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8202_SampsonCoMSWLF_20151111_GWMReport_DIN26366
SECOND SEMI-ANNUAL 2015 SAMPLING EVENT Sampson County Disposal, LLC Active MSW and C&D Landfills, Permit No. 82-02 Sampson County, North Carolina Submitted To: Sampson County Disposal, LLC 7434 Roseboro Highway (NC Highway 24) Roseboro, NC 28382 Submitted By: Golder Associates NC, Inc. 5B Oak Branch Drive Greensboro, NC 27407 USA January 2016 073-9603715.100 WA T E R Q U A L I T Y M O N I T O R I N G RE P O R T Golder Associates NC, Inc. 5B Oak Branch Drive Greensboro, NC. 27407 USA Tel: (336) 852-4903 Fax: (336) 852-4904 www.golder.com Golder Associates: Operations in Africa, Asia, Australasia, Europe, North America and South America January 29, 2016 073-9603715.100 Mr. Ervin Lane Department of Environment and Natural Resources Division of Waste Management, Solid Waste Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 RE: WATER QUALITY MONITORING REPORT, SECOND SEMI-ANNUAL 2015 SAMPLING EVENT SAMPSON COUNTY DISPOSAL, LLC ACTIVE MSW AND C&D LANDFILLS PERMIT NO. 82-02 SAMPSON COUNTY, NORTH CAROLINA Dear Ervin, On behalf of Sampson County Disposal, LLC (Sampson County), a subsidiary of Waste Industries USA, Inc. (Waste Industries), Golder Associates NC, Inc. (Golder) is submitting the enclosed Water Quality Monitoring Report, which documents the results of the November 9 - 11, 2015, compliance monitoring event, and December 30, 2015, verification event at the above-referenced facility. Groundwater, surface water, and leachate samples were analyzed for North Carolina (NC) Appendix I constituents, with the exception of MW-100B, which was only analyzed for the NC Appendix I list of inorganic constituents per the approved monitoring plan. Samples for the Construction and Demolition (C&D) landfill wells were also analyzed for the other required parameters for C&D landfills, as specified in Title 15A NCAC 13B.0544 including tetrahydrofuran, and the leachate sample was also analyzed for additional required parameters. As presented, five inorganic constituents (antimony, chromium, cobalt, copper, and zinc) were detected at concentrations above their respective Solid Waste Section Limits (SWSLs) in samples from one or more downgradient compliance monitoring points at the active MSW landfill during the November 2015 monitoring event. The concentrations of three of these metals (antimony, chromium, and cobalt) were also above the established groundwater standards; in addition, estimated cobalt and vanadium concentrations below the SWSL were above applicable standards for one or more downgradient monitoring points. As allowed by 15A NCAC 13B. 1632 (g) and (h), statistical analyses were performed to determine the source of above-standard, quanitfiable concentrations of antimony, chromium, and cobalt. Based on the statistical analyses, the antimony and chromium concentrations are below statistical background limits, and do not warrant additional action. The cobalt detection at the GGI-1 Outfall, however, was statistically significant. A verification sampling event was conducted on December 30, 2015, and the GGI-1 Outfall was re-sampled and analyzed for total and dissolved cobalt. The verification concentrations confirmed the initial results, and do not appear to be biased significantly high by turbidity, although elevated turbidity was noted at the location during both sampling events (fine-grained particulates may bias metals results high). Based on information provided by the site and their engineering firm, there was an apparent back-up within the Gravity Groundwater Intercept (GGI) system prior to the November event, which has since been cleared. However, sediment build-up may take additional time to clear out. There were no leachate indicators noted for this sample or other atypical results aside from relatively high metals concentrations as compared to historical data. Therefore, we recommend reviewing the results from the next semi-annual event to determine if additional action is warranted. Mr. Ervin Lane January 29, 2016 NC Dept. of Environment & Natural Resources 2 073-9603715.100 As presented, five inorganic constituents (antimony, chromium, cobalt, copper, and zinc) were detected at concentrations above their respective Solid Waste Section Limits (SWSLs) in samples from one or more downgradient compliance monitoring points at the active MSW landfill during the November 2015 monitoring event. The concentrations of antimony, chromium, and cobalt in samples from one or more downgradient monitoring well were reported above the establish groundwater standard and the SWSL. As allowed by 15A NCAC 13B. 1632 (g) and (h), statistical analyses were performed to determine the source of above-standard concentration of antimony, chromium, and cobalt reported in samples from one or more downgradient monitoring point. Based on statistical analyses, the aforementioned concentrations are below statistical background and do not warrant additional action with the exception of cobalt at GGI-1 Outfall, which was statistically significant. A verification sampling event was conducted on December 30, 2015, and GGI-1 Outfall was re-sampled and analyzed for total and dissolved cobalt. Based on these results, the concentrations confirmed and do not appear to be biased significantly high by turbidity, although elevated turbidity was noted at the location during both sampling events and fine-grained particulates may bias results high. Based on information provided by the Waste Industries and their engineering firm, there was a connection being made to the GGI system during both the initial and re-sample time period in which a portion of the GGI system was open for connection and silt was known to have entered the system. The sediment has sediment in the system was cleaned as best possible in early 2016; however, sediment build up may take additional time to clear out. There were no leachate indicators noted for this sample or other atypical results aside from relatively high metals concentrations. Therefore, we recommend reviewing the results from the next semi-annual event to determine if additional action is warranted. At the C&D facility, four NC Appendix I inorganic constituents (arsenic, barium, chromium, and copper) were reported at concentrations greater than their respective SWSLs in samples from one or more downgradient monitoring wells during the November 2015 monitoring event. The concentrations of arsenic and chromium were reported to be above the NC2L in samples from one or more downgradient monitoring well. Statistical analyses were performed to determine if the reported concentrations represent statistically significant increases over background concentrations. Based on the results of the statistical analysis, the reported concentrations of arsenic and chromium were not statistically significant and no further action is warranted. Indicator parameters iron and manganese were also detected at concentrations above their respective SWSLs and NC 2L Groundwater Standards in samples from one or more downgradient wells during the event, as they have been during previous events. Based on historical data and statistical analyses, no further action is recommended. Cobalt and vanadium were reported in samples from one or more upgradient and/or downgradient C&D and MSW wells at estimated concentrations above the applicable groundwater standards but below their respective SWSLs as they have been during previous events. No further action is required since concentrations are estimated, and data are similar to historical and/or upgradient monitoring data. No NC Appendix I VOCs were detected at concentrations above SWSLs during this monitoring event in any compliance monitoring point. Zinc was detected at downstream points SW-4 and SW-5 at concentrations above the SWSL and applicable surface water standard during this event, as it has been in the historically at SW-5, and may be biased high by turbidity induced by heavy rainfall prior to the sampling event. Silver and acetone were detected at estimated concentrations below the SWLs and above the surface water standards at SW-5 during this event; no further action is warranted based on estimated concentrations. No NC other constituents were detected above the SWSLs or applicable surface water standards in any surface water monitoring points during the November 2015 event. In the absence of leachate indicator parameters, no further action is warranted at this time. Also, leachate results were generally consistent with historical data for this facility. Based on these results, Sampson County Disposal, LLC will continue groundwater monitoring in accordance with the requirements of the Detection Monitoring Program as outlined in Title 15A NCAC 13B.1633 and .0544. The next semi-annual monitoring event is tentatively scheduled for May 2016. If you have any questions, please contact the undersigned at 336-852-4903. January 2016 i 073-9603715 Table of Contents COVER LETTER 1.0 INTRODUCTION ............................................................................................................................... 1 1.1 Site Description and Background .................................................................................................. 1 1.2 Compliance Monitoring History ..................................................................................................... 1 1.3 Hydrogeologic Setting ................................................................................................................... 3 2.0 FIELD PROGRAM, MONITORING RESULTS, AND DISCUSSION ................................................ 4 2.1 Visual Inspection Program ............................................................................................................ 4 2.2 Well Network and Groundwater Elevation Measurements ........................................................... 4 2.3 November 2015 Monitoring Event................................................................................................. 5 2.4 December 2015 Verification Groundwater Monitoring Event ........................................................ 6 2.5 Laboratory Analysis Program ........................................................................................................ 6 2.6 November 2015 Sampling Results ............................................................................................... 6 2.7 December 2015 Verification Sampling Results ............................................................................. 7 3.0 LABORATORY AND FIELD QA/QC ................................................................................................. 7 4.0 DATA EVALUATION ......................................................................................................................... 7 4.1 North Carolina Groundwater and Surface Water Standard Comparisons .................................... 7 4.2 Statistical Evaluations ................................................................................................................... 8 5.0 CONCLUSIONS ................................................................................................................................ 8 6.0 REFERENCES .................................................................................................................................. 9 List of Tables Table 1 Summary of Historical Groundwater Elevation Data Table 2 Summary of Estimated Horizontal Flow Velocities Table 3 Summary of Well Construction Information Table 4 Summary of Groundwater Monitoring Results Detected Constituents in MSW Wells Table 5 Summary of Field Parameters for MSW Wells Table 6 Summary of Groundwater Monitoring Results Detected Constituents in C&D Wells Table 7 Summary of Field Parameters for C&D Wells Table 8 Summary of Surface Water Monitoring Results Table 9 Summary of Surface Water Field Parameters Table 10 Summary of Detected Leachate Parameters List of Drawings Drawing 1 Groundwater Contour Map, November 9 - 11, 2015 List of Appendices Appendix A Groundwater and Surface Water Sampling Logs Appendix B November 2015 Groundwater Certificates-of-Analysis, Chain-of-Custody Forms and Laboratory Data Reviews Appendix C Statistical Evaluation Worksheets and Summary Table January 2016 1 073-9603715 1.0 INTRODUCTION This report summarizes the monitoring results from the November 9 - 11, 2015, groundwater, surface water, and leachate sampling and analysis event at the active Sampson County, LLC Municipal Solid Waste (MSW) and Construction & Demolition (C&D) Landfills in Sampson County. The active MSW Landfill facility is a Subtitle D facility and is monitored in accordance with Title 15A of the North Carolina Administrative Code (NCAC) Subchapter 13B.1633. Groundwater at the closed C&D Landfill is monitored in accordance with Title 15A NCAC 13B.0544. The facility is located on the northern half of the Sampson County Landfill property and is comprised of the Phase 1 active Subtitle D lined MSW landfill and one active C&D landfill. The facility is owned and operated by Sampson County, LLC, a subsidiary of Waste Industries, Inc., under Permit No. 82-02 issued by the North Carolina (NC) Department of Environment and Natural Resources (DENR). The southern half of the landfill property is comprised of one closed Subtitle D lined MSW landfill and one closed C&D landfill, which are covered under Permit No. 82-01. The results for the closed facility are submitted under separate cover. 1.1 Site Description and Background The location of the facility is shown on the inlay on Drawing 1. The Sampson County Landfill is located approximately 6.5 miles west of Clinton, North Carolina in Sampson County near the rural community of Snow Hill. Access to the site is from Roseboro Highway (N.C. Highway 24), south of the site. The Bearskin Swamp is located along the eastern property boundary and drains to the southwest into Little Coharie Creek. The location of this surface water feature is shown on Drawing 1. Based on the topography as shown on Drawing 1, topographic surface elevations at the facility range from approximately 130 feet above mean sea level (AMSL) along the perimeter of the C&D disposal area on the southeastern portion of the facility, to nearly 250 feet AMSL in the southeastern portion of the MSW disposal area. The site is surrounded predominantly by wooded, agricultural, or rural residential properties. The Permit 82-01 closed MSW and C&D landfills are located south of the active landfills. The property also includes a closed, unlined disposal area owned and maintained by Sampson County. This area is located south of the active facility. Roseboro Highway (N.C. Highway 24) is located to the south of the active landfills. 1.2 Compliance Monitoring History Groundwater monitoring at the facility was initiated in October 1996. The facility’s approved MSW monitoring network is currently comprised of eight monitoring wells, which monitor the uppermost aquifer beneath the facility. Monitoring wells MW-102A and MW-103A are the upgradient background wells for the MSW landfill. An additional upgradient background well (MW-100B) is monitored for NC Appendix I January 2016 2 073-9603715 inorganic constituents. Monitoring well MW-100B was installed as a replacement well MW-100A prior to the May 2010 sampling event due to site construction activities. Wells MW-104, MW-105A, MW-106, MW-107S, and MW-108 are downgradient compliance wells for the MSW landfill. Additionally, upgradient well MW-1N and downgradient wells MW-2N, MW-3N, MW-4N, MW-5AN, and MW-5BN monitor groundwater at the C&D landfill. Groundwater beneath the two disposal units is currently monitored by a combined total of 14 monitoring wells. In addition to the wells, groundwater quality is also monitored at GGI Outfalls 1 and 2, gravity groundwater intercept outfall sampling locations. GGI Outfall 1 is located east of the MSW disposal area, while GGI Outfall 2 is located north of the MSW, both outfalls discharging into wetland areas. Monitoring well MW-107D had been sampled in previous events as part of an assessment of volatile organic constituents (VOCs) detected in MW-107S. Historical analytical results for samples from MW-107S and MW-107D indicate that VOCs have been present in groundwater, and may be related to landfill gas impacts to groundwater and/or historical leachate seeps along the adjacent side slopes as discussed in the September 20, 2007, meeting with the Solid Waste Section. The corrective action for these potential sources was implemented with the initial installation of several active gas extraction wells during final capping activities, as well as the installation of additional landfill gas extraction wells near the eastern slope of the facility. Recent data for samples from MW-107S and MW-107D indicate that concentrations of VOCs in groundwater samples are below SWSLs and that these corrective measures have improved groundwater quality in this area. The North Carolina Department of Environment and Natural Resources (NC DENR) granted approval to discontinue sampling monitoring well MW-107D in electronic correspondence dated October 24, 2012. The approval to discontinue sampling MW-107D is contingent upon being able to collect a sample from MW-107S and that no quantifiable detections of VOCs are reported in the sample collected from MW-107S. If MW-107S is dry, or if VOCs are reported at quantifiable concentrations, then the facility must resume sampling MW-107D. Based on the May 2015 data, there were no quantifiable detections of VOCs in the sample from MW-107S and therefore MW-107D will not be sampled during the next scheduled compliance monitoring event. The facility’s monitoring network also includes three surface water sampling points, SW-1, SW-4, and SW-5. SW-1 is the facility’s upstream sampling point located along Bearskin Swamp north of the active facility. Surface water point SW-4 is located downstream and north of the MSW disposal area along an unnamed tributary to the Bearskin Swamp. Surface water point SW-5 is a second downstream sampling location located east of the active facility in a drainage channel into the wetlands area. Surface points SW-1, SW-4, and SW-5 are sampled in conjunction with the groundwater monitoring wells in accordance with the facility’s permit and Water Quality Monitoring Plan. January 2016 3 073-9603715 1.3 Hydrogeologic Setting The facility is located in the western portion of the Coastal Plain Physiographic Province of North Carolina. The geologic units of this region are relatively young, dating from the Cretaceous Period to the present, and have been formed through transgression and regression of the Atlantic Ocean. The natural topography is flat to gently rolling with the upland surfaces gradually sloping downward in a southeasterly direction (S&ME 1992). The site is underlain by sands, silts, and clays of the Black Creek Formation, which consists of crossbedded layers of black to gray thinly-laminated clay and sand lenses of varied thickness and grain size. The formation is rich in mica, lignite, and iron sulfides. The Tuscaloosa formation underlies the Black Creek Formation and is comprised of gray to white sand and gravel with clay lenses (NCGS 1985). An unconformity forms the contact between the two formations with some interfingering of the two layers in the transition zone (NCGS 1960). The uppermost groundwater beneath the facility is present in a shallow, unconfined aquifer comprised of sands mixed with thin clay seams and larger seams of fine sand. Beneath the uppermost aquifer, a clay confining layer is present generally at a depth of approximately 20 - 25 feet below ground surface (BGS). The clay confining layer generally consists of black or dark gray silty clay with thin seams of light gray fine sand (S&ME 1992). Groundwater occurs at depths varying from approximately 4 - 16 feet BGS (plus or minus) across the entire site. Depth-to-water measurements obtained during the November 2015 monitoring event are summarized in Table 1 and were used to prepare a groundwater surface contour map presented on Drawing 1. Surface water and groundwater at the site generally flows to the northeast and east toward Bearskin Swamp located along the eastern property boundary. The Bearskin Swamp flows south to southwest and drains into Little Coharie Creek, located approximately two miles southwest of the facility. The groundwater contour map and interpreted flow directions are generally consistent with previously submitted interpretations for this facility. Based on the November 2015 groundwater contour map, the hydraulic gradient in the shallow aquifer underlying the site, as measured along the conceptual flow path shown on the contour map, was calculated to be approximately 0.006 feet/foot. Groundwater velocities were calculated using a hydraulic conductivity of 1.295 X 10-2 centimeters per second (cm/s), which is the average of the hydraulic conductivities calculated for the hydrogeologic units present at the facility (GNRA December 1999). The estimated effective porosity of the shallow aquifer is also based on the average of the effective porosities for the hydrogeologic units, which is 0.25 (GNRA December 1999). Using the above values, the estimated rate of groundwater flow for the uppermost aquifer beneath the facility was calculated using the following modified Darcy equation: Vgw = Ki/ne January 2016 4 073-9603715 where Vgw = average linear velocity (feet/year), K = hydraulic conductivity (feet/year), i = horizontal hydraulic gradient, and ne = effective porosity. The average estimated linear groundwater flow velocity under the waste management unit is approximately 347.5 feet/year toward the northeast, which is generally consistent with previous estimates (Table 2). The linear velocity equation above makes the simplified assumptions of a homogeneous and isotropic aquifer. Therefore, this equation represents a likely average value for the uppermost aquifer and does not account for heterogeneous and/or anisotropic conditions that may be present in the uppermost aquifer at the facility. 2.0 FIELD PROGRAM, MONITORING RESULTS, AND DISCUSSION Field activities conducted as part of the November 2015 sampling event are discussed in the following sections. 2.1 Visual Inspection Program In detect a potential release at the earliest possible time, the visual inspection program is used at the active MSW and C&D landfills by the sampling personnel. This program includes physical indicators such as potential water table mounding beneath the waste management unit, physical examination of any stresses in biological communities, visible signs of leachate migration (i.e., leachate seeps), unexplained changes in soil characteristics, and any other change to the environment due to the waste management unit. During the November 2015 compliance monitoring event, no physical indicators of a potential release were observed in the vicinity of the waste management areas by the sampling personnel. 2.2 Well Network and Groundwater Elevation Measurements The current network of groundwater monitoring wells at the facility consists of 14 wells and two gravity groundwater intercept outfalls. Available monitoring well construction information for all site monitoring wells is summarized on Table 3, and the well locations are shown on Drawing 1. The well locations were selected to yield groundwater samples representative of the conditions in the uppermost aquifer underlying the facility, and to monitor for potential releases from the landfill unit. One upstream surface water monitoring point (SW-1) and two downstream surface water monitoring points (SW-4 and SW-5) are also monitored. Depth-to-water measurements are recorded to the nearest 0.01 foot prior to initiating groundwater purging and sampling activities. The respective groundwater level elevations for this event are presented in Table 1. The historical water level data are also shown on this table. As presented, recent groundwater elevation data for the monitoring well network indicate that the hydraulic head level in the uppermost aquifer beneath the facility is fairly consistent, with temporal variation from the long-term average limited to approximately 5 - 10 feet (plus or minus) under normal conditions. The range in fluctuation appears to be greatest in the upgradient background wells, MW-102A and MW-103A, which are located in a January 2016 5 073-9603715 groundwater recharge area. The range in fluctuation in the downgradient compliance wells, which are located near groundwater discharge areas, is less, presumably due to the stabilizing effect of the hydraulic discharge boundary. 2.3 November 2015 Monitoring Event Personnel from Golder visited the facility on November 9 - 11, 2015, to purge and sample monitoring wells, to sample the gravity groundwater intercepts, surface water monitoring points, and the facility’s leachate collection system. Depth-to-water measurements were obtained from the network monitoring wells to the nearest 0.01 foot using an electronic water level indicator prior to purging the wells. The respective groundwater level elevations for this event are presented in Table 1. The historical groundwater level elevation data are also shown on this table. Monitoring wells were purged and sampled using the dedicated pumps at the facility following low-flow micropurge procedures. Measurements of temperature, pH, specific conductivity, turbidity, dissolved oxygen, and oxidation reduction potential were recorded on approximately 3-minute intervals, depending on the purge rate. In general, the purge rate for each well was matched to the yield of the monitoring well, as determined by continuously monitoring the depth to the water, up to a maximum purge rate of 500 milliliters per minute. Purging was continued until stabilization was indicated by the water quality parameters. Prior to sampling, the laboratory-supplied sample containers were prepared. Each sample container was labeled with the sample identification number, sampling personnel, date and time of sample collection, project name and number, and requested chemical analyses. The required groundwater samples were collected directly from the dedicated Grundfos® or bladder pump’s discharge lines in the labeled, laboratory-supplied, pre-preserved sample containers after purging was completed based on stabilization of all water quality parameters. After collection, the samples were placed in a cooler on ice, under chain-of-custody control. Copies of the sampling logs are presented in Appendix A. Included in each log is a description of the sampling equipment, sampling method and location, field observations, and water quality measurements. The surface water samples were collected directly from the stream, by lowering the sample containers into the stream flow with the opening facing away from the current flow, taking care to prevent the overflow of the sample containers and to minimize sample-induced turbidity. Measurements of temperature, pH, specific conductivity, turbidity, dissolved oxygen, and oxygen reduction potential were measured directly from the stream and recorded during the collection of the surface water samples. January 2016 6 073-9603715 The leachate sample was collected directly from the leachate piping manifold in the area that serves as secondary containment for the leachate transportation vehicles. Measurements of temperature, pH, specific conductivity, and turbidity were recorded during the collection of the leachate sample. After collection, the surface water and leachate samples were placed in a cooler on ice, under chain-of- custody control. Copies of the sampling logs are presented in Appendix A. Included in each log is a description of the sampling equipment, sampling location, sampling method, field observations, and water quality measurements. 2.4 December 2015 Verification Groundwater Monitoring Event Golder personnel visited the facility on December 30, 2015, to re-sample GGI-1 Outfall to verify the cobalt concentration during the November 2015 event. The well was purged and sampled utilizing techniques as those described above. After collection, the sample was placed in a cooler on ice, under chain-of-custody control for analysis of total and dissolved cobalt. A copy of the sampling log is presented in Appendix A. Included in the log is a description of the sampling equipment, sampling method, field observations, location, and water quality measurements. 2.5 Laboratory Analysis Program The November 2015 groundwater, surface water, and leachate samples were submitted to Environmental Conservation Laboratories, Inc. (ENCO) of Cary, North Carolina under chain-of-custody control for analysis. As presented, groundwater, surface water, and leachate samples at the facility were analyzed for NC Appendix I constituents, with the exception of MW-100B which is only analyzed for the NC Appendix I list of inorganic constituents. Samples from C&D wells MW-1N, MW-2N, MW-3N, MW-4N, MW-5AN, and MW-5BN were also analyzed for other required parameters for C&D landfills, as specified in Title 15A NCAC 13B.0544 including tetrahydrofuran. The leachate sample was also analyzed for the other required leachate parameters. The samples were received at the laboratory in good condition and were properly preserved. 2.6 November 2015 Sampling Results Analytical results for the November 2015 groundwater, surface water, and leachate samples are summarized in Tables 4, 5, 6, 7, 8, 9, and 10 along with available historical data. The laboratory certificates-of-analysis, chain-of-custody form, and laboratory data reviews for the sampling event are included in Appendix B. January 2016 7 073-9603715 As presented, seven inorganic constituents (antimony, chromium, cobalt, copper, and zinc) were detected at concentrations above their respective Solid Waste Section Limits (SWSLs) in samples from one or more downgradient compliance monitoring points at the active MSW landfill during the November 2015 monitoring event. At the C&D facility, four NC Appendix I inorganic constituents (arsenic, barium, chromium, and copper) were detected at concentrations above their respective SWSLs in samples from downgradient monitoring wells during the November 2015 monitoring event. No NC Appendix I organic constituents were detected in samples from groundwater or surface water monitoring points during the event above SWSLs. Barium, beryllium, cobalt, and zinc were detected at one or more downstream monitoring points above the SWSLs during this event. Also, leachate results were consistent with historical data for this facility. 2.7 December 2015 Verification Sampling Results The sample collected on December 30, 2015 from GGI-1 was analyzed for total and dissolved cobalt. Both concentrations were similar to the original value and indicate that if turbidity is biasing results high as evidenced by relatively high field turbidity values, the particulates are fine-grained. 3.0 LABORATORY AND FIELD QA/QC A field blank was collected by Golder personnel as part of the November 2015 groundwater sampling events. In addition to the field blank, a laboratory-prepared trip blank accompanied the volatile sample containers to and from the laboratory. ENCO analyzed the field blank for NC Appendix I constituents and the trip blank for NC Appendix I volatile organic compounds. Reviews of the laboratory data were performed by Golder personnel and are included in Appendix B. No constituents were detected in the method blank or field blank during this event and no data qualification was necessary. 4.0 DATA EVALUATION The results of the data evaluations are presented in the following sections. 4.1 North Carolina Groundwater and Surface Water Standard Comparisons At the MSW facility, concentrations of antimony, chromium, and cobalt exceeded the groundwater standards and SWSLs during this event at one or more downgradient well. As described below, the concentrations of antimony and chromium were determined to be below background and no further action is warranted. The concentration of cobalt was determined to represent a statistically significant increase over background concentrations at GGI-1 Outfall and is described further below. Cobalt and vanadium were reported at estimated concentrations below the SWSLs but above the Solid Waste Section Standard (SWS GWPS) in samples from one or more downgradient monitoring points during this event; no further action is required since concentrations are estimated and consistent with historical data. January 2016 8 073-9603715 At the C&D facility, arsenic and chromium were reported at quantifiable concentrations above the NC 2L Standard in the samples collected from one or more downgradient wells during this event. As described below, the concentrations of arsenic and chromium were determined to be below background and no further action is warranted. Cobalt and vanadium were also reported at estimated concentrations below the SWSLs but above applicable groundwater standards in one or more monitoring points during this event; no further action is required for these detections because the concentrations are estimated. Indicator parameters iron and manganese were reported at concentrations above their respective SWSLs and NC 2L Groundwater Standards in samples from one or more downgradient C&D wells during the event, as they have been during previous events and appear to be naturally occurring based on statistical analysis. Zinc was detected at downstream monitoring points SW-4 and SW-5 during this event above the SWSL and applicable surface water standard; concentrations may be biased high by turbidity due to heavy rains preceding the sampling event. Silver and acetone were also detected at SW-5 at estimated concentrations below the SWSLs but above applicable groundwater standards. No other NC Appendix I constituents were reported above applicable surface water standards from samples collected from the downstream surface water monitoring points during the November 2015 event. 4.2 Statistical Evaluations As presented above, antimony, cobalt, and chromium at the active MSW facility and arsenic, chromium, iron, and manganese at the active C&D facility were detected above their respective SWSLs and applicable groundwater standards in samples from one or more downgradient compliance monitoring points during the November 2015 monitoring event. In order to determine the source of these concentrations, statistical analyses were performed as allowed by 15A NCAC 13B.1632 (g) and (h). The concentrations of the constituents detected in downgradient monitoring wells were statistically evaluated to determine if the reported concentrations exceeded the facility background concentrations. The summary tables for statistical analyses and statistical worksheets are presented as Appendix C. Based on statistical evaluations, the concentrations of the aforementioned metals are below background and appear to be naturally occurring, with the exception of cobalt in the sample from GGI Outfall 1, which was statistically significant. Verification sampling confirmed the original results and total and dissolved concentrations were similar; however, the field turbidity values were high for the November and December 2015 sampling events. 5.0 CONCLUSIONS The above-standard concentrations of cobalt at GGI-1 Outfall do not appear to be biased significantly high by turbidity, although elevated turbidity was noted at the location during both sampling events and fine-grained particulates may bias results high. Based on information provided by the Waste Industries and their engineering firm, there was a connection being made to the GGI system during both the initial and re-sample time period in which a portion of the GGI system was open for connection and silt was January 2016 9 073-9603715 known to have entered the system. The sediment has sediment in the system was cleaned as best possible in early 2016; however, sediment build up may take additional time to clear out. There were no leachate indicators noted for this sample or other atypical results aside from relatively high metals concentrations. Therefore, we recommend reviewing the results from the next semi-annual event to determine if additional action is warranted. Based on the results summarized herein, Sampson County Disposal, LLC will continue monitoring the uppermost aquifer beneath this facility in accordance with the requirements of the Detection Monitoring Program as outlined in Title 15A NCAC 13B.1633 and .0544. The next sampling event is tentatively scheduled for May 2016. 6.0 REFERENCES GNRA (G.N. Richardson & Associates, Inc.), Raleigh, NC, December 2006, Water Quality and Leachate Monitoring Report-November 2006 Semi-annual Monitoring Event. GNRA (G.N. Richardson & Associates, Inc.), Raleigh, NC, July 2006, Water Quality and Leachate Monitoring Report-November 2006 Semi-annual Monitoring Event. GNRA (G.N. Richardson & Associates, Inc.), Raleigh, NC, December 1999, Water Quality and Leachate Monitoring Report-November 1999 Semi-annual Monitoring Event. GNRA (G.N. Richardson & Associates, Inc.), Raleigh, NC, November 2000, Water Quality Monitoring Plan, Permit Area 82-02 MSW Landfill Phase 2. GNRA (G.N. Richardson & Associates, Inc.), Raleigh, NC, September 2004, Revised July 2005, Water Quality Monitoring Report-Sampson County Landfill-NPE Landfills. NCGS (North Carolina Geologic Survey), 1985, Geologic Map of North Carolina. NCGS (North Carolina Geologic Survey), 1960, Geology and Groundwater of Goldsboro Area. S&ME (S&ME, Inc.), Charlotte, NC, August 1992, Site Suitability Update for Sampson County Municipal Solid Waste Landfill. G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Final\Final Sampson Active 2nd Semi-Annual WQMR November 2015.docx TABLES January 2016 Page 1 of 1 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx TOC Elevation (ft AMSL) Date GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW 11/5/2002 136.90 12.18 125.76 4.10 124.55 5.00 128.18 10.14 124.72 10.71 123.73 11.46 ------------133.43 15.00 ----128.30 15.11 127.75 11.71 ----121.26 14.155/29/2003 141.83 7.25 126.51 3.35 126.60 2.95 131.37 6.95 127.71 7.72 127.44 7.75 ------------136.48 11.95 ----130.29 13.12 129.04 10.42 ----122.71 12.7011/5/2003 ----------------------------156.32 6.60 155.83 5.87 ------------------------5/25/2004 ------------------------------------------------------------ 11/23/2004 ------------------------------------------------------------5/16-17/2005 137.55 11.53 126.15 3.71 125.27 4.28 128.85 9.47 125.71 9.72 125.21 9.98 ----151.51 11.41 150.36 11.34 133.09 15.34 ----128.37 15.04 127.84 11.62 ----121.01 14.4011/25/2005 ------------------------------------------------------------5/24/2006 ------------------------------------------------------------11/20/2006 ----------------128.03 7.40 127.07 8.12 ----154.78 8.14 153.56 8.14 133.63 14.80 ----128.54 14.87 128.83 10.63 ----121.64 13.77 5/21-22/2007 138.93 10.15 126.15 3.71 125.20 4.35 129.01 9.31 126.13 9.30 125.57 9.62 ----153.68 9.24 152.89 8.81 132.47 15.96 125.38 7.14 128.08 15.33 127.96 11.50 ----121.16 14.2511/12-15/2007 136.00 13.08 125.14 4.72 123.72 5.83 127.34 10.98 124.41 11.02 124.01 11.18 ----146.87 16.05 146.21 15.49 131.92 16.51 124.82 7.70 127.74 15.67 127.03 12.43 126.62 12.73 121.19 14.225/27-29/2008 139.04 10.04 125.69 4.17 125.75 3.80 128.87 9.45 126.04 9.39 125.48 9.71 ----152.14 10.78 151.42 10.28 132.67 15.76 125.18 7.34 128.14 15.27 127.41 12.05 126.79 12.56 121.26 14.1511/17-20/2008 140.02 9.06 126.38 3.48 126.19 3.36 130.07 8.25 127.36 8.07 126.47 8.72 ----151.47 11.45 150.78 10.92 132.00 16.43 125.87 6.65 127.79 15.62 127.95 11.51 127.43 11.92 122.10 13.315/26-27/2009 139.04 10.04 125.82 4.04 125.50 4.05 128.71 9.61 126.42 9.01 125.61 9.58 ----150.01 12.91 149.75 11.95 131.87 16.56 125.27 7.25 127.32 16.09 127.11 12.35 126.31 13.04 121.19 14.22 11/9-11/2009 135.98 13.10 125.20 4.66 124.02 5.53 127.53 10.79 124.76 10.67 124.22 10.97 ----146.26 16.66 145.98 15.72 130.43 18.00 124.82 7.70 126.11 17.30 125.06 14.40 125.27 14.08 120.26 15.155/24-26/2010 140.21 8.87 126.38 3.48 126.33 3.22 130.92 7.40 128.93 6.50 127.23 7.96 --18.14 150.71 12.21 152.33 9.37 132.11 16.32 125.84 6.68 127.31 16.10 127.44 12.02 127.03 12.32 122.54 12.8711/15-17/2010 138.31 10.77 125.80 4.06 125.47 4.08 128.97 9.35 126.15 9.28 125.53 9.66 --21.81 149.92 13.00 149.22 12.48 131.75 16.68 125.02 7.50 126.59 16.82 125.51 13.95 125.31 14.04 120.57 14.845/9-11/2011 136.08 13.00 125.87 3.99 124.99 4.56 128.47 9.85 125.57 9.86 124.94 10.25 --20.60 147.63 15.29 146.92 14.78 131.18 17.25 125.10 7.42 126.20 17.21 125.55 13.91 124.96 14.39 120.71 14.7011/14/2011 135.53 13.55 125.71 4.15 124.15 5.40 127.48 10.84 124.23 11.20 124.18 11.01 --22.20 145.66 17.26 145.24 16.46 130.21 18.22 125.04 7.48 125.28 18.13 124.99 14.47 124.75 14.60 120.01 15.40 5/7/2012 135.08 14.00 125.72 4.14 124.22 5.33 126.52 11.80 124.12 11.31 123.69 11.50 137.88 23.80 145.77 17.15 145.25 16.45 127.93 20.50 125.05 7.47 125.31 18.10 <121.81 --124.35 15.00 120.09 15.3211/5/2012 134.32 14.76 125.08 4.78 122.74 6.81 125.63 12.69 122.60 12.83 122.47 12.72 137.40 24.28 145.20 17.72 144.72 16.98 129.59 18.84 124.54 7.98 124.77 18.64 123.71 15.75 123.56 15.79 118.80 16.615/13/2013 134.53 14.55 125.80 4.06 124.30 5.25 127.42 10.90 124.10 11.33 123.63 11.56 137.27 24.41 144.64 18.28 144.52 17.18 130.81 17.62 125.03 7.49 125.27 18.14 125.30 14.16 124.76 14.59 119.89 15.5211/11/2013 135.74 13.34 125.65 4.21 124.28 5.27 127.05 11.27 123.71 11.72 123.61 11.58 138.36 23.32 146.05 16.87 145.59 16.11 130.41 18.02 124.79 7.73 124.91 18.50 123.71 15.75 123.37 15.98 118.79 16.625/12-13/2014 137.34 11.74 126.05 3.81 125.44 4.11 128.63 9.69 125.53 9.90 125.02 10.17 139.62 22.06 146.31 16.61 147.60 14.10 132.37 16.06 125.19 7.33 126.53 16.88 125.36 14.10 124.94 14.41 120.09 15.32 11/17-19/2014 135.33 13.75 125.51 4.35 123.50 6.05 126.62 11.70 123.48 11.95 123.79 11.40 138.08 23.60 143.63 19.29 144.75 16.95 130.13 18.30 124.47 8.05 124.91 18.50 123.86 15.60 123.50 15.85 118.62 16.795/12/2015 138.35 10.73 126.64 3.22 126.48 3.07 130.30 8.02 128.06 7.37 126.54 8.65 139.96 21.72 147.46 15.46 148.97 12.73 133.50 14.93 125.74 6.78 126.96 16.45 126.84 12.62 126.13 13.22 121.76 13.6511/9/2015 137.66 11.42 126.66 3.20 126.40 3.15 129.49 8.83 126.83 8.60 125.92 9.27 139.10 22.58 146.04 16.88 147.65 14.05 133.48 14.95 125.64 6.88 125.81 17.60 126.69 12.77 126.14 13.21 121.14 14.27MEAN137.32 11.76 125.89 3.97 125.00 4.55 128.45 9.87 125.66 9.77 125.06 10.13 138.46 22.38 148.67 14.25 148.55 13.15 131.88 16.55 125.16 7.37 126.84 16.57 126.43 13.03 125.37 13.98 120.76 14.65MAXIMUM141.83 14.76 126.66 4.78 126.60 6.81 131.37 12.69 128.93 12.83 127.44 12.72 139.96 24.41 156.32 19.29 155.83 17.18 136.48 20.50 125.87 8.05 130.29 18.64 129.04 15.75 127.43 15.98 122.71 16.79MINIMUM134.32 7.25 125.08 3.20 122.74 2.95 125.63 6.95 122.60 6.50 122.47 7.75 137.27 18.14 143.63 6.60 144.52 5.87 127.93 11.95 124.47 6.65 124.77 13.12 <121.81 10.42 123.37 11.92 118.62 12.70 Notes:1. GW Elev = Groundwater elevation in feet above mean sea level (AMSL)2. DTW = Depth to Water (measured in feet below top of casing)3. -- = no data available 4. TOC = top of casing5. MW = monitoring well6. TOC and Water Elevation Data for dates prior to May 2007 from available historical G.N. Richardson & Associates, Inc. Semi-Annual Monitoring Event Reports and S&ME historical reports. 6. Top of cas EPA MCL = 10 ug/L TABLE 1 Summary of Historical Groundwater Elevation DataSampson County Active MSW/C&D Landfill, Permit No. 82-02Sampson County, North Carolina MW-1N MW-107DMW-107SMW-106MW-105AMW-104MW-103AMW-102AMW-5ANMW-4NMW-3NMW-2N MW-108MW-100BMW-5BN 148.43161.70162.92 Monitoring Well 149.08 135.41132.52 143.41 139.46 139.35135.19135.43138.32129.55129.86 161.68 January 2016 Page 1 of 1 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Gradient Calculation Segment Flow Direction Gradient Segment Length (feet) Hydraulic Conductivity (K, feet/year) Horizontal Gradient (i, feet) Effective Porosity (ne) Hydraulic Conductivity (K, cm/sec) Velocity (Vgw, feet/year) 150125 140 120135130 Notes: 1. Horizontal velocities based on the modified Darcy equation Vgw = Ki/ne.2. Values for K and ne were based on mean values for MW-104, MW-106, MW-107S, MW-107D and MW-108 referenced in the December 1999 G.N. Richardson and Associates, Inc. Water Quality and Leachate Monitoring Report . TABLE 2 Summary of Estimated Horizontal Flow Velocities November 2015 i1 4615 0.25 290.350.012950.0054ENE Sampson County Active MSW/C&D Landfill, Permit No. 82-02Sampson County, North Carolina ENE NE i2 i3 417.66 334.67 0.25 0.25 0.01295 0.01295 2566 801 0.0078 0.0062 January 2016 Page 1 of 1 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx MW-100B 446881.50 2161983.42 4/14/2010 157.27 160.30 35 2 25-35 132.27-122.27 Sand/Silt Active MW-102A 448225.98 2159230.55 9/15/2003 --162.92 20 2 5-20 157.92-142.92 Sand/Clay Active MW-103A 447029.28 2159719.61 9/16/2003 --161.70 20 2 5-20 156.70-141.70 Clay Active MW-104 449816.45 2162418.65 ----148.43 20 2 10-20 138.43-128.43 --Active MW-105A 448119.79 2163946.35 1/30/2007 129.89 132.52 20 2 8-18 121.89-111.89 Sandy/Clay Active MW-106 449849.25 2163520.87 11/1/1999 --143.41 20 2 5-20 138.41-123.41 --Active MW-107S 449277.51 2163653.85 11/1/1999 --139.46 17 2 5-15 134.46-124.46 --Active MW-107D 449322.35 2163623.42 11/1/1999 --139.35 30 2 15-25 124.35-114.35 --Water Levels MW-108 448660.92 2164058.43 10/29/1999 --135.41 25 2 15-25 120.41-110.41 --Active MW-1N 446776.69 2163484.24 7/25/1996 148.08 149.08 23 2 7.1-22.1 140.98-125.98 --Active (C&D) MW-2N 447798.67 2163861.27 7/26/1996 130.14 129.86 19.5 2 3-18 127.14-112.14 --Active (C&D) MW-3N 447777.94 2164462.97 7/24/1996 128.36 129.55 22.65 2 6-21 122.36-107.36 --Active (C&D) MW-4N 447010.66 2164647.47 7/26/2000 135.49 138.32 20 2 5-20 130.49-115.49 Sand Active (C&D) MW-5AN 446449.12 2164831.01 7/26/2000 132.41 135.43 20 2 5-20 127.41-112.41 Sand Active (C&D) MW-5BN 446434.33 2164844.62 7/26/2000 132.71 135.19 23 2 35-45 97.71-87.71 Sand Active (C&D) Notes:1. ft AMSL= feet above mean sea level 2. ft BGS= feet below ground surface 3. -- = no data available 4. Well depths based on field measurements taken during the May 2007 monitoring event for MW-104 and MW-108. 5. Well depths for all other wells based on well construction information provided by G.N. Richardson & Associates, Inc. 6. Top of casing elevation for MW-100B was modified and re-surveyed in May 2012. TABLE 3 Summary of Well Construction Information Sampson County Active MSW/C&D Landfill, Permit No. 82-02 Sampson County, North Carolina Well Identification Construction Date Well Status Screened Interval (ft AMSL) Ground Surface Elevation (ft AMSL) Top of Casing Elevation (ft AMSL) Well Depth (feet) Well Diameter (inches) Screened Interval (ft bgs) Geology of Screened IntervalNorthingEasting January 2016 Page 1 of 8 Project No. 0739603714.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Antimony ug/L 01/11/00 --10 14 --------ND --ND ND ND ------SWS GPS = 1 ug/L ug/L 02/21/00 --10 ND ------------------------ EPA MCL = 6 ug/L ug/L 02/22/00 --10 ----------------ND ND ------ug/L 10/10/00 --30 ND --------ND --ND ND ND ------ ug/L 07/12/01 --30 ND --------ND --ND ND ND ------ug/L 10/24/01 --30 ND --------ND --ND ----------ug/L 05/28/02 --30 ND --------ND --ND ---------- ug/L 11/05/02 --30 ND --------ND --ND ----------ug/L 05/29/03 --30 ND --------ND --ND ---------- ug/L 11/05/03 --30 ------ND ND ----------------ug/L 05/25/04 --30 ND ----ND ND ND --ND ----------ug/L 11/23/04 --30 ND ----ND ND ND --ND ND ND ------ ug/L 05/16/05 --30 ------ND ND ND --ND ND ND ------ug/L 11/25/05 --30 ------ND ND ND --ND ND ND ------ ug/L 05/24/06 --30 ------ND ND ND --ND ND ND ----NDug/L 11/20/06 --30 ------ND ND ND --ND ND ND ----NDug/L 05/22/07 --6 --ND --ND ND ND ND ND ND ND ----ND ug/L 11/13/07 --6 --ND --ND ND ND ND ND ND ND ----NDug/L 05/29/08 --6 --ND --ND ND ND ND ND ND ND ----ND ug/L 11/17/08 --6 --ND --ND ND ND ND ND ND ND ----NDug/L 05/26/09 --6 --ND --ND ND ND ND ND ND ND ----NDug/L 11/10/09 --6 --ND --ND 0.104 B 0.181 B ND ND ND 0.142 B ----0.0770 J ug/L 05/26/10 --6 ----ND ND ND 0.360 J ND ND ND ND ----NDug/L 11/15/10 --6 ----ND ND ND 0.309 J ND ND ND ND ----ND ug/L 05/09/11 --6 ----ND ND ND ND ND ND ND ND ----NDug/L 11/14/11 --6 ----ND ND ND ND ND ND ND ND ----NDug/L 05/07/12 --6 ----0.270 J ND 0.814 J ND ND ND Dry 0.290 J ----ND ug/L 11/05/12 --6 ----ND ND 0.612 J ND ND ND ND ND ND ND NDug/L 05/13/13 --6 ----ND ND 0.358 J ND ND ND ND ND ND ND ND ug/L 11/11/13 --6 ----0.427 J ND ND ND ND ND ND ND ND ND NDug/L 05/12/14 --6 ----0.253 J ND ND ND ND ND 0.253 J ND ND ND NDug/L 11/17/14 0.220 6 ----0.415 J 0.232 J 0.695 J ND ND ND ND ND 0.380 J ND ND ug/L 05/12/15 0.220 6 ----ND ND 0.848 J ND ND ND 0.650 J ND 3.21 J 0.291 J NDug/L 11/09/15 0.220 6 ----ND ND 0.868 J ND ND ND ND ND 6.84 ND ND Arsenic ug/L 01/11/00 --5 7.2 --------10.1 --8.04 ND ND ------NC 2L = 10 ug/L ug/L 02/21/00 --5 ND ------------------------EPA MCL = 10 ug/L ug/L 02/22/00 --5 ----------------ND ND ------ ug/L 10/10/00 --10 ND --------ND --ND ND ND ------ug/L 07/12/01 --10 ND --------ND --ND ND ND ------ ug/L 10/24/01 --10 ND --------ND --ND --ND ------ug/L 05/28/02 --10 ND --------ND --ND --ND ------ug/L 11/05/02 --10 ND --------ND --ND ND ND ------ ug/L 05/29/03 --10 ND --------ND --ND ND ND ------ug/L 11/05/03 --10 ------ND ND ---------------- ug/L 05/25/04 --10 ND ----ND ND ND --ND ND ND ------ug/L 11/23/04 --10 ND ----ND ND ND --ND ND ND ------ug/L 05/16/05 --10 ------ND ND ND --ND ND ND ------ ug/L 11/25/05 --10 ------ND ND ND --ND ND ND ------ug/L 05/24/06 --10 ------ND ND ND --ND ND ND ----ND ug/L 11/20/06 --10 ------ND ND ND --ND ND ND ----NDug/L 05/22/07 --10 --ND --ND ND 2.6 B ND ND 3.6 B ND ----2.2 Jug/L 11/13/07 --10 --5.7 B --3.3 B 2.4 B 6.2 B 2.0 B 4.6 B 5.0 B 4.1 B ----2.4 J ug/L 05/29/08 --10 --ND --2.3 B ND 12.1 B 4.6 B ND 2.0 B ND ----3.2 Jug/L 11/17/08 --10 --ND --ND 2.8 J 6.5 J ND ND 5.4 J ND ----ND ug/L 05/26/09 --10 --ND --ND ND 8.7 J ND ND 8.7 J 4.1 J ----NDug/L 11/10/09 --10 --4.02 J --ND ND 15.3 ND ND 17.3 4.01 J ----NDug/L 01/18/10 --10 ----------------21.7 ------ND ug/L 05/26/10 --10 ----ND ND ND 11.5 ND ND 12.4 4.31 J ----NDug/L 11/15/10 --10 ----ND ND ND 10.8 B ND ND 17.5 B 3.04 B ----3.98 J ug/L 05/09/11 --10 ----ND ND ND ND ND ND 16.7 8.31 J ----NDug/L 11/14/11 --10 ----ND ND 3.14 J 9.14 J 3.71 J ND 19.5 6.37 J ----NDug/L 01/17/12 --10 -------------------------- Arsenic (Dissolved)ug/L 01/17/12 --10 --------------------------ug/L 05/07/12 --10 ----ND ND ND 3.10 J ND ND Dry 3.32 J ----ND ug/L 11/05/12 --10 ----ND 3.27 B ND 6.67 B ND 3.70 B 29.7 4.32 B 5.25 B ND 4.48 JVerification Event ug/L 01/10/13 --10 ----------------5.80 J ------NDug/L 05/13/13 --10 ----ND ND ND 6.93 J ND ND ND ND ND ND ND ug/L 11/11/13 --10 ----ND ND 5.54 J 7.39 J ND 5.88 J 17.6 ND ND ND NDug/L 05/12/14 --10 ----ND ND ND ND ND 5.56 J ND ND ND ND ND ug/L 11/17/14 5.40 10 ----ND ND ND ND ND ND ND ND ND ND NDug/L 05/12/15 5.40 10 ----ND ND ND ND ND ND ND ND ND ND NDug/L 11/09/15 5.40 10 ----ND ND ND ND ND ND ND ND ND ND ND Barium ug/L 01/11/00 ----52.7 --------34.1 --17.8 28 17.5 ------NC 2L = 700 ug/L ug/L 02/21/00 ----65.4 ------------------------ EPA MCL = 2000 ug/L ug/L 02/22/00 --------------------30.4 14.7 ------ug/L 10/10/00 --500 ND --------ND --ND ND ND ------ug/L 07/12/01 --500 ND --------ND --ND ND ND ------ ug/L 10/24/01 --500 ND --------ND --ND --ND ------ug/L 05/28/02 --500 ND --------ND --ND --ND ------ ug/L 11/05/02 --500 ND --------ND --ND ND ND ------ug/L 05/29/03 --500 ND --------ND --ND ND ND ------ug/L 11/05/03 --500 ------ND ND ---------------- ug/L 05/25/04 --500 ND ----ND ND ND --ND ND ND ------ug/L 11/23/04 --500 ND ----ND ND ND --ND ND ND ------ ug/L 05/16/05 --500 ------ND ND ND --ND ND ND ------ug/L 11/25/05 --500 ------ND ND ND --ND ND ND ------ug/L 05/24/06 --500 ------ND ND ND --ND ND ND ----ND ug/L 11/20/06 --500 ------ND ND ND --ND ND ND ----NDug/L 05/22/07 --100 --146 --25 J 8.0 J 67.5 J 16.2 J 11.7 J 59.6 J 34 J ----0.3 J ug/L 11/13/07 --100 --158 --8.50 J 9.00 J 77.5 J 17.0 J 32.4 J 42.6 J 66.5 J ----0.2 Jug/L 05/29/08 --100 --140 --25.7 J 7.50 J 56.4 J 21.8 J 17.7 J 46.0 J 82.9 J ----0.60 Jug/L 11/17/08 --100 --126 --11.1 J 10.2 J 75.3 J 37.8 J 30.9 J 52.2 J 85.2 J ----ND ug/L 05/26/09 --100 --143 --7.72 J 16.8 J 72.7 J 26.8 J 26.7 J 46.7 J 62.2 J ----NDug/L 11/10/09 --100 --116 --11.6 J 14.8 J 71.4 J 27.6 J 34.7 J 41.8 J 51.1 J ----ND ug/L 05/26/10 --100 ----112 7.64 J 7.61 J 92.2 J 41.4 J 13.4 J 73.2 J 39.0 J ----NDug/L 11/15/10 --100 ----78.6 J 10.6 J 9.14 J 76.4 J 41.0 J 30.0 J 42.5 J 41.6 J ----NDug/L 05/09/11 --100 ----173 8.18 J 9.80 J 119 44.7 J 29.2 J 34.6 J 44.2 J ----ND ug/L 11/14/11 --100 ----185 7.25 J 10.5 J 226 38.8 J 29.1 J 39.9 J 43.9 J ----NDug/L 05/07/12 --100 ----275 10.9 J 10.9 J 107 38.5 J 57.5 J Dry 59.3 J ----ND ug/L 11/05/12 --100 ----206 9.58 J 14.2 J 53.3 J 33.3 J 26.9 J 33.8 J 50.0 J 205 49.8 J NDug/L 05/13/13 --100 ----288 9.63 J 12.8 J 40.2 J 34.8 J 22.2 J 23.9 J 35.7 J 217 78.1 J 1.21 Jug/L 11/11/13 --100 ----462 16.6 J 12.9 J 56.9 J 35.2 J 19.2 J 26.2 J 44.3 J 212 53.2 J 1.22 J ug/L 05/12/14 --100 ----906 15.8 J 9.11 J 30.6 J 37.3 J 29.8 J 24.3 J 54.2 J 247 68.0 J NDug/L 11/17/14 1.00 100 ----368 8.55 J 11.1 J 48.6 J 37.2 J 20.4 J 28.9 J 50.7 J 87.1 J 46.4 J 1.08 J ug/L 05/12/15 1.00 100 ----363 17.6 J 10.0 J 38.4 J 37.2 J 14.2 J 28.5 J 55.3 J 31.5 J 69.2 J NDug/L 11/09/15 1.00 100 ----247 10.8 J 11.0 J 56.7 J 39.8 J 18.7 J 28.2 J 65.7 J 42.9 J 18.9 J NDBerylliumug/L 01/11/00 --5 ND --------ND --ND ND ND ------ SWS GPS = 4 ug/L ug/L 02/21/00 --5 ND ------------------------EPA MCL = 4 ug/L ug/L 02/22/00 --5 ----------------ND ND ------ ug/L 10/10/00 --2 ND --------ND --ND ND ND ------ug/L 07/12/01 --2 ND --------ND --ND ND ND ------ug/L 10/24/01 --2 ND --------ND --ND --ND ------ ug/L 05/28/02 --2 ND --------ND --ND --ND ------ug/L 11/05/02 --2 ND --------ND --ND ND ND ------ ug/L 05/29/03 --2 ND --------ND --ND ND ND ------ug/L 11/05/03 --2 ------ND ND ------ND --------ug/L 05/25/04 --2 ND ----ND ND ND --ND ND ND ------ ug/L 11/23/04 --2 ND ----ND ND ND --ND ND ND ------ug/L 05/16/05 --2 ------ND ND ND --ND ND ND ------ ug/L 11/25/05 --2 ------ND ND ND --ND ND ND ------ug/L 05/24/06 --2 ------ND ND ND --ND ND ND ----NDug/L 11/20/06 --2 ------ND ND ND --ND ND ND ----ND ug/L 05/22/07 --1 --ND --ND ND ND ND ND 1.5 ND ----NDug/L 11/13/07 --1 --ND --ND ND ND ND ND 1.40 ND ----ND ug/L 05/29/08 --1 --ND --ND ND 0.70 J ND ND 1.00 ND ----NDug/L 11/17/08 --1 --ND --ND ND 0.40 J ND ND 1.60 ND ----NDug/L 05/26/09 --1 --0.14 J --ND 0.10 J 0.74 J ND ND 1.95 0.33 J ----ND ug/L 11/10/09 --1 --ND --ND ND 1.07 ND 0.108 J 5.47 0.227 J ----NDug/L 01/18/10 --1 ----------------4.64 ------0.201 J Beryllium (Dissolved)ug/L 01/18/10 --1 ----------------3.62 ------0.201 Jug/L 05/26/10 --1 ----ND ND ND 1.11 0.229 J 0.250 J 2.77 0.583 J ----NDug/L 11/15/10 --1 ----ND ND ND 0.887 B 0.385 B ND 5.16 0.280 B ----0.106 J ug/L 05/09/11 --1 ----ND ND ND 0.185 J 0.104 J 0.227 J 3.63 0.357 J ----NDug/L 11/14/11 --1 ----ND ND ND 0.560 J ND 0.134 J 4.04 0.413 J ----ND ug/L 05/07/12 --1 ----ND ND ND 0.538 J ND 0.657 J Dry 0.133 J ----NDug/L 11/05/12 --1 ----ND ND ND 0.450 J 0.113 J 0.287 J 5.32 0.303 J 0.254 J 0.170 J NDug/L 05/13/13 --1 ----ND ND ND 0.392 J ND ND 0.790 J 0.240 J 0.250 J 0.200 J ND ug/L 11/11/13 --1 ----ND ND ND 0.462 J 0.113 J 0.247 J 2.78 0.445 J 0.242 J 0.150 J NDug/L 05/12/14 --1 ----ND ND ND 0.214 J 0.106 J ND 0.142 J 0.755 J 0.231 J 0.280 J ND ug/L 11/17/14 0.100 1 ----ND ND ND 0.336 J 0.199 J 0.280 J 1.96 0.777 J ND 0.254 J NDug/L 05/12/15 0.100 1 ----ND ND ND ND ND ND ND 0.403 J ND 0.361 J NDug/L 11/09/15 0.100 1 ----ND ND ND 0.159 J ND ND 0.482 J 0.936 J 0.108 J ND ND GGI Outfall 2GGI Outfall 1MW-105A MW-106 MW-107S MW-108 SWSReporting Limit Upgradient TABLE 4 Summary of Groundwater Monitoring Results for MSW Wells Detected Constituents Sampson County Active MSW Landfill, Permit No. 82-02 Sampson County, North Carolina Blanks Downgradient MW-100 MW-100A MW-100B MW-102A MW-103A MW-104MDLDetected Monitoring Constituent/Parameter Reporting Units Sample Date January 2016 Page 2 of 8 Project No. 0739603714.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx GGI Outfall 2GGI Outfall 1MW-105A MW-106 MW-107S MW-108 SWSReporting Limit Upgradient TABLE 4 Summary of Groundwater Monitoring Results for MSW Wells Detected Constituents Sampson County Active MSW Landfill, Permit No. 82-02 Sampson County, North Carolina Blanks Downgradient MW-100 MW-100A MW-100B MW-102A MW-103A MW-104MDLDetected Monitoring Constituent/Parameter Reporting Units Sample Date Cadmium ug/L 01/11/00 --5 ND --------ND --6.38 ND ND ------NC 2L = 2 ug/L ug/L 02/21/00 --5 ND ------------------------ EPA MCL = 5 ug/L ug/L 02/22/00 --5 ----------------ND ND ------ug/L 10/10/00 --1 ND --------ND --ND ND ND ------ ug/L 07/12/01 --1 ND --------ND --ND ND ND ------ug/L 10/24/01 --1 ND --------ND --ND --ND ------ug/L 05/28/02 --1 ND --------ND --ND --ND ------ ug/L 11/05/02 --1 ND --------ND --ND ND ND ------ug/L 05/29/03 --1 ND --------ND --ND ND ND ------ ug/L 11/05/03 --1 ------ND ND 2 --------------ug/L 05/25/04 --1 ND ----ND ND ND --ND ND ND ------ug/L 11/23/04 --1 5 ----ND ND ND --ND 2 ND ------ ug/L 05/16/05 --1 ------ND ND ND --ND ND ND ------ug/L 11/25/05 --1 ------ND ND ND --ND 2 ND ------ ug/L 05/24/06 --1 ------ND ND ND --ND 1 ND ----NDug/L 11/20/06 --1 ------ND ND ND --ND 4 ND ----NDug/L 05/22/07 --1 --ND --ND ND ND ND ND ND ND ----ND ug/L 11/13/07 --1 --ND --ND ND ND ND ND ND ND ----NDug/L 05/29/08 --1 --ND --ND ND ND ND ND ND ND ----0.50 J ug/L 11/17/08 --1 --ND --ND ND ND ND ND ND ND ----NDug/L 05/26/09 --1 --ND --ND 0.23 J 0.39 J 0.09 J 0.75 J 0.84 J 0.18 J ----NDug/L 11/10/09 --1 --ND --ND ND 0.790 J ND ND ND ND ----ND ug/L 05/26/10 --1 ----ND ND ND 1.17 ND ND 1.66 ND ----NDug/L 11/15/10 --1 ----ND ND ND 0.973 J ND ND 1.56 ND ----ND ug/L 05/09/11 --1 ----ND ND ND ND ND ND 1.84 ND ----NDug/L 11/14/11 --1 ----0.490 J ND ND 0.782 J 0.405 J ND 2.81 0.407 J ----NDug/L 05/07/12 --1 ----ND ND ND 0.701 J ND ND Dry 0.952 J ----ND ug/L 11/05/12 --1 ----ND ND ND 0.559 J ND ND 1.68 0.564 J ND ND NDug/L 05/13/13 --1 ----0.424 J 0.384 J ND 0.664 J ND ND 1.73 0.749 J ND ND ND ug/L 11/11/13 --1 ----ND ND ND 0.705 J ND ND 1.97 0.608 J ND ND NDug/L 05/12/14 --1 ----ND ND ND 0.504 J ND ND ND 0.463 J ND ND NDug/L 11/17/14 0.360 1 ----ND ND ND 0.452 J ND ND 1.49 0.381 J ND ND ND ug/L 05/12/15 0.360 1 ----ND ND ND ND ND ND ND ND 0.534 J ND NDug/L 11/09/15 0.360 1 ----ND ND ND ND ND ND ND 0.440 J ND ND ND Chromium ug/L 01/11/00 --5 ND --------ND --ND ND 5.14 ------NC 2L = 10 ug/L ug/L 02/21/00 --5 ND ------------------------EPA MCL = 100 ug/L ug/L 02/22/00 --5 ----------------ND ND ------ ug/L 10/10/00 --10 ND --------ND --ND ND ND ------ug/L 07/12/01 --10 ND --------ND --ND ND ND ------ ug/L 10/24/01 --10 ND --------ND --ND --ND ------ug/L 05/28/02 --10 ND --------65 --ND --ND ------ug/L 11/05/02 --10 ND --------ND --ND ND ND ------ ug/L 05/29/03 --10 ND --------19 --ND ND ND ------ug/L 11/05/03 --10 ------ND ND ----11 ---------- ug/L 05/25/04 --10 ND ----ND ND 14 --23 12 ND ------ug/L 11/23/04 --10 ND ----77 ND 22 --73 ND ND ------ug/L 05/16/05 --10 ------ND ND ND --ND ND ND ------ ug/L 11/25/05 --10 ------ND ND ND --ND 19 ND ------ug/L 05/24/06 --10 ------ND ND 23 --ND 11 ND ----ND ug/L 11/20/06 --10 ------ND ND ND --ND ND ND ----NDug/L 05/22/07 --10 --ND --ND 2.3 J ND ND ND ND ND ----NDug/L 11/13/07 --10 --ND --2.0 J ND ND 5.9 J 6.4 J 13.7 ND ----ND ug/L 05/29/08 --10 --ND --ND ND ND 6.8 J ND ND ND ----NDug/L 11/17/08 --10 --ND --2.8 B ND ND 5.8 B ND ND 7.9 B ----4.9 J ug/L 05/26/09 --10 --0.8 J --ND 8.2 J 17.7 3.3 J ND 15.8 1.1 J ----NDug/L 11/10/09 --10 --1.87 J --7.90 J 3.75 J 6.13 J 2.32 J ND ND 2.21 J ----NDug/L 05/26/10 --10 ----ND ND 2.39 J 6.95 J ND ND 3.51 J 2.31 J ----ND ug/L 11/15/10 --10 ----ND 3.63 J 2.08 J 2.52 J 1.07 J ND 1.63 J ND ----NDug/L 05/09/11 --10 ----ND 2.82 J 6.80 J 9.16 J ND ND 6.80 J 3.27 J ----ND ug/L 11/14/11 --10 ----ND 2.67 J 4.26 J 4.21 J ND ND 3.82 J 3.05 J ----NDug/L 05/07/12 --10 ----ND 13.0 3.80 J 3.51 J ND 13.4 Dry 4.53 J ----NDug/L 11/05/12 --10 ----ND 1.36 J 3.78 J 4.36 J 1.29 J 2.46 J 3.62 J 2.42 J ND ND ND ug/L 05/13/13 --10 ----ND 11.4 7.12 J 8.38 J ND 2.71 J 2.63 J 5.10 J ND 1.82 J NDug/L 11/11/13 --10 ----ND 3.61 J 6.33 J 6.79 J 4.41 J 2.75 J 2.97 J 3.01 J 4.62 J 2.15 J ND ug/L 05/12/14 --10 ----ND 6.54 J 4.63 J 4.24 J 2.38 J 1.42 J ND 2.99 J ND ND NDug/L 11/17/14 1.40 10 ----ND 5.47 J 3.46 J 4.20 J 1.55 J 2.59 J 2.10 J 3.18 J ND ND NDug/L 05/12/15 1.40 10 ----1.81 B 12.8 4.88 B 7.62 B 1.91 B 3.26 B 6.12 B 3.02 B 6.75 B 2.10 B 1.82 J ug/L 11/09/15 1.40 10 ----ND 5.90 J 6.37 J 7.80 J ND 3.19 J 4.20 J 2.53 J 13.1 ND NDCobalt ug/L 01/11/00 --5 5.52 --------ND --ND ND ND ------ SWS GPS = 1 ug/L ug/L 02/21/00 --5 ND ------------------------EPA MCL = 100 ug/L ug/L 02/22/00 --5 ----------------ND ND ------ug/L 10/10/00 --10 ND --------ND --ND 39 ND ------ ug/L 07/12/01 --10 ND --------ND --ND 54 ND ------ug/L 10/24/01 --10 ND --------ND --ND --ND ------ ug/L 05/28/02 --10 ND --------ND --ND --ND ------ug/L 11/05/02 --10 ND --------ND --ND ND ND ------ug/L 05/29/03 --10 ND --------14 --ND 19 ND ------ ug/L 11/05/03 --10 ------ND ND 22 ----47 --------ug/L 05/25/04 --10 ND ----ND ND 20 --ND 104 ND ------ ug/L 11/23/04 --10 ND ----ND ND 14 --ND 117 ND ------ug/L 05/16/05 --10 ------ND ND ND --10 ND ND ------ug/L 11/25/05 --10 ------ND ND ND --ND 35 ND ------ ug/L 05/24/06 --10 ------ND ND ND --ND 32 ND ----NDug/L 11/20/06 --10 ------ND ND ND --ND 29 ND ----ND ug/L 05/22/07 --10 --ND --ND ND 20.2 ND ND 75 2.8 J ----NDug/L 11/13/07 --10 --ND --ND ND 11.1 3.0 J ND 34.2 7.8 J ----NDug/L 05/29/08 --10 --ND --ND ND 58.4 3.9 J ND 23.5 27.7 ----ND ug/L 11/17/08 --10 --ND --ND ND 21.6 5.9 J 1.1 J 68.0 7.2 J ----NDug/L 05/26/09 --10 --1.8 J --ND 0.8 J 35.3 2.4 J ND 59.4 11.4 ----ND ug/L 11/10/09 --10 --1.75 J --ND ND 39.0 3.94 J ND 121 6.78 J ----NDug/L 05/26/10 --10 ----ND ND ND 67.8 2.79 J ND 102 14.1 ----NDug/L 11/15/10 --10 ----ND ND ND 46.2 9.38 J 1.62 J 132 28.7 ----ND ug/L 12/21/10 --10 ------------------45.5 ----NDug/L 05/09/11 --10 ----1.51 J ND ND 4.21 J 2.50 J 1.23 J 105 48.2 ----ND ug/L 11/14/11 --10 ----2.43 J 1.12 J 1.39 J 16.1 2.76 J 2.02 J 103 38.2 ----NDug/L 01/17/12 --10 --------------------------Cobalt (Dissolved)ug/L 01/17/12 --10 -------------------------- ug/L 05/07/12 --10 ----1.15 J ND ND 9.55 J 1.72 J 10.0 Dry 23.6 ----NDVerification Event ug/L 07/11/12 --10 -------------------------- Cobalt (Dissolved)ug/L 07/11/12 --10 --------------------------ug/L 11/05/12 --10 ----1.66 J 1.22 J 2.18 J 12.4 2.75 J 2.28 J 139 27.5 3.48 J 3.49 J NDug/L 05/13/13 --10 ----ND ND 1.93 J 8.59 J 1.61 J 2.57 J 31.8 20.9 3.32 J 5.94 J ND ug/L 11/11/13 --10 ----ND ND 1.60 J 19.3 3.41 J 2.41 J 100 36.0 3.50 J 3.48 J NDug/L 05/12/14 --10 ----ND ND ND 8.49 J 2.54 J 1.15 J 4.59 J 38.4 2.93 J 6.21 J ND ug/L 11/17/14 1.10 10 ----ND ND 1.16 J 11.7 3.97 J 1.74 J 76.0 22.3 ND 3.22 J NDug/L 05/12/15 1.10 10 ----1.23 J 1.25 J 2.18 J 6.07 J 2.33 J 1.36 J 3.48 J 11.8 6.87 J 10.2 NDug/L 11/09/15 1.10 10 ----1.30 J ND ND 6.23 J 3.55 J 1.13 J 14.8 20.9 12.3 1.70 J ND Verification Event ug/L 12/30/15 1.10 10 --------------------16.7 --NDCobalt (Dissolved)ug/L 12/30/15 1.10 10 --------------------15.2 --ND Copper ug/L 01/11/00 --5 ND --------ND --ND ND ND ------NC 2L = 1000 ug/L ug/L 02/21/00 --5 ND ------------------------EPA MCL = 1300 ug/L#ug/L 02/22/00 --5 ----------------ND ND ------ ug/L 10/10/00 --200 ND --------ND --ND ND ND ------ug/L 07/12/01 --200 ND --------ND --ND ND ND ------ ug/L 10/24/01 --200 ND --------ND --ND --ND ------ug/L 05/28/02 --200 ND --------ND --ND --ND ------ug/L 11/05/02 --200 ND --------ND --ND ND ND ------ ug/L 05/29/03 --200 ND --------ND --ND ND ND ------ug/L 11/05/03 --200 ------ND ND ---------------- ug/L 05/25/04 --200 ND ----ND ND ND --ND ND ND ------ug/L 11/23/04 --200 ND ----ND ND ND --ND ND ND ------ug/L 05/16/05 --200 ------ND ND ND --ND ND ND ------ ug/L 11/25/05 --200 ------ND ND ND --ND ND ND ------ug/L 05/24/06 --200 ------ND ND ND --ND ND ND ----ND ug/L 11/20/06 ----------ND ND ND --ND ND ND ----NDug/L 05/22/07 --10 --ND --ND ND ND ND ND ND ND ----NDug/L 11/13/07 --10 --ND --1.00 J 10.0 ND ND 3.90 J ND ND ----ND ug/L 05/29/08 --10 --ND --ND ND ND 1.00 B ND ND ND ----1.00 Jug/L 11/17/08 --10 --ND --ND ND ND ND 1.80 J ND ND ----ND ug/L 05/26/09 --10 --ND --1.00 B 1.49 B 4.37 B 1.20 B 1.76 B 2.44 B ND ----1.47 Jug/L 11/10/09 --10 --4.64 J --3.17 J 2.26 J ND ND ND 4.52 J ND ----NDug/L 05/26/10 --10 ----ND ND ND ND ND ND ND ND ----ND ug/L 11/15/10 --10 ----ND ND ND ND ND ND ND ND ----NDug/L 05/09/11 --10 ----ND ND ND ND ND 4.99 J 10.6 3.88 J ----ND ug/L 11/14/11 --10 ----6.65 J ND ND ND 2.69 J 2.12 J 156 2.31 J ----NDug/L 05/07/12 --10 ----ND 3.00 J ND ND ND 8.77 J Dry 6.32 J ----NDug/L 11/05/12 --10 ----ND ND ND ND ND 5.89 J 1.70 J ND ND ND ND ug/L 05/13/13 --10 ----ND 2.25 J ND ND ND ND 8.21 J 4.99 J ND 2.71 J NDug/L 11/11/13 --10 ----ND ND ND ND ND 36.6 ND 1.70 J ND ND ND ug/L 05/12/14 --10 ----2.94 J ND ND ND ND 40.3 ND 5.14 J 1.70 J ND NDug/L 11/17/14 1.60 10 ----ND ND ND ND ND 9.72 J ND 5.32 J ND ND NDug/L 05/12/15 1.60 10 ----ND ND ND ND ND 3.82 J 3.09 J 3.41 J 26.6 ND ND ug/L 11/09/15 1.60 10 ----ND ND ND ND ND ND 3.00 J 9.75 J 21.5 ND ND January 2016 Page 3 of 8 Project No. 0739603714.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx GGI Outfall 2GGI Outfall 1MW-105A MW-106 MW-107S MW-108 SWSReporting Limit Upgradient TABLE 4 Summary of Groundwater Monitoring Results for MSW Wells Detected Constituents Sampson County Active MSW Landfill, Permit No. 82-02 Sampson County, North Carolina Blanks Downgradient MW-100 MW-100A MW-100B MW-102A MW-103A MW-104MDLDetected Monitoring Constituent/Parameter Reporting Units Sample Date Lead ug/L 01/11/00 --5 5.12 --------ND --ND ND 5.42 ------NC 2L = 15 ug/L ug/L 02/21/00 --5 ND ------------------------EPA MCL = 15 ug/L#ug/L 02/22/00 --5 ----------------ND ND ------ug/L 10/10/00 --10 ND --------ND --ND 15 ND ------ ug/L 07/12/01 --10 ND --------ND --ND 17 ND ------ug/L 10/24/01 --10 ND --------ND --ND --ND ------ug/L 05/28/02 --10 ND --------11 --ND --ND ------ ug/L 11/05/02 --10 ND --------ND --ND ND ND ------ug/L 05/29/03 --10 ND --------ND --ND ND ND ------ ug/L 11/05/03 --10 ------ND ND ----------------ug/L 05/25/04 --10 ND ----ND ND ND --ND ND ND ------ug/L 11/23/04 --10 ND ----22 ND ND --ND ND ND ------ ug/L 05/16/05 --10 ------ND ND 41 --ND ND ND ------ug/L 11/25/05 --10 ------ND ND ND --ND ND ND ------ ug/L 05/24/06 --10 ------ND ND ND --ND ND ND ----NDug/L 11/20/06 --10 ------ND ND ND --ND ND ND ----NDug/L 05/22/07 --10 --ND --ND ND ND ND ND ND ND ----ND ug/L 11/13/07 --10 --ND --ND ND ND ND ND 3.4 J ND ----NDug/L 05/29/08 --10 --2.1 J --ND ND 4.7 J 2.7 J ND ND ND ----ND ug/L 11/17/08 --10 --ND --ND ND 3.5 J ND ND 3.9 J ND ----NDug/L 05/26/09 --10 --2.2 J --ND ND 11.3 ND ND 7.8 J ND ----NDug/L 11/10/09 --10 --ND --ND ND 8.24 J 1.91 J ND 16.4 2.32 J ----ND ug/L 05/26/10 --10 ----ND ND ND 9.50 J 1.91 J ND 11.2 4.13 J ----NDug/L 11/15/10 --10 ----2.56 J 2.68 J 1.95 J 7.87 J 2.59 J 2.34 J 13.5 4.31 J ----ND ug/L 05/09/11 --10 ----ND ND ND 2.18 J 2.53 J ND 11.8 3.33 J ----NDug/L 11/14/11 --10 ----ND ND ND 4.59 J ND ND 9.02 J ND ----NDug/L 01/17/12 --10 -------------------------- Lead (Dissolved)ug/L 01/17/12 --10 --------------------------ug/L 05/07/12 --10 ----ND ND ND 2.31 J ND 7.50 J Dry ND ----ND Verification Event ug/L 07/11/12 --10 --------------------------Lead (Dissolved)ug/L 07/11/12 --10 --------------------------ug/L 11/05/12 --10 ----ND ND ND 4.91 J ND ND 14.4 2.20 J ND 1.95 J ND ug/L 05/13/13 --10 ----ND ND ND 2.96 J ND ND ND ND ND ND NDug/L 11/11/13 --10 ----ND ND ND ND ND ND 5.04 J ND ND ND ND ug/L 05/12/14 --10 ----ND ND ND 2.79 J 2.42 J ND ND 2.73 J ND ND NDug/L 11/17/14 2.10 10 ----ND ND ND ND ND ND 5.80 J ND ND ND NDug/L 05/12/15 2.10 10 ----ND ND ND ND ND ND ND ND 10.9 ND ND ug/L 11/09/15 2.10 10 ----ND ND ND 5.88 J ND ND ND ND 5.55 J 4.21 J NDNickel ug/L 01/11/00 --5 ND --------ND --ND ND ND ------ NC 2L = 100 ug/L ug/L 02/21/00 --5 ND ------------------------No EPA MCL ug/L 02/22/00 --5 ----------------ND ND ------ug/L 10/10/00 --50 ND --------ND --ND ND ND ------ ug/L 07/12/01 --50 ND --------ND --ND ND ND ------ug/L 10/24/01 --50 ND --------ND --ND --ND ------ ug/L 05/28/02 --50 ND --------ND --ND --ND ------ug/L 11/05/02 --50 ND --------ND --ND ND ND ------ug/L 05/29/03 --50 ND --------ND --ND ND ND ------ ug/L 11/05/03 --50 ------ND ND ----------------ug/L 05/25/04 --50 ND ----ND ND ND --ND 86 ND ------ ug/L 11/23/04 --50 ND ----ND ND ND --ND 107 ND ------ug/L 05/16/05 --50 ------ND ND ND --ND ND ND ------ug/L 11/25/05 --50 ------ND ND ND --ND 61 ND ------ ug/L 05/24/06 --50 ------ND ND ND --ND ND ND ----NDug/L 11/20/06 --50 ------ND ND ND --ND ND ND ----ND ug/L 05/22/07 --50 --ND --ND 2.2 J 15.4 J ND ND 74.6 3.9 J ----NDug/L 11/13/07 --50 --ND --ND ND 7.8 J 8.2 J 8.7 J 49.4 J 8.3 J ----NDug/L 05/29/08 --50 --ND --ND ND 37.1 J 4.3 J ND 27.6 J 19.9 J ----ND ug/L 11/17/08 --50 --ND --2.8 B 2.2 B 17.6 J 5.7 B ND 64.9 20.9 J ----3.2 Jug/L 05/26/09 --50 --2.4 B --1.9 B 7.2 J 31.3 J 3.4 B 1.5 B 71.7 12.4 J ----0.7 J ug/L 11/10/09 --50 --ND --4.16 J 2.37 J 26.0 J ND ND 139 9.78 J ----NDug/L 01/18/10 --50 ----------------75.3 ------NDNickel (Dissolved)ug/L 01/18/10 --50 ----------------74.6 ------ND ug/L 05/26/10 --50 ----ND ND ND 49.0 J ND ND 98.3 17.6 J ----NDug/L 11/15/10 --50 ----ND 2.09 J ND 31.4 J 7.49 J ND 110 14.7 J ----ND ug/L 05/09/11 --50 ----ND 2.77 J 4.54 J 7.57 J 2.61 J 2.22 J 82.3 28.8 J ----NDug/L 11/14/11 --50 ----2.86 J 3.80 J 5.27 J 13.4 J 4.55 J 2.91 J 89.1 25.0 J ----NDug/L 05/07/12 --50 ----ND 8.30 J 3.30 J 7.05 J 2.55 J 15.8 J Dry 19.8 J ----ND ug/L 11/05/12 --50 ----ND 2.05 J 3.89 J 10.2 J 2.66 J 3.07 J 105 20.9 J 2.92 J 2.65 J NDug/L 05/13/13 --50 ----ND 8.13 J 6.65 J 9.46 J 2.29 J 2.61 J 24.1 J 16.9 J 3.36 J 5.23 J ND ug/L 11/11/13 --50 ----ND 2.42 J 3.45 J 14.5 J 3.63 J 3.98 J 69.5 29.0 J 3.50 J 2.78 J NDug/L 05/12/14 --50 ----ND 4.34 J 3.06 J 5.98 J 1.86 J ND 3.05 J 32.0 J 2.49 J 4.03 J NDug/L 11/17/14 1.80 50 ----ND 3.32 J 2.05 J 8.04 J 2.73 J 2.48 J 54.4 20.0 J 3.22 J ND ND ug/L 05/12/15 1.80 50 ----ND 8.15 B 3.98 B 6.92 B 2.63 B 1.98 B 6.67 B 11.2 J 17.0 J 12.3 J 1.89 Jug/L 11/09/15 1.80 50 ----ND 4.36 J 5.25 J 7.25 J 3.69 J 2.46 J 15.5 J 20.2 J 23.3 J 2.22 J ND Selenium ug/L 01/11/00 --5 ND ND ------ND --ND ND ND ------NC 2L = 20 ug/L ug/L 02/21/00 --5 ND ND ----------------------EPA MCL = 50 ug/L ug/L 02/22/00 --5 ----------------ND ND ------ ug/L 10/10/00 --20 ND ND ------ND --ND ND ND ------ug/L 07/12/01 --20 ND ND ------ND --ND ND ND ------ ug/L 10/24/01 --20 ND ND ------ND --ND --ND ------ug/L 05/28/02 --20 ND ND ------ND --ND --ND ------ug/L 11/05/02 --20 ND ND ------ND --ND ND ND ------ ug/L 05/29/03 --20 ND ND ------ND --ND ND ND ------ug/L 11/05/03 --20 ------ND ND ---------------- ug/L 05/25/04 --20 ND ND --ND ND ND --ND ND ND ------ug/L 11/23/04 --20 ND ND --ND ND ND --ND ND ND ------ug/L 05/16/05 --20 ------ND ND ND --ND ND ND ------ ug/L 11/25/05 --20 ------ND ND ND --ND ND ND ------ug/L 05/24/06 --20 ------ND ND ND --ND ND ND ----ND ug/L 11/20/06 --20 ------ND ND ND --ND ND ND ----NDug/L 05/22/07 --10 --ND --ND ND ND ND ND ND ND ----NDug/L 11/13/07 --10 --ND --ND 2.0 B ND ND ND ND ND ----3.1 J ug/L 05/29/08 --10 --ND --2.7 B 2.1 B ND 3.5 B ND ND ND ----2.1 Jug/L 11/17/08 --10 --ND --ND ND ND ND ND ND ND ----ND ug/L 05/26/09 --10 --ND --ND ND ND ND ND ND ND ----NDug/L 11/10/09 --10 --ND --ND ND ND ND ND ND ND ----NDug/L 05/26/10 --10 ----ND ND ND ND ND ND ND ND ----ND ug/L 11/15/10 --10 ----ND ND ND ND ND ND ND ND ----NDug/L 05/09/11 --10 ----ND ND ND ND ND ND ND ND ----ND ug/L 05/09/11 --10 ----ND ND ND ND ND ND ND ND ----NDug/L 11/14/11 --10 ----ND ND ND ND ND ND ND ND ----NDug/L 05/07/12 --10 ----ND ND ND 2.94 B ND ND Dry 3.13 (ND)B ----4.01 (ND)J ug/L 11/05/12 --10 ----ND ND ND ND ND ND ND ND ND ND NDug/L 05/13/13 --10 ----ND ND ND ND ND ND ND ND ND ND ND ug/L 11/11/13 --10 ----ND ND ND ND ND ND ND ND ND ND NDug/L 05/12/14 --10 ----ND ND ND ND ND ND ND ND ND ND NDug/L 11/17/14 5.00 10 ----ND ND ND ND ND ND ND ND ND ND ND ug/L 05/12/15 5.00 10 ----ND ND ND ND ND ND ND ND ND ND NDug/L 05/12/15 5.00 10 ----ND ND ND ND ND ND ND ND ND ND ND Silver ug/L 01/11/00 --5 ND ND ------ND --ND ND ND ------NC 2L = 20 ug/L ug/L 02/21/00 --5 ND ND ----------------------EPA MCL = 100 ug/L*ug/L 02/22/00 --------------------ND ND ------ ug/L 10/10/00 --10 ND ND ------ND --ND ND ND ------ug/L 07/12/01 --10 ND ND ------ND --ND ND ND ------ ug/L 10/24/01 --10 ND ND ------ND --ND --ND ------ug/L 05/28/02 --10 ND ND ------ND --ND --ND ------ug/L 11/05/02 --10 ND ND ------ND --ND ND ND ------ ug/L 05/29/03 --10 ND ND ------ND --ND ND ND ------ug/L 11/05/03 --10 ------ND ND ---------------- ug/L 05/25/04 --10 ND ND --ND ND ND --ND ND ND ------ug/L 11/23/04 --10 ND ND --ND ND ND --ND ND ND ------ug/L 05/16/05 --10 ------ND ND ND --ND ND ND ------ ug/L 11/25/05 --10 ------ND ND ND --ND ND ND ------ug/L 05/24/06 --10 ------ND ND ND --ND ND ND ----ND ug/L 11/20/06 --10 ------ND ND ND --ND ND ND ----NDug/L 05/22/07 --10 --ND --ND ND ND ND ND ND ND ----NDug/L 11/13/07 --10 --ND --ND ND ND ND ND ND ND ----ND ug/L 05/29/08 --10 --ND --ND ND ND 2.1 B ND ND ND ----2.9 Jug/L 11/17/08 --10 --ND --ND ND ND ND ND ND ND ----ND ug/L 05/26/09 --10 --ND --ND ND 33.5 ND ND ND ND ----NDug/L 07/23/09 --10 ----------ND ------------NDug/L 11/10/09 --10 --ND --ND ND ND ND ND ND ND ----ND ug/L 05/26/10 --10 ----ND ND ND ND ND ND ND ND ----NDug/L 11/15/10 --10 ----ND ND ND ND ND ND ND ND ----ND ug/L 05/09/11 --10 ----ND ND ND ND ND ND ND ND ----NDug/L 11/14/11 --10 ----ND ND ND ND ND ND ND ND ----NDug/L 05/07/12 --10 ----ND ND ND ND ND ND Dry ND ----ND ug/L 11/05/12 --10 ----ND ND ND ND ND ND ND ND ND ND NDug/L 05/13/13 --10 ----ND ND ND ND ND ND ND ND ND ND ND ug/L 11/11/13 --10 ----ND ND ND ND ND ND ND ND ND ND NDug/L 05/12/14 --10 ----ND ND ND ND ND ND ND ND ND ND NDug/L 11/17/14 1.90 10 ----ND ND ND ND ND ND ND ND ND ND ND ug/L 05/12/15 1.90 10 ----ND ND ND ND ND ND ND ND ND ND NDug/L 11/09/15 1.90 10 ----ND ND ND ND ND ND ND ND 1.91 J ND ND January 2016 Page 4 of 8 Project No. 0739603714.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx GGI Outfall 2GGI Outfall 1MW-105A MW-106 MW-107S MW-108 SWSReporting Limit Upgradient TABLE 4 Summary of Groundwater Monitoring Results for MSW Wells Detected Constituents Sampson County Active MSW Landfill, Permit No. 82-02 Sampson County, North Carolina Blanks Downgradient MW-100 MW-100A MW-100B MW-102A MW-103A MW-104MDLDetected Monitoring Constituent/Parameter Reporting Units Sample Date Thallium ug/L 01/11/00 --10 ND --------ND --ND ND ND ------SWS GPS = 0.28 ug/L ug/L 02/21/00 --10 ND ------------------------ EPA MCL = 2 ug/L ug/L 02/22/00 --10 ----------------ND ND ------ug/L 10/10/00 --10 ND --------ND --ND ND ND ------ ug/L 07/12/01 --10 ND --------ND --ND ND ND ------ug/L 10/24/01 --10 ND --------ND --ND --ND ------ug/L 05/28/02 --10 ND --------ND --ND --ND ------ ug/L 11/05/02 --10 ND --------ND --ND ND ND ------ug/L 05/29/03 --10 ND --------ND --ND ND ND ------ ug/L 11/05/03 --10 ------ND ND ----------------ug/L 05/25/04 --10 ND ----ND ND ND --ND ND ND ------ug/L 11/23/04 --10 ND ----ND ND ND --ND ND ND ------ ug/L 05/16/05 --10 ------ND ND ND --ND ND ND ------ug/L 11/25/05 --10 ------ND ND ND --ND ND ND ------ ug/L 05/24/06 --10 ------ND ND ND --ND ND ND ----NDug/L 11/20/06 --10 ------ND ND ND --ND ND ND ----NDug/L 05/22/07 --5.5 --0.108 J --ND ND ND ND ND 0.07 J ND ----ND ug/L 11/13/07 --5.5 --0.093 J --ND ND ND ND ND ND 0.052 J ----NDug/L 05/29/08 --5.5 --0.090 J --ND 0.047 J ND ND ND ND 0.066 J ----ND ug/L 11/17/08 --5.5 --0.070 J --ND ND 0.044 J ND ND 0.045 J ND ----NDug/L 05/26/09 --5.5 --ND --ND ND ND ND ND ND ND ----NDug/L 11/10/09 --5.5 --ND --ND ND ND ND ND 2.31 J ND ----ND ug/L 05/26/10 --5.5 ----ND ND ND ND ND ND ND ND ----NDug/L 11/15/10 --5.5 ----ND ND ND ND ND ND ND ND ----ND ug/L 05/09/11 --5.5 ----ND ND ND ND ND ND ND ND ----NDug/L 11/14/11 --5.5 ----ND ND ND ND ND ND ND ND ----NDug/L 05/07/12 --5.5 ----0.115 J ND 0.150 J ND ND ND Dry 0.146 J ----ND ug/L 11/05/12 --5.5 ----ND ND ND ND ND ND ND ND ND ND NDug/L 05/13/13 --5.5 ----0.121 J ND ND ND ND ND ND ND ND ND ND ug/L 11/11/13 --5.5 ----0.147 J ND ND ND ND ND ND ND ND ND NDug/L 05/12/14 --5.5 ----0.202 J ND ND ND ND ND ND ND ND ND NDug/L 11/17/14 0.110 5.5 ----0.155 J ND ND ND ND ND ND ND ND ND ND ug/L 05/12/15 0.110 5.5 ----0.130 J ND ND ND ND ND ND ND 0.189 J ND NDug/L 11/09/15 0.110 5.5 ----ND ND ND ND ND ND ND ND ND ND ND Vanadium ug/L 01/11/00 --5 5.71 --------ND --ND 5.08 12 ------SWS GPS = 0.3 ug/L ug/L 02/21/00 --5 ND ------------------------No EPA MCL ug/L 02/22/00 --5 ----------------ND ND ------ ug/L 10/10/00 --40 ND --------ND --ND ND ND ------ug/L 07/12/01 --40 ND --------ND --ND ND ND ------ ug/L 10/24/01 --40 ND --------ND --ND --ND ------ug/L 05/28/02 --40 ND --------ND --ND --ND ------ug/L 11/05/02 --40 ND --------ND --ND ND ND ------ ug/L 05/29/03 --40 ND --------ND --ND ND ND ------ug/L 11/05/03 --40 ------ND ND ---------------- ug/L 05/25/04 --40 ND ----ND ND ND --ND ND ND ------ug/L 11/23/04 --40 ND ----0.059 ND ND --ND ND ND ------ug/L 05/16/05 --40 ------ND ND ND --ND ND ND ------ ug/L 11/25/05 --40 ------ND ND ND --ND ND ND ------ug/L 05/24/06 --40 ------ND ND ND --ND ND ND ----ND ug/L 11/20/06 --40 ------ND ND ND --ND ND ND ----NDug/L 05/22/07 --25 --ND --ND ND ND ND ND ND 6.5 J ----NDug/L 11/13/07 --25 --4.6 J --ND ND ND ND ND ND 6.4 J ----ND ug/L 05/29/08 --25 --3.0 B --ND ND ND 6.7 J ND ND ND ----1.2 Jug/L 11/17/08 --25 --ND --ND ND ND ND ND ND 33.3 ----ND ug/L 02/17/09 --25 ------------------14.3 J ----NDug/L 05/26/09 --25 --4.1 J --0.7 J 1.3 J 7.5 J 4.0 J 0.7 J 10.0 J 23.4 J ----NDug/L 11/10/09 --25 --2.33 J --3.59 J ND ND ND ND 8.07 J 18.0 J ----ND ug/L 05/26/10 --25 ----ND ND ND ND ND ND ND 1.63 J ----NDug/L 11/15/10 --25 ----ND 1.52 J ND ND 1.44 J ND 7.07 J 7.49 J ----ND ug/L 05/09/11 --25 ----ND ND ND ND ND ND 3.14 J 1.53 J ----NDug/L 11/14/11 --25 ----ND ND ND ND 6.74 J ND ND 21.2 J ----NDug/L 01/17/12 --25 -------------------------- Vanadium (Dissolved)ug/L 01/17/12 --25 --------------------------ug/L 05/07/12 --25 ----ND 3.49 J ND ND ND 12.6 J Dry 2.83 J ----ND Verification Event ug/L 07/11/12 --25 --------------------------Vanadium (Dissolved)ug/L 07/11/12 --25 --------------------------ug/L 11/05/12 --25 ----ND ND ND ND 1.52 J 1.82 J ND ND ND ND ND ug/L 05/13/13 --25 ----ND ND ND ND ND ND ND ND ND ND NDug/L 11/11/13 --25 ----ND ND ND ND 2.64 J ND ND 4.21 J ND ND ND ug/L 05/12/14 --25 ----ND ND ND ND 24.7 J ND ND ND ND ND NDug/L 11/17/14 1.40 25 ----ND ND ND ND 11.1 J ND ND 8.34 J ND ND NDug/L 05/12/15 1.40 25 ----ND ND ND ND 11.7 J ND ND ND 3.31 J ND ND ug/L 11/09/15 1.40 25 ----ND ND ND ND 12.3 J ND 8.84 J 1.90 J 4.61 J 4.40 J NDZinc ug/L 01/11/00 --5 8.05 --------5.59 --10.8 5.45 10.3 ------ NC 2L = 1000 ug/L ug/L 02/21/00 --5 ND ------------------------EPA MCL = 5000 ug/L*ug/L 02/22/00 --5 ----------------ND 5.83 ------ug/L 10/10/00 --50 ND --------ND --ND 80 ND ------ ug/L 07/12/01 --50 ND --------ND ----92 ND ------ug/L 10/24/01 --20 ND --------ND --ND --ND ------ ug/L 05/28/02 --50 ND --------ND --ND --ND ------ug/L 11/05/02 --50 ND --------ND --ND ND ND ------ug/L 05/29/03 --50 ND --------ND --ND ND ND ------ ug/L 11/05/03 --50 ------ND ND ------65 --------ug/L 05/25/04 --50 ND ----ND ND ND --ND 293 ND ------ ug/L 11/23/04 --50 ND ----ND ND ND --ND 443 ND ------ug/L 05/16/05 --50 ------ND ND ND --ND ND ND ------ug/L 11/25/05 --50 ------ND ND ND --ND 203 ND ------ ug/L 05/24/06 --50 ------ND ND ND --ND 87 ND ----NDug/L 11/20/06 --50 ------ND ND ND --ND 117 ND ----ND ug/L 05/22/07 --10 --2.3 J --ND ND 27.2 1.5 J ND 234 2.9 J ----NDug/L 11/13/07 --10 --ND --ND ND 18.0 2.5 J 217 133 17.5 ----NDug/L 01/09/08 --10 --------------3.7 J --------ND ug/L 05/29/08 --10 --2.5 B --1.6 B ND 96.2 10.2 1.9 B 75.5 25.6 ----1.8 Jug/L 11/17/08 --10 --17.6 B --ND ND 35.6 4.7 B 6.2 B 195 12.8 B ----4.6 J ug/L 05/26/09 --10 --6.7 J --5.9 J 3.7 J 55.4 5.2 J 17.5 183 12.7 ----NDug/L 11/10/09 --10 --5.18 J --ND ND 57.6 ND ND 449 12.0 ----NDug/L 01/18/10 --10 ----------------233 ------ND Dissolved Zinc ug/L 01/18/10 --10 ----------------231 ------NDug/L 05/26/10 --10 ----5.46 J ND ND 126 ND ND 294 8.72 J ----ND ug/L 11/15/10 --10 ----ND ND ND 105 40.1 ND 323 39.1 ----NDug/L 05/09/11 --10 ----ND ND ND 5.15 J 7.32 J 11.4 257 52.8 ----NDug/L 11/14/11 --10 ----ND ND ND 26.5 6.30 J 3.91 J 355 28.4 ----ND ug/L 05/07/12 --10 ----ND ND ND 11.8 ND 18.4 Dry 56.8 ----NDug/L 11/05/12 --10 ----ND ND ND 14.6 ND 7.81 J 274 14.3 9.63 J 7.73 J ND ug/L 05/13/13 --10 ----4.86 J ND ND 5.85 J 5.25 J 5.13 J 108 26.4 10.2 16.2 NDug/L 11/11/13 --10 ----ND ND ND 15.2 12.4 26.4 211 50.5 15.8 15.0 NDug/L 05/12/14 --10 ----ND ND ND 4.16 J 9.00 J 12.7 10.0 69.3 11.8 19.6 ND ug/L 11/17/14 3.80 10 ----ND ND ND 8.92 J 12.4 4.36 J 138 53.1 22.5 15.1 NDug/L 05/12/15 3.80 10 ----ND ND 5.43 J 9.49 J 7.63 J ND 6.75 J 26.3 190 26.2 ND ug/L 11/09/15 3.80 10 ----5.26 J ND ND 6.40 J 20.3 6.22 J 36.8 53.8 150 9.80 J NDAcetoneug/L 01/11/00 --10 ND --------ND --ND ND ND ------NC 2L = 6000 ug/L ug/L 02/21/00 --10 ND ------------------------ No EPA MCL ug/L 02/22/00 --10 ----------------ND ND ------ug/L 10/10/00 --100 ND --------ND --ND ND ND ------ ug/L 07/12/01 --100 ND --------ND --ND ND ND ------ug/L 10/24/01 --100 ----------ND --ND --ND ------ug/L 05/28/02 --100 ND --------ND --ND --ND ------ ug/L 11/05/02 --100 ND --------ND --ND ND ND ------ug/L 05/29/03 --100 ND --------ND --ND ND ND ------ ug/L 11/05/03 --100 ND ----ND ND ND --ND ND ND ------ug/L 05/25/04 --100 ND ----ND ND ND --ND ND ND ------ug/L 11/23/04 --100 ND ----ND ND ND --ND ND ND ------ ug/L 05/16/05 --100 ------ND ND ND --ND ND ND ------ug/L 11/25/05 --100 ------ND ND ND --ND ND ND ------ ug/L 05/24/06 --100 ------ND ND ND --ND ND ND ----NDug/L 11/20/06 --100 ------ND ND ND --ND ND 204 ----NDug/L 02/28/07 --100 ------------------ND ----ND ug/L 05/22/07 --100 --ND --ND 1.7 B 1.6 B 3.2 B ND 9.7 B ND ----6.6 Jug/L 11/13/07 --100 --ND --ND ND ND ND ND ND ND ----ND ug/L 05/29/08 --100 --ND --ND ND ND ND ND ND ND ----2.9 Jug/L 11/17/08 --100 --ND --ND ND ND ND ND ND 23 B ----9.8 Jug/L 05/26/09 --100 --ND --ND ND ND ND ND ND ND ----ND ug/L 11/10/09 --100 ------ND ND ND ND ND 2.8 J ND ----NDug/L 05/26/10 --100 ------ND ND ND ND ND 7.0 J 5.2 J ----ND ug/L 11/15/10 --100 ------ND ND ND ND 4.6 B ND ND ----9.2 Jug/L 05/09/11 --100 ------ND ND ND ND ND ND ND ----NDug/L 11/14/11 --100 ------ND ND ND ND ND ND ND ----ND ug/L 05/07/12 --100 ------ND ND ND ND ND Dry ND ----NDug/L 11/05/12 --100 ------ND ND ND ND ND ND ND ND ND ND ug/L 05/13/13 --100 ------ND ND ND ND ND ND ND ND ND NDug/L 11/11/13 --100 ------ND ND ND ND ND ND ND ND ND NDug/L 05/12/14 --100 ------ND ND ND ND ND ND ND ND ND ND ug/L 11/17/14 1.2 100 ------ND ND ND ND ND ND ND ND ND NDug/L 05/12/15 1.2 100 ------ND ND ND ND ND ND ND 9.7 J ND ND ug/L 11/09/15 1.2 100 -----ND ND ND ND ND ND ND 3.7 J ND ND January 2016 Page 5 of 8 Project No. 0739603714.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx GGI Outfall 2GGI Outfall 1MW-105A MW-106 MW-107S MW-108 SWSReporting Limit Upgradient TABLE 4 Summary of Groundwater Monitoring Results for MSW Wells Detected Constituents Sampson County Active MSW Landfill, Permit No. 82-02 Sampson County, North Carolina Blanks Downgradient MW-100 MW-100A MW-100B MW-102A MW-103A MW-104MDLDetected Monitoring Constituent/Parameter Reporting Units Sample Date Benzene ug/L 01/11/00 --2 ND --------ND --ND ND ND ------NC 2L = 1 ug/L ug/L 02/21/00 --2 ND ------------------------ EPA MCL = 5 ug/L ug/L 02/22/00 --2 ----------------ND ND ------ug/L 10/10/00 --5 ND --------ND --ND ND ND ------ ug/L 07/12/01 --5 ND --------ND --ND ND ND ------ug/L 10/24/01 --5 ----------ND --ND --ND ------ug/L 05/28/02 --5 ND --------ND --ND --ND ------ ug/L 11/05/02 --5 ND --------ND --ND ND ND ------ug/L 05/29/03 --5 ND --------ND --ND ND ND ------ ug/L 11/05/03 --5 ND ----ND ND ND --ND ND ND ------ug/L 05/25/04 --5 ND ----ND ND ND --ND ND ND ------ug/L 11/23/04 --5 ND ----ND ND ND --ND ND ND ------ ug/L 05/16/05 --5 ------ND ND ND --ND ND ND ------ug/L 11/25/05 --5 ------ND ND ND --ND ND ND ------ ug/L 05/24/06 --5 ------ND ND ND --ND ND ND ----NDug/L 11/20/06 --5 ------ND ND ND --ND ND ND ----NDug/L 05/22/07 --1 --ND --ND ND ND ND ND 3.8 ND ----ND ug/L 08/07/07 --1 ----------------2.3 ------NDug/L 11/13/07 --1 --ND --ND ND ND ND ND 0.73 J ND ----ND ug/L 05/29/08 --1 --ND --ND ND ND ND ND 0.95 J ND ----NDug/L 11/17/08 --1 --ND --ND ND ND ND ND 0.79 J ND ----NDug/L 05/26/09 --1 --ND --ND ND ND ND ND 0.61 J ND ----ND ug/L 11/10/09 --1 ------ND ND ND ND ND ND ND ----NDug/L 05/26/10 --1 ------ND ND ND ND ND ND ND ----ND ug/L 11/15/10 --1 ------ND ND ND ND ND ND ND ----NDug/L 05/09/11 --1 ------ND ND ND ND ND ND ND ----NDug/L 11/14/11 --1 ------ND ND ND ND ND ND ND ----ND ug/L 05/07/12 --1 ------ND ND ND ND ND Dry ND ----NDug/L 11/05/12 --1 ------ND ND ND ND ND ND ND ND ND ND ug/L 05/13/13 --1 ------ND ND ND ND ND ND ND ND ND NDug/L 11/11/13 --1 ------ND ND ND ND ND ND ND ND ND NDug/L 05/12/14 --1 ------ND ND ND ND ND ND ND ND ND ND ug/L 11/17/14 0.15 1 ------ND ND ND ND ND ND ND ND ND NDug/L 05/12/15 0.15 1 ------ND ND ND ND ND ND ND ND ND ND ug/L 11/09/15 0.15 1 -----ND ND ND ND ND ND ND ND ND NDCarbon disulfide ug/L 01/11/00 ----ND ND ------ND --ND ND ND ------NC 2L = 700 ug/L ug/L 02/21/00 ----ND ND ---------------------- No EPA MCL ug/L 02/22/00 --------------------ND ND ------ug/L 10/10/00 ----ND ND ------ND --ND ND ND ------ ug/L 07/12/01 ----ND ND ------ND --ND ND ND ------ug/L 10/24/01 --------------ND --ND --ND ------ug/L 05/28/02 ----ND ND ------ND --ND --ND ------ ug/L 11/05/02 ----ND ND ------ND --ND ND ND ------ug/L 05/29/03 ----ND ND ------ND --ND ND ND ------ ug/L 11/05/03 ----ND ND --ND ND ND --ND ND ND ------ug/L 05/25/04 ----ND ND --ND ND ND --ND ND ND ------ug/L 11/23/04 ----ND ND --ND ND ND --ND ND ND ------ ug/L 05/16/05 ----------ND ND ND --ND ND ND ------ug/L 11/25/05 ----------ND ND ND --ND ND ND ------ ug/L 05/24/06 --100 ------ND ND ND --ND ND ND ----NDug/L 11/20/06 --100 ------ND ND ND --ND ND ND ----NDug/L 05/22/07 --100 --ND --ND ND ND ND ND ND ND ----ND ug/L 11/13/07 --100 --ND --ND ND ND ND ND ND ND ----NDug/L 05/29/08 --100 --ND --ND ND ND ND ND ND ND ----ND ug/L 11/17/08 --100 --ND --ND ND ND ND ND ND 2.6 J ----NDug/L 05/26/09 --100 --ND --ND ND ND ND ND ND ND ----NDug/L 11/10/09 --100 ------ND ND ND ND ND ND ND ----ND ug/L 05/26/10 --100 ------ND ND ND ND ND ND ND ----NDug/L 11/15/10 --100 ------ND ND ND ND ND ND ND ----ND ug/L 05/09/11 --100 ------ND ND ND ND ND ND ND ----NDug/L 11/14/11 --100 ------ND ND ND ND ND ND ND ----NDug/L 05/07/12 --100 ------ND ND ND ND ND Dry ND ----ND ug/L 11/05/12 --100 ------ND ND ND ND ND ND ND ND ND NDug/L 05/13/13 --100 ------ND ND ND ND ND ND ND ND ND ND ug/L 11/11/13 --100 ------ND ND ND ND ND ND ND ND ND NDug/L 05/12/14 --100 ------ND ND ND ND ND ND ND ND ND NDug/L 11/17/14 1.5 100 ------ND ND ND ND ND ND ND ND ND ND ug/L 05/12/15 1.5 100 ------ND ND ND ND ND ND ND ND ND NDug/L 11/09/15 1.5 100 ---ND ND ND ND ND ND ND ND ND ND Chlorobenzene ug/L 01/11/00 --2 ND --------ND --ND ND ND ------NC 2L = 50 ug/L ug/L 02/21/00 --2 ND ------------------------EPA MCL = 100 ug/L ug/L 02/22/00 --2 ----------------ND ND ------ ug/L 10/10/00 --5 ND --------ND --ND ND ND ------ug/L 07/12/01 --5 ND --------ND --ND ND ND ------ ug/L 10/24/01 --5 ----------ND --ND --ND ------ug/L 05/28/02 --5 ND --------ND --ND --ND ------ug/L 11/05/02 --5 ND --------ND --ND ND ND ------ ug/L 05/29/03 --5 ND --------ND --ND ND ND ------ug/L 11/05/03 --5 ND ----ND ND ND --ND ND ND ------ ug/L 05/25/04 --5 ND ----ND ND ND --ND ND ND ------ug/L 11/23/04 --5 ND ----ND ND ND --ND ND ND ------ug/L 05/16/05 --5 ------ND ND ND --ND ND ND ------ ug/L 11/25/05 --5 ------ND ND ND --ND ND ND ------ug/L 05/24/06 --5 ------ND ND ND --ND ND ND ----ND ug/L 11/20/06 --5 ------ND ND ND --ND ND ND ----NDug/L 05/22/07 --3 --ND --ND ND ND ND ND 1.4 J ND ----NDug/L 11/13/07 --3 --ND --ND ND ND ND ND ND ND ----ND ug/L 05/29/08 --3 --ND --ND ND ND ND ND ND ND ----NDug/L 11/17/08 --3 --ND --ND ND ND ND ND ND ND ----ND ug/L 05/26/09 --3 --ND --ND ND ND ND ND ND ND ----NDug/L 11/10/09 --3 ------ND ND ND ND ND ND ND ----NDug/L 05/26/10 --3 ------ND ND ND ND ND ND ND ----ND ug/L 11/15/10 --3 ------ND ND ND ND ND ND ND ----NDug/L 05/09/11 --3 ------ND ND ND ND ND ND ND ----ND ug/L 11/14/11 --3 ------ND ND ND ND ND ND ND ----NDug/L 05/07/12 --3 ------ND ND ND ND ND Dry ND ----NDug/L 11/05/12 --3 ------ND ND ND ND ND ND ND ND ND ND ug/L 05/13/13 --3 ------ND ND ND ND ND ND ND ND ND NDug/L 11/11/13 --3 ------ND ND ND ND ND ND ND ND ND ND ug/L 05/12/14 --3 ------ND ND ND ND ND ND ND ND ND NDug/L 11/17/14 0.17 3 ------ND ND ND ND ND ND ND ND ND NDug/L 05/12/15 0.17 3 ------ND ND ND ND ND ND ND ND ND ND ug/L 11/09/15 0.17 3 -----ND ND ND ND ND ND ND ND ND NDChloroformug/L 01/11/00 --2 ND --------ND --ND ND ND ------ NC 2L = 70 ug/L ug/L 02/21/00 --2 ND ------------------------EPA MCL = 80 ug/L ug/L 02/22/00 --2 ----------------ND ND ------ug/L 10/10/00 --5 ND --------ND --ND ND ND ------ ug/L 07/12/01 --5 ND --------ND --ND ND ND ------ug/L 10/24/01 --5 ----------ND --ND --ND ------ ug/L 05/28/02 --5 ND --------ND --ND --ND ------ug/L 11/05/02 --5 ND --------ND --ND ND ND ------ug/L 05/29/03 --5 ND --------ND --ND ND ND ------ ug/L 11/05/03 --5 ND ----ND ND ND --ND ND ND ------ug/L 05/25/04 --5 ND ----ND ND ND --ND ND ND ------ ug/L 11/23/04 --5 ND ----ND ND ND --ND ND ND ------ug/L 05/16/05 --5 ------ND ND ND --ND ND ND ------ug/L 11/25/05 --5 ------ND ND ND --ND ND ND ------ ug/L 05/24/06 --5 ------ND ND ND --ND ND ND ----NDug/L 11/20/06 --5 ------ND ND ND --ND ND ND ----ND ug/L 05/22/07 --5 --ND --ND ND ND ND ND ND ND ----NDug/L 11/13/07 --5 --ND --ND ND ND ND ND ND ND ----NDug/L 05/29/08 --5 --ND --ND ND ND ND ND ND ND ----ND ug/L 11/17/08 --5 --0.68 J --ND ND ND ND ND ND ND ----NDug/L 05/26/09 --5 --ND --ND ND ND ND ND ND ND ----ND ug/L 11/10/09 --5 ------ND ND ND ND ND ND ND ----NDug/L 05/26/10 --5 ------ND ND ND ND ND ND ND ----NDug/L 11/15/10 --5 ------ND ND ND ND ND ND ND ----ND ug/L 05/09/11 --5 ------ND ND ND ND ND ND ND ----NDug/L 11/14/11 --5 ------ND ND ND ND ND ND ND ----ND ug/L 05/07/12 --5 ------ND ND ND ND ND Dry ND ----NDug/L 11/05/12 --5 ------ND ND ND ND ND ND ND ND ND NDug/L 05/13/13 --5 ------ND ND ND ND ND ND ND ND ND ND ug/L 11/11/13 --5 ------ND ND ND ND ND ND ND ND ND NDug/L 05/12/14 --5 ------ND ND ND ND ND ND ND ND ND ND ug/L 11/17/14 0.18 5 ------ND ND ND ND ND ND ND ND ND NDug/L 05/12/15 0.18 5 ------ND ND ND ND ND ND ND ND ND NDug/L 11/09/15 0.18 5 -----ND ND ND ND ND ND ND ND ND ND January 2016 Page 6 of 8 Project No. 0739603714.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx GGI Outfall 2GGI Outfall 1MW-105A MW-106 MW-107S MW-108 SWSReporting Limit Upgradient TABLE 4 Summary of Groundwater Monitoring Results for MSW Wells Detected Constituents Sampson County Active MSW Landfill, Permit No. 82-02 Sampson County, North Carolina Blanks Downgradient MW-100 MW-100A MW-100B MW-102A MW-103A MW-104MDLDetected Monitoring Constituent/Parameter Reporting Units Sample Date 1,1-Dichloroethane ug/L 01/11/00 --2 ND --------ND --ND ND ND ------NC 2L = 6 ug/L ug/L 02/21/00 --2 ND ------------------------ No EPA MCL ug/L 02/22/00 --2 ----------------ND ND ------ug/L 10/10/00 --5 ND --------ND --ND ND ND ------ ug/L 07/12/01 --5 ND --------ND --ND ND ND ------ug/L 10/24/01 --5 ----------ND --ND --ND ------ug/L 05/28/02 --5 ND --------ND --ND --ND ------ ug/L 11/05/02 --5 ND --------ND --ND ND ND ------ug/L 05/29/03 --5 ND --------ND --ND ND ND ------ ug/L 11/05/03 --5 ND ----ND ND ND --ND ND ND ------ug/L 05/25/04 --5 ND ----ND ND ND --ND ND ND ------ug/L 11/23/04 --5 ND ----ND ND ND --ND ND ND ------ ug/L 05/16/05 --5 ------ND ND ND --ND ND ND ------ug/L 11/25/05 --5 ------ND ND ND --ND ND ND ------ ug/L 05/24/06 --5 ------ND ND ND --ND ND ND ----NDug/L 11/20/06 --5 ------ND ND ND --ND ND ND ----NDug/L 05/22/07 --5 --ND --ND ND ND ND ND 0.39 J ND ----ND ug/L 11/13/07 --5 --ND --ND ND ND ND ND ND ND ----NDug/L 05/29/08 --5 --ND --ND ND ND ND ND ND ND ----ND ug/L 11/17/08 --5 --ND --ND ND ND ND ND ND ND ----NDug/L 05/26/09 --5 --ND --ND ND ND ND ND ND ND ----NDug/L 11/10/09 --5 ------ND ND ND ND ND ND ND ----ND ug/L 05/26/10 --5 ------ND ND ND ND ND ND ND ----NDug/L 11/15/10 --5 ------ND ND ND ND ND ND ND ----ND ug/L 05/09/11 --5 ------ND ND ND ND ND ND ND ----NDug/L 11/14/11 --5 ------ND ND ND ND ND ND ND ----NDug/L 05/07/12 --5 ------ND ND ND ND ND Dry ND ----ND ug/L 11/05/12 --5 ------ND ND ND ND ND ND ND ND ND NDug/L 05/13/13 --5 ------ND ND ND ND ND ND ND ND ND ND ug/L 11/11/13 --5 ------ND ND ND ND ND ND ND ND ND NDug/L 05/12/14 --5 ------ND ND ND ND ND ND ND ND ND NDug/L 11/17/14 0.13 5 ------ND ND ND ND ND ND ND ND ND ND ug/L 05/12/15 0.13 5 ------ND ND ND ND ND ND ND ND ND NDug/L 11/09/15 0.13 5 -----ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene ug/L 01/11/00 --2 ND --------ND --ND ND ND ------NC 2L = 70 ug/L ug/L 02/21/00 --2 ND ------------------------EPA MCL = 70 ug/L ug/L 02/22/00 --2 ----------------ND ND ------ ug/L 10/10/00 --5 ND --------ND --ND ND ND ------ug/L 07/12/01 --5 ND --------ND --ND ND ND ------ ug/L 10/24/01 --5 ----------ND --ND --ND ------ug/L 05/28/02 --5 ND --------ND --ND --ND ------ug/L 11/05/02 --5 ND --------ND --ND ND ND ------ ug/L 05/29/03 --5 ND --------ND --ND ND ND ------ug/L 11/05/03 --5 ND ----ND ND ND --ND ND ND ------ ug/L 05/25/04 --5 ND ----ND ND ND --ND ND ND ------ug/L 11/23/04 --5 ND ----ND ND ND --ND ND ND ------ug/L 05/16/05 --5 ------ND ND ND --ND ND ND ------ ug/L 11/25/05 --5 ------ND ND ND --ND ND ND ------ug/L 05/24/06 --5 ------ND ND ND --ND ND ND ----ND ug/L 11/20/06 --5 ------ND ND ND --ND ND ND ----NDug/L 05/22/07 --5 --ND --ND ND ND ND ND ND 1.5 J ----NDug/L 11/13/07 --5 --ND --ND ND ND ND ND 0.69 J ND ----ND ug/L 05/29/08 --5 --ND --ND ND ND ND ND ND ND ----NDug/L 11/17/08 --5 --ND --ND ND ND ND ND ND ND ----ND ug/L 05/26/09 --5 --ND --ND ND ND ND ND ND ND ----NDug/L 11/10/09 --5 ------ND ND ND ND ND ND ND ----NDug/L 05/26/10 --5 ------ND ND ND ND ND ND ND ----ND ug/L 11/15/10 --5 ------ND ND ND ND ND ND ND ----NDug/L 05/09/11 --5 ------ND ND ND ND ND ND ND ----ND ug/L 11/14/11 --5 ------ND ND ND ND ND ND ND ----NDug/L 05/07/12 --5 ------ND ND ND ND ND Dry ND ----NDug/L 11/05/12 --5 ------ND ND ND ND ND ND ND ND ND ND ug/L 05/13/13 --5 ------ND ND ND ND ND ND ND ND ND NDug/L 11/11/13 --5 ------ND ND ND ND ND ND ND ND ND ND ug/L 05/12/14 --5 ------ND ND ND ND ND ND ND ND ND NDug/L 11/17/14 0.15 5 ------ND ND ND ND ND ND ND ND ND NDug/L 05/12/15 0.15 5 ------ND ND ND ND ND ND ND ND ND ND ug/L 11/09/15 0.15 5 -----ND ND ND ND ND ND ND ND ND NDEthylbenzeneug/L 01/11/00 --2 ND --------ND --ND ND ND ------ NC 2L = 600 ug/L ug/L 02/21/00 --2 ND ------------------------EPA MCL = 700 ug/L ug/L 02/22/00 --2 ----------------ND ND ------ug/L 10/10/00 --5 ND --------ND --ND ND ND ------ ug/L 07/12/01 --5 ND --------ND --ND ND ND ------ug/L 10/24/01 --5 ----------ND --ND --ND ------ ug/L 05/28/02 --5 ND --------ND --ND --ND ------ug/L 11/05/02 --5 ND --------ND --ND ND ND ------ug/L 05/29/03 --5 ND --------ND --ND ND ND ------ ug/L 11/05/03 --5 ND ----ND ND ND --ND ND ND ------ug/L 05/25/04 --5 ND ----ND ND ND --ND ND ND ------ ug/L 11/23/04 --5 ND ----ND ND ND --ND ND ND ------ug/L 05/16/05 --5 ------ND ND ND --ND ND ND ------ug/L 11/25/05 --5 ------ND ND ND --ND ND ND ------ ug/L 05/24/06 --5 ------ND ND ND --ND 6.2 ND ----NDug/L 11/20/06 --5 ------ND ND ND --ND ND ND ----ND ug/L 05/22/07 --1 --ND --ND ND ND ND ND ND ND ----NDug/L 11/13/07 --1 --ND --ND ND ND ND ND ND ND ----NDug/L 05/29/08 --1 --ND --ND ND ND ND ND ND ND ----ND ug/L 11/17/08 --1 --ND --ND ND ND ND ND ND 0.44 J ----NDug/L 05/26/09 --1 --ND --ND ND ND ND ND ND ND ----ND ug/L 11/10/09 --1 ------ND ND ND ND ND ND ND ----NDug/L 05/26/10 --1 ------ND ND ND ND ND ND ND ----NDug/L 11/15/10 --1 ------ND ND ND ND ND ND ND ----ND ug/L 05/09/11 --1 ------ND ND ND ND ND ND ND ----NDug/L 11/14/11 --1 ------ND ND ND ND ND ND ND ----ND ug/L 05/07/12 --1 ------ND ND ND ND ND Dry ND ----NDug/L 11/05/12 --1 ------ND ND ND ND ND ND ND ND ND NDug/L 05/13/13 --1 ------ND ND ND ND ND ND ND ND ND ND ug/L 11/11/13 --1 ------ND ND ND ND ND ND ND ND ND NDug/L 05/12/14 --1 ------ND ND ND ND ND ND ND ND ND ND ug/L 11/17/14 0.13 1 ------ND ND ND ND ND ND ND ND ND NDug/L 05/12/15 0.13 1 ------ND ND ND ND ND ND ND ND ND NDug/L 11/09/15 0.13 1 -----ND ND ND ND ND ND ND ND ND ND 2-Butanone ug/L 01/11/00 --10 ND --------ND --ND ND ND ------NC 2L = 4000 ug/L ug/L 02/21/00 --10 ND ------------------------ No EPA MCL ug/L 02/22/00 --10 ----------------ND ND ------ug/L 10/10/00 --100 ND --------ND --ND ND ND ------ug/L 07/12/01 --100 ND --------ND --ND ND ND ------ ug/L 10/24/01 --100 ----------ND --ND --ND ------ug/L 05/28/02 --100 ND --------ND --ND --ND ------ ug/L 11/05/02 --100 ND --------ND --ND ND ND ------ug/L 05/29/03 --100 ND --------ND --ND ND ND ------ug/L 11/05/03 --100 ND ----ND ND ND --ND ND ND ------ ug/L 05/25/04 --100 ND ----ND ND ND --ND ND ND ------ug/L 11/23/04 --100 ND ----ND ND ND --ND ND ND ------ ug/L 05/16/05 --100 ------ND ND ND --ND ND ND ------ug/L 11/25/05 --100 ------ND ND ND --ND ND ND ------ug/L 05/24/06 --100 ------ND ND ND --ND ND ND ----ND ug/L 11/20/06 --100 ------ND ND ND --ND ND 184 ----NDug/L 02/28/07 --100 ------------------ND ----ND ug/L 05/22/07 --100 --ND --ND ND ND ND ND ND ND ----NDug/L 11/13/07 --100 --ND --ND ND ND ND ND ND ND ----NDug/L 05/29/08 --100 --ND --ND ND ND ND ND ND ND ----ND ug/L 11/17/08 --100 --ND --ND ND ND ND ND ND 28 J ----NDug/L 05/26/09 --100 --ND --ND ND ND ND ND ND ND ----ND ug/L 11/10/09 --100 ------ND ND ND ND ND ND ND ----NDug/L 05/26/10 --100 ------ND ND ND ND ND ND ND ----NDug/L 11/15/10 --100 ------ND ND ND ND ND ND ND ----6.4 J ug/L 05/09/11 --100 ------ND ND ND ND ND ND ND ----NDug/L 11/14/11 --100 ------ND ND ND ND ND ND ND ----ND ug/L 05/07/12 --100 ------ND ND ND ND ND Dry ND ----NDug/L 11/05/12 --100 ------ND ND ND ND ND ND ND ND ND NDug/L 05/13/13 --100 ------ND ND ND ND ND ND ND ND ND ND ug/L 11/11/13 --100 ------ND ND ND ND ND ND ND ND ND NDug/L 05/12/14 --100 ------ND ND ND ND ND ND ND ND ND ND ug/L 11/17/14 1.3 100 ------ND ND ND ND ND ND ND ND ND NDug/L 05/12/15 1.3 100 ------ND ND ND ND ND ND ND ND ND NDug/L 11/09/15 1.3 100 -----ND ND ND ND ND ND ND ND ND ND January 2016 Page 7 of 8 Project No. 0739603714.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx GGI Outfall 2GGI Outfall 1MW-105A MW-106 MW-107S MW-108 SWSReporting Limit Upgradient TABLE 4 Summary of Groundwater Monitoring Results for MSW Wells Detected Constituents Sampson County Active MSW Landfill, Permit No. 82-02 Sampson County, North Carolina Blanks Downgradient MW-100 MW-100A MW-100B MW-102A MW-103A MW-104MDLDetected Monitoring Constituent/Parameter Reporting Units Sample Date 4-Methyl-2-pentanone ug/L 01/11/00 ----ND ND ------ND --ND ND ND ------SWS GWS = 560 ug/L ug/L 02/21/00 ----ND ND ---------------------- EPA MCL = 5 ug/L ug/L 02/22/00 --------------------ND ND ------ug/L 10/10/00 ----ND ND ------ND --ND ND ND ------ ug/L 07/12/01 ----ND ND ------ND --ND ND ND ------ug/L 10/24/01 --------------ND --ND --ND ------ug/L 05/28/02 ----ND ND ------ND --ND --ND ------ ug/L 11/05/02 ----ND ND ------ND --ND ND ND ------ug/L 05/29/03 ----ND ND ------ND --ND ND ND ------ ug/L 11/05/03 ----ND ND --ND ND ND --ND ND ND ------ug/L 05/25/04 ----ND ND --ND ND ND --ND ND ND ------ug/L 11/23/04 ----ND ND --ND ND ND --ND ND ND ------ ug/L 05/16/05 ----------ND ND ND --ND ND ND ------ug/L 11/25/05 ----------ND ND ND --ND ND ND ------ ug/L 05/24/06 --100 ------ND ND ND --ND ND ND ----NDug/L 11/20/06 --100 ------ND ND ND --ND ND ND ----NDug/L 05/22/07 --100 --ND --ND ND ND ND ND ND ND ----ND ug/L 11/13/07 --100 --ND --ND ND ND ND ND ND ND ----NDug/L 05/29/08 --100 --ND --ND ND ND ND ND ND ND ----ND ug/L 11/17/08 --100 --ND --ND ND ND ND ND ND 1.7 J ----NDug/L 05/26/09 --100 --ND --ND ND ND ND ND ND ND ----NDug/L 11/10/09 --100 ------ND ND ND ND ND ND ND ----ND ug/L 05/26/10 --100 ------ND ND ND ND ND ND ND ----NDug/L 11/15/10 --100 ------ND ND ND ND ND ND ND ----ND ug/L 05/09/11 --100 ------ND ND ND ND ND ND ND ----NDug/L 11/14/11 --100 ------ND ND ND ND ND ND ND ----NDug/L 05/07/12 --100 ------ND ND ND ND ND Dry ND ----ND ug/L 11/05/12 --100 ------ND ND ND ND ND ND ND ND ND NDug/L 05/13/13 --100 ------ND ND ND ND ND ND ND ND ND ND ug/L 11/11/13 --100 ------ND ND ND ND ND ND ND ND ND NDug/L 05/12/14 --100 ------ND ND ND ND ND ND ND ND ND NDug/L 11/17/14 1.1 100 ------ND ND ND ND ND ND ND ND ND ND ug/L 05/12/15 1.1 100 ------ND ND ND ND ND ND ND ND ND NDug/L 11/09/15 1.1 100 -----ND ND ND ND ND ND ND ND ND ND Tetrachloroethene ug/L 01/11/00 --2 ND --------ND --ND ND ND ------NC 2L = 0.7 ug/L ug/L 02/21/00 --2 ND ------------------------EPA MCL = 5 ug/L ug/L 02/22/00 --2 ----------------ND ND ------ ug/L 10/10/00 --5 ND --------ND --ND ND ND ------ug/L 07/12/01 --5 ND --------ND --ND ND ND ------ ug/L 10/24/01 --5 ----------ND --ND --ND ------ug/L 05/28/02 --5 ND --------ND --ND --ND ------ug/L 11/05/02 --5 ND --------ND --ND ND ND ------ ug/L 05/29/03 --5 ND --------ND --ND ND ND ------ug/L 11/05/03 --5 ND ----ND ND ND --ND ND ND ------ ug/L 05/25/04 --5 ND ----ND ND ND --ND ND ND ------ug/L 11/23/04 --5 ND ----ND ND ND --ND ND ND ------ug/L 05/16/05 --5 ------ND ND ND --ND ND ND ------ ug/L 11/25/05 --5 ------ND ND ND --ND ND ND ------ug/L 05/24/06 --5 ------ND ND ND --ND ND ND ----ND ug/L 11/20/06 --5 ------ND ND ND --ND ND ND ----NDug/L 05/22/07 --1 --ND --ND ND ND ND ND 0.79 J ND ----NDug/L 11/13/07 --1 --ND --ND ND ND ND ND ND ND ----ND ug/L 05/29/08 --1 --ND --ND ND ND ND ND ND ND ----NDug/L 11/17/08 --1 --ND --ND ND ND ND ND 0.49 J ND ----ND ug/L 05/26/09 --1 --ND --ND ND ND ND ND ND ND ----NDug/L 11/10/09 --1 ------ND ND ND ND ND ND ND ----NDug/L 05/26/10 --1 ------ND ND ND ND ND ND ND ----ND ug/L 11/15/10 --1 ------ND ND ND ND ND ND ND ----NDug/L 05/09/11 --1 ------ND ND ND ND ND ND ND ----ND ug/L 11/14/11 --1 ------ND ND ND ND ND ND ND ----NDug/L 05/07/12 --1 ------ND ND ND ND ND Dry ND ----NDug/L 11/05/12 --1 ------ND ND ND ND ND ND ND ND ND ND ug/L 05/13/13 --1 ------ND ND ND ND ND ND ND ND ND NDug/L 11/11/13 --1 ------ND ND ND ND ND ND ND ND ND ND ug/L 05/12/14 --1 ------ND ND ND ND ND ND ND ND ND NDug/L 11/17/14 0.17 1 ------ND ND ND ND ND ND ND ND ND NDug/L 05/12/15 0.17 1 ------ND ND ND ND ND ND ND ND ND ND ug/L 11/09/15 0.17 1 -----ND ND ND ND ND ND ND ND ND NDTrichloroetheneug/L 01/11/00 --2 ND --------ND --ND ND ND ------ NC 2L = 3 ug/L ug/L 02/21/00 --2 ND ------------------------EPA MCL = 5 ug/L ug/L 02/22/00 --2 ----------------ND ND ------ug/L 10/10/00 --5 ND --------ND --ND ND ND ------ ug/L 07/12/01 --5 ND --------ND --ND ND ND ------ug/L 10/24/01 --5 ----------ND --ND --ND ------ ug/L 05/28/02 --5 ND --------ND --ND --ND ------ug/L 11/05/02 --5 ND --------ND --ND ND ND ------ug/L 05/29/03 --5 ND --------ND --ND ND ND ------ ug/L 11/05/03 --5 ND ----ND ND ND --ND ND ND ------ug/L 05/25/04 --5 ND ----ND ND ND --ND ND ND ------ ug/L 11/23/04 --5 ND ----ND ND ND --ND ND ND ------ug/L 05/16/05 --5 ------ND ND ND --ND ND ND ------ug/L 11/25/05 --5 ------ND ND ND --ND ND ND ------ ug/L 05/24/06 --5 ------ND ND ND --ND ND ND ----NDug/L 11/20/06 --5 ------ND ND ND --ND ND ND ----ND ug/L 05/22/07 --1 --ND --ND ND ND ND ND 0.33 J ND ----NDug/L 11/13/07 --1 --ND --ND ND ND ND ND ND ND ----NDug/L 05/29/08 --1 --ND --ND ND ND ND ND ND ND ----ND ug/L 11/17/08 --1 --ND --ND ND ND ND ND ND ND ----NDug/L 05/26/09 --1 --ND --ND ND ND ND ND ND ND ----ND ug/L 11/10/09 --1 ------ND ND ND ND ND ND ND ----NDug/L 05/26/10 --1 ------ND ND ND ND ND ND ND ----NDug/L 11/15/10 --1 ------ND ND ND ND ND ND ND ----ND ug/L 05/09/11 --1 ------ND ND ND ND ND ND ND ----NDug/L 11/14/11 --1 ------ND ND ND ND ND ND ND ----ND ug/L 05/07/12 --1 ------ND ND ND ND ND Dry ND ----NDug/L 11/05/12 --1 ------ND ND ND ND ND ND ND ND ND NDug/L 05/13/13 --1 ------ND ND ND ND ND ND ND ND ND ND ug/L 11/11/13 --1 ------ND ND ND ND ND ND ND ND ND NDug/L 05/12/14 --1 ------ND ND ND ND ND ND ND ND ND ND ug/L 11/17/14 0.15 1 ------ND ND ND ND ND ND ND ND ND NDug/L 05/12/15 0.15 1 ------ND ND ND ND ND ND ND ND ND NDug/L 11/09/15 0.15 1 -----ND ND ND ND ND ND ND ND ND ND Vinyl chloride ug/L 01/11/00 --2 ND --------ND --ND ND ND ------NC 2L = 0.03 ug/L ug/L 02/21/00 --2 ND ------------------------ EPA MCL = 2 ug/L ug/L 02/22/00 --2 ----------------ND ND ------ug/L 10/10/00 --10 ND --------ND --ND ND ND ------ug/L 07/12/01 --10 ND --------ND --ND ND ND ------ ug/L 10/24/01 --10 ----------ND --ND --ND ------ug/L 05/28/02 --10 ND --------ND --ND --ND ------ ug/L 11/05/02 --10 ND --------ND --ND ND ND ------ug/L 05/29/03 --10 ND --------ND --ND ND ND ------ug/L 11/05/03 --10 ND ----ND ND ND --ND ND ND ------ ug/L 05/25/04 --10 ND ----ND ND ND --ND ND ND ------ug/L 11/23/04 --10 ND ----ND ND ND --ND ND ND ------ ug/L 05/16/05 --10 ------ND ND ND --ND ND ND ------ug/L 11/25/05 --10 ------ND ND ND --ND ND ND ------ug/L 05/24/06 --10 ------ND ND ND --ND ND ND ----NDug/L 11/20/06 --10 ------ND ND ND --ND ND ND ----NDug/L 05/22/07 --1 --ND --ND ND ND --ND 1.6 ND ----NDug/L 08/07/07 --1 ----------------ND ------ND ug/L 11/13/07 --1 --ND --ND ND ND ND ND 0.74 J ND ----NDug/L 05/29/08 --1 --ND --ND ND ND ND ND 0.46 J ND ----NDug/L 11/17/08 --1 --ND --ND ND ND ND ND ND ND ----NDug/L 05/26/09 --1 --ND --ND ND ND ND ND ND ND ----ND ug/L 11/10/09 --1 ------ND ND ND ND ND ND ND ----NDug/L 05/26/10 --1 ------ND ND ND ND ND ND ND ----NDug/L 11/15/10 --1 ------ND ND ND ND ND ND ND ----NDug/L 05/09/11 --1 ------ND ND ND ND ND ND ND ----ND ug/L 11/14/11 --1 ------ND ND ND ND ND ND ND ----NDug/L 05/07/12 --1 ------ND ND ND ND ND Dry ND ----NDug/L 11/05/12 --1 ------ND ND ND ND ND ND ND ND ND NDug/L 05/13/13 --1 ------ND ND ND ND ND ND ND ND ND ND ug/L 11/11/13 --1 ------ND ND ND ND ND ND ND ND ND NDug/L 05/12/14 --1 ------ND ND ND ND ND ND ND ND ND NDug/L 11/17/14 0.32 1 ------ND ND ND ND ND ND ND ND ND NDug/L 05/12/15 0.32 1 ------ND ND ND ND ND ND ND ND ND ND ug/L 11/09/15 0.32 1 -----ND ND ND ND ND ND ND ND ND ND January 2016 Page 8 of 8 Project No. 0739603714.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx GGI Outfall 2GGI Outfall 1MW-105A MW-106 MW-107S MW-108 SWSReporting Limit Upgradient TABLE 4 Summary of Groundwater Monitoring Results for MSW Wells Detected Constituents Sampson County Active MSW Landfill, Permit No. 82-02 Sampson County, North Carolina Blanks Downgradient MW-100 MW-100A MW-100B MW-102A MW-103A MW-104MDLDetected Monitoring Constituent/Parameter Reporting Units Sample Date Xylenes (Total)ug/L 01/11/00 --6 ND --------ND --ND ND ND ------NC 2L = 500 ug/L ug/L 02/21/00 --6 ND ------------------------ EPA MCL = 10000 ug/L ug/L 02/22/00 --6 ----------------ND ND ------ug/L 10/10/00 --5 ND --------ND --ND ND ND ------ug/L 07/12/01 --5 ND --------ND --ND ND ND ------ug/L 10/24/01 --5 ----------ND --ND --ND ------ ug/L 05/28/02 --5 ND --------ND --ND --ND ------ug/L 11/05/02 --5 ND --------ND --ND ND ND ------ug/L 05/29/03 --5 ND --------ND --ND ND ND ------ug/L 11/05/03 --5 ND ----ND ND ND --ND ND ND ------ ug/L 05/25/04 --5 ND ----ND ND ND --ND ND ND ------ug/L 11/23/04 --5 ND ----ND ND ND --ND ND ND ------ug/L 05/16/05 --5 ------ND ND ND --ND ND ND ------ug/L 11/25/05 --5 ------ND ND ND --ND 18.2 ND ------ug/L 05/24/06 --5 ------ND ND ND --ND 18.1 ND ----NDug/L 11/20/06 --5 ------ND ND ND --ND ND ND ----NDug/L 05/22/07 --5 --ND --ND ND ND ND ND 5.7 ND ----NDug/L 08/07/07 --5 ----------------2.7 J ------NDug/L 11/13/07 --5 --ND --ND ND ND ND ND 2.2 J ND ----ND ug/L 05/29/08 --5 --ND --ND ND ND ND ND 2.2 J ND ----NDug/L 11/17/08 --5 --ND --ND ND ND ND ND ND 0.48 J ----NDug/L 05/26/09 --5 --ND --ND ND ND ND ND ND ND ----NDug/L 11/10/09 --5 ------ND ND ND ND ND ND ND ----ND ug/L 05/26/10 --5 ------ND ND ND ND ND ND ND ----NDug/L 11/15/10 --5 ------ND ND ND ND ND ND ND ----NDug/L 05/09/11 --5 ------ND ND ND ND ND ND ND ----NDug/L 11/14/11 --5 ------ND ND ND ND ND ND ND ----ND ug/L 05/07/12 --5 ------ND ND ND ND ND Dry ND ----NDug/L 11/05/12 --5 ------ND ND ND ND ND ND ND ND ND NDug/L 05/13/13 --5 ------ND ND ND ND ND ND ND ND ND NDug/L 11/11/13 --5 ------ND ND ND ND ND ND ND ND ND ND ug/L 05/12/14 --5 ------ND ND ND ND ND ND ND ND ND NDug/L 11/17/14 0.45 5 ------ND ND ND ND ND ND ND ND ND NDug/L 05/12/15 0.45 5 ------ND ND ND ND ND ND ND ND ND NDug/L 11/09/15 0.45 5 -----ND ND ND ND ND ND ND ND ND ND Notes:ug/L =micrograms per liter ND =Not detected at the stated reporting limitJ =Estimated value B =Blank-qualified data -- =no data# =EPA Action Level * = EPA Secondary MCLBold only =Concentration above current NC 2L Groundwater Standard or NC SWS Groundwater Protection Standard Shaded and Bold =Concentration above current NC 2L Groundwater Standard or NC SWS Groundwater Protection Standard and EPA MCL GGI = Gravity Groundwater InterceptBlanks =field, trip and method blanksStandards =NC 2L Groundwater Standards or North Carolina Solid Waste Section Groundwater Protection StandardsSWS Reporting Limit =NCPQL or lab-specific reporting limit prior to 2007 and NCSWSL starting in 01/18/07 SWS GPS =Solid Waste Section Groundwater Protection Standard EPA MCL =US Environmental Protection Agency Maximum Contaminant LevelNC 2L = North Carolina 2L Groundwater Standard 1) MW-100A and MW-105A are replacement wells for MW-100 and MW-105, respectively. MW-100B replaced MW-100A prior to the May 2010 sampling event.2) Data prior to 2/28/07 provided by Richardson, Smith, Gardner and Associates. 3) Additions to GGI-1 were not constrtucted by the May 2010 compliance event. Golder returned to sample GGI-1 on 6-29-10 and the sampling point was dry. 4) Results from laboratory re-analyses are reported in parentheses. January 2016 Page 1 of 6 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx pH (field)S.U.05/28/02 4.1 --------4.4 --4.6 ----4.5 ---- S.U.11/05/02 4.3 --------4.5 --4.6 4.6 --4.7 ---- S.U.05/29/03 4.4 --------4.3 --3.9 4.1 --4.6 ---- S.U.11/05/03 ------4.5 4.5 ---------------- S.U.05/24/06 ------4.9 4.5 4.4 --4.9 4.3 --4.8 ---- S.U.11/20/06 ------4.8 4.8 4.3 --4.8 3.6 --4.5 ---- S.U.05/22/07 --5.55 --4.40 4.18 3.91 4.56 4.10 3.82 --4.40 ---- Verification Event S.U.08/07/07 ----------------3.50 -------- S.U.11/13/07 --5.80 --4.26 4.55 4.21 4.73 4.78 3.70 4.38 4.26 ---- Verification Event S.U.01/09/08 --------------4.54 ---------- S.U.05/29/08 --4.92 --4.23 4.22 3.72 4.53 4.74 3.40 4.14 4.17 ---- S.U.11/17/08 --5.10 --4.16 4.04 3.68 3.79 5.29 3.24 3.90 5.11 ---- Verification Event S.U.02/17/09 --------------------4.64 ---- S.U.05/26/09 --5.01 --4.69 4.55 3.93 4.48 5.47 3.62 4.09 4.75 ---- Verification Event S.U.07/23/09 ----------3.94 -------------- S.U.11/10/09 --4.80 --4.56 4.47 3.77 4.28 4.08 3.46 3.72 4.35 ---- Verification Event S.U.01/18/10 --------------3.43 -------- S.U.05/26/10 ----6.06 3.34 4.07 3.76 4.06 5.55 3.34 3.56 4.06 ---- S.U.11/15/10 ----7.11 4.92 4.75 3.86 4.20 6.32 3.50 3.82 4.31 ---- Verification Event S.U.12/21/10 --------------------4.38 ---- S.U.05/09/11 ----4.54 4.08 3.81 3.63 3.54 3.66 2.88 3.18 3.39 ---- S.U.11/14/11 ----5.13 5.16 5.20 3.90 4.64 4.19 3.64 4.01 4.25 ---- Verification Event S.U.01/17/12 -------------------------- S.U.05/07/12 ----5.53 4.02 3.36 3.69 3.67 3.60 Dry 3.22 3.89 ---- Verification Event S.U.07/11/12 -------------------------- S.U.11/05/12 ----5.38 4.29 3.89 4.04 4.44 4.11 3.09 --4.31 4.04 4.77 Verification Event S.U.01/10/13 ----------------3.31 -------- S.U.05/13/13 ----6.61 4.56 4.35 4.35 3.96 5.70 3.46 --4.29 4.04 5.48 S.U.11/11/13 ----5.75 4.76 4.88 4.13 4.61 4.18 3.60 --4.35 4.33 4.68 S.U.05/12/14 ----6.42 5.00 4.87 4.43 4.67 4.31 3.86 --4.43 5.72 4.43 S.U.11/17/14 ----5.33 4.17 4.26 3.64 4.17 3.45 3.42 --3.69 6.32 5.06 S.U.05/12/15 ----3.81 4.20 3.65 4.17 3.40 4.15 4.67 --4.09 6.30 5.11 S.U.11/09/15 ----4.84 3.48 3.71 3.76 3.92 4.62 3.54 --3.84 6.77 3.45 Verification Event S.U.12/30/15 ----------------------7.14 -- GGI Outfall 1 GGI Outfall 2MW-107S MW-107D TABLE 5 Summary of Field Parameters for MSW Wells Sampson County Active MSW Landfill, Permit No. 82-02 Sampson County, North Carolina MW-108 Upgradient Downgradient MW-100 MW-100A MW-100B MW-102A MW-103A MW-104 MW-105A MW-106 Detected Monitoring Constituent/Parameter Reporting Units Sample Date January 2016 Page 2 of 6 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx GGI Outfall 1 GGI Outfall 2MW-107S MW-107D TABLE 5 Summary of Field Parameters for MSW Wells Sampson County Active MSW Landfill, Permit No. 82-02 Sampson County, North Carolina MW-108 Upgradient Downgradient MW-100 MW-100A MW-100B MW-102A MW-103A MW-104 MW-105A MW-106 Detected Monitoring Constituent/Parameter Reporting Units Sample Date Specific Conductance (field)uS/cm 05/28/02 160 --------55 --26 ----38 ---- uS/cm 11/05/02 164 --------97 --31 53 --56 ---- uS/cm 05/29/03 -------------------------- uS/cm 11/05/03 ------54 44 ---------------- uS/cm 05/24/06 ------21 20 183 --24 271 --42 ---- uS/cm 11/20/06 ------33 25 148 --34 1142 --315 ---- uS/cm 05/22/07 --450 --20 11 270 300 14 685 --161 ---- Verification Event uS/cm 08/07/07 ----------------529 -------- uS/cm 11/13/07 --495 --29 29 220 65 54 777 226 538 ---- Verification Event uS/cm 01/09/08 --------------57 ---------- uS/cm 05/29/08 --213 --39 25 660 56 44 500 169 499 ---- uS/cm 11/17/08 --193 --81 38 299 50 62 769 157 1020 ---- Verification Event uS/cm 02/17/09 --------------------524 ---- uS/cm 05/26/09 --228 --15 26 437 53 41 648 222 676 ---- Verification Event uS/cm 07/23/09 ----------578 -------------- uS/cm 11/10/09 --177 --18 27 492 75 45 1265 329 422 ---- Verification Event uS/cm 01/18/10 ----------------1057 -------- uS/cm 05/26/10 ----524 16 22 675 94 85 1123 452 508 ---- uS/cm 11/15/10 ----385 20 22 581 215 172 1346 606 590 ---- Verification Event uS/cm 11/15/10 --------------------597 ---- uS/cm 05/09/11 ----423 21 23 190 118 67 1201 709 599 ---- uS/cm 11/14/11 ----313 18 17 636 83 46 980 584 392 ---- Verification Event uS/cm 01/17/12 -------------------------- uS/cm 05/07/12 ----356 17 17 726 83 95 Dry 645 685 ---- Verification Event uS/cm 07/11/12 -------------------------- uS/cm 11/05/12 ----257 21 19 441 78 58 1339 --508 332 123 Verification Event uS/cm 01/10/13 ----------------640 -------- uS/cm 05/13/13 ----353 19 18 480 72 69 452 --363 337 245 uS/cm 11/11/13 ----473 93 83 389 194 106 1019 --351 303 164 uS/cm 05/12/14 ----1018 61 46 402 106 86 348 --525 479 259 uS/cm 11/17/14 ----493 27 24 336 115 62 866 --547 498 261 uS/cm 05/12/15 ----371 22 18 169 73 38 466 --291 493 346 uS/cm 11/09/15 ----268 23 20 188 125 44 444 --757 1175 50 Verification Event uS/cm 12/30/15 ----------------------1465 -- January 2016 Page 3 of 6 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx GGI Outfall 1 GGI Outfall 2MW-107S MW-107D TABLE 5 Summary of Field Parameters for MSW Wells Sampson County Active MSW Landfill, Permit No. 82-02 Sampson County, North Carolina MW-108 Upgradient Downgradient MW-100 MW-100A MW-100B MW-102A MW-103A MW-104 MW-105A MW-106 Detected Monitoring Constituent/Parameter Reporting Units Sample Date Temperature (field)Celsius 05/28/02 19.00 --------22.00 --20.00 ----20.00 ---- Celsius 11/05/02 18.00 --------21.00 --21.00 22.00 --21.00 ---- Celsius 05/29/03 18.00 --------18.00 --17.00 19.00 --19.00 ---- Celsius 11/05/03 ------22.00 20.00 ---------------- Celsius 05/24/06 ------17.00 22.00 21.00 --20.00 21.00 --25.00 ---- Celsius 11/20/06 ------19.00 18.00 19.00 --19.00 20.00 --21.00 ---- Celsius 05/22/07 --22.71 --18.84 17.90 18.11 17.22 17.16 19.88 --21.98 ---- Verification Event Celsius 08/07/07 ----------------22.39 -------- Celsius 11/13/07 --19.88 --22.07 20.98 22.33 20.09 21.70 27.22 22.71 23.85 ---- Verification Event Celsius 01/09/08 --------------17.93 ---------- Celsius 05/29/08 --18.88 --18.54 18.32 19.23 17.69 16.83 23.83 21.09 21.35 ---- Celsius 11/17/08 --16.95 --21.22 18.68 21.29 19.45 19.23 21.13 19.98 22.48 ---- Verification Event Celsius 02/17/09 --------------------21.00 ---- Celsius 05/26/09 --18.61 --19.10 18.14 19.84 18.05 19.20 20.82 20.10 22.36 ---- Verification Event Celsius 07/23/09 ----------26.46 -------------- Celsius 11/10/09 --18.99 --22.02 20.64 21.38 20.35 21.74 20.74 21.96 24.02 ---- Verification Event Celsius 01/18/10 --------------18.49 -------- Celsius 05/26/10 ----18.64 17.62 18.76 20.16 17.41 19.25 20.92 19.90 22.14 ---- Celsius 11/15/10 ----20.47 22.64 18.94 21.85 20.02 21.10 21.17 22.92 24.23 ---- Verification Event Celsius 12/21/10 --------------------21.18 ---- Celsius 05/09/11 ----16.59 20.26 17.36 19.16 17.73 18.66 21.48 19.78 21.57 ---- Celsius 11/14/11 ----19.48 23.41 20.1 21.87 19.93 22.19 20.69 21.95 24.55 ---- Verification Event Celsius 01/17/12 -------------------------- Celsius 05/07/12 ----18.70 20.37 18.34 19..51 17.51 19.48 Dry 22.37 23.52 ---- Verification Event Celsius 07/11/12 -------------------------- Celsius 11/05/12 ----18.20 22.53 19.91 22.33 18.52 20.82 18.92 --23.57 20.79 21.56 Verification Event Celsius 01/10/13 ----------------19.20 -------- Celsius 05/13/13 ----19.26 21.02 20.45 20.52 16.20 21.53 14.84 --21.22 20.56 21.94 Celsius 11/11/13 ----20.3 22.8 20.7 24.3 19.1 21.6 18.7 --24.0 21.7 22.5 Celsius 05/12/14 ----21.0 20.1 19.4 20.4 17.0 21.0 16..2 --21.5 27.7 24.3 Celsius 11/17/14 ----20.3 21.1 20.1 22.7 15.3 21.1 17.4 --23.4 8.8 6.6 Celsius 05/12/15 ----19.7 18.8 18.8 18.6 19.3 17.1 17.2 --18.9 24.0 20.1 Celsius 11/09/15 ----19.3 22.1 19.9 21.9 18.3 21.2 21.2 --23.8 18.5 16.9 Verification Event Celsius 12/30/15 ----------------------22.1 -- January 2016 Page 4 of 6 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx GGI Outfall 1 GGI Outfall 2MW-107S MW-107D TABLE 5 Summary of Field Parameters for MSW Wells Sampson County Active MSW Landfill, Permit No. 82-02 Sampson County, North Carolina MW-108 Upgradient Downgradient MW-100 MW-100A MW-100B MW-102A MW-103A MW-104 MW-105A MW-106 Detected Monitoring Constituent/Parameter Reporting Units Sample Date Turbidity (field)NTU 05/22/07 --0 --32 20.2 17 61.4 68.1 0 --113 ---- Verification Event NTU 08/07/07 ---------------->1000 -------- NTU 11/13/07 --133 --45.5 16.7 44.8 75.3 38.7 271 39.4 32.2 ---- Verification Event NTU 01/09/08 --------------20.2 ---------- NTU 05/29/08 --197 --7.80 8.56 8.66 99.1 61.0 9.36 6.88 5.49 ---- NTU 11/17/08 --36.9 --28.1 2.31 25.6 7.91 8.26 11.6 1.10 6.86 ---- Verification Event NTU 02/17/09 --------------------1.27 ---- NTU 05/26/09 --18.9 --7.61 41.7 45.1 30.3 49.2 7.65 3.96 7.62 ---- Verification Event NTU 07/23/09 ----------19.6 -------------- NTU 11/10/09 --34.6 --97.0 17.7 5.13 1.94 73.0 54.10 1.37 4.10 ---- Verification Event NTU 01/18/10 ----------------16.4 -------- NTU 05/26/10 ----16.4 9.16 3.29 19.5 0.47 9.94 19.5 1.76 1.10 ---- NTU 11/15/10 ----3.36 16.2 3.05 2.35 1.32 18.1 41.3 1.62 1.92 ---- Verification Event NTU 12/21/10 --------------------10.4 ---- NTU 05/09/11 ----1.75 10.8 3.39 4.83 0.42 6.05 12.7 1.03 0.69 ---- NTU 11/14/11 ----18.1 8.32 26.7 5.82 3.77 16.0 32.6 2.94 1.23 ---- NTU 01/17/12 -------------------------- NTU 05/07/12 ----4.58 77.4 16.3 6.44 2.46 227 Dry 2.60 4.35 ---- Verification Event NTU 07/11/12 -------------------------- NTU 11/05/12 ----12.1 2.22 6.49 3.57 11.6 88.1 23.7 --2.14 7.36 1.21 Verification Event NTU 01/10/13 ----------------214 -------- NTU 05/13/13 ----4.03 6.35 2.85 6.14 4.38 26.2 3.56 --1.21 1.40 3.31 NTU 11/11/13 ----3.82 4.04 5.00 12.2 16.4 12.0 21.0 --10.5 2.33 1.85 NTU 05/12/14 ----3.74 7.26 5.23 6.61 92.5 8.66 4.63 --3.18 7.41 4.56 NTU 11/17/14 ----1.38 9.21 2.22 5.22 51.1 31.0 13.6 --6.37 13.6 7.42 NTU 05/12/15 ----14.6 14.1 2.04 3.88 24.0 6.35 20.9 --0.96 46.8 8.72 NTU 11/09/15 ----5.96 7.57 1.99 5.68 30.8 29.80 47.8 --1.73 58.3 64.6 Verification Event NTU 12/30/15 ----------------------70.5 -- January 2016 Page 5 of 6 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx GGI Outfall 1 GGI Outfall 2MW-107S MW-107D TABLE 5 Summary of Field Parameters for MSW Wells Sampson County Active MSW Landfill, Permit No. 82-02 Sampson County, North Carolina MW-108 Upgradient Downgradient MW-100 MW-100A MW-100B MW-102A MW-103A MW-104 MW-105A MW-106 Detected Monitoring Constituent/Parameter Reporting Units Sample Date ORP (field)millivolts 05/22/07 ------332 350 349 229 235 ----66 ---- millivolts 11/13/07 ------317 333 404 266 312 351 322 279 ---- Verification Event millivolts 01/09/08 --------------150 ---------- millivolts 05/29/08 ------303 317 404 186 55 308 280 187 ---- millivolts 11/17/08 ------314.0 310.6 350.7 240.7 91.0 358.1 310.5 -60.3 ---- Verification Event millivolts 02/17/09 --------------------50.7 ---- millivolts 05/26/09 ------202.2 219.5 311.9 218.3 142.9 331.2 277.7 61.5 ---- Verification Event millivolts 07/23/09 ----------576 -------------- millivolts 11/10/09 ------251.7 260.8 331.2 252.8 277.9 299.4 321.9 227.8 ---- Verification Event millivolts 01/18/10 --------------312.5 -------- millivolts 05/26/10 ------241.2 217.2 263.2 215.1 43.6 298.1 272.5 232 ---- millivolts 11/15/10 ------243.2 254.5 366.7 340.3 -19.0 341.1 312.0 260.9 ---- Verification Event millivolts 12/21/10 --------------------212.3 ---- millivolts 05/09/11 ------237.4 255.2 229.9 230.9 242.3 314.8 266.5 266.4 ---- millivolts 11/14/11 ------98.9 91.7 169.0 109.9 118.4 374.4 238.7 177.6 ---- millivolts 05/07/12 ------243.3 271.3 256.7 222.5 160.9 Dry 289.5 225.4 ---- Verification Event millivolts 07/11/12 -------------------------- millivolts 11/05/12 ----10.8 149.3 165.7 153.1 99.4 119.3 ----100.7 224.7 213.7 millivolts 05/13/13 ----86.8 127.1 138.5 132.3 113.1 -17.0 ----101.5 130.1 93.4 millivolts 11/11/13 ----265.8 341.5 332.4 392.5 281.7 134.4 ----359.1 402.3 352.5 millivolts 05/12/14 ----180.6 315.1 337.3 405.2 280.5 410.2 ----418.8 287.5 361.7 millivolts 11/17/14 ----194.4 159.6 199.2 257.8 297.8 267.0 ----316.3 155.5 83.5 millivolts 05/12/15 ----156.0 196.3 178.4 164.7 187.5 156.7 148.7 --176.8 74.5 163.3 millivolts 11/09/15 ----408.8 540.9 536.8 467.4 364.0 43.9 379.7 --400.1 132.5 402 Verification Event millivolts 12/30/15 ----------------------130.6 -- January 2016 Page 6 of 6 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx GGI Outfall 1 GGI Outfall 2MW-107S MW-107D TABLE 5 Summary of Field Parameters for MSW Wells Sampson County Active MSW Landfill, Permit No. 82-02 Sampson County, North Carolina MW-108 Upgradient Downgradient MW-100 MW-100A MW-100B MW-102A MW-103A MW-104 MW-105A MW-106 Detected Monitoring Constituent/Parameter Reporting Units Sample Date Dissolved Oxygen (field)mg/L 05/22/07 ------3.90 8.80 1.50 2.20 4.50 ----0.40 ---- mg/L 11/13/07 ------7.91 8.30 1.60 4.05 4.68 2.49 1.06 0.78 ---- Verification Event mg/L 01/09/08 --------------2.64 ---------- mg/L 05/29/08 ------6.97 9.23 1.44 0.30 1.01 0.91 0.37 1.99 ---- mg/L 11/17/08 ------8.21 8.14 10.09 2.83 2.80 4.18 1.62 10.34 ---- Verification Event mg/L 02/17/09 --------------------0.39 ---- mg/L 05/26/09 ------9.23 8.90 4.03 0.84 3.50 1.90 0.66 1.46 ---- Verification Event mg/L 07/23/09 ----------1.81 -------------- mg/L 11/10/09 ------8.40 8.58 2.85 2.72 4.57 0.87 0.55 0.79 ---- Verification Event mg/L 01/18/10 --------------1.35 -------- mg/L 05/26/10 ------8.34 7.91 2.39 0.82 1.27 1.04 0.60 0.99 ---- mg/L 11/15/10 ------7.40 8.72 2.02 1.03 1.66 2.84 1.09 3.04 ---- Verification Event mg/L 12/21/10 --------------------1.74 ---- mg/L 05/09/11 ------7.48 8.02 6.18 0.61 5.00 4.46 0.63 0.71 ---- mg/L 11/14/11 ------7.66 7.83 4.98 0.99 3.42 3.16 2.70 1.41 ---- mg/L 05/07/12 ------8.87 8.51 6.48 0.80 4.19 Dry 2.14 1.73 ---- Verification Event mg/L 07/11/12 -------------------------- mg/L 11/05/12 ----0.49 6.84 7.06 3.45 1.09 2.76 ----1.53 5.39 4.38 mg/L 05/13/13 ----0.49 7.08 7.44 4.88 0.37 2.13 ----1.47 6.28 2.93 mg/L 11/11/13 ----0.52 7.26 8.04 3.59 1.21 2.72 ----1.35 5.41 3.41 mg/L 05/12/14 ----1.02 8.25 9.01 5.89 0.62 5.46 ----1.27 5.50 2.03 mg/L 11/17/14 ----0.60 7.76 7.19 2.64 0.70 4.97 ----1.72 6.26 7.29 mg/L 05/12/15 ----0.69 6.64 7.13 5.21 0.54 3.03 2.81 --0.69 4.82 1.59 mg/L 11/09/15 ----1.93 7.61 7.43 4.82 0.65 1.32 3.56 --0.64 4.82 6.49 Verification Event mg/L 12/30/15 ----------------------4.70 -- Notes:mg/L =milligrams per liter S.U. =Standard Units NTU =Nephelometric Turbidity Units ND =Not detected at the stated reporting limit uS/cm=microsiemens per centimeter -- =no data GGI = Gravity Groundwater Intercept January 2016 Page 1 of 17 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx MW-1N MW-2N MW-3N MW-4N MW-5AN MW-5BN Antimony ug/L 10/08/96 --5 ND ND ND --------SWS GPS = 1 ug/L ug/L 02/18/97 --5 ND ND ND --------EPA MCL = 6 ug/L ug/L 08/29/97 --30 ND ND ND --------ug/L 02/23/98 --10 ND ND ND --------ug/L 08/24/98 --10 ND ND ND --------ug/L 02/22/99 --10 ND ND ND --------ug/L 08/23/99 --10 ND ND ND --------ug/L 02/21/00 --10 ND ND ND --------ug/L 07/12/01 --30 ND ND ND ND ND ND --ug/L 10/24/01 --30 ND ND ND ND ND ND --ug/L 05/28/02 --30 --------------ug/L 11/05/02 --30 --------------ug/L 05/29/03 --30 --------------ug/L 11/05/03 --30 -------------- ug/L 05/25/04 --30 --------------ug/L 11/23/04 --30 --------------ug/L 05/16/05 --30 --------------ug/L 11/25/05 --30 --------------ug/L 05/24/06 --30 ------------NDug/L 11/20/06 --30 ------------NDug/L 05/22/07 --6 0.63 J ND ND ND ND ND NDug/L 11/14/07 --6 ND ND ND ND ND ND NDug/L 05/29/08 --6 ND ND ND ND ND ND NDug/L 11/17/08 --6 ND ND ND ND ND ND NDug/L 05/27/09 --6 ND ND ND ND ND ND NDug/L 11/11/09 --6 0.661 J 0.474 J 0.251 B ND 0.302 B ND 0.0730 Jug/L 05/26/10 --6 ND ND ND ND ND ND NDug/L 11/15/10 --6 ND ND ND ND ND ND NDug/L 05/09/11 --6 ND ND ND ND ND ND NDug/L 11/14/11 --6 ND ND ND ND ND ND NDug/L 05/08/12 --6 0.382 J ND 1.15 J ND 0.390 J ND NDug/L 11/05/12 --6 ND ND ND ND ND ND NDug/L 05/14/13 --6 ND ND ND ND ND ND NDug/L 11/12/13 --6 ND ND ND ND ND ND NDug/L 05/13/14 --6 ND ND ND ND ND ND NDug/L 11/17/14 0.220 6 ND 0.762 J ND ND ND ND NDug/L 05/12/15 0.220 6 ND ND ND ND ND ND NDug/L 11/09/15 0.220 6 ND ND ND ND ND ND NDArsenic ug/L 10/08/96 --5 ND ND ND -------- NC 2L = 10 ug/L ug/L 02/18/97 --5 ND ND ND --------EPA MCL = 10 ug/L ug/L 08/29/97 --10 ND ND ND --------ug/L 02/23/98 --5 ND ND ND --------ug/L 08/24/98 --5 ND 6.18 13 --------ug/L 02/22/99 --5 ND ND 9.09 --------ug/L 08/23/99 --5 ND 9.11 16 --------ug/L 02/21/00 --5 ND 9.94 9.64 --------ug/L 10/10/00 --10 ND ND 13 ND ND ND -- ug/L 07/12/01 --10 ND ND ND ND ND ND --ug/L 10/24/01 --10 ND ND ND ND ND ND --ug/L 05/28/02 --10 ND ND ND ND ND ND --ug/L 11/05/02 --10 ND ND ND ND ND ND --ug/L 05/29/03 --10 ND ND ND ND ND ND --ug/L 11/05/03 --10 --------------ug/L 05/25/04 --10 ND 12 ND ND ND ND --ug/L 11/23/04 --10 ND ND ND ND ND ND --ug/L 05/16/05 --10 ND ND ND ND ND ND --ug/L 11/25/05 --10 ND ND ND ND ND ND --ug/L 05/24/06 --10 ND ND ND ND ND ND NDug/L 11/20/06 --10 ND 14 ND 10 ND ND NDug/L 05/22/07 --10 ND ND ND ND ND ND 2.2 Jug/L 11/14/07 --10 ND ND ND ND ND ND NDug/L 05/29/08 --10 ND ND 4.8 B ND 3.2 B 2.0 B 3.2 Jug/L 11/17/08 --10 ND ND ND ND ND ND NDug/L 05/27/09 --10 3.2 J 6.2 J 9.2 J ND ND ND ND ug/L 11/11/09 --10 ND ND ND ND ND ND NDug/L 05/26/10 --10 ND 3.76 J 7.44 J ND ND ND NDug/L 11/15/10 --10 ND 3.25 B ND ND ND ND 3.98 Jug/L 05/09/11 --10 ND ND 7.77 J 3.11 J ND ND NDug/L 11/14/11 --10 ND ND ND ND 3.67 J ND NDug/L 05/08/12 --10 ND ND ND ND ND ND NDug/L 11/05/12 --10 3.57 B 3.43 B ND 3.18 B 4.00 B ND 4.48 Jug/L 05/14/13 --10 ND ND ND ND ND ND ND ug/L 11/12/13 --10 ND ND ND ND ND ND NDug/L 05/13/14 --10 ND ND ND ND ND ND NDug/L 11/17/14 5.40 10 ND ND ND ND ND ND NDug/L 05/12/15 5.40 10 ND ND ND ND ND ND NDug/L 11/09/15 5.40 10 ND ND 10.1 ND ND ND ND SWS Reporting Limit Upgradient Downgradient Summary of Groundwater Monitoring Results for C&D Wells BlanksMethod Detection Limit TABLE 6 Sampson County, North Carolina Detected Constituents Sampson County Active C&D Landfill, Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date January 2016 Page 2 of 17 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx MW-1N MW-2N MW-3N MW-4N MW-5AN MW-5BN SWS Reporting Limit Upgradient Downgradient Summary of Groundwater Monitoring Results for C&D Wells BlanksMethod Detection Limit TABLE 6 Sampson County, North Carolina Detected Constituents Sampson County Active C&D Landfill, Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date Barium ug/L 10/08/96 ----31 28 25 --------NC 2L = 700 ug/L ug/L 02/18/97 --500 26 71 23 --------EPA MCL = 2000 ug/L ug/L 08/29/97 --500 ND ND ND --------ug/L 02/23/98 ----47 165 180 --------ug/L 08/24/98 ----34.3 178 159 --------ug/L 02/22/99 ----37.9 145 162 --------ug/L 08/23/99 ----64.1 148 201 --------ug/L 02/21/00 ----28.6 157 195 --------ug/L 10/10/00 --500 ND ND ND ND ND ND --ug/L 07/12/01 --500 ND ND ND ND ND ND --ug/L 10/24/01 --500 ND ND ND ND ND ND --ug/L 05/28/02 --500 ND ND ND ND ND ND --ug/L 11/05/02 --500 ND ND ND ND ND ND --ug/L 05/29/03 --500 ND ND ND ND ND ND -- ug/L 11/05/03 --500 --------------ug/L 05/25/04 --500 ND ND ND ND ND ND --ug/L 11/23/04 --500 ND ND ND ND ND ND --ug/L 05/16/05 --500 ND ND ND ND ND ND --ug/L 11/25/05 --500 ND ND ND ND ND ND --ug/L 05/24/06 --500 ND ND ND ND ND ND NDug/L 11/20/06 --500 ND ND ND ND ND ND NDug/L 05/22/07 --100 105 90.2 J 151 80.5 J 69.7 J 36.7 J 0.3 Jug/L 11/14/07 --100 253 101 95.2 J 120 73.3 J 33.1 J 0.20 Jug/L 05/29/08 --100 111 60.5 J 138 91.4 J 55.2 J 29.5 J 0.6 Jug/L 11/17/08 --100 109 61.3 J 148 51.5 J 18.2 J 36.7 J NDug/L 05/27/09 --100 96.2 J 60.5 J 156 78.2 J 44.1 J 34.9 J NDug/L 11/11/09 --100 225 69.8 J 95.2 J 93.5 J 74.1 J 33.0 J NDug/L 05/26/10 --100 50.1 J 76.2 J 119 29.7 J 16.1 J 33.0 J NDug/L 11/15/10 --100 56.0 J 55.7 J 107 96.7 J 36.5 J 34.1 J NDug/L 05/09/11 --100 135 71.7 J 137 68.8 J 51.6 J 31.8 J NDug/L 11/14/11 --100 166 73.1 J 115 53.8 J 69.7 J 36.3 J NDug/L 05/08/12 --100 146 60.5 J 127 43.0 J 55.9 J 29.3 J NDug/L 11/05/12 --100 233 81.4 J 138 75.3 J 65.2 J 37.6 J NDug/L 05/14/13 --100 229 60.5 J 104 25.2 J 30.0 J 36.4 J 1.21 Jug/L 11/12/13 --100 126 61.5 J 155 52.9 J 52.3 J 33.8 J 1.22 Jug/L 05/13/14 --100 68.1 J 47.2 J 153 13.4 J 26.6 J 32.0 J NDug/L 11/17/14 1.00 100 179 56.8 J 147 150 53.7 J 31.6 J NDug/L 05/12/15 1.00 100 54.6 J 42.8 J 155 30.3 J 15.9 J 37.8 J NDug/L 11/09/15 1.00 100 105 57.3 J 173 33.2 J 16.0 J 34.9 J ND Beryllium ug/L 10/08/96 --1 ND ND ND --------GWPS = 4 ug/L ug/L 10/24/96 ------------------EPA MCL = 4 ug/L ug/L 02/18/97 --1 ND ND ND --------ug/L 02/19/97 --1 --------------ug/L 04/24/97 ------------------ug/L 08/28/97 --2 --------------ug/L 08/29/97 --2 ND ND ND --------ug/L 10/09/97 ------------------ ug/L 10/30/97 ------------------ug/L 02/23/98 --5 ND ND ND --------ug/L 02/24/98 --5 --------------ug/L 04/20/98 ------------------ug/L 08/24/98 --5 ND ND ND --------ug/L 10/27/98 ------------------ug/L 02/22/99 --5 ND ND ND --------ug/L 04/20/99 ------------------ug/L 08/23/99 --5 ND ND ND --------ug/L 08/24/99 --5 --------------ug/L 01/11/00 --5 --------------ug/L 02/21/00 --5 ND ND ND --------ug/L 02/22/00 --5 --------------ug/L 10/10/00 --2 --------------ug/L 07/12/01 --2 ND ND ND ND ND ND --ug/L 10/24/01 --2 ND ND ND ND ND ND --ug/L 05/28/02 --2 -------------- ug/L 11/05/02 --2 --------------ug/L 05/29/03 --2 --------------ug/L 11/05/03 --2 --------------ug/L 05/25/04 --2 --------------ug/L 11/23/04 --2 --------------ug/L 05/16/05 --2 --------------ug/L 11/25/05 --2 --------------ug/L 05/24/06 --2 ------------ND ug/L 11/20/06 --2 ------------NDug/L 05/22/07 --1 ND ND ND ND ND ND NDug/L 11/14/07 --1 ND ND ND ND ND ND NDug/L 05/29/08 --1 ND ND ND ND ND ND NDug/L 11/17/08 --1 ND ND ND ND ND ND NDug/L 05/27/09 --1 0.11 J ND ND 0.09 J ND ND NDug/L 11/11/09 --1 0.245 J ND ND ND ND ND NDug/L 05/26/10 --1 ND ND ND ND ND ND NDug/L 11/15/10 --1 ND ND ND ND ND 0.115 B 0.106 Jug/L 05/09/11 --1 ND ND ND ND ND ND NDug/L 11/14/11 --1 0.162 J ND ND ND 0.101 J 0.108 J NDug/L 05/08/12 --1 0.188 J ND ND ND ND ND NDug/L 11/05/12 --1 0.208 J ND ND 0.102 J ND ND NDug/L 05/14/13 --1 0.185 J ND ND ND ND ND NDug/L 11/12/13 --1 0.111 J ND ND ND ND ND NDug/L 05/13/14 --1 ND ND ND ND ND ND NDug/L 11/17/14 0.100 1 0.160 J ND ND 0.203 J ND 0.114 J ND ug/L 05/12/15 0.100 1 ND ND ND ND ND ND NDug/L 11/09/15 0.100 1 ND ND ND ND ND ND ND January 2016 Page 3 of 17 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx MW-1N MW-2N MW-3N MW-4N MW-5AN MW-5BN SWS Reporting Limit Upgradient Downgradient Summary of Groundwater Monitoring Results for C&D Wells BlanksMethod Detection Limit TABLE 6 Sampson County, North Carolina Detected Constituents Sampson County Active C&D Landfill, Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date Cadmium ug/L 02/05/96 --1 ND ------------NC 2L = 2 ug/L ug/L 10/08/96 --1 --ND ND --------EPA MCL = 5 ug/L ug/L 02/18/97 --1 ND ND ND --------ug/L 08/29/97 --1 ND ND ND --------ug/L 02/23/98 --5 ND ND ND --------ug/L 08/24/98 --5 ND ND ND --------ug/L 02/22/99 --5 ND ND ND --------ug/L 08/23/99 --5 ND ND ND --------ug/L 02/21/00 --5 ND ND ND --------ug/L 10/10/00 --1 ND 7 4 ND ND ND --ug/L 07/12/01 --1 ND 6 3 ND ND ND --ug/L 10/24/01 --1 ND 4 3 ND ND ND --ug/L 05/28/02 --1 ND ND ND ND ND ND --ug/L 11/05/02 --1 ND ND ND ND ND ND -- ug/L 05/29/03 --1 ND ND ND ND ND ND --ug/L 11/05/03 --1 --------------ug/L 05/25/04 --1 ND ND ND ND ND ND --ug/L 11/23/04 --1 ND ND ND ND ND ND --ug/L 05/16/05 --1 ND ND ND ND ND ND --ug/L 11/25/05 --1 ND ND ND ND ND ND --ug/L 05/24/06 --1 ND ND ND ND ND ND NDug/L 11/20/06 --1 ND ND ND ND ND ND NDug/L 05/22/07 --1 0.50 J ND ND ND ND ND NDug/L 11/14/07 --1 ND ND ND ND ND 0.50 J NDug/L 05/29/08 --1 ND ND ND ND ND ND 0.5 Jug/L 11/17/08 --1 ND ND ND ND ND ND NDug/L 05/27/09 --1 0.20 J 0.24 J 0.14 J ND 0.14 J ND NDug/L 11/11/09 --1 ND ND ND ND ND ND NDug/L 05/26/10 --1 ND ND ND ND ND ND NDug/L 11/15/10 --1 ND ND ND ND ND 0.400 J NDug/L 05/09/11 --1 ND ND ND ND ND ND NDug/L 11/14/11 --1 ND ND ND ND ND ND NDug/L 05/08/12 --1 ND ND ND ND ND ND NDug/L 11/05/12 --1 ND ND ND ND ND ND NDug/L 05/14/13 --1 ND ND ND ND ND ND NDug/L 11/12/13 --1 ND ND ND ND ND ND NDug/L 05/13/14 --1 ND ND ND ND ND ND NDug/L 11/17/14 0.360 1 0.564 J ND ND ND ND ND NDug/L 05/12/15 0.360 1 ND ND ND ND ND ND ND ug/L 11/09/15 0.360 1 ND ND ND ND ND ND NDChromium ug/L 10/08/96 --2 ND ND ND --------NC 2L = 10 ug/L ug/L 02/18/97 --2 ND ND ND --------EPA MCL = 100 ug/L ug/L 08/29/97 --10 ND ND ND --------ug/L 02/23/98 --5 ND ND ND --------ug/L 08/24/98 --5 ND ND ND --------ug/L 02/22/99 --5 ND ND ND --------ug/L 08/23/99 --5 ND ND ND --------ug/L 02/21/00 --5 ND ND ND --------ug/L 10/10/00 --10 ND ND ND ND ND ND --ug/L 07/12/01 --10 ND ND ND 22 ND ND --ug/L 10/24/01 --10 ND ND ND ND ND ND --ug/L 05/28/02 --10 20 ND ND 28 19 ND --ug/L 11/05/02 --10 ND ND ND ND ND ND --ug/L 05/29/03 --10 ND ND ND 96 ND ND --ug/L 11/05/03 --10 --------------ug/L 05/25/04 --10 ND ND ND ND ND ND --ug/L 11/23/04 --10 ND ND ND ND 14 ND --ug/L 05/16/05 --10 ND ND ND ND ND ND --ug/L 11/25/05 --10 ND ND ND ND ND ND --ug/L 05/24/06 --10 ND ND ND ND ND ND NDug/L 11/20/06 --10 ND ND ND 31 ND ND NDug/L 05/22/07 --10 ND ND ND 52.9 ND ND NDug/L 11/14/07 --10 ND ND ND 12.7 ND ND NDug/L 05/29/08 --10 ND ND ND 8.2 J 2.0 J ND ND ug/L 11/17/08 --10 3.4 B ND ND 14.1 B 3.3 B 1.4 B 4.9 Jug/L 05/27/09 --10 ND ND ND 7.5 J 1.4 J ND NDug/L 11/11/09 --10 ND 27.0 2.64 J 39.2 8.53 J ND NDug/L 05/26/10 --10 ND 4.34 J 1.86 J 14.5 5.23 J ND NDug/L 11/15/10 --10 ND 4.54 J 1.59 J 11.6 2.41 J ND NDug/L 05/09/11 --10 ND ND 2.56 J 4.31 J 3.60 J ND NDug/L 11/14/11 --10 ND 1.47 J 3.20 J 3.89 J 13.7 ND NDug/L 05/08/12 --10 2.09 J 2.67 J 2.61 J 12.4 14.2 ND ND ug/L 11/05/12 --10 19.4 1.14 J 1.73 J 14.8 11.2 ND NDug/L 05/14/13 --10 1.93 J 2.31 J 1.60 J 24.8 7.86 J ND NDug/L 11/12/13 --10 1.97 J ND 6.16 J 17.4 9.34 J 4.34 1 NDug/L 05/13/14 --10 ND 5.58 J ND 57.9 10.5 ND NDug/L 11/17/14 1.40 10 ND ND 1.70 J 10.3 9.85 J ND NDug/L 05/12/15 1.40 10 2.50 B 1.91 B 3.28 B 33.0 16.0 1.79 B 1.68 Jug/L 11/09/15 1.40 10 ND ND ND 19.1 14.3 ND ND January 2016 Page 4 of 17 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx MW-1N MW-2N MW-3N MW-4N MW-5AN MW-5BN SWS Reporting Limit Upgradient Downgradient Summary of Groundwater Monitoring Results for C&D Wells BlanksMethod Detection Limit TABLE 6 Sampson County, North Carolina Detected Constituents Sampson County Active C&D Landfill, Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date Cobalt ug/L 10/08/96 --2 ND ND ND --------GWPS = 1 ug/L ug/L 10/24/96 ------------------No EPA MCL ug/L 02/18/97 --3 ND ND ND --------ug/L 02/19/97 --3 --------------ug/L 04/24/97 ------------------ug/L 08/28/97 --10 --------------ug/L 08/29/97 --10 ND ND ND --------ug/L 10/09/97 ------------------ug/L 10/30/97 ------------------ug/L 02/23/98 --5 ND ND ND --------ug/L 02/24/98 --5 --------------ug/L 04/20/98 ------------------ug/L 08/24/98 --5 ND ND ND --------ug/L 10/27/98 ------------------ ug/L 02/22/99 --5 ND ND ND --------ug/L 04/20/99 ------------------ug/L 08/23/99 --5 ND ND ND --------ug/L 08/24/99 --5 --------------ug/L 01/11/00 --5 --------------ug/L 02/21/00 --5 ND ND ND --------ug/L 02/22/00 --5 --------------ug/L 10/10/00 --10 --------------ug/L 07/12/01 --10 ND ND ND ND ND ND --ug/L 10/24/01 --10 ND ND ND ND ND ND --ug/L 05/28/02 --10 --------------ug/L 11/05/02 --10 --------------ug/L 05/29/03 --10 --------------ug/L 11/05/03 --10 --------------ug/L 05/25/04 --10 --------------ug/L 11/23/04 --10 --------------ug/L 05/16/05 --10 --------------ug/L 11/25/05 --10 --------------ug/L 05/24/06 --10 ------------NDug/L 11/20/06 --10 ------------NDug/L 05/22/07 --10 ND ND ND ND ND ND NDug/L 11/14/07 --10 3.0 J ND ND ND ND ND NDug/L 05/29/08 --10 2.4 J ND ND 3.1 J 2.2 J ND NDug/L 11/17/08 --10 1.5 J ND ND ND ND ND NDug/L 05/27/09 --10 1.1 J 0.7 J ND 0.9 J 1.0 J 0.6 J ND ug/L 11/11/09 --10 2.05 J ND ND 1.57 J 1.26 J ND NDug/L 05/26/10 --10 ND ND ND 1.54 J 1.24 J ND NDug/L 11/15/10 --10 ND ND ND 1.19 J ND ND NDug/L 05/09/11 --10 ND ND ND ND 1.22 J ND NDug/L 11/14/11 --10 ND ND ND ND 3.83 J ND NDug/L 05/08/12 --10 1.50 J ND ND ND 8.12 J ND NDug/L 11/05/12 --10 2.93 J 1.13 J ND 1.38 J 8.68 J 1.40 J NDug/L 05/14/13 --10 2.09 J ND ND ND 9.01 J 1.15 J ND ug/L 11/12/13 --10 1.35 J ND ND 1.22 J 11.9 ND NDug/L 05/13/14 --10 ND ND ND 1.78 J 8.78 J ND NDug/L 11/17/14 1.10 10 1.92 J 1.17 J ND 2.10 J 9.58 J 1.40 J NDug/L 05/12/15 1.10 10 ND ND ND 2.73 J 9.21 J 1.24 J NDug/L 11/09/15 1.10 10 ND ND ND ND 9.10 J ND NDCopper ug/L 10/08/96 --10 ND ND ND --------NC 2L = 1000 ug/L ug/L 02/18/97 --50 ND ND ND --------EPA MCL = 1300 ug/L#ug/L 08/29/97 --200 ND ND ND --------ug/L 02/23/98 --5 ND ND ND --------ug/L 08/24/98 --5 ND ND ND --------ug/L 02/22/99 --5 ND ND ND --------ug/L 08/23/99 --5 ND ND ND --------ug/L 02/21/00 --5 ND ND ND --------ug/L 07/12/01 --200 ND ND ND ND ND ND --ug/L 10/24/01 --200 ND ND ND ND ND ND --ug/L 05/28/02 --200 --------------ug/L 11/05/02 --200 -------------- ug/L 05/29/03 --200 --------------ug/L 11/05/03 --200 --------------ug/L 05/25/04 --200 --------------ug/L 11/23/04 --200 --------------ug/L 05/16/05 --200 --------------ug/L 11/25/05 --200 --------------ug/L 05/24/06 --200 ------------NDug/L 11/20/06 --200 ------------ND ug/L 05/22/07 --10 ND ND ND ND ND 6.00 J NDug/L 11/14/07 --10 0.70 J ND ND ND ND 2.80 J NDug/L 05/29/08 --10 ND ND ND 2.00 B ND 8.10 J 1.00 Jug/L 11/17/08 --10 ND ND ND ND 1.60 J 2.00 J NDug/L 05/27/09 --10 ND ND ND ND 4.66 B 7.31 B 1.47 Jug/L 11/11/09 --10 ND ND ND 2.94 J 3.01 J 2.78 J NDug/L 05/26/10 --10 ND ND ND 3.97 J 3.74 J 3.40 J NDug/L 11/15/10 --10 ND ND ND 2.17 J ND ND NDug/L 05/09/11 --10 ND ND ND ND ND 5.54 J NDug/L 11/14/11 --10 ND ND ND ND 2.65 J 2.99 J NDug/L 05/08/12 --10 ND ND ND 1.80 J ND 6.63 J NDug/L 11/05/12 --10 ND ND ND ND ND 1.99 J NDug/L 05/14/13 --10 ND ND ND 1.90 J ND 8.83 J NDug/L 11/12/13 --10 ND ND ND ND 3.28 J 13.7 NDug/L 05/13/14 --10 ND ND ND 3.36 J 1.77 J 13.5 NDug/L 11/17/14 1.60 10 ND ND ND ND ND 29.8 NDug/L 05/12/15 1.60 10 ND ND ND 7.11 J 2.41 J 4.39 J ND ug/L 11/09/15 1.60 10 ND ND ND 3.22 J ND 12.7 ND January 2016 Page 5 of 17 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx MW-1N MW-2N MW-3N MW-4N MW-5AN MW-5BN SWS Reporting Limit Upgradient Downgradient Summary of Groundwater Monitoring Results for C&D Wells BlanksMethod Detection Limit TABLE 6 Sampson County, North Carolina Detected Constituents Sampson County Active C&D Landfill, Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date Lead ug/L 10/08/96 --5 ND ND ND --------NC 2L = 15 ug/L ug/L 02/18/97 --5 ND ND ND --------EPA MCL = 15 ug/L#ug/L 08/29/97 --10 ND ND ND --------ug/L 02/23/98 --5 ND ND ND --------ug/L 08/24/98 --5 ND ND ND --------ug/L 02/22/99 --5 ND ND ND --------ug/L 08/23/99 --5 ND ND ND --------ug/L 02/21/00 --5 ND ND ND --------ug/L 10/10/00 --10 ND ND 11 14 ND ND --ug/L 07/12/01 --10 ND 10 11 44 ND ND --ug/L 10/24/01 --10 ND ND ND ND ND 12 --ug/L 05/28/02 --10 ND ND ND ND ND ND --ug/L 11/05/02 --10 ND ND ND ND ND ND --ug/L 05/29/03 --10 ND ND ND 28 ND ND -- ug/L 11/05/03 --10 --------------ug/L 05/25/04 --10 ND ND ND ND ND ND --ug/L 11/23/04 --10 ND ND ND ND ND ND --ug/L 05/16/05 --10 ND ND ND ND ND ND --ug/L 11/25/05 --10 ND ND ND ND ND ND --ug/L 05/24/06 --10 ND ND ND ND ND ND NDug/L 11/20/06 --10 ND ND ND 17 ND ND NDug/L 05/22/07 --10 3.1 J ND 2.8 J ND ND ND ND ug/L 11/14/07 --10 ND ND ND ND ND ND NDug/L 05/29/08 --10 ND ND ND ND ND ND NDug/L 11/17/08 --10 ND ND ND 2.5 J ND ND NDug/L 05/27/09 --10 ND ND ND 1.9 J ND ND NDug/L 11/11/09 --10 2.00 J 2.38 J ND 2.79 J 3.46 J ND NDug/L 05/26/10 --10 ND 2.85 J ND 5.26 J ND ND NDug/L 11/15/10 --10 ND 2.64 J ND 4.19 J 3.63 J ND NDug/L 05/09/11 --10 ND 3.24 J ND ND 2.92 J ND NDug/L 11/14/11 --10 ND ND ND ND 3.89 J ND NDug/L 05/08/12 --10 ND ND ND ND 4.65 J ND NDug/L 11/05/12 --10 2.69 J ND 2.41 J ND 3.20 J ND NDug/L 05/14/13 --10 ND ND ND 2.69 J ND ND NDug/L 11/12/13 --10 ND ND ND ND ND ND NDug/L 05/13/14 --10 ND ND ND 3.10 J ND ND NDug/L 11/17/14 2.10 10 ND ND ND ND 2.82 J 3.62 J NDug/L 05/12/15 2.10 10 ND ND ND 6.18 J ND ND NDug/L 11/09/15 2.10 10 ND ND ND 4.44 J 3.18 J ND ND Mercury ug/L 10/10/00 --1 ND ND ND ND ND ND --NC 2L = 1 ug/L ug/L 07/12/01 ------------------EPA MCL = 2 ug/L ug/L 10/24/01 ------------------ug/L 05/28/02 --1 ND ND ND ND ND ND --ug/L 11/05/02 ----ND ND ND ND ND ND --ug/L 05/29/03 --1 ND ND ND ND ND ND --ug/L 11/05/03 ------------------ug/L 05/25/04 --0.5 ND ND ND ND ND ND -- ug/L 11/23/04 --1 ND ND ND ND ND ND --ug/L 05/16/05 --0.5 ND ND ND ND ND ND --ug/L 11/25/05 --1 ND ND ND ND ND ND --ug/L 05/24/06 --1 ND ND ND ND ND ND NDug/L 11/20/06 ----ND ND ND ND ND ND NDug/L 05/22/07 --0.2 ND ND ND ND ----NDug/L 11/14/07 --0.2 ND ND ND ND ND ND 0.16 Jug/L 05/29/08 --0.2 ND ND ND ND ND ND NDug/L 11/17/08 --0.2 ND ND ND ND ND ND NDug/L 05/27/09 --0.2 ND ND ND ND ND ND NDug/L 11/11/09 --0.2 ND ND ND ND ND ND NDug/L 05/26/10 --0.2 ND ND ND ND ND ND NDug/L 11/15/10 --0.2 ND ND ND ND ND ND NDug/L 05/09/11 --0.2 ND ND ND ND ND ND NDug/L 11/14/11 --0.2 0.264 ND ND ND ND ND NDug/L 05/08/12 --0.2 ND ND ND ND ND ND NDug/L 11/05/12 --0.2 ND ND ND ND ND ND ND ug/L 05/14/13 --0.2 ND ND ND ND ND ND NDug/L 11/12/13 --0.2 ND ND ND ND ND ND NDug/L 05/13/14 --0.2 ND ND ND ND ND ND NDug/L 11/17/14 0.170 0.2 ND ND ND ND ND ND NDug/L 05/12/15 0.170 0.2 ND ND ND ND ND ND NDug/L 11/09/15 0.170 0.2 ND ND ND ND ND ND ND January 2016 Page 6 of 17 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx MW-1N MW-2N MW-3N MW-4N MW-5AN MW-5BN SWS Reporting Limit Upgradient Downgradient Summary of Groundwater Monitoring Results for C&D Wells BlanksMethod Detection Limit TABLE 6 Sampson County, North Carolina Detected Constituents Sampson County Active C&D Landfill, Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date Nickel ug/L 10/08/96 --50 ND ND ND --------NC 2L = 100 ug/L ug/L 02/18/97 --50 ND ND ND --------No EPA MCL ug/L 08/29/97 --50 ND ND ND --------ug/L 02/23/98 --5 ND ND ND --------ug/L 08/24/98 --5 ND ND ND --------ug/L 02/22/99 --5 ND ND ND --------ug/L 08/23/99 --5 ND ND ND --------ug/L 02/21/00 --5 ND ND ND --------ug/L 07/12/01 --50 ND ND ND ND ND ND --ug/L 10/24/01 --50 ND ND ND ND ND ND --ug/L 05/28/02 --50 --------------ug/L 11/05/02 --50 --------------ug/L 05/29/03 --50 --------------ug/L 11/05/03 --50 -------------- ug/L 05/25/04 --50 --------------ug/L 11/23/04 --50 --------------ug/L 05/16/05 --50 --------------ug/L 11/25/05 --50 --------------ug/L 05/24/06 --50 ------------NDug/L 11/20/06 --50 ------------NDug/L 05/22/07 --50 2.7 J ND ND 37.5 J ND ND NDug/L 11/14/07 --50 ND ND ND 10.4 J 2.1 J ND NDug/L 05/29/08 --50 2.8 J ND ND 4.8 J 2.6 J ND NDug/L 11/17/08 --50 2.8 B 1.9 B ND 6.3 B 2.5 B ND 3.2 Jug/L 05/27/09 --50 1.6 B 0.8 B 0.9 B 5.6 J 2.6 B 1.2 B 0.7 Jug/L 11/11/09 --50 ND 16.7 J ND 25.5 J 4.41 J ND NDug/L 05/26/10 --50 ND 2.40 J ND 4.82 J 2.69 J ND NDug/L 11/15/10 --50 ND 1.96 J ND 6.51 J ND ND NDug/L 05/09/11 --50 ND ND ND 4.28 J 2.97 J ND NDug/L 11/14/11 --50 ND ND ND 2.85 J 7.01 J ND NDug/L 05/08/12 --50 2.46 J ND ND 8.28 J 7.92 J ND NDug/L 11/05/12 --50 13.0 J ND ND 12.3 J 6.85 J ND NDug/L 05/14/13 --50 3.45 J 1.80 J 2.81 J 15.4 J 5.87 J ND NDug/L 11/12/13 --50 ND ND 2.23 J 11.1 J 5.69 J ND NDug/L 05/13/14 --50 ND 2.81 J ND 36.5 J 5.43 J ND NDug/L 11/17/14 1.80 50 ND ND ND 8.35 J 6.28 J ND NDug/L 05/12/15 1.80 50 2.00 B ND 1.89 B 14.1 J 7.78 B ND 1.89 Jug/L 11/09/15 1.80 50 ND ND ND 10.1 J 7.50 J ND NDSeleniumug/L 10/08/96 --5 ND ND ND -------- NC 2L = 20 ug/L ug/L 10/24/96 --20 --------------EPA MCL = 50 ug/L ug/L 02/18/97 --5 ND ND ND --------ug/L 02/19/97 --5 --------------ug/L 04/24/97 --20 --------------ug/L 08/28/97 --20 --------------ug/L 08/29/97 --20 ND ND ND --------ug/L 10/09/97 --20 --------------ug/L 10/30/97 ------------------ug/L 02/23/98 --5 ND ND ND --------ug/L 02/24/98 --5 --------------ug/L 04/20/98 --20 --------------ug/L 08/24/98 --5 ND ND ND --------ug/L 10/27/98 --20 --------------ug/L 02/22/99 --5 ND ND ND --------ug/L 04/20/99 --20 --------------ug/L 08/23/99 --5 ND ND ND --------ug/L 08/24/99 --5 --------------ug/L 01/11/00 --5 --------------ug/L 02/21/00 --5 ND ND ND --------ug/L 02/22/00 --5 --------------ug/L 10/10/00 --20 ND ND ND ND ND ND --ug/L 07/12/01 --20 ND ND ND ND ND ND --ug/L 10/24/01 --20 ND ND ND ND ND ND --ug/L 05/28/02 --20 ND ND ND ND ND ND --ug/L 11/05/02 --20 ND ND ND ND ND ND -- ug/L 05/29/03 --20 ND ND ND ND ND ND --ug/L 11/05/03 --20 --------------ug/L 05/25/04 --20 ND ND ND ND ND ND --ug/L 11/23/04 --20 ND ND ND ND ND ND --ug/L 05/16/05 --20 ND ND ND ND ND ND --ug/L 11/25/05 --20 ND ND ND ND ND ND --ug/L 05/24/06 --20 ND ND ND ND ND ND NDug/L 11/20/06 --20 ND ND ND ND ND ND NDug/L 05/22/07 --10 ND ND ND ND ND ND NDug/L 11/14/07 --10 ND ND ND 2.0 B ND ND 3.1 Jug/L 05/29/08 --10 ND ND ND ND ND ND 2.1 Jug/L 11/17/08 --10 ND ND ND ND ND ND NDug/L 05/27/09 --10 ND ND ND ND ND ND NDug/L 11/11/09 --10 ND ND ND ND ND ND 3.41 Jug/L 05/26/10 --10 ND ND ND ND ND ND 3.71 Jug/L 11/15/10 --10 ND ND ND ND ND ND NDug/L 05/09/11 --10 ND ND ND ND ND ND NDug/L 11/14/11 --10 ND ND ND ND ND ND NDug/L 05/08/12 --10 ND ND ND ND ND 6.46 J 4.01 Jug/L 11/05/12 --10 ND ND ND ND ND ND NDug/L 05/14/13 --10 ND ND ND ND ND ND NDug/L 11/12/13 --10 ND ND ND ND ND ND NDug/L 05/13/14 --10 ND ND ND ND ND ND NDug/L 11/17/14 5.00 10 ND ND ND ND ND ND NDug/L 05/12/15 5.00 10 ND ND ND ND ND ND ND ug/L 11/09/15 5.00 10 ND ND ND ND ND ND ND January 2016 Page 7 of 17 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx MW-1N MW-2N MW-3N MW-4N MW-5AN MW-5BN SWS Reporting Limit Upgradient Downgradient Summary of Groundwater Monitoring Results for C&D Wells BlanksMethod Detection Limit TABLE 6 Sampson County, North Carolina Detected Constituents Sampson County Active C&D Landfill, Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date Silver ug/L 10/08/96 --5 ND ND ND --------NC 2L = 20 ug/L ug/L 10/24/96 --10 --------------EPA MCL = 100 ug/L ug/L 02/18/97 --5 ND ND ND --------ug/L 02/19/97 --5 --------------ug/L 04/24/97 --10 --------------ug/L 08/28/97 --10 --------------ug/L 08/29/97 --10 ND ND ND --------ug/L 10/09/97 --10 --------------ug/L 10/30/97 ------------------ug/L 02/23/98 --5 ND ND ND --------ug/L 02/24/98 --5 --------------ug/L 04/20/98 --10 --------------ug/L 08/24/98 --5 ND ND ND --------ug/L 10/27/98 --10 -------------- ug/L 02/22/99 --5 ND ND ND --------ug/L 04/20/99 --10 --------------ug/L 08/23/99 --5 ND ND ND --------ug/L 08/24/99 --5 --------------ug/L 01/11/00 --5 --------------ug/L 02/21/00 --5 ND ND ND --------ug/L 02/22/00 ------------------ug/L 10/10/00 --10 ND ND ND ND ND ND --ug/L 07/12/01 --10 ND ND ND ND ND ND --ug/L 10/24/01 --10 ND ND ND ND ND ND --ug/L 05/28/02 --10 ND ND ND ND ND ND --ug/L 11/05/02 --10 ND ND ND ND ND ND --ug/L 05/29/03 --10 ND ND ND ND ND ND --ug/L 11/05/03 --10 --------------ug/L 05/25/04 --10 ND ND ND ND ND ND --ug/L 11/23/04 --10 ND ND ND ND ND ND --ug/L 05/16/05 --10 ND ND ND ND ND ND --ug/L 11/25/05 --10 ND ND ND ND ND ND --ug/L 05/24/06 --10 ND ND ND ND ND ND NDug/L 11/20/06 --10 ND ND ND ND ND ND NDug/L 05/22/07 --10 ND ND ND ND ND ND NDug/L 11/14/07 --10 ND ND ND ND ND ND NDug/L 05/29/08 --10 ND ND ND 3.0 B ND ND 2.9 Jug/L 11/17/08 --10 ND ND ND ND ND ND NDug/L 05/27/09 --10 ND ND ND ND ND ND NDug/L 11/11/09 --10 ND ND ND ND ND ND NDug/L 05/26/10 --10 ND ND ND ND ND ND NDug/L 11/15/10 --10 ND ND 1.93 J ND ND ND NDug/L 05/09/11 --10 ND ND ND ND ND ND NDug/L 11/14/11 --10 ND ND ND ND ND ND NDug/L 05/08/12 --10 ND ND ND ND ND ND NDug/L 11/05/12 --10 ND ND ND ND ND ND NDug/L 05/14/13 --10 ND ND ND ND ND ND NDug/L 11/12/13 --10 ND ND ND ND ND ND NDug/L 05/13/14 --10 ND ND ND 31.5 (ND)ND ND NDug/L 11/17/14 1.90 10 ND ND ND ND ND ND NDug/L 05/12/15 1.90 10 ND ND 1.97 J ND ND ND NDug/L 11/09/15 1.90 10 ND 1.99 J 5.26 J ND ND ND ND January 2016 Page 8 of 17 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx MW-1N MW-2N MW-3N MW-4N MW-5AN MW-5BN SWS Reporting Limit Upgradient Downgradient Summary of Groundwater Monitoring Results for C&D Wells BlanksMethod Detection Limit TABLE 6 Sampson County, North Carolina Detected Constituents Sampson County Active C&D Landfill, Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date Thallium ug/L 10/08/96 --1 ND ND ND --------GWPS= 0.28 ug/L ug/L 10/24/96 ------------------EPA MCL = 2 ug/L ug/L 02/18/97 --1 ND ND ND --------ug/L 02/19/97 --1 --------------ug/L 04/24/97 ------------------ug/L 08/28/97 --10 --------------ug/L 08/29/97 --10 ND ND ND --------ug/L 10/09/97 ------------------ug/L 10/30/97 ------------------ug/L 02/23/98 --10 ND ND ND --------ug/L 02/24/98 --10 --------------ug/L 04/20/98 ------------------ug/L 08/24/98 --10 ND ND ND --------ug/L 10/27/98 ------------------ ug/L 02/22/99 --10 ND ND ND --------ug/L 04/20/99 ------------------ug/L 08/23/99 --10 ND ND ND --------ug/L 08/24/99 --10 --------------ug/L 01/11/00 --10 --------------ug/L 02/21/00 --10 ND ND ND --------ug/L 02/22/00 --10 --------------ug/L 10/10/00 --10 --------------ug/L 07/12/01 --10 ND ND ND ND ND ND --ug/L 10/24/01 --10 ND ND ND ND ND ND --ug/L 05/28/02 --10 --------------ug/L 11/05/02 ------------------ug/L 05/29/03 --10 --------------ug/L 11/05/03 --10 --------------ug/L 05/25/04 --10 --------------ug/L 11/23/04 --10 --------------ug/L 05/16/05 --10 --------------ug/L 11/25/05 --10 --------------ug/L 05/24/06 --10 ------------NDug/L 11/20/06 --10 ------------NDug/L 05/22/07 --5.5 ND ND ND ND ND ND NDug/L 11/14/07 --5.5 0.077 J ND ND ND ND ND NDug/L 05/29/08 --5.5 ND ND ND ND ND ND NDug/L 11/17/08 --5.5 ND ND ND 0.041 J ND ND NDug/L 05/27/09 --5.5 ND ND ND ND ND ND ND ug/L 11/11/09 --5.5 ND ND ND ND ND 4.78 J NDug/L 05/26/10 --5.5 ND ND ND ND ND ND NDug/L 11/15/10 --5.5 ND ND ND ND ND ND NDug/L 05/09/11 --5.5 ND ND ND ND ND ND NDug/L 11/14/11 --5.5 ND ND ND ND ND ND NDug/L 05/08/12 --5.5 ND ND 0.253 J ND ND ND NDug/L 11/05/12 --5.5 ND ND ND ND ND ND NDug/L 05/14/13 --5.5 ND ND ND ND ND ND NDug/L 11/12/13 --5.5 ND ND ND ND ND ND NDug/L 05/13/14 --5.5 ND ND ND ND ND ND NDug/L 11/17/14 0.110 5.5 ND 0.116 J ND ND ND ND NDug/L 05/12/15 0.110 5.5 ND ND ND ND ND ND NDug/L 11/09/15 0.110 5.5 ND ND ND ND ND ND NDVanadium ug/L 10/08/96 --5 ND ND ND --------SWS GPS = 0.3 ug/L ug/L 02/18/97 --5 ND ND ND --------No EPA MCL ug/L 08/29/97 --40 ND ND ND --------ug/L 02/23/98 --5 ND ND ND --------ug/L 08/24/98 --5 ND ND 6.06 --------ug/L 02/22/99 --5 ND ND ND --------ug/L 08/23/99 --5 ND ND ND --------ug/L 02/21/00 --5 ND ND ND --------ug/L 07/12/01 --40 ND ND ND ND ND ND --ug/L 10/24/01 --40 ND ND ND ND ND ND --ug/L 05/28/02 --40 --------------ug/L 11/05/02 --40 -------------- ug/L 05/29/03 --40 --------------ug/L 11/05/03 --40 --------------ug/L 05/25/04 --40 --------------ug/L 11/23/04 --40 --------------ug/L 05/16/05 --40 --------------ug/L 11/25/05 --40 --------------ug/L 05/24/06 --40 ------------NDug/L 11/20/06 --40 ------------ND ug/L 05/22/07 --25 ND ND ND 2.6 J ND ND NDug/L 11/14/07 --25 ND ND ND 1.6 J ND ND NDug/L 05/29/08 --25 ND ND ND 5.4 B 1.7 B 1.0 B 1.2 Jug/L 11/17/08 --25 ND ND ND 14.4 J 1.6 J ND NDug/L 05/27/09 --25 ND 1.0 J 0.9 J 5.8 J 0.8 J ND NDug/L 11/11/09 --25 ND 4.26 J ND 6.65 J 3.41 J ND NDug/L 05/26/10 --25 ND ND 3.17 J 18.7 J 3.27 J ND NDug/L 11/15/10 --25 ND 3.56 J ND 6.05 J 1.78 J ND NDug/L 05/09/11 --25 ND ND ND ND ND ND NDug/L 11/14/11 --25 ND ND ND ND 5.92 J ND NDug/L 05/08/12 --25 ND ND ND 3.84 J 4.24 J ND NDug/L 11/05/12 --25 6.85 J ND ND ND 3.33 J ND NDug/L 05/14/13 --25 ND ND ND 7.66 J ND ND NDug/L 11/12/13 --25 ND ND ND ND ND ND NDug/L 05/13/14 --25 ND 3.02 J ND 8.66 J 3.76 J ND NDug/L 11/17/14 1.40 25 ND ND ND ND 3.82 J ND NDug/L 05/12/15 1.40 25 ND ND ND 35.3 14.5 J ND ND (Dissolved)ug/L 05/12/15 1.40 25 ------2.79 J ------ug/L 11/09/15 1.40 25 ND ND ND 13.4 J 9.06 J ND ND January 2016 Page 9 of 17 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx MW-1N MW-2N MW-3N MW-4N MW-5AN MW-5BN SWS Reporting Limit Upgradient Downgradient Summary of Groundwater Monitoring Results for C&D Wells BlanksMethod Detection Limit TABLE 6 Sampson County, North Carolina Detected Constituents Sampson County Active C&D Landfill, Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date Zinc ug/L 10/08/96 ----24 18 30.5 --------NC 2L = 1000 ug/L ug/L 02/18/97 --10 ND ND ND --------EPA MCL = 5000 ug/L*ug/L 08/29/97 --50 ND ND ND --------ug/L 02/23/98 --5 ND ND 6.27 --------ug/L 08/24/98 --5 ND ND ND --------ug/L 02/22/99 --5 ND ND ND --------ug/L 08/23/99 --5 ND ND ND --------ug/L 02/21/00 --5 ND 7.39 ND --------ug/L 07/12/01 --50 ND ND ND 413 ND ND --ug/L 10/24/01 --20 ND ND ND ND ND 21 --ug/L 05/28/02 --50 --------------ug/L 11/05/02 --50 --------------ug/L 05/29/03 --50 --------------ug/L 11/05/03 --50 -------------- ug/L 05/25/04 --50 --------------ug/L 11/23/04 --50 --------------ug/L 05/16/05 --50 --------------ug/L 11/25/05 --50 --------------ug/L 05/24/06 --50 ------------NDug/L 11/20/06 --50 ------------NDug/L 05/22/07 --10 2.1 J 2.7 J 1.1 J 5.6 J 1.1 J 2.7 J NDug/L 11/14/07 --10 2.5 J 3.1 J ND 3.1 J 1.4 J 3.7 J NDug/L 05/29/08 --10 2.0 B 4.8 B ND 4.3 B 1.6 B 3.9 B 1.8 Jug/L 11/17/08 --10 ND ND ND 13.5 B ND 3.9 B 4.6 Jug/L 05/27/09 --10 ND 6.0 J ND 6.4 J 7.4 J 9.4 J NDug/L 11/11/09 --10 ND 7.45 J ND 4.86 J ND ND NDug/L 05/26/10 --10 ND 6.82 J ND 6.41 J ND 6.28 J NDug/L 11/15/10 --10 ND ND ND 4.64 J ND ND NDug/L 05/09/11 --10 ND 6.43 J ND ND ND ND NDug/L 11/14/11 --10 ND ND ND ND 3.85 J ND NDug/L 05/08/12 --10 ND ND ND ND ND ND NDug/L 11/05/12 --10 ND ND 4.21 J ND ND ND NDug/L 05/14/13 --10 ND 5.08 J ND ND ND ND NDug/L 11/12/13 --10 ND 4.47 J 5.26 J 4.80 J 4.14 J 7.92 J NDug/L 05/13/14 --10 ND 4.60 J ND ND ND ND NDug/L 11/17/14 3.80 10 ND ND ND 12.4 ND 4.26 J NDug/L 05/12/15 3.80 10 39.3 11.8 ND 16.5 7.85 J ND NDug/L 11/09/15 3.80 10 ND ND ND 5.72 J 4.38 J ND NDIronug/L 10/08/96 --50 ND 1600 2600 -------- NC 2L = 300 ug/L ug/L 02/18/97 --50 ND 4600 1100 --------EPA MCL = 300 ug/L*ug/L 08/29/97 --50 ND 54500 2300 --------ug/L 02/23/98 --50 ND 53100 5380 --------ug/L 08/24/98 --50 ND 79200 56000 --------ug/L 02/22/99 --50 ND 63300 83600 --------ug/L 08/23/99 --50 311 76400 68600 --------ug/L 02/21/00 --50 ND 73300 61400 --------ug/L 10/10/00 ------------------ ug/L 07/12/01 ------------------ug/L 10/24/01 ------------------ug/L 05/28/02 ------------------ug/L 11/05/02 ------------------ug/L 05/29/03 ------------------ug/L 11/05/03 ------------------ug/L 05/25/04 ------------------ug/L 11/23/04 ------------------ug/L 05/16/05 ------------------ug/L 11/25/05 ------------------ug/L 05/24/06 ------------------ug/L 11/20/06 ------------------ug/L 05/22/07 --300 47 J 45900 39000 2020 ----NDug/L 11/14/07 --300 154 J 23700 1430 961 77 B 637 20 Jug/L 05/29/08 --300 33 J 31200 32600 1590 333 702 NDug/L 11/17/08 --300 31 J 22900 25000 6920 1130 600 NDug/L 05/27/09 --300 ND 35300 28200 1950 251 J 660 ND ug/L 11/11/09 --300 ND 17700 7120 2780 1280 533 NDug/L 05/26/10 --300 ND 39600 34500 8530 1730 494 NDug/L 11/15/10 --300 ND 35600 11300 2070 417 531 26.2 Jug/L 05/09/11 --300 ND 34400 22000 133 J 323 640 NDug/L 11/14/11 --300 46.8 J 15600 4840 124 J 1960 575 NDmg/L 05/08/12 --300 132 J 18200 4330 1540 1480 604 NDug/L 11/05/12 --300 3540 21900 19100 472 1390 455 NDug/L 05/14/13 --300 275 J 13200 87.2 J 2880 245 J 508 ND ug/L 11/12/13 --300 628 18200 7460 295 J 526 556 NDug/L 05/13/14 --300 ND 15900 12400 3110 1350 577 NDug/L 11/17/14 22.0 300 46.8 J 9570 1980 244 J 1080 2160 NDug/L 05/12/15 22.0 300 32.3 B 13100 5730 14600 6850 604 58.3 Jug/L 11/09/15 22.0 300 ND 5920 4170 4930 3920 723 ND January 2016 Page 10 of 17 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx MW-1N MW-2N MW-3N MW-4N MW-5AN MW-5BN SWS Reporting Limit Upgradient Downgradient Summary of Groundwater Monitoring Results for C&D Wells BlanksMethod Detection Limit TABLE 6 Sampson County, North Carolina Detected Constituents Sampson County Active C&D Landfill, Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date Manganese ug/L 10/08/96 --10 ND ND 15 --------NC 2L = 50 ug/L ug/L 02/18/97 --10 ND 32 11 --------EPA MCL = 50 ug/L*ug/L 08/29/97 --30 ND 118 ND --------ug/L 02/23/98 --10 ND 194 81.4 --------ug/L 08/24/98 --23.3 ND 274 508 --------ug/L 02/22/99 --10 ND 247 585 --------ug/L 08/23/99 --10 13.3 327 501 --------ug/L 02/21/00 --10 ND 381 528 --------ug/L 02/22/00 ------------ ------ug/L 10/10/00 ------------------ug/L 07/12/01 ------------------ug/L 10/24/01 ------------------ug/L 05/28/02 ------------------ug/L 11/05/02 ------------------ ug/L 05/29/03 ------------------ug/L 11/05/03 ------------------ug/L 05/25/04 ------------------ug/L 11/23/04 ------------------ug/L 05/16/05 ------------------ug/L 11/25/05 ------------------ug/L 05/24/06 ------------------ug/L 11/20/06 ------------------ ug/L 05/22/07 --50 15.0 J 274 371 21.9 J ----NDug/L 11/14/07 --50 14.9 J 212 29.4 J 23.1 J 69.2 23.2 J NDug/L 05/29/08 --50 20.6 J 205 308 17.5 J 50.3 32.7 J NDug/L 11/17/08 --50 15.4 J 228 410 17.3 J 12.3 J 24.4 J NDug/L 05/27/09 --50 10.4 J 204 391 15.7 J 33.7 J 32.6 J NDug/L 11/11/09 --50 10.5 J 182 103 20.6 J 66.6 28.5 J NDug/L 05/26/10 --50 12.5 J 218 315 14.2 J 12.9 J 23.2 J NDug/L 11/15/10 --50 11.1 J 175 289 21.1 J 30.2 J 21.7 J NDug/L 05/09/11 --50 17.1 J 210 323 14.8 J 47.7 J 26.4 J NDug/L 11/14/11 --50 20.7 J 158 99.1 9.81 J 62.1 23.5 J NDmg/L 05/08/12 --50 16.8 J 112 132 11.6 J 61.8 24.5 J NDug/L 11/05/12 --50 21.1 J 137 180 13.1 J 69.3 21.2 J NDug/L 05/14/13 --50 19.0 J 113 26.0 J 9.35 J 33.6 J 20.7 J NDug/L 11/12/13 --50 20.0 J 112 235 10.9 J 49.0 J 18.5 J NDug/L 05/13/14 --50 25.2 J 162 231 13.5 J 24.7 J 18.9 J NDug/L 11/17/14 1.10 50 27.5 J 98.3 66.5 26.2 J 56.5 22.3 J NDug/L 05/12/15 1.10 50 21.5 J 88.8 199 21.4 J 13.4 J 21.8 J ND ug/L 11/09/15 1.10 50 26.1 J 182 131 10.7 J 11.5 J 27.0 J NDAcetoneug/L 10/08/96 --100 ND ND ND --------NC 2L = 6000 ug/L ug/L 02/18/97 --100 ND ND ND --------No EPA MCL ug/L 08/29/97 --10 ND ND ND --------ug/L 10/30/97 ------25.2 ----------ug/L 02/23/98 --10 ND ND 11.4 --------ug/L 08/24/98 ----1080 3860 521 --------ug/L 02/22/99 --10 ND ND ND --------ug/L 08/23/99 --5 ND ND 5.56 --------ug/L 02/21/00 --10 ND 13.5 17.7 --------ug/L 10/10/00 --100 ND ND ND ND ND ND --ug/L 07/12/01 --100 ND ND ND ND ND ND --ug/L 10/24/01 --100 ND ND ND ND ND ND --ug/L 05/28/02 --100 ND ND ND ND ND ND --ug/L 11/05/02 --100 ND ND ND ND ND ND --ug/L 05/29/03 --100 ND ND ND ND ND ND --ug/L 11/05/03 --100 ND ND ND ND ND ND --ug/L 05/25/04 --100 ND ND ND ND ND ND --ug/L 11/23/04 --100 ND ND ND ND ND ND --ug/L 05/16/05 --100 ND ND ND ND ND ND --ug/L 11/25/05 --100 ND ND ND ND ND ND --ug/L 05/24/06 --100 ND ND ND ND ND ND NDug/L 11/20/06 --100 ND ND ND ND ND ND NDug/L 05/22/07 --100 ND 4.8 B 3.6 B 6.1 B ND ND 6.6 Jug/L 11/14/07 --100 ND ND ND ND ND ND ND ug/L 05/29/08 --100 2.2 B ND ND ND ND ND 2.9 Jug/L 11/17/08 --100 ND ND ND ND ND ND 9.8 Jug/L 05/27/09 --100 ND ND ND ND ND ND NDug/L 11/11/09 --100 ND ND ND ND ND ND NDug/L 05/26/10 --100 ND ND ND ND ND ND NDug/L 11/15/10 --100 ND ND ND ND ND ND 9.2 Jug/L 05/09/11 --100 ND ND ND ND ND ND NDug/L 11/14/11 --100 ND ND ND ND ND ND NDug/L 05/08/12 --100 ND ND ND ND ND ND NDug/L 11/05/12 --100 ND ND ND ND ND ND NDug/L 05/14/13 --100 ND ND ND ND ND ND NDug/L 11/12/13 --100 ND ND ND ND ND ND NDug/L 05/13/14 --100 ND ND ND ND ND ND NDug/L 11/17/14 1.20 100 ND ND ND ND ND ND NDug/L 05/12/15 1.20 100 ND ND ND ND ND ND NDug/L 11/09/15 1.20 100 ND ND ND ND ND ND ND January 2016 Page 11 of 17 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx MW-1N MW-2N MW-3N MW-4N MW-5AN MW-5BN SWS Reporting Limit Upgradient Downgradient Summary of Groundwater Monitoring Results for C&D Wells BlanksMethod Detection Limit TABLE 6 Sampson County, North Carolina Detected Constituents Sampson County Active C&D Landfill, Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date Benzene ug/L 10/08/96 ----ND ND ND --------NC 2L = 1 ug/L ug/L 10/24/96 ------------------EPA MCL = 5 ug/L ug/L 02/18/97 ----ND ND ND --------ug/L 02/19/97 ------------------ug/L 04/24/97 ------------------ug/L 08/28/97 ------------------ug/L 08/29/97 ----ND ND ND --------ug/L 10/09/97 ------------------ug/L 10/30/97 ------ND ----------ug/L 02/23/98 ----ND ND ND --------ug/L 02/24/98 ------------------ug/L 04/20/98 ------------------ug/L 08/24/98 ----ND ND ND --------ug/L 10/27/98 ------------------ ug/L 02/22/99 ----ND ND ND --------ug/L 04/20/99 ------------------ug/L 08/23/99 ----ND ND ND --------ug/L 08/24/99 ------------------ug/L 01/11/00 ------------------ug/L 02/21/00 ----ND ND ND --------ug/L 02/22/00 ------------------ug/L 10/10/00 ----ND ND ND ND ND ND --ug/L 07/12/01 ----ND ND ND ND ND ND --ug/L 10/24/01 ----ND ND ND ND ND ND --ug/L 05/28/02 ----ND ND ND ND ND ND --ug/L 11/05/02 ----ND ND ND ND ND ND --ug/L 05/29/03 ----ND ND ND ND ND ND --ug/L 11/05/03 ----ND ND ND ND ND ND --ug/L 05/25/04 ----ND ND ND ND ND ND --ug/L 11/23/04 ----ND ND ND ND ND ND --ug/L 05/16/05 ----ND ND ND ND ND ND --ug/L 11/25/05 ----ND ND ND ND ND ND --ug/L 05/24/06 --5 ND ND ND ND ND ND NDug/L 11/20/06 --5 ND ND ND ND ND ND NDug/L 05/22/07 --1 ND ND ND ND ND ND NDug/L 11/14/07 --1 ND ND ND ND ND ND NDug/L 05/29/08 --1 ND ND ND ND ND ND NDug/L 11/17/08 --1 ND ND ND ND ND ND NDug/L 05/27/09 --1 ND ND ND ND ND ND ND ug/L 11/11/09 --1 ND 0.77 J 0.72 J ND ND ND NDug/L 05/26/10 --1 ND ND ND ND ND ND NDug/L 11/15/10 --1 ND ND ND ND ND ND NDug/L 05/09/11 --1 ND ND ND ND ND ND NDug/L 11/14/11 --1 ND ND ND ND ND ND NDug/L 05/08/12 --1 ND ND ND ND ND ND NDug/L 11/05/12 --1 ND ND ND ND ND ND NDug/L 05/14/13 --1 ND ND ND ND ND ND NDug/L 11/12/13 --1 ND ND ND ND ND ND NDug/L 05/13/14 --1 ND ND ND ND ND ND NDug/L 11/17/14 0.15 1 ND ND ND ND ND ND NDug/L 05/12/15 0.15 1 ND ND ND ND ND ND NDug/L 11/09/15 0.15 1 ND ND ND ND ND ND NDChloroethaneug/L 10/08/96 --10 ND ND ND --------NC 2L = 3000 ug/L ug/L 02/18/97 --10 ND ND ND --------No EPA MCL ug/L 08/29/97 --2 ND ND ND --------ug/L 10/30/97 --2 --ND ----------ug/L 02/23/98 --2 ND ND ND --------ug/L 08/24/98 --1 ND 1.47 1.36 --------ug/L 02/22/99 --2 ND ND 2.17 --------ug/L 08/23/99 --1 ND 1.93 1.2 --------ug/L 02/21/00 --2 ND ND ND --------ug/L 10/10/00 --10 ND ND ND ND ND ND --ug/L 07/12/01 --10 ND ND ND ND ND ND --ug/L 10/24/01 --10 ND ND ND ND ND ND -- ug/L 05/28/02 --10 ND ND ND ND ND ND --ug/L 11/05/02 --10 ND ND ND ND ND ND --ug/L 05/29/03 --10 ND ND ND ND ND ND --ug/L 11/05/03 --10 ND ND ND ND ND ND --ug/L 05/25/04 --10 ND ND ND ND ND ND --ug/L 11/23/04 --10 ND ND ND ND ND ND --ug/L 05/16/05 --10 ND ND ND ND ND ND --ug/L 11/25/05 --10 ND ND ND ND ND ND --ug/L 05/24/06 --10 ND ND ND ND ND ND NDug/L 11/20/06 --10 ND ND ND ND ND ND NDug/L 05/22/07 --10 ND ND ND ND ND ND NDug/L 11/14/07 --10 ND ND ND ND ND ND NDug/L 05/29/08 --10 ND ND ND ND ND ND NDug/L 11/17/08 --10 ND ND ND ND ND ND NDug/L 05/27/09 --10 ND ND ND ND ND ND NDug/L 11/11/09 --10 ND ND ND ND ND ND NDug/L 05/26/10 --10 ND ND ND ND ND ND NDug/L 11/15/10 --10 ND ND ND ND ND ND NDug/L 05/09/11 --10 ND ND ND ND ND ND NDug/L 11/14/11 --10 ND ND ND ND ND ND NDug/L 05/08/12 --10 ND ND ND ND ND ND NDug/L 11/05/12 --10 ND ND ND ND ND ND NDug/L 05/14/13 --10 ND ND ND ND ND ND NDug/L 11/12/13 --10 ND ND ND ND ND ND NDug/L 05/13/14 --10 ND ND ND ND ND ND ND ug/L 11/17/14 0.23 10 ND ND ND ND ND ND NDug/L 05/12/15 0.23 10 ND ND ND ND ND ND NDug/L 11/09/15 0.23 10 ND ND ND ND ND ND ND January 2016 Page 12 of 17 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx MW-1N MW-2N MW-3N MW-4N MW-5AN MW-5BN SWS Reporting Limit Upgradient Downgradient Summary of Groundwater Monitoring Results for C&D Wells BlanksMethod Detection Limit TABLE 6 Sampson County, North Carolina Detected Constituents Sampson County Active C&D Landfill, Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date Chloroform ug/L 10/08/96 --5 ND ND ND --------NC 2L = 70 ug/L ug/L 02/18/97 --5 ND ND ND --------EPA MCL = 80 ug/L ug/L 08/29/97 --2 ND ND ND --------ug/L 10/30/97 --2 --ND ----------ug/L 02/23/98 --2 ND ND ND --------ug/L 08/24/98 --1 ND ND ND --------ug/L 02/22/99 --2 ND ND ND --------ug/L 08/23/99 --1 ND ND ND --------ug/L 02/21/00 --2 ND ND ND --------ug/L 10/10/00 --5 ND ND ND ND ND ND --ug/L 07/12/01 --5 ND ND ND ND ND ND --ug/L 10/24/01 --5 ND ND ND ND ND ND --ug/L 05/28/02 --5 ND ND ND ND ND ND --ug/L 11/05/02 --5 ND ND ND ND ND ND -- ug/L 05/29/03 --5 ND ND ND ND ND ND --ug/L 11/05/03 --5 ND ND ND ND ND 18.4 --ug/L 05/25/04 --5 ND ND ND ND ND ND --ug/L 11/23/04 --5 ND ND ND ND ND ND --ug/L 05/16/05 --5 ND ND ND ND ND ND --ug/L 11/25/05 --5 ND ND ND ND ND ND --ug/L 05/24/06 --5 ND ND ND ND ND ND NDug/L 11/20/06 --5 ND ND ND ND ND ND NDug/L 05/22/07 --5 ND ND ND ND ND ND NDug/L 11/14/07 --5 ND ND ND ND ND ND NDug/L 05/29/08 --5 ND ND ND ND ND ND NDug/L 11/17/08 --5 ND ND ND ND ND ND NDug/L 05/27/09 --5 ND ND ND ND ND ND NDug/L 11/11/09 --5 ND ND ND ND ND ND NDug/L 05/26/10 --5 ND ND ND ND ND ND NDug/L 11/15/10 --5 ND ND ND ND ND ND NDug/L 05/09/11 --5 ND ND ND ND ND ND NDug/L 11/14/11 --5 ND ND ND ND ND ND NDug/L 05/08/12 --5 ND ND ND ND ND ND NDug/L 11/05/12 --5 ND ND ND ND ND ND NDug/L 05/14/13 --5 ND ND ND ND ND ND NDug/L 11/12/13 --5 ND ND ND ND ND ND NDug/L 05/13/14 --5 ND ND ND ND ND ND NDug/L 11/17/14 0.18 5 ND ND ND ND ND ND NDug/L 05/12/15 0.18 5 ND ND ND ND ND ND ND ug/L 11/09/15 0.18 5 ND ND ND ND ND ND ND1,2-Dichloropropane ug/L 10/08/96 --5 ND ND ND --------NC 2L = 0.6 ug/L ug/L 02/18/97 --5 ND ND ND --------EPA MCL = 5 ug/L ug/L 08/29/97 --2 ND ND ND --------ug/L 10/30/97 --2 --ND ----------ug/L 02/23/98 --2 ND ND ND --------ug/L 08/24/98 --1 ND 24.1 ND --------ug/L 02/22/99 --2 ND ND ND -------- ug/L 08/23/99 --1 ND ND ND --------ug/L 02/21/00 --2 ND ND ND --------ug/L 10/10/00 --5 ND ND ND ND ND ND --ug/L 07/12/01 --5 ND ND ND ND ND ND --ug/L 10/24/01 --5 ND ND ND ND ND ND --ug/L 05/28/02 --5 ND ND ND ND ND ND --ug/L 11/05/02 --5 ND ND ND ND ND ND --ug/L 05/29/03 --5 ND ND ND ND ND ND --ug/L 11/05/03 --5 ND ND ND ND ND ND --ug/L 05/25/04 --5 ND ND ND ND ND ND --ug/L 11/23/04 --5 ND ND ND ND ND ND --ug/L 05/16/05 --5 ND ND ND ND ND ND --ug/L 11/25/05 --5 ND ND ND ND ND ND --ug/L 05/24/06 --5 ND ND ND ND ND ND NDug/L 11/20/06 --5 ND ND ND ND ND ND NDug/L 05/22/07 --1 ND ND ND ND ND ND NDug/L 11/14/07 --1 ND ND ND ND ND ND ND ug/L 05/29/08 --1 ND ND ND ND ND ND NDug/L 11/17/08 --1 ND ND ND ND ND ND NDug/L 05/27/09 --1 ND ND ND ND ND ND NDug/L 11/11/09 --1 ND ND ND ND ND ND NDug/L 05/26/10 --1 ND ND ND ND ND ND NDug/L 11/15/10 --1 ND ND ND ND ND ND NDug/L 05/09/11 --1 ND ND ND ND ND ND NDug/L 11/14/11 --1 ND ND ND ND ND ND ND ug/L 05/08/12 --1 ND ND ND ND ND ND NDug/L 11/05/12 --1 ND ND ND ND ND ND NDug/L 05/14/13 --1 ND ND ND ND ND ND NDug/L 11/12/13 --1 ND ND ND ND ND ND NDug/L 05/13/14 --1 ND ND ND ND ND ND NDug/L 11/17/14 0.10 1 ND ND ND ND ND ND NDug/L 05/12/15 0.10 1 ND ND ND ND ND ND NDug/L 11/09/15 0.10 1 ND ND ND ND ND ND ND January 2016 Page 13 of 17 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx MW-1N MW-2N MW-3N MW-4N MW-5AN MW-5BN SWS Reporting Limit Upgradient Downgradient Summary of Groundwater Monitoring Results for C&D Wells BlanksMethod Detection Limit TABLE 6 Sampson County, North Carolina Detected Constituents Sampson County Active C&D Landfill, Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date 2-Butanone ug/L 10/08/96 --100 ND ND ND --------NC 2L = 4000 ug/L ug/L 02/18/97 --100 ND ND ND --------No EPA MCL ug/L 08/29/97 --10 ND 12.5 ND --------ug/L 10/30/97 ------13.5 ----------ug/L 02/23/98 --10 ND ND ND --------ug/L 08/24/98 --5.9 ND ND ND --------ug/L 02/22/99 --10 ND ND ND --------ug/L 08/23/99 --10 ND ND ND --------ug/L 02/21/00 --10 ND ND ND --------ug/L 10/10/00 --100 ND ND ND ND ND ND --ug/L 07/12/01 --100 ND ND ND ND ND ND --ug/L 10/24/01 --100 ND ND ND ND ND ND --ug/L 05/28/02 --100 ND ND ND ND ND ND --ug/L 11/05/02 --100 ND ND ND ND ND ND -- ug/L 05/29/03 --100 ND ND ND ND ND ND --ug/L 11/05/03 --100 ND ND ND ND ND ND --ug/L 05/25/04 --100 ND ND ND ND ND ND --ug/L 11/23/04 --100 ND ND ND ND ND ND --ug/L 05/16/05 --100 ND ND ND ND ND ND --ug/L 11/25/05 --100 ND ND ND ND ND ND --ug/L 05/24/06 --100 ND ND ND ND ND ND NDug/L 11/20/06 --100 ND ND ND ND ND ND NDug/L 05/22/07 --100 ND ND ND ND ND ND NDug/L 11/14/07 --100 ND ND ND ND ND ND NDug/L 05/29/08 --100 ND ND ND ND ND ND NDug/L 11/17/08 --100 ND ND ND ND ND ND NDug/L 05/27/09 --100 ND ND ND ND ND ND NDug/L 11/11/09 --100 ND ND ND ND ND ND NDug/L 05/26/10 --100 ND ND ND ND ND ND NDug/L 11/15/10 --100 ND ND ND ND ND ND 6.4 Jug/L 05/09/11 --100 ND ND ND ND ND ND NDug/L 11/14/11 --100 ND ND ND ND ND ND NDug/L 05/08/12 --100 ND ND ND ND ND ND NDug/L 11/05/12 --100 ND ND ND ND ND ND NDug/L 05/14/13 --100 ND ND ND ND ND ND NDug/L 11/12/13 --100 ND ND ND ND ND ND NDug/L 05/13/14 --100 ND ND ND ND ND ND NDug/L 11/17/14 1.30 100 ND ND ND ND ND ND NDug/L 05/12/15 1.30 100 ND ND ND ND ND ND ND ug/L 11/09/15 1.30 100 ND ND ND ND ND ND NDTetrachloroetheneug/L 10/08/96 ----ND ND ND --------NC 2L = 0.7 ug/L ug/L 10/24/96 ------------------EPA MCL = 5 ug/L ug/L 02/18/97 ----ND ND ND --------ug/L 02/19/97 ------------------ug/L 04/24/97 ------------------ug/L 08/28/97 ------------------ug/L 08/29/97 ----ND ND ND --------ug/L 10/09/97 ------------------ug/L 10/30/97 ------ND ----------ug/L 02/23/98 ----ND ND ND --------ug/L 02/24/98 ------------------ug/L 04/20/98 ------------------ug/L 08/24/98 ----ND ND ND --------ug/L 10/27/98 ------------------ug/L 02/22/99 ----ND ND ND --------ug/L 04/20/99 ------------------ug/L 08/23/99 ----ND ND ND --------ug/L 08/24/99 ------------------ug/L 01/11/00 ------------------ug/L 02/21/00 ----ND ND ND --------ug/L 02/22/00 ------------------ug/L 10/10/00 ----ND ND ND ND ND ND --ug/L 07/12/01 ----ND ND ND ND ND ND --ug/L 10/24/01 ----ND ND ND ND ND ND -- ug/L 05/28/02 ----ND ND ND ND ND ND --ug/L 11/05/02 ----ND ND ND ND ND ND --ug/L 05/29/03 ----ND ND ND ND ND ND --ug/L 11/05/03 ----ND ND ND ND ND ND --ug/L 05/25/04 ----ND ND ND ND ND ND --ug/L 11/23/04 ----ND ND ND ND ND ND --ug/L 05/16/05 ----ND ND ND ND ND ND --ug/L 11/25/05 ----ND ND ND ND ND ND --ug/L 05/24/06 --5 ND ND ND ND ND ND NDug/L 11/20/06 --5 ND ND ND ND ND ND NDug/L 05/22/07 --1 ND ND ND ND ND ND NDug/L 11/14/07 --1 ND ND ND ND ND ND NDug/L 05/29/08 --1 0.53 J ND ND ND ND ND NDug/L 11/17/08 --1 ND ND ND ND ND ND NDug/L 05/27/09 --1 ND ND ND ND ND ND NDug/L 11/11/09 --1 ND ND ND ND ND ND NDug/L 05/26/10 --1 ND ND ND ND ND ND NDug/L 11/15/10 --1 ND ND ND ND ND ND NDug/L 05/09/11 --1 ND ND ND ND ND ND NDug/L 11/14/11 --1 ND ND ND ND ND ND NDug/L 05/08/12 --1 ND ND ND ND ND ND NDug/L 11/05/12 --1 ND ND ND ND ND ND NDug/L 05/14/13 --1 ND ND ND ND ND ND NDug/L 11/12/13 --1 ND ND ND ND ND ND NDug/L 05/13/14 --1 ND ND ND ND ND ND ND ug/L 11/17/14 0.17 1 ND ND ND ND ND ND NDug/L 05/12/15 0.17 1 ND ND ND ND ND ND NDug/L 11/09/15 0.17 1 ND ND ND ND ND ND ND January 2016 Page 14 of 17 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx MW-1N MW-2N MW-3N MW-4N MW-5AN MW-5BN SWS Reporting Limit Upgradient Downgradient Summary of Groundwater Monitoring Results for C&D Wells BlanksMethod Detection Limit TABLE 6 Sampson County, North Carolina Detected Constituents Sampson County Active C&D Landfill, Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date Toluene ug/L 10/08/96 --5 ND ND ND --------NC 2L = 600 ug/L ug/L 02/18/97 --5 ND ND ND --------EPA MCL = 1000 ug/L ug/L 08/29/97 --2 ND 15.1 ND --------ug/L 10/30/97 ------19.9 ----------ug/L 02/23/98 --2 ND 3.76 ND --------ug/L 08/24/98 --1 ND ND 4.21 --------ug/L 02/22/99 --2 ND ND ND --------ug/L 08/23/99 --1 ND ND ND --------ug/L 02/21/00 --2 ND ND ND --------ug/L 10/10/00 --5 ND ND ND ND ND ND --ug/L 07/12/01 --5 ND ND ND ND ND ND --ug/L 10/24/01 --5 ND ND ND ND ND ND --ug/L 05/28/02 --5 ND ND ND ND ND ND --ug/L 11/05/02 --5 ND ND ND ND ND ND -- ug/L 05/29/03 --5 ND ND ND ND ND ND --ug/L 11/05/03 --5 ND ND ND ND ND ND --ug/L 05/25/04 --5 ND ND ND ND ND ND --ug/L 11/23/04 --5 ND ND ND ND ND ND --ug/L 05/16/05 --5 ND ND ND ND ND ND --ug/L 11/25/05 --5 ND ND ND ND ND ND --ug/L 05/24/06 --5 ND ND ND ND ND ND NDug/L 11/20/06 --5 ND ND ND ND ND ND NDug/L 05/22/07 --1 ND ND ND ND ND ND NDug/L 11/14/07 --1 ND ND ND ND ND ND NDug/L 05/29/08 --1 ND ND ND ND ND ND NDug/L 11/17/08 --1 ND ND ND ND ND ND NDug/L 05/27/09 --1 ND ND ND ND ND ND NDug/L 11/11/09 --1 ND ND ND ND ND ND NDug/L 05/26/10 --1 ND ND ND ND ND ND NDug/L 11/15/10 --1 ND ND ND ND ND ND NDug/L 05/09/11 --1 ND ND ND ND ND ND NDug/L 11/14/11 --1 ND ND ND ND ND ND NDug/L 05/08/12 --1 ND ND ND ND ND ND NDug/L 11/05/12 --1 ND ND ND ND ND ND NDug/L 05/14/13 --1 ND ND ND ND ND ND NDug/L 11/12/13 --1 ND ND ND ND ND ND NDug/L 05/13/14 --1 ND ND ND ND ND ND NDug/L 11/17/14 0.14 1 ND ND ND ND ND ND NDug/L 05/12/15 0.14 1 ND ND ND ND ND ND ND ug/L 11/09/15 0.14 1 ND ND ND ND ND ND NDTrichlorofluoromethaneug/L 10/08/96 --5 ND ND ND --------NC 2L = 2000 ug/L ug/L 02/18/97 --5 ND ND ND --------No EPA MCL ug/L 08/29/97 --2 ND ND 2.11 --------ug/L 10/30/97 --2 --ND ----------ug/L 02/23/98 --2 ND ND ND --------ug/L 08/24/98 --1.7 ND ND ND --------ug/L 02/22/99 --10 ND ND ND --------ug/L 08/23/99 --5 ND ND ND --------ug/L 02/21/00 --2 ND ND ND --------ug/L 10/10/00 --5 ND ND ND ND ND ND --ug/L 07/12/01 --5 ND ND ND ND ND ND --ug/L 10/24/01 --5 ND ND ND ND ND ND --ug/L 05/28/02 --5 ND ND ND ND ND ND --ug/L 11/05/02 --5 ND ND ND ND ND ND --ug/L 05/29/03 --5 ND ND ND ND ND ND --ug/L 11/05/03 --5 ND ND ND ND ND ND --ug/L 05/25/04 --5 ND ND ND ND ND ND --ug/L 11/23/04 --5 ND ND ND ND ND ND --ug/L 05/16/05 --5 ND ND ND ND ND ND --ug/L 11/25/05 --5 ND ND ND ND ND ND --ug/L 05/24/06 --5 ND ND ND ND ND ND NDug/L 11/20/06 --5 ND ND ND ND ND ND NDug/L 05/22/07 --1 ND ND ND ND ND ND NDug/L 11/14/07 --1 ND ND ND ND ND ND ND ug/L 05/29/08 --1 ND ND ND ND ND ND NDug/L 11/17/08 --1 ND ND ND ND ND ND NDug/L 05/27/09 --1 ND ND ND ND ND ND NDug/L 11/11/09 --1 ND ND ND ND ND ND NDug/L 05/26/10 --1 ND ND ND ND ND ND NDug/L 11/15/10 --1 ND ND ND ND ND ND NDug/L 05/09/11 --1 ND ND ND ND ND ND NDug/L 11/14/11 --1 ND ND ND ND ND ND NDug/L 05/08/12 --1 ND ND ND ND ND ND NDug/L 11/05/12 --1 ND ND ND ND ND ND NDug/L 05/14/13 --1 ND ND ND ND ND ND NDug/L 11/12/13 --1 ND ND ND ND ND ND NDug/L 05/13/14 --1 ND ND ND ND ND ND NDug/L 11/17/14 0.24 1 ND ND ND ND ND ND NDug/L 05/12/15 0.24 1 ND ND ND ND ND ND NDug/L 11/09/15 0.24 1 ND ND ND ND ND ND ND January 2016 Page 15 of 17 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx MW-1N MW-2N MW-3N MW-4N MW-5AN MW-5BN SWS Reporting Limit Upgradient Downgradient Summary of Groundwater Monitoring Results for C&D Wells BlanksMethod Detection Limit TABLE 6 Sampson County, North Carolina Detected Constituents Sampson County Active C&D Landfill, Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date Vinyl chloride ug/L 10/08/96 --10 ND ND ND --------NC 2L = 0.03 ug/L ug/L 02/18/97 --10 ND ND ND --------EPA MCL = 2 ug/L ug/L 08/29/97 --2 ND ND ND --------ug/L 10/30/97 --2 --ND ----------ug/L 02/23/98 --2 ND ND ND --------ug/L 08/24/98 --1 ND ND ND --------ug/L 02/22/99 --2 ND ND ND --------ug/L 08/23/99 --1 ND 4.75 9.09 --------ug/L 02/21/00 --2 ND ND ND --------ug/L 10/10/00 --10 ND ND ND ND ND ND --ug/L 07/12/01 --10 ND ND ND ND ND ND --ug/L 10/24/01 --10 ND ND ND ND ND ND --ug/L 05/28/02 --10 ND ND ND ND ND ND --ug/L 11/05/02 --10 ND ND ND ND ND ND -- ug/L 05/29/03 --10 ND ND ND ND ND ND --ug/L 11/05/03 --10 ND ND ND ND ND ND --ug/L 05/25/04 --10 ND ND ND ND ND ND --ug/L 11/23/04 --10 ND ND ND ND ND ND --ug/L 05/16/05 --10 ND ND ND ND ND ND --ug/L 11/25/05 --10 ND ND ND ND ND ND --ug/L 05/24/06 --10 ND ND ND ND ND ND NDug/L 11/20/06 --10 ND ND ND ND ND ND ND ug/L 05/22/07 --1 ND ND ND ND ND ND NDug/L 11/14/07 --1 ND ND ND ND ND ND NDug/L 05/29/08 --1 ND ND ND ND ND ND NDug/L 11/17/08 --1 ND ND ND ND ND ND NDug/L 05/27/09 --1 ND ND ND ND ND ND NDug/L 11/11/09 --1 ND ND ND ND ND ND NDug/L 05/26/10 --1 ND ND ND ND ND ND NDug/L 11/15/10 --1 ND ND ND ND ND ND NDug/L 05/09/11 --1 ND ND ND ND ND ND NDug/L 11/14/11 --1 ND ND ND ND ND ND NDug/L 05/08/12 --1 ND ND ND ND ND ND NDug/L 11/05/12 --1 ND ND ND ND ND ND NDug/L 05/14/13 --1 ND ND ND ND ND ND NDug/L 11/12/13 --1 ND ND ND ND ND ND NDug/L 05/13/14 --1 ND ND ND ND ND ND NDug/L 11/17/14 0.32 1 ND ND ND ND ND ND NDug/L 05/12/15 0.32 1 ND ND ND ND ND ND ND ug/L 11/09/15 0.32 1 ND ND ND ND ND ND NDXylenes (Total)ug/L 10/08/96 --5 ND ND ND --------NC 2L = 500 ug/L ug/L 02/18/97 --5 ND ND ND --------EPA MCL = 10000 ug/L ug/L 08/29/97 --4 ND ND ND --------ug/L 10/30/97 --4 --ND ----------ug/L 02/23/98 --4 ND ND ND --------ug/L 08/24/98 --2 ND ND 2.08 --------ug/L 02/22/99 --2 ND ND ND -------- ug/L 08/23/99 --2 ND ND ND --------ug/L 02/21/00 --6 ND ND ND --------ug/L 10/10/00 --5 ND ND ND ND ND ND --ug/L 07/12/01 --5 ND ND ND ND ND ND --ug/L 10/24/01 --5 ND ND ND ND ND ND --ug/L 05/28/02 --5 ND ND ND ND ND ND --ug/L 11/05/02 --5 ND ND ND ND ND ND --ug/L 05/29/03 --5 ND ND ND ND ND ND --ug/L 11/05/03 --5 ND ND ND ND ND 5.9 --ug/L 05/25/04 --5 ND ND ND ND ND ND --ug/L 11/23/04 --5 ND ND ND ND ND ND --ug/L 05/16/05 --5 ND ND ND ND ND ND --ug/L 11/25/05 --5 ND ND ND ND ND ND --ug/L 05/24/06 --5 ND ND ND ND ND ND NDug/L 11/20/06 --5 ND ND ND ND ND ND NDug/L 05/22/07 --5 ND ND ND ND ND ND NDug/L 11/14/07 --5 ND ND ND ND ND ND NDug/L 05/29/08 --5 ND ND ND ND ND ND NDug/L 11/17/08 --5 ND ND ND ND ND ND NDug/L 05/27/09 --5 ND ND ND ND ND ND NDug/L 11/11/09 --5 ND ND ND ND ND ND NDug/L 05/26/10 --5 ND ND ND ND ND ND NDug/L 11/15/10 --5 ND ND ND ND ND ND NDug/L 05/09/11 --5 ND ND ND ND ND ND NDug/L 11/14/11 --5 ND ND ND ND ND ND NDug/L 05/08/12 --5 ND ND ND ND ND ND NDug/L 11/05/12 --5 ND ND ND ND ND ND NDug/L 05/14/13 --5 ND ND ND ND ND ND NDug/L 11/12/13 --5 ND ND ND ND ND ND NDug/L 05/13/14 --5 ND ND ND ND ND ND NDug/L 11/17/14 0.45 5 ND ND ND ND ND ND NDug/L 05/12/15 0.45 5 ND ND ND ND ND ND NDug/L 11/09/15 0.45 5 ND ND ND ND ND ND ND January 2016 Page 16 of 17 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx MW-1N MW-2N MW-3N MW-4N MW-5AN MW-5BN SWS Reporting Limit Upgradient Downgradient Summary of Groundwater Monitoring Results for C&D Wells BlanksMethod Detection Limit TABLE 6 Sampson County, North Carolina Detected Constituents Sampson County Active C&D Landfill, Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date Tetrahydrofuran ug/L 05/09/11 ----ND ND 1.2 ND ND ND ND(no standard)ug/L 11/14/11 ----ND ND ND ND ND ND NDNo EPA MCL ug/L 05/08/12 ----ND ND ND ND ND ND NDug/L 11/05/12 ----ND ND ND ND ND ND NDug/L 05/14/13 ----ND ND ND ND ND ND NDug/L 11/12/13 ----ND ND ND ND ND ND NDug/L 05/13/14 ----ND ND ND ND ND ND NDug/L 11/17/14 0.80 --ND ND ND ND ND ND NDug/L 05/12/15 0.80 --ND ND ND ND ND ND NDug/L 11/09/15 0.80 --ND ND ND ND ND ND NDChloridemg/L 10/08/96 ----2.2 4.2 3.7 --------NC 2L = 250 mg/L mg/L 02/18/97 ----2.4 36 1.7 --------EPA MCL = 250 mg/L mg/L 08/29/97 ----2.03 194 12.4 --------mg/L 02/23/98 ----3.37 186 74.1 --------mg/L 08/24/98 ----3.01 252 271 --------mg/L 02/22/99 ----3.25 212 258 --------mg/L 08/23/99 ----4.49 192 254 --------mg/L 05/22/07 ----11 43 71 0.7 ----NDmg/L 11/14/07 ----10 62 93 20 6.3 3.3 J NDmg/L 05/29/08 ----5.9 B 37 67 5.9 B 3.7 B 2.5 B 1.9 Jmg/L 11/17/08 ----5.1 33 44 7.4 1.2 J 1.8 J NDmg/L 05/27/09 ----7.9 29 42 9.5 4.3 J 3.6 J NDmg/L 11/11/09 ----7.6 31 42 12 5.5 3.7 J NDmg/L 05/26/10 ----6.0 40 43 8.9 3.8 J 3.7 J NDmg/L 11/15/10 ----8.5 B 29 29 13 4.3 B 3.4 B 1.9 Jmg/L 05/09/11 ----26 29 34 9.4 B 4.3 B 3.3 B 1.9 Jmg/L 11/14/11 ----57 27 77 8.6 4.6 B 3.0 B 1.5 Jmg/L 05/08/12 ----43 26 130 7.5 4.3 B 2.9 B 1.2 Jmg/L 11/05/12 ----72 36 140 14 6.1 B 3.1 B 1.4 Jmg/L 05/14/13 ----49 21 160 3.6 3.2 3.1 NDmg/L 11/12/13 ----37 20 130 12 5.4 3.0 J NDmg/L 05/13/14 ----150 9.1 97 3.3 J 3.0 J 3.1 J NDmg/L 11/17/14 2.2 --79 15 110 43 5.2 3.5 J NDmg/L 05/12/15 2.2 --21 11 97 3.2 J 2.4 J 3.7 J NDmg/L 11/09/15 2.2 --48 110 70 5.5 ND 2.3 J NDTotal Dissolved Solids mg/L 10/08/96 ----140 130 160 --------NC 2L = 1000 mg/L mg/L 02/18/97 ----10 54 22 --------No EPA MCL mg/L 08/29/97 ----22 403 54 --------mg/L 02/23/98 ----30 452 233 --------mg/L 08/24/98 ----27 638 830 --------mg/L 02/22/99 ----36 563 1120 --------mg/L 08/23/99 ----30 556 1150 --------mg/L 05/22/07 ----28 470 860 120 ----NDmg/L 11/14/07 ----78 570 830 180 62 44 ND mg/L 05/29/08 ----48 430 900 140 40 40 NDmg/L 11/17/08 ----38 390 890 150 32 50 NDmg/L 05/27/09 ----36 370 950 160 50 44 NDmg/L 11/11/09 ----52 360 870 160 62 18 NDmg/L 05/26/10 ----36 530 970 200 58 40 NDmg/L 11/15/10 ----18 370 1000 150 22 18 NDmg/L 05/09/11 ----110 440 940 110 50 50 NDmg/L 11/14/11 ----94 300 830 64 36 30 NDmg/L 05/08/12 ----130 290 1000 56 26 46 NDmg/L 11/05/12 ----130 320 920 48 24 10 NDmg/L 05/14/13 ----200 300 890 140 54 76 NDmg/L 11/12/13 ----110 300 890 38 46 24 NDmg/L 05/13/14 ----40 170 840 58 22 22 NDmg/L 11/17/14 10.00 --160 250 970 100 24 10 NDmg/L 05/12/15 10.00 --56 160 850 260 86 ND NDmg/L 11/09/15 10.00 --100 230 880 110 ND ND NDSulfate mg/L 10/08/96 --1 5.01 --7.8 --------NC 2L = 250 mg/L mg/L 02/18/97 --5 5.9 --9.6 --------No EPA MCL mg/L 08/29/97 --1 14.9 4.4 7.66 --------mg/L 02/23/98 --0.2 74.9 7.24 4.22 --------mg/L 08/24/98 --0.2 46.8 8.16 2.63 --------mg/L 02/22/99 --0.2 43.8 19.3 6.05 --------mg/L 08/23/99 --0.2 3.14 21.7 1.11 --------mg/L 05/22/07 --250 2.9 B 180 50 48 ----2.5 Jmg/L 11/14/07 --250 1.6 J 110 J 110 J 55 J 8.6 J 4.8 J ND mg/L 05/29/08 --250 4.8 J 110 J 100 J 55 J 12 J 6.9 J NDmg/L 11/17/08 --250 5.3 J 100 J 35 J 30 J 6.9 J 8.4 J NDmg/L 05/27/09 --250 5.0 J 100 J 36 J 50 J 10 J 8.6 J NDmg/L 11/11/09 --250 3.3 J 79 J 80 J 53 J 12 J 8.1 J NDmg/L 05/26/10 --250 5.3 J 110 J 79 J 25 J 6.1 J 8.3 J NDmg/L 11/15/10 --250 4.8 J 90 J 54 J 56 J 9.9 J 8.1 J NDmg/L 05/09/11 --250 4.2 J 78 J 49 J 39 J 11 J 7.3 J NDmg/L 11/14/11 --250 4.4 J 57 J 100 J 24 J 11 J 7.7 J ND mg/L 05/08/12 --250 4.6 J 28 J 130 J 20 J 13 J 6.8 J NDmg/L 11/05/12 --250 3.5 J 32 J 130 J 25 J 11 J 8.2 J NDmg/L 05/14/13 --250 5.0 J 43 J 220 J 14 J 9.6 J 7.8 J NDmg/L 11/12/13 --250 6.4 J 46 J 100 J 14 J 9.1 J 7.0 J NDmg/L 41772.00 --250 8.3 J 43 J 69 J 9.9 J 8.0 J 7.4 J NDmg/L 11/17/14 2.9 250 8.9 J 46 J 76 J 19 J 9.8 J 7.1 J NDmg/L 05/12/15 2.9 250 7.5 J 41 J 52 J 5.3 J 3.8 J 8.5 J NDmg/L 11/09/15 2.9 250 8.9 J 45 J 43 J 12 J 3.5 J 6.7 J ND January 2016 Page 17 of 17 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx MW-1N MW-2N MW-3N MW-4N MW-5AN MW-5BN SWS Reporting Limit Upgradient Downgradient Summary of Groundwater Monitoring Results for C&D Wells BlanksMethod Detection Limit TABLE 6 Sampson County, North Carolina Detected Constituents Sampson County Active C&D Landfill, Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date Alkalinity mg/L 10/08/96 --1.00 --1.00 13.00 --------(no standard)mg/L 02/18/97 --1 1 --3 --------No EPA MCL mg/L 08/28/97 --1 --60.3 ----------mg/L 08/29/97 --1 1.56 --3.64 --------mg/L 02/23/98 --1 --92.7 2.78 --------mg/L 08/24/98 --1 1.5 129 316 --------mg/L 02/22/99 --1 1.99 153 608 --------mg/L 08/23/99 --1 1.89 173 503 --------mg/L 05/22/07 ----3.2 2.3 2.8 ND ----NDmg/L 11/14/07 ----ND 270 440 ND ND ND NDmg/L 05/29/08 ----ND 97 370 ND ND ND NDmg/L 11/17/08 ----2.8 B 150 460 ND 2.7 B ND 6.3 Jmg/L 05/27/09 ----9.6 J 150 580 11 J 12 J 12 J NDmg/L 11/11/09 ----ND 180 440 ND ND ND ND mg/L 05/26/10 ----8.0 J 280 720 9.4 J 8.2 J 12 J NDmg/L 11/15/10 ----ND 220 840 ND ND ND NDmg/L 05/09/11 ----ND 240 650 ND ND 12 NDmg/L 11/14/11 ----ND 250 620 ND ND ND NDmg/L 05/08/12 ----ND 200 550 ND ND ND NDmg/L 11/05/12 ----ND 330 500 ND ND ND NDmg/L 05/14/13 ----ND 150 280 ND ND ND NDmg/L 11/12/13 ----ND 190 480 ND ND ND NDmg/L 05/13/14 ----ND 86 580 ND ND ND NDmg/L 11/17/14 14.00 --ND 190 680 ND ND ND NDmg/L 05/12/15 14.00 --ND 110 530 32 15 ND NDmg/L 11/09/15 14.00 --ND 160 660 ND ND ND ND Notes:mg/L =milligrams per literug/L =micrograms per literND =Not detected at the stated reporting limitJ =Estimated value B =Blank-qualified data# =EPA Action Level* = EPA Secondary MCL-- =no dataBold only =Concentration above current NC 2L Groundwater Standard or NC SWS Groundwater Protection Standard Shaded and Bold =Concentration above current NC 2L Groundwater Standard or NC SWS Groundwater Protection Standard and EPA MCLBlanks =field, trip and/or method blanksSWS GPS =Solid Waste Section Groundwater Protection StandardEPA MCL =US Environmental Protection Agency Maximum Contaminant LevelNC 2L = North Carolina 2L Groundwater StandardSWS Reporting Limit =NCPQL or lab-specific reporting limit prior to 2007 and NCSWSL starting on 01/18/071) Data prior to 2/28/07 provided by Richardson, Smith, Gardner and Associates.2) Results from laboratory re-analysis are reported in parentheses.3) The following dilutions were noted for the November 2015 event: MW-2N: Alkalinity (2x) and MW-3N: Alkalinity (5x) January 2016 Page 1 of 3 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx MW-1N MW-2N MW-3N MW-4N MW-5AN MW-5BN pH (field)S.U.10/08/96 5.76 4.82 5.49 ---- S.U.02/18/97 4.82 --5.43 ------ S.U.08/28/97 --5.63 -------- S.U.08/29/97 5.02 --5.08 ------ S.U.10/09/97 --5.65 -------- S.U.10/30/97 --5.50 -------- S.U.02/23/98 4.36 --4.47 ------ S.U.04/20/98 --5.52 -------- S.U.08/24/98 4.98 --6.15 ------ S.U.10/27/98 --6.10 --------S.U.02/22/99 4.60 --6.51 ------S.U.04/20/99 --5.88 --------S.U.08/23/99 4.77 --6.46 ------S.U.05/28/02 --6.10 --------S.U.11/05/02 4.50 5.70 6.60 4.80 4.60 5.60S.U.05/29/03 4.60 --6.10 5.50 4.90 5.70S.U.05/24/06 4.30 6.10 6.60 4.70 4.40 5.70S.U.11/20/06 4.20 6.10 6.50 5.90 5.10 5.50S.U.05/22/07 3.76 6.27 6.50 4.74 4.43 5.30S.U.11/14/07 4.01 6.36 6.93 4.46 4.56 5.44S.U.05/29/08 4.24 6.40 6.73 4.54 4.55 5.60 S.U.11/17/08 4.68 6.93 7.29 6.18 5.67 5.01 S.U.05/27/09 4.13 6.37 6.61 4.62 4.73 5.14 S.U.11/11/09 3.91 6.17 6.56 4.56 4.48 5.33 S.U.05/26/10 3.94 6.12 6.18 5.43 4.83 4.48 S.U.11/15/10 4.35 6.46 6.85 4.59 4.59 5.18 S.U.05/09/11 3.41 5.88 6.18 3.82 3.78 4.75 S.U.11/14/11 4.56 6.18 6.63 4.62 4.45 5.15 S.U.05/08/12 3.31 5.79 6.42 4.85 4.14 5.04 S.U.11/05/12 4.16 6.37 6.81 4.79 4.45 4.92 S.U.05/14/13 4.14 6.37 6.77 6.05 4.47 4.92 S.U.11/12/13 4.46 6.41 6.87 5.18 4.77 5.74 S.U.05/13/14 4.35 6.45 6.82 5.84 5.18 5.54 S.U.11/17/14 3.95 5.95 6.65 4.20 4.28 5.11 S.U.05/12/15 2.36 4.17 6.22 6.77 5.34 4.46S.U.11/09/15 4.11 6.10 6.74 5.33 5.01 5.40Specific Conductance (field)uS/cm 10/08/96 33 126 55 ------uS/cm 02/18/97 34 --48 ------uS/cm 08/28/97 --634 --------uS/cm 08/29/97 30 --80 ------uS/cm 10/09/97 --842 --------uS/cm 10/30/97 --582 --------uS/cm 02/23/98 42 --181 ------uS/cm 04/20/98 --1098 --------uS/cm 08/24/98 32.9 --1161 ------uS/cm 10/27/98 --764 -------- uS/cm 02/22/99 52.4 --1931 ------ uS/cm 04/20/99 --1052 -------- uS/cm 08/23/99 65.7 --1871 ------ uS/cm 05/28/02 --778 -------- uS/cm 11/05/02 65 --1241 91 86 44 uS/cm 05/24/06 95 724 1327 53 102 47 uS/cm 11/20/06 110 707 1071 51 36 40 uS/cm 05/22/07 89 934 1630 178 87 30 uS/cm 11/14/07 175 1000 1340 316 140 60 uS/cm 05/29/08 109 761 1570 202 84 45 uS/cm 11/17/08 78 629 1368 125 29 37 uS/cm 05/27/09 78 691 1582 193 53 38 uS/cm 11/11/09 118 736 1439 222 84 39 uS/cm 05/26/10 70 980 1625 156 44 38uS/cm 11/15/10 89 809 1684 267 66 43uS/cm 05/09/11 187 894 1848 212 79 44uS/cm 11/14/11 260 731 1554 133 82 40uS/cm 05/08/12 192 550 1514 115 74 38uS/cm 11/05/12 341 815 1554 142 86 35uS/cm 05/14/13 262 505 1232 75 45 36uS/cm 11/12/13 266 526 1328 155 126 88uS/cm 05/13/14 162 343 1467 83 72 68uS/cm 11/17/14 407 561 1723 282 85 46uS/cm 05/12/15 127 335 1336 107 28 34uS/cm 11/09/15 266 479 1521 101 30 40 Upgradient DowngradientDetected Monitoring Constituent/Parameter Reporting Units Sample Date Sampson County, North Carolina TABLE 7 Summary of Field Parameters for C&D Wells Sampson County Active C&D Landfill, Permit No. 82-02 January 2016 Page 2 of 3 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx MW-1N MW-2N MW-3N MW-4N MW-5AN MW-5BN Upgradient DowngradientDetected Monitoring Constituent/Parameter Reporting Units Sample Date Sampson County, North Carolina TABLE 7 Summary of Field Parameters for C&D Wells Sampson County Active C&D Landfill, Permit No. 82-02 Temperature (field)Celsius 10/08/96 20.80 14.70 21.10 ------ Celsius 02/18/97 16.10 --13.60 ------ Celsius 08/28/97 --21.10 -------- Celsius 08/29/97 21.10 --21.90 ------ Celsius 10/09/97 --18.80 -------- Celsius 10/30/97 --14.80 -------- Celsius 02/23/98 14.60 --14.20 ------ Celsius 04/20/98 --22.90 -------- Celsius 08/24/98 22.90 --22.10 ------ Celsius 10/27/98 --13.40 --------Celsius 02/22/99 14.80 --14.00 ------Celsius 04/20/99 --21.10 --------Celsius 08/23/99 20.90 --21.00 ------Celsius 05/28/02 --18.00 --------Celsius 11/05/02 18.00 18.00 19.00 13.00 22.00 18.00Celsius05/29/03 19.00 --18.00 20.00 20.00 19.00Celsius05/24/06 18.00 17.00 17.00 19.00 18.00 19.00Celsius11/20/06 20.00 18.00 18.00 17.00 16.00 19.00Celsius05/22/07 19.39 17.29 17.34 20.06 18.10 19.10Celsius11/14/07 21.45 19.87 23.99 24.51 22.96 20.50Celsius05/29/08 18.85 17.33 17.39 19.19 18.90 19.18 Celsius 11/17/08 18.99 17.70 17.98 19.31 18.12 18.95 Celsius 05/27/09 18.78 16.63 17.18 19.09 19.52 19.86 Celsius 11/11/09 19.74 19.31 18.27 20.01 20.51 19.28 Celsius 05/26/10 18.81 18.41 17.25 21.18 19.56 18.45 Celsius 11/15/10 20.82 20.39 18.36 21.40 20.54 19.01 Celsius 05/09/11 19.63 17.35 16.89 19.49 18.28 18.98 Celsius 11/14/11 21.93 20.46 19.46 21.86 21.67 20.87 Celsius 05/08/12 19.95 18.80 18.54 20.09 20.77 20.82 Celsius 11/05/12 19.40 19.58 18.34 21.78 21.92 19.13 Celsius 05/14/13 18.87 17.51 17.17 18.64 19.58 19.39 Celsius 11/12/13 21.3 19.9 19.1 22.3 22.7 20.6 Celsius 05/13/14 19.1 17.6 17.2 20.5 18.8 19.8 Celsius 11/17/14 21.4 19.4 19.0 21.4 22.1 20.1 Celsius 05/12/15 18.5 16.3 16.0 19.2 18.9 18.4Celsius11/09/15 20.8 19.9 19.2 22.4 21.8 20.3Turbidity (field)NTU 10/08/96 0.94 2.7 4.1 ------NTU 02/18/97 0.47 ----------NTU 08/28/97 --7.76 8.72 ------NTU 08/29/97 4.17 ----------NTU 10/09/97 --3.12 --------NTU 10/30/97 --4 2 ------NTU 02/23/98 2 ----------NTU 04/20/98 --3 2.33 ------NTU 08/24/98 1.09 ----------NTU 10/27/98 --7.13 1 ------ NTU 02/22/99 1 ---------- NTU 04/20/99 --5.01 4.69 ------ NTU 08/23/99 10.3 ---------- NTU 05/22/07 13.9 52.2 1.4 9.1 0 0 NTU 11/14/07 78.5 152 98.1 68.1 59 36.5 NTU 05/29/08 5.4 29.8 29.6 45.2 63 6.6 NTU 11/17/08 0.34 13.6 5.00 78.0 50.3 0.49 NTU 05/27/09 2.60 74.5 2.71 46.5 51.7 2.65 NTU 11/11/09 0.59 47.0 13.9 95.2 89.7 0.38 NTU 05/26/10 0.53 6.79 70.9 99.1 49.0 18.45 NTU 11/15/10 0.48 3.43 4.02 42.1 44.5 0.84 NTU 05/09/11 0.23 0.49 0.67 8.85 57.8 0.46 NTU 11/14/11 85 2.64 21.5 10.7 90.6 1.04 NTU 05/08/12 5.51 5.26 15.5 88.0 160 2.95NTU11/05/12 26.8 3.42 17.7 23.8 87.7 0.64NTU05/14/13 10.8 9.63 1.16 97.3 18.7 0.68NTU11/12/13 24.1 22.4 2.84 11.5 25.9 1.82NTU05/13/14 3.16 88.5 9.01 95.0 49.3 2.06NTU11/17/14 0.50 56.5 18.20 9.5 50.3 2.52NTU05/12/15 0.26 4.11 0.74 272 115 0.55NTU11/09/15 1.09 10.4 1.52 165 102 3.25 January 2016 Page 3 of 3 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx MW-1N MW-2N MW-3N MW-4N MW-5AN MW-5BN Upgradient DowngradientDetected Monitoring Constituent/Parameter Reporting Units Sample Date Sampson County, North Carolina TABLE 7 Summary of Field Parameters for C&D Wells Sampson County Active C&D Landfill, Permit No. 82-02 ORP (field)millivolts 05/22/07 428 -80 -151 301 367 140 millivolts 11/14/07 399 -59 -47 317 300 147 millivolts 05/29/08 382 -68 -127 310 159 106 millivolts 11/17/08 321.5 21.7 -52.4 295.9 304.3 164.0 millivolts 05/27/09 292.3 -19.3 -39.3 259.9 218.6 157.6 millivolts 11/11/09 284.5 -34.6 -42.3 233.1 230.4 149.7 millivolts 05/26/10 213.3 -21.1 -45.3 140.7 164.3 169.5 millivolts 11/15/10 262.9 -39.1 -69.8 279.9 282.8 199.4 millivolts 05/09/11 265.2 -32.3 -37.2 240.8 247.0 161.5 millivolts 11/14/11 105.4 -15.2 -48.2 167.1 142.2 72.5millivolts05/08/12 253.4 -90.9 -61.4 142.7 200.9 137.3millivolts11/05/12 108.0 -14.3 -61.8 116.9 111.8 79.1millivolts05/14/13 102.9 -45.4 21.4 80.1 128.3 106.7millivolts11/12/13 382.5 -77.9 -52.0 294.5 347.1 154.3millivolts05/13/14 391.6 0.0 -87.9 174.7 302.3 146.7millivolts11/17/14 218.6 13.9 29.9 170.3 162.2 132.0millivolts05/12/15 168.7 12.1 -47.0 12.7 107.9 107.2millivolts11/09/15 485.6 28.7 -38.8 363.8 282.4 198.2Dissolved Oxygen (field)mg/L 05/22/07 5.10 0.60 0.50 6.10 5.30 2.50mg/L 11/14/07 1.58 0.72 0.58 6.84 6.80 0.66mg/L 05/29/08 4.83 0.42 0.38 8.56 6.76 4.51 mg/L 11/17/08 5.59 1.05 0.87 6.71 8.73 2.19 mg/L 05/27/09 4.57 0.38 0.46 6.28 6.45 1.21 mg/L 11/11/09 2.17 0.75 0.88 4.56 6.06 1.30 mg/L 05/26/10 5.59 0.39 0.59 6.30 6.94 0.57 mg/L 11/15/10 6.20 1.08 1.52 5.10 6.19 0.47 mg/L 05/09/11 5.67 0.76 0.65 5.59 6.71 0.98 mg/L 11/14/11 4.68 0.24 0.26 3.60 4.41 1.52 mg/L 05/08/12 6.45 0.90 0.49 6.75 6.17 3.30 mg/L 11/05/12 1.42 0.58 0.28 4.33 5.23 1.12 mg/L 05/14/13 2.24 2.86 0.79 7.54 7.35 1.62 mg/L 11/12/13 5.07 0.22 0.67 5.50 6.51 1.18 mg/L 05/13/14 8.22 0.19 0.30 7.96 7.25 1.08 mg/L 11/17/14 3.88 0.40 0.15 3.09 5.25 1.22 mg/L 05/12/15 7.17 0.48 0.33 7.00 6.34 0.38mg/L 11/09/15 6.74 0.48 0.30 5.83 6.05 2.30 Notes:mg/L =milligrams per literS.U. =Standard UnitsNTU =Nephelometric Turbidity UnitsND =Not detected at the stated reporting limituS/cm =microsiemens per centimeter-- =no data January 2016 Page 1 of 9 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Antimony ug/L 11/05/03 --dry ----ND No SW Standard ug/L 05/25/04 30 dry ND --ND ug/L 05/16/05 30 dry ND --ND ug/L 11/25/05 30 dry ND --ND ug/L 05/24/06 30 dry ND --ND ug/L 11/20/06 30 dry ND --ND ug/L 05/22/07 6 dry ND --ND ug/L 11/15/07 6 ND ND dry -- ug/L 05/28/08 6 ND ND ND ND ug/L 11/17/08 6 dry ND ND ND ug/L 05/26/09 6 ND ND ND ND ug/L 11/11/09 6 0.0860 B ND 0.0730 B 0.0770 J ug/L 05/26/10 6 ND ND ND ND ug/L 11/15/10 6 ND ND ND ND ug/L 05/09/11 6 ND ND ND ND ug/L 11/14/11 6 ND ND ND ND ug/L 05/08/12 6 ND ND 0.264 J ND ug/L 11/05/12 6 ND ND ND ND ug/L 05/13/13 6 ND ND ND ND ug/L 11/11/13 6 ND ND ND ND ug/L 05/12/14 6 ND ND ND ND ug/L 11/17/14 6 0.363 J 0.234 J 0.806 J ND ug/L 05/12/15 6 0.368 J ND 1.37 J ND ug/L 11/09/15 6 ND ND 0.794 J ND Arsenic ug/L 11/05/03 --dry ND --ND SW Standard = 50 ug/L ug/L 05/25/04 10 dry ND --ND ug/L 05/16/05 10 dry ND --ND ug/L 11/25/05 10 dry ND --ND ug/L 05/24/06 10 dry ND --ND ug/L 11/20/06 10 dry ND --ND ug/L 05/22/07 10 dry ND --ND ug/L 11/15/07 10 ND ND dry ND ug/L 05/28/08 10 6.6 B 2.9 B ND 4.3 J ug/L 11/17/08 10 dry ND ND ND ug/L 05/26/09 10 ND ND ND ND ug/L 11/11/09 10 2.94 J 2.87 J ND ND ug/L 05/26/10 10 ND ND ND ND ug/L 11/15/10 10 ND ND ND 3.98 J ug/L 05/09/11 10 ND ND 3.13 J ND ug/L 11/14/11 10 2.81 J ND ND ND ug/L 05/08/12 10 11.9 ND ND ND ug/L 11/05/12 10 4.55 B 4.38 B 4.29 B 4.48 J ug/L 05/13/13 10 ND ND ND ND ug/L 11/11/13 10 ND ND ND ND ug/L 05/12/14 10 ND ND ND ND ug/L 11/17/14 10 ND 6.18 J ND ND ug/L 05/12/15 10 ND ND ND ND ug/L 11/09/15 10 ND ND ND ND Blanks Sampson County, North Carolina TABLE 8 Summary of Surface Water Monitoring Results Detected Constituents Sampson County Active MSW/C&D Landfill , Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date SWS Reporting Limit DownstreamUpstream SW-1 SW-4 SW-5 January 2016 Page 2 of 9 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Blanks Sampson County, North Carolina TABLE 8 Summary of Surface Water Monitoring Results Detected Constituents Sampson County Active MSW/C&D Landfill , Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date SWS Reporting Limit DownstreamUpstream SW-1 SW-4 SW-5 Barium ug/L 11/05/03 ----ND --ND (No SW Standard)ug/L 05/25/04 500 --ND --ND ug/L 05/16/05 500 --ND --ND ug/L 11/25/05 500 --ND --ND ug/L 05/24/06 500 --ND --ND ug/L 11/20/06 500 --ND --ND ug/L 05/22/07 100 dry 27.8 J --0.3 J ug/L 11/15/07 100 40.0 J 12.3 J dry 0.20 J ug/L 05/28/08 100 21.3 J 58.2 J 57.2 J 0.60 J ug/L 11/17/08 100 dry 12.1 J 48.1 J ND ug/L 05/26/09 100 11.2 J 16.9 J 61.0 J ND ug/L 11/11/09 100 60.1 J 26.0 J 55.9 J ND ug/L 05/26/10 100 12.5 J 68.2 J 15.2 J ND ug/L 11/15/10 100 8.18 J 8.11 J 143 ND ug/L 05/09/11 100 13.2 J 12.5 J 122 ND ug/L 11/14/11 100 11.9 J 16.4 J 214 ND ug/L 05/08/12 100 45.9 J 50.6 J 144 ND ug/L 11/05/12 100 9.37 J 15.6 J 207 ND ug/L 05/13/13 100 11.5 J 14.4 J 163 1.21 J ug/L 11/11/13 100 9.56 J 15.5 J 194 1.22 J ug/L 05/12/14 100 13.8 J 14.5 J 189 ND ug/L 11/17/14 100 10.0 J 22.4 J 60.2 J ND ug/L 05/12/15 100 20.6 J 16.7 J 150 ND ug/L 11/09/15 100 24.6 J 30.2 J 144 ND Beryllium ug/L 11/05/03 --dry ND --ND SW Standard = 6.5 ug/L ug/L 05/25/04 2 dry ND --ND ug/L 05/16/05 2 dry ND --ND ug/L 11/25/05 2 dry ND --ND ug/L 05/24/06 2 dry ND --ND ug/L 11/20/06 2 dry ND --ND ug/L 05/22/07 1 dry ND --ND ug/L 11/15/07 1 ND ND dry ND ug/L 05/28/08 1 ND ND ND ND ug/L 11/17/08 1 dry ND ND ND ug/L 05/26/09 1 ND 0.11 J ND ND ug/L 11/11/09 1 0.425 J 0.303 J ND ND ug/L 05/26/10 1 ND 0.120 J 0.152 J ND ug/L 11/15/10 1 ND ND 0.549 J 0.106 J ug/L 05/09/11 1 ND 0.111 J 0.806 J ND ug/L 11/14/11 1 ND 0.102 J 0.260 J ND ug/L 05/08/12 1 0.710 J ND ND ND ug/L 11/05/12 1 ND 0.128 J 0.363 J ND ug/L 05/13/13 1 ND ND ND ND ug/L 11/11/13 1 ND ND 0.337 J ND ug/L 05/12/14 1 ND ND ND ND ug/L 11/17/14 1 ND ND ND ND ug/L 05/12/15 1 ND ND 0.124 J ND ug/L 11/09/15 1 ND 1.41 ND ND January 2016 Page 3 of 9 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Blanks Sampson County, North Carolina TABLE 8 Summary of Surface Water Monitoring Results Detected Constituents Sampson County Active MSW/C&D Landfill , Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date SWS Reporting Limit DownstreamUpstream SW-1 SW-4 SW-5 Cadmium ug/L 11/05/03 --dry ND --ND SW Standard = 2 ug/L ug/L 05/25/04 1 dry ND --ND ug/L 05/16/05 1 dry ND --ND ug/L 11/25/05 1 dry ND --ND ug/L 05/24/06 1 dry ND --ND ug/L 11/20/06 1 dry ND --ND ug/L 05/22/07 1 dry ND --ND ug/L 11/15/07 1 ND ND dry ND ug/L 05/28/08 1 ND ND ND ND ug/L 11/17/08 1 dry ND ND ND ug/L 05/26/09 1 ND ND ND ND ug/L 11/11/09 1 ND ND ND ND ug/L 05/26/10 1 ND ND ND ND ug/L 11/15/10 1 ND ND 0.360 J ND ug/L 05/09/11 1 ND ND ND ND ug/L 11/14/11 1 ND ND ND ND ug/L 05/08/12 1 ND ND ND ND ug/L 11/05/12 1 ND ND ND ND ug/L 05/13/13 1 ND ND ND ND ug/L 11/11/13 1 ND ND ND ND ug/L 05/12/14 1 ND ND ND ND ug/L 11/17/14 1 ND ND ND ND ug/L 05/12/15 1 ND ND ND ND ug/L 11/09/15 1 ND ND ND ND Chromium ug/L 11/05/03 --dry ND --ND SW Standard = 50 ug/L ug/L 05/25/04 10 dry ND --ND ug/L 05/16/05 10 dry ND --ND ug/L 11/25/05 10 dry ND --ND ug/L 05/24/06 10 dry ND --ND ug/L 11/20/06 10 dry ND --ND ug/L 05/22/07 10 dry ND --ND ug/L 11/15/07 10 ND ND dry ND ug/L 05/28/08 10 2.0 J 19.4 ND ND ug/L 11/17/08 10 dry 7.2 B 7.9 B 4.9 J ug/L 05/26/09 10 ND ND ND ND ug/L 11/11/09 10 1.23 J ND ND ND ug/L 05/26/10 10 ND 1.35 J ND ND ug/L 11/15/10 10 ND ND ND ND ug/L 05/09/11 10 ND ND ND ND ug/L 11/14/11 10 ND ND ND ND ug/L 05/08/12 10 9.66 J ND ND ND ug/L 11/05/12 10 ND ND ND ND ug/L 05/13/13 10 ND ND ND ND ug/L 11/11/13 10 ND ND ND ND ug/L 05/12/14 10 ND ND ND ND ug/L 11/17/14 10 ND 1.57 J ND ND ug/L 05/12/15 10 2.78 B 2.41 B 7.43 B 1.82 J ug/L 11/09/15 10 ND ND 1.98 J ND January 2016 Page 4 of 9 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Blanks Sampson County, North Carolina TABLE 8 Summary of Surface Water Monitoring Results Detected Constituents Sampson County Active MSW/C&D Landfill , Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date SWS Reporting Limit DownstreamUpstream SW-1 SW-4 SW-5 Cobalt ug/L 11/05/03 ----ND --ND (No SW Standard)ug/L 05/25/04 10 --ND --ND ug/L 05/16/05 10 --ND --ND ug/L 11/25/05 10 --ND --ND ug/L 05/24/06 10 --ND --ND ug/L 11/20/06 10 --ND --ND ug/L 05/22/07 10 dry 5.6 J --ND ug/L 11/15/07 10 2.5 J 3.3 J dry ND ug/L 05/28/08 10 2.5 J 6.0 J 4.1 J ND ug/L 11/17/08 10 dry ND 2.3 J ND ug/L 05/26/09 10 1.1 J 3.3 J 0.9 J ND ug/L 11/11/09 10 1.33 J 6.13 J 1.17 J ND ug/L 05/26/10 10 ND 1.39 J 2.05 J ND ug/L 11/15/10 10 ND ND 9.34 J ND ug/L 05/09/11 10 ND 1.72 J 13.1 ND ug/L 11/14/11 10 1.97 J 3.13 J 6.43 J ND ug/L 05/08/12 10 2.20 J 4.46 J ND ND ug/L 11/05/12 10 2.16 J 3.16 J 4.96 J ND ug/L 05/13/13 10 1.61 J 1.53 J ND ND ug/L 11/11/13 10 1.14 J 1.90 J 6.10 J ND ug/L 05/12/14 10 1.46 J 1.24 J 2.05 J ND ug/L 11/17/14 10 1.43 J 1.93 J ND ND ug/L 05/12/15 10 1.11 J ND 18.7 ND ug/L 11/09/15 10 1.17 J 18.7 7.35 J ND Copper ug/L 11/05/03 --dry ND --ND SW Standard = 7 ug/L*ug/L 05/25/04 200 dry ND --ND ug/L 05/16/05 200 dry ND --ND ug/L 11/25/05 200 dry ND --ND ug/L 05/24/06 200 dry ND --ND ug/L 11/20/06 200 dry ND --ND ug/L 05/22/07 10 dry ND --ND ug/L 11/15/07 10 ND ND dry ND ug/L 05/28/08 10 1.20 B ND ND 1.00 J ug/L 11/17/08 10 dry ND 1.70 J ND ug/L 05/26/09 10 ND ND ND 1.47 J ug/L 11/11/09 10 ND ND ND ND ug/L 05/26/10 10 ND ND ND ND ug/L 11/15/10 10 ND ND 2.48 J ND ug/L 05/09/11 10 ND ND 2.63 J ND ug/L 11/14/11 10 ND 1.67 J 2.82 J ND ug/L 05/08/12 10 10.6 ND 2.86 J ND ug/L 11/05/12 10 ND ND ND ND ug/L 05/13/13 10 ND ND ND ND ug/L 11/11/13 10 ND ND ND ND ug/L 05/12/14 10 ND ND 1.70 J ND ug/L 11/17/14 10 ND ND ND ND ug/L 05/12/15 10 ND ND 7.12 J ND ug/L 11/09/15 10 ND ND ND ND January 2016 Page 5 of 9 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Blanks Sampson County, North Carolina TABLE 8 Summary of Surface Water Monitoring Results Detected Constituents Sampson County Active MSW/C&D Landfill , Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date SWS Reporting Limit DownstreamUpstream SW-1 SW-4 SW-5 Lead ug/L 11/05/03 --dry ND --ND SW Standard = 25 ug/L*ug/L 05/25/04 10 dry ND --ND ug/L 05/16/05 10 dry ND --ND ug/L 11/25/05 10 dry ND --ND ug/L 05/24/06 10 dry ND --ND ug/L 11/20/06 10 dry ND --ND ug/L 05/22/07 10 dry ND --ND ug/L 11/15/07 10 ND ND dry ND ug/L 05/28/08 10 2.0 J 13.3 ND ND ug/L 11/17/08 10 dry ND ND ND ug/L 05/26/09 10 ND 2.0 J 1.7 J ND ug/L 11/11/09 10 1.99 J 2.84 J ND ND ug/L 05/26/10 10 ND 2.47 J 2.40 J ND ug/L 11/15/10 10 2.61 J ND 6.28 J ND ug/L 05/09/11 10 3.82 J ND 8.16 J ND ug/L 11/14/11 10 ND ND ND ND ug/L 05/08/12 10 42.6 ND 2.49 J ND ug/L 11/05/12 10 1.99 J 2.01 J 2.12 J ND ug/L 05/13/13 10 ND ND ND ND ug/L 11/11/13 10 ND ND 2.24 J ND ug/L 05/12/14 10 2.15 J ND ND ND ug/L 11/17/14 10 ND ND ND ND ug/L 05/12/15 10 ND ND 5.01 J ND ug/L 11/09/15 10 ND ND ND ND Nickel ug/L 11/05/03 ----ND --ND SW Standard = 88 ug/L**ug/L 05/25/04 50 --ND --ND ug/L 05/16/05 50 --ND --ND ug/L 11/25/05 50 --ND --ND ug/L 05/24/06 50 --ND --ND ug/L 11/20/06 50 --ND --ND ug/L 05/22/07 50 dry 7.6 J --ND ug/L 11/15/07 50 ND 2.6 J dry ND ug/L 05/28/08 50 3.6 J 11.3 J 12.5 J ND ug/L 11/17/08 50 dry 6.7 B 9.0 B 3.2 J ug/L 05/26/09 50 2.1 B 4.5 J 3.7 J 0.7 J ug/L 11/11/09 50 ND 6.92 J ND ND ug/L 05/26/10 50 ND 2.28 J ND ND ug/L 11/15/10 50 ND ND 9.91 J ND ug/L 05/09/11 50 2.47 J 2.04 J 16.8 J ND ug/L 11/14/11 50 2.64 J 3.75 J 7.47 J ND ug/L 05/08/12 50 9.14 J 2.86 J 2.69 J ND ug/L 11/05/12 50 2.06 J 2.09 J 4.90 J ND ug/L 05/13/13 50 2.52 J ND 3.77 J ND ug/L 11/11/13 50 ND ND 4.66 J ND ug/L 05/12/14 50 ND ND 3.19 J ND ug/L 11/17/14 50 ND ND 4.34 J ND ug/L 05/12/15 50 3.02 J 2.55 J 20.7 J ND ug/L 11/09/15 50 ND 31.2 J 7.64 J ND January 2016 Page 6 of 9 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Blanks Sampson County, North Carolina TABLE 8 Summary of Surface Water Monitoring Results Detected Constituents Sampson County Active MSW/C&D Landfill , Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date SWS Reporting Limit DownstreamUpstream SW-1 SW-4 SW-5 Selenium ug/L 11/05/03 ----ND --ND SW Standard = 5 ug/L ug/L 05/25/04 20 --ND --ND ug/L 05/16/05 20 --ND --ND ug/L 11/25/05 20 --ND --ND ug/L 05/24/06 20 --ND --ND ug/L 11/20/06 20 --ND --ND ug/L 05/22/07 10 dry ND --ND ug/L 11/15/07 10 2.0 B ND dry 3.1 J ug/L 05/28/08 10 ND ND ND ND ug/L 11/17/08 10 dry ND ND ND ug/L 05/26/09 10 ND ND ND ND ug/L 11/11/09 10 ND ND ND ND ug/L 05/26/10 10 ND ND ND ND ug/L 11/15/10 10 ND ND ND ND ug/L 05/09/11 10 2.85 J ND ND ND ug/L 05/09/11 10 0.987 J ND ND ND ug/L 11/14/11 10 ND ND ND ND ug/L 05/08/12 10 ND ND ND 4.01 J ug/L 11/05/12 10 ND ND ND ND ug/L 05/13/13 10 ND ND ND ND ug/L 11/11/13 10 ND ND ND ND ug/L 05/12/14 10 ND ND ND ND ug/L 11/17/14 10 ND ND ND ND ug/L 05/12/15 10 ND ND ND ND ug/L 11/09/15 10 ND ND ND ND Silver ug/L 11/05/03 --dry ND --ND SW Standard = 0.06 ug/L*ug/L 05/25/04 10 dry ND --ND ug/L 05/16/05 10 dry ND --ND ug/L 11/25/05 10 dry ND --ND ug/L 05/24/06 10 dry ND --ND ug/L 11/20/06 10 dry ND --ND ug/L 05/22/07 10 dry ND --ND ug/L 11/15/07 10 ND ND dry ND ug/L 05/28/08 10 ND ND ND ND ug/L 11/17/08 10 dry ND 2.6 J ND ug/L 05/26/09 10 ND ND ND ND ug/L 11/11/09 10 ND ND ND ND ug/L 05/26/10 10 ND ND ND ND ug/L 11/15/10 10 ND ND ND ND ug/L 05/09/11 10 ND ND ND ND ug/L 11/14/11 10 ND ND ND ND ug/L 05/08/12 10 ND ND ND ND ug/L 11/05/12 10 ND ND ND ND ug/L 05/13/13 10 ND ND ND ND ug/L 11/11/13 10 ND ND ND ND ug/L 05/12/14 10 ND ND ND ND ug/L 11/17/14 10 ND ND ND ND ug/L 05/12/15 10 ND ND ND ND ug/L 11/09/15 10 ND ND 1.95 J ND January 2016 Page 7 of 9 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Blanks Sampson County, North Carolina TABLE 8 Summary of Surface Water Monitoring Results Detected Constituents Sampson County Active MSW/C&D Landfill , Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date SWS Reporting Limit DownstreamUpstream SW-1 SW-4 SW-5 Thallium ug/L 11/05/03 --dry ND --ND (No SW Standard)ug/L 05/25/04 10 dry ND --ND ug/L 05/16/05 10 dry ND --ND ug/L 11/25/05 10 dry ND --ND ug/L 05/24/06 10 dry ND --ND ug/L 11/20/06 10 dry ND --ND ug/L 05/22/07 5.5 dry ND --ND ug/L 11/15/07 5.5 ND ND dry -- ug/L 05/28/08 5.5 ND 0.064 J 0.043 J ND ug/L 11/17/08 5.5 dry ND ND ND ug/L 05/26/09 5.5 ND ND ND ND ug/L 11/11/09 5.5 ND ND ND ND ug/L 05/26/10 5.5 ND ND ND ND ug/L 11/15/10 5.5 ND ND ND ND ug/L 05/09/11 5.5 ND ND ND ND ug/L 11/14/11 5.5 ND ND ND ND ug/L 05/08/12 5.5 ND ND ND ND ug/L 11/05/12 5.5 ND ND ND ND ug/L 05/13/13 5.5 ND ND ND ND ug/L 11/11/13 5.5 ND ND ND ND ug/L 05/12/14 5.5 ND ND ND ND ug/L 11/17/14 5.5 ND ND ND ND ug/L 05/12/15 5.5 ND ND ND ND ug/L 11/09/15 5.5 ND ND ND ND Vanadium ug/L 11/05/03 --dry ND --ND (No SW Standard)ug/L 05/25/04 40 dry ND --ND ug/L 05/16/05 40 dry ND --ND ug/L 11/25/05 40 dry ND --ND ug/L 05/24/06 40 dry ND --ND ug/L 11/20/06 40 dry ND --ND ug/L 05/22/07 25 dry ND --ND ug/L 11/15/07 25 ND ND dry ND ug/L 05/28/08 25 1.7 B 42.8 ND 1.2 J ug/L 11/17/08 25 dry ND ND ND ug/L 05/26/09 25 0.7 J 1.1 J 1.2 J ND ug/L 11/11/09 25 1.74 J 1.61 J ND ND ug/L 05/26/10 25 ND 3.13 J ND ND ug/L 11/15/10 25 ND ND ND ND ug/L 05/09/11 25 ND ND ND ND ug/L 11/14/11 25 ND ND ND ND ug/L 05/08/12 25 12.9 J ND ND ND ug/L 11/05/12 25 ND ND ND ND ug/L 05/13/13 25 ND ND ND ND ug/L 11/11/13 25 ND ND ND ND ug/L 05/12/14 25 ND ND ND ND ug/L 11/17/14 25 ND 3.28 J ND ND ug/L 05/12/15 25 ND ND 4.12 J ND ug/L 11/09/15 25 ND ND 1.84 J ND January 2016 Page 8 of 9 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Blanks Sampson County, North Carolina TABLE 8 Summary of Surface Water Monitoring Results Detected Constituents Sampson County Active MSW/C&D Landfill , Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date SWS Reporting Limit DownstreamUpstream SW-1 SW-4 SW-5 Zinc ug/L 11/05/03 ----ND --ND SW Standard = 50 ug/L*ug/L 05/25/04 50 --ND --ND ug/L 05/16/05 50 --ND --ND ug/L 11/25/05 50 --ND --ND ug/L 05/24/06 50 --ND --ND ug/L 11/20/06 50 --ND --ND ug/L 05/22/07 10 dry 17.8 --ND ug/L 11/15/07 10 6.6 J 6.5 J dry ND ug/L 05/28/08 10 6.9 B 31.9 15.9 1.8 J ug/L 11/17/08 10 dry 9.7 B 24.2 4.6 J ug/L 05/26/09 10 ND 14.6 19.7 ND ug/L 11/11/09 10 16.0 31.3 22.4 ND ug/L 05/26/10 10 ND 42.0 5.72 J ND ug/L 11/15/10 10 ND ND 97.8 ND ug/L 12/21/10 10 ----98.1 -- ug/L 05/09/11 10 4.82 J 10.4 110 ND ug/L 11/14/11 10 4.35 J 10.6 36.8 ND ug/L 05/08/12 10 14.5 6.92 J 8.29 J ND ug/L 11/05/12 10 ND ND 24.6 ND ug/L 05/13/13 10 5.55 J 5.15 J 6.06 J ND ug/L 11/11/13 10 4.13 J 4.26 J 47.5 ND ug/L 05/12/14 10 ND ND 21.0 ND ug/L 11/17/14 10 4.51 J 7.67 J 5.23 J ND ug/L 05/12/15 10 ND 3.88 J 180 ND ug/L 11/09/15 10 4.18 J 77.2 62.8 ND Acetone ug/L 11/05/03 100 dry ND --ND SW Standard = 2 ug/L*ug/L 05/25/04 100 dry ND --ND ug/L 05/16/05 100 dry ND --ND ug/L 11/25/05 100 dry ND --ND ug/L 05/24/06 100 dry ND --ND ug/L 11/20/06 100 dry ND --ND ug/L 05/22/07 100 dry ND --6.6 J ug/L 11/15/07 100 ND ND dry -- ug/L 05/28/08 100 ND 5.6 B 7.1 B 2.9 J ug/L 11/17/08 100 dry 8.4 B 9.2 B 9.8 J ug/L 05/26/09 100 ND ND ND ND ug/L 11/11/09 100 ND ND ND ND ug/L 05/26/10 100 ND ND ND ND ug/L 11/15/10 100 ND ND 9.7 B 9.2 J ug/L 05/09/11 100 ND ND 3.9 J ND ug/L 11/14/11 100 ND ND ND ND ug/L 05/08/12 100 ND ND ND ND ug/L 11/05/12 100 ND ND ND ND ug/L 11/05/12 100 ND ND ND ND ug/L 05/13/13 100 ND ND ND ND ug/L 11/11/13 100 ND ND ND ND ug/L 05/12/14 100 ND ND ND ND ug/L 11/17/14 100 ND ND ND ND ug/L 05/12/15 100 ND ND 17 J ND ug/L 11/09/15 100 ND ND 23 J ND January 2016 Page 9 of 9 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Blanks Sampson County, North Carolina TABLE 8 Summary of Surface Water Monitoring Results Detected Constituents Sampson County Active MSW/C&D Landfill , Permit No. 82-02 Detected Monitoring Constituent/Parameter Reporting Units Sample Date SWS Reporting Limit DownstreamUpstream SW-1 SW-4 SW-5 Chloroform ug/L 11/05/03 5 --ND --ND (No SW Standard)ug/L 05/25/04 5 --ND --ND ug/L 05/16/05 5 --ND --ND ug/L 11/25/05 5 --ND --ND ug/L 05/24/06 5 --ND --ND ug/L 11/20/06 5 --ND --ND ug/L 05/22/07 5 dry ND --ND ug/L 11/15/07 5 ND 0.48 J dry ND ug/L 05/28/08 5 ND ND ND ND ug/L 11/17/08 5 dry ND ND ND ug/L 05/26/09 5 ND ND ND ND ug/L 11/11/09 5 ND ND ND ND ug/L 05/26/10 5 ND ND ND ND ug/L 11/15/10 5 ND ND ND ND ug/L 05/09/11 5 ND ND ND ND ug/L 11/14/11 5 ND ND ND ND ug/L 05/08/12 5 ND ND ND ND ug/L 11/05/12 5 ND ND ND ND ug/L 11/05/12 5 ND ND ND ND ug/L 05/13/13 5 ND ND ND ND ug/L 11/11/13 5 ND ND ND ND ug/L 05/12/14 5 ND ND ND ND ug/L 11/17/14 5 ND ND ND ND ug/L 05/12/15 5 ND ND ND ND ug/L 11/09/15 5 ND ND ND ND Tetrahydrofuran ug/L 05/08/12 ------ND ND ug/L 11/05/12 ------ND ND ug/L 05/13/13 ------ND -- ug/L 11/11/13 ------ND ND ug/L 05/12/14 -----ND ND ug/L 11/17/14 ------ND ND ug/L 05/12/15 ------ND ND ug/L 11/09/15 -----2.1 ND Notes:ug/L =micrograms per liter ND =Not detected at the stated reporting limit J =estimated value -- =no data Blanks =field, trip and/or method blanks Bold = Concentrations above applicable Surface Water Standards SWS Reporting Limit =NCPQL or lab-specific reporting limit prior to 2007 and NCSWSL starting on 1/18/07 dry = SW Standard = * =SW Standard = Action Level ** = 1) Surface Water Standards based on Class C Freshwater Aquatic Life stream classification for the Bearskin Swamp per 15A NCAC 2B. 3) Data prior to 2/28/07 provided by Richardson, Smith, Gardner and Associates. 4) SW-5 was added as a downstream sampling point for Phase 2 following the May 2007 sampling event. 5) Data in parentheses are from laboratory re-analysis. no sample collected because sampling point was dry Surface Water Standard Narrative Standard January 2016 Page 1 of 3 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx pH (field)S.U.05/24/06 --5.1 -- S.U.11/20/06 --4.4 -- S.U.05/23/07 dry 3.14 -- S.U.11/13/07 5.60 6.16 dry S.U.05/28/08 4.12 3.84 6.30 S.U.11/17/08 dry 4.03 6.23 S.U.05/26/09 4.34 4.20 6.67 S.U.11/11/09 3.18 3.44 5.80 S.U.05/26/10 4.35 4.23 5.54 S.U.11/15/10 4.26 4.06 3.90 (Verification)S.U.12/21/10 ----3.60 S.U.05/09/11 2.88 3.26 3.30 S.U.11/14/11 5.03 4.45 4.07 S.U.05/08/12 4.25 5.30 6.19 S.U.11/05/12 3.53 4.12 4.14 S.U.05/13/13 5.54 4.48 5.37 S.U.11/11/13 4.54 4.30 4.42 S.U.05/12/14 5.00 4.47 5.72 S.U.11/18/14 4.12 4.40 5.64 S.U.05/12/15 3.04 2.04 3.38 S.U.11/09/15 4.06 2.70 6.58 Specific Conductance (field)uS/cm 05/24/06 --23 -- uS/cm 11/20/06 --54 -- uS/cm 05/23/07 dry 111 -- uS/cm 11/13/07 177 109 dry uS/cm 05/28/08 59 119 672 uS/cm 11/17/08 dry 41 367 uS/cm 05/26/09 34 69 329 uS/cm 11/11/09 128 129 423 uS/cm 05/26/10 32 50 253 uS/cm 11/15/10 34 51 482 (Verification)uS/cm 12/21/10 ----567 uS/cm 05/09/11 40 53 531 uS/cm 11/14/11 35 62 443 uS/cm 05/08/12 34 114 431 uS/cm 11/05/12 27 44 253 uS/cm 05/13/13 36 38 420 uS/cm 11/11/13 69 88 317 uS/cm 05/12/14 53 64 479 uS/cm 11/18/14 40 49 605 uS/cm 05/12/15 35 35 668 uS/cm 11/09/15 47 359 591 Downstream SW-1 SW-4 SW-5 TABLE 9 Summary of Surface Water Field Parameters Sampson County Active MSW/C&D Landfill , Permit No. 82-02 Sampson County, North Carolina Detected Monitoring Constituent/Parameter Reporting Units Sample Date Upstream January 2016 Page 2 of 3 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Downstream SW-1 SW-4 SW-5 TABLE 9 Summary of Surface Water Field Parameters Sampson County Active MSW/C&D Landfill , Permit No. 82-02 Sampson County, North Carolina Detected Monitoring Constituent/Parameter Reporting Units Sample Date Upstream Temperature (field)Celsius 05/24/06 --16 -- Celsius 11/20/06 --13 -- Celsius 05/23/07 dry 17.27 -- Celsius 11/13/07 13.89 14.76 dry Celsius 05/28/08 16.67 17.02 17.25 Celsius 11/17/08 dry 10.74 11.24 Celsius 05/26/09 17.44 18.18 19.01 Celsius 11/11/09 15.24 15.22 14.93 Celsius 05/26/10 17.04 17.59 19.38 Celsius 11/15/10 14.62 17.20 10.93 (Verification)Celsius 12/21/10 ----4.10 Celsius 05/09/11 16.44 16.41 20.18 Celsius 11/14/11 16.50 16.67 18.69 Celsius 05/08/12 16.96 20.97 27.52 Celsius 11/05/12 10.60 10.56 7.88 Celsius 05/13/13 15.75 15.51 22.36 Celsius 11/11/13 12.8 12.8 10.1 Celsius 05/12/14 17.7 17.9 27.7 Celsius 11/18/14 11.2 10.9 9.3 Celsius 05/12/15 17.3 17.3 28.1 Celsius 11/09/15 16.8 16.3 17.7 Turbidity (field)NTU 05/23/07 dry ---- NTU 11/13/07 72.7 51.3 dry NTU 05/28/08 41.1 663 74.6 NTU 11/17/08 dry 0.85 5.53 NTU 05/26/09 25.7 10.3 14.3 NTU 11/11/09 8.38 62.9 11.3 NTU 05/26/10 2.95 7.60 34.9 NTU 11/15/10 4.38 33.8 21.0 (Verification)NTU 12/21/10 ----3.34 NTU 05/09/11 3.57 2.58 1.25 NTU 11/14/11 17.7 17.9 3.08 NTU 05/08/12 47.0 3.06 21.2 NTU 11/05/12 7.86 2.28 1.31 NTU 05/13/13 6.18 4.15 9.13 NTU 11/11/13 3.40 11.6 2.42 NTU 05/12/14 6.95 8.43 7.41 NTU 11/18/14 158 44.4 7.89 NTU 05/12/15 4.92 3.27 88.2 NTU 11/09/15 22.2 16.2 32.8 January 2016 Page 3 of 3 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Downstream SW-1 SW-4 SW-5 TABLE 9 Summary of Surface Water Field Parameters Sampson County Active MSW/C&D Landfill , Permit No. 82-02 Sampson County, North Carolina Detected Monitoring Constituent/Parameter Reporting Units Sample Date Upstream ORP (field)mV 05/23/07 dry 457 -- mV 11/13/07 242 280 dry mV 05/28/08 364 365 30 mV 11/17/08 dry 270.0 160.0 mV 05/26/09 197.1 237.8 71.7 mV 11/11/09 342.4 270.1 204.8 mV 05/26/10 246.9 219.5 148.2 mV 11/15/10 318.9 297.8 311.5 (Verification)mV 12/21/10 ----352.3 mV 05/09/11 272.7 272.3 210.9 mV 11/14/11 148.0 153.2 228.1 mV 05/08/12 160.3 143.7 125.6 mV 11/05/12 169.9 126.8 156.3 mV 05/13/13 134.5 155.8 88.8 mV 11/11/13 355.6 273.4 426.3 mV 05/12/14 358.8 314.4 287.5 mV 11/18/14 290.7 164.9 169.0 mV 05/12/15 282.5 351.2 253.7 mV 11/09/15 465.1 538.3 122.2 Dissolved Oxygen (field)mg/L 05/23/07 dry 0.7 -- mg/L 11/13/07 9.13 9.00 dry mg/L 05/28/08 8.16 7.91 6.18 mg/L 11/17/08 dry 9.40 6.74 mg/L 05/26/09 7.57 7.25 13.15 mg/L 11/11/09 5.91 8.22 5.86 mg/L 05/26/10 7.49 8.82 3.76 mg/L 11/15/10 10.95 9.73 13.69 (Verification)mg/L 12/21/10 ----14.46 mg/L 05/09/11 8.72 9.18 10.33 mg/L 11/14/11 7.67 7.18 8.09 mg/L 05/08/12 7.51 6.20 5.71 mg/L 11/05/12 9.31 7.40 8.44 mg/L 05/13/13 8.89 8.34 8.69 mg/L 11/11/13 9.77 8.48 9.26 mg/L 05/12/14 8.55 7.71 5.50 mg/L 11/18/14 10.74 9.44 10.12 mg/L 05/12/15 7.62 6.23 3.37 mg/L 11/09/15 6.88 8.57 5.60 Notes:mg/L =milligrams per liter S.U. =Standard Units NTU =Nephelometric Turbidity Units uS/cm =microsiemens per centimeter mV =millivolts -- =no data dry = no sample collected because sampling point was dry 1)SW-5 was added as a downstream sampling point for Phase 2 following the following the May 2007 sampling event. January 2016 Page 1 of 12 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Detected Monitoring Constituent/Parameter Units Sample Date SWS Reporting LimitAntimonyug/L 05/23/07 6 84.8 ND ug/L 11/15/07 6 11.0 ND ug/L 05/28/08 6 16.8 J ND ug/L 11/20/08 6 9.20 J ND ug/L 05/28/09 6 15.3 J ND ug/L 11/12/09 6 6.42 J 0.0730 J ug/L 05/27/10 6 9.61 J ND ug/L 11/15/10 6 11.5 J ND ug/L 05/12/11 6 8.95 J ND ug/L 11/17/11 6 8.09 J ND ug/L 05/10/12 6 10.4 J ND ug/L 11/09/12 6 2.66 J ND ug/L 05/15/13 6 ND ND ug/L 11/13/13 6 ND ND ug/L 05/14/14 6 26.5 J ND ug/L 11/19/14 6 23.0 ND ug/L 05/12/15 6 22.1 ND ug/L 11/12/15 6 26.8 ND Arsenic ug/L 05/24/06 10 25 ND ug/L 11/27/06 10 62 ND ug/L 05/23/07 10 ND 2.2 J ug/L 11/15/07 10 ND 2.4 J ug/L 05/28/08 10 ND 3.2 J ug/L 11/20/08 10 ND ND ug/L 05/28/09 10 89.5 J ND ug/L 11/12/09 10 41.2 ND ug/L 05/27/10 10 53.7 ND ug/L 11/15/10 10 31.0 ND ug/L 05/12/11 10 29.7 ND ug/L 11/17/11 10 51.1 J ND ug/L 05/10/12 10 78.5 ND ug/L 11/09/12 10 59.6 4.48 J ug/L 05/15/13 10 50.2 ND ug/L 11/13/13 10 103 ND ug/L 05/14/14 10 84.9 ND ug/L 11/19/14 10 122 ND ug/L 05/12/15 10 111 ND ug/L 11/12/15 10 138 ND Barium ug/L 05/23/07 100 46.5 J 0.30 J ug/L 11/15/07 100 33.8 J 0.20 J ug/L 05/28/08 100 98.0 J 0.60 J ug/L 11/20/08 100 178 ND ug/L 05/28/09 100 152 ND ug/L 11/12/09 100 66.9 J ND ug/L 05/27/10 100 177 ND ug/L 11/15/10 100 156 ND ug/L 05/12/11 100 49.6 J ND ug/L 11/17/11 100 241 ND ug/L 05/10/12 100 220 ND ug/L 11/09/12 100 72.4 J ND ug/L 05/15/13 100 256 ND ug/L 11/13/13 100 285 ND ug/L 05/14/14 100 243 ND ug/L 11/19/14 100 207 ND ug/L 05/12/15 100 305 ND ug/L 11/12/15 100 316 ND TABLE 10 Summary of Detected Leachate Parameters Sampson County Active MSW Landfill, Permit No. 82-02 Leachate Blanks January 2016 Page 2 of 12 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Detected Monitoring Constituent/Parameter Units Sample Date SWS Reporting Limit TABLE 10 Summary of Detected Leachate Parameters Sampson County Active MSW Landfill, Permit No. 82-02 Leachate Blanks Cadmium ug/L 05/24/06 10 76 ND ug/L 11/27/06 10 37 ND ug/L 05/23/07 1 ND ND ug/L 11/15/07 1 ND ND ug/L 05/28/08 1 ND 0.50 J ug/L 11/20/08 1 ND ND ug/L 05/28/09 1 0.90 J ND ug/L 11/12/09 1 ND ND ug/L 05/27/10 1 ND ND ug/L 11/15/10 1 ND ND ug/L 05/12/11 1 ND ND ug/L 11/17/11 1 ND ND ug/L 05/10/12 1 ND ND ug/L 11/09/12 1 ND ND ug/L 05/15/13 1 ND ND ug/L 11/13/13 1 ND ND ug/L 05/14/14 1 ND ND ug/L 11/19/14 1 ND ND ug/L 05/12/15 1 ND ND ug/L 11/12/15 1 ND ND Chromium ug/L 11/27/06 10 29 ND ug/L 05/23/07 10 ND ND ug/L 05/23/07 10 143 ND ug/L 11/15/07 10 ND ND ug/L 05/28/08 10 ND ND ug/L 11/20/08 10 47.0 J 4.9 J ug/L 05/28/09 10 171 ND ug/L 11/12/09 10 141 ND ug/L 05/27/10 10 121 ND ug/L 11/15/10 10 114 ND ug/L 05/12/11 10 103 ND ug/L 11/17/11 10 174 ND ug/L 05/10/12 10 233 ND ug/L 11/09/12 10 161 ND ug/L 05/15/13 10 250 ND ug/L 11/13/13 10 253 ND ug/L 05/14/14 10 230 ND ug/L 11/19/14 10 289 ND ug/L 05/12/15 10 287 1.82 J ug/L 11/12/15 10 300 ND Cobalt ug/L 05/24/06 10 89 ND ug/L 11/15/07 10 213 ND ug/L 05/28/08 10 181 1.0 J ug/L 11/20/08 10 158 ND ug/L 05/28/09 10 184 ND ug/L 11/12/09 10 83.5 ND ug/L 05/27/10 10 119 ND ug/L 11/15/10 10 65.5 ND ug/L 05/12/11 10 83.6 ND ug/L 11/17/11 10 69.9 J ND ug/L 05/10/12 10 143 ND ug/L 11/09/12 10 84.7 ND ug/L 05/15/13 10 108 ND ug/L 11/13/13 10 100 ND ug/L 05/14/14 10 95.7 ND ug/L 11/19/14 10 129 ND ug/L 05/12/15 10 125 ND ug/L 11/12/15 10 99.6 ND January 2016 Page 3 of 12 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Detected Monitoring Constituent/Parameter Units Sample Date SWS Reporting Limit TABLE 10 Summary of Detected Leachate Parameters Sampson County Active MSW Landfill, Permit No. 82-02 Leachate Blanks Copper ug/L 05/23/07 10 ND ND ug/L 11/15/07 10 ND ND ug/L 05/28/08 10 91.0 J ND ug/L 11/20/08 10 ND ND ug/L 05/28/09 10 ND 1.47 J ug/L 11/12/09 10 4.06 J ND ug/L 05/27/10 10 13.1 ND ug/L 11/15/10 10 ND ND ug/L 05/12/11 10 2.81 J ND ug/L 11/17/11 10 ND ND ug/L 05/10/12 10 9.97 J ND ug/L 11/09/12 10 ND ND ug/L 05/15/13 10 ND ND ug/L 11/13/13 10 31.9 J ND ug/L 05/14/14 10 212 ND ug/L 11/19/14 10 99.5 ND ug/L 05/12/15 10 4.28 J ND ug/L 11/12/15 10 14.0 ND Lead ug/L 05/23/07 10 ND ND ug/L 11/15/07 10 ND ND ug/L 05/29/08 10 ND ND ug/L 11/20/08 10 ND ND ug/L 05/28/09 10 16.0 J ND ug/L 11/12/09 10 ND ND ug/L 05/27/10 10 4.07 J ND ug/L 11/15/10 10 3.24 J ND ug/L 05/12/11 10 5.44 J ND ug/L 11/17/11 10 ND ND ug/L 05/10/12 10 15.9 J ND ug/L 11/09/12 10 17.2 J 2.36 J ug/L 05/15/13 10 ND ND ug/L 11/13/13 10 ND ND ug/L 05/14/14 10 14.3 J ND ug/L 11/19/14 10 10.9 J ND ug/L 05/12/15 10 6.87 J ND ug/L 11/12/15 10 14.3 ND Nickel ug/L 05/24/06 50 150 ND ug/L 05/23/07 50 158 ND ug/L 11/15/07 50 235 ND ug/L 05/28/08 50 255 ND ug/L 11/20/08 50 267 3.2 J ug/L 05/28/09 50 252 1.7 J ug/L 11/12/09 50 125 ND ug/L 05/27/10 50 203 ND ug/L 11/15/10 50 126 ND ug/L 05/12/11 50 172 ND ug/L 11/17/11 50 196 ND ug/L 05/10/12 50 300 ND ug/L 11/09/12 50 216 ND ug/L 05/15/13 50 318 ND ug/L 11/13/13 50 299 ND ug/L 05/14/14 50 268 ND ug/L 11/19/14 50 323 ND ug/L 05/12/15 50 270 1.89 J ug/L 11/12/15 50 289 ND January 2016 Page 4 of 12 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Detected Monitoring Constituent/Parameter Units Sample Date SWS Reporting Limit TABLE 10 Summary of Detected Leachate Parameters Sampson County Active MSW Landfill, Permit No. 82-02 Leachate Blanks Selenium ug/L 11/27/06 20 178 ND ug/L 05/23/07 10 ND ND ug/L 11/15/07 10 12.7 B 3.1 J ug/L 05/28/08 10 21.0 J 2.1 J ug/L 11/20/08 10 ND ND ug/L 05/28/09 10 ND ND ug/L 11/12/09 10 6.63 J ND ug/L 05/27/10 10 3.49 J ND ug/L 11/15/10 10 11.3 ND ug/L 05/12/11 10 ND ND ug/L 11/17/11 10 ND ND ug/L 05/10/12 10 15.9 J ND ug/L 11/09/12 10 ND ND ug/L 05/15/13 10 ND ND ug/L 11/13/13 10 ND ND ug/L 05/14/14 10 ND ND ug/L 11/19/14 10 ND ND ug/L 05/12/15 10 ND ND ug/L 11/12/15 10 ND ND Silver ug/L 05/23/07 10 ND ND ug/L 11/15/07 10 ND ND ug/L 05/28/08 10 28.0 J 2.9 J ug/L 11/20/08 10 ND ND ug/L 05/28/09 10 18.1 J ND ug/L 11/12/09 10 ND ND ug/L 05/27/10 10 ND ND ug/L 11/15/10 10 ND ND ug/L 05/12/11 10 2.86 J ND ug/L 11/17/11 10 ND ND ug/L 05/10/12 10 ND ND ug/L 11/09/12 10 ND ND ug/L 05/15/13 10 ND ND ug/L 11/13/13 10 ND ND ug/L 05/14/14 10 ND ND ug/L 11/19/14 10 ND ND ug/L 05/12/15 10 ND ND ug/L 11/12/15 10 ND ND Thallium ug/L 05/23/07 5.5 ND ND ug/L 11/15/07 5.5 ND ND ug/L 05/29/08 5.5 ND ND ug/L 11/20/08 5.5 ND ND ug/L 05/28/09 5.5 ND ND ug/L 11/12/09 5.5 ND ND ug/L 05/27/10 5.5 ND ND ug/L 11/15/10 5.5 ND ND ug/L 05/12/11 5.5 7.80 J ND ug/L 11/17/11 5.5 1.52 J ND ug/L 05/10/12 5.5 ND ND ug/L 11/09/12 5.5 ND ND ug/L 05/15/13 5.5 ND ND ug/L 11/13/13 5.5 ND ND ug/L 05/14/14 5.5 ND ND ug/L 11/19/14 5.5 ND ND ug/L 05/12/15 5.5 ND ND ug/L 11/12/15 5.5 ND ND January 2016 Page 5 of 12 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Detected Monitoring Constituent/Parameter Units Sample Date SWS Reporting Limit TABLE 10 Summary of Detected Leachate Parameters Sampson County Active MSW Landfill, Permit No. 82-02 Leachate Blanks Vanadium ug/L 05/24/06 40 54 ND ug/L 11/27/06 50 237 ND ug/L 05/23/07 25 54.5 ND ug/L 11/15/07 25 16.0 J ND ug/L 05/28/08 25 42.0 J 1.2 J ug/L 11/20/08 25 35.0 J ND ug/L 05/28/09 25 88.8 J ND ug/L 11/12/09 25 69.5 ND ug/L 05/27/10 25 65.9 ND ug/L 11/15/10 25 63.2 ND ug/L 05/12/11 25 49.5 ND ug/L 11/17/11 25 73.1 J ND ug/L 05/10/12 25 115 ND ug/L 11/09/12 25 83.4 J ND ug/L 05/15/13 25 127 ND ug/L 11/13/13 25 122 ND ug/L 05/14/14 25 105 ND ug/L 11/19/14 25 119 ND ug/L 05/12/15 25 123 ND ug/L 11/12/15 25 125 ND Zinc ug/L 05/24/06 50 409 ND ug/L 05/23/07 10 373 ND ug/L 11/15/07 10 705 ND ug/L 05/28/08 10 678 1.8 J ug/L 11/20/08 10 423 4.6 J ug/L 05/28/09 10 354 ND ug/L 11/12/09 10 270 ND ug/L 05/27/10 10 225 ND ug/L 11/15/10 10 383 ND ug/L 05/12/11 10 178 ND ug/L 11/17/11 10 228 ND ug/L 05/10/12 10 520 ND ug/L 11/09/12 10 204 ND ug/L 05/15/13 10 181 ND ug/L 11/13/13 10 219 ND ug/L 05/14/14 10 423 ND ug/L 11/19/14 10 232 ND ug/L 05/12/15 10 215 ND ug/L 11/12/15 10 160 ND Acetone ug/L 05/24/06 100 1610 ND ug/L 11/27/06 100 5300 ND ug/L 05/23/07 100 11000 6.6 J ug/L 11/15/07 100 33 J ND ug/L 05/28/08 100 1600 2.9 J ug/L 11/20/08 100 1500 9.8 ug/L 05/28/09 100 5200 ND ug/L 11/12/09 100 1000 ND ug/L 05/27/10 100 ND ND ug/L 11/15/10 100 5900 ND ug/L 05/12/11 100 ND ND ug/L 11/17/11 100 3100 ND ug/L 05/10/12 100 93 J ND ug/L 11/09/12 100 44 J ND ug/L 05/15/13 100 ND ND ug/L 11/13/13 100 2700 ND ug/L 05/14/14 100 1400 ND ug/L 11/19/14 100 ND ND ug/L 05/12/15 100 2100 ND ug/L 11/12/15 100 24 J ND January 2016 Page 6 of 12 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Detected Monitoring Constituent/Parameter Units Sample Date SWS Reporting Limit TABLE 10 Summary of Detected Leachate Parameters Sampson County Active MSW Landfill, Permit No. 82-02 Leachate Blanks Benzene ug/L 11/27/06 5 10.6 ND ug/L 05/23/07 1 ND ND ug/L 11/15/07 1 ND ND ug/L 05/28/08 1 ND ND ug/L 11/20/08 1 4.6 J ND ug/L 05/28/09 1 ND ND ug/L 11/12/09 1 ND ND ug/L 05/27/10 1 ND ND ug/L 11/15/10 1 ND ND ug/L 05/12/11 1 ND ND ug/L 11/17/11 1 ND ND ug/L 05/10/12 1 2.2 J ND ug/L 11/09/12 1 ND ND ug/L 05/15/13 1 6.2 ND ug/L 11/13/13 1 ND ND ug/L 05/14/14 1 ND ND ug/L 11/19/14 1 ND ND ug/L 05/12/15 1 ND ND ug/L 11/12/15 1 4.9 J ND 1,4-Dichlorobenzene ug/L 05/23/07 1 ND ND ug/L 11/15/07 1 ND ND ug/L 05/29/08 1 ND ND ug/L 11/20/08 1 5.5 J ND ug/L 05/28/09 1 ND ND ug/L 11/12/09 1 ND ND ug/L 05/27/10 1 ND ND ug/L 11/15/10 1 ND ND ug/L 05/12/11 1 ND ND ug/L 11/17/11 1 9.7 J ND ug/L 05/10/12 1 4.3 J ND ug/L 11/09/12 1 3.6 J ND ug/L 05/15/13 1 ND ND ug/L 11/13/13 1 ND ND ug/L 05/14/14 1 ND ND ug/L 11/19/14 1 ND ND ug/L 05/12/15 1 4.2 J ND ug/L 11/12/15 1 7.5 J ND 1,2-Dichloroethane ug/L 11/27/06 5 6.6 ND ug/L 05/23/07 1 ND ND ug/L 11/15/07 1 ND ND ug/L 05/28/08 1 ND ND ug/L 11/20/08 1 ND ND ug/L 05/28/09 1 ND ND ug/L 11/12/09 1 ND ND ug/L 05/27/10 1 ND ND ug/L 11/15/10 1 ND ND ug/L 05/12/11 1 ND ND ug/L 11/17/11 1 ND ND ug/L 05/10/12 1 ND ND ug/L 11/09/12 1 ND ND ug/L 05/15/13 1 ND ND ug/L 11/13/13 1 ND ND ug/L 05/14/14 1 ND ND ug/L 11/19/14 1 ND ND ug/L 05/12/15 1 9.7 J ND ug/L 11/12/15 1 ND ND January 2016 Page 7 of 12 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Detected Monitoring Constituent/Parameter Units Sample Date SWS Reporting Limit TABLE 10 Summary of Detected Leachate Parameters Sampson County Active MSW Landfill, Permit No. 82-02 Leachate Blanks cis-1,2-Dichloroethene ug/L 11/27/06 5 5.4 ND ug/L 05/23/07 5 ND ND ug/L 11/15/07 5 ND ND ug/L 05/28/08 5 ND ND ug/L 11/20/08 5 ND ND ug/L 05/28/09 5 ND ND ug/L 11/12/09 5 ND ND ug/L 05/27/10 5 ND ND ug/L 11/15/10 5 ND ND ug/L 05/12/11 5 ND ND ug/L 11/17/11 5 ND ND ug/L 05/10/12 5 ND ND ug/L 11/09/12 5 ND ND ug/L 05/15/13 5 ND ND ug/L 11/13/13 5 ND ND ug/L 05/14/14 5 ND ND ug/L 11/19/14 5 ND ND ug/L 05/12/15 5 ND ND ug/L 11/12/15 5 4.8 J ND Ethylbenzene ug/L 05/24/06 5 6.1 ND ug/L 11/27/06 5 18.4 ND ug/L 05/23/07 1 ND ND ug/L 11/15/07 1 ND ND ug/L 05/28/08 1 ND ND ug/L 11/20/08 1 12 ND ug/L 05/28/09 1 ND ND ug/L 11/12/09 1 8.6 J ND ug/L 05/27/10 1 ND ND ug/L 11/15/10 1 22 J ND ug/L 05/12/11 1 ND ND ug/L 11/17/11 1 13 ND ug/L 05/10/12 1 7.3 ND ug/L 11/09/12 1 5.2 ND ug/L 05/15/13 1 7.2 ND ug/L 11/13/13 1 ND ND ug/L 05/14/14 1 4.0 J ND ug/L 11/19/14 1 ND ND ug/L 05/12/15 1 ND ND ug/L 11/12/15 1 16 ND 2-Hexanone ug/L 05/23/07 50 ND ND ug/L 11/15/07 50 ND ND ug/L 05/29/08 50 ND ND ug/L 11/20/08 50 ND ND ug/L 05/28/09 50 ND ND ug/L 11/12/09 50 ND ND ug/L 05/27/10 50 ND ND ug/L 11/15/10 50 ND ND ug/L 05/12/11 50 ND ND ug/L 11/17/11 50 ND ND ug/L 05/10/12 50 6.7 J ND ug/L 11/09/12 50 ND ND ug/L 05/15/13 50 ND ND ug/L 11/13/13 50 ND ND ug/L 05/14/14 50 ND ND ug/L 11/19/14 50 ND ND ug/L 05/12/15 50 ND ND ug/L 11/12/15 50 26 J ND January 2016 Page 8 of 12 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Detected Monitoring Constituent/Parameter Units Sample Date SWS Reporting Limit TABLE 10 Summary of Detected Leachate Parameters Sampson County Active MSW Landfill, Permit No. 82-02 Leachate Blanks 2-Butanone ug/L 05/24/06 100 2100 ND ug/L 11/27/06 100 8590 ND ug/L 05/23/07 100 13000 ND ug/L 11/15/07 100 ND ND ug/L 05/28/08 100 1500 ND ug/L 11/20/08 100 2500 ND ug/L 05/28/09 100 8300 ND ug/L 11/12/09 100 800 ND ug/L 05/27/10 100 ND ND ug/L 11/15/10 100 11000 ND ug/L 05/12/11 100 ND ND ug/L 11/17/11 100 3200 ND ug/L 05/10/12 100 ND ND ug/L 11/09/12 100 ND ND ug/L 05/15/13 100 48 J ND ug/L 11/13/13 100 2700 ND ug/L 05/14/14 100 1300 ND ug/L 11/19/14 100 ND ND ug/L 05/12/15 100 3100 ND ug/L 11/12/2015 100 78 J ND 4-Methyl-2-pentanone ug/L 11/27/06 100 121 ND ug/L 05/23/07 100 150 ND ug/L 11/15/07 100 ND ND ug/L 05/28/08 100 ND ND ug/L 11/20/08 100 50 J ND ug/L 05/28/09 100 ND ND ug/L 11/12/09 100 ND ND ug/L 05/27/10 100 ND ND ug/L 11/15/10 100 99 J ND ug/L 05/12/11 100 ND ND ug/L 11/17/11 100 30 J ND ug/L 05/10/12 100 42 J ND ug/L 11/09/12 100 23 J ND ug/L 05/15/13 100 56 J ND ug/L 11/13/13 100 29 J ND ug/L 05/14/14 100 31 J ND ug/L 11/19/14 100 ND ND ug/L 05/12/15 100 62 J ND ug/L 11/12/15 100 150 ND Toluene ug/L 11/27/06 5 95.4 ND ug/L 05/23/07 1 20 ND ug/L 11/15/07 1 ND ND ug/L 05/28/08 1 ND ND ug/L 11/20/08 1 19 ND ug/L 05/28/09 1 27 J ND ug/L 11/12/09 1 12 J ND ug/L 05/27/10 1 ND ND ug/L 11/15/10 1 46 J ND ug/L 05/12/11 1 ND ND ug/L 11/17/11 1 16 ND ug/L 05/10/12 1 12 ND ug/L 11/09/12 1 13 ND ug/L 05/15/13 1 14 ND ug/L 11/13/13 1 11 J ND ug/L 05/14/14 1 6.6 J ND ug/L 11/19/14 1 6.3 J ND ug/L 05/12/15 1 17 ND ug/L 11/12/15 1 32 ND January 2016 Page 9 of 12 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Detected Monitoring Constituent/Parameter Units Sample Date SWS Reporting Limit TABLE 10 Summary of Detected Leachate Parameters Sampson County Active MSW Landfill, Permit No. 82-02 Leachate Blanks Trichloroethene ug/L 05/23/07 1 ND ND ug/L 11/15/07 1 9.6 ND ug/L 05/28/08 1 ND ND ug/L 11/20/08 1 ND ND ug/L 05/28/09 1 ND ND ug/L 11/12/09 1 ND ND ug/L 05/27/10 1 ND ND ug/L 11/15/10 1 ND ND ug/L 05/12/11 1 ND ND ug/L 11/17/11 1 ND ND ug/L 05/10/12 1 ND ND ug/L 11/09/12 1 ND ND ug/L 05/15/13 1 ND ND ug/L 11/13/13 1 ND ND ug/L 05/14/14 1 ND ND ug/L 11/19/14 1 ND ND ug/L 05/12/15 1 ND ND ug/L 11/12/15 1 ND ND Xylenes (Total)ug/L 05/24/06 5 8.9 ND ug/L 11/27/06 5 38.7 ND ug/L 05/23/07 4 ND ND ug/L 11/15/07 5 ND ND ug/L 05/28/08 5 ND ND ug/L 11/20/08 5 26 ND ug/L 05/28/09 5 22 J ND ug/L 11/12/09 5 12 J ND ug/L 05/27/10 5 ND ND ug/L 11/15/10 5 28 J ND ug/L 05/12/11 5 ND ND ug/L 11/17/11 5 32 ND ug/L 05/10/12 5 18 ND ug/L 11/09/12 5 12 J ND ug/L 05/15/13 5 15 ND ug/L 11/13/13 5 ND ND ug/L 05/14/14 5 5.7 J ND ug/L 11/19/14 5 4.6 J ND ug/L 05/12/15 5 ND ND ug/L 11/12/15 5 33 ND Nitrate as N mg/L 05/24/06 --0.14 ND mg/L 11/27/06 --0.18 ND mg/L 05/23/07 --0.51 ND mg/L 11/15/07 10 ND -- mg/L 05/28/08 10 ND ND mg/L 11/20/08 10 ND ND mg/L 05/28/09 10 ND ND mg/L 11/12/09 10 ND -- mg/L 05/27/10 10 ND ND mg/L 11/15/10 10 ND - mg/L 05/12/11 10 ND ND mg/L 11/17/11 10 ND - mg/L 05/10/12 10 ND -- mg/L 11/09/12 10 ND - mg/L 05/15/13 10 0.8 J ND mg/L 11/13/13 10 ND - mg/L 05/14/14 10 ND ND mg/L 11/19/14 10 ND ND mg/L 05/12/15 10 0.18 J ND mg/L 11/12/15 10 ND ND January 2016 Page 10 of 12 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Detected Monitoring Constituent/Parameter Units Sample Date SWS Reporting Limit TABLE 10 Summary of Detected Leachate Parameters Sampson County Active MSW Landfill, Permit No. 82-02 Leachate Blanks Sulfate as SO4 mg/L 05/24/06 --10.9 ND mg/L 11/27/06 5 ND ND mg/L 05/23/07 250 140 2.5 J mg/L 11/15/07 250 26 J ND mg/L 05/28/08 250 19 J ND mg/L 11/20/08 250 5.2 J ND mg/L 05/28/09 250 2.7 J ND mg/L 11/12/09 250 9.5 J ND mg/L 05/27/10 250 25 J ND mg/L 11/15/10 250 6.6 J ND mg/L 05/12/11 250 12 J ND mg/L 11/17/11 250 ND ND mg/L 05/10/12 250 160 J ND mg/L 11/09/12 250 7.6 J ND mg/L 05/15/13 250 8.7 J ND mg/L 11/13/13 250 4.3 J ND mg/L 05/14/14 250 280 ND mg/L 11/19/14 250 32 J ND mg/L 05/12/15 250 5.9 J ND mg/L 11/12/15 250 ND ND Biochemical Oxygen Demand mg/L 05/24/06 --920 -- mg/L 11/27/06 --1849 -- mg/L 05/23/07 --2500 -- mg/L 11/15/07 --540 ND mg/L 05/28/08 --1700 ND mg/L 11/20/08 -->230 ND mg/L 05/28/09 --560 ND mg/L 11/12/09 --340 ND mg/L 05/27/10 --ND ND mg/L 11/15/10 --> 2300 ND mg/L 05/12/11 --55 ND mg/L 11/17/11 --390 ND mg/L 05/10/12 --240 ND mg/L 11/09/12 --230 ND mg/L 05/15/13 --630 ND mg/L 11/13/13 -->750 ND mg/L 05/14/14 --420 ND mg/L 11/19/14 --290 ND mg/L 05/12/15 --420 ND mg/L 11/12/15 --650 ND Chemical Oxygen Demand mg/L 05/24/06 --3901 -- mg/L 11/27/06 --2685 -- mg/L 05/23/07 --9000 -- mg/L 11/15/07 --4800 ND mg/L 05/28/08 --4600 ND mg/L 11/20/08 --4300 ND mg/L 05/28/09 --5500 ND mg/L 11/12/09 --5000 ND mg/L 05/27/10 --2700 ND mg/L 11/15/10 --6300 ND mg/L 05/12/11 --2700 ND mg/L 11/17/11 --4400 ND mg/L 05/10/12 --5100 ND mg/L 11/09/12 --3500 ND mg/L 05/15/13 --5900 ND mg/L 11/13/13 --5700 ND mg/L 05/14/14 --5000 ND mg/L 11/19/14 --5900 ND mg/L 05/12/15 --5900 ND mg/L 11/12/15 --5500 ND January 2016 Page 11 of 12 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Detected Monitoring Constituent/Parameter Units Sample Date SWS Reporting Limit TABLE 10 Summary of Detected Leachate Parameters Sampson County Active MSW Landfill, Permit No. 82-02 Leachate Blanks Phosphorus mg/L 05/24/06 --2.56 ND mg/L 11/27/06 --0.61 ND mg/L 05/23/07 --1.9 ND mg/L 11/15/07 --3.0 ND mg/L 05/28/08 --2.6 ND mg/L 11/20/08 --3.4 ND mg/L 05/28/09 --3.9 ND mg/L 11/12/09 --5.0 ND mg/L 05/27/10 --2.5 ND mg/L 11/15/10 --3.1 ND mg/L 05/12/11 --1.3 ND mg/L 11/17/11 --3.8 ND mg/L 05/10/12 --4.2 ND mg/L 11/09/12 --2.6 ND mg/L 05/15/13 --5.1 ND mg/L 11/13/13 --5.6 ND mg/L 05/14/14 --5.4 ND mg/L 11/19/14 --7.0 ND mg/L 05/12/15 --9.0 ND mg/L 11/12/15 --8.2 ND pH (field)S.U.05/24/06 --7.2 -- S.U.11/20/06 --7.0 -- S.U.05/23/07 --7.80 -- S.U.11/15/07 --8.38 -- S.U.05/28/08 --8.08 -- S.U.11/20/08 --7.97 -- S.U.05/28/09 --7.82 -- S.U.11/12/09 --8.08 -- S.U.05/26/10 --8.30 -- S.U.11/15/10 --7.89 -- S.U.05/09/11 --8.35 -- S.U.11/17/11 --7.82 -- S.U.05/10/12 --8.39 -- S.U.11/09/12 --8.06 -- S.U.05/15/13 --7.91 -- S.U.11/13/13 --8.16 -- S.U.05/14/14 --8.34 -- S.U.11/19/14 --9.19 -- S.U.05/12/15 --8.04 -- S.U.11/12/15 --6.77 -- Specific Conductance (field)µS/cm 05/24/06 --9980 -- µS/cm 11/20/06 --4280 -- µS/cm 05/23/07 --2240 -- µS/cm 11/15/07 --2210 -- µS/cm 05/28/08 --1080 -- µS/cm 11/20/08 --2050 -- µS/cm 05/28/09 --2216 -- µS/cm 11/12/09 --1101 -- µS/cm 05/26/10 --1847 -- µS/cm 11/15/10 --1854 -- µS/cm 05/09/11 --1824 -- uS/cm 11/17/11 --1950 -- uS/cm 05/10/12 --1917 -- µS/cm 11/09/12 --1357 -- µS/cm 05/15/13 --25990 -- uS/cm 11/13/13 --18021 -- µS/cm 05/14/14 --21715 -- µS/cm 11/19/14 --20440 -- µS/cm 05/12/15 --22660 -- uS/cm 11/12/15 --25521 -- January 2016 Page 12 of 12 Project No. 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Tables\Sampson County Active MSW Landfill November 2015 (Autosaved).xlsx Detected Monitoring Constituent/Parameter Units Sample Date SWS Reporting Limit TABLE 10 Summary of Detected Leachate Parameters Sampson County Active MSW Landfill, Permit No. 82-02 Leachate Blanks Temperature (field)°C 05/24/06 --23 -- °C 11/20/06 --19 -- °C 05/23/07 --28.83 -- °C 11/15/07 --14.55 -- °C 05/28/08 --24.78 -- °C 11/20/08 --18.97 -- °C 05/28/09 --25.44 -- °C 11/12/09 --15.56 -- °C 05/26/10 --34.88 -- °C 11/15/10 --19.94 -- °C 05/09/11 --18.24 -- °C 11/17/11 --23.42 -- °C 05/10/12 --17.99 -- °C 11/09/12 --15.21 -- °C 05/15/13 --28.72 -- °C 11/13/13 --13.7 -- °C 05/14/14 --30.4 -- °C 11/19/14 --13.4 -- °C 05/12/15 --33.9 -- °C 11/12/15 --18.6 -- Turbidity (field)NTU 05/23/07 --206 ND NTU 11/15/07 --421 ND NTU 05/28/08 --963 -- NTU 11/20/08 --52.7 -- NTU 05/28/09 --NM -- NTU 11/12/09 --40.1 -- NTU 05/26/10 ------ NTU 11/15/10 ------ NTU 05/09/11 ------ NTU 11/17/11 ------ NTU 05/10/12 -->1000 -- NTU 11/09/12 --51.7 -- NTU 05/15/13 --98.2 -- NTU 11/13/13 --86.6 -- NTU 05/14/14 --278 -- NTU 11/09/14 --357 -- NTU 05/12/15 --66.9 -- NTU 11/12/15 --189 -- Notes: mg/L =milligrams per liter ug/L =micrograms per liter S.U. =Standard Units ND =Not detected at the stated reporting limit NM =Not Measured J =Estimated value µS/cm=microsiemens per centimeter NTU =Nephelometric Turbidity Units °C =degrees Celsius -- =no data available or no limit established Blanks =field, trip and/or method blanks SWS Reporting Limit =NCPQL or lab-specific reporting limit prior to 2007 and NCSWSL starting on 01/18/07 1) Data prior to 2/28/07 provided by Richardson, Smith, Gardner and Associates. 2) The following dilutions were noted for theNovember 2015 event: BOD (10x), Phosphorus (5x), and VOCs (10x) DRAWING 1 4 0 13 5 1 4 0 130 1 5 0 1 4 5 C&D DISPOSAL AREA EXISTING MSW DISPOSAL AREA IF T H I S M E A S U R E M E N T D O E S N O T M A T C H W H A T I S S H O W N , T H E S H E E T S I Z E H A S B E E N M O D I F I E D F R O M : A N S I D CONSULTANT DESIGN PREPARED REVIEW APPROVED YYYY-MM-DD TITLE PROJECT No.Rev. PROJECT CLIENT Pa t h : \ \ g r e e n s b o r o \ C A D \ _ 2 0 0 7 \ 0 7 3 9 6 0 3 7 - W I - S a m p s o n A c t i v e \ P R O D U C T I O N \ _ A - 2 0 1 5 W Q M R E P O R T M A P S \ | F i l e N a m e : 0 7 3 9 6 0 3 7 1 5 A 0 0 2 . d w g 0 1 i n 0739603715 PHASE 100 DRAWING 10 2015-12-17 BSD ACS DYR RPK SAMPSON COUNTY, LLC ACTIVE LANDFILLS, PERMIT NO. 82-02 SAMPSON COUNTY, NC WASTE INDUSTRIES USA, INC. GROUNDWATER CONTOUR MAP NOVEMBER 9, 2015 EXISTING 10-FOOT GROUND SURFACE CONTOUR EXISTING 2-FOOT GROUND SURFACE CONTOUR APPROXIMATE LIMITS OF WASTE PROPERTY LINE EXISTING ROAD GROUNDWATER ELEVATION 5 FT CONTOURS GROUNDWATER FLOW ARROW MONITORING WELL AND IDENTIFICATION LANDFILL GAS MONITORING PROBE GRAVITY GROUNDWATER INTERCEPT LOCATION SURFACE WATER MONITORING POINT NOT AVAILABLE LEGEND NOTES 140 1. TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET 2. GROUNDWATER SURFACE CONTOUR INTERVAL = 5 FEET 3. GROUNDWATER ELEVATIONS MEASURED ON NOVEMBER 9, 2015. 4. GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION BETWEEN AND EXTRAPOLATION FROM KNOWN DATA, TOPOGRAPHIC CONTOURS, AND KNOWN FIELD CONDITIONS. THEREFORE, GROUNDWATER CONTOURS MAY NOT REFLECT ACTUAL CONDITIONS. 5. GROUNDWATER CONTOUR LINES SHOW THE WATER TABLE SHAPE AND ELEVATION. THESE CONTOURS ARE INFERRED LINES FOLLOWING THE GROUNDWATER SURFACE AT A CONSTANT ELEVATION ABOVE SEA LEVEL. THE GROUNDWATER FLOW DIRECTION IS GENERALLY PERPENDICULAR TO THE GROUNDWATER SURFACE CONTOURS, SIMILAR TO THE RELATIONSHIP BETWEEN SURFACE WATER FLOW AND TOPOGRAPHIC CONTOURS. 6. SW-1S IS THE UPSTREAM SAMPLING POINT FOR THE CLOSED LANDFILL ON THE SOUTHERN PROPERTY (PERMIT 82-01). SW-1 IS LOCATED OFF THE MAPPED AREA TO THE NORTHEAST AS SHOWN. 7. MONITORING WELLS MW-1N, MW-2N, MW-3N AND MW-4N ARE FOR THE C&D LANDFILL. 8. MW-107D IS NOT PART OF THE APPROVED MONITORING NETWORK AND THE GROUNDWATER ELEVATIONS WAS NOT USED IN THE CONSTRUCTION OF THE CONTOUR MAP. 9. BASE MAP PROVIDED BY G.N. RICHARDSON & ASSOCIATES, INC. TOPOGRAPHY PROVIDED FROM AERIAL SURVEYS PREPARED BY GEODATA CORP, PHOTOGRAPHY DATES JANUARY 8, 2015 AND MARCH 10, 2014. 10. COORDINATE SYSTEM IS N.C. STATE PLANE GRID. VICINITY MAP 1:121,500 SITE APPENDIX A GROUNDWATER, SURFACE WATER, AND LEACHATE SAMPLING LOGS APPENDIX B NOVEMBER 2015 GROUNDWATER, SURFACE WATER, AND LEACHATE CERTIFICATE- OF-ANALYSIS, CHAIN-OF-CUSTODY FORMS AND LABORATORY DATA REVIEWS Page 1 of 53 Page 2 of 53 Page 3 of 53 Page 4 of 53 Page 5 of 53 Page 6 of 53 Page 7 of 53 Page 8 of 53 Page 9 of 53 Page 10 of 53 Page 11 of 53 Page 12 of 53 Page 13 of 53 Page 14 of 53 Page 15 of 53 Page 16 of 53 Page 17 of 53 Page 18 of 53 Page 19 of 53 Page 20 of 53 Page 21 of 53 Page 22 of 53 Page 23 of 53 Page 24 of 53 Page 25 of 53 Page 26 of 53 Page 27 of 53 Page 28 of 53 Page 29 of 53 Page 30 of 53 Page 31 of 53 Page 32 of 53 Page 33 of 53 Page 34 of 53 Page 35 of 53 Page 36 of 53 Page 37 of 53 Page 38 of 53 Page 39 of 53 Page 40 of 53 Page 41 of 53 Page 42 of 53 Page 43 of 53 Page 44 of 53 Page 45 of 53 Page 46 of 53 Page 47 of 53 Page 48 of 53 Page 49 of 53 Page 50 of 53 Page 51 of 53 Page 52 of 53 Page 53 of 53 Page 1 of 1 GOLDER ASSOCIATES NC, INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 1 of 3 Project Name: Sampson County Active MSW Landfill Project Reference Number: 073-9603715.100 Sampling Event Date: November 9-10, 2015 Review Date: November 25, 2015 Initials: TM Report #: C513742 Person(s) performing the review are to initial each item on this form as acknowledgement of data acceptance, or as acknowledgement of a review issue. In the case of the latter, a brief explanation should follow the applicable item. Golder Associates Inc. has reviewed the laboratory certificates of analysis, chain-of-custody form, and laboratory provided sample group quality assurance and quality control data for the above referenced sample group to identify potential bias or inaccuracy, in general accordance with the following United States Environmental Protection Agency documents: • Region III Modifications to Functional Guidelines for Organic Data Review Multi-Media, Multi-Concentration, September 1994; • Region III Modifications to the Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, April 1993; and • Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, July 1998. COMPLIANCE ANALYTE LIST(S) (check all that apply) NC Closed Facility/C & D List X NC Appendix I NC Appendix I + Detects NC Appendix II NC Subtitle D Leachate List Other: MW-100B sampled for NC Appendix I metals only. 1.0 CHAIN OF CUSTODY (COC) REVIEW TM COC was properly signed by all parties. TM Correct project name and number are on the form. TM Sample receipt condition at laboratory was acceptable. TM Each sample and blank submitted for analysis appears in the report. 2.0 SAMPLE HOLDING TIMES TM Holding times for extraction and/or analysis were met for each analytical method (see below for reference). GOLDER ASSOCIATES NC, INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 2 of 4 Review Criteria Method Analytes Holding Time SW-846 Method 8260 and 8011 VOCs 14 days SW-846 Methods 8270, 8080, 8081, 8082, and 8151 SVOCs, PCBs, pesticides and herbicides 7 days for extraction, 40 days from extraction for analysis SW-846 Methods 6000 and 7000 Series Metals except mercury 6 months (no temperature requirements) SW-846 Method 7470 Mercury 28 days SW-846 Method 376.1 Sulfide 7 days SW-846 Method 9010 Cyanide 14 days EPA Method 300 Nitrate/Sulfate 48 hours/28 days EPA Method 405.1 BOD 48 hours EPA Method 410.4 COD 28 days EPA Method 365.4 Phosphorous 28 days 3.0 LABORATORY QUALITY CONTROL REVIEW TM Laboratory analyzed at least one internal blank for each method, where applicable. TM Laboratory blank is interference-free. TM Surrogate recoveries are provided for each analytical method, where applicable. TM Surrogate recoveries for each method are within the acceptable limits (i.e., at least 50% of the surrogates were within range). • The 8260B surrogate spike recovery of Dibromofluoromethane exceeded acceptance criteria for one of the Method Blanks and sample MW-103A (MS/MSD). These samples were approved based on acceptable recovery of the other surrogate standards. TM MS/MSD/LCS data results are provided for each analytical method. TM MS/MSD/LCS recoveries for each method are within the acceptable limits (i.e., at least 1 of the 3 were within range). • The spike recovery of Trichloroethene exhibited a high bias for the 8260B LCS samples; however, this analyte was not detected in the associated samples, reducing the impact of the deviation. The spike recoveries of 1,1-Dichloroethene, Toluene, and Trichloroethene were outside of control limits for the 8260B MS and or MSD samples. The QC batches were approved based on acceptable LCS recovery of these analytes. 4.0 ANALYTE LISTS/METHODS TM The proper number of constituents are present for each analyte list as identified above (including detects where applicable). TM Proper EPA SW-846 analytical methods were used for analysis. 5.0 DATA REPORTING TM All analytical reporting associated with the event was performed by the contracted lab. TM Trip, field and/or equipment, and laboratory blank results have all been reported. All detects for blanks are listed below by constituent. All laboratory method blanks, if any, have been ‘flagged’ with a ‘B’ where detected in other samples as appropriate and a laboratory narrative was provided. If the sample was flagged by the laboratory and is not within 5X of the concentration in the blank (or 10X for commonly detected laboratory contaminants-acetone, methylene chloride and phthalates), list below with explanation if flags should be removed. If flags need to be added for samples, also list below. GOLDER ASSOCIATES NC, INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 3 of 4 TM It is clear from the laboratory report that samples have or have not been diluted during analysis, and if the samples have been diluted, the result is reported as a multiple of the dilution (e.g., a sample diluted 10x resulting in an analytical detection of 1.0 should be reported as 10). Those that have been diluted are listed below with the dilution factor. • MW-108: Thallium 10x TM The report provides the reporting limit for each constituent. TM The results were reported at or below their proper reporting limits (e.g., NC Solid Waste Section Approved QLs). Those that are not reported correctly are listed below (by constituent) with the proper reporting limit listed beside them. State if the reporting limit error is due to dilutions. TM No inorganic or organic constituents were reported above their respective NC 2L Drinking Water Standards or Groundwater Protection Standards (GWPS) in wells or field/equipment/trip blanks or Surface Water Standards for surface points. Antimony (GWPS = 1 ug/L) o GGI 1 Outfall @ 6.84 ug/L Cobalt (GWPS = 1 ug/L) o MW-100B @ 1.30 ug/L (J) o MW-104 @ 6.23 ug/L (J) o MW-105A @ 3.55 ug/L (J) o MW-106 @ 1.13 ug/L (J) o MW-107s @ 14.8 ug/L o MW-108 @ 20.9 ug/L o GGI 1 Outfall @ 12.3 ug/L o GGI Outfall 2 @ 1.70 ug/L (J) Chromium (NC 2L = 10 ug/L) o GGI 1 Outfall @ 13.1 ug/L Vanadium (GWPS = 0.3 ug/L) o MW-105A @ 12.3 ug/L (J) o MW-107S@ 8.84 ug/L (J) o MW-108 @ 1.90 (J) o GGI 1 Outfall @ 4.61 ug/L (J) o GGI 2 Outfall @ 4.40 ug/L (J) TM No inorganic or organic constituents were detected in a well or surface water point at quantified concentrations outside of their historical range (more than 5X previous concentrations or first-time detections). TM Other report issues/Communications with laboratory/etc.: • MW-108 was processed at dilution for the analysis for Thallium due to matrix interference, resulting in elevated reporting limits. Page 1 of 49 Page 2 of 49 Page 3 of 49 Page 4 of 49 Page 5 of 49 Page 6 of 49 Page 7 of 49 Page 8 of 49 Page 9 of 49 Page 10 of 49 Page 11 of 49 Page 12 of 49 Page 13 of 49 Page 14 of 49 Page 15 of 49 Page 16 of 49 Page 17 of 49 Page 18 of 49 Page 19 of 49 Page 20 of 49 Page 21 of 49 Page 22 of 49 Page 23 of 49 Page 24 of 49 Page 25 of 49 Page 26 of 49 Page 27 of 49 Page 28 of 49 Page 29 of 49 Page 30 of 49 Page 31 of 49 Page 32 of 49 Page 33 of 49 Page 34 of 49 Page 35 of 49 Page 36 of 49 Page 37 of 49 Page 38 of 49 Page 39 of 49 Page 40 of 49 Page 41 of 49 Page 42 of 49 Page 43 of 49 Page 44 of 49 Page 45 of 49 Page 46 of 49 Page 47 of 49 Page 48 of 49 Page 49 of 49 Page 1 of 1 GOLDER ASSOCIATES NC, INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 1 of 3 Project Name: Sampson County – Active C&D Wells Project Reference Number: 0739-603715.100 Sampling Event Date: November 9-10, 2015 Review Date: November 25, 2015 Initials: TM Report #: C513743 Person(s) performing the review are to initial each item on this form as acknowledgement of data acceptance, or as acknowledgement of a review issue. In the case of the latter, a brief explanation should follow the applicable item. Golder Associates Inc. has reviewed the laboratory certificates of analysis, chain-of-custody form, and laboratory provided sample group quality assurance and quality control data for the above referenced sample group to identify potential bias or inaccuracy, in general accordance with the following United States Environmental Protection Agency documents: • Region III Modifications to Functional Guidelines for Organic Data Review Multi-Media, Multi- Concentration, September 1994; • Region III Modifications to the Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, April 1993; and • Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, July 1998. COMPLIANCE ANALYTE LIST(S) (check all that apply) X NC Closed Facility/C & D List NC Appendix I NC Appendix I + Detects NC Appendix II NC Subtitle D Leachate List Other: 1.0 CHAIN OF CUSTODY (COC) REVIEW TM COC was properly signed by all parties. TM Correct project name and number are on the form. TM Sample receipt condition at laboratory was acceptable. TM Each sample and blank submitted for analysis appears in the report. 2.0 SAMPLE HOLDING TIMES TM Holding times for extraction and/or analysis were met for each analytical method (see below for reference). GOLDER ASSOCIATES NC, INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 2 of 3 Review Criteria Method Analytes Holding Time SW-846 Method 8260 and 8011 VOCs 14 days SW-846 Methods 8270, 8080, 8081, 8082, and 8151 SVOCs, PCBs, pesticides and herbicides 7 days for extraction, 40 days from extraction for analysis SW-846 Methods 6000 and 7000 Series Metals except mercury 6 months (no temperature requirements) SW-846 Method 7470 Mercury 28 days SW-846 Method 376.1 Sulfide 7 days SW-846 Method 9010 Cyanide 14 days EPA Method 300 Nitrate/Sulfate 48 hours/28 days EPA Method 405.1 BOD 48 hours EPA Method 410.4 COD 28 days EPA Method 365.4 Phosphorous 28 days 3.0 LABORATORY QUALITY CONTROL REVIEW TM Laboratory analyzed at least one internal blank for each method, where applicable. TM Laboratory blank is interference-free. TM Surrogate recoveries are provided for each analytical method, where applicable. TM Surrogate recoveries for each method are within the acceptable limits (i.e., at least 50% of the surrogates were within range). The 8260B surrogate spike recovery of Dibromofluoromethane was outside of control limits for samples MW-1N and MW-4N. These samples were approved based on the acceptable recovery of the other surrogate standards. TM MS/MSD/LCS data results are provided for each analytical method. TM MS/MSD/LCS recoveries for each method are within the acceptable limits (i.e., at least 1 of the 3 were within range). The spike recovery of Alkalinity was outside of control limits for the MS and MSD samples. The QC batch was approved based on acceptable LCS recovery of this analyte. 4.0 ANALYTE LISTS/METHODS TM The proper number of constituents are present for each analyte list as identified above (including detects where applicable). TM Proper EPA SW-846 analytical methods were used for analysis. 5.0 DATA REPORTING TM All analytical reporting associated with the event was performed by the contracted lab. TM Trip, field and/or equipment, and laboratory blank results have all been reported. All detects for blanks are listed below by constituent. All laboratory method blanks, if any, have been ‘flagged’ with a ‘B’ where detected in other samples as appropriate and a laboratory narrative was provided. If the sample was flagged by the laboratory and is not within 5X of the concentration in the blank (or 10X for commonly detected laboratory contaminants-acetone, methylene chloride and phthalates), list below with explanation if flags should be removed. If flags need to be added for samples, also list below. GOLDER ASSOCIATES NC, INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 3 of 3 TM It is clear from the laboratory report that samples have or have not been diluted during analysis, and if the samples have been diluted, the result is reported as a multiple of the dilution (e.g., a sample diluted 10x resulting in an analytical detection of 1.0 should be reported as 10). Those that have been diluted are listed below with the dilution factor. MW-2N: Alkalinity (2x) MW-3N: Alkalinity (5x) TM The report provides the reporting limit for each constituent. TM The results were reported at or below their proper reporting limits (e.g., NC Solid Waste Section Approved QLs). Those that are not reported correctly are listed below (by constituent) with the proper reporting limit listed beside them. State if the reporting limit error is due to dilutions. TM No inorganic or organic constituents were reported above their respective NC 2L Drinking Water Standards or Groundwater Protection Standards (GWPS) in wells or field/equipment/trip blanks or Surface Water Standards in surface points. Chromium (NC 2L = 10 ug/L) MW-4N @ 19.1 ug/L MW-5AN @ 14.3 ug/L Cobalt (GWPS = 1 ug/L) MW-5AN @ 9.10 ug/L (J) Vanadium (GWPS = 0.3 ug/L) MW-4N @ 13.4 ug/L (J) MW-5AN @ 9.06 ug/L (J) Iron (NC 2L = 300 ug/L) MW-2N @ 5920 ug/L MW-3N @ 4170 ug/L MW-4N @ 4930 ug/L MW-5AN @ 3920 ug/L MW-5BN @ 723 ug/L Manganese (NC2L = 50 ug/L) MW-2N @ 182 ug/L MW-3N @ 131 ug/L TM No inorganic or organic constituents were detected in a well or surface water point at quantified concentrations outside of their historical range (more than 5X previous concentrations or first-time detections). TM Other report issues/Communications with laboratory/etc.: Page 1 of 21 Page 2 of 21 Page 3 of 21 Page 4 of 21 Page 5 of 21 Page 6 of 21 Page 7 of 21 Page 8 of 21 Page 9 of 21 Page 10 of 21 Page 11 of 21 Page 12 of 21 Page 13 of 21 Page 14 of 21 Page 15 of 21 Page 16 of 21 Page 17 of 21 Page 18 of 21 Page 19 of 21 Page 20 of 21 Page 21 of 21 Page 1 of 1 GOLDER ASSOCIATES NC, INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 1 of 3 Project Name: Sampson County Active MSW Landfill Project Reference Number: 073-9603715.100 Sampling Event Date: November 11, 2015 Review Date: November 25, 2015 Initials: TM Report #: C503744 Person(s) performing the review are to initial each item on this form as acknowledgement of data acceptance, or as acknowledgement of a review issue. In the case of the latter, a brief explanation should follow the applicable item. Golder Associates Inc. has reviewed the laboratory certificates of analysis, chain-of-custody form, and laboratory provided sample group quality assurance and quality control data for the above referenced sample group to identify potential bias or inaccuracy, in general accordance with the following United States Environmental Protection Agency documents: • Region III Modifications to Functional Guidelines for Organic Data Review Multi-Media, Multi-Concentration, September 1994; • Region III Modifications to the Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, April 1993; and • Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, July 1998. COMPLIANCE ANALYTE LIST(S) (check all that apply) NC Closed Facility/C & D List X NC Appendix I NC Appendix I + Detects NC Appendix II NC Subtitle D Leachate List Other: 1.0 CHAIN OF CUSTODY (COC) REVIEW TM COC was properly signed by all parties. TM Correct project name and number are on the form. TM Sample receipt condition at laboratory was acceptable. TM Each sample and blank submitted for analysis appears in the report. GOLDER ASSOCIATES NC, INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 2 of 3 2.0 SAMPLE HOLDING TIMES TM Holding times for extraction and/or analysis were met for each analytical method (see below for reference). Review Criteria Method Analytes Holding Time SW-846 Method 8260 and 8011 VOCs 14 days SW-846 Methods 8270, 8080, 8081, 8082, and 8151 SVOCs, PCBs, pesticides and herbicides 7 days for extraction, 40 days from extraction for analysis SW-846 Methods 6000 and 7000 Series Metals except mercury 6 months (no temperature requirements) SW-846 Method 7470 Mercury 28 days SW-846 Method 376.1 Sulfide 7 days SW-846 Method 9010 Cyanide 14 days EPA Method 300 Nitrate/Sulfate 48 hours/28 days EPA Method 405.1 BOD 48 hours EPA Method 410.4 COD 28 days EPA Method 365.4 Phosphorous 28 days 3.0 LABORATORY QUALITY CONTROL REVIEW TM Laboratory analyzed at least one internal blank for each method, where applicable. TM Laboratory blank is interference-free. TM Surrogate recoveries are provided for each analytical method, where applicable. TM Surrogate recoveries for each method are within the acceptable limits (i.e., at least 50% of the surrogates were within range). TM MS/MSD/LCS data results are provided for each analytical method. TM MS/MSD/LCS recoveries for each method are within the acceptable limits (i.e., at least 1 of the 3 were within range). The spike recovery of Trichloroethene exhibited a high bias in the 8260B LCS sample; however, this analyte was not detected in the associated samples, reducing the impact of deviation. The spike recoveries of Toluene and Trichloroethene were outside of control limits for the MS and or MSD samples. The QC batch was approved based on LCS recovery of these analytes. 4.0 ANALYTE LISTS/METHODS TM The proper number of constituents are present for each analyte list as identified above (including detects where applicable). TM Proper EPA SW-846 analytical methods were used for analysis. 5.0 DATA REPORTING TM All analytical reporting associated with the event was performed by the contracted lab. TM Trip, field and/or equipment, and laboratory blank results have all been reported. All detects for blanks are listed below by constituent. All laboratory method blanks, if any, have been ‘flagged’ with a ‘B’ where detected in other samples as appropriate and a laboratory narrative was provided. If the sample was flagged by the laboratory and is not within 5X of the concentration in the blank (or 10X for commonly detected laboratory contaminants-acetone, GOLDER ASSOCIATES NC, INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 3 of 3 methylene chloride and phthalates), list below with explanation if flags should be removed. If flags need to be added for samples, also list below. TM It is clear from the laboratory report that samples have or have not been diluted during analysis, and if the samples have been diluted, the result is reported as a multiple of the dilution (e.g., a sample diluted 10x resulting in an analytical detection of 1.0 should be reported as 10). Those that have been diluted are listed below with the dilution factor. SW-4: Thallium 10x TM The report provides the reporting limit for each constituent. TM The results were reported at or below their proper reporting limits (e.g., NC Solid Waste Section Approved QLs). Those that are not reported correctly are listed below (by constituent) with the proper reporting limit listed beside them. State if the reporting limit error is due to dilutions. TM No inorganic or organic constituents were reported above their respective NC 2L Drinking Water Standards or Groundwater Protection Standards (GWPS) in wells or field/equipment/trip blanks or Surface Water Standards for surface points. Zinc: SW-4 @ 77.2 ug/L, SW-5 @ 62.8 ug/L Acetone: SW-5 @ 23 ug/L (J) Silver: SW-5 @ 1.95 ug/L (J) TM No inorganic or organic constituents were detected in a well or surface water point at quantified concentrations outside of their historical range (more than 5X previous concentrations or first-time detections). TM Other report issues/Communications with laboratory/etc.: Page 1 of 19 Page 2 of 19 Page 3 of 19 Page 4 of 19 Page 5 of 19 Page 6 of 19 Page 7 of 19 Page 8 of 19 Page 9 of 19 Page 10 of 19 Page 11 of 19 Page 12 of 19 Page 13 of 19 Page 14 of 19 Page 15 of 19 Page 16 of 19 Page 17 of 19 Page 18 of 19 Page 19 of 19 Page 1 of 1 GOLDER ASSOCIATES NC, INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 1 of 3 Project Name: Sampson County Active Landfill – Leachate Project Reference Number: 0739-603715.100 Sampling Event Date: November 12, 2015 Review Date: December 4, 2015 Initials: TM Report #: C513740 Person(s) performing the review are to initial each item on this form as acknowledgement of data acceptance, or as acknowledgement of a review issue. In the case of the latter, a brief explanation should follow the applicable item. Golder Associates Inc. has reviewed the laboratory certificates of analysis, chain-of-custody form, and laboratory provided sample group quality assurance and quality control data for the above referenced sample group to identify potential bias or inaccuracy, in general accordance with the following United States Environmental Protection Agency documents: • Region III Modifications to Functional Guidelines for Organic Data Review Multi-Media, Multi- Concentration, September 1994; • Region III Modifications to the Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, April 1993; and • Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, July 1998. COMPLIANCE ANALYTE LIST(S) (check all that apply) NC Closed Facility/C & D List NC Appendix I NC Appendix I + Detects NC Appendix II X NC Subtitle D Leachate List Other: 1.0 CHAIN OF CUSTODY (COC) REVIEW TM COC was properly signed by all parties. TM Correct project name and number are on the form. TM Sample receipt condition at laboratory was acceptable. TM Each sample and blank submitted for analysis appears in the report. 2.0 SAMPLE HOLDING TIMES TM Holding times for extraction and/or analysis were met for each analytical method (see below for reference). GOLDER ASSOCIATES NC, INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 2 of 3 Review Criteria Method Analytes Holding Time SW-846 Method 8260 and 8011 VOCs 14 days SW-846 Methods 8270, 8080, 8081, 8082, and 8151 SVOCs, PCBs, pesticides and herbicides 7 days for extraction, 40 days from extraction for analysis SW-846 Methods 6000 and 7000 Series Metals except mercury 6 months (no temperature requirements) SW-846 Method 7470 Mercury 28 days SW-846 Method 376.1 Sulfide 7 days SW-846 Method 9010 Cyanide 14 days EPA Method 300 Nitrate/Sulfate 48 hours/28 days EPA Method 405.1 BOD 48 hours EPA Method 410.4 COD 28 days EPA Method 365.4 Phosphorous 28 days 3.0 LABORATORY QUALITY CONTROL REVIEW TM Laboratory analyzed at least one internal blank for each method, where applicable. TM Laboratory blank is interference-free. TM Surrogate recoveries are provided for each analytical method, where applicable. TM Surrogate recoveries for each method are within the acceptable limits (i.e., at least 50% of the surrogates were within range). TM MS/MSD/LCS data results are provided for each analytical method. TM MS/MSD/LCS recoveries for each method are within the acceptable limits (i.e., at least 1 of the 3 were within range). The spike recovery of Alkalinity was outside of control limits for the MS and MSD samples. The QC batch was approved based on acceptable LCS recovery of this analyte. 4.0 ANALYTE LISTS/METHODS TM The proper number of constituents are present for each analyte list as identified above (including detects where applicable). TM Proper EPA SW-846 analytical methods were used for analysis. 5.0 DATA REPORTING TM All analytical reporting associated with the event was performed by the contracted lab. TM Trip, field and/or equipment, and laboratory blank results have all been reported. All detects for blanks are listed below by constituent. All laboratory method blanks, if any, have been ‘flagged’ with a ‘B’ where detected in other samples as appropriate and a laboratory narrative was provided. If the sample was flagged by the laboratory and is not within 5X of the concentration in the blank (or 10X for commonly detected laboratory contaminants-acetone, methylene chloride and phthalates), list below with explanation if flags should be removed. If flags need to be added for samples, also list below. GOLDER ASSOCIATES NC, INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 3 of 3 TM It is clear from the laboratory report that samples have or have not been diluted during analysis, and if the samples have been diluted, the result is reported as a multiple of the dilution (e.g., a sample diluted 10x resulting in an analytical detection of 1.0 should be reported as 10). Those that have been diluted are listed below with the dilution factor. Leachate (L-1) Chloride (40x) Alkalinity (100x) TM The report provides the reporting limit for each constituent. TM The results were reported at or below their proper reporting limits (e.g., NC Solid Waste Section Approved QLs). Those that are not reported correctly are listed below (by constituent) with the proper reporting limit listed beside them. State if the reporting limit error is due to dilutions. N/A No inorganic or organic constituents were reported above their respective NC 2L Drinking Water Standards or Groundwater Protection Standards in field/equipment/trip blanks or Surface Water Standards in surface points. TM No quantifiable inorganic or organic constituents were detected in a well or surface water point at concentrations outside of their historical range (more than 5X previous concentrations or first-time detections). TM Other report issues/Communications with laboratory/etc.: Page 1 of 11 Page 2 of 11 Page 3 of 11 Page 4 of 11 Page 5 of 11 Page 6 of 11 Page 7 of 11 Page 8 of 11 Page 9 of 11 Page 10 of 11 Page 11 of 11 Page 1 of 1 APPENDIX C STATISTICAL EVALUATION WORKSHEETS & SUMMARY TABLE January 2016 Page 1 of 1 0739-603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Stats\Stats Summary MSW Wells Table Nov 2015.xls MW-104 MW-105A MW-106 MW-107S MW-108 GGI Outfall 1 GGI Outfall 2 Antimony ug/L Interwell Nonparametric Prediction Limit 14.0 ND ND ND ND ND 6.84 ND Chromium ug/L Interwell Nonparametric Prediction Limit 77.0 7.80 J ND 3.19 J 4.20 J 2.53 J 13.1 ND Interwell Nonparametric Prediction Limit 5.52 Intrawell MW-107s Upper Tolerance Limit 183 Intrawell MW-108 Nonparametric Prediction Limit 48.2 GGI Outfall 1 Nonparametric Prediction Limit 10.0 Notes:1. Shaded values represent confirmed statistical significant increases (SSIs) over background concentrations. 2. Statistical worksheets are provided in Appendix C. 3. ug/L = micrograms per liter; ND = not detected at the laboratory detection limit; J = estimated concentration below the Solid Waste Section Limit Cobalt Prediction IntervalStatistical Evaluation Method Summary of Statistical Analysis Sampson County Active MSW Landfill, Permit No. 82-02 Sampson County, North Carolina November 2015 Downgradient Monitoring Wells and Concentrations Detected Monitoring Constituent/Analytes Reporting Units 12.3 1.70 Jug/L 6.23 J 3.55 J 1.13 J 14.8 20.9 January 2016 Page 1 of 1 0739603715.100 G:\Projects\Waste Industries\Sampson County\Active MSW Landfill 82-02\GWMR\Nov 2015\Stats\Stats Summary C&D Wells Table Nov 2015.xls MW-2N MW-3N MW-4N MW-5AN MW-5BN Interwell Nonparametric Prediction Limit 5.40 MW-3N Intrawell Nonparametric Prediction Limit 16.0 Chromium ug/L Interwell Nonparametric Prediction Limit 20.0 ND ND 19.1 14.3 ND Interwell Nonparametric Prediction Limit 3540 MW-2N Intrawell Upper Tolerance Limit 92449 MW-3N Intrawell Upper Tolerance Limit 84114 MW-4N Intrawell Upper Tolerance Limit 15904 MW-5AN Intrawell Upper Tolerance Limit 6415 Interwell Nonparametric Prediction Limit 25.0 MW-2N Intrawell Upper Tolerance Limit 406 MW-3N Intrawell Upper Tolerance Limit 715 Notes:1. Shaded values represent apparent statistical significant increases (SSIs) over background concentrations. 2. Statistical worksheets are provided in Appendix C. 3. ug/L = micrograms per liter; ND = not detected at the laboratory detection limit; J = estimated concentration below the Solid Waste Section Limit Summary of Statistical Analysis Sampson County Active C&D Landfill, Permit No. 82-02 Sampson County, North Carolina November 2015 Iron ug/L 5920 4170 4930 3920 27.0 J 723 Downgradient Monitoring Wells and ConcentrationsDetected Monitoring Constituent/Analytes Reporting Units Prediction IntervalStatistical Evaluation Method ND Manganese ug/L 182 131 10.7 J 11.5 J Arsenic ug/L ND 10.1 ND ND Golder Associates NC, Inc. 5B Oak Branch Drive Greensboro, NC 27407 USA (336) 852-4903 - Phone (336) 852-4904 - Fax