 37.350 75 55-128
Isodrin ug/L 66.4 L05013368-129
Isophorone ug/L 42.050 84 31-118
Isosafrole ug/L 34.050 68 48-107
Kepone ug/L 39.2100 39 10-124
Methapyrilene ug/L 3.6J L050740-160
Methyl methanesulfonate ug/L 23.650 47 25-114
Methyl parathion ug/L 52.750 105 58-137
N-Nitroso-di-n-butylamine ug/L 32.550 65 36-115
N-Nitroso-di-n-propylamine ug/L 24.850 50 32-119
N-Nitrosodiethylamine ug/L 40.350 81 47-115
N-Nitrosodimethylamine ug/L 19.250 38 13-120
N-Nitrosodiphenylamine ug/L 47.050 94 43-120
N-Nitrosomethylethylamine ug/L 31.750 63 39-120
N-Nitrosopiperidine ug/L 55.250 110 43-113
N-Nitrosopyrrolidine ug/L 32.150 64 32-110
Nitrobenzene ug/L 40.750 81 33-110
O,O,O-Triethylphosphorothioate ug/L 49.450 99 51-127
O-Toluidine ug/L 31.050 62 27-120
P-Dimethylaminoazobenzene ug/L 27.3100 27 10-120
p-Phenylenediamine ug/L 50.450 101 72-143
Parathion (Ethyl parathion)ug/L 51.550 103 56-140
Pentachlorobenzene ug/L 42.650 85 30-137
Pentachloronitrobenzene ug/L 55.550 111 70-124
Pentachlorophenol ug/L 92.5250 37 10-137
Phenacetin ug/L 51.350 103 60-130
Phenanthrene ug/L 46.450 93 57-117
Phenol ug/L 15.250 30 10-120
Phorate ug/L 63.4 L05012755-126
Pronamide ug/L 60.450 121 75-124
Pyrene ug/L 56.250 112 55-122
Safrole ug/L 39.050 78 41-120
Thionazin ug/L 36.750 73 63-137
2,4,6-Tribromophenol (S)%S011527-110
2-Fluorobiphenyl (S)%62 27-110
2-Fluorophenol (S)%38 12-110
Nitrobenzene-d5 (S)%95 21-110
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1629826LABORATORY CONTROL SAMPLE:
LCSSpike
Phenol-d6 (S)%26 10-110
Terphenyl-d14 (S)%104 31-107
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1629827MATRIX SPIKE SAMPLE:
MSSpike
Result
92278963015
1,2,4,5-Tetrachlorobenzene ug/L 28.450 57 50-150ND
1,3,5-Trinitrobenzene ug/L 57.150 114 50-150ND
1,3-Dinitrobenzene ug/L 45.450 91 50-150ND
1,4-Naphthoquinone ug/L 35.950 72 50-150ND
1-Naphthalenamine ug/L 27.550 55 50-150ND
2,3,4,6-Tetrachlorophenol ug/L 66.050 132 50-150ND
2,4,5-Trichlorophenol ug/L 30.150 60 19-105ND
2,4,6-Trichlorophenol ug/L 30.750 61 13-108ND
2,4-Dichlorophenol ug/L 32.650 65 29-111ND
2,4-Dimethylphenol ug/L 28.050 56 21-103ND
2,4-Dinitrophenol ug/L 126250 50 10-109ND
2,4-Dinitrotoluene ug/L 42.850 86 27-104ND
2,6-Dichlorophenol ug/L 43.350 87 50-150ND
2,6-Dinitrotoluene ug/L 43.850 88 28-101ND
2-Acetylaminofluorene ug/L 45.350 91 50-150ND
2-Chloronaphthalene ug/L 32.950 66 14-102ND
2-Chlorophenol ug/L 37.050 74 16-110ND
2-Methylnaphthalene ug/L 29.850 60 13-110ND
2-Methylphenol(o-Cresol)ug/L 32.950 66 19-110ND
2-Naphthalenamine ug/L 29.750 59 50-150ND
2-Nitroaniline ug/L 44.5J100 45 26-103ND
2-Nitrophenol ug/L 32.250 64 20-110ND
3&4-Methylphenol(m&p Cresol)ug/L 67.1 M15013420-110ND
3,3'-Dichlorobenzidine ug/L 88.3250 35 25-112ND
3,3'-Dimethylbenzidine ug/L 58.1100 58 50-150ND
3-Methylcholanthrene ug/L 44.250 77 50-1505.4J
3-Nitroaniline ug/L 79.0100 79 29-110ND
4,6-Dinitro-2-methylphenol ug/L 84.3100 84 10-117ND
4-Aminobiphenyl ug/L 41.850 84 50-150ND
4-Bromophenylphenyl ether ug/L 40.650 81 20-105ND
4-Chloro-3-methylphenol ug/L 64.6100 65 22-110ND
4-Chloroaniline ug/L 71.4100 71 20-100ND
4-Chlorophenylphenyl ether ug/L 30.850 62 19-102ND
4-Nitroaniline ug/L 67.3100 67 29-110ND
4-Nitrophenol ug/L 62.9250 25 10-110ND
5-Nitro-o-toluidine ug/L 39.050 78 50-150ND
7,12-Dimethylbenz(a)anthracene ug/L 49.950 100 50-150ND
Acenaphthene ug/L 41.350 83 17-100ND
Acenaphthylene ug/L 41.350 83 21-100ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1629827MATRIX SPIKE SAMPLE:
MSSpike
Result
92278963015
Acetophenone ug/L 41.650 83 50-150ND
Anthracene ug/L 44.450 89 24-109ND
Benzo(a)anthracene ug/L 45.850 92 22-117ND
Benzo(a)pyrene ug/L 45.050 90 23-104ND
Benzo(b)fluoranthene ug/L 45.850 92 23-103ND
Benzo(g,h,i)perylene ug/L 38.750 77 18-111ND
Benzo(k)fluoranthene ug/L 53.250 106 22-113ND
Benzyl alcohol ug/L 64.2100 64 19-101ND
bis(2-Chloroethoxy)methane ug/L 24.750 49 22-110ND
bis(2-Chloroethyl) ether ug/L 29.850 60 16-110ND
bis(2-Chloroisopropyl) ether ug/L 23.650 47 14-110ND
bis(2-Ethylhexyl)phthalate ug/L 58.8 M15011823-102ND
Butylbenzylphthalate ug/L 60.3 M15012125-110ND
Chlorobenzilate ug/L 54.950 110 50-150ND
Chrysene ug/L 44.350 89 23-115ND
Di-n-butylphthalate ug/L 59.4 M15011926-110ND
Di-n-octylphthalate ug/L 42.450 85 22-110ND
Diallate ug/L 39.150 78 50-150ND
Dibenz(a,h)anthracene ug/L 45.750 91 21-112ND
Dibenzofuran ug/L 37.950 76 19-102ND
Diethylphthalate ug/L 34.5J50 69 29-110ND
Dimethoate ug/L 40.450 81 50-150ND
Dimethylphthalate ug/L 41.650 83 27-110ND
Diphenylamine ug/L 48.350 97 50-150ND
Disulfoton ug/L 43.150 86 50-150ND
Ethyl methanesulfonate ug/L 28.850 58 50-150ND
Famphur ug/L 35.6 M11003650-150ND
Fluoranthene ug/L 63.2 M05012623-112ND
Fluorene ug/L 33.350 67 22-104ND
Hexachlorobenzene ug/L 46.950 94 21-116ND
Hexachlorocyclopentadiene ug/L 16.550 33 10-110ND
Hexachloroethane ug/L 33.850 68 10-110ND
Hexachloropropene ug/L 32.050 64 50-150ND
Indeno(1,2,3-cd)pyrene ug/L 47.050 94 20-113ND
Isodrin ug/L 66.050 132 50-150ND
Isophorone ug/L 24.6 M1504950-150ND
Isosafrole ug/L 33.950 68 50-150ND
Kepone ug/L 44.0 M11004450-150ND
Methapyrilene ug/L 42.3J50 85 50-150ND
Methyl methanesulfonate ug/L 27.450 55 50-150ND
Methyl parathion ug/L 47.650 95 50-150ND
N-Nitroso-di-n-butylamine ug/L 24.0 M1504850-150ND
N-Nitroso-di-n-propylamine ug/L 38.950 78 21-105ND
N-Nitrosodiethylamine ug/L 30.550 61 50-150ND
N-Nitrosodimethylamine ug/L 19.550 39 10-110ND
N-Nitrosodiphenylamine ug/L 48.350 97 23-107ND
N-Nitrosomethylethylamine ug/L 31.850 64 50-150ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1629827MATRIX SPIKE SAMPLE:
MSSpike
Result
92278963015
N-Nitrosopiperidine ug/L 32.150 64 50-150ND
N-Nitrosopyrrolidine ug/L 46.750 93 50-150ND
Nitrobenzene ug/L 22.650 45 20-110ND
O,O,O-Triethylphosphorothioate ug/L 33.150 66 50-150ND
O-Toluidine ug/L 41.450 83 50-150ND
P-Dimethylaminoazobenzene ug/L 25.8 M11002650-150ND
p-Phenylenediamine ug/L 38.550 77 50-150ND
Parathion (Ethyl parathion)ug/L 63.650 127 50-150ND
Pentachlorobenzene ug/L 37.750 75 50-150ND
Pentachloronitrobenzene ug/L 50.850 102 50-150ND
Pentachlorophenol ug/L 80.7250 32 10-118ND
Phenacetin ug/L 47.450 95 50-150ND
Phenanthrene ug/L 43.150 86 24-106ND
Phenol ug/L 13.050 26 12-110ND
Phorate ug/L 56.550 113 50-150ND
Pronamide ug/L 55.750 111 50-150ND
Pyrene ug/L 53.050 106 24-114ND
Safrole ug/L 33.150 66 50-150ND
Thionazin ug/L 34.350 69 50-150ND
2,4,6-Tribromophenol (S)%99 27-110
2-Fluorobiphenyl (S)%57 27-110
2-Fluorophenol (S)%26 12-110
Nitrobenzene-d5 (S)%49 21-110
Phenol-d6 (S)%21 10-110
Terphenyl-d14 (S)%90 31-107
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278963016
1629828SAMPLE DUPLICATE:
1,2,4,5-Tetrachlorobenzene ug/L ND 30ND
1,3,5-Trinitrobenzene ug/L ND 30ND
1,3-Dinitrobenzene ug/L ND 30ND
1,4-Naphthoquinone ug/L ND 30ND
1-Naphthalenamine ug/L ND 30ND
2,3,4,6-Tetrachlorophenol ug/L ND 30ND
2,4,5-Trichlorophenol ug/L ND 30ND
2,4,6-Trichlorophenol ug/L ND 30ND
2,4-Dichlorophenol ug/L ND 30ND
2,4-Dimethylphenol ug/L ND 30ND
2,4-Dinitrophenol ug/L ND 30ND
2,4-Dinitrotoluene ug/L ND 30ND
2,6-Dichlorophenol ug/L ND 30ND
2,6-Dinitrotoluene ug/L ND 30ND
2-Acetylaminofluorene ug/L ND 30ND
2-Chloronaphthalene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278963016
1629828SAMPLE DUPLICATE:
2-Chlorophenol ug/L ND 30ND
2-Methylnaphthalene ug/L ND 30ND
2-Methylphenol(o-Cresol)ug/L ND 30ND
2-Naphthalenamine ug/L ND 30ND
2-Nitroaniline ug/L ND 30ND
2-Nitrophenol ug/L ND 30ND
3&4-Methylphenol(m&p Cresol)ug/L ND 30ND
3,3'-Dichlorobenzidine ug/L ND 30ND
3,3'-Dimethylbenzidine ug/L ND 30ND
3-Methylcholanthrene ug/L ND 30ND
3-Nitroaniline ug/L ND 30ND
4,6-Dinitro-2-methylphenol ug/L ND 30ND
4-Aminobiphenyl ug/L ND 30ND
4-Bromophenylphenyl ether ug/L ND 30ND
4-Chloro-3-methylphenol ug/L ND 30ND
4-Chloroaniline ug/L ND 30ND
4-Chlorophenylphenyl ether ug/L ND 30ND
4-Nitroaniline ug/L ND 30ND
4-Nitrophenol ug/L ND 30ND
5-Nitro-o-toluidine ug/L NDND
7,12-Dimethylbenz(a)anthracene ug/L ND 30ND
Acenaphthene ug/L ND 30ND
Acenaphthylene ug/L ND 30ND
Acetophenone ug/L ND 30ND
Anthracene ug/L ND 30ND
Benzo(a)anthracene ug/L ND 30ND
Benzo(a)pyrene ug/L ND 30ND
Benzo(b)fluoranthene ug/L ND 30ND
Benzo(g,h,i)perylene ug/L ND 30ND
Benzo(k)fluoranthene ug/L ND 30ND
Benzyl alcohol ug/L ND 30ND
bis(2-Chloroethoxy)methane ug/L ND 30ND
bis(2-Chloroethyl) ether ug/L ND 30ND
bis(2-Chloroisopropyl) ether ug/L ND 30ND
bis(2-Ethylhexyl)phthalate ug/L ND 30ND
Butylbenzylphthalate ug/L ND 30ND
Chlorobenzilate ug/L ND 30ND
Chrysene ug/L ND 30ND
Di-n-butylphthalate ug/L ND 30ND
Di-n-octylphthalate ug/L ND 30ND
Diallate ug/L ND 30ND
Dibenz(a,h)anthracene ug/L ND 30ND
Dibenzofuran ug/L ND 30ND
Diethylphthalate ug/L ND 30ND
Dimethoate ug/L ND 30ND
Dimethylphthalate ug/L ND 30ND
Diphenylamine ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 44 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278963016
1629828SAMPLE DUPLICATE:
Disulfoton ug/L ND 30ND
Ethyl methanesulfonate ug/L ND 30ND
Famphur ug/L ND 30ND
Fluoranthene ug/L ND 30ND
Fluorene ug/L ND 30ND
Hexachlorobenzene ug/L ND 30ND
Hexachlorocyclopentadiene ug/L ND 30ND
Hexachloroethane ug/L ND 30ND
Hexachloropropene ug/L ND 30ND
Indeno(1,2,3-cd)pyrene ug/L ND 30ND
Isodrin ug/L ND 30ND
Isophorone ug/L ND 30ND
Isosafrole ug/L ND 30ND
Kepone ug/L ND 30ND
Methapyrilene ug/L ND 30ND
Methyl methanesulfonate ug/L ND 30ND
Methyl parathion ug/L ND 30ND
N-Nitroso-di-n-butylamine ug/L ND 30ND
N-Nitroso-di-n-propylamine ug/L ND 30ND
N-Nitrosodiethylamine ug/L ND 30ND
N-Nitrosodimethylamine ug/L ND 30ND
N-Nitrosodiphenylamine ug/L ND 30ND
N-Nitrosomethylethylamine ug/L ND 30ND
N-Nitrosopiperidine ug/L ND 30ND
N-Nitrosopyrrolidine ug/L ND 30ND
Nitrobenzene ug/L ND 30ND
O,O,O-Triethylphosphorothioate ug/L ND 30ND
O-Toluidine ug/L ND 30ND
P-Dimethylaminoazobenzene ug/L ND 30ND
p-Phenylenediamine ug/L ND 30ND
Parathion (Ethyl parathion)ug/L ND 30ND
Pentachlorobenzene ug/L ND 30ND
Pentachloronitrobenzene ug/L ND 30ND
Pentachlorophenol ug/L ND 30ND
Phenacetin ug/L ND 30ND
Phenanthrene ug/L ND 30ND
Phenol ug/L ND 30ND
Phorate ug/L ND 30ND
Pronamide ug/L ND 30ND
Pyrene ug/L ND 30ND
Safrole ug/L ND 30ND
Thionazin ug/L ND 30ND
2,4,6-Tribromophenol (S)%64 1070
2-Fluorobiphenyl (S)%65 971
2-Fluorophenol (S)%31 1235
Nitrobenzene-d5 (S)%68 1277
Phenol-d6 (S)%18 1722
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 45 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278963016
1629828SAMPLE DUPLICATE:
Terphenyl-d14 (S)%83 778
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 46 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/41955
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92279347001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1628049
Associated Lab Samples:92279347001
Matrix:Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 12/14/15 13:291000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1628050LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 4850050000 97 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1628051MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278963003
1628052
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L M1,R1500009980-12012 25 2550000150 mg/L 200000 156000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1628053MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278963011
1628054
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L M1500007480-120131 4 2550000596 mg/L 633000 662000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 47 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/41916
SM 2540C
SM 2540C
2540C Total Dissolved Solids
Associated Lab Samples:92279347001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1626642
Associated Lab Samples:92279347001
Matrix:Water
AnalyzedMDL
Total Dissolved Solids ug/L ND 25000 12/11/15 10:3925000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1626643LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids ug/L 246000250000 98 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92279178001
1626644SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 316000 4 5330 mg/L
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278979001
1626645SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 320000 D675299 mg/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 48 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/41914
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92279347001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1626491
Associated Lab Samples:92279347001
Matrix:Water
AnalyzedMDL
Sulfide ug/L ND 1000 12/11/15 15:00100
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1626492LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide ug/L 504J500 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1626493MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279262001
1626494
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 91 90-11091 0 10500ND457J457J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1626495MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279262011
1626496
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 94 90-11094 0 10500ND470J470J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 49 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/41938
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92279347002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1627829
Associated Lab Samples:92279347002
Matrix:Water
AnalyzedMDL
Sulfide ug/L ND 1000 12/14/15 12:30100
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1627830LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide ug/L 506J500 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1627831MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279347002
1627832
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 92 90-11092 0 10500ND462J462J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1627833MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279409003
1627834
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L M15008990-11089 0 10500ND444J444J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 50 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/25748
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples:92279347001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1626618
Associated Lab Samples:92279347001
Matrix:Water
AnalyzedMDL
Sulfate ug/L ND 250000 12/11/15 14:061000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1626619LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 21000J20000 105 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1626620MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278963003
1626621
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 103 90-110103 1 102000010.1 mg/L 30600J 30800J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1626622MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279395006
1626623
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 102 90-110104 1 10200009260J29800J30100J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 51 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/25851
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples:92279347001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1633380
Associated Lab Samples:92279347001
Matrix:Water
AnalyzedMDL
Chloride ug/L ND 1000 12/18/15 17:52500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1633381LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 1990020000 99 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1633382MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92280333001
1633383
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L 20000 101 90-110101 0 10200003.0 mg/L 23300 23200
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1633384MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279763005
1633385
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M11000006890-11068 0 1010000063.2 mg/L 132000 131000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 52 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/25788
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples:92279347001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1628959
Associated Lab Samples:92279347001
Matrix:Water
AnalyzedMDL
Cyanide ug/L ND 10.0 12/16/15 10:524.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1628960LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 90.6100 91 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1628961MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279059001
1628962
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 115 75-125116 1 10100ND120121
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1628963MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278760008
1628964
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 102 75-12598 3 101000.0096
mg/L 112 108
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 53 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/25789
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples:92279347002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1628965
Associated Lab Samples:92279347002
Matrix:Water
AnalyzedMDL
Cyanide ug/L ND 10.0 12/16/15 11:204.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1628966LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 95.2100 95 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1628967MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279219001
1628968
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 109 75-125113 4 10100ND112116
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1628969MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279489002
1628970
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 99 75-125106 7 10100ND102109
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 54 of 58
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Common Laboratory Contaminant.C9
The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.D6
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.L2
Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples. Results unaffected by high bias.L3
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
Surrogate recovery outside laboratory control limits.S0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 55 of 58
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92279347
BURKE CO. JOHN'S R-BG & BLANKS
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92279347001 OEXT/39722 GCSV/235551203-MW21 EPA 3510 EPA 8081
92279347002 OEXT/39722 GCSV/235551203-FIELD BLANK EPA 3510 EPA 8081
92279347001 OEXT/39678 GCSV/235231203-MW21 EPA 3510 EPA 8082
92279347002 OEXT/39678 GCSV/235231203-FIELD BLANK EPA 3510 EPA 8082
92279347001 OEXT/25723 GCSV/167651203-MW21 EPA 8151 EPA 8151
92279347002 OEXT/25723 GCSV/167651203-FIELD BLANK EPA 8151 EPA 8151
92279347001 MPRP/20260 ICP/182841203-MW21 EPA 3010A EPA 6010
92279347002 MPRP/20260 ICP/182841203-FIELD BLANK EPA 3010A EPA 6010
92279347001 MERP/8788 MERC/84421203-MW21 EPA 7470 EPA 7470
92279347002 MERP/8788 MERC/84421203-FIELD BLANK EPA 7470 EPA 7470
92279347001 OEXT/39746 MSSV/116701203-MW21 EPA 3510 EPA 8270
92279347002 OEXT/39746 MSSV/116701203-FIELD BLANK EPA 3510 EPA 8270
92279347001 MSV/347861203-MW21 EPA 8260
92279347002 MSV/348201203-FIELD BLANK EPA 8260
92279347003 MSV/347861203-TRIP BLANK EPA 8260
92279347001 WET/419551203-MW21 SM 2320B
92279347001 WET/419161203-MW21 SM 2540C
92279347001 WET/419141203-MW21 SM 4500-S2D
92279347002 WET/419381203-FIELD BLANK SM 4500-S2D
92279347001 WETA/257481203-MW21 EPA 300.0
92279347001 WETA/258511203-MW21 SM 4500-Cl-E
92279347001 WETA/257881203-MW21 SM 4500-CN-E
92279347002 WETA/257891203-FIELD BLANK SM 4500-CN-E
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 05:21 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 56 of 58
Page 57 of 58
Page 58 of 58
#=CL#
December 29, 2015
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92279394
92279394
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
BURKE-JOHN'S R.-ADD. WELLS LFG
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on December 10, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc:Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 21
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92279394
BURKE-JOHN'S R.-ADD. WELLS LFG
Minnesota Certification IDs1700 Elm Street SE Suite 200, Minneapolis, MN 55414525 N 8th Street, Salina, KS 67401
A2LA Certification #: 2926.01Alaska Certification #: UST-078Alaska Certification #MN00064Alabama Certification #40770Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680California Certification #: 01155CAColorado Certification #PaceConnecticut Certification #: PH-0256EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605Guam Certification #:14-008rGeorgia Certification #: 959Georgia EPD #: PaceIdaho Certification #: MN00064
Hawaii Certification #MN00064Illinois Certification #: 200011Indiana Certification#C-MN-01Iowa Certification #: 368Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062Kentucky Dept of Envi. Protection - WW #:90062Louisiana DEQ Certification #: 3086Louisiana DHH #: LA140001Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909Minnesota Certification #: 027-053-137
Mississippi Certification #: PaceMontana Certification #: MT0092Nevada Certification #: MN_00064Nebraska Certification #: PaceNew Jersey Certification #: MN-002
New York Certification #: 11647North Carolina Certification #: 530North Carolina State Public Health #: 27700North Dakota Certification #: R-036Ohio EPA #: 4150
Ohio VAP Certification #: CL101Oklahoma Certification #: 9507Oregon Certification #: MN200001Oregon Certification #: MN300001Pennsylvania Certification #: 68-00563
Puerto Rico CertificationSaipan (CNMI) #:MP0003South Carolina #:74003001Texas Certification #: T104704192Tennessee Certification #: 02818
Utah Certification #: MN000642013-4Virginia DGS Certification #: 251Washington Certification #: C486West Virginia Certification #: 382West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84West Virginia Certification #: 357
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 21
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92279394
BURKE-JOHN'S R.-ADD. WELLS LFG
Lab ID Sample ID Matrix Date Collected Date Received
92279394001 1203-MW15S Water 12/09/15 13:11 12/10/15 10:48
92279394002 1203-PZ12 Water 12/09/15 10:50 12/10/15 10:48
92279394003 1203-PZ30S Water 12/08/15 15:15 12/10/15 10:48
92279394004 1203-PZ31 Water 12/08/15 15:23 12/10/15 10:48
92279394005 1203-PZ35 Water 12/09/15 14:45 12/10/15 10:48
92279394006 1203-PZ36 Water 12/09/15 14:15 12/10/15 10:48
92279394007 1203-MW38 Water 12/09/15 14:30 12/10/15 10:48
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 21
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92279394
BURKE-JOHN'S R.-ADD. WELLS LFG
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92279394001 1203-MW15S RSK 175 1 PASI-MDR1
EPA 8260 11 PASI-CGAW
92279394002 1203-PZ12 RSK 175 1 PASI-MDR1
EPA 8260 11 PASI-CGAW
92279394003 1203-PZ30S RSK 175 1 PASI-MDR1
EPA 8260 11 PASI-CGAW
92279394004 1203-PZ31 RSK 175 1 PASI-MDR1
EPA 8260 11 PASI-CGAW
92279394005 1203-PZ35 RSK 175 1 PASI-MDR1
EPA 8260 11 PASI-CGAW
92279394006 1203-PZ36 RSK 175 1 PASI-MDR1
EPA 8260 11 PASI-CGAW
92279394007 1203-MW38 RSK 175 1 PASI-MDR1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 21
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92279394
BURKE-JOHN'S R.-ADD. WELLS LFG
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92279394001 1203-MW15S
Methane 8550 ug/L 12/16/15 12:0910.0RSK 175
Benzene 1.2 ug/L 12/20/15 21:381.0EPA 8260
1,4-Dichlorobenzene 1.0 ug/L 12/20/15 21:381.0EPA 8260
1,1-Dichloroethane 2.2J ug/L 12/20/15 21:385.0EPA 8260
Methylene Chloride 2.6 ug/L 12/20/15 21:38 C91.0EPA 8260
Tetrachloroethene 2.1 ug/L 12/20/15 21:381.0EPA 8260
Trichloroethene 1.1 ug/L 12/20/15 21:381.0EPA 8260
92279394002 1203-PZ12
Methane 3.0J ug/L 12/16/15 12:1710.0RSK 175
92279394003 1203-PZ30S
Methane 2.5J ug/L 12/15/15 16:4810.0RSK 175
92279394004 1203-PZ31
Methane 4.8J ug/L 12/15/15 17:0410.0RSK 175
92279394005 1203-PZ35
Methane 2.7J ug/L 12/16/15 12:2510.0RSK 175
92279394006 1203-PZ36
Methane 3780 ug/L 12/16/15 11:1910.0RSK 175
Benzene 5.8 ug/L 12/20/15 22:291.0EPA 8260
1,4-Dichlorobenzene 19.6 ug/L 12/20/15 22:291.0EPA 8260
1,1-Dichloroethane 5.9 ug/L 12/20/15 22:295.0EPA 8260
1,2-Dichloroethane 0.66J ug/L 12/20/15 22:291.0EPA 8260
Methylene Chloride 11.2 ug/L 12/20/15 22:291.0EPA 8260
Tetrachloroethene 5.0 ug/L 12/20/15 22:291.0EPA 8260
Trichloroethene 2.9 ug/L 12/20/15 22:291.0EPA 8260
Vinyl chloride 0.80J ug/L 12/20/15 22:291.0EPA 8260
92279394007 1203-MW38
Methane 3120 ug/L 12/16/15 14:5010.0RSK 175
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279394
BURKE-JOHN'S R.-ADD. WELLS LFG
Sample:1203-MW15S Lab ID:92279394001 Collected:12/09/15 13:11 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 8550 ug/L 12/16/15 12:09 74-82-810.0 0.63 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene 1.2 ug/L 12/20/15 21:38 71-43-21.0 0.25 1
1,4-Dichlorobenzene 1.0 ug/L 12/20/15 21:38 106-46-71.0 0.33 1
1,1-Dichloroethane 2.2J ug/L 12/20/15 21:38 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/20/15 21:38 107-06-21.0 0.24 1
Methylene Chloride 2.6 ug/L 12/20/15 21:38 75-09-2 C91.0 0.97 1
Tetrachloroethene 2.1 ug/L 12/20/15 21:38 127-18-41.0 0.46 1
Trichloroethene 1.1 ug/L 12/20/15 21:38 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 12/20/15 21:38 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)101 %12/20/15 21:38 460-00-470-130 1
1,2-Dichloroethane-d4 (S)96 %12/20/15 21:38 17060-07-070-130 1
Toluene-d8 (S)106 %12/20/15 21:38 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 07:52 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279394
BURKE-JOHN'S R.-ADD. WELLS LFG
Sample:1203-PZ12 Lab ID:92279394002 Collected:12/09/15 10:50 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 3.0J ug/L 12/16/15 12:17 74-82-810.0 0.63 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 12/20/15 21:55 71-43-21.0 0.25 1
1,4-Dichlorobenzene ND ug/L 12/20/15 21:55 106-46-71.0 0.33 1
1,1-Dichloroethane ND ug/L 12/20/15 21:55 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/20/15 21:55 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 12/20/15 21:55 75-09-21.0 0.97 1
Tetrachloroethene ND ug/L 12/20/15 21:55 127-18-41.0 0.46 1
Trichloroethene ND ug/L 12/20/15 21:55 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 12/20/15 21:55 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)104 %12/20/15 21:55 460-00-470-130 1
1,2-Dichloroethane-d4 (S)96 %12/20/15 21:55 17060-07-070-130 1
Toluene-d8 (S)109 %12/20/15 21:55 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 07:52 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279394
BURKE-JOHN'S R.-ADD. WELLS LFG
Sample:1203-PZ30S Lab ID:92279394003 Collected:12/08/15 15:15 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 2.5J ug/L 12/15/15 16:48 74-82-810.0 0.63 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 12/19/15 10:18 71-43-21.0 0.25 1
1,4-Dichlorobenzene ND ug/L 12/19/15 10:18 106-46-71.0 0.33 1
1,1-Dichloroethane ND ug/L 12/19/15 10:18 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/19/15 10:18 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 12/19/15 10:18 75-09-21.0 0.97 1
Tetrachloroethene ND ug/L 12/19/15 10:18 127-18-41.0 0.46 1
Trichloroethene ND ug/L 12/19/15 10:18 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 12/19/15 10:18 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)104 %12/19/15 10:18 460-00-470-130 1
1,2-Dichloroethane-d4 (S)95 %12/19/15 10:18 17060-07-070-130 1
Toluene-d8 (S)112 %12/19/15 10:18 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 07:52 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279394
BURKE-JOHN'S R.-ADD. WELLS LFG
Sample:1203-PZ31 Lab ID:92279394004 Collected:12/08/15 15:23 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 4.8J ug/L 12/15/15 17:04 74-82-810.0 0.63 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 12/19/15 10:35 71-43-21.0 0.25 1
1,4-Dichlorobenzene ND ug/L 12/19/15 10:35 106-46-71.0 0.33 1
1,1-Dichloroethane ND ug/L 12/19/15 10:35 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/19/15 10:35 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 12/19/15 10:35 75-09-21.0 0.97 1
Tetrachloroethene ND ug/L 12/19/15 10:35 127-18-41.0 0.46 1
Trichloroethene ND ug/L 12/19/15 10:35 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 12/19/15 10:35 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)105 %12/19/15 10:35 460-00-470-130 1
1,2-Dichloroethane-d4 (S)97 %12/19/15 10:35 17060-07-070-130 1
Toluene-d8 (S)109 %12/19/15 10:35 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 07:52 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279394
BURKE-JOHN'S R.-ADD. WELLS LFG
Sample:1203-PZ35 Lab ID:92279394005 Collected:12/09/15 14:45 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 2.7J ug/L 12/16/15 12:25 74-82-810.0 0.63 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 12/20/15 22:13 71-43-21.0 0.25 1
1,4-Dichlorobenzene ND ug/L 12/20/15 22:13 106-46-71.0 0.33 1
1,1-Dichloroethane ND ug/L 12/20/15 22:13 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/20/15 22:13 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 12/20/15 22:13 75-09-21.0 0.97 1
Tetrachloroethene ND ug/L 12/20/15 22:13 127-18-41.0 0.46 1
Trichloroethene ND ug/L 12/20/15 22:13 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 12/20/15 22:13 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)102 %12/20/15 22:13 460-00-470-130 1
1,2-Dichloroethane-d4 (S)103 %12/20/15 22:13 17060-07-070-130 1
Toluene-d8 (S)111 %12/20/15 22:13 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 07:52 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279394
BURKE-JOHN'S R.-ADD. WELLS LFG
Sample:1203-PZ36 Lab ID:92279394006 Collected:12/09/15 14:15 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 3780 ug/L 12/16/15 11:19 74-82-810.0 0.63 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene 5.8 ug/L 12/20/15 22:29 71-43-21.0 0.25 1
1,4-Dichlorobenzene 19.6 ug/L 12/20/15 22:29 106-46-71.0 0.33 1
1,1-Dichloroethane 5.9 ug/L 12/20/15 22:29 75-34-35.0 0.32 1
1,2-Dichloroethane 0.66J ug/L 12/20/15 22:29 107-06-21.0 0.24 1
Methylene Chloride 11.2 ug/L 12/20/15 22:29 75-09-21.0 0.97 1
Tetrachloroethene 5.0 ug/L 12/20/15 22:29 127-18-41.0 0.46 1
Trichloroethene 2.9 ug/L 12/20/15 22:29 79-01-61.0 0.47 1
Vinyl chloride 0.80J ug/L 12/20/15 22:29 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)98 %12/20/15 22:29 460-00-470-130 1
1,2-Dichloroethane-d4 (S)96 %12/20/15 22:29 17060-07-070-130 1
Toluene-d8 (S)112 %12/20/15 22:29 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 07:52 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279394
BURKE-JOHN'S R.-ADD. WELLS LFG
Sample:1203-MW38 Lab ID:92279394007 Collected:12/09/15 14:30 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 3120 ug/L 12/16/15 14:50 74-82-810.0 0.63 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 07:52 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279394
BURKE-JOHN'S R.-ADD. WELLS LFG
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/24853
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92279394003, 92279394004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2158782
Associated Lab Samples:92279394003, 92279394004
Matrix:Water
AnalyzedMDL
Methane ug/L 1.5J 10.0 12/15/15 14:310.63
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2158783LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2158784
Methane ug/L 57.260.7 94 85-1159758.8 3 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278963007
2158831SAMPLE DUPLICATE:
Methane ug/L ND 209.1J
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92279394003
2158832SAMPLE DUPLICATE:
Methane ug/L 3.0J 202.5J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 07:52 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279394
BURKE-JOHN'S R.-ADD. WELLS LFG
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/24864
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92279394001, 92279394002, 92279394005, 92279394006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2159892
Associated Lab Samples:92279394001, 92279394002, 92279394005, 92279394006
Matrix:Water
AnalyzedMDL
Methane ug/L 1.4J 10.0 12/16/15 09:170.63
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2159893LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2159894
Methane ug/L 55.860.7 92 85-1159255.8 0 20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 07:52 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279394
BURKE-JOHN'S R.-ADD. WELLS LFG
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/24865
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92279394007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2159899
Associated Lab Samples:92279394007
Matrix:Water
AnalyzedMDL
Methane ug/L 1.4J 10.0 12/16/15 13:280.63
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2159900LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2159901
Methane ug/L 55.860.7 92 85-1159154.9 2 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92279322001
2160006SAMPLE DUPLICATE:
Methane ug/L 89.0 R1222071.7
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
10333128005
2160007SAMPLE DUPLICATE:
Methane ug/L 27.2 12 2030.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 07:52 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279394
BURKE-JOHN'S R.-ADD. WELLS LFG
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34786
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92279394003, 92279394004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1633238
Associated Lab Samples:92279394003, 92279394004
Matrix:Water
AnalyzedMDL
1,1-Dichloroethane ug/L ND 5.0 12/19/15 01:260.32
1,2-Dichloroethane ug/L ND 1.0 12/19/15 01:260.24
1,4-Dichlorobenzene ug/L ND 1.0 12/19/15 01:260.33
Benzene ug/L ND 1.0 12/19/15 01:260.25
Methylene Chloride ug/L ND 1.0 12/19/15 01:260.97
Tetrachloroethene ug/L 1.2 1.0 12/19/15 01:260.46
Trichloroethene ug/L ND 1.0 12/19/15 01:260.47
Vinyl chloride ug/L ND 1.0 12/19/15 01:260.62
1,2-Dichloroethane-d4 (S)%94 70-130 12/19/15 01:26
4-Bromofluorobenzene (S)%101 70-130 12/19/15 01:26
Toluene-d8 (S)%105 70-130 12/19/15 01:26
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1633239LABORATORY CONTROL SAMPLE:
LCSSpike
1,1-Dichloroethane ug/L 47.450 95 73-126
1,2-Dichloroethane ug/L 45.350 91 67-128
1,4-Dichlorobenzene ug/L 48.450 97 78-130
Benzene ug/L 50.150 100 80-125
Methylene Chloride ug/L 55.350 111 64-133
Tetrachloroethene ug/L 48.850 98 78-122
Trichloroethene ug/L 50.650 101 78-122
Vinyl chloride ug/L 49.450 99 58-137
1,2-Dichloroethane-d4 (S)%92 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%97 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 07:52 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279394
BURKE-JOHN'S R.-ADD. WELLS LFG
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34820
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92279394001, 92279394002, 92279394005, 92279394006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1634031
Associated Lab Samples:92279394001, 92279394002, 92279394005, 92279394006
Matrix:Water
AnalyzedMDL
1,1-Dichloroethane ug/L ND 5.0 12/20/15 18:490.32
1,2-Dichloroethane ug/L ND 1.0 12/20/15 18:490.24
1,4-Dichlorobenzene ug/L ND 1.0 12/20/15 18:490.33
Benzene ug/L ND 1.0 12/20/15 18:490.25
Methylene Chloride ug/L ND 1.0 12/20/15 18:490.97
Tetrachloroethene ug/L ND 1.0 12/20/15 18:490.46
Trichloroethene ug/L ND 1.0 12/20/15 18:490.47
Vinyl chloride ug/L ND 1.0 12/20/15 18:490.62
1,2-Dichloroethane-d4 (S)%92 70-130 12/20/15 18:49
4-Bromofluorobenzene (S)%102 70-130 12/20/15 18:49
Toluene-d8 (S)%111 70-130 12/20/15 18:49
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1634032LABORATORY CONTROL SAMPLE:
LCSSpike
1,1-Dichloroethane ug/L 47.950 96 73-126
1,2-Dichloroethane ug/L 45.250 90 67-128
1,4-Dichlorobenzene ug/L 49.650 99 78-130
Benzene ug/L 53.550 107 80-125
Methylene Chloride ug/L 58.350 117 64-133
Tetrachloroethene ug/L 48.950 98 78-122
Trichloroethene ug/L 52.950 106 78-122
Vinyl chloride ug/L 50.050 100 58-137
1,2-Dichloroethane-d4 (S)%102 70-130
4-Bromofluorobenzene (S)%105 70-130
Toluene-d8 (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 07:52 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 21
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92279394
BURKE-JOHN'S R.-ADD. WELLS LFG
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - MinneapolisPASI-M
ANALYTE QUALIFIERS
Common Laboratory Contaminant.C9
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 07:52 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 21
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92279394
BURKE-JOHN'S R.-ADD. WELLS LFG
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92279394001 AIR/248641203-MW15S RSK 175
92279394002 AIR/248641203-PZ12 RSK 175
92279394003 AIR/248531203-PZ30S RSK 175
92279394004 AIR/248531203-PZ31 RSK 175
92279394005 AIR/248641203-PZ35 RSK 175
92279394006 AIR/248641203-PZ36 RSK 175
92279394007 AIR/248651203-MW38 RSK 175
92279394001 MSV/348201203-MW15S EPA 8260
92279394002 MSV/348201203-PZ12 EPA 8260
92279394003 MSV/347861203-PZ30S EPA 8260
92279394004 MSV/347861203-PZ31 EPA 8260
92279394005 MSV/348201203-PZ35 EPA 8260
92279394006 MSV/348201203-PZ36 EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/29/2015 07:52 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 21
Page 20 of 21
Page 21 of 21
#=CL#
December 22, 2015
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92279300
92279300
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
BURKE-JOHN'S R.-SURFACE WATER
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on December 10, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 38
#=CL#
December 22, 2015
Page 2
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92279300
cc:Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 38
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92279300
BURKE-JOHN'S R.-SURFACE WATER
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 38
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92279300
BURKE-JOHN'S R.-SURFACE WATER
Lab ID Sample ID Matrix Date Collected Date Received
92279300001 1203-SMP5 Water 12/09/15 11:43 12/10/15 10:48
92279300002 1203-SMP6 Water 12/09/15 09:50 12/10/15 10:48
92279300003 1203-SMP7 Water 12/09/15 10:34 12/10/15 10:48
92279300004 1203-MW11 Water 12/08/15 12:05 12/10/15 10:48
92279300005 1203-MW12 Water 12/08/15 12:51 12/10/15 10:48
92279300006 1203-MW16S Water 12/08/15 13:30 12/10/15 10:48
92279300007 1203-MW21 Water 12/08/15 11:20 12/10/15 10:48
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 38
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92279300
BURKE-JOHN'S R.-SURFACE WATER
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92279300001 1203-SMP5 EPA 8081 3 PASI-CSWB
EPA 6010 16 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8260 51 PASI-CGAW
SM 4500-CN-E 1 PASI-AAES2
92279300002 1203-SMP6 EPA 8081 3 PASI-CSWB
EPA 6010 16 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8260 51 PASI-CGAW
SM 4500-CN-E 1 PASI-AAES2
92279300003 1203-SMP7 EPA 8081 3 PASI-CSWB
EPA 6010 16 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8260 51 PASI-CGAW
SM 4500-CN-E 1 PASI-AAES2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 38
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92279300
BURKE-JOHN'S R.-SURFACE WATER
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92279300001 1203-SMP5
Barium 26.1J ug/L 12/17/15 01:08100EPA 6010
92279300002 1203-SMP6
Barium 23.4J ug/L 12/17/15 01:11100EPA 6010
92279300003 1203-SMP7
Barium 27.8J ug/L 12/17/15 01:24100EPA 6010
Vanadium 3.9J ug/L 12/17/15 01:2425.0EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279300
BURKE-JOHN'S R.-SURFACE WATER
Sample:1203-SMP5 Lab ID:92279300001 Collected:12/09/15 11:43 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
alpha-BHC ND ug/L 12/16/15 21:05 319-84-612/14/15 15:000.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)79 %12/16/15 21:05 877-09-812/14/15 15:0020-130 1
Decachlorobiphenyl (S)74 %12/16/15 21:05 2051-24-312/14/15 15:0020-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/17/15 01:08 7440-36-012/12/15 00:006.0 3.8 1
Arsenic ND ug/L 12/17/15 01:08 7440-38-212/12/15 00:0010.0 2.5 1
Barium 26.1J ug/L 12/17/15 01:08 7440-39-312/12/15 00:001002.5 1
Beryllium ND ug/L 12/17/15 01:08 7440-41-712/12/15 00:001.0 0.50 1
Cadmium ND ug/L 12/17/15 01:08 7440-43-912/12/15 00:001.0 0.50 1
Chromium ND ug/L 12/17/15 01:08 7440-47-312/12/15 00:0010.0 2.5 1
Cobalt ND ug/L 12/17/15 01:08 7440-48-412/12/15 00:0010.0 2.5 1
Copper ND ug/L 12/17/15 01:08 7440-50-812/12/15 00:0010.0 2.5 1
Lead ND ug/L 12/17/15 01:08 7439-92-112/12/15 00:0010.0 2.5 1
Nickel ND ug/L 12/17/15 01:08 7440-02-012/12/15 00:0050.0 2.5 1
Selenium ND ug/L 12/17/15 01:08 7782-49-212/12/15 00:0010.0 5.0 1
Silver ND ug/L 12/17/15 01:08 7440-22-412/12/15 00:0010.0 2.5 1
Thallium ND ug/L 12/17/15 01:08 7440-28-012/12/15 00:005.5 5.0 1
Tin ND ug/L 12/17/15 01:08 7440-31-512/12/15 00:001002.5 1
Vanadium ND ug/L 12/17/15 01:08 7440-62-212/12/15 00:0025.0 2.5 1
Zinc ND ug/L 12/17/15 01:08 7440-66-612/12/15 00:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/17/15 18:20 7439-97-612/17/15 14:050.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/19/15 18:12 67-64-110010.0 1
Acrylonitrile ND ug/L 12/19/15 18:12 107-13-12001.9 1
Benzene ND ug/L 12/19/15 18:12 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/19/15 18:12 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/19/15 18:12 75-27-41.0 0.18 1
Bromoform ND ug/L 12/19/15 18:12 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/19/15 18:12 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/19/15 18:12 78-93-31000.96 1
Carbon disulfide ND ug/L 12/19/15 18:12 75-15-01001.2 1
Carbon tetrachloride ND ug/L 12/19/15 18:12 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/19/15 18:12 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/19/15 18:12 75-00-310.0 0.54 1
Chloroform ND ug/L 12/19/15 18:12 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/19/15 18:12 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/19/15 18:12 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/19/15 18:12 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/19/15 18:12 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/19/15 18:12 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/19/15 18:12 95-50-15.0 0.30 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 04:53 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279300
BURKE-JOHN'S R.-SURFACE WATER
Sample:1203-SMP5 Lab ID:92279300001 Collected:12/09/15 11:43 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,4-Dichlorobenzene ND ug/L 12/19/15 18:12 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/19/15 18:12 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 12/19/15 18:12 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 12/19/15 18:12 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/19/15 18:12 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/19/15 18:12 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/19/15 18:12 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/19/15 18:12 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/19/15 18:12 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/19/15 18:12 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/19/15 18:12 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/19/15 18:12 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/19/15 18:12 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/19/15 18:12 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 12/19/15 18:12 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/19/15 18:12 108-10-11000.33 1
Styrene ND ug/L 12/19/15 18:12 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/19/15 18:12 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/19/15 18:12 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/19/15 18:12 127-18-41.0 0.46 1
Toluene ND ug/L 12/19/15 18:12 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/19/15 18:12 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/19/15 18:12 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/19/15 18:12 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/19/15 18:12 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/19/15 18:12 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/19/15 18:12 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/19/15 18:12 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/19/15 18:12 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)104 %12/19/15 18:12 460-00-470-130 1
1,2-Dichloroethane-d4 (S)104 %12/19/15 18:12 17060-07-070-130 1
Toluene-d8 (S)115 %12/19/15 18:12 2037-26-570-130 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND mg/L 12/16/15 11:25 57-12-50.010 0.0040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 04:53 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279300
BURKE-JOHN'S R.-SURFACE WATER
Sample:1203-SMP6 Lab ID:92279300002 Collected:12/09/15 09:50 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
alpha-BHC ND ug/L 12/16/15 21:23 319-84-612/14/15 15:000.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)70 %12/16/15 21:23 877-09-812/14/15 15:0020-130 1
Decachlorobiphenyl (S)48 %12/16/15 21:23 2051-24-312/14/15 15:0020-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/17/15 01:11 7440-36-012/12/15 00:006.0 3.8 1
Arsenic ND ug/L 12/17/15 01:11 7440-38-212/12/15 00:0010.0 2.5 1
Barium 23.4J ug/L 12/17/15 01:11 7440-39-312/12/15 00:001002.5 1
Beryllium ND ug/L 12/17/15 01:11 7440-41-712/12/15 00:001.0 0.50 1
Cadmium ND ug/L 12/17/15 01:11 7440-43-912/12/15 00:001.0 0.50 1
Chromium ND ug/L 12/17/15 01:11 7440-47-312/12/15 00:0010.0 2.5 1
Cobalt ND ug/L 12/17/15 01:11 7440-48-412/12/15 00:0010.0 2.5 1
Copper ND ug/L 12/17/15 01:11 7440-50-812/12/15 00:0010.0 2.5 1
Lead ND ug/L 12/17/15 01:11 7439-92-112/12/15 00:0010.0 2.5 1
Nickel ND ug/L 12/17/15 01:11 7440-02-012/12/15 00:0050.0 2.5 1
Selenium ND ug/L 12/17/15 01:11 7782-49-212/12/15 00:0010.0 5.0 1
Silver ND ug/L 12/17/15 01:11 7440-22-412/12/15 00:0010.0 2.5 1
Thallium ND ug/L 12/17/15 01:11 7440-28-012/12/15 00:005.5 5.0 1
Tin ND ug/L 12/17/15 01:11 7440-31-512/12/15 00:001002.5 1
Vanadium ND ug/L 12/17/15 01:11 7440-62-212/12/15 00:0025.0 2.5 1
Zinc ND ug/L 12/17/15 01:11 7440-66-612/12/15 00:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/17/15 18:22 7439-97-612/17/15 14:050.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/19/15 18:29 67-64-110010.0 1
Acrylonitrile ND ug/L 12/19/15 18:29 107-13-12001.9 1
Benzene ND ug/L 12/19/15 18:29 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/19/15 18:29 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/19/15 18:29 75-27-41.0 0.18 1
Bromoform ND ug/L 12/19/15 18:29 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/19/15 18:29 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/19/15 18:29 78-93-31000.96 1
Carbon disulfide ND ug/L 12/19/15 18:29 75-15-01001.2 1
Carbon tetrachloride ND ug/L 12/19/15 18:29 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/19/15 18:29 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/19/15 18:29 75-00-310.0 0.54 1
Chloroform ND ug/L 12/19/15 18:29 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/19/15 18:29 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/19/15 18:29 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/19/15 18:29 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/19/15 18:29 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/19/15 18:29 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/19/15 18:29 95-50-15.0 0.30 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 04:53 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279300
BURKE-JOHN'S R.-SURFACE WATER
Sample:1203-SMP6 Lab ID:92279300002 Collected:12/09/15 09:50 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,4-Dichlorobenzene ND ug/L 12/19/15 18:29 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/19/15 18:29 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 12/19/15 18:29 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 12/19/15 18:29 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/19/15 18:29 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/19/15 18:29 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/19/15 18:29 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/19/15 18:29 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/19/15 18:29 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/19/15 18:29 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/19/15 18:29 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/19/15 18:29 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/19/15 18:29 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/19/15 18:29 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 12/19/15 18:29 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/19/15 18:29 108-10-11000.33 1
Styrene ND ug/L 12/19/15 18:29 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/19/15 18:29 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/19/15 18:29 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/19/15 18:29 127-18-41.0 0.46 1
Toluene ND ug/L 12/19/15 18:29 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/19/15 18:29 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/19/15 18:29 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/19/15 18:29 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/19/15 18:29 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/19/15 18:29 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/19/15 18:29 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/19/15 18:29 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/19/15 18:29 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)104 %12/19/15 18:29 460-00-470-130 1
1,2-Dichloroethane-d4 (S)95 %12/19/15 18:29 17060-07-070-130 1
Toluene-d8 (S)111 %12/19/15 18:29 2037-26-570-130 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND mg/L 12/16/15 11:26 57-12-50.010 0.0040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 04:53 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279300
BURKE-JOHN'S R.-SURFACE WATER
Sample:1203-SMP7 Lab ID:92279300003 Collected:12/09/15 10:34 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
alpha-BHC ND ug/L 12/16/15 21:41 319-84-612/14/15 15:000.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)82 %12/16/15 21:41 877-09-812/14/15 15:0020-130 1
Decachlorobiphenyl (S)40 %12/16/15 21:41 2051-24-312/14/15 15:0020-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/17/15 01:24 7440-36-012/12/15 00:006.0 3.8 1
Arsenic ND ug/L 12/17/15 01:24 7440-38-212/12/15 00:0010.0 2.5 1
Barium 27.8J ug/L 12/17/15 01:24 7440-39-312/12/15 00:001002.5 1
Beryllium ND ug/L 12/17/15 01:24 7440-41-712/12/15 00:001.0 0.50 1
Cadmium ND ug/L 12/17/15 01:24 7440-43-912/12/15 00:001.0 0.50 1
Chromium ND ug/L 12/17/15 01:24 7440-47-312/12/15 00:0010.0 2.5 1
Cobalt ND ug/L 12/17/15 01:24 7440-48-412/12/15 00:0010.0 2.5 1
Copper ND ug/L 12/17/15 01:24 7440-50-812/12/15 00:0010.0 2.5 1
Lead ND ug/L 12/17/15 01:24 7439-92-112/12/15 00:0010.0 2.5 1
Nickel ND ug/L 12/17/15 01:24 7440-02-012/12/15 00:0050.0 2.5 1
Selenium ND ug/L 12/17/15 01:24 7782-49-212/12/15 00:0010.0 5.0 1
Silver ND ug/L 12/17/15 01:24 7440-22-412/12/15 00:0010.0 2.5 1
Thallium ND ug/L 12/17/15 01:24 7440-28-012/12/15 00:005.5 5.0 1
Tin ND ug/L 12/17/15 01:24 7440-31-512/12/15 00:001002.5 1
Vanadium 3.9J ug/L 12/17/15 01:24 7440-62-212/12/15 00:0025.0 2.5 1
Zinc ND ug/L 12/17/15 01:24 7440-66-612/12/15 00:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/17/15 18:25 7439-97-612/17/15 14:050.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/19/15 19:03 67-64-110010.0 1
Acrylonitrile ND ug/L 12/19/15 19:03 107-13-12001.9 1
Benzene ND ug/L 12/19/15 19:03 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/19/15 19:03 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/19/15 19:03 75-27-41.0 0.18 1
Bromoform ND ug/L 12/19/15 19:03 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/19/15 19:03 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/19/15 19:03 78-93-31000.96 1
Carbon disulfide ND ug/L 12/19/15 19:03 75-15-01001.2 1
Carbon tetrachloride ND ug/L 12/19/15 19:03 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/19/15 19:03 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/19/15 19:03 75-00-310.0 0.54 1
Chloroform ND ug/L 12/19/15 19:03 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/19/15 19:03 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/19/15 19:03 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/19/15 19:03 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/19/15 19:03 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/19/15 19:03 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/19/15 19:03 95-50-15.0 0.30 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 04:53 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279300
BURKE-JOHN'S R.-SURFACE WATER
Sample:1203-SMP7 Lab ID:92279300003 Collected:12/09/15 10:34 Received:12/10/15 10:48 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,4-Dichlorobenzene ND ug/L 12/19/15 19:03 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/19/15 19:03 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 12/19/15 19:03 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 12/19/15 19:03 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/19/15 19:03 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/19/15 19:03 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/19/15 19:03 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/19/15 19:03 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/19/15 19:03 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/19/15 19:03 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/19/15 19:03 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/19/15 19:03 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/19/15 19:03 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/19/15 19:03 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 12/19/15 19:03 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/19/15 19:03 108-10-11000.33 1
Styrene ND ug/L 12/19/15 19:03 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/19/15 19:03 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/19/15 19:03 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/19/15 19:03 127-18-41.0 0.46 1
Toluene ND ug/L 12/19/15 19:03 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/19/15 19:03 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/19/15 19:03 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/19/15 19:03 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/19/15 19:03 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/19/15 19:03 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/19/15 19:03 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/19/15 19:03 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/19/15 19:03 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %12/19/15 19:03 460-00-470-130 1
1,2-Dichloroethane-d4 (S)97 %12/19/15 19:03 17060-07-070-130 1
Toluene-d8 (S)108 %12/19/15 19:03 2037-26-570-130 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND mg/L 12/16/15 11:29 57-12-50.010 0.0040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 04:53 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279300
BURKE-JOHN'S R.-SURFACE WATER
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/8788
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples:92279300001, 92279300002, 92279300003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1629746
Associated Lab Samples:92279300001, 92279300002, 92279300003
Matrix:Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/17/15 17:420.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1629747LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.42.5 96 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1629748MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279275008
1629749
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 96 75-12599 3 252.5ND 2.4 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 04:53 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279300
BURKE-JOHN'S R.-SURFACE WATER
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20260
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92279300001, 92279300002, 92279300003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1627221
Associated Lab Samples:92279300001, 92279300002, 92279300003
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 12/17/15 00:323.8
Arsenic ug/L ND 10.0 12/17/15 00:322.5
Barium ug/L ND 100 12/17/15 00:322.5
Beryllium ug/L ND 1.0 12/17/15 00:320.50
Cadmium ug/L ND 1.0 12/17/15 00:320.50
Chromium ug/L ND 10.0 12/17/15 00:322.5
Cobalt ug/L ND 10.0 12/17/15 00:322.5
Copper ug/L ND 10.0 12/17/15 00:322.5
Lead ug/L ND 10.0 12/17/15 00:322.5
Nickel ug/L ND 50.0 12/17/15 00:322.5
Selenium ug/L ND 10.0 12/17/15 00:325.0
Silver ug/L ND 10.0 12/17/15 00:322.5
Thallium ug/L ND 5.5 12/17/15 00:325.0
Tin ug/L ND 100 12/17/15 00:322.5
Vanadium ug/L ND 25.0 12/17/15 00:322.5
Zinc ug/L ND 10.0 12/17/15 00:325.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1627222LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 547500 109 80-120
Arsenic ug/L 489500 98 80-120
Barium ug/L 479500 96 80-120
Beryllium ug/L 472500 94 80-120
Cadmium ug/L 497500 99 80-120
Chromium ug/L 464500 93 80-120
Cobalt ug/L 507500 101 80-120
Copper ug/L 490500 98 80-120
Lead ug/L 500500 100 80-120
Nickel ug/L 500500 100 80-120
Selenium ug/L 506500 101 80-120
Silver ug/L 254250 102 80-120
Thallium ug/L 476500 95 80-120
Tin ug/L 550500 110 80-120
Vanadium ug/L 520500 104 80-120
Zinc ug/L 515500 103 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 04:53 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279300
BURKE-JOHN'S R.-SURFACE WATER
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1627223MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279296001
1627224
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 79 75-12575 4 25500ND395379
Arsenic ug/L 500 92 75-12591 2 25500ND464454
Barium ug/L 500 94 75-12595 0 25500151621624
Beryllium ug/L 500 92 75-12592 0 255002.8 462 461
Cadmium ug/L 500 95 75-12593 2 25500ND475467
Chromium ug/L 500 91 75-12590 1 255006.9 464 458
Cobalt ug/L 500 96 75-12595 2 2550012.0 493 484
Copper ug/L 500 96 75-12595 1 2550014.9 496 492
Lead ug/L 500 94 75-12592 2 255008.6 476 469
Nickel ug/L 500 95 75-12594 1 2550015.6 491 484
Selenium ug/L 500 94 75-12593 2 25500ND472465
Silver ug/L 250 98 75-12597 1 25250ND245242
Thallium ug/L 500 88 75-12587 1 255005.1J 443 440
Tin ug/L 500 103 75-125100 2 25500ND515503
Vanadium ug/L 500 103 75-125102 1 2550016.8 532 525
Zinc ug/L 500 101 75-125101 1 2550035.2 542 538
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 04:53 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279300
BURKE-JOHN'S R.-SURFACE WATER
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34799
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92279300001, 92279300002, 92279300003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1633901
Associated Lab Samples:92279300001, 92279300002, 92279300003
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 12/19/15 13:250.33
1,1,1-Trichloroethane ug/L ND 1.0 12/19/15 13:250.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 12/19/15 13:250.40
1,1,2-Trichloroethane ug/L ND 1.0 12/19/15 13:250.29
1,1-Dichloroethane ug/L ND 5.0 12/19/15 13:250.32
1,1-Dichloroethene ug/L ND 5.0 12/19/15 13:250.56
1,2,3-Trichloropropane ug/L ND 1.0 12/19/15 13:250.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 12/19/15 13:252.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/19/15 13:250.27
1,2-Dichlorobenzene ug/L ND 5.0 12/19/15 13:250.30
1,2-Dichloroethane ug/L ND 1.0 12/19/15 13:250.24
1,2-Dichloropropane ug/L ND 1.0 12/19/15 13:250.27
1,4-Dichlorobenzene ug/L ND 1.0 12/19/15 13:250.33
2-Butanone (MEK)ug/L ND 100 12/19/15 13:250.96
2-Hexanone ug/L ND 50.0 12/19/15 13:250.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 12/19/15 13:250.33
Acetone ug/L ND 100 12/19/15 13:2510.0
Acrylonitrile ug/L ND 200 12/19/15 13:251.9
Benzene ug/L ND 1.0 12/19/15 13:250.25
Bromochloromethane ug/L ND 3.0 12/19/15 13:250.17
Bromodichloromethane ug/L ND 1.0 12/19/15 13:250.18
Bromoform ug/L ND 3.0 12/19/15 13:250.26
Bromomethane ug/L ND 10.0 12/19/15 13:250.29
Carbon disulfide ug/L ND 100 12/19/15 13:251.2
Carbon tetrachloride ug/L ND 1.0 12/19/15 13:250.25
Chlorobenzene ug/L ND 3.0 12/19/15 13:250.23
Chloroethane ug/L ND 10.0 12/19/15 13:250.54
Chloroform ug/L ND 5.0 12/19/15 13:250.14
Chloromethane ug/L ND 1.0 12/19/15 13:250.11
cis-1,2-Dichloroethene ug/L ND 5.0 12/19/15 13:250.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/19/15 13:250.13
Dibromochloromethane ug/L ND 3.0 12/19/15 13:250.21
Dibromomethane ug/L ND 10.0 12/19/15 13:250.21
Dichlorodifluoromethane ug/L ND 5.0 12/19/15 13:250.21
Ethylbenzene ug/L ND 1.0 12/19/15 13:250.30
Iodomethane ug/L ND 10.0 12/19/15 13:250.32
Methylene Chloride ug/L ND 1.0 12/19/15 13:250.97
Styrene ug/L ND 1.0 12/19/15 13:250.26
Tetrachloroethene ug/L ND 1.0 12/19/15 13:250.46
Toluene ug/L ND 1.0 12/19/15 13:250.26
trans-1,2-Dichloroethene ug/L ND 5.0 12/19/15 13:250.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 04:53 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279300
BURKE-JOHN'S R.-SURFACE WATER
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1633901
Associated Lab Samples:92279300001, 92279300002, 92279300003
Matrix:Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 12/19/15 13:250.26
trans-1,4-Dichloro-2-butene ug/L ND 100 12/19/15 13:251.0
Trichloroethene ug/L ND 1.0 12/19/15 13:250.47
Trichlorofluoromethane ug/L ND 1.0 12/19/15 13:250.20
Vinyl acetate ug/L ND 50.0 12/19/15 13:250.35
Vinyl chloride ug/L ND 1.0 12/19/15 13:250.62
Xylene (Total)ug/L ND 5.0 12/19/15 13:250.66
1,2-Dichloroethane-d4 (S)%102 70-130 12/19/15 13:25
4-Bromofluorobenzene (S)%102 70-130 12/19/15 13:25
Toluene-d8 (S)%110 70-130 12/19/15 13:25
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1633902LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 52.650 105 80-125
1,1,1-Trichloroethane ug/L 55.250 110 71-129
1,1,2,2-Tetrachloroethane ug/L 52.850 106 79-124
1,1,2-Trichloroethane ug/L 53.550 107 85-125
1,1-Dichloroethane ug/L 49.350 99 73-126
1,1-Dichloroethene ug/L 54.250 108 66-135
1,2,3-Trichloropropane ug/L 50.950 102 75-130
1,2-Dibromo-3-chloropropane ug/L 50.950 102 71-133
1,2-Dibromoethane (EDB)ug/L 55.650 111 83-124
1,2-Dichlorobenzene ug/L 51.650 103 80-133
1,2-Dichloroethane ug/L 50.150 100 67-128
1,2-Dichloropropane ug/L 49.050 98 75-132
1,4-Dichlorobenzene ug/L 53.050 106 78-130
2-Butanone (MEK)ug/L 109100 109 61-144
2-Hexanone ug/L 104100 104 68-143
4-Methyl-2-pentanone (MIBK)ug/L 99.9J100 100 72-135
Acetone ug/L 107100 107 48-146
Acrylonitrile ug/L 263250 105 40-160
Benzene ug/L 52.150 104 80-125
Bromochloromethane ug/L 59.350 119 71-125
Bromodichloromethane ug/L 54.550 109 78-124
Bromoform ug/L 44.150 88 71-128
Bromomethane ug/L 45.450 91 40-160
Carbon disulfide ug/L 55.0J50 110 50-160
Carbon tetrachloride ug/L 53.350 107 69-131
Chlorobenzene ug/L 53.950 108 81-122
Chloroethane ug/L 48.350 97 39-148
Chloroform ug/L 55.350 111 73-127
Chloromethane ug/L 55.950 112 44-146
cis-1,2-Dichloroethene ug/L 51.550 103 74-124
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 04:53 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279300
BURKE-JOHN'S R.-SURFACE WATER
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1633902LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,3-Dichloropropene ug/L 56.550 113 72-132
Dibromochloromethane ug/L 54.550 109 78-125
Dibromomethane ug/L 53.250 106 82-120
Dichlorodifluoromethane ug/L 46.650 93 34-157
Ethylbenzene ug/L 52.950 106 79-121
Iodomethane ug/L 88.7100 89 39-154
Methylene Chloride ug/L 59.250 118 64-133
Styrene ug/L 53.250 106 84-126
Tetrachloroethene ug/L 53.650 107 78-122
Toluene ug/L 49.950 100 80-121
trans-1,2-Dichloroethene ug/L 51.550 103 71-127
trans-1,3-Dichloropropene ug/L 52.150 104 69-141
trans-1,4-Dichloro-2-butene ug/L 54.8J50 110 40-160
Trichloroethene ug/L 55.350 111 78-122
Trichlorofluoromethane ug/L 50.850 102 53-137
Vinyl acetate ug/L 104100 104 40-160
Vinyl chloride ug/L 55.350 111 58-137
Xylene (Total)ug/L 158150 106 81-126
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%104 70-130
Toluene-d8 (S)%96 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1633904MATRIX SPIKE SAMPLE:
MSSpike
Result
92279300003
1,1,1,2-Tetrachloroethane ug/L 15.420 77 70-130ND
1,1,1-Trichloroethane ug/L 19.820 99 70-130ND
1,1,2,2-Tetrachloroethane ug/L 16.820 84 70-130ND
1,1,2-Trichloroethane ug/L 16.820 84 70-130ND
1,1-Dichloroethane ug/L 19.420 97 70-130ND
1,1-Dichloroethene ug/L 18.920 94 70-166ND
1,2,3-Trichloropropane ug/L 17.620 88 70-130ND
1,2-Dibromo-3-chloropropane ug/L 15.820 79 70-130ND
1,2-Dibromoethane (EDB)ug/L 16.520 82 70-130ND
1,2-Dichlorobenzene ug/L 17.620 88 70-130ND
1,2-Dichloroethane ug/L 17.420 87 70-130ND
1,2-Dichloropropane ug/L 17.620 88 70-130ND
1,4-Dichlorobenzene ug/L 17.220 86 70-130ND
2-Butanone (MEK)ug/L 36.4J40 91 70-130ND
2-Hexanone ug/L 33.6J40 84 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 36.3J40 91 70-130ND
Acetone ug/L 39.6J40 99 70-130ND
Acrylonitrile ug/L 95.0J100 95 70-130ND
Benzene ug/L 18.620 93 70-148ND
Bromochloromethane ug/L 22.420 112 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 04:53 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279300
BURKE-JOHN'S R.-SURFACE WATER
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1633904MATRIX SPIKE SAMPLE:
MSSpike
Result
92279300003
Bromodichloromethane ug/L 17.520 87 70-130ND
Bromoform ug/L 15.420 77 70-130ND
Bromomethane ug/L 16.920 84 70-130ND
Carbon disulfide ug/L 19.8J20 99 70-130ND
Carbon tetrachloride ug/L 18.320 91 70-130ND
Chlorobenzene ug/L 18.120 90 70-146ND
Chloroethane ug/L 16.220 81 70-130ND
Chloroform ug/L 19.820 99 70-130ND
Chloromethane ug/L 23.020 115 70-130ND
cis-1,2-Dichloroethene ug/L 18.720 94 70-130ND
cis-1,3-Dichloropropene ug/L 17.420 87 70-130ND
Dibromochloromethane ug/L 15.320 77 70-130ND
Dibromomethane ug/L 19.720 98 70-130ND
Dichlorodifluoromethane ug/L 17.520 88 70-130ND
Ethylbenzene ug/L 17.520 87 70-130ND
Iodomethane ug/L 28.340 71 70-130ND
Methylene Chloride ug/L 20.820 104 70-130ND
Styrene ug/L 17.220 86 70-130ND
Tetrachloroethene ug/L 16.920 85 70-130ND
Toluene ug/L 19.220 96 70-155ND
trans-1,2-Dichloroethene ug/L 20.020 100 70-130ND
trans-1,3-Dichloropropene ug/L 15.620 78 70-130ND
trans-1,4-Dichloro-2-butene ug/L 16.1J20 81 70-130ND
Trichloroethene ug/L 18.120 91 69-151ND
Trichlorofluoromethane ug/L 17.420 87 70-130ND
Vinyl acetate ug/L 28.9J40 72 70-130ND
Vinyl chloride ug/L 20.320 102 70-130ND
1,2-Dichloroethane-d4 (S)%109 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%107 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92279300002
1633903SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 04:53 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279300
BURKE-JOHN'S R.-SURFACE WATER
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92279300002
1633903SAMPLE DUPLICATE:
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Dichlorodifluoromethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%98 395
4-Bromofluorobenzene (S)%106 1104
Toluene-d8 (S)%109 2111
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 04:53 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279300
BURKE-JOHN'S R.-SURFACE WATER
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/39710
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples:92279300001, 92279300002, 92279300003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1628602
Associated Lab Samples:92279300001, 92279300002, 92279300003
Matrix:Water
AnalyzedMDL
alpha-BHC ug/L ND 0.050 12/16/15 14:330.050
Decachlorobiphenyl (S)%63 20-130 12/16/15 14:33
Tetrachloro-m-xylene (S)%65 20-130 12/16/15 14:33
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1628603LABORATORY CONTROL SAMPLE:
LCSSpike
alpha-BHC ug/L 0.21.25 86 20-150
Decachlorobiphenyl (S)%68 20-130
Tetrachloro-m-xylene (S)%79 20-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1628604MATRIX SPIKE SAMPLE:
MSSpike
Result
92278963013
alpha-BHC ug/L 0.20.25 79 20-150ND
Decachlorobiphenyl (S)%86 20-130
Tetrachloro-m-xylene (S)%75 20-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278963014
1628605SAMPLE DUPLICATE:
alpha-BHC ug/L ND 30ND
Decachlorobiphenyl (S)%58 964
Tetrachloro-m-xylene (S)%65 462
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 04:53 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279300
BURKE-JOHN'S R.-SURFACE WATER
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/25789
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples:92279300001, 92279300002, 92279300003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1628965
Associated Lab Samples:92279300001, 92279300002, 92279300003
Matrix:Water
AnalyzedMDL
Cyanide mg/L ND 0.010 12/16/15 11:200.0040
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1628966LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide mg/L 0.095.1 95 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1628967MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279219001
1628968
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide mg/L .1 109 75-125113 4 10.1ND 0.11 0.12
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1628969MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279489002
1628970
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide mg/L .1 99 75-125106 7 10.1ND 0.10 0.11
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 04:53 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 38
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92279300
BURKE-JOHN'S R.-SURFACE WATER
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 04:53 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 38
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92279300
BURKE-JOHN'S R.-SURFACE WATER
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92279300001 OEXT/39710 GCSV/235391203-SMP5 EPA 3510 EPA 8081
92279300002 OEXT/39710 GCSV/235391203-SMP6 EPA 3510 EPA 8081
92279300003 OEXT/39710 GCSV/235391203-SMP7 EPA 3510 EPA 8081
92279300001 MPRP/20260 ICP/182841203-SMP5 EPA 3010A EPA 6010
92279300002 MPRP/20260 ICP/182841203-SMP6 EPA 3010A EPA 6010
92279300003 MPRP/20260 ICP/182841203-SMP7 EPA 3010A EPA 6010
92279300001 MERP/8788 MERC/84421203-SMP5 EPA 7470 EPA 7470
92279300002 MERP/8788 MERC/84421203-SMP6 EPA 7470 EPA 7470
92279300003 MERP/8788 MERC/84421203-SMP7 EPA 7470 EPA 7470
92279300001 MSV/347991203-SMP5 EPA 8260
92279300002 MSV/347991203-SMP6 EPA 8260
92279300003 MSV/347991203-SMP7 EPA 8260
92279300001 WETA/257891203-SMP5 SM 4500-CN-E
92279300002 WETA/257891203-SMP6 SM 4500-CN-E
92279300003 WETA/257891203-SMP7 SM 4500-CN-E
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 04:53 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 38
Page 25 of 38
Page 26 of 38
Page 27 of 38
Page 28 of 38
Page 29 of 38
Page 30 of 38
Page 31 of 38
Page 32 of 38
Page 33 of 38
Page 34 of 38
Page 35 of 38
Page 36 of 38
Page 37 of 38
Page 38 of 38

Appendix C

Statistical Analyses Worksheets

JOYCE Project:Burke County - John's River Landfill
Project No: 277.1601.12
Date: 08-Dec-15
Analyte:Thallium
Quantitation
Concentration Limit
Sample No. Sample Date Location (µg/L) (µg/L)
1 5/1/1998 MW-9 ND 1 0.042
2 11/1/1998 MW-9 ND 1 2.0
3 5/11/1999 MW-9 2.0 2 3.0
4 10/18/1999 MW-9 ND 10 16.0
5 5/3/2000 MW-9 ND 10 ND
6 11/7/2000 MW-9 ND 10 ND
7 5/31/2001 MW-9 ND 10 ND
8 11/7/2001 MW-9 ND 10 ND
9 5/22/2002 MW-9 ND 10 ND
10 11/14/2002 MW-9 ND 10 ND
11 5/14/2003 MW-9 ND 10 ND
12 11/20/2003 MW-9 ND 10 ND
13 5/6/2004 MW-9 ND 10 ND
14 11/10/2004 MW-9 ND 10 ND
15 5/5/2005 MW-9 16.0 10 ND
16 5/11/1999 MW-17 3.0 2 ND
17 10/18/1999 MW-17 ND 10 ND
18 5/3/2000 MW-17 ND 10 ND
19 11/7/2000 MW-17 ND 10 ND
20 5/31/2001 MW-17 ND 10 ND
21 11/7/2001 MW-17 ND 10 ND
22 5/22/2002 MW-17 ND 10 ND
23 11/14/2002 MW-17 ND 10 ND
24 5/14/2003 MW-17 ND 10 ND
25 11/20/2003 MW-17 ND 10 ND
26 5/6/2004 MW-17 ND 10 ND
27 11/10/2004 MW-17 ND 10 ND
28 5/5/2005 MW-17 ND 10 ND
29 11/3/2005 MW-17 ND 10 ND
30 5/25/2006 MW-17 ND 10 ND
31 11/2/2006 MW-17 ND 10 ND
32 5/30/2007 MW-17 ND 5.5 ND
33 11/29/2007 MW-17 0.042 5.5 ND
34 5/29/2008 MW-17 ND 5.5 ND
35 11/6/2008 MW-17 ND 5.5 ND
36 6/3/2009 MW-17 ND 5.5 ND
37 11/18/2009 MW-17 ND 5.5 ND
38 6/16/2010 MW-17 ND 5.5 ND
39 6/1/2011 MW-17 ND 5.5 ND
40 12/1/2010 MW-20 ND 5.5 ND
41 6/1/2011 MW-20 ND 5.5 ND
42 12/20/2011 MW-20 ND 5.5 ND
43 5/30/2012 MW-20 ND 5.5 ND
44 12/5/2012 MW-20 ND 5.5 ND
45 6/12/2013 MW-20 ND 5.5 ND
46 10/28/2013 MW-20 ND 5.5 ND
47 5/6/2014 MW-20 ND 5.5 ND
48 10/23/2014 MW-21 ND 5.5 ND
49 5/20/2015 MW-21 ND 5.5 ND
50 12/8/2015 MW-21 ND 5.5 ND
Number of Data: 50
Number of Truncated Data: 46
Percentage of Truncated Data: 92%
Upper Poisson Prediction Limit: 37
Note:
All concentrations in micrograms per liter (µg/L).
ND = Not detected (truncated).
Sorted
Concentration (µg/L)

Appendix D

Historical Detected Groundwater Constituents

APPENDIX D:
HISTORICAL DETECTED GROUNDWATER CONSTITUENTS
Analyte Sample Collect Date EPA Method DL RL MW-21 MW-20 MW-22S MW-38 Blanks
Inorganic Compounds
Alkalinity, Total as CaCO3 10-Apr-14 SM 2320B 1,000 5,000 1,560 J --- 5,510 208,000 ND
NC 2L = NE (01/01/10) 6-May-14 SM 2320B 1,000 5,000 1,170 J --- 4,060 J 209,000 ND
20-Jun-14 SM 2320B 1,000 5,000 2,020 J --- 4,060 J 262,000 ND
17-Jul-14 SM 2320B 1,000 5,000 1,990 J --- 3,960 J 197,000 ND
23-Oct-14 SM 2320B 1,000 5,000 1,360 J 7,980 4,340 J 232,000 ND
21-May-15 SM 2320B 1,000 5,000 ND 6,540 3,630 J 206,000 ---
8-Dec-15 SM 2320B 1,000 5,000 1,030 J 8,280 6,670 234,000 ---
Arsenic 8-Dec-15 EPA 6010 2.5 10 ND ND 12.7 4.9 J ND
NC 2L = 10 µg/L (01/01/10) 4-Feb-16 EPA 6010 2.5 10 ------ 5.8 J ---ND
Barium 10-Apr-14 EPA 6010 5 100 14.4 J --- 86.9 J 127 ND
NC 2L = 700 µg/L (01/01/10)6-May-14 EPA 6010 5 100 11.7 J --- 75.7 J 110 ND
20-Jun-14 EPA 6010 5 100 14.2 J --- 52.2 J 85.2 J ND
17-Jul-14 EPA 6010 5 100 14.4 J --- 52.4 J 58.1 J ND
23-Oct-14 EPA 6010 5.0 100 20.3 J 70.0 J 20.8 J 97.8 J ND
21-May-15 EPA 6010 5.0 100 17.9 J 116.0 28.3 J 91 J ND
8-Dec-15 EPA 6010 2.5 100 17.6 J 67.3 J 1110 83.5 J ND
Verification Sample >4-Feb-16 EPA 6010 2.5 100 --- --- 264 --- ND
Beryllium 8-Dec-15 EPA 6010 0.5 1 ND ND 3.4 ND ND
GWPS = 4 µg/L (01/01/10). Verification Sample >4-Feb-16 EPA 6010 0.5 1 --- --- 0.83 J --- ND
Chloride 10-Apr-14 SM 4500-Cl-E 1,000 1,000 ND --- ND 4,980 ND
NC 2L = 250,000 µg/L (01/01/10) 6-May-14 SM 4500-Cl-E 1,000 1,000 ND --- 1,140 4,930 ND
20-Jun-14 SM 4500-Cl-E 1,000 1,000 ND --- 1,320 4,410 ND
17-Jul-14 SM 4500-Cl-E 500 1,000 570 J --- 1,090 4,310 ND
23-Oct-14 SM 4500-Cl-E 500 1,000 ND 1,050 727 J 4,650 ND
21-May-15 SM 4500-Cl-E 500 1,000 750 J 1,550 1,380 4,980 ---
8-Dec-15 SM 4500-Cl-E 500 1,000 859 J 1,840 4,200 4,390 ---
Chromium 10-Apr-14 EPA 6010 5.0 10.0 ND --- ND ND ND
NC 2L = 10 µg/L (01/01/10)6-May-14 EPA 6010 5.0 10.0 ND --- ND ND ND
20-Jun-14 EPA 6010 5.0 10.0 ND --- ND ND ND
17-Jul-14 EPA 6010 5.0 10.0 ND --- ND ND ND
23-Oct-14 EPA 6010 5.0 10.0 ND 7.0 J ND ND ND
21-May-15 EPA 6010 5.0 10.0 ND 7.4 J ND ND ND
8-Dec-15 EPA 6010 2.5 10.0 ND 4.7 J 16.8 ND ND
Verification Sample >4-Feb-16 EPA 6010 2.5 10.0 --- ---6.6 J ---ND
Cobalt 10-Apr-14 EPA 6010 5 10 ND --- ND 80.8 ND
GWPS = 1 µg/L (10/1/10) 6-May-14 EPA 6010 5 10 ND --- ND 58.0 ND
20-Jun-14 EPA 6010 5 10 ND --- ND 12.5 ND
17-Jul-14 EPA 6010 5 10 ND --- ND 18.9 ND
23-Oct-14 EPA 6010 5.0 10.0 ND ND ND 21.5 ND
21-May-15 EPA 6010 5.0 10.0 ND 2.9 J ND 10.5 ND
8-Dec-15 EPA 6010 2.5 10.0 ND ND 11.2 4.1 J ND
Verification Sample >4-Feb-16 EPA 6010 2.5 10.0 --- ---3.2 J ---ND
Copper 8-Dec-15 EPA 6010 2.5 10.0 ND J 30.0 3.3 J NDNC 2L = 1,000 µg/L (01/01/10). Verifi. Sample
>4-Feb-16 EPA 6010 2.5 10.0 --- ---10.4 ---ND
Iron 10-Apr-14 EPA 6010 50 300 ND ---559 22,800 ND
NC 2L = 300 µg/L (01/01/10) 6-May-14 EPA 6010 50 300 177 J ---3,930 16,300 ND
20-Jun-14 EPA 6010 50 300 200 J ---402 14,400 ND
17-Jul-14 EPA 6010 50 300 381 ---2,280 4,390 ND
23-Oct-14 EPA 6010 50.0 300 2,340 3,990 719 16,700 ND
21-May-15 EPA 6010 50.0 300 350 6,660 295 J 16,100 ND
8-Dec-15 EPA 6010 25.0 300 1,380 3,590 29,700 27,800 ND
Verification Sample >4-Feb-16 EPA 6010 25.0 300 --- ---9,840 ---ND
Lead 8-Dec-15 EPA 6010 2.5 10.0 ND 3.0 J 39.4 3.2 J ND
NC 2L = 15 µg/L (01/01/10) 4-Feb-16 EPA 6010 2.5 10.0 --- ---10.5 ---ND
Manganese 10-Apr-14 EPA 6010 5 50 20.8 J ---132 5,450 ND
NC 2L = 50 µg/L (01/01/10)6-May-14 EPA 6010 5 50 22.5 J ---77.5 4,830 ND
20-Jun-14 EPA 6010 5 50 24.7 J ---52.2 3,790 ND
17-Jul-14 EPA 6010 5 50 27.9 J --- 39.8 J 3,380 ND
23-Oct-14 EPA 6010 5.0 50.0 73.6 77.5 16.6 J 3,930 ND
21-May-15 EPA 6010 5.0 50.0 27.4 J 146 11.7 J 3,060 ND
8-Dec-15 EPA 6010 2.5 50.0 50.0 J 68.5 462 3,220 ND
Verification Sample >4-Feb-16 EPA 6010 2.5 50.0 --- ---124 ---ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 1 of 4
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED GROUNDWATER CONSTITUENTS
Analyte Sample Collect Date EPA Method DL RL MW-21 MW-20 MW-22S MW-38 Blanks
Nickel 10-Apr-14 EPA 6010 5 50 ND --- ND ND ND
NC 2L = 100 µg/L (10/23/07) 6-May-14 EPA 6008 5 50 ND --- ND 10.6 J ND
20-Jun-14 EPA 6009 5 50 ND --- ND ND ND
17-Jul-14 EPA 6010 5 50 ND --- ND 5 J ND
23-Oct-14 EPA 6010 5.0 50.0 ND ND ND 5.1 J ND
21-May-15 EPA 6010 5.0 50.0 ND 4.3 ND 4.3 J ND
8-Dec-15 EPA 6010 2.5 50.0 ND 2.5 J 18.7 J 3.0 J ND
Verification Sample >4-Feb-16 EPA 6010 2.5 50.0 --- ---5.7 J ---ND
Thallium 8-Dec-15 EPA 6010 5.0 5.5 ND ND ND ND J ND
GWPS = 0.28 µg/L 4-Feb-16 EPA 6010 2.5 50.0 --- ---9.1 ---ND
Sulfate 10-Apr-14 EPA 300.0 2,000 250,000 ND --- 2,110 J 3,430 J ND
NC 2L = 250,000 µg/L (01/01/10) 6-May-14 EPA 300.0 2,000 250,000 ND --- 8,740 J ND ND
20-Jun-14 EPA 300.0 2,000 250,000 ND --- ND 10,100 J ND
17-Jul-14 EPA 300.0 1,000 250,000 1,340 J --- 1,560 J 8,720 J ND
23-Oct-14 EPA 300.0 1,000 250,000 ND 1,300 J 1,320 J 3,320 J ND
21-May-15 EPA 300.0 1,000 250,000 ND ND ND 2,650 J ND
8-Dec-15 EPA 300.0 1,000 250,000 ND ND ND 4,640 J ND
Total Dissolved Solids, Dissolved 10-Apr-14 SM 2540C 25,000 25,000 37,000 --- 68,000 302,000 ND
NC 2L = 500,000 µg/L (01/01/10) 6-May-14 SM 2540C 25,000 25,000 ND --- 30,000 257,000 ND
20-Jun-14 SM 2540C 25,000 25,000 ND --- ND 301,000 ND
17-Jul-14 SM 2540C 25,000 25,000 ND --- ND 245,000 ND
23-Oct-14 SM 2540C 25,000 25,000 ND 25,000 ND 265,000 ND
21-May-15 SM 2540C 25,000 25,000 ND 36,000 29,000 268,000 ---
8-Dec-15 SM 2540C 25,000 25,000 ND 31,000 96,000 311,000 ---
Vanadium 10-Apr-14 EPA 6010 5 25 ND --- ND ND ND
GWPS = 0.3 µg/L (10/1/10) 6-May-14 EPA 6010 5 25 ND --- 7.3 J ND ND
20-Jun-14 EPA 6010 5 25 ND --- ND ND ND
17-Jul-14 EPA 6010 5 25 ND --- ND ND ND
23-Oct-14 EPA 6010 5.0 25.0 9.6 J 6.5 J ND ND ND
21-May-15 EPA 6010 5.0 25.0 ND 11.6 ND 4 J ND
8-Dec-15 EPA 6010 2.5 25.0 ND J 6.9 J 44.8 8.5 J ND
Verification Sample >4-Feb-16 EPA 6010 2.5 50.0 --- ---16.0 J ---ND
Zinc 10-Apr-14 EPA 6010 10 10 ND --- 19.6 ND ND
NC 2L = 1,000 µg/L (01/01/10) 6-May-14 EPA 6010 10 10 ND --- 15.5 15.8 ND
20-Jun-14 EPA 6010 10 10 ND --- ND ND 10.9
17-Jul-14 EPA 6010 10 10 ND --- ND 12.5 B 10.5
23-Oct-14 EPA 6010 10.0 10.0 ND 12.8 ND ND ND
21-May-15 EPA 6010 10.0 10.0 26.4 19.7 ND ND ND
8-Dec-15 EPA 6010 5.0 10.0 ND 10.3 127 8.7 J ND
Verification Sample >4-Feb-16 EPA 6010 5.0 10.0 --- ---36.5 ND ND
Organic Compounds
Acetone 10-Apr-14 EPA 8260 10.0 100.0 ND ---ND 10.2 J ND
NC 2L = 6,000 µg/L 6-May-14 EPA 8260 10.0 100.0 ND ---ND ND ND
20-Jun-14 EPA 8260 10.0 100.0 ND ---ND ND ND
17-Jul-14 EPA 8260 10.0 100.0 ND ---ND ND ND
23-Oct-14 EPA 8260 10.0 100.0 ND ND ND ND ND
21-May-15 EPA 8260 10.0 100.0 ND ND ND ND ND
8-Dec-15 EPA 8260 10.0 100.0 ND ND ND ND ND
Benzene 10-Apr-14 EPA 8260 0.25 1 ND --- ND 6.6 ND
NC 2L = 1 µg/L (10/23/07) 6-May-14 EPA 8260 0.25 1 ND --- ND 6.5 ND
20-Jun-14 EPA 8260 0.25 1 ND --- ND 5.5 ND
17-Jul-14 EPA 8260 0.25 1 ND --- ND 4.6 ND
23-Oct-14 EPA 8260 0.25 1.0 ND ND ND 5.9 ND
21-May-15 EPA 8260 0.25 1.0 ND ND ND 4.9 ND
8-Dec-15 EPA 8260 0.25 1.0 ND ND ND 4.4 ND
Chlorobenzene 10-Apr-14 EPA 8260 0.23 3 ND --- ND 0.71 J ND
NC 2L = 50 µg/L (10/23/07) 6-May-14 EPA 8260 0.23 3 ND --- ND 0.6 J ND
20-Jun-14 EPA 8260 0.23 3 ND --- ND 0.5 J ND
17-Jul-14 EPA 8260 0.23 3 ND --- ND 0.61 J ND
23-Oct-14 EPA 8260 0.23 3.0 ND ND ND 0.61 J ND
21-May-15 EPA 8260 0.23 3.0 ND ND ND 0.51 J ND
8-Dec-15 EPA 8260 0.23 3.0 ND ND ND 0.49 J ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 2 of 4
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED GROUNDWATER CONSTITUENTS
Analyte Sample Collect Date EPA Method DL RL MW-21 MW-20 MW-22S MW-38 Blanks
1,2-Dichlorobenzene 10-Apr-14 EPA 8260 0.3 5 ND --- ND 0.3 J ND
NC 2L = 20 µg/L (01/01/10) 6-May-14 EPA 8260 0.3 5 ND --- ND 0.36 J ND
20-Jun-14 EPA 8260 0.3 5 ND --- ND ND ND
17-Jul-14 EPA 8260 0.3 5 ND --- ND ND ND
23-Oct-14 EPA 8260 0.30 5.0 ND ND ND 0.31 J ND
21-May-15 EPA 8260 0.30 5.0 ND ND ND ND ND
8-Dec-15 EPA 8260 0.30 5.0 ND ND ND ND ND
1,4-Dichlorobenzene 10-Apr-14 EPA 8260 0.33 1 ND --- ND 13.9 ND
NC 2L = 6 µg/L (01/01/10) 6-May-14 EPA 8260 0.33 1 ND --- ND 13.5 ND
20-Jun-14 EPA 8260 0.33 1 ND --- ND 9.9 ND
17-Jul-14 EPA 8260 0.33 1 ND --- ND 13.0 ND
23-Oct-14 EPA 8260 0.33 1.0 ND ND ND 12.9 ND
21-May-15 EPA 8260 0.33 1.0 ND ND ND 12.3 ND
8-Dec-15 EPA 8260 0.33 1.0 ND ND ND 12.2 ND
1,1-Dichloroethane 10-Apr-14 EPA 8260 0.32 5 ND --- ND 8.6 ND
NC 2L = 6 µg/L (01/01/10) 6-May-14 EPA 8260 0.32 5 ND --- ND 8.1 ND
20-Jun-14 EPA 8260 0.32 5 ND --- ND 8.0 ND
17-Jul-14 EPA 8260 0.32 5 ND --- ND 5.7 ND
23-Oct-14 EPA 8260 0.32 5.0 ND ND ND 6.9 ND
21-May-15 EPA 8260 0.32 5.0 ND ND ND 5.5 ND
8-Dec-15 EPA 8260 0.32 5.0 ND ND ND 7.2 ND
1,2-Dichloroethane 10-Apr-14 EPA 8260 0.12 1 ND --- ND 0.77 J ND
NC 2L = 0.4 µg/L (01/01/10) 6-May-14 EPA 8260 0.12 1 ND --- ND ND ND
20-Jun-14 EPA 8260 0.12 1 ND --- ND 0.63 J ND
17-Jul-14 EPA 8260 0.12 1 ND --- ND 0.79 J ND
23-Oct-14 EPA 8260 0.12 1.0 ND ND ND 0.63 J ND
21-May-15 EPA 8260 0.12 1.0 ND ND ND ND ND
8-Dec-15 EPA 8260 0.24 1.0 ND ND ND 0.70 J ND
cis-1,2-Dichloroethene 10-Apr-14 EPA 8260 0.19 5 ND --- ND 19.6 ND
NC 2L = 70 µg/L (10/23/07) 6-May-14 EPA 8260 0.19 5 ND --- ND 17.1 ND
20-Jun-14 EPA 8260 0.19 5 ND --- ND 16 ND
17-Jul-14 EPA 8260 0.19 5 ND --- ND 14.1 ND
23-Oct-14 EPA 8260 0.19 5.0 ND ND ND 16.3 ND
21-May-15 EPA 8260 0.19 5.0 ND ND ND 12.1 ND
8-Dec-15 EPA 8260 0.19 5.0 ND ND ND 14.7 ND
Ethylbenzene 10-Apr-14 EPA 8260 0.3 1 ND --- ND 1.2 ND
NC 2L = 600 µg/L (01/01/10) 6-May-14 EPA 8260 0.3 1 ND --- ND 1.3 ND
20-Jun-14 EPA 8260 0.3 1 ND --- ND 0.77 J ND
17-Jul-14 EPA 8260 0.3 1 ND --- ND 0.64 J ND
23-Oct-14 EPA 8260 0.30 1.0 ND ND ND 1.3 ND
21-May-15 EPA 8260 0.30 1.0 ND ND ND 1.1 ND
8-Dec-15 EPA 8260 0.30 1.0 ND ND ND ND ND
2-Hexanone (MBK) 10-Apr-14 EPA 8260 0.46 50 ND --- 0.55 J ND ND
GWPS = 280 µg/L (01/01/10) 6-May-14 EPA 8260 0.46 50 ND --- ND ND ND
20-Jun-14 EPA 8260 0.46 50 ND --- ND ND ND
17-Jul-14 EPA 8260 0.46 50 ND --- ND ND ND
23-Oct-14 EPA 8260 0.46 50 ND ND ND ND ND
GWPS = 280 µg/L (02/01/15) 21-May-15 EPA 8260 0.46 50 ND ND ND ND ND
8-Dec-15 EPA 8260 0.46 50 ND ND ND ND ND
4-Methyl-2-pentanone (MIBK) 10-Apr-14 EPA 8260 0.33 100 ND --- ND 3.7 J ND
GWPS = 560 µg/L (12/7/10) 6-May-14 EPA 8260 0.33 100 ND --- ND 8.2 J ND
20-Jun-14 EPA 8260 0.33 100 ND --- ND ND ND
17-Jul-14 EPA 8260 0.33 100 ND --- ND ND ND
23-Oct-14 EPA 8260 0.33 100.0 ND ND ND 1.5 J ND
21-May-15 EPA 8260 0.33 100.0 ND ND ND ND
8-Dec-15 EPA 8260 0.33 100.0 ND ND ND ND ND
Methane 10-Apr-14 RSK 174 3.3 6.6 --- --- --- --- ---
6-May-14 RSK 175 3.3 6.6 --- --- --- 4,150 ---
20-Jun-14 RSK 176 3.3 6.6 --- --- --- --- ---
17-Jul-14 RSK 177 3.3 6.6 --- --- --- --- ---
23-Oct-14 RSK 175 3.3 6.6 --- --- ---6,820 ---
21-May-15 RSK 175 3.3 6.6 --- --- ---4,900 ---
8-Dec-15 RSK 175 3.3 6.6 --- --- ---3,112 2.0 J
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 3 of 4
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED GROUNDWATER CONSTITUENTS
Analyte Sample Collect Date EPA Method DL RL MW-21 MW-20 MW-22S MW-38 Blanks
Methylene Chloride 8-Dec-15 EPA 8260 1.0 1.0 ND ND ND ND 2.0
NC 2L = 5 (02/01/15)
Tetrahydrofuran 10-Apr-14 EPA 8260 3.1 10 ND --- ND 923 ND
NC 2L = NE (01/01/10) 6-May-14 EPA 8260 3.1 10 ND --- ND 848 ND
20-Jun-14 EPA 8260 3.1 10 ND --- ND 758 ND
17-Jul-14 EPA 8260 3.1 10 ND --- ND 841 ND
23-Oct-14 EPA 8260 3.1 10.0 ND ND ND 744 ND
21-May-15 EPA 8260 3.1 10.0 ND ND ND 407 ND
8-Dec-15 EPA 8260 3.1 10.0 ND ND ND 39.1 ND
Toluene 10-Apr-14 EPA 8260 0.26 1 ND --- ND 0.62 J ND
NC 2L = 600 µg/L (01/01/10) 6-May-14 EPA 8260 0.26 1 ND --- ND 0.68 J ND
20-Jun-14 EPA 8260 0.26 1 ND --- ND 0.32 J ND
17-Jul-14 EPA 8260 0.26 1 ND --- ND 0.28 J ND
23-Oct-14 EPA 8260 0.26 1.0 ND ND ND 0.66 J ND
21-May-15 EPA 8260 0.26 1.0 ND ND ND 0.48 J ND
8-Dec-15 EPA 8260 0.26 1.0 ND ND ND ND ND
Trichloroethene 10-Apr-14 EPA 8260 0.47 1 ND --- ND 2.7 ND
NC 2L = 3 µg/L (01/01/10) 6-May-14 EPA 8260 0.47 1 ND --- ND 2.1 ND
20-Jun-14 EPA 8260 0.47 1 ND --- ND 2.2 ND
17-Jul-14 EPA 8260 0.47 1 ND --- ND 2.5 ND
23-Oct-14 EPA 8260 0.47 1.0 ND ND ND 1.8 ND
21-May-15 EPA 8260 0.47 1.0 ND ND ND 0.92 J ND
8-Dec-15 EPA 8260 0.47 1.0 ND ND ND 2.1 ND
Xylene (Total) 10-Apr-14 EPA 8260 0.66 5 ND --- ND 16.9 ND
NC 2L = 500 µg/L (01/01/10) 6-May-14 EPA 8260 0.66 5 ND --- ND 19.3 ND
20-Jun-14 EPA 8260 0.66 5 ND --- ND 2.5 J ND
17-Jul-14 EPA 8260 0.66 5 ND --- ND 8.8 ND
23-Oct-14 EPA 8260 0.66 5.0 ND ND ND 18.7 ND
21-May-15 EPA 8260 0.66 5.0 ND ND ND 17.1 ND
8-Dec-15 EPA 8260 0.66 5.0 ND ND ND 1.6 J ND
Notes:
All concentrations in micrograms per liter (µg/L) = parts per billion.
RL = Reporting Limit (SWSL).
DL = Laboratory Detection Limit.
--- = Not sampled for this parameter or Not reported.
ND = Not Detected at or above the DL.
J = Estimated value - concentration is less than the RL but greater than the DL.
B = Blank-Qualified (Concentration suspected to reflect laboratory or field contamination based on similar concentrations detected in field, trip, or method blanks).
NC 2L = Groundwater Standard from 15A NCAC 2L.0202.
GWPS = Groundwater Protection Standard set by NC-DENR-SWS for constituents with no listed NC 2L standard.
NE = No NC 2L or GWPS established.
Values above the NC 2L Standard or GWPS are bold.
Background data: April to July 2014.
Verification Sampling Event for metals in MW-22S was performed on February 4, 2016
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 4 of 4
Joyce Engineering

Appendix E

Historical Detected Constituents in Additional Wells and Piezometers

APPENDIX E:
DETECTED CONSTITUENTS IN ADDITIONAL WELLS/PIEZOMETERS
Sample
Analyte Collection Date DL RL MW-36 MW-15S PZ-12 PZ-30S PZ-31 PZ-34 Blanks
Organic Compounds
Acetone 18-Feb-13 10.0 100 19.8 J --- --- ND --- --- ND
18-Jul-13 10.0 100 --- --- --- --- ND ND 15.80 J
NC 2L = 6,000 µg/L (01/01/10)6-May-14 10.0 100 --- --- --- --- --- nle ND
22-Oct-14 10.0 100 --- --- --- --- --- nle ND
21-May-15 10.0 100 --- --- --- --- --- nle ND
9-Dec-16 10.0 100 --- --- --- --- --- nle ND
Benzene 18-Feb-13 0.25 1.0 8.0 --- --- ND --- --- ND
18-Jul-13 0.25 1.0 --- --- --- ---7.6 ND ND
NC 2L = 1 µg/L (10/23/07)6-May-14 0.25 1.0 8.7 4.6 --- ND ND nle ND
22-Oct-14 0.25 1.0 8.3 3.3 ND ND ND nle ND
21-May-15 0.25 1.0 5.8 2.0 ND ND ND nle ND
9-Dec-15 0.25 1.0 5.8 1.2 ND ND ND --- ---
Chlorobenzene 18-Feb-13 0.23 3.0 0.760 J --- --- ND --- --- ND
18-Jul-13 0.23 3.0 --- --- --- --- 0.480 J ND ND
NC 2L = 50 µg/L (10/23/07)6-May-14 0.23 3.0 --- --- --- --- --- nle ND
22-Oct-14 0.23 3.0 --- --- --- --- --- nle ND
21-May-15 0.23 3.0 --- --- --- --- --- nle ND
9-Dec-16 0.23 3.0 --- --- --- --- --- nle ND
Chloroethane 18-Feb-13 0.54 10.0 1.10 J --- --- ND --- --- ND
18-Jul-13 0.54 10.0 --- --- --- --- ND ND ND
NC 2L = 3,000 µg/L (01/01/10)6-May-14 0.54 10.0 --- --- --- --- --- nle ND
22-Oct-14 0.54 10.0 --- --- --- --- --- nle ND
21-May-15 0.54 10.0 --- --- --- --- --- nle ND
9-Dec-16 0.54 10.0 --- --- --- --- --- nle ND
1,2-Dichlorobenzene 18-Feb-13 0.30 5.0 0.44 J --- --- ND --- --- ND
18-Jul-13 0.30 5.0 --- --- --- --- 0.61 J ND ND
NC 2L = 20 µg/L (01/01/10)6-May-14 0.30 5.0 --- --- --- --- --- nle ND
22-Oct-14 0.30 5.0 --- --- --- --- --- nle ND
21-May-15 0.30 5.0 --- --- --- --- --- nle ND
9-Dec-16 0.30 5.0 --- --- --- --- --- nle ND
1,4-Dichlorobenzene 18-Feb-13 0.33 1.0 18.0 --- --- ND --- --- ND
18-Jul-13 0.33 1.0 --- --- --- ---6.5 ND ND
NC 2L = 6 µg/L (01/01/10)6-May-14 0.33 1.0 10.0 2.3 --- ND ND nle ND
22-Oct-14 0.33 1.0 15.2 1.6 ND ND ND nle ND
21-May-15 0.33 1.0 18.7 1.4 ND ND ND --- ---
9-Dec-15 0.33 1.0 19.6 1.0 ND ND ND --- ---
1,1-Dichloroethane 18-Feb-13 0.32 5.0 7.9 --- --- ND --- --- ND
18-Jul-13 0.32 5.0 --- --- --- ---11.3 ND ND
NC 2L = 6 µg/L (01/01/10)6-May-14 0.32 5.0 11.6 7.1 --- ND ND nle ND
22-Oct-14 0.32 5.0 9.0 4.9 J ND ND ND nle ND
21-May-15 0.32 5.0 4.8 J 2.4 J ND ND ND --- ---
9-Dec-15 0.32 5.0 5.9 2.2 J ND ND ND --- ---
1,2-Dichloroethane 18-Feb-13 0.12 1.0 1.0 --- --- ND --- --- ND
18-Jul-13 0.12 1.0 --- --- --- --- 0.54 J ND ND
NC 2L = 0.4 µg/L (01/01/10)6-May-14 0.12 1.0 0.78 J ND --- ND ND nle ND
22-Oct-14 0.12 1.0 0.92 J ND ND ND ND nle ND
21-May-15 0.12 1.0 ND ND ND ND ND --- ---
9-Dec-15 0.24 1.0 0.66 J ND ND ND ND --- ---
cis-1,2-Dichloroethylene 18-Feb-13 0.19 5.0 21.0 --- --- ND --- --- ND
18-Jul-13 0.19 5.0 --- --- --- --- 19.3 ND ND
NC 2L = 70 µg/L (10/23/07)6-May-14 0.19 5.0 --- --- --- --- --- nle ND
22-Oct-14 0.19 5.0 --- --- --- --- --- nle ND
21-May-15 0.19 5.0 --- --- --- --- --- nle ND
9-Dec-16 0.19 5.0 --- --- --- --- --- nle ND
Ethylbenzene 18-Feb-13 0.30 1.0 23.2 --- --- ND --- --- ND
18-Jul-13 0.30 1.0 --- --- --- --- 0.94 J ND ND
NC 2L = 600 µg/L (01/01/10)6-May-14 0.30 1.0 --- --- --- --- --- nle ND
22-Oct-14 0.30 1.0 --- --- --- --- --- nle ND
21-May-15 0.30 1.0 --- --- --- --- --- nle ND
9-Dec-16 0.30 1.0 --- --- --- --- --- nle ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 1 of 2
Joyce Engineering
APPENDIX E:
DETECTED CONSTITUENTS IN ADDITIONAL WELLS/PIEZOMETERS
Sample
Analyte Collection Date DL RL MW-36 MW-15S PZ-12 PZ-30S PZ-31 PZ-34 Blanks
Methylene Chloride 18-Feb-13 0.97 1.0 17.9 --- --- ND --- --- ND
18-Jul-13 0.97 1.0 NS --- --- ---16.4 ND ND
NC 2L = 5 µg/L (01/01/10)6-May-14 0.97 1.0 24.1 16.7 --- ND ND nle 2.20
22-Oct-14 0.97 1.0 15.7 1.6 ND ND ND nle ND
21-May-15 0.97 1.0 9.5 B 4.4 B ND ND ND --- 1.70
9-Dec-15 0.97 1.0 11.2 B 2.6 B ND ND ND --- 2.00
Tetrachloroethene 18-Feb-13 0.46 1.0 5.5 --- --- ND --- --- ND
18-Jul-13 0.46 1.0 NS --- --- ---7.8 ND ND
NC 2L = 0.7 µg/L (10/23/07)6-May-14 0.46 1.0 7.9 6.9 --- ND ND nle ND
22-Oct-14 0.46 1.0 7.3 5.2 ND ND ND nle ND
21-May-15 0.46 1.0 6.0 3.3 ND ND ND --- ---
9-Dec-15 0.46 1.0 5.0 2.1 ND ND ND --- ---
Toluene 18-Feb-13 0.26 1.0 44.10 --- --- ND --- --- ND
18-Jul-13 0.26 1.0 --- --- --- --- 1.50 ND ND
NC 2L = 600 µg/L (01/01/10)6-May-14 0.26 1.0 --- --- --- --- --- nle ND
22-Oct-14 0.26 1.0 --- --- --- --- --- nle ND
21-May-15 0.26 1.0 --- --- --- --- --- nle ND
9-Dec-16 0.26 1.0 --- --- --- --- --- nle ND
Trichloroethene 18-Feb-13 0.47 1.0 3.6 --- --- ND --- --- ND
18-Jul-13 0.47 1.0 --- --- --- ---5.8 ND ND
NC 2L = 3 µg/L (01/01/10)6-May-14 0.47 1.0 6.0 4.3 --- ND ND nle ND
22-Oct-14 0.47 1.0 5.1 3.4 ND ND ND nle ND
21-May-15 0.47 1.0 3.5 2.1 ND ND ND --- ---
9-Dec-15 0.47 1.0 2.9 1.1 ND ND ND --- ---
Trichlorofluoromethane 18-Feb-13 0.20 1.0 0.650 J --- --- ND --- --- ND
18-Jul-13 0.20 1.0 --- --- --- --- 0.890 J ND ND
NC 2L = 2,000 µg/L (01/01/10)6-May-14 0.20 1.0 --- --- --- --- --- nle ND
22-Oct-14 0.20 1.0 --- --- --- --- --- nle ND
21-May-15 0.20 1.0 --- --- --- --- --- nle ND
9-Dec-16 0.20 1.0 --- --- --- --- --- nle ND
Vinyl chloride 18-Feb-13 0.62 1.0 1.2 --- --- ND --- --- ND
18-Jul-13 0.62 1.0 --- --- --- --- ND ND ND
NC 2L = 0.03 µg/L (01/01/10)6-May-14 0.62 1.0 1.1 ND --- ND ND nle ND
22-Oct-14 0.62 1.0 0.87 J ND ND ND ND nle ND
21-May-15 0.62 1.0 ND ND ND ND ND --- ---
9-Dec-15 0.62 1.0 0.80 J ND ND ND ND --- ---
Xylene (Total)18-Feb-13 0.66 2.0 295 --- --- ND --- --- ND
18-Jul-13 0.66 2.0 --- --- --- --- 92.5 ND ND
NC 2L = 500 µg/L (01/01/10)6-May-14 0.66 2.0 --- --- --- --- --- nle ND
22-Oct-14 0.66 2.0 --- --- --- --- --- nle ND
21-May-15 0.66 2.0 --- ND ND ND ND --- ---
9-Dec-16 0.66 2.0 --- ND ND ND ND --- ---
Methane 18-Feb-13 0.66 2.0 --- --- --- --- --- --- ---
(Dissolved Methane)18-Jul-13 0.66 2.0 --- --- --- --- --- --- ---
6-May-14 0.66 2.0 348 9940 --- ND ND nle ---
22-Oct-14 3.30 6.6 8450 13000 ND ND ND nle ND
21-May-15 0.63 10.0 173 4680 2.0 J 1.5 J 1.7 J --- ---
9-Dec-15 0.63 10.0 3780 8550 3.0 J 2.5 J 4.8 J --- ---
Notes:
All concentrations in micrograms per liter (µg/L) = parts per billion. ND = Not Detected above the DL.
DL = Laboratory Detection Limit. J = Estimated value - Concentration is less than the SWSL but greater than the DL.
RL = SWSL = Solid Waste Section Reporting Limit. B = Blank-Qualified (Concentration suspected to reflect laboratory or field contamination).
NC 2L = Groundwater Standard from 15A NCAC 2L.0202.Values above the NC 2L Standard are bold
Italics = Constituent of Concern (COC).
nle = No longer exists (MW-34 was accidentaly destroyed during construciton activties).
--- = Not reported or Not monitored
MW-36 was converted from PZ-36.
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 2 of 2
Joyce Engineering

Appendix F

Historical Detected Surface Water Constituents

APPENDIX F:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Inorganic Compounds
Antimony 6-Nov-08 2.6 6.0 ND 8.4 ---ND
3-Jun-09 2.6 6.0 ND ND --- ND
18-Nov-09 2.6 6.0 ND ND --- ND
NC 2B = NE (05/01/07) 15-Jun-10 2.6 6.0 ND ND --- ND
1-Dec-10 2.6 6.0 ND ND --- ND
1-Jun-11 2.6 6.0 ND ND --- ND
20-Dec-11 5.0 6.0 ND ND --- ND
30-May-12 5.0 6.0 ND ND --- ND
5-Dec-12 5.0 6.0 ND ND --- ND
12-Jun-13 5.0 6.0 ND ND --- ND
28-Oct-13 5.0 6.0 ND ND --- ND
6-May-14 5.0 6.0 ND ND --- ND
22-Oct-14 5.0 6.0 --- ND ND ND
21-May-15 3.8 6.0 ND ND ND ND
9-Dec-15 3.8 6.0 ND ND ND ND
Arsenic 6-Nov-08 2.7 10.0 2.9 B 4.5 B ---4.1 J
3-Jun-09 2.7 10.0 ND 4.5 J --- ND
18-Nov-09 2.7 10.0 ND ND --- ND
NC 2B = 10 µg/L (05/01/07) 15-Jun-10 2.7 10.0 ND ND --- ND
1-Dec-10 2.7 10.0 ND ND --- ND
1-Jun-11 2.7 10.0 ND ND --- ND
20-Dec-11 5.0 10.0 ND ND --- ND
30-May-12 5.0 10.0 ND ND --- ND
5-Dec-12 5.0 10.0 ND ND --- ND
12-Jun-13 5.0 10.0 ND ND --- ND
28-Oct-13 5.0 10.0 ND ND --- ND
6-May-14 5.0 10.0 ND ND --- ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
Barium 30-May-07 --- 100 81.3 J 23.8 J ---0.2 J
29-Nov-07 --- 100 116 27.5 J --- 0.50 J
29-May-08 0.2 100 71.9 J 19.6 J --- ND
6-Nov-08 0.20 100 82.5 J 40.2 B --- 9.6 J
3-Jun-09 0.20 100 104 36.2 B --- 15.9 J
18-Nov-09 0.20 100 49.9 B 15.7 B --- 20.1 J
NC 2B = 1,000 µg/L (05/01/07) 15-Jun-10 0.20 100 47.6 J 20.7 J --- 0.77 J
1-Dec-10 0.20 100 39.8 J 46.8 J --- ND
1-Jun-11 0.20 100 51.6 J 19.9 J --- ND
20-Dec-11 5.0 100 63.7 J 13.9 J --- ND
30-May-12 5.0 100 16.9 J 22.0 J --- ND
5-Dec-12 5.0 100 69.9 J 24.8 J --- ND
12-Jun-13 5.0 100 54.9 B 40.0 B ---13.6 J
28-Oct-13 5.0 100 35.4 J 20.8 J --- ND
6-May-14 5.0 100 37.0 J 17.8 J --- ND
22-Oct-14 5.0 100 --- 25.5 J 19.8 J ND
21-May-15 2.5 100 53.0 J 14.6 J 21.6 J ND
9-Dec-15 2.5 100 26.1 J 23.4 J 27.8 J ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 1 of 8
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Beryllium 14-Nov-02 --- 2 2.0 B 2.2 B ---2.1
14-May-03 --- 2 ND ND --- ND
20-Nov-03 --- 2 ND ND --- ND
6-May-04 --- 2 ND ND --- ND
10-Nov-04 --- 2 ND ND --- ND
5-May-05 --- 2 ND ND --- ND
3-Nov-05 --- 2 ND ND --- ND
25-May-06 --- 2 ND ND --- ND
2-Nov-06 --- 2 ND ND --- ND
30-May-07 --- 1 ND ND --- ND
29-Nov-07 --- 1 ND ND --- ND
29-May-08 0.10 1.0 ND ND --- ND
6-Nov-08 0.10 1.0 0.24 B 0.37 B ---0.29 J
3-Jun-09 0.10 1.0 0.64 J 0.21 J --- ND
18-Nov-09 0.10 1.0 ND ND --- ND
NC 2B = 6.5 µg/L (05/01/07) 15-Jun-10 0.10 1.0 ND ND ---ND
1-Dec-10 0.10 1.0 ND ND --- ND
1-Jun-11 0.10 1.0 ND ND --- ND
20-Dec-11 1.0 1.0 ND ND --- ND
30-May-12 1.0 1.0 ND ND --- ND
5-Dec-12 1.0 1.0 ND ND --- ND
12-Jun-13 1.0 1.0 ND ND --- ND
28-Oct-13 1.0 1.0 ND ND --- ND
6-May-14 1.0 1.0 ND ND --- ND
22-Oct-14 1.0 1.0 --- ND ND ND
21-May-15 0.5 1.0 ND ND ND ND
9-Dec-15 0.5 1.0 ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 2 of 8
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Cadmium 7-Nov-01 --- 1 ND 1.0 --- ND
22-May-02 --- 1 ND 1.7 B --- 1.3
14-Nov-02 --- 1 ND ND --- ND
14-May-03 --- 1 ND ND --- ND
20-Nov-03 --- 1 ND ND --- ND
6-May-04 --- 1 ND ND --- ND
10-Nov-04 --- 1 ND ND --- ND
5-May-05 --- 1 ND ND --- ND
3-Nov-05 --- 1 ND ND --- ND
25-May-06 --- 1 ND ND --- ND
2-Nov-06 --- 1 ND ND --- ND
30-May-07 --- 1 ND ND --- ND
29-Nov-07 --- 1 ND ND ---ND
29-May-08 0.5 1.0 ND ND --- ND
6-Nov-08 0.50 1.0 ND ND --- ND
3-Jun-09 0.50 1.0 ND ND ---ND
18-Nov-09 0.50 1.0 ND ND --- ND
NC 2B = 2 µg/L (05/01/07) 15-Jun-10 0.50 1.0 ND ND --- ND
1-Dec-10 0.50 1.0 ND ND --- ND
1-Jun-11 0.50 1.0 ND ND --- ND
20-Dec-11 1.0 1.0 ND ND --- ND
30-May-12 1.0 1.0 ND ND --- ND
5-Dec-12 1.0 1.0 ND ND --- ND
12-Jun-13 1.0 1.0 ND ND --- ND
28-Oct-13 1.0 1.0 ND ND --- ND
6-May-14 1.0 1.0 ND ND --- ND
22-Oct-14 1.0 1.0 --- ND ND ND
21-May-15 0.5 1.0 ND ND ND ND
9-Dec-15 0.5 1.0 ND ND ND ND
Chromium 6-Nov-08 0.40 10.0 ND 0.47 J --- ND
3-Jun-09 0.40 10.0 7.5 J 3.2 J --- ND
18-Nov-09 0.40 10.0 ND ND --- ND
NC 2B = 50 µg/L (05/01/07) 15-Jun-10 0.40 10.0 1.2 B 0.48 B --- 0.74 J
1-Dec-10 0.40 10.0 0.68 B 5.1 J --- 0.51 J
1-Jun-11 0.40 10.0 0.59 B 0.59 B --- 0.73 J
20-Dec-11 5.0 10.0 ND ND --- ND
30-May-12 5.0 10.0 ND ND --- ND
5-Dec-12 5.0 10.0 ND ND --- ND
12-Jun-13 5.0 10.0 ND ND --- ND
28-Oct-13 5.0 10.0 ND ND --- ND
6-May-14 5.0 10.0 ND ND --- ND
22-Oct-14 5.0 10.0 --- ND 9.7 J ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 3 of 8
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Cobalt 22-May-02 --- 10 14.0 17.0 --- 11.0
14-Nov-02 --- 10 ND ND --- ND
14-May-03 --- 10 ND 10.0 --- ND
20-Nov-03 --- 10 14.0 ND --- ND
6-May-04 --- 10 ND ND --- ND
10-Nov-04 --- 10 10.0 ND --- ND
5-May-05 --- 10 10.0 ND --- ND
3-Nov-05 --- 10 16.0 ND --- ND
25-May-06 --- 10 12 ND --- ND
2-Nov-06 --- 10 13.6 ND --- ND
30-May-07 --- 10 12.3 8.8 J --- ND
29-Nov-07 --- 10 19.0 2.1 J --- ND
29-May-08 0.60 10.0 13.7 ND --- ND
6-Nov-08 0.60 10.0 12.6 ND --- 0.65 J
3-Jun-09 0.60 10.0 11.9 B 6.6 B --- 7.6 J
18-Nov-09 0.60 10.0 3.6 J 4.6 J --- ND
NC 2B = NE (05/01/07) 15-Jun-10 0.60 10.0 6.4 J 22.3 --- ND
1-Dec-10 0.60 10.0 0.76 J 4.1 J --- ND
1-Jun-11 0.60 10.0 2.0 J 1.7 J --- ND
20-Dec-11 5.0 10.0 ND ND --- ND
30-May-12 5.0 10.0 ND ND --- ND
5-Dec-12 5.0 10.0 29.0 7.7 J --- ND
12-Jun-13 5.0 10.0 ND 9.1 J --- ND
28-Oct-13 5.0 10.0 11.5 12.4 --- ND
6-May-14 5.0 10.0 ND ND --- ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 6.3 J ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
Copper 29-May-08 0.30 10.0 ND 1.3 B --- 0.37 J
6-Nov-08 4.0 10.0 0.45 B 3.4 J --- 0.65 J
3-Jun-09 0.30 10.0 6.6 J 2.1 J --- ND
18-Nov-09 0.30 10.0 ND ND --- ND
NC 2B = 7 µg/L (05/01/07) 15-Jun-10 0.30 10.0 0.56 B ND --- 0.77 J
1-Dec-10 0.30 10.0 3.6 J 5.9 J --- ND
1-Jun-11 0.30 10.0 1.8 J 0.35 J --- ND
20-Dec-11 5.0 10.0 ND ND --- ND
30-May-12 5.0 10.0 ND ND --- ND
5-Dec-12 5.0 10.0 ND ND --- ND
12-Jun-13 5.0 10.0 5.2 B ND --- 9.8 J
28-Oct-13 5.0 10.0 ND ND --- ND
6-May-14 5.0 10.0 ND ND --- ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 4 of 8
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Lead 3-Jun-09 4.0 10.0 7.3 J ND --- ND
18-Nov-09 4.0 10.0 ND ND --- ND
NC 2B = 25 µg/L (05/01/07) 15-Jun-10 4.0 10.0 ND ND --- ND
1-Dec-10 4.0 10.0 ND 4.6 J --- ND
1-Jun-11 4.0 10.0 ND ND --- ND
20-Dec-11 5.0 10.0 ND ND --- ND
30-May-12 5.0 10.0 ND ND --- ND
5-Dec-12 5.0 10.0 ND ND --- ND
12-Jun-13 5.0 10.0 ND ND --- ND
28-Oct-13 5.0 10.0 ND ND --- ND
6-May-14 5.0 10.0 ND ND --- ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
Nickel 3-Jun-09 1.7 50.0 5.5 B ND --- 1.7 J
18-Nov-09 1.7 50.0 ND ND --- ND
NC 2B = 25 µg/L (05/01/07) 15-Jun-10 1.7 50.0 ND ND --- ND
1-Dec-10 1.7 50.0 2.8 J 2.8 J --- ND
1-Jun-11 1.7 50.0 ND ND --- 2.3 J
20-Dec-11 5.0 50.0 ND ND --- ND
30-May-12 5.0 50.0 ND ND --- ND
5-Dec-12 5.0 50.0 ND ND --- ND
12-Jun-13 5.0 50.0 ND ND --- ND
28-Oct-13 5.0 50.0 ND ND --- ND
6-May-14 5.0 50.0 ND ND --- ND
22-Oct-14 5.0 50.0 --- ND ND ND
21-May-15 2.5 50.0 ND ND ND ND
9-Dec-15 2.5 50.0 ND ND ND ND
Selenium 6-Nov-08 3.8 10 ND 10.9 --- ND
3-Jun-09 3.8 10.0 ND ND --- ND
18-Nov-09 3.8 10.0 ND ND --- ND
NC 2B = 5 µg/L (05/01/07) 15-Jun-10 3.8 10.0 ND ND --- ND
1-Dec-10 3.8 10.0 ND ND --- ND
1-Jun-11 3.8 10.0 ND ND --- ND
20-Dec-11 10.0 10.0 ND ND --- ND
30-May-12 10.0 10.0 ND ND --- ND
5-Dec-12 10.0 10.0 ND ND --- ND
12-Jun-13 10.0 10.0 ND ND --- ND
28-Oct-13 10.0 10.0 ND ND --- ND
6-May-14 10.0 10.0 ND ND --- ND
22-Oct-14 10.0 10.0 --- ND ND ND
21-May-15 5.0 10.0 ND ND ND ND
9-Dec-15 5.0 10.0 ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 5 of 8
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Silver 22-May-02 --- 10 16.0 B 15.0 B --- 15.0
14-Nov-02 --- 10 ND ND --- ND
14-May-03 --- 10 ND ND --- ND
20-Nov-03 --- 10 ND ND --- ND
6-May-04 --- 10 ND ND --- ND
10-Nov-04 --- 10 ND ND --- ND
5-May-05 --- 10 ND ND --- ND
3-Nov-05 --- 10 ND ND --- ND
25-May-06 --- 10 ND ND --- ND
2-Nov-06 --- 10 ND ND --- ND
30-May-07 --- 10 ND ND --- ND
29-Nov-07 --- 10 ND ND --- ND
29-May-08 0.10 10.0 0.29 J 0.13 J --- ND
6-Nov-08 0.10 10.0 0.72 B 0.38 B --- 0.23 J
3-Jun-09 0.10 10.0 0.18 B ND --- 0.31 J
18-Nov-09 0.10 10.0 0.27 B 0.23 B --- 0.23 J
NC 2B = 0.06 µg/L (05/01/07) 15-Jun-10 0.10 10.0 ND ND --- ND
1-Dec-10 0.10 10.0 ND ND --- ND
1-Jun-11 0.10 10.0 ND 0.22 J --- ND
20-Dec-11 5.0 10.0 ND ND --- ND
30-May-12 5.0 10.0 ND ND --- ND
5-Dec-12 5.0 10.0 ND ND --- ND
12-Jun-13 5.0 10.0 ND ND --- ND
28-Oct-13 5.0 10.0 ND ND --- ND
6-May-14 5.0 10.0 ND ND --- ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
Thallium 5-May-05 --- 10 22.0 11.0 --- ND
3-Nov-05 --- 10 20.0 ND --- ND
25-May-06 --- 10 ND ND --- ND
2-Nov-06 --- 10 ND ND --- ND
30-May-07 --- 5.5 0.053 J ND --- ND
29-Nov-07 --- 5.5 0.055 J ND --- ND
29-May-08 3.0 5.5 ND ND --- ND
6-Nov-08 3.0 5.5 ND ND --- ND
3-Jun-09 3.0 5.5 ND ND --- ND
18-Nov-09 3.0 5.5 ND ND --- 4.2 J
NC 2B = NE (05/01/07) 15-Jun-10 3.0 5.5 3.2 J ND --- ND
1-Dec-10 3.0 5.5 ND ND --- 4.0 J
1-Jun-11 3.0 5.5 ND ND --- ND
20-Dec-11 5.4 5.5 ND ND --- ND
30-May-12 5.4 5.5 ND ND --- ND
5-Dec-12 5.4 5.5 ND ND --- ND
12-Jun-13 5.4 5.5 ND ND --- ND
28-Oct-13 5.4 5.5 ND ND --- ND
6-May-14 5.4 5.5 ND ND --- ND
22-Oct-14 5.4 5.5 --- ND ND ND
21-May-15 5.0 5.5 ND ND ND ND
9-Dec-15 5.0 5.5 ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 6 of 8
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Vanadium 6-Nov-08 0.20 25.0 0.90 B 8.9 B --- 2.1 J
3-Jun-09 0.20 25.0 17.4 J 7.5 J --- 1.0 J
18-Nov-09 0.20 25.0 0.26 B 0.30 B --- 0.56 J
NC 2B = NE (05/01/07) 15-Jun-10 0.20 25.0 1.5 B 1.0 B --- 0.98 J
1-Dec-10 0.20 25.0 1.1 J 13.7 J --- ND
1-Jun-11 0.20 25.0 1.1 J 0.74 J --- ND
20-Dec-11 5.0 25.0 ND ND --- ND
30-May-12 5.0 25.0 ND ND --- ND
5-Dec-12 5.0 25.0 ND ND --- ND
12-Jun-13 5.0 25.0 7.6 J ND --- ND
28-Oct-13 5.0 25.0 ND ND --- ND
6-May-14 5.0 25.0 ND ND --- ND
22-Oct-14 5.0 25.0 --- ND ND ND
21-May-15 2.5 25.0 7.5 J ND 4.1 J ND
9-Dec-15 2.5 25.0 ND ND 3.9 J ND
Zinc 30-May-07 --- 10 1.8 B ND --- 1.6 J
29-Nov-07 --- 10 9.6 B ND --- 3.1 J
29-May-08 0.40 10.0 6.0 B ND --- 3.0 J
6-Nov-08 0.40 10.0 0.82 B 1.4 B --- 2.7 J
3-Jun-09 0.40 10.0 33.7 B 9.6 B --- 82.0
18-Nov-09 0.40 10.0 2.2 B 2.5 B --- 3.1 J
NC 2B = 50 µg/L (05/01/07) 15-Jun-10 0.40 10.0 ND ND --- ND
1-Dec-10 0.40 10.0 8.8 J 6.6 J --- 0.62 J
1-Jun-11 0.40 10.0 15.1 B 21.5 B --- 13.7
20-Dec-11 10.0 10.0 ND ND --- ND
30-May-12 10.0 10.0 ND ND --- ND
5-Dec-12 10.0 10.0 ND ND --- ND
12-Jun-13 10.0 10.0 ND ND --- 76.5
28-Oct-13 10.0 10.0 ND ND --- ND
6-May-14 10.0 10.0 ND ND --- ND
22-Oct-14 10.0 10.0 --- ND ND ND
21-May-15 5.0 10.0 ND 5.8 J ND ND
9-Dec-15 5.0 10.0 ND ND ND ND
Organic Compounds
Acetone 29-Nov-07 --- 100 3.6 B ND --- 5.1 J
29-May-08 20 100 ND ND --- ND
6-Nov-08 20 100 ND ND --- ND
3-Jun-09 2.2 100 5.7 J ND --- ND
18-Nov-09 2.2 100 ND ND --- ND
NC 2B = NE (05/01/07) 15-Jun-10 2.2 100 2.2 B 2.3 B --- 7.2 J
1-Dec-10 2.2 100 ND ND --- 3.7 J
1-Jun-11 2.2 100 5.4 B 2.9 B --- 3.9 J
20-Dec-11 2.2 100 ND ND --- ND
30-May-12 2.2 100 ND ND --- ND
5-Dec-12 10.0 100 ND ND --- ND
12-Jun-13 10.0 100 ND ND --- ND
28-Oct-13 10.0 100 ND ND --- ND
6-May-14 10.0 100 ND ND --- ND
22-Oct-14 10.0 100 --- ND ND ND
21-May-15 10.0 100 ND ND ND ND
9-Dec-15 10.0 100 ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 7 of 8
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Chloromethane 15-Jun-10 0.11 1.0 ND 0.11 J --- ND
NC 2B = NE (05/01/07) 1-Dec-10 0.11 1.0 ND ND --- ND
1-Jun-11 0.11 1.0 ND ND --- ND
20-Dec-11 0.11 1.0 ND ND --- ND
30-May-12 0.11 1.0 ND ND --- ND
5-Dec-12 0.11 1.0 ND ND --- ND
12-Jun-13 0.11 1.0 ND ND --- ND
28-Oct-13 0.11 1.0 ND ND --- ND
6-May-14 0.11 1.0 ND ND --- ND
22-Oct-14 0.11 1.0 --- ND ND ND
21-May-15 0.11 1.0 ND ND ND ND
9-Dec-15 0.11 1.0 ND ND ND ND
1,1-Dichloroethane 1-Jun-11 0.32 5.0 ND 0.41 J --- ND
NC 2B = NE (05/01/07) 20-Dec-11 0.32 5.0 ND ND --- ND
30-May-12 0.32 5.0 ND ND --- ND
5-Dec-12 0.32 5.0 ND 1.6 J --- ND
12-Jun-13 0.32 5.0 ND ND --- ND
28-Oct-13 0.32 5.0 ND 0.96 J --- ND
6-May-14 0.32 5.0 ND ND --- ND
22-Oct-14 0.32 5.0 --- 1.5 J ND ND
21-May-15 0.32 5.0 ND ND ND ND
9-Dec-15 0.32 5.0 ND ND ND ND
cis-1,2-Dichloroethene 22-Oct-14 0.2 5.0 --- 0.20 J ND ND
21-May-15 0.2 5.0 ND ND ND ND
9-Dec-15 0.2 5.0 ND ND ND ND
NC 2B = NE (05/15/13)
Notes:
All concentrations in micrograms per liter (µg/L) = parts per billion.
RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006;
and SWSL for December 2006 - present).
DL = Laboratory Detection Limit.
NI = Monitoring well not yet installed.
AB = Monitoring well abandoned.
--- = Not sampled for this parameter or Not reported
ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006).
J = Estimated value - concentration is less than the RL but greater than the DL.
B = Blank-Qualified (Concentration suspected to reflect laboratory or field contamination based on
similar concentrations detected in field, trip, or method blanks).
D = Sample was diluted when analyzed.
NC 2B = Groundwater Standard from 15A NCAC 2B.
NE = No NC 2B established.
Values above the NC 2B Standard are bold.
Surface waters classified as WS-IV (water supply IV, highly developed), B (primary recreation, fresh water), and CA (critical area).
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 8 of 8
Joyce Engineering