9601_WayneCounty_CDLF_GWMReport_DIN26414_20150821

Wayne County Active C&D and Closed MSWLF
Dudley, North Carolina
August 2015
MESCO Project Number: G15016.0
Semi-Annual Water Quality Monitoring Report
with Corrective Action Update
Prepared for
Municipal Engineering Services Company, P.A.Garner and Boone, North Carolina
P.O. Box 97
Garner, NC 27529
License No. C-0281

Permit Number: 96-01
TABLE OF CONTENTS
SECTION
Introduction Page 1
Background Page 1
Sampling Procedure Page 2
Field Parameter Data Page 2
Laboratory Results Page 3
Quality Control Samples Page 3
Groundwater Samples Page 3
Surface Water Samples Page 3
Corrective Action Update Page 3
Groundwater and Surface Water Characterization Page 3
Findings Page 4
Closing Page 5
FIGURES
Topographic Map with Site Location Figure 1
Potentiometric Map of Uppermost Aquifer w/ VOC Detection Above 2L Standard Figure 2
Time-Series Graphs of Select Constituents Figure 3
TABLES
Groundwater Monitoring Well Construction Table Table 1
Field Observations of Monitoring Locations Table 2
Field Parameter Data Summary Table 3
Sampling and Analysis Summary Table 4
Detections Above SWSL, GWP, 2L, or 2B (Appendix 1) Table 5
Hydrologic Properties at Monitoring Well Locations Table 6
APPENDICIES
Laboratory Analysis Reports and Chains of Custody Appendix A
Field Sampling Data Sheet(s) Appendix B
April 12, 2016
Ms. Jaclynne Drummond
Solid Waste Section (SWS)
Division of Waste Management
North Carolina Department of Environmental Quality (NCDEQ)
2090 US 70 Highway
Swannanoa, NC 28778
Re: Semi-Annual Water Quality Monitoring Report with Corrective Action Update
Wayne County Active C&D and Closed MSWLF (Dudley)
Permit No. 96-01
MESCO Project No. G15016.0
Event Date(s): August 20-21, 2015
Dear Ms. Drummond:
Introduction
The Wayne County Landfill (Permit #96-01) is located at 460 S Landfill Road (SR 1129), Dudley, Wayne County,
North Carolina. A topographic map showing the location of the site is included as Figure 1.
The Wayne County unlined closed Municipal Solid Waste Landfill (MSWLF) and active Construction and Demolition
(C&D) Landfill located in Dudley NC, currently operating under Permit #96-01 is required to submit semi-annual
compliance reports as a condition of 15A NCAC 13B.1630. This report documents the quality of the ground and
surface waters during this monitoring event performed on August 20-21, 2015. Laboratory analytical results indicate
that no constituents attributed to anthropogenic sources were detected in concentrations exceeding regulatory
Standards for the second consecutive event. Corrective action via monitored natural attenuation (MNA) is planned to
continue.
As specified within 15A NCAC 13B.1632(j), the SWS Environmental Monitoring Report Form and SWS
memorandums this report contains sampling procedures, field and laboratory results, corrective action update,
ground/surface water characterization, and findings. Well construction summary table, field observations table, field
parameter data table, sampling and analysis summary table, detections compared to Standards tables, a groundwater
flow directions/rates table, potentiometric map, time-series graph, quality assurance/quality control data, and
laboratory analytical data results are enclosed herein.

Background
Prior to operating as a C&D landfill the site operated as a Municipal Solid Waste (MSW) unlined sanitary landfill that
consisted of two units. The first unit (Unit 1) was closed prior to October 1991 with a 24 inch final soil cover. The
second unit (Unit 2) was closed with a low permeability cohesive cap and erosive layer prior to December 31, 1998 in
accordance with the Transition Plan. The C&D landfill is operating on top of the Unit 2 MSW landfill. The separate
active Subtitle D Lined MSWLF (permit #96-06), located adjacent to the C&D landfill across an unnamed tributary of
Edward's Branch, was monitored in conjunction with this site but reported separately.
Water quality at this landfill has been monitored at least semi-annually since 1991. Current data was compared to data
compiled since 1994 in support of this report. Municipal Engineering Services Company, P.A. (MESCO) submitted an
Assessment and Corrective Action (ACM) [DIN8821] report dated August 30, 2007 which was approved by the NC Solid
Waste Section (SWS) on November 1, 2007 [DIN3328]. MESCO then developed a Corrective Action Plan (CAP)
[DIN8821] on October 22, 2009 which was approved by the SWS on October 23, 2009 [DIN8822]. Groundwater
remediation using Monitored Natural Attenuation (MNA) was initiated on August 6, 2009 and has continued on a semi-
annual basis. Following establishment of the two year MNA baseline, MESCO completed a Corrective Action
Evaluation Report (CAER) [DIN 13923] on May 10, 2011. The CAER was reviewed and the proposed modifications of
MNA parameters and frequency were approved by the SWS [DIN 16967]. Background well MW-1 was abandoned and
replaced by MW-1R as pre-authorized by SWS [DIN 19050] on June 4, 2013. MESCO submitted a Request for
Appendix II Groundwater Monitoring Modification dated April 24, 2014 which was approved by the SWS. The Water
Quality Sampling and Analysis Plan (SAP) which provides for a subset of wells to decrease Appendix II monitoring
frequency was revised and submitted on December 15, 2014 as requested by Ms. Christine Ritter of the SWS.
Groundwater remediation through MNA per the CAP is scheduled to continue provided there is no change directed by the
SWS.
Sampling Procedure
MESCO performed this sampling event utilizing portable monitoring methodology in accordance with the approved SAP
based on the Solid Waste Section Guidelines for Groundwater, Soil, and Surface Water Sampling revised April 2008.
The new site-specific SAP entails continued semi-annual water quality monitoring which includes annual corrective
action monitoring and targeting of specific Appendix II constituents at a subset of wells once every three years. Keeping
with the established schedule this event consists of detection monitoring (Appendix I) at all locations. Water samples
were collected from monitoring locations designated in the SAP with the exception of SW-2 and SW-3, which were dry.
Water quality monitoring was performed on ten wells (MW-2, MW-3, MW-4, MW-5, MW-6, MW-7, MW-8, MW-9,
MW-10 and MW-11), one background well (MW-1R) and one surface water point (SW-1). Quality control measures
implemented during this event included quantification of an equipment blank (EB), field blank (FB) and travel blank
(TB). A supplemental surface water sample (SW-By_MW-2) was collected from the western tributary of Edward's
Branch directly downgradient of MW-2. Data from two surface water locations from the Subtitle D Lined SAP SW-2
(shared) and SW-3 (shared) are presented because this local discharge feature is shared by both permits. Monitoring
locations are depicted on the potentiometric map, included as Figure 2.
This semi-annual event consisted of targeting constituents listed in 40 CFR Appendix I. MNA performance monitoring
entailed only field parameters as this event was exempt from lab analysis. Water samples were collected from monitoring
locations designated in the SAP with the exception of SW-2 and SW-3, which were dry. Water quality monitoring was
performed on ten wells (MW-2, MW-3, MW-4, MW-5, MW-6, MW-7, MW-8, MW-9, MW-10 and MW-11), one
background well (MW-1R) and one surface water point (SW-1). Quality control measures implemented during this event
included quantification of an equipment blank (EB), field blank (FB) and travel blank (TB). A supplemental surface
2
water sample (SW-By_MW-2) was collected from the western tributary of Edward's Branch directly downgradient of
MW-2. Data from two surface water locations from the Subtitle D Lined SAP SW-2 (shared) and SW-3 (shared) are
presented because this local discharge feature is shared by both permits. Monitoring locations are depicted on the
potentiometric map, included as Figure 2.
A summary detailing the construction of the water monitoring wells is presented on Table 1. The function and integrity
of all monitoring locations were visually evaluated and no deficiencies identified as documented on Table 2. The depth
to water in each well was electronically gaged prior to purging to quantify the static water level elevation. Low-flow
pumping methodology or bailing was utilized to adequately purge the wells a minimum of three times the volume of
standing water in the well or until dry. Surface water samples were dipped from the surface of the creeks at previously
designated locations. Samples were then placed into laboratory-prepared, pre-preserved containers. Samples were kept
on ice and transported to a NC-certified laboratory under proper chain of custody (C-O-C) protocol and analyzed within
the required hold times.
Field Parameter Data
Stabilized field parameters were recorded during purging which included pH, specific conductance, temperature,
dissolved oxygen (DO), oxidation reduction potential (ORP), dissolved carbon dioxide (CO2), total dissolved solids
(TDS) and turbidity. A summary of the field parameter data is presented in Table 3 and the field sampling data sheet is
enclosed in Appendix B.
Laboratory Results
Pace Analytical Laboratories (PACE) performed the laboratory analysis. All samples were analyzed for Appendix I
constituents listed in 40 CFR 258. A sampling and analysis table summarizing the locations, targeted constituents and
methods is presented as Table 4. Laboratory results and C-O-Cs are contained in Appendix A.
Water samples were analyzed to the laboratory-established Method Detection Limits (MDL), which are at or below the
current Solid Waste Section Limit (SWSL). Table 5 summarizes constituents detected in groundwater and surface water
samples that attain or were above the current SWSL, Groundwater Protection Standards (GWP), North Carolina
Groundwater Standards (2L), the applicable North Carolina Surface Water Standards (2B) for a Class C waterbody and
Maximum Contaminant Levels (MCL) also known as “Federal Primary Drinking Water Standards”.
Quality Control Samples
Methylene chloride was detected in non-quantifiable (“j-qualified”) levels in all blanks (EB, FB, TB). Since methylene
chloride, a common laboratory contaminant, was not detected in any ground or surface water samples above regulatory
Standards, any potential lab induced artifact contamination is non-consequential.
Groundwater Samples
Total metals detected in excess of their respective 2L Standards were arsenic in MW-2 [13.8 µg/L / (2L Standard of 10.0
µg/L)] and cadmium (2L Standard of 2.0 µg/L) in MW-3 (24.8 µg/L), MW-4 (2.2 µg/L), MW-6 (2.5 µg/L), MW-10 (2.1
µg/L) and MW-11 (2.6 µg/L).
During this event benzene was detected in sample MW-2 at 0.99 j µg/L which is below the 2L Standard (1.0 µg/L) for the
second consecutive event after being consistently reported in excess of the 2L Standard the previous seven years.
3
Surface Water Samples
Constituents were not detected in any surface water sample in concentrations above the established 2B Standards.
Supplemental surface water sample SW-By_MW-2 collected at the property line approximately 166 feet hydraulically
downgradient of MW-2 continues to lack Appendix II VOCs.
Corrective Action Update
Groundwater remediation measures through MNA continues to be implemented at the facility. Semi-annual MNA
monitoring of MW-2, MW-8 and background well MW-1 was initiated on August 6, 2009 and was consistently
performed for the full suite of SWS recommended parameters for six consecutive semi-annual events. The SAP
prescribes MNA monitoring for specific constituents to be performed annually or bi-annually. Keeping with established
schedule MNA parameters were not quantified in the lab during this event but will be during the next event.
The active Landfill Gas Collection and Control System (GCCS) continues operations. The GCCS extracts LFG for
energy production therefore is closely maintained for optimum efficiency which may have a collateral remediation effect
on groundwater.
Groundwater and Surface Water Characterization
A potentiometric map of the uppermost aquifer created from groundwater elevation data collected during this event is
included as Figure 2. Groundwater flow rates and directions were calculated based on collected data and are included in
Table 6. Groundwater generally generally flows southwesterly towards Edward's Branch ranging from approximately 2
foot/year (MW-7) to 343 feet/year (MW-3) with an average rate of 75 feet/year The calculated flow directions and
gradients are consistent with historical observations. Streams located within the facility boundaries were visually
observed at low seasonal flow, low volume and low turbidity.
Findings
Contaminants attributed to anthropogenic sources were not detected in any sample above regulatory Standards during this
and the previous event performed in February 2015. During the previous seven years the only contaminant detected in
excess of 2L Standard originating from landfill activities was benzene in MW-2 (Figure 3). The horizontal plume extent
downgradient of MW-2 appears to have not impacted the adjacent local discharge feature as evidenced by the lack of
detections in samples SW-By_MW-2 and SW-1.
Groundwater quality monitored by MW-8, located hydraulically upgradient of waste, has improved significantly since the
ACM was drafted as evidenced by the lack of contaminant detections in levels exceeding the 2L Standard during the past
8 years. The single contaminant of concern detected above 2L in MW-8 since ACM (1,4-dichlorobenzene) has not been
detected at a concentration above its current 2L Standard since August 2007 (Figure 3). Samples collected from MW-9
and MW-10, installed to delineate the impact beyond MW-8, continue to lack detections.
The preliminary source of the few metal detections is not believed to be anthropogenic but rather originating from erosion
of natural deposits.
The lack of detections in surface water samples indicate the discharge features remain unimpacted.
4
Figures
Topographic Map with Site Location
01 1 MILE
FIGURE 1
Wayne County Landfill North Carolina (Dudley)
CLOSED MSW FACILITY
SUBTITLE D MSW
LANDFILL FACILITY
460 B South Landfill Rd
Dudley, NC 28333
Lat:35-17-19.1338
Long:-78-04-17.2971
Northing:561283.19
Easting:2277068.62
N
Wayne County Active C&D and Closed MSWLF (Dudley)Page 1 of 1
Figure 3
Time-Series Graphs of Select Constituents
September 8, 1994 - August 21, 2015
Non-Detects Shown at Method Detection Level.
2L
2L
2L
2L
2L NC Groundwater Standard
MCLMCL “Drinking Water Standard”
Tables
Wayne County Active C&D and Closed MSWLF (Dudley)Page 1 of 1
Table 1
Groundwater Monitoring Well Construction Table
August 20-21, 2015
Latitude Longitude
(inches)(ft)
MW-1R 6/4/13 2 27.32 12.32 15 Soil Sand 169.64 166.64 147.69 21.95 35.292408 -78.064431
MW-2 8/28/90 2 15 10 5 Soil Sand 134.52 132.78 128.57 5.95 35.290714 -78.076225
MW-3 8/27/90 2 18 12 6 Soil Sand 134.81 133.03 134.29 0.52 35.293192 -78.072156
MW-4 8/28/90 2 15 10 5 Soil Sand 150.20 148.17 142.75 7.45 35.293003 -78.066253
MW-5 8/31/94 2 18 3 15 Soil Sand 124.78 120.56 121.37 3.41 35.292597 -78.075936
MW-6 8/31/94 2 18.14 3.14 15 Soil Sand 145.53 143.62 138.38 7.15 35.293439 -78.068656
MW-7 8/31/94 2 19 4 15 Soil Sand 143.59 140.74 134.15 9.44 35.288761 -78.074700
MW-8 8/30/94 2 29 14 15 Soil Sand 161.88 160.88 142.50 19.38 35.290178 -78.068706
MW-9 7/9/09 2 25 10 15 Soil Sand 162.96 159.78 143.15 19.81 35.290025 -78.068242
MW-10 7/9/09 2 25 10 15 Soil Sand 162.90 160.01 144.89 18.01 35.289869 -78.069167
MW-11 7/9/09 2 15 5 10 Soil Sand 127.23 124.50 124.08 3.15 35.291844 -78.076250
NOTE:
Monitoring
Well
Date
Installed
Well Diameter
Total
Well
Depth
Top of
Screen
Depth
Screen Length Geology of
Screened
Interval
Top of
Casing
Elevation
Ground Elevation Groundwater Elevation Depth to Water
(ft bgs)(ft bgs)(ft amsl)(ft amsl)(ft amsl)(ft btoc)
na = not available
bgs = below ground surface
amsl= above mean sea level
btoc = below top of PVC well casing
Wayne County Active C&D and Closed MSWLF Page 1 of 1
Table 2
Field Observations of Monitoring Locations
August 20-21, 2015
Locked Comments
MW-1R Yes Yes Yes Yes Yes Yes
MW-2 Yes Yes Yes Yes Yes Yes
MW-3 Yes Yes Yes Yes Yes Yes Flowing artesian, lock rusting
MW-4 Yes Yes Yes Yes Yes Yes
MW-5 Yes Yes Yes Yes Yes Yes
MW-6 Yes Yes Yes Yes Yes Yes
MW-7 Yes Yes Yes Yes Yes Yes
MW-8 Yes Yes Yes Yes Yes Yes
MW-9 Yes Yes No Yes Yes Yes
MW-10 Yes Yes Yes Yes Yes Yes
MW-11 Yes Yes Yes Yes Yes Yes Flowing artesian, lock rusting
SW-1 Yes -----Shared Downstream of SW-3
SW-2 No -----Dry-Upstream nearest MW-7
SW-2 Yes -----Shared nearest lined MW-2
SW-3 Yes -----Shared downstream of SW-2
SW-3 No -----Dry-Shared Upstream nearest MW-4
SW-By _MW-2 Yes -----Not required but supplemental sample
Any unusual field conditions, observations, or events:
All wells with the exception of MW-1R and MW-4 have been painted blue by the County since August 2013.
Wells have had sediment removed from concrete pads surrounding wells by County since August 2013.
Sample
Location
Viable
Monitoring
Location
Lack of Any
Evidence of
Tampering
Hinge/Hasp
Operational
Tagged
or
Labeled
Concrete
Surface Pad
Effective
Wayne County Active C&D and Closed MSWLF (Dudley)Page 1 of 1
Table 3
Field Parameter Data Summary
August 20-21, 2015
Parameter Temp.ORP DO pH TDS Turbidity
Units C mg/L SU mg/L NTU or Visual
MW-1R 21.95 147.68 169.63 17.1 410 5.1 6.13 10 0 303
MW-2 5.95 128.57 134.52 21.3 -29 1.1 6.83 1380 680 219
MW-3 0.52 134.29 134.81 19.1 251 3.4 5.28 20 0 Slight
MW-4 7.45 142.75 150.20 19.4 238 2.3 5.91 40 20 Clear
MW-5 3.41 121.37 124.78 20.7 210 2.5 5.59 60 20 Slight
MW-6 7.15 138.38 145.53 20.5 138 2.1 5.41 90 40 Clear
MW-7 9.44 134.15 143.59 20.1 373 2.2 5.38 80 30 Clear
MW-8 19.38 142.50 161.88 18.1 338 2.5 5.11 90 40 89
MW-9 19.81 143.15 162.96 18.7 352 3.7 5.13 80 30 Moderate
MW-10 18.01 144.89 162.90 18.1 381 5.1 5.91 80 30 Moderate
MW-11 3.15 124.08 127.23 20.1 142 4.7 5.81 1310 690 Very
Minimum 0.52 121.37 124.78 17.1 -29 1.1 5.11 10 0 Clear
Average 10.57 136.53 147.09 19.4 255 3.2 5.68 295 144 Slight
Maximum 21.95 147.68 169.63 21.3 410 5.1 6.83 1380 690 Very
SW-1 ---20.5 NR NR 7.07 430 210 Clear
SW-2 ---20.3 NR NR 7.01 370 160 Clear
---24.7 193 5.3 7.01 280 130 Clear
SW-3 ---20.1 NR NR 7.01 400 190 Clear
Minimum ---20.1 193 5.3 7.01 280 130 Clear
Average ---21.4 193 5.3 7.03 370 173 Clear
Maximum ---24.7 193 5.3 7.07 430 210 Clear
NR = No reading attempted
Depth to
Water
Water
Elevation
TOC
Elevation
Specific
Conductance
ft (btoc)ft (amsl)ft (amsl)mV umhos/cm
SW-ByMW-2
Wayne County Active C&D and Closed MSWLF (Dudley)Page 1 of 1
Table 4
Sampling and Analysis Summary
August 20-21, 2015
Field Parameter MNA
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MW-1R x x x x x x x x x
MW-2 x x x x x x x x x
MW-3 x x x x x x x x
MW-4 x x x x x x x x
MW-5 x x x x x x x x
MW-6 x x x x x x x x
MW-7 x x x x x x x x
MW-8 x x x x x x x x x
MW-9 x x x x x x x x
MW-10 x x x x x x x x
MW-11 x x x x x x x x
SW-1 x x x x x x
SW-2 Dry
SW-2 (shared)x x x x x x
x x x x x
SW-3 (shared)x x x x x x
SW-3 Dry
EB x x
FB x x
TB x
App. I App II
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SW-ByMW-2
App I & II = Appendix I & II List from current 40 CFR 258
Wayne County Active C&D and Closed MSWLF (Dudley)Page 1 of 1
Table 5
Detections in Water Samples above SWSL, GWP, 2L, 2B or MCL (Appendix I)
August 20-21, 2015
Result Unit
MW-2 Arsenic, total 8/21/15 13.8 2.5 10 10 10 N
MW-2 8/21/15 0.32J 0.3 5 24 NE
MW-2 8/21/15 2.3 0.33 1 6 75
MW-2 Barium, total 8/21/15 147 2.5 100 700 1300
MW-2 8/21/15 12.4 0.23 3 50 100
MW-2 Vanadium, total 8/21/15 3.6 J 2.5 25 NE 3.5 NE
MW-3 Cadmium, total 8/21/15 24.8 0.5 1 2 5 N
MW-3 Vanadium, total 8/21/15 7.8J 2.5 25 NE 3.5 NE
MW-3 Zinc, total 8/21/15 13.8 5 10 1000 5000
MW-4 Cadmium, total 8/20/15 2.2 0.5 1 2 5 N
MW-5 Cadmium, total 8/21/15 1.4 0.5 1 2 5
MW-5 Zinc, total 8/21/15 11.7 5 10 1000 5000
MW-6 Cadmium, total 8/20/15 2.5 0.5 1 2 5 N
MW-6 8/20/15 0.37J 0.3 5 24 NE
MW-7 Vanadium, total 8/20/15 4.8J 2.5 25 NE 3.5 NE
MW-10 Cadmium, total 8/20/15 2.1 0.5 1 2 5 N
MW-10 Chromium, total 8/20/15 16.9 2.5 10 10 100 N
MW-10 Barium, total 8/20/15 377 2.5 100 700 1300
MW-11 Cadmium, total 8/21/15 2.6 0.5 1 2 5 N
SW-2 Vanadium, total 8/21/15 4.2J 2.5 25 NE NE
SW-2 Zinc, total 8/21/15 13 5 10 50 5000
FB Methylene Chloride 8/21/15 1.3 0.97 1 4.6 5
EB Methylene Chloride 8/21/15 1.1 0.97 1 4.6 5
TB Methylene Chloride 8/21/15 2.4 0.97 1 4.6 5
A definitive source of the detection was not determined as part of this report. Preliminary cause only listed pursuant to EMRF instructions.
J=The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL),
adjusted for actual sample preparation data and moisture content, where applicable
N = Natural originating from erosion of natural deposits. Source not anthropogenic.
BOLD = Concentration > 2L, 2B, GWP or MCL Standard
Sample
ID Parameter Name 1 Sample
Date MDL 2 SWSL 3 2L 4 2B 5 GWP 6 MCL 7 Preliminary
Cause 8
ug/L
1,2-Dichlorobenzene ug/L
1,4-Dichlorobenzene ug/L
ug/L
Chlorobenzene ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1,2-Dichlorobenzene ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1 Table contains constituents listed in 40CFR Appendix I detected at or above SWSL, GWP, 2L, 2B or MCL
2 MDL = Method Detection Limit
3 SWSL = Solid Waste Section Reporting Limit
4 2L = North Carolina 15A NCAC 2L Groundwater Quality Standard
5 2B = North Carolina 15 NCAC 2B Surface Water Quality Standard for this Specific Stream Classification
6 GWP = Groundwater Protection Standard
7 MCL = Primary Drinking Water Standard (not currently applicable for regulatory comparisons)
8 Preliminary Cause = Refers to a preliminary analysis of the cause and/or source of a detection over the respective 2L/2B Standard.
Wayne County Active C&D and Closed MSWLF (Dudley)Page 1 of 1
Table 6
August 20-21, 2015
MW-1R 20 0.018 N31W 21.95 147.69
MW-2 3.00E-04 20 0.018 28 N54W 5.95 128.57
MW-3 6.40E-03 20 0.010 343 N54W 0.52 134.29
MW-4 9.90E-04 20 0.023 116 N28W 7.45 142.75
MW-5 3.10E-05 20 0.023 4 N41W 3.41 121.37
MW-6 1.60E-04 20 0.011 9 N29W 7.15 138.38
MW-7 7.30E-05 20 0.006 2 N70W 9.44 134.15
MW-8 3.40E-04 20 0.012 21 N11W 19.38 142.50
Minimum 3.10E-05 20 0.006 2 -0.52 121.37
Average 1.18E-03 20 0.015 75 -9.41 136.21
Maximum 6.40E-03 20 0.023 343 -21.95 147.69
NOTE: Data for conductivities and effective porosity obtained from GAI Consultants' Water Sampling Report (January, 1995).
where
Hydrologic Properties at Monitoring Well Locations
Monitoring
Well
Hydraulic
Conductivity
(cm/sec)
Effective
Porosity (%)
Hydraulic
Gradient (ft/ft)
Linear Velocity
(ft/yr)
Flow
Direction
Depth to
Groundwater
(ft btoc)
Groundwater
Potentiometric
Elevation
(ft amsl)
na na
Hydrologic Gradient from groundwater elevations recorded on August 20-21, 2015.
Linear Velocity (Q) is defined by modified Darcy's equation:
K = hydraulic conductivity
ne = effective porosity
dh = head difference
dl = horizontal distance
dl
dh
n
KQ
e
-=
Appendix A
Laboratory Analysis Reports
Chains of Custody
#=CL#
September 09, 2015
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92264558
92264558
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
PO Box 97
Garner, NC 27529
WAYNE CLOSED MSWLF (DUDLEY)
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory between August 21,
2015 and August 25, 2015. The results relate only to the samples included in this report. Results
reported herein conform to the most current TNI standards and the laboratory's Quality Assurance
Manual, where applicable, unless otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 49
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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[phone]
Page 2 of 49
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Lab ID Sample ID Matrix Date Collected Date Received
92264558001 MW-4 Water 08/20/15 16:10 08/21/15 15:25
92264558002 MW-6 Water 08/20/15 17:25 08/21/15 15:25
92264558003 MW-7 Water 08/20/15 17:10 08/21/15 15:25
92264558004 MW-8 Water 08/20/15 16:20 08/21/15 15:25
92264558005 MW-9 Water 08/20/15 16:55 08/21/15 15:25
92264558006 MW-10 Water 08/20/15 16:40 08/21/15 15:25
92264558007 MW-1R Water 08/21/15 09:45 08/25/15 15:20
92264558008 MW-2 Water 08/21/15 10:30 08/25/15 15:20
92264558009 MW-3 Water 08/21/15 11:25 08/25/15 15:20
92264558010 MW-5 Water 08/21/15 12:00 08/25/15 15:20
92264558011 MW-11 Water 08/21/15 13:35 08/25/15 15:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 3 of 49
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92264558001 MW-4 EPA 6010 15 PASI-AJDA
EPA 8260 51 PASI-CGAW
92264558002 MW-6 EPA 6010 15 PASI-AJDA
EPA 8260 51 PASI-CGAW
92264558003 MW-7 EPA 6010 15 PASI-AJDA
EPA 8260 51 PASI-CGAW
92264558004 MW-8 EPA 6010 15 PASI-AJDA
EPA 8260 51 PASI-CGAW
92264558005 MW-9 EPA 6010 15 PASI-AJDA
EPA 8260 51 PASI-CGAW
92264558006 MW-10 EPA 6010 15 PASI-AJDA
EPA 8260 51 PASI-CGAW
92264558007 MW-1R EPA 6010 15 PASI-AJDA
EPA 8260 51 PASI-CNB
92264558008 MW-2 EPA 6010 15 PASI-AJDA
EPA 8260 51 PASI-CNB
92264558009 MW-3 EPA 6010 15 PASI-AJDA
EPA 8260 51 PASI-CNB
92264558010 MW-5 EPA 6010 15 PASI-AJDA
EPA 8260 51 PASI-CNB
92264558011 MW-11 EPA 6010 15 PASI-AJDA
EPA 8260 51 PASI-CNB
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 4 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Sample:MW-4 Lab ID:92264558001 Collected:08/20/15 16:10 Received:08/21/15 15:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 08/30/15 22:42 7440-36-008/25/15 18:306.0 3.8 1
Arsenic ND ug/L 08/30/15 22:42 7440-38-208/25/15 18:3010.0 2.5 1
Barium 23.2J ug/L 08/30/15 22:42 7440-39-308/25/15 18:301002.5 1
Beryllium ND ug/L 08/30/15 22:42 7440-41-708/25/15 18:301.0 0.50 1
Cadmium 2.2 ug/L 08/30/15 22:42 7440-43-908/25/15 18:301.0 0.50 1
Chromium ND ug/L 08/30/15 22:42 7440-47-308/25/15 18:3010.0 2.5 1
Cobalt ND ug/L 08/30/15 22:42 7440-48-408/25/15 18:3010.0 2.5 1
Copper ND ug/L 08/30/15 22:42 7440-50-808/25/15 18:3010.0 2.5 1
Lead ND ug/L 08/30/15 22:42 7439-92-108/25/15 18:3010.0 2.5 1
Nickel ND ug/L 08/30/15 22:42 7440-02-008/25/15 18:3050.0 2.5 1
Selenium ND ug/L 08/30/15 22:42 7782-49-208/25/15 18:3010.0 5.0 1
Silver ND ug/L 08/30/15 22:42 7440-22-408/25/15 18:3010.0 2.5 1
Thallium ND ug/L 08/30/15 22:42 7440-28-008/25/15 18:305.5 5.0 1
Vanadium ND ug/L 08/30/15 22:42 7440-62-208/25/15 18:3025.0 2.5 1
Zinc ND ug/L 08/30/15 22:42 7440-66-608/25/15 18:3010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 09/03/15 13:44 67-64-110010.0 1
Acrylonitrile ND ug/L 09/03/15 13:44 107-13-12001.9 1
Benzene ND ug/L 09/03/15 13:44 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 09/03/15 13:44 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 09/03/15 13:44 75-27-41.0 0.18 1
Bromoform ND ug/L 09/03/15 13:44 75-25-23.0 0.26 1
Bromomethane ND ug/L 09/03/15 13:44 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 09/03/15 13:44 78-93-31000.96 1
Carbon disulfide ND ug/L 09/03/15 13:44 75-15-01001.2 1
Carbon tetrachloride ND ug/L 09/03/15 13:44 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 09/03/15 13:44 108-90-73.0 0.23 1
Chloroethane ND ug/L 09/03/15 13:44 75-00-310.0 0.54 1
Chloroform ND ug/L 09/03/15 13:44 67-66-35.0 0.14 1
Chloromethane ND ug/L 09/03/15 13:44 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 09/03/15 13:44 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 09/03/15 13:44 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 09/03/15 13:44 106-93-41.0 0.27 1
Dibromomethane ND ug/L 09/03/15 13:44 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 09/03/15 13:44 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 09/03/15 13:44 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 09/03/15 13:44 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 09/03/15 13:44 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 09/03/15 13:44 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 09/03/15 13:44 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 09/03/15 13:44 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 09/03/15 13:44 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 09/03/15 13:44 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 09/03/15 13:44 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 09/03/15 13:44 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 5 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Sample:MW-4 Lab ID:92264558001 Collected:08/20/15 16:10 Received:08/21/15 15:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 09/03/15 13:44 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 09/03/15 13:44 100-41-41.0 0.30 1
2-Hexanone ND ug/L 09/03/15 13:44 591-78-650.0 0.46 1
Iodomethane ND ug/L 09/03/15 13:44 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 09/03/15 13:44 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 09/03/15 13:44 108-10-11000.33 1
Styrene ND ug/L 09/03/15 13:44 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 09/03/15 13:44 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 09/03/15 13:44 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 09/03/15 13:44 127-18-41.0 0.46 1
Toluene ND ug/L 09/03/15 13:44 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 09/03/15 13:44 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 09/03/15 13:44 79-00-51.0 0.29 1
Trichloroethene ND ug/L 09/03/15 13:44 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 09/03/15 13:44 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 09/03/15 13:44 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 09/03/15 13:44 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 09/03/15 13:44 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 09/03/15 13:44 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)101 %09/03/15 13:44 460-00-470-130 1
1,2-Dichloroethane-d4 (S)96 %09/03/15 13:44 17060-07-070-130 1
Toluene-d8 (S)103 %09/03/15 13:44 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Sample:MW-6 Lab ID:92264558002 Collected:08/20/15 17:25 Received:08/21/15 15:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 08/30/15 22:51 7440-36-008/25/15 18:306.0 3.8 1
Arsenic ND ug/L 08/30/15 22:51 7440-38-208/25/15 18:3010.0 2.5 1
Barium 79.7J ug/L 08/30/15 22:51 7440-39-308/25/15 18:301002.5 1
Beryllium ND ug/L 08/30/15 22:51 7440-41-708/25/15 18:301.0 0.50 1
Cadmium 2.5 ug/L 08/30/15 22:51 7440-43-908/25/15 18:301.0 0.50 1
Chromium ND ug/L 08/30/15 22:51 7440-47-308/25/15 18:3010.0 2.5 1
Cobalt ND ug/L 08/30/15 22:51 7440-48-408/25/15 18:3010.0 2.5 1
Copper ND ug/L 08/30/15 22:51 7440-50-808/25/15 18:3010.0 2.5 1
Lead ND ug/L 08/30/15 22:51 7439-92-108/25/15 18:3010.0 2.5 1
Nickel ND ug/L 08/30/15 22:51 7440-02-008/25/15 18:3050.0 2.5 1
Selenium ND ug/L 08/30/15 22:51 7782-49-208/25/15 18:3010.0 5.0 1
Silver ND ug/L 08/30/15 22:51 7440-22-408/25/15 18:3010.0 2.5 1
Thallium ND ug/L 08/30/15 22:51 7440-28-008/25/15 18:305.5 5.0 1
Vanadium ND ug/L 08/30/15 22:51 7440-62-208/25/15 18:3025.0 2.5 1
Zinc ND ug/L 08/30/15 22:51 7440-66-608/25/15 18:3010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 09/01/15 13:57 67-64-110010.0 1
Acrylonitrile ND ug/L 09/01/15 13:57 107-13-12001.9 1
Benzene 0.28J ug/L 09/01/15 13:57 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 09/01/15 13:57 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 09/01/15 13:57 75-27-41.0 0.18 1
Bromoform ND ug/L 09/01/15 13:57 75-25-23.0 0.26 1
Bromomethane ND ug/L 09/01/15 13:57 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 09/01/15 13:57 78-93-31000.96 1
Carbon disulfide ND ug/L 09/01/15 13:57 75-15-01001.2 1
Carbon tetrachloride ND ug/L 09/01/15 13:57 56-23-51.0 0.25 1
Chlorobenzene 1.0J ug/L 09/01/15 13:57 108-90-73.0 0.23 1
Chloroethane ND ug/L 09/01/15 13:57 75-00-310.0 0.54 1
Chloroform ND ug/L 09/01/15 13:57 67-66-35.0 0.14 1
Chloromethane ND ug/L 09/01/15 13:57 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 13:57 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 09/01/15 13:57 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 09/01/15 13:57 106-93-41.0 0.27 1
Dibromomethane ND ug/L 09/01/15 13:57 74-95-310.0 0.21 1
1,2-Dichlorobenzene 0.37J ug/L 09/01/15 13:57 95-50-15.0 0.30 1
1,4-Dichlorobenzene 0.63J ug/L 09/01/15 13:57 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 13:57 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 09/01/15 13:57 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 09/01/15 13:57 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 09/01/15 13:57 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 0.31J ug/L 09/01/15 13:57 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 09/01/15 13:57 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 09/01/15 13:57 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 09/01/15 13:57 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 09/01/15 13:57 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Sample:MW-6 Lab ID:92264558002 Collected:08/20/15 17:25 Received:08/21/15 15:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 09/01/15 13:57 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 09/01/15 13:57 100-41-41.0 0.30 1
2-Hexanone ND ug/L 09/01/15 13:57 591-78-650.0 0.46 1
Iodomethane 0.42J ug/L 09/01/15 13:57 74-88-4 B,C910.0 0.32 1
Methylene Chloride ND ug/L 09/01/15 13:57 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 13:57 108-10-11000.33 1
Styrene ND ug/L 09/01/15 13:57 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 13:57 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 13:57 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 09/01/15 13:57 127-18-41.0 0.46 1
Toluene ND ug/L 09/01/15 13:57 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 09/01/15 13:57 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 09/01/15 13:57 79-00-51.0 0.29 1
Trichloroethene ND ug/L 09/01/15 13:57 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 09/01/15 13:57 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 09/01/15 13:57 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 09/01/15 13:57 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 09/01/15 13:57 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 09/01/15 13:57 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)102 %09/01/15 13:57 460-00-470-130 1
1,2-Dichloroethane-d4 (S)96 %09/01/15 13:57 17060-07-070-130 1
Toluene-d8 (S)101 %09/01/15 13:57 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Sample:MW-7 Lab ID:92264558003 Collected:08/20/15 17:10 Received:08/21/15 15:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 08/30/15 22:54 7440-36-008/25/15 18:306.0 3.8 1
Arsenic ND ug/L 08/30/15 22:54 7440-38-208/25/15 18:3010.0 2.5 1
Barium 25.9J ug/L 08/30/15 22:54 7440-39-308/25/15 18:301002.5 1
Beryllium ND ug/L 08/30/15 22:54 7440-41-708/25/15 18:301.0 0.50 1
Cadmium ND ug/L 08/30/15 22:54 7440-43-908/25/15 18:301.0 0.50 1
Chromium ND ug/L 08/30/15 22:54 7440-47-308/25/15 18:3010.0 2.5 1
Cobalt ND ug/L 08/30/15 22:54 7440-48-408/25/15 18:3010.0 2.5 1
Copper ND ug/L 08/30/15 22:54 7440-50-808/25/15 18:3010.0 2.5 1
Lead 2.8J ug/L 08/30/15 22:54 7439-92-108/25/15 18:3010.0 2.5 1
Nickel ND ug/L 08/30/15 22:54 7440-02-008/25/15 18:3050.0 2.5 1
Selenium ND ug/L 08/30/15 22:54 7782-49-208/25/15 18:3010.0 5.0 1
Silver ND ug/L 08/30/15 22:54 7440-22-408/25/15 18:3010.0 2.5 1
Thallium ND ug/L 08/30/15 22:54 7440-28-008/25/15 18:305.5 5.0 1
Vanadium 4.8J ug/L 08/30/15 22:54 7440-62-208/25/15 18:3025.0 2.5 1
Zinc ND ug/L 08/30/15 22:54 7440-66-608/25/15 18:3010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 09/01/15 14:15 67-64-110010.0 1
Acrylonitrile ND ug/L 09/01/15 14:15 107-13-12001.9 1
Benzene ND ug/L 09/01/15 14:15 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 09/01/15 14:15 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 09/01/15 14:15 75-27-41.0 0.18 1
Bromoform ND ug/L 09/01/15 14:15 75-25-23.0 0.26 1
Bromomethane ND ug/L 09/01/15 14:15 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 09/01/15 14:15 78-93-31000.96 1
Carbon disulfide ND ug/L 09/01/15 14:15 75-15-01001.2 1
Carbon tetrachloride ND ug/L 09/01/15 14:15 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 09/01/15 14:15 108-90-73.0 0.23 1
Chloroethane ND ug/L 09/01/15 14:15 75-00-310.0 0.54 1
Chloroform ND ug/L 09/01/15 14:15 67-66-35.0 0.14 1
Chloromethane ND ug/L 09/01/15 14:15 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 14:15 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 09/01/15 14:15 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 09/01/15 14:15 106-93-41.0 0.27 1
Dibromomethane ND ug/L 09/01/15 14:15 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 09/01/15 14:15 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 09/01/15 14:15 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 14:15 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 09/01/15 14:15 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 09/01/15 14:15 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 09/01/15 14:15 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 09/01/15 14:15 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 09/01/15 14:15 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 09/01/15 14:15 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 09/01/15 14:15 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 09/01/15 14:15 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Sample:MW-7 Lab ID:92264558003 Collected:08/20/15 17:10 Received:08/21/15 15:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 09/01/15 14:15 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 09/01/15 14:15 100-41-41.0 0.30 1
2-Hexanone ND ug/L 09/01/15 14:15 591-78-650.0 0.46 1
Iodomethane 0.36J ug/L 09/01/15 14:15 74-88-4 B,C910.0 0.32 1
Methylene Chloride ND ug/L 09/01/15 14:15 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 14:15 108-10-11000.33 1
Styrene ND ug/L 09/01/15 14:15 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 14:15 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 14:15 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 09/01/15 14:15 127-18-41.0 0.46 1
Toluene ND ug/L 09/01/15 14:15 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 09/01/15 14:15 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 09/01/15 14:15 79-00-51.0 0.29 1
Trichloroethene ND ug/L 09/01/15 14:15 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 09/01/15 14:15 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 09/01/15 14:15 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 09/01/15 14:15 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 09/01/15 14:15 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 09/01/15 14:15 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %09/01/15 14:15 460-00-470-130 1
1,2-Dichloroethane-d4 (S)94 %09/01/15 14:15 17060-07-070-130 1
Toluene-d8 (S)102 %09/01/15 14:15 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Sample:MW-8 Lab ID:92264558004 Collected:08/20/15 16:20 Received:08/21/15 15:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 08/30/15 22:57 7440-36-008/25/15 18:306.0 3.8 1
Arsenic ND ug/L 08/30/15 22:57 7440-38-208/25/15 18:3010.0 2.5 1
Barium 97.1J ug/L 08/30/15 22:57 7440-39-308/25/15 18:301002.5 1
Beryllium ND ug/L 08/30/15 22:57 7440-41-708/25/15 18:301.0 0.50 1
Cadmium ND ug/L 08/30/15 22:57 7440-43-908/25/15 18:301.0 0.50 1
Chromium ND ug/L 08/30/15 22:57 7440-47-308/25/15 18:3010.0 2.5 1
Cobalt ND ug/L 08/30/15 22:57 7440-48-408/25/15 18:3010.0 2.5 1
Copper ND ug/L 08/30/15 22:57 7440-50-808/25/15 18:3010.0 2.5 1
Lead ND ug/L 08/30/15 22:57 7439-92-108/25/15 18:3010.0 2.5 1
Nickel ND ug/L 08/30/15 22:57 7440-02-008/25/15 18:3050.0 2.5 1
Selenium ND ug/L 08/30/15 22:57 7782-49-208/25/15 18:3010.0 5.0 1
Silver ND ug/L 08/30/15 22:57 7440-22-408/25/15 18:3010.0 2.5 1
Thallium ND ug/L 08/30/15 22:57 7440-28-008/25/15 18:305.5 5.0 1
Vanadium ND ug/L 08/30/15 22:57 7440-62-208/25/15 18:3025.0 2.5 1
Zinc 6.8J ug/L 08/30/15 22:57 7440-66-608/25/15 18:3010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 09/01/15 14:32 67-64-110010.0 1
Acrylonitrile ND ug/L 09/01/15 14:32 107-13-12001.9 1
Benzene ND ug/L 09/01/15 14:32 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 09/01/15 14:32 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 09/01/15 14:32 75-27-41.0 0.18 1
Bromoform ND ug/L 09/01/15 14:32 75-25-23.0 0.26 1
Bromomethane ND ug/L 09/01/15 14:32 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 09/01/15 14:32 78-93-31000.96 1
Carbon disulfide ND ug/L 09/01/15 14:32 75-15-01001.2 1
Carbon tetrachloride ND ug/L 09/01/15 14:32 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 09/01/15 14:32 108-90-73.0 0.23 1
Chloroethane ND ug/L 09/01/15 14:32 75-00-310.0 0.54 1
Chloroform ND ug/L 09/01/15 14:32 67-66-35.0 0.14 1
Chloromethane ND ug/L 09/01/15 14:32 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 14:32 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 09/01/15 14:32 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 09/01/15 14:32 106-93-41.0 0.27 1
Dibromomethane ND ug/L 09/01/15 14:32 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 09/01/15 14:32 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 09/01/15 14:32 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 14:32 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 09/01/15 14:32 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 09/01/15 14:32 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 09/01/15 14:32 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 09/01/15 14:32 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 09/01/15 14:32 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 09/01/15 14:32 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 09/01/15 14:32 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 09/01/15 14:32 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Sample:MW-8 Lab ID:92264558004 Collected:08/20/15 16:20 Received:08/21/15 15:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 09/01/15 14:32 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 09/01/15 14:32 100-41-41.0 0.30 1
2-Hexanone ND ug/L 09/01/15 14:32 591-78-650.0 0.46 1
Iodomethane 0.36J ug/L 09/01/15 14:32 74-88-4 B,C910.0 0.32 1
Methylene Chloride ND ug/L 09/01/15 14:32 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 14:32 108-10-11000.33 1
Styrene ND ug/L 09/01/15 14:32 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 14:32 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 14:32 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 09/01/15 14:32 127-18-41.0 0.46 1
Toluene ND ug/L 09/01/15 14:32 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 09/01/15 14:32 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 09/01/15 14:32 79-00-51.0 0.29 1
Trichloroethene ND ug/L 09/01/15 14:32 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 09/01/15 14:32 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 09/01/15 14:32 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 09/01/15 14:32 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 09/01/15 14:32 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 09/01/15 14:32 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %09/01/15 14:32 460-00-470-130 1
1,2-Dichloroethane-d4 (S)95 %09/01/15 14:32 17060-07-070-130 1
Toluene-d8 (S)101 %09/01/15 14:32 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Sample:MW-9 Lab ID:92264558005 Collected:08/20/15 16:55 Received:08/21/15 15:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 08/30/15 23:00 7440-36-008/25/15 18:306.0 3.8 1
Arsenic ND ug/L 08/30/15 23:00 7440-38-208/25/15 18:3010.0 2.5 1
Barium 15.0J ug/L 08/30/15 23:00 7440-39-308/25/15 18:301002.5 1
Beryllium ND ug/L 08/30/15 23:00 7440-41-708/25/15 18:301.0 0.50 1
Cadmium ND ug/L 08/30/15 23:00 7440-43-908/25/15 18:301.0 0.50 1
Chromium ND ug/L 08/30/15 23:00 7440-47-308/25/15 18:3010.0 2.5 1
Cobalt ND ug/L 08/30/15 23:00 7440-48-408/25/15 18:3010.0 2.5 1
Copper ND ug/L 08/30/15 23:00 7440-50-808/25/15 18:3010.0 2.5 1
Lead ND ug/L 08/30/15 23:00 7439-92-108/25/15 18:3010.0 2.5 1
Nickel ND ug/L 08/30/15 23:00 7440-02-008/25/15 18:3050.0 2.5 1
Selenium ND ug/L 08/30/15 23:00 7782-49-208/25/15 18:3010.0 5.0 1
Silver ND ug/L 08/30/15 23:00 7440-22-408/25/15 18:3010.0 2.5 1
Thallium ND ug/L 08/30/15 23:00 7440-28-008/25/15 18:305.5 5.0 1
Vanadium ND ug/L 08/30/15 23:00 7440-62-208/25/15 18:3025.0 2.5 1
Zinc ND ug/L 08/30/15 23:00 7440-66-608/25/15 18:3010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 09/01/15 14:49 67-64-110010.0 1
Acrylonitrile ND ug/L 09/01/15 14:49 107-13-12001.9 1
Benzene ND ug/L 09/01/15 14:49 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 09/01/15 14:49 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 09/01/15 14:49 75-27-41.0 0.18 1
Bromoform ND ug/L 09/01/15 14:49 75-25-23.0 0.26 1
Bromomethane ND ug/L 09/01/15 14:49 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 09/01/15 14:49 78-93-31000.96 1
Carbon disulfide ND ug/L 09/01/15 14:49 75-15-01001.2 1
Carbon tetrachloride ND ug/L 09/01/15 14:49 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 09/01/15 14:49 108-90-73.0 0.23 1
Chloroethane ND ug/L 09/01/15 14:49 75-00-310.0 0.54 1
Chloroform 0.70J ug/L 09/01/15 14:49 67-66-35.0 0.14 1
Chloromethane ND ug/L 09/01/15 14:49 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 14:49 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 09/01/15 14:49 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 09/01/15 14:49 106-93-41.0 0.27 1
Dibromomethane ND ug/L 09/01/15 14:49 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 09/01/15 14:49 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 09/01/15 14:49 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 14:49 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 09/01/15 14:49 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 09/01/15 14:49 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 09/01/15 14:49 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 09/01/15 14:49 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 09/01/15 14:49 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 09/01/15 14:49 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 09/01/15 14:49 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 09/01/15 14:49 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Sample:MW-9 Lab ID:92264558005 Collected:08/20/15 16:55 Received:08/21/15 15:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 09/01/15 14:49 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 09/01/15 14:49 100-41-41.0 0.30 1
2-Hexanone ND ug/L 09/01/15 14:49 591-78-650.0 0.46 1
Iodomethane ND ug/L 09/01/15 14:49 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 09/01/15 14:49 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 14:49 108-10-11000.33 1
Styrene ND ug/L 09/01/15 14:49 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 14:49 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 14:49 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 09/01/15 14:49 127-18-41.0 0.46 1
Toluene ND ug/L 09/01/15 14:49 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 09/01/15 14:49 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 09/01/15 14:49 79-00-51.0 0.29 1
Trichloroethene ND ug/L 09/01/15 14:49 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 09/01/15 14:49 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 09/01/15 14:49 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 09/01/15 14:49 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 09/01/15 14:49 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 09/01/15 14:49 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)101 %09/01/15 14:49 460-00-470-130 1
1,2-Dichloroethane-d4 (S)95 %09/01/15 14:49 17060-07-070-130 1
Toluene-d8 (S)102 %09/01/15 14:49 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Sample:MW-10 Lab ID:92264558006 Collected:08/20/15 16:40 Received:08/21/15 15:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 08/30/15 23:03 7440-36-008/25/15 18:306.0 3.8 1
Arsenic ND ug/L 08/30/15 23:03 7440-38-208/25/15 18:3010.0 2.5 1
Barium 377 ug/L 08/30/15 23:03 7440-39-308/25/15 18:301002.5 1
Beryllium ND ug/L 08/30/15 23:03 7440-41-708/25/15 18:301.0 0.50 1
Cadmium 2.1 ug/L 08/30/15 23:03 7440-43-908/25/15 18:301.0 0.50 1
Chromium 16.9 ug/L 08/30/15 23:03 7440-47-308/25/15 18:3010.0 2.5 1
Cobalt ND ug/L 08/30/15 23:03 7440-48-408/25/15 18:3010.0 2.5 1
Copper ND ug/L 08/30/15 23:03 7440-50-808/25/15 18:3010.0 2.5 1
Lead ND ug/L 08/30/15 23:03 7439-92-108/25/15 18:3010.0 2.5 1
Nickel 15.7J ug/L 08/30/15 23:03 7440-02-008/25/15 18:3050.0 2.5 1
Selenium ND ug/L 08/30/15 23:03 7782-49-208/25/15 18:3010.0 5.0 1
Silver ND ug/L 08/30/15 23:03 7440-22-408/25/15 18:3010.0 2.5 1
Thallium ND ug/L 08/30/15 23:03 7440-28-008/25/15 18:305.5 5.0 1
Vanadium ND ug/L 08/30/15 23:03 7440-62-208/25/15 18:3025.0 2.5 1
Zinc 9.6J ug/L 08/30/15 23:03 7440-66-608/25/15 18:3010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 09/01/15 15:06 67-64-110010.0 1
Acrylonitrile ND ug/L 09/01/15 15:06 107-13-12001.9 1
Benzene ND ug/L 09/01/15 15:06 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 09/01/15 15:06 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 09/01/15 15:06 75-27-41.0 0.18 1
Bromoform ND ug/L 09/01/15 15:06 75-25-23.0 0.26 1
Bromomethane ND ug/L 09/01/15 15:06 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 09/01/15 15:06 78-93-31000.96 1
Carbon disulfide ND ug/L 09/01/15 15:06 75-15-01001.2 1
Carbon tetrachloride ND ug/L 09/01/15 15:06 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 09/01/15 15:06 108-90-73.0 0.23 1
Chloroethane ND ug/L 09/01/15 15:06 75-00-310.0 0.54 1
Chloroform ND ug/L 09/01/15 15:06 67-66-35.0 0.14 1
Chloromethane ND ug/L 09/01/15 15:06 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 15:06 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 09/01/15 15:06 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 09/01/15 15:06 106-93-41.0 0.27 1
Dibromomethane ND ug/L 09/01/15 15:06 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 09/01/15 15:06 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 09/01/15 15:06 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 15:06 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 09/01/15 15:06 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 09/01/15 15:06 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 09/01/15 15:06 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 09/01/15 15:06 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 09/01/15 15:06 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 09/01/15 15:06 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 09/01/15 15:06 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 09/01/15 15:06 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 15 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Sample:MW-10 Lab ID:92264558006 Collected:08/20/15 16:40 Received:08/21/15 15:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 09/01/15 15:06 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 09/01/15 15:06 100-41-41.0 0.30 1
2-Hexanone ND ug/L 09/01/15 15:06 591-78-650.0 0.46 1
Iodomethane ND ug/L 09/01/15 15:06 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 09/01/15 15:06 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 15:06 108-10-11000.33 1
Styrene ND ug/L 09/01/15 15:06 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 15:06 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 15:06 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 09/01/15 15:06 127-18-41.0 0.46 1
Toluene ND ug/L 09/01/15 15:06 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 09/01/15 15:06 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 09/01/15 15:06 79-00-51.0 0.29 1
Trichloroethene ND ug/L 09/01/15 15:06 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 09/01/15 15:06 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 09/01/15 15:06 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 09/01/15 15:06 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 09/01/15 15:06 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 09/01/15 15:06 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %09/01/15 15:06 460-00-470-130 1
1,2-Dichloroethane-d4 (S)95 %09/01/15 15:06 17060-07-070-130 1
Toluene-d8 (S)102 %09/01/15 15:06 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Sample:MW-1R Lab ID:92264558007 Collected:08/21/15 09:45 Received:08/25/15 15:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 08/31/15 01:39 7440-36-008/27/15 20:006.0 3.8 1
Arsenic ND ug/L 08/31/15 01:39 7440-38-208/27/15 20:0010.0 2.5 1
Barium 8.6J ug/L 08/31/15 01:39 7440-39-308/27/15 20:001002.5 1
Beryllium ND ug/L 08/31/15 01:39 7440-41-708/27/15 20:001.0 0.50 1
Cadmium ND ug/L 08/31/15 01:39 7440-43-908/27/15 20:001.0 0.50 1
Chromium ND ug/L 08/31/15 01:39 7440-47-308/27/15 20:0010.0 2.5 1
Cobalt ND ug/L 08/31/15 01:39 7440-48-408/27/15 20:0010.0 2.5 1
Copper ND ug/L 08/31/15 01:39 7440-50-808/27/15 20:0010.0 2.5 1
Lead ND ug/L 08/31/15 01:39 7439-92-108/27/15 20:0010.0 2.5 1
Nickel ND ug/L 08/31/15 01:39 7440-02-008/27/15 20:0050.0 2.5 1
Selenium ND ug/L 08/31/15 01:39 7782-49-208/27/15 20:0010.0 5.0 1
Silver ND ug/L 08/31/15 01:39 7440-22-408/27/15 20:0010.0 2.5 1
Thallium ND ug/L 08/31/15 01:39 7440-28-008/27/15 20:005.5 5.0 1
Vanadium ND ug/L 08/31/15 01:39 7440-62-208/27/15 20:0025.0 2.5 1
Zinc ND ug/L 08/31/15 01:39 7440-66-608/27/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 09/01/15 16:10 67-64-110010.0 1
Acrylonitrile ND ug/L 09/01/15 16:10 107-13-12001.9 1
Benzene ND ug/L 09/01/15 16:10 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 09/01/15 16:10 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 09/01/15 16:10 75-27-41.0 0.18 1
Bromoform ND ug/L 09/01/15 16:10 75-25-23.0 0.26 1
Bromomethane ND ug/L 09/01/15 16:10 74-83-9 M110.0 0.29 1
2-Butanone (MEK)ND ug/L 09/01/15 16:10 78-93-31000.96 1
Carbon disulfide ND ug/L 09/01/15 16:10 75-15-01001.2 1
Carbon tetrachloride ND ug/L 09/01/15 16:10 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 09/01/15 16:10 108-90-73.0 0.23 1
Chloroethane ND ug/L 09/01/15 16:10 75-00-310.0 0.54 1
Chloroform 0.55J ug/L 09/01/15 16:10 67-66-35.0 0.14 1
Chloromethane ND ug/L 09/01/15 16:10 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 16:10 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 09/01/15 16:10 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 09/01/15 16:10 106-93-41.0 0.27 1
Dibromomethane ND ug/L 09/01/15 16:10 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 09/01/15 16:10 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 09/01/15 16:10 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 16:10 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 09/01/15 16:10 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 09/01/15 16:10 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 09/01/15 16:10 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 09/01/15 16:10 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 09/01/15 16:10 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 09/01/15 16:10 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 09/01/15 16:10 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 09/01/15 16:10 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Sample:MW-1R Lab ID:92264558007 Collected:08/21/15 09:45 Received:08/25/15 15:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 09/01/15 16:10 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 09/01/15 16:10 100-41-41.0 0.30 1
2-Hexanone ND ug/L 09/01/15 16:10 591-78-650.0 0.46 1
Iodomethane ND ug/L 09/01/15 16:10 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 09/01/15 16:10 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 16:10 108-10-11000.33 1
Styrene ND ug/L 09/01/15 16:10 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 16:10 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 16:10 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 09/01/15 16:10 127-18-41.0 0.46 1
Toluene ND ug/L 09/01/15 16:10 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 09/01/15 16:10 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 09/01/15 16:10 79-00-51.0 0.29 1
Trichloroethene ND ug/L 09/01/15 16:10 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 09/01/15 16:10 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 09/01/15 16:10 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 09/01/15 16:10 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 09/01/15 16:10 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 09/01/15 16:10 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)101 %09/01/15 16:10 460-00-470-130 1
1,2-Dichloroethane-d4 (S)117 %09/01/15 16:10 17060-07-070-130 1
Toluene-d8 (S)100 %09/01/15 16:10 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Sample:MW-2 Lab ID:92264558008 Collected:08/21/15 10:30 Received:08/25/15 15:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 08/31/15 01:57 7440-36-008/27/15 20:006.0 3.8 1
Arsenic 13.8 ug/L 08/31/15 01:57 7440-38-208/27/15 20:0010.0 2.5 1
Barium 147 ug/L 08/31/15 01:57 7440-39-308/27/15 20:001002.5 1
Beryllium ND ug/L 08/31/15 01:57 7440-41-708/27/15 20:001.0 0.50 1
Cadmium ND ug/L 08/31/15 01:57 7440-43-908/27/15 20:001.0 0.50 1
Chromium ND ug/L 08/31/15 01:57 7440-47-308/27/15 20:0010.0 2.5 1
Cobalt ND ug/L 08/31/15 01:57 7440-48-408/27/15 20:0010.0 2.5 1
Copper ND ug/L 08/31/15 01:57 7440-50-808/27/15 20:0010.0 2.5 1
Lead 4.1J ug/L 08/31/15 01:57 7439-92-108/27/15 20:0010.0 2.5 1
Nickel ND ug/L 08/31/15 01:57 7440-02-008/27/15 20:0050.0 2.5 1
Selenium ND ug/L 08/31/15 01:57 7782-49-208/27/15 20:0010.0 5.0 1
Silver ND ug/L 08/31/15 01:57 7440-22-408/27/15 20:0010.0 2.5 1
Thallium ND ug/L 08/31/15 01:57 7440-28-008/27/15 20:005.5 5.0 1
Vanadium 3.6J ug/L 08/31/15 01:57 7440-62-208/27/15 20:0025.0 2.5 1
Zinc ND ug/L 08/31/15 01:57 7440-66-608/27/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 09/01/15 16:27 67-64-110010.0 1
Acrylonitrile ND ug/L 09/01/15 16:27 107-13-12001.9 1
Benzene 0.99J ug/L 09/01/15 16:27 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 09/01/15 16:27 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 09/01/15 16:27 75-27-41.0 0.18 1
Bromoform ND ug/L 09/01/15 16:27 75-25-23.0 0.26 1
Bromomethane ND ug/L 09/01/15 16:27 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 09/01/15 16:27 78-93-31000.96 1
Carbon disulfide ND ug/L 09/01/15 16:27 75-15-01001.2 1
Carbon tetrachloride ND ug/L 09/01/15 16:27 56-23-51.0 0.25 1
Chlorobenzene 12.4 ug/L 09/01/15 16:27 108-90-73.0 0.23 1
Chloroethane ND ug/L 09/01/15 16:27 75-00-310.0 0.54 1
Chloroform ND ug/L 09/01/15 16:27 67-66-35.0 0.14 1
Chloromethane ND ug/L 09/01/15 16:27 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 16:27 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 09/01/15 16:27 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 09/01/15 16:27 106-93-41.0 0.27 1
Dibromomethane ND ug/L 09/01/15 16:27 74-95-310.0 0.21 1
1,2-Dichlorobenzene 0.32J ug/L 09/01/15 16:27 95-50-15.0 0.30 1
1,4-Dichlorobenzene 2.3 ug/L 09/01/15 16:27 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 16:27 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 09/01/15 16:27 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 09/01/15 16:27 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 09/01/15 16:27 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 09/01/15 16:27 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 09/01/15 16:27 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 09/01/15 16:27 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 09/01/15 16:27 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 09/01/15 16:27 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Sample:MW-2 Lab ID:92264558008 Collected:08/21/15 10:30 Received:08/25/15 15:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 09/01/15 16:27 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 09/01/15 16:27 100-41-41.0 0.30 1
2-Hexanone ND ug/L 09/01/15 16:27 591-78-650.0 0.46 1
Iodomethane ND ug/L 09/01/15 16:27 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 09/01/15 16:27 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 16:27 108-10-11000.33 1
Styrene ND ug/L 09/01/15 16:27 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 16:27 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 16:27 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 09/01/15 16:27 127-18-41.0 0.46 1
Toluene ND ug/L 09/01/15 16:27 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 09/01/15 16:27 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 09/01/15 16:27 79-00-51.0 0.29 1
Trichloroethene ND ug/L 09/01/15 16:27 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 09/01/15 16:27 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 09/01/15 16:27 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 09/01/15 16:27 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 09/01/15 16:27 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 09/01/15 16:27 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)103 %09/01/15 16:27 460-00-470-130 1
1,2-Dichloroethane-d4 (S)117 %09/01/15 16:27 17060-07-070-130 1
Toluene-d8 (S)103 %09/01/15 16:27 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Sample:MW-3 Lab ID:92264558009 Collected:08/21/15 11:25 Received:08/25/15 15:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 08/31/15 02:00 7440-36-008/27/15 20:006.0 3.8 1
Arsenic ND ug/L 08/31/15 02:00 7440-38-208/27/15 20:0010.0 2.5 1
Barium 18.1J ug/L 08/31/15 02:00 7440-39-308/27/15 20:001002.5 1
Beryllium ND ug/L 08/31/15 02:00 7440-41-708/27/15 20:001.0 0.50 1
Cadmium 24.8 ug/L 08/31/15 02:00 7440-43-908/27/15 20:001.0 0.50 1
Chromium ND ug/L 08/31/15 02:00 7440-47-308/27/15 20:0010.0 2.5 1
Cobalt ND ug/L 08/31/15 02:00 7440-48-408/27/15 20:0010.0 2.5 1
Copper 5.7J ug/L 08/31/15 02:00 7440-50-808/27/15 20:0010.0 2.5 1
Lead ND ug/L 08/31/15 02:00 7439-92-108/27/15 20:0010.0 2.5 1
Nickel 14.4J ug/L 08/31/15 02:00 7440-02-008/27/15 20:0050.0 2.5 1
Selenium ND ug/L 08/31/15 02:00 7782-49-208/27/15 20:0010.0 5.0 1
Silver ND ug/L 08/31/15 02:00 7440-22-408/27/15 20:0010.0 2.5 1
Thallium ND ug/L 08/31/15 02:00 7440-28-008/27/15 20:005.5 5.0 1
Vanadium 7.8J ug/L 08/31/15 02:00 7440-62-208/27/15 20:0025.0 2.5 1
Zinc 13.8 ug/L 08/31/15 02:00 7440-66-608/27/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 09/01/15 16:44 67-64-110010.0 1
Acrylonitrile ND ug/L 09/01/15 16:44 107-13-12001.9 1
Benzene ND ug/L 09/01/15 16:44 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 09/01/15 16:44 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 09/01/15 16:44 75-27-41.0 0.18 1
Bromoform ND ug/L 09/01/15 16:44 75-25-23.0 0.26 1
Bromomethane ND ug/L 09/01/15 16:44 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 09/01/15 16:44 78-93-31000.96 1
Carbon disulfide ND ug/L 09/01/15 16:44 75-15-01001.2 1
Carbon tetrachloride ND ug/L 09/01/15 16:44 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 09/01/15 16:44 108-90-73.0 0.23 1
Chloroethane ND ug/L 09/01/15 16:44 75-00-310.0 0.54 1
Chloroform ND ug/L 09/01/15 16:44 67-66-35.0 0.14 1
Chloromethane ND ug/L 09/01/15 16:44 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 16:44 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 09/01/15 16:44 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 09/01/15 16:44 106-93-41.0 0.27 1
Dibromomethane ND ug/L 09/01/15 16:44 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 09/01/15 16:44 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 09/01/15 16:44 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 16:44 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 09/01/15 16:44 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 09/01/15 16:44 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 09/01/15 16:44 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 09/01/15 16:44 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 09/01/15 16:44 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 09/01/15 16:44 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 09/01/15 16:44 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 09/01/15 16:44 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
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Page 21 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Sample:MW-3 Lab ID:92264558009 Collected:08/21/15 11:25 Received:08/25/15 15:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 09/01/15 16:44 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 09/01/15 16:44 100-41-41.0 0.30 1
2-Hexanone ND ug/L 09/01/15 16:44 591-78-650.0 0.46 1
Iodomethane ND ug/L 09/01/15 16:44 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 09/01/15 16:44 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 16:44 108-10-11000.33 1
Styrene ND ug/L 09/01/15 16:44 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 16:44 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 16:44 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 09/01/15 16:44 127-18-41.0 0.46 1
Toluene ND ug/L 09/01/15 16:44 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 09/01/15 16:44 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 09/01/15 16:44 79-00-51.0 0.29 1
Trichloroethene ND ug/L 09/01/15 16:44 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 09/01/15 16:44 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 09/01/15 16:44 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 09/01/15 16:44 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 09/01/15 16:44 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 09/01/15 16:44 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %09/01/15 16:44 460-00-470-130 1
1,2-Dichloroethane-d4 (S)117 %09/01/15 16:44 17060-07-070-130 1
Toluene-d8 (S)101 %09/01/15 16:44 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
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Page 22 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Sample:MW-5 Lab ID:92264558010 Collected:08/21/15 12:00 Received:08/25/15 15:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 08/31/15 02:03 7440-36-008/27/15 20:006.0 3.8 1
Arsenic ND ug/L 08/31/15 02:03 7440-38-208/27/15 20:0010.0 2.5 1
Barium 38.0J ug/L 08/31/15 02:03 7440-39-308/27/15 20:001002.5 1
Beryllium ND ug/L 08/31/15 02:03 7440-41-708/27/15 20:001.0 0.50 1
Cadmium 1.4 ug/L 08/31/15 02:03 7440-43-908/27/15 20:001.0 0.50 1
Chromium ND ug/L 08/31/15 02:03 7440-47-308/27/15 20:0010.0 2.5 1
Cobalt ND ug/L 08/31/15 02:03 7440-48-408/27/15 20:0010.0 2.5 1
Copper ND ug/L 08/31/15 02:03 7440-50-808/27/15 20:0010.0 2.5 1
Lead ND ug/L 08/31/15 02:03 7439-92-108/27/15 20:0010.0 2.5 1
Nickel ND ug/L 08/31/15 02:03 7440-02-008/27/15 20:0050.0 2.5 1
Selenium ND ug/L 08/31/15 02:03 7782-49-208/27/15 20:0010.0 5.0 1
Silver ND ug/L 08/31/15 02:03 7440-22-408/27/15 20:0010.0 2.5 1
Thallium ND ug/L 08/31/15 02:03 7440-28-008/27/15 20:005.5 5.0 1
Vanadium ND ug/L 08/31/15 02:03 7440-62-208/27/15 20:0025.0 2.5 1
Zinc 11.7 ug/L 08/31/15 02:03 7440-66-608/27/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 09/01/15 17:01 67-64-110010.0 1
Acrylonitrile ND ug/L 09/01/15 17:01 107-13-12001.9 1
Benzene ND ug/L 09/01/15 17:01 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 09/01/15 17:01 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 09/01/15 17:01 75-27-41.0 0.18 1
Bromoform ND ug/L 09/01/15 17:01 75-25-23.0 0.26 1
Bromomethane ND ug/L 09/01/15 17:01 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 09/01/15 17:01 78-93-31000.96 1
Carbon disulfide ND ug/L 09/01/15 17:01 75-15-01001.2 1
Carbon tetrachloride ND ug/L 09/01/15 17:01 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 09/01/15 17:01 108-90-73.0 0.23 1
Chloroethane ND ug/L 09/01/15 17:01 75-00-310.0 0.54 1
Chloroform ND ug/L 09/01/15 17:01 67-66-35.0 0.14 1
Chloromethane ND ug/L 09/01/15 17:01 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 17:01 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 09/01/15 17:01 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 09/01/15 17:01 106-93-41.0 0.27 1
Dibromomethane ND ug/L 09/01/15 17:01 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 09/01/15 17:01 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 09/01/15 17:01 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 17:01 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 09/01/15 17:01 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 09/01/15 17:01 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 09/01/15 17:01 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 09/01/15 17:01 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 09/01/15 17:01 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 09/01/15 17:01 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 09/01/15 17:01 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 09/01/15 17:01 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
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Huntersville, NC 28078
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Page 23 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Sample:MW-5 Lab ID:92264558010 Collected:08/21/15 12:00 Received:08/25/15 15:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 09/01/15 17:01 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 09/01/15 17:01 100-41-41.0 0.30 1
2-Hexanone ND ug/L 09/01/15 17:01 591-78-650.0 0.46 1
Iodomethane ND ug/L 09/01/15 17:01 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 09/01/15 17:01 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 17:01 108-10-11000.33 1
Styrene ND ug/L 09/01/15 17:01 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 17:01 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 17:01 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 09/01/15 17:01 127-18-41.0 0.46 1
Toluene ND ug/L 09/01/15 17:01 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 09/01/15 17:01 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 09/01/15 17:01 79-00-51.0 0.29 1
Trichloroethene ND ug/L 09/01/15 17:01 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 09/01/15 17:01 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 09/01/15 17:01 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 09/01/15 17:01 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 09/01/15 17:01 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 09/01/15 17:01 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)104 %09/01/15 17:01 460-00-470-130 1
1,2-Dichloroethane-d4 (S)118 %09/01/15 17:01 17060-07-070-130 1
Toluene-d8 (S)102 %09/01/15 17:01 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Sample:MW-11 Lab ID:92264558011 Collected:08/21/15 13:35 Received:08/25/15 15:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 08/31/15 02:06 7440-36-008/27/15 20:006.0 3.8 1
Arsenic ND ug/L 08/31/15 02:06 7440-38-208/27/15 20:0010.0 2.5 1
Barium 72.1J ug/L 08/31/15 02:06 7440-39-308/27/15 20:001002.5 1
Beryllium ND ug/L 08/31/15 02:06 7440-41-708/27/15 20:001.0 0.50 1
Cadmium 2.6 ug/L 08/31/15 02:06 7440-43-908/27/15 20:001.0 0.50 1
Chromium ND ug/L 08/31/15 02:06 7440-47-308/27/15 20:0010.0 2.5 1
Cobalt ND ug/L 08/31/15 02:06 7440-48-408/27/15 20:0010.0 2.5 1
Copper ND ug/L 08/31/15 02:06 7440-50-808/27/15 20:0010.0 2.5 1
Lead ND ug/L 08/31/15 02:06 7439-92-108/27/15 20:0010.0 2.5 1
Nickel 4.1J ug/L 08/31/15 02:06 7440-02-008/27/15 20:0050.0 2.5 1
Selenium ND ug/L 08/31/15 02:06 7782-49-208/27/15 20:0010.0 5.0 1
Silver ND ug/L 08/31/15 02:06 7440-22-408/27/15 20:0010.0 2.5 1
Thallium ND ug/L 08/31/15 02:06 7440-28-008/27/15 20:005.5 5.0 1
Vanadium 3.1J ug/L 08/31/15 02:06 7440-62-208/27/15 20:0025.0 2.5 1
Zinc ND ug/L 08/31/15 02:06 7440-66-608/27/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 09/01/15 17:18 67-64-110010.0 1
Acrylonitrile ND ug/L 09/01/15 17:18 107-13-12001.9 1
Benzene ND ug/L 09/01/15 17:18 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 09/01/15 17:18 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 09/01/15 17:18 75-27-41.0 0.18 1
Bromoform ND ug/L 09/01/15 17:18 75-25-23.0 0.26 1
Bromomethane ND ug/L 09/01/15 17:18 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 09/01/15 17:18 78-93-31000.96 1
Carbon disulfide ND ug/L 09/01/15 17:18 75-15-01001.2 1
Carbon tetrachloride ND ug/L 09/01/15 17:18 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 09/01/15 17:18 108-90-73.0 0.23 1
Chloroethane ND ug/L 09/01/15 17:18 75-00-310.0 0.54 1
Chloroform ND ug/L 09/01/15 17:18 67-66-35.0 0.14 1
Chloromethane 0.21J ug/L 09/01/15 17:18 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 17:18 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 09/01/15 17:18 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 09/01/15 17:18 106-93-41.0 0.27 1
Dibromomethane ND ug/L 09/01/15 17:18 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 09/01/15 17:18 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 09/01/15 17:18 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 17:18 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 09/01/15 17:18 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 09/01/15 17:18 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 09/01/15 17:18 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 09/01/15 17:18 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 09/01/15 17:18 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 09/01/15 17:18 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 09/01/15 17:18 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 09/01/15 17:18 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Sample:MW-11 Lab ID:92264558011 Collected:08/21/15 13:35 Received:08/25/15 15:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 09/01/15 17:18 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 09/01/15 17:18 100-41-41.0 0.30 1
2-Hexanone ND ug/L 09/01/15 17:18 591-78-650.0 0.46 1
Iodomethane ND ug/L 09/01/15 17:18 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 09/01/15 17:18 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 17:18 108-10-11000.33 1
Styrene ND ug/L 09/01/15 17:18 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 17:18 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 17:18 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 09/01/15 17:18 127-18-41.0 0.46 1
Toluene ND ug/L 09/01/15 17:18 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 09/01/15 17:18 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 09/01/15 17:18 79-00-51.0 0.29 1
Trichloroethene ND ug/L 09/01/15 17:18 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 09/01/15 17:18 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 09/01/15 17:18 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 09/01/15 17:18 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 09/01/15 17:18 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 09/01/15 17:18 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)103 %09/01/15 17:18 460-00-470-130 1
1,2-Dichloroethane-d4 (S)118 %09/01/15 17:18 17060-07-070-130 1
Toluene-d8 (S)101 %09/01/15 17:18 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/19334
EPA 3010
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92264558001, 92264558002, 92264558003, 92264558004, 92264558005, 92264558006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1540923
Associated Lab Samples:92264558001, 92264558002, 92264558003, 92264558004, 92264558005, 92264558006
Matrix:Water
Analyzed
Antimony ug/L ND 6.0 08/30/15 22:27
Arsenic ug/L ND 10.0 08/30/15 22:27
Barium ug/L ND 100 08/30/15 22:27
Beryllium ug/L ND 1.0 08/30/15 22:27
Cadmium ug/L ND 1.0 08/30/15 22:27
Chromium ug/L ND 10.0 08/30/15 22:27
Cobalt ug/L ND 10.0 08/30/15 22:27
Copper ug/L ND 10.0 08/30/15 22:27
Lead ug/L ND 10.0 08/30/15 22:27
Nickel ug/L ND 50.0 08/30/15 22:27
Selenium ug/L ND 10.0 08/30/15 22:27
Silver ug/L ND 10.0 08/30/15 22:27
Thallium ug/L ND 5.5 08/30/15 22:27
Vanadium ug/L ND 25.0 08/30/15 22:27
Zinc ug/L ND 10.0 08/30/15 22:27
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1540924LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 392417 94 80-120
Arsenic ug/L 380417 91 80-120
Barium ug/L 396417 95 80-120
Beryllium ug/L 395417 95 80-120
Cadmium ug/L 377417 91 80-120
Chromium ug/L 386417 93 80-120
Cobalt ug/L 387417 93 80-120
Copper ug/L 399417 96 80-120
Lead ug/L 383417 92 80-120
Nickel ug/L 374417 90 80-120
Selenium ug/L 373417 90 80-120
Silver ug/L 194208 93 80-120
Thallium ug/L 395417 95 80-120
Vanadium ug/L 394417 95 80-120
Zinc ug/L 378417 91 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1540925MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92264558001
1540926
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 417 107 75-12591 16 25417ND445380
Arsenic ug/L 417 104 75-12588 16 25417ND432368
Barium ug/L 417 108 75-12592 15 2541723.2J 472 407
Beryllium ug/L 417 108 75-12592 15 25417ND449385
Cadmium ug/L 417 103 75-12587 16 254172.2 430 366
Chromium ug/L 417 104 75-12589 15 25417ND433371
Cobalt ug/L 417 105 75-12590 16 25417ND438374
Copper ug/L 417 108 75-12592 16 25417ND452386
Lead ug/L 417 103 75-12588 16 25417ND430368
Nickel ug/L 417 102 75-12587 16 25417ND423361
Selenium ug/L 417 101 75-12587 15 25417ND425364
Silver ug/L 208 106 75-12590 16 25208ND221189
Thallium ug/L 417 107 75-12591 16 25417ND445381
Vanadium ug/L 417 107 75-12591 16 25417ND445381
Zinc ug/L 417 103 75-12588 16 25417ND431368
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/19358
EPA 3010
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92264558007, 92264558008, 92264558009, 92264558010, 92264558011
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1543211
Associated Lab Samples:92264558007, 92264558008, 92264558009, 92264558010, 92264558011
Matrix:Water
Analyzed
Antimony ug/L ND 6.0 08/31/15 01:33
Arsenic ug/L ND 10.0 08/31/15 01:33
Barium ug/L ND 100 08/31/15 01:33
Beryllium ug/L ND 1.0 08/31/15 01:33
Cadmium ug/L ND 1.0 08/31/15 01:33
Chromium ug/L ND 10.0 08/31/15 01:33
Cobalt ug/L ND 10.0 08/31/15 01:33
Copper ug/L ND 10.0 08/31/15 01:33
Lead ug/L ND 10.0 08/31/15 01:33
Nickel ug/L ND 50.0 08/31/15 01:33
Selenium ug/L ND 10.0 08/31/15 01:33
Silver ug/L ND 10.0 08/31/15 01:33
Thallium ug/L ND 5.5 08/31/15 01:33
Vanadium ug/L ND 25.0 08/31/15 01:33
Zinc ug/L ND 10.0 08/31/15 01:33
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1543212LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 469500 94 80-120
Arsenic ug/L 458500 92 80-120
Barium ug/L 470500 94 80-120
Beryllium ug/L 469500 94 80-120
Cadmium ug/L 453500 91 80-120
Chromium ug/L 456500 91 80-120
Cobalt ug/L 464500 93 80-120
Copper ug/L 473500 95 80-120
Lead ug/L 458500 92 80-120
Nickel ug/L 450500 90 80-120
Selenium ug/L 451500 90 80-120
Silver ug/L 232250 93 80-120
Thallium ug/L 472500 94 80-120
Vanadium ug/L 467500 93 80-120
Zinc ug/L 453500 91 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1543213MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92264558007
1543214
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 104 75-12592 12 25500ND521462
Arsenic ug/L 500 102 75-12591 11 25500ND508454
Barium ug/L 500 105 75-12594 11 255008.6J 535 480
Beryllium ug/L 500 105 75-12594 11 25500ND525471
Cadmium ug/L 500 101 75-12590 11 25500ND503449
Chromium ug/L 500 102 75-12592 10 25500ND511462
Cobalt ug/L 500 103 75-12592 11 25500ND516461
Copper ug/L 500 105 75-12595 11 25500ND528474
Lead ug/L 500 101 75-12590 11 25500ND507454
Nickel ug/L 500 100 75-12589 11 25500ND499447
Selenium ug/L 500 100 75-12589 11 25500ND503448
Silver ug/L 250 103 75-12592 11 25250ND258230
Thallium ug/L 500 105 75-12594 11 25500ND525470
Vanadium ug/L 500 104 75-12594 10 25500ND523472
Zinc ug/L 500 101 75-12590 11 25500ND504453
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/33199
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92264558002, 92264558003, 92264558004, 92264558005, 92264558006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1545743
Associated Lab Samples:92264558002, 92264558003, 92264558004, 92264558005, 92264558006
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 5.0 09/01/15 12:49
1,1,1-Trichloroethane ug/L ND 1.0 09/01/15 12:49
1,1,2,2-Tetrachloroethane ug/L ND 3.0 09/01/15 12:49
1,1,2-Trichloroethane ug/L ND 1.0 09/01/15 12:49
1,1-Dichloroethane ug/L ND 5.0 09/01/15 12:49
1,1-Dichloroethene ug/L ND 5.0 09/01/15 12:49
1,2,3-Trichloropropane ug/L ND 1.0 09/01/15 12:49
1,2-Dibromo-3-chloropropane ug/L ND 13.0 09/01/15 12:49
1,2-Dibromoethane (EDB)ug/L ND 1.0 09/01/15 12:49
1,2-Dichlorobenzene ug/L ND 5.0 09/01/15 12:49
1,2-Dichloroethane ug/L ND 1.0 09/01/15 12:49
1,2-Dichloropropane ug/L ND 1.0 09/01/15 12:49
1,3-Dichloropropane ug/L ND 1.0 09/01/15 12:49
1,4-Dichlorobenzene ug/L ND 1.0 09/01/15 12:49
2-Butanone (MEK)ug/L ND 100 09/01/15 12:49
2-Hexanone ug/L ND 50.0 09/01/15 12:49
4-Methyl-2-pentanone (MIBK)ug/L ND 100 09/01/15 12:49
Acetone ug/L ND 100 09/01/15 12:49
Acrylonitrile ug/L ND 200 09/01/15 12:49
Benzene ug/L ND 1.0 09/01/15 12:49
Bromochloromethane ug/L ND 3.0 09/01/15 12:49
Bromodichloromethane ug/L ND 1.0 09/01/15 12:49
Bromoform ug/L ND 3.0 09/01/15 12:49
Bromomethane ug/L ND 10.0 09/01/15 12:49
Carbon disulfide ug/L ND 100 09/01/15 12:49
Carbon tetrachloride ug/L ND 1.0 09/01/15 12:49
Chlorobenzene ug/L ND 3.0 09/01/15 12:49
Chloroethane ug/L ND 10.0 09/01/15 12:49
Chloroform ug/L ND 5.0 09/01/15 12:49
Chloromethane ug/L ND 1.0 09/01/15 12:49
cis-1,2-Dichloroethene ug/L ND 5.0 09/01/15 12:49
cis-1,3-Dichloropropene ug/L ND 1.0 09/01/15 12:49
Dibromochloromethane ug/L ND 3.0 09/01/15 12:49
Dibromomethane ug/L ND 10.0 09/01/15 12:49
Ethylbenzene ug/L ND 1.0 09/01/15 12:49
Iodomethane ug/L 0.49J 10.0 C909/01/15 12:49
Methylene Chloride ug/L ND 1.0 09/01/15 12:49
Styrene ug/L ND 1.0 09/01/15 12:49
Tetrachloroethene ug/L ND 1.0 09/01/15 12:49
Toluene ug/L ND 1.0 09/01/15 12:49
trans-1,2-Dichloroethene ug/L ND 5.0 09/01/15 12:49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1545743
Associated Lab Samples:92264558002, 92264558003, 92264558004, 92264558005, 92264558006
Matrix:Water
Analyzed
trans-1,3-Dichloropropene ug/L ND 1.0 09/01/15 12:49
trans-1,4-Dichloro-2-butene ug/L ND 100 09/01/15 12:49
Trichloroethene ug/L ND 1.0 09/01/15 12:49
Trichlorofluoromethane ug/L ND 1.0 09/01/15 12:49
Vinyl acetate ug/L ND 50.0 09/01/15 12:49
Vinyl chloride ug/L ND 1.0 09/01/15 12:49
Xylene (Total)ug/L ND 5.0 09/01/15 12:49
1,2-Dichloroethane-d4 (S)%95 70-130 09/01/15 12:49
4-Bromofluorobenzene (S)%99 70-130 09/01/15 12:49
Toluene-d8 (S)%101 70-130 09/01/15 12:49
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1545744LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 52.450 105 80-125
1,1,1-Trichloroethane ug/L 44.050 88 71-129
1,1,2,2-Tetrachloroethane ug/L 51.050 102 79-124
1,1,2-Trichloroethane ug/L 48.150 96 85-125
1,1-Dichloroethane ug/L 42.350 85 73-126
1,1-Dichloroethene ug/L 49.750 99 66-135
1,2,3-Trichloropropane ug/L 49.650 99 75-130
1,2-Dibromo-3-chloropropane ug/L 54.950 110 71-133
1,2-Dibromoethane (EDB)ug/L 51.750 103 83-124
1,2-Dichlorobenzene ug/L 52.650 105 80-133
1,2-Dichloroethane ug/L 39.650 79 67-128
1,2-Dichloropropane ug/L 47.250 94 75-132
1,3-Dichloropropane ug/L 49.050 98 76-131
1,4-Dichlorobenzene ug/L 52.350 105 78-130
2-Butanone (MEK)ug/L 98.7J100 99 61-144
2-Hexanone ug/L 110100 110 68-143
4-Methyl-2-pentanone (MIBK)ug/L 102100 102 72-135
Acetone ug/L 86.1J100 86 48-146
Acrylonitrile ug/L 225250 90 40-160
Benzene ug/L 48.450 97 80-125
Bromochloromethane ug/L 45.050 90 71-125
Bromodichloromethane ug/L 48.150 96 78-124
Bromoform ug/L 42.250 84 71-128
Bromomethane ug/L 31.050 62 40-160
Carbon disulfide ug/L 41.4J50 83 50-160
Carbon tetrachloride ug/L 45.850 92 69-131
Chlorobenzene ug/L 49.750 99 81-122
Chloroethane ug/L 31.650 63 39-148
Chloroform ug/L 44.550 89 73-127
Chloromethane ug/L 36.250 72 44-146
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1545744LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 43.350 87 74-124
cis-1,3-Dichloropropene ug/L 50.650 101 72-132
Dibromochloromethane ug/L 46.750 93 78-125
Dibromomethane ug/L 46.650 93 82-120
Ethylbenzene ug/L 47.850 96 79-121
Iodomethane ug/L 79.0100 79 39-154
Methylene Chloride ug/L 41.850 84 64-133
Styrene ug/L 50.650 101 84-126
Tetrachloroethene ug/L 47.550 95 78-122
Toluene ug/L 46.450 93 80-121
trans-1,2-Dichloroethene ug/L 43.750 87 71-127
trans-1,3-Dichloropropene ug/L 50.150 100 69-141
trans-1,4-Dichloro-2-butene ug/L 56.0J50 112 40-160
Trichloroethene ug/L 47.350 95 78-122
Trichlorofluoromethane ug/L 36.550 73 53-137
Vinyl acetate ug/L 93.2100 93 40-160
Vinyl chloride ug/L 38.150 76 58-137
Xylene (Total)ug/L 145150 97 81-126
1,2-Dichloroethane-d4 (S)%92 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%97 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1545745MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92263765020
1545746
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 104 70-130111 7 3020ND20.8 22.2
1,1,1-Trichloroethane ug/L 20 98 70-130104 6 3020ND20.1 21.3
1,1,2,2-Tetrachloroethane ug/L 20 105 70-130110 4 3020ND21.0 22.0
1,1,2-Trichloroethane ug/L 20 101 70-130107 6 3020ND20.1 21.3
1,1-Dichloroethane ug/L 20 97 70-13099 2 30200.84J 20.3 20.6
1,1-Dichloroethene ug/L 20 107 70-166106 1 30200.95J 22.4 22.2
1,2,3-Trichloropropane ug/L 20 105 70-130107 2 3020ND21.0 21.4
1,2-Dibromo-3-
chloropropane ug/L 20 102 70-130106 4 3020ND20.4 21.2
1,2-Dibromoethane (EDB)ug/L 20 107 70-130113 6 3020ND21.4 22.7
1,2-Dichlorobenzene ug/L 20 113 70-130117 4 3020ND22.5 23.5
1,2-Dichloroethane ug/L 20 86 70-13088 2 3020ND17.4 17.8
1,2-Dichloropropane ug/L 20 101 70-130106 5 3020ND20.2 21.3
1,3-Dichloropropane ug/L 20 103 70-130108 5 3020ND20.6 21.7
1,4-Dichlorobenzene ug/L 20 113 70-130116 3 3020ND22.5 23.3
2-Butanone (MEK)ug/L 40 95 70-13098 3 3040ND37.9J 39.0J
2-Hexanone ug/L 40 114 70-130118 3 3040ND45.7J 47.3J
4-Methyl-2-pentanone
(MIBK)ug/L 40 102 70-130107 5 3040ND40.7J 42.6J
Acetone ug/L 40 86 70-13088 2 3040ND35.8J 36.6J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1545745MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92263765020
1545746
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Acrylonitrile ug/L 100 97 70-130104 7 30100ND97.3J 104J
Benzene ug/L 20 106 70-148111 5 3020ND21.2 22.3
Bromochloromethane ug/L 20 108 70-130107 1 3020ND21.6 21.4
Bromodichloromethane ug/L 20 101 70-130112 11 3020ND20.1 22.4
Bromoform ug/L 20 82 70-13093 13 3020ND16.3 18.5
Bromomethane ug/L 20 79 70-13083 6 3020ND15.9 16.8
Carbon disulfide ug/L 20 100 70-130100 0 3020ND20.0J 20.0J
Carbon tetrachloride ug/L 20 101 70-130108 7 3020ND20.1 21.5
Chlorobenzene ug/L 20 108 70-146114 5 3020ND21.6 22.8
Chloroethane ug/L 20 81 70-13082 1 3020ND16.2 16.4
Chloroform ug/L 20 101 70-130101 0 3020ND20.1 20.1
Chloromethane ug/L 20 75 70-13077 2 3020ND15.0 15.3
cis-1,2-Dichloroethene ug/L 20 109 70-13072 8 302069.3 91.0 83.7
cis-1,3-Dichloropropene ug/L 20 101 70-130110 8 3020ND20.2 21.9
Dibromochloromethane ug/L 20 92 70-130104 12 3020ND18.4 20.8
Dibromomethane ug/L 20 99 70-130104 5 3020ND19.8 20.9
Ethylbenzene ug/L 20 107 70-130111 4 3020ND21.4 22.3
Iodomethane ug/L 40 84 70-13084 0 30400.48J 33.9 33.9
Methylene Chloride ug/L 20 90 70-13089 1 3020ND17.9 17.8
Styrene ug/L 20 109 70-130114 5 3020ND21.8 22.8
Tetrachloroethene ug/L 20 106 70-130110 4 3020ND21.1 22.1
Toluene ug/L 20 102 70-155106 4 3020ND20.3 21.2
trans-1,2-Dichloroethene ug/L 20 102 70-130102 0 3020ND20.5 20.6
trans-1,3-Dichloropropene ug/L 20 101 70-130108 7 3020ND20.3 21.7
trans-1,4-Dichloro-2-butene ug/L 20 122 70-130122 0 3020ND24.5J 24.5J
Trichloroethene ug/L 20 114 69-151124 2 302066.2 88.9 91.0
Trichlorofluoromethane ug/L 20 92 70-13095 3 3020ND18.5 19.0
Vinyl acetate ug/L 40 91 70-13093 2 3040ND36.5J 37.4J
Vinyl chloride ug/L 20 93 70-13095 2 3020ND19.1 19.4
1,2-Dichloroethane-d4 (S)%94 70-13092
4-Bromofluorobenzene (S)%99 70-13098
Toluene-d8 (S)%97 70-13098
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/33203
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92264558007, 92264558008, 92264558009, 92264558010, 92264558011
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1545863
Associated Lab Samples:92264558007, 92264558008, 92264558009, 92264558010, 92264558011
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 5.0 09/01/15 15:02
1,1,1-Trichloroethane ug/L ND 1.0 09/01/15 15:02
1,1,2,2-Tetrachloroethane ug/L ND 3.0 09/01/15 15:02
1,1,2-Trichloroethane ug/L ND 1.0 09/01/15 15:02
1,1-Dichloroethane ug/L ND 5.0 09/01/15 15:02
1,1-Dichloroethene ug/L ND 5.0 09/01/15 15:02
1,2,3-Trichloropropane ug/L ND 1.0 09/01/15 15:02
1,2-Dibromo-3-chloropropane ug/L ND 13.0 09/01/15 15:02
1,2-Dibromoethane (EDB)ug/L ND 1.0 09/01/15 15:02
1,2-Dichlorobenzene ug/L ND 5.0 09/01/15 15:02
1,2-Dichloroethane ug/L ND 1.0 09/01/15 15:02
1,2-Dichloropropane ug/L ND 1.0 09/01/15 15:02
1,3-Dichloropropane ug/L ND 1.0 09/01/15 15:02
1,4-Dichlorobenzene ug/L ND 1.0 09/01/15 15:02
2-Butanone (MEK)ug/L ND 100 09/01/15 15:02
2-Hexanone ug/L ND 50.0 09/01/15 15:02
4-Methyl-2-pentanone (MIBK)ug/L ND 100 09/01/15 15:02
Acetone ug/L ND 100 09/01/15 15:02
Acrylonitrile ug/L ND 200 09/01/15 15:02
Benzene ug/L ND 1.0 09/01/15 15:02
Bromochloromethane ug/L ND 3.0 09/01/15 15:02
Bromodichloromethane ug/L ND 1.0 09/01/15 15:02
Bromoform ug/L ND 3.0 09/01/15 15:02
Bromomethane ug/L ND 10.0 09/01/15 15:02
Carbon disulfide ug/L ND 100 09/01/15 15:02
Carbon tetrachloride ug/L ND 1.0 09/01/15 15:02
Chlorobenzene ug/L ND 3.0 09/01/15 15:02
Chloroethane ug/L ND 10.0 09/01/15 15:02
Chloroform ug/L ND 5.0 09/01/15 15:02
Chloromethane ug/L ND 1.0 09/01/15 15:02
cis-1,2-Dichloroethene ug/L ND 5.0 09/01/15 15:02
cis-1,3-Dichloropropene ug/L ND 1.0 09/01/15 15:02
Dibromochloromethane ug/L ND 3.0 09/01/15 15:02
Dibromomethane ug/L ND 10.0 09/01/15 15:02
Ethylbenzene ug/L ND 1.0 09/01/15 15:02
Iodomethane ug/L ND 10.0 09/01/15 15:02
Methylene Chloride ug/L ND 1.0 09/01/15 15:02
Styrene ug/L ND 1.0 09/01/15 15:02
Tetrachloroethene ug/L ND 1.0 09/01/15 15:02
Toluene ug/L ND 1.0 09/01/15 15:02
trans-1,2-Dichloroethene ug/L ND 5.0 09/01/15 15:02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1545863
Associated Lab Samples:92264558007, 92264558008, 92264558009, 92264558010, 92264558011
Matrix:Water
Analyzed
trans-1,3-Dichloropropene ug/L ND 1.0 09/01/15 15:02
trans-1,4-Dichloro-2-butene ug/L ND 100 09/01/15 15:02
Trichloroethene ug/L ND 1.0 09/01/15 15:02
Trichlorofluoromethane ug/L ND 1.0 09/01/15 15:02
Vinyl acetate ug/L ND 50.0 09/01/15 15:02
Vinyl chloride ug/L ND 1.0 09/01/15 15:02
Xylene (Total)ug/L ND 5.0 09/01/15 15:02
1,2-Dichloroethane-d4 (S)%117 70-130 09/01/15 15:02
4-Bromofluorobenzene (S)%105 70-130 09/01/15 15:02
Toluene-d8 (S)%102 70-130 09/01/15 15:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1545864LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 49.850 100 80-125
1,1,1-Trichloroethane ug/L 58.850 118 71-129
1,1,2,2-Tetrachloroethane ug/L 52.250 104 79-124
1,1,2-Trichloroethane ug/L 49.950 100 85-125
1,1-Dichloroethane ug/L 50.150 100 73-126
1,1-Dichloroethene ug/L 61.350 123 66-135
1,2,3-Trichloropropane ug/L 57.750 115 75-130
1,2-Dibromo-3-chloropropane ug/L 62.050 124 71-133
1,2-Dibromoethane (EDB)ug/L 53.250 106 83-124
1,2-Dichlorobenzene ug/L 50.650 101 80-133
1,2-Dichloroethane ug/L 51.050 102 67-128
1,2-Dichloropropane ug/L 46.050 92 75-132
1,3-Dichloropropane ug/L 48.650 97 76-131
1,4-Dichlorobenzene ug/L 50.950 102 78-130
2-Butanone (MEK)ug/L 125100 125 61-144
2-Hexanone ug/L 128100 128 68-143
4-Methyl-2-pentanone (MIBK)ug/L 121100 121 72-135
Acetone ug/L 129100 129 48-146
Acrylonitrile ug/L 323250 129 40-160
Benzene ug/L 47.650 95 80-125
Bromochloromethane ug/L 52.350 105 71-125
Bromodichloromethane ug/L 55.250 110 78-124
Bromoform ug/L 44.350 89 71-128
Bromomethane ug/L 39.850 80 40-160
Carbon disulfide ug/L 45.6J50 91 50-160
Carbon tetrachloride ug/L 53.450 107 69-131
Chlorobenzene ug/L 49.350 99 81-122
Chloroethane ug/L 46.450 93 39-148
Chloroform ug/L 55.050 110 73-127
Chloromethane ug/L 40.550 81 44-146
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1545864LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 52.450 105 74-124
cis-1,3-Dichloropropene ug/L 50.950 102 72-132
Dibromochloromethane ug/L 47.550 95 78-125
Dibromomethane ug/L 50.650 101 82-120
Ethylbenzene ug/L 49.950 100 79-121
Iodomethane ug/L 79.0100 79 39-154
Methylene Chloride ug/L 50.550 101 64-133
Styrene ug/L 52.350 105 84-126
Tetrachloroethene ug/L 50.450 101 78-122
Toluene ug/L 48.150 96 80-121
trans-1,2-Dichloroethene ug/L 53.850 108 71-127
trans-1,3-Dichloropropene ug/L 54.250 108 69-141
trans-1,4-Dichloro-2-butene ug/L 68.9J50 138 40-160
Trichloroethene ug/L 48.250 96 78-122
Trichlorofluoromethane ug/L 55.550 111 53-137
Vinyl acetate ug/L 111100 111 40-160
Vinyl chloride ug/L 45.350 91 58-137
Xylene (Total)ug/L 154150 102 81-126
1,2-Dichloroethane-d4 (S)%114 70-130
4-Bromofluorobenzene (S)%106 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1545865MATRIX SPIKE SAMPLE:
MSSpike
Result
92264558007
1,1,1,2-Tetrachloroethane ug/L 21.520 108 70-130ND
1,1,1-Trichloroethane ug/L 23.220 116 70-130ND
1,1,2,2-Tetrachloroethane ug/L 20.220 101 70-130ND
1,1,2-Trichloroethane ug/L 21.020 105 70-130ND
1,1-Dichloroethane ug/L 22.020 110 70-130ND
1,1-Dichloroethene ug/L 25.220 126 70-166ND
1,2,3-Trichloropropane ug/L 20.120 100 70-130ND
1,2-Dibromo-3-chloropropane ug/L 19.920 99 70-130ND
1,2-Dibromoethane (EDB)ug/L 22.520 113 70-130ND
1,2-Dichlorobenzene ug/L 22.420 112 70-130ND
1,2-Dichloroethane ug/L 20.020 99 70-130ND
1,2-Dichloropropane ug/L 21.620 108 70-130ND
1,3-Dichloropropane ug/L 22.120 111 70-130ND
1,4-Dichlorobenzene ug/L 22.020 110 70-130ND
2-Butanone (MEK)ug/L 39.3J40 98 70-130ND
2-Hexanone ug/L 41.7J40 104 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 40.3J40 101 70-130ND
Acetone ug/L 40.9J40 94 70-130ND
Acrylonitrile ug/L 108J100 108 70-130ND
Benzene ug/L 23.520 118 70-148ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
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[phone]
Page 37 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1545865MATRIX SPIKE SAMPLE:
MSSpike
Result
92264558007
Bromochloromethane ug/L 23.720 118 70-130ND
Bromodichloromethane ug/L 21.720 108 70-130ND
Bromoform ug/L 18.320 91 70-130ND
Bromomethane ug/L 28.3 M12014170-130ND
Carbon disulfide ug/L 24.1J20 121 70-130ND
Carbon tetrachloride ug/L 23.320 116 70-130ND
Chlorobenzene ug/L 22.720 113 70-146ND
Chloroethane ug/L 22.420 112 70-130ND
Chloroform ug/L 24.120 118 70-1300.55J
Chloromethane ug/L 20.020 100 70-130ND
cis-1,2-Dichloroethene ug/L 23.020 115 70-130ND
cis-1,3-Dichloropropene ug/L 21.820 109 70-130ND
Dibromochloromethane ug/L 19.820 99 70-130ND
Dibromomethane ug/L 21.620 108 70-130ND
Ethylbenzene ug/L 22.520 112 70-130ND
Iodomethane ug/L 36.840 92 70-130ND
Methylene Chloride ug/L 20.320 102 70-130ND
Styrene ug/L 22.220 111 70-130ND
Tetrachloroethene ug/L 22.820 114 70-130ND
Toluene ug/L 22.420 112 70-155ND
trans-1,2-Dichloroethene ug/L 24.320 122 70-130ND
trans-1,3-Dichloropropene ug/L 20.520 102 70-130ND
trans-1,4-Dichloro-2-butene ug/L 14.6J20 73 70-130ND
Trichloroethene ug/L 21.320 106 69-151ND
Trichlorofluoromethane ug/L 23.620 118 70-130ND
Vinyl acetate ug/L 41.0J40 103 70-130ND
Vinyl chloride ug/L 25.520 127 70-130ND
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92264558008
1545866SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L 0.36J 300.32J
1,2-Dichloroethane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92264558008
1545866SAMPLE DUPLICATE:
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L 2.6 15 302.3
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L 1.2 300.99J
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L 13.6 9 3012.4
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%99 17117
4-Bromofluorobenzene (S)%99 4103
Toluene-d8 (S)%101 2103
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/33243
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92264558001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1548198
Associated Lab Samples:92264558001
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 5.0 09/03/15 13:26
1,1,1-Trichloroethane ug/L ND 1.0 09/03/15 13:26
1,1,2,2-Tetrachloroethane ug/L ND 3.0 09/03/15 13:26
1,1,2-Trichloroethane ug/L ND 1.0 09/03/15 13:26
1,1-Dichloroethane ug/L ND 5.0 09/03/15 13:26
1,1-Dichloroethene ug/L ND 5.0 09/03/15 13:26
1,2,3-Trichloropropane ug/L ND 1.0 09/03/15 13:26
1,2-Dibromo-3-chloropropane ug/L ND 13.0 09/03/15 13:26
1,2-Dibromoethane (EDB)ug/L ND 1.0 09/03/15 13:26
1,2-Dichlorobenzene ug/L ND 5.0 09/03/15 13:26
1,2-Dichloroethane ug/L ND 1.0 09/03/15 13:26
1,2-Dichloropropane ug/L ND 1.0 09/03/15 13:26
1,3-Dichloropropane ug/L ND 1.0 09/03/15 13:26
1,4-Dichlorobenzene ug/L ND 1.0 09/03/15 13:26
2-Butanone (MEK)ug/L ND 100 09/03/15 13:26
2-Hexanone ug/L ND 50.0 09/03/15 13:26
4-Methyl-2-pentanone (MIBK)ug/L ND 100 09/03/15 13:26
Acetone ug/L ND 100 09/03/15 13:26
Acrylonitrile ug/L ND 200 09/03/15 13:26
Benzene ug/L ND 1.0 09/03/15 13:26
Bromochloromethane ug/L ND 3.0 09/03/15 13:26
Bromodichloromethane ug/L ND 1.0 09/03/15 13:26
Bromoform ug/L ND 3.0 09/03/15 13:26
Bromomethane ug/L ND 10.0 09/03/15 13:26
Carbon disulfide ug/L ND 100 09/03/15 13:26
Carbon tetrachloride ug/L ND 1.0 09/03/15 13:26
Chlorobenzene ug/L ND 3.0 09/03/15 13:26
Chloroethane ug/L ND 10.0 09/03/15 13:26
Chloroform ug/L ND 5.0 09/03/15 13:26
Chloromethane ug/L ND 1.0 09/03/15 13:26
cis-1,2-Dichloroethene ug/L ND 5.0 09/03/15 13:26
cis-1,3-Dichloropropene ug/L ND 1.0 09/03/15 13:26
Dibromochloromethane ug/L ND 3.0 09/03/15 13:26
Dibromomethane ug/L ND 10.0 09/03/15 13:26
Ethylbenzene ug/L ND 1.0 09/03/15 13:26
Iodomethane ug/L ND 10.0 09/03/15 13:26
Methylene Chloride ug/L ND 1.0 09/03/15 13:26
Styrene ug/L ND 1.0 09/03/15 13:26
Tetrachloroethene ug/L ND 1.0 09/03/15 13:26
Toluene ug/L ND 1.0 09/03/15 13:26
trans-1,2-Dichloroethene ug/L ND 5.0 09/03/15 13:26
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1548198
Associated Lab Samples:92264558001
Matrix:Water
Analyzed
trans-1,3-Dichloropropene ug/L ND 1.0 09/03/15 13:26
trans-1,4-Dichloro-2-butene ug/L ND 100 09/03/15 13:26
Trichloroethene ug/L ND 1.0 09/03/15 13:26
Trichlorofluoromethane ug/L ND 1.0 09/03/15 13:26
Vinyl acetate ug/L ND 50.0 09/03/15 13:26
Vinyl chloride ug/L ND 1.0 09/03/15 13:26
Xylene (Total)ug/L ND 5.0 09/03/15 13:26
1,2-Dichloroethane-d4 (S)%95 70-130 09/03/15 13:26
4-Bromofluorobenzene (S)%101 70-130 09/03/15 13:26
Toluene-d8 (S)%103 70-130 09/03/15 13:26
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1548199LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 48.750 97 80-125
1,1,1-Trichloroethane ug/L 44.750 89 71-129
1,1,2,2-Tetrachloroethane ug/L 48.750 97 79-124
1,1,2-Trichloroethane ug/L 47.550 95 85-125
1,1-Dichloroethane ug/L 45.050 90 73-126
1,1-Dichloroethene ug/L 55.150 110 66-135
1,2,3-Trichloropropane ug/L 47.550 95 75-130
1,2-Dibromo-3-chloropropane ug/L 47.450 95 71-133
1,2-Dibromoethane (EDB)ug/L 51.250 102 83-124
1,2-Dichlorobenzene ug/L 50.150 100 80-133
1,2-Dichloroethane ug/L 41.950 84 67-128
1,2-Dichloropropane ug/L 47.850 96 75-132
1,3-Dichloropropane ug/L 48.350 97 76-131
1,4-Dichlorobenzene ug/L 48.550 97 78-130
2-Butanone (MEK)ug/L 98.6J100 99 61-144
2-Hexanone ug/L 99.8100 100 68-143
4-Methyl-2-pentanone (MIBK)ug/L 95.8J100 96 72-135
Acetone ug/L 91.5J100 91 48-146
Acrylonitrile ug/L 236250 94 40-160
Benzene ug/L 50.750 101 80-125
Bromochloromethane ug/L 50.450 101 71-125
Bromodichloromethane ug/L 47.050 94 78-124
Bromoform ug/L 37.550 75 71-128
Bromomethane ug/L 35.050 70 40-160
Carbon disulfide ug/L 44.4J50 89 50-160
Carbon tetrachloride ug/L 46.950 94 69-131
Chlorobenzene ug/L 48.650 97 81-122
Chloroethane ug/L 37.950 76 39-148
Chloroform ug/L 46.550 93 73-127
Chloromethane ug/L 40.150 80 44-146
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1548199LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 45.250 90 74-124
cis-1,3-Dichloropropene ug/L 49.050 98 72-132
Dibromochloromethane ug/L 43.050 86 78-125
Dibromomethane ug/L 48.150 96 82-120
Ethylbenzene ug/L 46.850 94 79-121
Iodomethane ug/L 79.4100 79 39-154
Methylene Chloride ug/L 47.650 95 64-133
Styrene ug/L 48.150 96 84-126
Tetrachloroethene ug/L 47.850 96 78-122
Toluene ug/L 46.450 93 80-121
trans-1,2-Dichloroethene ug/L 46.450 93 71-127
trans-1,3-Dichloropropene ug/L 48.250 96 69-141
trans-1,4-Dichloro-2-butene ug/L 52.5J50 105 40-160
Trichloroethene ug/L 49.850 100 78-122
Trichlorofluoromethane ug/L 42.750 85 53-137
Vinyl acetate ug/L 96.9100 97 40-160
Vinyl chloride ug/L 42.650 85 58-137
Xylene (Total)ug/L 142150 95 81-126
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%97 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1548200MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92265659001
1548201
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 96 70-13099 3 3020ND19.2 19.7
1,1,1-Trichloroethane ug/L 20 104 70-130105 1 3020ND20.8 21.0
1,1,2,2-Tetrachloroethane ug/L 20 101 70-130102 1 3020ND20.2 20.4
1,1,2-Trichloroethane ug/L 20 102 70-130103 1 3020ND20.4 20.5
1,1-Dichloroethane ug/L 20 101 70-130103 1 30203.0 23.3 23.6
1,1-Dichloroethene ug/L 20 119 70-166118 1 3020ND23.7 23.5
1,2,3-Trichloropropane ug/L 20 103 70-130102 1 3020ND20.7 20.4
1,2-Dibromo-3-
chloropropane ug/L 20 91 70-13091 1 3020ND18.1 18.3
1,2-Dibromoethane (EDB)ug/L 20 105 70-130108 3 3020ND21.0 21.5
1,2-Dichlorobenzene ug/L 20 108 70-130108 0 3020ND21.7 21.6
1,2-Dichloroethane ug/L 20 92 70-13092 1 30200.50J 18.9 18.8
1,2-Dichloropropane ug/L 20 103 70-130106 2 3020ND20.7 21.2
1,3-Dichloropropane ug/L 20 101 70-130103 3 3020ND20.1 20.7
1,4-Dichlorobenzene ug/L 20 106 70-130107 1 3020ND21.2 21.4
2-Butanone (MEK)ug/L 40 101 70-130104 3 3040ND40.4J 41.5J
2-Hexanone ug/L 40 98 70-130104 6 3040ND39.1J 41.4J
4-Methyl-2-pentanone
(MIBK)ug/L 40 101 70-130100 1 3040ND40.3J 39.9J
Acetone ug/L 40 91 70-13097 6 3040ND38.5J 40.9J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1548200MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92265659001
1548201
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Acrylonitrile ug/L 100 99 70-130101 2 30100ND99.0J 101J
Benzene ug/L 20 111 70-148115 3 3020ND22.5 23.1
Bromochloromethane ug/L 20 111 70-130114 3 3020ND22.2 22.9
Bromodichloromethane ug/L 20 102 70-130102 1 3020ND20.4 20.3
Bromoform ug/L 20 75 70-13075 1 3020ND15.1 14.9
Bromomethane ug/L M1207670-13066 14 3020ND15.3 13.2
Carbon disulfide ug/L 20 104 70-130104 0 3020ND20.9J 20.8J
Carbon tetrachloride ug/L 20 104 70-130107 3 3020ND20.8 21.4
Chlorobenzene ug/L 20 108 70-146108 0 3020ND21.7 21.6
Chloroethane ug/L 20 117 70-130111 5 30201.4 24.8 23.7
Chloroform ug/L 20 105 70-130106 1 3020ND21.0 21.1
Chloromethane ug/L 20 104 70-13097 6 3020ND20.8 19.5
cis-1,2-Dichloroethene ug/L 20 108 70-130103 5 30200.78J 22.4 21.4
cis-1,3-Dichloropropene ug/L 20 92 70-13095 4 3020ND18.4 19.0
Dibromochloromethane ug/L 20 86 70-13087 1 3020ND17.2 17.5
Dibromomethane ug/L 20 104 70-130105 1 3020ND20.8 21.0
Ethylbenzene ug/L 20 103 70-130105 2 3020ND20.6 21.1
Iodomethane ug/L M1406270-13083 29 3040ND24.9 33.3
Methylene Chloride ug/L 20 108 70-130109 1 3020ND22.4 22.7
Styrene ug/L 20 102 70-130104 2 3020ND20.5 20.9
Tetrachloroethene ug/L 20 103 70-130105 2 3020ND20.6 20.9
Toluene ug/L 20 106 70-155106 0 3020ND21.1 21.2
trans-1,2-Dichloroethene ug/L 20 105 70-130107 1 3020ND21.1 21.3
trans-1,3-Dichloropropene ug/L 20 92 70-13097 5 3020ND18.5 19.3
trans-1,4-Dichloro-2-butene ug/L 20 92 70-13097 6 3020ND18.3J 19.5J
Trichloroethene ug/L 20 119 69-151110 8 3020ND23.8 22.0
Trichlorofluoromethane ug/L 20 111 70-130110 1 3020ND22.2 22.0
Vinyl acetate ug/L 40 82 70-13081 1 3040ND32.9J 32.5J
Vinyl chloride ug/L 20 104 70-130104 0 3020ND21.0 21.0
1,2-Dichloroethane-d4 (S)%94 70-13094
4-Bromofluorobenzene (S)%100 70-130101
Toluene-d8 (S)%98 70-13097
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
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Page 43 of 49
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Analyte was detected in the associated method blank.B
Common Laboratory Contaminant.C9
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
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Page 44 of 49
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92264558
WAYNE CLOSED MSWLF (DUDLEY)
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92264558001 MPRP/19334 ICP/17381MW-4 EPA 3010 EPA 6010
92264558002 MPRP/19334 ICP/17381MW-6 EPA 3010 EPA 6010
92264558003 MPRP/19334 ICP/17381MW-7 EPA 3010 EPA 6010
92264558004 MPRP/19334 ICP/17381MW-8 EPA 3010 EPA 6010
92264558005 MPRP/19334 ICP/17381MW-9 EPA 3010 EPA 6010
92264558006 MPRP/19334 ICP/17381MW-10 EPA 3010 EPA 6010
92264558007 MPRP/19358 ICP/17401MW-1R EPA 3010 EPA 6010
92264558008 MPRP/19358 ICP/17401MW-2 EPA 3010 EPA 6010
92264558009 MPRP/19358 ICP/17401MW-3 EPA 3010 EPA 6010
92264558010 MPRP/19358 ICP/17401MW-5 EPA 3010 EPA 6010
92264558011 MPRP/19358 ICP/17401MW-11 EPA 3010 EPA 6010
92264558001 MSV/33243MW-4 EPA 8260
92264558002 MSV/33199MW-6 EPA 8260
92264558003 MSV/33199MW-7 EPA 8260
92264558004 MSV/33199MW-8 EPA 8260
92264558005 MSV/33199MW-9 EPA 8260
92264558006 MSV/33199MW-10 EPA 8260
92264558007 MSV/33203MW-1R EPA 8260
92264558008 MSV/33203MW-2 EPA 8260
92264558009 MSV/33203MW-3 EPA 8260
92264558010 MSV/33203MW-5 EPA 8260
92264558011 MSV/33203MW-11 EPA 8260
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/09/2015 05:25 PM
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[phone]
Page 45 of 49
Page 46 of 49
Page 47 of 49
Page 48 of 49
Page 49 of 49
#=CL#
September 04, 2015
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92264878
92264878
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
PO Box 97
Garner, NC 27529
WAYNE MSWLF-SWS
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on August 25, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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[phone]
Page 1 of 21
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92264878
WAYNE MSWLF-SWS
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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Page 2 of 21
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92264878
WAYNE MSWLF-SWS
Lab ID Sample ID Matrix Date Collected Date Received
92264878001 SW-2 Water 08/21/15 15:50 08/25/15 15:26
92264878002 SW-3 Water 08/21/15 14:00 08/25/15 15:26
92264878003 SW-1 Water 08/21/15 14:15 08/25/15 15:26
REPORT OF LABORATORY ANALYSIS
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Page 3 of 21
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92264878
WAYNE MSWLF-SWS
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92264878001 SW-2 EPA 6010 15 PASI-AJDA
EPA 8260 51 PASI-CNB
92264878002 SW-3 EPA 6010 15 PASI-AJDA
EPA 8260 51 PASI-CNB
92264878003 SW-1 EPA 6010 15 PASI-AJDA
EPA 8260 51 PASI-CNB
REPORT OF LABORATORY ANALYSIS
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Page 4 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264878
WAYNE MSWLF-SWS
Sample:SW-2 Lab ID:92264878001 Collected:08/21/15 15:50 Received:08/25/15 15:26 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 08/31/15 02:10 7440-36-008/27/15 20:006.0 3.8 1
Arsenic ND ug/L 08/31/15 02:10 7440-38-208/27/15 20:0010.0 2.5 1
Barium 57.7J ug/L 08/31/15 02:10 7440-39-308/27/15 20:001002.5 1
Beryllium ND ug/L 08/31/15 02:10 7440-41-708/27/15 20:001.0 0.50 1
Cadmium ND ug/L 08/31/15 02:10 7440-43-908/27/15 20:001.0 0.50 1
Chromium ND ug/L 08/31/15 02:10 7440-47-308/27/15 20:0010.0 2.5 1
Cobalt ND ug/L 08/31/15 02:10 7440-48-408/27/15 20:0010.0 2.5 1
Copper ND ug/L 08/31/15 02:10 7440-50-808/27/15 20:0010.0 2.5 1
Lead ND ug/L 08/31/15 02:10 7439-92-108/27/15 20:0010.0 2.5 1
Nickel ND ug/L 08/31/15 02:10 7440-02-008/27/15 20:0050.0 2.5 1
Selenium ND ug/L 08/31/15 02:10 7782-49-208/27/15 20:0010.0 5.0 1
Silver ND ug/L 08/31/15 02:10 7440-22-408/27/15 20:0010.0 2.5 1
Thallium ND ug/L 08/31/15 02:10 7440-28-008/27/15 20:005.5 5.0 1
Vanadium 4.2J ug/L 08/31/15 02:10 7440-62-208/27/15 20:0025.0 2.5 1
Zinc 13.0 ug/L 08/31/15 02:10 7440-66-608/27/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 09/01/15 17:34 67-64-110010.0 1
Acrylonitrile ND ug/L 09/01/15 17:34 107-13-12001.9 1
Benzene ND ug/L 09/01/15 17:34 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 09/01/15 17:34 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 09/01/15 17:34 75-27-41.0 0.18 1
Bromoform ND ug/L 09/01/15 17:34 75-25-23.0 0.26 1
Bromomethane ND ug/L 09/01/15 17:34 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 09/01/15 17:34 78-93-31000.96 1
Carbon disulfide ND ug/L 09/01/15 17:34 75-15-01001.2 1
Carbon tetrachloride ND ug/L 09/01/15 17:34 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 09/01/15 17:34 108-90-73.0 0.23 1
Chloroethane ND ug/L 09/01/15 17:34 75-00-310.0 0.54 1
Chloroform ND ug/L 09/01/15 17:34 67-66-35.0 0.14 1
Chloromethane 0.33J ug/L 09/01/15 17:34 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 17:34 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 09/01/15 17:34 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 09/01/15 17:34 106-93-41.0 0.27 1
Dibromomethane ND ug/L 09/01/15 17:34 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 09/01/15 17:34 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 09/01/15 17:34 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 17:34 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 09/01/15 17:34 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 09/01/15 17:34 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 09/01/15 17:34 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 09/01/15 17:34 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 09/01/15 17:34 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 09/01/15 17:34 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 09/01/15 17:34 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 09/01/15 17:34 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
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Page 5 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264878
WAYNE MSWLF-SWS
Sample:SW-2 Lab ID:92264878001 Collected:08/21/15 15:50 Received:08/25/15 15:26 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 09/01/15 17:34 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 09/01/15 17:34 100-41-41.0 0.30 1
2-Hexanone ND ug/L 09/01/15 17:34 591-78-650.0 0.46 1
Iodomethane ND ug/L 09/01/15 17:34 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 09/01/15 17:34 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 17:34 108-10-11000.33 1
Styrene ND ug/L 09/01/15 17:34 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 17:34 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 17:34 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 09/01/15 17:34 127-18-41.0 0.46 1
Toluene ND ug/L 09/01/15 17:34 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 09/01/15 17:34 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 09/01/15 17:34 79-00-51.0 0.29 1
Trichloroethene ND ug/L 09/01/15 17:34 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 09/01/15 17:34 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 09/01/15 17:34 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 09/01/15 17:34 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 09/01/15 17:34 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 09/01/15 17:34 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)104 %09/01/15 17:34 460-00-470-130 1
1,2-Dichloroethane-d4 (S)118 %09/01/15 17:34 17060-07-070-130 1
Toluene-d8 (S)102 %09/01/15 17:34 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
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Page 6 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264878
WAYNE MSWLF-SWS
Sample:SW-3 Lab ID:92264878002 Collected:08/21/15 14:00 Received:08/25/15 15:26 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 08/31/15 02:13 7440-36-008/27/15 20:006.0 3.8 1
Arsenic ND ug/L 08/31/15 02:13 7440-38-208/27/15 20:0010.0 2.5 1
Barium 67.7J ug/L 08/31/15 02:13 7440-39-308/27/15 20:001002.5 1
Beryllium ND ug/L 08/31/15 02:13 7440-41-708/27/15 20:001.0 0.50 1
Cadmium ND ug/L 08/31/15 02:13 7440-43-908/27/15 20:001.0 0.50 1
Chromium ND ug/L 08/31/15 02:13 7440-47-308/27/15 20:0010.0 2.5 1
Cobalt ND ug/L 08/31/15 02:13 7440-48-408/27/15 20:0010.0 2.5 1
Copper ND ug/L 08/31/15 02:13 7440-50-808/27/15 20:0010.0 2.5 1
Lead ND ug/L 08/31/15 02:13 7439-92-108/27/15 20:0010.0 2.5 1
Nickel ND ug/L 08/31/15 02:13 7440-02-008/27/15 20:0050.0 2.5 1
Selenium ND ug/L 08/31/15 02:13 7782-49-208/27/15 20:0010.0 5.0 1
Silver ND ug/L 08/31/15 02:13 7440-22-408/27/15 20:0010.0 2.5 1
Thallium ND ug/L 08/31/15 02:13 7440-28-008/27/15 20:005.5 5.0 1
Vanadium ND ug/L 08/31/15 02:13 7440-62-208/27/15 20:0025.0 2.5 1
Zinc 6.1J ug/L 08/31/15 02:13 7440-66-608/27/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 09/01/15 17:51 67-64-110010.0 1
Acrylonitrile ND ug/L 09/01/15 17:51 107-13-12001.9 1
Benzene ND ug/L 09/01/15 17:51 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 09/01/15 17:51 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 09/01/15 17:51 75-27-41.0 0.18 1
Bromoform ND ug/L 09/01/15 17:51 75-25-23.0 0.26 1
Bromomethane ND ug/L 09/01/15 17:51 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 09/01/15 17:51 78-93-31000.96 1
Carbon disulfide ND ug/L 09/01/15 17:51 75-15-01001.2 1
Carbon tetrachloride ND ug/L 09/01/15 17:51 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 09/01/15 17:51 108-90-73.0 0.23 1
Chloroethane ND ug/L 09/01/15 17:51 75-00-310.0 0.54 1
Chloroform ND ug/L 09/01/15 17:51 67-66-35.0 0.14 1
Chloromethane ND ug/L 09/01/15 17:51 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 17:51 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 09/01/15 17:51 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 09/01/15 17:51 106-93-41.0 0.27 1
Dibromomethane ND ug/L 09/01/15 17:51 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 09/01/15 17:51 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 09/01/15 17:51 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 17:51 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 09/01/15 17:51 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 09/01/15 17:51 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 09/01/15 17:51 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 09/01/15 17:51 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 09/01/15 17:51 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 09/01/15 17:51 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 09/01/15 17:51 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 09/01/15 17:51 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
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Huntersville, NC 28078
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Page 7 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264878
WAYNE MSWLF-SWS
Sample:SW-3 Lab ID:92264878002 Collected:08/21/15 14:00 Received:08/25/15 15:26 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 09/01/15 17:51 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 09/01/15 17:51 100-41-41.0 0.30 1
2-Hexanone ND ug/L 09/01/15 17:51 591-78-650.0 0.46 1
Iodomethane ND ug/L 09/01/15 17:51 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 09/01/15 17:51 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 17:51 108-10-11000.33 1
Styrene ND ug/L 09/01/15 17:51 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 17:51 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 17:51 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 09/01/15 17:51 127-18-41.0 0.46 1
Toluene ND ug/L 09/01/15 17:51 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 09/01/15 17:51 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 09/01/15 17:51 79-00-51.0 0.29 1
Trichloroethene ND ug/L 09/01/15 17:51 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 09/01/15 17:51 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 09/01/15 17:51 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 09/01/15 17:51 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 09/01/15 17:51 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 09/01/15 17:51 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %09/01/15 17:51 460-00-470-130 1
1,2-Dichloroethane-d4 (S)120 %09/01/15 17:51 17060-07-070-130 1
Toluene-d8 (S)102 %09/01/15 17:51 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
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Huntersville, NC 28078
[phone]
Page 8 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264878
WAYNE MSWLF-SWS
Sample:SW-1 Lab ID:92264878003 Collected:08/21/15 14:15 Received:08/25/15 15:26 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 08/31/15 02:16 7440-36-008/27/15 20:006.0 3.8 1
Arsenic ND ug/L 08/31/15 02:16 7440-38-208/27/15 20:0010.0 2.5 1
Barium 64.4J ug/L 08/31/15 02:16 7440-39-308/27/15 20:001002.5 1
Beryllium ND ug/L 08/31/15 02:16 7440-41-708/27/15 20:001.0 0.50 1
Cadmium 0.56J ug/L 08/31/15 02:16 7440-43-908/27/15 20:001.0 0.50 1
Chromium ND ug/L 08/31/15 02:16 7440-47-308/27/15 20:0010.0 2.5 1
Cobalt ND ug/L 08/31/15 02:16 7440-48-408/27/15 20:0010.0 2.5 1
Copper ND ug/L 08/31/15 02:16 7440-50-808/27/15 20:0010.0 2.5 1
Lead ND ug/L 08/31/15 02:16 7439-92-108/27/15 20:0010.0 2.5 1
Nickel ND ug/L 08/31/15 02:16 7440-02-008/27/15 20:0050.0 2.5 1
Selenium ND ug/L 08/31/15 02:16 7782-49-208/27/15 20:0010.0 5.0 1
Silver ND ug/L 08/31/15 02:16 7440-22-408/27/15 20:0010.0 2.5 1
Thallium ND ug/L 08/31/15 02:16 7440-28-008/27/15 20:005.5 5.0 1
Vanadium ND ug/L 08/31/15 02:16 7440-62-208/27/15 20:0025.0 2.5 1
Zinc ND ug/L 08/31/15 02:16 7440-66-608/27/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 09/01/15 18:08 67-64-110010.0 1
Acrylonitrile ND ug/L 09/01/15 18:08 107-13-12001.9 1
Benzene ND ug/L 09/01/15 18:08 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 09/01/15 18:08 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 09/01/15 18:08 75-27-41.0 0.18 1
Bromoform ND ug/L 09/01/15 18:08 75-25-23.0 0.26 1
Bromomethane ND ug/L 09/01/15 18:08 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 09/01/15 18:08 78-93-31000.96 1
Carbon disulfide ND ug/L 09/01/15 18:08 75-15-01001.2 1
Carbon tetrachloride ND ug/L 09/01/15 18:08 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 09/01/15 18:08 108-90-73.0 0.23 1
Chloroethane ND ug/L 09/01/15 18:08 75-00-310.0 0.54 1
Chloroform ND ug/L 09/01/15 18:08 67-66-35.0 0.14 1
Chloromethane ND ug/L 09/01/15 18:08 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 18:08 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 09/01/15 18:08 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 09/01/15 18:08 106-93-41.0 0.27 1
Dibromomethane ND ug/L 09/01/15 18:08 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 09/01/15 18:08 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 09/01/15 18:08 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 18:08 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 09/01/15 18:08 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 09/01/15 18:08 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 09/01/15 18:08 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 09/01/15 18:08 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 09/01/15 18:08 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 09/01/15 18:08 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 09/01/15 18:08 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 09/01/15 18:08 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
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Page 9 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264878
WAYNE MSWLF-SWS
Sample:SW-1 Lab ID:92264878003 Collected:08/21/15 14:15 Received:08/25/15 15:26 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 09/01/15 18:08 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 09/01/15 18:08 100-41-41.0 0.30 1
2-Hexanone ND ug/L 09/01/15 18:08 591-78-650.0 0.46 1
Iodomethane ND ug/L 09/01/15 18:08 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 09/01/15 18:08 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 18:08 108-10-11000.33 1
Styrene ND ug/L 09/01/15 18:08 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 18:08 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 18:08 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 09/01/15 18:08 127-18-41.0 0.46 1
Toluene ND ug/L 09/01/15 18:08 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 09/01/15 18:08 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 09/01/15 18:08 79-00-51.0 0.29 1
Trichloroethene ND ug/L 09/01/15 18:08 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 09/01/15 18:08 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 09/01/15 18:08 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 09/01/15 18:08 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 09/01/15 18:08 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 09/01/15 18:08 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)103 %09/01/15 18:08 460-00-470-130 1
1,2-Dichloroethane-d4 (S)120 %09/01/15 18:08 17060-07-070-130 1
Toluene-d8 (S)101 %09/01/15 18:08 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
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[phone]
Page 10 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264878
WAYNE MSWLF-SWS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/19358
EPA 3010
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92264878001, 92264878002, 92264878003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1543211
Associated Lab Samples:92264878001, 92264878002, 92264878003
Matrix:Water
Analyzed
Antimony ug/L ND 6.0 08/31/15 01:33
Arsenic ug/L ND 10.0 08/31/15 01:33
Barium ug/L ND 100 08/31/15 01:33
Beryllium ug/L ND 1.0 08/31/15 01:33
Cadmium ug/L ND 1.0 08/31/15 01:33
Chromium ug/L ND 10.0 08/31/15 01:33
Cobalt ug/L ND 10.0 08/31/15 01:33
Copper ug/L ND 10.0 08/31/15 01:33
Lead ug/L ND 10.0 08/31/15 01:33
Nickel ug/L ND 50.0 08/31/15 01:33
Selenium ug/L ND 10.0 08/31/15 01:33
Silver ug/L ND 10.0 08/31/15 01:33
Thallium ug/L ND 5.5 08/31/15 01:33
Vanadium ug/L ND 25.0 08/31/15 01:33
Zinc ug/L ND 10.0 08/31/15 01:33
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1543212LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 469500 94 80-120
Arsenic ug/L 458500 92 80-120
Barium ug/L 470500 94 80-120
Beryllium ug/L 469500 94 80-120
Cadmium ug/L 453500 91 80-120
Chromium ug/L 456500 91 80-120
Cobalt ug/L 464500 93 80-120
Copper ug/L 473500 95 80-120
Lead ug/L 458500 92 80-120
Nickel ug/L 450500 90 80-120
Selenium ug/L 451500 90 80-120
Silver ug/L 232250 93 80-120
Thallium ug/L 472500 94 80-120
Vanadium ug/L 467500 93 80-120
Zinc ug/L 453500 91 80-120
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264878
WAYNE MSWLF-SWS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1543213MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92264558007
1543214
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 104 75-12592 12 25500ND521462
Arsenic ug/L 500 102 75-12591 11 25500ND508454
Barium ug/L 500 105 75-12594 11 255008.6J 535 480
Beryllium ug/L 500 105 75-12594 11 25500ND525471
Cadmium ug/L 500 101 75-12590 11 25500ND503449
Chromium ug/L 500 102 75-12592 10 25500ND511462
Cobalt ug/L 500 103 75-12592 11 25500ND516461
Copper ug/L 500 105 75-12595 11 25500ND528474
Lead ug/L 500 101 75-12590 11 25500ND507454
Nickel ug/L 500 100 75-12589 11 25500ND499447
Selenium ug/L 500 100 75-12589 11 25500ND503448
Silver ug/L 250 103 75-12592 11 25250ND258230
Thallium ug/L 500 105 75-12594 11 25500ND525470
Vanadium ug/L 500 104 75-12594 10 25500ND523472
Zinc ug/L 500 101 75-12590 11 25500ND504453
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264878
WAYNE MSWLF-SWS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/33203
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92264878001, 92264878002, 92264878003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1545863
Associated Lab Samples:92264878001, 92264878002, 92264878003
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 5.0 09/01/15 15:02
1,1,1-Trichloroethane ug/L ND 1.0 09/01/15 15:02
1,1,2,2-Tetrachloroethane ug/L ND 3.0 09/01/15 15:02
1,1,2-Trichloroethane ug/L ND 1.0 09/01/15 15:02
1,1-Dichloroethane ug/L ND 5.0 09/01/15 15:02
1,1-Dichloroethene ug/L ND 5.0 09/01/15 15:02
1,2,3-Trichloropropane ug/L ND 1.0 09/01/15 15:02
1,2-Dibromo-3-chloropropane ug/L ND 13.0 09/01/15 15:02
1,2-Dibromoethane (EDB)ug/L ND 1.0 09/01/15 15:02
1,2-Dichlorobenzene ug/L ND 5.0 09/01/15 15:02
1,2-Dichloroethane ug/L ND 1.0 09/01/15 15:02
1,2-Dichloropropane ug/L ND 1.0 09/01/15 15:02
1,3-Dichloropropane ug/L ND 1.0 09/01/15 15:02
1,4-Dichlorobenzene ug/L ND 1.0 09/01/15 15:02
2-Butanone (MEK)ug/L ND 100 09/01/15 15:02
2-Hexanone ug/L ND 50.0 09/01/15 15:02
4-Methyl-2-pentanone (MIBK)ug/L ND 100 09/01/15 15:02
Acetone ug/L ND 100 09/01/15 15:02
Acrylonitrile ug/L ND 200 09/01/15 15:02
Benzene ug/L ND 1.0 09/01/15 15:02
Bromochloromethane ug/L ND 3.0 09/01/15 15:02
Bromodichloromethane ug/L ND 1.0 09/01/15 15:02
Bromoform ug/L ND 3.0 09/01/15 15:02
Bromomethane ug/L ND 10.0 09/01/15 15:02
Carbon disulfide ug/L ND 100 09/01/15 15:02
Carbon tetrachloride ug/L ND 1.0 09/01/15 15:02
Chlorobenzene ug/L ND 3.0 09/01/15 15:02
Chloroethane ug/L ND 10.0 09/01/15 15:02
Chloroform ug/L ND 5.0 09/01/15 15:02
Chloromethane ug/L ND 1.0 09/01/15 15:02
cis-1,2-Dichloroethene ug/L ND 5.0 09/01/15 15:02
cis-1,3-Dichloropropene ug/L ND 1.0 09/01/15 15:02
Dibromochloromethane ug/L ND 3.0 09/01/15 15:02
Dibromomethane ug/L ND 10.0 09/01/15 15:02
Ethylbenzene ug/L ND 1.0 09/01/15 15:02
Iodomethane ug/L ND 10.0 09/01/15 15:02
Methylene Chloride ug/L ND 1.0 09/01/15 15:02
Styrene ug/L ND 1.0 09/01/15 15:02
Tetrachloroethene ug/L ND 1.0 09/01/15 15:02
Toluene ug/L ND 1.0 09/01/15 15:02
trans-1,2-Dichloroethene ug/L ND 5.0 09/01/15 15:02
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264878
WAYNE MSWLF-SWS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1545863
Associated Lab Samples:92264878001, 92264878002, 92264878003
Matrix:Water
Analyzed
trans-1,3-Dichloropropene ug/L ND 1.0 09/01/15 15:02
trans-1,4-Dichloro-2-butene ug/L ND 100 09/01/15 15:02
Trichloroethene ug/L ND 1.0 09/01/15 15:02
Trichlorofluoromethane ug/L ND 1.0 09/01/15 15:02
Vinyl acetate ug/L ND 50.0 09/01/15 15:02
Vinyl chloride ug/L ND 1.0 09/01/15 15:02
Xylene (Total)ug/L ND 5.0 09/01/15 15:02
1,2-Dichloroethane-d4 (S)%117 70-130 09/01/15 15:02
4-Bromofluorobenzene (S)%105 70-130 09/01/15 15:02
Toluene-d8 (S)%102 70-130 09/01/15 15:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1545864LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 49.850 100 80-125
1,1,1-Trichloroethane ug/L 58.850 118 71-129
1,1,2,2-Tetrachloroethane ug/L 52.250 104 79-124
1,1,2-Trichloroethane ug/L 49.950 100 85-125
1,1-Dichloroethane ug/L 50.150 100 73-126
1,1-Dichloroethene ug/L 61.350 123 66-135
1,2,3-Trichloropropane ug/L 57.750 115 75-130
1,2-Dibromo-3-chloropropane ug/L 62.050 124 71-133
1,2-Dibromoethane (EDB)ug/L 53.250 106 83-124
1,2-Dichlorobenzene ug/L 50.650 101 80-133
1,2-Dichloroethane ug/L 51.050 102 67-128
1,2-Dichloropropane ug/L 46.050 92 75-132
1,3-Dichloropropane ug/L 48.650 97 76-131
1,4-Dichlorobenzene ug/L 50.950 102 78-130
2-Butanone (MEK)ug/L 125100 125 61-144
2-Hexanone ug/L 128100 128 68-143
4-Methyl-2-pentanone (MIBK)ug/L 121100 121 72-135
Acetone ug/L 129100 129 48-146
Acrylonitrile ug/L 323250 129 40-160
Benzene ug/L 47.650 95 80-125
Bromochloromethane ug/L 52.350 105 71-125
Bromodichloromethane ug/L 55.250 110 78-124
Bromoform ug/L 44.350 89 71-128
Bromomethane ug/L 39.850 80 40-160
Carbon disulfide ug/L 45.6J50 91 50-160
Carbon tetrachloride ug/L 53.450 107 69-131
Chlorobenzene ug/L 49.350 99 81-122
Chloroethane ug/L 46.450 93 39-148
Chloroform ug/L 55.050 110 73-127
Chloromethane ug/L 40.550 81 44-146
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264878
WAYNE MSWLF-SWS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1545864LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 52.450 105 74-124
cis-1,3-Dichloropropene ug/L 50.950 102 72-132
Dibromochloromethane ug/L 47.550 95 78-125
Dibromomethane ug/L 50.650 101 82-120
Ethylbenzene ug/L 49.950 100 79-121
Iodomethane ug/L 79.0100 79 39-154
Methylene Chloride ug/L 50.550 101 64-133
Styrene ug/L 52.350 105 84-126
Tetrachloroethene ug/L 50.450 101 78-122
Toluene ug/L 48.150 96 80-121
trans-1,2-Dichloroethene ug/L 53.850 108 71-127
trans-1,3-Dichloropropene ug/L 54.250 108 69-141
trans-1,4-Dichloro-2-butene ug/L 68.9J50 138 40-160
Trichloroethene ug/L 48.250 96 78-122
Trichlorofluoromethane ug/L 55.550 111 53-137
Vinyl acetate ug/L 111100 111 40-160
Vinyl chloride ug/L 45.350 91 58-137
Xylene (Total)ug/L 154150 102 81-126
1,2-Dichloroethane-d4 (S)%114 70-130
4-Bromofluorobenzene (S)%106 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1545865MATRIX SPIKE SAMPLE:
MSSpike
Result
92264558007
1,1,1,2-Tetrachloroethane ug/L 21.520 108 70-130ND
1,1,1-Trichloroethane ug/L 23.220 116 70-130ND
1,1,2,2-Tetrachloroethane ug/L 20.220 101 70-130ND
1,1,2-Trichloroethane ug/L 21.020 105 70-130ND
1,1-Dichloroethane ug/L 22.020 110 70-130ND
1,1-Dichloroethene ug/L 25.220 126 70-166ND
1,2,3-Trichloropropane ug/L 20.120 100 70-130ND
1,2-Dibromo-3-chloropropane ug/L 19.920 99 70-130ND
1,2-Dibromoethane (EDB)ug/L 22.520 113 70-130ND
1,2-Dichlorobenzene ug/L 22.420 112 70-130ND
1,2-Dichloroethane ug/L 20.020 99 70-130ND
1,2-Dichloropropane ug/L 21.620 108 70-130ND
1,3-Dichloropropane ug/L 22.120 111 70-130ND
1,4-Dichlorobenzene ug/L 22.020 110 70-130ND
2-Butanone (MEK)ug/L 39.3J40 98 70-130ND
2-Hexanone ug/L 41.7J40 104 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 40.3J40 101 70-130ND
Acetone ug/L 40.9J40 94 70-130ND
Acrylonitrile ug/L 108J100 108 70-130ND
Benzene ug/L 23.520 118 70-148ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
Pace Analytical Services, Inc.
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Page 15 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264878
WAYNE MSWLF-SWS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1545865MATRIX SPIKE SAMPLE:
MSSpike
Result
92264558007
Bromochloromethane ug/L 23.720 118 70-130ND
Bromodichloromethane ug/L 21.720 108 70-130ND
Bromoform ug/L 18.320 91 70-130ND
Bromomethane ug/L 28.3 M12014170-130ND
Carbon disulfide ug/L 24.1J20 121 70-130ND
Carbon tetrachloride ug/L 23.320 116 70-130ND
Chlorobenzene ug/L 22.720 113 70-146ND
Chloroethane ug/L 22.420 112 70-130ND
Chloroform ug/L 24.120 118 70-1300.55J
Chloromethane ug/L 20.020 100 70-130ND
cis-1,2-Dichloroethene ug/L 23.020 115 70-130ND
cis-1,3-Dichloropropene ug/L 21.820 109 70-130ND
Dibromochloromethane ug/L 19.820 99 70-130ND
Dibromomethane ug/L 21.620 108 70-130ND
Ethylbenzene ug/L 22.520 112 70-130ND
Iodomethane ug/L 36.840 92 70-130ND
Methylene Chloride ug/L 20.320 102 70-130ND
Styrene ug/L 22.220 111 70-130ND
Tetrachloroethene ug/L 22.820 114 70-130ND
Toluene ug/L 22.420 112 70-155ND
trans-1,2-Dichloroethene ug/L 24.320 122 70-130ND
trans-1,3-Dichloropropene ug/L 20.520 102 70-130ND
trans-1,4-Dichloro-2-butene ug/L 14.6J20 73 70-130ND
Trichloroethene ug/L 21.320 106 69-151ND
Trichlorofluoromethane ug/L 23.620 118 70-130ND
Vinyl acetate ug/L 41.0J40 103 70-130ND
Vinyl chloride ug/L 25.520 127 70-130ND
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92264558008
1545866SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L 0.36J 300.32J
1,2-Dichloroethane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
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Page 16 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264878
WAYNE MSWLF-SWS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92264558008
1545866SAMPLE DUPLICATE:
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L 2.6 15 302.3
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L 1.2 300.99J
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L 13.6 9 3012.4
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%99 17117
4-Bromofluorobenzene (S)%99 4103
Toluene-d8 (S)%101 2103
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
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[phone]
Page 17 of 21
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92264878
WAYNE MSWLF-SWS
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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Page 18 of 21
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92264878
WAYNE MSWLF-SWS
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92264878001 MPRP/19358 ICP/17401SW-2 EPA 3010 EPA 6010
92264878002 MPRP/19358 ICP/17401SW-3 EPA 3010 EPA 6010
92264878003 MPRP/19358 ICP/17401SW-1 EPA 3010 EPA 6010
92264878001 MSV/33203SW-2 EPA 8260
92264878002 MSV/33203SW-3 EPA 8260
92264878003 MSV/33203SW-1 EPA 8260
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
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Page 19 of 21
Page 20 of 21
Page 21 of 21
#=CL#
September 04, 2015
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92264881
92264881
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
PO Box 97
Garner, NC 27529
WAYNE MSWLF BLANKS
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on August 25, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 1 of 21
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92264881
WAYNE MSWLF BLANKS
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 2 of 21
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92264881
WAYNE MSWLF BLANKS
Lab ID Sample ID Matrix Date Collected Date Received
92264881001 EB Water 08/21/15 15:00 08/25/15 15:26
92264881002 FB Water 08/21/15 15:10 08/25/15 15:26
92264881003 TB Water 08/21/15 00:00 08/25/15 15:26
REPORT OF LABORATORY ANALYSIS
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Page 3 of 21
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92264881
WAYNE MSWLF BLANKS
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92264881001 EB EPA 6010 15 PASI-AJDA
EPA 8260 51 PASI-CNB
92264881002 FB EPA 6010 15 PASI-AJDA
EPA 8260 51 PASI-CNB
92264881003 TB EPA 8260 51 PASI-CNB
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 4 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264881
WAYNE MSWLF BLANKS
Sample:EB Lab ID:92264881001 Collected:08/21/15 15:00 Received:08/25/15 15:26 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 08/31/15 00:22 7440-36-008/26/15 18:306.0 3.8 1
Arsenic ND ug/L 08/31/15 00:22 7440-38-208/26/15 18:3010.0 2.5 1
Barium 7.4J ug/L 08/31/15 00:22 7440-39-308/26/15 18:301002.5 1
Beryllium ND ug/L 08/31/15 00:22 7440-41-708/26/15 18:301.0 0.50 1
Cadmium ND ug/L 08/31/15 00:22 7440-43-908/26/15 18:301.0 0.50 1
Chromium ND ug/L 08/31/15 00:22 7440-47-308/26/15 18:3010.0 2.5 1
Cobalt ND ug/L 08/31/15 00:22 7440-48-408/26/15 18:3010.0 2.5 1
Copper ND ug/L 08/31/15 00:22 7440-50-808/26/15 18:3010.0 2.5 1
Lead ND ug/L 08/31/15 00:22 7439-92-108/26/15 18:3010.0 2.5 1
Nickel ND ug/L 08/31/15 00:22 7440-02-008/26/15 18:3050.0 2.5 1
Selenium ND ug/L 08/31/15 00:22 7782-49-208/26/15 18:3010.0 5.0 1
Silver ND ug/L 08/31/15 00:22 7440-22-408/26/15 18:3010.0 2.5 1
Thallium ND ug/L 08/31/15 00:22 7440-28-008/26/15 18:305.5 5.0 1
Vanadium ND ug/L 08/31/15 00:22 7440-62-208/26/15 18:3025.0 2.5 1
Zinc ND ug/L 08/31/15 00:22 7440-66-608/26/15 18:3010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 09/01/15 18:42 67-64-110010.0 1
Acrylonitrile ND ug/L 09/01/15 18:42 107-13-12001.9 1
Benzene ND ug/L 09/01/15 18:42 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 09/01/15 18:42 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 09/01/15 18:42 75-27-41.0 0.18 1
Bromoform ND ug/L 09/01/15 18:42 75-25-23.0 0.26 1
Bromomethane ND ug/L 09/01/15 18:42 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 09/01/15 18:42 78-93-31000.96 1
Carbon disulfide ND ug/L 09/01/15 18:42 75-15-01001.2 1
Carbon tetrachloride ND ug/L 09/01/15 18:42 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 09/01/15 18:42 108-90-73.0 0.23 1
Chloroethane ND ug/L 09/01/15 18:42 75-00-310.0 0.54 1
Chloroform ND ug/L 09/01/15 18:42 67-66-35.0 0.14 1
Chloromethane ND ug/L 09/01/15 18:42 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 18:42 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 09/01/15 18:42 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 09/01/15 18:42 106-93-41.0 0.27 1
Dibromomethane ND ug/L 09/01/15 18:42 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 09/01/15 18:42 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 09/01/15 18:42 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 18:42 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 09/01/15 18:42 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 09/01/15 18:42 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 09/01/15 18:42 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 09/01/15 18:42 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 09/01/15 18:42 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 09/01/15 18:42 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 09/01/15 18:42 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 09/01/15 18:42 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
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Page 5 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264881
WAYNE MSWLF BLANKS
Sample:EB Lab ID:92264881001 Collected:08/21/15 15:00 Received:08/25/15 15:26 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 09/01/15 18:42 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 09/01/15 18:42 100-41-41.0 0.30 1
2-Hexanone ND ug/L 09/01/15 18:42 591-78-650.0 0.46 1
Iodomethane ND ug/L 09/01/15 18:42 74-88-410.0 0.32 1
Methylene Chloride 1.1 ug/L 09/01/15 18:42 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 18:42 108-10-11000.33 1
Styrene ND ug/L 09/01/15 18:42 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 18:42 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 18:42 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 09/01/15 18:42 127-18-41.0 0.46 1
Toluene ND ug/L 09/01/15 18:42 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 09/01/15 18:42 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 09/01/15 18:42 79-00-51.0 0.29 1
Trichloroethene ND ug/L 09/01/15 18:42 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 09/01/15 18:42 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 09/01/15 18:42 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 09/01/15 18:42 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 09/01/15 18:42 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 09/01/15 18:42 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)104 %09/01/15 18:42 460-00-470-130 1
1,2-Dichloroethane-d4 (S)119 %09/01/15 18:42 17060-07-070-130 1
Toluene-d8 (S)103 %09/01/15 18:42 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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Page 6 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264881
WAYNE MSWLF BLANKS
Sample:FB Lab ID:92264881002 Collected:08/21/15 15:10 Received:08/25/15 15:26 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 08/31/15 00:25 7440-36-008/26/15 18:306.0 3.8 1
Arsenic ND ug/L 08/31/15 00:25 7440-38-208/26/15 18:3010.0 2.5 1
Barium 7.8J ug/L 08/31/15 00:25 7440-39-308/26/15 18:301002.5 1
Beryllium ND ug/L 08/31/15 00:25 7440-41-708/26/15 18:301.0 0.50 1
Cadmium ND ug/L 08/31/15 00:25 7440-43-908/26/15 18:301.0 0.50 1
Chromium ND ug/L 08/31/15 00:25 7440-47-308/26/15 18:3010.0 2.5 1
Cobalt ND ug/L 08/31/15 00:25 7440-48-408/26/15 18:3010.0 2.5 1
Copper ND ug/L 08/31/15 00:25 7440-50-808/26/15 18:3010.0 2.5 1
Lead ND ug/L 08/31/15 00:25 7439-92-108/26/15 18:3010.0 2.5 1
Nickel ND ug/L 08/31/15 00:25 7440-02-008/26/15 18:3050.0 2.5 1
Selenium ND ug/L 08/31/15 00:25 7782-49-208/26/15 18:3010.0 5.0 1
Silver ND ug/L 08/31/15 00:25 7440-22-408/26/15 18:3010.0 2.5 1
Thallium ND ug/L 08/31/15 00:25 7440-28-008/26/15 18:305.5 5.0 1
Vanadium ND ug/L 08/31/15 00:25 7440-62-208/26/15 18:3025.0 2.5 1
Zinc ND ug/L 08/31/15 00:25 7440-66-608/26/15 18:3010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 09/01/15 18:59 67-64-110010.0 1
Acrylonitrile ND ug/L 09/01/15 18:59 107-13-12001.9 1
Benzene ND ug/L 09/01/15 18:59 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 09/01/15 18:59 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 09/01/15 18:59 75-27-41.0 0.18 1
Bromoform ND ug/L 09/01/15 18:59 75-25-23.0 0.26 1
Bromomethane ND ug/L 09/01/15 18:59 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 09/01/15 18:59 78-93-31000.96 1
Carbon disulfide ND ug/L 09/01/15 18:59 75-15-01001.2 1
Carbon tetrachloride ND ug/L 09/01/15 18:59 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 09/01/15 18:59 108-90-73.0 0.23 1
Chloroethane ND ug/L 09/01/15 18:59 75-00-310.0 0.54 1
Chloroform ND ug/L 09/01/15 18:59 67-66-35.0 0.14 1
Chloromethane ND ug/L 09/01/15 18:59 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 18:59 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 09/01/15 18:59 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 09/01/15 18:59 106-93-41.0 0.27 1
Dibromomethane ND ug/L 09/01/15 18:59 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 09/01/15 18:59 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 09/01/15 18:59 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 18:59 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 09/01/15 18:59 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 09/01/15 18:59 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 09/01/15 18:59 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 09/01/15 18:59 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 09/01/15 18:59 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 09/01/15 18:59 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 09/01/15 18:59 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 09/01/15 18:59 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
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Page 7 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264881
WAYNE MSWLF BLANKS
Sample:FB Lab ID:92264881002 Collected:08/21/15 15:10 Received:08/25/15 15:26 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 09/01/15 18:59 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 09/01/15 18:59 100-41-41.0 0.30 1
2-Hexanone ND ug/L 09/01/15 18:59 591-78-650.0 0.46 1
Iodomethane ND ug/L 09/01/15 18:59 74-88-410.0 0.32 1
Methylene Chloride 1.3 ug/L 09/01/15 18:59 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 18:59 108-10-11000.33 1
Styrene ND ug/L 09/01/15 18:59 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 18:59 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 18:59 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 09/01/15 18:59 127-18-41.0 0.46 1
Toluene ND ug/L 09/01/15 18:59 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 09/01/15 18:59 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 09/01/15 18:59 79-00-51.0 0.29 1
Trichloroethene ND ug/L 09/01/15 18:59 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 09/01/15 18:59 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 09/01/15 18:59 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 09/01/15 18:59 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 09/01/15 18:59 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 09/01/15 18:59 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)101 %09/01/15 18:59 460-00-470-130 1
1,2-Dichloroethane-d4 (S)120 %09/01/15 18:59 17060-07-070-130 1
Toluene-d8 (S)102 %09/01/15 18:59 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
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Huntersville, NC 28078
[phone]
Page 8 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264881
WAYNE MSWLF BLANKS
Sample:TB Lab ID:92264881003 Collected:08/21/15 00:00 Received:08/25/15 15:26 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 09/01/15 19:16 67-64-110010.0 1
Acrylonitrile ND ug/L 09/01/15 19:16 107-13-12001.9 1
Benzene ND ug/L 09/01/15 19:16 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 09/01/15 19:16 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 09/01/15 19:16 75-27-41.0 0.18 1
Bromoform ND ug/L 09/01/15 19:16 75-25-23.0 0.26 1
Bromomethane ND ug/L 09/01/15 19:16 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 09/01/15 19:16 78-93-31000.96 1
Carbon disulfide ND ug/L 09/01/15 19:16 75-15-01001.2 1
Carbon tetrachloride ND ug/L 09/01/15 19:16 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 09/01/15 19:16 108-90-73.0 0.23 1
Chloroethane ND ug/L 09/01/15 19:16 75-00-310.0 0.54 1
Chloroform ND ug/L 09/01/15 19:16 67-66-35.0 0.14 1
Chloromethane ND ug/L 09/01/15 19:16 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 19:16 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 09/01/15 19:16 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 09/01/15 19:16 106-93-41.0 0.27 1
Dibromomethane ND ug/L 09/01/15 19:16 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 09/01/15 19:16 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 09/01/15 19:16 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 19:16 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 09/01/15 19:16 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 09/01/15 19:16 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 09/01/15 19:16 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 09/01/15 19:16 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 09/01/15 19:16 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 09/01/15 19:16 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 09/01/15 19:16 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 09/01/15 19:16 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 09/01/15 19:16 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 09/01/15 19:16 100-41-41.0 0.30 1
2-Hexanone ND ug/L 09/01/15 19:16 591-78-650.0 0.46 1
Iodomethane ND ug/L 09/01/15 19:16 74-88-410.0 0.32 1
Methylene Chloride 2.4 ug/L 09/01/15 19:16 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 19:16 108-10-11000.33 1
Styrene ND ug/L 09/01/15 19:16 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 19:16 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 19:16 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 09/01/15 19:16 127-18-41.0 0.46 1
Toluene ND ug/L 09/01/15 19:16 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 09/01/15 19:16 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 09/01/15 19:16 79-00-51.0 0.29 1
Trichloroethene ND ug/L 09/01/15 19:16 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 09/01/15 19:16 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 09/01/15 19:16 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 09/01/15 19:16 108-05-450.0 0.35 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
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Huntersville, NC 28078
[phone]
Page 9 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264881
WAYNE MSWLF BLANKS
Sample:TB Lab ID:92264881003 Collected:08/21/15 00:00 Received:08/25/15 15:26 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Vinyl chloride ND ug/L 09/01/15 19:16 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 09/01/15 19:16 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)104 %09/01/15 19:16 460-00-470-130 1
1,2-Dichloroethane-d4 (S)119 %09/01/15 19:16 17060-07-070-130 1
Toluene-d8 (S)101 %09/01/15 19:16 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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[phone]
Page 10 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264881
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/19347
EPA 3010
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92264881001, 92264881002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1542455
Associated Lab Samples:92264881001, 92264881002
Matrix:Water
Analyzed
Antimony ug/L ND 6.0 08/31/15 00:04
Arsenic ug/L ND 10.0 08/31/15 00:04
Barium ug/L ND 100 08/31/15 00:04
Beryllium ug/L ND 1.0 08/31/15 00:04
Cadmium ug/L ND 1.0 08/31/15 00:04
Chromium ug/L ND 10.0 09/02/15 20:47
Cobalt ug/L ND 10.0 08/31/15 00:04
Copper ug/L ND 10.0 08/31/15 00:04
Lead ug/L ND 10.0 08/31/15 00:04
Nickel ug/L ND 50.0 09/02/15 20:47
Selenium ug/L ND 10.0 08/31/15 00:04
Silver ug/L ND 10.0 08/31/15 00:04
Thallium ug/L ND 5.5 08/31/15 00:04
Vanadium ug/L ND 25.0 08/31/15 00:04
Zinc ug/L ND 10.0 08/31/15 00:04
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1542456LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 387417 93 80-120
Arsenic ug/L 374417 90 80-120
Barium ug/L 388417 93 80-120
Beryllium ug/L 387417 93 80-120
Cadmium ug/L 373417 89 80-120
Chromium ug/L 449417 108 80-120
Cobalt ug/L 381417 92 80-120
Copper ug/L 391417 94 80-120
Lead ug/L 377417 91 80-120
Nickel ug/L 467417 112 80-120
Selenium ug/L 371417 89 80-120
Silver ug/L 190208 91 80-120
Thallium ug/L 387417 93 80-120
Vanadium ug/L 383417 92 80-120
Zinc ug/L 374417 90 80-120
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264881
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1542457MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92264856001
1542458
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 417 106 75-12593 13 254178.8 451 397
Arsenic ug/L 417 104 75-12591 13 25417ND431379
Barium ug/L 417 105 75-12590 7 25417454890831
Beryllium ug/L 417 103 75-12591 13 25417ND430378
Cadmium ug/L 417 101 75-12588 13 25417ND421368
Chromium ug/L 417 97 75-12585 13 25417ND405356
Cobalt ug/L 417 97 75-12585 13 25417ND404356
Copper ug/L 417 107 75-12593 13 254174.6J 448 392
Lead ug/L 417 94 75-12583 12 25417ND394348
Nickel ug/L 417 93 75-12581 11 2541786.6 473 424
Selenium ug/L 417 100 75-12589 12 25417ND418370
Silver ug/L 208 103 75-12590 13 25208ND214188
Thallium ug/L 417 97 75-12585 13 25417ND402353
Vanadium ug/L 417 102 75-12589 13 254176.5J 431 378
Zinc ug/L 417 94 75-12583 13 25417ND394346
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264881
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/33203
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92264881001, 92264881002, 92264881003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1545863
Associated Lab Samples:92264881001, 92264881002, 92264881003
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 5.0 09/01/15 15:02
1,1,1-Trichloroethane ug/L ND 1.0 09/01/15 15:02
1,1,2,2-Tetrachloroethane ug/L ND 3.0 09/01/15 15:02
1,1,2-Trichloroethane ug/L ND 1.0 09/01/15 15:02
1,1-Dichloroethane ug/L ND 5.0 09/01/15 15:02
1,1-Dichloroethene ug/L ND 5.0 09/01/15 15:02
1,2,3-Trichloropropane ug/L ND 1.0 09/01/15 15:02
1,2-Dibromo-3-chloropropane ug/L ND 13.0 09/01/15 15:02
1,2-Dibromoethane (EDB)ug/L ND 1.0 09/01/15 15:02
1,2-Dichlorobenzene ug/L ND 5.0 09/01/15 15:02
1,2-Dichloroethane ug/L ND 1.0 09/01/15 15:02
1,2-Dichloropropane ug/L ND 1.0 09/01/15 15:02
1,3-Dichloropropane ug/L ND 1.0 09/01/15 15:02
1,4-Dichlorobenzene ug/L ND 1.0 09/01/15 15:02
2-Butanone (MEK)ug/L ND 100 09/01/15 15:02
2-Hexanone ug/L ND 50.0 09/01/15 15:02
4-Methyl-2-pentanone (MIBK)ug/L ND 100 09/01/15 15:02
Acetone ug/L ND 100 09/01/15 15:02
Acrylonitrile ug/L ND 200 09/01/15 15:02
Benzene ug/L ND 1.0 09/01/15 15:02
Bromochloromethane ug/L ND 3.0 09/01/15 15:02
Bromodichloromethane ug/L ND 1.0 09/01/15 15:02
Bromoform ug/L ND 3.0 09/01/15 15:02
Bromomethane ug/L ND 10.0 09/01/15 15:02
Carbon disulfide ug/L ND 100 09/01/15 15:02
Carbon tetrachloride ug/L ND 1.0 09/01/15 15:02
Chlorobenzene ug/L ND 3.0 09/01/15 15:02
Chloroethane ug/L ND 10.0 09/01/15 15:02
Chloroform ug/L ND 5.0 09/01/15 15:02
Chloromethane ug/L ND 1.0 09/01/15 15:02
cis-1,2-Dichloroethene ug/L ND 5.0 09/01/15 15:02
cis-1,3-Dichloropropene ug/L ND 1.0 09/01/15 15:02
Dibromochloromethane ug/L ND 3.0 09/01/15 15:02
Dibromomethane ug/L ND 10.0 09/01/15 15:02
Ethylbenzene ug/L ND 1.0 09/01/15 15:02
Iodomethane ug/L ND 10.0 09/01/15 15:02
Methylene Chloride ug/L ND 1.0 09/01/15 15:02
Styrene ug/L ND 1.0 09/01/15 15:02
Tetrachloroethene ug/L ND 1.0 09/01/15 15:02
Toluene ug/L ND 1.0 09/01/15 15:02
trans-1,2-Dichloroethene ug/L ND 5.0 09/01/15 15:02
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264881
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1545863
Associated Lab Samples:92264881001, 92264881002, 92264881003
Matrix:Water
Analyzed
trans-1,3-Dichloropropene ug/L ND 1.0 09/01/15 15:02
trans-1,4-Dichloro-2-butene ug/L ND 100 09/01/15 15:02
Trichloroethene ug/L ND 1.0 09/01/15 15:02
Trichlorofluoromethane ug/L ND 1.0 09/01/15 15:02
Vinyl acetate ug/L ND 50.0 09/01/15 15:02
Vinyl chloride ug/L ND 1.0 09/01/15 15:02
Xylene (Total)ug/L ND 5.0 09/01/15 15:02
1,2-Dichloroethane-d4 (S)%117 70-130 09/01/15 15:02
4-Bromofluorobenzene (S)%105 70-130 09/01/15 15:02
Toluene-d8 (S)%102 70-130 09/01/15 15:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1545864LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 49.850 100 80-125
1,1,1-Trichloroethane ug/L 58.850 118 71-129
1,1,2,2-Tetrachloroethane ug/L 52.250 104 79-124
1,1,2-Trichloroethane ug/L 49.950 100 85-125
1,1-Dichloroethane ug/L 50.150 100 73-126
1,1-Dichloroethene ug/L 61.350 123 66-135
1,2,3-Trichloropropane ug/L 57.750 115 75-130
1,2-Dibromo-3-chloropropane ug/L 62.050 124 71-133
1,2-Dibromoethane (EDB)ug/L 53.250 106 83-124
1,2-Dichlorobenzene ug/L 50.650 101 80-133
1,2-Dichloroethane ug/L 51.050 102 67-128
1,2-Dichloropropane ug/L 46.050 92 75-132
1,3-Dichloropropane ug/L 48.650 97 76-131
1,4-Dichlorobenzene ug/L 50.950 102 78-130
2-Butanone (MEK)ug/L 125100 125 61-144
2-Hexanone ug/L 128100 128 68-143
4-Methyl-2-pentanone (MIBK)ug/L 121100 121 72-135
Acetone ug/L 129100 129 48-146
Acrylonitrile ug/L 323250 129 40-160
Benzene ug/L 47.650 95 80-125
Bromochloromethane ug/L 52.350 105 71-125
Bromodichloromethane ug/L 55.250 110 78-124
Bromoform ug/L 44.350 89 71-128
Bromomethane ug/L 39.850 80 40-160
Carbon disulfide ug/L 45.6J50 91 50-160
Carbon tetrachloride ug/L 53.450 107 69-131
Chlorobenzene ug/L 49.350 99 81-122
Chloroethane ug/L 46.450 93 39-148
Chloroform ug/L 55.050 110 73-127
Chloromethane ug/L 40.550 81 44-146
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
Pace Analytical Services, Inc.
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[phone]
Page 14 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264881
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1545864LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 52.450 105 74-124
cis-1,3-Dichloropropene ug/L 50.950 102 72-132
Dibromochloromethane ug/L 47.550 95 78-125
Dibromomethane ug/L 50.650 101 82-120
Ethylbenzene ug/L 49.950 100 79-121
Iodomethane ug/L 79.0100 79 39-154
Methylene Chloride ug/L 50.550 101 64-133
Styrene ug/L 52.350 105 84-126
Tetrachloroethene ug/L 50.450 101 78-122
Toluene ug/L 48.150 96 80-121
trans-1,2-Dichloroethene ug/L 53.850 108 71-127
trans-1,3-Dichloropropene ug/L 54.250 108 69-141
trans-1,4-Dichloro-2-butene ug/L 68.9J50 138 40-160
Trichloroethene ug/L 48.250 96 78-122
Trichlorofluoromethane ug/L 55.550 111 53-137
Vinyl acetate ug/L 111100 111 40-160
Vinyl chloride ug/L 45.350 91 58-137
Xylene (Total)ug/L 154150 102 81-126
1,2-Dichloroethane-d4 (S)%114 70-130
4-Bromofluorobenzene (S)%106 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1545865MATRIX SPIKE SAMPLE:
MSSpike
Result
92264558007
1,1,1,2-Tetrachloroethane ug/L 21.520 108 70-130ND
1,1,1-Trichloroethane ug/L 23.220 116 70-130ND
1,1,2,2-Tetrachloroethane ug/L 20.220 101 70-130ND
1,1,2-Trichloroethane ug/L 21.020 105 70-130ND
1,1-Dichloroethane ug/L 22.020 110 70-130ND
1,1-Dichloroethene ug/L 25.220 126 70-166ND
1,2,3-Trichloropropane ug/L 20.120 100 70-130ND
1,2-Dibromo-3-chloropropane ug/L 19.920 99 70-130ND
1,2-Dibromoethane (EDB)ug/L 22.520 113 70-130ND
1,2-Dichlorobenzene ug/L 22.420 112 70-130ND
1,2-Dichloroethane ug/L 20.020 99 70-130ND
1,2-Dichloropropane ug/L 21.620 108 70-130ND
1,3-Dichloropropane ug/L 22.120 111 70-130ND
1,4-Dichlorobenzene ug/L 22.020 110 70-130ND
2-Butanone (MEK)ug/L 39.3J40 98 70-130ND
2-Hexanone ug/L 41.7J40 104 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 40.3J40 101 70-130ND
Acetone ug/L 40.9J40 94 70-130ND
Acrylonitrile ug/L 108J100 108 70-130ND
Benzene ug/L 23.520 118 70-148ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
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[phone]
Page 15 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264881
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1545865MATRIX SPIKE SAMPLE:
MSSpike
Result
92264558007
Bromochloromethane ug/L 23.720 118 70-130ND
Bromodichloromethane ug/L 21.720 108 70-130ND
Bromoform ug/L 18.320 91 70-130ND
Bromomethane ug/L 28.3 M12014170-130ND
Carbon disulfide ug/L 24.1J20 121 70-130ND
Carbon tetrachloride ug/L 23.320 116 70-130ND
Chlorobenzene ug/L 22.720 113 70-146ND
Chloroethane ug/L 22.420 112 70-130ND
Chloroform ug/L 24.120 118 70-1300.55J
Chloromethane ug/L 20.020 100 70-130ND
cis-1,2-Dichloroethene ug/L 23.020 115 70-130ND
cis-1,3-Dichloropropene ug/L 21.820 109 70-130ND
Dibromochloromethane ug/L 19.820 99 70-130ND
Dibromomethane ug/L 21.620 108 70-130ND
Ethylbenzene ug/L 22.520 112 70-130ND
Iodomethane ug/L 36.840 92 70-130ND
Methylene Chloride ug/L 20.320 102 70-130ND
Styrene ug/L 22.220 111 70-130ND
Tetrachloroethene ug/L 22.820 114 70-130ND
Toluene ug/L 22.420 112 70-155ND
trans-1,2-Dichloroethene ug/L 24.320 122 70-130ND
trans-1,3-Dichloropropene ug/L 20.520 102 70-130ND
trans-1,4-Dichloro-2-butene ug/L 14.6J20 73 70-130ND
Trichloroethene ug/L 21.320 106 69-151ND
Trichlorofluoromethane ug/L 23.620 118 70-130ND
Vinyl acetate ug/L 41.0J40 103 70-130ND
Vinyl chloride ug/L 25.520 127 70-130ND
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92264558008
1545866SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L 0.36J 300.32J
1,2-Dichloroethane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264881
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92264558008
1545866SAMPLE DUPLICATE:
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L 2.6 15 302.3
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L 1.2 300.99J
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L 13.6 9 3012.4
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%99 17117
4-Bromofluorobenzene (S)%99 4103
Toluene-d8 (S)%101 2103
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 21
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92264881
WAYNE MSWLF BLANKS
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 21
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92264881
WAYNE MSWLF BLANKS
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92264881001 MPRP/19347 ICP/17392EBEPA 3010 EPA 6010
92264881002 MPRP/19347 ICP/17392FBEPA 3010 EPA 6010
92264881001 MSV/33203EBEPA 8260
92264881002 MSV/33203FBEPA 8260
92264881003 MSV/33203TBEPA 8260
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 21
Page 20 of 21
Page 21 of 21
Appendix B
Field Sampling Parameter Data Sheet(s)