8106_DukeRogers_April2016_1stSemiAnnual_DIN26249_20160628

526 South Church Street
Charlotte, NC 28202
Mailing Address:
PO Box 1006
Mail Code EC13K
Charlotte, NC 28201-1006
980 373 2779
704 382 6240 fax July 1, 2016
Ms. Elizabeth Werner
North Carolina Department of Environmental Quality
Division of Waste Management
Solid Waste Section
1646 Mail Service Center
Raleigh, NC 27699-1646
Subject: Semi-annual Groundwater Monitoring Report - April 2016
Duke Energy Carolina, LLC
Permit No. 8106-INDUS
Rogers Energy Complex (formerly Cliffside Steam Station)
573 Duke Power Road, Mooresboro, NC 28114
Dear Ms. Werner:
Duke Energy is providing the results of semi-annual groundwater monitoring for the Rogers Energy
Complex CCP Landfill, located in Mooresboro, North Carolina.
On April 6, 2016, groundwater and surface water samples were collected in accordance with the
Water Quality Monitoring Plan. Table 4 provides a summary of groundwater field and analytical
results. Table 6 provides a summary of surface water field and analytical results. Table 7 provides
a summary of leachate field and analytical results.
Duke Energy personnel sample designated groundwater and surface water locations at the Rogers
Energy Complex CCP Landfill semi-annually during April and October. The next landfill monitoring
event is planned for October 2016 with a report of monitoring results to follow.
If you have any questions or concerns, please contact me at 980-373-2779 or at
[e-mail].
Respectfully submitted,
Ryan Czop, Engineer I
Environmental Services
Electronic cc: Steve Hodges, Duke Energy
Tim Hunsucker, Duke Energy
Sean DeNeale, Duke Energy
Ed Sullivan, Duke Energy
Bill Miller, HDR Engineering, Inc.
Scott Spinner, HDR Engineering, Inc.
Ian Holdeman, HDR Engineering, Inc.

Coal Combustion Products (CCP) Landfill
Phase I
Permit No. 8106
Semiannual Groundwater
Monitoring Report
April 2016 Sampling Event
Rogers Energy Complex
June 28, 2016

Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Rogers Energy Complex, CCP Landfill, Phase I, Permit No.8106
April 2016 Sampling Event
Contents

i
Contents
Page
Section 1 – Background ................................................................................................................ 1
Section 2 – Methods ..................................................................................................................... 3
2.1 Sampling and Analysis Methods .................................................................................... 3
2.2 Statement of Work .......................................................................................................... 3
Section 3 - Results ........................................................................................................................ 5
3.1 Site Groundwater Flow ................................................................................................... 5
3.2 Analytical Results ........................................................................................................... 5

Figures
1. Site Location Map
2. Sample Locations
3. Generalized Groundwater Surface Contours
Tables
1. Well Construction Information
2. Groundwater Flow Velocities
3. Field Data Parameters
4. Groundwater Field and Analytical Results
5. Field and Analytical Results that Equal or Exceed 15A NCAC 2L Groundwater Quality
Standards
6. Surface Water Field and Analytical Results
7. Leachate Field and Analytical Results
Appendices
Appendix A – Field Sampling Forms
Appendix B – Laboratory Report and Chain-of-Custody Forms
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Rogers Energy Complex, CCP Landfill, Phase I, Permit No.8106
April 2016 Sampling Event
Section 1 – Background

1
Section 1 – Background
Rogers Energy Complex is located in Rutherford and Cleveland Counties near Cliffside, North
Carolina. The station is owned and operated by Duke Energy Carolinas, LLC (Duke Energy)
and generates electricity by combustion of coal. The Coal Combustion Products (CCP) Landfill,
Phase I, was constructed with an engineered liner system and permitted to receive fly ash,
bottom ash, boiler slag, mill rejects, flue gas desulfurization sludge, gypsum, leachate basin
sludge, non-hazardous sandblast material, limestone, ball mill rejects, coal, carbon, sulfur
pellets, cation and anion resins, sediment from sumps, and cooling tower sludge under North
Carolina Department of Environmental Quality (NCDEQ) Solid Waste Permit No. 8106. Waste
was first placed into the landfill on October 24, 2010.
The CCP landfill is located southwest of the Rogers Energy Complex on Duke Energy property
and is situated completely within Rutherford County. The CCP landfill is northeast of the
intersection of Old U.S. Highway 221A and Ballenger Road (Figure 1). Phase I of the CCP
landfill has a footprint of approximately 23 acres. The monitoring system for Phase I of the
landfill consists of nine groundwater monitoring wells, two surface water sample locations, and
one leachate sampling location as listed below. Construction of Phase II was completed in early
2016 and has a footprint of approximately 15 acres. The monitoring plan for this phase has
been approved by the Solid Waste Section. Operational approval occurred after the sampling
event discussed in this report, so the data from the Phase II sampling locations will not be
discussed or presented. This is discussed in more detail in section 3.2.

Monitoring Wells: CCPMW-1S
CCPMW-1D
CCPMW-2S
CCPMW-2D
CCPMW-3S
CCPMW-3D
CCPTW-1S
CCPTW-1D
CCPTW-2

Surface Water: CCPSW-1
CCPSW-2

Leachate Sample: CCP-Leachate

The groundwater monitoring wells, surface water sample locations, and leachate sample
locations are shown on Figure 2. Wells with a “D” designation (e.g., CCPMW-1D) are deep wells
that were installed with the well screen below auger refusal. Wells with an “S” designation or no
designation (e.g., CCPTW-2) are shallow wells that were installed with the well screen above
auger refusal. Well construction information is presented in Table 1. The leachate sample is
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Rogers Energy Complex, CCP Landfill, Phase I, Permit No.8106
April 2016 Sampling Event
Section 1 – Background

2
collected at the inlet to the leachate basin instead of the sampling port next to the landfill. The
sample port at the edge of the landfill was getting clogged with silt between sampling events.
There is not a good location to flush the sampling port out so it was decided to collect a sample
where the leachate enters the leachate basin. The inlet to the leachate basin is high on the bank
so the sample represents the leachate entering the concrete basin. The leachate basin is
located on the southeast side of the landfill.

As is typical in the Piedmont region, groundwater at the landfill site occurs within the residuum,
saprolite, partially weathered rock, and fractured bedrock. Groundwater generally flows from
regions of higher topography to regions of lower topography. The highest topographic area at
the landfill site is along the western edge of the landfill. Monitoring wells CCPMW-1S and
CCPMW-1D are considered by the Water Quality Monitoring Plan as background wells for the
landfill.1

Two drainage features are located in close proximity to the CCP landfill: one to the northwest
and one to the southeast. Based on the generalized groundwater surface contours developed
using the groundwater elevations measured in the shallow wells (Figure 3), the expected
groundwater discharge area for the landfill is to Suck Creek, located southeast of the landfill.
Suck Creek flows to the north, to the Broad River.

1 Duke Energy Cliffside CCP Landfill Water Quality Monitoring Plan, December 2011.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Rogers Energy Complex, CCP Landfill, Phase I, Permit No.8106
April 2016 Sampling Event
Section 2 – Methods

3
Section 2 – Methods
2.1 Sampling and Analysis Methods
Groundwater, surface water, and leachate sampling, as well as documentation of sampling
activities were performed by Duke Energy personnel (Duke Energy Carolinas Field Certification
#5193). Copies of the field sampling forms are included in Appendix A. The parameters and
constituents reported were analyzed by Duke Energy Analytical Laboratory (North Carolina
Laboratory Certification #248).
Samples were analyzed for the following constituents:2
 Barium, boron, copper, iron, manganese, silver, and zinc using Solid Waste (SW)
Method 6010D
 Arsenic, cadmium, chromium, lead, nickel, and selenium using SW Method 6020B
 Mercury using Environmental Protection Agency (EPA) Method 7470A
 Chloride, fluoride, nitrate as nitrogen, and sulfate using EPA Method 9056A
 Total dissolved solids using Standard Method (SM) 2540C
Surface water sample locations CCPSW-1 and CCPSW-2 were also field filtered using a 0.45
micron in-line filter and dissolved analysis performed for the following constituents:
 Cadmium, chromium, copper, lead, nickel, and silver using SW Method 6020B

 Zinc using SW Method 6010D
2.2 Statement of Work
HDR completed the following tasks:
 Received field sampling information provided by Duke Energy (performed by Duke
Energy personnel) for monitoring wells CCPMW-1S, CCPMW-1D, CCPMW-2S,
CCPMW-2D, CCPMW-3S, CCPMW-3D, CCPTW-1S, CCPTW-1D, and CCPTW-2. Data
was also received for surface water sample locations CCPSW-1 and CCPSW-2 and for
leachate sampling location CCP-Leachate. The samples were collected on April 6, 2016,
and HDR received the data on May 4, 2016.
 Reviewed the laboratory analytical results for samples. The Electronic Data Deliverable
(EDDs) provided by Duke Energy were adapted to conform to the format requirements of
the NCDEQ EDD template. In the EDDs, HDR added an italicized J’ data qualifier (J’) to
2 Samples were analyzed for constituents listed in Table 4.2 of the Water Quality Monitoring Plan
submitted for the Permit to Construct Application for Phase II of the Landfill. Duke Energy, Cliffside Steam
Station, CCP Landfill-Phase II Permit to Construct Permit Application, CDM August 27, 2012.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Rogers Energy Complex, CCP Landfill, Phase I, Permit No.8106
April 2016 Sampling Event
Section 2 – Methods

4
indicate a detected concentration that equals or is greater than the laboratory’s method
reporting limit (MRL), but less than the Solid Waste Section Limit3 (SWSL), and retained
the laboratory-supplied qualifier J to indicate values that equal or are greater than the
laboratory’s method detection limit (MDL) but are less than the MRL. Copies of the
original EDDs are retained in HDR’s files.
 Developed a generalized groundwater surface contour map using map data and
groundwater elevation data supplied by Duke Energy. Calculated groundwater flow
velocities are based on groundwater surface contours.
 Prepared and submitted this Semiannual Groundwater Monitoring Report to Duke
Energy.

3 The Solid Waste Section Limit (SWSL) is defined by NCDEQ as the lowest amount of analyte in a
sample that can be quantitatively determined with suitable precision and accuracy. The SWSL is the
concentration below which reported results must be qualified as estimated. NCDEQ Division of Waste
Management Memorandum dated February 23, 2007.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Rogers Energy Complex, CCP Landfill, Phase I, Permit No.8106
April 2016 Sampling Event
Section 3 - Results

5
Section 3 - Results
3.1 Site Groundwater Flow
Generalized groundwater surface contours and groundwater flow direction arrows for the site
are shown on Figure 3. These contours were developed using the measured groundwater
elevations in the shallow wells on the date of sampling. Calculated groundwater flow velocities
are presented on Table 2.
Groundwater at the site generally flows from the northwest near CCPMW-1S to the southeast
toward Suck Creek.
3.2 Analytical Results
A summary of the field data is presented in Table 3.
The groundwater sampling field and analytical results are summarized in Table 4. The
groundwater analytical results for the semiannual constituents are compared to the groundwater
standards found in Title 15A NCAC 02L .0202 (g) (2L Standards). Concentrations with values
that attain or exceed the 2L Standards are noted in Table 4 by bold font. A summary of the
groundwater analytical results that attain or exceed the 2L Standards and a preliminary analysis
of the cause and significance of the exceedances are presented in Table 5.
Surface water sample locations CCPSW-1 and CCPSW-2 are located on Suck Creek. As a
result, the field and analytical results for these two locations are compared to Title 15A NCAC
Subchapter 2B Standards (2B Standards) for Class WS-IV surface water. The field and
analytical results for surface water sampling are summarized in Table 6.
Analytical results from monitoring wells CCPMW-4, CCPMW-5, and CCPMW-6S/D are included
in the EDD associated with this report. These monitoring wells are part of the newly completed
Phase II of the Rogers Energy Complex CCP Landfill, approved by SWS subsequent to the
sampling event. The results from these wells are not included in this semiannual groundwater
monitoring report but will be included in a subsequent report.
The MDL was greater than the respective 2B Standard for silver. The MDL for silver was below
the corresponding SWSL as required in the February 23, 2007, NCDEQ memo. This constituent
was not detected above the MDL in the analyzed samples and is not considered to exceed the
2B Standard.
The field and analytical results for leachate sampling are summarized in Table 7.
Concentrations with values that equal or are greater than the SWSLs are noted in Tables 4, 6,
and 7 by gray-shaded cells.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Rogers Energy Complex, CCP Landfill, Phase I, Permit No.8106
April 2016 Sampling Event
Section 3 - Results

6
Select samples were diluted, as is normal laboratory practice, to bring samples within the
calibrated range of the analysis. Specifics regarding the samples that were diluted, including the
dilution factor, are reported in the EDD.
The laboratory report and chain-of-custody forms can be found in Appendix B.

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Geology of Screened IntervalWell Diameter (in.)Casing Type
We
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Gr
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(f
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Page  1  of  1
Ta
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2

-

G
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F
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No
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:
1
.

L
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d
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.
2
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m
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w
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d
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c
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p
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,

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g
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w
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v
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a
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t
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m
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u
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a
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d
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w
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g
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v
a
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3
.

A
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l
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c
a
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u
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c
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n
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p
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s
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e
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n
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y
.
5
.

H
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d
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a
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d
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x
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.
6
.

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c
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p
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d

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d
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s
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d
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D
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C
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f
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p
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p
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h
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(f
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d
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)
Page 1 of 1
Ta
b
l
e

3

-
-

F
i
e
l
d

D
a
t
a

P
a
r
a
m
e
t
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s
Du
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E
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C
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a
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,

L
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C
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R
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s

E
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C
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C
C
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L
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d
f
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N
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.

8
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6
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C
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2
.
2
4

3
2
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3
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8
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3
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2
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N
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N
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6
1

0
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3
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A
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.
2
4

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1
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4
7
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5

4
4
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1
9
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6
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6

C
C
P
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W
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1
D

5
6
.
7
0

3
3
.
1
6

8
4
2
.
7
3

N
o
r
m
a
l

N
o
n
e

C
P

N
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A
3.
8
4

1
5
.
2
5

N
O

1
5
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3
1

4
4
5.3

3
.
4

4
5
9

8
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4
6
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6
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2
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1
6

C
C
P
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W
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2
S

4
4
.
0
7

3
6
.
1
3

8
0
6
.
1
1

N
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m
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N
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C
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N
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A
1.
3
0

4
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5
0

N
O

1
5
.
5
9

3
3
5.0

7
.
3

4
0
7

8
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3
1
4/
6
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2
0
1
6

C
C
P
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W
-
2
D

7
2
.
4
7

3
7
.
1
3

8
0
5
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2
5

N
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N
o
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C
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N
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5.
7
6

1
5
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5
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N
O

1
5
.
3
5

1
1
7
8.7

2
.
7

2
9
4

3
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9
7
4/
6
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2
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1
6

C
C
P
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3
S

1
5
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0
2

1
1
.
6
0

7
9
9
.
9
6

N
o
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N
o
n
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C
P

N
/
A
0.
5
6

2
.
2
5

N
O

1
5
.
2
7

6
3
5.0

2
.
6

4
9
6

2
.
6
6
4/
6
/
2
0
1
6

C
C
P
M
W
-
3
D

3
5
.
1
9

1
3
.
7
8

7
9
7
.
9
6

N
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m
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l

N
o
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C
P

N
/
A
3.
4
9

1
1
.
0
0

N
O

1
6
.
1
8

8
2
5.2

1
.
6

4
9
8

6
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3
6
4/
6
/
2
0
1
6

C
C
P
T
W
-
1
S

3
6
.
7
8

2
4
.
4
2

8
1
4
.
5
0

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A
2.
0
2

6
.
7
5

N
O

1
6
.
2
0

5
1
5.1

1
.
8

4
7
8

7
.
2
1
4/
6
/
2
0
1
6

C
C
P
T
W
-
1
D

6
8
.
2
3

2
5
.
8
3

8
1
2
.
7
0

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A
6.
9
2

1
0
.
0
0

Y
E
S

1
5
.
5
5

3
0
1
7.4

2
7
.
5

3
6
7

1
0
.
0
0
4/
6
/
2
0
1
6

C
C
P
T
W
-
2

4
7
.
6
3

3
9
.
5
7

8
0
2
.
6
1

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A
1.
3
1

4
.
5
0

N
O

1
6
.
0
1

8
2
5.0

4
.
4

4
7
8

6
.
9
3
4/
6
/
2
0
1
6

C
C
P
S
W
-
1

N
/
A
N/
A
N/
A
No
r
m
a
l

N
o
n
e

N
/
A
N/
A
N/
A
N/
A
N/
A
10
.
8
8

3
6
6.5

7
.
3

3
0
7

1
1
.
2
5
4/
6
/
2
0
1
6

C
C
P
S
W
-
2

N
/
A
N/
A
N/
A
No
r
m
a
l

N
o
n
e

N
/
A
N/
A
N/
A
N/
A
N/
A
12
.
7
6

3
8
6.4

8
.
7

2
7
7

1
1
.
1
6
4/
6
/
2
0
1
6

C
C
P
-
L
E
A
C
H
A
T
E

N
/
A
N/
A
N/
A
No
r
m
a
l

N
o
n
e

N
/
A
N/
A
N/
A
N/
A
N/
A
19
.
7
4

3
5
,
5
0
4

4
.
5

9
.
2

4
8
1

7
.
5
1
No
t
e
s
:

1
.

P
u
r
g
e

M
e
t
h
o
d
s
;

L
F
=
L
o
w

F
l
o
w
,

C
P
=
C
o
n
v
e
n
t
i
o
n
a
l

P
u
r
g
e

(
3
-
5

w
e
l
l

v
o
l
u
m
e
s
)
,

N
P
=
N
o

P
u
r
g
e

(
H
y
d
r
a
S
l
e
e
v
e
)
,

E
O
P
=
E
q
u
i
p
m
e
n
t

O
n
l
y

P
u
r
g
e
.

A
v
e
r
a
g
e

p
u
m
p

r
a
t
e

a
p
p
l
i
c
a
b
l
e

t
o

L
F

p
u
r
g
i
n
g

o
n
l
y
.

2
.

F
i
e
l
d

s
a
m
p
l
i
n
g

p
e
r
f
o
r
m
e
d

b
y

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

p
e
r
s
o
n
n
e
l
.

3
.

E
V
A
C

i
n
d
i
c
a
t
e
s

w
h
e
t
h
e
r

t
h
e

w
a
t
e
r

l
e
v
e
l

i
n

t
h
e

w
e
l
l

w
a
s

d
r
a
w
n

d
o
w
n

t
o

t
h
e

l
e
v
e
l

o
f

t
h
e

p
u
m
p

d
u
r
i
n
g

p
u
r
g
i
n
g
.

4
.

µ
Լ /c
m

i
n
d
i
c
a
t
e
s

m
i
c
r
o
m
h
o
s

p
e
r

c
e
n
t
i
m
e
t
e
r
.

5
.

S
U

i
n
d
i
c
a
t
e
s

S
t
a
n
d
a
r
d

U
n
i
t
s
.

6
.

N
T
U

i
n
d
i
c
a
t
e
s

N
e
p
h
e
l
o
m
e
t
r
i
c

T
u
r
b
i
d
i
t
y

U
n
i
t
s
.

7
.

m
V
-
N
H
E

i
n
d
i
c
a
t
e
s

m
i
l
l
i
v
o
l
t
s
-
N
o
r
m
a
l

H
y
d
r
o
g
e
n

E
l
e
c
t
r
o
d
e
.

8
.

m
g
/
L

i
n
d
i
c
a
t
e
s

m
i
l
l
i
g
r
a
m
s

p
e
r

l
i
t
e
r
.

9
.

N
/
A

i
n
d
i
c
a
t
e
s

n
o
t

a
p
p
l
i
c
a
b
l
e
.
10
.

I
n
f
o
r
m
a
t
i
o
n

p
r
o
v
i
d
e
d

b
y

T
i
m

H
u
n
s
u
c
k
e
r

o
f

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

o
n

M
a
y

4
,

2
0
1
6
.
AP
P
E
A
R
A
N
C
E
DA
T
E

S
A
M
P
L
E

I
D
WE
L
L
DE
P
T
H
(fe
e
t
)
DE
P
T
H

T
O
WA
T
E
R
(f
e
e
t
)
WA
T
E
R
EL
E
V
.
(f
e
e
t
)
DO (mg/L)
OD
O
R
PU
R
G
E
ME
T
H
O
D

AV
E
R
A
G
E
PU
M
P

R
A
T
E
(m
L
/
m
i
n
)
WE
L
L
VO
L
U
M
E
(g
a
l
)
EV
A
C
VO
L
U
M
E
(g
a
l
)
EV
A
C
(Y
E
S
/
N
O
)
TE
M
P
(d
e
g

C
)
SP
E
C
I
F
I
C
CO
N
D
U
C
T
A
N
C
E
(µ
Լ /c
m
)
pH
(S
U
)
TURBIDITY (NTU)ORP (mV-NHE) Page 1 of 1
Ta
b
l
e

4

-
-

G
r
o
u
n
d
w
a
t
e
r

F
i
e
l
d

a
n
d

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C
/
R
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g
e
r
s

E
n
e
r
g
y

C
o
m
p
l
e
x
C
C
P

L
a
n
d
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l
l
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P
h
a
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I

-
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m
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t

N
o
.

8
1
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l
d

p
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32
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1
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6
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.
5
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l
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p
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c
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c

C
o
n
d
u
c
t
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v
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t
y
32
3

µ
Լ /cm

5
1
9
3
-
NE

N
E

N
E
Te
m
p
e
r
a
t
u
r
e

3
2
5

°
C

5
1
9
3
-
NE

N
E

N
E
To
p

o
f

C
a
s
i
n
g
32
8

f
e
e
t
-
-
NE
NE NE
De
p
t
h

t
o

W
a
t
e
r
31
8

f
e
e
t
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-
NE
NE NE
Wa
t
e
r

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l
e
v
a
t
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n
31
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f
e
e
t
-
-
NE
NE NE
We
l
l

D
e
p
t
h
41
1

f
e
e
t
-
-
NE
NE NE
Ar
s
e
n
i
c
14

µ
g
/
L

2
4
8
0.3
5
2
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0.0
7
8

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0
.
0
7
8

U

0
.
8
1
3
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0.0
7
8

U

0
.
0
7
8

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0
.
0
7
8

1
0
10 10
Ba
r
i
u
m
15

µ
g
/
L

2
4
8
40
.
6
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14
.
9
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22
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7
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7.7
4
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30
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2
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1

1
0
0

7
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2
,
0
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0
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r
o
n

4
2
8

µ
g
/
L

2
4
8

8
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8
1
J
6.
6
8
J
7.5
9
J
6.9
3
J
26
.
6
J
11
.
1
J
3.
3

N
E
700 NE
Ca
d
m
i
u
m
34

µ
g
/
L

2
4
8
0.1
0
1

U

0
.
1
0
1

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0
.
1
0
1

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0
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1
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1

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1
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0
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1
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1
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l
o
r
i
d
e
45
5

µ
g
/
L

2
4
8
3,7
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5,2
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4,
6
0
0
4,
4
2
0
5,6
5
0
6,
5
4
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2
2

N
E
250,000

2
5
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,
0
0
0
*
Ch
r
o
m
i
u
m
51

µ
g
/
L

2
4
8
3.2
6
J '
0.4
9
9
J
1.0
4
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0.4
4
9
J
0.5
9
9
J
1.3
6
J '
0.0
6
1

1
0

1
0

1
0
0
Co
p
p
e
r
54

µ
g
/
L

2
4
8
4.1
4
J
1

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1
.
6
6
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1

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1

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1
10
1,000

1
,
3
0
0
Flu
o
r
i
d
e
31
2

µ
g
/
L

2
4
8
17

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18
J
17

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53
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21
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22
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2
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0
0
0

2
,
0
0
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4
,
0
0
0
Ir
o
n

3
4
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µ
g
/
L

2
4
8
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2
0
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.
6
J '
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4
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62
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7.2
9
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3

3
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0
300 300*
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a
d
13
1

µ
g
/
L

2
4
8
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J '
0.0
6
5

U

0
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1
4
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5

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0
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1
2
9
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0
6
5

U

0
.
0
6
5

1
0
15 15
Ma
n
g
a
n
e
s
e
34
2

µ
g
/
L

2
4
8
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.
2
12
.
8
J '
12
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8
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3
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53
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1
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0.
2

5
0

5
0

5
0
*
Me
r
c
u
r
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1
3
2

µ
g
/
L

2
4
8

0
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0
3
3
4

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0
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0
3
3
4

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0
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0
3
3
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0
3
3
4

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0
3
3
4

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0
3
3
4

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0
.
0
3
3
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0
.
2

1

2
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k
e
l

1
5
2

µ
g
/
L

2
4
8

1
.
8
8
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0
8
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0.
5
3
7
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9
4

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0
.
4
3
4
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0.
2
3
4
J
0.1
9
4

5
0
100 NE
Ni
t
r
a
t
e

a
s

N
i
t
r
o
g
e
n

3
0
3

µ
g
/
L

2
4
8
18
.
3
J
64
4
J '
50
0
J '
97
6
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1,0
5
0
J '
1,
2
8
0
J '
5.
4

1
0
,
0
0
0

1
0
,
0
0
0

1
0
,
0
0
0
Se
l
e
n
i
u
m

1
8
3

µ
g
/
L

2
4
8

0
.
1
1
5
J
0.0
9
6
J
0.
0
9
2

U

0
.
1
3
5
J
0.1
3
2
J
0.
1
9
6
J
0.0
9
2

1
0
20 50
Si
l
v
e
r
18
4

µ
g
/
L

2
4
8
0.
7

U
0.7

U
0.
7

U
0.
7

U
0.7

U
0.
7

U

0
.
7

1
0
20 100*
Su
l
f
a
t
e
31
5

µ
g
/
L

2
4
8
24
8
J '
1,1
9
0
J '
30
2
J '
4,3
4
0
J '
7,1
0
0
J '
11
,
7
0
0
J '
18

2
5
0
,
0
0
0

2
5
0
,
0
0
0

2
5
0
,
0
0
0
*
To
t
a
l

D
i
s
s
o
l
v
e
d

S
o
l
i
d
s
31
1

µ
g
/
L

2
4
8

1
6
,
7
0
0

U

2
6
,
0
0
0

2
4
,
0
0
0
J
84
,
0
0
0

4
0
,
0
0
0

4
4
,
0
0
0

1
6
,
7
0
0

N
E
500,000 500,000*
Zin
c
21
3

µ
g
/
L

2
4
8
8.
9
J '
3.
2
8
J
3.2
4
J
2.
6

U
2.6

U
2.
6

U

2
.
6

1
0
1,000 5,000*
No
t
e
s
:
1
.

C
o
n
c
e
n
t
r
a
t
i
o
n
s

p
r
e
s
e
n
t
e
d

i
n

m
i
c
r
o
g
r
a
m
s

p
e
r

l
i
t
e
r

(
µ
g
/
L
)
.
2
.

S
W
S

I
D

i
s

t
h
e

S
o
l
i
d

W
a
s
t
e

S
e
c
t
i
o
n

I
d
e
n
t
i
f
i
c
a
t
i
o
n

N
u
m
b
e
r
.
3
.

M
D
L

i
s

t
h
e

l
a
b
o
r
a
t
o
r
y

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.

T
h
e

M
D
L

v
a
l
u
e
s

p
r
e
s
e
n
t
e
d

a
r
e

f
o
r

s
a
m
p
l
e
s

n
o
t

d
i
l
u
t
e
d

b
y

t
h
e

l
a
b
o
r
a
t
o
r
y

d
u
r
i
n
g

a
n
a
l
y
s
i
s
.

4
.

S
W
S
L

i
s

t
h
e

S
o
l
i
d

W
a
s
t
e

S
e
c
t
i
o
n

L
i
m
i
t
.

N
C
D
E
Q

d
e
f
i
n
e
s

t
h
e

S
W
S
L

a
s

t
h
e

l
o
w
e
s
t

a
m
o
u
n
t

o
f

a
n
a
l
y
t
e

i
n

a

s
a
m
p
l
e

t
h
a
t

c
a
n

b
e

q
u
a
n
t
i
t
a
t
i
v
e
l
y

d
e
t
e
r
m
i
n
e
d

w
i
t
h

s
u
i
t
a
b
l
e

p
r
e
c
i
s
i
o
n

a
n
d

a
c
c
u
r
a
c
y
.

5
.

1
5
A

N
C
A
C

2
L

S
t
a
n
d
a
r
d

r
e
f
e
r
s

t
o

C
l
a
s
s

G
A

S
t
a
n
d
a
r
d
s

a
s

f
o
u
n
d

i
n

1
5
A

N
C
A
C

0
2
L

.
0
2
0
2

G
r
o
u
n
d
w
a
t
e
r

Q
u
a
l
i
t
y

S
t
a
n
d
a
r
d
s
,

l
a
s
t

a
m
e
n
d
e
d

o
n

A
p
r
i
l

1
,

2
0
1
3
.

6
.

M
C
L

i
s

t
h
e

F
e
d
e
r
a
l

M
a
x
i
m
u
m

C
o
n
t
a
m
i
n
a
n
t

L
e
v
e
l

a
s

f
o
u
n
d

i
n

4
0

C
F
R
,

S
u
b
p
a
r
t

G
,

§
1
4
1
.
6
2
.
7
.

*

C
o
n
c
e
n
t
r
a
t
i
o
n

l
i
s
t
e
d

i
s

a

s
e
c
o
n
d
a
r
y

m
a
x
i
m
u
m

c
o
n
t
a
m
i
n
a
n
t

l
e
v
e
l

(
S
M
C
L
)
.

S
M
C
L
s

a
r
e

e
s
t
a
b
l
i
s
h
e
d

b
y

E
P
A

i
n

t
h
e

N
a
t
i
o
n
a
l

S
e
c
o
n
d
a
r
y

D
r
i
n
k
i
n
g

W
a
t
e
r

R
e
g
u
l
a
t
i
o
n
s
.
8
.

N
E

i
n
d
i
c
a
t
e
s

n
o
t

e
s
t
a
b
l
i
s
h
e
d
.

N
A

i
n
d
i
c
a
t
e
s

n
o
t

a
n
a
l
y
z
e
d
.

B
l
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

t
h
a
t

t
h
e
r
e

i
s

n
o

i
n
f
o
r
m
a
t
i
o
n

r
e
l
e
v
a
n
t

t
o

t
h
e

r
e
s
p
e
c
t
i
v
e

r
o
w
.
9
.

N
S

i
n
d
i
c
a
t
e
s

n
o

s
a
m
p
l
e

w
a
s

c
o
l
l
e
c
t
e
d
.

10
.

G
r
a
y
e
d

v
a
l
u
e
s

i
n
d
i
c
a
t
e

v
a
l
u
e
s

t
h
a
t

e
q
u
a
l

o
r

a
r
e

g
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Page 1 of 1
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Page 1 of 1

A
Appendix A
Field Sampling Forms

ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬▬►0.0 0.0 ▬/▬►0.0
SS 344.0 ▬▬►350 347.6 ▬/▬►350
SS 73.4 ▬/▬►75 74.2 ▬/▬►75
SS ▬/▬►1410 ▬/▬►1410
B (7.00)7.09 ▬▬►7.02 6.97 ▬/▬►7.02
B (4.00)4.05 ▬▬►4.00 4.01 ▬/▬►4.00
B (10.00)10.13 ▬/▬►10.06 10.14 ▬/▬►10.06
20.13 19.90
pH Check B (7.00)▬▬►0.00
Time:0.00
438 ▬▬►441 437 ▬/▬►441
N/A ▬/▬►N/A N/A ▬/▬►N/A
Zobell's 20.15 19.81
TEMP (CO)
BP (mmHg)
COND
100 % mg/L 9.11 ▬▬►9.12 8.95 ▬/▬►8.94
After Cal 9.12 99.99 8.92 99.77
LCS 9.11 99.88 8.92 99.77
LCSD 9.11 0.00 8.91 -0.11
SS 54.8 ▬/▬►56.0 ▬/▬►56.0
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
FIELD SAMPLING CALIBRATION FORM
STUDY:CLIFFSIDE STEAM STATION - CCP LANDFILL GROUNDWATER MONITORING
DATE (s):April 6, 2016 SURFACE UNIT READER:LDC
OTHER EQUIPMENT:TURBIDIMETER NO.2 - 3260-GW Mostly clear, slight breeze, 40 to 55 deg F
COLLECTORS:LDC, PSP, HET SURFACE UNIT SERIAL #:0662
ANALYZER MODEL#:HL4 400437
Calibration Date / Time 6-Apr-16 430 7-Apr-16 915
PROCEDURE #:HYDROLAB 3210.5 VALIDATED BY:
Parameter Calibration Results Calibration Results
CALIBRATION BP (mmHg)750.70 CALIBRATION BP (mmHg)735.49
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
INSTRUMENT ZEROED INSTRUMENT ZEROED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.Buffer Temp.
ORP Temp.ORP Temp.
ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.
99.8
CALIBRATION PASS CALIBRATION PASS
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
After Cal % SAT After Cal % SAT
TURB
(ntu)CALIBRATION ACCEPTED
CALIBRATION PASS CALIBRATION PASS
DO
(mg/L)
19.20 19.15
750.70 735.49
93
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 751.7 (mmHg)Ending BP 748.7
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬▬►0.0 0.0 ▬/▬►0.0
SS 345.6 ▬▬►350 347.6 ▬/▬►350
SS 73.6 ▬/▬►75 76.1 ▬/▬►75
SS ▬/▬►1410 ▬/▬►1410
B (7.00)7.09 ▬▬►7.02 7.01 ▬/▬►7.02
B (4.00)4.13 ▬▬►4.00 4.02 ▬/▬►4.00
B (10.00)10.05 ▬/▬►10.06 10.06 ▬/▬►10.06
20.27 20.06
pH Check B (7.00)▬▬►0.00
Time:0.00
440 ▬▬►440 439 ▬/▬►441
N/A ▬/▬►N/A N/A ▬/▬►N/A
Zobell's 20.25 19.92
TEMP (CO)
BP (mmHg)
COND
100 % mg/L 9.08 ▬▬►9.11 8.94 ▬/▬►8.93
After Cal 9.13 ▬/▬►100.18 8.94 100.07
LCS 9.11 ▬/▬►99.97 8.94 100.07
LCSD 9.12 ▬/▬►0.11 8.93 -0.11
SS 53.6 ▬/▬►53.5 54.9 ▬/▬►53.5
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 751.7 (mmHg)Ending BP 748.7
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
TURB
(ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION PASS CALIBRATION PASS
DO
(mg/L)
19.24 19.19
750.70 735.49
98
CALIBRATION PASS CALIBRATION PASS
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
After Cal % SAT After Cal % SAT
98.9
ORP Temp.ORP Temp.
ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.Buffer Temp.
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
INSTRUMENT ZEROED INSTRUMENT ZEROED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Parameter Calibration Results Calibration Results
CALIBRATION BP (mmHg)750.70 CALIBRATION BP (mmHg)735.49
Calibration Date / Time 6-Apr-16 405 7-Apr-16 845
PROCEDURE #:HYDROLAB 3210.5 VALIDATED BY:
FIELD SAMPLING CALIBRATION FORM
STUDY:CLIFFSIDE STEAM STATION - CCP LANDFILL GROUNDWATER MONITORING
DATE (s):April 6, 2016 SURFACE UNIT READER:PSP
OTHER EQUIPMENT:TURBIDIMETER NO.1 - 3260-GW Mostly clear, slight breeze, 40 to 55 deg F
COLLECTORS:LDC, PSP, HET SURFACE UNIT SERIAL #:0722
ANALYZER MODEL#:HL4 400440
32.24 42.24
18 (psi)10 (sec)(sec)
(gal)
896 (ml)
495 (ml)
1391 (ml)=0.37 (gal)@
QC By:Sample preservation verified to pH
(units)< 2.0
SAMPLING NOTES
Try low flow next sampling round if well volume is about 1.5 gal.
ADDITIONAL WELL CONDITION NOTES
NA
Pump (Bladder) Volume
Tubing Volume
Total Purge Volume
447 9.19 N/A
EQUIPMENT PURGE ONLY SAMPLE CHLORINE
(mg/l)SAMPLE COLLECTED BYRemoved 0.5 gal.
32.38 450
WATER LEVEL RATE WATER LEVEL COND.
LDC
WELL CONDITION
PROTECTIVE CASING
WELL PAD
WELL TAG
Good Condition
Minor Cracks
4.77 47.5
Good Condition
Good Tag
WELL CASING
33.02 15.24 21
(ft)(ml/min)(ft)(deg C)(umho/cm)(SU)
OXYGEN
INITIAL FLOW FINAL TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
SAMPLING EQUIPMENT
TUBING DIAMETER (in)1/2 OD
QED T1200
WATER ELEVATION (ft msl)843.20
APPEARANCE
DETECTED ODOR None
Normal
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88
WELL DEPTH (ft TOC)
WELL DIAMETER (in)MIDDLE OF WETTED SCREEN (ft toc)
SCREEN INTERVAL (ft TOC)TO
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)32.38 WATER COLUMN (ft)9.86
EQUIPMENT INFORMATION
LEVEL METER SERIAL#28651
41.24PUMP INTAKE DEPTH (ft TOC)42.24
TOC ELEV (ft msl)
GS ELEV (ft msl)
875.58
873.24
WELL/LOCATION NAME CCPMW-1S
FIELD CREW LDC, PSP, HET
MONITORING WELL INFORMATION
2
N/A
PROCEDURE NO 3175.3DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
FOR EQUIPMENT PURGE ONLY SAMPLING
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID
PROJECT NAME CLIFFSIDE CCP LANDFILL
SAMPLING DATE(s)6-Apr-2016
37.31
PURGE METHOD
Equip. Only Purge
DISCHARGERECHARGEPRESSURE 10
PUMP CONTROLLER SETTINGS
0.1631CONVERSION FACTOR
Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
1.61WELL VOLUME
4/6/2016 1140
DATE TIME
(mg/L)(NTU)(mV -NEH)
51.70 56.70
38 (psi)9 (sec)(sec)
(gal)
3.84 (gal)
@
QC By:
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME CCPMW-1D
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)875.89 MIDDLE OF WETTED SCREEN (ft toc)54.20
SCREEN LENGTH (ft)5.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)56.70 GS ELEV (ft msl)873.33 PUMP INTAKE DEPTH (ft TOC)55.70
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 6
28651 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)33.16 WATER COLUMN (ft)23.54 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)842.73 WELL VOLUME 3.84
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
4.00 34.68 NO 15.07 46 5.12 3.3 444
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
7.97 3.59
3.75 NO 15.30 43 5.30 4.6 457 8.44
3.75 NO 15.29 43 5.25 2.9 451 8.36
3.75 NO 15.31 44 5.34 3.4 459 8.46
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
15.25 LDC 4/6/2016 1235 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
34.07 44.07
20 (psi)10 (sec)(sec)
(gal)
1.30 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
4.50 LDC 4/6/2016 0830 N/A
1.50 NO 15.59 33 5.04 7.3 407 8.31
1.50 NO 15.58 33 4.98 4.8 425 8.33
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.50 NO 15.48 33 4.96 15.1 414
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
8.36
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)36.13 WATER COLUMN (ft)7.94 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)806.11 WELL VOLUME 1.30
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
28651 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)842.24 MIDDLE OF WETTED SCREEN (ft toc)40.10
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)44.07 GS ELEV (ft msl)840.26 PUMP INTAKE DEPTH (ft TOC)43.07
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME CCPMW-2S
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
67.47 72.47
40 (psi)10 (sec)(sec)
(gal)
5.76 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
15.50 LDC 4/6/2016 0930 N/A
2.25 NO 15.35 117 8.71 2.7 294 3.97
2.25 NO 15.31 118 8.84 2.7 287 3.85
2.13
2.25 59.67 NO 15.22 120 8.98 2.9 268 3.68 2.09
2.75 59.41 NO 15.24 127 9.24 2.7 253 3.40
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
6.00 56.64 NO 15.19 140 9.62 3.1 261
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
2.15 2.58
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)37.13 WATER COLUMN (ft)35.34 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)805.25 WELL VOLUME 5.76
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
28651 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)842.38 MIDDLE OF WETTED SCREEN (ft toc)69.97
SCREEN LENGTH (ft)5.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)72.47 GS ELEV (ft msl)840.17 PUMP INTAKE DEPTH (ft TOC)71.47
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME CCPMW-2D
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
10.02 15.02
8 (psi)10 (sec)(sec)
(gal)
0.56 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
2.25 PSP, HET 4/6/2016 1110 N/A
0.75 NO 15.27 63 4.98 2.6 496 2.66
0.75 NO 15.18 63 4.98 3.2 492 2.71
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
0.75 NO 15.14 63 4.98 5.1 485
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
3.72
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)11.60 WATER COLUMN (ft)3.42 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)799.96 WELL VOLUME 0.56
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)811.56 MIDDLE OF WETTED SCREEN (ft toc)13.31
SCREEN LENGTH (ft)5.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)15.02 GS ELEV (ft msl)810.56 PUMP INTAKE DEPTH (ft TOC)14.02
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME CCPMW-3S
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
30.19 35.19
20 (psi)10 (sec)(sec)
(gal)
3.49 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
11.00 PSP, HET 4/6/2016 1155 N/A
3.50 NO 16.18 82 5.22 1.6 498 6.36
3.50 NO 16.17 82 5.22 1.6 493 6.25
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
4.00 NO 16.19 83 5.22 2.1 487
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
5.97
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)13.78 WATER COLUMN (ft)21.41 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)797.96 WELL VOLUME 3.49
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)811.74 MIDDLE OF WETTED SCREEN (ft toc)32.69
SCREEN LENGTH (ft)5.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)35.19 GS ELEV (ft msl)810.47 PUMP INTAKE DEPTH (ft TOC)34.18
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME CCPMW-3D
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
53.33 68.33
35 (psi)10 (sec)(sec)
(gal)
7.20 (gal)
@
QC By:
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME CCPMW-4
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)845.95 MIDDLE OF WETTED SCREEN (ft toc)60.83
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)68.33 GS ELEV (ft msl)843.29 PUMP INTAKE DEPTH (ft TOC)67.33
Well evacuated 1440 hrs on 4/6/2016 PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
7.20
DETECTED ODOR H2S CONVERSION FACTOR 0.1631
APPEARANCE Turbid
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)24.19 WATER COLUMN (ft)44.14 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)821.76 WELL VOLUME
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
7.25 61.50 NO 15.38 214 10.17 303.0 -318
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
0.00 1.11
1.25 YES 15.98 202 10.14 303.0 -188 0.28
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
8.50 PSP, HET 4/6/2016 1530 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
Sample preservation verified to pH
(units)< 2.0
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
Could not stabilize at 53 feet pumping 60 ml/min on 25 psi 25 and 5 or 5 and 25. water level before sampling was 64.35 feet below TOC.
65.40 75.40
40 (psi)10 (sec)(sec)
(gal)
5.86 (gal)
@
QC By:
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME CCPMW-5
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)858.63 MIDDLE OF WETTED SCREEN (ft toc)70.40
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)75.40 GS ELEV (ft msl)855.87 PUMP INTAKE DEPTH (ft TOC)74.40
Well evacuated @ 1320 hrs, on 4/6/2016 PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
5.86
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)39.47 WATER COLUMN (ft)35.93 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)819.16 WELL VOLUME
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
6.00 69.72 NO 15.57 177 10.39 5.7 225
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
3.47 0.93
0.54
0.75 YES 15.82 162 9.94 13.4 237 1.37
1.00 72.07 NO 15.66 183 10.05 11.6 240 0.93
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
7.75 PSP, HET 4/6/2016 1515 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
Sample preservation verified to pH
(units)< 2.0
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
Could not stabilize at 67 feet pumping at 40 ml/min, on 30 psi 10 and 20, played with settings and still could not stabilize draw down. Evacuated well to return to sample later.
Water level before sampling was 69.54 feet below TOC.
36.73 46.73
20 (psi)10 (sec)(sec)
(gal)
@
QC By:
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME CCPMW-6S
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)854.38 MIDDLE OF WETTED SCREEN (ft toc)41.73
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)46.73 GS ELEV (ft msl)851.48 PUMP INTAKE DEPTH (ft TOC)45.73
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
28651 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
2.18
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)33.37 WATER COLUMN (ft)13.36 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)821.01 WELL VOLUME
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
10:05 33.64 276 15.47 61 5.13 68.2 434 5.99 N/A
10:00 33.64 276 15.39 74 5.12 86.5 429 6.48
N/A
10:15 33.64 276 15.41 61 5.16 27.4 436 5.17 N/A
10:10 33.64 276 15.46 62 5.13 36.8 435 5.63
N/A
10:25 33.64 276 15.44 62 5.19 14.5 439 4.86 N/A
10:20 33.64 276 15.48 68 5.18 19.3 438 4.96
N/A
10:35 33.64 276 15.40 64 5.20 9.7 441 5.01 N/A
10:30 33.64 276 15.40 66 5.18 12.4 440 5.12
DRAW-DOWN 0.27 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.75 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 3.35 (gal)LDC 4/6/2016 1040 NA
Sample preservation verified to pH
(units)< 2.0
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
53.08 63.08
30 (psi)13 (sec)(sec)
(gal)
@
QC By:
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME CCPMW-6D
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)854.35 MIDDLE OF WETTED SCREEN (ft toc)58.08
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)63.08 GS ELEV (ft msl)851.45 PUMP INTAKE DEPTH (ft TOC)62.08
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 7
28651 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
4.85
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)33.35 WATER COLUMN (ft)29.73 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)821.00 WELL VOLUME
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
10:45 33.38 291 15.72 86 5.57 3.9 426 7.24 N/A
10:40 33.38 291 15.72 91 5.60 3.0 425 7.09
N/A
10:55 33.38 291 15.80 85 5.52 2.5 426 7.47 N/A
10:50 33.38 291 15.72 89 5.54 2.4 426 7.43
DRAW-DOWN 0.03 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 3.50 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 4.70 (gal)LDC 4/6/2016 1100 NA
Sample preservation verified to pH
(units)< 2.0
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
26.78 36.78
18 (psi)10 (sec)(sec)
(gal)
2.02 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
6.75 PSP, HET 4/6/2016 0950 N/A
2.50 NO 16.20 51 5.09 1.8 478 7.21
2.00 NO 16.16 51 5.10 2.8 491 7.42
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
2.25 NO 16.21 51 5.10 5.4 473
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
7.41
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)24.42 WATER COLUMN (ft)12.36 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)814.50 WELL VOLUME 2.02
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)838.92 MIDDLE OF WETTED SCREEN (ft toc)31.78
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)36.78 GS ELEV (ft msl)836.81 PUMP INTAKE DEPTH (ft TOC)35.78
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME CCPTW-1S
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
63.23 68.23
35 (psi)10 (sec)(sec)
(gal)
6.92 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
10.00 PSP, HET 4/6/2016 1010 N/A
0.25 YES 15.55 301 7.39 27.5 367 10.00
0.75 NO 15.55 350 7.37 12.7 352 6.20
0.62
0.75 NO 16.22 354 7.41 5.3 379 1.17
1.25 64.41 NO 16.23 302 7.55 3.3 373 5.65
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
7.00 61.23 NO 16.31 252 7.71 2.6 374
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
8.87 1.14
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)25.83 WATER COLUMN (ft)42.40 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)812.70 WELL VOLUME 6.92
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)838.53 MIDDLE OF WETTED SCREEN (ft toc)65.73
SCREEN LENGTH (ft)5.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)68.23 GS ELEV (ft msl)836.41 PUMP INTAKE DEPTH (ft TOC)67.23
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME CCPTW-1D
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
37.63 47.63
22 (psi)10 (sec)(sec)
(gal)
1.31 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
4.50 PSP, HET 4/6/2016 0825 N/A
1.50 NO 16.01 82 4.98 4.4 478 6.93
1.50 NO 16.02 82 4.98 5.7 470 6.96
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.50 NO 15.98 81 4.96 1.9 453
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
6.95
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)39.57 WATER COLUMN (ft)8.06 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)802.61 WELL VOLUME 1.31
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 20
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)842.18 MIDDLE OF WETTED SCREEN (ft toc)43.60
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)47.63 GS ELEV (ft msl)839.62 PUMP INTAKE DEPTH (ft TOC)46.63
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME CCPTW-2
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
0.00 0.00
(psi)(sec)(sec)
(gal)
(ft)=(in)@
QC By:
SAMPLING NOTES
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
1305
307 11.25
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 10.88 36 6.48 7.3
TIME
LDC 4/6/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
DETECTED ODOR CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE
N/A SAMPLING EQUIPMENT GRAB PURGE METHOD
TUBING DIAMETER (in)No Purge
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME CCPSW-1
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
0.00 0.00
(psi)(sec)(sec)
(gal)
(ft)=(in)@
QC By:
SAMPLING NOTES
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
1500
277 11.16
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 12.76 38 6.42 8.7
TIME
LDC 4/6/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
DETECTED ODOR CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME CCPSW-2
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
0.00 0.00
(psi)(sec)(sec)
(gal)
(ft)=(in)@
QC By:
SAMPLING NOTES
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
1405
481 7.51
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 19.74 35504 4.49 9.2
TIME
LDC 4/6/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE
N/A SAMPLING EQUIPMENT GRAB PURGE METHOD
TUBING DIAMETER (in)No Purge
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)6-Apr-2016 WELL/LOCATION NAME CCP-LEACHATE
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PERMIT #
CCPMW-1S CCPMW-1D CCPMW-2S CCPMW-2D CCPMW-3S CCPMW-3D CCPMW-4 CCPMW-5 CCPMW-6S CCPMW-6D CCPTW-1S CCPTW-1D CCPTW-2 CCPSW-1 CCPSW-2 LEACHATE
YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A N/A N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A N/A N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A N/A N/A
YES YES YES YES YES YES YES YES YES YES YES YES N/A N/A N/A
YES
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A N/A N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A N/A N/A
N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A N/A N/A
NORTH CAROLINA GROUNDWATER SAMPLING SITE CHECKLIST
LOCATION / SITE CLIFFSIDE STEAM STATION - CCP LANDFILL GROUNDWATER MONITORING 81-06 SAMPLE DATE April 6, 2016
SITE CONTACT Steve Hodges FIELD CREW LDC, PSP, HET
WEATHER Mostly clear, slight breeze, 40 to 55 deg F.
WELL LOCK CONDITION
PAGE 1 OF 1
ACCESS TO WELLS
Access cleared into well
Access cleared around well
Tall grass or weeds - needs mowing
Road washing out / muddy / needs grading
Fallen tree blocking access
WELL SECURITY
Well found locked
Well found unlocked
Undermined / washing out
Lock in good condition
Lock rusted, difficult to open / needs replacing
Replaced damaged lock
WELL CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
CONCRETE PADS
Pad in good condition
Minor cracks
Major cracks / broken / repair required
Replaced damaged well cap
Fire ants around concrete pad
WELL PROTECTIVE CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
Broken hinge on protective lid
Wasp nest inside protective casing
Ants inside protective casing
WELL CAPS
Well cap in good conditon
Damaged / needs replacement
Lacks required information - Completion date
FLUSH MOUNT WELLS
Vault in good condition
Water inside vault
Vault bolt holes broken or stripped
Bolts stripped
Vault lid cracked or broken
WELL ID TAGS
Well tag in good condition
Well tag missing
Well tag damaged / illegible
Lacks required information - Driller Reg #
Lacks required information - Total well depth
Lacks required information - Depth to screen
Lacks required information - Non potable tag
NOTE:
WELL DEPTH TO WATER Purge AVG *WELL EVAC SPECIFIC
WELL DEPTH WATER ELEV.Method PMP RATE VOL VOL EVAC TEMP CONDUCTANCE pH TURBIDITY ORP DO
DATE NO.(feet-toc)(feet-toc)(feet)APPEARANCE ODOR (ml/min)(gal)(gal)(yes/no)(deg C)(umho/cm)(units)(NTU)(mV-NHE)(mg/l)
4/6/2016 CCPMW-1S 42.24 32.38 843.20 Normal None EOP N/A 1.61 0.37 N/A 15.24 21 4.8 47.5 447 9.19
4/6/2016 CCPMW-1D 56.70 33.16 842.73 Normal None C N/A 3.84 15.25 NO 15.31 44 5.3 3.4 459 8.46
4/6/2016 CCPMW-2S 44.07 36.13 806.11 Normal None C N/A 1.30 4.50 NO 15.59 33 5.0 7.3 407 8.31
4/6/2016 CCPMW-2D 72.47 37.13 805.25 Normal None C N/A 5.76 15.50 NO 15.35 117 8.7 2.7 294 3.97
4/6/2016 CCPMW-3S 15.02 11.60 799.96 Normal None C N/A 0.56 2.25 NO 15.27 63 5.0 2.6 496 2.66
4/6/2016 CCPMW-3D 35.19 13.78 797.96 Normal None C N/A 3.49 11.00 NO 16.18 82 5.2 1.6 498 6.36
4/6/2016 CCPMW-4 68.33 24.19 821.76 Turbid H2S C N/A 7.20 8.50 YES 15.98 202 10.1 303.0 -188 0.28
4/6/2016 CCPMW-5 75.40 39.47 819.16 Normal None C N/A 5.86 7.75 YES 15.82 162 9.9 13.4 237 1.37
4/6/2016 CCPMW-6S 46.73 33.37 821.01 Normal None LF 276 2.18 3.35 N/A 15.40 64 5.2 9.7 441 5.01
4/6/2016 CCPMW-6D 63.08 33.35 821.00 Normal None LF 291 4.85 4.70 N/A 15.80 85 5.5 2.5 426 7.47
4/6/2016 CCPTW-1S 36.78 24.42 814.50 Normal None C N/A 2.02 6.75 NO 16.20 51 5.1 1.8 478 7.21
4/6/2016 CCPTW-1D 68.23 25.83 812.70 Normal None C N/A 6.92 10.00 YES 15.55 301 7.4 27.5 367 10.00
4/6/2016 CCPTW-2 47.63 39.57 802.61 Normal None C N/A 1.31 4.50 NO 16.01 82 5.0 4.4 478 6.93
4/6/2016 CCPSW-1 N/A N/A N/A Normal ---NP N/A N/A N/A N/A 10.88 36 6.5 7.3 307 11.25
4/6/2016 CCPSW-2 N/A N/A N/A Normal ---NP N/A N/A N/A N/A 12.76 38 6.4 8.7 277 11.16
4/6/2016 CCP-LEACHATE N/A N/A N/A Normal None NP N/A N/A N/A N/A 19.74 35504 4.5 9.2 481 7.51
Purge Methods
LF = Low Flow
LF(M) = Low Flow (Mod.)
C = Connventional
NP = No Purge
EOP = Equip. Only Purge
LO = Level Only
* = Applicable to LF & LF(M) Purging Only
CLIFFSIDE STEAM STATION
CLIFFSIDE CCP LANDFILL
GROUNDWATER MONITORING FIELD DATA
PERMIT #81-06

B
Appendix B
Laboratory Report and
Chain-of-Custody Forms

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16030484
Project Name:CLIFFSIDE - GW CCP LANDFILL
Lab Contact: Peggy Kendall
Date:4/25/2016
Customer Address:573 Duke Power Rd
Customer Name(s):Chuck Campbell, TSH, SEAN DENEALE
Mail Code: Clliffside Steam Station
Mooresboro, NC 28024
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Peggy Kendall
Page 1 of 31
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016007824 CLIFFSIDE 06-Apr-16 11:40 AM LDC CCPMW-1S
2016007825 CLIFFSIDE 06-Apr-16 12:35 PM LDC CCPMW-1D
2016007826 CLIFFSIDE 06-Apr-16 8:30 AM LDC CCPMW-2S
2016007827 CLIFFSIDE 06-Apr-16 9:30 AM LDC CCPMW-2D
2016007828 CLIFFSIDE 06-Apr-16 11:10 AM PSP CCPMW-3S
2016007829 CLIFFSIDE 06-Apr-16 11:55 AM PSP CCPMW-3D
2016007830 CLIFFSIDE 06-Apr-16 3:30 PM PSP CCPMW-4
2016007831 CLIFFSIDE 06-Apr-16 3:15 PM PSP CCPMW-5
2016007832 CLIFFSIDE 06-Apr-16 10:40 AM LDC CCPMW-6S
2016007833 CLIFFSIDE 06-Apr-16 11:00 AM LDC CCPMW-6D
2016007834 CLIFFSIDE 06-Apr-16 9:50 AM PSP CCPTW-1S
2016007835 CLIFFSIDE 06-Apr-16 10:10 AM PSP CCPTW-1D
2016007836 CLIFFSIDE 06-Apr-16 8:25 AM PSP CCPTW-2
2016007837 CLIFFSIDE 06-Apr-16 1:05 PM LDC CCPSW-1
2016007838 CLIFFSIDE 06-Apr-16 3:00 PM LDC CCPSW-2
2016007839 CLIFFSIDE 06-Apr-16 2:05 PM LDC CCP Leachate
2016007840 CLIFFSIDE 06-Apr-16 3:35 PM PSP FIELD BLANK
17 Total Samples
Page 2 of 31
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:4/25/2016
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
2016007824
Collection Date:06-Apr-16 11:40 AM
Site:CCPMW-1S
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 04/08/2016 13:58 CJELLIO51
INORGANIC IONS BY IC
Chloride 3.8 mg/L EPA 9056A 04/07/2016 10:25 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/07/2016 10:25 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 04/07/2016 10:25 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 04/07/2016 10:25 BGN90340.023 1
Sulfate 0.25 mg/L EPA 9056A 04/07/2016 10:25 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/15/2016 11:37 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.041 mg/L SW 6010D 04/13/2016 21:21 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/13/2016 21:21 MHH71310.05 1
Calcium (Ca)0.147 mg/L SW 6010D 04/13/2016 21:21 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/13/2016 21:21 MHH71310.005 1
Iron (Fe)2.22 mg/L SW 6010D 04/13/2016 21:21 MHH71310.01 1
Magnesium (Mg)1.12 mg/L SW 6010D 04/13/2016 21:21 MHH71310.005 1
Manganese (Mn)0.051 mg/L SW 6010D 04/13/2016 21:21 MHH71310.005 1
Potassium (K)1.16 mg/L SW 6010D 04/13/2016 21:21 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/13/2016 21:21 MHH71310.005 1
Sodium (Na)1.38 mg/L SW 6010D 04/13/2016 21:21 MHH71310.05 1
Zinc (Zn)0.009 mg/L SW 6010D 04/13/2016 21:21 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 04/13/2016 17:17 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 04/13/2016 17:17 JAHERMA11
Chromium (Cr)3.26 ug/L SW 6020B 04/13/2016 17:17 JAHERMA11
Lead (Pb)1.10 ug/L SW 6020B 04/13/2016 17:17 JAHERMA11
Nickel (Ni)1.88 ug/L SW 6020B 04/13/2016 17:17 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 04/13/2016 17:17 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 04/11/2016 16:06 PARMSTR251
Page 4 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
2016007825
Collection Date:06-Apr-16 12:35 PM
Site:CCPMW-1D
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)6.5 mg/L
(CaCO3)
SM 2320B 04/08/2016 13:58 CJELLIO51
INORGANIC IONS BY IC
Chloride 5.3 mg/L EPA 9056A 04/07/2016 11:34 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/07/2016 11:34 BGN90340.1 1
Nitrate 2.9 mg/L EPA 9056A 04/07/2016 11:34 BGN90340.1 1
Nitrate as N 0.64 mg-N/L EPA 9056A 04/07/2016 11:34 BGN90340.023 1
Sulfate 1.2 mg/L EPA 9056A 04/07/2016 11:34 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/15/2016 11:54 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.015 mg/L SW 6010D 04/13/2016 21:25 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/13/2016 21:25 MHH71310.05 1
Calcium (Ca)3.09 mg/L SW 6010D 04/13/2016 21:25 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/13/2016 21:25 MHH71310.005 1
Iron (Fe)0.048 mg/L SW 6010D 04/13/2016 21:25 MHH71310.01 1
Magnesium (Mg)1.30 mg/L SW 6010D 04/13/2016 21:25 MHH71310.005 1
Manganese (Mn)0.013 mg/L SW 6010D 04/13/2016 21:25 MHH71310.005 1
Potassium (K)1.16 mg/L SW 6010D 04/13/2016 21:25 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/13/2016 21:25 MHH71310.005 1
Sodium (Na)2.19 mg/L SW 6010D 04/13/2016 21:25 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/13/2016 21:25 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 04/13/2016 17:01 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 04/13/2016 17:01 JAHERMA11
Chromium (Cr)< 1 ug/L SW 6020B 04/13/2016 17:01 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/13/2016 17:01 JAHERMA11
Nickel (Ni)1.08 ug/L SW 6020B 04/13/2016 17:01 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 04/13/2016 17:01 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 26 mg/L SM2540C 04/11/2016 16:06 PARMSTR251
Page 5 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
2016007826
Collection Date:06-Apr-16 8:30 AM
Site:CCPMW-2S
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 04/08/2016 13:58 CJELLIO51
INORGANIC IONS BY IC
Chloride 4.6 mg/L EPA 9056A 04/07/2016 12:19 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/07/2016 12:19 BGN90340.1 1
Nitrate 2.2 mg/L EPA 9056A 04/07/2016 12:19 BGN90340.1 1
Nitrate as N 0.50 mg-N/L EPA 9056A 04/07/2016 12:19 BGN90340.023 1
Sulfate 0.30 mg/L EPA 9056A 04/07/2016 12:19 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/15/2016 11:40 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.023 mg/L SW 6010D 04/13/2016 21:09 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/13/2016 21:09 MHH71310.05 1
Calcium (Ca)1.65 mg/L SW 6010D 04/13/2016 21:09 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/13/2016 21:09 MHH71310.005 1
Iron (Fe)0.165 mg/L SW 6010D 04/13/2016 21:09 MHH71310.01 1
Magnesium (Mg)0.875 mg/L SW 6010D 04/13/2016 21:09 MHH71310.005 1
Manganese (Mn)0.013 mg/L SW 6010D 04/13/2016 21:09 MHH71310.005 1
Potassium (K)1.62 mg/L SW 6010D 04/13/2016 21:09 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/13/2016 21:09 MHH71310.005 1
Sodium (Na)1.82 mg/L SW 6010D 04/13/2016 21:09 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/13/2016 21:09 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 04/13/2016 17:23 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 04/13/2016 17:23 JAHERMA11
Chromium (Cr)1.04 ug/L SW 6020B 04/13/2016 17:23 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/13/2016 17:23 JAHERMA11
Nickel (Ni)< 1 ug/L SW 6020B 04/13/2016 17:23 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 04/13/2016 17:23 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 04/11/2016 16:06 PARMSTR251
Page 6 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
2016007827
Collection Date:06-Apr-16 9:30 AM
Site:CCPMW-2D
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)43 mg/L
(CaCO3)
SM 2320B 04/08/2016 13:58 CJELLIO51
INORGANIC IONS BY IC
Chloride 4.4 mg/L EPA 9056A 04/07/2016 12:42 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/07/2016 12:42 BGN90340.1 1
Nitrate 4.3 mg/L EPA 9056A 04/07/2016 12:42 BGN90340.1 1
Nitrate as N 0.98 mg-N/L EPA 9056A 04/07/2016 12:42 BGN90340.023 1
Sulfate 4.3 mg/L EPA 9056A 04/07/2016 12:42 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/15/2016 11:42 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.008 mg/L SW 6010D 04/13/2016 21:29 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/13/2016 21:29 MHH71310.05 1
Calcium (Ca)16.3 mg/L SW 6010D 04/13/2016 21:29 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/13/2016 21:29 MHH71310.005 1
Iron (Fe)0.010 mg/L SW 6010D 04/13/2016 21:29 MHH71310.01 1
Magnesium (Mg)0.647 mg/L SW 6010D 04/13/2016 21:29 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 04/13/2016 21:29 MHH71310.005 1
Potassium (K)2.62 mg/L SW 6010D 04/13/2016 21:29 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/13/2016 21:29 MHH71310.005 1
Sodium (Na)5.24 mg/L SW 6010D 04/13/2016 21:29 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/13/2016 21:29 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 04/13/2016 17:28 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 04/13/2016 17:28 JAHERMA11
Chromium (Cr)< 1 ug/L SW 6020B 04/13/2016 17:28 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/13/2016 17:28 JAHERMA11
Nickel (Ni)< 1 ug/L SW 6020B 04/13/2016 17:28 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 04/13/2016 17:28 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 84 mg/L SM2540C 04/11/2016 16:06 PARMSTR251
Page 7 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
2016007828
Collection Date:06-Apr-16 11:10 AM
Site:CCPMW-3S
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 04/08/2016 13:58 CJELLIO51
INORGANIC IONS BY IC
Chloride 5.7 mg/L EPA 9056A 04/07/2016 13:05 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/07/2016 13:05 BGN90340.1 1
Nitrate 4.7 mg/L EPA 9056A 04/07/2016 13:05 BGN90340.126 1.26
Nitrate as N 1.1 mg-N/L EPA 9056A 04/07/2016 13:05 BGN90340.023 1
Sulfate 7.1 mg/L EPA 9056A 04/07/2016 13:05 BGN90340.126 1.26
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/15/2016 11:45 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.030 mg/L SW 6010D 04/13/2016 21:33 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/13/2016 21:33 MHH71310.05 1
Calcium (Ca)4.17 mg/L SW 6010D 04/13/2016 21:33 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/13/2016 21:33 MHH71310.005 1
Iron (Fe)0.062 mg/L SW 6010D 04/13/2016 21:33 MHH71310.01 1
Magnesium (Mg)2.29 mg/L SW 6010D 04/13/2016 21:33 MHH71310.005 1
Manganese (Mn)0.054 mg/L SW 6010D 04/13/2016 21:33 MHH71310.005 1
Potassium (K)1.42 mg/L SW 6010D 04/13/2016 21:33 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/13/2016 21:33 MHH71310.005 1
Sodium (Na)1.65 mg/L SW 6010D 04/13/2016 21:33 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/13/2016 21:33 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 04/13/2016 17:34 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 04/13/2016 17:34 JAHERMA11
Chromium (Cr)< 1 ug/L SW 6020B 04/13/2016 17:34 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/13/2016 17:34 JAHERMA11
Nickel (Ni)< 1 ug/L SW 6020B 04/13/2016 17:34 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 04/13/2016 17:34 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 40 mg/L SM2540C 04/11/2016 16:06 PARMSTR251
Page 8 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
2016007829
Collection Date:06-Apr-16 11:55 AM
Site:CCPMW-3D
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)5.0 mg/L
(CaCO3)
SM 2320B 04/08/2016 13:58 CJELLIO51
INORGANIC IONS BY IC
Chloride 6.5 mg/L EPA 9056A 04/07/2016 14:14 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/07/2016 14:14 BGN90340.1 1
Nitrate 5.7 mg/L EPA 9056A 04/07/2016 14:14 BGN90340.126 1.26
Nitrate as N 1.3 mg-N/L EPA 9056A 04/07/2016 14:14 BGN90340.023 1
Sulfate 12 mg/L EPA 9056A 04/07/2016 14:14 BGN90340.126 1.26
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/15/2016 12:01 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.033 mg/L SW 6010D 04/13/2016 21:37 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/13/2016 21:37 MHH71310.05 1
Calcium (Ca)6.88 mg/L SW 6010D 04/13/2016 21:37 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/13/2016 21:37 MHH71310.005 1
Iron (Fe)< 0.01 mg/L SW 6010D 04/13/2016 21:37 MHH71310.01 1
Magnesium (Mg)2.46 mg/L SW 6010D 04/13/2016 21:37 MHH71310.005 1
Manganese (Mn)0.010 mg/L SW 6010D 04/13/2016 21:37 MHH71310.005 1
Potassium (K)1.58 mg/L SW 6010D 04/13/2016 21:37 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/13/2016 21:37 MHH71310.005 1
Sodium (Na)2.19 mg/L SW 6010D 04/13/2016 21:37 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/13/2016 21:37 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 04/13/2016 17:39 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 04/13/2016 17:39 JAHERMA11
Chromium (Cr)1.36 ug/L SW 6020B 04/13/2016 17:39 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/13/2016 17:39 JAHERMA11
Nickel (Ni)< 1 ug/L SW 6020B 04/13/2016 17:39 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 04/13/2016 17:39 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 44 mg/L SM2540C 04/11/2016 16:06 PARMSTR251
Page 9 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
2016007830
Collection Date:06-Apr-16 3:30 PM
Site:CCPMW-4
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)49 mg/L
(CaCO3)
SM 2320B 04/08/2016 13:58 CJELLIO51
INORGANIC IONS BY IC
Chloride 2.5 mg/L EPA 9056A 04/07/2016 14:37 BGN90340.1 1
Fluoride 0.37 mg/L EPA 9056A 04/07/2016 14:37 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 04/07/2016 14:37 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 04/07/2016 14:37 BGN90340.023 1
Sulfate 1.9 mg/L EPA 9056A 04/07/2016 14:37 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/15/2016 12:04 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.208 mg/L SW 6010D 04/13/2016 21:49 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/13/2016 21:49 MHH71310.05 1
Calcium (Ca)21.8 mg/L SW 6010D 04/13/2016 21:49 MHH71310.01 1
Copper (Cu)0.067 mg/L SW 6010D 04/13/2016 21:49 MHH71310.005 1
Iron (Fe)38.1 mg/L SW 6010D 04/13/2016 21:49 MHH71310.01 1
Magnesium (Mg)10.4 mg/L SW 6010D 04/13/2016 21:49 MHH71310.005 1
Manganese (Mn)0.492 mg/L SW 6010D 04/13/2016 21:49 MHH71310.005 1
Potassium (K)35.2 mg/L SW 6010D 04/13/2016 21:49 MHH7131110
Silver (Ag)< 0.005 mg/L SW 6010D 04/13/2016 21:49 MHH71310.005 1
Sodium (Na)21.4 mg/L SW 6010D 04/13/2016 21:49 MHH71310.05 1
Zinc (Zn)0.105 mg/L SW 6010D 04/13/2016 21:49 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)6.12 ug/L SW 6020B 04/13/2016 17:44 JAHERMA11
Cadmium (Cd)1.88 ug/L SW 6020B 04/13/2016 17:44 JAHERMA11
Chromium (Cr)121 ug/L SW 6020B 04/13/2016 17:44 JAHERMA11
Lead (Pb)16.9 ug/L SW 6020B 04/13/2016 17:44 JAHERMA11
Nickel (Ni)60.5 ug/L SW 6020B 04/13/2016 17:44 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 04/13/2016 17:44 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 280 mg/L SM2540C 04/11/2016 16:06 PARMSTR2501
Page 10 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
2016007831
Collection Date:06-Apr-16 3:15 PM
Site:CCPMW-5
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)49 mg/L
(CaCO3)
SM 2320B 04/08/2016 13:58 CJELLIO51
INORGANIC IONS BY IC
Chloride 4.0 mg/L EPA 9056A 04/07/2016 15:00 BGN90340.1 1
Fluoride 0.38 mg/L EPA 9056A 04/07/2016 15:00 BGN90340.1 1
Nitrate 1.4 mg/L EPA 9056A 04/07/2016 15:00 BGN90340.1 1
Nitrate as N 0.32 mg-N/L EPA 9056A 04/07/2016 15:00 BGN90340.023 1
Sulfate 20 mg/L EPA 9056A 04/07/2016 15:00 BGN90340.44 4.4
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/15/2016 12:06 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L SW 6010D 04/13/2016 21:53 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/13/2016 21:53 MHH71310.05 1
Calcium (Ca)17.2 mg/L SW 6010D 04/13/2016 21:53 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/13/2016 21:53 MHH71310.005 1
Iron (Fe)0.301 mg/L SW 6010D 04/13/2016 21:53 MHH71310.01 1
Magnesium (Mg)0.238 mg/L SW 6010D 04/13/2016 21:53 MHH71310.005 1
Manganese (Mn)0.005 mg/L SW 6010D 04/13/2016 21:53 MHH71310.005 1
Potassium (K)2.55 mg/L SW 6010D 04/13/2016 21:53 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/13/2016 21:53 MHH71310.005 1
Sodium (Na)13.3 mg/L SW 6010D 04/13/2016 21:53 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/13/2016 21:53 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)4.65 ug/L SW 6020B 04/13/2016 18:06 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 04/13/2016 18:06 JAHERMA11
Chromium (Cr)1.56 ug/L SW 6020B 04/13/2016 18:06 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/13/2016 18:06 JAHERMA11
Nickel (Ni)1.02 ug/L SW 6020B 04/13/2016 18:06 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 04/13/2016 18:06 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 96 mg/L SM2540C 04/11/2016 16:06 PARMSTR251
Page 11 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
2016007832
Collection Date:06-Apr-16 10:40 AM
Site:CCPMW-6S
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 04/08/2016 13:58 CJELLIO51
INORGANIC IONS BY IC
Chloride 6.2 mg/L EPA 9056A 04/07/2016 15:45 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/07/2016 15:45 BGN90340.1 1
Nitrate 11 mg/L EPA 9056A 04/07/2016 15:45 BGN90340.137 1.37
Nitrate as N 2.5 mg-N/L EPA 9056A 04/07/2016 15:45 BGN90340.023 1
Sulfate 7.8 mg/L EPA 9056A 04/07/2016 15:45 BGN90340.137 1.37
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/15/2016 12:33 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.053 mg/L SW 6010D 04/13/2016 21:57 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/13/2016 21:57 MHH71310.05 1
Calcium (Ca)1.87 mg/L SW 6010D 04/13/2016 21:57 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/13/2016 21:57 MHH71310.005 1
Iron (Fe)0.381 mg/L SW 6010D 04/13/2016 21:57 MHH71310.01 1
Magnesium (Mg)2.68 mg/L SW 6010D 04/13/2016 21:57 MHH71310.005 1
Manganese (Mn)0.795 mg/L SW 6010D 04/13/2016 21:57 MHH71310.005 1
Potassium (K)2.61 mg/L SW 6010D 04/13/2016 21:57 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/13/2016 21:57 MHH71310.005 1
Sodium (Na)4.84 mg/L SW 6010D 04/13/2016 21:57 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/13/2016 21:57 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 04/13/2016 18:11 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 04/13/2016 18:11 JAHERMA11
Chromium (Cr)< 1 ug/L SW 6020B 04/13/2016 18:11 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/13/2016 18:11 JAHERMA11
Nickel (Ni)8.35 ug/L SW 6020B 04/13/2016 18:11 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 04/13/2016 18:11 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 52 mg/L SM2540C 04/12/2016 15:18 PARMSTR251
Page 12 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
2016007833
Collection Date:06-Apr-16 11:00 AM
Site:CCPMW-6D
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)10 mg/L
(CaCO3)
SM 2320B 04/08/2016 13:58 CJELLIO51
INORGANIC IONS BY IC
Chloride 6.3 mg/L EPA 9056A 04/07/2016 16:31 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/07/2016 16:31 BGN90340.1 1
Nitrate 20 mg/L EPA 9056A 04/07/2016 16:31 BGN9034110
Nitrate as N 4.4 mg-N/L EPA 9056A 04/07/2016 16:31 BGN90340.023 1
Sulfate 1.8 mg/L EPA 9056A 04/07/2016 16:31 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/15/2016 12:09 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.060 mg/L SW 6010D 04/13/2016 22:01 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/13/2016 22:01 MHH71310.05 1
Calcium (Ca)5.62 mg/L SW 6010D 04/13/2016 22:01 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/13/2016 22:01 MHH71310.005 1
Iron (Fe)< 0.01 mg/L SW 6010D 04/13/2016 22:01 MHH71310.01 1
Magnesium (Mg)2.36 mg/L SW 6010D 04/13/2016 22:01 MHH71310.005 1
Manganese (Mn)0.063 mg/L SW 6010D 04/13/2016 22:01 MHH71310.005 1
Potassium (K)2.18 mg/L SW 6010D 04/13/2016 22:01 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/13/2016 22:01 MHH71310.005 1
Sodium (Na)5.51 mg/L SW 6010D 04/13/2016 22:01 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/13/2016 22:01 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 04/13/2016 18:17 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 04/13/2016 18:17 JAHERMA11
Chromium (Cr)< 1 ug/L SW 6020B 04/13/2016 18:17 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/13/2016 18:17 JAHERMA11
Nickel (Ni)1.24 ug/L SW 6020B 04/13/2016 18:17 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 04/13/2016 18:17 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 51 mg/L SM2540C 04/12/2016 15:18 PARMSTR251
Page 13 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
2016007834
Collection Date:06-Apr-16 9:50 AM
Site:CCPTW-1S
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)5.0 mg/L
(CaCO3)
SM 2320B 04/08/2016 13:58 CJELLIO51
INORGANIC IONS BY IC
Chloride 5.0 mg/L EPA 9056A 04/07/2016 19:33 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/07/2016 19:33 BGN90340.1 1
Nitrate 8.5 mg/L EPA 9056A 04/07/2016 19:33 BGN90340.191 1.91
Nitrate as N 1.9 mg-N/L EPA 9056A 04/07/2016 19:33 BGN90340.023 1
Sulfate 0.38 mg/L EPA 9056A 04/07/2016 19:33 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)0.08 ug/L EPA 7470A 04/15/2016 12:11 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.031 mg/L SW 6010D 04/13/2016 22:05 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/13/2016 22:05 MHH71310.05 1
Calcium (Ca)2.13 mg/L SW 6010D 04/13/2016 22:05 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/13/2016 22:05 MHH71310.005 1
Iron (Fe)0.023 mg/L SW 6010D 04/13/2016 22:05 MHH71310.01 1
Magnesium (Mg)1.92 mg/L SW 6010D 04/13/2016 22:05 MHH71310.005 1
Manganese (Mn)0.011 mg/L SW 6010D 04/13/2016 22:05 MHH71310.005 1
Potassium (K)1.42 mg/L SW 6010D 04/13/2016 22:05 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/13/2016 22:05 MHH71310.005 1
Sodium (Na)2.94 mg/L SW 6010D 04/13/2016 22:05 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/13/2016 22:05 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 04/13/2016 18:22 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 04/13/2016 18:22 JAHERMA11
Chromium (Cr)< 1 ug/L SW 6020B 04/13/2016 18:22 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/13/2016 18:22 JAHERMA11
Nickel (Ni)< 1 ug/L SW 6020B 04/13/2016 18:22 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 04/13/2016 18:22 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 25 mg/L SM2540C 04/12/2016 15:18 PARMSTR251
Page 14 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
2016007835
Collection Date:06-Apr-16 10:10 AM
Site:CCPTW-1D
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)43 mg/L
(CaCO3)
SM 2320B 04/08/2016 13:58 CJELLIO51
INORGANIC IONS BY IC
Chloride 2.9 mg/L EPA 9056A 04/07/2016 19:56 BGN90340.1 1
Fluoride 0.22 mg/L EPA 9056A 04/07/2016 19:56 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 04/07/2016 19:56 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 04/07/2016 19:56 BGN90340.023 1
Sulfate 38 mg/L EPA 9056A 04/07/2016 19:56 BGN90340.839 8.39
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/15/2016 12:14 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.026 mg/L SW 6010D 04/13/2016 22:09 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/13/2016 22:09 MHH71310.05 1
Calcium (Ca)32.4 mg/L SW 6010D 04/13/2016 22:09 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/13/2016 22:09 MHH71310.005 1
Iron (Fe)0.084 mg/L SW 6010D 04/13/2016 22:09 MHH71310.01 1
Magnesium (Mg)2.98 mg/L SW 6010D 04/13/2016 22:09 MHH71310.005 1
Manganese (Mn)0.026 mg/L SW 6010D 04/13/2016 22:09 MHH71310.005 1
Potassium (K)2.80 mg/L SW 6010D 04/13/2016 22:09 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/13/2016 22:09 MHH71310.005 1
Sodium (Na)14.5 mg/L SW 6010D 04/13/2016 22:09 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/13/2016 22:09 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 04/13/2016 18:28 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 04/13/2016 18:28 JAHERMA11
Chromium (Cr)< 1 ug/L SW 6020B 04/13/2016 18:28 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/13/2016 18:28 JAHERMA11
Nickel (Ni)< 1 ug/L SW 6020B 04/13/2016 18:28 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 04/13/2016 18:28 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 150 mg/L SM2540C 04/12/2016 15:18 PARMSTR251
Page 15 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
2016007836
Collection Date:06-Apr-16 8:25 AM
Site:CCPTW-2
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 04/08/2016 13:58 CJELLIO51
INORGANIC IONS BY IC
Chloride 11 mg/L EPA 9056A 04/07/2016 20:42 BGN90340.2 2
Fluoride < 0.1 mg/L EPA 9056A 04/07/2016 20:42 BGN90340.1 1
Nitrate 8.8 mg/L EPA 9056A 04/07/2016 20:42 BGN90340.117 1.17
Nitrate as N 2.0 mg-N/L EPA 9056A 04/07/2016 20:42 BGN90340.023 1
Sulfate 5.3 mg/L EPA 9056A 04/07/2016 20:42 BGN90340.117 1.17
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/15/2016 12:16 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.045 mg/L SW 6010D 04/13/2016 22:13 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/13/2016 22:13 MHH71310.05 1
Calcium (Ca)4.57 mg/L SW 6010D 04/13/2016 22:13 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/13/2016 22:13 MHH71310.005 1
Iron (Fe)0.162 mg/L SW 6010D 04/13/2016 22:13 MHH71310.01 1
Magnesium (Mg)3.60 mg/L SW 6010D 04/13/2016 22:13 MHH71310.005 1
Manganese (Mn)0.013 mg/L SW 6010D 04/13/2016 22:13 MHH71310.005 1
Potassium (K)1.82 mg/L SW 6010D 04/13/2016 22:13 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/13/2016 22:13 MHH71310.005 1
Sodium (Na)2.24 mg/L SW 6010D 04/13/2016 22:13 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/13/2016 22:13 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 04/13/2016 18:33 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 04/13/2016 18:33 JAHERMA11
Chromium (Cr)1.17 ug/L SW 6020B 04/13/2016 18:33 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/13/2016 18:33 JAHERMA11
Nickel (Ni)1.08 ug/L SW 6020B 04/13/2016 18:33 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 04/13/2016 18:33 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 55 mg/L SM2540C 04/12/2016 15:18 PARMSTR251
Page 16 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
2016007837
Collection Date:06-Apr-16 1:05 PM
Site:CCPSW-1
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)7.7 mg/L
(CaCO3)
SM 2320B 04/08/2016 13:58 CJELLIO51
INORGANIC IONS BY IC
Chloride 3.4 mg/L EPA 9056A 04/07/2016 18:02 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/07/2016 18:02 BGN90340.1 1
Nitrate 2.0 mg/L EPA 9056A 04/07/2016 18:02 BGN9034110
Nitrate as N 0.45 mg-N/L EPA 9056A 04/07/2016 18:02 BGN90340.023 1
Sulfate 1.9 mg/L EPA 9056A 04/07/2016 18:02 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/15/2016 12:19 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.024 mg/L SW 6010D 04/13/2016 22:17 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/13/2016 22:17 MHH71310.05 1
Calcium (Ca)2.13 mg/L SW 6010D 04/13/2016 22:17 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/13/2016 22:17 MHH71310.005 1
Iron (Fe)1.02 mg/L SW 6010D 04/13/2016 22:17 MHH71310.01 1
Magnesium (Mg)1.14 mg/L SW 6010D 04/13/2016 22:17 MHH71310.005 1
Manganese (Mn)0.048 mg/L SW 6010D 04/13/2016 22:17 MHH71310.005 1
Potassium (K)1.58 mg/L SW 6010D 04/13/2016 22:17 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/13/2016 22:17 MHH71310.005 1
Sodium (Na)2.40 mg/L SW 6010D 04/13/2016 22:17 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/13/2016 22:17 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 04/13/2016 18:38 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 04/13/2016 18:38 JAHERMA11
Chromium (Cr)< 1 ug/L SW 6020B 04/13/2016 18:38 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/13/2016 18:38 JAHERMA11
Nickel (Ni)< 1 ug/L SW 6020B 04/13/2016 18:38 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 04/13/2016 18:38 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 37 mg/L SM2540C 04/12/2016 15:18 PARMSTR251
Page 17 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
2016007838
Collection Date:06-Apr-16 3:00 PM
Site:CCPSW-2
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)7.6 mg/L
(CaCO3)
SM 2320B 04/08/2016 13:58 CJELLIO51
INORGANIC IONS BY IC
Chloride 3.6 mg/L EPA 9056A 04/07/2016 21:27 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/07/2016 21:27 BGN90340.1 1
Nitrate 1.9 mg/L EPA 9056A 04/07/2016 21:27 BGN90340.1 1
Nitrate as N 0.43 mg-N/L EPA 9056A 04/07/2016 21:27 BGN90340.023 1
Sulfate 1.7 mg/L EPA 9056A 04/07/2016 21:27 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/15/2016 12:21 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.024 mg/L SW 6010D 04/13/2016 22:26 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/13/2016 22:26 MHH71310.05 1
Calcium (Ca)2.17 mg/L SW 6010D 04/13/2016 22:26 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/13/2016 22:26 MHH71310.005 1
Iron (Fe)0.934 mg/L SW 6010D 04/13/2016 22:26 MHH71310.01 1
Magnesium (Mg)1.16 mg/L SW 6010D 04/13/2016 22:26 MHH71310.005 1
Manganese (Mn)0.046 mg/L SW 6010D 04/13/2016 22:26 MHH71310.005 1
Potassium (K)1.57 mg/L SW 6010D 04/13/2016 22:26 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/13/2016 22:26 MHH71310.005 1
Sodium (Na)2.43 mg/L SW 6010D 04/13/2016 22:26 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/13/2016 22:26 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 04/13/2016 18:44 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 04/13/2016 18:44 JAHERMA11
Chromium (Cr)< 1 ug/L SW 6020B 04/13/2016 18:44 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/13/2016 18:44 JAHERMA11
Nickel (Ni)< 1 ug/L SW 6020B 04/13/2016 18:44 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 04/13/2016 18:44 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 35 mg/L SM2540C 04/12/2016 15:18 PARMSTR251
Page 18 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
2016007839
Collection Date:06-Apr-16 2:05 PM
Site:CCP Leachate
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 04/08/2016 13:58 CJELLIO51
INORGANIC IONS BY IC
Chloride 15000 mg/L EPA 9056A 04/07/2016 13:27 BGN90342002000
Fluoride < 10 mg/L EPA 9056A 04/07/2016 13:27 BGN903410100
Nitrate 10 mg/L EPA 9056A 04/07/2016 13:27 BGN903410100
Nitrate as N 2.3 mg-N/L EPA 9056A 04/07/2016 13:27 BGN90340.023 1
Sulfate 930 mg/L EPA 9056A 04/07/2016 13:27 BGN903410100
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/15/2016 12:40 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.853 mg/L SW 6010D 04/13/2016 22:42 MHH71310.05 10
Boron (B)9.56 mg/L SW 6010D 04/13/2016 22:42 MHH71310.5 10
Calcium (Ca)6450 mg/L SW 6010D 04/13/2016 22:42 MHH71311100
Copper (Cu)< 0.05 mg/L SW 6010D 04/13/2016 22:42 MHH71310.05 10
Iron (Fe)8.93 mg/L SW 6010D 04/13/2016 22:42 MHH71310.1 10
Magnesium (Mg)60.9 mg/L SW 6010D 04/13/2016 22:42 MHH71310.05 10
Manganese (Mn)56.4 mg/L SW 6010D 04/13/2016 22:42 MHH71310.05 10
Potassium (K)424 mg/L SW 6010D 04/13/2016 22:42 MHH713110100
Silver (Ag)< 0.05 mg/L SW 6010D 04/13/2016 22:42 MHH71310.05 10
Sodium (Na)348 mg/L SW 6010D 04/13/2016 22:42 MHH71310.5 10
Zinc (Zn)0.409 mg/L SW 6010D 04/13/2016 22:42 MHH71310.05 10
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)50.2 ug/L SW 6020B 04/13/2016 18:49 JAHERMA11
Cadmium (Cd)3.84 ug/L SW 6020B 04/13/2016 18:49 JAHERMA11
Chromium (Cr)1.09 ug/L SW 6020B 04/13/2016 18:49 JAHERMA11
Lead (Pb)251 ug/L SW 6020B 04/13/2016 18:49 JAHERMA11
Nickel (Ni)248 ug/L SW 6020B 04/13/2016 18:49 JAHERMA11
Selenium (Se)96.9 ug/L SW 6020B 04/13/2016 18:49 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 29000 mg/L SM2540C 04/12/2016 15:18 PARMSTR5001
Page 19 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
2016007840
Collection Date:06-Apr-16 3:35 PM
Site:FIELD BLANK
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 04/08/2016 13:58 CJELLIO51
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 9056A 04/07/2016 21:50 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/07/2016 21:50 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 04/07/2016 21:50 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 04/07/2016 21:50 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 04/07/2016 21:50 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/15/2016 12:43 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L SW 6010D 04/13/2016 22:30 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/13/2016 22:30 MHH71310.05 1
Calcium (Ca)0.011 mg/L SW 6010D 04/13/2016 22:30 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/13/2016 22:30 MHH71310.005 1
Iron (Fe)< 0.01 mg/L SW 6010D 04/13/2016 22:30 MHH71310.01 1
Magnesium (Mg)< 0.005 mg/L SW 6010D 04/13/2016 22:30 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 04/13/2016 22:30 MHH71310.005 1
Potassium (K)< 0.1 mg/L SW 6010D 04/13/2016 22:30 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/13/2016 22:30 MHH71310.005 1
Sodium (Na)< 0.05 mg/L SW 6010D 04/13/2016 22:30 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/13/2016 22:30 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 04/13/2016 18:55 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 04/13/2016 18:55 JAHERMA11
Chromium (Cr)< 1 ug/L SW 6020B 04/13/2016 18:55 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 04/13/2016 18:55 JAHERMA11
Nickel (Ni)< 1 ug/L SW 6020B 04/13/2016 18:55 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 04/13/2016 18:55 JAHERMA11
Page 20 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
Q16040161 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16030484 -- 2016007824
Alkalinity (mg/L CaCO3)92.1mg/L
(CaCO3)
-10.57
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3) 10.86 91.2mg/L
(CaCO3)
-1208019.91
Page 21 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
Q16040104 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0296 mg/L -10.0296 0.1 < 1/2 RDL
Fluoride 0.0441 mg/L -10.0441 0.1 < 1/2 RDL
Nitrate 0.012 mg/L -10.012 0.1 < 1/2 RDL
Sulfate -0.0018 mg/L -1-0.0018 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 6.35 5 101mg/L -1208016.35
Fluoride 5.34 5 106mg/L -1208015.34
Nitrate 5.19 5 104mg/L -1208015.19
Sulfate 6.99 5 104mg/L -1208016.99
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 6.35 5 101 0.00197mg/L -1208016.35
Fluoride 5.38 5 107 0.65mg/L -1208015.38
Nitrate 5.21 5 104 0.359mg/L -1208015.21
Sulfate 7 5 104 0.276mg/L -1208017
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 5.85 5 95.9mg/L -1208015.85
Fluoride 5.39 5 107mg/L -1208015.39
Nitrate 5.16 5 102mg/L -1208015.16
Sulfate 8.96 5 102mg/L -1208018.96
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 5.92 5 97.3 1.46mg/L -1208015.92
Fluoride 5.4 5 107 0.112mg/L -1208015.4
Nitrate 5.15 5 102 0.0449mg/L -1208015.15
Sulfate 8.95 5 102 0.237mg/L -1208018.95
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 4.99 5 99.8mg/L -1208014.99
Fluoride 5.47 5 109mg/L -1208015.47
Nitrate 5.14 5 103mg/L -1208015.14
Sulfate 5.17 5 103mg/L -1208015.17
Page 22 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
Q16040192 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.027 mg/L -10.027 0.1 < 1/2 RDL
Fluoride 0 mg/L -10 0.1 < 1/2 RDL
Nitrate 0 mg/L -10 0.1 < 1/2 RDL
Sulfate 0 mg/L -10 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 8.77 5 99.5mg/L -1208018.77
Fluoride 1.02 1 100mg/L -1208011.02
Nitrate 1.03 1 95.1mg/L -1208011.03
Sulfate 1.2 1 95.4mg/L -1208011.2
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 8.74 5 99 0.463mg/L -1208018.74
Fluoride 1.02 1 100 0.0999mg/L -1208011.02
Nitrate 1.03 1 95.3 0.21mg/L -1208011.03
Sulfate 1.2 1 95.6 0.209mg/L -1208011.2
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 7.78 5 97.1mg/L -1208017.78
Fluoride 1.03 1 99.9mg/L -1208011.03
Nitrate 2.63 1 95.7mg/L -1208011.16
Sulfate 2.32 1 95.1mg/L -1208011.14
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 7.78 5 97.1 0.0165mg/L -1208017.78
Fluoride 1.03 1 99.9 0mg/L -1208011.03
Nitrate 2.63 1 95.6 0.105mg/L -1208011.15
Sulfate 2.32 1 95 0.105mg/L -1208011.14
Final QualifierDilMeasuredUnits:Parameter
IS # 3
% Recovery LCL UCLSpike
Chloride 7.5 5 99.3mg/L -1208017.5
Fluoride 5mg/L -120801Not Tested
Nitrate 5mg/L -120801Not Tested
Sulfate 5mg/L -120801Not Tested
Page 23 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
Q16040192 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
ISD # 3
RPD% Recovery LCL UCLSpike
Chloride 7.52 5 99.7 0.452mg/L -1208017.52
Fluoride 5mg/L -120801Not Tested
Nitrate 5mg/L -120801Not Tested
Sulfate 5mg/L -120801Not Tested
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 4.82 5 96.4mg/L -1208014.82
Fluoride 2.02 2 101mg/L -1208012.02
Nitrate 1.94 2 97.2mg/L -1208011.94
Sulfate 1.95 2 97.6mg/L -1208011.95
Page 24 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
Q16040319 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.007 ug/L -10.007 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.002 ug/L -10.002 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Mercury (Hg) 0.004 ug/L -10.004 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.08 1 107ug/L -1257511.08
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 1.06 1 105 2.07ug/L -11.06
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.03 2 102ug/L -1158512.03
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 2 2 99.9ug/L -1158512
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16030484 -- 2016007825
Mercury (Hg) 1.04 1 104ug/L -1257511.04
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16030484 -- 2016007825
Mercury (Hg) 1.02 1 102 2.05ug/L -1257511.02
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16030484 -- 2016007832
Mercury (Hg) 1 1 100ug/L -1257511
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16030484 -- 2016007832
Mercury (Hg) 0.999 1 99.7 0.5ug/L -1257510.999
Page 25 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
Q16040207 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) -0.000046 mg/L -1-0.000046 0.005 < 1/2 RDL
Boron (B) 0.00183 mg/L -10.00183 0.05 < 1/2 RDL
Calcium (Ca) 0.00207 mg/L -10.00207 0.01 < 1/2 RDL
Copper (Cu) 0.000264 mg/L -10.000264 0.005 < 1/2 RDL
Iron (Fe) 0.000312 mg/L -10.000312 0.01 < 1/2 RDL
Magnesium (Mg) -0.00132 mg/L -1-0.00132 0.005 < 1/2 RDL
Manganese (Mn) -0.000005 mg/L -1-0.000005 0.005 < 1/2 RDL
Potassium (K) -0.0116 mg/L -1-0.0116 0.1 < 1/2 RDL
Silver (Ag) 0.000168 mg/L -10.000168 0.005 < 1/2 RDL
Sodium (Na) 0.00065 mg/L -10.00065 0.05 < 1/2 RDL
Zinc (Zn) 0.000751 mg/L -10.000751 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 5.2 5 104mg/L -1208015.2
Boron (B) 5.11 5 102mg/L -1208015.11
Calcium (Ca) 5.15 5 103mg/L -1208015.15
Copper (Cu) 5.06 5 101mg/L -1208015.06
Iron (Fe) 5.11 5 102mg/L -1208015.11
Magnesium (Mg) 5.06 5 101mg/L -1208015.06
Manganese (Mn) 5.16 5 103mg/L -1208015.16
Potassium (K) 5.05 5 101mg/L -1208015.05
Silver (Ag) 0.492 0.5 98.4mg/L -1208010.492
Sodium (Na) 5.05 5 101mg/L -1208015.05
Zinc (Zn) 5.17 5 103mg/L -1208015.17
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16030484 -- 2016007826
Barium (Ba) 5.04 5 100mg/L -1257515.04
Boron (B) 4.91 5 98.1mg/L -1257514.91
Calcium (Ca) 6.53 5 97.5mg/L -1257516.53
Copper (Cu) 4.85 5 96.9mg/L -1257514.85
Iron (Fe) 5.08 5 98.3mg/L -1257515.08
Magnesium (Mg) 5.67 5 95.9mg/L -1257515.67
Manganese (Mn) 4.97 5 99.2mg/L -1257514.97
Potassium (K) 6.49 5 97.6mg/L -1257516.49
Silver (Ag) 0.475 0.5 94.9mg/L -1257510.475
Sodium (Na) 6.68 5 97.2mg/L -1257516.68
Zinc (Zn) 4.95 5 99mg/L -1257514.95
Page 26 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
Q16040207 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16030484 -- 2016007826
Barium (Ba) 5.07 5 101 0.497mg/L -1257515.07
Boron (B) 5.02 5 100 2.24mg/L -1257515.02
Calcium (Ca) 6.58 5 98.6 1.06mg/L -1257516.58
Copper (Cu) 4.87 5 97.4 0.494mg/L -1257514.87
Iron (Fe) 5.11 5 98.8 0.528mg/L -1257515.11
Magnesium (Mg) 5.72 5 96.9 1.08mg/L -1257515.72
Manganese (Mn) 5 5 99.7 0.503mg/L -1257515
Potassium (K) 6.57 5 99.1 1.55mg/L -1257516.57
Silver (Ag) 0.481 0.5 96.2 1.33mg/L -1257510.481
Sodium (Na) 6.78 5 99.1 1.96mg/L -1257516.78
Zinc (Zn) 4.97 5 99.3 0.343mg/L -1257514.97
Page 27 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
Q16040212 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As) -0.0002 ug/L -1-0.0002 1 < 1/2 RDL
Cadmium (Cd) 0.0016 ug/L -10.0016 1 < 1/2 RDL
Chromium (Cr) 0.0059 ug/L -10.0059 1 < 1/2 RDL
Lead (Pb) 0.0014 ug/L -10.0014 1 < 1/2 RDL
Nickel (Ni) -0.0142 ug/L -1-0.0142 1 < 1/2 RDL
Selenium (Se) 0.0578 ug/L -10.0578 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As) 49.1 50 98.1ug/L -12080149.1
Cadmium (Cd) 48.9 50 97.7ug/L -12080148.9
Chromium (Cr) 50 50 100ug/L -12080150
Lead (Pb) 48.5 50 97ug/L -12080148.5
Nickel (Ni) 48.8 50 97.5ug/L -12080148.8
Selenium (Se) 47.8 50 95.7ug/L -12080147.8
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16030484 -- 2016007825
Arsenic (As) 48.6 50 97.2ug/L -12080148.6
Cadmium (Cd) 48.7 50 97.4ug/L -12080148.7
Chromium (Cr) 50 50 99.1ug/L -12080150
Lead (Pb) 48.5 50 96.9ug/L -12080148.5
Nickel (Ni) 50 50 97.7ug/L -12080150
Selenium (Se) 48.4 50 96.6ug/L -12080148.4
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16030484 -- 2016007825
Arsenic (As) 48.6 50 97.2 0.00617ug/L -12080148.6
Cadmium (Cd) 48.6 50 97.2 0.172ug/L -12080148.6
Chromium (Cr) 49.6 50 98.3 0.835ug/L -12080149.6
Lead (Pb) 48.3 50 96.6 0.282ug/L -12080148.3
Nickel (Ni) 49.9 50 97.7 0.095ug/L -12080149.9
Selenium (Se) 48.5 50 96.7 0.15ug/L -12080148.5
Page 28 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
Q16040187 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16030238 -- 2016006726
TDS 0.44mg/L -11130
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16030238 -- 2016006746
TDS 1.09mg/L -1926
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J16030238 -- 2016006747
TDS 0.785mg/L -12030
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 97mg/L -11090197
Page 29 of 31
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030484
Q16040219 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16030638 -- 2016008507
TDS 1.14mg/L -1437
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16030638 -- 2016008508
TDS 0.181mg/L -1551
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J16030638 -- 2016008509
TDS 8mg/L -113
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 97mg/L -11090197
Page 30 of 31
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13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16030487
Project Name:CLIFFSIDE - GW CCP LANDFILL
Lab Contact: Peggy Kendall
Date:4/14/2016
Customer Address:573 Duke Power Rd
Customer Name(s):Chuck Campbell,Tim Hunsucker, Sean DeNeale
Mail Code: Clliffside Steam Station
Mooresboro, NC 28024
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Peggy Kendall
Page 1 of 8
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016007845 CLIFFSIDE 06-Apr-16 1:15 PM LDC CCPSW-1
2016007846 CLIFFSIDE 06-Apr-16 3:10 PM LDC CCPSW-2
2 Total Samples
Page 2 of 8
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:4/14/2016
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 8
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030487
2016007845
Collection Date:06-Apr-16 1:15 PM
Site:CCPSW-1
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
DISSOLVED METALS BY ICP
Zinc (Zn)0.006 mg/L SW 6010D 04/11/2016 14:22 JJMACKE0.005 1
DISSOLVED METALS BY ICP-MS
Cadmium (Cd)< 1 ug/L SW 6020B 04/08/2016 15:24 MHALL311
Chromium (Cr)< 1 ug/L SW 6020B 04/08/2016 15:24 MHALL311
Copper (Cu)< 1 ug/L SW 6020B 04/08/2016 15:24 MHALL311
Lead (Pb)< 1 ug/L SW 6020B 04/08/2016 15:24 MHALL311
Nickel (Ni)< 1 ug/L SW 6020B 04/08/2016 15:24 MHALL311
Silver (Ag)< 1 ug/L SW 6020B 04/08/2016 15:24 MHALL311
Page 4 of 8
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030487
2016007846
Collection Date:06-Apr-16 3:10 PM
Site:CCPSW-2
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
DISSOLVED METALS BY ICP
Zinc (Zn)< 0.005 mg/L SW 6010D 04/11/2016 14:26 JJMACKE0.005 1
DISSOLVED METALS BY ICP-MS
Cadmium (Cd)< 1 ug/L SW 6020B 04/08/2016 15:40 MHALL311
Chromium (Cr)< 1 ug/L SW 6020B 04/08/2016 15:40 MHALL311
Copper (Cu)< 1 ug/L SW 6020B 04/08/2016 15:40 MHALL311
Lead (Pb)< 1 ug/L SW 6020B 04/08/2016 15:40 MHALL311
Nickel (Ni)< 1 ug/L SW 6020B 04/08/2016 15:40 MHALL311
Silver (Ag)< 1 ug/L SW 6020B 04/08/2016 15:40 MHALL311
Page 5 of 8
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030487
Q16040198 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Zinc (Zn) -0.000062 mg/L -1-0.000062 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Zinc (Zn) 1 1 100mg/L -1158511
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16040125 -- 2016009694
Zinc (Zn) 5.27 5 105mg/L -1307015.27
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16040125 -- 2016009694
Zinc (Zn) 5.3 5 106 0.492mg/L -1307015.3
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16040211 -- 2016009995
Zinc (Zn) 4.83 5 96.6mg/L -1307014.83
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16040211 -- 2016009995
Zinc (Zn) 4.51 5 90.1 6.96mg/L -1307014.51
Page 6 of 8
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030487
Q16040164 IMS Dissolved DISSOLVED METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Cadmium (Cd) 0 ug/L -10 1 < 1/2 RDL
Chromium (Cr) -0.0403 ug/L -1-0.0403 1 < 1/2 RDL
Copper (Cu) -0.0061 ug/L -1-0.0061 1 < 1/2 RDL
Lead (Pb) -0.0005 ug/L -1-0.0005 1 < 1/2 RDL
Nickel (Ni) -0.0063 ug/L -1-0.0063 1 < 1/2 RDL
Silver (Ag) 0.0002 ug/L -10.0002 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Cadmium (Cd) 8.56 8 107ug/L -1158518.56
Chromium (Cr) 84.5 80 106ug/L -11585184.5
Copper (Cu) 40.7 40 102ug/L -11585140.7
Lead (Pb) 84 80 105ug/L -11585184
Nickel (Ni) 83.1 80 104ug/L -11585183.1
Silver (Ag) 41.5 40 104ug/L -11585141.5
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16030487 -- 2016007845
Cadmium (Cd) 51.4 50 103ug/L -13070151.4
Chromium (Cr) 51.1 50 102ug/L -13070151.1
Copper (Cu) 50.2 50 99.5ug/L -13070150.2
Lead (Pb) 51.7 50 103ug/L -13070151.7
Nickel (Ni) 50.3 50 99.8ug/L -13070150.3
Silver (Ag) 49.5 50 99.1ug/L -13070149.5
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16030487 -- 2016007845
Cadmium (Cd) 51 50 102 0.604ug/L -13070151
Chromium (Cr) 51.7 50 103 1.19ug/L -13070151.7
Copper (Cu) 50 50 99.2 0.383ug/L -13070150
Lead (Pb) 51.9 50 104 0.423ug/L -13070151.9
Nickel (Ni) 50.2 50 99.6 0.222ug/L -13070150.2
Silver (Ag) 49 50 98 1.15ug/L -13070149
Page 7 of 8
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