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HomeMy WebLinkAbout5803_MadisonCounty_GWMReport_DIN26372_20151021 Prepared for Madison County, North Carolina Project Number 2313.1302 Prepared by Altamont Environmental, Inc. 231 Haywood Street Asheville, NC 28801 828.281.3350 Fall 2015 Semiannual Water Quality Monitoring Report Madison County Operating Solid Waste Facility Madison County, North Carolina Permit No. 58-03 February 16, 2016 Fall 2015 Semiannual Water Quality Monitoring Report February 16, 2016 Permit No. 58-03, Madison County, North Carolina Page iii P:\Madison County\Reports\2015\Fall\5803-Operating\FINAL 5803Oct2015 Semiannual Water Quality Report.doc Table of Contents 1.0 Introduction .................................................................................................................... 1 1.1 Groundwater Purging and Sampling Methods ..............................................................2 1.2 Surface Water Sampling Methods .................................................................................2 1.3 Leachte Sampling Methods ...........................................................................................2 1.4 Sample Handling, Documentation, and Analysis...........................................................3 2.0 Findings .......................................................................................................................... 4 2.1 Analytical Results ..........................................................................................................4 2.1.1 Groundwater Monitoring Wells .........................................................................4 2.1.2 Surface Water ...................................................................................................5 2.1.3 Leachate ...........................................................................................................5 3.0 Hydrogeology .................................................................................................................. 7 4.0 Summary ........................................................................................................................ 8 4.1 Future Activities .............................................................................................................8 5.0 References ..................................................................................................................... 9 Figures 1. Site Location Map 2. Sample Locations 3. Generalized Groundwater Flow Tables 1. Well Construction Details and Corresponding Elevations 2. Summary of Laboratory Analyses Performed on Samples 3. Groundwater and Surface Water Summary of Detected Compounds 4. Leachate Summary of Detected Compounds 5. Groundwater and Surface Water Solid Waste Section Limits Exceedances Notification 6. Groundwater and Surface Water Quality Standards Exceedances Notification Appendices A. Sampling Logs and Equipment Documentation and Instrument Calibration Data Sheets B.Reports of Laboratory Analysis and Chain-of-Custody Documentation C. Environmental Monitoring Reporting Form and Electronic Submittal of Environmental Monitoring Data 5803Apr2015 (Electronic Only) Fall 2015 Semiannual Water Quality Monitoring Report February 16, 2016 Permit No. 58-03, Madison County, North Carolina Page 1 P:\Madison County\Reports\2015\Fall\5803-Operating\FINAL 5803Oct2015 Semiannual Water Quality Report.doc 1.0 Introduction The Madison County Solid Waste Department operates a solid waste facility (Operating Landfill) located on Craig Rudisill Road, west of U.S. Highway 25/70 near Marshall, North Carolina. The site location map is included as Figure 1. The Operating Landfill includes the following permitted components: Operating Construction and Demolition Debris (C&D) landfill cell (Permit No. 58-03) Operating Transfer Station (Permit No. 58-03T) Closed C&D landfill cell (Permit No. 58-03) Closed Municipal Solid Waste (MSW) landfill cell (Permit No. 58-03) The Operating Landfill also contains a leachate underground holding tank that was installed in August 2011. Previously, the leachate was stored in a lined leachate basin that is no longer in use. State regulations applicable to landfills are enforced by the North Carolina Department of Environmental Quality (DEQ), Division of Waste Management (DWM). This solid waste facility is permitted by the DEQ DWM under Permit No. 58-03. The permit requires semiannual monitoring of groundwater, surface water, and leachate quality. This report documents the second semiannual groundwater, surface water, and leachate monitoring event for 2015 and is being submitted in accordance with requirements stipulated in the DEQ Solid Waste Management Rules, Title 15A, Subchapter 13B, of the North Carolina Administrative Code (15A NCAC 13B). This semiannual report provides an evaluation of groundwater, surface water, and leachate quality for the solid waste facility. The water quality monitoring network for the Operating Landfill consists of nine compliance monitoring wells (MW-01, MW-02, MW-03, MW-04, MW-05, MW-06R, MW-07R, MW-08, and MW-09), two surface water sample locations (SW-01 and SW-02R) located along a tributary to Walnut Creek, and a leachate sample (LT-01) collected from the fill port on the underground holding tank. Monitoring well construction details are summarized in Table 1. Fall 2015 Semiannual Water Quality Monitoring Report February 16, 2016 Permit No. 58-03, Madison County, North Carolina Page 2 P:\Madison County\Reports\2015\Fall\5803-Operating\FINAL 5803Oct2015 Semiannual Water Quality Report.doc Methods On October 20 and 21, 2015, Altamont Environmental, Inc. (Altamont) collected nine groundwater samples from monitoring wells, two surface water samples from a tributary to Walnut Creek, and one aqueous sample from the leachate underground holding tank located at the Madison County Operating Solid Waste Facility. One of the monitoring wells sampled, MW-06R, is upgradient from the landfill. Groundwater collected from this well is assumed to represent background groundwater quality at the site. This monitoring well was installed on September 30, 2008 as a replacement for the pre-existing background monitoring well, MW-06, which had historically been dry. Sampling locations are shown on Figures 2 and 3. 1.1 Groundwater Purging and Sampling Methods Prior to collecting groundwater samples from the monitoring wells, the static water level was measured and recorded for each well. The monitoring wells were purged and sampled using low-flow techniques in accordance with the procedures described in Low-Flow (Minimal Drawdown) Ground-Water Sampling Procedures, United States Environmental Protection Agency (EPA), Groundwater Issues (Puls and Barcelona 1996). During purging, pH, specific conductivity (SC), dissolved oxygen (DO), oxidation-reduction potential (ORP), turbidity, and temperature were measured and recorded approximately every 3 minutes. Well purging continued until these parameters stabilized for three consecutive readings. The required stabilization criteria are as follows: pH values within +/- 0.1 pH unit SC values within +/- 3 percent Temperature, DO, and turbidity values within +/- 10 percent ORP values within +/- 10 millivolts Following stabilization of these parameters, a groundwater sample was collected by a technician wearing a new pair of non-reactive nitrile gloves. Each sample was placed directly into laboratory-supplied sample containers. Low-flow sampling logs are included in Appendix A. 1.2 Surface Water Sampling Methods Surface water samples SW-01 and SW-02R were collected at designated locations from an unnamed tributary to Walnut Creek, which flows in a northerly direction adjacent to the western border of the Operating Landfill (Figure 2). Sample SW-01 is considered representative of surface water quality upstream of the Operating Landfill, while sample SW-02R is considered representative of surface water quality downstream from the facility. Surface water samples were collected in laboratory-supplied sample containers by a technician wearing a new pair of non-reactive nitrile gloves. As with groundwater sampling, temperature, pH, SC, DO, ORP, and turbidity were measured and recorded at each surface water sampling location prior to sample collection. Field parameters and observations pertaining to surface water quality are provided on sampling logs included in Appendix A. 1.3 Leachate Sampling Methods One aqueous sample was collected from the leachate underground holding tank, designated as LT-01. Historically leachate was collected from a lined storage basin. On August 12, 2011, a leachate underground holding tank was installed and connected to the leachate collection piping associated with the closed MSW landfill cell. Shortly thereafter, the lined leachate basin was closed. Sample LT-01 was collected on October 20, 2015 from one of the tank’s fill ports using a new disposable polyethylene bailer. One round of field parameters (as described above) was measured and recorded for sample LT-01 (see Appendix A). Leachate Fall 2015 Semiannual Water Quality Monitoring Report February 16, 2016 Permit No. 58-03, Madison County, North Carolina Page 3 P:\Madison County\Reports\2015\Fall\5803-Operating\FINAL 5803Oct2015 Semiannual Water Quality Report.doc collected in the holding tank at the site is trucked, as needed, to the Metropolitan Sewerage District (MSD) treatment facility for the town of Marshall, North Carolina. 1.4 Sample Handling, Documentation, and Analysis Field parameters for groundwater and surface water were measured and the results are provided on the sampling logs provided in Appendix A. Following sample collection, each sample was immediately placed on ice in a sample cooler for transport to TestAmerica Laboratories, Inc. (TestAmerica), a North Carolina certified laboratory located in Nashville, Tennessee. Altamont submitted the groundwater, surface water, and leachate samples for the required analyses summarized in Table 2. Proper chain-of-custody documentation procedures were followed during collection and transport of each sample. Two trip blanks provided by the laboratory, each stored in a separate sample cooler, were analyzed for Appendix I volatile organic compounds (VOCs). The reports of laboratory analysis and chain-of-custody documentation are provided in Appendix B. Fall 2015 Semiannual Water Quality Monitoring Report February 16, 2016 Permit No. 58-03, Madison County, North Carolina Page 4 P:\Madison County\Reports\2015\Fall\5803-Operating\FINAL 5803Oct2015 Semiannual Water Quality Report.doc 2.0 Findings 2.1 Analytical Results The field parameter data and laboratory analytical results for groundwater, surface water, the leachate sample collected at the Operating Landfill and the trip blanks are included in Appendices A and B, respectively (in hard copy) and also in Appendix C in the Electronic Data Deliverable (EDD) format specified by the DEQ Solid Waste Section (SWS) of the DWM (most recently updated on May 5, 2010). As stipulated in the DWM documents referenced above, non-detections were reported at the laboratory- specific method detection limit (MDL), and all concentrations exceeding the MDL were reported and appropriately qualified (Tables 3, 4, 5, and 6). The MDL is the minimum concentration of a substance that can be measured and reported by a laboratory with 99 percent confidence that the analyte concentration is greater than zero. The laboratory’s method reporting limit (MRL) is the minimum concentration of a target analyte that can be accurately determined by the referenced method. MRL is listed as the “Report Limit” (RL) column in the TestAmerica report of laboratory analysis (Appendix B). All detections were compared to analyte-specific Solid Waste Section Limits (SWSLs) established by the SWS. The SWSL is the lowest concentration, determined by the SWS, of an analyte in a sample that can be quantitatively determined with suitable precision and accuracy. If the reported concentration is greater than the laboratory MRL and less than the SWSL, the analytical result is qualified as estimated, and is flagged with a “J” qualifier (italicized J- flag) by Altamont per the DENR requirement. A “J” qualifier (non-italicized) is assigned by the laboratory and is used for parameters detected at estimated concentrations greater than the MDL but less than the MRL. Detected concentrations of constituents below the applicable SWSLs are not discussed in the text of this report, unless they exceed their applicable North Carolina water quality standard. Detected concentrations of analytes in groundwater samples were compared to the values specified by 15A NCAC 2L.0202 groundwater quality standards (2L standard). Detected concentrations of analytes in groundwater with no established 2L standards were compared to an updated list of the interim maximum allowable concentrations (IMACs) for Class GA and GSA groundwater (in accordance with 15A NCAC 02L .0202 [c]). Detections of analytes in surface water samples were compared to the standard from the 15A NCAC 2B.0200 surface water quality standards (2B standard) established for class C waters. Table 3 presents the summary of detected compounds only. Table 4 presents the summary of detected compounds for the leachate sample. Table 5 presents the concentrations of analytes that were above the applicable SWSLs. Table 6 presents the concentrations of analytes detected in the groundwater and/or surface water samples that exceeded their respective 2L standard, IMAC, or 2B standard. In the EDD (Appendix C), the identification of a well (“WELL ID”) consists of the name of the well prefaced by the un-hyphenated permit number for the facility. For example, monitoring well MW-01 is identified on the EDD as 5803-MW01. In the tables, figures, and text of this report, however, the identification of a well consists only of the name of the well (MW-01) and does not include the permit number for the facility. 2.1.1 GGroundwater Monitoring Wells The following sections summarize the results of laboratory and field parameter analyses of groundwater samples. 2.1.1.1Appendix I Metals Nine metals were detected above their respective MDLs in the samples collected from one or more of the monitoring wells (Table 3). Five metals (barium, cadmium, cobalt, selenium, and zinc) were detected above their SWSLs in one or more of the samples collected from the monitoring wells (Table 5). Cadmium was detected above the applicable 2L standard in the sample collected from monitoring well MW-07R. Cobalt Fall 2015 Semiannual Water Quality Monitoring Report February 16, 2016 Permit No. 58-03, Madison County, North Carolina Page 5 P:\Madison County\Reports\2015\Fall\5803-Operating\FINAL 5803Oct2015 Semiannual Water Quality Report.doc was detected above the applicable IMAC standard in the samples collected from monitoring wells MW-02, MW-03, MW-05, and MW-07R (Table 6). Vanadium was detected above the applicable IMAC standard in the samples collected from all nine monitoring wells (Table 6). As noted on Table 6, the metals that were detected could be naturally occurring. 2.1.1.2Appendix I VOCs One VOC (xylenes (total)) was detected in MW-03, MW-04, and MW-05, all under the respective SWSL. Acetone and methylene chloride were detected in the trip blanks, but were not detected in any of the groundwater samples. 2.1.1.3Field Parameters Field parameters were recorded during sampling activities on October 20 and 21, 2015. Measured pH values for all samples collected from monitoring wells were slightly below the 2L standard pH range of 6.5 to 8.5 Standard Units (SU) (Tables 3 and 6). 2.1.2 SSurface Water The following sections summarize the results of laboratory and field parameter analyses of surface water samples SW-01 and SW-02R. 2.1.2.1Appendix I Metals Seven metals were detected in SW-01. Three metals were detected in SW-02R. With the exception of barium, cadmium, cobalt, and zinc in SW-01, all concentrations of detected metals in both surface water samples were below their respective SWSLs (Tables 3 and 5). Only cobalt was detected above its applicable 2B standard in SW-01 (Tables 3 and 6). 2.1.2.2Appendix I VOCs No VOCs were detected in either of the surface water samples. 2.1.2.3Field Parameters The pH values recorded for both samples were within the 2B standard pH range of 6.0 to 9.0 SU (Table 3). In the SW-01 sample, dissolved oxygen was below the minimum allowable standard of 5.0 milligrams per liter (Tables 3 and 6). 2.1.3 LLeachate Analytical results for the leachate sample (LT-01) collected from the leachate underground holding tank are summarized in Table 4 and discussed below. 2.1.3.1 Appendix I Metals Eleven metals were detected in the sample collected from the leachate storage tank (Table 4). Ten metals (barium, beryllium, cadmium, chromium, cobalt, copper, nickel, silver, vanadium, and zinc) were detected above their associated SWSLs (Table 5). 2.1.3.2Appendix I VOCs Fall 2015 Semiannual Water Quality Monitoring Report February 16, 2016 Permit No. 58-03, Madison County, North Carolina Page 6 P:\Madison County\Reports\2015\Fall\5803-Operating\FINAL 5803Oct2015 Semiannual Water Quality Report.doc Acetone and trichlorofluoromethane were detected in the leachate sample (Table 4). No VOCs were detected at or above applicable SWSLs or 2L standards. Acetone and methylene chloride were detected in the trip blank associated with LT-01. 2.1.3.3Inorganics The leachate sample (LT-01) was also analyzed for biological oxygen demand (BOD), chemical oxygen demand (COD), nitrogen/nitrate, phosphorus, and sulfate. The analytical results for detected parameters are summarized in Table 4. Only nitrogen/nitrate was detected at a concentration in excess of the SWSL (Tables 4 and 5). 2.1.3.4Field Parameters Field parameters were measured and recorded for the leachate sample on October 20, 2015. Dissolved oxygen, pH, and turbidity results are summarized in Table 4. No standards exist for leachate; therefore, the recorded results are not evaluated. Fall 2015 Semiannual Water Quality Monitoring Report February 16, 2016 Permit No. 58-03, Madison County, North Carolina Page 7 P:\Madison County\Reports\2015\Fall\5803-Operating\FINAL 5803Oct2015 Semiannual Water Quality Report.doc 3.0 Hydrogeology The predominant groundwater flow direction within the regolith overlying the bedrock at the Operating Landfill appears to be west-northwest, toward an unnamed tributary of Walnut Creek. Figure 3 depicts the generalized groundwater flow direction based on groundwater measurements taken by Altamont on October 20 and 21, 2015. Water level data are summarized on Table 1. Fall 2015 Semiannual Water Quality Monitoring Report February 16, 2016 Permit No. 58-03, Madison County, North Carolina Page 8 P:\Madison County\Reports\2015\Fall\5803-Operating\FINAL 5803Oct2015 Semiannual Water Quality Report.doc 4.0 Summary Altamont completed the second semiannual water quality monitoring event of 2015 at the Madison County Operating Solid Waste Landfill on October 20 and 21, 2015. Tables 3, 4, 5, and 6 of this report, sampling logs in Appendix A, the TestAmerica Analytical Report in Appendix B, and the EDD in Appendix C provide detailed analytical results and field data used to interpret groundwater and surface water quality at the Operating Landfill. 4.1 Future Activities Altamont has discussed the exceedances of applicable water quality standards with Madison County. Altamont will continue to measure field parameters and collect water quality samples from groundwater, surface water, and leachate monitoring points associated with the Operating Landfill. Water quality samples will be submitted to a North Carolina certified laboratory for analysis for Appendix I metals and VOCs on a semiannual basis. The next sampling event is scheduled for April 2016. Fall 2015 Semiannual Water Quality Monitoring Report February 16, 2016 Permit No. 58-03, Madison County, North Carolina Page 9 P:\Madison County\Reports\2015\Fall\5803-Operating\FINAL 5803Oct2015 Semiannual Water Quality Report.doc 5.0 References DENR DWM Solid Waste Section (SWS). October 27, 2006. New Guidelines for Electronic Submittal of Environmental Monitoring Data. DENR DWM SWS, February 23, 2007. Addendum to October 27, 2006, NC SWS Memorandum Regarding New Guidelines for Electronic Submittal of Environmental Data. Puls, R.W., and M. J. Barcelona. 1996. Low-Flow (Minimal Drawdown) Ground-Water Sampling Procedures, U.S. Environmental Protection Agency, OSWER, EPA/540/S-95/504.  FFIGURES Site Location Copyright:© 2013 National Geographic Society, i-cubed        ¦    1        Landfill Parcel Boundary    #0 #0 !U !U !U !U !U!U !U !U !U       MW-01 SW-02R MW-08 MW-07R MW-02 MW-03 MW-04 MW-05 MW-09 SW-01 MW-06R                                  ¦                      !U #0      #0 #0 !U !U !U !U !U!U !U !U !U                                          MW-01(1,853.41) MW-08(1,879.30) MW-07R(1,889.75) MW-05(1,924.16) MW-09(1,941.66) MW-06R(1,932.82) MW-04(1,907.58) MW-03(1,909.32)MW-02(1,894.18)          SW-01 SW-02R 3 ¦                     !U #0          TTABLES Table 1 Well Construction Details and Corresponding Elevations Madison County Operating Solid Waste Facility, Madison County, North Carolina Depth to Water (from TOC) 58-03 MW-01 1,859.04 1,857.04 5.63 1,853.41 7 1,850.0 2 to 17 1,855.04 58-03 MW-02 1,898.94 1,895.94 4.76 1,894.18 6 1,889.9 1 to 16 1,892.94 58-03 MW-03 1,932.96 1,929.46 23.64 1,909.32 NA NA 15.5 to 25.5 1,913.96 58-03 MW-04 1,935.64 1,932.04 28.06 1,907.58 35.2 1,896.8 70.7 to 80.7 1,861.34 58-03 MW-05 1,972.76 1,969.26 48.60 1,924.16 NA NA 46.5 to 61.5 1,922.76 58-03 MW-06 2,082.87 2,081.87 NA NA 28 2,053.9 80 to 100 2,001.87 58-03 MW-06R 1,942.19 1,942.19 9.37 1,932.82 NA NA 10 to 25 1,932.19 58-03 MW-07R 1,919.34 1,916.64 29.59 1,889.75 NA NA 26 to 41 1,890.64 58-03 MW-08 1,899.92 1,896.92 20.62 1,879.30 NA NA 16 to 26 1,880.92 58-03 MW-09 1,949.43 1,946.43 7.77 1,941.66 NA NA 12.4 to 22.4 1,934.03 Notes: 1. Elevations are in feet, based on the NAVD 88 datum. 2. "TOC" means top of casing; "NA" means Not Applicable. 3. "Depth to Bedrock" and "Screened Interval" depths are measured in feet below ground surface. 4. For MW-01, MW-02, MW-05, and MW-06, TOC elevations are based on the report, Transition Plan Application (Law Engineering, April 1994). "Depth to Bedrock" and "Screened Interval" data were taken from boring logs completed on September 26, 27, 28, and 29, 1992 by Metro Drill, Inc. and April 12, 1995 by Engineering Tectonics. 5. MW-03 and MW-04 were installed during closure of MSW cell. TOC elevations are from the survey performed on December 14, 2006 by McGill Associates staff (J. Dallas Gordon, PLS). Ground survey data is included on the Closure Plan drawing generated by McGill Associates on January 4, 2007. Adjusted "Depth to Bedrock" and "Screened Interval" elevations were calculated using original data from September 1992 boring logs and new data from the December 14, 2006 survey. 6. For MW-07R and MW-08, TOC elevations were taken from survey data included on boring logs completed by Bunnell-Lammons Engineering, Inc. on July 28, 29, and 30, 2003. 7. For MW-09, TOC elevation was taken from survey data included on boring log completed by Bunnell-Lammons Engineering, Inc. on October 13, 2006. 8. Monitoring of background well MW-06 was terminated in Fall 2008 because the well was dry. MW-06R was installed on September 27, 2008 to replace MW-06. Survey data for MW-06R are based on a survey conducted on April 16, 2009 by Wes Cole Land Surveying, PA. 9. Ground elevations were calculated based on TOC elevations and field measurements. 10. Depth to water measurements were obtained in the field on October 20 and 21, 2015. MW-06 was gauged and recorded if water was present, but not sampled. Screened Interval Top of Screen Elevation Facility Permit Well ID TOC Elevation Groundwater Elevation Depth to Bedrock Top of Bedrock Elevation Ground Elevation P:\Madison County\Reports\2015\Fall\5803-Operating\5803_Oct2015 T1-Well Construction Details Page 1 of 1 Table 2 Summary of Laboratory Analyses Performed on Samples Madison County Operating Solid Waste Facility, Madison County, North Carolina Groundwater Samples Surface Water Samples Metals VOCs Metals VOCs EPA 6010C EPA 6020A EPA 7470A EPA 8260B EPA 6010C EPA 6020A EPA 7470A EPA 8260B MW-01 10/20/2015 X X SW-01 10/20/2015 X X MW-02 10/20/2015 X X SW-02R 10/20/2015 X X MW-03 10/21/2015 X X MW-04 10/21/2015 X X Quality Control Sample MW-05 10/21/2015 X X VOCs MW-06R 10/20/2015 X X EPA 8260B MW-07R 10/20/2015 X X TRIP BLANK 10/20/2015 X MW-08 10/20/2015 X X TRIP BLANK 10/21/2015 X MW-09 10/21/2015 X X TRIP BLANK (LT-01)10/20/2015 X Leachate Sample ` Metals VOCs Biochemical Oxygen Demand (BOD) Chemical Oxygen Demand (COD) Nitrate as N Total Phosphorus Sulfate EPA 6010C EPA 6020A EPA 7470A EPA 8260B SM 5210B SM 5220D Nitrate by calc EPA 365.4 EPA 300.0 LT-01 10/20/2015 X X X X X X X 1. Metals analyses include Appendix I metals per 40 CFR Part 258 "Appendix I Constituents for Detection Monitoring" and mercury. 3. VOCs analyses include Appendix I constituents per 40 CFR Part 258 and tetrahydrofuran. 4. Leachate sample (LT-1) was collected from the leachate underground holding tank. Notes: 2. VOCs = volatile organic compounds. Sample Name Collect Date Sample Name Collect Date Sample Name Collect Date Sample Name Collect Date P:\Madison County\Reports\2015\Fall\5803-Operating\5803Oct_2015 Tables Page 1 of 1 Table 3 Groundwater and Surface Water Summary of Detected Compounds Madison County Operating Solid Waste Facility, Madison County, North Carolina Metals VOCs Field Parameters Lab Certification 387 387 5445 (pH only) Lab Method EPA 6010C, 6020A EPA 8260B Parameter Barium Cadmium Chromium Cobalt Lead Nickel Selenium Vanadium Zinc Acetone Methylene Chloride Xylene (total) Dissolved Oxygen pH Turbidity CAS Number 7440-39-3 7440-43-9 7440-47-3 7440-48-4 7439-92-1 7440-02-0 7782-49-2 7440-62-2 7440-66-6 67-64-1 75-09-2 1330-20-7 7782-44-7 SW320 SW330 SWS ID 15 34 51 53 131 152 183 209 213 3 140 346 356 320 330 Units µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/L SU NTU Sample Name Collect Date Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result MW-01 10/20/2015 97.9 J 0.500 U 3.00 U 0.500 U 2.00 U 3.00 U 5.00 U 2.66 J 10.0 U 2.66 U 0.220 U 0.580 U 1.50 5.61 6.68 MW-02 10/20/2015 94.3 J 0.500 U 3.00 U 4.53 J 2.00 U 3.00 U 5.00 U 8.07 J 10.0 U 2.66 U 0.220 U 0.580 U 0.58 6.00 42.15 MW-03 10/21/2015 188 0.500 U 3.00 U 77.9 10.0 U 3.00 U 11.1 1.76 J 10.0 U 2.66 U 0.220 U 1.03 J 5.57 6.10 4.78 MW-04 10/21/2015 151 0.500 U 3.00 U 0.500 U 2.20 J 3.00 U 5.00 U 6.34 J 10.0 U 2.66 U 0.220 U 1.09 J 5.00 6.39 3.55 MW-05 10/21/2015 134 0.500 U 3.00 U 1.25 J 2.30 J 7.60 J 5.20 J 6.65 J 10.0 U 2.66 U 0.220 U 1.25 J 1.16 5.93 7.29 MW-06R 10/20/2015 29.0 J 0.500 U 3.00 U 0.500 U 2.00 U 3 .00 U 5.00 U 3.09 J 10.0 U 2.66 U 0.220 U 0.580 U 5.11 6.30 0.86 MW-07R 10/20/2015 210 3.30 5.90 J 3.42 J 2.00 U 5.50 J 5.00 U 10.5 J 11.9 J 2.66 U 0.220 U 0.580 U 7.60 5.88 126.2 MW-08 10/20/2015 31.7 J 0.500 U 3.00 U 0.500 U 2.00 U 3.00 U 5.00 U 5.37 J 10.0 U 2.66 U 0.220 U 0.580 U 5.19 6.31 0.00 MW-09 10/21/2015 143 0.500 U 3.00 U 0.500 U 2.00 U 3.00 U 5.00 U 3.87 J 10.0 U 2.66 U 0.220 U 0.580 U 1.48 6.37 0.11 SW-01 10/20/2015 149 1.70 3.10 J 17.3 3.80 J 3.00 U 5.00 U 11.9 J 12.2 J 2.66 U 0.220 U 0.580 U 2.65 6.10 49.11 SW-02R 10/20/2015 48.4 J 0.500 U 3.00 U 0.500 U 2.00 J 3.00 U 5.00 U 3.08 J 10.0 U 2.66 U 0.220 U 0.580 U 12.09 7.30 1.55 TRIPBLANK (1)10/20/2015 NA NA NA NA NA NA NA NA NA 6.06 J 1.14 J 0.580 U NA NA NA TRIPBLANK (2)10/21/2015 NA NA NA NA NA NA NA NA NA 6.38 J 1.26 J 0.580 U NA NA NA MDL 5.00 0.500 3.00 0.500 2.00/10.0 3.00 5.00 0.100 10.0 2.66 0.220 0.580 NA NA NA MRL 10.0 1.0 5.0 2.0 5.0/25.0 10.0 10.0 2.0 25.0 25.0 5.0 3.0 NA NA NA SWSL 100 1 10 10 10 50 10 25 10 100 1 5 NE NE NE 2L 700 2 10 NE 15 100 20 NE 1,000 6,000 5 500 NE 6.5-8.5 NE IMAC NE NE NE 1 NE NE NE 0.3 NE NE NE NE NE NE NE GWPS NE NE NE 1 NE NE NE 0.3 NE NE NE NE NE NE NE 2B 1,000 2 50 3 25 88 5 NE 50 2,000 590 400 > 5.0 6.0-9.0 50 Notes: 1.Only detected constituents are listed on this table. Please refer to TestAmerica Laboratories, Inc. Report of Laboratory Analysis for further details. 2."Lab Method" is the analytical method used to analyze the constituents. 3."CAS Number" is a unique number assigned by the Chemical Abstracts Service (CAS) to all identified parameters. 4."SWS ID" is the Solid Waste Section Identification Number. 5."Units" are micrograms per liter (µg/L) for analytical results, milligrams per liter (mg/L) for dissolved oxygen, Standard Units (SU) for pH, and nephelometric turbidity units (NTU) for turbidity. 6."Collect Date" is the date on which the sample was collected in the field. 7."Result" is analytical data reported by the laboratory or field data collected by Altamont. 8."MDL" is the method detection limit, which is the minimum concentration of a substance that can be measured and reported with 99% confidence that the analyte concentration is greater than zero. 9."MRL" is the method reporting limit, which is the minimum concentration of a target analyte that can be accurately determined by the referenced method. MRL equals report limit (RL) values in the TestAmerica Reports of Laboratory Analysis. 10."SWSL" is the Solid Waste Section Limit. This limit (identified by DENR) is the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy. 11."U" is a laboratory data qualifier used for parameters not detected at concentrations above MDL. 12."J" is a laboratory data qualifier used for parameters detected at estimated concentrations above MDL but below MRL and SWSL. An italicized "J" qualifier is assigned by Altamont to reflect a detected concentration that is greater than MRL and MDL but less than the SWSL. 13."2L" and "IMAC" (Interim Maximum Allowable Concentration) are groundwater standards from "North Carolina Administrative Code, Title 15A: Department of Environment and Natural Resources, Subchapter 2L - Groundwater Classifications and Standards," DENR (Amended April 1, 2013). 14."GWPS" is the Groundwater Protection Standard pursuant to "15A NCAC 13B .1634," DENR. Current standards were obtained from http://portal.ncdenr.org/web/sw/envmonitoringlist (last updated June 13, 2011). 15."2B" indicates surface water standard per "North Carolina Administrative Code, Title 15A: Department of Environment and Natural Resources, Subchapter 2B - Surface Water and Wetland Standards," (last amended on May 1, 2007). For compounds with no 2B standard established, the NC and Environmental Protection Agency (EPA) National Criteria Table (Current as of May 15, 2013) was used for the most stringent of fresh water and human health. 16."NE" means Not Established. "NA" means Not Applicable. 17.Bold numbers indicate a detection. Shaded cells indicate result in exceedance of the 2L or IMAC or 2B (surface water) standards, or greater than or equal to the GWPS (if no 2L or IMAC exist). P:\Madison County\Reports\2015\Fall\5803-Operating\5803Oct_2015 Tables Page 1 of 1 Table 4 Leachate Summary of Detected Compounds Madison County Operating Solid Waste Facility, Madison County, North Carolina Metals VOCs General Chemistry Field Parameters Lab Certification 387 387 387 5445 (pH only) Lab Method EPA 6010C & 6020A EPA 8260B SM 5220D Nitrate by calc EPA 365.1 EPA 300.0 Parameter Barium Beryllium Cadmium Chromium Cobalt Copper Mercury Nickel Silver Vanadium Zinc Acetone Methylene Chloride Trichloro- fluoro- methane COD Nitrate as N Total Phosphorus Sulfate Dissolved Oxygen pH Turbidity CAS Number 7440-39-3 7440-41-7 7440-43-9 7440-47-3 7440-48-4 7440-50-8 7439-97-6 7440-02-0 7440-22-4 7440-62-2 7440-66-6 67-64-1 75-09-2 75-69-4 SW317 SW419 7723-14-0 14808-79-8 7782-44-7 SW320 SW330 SWS ID 15 23 34 51 53 54 132 152 184 209 213 3 140 203 317 419 412 315 356 320 330 Units µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/L SU NTU Sample Name Collect Date Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result LT-01 10/20/2015 17,400 31.2 J 62.5 409 2,010 41.5 J 0.118 J 439 22.0 J 158 19,800 5.46 J 0.22 U 0.512 J 356,000 20,400 1,240 105,000 J 6.65 7.96 955.2 TRIPBLANK (LT-01)10/20/2015 NA NA NA NA NA NA NA NA NA NA NA 3.20 J 1.41 J NA NA NA NA NA NA NA NA MDL 25.0 25.0 2.50 15.0 25.0 25.0 0.100 15.0 15.0 5.00 500.0 2.66 0.22 0.210 40,000 40.0 50.0 600 NA NA NA MRL 50.0 100 5.0 25.0 100 50.0 0.20 50.0 25.0 100 1250 25.0 5.0 1.00 200,000 100 100.0 1,000 NA NA NA SWSL 100 1 1 10 10 10 0.2 50 10 25 10 100 1 1 NE 10,000 NE 250,000 NE NE NE Notes: 1.Only detected constituents are listed on this table. Please refer to the TestAmerica Report of Laboratory Analysis for further details. 2."Lab Method" is the analytical method used to analyze the constituents. 3."CAS Number" is a unique number assigned by the Chemical Abstracts Service (CAS) to all identified parameters. 4."SWS ID" is the Solid Waste Section Identification Number. 5."Units" are micrograms per liter (µg/L) for analytical results, milligrams per liter (mg/L) for dissolved oxygen, Standard Units (SU) for pH, and nephelometric turbidity units (NTU) for turbidity. 6."Collect Date" is the date on which the sample was collected in the field. 7."Result" is analytical data reported by the laboratory or field data collected by Altamont. 8."MDL" is the method detection limit, which is the minimum concentration of a substance that can be measured and reported with 99% confidence that the analyte concentration is greater than zero. 9."MRL" is the method reporting limit, which is the minimum concentration of a target analyte that can be accurately determined by the referenced method. MRL equals report limit (RL) values in the TestAmerica Analytical Reports. 10."SWSL" is the Solid Waste Section Limit. This limit (identified by DENR) is the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy. 11."U" is a laboratory data qualifier used for parameters not detected at concentrations above MDL. 12."J" is a laboratory data qualifier used for parameters detected at estimated concentrations above MDL but below MRL and SWSL. An italicized "J" qualifier is assigned by Altamont to reflect a detected concentration that is greater than MRL and MDL but less than the SWSL. 13.VOCs indicates volatile organic compounds. COD means chemical oxygen demand. 14."NE" means Not Established. P:\Madison County\Reports\2015\Fall\5803-Operating\5803Oct_2015 Tables Page 1 of 1 Table 5 Groundwater and Surface Water Solid Waste Section Limits Exceedances Notification Madison County Operating Solid Waste Facility, Madison County, North Carolina FACILITY PERMIT WELL ID CAS NUMBER SWS ID PARAMETER RESULT UNITS METHOD MDL MRL SWSL COLLECT DATE 58-03 MW-03 7440-39-3 15 Barium 188 µg/L EPA 6010C 5.00 10.0 100 10/21/2015 58-03 MW-03 7440-48-4 53 Cobalt 77.9 µg/L EPA 6020A 0.500 2.0 10 10/21/2015 58-03 MW-03 7782-49-2 183 Selenium 11.1 µg/L EPA 6010C 5.00 10.0 10 10/21/2015 58-03 MW-04 7440-39-3 15 Barium 151 µg/L EPA 6010C 5.00 10.0 100 10/21/2015 58-03 MW-05 7440-39-3 15 Barium 134 µg/L EPA 6010C 5.00 10.0 100 10/21/2015 58-03 MW-07R 7440-39-3 15 Barium 210 µg/L EPA 6010C 5.00 10.0 100 10/20/2015 58-03 MW-07R 7440-43-9 34 Cadmium 3.30 µg/L EPA 6010C 0.500 1.0 1.0 10/20/2015 58-03 MW-07R 7440-66-6 213 Zinc 11.9 J µg/L EPA 6010C 10.0 25.0 10 10/20/2015 58-03 MW-09 7440-39-3 15 Barium 143 µg/L EPA 6010C 5.00 10.0 100 10/21/2015 58-03 SW-01 7440-39-3 15 Barium 149 µg/L EPA 6010C 5.00 10.0 100 10/20/2015 58-03 SW-01 7440-43-9 51 Cadmium 1.70 µg/L EPA 6010C 0.500 1.00 1 10/20/2015 58-03 SW-01 7440-48-4 53 Cobalt 17.3 µg/L EPA 6020A 0.500 2.0 10 10/20/2015 58-03 SW-01 7440-66-6 213 Zinc 12.2 J µg/L EPA 6010C 10.0 25.0 10 10/20/2015 58-03 LT-01 7440-39-3 15 Barium 17,400 µg/L EPA 6010C 25.0 50.0 100 10/20/2015 58-04 LT-02 7440-41-7 23 Beryllium 31.2 J µg/L EPA 6010C 25.0 100.0 1 10/20/2015 58-03 LT-01 7440-43-9 51 Cadmium 62.5 µg/L EPA 6010C 2.50 5.00 1 10/20/2015 58-03 LT-01 7440-47-3 51 Chromium 409 µg/L EPA 6010C 15.0 25.0 10 10/20/2015 58-03 LT-01 7440-48-4 53 Cobalt 2,010 µg/L EPA 6020A 25.0 100 10 10/20/2015 58-03 LT-01 7440-50-8 54 Copper 41.5 µg/L EPA 6010C 25.0 50.0 10 10/20/2015 58-04 LT-02 7440-02-0 152 Nickel 439 µg/L EPA 6010C 15.0 50.0 50 10/20/2015 58-05 LT-03 7440-22-4 184 Silver 22.0 J µg/L EPA 6010C 15.0 25.0 10 10/20/2015 58-06 LT-04 7440-62-2 209 Vanadium 158 µg/L EPA 6010C 5.00 100.0 25 10/20/2015 58-03 LT-01 7440-66-6 213 Zinc 19,800 µg/L EPA 6010C 500 1,250 10 10/20/2015 58-03 LT-01 SW419 419 Nitrogen/Nitrate 20,400 µg/L Nitrate by calc 40.0 100 10,000 10/20/2015 Notes: 1."CAS NUMBER" is a unique number assigned by the Chemical Abstracts Service (CAS) to all identified parameters. 2."SWS ID" is the Solid Waste Section Identification Number. 3."RESULT" is the analytical data reported by the laboratory. 4."UNITS" are micrograms per liter (µg/L) for analytical results, and milligrams per liter (mg/L) for nitrogen. 5."METHOD" is the analytical method used to analyze the constituents. 6."MDL" is the method detection limit, which is the minimum concentration of a substance that can be measured and reported with 99% confidence that the analyte concentration is greater than zero. 7."MRL" is the method reporting limit, which is the minimum concentration of a target analyte that can be accurately determined by the referenced method. 8."SWSL" is the Solid Waste Section Limit. This limit (identified by DEQ) is the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy. 9."COLLECT DATE" is the date on which the sample was collected in the field. 10.Shaded cells indicate result in exceedance of the 2B standard for surface water, 2L or Interim Maximum Allowable Concentration (IMAC) standards, or greater than or equal to the Groundwater Protection Standard (GWPS [if no 2L or IMAC exist]) for groundwater. 11.2L standard and IMAC are from "North Carolina Administrative Code, Title 15A: Department of Environment and Natural Resources, Subchapter 2L-Groundwater Classifications and Standards," DENR (Amended April 1, 2013). 12.GWPS is pursuant to "15A NCAC 13B .1634," DENR. Current standards were obtained from http://portal.ncdenr.org/web/sw/envmonitoringlist (last updated June 13, 2011). 13.2B standard is per "North Carolina Administrative Code, Title 15A: Department of Environment and Natural Resources, Subchapter 2B - Surface Water and Wetland Standards" (last amended on May 1, 2007). For constituents with no 2B standard established, the NC and Environmental Protection Agency (EPA) National Criteria Table (Current as of 5/15/2013) for the most stringent of fresh water and human health was used. P:\Madison County\Reports\2015\Fall\5803-Operating\5803Oct_2015 Tables Page 1 of 1 Table 6 Groundwater and Surface Water Quality Standards Exceedances Notification Madison County Operating Solid Waste Facility, Madison County, North Carolina FACILITY PERMIT WELL ID CAS NUMBER SWS ID PARAMETER RESULT UNITS QUALIFIER METHOD MDL MRL SWSL WATER QUALITY STANDARD COLLECT DATE CAUSE AND SIGNIFICANCE GROUNDWATER SAMPLES - 2L STANDARD, IMAC OR GWPS (µg/L) 58-03 MW-01 7440-62-2 209 Vanadium 2.66 ug/L J EPA 6010C 0.100 2.0 25 0.3 10/20/2015 Possibly naturally occurring. 58-03 MW-01 SW320 320 pH 5.61 SU 5455 NA NA NE 6.5 - 8.5 10/20/2015 Consistent with historic readings. 58-03 MW-02 7440-48-4 53 Cobalt 4.53 ug/L J EPA 6020A 0.500 2.0 10 1 10/20/2015 58-03 MW-02 7440-62-2 209 Vanadium 8.07 ug/L J EPA 6010C 0.100 2.0 25 0.3 10/20/2015 58-03 MW-02 SW320 320 pH 6.00 SU 5455 NA NA NE 6.5 - 8.5 10/20/2015 Consistent with historic readings. 58-03 MW-03 7440-48-4 53 Cobalt 77.9 ug/L EPA 6020A 0.500 2.0 10 1 10/21/2015 58-03 MW-03 7440-62-2 209 Vanadium 1.76 ug/L J EPA 6010C 0.100 2.0 25 0.3 10/21/2015 Possibly naturally occurring. 58-03 MW-03 SW320 320 pH 6.10 SU 5455 NA NA NE 6.5 - 8.5 10/21/2015 Consistent with historic readings. 58-03 MW-04 7440-62-2 209 Vanadium 6.34 ug/L J EPA 6010C 0.100 2.0 25 0.3 10/21/2015 Possibly naturally occurring. 58-03 MW-04 SW320 320 pH 6.39 SU 5455 NA NA NE 6.5 - 8.5 10/21/2015 Consistent with historic readings. 58-03 MW-05 7440-48-4 53 Cobalt 1.25 ug/L J EPA 6020A 0.500 2.0 10 1 10/21/2015 Possibly naturally occurring. 58-03 MW-05 7440-62-2 209 Vanadium 6.65 ug/L J EPA 6010C 0.100 2.0 25 0.3 10/21/2015 Possibly naturally occurring. 58-03 MW-05 SW320 320 pH 5.93 SU 5455 NA NA NE 6.5 - 8.5 10/21/2015 Consistent with historic readings. 58-03 MW-06R 7440-62-2 209 Vanadium 3.09 ug/L J EPA 6010C 0.100 2.0 25 0.3 10/20/2015 Possibly naturally occurring. 58-03 MW-06R SW320 320 pH 6.30 SU 5455 NA NA NE 6.5 - 8.5 10/20/2015 Consistent with historic readings. 58-03 MW-07R 7440-43-9 34 Cadmium 3.30 ug/L EPA 6010C 0.500 1.0 1 2 10/20/2015 Possibly naturally occurring. 58-04 MW-07R 7440-48-4 53 Cobalt 3.42 ug/L J EPA 6010C 0.500 2.0 10 2 10/20/2015 Possibly naturally occurring. 58-03 MW-07R 7440-62-2 209 Vanadium 10.5 ug/L J EPA 6010C 0.100 2.0 25 0.3 10/20/2015 Possibly naturally occurring. 58-03 MW-07R SW320 320 pH 5.88 SU 5455 NA NA NE 6.5 - 8.5 10/20/2015 Consistent with historic readings. 58-03 MW-08 7440-62-2 209 Vanadium 5.37 ug/L J EPA 6010C 0.100 2.0 25 0.3 10/20/2015 Possibly naturally occurring. 58-03 MW-08 SW320 320 pH 6.31 SU 5455 NA NA NE 6.5 - 8.5 10/20/2015 Consistent with historic readings. 58-03 MW-09 7440-62-2 209 Vanadium 3.87 ug/L J EPA 6010C 0.100 2.0 25 0.3 10/21/2015 Possibly naturally occurring. 58-03 MW-09 SW320 320 pH 6.37 SU 5455 NA NA NE 6.5 - 8.5 10/21/2015 Consistent with historic readings. 58-03 SW-01 7440-48-4 53 Cobalt 17.3 µg/L EPA 6020A 0.500 2.0 10 3 10/20/2015 Very little flow at sample location. 58-03 SW-01 7782-44-7 356 Dissolved Oxygen 2.65 mg/L NA NA NE > 5.0 10/20/2015 Naturally occurring. Notes: 1."CAS NUMBER" is a unique number assigned by the Chemical Abstracts Service (CAS) to all identified parameters. 2."SWS ID" is the Solid Waste Section Identification Number. 3."RESULT" is analytical data reported by the laboratory or field data collected by Altamont. 4."UNITS" are micrograms per liter (µg/L) for analytical results, Standard Units (SU) for pH, and milligrams per liter (mg/L) for dissolved oxygen. 5."QUALIFIER" is a data qualifier or "flag". A blank cell indicates that there is no qualifier associated with the reported result. 6."METHOD" is the analytical method used to analyze the constituents. 7."MDL" is the method detection limit, which is the minimum concentration of a substance that can be measured and reported with 99% confidence that the analyte concentration is greater than zero. 8."MRL" is the method reporting limit, which is the minimum concentration of a target analyte that can be accurately determined by the referenced method. 9."SWSL" is the Solid Waste Section Limit. This limit (identified by DENR) is the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy. 10."WATER QUALITY STANDARD" refers to the 2L standard, Interim Maximum Allowable Concentration (IMAC), or Groundwater Protection Standard (GWPS) for groundwater. 11."COLLECT DATE" is the date on which the sample was collected in the field. 12."NE" means Not Established. 13."J" is a laboratory data qualifier used for parameters detected at estimated concentrations above MDL but below MRL and SWSL. An italicized "J " qualifier is assigned by Altamont to reflect a detected concentration that is greater than MRL and MDL but less than the SWSL. 14.2L standard and IMAC are from "North Carolina Administrative Code, Title 15A: Department of Environment and Natural Resources, Subchapter 2L - Groundwater Classifications and Standards," DENR (Amended April 1, 2013). 15.GWPS is pursuant to "15A NCAC 13B .1634," DENR. Current standards were obtained from http://portal.ncdenr.org/web/sw/envmonitoringlist (last updated June 13, 2011). 16.2B standard per "North Carolina Administrative Code, Title 15A: Department of Environment and Natural Resources, Subchapter 2B - Surface Water and Wetland Standards," For constituents with no 2B standard established, the NC and Environmental Protection Agency (EPA) National Criteria Table (Current as of May 15, 2013) for the most stringent of fresh water and human health was used. Possibly naturally occurring. Possibly naturally occurring. P:\Madison County\Reports\2015\Fall\5803-Operating\5803Oct_2015 Tables Page 1 of 1  AAPPENDICES  AAPPENDIX A Sampling Logs and Equipment Documentation and Instrument Calibration Data Sheets  AAPPENDIX B Report of Laboratory Analysis and Chain-of-Custody Documentation ANALYTICAL REPORT TestAmerica Laboratories, Inc. TestAmerica Nashville 2960 Foster Creighton Drive Nashville, TN 37204 Tel:(615)726-0177 TestAmerica Job ID: 490-90194-1 Client Project/Site: Madison Co Operating Landing For: Altamont Environmental, Inc. 231 Haywood Street Asheville, North Carolina 28801 Attn: Mr. Brian Gant Authorized for release by: 11/9/2015 2:14:20 PM Ken Hayes, Project Manager II (615)301-5035 ken.hayes@testamericainc.com The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited parameters, exceptions are noted in this report. This report may not be reproduced except in full, and with written approval from the laboratory. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature. Results relate only to the items tested and the sample(s) as received by the laboratory. 1 2 3 4 5 6 7 8 9 10 11 12 13 Table of Contents Client: Altamont Environmental, Inc. Project/Site: Madison Co Operating Landing TestAmerica Job ID: 490-90194-1 Page 2 of 33 TestAmerica Nashville11/9/2015 Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1 Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2 Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3 Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4 Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5 Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6 QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .16 QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .25 Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .27 Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .29 Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .30 Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .31 Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .33 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 3 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 4 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 5 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 6 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 7 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 8 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 9 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 10 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 11 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 12 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 13 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 14 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 15 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 16 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 17 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 18 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 19 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 20 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 21 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 22 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 23 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 24 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 25 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 26 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 27 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 28 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 29 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 30 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 31 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 32 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 33 of 33 11/9/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 ANALYTICAL REPORT TestAmerica Laboratories, Inc. TestAmerica Nashville 2960 Foster Creighton Drive Nashville, TN 37204 Tel:(615)726-0177 TestAmerica Job ID: 490-90102-1 Client Project/Site: Madison Co Operating Landfill For: Altamont Environmental, Inc. 231 Haywood Street Asheville, North Carolina 28801 Attn: Mr. Brian Gant Authorized for release by: 11/10/2015 5:26:10 PM Ken Hayes, Project Manager II (615)301-5035 ken.hayes@testamericainc.com The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited parameters, exceptions are noted in this report. This report may not be reproduced except in full, and with written approval from the laboratory. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature. Results relate only to the items tested and the sample(s) as received by the laboratory. 1 2 3 4 5 6 7 8 9 10 11 12 13 Table of Contents Client: Altamont Environmental, Inc. Project/Site: Madison Co Operating Landfill TestAmerica Job ID: 490-90102-1 Page 2 of 42 TestAmerica Nashville11/10/2015 Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1 Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2 Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3 Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4 Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5 Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6 QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .22 QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .32 Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .35 Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .38 Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .39 Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .40 Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .42 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 3 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 4 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 5 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 6 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 7 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 8 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 9 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 10 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 11 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 12 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 13 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 14 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 15 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 16 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 17 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 18 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 19 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 20 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 21 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 22 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 23 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 24 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 25 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 26 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 27 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 28 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 29 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 30 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 31 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 32 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 33 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 34 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 35 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 36 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 37 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 38 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 39 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 40 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 41 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 42 of 42 11/10/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 ANALYTICAL REPORT TestAmerica Laboratories, Inc. TestAmerica Nashville 2960 Foster Creighton Drive Nashville, TN 37204 Tel:(615)726-0177 TestAmerica Job ID: 490-90059-1 Client Project/Site: Madison Co Operating Landfill For: Altamont Environmental, Inc. 231 Haywood Street Asheville, North Carolina 28801 Attn: Mr. Brian Gant Authorized for release by: 11/12/2015 5:23:39 PM Ken Hayes, Project Manager II (615)301-5035 ken.hayes@testamericainc.com The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited parameters, exceptions are noted in this report. This report may not be reproduced except in full, and with written approval from the laboratory. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature. Results relate only to the items tested and the sample(s) as received by the laboratory. 1 2 3 4 5 6 7 8 9 10 11 12 13 Table of Contents Client: Altamont Environmental, Inc. Project/Site: Madison Co Operating Landfill TestAmerica Job ID: 490-90059-1 Page 2 of 31 TestAmerica Nashville11/12/2015 Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1 Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2 Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3 Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4 Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6 Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7 QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .11 QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .23 Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .26 Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .27 Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .28 Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .29 Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .31 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 3 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 4 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 5 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 6 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 7 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 8 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 9 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 10 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 11 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 12 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 13 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 14 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 15 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 16 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 17 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 18 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 19 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 20 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 21 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 22 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 23 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 24 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 25 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 26 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 27 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 28 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 29 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 30 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 31 of 31 11/12/2015 1 2 3 4 5 6 7 8 9 10 11 12 13  APPENDIX C Environmental Monitoring Reporting Form and Electronic Submittal of Environmental Data Deliverable 5803Oct2015 (Electronic only) 5803Oct2015EDD FACILITY PERMIT WELL ID CAS Number SWS ID PARAMETER RESULT UNITS QUALIFIER METHOD MDL MRL SWSL DILUTION FACTOR COLLECT DATE EXTRACTION DATE ANALYSIS DATE NC LABORATORY CERTIFICATION NUMBER 58-03 5803-MW01 630-20-6 190 1,1,1,2-Tetrachloroethane 0.150 ug/L U 8260B 0.150 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 71-55-6 200 1,1,1-Trichloroethane 0.190 ug/L U 8260B 0.190 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 79-34-5 191 1,1,2,2-Tetrachloroethane 0.190 ug/L U 8260B 0.190 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 79-00-5 202 1,1,2-Trichloroethane 0.190 ug/L U 8260B 0.190 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 75-34-3 75 1,1-Dichloroethane 0.240 ug/L U 8260B 0.240 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 75-35-4 77 1,1-Dichloroethene 0.250 ug/L U 8260B 0.250 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 96-18-4 206 1,2,3-Trichloropropane 0.230 ug/L U 8260B 0.230 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 96-12-8 67 1,2-Dibromo-3-chloropropane 0.940 ug/L U 8260B 0.940 10.0 13 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 106-93-4 68 1,2-Dibromoethane 0.210 ug/L U 8260B 0.210 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 107-06-2 76 1,2-Dichloroethane 0.200 ug/L U 8260B 0.200 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 78-87-5 82 1,2-Dichloropropane 0.250 ug/L U 8260B 0.250 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 591-78-6 124 2-Hexanone 1.28 ug/L U 8260B 1.28 10.0 50 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 108-10-1 147 4-Methyl-2-pentanone 0.810 ug/L U 8260B 0.810 10.0 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 67-64-1 3 Acetone 2.66 ug/L U 8260B 2.66 25.0 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 107-13-1 8 Acrylonitrile 0.500 ug/L U 8260B 0.500 10.0 200 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 7440-36-0 13 Antimony 0.500 ug/L U 6020A 0.500 2.00 6 1 10/20/2015 10/23/2015 11/05/2015 387 58-03 5803-MW01 7440-38-2 14 Arsenic 8.60 ug/L U 6010C 8.60 10.0 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW01 7440-39-3 15 Barium 97.9 ug/L J 6010C 5.00 10.0 100 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW01 71-43-2 16 Benzene 0.200 ug/L U 8260B 0.200 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 7440-41-7 23 Beryllium 0.500 ug/L U 6020A 0.500 2.00 1 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-MW01 74-97-5 28 Bromochloromethane 0.150 ug/L U 8260B 0.150 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 75-27-4 29 Bromodichloromethane 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 75-25-2 30 Bromoform 0.290 ug/L U 8260B 0.290 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 7440-43-9 34 Cadmium 0.500 ug/L U 6010C 0.500 1.00 1 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW01 75-15-0 35 Carbon disulfide 0.220 ug/L U 8260B 0.220 1.00 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 56-23-5 36 Carbon tetrachloride 0.180 ug/L U 8260B 0.180 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 108-90-7 39 Chlorobenzene 0.180 ug/L U 8260B 0.180 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 75-00-3 41 Chloroethane 0.360 ug/L U 8260B 0.360 1.00 10 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 67-66-3 44 Chloroform 0.230 ug/L U 8260B 0.230 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 7440-47-3 51 Chromium 3.00 ug/L U 6010C 3.00 5.00 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW01 156-59-2 78 cis-1,2-Dichloroethene 0.210 ug/L U 8260B 0.210 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 10061-01-5 86 cis-1,3-Dichloropropene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 7440-48-4 53 Cobalt 0.500 ug/L U 6020A 0.500 2.00 10 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-MW01 7440-50-8 54 Copper 5.00 ug/L U 6010C 5.00 10.0 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW01 124-48-1 66 Dibromochloromethane 0.250 ug/L U 8260B 0.250 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 100-41-4 110 Ethylbenzene 0.190 ug/L U 8260B 0.190 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 7439-92-1 131 Lead 2.00 ug/L U 6010C 2.00 5.00 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW01 7439-97-6 132 Mercury 0.100 ug/L U 7470A 0.100 0.200 0.2 1 10/20/2015 10/26/2015 10/26/2015 387 58-03 5803-MW01 74-83-9 136 Methyl bromide 0.350 ug/L U 8260B 0.350 1.00 10 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 74-87-3 137 Methyl chloride 0.360 ug/L U 8260B 0.360 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 78-93-3 141 Methyl ethyl ketone 2.64 ug/L U 8260B 2.64 50.0 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 74-88-4 142 Methyl iodide; Iodomethane 1.50 ug/L U 8260B 1.50 10.0 10 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 74-95-3 139 Methylene bromide 0.450 ug/L U 8260B 0.450 1.00 10 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 75-09-2 140 Methylene Chloride 0.220 ug/L U 8260B 0.220 5.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 7440-02-0 152 Nickel 3.00 ug/L U 6010C 3.00 10.0 50 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW01 95-50-1 69 o-Dichlorobenzene 0.190 ug/L U 8260B 0.190 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 106-46-7 71 p-Dichlorobenzene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 7782-49-2 183 Selenium 5.00 ug/L U 6010C 5.00 10.0 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW01 7440-22-4 184 Silver 3.00 ug/L U 6010C 3.00 5.00 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW01 100-42-5 186 Styrene 0.280 ug/L U 8260B 0.280 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 127-18-4 192 Tetrachloroethene 0.140 ug/L U 8260B 0.140 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 109-99-9 458 Tetrahydrofuran 0.820 ug/L U 8260B 0.820 10.0 NE 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 7440-28-0 194 Thallium 0.200 ug/L U 6020A 0.200 2.00 5.5 1 10/20/2015 10/23/2015 10/30/2015 387 P:\Madison County\Reports\2015\Fall\5803-Operating\5803_2015Oct_EDD Page 1 of 17 5803Oct2015EDD FACILITY PERMIT WELL ID CAS Number SWS ID PARAMETER RESULT UNITS QUALIFIER METHOD MDL MRL SWSL DILUTION FACTOR COLLECT DATE EXTRACTION DATE ANALYSIS DATE NC LABORATORY CERTIFICATION NUMBER 58-03 5803-MW01 108-88-3 196 Toluene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 156-60-5 79 trans-1,2-Dichloroethene 0.230 ug/L U 8260B 0.230 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 10061-02-6 87 trans-1,3-Dichloropropene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 110-57-6 73 trans-1,4-Dichloro-2-butene 0.460 ug/L U 8260B 0.460 5.00 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 79-01-6 201 Trichloroethene 0.200 ug/L U 8260B 0.200 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 75-69-4 203 Trichlorofluoromethane 0.210 ug/L U 8260B 0.210 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 7440-62-2 209 Vanadium 2.66 ug/L J 6020A 0.100 2.00 25 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-MW01 108-05-4 210 Vinyl acetate 1.71 ug/L U 8260B 1.71 10.0 50 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 75-01-4 211 Vinyl chloride 0.180 ug/L U 8260B 0.180 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 1330-20-7 346 Xylene (total)0.580 ug/L U 8260B 0.580 3.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW01 7440-66-6 213 Zinc 10.0 ug/L U 6020A 10.0 25.0 10 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-MW01 7782-44-7 356 Dissolved Oxygen 1.50 mg/L 10/20/2015 58-03 5803-MW01 SW336 336 Oxygen Reduction Potential 241.0 mV 10/20/2015 58-03 5803-MW01 SW320 320 pH 5.61 SU 10/20/2015 5445 58-03 5803-MW01 SW323 323 Specific Conductivity 54 µS 10/20/2015 58-03 5803-MW01 SW325 325 Temperature 14.93 °C 10/20/2015 58-03 5803-MW01 SW330 330 Turbidity 6.68 NTU 10/20/2015 58-03 5803-MW01 SW318 318 Depth to Water 5.63 ft TOC 10/20/2015 58-03 5803-MW01 SW411 411 Total Well Depth 19.50 ft TOC 10/20/2015 58-03 5803-MW01 SW328 328 Top of Casing (TOC) Elevation 1,859.04 feet 58-03 5803-MW02 630-20-6 190 1,1,1,2-Tetrachloroethane 0.150 ug/L U 8260B 0.150 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 71-55-6 200 1,1,1-Trichloroethane 0.190 ug/L U 8260B 0.190 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 79-34-5 191 1,1,2,2-Tetrachloroethane 0.190 ug/L U 8260B 0.190 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 79-00-5 202 1,1,2-Trichloroethane 0.190 ug/L U 8260B 0.190 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 75-34-3 75 1,1-Dichloroethane 0.240 ug/L U 8260B 0.240 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 75-35-4 77 1,1-Dichloroethene 0.250 ug/L U 8260B 0.250 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 96-18-4 206 1,2,3-Trichloropropane 0.230 ug/L U 8260B 0.230 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 96-12-8 67 1,2-Dibromo-3-chloropropane 0.940 ug/L U 8260B 0.940 10.0 13 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 106-93-4 68 1,2-Dibromoethane 0.210 ug/L U 8260B 0.210 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 107-06-2 76 1,2-Dichloroethane 0.200 ug/L U 8260B 0.200 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 78-87-5 82 1,2-Dichloropropane 0.250 ug/L U 8260B 0.250 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 591-78-6 124 2-Hexanone 1.28 ug/L U 8260B 1.28 10.0 50 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 108-10-1 147 4-Methyl-2-pentanone 0.810 ug/L U 8260B 0.810 10.0 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 67-64-1 3 Acetone 2.66 ug/L U 8260B 2.66 25.0 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 107-13-1 8 Acrylonitrile 0.500 ug/L U 8260B 0.500 10.0 200 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 7440-36-0 13 Antimony 0.500 ug/L U 6020A 0.500 2.00 6 1 10/20/2015 10/23/2015 11/05/2015 387 58-03 5803-MW02 7440-38-2 14 Arsenic 8.60 ug/L U 6010C 8.60 10.0 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW02 7440-39-3 15 Barium 94.3 ug/L J 6010C 5.00 10.0 100 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW02 71-43-2 16 Benzene 0.200 ug/L U 8260B 0.200 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 7440-41-7 23 Beryllium 0.500 ug/L U 6020A 0.500 2.00 1 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-MW02 74-97-5 28 Bromochloromethane 0.150 ug/L U 8260B 0.150 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 75-27-4 29 Bromodichloromethane 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 75-25-2 30 Bromoform 0.290 ug/L U 8260B 0.290 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 7440-43-9 34 Cadmium 0.500 ug/L U 6010C 0.500 1.00 1 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW02 75-15-0 35 Carbon disulfide 0.220 ug/L U 8260B 0.220 1.00 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 56-23-5 36 Carbon tetrachloride 0.180 ug/L U 8260B 0.180 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 108-90-7 39 Chlorobenzene 0.180 ug/L U 8260B 0.180 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 75-00-3 41 Chloroethane 0.360 ug/L U 8260B 0.360 1.00 10 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 67-66-3 44 Chloroform 0.230 ug/L U 8260B 0.230 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 7440-47-3 51 Chromium 3.00 ug/L U 6010C 3.00 5.00 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW02 156-59-2 78 cis-1,2-Dichloroethene 0.210 ug/L U 8260B 0.210 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 10061-01-5 86 cis-1,3-Dichloropropene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 7440-48-4 53 Cobalt 4.53 ug/L J 6020A 0.500 2.00 10 1 10/20/2015 10/23/2015 10/30/2015 387 P:\Madison County\Reports\2015\Fall\5803-Operating\5803_2015Oct_EDD Page 2 of 17 5803Oct2015EDD FACILITY PERMIT WELL ID CAS Number SWS ID PARAMETER RESULT UNITS QUALIFIER METHOD MDL MRL SWSL DILUTION FACTOR COLLECT DATE EXTRACTION DATE ANALYSIS DATE NC LABORATORY CERTIFICATION NUMBER 58-03 5803-MW02 7440-50-8 54 Copper 5.00 ug/L U 6010C 5.00 10.0 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW02 124-48-1 66 Dibromochloromethane 0.250 ug/L U 8260B 0.250 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 100-41-4 110 Ethylbenzene 0.190 ug/L U 8260B 0.190 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 7439-92-1 131 Lead 2.00 ug/L U 6010C 2.00 5.00 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW02 7439-97-6 132 Mercury 0.100 ug/L U 7470A 0.100 0.200 0.2 1 10/20/2015 10/26/2015 10/27/2015 387 58-03 5803-MW02 74-83-9 136 Methyl bromide 0.350 ug/L U 8260B 0.350 1.00 10 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 74-87-3 137 Methyl chloride 0.360 ug/L U 8260B 0.360 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 78-93-3 141 Methyl ethyl ketone 2.64 ug/L U 8260B 2.64 50.0 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 74-88-4 142 Methyl iodide; Iodomethane 1.50 ug/L U 8260B 1.50 10.0 10 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 74-95-3 139 Methylene bromide 0.450 ug/L U 8260B 0.450 1.00 10 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 75-09-2 140 Methylene Chloride 0.220 ug/L U 8260B 0.220 5.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 7440-02-0 152 Nickel 3.00 ug/L U 6010C 3.00 10.0 50 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW02 95-50-1 69 o-Dichlorobenzene 0.190 ug/L U 8260B 0.190 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 106-46-7 71 p-Dichlorobenzene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 7782-49-2 183 Selenium 5.00 ug/L U 6010C 5.00 10.0 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW02 7440-22-4 184 Silver 3.00 ug/L U 6010C 3.00 5.00 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW02 100-42-5 186 Styrene 0.280 ug/L U 8260B 0.280 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 127-18-4 192 Tetrachloroethene 0.140 ug/L U 8260B 0.140 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 109-99-9 458 Tetrahydrofuran 0.820 ug/L U 8260B 0.820 10.0 NE 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 7440-28-0 194 Thallium 0.200 ug/L U 6020A 0.200 2.00 5.5 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-MW02 108-88-3 196 Toluene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 156-60-5 79 trans-1,2-Dichloroethene 0.230 ug/L U 8260B 0.230 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 10061-02-6 87 trans-1,3-Dichloropropene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 110-57-6 73 trans-1,4-Dichloro-2-butene 0.460 ug/L U 8260B 0.460 5.00 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 79-01-6 201 Trichloroethene 0.200 ug/L U 8260B 0.200 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 75-69-4 203 Trichlorofluoromethane 0.210 ug/L U 8260B 0.210 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 7440-62-2 209 Vanadium 8.07 ug/L J 6020A 0.100 2.00 25 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-MW02 108-05-4 210 Vinyl acetate 1.71 ug/L U 8260B 1.71 10.0 50 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 75-01-4 211 Vinyl chloride 0.180 ug/L U 8260B 0.180 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 1330-20-7 346 Xylene (total)0.580 ug/L U 8260B 0.580 3.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW02 7440-66-6 213 Zinc 10.0 ug/L U 6020A 10.0 25.0 10 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-MW02 7782-44-7 356 Dissolved Oxygen 0.58 mg/L 10/20/2015 58-03 5803-MW02 SW336 336 Oxygen Reduction Potential 208.6 mV 10/20/2015 58-03 5803-MW02 SW320 320 pH 6.00 SU 10/20/2015 5445 58-03 5803-MW02 SW323 323 Specific Conductivity 101 µS 10/20/2015 58-03 5803-MW02 SW325 325 Temperature 17.52 °C 10/20/2015 58-03 5803-MW02 SW330 330 Turbidity 42.15 NTU 10/20/2015 58-03 5803-MW02 SW318 318 Depth to Water 4.76 ft TOC 10/20/2015 58-03 5803-MW02 SW411 411 Total Well Depth 18.20 ft TOC 10/20/2015 58-03 5803-MW02 SW328 328 Top of Casing (TOC) Elevation 1,898.94 feet 58-03 5803-MW03 630-20-6 190 1,1,1,2-Tetrachloroethane 0.150 ug/L U 8260B 0.150 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 71-55-6 200 1,1,1-Trichloroethane 0.190 ug/L U 8260B 0.190 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 79-34-5 191 1,1,2,2-Tetrachloroethane 0.190 ug/L U 8260B 0.190 1.00 3 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 79-00-5 202 1,1,2-Trichloroethane 0.190 ug/L U 8260B 0.190 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 75-34-3 75 1,1-Dichloroethane 0.240 ug/L U 8260B 0.240 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 75-35-4 77 1,1-Dichloroethene 0.250 ug/L U 8260B 0.250 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 96-18-4 206 1,2,3-Trichloropropane 0.230 ug/L U 8260B 0.230 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 96-12-8 67 1,2-Dibromo-3-chloropropane 0.940 ug/L U 8260B 0.940 10.0 13 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 106-93-4 68 1,2-Dibromoethane 0.210 ug/L U 8260B 0.210 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 107-06-2 76 1,2-Dichloroethane 0.200 ug/L U 8260B 0.200 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 78-87-5 82 1,2-Dichloropropane 0.250 ug/L U 8260B 0.250 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 591-78-6 124 2-Hexanone 1.28 ug/L U 8260B 1.28 10.0 50 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 108-10-1 147 4-Methyl-2-pentanone 0.810 ug/L U 8260B 0.810 10.0 100 1 10/21/2015 10/24/2015 387 P:\Madison County\Reports\2015\Fall\5803-Operating\5803_2015Oct_EDD Page 3 of 17 5803Oct2015EDD FACILITY PERMIT WELL ID CAS Number SWS ID PARAMETER RESULT UNITS QUALIFIER METHOD MDL MRL SWSL DILUTION FACTOR COLLECT DATE EXTRACTION DATE ANALYSIS DATE NC LABORATORY CERTIFICATION NUMBER 58-03 5803-MW03 67-64-1 3 Acetone 2.66 ug/L U 8260B 2.66 25.0 100 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 107-13-1 8 Acrylonitrile 0.500 ug/L U 8260B 0.500 10.0 200 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 7440-36-0 13 Antimony 0.500 ug/L U 6020A 0.500 2.00 6 1 10/21/2015 10/24/2015 11/06/2015 387 58-03 5803-MW03 7440-38-2 14 Arsenic 8.60 ug/L U 6010C 8.60 10.0 10 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW03 7440-39-3 15 Barium 188 ug/L 6010C 5.00 10.0 100 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW03 71-43-2 16 Benzene 0.200 ug/L U 8260B 0.200 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 7440-41-7 23 Beryllium 0.500 ug/L U 6020A 0.500 2.00 1 1 10/21/2015 10/24/2015 10/30/2015 387 58-03 5803-MW03 74-97-5 28 Bromochloromethane 0.150 ug/L U 8260B 0.150 1.00 3 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 75-27-4 29 Bromodichloromethane 0.170 ug/L U 8260B 0.170 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 75-25-2 30 Bromoform 0.290 ug/L U 8260B 0.290 1.00 3 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 7440-43-9 34 Cadmium 0.500 ug/L U 6010C 0.500 1.00 1 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW03 75-15-0 35 Carbon disulfide 0.220 ug/L U 8260B 0.220 1.00 100 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 56-23-5 36 Carbon tetrachloride 0.180 ug/L U 8260B 0.180 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 108-90-7 39 Chlorobenzene 0.180 ug/L U 8260B 0.180 1.00 3 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 75-00-3 41 Chloroethane 0.360 ug/L U 8260B 0.360 1.00 10 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 67-66-3 44 Chloroform 0.230 ug/L U 8260B 0.230 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 7440-47-3 51 Chromium 3.00 ug/L U 6010C 3.00 5.00 10 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW03 156-59-2 78 cis-1,2-Dichloroethene 0.210 ug/L U 8260B 0.210 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 10061-01-5 86 cis-1,3-Dichloropropene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 7440-48-4 53 Cobalt 77.9 ug/L 6020A 0.500 2.00 10 1 10/21/2015 10/24/2015 10/30/2015 387 58-03 5803-MW03 7440-50-8 54 Copper 5.00 ug/L U 6010C 5.00 10.0 10 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW03 124-48-1 66 Dibromochloromethane 0.250 ug/L U 8260B 0.250 1.00 3 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 100-41-4 110 Ethylbenzene 0.190 ug/L U 8260B 0.190 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 7439-92-1 131 Lead 10.0 ug/L U 6010C 10.0 25.0 10 5 10/21/2015 10/26/2015 10/28/2015 387 58-03 5803-MW03 7439-97-6 132 Mercury 0.100 ug/L U 7470A 0.100 0.200 0.2 1 10/21/2015 10/27/2015 10/28/2015 387 58-03 5803-MW03 74-83-9 136 Methyl bromide 0.350 ug/L U 8260B 0.350 1.00 10 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 74-87-3 137 Methyl chloride 0.360 ug/L U 8260B 0.360 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 78-93-3 141 Methyl ethyl ketone 2.64 ug/L U 8260B 2.64 50.0 100 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 74-88-4 142 Methyl iodide; Iodomethane 1.50 ug/L U 8260B 1.50 10.0 10 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 74-95-3 139 Methylene bromide 0.450 ug/L U 8260B 0.450 1.00 10 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 75-09-2 140 Methylene Chloride 0.220 ug/L U 8260B 0.220 5.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 7440-02-0 152 Nickel 3.00 ug/L U 6010C 3.00 10.0 50 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW03 95-50-1 69 o-Dichlorobenzene 0.190 ug/L U 8260B 0.190 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 106-46-7 71 p-Dichlorobenzene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 7782-49-2 183 Selenium 11.1 ug/L 6010C 5.00 10.0 10 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW03 7440-22-4 184 Silver 3.00 ug/L U 6010C 3.00 5.00 10 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW03 100-42-5 186 Styrene 0.280 ug/L U 8260B 0.280 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 127-18-4 192 Tetrachloroethene 0.140 ug/L U 8260B 0.140 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 109-99-9 458 Tetrahydrofuran 0.820 ug/L U 8260B 0.820 10.0 NE 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 7440-28-0 194 Thallium 0.200 ug/L U 6020A 0.200 2.00 5.5 1 10/21/2015 10/24/2015 10/30/2015 387 58-03 5803-MW03 108-88-3 196 Toluene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 156-60-5 79 trans-1,2-Dichloroethene 0.230 ug/L U 8260B 0.230 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 10061-02-6 87 trans-1,3-Dichloropropene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 110-57-6 73 trans-1,4-Dichloro-2-butene 0.460 ug/L U 8260B 0.460 5.00 100 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 79-01-6 201 Trichloroethene 0.200 ug/L U 8260B 0.200 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 75-69-4 203 Trichlorofluoromethane 0.210 ug/L U 8260B 0.210 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 7440-62-2 209 Vanadium 1.76 ug/L J 6020A 0.100 2.00 25 1 10/21/2015 10/24/2015 10/30/2015 387 58-03 5803-MW03 108-05-4 210 Vinyl acetate 1.71 ug/L U 8260B 1.71 10.0 50 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 75-01-4 211 Vinyl chloride 0.180 ug/L U 8260B 0.180 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 1330-20-7 346 Xylene (total)1.03 ug/L J 8260B 0.580 3.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW03 7440-66-6 213 Zinc 10.0 ug/L U 6020A 10.0 25.0 10 1 10/21/2015 10/24/2015 11/06/2015 387 58-03 5803-MW03 7782-44-7 356 Dissolved Oxygen 5.57 mg/L 10/21/2015 58-03 5803-MW03 SW336 336 Oxygen Reduction Potential 112.3 mV 10/21/2015 P:\Madison County\Reports\2015\Fall\5803-Operating\5803_2015Oct_EDD Page 4 of 17 5803Oct2015EDD FACILITY PERMIT WELL ID CAS Number SWS ID PARAMETER RESULT UNITS QUALIFIER METHOD MDL MRL SWSL DILUTION FACTOR COLLECT DATE EXTRACTION DATE ANALYSIS DATE NC LABORATORY CERTIFICATION NUMBER 58-03 5803-MW03 SW320 320 pH 6.10 SU 10/21/2015 5445 58-03 5803-MW03 SW323 323 Specific Conductivity 232 µS 10/21/2015 58-03 5803-MW03 SW325 325 Temperature 13.48 °C 10/21/2015 58-03 5803-MW03 SW330 330 Turbidity 4.78 NTU 10/21/2015 58-03 5803-MW03 SW318 318 Depth to Water 23.64 ft TOC 10/21/2015 58-03 5803-MW03 SW411 411 Total Well Depth 35.90 ft TOC 58-03 5803-MW03 SW328 328 Top of Casing (TOC) Elevation 1,932.96 feet 58-03 5803-MW04 630-20-6 190 1,1,1,2-Tetrachloroethane 0.150 ug/L U 8260B 0.150 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 71-55-6 200 1,1,1-Trichloroethane 0.190 ug/L U 8260B 0.190 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 79-34-5 191 1,1,2,2-Tetrachloroethane 0.190 ug/L U 8260B 0.190 1.00 3 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 79-00-5 202 1,1,2-Trichloroethane 0.190 ug/L U 8260B 0.190 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 75-34-3 75 1,1-Dichloroethane 0.240 ug/L U 8260B 0.240 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 75-35-4 77 1,1-Dichloroethene 0.250 ug/L U 8260B 0.250 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 96-18-4 206 1,2,3-Trichloropropane 0.230 ug/L U 8260B 0.230 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 96-12-8 67 1,2-Dibromo-3-chloropropane 0.940 ug/L U 8260B 0.940 10.0 13 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 106-93-4 68 1,2-Dibromoethane 0.210 ug/L U 8260B 0.210 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 107-06-2 76 1,2-Dichloroethane 0.200 ug/L U 8260B 0.200 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 78-87-5 82 1,2-Dichloropropane 0.250 ug/L U 8260B 0.250 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 591-78-6 124 2-Hexanone 1.28 ug/L U 8260B 1.28 10.0 50 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 108-10-1 147 4-Methyl-2-pentanone 0.810 ug/L U 8260B 0.810 10.0 100 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 67-64-1 3 Acetone 2.66 ug/L U 8260B 2.66 25.0 100 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 107-13-1 8 Acrylonitrile 0.500 ug/L U 8260B 0.500 10.0 200 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 7440-36-0 13 Antimony 0.500 ug/L U 6020A 0.500 2.00 6 1 10/21/2015 10/24/2015 11/06/2015 387 58-03 5803-MW04 7440-38-2 14 Arsenic 8.60 ug/L U 6010C 8.60 10.0 10 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW04 7440-39-3 15 Barium 151 ug/L 6010C 5.00 10.0 100 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW04 71-43-2 16 Benzene 0.200 ug/L U 8260B 0.200 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 7440-41-7 23 Beryllium 0.500 ug/L U 6020A 0.500 2.00 1 1 10/21/2015 10/24/2015 10/30/2015 387 58-03 5803-MW04 74-97-5 28 Bromochloromethane 0.150 ug/L U 8260B 0.150 1.00 3 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 75-27-4 29 Bromodichloromethane 0.170 ug/L U 8260B 0.170 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 75-25-2 30 Bromoform 0.290 ug/L U 8260B 0.290 1.00 3 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 7440-43-9 34 Cadmium 0.500 ug/L U 6010C 0.500 1.00 1 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW04 75-15-0 35 Carbon disulfide 0.220 ug/L U 8260B 0.220 1.00 100 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 56-23-5 36 Carbon tetrachloride 0.180 ug/L U 8260B 0.180 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 108-90-7 39 Chlorobenzene 0.180 ug/L U 8260B 0.180 1.00 3 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 75-00-3 41 Chloroethane 0.360 ug/L U 8260B 0.360 1.00 10 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 67-66-3 44 Chloroform 0.230 ug/L U 8260B 0.230 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 7440-47-3 51 Chromium 3.00 ug/L U 6010C 3.00 5.00 10 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW04 156-59-2 78 cis-1,2-Dichloroethene 0.210 ug/L U 8260B 0.210 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 10061-01-5 86 cis-1,3-Dichloropropene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 7440-48-4 53 Cobalt 0.500 ug/L U 6020A 0.500 2.00 10 1 10/21/2015 10/24/2015 10/30/2015 387 58-03 5803-MW04 7440-50-8 54 Copper 5.00 ug/L U 6010C 5.00 10.0 10 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW04 124-48-1 66 Dibromochloromethane 0.250 ug/L U 8260B 0.250 1.00 3 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 100-41-4 110 Ethylbenzene 0.190 ug/L U 8260B 0.190 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 7439-92-1 131 Lead 2.20 ug/L J 6010C 2.00 5.00 10 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW04 7439-97-6 132 Mercury 0.100 ug/L U 7470A 0.100 0.200 0.2 1 10/21/2015 10/27/2015 10/28/2015 387 58-03 5803-MW04 74-83-9 136 Methyl bromide 0.350 ug/L U 8260B 0.350 1.00 10 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 74-87-3 137 Methyl chloride 0.360 ug/L U 8260B 0.360 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 78-93-3 141 Methyl ethyl ketone 2.64 ug/L U 8260B 2.64 50.0 100 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 74-88-4 142 Methyl iodide; Iodomethane 1.50 ug/L U 8260B 1.50 10.0 10 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 74-95-3 139 Methylene bromide 0.450 ug/L U 8260B 0.450 1.00 10 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 75-09-2 140 Methylene Chloride 0.220 ug/L U 8260B 0.220 5.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 7440-02-0 152 Nickel 3.00 ug/L U 6010C 3.00 10.0 50 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW04 95-50-1 69 o-Dichlorobenzene 0.190 ug/L U 8260B 0.190 1.00 5 1 10/21/2015 10/24/2015 387 P:\Madison County\Reports\2015\Fall\5803-Operating\5803_2015Oct_EDD Page 5 of 17 5803Oct2015EDD FACILITY PERMIT WELL ID CAS Number SWS ID PARAMETER RESULT UNITS QUALIFIER METHOD MDL MRL SWSL DILUTION FACTOR COLLECT DATE EXTRACTION DATE ANALYSIS DATE NC LABORATORY CERTIFICATION NUMBER 58-03 5803-MW04 106-46-7 71 p-Dichlorobenzene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 7782-49-2 183 Selenium 5.00 ug/L U 6010C 5.00 10.0 10 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW04 7440-22-4 184 Silver 3.00 ug/L U 6010C 3.00 5.00 10 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW04 100-42-5 186 Styrene 0.280 ug/L U 8260B 0.280 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 127-18-4 192 Tetrachloroethene 0.140 ug/L U 8260B 0.140 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 109-99-9 458 Tetrahydrofuran 0.820 ug/L U 8260B 0.820 10.0 NE 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 7440-28-0 194 Thallium 0.200 ug/L U 6020A 0.200 2.00 5.5 1 10/21/2015 10/24/2015 10/30/2015 387 58-03 5803-MW04 108-88-3 196 Toluene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 156-60-5 79 trans-1,2-Dichloroethene 0.230 ug/L U 8260B 0.230 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 10061-02-6 87 trans-1,3-Dichloropropene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 110-57-6 73 trans-1,4-Dichloro-2-butene 0.460 ug/L U 8260B 0.460 5.00 100 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 79-01-6 201 Trichloroethene 0.200 ug/L U 8260B 0.200 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 75-69-4 203 Trichlorofluoromethane 0.210 ug/L U 8260B 0.210 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 7440-62-2 209 Vanadium 6.34 ug/L J 6020A 0.100 2.00 25 1 10/21/2015 10/24/2015 10/30/2015 387 58-03 5803-MW04 108-05-4 210 Vinyl acetate 1.71 ug/L U 8260B 1.71 10.0 50 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 75-01-4 211 Vinyl chloride 0.180 ug/L U 8260B 0.180 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 1330-20-7 346 Xylene (total)1.09 ug/L J 8260B 0.580 3.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW04 7440-66-6 213 Zinc 10.0 ug/L U 6020A 10.0 25.0 10 1 10/21/2015 10/24/2015 11/06/2015 387 58-03 5803-MW04 7782-44-7 356 Dissolved Oxygen 5.00 mg/L 10/21/2015 58-03 5803-MW04 SW336 336 Oxygen Reduction Potential 172.1 mV 10/21/2015 58-03 5803-MW04 SW320 320 pH 6.39 SU 10/21/2015 5445 58-03 5803-MW04 SW323 323 Specific Conductivity 157 µS 10/21/2015 58-03 5803-MW04 SW325 325 Temperature 14.92 °C 10/21/2015 58-03 5803-MW04 SW330 330 Turbidity 3.55 NTU 10/21/2015 58-03 5803-MW04 SW318 318 Depth to Water 28.06 ft TOC 10/21/2015 58-03 5803-MW04 SW411 411 Total Well Depth 83.00 ft TOC 58-03 5803-MW04 SW328 328 Top of Casing (TOC) Elevation 1,935.64 feet 58-03 5803-MW05 630-20-6 190 1,1,1,2-Tetrachloroethane 0.150 ug/L U 8260B 0.150 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 71-55-6 200 1,1,1-Trichloroethane 0.190 ug/L U 8260B 0.190 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 79-34-5 191 1,1,2,2-Tetrachloroethane 0.190 ug/L U 8260B 0.190 1.00 3 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 79-00-5 202 1,1,2-Trichloroethane 0.190 ug/L U 8260B 0.190 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 75-34-3 75 1,1-Dichloroethane 0.240 ug/L U 8260B 0.240 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 75-35-4 77 1,1-Dichloroethene 0.250 ug/L U 8260B 0.250 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 96-18-4 206 1,2,3-Trichloropropane 0.230 ug/L U 8260B 0.230 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 96-12-8 67 1,2-Dibromo-3-chloropropane 0.940 ug/L U 8260B 0.940 10.0 13 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 106-93-4 68 1,2-Dibromoethane 0.210 ug/L U 8260B 0.210 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 107-06-2 76 1,2-Dichloroethane 0.200 ug/L U 8260B 0.200 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 78-87-5 82 1,2-Dichloropropane 0.250 ug/L U 8260B 0.250 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 591-78-6 124 2-Hexanone 1.28 ug/L U 8260B 1.28 10.0 50 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 108-10-1 147 4-Methyl-2-pentanone 0.810 ug/L U 8260B 0.810 10.0 100 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 67-64-1 3 Acetone 2.66 ug/L U 8260B 2.66 25.0 100 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 107-13-1 8 Acrylonitrile 0.500 ug/L U 8260B 0.500 10.0 200 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 7440-36-0 13 Antimony 0.500 ug/L U 6020A 0.500 2.00 6 1 10/21/2015 10/24/2015 11/06/2015 387 58-03 5803-MW05 7440-38-2 14 Arsenic 8.60 ug/L U 6010C 8.60 10.0 10 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW05 7440-39-3 15 Barium 134 ug/L 6010C 5.00 10.0 100 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW05 71-43-2 16 Benzene 0.200 ug/L U 8260B 0.200 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 7440-41-7 23 Beryllium 0.500 ug/L U 6020A 0.500 2.00 1 1 10/21/2015 10/24/2015 10/30/2015 387 58-03 5803-MW05 74-97-5 28 Bromochloromethane 0.150 ug/L U 8260B 0.150 1.00 3 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 75-27-4 29 Bromodichloromethane 0.170 ug/L U 8260B 0.170 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 75-25-2 30 Bromoform 0.290 ug/L U 8260B 0.290 1.00 3 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 7440-43-9 34 Cadmium 0.500 ug/L U 6010C 0.500 1.00 1 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW05 75-15-0 35 Carbon disulfide 0.220 ug/L U 8260B 0.220 1.00 100 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 56-23-5 36 Carbon tetrachloride 0.180 ug/L U 8260B 0.180 1.00 1 1 10/21/2015 10/24/2015 387 P:\Madison County\Reports\2015\Fall\5803-Operating\5803_2015Oct_EDD Page 6 of 17 5803Oct2015EDD FACILITY PERMIT WELL ID CAS Number SWS ID PARAMETER RESULT UNITS QUALIFIER METHOD MDL MRL SWSL DILUTION FACTOR COLLECT DATE EXTRACTION DATE ANALYSIS DATE NC LABORATORY CERTIFICATION NUMBER 58-03 5803-MW05 108-90-7 39 Chlorobenzene 0.180 ug/L U 8260B 0.180 1.00 3 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 75-00-3 41 Chloroethane 0.360 ug/L U 8260B 0.360 1.00 10 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 67-66-3 44 Chloroform 0.230 ug/L U 8260B 0.230 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 7440-47-3 51 Chromium 3.00 ug/L U 6010C 3.00 5.00 10 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW05 156-59-2 78 cis-1,2-Dichloroethene 0.210 ug/L U 8260B 0.210 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 10061-01-5 86 cis-1,3-Dichloropropene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 7440-48-4 53 Cobalt 1.25 ug/L J 6020A 0.500 2.00 10 1 10/21/2015 10/24/2015 10/30/2015 387 58-03 5803-MW05 7440-50-8 54 Copper 5.00 ug/L U 6010C 5.00 10.0 10 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW05 124-48-1 66 Dibromochloromethane 0.250 ug/L U 8260B 0.250 1.00 3 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 100-41-4 110 Ethylbenzene 0.190 ug/L U 8260B 0.190 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 7439-92-1 131 Lead 2.30 ug/L J 6010C 2.00 5.00 10 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW05 7439-97-6 132 Mercury 0.100 ug/L U 7470A 0.100 0.200 0.2 1 10/21/2015 10/27/2015 10/28/2015 387 58-03 5803-MW05 74-83-9 136 Methyl bromide 0.350 ug/L U 8260B 0.350 1.00 10 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 74-87-3 137 Methyl chloride 0.360 ug/L U 8260B 0.360 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 78-93-3 141 Methyl ethyl ketone 2.64 ug/L U 8260B 2.64 50.0 100 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 74-88-4 142 Methyl iodide; Iodomethane 1.50 ug/L U 8260B 1.50 10.0 10 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 74-95-3 139 Methylene bromide 0.450 ug/L U 8260B 0.450 1.00 10 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 75-09-2 140 Methylene Chloride 0.220 ug/L U 8260B 0.220 5.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 7440-02-0 152 Nickel 7.60 ug/L J 6010C 3.00 10.0 50 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW05 95-50-1 69 o-Dichlorobenzene 0.190 ug/L U 8260B 0.190 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 106-46-7 71 p-Dichlorobenzene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 7782-49-2 183 Selenium 5.20 ug/L J 6010C 5.00 10.0 10 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW05 7440-22-4 184 Silver 3.00 ug/L U 6010C 3.00 5.00 10 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW05 100-42-5 186 Styrene 0.280 ug/L U 8260B 0.280 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 127-18-4 192 Tetrachloroethene 0.140 ug/L U 8260B 0.140 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 109-99-9 458 Tetrahydrofuran 0.820 ug/L U 8260B 0.820 10.0 NE 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 7440-28-0 194 Thallium 0.200 ug/L U 6020A 0.200 2.00 5.5 1 10/21/2015 10/24/2015 10/30/2015 387 58-03 5803-MW05 108-88-3 196 Toluene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 156-60-5 79 trans-1,2-Dichloroethene 0.230 ug/L U 8260B 0.230 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 10061-02-6 87 trans-1,3-Dichloropropene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 110-57-6 73 trans-1,4-Dichloro-2-butene 0.460 ug/L U 8260B 0.460 5.00 100 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 79-01-6 201 Trichloroethene 0.200 ug/L U 8260B 0.200 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 75-69-4 203 Trichlorofluoromethane 0.210 ug/L U 8260B 0.210 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 7440-62-2 209 Vanadium 6.65 ug/L J 6020A 0.100 2.00 25 1 10/21/2015 10/24/2015 10/30/2015 387 58-03 5803-MW05 108-05-4 210 Vinyl acetate 1.71 ug/L U 8260B 1.71 10.0 50 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 75-01-4 211 Vinyl chloride 0.180 ug/L U 8260B 0.180 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 1330-20-7 346 Xylene (total)1.25 ug/L J 8260B 0.580 3.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW05 7440-66-6 213 Zinc 10.0 ug/L U 6020A 10.0 25.0 10 1 10/21/2015 10/24/2015 11/06/2015 387 58-03 5803-MW05 7782-44-7 356 Dissolved Oxygen 1.16 mg/L 10/21/2015 58-03 5803-MW05 SW336 336 Oxygen Reduction Potential 223.3 mV 10/21/2015 58-03 5803-MW05 SW320 320 pH 5.93 SU 10/21/2015 5445 58-03 5803-MW05 SW323 323 Specific Conductivity 220 µS 10/21/2015 58-03 5803-MW05 SW325 325 Temperature 19.75 °C 10/21/2015 58-03 5803-MW05 SW330 330 Turbidity 7.29 NTU 10/21/2015 58-03 5803-MW05 SW318 318 Depth to Water 48.60 ft TOC 10/21/2015 58-03 5803-MW05 SW411 411 Total Well Depth 64.00 ft TOC 58-03 5803-MW05 SW328 328 Top of Casing (TOC) Elevation 1,972.76 feet 58-03 5803-MW06R 630-20-6 190 1,1,1,2-Tetrachloroethane 0.150 ug/L U 8260B 0.150 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 71-55-6 200 1,1,1-Trichloroethane 0.190 ug/L U 8260B 0.190 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 79-34-5 191 1,1,2,2-Tetrachloroethane 0.190 ug/L U 8260B 0.190 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 79-00-5 202 1,1,2-Trichloroethane 0.190 ug/L U 8260B 0.190 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 75-34-3 75 1,1-Dichloroethane 0.240 ug/L U 8260B 0.240 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 75-35-4 77 1,1-Dichloroethene 0.250 ug/L U 8260B 0.250 1.00 5 1 10/20/2015 10/24/2015 387 P:\Madison County\Reports\2015\Fall\5803-Operating\5803_2015Oct_EDD Page 7 of 17 5803Oct2015EDD FACILITY PERMIT WELL ID CAS Number SWS ID PARAMETER RESULT UNITS QUALIFIER METHOD MDL MRL SWSL DILUTION FACTOR COLLECT DATE EXTRACTION DATE ANALYSIS DATE NC LABORATORY CERTIFICATION NUMBER 58-03 5803-MW06R 96-18-4 206 1,2,3-Trichloropropane 0.230 ug/L U 8260B 0.230 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 96-12-8 67 1,2-Dibromo-3-chloropropane 0.940 ug/L U 8260B 0.940 10.0 13 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 106-93-4 68 1,2-Dibromoethane 0.210 ug/L U 8260B 0.210 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 107-06-2 76 1,2-Dichloroethane 0.200 ug/L U 8260B 0.200 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 78-87-5 82 1,2-Dichloropropane 0.250 ug/L U 8260B 0.250 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 591-78-6 124 2-Hexanone 1.28 ug/L U 8260B 1.28 10.0 50 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 108-10-1 147 4-Methyl-2-pentanone 0.810 ug/L U 8260B 0.810 10.0 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 67-64-1 3 Acetone 2.66 ug/L U 8260B 2.66 25.0 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 107-13-1 8 Acrylonitrile 0.500 ug/L U 8260B 0.500 10.0 200 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 7440-36-0 13 Antimony 0.500 ug/L U 6020A 0.500 2.00 6 1 10/20/2015 10/23/2015 11/05/2015 387 58-03 5803-MW06R 7440-38-2 14 Arsenic 8.60 ug/L U 6010C 8.60 10.0 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW06R 7440-39-3 15 Barium 29.0 ug/L J 6010C 5.00 10.0 100 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW06R 71-43-2 16 Benzene 0.200 ug/L U 8260B 0.200 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 7440-41-7 23 Beryllium 0.500 ug/L U 6020A 0.500 2.00 1 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-MW06R 74-97-5 28 Bromochloromethane 0.150 ug/L U 8260B 0.150 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 75-27-4 29 Bromodichloromethane 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 75-25-2 30 Bromoform 0.290 ug/L U 8260B 0.290 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 7440-43-9 34 Cadmium 0.500 ug/L U 6010C 0.500 1.00 1 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW06R 75-15-0 35 Carbon disulfide 0.220 ug/L U 8260B 0.220 1.00 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 56-23-5 36 Carbon tetrachloride 0.180 ug/L U 8260B 0.180 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 108-90-7 39 Chlorobenzene 0.180 ug/L U 8260B 0.180 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 75-00-3 41 Chloroethane 0.360 ug/L U 8260B 0.360 1.00 10 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 67-66-3 44 Chloroform 0.230 ug/L U 8260B 0.230 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 7440-47-3 51 Chromium 3.00 ug/L U 6010C 3.00 5.00 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW06R 156-59-2 78 cis-1,2-Dichloroethene 0.210 ug/L U 8260B 0.210 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 10061-01-5 86 cis-1,3-Dichloropropene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 7440-48-4 53 Cobalt 0.500 ug/L U 6020A 0.500 2.00 10 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-MW06R 7440-50-8 54 Copper 5.00 ug/L U 6010C 5.00 10.0 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW06R 124-48-1 66 Dibromochloromethane 0.250 ug/L U 8260B 0.250 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 100-41-4 110 Ethylbenzene 0.190 ug/L U 8260B 0.190 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 7439-92-1 131 Lead 2.00 ug/L U 6010C 2.00 5.00 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW06R 7439-97-6 132 Mercury 0.100 ug/L U 7470A 0.100 0.200 0.2 1 10/20/2015 10/26/2015 10/26/2015 387 58-03 5803-MW06R 74-83-9 136 Methyl bromide 0.350 ug/L U 8260B 0.350 1.00 10 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 74-87-3 137 Methyl chloride 0.360 ug/L U 8260B 0.360 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 78-93-3 141 Methyl ethyl ketone 2.64 ug/L U 8260B 2.64 50.0 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 74-88-4 142 Methyl iodide; Iodomethane 1.50 ug/L U 8260B 1.50 10.0 10 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 74-95-3 139 Methylene bromide 0.450 ug/L U 8260B 0.450 1.00 10 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 75-09-2 140 Methylene Chloride 0.220 ug/L U 8260B 0.220 5.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 7440-02-0 152 Nickel 3.00 ug/L U 6010C 3.00 10.0 50 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW06R 95-50-1 69 o-Dichlorobenzene 0.190 ug/L U 8260B 0.190 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 106-46-7 71 p-Dichlorobenzene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 7782-49-2 183 Selenium 5.00 ug/L U 6010C 5.00 10.0 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW06R 7440-22-4 184 Silver 3.00 ug/L U 6010C 3.00 5.00 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW06R 100-42-5 186 Styrene 0.280 ug/L U 8260B 0.280 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 127-18-4 192 Tetrachloroethene 0.140 ug/L U 8260B 0.140 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 109-99-9 458 Tetrahydrofuran 0.820 ug/L U 8260B 0.820 10.0 NE 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 7440-28-0 194 Thallium 0.200 ug/L U 6020A 0.200 2.00 5.5 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-MW06R 108-88-3 196 Toluene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 156-60-5 79 trans-1,2-Dichloroethene 0.230 ug/L U 8260B 0.230 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 10061-02-6 87 trans-1,3-Dichloropropene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 110-57-6 73 trans-1,4-Dichloro-2-butene 0.460 ug/L U 8260B 0.460 5.00 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 79-01-6 201 Trichloroethene 0.200 ug/L U 8260B 0.200 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 75-69-4 203 Trichlorofluoromethane 0.210 ug/L U 8260B 0.210 1.00 1 1 10/20/2015 10/24/2015 387 P:\Madison County\Reports\2015\Fall\5803-Operating\5803_2015Oct_EDD Page 8 of 17 5803Oct2015EDD FACILITY PERMIT WELL ID CAS Number SWS ID PARAMETER RESULT UNITS QUALIFIER METHOD MDL MRL SWSL DILUTION FACTOR COLLECT DATE EXTRACTION DATE ANALYSIS DATE NC LABORATORY CERTIFICATION NUMBER 58-03 5803-MW06R 7440-62-2 209 Vanadium 3.09 ug/L J 6020A 0.100 2.00 25 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-MW06R 108-05-4 210 Vinyl acetate 1.71 ug/L U 8260B 1.71 10.0 50 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 75-01-4 211 Vinyl chloride 0.180 ug/L U 8260B 0.180 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 1330-20-7 346 Xylene (total)0.580 ug/L U 8260B 0.580 3.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW06R 7440-66-6 213 Zinc 10.0 ug/L U 6020A 10.0 25.0 10 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-MW06R 7782-44-7 356 Dissolved Oxygen 5.11 mg/L 10/20/2015 58-03 5803-MW06R SW336 336 Oxygen Reduction Potential 200.4 mV 10/20/2015 58-03 5803-MW06R SW320 320 pH 6.30 SU 10/20/2015 5445 58-03 5803-MW06R SW323 323 Specific Conductivity 96 uS 10/20/2015 58-03 5803-MW06R SW325 325 Temperature 17.17 °C 10/20/2015 58-03 5803-MW06R SW330 330 Turbidity 0.860 NTU 10/20/2015 58-03 5803-MW06R SW318 318 Depth to Water 9.37 ft TOC 10/20/2015 58-03 5803-MW06R SW411 411 Total Well Depth 25.00 ft TOC 58-03 5803-MW06R SW328 328 Top of Casing (TOC) Elevation 1,942.19 feet 58-03 5803-MW07R 630-20-6 190 1,1,1,2-Tetrachloroethane 0.150 ug/L U 8260B 0.150 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 71-55-6 200 1,1,1-Trichloroethane 0.190 ug/L U 8260B 0.190 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 79-34-5 191 1,1,2,2-Tetrachloroethane 0.190 ug/L U 8260B 0.190 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 79-00-5 202 1,1,2-Trichloroethane 0.190 ug/L U 8260B 0.190 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 75-34-3 75 1,1-Dichloroethane 0.240 ug/L U 8260B 0.240 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 75-35-4 77 1,1-Dichloroethene 0.250 ug/L U 8260B 0.250 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 96-18-4 206 1,2,3-Trichloropropane 0.230 ug/L U 8260B 0.230 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 96-12-8 67 1,2-Dibromo-3-chloropropane 0.940 ug/L U 8260B 0.940 10.0 13 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 106-93-4 68 1,2-Dibromoethane 0.210 ug/L U 8260B 0.210 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 107-06-2 76 1,2-Dichloroethane 0.200 ug/L U 8260B 0.200 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 78-87-5 82 1,2-Dichloropropane 0.250 ug/L U 8260B 0.250 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 591-78-6 124 2-Hexanone 1.28 ug/L U 8260B 1.28 10.0 50 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 108-10-1 147 4-Methyl-2-pentanone 0.810 ug/L U 8260B 0.810 10.0 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 67-64-1 3 Acetone 2.66 ug/L U 8260B 2.66 25.0 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 107-13-1 8 Acrylonitrile 0.500 ug/L U 8260B 0.500 10.0 200 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 7440-36-0 13 Antimony 0.500 ug/L U 6020A 0.500 2.00 6 1 10/20/2015 10/23/2015 11/05/2015 387 58-03 5803-MW07R 7440-38-2 14 Arsenic 8.60 ug/L U 6010C 8.60 10.0 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW07R 7440-39-3 15 Barium 210 ug/L 6010C 5.00 10.0 100 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW07R 71-43-2 16 Benzene 0.200 ug/L U 8260B 0.200 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 7440-41-7 23 Beryllium 0.500 ug/L U 6020A 0.500 2.00 1 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-MW07R 74-97-5 28 Bromochloromethane 0.150 ug/L U 8260B 0.150 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 75-27-4 29 Bromodichloromethane 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 75-25-2 30 Bromoform 0.290 ug/L U 8260B 0.290 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 7440-43-9 34 Cadmium 3.30 ug/L 6010C 0.500 1.00 1 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW07R 75-15-0 35 Carbon disulfide 0.220 ug/L U 8260B 0.220 1.00 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 56-23-5 36 Carbon tetrachloride 0.180 ug/L U 8260B 0.180 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 108-90-7 39 Chlorobenzene 0.180 ug/L U 8260B 0.180 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 75-00-3 41 Chloroethane 0.360 ug/L U 8260B 0.360 1.00 10 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 67-66-3 44 Chloroform 0.230 ug/L U 8260B 0.230 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 7440-47-3 51 Chromium 5.90 ug/L J 6010C 3.00 5.00 10 1 10/20/2015 10/23/2015 10/29/2015 387 58-03 5803-MW07R 156-59-2 78 cis-1,2-Dichloroethene 0.210 ug/L U 8260B 0.210 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 10061-01-5 86 cis-1,3-Dichloropropene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 7440-48-4 53 Cobalt 3.42 ug/L J 6020A 0.500 2.00 10 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-MW07R 7440-50-8 54 Copper 5.00 ug/L U 6010C 5.00 10.0 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW07R 124-48-1 66 Dibromochloromethane 0.250 ug/L U 8260B 0.250 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 100-41-4 110 Ethylbenzene 0.190 ug/L U 8260B 0.190 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 7439-92-1 131 Lead 2.00 ug/L U 6010C 2.00 5.00 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW07R 7439-97-6 132 Mercury 0.100 ug/L U 7470A 0.100 0.200 0.2 1 10/20/2015 10/26/2015 10/26/2015 387 58-03 5803-MW07R 74-83-9 136 Methyl bromide 0.350 ug/L U 8260B 0.350 1.00 10 1 10/20/2015 10/24/2015 387 P:\Madison County\Reports\2015\Fall\5803-Operating\5803_2015Oct_EDD Page 9 of 17 5803Oct2015EDD FACILITY PERMIT WELL ID CAS Number SWS ID PARAMETER RESULT UNITS QUALIFIER METHOD MDL MRL SWSL DILUTION FACTOR COLLECT DATE EXTRACTION DATE ANALYSIS DATE NC LABORATORY CERTIFICATION NUMBER 58-03 5803-MW07R 74-87-3 137 Methyl chloride 0.360 ug/L U 8260B 0.360 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 78-93-3 141 Methyl ethyl ketone 2.64 ug/L U 8260B 2.64 50.0 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 74-88-4 142 Methyl iodide; Iodomethane 1.50 ug/L U 8260B 1.50 10.0 10 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 74-95-3 139 Methylene bromide 0.450 ug/L U 8260B 0.450 1.00 10 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 75-09-2 140 Methylene Chloride 0.220 ug/L U 8260B 0.220 5.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 7440-02-0 152 Nickel 5.50 ug/L J 6010C 3.00 10.0 50 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW07R 95-50-1 69 o-Dichlorobenzene 0.190 ug/L U 8260B 0.190 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 106-46-7 71 p-Dichlorobenzene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 7782-49-2 183 Selenium 5.00 ug/L U 6010C 5.00 10.0 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW07R 7440-22-4 184 Silver 3.00 ug/L U 6010C 3.00 5.00 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW07R 100-42-5 186 Styrene 0.280 ug/L U 8260B 0.280 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 127-18-4 192 Tetrachloroethene 0.140 ug/L U 8260B 0.140 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 109-99-9 458 Tetrahydrofuran 0.820 ug/L U 8260B 0.820 10.0 NE 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 7440-28-0 194 Thallium 0.200 ug/L U 6020A 0.200 2.00 5.5 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-MW07R 108-88-3 196 Toluene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 156-60-5 79 trans-1,2-Dichloroethene 0.230 ug/L U 8260B 0.230 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 10061-02-6 87 trans-1,3-Dichloropropene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 110-57-6 73 trans-1,4-Dichloro-2-butene 0.460 ug/L U 8260B 0.460 5.00 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 79-01-6 201 Trichloroethene 0.200 ug/L U 8260B 0.200 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 75-69-4 203 Trichlorofluoromethane 0.210 ug/L U 8260B 0.210 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 7440-62-2 209 Vanadium 10.5 ug/L J 6020A 0.100 2.00 25 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-MW07R 108-05-4 210 Vinyl acetate 1.71 ug/L U 8260B 1.71 10.0 50 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 75-01-4 211 Vinyl chloride 0.180 ug/L U 8260B 0.180 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 1330-20-7 346 Xylene (total)0.580 ug/L U 8260B 0.580 3.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW07R 7440-66-6 213 Zinc 11.9 ug/L J 6020A 10.0 25.0 10 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-MW07R 7782-44-7 356 Dissolved Oxygen 7.60 mg/L 10/20/2015 58-03 5803-MW07R SW336 336 Oxygen Reduction Potential 236.7 mV 10/20/2015 58-03 5803-MW07R SW320 320 pH 5.88 SU 10/20/2015 5445 58-03 5803-MW07R SW323 323 Specific Conductivity 46 µS 10/20/2015 58-03 5803-MW07R SW325 325 Temperature 15.95 °C 10/20/2015 58-03 5803-MW07R SW330 330 Turbidity 126.20 NTU 10/20/2015 58-03 5803-MW07R SW318 318 Depth to Water 29.59 ft TOC 10/20/2015 58-03 5803-MW07R SW411 411 Total Well Depth 41.40 ft TOC 58-03 5803-MW07R SW328 328 Top of Casing (TOC) Elevation 1919.34 feet 58-03 5803-MW08 630-20-6 190 1,1,1,2-Tetrachloroethane 0.150 ug/L U 8260B 0.150 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 71-55-6 200 1,1,1-Trichloroethane 0.190 ug/L U 8260B 0.190 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 79-34-5 191 1,1,2,2-Tetrachloroethane 0.190 ug/L U 8260B 0.190 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 79-00-5 202 1,1,2-Trichloroethane 0.190 ug/L U 8260B 0.190 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 75-34-3 75 1,1-Dichloroethane 0.240 ug/L U 8260B 0.240 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 75-35-4 77 1,1-Dichloroethene 0.250 ug/L U 8260B 0.250 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 96-18-4 206 1,2,3-Trichloropropane 0.230 ug/L U 8260B 0.230 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 96-12-8 67 1,2-Dibromo-3-chloropropane 0.940 ug/L U 8260B 0.940 10.0 13 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 106-93-4 68 1,2-Dibromoethane 0.210 ug/L U 8260B 0.210 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 107-06-2 76 1,2-Dichloroethane 0.200 ug/L U 8260B 0.200 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 78-87-5 82 1,2-Dichloropropane 0.250 ug/L U 8260B 0.250 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 591-78-6 124 2-Hexanone 1.28 ug/L U 8260B 1.28 10.0 50 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 108-10-1 147 4-Methyl-2-pentanone 0.810 ug/L U 8260B 0.810 10.0 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 67-64-1 3 Acetone 2.66 ug/L U 8260B 2.66 25.0 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 107-13-1 8 Acrylonitrile 0.500 ug/L U 8260B 0.500 10.0 200 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 7440-36-0 13 Antimony 0.500 ug/L U 6020A 0.500 2.00 6 1 10/20/2015 10/23/2015 11/05/2015 387 58-03 5803-MW08 7440-38-2 14 Arsenic 8.60 ug/L U 6010C 8.60 10.0 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW08 7440-39-3 15 Barium 31.7 ug/L J 6010C 5.00 10.0 100 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW08 71-43-2 16 Benzene 0.200 ug/L U 8260B 0.200 1.00 1 1 10/20/2015 10/24/2015 387 P:\Madison County\Reports\2015\Fall\5803-Operating\5803_2015Oct_EDD Page 10 of 17 5803Oct2015EDD FACILITY PERMIT WELL ID CAS Number SWS ID PARAMETER RESULT UNITS QUALIFIER METHOD MDL MRL SWSL DILUTION FACTOR COLLECT DATE EXTRACTION DATE ANALYSIS DATE NC LABORATORY CERTIFICATION NUMBER 58-03 5803-MW08 7440-41-7 23 Beryllium 0.500 ug/L U 6020A 0.500 2.00 1 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-MW08 74-97-5 28 Bromochloromethane 0.150 ug/L U 8260B 0.150 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 75-27-4 29 Bromodichloromethane 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 75-25-2 30 Bromoform 0.290 ug/L U 8260B 0.290 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 7440-43-9 34 Cadmium 0.500 ug/L U 6010C 0.500 1.00 1 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW08 75-15-0 35 Carbon disulfide 0.220 ug/L U 8260B 0.220 1.00 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 56-23-5 36 Carbon tetrachloride 0.180 ug/L U 8260B 0.180 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 108-90-7 39 Chlorobenzene 0.180 ug/L U 8260B 0.180 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 75-00-3 41 Chloroethane 0.360 ug/L U 8260B 0.360 1.00 10 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 67-66-3 44 Chloroform 0.230 ug/L U 8260B 0.230 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 7440-47-3 51 Chromium 3.00 ug/L U 6010C 3.00 5.00 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW08 156-59-2 78 cis-1,2-Dichloroethene 0.210 ug/L U 8260B 0.210 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 10061-01-5 86 cis-1,3-Dichloropropene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 7440-48-4 53 Cobalt 0.500 ug/L U 6020A 0.500 2.00 10 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-MW08 7440-50-8 54 Copper 5.00 ug/L U 6010C 5.00 10.0 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW08 124-48-1 66 Dibromochloromethane 0.250 ug/L U 8260B 0.250 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 100-41-4 110 Ethylbenzene 0.190 ug/L U 8260B 0.190 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 7439-92-1 131 Lead 2.00 ug/L U 6010C 2.00 5.00 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW08 7439-97-6 132 Mercury 0.100 ug/L U 7470A 0.100 0.200 0.2 1 10/20/2015 10/26/2015 10/26/2015 387 58-03 5803-MW08 74-83-9 136 Methyl bromide 0.350 ug/L U 8260B 0.350 1.00 10 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 74-87-3 137 Methyl chloride 0.360 ug/L U 8260B 0.360 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 78-93-3 141 Methyl ethyl ketone 2.64 ug/L U 8260B 2.64 50.0 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 74-88-4 142 Methyl iodide; Iodomethane 1.50 ug/L U 8260B 1.50 10.0 10 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 74-95-3 139 Methylene bromide 0.450 ug/L U 8260B 0.450 1.00 10 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 75-09-2 140 Methylene Chloride 0.220 ug/L U 8260B 0.220 5.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 7440-02-0 152 Nickel 3.00 ug/L U 6010C 3.00 10.0 50 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW08 95-50-1 69 o-Dichlorobenzene 0.190 ug/L U 8260B 0.190 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 106-46-7 71 p-Dichlorobenzene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 7782-49-2 183 Selenium 5.00 ug/L U 6010C 5.00 10.0 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW08 7440-22-4 184 Silver 3.00 ug/L U 6010C 3.00 5.00 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-MW08 100-42-5 186 Styrene 0.280 ug/L U 8260B 0.280 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 127-18-4 192 Tetrachloroethene 0.140 ug/L U 8260B 0.140 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 109-99-9 458 Tetrahydrofuran 0.820 ug/L U 8260B 0.820 10.0 NE 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 7440-28-0 194 Thallium 0.200 ug/L U 6020A 0.200 2.00 5.5 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-MW08 108-88-3 196 Toluene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 156-60-5 79 trans-1,2-Dichloroethene 0.230 ug/L U 8260B 0.230 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 10061-02-6 87 trans-1,3-Dichloropropene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 110-57-6 73 trans-1,4-Dichloro-2-butene 0.460 ug/L U 8260B 0.460 5.00 100 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 79-01-6 201 Trichloroethene 0.200 ug/L U 8260B 0.200 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 75-69-4 203 Trichlorofluoromethane 0.210 ug/L U 8260B 0.210 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 7440-62-2 209 Vanadium 5.37 ug/L J 6020A 0.100 2.00 25 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-MW08 108-05-4 210 Vinyl acetate 1.71 ug/L U 8260B 1.71 10.0 50 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 75-01-4 211 Vinyl chloride 0.180 ug/L U 8260B 0.180 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 1330-20-7 346 Xylene (total)0.580 ug/L U 8260B 0.580 3.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-MW08 7440-66-6 213 Zinc 10.0 ug/L U 6020A 10.0 25.0 10 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-MW08 7782-44-7 356 Dissolved Oxygen 5.19 mg/L 10/20/2015 58-03 5803-MW08 SW336 336 Oxygen Reduction Potential 200.4 mV 10/20/2015 58-03 5803-MW08 SW320 320 pH 6.31 SU 10/20/2015 5445 58-03 5803-MW08 SW323 323 Specific Conductivity 208 µS 10/20/2015 58-03 5803-MW08 SW325 325 Temperature 14.50 °C 10/20/2015 58-03 5803-MW08 SW330 330 Turbidity 0 NTU 10/20/2015 58-03 5803-MW08 SW318 318 Depth to Water 20.62 ft TOC 10/20/2015 58-03 5803-MW08 SW411 411 Total Well Depth 26.60 ft TOC P:\Madison County\Reports\2015\Fall\5803-Operating\5803_2015Oct_EDD Page 11 of 17 5803Oct2015EDD FACILITY PERMIT WELL ID CAS Number SWS ID PARAMETER RESULT UNITS QUALIFIER METHOD MDL MRL SWSL DILUTION FACTOR COLLECT DATE EXTRACTION DATE ANALYSIS DATE NC LABORATORY CERTIFICATION NUMBER 58-03 5803-MW08 SW328 328 Top of Casing (TOC) Elevation 1,899.92 feet 58-03 5803-MW09 630-20-6 190 1,1,1,2-Tetrachloroethane 0.150 ug/L U 8260B 0.150 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 71-55-6 200 1,1,1-Trichloroethane 0.190 ug/L U 8260B 0.190 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 79-34-5 191 1,1,2,2-Tetrachloroethane 0.190 ug/L U 8260B 0.190 1.00 3 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 79-00-5 202 1,1,2-Trichloroethane 0.190 ug/L U 8260B 0.190 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 75-34-3 75 1,1-Dichloroethane 0.240 ug/L U 8260B 0.240 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 75-35-4 77 1,1-Dichloroethene 0.250 ug/L U 8260B 0.250 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 96-18-4 206 1,2,3-Trichloropropane 0.230 ug/L U 8260B 0.230 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 96-12-8 67 1,2-Dibromo-3-chloropropane 0.940 ug/L U 8260B 0.940 10.0 13 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 106-93-4 68 1,2-Dibromoethane 0.210 ug/L U 8260B 0.210 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 107-06-2 76 1,2-Dichloroethane 0.200 ug/L U 8260B 0.200 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 78-87-5 82 1,2-Dichloropropane 0.250 ug/L U 8260B 0.250 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 591-78-6 124 2-Hexanone 1.28 ug/L U 8260B 1.28 10.0 50 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 108-10-1 147 4-Methyl-2-pentanone 0.810 ug/L U 8260B 0.810 10.0 100 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 67-64-1 3 Acetone 2.66 ug/L U 8260B 2.66 25.0 100 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 107-13-1 8 Acrylonitrile 0.500 ug/L U 8260B 0.500 10.0 200 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 7440-36-0 13 Antimony 0.500 ug/L U 6020A 0.500 2.00 6 1 10/21/2015 10/24/2015 11/06/2015 387 58-03 5803-MW09 7440-38-2 14 Arsenic 8.60 ug/L U 6010C 8.60 10.0 10 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW09 7440-39-3 15 Barium 143 ug/L 6010C 5.00 10.0 100 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW09 71-43-2 16 Benzene 0.200 ug/L U 8260B 0.200 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 7440-41-7 23 Beryllium 0.500 ug/L U 6020A 0.500 2.00 1 1 10/21/2015 10/24/2015 10/30/2015 387 58-03 5803-MW09 74-97-5 28 Bromochloromethane 0.150 ug/L U 8260B 0.150 1.00 3 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 75-27-4 29 Bromodichloromethane 0.170 ug/L U 8260B 0.170 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 75-25-2 30 Bromoform 0.290 ug/L U 8260B 0.290 1.00 3 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 7440-43-9 34 Cadmium 0.500 ug/L U 6010C 0.500 1.00 1 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW09 75-15-0 35 Carbon disulfide 0.220 ug/L U 8260B 0.220 1.00 100 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 56-23-5 36 Carbon tetrachloride 0.180 ug/L U 8260B 0.180 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 108-90-7 39 Chlorobenzene 0.180 ug/L U 8260B 0.180 1.00 3 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 75-00-3 41 Chloroethane 0.360 ug/L U 8260B 0.360 1.00 10 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 67-66-3 44 Chloroform 0.230 ug/L U 8260B 0.230 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 7440-47-3 51 Chromium 3.00 ug/L U 6010C 3.00 5.00 10 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW09 156-59-2 78 cis-1,2-Dichloroethene 0.210 ug/L U 8260B 0.210 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 10061-01-5 86 cis-1,3-Dichloropropene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 7440-48-4 53 Cobalt 0.500 ug/L U 6020A 0.500 2.00 10 1 10/21/2015 10/24/2015 10/30/2015 387 58-03 5803-MW09 7440-50-8 54 Copper 5.00 ug/L U 6010C 5.00 10.0 10 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW09 124-48-1 66 Dibromochloromethane 0.250 ug/L U 8260B 0.250 1.00 3 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 100-41-4 110 Ethylbenzene 0.190 ug/L U 8260B 0.190 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 7439-92-1 131 Lead 2.00 ug/L U 6010C 2.00 5.00 10 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW09 7439-97-6 132 Mercury 0.100 ug/L U 7470A 0.100 0.200 0.2 1 10/21/2015 10/27/2015 10/28/2015 387 58-03 5803-MW09 74-83-9 136 Methyl bromide 0.350 ug/L U 8260B 0.350 1.00 10 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 74-87-3 137 Methyl chloride 0.360 ug/L U 8260B 0.360 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 78-93-3 141 Methyl ethyl ketone 2.64 ug/L U 8260B 2.64 50.0 100 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 74-88-4 142 Methyl iodide; Iodomethane 1.50 ug/L U 8260B 1.50 10.0 10 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 74-95-3 139 Methylene bromide 0.450 ug/L U 8260B 0.450 1.00 10 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 75-09-2 140 Methylene Chloride 0.220 ug/L U 8260B 0.220 5.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 7440-02-0 152 Nickel 3.00 ug/L U 6010C 3.00 10.0 50 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW09 95-50-1 69 o-Dichlorobenzene 0.190 ug/L U 8260B 0.190 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 106-46-7 71 p-Dichlorobenzene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 7782-49-2 183 Selenium 5.00 ug/L U 6010C 5.00 10.0 10 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW09 7440-22-4 184 Silver 3.00 ug/L U 6010C 3.00 5.00 10 1 10/21/2015 10/26/2015 10/27/2015 387 58-03 5803-MW09 100-42-5 186 Styrene 0.280 ug/L U 8260B 0.280 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 127-18-4 192 Tetrachloroethene 0.140 ug/L U 8260B 0.140 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 109-99-9 458 Tetrahydrofuran 0.820 ug/L U 8260B 0.820 10.0 NE 1 10/21/2015 10/24/2015 387 P:\Madison County\Reports\2015\Fall\5803-Operating\5803_2015Oct_EDD Page 12 of 17 5803Oct2015EDD FACILITY PERMIT WELL ID CAS Number SWS ID PARAMETER RESULT UNITS QUALIFIER METHOD MDL MRL SWSL DILUTION FACTOR COLLECT DATE EXTRACTION DATE ANALYSIS DATE NC LABORATORY CERTIFICATION NUMBER 58-03 5803-MW09 108-88-3 196 Toluene 0.200 ug/L U 6020A 0.200 2.00 5.5 1 10/21/2015 10/24/2015 10/30/2015 387 58-03 5803-MW09 7440-28-0 194 Thallium 0.170 ug/L U 8260B 0.170 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 156-60-5 79 trans-1,2-Dichloroethene 0.230 ug/L U 8260B 0.230 1.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 10061-02-6 87 trans-1,3-Dichloropropene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 110-57-6 73 trans-1,4-Dichloro-2-butene 0.460 ug/L U 8260B 0.460 5.00 100 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 79-01-6 201 Trichloroethene 0.200 ug/L U 8260B 0.200 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 75-69-4 203 Trichlorofluoromethane 0.210 ug/L U 8260B 0.210 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 7440-62-2 209 Vanadium 3.87 ug/L J 6020A 0.100 2.00 25 1 10/21/2015 10/24/2015 10/30/2015 387 58-03 5803-MW09 108-05-4 210 Vinyl acetate 1.71 ug/L U 8260B 1.71 10.0 50 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 75-01-4 211 Vinyl chloride 0.180 ug/L U 8260B 0.180 1.00 1 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 1330-20-7 346 Xylene (total)0.580 ug/L U 8260B 0.580 3.00 5 1 10/21/2015 10/24/2015 387 58-03 5803-MW09 7440-66-6 213 Zinc 10.0 ug/L U 6020A 10.0 25.0 10 1 10/21/2015 10/24/2015 11/06/2015 387 58-03 5803-MW09 7782-44-7 356 Dissolved Oxygen 1.48 mg/L 10/21/2015 58-03 5803-MW09 SW336 336 Oxygen Reduction Potential 179.3 mV 10/21/2015 58-03 5803-MW09 SW320 320 pH 6.37 SU 10/21/2015 5445 58-03 5803-MW09 SW323 323 Specific Conductivity 138 µS 10/21/2015 58-03 5803-MW09 SW325 325 Temperature 16.96 °C 10/21/2015 58-03 5803-MW09 SW330 330 Turbidity 0.110 NTU 10/21/2015 58-03 5803-MW09 SW318 318 Depth to Water 7.77 ft TOC 10/21/2015 58-03 5803-MW09 SW411 411 Total Well Depth 25.34 ft TOC 58-03 5803-MW09 SW328 328 Top of Casing (TOC) Elevation 1,949.43 feet 58-03 5803-SW01 630-20-6 190 1,1,1,2-Tetrachloroethane 0.150 ug/L U 8260B 0.150 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 71-55-6 200 1,1,1-Trichloroethane 0.190 ug/L U 8260B 0.190 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 79-34-5 191 1,1,2,2-Tetrachloroethane 0.190 ug/L U 8260B 0.190 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 79-00-5 202 1,1,2-Trichloroethane 0.190 ug/L U 8260B 0.190 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 75-34-3 75 1,1-Dichloroethane 0.240 ug/L U 8260B 0.240 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 75-35-4 77 1,1-Dichloroethene 0.250 ug/L U 8260B 0.250 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 96-18-4 206 1,2,3-Trichloropropane 0.230 ug/L U 8260B 0.230 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 96-12-8 67 1,2-Dibromo-3-chloropropane 0.940 ug/L U 8260B 0.940 10.0 13 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 106-93-4 68 1,2-Dibromoethane 0.210 ug/L U 8260B 0.210 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 107-06-2 76 1,2-Dichloroethane 0.200 ug/L U 8260B 0.200 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 78-87-5 82 1,2-Dichloropropane 0.250 ug/L U 8260B 0.250 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 591-78-6 124 2-Hexanone 1.28 ug/L U 8260B 1.28 10.0 50 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 108-10-1 147 4-Methyl-2-pentanone 0.810 ug/L U 8260B 0.810 10.0 100 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 67-64-1 3 Acetone 2.66 ug/L U 8260B 2.66 25.0 100 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 107-13-1 8 Acrylonitrile 0.500 ug/L U 8260B 0.500 10.0 200 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 7440-36-0 13 Antimony 0.500 ug/L U 6020A 0.500 2.00 6 1 10/20/2015 10/23/2015 11/05/2015 387 58-03 5803-SW01 7440-38-2 14 Arsenic 8.60 ug/L U 6010C 8.60 10.0 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-SW01 7440-39-3 15 Barium 149 ug/L 6010C 5.00 10.0 100 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-SW01 71-43-2 16 Benzene 0.200 ug/L U 8260B 0.200 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 7440-41-7 23 Beryllium 0.500 ug/L U 6020A 0.500 2.00 1 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-SW01 74-97-5 28 Bromochloromethane 0.150 ug/L U 8260B 0.150 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 75-27-4 29 Bromodichloromethane 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 75-25-2 30 Bromoform 0.290 ug/L U 8260B 0.290 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 7440-43-9 34 Cadmium 1.70 ug/L 6010C 0.500 1.00 1 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-SW01 75-15-0 35 Carbon disulfide 0.220 ug/L U 8260B 0.220 1.00 100 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 56-23-5 36 Carbon tetrachloride 0.180 ug/L U 8260B 0.180 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 108-90-7 39 Chlorobenzene 0.180 ug/L U 8260B 0.180 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 75-00-3 41 Chloroethane 0.360 ug/L U 8260B 0.360 1.00 10 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 67-66-3 44 Chloroform 0.230 ug/L U 8260B 0.230 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 7440-47-3 51 Chromium 3.10 ug/L J 6010C 3.00 5.00 10 1 10/20/2015 10/23/2015 10/29/2015 387 58-03 5803-SW01 156-59-2 78 cis-1,2-Dichloroethene 0.210 ug/L U 8260B 0.210 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 10061-01-5 86 cis-1,3-Dichloropropene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 P:\Madison County\Reports\2015\Fall\5803-Operating\5803_2015Oct_EDD Page 13 of 17 5803Oct2015EDD FACILITY PERMIT WELL ID CAS Number SWS ID PARAMETER RESULT UNITS QUALIFIER METHOD MDL MRL SWSL DILUTION FACTOR COLLECT DATE EXTRACTION DATE ANALYSIS DATE NC LABORATORY CERTIFICATION NUMBER 58-03 5803-SW01 7440-48-4 53 Cobalt 17.3 ug/L 6020A 0.500 2.00 10 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-SW01 7440-50-8 54 Copper 5.00 ug/L U 6010C 5.00 10.0 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-SW01 124-48-1 66 Dibromochloromethane 0.250 ug/L U 8260B 0.250 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 100-41-4 110 Ethylbenzene 0.190 ug/L U 8260B 0.190 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 7439-92-1 131 Lead 3.80 ug/L J 6010C 2.00 5.00 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-SW01 7439-97-6 132 Mercury 0.100 ug/L U 7470A 0.100 0.200 0.2 1 10/20/2015 10/26/2015 10/26/2015 387 58-03 5803-SW01 74-83-9 136 Methyl bromide 0.350 ug/L U 8260B 0.350 1.00 10 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 74-87-3 137 Methyl chloride 0.360 ug/L U 8260B 0.360 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 78-93-3 141 Methyl ethyl ketone 2.64 ug/L U 8260B 2.64 50.0 100 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 74-88-4 142 Methyl iodide; Iodomethane 1.50 ug/L U 8260B 1.50 10.0 10 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 74-95-3 139 Methylene bromide 0.450 ug/L U 8260B 0.450 1.00 10 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 75-09-2 140 Methylene Chloride 0.220 ug/L U 8260B 0.220 5.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 7440-02-0 152 Nickel 3.00 ug/L U 6010C 3.00 10.0 50 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-SW01 95-50-1 69 o-Dichlorobenzene 0.190 ug/L U 8260B 0.190 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 106-46-7 71 p-Dichlorobenzene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 7782-49-2 183 Selenium 5.00 ug/L U 6010C 5.00 10.0 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-SW01 7440-22-4 184 Silver 3.00 ug/L U 6010C 3.00 5.00 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-SW01 100-42-5 186 Styrene 0.280 ug/L U 8260B 0.280 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 127-18-4 192 Tetrachloroethene 0.140 ug/L U 8260B 0.140 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 109-99-9 458 Tetrahydrofuran 0.820 ug/L U 8260B 0.820 10.0 NE 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 7440-28-0 194 Thallium 0.200 ug/L U 6020A 0.200 2.00 5.5 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-SW01 108-88-3 196 Toluene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 156-60-5 79 trans-1,2-Dichloroethene 0.230 ug/L U 8260B 0.230 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 10061-02-6 87 trans-1,3-Dichloropropene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 110-57-6 73 trans-1,4-Dichloro-2-butene 0.460 ug/L U 8260B 0.460 5.00 100 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 79-01-6 201 Trichloroethene 0.200 ug/L U 8260B 0.200 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 75-69-4 203 Trichlorofluoromethane 0.210 ug/L U 8260B 0.210 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 7440-62-2 209 Vanadium 11.9 ug/L J 6020A 0.100 2.00 25 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-SW01 108-05-4 210 Vinyl acetate 1.71 ug/L U 8260B 1.71 10.0 50 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 75-01-4 211 Vinyl chloride 0.180 ug/L U 8260B 0.180 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 1330-20-7 346 Xylene (total)0.580 ug/L U 8260B 0.580 3.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-SW01 7440-66-6 213 Zinc 12.2 ug/L J 6020A 10.0 25.0 10 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-SW01 7782-44-7 356 Dissolved Oxygen 2.65 mg/L 10/20/2015 58-03 5803-SW01 SW336 336 Oxygen Reduction Potential 128.0 mV 10/20/2015 58-03 5803-SW01 SW320 320 pH 6.10 SU 10/20/2015 5445 58-03 5803-SW01 SW323 323 Specific Conductivity 114 µS 10/20/2015 58-03 5803-SW01 SW325 325 Temperature 14.97 °C 10/20/2015 58-03 5803-SW01 SW330 330 Turbidity 49.11 NTU 10/20/2015 58-03 5803-SW02R 630-20-6 190 1,1,1,2-Tetrachloroethane 0.150 ug/L U 8260B 0.150 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 71-55-6 200 1,1,1-Trichloroethane 0.190 ug/L U 8260B 0.190 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 79-34-5 191 1,1,2,2-Tetrachloroethane 0.190 ug/L U 8260B 0.190 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 79-00-5 202 1,1,2-Trichloroethane 0.190 ug/L U 8260B 0.190 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 75-34-3 75 1,1-Dichloroethane 0.240 ug/L U 8260B 0.240 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 75-35-4 77 1,1-Dichloroethene 0.250 ug/L U 8260B 0.250 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 96-18-4 206 1,2,3-Trichloropropane 0.230 ug/L U 8260B 0.230 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 96-12-8 67 1,2-Dibromo-3-chloropropane 0.940 ug/L U 8260B 0.940 10.0 13 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 106-93-4 68 1,2-Dibromoethane 0.210 ug/L U 8260B 0.210 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 107-06-2 76 1,2-Dichloroethane 0.200 ug/L U 8260B 0.200 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 78-87-5 82 1,2-Dichloropropane 0.250 ug/L U 8260B 0.250 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 591-78-6 124 2-Hexanone 1.28 ug/L U 8260B 1.28 10.0 50 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 108-10-1 147 4-Methyl-2-pentanone 0.810 ug/L U 8260B 0.810 10.0 100 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 67-64-1 3 Acetone 2.66 ug/L U 8260B 2.66 25.0 100 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 107-13-1 8 Acrylonitrile 0.500 ug/L U 8260B 0.500 10.0 200 1 10/20/2015 10/24/2015 387 P:\Madison County\Reports\2015\Fall\5803-Operating\5803_2015Oct_EDD Page 14 of 17 5803Oct2015EDD FACILITY PERMIT WELL ID CAS Number SWS ID PARAMETER RESULT UNITS QUALIFIER METHOD MDL MRL SWSL DILUTION FACTOR COLLECT DATE EXTRACTION DATE ANALYSIS DATE NC LABORATORY CERTIFICATION NUMBER 58-03 5803-SW02R 7440-36-0 13 Antimony 0.500 ug/L U 6020A 0.500 2.00 6 1 10/20/2015 10/23/2015 11/05/2015 387 58-03 5803-SW02R 7440-38-2 14 Arsenic 8.60 ug/L U 6010C 8.60 10.0 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-SW02R 7440-39-3 15 Barium 48.4 ug/L J 6010C 5.00 10.0 100 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-SW02R 71-43-2 16 Benzene 0.200 ug/L U 8260B 0.200 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 7440-41-7 23 Beryllium 0.500 ug/L U 6020A 0.500 2.00 1 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-SW02R 74-97-5 28 Bromochloromethane 0.150 ug/L U 8260B 0.150 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 75-27-4 29 Bromodichloromethane 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 75-25-2 30 Bromoform 0.290 ug/L U 8260B 0.290 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 7440-43-9 34 Cadmium 0.500 ug/L U 6010C 0.500 1.00 1 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-SW02R 75-15-0 35 Carbon disulfide 0.220 ug/L U 8260B 0.220 1.00 100 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 56-23-5 36 Carbon tetrachloride 0.180 ug/L U 8260B 0.180 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 108-90-7 39 Chlorobenzene 0.180 ug/L U 8260B 0.180 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 75-00-3 41 Chloroethane 0.360 ug/L U 8260B 0.360 1.00 10 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 67-66-3 44 Chloroform 0.230 ug/L U 8260B 0.230 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 7440-47-3 51 Chromium 3.00 ug/L U 6010C 3.00 5.00 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-SW02R 156-59-2 78 cis-1,2-Dichloroethene 0.210 ug/L U 8260B 0.210 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 10061-01-5 86 cis-1,3-Dichloropropene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 7440-48-4 53 Cobalt 0.500 ug/L U 6020A 0.500 2.00 10 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-SW02R 7440-50-8 54 Copper 5.00 ug/L U 6010C 5.00 10.0 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-SW02R 124-48-1 66 Dibromochloromethane 0.250 ug/L U 8260B 0.250 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 100-41-4 110 Ethylbenzene 0.190 ug/L U 8260B 0.190 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 7439-92-1 131 Lead 2.00 ug/L J 6010C 2.00 5.00 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-SW02R 7439-97-6 132 Mercury 0.100 ug/L U 7470A 0.100 0.200 0.2 1 10/20/2015 10/26/2015 10/26/2015 387 58-03 5803-SW02R 74-83-9 136 Methyl bromide 0.350 ug/L U 8260B 0.350 1.00 10 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 74-87-3 137 Methyl chloride 0.360 ug/L U 8260B 0.360 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 78-93-3 141 Methyl ethyl ketone 2.64 ug/L U 8260B 2.64 50.0 100 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 74-88-4 142 Methyl iodide; Iodomethane 1.50 ug/L U 8260B 1.50 10.0 10 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 74-95-3 139 Methylene bromide 0.450 ug/L U 8260B 0.450 1.00 10 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 75-09-2 140 Methylene Chloride 0.220 ug/L U 8260B 0.220 5.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 7440-02-0 152 Nickel 3.00 ug/L U 6010C 3.00 10.0 50 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-SW02R 95-50-1 69 o-Dichlorobenzene 0.190 ug/L U 8260B 0.190 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 106-46-7 71 p-Dichlorobenzene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 7782-49-2 183 Selenium 5.00 ug/L U 6010C 5.00 10.0 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-SW02R 7440-22-4 184 Silver 3.00 ug/L U 6010C 3.00 5.00 10 1 10/20/2015 10/23/2015 10/27/2015 387 58-03 5803-SW02R 100-42-5 186 Styrene 0.280 ug/L U 8260B 0.280 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 127-18-4 192 Tetrachloroethene 0.140 ug/L U 8260B 0.140 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 109-99-9 458 Tetrahydrofuran 0.820 ug/L U 8260B 0.820 10.0 NE 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 7440-28-0 194 Thallium 0.200 ug/L U 6020A 0.200 2.00 5.5 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-SW02R 108-88-3 196 Toluene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 156-60-5 79 trans-1,2-Dichloroethene 0.230 ug/L U 8260B 0.230 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 10061-02-6 87 trans-1,3-Dichloropropene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 110-57-6 73 trans-1,4-Dichloro-2-butene 0.460 ug/L U 8260B 0.460 5.00 100 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 79-01-6 201 Trichloroethene 0.200 ug/L U 8260B 0.200 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 75-69-4 203 Trichlorofluoromethane 0.210 ug/L U 8260B 0.210 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 7440-62-2 209 Vanadium 3.08 ug/L J 6020A 0.100 2.00 25 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-SW02R 108-05-4 210 Vinyl acetate 1.71 ug/L U 8260B 1.71 10.0 50 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 75-01-4 211 Vinyl chloride 0.180 ug/L U 8260B 0.180 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 1330-20-7 346 Xylene (total)0.580 ug/L U 8260B 0.580 3.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-SW02R 7440-66-6 213 Zinc 10.0 ug/L U 6020A 10.0 25.0 10 1 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-SW02R 7782-44-7 356 Dissolved Oxygen 12.09 mg/L 10/20/2015 58-03 5803-SW02R SW336 336 Oxygen Reduction Potential 130.6 mV 10/20/2015 58-03 5803-SW02R SW320 320 pH 7.30 SU 10/20/2015 5445 58-03 5803-SW02R SW323 323 Specific Conductivity 112 µS 10/20/2015 P:\Madison County\Reports\2015\Fall\5803-Operating\5803_2015Oct_EDD Page 15 of 17 5803Oct2015EDD FACILITY PERMIT WELL ID CAS Number SWS ID PARAMETER RESULT UNITS QUALIFIER METHOD MDL MRL SWSL DILUTION FACTOR COLLECT DATE EXTRACTION DATE ANALYSIS DATE NC LABORATORY CERTIFICATION NUMBER 58-03 5803-SW02R SW325 325 Temperature 10.82 °C 10/20/2015 58-03 5803-SW02R SW330 330 Turbidity 1.55 NTU 10/20/2015 58-03 5803-LT01 630-20-6 190 1,1,1,2-Tetrachloroethane 0.150 ug/L U 8260B 0.150 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 71-55-6 200 1,1,1-Trichloroethane 0.190 ug/L U 8260B 0.190 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 79-34-5 191 1,1,2,2-Tetrachloroethane 0.190 ug/L U 8260B 0.190 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 79-00-5 202 1,1,2-Trichloroethane 0.190 ug/L U 8260B 0.190 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 75-34-3 75 1,1-Dichloroethane 0.240 ug/L U 8260B 0.240 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 75-35-4 77 1,1-Dichloroethene 0.250 ug/L U 8260B 0.250 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 96-18-4 206 1,2,3-Trichloropropane 0.230 ug/L U 8260B 0.230 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 96-12-8 67 1,2-Dibromo-3-chloropropane 0.940 ug/L U 8260B 0.940 10.0 13 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 106-93-4 68 1,2-Dibromoethane 0.210 ug/L U 8260B 0.210 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 107-06-2 76 1,2-Dichloroethane 0.200 ug/L U 8260B 0.200 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 78-87-5 82 1,2-Dichloropropane 0.250 ug/L U 8260B 0.250 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 591-78-6 124 2-Hexanone 1.28 ug/L U 8260B 1.28 10.0 50 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 108-10-1 4-Methyl-2-pentanone 0.810 ug/L U 8260B 0.810 10.0 100 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 67-64-1 3 Acetone 5.46 ug/L J 8260B 2.66 25.0 100 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 107-13-1 8 Acrylonitrile 0.500 ug/L U 8260B 0.500 10.0 200 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 7440-36-0 13 Antimony 25.0 ug/L U 6020A 25.0 100 6 50 10/20/2015 10/23/2015 11/05/2015 387 58-03 5803-LT01 7440-38-2 14 Arsenic 43 ug/L U 6010C 43 50 10 5 10/20/2015 10/23/2015 10/28/2015 387 58-03 5803-LT01 7440-39-3 15 Barium 17,400 ug/L 6010C 25 50 100 5 10/20/2015 10/23/2015 10/28/2015 387 58-03 5803-LT01 71-43-2 16 Benzene 0.200 ug/L U 8260B 0.200 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 7440-41-7 23 Beryllium 31.2 ug/L J 6020A 25.0 100 1 50 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-LT01 SW316 316 Biochemical Oxygen Demand 400,000 ug/L U SM5210B 400,000 400,000 NE 20 10/20/2015 10/21/2015 387 58-03 5803-LT01 74-97-5 28 Bromochloromethane 0.150 ug/L U 8260B 0.150 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 75-27-4 29 Bromodichloromethane 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 75-25-2 30 Bromoform 0.290 ug/L U 8260B 0.290 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 7440-43-9 34 Cadmium 62.5 ug/L 6010C 2.5 5 1 5 10/20/2015 10/23/2015 10/28/2015 387 58-03 5803-LT01 75-15-0 35 Carbon disulfide 0.220 ug/L U 8260B 0.220 1.00 100 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 56-23-5 36 Carbon tetrachloride 0.180 ug/L U 8260B 0.180 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 SW317 317 Chemical Oxygen Demand 356,000 ug/L SM 5220D 40,000 200,000 NE 10 10/20/2015 10/22/2015 387 58-03 5803-LT01 108-90-7 39 Chlorobenzene 0.180 ug/L U 8260B 0.180 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 75-00-3 41 Chloroethane 0.360 ug/L U 8260B 0.360 1.00 10 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 67-66-3 44 Chloroform 0.230 ug/L U 8260B 0.230 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 7440-47-3 51 Chromium 409 ug/L 6010C 15 25 10 5 10/20/2015 10/23/2015 10/29/2015 387 58-03 5803-LT01 156-59-2 78 cis-1,2-Dichloroethene 0.210 ug/L U 8260B 0.210 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 10061-01-5 86 cis-1,3-Dichloropropene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 7440-48-4 53 Cobalt 2,010 ug/L 6020A 25.0 100 10 50 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-LT01 7440-50-8 54 Copper 41.5 ug/L J 6010C 25 50 10 5 10/20/2015 10/23/2015 10/28/2015 387 58-03 5803-LT01 124-48-1 66 Dibromochloromethane 0.250 ug/L U 8260B 0.250 1.00 3 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 100-41-4 110 Ethylbenzene 0.190 ug/L U 8260B 0.190 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 7439-92-1 131 Lead 10 ug/L U 6010C 10 25 10 5 10/20/2015 10/23/2015 10/28/2015 387 58-03 5803-LT01 7439-97-6 132 Mercury 0.118 ug/L J 7470A 0.100 0.200 0.2 1 10/20/2015 10/22/2015 10/22/2015 387 58-03 5803-LT01 74-83-9 136 Methyl bromide 0.350 ug/L U 8260B 0.350 1.00 10 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 74-87-3 137 Methyl chloride 0.360 ug/L U 8260B 0.360 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 78-93-3 Methyl ethyl ketone 2.64 ug/L U 8260B 2.64 50.0 100 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 74-88-4 142 Methyl iodide; Iodomethane 1.50 ug/L U 8260B 1.50 10.0 10 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 74-95-3 139 Methylene bromide 0.450 ug/L U 8260B 0.450 1.00 10 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 75-09-2 140 Methylene Chloride 0.220 ug/L U 8260B 0.220 5.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 7440-02-0 152 Nickel 439 ug/L 6010C 15 50 50 5 10/20/2015 10/23/2015 10/28/2015 387 58-03 5803-LT01 14797-55-8 303 Nitrate as N 20400 ug/L Nitrate by calc 40 100 10,000 1 10/20/2015 10/21/2015 387 58-03 5803-LT01 95-50-1 69 o-Dichlorobenzene 0.190 ug/L U 8260B 0.190 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 106-46-7 71 p-Dichlorobenzene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 7723-14-0 412 Phosphorus, Total 1240 ug/L 365.4 50 100 NE 1 10/20/2015 11/03/2015 11/03/2015 387 P:\Madison County\Reports\2015\Fall\5803-Operating\5803_2015Oct_EDD Page 16 of 17 5803Oct2015EDD FACILITY PERMIT WELL ID CAS Number SWS ID PARAMETER RESULT UNITS QUALIFIER METHOD MDL MRL SWSL DILUTION FACTOR COLLECT DATE EXTRACTION DATE ANALYSIS DATE NC LABORATORY CERTIFICATION NUMBER 58-03 5803-LT01 7782-49-2 183 Selenium 25 ug/L U 6010C 25 50 10 5 10/20/2015 10/23/2015 10/28/2015 387 58-03 5803-LT01 7440-22-4 184 Silver 22 ug/L J *6010C 15 25 10 5 10/20/2015 10/23/2015 10/29/2015 387 58-03 5803-LT01 100-42-5 186 Styrene 0.280 ug/L U 8260B 0.280 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 14808-79-8 315 Sulfate 105000 ug/L F1 300.0 600 1,000 250,000 1 10/20/2015 11/03/2015 387 58-03 5803-LT01 127-18-4 192 Tetrachloroethene 0.140 ug/L U 8260B 0.140 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 109-99-9 458 Tetrahydrofuran 0.820 ug/L U 8260B 0.820 10.0 NE 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 7440-28-0 194 Thallium 10.0 ug/L U 6020A 10.0 100 5.5 50 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-LT01 108-88-3 196 Toluene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 156-60-5 79 trans-1,2-Dichloroethene 0.230 ug/L U *8260B 0.230 1.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 10061-02-6 87 trans-1,3-Dichloropropene 0.170 ug/L U 8260B 0.170 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 110-57-6 73 trans-1,4-Dichloro-2-butene 0.460 ug/L U 8260B 0.460 5.00 100 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 79-01-6 201 Trichloroethene 0.200 ug/L U 8260B 0.200 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 75-69-4 203 Trichlorofluoromethane 0.512 ug/L J 8260B 0.210 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 7440-62-2 209 Vanadium 158 ug/L 6020A 5.00 100 25 50 10/20/2015 10/23/2015 11/05/2015 387 58-03 5803-LT01 108-05-4 210 Vinyl acetate 1.71 ug/L U 8260B 1.71 10.0 50 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 75-01-4 211 Vinyl chloride 0.180 ug/L U 8260B 0.180 1.00 1 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 1330-20-7 346 Xylene (total)0.580 ug/L U 8260B 0.580 3.00 5 1 10/20/2015 10/24/2015 387 58-03 5803-LT01 7440-66-6 213 Zinc 19800 ug/L 6020A 500 1,250 10 50 10/20/2015 10/23/2015 10/30/2015 387 58-03 5803-LT01 7782-44-7 356 Dissolved Oxygen 6.65 mg/L 10/20/2015 58-03 5803-LT01 SW336 336 Oxygen Reduction Potential 143.0 mV 10/20/2015 58-03 5803-LT01 SW320 320 pH 7.96 SU 10/20/2015 5445 58-03 5803-LT01 SW323 323 Specific Conductivity 2,025 µS 10/20/2015 58-03 5803-LT01 SW325 325 Temperature 18.54 °C 10/20/2015 58-03 5803-LT01 SW330 330 Turbidity 955.2 NTU 10/20/2015 P:\Madison County\Reports\2015\Fall\5803-Operating\5803_2015Oct_EDD Page 17 of 17