7305_DukeMayo_Nov2015_2ndSemiAnnual_DIN26341_20160222

Mayo Electric Generating Plant
Coal Combustion Products Monofill Phase 1
Permit No. 7305
Semiannual Groundwater Monitoring Report
November 2015 Sampling Event

March 13, 2015

Duke Energy Progress, Inc. | Semiannual Groundwater Monitoring ReportMayo Electric Generating Plant – Coal Combustion Products Monofill Phase 1November 2015 Sampling EventCONTENTS
i
Contents
Page
Contents ......................................................................................................................................... i
Section 1 - Background ................................................................................................................. 1
Section 2 - Methods ...................................................................................................................... 3
2.1 Sampling and Analysis Methods .................................................................................... 3
2.2 Statement of Work .......................................................................................................... 3
Section 3 - Results ........................................................................................................................ 5
3.1 Site Groundwater Flow ................................................................................................... 5
3.2 Analytical Results ........................................................................................................... 5

Figures
1. Site Location Map
2. Sample Locations
3. Generalized Groundwater Surface Contours
Tables
1. Well Construction Information
2. Groundwater Flow Velocities
3. Field Data Parameters
4. Groundwater Field and Analytical Results
5. Field and Analytical Results that Equal or Exceed 15A NCAC 2L Groundwater Quality
Standards
6. Surface Water Field and Analytical Results
7. Leachate Field and Analytical Results

Duke Energy Progress, Inc. | Semiannual Groundwater Monitoring ReportMayo Electric Generating Plant – Coal Combustion Products Monofill Phase 1November 2015 Sampling EventCONTENTS

ii
Appendices
A. Field Sampling Forms
B. Laboratory Report and Chain-of-Custody Forms

Duke Energy Progress, Inc. | Semiannual Groundwater Monitoring ReportMayo Electric Generating Plant – Coal Combustion Products Monofill Phase 1November 2015 Sampling EventSECTION 1 - BACKGROUND
1
Section 1 - Background
The 727-megawatt (MW) Mayo Electric Generating Plant (station) is located at 10660 Boston
Road, Roxboro, Person County, North Carolina. The station is owned and operated by Duke
Energy Progress (Duke Energy) and generates electricity by combustion of coal. The landfill,
Mayo Electric Generating Plant, Coal Combustion Products (CCP) Monofill, Phase 1, is located
to the northwest of the station. The landfill accepts fly ash, bottom ash, flue gas desulfurization
(FGD) by-products, and other by-products from coal combustion associated with power
generation at the station under North Carolina Department of Environmental Quality (NCDEQ)
Solid Waste Permit No. 7305. NCDEQ issued the Permit to Construct for the monofill on July
19, 2012. The permit to operate (PTO) was issued on July 10, 2014, and waste placement
began on November 7, 2014.
As described in the Water Quality Monitoring Plan (WQMP), the monofill is located within the
Piedmont physiographic province.1 The Piedmont physiographic province is comprised of
several geologic belts with areas of similar rock types and geologic history. The monofill is
located within the Milton Belt which includes metamorphosed volcanic and sedimentary rocks.
According to the WQMP, during the field investigation for the monofill Design Hydrogeologic
Report, three hydrogeologic units were identified on site: saprolite, partially weathered rock
(PWR), and bedrock. Groundwater was generally not encountered in the saprolite unit.
Groundwater was encountered in the PWR unit over much of the monofill site. The bedrock
hydrogeologic unit is continuous across the monofill site.
The monofill site is located on an upland area with surface water drainage features that
discharge to the east and northeast into Bowe’s Branch, a tributary of the Hyco River. The
surface water features to the west of the monofill site drain to the northwest to an un-named
tributary of Bowe’s Branch. The 104-acre disposal facility will be developed in 11 phases with
Phase 1 encompassing approximately 31 acres.
The monofill location and nearby area are presented on Figure 1. Figure 2 shows the Phase 1
monofill site, topography, and vicinity features.

1 Water Quality Monitoring Plan – Duke Energy Progress, Inc., Mayo CCP Monofill, Permit No. 73-05,
Golder Associates NC, Inc. Project No. 063-6562034, March 2014.
Duke Energy Progress, Inc. | Semiannual Groundwater Monitoring ReportMayo Electric Generating Plant – Coal Combustion Products Monofill Phase 1November 2015 Sampling EventSECTION 1 - BACKGROUND

2
As described in the WQMP, the monitoring system for the Phase 1 portion of the monofill
consists of the following:
Monitoring Wells: MW-1 MW-2
MW-3
MW-4 MW-5
Surface Water Sample Locations: SW-1
SW-2
SW-3
Leachate Sample Locations: L-1 L-2

The monitoring wells, surface water sampling locations, and leachate sampling location L-1 are
depicted on Figure 2.
According to the WQMP, MW-1 serves as a background water quality monitoring well and is
located upgradient of the monofill. The WQMP states the monitoring network is designed to
monitor for releases to the uppermost aquifer at the monofill. The wells were installed with
screen lengths ranging from 10 feet to 20 feet in length. Table 1 presents well construction
information for the landfill monitoring wells.
Surface water sampling location SW-1 is located on an un-named perennial stream (tributary of
Bowes Branch) and is southwest of Phase 1. SW-1 is located upstream of where groundwater
from the Phase 1 region would discharge into the unnamed tributary of Bowes Branch. Surface
water sampling location SW-2 is located on Bowes Branch to the east of the Phase 1 monofill.
Surface water sampling location SW-3 is located on Bowes Branch downstream from SW-1 and
SW-2. The surface water flow on Figure 2 is generally from the south to the north.
Leachate sample L-1 is collected from the facility’s leachate tanks located to the west of the
Phase 1 monofill. The leachate sample is collected from an inline sampling valve linked to each
of the three leachate tanks; therefore, the sample is considered a composite leachate sample.
The facility has the ability to direct leachate through a force main to the National Pollutant
Discharge Elimination System (NPDES) permitted scrubber blowdown pond located on the east
side of NC Highway 501. Should the facility have no leachate in the leachate tank system and
be diverting leachate from the monofill to the scrubber blowdown pond, the leachate sample will
be collected from the end of the pipe at the scrubber blowdown pond. If the leachate sample is
collected from this location, it will be identified as L-2.
Duke Energy Progress, Inc. | Semiannual Groundwater Monitoring ReportMayo Electric Generating Plant – Coal Combustion Products Monofill Phase 1November 2015 Sampling EventSECTION 2 - METHODS
3
Section 2 - Methods
2.1 Sampling and Analysis Methods
The collection of samples and documentation of sampling was performed by SynTerra
Corporation (SynTerra) personnel (SynTerra Field Certification #5591) according to the North
Carolina Solid Waste Management Guidelines. Copies of the field sampling forms are included
in Appendix A. The parameters and constituents reported were selected by Duke Energy and
the NCDEQ Division of Solid Waste and were analyzed by Duke Energy Analytical Laboratory
(North Carolina Laboratory Certification #248). The laboratory report and chain-of-custody forms
are included in Appendix B.
The groundwater and surface water samples were analyzed for the following constituents:
 Barium, boron, chromium, copper, iron, manganese, nickel, silver, and zinc using U.S.
Environmental Protection Agency (EPA) Method 200.7
 Arsenic, cadmium, lead, and selenium using EPA Method 200.8
 Chloride, fluoride, nitrate (as nitrogen), and sulfate using EPA Method 300.0
 Mercury using EPA Method 245.1
 Total dissolved solids using Standard Method (SM) 2540C
2.2 Statement of Work
HDR completed the following tasks:
 Received November 2015 field sampling information provided by Duke Energy
(performed by SynTerra personnel) for monitoring wells MW-1, MW-2, MW-3, MW-4,
and MW-5. Data was also received for surface water sample locations SW-1, SW-2, and
SW-3, and leachate sample “Leachate”. The samples were collected on November 3
and 4, 2015. HDR received the data on December 17, 2015.
 Reviewed the laboratory analytical results for the samples listed above. The Electronic
Data Deliverable (EDD) provided by Duke Energy was adapted to conform to the format
requirements of the NCDEQ EDD template. HDR added an italicized J data qualifier (J’)
to indicate a measured concentration that is equal to or greater than the laboratory’s
method reporting limit (MRL) but less than the Solid Waste Section Limit2 (SWSL). A
copy of the original EDD is retained in HDR’s files.
2 The Solid Waste Section Limit (SWSL) is defined by NCDEQ as the lowest amount of analyte in a
sample that can be quantitatively determined with suitable precision and accuracy. The SWSL is the concentration below which reported results must be qualified as estimated. NCDEQ Division of Waste
Management Memorandum dated February 23, 2007.
Duke Energy Progress, Inc. | Semiannual Groundwater Monitoring ReportMayo Electric Generating Plant – Coal Combustion Products Monofill Phase 1November 2015 Sampling EventSECTION 2 - METHODS

4
 Developed generalized groundwater surface contour map using map data and
groundwater elevation data supplied by Duke Energy. Calculated groundwater flow
velocities based on groundwater surface contours.
 Prepared and submitted this Semiannual Groundwater Monitoring Report to Duke
Energy.
Duke Energy Progress, Inc. | Semiannual Groundwater Monitoring ReportMayo Electric Generating Plant – Coal Combustion Products Monofill Phase 1November 2015 Sampling EventSECTION 3 - RESULTS
5
Section 3 - Results
3.1 Site Groundwater Flow
Generalized groundwater surface contours and groundwater flow direction arrows for the site
are shown on Figure 3. These contours were developed using the groundwater elevations
measured on the date of sampling. Calculated flow velocities are presented in Table 2.
Groundwater flow in the shallow aquifer beneath the Phase 1 footprint is from the areas of
higher topography located along the central and western portion of the Phase 1 footprint
generally towards the reach of Bowes Branch located along the eastern boundary of the
monofill.
3.2 Analytical Results
The measured field data parameters are presented in Table 3.
The field and analytical results of groundwater samples collected from the monitoring wells are
presented in Table 4. The analytical results for these samples are compared to the groundwater
standards established in Title 15A NCAC 02L .0202 (g) (2L Standards). Concentrations that
attain or exceed the 2L Standards are noted in Table 4 by bold font. A summary of the field and
analytical results that attain or exceed the 2L Standards and a preliminary analysis of the cause
and significance of the exceedances are presented in Table 5. The high chromium reading of
160 µg/L has been verified by the Duke Energy Analytical Laboratory. A copy of the email
conversation confirming the verification is retained in HDR’s files.
Surface water sample location SW-1 is located on an un-named perennial stream (tributary of
Bowes Branch) and surface water sampling locations SW-2 and SW-3 are located on Bowes
Branch. Bowes Branch is classified by the NCDEQ Division of Water Quality as a Class C water
body. As a result, the field and analytical results from these locations are compared to Title 15A
NCAC Subchapter 2B Standards (2B Standards) for Class C waters. The field and analytical
results for the surface water samples are summarized in Table 6.
Surface water samples were inadvertently not field-filtered nor where they analyzed for their
dissolved fraction results during the November 2015 sampling event. Sampling for these
parameters will be performed during the next sampling event. Several of the surface water
constituents have standards for the dissolved fraction of metals (15A NCAC 02B .0211 (11)
effective January 1st, 2015). The total recoverable results for copper at SW-1 and for silver at
SW-3 are greater than their respective dissolved fraction 2B Standards. The total recoverable
results for these constituents are not considered to exceed of the 2B Standards at these
locations.
The field and analytical results for leachate sampling are summarized in Table 7.
Concentrations with values that are equal to or greater than the SWSLs are noted in Tables 4,
6, and 7 by gray-shaded cells.
Duke Energy Progress, Inc. | Semiannual Groundwater Monitoring ReportMayo Electric Generating Plant – Coal Combustion Products Monofill Phase 1November 2015 Sampling EventSECTION 3 - RESULTS

6
Select samples were diluted, as is normal laboratory practice, to bring samples within the
calibrated range of the analysis. Specifics regarding the samples that were diluted, including the
dilution amount, are reported in the EDD.

FIGURES

TABLES
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Page 1 of 1
Ta
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3

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Page 1 of 1
Ta
b
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e

4

-

G
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Page 1 of 1

A
Appendix A
Field Sampling Forms

B
Appendix B
Laboratory Report and Chain-of-Custody Forms

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J15100404
Project Name:MAYO STEAM - LFGW
Lab Contact:Peggy Kendall
Date:11/19/2015
Customer Address:
Customer Name(s):J. TOEPFER, T. HUNSUCKER
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Peggy Kendall
Page 1 of 30
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2015033911 MAYO STEAM 03-Nov-15 2:06 PM illegible MW-1
2015033912 MAYO STEAM 03-Nov-15 10:03 AM illegible MW-2
2015033913 MAYO STEAM 03-Nov-15 11:30 AM illegible MW-3
2015033914 MAYO STEAM 03-Nov-15 12:56 PM illegible MW-4
2015033915 MAYO STEAM 03-Nov-15 12:09 PM illegible MW-5
2015033916 MAYO STEAM 03-Nov-15 12:56 PM illegible DUP
2015033917 MAYO STEAM 04-Nov-15 9:55 AM illegible FIELD BLANK
2015033918 MAYO STEAM 04-Nov-15 8:37 AM illegible SW-1
2015033919 MAYO STEAM 04-Nov-15 9:10 AM illegible SW-2
2015033920 MAYO STEAM 04-Nov-15 9:30 AM illegible SW-3
2015033921 MAYO STEAM 04-Nov-15 8:15 AM illegible Leachate
11 Total Samples
Page 2 of 30
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:11/19/2015
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
2015033911
Collection Date:03-Nov-15 2:06 PM
Site:MW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 14 mg/L EPA 300.0 11/04/2015 14:44 BGN90340.5 5
Fluoride < 0.1 mg/L EPA 300.0 11/04/2015 14:44 BGN90340.1 1
Nitrate 6.4 mg/L EPA 300.0 11/04/2015 14:44 BGN90340.1 1
Nitrate as N 1.4 mg-N/L EPA 300.0 11/04/2015 14:44 BGN90340.023 1
Sulfate 22 mg/L EPA 300.0 11/04/2015 14:44 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/07/2015 14:23 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.164 mg/L EPA 200.7 11/06/2015 10:35 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/06/2015 10:35 FCJORDA0.05 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/06/2015 10:35 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/06/2015 10:35 FCJORDA0.005 1
Iron (Fe)0.095 mg/L EPA 200.7 11/06/2015 10:35 FCJORDA0.01 1
Manganese (Mn)0.006 mg/L EPA 200.7 11/06/2015 10:35 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/06/2015 10:35 FCJORDA0.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/06/2015 10:35 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/06/2015 10:35 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/06/2015 16:13 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/06/2015 16:13 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/06/2015 16:13 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 11/06/2015 16:13 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 210 mg/L SM2540C 11/05/2015 14:15 CJELLIO251
Page 4 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
2015033912
Collection Date:03-Nov-15 10:03 AM
Site:MW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 48 mg/L EPA 300.0 11/04/2015 15:02 BGN9034110
Fluoride 0.18 mg/L EPA 300.0 11/04/2015 15:02 BGN90340.1 1
Nitrate 0.15 mg/L EPA 300.0 11/04/2015 15:02 BGN90340.1 1
Nitrate as N 0.03 mg-N/L EPA 300.0 11/04/2015 15:02 BGN90340.023 1
Sulfate 42 mg/L EPA 300.0 11/04/2015 15:02 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/07/2015 14:30 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.044 mg/L EPA 200.7 11/06/2015 10:46 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/06/2015 10:46 FCJORDA0.05 1
Chromium (Cr)0.008 mg/L EPA 200.7 11/06/2015 10:46 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/06/2015 10:46 FCJORDA0.005 1
Iron (Fe)0.358 mg/L EPA 200.7 11/06/2015 10:46 FCJORDA0.01 1
Manganese (Mn)0.388 mg/L EPA 200.7 11/06/2015 10:46 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/06/2015 10:46 FCJORDA0.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/06/2015 10:46 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/06/2015 10:46 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/06/2015 15:50 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/06/2015 15:50 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/06/2015 15:50 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 11/06/2015 15:50 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 450 mg/L SM2540C 11/05/2015 14:15 CJELLIO251
Page 5 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
2015033913
Collection Date:03-Nov-15 11:30 AM
Site:MW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 79 mg/L EPA 300.0 11/04/2015 15:20 BGN9034220
Fluoride 0.25 mg/L EPA 300.0 11/04/2015 15:20 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 300.0 11/04/2015 15:20 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 11/04/2015 15:20 BGN90340.023 1
Sulfate 18 mg/L EPA 300.0 11/04/2015 15:20 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/07/2015 14:37 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.166 mg/L EPA 200.7 11/06/2015 10:50 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/06/2015 10:50 FCJORDA0.05 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/06/2015 10:50 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/06/2015 10:50 FCJORDA0.005 1
Iron (Fe)0.325 mg/L EPA 200.7 11/06/2015 10:50 FCJORDA0.01 1
Manganese (Mn)0.397 mg/L EPA 200.7 11/06/2015 10:50 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/06/2015 10:50 FCJORDA0.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/06/2015 10:50 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/06/2015 10:50 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/06/2015 16:20 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/06/2015 16:20 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/06/2015 16:20 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 11/06/2015 16:20 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 430 mg/L SM2540C 11/05/2015 14:15 CJELLIO251
Page 6 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
2015033914
Collection Date:03-Nov-15 12:56 PM
Site:MW-4
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 57 mg/L EPA 300.0 11/04/2015 15:37 BGN9034220
Fluoride 0.15 mg/L EPA 300.0 11/04/2015 15:37 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 300.0 11/04/2015 15:37 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 11/04/2015 15:37 BGN90340.023 1
Sulfate 81 mg/L EPA 300.0 11/04/2015 15:37 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/07/2015 14:39 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.235 mg/L EPA 200.7 11/06/2015 10:54 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/06/2015 10:54 FCJORDA0.05 1
Chromium (Cr)0.160 mg/L EPA 200.7 11/06/2015 10:54 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/06/2015 10:54 FCJORDA0.005 1
Iron (Fe)0.988 mg/L EPA 200.7 11/06/2015 10:54 FCJORDA0.01 1
Manganese (Mn)0.351 mg/L EPA 200.7 11/06/2015 10:54 FCJORDA0.005 1
Nickel (Ni)0.083 mg/L EPA 200.7 11/06/2015 10:54 FCJORDA0.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/06/2015 10:54 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/06/2015 10:54 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/06/2015 16:28 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/06/2015 16:28 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/06/2015 16:28 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 11/06/2015 16:28 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 560 mg/L SM2540C 11/05/2015 14:15 CJELLIO251
Page 7 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
2015033915
Collection Date:03-Nov-15 12:09 PM
Site:MW-5
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 13 mg/L EPA 300.0 11/04/2015 17:25 BGN90340.2 2
Fluoride 0.22 mg/L EPA 300.0 11/04/2015 17:25 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 300.0 11/04/2015 17:25 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 11/04/2015 17:25 BGN90340.023 1
Sulfate 12 mg/L EPA 300.0 11/04/2015 17:25 BGN90340.2 2
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/07/2015 14:42 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.008 mg/L EPA 200.7 11/06/2015 10:58 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/06/2015 10:58 FCJORDA0.05 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/06/2015 10:58 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/06/2015 10:58 FCJORDA0.005 1
Iron (Fe)0.059 mg/L EPA 200.7 11/06/2015 10:58 FCJORDA0.01 1
Manganese (Mn)0.073 mg/L EPA 200.7 11/06/2015 10:58 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/06/2015 10:58 FCJORDA0.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/06/2015 10:58 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/06/2015 10:58 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/06/2015 16:36 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/06/2015 16:36 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/06/2015 16:36 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 11/06/2015 16:36 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 340 mg/L SM2540C 11/05/2015 14:15 CJELLIO251
Page 8 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
2015033916
Collection Date:03-Nov-15 12:56 PM
Site:DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 59 mg/L EPA 300.0 11/04/2015 21:36 BGN9034110
Fluoride 0.15 mg/L EPA 300.0 11/04/2015 21:36 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 300.0 11/04/2015 21:36 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 11/04/2015 21:36 BGN90340.023 1
Sulfate 81 mg/L EPA 300.0 11/04/2015 21:36 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/07/2015 14:44 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.231 mg/L EPA 200.7 11/06/2015 11:02 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/06/2015 11:02 FCJORDA0.05 1
Chromium (Cr)0.098 mg/L EPA 200.7 11/06/2015 11:02 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/06/2015 11:02 FCJORDA0.005 1
Iron (Fe)0.628 mg/L EPA 200.7 11/06/2015 11:02 FCJORDA0.01 1
Manganese (Mn)0.339 mg/L EPA 200.7 11/06/2015 11:02 FCJORDA0.005 1
Nickel (Ni)0.052 mg/L EPA 200.7 11/06/2015 11:02 FCJORDA0.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/06/2015 11:02 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/06/2015 11:02 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/06/2015 16:43 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/06/2015 16:43 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/06/2015 16:43 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 11/06/2015 16:43 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 580 mg/L SM2540C 11/05/2015 14:15 CJELLIO251
Page 9 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
2015033917
Collection Date:04-Nov-15 9:55 AM
Site:FIELD BLANK
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 11/05/2015 23:11 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 11/05/2015 23:11 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 300.0 11/05/2015 23:11 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 11/05/2015 23:11 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 300.0 11/05/2015 23:11 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/07/2015 14:46 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L EPA 200.7 11/09/2015 09:36 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/09/2015 09:36 FCJORDA0.05 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/09/2015 09:36 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/09/2015 09:36 FCJORDA0.005 1
Iron (Fe)< 0.01 mg/L EPA 200.7 11/09/2015 09:36 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 11/09/2015 09:36 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/09/2015 09:36 FCJORDA0.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/09/2015 09:36 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/09/2015 09:36 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/07/2015 16:23 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/07/2015 16:23 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/07/2015 16:23 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 11/07/2015 16:23 MHALL311
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 11/07/2015 11:35 CJELLIO251
Page 10 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
2015033918
Collection Date:04-Nov-15 8:37 AM
Site:SW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 5.6 mg/L EPA 300.0 11/05/2015 23:29 BGN90340.1 1
Fluoride 0.16 mg/L EPA 300.0 11/05/2015 23:29 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 300.0 11/05/2015 23:29 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 11/05/2015 23:29 BGN90340.023 1
Sulfate 6.2 mg/L EPA 300.0 11/05/2015 23:29 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/07/2015 14:49 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.048 mg/L EPA 200.7 11/09/2015 09:24 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/09/2015 09:24 FCJORDA0.05 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/09/2015 09:24 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/09/2015 09:24 FCJORDA0.005 1
Iron (Fe)2.98 mg/L EPA 200.7 11/09/2015 09:24 FCJORDA0.01 1
Manganese (Mn)0.081 mg/L EPA 200.7 11/09/2015 09:24 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/09/2015 09:24 FCJORDA0.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/09/2015 09:24 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/09/2015 09:24 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/07/2015 16:30 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/07/2015 16:30 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/07/2015 16:30 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 11/07/2015 16:30 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 120 mg/L SM2540C 11/07/2015 11:35 CJELLIO251
Page 11 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
2015033919
Collection Date:04-Nov-15 9:10 AM
Site:SW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 8.9 mg/L EPA 300.0 11/06/2015 00:23 BGN90340.1 1
Fluoride 0.14 mg/L EPA 300.0 11/06/2015 00:23 BGN90340.1 1
Nitrate 0.24 mg/L EPA 300.0 11/06/2015 00:23 BGN90340.1 1
Nitrate as N 0.06 mg-N/L EPA 300.0 11/06/2015 00:23 BGN90340.023 1
Sulfate 8.5 mg/L EPA 300.0 11/06/2015 00:23 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/07/2015 14:51 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.032 mg/L EPA 200.7 11/09/2015 09:39 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/09/2015 09:39 FCJORDA0.05 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/09/2015 09:39 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/09/2015 09:39 FCJORDA0.005 1
Iron (Fe)1.21 mg/L EPA 200.7 11/09/2015 09:39 FCJORDA0.01 1
Manganese (Mn)0.033 mg/L EPA 200.7 11/09/2015 09:39 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/09/2015 09:39 FCJORDA0.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/09/2015 09:39 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/09/2015 09:39 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/07/2015 16:37 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/07/2015 16:37 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/07/2015 16:37 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 11/07/2015 16:37 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 73 mg/L SM2540C 11/07/2015 11:35 CJELLIO251
Page 12 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
2015033920
Collection Date:04-Nov-15 9:30 AM
Site:SW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 7.5 mg/L EPA 300.0 11/06/2015 00:41 BGN90340.1 1
Fluoride 0.13 mg/L EPA 300.0 11/06/2015 00:41 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 300.0 11/06/2015 00:41 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 11/06/2015 00:41 BGN90340.023 1
Sulfate 8.0 mg/L EPA 300.0 11/06/2015 00:41 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/07/2015 14:54 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.032 mg/L EPA 200.7 11/09/2015 09:43 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/09/2015 09:43 FCJORDA0.05 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/09/2015 09:43 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/09/2015 09:43 FCJORDA0.005 1
Iron (Fe)1.40 mg/L EPA 200.7 11/09/2015 09:43 FCJORDA0.01 1
Manganese (Mn)0.052 mg/L EPA 200.7 11/09/2015 09:43 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/09/2015 09:43 FCJORDA0.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/09/2015 09:43 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/09/2015 09:43 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/07/2015 16:44 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/07/2015 16:44 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/07/2015 16:44 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 11/07/2015 16:44 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 72 mg/L SM2540C 11/07/2015 11:35 CJELLIO251
Page 13 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
2015033921
Collection Date:04-Nov-15 8:15 AM
Site:Leachate
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 47 mg/L EPA 300.0 11/06/2015 04:16 BGN9034110
Fluoride 0.11 mg/L EPA 300.0 11/06/2015 04:16 BGN90340.1 1
Nitrate 2.5 mg/L EPA 300.0 11/06/2015 04:16 BGN9034110
Nitrate as N 0.57 mg-N/L EPA 300.0 11/06/2015 04:16 BGN90340.023 1
Sulfate 85 mg/L EPA 300.0 11/06/2015 04:16 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/07/2015 14:56 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.038 mg/L EPA 200.7 11/09/2015 09:47 FCJORDA0.005 1
Boron (B)1.21 mg/L EPA 200.7 11/09/2015 09:47 FCJORDA0.05 1
Chromium (Cr)0.005 mg/L EPA 200.7 11/09/2015 09:47 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/09/2015 09:47 FCJORDA0.005 1
Iron (Fe)0.012 mg/L EPA 200.7 11/09/2015 09:47 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 11/09/2015 09:47 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/09/2015 09:47 FCJORDA0.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/09/2015 09:47 FCJORDA0.005 1
Zinc (Zn)0.103 mg/L EPA 200.7 11/09/2015 09:47 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)12.6 ug/L EPA 200.8 11/07/2015 16:51 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/07/2015 16:51 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/07/2015 16:51 MHALL311
Selenium (Se)1.27 ug/L EPA 200.8 11/07/2015 16:51 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 250 mg/L SM2540C 11/07/2015 11:35 CJELLIO251
Page 14 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
Q15110100 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0241 mg/L -10.0241 0.1 < 1/2 RDL
Fluoride 0.0451 mg/L -10.0451 0.1 < 1/2 RDL
Nitrate 0.0056 mg/L -10.0056 0.1 < 1/2 RDL
Sulfate 0.0122 mg/L -10.0122 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 10.9 5 105mg/L -12080110.9
Fluoride 5.34 5 104mg/L -1208015.34
Nitrate 5.33 5 105mg/L -1208015.33
Sulfate 11.6 5 109mg/L -12080111.6
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 10.9 5 106 0.485mg/L -12080110.9
Fluoride 5.31 5 103 0.405mg/L -1208015.31
Nitrate 5.19 5 103 2.59mg/L -1208015.19
Sulfate 11.7 5 109 0.248mg/L -12080111.7
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.2 5 104mg/L -1109015.2
Fluoride 5.11 5 102mg/L -1109015.11
Nitrate 5.01 5 100mg/L -1109015.01
Sulfate 5.12 5 102mg/L -1109015.12
Page 15 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
Q15110165 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0105 mg/L -10.0105 0.1 < 1/2 RDL
Fluoride 0.0326 mg/L -10.0326 0.1 < 1/2 RDL
Nitrate -0.0171 mg/L -1-0.0171 0.1 < 1/2 RDL
Sulfate -0.0333 mg/L -1-0.0333 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 10.9 5 93mg/L -12080110.9
Fluoride 4.55 5 87.9mg/L -1208014.55
Nitrate 4.69 5 94mg/L -1208014.69
Sulfate 10.4 5 92.5mg/L -12080110.4
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 10.9 5 92.5 0.561mg/L -12080110.9
Fluoride 4.58 5 88.5 0.66mg/L -1208014.58
Nitrate 4.69 5 94.1 0.0915mg/L -1208014.69
Sulfate 10.4 5 92.6 0.123mg/L -12080110.4
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 4.91 5 98.1mg/L -1109014.91
Fluoride 4.98 5 99.5mg/L -1109014.98
Nitrate 4.89 5 97.9mg/L -1109014.89
Sulfate 4.85 5 97.1mg/L -1109014.85
Page 16 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
Q15110154 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) -0.002 ug/L -1-0.002 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) -0.002 ug/L -1-0.002 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Mercury (Hg) 0 ug/L -10 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.05 2 102ug/L -1158512.05
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 2 2 100ug/L -1158512
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
Mercury (Hg) 1.95 2 97.3ug/L -1158511.95
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J15100433 -- 2015034024
Mercury (Hg) 0.987 100 99.2ug/L -1307010098.7
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J15100433 -- 2015034024
Mercury (Hg) 0.966 100 97.1 2.19ug/L -1307010096.6
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J15100218 -- 2015033095
Mercury (Hg) 0.981 1 98.6ug/L -1307010.981
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J15100218 -- 2015033095
Mercury (Hg) 0.977 1 98.2 0.407ug/L -1307010.977
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J15100400 -- 2015033877
Mercury (Hg) 0.919 1 88.7ug/L -1307010.919
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J15100400 -- 2015033877
Mercury (Hg) 0.938 1 90.6 2.12ug/L -1307010.938
Page 17 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
Q15110154 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J15100404 -- 2015033912
Mercury (Hg) 0.992 1 99.7ug/L -1307010.992
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J15100404 -- 2015033912
Mercury (Hg) 1 1 101 0.899ug/L -1307011
Final QualifierDilMeasuredUnits:Parameter
MS # 5
% Recovery LCL UCLSpike
Parent Sample: J15100405 -- 2015033925
Mercury (Hg) 0.973 1 96.9ug/L -1307010.973
Final QualifierDilMeasuredUnits:Parameter
MSD # 5
RPD% Recovery LCL UCLSpike
Parent Sample: J15100405 -- 2015033925
Mercury (Hg) 0.954 1 95 1.98ug/L -1307010.954
Page 18 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
Q15110086 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) -0.000312 mg/L -1-0.000312 0.005 < 1/2 RDL
Boron (B) -0.000106 mg/L -1-0.000106 0.05 < 1/2 RDL
Chromium (Cr) -0.000812 mg/L -1-0.000812 0.005 < 1/2 RDL
Copper (Cu) 0.000045 mg/L -10.000045 0.005 < 1/2 RDL
Iron (Fe) -0.000504 mg/L -1-0.000504 0.01 < 1/2 RDL
Manganese (Mn) -0.000228 mg/L -1-0.000228 0.005 < 1/2 RDL
Nickel (Ni) -0.000175 mg/L -1-0.000175 0.005 < 1/2 RDL
Silver (Ag) 0.0007 mg/L -10.0007 0.005 < 1/2 RDL
Zinc (Zn) -0.0299 mg/L -1-0.0299 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 5.17 5 103mg/L -1158515.17
Boron (B) 5.04 5 101mg/L -1158515.04
Chromium (Cr) 5.1 5 102mg/L -1158515.1
Copper (Cu) 5.1 5 102mg/L -1158515.1
Iron (Fe) 4.96 5 99.1mg/L -1158514.96
Manganese (Mn) 5.23 5 105mg/L -1158515.23
Nickel (Ni) 5.14 5 103mg/L -1158515.14
Silver (Ag) 0.523 0.5 105mg/L -1158510.523
Zinc (Zn) 5.08 5 102mg/L -1158515.08
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J15100404 -- 2015033911
Barium (Ba) 5.35 5 104mg/L -1307015.35
Boron (B) 5.07 5 101mg/L -1307015.07
Chromium (Cr) 4.99 5 99.8mg/L -1307014.99
Copper (Cu) 5.08 5 102mg/L -1307015.08
Iron (Fe) 5 5 98.1mg/L -1307015
Manganese (Mn) 5.11 5 102mg/L -1307015.11
Nickel (Ni) 4.96 5 99.3mg/L -1307014.96
Silver (Ag) 0.511 0.5 102mg/L -1307010.511
Zinc (Zn) 4.85 5 97.5mg/L -1307014.85
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J15100404 -- 2015033911
Barium (Ba) 5.37 5 104 0.25mg/L -1307015.37
Boron (B) 5.04 5 101 0.456mg/L -1307015.04
Chromium (Cr) 4.98 5 99.6 0.201mg/L -1307014.98
Copper (Cu) 5.07 5 101 0.158mg/L -1307015.07
Page 19 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
Q15110086 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J15100404 -- 2015033911
Iron (Fe) 4.98 5 97.7 0.388mg/L -1307014.98
Manganese (Mn) 5.09 5 102 0.314mg/L -1307015.09
Nickel (Ni) 4.95 5 99 0.262mg/L -1307014.95
Silver (Ag) 0.509 0.5 102 0.492mg/L -1307010.509
Zinc (Zn) 4.84 5 97.2 0.288mg/L -1307014.84
Page 20 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
Q15110132 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) -0.000524 mg/L -1-0.000524 0.005 < 1/2 RDL
Boron (B) 0.00506 mg/L -10.00506 0.05 < 1/2 RDL
Chromium (Cr) -0.00106 mg/L -1-0.00106 0.005 < 1/2 RDL
Copper (Cu) -0.000358 mg/L -1-0.000358 0.005 < 1/2 RDL
Iron (Fe) 0.000266 mg/L -10.000266 0.01 < 1/2 RDL
Manganese (Mn) -0.000345 mg/L -1-0.000345 0.005 < 1/2 RDL
Nickel (Ni) 0.000664 mg/L -10.000664 0.005 < 1/2 RDL
Silver (Ag) 0.000517 mg/L -10.000517 0.005 < 1/2 RDL
Zinc (Zn) -0.000764 mg/L -1-0.000764 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 5.04 5 101mg/L -1158515.04
Boron (B) 4.99 5 99.8mg/L -1158514.99
Chromium (Cr) 4.97 5 99.4mg/L -1158514.97
Copper (Cu) 4.96 5 99.2mg/L -1158514.96
Iron (Fe) 4.78 5 95.6mg/L -1158514.78
Manganese (Mn) 5.06 5 101mg/L -1158515.06
Nickel (Ni) 5.01 5 100mg/L -1158515.01
Silver (Ag) 0.522 0.5 104mg/L -1158510.522
Zinc (Zn) 4.94 5 98.8mg/L -1158514.94
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J15100404 -- 2015033918
Barium (Ba) 5.15 5 102mg/L -1307015.15
Boron (B) 5.04 5 101mg/L -1307015.04
Chromium (Cr) 4.99 5 99.8mg/L -1307014.99
Copper (Cu) 5.03 5 101mg/L -1307015.03
Iron (Fe) 8.14 5 103mg/L -1307018.14
Manganese (Mn) 5.17 5 102mg/L -1307015.17
Nickel (Ni) 4.99 5 99.8mg/L -1307014.99
Silver (Ag) 0.518 0.5 104mg/L -1307010.518
Zinc (Zn) 4.89 5 97.6mg/L -1307014.89
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J15100404 -- 2015033918
Barium (Ba) 5.16 5 102 0.0783mg/L -1307015.16
Boron (B) 5.02 5 100 0.439mg/L -1307015.02
Chromium (Cr) 4.98 5 99.5 0.341mg/L -1307014.98
Copper (Cu) 5 5 100 0.539mg/L -1307015
Page 21 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
Q15110132 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J15100404 -- 2015033918
Iron (Fe) 8.13 5 103 0.252mg/L -1307018.13
Manganese (Mn) 5.14 5 101 0.414mg/L -1307015.14
Nickel (Ni) 4.97 5 99.4 0.382mg/L -1307014.97
Silver (Ag) 0.517 0.5 103 0.117mg/L -1307010.517
Zinc (Zn) 4.87 5 97.3 0.328mg/L -1307014.87
Page 22 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
Q15110090 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As) 0.0222 ug/L -10.0222 1 < 1/2 RDL
Barium (Ba) -0.0126 ug/L -1-0.0126 1 < 1/2 RDL
Cadmium (Cd) 0.0029 ug/L -10.0029 1 < 1/2 RDL
Chromium (Cr) -0.0219 ug/L -1-0.0219 1 < 1/2 RDL
Copper (Cu) -0.021 ug/L -1-0.021 1 < 1/2 RDL
Lead (Pb) 0.0041 ug/L -10.0041 1 < 1/2 RDL
Nickel (Ni) -0.0973 ug/L -1-0.0973 1 < 1/2 RDL
Selenium (Se) 0.0116 ug/L -10.0116 1 < 1/2 RDL
Silver (Ag) 0.0022 ug/L -10.0022 1 < 1/2 RDL
Zinc (Zn) 0.055 ug/L -10.055 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As) 51.1 50 102ug/L -11585151.1
Barium (Ba) 53.2 50 106ug/L -11585153.2
Cadmium (Cd) 49.4 50 98.8ug/L -11585149.4
Chromium (Cr) 51.9 50 104ug/L -11585151.9
Copper (Cu) 51.2 50 102ug/L -11585151.2
Lead (Pb) 51.8 50 104ug/L -11585151.8
Nickel (Ni) 51.8 50 104ug/L -11585151.8
Selenium (Se) 53 50 106ug/L -11585153
Silver (Ag) 49.9 50 99.8ug/L -11585149.9
Zinc (Zn) 51.9 50 104ug/L -11585151.9
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J15100404 -- 2015033912
Arsenic (As) 50.7 50 101ug/L -13070150.7
Barium (Ba) 94.3 50 105ug/L -13070194.3
Cadmium (Cd) 49.4 50 98.6ug/L -13070149.4
Chromium (Cr) 52.2 50 93.9ug/L -13070152.2
Copper (Cu) 50.5 50 97.2ug/L -13070150.5
Lead (Pb) 51.5 50 103ug/L -13070151.5
Nickel (Ni) 50.9 50 95.6ug/L -13070150.9
Selenium (Se) 50.3 50 100ug/L -13070150.3
Silver (Ag) 47.9 50 95.8ug/L -13070147.9
Zinc (Zn) 54 50 91.5ug/L -13070154
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J15100404 -- 2015033912
Arsenic (As) 51.3 50 102 1.12ug/L -13070151.3
Page 23 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
Q15110090 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J15100404 -- 2015033912
Barium (Ba) 93.1 50 102 2.32ug/L -13070193.1
Cadmium (Cd) 49.6 50 99 0.445ug/L -13070149.6
Chromium (Cr) 52.5 50 94.5 0.701ug/L -13070152.5
Copper (Cu) 50 50 96.4 0.888ug/L -13070150
Lead (Pb) 51.3 50 102 0.37ug/L -13070151.3
Nickel (Ni) 51.5 50 96.8 1.27ug/L -13070151.5
Selenium (Se) 50 50 99.5 0.521ug/L -13070150
Silver (Ag) 47.9 50 95.8 0.0418ug/L -13070147.9
Zinc (Zn) 55.9 50 95.3 4.09ug/L -13070155.9
Page 24 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
Q15110137 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) 0.1 ug/L -10.1 1 < 1/2 RDL
Arsenic (As) -0.0008 ug/L -1-0.0008 1 < 1/2 RDL
Beryllium (Be) 0.0158 ug/L -10.0158 1 < 1/2 RDL
Cadmium (Cd) -0.0019 ug/L -1-0.0019 1 < 1/2 RDL
Cobalt (Co) 0.0023 ug/L -10.0023 1 < 1/2 RDL
Lead (Pb) -0.0162 ug/L -1-0.0162 1 < 1/2 RDL
Molybdenum (Mo) 0.0054 ug/L -10.0054 1 < 1/2 RDL
Selenium (Se) 0.0117 ug/L -10.0117 1 < 1/2 RDL
Thallium (Tl) Low Level -0.0352 ug/L -1-0.0352 0.2 < 1/2 RDL
Vanadium (V) Low Level -0.0244 ug/L -1-0.0244 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 51.3 50 103ug/L -11585151.3
Arsenic (As) 49.9 50 99.8ug/L -11585149.9
Beryllium (Be) 49.8 50 99.6ug/L -11585149.8
Cadmium (Cd) 49.6 50 99.2ug/L -11585149.6
Cobalt (Co) 50.7 50 101ug/L -11585150.7
Lead (Pb) 49.2 50 98.4ug/L -11585149.2
Molybdenum (Mo) 50.3 50 101ug/L -11585150.3
Selenium (Se) 49.8 50 99.6ug/L -11585149.8
Thallium (Tl) Low Level 47.6 50 95.2ug/L -11585147.6
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J15100405 -- 2015033922
Antimony (Sb) 53.4 50 107ug/L -13070153.4
Arsenic (As) 50.5 50 100ug/L -13070150.5
Beryllium (Be) 49.8 50 99.7ug/L -13070149.8
Cadmium (Cd) 49.1 50 98.1ug/L -13070149.1
Cobalt (Co) 50.2 50 99.7ug/L -13070150.2
Lead (Pb) 49.5 50 99ug/L -13070149.5
Molybdenum (Mo) 50.5 50 101ug/L -13070150.5
Selenium (Se) 52.8 50 95.7ug/L -13070152.8
Thallium (Tl) Low Level 48.3 50 96.5ug/L -13070148.3
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J15100405 -- 2015033922
Antimony (Sb) 52.2 50 104 2.22ug/L -13070152.2
Arsenic (As) 50 50 99.6 0.86ug/L -13070150
Beryllium (Be) 50.5 50 101 1.32ug/L -13070150.5
Page 25 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
Q15110137 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J15100405 -- 2015033922
Cadmium (Cd) 49 50 97.9 0.204ug/L -13070149
Cobalt (Co) 49.8 50 99 0.785ug/L -13070149.8
Lead (Pb) 50 50 99.9 0.905ug/L -13070150
Molybdenum (Mo) 50.2 50 100 0.598ug/L -13070150.2
Selenium (Se) 52.8 50 95.7 0.0836ug/L -13070152.8
Thallium (Tl) Low Level 49.1 50 98.1 1.64ug/L -13070149.1
Page 26 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
Q15110084 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J15100404 -- 2015033911
TDS 2.84mg/L -1214
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J15100404 -- 2015033912
TDS 0.887mg/L -1449
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 99mg/L -11090199
Page 27 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100404
Q15110150 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J15100218 -- 2015033087
TDS 2.35mg/L -1126
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J15100218 -- 2015033090
TDS 6.06mg/L -1187
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J15100218 -- 2015033091
TDS 1.92mg/L -1210
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 95mg/L -11090195
Page 28 of 30
Page 29 of 30
Page 30 of 30