8503_DukeBelewsCreekPineHall_Oct2015_2ndSemiAnnual_DIN26342_20160124

Pine Hall Road Ash Landfill
Permit No. 8503
Semiannual Groundwater Monitoring Report
October 2015 Sampling Event
Belews Creek Steam Station
January 24, 2016

Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Belews Creek Pine Hall Road Ash Landfill, Permit No.8503 October 2015 Sampling Event Contents

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Contents
Page
Section 1 – Background ................................................................................................................ 1
Section 2 – Methods ..................................................................................................................... 3
2.1 Sampling and Analysis Methods .................................................................................... 3
2.2 Statement of Work .......................................................................................................... 3
Section 3 – Results ...................................................................................................................... 5
3.1 Site Groundwater Flow ................................................................................................... 5
3.2 Analytical Results ........................................................................................................... 5

Figures
1. Site Location Map
2. Sample Locations
3. Generalized Groundwater Surface Contours – October 26, 2015
Tables
1. Well Construction Information
2. Groundwater Flow Velocities – October 26, 2015
3. Field Data Parameters
4. Field and Analytical Results for Semiannual Constituents
5. Semiannual Constituents 15A NCAC 2L Groundwater Quality Exceedances for Wells
Within Review Boundary
6. Semiannual Constituents 15A NCAC 2L Groundwater Quality Exceedances at or Beyond Review Boundary
Appendices
Appendix A – Field Sampling Forms
Appendix B – Laboratory Report and Chain-of-Custody Forms
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Belews Creek Pine Hall Road Ash Landfill, Permit No.8503 October 2015 Sampling Event Section 1 – Background

1
Section 1 – Background
The Pine Hall Road Ash Landfill is located at the Duke Energy Carolinas, LLC (Duke Energy)
Belews Creek Steam Station in Stokes County, North Carolina. The landfill is permitted under
the North Carolina Department of Environmental Quality (NCDEQ) Solid Waste Permit No. 8503
and was closed in December 2008. The ash landfill was permitted to accept only fly ash from
Belews Creek Steam Station operations. The ash landfill and nearby surrounding area are
portrayed on Figure 1.
The landfill was originally permitted in 1983. The original landfill was unlined and was permitted
with a soil cap 1 foot thick on the side slopes and 2 feet thick on flatter areas. A subsequent
expansion (Phase I Expansion) was permitted in 2003. This phase was also unlined but was
permitted with a synthetic cap system to be applied at closure.
After groundwater exceedances were observed in wells installed near the landfill, the placement
of additional ash in the Phase I Expansion was halted. The closure design was changed to
utilize an engineered cover system for the portion of the landfill indicated on Figure 2. The
engineered cover system consists of a 40-mil linear low density polyethylene geomembrane, a
geonet composite, 18 inches of compacted soil, and 6 inches of vegetative soil cover. The
engineered cover system was installed over a 37.9 acre area, indicated on Figure 2 as
“Approximate Limits of Engineered Cover System.” An adjacent 14.5 acre area, located to the
northeast, had additional soil cover applied and was graded to improve surface drainage. This
area is indicated on Figure 2 as “Limits of Soil Cap.” The construction of the engineered cover
system and additional soil cover on the 14.5 acre area was completed in December 2008.
The ash landfill is located to the north of the surface water divide that runs along Pine Hall Road
and to the east of a surface water divide that runs along Middleton Loop Road. These surface
water divides appear to mimic the shallow groundwater divides in the area near the landfill. Two
surface water features are located in the area near the landfill. One surface water drainage
feature drains along the eastern side of the landfill to the Ash Basin. The second surface water
drainage feature is located on the western side of the landfill and drains to the Ash Basin. The
surface water sample locations in these features are groundwater seeps and are believed to be
representative of groundwater. Samples collected from these locations are compared to 15A
North Carolina Administrative Code (NCAC) 2L groundwater quality standards (2L Standards).
Groundwater flow beneath the landfill is from Pine Hall Road, generally northward, toward the
Ash Basin. The Ash Basin is operated as a water treatment facility and is permitted by the
National Pollutant Discharge Elimination System (NPDES) program (NPDES Permit
#NC0024406).

Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Belews Creek Pine Hall Road Ash Landfill, Permit No.8503 October 2015 Sampling Event Section 1 – Background

2
The groundwater monitoring system at the landfill consists of the following sample locations as
listed below.
Monitoring Wells: MW-1 MW-1D MW-2 MW-3
MW-4 MW-5
MW-6 MW-7 MW2-7 MW2-9
OB-4 OB-5 OB-9
Surface Water
Sample Locations: SW-1A SW-2

The locations of the monitoring wells and surface water sample locations are shown on
Figure 2. A summary of monitoring well construction information is presented in Table 1. As
defined by the Groundwater Monitoring, Sampling and Analysis Plan (SAP) for the Pine Hall
Road Ash Landfill (prepared by S&ME, Inc. dated November 8, 2010, and approved by NCDEQ
on November 23, 2010), monitoring well MW-3 is considered to represent “background”
groundwater quality conditions.
The groundwater and surface water sampling was conducted by Duke Energy according to
North Carolina Solid Waste Management Guidelines. The constituents sampled and analyzed
were selected by Duke Energy and the NCDEQ Division of Solid Waste and are listed in the
SAP, hereafter referred to as semiannual constituents. The samples were analyzed by a North
Carolina certified laboratory.
During previous sampling events (since April of 2009) the groundwater samples were also
analyzed for Part 40 Code of Federal Regulations (CFR) Part 258, Appendix I constituents, in
addition to the semiannual constituents listed in the SAP. Appendix I sampling and analysis was
performed as part of the requirements contained in the Closure Plan Approval letter dated
December 7, 2007, Document ID RC03425.
Sampling of Appendix I constituents has been discontinued as per a June 8, 2015 electronic
mail correspondence from Elizabeth Werner of the NCDEQ Solid Waste Section. A copy of this
coorespondence is retained in Duke Energy’s operating record.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Belews Creek Pine Hall Road Ash Landfill, Permit No.8503 October 2015 Sampling Event Section 2 – Methods

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Section 2 – Methods
2.1 Sampling and Analysis Methods
Groundwater sampling and documentation of sampling activities were performed by Duke
Energy personnel (Duke Energy Carolinas Field Certification #5193). Copies of the field
sampling forms are included in Appendix A. The groundwater samples were analyzed by the
Duke Energy Analytical Laboratory (North Carolina Laboratory Certification #248) and provided
to HDR by Duke Energy. The laboratory report and chain-of-custody forms are included in
Appendix B.
The groundwater samples were analyzed for the following constituents and/or parameters:
 Barium, beryllium, boron, chromium, copper, iron, manganese, nickel, silver, and zinc
using United States Environmental Protection Agency (EPA) Method 200.7
 Antimony, arsenic, cadmium, cobalt, lead, selenium, thallium, and vanadium using EPA
Method 200.8
 Mercury using EPA Method 245.1
 Chloride, fluoride, nitrate as nitrogen, and sulfate using EPA Method 300.0
 Total dissolved solids using Standard Method (SM) 2540C
2.2 Statement of Work
HDR completed the following tasks:
 Received field sampling information provided by Duke Energy for monitoring wells
MW-1, MW-1D, MW-3, MW-4, MW-5, MW-6, MW-7, MW2-7, MW2-9, OB-4, OB-5, and
OB-9 and surface water sampling locations SW-1A and SW-2. A groundwater sample
was not collected from monitoring well MW-2 due to insufficient water volume in the well.
A depth to groundwater measurement and a groundwater sample could not be collected
from monitoring well MW-6 due to the water level in the well being below the depth of the
pump. The samples were collected by Duke Energy personnel on October 26, 2015,
and HDR received the data on November 11, 2015.
 Reviewed the laboratory analytical results for samples. The Electronic Data Deliverable
(EDD) provided by Duke Energy was adapted to conform to the format requirements of
the NCDEQ EDD template. HDR added an italicized J data qualifier (J’) to indicate a
detected concentration that equals or is greater than the laboratory’s method reporting
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Belews Creek Pine Hall Road Ash Landfill, Permit No.8503 October 2015 Sampling Event Section 2 – Methods

4
limit (MRL), but is less than the Solid Waste Section Limit1 (SWSL). A copy of the
original EDD is retained in HDR’s files.
 Developed a generalized groundwater surface contour map using map data and
groundwater elevation data supplied by Duke Energy. Calculated groundwater flow
velocities based on groundwater contours.
 Prepared this Semiannual Groundwater Monitoring Report and submitted it to Duke
Energy.

1 The Solid Waste Section Limit (SWSL) is defined by NCDEQ as the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy. The SWSL is the
concentration below which reported results must be qualified as estimated. NCDEQ Division of Waste Management Memorandum dated February 23, 2007.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Belews Creek Pine Hall Road Ash Landfill, Permit No.8503 October 2015 Sampling Event Section 3 – Results

5
Section 3 – Results
3.1 Site Groundwater Flow
Generalized groundwater surface contours and groundwater flow direction arrows for the site
are shown on Figure 3. These contours were developed using the measured groundwater
elevations in the wells on the date of sampling. Calculated groundwater flow velocities are
presented in Table 2.
Pine Hall Road is located generally along a surface water divide that also appears to be a
groundwater divide. Groundwater flow at the landfill site is from areas of higher topography
along Pine Hall Road, generally northward, toward the Ash Basin.
3.2 Analytical Results
A summary of the field data is presented in Table 3.
The field and analytical results of groundwater and surface water sampling are summarized in
Table 4. The analytical results for the semiannual constituents are compared to the groundwater
standards found in Title 15A NCAC 02L .0202 (g) (2L Standards). Concentrations that attain or
exceed the 2L Standards are noted in Table 4 by bold font. Concentrations that equal or are
greater than the SWSLs are noted in Table 4 by gray-shaded cells.
A summary of the 2L Standard exceedances for the semiannual constituents and a preliminary
analysis of the cause and significance of the exceedances is presented in Table 5 for sampling
locations located within the review boundary and in Table 6 for sampling locations located at or
beyond the review boundary.
Select samples were diluted as is normal laboratory practice to bring samples to the calibrated
range of the analysis. Specifics regarding the samples that were diluted, including the dilution
factor, are reported in the EDD.
HDR previously prepared and submitted an assessment to the NCDEQ for exceedances of 2L
Standards at this landfill (Groundwater Assessment Belews Creek Steam Station Pine Hall
Road Ash Landfill, Permit No. 8503, dated October 1, 2012). The report assessed 2L Standard
exceedances at wells MW-3 and MW-6 and found those exceedances to be attributed to
naturally occurring conditions.
The assessment report reviewed the location of wells and surface water sample locations with
exceedances of 2L Standards (MW-4, MW-7, MW2-7, MW2-9, SW-1A, and SW-2) and found
that the hydrologic boundaries and the groundwater flow at the site was such that the
groundwater at these locations was discharging to the ash basin. The report also concluded that
with the reduced infiltration, due to the engineered cover system installed in 2008, the
groundwater concentration of constituents attributable to fly ash in these wells will likely
continue to decrease over time.

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v
e
n
t
9
.

I
n
f
o
r
m
a
t
i
o
n

p
r
o
v
i
d
e
d

b
y

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C
.

o
n

N
o
v
e
m
b
e
r

1
1
,

2
0
1
5
Well Diameter (in.)Casing Type
Gr
o
u
n
d
w
a
t
e
r

El
e
v
a
t
i
o
n

(
f
t
.
)
De
p
t
h

t
o

W
a
t
e
r

be
l
o
w

T
O
C
(f
t
.
)
To
t
a
l

W
e
l
l

De
p
t
h

b
e
l
o
w

TO
C
(ft
.
)
De
p
t
h

t
o

T
o
p

o
f

Sc
r
e
e
n

f
r
o
m

T
O
C
(f
t
.
)
Sc
r
e
e
n
e
d

I
n
t
e
r
v
a
l

be
l
o
w

T
O
C
(f
t
.
)

G
e
o
l
o
g
y

o
f

S
c
r
e
e
n
e
d

I
n
t
e
r
v
a
l
We
l
l

I
D
We
l
l

I
n
s
t
a
l
l
a
t
i
o
n

Da
t
e
TO
C

Ele
v
a
t
i
o
n

(
f
t
.
)
Gr
o
u
n
d

S
u
r
f
a
c
e

Ele
v
a
t
i
o
n
(f
t
.
)
We
l
l

S
t
i
c
k
-
u
p

He
i
g
h
t

A
b
o
v
e

Gr
o
u
n
d

S
u
r
f
a
c
e

(f
t
.
)
Co
o
r
d
i
n
a
t
e
s
Ta
b
l
e

2

-

G
r
o
u
n
d
w
a
t
e
r

F
l
o
w

V
e
l
o
c
i
t
i
e
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C
/
B
e
l
e
w
s

C
r
e
e
k

S
t
e
a
m

S
t
a
t
i
o
n
Pi
n
e

H
a
l
l

R
o
a
d

A
s
h

L
a
n
d
f
i
l
l

-

P
e
r
m
i
t

N
o
.

8
5
0
3
OB
-
9

7
6
5
.
0

7
6
0
.
0

7
9
.
8

0
.
0
6
3

0
.
4
1
1

0
.
2
5
9

0
.
0
9
9
MW
-
4

7
6
0
.
0

7
5
5
.
0

1
5
5
.
5

0
.
0
3
2

0
.
4
1
1

0
.
2
5
9

0
.
0
5
1
OB
-
4

7
6
0
.
0

7
5
5
.
0

6
8
.
7

0
.
0
7
4

0
.
4
1
1

0
.
2
5
9

0
.
1
1
7
OB
-
5

7
6
0
.
0

7
5
5
.
2

1
1
1
.
6

0
.
0
4
3

0
.
4
1
1

0
.
2
5
9

0
.
0
6
8
MW
-
7

8
0
5
.
0

8
0
0
.
0

2
4
2
.
5

0
.
0
2
1

0
.
4
1
1

0
.
2
5
9

0
.
0
3
3
MW
2
-
7

7
6
5
.
0

7
6
3
.
3

2
5
.
5

0
.
0
6
6

0
.
4
1
1

0
.
2
5
9

0
.
1
0
4
MW
2
-
9

7
9
5
.
0

7
9
0
.
0

4
6
.
1

0
.
1
0
9

0
.
4
1
1

0
.
2
5
9

0
.
1
7
2
No
t
e
s
:
1
.

L
i
n
e
a
r

d
i
s
t
a
n
c
e

m
e
a
s
u
r
e
d

t
h
r
o
u
g
h

m
o
n
i
t
o
r
i
n
g

w
e
l
l
s

i
s

g
e
n
e
r
a
l
l
y

p
e
r
p
e
n
d
i
c
u
l
a
r

t
o

g
r
o
u
n
d
w
a
t
e
r

c
o
n
t
o
u
r
s
.
2
.

A
t

m
o
n
i
t
o
r
i
n
g

w
e
l
l

l
o
c
a
t
i
o
n
s

w
h
e
r
e

d
o
w
n
g
r
a
d
i
e
n
t

c
o
n
t
o
u
r
s

a
r
e

n
o
t

p
r
e
s
e
n
t
,

t
h
e

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n

a
t

t
h
e

m
o
n
i
t
o
r
i
n
g

w
e
l
l

i
s

u
s
e
d

a
s

t
h
e

d
o
w
n
g
r
a
d
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n
.
3
.

A
t

m
o
n
i
t
o
r
i
n
g

w
e
l
l

l
o
c
a
t
i
o
n
s

w
h
e
r
e

u
p
g
r
a
d
i
e
n
t

c
o
n
t
o
u
r
s

a
r
e

n
o
t

p
r
e
s
e
n
t
,

t
h
e

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n

a
t

t
h
e

m
o
n
i
t
o
r
i
n
g

w
e
l
l

i
s

u
s
e
d

a
s

t
h
e

u
p
g
r
a
d
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n
.
4
.

M
o
n
i
t
o
r
i
n
g

w
e
l
l
s

a
r
e

n
o
t

l
i
s
t
e
d

w
h
e
r
e

i
n
s
u
f
f
i
c
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

c
o
n
t
o
u
r

i
n
f
o
r
m
a
t
i
o
n

i
s

a
v
a
i
l
a
b
l
e

t
o

c
a
l
c
u
l
a
t
e

v
e
l
o
c
i
t
y
.
5
.

H
y
d
r
a
u
l
i
c

g
r
a
d
i
e
n
t

i
s

a
p
p
r
o
x
i
m
a
t
e
.
6
.

H
y
d
r
a
u
l
i
c

c
o
n
d
u
c
t
i
v
i
t
y

p
r
e
s
e
n
t
e
d

i
s

t
h
e

g
e
o
m
e
t
r
i
c

m
e
a
n

o
f

t
h
e

c
o
n
d
u
c
t
i
v
i
t
y

d
a
t
a

f
o
r

t
h
e

a
l
l
u
v
i
u
m
/
s
o
i
l
/
s
a
p
r
o
l
i
t
e

h
y
d
r
o
s
t
r
a
t
i
gr
a
p
h
i
c

l
a
y
e
r

i
n

t
h
e

H
D
R

C
o
n
d
u
c
t
i
v
i
t
y

D
a
t
a
b
a
s
e

(
u
n
p
u
b
l
i
s
h
e
d

d
a
t
a

f
r
o
m

C
a
r
o
l
i
n
a

s
i
t
e
s

w
i
t
h

f
o
l
i
a
t
e
d
/
l
a
y
e
r
e
d

b
e
d
r
o
c
k
)
.
7
.

E
f
f
e
c
t
i
v
e

p
o
r
o
s
i
t
y

p
r
e
s
e
n
t
e
d

i
s

t
h
e

m
e
a
n

v
a
l
u
e

o
f

t
h
e

a
l
l
u
v
i
u
m
/
s
o
i
l
/
s
a
p
r
o
l
i
t
e

h
y
d
r
o
s
t
r
a
t
i
g
r
a
p
h
i
c

l
a
y
e
r

e
s
t
i
m
a
t
e
d

f
r
o
m

s
o
i
l

te
s
t
i
n
g

u
s
i
n
g

F
e
t
t
e
r
/
B
e
a
r

D
i
a
g
r
a
m
s
.

8
.

H
y
d
r
a
u
l
i
c

g
r
a
d
i
e
n
t
s

a
n
d

g
r
o
u
n
d
w
a
t
e
r

v
e
l
o
c
i
t
i
e
s

c
a
l
c
u
l
a
t
e
d

b
a
s
e
d

o
n

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n

m
e
a
s
u
r
e
m
e
n
t
s

o
n

O
c
t
o
b
e
r

2
6
,

2
0
1
5
Hy
d
r
a
u
l
i
c

Co
n
d
u
c
t
i
v
i
t
y

(f
t
/
d
a
y
)
Ef
f
e
c
t
i
v
e

Po
r
o
s
i
t
y

(%
/
1
0
0
)
Gr
o
u
n
d
w
a
t
e
r

Ve
l
o
c
i
t
y

(f
t
/
d
a
y
)
We
l
l

I
D
Up
g
r
a
d
i
e
n
t

Gr
o
u
n
d
w
a
t
e
r

Co
n
t
o
u
r

El
e
v
a
t
i
o
n

(
f
t
)
D
o
w
n
g
r
a
d
i
e
n
t

Gr
o
u
n
d
w
a
t
e
r

Co
n
t
o
u
r

El
e
v
a
t
i
o
n
(f
t
)
Li
n
e
a
r

D
i
s
t
a
n
c
e

Be
t
w
e
e
n

Co
n
t
o
u
r
s

th
r
o
u
g
h

W
e
l
l
(f
t
)
Hy
d
r
a
u
l
i
c

Gr
a
d
i
e
n
t

(f
t
/
f
t
)
Ta
b
l
e

3

-

F
i
e
l
d

D
a
t
a

P
a
r
a
m
e
t
e
r
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C
/
B
e
l
e
w
s

C
r
e
e
k

S
t
e
a
m

S
t
a
t
i
o
n
Pi
n
e

H
a
l
l

R
o
a
d

A
s
h

L
a
n
d
f
i
l
l

-

P
e
r
m
i
t

N
o
.

8
5
0
3
10
/
2
6
/
2
0
1
5

M
W
-
1

4
7
.
2
0

3
8
.
0
3

8
1
4
.
6
6

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
5
0

4
.
0
0

N
O

1
4
.
2
6

1
9

5
.
1

5
.
5

4
2
6

8
.
0
6
10
/
2
6
/
2
0
1
5

M
W
-
1
D

9
0
.
5
3

4
4
.
7
5

8
0
9
.
4
0

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

7
.
4
7

1
5
.
0
0

N
O

1
4
.
2
2

1
2
3

6
.
6

1
.
6

3
4
6

4
.
7
5
10
/
2
6
/
2
0
1
5

M
W
-
2

5
0
.
0
0

4
7
.
9
4

8
1
0
.
1
1

N
S

N
o
n
e

E
O
P

N
/
A

0
.
3
4

0
.
4
1

N
S

N
S

N
S

N
S

N
S

N
S

N
S
10
/
2
6
/
2
0
1
5

M
W
-
3

4
9
.
5
0

4
3
.
8
7

7
9
8
.
9
4

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

0
.
9
2

1
.
0
0

Y
E
S

1
4
.
0
6

5
7

5
.
9

1
6
.
6

3
9
2

9
.
1
8
10
/
2
6
/
2
0
1
5

M
W
-
4

4
0
.
2
0

1
2
.
5
6

7
5
5
.
0
2

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

4
.
5
1

1
1
.
7
5

N
O

1
4
.
6
5

2
7
2

6
.
0

3
.
7

3
5
7

2
.
2
5
10
/
2
6
/
2
0
1
5

M
W
-
5

6
0
.
2
0

2
6
.
0
9

7
6
0
.
6
8

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

5
.
5
6

1
2
.
5
0

N
O

1
4
.
5
6

3
5

5
.
7

6
.
1

4
0
3

6
.
8
1
10
/
2
6
/
2
0
1
5

M
W
-
6

3
6
.
8
4

B
e
l
o
w

P
u
m
p

N
/
A

N
S

N
S

N
S

N
/
A

N
S

N
S

N
S

N
S

N
S

N
S

N
S

N
S

N
S
10
/
2
6
/
2
0
1
5

M
W
-
7

1
4
.
2
6

8
.
5
9

8
0
6
.
9
8

T
u
r
b
i
d

N
o
n
e

C
P

N
/
A

0
.
9
2

4
.
0
0

N
O

1
7
.
3
5

4
1
4

5
.
5

6
6
.
1

3
7
1

5
.
3
0
10
/
2
6
/
2
0
1
5

M
W
2
-
7

3
0
.
6
2

1
4
.
3
1

7
6
3
.
3
3

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

2
.
6
6

1
3
.
7
5

N
O

1
5
.
7
0

2
,
0
1
6

5
.
2
0

2
.
1

3
9
0

0
.
2
3
10
/
2
6
/
2
0
1
5

M
W
2
-
9

1
4
.
6
1

6
.
5
9

7
9
0
.
7
9

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
3
1

2
.
5
0

Y
E
S

1
6
.
5
4

2
7
7

6
.
1
0

7
.
0

3
0
7

2
.
4
2
10
/
2
6
/
2
0
1
5

O
B
-
4

3
0
.
0
3

2
2
.
6
5

7
5
4
.
9
5

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
2
0

3
.
7
5

N
O

1
4
.
9
1

2
,
6
5
0

7
.
3
0

2
.
6

2
8
0

0
.
7
8
10
/
2
6
/
2
0
1
5

O
B
-
5

3
6
.
6
0

2
5
.
7
3

7
5
5
.
2
0

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
7
7

6
.
0
0

N
O

1
5
.
0
8

3
0
.
0

5
.
4
0

4
.
6

3
9
2

5
.
0
2
10
/
2
6
/
2
0
1
5

O
B
-
9

4
8
.
5
7

3
8
.
0
7

7
6
1
.
5
2

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
7
1

5
.
2
5

N
O

1
4
.
5
2

2
,
0
5
4

5
.
1
0

1
.
0

2
9
5

0
.
1
5
10
/
2
6
/
2
0
1
5

S
W
-
1
A

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

1
3
.
5
4

1
,
4
3
7

6
.
1

2
.
0

3
4
9

5
.
7
1
10
/
2
6
/
2
0
1
5

S
W
-
2

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

1
3
.
8
1

1
5
6

6
.
3

5
.
6

2
9
5

8
.
9
1
No
t
e
s
:
1
.

P
u
r
g
e

M
e
t
h
o
d
s
;

L
F
=
L
o
w

F
l
o
w
,

L
F
(
M
)
=

L
o
w

F
l
o
w

(
M
o
d
i
f
i
e
d
)
,

C
P
=
C
o
n
v
e
n
t
i
o
n
a
l

P
u
r
g
e

(
3
-
5

w
e
l
l

v
o
l
u
m
e
s
)
,

E
O
P
=
E
q
u
i
p
m
e
n
t

O
n
l
y

P
u
r
g
e
, N
P
=
N
o

P
u
r
g
e

(
H
y
d
r
a
S
l
e
e
v
e
)
.

A
v
e
r
a
g
e

p
u
m
p

r
a
t
e

a
p
p
l
i
c
a
b
l
e

t
o

L
F

a
n
d

L
F
(
M
)

p
u
r
g
i
n
g

o
n
l
y
.
2
.

F
i
e
l
d

s
a
m
p
l
i
n
g

p
e
r
f
o
r
m
e
d

b
y

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

p
e
r
s
o
n
n
e
l
.
3
.

E
V
A
C

i
n
d
i
c
a
t
e
s

w
h
e
t
h
e
r

t
h
e

w
a
t
e
r

l
e
v
e
l

i
n

t
h
e

w
e
l
l

w
a
s

d
r
a
w
n

d
o
w
n

t
o

t
h
e

l
e
v
e
l

o
f

t
h
e

p
u
m
p

d
u
r
i
n
g

p
u
r
g
i
n
g
.
4
.

µƱ /cm

i
n
d
i
c
a
t
e
s

m
i
c
r
o
o
h
m
s

p
e
r

c
e
n
t
i
m
e
t
e
r
.
5
.

S
U

i
n
d
i
c
a
t
e
s

S
t
a
n
d
a
r
d

U
n
i
t
s
.
6
.

N
T
U

i
n
d
i
c
a
t
e
s

N
e
p
h
e
l
o
m
e
t
r
i
c

T
u
r
b
i
d
i
t
y

U
n
i
t
s
.
7
.

m
V
-
N
H
E

i
n
d
i
c
a
t
e
s

m
i
l
l
i
v
o
l
t
s
-
N
o
r
m
a
l

H
y
d
r
o
g
e
n

E
l
e
c
t
r
o
d
e
.
8
.

m
g
/
L

i
n
d
i
c
a
t
e
s

m
i
l
l
i
g
r
a
m
s

p
e
r

l
i
t
e
r
.
9
.

N
/
A

i
n
d
i
c
a
t
e
s

n
o
t

a
p
p
l
i
c
a
b
l
e
.
10
.

N
S

i
n
d
i
c
a
t
e
s

n
o

s
a
m
p
l
e

w
a
s

c
o
l
l
e
c
t
e
d
.
11
.

T
h
e

d
e
p
t
h

t
o

g
r
o
u
n
d
w
a
t
e
r

i
n

m
o
n
i
t
o
r
i
n
g

w
e
l
l

M
W
-
6

w
a
s

b
e
l
o
w

t
h
e

l
e
v
e
l

o
f

t
h
e

p
u
m
p
;

t
h
e
r
e
f
o
r
e
,

a

d
e
p
t
h

t
o

w
a
t
e
r

m
e
a
s
u
r
e
m
e
n
t

wa
s

n
o
t

r
e
c
o
r
d
e
d

a
n
d

a

g
r
o
u
n
d
w
a
t
e
r

s
a
m
p
l
e

w
a
s

n
o
t

c
o
l
l
e
c
t
e
d
.
12
.

T
h
e
r
e

w
a
s

i
n
s
u
f
f
i
c
i
e
n
t

v
o
l
u
m
e

i
n

m
o
n
i
t
o
r
i
n
g

w
e
l
l

M
W
-
2

t
o

c
o
l
l
e
c
t

a

g
r
o
u
n
d
w
a
t
e
r

s
a
m
p
l
e
.
13
.

I
n
f
o
r
m
a
t
i
o
n

p
r
o
v
i
d
e
d

b
y

T
i
m

H
u
n
s
u
c
k
e
r

o
f

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

o
n

N
o
v
e
m
b
e
r

1
1
,

2
0
1
5
.
AP
P
E
A
R
A
N
C
E
DA
T
E

S
A
M
P
L
E

I
D
WE
L
L
DE
P
T
H
(f
e
e
t
)
DE
P
T
H

T
O
WA
T
E
R
(f
e
e
t
)
WA
T
E
R
EL
E
V
.
(f
e
e
t
)
DO (mg/L)
OD
O
R
PU
R
G
E
ME
T
H
O
D

AV
E
R
A
G
E
PU
M
P

RA
T
E
(m
l
/
m
i
n
)
WE
L
L
VO
L
U
M
E
(g
a
l
)
EV
A
C
VO
L
U
M
E
(g
a
l
)
EV
A
C
(Y
E
S
/
N
O
)
TE
M
P
(d
e
g

C
)
SP
E
C
I
F
I
C
CO
N
D
U
C
T
A
N
C
E
(µ
Ʊ /c
m
)
pH
(S
U
)
TURBIDITY (NTU)ORP (mV-NHE)
Ta
b
l
e

4

-

F
i
e
l
d

a
n
d

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s

f
o
r

S
e
m
i
a
n
n
u
a
l

C
o
n
s
t
i
t
u
e
n
t
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C
/
B
e
l
e
w
s

C
r
e
e
k

S
t
e
a
m

S
t
a
t
i
o
n
Pi
n
e

H
a
l
l

R
o
a
d

A
s
h

L
a
n
d
f
i
l
l

-

P
e
r
m
i
t

N
o
.

8
5
0
3
Fie
l
d

p
H

3
2
0

S
U

5
1
9
3
---
NE

6
.
5
-
8
.
5

6
.
5
-
8
.
5
*
Fie
l
d

S
p
e
c
i
f
i
c

C
o
n
d
u
c
t
a
n
c
e

3
2
3

µ
Ʊ /cm

5
1
9
3
---
NE

N
E

N
E
Te
m
p
e
r
a
t
u
r
e

3
2
5

°
C

5
1
9
3
---
NE

N
E

N
E
To
p

C
a
s
i
n
g
32
8

f
e
e
t

-
-
-
---
NE

N
E

N
E
De
p
t
h

t
o

W
a
t
e
r
31
8

f
e
e
t

-
-
-
---
NE

N
E

N
E
Wa
t
e
r

E
l
e
v
a
t
i
o
n

3
1
9

f
e
e
t

-
-
-
---
NE

N
E

N
E
We
l
l

D
e
p
t
h

4
1
1

f
e
e
t

-
-
-
---
NE

N
E

N
E
Ar
s
e
n
i
c

1
4

µ
g
/
L

2
4
8

0
.
1
2
3
J
0.1
2
1
J
0.
4
0
1
J
0.
1
6
1

J

0
.
9
1
5
J
0.0
7
8

1
0

1
0

1
0
Ba
r
i
u
m

1
5

µ
g
/
L

2
4
8

1
9
.
6
J '
11
.
6
J '
58
.
3
J '
4.
4

J

3
5
.
9
J '
0.
1

1
0
0

7
0
0

2
,
0
0
0
Bo
r
o
n

4
2
8

µ
g
/
L

2
4
8

7
.
6
7
J
20
.
9
J
5.4
3
J
68
5

3
.
3

U
3.
3

N
E

7
0
0

N
E
Ca
d
m
i
u
m

3
4

µ
g
/
L

2
4
8

0
.
1
0
1

U

0
.
1
0
1

U

0
.
1
0
1

U

0
.
1
0
1

U

0
.
1
0
1

U
0.1
0
1

1

2

5
Ch
l
o
r
i
d
e

4
5
5

µ
g
/
L

2
4
8

1
,
6
1
0

8
,
2
8
0

9
,
0
9
0

2
,
6
2
0

1
,
9
5
0
22

N
E

2
5
0
,
0
0
0

2
5
0
,
0
0
0
*
Ch
r
o
m
i
u
m

5
1

µ
g
/
L

2
4
8

0
.
6
2
7
J
9.5
3
J '
1.3
4
J
13
.
4
1.
7
2
J
0.
5

1
0

1
0

1
0
0
Co
p
p
e
r
54

µ
g
/
L

2
4
8

1

U

9
.
2
J '
1

U

1

U

9
1
.
8
1

1
0

1
,
0
0
0

1
,
3
0
0
Fl
u
o
r
i
d
e

3
1
2

µ
g
/
L

2
4
8

4
9
.
5
J
13
7
J '
59
.
8
J
76

J

5
1
.
5
J
17

2
,
0
0
0

2
,
0
0
0

4
,
0
0
0
Ir
o
n

3
4
0

µ
g
/
L

2
4
8

1
6
1
J '
20
.
7
J '
99
1
12
3
J '
51
4
1.
3

3
0
0

3
0
0

3
0
0
*
Le
a
d

1
3
1

µ
g
/
L

2
4
8

0
.
5
8
1
J
0.0
6
5

U

0
.
4
4
9
J
0.
0
6
5

U

9
.
9
4
J '
0.0
6
5

1
0

1
5

1
5
Ma
n
g
a
n
e
s
e

3
4
2

µ
g
/
L

2
4
8

2
8
.
2
J '
15
.
7
J '
17
.
2
J '
2.3
9

J

1
3
.
9
J '
0.
2

5
0

5
0

5
0
*
Me
r
c
u
r
y

1
3
2

µ
g
/
L

2
4
8

0
.
0
0
7
J
0.0
1
J
0.0
1
J
0.
0
1
1

J

0
.
0
1
1
J
0.0
0
6

0
.
2

1

2
Ni
c
k
e
l

1
5
2

µ
g
/
L

2
4
8

0
.
5

U

9
.
2
2
J '
0.
5

U

0
.
5

U

0
.
5

U
0.
5

5
0

1
0
0

N
E
Nit
r
a
t
e

(
a
s

N
i
t
r
o
g
e
n
)

3
0
3

µ
g
/
L

2
4
8

2
5
7
J '
1,8
7
0
J '
7
J
93
9
J '
64
9
J '
5.
4

1
0
,
0
0
0

1
0
,
0
0
0

1
0
,
0
0
0
Se
l
e
n
i
u
m

1
8
3

µ
g
/
L

2
4
8

0
.
0
9
2

U

0
.
0
9
7
7
J
0.
0
9
2

U

1
7
.
7

0
.
0
9
2

U
0.0
9
2

1
0

2
0

5
0
Sil
v
e
r

1
8
4

µ
g
/
L

2
4
8

0
.
7

U

2
.
0
4
J
1.1
6
J
0.
7

U

0
.
7

U
0.
7

1
0

2
0

1
0
0
*
Su
l
f
a
t
e

3
1
5

µ
g
/
L

2
4
8

1
,
2
2
0
J '
96
7
J '
32
7
J '
89
,
1
0
0
J '
15
2
J '
18

2
5
0
,
0
0
0

2
5
0
,
0
0
0

2
5
0
,
0
0
0
*
To
t
a
l

D
i
s
s
o
l
v
e
d

S
o
l
i
d
s
31
1

µ
g
/
L

2
4
8

3
9
,
0
0
0

9
8
,
0
0
0

5
8
,
0
0
0

2
0
9
,
0
0
0

5
6
,
0
0
0
16
,
7
0
0

N
E

5
0
0
,
0
0
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n
c
e

3
2
3

µ
Ʊ /cm

5
1
9
3
---
NE

N
E

N
E
Te
m
p
e
r
a
t
u
r
e

3
2
5

°
C

5
1
9
3
---
NE

N
E

N
E
To
p

C
a
s
i
n
g
32
8

f
e
e
t

-
-
-
---
NE

N
E

N
E
De
p
t
h

t
o

W
a
t
e
r
31
8

f
e
e
t

-
-
-
---
NE

N
E

N
E
Wa
t
e
r

E
l
e
v
a
t
i
o
n

3
1
9

f
e
e
t

-
-
-
---
NE

N
E

N
E
We
l
l

D
e
p
t
h

4
1
1

f
e
e
t

-
-
-
---
NE

N
E

N
E
Ars
e
n
i
c

1
4

µ
g
/
L

2
4
8

0
.
6
8
8
J
1.1
2
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0.
9
7
7
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34
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7
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1
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r
i
u
m

1
5

µ
g
/
L

2
4
8

4
5
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5
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28
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1
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63
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7
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34
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7
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11
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1
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7
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2
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0
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Bo
r
o
n

4
2
8

µ
g
/
L

2
4
8
2,
9
3
0

2
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,
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0
28
6
18
,
0
0
0
47
.
8
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3.3

N
E

7
0
0

N
E
Ca
d
m
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u
m

3
4

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g
/
L

2
4
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0
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1
3
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7
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1
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5
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l
o
r
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4
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g
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9
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5
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E

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2
5
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r
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m
i
u
m

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5

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5
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p
p
e
r
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g
/
L

2
4
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1

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1

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5
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0
3
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r
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e

3
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g
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13
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98
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8
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4
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n

3
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7
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a
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1
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3
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n
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3
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Me
r
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k
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9
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9
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6
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5

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t
r
a
t
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(
a
s

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i
t
r
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g
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n
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3
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9
4
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9
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0
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0
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0

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0
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l
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n
i
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m

1
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2
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8
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11
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v
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l
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3
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0
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2
4
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To
t
a
l

D
i
s
s
o
l
v
e
d

S
o
l
i
d
s
31
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g
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2
4
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4
4
,
0
0
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8
2
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,
0
0
0
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7
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0
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0
30
,
0
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16
,
7
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5
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0
,
0
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5
0
0
,
0
0
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n
c

2
1
3

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g
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7

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5
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No
t
e
s
:
1
.

C
o
n
c
e
n
t
r
a
t
i
o
n
s

p
r
e
s
e
n
t
e
d

i
n

m
i
c
r
o
g
r
a
m
s

p
e
r

l
i
t
e
r

(
µ
g
/
L
)
.
2
.

S
W
S

I
D

i
s

t
h
e

S
o
l
i
d

W
a
s
t
e

S
e
c
t
i
o
n

I
d
e
n
t
i
f
i
c
a
t
i
o
n

N
u
m
b
e
r
.
3
.

M
D
L

i
s

t
h
e

l
a
b
o
r
a
t
o
r
y

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.

T
h
e

M
D
L

v
a
l
u
e
s

p
r
e
s
e
n
t
e
d

a
r
e

f
o
r

s
a
m
p
l
e
s

n
o
t

d
i
l
u
t
e
d

b
y

t
h
e

l
a
b
o
r
a
t
o
r
y

d
u
r
i
ng

a
n
a
l
y
s
i
s
.

4
.

S
W
S
L

i
s

t
h
e

S
o
l
i
d

W
a
s
t
e

S
e
c
t
i
o
n

L
i
m
i
t
.

N
C
D
E
Q

d
e
f
i
n
e
s

t
h
e

S
W
S
L

a
s

t
h
e

l
o
w
e
s
t

a
m
o
u
n
t

o
f

a
n
a
l
y
t
e

i
n

a

s
a
m
p
l
e

t
h
a
t

c
a
n

b
e

q
u
a
nt
i
t
a
t
i
v
e
l
y

d
e
t
e
r
m
i
n
e
d

w
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t
h

s
u
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t
a
b
l
e

p
r
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c
i
s
i
o
n

a
n
d

a
c
c
u
r
a
c
y
.

5
.

1
5
A

N
C
A
C

2
L

S
t
a
n
d
a
r
d

r
e
f
e
r
s

t
o

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l
a
s
s

G
A

S
t
a
n
d
a
r
d
s

a
s

f
o
u
n
d

i
n

1
5
A

N
C
A
C

0
2
L
.

0
2
0
2

G
r
o
u
n
d
w
a
t
e
r

Q
u
a
l
i
t
y

S
t
a
n
d
a
r
d
s
,

l
a
s
t

a
m
e
n
d
ed

o
n

A
p
r
i
l

1
,

2
0
1
3

(
A
p
p
e
n
d
i
x

I

r
e
v
i
s
e
d

A
p
r
i
l

1
,

2
0
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)
.

6
.

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C
L

i
s

t
h
e

F
e
d
e
r
a
l

M
a
x
i
m
u
m

C
o
n
t
a
m
i
n
a
n
t

L
e
v
e
l

a
s

f
o
u
n
d

i
n

4
0

C
F
R
,

S
u
b
p
a
r
t

G
,

§
1
4
1
.
6
2
.
7
.

*

C
o
n
c
e
n
t
r
a
t
i
o
n

l
i
s
t
e
d

i
s

a

s
e
c
o
n
d
a
r
y

m
a
x
i
m
u
m

c
o
n
t
a
m
i
n
a
n
t

l
e
v
e
l

(
S
M
C
L
)
.

S
M
C
L
s

a
r
e

e
s
t
a
b
l
i
s
h
e
d

b
y

E
P
A

i
n

t
h
e

N
a
t
i
o
n
a
l

S
e
c
o
nd
a
r
y

D
r
i
n
k
i
n
g

W
a
t
e
r

R
e
g
u
l
a
t
i
o
n
s
.
8
.

N
E

i
n
d
i
c
a
t
e
s

n
o
t

e
s
t
a
b
l
i
s
h
e
d
.

N
S

i
n
d
i
c
a
t
e
s

n
o

s
a
m
p
l
e

w
a
s

c
o
l
l
e
c
t
e
d
.

N
A

i
n
d
i
c
a
t
e
s

n
o
t

a
n
a
l
y
z
e
d
.

B
l
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

t
h
a
t
t
h
e
r
e

i
s

n
o

i
n
f
o
r
m
a
t
i
o
n

r
e
l
e
v
a
n
t

t
o

t
h
e

r
e
s
p
e
c
t
i
v
e

r
o
w
.

9
.

G
r
a
y
e
d

v
a
l
u
e
s

i
n
d
i
c
a
t
e

v
a
l
u
e
s

t
h
a
t

e
q
u
a
l

o
r

a
r
e

g
r
e
a
t
e
r

t
h
a
n

t
h
e

S
W
S
L
.
10
.

B
o
l
d

v
a
l
u
e
s

i
n
d
i
c
a
t
e

v
a
l
u
e
s

t
h
a
t

a
t
t
a
i
n

o
r

e
x
c
e
e
d

t
h
e

1
5
A

N
C
A
C

2
L

S
t
a
n
d
a
r
d
.
11
.

Q
u
a
l
i
f
i
e
r
s

i
n

n
o
n
-
i
t
a
l
i
c
i
z
e
d

t
e
x
t

a
r
e

l
a
b
o
r
a
t
o
r
y

d
a
t
a

q
u
a
l
i
f
i
e
r
s

o
r

"
f
l
a
g
s
"
.

"
U
"

i
s

u
s
e
d

t
o

i
d
e
n
t
i
f
y

r
e
s
u
l
t
s

n
o
t

d
e
t
e
c
t
e
d

a
t
c
o
n
c
e
n
t
r
a
t
i
o
n
s

w
h
i
c
h

e
q
u
a
l

t
h
e

l
a
b
o
r
a
t
o
r
y
'
s

M
D
L
.

"
J
"

i
s

u
s
e
d

t
o

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d
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n
t
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f
y

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t
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m
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t
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d

c
o
n
c
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n
t
r
a
t
i
o
n
s

w
h
i
c
h

e
q
u
a
l

o
r

a
r
e

g
r
e
a
t
e
r

t
h
a
n

t
h
e

M
D
L

b
u
t

a
r
e

l
e
s
s

t
h
a
n

t
h
e

l
a
b
o
r
a
t
o
r
y
's

m
e
t
h
o
d

r
e
p
o
r
t
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n
g

l
i
m
i
t

(
M
R
L
)
.

A
n

i
t
a
l
i
c
i
z
e
d

J'
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l
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g

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a

d
a
t
a

q
u
a
l
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f
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r
,

a
d
d
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d

b
y

H
D
R

t
o

i
n
d
i
c
a
t
e

c
o
n
c
e
n
t
r
a
t
i
o
n
s

w
h
i
c
h

e
q
u
a
l

o
r

a
r
e

g
r
e
a
t
e
r

t
h
a
n

t
h
e

l
a
b
o
r
a
t
o
r
y
'
s

M
R
L

b
u
t

a
r
e
le
s
s

t
h
a
n

t
h
e

S
W
S
L
.

12
.

S
U

i
n
d
i
c
a
t
e
s

S
t
a
n
d
a
r
d

U
n
i
t
s
.
13
.

µ
Ʊ /c
m

i
n
d
i
c
a
t
e
s

m
i
c
r
o
m
h
o
s

p
e
r

c
e
n
t
i
m
e
t
e
r
.
14
.

A
c
c
o
r
d
i
n
g

t
o

t
h
e

C
o
n
s
t
i
t
u
e
n
t

L
o
o
k
-
u
p

w
e
b
p
a
g
e

o
n

t
h
e

N
C
D
E
Q

D
i
v
i
s
i
o
n

o
f

W
a
s
t
e

M
a
n
a
g
e
m
e
n
t

w
e
b
p
a
g
e
,

t
h
e
r
e

i
s

n
o

S
W
S
L

o
r

2
L

S
t
a
n
da
r
d

f
o
r

c
h
l
o
r
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d
e

a
s
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A
Appendix A
Field Sampling Forms

ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬/▬►0.0 0.0 ▬/▬►0.0
SS 223.6 ▬▬►227 225.6 ▬/▬►227
SS 74.6 ▬/▬►75 74.2 ▬/▬►75
SS ▬/▬►3231.0 ▬/▬►3200
B (7.00)7.06 ▬▬►7.02 7.22 ▬/▬►7.02
B (4.00)3.98 ▬▬►4.00 4.19 ▬/▬►4.00
B (10.00)10.05 ▬/▬►10.06 10.26 ▬/▬►10.06
20.18 20.14
pH Check B (7.00)▬▬►
Time:
SS (7.00)301 ▬▬►295 280 ▬/▬►295
SS (4.00)N/A ▬/▬►470 N/A ▬/▬►470
20.01 20.10
W 9.00 8.80
W 9.00 8.80
AW 9.04 ▬▬►9.00 8.81 ▬/▬►8.80
SS 52.3 ▬/▬►53.5 54.1 ▬/▬►53.5
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
FIELD SAMPLING CALIBRATION FORM
STUDY:BELEWS CREEK STEAM STATION - PINE HALL LANDFILL GROUNDWATER MONITORING
DATE (s):October 26, 2015 SURFACE UNIT READER:LDC
OTHER EQUIPMENT:TURBIDIMETER NO.2 - 3260-GW Cloudy, windy, slight drizzle, 50 to 55 deg F
COLLECTORS:LDC, PSP SURFACE UNIT SERIAL #:S0205
ANALYZER MODEL#:MS5 66121
PROCEDURE #:HYDROLAB 3210.5 VALIDATED BY:
Calibration Date / Time 26-Oct-15 350 27-Oct-15 4:10
CALIBRATION BP (mmHg)748.0 CALIBRATION BP (mmHg)751.3
Parameter Calibration Results Calibration Results
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
Calibration Pass
SPEC. COND.
(uS/cm)
Instrument Zeroed Zero Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
pH
(units)
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Buffer Temp.Buffer Temp.
Buffer Temp.
Calibration Accepted Calibration Pass
ORP Temp.ORP Temp.
Calibration Pass
TURB
(ntu)Calibration Accepted Calibration Accepted
DO
(mg/L)Calibration Accepted
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 750.1 (mmHg)Ending BP 752.1
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬/▬►0.0 0.0 ▬/▬►0.0
SS 230.9 ▬▬►227 224.2 ▬/▬►227
SS 72.2 ▬/▬►75 72.2 ▬/▬►75
SS 3158.0 ▬/▬►3200 3160.0 ▬/▬►3200
B (7.00)7.04 ▬▬►7.02 7.06 ▬/▬►7.02
B (4.00)3.95 ▬▬►4.00 4.07 ▬/▬►4.00
B (10.00)9.98 ▬/▬►10.06 10.09 ▬/▬►10.06
20.12 20.14
pH Check B (7.00)▬▬►
Time:
SS (7.00)304 ▬▬►295 290 ▬/▬►295
SS (4.00)N/A ▬/▬►470 N/A ▬/▬►470
19.97 20.06
W 9.00 8.80
W 9.00 8.80
AW 9.19 ▬▬►9.00 8.78 ▬/▬►8.80
SS 53.9 ▬/▬►54.5 53.9 ▬/▬►54.5
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
FIELD SAMPLING CALIBRATION FORM
STUDY:BELEWS CREEK STEAM STATION - PINE HALL LANDFILL GROUNDWATER MONITORING
DATE (s):October 26, 2015 SURFACE UNIT READER:PSP
OTHER EQUIPMENT:TURBIDIMETER NO.1 - 3260-GW Cloudy, windy, slight drizzle, 50 to 55 deg F
COLLECTORS:LDC, PSP SURFACE UNIT SERIAL #:S05042
ANALYZER MODEL#:MS5 66120
PROCEDURE #:HYDROLAB 3210.5 VALIDATED BY:
Calibration Date / Time 26-Oct-15 410 27-Oct-15 4:00
CALIBRATION BP (mmHg)748.0 CALIBRATION BP (mmHg)751.3
Parameter Calibration Results Calibration Results
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
Calibration Accepted Calibration Pass
SPEC. COND.
(uS/cm)
Instrument Zeroed Zero Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
pH
(units)
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Buffer Temp.Buffer Temp.
Buffer Temp.
Calibration Accepted Calibration Pass
ORP Temp.ORP Temp.
Calibration Pass
TURB
(ntu)Calibration Accepted Calibration Accepted
DO
(mg/L)Calibration Accepted
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 750.1 (mmHg)Ending BP 752.1
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
37.20 47.20
25 (psi)12 (sec)(sec)
(gal)
1.50 (gal)
@
QC By:
SAMPLING NOTES
Non potable tag missing. Gap between lid and protective casing (allows wasps to enter
and build nest).
ADDITIONAL WELL CONDITION NOTES
Lacks Required Information
WELL CONDITION
PROTECTIVE CASING
WELL PAD
WELL TAG
Good Condition
Good Condition
Good ConditionWELL CASING
LDC N/A
TOTAL PURGE
VOLUME
4.00
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY
1.25 NO
1.25 NO 14.26 19 5.11
19 5.11 10.4
(recalculates on
current water
level)(deg C)(umho/cm)(SU)(NTU)(mV-NHE)(mg/L)
54.0 359 7.69 1.05
SAMPLING EQUIPMENT
TUBING DIAMETER (in)1/2 OD
QED T1200
PURGE COMPLETE TEMP SPECIFIC pH TURBIDITY
WATER ELEVATION (ft msl)814.66
APPEARANCE
DETECTED ODOR None
Normal
WATER LEVEL
AFTER PURGE *
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88
WELL DEPTH (ft TOC)
WELL DIAMETER (in)MIDDLE OF WETTED SCREEN (ft toc)
WELL VOL
SCREEN INTERVAL (ft TOC)TO
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)38.03 WATER COLUMN (ft)9.17
EQUIPMENT INFORMATION
LEVEL METER SERIAL#26056
46.20PUMP INTAKE DEPTH (ft TOC)47.20
TOC ELEV (ft msl)
GS ELEV (ft msl)
852.69
850.55
WELL/LOCATION NAME MW-1
FIELD CREW LDC, PSP
MONITORING WELL INFORMATION
2
N/A
PROCEDURE NO 3175.2DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID
PROJECT NAME PINE HALL LANDFILL
SAMPLING DATE(s)26-Oct-2015
42.62
PURGE METHOD
Conventional
DISCHARGERECHARGEPRESSURE 8
PUMP CONTROLLER SETTINGS
0.1631CONVERSION FACTOR
Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
1.50WELL VOLUME
(gal)
ORP
(ft)(YES/NO)
1.50 40.76 NO 14.19 20 5.22
14.21
VOLUME EVACUATION COND.
10/26/2015 1155
Sample preservation verified to pH
(units)< 2.0
DATE TIME
DISSOLVED
OXYGEN
5.5 426 8.06
8.00409
85.53 90.53
60 (psi)9 (sec)(sec)
(gal)
7.47 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)26-Oct-2015 WELL/LOCATION NAME MW-1D
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)854.15 MIDDLE OF WETTED SCREEN (ft toc)88.03
SCREEN LENGTH (ft)5.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)90.53 GS ELEV (ft msl)850.99 PUMP INTAKE DEPTH (ft TOC)89.50
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 6
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
See note below
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)44.75 WATER COLUMN (ft)45.78 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)809.40 WELL VOLUME 7.47
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
7.50 67.64 NO 14.20 123 6.45 1.6 347
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
4.78 3.73
3.75 NO 14.22 123 6.56 1.6 346 4.75
3.75 NO 14.27 117 6.51 1.9 345 5.09
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
15.00 LDC 10/26/2015 1045 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
After initial well is removed, recalculate well volume for subsequent readings. WL drawdown appears to stabilize around 64 ft.
40.00 50.00
(psi)(sec)(sec)
(gal)
1075 (ml)
495 (ml)
1570 (ml)=0.41 (gal)@
QC By:
SAMPLING NOTES
4/24/12 - Replaced pump and tubing in well and set intake to 49.5 ft (six inches from well bottom). Insufficient volume / recharge to pump.
PROTECTIVE CASING Good Condition Gap between lid and protective casing (allows wasps to enter and build nest).
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
SAMPLE COLLECTED BY DATE TIME
Total Purge Volume LDC 10/26/2015
Sample preservation verified to pH
(units)
N/A
Tubing Volume EQUIPMENT PURGE ONLY SAMPLE CHLORINE
(mg/l)Pump (Bladder) Volume
(ft)(ml/min)(ft)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
WATER LEVEL RATE WATER LEVEL COND.OXYGEN
INITIAL FLOW FINAL TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)47.94 WATER COLUMN (ft)2.06 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)810.11 WELL VOLUME 0.34
No sample - see note PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Equip. Only Purge
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)858.05 MIDDLE OF WETTED SCREEN (ft toc)48.97
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)50.00 GS ELEV (ft msl)855.44 PUMP INTAKE DEPTH (ft TOC)49.50
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)26-Oct-2015 WELL/LOCATION NAME MW-2
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR EQUIPMENT PURGE ONLY SAMPLING
39.50 49.50
25 (psi)14 (sec)(sec)
(gal)
0.92 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition Evacuated 10/26/15 at 1300 hrs. Non potable tag is missing.
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
1.00 LDC 10/26/2015 1305 N/A
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.00 YES 14.06 57 5.88 16.6 392
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
9.18
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)43.87 WATER COLUMN (ft)5.63 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)798.94 WELL VOLUME 0.92
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 6
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)842.81 MIDDLE OF WETTED SCREEN (ft toc)46.69
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)49.50 GS ELEV (ft msl)840.57 PUMP INTAKE DEPTH (ft TOC)48.50
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)26-Oct-2015 WELL/LOCATION NAME MW-3
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
30.20 40.20
22 (psi)10 (sec)(sec)
(gal)
4.51 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
11.75 LDC 10/26/2015 0910 N/A
1.75 NO 14.65 272 5.99 3.7 357 2.25
1.75 NO 14.67 270 6.01 7.4 356 2.40
1.75 NO 14.66 294 6.05 17.2 352 3.16
1.75 NO 14.75 315 6.04 27.5 270 2.64
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
4.75 30.03 NO 14.92 287 6.05 23.9 377
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
3.64 1.66
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)12.56 WATER COLUMN (ft)27.64 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)755.02 WELL VOLUME 4.51
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)767.58 MIDDLE OF WETTED SCREEN (ft toc)35.20
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)40.20 GS ELEV (ft msl)766.10 PUMP INTAKE DEPTH (ft TOC)39.20
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)26-Oct-2015 WELL/LOCATION NAME MW-4
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
50.20 60.20
30 (psi)6 (sec)(sec)
(gal)
5.56 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
12.50 PSP 10/26/2015 1410 N/A
2.25 NO 14.56 35 5.70 6.1 403 6.81
2.25 NO 14.57 35 5.66 7.4 406 6.83
2.25 NO 14.57 35 5.66 21.4 411 6.85
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
5.75 47.41 NO 14.53 37 5.74 20.4 415
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
7.16 2.09
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)26.09 WATER COLUMN (ft)34.11 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)760.68 WELL VOLUME 5.56
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 9
28650 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)786.77 MIDDLE OF WETTED SCREEN (ft toc)55.20
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)60.20 GS ELEV (ft msl)785.39 PUMP INTAKE DEPTH (ft TOC)59.20
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)26-Oct-2015 WELL/LOCATION NAME MW-5
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
26.84 36.84
25 (psi)5 (sec)(sec)
(gal)
(gal)
@
QC By:
SAMPLING NOTES
Could not measure WL - below top of pump.
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
0.00 LDC 10/26/2015 N/A
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR CONVERSION FACTOR 0.1631
APPEARANCE
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
No sample - see note PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)836.91 MIDDLE OF WETTED SCREEN (ft toc)31.84
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)36.84 GS ELEV (ft msl)834.40 PUMP INTAKE DEPTH (ft TOC)35.84
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)26-Oct-2015 WELL/LOCATION NAME MW-6
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
4.26 14.26
20 (psi)10 (sec)(sec)
(gal)
0.92 (gal)
@
QC By:
SAMPLING NOTES
Pump with 20 psi to evacuate the well and turbidity will fall below 10 ntu. Pumping at 20 psi does not reduce turbidity, for last reading pumped an additional 0.50 gallons because
turbidity was at 54.5 NTU's. the additional 0.50 gallons was purged at a setting of 10 psi with the same recharge/discharge settings above.
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
4.00 PSP 10/26/2015 0855 N/A
1.00 NO 17.35 414 5.46 66.1 371 5.30
0.50 NO 17.57 416 5.44 47.0 366 5.34
0.58
0.75 11.26 NO 17.78 421 5.45 21.5 362 5.62 0.49
0.75 10.70 NO 17.85 422 5.43 26.7 359 5.68
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.00 9.95 NO 17.97 424 5.41 28.4 353
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
5.66 0.70
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Turbid
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)8.59 WATER COLUMN (ft)5.67 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)806.98 WELL VOLUME 0.92
See note below PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
28650 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)815.57 MIDDLE OF WETTED SCREEN (ft toc)11.43
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)14.26 GS ELEV (ft msl)812.52 PUMP INTAKE DEPTH (ft TOC)13.26
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)26-Oct-2015 WELL/LOCATION NAME MW-7
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
20.62 30.62
25 (psi)5 (sec)(sec)
(gal)
2.66 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition Well pad covered in dirt, could not inspect well pad.
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
13.75 PSP 10/26/2015 1015 N/A
2.75 NO 15.70 2016 5.21 2.1 390 0.23
2.75 NO 15.69 1995 5.21 2.4 390 0.28
2.75 NO 15.69 1939 5.21 4.1 390 0.39
2.75 NO 15.70 1826 5.19 8.8 390 0.53
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
2.75 NO 15.66 1624 5.14 1.4 396
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
0.13
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)14.31 WATER COLUMN (ft)16.31 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)763.33 WELL VOLUME 2.66
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 7
28650 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)777.64 MIDDLE OF WETTED SCREEN (ft toc)25.62
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)30.62 GS ELEV (ft msl)775.45 PUMP INTAKE DEPTH (ft TOC)29.62
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)26-Oct-2015 WELL/LOCATION NAME MW2-7
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
4.61 14.61
10 (psi)5 (sec)(sec)
(gal)
1.31 (gal)
@
QC By:
SAMPLING NOTES
WL measured 11.06 feet at 1430 hrs on 10/26/15 - 0.58 gal well volume.
PROTECTIVE CASING Good Condition Well pad covered in dirt and grass unable to inspect.
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
2.50 PSP 10/26/2015 1435 N/A
1.00 YES 16.54 277 6.09 7.0 307 2.42
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.50 8.58 NO 17.10 264 5.85 7.0 316
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
2.60 0.98
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)6.59 WATER COLUMN (ft)8.02 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)790.79 WELL VOLUME 1.31
Well evacuated on 10/26/15 @ 0800 HRS PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
28650 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)797.38 MIDDLE OF WETTED SCREEN (ft toc)10.60
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)14.61 GS ELEV (ft msl)794.75 PUMP INTAKE DEPTH (ft TOC)13.61
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)26-Oct-2015 WELL/LOCATION NAME MW2-9
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
15.03 30.03
15 (psi)5 (sec)(sec)
(gal)
1.20 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
3.75 PSP 10/26/2015 1110 N/A
1.25 NO 14.91 2650 7.28 2.6 280 0.78
1.25 NO 14.91 2665 7.27 2.3 288 0.79
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.25 NO 14.93 2676 7.27 2.3 302
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
0.73
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)22.65 WATER COLUMN (ft)7.38 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)754.95 WELL VOLUME 1.20
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
28650 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)777.60 MIDDLE OF WETTED SCREEN (ft toc)26.34
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)30.03 GS ELEV (ft msl)774.72 PUMP INTAKE DEPTH (ft TOC)29.10
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)26-Oct-2015 WELL/LOCATION NAME OB-4
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
21.60 36.60
18 (psi)8 (sec)(sec)
(gal)
1.77 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
6.00 LDC 10/26/2015 0800 N/A
2.00 NO 15.08 30 5.40 4.6 392 5.02
2.00 NO 15.11 30 5.36 5.1 385 4.49
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
2.00 NO 15.13 30 5.32 3.6 398
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
3.99
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)25.73 WATER COLUMN (ft)10.87 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)755.20 WELL VOLUME 1.77
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 7
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)780.93 MIDDLE OF WETTED SCREEN (ft toc)31.17
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)36.60 GS ELEV (ft msl)778.13 PUMP INTAKE DEPTH (ft TOC)35.50
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)26-Oct-2015 WELL/LOCATION NAME OB-5
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
39.17 48.57
25 (psi)10 (sec)(sec)
(gal)
1.71 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)26-Oct-2015 WELL/LOCATION NAME OB-9
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)799.59 MIDDLE OF WETTED SCREEN (ft toc)43.87
SCREEN LENGTH (ft)9.40 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)48.57 GS ELEV (ft msl)797.11 PUMP INTAKE DEPTH (ft TOC)46.00
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
28650 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
1.71
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)38.07 WATER COLUMN (ft)10.50 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)761.52 WELL VOLUME
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.75 NO 14.57 2007 5.13 1.1 374
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
0.18
1.75 NO 14.52 2054 5.06 1.0 295 0.15
1.75 NO 14.52 2067 5.12 1.0 383 0.15
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
5.25 PSP 10/26/2015 1200 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
N/A
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)26-Oct-2015 WELL/LOCATION NAME SW-1A
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)N/A
SCREEN LENGTH (ft)N/A ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)N/A GS ELEV (ft msl)762.27 PUMP INTAKE DEPTH (ft TOC)N/A
Surface Water Location PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
N/A
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)N/A Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)N/A WELL VOLUME
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
PSP 10/26/2015
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 13.54 1437 6.13 2.0
0940
349 5.71
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
N/A
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)26-Oct-2015 WELL/LOCATION NAME SW-2
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)N/A
SCREEN LENGTH (ft)N/A ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)N/A GS ELEV (ft msl)775.30 PUMP INTAKE DEPTH (ft TOC)N/A
Surface Water Location PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
N/A
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)N/A Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)N/A WELL VOLUME
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
PSP 10/26/2015
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 13.81 156 6.32 5.6
1230
295 8.91
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
PERMIT #
MW-1 MW-1D MW-2 MW-3 MW-4 MW-5 MW-6 MW-7 MW2-7 MW2-9 OB-4 OB-5 OB-9 SW-1 SW-2
YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A N/A
SEE NOTE YES SEE NOTE YES YES YES YES YES YES YES YES YES YES N/A N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A N/A
N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
YES YES YES YES YES YES YES YES YES YES YES N/A N/A
NO NO
NORTH CAROLINA GROUNDWATER SAMPLING SITE CHECKLIST
LOCATION / SITE 85-03 SAMPLE DATE October 26, 2015BELEWS CREEK STEAM STATION - PINE HALL LANDFILL GROUNDWATER MONITORING
SITE CONTACT FIELD CREW LDC, PSP
WEATHER Cloudy, windy, slight drizzle, 50 to 55 deg F.
Melonie Martin, Kim Hutchinson
WELL LOCK CONDITION
PAGE 1 OF 1
ACCESS TO WELLS
Access cleared into well
Access cleared around well
Tall grass or weeds - needs mowing
Road washing out / muddy / needs grading
Fallen tree blocking access
WELL SECURITY
Well found locked
Well found unlocked
Undermined / washing out
Lock in good condition
Lock rusted, difficult to open / needs replacing
Replaced damaged lock
WELL CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
CONCRETE PADS
Pad in good condition
Minor cracks
Major cracks / broken / repair required
Replaced damaged well cap
Fire ants around concrete pad
WELL PROTECTIVE CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
Broken hinge on protective lid
Wasp nest inside protective casing
Ants inside protective casing
WELL CAPS
Well cap in good conditon
Damaged / needs replacement
Lacks required information - Completion date
FLUSH MOUNT WELLS
Vault in good condition
Water inside vault
Vault bolt holes broken or stripped
Bolts stripped
Vault lid cracked or broken
WELL ID TAGS
Well tag in good condition
Well tag missing
Well tag damaged / illegible
Lacks required information - Driller Reg #
Lacks required information - Total well depth
Lacks required information - Depth to screen
Lacks required information - Non potable tag
NOTE:MW-1 and MW-3 need non potable tags placed on outside of protective casing. MW-1 and MW-2 have a gap between lid and protective casing. Paul Purnell plans to make these repairs in December 2015.
WELL DEPTH TO WATER Purge AVG *WELL EVAC SPECIFIC
WELL DEPTH WATER ELEV.Method PMP RATE VOL VOL EVAC TEMP CONDUCTANCE pH TURBIDITY ORP DO
DATE NO.(feet-toc)(feet-toc)(feet)APPEARANCE ODOR (ml/min)(gal)(gal)(yes/no)(deg C)(umho/cm)(units)(NTU)(mV-NHE)(mg/l)
10/26/2015 MW-1 47.20 38.03 814.66 Normal None C N/A 1.50 4.00 NO 14.26 19 5.1 5.5 426 8.06
10/26/2015 MW-1D 90.53 44.75 809.40 Normal None C N/A 7.47 15.00 NO 14.22 123 6.6 1.6 346 4.75
10/26/2015 MW-2 50.00 47.94 810.11 0 None EOP N/A 0.34 0.41 N/A 0.00 0 0.0 0.0 0 0.00
10/26/2015 MW-3 49.50 43.87 798.94 Normal None C N/A 0.92 1.00 YES 14.06 57 5.9 16.6 392 9.18
10/26/2015 MW-4 40.20 12.56 755.02 Normal None C N/A 4.51 11.75 NO 14.65 272 6.0 3.7 357 2.25
10/26/2015 MW-5 60.20 26.09 760.68 Normal None C N/A 5.56 12.50 NO 14.56 35 5.7 6.1 403 6.81
10/26/2015 MW-6 36.84 Below Pump ---NS NS NS N/A NS NS NS NS NS NS NS NS NS
10/26/2015 MW-7 14.26 8.59 806.98 Turbid None C N/A 0.92 4.00 NO 17.35 414 5.5 66.1 371 5.30
10/26/2015 MW2-7 30.62 14.31 763.33 Normal None C N/A 2.66 13.75 NO 15.70 2016 5.2 2.1 390 0.23
10/26/2015 MW2-9 14.61 6.59 790.79 Normal None C N/A 1.31 2.50 YES 16.54 277 6.1 7.0 307 2.42
10/26/2015 OB-4 30.03 22.65 754.95 Normal None C N/A 1.20 3.75 NO 14.91 2650 7.3 2.6 280 0.78
10/26/2015 OB-5 36.60 25.73 755.20 Normal None C N/A 1.77 6.00 NO 15.08 30 5.4 4.6 392 5.02
10/26/2015 OB-9 48.57 38.07 761.52 Normal None C N/A 1.71 5.25 NO 14.52 2054 5.1 1.0 295 0.15
10/26/2015 SW-1A N/A N/A N/A Normal None NP N/A N/A N/A N/A 13.54 1437 6.1 2.0 349 5.71
10/26/2015 SW-2 N/A N/A N/A Normal None NP N/A N/A N/A N/A 13.81 156 6.3 5.6 295 8.91
Purge Methods
LF = Low Flow
LF(M) = Low Flow (Mod.)
C = Connventional
NP = No Purge
EOP = Equip. Only Purge
LO = Level Only
NS - Not Sampled / Insufficient Volume
* = Applicable to LF & LF(M) Purging Only
BELEWS CREEK STEAM STATION
PINE HALL LANDFILL
GROUNDWATER MONITORING FIELD DATA
PERMIT #85-03

B
Appendix B
Laboratory Report and
Chain-of-Custody Forms

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J15100188
Project Name:BELEWS - GW PINE HALL LF
Lab Contact:Peggy Kendall
Date:11/9/2015
Customer Address:3195 Pine Hall Rd
Customer Name(s):Chuck Campbell, T. Hunsucker, Ed Sullivan
Mailcode: Belews Steam Station
Belews Creek, NC 28012
Phone:
Report Authorized By:
(Signature)
Program Comments:
Checked history
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Peggy Kendall
Page 1 of 27
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2015032947 BELEWS 26-Oct-15 11:55 AM LDC MW-1
2015032948 BELEWS 26-Oct-15 10:45 AM LDC MW-1D
2015032950 BELEWS 26-Oct-15 1:05 PM LDC MW-3
2015032951 BELEWS 26-Oct-15 9:10 AM LDC MW-4
2015032952 BELEWS 26-Oct-15 2:10 PM PSP MW-5
2015032954 BELEWS 26-Oct-15 8:55 AM PSP MW-7
2015032955 BELEWS 26-Oct-15 10:15 AM PSP MW2-7
2015032956 BELEWS 26-Oct-15 2:35 PM PSP MW2-9
2015032957 BELEWS 26-Oct-15 11:10 AM PSP OB-4
2015032958 BELEWS 26-Oct-15 8:00 AM LDC OB-5
2015032959 BELEWS 26-Oct-15 12:00 PM PSP OB-9
2015032960 BELEWS 26-Oct-15 9:40 AM PSP SW-1A
2015032961 BELEWS 26-Oct-15 12:30 PM PSP SW-2
2015032962 BELEWS 26-Oct-15 2:45 PM LDC FIELD BLANK
14 Total Samples
Page 2 of 27
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By: Date:11/9/2015
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100188
2015032947
Collection Date:26-Oct-15 11:55 AM
Site:MW-1
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B4d 10/28/2015 13:39 GHUTCHI51
INORGANIC IONS BY IC
Chloride 1.6 mg/L EPA 300.0 10/27/2015 14:04 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 10/27/2015 14:04 BGN90340.1 1
Nitrate 1.1 mg/L EPA 300.0 10/27/2015 14:04 BGN90340.1 1
Nitrate as N 0.26 mg-N/L EPA 300.0 10/27/2015 14:04 BGN90340.023 1
Sulfate 1.2 mg/L EPA 300.0 10/27/2015 14:04 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 10/30/2015 09:46 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.020 mg/L EPA 200.7 10/28/2015 10:00 FCJORDA0.005 1
Beryllium (Be)< 0.005 mg/L EPA 200.7 10/28/2015 10:00 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 10/28/2015 10:00 FCJORDA0.05 1
Calcium (Ca)0.149 mg/L EPA 200.7 10/28/2015 10:00 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 10/28/2015 10:00 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 10/28/2015 10:00 FCJORDA0.005 1
Iron (Fe)0.161 mg/L EPA 200.7 10/28/2015 10:00 FCJORDA0.01 1
Magnesium (Mg)0.289 mg/L EPA 200.7 10/28/2015 10:00 FCJORDA0.005 1
Manganese (Mn)0.028 mg/L EPA 200.7 10/28/2015 10:00 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 10/28/2015 10:00 FCJORDA0.005 1
Potassium (K)0.540 mg/L EPA 200.7 10/28/2015 10:00 FCJORDA0.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 10/28/2015 10:00 FCJORDA0.005 1
Sodium (Na)1.65 mg/L EPA 200.7 10/28/2015 10:00 FCJORDA0.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 10/28/2015 10:00 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)1.14 ug/L SW 6020A 10/29/2015 12:28 JAHERMA11
Arsenic (As)< 1 ug/L SW 6020A 10/29/2015 12:28 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020A 10/29/2015 12:28 JAHERMA11
Cobalt (Co)< 1 ug/L SW 6020A 10/29/2015 12:28 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020A 10/29/2015 12:28 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020A 10/29/2015 12:28 JAHERMA11
Thallium (Tl) Low Level 0.206 ug/L SW 6020A 10/29/2015 12:28 JAHERMA0.2 1
Vanadium (V)< 1 ug/L SW 6020A 10/29/2015 12:28 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 39 mg/L SM2540C 10/27/2015 14:39 CJELLIO251
Page 4 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100188
2015032948
Collection Date:26-Oct-15 10:45 AM
Site:MW-1D
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)40 mg/L
(CaCO3)
SM2320B 10/28/2015 11:17 TJA7067201
INORGANIC IONS BY IC
Chloride 8.3 mg/L EPA 300.0 10/27/2015 14:58 BGN90340.1 1
Fluoride 0.14 mg/L EPA 300.0 10/27/2015 14:58 BGN90340.1 1
Nitrate 8.3 mg/L EPA 300.0 10/27/2015 14:58 BGN90340.1 1
Nitrate as N 1.9 mg-N/L EPA 300.0 10/27/2015 14:58 BGN90340.023 1
Sulfate 0.97 mg/L EPA 300.0 10/27/2015 14:58 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 10/30/2015 09:48 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.012 mg/L EPA 200.7 10/28/2015 10:12 FCJORDA0.005 1
Beryllium (Be)0.010 mg/L EPA 200.7 10/28/2015 10:12 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 10/28/2015 10:12 FCJORDA0.05 1
Calcium (Ca)5.67 mg/L EPA 200.7 10/28/2015 10:12 FCJORDA0.01 1
Chromium (Cr)0.010 mg/L EPA 200.7 10/28/2015 10:12 FCJORDA0.005 1
Copper (Cu)0.009 mg/L EPA 200.7 10/28/2015 10:12 FCJORDA0.005 1
Iron (Fe)0.021 mg/L EPA 200.7 10/28/2015 10:12 FCJORDA0.01 1
Magnesium (Mg)5.26 mg/L EPA 200.7 10/28/2015 10:12 FCJORDA0.005 1
Manganese (Mn)0.016 mg/L EPA 200.7 10/28/2015 10:12 FCJORDA0.005 1
Nickel (Ni)0.009 mg/L EPA 200.7 10/28/2015 10:12 FCJORDA0.005 1
Potassium (K)1.90 mg/L EPA 200.7 10/28/2015 10:12 FCJORDA0.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 10/28/2015 10:12 FCJORDA0.005 1
Sodium (Na)9.47 mg/L EPA 200.7 10/28/2015 10:12 FCJORDA0.05 1
Zinc (Zn)0.012 mg/L EPA 200.7 10/28/2015 10:12 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)1.09 ug/L SW 6020A 10/29/2015 12:07 JAHERMA11
Arsenic (As)< 1 ug/L SW 6020A 10/29/2015 12:07 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020A 10/29/2015 12:07 JAHERMA11
Cobalt (Co)< 1 ug/L SW 6020A 10/29/2015 12:07 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020A 10/29/2015 12:07 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020A 10/29/2015 12:07 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L SW 6020A 10/29/2015 12:07 JAHERMA0.2 1
Vanadium (V)< 1 ug/L SW 6020A 10/29/2015 12:07 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 98 mg/L SM2540C 10/27/2015 14:39 CJELLIO251
Page 5 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100188
2015032950
Collection Date:26-Oct-15 1:05 PM
Site:MW-3
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)9.1 mg/L
(CaCO3)
SM 2320B4d 10/28/2015 13:39 GHUTCHI51
INORGANIC IONS BY IC
Chloride 9.1 mg/L EPA 300.0 10/27/2015 15:51 BGN90340.2 2
Fluoride < 0.1 mg/L EPA 300.0 10/27/2015 15:51 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 300.0 10/27/2015 15:51 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 10/27/2015 15:51 BGN90340.023 1
Sulfate 0.33 mg/L EPA 300.0 10/27/2015 15:51 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 10/30/2015 09:51 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.058 mg/L EPA 200.7 10/28/2015 10:16 FCJORDA0.005 1
Beryllium (Be)< 0.005 mg/L EPA 200.7 10/28/2015 10:16 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 10/28/2015 10:16 FCJORDA0.05 1
Calcium (Ca)3.77 mg/L EPA 200.7 10/28/2015 10:16 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 10/28/2015 10:16 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 10/28/2015 10:16 FCJORDA0.005 1
Iron (Fe)0.991 mg/L EPA 200.7 10/28/2015 10:16 FCJORDA0.01 1
Magnesium (Mg)1.35 mg/L EPA 200.7 10/28/2015 10:16 FCJORDA0.005 1
Manganese (Mn)0.017 mg/L EPA 200.7 10/28/2015 10:16 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 10/28/2015 10:16 FCJORDA0.005 1
Potassium (K)2.40 mg/L EPA 200.7 10/28/2015 10:16 FCJORDA0.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 10/28/2015 10:16 FCJORDA0.005 1
Sodium (Na)2.99 mg/L EPA 200.7 10/28/2015 10:16 FCJORDA0.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 10/28/2015 10:16 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)1.12 ug/L SW 6020A 10/29/2015 12:35 JAHERMA11
Arsenic (As)< 1 ug/L SW 6020A 10/29/2015 12:35 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020A 10/29/2015 12:35 JAHERMA11
Cobalt (Co)< 1 ug/L SW 6020A 10/29/2015 12:35 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020A 10/29/2015 12:35 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020A 10/29/2015 12:35 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L SW 6020A 10/29/2015 12:35 JAHERMA0.2 1
Vanadium (V)2.09 ug/L SW 6020A 10/29/2015 12:35 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 58 mg/L SM2540C 10/27/2015 14:39 CJELLIO251
Page 6 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100188
2015032951
Collection Date:26-Oct-15 9:10 AM
Site:MW-4
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)34 mg/L
(CaCO3)
SM2320B 10/28/2015 11:17 TJA7067201
INORGANIC IONS BY IC
Chloride 2.6 mg/L EPA 300.0 10/27/2015 17:39 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 10/27/2015 17:39 BGN90340.1 1
Nitrate 4.2 mg/L EPA 300.0 10/27/2015 17:39 BGN90340.1 1
Nitrate as N 0.94 mg-N/L EPA 300.0 10/27/2015 17:39 BGN90340.023 1
Sulfate 89 mg/L EPA 300.0 10/27/2015 17:39 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 10/30/2015 09:53 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L EPA 200.7 10/28/2015 10:19 FCJORDA0.005 1
Beryllium (Be)< 0.005 mg/L EPA 200.7 10/28/2015 10:19 FCJORDA0.005 1
Boron (B)0.685 mg/L EPA 200.7 10/28/2015 10:19 FCJORDA0.05 1
Calcium (Ca)22.4 mg/L EPA 200.7 10/28/2015 10:19 FCJORDA0.01 1
Chromium (Cr)0.013 mg/L EPA 200.7 10/28/2015 10:19 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 10/28/2015 10:19 FCJORDA0.005 1
Iron (Fe)0.123 mg/L EPA 200.7 10/28/2015 10:19 FCJORDA0.01 1
Magnesium (Mg)12.8 mg/L EPA 200.7 10/28/2015 10:19 FCJORDA0.005 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 10/28/2015 10:19 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 10/28/2015 10:19 FCJORDA0.005 1
Potassium (K)1.21 mg/L EPA 200.7 10/28/2015 10:19 FCJORDA0.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 10/28/2015 10:19 FCJORDA0.005 1
Sodium (Na)8.11 mg/L EPA 200.7 10/28/2015 10:19 FCJORDA0.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 10/28/2015 10:19 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)1.17 ug/L SW 6020A 10/29/2015 12:41 JAHERMA11
Arsenic (As)< 1 ug/L SW 6020A 10/29/2015 12:41 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020A 10/29/2015 12:41 JAHERMA11
Cobalt (Co)< 1 ug/L SW 6020A 10/29/2015 12:41 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020A 10/29/2015 12:41 JAHERMA11
Selenium (Se)17.7 ug/L SW 6020A 10/29/2015 12:41 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L SW 6020A 10/29/2015 12:41 JAHERMA0.2 1
Vanadium (V)2.01 ug/L SW 6020A 10/29/2015 12:41 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 210 mg/L SM2540C 10/27/2015 14:39 CJELLIO251
Page 7 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100188
2015032952
Collection Date:26-Oct-15 2:10 PM
Site:MW-5
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)11 mg/L
(CaCO3)
SM 2320B4d 10/28/2015 13:39 GHUTCHI51
INORGANIC IONS BY IC
Chloride 2.0 mg/L EPA 300.0 10/27/2015 15:16 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 10/27/2015 15:16 BGN90340.1 1
Nitrate 2.9 mg/L EPA 300.0 10/27/2015 15:16 BGN90340.1 1
Nitrate as N 0.65 mg-N/L EPA 300.0 10/27/2015 15:16 BGN90340.023 1
Sulfate 0.15 mg/L EPA 300.0 10/27/2015 15:16 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 10/30/2015 09:55 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.036 mg/L EPA 200.7 10/28/2015 10:23 FCJORDA0.005 1
Beryllium (Be)< 0.005 mg/L EPA 200.7 10/28/2015 10:23 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 10/28/2015 10:23 FCJORDA0.05 1
Calcium (Ca)1.63 mg/L EPA 200.7 10/28/2015 10:23 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 10/28/2015 10:23 FCJORDA0.005 1
Copper (Cu)0.092 mg/L EPA 200.7 10/28/2015 10:23 FCJORDA0.005 1
Iron (Fe)0.514 mg/L EPA 200.7 10/28/2015 10:23 FCJORDA0.01 1
Magnesium (Mg)0.655 mg/L EPA 200.7 10/28/2015 10:23 FCJORDA0.005 1
Manganese (Mn)0.014 mg/L EPA 200.7 10/28/2015 10:23 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 10/28/2015 10:23 FCJORDA0.005 1
Potassium (K)2.61 mg/L EPA 200.7 10/28/2015 10:23 FCJORDA0.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 10/28/2015 10:23 FCJORDA0.005 1
Sodium (Na)3.74 mg/L EPA 200.7 10/28/2015 10:23 FCJORDA0.05 1
Zinc (Zn)0.051 mg/L EPA 200.7 10/28/2015 10:23 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020A 10/29/2015 12:48 JAHERMA11
Arsenic (As)< 1 ug/L SW 6020A 10/29/2015 12:48 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020A 10/29/2015 12:48 JAHERMA11
Cobalt (Co)< 1 ug/L SW 6020A 10/29/2015 12:48 JAHERMA11
Lead (Pb)9.94 ug/L SW 6020A 10/29/2015 12:48 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020A 10/29/2015 12:48 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L SW 6020A 10/29/2015 12:48 JAHERMA0.2 1
Vanadium (V)1.19 ug/L SW 6020A 10/29/2015 12:48 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 56 mg/L SM2540C 10/27/2015 14:39 CJELLIO251
Page 8 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100188
2015032954
Collection Date:26-Oct-15 8:55 AM
Site:MW-7
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)9.8 mg/L
(CaCO3)
SM 2320B4d 10/28/2015 13:39 GHUTCHI51
INORGANIC IONS BY IC
Chloride 8.8 mg/L EPA 300.0 10/27/2015 18:51 BGN90340.2 2
Fluoride < 0.2 mg/L EPA 300.0 10/27/2015 18:51 BGN90340.2 2
Nitrate 17 mg/L EPA 300.0 10/27/2015 18:51 BGN90340.5 5
Nitrate as N 3.9 mg-N/L EPA 300.0 10/27/2015 18:51 BGN90340.023 1
Sulfate 170 mg/L EPA 300.0 10/27/2015 18:51 BGN90342.5 25
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)0.05 ug/L EPA 245.1 10/30/2015 09:58 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.046 mg/L EPA 200.7 10/28/2015 10:27 FCJORDA0.005 1
Beryllium (Be)< 0.005 mg/L EPA 200.7 10/28/2015 10:27 FCJORDA0.005 1
Boron (B)2.93 mg/L EPA 200.7 10/28/2015 10:27 FCJORDA0.05 1
Calcium (Ca)34.7 mg/L EPA 200.7 10/28/2015 10:27 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 10/28/2015 10:27 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 10/28/2015 10:27 FCJORDA0.005 1
Iron (Fe)2.72 mg/L EPA 200.7 10/28/2015 10:27 FCJORDA0.01 1
Magnesium (Mg)16.2 mg/L EPA 200.7 10/28/2015 10:27 FCJORDA0.005 1
Manganese (Mn)0.062 mg/L EPA 200.7 10/28/2015 10:27 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 10/28/2015 10:27 FCJORDA0.005 1
Potassium (K)3.54 mg/L EPA 200.7 10/28/2015 10:27 FCJORDA0.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 10/28/2015 10:27 FCJORDA0.005 1
Sodium (Na)17.8 mg/L EPA 200.7 10/28/2015 10:27 FCJORDA0.05 1
Zinc (Zn)0.017 mg/L EPA 200.7 10/28/2015 10:27 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020A 10/29/2015 12:55 JAHERMA11
Arsenic (As)< 1 ug/L SW 6020A 10/29/2015 12:55 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020A 10/29/2015 12:55 JAHERMA11
Cobalt (Co)< 1 ug/L SW 6020A 10/29/2015 12:55 JAHERMA11
Lead (Pb)1.34 ug/L SW 6020A 10/29/2015 12:55 JAHERMA11
Selenium (Se)25.0 ug/L SW 6020A 10/29/2015 12:55 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L SW 6020A 10/29/2015 12:55 JAHERMA0.2 1
Vanadium (V)2.52 ug/L SW 6020A 10/29/2015 12:55 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 340 mg/L SM2540C 10/27/2015 14:39 CJELLIO251
Page 9 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100188
2015032955
Collection Date:26-Oct-15 10:15 AM
Site:MW2-7
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)17 mg/L
(CaCO3)
SM 2320B4d 10/28/2015 13:39 GHUTCHI51
INORGANIC IONS BY IC
Chloride 13 mg/L EPA 300.0 10/27/2015 19:08 BGN9034110
Fluoride < 1 mg/L EPA 300.0 10/27/2015 19:08 BGN9034110
Nitrate 88 mg/L EPA 300.0 10/27/2015 19:08 BGN90342.5 25
Nitrate as N 20 mg-N/L EPA 300.0 10/27/2015 19:08 BGN90340.023 1
Sulfate 1200 mg/L EPA 300.0 10/27/2015 19:08 BGN903420200
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)0.12 ug/L EPA 245.1 10/30/2015 10:00 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.028 mg/L EPA 200.7 10/28/2015 10:31 FCJORDA0.005 1
Beryllium (Be)< 0.005 mg/L EPA 200.7 10/28/2015 10:31 FCJORDA0.005 1
Boron (B)21.2 mg/L EPA 200.7 10/28/2015 10:31 FCJORDA0.05 1
Calcium (Ca)238 mg/L EPA 200.7 10/28/2015 10:31 FCJORDA0.1 10
Chromium (Cr)< 0.005 mg/L EPA 200.7 10/28/2015 10:31 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 10/28/2015 10:31 FCJORDA0.005 1
Iron (Fe)0.065 mg/L EPA 200.7 10/28/2015 10:31 FCJORDA0.01 1
Magnesium (Mg)118 mg/L EPA 200.7 10/28/2015 10:31 FCJORDA0.05 10
Manganese (Mn)0.416 mg/L EPA 200.7 10/28/2015 10:31 FCJORDA0.005 1
Nickel (Ni)0.010 mg/L EPA 200.7 10/28/2015 10:31 FCJORDA0.005 1
Potassium (K)4.04 mg/L EPA 200.7 10/28/2015 10:31 FCJORDA0.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 10/28/2015 10:31 FCJORDA0.005 1
Sodium (Na)74.4 mg/L EPA 200.7 10/28/2015 10:31 FCJORDA0.05 1
Zinc (Zn)0.017 mg/L EPA 200.7 10/28/2015 10:31 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020A 10/29/2015 13:02 JAHERMA11
Arsenic (As)1.12 ug/L SW 6020A 10/29/2015 13:02 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020A 10/29/2015 13:02 JAHERMA11
Cobalt (Co)< 1 ug/L SW 6020A 10/29/2015 13:02 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020A 10/29/2015 13:02 JAHERMA11
Selenium (Se)166 ug/L SW 6020A 10/29/2015 13:02 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L SW 6020A 10/29/2015 13:02 JAHERMA0.2 1
Vanadium (V)< 1 ug/L SW 6020A 10/29/2015 13:02 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 1800 mg/L SM2540C 10/27/2015 14:39 CJELLIO251
Page 10 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100188
2015032956
Collection Date:26-Oct-15 2:35 PM
Site:MW2-9
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)82 mg/L
(CaCO3)
SM2320B 10/28/2015 11:17 TJA7067201
INORGANIC IONS BY IC
Chloride 5.1 mg/L EPA 300.0 10/27/2015 18:33 BGN90340.1 1
Fluoride 0.14 mg/L EPA 300.0 10/27/2015 18:33 BGN90340.1 1
Nitrate 3.1 mg/L EPA 300.0 10/27/2015 18:33 BGN90340.1 1
Nitrate as N 0.71 mg-N/L EPA 300.0 10/27/2015 18:33 BGN90340.023 1
Sulfate 43 mg/L EPA 300.0 10/27/2015 18:33 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 10/30/2015 10:03 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.064 mg/L EPA 200.7 10/28/2015 10:35 FCJORDA0.005 1
Beryllium (Be)< 0.005 mg/L EPA 200.7 10/28/2015 10:35 FCJORDA0.005 1
Boron (B)0.286 mg/L EPA 200.7 10/28/2015 10:35 FCJORDA0.05 1
Calcium (Ca)21.0 mg/L EPA 200.7 10/28/2015 10:35 FCJORDA0.01 1
Chromium (Cr)0.018 mg/L EPA 200.7 10/28/2015 10:35 FCJORDA0.005 1
Copper (Cu)0.005 mg/L EPA 200.7 10/28/2015 10:35 FCJORDA0.005 1
Iron (Fe)3.13 mg/L EPA 200.7 10/28/2015 10:35 FCJORDA0.01 1
Magnesium (Mg)8.37 mg/L EPA 200.7 10/28/2015 10:35 FCJORDA0.005 1
Manganese (Mn)0.469 mg/L EPA 200.7 10/28/2015 10:35 FCJORDA0.005 1
Nickel (Ni)0.014 mg/L EPA 200.7 10/28/2015 10:35 FCJORDA0.005 1
Potassium (K)6.38 mg/L EPA 200.7 10/28/2015 10:35 FCJORDA0.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 10/28/2015 10:35 FCJORDA0.005 1
Sodium (Na)19.4 mg/L EPA 200.7 10/28/2015 10:35 FCJORDA0.05 1
Zinc (Zn)0.005 mg/L EPA 200.7 10/28/2015 10:35 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)1.71 ug/L SW 6020A 10/29/2015 13:09 JAHERMA11
Arsenic (As)< 1 ug/L SW 6020A 10/29/2015 13:09 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020A 10/29/2015 13:09 JAHERMA11
Cobalt (Co)1.92 ug/L SW 6020A 10/29/2015 13:09 JAHERMA11
Lead (Pb)1.03 ug/L SW 6020A 10/29/2015 13:09 JAHERMA11
Selenium (Se)1.38 ug/L SW 6020A 10/29/2015 13:09 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L SW 6020A 10/29/2015 13:09 JAHERMA0.2 1
Vanadium (V)2.92 ug/L SW 6020A 10/29/2015 13:09 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 200 mg/L SM2540C 10/27/2015 14:39 CJELLIO251
Page 11 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100188
2015032957
Collection Date:26-Oct-15 11:10 AM
Site:OB-4
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)270 mg/L
(CaCO3)
SM2320B 10/28/2015 11:17 TJA7067201
INORGANIC IONS BY IC
Chloride 9.3 mg/L EPA 300.0 10/27/2015 19:26 BGN9034110
Fluoride < 1 mg/L EPA 300.0 10/27/2015 19:26 BGN9034110
Nitrate 19 mg/L EPA 300.0 10/27/2015 19:26 BGN9034110
Nitrate as N 4.4 mg-N/L EPA 300.0 10/27/2015 19:26 BGN90340.023 1
Sulfate 1500 mg/L EPA 300.0 10/27/2015 19:26 BGN903450500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 10/30/2015 10:05 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.035 mg/L EPA 200.7 10/28/2015 10:39 FCJORDA0.005 1
Beryllium (Be)< 0.005 mg/L EPA 200.7 10/28/2015 10:39 FCJORDA0.005 1
Boron (B)18.0 mg/L EPA 200.7 10/28/2015 10:39 FCJORDA0.05 1
Calcium (Ca)603 mg/L EPA 200.7 10/28/2015 10:39 FCJORDA0.1 10
Chromium (Cr)< 0.005 mg/L EPA 200.7 10/28/2015 10:39 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 10/28/2015 10:39 FCJORDA0.005 1
Iron (Fe)0.077 mg/L EPA 200.7 10/28/2015 10:39 FCJORDA0.01 1
Magnesium (Mg)51.6 mg/L EPA 200.7 10/28/2015 10:39 FCJORDA0.05 10
Manganese (Mn)0.139 mg/L EPA 200.7 10/28/2015 10:39 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 10/28/2015 10:39 FCJORDA0.005 1
Potassium (K)47.1 mg/L EPA 200.7 10/28/2015 10:39 FCJORDA110
Silver (Ag)< 0.005 mg/L EPA 200.7 10/28/2015 10:39 FCJORDA0.005 1
Sodium (Na)10.3 mg/L EPA 200.7 10/28/2015 10:39 FCJORDA0.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 10/28/2015 10:39 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)26.7 ug/L SW 6020A 10/29/2015 13:16 JAHERMA11
Arsenic (As)34.8 ug/L SW 6020A 10/29/2015 13:16 JAHERMA11
Cadmium (Cd)2.69 ug/L SW 6020A 10/29/2015 13:16 JAHERMA11
Cobalt (Co)1.24 ug/L SW 6020A 10/29/2015 13:16 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020A 10/29/2015 13:16 JAHERMA11
Selenium (Se)119 ug/L SW 6020A 10/29/2015 13:16 JAHERMA11
Thallium (Tl) Low Level 8.93 ug/L SW 6020A 10/29/2015 13:16 JAHERMA0.2 1
Vanadium (V)203 ug/L SW 6020A 10/29/2015 13:16 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 2600 mg/L SM2540C 10/27/2015 14:39 CJELLIO501
Page 12 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100188
2015032958
Collection Date:26-Oct-15 8:00 AM
Site:OB-5
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)5.6 mg/L
(CaCO3)
SM 2320B4d 10/28/2015 13:39 GHUTCHI51
INORGANIC IONS BY IC
Chloride 3.4 mg/L EPA 300.0 10/27/2015 20:38 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 10/27/2015 20:38 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 300.0 10/27/2015 20:38 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 10/27/2015 20:38 BGN90340.023 1
Sulfate 0.19 mg/L EPA 300.0 10/27/2015 20:38 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 10/30/2015 10:12 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.110 mg/L EPA 200.7 10/28/2015 10:47 FCJORDA0.005 1
Beryllium (Be)< 0.005 mg/L EPA 200.7 10/28/2015 10:47 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 10/28/2015 10:47 FCJORDA0.05 1
Calcium (Ca)1.56 mg/L EPA 200.7 10/28/2015 10:47 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 10/28/2015 10:47 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 10/28/2015 10:47 FCJORDA0.005 1
Iron (Fe)0.190 mg/L EPA 200.7 10/28/2015 10:47 FCJORDA0.01 1
Magnesium (Mg)0.578 mg/L EPA 200.7 10/28/2015 10:47 FCJORDA0.005 1
Manganese (Mn)0.008 mg/L EPA 200.7 10/28/2015 10:47 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 10/28/2015 10:47 FCJORDA0.005 1
Potassium (K)2.62 mg/L EPA 200.7 10/28/2015 10:47 FCJORDA0.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 10/28/2015 10:47 FCJORDA0.005 1
Sodium (Na)1.89 mg/L EPA 200.7 10/28/2015 10:47 FCJORDA0.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 10/28/2015 10:47 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)1.21 ug/L SW 6020A 10/29/2015 13:23 JAHERMA11
Arsenic (As)< 1 ug/L SW 6020A 10/29/2015 13:23 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020A 10/29/2015 13:23 JAHERMA11
Cobalt (Co)< 1 ug/L SW 6020A 10/29/2015 13:23 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020A 10/29/2015 13:23 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020A 10/29/2015 13:23 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L SW 6020A 10/29/2015 13:23 JAHERMA0.2 1
Vanadium (V)< 1 ug/L SW 6020A 10/29/2015 13:23 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 30 mg/L SM2540C 10/27/2015 14:39 CJELLIO251
Page 13 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100188
2015032959
Collection Date:26-Oct-15 12:00 PM
Site:OB-9
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)7.8 mg/L
(CaCO3)
SM 2320B4d 10/28/2015 13:39 GHUTCHI51
INORGANIC IONS BY IC
Chloride 11 mg/L EPA 300.0 10/27/2015 23:01 BGN9034110
Fluoride < 1 mg/L EPA 300.0 10/27/2015 23:01 BGN9034110
Nitrate 25 mg/L EPA 300.0 10/27/2015 23:01 BGN9034110
Nitrate as N 5.6 mg-N/L EPA 300.0 10/27/2015 23:01 BGN90340.023 1
Sulfate 1200 mg/L EPA 300.0 10/27/2015 23:01 BGN903420200
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)0.22 ug/L EPA 245.1 10/30/2015 10:19 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.018 mg/L EPA 200.7 10/28/2015 11:03 FCJORDA0.005 1
Beryllium (Be)< 0.005 mg/L EPA 200.7 10/28/2015 11:03 FCJORDA0.005 1
Boron (B)31.1 mg/L EPA 200.7 10/28/2015 11:03 FCJORDA0.05 1
Calcium (Ca)238 mg/L EPA 200.7 10/28/2015 11:03 FCJORDA0.1 10
Chromium (Cr)< 0.005 mg/L EPA 200.7 10/28/2015 11:03 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 10/28/2015 11:03 FCJORDA0.005 1
Iron (Fe)< 0.01 mg/L EPA 200.7 10/28/2015 11:03 FCJORDA0.01 1
Magnesium (Mg)104 mg/L EPA 200.7 10/28/2015 11:03 FCJORDA0.05 10
Manganese (Mn)2.95 mg/L EPA 200.7 10/28/2015 11:03 FCJORDA0.005 1
Nickel (Ni)0.013 mg/L EPA 200.7 10/28/2015 11:03 FCJORDA0.005 1
Potassium (K)9.32 mg/L EPA 200.7 10/28/2015 11:03 FCJORDA0.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 10/28/2015 11:03 FCJORDA0.005 1
Sodium (Na)117 mg/L EPA 200.7 10/28/2015 11:03 FCJORDA0.05 1
Zinc (Zn)0.074 mg/L EPA 200.7 10/28/2015 11:03 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020A 10/29/2015 13:44 JAHERMA11
Arsenic (As)1.94 ug/L SW 6020A 10/29/2015 13:44 JAHERMA11
Cadmium (Cd)4.01 ug/L SW 6020A 10/29/2015 13:44 JAHERMA11
Cobalt (Co)< 1 ug/L SW 6020A 10/29/2015 13:44 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020A 10/29/2015 13:44 JAHERMA11
Selenium (Se)318 ug/L SW 6020A 10/29/2015 13:44 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L SW 6020A 10/29/2015 13:44 JAHERMA0.2 1
Vanadium (V)< 1 ug/L SW 6020A 10/29/2015 13:44 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 1900 mg/L SM2540C 10/27/2015 14:39 CJELLIO251
Page 14 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100188
2015032960
Collection Date:26-Oct-15 9:40 AM
Site:SW-1A
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)41 mg/L
(CaCO3)
SM2320B 10/28/2015 11:17 TJA7067201
INORGANIC IONS BY IC
Chloride 11 mg/L EPA 300.0 10/28/2015 07:31 BGN9034110
Fluoride < 0.1 mg/L EPA 300.0 10/28/2015 07:31 BGN90340.1 1
Nitrate 77 mg/L EPA 300.0 10/28/2015 07:31 BGN9034110
Nitrate as N 17 mg-N/L EPA 300.0 10/28/2015 07:31 BGN90340.023 1
Sulfate 740 mg/L EPA 300.0 10/28/2015 07:31 BGN903410100
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 10/30/2015 10:21 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.066 mg/L EPA 200.7 10/28/2015 11:07 FCJORDA0.005 1
Beryllium (Be)< 0.005 mg/L EPA 200.7 10/28/2015 11:07 FCJORDA0.005 1
Boron (B)13.8 mg/L EPA 200.7 10/28/2015 11:07 FCJORDA0.05 1
Calcium (Ca)150 mg/L EPA 200.7 10/28/2015 11:07 FCJORDA0.1 10
Chromium (Cr)< 0.005 mg/L EPA 200.7 10/28/2015 11:07 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 10/28/2015 11:07 FCJORDA0.005 1
Iron (Fe)0.017 mg/L EPA 200.7 10/28/2015 11:07 FCJORDA0.01 1
Magnesium (Mg)70.1 mg/L EPA 200.7 10/28/2015 11:07 FCJORDA0.05 10
Manganese (Mn)0.246 mg/L EPA 200.7 10/28/2015 11:07 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 10/28/2015 11:07 FCJORDA0.005 1
Potassium (K)5.39 mg/L EPA 200.7 10/28/2015 11:07 FCJORDA0.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 10/28/2015 11:07 FCJORDA0.005 1
Sodium (Na)50.1 mg/L EPA 200.7 10/28/2015 11:07 FCJORDA0.05 1
Zinc (Zn)0.006 mg/L EPA 200.7 10/28/2015 11:07 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020A 10/29/2015 13:51 JAHERMA11
Arsenic (As)< 1 ug/L SW 6020A 10/29/2015 13:51 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020A 10/29/2015 13:51 JAHERMA11
Cobalt (Co)< 1 ug/L SW 6020A 10/29/2015 13:51 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020A 10/29/2015 13:51 JAHERMA11
Selenium (Se)80.4 ug/L SW 6020A 10/29/2015 13:51 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L SW 6020A 10/29/2015 13:51 JAHERMA0.2 1
Vanadium (V)< 1 ug/L SW 6020A 10/29/2015 13:51 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 1300 mg/L SM2540C 10/27/2015 14:39 CJELLIO251
Page 15 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100188
2015032961
Collection Date:26-Oct-15 12:30 PM
Site:SW-2
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)12 mg/L
(CaCO3)
SM 2320B4d 10/28/2015 13:39 GHUTCHI51
INORGANIC IONS BY IC
Chloride 5.0 mg/L EPA 300.0 10/27/2015 22:43 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 10/27/2015 22:43 BGN90340.1 1
Nitrate 2.2 mg/L EPA 300.0 10/27/2015 22:43 BGN90340.1 1
Nitrate as N 0.49 mg-N/L EPA 300.0 10/27/2015 22:43 BGN90340.023 1
Sulfate 47 mg/L EPA 300.0 10/27/2015 22:43 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 10/30/2015 10:24 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.028 mg/L EPA 200.7 10/28/2015 11:11 FCJORDA0.005 1
Beryllium (Be)< 0.005 mg/L EPA 200.7 10/28/2015 11:11 FCJORDA0.005 1
Boron (B)1.42 mg/L EPA 200.7 10/28/2015 11:11 FCJORDA0.05 1
Calcium (Ca)7.72 mg/L EPA 200.7 10/28/2015 11:11 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 10/28/2015 11:11 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 10/28/2015 11:11 FCJORDA0.005 1
Iron (Fe)0.240 mg/L EPA 200.7 10/28/2015 11:11 FCJORDA0.01 1
Magnesium (Mg)5.76 mg/L EPA 200.7 10/28/2015 11:11 FCJORDA0.005 1
Manganese (Mn)0.034 mg/L EPA 200.7 10/28/2015 11:11 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 10/28/2015 11:11 FCJORDA0.005 1
Potassium (K)2.07 mg/L EPA 200.7 10/28/2015 11:11 FCJORDA0.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 10/28/2015 11:11 FCJORDA0.005 1
Sodium (Na)11.0 mg/L EPA 200.7 10/28/2015 11:11 FCJORDA0.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 10/28/2015 11:11 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020A 10/29/2015 13:58 JAHERMA11
Arsenic (As)< 1 ug/L SW 6020A 10/29/2015 13:58 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020A 10/29/2015 13:58 JAHERMA11
Cobalt (Co)< 1 ug/L SW 6020A 10/29/2015 13:58 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020A 10/29/2015 13:58 JAHERMA11
Selenium (Se)7.96 ug/L SW 6020A 10/29/2015 13:58 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L SW 6020A 10/29/2015 13:58 JAHERMA0.2 1
Vanadium (V)< 1 ug/L SW 6020A 10/29/2015 13:58 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 130 mg/L SM2540C 10/27/2015 14:39 CJELLIO251
Page 16 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100188
2015032962
Collection Date:26-Oct-15 2:45 PM
Site:FIELD BLANK
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)< 20 mg/L
(CaCO3)
SM2320B 10/28/2015 11:17 TJA7067201
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 10/27/2015 13:46 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 10/27/2015 13:46 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 300.0 10/27/2015 13:46 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 10/27/2015 13:46 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 300.0 10/27/2015 13:46 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 10/30/2015 10:26 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L EPA 200.7 10/28/2015 11:15 FCJORDA0.005 1
Beryllium (Be)< 0.005 mg/L EPA 200.7 10/28/2015 11:15 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 10/28/2015 11:15 FCJORDA0.05 1
Calcium (Ca)0.014 mg/L EPA 200.7 10/28/2015 11:15 FCJORDA0.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 10/28/2015 11:15 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 10/28/2015 11:15 FCJORDA0.005 1
Iron (Fe)< 0.01 mg/L EPA 200.7 10/28/2015 11:15 FCJORDA0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 10/28/2015 11:15 FCJORDA0.005 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 10/28/2015 11:15 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 10/28/2015 11:15 FCJORDA0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 10/28/2015 11:15 FCJORDA0.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 10/28/2015 11:15 FCJORDA0.005 1
Sodium (Na)< 0.05 mg/L EPA 200.7 10/28/2015 11:15 FCJORDA0.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 10/28/2015 11:15 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020A 10/29/2015 14:05 JAHERMA11
Arsenic (As)< 1 ug/L SW 6020A 10/29/2015 14:05 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020A 10/29/2015 14:05 JAHERMA11
Cobalt (Co)< 1 ug/L SW 6020A 10/29/2015 14:05 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020A 10/29/2015 14:05 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020A 10/29/2015 14:05 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L SW 6020A 10/29/2015 14:05 JAHERMA0.2 1
Vanadium (V)< 1 ug/L SW 6020A 10/29/2015 14:05 JAHERMA11
Page 17 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100188
Q15100483 ALK_FIX4.5 ALKALINITY (FIXED END POINT 4.5)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J15100247 -- 2015033209
Alkalinity (mg/L CaCO3)0.194mg/L
(CaCO3)
-179.6
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3)81.6 98.7mg/L
(CaCO3)
-12080180.6
Page 18 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100188
Q15100491 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J15100188 -- 2015032952
Alkalinity (mg/L CaCO3)1.68mg/L
(CaCO3)
-110.5
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3)8.16 87.5mg/L
(CaCO3)
-1208017.14
Page 19 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100188
Q15100439 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0392 mg/L -10.0392 0.1 < 1/2 RDL
Fluoride mg/L -10.0378 0.1 < 1/2 RDL
Nitrate 0.0226 mg/L -10.0226 0.1 < 1/2 RDL
Nitrate as N mg-N/L -10 0.023 < 1/2 RDL
Sulfate 0.0017 mg/L -10.0017 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 6.7 5 102mg/L -1208016.7
Fluoride 5 104mg/L -1208015.23
Nitrate 6.13 5 99.9mg/L -1208016.13
Sulfate 5.33 5 82.2mg/L -1208015.33
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 6.72 5 102 0.486mg/L -1208016.72
Fluoride 5 103 0.0213mg/L -1208015.22
Nitrate 6.15 5 100 0.276mg/L -1208016.15
Sulfate 5.31 5 81.8 0.564mg/L -1208015.31
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 8.39 5 100mg/L -1208018.39
Fluoride 5 97.7mg/L -1208014.95
Nitrate 4.91 5 97.7mg/L -1208014.91
Sulfate 5.05 5 97.1mg/L -1208015.05
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 8.4 5 100 0.267mg/L -1208018.4
Fluoride 5 98.5 0.785mg/L -1208014.99
Nitrate 4.92 5 97.9 0.149mg/L -1208014.92
Sulfate 5.06 5 97.3 0.247mg/L -1208015.06
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 4.85 5 97mg/L -1208014.85
Fluoride 5 103mg/L -1208015.17
Nitrate 4.92 5 98.3mg/L -1208014.92
Sulfate 4.88 5 97.6mg/L -1208014.88
Page 20 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100188
Q15100545 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.009 ug/L -10.009 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.019 ug/L -10.019 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.94 2 97ug/L -1158511.94
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.91 2 95.3ug/L -1158511.91
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J15090311 -- 2015030319
Mercury (Hg) 0.911 20 89.9ug/L -130702018.2
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J15090311 -- 2015030319
Mercury (Hg) 0.905 20 89.3 0.726ug/L -130702018.1
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J15100188 -- 2015032958
Mercury (Hg) 1.03 1 102ug/L -1307011.03
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J15100188 -- 2015032958
Mercury (Hg) 1.03 1 103 0.88ug/L -1307011.03
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J15100247 -- 2015033208
Mercury (Hg) 1.01 1 99.1ug/L -1307011.01
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J15100247 -- 2015033208
Mercury (Hg) 1.02 1 99.3 0.202ug/L -1307011.02
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J15100568 -- 2015034550
Mercury (Hg) 1.02 1 101ug/L -1307011.02
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J15100568 -- 2015034550
Mercury (Hg) 1.02 1 101 0ug/L -1307011.02
Page 21 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100188
Q15100441 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) -0.000101 mg/L -1-0.000101 0.005 < 1/2 RDL
Beryllium (Be) -0.000211 mg/L -1-0.000211 0.005 < 1/2 RDL
Boron (B) 0.00153 mg/L -10.00153 0.05 < 1/2 RDL
Calcium (Ca) 0.00669 mg/L -10.00669 0.01 > 1/2 RDL
Chromium (Cr) -0.000738 mg/L -1-0.000738 0.005 < 1/2 RDL
Copper (Cu) -0.00108 mg/L -1-0.00108 0.005 < 1/2 RDL
Iron (Fe) 0.000315 mg/L -10.000315 0.01 < 1/2 RDL
Magnesium (Mg) -0.000026 mg/L -1-0.000026 0.005 < 1/2 RDL
Manganese (Mn) -0.000344 mg/L -1-0.000344 0.005 < 1/2 RDL
Nickel (Ni) -0.00188 mg/L -1-0.00188 0.005 < 1/2 RDL
Potassium (K) 0.000967 mg/L -10.000967 0.1 < 1/2 RDL
Silver (Ag) 0.000483 mg/L -10.000483 0.005 < 1/2 RDL
Sodium (Na) 0.0111 mg/L -10.0111 0.05 < 1/2 RDL
Zinc (Zn) 0.000283 mg/L -10.000283 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 5.21 5 104mg/L -1208015.21
Beryllium (Be) 5.02 5 100mg/L -1208015.02
Boron (B) 5.06 5 101mg/L -1208015.06
Calcium (Ca) 4.94 5 98.8mg/L -1208014.94
Chromium (Cr) 5.14 5 103mg/L -1208015.14
Copper (Cu) 5.06 5 101mg/L -1208015.06
Iron (Fe) 4.97 5 99.4mg/L -1208014.97
Magnesium (Mg) 5.19 5 104mg/L -1208015.19
Manganese (Mn) 5.27 5 105mg/L -1208015.27
Nickel (Ni) 5.18 5 104mg/L -1208015.18
Potassium (K) 5.1 5 102mg/L -1208015.1
Silver (Ag) 0.523 0.5 105mg/L -1208010.523
Sodium (Na) 5.08 5 102mg/L -1208015.08
Zinc (Zn) 5.11 5 102mg/L -1208015.11
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J15100188 -- 2015032947
Barium (Ba) 5.2 5 104mg/L -1257515.2
Beryllium (Be) 4.99 5 99.7mg/L -1257514.99
Boron (B) 5.02 5 100mg/L -1257515.02
Calcium (Ca) 5.07 5 98.5mg/L -1257515.07
Chromium (Cr) 5.12 5 102mg/L -1257515.12
Copper (Cu) 5.02 5 100mg/L -1257515.02
Page 22 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100188
Q15100441 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J15100188 -- 2015032947
Iron (Fe) 5.11 5 99mg/L -1257515.11
Magnesium (Mg) 5.45 5 103mg/L -1257515.45
Manganese (Mn) 5.28 5 105mg/L -1257515.28
Nickel (Ni) 5.17 5 103mg/L -1257515.17
Potassium (K) 5.53 5 99.8mg/L -1257515.53
Silver (Ag) 0.518 0.5 103mg/L -1257510.518
Sodium (Na) 6.76 5 102mg/L -1257516.76
Zinc (Zn) 5.07 5 101mg/L -1257515.07
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J15100188 -- 2015032947
Barium (Ba) 5.28 5 105 1.59mg/L -1257515.28
Beryllium (Be) 5.04 5 101 0.998mg/L -1257515.04
Boron (B) 5.07 5 101 1.01mg/L -1257515.07
Calcium (Ca) 5.16 5 100 1.71mg/L -1257515.16
Chromium (Cr) 5.2 5 104 1.53mg/L -1257515.2
Copper (Cu) 5.09 5 102 1.46mg/L -1257515.09
Iron (Fe) 5.19 5 101 1.58mg/L -1257515.19
Magnesium (Mg) 5.55 5 105 1.94mg/L -1257515.55
Manganese (Mn) 5.37 5 107 1.64mg/L -1257515.37
Nickel (Ni) 5.24 5 105 1.46mg/L -1257515.24
Potassium (K) 5.61 5 101 1.47mg/L -1257515.61
Silver (Ag) 0.525 0.5 105 1.33mg/L -1257510.525
Sodium (Na) 6.87 5 105 2.09mg/L -1257516.87
Zinc (Zn) 5.16 5 103 1.72mg/L -1257515.16
Page 23 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100188
Q15100444 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) 0.392 ug/L -10.392 1 < 1/2 RDL
Arsenic (As) 0.0413 ug/L -10.0413 1 < 1/2 RDL
Beryllium (Be) 0 ug/L -10 1 < 1/2 RDL
Cadmium (Cd) -0.0005 ug/L -1-0.0005 1 < 1/2 RDL
Chromium (Cr) 0.0183 ug/L -10.0183 1 < 1/2 RDL
Cobalt (Co) 0.0022 ug/L -10.0022 1 < 1/2 RDL
Copper (Cu) 0.29 ug/L -10.29 1 < 1/2 RDL
Lead (Pb) 0.0177 ug/L -10.0177 1 < 1/2 RDL
Nickel (Ni) 0.0128 ug/L -10.0128 1 < 1/2 RDL
Selenium (Se) 0.0102 ug/L -10.0102 1 < 1/2 RDL
Silver (Ag) 0 ug/L -10 1 < 1/2 RDL
Thallium (Tl) Low Level -0.0428 ug/L -1-0.0428 0.2 < 1/2 RDL
Vanadium (V) 0.0601 ug/L -10.0601 1 < 1/2 RDL
Zinc (Zn) 0.241 ug/L -10.241 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 53.7 50 107ug/L -12080153.7
Arsenic (As) 51.2 50 102ug/L -12080151.2
Beryllium (Be) 52.1 50 104ug/L -12080152.1
Cadmium (Cd) 51.1 50 102ug/L -12080151.1
Chromium (Cr) 53.2 50 106ug/L -12080153.2
Cobalt (Co) 50.3 50 101ug/L -12080150.3
Copper (Cu) 52.2 50 104ug/L -12080152.2
Lead (Pb) 50.9 50 102ug/L -12080150.9
Nickel (Ni) 50.9 50 102ug/L -12080150.9
Selenium (Se) 50.9 50 102ug/L -12080150.9
Silver (Ag) 51.6 50 103ug/L -12080151.6
Thallium (Tl) Low Level 50 50 100ug/L -150
Vanadium (V) 50.4 50 101ug/L -12080150.4
Zinc (Zn) 51.8 50 104ug/L -12080151.8
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J15100188 -- 2015032948
Antimony (Sb) 53.9 50 106ug/L -12080153.9
Arsenic (As) 49.6 50 99ug/L -12080149.6
Beryllium (Be) 51.8 50 104ug/L -12080151.8
Cadmium (Cd) 49.6 50 99.3ug/L -12080149.6
Chromium (Cr) 52.6 50 105ug/L -12080152.6
Cobalt (Co) 49.8 50 99.5ug/L -12080149.8
Page 24 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100188
Q15100444 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J15100188 -- 2015032948
Copper (Cu) 51.5 50 102ug/L -12080151.5
Lead (Pb) 50.8 50 102ug/L -12080150.8
Nickel (Ni) 50.1 50 99.5ug/L -12080150.1
Selenium (Se) 47 50 93.8ug/L -12080147
Silver (Ag) 49.6 50 99.3ug/L -12080149.6
Thallium (Tl) Low Level 49.6 50 99.1ug/L -149.6
Vanadium (V) 50.5 50 100ug/L -12080150.5
Zinc (Zn) 51.2 50 98.5ug/L -12080151.2
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J15100188 -- 2015032948
Antimony (Sb) 54.2 50 106 0.642ug/L -12080154.2
Arsenic (As) 49.6 50 98.9 0.101ug/L -12080149.6
Beryllium (Be) 52.3 50 105 0.883ug/L -12080152.3
Cadmium (Cd) 49.7 50 99.4 0.101ug/L -12080149.7
Chromium (Cr) 52.2 50 104 0.708ug/L -12080152.2
Cobalt (Co) 50.4 50 101 1.08ug/L -12080150.4
Copper (Cu) 51.8 50 103 0.683ug/L -12080151.8
Lead (Pb) 50.5 50 101 0.572ug/L -12080150.5
Nickel (Ni) 50.3 50 100 0.521ug/L -12080150.3
Selenium (Se) 52.5 50 105 11.1ug/L -12080152.5
Silver (Ag) 50.3 50 101 1.28ug/L -12080150.3
Thallium (Tl) Low Level 49.4 50 98.7 0.425ug/L -149.4
Vanadium (V) 49.9 50 98.9 1.33ug/L -12080149.9
Zinc (Zn) 51.4 50 99 0.506ug/L -12080151.4
Page 25 of 27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100188
Q15100447 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J15100188 -- 2015032947
TDS 5.26mg/L -137
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J15100188 -- 2015032948
TDS 4mg/L -1102
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J15100188 -- 2015032950
TDS 8.26mg/L -163
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 97mg/L -11090197
Page 26 of 27
Page 27 of 27