8504_DukeBelewsCreek_CraigRd_Jan2016_1stSemiAnnaul_DIN26343_20160404

Belews Creek Steam Station
Semiannual Groundwater
Monitoring Report
Craig Road Ash Landfill, Phase 1 and 2
Permit No. 8504
January 2016 Sampling Event
April 4, 2016

Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2 January 2016 Sampling Event
TABLE OF CONTENTS

ii

Table of Contents
Page
Report Verification ......................................................................................................................... i
Table of Contents .......................................................................................................................... ii
Section 1 - Background ................................................................................................................. 1
Section 2 - Methods ...................................................................................................................... 3
2.1 Sampling and Analysis Methods .................................................................................... 3
2.2 Statement of Work .......................................................................................................... 3
Section 3 - Results ........................................................................................................................ 5
3.1 Site Groundwater Flow ................................................................................................... 5
3.2 Analytical Results ........................................................................................................... 5

FIGURES
1. Site Location Map
2. Sample Locations
3. Generalized Groundwater Surface Contours
TABLES
1. Well Construction Information
2. Groundwater Flow Velocities
3. Field Data Parameters
4. Groundwater Field and Analytical Results
5. Field and Analytical Results that Equal or Exceed NCAC 2L Groundwater Quality
Standards
6. Surface Water Field and Analytical Results
7. Leachate Field and Analytical Results
APPENDICES
A. Field Sampling Forms
B. Laboratory Report and Chain-of-Custody Forms

Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2 January 2016 Sampling Event
SECTION 1 - BACKGROUND

1

Section 1 - Background
Belews Creek Steam Station is located on Belews Lake in southwestern Stokes County near
Pine Hall, North Carolina. The station is owned and operated by Duke Energy Carolinas, LLC
(Duke Energy) and generates electricity by combustion of coal. The Craig Road Ash Landfill is
owned by Duke Energy and is permitted to receive coal ash, wastewater treatment sludge, and
off-spec flue gas desulfurization (FGD) residue (gypsum) generated at the Belews Creek Steam
Station under North Carolina Department of Environmental Quality (NCDEQ) Solid Waste
Permit No. 8504.
Phase 1 of the landfill was constructed with an engineered liner system and the waste boundary
contains an area of approximately 32.4 acres. Phase 1 began accepting waste in February
2008. Phase 2 of the landfill was constructed with an engineered liner system and the waste
boundary contains an area of approximately 34.7 acres. Placement of a protective cover layer of
approximately 137,000 tons of bottom ash on top of the Phase 2 liner system began on June
11, 2013. Phase 2 of the landfill received a Permit to Operate January 16, 2014 and started
receiving waste on June 13, 2014.
Phase 1 and Phase 2 of the Craig Road Ash Landfill and nearby area are portrayed on Figure 1.
The highest topographic area of the landfill site is at the center portion of the landfill along its
southern boundary. The predominant groundwater discharge areas are expected to be the
adjacent areas of Belews Lake located to the west, north, and east of the landfill. Figure 2
shows the landfill and the topography at the site.
As described in the Water Quality Monitoring Plan, the monitoring system for the landfill consists
of the following1:
Monitoring Wells: CRW-12 CRW-7 CRW-13
CRW-2 CRW-83 CRW-14
CRW-3 CRW-9 CRW-15
CRW-4 CRW-10 CRW-16
CRW-5 CRW-11 CRW-17
CRW-6 CRW-12

Surface Water Sample Locations: CRS-1 CRS-4
CRS-2 CRS-5
CRS-3 CRS-6

Leachate Sample Locations4: CWB-1
CWB-2
CWB-3

1 Water Quality Monitoring Plan – Phase1/Phase 2 Craig Road Landfill Expansion Duke Energy – Belews
Creek Steam Station, Belews Creek, North Carolina, S&ME Project No. 1356-10-041, April 26, 2012. 2 Monitoring well CRW-1 was abandoned on July 13, 2012, due to construction of Phase 2 of the landfill. 3 Monitoring well CRW-8 was damaged and subsequently replaced by CRW-8R on April 11, 2013. 4 The leachate sample locations are not described in the Water Quality Monitoring Plan but monitoring the
leachate in conjunction with the groundwater monitoring event is a requirement of the Permit to
Operate. Leachate sample locations CWB-1 and CWB-2 were formerly referred to as E-
WWBLeachate and W-WWBLeachate, respectively.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2 January 2016 Sampling Event
SECTION 1 - BACKGROUND

2

The sampling locations are depicted on Figure 2. A summary of monitoring well construction
information is presented in Table 1. According to the Water Quality Monitoring Plan, monitoring
well CRW-10 serves as a background water quality monitoring well.
Surface water sampling locations CRS-1 and CRS-2 are located on perennial streams which
drain to Belews Lake. Sampling locations CRS-4 and CRS-5 are located at groundwater seeps.
Sampling locations CRS-3 and CRS-6 are located at the outlets of the two landfill under-drains.
There is a single non-contact stormwater basin located to the north of the landfill. This basin is
located just north of CRW-4 and shown on Figure 2 as “Primary BMP”. There are three
stormwater basins that receive contact stormwater and leachate. These basins are shown on
Figure 2 as “West Ash Runoff Storage Basin,” “East Ash Runoff Storage Basin,” and “Phase 2
Contact Water Basin.”
Leachate sample locations are located where the leachate collection pipes drain into the contact
stormwater/leachate basins. The contact stormwater/leachate basins and leachate sample
locations are shown on Figure 2.
Monitoring wells CRHS-9 and CRHS-31 were installed as part of the site suitability study for
Phase 2 and were left in place during the January 2013 sampling event with the intent that they
would become part of the permanent groundwater monitoring network for the landfill. Due to the
poor performance of these wells with respect to recharge, these wells were replaced in April
2013 with monitoring wells CRW-12 and CRW-13, respectively.
Monitoring wells CRW-3, CRW-8R, CRW-11, CRW-12, and CRW-17 have had historically high
turbidity measurements reported in the wells. On May 2, 2015, Duke Energy attempted to
redevelop these monitoring wells. On June 29, 2015, Duke Energy purged additional well
volumes from these wells using each well’s dedicated pump in an effort to reduce the turbidity in
the wells. During the sampling event on January 11 and 12, 2016, the turbidity measurements in
these wells were reported at 46.4, 13.2, 56.7, 13.4, and 47.5 Nephelometric Turbidity Units
(NTUs). Due to the continued high turbidity measurements in the monitoring wells, Duke Energy
is considering the replacement of CRW-11, CRW-12, and CRW-17.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2 January 2016 Sampling Event
SECTION 2 - METHODS

3

Section 2 - Methods
2.1 Sampling and Analysis Methods
The collection of samples and documentation of sampling was performed by Duke Energy
personnel (Duke Energy Carolinas Field Certification #5193) according to the North Carolina
Solid Waste Management Guidelines. Copies of the field sampling forms are included in
Appendix A. The parameters and constituents sampled were selected by Duke Energy and the
NCDEQ Division of Solid Waste and were analyzed by Duke Energy Analytical Laboratory
(North Carolina Laboratory Certification #248) and provided to HDR by Duke Energy. The
laboratory report and chain-of-custody forms are included in Appendix B.
The groundwater, surface water, and leachate samples were analyzed using the following
analytical methods:
• Barium, boron, chromium, copper, iron, manganese, nickel, and zinc using Solid Waste
(SW) Method 6010C
• Arsenic, cadmium, lead, selenium, and silver using SW Method 6020A
• Chloride, fluoride, nitrate as nitrogen, and sulfate using US Environmental Protection
Agency (EPA) Method 9056A
• Mercury using EPA Method 7470
• Total dissolved solids using Standard Method (SM) 2540C
2.2 Statement of Work
HDR completed the following tasks:
• Received field sampling information provided by Duke Energy (performed by Duke
Energy personnel) for monitoring wells CRW-2, CRW-3, CRW-4, CRW-5, CRW-6,
CRW-7, CRW-8R, CRW-9, CRW-10, CRW-11, CRW-12, CRW-13, CRW-14, CRW-15,
CRW-16, and CRW-17. Data was also received for surface water sample locations CRS-
1, CRS-2, CRS-3, CRS-4, CRS-5, and CRS-6. Leachate sample data was received for
locations CWB-1 and CWB-2. A leachate sample was not collected at CWB-3 due to
lack of discharge from the leachate pipe at this location. The samples were collected on
January 11 and 12, 2016 and HDR received the data on February 8, 2016.
• Reviewed the laboratory analytical results for the samples. The Electronic Data
Deliverables (EDDs) provided by Duke Energy were adapted to conform to the format
requirements of the NCDEQ EDD template. HDR added an italicized J’ data qualifier (J’)
to indicate a measured concentration that attains or is greater than the laboratory’s
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2 January 2016 Sampling Event
SECTION 2 - METHODS

4

method reporting limit (MRL) but less than the Solid Waste Section Limit5 (SWSL).
Copies of the original EDDs are retained in HDR’s files.
• Developed a generalized groundwater surface contour map using map data and
groundwater elevation data supplied by Duke Energy. Calculated groundwater flow
velocities based on groundwater surface contours.
• Prepared and submitted this Semiannual Groundwater Monitoring Report to Duke
Energy.
5 The Solid Waste Section Limit (SWSL) is defined by NCDEQ as the lowest amount of analyte in a
sample that can be quantitatively determined with suitable precision and accuracy. The SWSL is the
concentration below which reported results must be qualified as estimated. NCDEQ Division of Waste
Management Memorandum dated February 23, 2007.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2 January 2016 Sampling Event
SECTION 3 - RESULTS

5

Section 3 - Results
3.1 Site Groundwater Flow
Generalized groundwater surface contours and groundwater flow direction arrows from the
sampling event for the site are shown on Figure 3. These contours were developed using the
groundwater elevations measured on the date of sampling. The surface water elevation for
Belews Lake was assumed at 724.5 feet. Calculated groundwater flow velocities are presented
on Table 2.
Groundwater flow at the site is from areas of higher topography located along the southern,
central portion of the landfill toward Belews Lake to the northwest, north, and to the northeast
and east toward the canal.
3.2 Analytical Results
A summary of the field data is presented in Table 3.
The field and analytical results of groundwater samples collected at the monitoring wells and at
surface water locations CRS-4 and CRS-5 are summarized in Table 4. The analysis results for
these locations are compared to the groundwater standards found in Title 15A NCAC 02L .0202
(g) (2L Standards)6. Concentrations with values that attain or exceed the 2L Standards are
noted in Table 4 by bold font. A summary of the field and analytical results that attain or exceed
the 2L Standards and a preliminary analysis of the cause and significance of the exceedances
are presented in Table 5.
Surface water sample locations CRS-1 and CRS-2 are located on perennial streams and CRS-3
and CRS-6 are located at the outlets of landfill under-drains. The streams and under-drains flow
to Belews Lake. Belews Lake is classified by the NCDEQ Division of Water Quality as a Class C
water body. As a result, the field and analytical results from these locations are compared to
Title 15A, NCAC, Subchapter 2B Standards (2B Standards) for Class C water. The field and
analytical results of the surface water sampling are summarized in Table 6.
The field and analytical results for leachate sampling are summarized in Table 7.
Concentrations with values that are equal to or greater than the SWSLs are noted by gray cells
in Tables 4, 6, and 7.
Selected samples were diluted as is normal laboratory practice to bring samples within the
calibrated range of the analysis. Specifics regarding the samples that were diluted, including the
dilution amount, are reported in the EDD.
6 Surface water locations CRS-4 and CRS-5 are located at groundwater seeps. Therefore, the analytical
results at these locations are compared to the Title 15A NCAC 02L .0202 (g) groundwater quality
standards (2L Standards).
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2 January 2016 Sampling Event
SECTION 3 - RESULTS

6

HDR prepared and submitted an assessment to NCDEQ on exceedances of the 2L and 2B
Standards at Phase 1 of this landfill (Groundwater Assessment, Belews Creek Steam Station,
Craig Road Ash Landfill, December 21, 2012).
The report assessed 2L Standard exceedances for:
• Chromium at CRW-2 and CRW-9
• Iron at CRW-2, CRW-3, CRW-5, CRW-6, CRW-7, CRW-8, CRW-9, CRS-4, and CRS-5
• Manganese at CRW-2, CRW-3, CRW-5, CRW-6, CRW-7, CRW-9, CRS-4, and CRS-5
The report assessed 2B Standard exceedances for:
• Iron at CRS-2 and CRS-3
The assessment report concluded that at the time of the assessment the exceedances
evaluated were naturally occurring and were not related to impacts from the landfill.

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2

P
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C
No
t
e
s
:
1
.

T
O
C

i
n
d
i
c
a
t
e
s

t
o
p

o
f

c
a
s
i
n
g
.
2
.

f
t
.

i
n
d
i
c
a
t
e
s

f
e
e
t
.
3
.

i
n
.

i
n
d
i
c
a
t
e
s

i
n
c
h
e
s

n
o
m
i
n
a
l

d
i
a
m
e
t
e
r
.
4
.

P
V
C

i
n
d
i
c
a
t
e
s

p
o
l
y
v
i
n
y
l

c
h
l
o
r
i
d
e
.
5
.

P
W
R

i
n
d
i
c
a
t
e
s

p
a
r
t
i
a
l
l
y

w
e
a
t
h
e
r
e
d

r
o
c
k
.
6
.

H
o
r
i
z
o
n
t
a
l

d
a
t
u
m

N
A
D
8
3
.
7
.

V
e
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t
i
c
a
l

d
a
t
u
m

i
s

N
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V
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8
8
.
8
.

D
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t
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g
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d

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a
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n
f
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y

D
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k
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E
n
e
r
g
y

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n

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e
b
r
u
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y

8
,

2
0
1
6
.
Page  1  of  1
Ta
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e

2

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G
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6
No
t
e
s
:

1
.

L
i
n
e
a
r

d
i
s
t
a
n
c
e

m
e
a
s
u
r
e
d

t
h
r
o
u
g
h

m
o
n
i
t
o
r
i
n
g

w
e
l
l
s

i
s

a
p
p
r
o
x
i
m
a
t
e
l
y

p
e
r
p
e
n
d
i
c
u
l
a
r

t
o

g
r
o
u
n
d
w
a
t
e
r

c
o
n
t
o
u
r
s
.

2
.

A
t

m
o
n
i
t
o
r
i
n
g

w
e
l
l

l
o
c
a
t
i
o
n
s

w
h
e
r
e

d
o
w
n
g
r
a
d
i
e
n
t

c
o
n
t
o
u
r
s

a
r
e

n
o
t

p
r
e
s
e
n
t
,

t
h
e

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n

a
t

t
h
e

m
o
n
i
t
o
r
i
n
g

w
e
l
l

i
s

u
s
e
d

a
s

t
h
e

d
o
w
n
g
r
a
d
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n
.

3
.

A
t

m
o
n
i
t
o
r
i
n
g

w
e
l
l

l
o
c
a
t
i
o
n
s

w
h
e
r
e

u
p
g
r
a
d
i
e
n
t

c
o
n
t
o
u
r
s

a
r
e

n
o
t

p
r
e
s
e
n
t
,

t
h
e

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n

a
t

t
h
e

m
o
n
i
t
o
r
i
n
g

w
e
l
l

i
s

u
s
e
d

a
s

t
h
e

u
p
g
r
a
d
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n
.

4
.

M
o
n
i
t
o
r
i
n
g

w
e
l
l
s

a
r
e

n
o
t

l
i
s
t
e
d

w
h
e
r
e

i
n
s
u
f
f
i
c
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

c
o
n
t
o
u
r

i
n
f
o
r
m
a
t
i
o
n

i
s

a
v
a
i
l
a
b
l
e

t
o

c
a
l
c
u
l
a
t
e

v
e
l
o
c
i
t
y
.

5
.

H
y
d
r
a
u
l
i
c

g
r
a
d
i
e
n
t
s

a
n
d

g
r
o
u
n
d
w
a
t
e
r

v
e
l
o
c
i
t
i
e
s

a
r
e

a
p
p
r
o
x
i
m
a
t
e
.

6
.

H
y
d
r
a
u
l
i
c

c
o
n
d
u
c
t
i
v
i
t
y

p
r
e
s
e
n
t
e
d

i
s

t
h
e

g
e
o
m
e
t
r
i
c

m
e
a
n

o
f

t
h
e

c
o
n
d
u
c
t
i
v
i
t
y

d
a
t
a

f
o
r

t
h
e

a
l
l
u
v
i
u
m
/
s
o
i
l
/
s
a
p
r
o
l
i
t
e

a
n
d

P
W
R

h
y
d
r
o
s
t
r
a
t
i
g
r
a
p
h
i
c

l
a
y
e
r

i
n

t
h
e

H
D
R

C
o
n
d
u
c
t
i
v
i
t
y

D
a
t
a
b
a
s
e

(
u
n
p
u
b
l
i
s
h
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d

d
a
t
a

f
r
o
m

P
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d
m
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n
t

C
a
r
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l
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a

s
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w
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f
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a
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d
/
l
a
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d

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r
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k
)
.

7
.

E
f
f
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c
t
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v
e

p
o
r
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s
i
t
y

p
r
e
s
e
n
t
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d

i
s

t
h
e

m
e
a
n

v
a
l
u
e

o
f

t
h
e

a
l
l
u
v
i
u
m
/
s
o
i
l
/
s
a
p
r
o
l
i
t
e

a
n
d

P
W
R

h
y
d
r
o
s
t
r
a
t
i
g
r
a
p
h
i
c

l
a
y
e
r

e
s
t
i
m
a
t
e
d

f
r
o
m

s
o
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l

t
e
s
t
i
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g

u
s
i
n
g

F
e
t
t
e
r
/
B
e
a
r

D
i
a
g
r
a
m
s
.

8
.

H
y
d
r
a
u
l
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c

g
r
a
d
i
e
n
t
s

a
n
d

g
r
o
u
n
d
w
a
t
e
r

v
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l
o
c
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t
i
e
s

b
a
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e
d

o
n

g
r
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n
d
w
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t
e
r

d
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p
t
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s

m
e
a
s
u
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d

o
n

J
a
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a
r
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1
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a
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d

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2
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.
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f
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Po
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y

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1
0
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)
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y

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(f
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)
Page 1 of 1
Ta
b
l
e

3

-

F
i
e
l
d

D
a
t
a

P
a
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a
m
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Du
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E
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C
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.
9
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4
4

N
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1
.
7
8

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0
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N
O

1
4
.
6
7
67
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6
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6
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2
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.
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m
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N
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P

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1
.
6
2

5
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N
O

1
5
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3
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4
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1

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C
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6

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6
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m
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1
.
1
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4
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7
7

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6
.
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6

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C
R
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-
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2
0

2
1
.
4
6

7
6
1
.
6
4

N
o
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m
a
l

N
o
n
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C
P

N
/
A

1
.
4
3

3
.
5
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Y
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S

1
5
.
4
0

5
2

5
.
5

1
4
3

4
7
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3
.
2
8
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6

C
R
W
-
7

2
9
.
9
0

2
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.
4
0

7
6
2
.
6
8

N
o
r
m
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l

N
o
n
e

C
P

N
/
A

1
.
2
2

1
.
2
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Y
E
S

1
6
.
3
3

5
1

5
.
7

2
9
2

4
5
5

6
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8
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2
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0
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6

C
R
W
-
8
R

4
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.
1
8

2
7
.
9
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7
4
8
.
4
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N
o
r
m
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l

N
o
n
e

L
F

3
3
0

2
.
0
0

3
.
1
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N
/
A

1
4
.
7
3

6
4

5
.
8

1
3
.
2

4
0
6

7
.
8
7
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1
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0
1
6

C
R
W
-
9

3
9
.
6
2

2
5
.
7
9

7
4
3
.
8
8

N
o
r
m
a
l

N
o
n
e

L
F

3
3
0

2
.
2
6

5
.
1
0

N
/
A

1
5
.
0
4

4
9

5
.
7

2
1

4
0
7

6
.
1
9
1/
1
2
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2
0
1
6

C
R
W
-
1
0

3
0
.
1
6

2
2
.
0
0

7
5
5
.
2
3

N
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r
m
a
l

N
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n
e

C
P

N
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1
.
3
3

4
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2
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S

1
4
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5
6

1
4
6

5
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3

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8
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6
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6
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0
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6

C
R
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.
5
2

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.
1
2

7
8
6
.
0
0

C
o
l
l
o
i
d
a
l

N
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n
e

C
P

N
/
A

1
.
3
7

9
.
0
0

N
O

1
4
.
4
3

1
1
3

6
.
1

5
6
.
7

4
5
8

8
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1
3
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1
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6

C
R
W
-
1
2

4
4
.
6
5

3
5
.
1
8

8
0
2
.
7
5

N
o
r
m
a
l

N
o
n
e

L
F

4
3
5

1
.
5
4

5
.
5
5

N
/
A

1
3
.
9
5

7
8

5
.
6

1
3
.
4

4
6
6

6
.
8
8
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0
1
6

C
R
W
-
1
3

3
9
.
2
8

3
1
.
5
7

7
9
0
.
9
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N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
2
6

6
.
0
0

N
O

1
3
.
6
2

1
6
0

5
.
8

7
.
3

4
3
0

7
.
9
5
1/
1
1
/
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0
1
6

C
R
W
-
1
4

4
1
.
4
4

2
1
.
5
3

7
7
3
.
3
4

N
o
r
m
a
l

N
o
n
e

L
F

4
2
0

3
.
2
5

5
.
4
5

N
/
A

1
4
.
4
6

2
1
3

5
.
6

2
.
9

3
7
4

6
.
1
1
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1
1
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0
1
6

C
R
W
-
1
5

3
8
.
8
2

3
4
.
2
9

7
3
4
.
1
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N
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r
m
a
l

N
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n
e

L
F

2
1
0

0
.
7
4

1
.
3
5

N
/
A

1
3
.
7
3

8
5

5
.
4

2
.
5

3
9
7

7
.
4
4
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1
1
/
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0
1
6

C
R
W
-
1
6

5
0
.
6
6

4
2
.
5
7

7
3
1
.
0
2

N
o
r
m
a
l

N
o
n
e

L
F

1
9
2

1
.
3
2

1
.
8
0

N
/
A

1
1
.
1
7

6
2

5
.
6

9
.
9

4
0
3

4
.
1
4
1/
1
2
/
2
0
1
6

C
R
W
-
1
7

4
1
.
7
0

3
5
.
8
6

7
9
8
.
7
0

C
o
l
l
o
i
d
a
l

N
o
n
e

C
P

N
/
A

0
.
9
5

5
.
0
0

N
O

1
3
.
8
0

3
4

5
.
1

4
7
.
5

4
4
3

4
.
8
2
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1
2
/
2
0
1
6

C
R
S
-
1

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
/
A

N
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A

N
/
A

N
/
A

N
/
A

6
.
1
4

1
0
4

6
.
7

1
4
.
4

3
3
9

1
1
.
2
8
1/
1
2
/
2
0
1
6

C
R
S
-
2

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

5
.
7

1
1
7

6
.
8

6
.
9

2
6
0

1
1
.
4
2
1/
1
1
/
2
0
1
6

C
R
S
-
3

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

8
.
6
9

2
6
2

6
.
7

7
.
9

2
7
6

8
.
9
7
1/
1
1
/
2
0
1
6

C
R
S
-
4

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

1
1
.
5
9

1
0
1

6
.
5

3
.
5

3
6
6

6
.
4
4
1/
1
2
/
2
0
1
6

C
R
S
-
5

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

9
.
5
2

7
6

5
.
9

2
.
1

2
7
2

5
.
8
1
1/
1
1
/
2
0
1
6

C
R
S
-
6

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

9
.
5
8

1
0
5

6
.
3

3
.
9

2
9
5

1
0
.
3
6
1/
1
1
/
2
0
1
6

C
W
B
-
1

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

1
5
.
2
6

4
3
3
6

4
.
5

5
.
1

5
2
4

8
.
6
5
1/
1
1
/
2
0
1
6

C
W
B
-
2

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

1
6
.
1
0

6
0
8
0

4
.
0

1
.
9

5
8
2

8
.
7
6
1/
1
1
/
2
0
1
6

C
W
B
-
3

N
/
A

N
/
A

N
/
A
No
t
e
s
:
1
.

P
u
r
g
e

M
e
t
h
o
d
s
;

L
F
=
L
o
w

F
l
o
w
,

C
P
=
C
o
n
v
e
n
t
i
o
n
a
l

P
u
r
g
e

(
3
-
5

w
e
l
l

v
o
l
u
m
e
s
)
,

N
P
=
N
o

P
u
r
g
e

(
H
y
d
r
a
S
l
e
e
v
e
)
,

E
O
P
=
E
q
u
i
p
m
e
n
t

O
n
l
y

P
u
r
g
e
.

P
u
m
p

r
a
t
e

a
p
p
l
i
c
a
b
l
e

t
o

L
F

p
u
r
g
i
n
g

o
n
l
y
.
2
.

F
i
e
l
d

s
a
m
p
l
i
n
g

p
e
r
f
o
r
m
e
d

b
y

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

p
e
r
s
o
n
n
e
l
.
3
.

E
V
A
C

i
n
d
i
c
a
t
e
s

w
h
e
t
h
e
r

t
h
e

w
a
t
e
r

l
e
v
e
l

i
n

t
h
e

w
e
l
l

w
a
s

d
r
a
w
n

d
o
w
n

t
o

t
h
e

l
e
v
e
l

o
f

t
h
e

p
u
m
p

d
u
r
i
n
g

p
u
r
g
i
n
g
.
4
.

µ
Լ /c
m

i
n
d
i
c
a
t
e
s

m
i
c
r
o
m
h
o
s

p
e
r

c
e
n
t
i
m
e
t
e
r
.
5
.

m
L
/
m
i
n

i
n
d
i
c
a
t
e
s

m
i
l
l
i
l
i
t
e
r
s

p
e
r

m
i
n
u
t
e
.
6
.

S
U

i
n
d
i
c
a
t
e
s

S
t
a
n
d
a
r
d

U
n
i
t
s
.
7
.

N
T
U

i
n
d
i
c
a
t
e
s

N
e
p
h
e
l
o
m
e
t
r
i
c

T
u
r
b
i
d
i
t
y

U
n
i
t
s
.
8
.

m
V
-
N
H
E

i
n
d
i
c
a
t
e
s

m
i
l
l
i
v
o
l
t
s
-
N
o
r
m
a
l

H
y
d
r
o
g
e
n

E
l
e
c
t
r
o
d
e
.
9
.

N
/
A

i
n
d
i
c
a
t
e
s

n
o
t

a
p
p
l
i
c
a
b
l
e
.
10
.

L
e
a
c
h
a
t
e

s
a
m
p
l
e
s

C
W
B
-
1

a
n
d

C
W
B
-
2

w
e
r
e

f
o
r
m
e
r
l
y

i
d
e
n
t
i
f
i
e
d

a
s

E
-
W
W
B

L
e
a
c
h
a
t
e

a
n
d

W
-
W
W
B

L
e
a
c
h
a
t
e
,

r
e
s
p
e
c
t
i
v
e
l
y
.
11
.

L
e
a
c
h
a
t
e

s
a
m
p
l
e

C
W
B
-
3

w
a
s

n
o
t

c
o
l
l
e
c
t
e
d

d
u
e

t
o

l
a
c
k

o
f

d
i
s
c
h
a
r
g
e

f
r
o
m

t
h
e

l
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a
c
h
a
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p
i
p
e

i
n
t
o

t
h
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P
h
a
s
e

2

l
e
a
c
h
a
t
e

p
o
n
d
.
12
.

I
n
f
o
r
m
a
t
i
o
n

p
r
o
v
i
d
e
d

b
y

T
i
m

H
u
n
s
u
c
k
e
r

o
f

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s

o
n

F
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b
r
u
a
r
y

8
,

2
0
1
6
.
WE
L
L
VO
L
U
M
E
(g
a
l
)
EV
A
C
VO
L
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M
E
(g
a
l
)
EV
A
C
(y
e
s
/
n
o
)
TE
M
P
(d
e
g

C
)
Dry

-

N
o

S
a
m
p
l
e
SP
E
C
I
F
I
C
CO
N
D
U
C
T
A
N
C
E
(µ
Լ /c
m
)
pH (SU)TURBIDITY (NTU)ORP (mV-NHE)
AP
P
E
A
R
A
N
C
E
DO (mg/L)
OD
O
R
PU
R
G
E
ME
T
H
O
D

PU
M
P

R
A
T
E
(m
L
/
m
i
n
)
SA
M
P
L
E
DA
T
E
S

S
A
M
P
L
E

I
D
WE
L
L
DE
P
T
H
(f
t
)
DE
P
T
H

T
O
WA
T
E
R
(ft
)
WA
T
E
R
EL
E
V
.
(ft
)
Page 1 of 1
Ta
b
l
e

4

-

G
r
o
u
n
d
w
a
t
e
r

F
i
e
l
d

a
n
d

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C
/
B
e
l
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6

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2
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26
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No
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:
1
.

1
5
A

N
C
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2
L

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f
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d

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1
5
A

N
C
A
C

0
2
L

.
0
2
0
2

G
r
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u
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w
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y

S
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,

l
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m
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A
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l

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Page 1 of 1

A
Appendix A
Field Sampling Forms

ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬▬►0.0 0.0 ▬/▬►0.0
SS 222.0 ▬▬►227 227.2 ▬▬►227
SS 73.0 ▬/▬►75 74.1 ▬/▬►75
SS ▬/▬►▬/▬►
B (7.00)7.13 ▬▬►7.02 7.01 ▬▬►7.02
B (4.00)3.94 ▬▬►4.00 4.05 ▬▬►4.00
B (10.00)10.19 ▬/▬►10.06 10.03 ▬/▬►10.06
20.35 19.95
pH Check B (7.00)▬▬►
Time:
SS (7.00)445 ▬▬►441 441 ▬▬►441
SS (4.00)N/A ▬/▬►N/A N/A ▬/▬►N/A
Zobell's 20.20 19.86
W 8.80 8.90
W 9.00 8.90
AW 8.78 ▬▬►8.90 8.84 ▬▬►8.90
SS 55.1 ▬/▬►54.3 55.1 ▬/▬►54.3
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
FIELD SAMPLING CALIBRATION FORM
STUDY:BELEWS CREEK STEAM STATION - CRAIG ROAD LANDFILL GROUNDWATER MONITORING
DATE (s):January 11 - 12, 2016 SURFACE UNIT READER:LDC
OTHER EQUIPMENT:TURBIDIMETER NO.2 - 3260-GW Clear, calm, 20 to 45 deg F
COLLECTORS:LDC, PSP SURFACE UNIT SERIAL #:0662
ANALYZER MODEL#:HL4 400437
PROCEDURE #:HYDROLAB 3210.5 VALIDATED BY:
Calibration Date / Time 11-Jan-16 4:20 12-Jan-16 4:15
CALIBRATION BP (mmHg)743.7 CALIBRATION BP (mmHg)744.5
Parameter Calibration Results Calibration Results
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)
Instrument Zeroed Zero Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
pH
(units)
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Buffer Temp.Buffer Temp.
Buffer Temp.
ORP
(mV)
Calibration Accepted Calibration Pass
ORP Temp.ORP Temp.
Calibration Pass
TURB
(ntu)Calibration Accepted Calibration Accepted
DO
(mg/L)Calibration Accepted
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 744.7 (mmHg)Ending BP 746.0
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬▬►0.0 0.0 ▬/▬►0.0
SS 227.2 ▬▬►227 229.1 ▬/▬►227
SS 74.1 ▬/▬►75 74.8 ▬/▬►75
SS ▬/▬►▬/▬►
B (7.00)7.01 ▬▬►7.02 7.03 ▬/▬►7.02
B (4.00)4.05 ▬▬►4.00 3.99 ▬/▬►4.00
B (10.00)10.03 ▬/▬►10.06 10.11 ▬/▬►10.06
19.95 20.13
pH Check B (7.00)▬▬►
Time:
SS (7.00)441 ▬▬►441 442 ▬/▬►441
SS (4.00)N/A ▬/▬►N/A N/A ▬/▬►N/A
Zobell's 19.86 20.08
W 8.90 9.00
W 8.90 9.00
AW 8.84 ▬▬►8.90 8.95 ▬/▬►9.00
SS 55.1 ▬/▬►54.3 54.7 ▬/▬►54.3
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
FIELD SAMPLING CALIBRATION FORM
STUDY:BELEWS CREEK STEAM STATION - CRAIG ROAD LANDFILL GROUNDWATER MONITORING
DATE (s):January 11 - 12, 2016 SURFACE UNIT READER:LDC
OTHER EQUIPMENT:TURBIDIMETER NO.2 - 3260-GW Clear, calm, 25 to 40 deg F
COLLECTORS:LDC, PSP SURFACE UNIT SERIAL #:0662
ANALYZER MODEL#:HL4 400437
PROCEDURE #:HYDROLAB 3210.5 VALIDATED BY:
Calibration Date / Time 12-Jan-16 4:15 13-Jan-16 6:45
CALIBRATION BP (mmHg)744.5 CALIBRATION BP (mmHg)746.0
Parameter Calibration Results Calibration Results
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)
Instrument Zeroed Zero Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
pH
(units)
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Buffer Temp.Buffer Temp.
Buffer Temp.
ORP
(mV)
Calibration Accepted Calibration Pass
ORP Temp.ORP Temp.
Calibration Pass
TURB
(ntu)Calibration Accepted Calibration Accepted
DO
(mg/L)Calibration Accepted
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 742.7 (mmHg)Ending BP 741.4
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬/▬►0.0 0.0 ▬/▬►0.0
SS 227.1 ▬▬►227 226.4 ▬▬►227
SS 73.7 ▬/▬►75 73.7 ▬/▬►75
SS ▬/▬►▬/▬►
B (7.00)6.93 ▬▬►7.02 7.10 ▬▬►7.02
B (4.00)3.97 ▬▬►4.00 4.03 ▬▬►4.00
B (10.00)10.03 ▬/▬►10.04 10.16 ▬/▬►10.06
20.50 20.04
pH Check B (7.00)▬▬►
Time:
SS (7.00)448 ▬▬►440 440 ▬▬►441
SS (4.00)N/A ▬/▬►N/A N/A ▬/▬►N/A
Zobell's 20.27 19.92
W 8.80 8.90
W 9.00 8.90
AW 8.85 ▬▬►8.90 8.88 ▬▬►8.90
SS 54.5 ▬/▬►54.1 54.0 ▬/▬►54.1
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
FIELD SAMPLING CALIBRATION FORM
STUDY:BELEWS CREEK STEAM STATION - CRAIG ROAD LANDFILL GROUNDWATER MONITORING
DATE (s):January 11 - 12, 2016 SURFACE UNIT READER:PSP
OTHER EQUIPMENT:TURBIDIMETER NO.1 - 3260-GW Clear, calm, 20 to 45 deg F
COLLECTORS:LDC, PSP SURFACE UNIT SERIAL #:S05042
ANALYZER MODEL#:MS5 66120
PROCEDURE #:HYDROLAB 3210.5 VALIDATED BY:
Calibration Date / Time 11-Jan-16 4:00 12-Jan-16 4:00
CALIBRATION BP (mmHg)743.7 CALIBRATION BP (mmHg)744.5
Parameter Calibration Results Calibration Results
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)
Instrument Zeroed Zero Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
pH
(units)
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Buffer Temp.Buffer Temp.
Buffer Temp.
ORP
(mV)
Calibration Accepted Calibration Pass
ORP Temp.ORP Temp.
Calibration Pass
TURB
(ntu)Calibration Accepted Calibration Accepted
DO
(mg/L)Calibration Accepted
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 744.7 (mmHg)Ending BP 746.0
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬/▬►0.0 0.0 ▬/▬►0.0
SS 226.4 ▬▬►227 226.8 ▬/▬►227
SS 73.7 ▬/▬►75 73.1 ▬/▬►75
SS ▬/▬►▬/▬►
B (7.00)7.10 ▬▬►7.02 7.00 ▬/▬►7.02
B (4.00)4.03 ▬▬►4.00 4.00 ▬/▬►4.00
B (10.00)10.16 ▬/▬►10.06 10.13 ▬/▬►10.06
20.04 20.26
pH Check B (7.00)▬▬►
Time:
SS (7.00)440 ▬▬►441 440 ▬/▬►441
SS (4.00)N/A ▬/▬►N/A N/A ▬/▬►N/A
Zobell's 19.92 20.20
W 8.90 9.00
W 8.90 9.00
AW 8.88 ▬▬►8.90 8.98 ▬/▬►9.00
SS 54.0 ▬/▬►54.1 54.0 ▬/▬►54.1
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
FIELD SAMPLING CALIBRATION FORM
STUDY:BELEWS CREEK STEAM STATION - CRAIG ROAD LANDFILL GROUNDWATER MONITORING
DATE (s):January 11 - 12, 2016 SURFACE UNIT READER:PSP
OTHER EQUIPMENT:TURBIDIMETER NO.1 - 3260-GW Clear, calm, 25 to 40 deg F
COLLECTORS:LDC, PSP SURFACE UNIT SERIAL #:S05042
ANALYZER MODEL#:MS5 66120
PROCEDURE #:HYDROLAB 3210.5 VALIDATED BY:
Calibration Date / Time 12-Jan-16 4:00 13-Jan-16 6:35
CALIBRATION BP (mmHg)744.5 CALIBRATION BP (mmHg)746.0
Parameter Calibration Results Calibration Results
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)
Instrument Zeroed Zero Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
pH
(units)
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Buffer Temp.Buffer Temp.
Buffer Temp.
ORP
(mV)
Calibration Accepted Calibration Pass
ORP Temp.ORP Temp.
Calibration Pass
TURB
(ntu)Calibration Accepted Calibration Accepted
DO
(mg/L)Calibration Accepted
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 742.7 (mmHg)Ending BP 741.4
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
28.24 38.24
15 (psi)6 (sec)(sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CRW-2
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)761.46 MIDDLE OF WETTED SCREEN (ft toc)33.24
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)38.24 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)36.00
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 6
28650 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
LIFT WELL CAP ONE FOOT UP FROM PVC WELL
CASING AND PUMP AT 480 mL/min.
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)23.27 WATER COLUMN (ft)14.97 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)738.19 WELL VOLUME 2.44
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
9:05 25.64 250 14.29 34 5.79 57.7 416 7.63 N/A
9:00 25.64 250 14.32 32 5.67 65.7 415 7.57
N/A
9:15 25.64 250 13.91 35 5.80 44.1 420 7.72 N/A
9:10 25.64 250 13.93 35 5.76 59.7 419 7.72
N/A
9:25 25.64 250 13.94 36 5.82 43.1 433 7.78 N/A
9:20 25.64 250 13.77 36 5.77 37.3 428 7.79
N/A
9:35 25.64 250 13.77 37 5.91 37.7 442 7.74 N/A
9:30 25.64 250 13.64 37 5.92 35.5 438 7.77
N/A
9:45 25.64 250 14.46 36 5.86 23.0 450 7.67 N/A
9:40 25.64 250 14.29 37 5.94 25.4 446 7.67
DRAW-DOWN 2.37 (ft)CHLORINE
(mg/l)INITIAL PURGE VOLUME 1.75 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 4.75 (gal)PSP 1/11/2016 0950 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
8.84 18.84
15 (psi)7 (sec)(sec)
(gal)
1.78 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
13.00 PSP 1/11/2016 1135 N/A
5.00 NO 14.67 67 5.60 46.4 444 4.60
2.00 NO 14.69 67 5.64 154.0 442 4.44
2.00 NO 14.72 67 5.74 325.0 431 4.32
2.00 NO 14.66 66 5.65 708.0 397 4.11
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
2.00 NO 14.73 66 5.57 319.0 413
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
4.13
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)7.95 WATER COLUMN (ft)10.89 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)738.44 WELL VOLUME 1.78
LIFT WELL CAP ONE FOOT UP FROM PVC WELL
CASING AND PUMP AT 528 mL/min.
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 3
28650 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)746.39 MIDDLE OF WETTED SCREEN (ft toc)13.84
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)18.84 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)17.50
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CRW-3
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
20.19 30.19
18 (psi)9 (sec)(sec)
(gal)
1.62 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
5.25 PSP 1/11/2016 1205 N/A
1.75 NO 15.35 68 6.37 4.1 431 8.45
1.75 NO 15.41 68 6.37 5.9 428 8.50
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.75 NO 15.43 68 6.36 9.0 422
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
8.55
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)20.26 WATER COLUMN (ft)9.93 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)753.27 WELL VOLUME 1.62
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 6
28650 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)773.53 MIDDLE OF WETTED SCREEN (ft toc)25.23
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)30.19 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)29.00
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CRW-4
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
13.16 23.16
18 (psi)10 (sec)(sec)
(gal)
1.14 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
3.75 PSP 1/12/2016 0830 N/A
1.25 NO 14.77 87 5.96 3.6 241 0.28
1.25 NO 14.95 87 5.96 10.4 245 0.22
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.25 NO 15.68 89 5.95 57.5 247
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
0.20
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)16.14 WATER COLUMN (ft)7.02 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)748.60 WELL VOLUME 1.14
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
28650 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)764.74 MIDDLE OF WETTED SCREEN (ft toc)19.65
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)23.16 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)22.50
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CRW-5
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
20.20 30.20
18 (psi)9 (sec)(sec)
(gal)
1.43 (gal)
@
QC By:
SAMPLING NOTES
Well evacuated on 1/11/16 @ 1245 HRS. @ 0850 hrs on 1/12/16 water level was 21.40 feet Bleow TOC (1.44 GAL).
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
3.50 PSP 1/12/2016 0855 N/A
0.50 YES 15.40 52 5.45 143.0 479 3.28
0.50
0.50 27.72 NO 16.39 49 5.52 93.4 487 4.38 0.40
1.00 27.12 NO 16.86 47 5.56 80.5 496 5.00
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.50 25.46 NO 17.08 45 5.50 42.6 502
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
6.05 0.77
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)21.46 WATER COLUMN (ft)8.74 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)761.64 WELL VOLUME 1.43
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 6
28650 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)783.10 MIDDLE OF WETTED SCREEN (ft toc)25.83
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)30.20 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)29.00
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CRW-6
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
19.90 29.90
18 (psi)5 (sec)(sec)
(gal)
1.22 (gal)
@
QC By:
SAMPLING NOTES
Well evacuated 1/11/16 @ 1300 HRS. On 1/12/16 @ 0910 hrs water level was 22.22 feet below TOC (1.25 GAL).
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
1.25 PSP 1/12/2016 0915 N/A
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.25 YES 16.33 51 5.71 292.0 455
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
6.85
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)22.40 WATER COLUMN (ft)7.50 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)762.68 WELL VOLUME 1.22
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
28650 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)785.08 MIDDLE OF WETTED SCREEN (ft toc)26.15
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)29.90 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)29.00
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CRW-7
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
30.18 40.18
18 (psi)10 (sec)(sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CRW-8R
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)776.39 MIDDLE OF WETTED SCREEN (ft toc)35.18
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)40.18 GS ELEV (ft msl)773.68 PUMP INTAKE DEPTH (ft TOC)39.68
SEE NOTE BELOW FOR SAMPLING PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
28650 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
2.00
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)27.90 WATER COLUMN (ft)12.28 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)748.49 WELL VOLUME
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
10:00 28.37 330 14.69 65 5.67 16.9 399 7.89 N/A
9:55 28.37 330 14.31 65 5.70 19.0 393 7.98
N/A
10:10 28.37 330 14.73 64 5.76 13.2 406 7.87 N/A
10:05 28.37 330 14.68 66 5.74 17.9 402 7.85
DRAW-DOWN 0.47 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 1.75 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 3.10 (gal)PSP 1/12/2016 1015 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
Lift well cap up one foot from PVC well casing, pump at 330 mL/min with settings indicated above and remove 2 gallons prior to recording low flow parameters.
29.62 39.62
18 (psi)10 (sec)(sec)
(gal)
@
QC By:
SAMPLING NOTES
Turbidity will decrease below 10 ntu if well is pumped at a flow rate of 200 mL/min.
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE VOLUME 5.10 (gal)PSP 1/12/2016 1135 NA
DRAW-DOWN 2.11 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 2.00 (gal)SAMPLE COLLECTED BY DATE TIME
N/A
11:30 27.90 330 15.04 49 5.72 21.0 407 6.19 N/A
11:25 27.90 330 15.09 49 5.71 25.5 404 6.20
N/A
11:20 27.90 330 14.90 49 5.73 24.8 400 6.22 N/A
11:15 27.90 330 14.93 49 5.75 34.1 396 6.22
N/A
11:10 27.90 330 14.87 49 5.74 43.0 391 6.26 N/A
11:05 27.90 330 15.11 49 5.71 71.0 385 6.33
N/A
11:00 27.90 330 15.08 48 5.86 132.0 377 6.38 N/A
10:55 27.90 330 15.07 46 5.87 245.0 377 6.70
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)25.79 WATER COLUMN (ft)13.83 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)743.88 WELL VOLUME 2.26
Target flow rate of 200 ml/min - See note PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
28650 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)769.67 MIDDLE OF WETTED SCREEN (ft toc)34.62
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)39.62 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)38.50
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CRW-9
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
20.16 30.16
18 (psi)10 (sec)(sec)
(gal)
1.33 (gal)
@
QC By:
SAMPLING NOTES
Evacuated 1/12/16 at 1115 hrs
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
4.25 LDC 1/12/2016 1120 N/A
1.25 YES 14.56 146 5.27 28.4 465 5.56
1.50 NO 14.66 142 5.27 38.1 461 5.62
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.50 NO 14.84 130 5.27 87.0 456
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
5.78
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)22.00 WATER COLUMN (ft)8.16 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)755.23 WELL VOLUME 1.33
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)777.23 MIDDLE OF WETTED SCREEN (ft toc)26.08
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)30.16 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)29.00
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CRW-10
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
28.52 38.52
15 (psi)11 (sec)(sec)
(gal)
1.37 (gal)
@
QC By:
SAMPLING NOTES
Remove hydraulic head by drawing down water level to 33.00 ft at 360 mL/min. Had to thaw discharge line. After 3rd reading, lowered pressure to 15 psi attempting to lower
turbidity. Next time, remove 2 well volumes prior to beginning field measurements.
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
9.00 LDC 1/12/2016 1025 N/A
1.50 NO 14.43 113 6.08 56.7 458 8.13
3.00 NO 14.47 113 6.11 115.0 451 8.07
1.50 NO 15.07 110 6.10 381.0 445 8.06
1.50 NO 15.09 110 6.09 327.0 440 8.01
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.50 NO 15.08 102 6.10 198.0 435
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
8.34
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
1.37
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Colloidal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)30.12 WATER COLUMN (ft)8.40 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)786.00 WELL VOLUME
SEE NOTE FOR SAMPLING PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 4
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)816.12 MIDDLE OF WETTED SCREEN (ft toc)34.32
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)38.52 GS ELEV (ft msl)813.38 PUMP INTAKE DEPTH (ft TOC)37.52
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CRW-11
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
34.65 44.65
15 (psi)10 (sec)(sec)
(gal)
@
QC By:
SAMPLING NOTES
Lift well cap up 3 ft from top of PVC well casing and pump at 400 mL/min
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE VOLUME 5.55 (gal)LDC 1/11/2016 0825 NA
DRAW-DOWN 1.23 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 1.50 (gal)SAMPLE COLLECTED BY DATE TIME
N/A
8:20 36.41 435 13.95 78 5.55 13.4 466 6.88 N/A
8:15 36.41 435 13.88 78 5.55 17.3 464 6.87
N/A
8:10 36.41 435 13.93 79 5.55 20.5 462 6.83 N/A
8:05 36.41 435 14.05 80 5.54 33.3 459 6.79
N/A
8:00 36.41 435 14.01 80 5.52 64.1 457 6.80 N/A
7:55 36.41 435 14.08 80 5.49 91.9 454 6.90
N/A
7:50 36.41 435 13.95 78 5.40 73.7 450 7.05 N/A
7:45 36.41 435 14.06 74 5.33 109.0 443 7.21
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
1.54
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)35.18 WATER COLUMN (ft)9.47 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)802.75 WELL VOLUME
SEE NOTE FOR SAMPLING PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)837.93 MIDDLE OF WETTED SCREEN (ft toc)39.92
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)44.65 GS ELEV (ft msl)835.00 PUMP INTAKE DEPTH (ft TOC)44.15
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CRW-12
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
29.28 39.28
19 (psi)10 (sec)(sec)
(gal)
1.26 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
6.00 LDC 1/11/2016 0935 N/A
1.50 NO 13.62 160 5.83 7.3 430 7.95
1.50 NO 13.46 158 5.83 11.9 429 7.97
1.50 NO 13.54 153 5.84 33.5 430 8.06
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.50 NO 13.86 130 5.84 93.1 451
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
8.13
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
1.26
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)31.57 WATER COLUMN (ft)7.71 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)790.92 WELL VOLUME
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)822.49 MIDDLE OF WETTED SCREEN (ft toc)35.43
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)39.28 GS ELEV (ft msl)819.44 PUMP INTAKE DEPTH (ft TOC)38.78
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CRW-13
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
26.44 41.44
20 (psi)5 (sec)(sec)
(gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE VOLUME 5.45 (gal)LDC 1/11/2016 1045 NA
DRAW-DOWN 0.14 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 1.00 (gal)SAMPLE COLLECTED BY DATE TIME
N/A10:40 21.67 420 14.46 213 5.64 2.9 374 6.11
N/A
10:35 21.67 420 14.53 217 5.65 2.8 373 5.98 N/A
10:30 21.67 420 14.51 226 5.67 3.3 372 5.76
N/A
10:25 21.67 420 14.46 241 5.72 3.0 372 5.30 N/A
10:20 21.67 420 14.35 261 5.76 3.1 371 4.72
N/A
10:15 21.67 420 14.33 289 5.84 3.8 370 4.00 N/A
10:10 21.67 420 14.28 346 5.99 3.3 266 2.88
N/A
10:05 21.67 420 14.32 384 6.11 4.1 366 2.44 N/A
10:00 21.67 420 14.10 416 6.33 4.1 380 2.05
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
3.25
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)21.53 WATER COLUMN (ft)19.91 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)773.34 WELL VOLUME
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)794.87 MIDDLE OF WETTED SCREEN (ft toc)33.94
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)41.44 GS ELEV (ft msl)792.23 PUMP INTAKE DEPTH (ft TOC)40.44
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CRW-14
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
28.82 38.82
25 (psi)11 (sec)(sec)
(gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE VOLUME 1.35 (gal)LDC 1/11/2016 1130 NA
DRAW-DOWN 1.27 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.50 (gal)SAMPLE COLLECTED BY DATE TIME
N/A
11:25 35.56 210 13.73 85 5.36 2.5 397 7.44 N/A
11:20 35.56 210 13.75 86 5.34 2.6 396 7.36
N/A
11:15 35.56 210 13.65 85 5.36 3.0 394 7.49 N/A
11:10 35.56 210 14.03 71 5.70 3.1 384 8.76
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
0.74
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)34.29 WATER COLUMN (ft)4.53 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)734.14 WELL VOLUME
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 9
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)768.43 MIDDLE OF WETTED SCREEN (ft toc)36.56
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)38.82 GS ELEV (ft msl)765.69 PUMP INTAKE DEPTH (ft TOC)38.32
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CRW-15
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
40.66 50.66
20 (psi)10 (sec)(sec)
(gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE VOLUME 1.80 (gal)PSP 1/11/2016 0810 NA
DRAW-DOWN 0.53 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.75 (gal)SAMPLE COLLECTED BY DATE TIME
N/A8:05 43.10 192 11.17 62 5.55 9.9 403 4.14
N/A
8:00 43.10 192 11.44 62 5.48 12.0 401 4.22 N/A
7:55 43.10 192 11.58 61 5.56 14.0 398 4.33
N/A
7:50 43.10 192 11.68 61 5.35 21.2 397 4.42 N/A
7:45 43.10 192 11.70 63 5.37 40.4 397 4.60
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
1.32
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)42.57 WATER COLUMN (ft)8.09 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)731.02 WELL VOLUME
LIFT WELL CAP FIVE FOOT UP FROM PVC WELL
CASING AND PUMP AT 150 mL/min.
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
28650 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)773.59 MIDDLE OF WETTED SCREEN (ft toc)46.62
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)50.66 GS ELEV (ft msl)770.58 PUMP INTAKE DEPTH (ft TOC)45.16
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CRW-16
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
31.70 41.70
30 (psi)15 (sec)(sec)
(gal)
0.95 (gal)
@
QC By:
SAMPLING NOTES
This well probably evacuates. Leave pump intake where it is (1 ft from bottom) and pump at 200 to 300 mL/min. Pump 2 gallons before recording field parameters to remove
hydraulic head. Had to thaw discharge line.
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
5.00 LDC 1/12/2016 0845 N/A
1.00 NO 13.80 34 5.13 47.5 443 4.82
1.00 NO 13.97 33 5.10 53.0 442 4.88
1.00 NO 14.25 33 5.04 48.2 436 4.67
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
2.00 37.01 NO 13.68 32 5.02 39.6 434
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
4.86 0.76
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
0.95
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Colloidal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)35.86 WATER COLUMN (ft)5.84 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)798.70 WELL VOLUME
SEE NOTES FOR SAMPLING PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)834.56 MIDDLE OF WETTED SCREEN (ft toc)38.78
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)41.70 GS ELEV (ft msl)831.62 PUMP INTAKE DEPTH (ft TOC)40.70
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CRW-17
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SAMPLING NOTES
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
1140
339 11.28
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 6.14 104 6.69 14.4
TIME
LDC 1/12/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT GRAB PURGE METHOD
TUBING DIAMETER (in)No Purge
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CRS-1
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SAMPLING NOTES
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
1205
260 11.42
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 5.70 117 6.82 6.9
TIME
PSP 1/12/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CRS-2
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SAMPLING NOTES
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
1020
276 8.97
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 8.69 262 6.65 7.9
TIME
PSP 1/11/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CRS-3
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SAMPLING NOTES
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
1055
366 6.44
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 11.59 101 6.45 3.5
TIME
PSP 1/11/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CRS-4
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SAMPLING NOTES
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
0740
272 5.81
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 9.52 76 5.85 2.1
TIME
PSP 1/12/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CRS-5
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SAMPLING NOTES
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
1200
295 10.36
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 9.58 105 6.28 3.9
TIME
LDC 1/11/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CRS-6
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Location Formally Called "E-WWB-Leachate"
WELL PAD
WELL CASING
WELL TAG
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
1250
524 8.65
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 15.26 4336 4.52 5.1
TIME
LDC 1/11/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CWB-1
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Location Formally Called "W-WWB-Leachate"
WELL PAD
WELL CASING
WELL TAG
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
1230
582 8.76
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 16.10 6080 4.03 1.9
TIME
LDC 1/11/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CWB-2
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jan-2016 12-Jan-2016 WELL/LOCATION NAME CWB-3
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
No sample / No discharge PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PURGE METHOD
TUBING DIAMETER (in)No Purge
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
PSP 1/11/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Phase 2 Leachate Pond
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
PERMIT #
CRW-2 CRW-3 CRW-4 CRW-5 CRW-6 CRW-7 CRW-8R CRW-9 CRW-10 CRW-11 CRW-12 CRW-13 CRW-14 CRW-15 CRW-16
YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
NORTH CAROLINA GROUNDWATER SAMPLING SITE CHECKLIST
LOCATION / SITE BELEWS CREEK STEAM STATION - CRAIG ROAD LANDFILL GROUNDWATER MONITORING 85-04 SAMPLE DATE January 11 - 12, 2016
SITE CONTACT Melonie Martin, Kim Hutchinson, Will Harrison FIELD CREW LDC, PSP
WEATHER Jan. 11 - clear, calm, 20 to 45 deg F. Jan. 12 - clear, calm, 25 to 40 deg F.
WELL LOCK CONDITION
PAGE 1 OF 2
ACCESS TO WELLS
Access cleared into well
Access cleared around well
Tall grass or weeds - needs mowing
Road washing out / muddy / needs grading
Fallen tree blocking access
WELL SECURITY
Well found locked
Well found unlocked
Undermined / washing out
Lock in good condition
Lock rusted, difficult to open / needs replacing
Replaced damaged lock
WELL CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
CONCRETE PADS
Pad in good condition
Minor cracks
Major cracks / broken / repair required
Replaced damaged well cap
Fire ants around concrete pad
WELL PROTECTIVE CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
Broken hinge on protective lid
Wasp nest inside protective casing
Ants inside protective casing
WELL CAPS
Well cap in good conditon
Damaged / needs replacement
Lacks required information - Completion date
FLUSH MOUNT WELLS
Vault in good condition
Water inside vault
Vault bolt holes broken or stripped
Bolts stripped
Vault lid cracked or broken
WELL ID TAGS
Well tag in good condition
Well tag missing
Well tag damaged / illegible
Lacks required information - Driller Reg #
Lacks required information - Total well depth
Lacks required information - Depth to screen
Lacks required information - Non potable tag
NOTE:
PERMIT #
CRW-17 CRS-1 CRS-2 CRS-3 CRS-4 CRS-5 CRS-6 CWB-1 CWB-2 CWB-3
YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES
YES N/A N/A N/A N/A N/A N/A N/A N/A N/A
YES N/A N/A N/A N/A N/A N/A N/A N/A N/A
YES N/A N/A N/A N/A N/A N/A N/A N/A N/A
YES N/A N/A N/A N/A N/A N/A N/A N/A N/A
YES N/A N/A N/A N/A N/A N/A N/A N/A N/A
YES N/A N/A N/A N/A N/A N/A N/A N/A N/A
N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
YES N/A N/A N/A N/A N/A N/A N/A N/A N/A
Lacks required information - Total well depth
Lacks required information - Depth to screen
Lacks required information - Non potable tag
NOTE:
Lacks required information - Completion date
FLUSH MOUNT WELLS
Vault in good condition
Water inside vault
Vault bolt holes broken or stripped
Bolts stripped
Vault lid cracked or broken
WELL ID TAGS
Well tag in good condition
Well tag missing
Well tag damaged / illegible
Lacks required information - Driller Reg #
Replaced damaged well cap
Fire ants around concrete pad
WELL PROTECTIVE CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
Broken hinge on protective lid
Wasp nest inside protective casing
Ants inside protective casing
WELL CAPS
Well cap in good conditon
Damaged / needs replacement
Undermined / washing out
Lock in good condition
Lock rusted, difficult to open / needs replacing
Replaced damaged lock
WELL CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
CONCRETE PADS
Pad in good condition
Minor cracks
Major cracks / broken / repair required
WELL LOCK CONDITION
PAGE 2 OF 2
ACCESS TO WELLS
Access cleared into well
Access cleared around well
Tall grass or weeds - needs mowing
Road washing out / muddy / needs grading
Fallen tree blocking access
WELL SECURITY
Well found locked
Well found unlocked
SITE CONTACT Melonie Martin, Kim Hutchinson, Will Harrison FIELD CREW LDC, PSP
WEATHER Jan. 11 - clear, calm, 20 to 45 deg F. Jan. 12 - clear, calm, 25 to 40 deg F.
NORTH CAROLINA GROUNDWATER SAMPLING SITE CHECKLIST
LOCATION / SITE BELEWS CREEK STEAM STATION - CRAIG ROAD LANDFILL GROUNDWATER MONITORING 85-04 SAMPLE DATE January 11 - 12, 2016
WELL DEPTH TO WATER Purge AVG *WELL EVAC SPECIFIC
WELL DEPTH WATER ELEV.Method PMP RATE VOL VOL EVAC TEMP CONDUCTANCE pH TURBIDITY ORP DO
DATE NO.(feet-toc)(feet-toc)(feet)APPEARANCE ODOR (ml/min)(gal)(gal)(yes/no)(deg C)(umho/cm)(units)(NTU)(mV-NHE)(mg/l)
1/11/2016 CRW-2 38.24 23.27 738.19 Normal None LF 250 2.44 4.75 N/A 14.46 36 5.9 23.0 450 7.67
1/11/2016 CRW-3 18.84 7.95 738.44 Normal None C N/A 1.78 13.00 NO 14.67 67 5.6 46.4 444 4.60
1/11/2016 CRW-4 30.19 20.26 753.27 Normal None C N/A 1.62 5.25 NO 15.35 68 6.4 4.1 431 8.45
1/12/2016 CRW-5 23.16 16.14 748.60 Normal None C N/A 1.14 3.75 NO 14.77 87 6.0 3.6 241 0.28
1/12/2016 CRW-6 30.20 21.46 761.64 Normal None C N/A 1.43 3.50 YES 15.40 52 5.5 143.0 479 3.28
1/12/2016 CRW-7 29.90 22.40 762.68 Normal None C N/A 1.22 1.25 YES 16.33 51 5.7 292.0 455 6.85
1/12/2016 CRW-8R 40.18 27.90 748.49 Normal None LF 330 2.00 3.10 N/A 14.73 64 5.8 13.2 406 7.87
1/12/2016 CRW-9 39.62 25.79 743.88 Normal None LF 330 2.26 5.10 N/A 15.04 49 5.7 21.0 407 6.19
1/12/2016 CRW-10 30.16 22.00 755.23 Normal None C N/A 1.33 4.25 YES 14.56 146 5.3 28.4 465 5.56
1/12/2016 CRW-11 38.52 30.12 786.00 Colloidal None C N/A 1.37 9.00 NO 14.43 113 6.1 56.7 458 8.13
1/11/2016 CRW-12 44.65 35.18 802.75 Normal None LF 435 1.54 5.55 N/A 13.95 78 5.6 13.4 466 6.88
1/11/2016 CRW-13 39.28 31.57 790.92 Normal None C N/A 1.26 6.00 NO 13.62 160 5.8 7.3 430 7.95
1/11/2016 CRW-14 41.44 21.53 773.34 Normal None LF 420 3.25 5.45 N/A 14.46 213 5.6 2.9 374 6.11
1/11/2016 CRW-15 38.82 34.29 734.14 Normal None LF 210 0.74 1.35 N/A 13.73 85 5.4 2.5 397 7.44
1/11/2016 CRW-16 50.66 42.57 731.02 Normal None LF 192 1.32 1.80 N/A 11.17 62 5.6 9.9 403 4.14
1/12/2016 CRW-17 41.70 35.86 798.70 Colloidal None C N/A 0.95 5.00 NO 13.80 34 5.1 47.5 443 4.82
1/12/2016 CRS-1 N/A N/A N/A Normal None NP N/A N/A N/A N/A 6.14 104 6.7 14.4 339 11.28
1/12/2016 CRS-2 N/A N/A N/A Normal None NP N/A N/A N/A N/A 5.70 117 6.8 6.9 260 11.42
1/11/2016 CRS-3 N/A N/A N/A Normal None NP N/A N/A N/A N/A 8.69 262 6.7 7.9 276 8.97
1/11/2016 CRS-4 N/A N/A N/A Normal None NP N/A N/A N/A N/A 11.59 101 6.5 3.5 366 6.44
1/12/2016 CRS-5 N/A N/A N/A Normal None NP N/A N/A N/A N/A 9.52 76 5.9 2.1 272 5.81
1/11/2016 CRS-6 N/A N/A N/A Normal None NP N/A N/A N/A N/A 9.58 105 6.3 3.9 295 10.36
1/11/2016 CWB-1 N/A N/A N/A Normal None NP N/A N/A N/A N/A 15.26 4336 4.5 5.1 524 8.65
1/11/2016 CWB-2 N/A N/A N/A Normal None NP N/A N/A N/A N/A 16.10 6080 4.0 1.9 582 8.76
1/11/2016 CWB-3 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
Purge Methods
LF = Low Flow
LF(M) = Low Flow (Mod.)
C = Connventional
NP = No Purge
EOP = Equip. Only Purge
LO = Level Only
* = Applicable to LF & LF(M) Purging Only
No Flow
BELEWS CREEK STEAM STATION
CRAIG ROAD LANDFILL
GROUNDWATER MONITORING FIELD DATA
PERMIT #85-04

B
Appendix B
Laboratory Report and
Chain-of-Custody Forms

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16010004
Project Name:BELEWS - GW CRAIG ROAD LF
Lab Contact:Peggy Kendall
Date:2/2/2016
Customer Address:3195 Pine Hall Rd
Customer Name(s):Chuck Campbell, T. Hunsucker, Ed Sullivan
Mailcode: Belews Steam Station
Belews Creek, NC 28012
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Peggy Kendall
Page 1 of 44
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016000005 BELEWS 11-Jan-16 9:50 AM PSP CRW-2
2016000006 BELEWS 11-Jan-16 11:35 AM PSP CRW-3
2016000007 BELEWS 11-Jan-16 12:05 PM PSP CRW-4
2016000008 BELEWS 12-Jan-16 8:30 AM PSP CRW-5
2016000009 BELEWS 12-Jan-16 8:55 AM PSP CRW-6
2016000010 BELEWS 12-Jan-16 9:15 AM PSP CRW-7
2016000011 BELEWS 12-Jan-16 10:15 AM PSP CRW-8R
2016000012 BELEWS 12-Jan-16 11:35 AM PSP CRW-9
2016000013 BELEWS 12-Jan-16 11:20 AM LDC CRW-10
2016000014 BELEWS 12-Jan-16 10:25 AM LDC CRW-11
2016000015 BELEWS 11-Jan-16 8:25 AM LDC CRW-12
2016000016 BELEWS 11-Jan-16 9:35 AM LDC CRW-13
2016000017 BELEWS 11-Jan-16 10:45 AM LDC CRW-14
2016000018 BELEWS 11-Jan-16 11:30 AM LDC CRW-15
2016000019 BELEWS 11-Jan-16 8:10 AM PSP CRW-16
2016000020 BELEWS 12-Jan-16 8:45 AM LDC CRW-17
2016000021 BELEWS 11-Jan-16 12:50 PM LDC CWB-1
2016000022 BELEWS 11-Jan-16 12:30 PM LDC CWB-2
2016000024 BELEWS 12-Jan-16 11:40 AM LDC CRS-1
2016000025 BELEWS 12-Jan-16 12:05 PM PSP CRS-2
2016000026 BELEWS 11-Jan-16 10:20 AM PSP CRS-3
2016000027 BELEWS 11-Jan-16 10:55 AM PSP CRS-4
2016000028 BELEWS 12-Jan-16 7:40 AM PSP CRS-5
2016000029 BELEWS 11-Jan-16 12:00 PM LDC CRS-6
2016000030 BELEWS 12-Jan-16 12:15 PM LDC FIELD BLANK
25 Total Samples
Page 2 of 44
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:2/1/2016
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000005
Collection Date:11-Jan-16 9:50 AM
Site:CRW-2
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)12 mg/L
(CaCO3)
SM 2320B4d 01/18/2016 15:05 GHUTCHI51
INORGANIC IONS BY IC
Chloride 1.9 mg/L EPA 9056A 01/12/2016 09:45 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 01/12/2016 09:45 BGN90340.1 1
Nitrate 0.24 mg/L EPA 9056A 01/12/2016 09:45 BGN90340.1 1
Nitrate as N 0.05 mg-N/L EPA 9056A 01/12/2016 09:45 BGN90340.023 1
Sulfate 0.30 mg/L EPA 9056A 01/12/2016 09:45 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/13/2016 11:01 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.044 mg/L SW 6010C 01/20/2016 11:53 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/20/2016 11:53 FCJORDA0.05 1
Calcium (Ca)2.32 mg/L SW 6010C 01/20/2016 11:53 FCJORDA0.01 1
Chromium (Cr)0.008 mg/L SW 6010C 01/20/2016 11:53 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/20/2016 11:53 FCJORDA0.005 1
Iron (Fe)1.58 mg/L SW 6010C 01/20/2016 11:53 FCJORDA0.01 1
Magnesium (Mg)1.37 mg/L SW 6010C 01/20/2016 11:53 FCJORDA0.005 1
Manganese (Mn)0.022 mg/L SW 6010C 01/20/2016 11:53 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010C 01/20/2016 11:53 FCJORDA0.005 1
Potassium (K)2.54 mg/L SW 6010C 01/20/2016 11:53 FCJORDA0.1 1
Sodium (Na)2.99 mg/L SW 6010C 01/20/2016 11:53 FCJORDA0.05 1
Zinc (Zn)0.007 mg/L SW 6010C 01/20/2016 11:53 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020A 01/13/2016 11:39 SLS256011
Cadmium (Cd)< 1 ug/L SW 6020A 01/13/2016 11:39 SLS256011
Lead (Pb)< 1 ug/L SW 6020A 01/13/2016 11:39 SLS256011
Selenium (Se)< 1 ug/L SW 6020A 01/13/2016 11:39 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/13/2016 11:39 SLS256011
TOTAL DISSOLVED SOLIDS
TDS 45 mg/L SM2540C 01/16/2016 13:06 CJELLIO251
Page 4 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000006
Collection Date:11-Jan-16 11:35 AM
Site:CRW-3
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)13 mg/L
(CaCO3)
SM 2320B4d 01/18/2016 15:05 GHUTCHI51
INORGANIC IONS BY IC
Chloride 6.0 mg/L EPA 9056A 01/12/2016 10:39 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 01/12/2016 10:39 BGN90340.1 1
Nitrate 1.1 mg/L EPA 9056A 01/12/2016 10:39 BGN90340.1 1
Nitrate as N 0.25 mg-N/L EPA 9056A 01/12/2016 10:39 BGN90340.023 1
Sulfate 5.2 mg/L EPA 9056A 01/12/2016 10:39 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/13/2016 11:08 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.078 mg/L SW 6010C 01/20/2016 12:05 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/20/2016 12:05 FCJORDA0.05 1
Calcium (Ca)5.54 mg/L SW 6010C 01/20/2016 12:05 FCJORDA0.01 1
Chromium (Cr)0.027 mg/L SW 6010C 01/20/2016 12:05 FCJORDA0.005 1
Copper (Cu)0.010 mg/L SW 6010C 01/20/2016 12:05 FCJORDA0.005 1
Iron (Fe)14.9 mg/L SW 6010C 01/20/2016 12:05 FCJORDA0.01 1
Magnesium (Mg)6.34 mg/L SW 6010C 01/20/2016 12:05 FCJORDA0.005 1
Manganese (Mn)0.234 mg/L SW 6010C 01/20/2016 12:05 FCJORDA0.005 1
Nickel (Ni)0.015 mg/L SW 6010C 01/20/2016 12:05 FCJORDA0.005 1
Potassium (K)3.40 mg/L SW 6010C 01/20/2016 12:05 FCJORDA0.1 1
Sodium (Na)4.83 mg/L SW 6010C 01/20/2016 12:05 FCJORDA0.05 1
Zinc (Zn)0.035 mg/L SW 6010C 01/20/2016 12:05 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)1.27 ug/L SW 6020A 01/13/2016 11:43 SLS256011
Cadmium (Cd)< 1 ug/L SW 6020A 01/13/2016 11:43 SLS256011
Lead (Pb)6.68 ug/L SW 6020A 01/13/2016 11:43 SLS256011
Selenium (Se)< 1 ug/L SW 6020A 01/13/2016 11:43 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/13/2016 11:43 SLS256011
TOTAL DISSOLVED SOLIDS
TDS 64 mg/L SM2540C 01/16/2016 13:06 CJELLIO251
Page 5 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000007
Collection Date:11-Jan-16 12:05 PM
Site:CRW-4
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)21 mg/L
(CaCO3)
SM 2320B4d 01/18/2016 15:05 GHUTCHI51
INORGANIC IONS BY IC
Chloride 2.6 mg/L EPA 9056A 01/12/2016 10:57 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 01/12/2016 10:57 BGN90340.1 1
Nitrate 5.2 mg/L EPA 9056A 01/12/2016 10:57 BGN90340.1 1
Nitrate as N 1.2 mg-N/L EPA 9056A 01/12/2016 10:57 BGN90340.023 1
Sulfate 3.4 mg/L EPA 9056A 01/12/2016 10:57 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/13/2016 11:10 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L SW 6010C 01/20/2016 12:09 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/20/2016 12:09 FCJORDA0.05 1
Calcium (Ca)5.22 mg/L SW 6010C 01/20/2016 12:09 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010C 01/20/2016 12:09 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/20/2016 12:09 FCJORDA0.005 1
Iron (Fe)0.198 mg/L SW 6010C 01/20/2016 12:09 FCJORDA0.01 1
Magnesium (Mg)1.61 mg/L SW 6010C 01/20/2016 12:09 FCJORDA0.005 1
Manganese (Mn)< 0.005 mg/L SW 6010C 01/20/2016 12:09 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010C 01/20/2016 12:09 FCJORDA0.005 1
Potassium (K)1.70 mg/L SW 6010C 01/20/2016 12:09 FCJORDA0.1 1
Sodium (Na)5.40 mg/L SW 6010C 01/20/2016 12:09 FCJORDA0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010C 01/20/2016 12:09 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020A 01/13/2016 11:24 SLS256011
Cadmium (Cd)< 1 ug/L SW 6020A 01/13/2016 11:24 SLS256011
Lead (Pb)< 1 ug/L SW 6020A 01/13/2016 11:24 SLS256011
Selenium (Se)< 1 ug/L SW 6020A 01/13/2016 11:24 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/13/2016 11:24 SLS256011
TOTAL DISSOLVED SOLIDS
TDS 56 mg/L SM2540C 01/16/2016 13:06 CJELLIO251
Page 6 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000008
Collection Date:12-Jan-16 8:30 AM
Site:CRW-5
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)24 mg/L
(CaCO3)
SM 2320B4d 01/18/2016 15:05 GHUTCHI51
INORGANIC IONS BY IC
Chloride 2.6 mg/L EPA 9056A 01/13/2016 14:48 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 01/13/2016 14:48 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 01/13/2016 14:48 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 01/13/2016 14:48 BGN90340.023 1
Sulfate 13 mg/L EPA 9056A 01/13/2016 14:48 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/28/2016 10:50 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.014 mg/L SW 6010C 01/20/2016 13:27 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/20/2016 13:27 FCJORDA0.05 1
Calcium (Ca)3.26 mg/L SW 6010C 01/20/2016 13:27 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010C 01/20/2016 13:27 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/20/2016 13:27 FCJORDA0.005 1
Iron (Fe)6.77 mg/L SW 6010C 01/20/2016 13:27 FCJORDA0.01 1
Magnesium (Mg)2.79 mg/L SW 6010C 01/20/2016 13:27 FCJORDA0.005 1
Manganese (Mn)0.096 mg/L SW 6010C 01/20/2016 13:27 FCJORDA0.005 1
Nickel (Ni)0.013 mg/L SW 6010C 01/20/2016 13:27 FCJORDA0.005 1
Potassium (K)1.48 mg/L SW 6010C 01/20/2016 13:27 FCJORDA0.1 1
Sodium (Na)4.20 mg/L SW 6010C 01/20/2016 13:27 FCJORDA0.05 1
Zinc (Zn)0.016 mg/L SW 6010C 01/20/2016 13:27 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020A 01/15/2016 12:21 SLS256011
Cadmium (Cd)< 1 ug/L SW 6020A 01/15/2016 12:21 SLS256011
Lead (Pb)< 1 ug/L SW 6020A 01/15/2016 12:21 SLS256011
Selenium (Se)< 1 ug/L SW 6020A 01/15/2016 12:21 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/15/2016 12:21 SLS256011
TOTAL DISSOLVED SOLIDS
TDS 63 mg/L SM2540C 01/16/2016 13:06 CJELLIO251
Page 7 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000009
Collection Date:12-Jan-16 8:55 AM
Site:CRW-6
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B4d 01/18/2016 15:05 GHUTCHI51
INORGANIC IONS BY IC
Chloride 1.5 mg/L EPA 9056A 01/13/2016 15:05 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 01/13/2016 15:05 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 01/13/2016 15:05 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 01/13/2016 15:05 BGN90340.023 1
Sulfate 17 mg/L EPA 9056A 01/13/2016 15:05 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/28/2016 10:58 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.027 mg/L SW 6010C 01/20/2016 13:40 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/20/2016 13:40 FCJORDA0.05 1
Calcium (Ca)2.70 mg/L SW 6010C 01/20/2016 13:40 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010C 01/20/2016 13:40 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/20/2016 13:40 FCJORDA0.005 1
Iron (Fe)1.47 mg/L SW 6010C 01/20/2016 13:40 FCJORDA0.01 1
Magnesium (Mg)2.52 mg/L SW 6010C 01/20/2016 13:40 FCJORDA0.005 1
Manganese (Mn)0.083 mg/L SW 6010C 01/20/2016 13:40 FCJORDA0.005 1
Nickel (Ni)0.020 mg/L SW 6010C 01/20/2016 13:40 FCJORDA0.005 1
Potassium (K)2.20 mg/L SW 6010C 01/20/2016 13:40 FCJORDA0.1 1
Sodium (Na)3.50 mg/L SW 6010C 01/20/2016 13:40 FCJORDA0.05 1
Zinc (Zn)0.019 mg/L SW 6010C 01/20/2016 13:40 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020A 01/15/2016 12:07 SLS256011
Cadmium (Cd)< 1 ug/L SW 6020A 01/15/2016 12:07 SLS256011
Lead (Pb)< 1 ug/L SW 6020A 01/15/2016 12:07 SLS256011
Selenium (Se)< 1 ug/L SW 6020A 01/15/2016 12:07 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/15/2016 12:07 SLS256011
TOTAL DISSOLVED SOLIDS
TDS 38 mg/L SM2540C 01/16/2016 13:06 CJELLIO251
Page 8 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000010
Collection Date:12-Jan-16 9:15 AM
Site:CRW-7
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)5.2 mg/L
(CaCO3)
SM 2320B4d 01/18/2016 15:05 GHUTCHI51
INORGANIC IONS BY IC
Chloride 4.0 mg/L EPA 9056A 01/13/2016 15:22 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 01/13/2016 15:22 BGN90340.1 1
Nitrate 1.1 mg/L EPA 9056A 01/13/2016 15:22 BGN90340.1 1
Nitrate as N 0.24 mg-N/L EPA 9056A 01/13/2016 15:22 BGN90340.023 1
Sulfate 1.4 mg/L EPA 9056A 01/13/2016 15:22 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/28/2016 11:00 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.062 mg/L SW 6010C 01/20/2016 13:44 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/20/2016 13:44 FCJORDA0.05 1
Calcium (Ca)1.75 mg/L SW 6010C 01/20/2016 13:44 FCJORDA0.01 1
Chromium (Cr)0.008 mg/L SW 6010C 01/20/2016 13:44 FCJORDA0.005 1
Copper (Cu)0.006 mg/L SW 6010C 01/20/2016 13:44 FCJORDA0.005 1
Iron (Fe)6.79 mg/L SW 6010C 01/20/2016 13:44 FCJORDA0.01 1
Magnesium (Mg)2.65 mg/L SW 6010C 01/20/2016 13:44 FCJORDA0.005 1
Manganese (Mn)0.083 mg/L SW 6010C 01/20/2016 13:44 FCJORDA0.005 1
Nickel (Ni)0.009 mg/L SW 6010C 01/20/2016 13:44 FCJORDA0.005 1
Potassium (K)4.48 mg/L SW 6010C 01/20/2016 13:44 FCJORDA0.1 1
Sodium (Na)2.42 mg/L SW 6010C 01/20/2016 13:44 FCJORDA0.05 1
Zinc (Zn)0.020 mg/L SW 6010C 01/20/2016 13:44 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020A 01/15/2016 12:26 SLS256011
Cadmium (Cd)< 1 ug/L SW 6020A 01/15/2016 12:26 SLS256011
Lead (Pb)2.76 ug/L SW 6020A 01/15/2016 12:26 SLS256011
Selenium (Se)< 1 ug/L SW 6020A 01/15/2016 12:26 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/15/2016 12:26 SLS256011
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 01/16/2016 13:06 CJELLIO251
Page 9 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000011
Collection Date:12-Jan-16 10:15 AM
Site:CRW-8R
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)19 mg/L
(CaCO3)
SM 2320B4d 01/18/2016 15:05 GHUTCHI51
INORGANIC IONS BY IC
Chloride 4.9 mg/L EPA 9056A 01/13/2016 13:02 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 01/13/2016 13:02 BGN90340.1 1
Nitrate 4.2 mg/L EPA 9056A 01/13/2016 13:02 BGN90340.1 1
Nitrate as N 0.94 mg-N/L EPA 9056A 01/13/2016 13:02 BGN90340.023 1
Sulfate 1.3 mg/L EPA 9056A 01/13/2016 13:02 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/28/2016 11:03 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.048 mg/L SW 6010C 01/20/2016 13:48 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/20/2016 13:48 FCJORDA0.05 1
Calcium (Ca)5.21 mg/L SW 6010C 01/20/2016 13:48 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010C 01/20/2016 13:48 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/20/2016 13:48 FCJORDA0.005 1
Iron (Fe)0.565 mg/L SW 6010C 01/20/2016 13:48 FCJORDA0.01 1
Magnesium (Mg)2.06 mg/L SW 6010C 01/20/2016 13:48 FCJORDA0.005 1
Manganese (Mn)0.009 mg/L SW 6010C 01/20/2016 13:48 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010C 01/20/2016 13:48 FCJORDA0.005 1
Potassium (K)2.31 mg/L SW 6010C 01/20/2016 13:48 FCJORDA0.1 1
Sodium (Na)4.18 mg/L SW 6010C 01/20/2016 13:48 FCJORDA0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010C 01/20/2016 13:48 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020A 01/15/2016 12:31 SLS256011
Cadmium (Cd)< 1 ug/L SW 6020A 01/15/2016 12:31 SLS256011
Lead (Pb)< 1 ug/L SW 6020A 01/15/2016 12:31 SLS256011
Selenium (Se)< 1 ug/L SW 6020A 01/15/2016 12:31 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/15/2016 12:31 SLS256011
TOTAL DISSOLVED SOLIDS
TDS 48 mg/L SM2540C 01/16/2016 13:06 CJELLIO251
Page 10 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000012
Collection Date:12-Jan-16 11:35 AM
Site:CRW-9
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)15 mg/L
(CaCO3)
SM 2320B4d 01/18/2016 15:05 GHUTCHI51
INORGANIC IONS BY IC
Chloride 2.4 mg/L EPA 9056A 01/13/2016 13:19 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 01/13/2016 13:19 BGN90340.1 1
Nitrate 2.2 mg/L EPA 9056A 01/13/2016 13:19 BGN90340.1 1
Nitrate as N 0.50 mg-N/L EPA 9056A 01/13/2016 13:19 BGN90340.023 1
Sulfate 2.2 mg/L EPA 9056A 01/13/2016 13:19 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/28/2016 11:05 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.021 mg/L SW 6010C 01/20/2016 13:52 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/20/2016 13:52 FCJORDA0.05 1
Calcium (Ca)4.09 mg/L SW 6010C 01/20/2016 13:52 FCJORDA0.01 1
Chromium (Cr)0.007 mg/L SW 6010C 01/20/2016 13:52 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/20/2016 13:52 FCJORDA0.005 1
Iron (Fe)1.41 mg/L SW 6010C 01/20/2016 13:52 FCJORDA0.01 1
Magnesium (Mg)1.31 mg/L SW 6010C 01/20/2016 13:52 FCJORDA0.005 1
Manganese (Mn)0.021 mg/L SW 6010C 01/20/2016 13:52 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010C 01/20/2016 13:52 FCJORDA0.005 1
Potassium (K)2.35 mg/L SW 6010C 01/20/2016 13:52 FCJORDA0.1 1
Sodium (Na)3.46 mg/L SW 6010C 01/20/2016 13:52 FCJORDA0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010C 01/20/2016 13:52 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020A 01/15/2016 12:36 SLS256011
Cadmium (Cd)< 1 ug/L SW 6020A 01/15/2016 12:36 SLS256011
Lead (Pb)< 1 ug/L SW 6020A 01/15/2016 12:36 SLS256011
Selenium (Se)< 1 ug/L SW 6020A 01/15/2016 12:36 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/15/2016 12:36 SLS256011
TOTAL DISSOLVED SOLIDS
TDS 45 mg/L SM2540C 01/16/2016 13:06 CJELLIO251
Page 11 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000013
Collection Date:12-Jan-16 11:20 AM
Site:CRW-10
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)8.2 mg/L
(CaCO3)
SM 2320B4d 01/18/2016 15:05 GHUTCHI51
INORGANIC IONS BY IC
Chloride 7.5 mg/L EPA 9056A 01/13/2016 15:39 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 01/13/2016 15:39 BGN90340.1 1
Nitrate 3.2 mg/L EPA 9056A 01/13/2016 15:39 BGN90340.1 1
Nitrate as N 0.71 mg-N/L EPA 9056A 01/13/2016 15:39 BGN90340.023 1
Sulfate 43 mg/L EPA 9056A 01/13/2016 15:39 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/28/2016 11:07 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.021 mg/L SW 6010C 01/20/2016 13:56 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/20/2016 13:56 FCJORDA0.05 1
Calcium (Ca)11.5 mg/L SW 6010C 01/20/2016 13:56 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010C 01/20/2016 13:56 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/20/2016 13:56 FCJORDA0.005 1
Iron (Fe)2.01 mg/L SW 6010C 01/20/2016 13:56 FCJORDA0.01 1
Magnesium (Mg)4.51 mg/L SW 6010C 01/20/2016 13:56 FCJORDA0.005 1
Manganese (Mn)0.046 mg/L SW 6010C 01/20/2016 13:56 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010C 01/20/2016 13:56 FCJORDA0.005 1
Potassium (K)2.89 mg/L SW 6010C 01/20/2016 13:56 FCJORDA0.1 1
Sodium (Na)7.46 mg/L SW 6010C 01/20/2016 13:56 FCJORDA0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010C 01/20/2016 13:56 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020A 01/15/2016 12:41 SLS256011
Cadmium (Cd)< 1 ug/L SW 6020A 01/15/2016 12:41 SLS256011
Lead (Pb)< 1 ug/L SW 6020A 01/15/2016 12:41 SLS256011
Selenium (Se)< 1 ug/L SW 6020A 01/15/2016 12:41 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/15/2016 12:41 SLS256011
TOTAL DISSOLVED SOLIDS
TDS 86 mg/L SM2540C 01/16/2016 13:06 CJELLIO251
Page 12 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000014
Collection Date:12-Jan-16 10:25 AM
Site:CRW-11
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)45 mg/L
(CaCO3)
SM 2320B4d 01/18/2016 15:05 GHUTCHI51
INORGANIC IONS BY IC
Chloride 3.1 mg/L EPA 9056A 01/13/2016 13:52 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 01/13/2016 13:52 BGN90340.1 1
Nitrate 6.9 mg/L EPA 9056A 01/13/2016 13:52 BGN90340.1 1
Nitrate as N 1.6 mg-N/L EPA 9056A 01/13/2016 13:52 BGN90340.023 1
Sulfate 0.67 mg/L EPA 9056A 01/13/2016 13:52 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/28/2016 11:10 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.029 mg/L SW 6010C 01/20/2016 14:00 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/20/2016 14:00 FCJORDA0.05 1
Calcium (Ca)10.3 mg/L SW 6010C 01/20/2016 14:00 FCJORDA0.01 1
Chromium (Cr)0.007 mg/L SW 6010C 01/20/2016 14:00 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/20/2016 14:00 FCJORDA0.005 1
Iron (Fe)2.07 mg/L SW 6010C 01/20/2016 14:00 FCJORDA0.01 1
Magnesium (Mg)5.36 mg/L SW 6010C 01/20/2016 14:00 FCJORDA0.005 1
Manganese (Mn)0.033 mg/L SW 6010C 01/20/2016 14:00 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010C 01/20/2016 14:00 FCJORDA0.005 1
Potassium (K)1.58 mg/L SW 6010C 01/20/2016 14:00 FCJORDA0.1 1
Sodium (Na)4.78 mg/L SW 6010C 01/20/2016 14:00 FCJORDA0.05 1
Zinc (Zn)0.008 mg/L SW 6010C 01/20/2016 14:00 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020A 01/15/2016 12:46 SLS256011
Cadmium (Cd)< 1 ug/L SW 6020A 01/15/2016 12:46 SLS256011
Lead (Pb)< 1 ug/L SW 6020A 01/15/2016 12:46 SLS256011
Selenium (Se)< 1 ug/L SW 6020A 01/15/2016 12:46 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/15/2016 12:46 SLS256011
TOTAL DISSOLVED SOLIDS
TDS 110 mg/L SM2540C 01/16/2016 13:06 CJELLIO251
Page 13 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000015
Collection Date:11-Jan-16 8:25 AM
Site:CRW-12
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)28 mg/L
(CaCO3)
SM 2320B4d 01/18/2016 15:05 GHUTCHI51
INORGANIC IONS BY IC
Chloride 3.3 mg/L EPA 9056A 01/12/2016 11:15 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 01/12/2016 11:15 BGN90340.1 1
Nitrate 1.7 mg/L EPA 9056A 01/12/2016 11:15 BGN90340.1 1
Nitrate as N 0.38 mg-N/L EPA 9056A 01/12/2016 11:15 BGN90340.023 1
Sulfate 1.0 mg/L EPA 9056A 01/12/2016 11:15 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/13/2016 11:13 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.026 mg/L SW 6010C 01/20/2016 12:13 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/20/2016 12:13 FCJORDA0.05 1
Calcium (Ca)5.96 mg/L SW 6010C 01/20/2016 12:13 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010C 01/20/2016 12:13 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/20/2016 12:13 FCJORDA0.005 1
Iron (Fe)0.485 mg/L SW 6010C 01/20/2016 12:13 FCJORDA0.01 1
Magnesium (Mg)2.13 mg/L SW 6010C 01/20/2016 12:13 FCJORDA0.005 1
Manganese (Mn)0.015 mg/L SW 6010C 01/20/2016 12:13 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010C 01/20/2016 12:13 FCJORDA0.005 1
Potassium (K)2.32 mg/L SW 6010C 01/20/2016 12:13 FCJORDA0.1 1
Sodium (Na)5.68 mg/L SW 6010C 01/20/2016 12:13 FCJORDA0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010C 01/20/2016 12:13 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020A 01/13/2016 11:48 SLS256011
Cadmium (Cd)< 1 ug/L SW 6020A 01/13/2016 11:48 SLS256011
Lead (Pb)< 1 ug/L SW 6020A 01/13/2016 11:48 SLS256011
Selenium (Se)< 1 ug/L SW 6020A 01/13/2016 11:48 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/13/2016 11:48 SLS256011
TOTAL DISSOLVED SOLIDS
TDS 51 mg/L SM2540C 01/16/2016 13:06 CJELLIO251
Page 14 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000016
Collection Date:11-Jan-16 9:35 AM
Site:CRW-13
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)38 mg/L
(CaCO3)
SM 2320B4d 01/18/2016 15:05 GHUTCHI51
INORGANIC IONS BY IC
Chloride 20 mg/L EPA 9056A 01/12/2016 13:20 BGN90340.5 5
Fluoride < 0.1 mg/L EPA 9056A 01/12/2016 13:20 BGN90340.1 1
Nitrate 7.5 mg/L EPA 9056A 01/12/2016 13:20 BGN90340.1 1
Nitrate as N 1.7 mg-N/L EPA 9056A 01/12/2016 13:20 BGN90340.023 1
Sulfate 1.1 mg/L EPA 9056A 01/12/2016 13:20 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/13/2016 11:15 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.020 mg/L SW 6010C 01/20/2016 12:17 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/20/2016 12:17 FCJORDA0.05 1
Calcium (Ca)12.9 mg/L SW 6010C 01/20/2016 12:17 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010C 01/20/2016 12:17 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/20/2016 12:17 FCJORDA0.005 1
Iron (Fe)0.422 mg/L SW 6010C 01/20/2016 12:17 FCJORDA0.01 1
Magnesium (Mg)6.95 mg/L SW 6010C 01/20/2016 12:17 FCJORDA0.005 1
Manganese (Mn)0.010 mg/L SW 6010C 01/20/2016 12:17 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010C 01/20/2016 12:17 FCJORDA0.005 1
Potassium (K)1.73 mg/L SW 6010C 01/20/2016 12:17 FCJORDA0.1 1
Sodium (Na)5.31 mg/L SW 6010C 01/20/2016 12:17 FCJORDA0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010C 01/20/2016 12:17 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020A 01/13/2016 11:53 SLS256011
Cadmium (Cd)< 1 ug/L SW 6020A 01/13/2016 11:53 SLS256011
Lead (Pb)< 1 ug/L SW 6020A 01/13/2016 11:53 SLS256011
Selenium (Se)< 1 ug/L SW 6020A 01/13/2016 11:53 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/13/2016 11:53 SLS256011
TOTAL DISSOLVED SOLIDS
TDS 120 mg/L SM2540C 01/16/2016 13:06 CJELLIO251
Page 15 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000017
Collection Date:11-Jan-16 10:45 AM
Site:CRW-14
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)39 mg/L
(CaCO3)
SM 2320B4d 01/18/2016 15:05 GHUTCHI51
INORGANIC IONS BY IC
Chloride 24 mg/L EPA 9056A 01/12/2016 13:38 BGN90340.5 5
Fluoride 0.25 mg/L EPA 9056A 01/12/2016 13:38 BGN90340.1 1
Nitrate 12 mg/L EPA 9056A 01/12/2016 13:38 BGN90340.5 5
Nitrate as N 2.7 mg-N/L EPA 9056A 01/12/2016 13:38 BGN90340.023 1
Sulfate 15 mg/L EPA 9056A 01/12/2016 13:38 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/13/2016 11:17 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.027 mg/L SW 6010C 01/20/2016 12:21 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/20/2016 12:21 FCJORDA0.05 1
Calcium (Ca)13.7 mg/L SW 6010C 01/20/2016 12:21 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010C 01/20/2016 12:21 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/20/2016 12:21 FCJORDA0.005 1
Iron (Fe)0.055 mg/L SW 6010C 01/20/2016 12:21 FCJORDA0.01 1
Magnesium (Mg)4.53 mg/L SW 6010C 01/20/2016 12:21 FCJORDA0.005 1
Manganese (Mn)0.012 mg/L SW 6010C 01/20/2016 12:21 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010C 01/20/2016 12:21 FCJORDA0.005 1
Potassium (K)3.14 mg/L SW 6010C 01/20/2016 12:21 FCJORDA0.1 1
Sodium (Na)17.9 mg/L SW 6010C 01/20/2016 12:21 FCJORDA0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010C 01/20/2016 12:21 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020A 01/13/2016 12:13 SLS256011
Cadmium (Cd)< 1 ug/L SW 6020A 01/13/2016 12:13 SLS256011
Lead (Pb)< 1 ug/L SW 6020A 01/13/2016 12:13 SLS256011
Selenium (Se)< 1 ug/L SW 6020A 01/13/2016 12:13 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/13/2016 12:13 SLS256011
TOTAL DISSOLVED SOLIDS
TDS 140 mg/L SM2540C 01/16/2016 13:06 CJELLIO251
Page 16 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000018
Collection Date:11-Jan-16 11:30 AM
Site:CRW-15
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)18 mg/L
(CaCO3)
SM 2320B4d 01/18/2016 15:05 GHUTCHI51
INORGANIC IONS BY IC
Chloride 11 mg/L EPA 9056A 01/13/2016 09:02 BGN90340.2 2
Fluoride < 0.1 mg/L EPA 9056A 01/13/2016 09:02 BGN90340.1 1
Nitrate 0.42 mg/L EPA 9056A 01/13/2016 09:02 BGN90340.1 1
Nitrate as N 0.09 mg-N/L EPA 9056A 01/13/2016 09:02 BGN90340.023 1
Sulfate 3.1 mg/L EPA 9056A 01/13/2016 09:02 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/13/2016 11:20 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.008 mg/L SW 6010C 01/20/2016 12:26 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/20/2016 12:26 FCJORDA0.05 1
Calcium (Ca)5.50 mg/L SW 6010C 01/20/2016 12:26 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010C 01/20/2016 12:26 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/20/2016 12:26 FCJORDA0.005 1
Iron (Fe)0.037 mg/L SW 6010C 01/20/2016 12:26 FCJORDA0.01 1
Magnesium (Mg)2.63 mg/L SW 6010C 01/20/2016 12:26 FCJORDA0.005 1
Manganese (Mn)0.005 mg/L SW 6010C 01/20/2016 12:26 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010C 01/20/2016 12:26 FCJORDA0.005 1
Potassium (K)2.41 mg/L SW 6010C 01/20/2016 12:26 FCJORDA0.1 1
Sodium (Na)5.26 mg/L SW 6010C 01/20/2016 12:26 FCJORDA0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010C 01/20/2016 12:26 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020A 01/13/2016 12:18 SLS256011
Cadmium (Cd)< 1 ug/L SW 6020A 01/13/2016 12:18 SLS256011
Lead (Pb)< 1 ug/L SW 6020A 01/13/2016 12:18 SLS256011
Selenium (Se)< 1 ug/L SW 6020A 01/13/2016 12:18 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/13/2016 12:18 SLS256011
TOTAL DISSOLVED SOLIDS
TDS 60 mg/L SM2540C 01/16/2016 13:06 CJELLIO251
Page 17 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000019
Collection Date:11-Jan-16 8:10 AM
Site:CRW-16
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)20 mg/L
(CaCO3)
SM 2320B4d 01/18/2016 15:05 GHUTCHI51
INORGANIC IONS BY IC
Chloride 5.6 mg/L EPA 9056A 01/12/2016 11:51 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 01/12/2016 11:51 BGN90340.1 1
Nitrate 0.34 mg/L EPA 9056A 01/12/2016 11:51 BGN90340.1 1
Nitrate as N 0.08 mg-N/L EPA 9056A 01/12/2016 11:51 BGN90340.023 1
Sulfate 0.97 mg/L EPA 9056A 01/12/2016 11:51 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/13/2016 11:22 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.023 mg/L SW 6010C 01/20/2016 12:30 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/20/2016 12:30 FCJORDA0.05 1
Calcium (Ca)5.45 mg/L SW 6010C 01/20/2016 12:30 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010C 01/20/2016 12:30 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/20/2016 12:30 FCJORDA0.005 1
Iron (Fe)0.397 mg/L SW 6010C 01/20/2016 12:30 FCJORDA0.01 1
Magnesium (Mg)1.41 mg/L SW 6010C 01/20/2016 12:30 FCJORDA0.005 1
Manganese (Mn)0.015 mg/L SW 6010C 01/20/2016 12:30 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010C 01/20/2016 12:30 FCJORDA0.005 1
Potassium (K)1.81 mg/L SW 6010C 01/20/2016 12:30 FCJORDA0.1 1
Sodium (Na)5.45 mg/L SW 6010C 01/20/2016 12:30 FCJORDA0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010C 01/20/2016 12:30 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020A 01/13/2016 12:23 SLS256011
Cadmium (Cd)< 1 ug/L SW 6020A 01/13/2016 12:23 SLS256011
Lead (Pb)< 1 ug/L SW 6020A 01/13/2016 12:23 SLS256011
Selenium (Se)< 1 ug/L SW 6020A 01/13/2016 12:23 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/13/2016 12:23 SLS256011
TOTAL DISSOLVED SOLIDS
TDS 37 mg/L SM2540C 01/16/2016 13:06 CJELLIO251
Page 18 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000020
Collection Date:12-Jan-16 8:45 AM
Site:CRW-17
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)9.5 mg/L
(CaCO3)
SM 2320B4d 01/19/2016 11:28 GHUTCHI51
INORGANIC IONS BY IC
Chloride 2.2 mg/L EPA 9056A 01/13/2016 14:15 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 01/13/2016 14:15 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 01/13/2016 14:15 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 01/13/2016 14:15 BGN90340.023 1
Sulfate 0.15 mg/L EPA 9056A 01/13/2016 14:15 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/28/2016 11:12 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.071 mg/L SW 6010C 01/20/2016 14:04 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/20/2016 14:04 FCJORDA0.05 1
Calcium (Ca)1.90 mg/L SW 6010C 01/20/2016 14:04 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010C 01/20/2016 14:04 FCJORDA0.005 1
Copper (Cu)0.008 mg/L SW 6010C 01/20/2016 14:04 FCJORDA0.005 1
Iron (Fe)2.68 mg/L SW 6010C 01/20/2016 14:04 FCJORDA0.01 1
Magnesium (Mg)1.01 mg/L SW 6010C 01/20/2016 14:04 FCJORDA0.005 1
Manganese (Mn)0.032 mg/L SW 6010C 01/20/2016 14:04 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010C 01/20/2016 14:04 FCJORDA0.005 1
Potassium (K)2.46 mg/L SW 6010C 01/20/2016 14:04 FCJORDA0.1 1
Sodium (Na)3.41 mg/L SW 6010C 01/20/2016 14:04 FCJORDA0.05 1
Zinc (Zn)0.010 mg/L SW 6010C 01/20/2016 14:04 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020A 01/15/2016 12:51 SLS256011
Cadmium (Cd)< 1 ug/L SW 6020A 01/15/2016 12:51 SLS256011
Lead (Pb)< 1 ug/L SW 6020A 01/15/2016 12:51 SLS256011
Selenium (Se)< 1 ug/L SW 6020A 01/15/2016 12:51 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/15/2016 12:51 SLS256011
TOTAL DISSOLVED SOLIDS
TDS 43 mg/L SM2540C 01/16/2016 13:06 CJELLIO251
Page 19 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000021
Collection Date:11-Jan-16 12:50 PM
Site:CWB-1
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B4d 01/19/2016 11:28 GHUTCHI51
INORGANIC IONS BY IC
Chloride 420 mg/L EPA 9056A 01/12/2016 14:31 BGN9034550
Fluoride < 2.5 mg/L EPA 9056A 01/12/2016 14:31 BGN90342.5 25
Nitrate 150 mg/L EPA 9056A 01/12/2016 14:31 BGN90342.5 25
Nitrate as N 34 mg-N/L EPA 9056A 01/12/2016 14:31 BGN90340.023 1
Sulfate 2400 mg/L EPA 9056A 01/12/2016 14:31 BGN903450500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/13/2016 11:25 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.036 mg/L SW 6010C 01/20/2016 12:34 FCJORDA0.005 1
Boron (B)30.3 mg/L SW 6010C 01/20/2016 12:34 FCJORDA0.5 10
Calcium (Ca)393 mg/L SW 6010C 01/20/2016 12:34 FCJORDA0.1 10
Chromium (Cr)< 0.005 mg/L SW 6010C 01/20/2016 12:34 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/20/2016 12:34 FCJORDA0.005 1
Iron (Fe)0.354 mg/L SW 6010C 01/20/2016 12:34 FCJORDA0.01 1
Magnesium (Mg)150 mg/L SW 6010C 01/20/2016 12:34 FCJORDA0.05 10
Manganese (Mn)22.8 mg/L SW 6010C 01/20/2016 12:34 FCJORDA0.05 10
Nickel (Ni)0.156 mg/L SW 6010C 01/20/2016 12:34 FCJORDA0.005 1
Potassium (K)49.8 mg/L SW 6010C 01/20/2016 12:34 FCJORDA110
Sodium (Na)145 mg/L SW 6010C 01/20/2016 12:34 FCJORDA0.5 10
Zinc (Zn)0.426 mg/L SW 6010C 01/20/2016 12:34 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)46.3 ug/L SW 6020A 01/13/2016 12:27 SLS256011
Cadmium (Cd)5.74 ug/L SW 6020A 01/13/2016 12:27 SLS256011
Lead (Pb)5.68 ug/L SW 6020A 01/13/2016 12:27 SLS256011
Selenium (Se)94.7 ug/L SW 6020A 01/13/2016 12:27 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/13/2016 12:27 SLS256011
TOTAL DISSOLVED SOLIDS
TDS 3600 mg/L SM2540C 01/16/2016 13:06 CJELLIO1001
Page 20 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000022
Collection Date:11-Jan-16 12:30 PM
Site:CWB-2
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B4d 01/19/2016 11:28 GHUTCHI51
INORGANIC IONS BY IC
Chloride 360 mg/L EPA 9056A 01/12/2016 14:14 BGN9034550
Fluoride < 5 mg/L EPA 9056A 01/12/2016 14:14 BGN9034550
Nitrate 180 mg/L EPA 9056A 01/12/2016 14:14 BGN9034550
Nitrate as N 41 mg-N/L EPA 9056A 01/12/2016 14:14 BGN90340.023 1
Sulfate 3800 mg/L EPA 9056A 01/12/2016 14:14 BGN90341001000
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/13/2016 11:27 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.027 mg/L SW 6010C 01/20/2016 12:38 FCJORDA0.005 1
Boron (B)73.9 mg/L SW 6010C 01/20/2016 12:38 FCJORDA0.5 10
Calcium (Ca)451 mg/L SW 6010C 01/20/2016 12:38 FCJORDA0.1 10
Chromium (Cr)< 0.005 mg/L SW 6010C 01/20/2016 12:38 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/20/2016 12:38 FCJORDA0.005 1
Iron (Fe)0.044 mg/L SW 6010C 01/20/2016 12:38 FCJORDA0.01 1
Magnesium (Mg)29.5 mg/L SW 6010C 01/20/2016 12:38 FCJORDA0.05 10
Manganese (Mn)29.5 mg/L SW 6010C 01/20/2016 12:38 FCJORDA0.05 10
Nickel (Ni)0.325 mg/L SW 6010C 01/20/2016 12:38 FCJORDA0.005 1
Potassium (K)183 mg/L SW 6010C 01/20/2016 12:38 FCJORDA110
Sodium (Na)274 mg/L SW 6010C 01/20/2016 12:38 FCJORDA0.5 10
Zinc (Zn)0.848 mg/L SW 6010C 01/20/2016 12:38 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)70.8 ug/L SW 6020A 01/13/2016 12:32 SLS256011
Cadmium (Cd)9.80 ug/L SW 6020A 01/13/2016 12:32 SLS256011
Lead (Pb)13.0 ug/L SW 6020A 01/13/2016 12:32 SLS256011
Selenium (Se)170 ug/L SW 6020A 01/13/2016 12:32 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/13/2016 12:32 SLS256011
TOTAL DISSOLVED SOLIDS
TDS 5100 mg/L SM2540C 01/16/2016 13:06 CJELLIO1251
Page 21 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000024
Collection Date:12-Jan-16 11:40 AM
Site:CRS-1
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)26 mg/L
(CaCO3)
SM 2320B4d 01/19/2016 11:28 GHUTCHI51
INORGANIC IONS BY IC
Chloride 6.6 mg/L EPA 9056A 01/13/2016 15:56 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 01/13/2016 15:56 BGN90340.1 1
Nitrate 1.2 mg/L EPA 9056A 01/13/2016 15:56 BGN90340.1 1
Nitrate as N 0.27 mg-N/L EPA 9056A 01/13/2016 15:56 BGN90340.023 1
Sulfate 13 mg/L EPA 9056A 01/13/2016 15:56 BGN90340.2 2
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/29/2016 13:13 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.027 mg/L SW 6010C 01/20/2016 14:08 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/20/2016 14:08 FCJORDA0.05 1
Calcium (Ca)8.96 mg/L SW 6010C 01/20/2016 14:08 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010C 01/20/2016 14:08 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/20/2016 14:08 FCJORDA0.005 1
Iron (Fe)0.349 mg/L SW 6010C 01/20/2016 14:08 FCJORDA0.01 1
Magnesium (Mg)3.78 mg/L SW 6010C 01/20/2016 14:08 FCJORDA0.005 1
Manganese (Mn)0.023 mg/L SW 6010C 01/20/2016 14:08 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010C 01/20/2016 14:08 FCJORDA0.005 1
Potassium (K)1.83 mg/L SW 6010C 01/20/2016 14:08 FCJORDA0.1 1
Sodium (Na)4.63 mg/L SW 6010C 01/20/2016 14:08 FCJORDA0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010C 01/20/2016 14:08 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020A 01/15/2016 12:56 SLS256011
Cadmium (Cd)< 1 ug/L SW 6020A 01/15/2016 12:56 SLS256011
Lead (Pb)< 1 ug/L SW 6020A 01/15/2016 12:56 SLS256011
Selenium (Se)< 1 ug/L SW 6020A 01/15/2016 12:56 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/15/2016 12:56 SLS256011
TOTAL DISSOLVED SOLIDS
TDS 55 mg/L SM2540C 01/16/2016 13:06 CJELLIO251
Page 22 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000025
Collection Date:12-Jan-16 12:05 PM
Site:CRS-2
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)21 mg/L
(CaCO3)
SM 2320B4d 01/19/2016 11:28 GHUTCHI51
INORGANIC IONS BY IC
Chloride 7.1 mg/L EPA 9056A 01/13/2016 21:17 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 01/13/2016 21:17 BGN90340.1 1
Nitrate 0.79 mg/L EPA 9056A 01/13/2016 21:17 BGN90340.1 1
Nitrate as N 0.18 mg-N/L EPA 9056A 01/13/2016 21:17 BGN90340.023 1
Sulfate 23 mg/L EPA 9056A 01/13/2016 21:17 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/28/2016 11:15 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.027 mg/L SW 6010C 01/20/2016 14:12 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/20/2016 14:12 FCJORDA0.05 1
Calcium (Ca)10.2 mg/L SW 6010C 01/20/2016 14:12 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010C 01/20/2016 14:12 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/20/2016 14:12 FCJORDA0.005 1
Iron (Fe)1.05 mg/L SW 6010C 01/20/2016 14:12 FCJORDA0.01 1
Magnesium (Mg)3.94 mg/L SW 6010C 01/20/2016 14:12 FCJORDA0.005 1
Manganese (Mn)0.105 mg/L SW 6010C 01/20/2016 14:12 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010C 01/20/2016 14:12 FCJORDA0.005 1
Potassium (K)2.08 mg/L SW 6010C 01/20/2016 14:12 FCJORDA0.1 1
Sodium (Na)4.87 mg/L SW 6010C 01/20/2016 14:12 FCJORDA0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010C 01/20/2016 14:12 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020A 01/15/2016 13:01 SLS256011
Cadmium (Cd)< 1 ug/L SW 6020A 01/15/2016 13:01 SLS256011
Lead (Pb)< 1 ug/L SW 6020A 01/15/2016 13:01 SLS256011
Selenium (Se)< 1 ug/L SW 6020A 01/15/2016 13:01 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/15/2016 13:01 SLS256011
TOTAL DISSOLVED SOLIDS
TDS 76 mg/L SM2540C 01/16/2016 13:06 CJELLIO251
Page 23 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000026
Collection Date:11-Jan-16 10:20 AM
Site:CRS-3
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)37 mg/L
(CaCO3)
SM 2320B4d 01/19/2016 11:28 GHUTCHI51
INORGANIC IONS BY IC
Chloride 9.2 mg/L EPA 9056A 01/12/2016 17:30 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 01/12/2016 17:30 BGN90340.1 1
Nitrate 0.36 mg/L EPA 9056A 01/12/2016 17:30 BGN90340.1 1
Nitrate as N 0.08 mg-N/L EPA 9056A 01/12/2016 17:30 BGN90340.023 1
Sulfate 41 mg/L EPA 9056A 01/12/2016 17:30 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/13/2016 11:34M2 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.036 mg/L SW 6010C 01/20/2016 12:50 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/20/2016 12:50 FCJORDA0.05 1
Calcium (Ca)31.2 mg/L SW 6010C 01/20/2016 12:50 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010C 01/20/2016 12:50 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/20/2016 12:50 FCJORDA0.005 1
Iron (Fe)0.539 mg/L SW 6010C 01/20/2016 12:50 FCJORDA0.01 1
Magnesium (Mg)8.46 mg/L SW 6010C 01/20/2016 12:50 FCJORDA0.005 1
Manganese (Mn)1.45 mg/L SW 6010C 01/20/2016 12:50 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010C 01/20/2016 12:50 FCJORDA0.005 1
Potassium (K)5.26 mg/L SW 6010C 01/20/2016 12:50 FCJORDA0.1 1
Sodium (Na)7.44 mg/L SW 6010C 01/20/2016 12:50 FCJORDA0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010C 01/20/2016 12:50 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020A 01/13/2016 12:37 SLS256011
Cadmium (Cd)< 1 ug/L SW 6020A 01/13/2016 12:37 SLS256011
Lead (Pb)< 1 ug/L SW 6020A 01/13/2016 12:37 SLS256011
Selenium (Se)< 1 ug/L SW 6020A 01/13/2016 12:37 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/13/2016 12:37 SLS256011
TOTAL DISSOLVED SOLIDS
TDS 150 mg/L SM2540C 01/16/2016 13:06 CJELLIO251
Page 24 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000027
Collection Date:11-Jan-16 10:55 AM
Site:CRS-4
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)19 mg/L
(CaCO3)
SM 2320B4d 01/19/2016 11:28 GHUTCHI51
INORGANIC IONS BY IC
Chloride 5.6 mg/L EPA 9056A 01/12/2016 17:13 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 01/12/2016 17:13 BGN90340.1 1
Nitrate 1.7 mg/L EPA 9056A 01/12/2016 17:13 BGN90340.1 1
Nitrate as N 0.39 mg-N/L EPA 9056A 01/12/2016 17:13 BGN90340.023 1
Sulfate 19 mg/L EPA 9056A 01/12/2016 17:13 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/13/2016 11:41 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.016 mg/L SW 6010C 01/20/2016 12:54 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/20/2016 12:54 FCJORDA0.05 1
Calcium (Ca)8.21 mg/L SW 6010C 01/20/2016 12:54 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010C 01/20/2016 12:54 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/20/2016 12:54 FCJORDA0.005 1
Iron (Fe)0.284 mg/L SW 6010C 01/20/2016 12:54 FCJORDA0.01 1
Magnesium (Mg)3.09 mg/L SW 6010C 01/20/2016 12:54 FCJORDA0.005 1
Manganese (Mn)0.074 mg/L SW 6010C 01/20/2016 12:54 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010C 01/20/2016 12:54 FCJORDA0.005 1
Potassium (K)2.31 mg/L SW 6010C 01/20/2016 12:54 FCJORDA0.1 1
Sodium (Na)5.30 mg/L SW 6010C 01/20/2016 12:54 FCJORDA0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010C 01/20/2016 12:54 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020A 01/13/2016 12:42 SLS256011
Cadmium (Cd)< 1 ug/L SW 6020A 01/13/2016 12:42 SLS256011
Lead (Pb)< 1 ug/L SW 6020A 01/13/2016 12:42 SLS256011
Selenium (Se)< 1 ug/L SW 6020A 01/13/2016 12:42 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/13/2016 12:42 SLS256011
TOTAL DISSOLVED SOLIDS
TDS 52 mg/L SM2540C 01/16/2016 13:06 CJELLIO251
Page 25 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000028
Collection Date:12-Jan-16 7:40 AM
Site:CRS-5
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)14 mg/L
(CaCO3)
SM 2320B4d 01/19/2016 11:28 GHUTCHI51
INORGANIC IONS BY IC
Chloride 4.3 mg/L EPA 9056A 01/13/2016 21:34 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 01/13/2016 21:34 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 01/13/2016 21:34 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 01/13/2016 21:34 BGN90340.023 1
Sulfate 13 mg/L EPA 9056A 01/13/2016 21:34 BGN90340.2 2
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/28/2016 11:17 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.032 mg/L SW 6010C 01/20/2016 14:25 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/20/2016 14:25 FCJORDA0.05 1
Calcium (Ca)4.23 mg/L SW 6010C 01/20/2016 14:25 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010C 01/20/2016 14:25 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/20/2016 14:25 FCJORDA0.005 1
Iron (Fe)2.95 mg/L SW 6010C 01/20/2016 14:25 FCJORDA0.01 1
Magnesium (Mg)2.55 mg/L SW 6010C 01/20/2016 14:25 FCJORDA0.005 1
Manganese (Mn)0.272 mg/L SW 6010C 01/20/2016 14:25 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010C 01/20/2016 14:25 FCJORDA0.005 1
Potassium (K)1.75 mg/L SW 6010C 01/20/2016 14:25 FCJORDA0.1 1
Sodium (Na)3.28 mg/L SW 6010C 01/20/2016 14:25 FCJORDA0.05 1
Zinc (Zn)0.007 mg/L SW 6010C 01/20/2016 14:25 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020A 01/15/2016 13:20 SLS256011
Cadmium (Cd)< 1 ug/L SW 6020A 01/15/2016 13:20 SLS256011
Lead (Pb)< 1 ug/L SW 6020A 01/15/2016 13:20 SLS256011
Selenium (Se)< 1 ug/L SW 6020A 01/15/2016 13:20 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/15/2016 13:20 SLS256011
TOTAL DISSOLVED SOLIDS
TDS 47 mg/L SM2540C 01/16/2016 13:06 CJELLIO251
Page 26 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000029
Collection Date:11-Jan-16 12:00 PM
Site:CRS-6
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)31 mg/L
(CaCO3)
SM 2320B4d 01/19/2016 11:28 GHUTCHI51
INORGANIC IONS BY IC
Chloride 7.7 mg/L EPA 9056A 01/12/2016 16:55 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 01/12/2016 16:55 BGN90340.1 1
Nitrate 1.4 mg/L EPA 9056A 01/12/2016 16:55 BGN90340.1 1
Nitrate as N 0.32 mg-N/L EPA 9056A 01/12/2016 16:55 BGN90340.023 1
Sulfate 6.7 mg/L EPA 9056A 01/12/2016 16:55 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/13/2016 11:43 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.034 mg/L SW 6010C 01/20/2016 12:58 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/20/2016 12:58 FCJORDA0.05 1
Calcium (Ca)8.00 mg/L SW 6010C 01/20/2016 12:58 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010C 01/20/2016 12:58 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/20/2016 12:58 FCJORDA0.005 1
Iron (Fe)0.282 mg/L SW 6010C 01/20/2016 12:58 FCJORDA0.01 1
Magnesium (Mg)4.02 mg/L SW 6010C 01/20/2016 12:58 FCJORDA0.005 1
Manganese (Mn)0.421 mg/L SW 6010C 01/20/2016 12:58 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010C 01/20/2016 12:58 FCJORDA0.005 1
Potassium (K)1.91 mg/L SW 6010C 01/20/2016 12:58 FCJORDA0.1 1
Sodium (Na)4.97 mg/L SW 6010C 01/20/2016 12:58 FCJORDA0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010C 01/20/2016 12:58 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020A 01/13/2016 12:47 SLS256011
Cadmium (Cd)< 1 ug/L SW 6020A 01/13/2016 12:47 SLS256011
Lead (Pb)< 1 ug/L SW 6020A 01/13/2016 12:47 SLS256011
Selenium (Se)< 1 ug/L SW 6020A 01/13/2016 12:47 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/13/2016 12:47 SLS256011
TOTAL DISSOLVED SOLIDS
TDS 47 mg/L SM2540C 01/16/2016 13:06 CJELLIO251
Page 27 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
2016000030
Collection Date:12-Jan-16 12:15 PM
Site:FIELD BLANK
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B4d 01/19/2016 11:28 GHUTCHI51
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 9056A 01/13/2016 17:54 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 01/13/2016 17:54 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 01/13/2016 17:54 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 01/13/2016 17:54 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 01/13/2016 17:54 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470 01/28/2016 11:32 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L SW 6010C 01/20/2016 14:29 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/20/2016 14:29 FCJORDA0.05 1
Calcium (Ca)0.010 mg/L SW 6010C 01/20/2016 14:29 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010C 01/20/2016 14:29 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/20/2016 14:29 FCJORDA0.005 1
Iron (Fe)< 0.01 mg/L SW 6010C 01/20/2016 14:29 FCJORDA0.01 1
Magnesium (Mg)< 0.005 mg/L SW 6010C 01/20/2016 14:29 FCJORDA0.005 1
Manganese (Mn)< 0.005 mg/L SW 6010C 01/20/2016 14:29 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010C 01/20/2016 14:29 FCJORDA0.005 1
Potassium (K)< 0.1 mg/L SW 6010C 01/20/2016 14:29 FCJORDA0.1 1
Sodium (Na)< 0.05 mg/L SW 6010C 01/20/2016 14:29 FCJORDA0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010C 01/20/2016 14:29 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020A 01/15/2016 13:25 SLS256011
Cadmium (Cd)< 1 ug/L SW 6020A 01/15/2016 13:25 SLS256011
Lead (Pb)< 1 ug/L SW 6020A 01/15/2016 13:25 SLS256011
Selenium (Se)< 1 ug/L SW 6020A 01/15/2016 13:25 SLS256011
Silver (Ag)< 1 ug/L SW 6020A 01/15/2016 13:25 SLS256011
Qualifiers:
M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable.
Page 28 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
Q16010399 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16010004 -- 2016000005
Alkalinity (mg/L CaCO3)7.29mg/L
(CaCO3)
-112.8
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16010004 -- 2016000020
Alkalinity (mg/L CaCO3)4mg/L
(CaCO3)
-19.09
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3)8.16 94.6mg/L
(CaCO3)
-1208017.72
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3)8.16 85mg/L
(CaCO3)
-1208016.94
Page 29 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
Q16010227 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0044 mg/L -10.0044 0.1 < 1/2 RDL
Fluoride 0.025 mg/L -10.025 0.1 < 1/2 RDL
Nitrate -0.0051 mg/L -1-0.0051 0.1 < 1/2 RDL
Sulfate -0.0454 mg/L -1-0.0454 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 6.85 5 99.9mg/L -1208016.85
Fluoride 5.18 5 102mg/L -1208015.18
Nitrate 5.27 5 101mg/L -1208015.27
Sulfate 5.4 5 102mg/L -1208015.4
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 6.87 5 100 0.416mg/L -1208016.87
Fluoride 5.17 5 102 0.0313mg/L -1208015.17
Nitrate 5.28 5 101 0.0794mg/L -1208015.28
Sulfate 5.41 5 102 0.214mg/L -1208015.41
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 6.39 5 106mg/L -1208016.39
Fluoride 5.24 5 104mg/L -1208015.24
Nitrate 5.54 5 105mg/L -1208015.54
Sulfate 8.87 5 103mg/L -1208018.87
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 6.4 5 106 0.0924mg/L -1208016.4
Fluoride 5.23 5 104 0.214mg/L -1208015.23
Nitrate 5.56 5 105 0.23mg/L -1208015.56
Sulfate 8.87 5 103 0.0736mg/L -1208018.87
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.3 5 106mg/L -1208015.3
Fluoride 5.14 5 103mg/L -1208015.14
Nitrate 5.37 5 107mg/L -1208015.37
Sulfate 5.41 5 108mg/L -1208015.41
Page 30 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
Q16010259 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0016 mg/L -10.0016 0.1 < 1/2 RDL
Fluoride 0.0244 mg/L -10.0244 0.1 < 1/2 RDL
Nitrate -0.0057 mg/L -1-0.0057 0.1 < 1/2 RDL
Sulfate -0.0405 mg/L -1-0.0405 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 5.71 5 103mg/L -1208015.71
Fluoride 5.2 5 103mg/L -1208015.2
Nitrate 5.12 5 102mg/L -1208015.12
Sulfate 7.69 5 101mg/L -1208017.69
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 5.71 5 103 0.143mg/L -1208015.71
Fluoride 5.23 5 104 0.593mg/L -1208015.23
Nitrate 5.11 5 102 0.174mg/L -1208015.11
Sulfate 7.68 5 101 0.0574mg/L -1208017.68
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 8.76 5 105mg/L -1208018.76
Fluoride 5.36 5 105mg/L -1208015.36
Nitrate 5.26 5 105mg/L -1208015.26
Sulfate 5.49 5 108mg/L -1208015.49
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 8.72 5 104 0.683mg/L -1208018.72
Fluoride 5.37 5 105 0.254mg/L -1208015.37
Nitrate 5.23 5 105 0.468mg/L -1208015.23
Sulfate 5.5 5 108 0.0426mg/L -1208015.5
Final QualifierDilMeasuredUnits:Parameter
IS # 3
% Recovery LCL UCLSpike
Chloride 7.12 5 106mg/L -1208017.12
Fluoride 5mg/L -120801Not Tested
Nitrate 5mg/L -120801Not Tested
Sulfate 10.5 5 103mg/L -12080110.5
Page 31 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
Q16010259 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
ISD # 3
RPD% Recovery LCL UCLSpike
Chloride 7.15 5 107 0.432mg/L -1208017.15
Fluoride 5mg/L -120801Not Tested
Nitrate 5mg/L -120801Not Tested
Sulfate 10.5 5 103 0.107mg/L -12080110.5
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.37 5 107mg/L -1208015.37
Fluoride 5.25 5 105mg/L -1208015.25
Nitrate 5.46 5 109mg/L -1208015.46
Sulfate 5.49 5 110mg/L -1208015.49
Page 32 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
Q16010249 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) -0.014 ug/L -1-0.014 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.09 2 104ug/L -1158512.09
Mercury (Hg) 2.09 2 104ug/L -1208012.09
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16010004 -- 2016000005
Mercury (Hg) 0.783 1 81.1ug/L -1257510.783
Mercury (Hg) 0.783 1 81.1ug/L -1307010.783
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16010004 -- 2016000005
Mercury (Hg) 0.855 1 88.3 8.5ug/L -1257510.855
Mercury (Hg) 0.855 1 88.3 8.5ug/L -1307010.855
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16010004 -- 2016000026
Mercury (Hg) 0.515 1 55.3ug/L -1257510.515
Mercury (Hg) 0.515 1 55.3ug/L -1307010.515
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16010004 -- 2016000026
Mercury (Hg) 0.465 1 50.3 9.47ug/L -1257510.465
Mercury (Hg) 0.465 1 50.3 9.47ug/L -1307010.465
Page 33 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
Q16010557 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.016 ug/L -10.016 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.03 2 102ug/L -1158512.03
Mercury (Hg) 2.03 2 102ug/L -1208012.03
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16010004 -- 2016000008
Mercury (Hg) 1.03 1 100ug/L -1307011.03
Mercury (Hg) 1.03 1 100ug/L -1257511.03
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16010004 -- 2016000008
Mercury (Hg) 1.03 1 101 0.797ug/L -1307011.03
Mercury (Hg) 1.03 1 101 0.797ug/L -1257511.03
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16010006 -- 2016000038
Mercury (Hg) 0.993 1 97.9ug/L -1307010.993
Mercury (Hg) 0.993 1 97.9ug/L -1257510.993
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16010006 -- 2016000038
Mercury (Hg) 0.999 1 98.5 0.611ug/L -1307010.999
Mercury (Hg) 0.999 1 98.5 0.611ug/L -1257510.999
Page 34 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
Q16010608 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg)ug/L -10.002 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg)2 92.2ug/L -1208011.84
Mercury (Hg)2 92.2ug/L -1158511.84
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16010004 -- 2016000024
Mercury (Hg)1 91.3ug/L -1257510.93
Mercury (Hg)1 91.3ug/L -1307010.93
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16010004 -- 2016000024
Mercury (Hg)1 95.3 4.29ug/L -1257510.97
Mercury (Hg)1 95.3 4.29ug/L -1307010.97
Page 35 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
Q16010229 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) -0.000178 mg/L -1-0.000178 0.005 < 1/2 RDL
Boron (B) 0.00103 mg/L -10.00103 0.05 < 1/2 RDL
Calcium (Ca) 0.00242 mg/L -10.00242 0.01 < 1/2 RDL
Chromium (Cr) -0.000009 mg/L -1-0.000009 0.005 < 1/2 RDL
Copper (Cu) -0.000331 mg/L -1-0.000331 0.005 < 1/2 RDL
Iron (Fe) -0.00085 mg/L -1-0.00085 0.01 < 1/2 RDL
Magnesium (Mg) -0.000858 mg/L -1-0.000858 0.005 < 1/2 RDL
Manganese (Mn) -0.000177 mg/L -1-0.000177 0.005 < 1/2 RDL
Nickel (Ni) -0.000082 mg/L -1-0.000082 0.005 < 1/2 RDL
Potassium (K) 0.0205 mg/L -10.0205 0.1 < 1/2 RDL
Sodium (Na) 0.000321 mg/L -10.000321 0.05 < 1/2 RDL
Zinc (Zn) -0.000267 mg/L -1-0.000267 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 5.05 5 101mg/L -1208015.05
Boron (B) 5 5 100mg/L -1208015
Calcium (Ca) 5.06 5 101mg/L -1208015.06
Chromium (Cr) 5.1 5 102mg/L -1208015.1
Copper (Cu) 5.02 5 100mg/L -1208015.02
Iron (Fe) 5.02 5 100mg/L -1208015.02
Magnesium (Mg) 5.12 5 102mg/L -1208015.12
Manganese (Mn) 5.03 5 101mg/L -1208015.03
Nickel (Ni) 5.1 5 102mg/L -1208015.1
Potassium (K) 4.99 5 99.7mg/L -1208014.99
Sodium (Na) 4.94 5 98.8mg/L -1208014.94
Zinc (Zn) 5.16 5 103mg/L -1208015.16
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16010004 -- 2016000005
Barium (Ba) 5.01 5 99.3mg/L -1257515.01
Boron (B) 4.91 5 98.1mg/L -1257514.91
Calcium (Ca) 7.33 5 100mg/L -1257517.33
Chromium (Cr) 5.03 5 100mg/L -1257515.03
Copper (Cu) 4.91 5 98.1mg/L -1257514.91
Iron (Fe) 6.55 5 99.3mg/L -1257516.55
Magnesium (Mg) 6.37 5 99.9mg/L -1257516.37
Manganese (Mn) 5.01 5 99.7mg/L -1257515.01
Nickel (Ni) 5.06 5 101mg/L -1257515.06
Potassium (K) 7.43 5 98mg/L -1257517.43
Page 36 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
Q16010229 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16010004 -- 2016000005
Sodium (Na) 7.81 5 96.3mg/L -1257517.81
Zinc (Zn) 5.12 5 102mg/L -1257515.12
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16010004 -- 2016000005
Barium (Ba) 5 5 99.2 0.161mg/L -1257515
Boron (B) 4.9 5 97.8 0.286mg/L -1257514.9
Calcium (Ca) 7.28 5 99 1.1mg/L -1257517.28
Chromium (Cr) 5.02 5 100 0.279mg/L -1257515.02
Copper (Cu) 4.9 5 97.9 0.184mg/L -1257514.9
Iron (Fe) 6.52 5 98.7 0.606mg/L -1257516.52
Magnesium (Mg) 6.4 5 100 0.599mg/L -1257516.4
Manganese (Mn) 4.99 5 99.3 0.362mg/L -1257514.99
Nickel (Ni) 5.02 5 100 0.755mg/L -1257515.02
Potassium (K) 7.44 5 98 0.0408mg/L -1257517.44
Sodium (Na) 7.81 5 96.4 0.0415mg/L -1257517.81
Zinc (Zn) 5.08 5 102 0.726mg/L -1257515.08
Page 37 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
Q16010295 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) -0.000004 mg/L -1-0.000004 0.005 < 1/2 RDL
Boron (B) 0.00399 mg/L -10.00399 0.05 < 1/2 RDL
Calcium (Ca) 0.00185 mg/L -10.00185 0.01 < 1/2 RDL
Chromium (Cr) -0.000067 mg/L -1-0.000067 0.005 < 1/2 RDL
Copper (Cu) 0.000012 mg/L -10.000012 0.005 < 1/2 RDL
Iron (Fe) -0.000543 mg/L -1-0.000543 0.01 < 1/2 RDL
Magnesium (Mg) -0.000742 mg/L -1-0.000742 0.005 < 1/2 RDL
Manganese (Mn) -0.000165 mg/L -1-0.000165 0.005 < 1/2 RDL
Nickel (Ni) 0.000088 mg/L -10.000088 0.005 < 1/2 RDL
Potassium (K) 0.0379 mg/L -10.0379 0.1 < 1/2 RDL
Sodium (Na) 0.0103 mg/L -10.0103 0.05 < 1/2 RDL
Zinc (Zn) -0.000206 mg/L -1-0.000206 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 4.81 5 96.1mg/L -1208014.81
Boron (B) 4.83 5 96.6mg/L -1208014.83
Calcium (Ca) 4.95 5 99mg/L -1208014.95
Chromium (Cr) 4.93 5 98.7mg/L -1208014.93
Copper (Cu) 4.76 5 95.3mg/L -1208014.76
Iron (Fe) 4.92 5 98.4mg/L -1208014.92
Magnesium (Mg) 4.99 5 99.8mg/L -1208014.99
Manganese (Mn) 4.91 5 98.1mg/L -1208014.91
Nickel (Ni) 5 5 100mg/L -1208015
Potassium (K) 4.8 5 96.1mg/L -1208014.8
Sodium (Na) 4.74 5 94.7mg/L -1208014.74
Zinc (Zn) 5.1 5 102mg/L -1208015.1
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16010004 -- 2016000008
Barium (Ba) 4.95 5 98.6mg/L -1257514.95
Boron (B) 4.93 5 98.5mg/L -1257514.93
Calcium (Ca) 8.29 5 101mg/L -1257518.29
Chromium (Cr) 5.05 5 101mg/L -1257515.05
Copper (Cu) 4.87 5 97.4mg/L -1257514.87
Iron (Fe) 11.7 5 99.3mg/L -12575111.7
Magnesium (Mg) 7.81 5 100mg/L -1257517.81
Manganese (Mn) 5.14 5 101mg/L -1257515.14
Nickel (Ni) 5.12 5 102mg/L -1257515.12
Potassium (K) 6.34 5 97.3mg/L -1257516.34
Page 38 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
Q16010295 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16010004 -- 2016000008
Sodium (Na) 9.06 5 97.2mg/L -1257519.06
Zinc (Zn) 5.2 5 104mg/L -1257515.2
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16010004 -- 2016000008
Barium (Ba) 4.9 5 97.8 0.855mg/L -1257514.9
Boron (B) 4.94 5 98.7 0.142mg/L -1257514.94
Calcium (Ca) 8.29 5 101 0.119mg/L -1257518.29
Chromium (Cr) 5.06 5 101 0.297mg/L -1257515.06
Copper (Cu) 4.86 5 97.2 0.123mg/L -1257514.86
Iron (Fe) 11.7 5 98.1 1.2mg/L -12575111.7
Magnesium (Mg) 7.82 5 101 0.338mg/L -1257517.82
Manganese (Mn) 5.12 5 100 0.358mg/L -1257515.12
Nickel (Ni) 5.14 5 102 0.332mg/L -1257515.14
Potassium (K) 6.34 5 97.4 0.0616mg/L -1257516.34
Sodium (Na) 9.07 5 97.5 0.247mg/L -1257519.07
Zinc (Zn) 5.24 5 104 0.788mg/L -1257515.24
Page 39 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
Q16010230 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As) -0.0004 ug/L -1-0.0004 1 < 1/2 RDL
Cadmium (Cd) 0.0007 ug/L -10.0007 1 < 1/2 RDL
Lead (Pb) -0.0083 ug/L -1-0.0083 1 < 1/2 RDL
Selenium (Se) 0.12 ug/L -10.12 1 < 1/2 RDL
Silver (Ag) -0.0001 ug/L -1-0.0001 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As) 51.3 50 103ug/L -12080151.3
Cadmium (Cd) 51.4 50 103ug/L -12080151.4
Lead (Pb) 50.5 50 101ug/L -12080150.5
Selenium (Se) 49.4 50 98.8ug/L -12080149.4
Silver (Ag) 51.9 50 104ug/L -12080151.9
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16010004 -- 2016000007
Arsenic (As) 51.8 50 103ug/L -12080151.8
Cadmium (Cd) 52.6 50 105ug/L -12080152.6
Lead (Pb) 51.9 50 104ug/L -12080151.9
Selenium (Se) 50.5 50 101ug/L -12080150.5
Silver (Ag) 52.3 50 105ug/L -12080152.3
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16010004 -- 2016000007
Arsenic (As) 50.2 50 100 3.14ug/L -12080150.2
Cadmium (Cd) 50.7 50 101 3.59ug/L -12080150.7
Lead (Pb) 50.7 50 101 2.49ug/L -12080150.7
Selenium (Se) 49 50 97.7 3.08ug/L -12080149
Silver (Ag) 51 50 102 2.68ug/L -12080151
Page 40 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
Q16010279 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As) 0.0052 ug/L -10.0052 1 < 1/2 RDL
Cadmium (Cd) 0.0011 ug/L -10.0011 1 < 1/2 RDL
Lead (Pb) -0.0065 ug/L -1-0.0065 1 < 1/2 RDL
Selenium (Se) -0.263 ug/L -1-0.263 1 < 1/2 RDL
Silver (Ag) -0.0771 ug/L -1-0.0771 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As) 48.9 50 97.7ug/L -12080148.9
Cadmium (Cd) 49.3 50 98.6ug/L -12080149.3
Lead (Pb) 49.4 50 98.8ug/L -12080149.4
Selenium (Se) 50.4 50 101ug/L -12080150.4
Silver (Ag) 50.2 50 100ug/L -12080150.2
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16010004 -- 2016000009
Arsenic (As) 48.1 50 95.9ug/L -12080148.1
Cadmium (Cd) 49 50 97.9ug/L -12080149
Lead (Pb) 49.7 50 97.8ug/L -12080149.7
Selenium (Se) 48.3 50 96.8ug/L -12080148.3
Silver (Ag) 49.4 50 98.8ug/L -12080149.4
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16010004 -- 2016000009
Arsenic (As) 48 50 95.7 0.139ug/L -12080148
Cadmium (Cd) 50.1 50 100 2.11ug/L -12080150.1
Lead (Pb) 49.6 50 97.5 0.226ug/L -12080149.6
Selenium (Se) 47.5 50 95.3 1.61ug/L -12080147.5
Silver (Ag) 49.8 50 99.6 0.842ug/L -12080149.8
Page 41 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010004
Q16010351 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16010004 -- 2016000005
TDS 4.55mg/L -143
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16010004 -- 2016000006
TDS 6.45mg/L -160
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J16010004 -- 2016000007
TDS 0mg/L -156
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 102mg/L -110901102
Page 42 of 44
Page 43 of 44
Page 44 of 44
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16010005
Project Name:BELEWS -
Lab Contact:Peggy Kendall
Date:2/2/2016
Customer Address:3195 Pine Hall Rd
Customer Name(s):Chuck Campbell, T. Hunsucker, Ed Sullivan
Mailcode: Belews Steam Station
Belews Creek, NC 28012
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Peggy Kendall
Page 1 of 10
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016000033 BELEWS 12-Jan-16 11:50 AM LDC CRS-1
2016000034 BELEWS 12-Jan-16 12:05 PM PSP CRS-2
2016000035 BELEWS 11-Jan-16 10:20 AM PSP CRS-3
2016000036 BELEWS 11-Jan-16 12:10 PM LDC CRS-6
4 Total Samples
Page 2 of 10
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:2/2/2016
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 10
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010005
2016000033
Collection Date:12-Jan-16 11:50 AM
Site:CRS-1
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
DISSOLVED METALS BY ICP
Barium (Ba)0.025 mg/L SW 6010C 01/21/2016 14:16 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/21/2016 14:16 FCJORDA0.05 1
Chromium (Cr)< 0.005 mg/L SW 6010C 01/21/2016 14:16 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/21/2016 14:16 FCJORDA0.005 1
Iron (Fe)0.050 mg/L SW 6010C 01/21/2016 14:16 FCJORDA0.01 1
Manganese (Mn)0.020 mg/L SW 6010C 01/21/2016 14:16 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010C 01/21/2016 14:16 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L SW 6010C 01/21/2016 14:16 FCJORDA0.005 1
DISSOLVED METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 01/29/2016 12:54 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 01/29/2016 12:54 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 01/29/2016 12:54 JAHERMA11
Silver (Ag)< 1 ug/L EPA 200.8 01/29/2016 12:54 JAHERMA11
Page 4 of 10
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010005
2016000034
Collection Date:12-Jan-16 12:05 PM
Site:CRS-2
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
DISSOLVED METALS BY ICP
Barium (Ba)0.028 mg/L SW 6010C 01/21/2016 14:28 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/21/2016 14:28 FCJORDA0.05 1
Chromium (Cr)< 0.005 mg/L SW 6010C 01/21/2016 14:28 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/21/2016 14:28 FCJORDA0.005 1
Iron (Fe)0.824 mg/L SW 6010C 01/21/2016 14:28 FCJORDA0.01 1
Manganese (Mn)0.102 mg/L SW 6010C 01/21/2016 14:28 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010C 01/21/2016 14:28 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L SW 6010C 01/21/2016 14:28 FCJORDA0.005 1
DISSOLVED METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 01/29/2016 13:48 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 01/29/2016 13:48 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 01/29/2016 13:48 JAHERMA11
Silver (Ag)< 1 ug/L EPA 200.8 01/29/2016 13:48 JAHERMA11
Page 5 of 10
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010005
2016000035
Collection Date:11-Jan-16 10:20 AM
Site:CRS-3
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
DISSOLVED METALS BY ICP
Barium (Ba)0.032 mg/L SW 6010C 01/21/2016 14:31 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/21/2016 14:31 FCJORDA0.05 1
Chromium (Cr)< 0.005 mg/L SW 6010C 01/21/2016 14:31 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/21/2016 14:31 FCJORDA0.005 1
Iron (Fe)0.377 mg/L SW 6010C 01/21/2016 14:31 FCJORDA0.01 1
Manganese (Mn)1.26 mg/L SW 6010C 01/21/2016 14:31 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010C 01/21/2016 14:31 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L SW 6010C 01/21/2016 14:31 FCJORDA0.005 1
DISSOLVED METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 01/29/2016 13:53 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 01/29/2016 13:53 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 01/29/2016 13:53 JAHERMA11
Silver (Ag)< 1 ug/L EPA 200.8 01/29/2016 13:53 JAHERMA11
Page 6 of 10
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010005
2016000036
Collection Date:11-Jan-16 12:10 PM
Site:CRS-6
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
DISSOLVED METALS BY ICP
Barium (Ba)0.033 mg/L SW 6010C 01/21/2016 14:35 FCJORDA0.005 1
Boron (B)< 0.05 mg/L SW 6010C 01/21/2016 14:35 FCJORDA0.05 1
Chromium (Cr)< 0.005 mg/L SW 6010C 01/21/2016 14:35 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L SW 6010C 01/21/2016 14:35 FCJORDA0.005 1
Iron (Fe)0.101 mg/L SW 6010C 01/21/2016 14:35 FCJORDA0.01 1
Manganese (Mn)0.420 mg/L SW 6010C 01/21/2016 14:35 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010C 01/21/2016 14:35 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L SW 6010C 01/21/2016 14:35 FCJORDA0.005 1
DISSOLVED METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 01/29/2016 13:58 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 01/29/2016 13:58 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 01/29/2016 13:58 JAHERMA11
Silver (Ag)< 1 ug/L EPA 200.8 01/29/2016 13:58 JAHERMA11
Page 7 of 10
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010005
Q16010452 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 0.98 1 98mg/L -1158510.98
Boron (B) 1.97 2 98.4mg/L -1158511.97
Chromium (Cr) 1.02 1 102mg/L -1158511.02
Copper (Cu) 1.95 2 97.4mg/L -1158511.95
Iron (Fe) 2.02 2 101mg/L -1158512.02
Manganese (Mn) 0.98 1 98mg/L -1158510.98
Nickel (Ni) 2.01 2 101mg/L -1158512.01
Zinc (Zn) 1.02 1 102mg/L -1158511.02
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16010005 -- 2016000033
Barium (Ba) 5.66 5 113mg/L -1307015.66
Boron (B) 5.5 5 110mg/L -1307015.5
Chromium (Cr) 5.5 5 110mg/L -1307015.5
Copper (Cu) 5.48 5 110mg/L -1307015.48
Iron (Fe) 5.54 5 110mg/L -1307015.54
Manganese (Mn) 5.63 5 112mg/L -1307015.63
Nickel (Ni) 5.43 5 109mg/L -1307015.43
Zinc (Zn) 5.68 5 114mg/L -1307015.68
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16010005 -- 2016000033
Barium (Ba) 5.58 5 111 1.56mg/L -1307015.58
Boron (B) 5.45 5 109 0.804mg/L -1307015.45
Chromium (Cr) 5.46 5 109 0.73mg/L -1307015.46
Copper (Cu) 5.44 5 109 0.788mg/L -1307015.44
Iron (Fe) 5.51 5 109 0.512mg/L -1307015.51
Manganese (Mn) 5.58 5 111 0.752mg/L -1307015.58
Nickel (Ni) 5.39 5 108 0.702mg/L -1307015.39
Zinc (Zn) 5.63 5 113 0.849mg/L -1307015.63
Page 8 of 10
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010005
Q16010505 IMS Dissolved DISSOLVED METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As) 0.007 ug/L -10.007 1 < 1/2 RDL
Cadmium (Cd) 0 ug/L -10 1 < 1/2 RDL
Lead (Pb) -0.006 ug/L -1-0.006 1 < 1/2 RDL
Silver (Ag) 0.006 ug/L -10.006 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As) 83 100 83ug/L -11585183
Cadmium (Cd) 8.25 100 8.25ug/L -1158518.25
Lead (Pb) 82.2 100 82.2ug/L -11585182.2
Silver (Ag) 41.8 100 41.8ug/L -11585141.8
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16010005 -- 2016000033
Arsenic (As) 50 50 99.8ug/L -13070150
Cadmium (Cd) 50.1 50 100ug/L -13070150.1
Lead (Pb) 50.3 50 101ug/L -13070150.3
Silver (Ag) 49.1 50 98.2ug/L -13070149.1
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16010005 -- 2016000033
Arsenic (As) 46.6 50 93 7.08ug/L -13070146.6
Cadmium (Cd) 45.9 50 91.9 8.71ug/L -13070145.9
Lead (Pb) 46.6 50 93.1 7.83ug/L -13070146.6
Silver (Ag) 45.7 50 91.5 7.1ug/L -13070145.7
Page 9 of 10
Page 10 of 10