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HomeMy WebLinkAbout3404_CityOfKernersville_GWMReport_DIN26394_20151119[ i R U S E O N L Y E ] j D P a p e r R e p o r t F i E l e c t r o n i c D a t a - E m a i l C D ( d a t a l o a d e d : Y e s / N o ) D o c / E v e n t # : N C D E N R E n v i r o n m e n t a l M o n i t o r i n g D i v i s i o n o f W a s t e M a n a g e m e n t - S o l i d W a s t e R e p o r t i n g F o r m N o t i c e : T h i s f o r m a n d a n y i n f o r m a t i o n a t t a c h e d t o i t a r e ‘ P u b l i c R e c o r d s ’ a s d e f i n e d i n N C G e n e r a l S t a t u t e 1 3 2 - 1 . A s s u c h , t h e s e d o c u m e n t s a r e a v a i l a b l e f o r i n s p e c t i o n a n d e x a m i n a t i o n b y a n y p e r s o n u p o n r e q u e s t ( N C G e n e r a l S t a t u t e 1 3 2 - 6 ) . I n s t r u c t i o n s : • P r e p a r e o n e f o r m f o r e a c h i n d i v i d u a l l y m o n i t o r e d u n i t . • P l e a s e t y p e o r p r i n t l e g i b l y . A t t a c h a n o t i f i c a t i o n t a b l e w i t h v a l u e s t h a t a t t a i n o r e x c e e d N C 2 L g r o u n d w a t e r s t a n d a r d s o r N C 2 B s u r f a c e w a t e r s t a n d a r d s . T h e n o t i f i c a t i o n m u s t i n c l u d e a p r e l i m i n a r y a n a l y s i s o f t h e c a u s e a n d s i g n i f i c a n c e o f e a c h v a l u e . ( e . g . n a t u r a l l y o c c u r r i n g , o f f - s i t e s o u r c e . p r e - e x i s t i n g c o n d i t i o n , e t c . ) . • A t t a c h a n o t i f i c a t i o n t a b l e o f a n y g r o u n d w a t e r o r s u r f a c e w a t e r v a l u e s t h a t e q u a l o r e x c e e d t h e r e p o r t i n g l i m i t s . • A t t a c h a n o t i f i c a t i o n t a b l e o f a n y m e t h a n e g a s v a l u e s t h a t a t t a i n o r e x c e e d e x p l o s i v e g a s l e v e l s . T h i s i n c l u d e s a n y s t r u c t u r e s o n o r n e a r b y t h e f a c i l i t y ( N C A C 1 3 B . 1 6 2 9 ( 4 ) ( a ) ( i ) . • S e n d t h e o r i g i n a l s i g n e d a n d s e a l e d f o r m , a n y t a b l e s , a n d E l e c t r o n i c D a t a D e l i v e r a b l e t o : C o m p l i a n c e U n i t , N C D E N R - D W M , S o l i d W a s t e S e c t i o n , 1 6 4 6 M a i l S e r v i c e C e n t e r , R a l e i g h , N C 2 7 6 9 9 - 1 6 4 6 . S o l i d W a s t e M o n i t o r i n g D a t a S u b m i t t a l I n f o r m a t i o n N a m e o f e n t i t y s u b m i t t i n g d a t a ( l a b o r a t o r y , c o n s u l t a n t , f a c i l i t y o w n e r ) : J o y c e E n g i n e e r i n g C o n t a c t f o r q u e s t i o n s a b o u t d a t a f o r m a t t i n g . I n c l u d e d a t a p r e p a r e r ’ s n a m e , t e l e p h o n e n u m b e r a n d E - m a i l a d d r e s s : N a m e : H a n n u K e m p p i n e n P G . P h o n e : ( 3 3 6 ) - 3 2 3 - 0 0 9 2 E - m a i l : h k e m p p i n @ j o y c e e n g i n e e r i n g . c o m N C L a n d f i l l R u l e : A c t u a l s a m p l i n g d a t e s ( e . g . , F a c i l i t y n a m e : F a c i l i t y A d d r e s s : F a c i l i t y P e r m i t # ( . 0 5 0 0 o r . 1 6 0 0 ) O c t o b e r 2 0 - 2 4 , 2 0 0 6 ) . F r e e m a n R o a d T o w n o f K e r n e r s v i l l e L a n d f i l l . 3 4 - 0 4 . 0 5 0 0 N o v e m b e r 1 9 , 2 0 1 5 K e r n e r s v i l l e , N C 2 7 2 8 4 E n v i r o n m e n t a l S t a t u s : ( C h e c k a l l t h a t a p p l y ) I n i t i a l / B a c k g r o u n d M o n i t o r i n g j D e t e c t i o n M o n i t o r i n g j A s s e s s m e n t M o n i t o r i n g j C o r r e c t i v e A c t i o n T e o f d a t a s u b m i t t e d : ( C h e c k a l l t h a t a p p l y ) G r o u n d w a t e r m o n i t o r i n g d a t a f r o m m o n i t o r i n g w e l l s j M e t h a n e g a s m o n i t o r i n g d a t a G r o u n d w a t e r m o n i t o r i n g d a t a f r o m p r i v a t e w a t e r s u p p l y w e l l s C o r r e c t i v e a c t i o n d a t a ( s p e c i f y ) M N A L e a c h a t e m o n i t o r i n g d a t a X S u r f a c e w a t e r m o n i t o r i n g d a t a E l O t h e r ( s p e c i f y ) N o t i f i c a t i o n a t t a c h e d ? N o . N o g r o u n d w a t e r o r s u r f a c e w a t e r s t a n d a r d s w e r e e x c e e d e d . X Y e s , a n o t i f i c a t i o n o f v a l u e s e x c e e d i n g a g r o u n d w a t e r o r s u r f a c e w a t e r s t a n d a r d i s a t t a c h e d . I t i n c l u d e s a l i s t o f g r o u n d w a t e r a n d s u r f a c e w a t e r m o n i t o r i n g p o i n t s , d a t e s , a n a l y t i c a l v a l u e s , N C 2 L g r o u n d w a t e r s t a n d a r d , N C 2 B s u r f a c e w a t e r s t a n d a r d o r N C S o l i d W a s t e G W P S a n d p r e l i m i n a r y a n a l y s i s o f t h e c a u s e a n d s i g n i f i c a n c e o f a n y c o n c e n t r a t i o n . E l Y e s , a n o t i f i c a t i o n o f v a l u e s e x c e e d i n g a n e x p l o s i v e m e t h a n e g a s l i m i t i s a t t a c h e d . I t i n c l u d e s t h e m e t h a n e m o n i t o r i n g p o i n t s , d a t e s , s a m p l e v a l u e s a n d e x p l o s i v e m e t h a n e g a s l i m i t s . C e r t i f i c a t i o n T o t h e b e s t o f m y k n o w l e d g e , t h e i n f o r m a t i o n r e p o r t e d a n d s t a t e m e n t s m a d e o n t h i s d a t a s u b m i t t a l a n d a t t a c h m e n t s a r e t r u e a n d c o r r e c t . F u r t h e r m o r e , I h a v e a t t a c h e d c o m p l e t e n o t i f i c a t i o n o f a n y s a m p l i n g v a l u e s m e e t i n g o r e x c e e d i n g g r o u n d w a t e r s t a n d a r d s o r e x p l o s i v e g a s l e v e l s , a n d a p r e l i m i n a r y a n a l y s i s o f t h e c a u s e a n d s i g n i f i c a n c e o f c o n c e n t r a t i o n s e x c e e d i n g g r o u n d w a t e r s t a n d a r d s . I a m a w a r e t h a t t h e r e a r e s i g n i f i c a n t p e n a l t i e s f o r m a k i n g a n y f a l s e s t a t e m e n t , r e p r e s e n t a t i o n , o r c e r t i f i c a t i o n i n c l u d i n g t h e p o s s i b i l i t y o f a f i n e a n d i m p r i s o n m e n t . S e n i o r P r o j e c t C o n s u l t a n t S i g n a t u r e D a t e 2 2 1 1 W . M e a d o w v i e w R d . S t e . 1 0 1 , G r e e n s b o r o , N C 2 7 4 0 7 F a c i l i t y R e p r e s e n t a t i v e A d d r e s s C - 0 7 8 2 H a n n u K e m p p i n e n P . G . F a c i l i t y R e p r e s e n t a t i v e N a m e ( P r i n t ) T i t l e ( 3 3 6 ) - 3 2 3 - 0 0 9 2 ( A r e a C o d e ) T e l e p h o n e N u m b e r / 2 . 2 o i A f f i x N C L i c e n s e d / N C P E F i r m L i c e n s e N u m b e r ( i f a p p l i c a b l e e f f e c t i v e M a y 1 , 2 0 0 9 ) R e v i s e d 6 / 2 0 0 9 2211 W. Meadowview Rd., #101 Greensboro, NC 27409 tel: 336/323-0092 fax: 336/323-0093 www.JoyceEngineering.com February 12, 2016 Ms. Jaclynne Drummond Compliance Hydrogeologist NC Department of Environment and Natural Resources Division of Waste Management – Solid Waste Section 2090 US Highway 70 Swannanoa, Nc 28778 RE: Second Semiannual Water Quality Monitoring Report of 2015 Town of Kernersville Landfill, Permit No. 34-04 Forsyth County, North Carolina JOYCE Project No. 00838.1601.12 Task No. 02 Dear Ms. Drummond: On behalf of the Town of Kernersville, Joyce Engineering is submitting the First Semiannual Water Quality Monitoring Report of 2015 for the closed Town of Kernersville Landfill, Permit No. 34-04. The attached report contains electronic versions of the complete report and all appendices for the November 2015 sampling event. Also attached is the North Carolina Environmental Monitoring Reporting Form for the November 2015 monitoring event. If you wish to have a hard copy of the report, drawings, or appendices, we will be happy to provide it upon your request. Please feel free to contact me or Alex Everhart at (336) 323-0092 if you have any questions regarding this report. Sincerely, JOYCE ENGINEERING Hannu Kemppinen P.G. Senior Project Consultant Attachment C: Thad Buck – Town of Kernersville, Solid Waste Superintendent PREPARED FOR: TOWN OF KERNERSVILLE PUBLIC WORKS DEPARTMENT P.O. BOX 728 KERNERSVILLE, NORTH CAROLINA 27285-0728 TOWN OF KERNERSVILLE LANDFILL PERMIT NO. 34-04 SECOND SEMIANNUAL WATER QUALITY MONITORING REPORT OF 2015 JANUARY 2016 PREPARED BY: 2211 WEST MEADOWVIEW ROAD, SUITE 101 GREENSBORO, NORTH CAROLINA 27407 NC LICENSE NUMBER C-0782 PHONE: (336) 323-0092 FAX: (336) 323-0093 JOYCE PROJECT NO. 838.1601.12 ______________________________________________________________________________ Second Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering Town of Kernersville Landfill, Permit No. 34-04 January 2016 i Second Semiannual Water Quality Monitoring Report of 2015 Town of Kernersville Landfill Forsyth County, North Carolina TABLE OF CONTENTS 1.0 INTRODUCTION............................................................................................................. 1 1.1 Site Information .................................................................................................................. 1 1.2 Site Geology and Hydrogeology ......................................................................................... 1 1.3 Regulatory Status ................................................................................................................ 1 2.0 FACILITY MONITORING PROGRAM ...................................................................... 2 2.1 Groundwater Monitoring Program ..................................................................................... 2 2.2 Surface Water Monitoring Program .................................................................................... 3 3.0 SECOND SEMIANNUAL SAMPLING EVENT OF 2015 ........................................... 3 3.1 Field Work and Visual Inspection ...................................................................................... 3 3.2 Laboratory Analysis and Quality Control ........................................................................... 4 4.0 DATA ANALYSIS ............................................................................................................ 5 4.1 Groundwater Data Analysis and Comparisons to Standards .............................................. 5 4.2 Surface Water Data Analysis and Comparisons to Standards ............................................ 5 5.0 EVALUATION OF MONITORED NATURAL ATTENUATION (MNA)................ 6 5.1 MNA Parameters and Biodegradation Screening Matrix ................................................... 6 6.0 CONCLUSION ................................................................................................................. 7 7.0 REFERENCES .................................................................................................................. 7 Tables Table 1A Summary of Historical Groundwater Elevations Table 1B Monitoring Well and Boring Completion Summary Table 2 Summary of Estimated Hydraulic Gradient and Linear Velocity Table 3 Summary of Historical Groundwater Constituents Table 4 Summary of Historical Surface Water Constituents Table 5 Summary of MNA Constituents Table 6 MNA Screening Matrix ______________________________________________________________________________ Second Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering Town of Kernersville Landfill, Permit No. 34-04 January 2016 ii Second Semiannual Water Quality Monitoring Report of 2015 Town of Kernersville Landfill Forsyth County, North Carolina TABLE OF CONTENTS (Continued) Figure Figure 1 Site Location Map Drawing Drawing 1 Potentiometric Surface Contour Map Appendices Appendix I Laboratory Analytical Reports and Field Data Logs Appendix II Summary of Detected Constituents Appendix III Summary of Exceedances Appendix IV Summary of Field Parameters ______________________________________________________________________________ Second Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering Town of Kernersville Landfill, Permit No. 34-04 January 2016 1 1.0 INTRODUCTION 1.1 Site Information The Town of Kernersville Landfill is a closed, unlined municipal solid waste (MSW) landfill located on approximately 58.2 acres in Forsyth and Guilford Counties, NC, approximately 10 miles north of the City of Kernersville. The waste disposal area comprises approximately 13.8 acres. The property boundary is indicated on an excerpt from the 7.5 minutes USGS topographic map for Belews Creek, North Carolina (Figure 1). The facility was issued a Permit to Operate on May 15, 1985 and a letter of closure was issued on December 10, 1991. The area surrounding the landfill is zoned residential/agricultural and contains open fields and woodlands. The landfill is separated to the North from the Waste Management Piedmont Landfill and Recycling Center Facility by Freeman Road. The landfill is bounded to the south by an unnamed tributary of Belews Creek. 1.2 Site Geology and Hydrogeology The Town of Kernersville Landfill is located in the Piedmont physiographic providence of North Carolina and is underlain by intrusive granitic rocks of Pennsylvanian to Permian age which are part of the Charlotte Belt Geologic Unit. The uppermost aquifer is unconfined and includes both saprolite and uppermost fractured bedrock, which are well connected. The groundwater level measurements taken on November 19, 2015, were used to construct the groundwater surface contours shown in Drawing 1. Historical static water levels are provided in Table 1A. Well construction parameters can be found in Table 1B. Groundwater flow at the site is generally to the southwest. Using the hydraulic gradients along the flow paths shown on Drawing 1, the linear flow velocity (V) was estimated using the modified Darcy equation: V=Ki/n. The hydraulic gradient (i) is 0.03 ft/ft. An effective porosity value (n) of 30 percent was estimated and a hydraulic conductivity (K) 1.73 ft/day was estimated from slug tests completed by JOYCE in November 2013 at the Town of Kernersville Landfill. The calculated groundwater flow rate averages approximately 63.26 ft/year. A summary of the hydraulic gradients and linear flow velocities is provided in Table 2. 1.3 Regulatory Status The Town of Kernersville Landfill is currently monitoring groundwater in accordance with criteria set forth in Title 15A Subchapter 13B .0500 of the North Carolina Solid Waste Management Rules (NCSWMR) for municipal solid waste landfills (MSWLF) closed prior to October 9, 1993. ______________________________________________________________________________ Second Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering Town of Kernersville Landfill, Permit No. 34-04 January 2016 2 Based on the presence of constituents above 2L standards that could potentially be crossing the facility boundary, NCDENR requested that Kernersville submit a Groundwater Assessment Plan to evaluate site conditions as they relate to groundwater quality. The Groundwater Assessment Report was submitted to NCDENR on May 13, 2013. The Groundwater Assessment Report concluded that, based on site hydrogeology, it is very unlikely that the site impacts above 2L standards are crossing the boundary. In a July 16, 2013, response to the Groundwater Assessment Report, NCDENR determined that despite the conclusion of the Assessment Report, the detection of VOCs at concentrations that exceed 2L standards beyond the compliance boundary of the site constitutes a violation of Solid Waste Section regulations. As required by NCDENR JOYCE submitted a Corrective Action Plan (CAP) on behalf of the Town of Kernersville Landfill in July 2014. NCDENR approved the Corrective Action Plan in a letter dated November 4, 2014. 2.0 FACILITY MONITORING PROGRAM 2.1 Groundwater Monitoring Program The current groundwater compliance monitoring network includes six monitoring wells, including one upgradient well and five downgradient wells. These wells are summarized below, along with their current monitoring program status. Monitoring Well Classification Monitoring Program Total Depth from TOC (ft) MW-1 Former Background Water Levels Only 34.69 MW-2 Compliance/MNA Detection (.0500)/CAP 13.18 MW-3S Compliance/MNA Detection (.0500)/CAP 24.00 MW-3D Compliance/MNA Detection (.0500)/CAP 56.96 MW-4 Compliance/MNA Detection (.0500)/CAP 14.40 MW-5 Compliance Detection (.0500) 11.36 MW-6 Background/MNA Detection (.0500)/CAP 20.46 *TOC = Top of casing. Corrective Action Plan (CAP): Monitored Natural Attenuation (MNA) and Phytoremediation The locations of the monitoring wells are shown on Drawing 1. Existing monitoring well MW-6 serves as the background well for the facility. Monitoring well MW-6 replaced MW-1 as the facility’s background well due to infrequent opportunities to sample the well as a result of low well volumes or the well-being dry. Downgradient monitoring wells MW-2, -3S, -3D, -4, and -5 are monitored as part of the compliance network for the facility. MW-1 is monitored for water levels only, as conditions permit. As a condition of the CAP monitoring wells MW-2, -3S, -3D, -4 and -6 are now monitored for the MNA constituents; nitrate, sulfate, chloride, sulfide, alkalinity, total organic carbon, methane, ethane, ethene, volatile fatty acids, dissolved hydrogen, biological oxygen demand, chemical oxygen demand. ______________________________________________________________________________ Second Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering Town of Kernersville Landfill, Permit No. 34-04 January 2016 3 Groundwater samples are collected semiannually during the second and fourth quarters. Samples are analyzed for all constituents listed in the NCSWMR Appendix I and MNA parameters during both the first and second semiannual events. 2.2 Surface Water Monitoring Program Surface water at the Town of Kernersville Landfill is monitored semiannually in conjunction with the groundwater sampling events. Samples are collected from three surface water monitoring points (SW-1, SW-2, and SW-3). The locations of the surface water monitoring points are shown on Drawing No. 1. Surface water samples are collected and analyzed for the NCSWMR Appendix I list of constituents during both semiannual monitoring events. The results are compared to the 15A NCAC 2B (NC 2B) Surface Water Standards in a value-to-value comparison. These surface water monitoring points are summarized below, along with their current monitoring program status. Surface Point Classification Monitoring Program SW-1 Up Stream/Compliance Surface Water SW-2 Compliance Surface Water SW-3 Compliance Surface Water 3.0 SECOND SEMIANNUAL SAMPLING EVENT OF 2015 3.1 Field Work and Visual Inspection In order to detect potential releases of leachate and/or landfill gas migration in a timely manner, a visual inspection program has been implemented at the Town of Kernersville Landfill. This inspection program involves field personnel making the following observations:  Observation of stress induced on the biological community (i.e., dead or dying vegetation),  Indications of leachate impact (i.e., seeps, impacted surface water),  Observations of erosion; and  Negative changes around the waste facility. On November 19, 2015, Joyce Engineering (JOYCE) personnel visited the facility to purge and sample the facility’s monitoring wells MW-2, MW-3S, MW-3D, MW-4 and MW-5. Well MW-6 was dry and was not sampled. Prior to purging, the depth to static water level was measured for all monitoring wells with an electronic water level indicator, accurate to 0.01 foot. MW-1 was measured for a static water level only. Monitoring wells were purged and sampled using either disposable bailers or a peristaltic pump. Measurements of temperature, pH, specific conductivity, dissolved oxygen, oxidation reduction ______________________________________________________________________________ Second Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering Town of Kernersville Landfill, Permit No. 34-04 January 2016 4 potential and turbidity were recorded in the site specific log book prior to purging, after each purge volume, and during sampling. Prior to sampling, laboratory-supplied containers were prepared with the following information:  Monitoring well number (completed by field personnel),  Date and time of sample collection (completed by field personnel),  Initials of sampling personnel (completed by field personnel),  Project name and number (completed by the laboratory),  Chemical preservative (completed by the laboratory); and  Requested chemical analysis (completed by the laboratory). Groundwater samples from each monitoring well were collected directly from the disposable bailers in the provided laboratory containers either immediately after purging or within 24 hours of the final purge volume. Immediately after collection, the samples were placed in a laboratory provided cooler and chilled on ice. Field data logs are provided in the Appendix to this report. Surface water samples were collected directly from stream flow, by lowering the prepared sample containers into the stream flow with the opening facing into the current flow. Care was taken not to overflow the sample containers (which could lead to preservative loss) and avoid sample-induced turbidity. At the time of sampling, surface water was also measured for temperature, pH, specific conductivity, and turbidity. After sample collection, the samples were placed in a laboratory provided cooler and chilled on ice. Field data logs are provided in the Appendix. 3.2 Laboratory Analysis and Quality Control The November 2015 groundwater and surface water samples were submitted to Pace Analytical Services, Inc. of Huntersville, North Carolina under chain-of-custody control for analysis. As presented earlier, the groundwater samples were analyzed for the NCSWMR Appendix I and MNA constituents. JOYCE requested a Level II data report for the final laboratory report. The samples were received by the laboratory on November 20, 2015, in good condition, properly preserved, and within analysis hold times. In addition to samples collected for compliance monitoring at the Town of Kernersville Landfill, a Field Blank was collected by JOYCE personnel as part of the November 2015 sampling event. Also, a Trip Blank was prepared by the laboratory to accompany the volatile sampling containers during shipment to and from the laboratory. The November 2015 Field Blank was analyzed for the NCSWMR Appendix I constituents while the November 2015 Trip Blank was analyzed for the NCSWMR Appendix I volatile organics only. Upon receipt of the laboratory data package, the data was reviewed by JOYCE personnel for the following:  General typographical errors, ______________________________________________________________________________ Second Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering Town of Kernersville Landfill, Permit No. 34-04 January 2016 5  Correct analyses performed and within method specified hold times,  Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate, and Laboratory Control Samples,  Blank qualified data (B-flags),  Detections above the groundwater and surface water standards; and  Detections that are above historical levels. 4.0 DATA ANALYSIS 4.1 Groundwater Data Analysis and Comparisons to Standards Results from the November 2015 sampling event were received December 22, 2015, from Pace and are found in the Appendix. Analytical results from monitoring wells were compared directly to the NC 2L Groundwater Standards (NC 2L) or Groundwater Protection Standards (GWPS). The following inorganic and organic constituents were detected at quantified concentrations in groundwater during the November 2015 sampling event. All concentrations are reported in micrograms per liter (µg/L). Concentrations with a “J” are considered to be estimated. Highlighted concentrations were detected above the NC 2L or GWPS in downgradient wells. Constituent NC2L/ (GWPS) Background Downgradient Blanks MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Barium 700 Dry 294 108 42.2 J 101 60.3 J ND Thallium 0.28 Dry ND ND 8.8 8.8 ND ND Zinc 1,000 Dry ND 23.1 7.3 J 10.7 16.3 ND Benzene 1 Dry 6.0 ND 0.37 J ND ND ND 1,4-Dichlorobenzene 6 Dry 4.8 1.4 3.5 2.5 ND ND 1,1-Dichloroethane 6 Dry 20.7 0.82 J 3.1 J 1.8 J ND ND 1,2 Dichloroethane 0.4 Dry 0.86 J 0.40 J 1.1 ND ND ND Cis-1,2-Dichloroethylene 70 Dry 44.4 5.6 51.2 18.8 ND ND 1,2-Dichloropropane 0.6 Dry 4.3 ND 1.1 ND ND ND Trichloroethylene 3 Dry 4.7 ND ND ND ND ND Vinyl Chloride 0.03 Dry 7.7 2.0 6.7 17.3 ND ND *ND = Not Detected above laboratory detection limits *NS= Well was bent and not sampled *J= Estimated In general, the organic and inorganic results are consistent with historical data. Historical groundwater data can be found in Table 3. The results, as reported by the laboratory, the laboratory quality/assurance/quality control information, and the chain-of-custody records are included in the Appendix. 4.2 Surface Water Data Analysis and Comparisons to Standards Zinc was detected above the NC SWSL in SW-3; however, it was below the NC 2B. There were no other constituent s detected at quantified concentrations or above the NC 2B standards in the surface waters during the November 2015 sampling event. In general, the results are consistent with historical data. Historical surface water data can be found in Table 4. The results, as ______________________________________________________________________________ Second Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering Town of Kernersville Landfill, Permit No. 34-04 January 2016 6 reported by the laboratory, the laboratory quality/assurance/quality control information, and the chain-of-custody records are included in the Appendix. 5.0 EVALUATION OF MONITORED NATURAL ATTENUATION (MNA) 5.1 MNA Parameters and Biodegradation Screening Matrix In accordance with the CAP for the facility, MNA baseline sampling was initiated with the November 2015 sampling event. The November 2015 sampling event will be the fourth and final baseline sampling event for MNA. During the November 2015 sampling event the full list of MNA parameters were obtained for the following wells: MW-2, MW-3S, MW-3D, and MW- 4. MW-6 was dry and was not sampled. MNA parameters included field parameters temperature, pH, specific conductance, oxidation reduction potential, turbidity, dissolved oxygen, as well as laboratory parameters dissolved hydrogen, nitrate, sulfate, chloride, alkalinity, sulfide TOC, ethane, ethene, methane and volatile fatty acids Table 5 summarizes the MNA data where available. Laboratory reports and field data forms are included in Appendix A. The MNA parameter data were evaluated in general accordance with the United States Environmental Protection Agency’s (EPA’s) Technical Protocol Manual (EPA, 1998) to determine whether the conditions are conducive to, or whether there is evidence for anaerobic degradation of the chlorinated hydrocarbons. Specifically, the results were evaluated according to the weighted system presented in Table 2.3 of the Technical Protocol Manual, referred to hereafter as the Biodegradation Screening Matrix. According to this manual, a score less than 5 indicates that there is inadequate evidence for anaerobic natural attenuation, a score of 6 to 14 indicates that there is limited evidence for anaerobic natural attenuation, a score of 15 to 19 indicates that there is adequate evidence for anaerobic natural attenuation, and a score of 20 or more indicates that there is strong evidence that anaerobic natural attenuation is occurring. The MNA evaluation was performed based on the results from the November 2015 sampling event for downgradient wells within the contaminant plume, compared where appropriate to the background well (MW-6). MW-6 was dry during the November 2015 event; therefore; the data from 2014 was used for comparison. The Biodegradation Screening Matrix is presented in Table 6 of this report. The aspect of the scoring process is ambiguous with respect to how it should be applied to a landfill site such as this facility, and that is the issue of daughter products. Methane, carbon dioxide (CO2), cis-1,2-dichloroethylene, vinyl chloride, and 1,1-dichlroethane can all be daughter products produced by the biodegradation of higher-order chlorinated ethanes and ethenes, and as such, their presence can be strong indicators that biodegradation is occurring, and are therefore included in the EPA scoring matrix. On the other hand, methane and CO2 are gases produced by the natural metabolization of biomass by microorganisms in a landfill, and cis-1,2- dichloroethylene, vinyl chloride, and 1,1-dichloroethane can be primary contaminants leached from waste in landfills. Some of these compounds are present in the groundwater plume; however, it is unclear whether or not they are daughter products indicating natural attenuation. For this reason, the score has been calculated both with and without the points for daughter products. ______________________________________________________________________________ Second Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering Town of Kernersville Landfill, Permit No. 34-04 January 2016 7 The following table summarizes the scoring results from Table 6 for both options for interpreting the data. The scores ranged from 11 to 23 (adequate evidence of natural attenuation to strong evidence of natural attenuation). In reality, the best score is probably in the middle of this range, indicating limited evidence of natural attenuation. Points Awarded including DP’s Points Awarded excluding DP’s 21 11 DP’s = Points for possible daughter products. 6.0 CONCLUSION Based on historical groundwater data, inorganic and organic constituents detected above their respective NC 2L and GWPS in samples collected during the November 2015 sampling event are consistent with previous events. In addition, there were no constituents detected at the surface water monitoring points above the NC 2B Standards. The Town of Kernersville Landfill will continue to monitor groundwater in accordance with the approved CAP. The next semiannual sampling event is tentatively scheduled for May 2016. 7.0 REFERENCES Brown, Philip M., Chief Geologist, 1985, Geologic Map of North Carolina, The North Carolina Geologic Survey, scale 1:500,000. Fetter, C.W., 2001, Applied Hydrogeology, Fourth Edition: Prentice-Hall, Inc.. Johnson, A.I., 1967, Specific Yield - Compilation of Specific Yields For Various Materials: U.S. Geological Survey Water Supply Paper 1662-D. Joyce Engineering, Inc. 2010. Water Quality Monitoring Plan, Piedmont Landfill & Recycling Center. September 2010. North Carolina Department of Environment and Natural Resources, 1990-2012, Solid Waste Management Regulations. USEPA, 1986, RCRA Ground Water Monitoring Technical Enforcement Guidance Document (TEGD). USEPA, 1992, Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance, Chapter 2, July. Tables Table 1A Summary of Historical Groundwater Elevations Table 1B Monitoring Well and Boring Completion Summary Table 2 Summary of Estimated Hydraulic Gradient and Linear Velocity Table 3 Summary of Historical Groundwater Constituents Table 4 Summary of Historical Surface Water Constituents Table 5 Summary of MNA Constituents Table 6 MNA Screening Matrix TABLE 1A SUMMARY OF HISTORICAL GROUNDWATER ELEVATIONS MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 TOC Elevation:806.42 804.87 762.19 764.57 764.56 760.26 773.32 Well Depth:34.69 20.46 13.18 24.00 56.96 14.40 11.36 30-Dec-09 772.45 786.66 759.16 751.54 752.79 754.33 769.21 01-Jun-10 773.45 788.32 758.90 750.76 752.63 753.90 769.69 16-Nov-10 773.55 787.93 759.14 750.98 752.59 753.74 769.81 29-Dec-10 773.29 787.37 758.83 749.82 752.45 753.68 769.56 29-Jun-11 773.10 786.81 758.38 750.54 752.16 753.41 769.73 01-Nov-11 771.92 785.10 758.49 754.73 751.90 753.08 769.63 01-May-12 771.88 785.32 758.54 750.86 752.34 753.55 769.55 07-Nov-12 771.65 DRY 758.20 750.30 751.61 752.87 768.57 09-May-13 769.95 787.56 759.20 752.52 753.24 754.44 - 07-Nov-13 771.46 DRY 758.09 750.12 751.50 752.79 768.13 05-Jun-14 772.22 785.84 758.45 750.67 752.14 753.36 768.57 20-Nov-14 771.73 784.41 758.08 750.24 751.53 752.81 769.23 27-Apr-15 -784.66 758.49 751.11 752.34 753.61 769.62 19-Nov-15 -784.62 757.18 747.60 750.53 750.66 768.69 Notes: TOC = Top of PVC well casing. Elevations in feet above mean sea level. Well depths in feet below TOC. Well ID: DowngradientBackground Town of Kernersville Landfill Permit No. 34-04 Joyce Engineering TABLE 1B MONITORING WELL AND BORING COMPLETION SUMMARY CASING GROUND DIAMETER SURFACE B.G.S.B.T.O.C. inches feet feet from to from to MW-1 2 803.89 806.42 32.16 34.69 24.69 34.96 779.2 768.9 SAPROLITE MW-2 2 760.07 762.19 11.06 13.18 3.18 13.18 756.9 746.9 SAPROLITE MW-3S 2 761.98 764.57 21.41 24.00 14 24 748.0 738.0 SAPROLITE MW-3D 2 762.02 764.56 54.42 56.96 36.96 56.96 725.1 705.1 SAPROLITE MW-4 2 757.00 760.26 11.14 14.40 4.4 14.4 752.6 742.6 SAPROLITE MW-5 2 771.00 773.32 9.04 11.36 6.36 11.36 764.6 759.6 SAPROLITE MW-6 2 801.77 804.87 17.36 20.46 10.46 20.46 791.3 781.3 SAPROLITE NOTES: B.G.S.Below Ground Surface M.S.L.Mean Sea Level B.T.O.C.Below Top of Casing T.O.C.Top of Casing *= Due to limited information this data is assumed based on field conditions TOTAL DEPTH WELL NUMBER LITHOLOGY OF SCREENED INTERVAL*T.O.C. WELL ELEVATIONS feet above M.S.L. SCREENED INTERVAL* DEPTH B.G.S.ELEV. M.S.L. Town of Kernersville Landfill Page 1 of 1 Joyce Engineering TABLE 2: SUMMARY OF ESTIMATED HYDRAULIC GRADIENT AND LINEAR VELOCITY Date of Water Table Measurements: November 19, 2015 SEGMENT HORIZ.HYDRAULIC EFFECTIVE LINEAR FLOW BEGIN & END GRADIENT CONDUCTIVITY POROSITY VELOCITY DIRECTION GW ELEVATION i K n e V (feet-AMSL)(ft/ft) (ft/day)(ft/year) 785 760 Average 0.0311 Average 63.26 Notes: Linear flow velocity: V = Ki/n e (modified Darcy equation). 1. Hydraulic conductivities (“K”) was estimated from slug test completed by JOYCE in April 2013 2. Velocity = Ki/n; assume homogeneous isotropic porous aquifer. 0.31 63.261.73E+00 FLOW LINE SEGMENT SEGMENT LENGTH (feet) i 1 805 SW 0.0311 Town of Kernersville Landfill Permit No. 34-04 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Inorganic Compounds Antimony 30-Dec-09 1.2 6.0 ---ND 5.4 B ND ND 4.5 B ---1.4 J GWPS = 1.4 µg/L (10/23/07)01-Jun-10 1.2 6.0 ---ND ND ND ND ND ---3.9 J GWPS = 1 µg/L (8/1/10)29-Dec-10 2.6 6.0 ---ND ND ND ND ND ND ND 29-Jun-11 5.0 6.0 ---ND ND ND ND ND ND ND 01-Nov-11 5.0 6.0 ---ND ND ND ND ND ND ND 01-May-12 5.0 6.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.48 6.0 ------ND ND ND ND ---ND 09-May-13 5.0 6.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 6.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 6.0 ---ND ND ND ND ND ND ND 20-Nov-14 3.8 6.0 ------ND ND ND ND ND ND 27-Apr-15 3.8 6.0 ------ND ND ND ND ND ND 19-Nov-15 3.8 6.0 ------ND ND ND ND ND ND Arsenic 29-Jun-11 5.0 10.0 ---ND ND ND ND ND 6.2 J ND NC 2L = 10 µg/L (1/11/10)01-Nov-11 5.0 10.0 ---ND ND ND ND ND ND ND 01-May-12 5.0 10.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.094 10.0 ------1.43 B 1.42 B 0.87 B 1.04 B ---1.0 J 09-May-13 5.0 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 10.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 10.0 ---ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 ------ND 2.5 J ND ND 2.7 J ND 27-Apr-15 2.5 10.0 ------ND ND ND ND ND ND 19-Nov-15 2.5 10.0 ------ND ND ND 2.7 J ND ND Barium 30-Dec-09 1.1 100 ---74.1 J 496 178 18.2 J 89.0 J ---3.6 J NC 2L = 700 µg/L (1/11/10)01-Jun-10 1.1 100 ---58.1 J 326 187 22.2 J 94.9 J ---2.0 J 29-Dec-10 0.20 100 ---46.3 B 430 112 38.0 B 92.1 J 72.6 J 11.3 J 29-Jun-11 5.0 100 ---77.7 J 370 128 41.2 J 98.4 J 113 ND 01-Nov-11 5.0 100 ---125 413 132 41.7 J 111 72.1 J ND 01-May-12 5.0 100 ---78.8 J 323 121 40.0 J 99.7 J 66.1 J ND 07-Nov-12 0.39 100 ------369 127 41.0 B 98.7 J ---12.2 J 09-May-13 5.0 100 ---78.6 J 307 112 40.0 J 85.6 J ---ND 07-Nov-13 5.0 100 ------302 113 38.0 J 89.6 J ---ND 05-Jun-14 5.0 100 ---60.3 J 285 117 39.2 J 80.3 J 75.0 J ND 20-Nov-14 2.5 100 ------301 113 39.5 J 83.3 J 108 ND 27-Apr-15 2.5 100 ------268 104 39.0 J 94.8 J 67.4 J ND 19-Nov-15 2.5 100 ------294 108 42.2 J 101 60.3 J ND Beryllium 30-Dec-09 0.2 1.0 ---ND 0.5 J ND ND ND ---ND GWPS = 4 µg/L (10/23/07)01-Jun-10 0.2 1.0 ---0.6 J 0.7 J ND ND ND ---ND 29-Dec-10 0.10 1.0 ---ND ND ND ND ND 0.48 J ND 29-Jun-11 1.0 1.0 ---ND ND ND ND ND ND ND 01-Nov-11 1.0 1.0 ---ND ND ND ND ND ND ND 01-May-12 1.0 1.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.049 1.00 ------0.34 J ND ND 0.099 J ---ND 09-May-13 1.0 1.0 ---ND ND ND ND ND ---ND 07-Nov-13 1.0 1.0 ------ND ND ND ND ---ND 05-Jun-14 1.0 1.0 ---ND ND ND ND ND ND ND 20-Nov-14 0.5 1.0 ------ND ND ND ND ND ND 27-Apr-15 0.5 1.0 ------ND ND ND ND ND ND 19-Nov-15 0.5 1.0 ------ND ND ND ND ND ND Cadmium 30-Dec-09 0.2 1.0 ---ND 0.5 J 5.6 ND ND ---ND NC 2L = 2 µg/L (1/11/10)01-Jun-10 0.2 1.0 ---2.9 1.0 B 5.3 0.4 B 0.4 B ---0.4 J 29-Dec-10 0.50 1.0 ---ND ND ND ND ND ND ND 29-Jun-11 1.0 1.0 ---ND ND ND ND ND ND ND 01-Nov-11 1.0 1.0 ---ND ND ND ND ND ND ND 01-May-12 1.0 1.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.026 1.00 ------0.15 J ND ND 0.043 J ---ND 09-May-13 1.0 1.0 ---ND ND ND ND ND ---ND 07-Nov-13 1.0 1.0 ------ND ND ND ND ---ND 05-Jun-14 1.0 1.0 ---ND ND ND ND ND ND ND 20-Nov-14 0.5 1.0 ------ND ND ND ND ND ND 27-Apr-15 0.5 1.0 ------ND ND ND ND ND ND 19-Nov-15 0.5 1.0 ------ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 1 of 8 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Chromium 30-Dec-09 0.7 10.0 ---ND 2.7 J 9.7 J ND 3.1 J ---ND NC 2L = 10 µg/L (1/11/10)01-Jun-10 0.7 10.0 ---3.5 J 1.6 J 12.4 1.2 J 3.2 J ---ND 29-Dec-10 0.40 10.0 ---0.48 J 1.3 J 0.57 J ND 5.5 J 3.8 J ND 29-Jun-11 5.0 10.0 ---ND ND ND ND ND ND ND 01-Nov-11 5.0 10.0 ---ND ND ND ND 10.3 ND ND 01-May-12 5.0 10.0 ---ND ND ND ND 5.8 J ND ND 07-Nov-12 0.030 10.0 ------0.71 J 0.12 B 0.094 B 7.31 J ---0.099 J 09-May-13 5.0 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 10.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 10.0 ---ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 ------ND ND ND ND ND ND 27-Apr-15 2.5 10.0 ------ND ND ND 7.2 J ND ND 19-Nov-15 2.5 10.0 ------ND ND ND 3.0 J ND ND Cobalt 30-Dec-09 0.7 10.0 ---ND 6.4 J 11.2 ND 1.8 J ---ND GWPS = 70 µg/L (10/23/07)01-Jun-10 0.7 10.0 ---1.8 J 2.5 J 8.5 J ND 1.7 J ---ND GWPS = 1 µg/L (10/1/10)29-Dec-10 0.60 10.0 ---ND 4.9 J 1.7 J ND 1.6 J 10.2 ND 29-Jun-11 5.0 10.0 ---ND ND ND ND ND 9.9 J ND 01-Nov-11 5.0 10.0 ---ND ND ND ND ND 5.2 J ND 01-May-12 5.0 10.0 ---ND ND ND ND ND 13.9 ND 07-Nov-12 0.053 10.0 ------1.98 J 3.89 J 0.43 B 2.02 J ---0.24 J 09-May-13 5.0 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 10.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 10.0 ---ND ND ND ND ND 12.0 ND 20-Nov-14 2.5 10.0 ------ND 2.5 J ND ND 10.2 ND 27-Apr-15 2.5 10.0 ------ND 2.7 J ND ND 10.7 ND 19-Nov-15 2.5 10.0 ------ND 3.9 J ND ND 3.5 J ND Copper 30-Dec-09 2.0 10.0 ---ND ND 10.6 ND 1.5 J ---ND NC 2L = 1,000 µg/L (10/23/07)01-Jun-10 2.0 10.0 ---12.2 B 3.3 B 33.2 3.9 B 6.8 B ---4.8 J 29-Dec-10 0.30 10.0 ---ND ND 0.49 J 0.59 J 1.5 J 7.9 J ND 29-Jun-11 5.0 10.0 ---ND ND ND ND ND 16.6 ND 01-Nov-11 5.0 10.0 ---ND ND ND ND 5.4 J ND ND 01-May-12 5.0 10.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.093 10.0 ------3.56 B 0.54 B 0.98 B 1.83 B ---1.23 J 09-May-13 5.0 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 10.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 10.0 ---ND ND ND ND ND 6.1 J ND 20-Nov-14 2.5 10.0 ------ND ND ND ND 5.3 J ND 27-Apr-15 2.5 10.0 ------ND ND ND 3.5 B 3.6 B 3.2 J 19-Nov-15 2.5 10.0 ------ND ND ND 2.6 J 5.1 J ND Lead 30-Dec-09 2.0 10.0 ---ND ND 10.2 ND ND ---ND NC 2L = 15 µg/L (10/23/07)01-Jun-10 2.0 10.0 ---9.1 B 8.2 B 8.7 B 3.0 B 3.9 B ---3.2 J 29-Dec-10 4.0 10.0 ---ND ND ND ND ND 6.5 J ND 29-Jun-11 5.0 10.0 ---ND ND ND ND ND 19.9 ND 01-Nov-11 5.0 10.0 ---5.5 J ND ND ND ND ND ND 01-May-12 5.0 10.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.025 10.0 ------1.00 B 0.091 B 0.066 B 1.12 B ---0.58 J 09-May-13 5.0 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 10.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 10.0 ---ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 ------ND ND ND ND 4.2 J ND 27-Apr-15 2.5 10.0 ------ND ND ND ND ND ND 19-Nov-15 2.5 10.0 ------ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 2 of 8 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Nickel 30-Dec-09 0.6 50.0 ---ND ND 8.1 J 1.8 J 1.6 J ---ND NC 2L = 100 µg/L (10/23/07)01-Jun-10 0.6 50.0 ---ND ND 6.0 J ND 0.9 J ---ND 29-Dec-10 1.7 50.0 ---ND ND ND ND ND 2.0 B 3.1 J 29-Jun-11 5.0 50.0 ---ND ND ND ND ND ND ND 01-Nov-11 5.0 50.0 ---ND ND ND ND ND ND ND 01-May-12 5.0 50.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.26 50.0 ------0.73 B 1.19 B 0.65 B 5.57 J ---0.84 J 09-May-13 5.0 50.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 50.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 50.0 ---ND ND ND ND ND ND ND 20-Nov-14 2.5 50.0 ------ND ND ND ND ND ND 27-Apr-15 2.5 50.0 ------ND ND ND 3.4 J ND ND 19-Nov-15 2.5 50.0 ------ND ND ND 2.6 J ND ND Selenium 30-Dec-09 6.3 10.0 ---ND ND 8.4 J ND ND ---ND NC 2L = 20 µg/L (1/11/10)01-Jun-10 6.3 10.0 ---ND ND 6.3 J ND ND ---ND 29-Dec-10 3.8 10.0 ---ND ND ND ND ND ND ND 29-Jun-11 10.0 10.0 ---ND ND ND ND ND ND ND 01-Nov-11 10.0 10.0 ---ND ND ND ND ND ND ND 01-May-12 10.0 10.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.11 10.0 ------0.16 J 0.38 J 0.20 J 0.25 J ---ND 09-May-13 10.0 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 10.0 10.0 ------ND ND ND ND ---ND 05-Jun-14 10.0 10.0 ---ND ND ND ND ND ND ND 20-Nov-14 5.0 10.0 ------ND ND ND ND ND ND 27-Apr-15 5.0 10.0 ------ND ND ND ND ND ND 19-Nov-15 5.0 10.0 ------ND ND ND ND ND ND Silver 30-Dec-09 1.1 10.0 ---ND 1.7 B 2.2 B ND ND ---1.9 J NC 2L = 20 µg/L (1/11/10)01-Jun-10 1.1 10.0 ---ND ND ND ND ND ---ND 29-Dec-10 0.10 10.0 ---ND 1.8 J 0.36 J 0.19 J 0.23 J ND ND 29-Jun-11 5.0 10.0 ---ND ND ND ND ND ND ND 01-Nov-11 5.0 10.0 ---ND ND ND ND ND ND ND 01-May-12 5.0 10.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.017 10.0 ------0.18 J ND ND 0.078 J ---ND 09-May-13 5.0 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 10.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 10.0 ---ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 ------ND ND ND ND ND ND 27-Apr-15 2.5 10.0 ------ND ND ND ND ND ND 19-Nov-15 2.5 10.0 ------ND ND ND ND ND ND Thallium 30-Dec-09 2.7 5.5 ---ND ND ND ND ND ---3.7 J GWPS = 0.28 µg/L (10/23/07)01-Jun-10 2.7 5.5 ---ND ND ND ND ND ---ND GWPS = 0.2 µg/L (10/1/10)29-Dec-10 3.0 5.5 ---ND 3.2 J ND ND 4.8 J ND ND 29-Jun-11 5.4 5.5 ---ND ND ND ND ND ND ND 01-Nov-11 5.4 5.5 ---ND ND ND ND ND ND ND 01-May-12 5.4 5.5 ---ND ND ND ND ND ND ND 07-Nov-12 0.060 5.50 ------0.16 J ND ND 0.76 J ---ND 09-May-13 5.4 5.5 ---ND ND ND ND ND ---ND 07-Nov-13 5.4 5.5 ------ND ND ND ND ---ND 05-Jun-14 5.4 5.5 ---ND ND ND ND ND ND ND 20-Nov-14 5.0 5.5 ------ND ND ND ND ND ND 27-Apr-15 5.0 5.5 ------ND ND ND ND ND ND 19-Nov-15 5.0 5.5 ------ND ND 8.8 8.8 ND ND Vanadium 30-Dec-09 0.4 25.0 ---ND 1.4 J 37.4 1.5 J 4.3 J ---ND GWPS = 3.5 µg/L (10/23/07)01-Jun-10 0.4 25.0 ---1.2 J 3.4 J 84.2 1.4 J 4.8 J ---ND GWPS = 0.3 µg/L (10/1/10)29-Dec-10 0.20 25.0 ---1.2 B 2.8 J 2.3 J 1.6 J 5.5 J 14.5 J 0.26 J 29-Jun-11 5.0 25.0 ---ND ND ND ND ND 22.0 J ND 01-Nov-11 5.0 25.0 ---7.2 J ND ND ND 12.0 J 7.2 J ND 01-May-12 5.0 25.0 ---ND ND ND ND 7.2 J 7.6 J ND 07-Nov-12 0.085 25.0 ------2.48 J 2.02 J 2.35 J 4.55 J ---ND 09-May-13 5.0 25.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 25.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 25.0 ---ND ND 11.4 J ND ND ND ND 20-Nov-14 2.5 25.0 ------ND 3.2 J ND ND 9.4 J ND 27-Apr-15 2.5 25.0 ------ND ND ND 8.9 J 5.6 J ND 19-Nov-15 2.5 25.0 ------3.1 J 4.3 J ND 6.5 J 3.9 J ND Town of Kernersville Landfill Permit No. 34-04 Page 3 of 8 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Zinc 30-Dec-09 2.7 10.0 ---ND 10.1 B 204 15.9 B 24.8 B ---5.8 J NC 2L = 1,000 µg/L (1/11/10)01-Jun-10 2.7 10.0 ---16.2 13.5 415 8.5 J 22.2 ---ND 29-Dec-10 0.40 10.0 ---12.2 B 15.8 B 8.9 B ND 4.6 B 38.1 B 12.5 29-Jun-11 10.0 10.0 ---ND 23.6 B 22.3 B ND 15.5 B 91.2 10.5 01-Nov-11 10.0 10.0 ---16.6 ND 40.0 ND 16.2 31.4 ND 01-May-12 10.0 10.0 ---ND ND 13.5 ND 10.2 12.0 ND 07-Nov-12 1.31 10.0 ------8.61 J 5.20 J 3.98 J 4.65 J ---ND 09-May-13 10.0 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 10.0 10.0 ------13.8 10.4 ND ND ---ND 05-Jun-14 10.0 10.0 ---ND ND 89.0 ND ND 19.4 ND 20-Nov-14 5.0 10.0 ------ND 20.9 ND ND 55.0 ND 27-Apr-15 5.0 10.0 ------7.3 B 11.5 B 8.0 B 14.1 B 10.3 B 7.5 J 19-Nov-15 5.0 10.0 ------ND 23.1 7.3 J 10.7 16.3 ND Organic Compounds Acetone 29-Jun-11 2.2 100 ---ND 2.3 B 2.4 B 3.9 B ND 3.8 B 5.3 J NC 2L = 6,000 µg/L (1/11/10)01-Nov-11 2.2 100 ---ND ND ND ND ND ND 14.6 J 01-May-12 2.2 100 ---ND ND ND ND ND ND ND 07-Nov-12 0.193 100 ------ND ND ND ND ---ND 09-May-13 10.0 100 ---ND ND ND ND ND ---12.0 J 07-Nov-13 10.0 100 ------ND ND ND ND ---ND 05-Jun-14 10.0 100 ---ND ND ND ND ND ND ND 20-Nov-14 10.0 100 ------ND ND ND ND ND ND 27-Apr-15 10.0 100 ------ND 14.8 B ND 21.3 B 14.1 B 20.7 J 19-Nov-15 10.0 100 ------ND ND ND ND ND ND Benzene 30-Dec-09 0.1 1.0 ---ND 8.4 0.3 J 0.4 J 0.3 J ---ND NC 2L = 1 µg/L (10/23/07)01-Jun-10 0.1 1.0 ---ND 2.9 ND ND ND ---ND 29-Dec-10 0.25 1.0 ---ND 8.1 ND ND ND ND ND 29-Jun-11 0.25 1.0 ---ND 7.2 0.38 J 0.45 J 0.42 J ND ND 01-Nov-11 0.25 1.0 ---ND 8.6 ND ND ND ND ND 01-May-12 0.25 1.0 ---ND 6.7 0.36 J 0.45 J 0.42 J ND ND 07-Nov-12 0.111 1.0 ------8.63 0.430 J 0.504 J 0.478 J ---ND 09-May-13 0.25 1.0 ---ND 5.2 0.27 J 0.32 J 0.30 J ---ND 07-Nov-13 0.25 1.0 ------6.9 0.33 J 0.38 J 0.39 J ---ND 05-Jun-14 0.25 1.0 ---ND 6.0 ND 0.42 J 0.40 J ND ND 20-Nov-14 0.25 1.0 ------6.2 0.30 J ND 0.32 J ND ND 27-Apr-15 0.25 1.0 ------6.4 0.38 J 0.48 J 0.45 J ND ND 19-Nov-15 0.25 1.0 ------6.0 ND 0.37 J ND ND ND Bromoform 09-May-13 0.26 3.0 ---ND ND 0.37 B ND ND ---0.37 J NC 2L = µg/L 4 (10/23/07)07-Nov-13 0.26 3.0 ------ND ND ND ND ---ND 05-Jun-14 0.26 3.0 ---ND ND ND ND ND ND ND 20-Nov-14 0.26 3.0 ------ND ND ND ND ND ND 27-Apr-15 0.26 3.0 ------ND ND ND ND ND ND 19-Nov-15 0.26 3.0 ------ND ND ND ND ND ND Chlorobenzene 30-Dec-09 0.1 3.0 ---ND 0.5 J 0.6 J ND ND ---ND NC 2L = 50 µg/L (10/23/07)01-Jun-10 0.1 3.0 ---ND ND ND ND ND ---ND 29-Dec-10 0.23 3.0 ---ND 0.61 J ND ND ND ND ND 29-Jun-11 0.23 3.0 ---ND 0.46 J 1.0 J 0.37 J ND ND ND 01-Nov-11 0.23 3.0 ---ND 0.59 J 1.1 J 0.37 J ND ND ND 01-May-12 0.23 3.0 ---ND {0.42}J 0.94 B 0.38 B ND ND 0.30 {ND}J 07-Nov-12 0.083 3.00 ------0.468 J 1.30 J 0.476 J ND ---ND 09-May-13 0.23 3.0 ---ND 0.27 J 0.72 J 0.27 J ND ---ND 07-Nov-13 0.23 3.0 ------0.42 J 0.97 J 0.38 J ND ---ND 05-Jun-14 0.23 3.0 ---ND 0.30 J 0.78 J 0.33 J ND ND ND 20-Nov-14 0.23 3.0 ------0.37 J 0.95 J 0.36 J ND ND ND 27-Apr-15 0.23 3.0 ------0.27 J 1.0 J 0.40 J ND ND ND 19-Nov-15 0.23 3.0 ------0.31 J 0.81 J 0.33 J ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 4 of 8 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Chloroethane 30-Dec-09 0.1 10.0 ---ND ND 0.5 J 0.5 J ND ---0.1 J NC 2L = 3,000 µg/L (1/11/10)01-Jun-10 0.1 10.0 ---ND ND 0.4 J ND ND ---ND 29-Dec-10 0.54 10.0 ---ND ND ND ND ND ND ND 29-Jun-11 0.54 10.0 ---ND ND 0.77 J ND 0.57 J ND ND 01-Nov-11 0.54 10.0 ---ND ND 0.79 J ND ND ND ND 01-May-12 0.54 10.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.235 10.0 ------ND ND ND ND ---ND 09-May-13 0.54 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 0.54 10.0 ------ND ND ND ND ---ND 05-Jun-14 0.54 10.0 ---ND ND ND ND ND ND ND 20-Nov-14 0.54 10.0 ------ND ND ND ND ND ND 27-Apr-15 0.54 10.0 ------ND 0.95 J 0.65 J 0.57 J ND ND 19-Nov-15 0.54 10.0 ------ND ND ND ND ND ND 1,4-Dichlorobenzene 30-Dec-09 0.1 1.0 ---ND 3.8 2.2 2.3 3.1 ---ND NC 2L = 6 µg/L (1/11/10)01-Jun-10 0.1 1.0 ---ND 1.2 0.9 J ND 1.2 ---ND 29-Dec-10 0.33 1.0 ---ND 3.9 1.1 2.3 1.9 ND ND 29-Jun-11 0.33 1.0 ---ND 3.8 2.8 3.6 3.2 ND ND 01-Nov-11 0.33 1.0 ---ND 4.7 4.1 4.1 3.5 ND ND 01-May-12 0.33 1.0 ---ND 4.0 2.7 4.1 3.2 ND ND 07-Nov-12 0.083 1.00 ------5.12 2.93 4.08 3.64 ---ND 09-May-13 0.33 1.0 ---ND 3.6 2.0 3.1 2.3 ---ND 07-Nov-13 0.33 1.0 ------5.4 2.5 4.2 3.2 ---ND 05-Jun-14 0.33 1.0 ---ND 5.0 1.9 4.0 2.7 ND ND 20-Nov-14 0.33 1.0 ------4.7 1.9 3.8 2.6 ND ND 27-Apr-15 0.33 1.0 ------4.7 2.1 4.2 2.7 ND ND 19-Nov-15 0.33 1.0 ------4.8 1.4 3.5 2.5 ND ND 1,1-Dichloroethane 30-Dec-09 0.2 5.0 ---ND 22.8 1.9 J 4.0 J 2.4 J ---ND NC 2L = 6 µg/L (1/11/10)01-Jun-10 0.2 5.0 ---ND 11.0 1.1 J ND 1.2 J ---ND 29-Dec-10 0.32 5.0 ---ND 28.2 2.4 J 4.1 J 2.6 J ND ND 29-Jun-11 0.32 5.0 ---ND 25.0 2.5 J 3.9 J 2.6 J ND ND 01-Nov-11 0.32 5.0 ---ND 27.2 2.3 J 4.0 J 2.3 J ND ND 01-May-12 0.32 5.0 ---ND 22.6 2.0 J 3.8 J 2.0 J ND ND 07-Nov-12 0.208 5.0 ------28.1 2.06 J 4.08 J ND ---ND 09-May-13 0.32 5.0 ---ND 18.7 1.4 J 3.0 J 1.6 J ---ND 07-Nov-13 0.32 5.0 ------26.6 1.7 J 4.2 J 2.2 J ---ND 05-Jun-14 0.32 5.0 ---ND 21.9 1.4 J 3.9 J 1.9 J ND ND 20-Nov-14 0.32 5.0 ------21.5 1.3 J 3.2 J 1.8 J ND ND 27-Apr-15 0.32 5.0 ------24.2 1.4 J 4.3 J 2.4 J ND ND 19-Nov-15 0.32 5.0 ------20.7 0.82 J 3.1 J 1.8 J ND ND 1,2-Dichloroethane 30-Dec-09 0.1 1.0 ---ND 1.2 0.7 J 1.2 ND ---ND NC 2L = 0.4 µg/L (1/11/10)01-Jun-10 0.1 1.0 ---ND ND ND ND ND ---ND 29-Dec-10 0.12 1.0 ---ND ND 0.82 J 1.1 ND ND ND 29-Jun-11 0.12 1.0 ---ND 0.76 J 0.86 J 1.3 ND ND ND 01-Nov-11 0.12 1.0 ---ND 0.95 J ND 1.3 ND ND ND 01-May-12 0.12 1.0 ---ND 0.71 J 0.70 J 1.1 ND ND ND 07-Nov-12 0.171 1.00 ------ND ND ND ND ---ND 09-May-13 0.12 1.0 ---ND 0.50 J 0.49 J 0.81 J ND ---ND 07-Nov-13 0.12 1.0 ------0.93 J 0.66 J 1.3 ND ---ND 05-Jun-14 0.12 1.0 ---ND 0.76 J 0.52 J 0.99 J ND ND ND 20-Nov-14 0.12 1.0 ------0.68 J 0.47 J 0.81 J ND ND ND 27-Apr-15 0.12 1.0 ------ND 0.56 J 1.2 0.15 J ND ND 19-Nov-15 0.24 1.0 ------0.86 J 0.40 J 1.1 ND ND ND 1,1-Dichloroethene 30-Dec-09 0.1 5.0 ---ND 0.4 J ND ND ND ---ND NC 2L = 7 µg/L (10/23/07)01-Jun-10 0.1 5.0 ---ND ND ND ND ND ---ND 29-Dec-10 0.56 5.0 ---ND ND ND ND ND ND ND 29-Jun-11 0.56 5.0 ---ND ND ND ND ND ND ND 01-Nov-11 0.56 5.0 ---ND ND ND ND ND ND ND 01-May-12 0.56 5.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.208 5.00 ------ND ND ND ND ---ND NC 2L = 350 µg/L (04/01/2013)09-May-13 0.56 5.0 ---ND ND ND ND ND ---ND 07-Nov-13 0.56 5.0 ------ND ND ND ND ---ND 05-Jun-14 0.56 5.0 ---ND 4.7 J ND ND ND ND ND 20-Nov-14 0.56 5.0 ---ND ND ND ND ND ND ND 27-Apr-15 0.56 5.0 ------ND ND ND ND ND ND 19-Nov-15 0.56 5.0 ------ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 5 of 8 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks cis-1,2-Dichloroethene 30-Dec-09 0.1 5.0 ---ND 68.2 11.0 51.0 21.8 ---ND NC 2L = 70 µg/L (10/23/07)01-Jun-10 0.1 5.0 ---ND 23.0 7.6 ND 10.2 ---ND 29-Dec-10 0.19 5.0 ---ND 66.7 16.8 56.7 24.1 ND ND 29-Jun-11 0.19 5.0 ---ND 55.1 16.5 62.7 25.1 ND ND 01-Nov-11 0.19 5.0 ---ND 59.4 15.2 59.3 23.2 ND ND 01-May-12 0.19 5.0 ---ND {48.7}14.2 59.5 22.1 ND 0.21 {ND}J 07-Nov-12 0.103 5.00 ------59.7 13.6 71.3 26.4 ---ND 09-May-13 0.19 5.0 ---ND 39.9 10.9 49.7 17.4 ---ND 07-Nov-13 0.19 5.0 ------53.9 10.7 67.1 21.8 ---ND 05-Jun-14 0.19 5.0 ---ND 47.0 11.2 58.1 20.0 ND ND 20-Nov-14 0.19 5.0 ------44.9 9.6 55.4 19.3 ND ND 27-Apr-15 0.19 5.0 ------51.8 9.7 65.3 24.0 ND ND 19-Nov-15 0.19 5.0 ------44.4 5.6 51.2 18.8 ND ND trans-1,2-Dichloroethene 30-Dec-09 0.1 5.0 ---ND 1.4 J ND 0.2 J 0.2 J ---ND NC 2L = 100 µg/L (10/23/07)01-Jun-10 0.1 5.0 ---ND 0.6 J ND ND ND ---ND 29-Dec-10 0.49 5.0 ---ND 1.7 J ND ND ND ND ND 29-Jun-11 0.49 5.0 ---ND 1.5 J ND ND ND ND ND 01-Nov-11 0.49 5.0 ---ND 1.6 J ND ND ND ND ND 01-May-12 0.49 5.0 ---ND 1.4 J ND ND ND ND ND 07-Nov-12 0.077 5.00 ------1.59 J ND ND ND ---ND 09-May-13 0.49 5.0 ---ND 1.1 J ND ND ND ---ND 07-Nov-13 0.49 5.0 ------1.6 J ND ND ND ---ND 05-Jun-14 0.49 5.0 ---ND 1.4 J ND ND ND ND ND 20-Nov-14 0.49 5.0 ------1.4 J ND ND ND ND ND 27-Apr-15 0.49 5.0 ------1.6 J ND ND ND ND ND 19-Nov-15 0.49 5.0 ------1.5 J ND ND ND ND ND 1,2-Dichloropropane 30-Dec-09 0.1 1.0 ---ND 5.7 0.6 J 1.1 0.7 J ---ND NC 2L = 0.6 µg/L (1/11/10)01-Jun-10 0.1 1.0 ---ND 1.9 ND ND ND ---ND 29-Dec-10 0.27 1.0 ---ND 5.3 ND ND ND ND ND 29-Jun-11 0.27 1.0 ---ND 4.8 0.90 J 1.3 0.73 J ND ND 01-Nov-11 0.27 1.0 ---ND 4.9 0.76 J 1.3 ND ND ND 01-May-12 0.27 1.0 ---ND 4.4 0.76 J 1.4 0.62 J ND ND 07-Nov-12 0.150 1.0 ------4.93 ND 1.66 ND ---ND 09-May-13 0.27 1.0 ---ND 3.3 0.51 J 0.96 J 0.45 J ---ND 07-Nov-13 0.27 1.0 ------4.4 0.63 J 1.3 0.57 J ---ND 05-Jun-14 0.27 1.0 ---ND 4.0 0.51 J ND 0.41 J ND ND 20-Nov-14 0.27 1.0 ------4.1 0.56 J 1.2 0.36 J ND ND 27-Apr-15 0.27 1.0 ------4.8 0.59 J 1.6 0.57 J ND ND 19-Nov-15 0.27 1.0 ------4.3 ND 1.1 ND ND ND Ethylbenzene 30-Dec-09 0.1 1.0 ---ND ND ND 0.4 J ND ---ND NC 2L = 600 µg/L (10/23/07)01-Jun-10 0.1 1.0 ---ND ND ND ND ND ---ND 29-Dec-10 0.30 1.0 ---ND ND ND ND ND ND ND 29-Jun-11 0.30 1.0 ---ND ND ND ND ND ND ND 01-Nov-11 0.30 1.0 ---ND ND ND ND ND ND ND 01-May-12 0.30 1.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.109 1.00 ------ND ND ND ND ---ND 09-May-13 0.30 1.0 ---ND ND ND ND ND ---ND 07-Nov-13 0.30 1.0 ------ND ND ND ND ---ND 05-Jun-14 0.30 1.0 ---ND ND ND ND ND ND ND 20-Nov-14 0.30 1.0 ------ND ND ND ND ND ND 27-Apr-15 0.30 1.0 ------ND ND ND ND ND ND 19-Nov-15 0.30 1.0 ------ND ND ND ND ND ND Tetrachloroethene 30-Dec-09 0.2 1.0 ---ND 1.2 ND ND ND ---ND NC 2L = 0.7 µg/L (10/23/07)01-Jun-10 0.2 1.0 ---ND 1.4 ND ND ND ---ND 29-Dec-10 0.46 1.0 ---ND 2.8 ND ND ND ND ND 29-Jun-11 0.46 1.0 ---ND 3.6 ND ND ND ND ND 01-Nov-11 0.46 1.0 ---ND 2.9 ND ND ND ND ND 01-May-12 0.46 1.0 ---ND 3.0 ND ND ND ND ND 07-Nov-12 0.193 1.00 ------2.52 ND ND ND ---ND 09-May-13 0.46 1.0 ---ND 1.9 ND ND ND ---ND 07-Nov-13 0.46 1.0 ------1.8 ND ND ND ---ND 05-Jun-14 0.46 1.0 ---ND 2.3 ND ND ND ND ND 20-Nov-14 0.46 1.0 ------1.1 ND ND ND ND ND 27-Apr-15 0.46 1.0 ------1.4 ND ND ND ND ND 19-Nov-15 0.46 1.0 ------0.90 J ND ND ND ND --- Town of Kernersville Landfill Permit No. 34-04 Page 6 of 8 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Toluene 29-Jun-11 0.26 1.0 ---ND ND ND ND ND 0.76 J ND NC 2L = 600 µg/L (1/11/10)01-Nov-11 0.26 1.0 ---ND ND ND ND ND ND ND 01-May-12 0.26 1.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.122 1.00 ------ND ND ND ND ---ND 09-May-13 0.26 1.0 ---ND ND ND ND ND ---ND 07-Nov-13 0.26 1.0 ------ND ND ND ND ---ND 05-Jun-14 0.26 1.0 ---ND ND ND ND ND ND ND 20-Nov-14 0.26 1.0 ------ND ND ND ND ND ND 27-Apr-15 0.26 1.0 ------ND ND ND ND ND ND 19-Nov-15 0.26 1.0 ------ND ND ND ND ND ND Trichloroethene 30-Dec-09 0.1 1.0 ---ND 8.0 ND ND 0.2 J ---ND NC 2L = 3 µg/L (1/11/10)01-Jun-10 0.1 1.0 ---ND 6.4 ND ND ND ---ND 29-Dec-10 0.47 1.0 ---ND 10.1 ND ND ND ND ND 29-Jun-11 0.47 1.0 ---ND 14.6 ND ND ND ND ND 01-Nov-11 0.47 1.0 ---ND 10.2 ND ND ND ND ND 01-May-12 0.47 1.0 ---ND 11.6 ND ND ND ND ND 07-Nov-12 0.161 1.00 ------9.97 ND ND ND ---ND 09-May-13 0.47 1.0 ---ND 8.4 ND ND ND ---ND 07-Nov-13 0.47 1.0 ------8.0 ND ND ND ---ND 05-Jun-14 0.47 1.0 ---ND 8.9 ND ND ND ND ND 20-Nov-14 0.47 1.0 ------5.1 ND ND ND ND ND 27-Apr-15 0.47 1.0 ------7.1 ND ND ND ND ND 19-Nov-15 0.47 1.0 ------4.7 ND ND ND ND ND Trichlorofluoromethane 29-Jun-11 0.20 1.0 ---ND 0.95 J ND ND ND ND ND NC 2L = 2000 µg/L (1/11/10)01-Nov-11 0.20 1.0 ---ND ND ND ND ND ND ND 01-May-12 0.20 1.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.157 1.00 ------ND ND ND ND ---ND 09-May-13 0.20 1.0 ---ND 0.66 J ND ND ND ---ND 07-Nov-13 0.20 1.0 ------ND ND ND ND ---ND 05-Jun-14 0.20 1.0 ---ND ND ND ND ND ND ND 20-Nov-14 0.20 1.0 ------ND ND ND ND ND ND 27-Apr-15 0.20 1.0 ------ND ND ND ND ND ND 19-Nov-15 0.20 1.0 ------0.41 J ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 7 of 8 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Vinyl chloride 30-Dec-09 0.1 1.0 ---ND 4.0 2.8 4.1 26.2 ---ND NC 2L = 0.03 µg/L (1/11/10)01-Jun-10 0.1 1.0 ---ND 2.2 3.0 ND 26.7 ---ND 29-Dec-10 0.62 1.0 ---ND 3.5 2.4 4.7 25.6 ND ND 29-Jun-11 0.62 1.0 ---ND 2.8 2.8 4.6 28.7 ND ND 01-Nov-11 0.62 1.0 ---ND 5.1 2.6 6.9 24.0 ND ND 01-May-12 0.62 1.0 ---ND 3.5 2.0 4.8 21.8 ND ND 07-Nov-12 0.127 1.00 ------7.94 2.73 6.99 29.9 ---ND 09-May-13 0.62 1.0 ---ND 2.8 1.9 4.2 18.6 ---ND 07-Nov-13 0.62 1.0 ------6.3 2.1 6.0 21.9 ---ND 05-Jun-14 0.62 1.0 ---ND 7.1 5.6 8.9 21.9 ND ND 20-Nov-14 0.62 1.0 ------5.2 2.1 5.3 16.2 ND ND 27-Apr-15 0.62 1.0 ------5.3 2.4 7.1 21.4 ND ND 19-Nov-15 0.62 1.0 ------7.7 2.0 6.7 17.3 ND ND Xylene (Total)30-Dec-09 0.3 4.0 ---ND ND ND 3.5 J ND ---ND NC 2L = 500 µg/L (1/11/10)01-Jun-10 0.3 4.0 ---ND ND ND ND ND ---ND 29-Dec-10 0.66 2.0 ---ND ND ND ND ND ND ND 29-Jun-11 0.66 2.0 ---ND ND ND ND ND ND ND 01-Nov-11 0.66 2.0 ---ND ND ND ND ND ND ND 01-May-12 0.66 2.0 ---ND 0.89 J ND ND ND ND ND 07-Nov-12 0.179 5.00 ------ND ND ND ND ---ND 09-May-13 0.66 5.0 ---ND ND ND ND ND ---ND 07-Nov-13 0.66 5.0 ------ND ND ND ND ---ND 05-Jun-14 0.66 5.0 ---ND ND ND ND ND ND ND 20-Nov-14 0.66 5.0 ------ND ND ND ND ND ND 27-Apr-15 0.66 5.0 ------ND ND ND ND ND ND 19-Nov-15 0.66 5.0 ------ND ND ND ND ND ND Notes: 1. RL = Reporting limit (NC SWSL). 2. All concentrations are in micrograms per liter (ug/L). 3. NC 2L Standard is the groundwater quality standard established under 15A NCAC 2L. 4. MW = Monitoring well. 5. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. 6. ND = Not detected at the laboratory's detection limit. 7. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. 8. B = Probable field and/or laboratory contamination since the concentration is within five times the concentration reported in the associated quality control blanks. 9. Bold values are greater than the NC 2L Standard or GWPS. 10. DL = Detection limit. 11. GWPS = Groundwater Protection Standard (GWPS is used when the NC 2L Standard has not been established.) 12. --- = Monitoring well was no sampled. Town of Kernersville Landfill Permit No. 34-04 Page 8 of 8 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Inorganic Compounds Antimony 30-Dec-09 1.2 6.0 1.5 B 6.4 B NS 1.4 J NC 2B = NE µg/L (05/01/07)01-Jun-10 1.2 6.0 6.7 B 2.5 B NS 3.9 J 29-Dec-10 2.6 6.0 ND ND ND ND 29-Jun-11 5.0 6.0 ND ND ND ND 01-Nov-11 5.0 6.0 ND ND ND ND 01-May-12 5.0 6.0 ND ND ND ND 07-Nov-12 0.48 6.0 ND ND ND ND 09-May-13 5.0 6.0 ND ND ND ND 07-Nov-13 5.0 6.0 ND ND ND ND 05-Jun-14 5.0 6.0 ND ND ND ND 20-Nov-14 3.8 6.0 ND ND ND ND 27-Apr-15 3.8 6.0 ND ND ND ND 19-Nov-15 3.8 6.0 ND ND ND ND Arsenic 07-Nov-12 0.094 10.0 0.17 B 0.26 B 0.24 B 1.0 J NC 2B = 50 µg/L (05/01/07)09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND 27-Apr-15 2.5 10.0 ND ND ND ND 19-Nov-15 2.5 10.0 3.0 J ND ND ND Barium 30-Dec-09 1.1 100 25.1 J 34 J NS 3.4 J NC 2B = NE µg/L (05/01/07)01-Jun-10 1.1 100 28.8 J 31.5 J NS 2.0 J 29-Dec-10 0.20 100 22.3 B 27.8 B 27.9 B 11.3 J 29-Jun-11 5.0 100 40.0 J 39.4 J 39.3 J ND 01-Nov-11 5.0 100 30.1 J 35.2 J 34.3 J ND 01-May-12 5.0 100 66.1 J 35.4 J 33.3 J ND 07-Nov-12 0.39 100 27.6 B 31.5 B 29.9 B 12.2 J 09-May-13 5.0 100 33.6 J 33.8 J 32.6 J ND 07-Nov-13 5.0 100 36.6 J 32.0 J 29.8 J ND 05-Jun-14 5.0 100 31.2 J 35.8 J 33.6 J ND 20-Nov-14 2.5 100 26.6 J 31.2 J 29.4 J ND 27-Apr-15 2.5 100 28.9 J 33.7 J 36.0 J ND 19-Nov-15 2.5 100 45.8 J 44.1 J 43.6 J ND Cadmium 30-Dec-09 0.2 1.0 ND ND NS ND NC 2B = 2 µg/L (05/01/07)01-Jun-10 0.2 1.0 0.9 B 0.4 B NS 0.4 J 29-Dec-10 0.50 1.0 ND ND ND ND 29-Jun-11 1.0 1.0 ND ND ND ND 01-Nov-11 1.0 1.0 ND ND ND ND 01-May-12 1.0 1.0 ND ND ND ND 07-Nov-12 0.026 1.000 ND ND ND ND 09-May-13 1.0 1.0 ND ND ND ND 07-Nov-13 1.0 1.0 ND ND ND ND 05-Jun-14 1.0 1.0 ND ND ND ND 20-Nov-14 0.5 1.0 ND ND ND ND 27-Apr-15 0.5 1.0 ND ND ND ND 19-Nov-15 0.5 1.0 ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 1 of 4 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Chromium 30-Dec-09 0.7 10.0 ND ND NS ND NC 2B = 50 µg/L (05/01/07)01-Jun-10 0.7 10.0 1.7 J 1.2 J NS ND 29-Dec-10 0.40 10.0 0.69 J 0.53 J 0.41 J ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.030 10.0 0.29 B 0.13 B 0.11 B 0.099 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND 2.7 J ND 27-Apr-15 2.5 10.0 ND ND ND ND 19-Nov-15 2.5 10.0 6.3 J 8.6 J 5.7 J ND Cobalt 30-Dec-09 0.7 10.0 ND ND NS ND NC 2B = NE µg/L (05/01/07)01-Jun-10 0.7 10.0 ND ND NS ND 29-Dec-10 0.60 10.0 ND 1.8 J 1.9 J ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.053 10.0 0.34 B 0.76 B 0.76 B 0.24 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND 27-Apr-15 2.5 10.0 ND ND ND ND 19-Nov-15 2.5 10.0 ND ND ND ND Copper 30-Dec-09 2.0 10.0 ND ND NS ND NC 2B = 7 µg/L (05/01/07)01-Jun-10 2.0 10.0 6.9 B 5.8 B NS 4.8 J 29-Dec-10 0.30 10.0 0.38 J ND ND ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.093 10.0 0.27 B 0.38 B 0.38 B 1.23 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND 27-Apr-15 2.5 10.0 3.5 B 7.2 B ND 3.2 J 19-Nov-15 2.5 10.0 5.2 J 6.5 J 5.9 J ND Town of Kernersville Landfill Permit No. 34-04 Page 2 of 4 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Lead 30-Dec-09 2.0 10.0 ND ND NS ND NC 2B = 25 µg/L (05/01/07)01-Jun-10 2.0 10.0 2.7 B 2.8 B NS 3.2 J 29-Dec-10 4.0 10.0 ND ND ND ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.025 10.0 0.071 B 0.049 B 0.060 B 0.58 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND 27-Apr-15 2.5 10.0 ND ND ND ND 19-Nov-15 2.5 10.0 4.7 J 2.6 J 5.0 J ND Nickel 07-Nov-12 0.26 50.0 0.46 B 0.39 B 0.35 B 0.84 J NC 2B = 88 µg/L (05/01/07)09-May-13 5.0 50.0 ND ND ND ND 07-Nov-13 5.0 50.0 ND ND ND ND 05-Jun-14 5.0 50.0 ND ND ND ND 20-Nov-14 2.5 50.0 ND ND ND ND 27-Apr-15 2.5 50.0 ND ND ND ND 19-Nov-15 2.5 50.0 ND 3.0 J ND ND Vanadium 30-Dec-09 0.4 25.0 2.0 J 0.8 J NS ND NC 2B = NE µg/L (05/01/07)01-Jun-10 0.4 25.0 2.2 J 2.4 J NS ND 29-Dec-10 0.20 25.0 0.67 B 0.37 B 0.62 B 0.26 J 29-Jun-11 5.0 25.0 ND ND ND ND 01-Nov-11 5.0 25.0 ND ND ND ND 01-May-12 5.0 25.0 ND ND ND ND 07-Nov-12 0.085 25.0 0.63 J 0.44 J 0.52 J ND 09-May-13 5.0 25.0 7.8 J 9.1 J 9.4 J ND 07-Nov-13 5.0 25.0 ND ND ND ND 05-Jun-14 5.0 25.0 ND ND ND ND 20-Nov-14 2.5 25.0 ND ND ND ND 27-Apr-15 2.5 25.0 ND 2.80 J ND ND 19-Nov-15 2.5 25.0 13.9 J 18.8 J 14.4 J ND Zinc 30-Dec-09 2.7 10.0 6.7 B ND NS 4.7 J NC 2B = 50 µg/L (05/01/07)01-Jun-10 2.7 10.0 6.7 J 8.7 J NS ND 29-Dec-10 0.40 10.0 ND 1.2 B 1.2 B 12.5 29-Jun-11 10.0 10.0 ND ND ND 10.5 01-Nov-11 10.0 10.0 ND ND ND ND 01-May-12 10.0 10.0 ND ND ND ND 07-Nov-12 1.31 10.0 ND ND 1.56 J ND 09-May-13 10.0 10.0 ND ND ND ND 07-Nov-13 10.0 10.0 ND ND ND ND 05-Jun-14 10.0 10.0 ND ND ND ND 20-Nov-14 5.0 10.0 ND ND ND ND 27-Apr-15 5.0 10.0 8.9 B 10.5 B 9.3 B 7.5 J 19-Nov-15 5.0 10.0 7.5 J 9.2 J 10.1 ND Town of Kernersville Landfill Permit No. 34-04 Page 3 of 4 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Organic Compounds Acetone 29-Jun-11 2.2 100 2.8 B 3.3 B 4.4 B 5.3 J NC 2B = NE µg/L (05/01/07)01-Nov-11 2.2 100 ND ND ND 14.6 J 01-May-12 2.2 100 ND ND ND ND 07-Nov-12 0.193 100 ND ND ND ND 09-May-13 10.0 100 ND ND ND 12.0 J 07-Nov-13 10.0 100 ND ND ND ND 05-Jun-14 10.0 100 ND ND ND ND 20-Nov-14 10.0 100 ND ND ND ND 27-Apr-15 10.0 100 12.4 B 10.6 B 13.8 B 20.7 J 19-Nov-15 10.0 100 ND ND ND ND cis-1,2-Dichloroethene 30-Dec-09 0.1 5.0 ND ND NS ND NC 2B = NE µg/L (05/01/07)01-Jun-10 0.1 5.0 ND ND NS ND 29-Dec-10 0.19 5.0 ND 0.39 J ND ND 29-Jun-11 0.19 5.0 0.26 J 0.30 J 0.33 J ND 01-Nov-11 0.19 5.0 ND ND ND ND 01-May-12 0.19 5.0 0.31 B ND ND 0.21 (ND)J 07-Nov-12 0.103 5.00 ND ND ND ND 09-May-13 0.19 5.0 ND ND ND ND 07-Nov-13 0.19 5.0 ND 0.38 J ND ND 05-Jun-14 0.19 5.0 ND 0.33 J ND ND 20-Nov-14 0.19 5.0 ND 0.49 J ND ND 27-Apr-15 0.19 5.0 ND ND 0.39 J ND 19-Nov-15 0.19 5.0 ND ND ND ND Notes: 1. RL = Reporting limit (NC SWSL). 2. All concentrations are in micrograms per liter (ug/L). 3. NC 2B Standard is the surface water quality standard. Classification is currently Freshwater Aquatic Life. 4. NS = Not sampled. 5. SMP = Surface water monitoring point. 6. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. 7. ND = Not detected at the laboratory's detection limit. 8. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. 9. B = Blank Qualifed 10. Shaded values are greater than the established NC 2B Surface Water Quality Standards. 11. DL = Detection limit. 12. NE = Not established. Town of Kernersville Landfill Permit No. 34-04 Page 4 of 4 Joyce Engineering TABLE 5 SUMMARY OF MNA CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 Alkalinity, Total as CaCO3 Jun-14 1000.0 5000 ---4600 J 148000 147000 160000 186000 (ug/L)Nov-14 1000.0 5000 ------159000 151000 159000 181000 Apr-15 1000.0 5000 ------141000 134000 146000 166000 Nov-15 1000.0 5000 ------158000 147000 158000 185000 Sulfate Jun-14 2000 250000 ---6500 J ND ND ND ND (ug/L)Nov-14 1000 250000 ------1760 J 1730 J 1870 J 1560 J Apr-15 1000 250000 ------ND ND ND ND Nov-15 1000 250000 ------1190 J 1360 J 1520 J 1240 J Nitrogen, Nitrate Jun-14 20.0 1000 ---72 J 56 J ND ND ND (ug/L)Nov-14 10.0 1000 ------45 J ND ND ND Apr-15 10.0 1000 ------ND ND ND ND Nov-15 10.0 1000 ------69.4 15.8 13.1 19.1 Ethene Jun-14 0.5 10 ------ND ND ND ND (ug/L)Nov-14 0.5 10 ------ND ND ND ND Apr-15 0.5 10 ------ND ND ND 4.1 Nov-15 0.5 10 ------ND ND ND ND Methane Jun-14 3.3 6.6 ------5530 254 242 515 (ug/L)Nov-14 3.3 6.6 ------4980 159 182 186 Apr-15 3.3 6.6 ------4160 178 188 536 Nov-15 3.3 6 ------6010 220 160 2.6 J Chloride Jun-14 1000 1000 ---2220 11200 25900 16800 15600 (ug/L)Nov-14 500 1000 ------17100 27900 17300 17100 Apr-15 500 1000 ------12200 26900 17200 17000 Nov-15 500 1000 ------16300 27800 17400 16900 Total Organic Carbon Jun-14 1000 1000 ---3100 10600 8300 1500 8200 (ug/L)Nov-14 500 1000 ------2150 1750 1370 1100 Apr-15 500 1000 ------1510 1720 1380 1630 Nov-15 500 1000 ------889 J 1210 ND 1900 Hydrogen Jun-14 0.13 0.6 ------1.5 1.2 120 3.5 (nM)Nov-14 0.13 0.6 ------2.0 1.1 4.4 1.4 Apr-15 0.13 0.6 ------2.3 1.4 320 4.4 Nov-15 0.13 0.6 ------1.9 1.4 7.4 1.4 BOD, 5 day Jun-14 2000 2000 ---ND ND ND ND ND (ug/L)Nov-14 2000 2000 ------4900 ND ND ND Apr-15 2000 2000 ------5670 ND ND ND Nov-15 2000 2000 ------5000 ND ND ND Chemical Oxygen Demand Jun-14 12500 25000 ---ND ND ND ND ND (ug/L)Nov-14 12500 25000 ------ND ND 431000 ND Apr-15 12500 25000 ------ND ND ND ND Nov-15 12500 25000 ------ND ND ND 16000 J Acetic Acid Jun-14 890 5000 ------ND ND ND ND (ug/L)Nov-14 890 5000 ------ND ND ND ND Apr-15 890 5000 ------2500 J ND 1700 J ND Nov-15 160 200 ------ND ND ND ND Propionic Acid Jun-14 730 5000 ------ND ND ND ND (ug/L)Nov-14 730 5000 ------ND ND ND ND Apr-15 730 5000 ------750 J ND ND ND Nov-15 65 100 ------ND ND ND ND Total Volatile Fatty Acids Jun-14 ------------ND ND ND ND (ug/L)Nov-14 ------------ND ND ND ND Apr-15 ------------3250 ND 1700 ND Nov-15 ------------ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 1 of 2 Joyce Engineering TABLE 5 SUMMARY OF MNA CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 Ferrious Iron Jun-14 ---------------0.00 0.00 0.90 (mg/L)Nov-14 ------------0.50 0.00 0.00 0.50 Apr-15 ------------0.50 0.20 0.00 0.70 Nov-15 ------------0.50 0.00 0.00 0.50 Oxidation Reduction Potential Jun-14 ------------92.6 65.7 15.4 38.3 (mV)Nov-14 ------------53.2 18.1 65.7 59.1 Apr-15 ------------55.9 31.3 43.9 41.5 Nov-15 ------------100.3 57.6 29.4 34.5 pH Jun-14 ------------5.56 6.62 6.05 6.41 (S.U.)Nov-14 ------------6.26 6.37 6.34 6.42 Apr-15 ------------6.12 6.35 6.29 6.46 Nov-15 ------------6.03 6.15 6.06 6.45 Dissovled Carbon Dioxide Jun-14 ---------------55 80 115 (mg/L)Nov-14 ------------65 45 90 35 Apr-15 ------------55 50 85 80 Nov-15 ------------125 115 90 70 Notes: MW = Monitoring well. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. ND = Not detected at the laboratory's detection limit. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. B = Probable field and/or laboratory contamination since the concentration is within five times the concentration reported in the associated quality control blanks. DL = Detection limit. QL = Quantitation limit (NC SWSL). --- = Monitoring well was not sampled. Town of Kernersville Landfill Permit No. 34-04 Page 2 of 2 Joyce Engineering TABLE 6: BIODEGRADATION SCREENING MATRIX Parameter Concentration Interpretation Possible Points Awarded Points Awarded in Plume Points with DP points without DP points Oxygen < 0.5 mg/L Tolerated, suppresses the reductive pathway at higher 3 0 0 concentrations > 5 mg/L Not tolerated; however, vinyl chloride may be oxidized -3 0 0 aerobically Nitrate < 1 mg/L At higher concentrations may compete with reductive 2 2 2 pathway Iron II (Ferrous Iron)> 1 mg/L Reductive pathway possible; vinyl chloride may be 3 0 0 oxidized under Fe (III) - reducing conditions Sulfate < 20 mg/L At higher concentrations may compete with reductive 2 2 2 pathway Sulfide > 1 mg/L Reductive pathway possible 3 0 0 Methane < 0.5 mg/L Vinyl chloride oxidizes 0 0 0 > 0.5 mg/L Ultimate reductive daughter product, vinyl chloride 3 0 0 accumulates Oxidation Reduction < 50 mV Reductive pathway possible 1 1 1 Potential < -100 mV Reductive pathway likely 2 0 0 pH 5 < pH < 9 Optimal range for reductive pathway 0 0 0 5 > pH > 9 Outside optimal range for reductive pathway -2 0 0 TOC > 20 mg/L Carbon and energy source; drives dechlorination; can 2 0 0 be natural or anthropogenic Temperature >20o C At T > 20oC biochemical process is accelerated 1 0 0 Carbon Dioxide > 2x background Ultimate oxidative daughter product 1 0 0 Alkalinity > 2x background Results from interaction between CO2 and 1 1 1 aquifer minerals Chloride > 2x background Daughter product of organic chlorine 2 2 2 Hydrogen > 1 nM Reductive pathway possible 3 3 3 < 1 nM Vinyl chloride oxidizes 0 Volatile Fatty Acids > 0.1 mg/L Intermediates resulting from biodegradation of more 2 0 0 complex compounds; carbon and energy source BTEX > 0.1 mg/L Carbon and energy source; drives dechlorination 2 0 0 Tetrachloroethene (PCE)---Material released 0 0 0 Trichloroethene (TCE)---Material released 0 0 0 ---Daughter product of PCE 2 2 0 Dichloroethenes (DCE)---Material released 0 0 0 Daughter product of TCE 2 2 0 Dichloroethene, cis-1,2,---Material released 0 0 0 ---Daughter product of trichlorethene 2 2 0 Vinyl Chloride (VC)---Material released 0 0 0 ---Daughter product of DCE 2 2 0 1,1,1-Trichloroethane (TCA)---Material released 0 0 0 1,1-Dichloroethane (DCA)---Material released 0 0 0 Daughter product of TCA 2 2 0 Chloroethane ---Daughter product of dichloroethane or vinyl chloride 0 0 0 under reducing conditions 2 0 0 Ethene/Ethane > 0.01 mg/L Daughter products of vinyl chloride/ethene 2 0 0 > 0.1 mg/L 3 0 0 Chloroform ---Material released 0 0 0 ---Daughter product of carbon tetrachloride 2 0 0 Dichloromethane (MC)---Material released 0 0 0 (Methylene Chloride)---Daughter product of chloroform 2 0 0 Based on data collected in November 2015.Total Points Awarded :21 11 mg/L = miligrams per liter mV = millivolts NOTE: Chloroethane, Methane, TCE, DCE, cis-1,2-DCE, MC, VC, DCA, and CO2 are all present in the plume; however, nM = Nanometer it is uncertain whether these are primary leachate constituents or daughter products (DPs); therefore, we C = Celcius have two calculation columns. The first column assumes all of these are daughter products, and the NA = Not Analyzed second column assumes none of them are. The true score is probably between the two. BTEX = Sum of Benzene, Toluene, Ethylbenzene, and Total Xylenes SCORE:Evid. of Nat. Atten. This screening matrix is prepared in general accordance with the United Stated Environmental Protection Agency's < 5 inadequate (EPA's) Table 2.3 Analytical Parameters and Weighted for Preliminary Screening for Anaerobic Biodegradation 6-14 limited Process presented in the EPA's Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents 15-19 adequate in Groundwater, September 1988.> 20 strong Town of Kernersville Joyce Engineering Figure Figure 1 Site Location Map Drawing Drawing 1 Potentiometric Surface Contour Map Appendix I Laboratory Analytical Report and Field Data Logs #=CL# December 22, 2015 LIMS USE: FR - ALEX EVERHART LIMS OBJECT ID: 92277051 92277051 Project: Pace Project No.: RE: Mr. Alex Everhart Joyce Engineering-NC 2211 W. Meadowview Road Suite 101 Greensboro, NC 27407 TOWN OF KERNERSVILLE Dear Mr. Everhart: Enclosed are the analytical results for sample(s) received by the laboratory on November 20, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. Some analyses have been subcontracted outside of the Pace Network. The subcontracted laboratory report has been attached. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Godwin kevin.godwin@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 17 #=CL# December 22, 2015 Page 2 LIMS USE: FR - ALEX EVERHART LIMS OBJECT ID: 92277051 cc:Mr. Van Burbach, Joyce Engineering-NC Alex Everhart, Joyce Engineering-NC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 17 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92277051 TOWN OF KERNERSVILLE Lab ID Sample ID Matrix Date Collected Date Received 92277051001 3404-MW2 Water 11/19/15 13:14 11/20/15 09:00 92277051002 3404-MW3S Water 11/19/15 10:27 11/20/15 09:00 92277051003 3404-MW3D Water 11/19/15 11:08 11/20/15 09:00 92277051004 3404-MW4 Water 11/19/15 12:05 11/20/15 09:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 17 Page 4 of 17 Page 5 of 17 Page 6 of 17 Page 7 of 17 Page 8 of 17 Page 9 of 17 Page 10 of 17 Page 11 of 17 Page 12 of 17 Page 13 of 17 Page 14 of 17 Page 15 of 17 Page 16 of 17 Page 17 of 17 #=CL# December 03, 2015 LIMS USE: FR - ALEX EVERHART LIMS OBJECT ID: 92277056 92277056 Project: Pace Project No.: RE: Mr. Alex Everhart Joyce Engineering-NC 2211 W. Meadowview Road Suite 101 Greensboro, NC 27407 TOWN OF KERNERSVILLE Dear Mr. Everhart: Enclosed are the analytical results for sample(s) received by the laboratory on November 20, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Godwin kevin.godwin@pacelabs.com Project Manager Enclosures cc:Mr. Van Burbach, Joyce Engineering-NC Alex Everhart, Joyce Engineering-NC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 44 #=CP# CERTIFICATIONS Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84 West Virginia Certification #: 357Virginia/VELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 44 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Lab ID Sample ID Matrix Date Collected Date Received 92277056001 3404-MW2 Water 11/19/15 12:41 11/20/15 09:00 92277056002 3404-MW3S Water 11/19/15 10:02 11/20/15 09:00 92277056003 3404-MW3D Water 11/19/15 11:08 11/20/15 09:00 92277056004 3404-MW4 Water 11/19/15 11:34 11/20/15 09:00 92277056005 3404-MW5 Water 11/19/15 09:41 11/20/15 09:00 92277056006 3404-SW1 Water 11/19/15 13:05 11/20/15 09:00 92277056007 3404-SW2 Water 11/19/15 12:55 11/20/15 09:00 92277056008 3404-SW3 Water 11/19/15 11:55 11/20/15 09:00 92277056009 3404-FIELD BLANK Water 11/19/15 13:20 11/20/15 09:00 92277056010 3404-TRIP BLANK Water 11/19/15 08:00 11/20/15 09:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 44 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92277056001 3404-MW2 EPA 6010 15 PASI-ACDF EPA 8260 50 PASI-CNB 92277056002 3404-MW3S EPA 6010 15 PASI-ACDF EPA 8260 50 PASI-CNB 92277056003 3404-MW3D EPA 6010 15 PASI-ACDF EPA 8260 50 PASI-CNB 92277056004 3404-MW4 EPA 6010 15 PASI-ACDF EPA 8260 50 PASI-CNB 92277056005 3404-MW5 EPA 6010 15 PASI-ACDF EPA 8260 50 PASI-CNB 92277056006 3404-SW1 EPA 6010 15 PASI-ACDF EPA 8260 50 PASI-CNB 92277056007 3404-SW2 EPA 6010 15 PASI-ACDF EPA 8260 50 PASI-CNB 92277056008 3404-SW3 EPA 6010 15 PASI-ACDF EPA 8260 50 PASI-CNB 92277056009 3404-FIELD BLANK EPA 6010 15 PASI-ACDF EPA 8260 50 PASI-CNB 92277056010 3404-TRIP BLANK EPA 8260 50 PASI-CNB REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 44 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92277056001 3404-MW2 Barium 294 ug/L 11/30/15 19:19100EPA 6010 Vanadium 3.1J ug/L 11/30/15 19:1925.0EPA 6010 Benzene 6.0 ug/L 11/21/15 15:431.0EPA 8260 Chlorobenzene 0.31J ug/L 11/21/15 15:433.0EPA 8260 1,4-Dichlorobenzene 4.8 ug/L 11/21/15 15:431.0EPA 8260 1,1-Dichloroethane 20.7 ug/L 11/21/15 15:435.0EPA 8260 1,2-Dichloroethane 0.86J ug/L 11/21/15 15:431.0EPA 8260 cis-1,2-Dichloroethene 44.4 ug/L 11/21/15 15:435.0EPA 8260 trans-1,2-Dichloroethene 1.5J ug/L 11/21/15 15:435.0EPA 8260 1,2-Dichloropropane 4.3 ug/L 11/21/15 15:431.0EPA 8260 Tetrachloroethene 0.90J ug/L 11/21/15 15:431.0EPA 8260 Trichloroethene 4.7 ug/L 11/21/15 15:431.0EPA 8260 Trichlorofluoromethane 0.41J ug/L 11/21/15 15:431.0EPA 8260 Vinyl chloride 7.7 ug/L 11/21/15 15:43 M11.0EPA 8260 92277056002 3404-MW3S Barium 108 ug/L 11/30/15 19:22100EPA 6010 Cobalt 3.9J ug/L 11/30/15 19:2210.0EPA 6010 Vanadium 4.3J ug/L 11/30/15 19:2225.0EPA 6010 Zinc 23.1 ug/L 11/30/15 19:2210.0EPA 6010 Chlorobenzene 0.81J ug/L 11/21/15 16:003.0EPA 8260 1,4-Dichlorobenzene 1.4 ug/L 11/21/15 16:001.0EPA 8260 1,1-Dichloroethane 0.82J ug/L 11/21/15 16:005.0EPA 8260 1,2-Dichloroethane 0.40J ug/L 11/21/15 16:001.0EPA 8260 cis-1,2-Dichloroethene 5.6 ug/L 11/21/15 16:005.0EPA 8260 Vinyl chloride 2.0 ug/L 11/21/15 16:001.0EPA 8260 92277056003 3404-MW3D Barium 42.2J ug/L 12/03/15 01:09100EPA 6010 Thallium 8.8 ug/L 12/03/15 01:095.5EPA 6010 Zinc 7.3J ug/L 12/03/15 01:0910.0EPA 6010 Benzene 0.37J ug/L 11/21/15 16:341.0EPA 8260 Chlorobenzene 0.33J ug/L 11/21/15 16:343.0EPA 8260 1,4-Dichlorobenzene 3.5 ug/L 11/21/15 16:341.0EPA 8260 1,1-Dichloroethane 3.1J ug/L 11/21/15 16:345.0EPA 8260 1,2-Dichloroethane 1.1 ug/L 11/21/15 16:341.0EPA 8260 cis-1,2-Dichloroethene 51.2 ug/L 11/21/15 16:345.0EPA 8260 1,2-Dichloropropane 1.1 ug/L 11/21/15 16:341.0EPA 8260 Vinyl chloride 6.7 ug/L 11/21/15 16:341.0EPA 8260 92277056004 3404-MW4 Arsenic 2.7J ug/L 12/03/15 01:1710.0EPA 6010 Barium 101 ug/L 12/03/15 01:17100EPA 6010 Chromium 3.0J ug/L 12/03/15 01:1710.0EPA 6010 Copper 2.6J ug/L 12/03/15 01:1710.0EPA 6010 Nickel 2.6J ug/L 12/03/15 01:1750.0EPA 6010 Thallium 8.8 ug/L 12/03/15 01:175.5EPA 6010 Vanadium 6.5J ug/L 12/03/15 01:1725.0EPA 6010 Zinc 10.7 ug/L 12/03/15 01:1710.0EPA 6010 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 44 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92277056004 3404-MW4 1,4-Dichlorobenzene 2.5 ug/L 11/21/15 16:511.0EPA 8260 1,1-Dichloroethane 1.8J ug/L 11/21/15 16:515.0EPA 8260 cis-1,2-Dichloroethene 18.8 ug/L 11/21/15 16:515.0EPA 8260 Vinyl chloride 17.3 ug/L 11/21/15 16:511.0EPA 8260 92277056005 3404-MW5 Barium 60.3J ug/L 12/03/15 01:21100EPA 6010 Cobalt 3.5J ug/L 12/03/15 01:2110.0EPA 6010 Copper 5.1J ug/L 12/03/15 01:2110.0EPA 6010 Vanadium 3.9J ug/L 12/03/15 01:2125.0EPA 6010 Zinc 16.3 ug/L 12/03/15 01:2110.0EPA 6010 92277056006 3404-SW1 Arsenic 3.0J ug/L 12/03/15 01:2410.0EPA 6010 Barium 45.8J ug/L 12/03/15 01:24100EPA 6010 Chromium 6.3J ug/L 12/03/15 01:2410.0EPA 6010 Copper 5.2J ug/L 12/03/15 01:2410.0EPA 6010 Lead 4.7J ug/L 12/03/15 01:2410.0EPA 6010 Vanadium 13.9J ug/L 12/03/15 01:2425.0EPA 6010 Zinc 7.5J ug/L 12/03/15 01:2410.0EPA 6010 92277056007 3404-SW2 Barium 44.1J ug/L 12/03/15 01:27100EPA 6010 Chromium 8.6J ug/L 12/03/15 01:2710.0EPA 6010 Copper 6.5J ug/L 12/03/15 01:2710.0EPA 6010 Lead 2.6J ug/L 12/03/15 01:2710.0EPA 6010 Nickel 3.0J ug/L 12/03/15 01:2750.0EPA 6010 Vanadium 18.8J ug/L 12/03/15 01:2725.0EPA 6010 Zinc 9.2J ug/L 12/03/15 01:2710.0EPA 6010 92277056008 3404-SW3 Barium 43.6J ug/L 12/03/15 01:30100EPA 6010 Chromium 5.7J ug/L 12/03/15 01:3010.0EPA 6010 Copper 5.9J ug/L 12/03/15 01:3010.0EPA 6010 Lead 5.0J ug/L 12/03/15 01:3010.0EPA 6010 Vanadium 14.4J ug/L 12/03/15 01:3025.0EPA 6010 Zinc 10.1 ug/L 12/03/15 01:3010.0EPA 6010 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 44 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Sample:3404-MW2 Lab ID:92277056001 Collected:11/19/15 12:41 Received:11/20/15 09:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/30/15 19:19 7440-36-011/25/15 22:006.0 3.8 1 Arsenic ND ug/L 11/30/15 19:19 7440-38-211/25/15 22:0010.0 2.5 1 Barium 294 ug/L 11/30/15 19:19 7440-39-311/25/15 22:001002.5 1 Beryllium ND ug/L 11/30/15 19:19 7440-41-711/25/15 22:001.0 0.50 1 Cadmium ND ug/L 11/30/15 19:19 7440-43-911/25/15 22:001.0 0.50 1 Chromium ND ug/L 11/30/15 19:19 7440-47-311/25/15 22:0010.0 2.5 1 Cobalt ND ug/L 11/30/15 19:19 7440-48-411/25/15 22:0010.0 2.5 1 Copper ND ug/L 11/30/15 19:19 7440-50-811/25/15 22:0010.0 2.5 1 Lead ND ug/L 11/30/15 19:19 7439-92-111/25/15 22:0010.0 2.5 1 Nickel ND ug/L 11/30/15 19:19 7440-02-011/25/15 22:0050.0 2.5 1 Selenium ND ug/L 11/30/15 19:19 7782-49-211/25/15 22:0010.0 5.0 1 Silver ND ug/L 11/30/15 19:19 7440-22-411/25/15 22:0010.0 2.5 1 Thallium ND ug/L 12/01/15 19:12 7440-28-011/25/15 22:005.5 5.0 1 Vanadium 3.1J ug/L 11/30/15 19:19 7440-62-211/25/15 22:0025.0 2.5 1 Zinc ND ug/L 11/30/15 19:19 7440-66-611/25/15 22:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 11/21/15 15:43 67-64-110010.0 1 Acrylonitrile ND ug/L 11/21/15 15:43 107-13-12001.9 1 Benzene 6.0 ug/L 11/21/15 15:43 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 11/21/15 15:43 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 11/21/15 15:43 75-27-41.0 0.18 1 Bromoform ND ug/L 11/21/15 15:43 75-25-23.0 0.26 1 Bromomethane ND ug/L 11/21/15 15:43 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 11/21/15 15:43 78-93-31000.96 1 Carbon disulfide ND ug/L 11/21/15 15:43 75-15-01001.2 1 Carbon tetrachloride ND ug/L 11/21/15 15:43 56-23-51.0 0.25 1 Chlorobenzene 0.31J ug/L 11/21/15 15:43 108-90-73.0 0.23 1 Chloroethane ND ug/L 11/21/15 15:43 75-00-310.0 0.54 1 Chloroform ND ug/L 11/21/15 15:43 67-66-35.0 0.14 1 Chloromethane ND ug/L 11/21/15 15:43 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 11/21/15 15:43 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 11/21/15 15:43 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 11/21/15 15:43 106-93-41.0 0.27 1 Dibromomethane ND ug/L 11/21/15 15:43 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 11/21/15 15:43 95-50-15.0 0.30 1 1,4-Dichlorobenzene 4.8 ug/L 11/21/15 15:43 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 11/21/15 15:43 110-57-6 M11001.0 1 1,1-Dichloroethane 20.7 ug/L 11/21/15 15:43 75-34-35.0 0.32 1 1,2-Dichloroethane 0.86J ug/L 11/21/15 15:43 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 11/21/15 15:43 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 44.4 ug/L 11/21/15 15:43 156-59-25.0 0.19 1 trans-1,2-Dichloroethene 1.5J ug/L 11/21/15 15:43 156-60-55.0 0.49 1 1,2-Dichloropropane 4.3 ug/L 11/21/15 15:43 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 11/21/15 15:43 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 11/21/15 15:43 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 44 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Sample:3404-MW2 Lab ID:92277056001 Collected:11/19/15 12:41 Received:11/20/15 09:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Ethylbenzene ND ug/L 11/21/15 15:43 100-41-41.0 0.30 1 2-Hexanone ND ug/L 11/21/15 15:43 591-78-650.0 0.46 1 Iodomethane ND ug/L 11/21/15 15:43 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 11/21/15 15:43 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 11/21/15 15:43 108-10-11000.33 1 Styrene ND ug/L 11/21/15 15:43 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 11/21/15 15:43 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 11/21/15 15:43 79-34-53.0 0.40 1 Tetrachloroethene 0.90J ug/L 11/21/15 15:43 127-18-41.0 0.46 1 Toluene ND ug/L 11/21/15 15:43 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 11/21/15 15:43 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 11/21/15 15:43 79-00-51.0 0.29 1 Trichloroethene 4.7 ug/L 11/21/15 15:43 79-01-61.0 0.47 1 Trichlorofluoromethane 0.41J ug/L 11/21/15 15:43 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 11/21/15 15:43 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 11/21/15 15:43 108-05-450.0 0.35 1 Vinyl chloride 7.7 ug/L 11/21/15 15:43 75-01-4 M11.0 0.62 1 Xylene (Total)ND ug/L 11/21/15 15:43 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)103 %11/21/15 15:43 460-00-470-130 1 1,2-Dichloroethane-d4 (S)103 %11/21/15 15:43 17060-07-070-130 1 Toluene-d8 (S)101 %11/21/15 15:43 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 44 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Sample:3404-MW3S Lab ID:92277056002 Collected:11/19/15 10:02 Received:11/20/15 09:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/30/15 19:22 7440-36-011/25/15 22:006.0 3.8 1 Arsenic ND ug/L 11/30/15 19:22 7440-38-211/25/15 22:0010.0 2.5 1 Barium 108 ug/L 11/30/15 19:22 7440-39-311/25/15 22:001002.5 1 Beryllium ND ug/L 11/30/15 19:22 7440-41-711/25/15 22:001.0 0.50 1 Cadmium ND ug/L 11/30/15 19:22 7440-43-911/25/15 22:001.0 0.50 1 Chromium ND ug/L 11/30/15 19:22 7440-47-311/25/15 22:0010.0 2.5 1 Cobalt 3.9J ug/L 11/30/15 19:22 7440-48-411/25/15 22:0010.0 2.5 1 Copper ND ug/L 11/30/15 19:22 7440-50-811/25/15 22:0010.0 2.5 1 Lead ND ug/L 11/30/15 19:22 7439-92-111/25/15 22:0010.0 2.5 1 Nickel ND ug/L 11/30/15 19:22 7440-02-011/25/15 22:0050.0 2.5 1 Selenium ND ug/L 11/30/15 19:22 7782-49-211/25/15 22:0010.0 5.0 1 Silver ND ug/L 11/30/15 19:22 7440-22-411/25/15 22:0010.0 2.5 1 Thallium ND ug/L 12/01/15 19:15 7440-28-011/25/15 22:005.5 5.0 1 Vanadium 4.3J ug/L 11/30/15 19:22 7440-62-211/25/15 22:0025.0 2.5 1 Zinc 23.1 ug/L 11/30/15 19:22 7440-66-611/25/15 22:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 11/21/15 16:00 67-64-110010.0 1 Acrylonitrile ND ug/L 11/21/15 16:00 107-13-12001.9 1 Benzene ND ug/L 11/21/15 16:00 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 11/21/15 16:00 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 11/21/15 16:00 75-27-41.0 0.18 1 Bromoform ND ug/L 11/21/15 16:00 75-25-23.0 0.26 1 Bromomethane ND ug/L 11/21/15 16:00 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 11/21/15 16:00 78-93-31000.96 1 Carbon disulfide ND ug/L 11/21/15 16:00 75-15-01001.2 1 Carbon tetrachloride ND ug/L 11/21/15 16:00 56-23-51.0 0.25 1 Chlorobenzene 0.81J ug/L 11/21/15 16:00 108-90-73.0 0.23 1 Chloroethane ND ug/L 11/21/15 16:00 75-00-310.0 0.54 1 Chloroform ND ug/L 11/21/15 16:00 67-66-35.0 0.14 1 Chloromethane ND ug/L 11/21/15 16:00 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 11/21/15 16:00 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 11/21/15 16:00 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 11/21/15 16:00 106-93-41.0 0.27 1 Dibromomethane ND ug/L 11/21/15 16:00 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 11/21/15 16:00 95-50-15.0 0.30 1 1,4-Dichlorobenzene 1.4 ug/L 11/21/15 16:00 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 11/21/15 16:00 110-57-61001.0 1 1,1-Dichloroethane 0.82J ug/L 11/21/15 16:00 75-34-35.0 0.32 1 1,2-Dichloroethane 0.40J ug/L 11/21/15 16:00 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 11/21/15 16:00 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 5.6 ug/L 11/21/15 16:00 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 11/21/15 16:00 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 11/21/15 16:00 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 11/21/15 16:00 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 11/21/15 16:00 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 44 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Sample:3404-MW3S Lab ID:92277056002 Collected:11/19/15 10:02 Received:11/20/15 09:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Ethylbenzene ND ug/L 11/21/15 16:00 100-41-41.0 0.30 1 2-Hexanone ND ug/L 11/21/15 16:00 591-78-650.0 0.46 1 Iodomethane ND ug/L 11/21/15 16:00 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 11/21/15 16:00 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 11/21/15 16:00 108-10-11000.33 1 Styrene ND ug/L 11/21/15 16:00 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 11/21/15 16:00 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 11/21/15 16:00 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 11/21/15 16:00 127-18-41.0 0.46 1 Toluene ND ug/L 11/21/15 16:00 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 11/21/15 16:00 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 11/21/15 16:00 79-00-51.0 0.29 1 Trichloroethene ND ug/L 11/21/15 16:00 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 11/21/15 16:00 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 11/21/15 16:00 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 11/21/15 16:00 108-05-450.0 0.35 1 Vinyl chloride 2.0 ug/L 11/21/15 16:00 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 11/21/15 16:00 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)105 %11/21/15 16:00 460-00-470-130 1 1,2-Dichloroethane-d4 (S)102 %11/21/15 16:00 17060-07-070-130 1 Toluene-d8 (S)101 %11/21/15 16:00 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 44 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Sample:3404-MW3D Lab ID:92277056003 Collected:11/19/15 11:08 Received:11/20/15 09:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 12/03/15 01:09 7440-36-011/25/15 23:306.0 3.8 1 Arsenic ND ug/L 12/03/15 01:09 7440-38-211/25/15 23:3010.0 2.5 1 Barium 42.2J ug/L 12/03/15 01:09 7440-39-311/25/15 23:301002.5 1 Beryllium ND ug/L 12/03/15 01:09 7440-41-711/25/15 23:301.0 0.50 1 Cadmium ND ug/L 12/03/15 01:09 7440-43-911/25/15 23:301.0 0.50 1 Chromium ND ug/L 12/03/15 01:09 7440-47-311/25/15 23:3010.0 2.5 1 Cobalt ND ug/L 12/03/15 01:09 7440-48-411/25/15 23:3010.0 2.5 1 Copper ND ug/L 12/03/15 01:09 7440-50-811/25/15 23:3010.0 2.5 1 Lead ND ug/L 12/03/15 01:09 7439-92-111/25/15 23:3010.0 2.5 1 Nickel ND ug/L 12/03/15 01:09 7440-02-011/25/15 23:3050.0 2.5 1 Selenium ND ug/L 12/03/15 01:09 7782-49-211/25/15 23:3010.0 5.0 1 Silver ND ug/L 12/03/15 01:09 7440-22-411/25/15 23:3010.0 2.5 1 Thallium 8.8 ug/L 12/03/15 01:09 7440-28-011/25/15 23:305.5 5.0 1 Vanadium ND ug/L 12/03/15 01:09 7440-62-211/25/15 23:3025.0 2.5 1 Zinc 7.3J ug/L 12/03/15 01:09 7440-66-611/25/15 23:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 11/21/15 16:34 67-64-110010.0 1 Acrylonitrile ND ug/L 11/21/15 16:34 107-13-12001.9 1 Benzene 0.37J ug/L 11/21/15 16:34 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 11/21/15 16:34 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 11/21/15 16:34 75-27-41.0 0.18 1 Bromoform ND ug/L 11/21/15 16:34 75-25-23.0 0.26 1 Bromomethane ND ug/L 11/21/15 16:34 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 11/21/15 16:34 78-93-31000.96 1 Carbon disulfide ND ug/L 11/21/15 16:34 75-15-01001.2 1 Carbon tetrachloride ND ug/L 11/21/15 16:34 56-23-51.0 0.25 1 Chlorobenzene 0.33J ug/L 11/21/15 16:34 108-90-73.0 0.23 1 Chloroethane ND ug/L 11/21/15 16:34 75-00-310.0 0.54 1 Chloroform ND ug/L 11/21/15 16:34 67-66-35.0 0.14 1 Chloromethane ND ug/L 11/21/15 16:34 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 11/21/15 16:34 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 11/21/15 16:34 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 11/21/15 16:34 106-93-41.0 0.27 1 Dibromomethane ND ug/L 11/21/15 16:34 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 11/21/15 16:34 95-50-15.0 0.30 1 1,4-Dichlorobenzene 3.5 ug/L 11/21/15 16:34 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 11/21/15 16:34 110-57-61001.0 1 1,1-Dichloroethane 3.1J ug/L 11/21/15 16:34 75-34-35.0 0.32 1 1,2-Dichloroethane 1.1 ug/L 11/21/15 16:34 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 11/21/15 16:34 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 51.2 ug/L 11/21/15 16:34 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 11/21/15 16:34 156-60-55.0 0.49 1 1,2-Dichloropropane 1.1 ug/L 11/21/15 16:34 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 11/21/15 16:34 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 11/21/15 16:34 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 44 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Sample:3404-MW3D Lab ID:92277056003 Collected:11/19/15 11:08 Received:11/20/15 09:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Ethylbenzene ND ug/L 11/21/15 16:34 100-41-41.0 0.30 1 2-Hexanone ND ug/L 11/21/15 16:34 591-78-650.0 0.46 1 Iodomethane ND ug/L 11/21/15 16:34 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 11/21/15 16:34 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 11/21/15 16:34 108-10-11000.33 1 Styrene ND ug/L 11/21/15 16:34 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 11/21/15 16:34 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 11/21/15 16:34 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 11/21/15 16:34 127-18-41.0 0.46 1 Toluene ND ug/L 11/21/15 16:34 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 11/21/15 16:34 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 11/21/15 16:34 79-00-51.0 0.29 1 Trichloroethene ND ug/L 11/21/15 16:34 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 11/21/15 16:34 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 11/21/15 16:34 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 11/21/15 16:34 108-05-450.0 0.35 1 Vinyl chloride 6.7 ug/L 11/21/15 16:34 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 11/21/15 16:34 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)104 %11/21/15 16:34 460-00-470-130 1 1,2-Dichloroethane-d4 (S)101 %11/21/15 16:34 17060-07-070-130 1 Toluene-d8 (S)101 %11/21/15 16:34 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 44 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Sample:3404-MW4 Lab ID:92277056004 Collected:11/19/15 11:34 Received:11/20/15 09:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 12/03/15 01:17 7440-36-011/25/15 23:306.0 3.8 1 Arsenic 2.7J ug/L 12/03/15 01:17 7440-38-211/25/15 23:3010.0 2.5 1 Barium 101 ug/L 12/03/15 01:17 7440-39-311/25/15 23:301002.5 1 Beryllium ND ug/L 12/03/15 01:17 7440-41-711/25/15 23:301.0 0.50 1 Cadmium ND ug/L 12/03/15 01:17 7440-43-911/25/15 23:301.0 0.50 1 Chromium 3.0J ug/L 12/03/15 01:17 7440-47-311/25/15 23:3010.0 2.5 1 Cobalt ND ug/L 12/03/15 01:17 7440-48-411/25/15 23:3010.0 2.5 1 Copper 2.6J ug/L 12/03/15 01:17 7440-50-811/25/15 23:3010.0 2.5 1 Lead ND ug/L 12/03/15 01:17 7439-92-111/25/15 23:3010.0 2.5 1 Nickel 2.6J ug/L 12/03/15 01:17 7440-02-011/25/15 23:3050.0 2.5 1 Selenium ND ug/L 12/03/15 01:17 7782-49-211/25/15 23:3010.0 5.0 1 Silver ND ug/L 12/03/15 01:17 7440-22-411/25/15 23:3010.0 2.5 1 Thallium 8.8 ug/L 12/03/15 01:17 7440-28-011/25/15 23:305.5 5.0 1 Vanadium 6.5J ug/L 12/03/15 01:17 7440-62-211/25/15 23:3025.0 2.5 1 Zinc 10.7 ug/L 12/03/15 01:17 7440-66-611/25/15 23:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 11/21/15 16:51 67-64-110010.0 1 Acrylonitrile ND ug/L 11/21/15 16:51 107-13-12001.9 1 Benzene ND ug/L 11/21/15 16:51 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 11/21/15 16:51 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 11/21/15 16:51 75-27-41.0 0.18 1 Bromoform ND ug/L 11/21/15 16:51 75-25-23.0 0.26 1 Bromomethane ND ug/L 11/21/15 16:51 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 11/21/15 16:51 78-93-31000.96 1 Carbon disulfide ND ug/L 11/21/15 16:51 75-15-01001.2 1 Carbon tetrachloride ND ug/L 11/21/15 16:51 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 11/21/15 16:51 108-90-73.0 0.23 1 Chloroethane ND ug/L 11/21/15 16:51 75-00-310.0 0.54 1 Chloroform ND ug/L 11/21/15 16:51 67-66-35.0 0.14 1 Chloromethane ND ug/L 11/21/15 16:51 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 11/21/15 16:51 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 11/21/15 16:51 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 11/21/15 16:51 106-93-41.0 0.27 1 Dibromomethane ND ug/L 11/21/15 16:51 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 11/21/15 16:51 95-50-15.0 0.30 1 1,4-Dichlorobenzene 2.5 ug/L 11/21/15 16:51 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 11/21/15 16:51 110-57-61001.0 1 1,1-Dichloroethane 1.8J ug/L 11/21/15 16:51 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 11/21/15 16:51 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 11/21/15 16:51 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 18.8 ug/L 11/21/15 16:51 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 11/21/15 16:51 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 11/21/15 16:51 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 11/21/15 16:51 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 11/21/15 16:51 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 44 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Sample:3404-MW4 Lab ID:92277056004 Collected:11/19/15 11:34 Received:11/20/15 09:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Ethylbenzene ND ug/L 11/21/15 16:51 100-41-41.0 0.30 1 2-Hexanone ND ug/L 11/21/15 16:51 591-78-650.0 0.46 1 Iodomethane ND ug/L 11/21/15 16:51 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 11/21/15 16:51 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 11/21/15 16:51 108-10-11000.33 1 Styrene ND ug/L 11/21/15 16:51 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 11/21/15 16:51 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 11/21/15 16:51 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 11/21/15 16:51 127-18-41.0 0.46 1 Toluene ND ug/L 11/21/15 16:51 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 11/21/15 16:51 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 11/21/15 16:51 79-00-51.0 0.29 1 Trichloroethene ND ug/L 11/21/15 16:51 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 11/21/15 16:51 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 11/21/15 16:51 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 11/21/15 16:51 108-05-450.0 0.35 1 Vinyl chloride 17.3 ug/L 11/21/15 16:51 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 11/21/15 16:51 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)104 %11/21/15 16:51 460-00-470-130 1 1,2-Dichloroethane-d4 (S)100 %11/21/15 16:51 17060-07-070-130 1 Toluene-d8 (S)101 %11/21/15 16:51 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 44 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Sample:3404-MW5 Lab ID:92277056005 Collected:11/19/15 09:41 Received:11/20/15 09:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 12/03/15 01:21 7440-36-011/25/15 23:306.0 3.8 1 Arsenic ND ug/L 12/03/15 01:21 7440-38-211/25/15 23:3010.0 2.5 1 Barium 60.3J ug/L 12/03/15 01:21 7440-39-311/25/15 23:301002.5 1 Beryllium ND ug/L 12/03/15 01:21 7440-41-711/25/15 23:301.0 0.50 1 Cadmium ND ug/L 12/03/15 01:21 7440-43-911/25/15 23:301.0 0.50 1 Chromium ND ug/L 12/03/15 01:21 7440-47-311/25/15 23:3010.0 2.5 1 Cobalt 3.5J ug/L 12/03/15 01:21 7440-48-411/25/15 23:3010.0 2.5 1 Copper 5.1J ug/L 12/03/15 01:21 7440-50-811/25/15 23:3010.0 2.5 1 Lead ND ug/L 12/03/15 01:21 7439-92-111/25/15 23:3010.0 2.5 1 Nickel ND ug/L 12/03/15 01:21 7440-02-011/25/15 23:3050.0 2.5 1 Selenium ND ug/L 12/03/15 01:21 7782-49-211/25/15 23:3010.0 5.0 1 Silver ND ug/L 12/03/15 01:21 7440-22-411/25/15 23:3010.0 2.5 1 Thallium ND ug/L 12/03/15 01:21 7440-28-011/25/15 23:305.5 5.0 1 Vanadium 3.9J ug/L 12/03/15 01:21 7440-62-211/25/15 23:3025.0 2.5 1 Zinc 16.3 ug/L 12/03/15 01:21 7440-66-611/25/15 23:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 11/21/15 17:09 67-64-110010.0 1 Acrylonitrile ND ug/L 11/21/15 17:09 107-13-12001.9 1 Benzene ND ug/L 11/21/15 17:09 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 11/21/15 17:09 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 11/21/15 17:09 75-27-41.0 0.18 1 Bromoform ND ug/L 11/21/15 17:09 75-25-23.0 0.26 1 Bromomethane ND ug/L 11/21/15 17:09 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 11/21/15 17:09 78-93-31000.96 1 Carbon disulfide ND ug/L 11/21/15 17:09 75-15-01001.2 1 Carbon tetrachloride ND ug/L 11/21/15 17:09 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 11/21/15 17:09 108-90-73.0 0.23 1 Chloroethane ND ug/L 11/21/15 17:09 75-00-310.0 0.54 1 Chloroform ND ug/L 11/21/15 17:09 67-66-35.0 0.14 1 Chloromethane ND ug/L 11/21/15 17:09 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 11/21/15 17:09 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 11/21/15 17:09 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 11/21/15 17:09 106-93-41.0 0.27 1 Dibromomethane ND ug/L 11/21/15 17:09 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 11/21/15 17:09 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 11/21/15 17:09 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 11/21/15 17:09 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 11/21/15 17:09 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 11/21/15 17:09 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 11/21/15 17:09 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 11/21/15 17:09 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 11/21/15 17:09 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 11/21/15 17:09 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 11/21/15 17:09 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 11/21/15 17:09 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 44 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Sample:3404-MW5 Lab ID:92277056005 Collected:11/19/15 09:41 Received:11/20/15 09:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Ethylbenzene ND ug/L 11/21/15 17:09 100-41-41.0 0.30 1 2-Hexanone ND ug/L 11/21/15 17:09 591-78-650.0 0.46 1 Iodomethane ND ug/L 11/21/15 17:09 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 11/21/15 17:09 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 11/21/15 17:09 108-10-11000.33 1 Styrene ND ug/L 11/21/15 17:09 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 11/21/15 17:09 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 11/21/15 17:09 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 11/21/15 17:09 127-18-41.0 0.46 1 Toluene ND ug/L 11/21/15 17:09 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 11/21/15 17:09 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 11/21/15 17:09 79-00-51.0 0.29 1 Trichloroethene ND ug/L 11/21/15 17:09 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 11/21/15 17:09 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 11/21/15 17:09 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 11/21/15 17:09 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 11/21/15 17:09 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 11/21/15 17:09 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)107 %11/21/15 17:09 460-00-470-130 1 1,2-Dichloroethane-d4 (S)99 %11/21/15 17:09 17060-07-070-130 1 Toluene-d8 (S)100 %11/21/15 17:09 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 44 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Sample:3404-SW1 Lab ID:92277056006 Collected:11/19/15 13:05 Received:11/20/15 09:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 12/03/15 01:24 7440-36-011/25/15 23:306.0 3.8 1 Arsenic 3.0J ug/L 12/03/15 01:24 7440-38-211/25/15 23:3010.0 2.5 1 Barium 45.8J ug/L 12/03/15 01:24 7440-39-311/25/15 23:301002.5 1 Beryllium ND ug/L 12/03/15 01:24 7440-41-711/25/15 23:301.0 0.50 1 Cadmium ND ug/L 12/03/15 01:24 7440-43-911/25/15 23:301.0 0.50 1 Chromium 6.3J ug/L 12/03/15 01:24 7440-47-311/25/15 23:3010.0 2.5 1 Cobalt ND ug/L 12/03/15 01:24 7440-48-411/25/15 23:3010.0 2.5 1 Copper 5.2J ug/L 12/03/15 01:24 7440-50-811/25/15 23:3010.0 2.5 1 Lead 4.7J ug/L 12/03/15 01:24 7439-92-111/25/15 23:3010.0 2.5 1 Nickel ND ug/L 12/03/15 01:24 7440-02-011/25/15 23:3050.0 2.5 1 Selenium ND ug/L 12/03/15 01:24 7782-49-211/25/15 23:3010.0 5.0 1 Silver ND ug/L 12/03/15 01:24 7440-22-411/25/15 23:3010.0 2.5 1 Thallium ND ug/L 12/03/15 01:24 7440-28-011/25/15 23:305.5 5.0 1 Vanadium 13.9J ug/L 12/03/15 01:24 7440-62-211/25/15 23:3025.0 2.5 1 Zinc 7.5J ug/L 12/03/15 01:24 7440-66-611/25/15 23:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 11/21/15 17:26 67-64-110010.0 1 Acrylonitrile ND ug/L 11/21/15 17:26 107-13-12001.9 1 Benzene ND ug/L 11/21/15 17:26 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 11/21/15 17:26 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 11/21/15 17:26 75-27-41.0 0.18 1 Bromoform ND ug/L 11/21/15 17:26 75-25-23.0 0.26 1 Bromomethane ND ug/L 11/21/15 17:26 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 11/21/15 17:26 78-93-31000.96 1 Carbon disulfide ND ug/L 11/21/15 17:26 75-15-01001.2 1 Carbon tetrachloride ND ug/L 11/21/15 17:26 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 11/21/15 17:26 108-90-73.0 0.23 1 Chloroethane ND ug/L 11/21/15 17:26 75-00-310.0 0.54 1 Chloroform ND ug/L 11/21/15 17:26 67-66-35.0 0.14 1 Chloromethane ND ug/L 11/21/15 17:26 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 11/21/15 17:26 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 11/21/15 17:26 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 11/21/15 17:26 106-93-41.0 0.27 1 Dibromomethane ND ug/L 11/21/15 17:26 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 11/21/15 17:26 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 11/21/15 17:26 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 11/21/15 17:26 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 11/21/15 17:26 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 11/21/15 17:26 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 11/21/15 17:26 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 11/21/15 17:26 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 11/21/15 17:26 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 11/21/15 17:26 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 11/21/15 17:26 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 11/21/15 17:26 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 44 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Sample:3404-SW1 Lab ID:92277056006 Collected:11/19/15 13:05 Received:11/20/15 09:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Ethylbenzene ND ug/L 11/21/15 17:26 100-41-41.0 0.30 1 2-Hexanone ND ug/L 11/21/15 17:26 591-78-650.0 0.46 1 Iodomethane ND ug/L 11/21/15 17:26 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 11/21/15 17:26 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 11/21/15 17:26 108-10-11000.33 1 Styrene ND ug/L 11/21/15 17:26 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 11/21/15 17:26 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 11/21/15 17:26 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 11/21/15 17:26 127-18-41.0 0.46 1 Toluene ND ug/L 11/21/15 17:26 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 11/21/15 17:26 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 11/21/15 17:26 79-00-51.0 0.29 1 Trichloroethene ND ug/L 11/21/15 17:26 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 11/21/15 17:26 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 11/21/15 17:26 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 11/21/15 17:26 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 11/21/15 17:26 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 11/21/15 17:26 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)104 %11/21/15 17:26 460-00-470-130 1 1,2-Dichloroethane-d4 (S)102 %11/21/15 17:26 17060-07-070-130 1 Toluene-d8 (S)101 %11/21/15 17:26 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 44 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Sample:3404-SW2 Lab ID:92277056007 Collected:11/19/15 12:55 Received:11/20/15 09:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 12/03/15 01:27 7440-36-011/25/15 23:306.0 3.8 1 Arsenic ND ug/L 12/03/15 01:27 7440-38-211/25/15 23:3010.0 2.5 1 Barium 44.1J ug/L 12/03/15 01:27 7440-39-311/25/15 23:301002.5 1 Beryllium ND ug/L 12/03/15 01:27 7440-41-711/25/15 23:301.0 0.50 1 Cadmium ND ug/L 12/03/15 01:27 7440-43-911/25/15 23:301.0 0.50 1 Chromium 8.6J ug/L 12/03/15 01:27 7440-47-311/25/15 23:3010.0 2.5 1 Cobalt ND ug/L 12/03/15 01:27 7440-48-411/25/15 23:3010.0 2.5 1 Copper 6.5J ug/L 12/03/15 01:27 7440-50-811/25/15 23:3010.0 2.5 1 Lead 2.6J ug/L 12/03/15 01:27 7439-92-111/25/15 23:3010.0 2.5 1 Nickel 3.0J ug/L 12/03/15 01:27 7440-02-011/25/15 23:3050.0 2.5 1 Selenium ND ug/L 12/03/15 01:27 7782-49-211/25/15 23:3010.0 5.0 1 Silver ND ug/L 12/03/15 01:27 7440-22-411/25/15 23:3010.0 2.5 1 Thallium ND ug/L 12/03/15 01:27 7440-28-011/25/15 23:305.5 5.0 1 Vanadium 18.8J ug/L 12/03/15 01:27 7440-62-211/25/15 23:3025.0 2.5 1 Zinc 9.2J ug/L 12/03/15 01:27 7440-66-611/25/15 23:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 11/21/15 17:43 67-64-110010.0 1 Acrylonitrile ND ug/L 11/21/15 17:43 107-13-12001.9 1 Benzene ND ug/L 11/21/15 17:43 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 11/21/15 17:43 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 11/21/15 17:43 75-27-41.0 0.18 1 Bromoform ND ug/L 11/21/15 17:43 75-25-23.0 0.26 1 Bromomethane ND ug/L 11/21/15 17:43 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 11/21/15 17:43 78-93-31000.96 1 Carbon disulfide ND ug/L 11/21/15 17:43 75-15-01001.2 1 Carbon tetrachloride ND ug/L 11/21/15 17:43 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 11/21/15 17:43 108-90-73.0 0.23 1 Chloroethane ND ug/L 11/21/15 17:43 75-00-310.0 0.54 1 Chloroform ND ug/L 11/21/15 17:43 67-66-35.0 0.14 1 Chloromethane ND ug/L 11/21/15 17:43 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 11/21/15 17:43 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 11/21/15 17:43 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 11/21/15 17:43 106-93-41.0 0.27 1 Dibromomethane ND ug/L 11/21/15 17:43 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 11/21/15 17:43 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 11/21/15 17:43 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 11/21/15 17:43 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 11/21/15 17:43 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 11/21/15 17:43 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 11/21/15 17:43 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 11/21/15 17:43 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 11/21/15 17:43 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 11/21/15 17:43 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 11/21/15 17:43 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 11/21/15 17:43 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 44 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Sample:3404-SW2 Lab ID:92277056007 Collected:11/19/15 12:55 Received:11/20/15 09:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Ethylbenzene ND ug/L 11/21/15 17:43 100-41-41.0 0.30 1 2-Hexanone ND ug/L 11/21/15 17:43 591-78-650.0 0.46 1 Iodomethane ND ug/L 11/21/15 17:43 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 11/21/15 17:43 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 11/21/15 17:43 108-10-11000.33 1 Styrene ND ug/L 11/21/15 17:43 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 11/21/15 17:43 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 11/21/15 17:43 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 11/21/15 17:43 127-18-41.0 0.46 1 Toluene ND ug/L 11/21/15 17:43 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 11/21/15 17:43 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 11/21/15 17:43 79-00-51.0 0.29 1 Trichloroethene ND ug/L 11/21/15 17:43 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 11/21/15 17:43 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 11/21/15 17:43 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 11/21/15 17:43 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 11/21/15 17:43 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 11/21/15 17:43 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)104 %11/21/15 17:43 460-00-470-130 1 1,2-Dichloroethane-d4 (S)102 %11/21/15 17:43 17060-07-070-130 1 Toluene-d8 (S)103 %11/21/15 17:43 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 44 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Sample:3404-SW3 Lab ID:92277056008 Collected:11/19/15 11:55 Received:11/20/15 09:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 12/03/15 01:30 7440-36-011/25/15 23:306.0 3.8 1 Arsenic ND ug/L 12/03/15 01:30 7440-38-211/25/15 23:3010.0 2.5 1 Barium 43.6J ug/L 12/03/15 01:30 7440-39-311/25/15 23:301002.5 1 Beryllium ND ug/L 12/03/15 01:30 7440-41-711/25/15 23:301.0 0.50 1 Cadmium ND ug/L 12/03/15 01:30 7440-43-911/25/15 23:301.0 0.50 1 Chromium 5.7J ug/L 12/03/15 01:30 7440-47-311/25/15 23:3010.0 2.5 1 Cobalt ND ug/L 12/03/15 01:30 7440-48-411/25/15 23:3010.0 2.5 1 Copper 5.9J ug/L 12/03/15 01:30 7440-50-811/25/15 23:3010.0 2.5 1 Lead 5.0J ug/L 12/03/15 01:30 7439-92-111/25/15 23:3010.0 2.5 1 Nickel ND ug/L 12/03/15 01:30 7440-02-011/25/15 23:3050.0 2.5 1 Selenium ND ug/L 12/03/15 01:30 7782-49-211/25/15 23:3010.0 5.0 1 Silver ND ug/L 12/03/15 01:30 7440-22-411/25/15 23:3010.0 2.5 1 Thallium ND ug/L 12/03/15 01:30 7440-28-011/25/15 23:305.5 5.0 1 Vanadium 14.4J ug/L 12/03/15 01:30 7440-62-211/25/15 23:3025.0 2.5 1 Zinc 10.1 ug/L 12/03/15 01:30 7440-66-611/25/15 23:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 11/21/15 18:00 67-64-110010.0 1 Acrylonitrile ND ug/L 11/21/15 18:00 107-13-12001.9 1 Benzene ND ug/L 11/21/15 18:00 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 11/21/15 18:00 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 11/21/15 18:00 75-27-41.0 0.18 1 Bromoform ND ug/L 11/21/15 18:00 75-25-23.0 0.26 1 Bromomethane ND ug/L 11/21/15 18:00 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 11/21/15 18:00 78-93-31000.96 1 Carbon disulfide ND ug/L 11/21/15 18:00 75-15-01001.2 1 Carbon tetrachloride ND ug/L 11/21/15 18:00 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 11/21/15 18:00 108-90-73.0 0.23 1 Chloroethane ND ug/L 11/21/15 18:00 75-00-310.0 0.54 1 Chloroform ND ug/L 11/21/15 18:00 67-66-35.0 0.14 1 Chloromethane ND ug/L 11/21/15 18:00 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 11/21/15 18:00 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 11/21/15 18:00 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 11/21/15 18:00 106-93-41.0 0.27 1 Dibromomethane ND ug/L 11/21/15 18:00 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 11/21/15 18:00 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 11/21/15 18:00 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 11/21/15 18:00 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 11/21/15 18:00 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 11/21/15 18:00 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 11/21/15 18:00 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 11/21/15 18:00 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 11/21/15 18:00 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 11/21/15 18:00 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 11/21/15 18:00 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 11/21/15 18:00 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 44 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Sample:3404-SW3 Lab ID:92277056008 Collected:11/19/15 11:55 Received:11/20/15 09:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Ethylbenzene ND ug/L 11/21/15 18:00 100-41-41.0 0.30 1 2-Hexanone ND ug/L 11/21/15 18:00 591-78-650.0 0.46 1 Iodomethane ND ug/L 11/21/15 18:00 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 11/21/15 18:00 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 11/21/15 18:00 108-10-11000.33 1 Styrene ND ug/L 11/21/15 18:00 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 11/21/15 18:00 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 11/21/15 18:00 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 11/21/15 18:00 127-18-41.0 0.46 1 Toluene ND ug/L 11/21/15 18:00 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 11/21/15 18:00 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 11/21/15 18:00 79-00-51.0 0.29 1 Trichloroethene ND ug/L 11/21/15 18:00 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 11/21/15 18:00 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 11/21/15 18:00 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 11/21/15 18:00 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 11/21/15 18:00 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 11/21/15 18:00 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)103 %11/21/15 18:00 460-00-470-130 1 1,2-Dichloroethane-d4 (S)100 %11/21/15 18:00 17060-07-070-130 1 Toluene-d8 (S)100 %11/21/15 18:00 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 44 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Sample:3404-FIELD BLANK Lab ID:92277056009 Collected:11/19/15 13:20 Received:11/20/15 09:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 12/03/15 01:33 7440-36-011/25/15 23:306.0 3.8 1 Arsenic ND ug/L 12/03/15 01:33 7440-38-211/25/15 23:3010.0 2.5 1 Barium ND ug/L 12/03/15 01:33 7440-39-311/25/15 23:301002.5 1 Beryllium ND ug/L 12/03/15 01:33 7440-41-711/25/15 23:301.0 0.50 1 Cadmium ND ug/L 12/03/15 01:33 7440-43-911/25/15 23:301.0 0.50 1 Chromium ND ug/L 12/03/15 01:33 7440-47-311/25/15 23:3010.0 2.5 1 Cobalt ND ug/L 12/03/15 01:33 7440-48-411/25/15 23:3010.0 2.5 1 Copper ND ug/L 12/03/15 01:33 7440-50-811/25/15 23:3010.0 2.5 1 Lead ND ug/L 12/03/15 01:33 7439-92-111/25/15 23:3010.0 2.5 1 Nickel ND ug/L 12/03/15 01:33 7440-02-011/25/15 23:3050.0 2.5 1 Selenium ND ug/L 12/03/15 01:33 7782-49-211/25/15 23:3010.0 5.0 1 Silver ND ug/L 12/03/15 01:33 7440-22-411/25/15 23:3010.0 2.5 1 Thallium ND ug/L 12/03/15 01:33 7440-28-011/25/15 23:305.5 5.0 1 Vanadium ND ug/L 12/03/15 01:33 7440-62-211/25/15 23:3025.0 2.5 1 Zinc ND ug/L 12/03/15 01:33 7440-66-611/25/15 23:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 11/21/15 20:33 67-64-110010.0 1 Acrylonitrile ND ug/L 11/21/15 20:33 107-13-12001.9 1 Benzene ND ug/L 11/21/15 20:33 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 11/21/15 20:33 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 11/21/15 20:33 75-27-41.0 0.18 1 Bromoform ND ug/L 11/21/15 20:33 75-25-23.0 0.26 1 Bromomethane ND ug/L 11/21/15 20:33 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 11/21/15 20:33 78-93-31000.96 1 Carbon disulfide ND ug/L 11/21/15 20:33 75-15-01001.2 1 Carbon tetrachloride ND ug/L 11/21/15 20:33 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 11/21/15 20:33 108-90-73.0 0.23 1 Chloroethane ND ug/L 11/21/15 20:33 75-00-310.0 0.54 1 Chloroform ND ug/L 11/21/15 20:33 67-66-35.0 0.14 1 Chloromethane ND ug/L 11/21/15 20:33 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 11/21/15 20:33 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 11/21/15 20:33 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 11/21/15 20:33 106-93-41.0 0.27 1 Dibromomethane ND ug/L 11/21/15 20:33 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 11/21/15 20:33 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 11/21/15 20:33 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 11/21/15 20:33 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 11/21/15 20:33 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 11/21/15 20:33 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 11/21/15 20:33 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 11/21/15 20:33 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 11/21/15 20:33 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 11/21/15 20:33 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 11/21/15 20:33 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 11/21/15 20:33 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 44 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Sample:3404-FIELD BLANK Lab ID:92277056009 Collected:11/19/15 13:20 Received:11/20/15 09:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Ethylbenzene ND ug/L 11/21/15 20:33 100-41-41.0 0.30 1 2-Hexanone ND ug/L 11/21/15 20:33 591-78-650.0 0.46 1 Iodomethane ND ug/L 11/21/15 20:33 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 11/21/15 20:33 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 11/21/15 20:33 108-10-11000.33 1 Styrene ND ug/L 11/21/15 20:33 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 11/21/15 20:33 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 11/21/15 20:33 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 11/21/15 20:33 127-18-41.0 0.46 1 Toluene ND ug/L 11/21/15 20:33 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 11/21/15 20:33 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 11/21/15 20:33 79-00-51.0 0.29 1 Trichloroethene ND ug/L 11/21/15 20:33 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 11/21/15 20:33 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 11/21/15 20:33 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 11/21/15 20:33 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 11/21/15 20:33 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 11/21/15 20:33 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)103 %11/21/15 20:33 460-00-470-130 1 1,2-Dichloroethane-d4 (S)102 %11/21/15 20:33 17060-07-070-130 1 Toluene-d8 (S)100 %11/21/15 20:33 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 44 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Sample:3404-TRIP BLANK Lab ID:92277056010 Collected:11/19/15 08:00 Received:11/20/15 09:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 11/21/15 20:50 67-64-110010.0 1 Acrylonitrile ND ug/L 11/21/15 20:50 107-13-12001.9 1 Benzene ND ug/L 11/21/15 20:50 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 11/21/15 20:50 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 11/21/15 20:50 75-27-41.0 0.18 1 Bromoform ND ug/L 11/21/15 20:50 75-25-23.0 0.26 1 Bromomethane ND ug/L 11/21/15 20:50 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 11/21/15 20:50 78-93-31000.96 1 Carbon disulfide ND ug/L 11/21/15 20:50 75-15-01001.2 1 Carbon tetrachloride ND ug/L 11/21/15 20:50 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 11/21/15 20:50 108-90-73.0 0.23 1 Chloroethane ND ug/L 11/21/15 20:50 75-00-310.0 0.54 1 Chloroform ND ug/L 11/21/15 20:50 67-66-35.0 0.14 1 Chloromethane ND ug/L 11/21/15 20:50 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 11/21/15 20:50 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 11/21/15 20:50 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 11/21/15 20:50 106-93-41.0 0.27 1 Dibromomethane ND ug/L 11/21/15 20:50 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 11/21/15 20:50 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 11/21/15 20:50 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 11/21/15 20:50 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 11/21/15 20:50 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 11/21/15 20:50 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 11/21/15 20:50 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 11/21/15 20:50 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 11/21/15 20:50 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 11/21/15 20:50 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 11/21/15 20:50 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 11/21/15 20:50 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 11/21/15 20:50 100-41-41.0 0.30 1 2-Hexanone ND ug/L 11/21/15 20:50 591-78-650.0 0.46 1 Iodomethane ND ug/L 11/21/15 20:50 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 11/21/15 20:50 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 11/21/15 20:50 108-10-11000.33 1 Styrene ND ug/L 11/21/15 20:50 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 11/21/15 20:50 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 11/21/15 20:50 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 11/21/15 20:50 127-18-41.0 0.46 1 Toluene ND ug/L 11/21/15 20:50 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 11/21/15 20:50 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 11/21/15 20:50 79-00-51.0 0.29 1 Trichloroethene ND ug/L 11/21/15 20:50 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 11/21/15 20:50 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 11/21/15 20:50 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 11/21/15 20:50 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 11/21/15 20:50 75-01-41.0 0.62 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 44 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Sample:3404-TRIP BLANK Lab ID:92277056010 Collected:11/19/15 08:00 Received:11/20/15 09:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Xylene (Total)ND ug/L 11/21/15 20:50 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)105 %11/21/15 20:50 460-00-470-130 1 1,2-Dichloroethane-d4 (S)103 %11/21/15 20:50 17060-07-070-130 1 Toluene-d8 (S)102 %11/21/15 20:50 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 44 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/20122 EPA 3010 EPA 6010 6010 MET NC Groundwater Associated Lab Samples:92277056001, 92277056002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1615891 Associated Lab Samples:92277056001, 92277056002 Matrix:Water AnalyzedMDL Antimony ug/L ND 6.0 12/01/15 16:213.8 Arsenic ug/L ND 10.0 12/01/15 16:212.5 Barium ug/L ND 100 12/01/15 16:212.5 Beryllium ug/L ND 1.0 12/01/15 16:210.50 Cadmium ug/L ND 1.0 12/01/15 16:210.50 Chromium ug/L ND 10.0 12/01/15 16:212.5 Cobalt ug/L ND 10.0 12/01/15 16:212.5 Copper ug/L ND 10.0 12/01/15 16:212.5 Lead ug/L ND 10.0 12/01/15 16:212.5 Nickel ug/L ND 50.0 12/01/15 16:212.5 Selenium ug/L ND 10.0 12/01/15 16:215.0 Silver ug/L ND 10.0 12/01/15 16:212.5 Thallium ug/L ND 5.5 12/01/15 17:425.0 Vanadium ug/L ND 25.0 12/01/15 16:212.5 Zinc ug/L ND 10.0 12/01/15 16:215.0 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1615892LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 485500 97 80-120 Arsenic ug/L 463500 93 80-120 Barium ug/L 479500 96 80-120 Beryllium ug/L 480500 96 80-120 Cadmium ug/L 477500 95 80-120 Chromium ug/L 474500 95 80-120 Cobalt ug/L 479500 96 80-120 Copper ug/L 484500 97 80-120 Lead ug/L 474500 95 80-120 Nickel ug/L 478500 96 80-120 Selenium ug/L 468500 94 80-120 Silver ug/L 228250 91 80-120 Thallium ug/L 465500 93 80-120 Vanadium ug/L 475500 95 80-120 Zinc ug/L 474500 95 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 44 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1615893MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92276295009 1615894 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony ug/L 500 98 75-12592 7 25500ND493461 Arsenic ug/L 500 96 75-12589 7 25500ND480447 Barium ug/L 500 97 75-12592 4 2550092.7 578 554 Beryllium ug/L 500 98 75-12592 6 25500ND489461 Cadmium ug/L 500 97 75-12591 7 25500ND487453 Chromium ug/L 500 96 75-12591 5 25500ND481457 Cobalt ug/L 500 95 75-12589 6 255002.5J 478 449 Copper ug/L 500 99 75-12593 6 25500ND498467 Lead ug/L 500 94 75-12588 7 25500ND473442 Nickel ug/L 500 95 75-12589 6 25500ND476447 Selenium ug/L 500 95 75-12589 7 25500ND478445 Silver ug/L 250 94 75-12588 7 25250ND236220 Thallium ug/L 500 97 75-12590 8 25500ND488453 Vanadium ug/L 500 98 75-12592 6 255003.7J 491 462 Zinc ug/L 500 94 75-12588 6 25500ND468442 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 44 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/20123 EPA 3010 EPA 6010 6010 MET NC Groundwater Associated Lab Samples:92277056003, 92277056004, 92277056005, 92277056006, 92277056007, 92277056008, 92277056009 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1615895 Associated Lab Samples:92277056003, 92277056004, 92277056005, 92277056006, 92277056007, 92277056008, 92277056009 Matrix:Water AnalyzedMDL Antimony ug/L ND 6.0 12/03/15 00:533.8 Arsenic ug/L ND 10.0 12/03/15 00:532.5 Barium ug/L ND 100 12/03/15 00:532.5 Beryllium ug/L ND 1.0 12/03/15 00:530.50 Cadmium ug/L ND 1.0 12/03/15 00:530.50 Chromium ug/L ND 10.0 12/03/15 00:532.5 Cobalt ug/L ND 10.0 12/03/15 00:532.5 Copper ug/L ND 10.0 12/03/15 00:532.5 Lead ug/L ND 10.0 12/03/15 00:532.5 Nickel ug/L ND 50.0 12/03/15 00:532.5 Selenium ug/L ND 10.0 12/03/15 00:535.0 Silver ug/L ND 10.0 12/03/15 00:532.5 Thallium ug/L ND 5.5 12/03/15 00:535.0 Vanadium ug/L ND 25.0 12/03/15 00:532.5 Zinc ug/L ND 10.0 12/03/15 00:535.0 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1615896LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 507500 101 80-120 Arsenic ug/L 474500 95 80-120 Barium ug/L 493500 99 80-120 Beryllium ug/L 493500 99 80-120 Cadmium ug/L 496500 99 80-120 Chromium ug/L 496500 99 80-120 Cobalt ug/L 500500 100 80-120 Copper ug/L 508500 102 80-120 Lead ug/L 494500 99 80-120 Nickel ug/L 497500 99 80-120 Selenium ug/L 496500 99 80-120 Silver ug/L 236250 95 80-120 Thallium ug/L 456500 91 80-120 Vanadium ug/L 502500 100 80-120 Zinc ug/L 491500 98 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 44 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1615897MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92277056003 1615898 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony ug/L 500 107 75-125101 7 25500ND538504 Arsenic ug/L 500 101 75-12595 6 25500ND507475 Barium ug/L 500 105 75-12599 6 2550042.2J 566 535 Beryllium ug/L 500 106 75-12599 7 25500ND531497 Cadmium ug/L 500 105 75-12599 6 25500ND524493 Chromium ug/L 500 105 75-12599 6 25500ND528498 Cobalt ug/L 500 104 75-12598 6 25500ND519489 Copper ug/L 500 109 75-125102 6 25500ND544511 Lead ug/L 500 103 75-12597 6 25500ND514484 Nickel ug/L 500 103 75-12597 6 25500ND514485 Selenium ug/L 500 104 75-12597 7 25500ND521487 Silver ug/L 250 100 75-12594 6 25250ND251236 Thallium ug/L 500 93 75-12589 4 255008.8 475 455 Vanadium ug/L 500 108 75-125102 6 25500ND543513 Zinc ug/L 500 101 75-12596 6 255007.3J 514 486 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 44 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MSV/34379 EPA 8260 EPA 8260 8260 MSV Low Level Landfill Associated Lab Samples:92277056001, 92277056002, 92277056003, 92277056004, 92277056005, 92277056006, 92277056007, 92277056008 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1612653 Associated Lab Samples:92277056001, 92277056002, 92277056003, 92277056004, 92277056005, 92277056006, 92277056007, 92277056008 Matrix:Water AnalyzedMDL 1,1,1,2-Tetrachloroethane ug/L ND 5.0 11/21/15 11:450.33 1,1,1-Trichloroethane ug/L ND 1.0 11/21/15 11:450.48 1,1,2,2-Tetrachloroethane ug/L ND 3.0 11/21/15 11:450.40 1,1,2-Trichloroethane ug/L ND 1.0 11/21/15 11:450.29 1,1-Dichloroethane ug/L ND 5.0 11/21/15 11:450.32 1,1-Dichloroethene ug/L ND 5.0 11/21/15 11:450.56 1,2,3-Trichloropropane ug/L ND 1.0 11/21/15 11:450.41 1,2-Dibromo-3-chloropropane ug/L ND 13.0 11/21/15 11:452.0 1,2-Dibromoethane (EDB)ug/L ND 1.0 11/21/15 11:450.27 1,2-Dichlorobenzene ug/L ND 5.0 11/21/15 11:450.30 1,2-Dichloroethane ug/L ND 1.0 11/21/15 11:450.24 1,2-Dichloropropane ug/L ND 1.0 11/21/15 11:450.27 1,4-Dichlorobenzene ug/L ND 1.0 11/21/15 11:450.33 2-Butanone (MEK)ug/L ND 100 11/21/15 11:450.96 2-Hexanone ug/L ND 50.0 11/21/15 11:450.46 4-Methyl-2-pentanone (MIBK)ug/L ND 100 11/21/15 11:450.33 Acetone ug/L ND 100 11/21/15 11:4510.0 Acrylonitrile ug/L ND 200 11/21/15 11:451.9 Benzene ug/L ND 1.0 11/21/15 11:450.25 Bromochloromethane ug/L ND 3.0 11/21/15 11:450.17 Bromodichloromethane ug/L ND 1.0 11/21/15 11:450.18 Bromoform ug/L ND 3.0 11/21/15 11:450.26 Bromomethane ug/L ND 10.0 11/21/15 11:450.29 Carbon disulfide ug/L ND 100 11/21/15 11:451.2 Carbon tetrachloride ug/L ND 1.0 11/21/15 11:450.25 Chlorobenzene ug/L ND 3.0 11/21/15 11:450.23 Chloroethane ug/L ND 10.0 11/21/15 11:450.54 Chloroform ug/L ND 5.0 11/21/15 11:450.14 Chloromethane ug/L ND 1.0 11/21/15 11:450.11 cis-1,2-Dichloroethene ug/L ND 5.0 11/21/15 11:450.19 cis-1,3-Dichloropropene ug/L ND 1.0 11/21/15 11:450.13 Dibromochloromethane ug/L ND 3.0 11/21/15 11:450.21 Dibromomethane ug/L ND 10.0 11/21/15 11:450.21 Ethylbenzene ug/L ND 1.0 11/21/15 11:450.30 Iodomethane ug/L ND 10.0 11/21/15 11:450.32 Methylene Chloride ug/L ND 1.0 11/21/15 11:450.97 Styrene ug/L ND 1.0 11/21/15 11:450.26 Tetrachloroethene ug/L ND 1.0 11/21/15 11:450.46 Toluene ug/L ND 1.0 11/21/15 11:450.26 trans-1,2-Dichloroethene ug/L ND 5.0 11/21/15 11:450.49 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 44 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1612653 Associated Lab Samples:92277056001, 92277056002, 92277056003, 92277056004, 92277056005, 92277056006, 92277056007, 92277056008 Matrix:Water AnalyzedMDL trans-1,3-Dichloropropene ug/L ND 1.0 11/21/15 11:450.26 trans-1,4-Dichloro-2-butene ug/L ND 100 11/21/15 11:451.0 Trichloroethene ug/L ND 1.0 11/21/15 11:450.47 Trichlorofluoromethane ug/L ND 1.0 11/21/15 11:450.20 Vinyl acetate ug/L ND 50.0 11/21/15 11:450.35 Vinyl chloride ug/L ND 1.0 11/21/15 11:450.62 Xylene (Total)ug/L ND 5.0 11/21/15 11:450.66 1,2-Dichloroethane-d4 (S)%100 70-130 11/21/15 11:45 4-Bromofluorobenzene (S)%105 70-130 11/21/15 11:45 Toluene-d8 (S)%99 70-130 11/21/15 11:45 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1612654LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 46.150 92 80-125 1,1,1-Trichloroethane ug/L 49.050 98 71-129 1,1,2,2-Tetrachloroethane ug/L 43.250 86 79-124 1,1,2-Trichloroethane ug/L 49.650 99 85-125 1,1-Dichloroethane ug/L 49.050 98 73-126 1,1-Dichloroethene ug/L 54.250 108 66-135 1,2,3-Trichloropropane ug/L 47.950 96 75-130 1,2-Dibromo-3-chloropropane ug/L 41.850 84 71-133 1,2-Dibromoethane (EDB)ug/L 45.750 91 83-124 1,2-Dichlorobenzene ug/L 46.750 93 80-133 1,2-Dichloroethane ug/L 47.250 94 67-128 1,2-Dichloropropane ug/L 46.850 94 75-132 1,4-Dichlorobenzene ug/L 46.850 94 78-130 2-Butanone (MEK)ug/L 105100 105 61-144 2-Hexanone ug/L 90.2100 90 68-143 4-Methyl-2-pentanone (MIBK)ug/L 102100 102 72-135 Acetone ug/L 107100 107 48-146 Acrylonitrile ug/L 254250 102 40-160 Benzene ug/L 50.150 100 80-125 Bromochloromethane ug/L 51.350 103 71-125 Bromodichloromethane ug/L 45.750 91 78-124 Bromoform ug/L 39.950 80 71-128 Bromomethane ug/L 49.350 99 40-160 Carbon disulfide ug/L 53.3J50 107 50-160 Carbon tetrachloride ug/L 51.550 103 69-131 Chlorobenzene ug/L 45.550 91 81-122 Chloroethane ug/L 53.650 107 39-148 Chloroform ug/L 50.850 102 73-127 Chloromethane ug/L 51.750 103 44-146 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 44 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1612654LABORATORY CONTROL SAMPLE: LCSSpike cis-1,2-Dichloroethene ug/L 51.250 102 74-124 cis-1,3-Dichloropropene ug/L 47.850 96 72-132 Dibromochloromethane ug/L 44.450 89 78-125 Dibromomethane ug/L 52.550 105 82-120 Ethylbenzene ug/L 45.150 90 79-121 Iodomethane ug/L 102100 102 39-154 Methylene Chloride ug/L 51.550 103 64-133 Styrene ug/L 46.550 93 84-126 Tetrachloroethene ug/L 48.450 97 78-122 Toluene ug/L 48.050 96 80-121 trans-1,2-Dichloroethene ug/L 54.050 108 71-127 trans-1,3-Dichloropropene ug/L 46.250 92 69-141 trans-1,4-Dichloro-2-butene ug/L 36.9J50 74 40-160 Trichloroethene ug/L 49.750 99 78-122 Trichlorofluoromethane ug/L 53.150 106 53-137 Vinyl acetate ug/L 97.7100 98 40-160 Vinyl chloride ug/L 60.150 120 58-137 Xylene (Total)ug/L 135150 90 81-126 1,2-Dichloroethane-d4 (S)%99 70-130 4-Bromofluorobenzene (S)%107 70-130 Toluene-d8 (S)%101 70-130 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1612655MATRIX SPIKE SAMPLE: MSSpike Result 92277056001 1,1,1,2-Tetrachloroethane ug/L 19.420 97 70-130ND 1,1,1-Trichloroethane ug/L 22.520 113 70-130ND 1,1,2,2-Tetrachloroethane ug/L 18.120 91 70-130ND 1,1,2-Trichloroethane ug/L 21.120 106 70-130ND 1,1-Dichloroethane ug/L 43.520 114 70-13020.7 1,1-Dichloroethene ug/L 25.120 124 70-166ND 1,2,3-Trichloropropane ug/L 19.420 97 70-130ND 1,2-Dibromo-3-chloropropane ug/L 18.720 93 70-130ND 1,2-Dibromoethane (EDB)ug/L 19.320 97 70-130ND 1,2-Dichlorobenzene ug/L 20.220 100 70-130ND 1,2-Dichloroethane ug/L 22.420 108 70-1300.86J 1,2-Dichloropropane ug/L 24.520 101 70-1304.3 1,4-Dichlorobenzene ug/L 25.520 104 70-1304.8 2-Butanone (MEK)ug/L 45.0J40 113 70-130ND 2-Hexanone ug/L 38.7J40 97 70-130ND 4-Methyl-2-pentanone (MIBK)ug/L 44.4J40 111 70-130ND Acetone ug/L 43.1J40 108 70-130ND Acrylonitrile ug/L 109J100 109 70-130ND Benzene ug/L 28.920 114 70-1486.0 Bromochloromethane ug/L 22.920 115 70-130ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 44 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1612655MATRIX SPIKE SAMPLE: MSSpike Result 92277056001 Bromodichloromethane ug/L 20.120 101 70-130ND Bromoform ug/L 16.320 82 70-130ND Bromomethane ug/L 19.520 97 70-130ND Carbon disulfide ug/L 24.0J20 120 70-130ND Carbon tetrachloride ug/L 23.420 117 70-130ND Chlorobenzene ug/L 20.220 99 70-1460.31J Chloroethane ug/L 23.820 119 70-130ND Chloroform ug/L 23.020 115 70-130ND Chloromethane ug/L 22.520 113 70-130ND cis-1,2-Dichloroethene ug/L 68.120 119 70-13044.4 cis-1,3-Dichloropropene ug/L 20.320 101 70-130ND Dibromochloromethane ug/L 18.820 94 70-130ND Dibromomethane ug/L 22.420 112 70-130ND Ethylbenzene ug/L 19.920 100 70-130ND Iodomethane ug/L 38.140 95 70-130ND Methylene Chloride ug/L 24.320 122 70-130ND Styrene ug/L 19.820 99 70-130ND Tetrachloroethene ug/L 21.920 105 70-1300.90J Toluene ug/L 21.820 109 70-155ND trans-1,2-Dichloroethene ug/L 26.020 123 70-1301.5J trans-1,3-Dichloropropene ug/L 20.020 100 70-130ND trans-1,4-Dichloro-2-butene ug/L 13.1J M1206570-130ND Trichloroethene ug/L 27.120 112 69-1514.7 Trichlorofluoromethane ug/L 25.320 124 70-1300.41J Vinyl acetate ug/L 37.4J40 93 70-130ND Vinyl chloride ug/L 35.0 M12013770-1307.7 1,2-Dichloroethane-d4 (S)%100 70-130 4-Bromofluorobenzene (S)%105 70-130 Toluene-d8 (S)%99 70-130 Parameter Units Dup Result Max RPD QualifiersRPDResult 92277056002 1612656SAMPLE DUPLICATE: 1,1,1,2-Tetrachloroethane ug/L ND 30ND 1,1,1-Trichloroethane ug/L ND 30ND 1,1,2,2-Tetrachloroethane ug/L ND 30ND 1,1,2-Trichloroethane ug/L ND 30ND 1,1-Dichloroethane ug/L 0.85J 300.82J 1,1-Dichloroethene ug/L ND 30ND 1,2,3-Trichloropropane ug/L ND 30ND 1,2-Dibromo-3-chloropropane ug/L ND 30ND 1,2-Dibromoethane (EDB)ug/L ND 30ND 1,2-Dichlorobenzene ug/L ND 30ND 1,2-Dichloroethane ug/L ND 300.40J 1,2-Dichloropropane ug/L ND 30ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 44 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result Max RPD QualifiersRPDResult 92277056002 1612656SAMPLE DUPLICATE: 1,4-Dichlorobenzene ug/L 1.2 11 301.4 2-Butanone (MEK)ug/L ND 30ND 2-Hexanone ug/L ND 30ND 4-Methyl-2-pentanone (MIBK)ug/L ND 30ND Acetone ug/L ND 30ND Acrylonitrile ug/L ND 30ND Benzene ug/L ND 30ND Bromochloromethane ug/L ND 30ND Bromodichloromethane ug/L ND 30ND Bromoform ug/L ND 30ND Bromomethane ug/L ND 30ND Carbon disulfide ug/L ND 30ND Carbon tetrachloride ug/L ND 30ND Chlorobenzene ug/L 0.81J 300.81J Chloroethane ug/L ND 30ND Chloroform ug/L ND 30ND Chloromethane ug/L ND 30ND cis-1,2-Dichloroethene ug/L 5.3 4 305.6 cis-1,3-Dichloropropene ug/L ND 30ND Dibromochloromethane ug/L ND 30ND Dibromomethane ug/L ND 30ND Ethylbenzene ug/L ND 30ND Iodomethane ug/L ND 30ND Methylene Chloride ug/L ND 30ND Styrene ug/L ND 30ND Tetrachloroethene ug/L ND 30ND Toluene ug/L ND 30ND trans-1,2-Dichloroethene ug/L ND 30ND trans-1,3-Dichloropropene ug/L ND 30ND trans-1,4-Dichloro-2-butene ug/L ND 30ND Trichloroethene ug/L ND 30ND Trichlorofluoromethane ug/L ND 30ND Vinyl acetate ug/L ND 30ND Vinyl chloride ug/L 1.9 2 302.0 Xylene (Total)ug/L ND 30ND 1,2-Dichloroethane-d4 (S)%101 1102 4-Bromofluorobenzene (S)%105 0105 Toluene-d8 (S)%100 1101 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 44 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MSV/34380 EPA 8260 EPA 8260 8260 MSV Low Level Landfill Associated Lab Samples:92277056009, 92277056010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1612657 Associated Lab Samples:92277056009, 92277056010 Matrix:Water AnalyzedMDL 1,1,1,2-Tetrachloroethane ug/L ND 5.0 11/21/15 12:020.33 1,1,1-Trichloroethane ug/L ND 1.0 11/21/15 12:020.48 1,1,2,2-Tetrachloroethane ug/L ND 3.0 11/21/15 12:020.40 1,1,2-Trichloroethane ug/L ND 1.0 11/21/15 12:020.29 1,1-Dichloroethane ug/L ND 5.0 11/21/15 12:020.32 1,1-Dichloroethene ug/L ND 5.0 11/21/15 12:020.56 1,2,3-Trichloropropane ug/L ND 1.0 11/21/15 12:020.41 1,2-Dibromo-3-chloropropane ug/L ND 13.0 11/21/15 12:022.0 1,2-Dibromoethane (EDB)ug/L ND 1.0 11/21/15 12:020.27 1,2-Dichlorobenzene ug/L ND 5.0 11/21/15 12:020.30 1,2-Dichloroethane ug/L ND 1.0 11/21/15 12:020.24 1,2-Dichloropropane ug/L ND 1.0 11/21/15 12:020.27 1,4-Dichlorobenzene ug/L ND 1.0 11/21/15 12:020.33 2-Butanone (MEK)ug/L ND 100 11/21/15 12:020.96 2-Hexanone ug/L ND 50.0 11/21/15 12:020.46 4-Methyl-2-pentanone (MIBK)ug/L ND 100 11/21/15 12:020.33 Acetone ug/L ND 100 11/21/15 12:0210.0 Acrylonitrile ug/L ND 200 11/21/15 12:021.9 Benzene ug/L ND 1.0 11/21/15 12:020.25 Bromochloromethane ug/L ND 3.0 11/21/15 12:020.17 Bromodichloromethane ug/L ND 1.0 11/21/15 12:020.18 Bromoform ug/L ND 3.0 11/21/15 12:020.26 Bromomethane ug/L ND 10.0 11/21/15 12:020.29 Carbon disulfide ug/L ND 100 11/21/15 12:021.2 Carbon tetrachloride ug/L ND 1.0 11/21/15 12:020.25 Chlorobenzene ug/L ND 3.0 11/21/15 12:020.23 Chloroethane ug/L ND 10.0 11/21/15 12:020.54 Chloroform ug/L ND 5.0 11/21/15 12:020.14 Chloromethane ug/L ND 1.0 11/21/15 12:020.11 cis-1,2-Dichloroethene ug/L ND 5.0 11/21/15 12:020.19 cis-1,3-Dichloropropene ug/L ND 1.0 11/21/15 12:020.13 Dibromochloromethane ug/L ND 3.0 11/21/15 12:020.21 Dibromomethane ug/L ND 10.0 11/21/15 12:020.21 Ethylbenzene ug/L ND 1.0 11/21/15 12:020.30 Iodomethane ug/L ND 10.0 11/21/15 12:020.32 Methylene Chloride ug/L ND 1.0 11/21/15 12:020.97 Styrene ug/L ND 1.0 11/21/15 12:020.26 Tetrachloroethene ug/L ND 1.0 11/21/15 12:020.46 Toluene ug/L ND 1.0 11/21/15 12:020.26 trans-1,2-Dichloroethene ug/L ND 5.0 11/21/15 12:020.49 trans-1,3-Dichloropropene ug/L ND 1.0 11/21/15 12:020.26 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 36 of 44 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1612657 Associated Lab Samples:92277056009, 92277056010 Matrix:Water AnalyzedMDL trans-1,4-Dichloro-2-butene ug/L ND 100 11/21/15 12:021.0 Trichloroethene ug/L ND 1.0 11/21/15 12:020.47 Trichlorofluoromethane ug/L ND 1.0 11/21/15 12:020.20 Vinyl acetate ug/L ND 50.0 11/21/15 12:020.35 Vinyl chloride ug/L ND 1.0 11/21/15 12:020.62 Xylene (Total)ug/L ND 5.0 11/21/15 12:020.66 1,2-Dichloroethane-d4 (S)%100 70-130 11/21/15 12:02 4-Bromofluorobenzene (S)%105 70-130 11/21/15 12:02 Toluene-d8 (S)%101 70-130 11/21/15 12:02 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1612658LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 46.250 92 80-125 1,1,1-Trichloroethane ug/L 48.850 98 71-129 1,1,2,2-Tetrachloroethane ug/L 44.050 88 79-124 1,1,2-Trichloroethane ug/L 49.450 99 85-125 1,1-Dichloroethane ug/L 49.250 98 73-126 1,1-Dichloroethene ug/L 53.250 106 66-135 1,2,3-Trichloropropane ug/L 48.150 96 75-130 1,2-Dibromo-3-chloropropane ug/L 44.750 89 71-133 1,2-Dibromoethane (EDB)ug/L 47.750 95 83-124 1,2-Dichlorobenzene ug/L 47.450 95 80-133 1,2-Dichloroethane ug/L 48.350 97 67-128 1,2-Dichloropropane ug/L 46.150 92 75-132 1,4-Dichlorobenzene ug/L 48.050 96 78-130 2-Butanone (MEK)ug/L 105100 105 61-144 2-Hexanone ug/L 92.9100 93 68-143 4-Methyl-2-pentanone (MIBK)ug/L 104100 104 72-135 Acetone ug/L 110100 110 48-146 Acrylonitrile ug/L 259250 104 40-160 Benzene ug/L 49.750 99 80-125 Bromochloromethane ug/L 52.450 105 71-125 Bromodichloromethane ug/L 45.750 91 78-124 Bromoform ug/L 40.850 82 71-128 Bromomethane ug/L 49.550 99 40-160 Carbon disulfide ug/L 53.4J50 107 50-160 Carbon tetrachloride ug/L 51.350 103 69-131 Chlorobenzene ug/L 45.650 91 81-122 Chloroethane ug/L 52.650 105 39-148 Chloroform ug/L 50.750 101 73-127 Chloromethane ug/L 52.350 105 44-146 cis-1,2-Dichloroethene ug/L 51.050 102 74-124 cis-1,3-Dichloropropene ug/L 48.250 96 72-132 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 37 of 44 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1612658LABORATORY CONTROL SAMPLE: LCSSpike Dibromochloromethane ug/L 44.750 89 78-125 Dibromomethane ug/L 52.250 104 82-120 Ethylbenzene ug/L 45.250 90 79-121 Iodomethane ug/L 99.4100 99 39-154 Methylene Chloride ug/L 52.450 105 64-133 Styrene ug/L 45.850 92 84-126 Tetrachloroethene ug/L 47.150 94 78-122 Toluene ug/L 47.450 95 80-121 trans-1,2-Dichloroethene ug/L 54.250 108 71-127 trans-1,3-Dichloropropene ug/L 46.850 94 69-141 trans-1,4-Dichloro-2-butene ug/L 39.3J50 79 40-160 Trichloroethene ug/L 47.950 96 78-122 Trichlorofluoromethane ug/L 53.050 106 53-137 Vinyl acetate ug/L 99.3100 99 40-160 Vinyl chloride ug/L 59.050 118 58-137 Xylene (Total)ug/L 133150 88 81-126 1,2-Dichloroethane-d4 (S)%98 70-130 4-Bromofluorobenzene (S)%106 70-130 Toluene-d8 (S)%99 70-130 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1612659MATRIX SPIKE SAMPLE: MSSpike Result 92277140001 1,1,1,2-Tetrachloroethane ug/L 20.520 103 70-130ND 1,1,1-Trichloroethane ug/L 23.620 118 70-130ND 1,1,2,2-Tetrachloroethane ug/L 18.720 94 70-130ND 1,1,2-Trichloroethane ug/L 22.520 113 70-130ND 1,1-Dichloroethane ug/L 23.820 119 70-130ND 1,1-Dichloroethene ug/L 26.120 131 70-166ND 1,2,3-Trichloropropane ug/L 20.020 100 70-130ND 1,2-Dibromo-3-chloropropane ug/L 19.420 97 70-130ND 1,2-Dibromoethane (EDB)ug/L 19.820 99 70-130ND 1,2-Dichlorobenzene ug/L 20.820 104 70-130ND 1,2-Dichloroethane ug/L 22.820 114 70-130ND 1,2-Dichloropropane ug/L 21.920 110 70-130ND 1,4-Dichlorobenzene ug/L 20.820 104 70-130ND 2-Butanone (MEK)ug/L 45.8J40 114 70-130ND 2-Hexanone ug/L 40.9J40 102 70-130ND 4-Methyl-2-pentanone (MIBK)ug/L 47.9J40 120 70-130ND Acetone ug/L 51.6J40 115 70-130ND Acrylonitrile ug/L 119J100 119 70-130ND Benzene ug/L 23.520 117 70-148ND Bromochloromethane ug/L 24.920 125 70-130ND Bromodichloromethane ug/L 21.220 106 70-130ND Bromoform ug/L 17.420 87 70-130ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 38 of 44 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1612659MATRIX SPIKE SAMPLE: MSSpike Result 92277140001 Bromomethane ug/L 20.820 104 70-130ND Carbon disulfide ug/L 25.1J20 125 70-130ND Carbon tetrachloride ug/L 24.120 121 70-130ND Chlorobenzene ug/L 20.820 104 70-146ND Chloroethane ug/L 25.920 130 70-130ND Chloroform ug/L 25.020 120 70-130ND Chloromethane ug/L 25.220 126 70-130ND cis-1,2-Dichloroethene ug/L 24.920 125 70-130ND cis-1,3-Dichloropropene ug/L 21.820 109 70-130ND Dibromochloromethane ug/L 19.020 95 70-130ND Dibromomethane ug/L 23.820 119 70-130ND Ethylbenzene ug/L 20.420 102 70-130ND Iodomethane ug/L 46.140 115 70-130ND Methylene Chloride ug/L 24.820 124 70-130ND Styrene ug/L 19.620 98 70-130ND Tetrachloroethene ug/L 22.120 111 70-130ND Toluene ug/L 22.720 112 70-155ND trans-1,2-Dichloroethene ug/L 25.620 128 70-130ND trans-1,3-Dichloropropene ug/L 21.120 105 70-130ND trans-1,4-Dichloro-2-butene ug/L 15.0J20 75 70-130ND Trichloroethene ug/L 23.120 115 69-151ND Trichlorofluoromethane ug/L 26.120 130 70-130ND Vinyl acetate ug/L 39.2J40 98 70-130ND Vinyl chloride ug/L 28.9 M12014470-130ND 1,2-Dichloroethane-d4 (S)%101 70-130 4-Bromofluorobenzene (S)%104 70-130 Toluene-d8 (S)%101 70-130 Parameter Units Dup Result Max RPD QualifiersRPDResult 92277140002 1612660SAMPLE DUPLICATE: 1,1,1,2-Tetrachloroethane ug/L ND 30ND 1,1,1-Trichloroethane ug/L ND 30ND 1,1,2,2-Tetrachloroethane ug/L ND 30ND 1,1,2-Trichloroethane ug/L ND 30ND 1,1-Dichloroethane ug/L ND 30ND 1,1-Dichloroethene ug/L ND 30ND 1,2,3-Trichloropropane ug/L ND 30ND 1,2-Dibromo-3-chloropropane ug/L ND 30ND 1,2-Dibromoethane (EDB)ug/L ND 30ND 1,2-Dichlorobenzene ug/L ND 30ND 1,2-Dichloroethane ug/L ND 30ND 1,2-Dichloropropane ug/L ND 30ND 1,4-Dichlorobenzene ug/L ND 30ND 2-Butanone (MEK)ug/L ND 30ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 39 of 44 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result Max RPD QualifiersRPDResult 92277140002 1612660SAMPLE DUPLICATE: 2-Hexanone ug/L ND 30ND 4-Methyl-2-pentanone (MIBK)ug/L ND 30ND Acetone ug/L ND 30ND Acrylonitrile ug/L ND 30ND Benzene ug/L ND 30ND Bromochloromethane ug/L ND 30ND Bromodichloromethane ug/L ND 30ND Bromoform ug/L ND 30ND Bromomethane ug/L ND 30ND Carbon disulfide ug/L ND 30ND Carbon tetrachloride ug/L ND 30ND Chlorobenzene ug/L ND 30ND Chloroethane ug/L ND 30ND Chloroform ug/L 0.18J 30ND Chloromethane ug/L ND 30ND cis-1,2-Dichloroethene ug/L ND 30ND cis-1,3-Dichloropropene ug/L ND 30ND Dibromochloromethane ug/L ND 30ND Dibromomethane ug/L ND 30ND Ethylbenzene ug/L ND 30ND Iodomethane ug/L ND 30ND Methylene Chloride ug/L ND 30ND Styrene ug/L ND 30ND Tetrachloroethene ug/L ND 30ND Toluene ug/L ND 30ND trans-1,2-Dichloroethene ug/L ND 30ND trans-1,3-Dichloropropene ug/L ND 30ND trans-1,4-Dichloro-2-butene ug/L ND 30ND Trichloroethene ug/L ND 30ND Trichlorofluoromethane ug/L ND 30ND Vinyl acetate ug/L ND 30ND Vinyl chloride ug/L ND 30ND Xylene (Total)ug/L ND 30ND 1,2-Dichloroethane-d4 (S)%103 2101 4-Bromofluorobenzene (S)%103 2106 Toluene-d8 (S)%101 1102 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 40 of 44 #=QL# QUALIFIERS Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - CharlottePASI-C ANALYTE QUALIFIERS Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 41 of 44 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92277056 TOWN OF KERNERSVILLE Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92277056001 MPRP/20122 ICP/181513404-MW2 EPA 3010 EPA 6010 92277056002 MPRP/20122 ICP/181513404-MW3S EPA 3010 EPA 6010 92277056003 MPRP/20123 ICP/181523404-MW3D EPA 3010 EPA 6010 92277056004 MPRP/20123 ICP/181523404-MW4 EPA 3010 EPA 6010 92277056005 MPRP/20123 ICP/181523404-MW5 EPA 3010 EPA 6010 92277056006 MPRP/20123 ICP/181523404-SW1 EPA 3010 EPA 6010 92277056007 MPRP/20123 ICP/181523404-SW2 EPA 3010 EPA 6010 92277056008 MPRP/20123 ICP/181523404-SW3 EPA 3010 EPA 6010 92277056009 MPRP/20123 ICP/181523404-FIELD BLANK EPA 3010 EPA 6010 92277056001 MSV/343793404-MW2 EPA 8260 92277056002 MSV/343793404-MW3S EPA 8260 92277056003 MSV/343793404-MW3D EPA 8260 92277056004 MSV/343793404-MW4 EPA 8260 92277056005 MSV/343793404-MW5 EPA 8260 92277056006 MSV/343793404-SW1 EPA 8260 92277056007 MSV/343793404-SW2 EPA 8260 92277056008 MSV/343793404-SW3 EPA 8260 92277056009 MSV/343803404-FIELD BLANK EPA 8260 92277056010 MSV/343803404-TRIP BLANK EPA 8260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2015 04:06 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 42 of 44 Page 43 of 44 Page 44 of 44 #=CL# December 22, 2015 LIMS USE: FR - ALEX EVERHART LIMS OBJECT ID: 92277063 92277063 Project: Pace Project No.: RE: Mr. Alex Everhart Joyce Engineering-NC 2211 W. Meadowview Road Suite 101 Greensboro, NC 27407 TOWN OF KERNERSVILLE MNA Dear Mr. Everhart: Enclosed are the analytical results for sample(s) received by the laboratory on November 20, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. Some analyses have been subcontracted outside of the Pace Network. The subcontracted laboratory report has been attached. Report revised 12/22/15 to update Nitrate units from mg/L to ug/L. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Godwin kevin.godwin@pacelabs.com Project Manager REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 31 #=CL# December 22, 2015 Page 2 LIMS USE: FR - ALEX EVERHART LIMS OBJECT ID: 92277063 Enclosures cc:Mr. Van Burbach, Joyce Engineering-NC Alex Everhart, Joyce Engineering-NC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 31 #=CP# CERTIFICATIONS Pace Project No.: Project: 92277063 TOWN OF KERNERSVILLE MNA Minnesota Certification IDs1700 Elm Street SE Suite 200, Minneapolis, MN 55414A2LA Certification #: 2926.01 Alaska Certification #: UST-078Alaska Certification #MN00064Alabama Certification #40770Arizona Certification #: AZ-0014Arkansas Certification #: 88-0680 California Certification #: 01155CAColorado Certification #PaceConnecticut Certification #: PH-0256EPA Region 8 Certification #: 8TMS-LFlorida/NELAP Certification #: E87605 Guam Certification #:14-008rGeorgia Certification #: 959Georgia EPD #: PaceIdaho Certification #: MN00064Hawaii Certification #MN00064 Illinois Certification #: 200011Indiana Certification#C-MN-01Iowa Certification #: 368Kansas Certification #: E-10167Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062Louisiana DEQ Certification #: 3086Louisiana DHH #: LA140001Maine Certification #: 2013011Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Minnesota Certification #: 027-053-137Mississippi Certification #: Pace Montana Certification #: MT0092Nevada Certification #: MN_00064Nebraska Certification #: PaceNew Jersey Certification #: MN-002New York Certification #: 11647 North Carolina Certification #: 530North Carolina State Public Health #: 27700North Dakota Certification #: R-036Ohio EPA #: 4150Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507Oregon Certification #: MN200001Oregon Certification #: MN300001Pennsylvania Certification #: 68-00563Puerto Rico Certification Saipan (CNMI) #:MP0003South Carolina #:74003001Texas Certification #: T104704192Tennessee Certification #: 02818Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251Washington Certification #: C486West Virginia Certification #: 382West Virginia DHHR #:9952CWisconsin Certification #: 999407970 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 31 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92277063 TOWN OF KERNERSVILLE MNA Lab ID Sample ID Matrix Date Collected Date Received 92277063001 3404-MW2 Water 11/19/15 12:41 11/20/15 09:30 92277063002 3404-MW3S Water 11/19/15 10:02 11/20/15 09:30 92277063003 3404-MW3D Water 11/19/15 10:45 11/20/15 09:30 92277063004 3404-MW4 Water 11/19/15 11:34 11/20/15 09:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 31 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92277063 TOWN OF KERNERSVILLE MNA Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92277063001 3404-MW2 RSK 175 3 PASI-MJRB SM 2320B 1 PASI-AMLS SM 4500-S2D 1 PASI-AMJP SM 5210B 1 PASI-ABRJ EPA 300.0 1 PASI-AMDW EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-AWRC SM 5220D 1 PASI-AWRC SM 5310B 1 PASI-AMDW 92277063002 3404-MW3S RSK 175 3 PASI-MJRB SM 2320B 1 PASI-AMLS SM 4500-S2D 1 PASI-AMJP SM 5210B 1 PASI-ABRJ EPA 300.0 1 PASI-AMDW EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-AWRC SM 5220D 1 PASI-AWRC SM 5310B 1 PASI-AMDW 92277063003 3404-MW3D RSK 175 3 PASI-MJRB SM 2320B 1 PASI-AMLS SM 4500-S2D 1 PASI-AMJP SM 5210B 1 PASI-ABRJ EPA 300.0 1 PASI-AMDW EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-AWRC SM 5220D 1 PASI-AWRC SM 5310B 1 PASI-AMDW 92277063004 3404-MW4 RSK 175 3 PASI-MJRB SM 2320B 1 PASI-AMLS SM 4500-S2D 1 PASI-AMJP SM 5210B 1 PASI-ABRJ EPA 300.0 1 PASI-AMDW EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-AWRC SM 5220D 1 PASI-AWRC SM 5310B 1 PASI-AMDW REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 31 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92277063 TOWN OF KERNERSVILLE MNA Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92277063001 3404-MW2 Methane 6010 ug/L 11/24/15 19:1810.0RSK 175 Alkalinity, Total as CaCO3 158000 ug/L 12/01/15 19:135000SM 2320B BOD, 5 day 5000 ug/L 11/25/15 22:052000SM 5210B Sulfate 1190J ug/L 11/30/15 11:59250000EPA 300.0 Nitrogen, Nitrate 69.4J ug/L 11/21/15 09:42 B10000EPA 353.2 Chloride 16300 ug/L 12/01/15 23:141000SM 4500-Cl-E Total Organic Carbon 889J ug/L 11/30/15 20:301000SM 5310B 92277063002 3404-MW3S Methane 220 ug/L 11/24/15 19:3410.0RSK 175 Alkalinity, Total as CaCO3 147000 ug/L 12/01/15 19:455000SM 2320B Sulfate 1360J ug/L 11/30/15 12:40250000EPA 300.0 Nitrogen, Nitrate 15.8J ug/L 11/21/15 09:17 B10000EPA 353.2 Chloride 27800 ug/L 12/01/15 23:151000SM 4500-Cl-E Total Organic Carbon 1210 ug/L 11/30/15 20:401000SM 5310B 92277063003 3404-MW3D Methane 160 ug/L 11/24/15 19:4210.0RSK 175 Alkalinity, Total as CaCO3 158000 ug/L 12/01/15 19:585000SM 2320B Sulfate 1520J ug/L 11/30/15 12:54250000EPA 300.0 Nitrogen, Nitrate 13.1J ug/L 11/21/15 09:18 B10000EPA 353.2 Chloride 17400 ug/L 12/01/15 23:151000SM 4500-Cl-E 92277063004 3404-MW4 Methane 2.6J ug/L 11/24/15 19:5010.0RSK 175 Alkalinity, Total as CaCO3 185000 ug/L 12/01/15 20:115000SM 2320B Sulfate 1240J ug/L 11/30/15 13:07250000EPA 300.0 Nitrogen, Nitrate 19.1J ug/L 11/21/15 09:37 B10000EPA 353.2 Chloride 16900 ug/L 12/01/15 23:161000SM 4500-Cl-E Chemical Oxygen Demand 16000J ug/L 11/24/15 15:4025000SM 5220D Total Organic Carbon 1900 ug/L 11/30/15 21:051000SM 5310B REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92277063 TOWN OF KERNERSVILLE MNA Sample:3404-MW2 Lab ID:92277063001 Collected:11/19/15 12:41 Received:11/20/15 09:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: RSK 175RSK 175 AIR Headspace Ethane ND ug/L 11/24/15 19:18 74-84-010.0 5.0 1 Ethene ND ug/L 11/24/15 19:18 74-85-110.0 0.47 1 Methane 6010 ug/L 11/24/15 19:18 74-82-810.0 0.63 1 Analytical Method: SM 2320B2320B Alkalinity Alkalinity, Total as CaCO3 158000 ug/L 12/01/15 19:13500010001 Analytical Method: SM 4500-S2D4500S2D Sulfide Water Sulfide ND ug/L 11/23/15 23:30 18496-25-810001001 Analytical Method: SM 5210B5210B BOD, 5 day BOD, 5 day 5000 ug/L 11/25/15 22:0511/21/15 03:50200020001 Analytical Method: EPA 300.0300.0 IC Anions 28 Days Sulfate 1190J ug/L 11/30/15 11:59 14808-79-825000010001 Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate 69.4J ug/L 11/21/15 09:42 B1000010.0 1 Analytical Method: SM 4500-Cl-E4500 Chloride Chloride 16300 ug/L 12/01/15 23:14 16887-00-610005001 Analytical Method: SM 5220D5220D COD Chemical Oxygen Demand ND ug/L 11/24/15 15:4025000125001 Analytical Method: SM 5310B5310B TOC Total Organic Carbon 889J ug/L 11/30/15 20:30 7440-44-010005001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 07:43 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92277063 TOWN OF KERNERSVILLE MNA Sample:3404-MW3S Lab ID:92277063002 Collected:11/19/15 10:02 Received:11/20/15 09:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: RSK 175RSK 175 AIR Headspace Ethane ND ug/L 11/24/15 19:34 74-84-010.0 5.0 1 Ethene ND ug/L 11/24/15 19:34 74-85-110.0 0.47 1 Methane 220 ug/L 11/24/15 19:34 74-82-810.0 0.63 1 Analytical Method: SM 2320B2320B Alkalinity Alkalinity, Total as CaCO3 147000 ug/L 12/01/15 19:45500010001 Analytical Method: SM 4500-S2D4500S2D Sulfide Water Sulfide ND ug/L 11/23/15 23:30 18496-25-810001001 Analytical Method: SM 5210B5210B BOD, 5 day BOD, 5 day ND ug/L 11/25/15 22:0511/21/15 03:50200020001 Analytical Method: EPA 300.0300.0 IC Anions 28 Days Sulfate 1360J ug/L 11/30/15 12:40 14808-79-825000010001 Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate 15.8J ug/L 11/21/15 09:17 B1000010.0 1 Analytical Method: SM 4500-Cl-E4500 Chloride Chloride 27800 ug/L 12/01/15 23:15 16887-00-610005001 Analytical Method: SM 5220D5220D COD Chemical Oxygen Demand ND ug/L 11/24/15 15:4025000125001 Analytical Method: SM 5310B5310B TOC Total Organic Carbon 1210 ug/L 11/30/15 20:40 7440-44-010005001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 07:43 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92277063 TOWN OF KERNERSVILLE MNA Sample:3404-MW3D Lab ID:92277063003 Collected:11/19/15 10:45 Received:11/20/15 09:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: RSK 175RSK 175 AIR Headspace Ethane ND ug/L 11/24/15 19:42 74-84-010.0 5.0 1 Ethene ND ug/L 11/24/15 19:42 74-85-110.0 0.47 1 Methane 160 ug/L 11/24/15 19:42 74-82-810.0 0.63 1 Analytical Method: SM 2320B2320B Alkalinity Alkalinity, Total as CaCO3 158000 ug/L 12/01/15 19:58500010001 Analytical Method: SM 4500-S2D4500S2D Sulfide Water Sulfide ND ug/L 11/23/15 23:30 18496-25-810001001 Analytical Method: SM 5210B5210B BOD, 5 day BOD, 5 day ND ug/L 11/25/15 22:0511/21/15 03:50200020001 Analytical Method: EPA 300.0300.0 IC Anions 28 Days Sulfate 1520J ug/L 11/30/15 12:54 14808-79-825000010001 Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate 13.1J ug/L 11/21/15 09:18 B1000010.0 1 Analytical Method: SM 4500-Cl-E4500 Chloride Chloride 17400 ug/L 12/01/15 23:15 16887-00-610005001 Analytical Method: SM 5220D5220D COD Chemical Oxygen Demand ND ug/L 11/24/15 15:4025000125001 Analytical Method: SM 5310B5310B TOC Total Organic Carbon ND ug/L 11/30/15 20:51 7440-44-010005001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 07:43 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92277063 TOWN OF KERNERSVILLE MNA Sample:3404-MW4 Lab ID:92277063004 Collected:11/19/15 11:34 Received:11/20/15 09:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: RSK 175RSK 175 AIR Headspace Ethane ND ug/L 11/24/15 19:50 74-84-010.0 5.0 1 Ethene ND ug/L 11/24/15 19:50 74-85-110.0 0.47 1 Methane 2.6J ug/L 11/24/15 19:50 74-82-810.0 0.63 1 Analytical Method: SM 2320B2320B Alkalinity Alkalinity, Total as CaCO3 185000 ug/L 12/01/15 20:11500010001 Analytical Method: SM 4500-S2D4500S2D Sulfide Water Sulfide ND ug/L 11/23/15 23:30 18496-25-810001001 Analytical Method: SM 5210B5210B BOD, 5 day BOD, 5 day ND ug/L 11/25/15 22:05 B211/21/15 03:50200020001 Analytical Method: EPA 300.0300.0 IC Anions 28 Days Sulfate 1240J ug/L 11/30/15 13:07 14808-79-825000010001 Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate 19.1J ug/L 11/21/15 09:37 B1000010.0 1 Analytical Method: SM 4500-Cl-E4500 Chloride Chloride 16900 ug/L 12/01/15 23:16 16887-00-610005001 Analytical Method: SM 5220D5220D COD Chemical Oxygen Demand 16000J ug/L 11/24/15 15:4025000125001 Analytical Method: SM 5310B5310B TOC Total Organic Carbon 1900 ug/L 11/30/15 21:05 7440-44-010005001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 07:43 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92277063 TOWN OF KERNERSVILLE MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: AIR/24713 RSK 175 RSK 175 RSK 175 AIR HEADSPACE Associated Lab Samples:92277063001, 92277063002, 92277063003, 92277063004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2143732 Associated Lab Samples:92277063001, 92277063002, 92277063003, 92277063004 Matrix:Water AnalyzedMDL Ethane ug/L ND 10.0 11/24/15 19:095.0 Ethene ug/L ND 10.0 11/24/15 19:090.47 Methane ug/L 1.4J 10.0 11/24/15 19:090.63 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2143733LABORATORY CONTROL SAMPLE & LCSD: LCSSpike LCSD % Rec RPD Max RPD LCSD Result 2143734 Ethane ug/L 116114 102 85-115102116 0 20 Ethene ug/L 107106 101 85-115102108 1 20 Methane ug/L 60.760.7 100 85-11510060.4 1 20 Parameter Units Dup Result Max RPD QualifiersRPDResult 92277063001 2143735SAMPLE DUPLICATE: Ethane ug/L ND 20ND Ethene ug/L ND 20ND Methane ug/L 5550 8 206010 Parameter Units Dup Result Max RPD QualifiersRPDResult 92277119007 2143736SAMPLE DUPLICATE: Ethane ug/L ND 20ND Ethene ug/L ND 20ND Methane ug/L 17500 7 2016300 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 07:43 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92277063 TOWN OF KERNERSVILLE MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/41659 SM 2320B SM 2320B 2320B Alkalinity Associated Lab Samples:92277063001, 92277063002, 92277063003, 92277063004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1616790 Associated Lab Samples:92277063001, 92277063002, 92277063003, 92277063004 Matrix:Water AnalyzedMDL Alkalinity, Total as CaCO3 ug/L ND 5000 12/01/15 14:381000 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1616791LABORATORY CONTROL SAMPLE: LCSSpike Alkalinity, Total as CaCO3 ug/L 4990050000 100 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1616792MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92277119005 1616793 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Alkalinity, Total as CaCO3 ug/L 50000 100 80-120100 0 2550000ND5070050600 Parameter Units MS Result % Rec Limits Qual% RecConc. 1616798MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92277515002 1616799 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Alkalinity, Total as CaCO3 ug/L 50000 98 80-120103 2 255000070.3 mg/L 119000 122000 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 07:43 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92277063 TOWN OF KERNERSVILLE MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/41571 SM 4500-S2D SM 4500-S2D 4500S2D Sulfide Water Associated Lab Samples:92277063001, 92277063002, 92277063003, 92277063004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1613121 Associated Lab Samples:92277063001, 92277063002, 92277063003, 92277063004 Matrix:Water AnalyzedMDL Sulfide ug/L ND 1000 11/23/15 23:30100 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1613122LABORATORY CONTROL SAMPLE: LCSSpike Sulfide ug/L 511J500 102 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1613123MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92276764001 1613124 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfide ug/L 500 96 90-11096 0 10500ND479J479J Parameter Units MS Result % Rec Limits Qual% RecConc. 1613125MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92276295016 1613126 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfide ug/L 500 92 90-11092 0 10500ND460J460J REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 07:43 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92277063 TOWN OF KERNERSVILLE MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/41545 SM 5210B SM 5210B 5210B BOD, 5 day Associated Lab Samples:92277063001, 92277063002, 92277063003, 92277063004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1612650 Associated Lab Samples:92277063001, 92277063002, 92277063003, 92277063004 Matrix:Water AnalyzedMDL BOD, 5 day ug/L ND 2000 11/25/15 22:052000 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1612651LABORATORY CONTROL SAMPLE: LCSSpike BOD, 5 day ug/L 182000198000 92 84.6-115.4 Parameter Units Dup Result Max RPD QualifiersRPDResult 92276796001 1612652SAMPLE DUPLICATE: BOD, 5 day ug/L 3100 10 102.8 mg/L REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 07:43 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92277063 TOWN OF KERNERSVILLE MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/25567 EPA 300.0 EPA 300.0 300.0 IC Anions Associated Lab Samples:92277063001, 92277063002, 92277063003, 92277063004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1616290 Associated Lab Samples:92277063001, 92277063002, 92277063003, 92277063004 Matrix:Water AnalyzedMDL Sulfate ug/L ND 250000 11/30/15 11:321000 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1616291LABORATORY CONTROL SAMPLE: LCSSpike Sulfate ug/L 19500J20000 97 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1616292MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92277063001 1616293 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate ug/L 20000 100 90-110100 0 10200001190J21200J21200J Parameter Units MS Result % Rec Limits Qual% RecConc. 1616294MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92277063002 1616295 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate ug/L 20000 94 90-11093 1 10200001360J20200J20000J REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 07:43 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92277063 TOWN OF KERNERSVILLE MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/25491 EPA 353.2 EPA 353.2 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples:92277063001, 92277063002, 92277063003, 92277063004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1612600 Associated Lab Samples:92277063001, 92277063002, 92277063003, 92277063004 Matrix:Water AnalyzedMDL Nitrogen, Nitrate ug/L 15.1J 10000 11/21/15 09:1310.0 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1612601LABORATORY CONTROL SAMPLE: LCSSpike Nitrogen, Nitrate ug/L 2410J2500 96 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1612602MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92277045001 1612603 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate ug/L 2500 94 90-11094 0 1025002.5 mg/L 4860J 4870J Parameter Units MS Result % Rec Limits Qual% RecConc. 1612604MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92277042001 1612605 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate ug/L 2500 95 90-11095 0 1025000.26 mg/L 2640J 2640J REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 07:43 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92277063 TOWN OF KERNERSVILLE MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/25595 SM 4500-Cl-E SM 4500-Cl-E 4500 Chloride Associated Lab Samples:92277063001, 92277063002, 92277063003, 92277063004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1617477 Associated Lab Samples:92277063001, 92277063002, 92277063003, 92277063004 Matrix:Water AnalyzedMDL Chloride ug/L ND 1000 12/01/15 23:04500 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1617478LABORATORY CONTROL SAMPLE: LCSSpike Chloride ug/L 1990020000 99 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1617479MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92277541002 1617480 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride ug/L 20000 107 90-110106 1 10200007.5 mg/L 28900 28600 Parameter Units MS Result % Rec Limits Qual% RecConc. 1617481MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92277541003 1617482 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride ug/L 20000 105 90-110104 1 10200002.6 mg/L 23600 23400 Parameter Units MS Result % Rec Limits Qual% RecConc. 1617701MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92277771001 1617702 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride ug/L M11000003690-11035 1 1010000021.8 mg/L 57400 56600 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 07:43 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92277063 TOWN OF KERNERSVILLE MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/25529 SM 5220D SM 5220D 5220D COD Associated Lab Samples:92277063001, 92277063002, 92277063003, 92277063004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1614082 Associated Lab Samples:92277063001, 92277063002, 92277063003, 92277063004 Matrix:Water AnalyzedMDL Chemical Oxygen Demand ug/L ND 25000 11/24/15 15:4012500 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1614083LABORATORY CONTROL SAMPLE: LCSSpike Chemical Oxygen Demand ug/L 740000750000 99 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1614084MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92276957001 1614085 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chemical Oxygen Demand ug/L 1500000 88 90-11088 0 31500000833 mg/L 2150000 2150000 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 07:43 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92277063 TOWN OF KERNERSVILLE MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/25563 SM 5310B SM 5310B 5310B TOC Associated Lab Samples:92277063001, 92277063002, 92277063003, 92277063004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1616105 Associated Lab Samples:92277063001, 92277063002, 92277063003, 92277063004 Matrix:Water AnalyzedMDL Total Organic Carbon ug/L ND 1000 11/30/15 17:31500 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1616106LABORATORY CONTROL SAMPLE: LCSSpike Total Organic Carbon ug/L 2290025000 92 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1616107MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92276855001 1616108 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Total Organic Carbon ug/L M1,R1250008590-11095 10 5250001.5 mg/L 22900 25400 Parameter Units MS Result % Rec Limits Qual% RecConc. 1616109MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92277063004 1616110 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Total Organic Carbon ug/L 25000 90 90-11090 1 52500019002430024500 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 07:43 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 31 #=QL# QUALIFIERS Pace Project No.: Project: 92277063 TOWN OF KERNERSVILLE MNA DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - MinneapolisPASI-M ANALYTE QUALIFIERS Analyte was detected in the associated method blank.B Oxygen usage is less than 2.0 for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample.B2 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 RPD value was outside control limits.R1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 07:43 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 31 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92277063 TOWN OF KERNERSVILLE MNA Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92277063001 AIR/247133404-MW2 RSK 175 92277063002 AIR/247133404-MW3S RSK 175 92277063003 AIR/247133404-MW3D RSK 175 92277063004 AIR/247133404-MW4 RSK 175 92277063001 WET/416593404-MW2 SM 2320B 92277063002 WET/416593404-MW3S SM 2320B 92277063003 WET/416593404-MW3D SM 2320B 92277063004 WET/416593404-MW4 SM 2320B 92277063001 WET/415713404-MW2 SM 4500-S2D 92277063002 WET/415713404-MW3S SM 4500-S2D 92277063003 WET/415713404-MW3D SM 4500-S2D 92277063004 WET/415713404-MW4 SM 4500-S2D 92277063001 WET/41545 WET/415473404-MW2 SM 5210B SM 5210B 92277063002 WET/41545 WET/415473404-MW3S SM 5210B SM 5210B 92277063003 WET/41545 WET/415473404-MW3D SM 5210B SM 5210B 92277063004 WET/41545 WET/415473404-MW4 SM 5210B SM 5210B 92277063001 WETA/255673404-MW2 EPA 300.0 92277063002 WETA/255673404-MW3S EPA 300.0 92277063003 WETA/255673404-MW3D EPA 300.0 92277063004 WETA/255673404-MW4 EPA 300.0 92277063001 WETA/254913404-MW2 EPA 353.2 92277063002 WETA/254913404-MW3S EPA 353.2 92277063003 WETA/254913404-MW3D EPA 353.2 92277063004 WETA/254913404-MW4 EPA 353.2 92277063001 WETA/255953404-MW2 SM 4500-Cl-E 92277063002 WETA/255953404-MW3S SM 4500-Cl-E 92277063003 WETA/255953404-MW3D SM 4500-Cl-E 92277063004 WETA/255953404-MW4 SM 4500-Cl-E 92277063001 WETA/255293404-MW2 SM 5220D 92277063002 WETA/255293404-MW3S SM 5220D 92277063003 WETA/255293404-MW3D SM 5220D 92277063004 WETA/255293404-MW4 SM 5220D 92277063001 WETA/255633404-MW2 SM 5310B 92277063002 WETA/255633404-MW3S SM 5310B 92277063003 WETA/255633404-MW3D SM 5310B 92277063004 WETA/255633404-MW4 SM 5310B REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/22/2015 07:43 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 31 Page 22 of 31 Page 23 of 31 Page 24 of 31 Page 25 of 31 Page 26 of 31 Page 27 of 31 Page 28 of 31 Page 29 of 31 Page 30 of 31 Page 31 of 31 D A T E : 1 1 / 1 9 / 1 5 I , . , j g J r L . E r ] G t r \ t E E R 1 r J G G R O U N D W A T E R S A M P L I N G L O G W e l l L o c a t i o n : B a c k s i d e o f l a n d f i l l a l o n g C r e e k 2 i n c h e s 5 . 0 1 f e e t 1 3 . 1 8 f e e t 8 . 1 7 f e e t [ D T B - D T W ] D i s s o l v e d C 0 2 : 1 2 5 m g / L D a t e : ‘ 1 f — D a t e : 1 7 1 3 1 / c — P r o j e c t N a m e : W e l l I D : T o w n O f K e m e r s v i l l e P r o j e c t N o . I T a s k N o . : 8 3 8 . 1 6 0 1 . 1 2 . 0 1 M W - 2 S a m p l e r ( s ) : H . S e a t o n ! G . E l l e r W e l l D i a m e t e r : I n i t i a l D e p t h t o W a t e r ( D T W ) : D e p t h t o B o t t o m ( D T B ) : W a t e r C o l u m n T h i c k n e s s ( W C T ) : C a l c u l a t i o n f o r O n e W e l l V o l u m e ( W V ) : F o r 2 ” W e l l : W C T X 0 . 1 6 3 F o r 4 ” W e l l : W C T X 0 . 6 5 3 F o r T H R E E W e l l V o l u m e s : W V X 3 A c t u a l A m o u n t P u r g e d / B a i l e d : P u r g e d w i t h : D i s p o s a b l e b a i l e r S a m p l e d w i t h : D i s p o s a b l e b a i l e r D e p t h t o W a t e r b e f o r e S a m p l i n g : 1 3 a t 1 o n s - g a l l o n s 3 . 9 g a l l o n s 3 . 9 g a l l o n s f e e t G a l l o n s T i m e T e m p ( ° C ) D O C o n d . ( u S ) p H O R P T u r b . ( n t u ) I n i t i a l s 0 1 2 3 8 1 6 . 6 2 . 8 7 2 4 7 . 2 6 . 2 2 1 3 4 . 4 6 . 7 4 H S 1 . 3 1 2 3 9 1 6 . 1 2 . 2 9 2 4 5 . 3 5 . 9 9 1 3 5 . 1 6 . 0 8 H S 2 . 6 1 2 4 0 1 6 . 5 2 . 3 6 2 5 7 . 1 5 . 9 8 1 0 5 . 5 4 . 2 3 H S 3 . 9 1 2 4 1 1 7 . 1 1 . 8 5 2 9 3 . 1 6 . 0 3 1 0 0 . 3 4 . 4 0 H S B e f o r e 1 2 4 1 1 7 . 1 1 . 8 5 2 9 3 . 1 6 . 0 3 1 0 0 . 3 4 . 4 0 H S S a m p l i n g C o m m e n t s ( w e a t h e r c o n d i t i o n s , o d o r , c o l o r , s i l t , e t c . ) : T h e w e a t h e r w a s p a r t l y c l o u d y w i t h t e m p e r a t u r e s i n t h e 6 0 s o n 1 1 / 1 9 / 2 0 1 5 . f e 2 + : 0 . 5 m / L S i g n a t u r e : Q A I Q C S i g n O f f : 4 / £ - / ‘ / 7 D A T E : 1 1 / 1 9 / 1 5 J O Y C E _ _ _ _ _ _ _ _ _ G R O U N D W A T E R S A M P L I N G L O G P r o j e c t N a m e : T o w n O f K e m e r s v i l l e P r o j e c t N o . / T a s k N o . : 8 3 8 . 1 6 0 1 . 1 2 . 0 1 W e l l I D : M W - 3 D S a m p l e r ( s ) : H . S e a t o n ! G . E l l e r W e l l L o c a t i o n : B a c k s i d e o f l a n d f i l l a l o n g C r e e k W e l l D i a m e t e r : 2 i n c h e s I n i t i a l D e p t h t o W a t e r ( D T W ) : 1 4 . 0 3 f e e t D e p t h t o B o t t o m ( D T B ) : 5 6 . 9 6 f e e t W a t e r C o l u m n T h i c k n e s s ( W C T ) : 4 2 . 9 3 f e e t [ D T B - D T W ] C a l c u l a t i o n f o r O n e W e l l V o l u m e ( W V ) : F o r 2 ” W e l l : W C T X 0 . 1 6 3 = 6 . 9 g a l l o n s F o r 4 ” W e l l : W C T X 0 . 6 5 3 = - g a l l o n s F o r T H R E E W e l l V o l u m e s : W V X 3 = 2 0 . 7 g a l l o n s A c t u a l A m o u n t P u r g e d / B a i l e d : 2 0 . 7 g a l l o n s P u r g e d w i t h : D i s p o s a b l e B a i l e r S a m p l e d w i t h : D i s p o s a b l e B a i l e r D e p t h t o W a t e r b e f o r e S a m p l i n g : - f e e t G a l l o n s T i m e T e m p ( ° C ) D O C o n d . ( j i S ) p H O R P T u r b . ( n t u ) I n i t i a l s 0 1 0 1 9 1 6 . 8 0 . 5 7 2 9 6 . 4 6 . 3 6 - 2 1 . 5 7 . 8 9 H S 6 . 9 1 0 2 6 1 5 . 9 1 . 8 7 2 9 0 . 4 6 . 3 1 - 1 2 . 6 9 . 0 7 H S 1 3 . 8 1 0 3 1 1 5 . 8 3 . 4 0 2 9 0 . 0 6 . 1 4 2 8 . 3 6 . 5 9 H S 2 0 . 7 1 0 4 5 1 5 . 8 0 . 8 1 2 9 4 . 7 6 . 0 6 2 9 . 4 7 . 0 0 H S B e f o r e 1 0 4 5 1 5 . 8 0 . 8 1 2 9 4 . 7 6 . 0 6 2 9 . 4 7 . 0 0 H S S a m p l i n g C o m m e n t s ( w e a t h e r c o n d i t i o n s , o d o r , c o l o r , s i l t , e t c . ) : T h e w e a t h e r w a s p a r t l y c l o u d y w i t h t e m p e r a t u r e s i n t h e 6 0 s o n 1 1 / 1 9 / 2 0 1 5 F e 2 + : 0 m / L D i s s o l v e d C O 2 : 9 0 m g / L S i g n a t u r e : _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ D a t e : _ _ _ _ _ _ _ _ _ _ Q A I Q C S i g n O f f : / I L i I D a t e : _ _ _ _ _ _ _ _ _ D A T E : 1 1 / 1 9 / 1 5 D i s s o l v e d C 0 2 : 1 1 5 m g / L S i g n a t u r e : ‘ 7 Q A I Q C S i g n O f f : % 7 f / / L 4 — 2 i n c h e s 1 6 . 9 7 f e e t 2 4 . 0 0 f e e t 7 . 1 1 f e e t [ D T B - D T W ] 1 . 2 g a l l o n s - g a l l o n s 3 . 6 g a l l o n s 3 . 6 g a l l o n s J O Y C E G R O U N D W A T E R S A M P L I N G L O G P r o j e c t N a m e : T o w n O f K e m e r s v i l l e P r o j e c t N o . / T a s k N o . : 8 3 8 . 1 6 0 1 . 1 2 . 0 1 W e l l I D : M W - 3 S S a m p l e r ( s ) : H . S e a t o n l G . E l l e r W e l l L o c a t i o n : B a c k s i d e o f l a n d f i l l a l o n e C r e e k W e l l D i a m e t e r : I n i t i a l D e p t h t o W a t e r ( D T W ) : D e p t h t o B o t t o m ( D T B ) : W a t e r C o l u m n T h i c k n e s s ( W C T ) : C a l c u l a t i o n f o r O n e W e l l V o l u m e ( W V ) : f o r 2 ” W e l l : W C T X 0 . 1 6 3 f o r 4 ” W e l l : W C T X 0 . 6 5 3 F o r T H R E E W e l l V o l u m e s : W V X 3 A c t u a l A m o u n t P u r g e d / B a i l e d : P u r g e d w i t h : D i s p o s a b l e B a i l e r S a m p l e d w i t h : D i s p o s a b l e B a i l e r D e p t h t o W a t e r b e f o r e S a m p l i n g : f e e t G a l l o n s T i m e T e m p ( ° C ) D O C o n d . ( i S ) p H O R P T u r b . ( n t u ) I n i t i a l s 0 0 9 5 8 1 5 . 8 1 . 0 1 2 6 6 . 4 5 . 7 6 6 2 . 1 1 6 . 4 H S 1 . 2 0 9 5 9 1 6 . 4 3 . 0 1 2 8 9 . 3 6 . 0 0 5 1 . 4 2 1 . 2 H S 2 . 4 1 0 0 0 1 6 . 1 2 . 3 4 2 9 8 . 1 6 . 0 8 3 6 . 1 1 9 . 9 H S 3 . 6 1 0 0 2 1 6 . 0 2 . 4 9 3 0 1 . 5 6 . 1 5 5 7 . 6 2 0 . 7 H S B e f o r e 1 0 0 2 1 6 . 0 2 . 4 9 3 0 1 . 5 6 . 1 5 5 7 . 6 2 0 . 7 H S S a m p l i n g F e 2 + : 0 . 0 m J L C o m m e n t s ( w e a t h e r c o n d i t i o n s , o d o r , c o l o r , s i l t , e t c . ) : T h e w e a t h e r w a s p a r t l y c l o u d y w i t h t e m p e r a t u r e s i n t h e 6 0 s o n 1 1 / 1 9 / 2 0 1 5 D a t e : D a t e : D A T E : 1 1 / 1 9 / 1 5 J O Y C E _ _ _ _ _ _ _ _ _ E N Q 3 I t \ ] E E R I ! \ 1 1 3 G R O U N D W A T E R S A M P L I N G L O G P r o j e c t N a m e : T o w n O f K e m e r s v i l l e P r o j e c t N o . / T a s k N o . : 8 3 8 . 1 6 0 1 . 1 2 . 0 1 W e l l I D : M W - 4 S a m p l e r ( s ) : H . S e a t o n l G . E l l e r W e l l L o c a t i o n : B a c k s i d e o f l a n d f i l l a l o n g C r e e k W e l l D i a m e t e r : 2 i n c h e s I n i t i a l D e p t h t o W a t e r ( D T W ) : 9 . 6 0 f e e t D e p t h t o B o t t o m ( D T B ) : 1 4 . 4 0 f e e t W a t e r C o l u m n T h i c k n e s s ( W C T ) : 4 . 8 0 f e e t [ D T B - D T W ] C a l c u l a t i o n f o r O n e W e l l V o l u m e ( W V ) : F o r 2 ” W e l l : W C T X 0 . 1 6 3 = 0 . 8 g a l l o n s F o r 4 ” W e l l : W C T X 0 . 6 5 3 = - g a l l o n s F o r T H R E E W e l l V o L u m e s : W V X 3 = 2 . 4 g a l l o n s A c t u a l A m o u n t P u r g e d / B a i l e d : 2 . 4 g a l l o n s P u r g e d w i t h : D i s p o s a b l e B a i l e r S a m p l e d w i t h : D i s p o s a b l e B a i l e r D e p t h t o W a t e r b e f o r e S a m p l i n g : - f e e t G a l l o n s T i m e T e m p ( ° C ) D O C o n d . ( . t S ) p H O R P T u r b . ( n t u ) I n i t i a l s 0 1 1 2 9 1 6 . 3 7 . 0 9 3 2 2 . 1 6 . 5 0 5 3 . 5 1 0 . 1 H S 0 . 8 1 1 3 0 1 5 . 7 6 . 1 3 3 1 9 . 1 6 . 5 0 5 7 . 4 6 . 4 7 H S 1 . 6 1 1 3 2 1 5 . 9 4 . 1 3 3 2 0 . 6 6 . 4 1 1 2 . 4 7 . 0 8 H S 2 . 4 1 1 3 4 1 6 . 0 3 . 9 2 3 2 0 . 4 6 . 4 5 3 4 . 5 7 . 7 2 H S B e f o r e 1 1 3 4 1 6 . 0 3 . 9 2 3 2 0 . 4 6 . 4 5 3 4 . 5 7 . 7 2 H S S a m p l i n g C o m m e n t s ( w e a t h e r c o n d i t i o n s , o d o r , c o l o r , s i l t , e t c . ) : T h e w e a t h e r w a s p a r t l y c l o u d y w i t h t e m p e r a t u r e s i n t h e 6 0 s o n 1 1 / 1 9 / 2 0 1 5 . f i e l d b l a n k t a k e n @ 1 3 2 0 f e 2 + : 0 . 5 m g / L D i s s o l v e d C O 2 : 7 0 m g ’ L S i g n a t u r e : _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ D a t e : / I / I ‘ ? / / Q A I Q C S i g n O f f : u 4 D a t e : _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ D A T E : 1 1 / 1 9 / 1 5 2 i n c h e s 4 . 6 3 f e e t 1 1 . 3 6 f e e t 6 . 7 3 f e e t [ D T B - D T W ] _ _ _ _ _ _ _ _ _ _ _ _ _ _ g a l l o n s _ _ _ _ _ _ _ _ _ _ _ _ _ a I l o n s _ _ _ _ _ _ _ _ _ _ _ _ _ _ g a l l o n s g a l l o n s _ _ _ _ _ _ _ _ _ _ _ D a t e : / D a t e : J O Y C E E r J G f l \ J E E R ! r J G P r o j e c t N a m e : T o w n O f K e m e r s v i l l e W e l l I D : M W - 5 W e l l L o c a t i o n : D o w n h i l l b e t w e e n o l d c e l l a n d s h o o t i n g r a n g e . G R O U N D W A T E R S A M P L I N G L O G P r o j e c t N o . / T a s k N o . : 8 3 8 . 1 6 0 1 . 1 2 . 0 1 S a m p l e r ( s ) : H . S e a t o n ! G . E l l e r W e l l D i a m e t e r : _ _ _ _ _ _ _ _ _ _ _ _ _ _ I n i t i a l D e p t h t o W a t e r ( D T W ) : _ _ _ _ _ _ _ _ _ _ _ _ _ D e p t h t o B o t t o m ( D T B ) : _ _ _ _ _ _ _ _ _ _ _ _ W a t e r C o l u m n T h i c k n e s s ( W C T ) : _ _ _ _ _ _ _ _ _ _ _ C a l c u l a t i o n f o r O n e W e l l V o l u m e ( W V ) : F o r 2 ” W e l l : W C T X 0 . 1 6 3 = 1 . 0 F o r 4 ” W e l l : W C T X 0 . 6 5 3 = - F o r T H R E E W e l l V o l u m e s : W V X 3 = 3 . 0 A c t u a l A m o u n t P u r g e d / B a i l e d : 3 . 0 P u r g e d w i t h : D i s p o s a b l e b a i l e r S a m p l e d w i t h : _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ D e p t h t o W a t e r b e f o r e S a m p l i n g : - f e e t D i s p o s a b l e b a i l e r G a l l o n s T i m e T e m p ( ° C ) p 1 1 C o n d . ( j i S ) T u r b . ( n t u ) I n i t i a l s 0 0 9 3 6 1 4 . 3 7 . 8 8 9 2 9 . 7 8 H S 1 . 0 0 9 3 8 1 3 . 3 7 . 1 0 3 9 1 0 . 6 H S 2 . 0 0 9 3 9 1 3 . 1 6 . 0 8 3 6 1 0 . 9 H S 3 . 0 0 9 4 1 1 3 . 2 5 . 4 5 3 6 1 1 . 2 H S B e f o r e S a m p l i n g 0 9 4 1 1 3 . 2 5 . 4 5 3 6 1 1 . 2 H S C o m m e n t s ( w e a t h e r c o n d i t i o n s , o d o r , c o l o r , s i l t , e t c . ) : T h e w e a t h e r w a s p a r t l y c l o u d y w i t h t e m p e r a t u r e s i n t h e 6 0 s o n 1 1 / 1 9 / 2 0 1 5 S i g n a t u r e : Q A / Q C S i g n O f f : I I ‘ — 7 D A T E : 1 1 / 1 9 / 1 5 J O Y C E _ _ _ _ _ _ _ _ E t ’ J G t t ’ J E F R t t J G G R O U N D W A T E R S A M P L I N G L O G P r o j e c t N a m e : T o w n O f K e m e r s v i l l e P r o j e c t N o . / T a s k N o . : 8 3 8 . 1 6 0 1 . 1 2 . 0 1 W e l l I D : M W - 6 S a m p l e r ( s ) : H . S e a t o n l G . E l l e r W e l l L o c a t i o n : O n R i g h t s i d e o f r o a d b e h i n d o l d s c a l e h o u s e l o c a t i o n . W e l l D i a m e t e r : _ _ _ _ _ _ _ _ _ _ _ _ _ _ I n i t i a l D e p t h t o W a t e r ( D T W ) : _ _ _ _ _ _ _ _ _ _ _ _ _ _ D e p t h t o B o t t o m ( D T B ) : _ _ _ _ _ _ _ _ _ _ _ _ W a t e r C o l u m n T h i c k n e s s ( W C T ) : _ _ _ _ _ _ _ _ _ _ _ C a l c u l a t i o n f o r O n e W e l l V o l u m e ( W V ) : f o r 2 ” W e l l : W C T X 0 . 1 6 3 = _ _ _ _ _ _ _ _ _ _ _ _ f o r 4 ” W e l l : W C T X 0 . 6 5 3 = _ _ _ _ _ _ _ _ _ _ _ _ _ f o r T H R E E W e l l V o l u m e s : W V X 3 = _ _ _ _ _ _ _ _ _ _ A c t u a l A m o u n t P u r g e d / B a i l e d : - g a l l o n s P u r g e d w i t h : - S a m p l e d w i t h : - D e p t h t o W a t e r b e f o r e S a m p l i n g : - f e e t S i g n a t u r e : Q A / Q C S i g n O f f : / / _ _ 1 < D a t e : / / 4 / D a t e : 2 i n c h e s - - f e e t 2 0 . 4 6 f e e t 0 . 2 1 f e e t [ D T B - D T W ] - g a l l o n s - g a l l o n s - a 1 l o n s G a l l o n s l i m e T e m p ( ° C ) D O C o n d . ( u S ) p 1 1 O R P l u r b . ( n t u ) I n i t i a l s D r y B e f o r e S a m p l i n g C o m m e n t s ( w e a t h e r c o n d i t i o n s , o d o r , c o l o r , s i l t , e t c . ) : T h e w e a t h e r w a s p a r t l y c l o u d y w i t h t e m n e r a t u r e s i n t h e 6 0 s o n 1 1 / 1 9 / 2 0 1 5 . T h e w e l l w a s d w a n d n o t s a m n l e d D A T E : 1 1 / 1 9 / 1 5 S U R F A C E W A T E R M O N I T O R I N G L O G _ _ _ _ _ _ _ _ _ _ _ P r o j e c t / T a s k N o . : 8 3 8 . 1 6 0 1 . 1 2 . 0 1 S a m p l e r ( s ) : H . S e a t o n ! G . E l l e r F i e l d P a r a m e t e r s : T i m e o f S a m p l i n g : 1 3 0 5 p H : 6 . 9 2 T e m p e r a t u r e : 1 7 . 0 C o n d u c t i v i t y : 4 8 . 4 T u r b i d i t y : 1 7 . 7 ( n t u ) C o m m e n t s / S a m p l e D e s c r i p t i o n ( w e a t h e r c o n d i t i o n s , o d o r , c o l o r , s i l t , e t c . ) : T h e w e a t h e r w a s p a r t l y c l o u d y w i t h t e m p e r a t u r e s i n t h e 6 0 s o n 1 1 / 1 9 / 2 0 1 5 . J O Y C E E f \ J G I r J E E R i r \ I G P r o j e c t N a m e : T o w n O f K e m e r s v i l l e S u r f a c e P o i n t I D : S W - i L o c a t i o n : U n s t r e a m o f M W - 2 b e f o r e 2 c r e e k s m e r g e . ( ° C ) ( i S ) S k e t c h o f S i g n a t u r e : _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ D a t e : _ _ _ _ _ _ _ _ _ _ _ _ Q A I Q C S i g n O f f : _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ D a t e : _ _ _ _ _ _ _ _ _ _ _ _ _ D A T E : 1 1 / 1 9 / 1 5 J O Y C E _ _ _ _ _ _ _ _ _ E t J G t h . J E E R I ! \ J G S U R F A C E W A T E R M O N I T O R I N G L O G P r o j e c t N a m e : T o w n O f K e m e r s v i l l e P r o j e c t / T a s k N o . : 8 3 8 . 1 5 0 1 . 1 2 . 0 1 S u r f a c e P o i n t I D : S W - 2 S a m p l e r ( s ) : H . S e a t o n ! G . E l l e r L o c a t i o n : D o w n S t r e a m o f M W - 4 a t p r o p e r t y l i n e . F i e l d P a r a m e t e r s : T i m e o f S a m p l i n g : 1 2 5 5 p H : 7 . 0 1 T e m p e r a t u r e : 1 6 . 8 ( ° C ) C o n d u c t i v i t y : 5 7 . 8 ( j i S ) T u r b i d i t y : 1 8 . 1 ( n t u ) C o m m e n t s / S a m p l e D e s c r i p t i o n ( w e a t h e r c o n d i t i o n s , o d o r , c o l o r , s i l t , e t c . ) : T h e w e a t h e r w a s p a r t l y c l o u d y w i t h t e m p e r a t u r e s i n t h e 6 0 s o n 1 1 / 1 9 / 2 0 1 5 . S k e t c h o f S a r n p 2 e L o c a % o n , % i n c l u d e f l o w / i r e c t i o n , d r 7 n a g e P a t w a Y s e t c . ) : / / I i S i g n a t u r e : _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ D a t e : / 7 ) ) Q / f t Q A / Q C S i g n O f f : / / D a t e : _ _ _ _ _ _ _ _ _ _ D A T E : 1 1 / 1 9 / 1 5 J O Y C E _ _ _ _ _ _ _ _ _ _ E N G I t ’ J E E R I t . ] G S U R F A C E W A T E R M O N I T O R I N G L O G P r o j e c t N a m e : T o w n O f K e m e r s v i l l e P r o j e c t / T a s k N o . : 8 3 8 . 1 6 0 1 . 1 2 . 0 1 S u r f a c e P o i n t I D : S W - 3 S a m p l e r ( s ) : H . S e a t o n , G . E l l e r L o c a t i o n : I n t h e s t r e a m d i r e c t l y a c r o s s f r o m M W - 2 F i e l d P a r a m e t e r s : T i m e o f S a m p l i n g : 1 1 5 5 p H : 7 . 2 8 T e m p e r a t u r e : 1 5 . 9 ( ° C ) C o n d u c t i v i t y : 5 5 . 8 ( p S ) T u r b i d i t y : 1 5 . 2 5 ( n t u ) C o m m e n t s / S a m p l e D e s c r i p t i o n ( w e a t h e r c o n d i t i o n s , o d o r , c o l o r , s i l t , e t c . ) : _ _ _ _ _ _ _ _ _ _ _ T h e w e a t h e r w a s p a r t l y c l o u d y w i t h t e m p e r a t u r e s i n t h e 6 0 s o n 1 1 / 1 9 / 2 0 1 5 . S k e t c h o f S a m p l e L o c a t i o n i u c 1 u d e f l o w d i r e c t i o n , r a i n a e p a h w a y s , e t c . ) : / c i 0 / / 1 / S i g n a t u r e : _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ D a t e : t i / / q / 4 Q A / Q C S i g n O f f : 4 3 / D a t e : _ _ _ _ _ _ _ _ _ _ Appendix II Summary of Detections Summary of Detections WELL ID PARAMETER RESULT UNITS SWSL COLLECT DATE 3404-MW2 1,1-Dichloroethane 20.7 µg/L 5 11/19/2015 3404-MW2 1,2-Dichloropropane 4.3 µg/L 1 11/19/2015 3404-MW2 1,4-Dichlorobenzene 4.8 µg/L 1 11/19/2015 3404-MW2 Barium 294 µg/L 100 11/19/2015 3404-MW2 Benzene 6 µg/L 1 11/19/2015 3404-MW2 cis-1,2-Dichloroethene 44.4 µg/L 5 11/19/2015 3404-MW2 Trichloroethene 4.7 µg/L 1 11/19/2015 3404-MW2 Vinyl chloride 7.7 µg/L 1 11/19/2015 3404-MW3D 1,2-Dichloroethane 1.1 µg/L 1 11/19/2015 3404-MW3D 1,2-Dichloropropane 1.1 µg/L 1 11/19/2015 3404-MW3D 1,4-Dichlorobenzene 3.5 µg/L 1 11/19/2015 3404-MW3D cis-1,2-Dichloroethene 51.2 µg/L 5 11/19/2015 3404-MW3D Thallium 8.8 µg/L 5.5 11/19/2015 3404-MW3D Vinyl chloride 6.7 µg/L 1 11/19/2015 3404-MW3S 1,4-Dichlorobenzene 1.4 µg/L 1 11/19/2015 3404-MW3S Barium 108 µg/L 100 11/19/2015 3404-MW3S cis-1,2-Dichloroethene 5.6 µg/L 5 11/19/2015 3404-MW3S Vinyl chloride 2 µg/L 1 11/19/2015 3404-MW3S Zinc 23.1 µg/L 10 11/19/2015 3404-MW4 1,4-Dichlorobenzene 2.5 µg/L 1 11/19/2015 3404-MW4 Barium 101 µg/L 100 11/19/2015 3404-MW4 cis-1,2-Dichloroethene 18.8 µg/L 5 11/19/2015 3404-MW4 Thallium 8.8 µg/L 5.5 11/19/2015 3404-MW4 Vinyl chloride 17.3 µg/L 1 11/19/2015 3404-MW4 Zinc 10.7 µg/L 10 11/19/2015 3404-MW5 Zinc 16.3 µg/L 10 11/19/2015 3404-SW3 Zinc 10.1 µg/L 10 11/19/2015 Notes:µg/L = Micorgrams per liter SWSL = NC Soild Waste Section Reporting Limit Laboratory Reporting limit used when SWSL has not been established Town of Kernersville Landfill Permit No. 34-04 Page 1 of 1 Joyce Engineering Appendix III Summary of Exceedances Summary of Exceedances WELL ID PARAMETER RESULT UNITS NC2L/GWPS GPS SWSL COLLECT DATE 3404-MW2 1,1-Dichloroethane 20.7 µg/L 6 6 5 11/19/2015 3404-MW2 1,2-Dichloropropane 4.3 µg/L 0.6 0.6 1 11/19/2015 3404-MW2 Benzene 6 µg/L 1 1 1 11/19/2015 3404-MW2 Trichloroethene 4.7 µg/L 3 3 1 11/19/2015 3404-MW2 Vinyl chloride 7.7 µg/L 0.03 0.03 1 11/19/2015 3404-MW3D 1,2-Dichloroethane 1.1 µg/L 0.4 0.4 1 11/19/2015 3404-MW3D 1,2-Dichloropropane 1.1 µg/L 0.6 0.6 1 11/19/2015 3404-MW3D Thallium 8.8 µg/L 0.28 0.28 5.5 11/19/2015 3404-MW3D Vinyl chloride 6.7 µg/L 0.03 0.03 1 11/19/2015 3404-MW3S Vinyl chloride 2 µg/L 0.03 0.03 1 11/19/2015 3404-MW4 Vinyl chloride 17.3 µg/L 0.03 0.03 1 11/19/2015 3404-MW4 Thallium 8.8 µg/L 0.28 0.28 5.5 11/19/2015 Notes:µg/L = Micorgrams per liter SWSL = NC Soild Waste Section Reporting Limit Laboratory Reporting limit used when SWSL has not been established NC2L = NC Groundwater Standard from 15A NCAC 2L.0202 GWPS = NC Solid Waste Section Groundwater Protection Standard (for constituents with no NC2L) GPS = Groundwater Protection Standard as defined by 15A NCAC 13B.1634(g) NA= Not Applicable Town of Kernersville Landfill Permit No. 34-04 Page 1 of 1 Joyce Engineering Appendix IV Summary of Field Parameters Summary of Field Parameters WELL ID PARAMETER RESULT UNITS COLLECT DATE MW-2 Dissolved Oxygen 1.85 mg/L 11/19/2015 MW-2 Oxidation Reduction Potential 100.3 mV 11/19/2015 MW-2 pH 6.03 S.U.11/19/2015 MW-2 Temperature 17.1 ºC 11/19/2015 MW-2 Ferrous Iron 0.5 mg/L 11/19/2015 MW-2 Dissolved Carbon Dioxide 90 mg/L 11/19/2015 MW-2 Conductivity 293.1 µS 11/19/2015 MW-2 Turbididty 4.4 NTU 11/19/2015 MW-2 Static Water Level 5.01 ft 11/19/2015 MW-2 Well Depth 13.18 ft 11/19/2015 MW-3S pH 6.15 S.U.11/19/2015 MW-3S Temperature 16 ºC 11/19/2015 MW-3S Conductivity 301.5 µS 11/19/2015 MW-3S Ferrous Iron 0.0 mg/L 11/19/2015 MW-3S Dissolved Carbon Dioxide 115 mg/L 11/19/2015 MW-3S Static Water Level 16.97 ft 11/19/2015 MW-3S Well Depth 24 ft 11/19/2015 MW-3S Dissolved Oxygen 2.49 mg/L 11/19/2015 MW-3S Oxidation Reduction Potential 57.6 mV 11/19/2015 MW-3D Dissolved Oxygen 0.81 mg/L 11/19/2015 MW-3D Oxidation Reduction Potential 29.4 mV 11/19/2015 MW-3D pH 6.06 S.U.11/19/2015 MW-3D Temperature 15.8 ºC 11/19/2015 MW-3D Ferrous Iron 0.0 mg/L 11/19/2015 MW-3D Conductivity 294.7 µS 11/19/2015 MW-3D Dissolved Carbon Dioxide 90 mg/L 11/19/2015 MW-3D Turbididty 7.00 NTU 11/19/2015 MW-3D Static Water Level 14.03 ft 11/19/2015 MW-3D Well Depth 56.96 ft 11/19/2015 MW-4 pH 6.45 S.U.11/19/2015 MW-4 Temperature 16 ºC 11/19/2015 MW-4 Conductivity 320.4 µS 11/19/2015 MW-4 Turbididty 7.72 NTU 11/19/2015 MW-4 Ferrous Iron 0.5 mg/L 11/19/2015 MW-4 Dissolved Carbon Dioxide 70 mg/L 11/19/2015 MW-4 Static Water Level 9.6 ft 11/19/2015 MW-4 Well Depth 14.4 ft 11/19/2015 MW-4 Dissolved Oxygen 3.92 mg/L 11/19/2015 MW-4 Oxidation Reduction Potential 34.5 mV 11/19/2015 MW-5 pH 5.45 S.U.11/19/2015 MW-5 Temperature 13.2 ºC 11/19/2015 MW-5 Conductivity 36 µS 11/19/2015 MW-5 Turbididty 11.2 NTU 11/19/2015 MW-5 Static Water Level 4.63 ft 11/19/2015 MW-5 Well Depth 11.36 ft 11/19/2015 Town of Kernersville Landfill Permit No. 34-04 Page 1 of 2 Joyce Engineering Summary of Field Parameters WELL ID PARAMETER RESULT UNITS COLLECT DATE SW-1 pH 6.92 S.U.11/19/2015 SW-1 Temperature 17 ºC 11/19/2015 SW-1 Conductivity 48.4 µS 11/19/2015 SW-1 Turbididty 17.7 NTU 11/19/2015 SW-2 pH 7.01 S.U.11/19/2015 SW-2 Temperature 16.8 ºC 11/19/2015 SW-2 Conductivity 57.8 µS 11/19/2015 SW-2 Turbididty 18.1 NTU 11/19/2015 SW-3 pH 7.28 S.U.11/19/2015 SW-3 Temperature 15.9 ºC 11/19/2015 SW-3 Conductivity 55.8 µS 11/19/2015 SW-3 Turbididty 15.25 NTU 11/19/2015 Notes:ºC= degrees Centigrade S.U.= Standard Units µS = microsemens NTU = Nephelometric Turbidity Units ft = feet mV = millivolts mg/L = milligrams per liter Town of Kernersville Landfill Permit No. 34-04 Page 2 of 2 Joyce Engineering