Loading...
HomeMy WebLinkAbout4403_FrancisFarm_March2016_1stSemiAnnual_DIN26337_20160624Bunnell-Lammons Engineering,Inc. Trevor J.Benton,P.G.864-288-1265 trevor@blecorp.com Closed Francis Farms Landfill 44-03 .1600 Trevor J.Benton,P.G.Hydrogeologist 864-288-1265 06/23/2016 BLE BUNNELL-LAMMONS ENGINEERING, INC. GEOTECHNICAL, ENVIRONMENTAL AND CONSTRUCTION MATERIALS CONSULTANTS REPORT OF GROUNDWATER QUALITY RESULTS & STATISTICAL ANALYSIS FIRST SEMI-ANNUAL SAMPLING EVENT OF 2016 CLOSED FRANCIS FARM LANDFILL PERMIT NUMBER: 44-03 HAYWOOD COUNTY, NORTH CAROLINA Prepared For: HAYWOOD COUNTY SOLID WASTE MANAGEMENT 278 Recycle Road Clyde, North Carolina 28721 Prepared By: BUNNELL-LAMMONS ENGINEERING, INC. 6004 Ponder Court Greenville, South Carolina 29615 June 23, 2016 BLE Project Number J15-1957-48 BUNNELL-LAMMONS ENGINEERING, INC. GEOTECHNICAL, ENVIRONMENTAL AND CONSTRUCTION MATERIALS CONSULTANTS 6004 PONDERS COURT PHONE (864) 288-1265 GREENVILLE, SOUTH CAROLINA 29615 FAX (864) 288-4430 June 23, 2016 Haywood County Solid Waste Management 278 Recycle Road Clyde, North Carolina 28721 Attention: Mr. David B. Francis Solid Waste Administrator Subject: Report of Groundwater Quality Results & Statistical Analysis First Semi-Annual Sampling Event of 2016 Permit Number: 44-03 Haywood County, North Carolina BLE Project Number J15-1957-48 Dear Mr. Francis: As authorized, Bunnell-Lammons Engineering, Inc. (BLE) has performed the statistical analysis of groundwater quality data obtained from the subject site. The enclosed report describes the work performed and presents the results obtained with our conclusions. The purpose of this work was to statistically compare the laboratory analytical results of groundwater samples from the background monitoring wells to the downgradient monitoring wells at the subject closed municipal solid waste (MSW) landfill in accordance with Title 15A NCAC 13B .1632 (g), (h), and (i). This report of the sampling and statistical analysis has been prepared for submittal to the North Carolina Division of Waste Management (NCDWM) in accordance with Rule 15A NCAC 13B .1632 (j). We appreciate the opportunity to serve as your geological consultant on this project and look forward to working with you on future projects. If you have any questions, please contact us at (864) 288-1265. Sincerely, BUNNELL-LAMMONS ENGINEERING, INC. Trevor J. Benton, P.G. Mark S. Preddy, P.G. Senior Geologist Senior Geologist Licensed, North Carolina No. 2025 Licensed, North Carolina No. 1043 cc: Ms. Elizabeth Werner – NCDEQ Solid Waste Section, 401 Oberlin Road, Suite 150, Raleigh, North Carolina 27605 Closed Francis Farm Landfill – Haywood Co., NC June 23, 2016 Groundwater Statistics Report – First Event of 2016 BLE Project Number J15-1957-48 2 PROJECT INFORMATION The subject closed municipal solid waste landfill site is located in Haywood County, North Carolina, approximately two miles northeast of Waynesville on Francis Farm Road (Figure 1). The facility currently has a total of 30 groundwater monitoring wells. The landfill well network currently consists of one upgradient groundwater monitoring well (MW-12) and 29 downgradient wells installed at the facility as part of the assessment monitoring plan. On August 15, 2013, the NCDWM approved replacement of the previously existing surface water monitoring points designated SW-1, SW-2, and Blanton Branch. These new surface water sampling locations consist of one upgradient (US-1) and three downgradient (DS-1, DS-2, and DS-3) sampling points. BLE was retained by Haywood County to prepare the semi-annual sampling reports for 2016. Historical data from multiple sources and in multiple formats has been gathered and synthesized into this report. This report presents data from the first semi-annual sampling event in 2016 for the site. The water samples were collected and analyzed as required by North Carolina's regulations for operation of municipal solid waste landfills. This report incorporates water quality data collected from the site from February 1999 to March 2016 from the following sources:  29 sampling events for well MW-5;  11 sampling events for newly installed (2010) wells MW-6 through MW-12, and MW-15;  9 sampling events for newly installed (2011) wells MW-16 through MW-21;  7 sampling events for newly installed (2012) wells MW-16D, MW-19D, MW-20D, MW- 21, MW-22, MW-24, and MW-25;  5 sampling events for newly installed (2013) well MW-23D;  27 sampling events for surface water locations SW-1 and SW-2 (these are no longer sampled); and  6 sampling events for surface water locations US-1, DS-1, DS-2, and DS-3. As approved by the North Carolina Department of Environmental Quality (NCDEQ), monitoring wells MW-1, MW-1A, MW-2A, MW-3A, MW-4, MW-13, MW-14 and MW-14D were abandoned in December 2015. FIELD ACTIVITIES, SAMPLING, AND ANALYSIS Groundwater and surface water samples were collected for the first semi-annual sampling event of 2016 by personnel from Shealy Environmental Services, Inc. (Shealy) of Columbia, South Carolina during March 16-18, 2016. Groundwater samples were collected from each of the 23 groundwater monitoring well locations located on the site. Additionally, four on-site surface water locations were sampled during the event. The groundwater samples were analyzed in the laboratory for North Carolina’s Appendix II list of volatile organic compounds (VOCs), North Carolina Appendix I metals, pesticides, and cyanide and in the field for pH, specific conductance, turbidity, and temperature. The surface water samples were analyzed in the laboratory for North Carolina’s Appendix II list of VOCs and metals, and in the field for pH, specific conductance, and temperature. Closed Francis Farm Landfill – Haywood Co., NC June 23, 2016 Groundwater Statistics Report – First Event of 2016 BLE Project Number J15-1957-48 3 Summary tables of analytical results are attached in Appendix A (groundwater) and Appendix B (surface water). A copy of the Shealy laboratory and field data is included in Appendix C. The NCDEQ-approved sampling matrix for groundwater and surface water are included in Appendix C. GROUNDWATER FLOW The water level data collected during the groundwater sampling is presented in Table 1. A water table surface elevation contour map featuring the new survey elevation data is presented as Figure 2 along with generalized groundwater flow directions. SUMMARY OF LABORATORY RESULTS Groundwater Total metal detections in groundwater during the current sampling event included:  total barium (22 wells);  total chromium (2 wells);  total copper (1 well); and  total zinc (8 wells). VOC detections in groundwater included:  benzene (2 wells);  chlorobenzene (1 well);  1,2-dichlorobenzene (3 wells);  1,4-dichlorobenzene (4 wells);  1,1-dichloroethane (10 wells);  1,2-dichloroethane (2 wells);  cis-1,2-dichloroethene (8 wells);  tetrachloroethene (2 wells); and  trichloroethene (3 wells). The concentrations of the following constituents were detected above North Carolina’s maximum contaminant levels1 (MCLs):  total chromium (MW-16D and MW-17);  benzene (MW-5 and MW-25);  1,1-dichloroethane (MW-11 and MW-25);  1,2-dichloroethane (MW-7 and MW-19); and  tetrachloroethene (MW-5 and MW-25). 1 North Carolina Department of Environmental Quality, Classifications of Water Quality Standards, Section 15A NCAC 2L.202, December 1, 2005. Closed Francis Farm Landfill – Haywood Co., NC June 23, 2016 Groundwater Statistics Report – First Event of 2016 BLE Project Number J15-1957-48 4 Summary tables of the current and historical detected concentrations in groundwater are included in Appendix A. The laboratory data sheets are included in Appendix C. Surface Water Concentrations of total barium (4 locations) were detected in the surface water samples during the current sampling event. None of the concentrations were above established North Carolina surface water2 MCL. Additionally, no VOCs were detected in the surface water samples. Summary tables of the current and historical detected concentrations in surface water are included in Appendix B. the laboratory data sheets are included in Appendix C. STATISTICAL METHODS PERFORMED The purpose of performing statistical analysis of groundwater quality data is to determine if a release of leachate has occurred from the landfill cells to the groundwater at the site. The US EPA has prepared a guidance document for evaluating groundwater quality data titled Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities – Unified Guidance (March 2009). The procedures and methodology used for data analysis of this project are consistent with this US EPA guidance document, and meet or exceed the performance criteria specified in the North Carolina solid waste management rules Title 15A NCAC 13B .1632(g-i). Four methods of statistical analysis were performed depending on the number of detected concentrations and the distribution of the data for a specific compound, as follows: 1. If 15% to 90% of the data were not detected, the one-way non-parametric analysis of variance (ANOVA) Kruskal-Wallis rank-sum test was performed; 2. If less than 15% of the data were not detected, and if the data was normally distributed and homogeneous, then one-way parametric ANOVA was performed. If the data were not normally distributed and homogeneous, then a non-parametric type test was used (Kruskal-Wallis); 3. Alternatively, if greater than 50% of the data were not detected, Poisson Prediction Limits may be performed, or if less than 50% of the data were not detected, Normal Prediction Limits may be performed; and 4. Intrawell comparisons were performed, if necessary, using Shewhart-CUSUM control charts. It is important to note that the nature of the statistical procedures applied to the data frequently leads to false positives, which result in statistically significant increases (SSI). These false positives are inherent to the statistical procedures themselves and are a result of the insufficiency of the mathematical equations to represent the multiple factors affecting the groundwater quality variability at a given site. Furthermore, a clear distinction should be made between the terms “calculated SSI” and “validated SSI.” A calculated SSI is the result of the application of mathematical equations to evaluate variability of water quality data over time by mathematical means. A validated SSI is determined when, based on a review of the data set as a whole, it can be concluded that the 2 North Carolina Department of Environmental Quality, “Redbook”, Surface Waters and Wetlands Standards, Section 15A NCAC 02B.0100, .0200, and .0300, May 1, 2007. Closed Francis Farm Landfill – Haywood Co., NC June 23, 2016 Groundwater Statistics Report – First Event of 2016 BLE Project Number J15-1957-48 5 calculated statistical significance might be a function of a release of leachate to groundwater, and not a function of natural variability and/or other conditions. SUMMARY OF STATISTICAL RESULTS The statistical analysis was performed on constituents that have been historically detected above the laboratory reporting limit, and have been detected during the current sampling event. The statistical results summarized on Table 2 and included in Appendix D indicate that: 1. The Poisson Prediction Limit test performed for total antimony, total arsenic, total beryllium, total cadmium, total lead, total selenium, total silver, total thallium, benzene, carbon disulfide, chlorobenzene, chloroethane, chloroform, 1,4-dichlorobenzene, 1,2-dichloroethane, 1,1- dichloroethene, cis-1,3-dichloropropene, dichloromethane, trichlorofluoromethane, total xylenes, and naphthalene did not calculate SSIs. However, the Poisson Prediction Limit and Wilcoxon tests calculated SSIs for 1,2-dichlorobenzene (MW-11 and MW-15). 2. The Kruskal-Wallis tests used for total chromium, total cobalt, total copper, total nickel, total vanadium, and total zinc did not calculate SSIs. However, the Kruskal-Wallis and Wilcoxon tests calculated SSIs for 1,1-dichloroethane (MW-5, MW-7, MW-10, MW-11, MW-16D, MW- 19, MW-19D, and MW-25), cis-1,2-dichloroethene (MW-7, MW-10, MW-11, MW-15, MW- 19, and MW-25), tetrachloroethene (MW-5 and MW-25), and trichloroethene (MW-5 and MW- 25). 3. The parametric ANOVA test used for total barium did not calculate an SSI. CONCLUSION Concentrations of total metals (groundwater and surface water) and VOCs (groundwater) were detected at the site during the current sampling event. Groundwater concentrations of total chromium (MW-16D and MW-17), benzene (MW-5 and MW-25), 1,1-dichloroethane (MW-11 and MW-25), 1,2-dichloroethane (MW-7 and MW-19) and tetrachloroethene (MW-5 and MW-25) were detected above North Carolina’s MCL in several monitoring wells. The detected concentrations of total metals are most likely naturally occurring and related to sample turbidity. Metal cations typically adsorb to the surface of platy particles (clay and silt). Therefore, turbidity of the groundwater and surface water samples will relate to detected concentrations of the metal cations. Consequently, the metal concentrations detected should be considered natural background concentrations. A NCDEQ-approved groundwater assessment is currently in progress at the facility. Four phases of well installation and sampling are complete and have been reported to the NCDEQ. Phase I included installation of monitoring wells MW-6 through MW-15. Phase II included installation of monitoring wells MW-16 through MW-21. Phase III included installation of monitoring wells MW-14D through MW-25. The Phase IV well installation was conducted in December 2013 and included installation of monitoring well MW-23D. The laboratory analyses results contained herein includes the assessment wells from all four phases, plus the previously existing compliance wells. Closed Francis Farm Landfill – Haywood Co., NC June 23, 2016 Groundwater Statistics Report – First Event of 2016 BLE Project Number J15-1957-48 6 Additionally, wells MW-1, MW-1A, MW-2A, MW-3A, MW-4, MW-13, MW-14 and MW-14D were abandoned in December 2015. The approved groundwater sampling matrix at the site includes the Appendix II list of VOCs and Appendix I metals, pesticides, and cyanide. The next regularly scheduled groundwater sampling event will be conducted in August 2016. TABLES TABLE 1 GROUNDWATER MONITORING WELL CONSTRUCTION AND GROUNDWATER ELEVATION DATA Closed Francis Farm Landfill Haywood County, North Carolina Permit Number 44-03 BLE Project Number J15-1957-48 March 16-17, 2016 Well Northing Easting Meas. Pt.Gnd. Surface *Depth to Depth to Water Total Borehole Screen Well Well Top of Rock Top of Well Location (feet)(feet)Elevation Elevation Water (bgs)Water (bmp)Elevation Depth (bgs)Depth (bgs)Type Monitors Depth (bgs)Rock Elev. MW-1 On-Site 662,529.13 822,317.14 2,666.59 2,663.72 A A A UK UK -UK UK -UK UK UK UK UK MW-1A On-Site 662,590.73 822,083.15 2,690.88 2,687.97 A A A UK UK -UK UK -UK UK UK UK UK MW-2A On-Site 662,347.08 822,814.69 2,643.78 2,640.98 A A A 27.0 12.0 -27.0 2,629.0 -2,614.0 II PWR/BR 18.0 2,623.0 MW-3A On-Site 661,921.62 823,026.22 2,674.29 2,671.59 A A A UK UK -UK UK -UK UK UK UK UK MW-4 On-Site 661,420.29 822,245.39 2,789.47 2,786.88 A A A UK UK -UK UK -UK UK UK UK UK MW-5 On-Site 661,286.31 822,167.91 2,797.08 2,797.37 72.41 72.12 2,724.96 94.0 73.1 -88.1 2,724.3 -2,709.3 II PWR 89.0 2,708.4 Groundwater Monitoring Wells MW-6 through MW-25 Installed by BLE MW-6 Off-Site 662,941.12 822,167.78 2,612.63 2,613.03 5.85 5.45 2,607.18 12.5 2.3 -12.3 2,610.7 -2,600.7 II Res/Collv 12.5 2,600.5 MW-7 Off-Site 662,800.72 822,584.39 2,621.33 2,621.48 6.44 6.29 2,615.04 24.0 4.0 -19.0 2,617.5 -2,602.5 II Collv/Allv NE NE MW-8 Off-Site 662,619.60 822,989.68 2,620.05 2,620.25 5.51 5.31 2,614.74 19.0 3.0 -13.0 2,617.3 -2,607.3 II Alluvial NE NE MW-9 Off-Site 662,309.84 823,295.25 2,618.67 2,619.19 2.68 2.16 2,616.51 19.0 2.0 -12.0 2,617.2 -2,607.2 II Alluvial NE NE MW-10 Off-Site 661,947.33 823,365.59 2,623.60 2,623.96 2.10 1.74 2,621.86 15.0 2.0 -12.0 2,622.0 -2,612.0 II Alluvial NE NE MW-11 On-Site 661,509.39 822,572.73 2,756.22 2,756.46 78.58 78.34 2,677.88 100.0 70.8 -85.8 2,685.7 -2,670.7 II BR 71.0 2,685.5 MW-12 Off-Site 661,078.94 822,142.39 2,803.11 2,800.28 68.34 71.17 2,731.94 90.0 64.8 -79.8 2,735.5 -2,720.5 II BR 64.0 2,736.3 MW-13 On-Site 661,377.43 821,791.88 2,799.14 2,799.51 A A A 127.0 74.0 -89.0 2,725.5 -2,710.5 II PWR/BR 81.0 2,718.5 MW-14 On-Site 661,894.81 821,755.37 2,770.34 2,770.64 A A A 120.0 93.8 -108.8 2,676.8 -2,661.8 II BR 33.0 2,737.6 MW-14D On-Site 661,878.59 821,754.85 2,771.63 2,772.05 A A A 250.5 202.0 -212.0 2,570.0 -2,560.0 II BR 41.0 2,731.0 MW-15 On-Site 662,338.59 821,896.86 2,719.57 2,716.89 78.02 80.70 2,638.87 163.0 75.8 -90.8 2,641.1 -2,626.1 II BR 19.0 2,697.9 MW-16 Off-Site 661,203.62 821,457.75 2,716.16 2,716.29 54.54 54.41 2,661.75 70.0 54.8 -69.8 2,661.5 -2,646.5 II PWR/BR 63.0 2,653.3 MW-16D Off-Site 661,192.49 821,467.73 2,716.28 2,716.57 70.88 70.59 2,645.69 150.0 116.0 -126.0 2,600.6 -2,590.6 II BR 81.0 2,635.6 MW-17 Off-Site 661,739.15 821,178.09 2,664.77 2,665.07 48.70 48.40 2,616.37 73.0 49.8 -64.8 2,615.3 -2,600.3 II PWR/BR 63.0 2,602.1 MW-18 Off-Site 662,150.91 821,256.31 2,620.91 2,620.93 24.07 24.05 2,596.86 41.0 25.8 -40.8 2,595.1 -2,580.1 II BR 22.0 2,598.9 MW-19 Off-Site 662,965.29 822,624.55 2,615.08 2,615.29 6.84 6.63 2,608.45 21.0 5.5 -20.5 2,609.8 -2,594.8 II Allv/Res NE NE MW-19D Off-Site 662,952.84 822,617.92 2,615.33 2,615.62 6.57 6.28 2,609.05 59.0 53.9 -58.9 2,561.7 -2,556.7 II PWR NE NE MW-20 Off-Site 661,973.29 823,503.41 2,621.94 2,622.13 2.18 1.99 2,619.95 15.5 5.3 -15.3 2,616.8 -2,606.8 II Alluvial NE NE MW-20D Off-Site 661,973.43 823,494.68 2,621.94 2,622.12 0.98 0.80 2,621.14 69.0 60.0 -65.0 2,562.1 -2,557.1 II PWR NE NE MW-21 Off-Site 661,424.40 823,203.28 2,658.37 2,658.72 17.74 17.39 2,640.98 36.0 18.8 -33.8 2,639.9 -2,624.9 II Residuum NE NE MW-22 Off-Site 661,046.30 820,724.07 2,599.86 2,600.00 1.92 1.79 2,598.07 25.0 4.0 -24.0 2,596.0 -2,576.0 II Alluvial NE NE MW-23 Off-Site 663,169.77 822,719.36 2,611.43 2,611.63 1.94 1.75 2,609.68 24.0 3.8 -23.8 2,607.8 -2,587.8 II Alluvial NE NE MW-23D Off-Site 663,182.53 822,725.71 2,611.52 2,611.75 2.28 2.05 2,609.47 62.0 53.0 -58.0 2,558.8 -2,553.8 III BR 37.0 2,574.8 MW-24 Off-Site 662,019.81 823,641.42 2,625.80 2,626.04 4.03 3.79 2,622.01 35.0 7.5 -27.5 2,618.5 -2,598.5 II Collv/PWR/BR 15.0 2,611.0 MW-25 Off-Site 661,488.76 822,382.32 2,756.31 2,756.67 130.76 130.40 2,625.91 259.5 249.3 -259.3 2,507.4 -2,497.4 II BR 62.0 2,694.7 Notes: All survey data provided by McGill Associates, all units in feet.Measuring Point Elevation is top of casing BR & PWR = Bedrock & Partially Weathered Rock *DTW from bgs values have been calculated from survey data provided by McGill Associates.II = Type II well Res = Residuum All values shown to the nearest 0.1-ft have been rounded.III = Type III well Collv = Colluvium Water levels measured on 8-24-15 by Shealy Environmental Services, Inc.NE = Not encountered Allv = Alluvium MW-1, -1A, -2A, -3A, -4, -5 installed by others. MW-6 through MW-25 installed by BLE.UK = Unknown, information is not available NP = Well Not Present at Time of Measurement Screen Elevation Table 1 GWM updated of 1957-48 Francis Farm GW Stats 1st 2016.xlsm Prepared by: IAI Checked by: DSW TABLE 2 SUMMARY OF STATISTICAL ANALYSIS RESULTS Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Chemical/Percent Primary Primary Secondary Secondary SSI (1)SSI Concentration Above MCL (2) Compound ND Statistical Test Pass/Fail Statistical Test Pass/Fail Calculated During Current Event Total Antimony 99.5%Poisson Prediction Limits Pass --No - Total Arsenic 95.1%Poisson Prediction Limits Pass --No - Total Barium 0.9%ANOVA Pass --No - Total Beryllium 97.6%Poisson Prediction Limits Pass --No - Total Cadmium 98.2%Poisson Prediction Limits Pass --No - Total Chromium 70.7%Kruskal-Wallis Pass --No - Total Cobalt 84.1%Kruskal-Wallis Pass --No - Total Copper 81.6%Kruskal-Wallis Pass --No - Total Lead 92.4%Poisson Prediction Limits Pass --No - Total Nickel 78.9%Kruskal-Wallis Pass --No - Total Selenium 98.7%Poisson Prediction Limits Pass --No - Total Silver 99.6%Poisson Prediction Limits Pass --No - Total Thallium 99.5%Poisson Prediction Limits Pass --No - Total Vanadium 73.9%Kruskal-Wallis Pass --No - Total Zinc 56.0%Kruskal-Wallis Pass --No - Benzene 88.7%Poisson Prediction Limits Pass --No - Carbon Disulfide 99.1%Poisson Prediction Limits Pass --No - Chlorobenzene 93.7%Poisson Prediction Limits Pass --No - Chloroethane 87.8%Poisson Prediction Limits Pass --No - Chloroform 99.1%Poisson Prediction Limits Pass --No - 1,2-Dichlorobenzene 79.7%Poisson Prediction Limits Fail Shewhart-CUSUM/Wilcoxon Fail Yes (MW-11, -15)No 1,4-Dichlorobenzene 79.7%Poisson Prediction Limits Pass --No - 1,1-Dichloroethane 55.9%Kruskal-Wallis Fail Shewhart-CUSUM/Wilcoxon Fail Yes ( MW-5, -7, -10, -11, -16D, -19, -19D, -25)Yes (MW-11, -25) 1,2-Dichloroethane 88.7%Poisson Prediction Limits Pass --No - 1,1-Dichloroethene 99.5%Poisson Prediction Limits Pass --No - cis-1,2-Dichloroethene 57.7%Kruskal-Wallis Fail Shewhart-CUSUM/Wilcoxon Fail Yes (MW-7, -10, -11, -15, -19, -25)No cis-1,3-Dichloropropene 99.5%Poisson Prediction Limits Pass --No - Dichloromethane 94.6%Poisson Prediction Limits Pass --No - Tetrachloroethene 85.1%Kruskal-Wallis Fail Shewhart-CUSUM/Wilcoxon Fail Yes (MW-5, -25)Yes (MW-5, -25) Trichloroethene 85.1%Kruskal-Wallis Fail Shewhart-CUSUM/Wilcoxon Fail Yes (MW-5, -25)No Trichlorofluoromethane 99.1%Poisson Prediction Limits Pass --No - Total Xylenes 98.6%Poisson Prediction Limits Pass --No - Naphthalene 97.9%Poisson Prediction Limits Pass --No - Notes: 1. SSI = Statistically Significant Increase 2. MCL = Maximum Contaminant Level Table 2 of 1957-48 Francis Farm GW Stats 1st 2016.xlsm Prepared by: IAI Checked by: MSP FIGURES R A C C O O N C R E E K R A C C O O N C R E E K R A T C L I F F E C O V E B R A N C H UNNAMED TRIBUTARY BL A N T O N B R A N C H RATCLIFFE C O V E B R A N C H MM-10 MM-11 MM-12 SM-1a SM-1c SM-1b SM-3 MM-7 MM-9 MM-3 MM-13 MM-2 MM-5 MM-4 R A T C L I F F E C O V E B R A N C H ( F L O W ) (FL O W ) ( FLOW) ( F L O W ) ( F L O W ) ( F L O W ) ( F L O W ) 2621.14 MM-5 SM-1a SM-2 MM-8 MM-1 MM-6 MW-3A ABANDONED MW-3A MW-4 MW-5 MW-25 MW-1A * * * 2621.86 MW-2A MW-1 APPENDICES APPENDIX A SUMMARY TABLES OF GROUNDWATER ANALYTICAL RESULTS Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (2-18-1999) TEST UNITS MRL MCL MW-12 MW- 5A MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Specific Conductance mmhos/cm 1 NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Temperature °C -NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Turbidity NTU 0.1 NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Antimony (Sb)mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Arsenic (As)mg/l 5 50NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Barium (Ba)mg/l 100 2000NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Beryllium (Be)mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Cadmium (Cd)mg/l 10 1.75NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Chromium (Cr)mg/l 20 50NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Cobalt (Co)mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Copper (Cu)mg/l NT 1000NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Lead (Pb)mg/l 100 15NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Mercury (Hg)mg/l 0.2 1.05NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Nickel (Ni)mg/l 50 100NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Selenium (Se)mg/l 5 50NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Silver (Ag)mg/l 50 17.5NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Thallium (Tl)mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Vanadium (V)mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Zinc (Zn)mg/l NT 1050NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Acetone mg/l NT 700NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acrylonitrile mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Benzene mg/l NT 1NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromochloromethane mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromodichloromethane mg/l NT 0.56NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromoform mg/l NT 0.19NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Carbon Disulfide mg/l NT 700NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromomethane (Methylbromide)mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Carbon tetrachloride mg/l NT 0.269NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chlorobenzene (mono)mg/l NT 50NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chloroethane mg/l NT 2800NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chloroform mg/l NT 70NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chloromethane (Methylchloride)mg/l NT 2.6NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Dibromochloromethane mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l NT 0.025NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l NT 0.00047NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Dibromomethane mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dichlorobenzene mg/l NT 24NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,4-Dichlorobenzene mg/l NT 1.4NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT trans-1,4-Dichloro-2-butene mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1-Dichloroethane mg/l NT 70NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dichloroethane mg/l NT 0.38NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1-Dichloroethene (-ethylene)mg/l NT 7NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l NT 70NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l NT 100NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dichloropropane mg/l NT 0.51NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l NT 0.19NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l NT 0.19NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Ethylbenzene mg/l NT 550NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 2-Hexanone mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Iodomethane mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Dichloromethane (Methylene chloride)mg/l NT 4.6NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l NT 4200NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 4-Methyl-2-Pentanone mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Styrene mg/l NT 100NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,1,2-Tetrachloroethane mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,2,2-Tetrachloroethane mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Tetrachloroethene (-ethylene)mg/l NT 0.7NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Toluene mg/l NT 1000NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,1-Trichloroethane mg/l NT 200NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,2-Trichloroethane mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Trichloroethene (-ethylene)mg/l NT 2.8NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Trichlorofluoromethane mg/l NT 2100NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2,3-Trichloropropane mg/l NT 0.005NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Vinyl acetate mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Vinyl chloride mg/l NT 0.015NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Xylenes mg/l NT 530NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (2-18-1999) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (8-16-1999) TEST UNITS MRL MCL MW-12 MW- 5A MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Specific Conductance mmhos/cm 1 NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Temperature °C -NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Turbidity NTU 0.1 NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Antimony (Sb)mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Arsenic (As)mg/l 5 50NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Barium (Ba)mg/l 100 2000NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Beryllium (Be)mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Cadmium (Cd)mg/l 10 1.75NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Chromium (Cr)mg/l 20 50NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Cobalt (Co)mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Copper (Cu)mg/l NT 1000NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Lead (Pb)mg/l 100 15NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Mercury (Hg)mg/l 0.2 1.05NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Nickel (Ni)mg/l 50 100NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Selenium (Se)mg/l 5 50NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Silver (Ag)mg/l 50 17.5NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Thallium (Tl)mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Vanadium (V)mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Zinc (Zn)mg/l NT 1050NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Acetone mg/l NT 700NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acrylonitrile mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Benzene mg/l NT 1NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromochloromethane mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromodichloromethane mg/l NT 0.56NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromoform mg/l NT 0.19NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Carbon Disulfide mg/l NT 700NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromomethane (Methylbromide)mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Carbon tetrachloride mg/l NT 0.269NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chlorobenzene (mono)mg/l NT 50NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chloroethane mg/l NT 2800NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chloroform mg/l NT 70NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chloromethane (Methylchloride)mg/l NT 2.6NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Dibromochloromethane mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l NT 0.025NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l NT 0.00047NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Dibromomethane mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dichlorobenzene mg/l NT 24NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,4-Dichlorobenzene mg/l NT 1.4NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT trans-1,4-Dichloro-2-butene mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1-Dichloroethane mg/l NT 70NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dichloroethane mg/l NT 0.38NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1-Dichloroethene (-ethylene)mg/l NT 7NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l NT 70NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l NT 100NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dichloropropane mg/l NT 0.51NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l NT 0.19NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l NT 0.19NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Ethylbenzene mg/l NT 550NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 2-Hexanone mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Iodomethane mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Dichloromethane (Methylene chloride)mg/l NT 4.6NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l NT 4200NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 4-Methyl-2-Pentanone mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Styrene mg/l NT 100NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,1,2-Tetrachloroethane mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,2,2-Tetrachloroethane mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Tetrachloroethene (-ethylene)mg/l NT 0.7NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Toluene mg/l NT 1000NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,1-Trichloroethane mg/l NT 200NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,2-Trichloroethane mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Trichloroethene (-ethylene)mg/l NT 2.8NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Trichlorofluoromethane mg/l NT 2100NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2,3-Trichloropropane mg/l NT 0.005NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Vinyl acetate mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Vinyl chloride mg/l NT 0.015NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Xylenes mg/l NT 530NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (8-16-1999) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (2-14-2000) TEST UNITS MRL MCL MW-12 MW- 5A MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Specific Conductance mmhos/cm 1 NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Temperature °C -NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Turbidity NTU 0.1 NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Antimony (Sb)mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Arsenic (As)mg/l 5 50NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Barium (Ba)mg/l 100 2000NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Beryllium (Be)mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Cadmium (Cd)mg/l 10 1.75NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Chromium (Cr)mg/l 20 50NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Cobalt (Co)mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Copper (Cu)mg/l NT 1000NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Lead (Pb)mg/l 100 15NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Mercury (Hg)mg/l 0.2 1.05NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Nickel (Ni)mg/l 50 100NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Selenium (Se)mg/l 5 50NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Silver (Ag)mg/l 50 17.5NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Thallium (Tl)mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Vanadium (V)mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Zinc (Zn)mg/l NT 1050NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Acetone mg/l NT 700NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acrylonitrile mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Benzene mg/l NT 1NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromochloromethane mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromodichloromethane mg/l NT 0.56NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromoform mg/l NT 0.19NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Carbon Disulfide mg/l NT 700NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromomethane (Methylbromide)mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Carbon tetrachloride mg/l NT 0.269NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chlorobenzene (mono)mg/l NT 50NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chloroethane mg/l NT 2800NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chloroform mg/l NT 70NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chloromethane (Methylchloride)mg/l NT 2.6NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Dibromochloromethane mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l NT 0.025NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l NT 0.00047NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Dibromomethane mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dichlorobenzene mg/l NT 24NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,4-Dichlorobenzene mg/l NT 1.4NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT trans-1,4-Dichloro-2-butene mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1-Dichloroethane mg/l NT 70NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dichloroethane mg/l NT 0.38NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1-Dichloroethene (-ethylene)mg/l NT 7NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l NT 70NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l NT 100NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dichloropropane mg/l NT 0.51NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l NT 0.19NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l NT 0.19NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Ethylbenzene mg/l NT 550NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 2-Hexanone mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Iodomethane mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Dichloromethane (Methylene chloride)mg/l NT 4.6NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l NT 4200NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 4-Methyl-2-Pentanone mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Styrene mg/l NT 100NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,1,2-Tetrachloroethane mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,2,2-Tetrachloroethane mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Tetrachloroethene (-ethylene)mg/l NT 0.7NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Toluene mg/l NT 1000NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,1-Trichloroethane mg/l NT 200NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,2-Trichloroethane mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Trichloroethene (-ethylene)mg/l NT 2.8NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Trichlorofluoromethane mg/l NT 2100NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2,3-Trichloropropane mg/l NT 0.005NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Vinyl acetate mg/l NT NENP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Vinyl chloride mg/l NT 0.015NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Xylenes mg/l NT 530NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (2-14-2000) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (8-14-2000) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Specific Conductance mmhos/cm 1 NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Temperature °C -NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Turbidity NTU 0.1 NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Antimony (Sb)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Arsenic (As)mg/l 5 50NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Barium (Ba)mg/l 100 2000NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Beryllium (Be)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Cadmium (Cd)mg/l 10 1.75NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Chromium (Cr)mg/l 20 50NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Cobalt (Co)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Copper (Cu)mg/l NT 1000NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Lead (Pb)mg/l 100 15NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Mercury (Hg)mg/l 0.2 1.05NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Nickel (Ni)mg/l 50 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Selenium (Se)mg/l 5 50NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Silver (Ag)mg/l 50 17.5NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 3 Total Thallium (Tl)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Vanadium (V)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Zinc (Zn)mg/l NT 1050NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acetone mg/l NT 700NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acrylonitrile mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Benzene mg/l NT 1NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromochloromethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromodichloromethane mg/l NT 0.56NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromoform mg/l NT 0.19NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Carbon Disulfide mg/l NT 700NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromomethane (Methylbromide)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Carbon tetrachloride mg/l NT 0.269NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chlorobenzene (mono)mg/l NT 50NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chloroethane mg/l NT 2800NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chloroform mg/l NT 70NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chloromethane (Methylchloride)mg/l NT 2.6NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Dibromochloromethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l NT 0.025NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l NT 0.00047NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Dibromomethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dichlorobenzene mg/l NT 24NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,4-Dichlorobenzene mg/l NT 1.4NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT trans-1,4-Dichloro-2-butene mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1-Dichloroethane mg/l NT 70NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dichloroethane mg/l NT 0.38NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1-Dichloroethene (-ethylene)mg/l NT 7NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l NT 70NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l NT 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dichloropropane mg/l NT 0.51NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l NT 0.19NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l NT 0.19NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Ethylbenzene mg/l NT 550NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 2-Hexanone mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Iodomethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Dichloromethane (Methylene chloride)mg/l NT 4.6NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l NT 4200NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 4-Methyl-2-Pentanone mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Styrene mg/l NT 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,1,2-Tetrachloroethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,2,2-Tetrachloroethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Tetrachloroethene (-ethylene)mg/l NT 0.7NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Toluene mg/l NT 1000NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,1-Trichloroethane mg/l NT 200NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,2-Trichloroethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Trichloroethene (-ethylene)mg/l NT 2.8NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Trichlorofluoromethane mg/l NT 2100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2,3-Trichloropropane mg/l NT 0.005NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Vinyl acetate mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Vinyl chloride mg/l NT 0.015NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Xylenes mg/l NT 530NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (8-14-2000) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (3-19-2001) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NENP 5.8 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Specific Conductance mmhos/cm 1 NENP 130 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Temperature °C -NENP 12.1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Turbidity NTU 0.1 NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Antimony (Sb)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Arsenic (As)mg/l 5 50NP 11 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Barium (Ba)mg/l 100 2000NP 2000 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Beryllium (Be)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Cadmium (Cd)mg/l 10 1.75NP 18 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Chromium (Cr)mg/l 20 50NP 140 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Cobalt (Co)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Copper (Cu)mg/l NT 1000NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Lead (Pb)mg/l 100 15NP 38 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Mercury (Hg)mg/l 0.2 1.05NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Nickel (Ni)mg/l 50 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Selenium (Se)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Silver (Ag)mg/l 50 17.5NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Thallium (Tl)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Vanadium (V)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Zinc (Zn)mg/l NT 1050NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Acetone mg/l NT 700NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acrylonitrile mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Benzene mg/l NT 1NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromochloromethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromodichloromethane mg/l NT 0.56NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromoform mg/l NT 0.19NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Carbon Disulfide mg/l NT 700NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromomethane (Methylbromide)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Carbon tetrachloride mg/l NT 0.269NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chlorobenzene (mono)mg/l NT 50NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chloroethane mg/l NT 2800NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chloroform mg/l NT 70NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chloromethane (Methylchloride)mg/l NT 2.6NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Dibromochloromethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l NT 0.025NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l NT 0.00047NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Dibromomethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dichlorobenzene mg/l NT 24NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,4-Dichlorobenzene mg/l NT 1.4NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT trans-1,4-Dichloro-2-butene mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1-Dichloroethane mg/l NT 70NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dichloroethane mg/l NT 0.38NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1-Dichloroethene (-ethylene)mg/l NT 7NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l NT 70NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l NT 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dichloropropane mg/l NT 0.51NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l NT 0.19NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l NT 0.19NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Ethylbenzene mg/l NT 550NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 2-Hexanone mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Iodomethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Dichloromethane (Methylene chloride)mg/l NT 4.6NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l NT 4200NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 4-Methyl-2-Pentanone mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Styrene mg/l NT 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,1,2-Tetrachloroethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,2,2-Tetrachloroethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Tetrachloroethene (-ethylene)mg/l NT 0.7NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Toluene mg/l NT 1000NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,1-Trichloroethane mg/l NT 200NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,2-Trichloroethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Trichloroethene (-ethylene)mg/l NT 2.8NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Trichlorofluoromethane mg/l NT 2100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2,3-Trichloropropane mg/l NT 0.005NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Vinyl acetate mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Vinyl chloride mg/l NT 0.015NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Xylenes mg/l NT 530NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (3-19-2001) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (8-27-2002) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NENP 5.83 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Specific Conductance mmhos/cm 1 NENP 170 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Temperature °C -NENP 14.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Turbidity NTU 0.1 NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Antimony (Sb)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Arsenic (As)mg/l 5 50NP 25 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Barium (Ba)mg/l 100 2000NP 2800 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Beryllium (Be)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Cadmium (Cd)mg/l 10 1.75NP 21 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Chromium (Cr)mg/l 20 50NP 210 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Cobalt (Co)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Copper (Cu)mg/l NT 1000NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Lead (Pb)mg/l 100 15NP 47 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Mercury (Hg)mg/l 0.2 1.05NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Nickel (Ni)mg/l 50 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Selenium (Se)mg/l 5 50NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Silver (Ag)mg/l 50 17.5NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Thallium (Tl)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Vanadium (V)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Zinc (Zn)mg/l NT 1050NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acetone mg/l NT 700NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acrylonitrile mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Benzene mg/l NT 1NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromochloromethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromodichloromethane mg/l NT 0.56NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromoform mg/l NT 0.19NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Carbon Disulfide mg/l NT 700NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromomethane (Methylbromide)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Carbon tetrachloride mg/l NT 0.269NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chlorobenzene (mono)mg/l NT 50NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chloroethane mg/l NT 2800NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chloroform mg/l NT 70NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chloromethane (Methylchloride)mg/l NT 2.6NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Dibromochloromethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l NT 0.025NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l NT 0.00047NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Dibromomethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dichlorobenzene mg/l NT 24NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,4-Dichlorobenzene mg/l NT 1.4NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT trans-1,4-Dichloro-2-butene mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1-Dichloroethane mg/l NT 70NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dichloroethane mg/l NT 0.38NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1-Dichloroethene (-ethylene)mg/l NT 7NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l NT 70NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l NT 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dichloropropane mg/l NT 0.51NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l NT 0.19NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l NT 0.19NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Ethylbenzene mg/l NT 550NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 2-Hexanone mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Iodomethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Dichloromethane (Methylene chloride)mg/l NT 4.6NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l NT 4200NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 4-Methyl-2-Pentanone mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Styrene mg/l NT 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,1,2-Tetrachloroethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,2,2-Tetrachloroethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Tetrachloroethene (-ethylene)mg/l NT 0.7NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Toluene mg/l NT 1000NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,1-Trichloroethane mg/l NT 200NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,2-Trichloroethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Trichloroethene (-ethylene)mg/l NT 2.8NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Trichlorofluoromethane mg/l NT 2100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2,3-Trichloropropane mg/l NT 0.005NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Vinyl acetate mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Vinyl chloride mg/l NT 0.015NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Xylenes mg/l NT 530NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (8-27-2002) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (2-24-2003) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NENP 5.59 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Specific Conductance mmhos/cm 1 NENP 165 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Temperature °C -NENP 12.2 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Turbidity NTU 0.1 NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Antimony (Sb)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Arsenic (As)mg/l 5 50NP 23 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Barium (Ba)mg/l 100 2000NP 2500 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Beryllium (Be)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Cadmium (Cd)mg/l 10 1.75NP 19 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Chromium (Cr)mg/l 20 50NP 200 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Cobalt (Co)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Copper (Cu)mg/l NT 1000NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Lead (Pb)mg/l 100 15NP 41 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Mercury (Hg)mg/l 0.2 1.05NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Nickel (Ni)mg/l 50 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Selenium (Se)mg/l 5 50NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Silver (Ag)mg/l 50 17.5NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 3.3 Total Thallium (Tl)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Vanadium (V)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Zinc (Zn)mg/l NT 1050NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acetone mg/l NT 700NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acrylonitrile mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Benzene mg/l NT 1NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromochloromethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromodichloromethane mg/l NT 0.56NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromoform mg/l NT 0.19NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Carbon Disulfide mg/l NT 700NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Bromomethane (Methylbromide)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Carbon tetrachloride mg/l NT 0.269NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chlorobenzene (mono)mg/l NT 50NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chloroethane mg/l NT 2800NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chloroform mg/l NT 70NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Chloromethane (Methylchloride)mg/l NT 2.6NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Dibromochloromethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l NT 0.025NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l NT 0.00047NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Dibromomethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dichlorobenzene mg/l NT 24NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,4-Dichlorobenzene mg/l NT 1.4NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT trans-1,4-Dichloro-2-butene mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1-Dichloroethane mg/l NT 70NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dichloroethane mg/l NT 0.38NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1-Dichloroethene (-ethylene)mg/l NT 7NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l NT 70NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l NT 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2-Dichloropropane mg/l NT 0.51NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l NT 0.19NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l NT 0.19NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Ethylbenzene mg/l NT 550NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 2-Hexanone mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Iodomethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Dichloromethane (Methylene chloride)mg/l NT 4.6NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l NT 4200NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 4-Methyl-2-Pentanone mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Styrene mg/l NT 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,1,2-Tetrachloroethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,2,2-Tetrachloroethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Tetrachloroethene (-ethylene)mg/l NT 0.7NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Toluene mg/l NT 1000NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,1-Trichloroethane mg/l NT 200NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,1,2-Trichloroethane mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Trichloroethene (-ethylene)mg/l NT 2.8NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Trichlorofluoromethane mg/l NT 2100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,2,3-Trichloropropane mg/l NT 0.005NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Vinyl acetate mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Vinyl chloride mg/l NT 0.015NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Xylenes mg/l NT 530NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (2-24-2003) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (8-11-2003) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NENP 5.89 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Specific Conductance mmhos/cm 1 NENP 189 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Temperature °C -NENP 15.2 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Turbidity NTU 0.1 NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Antimony (Sb)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Arsenic (As)mg/l 5 50NP 9.9 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Barium (Ba)mg/l 5 2000NP 1200 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Beryllium (Be)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Cadmium (Cd)mg/l 1 1.75NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Chromium (Cr)mg/l 2 50NP 81 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Cobalt (Co)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Copper (Cu)mg/l NT 1000NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Lead (Pb)mg/l 5 15NP 30 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Mercury (Hg)mg/l 0.2 1.05NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Nickel (Ni)mg/l 50 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Selenium (Se)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Silver (Ag)mg/l 2 17.5NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Thallium (Tl)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Vanadium (V)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Zinc (Zn)mg/l NT 1050NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acetone mg/l 10 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Acrylonitrile mg/l 25 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Benzene mg/l 5 1NP 9 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromochloromethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromodichloromethane mg/l 5 0.56NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromoform mg/l 5 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon Disulfide mg/l 10 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromomethane (Methylbromide)mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon tetrachloride mg/l 5 0.269NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chlorobenzene (mono)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroethane mg/l 10 2800NP 33 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroform mg/l 5 70NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloromethane (Methylchloride)mg/l 5 2.6NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromochloromethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.025NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.00047NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromomethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichlorobenzene mg/l 5 24NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,4-Dichlorobenzene mg/l 5 1.4NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,4-Dichloro-2-butene mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethane mg/l 5 70NP 23 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloroethane mg/l 5 0.38NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 5 7NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 70NP 21 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 5 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloropropane mg/l 5 0.51NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 5 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 5 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Ethylbenzene mg/l 5 550NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Hexanone mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Iodomethane mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dichloromethane (Methylene chloride)mg/l 5 4.6NP 21 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 10 4200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 4-Methyl-2-Pentanone mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Styrene mg/l 5 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1,2-Tetrachloroethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2,2-Tetrachloroethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Tetrachloroethene (-ethylene)mg/l 5 0.7NP 8.9 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Toluene mg/l 5 1000NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1-Trichloroethane mg/l 5 200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2-Trichloroethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichloroethene (-ethylene)mg/l 5 2.8NP 11 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichlorofluoromethane mg/l 10 2100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2,3-Trichloropropane mg/l 5 0.005NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl acetate mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl chloride mg/l 5 0.015NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Xylenes mg/l 10 530NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (8-11-2003) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (2-9-2004) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NENP 5.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Specific Conductance mmhos/cm 1 NENP 165 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Temperature °C -NENP 11.8 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Turbidity NTU 0.1 NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Antimony (Sb)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Arsenic (As)mg/l 5 50NP 8.3 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Barium (Ba)mg/l 5 2000NP 890 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Beryllium (Be)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Cadmium (Cd)mg/l 1 1.75NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Chromium (Cr)mg/l 2 50NP 57 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Cobalt (Co)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Copper (Cu)mg/l NT 1000NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Lead (Pb)mg/l 5 15NP 18 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Mercury (Hg)mg/l 0.2 1.05NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Nickel (Ni)mg/l 50 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Selenium (Se)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Silver (Ag)mg/l 2 17.5NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Thallium (Tl)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Vanadium (V)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Zinc (Zn)mg/l NT 1050NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acetone mg/l 10 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Acrylonitrile mg/l 25 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Benzene mg/l 5 1NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromochloromethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromodichloromethane mg/l 5 0.56NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromoform mg/l 5 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon Disulfide mg/l 10 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromomethane (Methylbromide)mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon tetrachloride mg/l 5 0.269NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chlorobenzene (mono)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroethane mg/l 10 2800NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroform mg/l 5 70NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloromethane (Methylchloride)mg/l 5 2.6NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromochloromethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.025NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.00047NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromomethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichlorobenzene mg/l 5 24NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,4-Dichlorobenzene mg/l 5 1.4NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,4-Dichloro-2-butene mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethane mg/l 5 70NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloroethane mg/l 5 0.38NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 5 7NP 11 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 70NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 5 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloropropane mg/l 5 0.51NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 5 0.19NP 8.1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 5 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Ethylbenzene mg/l 5 550NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Hexanone mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Iodomethane mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dichloromethane (Methylene chloride)mg/l 5 4.6NP 8.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 10 4200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 4-Methyl-2-Pentanone mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Styrene mg/l 5 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1,2-Tetrachloroethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2,2-Tetrachloroethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Tetrachloroethene (-ethylene)mg/l 5 0.7NP 6.2 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Toluene mg/l 5 1000NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1-Trichloroethane mg/l 5 200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2-Trichloroethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichloroethene (-ethylene)mg/l 5 2.8NP 6.2 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichlorofluoromethane mg/l 10 2100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2,3-Trichloropropane mg/l 5 0.005NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl acetate mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl chloride mg/l 5 0.015NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Xylenes mg/l 10 530NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (2-9-2004) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (8-16-2004) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NENP 5.84 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Specific Conductance mmhos/cm 1 NENP 170 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Temperature °C -NENP 15.3 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Turbidity NTU 0.1 NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Antimony (Sb)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Arsenic (As)mg/l 5 50NP 6.1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Barium (Ba)mg/l 5 2000NP 1100 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Beryllium (Be)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Cadmium (Cd)mg/l 1 1.75NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Chromium (Cr)mg/l 2 50NP 52 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Cobalt (Co)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Copper (Cu)mg/l NT 1000NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Lead (Pb)mg/l 5 15NP 23 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Mercury (Hg)mg/l 0.2 1.05NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 0.7 Total Nickel (Ni)mg/l 50 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Selenium (Se)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Silver (Ag)mg/l 2 17.5NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Thallium (Tl)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Vanadium (V)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Zinc (Zn)mg/l NT 1050NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acetone mg/l 100 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Acrylonitrile mg/l 200 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Benzene mg/l 5 1NP 6.1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromochloromethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromodichloromethane mg/l 5 0.56NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromoform mg/l 5 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon Disulfide mg/l 100 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromomethane (Methylbromide)mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon tetrachloride mg/l 10 0.269NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chlorobenzene (mono)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroethane mg/l 10 2800NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroform mg/l 5 70NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloromethane (Methylchloride)mg/l 10 2.6NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromochloromethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.00047NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromomethane mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichlorobenzene mg/l 5 24NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,4-Dichlorobenzene mg/l 5 1.4NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,4-Dichloro-2-butene mg/l 100 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethane mg/l 5 70NP 12 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloroethane mg/l 5 0.38NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 5 7NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 70NP 15 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 5 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloropropane mg/l 5 0.51NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 10 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 10 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Ethylbenzene mg/l 5 550NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Hexanone mg/l 50 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Iodomethane mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dichloromethane (Methylene chloride)mg/l 10 4.6NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 100 4200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 4-Methyl-2-Pentanone mg/l 100 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Styrene mg/l 10 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1,2-Tetrachloroethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2,2-Tetrachloroethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Tetrachloroethene (-ethylene)mg/l 5 0.7NP 5.8 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Toluene mg/l 5 1000NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1-Trichloroethane mg/l 5 200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2-Trichloroethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichloroethene (-ethylene)mg/l 5 2.8NP 5.5 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichlorofluoromethane mg/l 5 2100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2,3-Trichloropropane mg/l 15 0.005NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl acetate mg/l 50 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl chloride mg/l 10 0.015NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Xylenes mg/l 5 530NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (8-16-2004) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (2-14-2005) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NENP 5.6 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Specific Conductance mmhos/cm 1 NENP 131 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Temperature °C -NENP 11.3 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Turbidity NTU 0.1 NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Antimony (Sb)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Arsenic (As)mg/l 5 50NP 6.2 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Barium (Ba)mg/l 5 2000NP 520 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Beryllium (Be)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Cadmium (Cd)mg/l 1 1.75NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Chromium (Cr)mg/l 2 50NP 11 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Cobalt (Co)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Copper (Cu)mg/l NT 1000NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Lead (Pb)mg/l 5 15NP 7.9 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Mercury (Hg)mg/l 0.2 1.05NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Nickel (Ni)mg/l 50 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Selenium (Se)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5.8 Total Silver (Ag)mg/l 2 17.5NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Thallium (Tl)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Vanadium (V)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Zinc (Zn)mg/l NT 1050NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acetone mg/l 100 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Acrylonitrile mg/l 200 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Benzene mg/l 5 1NP 7.1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromochloromethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromodichloromethane mg/l 5 0.56NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromoform mg/l 5 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon Disulfide mg/l 100 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromomethane (Methylbromide)mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon tetrachloride mg/l 10 0.269NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chlorobenzene (mono)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroethane mg/l 10 2800NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroform mg/l 5 70NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloromethane (Methylchloride)mg/l 10 2.6NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromochloromethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.00047NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromomethane mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichlorobenzene mg/l 5 24NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,4-Dichlorobenzene mg/l 5 1.4NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,4-Dichloro-2-butene mg/l 100 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethane mg/l 5 70NP 15 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloroethane mg/l 5 0.38NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 5 7NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 70NP 20 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 5 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloropropane mg/l 5 0.51NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 10 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 10 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Ethylbenzene mg/l 5 550NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Hexanone mg/l 50 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Iodomethane mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dichloromethane (Methylene chloride)mg/l 10 4.6NP 12 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 100 4200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 4-Methyl-2-Pentanone mg/l 100 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Styrene mg/l 10 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1,2-Tetrachloroethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2,2-Tetrachloroethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Tetrachloroethene (-ethylene)mg/l 5 0.7NP 6.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Toluene mg/l 5 1000NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1-Trichloroethane mg/l 5 200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2-Trichloroethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichloroethene (-ethylene)mg/l 5 2.8NP 7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichlorofluoromethane mg/l 5 2100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2,3-Trichloropropane mg/l 15 0.005NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl acetate mg/l 50 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl chloride mg/l 10 0.015NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Xylenes mg/l 5 530NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (2-14-2005) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (9-1-2005) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NENP 5.63 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Specific Conductance mmhos/cm 1 NENP 150 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Temperature °C -NENP 13.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Turbidity NTU 0.1 NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Antimony (Sb)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Arsenic (As)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Barium (Ba)mg/l 5 2000NP 330 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Beryllium (Be)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Cadmium (Cd)mg/l 1 1.75NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Chromium (Cr)mg/l 2 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Cobalt (Co)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Copper (Cu)mg/l NT 1000NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Lead (Pb)mg/l 5 15NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Mercury (Hg)mg/l 0.2 1.05NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Nickel (Ni)mg/l 50 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Selenium (Se)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Silver (Ag)mg/l 2 17.5NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Thallium (Tl)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Vanadium (V)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Zinc (Zn)mg/l NT 1050NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acetone mg/l 10 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Acrylonitrile mg/l 25 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Benzene mg/l 5 1NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromochloromethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromodichloromethane mg/l 5 0.56NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromoform mg/l 5 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon Disulfide mg/l 10 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromomethane (Methylbromide)mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon tetrachloride mg/l 5 0.269NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chlorobenzene (mono)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroethane mg/l 10 2800NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroform mg/l 5 70NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloromethane (Methylchloride)mg/l 5 2.6NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromochloromethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.025NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.00047NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromomethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichlorobenzene mg/l 5 24NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,4-Dichlorobenzene mg/l 5 1.4NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,4-Dichloro-2-butene mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethane mg/l 5 70NP 10 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloroethane mg/l 5 0.38NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 5 7NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 70NP 13 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 5 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloropropane mg/l 5 0.51NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 5 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 5 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Ethylbenzene mg/l 5 550NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Hexanone mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Iodomethane mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dichloromethane (Methylene chloride)mg/l 5 4.6NP 7.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 10 4200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 4-Methyl-2-Pentanone mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Styrene mg/l 5 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1,2-Tetrachloroethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2,2-Tetrachloroethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Tetrachloroethene (-ethylene)mg/l 5 0.7NP 5.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Toluene mg/l 5 1000NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1-Trichloroethane mg/l 5 200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2-Trichloroethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichloroethene (-ethylene)mg/l 5 2.8NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichlorofluoromethane mg/l 10 2100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2,3-Trichloropropane mg/l 5 0.005NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl acetate mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl chloride mg/l 5 0.015NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Xylenes mg/l 10 530NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (9-1-2005) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (2-16-2006) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NENP 5.65 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Specific Conductance mmhos/cm 1 NENP 168 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Temperature °C -NENP 12.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Turbidity NTU 0.1 NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Antimony (Sb)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Arsenic (As)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Barium (Ba)mg/l 5 2000NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Beryllium (Be)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Cadmium (Cd)mg/l 1 1.75NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Chromium (Cr)mg/l 2 50NP 16 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Cobalt (Co)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Copper (Cu)mg/l NT 1000NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Lead (Pb)mg/l 5 15NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Mercury (Hg)mg/l 0.2 1.05NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Nickel (Ni)mg/l 50 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Selenium (Se)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Silver (Ag)mg/l 2 17.5NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Thallium (Tl)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Vanadium (V)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Zinc (Zn)mg/l NT 1050NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acetone mg/l 10 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Acrylonitrile mg/l 25 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Benzene mg/l 5 1NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromochloromethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromodichloromethane mg/l 5 0.56NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromoform mg/l 5 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon Disulfide mg/l 10 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromomethane (Methylbromide)mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon tetrachloride mg/l 5 0.269NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chlorobenzene (mono)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroethane mg/l 10 2800NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroform mg/l 5 70NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloromethane (Methylchloride)mg/l 5 2.6NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromochloromethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.025NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.00047NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromomethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichlorobenzene mg/l 5 24NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,4-Dichlorobenzene mg/l 5 1.4NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,4-Dichloro-2-butene mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethane mg/l 5 70NP 7.1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloroethane mg/l 5 0.38NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 5 7NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 70NP 7.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 5 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloropropane mg/l 5 0.51NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 5 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 5 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Ethylbenzene mg/l 5 550NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Hexanone mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Iodomethane mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dichloromethane (Methylene chloride)mg/l 5 4.6NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 10 4200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 4-Methyl-2-Pentanone mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Styrene mg/l 5 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1,2-Tetrachloroethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2,2-Tetrachloroethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Tetrachloroethene (-ethylene)mg/l 5 0.7NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Toluene mg/l 5 1000NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1-Trichloroethane mg/l 5 200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2-Trichloroethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichloroethene (-ethylene)mg/l 5 2.8NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichlorofluoromethane mg/l 10 2100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2,3-Trichloropropane mg/l 5 0.005NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl acetate mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl chloride mg/l 5 0.015NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Xylenes mg/l 10 530NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (2-16-2006) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (8-30-2006) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NENP 5.95 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Specific Conductance mmhos/cm 1 NENP 213 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Temperature °C -NENP 15.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Turbidity NTU 0.1 NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Antimony (Sb)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Arsenic (As)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Barium (Ba)mg/l 5 2000NP 250 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Beryllium (Be)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Cadmium (Cd)mg/l 1 1.75NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Chromium (Cr)mg/l 2 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Cobalt (Co)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Copper (Cu)mg/l NT 1000NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Lead (Pb)mg/l 5 15NP 6.5 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Mercury (Hg)mg/l 0.2 1.05NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Nickel (Ni)mg/l 50 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Selenium (Se)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Silver (Ag)mg/l 2 17.5NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Thallium (Tl)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Vanadium (V)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Zinc (Zn)mg/l NT 1050NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acetone mg/l 25 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Acrylonitrile mg/l 25 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Benzene mg/l 5 1NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromochloromethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromodichloromethane mg/l 5 0.56NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromoform mg/l 5 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon Disulfide mg/l 10 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromomethane (Methylbromide)mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon tetrachloride mg/l 5 0.269NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chlorobenzene (mono)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroethane mg/l 10 2800NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroform mg/l 5 70NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloromethane (Methylchloride)mg/l 5 2.6NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromochloromethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.025NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.00047NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromomethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichlorobenzene mg/l 5 24NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,4-Dichlorobenzene mg/l 5 1.4NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,4-Dichloro-2-butene mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethane mg/l 5 70NP 5.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloroethane mg/l 5 0.38NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 5 7NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 70NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 5 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloropropane mg/l 5 0.51NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 5 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 5 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Ethylbenzene mg/l 5 550NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Hexanone mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Iodomethane mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dichloromethane (Methylene chloride)mg/l 5 4.6NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 10 4200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 4-Methyl-2-Pentanone mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Styrene mg/l 5 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1,2-Tetrachloroethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2,2-Tetrachloroethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Tetrachloroethene (-ethylene)mg/l 5 0.7NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Toluene mg/l 5 1000NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1-Trichloroethane mg/l 5 200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2-Trichloroethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichloroethene (-ethylene)mg/l 5 2.8NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichlorofluoromethane mg/l 10 2100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2,3-Trichloropropane mg/l 5 0.005NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl acetate mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl chloride mg/l 5 0.015NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Xylenes mg/l 10 530NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (8-30-2006) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (2-26-2007) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NENP 5.36 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Specific Conductance mmhos/cm 1 NENP 180 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Temperature °C -NENP 12.2 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Turbidity NTU 0.1 NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Antimony (Sb)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Arsenic (As)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Barium (Ba)mg/l 5 2000NP 280 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Beryllium (Be)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Cadmium (Cd)mg/l 1 1.75NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Chromium (Cr)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Cobalt (Co)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Copper (Cu)mg/l NT 1000NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Lead (Pb)mg/l 5 15NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Mercury (Hg)mg/l 0.2 1.05NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Nickel (Ni)mg/l 50 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Selenium (Se)mg/l 10 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Silver (Ag)mg/l 5 17.5NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Thallium (Tl)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Vanadium (V)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Zinc (Zn)mg/l NT 1050NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acetone mg/l 25 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Acrylonitrile mg/l 25 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Benzene mg/l 5 1NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromochloromethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromodichloromethane mg/l 5 0.56NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromoform mg/l 5 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon Disulfide mg/l 10 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromomethane (Methylbromide)mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon tetrachloride mg/l 5 0.269NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chlorobenzene (mono)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroethane mg/l 10 2800NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroform mg/l 5 70NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloromethane (Methylchloride)mg/l 5 2.6NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromochloromethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.025NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.00047NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromomethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichlorobenzene mg/l 5 24NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,4-Dichlorobenzene mg/l 5 1.4NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,4-Dichloro-2-butene mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethane mg/l 5 70NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloroethane mg/l 5 0.38NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 5 7NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 70NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 5 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloropropane mg/l 5 0.51NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 5 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 5 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Ethylbenzene mg/l 5 550NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Hexanone mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Iodomethane mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dichloromethane (Methylene chloride)mg/l 5 4.6NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 10 4200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 4-Methyl-2-Pentanone mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Styrene mg/l 5 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1,2-Tetrachloroethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2,2-Tetrachloroethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Tetrachloroethene (-ethylene)mg/l 5 0.7NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Toluene mg/l 5 1000NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1-Trichloroethane mg/l 5 200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2-Trichloroethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichloroethene (-ethylene)mg/l 5 2.8NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichlorofluoromethane mg/l 10 2100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2,3-Trichloropropane mg/l 5 0.005NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl acetate mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl chloride mg/l 5 0.015NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Xylenes mg/l 10 530NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (2-26-2007) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (8-13-2007) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NENP 5.76 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Specific Conductance mmhos/cm 10 NENP 148 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Temperature °C -NENP 15 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Turbidity NTU 0.1 NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Antimony (Sb)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Arsenic (As)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Barium (Ba)mg/l 5 2000NP 208 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Beryllium (Be)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Cadmium (Cd)mg/l 1 1.75NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Chromium (Cr)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Cobalt (Co)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Copper (Cu)mg/l NT 1000NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Lead (Pb)mg/l 5 15NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Mercury (Hg)mg/l 0.2 1.05NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Nickel (Ni)mg/l NT 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Selenium (Se)mg/l 10 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Silver (Ag)mg/l 5 17.5NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Thallium (Tl)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Vanadium (V)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Zinc (Zn)mg/l NT 1050NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acetone mg/l 25 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Acrylonitrile mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Benzene mg/l 1 1NP 1.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromochloromethane mg/l 1 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromodichloromethane mg/l 1 0.56NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromoform mg/l 1 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon Disulfide mg/l 2 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromomethane (Methylbromide)mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon tetrachloride mg/l 1 0.269NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chlorobenzene (mono)mg/l 1 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroethane mg/l 1 2800NP 2.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroform mg/l 1 70NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloromethane (Methylchloride)mg/l 1 2.6NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromochloromethane mg/l 1 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 0.025NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.00047NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromomethane mg/l 1 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichlorobenzene mg/l 1 24NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,4-Dichlorobenzene mg/l 1 1.4NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,4-Dichloro-2-butene mg/l 1 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethane mg/l 1 70NP 4.3 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloroethane mg/l 1 0.38NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 1 7NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70NP 4.3 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloropropane mg/l 1 0.51NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Ethylbenzene mg/l 1 550NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Hexanone mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Iodomethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dichloromethane (Methylene chloride)mg/l 2 4.6NP 2.9 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 4-Methyl-2-Pentanone mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Styrene mg/l 1 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1,2-Tetrachloroethane mg/l 1 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2,2-Tetrachloroethane mg/l 1 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Tetrachloroethene (-ethylene)mg/l 1 0.7NP 3.6 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Toluene mg/l 1 1000NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1-Trichloroethane mg/l 1 200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2-Trichloroethane mg/l 1 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichloroethene (-ethylene)mg/l 1 2.8NP 2.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichlorofluoromethane mg/l 1 2100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2,3-Trichloropropane mg/l 1 0.005NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl acetate mg/l 2 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl chloride mg/l 1 0.015NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Xylenes mg/l 2 530NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (8-13-2007) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (2-11-2008) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NENP 5.47 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Specific Conductance mmhos/cm 10 NENP 158 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Temperature °C -NENP 12.2 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Turbidity NTU NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Antimony (Sb)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Arsenic (As)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Barium (Ba)mg/l 5 2000NP 238 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Beryllium (Be)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Cadmium (Cd)mg/l 1 1.75NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Chromium (Cr)mg/l 5 50NP 6.3 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Cobalt (Co)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Copper (Cu)mg/l NT 1000NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Lead (Pb)mg/l 5 15NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Mercury (Hg)mg/l 0.2 1.05NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Nickel (Ni)mg/l NT 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Selenium (Se)mg/l 10 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Silver (Ag)mg/l 5 17.5NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Thallium (Tl)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Vanadium (V)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Zinc (Zn)mg/l NT 1050NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acetone mg/l 25 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Acrylonitrile mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Benzene mg/l 1 1NP 2 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromochloromethane mg/l 1 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromodichloromethane mg/l 1 0.56NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromoform mg/l 1 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon Disulfide mg/l 2 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromomethane (Methylbromide)mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon tetrachloride mg/l 1 0.269NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chlorobenzene (mono)mg/l 1 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroethane mg/l 1 2800NP 2.5 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroform mg/l 1 70NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloromethane (Methylchloride)mg/l 1 2.6NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromochloromethane mg/l 1 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 0.025NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.00047NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromomethane mg/l 1 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichlorobenzene mg/l 1 24NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,4-Dichlorobenzene mg/l 1 1.4NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,4-Dichloro-2-butene mg/l 1 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethane mg/l 1 70NP 4.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloroethane mg/l 1 0.38NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 1 7NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70NP 4.5 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloropropane mg/l 1 0.51NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Ethylbenzene mg/l 1 550NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Hexanone mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Iodomethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dichloromethane (Methylene chloride)mg/l 2 4.6NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 4-Methyl-2-Pentanone mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Styrene mg/l 1 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1,2-Tetrachloroethane mg/l 1 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2,2-Tetrachloroethane mg/l 1 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Tetrachloroethene (-ethylene)mg/l 1 0.7NP 3.5 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Toluene mg/l 1 1000NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1-Trichloroethane mg/l 1 200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2-Trichloroethane mg/l 1 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichloroethene (-ethylene)mg/l 1 2.8NP 2.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichlorofluoromethane mg/l 1 2100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2,3-Trichloropropane mg/l 1 0.005NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl acetate mg/l 2 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl chloride mg/l 1 0.015NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Xylenes mg/l 2 530NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (2-11-2008) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (8-25-2008) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NENP 5.71 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Specific Conductance mmhos/cm 10 NENP 180 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Temperature °C -NENP 14.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Turbidity NTU NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Antimony (Sb)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Arsenic (As)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Barium (Ba)mg/l 5 2000NP 195 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Beryllium (Be)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Cadmium (Cd)mg/l 1 1.75NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Chromium (Cr)mg/l 5 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Cobalt (Co)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Copper (Cu)mg/l NT 1000NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Lead (Pb)mg/l 5 15NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Mercury (Hg)mg/l 0.2 1.05NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Nickel (Ni)mg/l NT 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Selenium (Se)mg/l 10 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Silver (Ag)mg/l 5 17.5NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Thallium (Tl)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Vanadium (V)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Zinc (Zn)mg/l NT 1050NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acetone mg/l 25 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Acrylonitrile mg/l 10 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Benzene mg/l 1 1NP 2.3 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromochloromethane mg/l 1 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromodichloromethane mg/l 1 0.56NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromoform mg/l 1 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon Disulfide mg/l 2 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromomethane (Methylbromide)mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon tetrachloride mg/l 1 0.269NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chlorobenzene (mono)mg/l 1 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroethane mg/l 1 2800NP 2.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroform mg/l 1 70NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloromethane (Methylchloride)mg/l 1 2.6NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromochloromethane mg/l 1 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 0.025NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.00047NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromomethane mg/l 1 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichlorobenzene mg/l 1 24NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,4-Dichlorobenzene mg/l 1 1.4NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,4-Dichloro-2-butene mg/l 1 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethane mg/l 1 70NP 5.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloroethane mg/l 1 0.38NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 1 7NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70NP 5.8 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloropropane mg/l 1 0.51NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Ethylbenzene mg/l 1 550NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Hexanone mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Iodomethane mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dichloromethane (Methylene chloride)mg/l 2 4.6NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 4-Methyl-2-Pentanone mg/l 5 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Styrene mg/l 1 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1,2-Tetrachloroethane mg/l 1 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2,2-Tetrachloroethane mg/l 1 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Tetrachloroethene (-ethylene)mg/l 1 0.7NP 3.9 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Toluene mg/l 1 1000NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1-Trichloroethane mg/l 1 200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2-Trichloroethane mg/l 1 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichloroethene (-ethylene)mg/l 1 2.8NP 3 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichlorofluoromethane mg/l 1 2100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2,3-Trichloropropane mg/l 1 0.005NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl acetate mg/l 2 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl chloride mg/l 1 0.015NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Xylenes mg/l 3 530NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (8-25-2008) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (2-23-2009) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NENP 5.56 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Specific Conductance mmhos/cm -NENP 238 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Temperature °C -NENP 8.6 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Turbidity NTU NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Antimony (Sb)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Arsenic (As)mg/l 5.0 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Barium (Ba)mg/l 5.0 2000NP 270 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Beryllium (Be)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Cadmium (Cd)mg/l 1.0 1.75NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Chromium (Cr)mg/l 5.0 50NP 7.2 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Cobalt (Co)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Copper (Cu)mg/l NT 1000NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Lead (Pb)mg/l 5.0 15NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Mercury (Hg)mg/l 0.20 1.05NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Nickel (Ni)mg/l NT 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Selenium (Se)mg/l 10.0 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Silver (Ag)mg/l 5.0 17.5NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Thallium (Tl)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Vanadium (V)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Zinc (Zn)mg/l NT 1050NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acetone mg/l 25.0 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Acrylonitrile mg/l 10.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Benzene mg/l 1.0 1NP 2.1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromochloromethane mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromodichloromethane mg/l 1.0 0.56NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromoform mg/l 1.0 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon Disulfide mg/l 2.0 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromomethane (Methylbromide)mg/l 5.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon tetrachloride mg/l 1.0 0.269NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chlorobenzene (mono)mg/l 1.0 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroethane mg/l 1.0 2800NP 2.1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroform mg/l 1.0 70NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloromethane (Methylchloride)mg/l 1.0 2.6NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromochloromethane mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3.0 0.025NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 0.00047NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromomethane mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichlorobenzene mg/l 1.0 24NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,4-Dichlorobenzene mg/l 1.0 1.4NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,4-Dichloro-2-butene mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethane mg/l 1.0 70NP 5.2 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloroethane mg/l 1.0 0.38NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 7NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 70NP 5.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloropropane mg/l 1.0 0.51NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Ethylbenzene mg/l 1.0 550NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Hexanone mg/l 5.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Iodomethane mg/l 5.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dichloromethane (Methylene chloride)mg/l 2.0 4.6NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 4200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 4-Methyl-2-Pentanone mg/l 5.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Styrene mg/l 1.0 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2,2-Tetrachloroethane mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Tetrachloroethene (-ethylene)mg/l 1.0 0.7NP 3.9 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Toluene mg/l 1.0 1000NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1-Trichloroethane mg/l 1.0 200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2-Trichloroethane mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichloroethene (-ethylene)mg/l 1.0 2.8NP 3.0 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichlorofluoromethane mg/l 1.0 2100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2,3-Trichloropropane mg/l 1.0 0.005NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl acetate mg/l 2.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl chloride mg/l 1.0 0.015NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Xylenes mg/l 2.0 530NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (2-23-2009) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (8-24-2009) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NENP 5.59 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Specific Conductance mmhos/cm -NENP 217 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Temperature °C -NENP 13.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Turbidity NTU NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Antimony (Sb)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Arsenic (As)mg/l 5.0 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Barium (Ba)mg/l 5.0 2000NP 264 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Beryllium (Be)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Cadmium (Cd)mg/l 1.0 1.75NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Chromium (Cr)mg/l 5.0 50NP 6.5 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Cobalt (Co)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Copper (Cu)mg/l NT 1000NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Lead (Pb)mg/l 5.0 15NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Mercury (Hg)mg/l 0.20 1.05NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Nickel (Ni)mg/l NT 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Selenium (Se)mg/l 10.0 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Silver (Ag)mg/l 5.0 17.5NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Thallium (Tl)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Vanadium (V)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Zinc (Zn)mg/l NT 1050NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acetone mg/l 25.0 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Acrylonitrile mg/l 10.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Benzene mg/l 1.0 1NP 3 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromochloromethane mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromodichloromethane mg/l 1.0 0.56NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromoform mg/l 1.0 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon Disulfide mg/l 2.0 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromomethane (Methylbromide)mg/l 5.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon tetrachloride mg/l 1.0 0.269NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chlorobenzene (mono)mg/l 1.0 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroethane mg/l 1.0 2800NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroform mg/l 1.0 70NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloromethane (Methylchloride)mg/l 1.0 2.6NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromochloromethane mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3.0 0.025NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 0.00047NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromomethane mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichlorobenzene mg/l 1.0 24NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,4-Dichlorobenzene mg/l 1.0 1.4NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,4-Dichloro-2-butene mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethane mg/l 1.0 70NP 7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloroethane mg/l 1.0 0.38NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 7NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 70NP 7.1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloropropane mg/l 1.0 0.51NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Ethylbenzene mg/l 1.0 550NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Hexanone mg/l 5.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Iodomethane mg/l 5.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dichloromethane (Methylene chloride)mg/l 2.0 4.6NP 2.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 4200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 4-Methyl-2-Pentanone mg/l 5.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Styrene mg/l 1.0 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2,2-Tetrachloroethane mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Tetrachloroethene (-ethylene)mg/l 1.0 0.7NP 4.2 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Toluene mg/l 1.0 1000NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1-Trichloroethane mg/l 1.0 200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2-Trichloroethane mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichloroethene (-ethylene)mg/l 1.0 2.8NP 3.5 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichlorofluoromethane mg/l 1.0 2100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2,3-Trichloropropane mg/l 1.0 0.005NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl acetate mg/l 2.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl chloride mg/l 1.0 0.015NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Xylenes mg/l 2.0 530NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (8-24-2009) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (2-22-2010) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NENP 5.84 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Specific Conductance mmhos/cm -NENP 236 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Temperature °C -NENP 12.8 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Turbidity NTU NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Antimony (Sb)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Arsenic (As)mg/l 5.0 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Barium (Ba)mg/l 5.0 2000NP 260 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Beryllium (Be)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Cadmium (Cd)mg/l 1.0 1.75NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Chromium (Cr)mg/l 5.0 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Cobalt (Co)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Copper (Cu)mg/l NT 1000NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Lead (Pb)mg/l 5.0 15NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Mercury (Hg)mg/l 0.20 1.05NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Nickel (Ni)mg/l NT 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Selenium (Se)mg/l 10.0 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Silver (Ag)mg/l 5.0 17.5NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Thallium (Tl)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Vanadium (V)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Zinc (Zn)mg/l NT 1050NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acetone mg/l 25.0 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Acrylonitrile mg/l 10.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Benzene mg/l 1.0 1NP 3.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromochloromethane mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromodichloromethane mg/l 1.0 0.56NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromoform mg/l 1.0 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon Disulfide mg/l 2.0 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromomethane (Methylbromide)mg/l 5.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon tetrachloride mg/l 1.0 0.269NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chlorobenzene (mono)mg/l 1.0 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroethane mg/l 1.0 2800NP 3.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroform mg/l 1.0 70NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloromethane (Methylchloride)mg/l 1.0 2.6NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromochloromethane mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3.0 0.025NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 0.00047NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromomethane mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichlorobenzene mg/l 1.0 24NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,4-Dichlorobenzene mg/l 1.0 1.4NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,4-Dichloro-2-butene mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethane mg/l 1.0 70NP 10.1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloroethane mg/l 1.0 0.38NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 7NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 70NP 7.8 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloropropane mg/l 1.0 0.51NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Ethylbenzene mg/l 1.0 550NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Hexanone mg/l 5.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Iodomethane mg/l 5.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dichloromethane (Methylene chloride)mg/l 2.0 4.6NP 2.9 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 4200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 4-Methyl-2-Pentanone mg/l 5.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Styrene mg/l 1.0 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2,2-Tetrachloroethane mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Tetrachloroethene (-ethylene)mg/l 1.0 0.7NP 5.1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Toluene mg/l 1.0 1000NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1-Trichloroethane mg/l 1.0 200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2-Trichloroethane mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichloroethene (-ethylene)mg/l 1.0 2.8NP 4.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichlorofluoromethane mg/l 1.0 2100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2,3-Trichloropropane mg/l 1.0 0.005NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl acetate mg/l 2.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl chloride mg/l 1.0 0.015NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Xylenes mg/l 2.0 530NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (2-22-2010) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (8-30-2010) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NENP 5.64 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Specific Conductance mmhos/cm -NENP 266 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Temperature °C -NENP 14.1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Turbidity NTU NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Antimony (Sb)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Arsenic (As)mg/l 5.0 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Barium (Ba)mg/l 5.0 2000NP 246 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Beryllium (Be)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Cadmium (Cd)mg/l 1.0 1.75NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Chromium (Cr)mg/l 5.0 50NP 8.8 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Cobalt (Co)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Copper (Cu)mg/l NT 1000NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Lead (Pb)mg/l 5.0 15NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Mercury (Hg)mg/l 0.20 1.05NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Nickel (Ni)mg/l NT 100NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Selenium (Se)mg/l 10.0 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Silver (Ag)mg/l 5.0 17.5NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Thallium (Tl)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Vanadium (V)mg/l NT NENP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Zinc (Zn)mg/l NT 1050NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Acetone mg/l 25.0 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Acrylonitrile mg/l 10.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Benzene mg/l 1.0 1NP 4.8 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromochloromethane mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromodichloromethane mg/l 1.0 0.56NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromoform mg/l 1.0 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon Disulfide mg/l 2.0 700NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromomethane (Methylbromide)mg/l 2.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon tetrachloride mg/l 1.0 0.269NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chlorobenzene (mono)mg/l 1.0 50NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroethane mg/l 1.0 2800NP 4.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroform mg/l 1.0 70NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloromethane (Methylchloride)mg/l 1.0 2.6NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromochloromethane mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5.0 0.025NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 0.00047NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromomethane mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichlorobenzene mg/l 1.0 24NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,4-Dichlorobenzene mg/l 1.0 1.4NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,4-Dichloro-2-butene mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethane mg/l 1.0 70NP 11.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloroethane mg/l 1.0 0.38NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 7NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 70NP 6.1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloropropane mg/l 1.0 0.51NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 0.19NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Ethylbenzene mg/l 1.0 550NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Hexanone mg/l 5.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Iodomethane mg/l 5.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dichloromethane (Methylene chloride)mg/l 2.0 4.6NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 4200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 4-Methyl-2-Pentanone mg/l 5.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Styrene mg/l 1.0 100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2,2-Tetrachloroethane mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Tetrachloroethene (-ethylene)mg/l 1.0 0.7NP 6.3 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Toluene mg/l 1.0 1000NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1-Trichloroethane mg/l 1.0 200NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2-Trichloroethane mg/l 1.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichloroethene (-ethylene)mg/l 1.0 2.8NP 5.8 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichlorofluoromethane mg/l 1.0 2100NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2,3-Trichloropropane mg/l 1.0 0.005NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl acetate mg/l 2.0 NENP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl chloride mg/l 1.0 0.015NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Xylenes mg/l 2.0 530NP 2 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (8-30-2010) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (2-22-2011) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NE 5.89 5.51 5.49 5.45 5.82 5.60 5.10 6.50 7.12 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Specific Conductance mmhos/cm -NE 94 264 77 273 216 142 62 676 732 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Temperature °C -NE 13.1 12.3 12.8 10.9 10.9 9.3 8.1 14.4 13.5 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Turbidity NTU -NE 23 3.68 4 7.19 6.53 275 97 4.16 5.78 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Antimony (Sb)mg/l 5.0 NEND ND ND ND ND 5.1 ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Arsenic (As)mg/l 5.0 10ND ND ND ND ND 5.8 ND 5.3 ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Barium (Ba)mg/l 5.0 700 197 237 54 213 72.8 1190 193 138 68.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Beryllium (Be)mg/l 1.0 NEND ND ND ND ND 3.6 ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Cadmium (Cd)mg/l 1.0 2ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Chromium (Cr)mg/l 5.0 10 8.1 ND ND ND 6.3 161 17.6ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Cobalt (Co)mg/l 5.0 NE 9.8 16.8 ND 5.4 ND 40.5 5.2 9.4 ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Copper (Cu)mg/l 5.0 1000ND 155 ND ND ND 64.3 10.7ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Lead (Pb)mg/l 5.0 15ND 7.2 ND ND ND 16.2 6.3ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Mercury (Hg)mg/l 0.20 1ND NT ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Nickel (Ni)mg/l 5.0 100 7.6 5.4 8 ND ND 97.3 8.4ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Selenium (Se)mg/l 10.0 20ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Silver (Ag)mg/l 5.0 20ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Thallium (Tl)mg/l 5.4 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Vanadium (V)mg/l 5.0 NE 7.8 ND ND ND 5.6 205 22.8ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Zinc (Zn)mg/l 10 1000 26.5 90.4 ND 19.8 ND 162 36.7 10.3 ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Acetone mg/l 25.0 6000ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Acrylonitrile mg/l 10.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Benzene mg/l 1.0 1ND 5.1 ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromochloromethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromodichloromethane mg/l 1.0 0.6ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromoform mg/l 1.0 4ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon Disulfide mg/l 2.0 700ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromomethane (Methylbromide)mg/l 2.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon tetrachloride mg/l 1.0 0.3ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chlorobenzene (mono)mg/l 1.0 50ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroethane mg/l 1.0 3,000ND 4 ND 1.3 ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroform mg/l 1.0 70ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloromethane (Methylchloride)mg/l 1.0 3ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromochloromethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5.0 0.04ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 0.02000ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromomethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichlorobenzene mg/l 1.0 20ND ND ND 1.4 ND ND ND 4.2 3.3 NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,4-Dichlorobenzene mg/l 1.0 6ND 1.3 ND 1.7 ND ND ND 1.4 ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,4-Dichloro-2-butene mg/l 1.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethane mg/l 1.0 6ND 12.9 ND 4.4 ND ND 3.1 7.5 1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloroethane mg/l 1.0 0.4ND ND ND 3 ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 7ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 70ND 14.4 ND 2.7 ND ND 2.3 10.9 8.9 NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 100ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloropropane mg/l 1.0 0.6ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 0.4ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 0.4ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Ethylbenzene mg/l 1.0 600ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Hexanone mg/l 5.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Iodomethane mg/l 5.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dichloromethane (Methylene chloride)mg/l 2.0 5ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 4000ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 4-Methyl-2-Pentanone mg/l 5.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Styrene mg/l 1.0 70ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2,2-Tetrachloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Tetrachloroethene (-ethylene)mg/l 1.0 0.7ND 5.6 ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Toluene mg/l 1.0 600ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1-Trichloroethane mg/l 1.0 200ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2-Trichloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichloroethene (-ethylene)mg/l 1.0 3ND 4.8 ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichlorofluoromethane mg/l 1.0 2000ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2,3-Trichloropropane mg/l 1.0 0.005ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl acetate mg/l 2.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl chloride mg/l 1.0 0.03ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Xylenes mg/l 2.0 500ND 2.5 ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (2-22-2011) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (8-22-2011) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NE 6.00 5.70 5.70 5.80 6.00 5.80 5.40 6.60 7.30 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Specific Conductance mmhos/cm -NE 93 245 75 256 230 114 56 627 660 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Temperature °C -NE 13.5 13.4 17.8 15.6 15.3 16.8 17.4 15 14.3 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Turbidity NTU -NE 153 41 18 999 4.4 108 190 9.5 12 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Antimony (Sb)mg/l 5.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Arsenic (As)mg/l 5.0 10ND ND ND 8.7 ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Barium (Ba)mg/l 5.0 700 191 280 66.8 1640 76.4 202 71.9 104 57.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Beryllium (Be)mg/l 1.0 NEND ND ND 2.4 ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Cadmium (Cd)mg/l 1.0 2ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Chromium (Cr)mg/l 5.0 10 8.3 ND ND 105 ND 19.3 ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Cobalt (Co)mg/l 5.0 NEND 9.7 ND 43.1 ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Copper (Cu)mg/l 5.0 1000ND 7.3 ND 125 ND 7.9 ND 7.5 ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Lead (Pb)mg/l 5.0 15ND ND ND 37.2 ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Mercury (Hg)mg/l NT 1NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Total Nickel (Ni)mg/l 5.0 100 7.7 7.4 5.5 62.1 ND 10.9 ND 5.2 ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Selenium (Se)mg/l 10.0 20ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Silver (Ag)mg/l 5.0 20ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Thallium (Tl)mg/l 5.4 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Vanadium (V)mg/l 5.0 NE 8.1 ND ND 185 ND 23.1 ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Zinc (Zn)mg/l 10 1000ND 16.9 ND 283 ND 15.9 ND 50.6 ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Acetone mg/l 25.0 6000ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Acrylonitrile mg/l 10.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Benzene mg/l 1.0 1ND 4.2 ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromochloromethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromodichloromethane mg/l 1.0 0.6ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromoform mg/l 1.0 4ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon Disulfide mg/l 2.0 700ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Bromomethane (Methylbromide)mg/l 2.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Carbon tetrachloride mg/l 1.0 0.3ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chlorobenzene (mono)mg/l 1.0 50ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroethane mg/l 1.0 3000ND 2.9 ND 1.2 ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloroform mg/l 1.0 70ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Chloromethane (Methylchloride)mg/l 1.0 3ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromochloromethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5.0 0.04ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 0.02000ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dibromomethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichlorobenzene mg/l 1.0 20ND ND ND 1.5 ND ND ND 4 2.8 NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,4-Dichlorobenzene mg/l 1.0 6ND 1.1 ND 1.6 ND ND ND 1.5 ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,4-Dichloro-2-butene mg/l 1.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethane mg/l 1.0 6ND 9.6 ND 4.6 ND 1.5 2.8 9.6 ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloroethane mg/l 1.0 0.4ND ND ND 3.2 ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 7ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 70ND 11.5 ND 3.6 ND 2.3 2.1 10.1 7.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 100ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2-Dichloropropane mg/l 1.0 0.6ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 0.4ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 0.4ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Ethylbenzene mg/l 1.0 600ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Hexanone mg/l 5.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Iodomethane mg/l 5.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Dichloromethane (Methylene chloride)mg/l 2.0 5ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 4000ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 4-Methyl-2-Pentanone mg/l 5.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Styrene mg/l 1.0 70ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2,2-Tetrachloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Tetrachloroethene (-ethylene)mg/l 1.0 0.7ND 4.6 ND ND ND 1.2 ND 1 ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Toluene mg/l 1.0 600ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,1-Trichloroethane mg/l 1.0 200ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,1,2-Trichloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichloroethene (-ethylene)mg/l 1.0 3ND 3.7 ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Trichlorofluoromethane mg/l 1.0 2000ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND 1,2,3-Trichloropropane mg/l 1.0 0.005ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl acetate mg/l 2.0 NEND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Vinyl chloride mg/l 1.0 0.03ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Total Xylenes mg/l 2.0 500ND 2.1 ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP ND Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (8-22-2011) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (2-22-2012) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NE 6.50 5.80 6.20 5.80 6.30 6.20 5.60 6.60 7.50 6.20 NP 6.40 5.90 5.70NP 6.50 NP 5.80 NP NP NP NP NP NT Specific Conductance mmhos/cm -NE 81 246 63 299 207 138 61 678 683 147 NP 82 71 201NP 63 NP 25 NP NP NP NP NP NT Temperature °C -NE 11.4 12.2 12.3 11.4 10.5 10.5 12.2 13.4 12.7 14.3 NP 13.8 13 11.8NP 13.6 NP 13.4 NP NP NP NP NP NT Turbidity NTU -NE 50.7 3.5 9.7 11.2 16.1 17.4 30.9 3.57 4.77 10 NP 4.18 58.1 10.56NP 44.2 NP 12.3 NP NP NP NP NP NT Total Antimony (Sb)mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Total Arsenic (As)mg/l 5.0 10ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Total Barium (Ba)mg/l 5.0 700 196 214 48.7 207 62.7 126 102 90.2 49.9 249 NP 93.5 135 141NP 80.3 NP 56.3 NP NP NP NP NP ND Total Beryllium (Be)mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Total Cadmium (Cd)mg/l 1.0 2ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Total Chromium (Cr)mg/l 5.0 10 11.1 ND ND 5.2 6.9 10.6 6.2ND ND 5.7 NP ND 7.3 ND NP 6.4 NP ND NP NP NP NP NP ND Total Cobalt (Co)mg/l 5.0 NEND 5.8 ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Total Copper (Cu)mg/l 5.0 1000 8.3 ND ND ND 5.7 6.9 ND ND ND 6.8 NP ND 5.4 ND NP 7.4 NP ND NP NP NP NP NP ND Total Lead (Pb)mg/l 5.0 15ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Total Mercury (Hg)mg/l 0.20 1ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Total Nickel (Ni)mg/l 5.0 100 9.6 ND ND ND ND 5 ND ND ND ND NP ND 6.2 ND NP 5.9 NP ND NP NP NP NP NP ND Total Selenium (Se)mg/l 10.0 20ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Total Silver (Ag)mg/l 5.0 20ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Total Thallium (Tl)mg/l 5.4 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Total Vanadium (V)mg/l 5.0 NE 14.1 ND ND ND 8.8 12.5 8.6ND ND 11 NP ND 9.8 6.1NP 7.6 NP ND NP NP NP NP NP ND Total Zinc (Zn)mg/l 10 1000 10.9 ND 10.4 16.7 16.8 23.1 31.8ND ND 21.4 NP 12.4 17.2 24.3NP 26.9 NP 15.3 NP NP NP NP NP ND Acetone mg/l 25.0 6000ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Acrylonitrile mg/l 10.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Benzene mg/l 1.0 1ND 3.9 ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Bromochloromethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Bromodichloromethane mg/l 1.0 0.6ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Bromoform mg/l 1.0 4ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Carbon Disulfide mg/l 2.0 700ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Bromomethane (Methylbromide)mg/l 2.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Carbon tetrachloride mg/l 1.0 0.3ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Chlorobenzene (mono)mg/l 1.0 50ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Chloroethane mg/l 1.0 3000ND 2.3 ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Chloroform mg/l 1.0 70ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Chloromethane (Methylchloride)mg/l 1.0 3ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Dibromochloromethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5.0 0.04ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 0.02000ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Dibromomethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 1,2-Dichlorobenzene mg/l 1.0 20ND ND ND 1.6 ND ND ND 5 4 ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 1,4-Dichlorobenzene mg/l 1.0 6ND ND ND 1.6 ND ND ND 1.6 ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND trans-1,4-Dichloro-2-butene mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 1,1-Dichloroethane mg/l 1.0 6ND 8.1 ND 3 ND ND 2.1 8.5 ND 1.8 NP ND ND 3.4NP ND NP ND NP NP NP NP NP ND 1,2-Dichloroethane mg/l 1.0 0.4ND ND ND 2.2 ND ND ND ND ND ND NP ND ND 3.2NP ND NP ND NP NP NP NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 7ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 70ND 10.2 ND 2.4 ND ND 1.7 10.6 9 1.5 NP ND ND 1.3NP ND NP ND NP NP NP NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 100ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 1,2-Dichloropropane mg/l 1.0 0.6ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 0.4ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 0.4ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Ethylbenzene mg/l 1.0 600ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 2-Hexanone mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Iodomethane mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Dichloromethane (Methylene chloride)mg/l 2.0 5ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 4000ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 4-Methyl-2-Pentanone mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Styrene mg/l 1.0 70ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 1,1,2,2-Tetrachloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Tetrachloroethene (-ethylene)mg/l 1.0 0.7ND 3.7 ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Toluene mg/l 1.0 600ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 1,1,1-Trichloroethane mg/l 1.0 200ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 1,1,2-Trichloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Trichloroethene (-ethylene)mg/l 1.0 3ND 3.6 ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Trichlorofluoromethane mg/l 1.0 2000ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP 3.8 NP 3.8 NP NP NP NP NP ND 1,2,3-Trichloropropane mg/l 1.0 0.005ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Vinyl acetate mg/l 2.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Vinyl chloride mg/l 1.0 0.03ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Total Xylenes mg/l 2.0 500ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Naphthalene mg/l 1.0 6ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 1,3-dichlorobenzene mg/l 1.0 200ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Dichlorodifluoromethane mg/l 1.0 1000ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (2-22-2012) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (8-29-2012) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NE 6.20 5.90 5.90 5.90 6.20 5.90 5.50 6.20 7.20 6.10 NP 6.30 6.10 5.70NP 6.10 NP 5.80 NP NP NP NP NP NT Specific Conductance mmhos/cm -NE 87 234 67 278 274 114 56 611 681 138 NP 75 65 230NP 59 NP 27 NP NP NP NP NP NT Temperature °C -NE 14.1 15.1 16.6 16.2 20 18.6 19.4 15.8 14.2 15.2 NP 15.4 14.8 18.6NP 16.6 NP 18.4 NP NP NP NP NP NT Turbidity NTU -NE 630 33.9 7.29 15 15.4 28.7 20.7 8.69 4.67 14.7 NP 14.8 8.53 3.84NP 622 NP 22.8 NP NP NP NP NP NT Total Antimony (Sb)mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Total Arsenic (As)mg/l 5.0 10ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP 11.2 NP ND NP NP NP NP NP ND Total Barium (Ba)mg/l 5.0 700 335 289 42.8 224 67.4 106 110 106 64 184 NP 96.2 83.7 137NP 615 NP 51 NP NP NP NP NP ND Total Beryllium (Be)mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP 1.1 NP ND NP NP NP NP NP ND Total Cadmium (Cd)mg/l 1.0 2ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Total Chromium (Cr)mg/l 5.0 10 40.2 7.1 6.1 9.7 ND 7.9 6.5ND ND ND NP ND ND ND NP 56.3 NP ND NP NP NP NP NP ND Total Cobalt (Co)mg/l 5.0 NE 11.7 17.3 ND 5.1 ND ND ND ND ND ND NP ND ND ND NP 21.4 NP ND NP NP NP NP NP ND Total Copper (Cu)mg/l 5.0 1000 17.3 16.2 ND 5.6 ND ND 5ND ND ND NP ND ND ND NP 78.5 NP ND NP NP NP NP NP ND Total Lead (Pb)mg/l 5.0 15 9.2 ND ND ND ND ND ND ND ND ND NP ND ND ND NP 13.3 NP ND NP NP NP NP NP ND Total Mercury (Hg)mg/l 0.20 1ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Total Nickel (Ni)mg/l 5.0 100 22.3 9.2 ND 5.5 ND ND ND ND ND ND NP ND ND ND NP 60.8 NP ND NP NP NP NP NP ND Total Selenium (Se)mg/l 10.0 20ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Total Silver (Ag)mg/l 5.0 20ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Total Thallium (Tl)mg/l 5.4 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Total Vanadium (V)mg/l 5.0 NE 49 14.7 ND 9.9 ND 10.6 10ND ND 5.5 NP ND ND ND NP 86.2 NP ND NP NP NP NP NP ND Total Zinc (Zn)mg/l 10 1000 21 12.7 37.8 20.3 14.5 10.4 19.5ND ND ND NP ND ND 13.6NP 198 NP 11.7 NP NP NP NP NP ND Acetone mg/l 25.0 6000ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Acrylonitrile mg/l 50.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Benzene mg/l 1.0 1ND 3.3 ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Bromochloromethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Bromodichloromethane mg/l 1.0 0.6ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Bromoform mg/l 1.0 4ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Carbon Disulfide mg/l 2.0 700ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Bromomethane (Methylbromide)mg/l 2.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Carbon tetrachloride mg/l 1.0 0.3ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Chlorobenzene (mono)mg/l 1.0 50ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Chloroethane mg/l 1.0 3000ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Chloroform mg/l 1.0 70ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Chloromethane (Methylchloride)mg/l 1.0 3ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Dibromochloromethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5.0 0.04ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 0.02000ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Dibromomethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 1,2-Dichlorobenzene mg/l 1.0 20ND ND ND 1.6 ND ND ND 5.9 4.4 ND NP ND ND 1.2NP ND NP ND NP NP NP NP NP ND 1,4-Dichlorobenzene mg/l 1.0 6ND ND ND 1.4 ND ND ND 1.8 ND ND NP ND ND 1.3NP ND NP ND NP NP NP NP NP ND trans-1,4-Dichloro-2-butene mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 1,1-Dichloroethane mg/l 1.0 6ND 7.4 ND 2.6 ND ND 1.8 6.8 ND 1.6 NP ND ND 4.5NP ND NP ND NP NP NP NP NP ND 1,2-Dichloroethane mg/l 1.0 0.4ND ND ND 1.7 ND ND ND ND ND ND NP ND ND 3.9NP ND NP ND NP NP NP NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 7ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 70ND 8 ND 2.2 ND 1.6 1.3 15.1 5.3 1.2 NP ND ND 1.3NP ND NP ND NP NP NP NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 100ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 1,2-Dichloropropane mg/l 1.0 0.6ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 0.4ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 0.4ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Ethylbenzene mg/l 1.0 600ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 2-Hexanone mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Iodomethane mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Dichloromethane (Methylene chloride)mg/l 1.0 5ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 4000ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 4-Methyl-2-Pentanone mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Styrene mg/l 1.0 70ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 1,1,2,2-Tetrachloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Tetrachloroethene (-ethylene)mg/l 1.0 0.7ND 3.7 ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Toluene mg/l 1.0 600ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 1,1,1-Trichloroethane mg/l 1.0 200ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 1,1,2-Trichloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Trichloroethene (-ethylene)mg/l 1.0 3ND 3.4 ND ND ND ND ND 1.1 ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Trichlorofluoromethane mg/l 1.0 2000ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 1,2,3-Trichloropropane mg/l 1.0 0.005ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Vinyl acetate mg/l 2.0 NEND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Vinyl chloride mg/l 1.0 0.03ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Total Xylenes mg/l 2.0 500ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Naphthalene mg/l 1.0 6ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND 1,3-dichlorobenzene mg/l 1.0 200ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Dichlorodifluoromethane mg/l 1.0 1000ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP ND Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (8-29-2012) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (2-18-2013) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NE 6.50 5.90 6.00 6.00 6.30 6.10 5.70 6.60 7.50 6.20 8.59 6.30 6.10 5.80 6.20 6.50 6.70 5.70 5.80 6.10 NP 6.20 11.34 NT Specific Conductance mmhos/cm -NE 80 242 57 333 198 66 57 667 678 107 184.7 75 65 201 611 59 85 24 75.8 87.5 NP 56.4 891 NT Temperature °C -NE 11 12.2 12.6 13.4 10.4 9.9 10.9 15.2 14 12 14 11.5 11.7 11.1 11.8 10.9 11.4 12 9.8 9.5 NP 11.2 14.9 NT Turbidity NTU -NE 40 10.08 1.3 5.4 12.9 6.24 31.7 2.53 3.39 2.14 9.97 1.32 7.73 9.7 9.23 80 27.8 6.09 9.26 900 NP 4.53 15.3 NT Total Antimony (Sb)mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Total Arsenic (As)mg/l 10.0 10ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Total Barium (Ba)mg/l 5.0 700 216 229 16.2 200 41.3 75.7 86 95.5 42.6 118 56.1 65.6 91.5 131 265 100 54.5 45.6 103 1470 NP 31.6 64.6 ND Total Beryllium (Be)mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2.5 NP ND ND ND Total Cadmium (Cd)mg/l 1.0 2ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2.4 NP ND ND ND Total Chromium (Cr)mg/l 5.0 10 16 ND ND ND ND ND ND ND ND ND 6 1.7 2.6 ND ND 7 ND ND ND 292 NP ND 51.4 ND Total Cobalt (Co)mg/l 5.0 NE 7 14.8 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 72.7 NP ND ND ND Total Copper (Cu)mg/l 5.0 1000 9 7.3 ND ND ND ND ND ND ND ND ND ND ND ND ND 8.8 ND ND ND 207 NP ND 12.3 ND Total Lead (Pb)mg/l 5.0 15ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5.4 NP ND ND ND Total Mercury (Hg)mg/l 0.20 1ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Total Nickel (Ni)mg/l 5.0 100 11.3 6 ND ND ND ND ND ND ND ND ND ND ND ND 6.6 8.4 ND ND ND 104 NP ND 18.5 ND Total Selenium (Se)mg/l 10.0 20ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Total Silver (Ag)mg/l 5.0 20ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Total Thallium (Tl)mg/l 5.4 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Total Vanadium (V)mg/l 5.0 NE 20.8 ND ND ND 5.3ND ND ND ND ND ND ND ND ND ND 10.6 5.1 ND ND 393 NP ND 24.5 ND Total Zinc (Zn)mg/l 10 1000 13.6 11.5 19.5 ND 20.2ND ND ND ND ND ND ND 12.4 ND ND 24.8 21.4 ND ND 195 NP ND 39.2 ND Acetone mg/l 25.0 6000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Acrylonitrile mg/l 10.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Benzene mg/l 1.0 1ND 4.1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Bromochloromethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Bromodichloromethane mg/l 1.0 0.6ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Bromoform mg/l 1.0 4ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Carbon Disulfide mg/l 2.0 700ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND 3.9 ND Bromomethane (Methylbromide)mg/l 2.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Carbon tetrachloride mg/l 1.0 0.3ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Chlorobenzene (mono)mg/l 1.0 50ND ND ND 1.1 ND ND ND ND ND ND ND ND ND ND 2.3 ND ND ND ND ND NP ND ND ND Chloroethane mg/l 1.0 3000ND 2.4 ND 1.3 ND ND ND ND ND ND ND ND ND ND 2.1 ND ND ND ND ND NP ND ND ND Chloroform mg/l 1.0 70ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Chloromethane (Methylchloride)mg/l 1.0 3ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Dibromochloromethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5.0 0.04ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 0.02000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Dibromomethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 1,2-Dichlorobenzene mg/l 1.0 20ND ND ND 2.2 ND ND ND 5.9 9.2 ND ND ND ND 1.1 3.2 ND ND ND ND ND NP ND ND ND 1,4-Dichlorobenzene mg/l 1.0 6ND 1.1 ND 1.9 ND ND ND 1.6 1.6 ND ND ND ND 1.1 2.7 ND ND ND ND ND NP ND ND ND trans-1,4-Dichloro-2-butene mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 1,1-Dichloroethane mg/l 1.0 6ND 7.9 ND 2.9 ND ND 1.8 5.7 ND ND 1.1 ND ND 3.6 3.4 ND ND ND ND ND NP ND 3.1 ND 1,2-Dichloroethane mg/l 1.0 0.4ND ND ND 2.2 ND ND ND ND ND ND ND ND ND 3 3.7 ND ND ND ND ND NP ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 7ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 70ND 10.4 ND 2.6 ND ND 1.6 17.3 10.6 ND ND ND ND 1.1ND ND ND ND ND ND NP ND 2 ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 100ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 1,2-Dichloropropane mg/l 1.0 0.6ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 0.4ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 0.4ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Ethylbenzene mg/l 1.0 600ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 2-Hexanone mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Iodomethane mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Dichloromethane (Methylene chloride)mg/l 1.0 5ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND 2.4 ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 4000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 4-Methyl-2-Pentanone mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Styrene mg/l 1.0 70ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Tetrachloroethene (-ethylene)mg/l 1.0 0.7ND 4.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Toluene mg/l 1.0 600ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 1,1,1-Trichloroethane mg/l 1.0 200ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 1,1,2-Trichloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Trichloroethene (-ethylene)mg/l 1.0 3ND 3.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Trichlorofluoromethane mg/l 1.0 2000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 1,2,3-Trichloropropane mg/l 1.0 0.005ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Vinyl acetate mg/l 2.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Vinyl chloride mg/l 1.0 0.03ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Total Xylenes mg/l 2.0 500ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Naphthalene mg/l 1.0 6ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 1,3-dichlorobenzene mg/l 1.0 200ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Dichlorodifluoromethane mg/l 1.0 1000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (2-18-2013) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (8-26-2013) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NE 6.30 5.80 5.60 4.60 6.80 5.80 5.70 6.40 7.40 6.50 7.30 7.40 6.20 5.90 5.70 6.70 7.00 5.60 5.90 5.40 NP 6.30 11.55 NT Specific Conductance mmhos/cm -NE 87.3 264 72.6 354.3 233.1 121.9 61 650 718 95.2 174 67.1 63.8 209.6 627 60.5 91.5 18.4 73.8 96.6 NP 50.3 5440 NT Temperature °C -NE 13.7 15.5 17 16.4 20.9 18 19.5 16.4 15.1 14.4 14.2 14.6 14.1 17.5 16.3 16.1 15.7 14.7 18.4 18.9 NP 17.2 15.4 NT Turbidity NTU -NE 13 8.96 1.76 6.47 3.25 10.18 6.51 3.01 1.75 2.11 5.36 2.07 22 2.75 6.33 27 7200 9.1 6.98 24.7 NP 6.99 9.45 NT Total Antimony (Sb)mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Total Arsenic (As)mg/l 10.0 10ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Total Barium (Ba)mg/l 5.0 700 207 255 23.7 204 50.7 79.8 77.5 111 45.1 97.1 36.4 48.8 135 112 264 58.9 253 49.6 96.6 283 NP 42 106 ND Total Beryllium (Be)mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.1 ND ND ND NP ND ND ND Total Cadmium (Cd)mg/l 1.0 2ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Total Chromium (Cr)mg/l 5.0 10 6 ND ND ND ND ND ND ND ND ND ND ND 6.6 ND ND ND 23.8 ND ND 40.6 NP ND 151 ND Total Cobalt (Co)mg/l 5.0 NE 5.8 26.6 ND ND ND ND ND 5.3 ND ND ND ND 7.4 ND 13.3 ND 23.7 ND 5.4 22 NP ND ND ND Total Copper (Cu)mg/l 5.0 1000 6.3 8.4 ND ND ND ND ND ND ND ND ND ND 5.6 ND ND ND 28 ND ND 25.9 NP ND ND ND Total Lead (Pb)mg/l 5.0 15ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5.7 ND ND ND NP ND ND ND Total Mercury (Hg)mg/l 0.20 1ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Total Nickel (Ni)mg/l 5.0 100 5.1 8.1 ND ND ND ND ND ND ND ND ND ND 6.3 ND 6.2 ND 11.7 ND ND 14.3 NP ND ND ND Total Selenium (Se)mg/l 10.0 20ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 67.9 NP ND ND ND Total Silver (Ag)mg/l 5.0 20ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 102 NP ND ND ND Total Thallium (Tl)mg/l 5.4 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Total Vanadium (V)mg/l 5.0 NE 6.8 ND ND ND ND 6 ND ND ND ND ND ND 8.8 ND ND 5.8 37.2 ND ND ND NP ND ND ND Total Zinc (Zn)mg/l 10 1000 11 29 34.3 10.8 14.1 11.6 17.1ND ND ND ND ND 21.8 22.1 102 45 129 11.4 25.5ND NP 34.7 12.1 ND Acetone mg/l 25.0 6000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Acrylonitrile mg/l 10.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Benzene mg/l 1.0 1ND 3.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND 8.6 ND Bromochloromethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Bromodichloromethane mg/l 1.0 0.6ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Bromoform mg/l 1.0 4ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Carbon Disulfide mg/l 2.0 700ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND 5.8 ND Bromomethane (Methylbromide)mg/l 2.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Carbon tetrachloride mg/l 1.0 0.3ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Chlorobenzene (mono)mg/l 1.0 50ND ND ND 1.2 ND ND ND ND ND ND ND ND ND ND 2.3 ND ND ND ND ND NP ND ND ND Chloroethane mg/l 1.0 3000ND 2.1 ND 1.5 ND ND ND ND ND ND ND ND ND ND 2.8 ND ND ND ND ND NP ND 2.4 ND Chloroform mg/l 1.0 70ND ND ND ND ND ND ND ND ND 2.3 ND ND ND ND ND ND ND ND ND ND NP ND ND ND Chloromethane (Methylchloride)mg/l 1.0 3ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Dibromochloromethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5.0 0.04ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 0.02000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Dibromomethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 1,2-Dichlorobenzene mg/l 1.0 20ND ND ND 2.6 ND ND ND 4.2 8.2 ND ND ND ND 1.2 3.4 ND ND ND ND ND NP ND ND ND 1,4-Dichlorobenzene mg/l 1.0 6ND 1.1 ND 2.2 ND ND ND 1.5 1.1 ND ND ND ND 1.2 3 ND ND ND ND ND NP ND 3.9 ND trans-1,4-Dichloro-2-butene mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 1,1-Dichloroethane mg/l 1.0 6ND 7.8 ND 2.6 ND ND 1.5 6.6 ND ND 1.1 ND ND 2.8 2.7 ND ND ND ND ND NP ND 16.3 ND 1,2-Dichloroethane mg/l 1.0 0.4ND ND ND 1.9 ND ND ND ND ND ND ND ND ND 2.5 3 ND ND ND ND ND NP ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 7ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 70ND 8.6 ND 1.8 ND 1.1 1.4 17.2 4.5 ND ND ND ND 1.1ND ND ND ND ND ND NP ND 23.2 ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 100ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 1,2-Dichloropropane mg/l 1.0 0.6ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 0.4ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 0.4ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Ethylbenzene mg/l 1.0 600ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 2-Hexanone mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Iodomethane mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Dichloromethane (Methylene chloride)mg/l 1.0 5ND 2.9 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND 28.3 ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 4000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 4-Methyl-2-Pentanone mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Styrene mg/l 1.0 70ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Tetrachloroethene (-ethylene)mg/l 1.0 0.7ND 4.4 ND ND ND ND ND 1 ND ND ND ND ND ND ND ND ND ND ND ND NP ND 3.3 ND Toluene mg/l 1.0 600ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 1,1,1-Trichloroethane mg/l 1.0 200ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 1,1,2-Trichloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Trichloroethene (-ethylene)mg/l 1.0 3ND 3.8 ND ND ND ND ND 1.1 ND ND ND ND ND ND ND ND ND ND ND ND NP ND 3.7 ND Trichlorofluoromethane mg/l 1.0 2000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND 1,2,3-Trichloropropane mg/l 1.0 0.005ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Vinyl acetate mg/l 2.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Vinyl chloride mg/l 1.0 0.03ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Total Xylenes mg/l 2.0 500ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Naphthalene mg/l 1.0 6ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND 7.7 ND 1,3-dichlorobenzene mg/l 1.0 200ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Dichlorodifluoromethane mg/l 1.0 1000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND ND Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (8-26-2013) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (2-20-2014) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NE 6.60 5.80 5.80 5.90 6.30 5.90 5.50 6.40 7.40 6.10 7.20 6.00 5.90 5.80 6.10 6.30 6.60 5.40 5.80 5.80 6.80 6.10 10.15 NT Specific Conductance mmhos/cm -NE 107 258 >4 383 208.0 115 62 617 701 89 186 77 60 440.0 639 61 91 18 72 87 124 55 663 NT Temperature °C -NE 12 12.5 11.3 12.5 10.5 11.4 11.6 15 13.2 11.3 11.8 11.6 14 13.6 12.8 13.4 12 14.1 7.8 11 10.3 12.5 14.8 NT Turbidity NTU -NE 9.2 1.42 3.3 4.6 2.87 3.7 67 2.87 3.29 15.8 6.71 2.96 6.54 2.22 3.12 3.38 55 100 5.59 2.28 206 4.2 4.56 NT Total Antimony (Sb)mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10.0 10ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5.0 700 185 210 16.8 214 13 92.5 97.3 85.3 40.1 176 38.6 48.8 80.1 183 278 32.5 109 122 74.7 86.9 70.8 42.8 19.2 ND Total Beryllium (Be)mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1.0 2ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5.0 10 6.5 ND ND ND ND ND ND ND ND 5.6 ND ND ND ND ND ND 10.8 11 ND ND ND ND ND ND Total Cobalt (Co)mg/l 5.0 NEND 6.9 ND ND ND ND ND ND ND ND ND ND ND 10.2 13.9 ND ND 6 ND ND ND ND ND ND Total Copper (Cu)mg/l 5.0 1000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 10.8 8.3 ND ND ND ND ND ND Total Lead (Pb)mg/l 5.0 15ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Mercury (Hg)mg/l 0.20 1ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5.0 100 8 ND ND ND ND ND ND ND ND ND ND ND ND ND 6.5 ND ND ND ND ND ND ND ND ND Total Selenium (Se)mg/l 10.0 20ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5.0 20ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NEND ND ND ND ND 6.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5.0 NE 7.4 ND ND ND ND 6.5 7.6ND ND 12.8 ND ND ND ND ND ND 15.8 16.5 ND 5.3 ND ND 9.2 ND Total Zinc (Zn)mg/l 10 1000ND ND ND 54 ND ND ND ND ND 14 ND ND ND 12.5ND ND 42.2 22.2 35.2ND ND 13.8 ND ND Acetone mg/l 25.0 6000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1.0 1ND 4.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5.7 ND Bromochloromethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1.0 0.6ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1.0 4ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2.0 700ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1.0 0.3ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1.0 50ND ND ND 1.2 ND ND ND ND ND ND ND ND ND 1.8 2.0 ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1.0 3000ND 1.4 ND 1.2 ND ND ND ND ND ND ND ND ND 1.7 1.6 ND ND ND ND ND ND ND ND ND Chloroform mg/l 1.0 70ND ND ND ND ND ND ND ND ND 1.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1.0 3ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5.0 0.04ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 0.02ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1.0 20ND ND ND 2.8 ND ND ND 3.3 7.2 ND ND ND ND 3.1 3.3 ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1.0 6ND 1.4 ND 2.3 ND ND ND 1 ND ND ND ND ND 2.8 2.5 ND ND ND ND ND ND ND 2.8 ND trans-1,4-Dichloro-2-butene mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1.0 6ND 6.8 ND 2.3 ND ND 1.1 5.2 ND ND 1.2 ND ND 3.4 2.3 ND 1.1 ND ND ND ND ND 8.7 ND 1,2-Dichloroethane mg/l 1.0 0.4ND ND ND 1.7 ND ND ND ND ND ND ND ND ND 3 2.6 ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 7ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 70ND 10.2 ND 1.6 ND 1 1.2 14.8 3.7 ND ND ND ND 1.9ND ND ND ND ND ND ND ND 14.1 ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 100ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1.0 0.6ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 0.4ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 0.4ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1.0 600ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 1.0 5ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 4000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1.0 70ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1.0 0.7ND 5.1 ND ND ND ND ND 1.1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.3 ND Toluene mg/l 1.0 600ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1.0 200ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1.0 3ND 4.1 ND ND ND ND ND 1.2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.9 ND Trichlorofluoromethane mg/l 1.0 2000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1.0 0.005ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1.0 0.03ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Xylenes mg/l 2.0 500ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Naphthalene mg/l 1.0 6ND ND 1.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 8.9 ND 1,3-dichlorobenzene mg/l 1.0 200ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichlorodifluoromethane mg/l 1.0 1000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (2-20-2014) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (8-28-14) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NE 6.60 5.90 5.90 6.20 6.50 6.00 6.00 6.60 7.50 6.50 7.40 6.60 6.50 5.80 6.30 6.40 7.00 5.80 5.90 6.10 7.20 6.30 8.30 NT Specific Conductance mmhos/cm -NE 113 217 65 340 249.0 107 59 600 672 93 182 81 58 238 632 64 94 17 68 99 120 40 540 NT Temperature °C -NE 13.6 13.9 16.9 15.8 18.3 17.9 18.9 15.7 15.4 15.6 14.5 14.9 16.2 19.4 17.5 17.1 17.5 14.5 16 21.1 15.9 17.7 15.7 NT Turbidity NTU -NE 10 10.05 5.79 4.36 4.88 1.61 5.97 315 4.73 14.2 3.31 7.15 8.18 1.95 2.09 24.8.50 2.01 10 6.39 2.43 2.04 65 NT Total Antimony (Sb)mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10.0 10ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5.0 700 339 199 39.2 183 34.2 54.4 67.6 82.3 38 134 32.5 60 92.8 136 272 46.3 119 28.5 80 107 69.2 22.7 30.8 ND Total Beryllium (Be)mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1.0 2ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5.0 10 20.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 11.6 ND ND ND ND ND 8.8 ND Total Cobalt (Co)mg/l 5.0 NEND 8.1 ND ND ND ND ND ND ND ND ND ND ND ND 11.6 ND ND ND ND ND ND ND ND ND Total Copper (Cu)mg/l 5.0 1000 7.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 13.1 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5.0 15ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Mercury (Hg)mg/l NT 1NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT Total Nickel (Ni)mg/l 5.0 100 17.3 5.5 ND ND ND ND ND ND ND ND ND ND ND ND 11.2 ND 6.9 ND ND ND ND ND ND ND Total Selenium (Se)mg/l 10.0 20ND ND ND ND ND ND ND ND 15 ND ND ND ND ND ND ND ND ND ND ND ND ND 12 ND Total Silver (Ag)mg/l 5.0 20ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5.0 NE 24.8 ND ND ND ND ND ND ND ND 7.3 ND ND ND ND ND ND 17.3 ND ND 15.4 ND ND 5.3 ND Total Zinc (Zn)mg/l 10 1000 20.7 ND 83 ND ND ND ND ND ND 11.8 ND ND 10.4 ND ND ND 27.7 ND ND ND ND ND ND ND Acetone mg/l 25.0 6000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1.0 1ND 3.2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 ND Bromochloromethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1.0 0.6ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1.0 4ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2.0 700ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1.0 0.3ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1.0 50ND ND ND 1.3 ND ND ND ND ND ND ND ND ND ND 2.3 ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1.0 3000ND 1.8 ND 1.8 ND ND ND ND ND ND ND ND ND ND 2.6 ND ND ND ND ND ND ND ND ND Chloroform mg/l 1.0 70ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1.0 3ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 2.0 0.04ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 0.02ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1.0 20ND ND ND 2.6 ND ND ND 2.5 6.3 ND ND ND ND 1.5 3.4 ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1.0 6ND ND ND 2.3 ND ND ND ND ND ND ND ND ND 1.8 3 ND ND ND ND ND ND ND 1.4 ND trans-1,4-Dichloro-2-butene mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1.0 6ND 8.1 ND 3 ND 1.1 1.6 6 ND ND 1.4 ND ND 3.9 2.9 ND 1.2 ND ND ND ND ND 14.7 ND 1,2-Dichloroethane mg/l 1.0 0.4ND ND ND 2 ND ND ND ND ND ND ND ND ND 3 3 ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 7ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 70ND 7.9 ND 2.4 ND 1.5 1.6 17.4 3 ND 1 ND ND 1.7ND ND 1.1 ND ND ND ND ND 14.8 ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 100ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1.0 0.6ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 0.4ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 0.4ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1.0 600ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2.0 5ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5.5 ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 4000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1.0 70ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1.0 0.7ND 4.2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.6 ND Toluene mg/l 1.0 600ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1.0 200ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1.0 3ND 3.6 ND ND ND ND ND 1.1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2.2 ND Trichlorofluoromethane mg/l 1.0 2000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1.0 0.005ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1.0 0.03ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Xylenes mg/l 2.0 500ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Naphthalene mg/l NT 6NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT 1,3-dichlorobenzene mg/l NT 200NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT Dichlorodifluoromethane mg/l NT 1000NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (8-28-14) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (3-20-15) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NE 6.30 5.80 6.00 5.80 6.60 6.40 5.90 6.30 7.00 6.30 6.70 6.80 6.60 5.80 6.10 6.90 6.70 6.20 6.00 6.60 6.70 6.90 8.10 NT Specific Conductance mmhos/cm -NE 99 198.3 52 297 168.0 121 58 517.8 651.1 109.5 181.8 68.1 60.1 229.0 574 64.3 83.5 18.7 64.6 100 109.5 63.1 429.4 NT Temperature °C -NE 10.1 10.4 10.7 12 10.1 9.1 10.7 12.9 11.3 10.9 10.4 10.7 10.5 11.4 12.1 13 12.3 12.8 6.7 7.3 8.5 10.5 11.2 NT Turbidity NTU -NE 4.34 1.8 11.2 11.7 8.89 19.4 28.2 3.87 7.4 15.2 4.87 2.7 5.68 2.87 4.27 16.7 80.8 3.98 6.07 33.9 6.92 1.63 9.42 NT Total Antimony (Sb)mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10.0 10ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5.0 700 138 171 60.5 181 25.8 137 87.2 55.4 46.9 171 32.7 45.1 68 136 271 68.3 187 32.3 67.1 198 73.5 27.2 32.9 ND Total Beryllium (Be)mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1.0 2ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5.0 10 5.1 ND 6.9 ND 6.2 12.4 ND ND ND ND ND ND ND ND ND 6 17.3 ND ND 24.7 ND ND 12 ND Total Cobalt (Co)mg/l 5.0 NEND 5.3 ND ND ND ND ND ND ND ND ND ND ND ND 12.6 ND ND ND ND 5.6 ND ND ND ND Total Copper (Cu)mg/l 5.0 1000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 6.8 21.2 ND ND 16.9 ND ND ND ND Total Lead (Pb)mg/l 5.0 15ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 6.3 ND ND ND ND ND ND ND Total Mercury (Hg)mg/l 0.20 1ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5.0 100 13.2 5.2 ND ND ND 6.5 ND ND ND ND ND ND ND ND 13 ND 10.7 ND ND 10.2 ND ND 8.8 ND Total Selenium (Se)mg/l 10.0 20ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5.0 20ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5.0 NE 5.8 ND 8.9 ND ND 14.3 5.2ND ND 10.9 ND ND ND ND ND 8.1 27.2 ND ND 42.9 ND ND ND ND Total Zinc (Zn)mg/l 10 1000 21.2 ND 39.4 ND ND 14.5 ND 19.6 ND 61.5 ND ND ND 57.3 18.8 26.7 48.1 ND 16.7 112 ND ND 15 ND Acetone mg/l 25.0 6000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 50.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1.0 1ND 1.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1.0 0.6ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1.0 4ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2.0 700ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1.0 0.3ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1.0 50ND ND ND 1.1 ND ND ND ND ND ND ND ND ND ND 2.1 ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1.0 3000ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2 ND ND ND ND ND ND ND ND ND Chloroform mg/l 1.0 70ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1.0 3ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 2.0 0.04ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 0.02ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1.0 20ND ND ND 1.9 ND ND ND 1.9 5.7 ND ND ND ND 1.1 3.2 ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1.0 6ND ND ND 2 ND ND ND ND ND ND ND ND ND 1.3 2.8 ND ND ND ND ND ND ND 1.2 ND trans-1,4-Dichloro-2-butene mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1.0 6ND 4.3 ND 2.4 ND ND 1.6 5 ND ND 1.2 ND ND 3 2.4 ND 1 ND ND ND ND ND 10.9 ND 1,2-Dichloroethane mg/l 1.0 0.4ND ND ND 1.8 ND ND ND ND ND ND ND ND ND 2.6 3 ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 7ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 70ND 2.9 ND 1.8 ND ND 1.4 12.2 1.8 ND ND ND ND 1.3ND ND ND ND ND ND ND ND 9.2 ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 100ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1.0 0.6ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 0.4ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 0.4ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1.0 600ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 1.0 5ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4.9 ND 2-Butanone (Methyl ethyl ketone)mg/l 2.0 4000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1.0 70ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1.0 0.7ND 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 ND Toluene mg/l 1.0 600ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1.0 200ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1.0 3ND 2.0 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.3 ND Trichlorofluoromethane mg/l 1.0 2000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1.0 0.005ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1.0 0.03ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Xylenes mg/l 2.0 500ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Naphthalene mg/l 1.0 6ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,3-dichlorobenzene mg/l 1.0 200ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichlorodifluoromethane mg/l 1.0 1000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled 8. The monitoring wells were sampled between February 20 and March 20, 2015. to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (3-20-15) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (8-26-15) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NE 6.45 5.54 6.17 5.75 6.21 5.81 5.35 6.47 7.06 6.85 6.74 6.19 6.99 5.76 6.13 6.58 6.98 7.82 6.28 6.18 6.36 6.30 7.41NT Specific Conductance mmhos/cm -NE 79.1 156.9 59.3 230.7 183.7 93.4 46.5 14.5 532 88.3 173.4 65.3 48.9 187.5 490.8 47.1 69.4 20.7 56.7 74.9 90.7 29.2 533NT Temperature °C -NE 13.5 16.6 18.1 16.5 18.2 17.3 19.1 341.6 18.7 15.7 15.1 16 16 19.4 17.3 17.2 17.4 16.6 17.3 15.5 14.4 14.9 20.3NT Turbidity NTU -NE >1000 13.6 >1000 >1000 >1000 195 >1000 49.1 41.3 297 95 229 84.4 >1000 68.3 >1000 >1000 407>1000 88.1 22 >1000 28NT Total Antimony (Sb)mg/l 20.0 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 15.0 10 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 25.0 700 150 160 64 170 91 68 97 52 53 200 62 72 92 140 270 54 66 50 120 110 66 63 45ND Total Beryllium (Be)mg/l 5.0 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 5.0 2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 10.0 10 ND ND ND ND 16 ND ND ND ND ND 25ND ND ND ND ND ND ND ND 11 ND ND ND ND Total Cobalt (Co)mg/l 25.0 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Copper (Cu)mg/l 10.0 1000 ND ND ND 11 ND ND 12 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Lead (Pb)mg/l 10.0 15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Mercury (Hg)mg/l NT 1 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT Total Nickel (Ni)mg/l 40.0 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Selenium (Se)mg/l 20.0 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 10.0 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 50.0 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 50.0 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Zinc (Zn)mg/l 20 1000 ND ND 27 ND 67 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acetone mg/l 20.0 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 20.0 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1.0 1 ND 1.2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1.0 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1.0 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1.0 4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 1.0 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2.0 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1.0 0.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1.0 50 ND ND ND 1.2 ND ND ND ND ND ND ND ND ND ND 2.2 ND ND ND ND ND ND ND ND ND Chloroethane mg/l 2.0 3000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroform mg/l 1.0 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1.0 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1.0 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 1.0 0.04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 0.02 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1.0 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1.0 20 ND ND ND 2.7 ND ND ND ND 7.6 ND ND ND ND 1.6 3.7 ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1.0 6 ND ND ND 2.2 ND ND ND ND ND ND ND ND ND 1.6 3 ND ND ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1.0 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1.0 6 ND 4.1 ND 2.8 ND 1.1 1.5 6.8 ND ND 1.5ND ND 3.8 2.7 ND ND ND ND ND ND ND 9.1ND 1,2-Dichloroethane mg/l 1.0 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND 2.7 2.8 ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 70 ND 2.4 ND 2.6 ND 1.3 1.3 12 2.2 ND ND ND ND 1.9 ND ND ND ND ND ND ND ND 5.2ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1.0 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1.0 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 10.0 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5.0 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 1.0 5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 10.0 4000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 10.0 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1.0 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1.0 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1.0 0.7 ND 2.6 ND ND ND ND ND 1.1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene mg/l 1.0 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1.0 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1.0 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1.0 3 ND 1.6 ND ND ND ND ND 1.1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1.0 2000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1.0 0.005 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 5.0 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1.0 0.03 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Xylenes mg/l 1.0 500 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Naphthalene mg/l NT 6 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT 1,3-dichlorobenzene mg/l 1.0 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichlorodifluoromethane mg/l 2.0 1000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (8-26-15) Closed Francis Farm Landfill - Haywood Co., NC Groundwater Sampling Event (3-17-16) TEST UNITS MRL MCL MW-12 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-15 MW-16 MW- 16D MW-17 MW-18 MW-19 MW- 19D MW-20 MW- 20D MW-21 MW-22 MW-23 MW- 23D MW-24 MW-25 EQUIP. BLANK pH pH units -NE 6.43 5.64 5.45 5.96 5.95 5.70 5.37 6.85 7.77 6.50 7.22 6.00 5.70 5.76 6.15 6.14 6.48 4.98 5.59 5.90 6.53 5.68 5.69 NT Specific Conductance mmhos/cm -NE 85.6 178.7 71.8 358.6 191.0 114.1 61.2 449.8 553 102.6 202.7 92.6 60.8 184.4 550 64.6 97.8 19.2 66.8 87.2 115.9 38.5 524 NT Temperature °C -NE 13.3 12.1 10.8 13.2 11.8 11.6 11.6 16.8 14.8 14.9 18.5 13.5 13.3 12.1 14.4 14.3 13.9 13.8 12.3 12.7 15.3 14.1 16.8 NT Turbidity NTU -NE 133 33.1 1000 1000 184 424 886 14.8 105 1000 13.4 81.2 9.38 976 4.6 1000 1000 250 550 56.4 4.43 87.5 14.2 NT Total Antimony (Sb)mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10.0 10ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5.0 700 160 190 ND 260 25 69 72 54 38 150 40 170 81 110 290 25 88 43 69 97 68 33 32 ND Total Beryllium (Be)mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1.0 2ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5.0 10ND ND ND ND ND ND ND ND ND ND 15 25ND ND ND ND ND ND ND ND ND ND ND ND Total Cobalt (Co)mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Copper (Cu)mg/l 5.0 1000ND ND ND ND ND ND ND ND ND ND ND 12ND ND ND ND ND ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5.0 15ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Mercury (Hg)mg/l 0.20 1NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT Total Nickel (Ni)mg/l 5.0 100ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Selenium (Se)mg/l 10.0 20ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5.0 20ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Zinc (Zn)mg/l 10 1000ND ND 50 ND ND ND ND ND ND 26 26 22ND 72 45 ND 34 ND ND ND ND ND 47 ND Acetone mg/l 25.0 6000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1.0 1ND 1.5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.7 ND Bromochloromethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1.0 0.6ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1.0 4ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2.0 700ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1.0 0.3ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1.0 50ND ND ND 1.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1.0 3000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroform mg/l 1.0 70ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1.0 3ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5.0 0.04ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 0.02ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1.0 20ND ND ND 3 ND ND ND 3.6 8.9 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1.0 6ND ND ND 2.4 ND ND ND 1.1 1.4 ND ND ND ND ND ND ND ND ND ND ND ND ND 1.4 ND trans-1,4-Dichloro-2-butene mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1.0 6ND 4.7 ND 2.8 ND 1.6 1.8 6.8 ND ND 1.5 ND ND 2.2ND 1.1 1.4 ND ND ND ND ND 11 ND 1,2-Dichloroethane mg/l 1.0 0.4ND ND ND 1.8 ND ND ND ND ND ND ND ND ND 1.3ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 7ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 70ND 2.8 ND 1.9 ND 1.7 1.8 16 4.4 ND ND ND ND ND ND ND 1 ND ND ND ND ND 8 ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 100ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1.0 0.6ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 0.4ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 0.4ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1.0 600ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 1.0 5ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 4000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1.0 70ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1.0 0.7ND 3.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.5 ND Toluene mg/l 1.0 600ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1.0 200ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1.0 3ND 1.7 ND ND ND ND ND 1.1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.7 ND Trichlorofluoromethane mg/l 1.0 2000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1.0 0.005ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2.0 NEND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1.0 0.03ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Xylenes mg/l 2.0 500ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Naphthalene mg/l 1.0 6ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,3-dichlorobenzene mg/l 1.0 200ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichlorodifluoromethane mg/l 1.0 1000ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable5. NS = Not Sampled to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Shaded cells indicated exceedances of MCLs.6. NT = Not Tested 2. NE = Not Established; North Carolina has not established a MCL 7. NP = Not Present during sampling event 3. MRL = Laboratory Method Reporting Limit 8 . A = Well abandoned 4. ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. 1957-48 Francis Farm GW Stats 1st 2016.xlsm (3-17-16) APPENDIX B SUMMARY TABLES OF SURFACE WATER ANALYTICAL RESULTS Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (2-18-1999) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 7 7 6.7 Specific Conductance mmhos/cm (on-site)1 NE 32 41 75 Temperature °C (on-site)-29 9.4 10 12 Turbidity NTU (on-site)0.1 50 NT NT NT Total Antimony (Sb)mg/l 30 NE NT NT NT Total Arsenic (As)mg/l 10 10 ND ND ND Total Barium (Ba)mg/l 500 NE ND ND ND Total Beryllium (Be)mg/l 2 6.5 NT NT NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND Total Chromium (Cr)mg/l 10 50 ND ND ND Total Cobalt (Co)mg/l 10 NE NT NT NT Total Copper (Cu)mg/l 200 7 NT NT NT Total Lead (Pb)mg/l 10 25 ND ND ND Total Mercury (Hg)mg/l 0.2 0.012 ND ND ND Total Nickel (Ni)mg/l 50 88 NT ND NT Total Selenium (Se)mg/l 20 5 ND ND ND Total Silver (Ag)mg/l 10 0.06 ND ND ND Total Thallium (Tl)mg/l 10 NE NT NT NT Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l 50 50 NT NT NT Acetone mg/l 100 NE NT NT NT Acrylonitrile mg/l 200 NE NT NT NT Benzene mg/l 5 51 NT NT NT Bromochloromethane mg/l 5 NE NT NT NT Bromodichloromethane mg/l 5 NE NT NT NT Bromoform mg/l 5 NE NT NT NT Carbon Disulfide mg/l 100 NE NT NT NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NT Carbon tetrachloride mg/l 10 1.6 NT NT NT Chlorobenzene (mono)mg/l 5 NE NT NT NT Chloroethane mg/l 10 NE NT NT NT Chloroform mg/l 5 NE NT NT NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NT Dibromochloromethane mg/l 5 NE NT NT NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE NT NT NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE NT NT NT Dibromomethane mg/l 10 NE NT NT NT 1,2-Dichlorobenzene mg/l 5 NE NT NT NT 1,4-Dichlorobenzene mg/l 5 NE NT NT NT trans-1,4-Dichloro-2butene mg/l 100 NE NT NT NT 1,1-Dichloroethane mg/l 5 NE NT NT NT 1,2-Dichloroethane mg/l 5 NE NT NT NT 1,1-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT trans-1,2-Dichloroethene (-ylene)mg/l 5 NE NT NT NT 1,2-Dichloropropane mg/l 5 NE NT NT NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT Ethylbenzene mg/l 5 NE NT NT NT 2-Hexanone mg/l 50 NE NT NT NT Iodomethane mg/l 10 NE NT NT NT Dichloromethane (Methylene chloride)mg/l 10 NE NT NT NT 2-Butanone (Methyl ethyl ketone)mg/l 100 NE NT NT NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NT Styrene mg/l 10 NE NT NT NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NT 1,1,2,2-Tetrachloroethane mg/l 5 4 NT NT NT Tetrachloroethene (-ethylene)mg/l 5 3.3 NT NT NT Toluene mg/l 5 0.36 NT NT NT 1,1,1-Trichloroethane mg/l 5 NE NT NT NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NT Trichloroethene (-ethylene)mg/l 5 30 NT NT NT Trichlorofluoromethane mg/l 5 NE NT NT NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NT Vinyl acetate mg/l 50 NE NT NT NT Vinyl chloride mg/l 10 2.4 NT NT NT Total Xylenes mg/l 5 NE NT NT NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (2-18-1999) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (8-16-1999) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 6.2 6.3 6.3 Specific Conductance mmhos/cm (on-site)1 NE 60 80 100 Temperature °C (on-site)-29 19 21 22 Turbidity NTU (on-site)0.1 50 NT NT NT Total Antimony (Sb)mg/l 30 NE NT NT NT Total Arsenic (As)mg/l 10 10 ND ND ND Total Barium (Ba)mg/l 500 NE 29 29 29 Total Beryllium (Be)mg/l 2 6.5 NT NT NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND Total Chromium (Cr)mg/l 10 50 ND ND ND Total Cobalt (Co)mg/l 10 NE NT NT NT Total Copper (Cu)mg/l 200 7 NT NT NT Total Lead (Pb)mg/l 10 25 ND ND ND Total Mercury (Hg)mg/l 0.2 0.012 ND ND ND Total Nickel (Ni)mg/l 50 88 NT NT NT Total Selenium (Se)mg/l 20 5 ND ND ND Total Silver (Ag)mg/l 10 0.06 ND ND ND Total Thallium (Tl)mg/l 10 NE NT NT NT Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l 50 50 NT NT NT Acetone mg/l 100 NE NT NT NT Acrylonitrile mg/l 200 NE NT NT NT Benzene mg/l 5 51 NT NT NT Bromochloromethane mg/l 5 NE NT NT NT Bromoform mg/l 5 NE NT NT NT Bromofrom mg/l 5 NE NT NT NT Carbon Disulfide mg/l 100 NE NT NT NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NT Carbon tetrachloride mg/l 10 1.6 NT NT NT Chlorobenzene (mono)mg/l 5 NE NT NT NT Chloroethane mg/l 10 NE NT NT NT Chloroform mg/l 5 NE NT NT NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NT Dibromochloromethane mg/l 5 NE NT NT NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE NT NT NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE NT NT NT Dibromomethane mg/l 10 NE NT NT NT 1,2-Dichlorobenzene mg/l 5 NE NT NT NT 1,4-Dichlorobenzene mg/l 5 NE NT NT NT trans-1,4-Dichloro-2butene mg/l 100 NE NT NT NT 1,1-Dichloroethane mg/l 5 NE NT NT NT 1,2-Dichloroethane mg/l 5 NE NT NT NT 1,1-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT trans-1,2-Dichloroethene (-ylene)mg/l 5 NE NT NT NT 1,2-Dichloropropane mg/l 5 NE NT NT NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT Ethylbenzene mg/l 5 NE NT NT NT 2-Hexanone mg/l 50 NE NT NT NT Iodomethane mg/l 10 NE NT NT NT Dichloromethane (Methylene chloride)mg/l 10 NE NT NT NT 2-Butanone (Methyl ethyl ketone)mg/l 100 NE NT NT NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NT Styrene mg/l 10 NE NT NT NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NT 1,1,2,2-Tetrachloroethane mg/l 5 4 NT NT NT Tetrachloroethene (-ethylene)mg/l 5 3.3 NT NT NT Toluene mg/l 5 0.36 NT NT NT 1,1,1-Trichloroethane mg/l 5 NE NT NT NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NT Trichloroethene (-ethylene)mg/l 5 30 NT NT NT Trichlorofluoromethane mg/l 5 NE NT NT NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NT Vinyl acetate mg/l 50 NE NT NT NT Vinyl chloride mg/l 10 2.4 NT NT NT Total Xylenes mg/l 5 NE NT NT NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (8-16-1999) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (2-14-2000) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 6.2 6.2 6.4 Specific Conductance mmhos/cm (on-site)1 NE 55 70 110 Temperature °C (on-site)-29 10 10 9 Turbidity NTU (on-site)0.1 50 NT NT NT Total Antimony (Sb)mg/l 30 NE NT NT NT Total Arsenic (As)mg/l 10 10 ND ND ND Total Barium (Ba)mg/l 500 NE 43 69 56 Total Beryllium (Be)mg/l 2 6.5 NT NT NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND Total Chromium (Cr)mg/l 10 50 ND 7.5 ND Total Cobalt (Co)mg/l 10 NE NT NT NT Total Copper (Cu)mg/l 200 7 NT NT NT Total Lead (Pb)mg/l 10 25 ND ND ND Total Mercury (Hg)mg/l 0.2 0.012 ND ND ND Total Nickel (Ni)mg/l 50 88 NT ND NT Total Selenium (Se)mg/l 20 5 ND ND ND Total Silver (Ag)mg/l 10 0.06 ND ND ND Total Thallium (Tl)mg/l 10 NE NT NT NT Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l 50 50 NT NT NT Acetone mg/l 100 NE NT NT NT Acrylonitrile mg/l 200 NE NT NT NT Benzene mg/l 5 51 NT NT NT Bromochloromethane mg/l 5 NE NT NT NT Bromodichloromethane mg/l 5 NE NT NT NT Bromoform mg/l 5 NE NT NT NT Carbon Disulfide mg/l 100 NE NT NT NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NT Carbon tetrachloride mg/l 10 1.6 NT NT NT Chlorobenzene (mono)mg/l 5 NE NT NT NT Chloroethane mg/l 10 NE NT NT NT Chloroform mg/l 5 NE NT NT NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NT Dibromochloromethane mg/l 5 NE NT NT NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE NT NT NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE NT NT NT Dibromomethane mg/l 10 NE NT NT NT 1,2-Dichlorobenzene mg/l 5 NE NT NT NT 1,4-Dichlorobenzene mg/l 5 NE NT NT NT trans-1,4-Dichloro-2butene mg/l 100 NE NT NT NT 1,1-Dichloroethane mg/l 5 NE NT NT NT 1,2-Dichloroethane mg/l 5 NE NT NT NT 1,1-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT trans-1,2-Dichloroethene (-ylene)mg/l 5 NE NT NT NT 1,2-Dichloropropane mg/l 5 NE NT NT NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT Ethylbenzene mg/l 5 NE NT NT NT 2-Hexanone mg/l 50 NE NT NT NT Iodomethane mg/l 10 NE NT NT NT Dichloromethane (Methylene chloride)mg/l 10 NE NT NT NT 2-Butanone (Methyl ethyl ketone)mg/l 100 NE NT NT NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NT Styrene mg/l 10 NE NT NT NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NT 1,1,2,2-Tetrachloroethane mg/l 5 4 NT NT NT Tetrachloroethene (-ethylene)mg/l 5 3.3 NT NT NT Toluene mg/l 5 0.36 NT NT NT 1,1,1-Trichloroethane mg/l 5 NE NT NT NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NT Trichloroethene (-ethylene)mg/l 5 30 NT NT NT Trichlorofluoromethane mg/l 5 NE NT NT NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NT Vinyl acetate mg/l 50 NE NT NT NT Vinyl chloride mg/l 10 2.4 NT NT NT Total Xylenes mg/l 5 NE NT NT NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (2-14-2000) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (8-14-2000) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 6.4 6.8 6.6 Specific Conductance mmhos/cm (on-site)1 NE 52 78 110 Temperature °C (on-site)-29 17 19 20 Turbidity NTU (on-site)0.1 50 NT NT NT Total Antimony (Sb)mg/l 30 NE NT NT NT Total Arsenic (As)mg/l 10 10 ND ND ND Total Barium (Ba)mg/l 500 NE 28 35 36 Total Beryllium (Be)mg/l 2 6.5 NT NT NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND Total Chromium (Cr)mg/l 10 50 ND ND ND Total Cobalt (Co)mg/l 10 NE NT NT NT Total Copper (Cu)mg/l 200 7 NT NT NT Total Lead (Pb)mg/l 10 25 ND ND ND Total Mercury (Hg)mg/l 0.2 0.012 ND ND ND Total Nickel (Ni)mg/l 50 88 NT NT NT Total Selenium (Se)mg/l 20 5 ND ND ND Total Silver (Ag)mg/l 10 0.06 18 12 9.6 Total Thallium (Tl)mg/l 10 NE NT NT NT Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l 50 50 NT NT NT Acetone mg/l 100 NE NT NT NT Acrylonitrile mg/l 200 NE NT NT NT Benzene mg/l 5 51 NT NT NT Bromochloromethane mg/l 5 NE NT NT NT Bromodichloromethane mg/l 5 NE NT NT NT Bromoform mg/l 5 NE NT NT NT Carbon Disulfide mg/l 100 NE NT NT NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NT Carbon tetrachloride mg/l 10 1.6 NT NT NT Chlorobenzene (mono)mg/l 5 NE NT NT NT Chloroethane mg/l 10 NE NT NT NT Chloroform mg/l 5 NE NT NT NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NT Dibromochloromethane mg/l 5 NE NT NT NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE NT NT NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE NT NT NT Dibromomethane mg/l 10 NE NT NT NT 1,2-Dichlorobenzene mg/l 5 NE NT NT NT 1,4-Dichlorobenzene mg/l 5 NE NT NT NT trans-1,4-Dichloro-2butene mg/l 100 NE NT NT NT 1,1-Dichloroethane mg/l 5 NE NT NT NT 1,2-Dichloroethane mg/l 5 NE NT NT NT 1,1-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT trans-1,2-Dichloroethene (-ylene)mg/l 5 NE NT NT NT 1,2-Dichloropropane mg/l 5 NE NT NT NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT Ethylbenzene mg/l 5 NE NT NT NT 2-Hexanone mg/l 50 NE NT NT NT Iodomethane mg/l 10 NE NT NT NT Dichloromethane (Methylene chloride)mg/l 10 NE NT NT NT 2-Butanone (Methyl ethyl ketone)mg/l 100 NE NT NT NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NT Styrene mg/l 10 NE NT NT NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NT 1,1,2,2-Tetrachloroethane mg/l 5 4 NT NT NT Tetrachloroethene (-ethylene)mg/l 5 3.3 NT NT NT Toluene mg/l 5 0.36 NT NT NT 1,1,1-Trichloroethane mg/l 5 NE NT NT NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NT Trichloroethene (-ethylene)mg/l 5 30 NT NT NT Trichlorofluoromethane mg/l 5 NE NT NT NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NT Vinyl acetate mg/l 50 NE NT NT NT Vinyl chloride mg/l 10 2.4 NT NT NT Total Xylenes mg/l 5 NE NT NT NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (8-14-2000) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (3-19-2001) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 6.3 6.9 7 Specific Conductance mmhos/cm (on-site)1 NE 40 52 110 Temperature °C (on-site)-29 10.8 9.7 9.6 Turbidity NTU (on-site)0.1 50 NT NT NT Total Antimony (Sb)mg/l 30 NE NT NT NT Total Arsenic (As)mg/l 10 10 ND ND ND Total Barium (Ba)mg/l 500 NE 32 32 30 Total Beryllium (Be)mg/l 2 6.5 NT NT ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND Total Chromium (Cr)mg/l 10 50 ND ND ND Total Cobalt (Co)mg/l 10 NE NT NT ND Total Copper (Cu)mg/l 200 7 NT NT NT Total Lead (Pb)mg/l 10 25 ND ND ND Total Mercury (Hg)mg/l 0.2 0.012 ND ND ND Total Nickel (Ni)mg/l 50 88 NT ND ND Total Selenium (Se)mg/l 20 5 ND ND ND Total Silver (Ag)mg/l 10 0.06 ND ND ND Total Thallium (Tl)mg/l 10 NE NT NT NT Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l 50 50 NT NT NT Acetone mg/l 100 NE NT NT NT Acrylonitrile mg/l 200 NE NT NT NT Benzene mg/l 5 51 NT NT NT Bromochloromethane mg/l 5 NE NT NT NT Bromodichloromethane mg/l 5 NE NT NT NT Bromoform mg/l 5 NE NT NT NT Carbon Disulfide mg/l 100 NE NT NT NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NT Carbon tetrachloride mg/l 10 1.6 NT NT NT Chlorobenzene (mono)mg/l 5 NE NT NT NT Chloroethane mg/l 10 NE NT NT NT Chloroform mg/l 5 NE NT NT NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NT Dibromochloromethane mg/l 5 NE NT NT NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE NT NT NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE NT NT NT Dibromomethane mg/l 10 NE NT NT NT 1,2-Dichlorobenzene mg/l 5 NE NT NT NT 1,4-Dichlorobenzene mg/l 5 NE NT NT NT trans-1,4-Dichloro-2butene mg/l 100 NE NT NT NT 1,1-Dichloroethane mg/l 5 NE NT NT NT 1,2-Dichloroethane mg/l 5 NE NT NT NT 1,1-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT trans-1,2-Dichloroethene (-ylene)mg/l 5 NE NT NT NT 1,2-Dichloropropane mg/l 5 NE NT NT NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT Ethylbenzene mg/l 5 NE NT NT NT 2-Hexanone mg/l 50 NE NT NT NT Iodomethane mg/l 10 NE NT NT NT Dichloromethane (Methylene chloride)mg/l 10 NE NT NT NT 2-Butanone (Methyl ethyl ketone)mg/l 100 NE NT NT NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NT Styrene mg/l 10 NE NT NT NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NT 1,1,2,2-Tetrachloroethane mg/l 5 4 NT NT NT Tetrachloroethene (-ethylene)mg/l 5 3.3 NT NT NT Toluene mg/l 5 0.36 NT NT NT 1,1,1-Trichloroethane mg/l 5 NE NT NT NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NT Trichloroethene (-ethylene)mg/l 5 30 NT NT NT Trichlorofluoromethane mg/l 5 NE NT NT NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NT Vinyl acetate mg/l 50 NE NT NT NT Vinyl chloride mg/l 10 2.4 NT NT NT Total Xylenes mg/l 5 NE NT NT NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (3-19-2001) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (8-27-2002) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 6.37 6.84 6.8 Specific Conductance mmhos/cm (on-site)1 NE 55 80 149 Temperature °C (on-site)-29 18.5 20 22.6 Turbidity NTU (on-site)0.1 50 NT NT NT Total Antimony (Sb)mg/l 30 NE NT NT NT Total Arsenic (As)mg/l 10 10 ND ND ND Total Barium (Ba)mg/l 500 NE ND 49 71 Total Beryllium (Be)mg/l 2 6.5 NT NT NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND Total Chromium (Cr)mg/l 10 50 ND ND ND Total Cobalt (Co)mg/l 10 NE NT NT NT Total Copper (Cu)mg/l 200 7 NT NT NT Total Lead (Pb)mg/l 10 25 ND ND ND Total Mercury (Hg)mg/l 0.2 0.012 ND ND ND Total Nickel (Ni)mg/l 50 88 NT NT NT Total Selenium (Se)mg/l 20 5 ND ND ND Total Silver (Ag)mg/l 10 0.06 ND ND ND Total Thallium (Tl)mg/l 10 NE NT NT NT Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l 50 50 NT NT NT Acetone mg/l 100 NE NT NT NT Acrylonitrile mg/l 200 NE NT NT NT Benzene mg/l 5 51 NT NT NT Bromochloromethane mg/l 5 NE NT NT NT Bromodichloromethane mg/l 5 NE NT NT NT Bromoform mg/l 5 NE NT NT NT Carbon Disulfide mg/l 100 NE NT NT NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NT Carbon tetrachloride mg/l 10 1.6 NT NT NT Chlorobenzene (mono)mg/l 5 NE NT NT NT Chloroethane mg/l 10 NE NT NT NT Chloroform mg/l 5 NE NT NT NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NT Dibromochloromethane mg/l 5 NE NT NT NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE NT NT NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE NT NT NT Dibromomethane mg/l 10 NE NT NT NT 1,2-Dichlorobenzene mg/l 5 NE NT NT NT 1,4-Dichlorobenzene mg/l 5 NE NT NT NT trans-1,4-Dichloro-2butene mg/l 100 NE NT NT NT 1,1-Dichloroethane mg/l 5 NE NT NT NT 1,2-Dichloroethane mg/l 5 NE NT NT NT 1,1-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT trans-1,2-Dichloroethene (-ylene)mg/l 5 NE NT NT NT 1,2-Dichloropropane mg/l 5 NE NT NT NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT Ethylbenzene mg/l 5 NE NT NT NT 2-Hexanone mg/l 50 NE NT NT NT Iodomethane mg/l 10 NE NT NT NT Dichloromethane (Methylene chloride)mg/l 10 NE NT NT NT 2-Butanone (Methyl ethyl ketone)mg/l 100 NE NT NT NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NT Styrene mg/l 10 NE NT NT NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NT 1,1,2,2-Tetrachloroethane mg/l 5 4 NT NT NT Tetrachloroethene (-ethylene)mg/l 5 3.3 NT NT NT Toluene mg/l 5 0.36 NT NT NT 1,1,1-Trichloroethane mg/l 5 NE NT NT NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NT Trichloroethene (-ethylene)mg/l 5 30 NT NT NT Trichlorofluoromethane mg/l 5 NE NT NT NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NT Vinyl acetate mg/l 50 NE NT NT NT Vinyl chloride mg/l 10 2.4 NT NT NT Total Xylenes mg/l 5 NE NT NT NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (8-27-2002) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (2-24-2003) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 7.05 6.84 6.8 Specific Conductance mmhos/cm (on-site)1 NE 41 50 110 Temperature °C (on-site)-29 11.6 12.2 13 Turbidity NTU (on-site)0.1 50 NT NT NT Total Antimony (Sb)mg/l 30 NE NT NT NT Total Arsenic (As)mg/l 10 10 ND ND ND Total Barium (Ba)mg/l 500 NE 35 42 45 Total Beryllium (Be)mg/l 2 6.5 NT NT NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND Total Chromium (Cr)mg/l 10 50 ND ND ND Total Cobalt (Co)mg/l 10 NE NT NT NT Total Copper (Cu)mg/l 200 7 NT NT NT Total Lead (Pb)mg/l 10 25 ND ND ND Total Mercury (Hg)mg/l 0.2 0.012 ND ND ND Total Nickel (Ni)mg/l 50 88 NT NT NT Total Selenium (Se)mg/l 20 5 ND ND ND Total Silver (Ag)mg/l 10 0.06 2.9 4.4 4.1 Total Thallium (Tl)mg/l 10 NE NT NT NT Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l 50 50 NT NT NT Acetone mg/l 100 NE NT NT NT Acrylonitrile mg/l 200 NE NT NT NT Benzene mg/l 5 51 NT NT NT Bromochloromethane mg/l 5 NE NT NT NT Bromodichloromethane mg/l 5 NE NT NT NT Bromoform mg/l 5 NE NT NT NT Carbon Disulfide mg/l 100 NE NT NT NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NT Carbon tetrachloride mg/l 10 1.6 NT NT NT Chlorobenzene (mono)mg/l 5 NE NT NT NT Chloroethane mg/l 10 NE NT NT NT Chloroform mg/l 5 NE NT NT NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NT Dibromochloromethane mg/l 5 NE NT NT NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE NT NT NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE NT NT NT Dibromomethane mg/l 10 NE NT NT NT 1,2-Dichlorobenzene mg/l 5 NE NT NT NT 1,4-Dichlorobenzene mg/l 5 NE NT NT NT trans-1,4-Dichloro-2butene mg/l 100 NE NT NT NT 1,1-Dichloroethane mg/l 5 NE NT NT NT 1,2-Dichloroethane mg/l 5 NE NT NT NT 1,1-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT trans-1,2-Dichloroethene (-ylene)mg/l 5 NE NT NT NT 1,2-Dichloropropane mg/l 5 NE NT NT NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT Ethylbenzene mg/l 5 NE NT NT NT 2-Hexanone mg/l 50 NE NT NT NT Iodomethane mg/l 10 NE NT NT NT Dichloromethane (Methylene chloride)mg/l 10 NE NT NT NT 2-Butanone (Methyl ethyl ketone)mg/l 100 NE NT NT NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NT Styrene mg/l 10 NE NT NT NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NT 1,1,2,2-Tetrachloroethane mg/l 5 4 NT NT NT Tetrachloroethene (-ethylene)mg/l 5 3.3 NT NT NT Toluene mg/l 5 0.36 NT NT NT 1,1,1-Trichloroethane mg/l 5 NE NT NT NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NT Trichloroethene (-ethylene)mg/l 5 30 NT NT NT Trichlorofluoromethane mg/l 5 NE NT NT NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NT Vinyl acetate mg/l 50 NE NT NT NT Vinyl chloride mg/l 10 2.4 NT NT NT Total Xylenes mg/l 5 NE NT NT NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (2-24-2003) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (8-11-2003) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 7.24 7.15 7.1 Specific Conductance mmhos/cm (on-site)1 NE 51 75 111 Temperature °C (on-site)-29 19 21.6 23 Turbidity NTU (on-site)0.1 50 NT NT NT Total Antimony (Sb)mg/l 30 NE NT NT NT Total Arsenic (As)mg/l 10 10 ND ND ND Total Barium (Ba)mg/l 500 NE 29 45 28 Total Beryllium (Be)mg/l 2 6.5 NT NT NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND Total Chromium (Cr)mg/l 10 50 ND 2.6 ND Total Cobalt (Co)mg/l 10 NE NT NT NT Total Copper (Cu)mg/l 200 7 NT NT NT Total Lead (Pb)mg/l 10 25 ND ND ND Total Mercury (Hg)mg/l 0.2 0.012 ND ND ND Total Nickel (Ni)mg/l 50 88 NT NT NT Total Selenium (Se)mg/l 20 5 ND ND ND Total Silver (Ag)mg/l 10 0.06 ND ND ND Total Thallium (Tl)mg/l 10 NE NT NT NT Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l 50 50 NT NT NT Acetone mg/l 100 NE ND ND ND Acrylonitrile mg/l 200 NE ND ND ND Benzene mg/l 5 51 ND ND ND Bromochloromethane mg/l 5 NE ND ND ND Bromodichloromethane mg/l 5 NE ND ND ND Bromoform mg/l 5 NE ND ND ND Carbon Disulfide mg/l 100 NE ND ND ND Bromomethane (Methylbromide)mg/l 10 NE ND ND ND Carbon tetrachloride mg/l 10 1.6 ND ND ND Chlorobenzene (mono)mg/l 5 NE ND ND ND Chloroethane mg/l 10 NE ND ND ND Chloroform mg/l 5 NE ND ND ND Chloromethane (Methylchloride)mg/l 10 NE ND ND ND Dibromochloromethane mg/l 5 NE ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE ND ND ND Dibromomethane mg/l 10 NE ND ND ND 1,2-Dichlorobenzene mg/l 5 NE ND ND ND 1,4-Dichlorobenzene mg/l 5 NE ND ND ND trans-1,4-Dichloro-2butene mg/l 100 NE ND ND ND 1,1-Dichloroethane mg/l 5 NE ND ND ND 1,2-Dichloroethane mg/l 5 NE ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 5 NE ND ND ND 1,2-Dichloropropane mg/l 5 NE ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND Ethylbenzene mg/l 5 NE ND ND ND 2-Hexanone mg/l 50 NE ND ND ND Iodomethane mg/l 10 NE ND ND ND Dichloromethane (Methylene chloride)mg/l 10 NE ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 100 NE ND ND ND 4-Methyl-2-Pentanone mg/l 100 NE ND ND ND Styrene mg/l 10 NE ND ND ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND 1,1,2,2-Tetrachloroethane mg/l 5 4 ND ND ND Tetrachloroethene (-ethylene)mg/l 5 3.3 ND ND ND Toluene mg/l 5 0.36 ND ND ND 1,1,1-Trichloroethane mg/l 5 NE ND ND ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND Trichloroethene (-ethylene)mg/l 5 30 ND ND ND Trichlorofluoromethane mg/l 5 NE ND ND ND 1,2,3-Trichloropropane mg/l 15 NE ND ND ND Vinyl acetate mg/l 50 NE ND ND ND Vinyl chloride mg/l 10 2.4 ND ND ND Total Xylenes mg/l 5 NE ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (8-11-2003) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (2-9-2004) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 6.22 6.71 6.38 Specific Conductance mmhos/cm (on-site)1 NE 39 42 80 Temperature °C (on-site)-29 7.8 7.8 8.1 Turbidity NTU (on-site)0.1 50 NT NT NT Total Antimony (Sb)mg/l 30 NE NT NT NT Total Arsenic (As)mg/l 10 10 ND ND ND Total Barium (Ba)mg/l 500 NE 30 37 34 Total Beryllium (Be)mg/l 2 6.5 NT NT NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND Total Chromium (Cr)mg/l 10 50 ND ND ND Total Cobalt (Co)mg/l 10 NE NT NT NT Total Copper (Cu)mg/l 200 7 NT NT NT Total Lead (Pb)mg/l 10 25 ND ND ND Total Mercury (Hg)mg/l 0.2 0.012 ND ND ND Total Nickel (Ni)mg/l 50 88 NT NT NT Total Selenium (Se)mg/l 20 5 ND ND ND Total Silver (Ag)mg/l 10 0.06 ND ND ND Total Thallium (Tl)mg/l 10 NE NT NT NT Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l 50 50 NT NT NT Acetone mg/l 100 NE ND ND 14 Acrylonitrile mg/l 200 NE ND ND ND Benzene mg/l 5 51 ND ND ND Bromochloromethane mg/l 5 NE ND ND ND Bromodichloromethane mg/l 5 NE ND ND ND Bromoform mg/l 5 NE ND ND ND Carbon Disulfide mg/l 100 NE ND ND ND Bromomethane (Methylbromide)mg/l 10 NE ND ND ND Carbon tetrachloride mg/l 10 1.6 ND ND ND Chlorobenzene (mono)mg/l 5 NE ND ND ND Chloroethane mg/l 10 NE ND ND ND Chloroform mg/l 5 NE ND ND ND Chloromethane (Methylchloride)mg/l 10 NE ND ND ND Dibromochloromethane mg/l 5 NE ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE ND ND ND Dibromomethane mg/l 10 NE ND ND ND 1,2-Dichlorobenzene mg/l 5 NE ND ND ND 1,4-Dichlorobenzene mg/l 5 NE ND ND ND trans-1,4-Dichloro-2butene mg/l 100 NE ND ND ND 1,1-Dichloroethane mg/l 5 NE ND ND ND 1,2-Dichloroethane mg/l 5 NE ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 5 NE ND ND ND 1,2-Dichloropropane mg/l 5 NE ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND Ethylbenzene mg/l 5 NE ND ND ND 2-Hexanone mg/l 50 NE ND ND ND Iodomethane mg/l 10 NE ND ND ND Dichloromethane (Methylene chloride)mg/l 10 NE ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 100 NE ND ND ND 4-Methyl-2-Pentanone mg/l 100 NE ND ND ND Styrene mg/l 10 NE ND ND ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND 1,1,2,2-Tetrachloroethane mg/l 5 4 ND ND ND Tetrachloroethene (-ethylene)mg/l 5 3.3 ND ND ND Toluene mg/l 5 0.36 ND ND ND 1,1,1-Trichloroethane mg/l 5 NE ND ND ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND Trichloroethene (-ethylene)mg/l 5 30 ND ND ND Trichlorofluoromethane mg/l 5 NE ND ND ND 1,2,3-Trichloropropane mg/l 15 NE ND ND ND Vinyl acetate mg/l 50 NE ND ND ND Vinyl chloride mg/l 10 2.4 ND ND ND Total Xylenes mg/l 5 NE ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (2-9-2004) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (8-16-2004) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 6.98 7.11 6.8 Specific Conductance mmhos/cm (on-site)1 NE 59 80 125 Temperature °C (on-site)-29 19.4 22.3 24.8 Turbidity NTU (on-site)0.1 50 NT NT NT Total Antimony (Sb)mg/l 30 NE NT NT NT Total Arsenic (As)mg/l 10 10 ND ND ND Total Barium (Ba)mg/l 500 NE 34 40 43 Total Beryllium (Be)mg/l 2 6.5 NT NT NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND Total Chromium (Cr)mg/l 10 50 ND ND ND Total Cobalt (Co)mg/l 10 NE NT NT NT Total Copper (Cu)mg/l 200 7 NT NT NT Total Lead (Pb)mg/l 10 25 ND ND ND Total Mercury (Hg)mg/l 0.2 0.012 0.25 0.67 0.29 Total Nickel (Ni)mg/l 50 88 NT NT NT Total Selenium (Se)mg/l 20 5 ND ND ND Total Silver (Ag)mg/l 10 0.06 ND ND ND Total Thallium (Tl)mg/l 10 NE NT NT NT Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l 50 50 NT NT NT Acetone mg/l 100 NE ND ND ND Acrylonitrile mg/l 200 NE ND ND ND Benzene mg/l 5 51 ND ND ND Bromochloromethane mg/l 5 NE ND ND ND Bromodichloromethane mg/l 5 NE ND ND ND Bromoform mg/l 5 NE ND ND ND Carbon Disulfide mg/l 100 NE ND ND ND Bromomethane (Methylbromide)mg/l 10 NE ND ND ND Carbon tetrachloride mg/l 10 1.6 ND ND ND Chlorobenzene (mono)mg/l 5 NE ND ND ND Chloroethane mg/l 10 NE ND ND ND Chloroform mg/l 5 NE ND ND ND Chloromethane (Methylchloride)mg/l 10 NE ND ND ND Dibromochloromethane mg/l 5 NE ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE ND ND ND Dibromomethane mg/l 10 NE ND ND ND 1,2-Dichlorobenzene mg/l 5 NE ND ND ND 1,4-Dichlorobenzene mg/l 5 NE ND ND ND trans-1,4-Dichloro-2butene mg/l 100 NE ND ND ND 1,1-Dichloroethane mg/l 5 NE ND ND ND 1,2-Dichloroethane mg/l 5 NE ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 5 NE ND ND ND 1,2-Dichloropropane mg/l 5 NE ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND Ethylbenzene mg/l 5 NE ND ND ND 2-Hexanone mg/l 50 NE ND ND ND Iodomethane mg/l 10 NE ND ND ND Dichloromethane (Methylene chloride)mg/l 10 NE ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 100 NE ND ND ND 4-Methyl-2-Pentanone mg/l 100 NE ND ND ND Styrene mg/l 10 NE ND ND ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND 1,1,2,2-Tetrachloroethane mg/l 5 4 ND ND ND Tetrachloroethene (-ethylene)mg/l 5 3.3 ND ND ND Toluene mg/l 5 0.36 ND ND ND 1,1,1-Trichloroethane mg/l 5 NE ND ND ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND Trichloroethene (-ethylene)mg/l 5 30 ND ND ND Trichlorofluoromethane mg/l 5 NE ND ND ND 1,2,3-Trichloropropane mg/l 15 NE ND ND ND Vinyl acetate mg/l 50 NE ND ND ND Vinyl chloride mg/l 10 2.4 ND ND ND Total Xylenes mg/l 5 NE ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (8-16-2004) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (2-14-2005) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 8.06 7.32 7.97 Specific Conductance mmhos/cm (on-site)1 NE 38 120 45 Temperature °C (on-site)-29 8.2 10.7 9.3 Turbidity NTU (on-site)0.1 50 NT NT NT Total Antimony (Sb)mg/l 30 NE NT NT NT Total Arsenic (As)mg/l 10 10 ND ND ND Total Barium (Ba)mg/l 500 NE 35 52 52 Total Beryllium (Be)mg/l 2 6.5 NT NT NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND Total Chromium (Cr)mg/l 10 50 ND 5.6 3.7 Total Cobalt (Co)mg/l 10 NE NT NT NT Total Copper (Cu)mg/l 200 7 NT NT NT Total Lead (Pb)mg/l 10 25 ND ND ND Total Mercury (Hg)mg/l 0.2 0.012 ND ND ND Total Nickel (Ni)mg/l 50 88 NT NT NT Total Selenium (Se)mg/l 20 5 8.6 ND 5.5 Total Silver (Ag)mg/l 10 0.06 ND ND ND Total Thallium (Tl)mg/l 10 NE NT NT NT Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l 50 50 NT NT NT Acetone mg/l 100 NE ND ND ND Acrylonitrile mg/l 200 NE ND ND ND Benzene mg/l 5 51 ND ND ND Bromochloromethane mg/l 5 NE ND ND ND Bromodichloromethane mg/l 5 NE ND ND ND Bromoform mg/l 5 NE ND ND ND Carbon Disulfide mg/l 100 NE ND ND ND Bromomethane (Methylbromide)mg/l 10 NE ND ND ND Carbon tetrachloride mg/l 10 1.6 ND ND ND Chlorobenzene (mono)mg/l 5 NE ND ND ND Chloroethane mg/l 10 NE ND ND ND Chloroform mg/l 5 NE ND ND ND Chloromethane (Methylchloride)mg/l 10 NE ND ND ND Dibromochloromethane mg/l 5 NE ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE ND ND ND Dibromomethane mg/l 10 NE ND ND ND 1,2-Dichlorobenzene mg/l 5 NE ND ND ND 1,4-Dichlorobenzene mg/l 5 NE ND ND ND trans-1,4-Dichloro-2butene mg/l 100 NE ND ND ND 1,1-Dichloroethane mg/l 5 NE ND ND ND 1,2-Dichloroethane mg/l 5 NE ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 5 NE ND ND ND 1,2-Dichloropropane mg/l 5 NE ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND Ethylbenzene mg/l 5 NE ND ND ND 2-Hexanone mg/l 50 NE ND ND ND Iodomethane mg/l 10 NE ND ND ND Dichloromethane (Methylene chloride)mg/l 10 NE ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 100 NE ND ND ND 4-Methyl-2-Pentanone mg/l 100 NE ND ND ND Styrene mg/l 10 NE ND ND ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND 1,1,2,2-Tetrachloroethane mg/l 5 4 ND ND ND Tetrachloroethene (-ethylene)mg/l 5 3.3 ND ND ND Toluene mg/l 5 0.36 ND ND ND 1,1,1-Trichloroethane mg/l 5 NE ND ND ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND Trichloroethene (-ethylene)mg/l 5 30 ND ND ND Trichlorofluoromethane mg/l 5 NE ND ND ND 1,2,3-Trichloropropane mg/l 15 NE ND ND ND Vinyl acetate mg/l 50 NE ND ND ND Vinyl chloride mg/l 10 2.4 ND ND ND Total Xylenes mg/l 5 NE ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (2-14-2005) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (9-1-2005) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 7.21 7.13 7.5 Specific Conductance mmhos/cm (on-site)1 NE 61 78 120 Temperature °C (on-site)-29 19.8 22.6 24.1 Turbidity NTU (on-site)0.1 50 NT NT NT Total Antimony (Sb)mg/l 30 NE NT NT NT Total Arsenic (As)mg/l 10 10 ND ND ND Total Barium (Ba)mg/l 500 NE 41 48 41 Total Beryllium (Be)mg/l 2 6.5 NT NT NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND Total Chromium (Cr)mg/l 10 50 ND ND ND Total Cobalt (Co)mg/l 10 NE NT NT NT Total Copper (Cu)mg/l 200 7 NT NT NT Total Lead (Pb)mg/l 10 25 ND ND ND Total Mercury (Hg)mg/l 0.2 0.012 ND ND ND Total Nickel (Ni)mg/l 50 88 NT NT NT Total Selenium (Se)mg/l 20 5 ND ND ND Total Silver (Ag)mg/l 10 0.06 ND ND ND Total Thallium (Tl)mg/l 10 NE NT NT NT Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l 50 50 NT NT NT Acetone mg/l 100 NE ND ND ND Acrylonitrile mg/l 200 NE ND ND ND Benzene mg/l 5 51 ND ND ND Bromochloromethane mg/l 5 NE ND ND ND Bromodichloromethane mg/l 5 NE ND ND ND Bromoform mg/l 5 NE ND ND ND Carbon Disulfide mg/l 100 NE ND ND ND Bromomethane (Methylbromide)mg/l 10 NE ND ND ND Carbon tetrachloride mg/l 10 1.6 ND ND ND Chlorobenzene (mono)mg/l 5 NE ND ND ND Chloroethane mg/l 10 NE ND ND ND Chloroform mg/l 5 NE ND ND ND Chloromethane (Methylchloride)mg/l 10 NE ND ND ND Dibromochloromethane mg/l 5 NE ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE ND ND ND Dibromomethane mg/l 10 NE ND ND ND 1,2-Dichlorobenzene mg/l 5 NE ND ND ND 1,4-Dichlorobenzene mg/l 5 NE ND ND ND trans-1,4-Dichloro-2butene mg/l 100 NE ND ND ND 1,1-Dichloroethane mg/l 5 NE ND ND ND 1,2-Dichloroethane mg/l 5 NE ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 5 NE ND ND ND 1,2-Dichloropropane mg/l 5 NE ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND Ethylbenzene mg/l 5 NE ND ND ND 2-Hexanone mg/l 50 NE ND ND ND Iodomethane mg/l 10 NE ND ND ND Dichloromethane (Methylene chloride)mg/l 10 NE ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 100 NE ND ND ND 4-Methyl-2-Pentanone mg/l 100 NE ND ND ND Styrene mg/l 10 NE ND ND ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND 1,1,2,2-Tetrachloroethane mg/l 5 4 ND ND ND Tetrachloroethene (-ethylene)mg/l 5 3.3 ND ND ND Toluene mg/l 5 0.36 ND ND ND 1,1,1-Trichloroethane mg/l 5 NE ND ND ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND Trichloroethene (-ethylene)mg/l 5 30 ND ND ND Trichlorofluoromethane mg/l 5 NE ND ND ND 1,2,3-Trichloropropane mg/l 15 NE ND ND ND Vinyl acetate mg/l 50 NE ND ND ND Vinyl chloride mg/l 10 2.4 ND ND ND Total Xylenes mg/l 5 NE ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (9-1-2005) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (2-16-2006) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 NT NT NT Specific Conductance mmhos/cm (on-site)1 NE NT NT NT Temperature °C (on-site)-29 NT NT NT Turbidity NTU (on-site)0.1 50 NT NT NT Total Antimony (Sb)mg/l 30 NE NT NT NT Total Arsenic (As)mg/l 10 10 ND ND ND Total Barium (Ba)mg/l 500 NE ND ND ND Total Beryllium (Be)mg/l 2 6.5 NT NT NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND Total Chromium (Cr)mg/l 10 50 ND ND ND Total Cobalt (Co)mg/l 10 NE NT NT NT Total Copper (Cu)mg/l 200 7 NT NT NT Total Lead (Pb)mg/l 10 25 ND ND ND Total Mercury (Hg)mg/l 0.2 0.012 ND ND ND Total Nickel (Ni)mg/l 50 88 NT NT NT Total Selenium (Se)mg/l 20 5 ND ND ND Total Silver (Ag)mg/l 10 0.06 ND ND ND Total Thallium (Tl)mg/l 10 NE NT NT NT Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l 50 50 NT NT NT Acetone mg/l 100 NE ND ND ND Acrylonitrile mg/l 200 NE ND ND ND Benzene mg/l 5 51 ND ND ND Bromochloromethane mg/l 5 NE ND ND ND Bromodichloromethane mg/l 5 NE ND ND ND Bromoform mg/l 5 NE ND ND ND Carbon Disulfide mg/l 100 NE ND ND ND Bromomethane (Methylbromide)mg/l 10 NE ND ND ND Carbon tetrachloride mg/l 10 1.6 ND ND ND Chlorobenzene (mono)mg/l 5 NE ND ND ND Chloroethane mg/l 10 NE ND ND ND Chloroform mg/l 5 NE ND ND ND Chloromethane (Methylchloride)mg/l 10 NE ND ND ND Dibromochloromethane mg/l 5 NE ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE ND ND ND Dibromomethane mg/l 10 NE ND ND ND 1,2-Dichlorobenzene mg/l 5 NE ND ND ND 1,4-Dichlorobenzene mg/l 5 NE ND ND ND trans-1,4-Dichloro-2butene mg/l 100 NE ND ND ND 1,1-Dichloroethane mg/l 5 NE ND ND ND 1,2-Dichloroethane mg/l 5 NE ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 5 NE ND ND ND 1,2-Dichloropropane mg/l 5 NE ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND Ethylbenzene mg/l 5 NE ND ND ND 2-Hexanone mg/l 50 NE ND ND ND Iodomethane mg/l 10 NE ND ND ND Dichloromethane (Methylene chloride)mg/l 10 NE ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 100 NE ND ND ND 4-Methyl-2-Pentanone mg/l 100 NE ND ND ND Styrene mg/l 10 NE ND ND ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND 1,1,2,2-Tetrachloroethane mg/l 5 4 ND ND ND Tetrachloroethene (-ethylene)mg/l 5 3.3 ND ND ND Toluene mg/l 5 0.36 ND ND ND 1,1,1-Trichloroethane mg/l 5 NE ND ND ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND Trichloroethene (-ethylene)mg/l 5 30 ND ND ND Trichlorofluoromethane mg/l 5 NE ND ND ND 1,2,3-Trichloropropane mg/l 15 NE ND ND ND Vinyl acetate mg/l 50 NE ND ND ND Vinyl chloride mg/l 10 2.4 ND ND ND Total Xylenes mg/l 5 NE ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (2-16-2006) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (8-30-2006) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 7.12 7.33 7.05 Specific Conductance mmhos/cm (on-site)1 NE 75 96 134 Temperature °C (on-site)-29 21.3 26.2 27.6 Turbidity NTU (on-site)0.1 50 NT NT NT Total Antimony (Sb)mg/l 30 NE NT NT NT Total Arsenic (As)mg/l 10 10 ND ND ND Total Barium (Ba)mg/l 500 NE 33 37 48 Total Beryllium (Be)mg/l 2 6.5 NT NT NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND Total Chromium (Cr)mg/l 10 50 ND ND ND Total Cobalt (Co)mg/l 10 NE NT NT NT Total Copper (Cu)mg/l 200 7 NT NT NT Total Lead (Pb)mg/l 10 25 ND ND ND Total Mercury (Hg)mg/l 0.2 0.012 ND ND ND Total Nickel (Ni)mg/l 50 88 NT NT NT Total Selenium (Se)mg/l 20 5 ND ND ND Total Silver (Ag)mg/l 10 0.06 ND ND ND Total Thallium (Tl)mg/l 10 NE NT NT NT Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l 50 50 NT NT NT Acetone mg/l 100 NE ND ND ND Acrylonitrile mg/l 200 NE ND ND ND Benzene mg/l 5 51 ND ND ND Bromochloromethane mg/l 5 NE ND ND ND Bromodichloromethane mg/l 5 NE ND ND ND Bromoform mg/l 5 NE ND ND ND Carbon Disulfide mg/l 100 NE ND ND ND Bromomethane (Methylbromide)mg/l 10 NE ND ND ND Carbon tetrachloride mg/l 10 1.6 ND ND ND Chlorobenzene (mono)mg/l 5 NE ND ND ND Chloroethane mg/l 10 NE ND ND ND Chloroform mg/l 5 NE ND ND ND Chloromethane (Methylchloride)mg/l 10 NE ND ND ND Dibromochloromethane mg/l 5 NE ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE ND ND ND Dibromomethane mg/l 10 NE ND ND ND 1,2-Dichlorobenzene mg/l 5 NE ND ND ND 1,4-Dichlorobenzene mg/l 5 NE ND ND ND trans-1,4-Dichloro-2butene mg/l 100 NE ND ND ND 1,1-Dichloroethane mg/l 5 NE ND ND ND 1,2-Dichloroethane mg/l 5 NE ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 5 NE ND ND ND 1,2-Dichloropropane mg/l 5 NE ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND Ethylbenzene mg/l 5 NE ND ND ND 2-Hexanone mg/l 50 NE ND ND ND Iodomethane mg/l 10 NE ND ND ND Dichloromethane (Methylene chloride)mg/l 10 NE ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 100 NE ND ND ND 4-Methyl-2-Pentanone mg/l 100 NE ND ND ND Styrene mg/l 10 NE ND ND ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND 1,1,2,2-Tetrachloroethane mg/l 5 4 ND ND ND Tetrachloroethene (-ethylene)mg/l 5 3.3 ND ND ND Toluene mg/l 5 0.36 ND ND ND 1,1,1-Trichloroethane mg/l 5 NE ND ND ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND Trichloroethene (-ethylene)mg/l 5 30 ND ND ND Trichlorofluoromethane mg/l 5 NE ND ND ND 1,2,3-Trichloropropane mg/l 15 NE ND ND ND Vinyl acetate mg/l 50 NE ND ND ND Vinyl chloride mg/l 10 2.4 ND ND ND Total Xylenes mg/l 5 NE ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (8-30-2006) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (2-26-2007) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 7.18 7.36 7.36 Specific Conductance mmhos/cm (on-site)1 NE 62 206 91 Temperature °C (on-site)-29 12.3 12.3 12.6 Turbidity NTU (on-site)0.1 50 NT NT NT Total Antimony (Sb)mg/l 30 NE NT NT NT Total Arsenic (As)mg/l 5 10 ND ND ND Total Barium (Ba)mg/l 5 NE 34 36 36 Total Beryllium (Be)mg/l 2 6.5 NT NT NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND Total Cobalt (Co)mg/l 10 NE NT NT NT Total Copper (Cu)mg/l 200 7 NT NT NT Total Lead (Pb)mg/l 5 25 ND ND ND Total Mercury (Hg)mg/l 0.2 0.012 ND ND ND Total Nickel (Ni)mg/l 50 88 NT NT NT Total Selenium (Se)mg/l 10 5 ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND Total Thallium (Tl)mg/l 10 NE NT NT NT Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l 50 50 NT NT NT Acetone mg/l 25 NE ND ND ND Acrylonitrile mg/l 25 NE ND ND ND Benzene mg/l 5 51 ND ND ND Bromochloromethane mg/l 5 NE ND ND ND Bromodichloromethane mg/l 5 NE ND ND ND Bromoform mg/l 5 NE ND ND ND Carbon Disulfide mg/l 10 NE ND ND ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND Carbon tetrachloride mg/l 5 1.6 ND ND ND Chlorobenzene (mono)mg/l 5 NE ND ND ND Chloroethane mg/l 10 NE ND ND ND Chloroform mg/l 5 NE ND ND ND Chloromethane (Methylchloride)mg/l 5 NE ND ND ND Dibromochloromethane mg/l 5 NE ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 NE ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE ND ND ND Dibromomethane mg/l 5 NE ND ND ND 1,2-Dichlorobenzene mg/l 5 NE ND ND ND 1,4-Dichlorobenzene mg/l 5 NE ND ND ND trans-1,4-Dichloro-2butene mg/l 5 NE ND ND ND 1,1-Dichloroethane mg/l 5 NE ND ND ND 1,2-Dichloroethane mg/l 5 NE ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 5 NE ND ND ND 1,2-Dichloropropane mg/l 5 NE ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 5 NE ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 5 NE ND ND ND Ethylbenzene mg/l 5 NE ND ND ND 2-Hexanone mg/l 10 NE ND ND ND Iodomethane mg/l 10 NE ND ND ND Dichloromethane (Methylene chloride)mg/l 5 NE ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 10 NE ND ND ND 4-Methyl-2-Pentanone mg/l 10 NE ND ND ND Styrene mg/l 5 NE ND ND ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND 1,1,2,2-Tetrachloroethane mg/l 5 4 ND ND ND Tetrachloroethene (-ethylene)mg/l 5 3.3 ND ND ND Toluene mg/l 5 0.36 ND ND ND 1,1,1-Trichloroethane mg/l 5 NE ND ND ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND Trichloroethene (-ethylene)mg/l 5 30 ND ND ND Trichlorofluoromethane mg/l 10 NE ND ND ND 1,2,3-Trichloropropane mg/l 5 NE ND ND ND Vinyl acetate mg/l 10 NE ND ND ND Vinyl chloride mg/l 5 2.4 ND ND ND Total Xylenes mg/l 10 NE ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (2-26-2007) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (8-13-2007) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 7.38 7.2 7.2 Specific Conductance mmhos/cm (on-site)10 NE 63.6 84.2 83 Temperature °C (on-site)-29 21 25.4 26.1 Turbidity NTU (on-site)0.1 50 NT NT NT Total Antimony (Sb)mg/l NT NE NT NT NT Total Arsenic (As)mg/l 5 10 ND ND ND Total Barium (Ba)mg/l 5 NE 31.6 34.7 34.3 Total Beryllium (Be)mg/l NT 6.5 NT NT NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND Total Cobalt (Co)mg/l NT NE NT NT NT Total Copper (Cu)mg/l NT 7 NT NT NT Total Lead (Pb)mg/l 5 25 ND ND ND Total Mercury (Hg)mg/l 0.2 0.012 ND ND ND Total Nickel (Ni)mg/l NT 88 NT NT NT Total Selenium (Se)mg/l 10 5 ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND Total Thallium (Tl)mg/l NT NE NT NT NT Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l NT 50 NT NT NT Acetone mg/l 25 NE ND ND ND Acrylonitrile mg/l 10 NE ND ND ND Benzene mg/l 1 51 ND ND ND Bromochloromethane mg/l 1 NE ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND Bromoform mg/l 1 NE ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND Chloroethane mg/l 1 NE ND ND ND Chloroform mg/l 1 NE ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 NE ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND Dibromomethane mg/l 1 NE ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND trans-1,4-Dichloro-2butene mg/l 1 NE ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 NE ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND Ethylbenzene mg/l 1 NE ND ND ND 2-Hexanone mg/l 5 NE ND ND ND Iodomethane mg/l 5 NE ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND Styrene mg/l 1 NE ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND Toluene mg/l 1 0.36 ND ND ND 1,1,1-Trichloroethane mg/l 1 NE ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND Vinyl acetate mg/l 2 NE ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND Total Xylenes mg/l 2 NE ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (8-13-2007) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event 2-11-2008 TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 7.08 6.95 6.86 Specific Conductance mmhos/cm (on-site)10 NE 66 92 81 Temperature °C (on-site)-29 9.1 11.1 10.2 Turbidity NTU (on-site)0.1 50 NT NT NT Total Antimony (Sb)mg/l NT NE NT NT NT Total Arsenic (As)mg/l 5 10 ND ND ND Total Barium (Ba)mg/l 5 NE 33.9 45.4 40.5 Total Beryllium (Be)mg/l NT 6.5 ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND Total Cobalt (Co)mg/l NT NE NT NT NT Total Copper (Cu)mg/l NT 7 NT NT NT Total Lead (Pb)mg/l 5 25 ND ND ND Total Mercury (Hg)mg/l 0.2 0.012 ND ND ND Total Nickel (Ni)mg/l NT 88 NT NT NT Total Selenium (Se)mg/l 10 5 ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND Total Thallium (Tl)mg/l NT NE NT NT NT Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l NT 50 NT NT NT Acetone mg/l 25 NE ND ND ND Acrylonitrile mg/l 10 NE ND ND ND Benzene mg/l 1 51 ND ND ND Bromochloromethane mg/l 1 NE ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND Bromoform mg/l 1 NE ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND Chloroethane mg/l 1 NE ND ND ND Chloroform mg/l 1 NE ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 NE ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND Dibromomethane mg/l 1 NE ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND trans-1,4-Dichloro-2butene mg/l 1 NE ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 NE ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND Ethylbenzene mg/l 1 NE ND ND ND 2-Hexanone mg/l 5 NE ND ND ND Iodomethane mg/l 5 NE ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND Styrene mg/l 1 NE ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND Toluene mg/l 1 0.36 ND ND ND 1,1,1-Trichloroethane mg/l 1 NE ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND Vinyl acetate mg/l 2 NE ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND Total Xylenes mg/l 2 NE ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx 2-11-2008 Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event 8-25-2008 TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 7.24 6.88 6.7 Specific Conductance mmhos/cm (on-site)10 NE 74 135 97 Temperature °C (on-site)-29 20.3 22.7 20.7 Turbidity NTU (on-site)NT 50 NT NT NT Total Antimony (Sb)mg/l NT NE NT NT NT Total Arsenic (As)mg/l 5 10 ND ND ND Total Barium (Ba)mg/l 5 NE 38.8 59.0 36.0 Total Beryllium (Be)mg/l NT 6.5 NT NT NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND Total Cobalt (Co)mg/l NT NE NT NT NT Total Copper (Cu)mg/l NT 7 NT NT NT Total Lead (Pb)mg/l 5 25 ND ND ND Total Mercury (Hg)mg/l 0.2 0.012 ND ND ND Total Nickel (Ni)mg/l NT 88 NT NT NT Total Selenium (Se)mg/l 10 5 ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND Total Thallium (Tl)mg/l NT NE NT NT NT Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l NT 50 NT NT NT Acetone mg/l 25 NE ND ND ND Acrylonitrile mg/l 10 NE ND ND ND Benzene mg/l 1 51 ND ND ND Bromochloromethane mg/l 1 NE ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND Bromoform mg/l 1 NE ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND Chloroethane mg/l 1 NE ND ND ND Chloroform mg/l 1 NE ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 NE ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND Dibromomethane mg/l 1 NE ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND trans-1,4-Dichloro-2butene mg/l 1 NE ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 NE ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND Ethylbenzene mg/l 1 NE ND ND ND 2-Hexanone mg/l 5 NE ND ND ND Iodomethane mg/l 5 NE ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND Styrene mg/l 1 NE ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND Toluene mg/l 1 0.36 ND ND ND 1,1,1-Trichloroethane mg/l 1 NE ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND Vinyl acetate mg/l 2 NE ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND Total Xylenes mg/l 3 NE ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx 8-25-2008 Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (2-23-2009) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 6.56 6.62 6.54 Specific Conductance mmhos/cm (on-site)-NE 66 96 87 Temperature °C (on-site)-29 6.0 9.1 7.1 Turbidity NTU (on-site)NT 50 NT NT NT Total Antimony (Sb)mg/l NT NE NT NT NT Total Arsenic (As)mg/l 5.0 10 ND ND ND Total Barium (Ba)mg/l 5.0 NE 35.5 47.6 40.3 Total Beryllium (Be)mg/l NT 6.5 NT NT NT Total Cadmium (Cd)mg/l 1.0 0.4 ND ND ND Total Chromium (Cr)mg/l 5.0 50 ND ND ND Total Cobalt (Co)mg/l NT NE NT NT NT Total Copper (Cu)mg/l NT 7 NT NT NT Total Lead (Pb)mg/l 5.0 25 ND ND ND Total Mercury (Hg)mg/l 0.20 0.012 ND ND ND Total Nickel (Ni)mg/l NT 88 NT NT NT Total Selenium (Se)mg/l 10 5 ND ND ND Total Silver (Ag)mg/l 5.0 0.06 ND ND ND Total Thallium (Tl)mg/l NT NE NT NT NT Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l NT 50 NT NT NT Acetone mg/l 25 NE ND ND ND Acrylonitrile mg/l 10.0 NE ND ND ND Benzene mg/l 1.0 51 ND ND ND Bromochloromethane mg/l 1.0 NE ND ND ND Bromodichloromethane mg/l 1.0 NE ND ND ND Bromoform mg/l 1.0 NE ND ND ND Carbon Disulfide mg/l 2.0 NE ND ND ND Bromomethane (Methylbromide)mg/l 5.0 NE ND ND ND Carbon tetrachloride mg/l 1.0 1.6 ND ND ND Chlorobenzene (mono)mg/l 1.0 NE ND ND ND Chloroethane mg/l 1.0 NE ND ND ND Chloroform mg/l 1.0 NE ND ND ND Chloromethane (Methylchloride)mg/l 1.0 NE ND ND ND Dibromochloromethane mg/l 1.0 NE ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3.0 NE ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 NE ND ND ND Dibromomethane mg/l 1.0 NE ND ND ND 1,2-Dichlorobenzene mg/l 1.0 NE ND ND ND 1,4-Dichlorobenzene mg/l 1.0 NE ND ND ND trans-1,4-Dichloro-2butene mg/l 1.0 NE ND ND ND 1,1-Dichloroethane mg/l 1.0 NE ND ND ND 1,2-Dichloroethane mg/l 1.0 NE ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 NE ND ND ND 1,2-Dichloropropane mg/l 1.0 NE ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND Ethylbenzene mg/l 1.0 NE ND ND ND 2-Hexanone mg/l 5.0 NE ND ND ND Iodomethane mg/l 5.0 NE ND ND ND Dichloromethane (Methylene chloride)mg/l 2.0 NE ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 NE ND ND ND 4-Methyl-2-Pentanone mg/l 5.0 NE ND ND ND Styrene mg/l 1.0 NE ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NE ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1.0 4 ND ND ND Tetrachloroethene (-ethylene)mg/l 1.0 3.3 ND ND ND Toluene mg/l 1.0 0.36 ND ND ND 1,1,1-Trichloroethane mg/l 1.0 NE ND ND ND 1,1,2-Trichloroethane mg/l 1.0 NE ND ND ND Trichloroethene (-ethylene)mg/l 1.0 30 ND ND ND Trichlorofluoromethane mg/l 1.0 NE ND ND ND 1,2,3-Trichloropropane mg/l 1.0 NE ND ND ND Vinyl acetate mg/l 2.0 NE ND ND ND Vinyl chloride mg/l 1.0 2.4 ND ND ND Total Xylenes mg/l 2.0 NE ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (2-23-2009) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (8-24-2009) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 6.6 6.35 6.52 Specific Conductance mmhos/cm (on-site)-NE 72 108 96 Temperature °C (on-site)-29 19.2 22.1 6.52 Turbidity NTU (on-site)NT 50 NT NT NT Total Antimony (Sb)mg/l NT NE NT NT NT Total Arsenic (As)mg/l 5.0 10 ND ND ND Total Barium (Ba)mg/l 5.0 NE 41.7 41.5 36.8 Total Beryllium (Be)mg/l NT 6.5 NT NT NT Total Cadmium (Cd)mg/l 1.0 0.4 ND ND ND Total Chromium (Cr)mg/l 5.0 50 ND ND ND Total Cobalt (Co)mg/l NT NE NT NT NT Total Copper (Cu)mg/l NT 7 NT NT NT Total Lead (Pb)mg/l 5.0 25 ND ND ND Total Mercury (Hg)mg/l 0.20 0.012 ND ND ND Total Nickel (Ni)mg/l NT 88 NT NT NT Total Selenium (Se)mg/l 10 5 ND ND ND Total Silver (Ag)mg/l 5.0 0.06 ND ND ND Total Thallium (Tl)mg/l NT NE NT NT NT Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l NT 50 NT NT NT Acetone mg/l 25 NE ND ND ND Acrylonitrile mg/l 10.0 NE ND ND ND Benzene mg/l 1.0 51 ND ND ND Bromochloromethane mg/l 1.0 NE ND ND ND Bromodichloromethane mg/l 1.0 NE ND ND ND Bromoform mg/l 1.0 NE ND ND ND Carbon Disulfide mg/l 2.0 NE ND ND ND Bromomethane (Methylbromide)mg/l 5.0 NE ND ND ND Carbon tetrachloride mg/l 1.0 1.6 ND ND ND Chlorobenzene (mono)mg/l 1.0 NE ND ND ND Chloroethane mg/l 1.0 NE ND ND ND Chloroform mg/l 1.0 NE ND ND ND Chloromethane (Methylchloride)mg/l 1.0 NE ND ND ND Dibromochloromethane mg/l 1.0 NE ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3.0 NE ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 NE ND ND ND Dibromomethane mg/l 1.0 NE ND ND ND 1,2-Dichlorobenzene mg/l 1.0 NE ND ND ND 1,4-Dichlorobenzene mg/l 1.0 NE ND ND ND trans-1,4-Dichloro-2butene mg/l 1.0 NE ND ND ND 1,1-Dichloroethane mg/l 1.0 NE ND ND ND 1,2-Dichloroethane mg/l 1.0 NE ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 NE ND ND ND 1,2-Dichloropropane mg/l 1.0 NE ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND Ethylbenzene mg/l 1.0 NE ND ND ND 2-Hexanone mg/l 5.0 NE ND ND ND Iodomethane mg/l 5.0 NE ND ND ND Dichloromethane (Methylene chloride)mg/l 2.0 NE ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 NE ND ND ND 4-Methyl-2-Pentanone mg/l 5.0 NE ND ND ND Styrene mg/l 1.0 NE ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NE ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1.0 4 ND ND ND Tetrachloroethene (-ethylene)mg/l 1.0 3.3 ND ND ND Toluene mg/l 1.0 0.36 ND ND ND 1,1,1-Trichloroethane mg/l 1.0 NE ND ND ND 1,1,2-Trichloroethane mg/l 1.0 NE ND ND ND Trichloroethene (-ethylene)mg/l 1.0 30 ND ND ND Trichlorofluoromethane mg/l 1.0 NE ND ND ND 1,2,3-Trichloropropane mg/l 1.0 NE ND ND ND Vinyl acetate mg/l 2.0 NE ND ND ND Vinyl chloride mg/l 1.0 2.4 ND ND ND Total Xylenes mg/l 2.0 NE ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (8-24-2009) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (2-22-2010) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 6.54 6.54 6.65 Specific Conductance mmhos/cm (on-site)-NE 66 108 72 Temperature °C (on-site)-29 10.2 13.5 10.5 Turbidity NTU (on-site)NT 50 NT NT NT Total Antimony (Sb)mg/l NT NE NT NT NT Total Arsenic (As)mg/l 5.0 10 ND ND ND Total Barium (Ba)mg/l 5.0 NE 35.4 51.7 43.9 Total Beryllium (Be)mg/l NT 6.5 NT NT NT Total Cadmium (Cd)mg/l 1.0 0.4 ND ND ND Total Chromium (Cr)mg/l 5.0 50 ND ND ND Total Cobalt (Co)mg/l NT NE NT NT NT Total Copper (Cu)mg/l NT 7 NT NT NT Total Lead (Pb)mg/l 5.0 25 ND ND ND Total Mercury (Hg)mg/l 0.20 0.012 ND ND ND Total Nickel (Ni)mg/l NT 88 NT NT NT Total Selenium (Se)mg/l 10 5 ND ND ND Total Silver (Ag)mg/l 5.0 0.06 ND ND ND Total Thallium (Tl)mg/l NT NE NT NT NT Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l NT 50 NT NT NT Acetone mg/l 25 NE ND ND ND Acrylonitrile mg/l 10.0 NE ND ND ND Benzene mg/l 1.0 51 ND ND ND Bromochloromethane mg/l 1.0 NE ND ND ND Bromodichloromethane mg/l 1.0 NE ND ND ND Bromoform mg/l 1.0 NE ND ND ND Carbon Disulfide mg/l 2.0 NE ND ND ND Bromomethane (Methylbromide)mg/l 5.0 NE ND ND ND Carbon tetrachloride mg/l 1.0 1.6 ND ND ND Chlorobenzene (mono)mg/l 1.0 NE ND ND ND Chloroethane mg/l 1.0 NE ND ND ND Chloroform mg/l 1.0 NE ND ND ND Chloromethane (Methylchloride)mg/l 1.0 NE ND ND ND Dibromochloromethane mg/l 1.0 NE ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3.0 NE ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 NE ND ND ND Dibromomethane mg/l 1.0 NE ND ND ND 1,2-Dichlorobenzene mg/l 1.0 NE ND ND ND 1,4-Dichlorobenzene mg/l 1.0 NE ND ND ND trans-1,4-Dichloro-2butene mg/l 1.0 NE ND ND ND 1,1-Dichloroethane mg/l 1.0 NE ND ND ND 1,2-Dichloroethane mg/l 1.0 NE ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 NE ND ND ND 1,2-Dichloropropane mg/l 1.0 NE ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND Ethylbenzene mg/l 1.0 NE ND ND ND 2-Hexanone mg/l 5.0 NE ND ND ND Iodomethane mg/l 5.0 NE ND ND ND Dichloromethane (Methylene chloride)mg/l 2.0 NE ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 NE ND ND ND 4-Methyl-2-Pentanone mg/l 5.0 NE ND ND ND Styrene mg/l 1.0 NE ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NE ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1.0 4 ND ND ND Tetrachloroethene (-ethylene)mg/l 1.0 3.3 ND ND ND Toluene mg/l 1.0 0.36 ND ND ND 1,1,1-Trichloroethane mg/l 1.0 NE ND ND ND 1,1,2-Trichloroethane mg/l 1.0 NE ND ND ND Trichloroethene (-ethylene)mg/l 1.0 30 ND ND ND Trichlorofluoromethane mg/l 1.0 NE ND ND ND 1,2,3-Trichloropropane mg/l 1.0 NE ND ND ND Vinyl acetate mg/l 2.0 NE ND ND ND Vinyl chloride mg/l 1.0 2.4 ND ND ND Total Xylenes mg/l 2.0 NE ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (2-22-2010) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (8-30-2010) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 6.53 6.38 6.5 Specific Conductance mmhos/cm (on-site)-NE 72 104 96 Temperature °C (on-site)-29 20.9 24.5 23.2 Turbidity NTU (on-site)NT 50 NT NT NT Total Antimony (Sb)mg/l NT NE NT NT NT Total Arsenic (As)mg/l 5.0 10 ND ND ND Total Barium (Ba)mg/l 5.0 NE 65 44.4 37.7 Total Beryllium (Be)mg/l NT 6.5 NT ND NT Total Cadmium (Cd)mg/l 1.0 0.4 ND ND ND Total Chromium (Cr)mg/l 5.0 50 7.1 ND ND Total Cobalt (Co)mg/l NT NE NT NT NT Total Copper (Cu)mg/l NT 7 NT NT NT Total Lead (Pb)mg/l 5.0 25 ND ND ND Total Mercury (Hg)mg/l 0.20 0.012 ND ND ND Total Nickel (Ni)mg/l NT 88 NT NT NT Total Selenium (Se)mg/l 10 5 ND ND ND Total Silver (Ag)mg/l 5.0 0.06 ND ND ND Total Thallium (Tl)mg/l NT NE NT NT NT Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l NT 50 NT NT NT Acetone mg/l 25 NE ND ND ND Acrylonitrile mg/l 10.0 NE ND ND ND Benzene mg/l 1.0 51 ND ND ND Bromochloromethane mg/l 1.0 NE ND ND ND Bromodichloromethane mg/l 1.0 NE ND ND ND Bromoform mg/l 1.0 NE ND ND ND Carbon Disulfide mg/l 2.0 NE ND ND ND Bromomethane (Methylbromide)mg/l 2.0 NE ND ND ND Carbon tetrachloride mg/l 1.0 1.6 ND ND ND Chlorobenzene (mono)mg/l 1.0 NE ND ND ND Chloroethane mg/l 1.0 NE ND ND ND Chloroform mg/l 1.0 NE ND ND ND Chloromethane (Methylchloride)mg/l 1.0 NE ND ND ND Dibromochloromethane mg/l 1.0 NE ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5.0 NE ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 NE ND ND ND Dibromomethane mg/l 1.0 NE ND ND ND 1,2-Dichlorobenzene mg/l 1.0 NE ND ND ND 1,4-Dichlorobenzene mg/l 1.0 NE ND ND ND trans-1,4-Dichloro-2butene mg/l 1.0 NE ND ND ND 1,1-Dichloroethane mg/l 1.0 NE ND ND ND 1,2-Dichloroethane mg/l 1.0 NE ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 NE ND ND ND 1,2-Dichloropropane mg/l 1.0 NE ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND Ethylbenzene mg/l 1.0 NE ND ND ND 2-Hexanone mg/l 5.0 NE ND ND ND Iodomethane mg/l 5.0 NE ND ND ND Dichloromethane (Methylene chloride)mg/l 2.0 NE ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 NE ND ND ND 4-Methyl-2-Pentanone mg/l 5.0 NE ND ND ND Styrene mg/l 1.0 NE ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NE ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1.0 4 ND ND ND Tetrachloroethene (-ethylene)mg/l 1.0 3.3 ND ND ND Toluene mg/l 1.0 0.36 ND ND ND 1,1,1-Trichloroethane mg/l 1.0 NE ND ND ND 1,1,2-Trichloroethane mg/l 1.0 NE ND ND ND Trichloroethene (-ethylene)mg/l 1.0 30 ND ND ND Trichlorofluoromethane mg/l 1.0 NE ND ND ND 1,2,3-Trichloropropane mg/l 1.0 NE ND ND ND Vinyl acetate mg/l 2.0 NE ND ND ND Vinyl chloride mg/l 1.0 2.4 ND ND ND Total Xylenes mg/l 2.0 NE ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (8-30-2010) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (2-22-2011) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 6.45 6.33 6.28 Specific Conductance mmhos/cm (on-site)-NE 86 99 112 Temperature °C (on-site)-29 10.8 8.4 13.9 Turbidity NTU (on-site)-50 0.94 1.3 1.45 Total Antimony (Sb)mg/l 5.0 NE ND ND ND Total Arsenic (As)mg/l 5.0 10 ND ND ND Total Barium (Ba)mg/l 5.0 NE 37.5 39.8 46.9 Total Beryllium (Be)mg/l 1.0 6.5 ND ND ND Total Cadmium (Cd)mg/l 1.0 0.4 ND ND ND Total Chromium (Cr)mg/l 5.0 50 ND ND ND Total Cobalt (Co)mg/l 5.0 NE 7.2 5.4 ND Total Copper (Cu)mg/l 5.0 7 ND ND ND Total Lead (Pb)mg/l 5.0 25 ND ND ND Total Mercury (Hg)mg/l NT 0.012 NT NT NT Total Nickel (Ni)mg/l 5.0 88 ND ND ND Total Selenium (Se)mg/l 10.0 5 ND ND ND Total Silver (Ag)mg/l 5.0 0.06 ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l 10.0 50 ND 12.7 ND Acetone mg/l 25.0 NE ND ND ND Acrylonitrile mg/l 10.0 NE ND ND ND Benzene mg/l 1.0 51 ND ND ND Bromochloromethane mg/l 1.0 NE ND ND ND Bromodichloromethane mg/l 1.0 NE ND ND ND Bromoform mg/l 1.0 NE ND ND ND Carbon Disulfide mg/l 2.0 NE ND ND ND Bromomethane (Methylbromide)mg/l 2.0 NE ND ND ND Carbon tetrachloride mg/l 1.0 1.6 ND ND ND Chlorobenzene (mono)mg/l 1.0 NE ND ND ND Chloroethane mg/l 1.0 NE ND ND ND Chloroform mg/l 1.0 NE ND ND ND Chloromethane (Methylchloride)mg/l 1.0 NE ND ND ND Dibromochloromethane mg/l 1.0 NE ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5.0 NE ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 NE ND ND ND Dibromomethane mg/l 1.0 NE ND ND ND 1,2-Dichlorobenzene mg/l 1.0 NE ND ND ND 1,4-Dichlorobenzene mg/l 1.0 NE ND ND ND trans-1,4-Dichloro-2butene mg/l 1.0 NE ND ND ND 1,1-Dichloroethane mg/l 1.0 NE ND ND ND 1,2-Dichloroethane mg/l 1.0 NE ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 NE ND ND ND 1,2-Dichloropropane mg/l 1.0 NE ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND Ethylbenzene mg/l 1.0 NE ND ND ND 2-Hexanone mg/l 5.0 NE ND ND ND Iodomethane mg/l 5.0 NE ND ND ND Dichloromethane (Methylene chloride)mg/l 2.0 NE ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 NE ND ND ND 4-Methyl-2-Pentanone mg/l 5.0 NE ND ND ND Styrene mg/l 1.0 NE ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NE ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1.0 4 ND ND ND Tetrachloroethene (-ethylene)mg/l 1.0 3.3 ND ND ND Toluene mg/l 1.0 0.36 ND ND ND 1,1,1-Trichloroethane mg/l 1.0 NE ND ND ND 1,1,2-Trichloroethane mg/l 1.0 NE ND ND ND Trichloroethene (-ethylene)mg/l 1.0 30 ND ND ND Trichlorofluoromethane mg/l 1.0 NE ND ND ND 1,2,3-Trichloropropane mg/l 1.0 NE ND ND ND Vinyl acetate mg/l 2.0 NE ND ND ND Vinyl chloride mg/l 1.0 2.4 ND ND ND Total Xylenes mg/l 2.0 NE ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (2-22-2011) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (8-22-2011) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 6.6 6.5 6.6 Specific Conductance mmhos/cm (on-site)-NE 93 99 114 Temperature °C (on-site)-29 23.5 24 22 Turbidity NTU (on-site)-50 37 5.9 5.7 Total Antimony (Sb)mg/l 5.0 NE ND ND ND Total Arsenic (As)mg/l 5.0 10 ND ND ND Total Barium (Ba)mg/l 5.0 NE 45.5 41.8 41.6 Total Beryllium (Be)mg/l 1.0 6.5 ND ND ND Total Cadmium (Cd)mg/l 1.0 0.4 ND ND ND Total Chromium (Cr)mg/l 5.0 50 ND ND ND Total Cobalt (Co)mg/l 5.0 NE ND ND ND Total Copper (Cu)mg/l 5.0 7 ND ND ND Total Lead (Pb)mg/l 5.0 25 ND ND ND Total Mercury (Hg)mg/l NT 0.012 NT NT NT Total Nickel (Ni)mg/l 5.0 88 ND ND ND Total Selenium (Se)mg/l 10.0 5 ND ND ND Total Silver (Ag)mg/l 5.0 0.06 ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l 10.0 50 ND ND ND Acetone mg/l 25.0 NE ND ND ND Acrylonitrile mg/l 10.0 NE ND ND ND Benzene mg/l 1.0 51 ND ND ND Bromochloromethane mg/l 1.0 NE ND ND ND Bromodichloromethane mg/l 1.0 NE ND ND ND Bromoform mg/l 1.0 NE ND ND ND Carbon Disulfide mg/l 2.0 NE ND ND ND Bromomethane (Methylbromide)mg/l 2.0 NE ND ND ND Carbon tetrachloride mg/l 1.0 1.6 ND ND ND Chlorobenzene (mono)mg/l 1.0 NE ND ND ND Chloroethane mg/l 1.0 NE ND ND ND Chloroform mg/l 1.0 NE ND ND ND Chloromethane (Methylchloride)mg/l 1.0 NE ND ND ND Dibromochloromethane mg/l 1.0 NE ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5.0 NE ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 NE ND ND ND Dibromomethane mg/l 1.0 NE ND ND ND 1,2-Dichlorobenzene mg/l 1.0 NE ND ND ND 1,4-Dichlorobenzene mg/l 1.0 NE ND ND ND trans-1,4-Dichloro-2butene mg/l 1.0 NE ND ND ND 1,1-Dichloroethane mg/l 1.0 NE ND ND ND 1,2-Dichloroethane mg/l 1.0 NE ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 NE ND ND ND 1,2-Dichloropropane mg/l 1.0 NE ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND Ethylbenzene mg/l 1.0 NE ND ND ND 2-Hexanone mg/l 5.0 NE ND ND ND Iodomethane mg/l 5.0 NE ND ND ND Dichloromethane (Methylene chloride)mg/l 2.0 NE ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 NE ND ND ND 4-Methyl-2-Pentanone mg/l 5.0 NE ND ND ND Styrene mg/l 1.0 NE ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NE ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1.0 4 ND ND ND Tetrachloroethene (-ethylene)mg/l 1.0 3.3 ND ND ND Toluene mg/l 1.0 0.36 ND ND ND 1,1,1-Trichloroethane mg/l 1.0 NE ND ND ND 1,1,2-Trichloroethane mg/l 1.0 NE ND ND ND Trichloroethene (-ethylene)mg/l 1.0 30 ND ND ND Trichlorofluoromethane mg/l 1.0 NE ND ND ND 1,2,3-Trichloropropane mg/l 1.0 NE ND ND ND Vinyl acetate mg/l 2.0 NE ND ND ND Vinyl chloride mg/l 1.0 2.4 ND ND ND Total Xylenes mg/l 2.0 NE ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (8-22-2011) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (2-22-2012) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 7.4 7 7.1 Specific Conductance mmhos/cm (on-site)-NE 75 85 101 Temperature °C (on-site)-29 12.4 11 12.1 Turbidity NTU (on-site)-50 2.95 4.53 3.9 Total Antimony (Sb)mg/l 5.0 NE ND ND ND Total Arsenic (As)mg/l 5.0 10 ND ND ND Total Barium (Ba)mg/l 5.0 NE 35.1 36.0 38.6 Total Beryllium (Be)mg/l 1.0 6.5 ND ND ND Total Cadmium (Cd)mg/l 1.0 0.4 ND ND ND Total Chromium (Cr)mg/l 5.0 50 ND ND ND Total Cobalt (Co)mg/l 5.0 NE ND ND ND Total Copper (Cu)mg/l 5.0 7 ND ND ND Total Lead (Pb)mg/l 5.0 25 ND ND ND Total Mercury (Hg)mg/l 0.20 0.012 ND ND ND Total Nickel (Ni)mg/l 5.0 88 ND ND ND Total Selenium (Se)mg/l 10.0 5 ND ND ND Total Silver (Ag)mg/l 5.0 0.06 ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l 10.0 50 ND ND ND Acetone mg/l 25 NE ND ND ND Acrylonitrile mg/l 10.0 NE ND ND ND Benzene mg/l 1.0 51 ND ND ND Bromochloromethane mg/l 1.0 NE ND ND ND Bromodichloromethane mg/l 1.0 NE ND ND ND Bromoform mg/l 1.0 NE ND ND ND Carbon Disulfide mg/l 2.0 NE ND ND ND Bromomethane (Methylbromide)mg/l 2.0 NE ND ND ND Carbon tetrachloride mg/l 1.0 1.6 ND ND ND Chlorobenzene (mono)mg/l 1.0 NE ND ND ND Chloroethane mg/l 1.0 NE ND ND ND Chloroform mg/l 1.0 NE ND ND ND Chloromethane (Methylchloride)mg/l 1.0 NE ND ND ND Dibromochloromethane mg/l 1.0 NE ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5.0 NE ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 NE ND ND ND Dibromomethane mg/l 1.0 NE ND ND ND 1,2-Dichlorobenzene mg/l 1.0 NE ND ND ND 1,4-Dichlorobenzene mg/l 1.0 NE ND ND ND trans-1,4-Dichloro-2butene mg/l 1.0 NE ND ND ND 1,1-Dichloroethane mg/l 1.0 NE ND ND ND 1,2-Dichloroethane mg/l 1.0 NE ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 NE ND ND ND 1,2-Dichloropropane mg/l 1.0 NE ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND Ethylbenzene mg/l 1.0 NE ND ND ND 2-Hexanone mg/l 5.0 NE ND ND ND Iodomethane mg/l 5.0 NE ND ND ND Dichloromethane (Methylene chloride)mg/l 2.0 NE ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 NE ND ND ND 4-Methyl-2-Pentanone mg/l 5.0 NE ND ND ND Styrene mg/l 1.0 NE ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NE ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1.0 4 ND ND ND Tetrachloroethene (-ethylene)mg/l 1.0 3.3 ND ND ND Toluene mg/l 1.0 0.36 ND ND ND 1,1,1-Trichloroethane mg/l 1.0 NE ND ND ND 1,1,2-Trichloroethane mg/l 1.0 NE ND ND ND Trichloroethene (-ethylene)mg/l 1.0 30 ND ND ND Trichlorofluoromethane mg/l 1.0 NE ND ND ND 1,2,3-Trichloropropane mg/l 1.0 NE ND ND ND Vinyl acetate mg/l 2.0 NE ND ND ND Vinyl chloride mg/l 1.0 2.4 ND ND ND Total Xylenes mg/l 2.0 NE ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (2-22-2012) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (8-29-2012) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 6.4 7.3 6.9 Specific Conductance mmhos/cm (on-site)-NE 89 106 113 Temperature °C (on-site)-29 22.8 21.4 21 Turbidity NTU (on-site)-50 5.99 7.39 7 Total Antimony (Sb)mg/l 5.0 NE ND ND ND Total Arsenic (As)mg/l 5.0 10 ND ND ND Total Barium (Ba)mg/l 5.0 NE 40.2 41.9 47.2 Total Beryllium (Be)mg/l 1.0 6.5 ND ND ND Total Cadmium (Cd)mg/l 1.0 0.4 ND ND ND Total Chromium (Cr)mg/l 5.0 50 ND ND ND Total Cobalt (Co)mg/l 5.0 NE ND ND ND Total Copper (Cu)mg/l 5.0 7 ND ND ND Total Lead (Pb)mg/l 5.0 25 ND ND ND Total Mercury (Hg)mg/l 0.20 0.012 ND ND ND Total Nickel (Ni)mg/l 5.0 88 ND ND ND Total Selenium (Se)mg/l 10.0 5 ND ND ND Total Silver (Ag)mg/l 5.0 0.06 ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l 10.0 50 ND ND ND Acetone mg/l 25 NE ND ND ND Acrylonitrile mg/l 10.0 NE ND ND ND Benzene mg/l 1.0 51 ND ND ND Bromochloromethane mg/l 1.0 NE ND ND ND Bromodichloromethane mg/l 1.0 NE ND ND ND Bromoform mg/l 1.0 NE ND ND ND Carbon Disulfide mg/l 2.0 NE ND ND ND Bromomethane (Methylbromide)mg/l 2.0 NE ND ND ND Carbon tetrachloride mg/l 1.0 1.6 ND ND ND Chlorobenzene (mono)mg/l 1.0 NE ND ND ND Chloroethane mg/l 1.0 NE ND ND ND Chloroform mg/l 1.0 NE ND ND ND Chloromethane (Methylchloride)mg/l 1.0 NE ND ND ND Dibromochloromethane mg/l 1.0 NE ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5.0 NE ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 NE ND ND ND Dibromomethane mg/l 1.0 NE ND ND ND 1,2-Dichlorobenzene mg/l 1.0 NE ND ND ND 1,4-Dichlorobenzene mg/l 1.0 NE ND ND ND trans-1,4-Dichloro-2butene mg/l 1.0 NE ND ND ND 1,1-Dichloroethane mg/l 1.0 NE ND ND ND 1,2-Dichloroethane mg/l 1.0 NE ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 NE ND ND ND 1,2-Dichloropropane mg/l 1.0 NE ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND Ethylbenzene mg/l 1.0 NE ND ND ND 2-Hexanone mg/l 5.0 NE ND ND ND Iodomethane mg/l 5.0 NE ND ND ND Dichloromethane (Methylene chloride)mg/l 1.0 NE ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 NE ND ND ND 4-Methyl-2-Pentanone mg/l 5.0 NE ND ND ND Styrene mg/l 1.0 NE ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NE ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1.0 4 ND ND ND Tetrachloroethene (-ethylene)mg/l 1.0 3.3 ND ND ND Toluene mg/l 1.0 0.36 ND ND ND 1,1,1-Trichloroethane mg/l 1.0 NE ND ND ND 1,1,2-Trichloroethane mg/l 1.0 NE ND ND ND Trichloroethene (-ethylene)mg/l 1.0 30 ND ND ND Trichlorofluoromethane mg/l 1.0 NE ND ND ND 1,2,3-Trichloropropane mg/l 1.0 NE ND ND ND Vinyl acetate mg/l 2.0 NE ND ND ND Vinyl chloride mg/l 1.0 2.4 ND ND ND Total Xylenes mg/l 2.0 NE ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (8-29-2012) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (2-18-2013) TEST UNITS MDL MRL SW-1 SW-2 Blanton Branch pH pH units (on-site)-<6.0; >9.0 6.9 7.1 7.1 Specific Conductance mmhos/cm (on-site)-NE 68 75 97 Temperature °C (on-site)-29 9.0 9.4 11.3 Turbidity NTU (on-site)-50 2.40 2.48 294 Total Antimony (Sb)mg/l 5.0 NE ND ND ND Total Arsenic (As)mg/l 5.0 10 ND ND ND Total Barium (Ba)mg/l 5.0 NE 35 38.0 41.4 Total Beryllium (Be)mg/l 1.0 6.5 ND ND ND Total Cadmium (Cd)mg/l 1.0 0.4 ND ND ND Total Chromium (Cr)mg/l 5.0 50 ND ND ND Total Cobalt (Co)mg/l 5.0 NE ND ND ND Total Copper (Cu)mg/l 5.0 7 ND ND ND Total Lead (Pb)mg/l 5.0 25 ND ND ND Total Mercury (Hg)mg/l 0.20 0.012 ND ND ND Total Nickel (Ni)mg/l 5.0 88 ND ND ND Total Selenium (Se)mg/l 10.0 5 ND ND ND Total Silver (Ag)mg/l 5.0 0.06 ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND Total Vanadium (V)mg/l 5.0 NE NT NT NT Total Zinc (Zn)mg/l 10.0 50 ND ND ND Acetone mg/l 25 NE ND ND ND Acrylonitrile mg/l 10.0 NE ND ND ND Benzene mg/l 1.0 51 ND ND ND Bromochloromethane mg/l 1.0 NE ND ND ND Bromodichloromethane mg/l 1.0 NE ND ND ND Bromoform mg/l 1.0 NE ND ND ND Carbon Disulfide mg/l 2.0 NE ND ND ND Bromomethane (Methylbromide)mg/l 2.0 NE ND ND ND Carbon tetrachloride mg/l 1.0 1.6 ND ND ND Chlorobenzene (mono)mg/l 1.0 NE ND ND ND Chloroethane mg/l 1.0 NE ND ND ND Chloroform mg/l 1.0 NE ND ND ND Chloromethane (Methylchloride)mg/l 1.0 NE ND ND ND Dibromochloromethane mg/l 1.0 NE ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5.0 NE ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 NE ND ND ND Dibromomethane mg/l 1.0 NE ND ND ND 1,2-Dichlorobenzene mg/l 1.0 NE ND ND ND 1,4-Dichlorobenzene mg/l 1.0 NE ND ND ND trans-1,4-Dichloro-2butene mg/l 1.0 NE ND ND ND 1,1-Dichloroethane mg/l 1.0 NE ND ND ND 1,2-Dichloroethane mg/l 1.0 NE ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 NE ND ND ND 1,2-Dichloropropane mg/l 1.0 NE ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND Ethylbenzene mg/l 1.0 NE ND ND ND 2-Hexanone mg/l 5.0 NE ND ND ND Iodomethane mg/l 5.0 NE ND ND ND Dichloromethane (Methylene chloride)mg/l 1.0 NE ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 NE ND ND ND 4-Methyl-2-Pentanone mg/l 5.0 NE ND ND ND Styrene mg/l 1.0 NE ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NE ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1.0 4 ND ND ND Tetrachloroethene (-ethylene)mg/l 1.0 3.3 ND ND ND Toluene mg/l 1.0 0.36 ND ND ND 1,1,1-Trichloroethane mg/l 1.0 NE ND ND ND 1,1,2-Trichloroethane mg/l 1.0 NE ND ND ND Trichloroethene (-ethylene)mg/l 1.0 30 ND ND ND Trichlorofluoromethane mg/l 1.0 NE ND ND ND 1,2,3-Trichloropropane mg/l 1.0 NE ND ND ND Vinyl acetate mg/l 2.0 NE ND ND ND Vinyl chloride mg/l 1.0 2.4 ND ND ND Total Xylenes mg/l 2.0 NE ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (2-18-2013) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (8-26-13) TEST UNITS MDL MRL US-1 DS-1 DS-2 DS-3 pH pH units (on-site)-<6.0; >9.0 7.2 7 7.1 7.3 Specific Conductance mmhos/cm (on-site)-NE 81.2 80.9 86.4 88.4 Temperature °C (on-site)-29 19.0 19.2 19.1 19.6 Turbidity NTU (on-site)-50 11.6 8.32 7.09 4.82 Total Antimony (Sb)mg/l 5.0 NE ND ND ND ND Total Arsenic (As)mg/l 5.0 10 ND ND ND ND Total Barium (Ba)mg/l 5.0 NE 60.1 48.5 46.3 44.5 Total Beryllium (Be)mg/l 1.0 6.5 ND ND ND ND Total Cadmium (Cd)mg/l 1.0 0.4 ND ND ND ND Total Chromium (Cr)mg/l 5.0 50 6.1 ND ND ND Total Cobalt (Co)mg/l 5.0 NE 5.7 ND ND ND Total Copper (Cu)mg/l 5.0 7 ND ND ND ND Total Lead (Pb)mg/l 5.0 25 ND ND ND ND Total Mercury (Hg)mg/l 0.20 0.012 ND ND ND ND Total Nickel (Ni)mg/l 5.0 88 ND ND ND ND Total Selenium (Se)mg/l 10.0 5 ND ND ND ND Total Silver (Ag)mg/l 5.0 0.06 ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND Total Vanadium (V)mg/l 5.0 NE 9 5.9 ND ND Total Zinc (Zn)mg/l 10.0 50 14.3 ND 11.9 ND Acetone mg/l 25 NE ND ND ND ND Acrylonitrile mg/l 10.0 NE ND ND ND ND Benzene mg/l 1.0 51 ND ND ND ND Bromochloromethane mg/l 1.0 NE ND ND ND ND Bromodichloromethane mg/l 1.0 NE ND ND ND ND Bromoform mg/l 1.0 NE ND ND ND ND Carbon Disulfide mg/l 2.0 NE ND ND ND ND Bromomethane (Methylbromide)mg/l 2.0 NE ND ND ND ND Carbon tetrachloride mg/l 1.0 1.6 ND ND ND ND Chlorobenzene (mono)mg/l 1.0 NE ND ND ND ND Chloroethane mg/l 1.0 NE ND ND ND ND Chloroform mg/l 1.0 NE ND ND ND ND Chloromethane (Methylchloride)mg/l 1.0 NE ND ND ND ND Dibromochloromethane mg/l 1.0 NE ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5.0 NE ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 NE ND ND ND ND Dibromomethane mg/l 1.0 NE ND ND ND ND 1,2-Dichlorobenzene mg/l 1.0 NE ND ND ND ND 1,4-Dichlorobenzene mg/l 1.0 NE ND ND ND ND trans-1,4-Dichloro-2butene mg/l 1.0 NE ND ND ND ND 1,1-Dichloroethane mg/l 1.0 NE ND ND ND ND 1,2-Dichloroethane mg/l 1.0 NE ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 NE ND ND ND ND 1,2-Dichloropropane mg/l 1.0 NE ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND ND Ethylbenzene mg/l 1.0 NE ND ND ND ND 2-Hexanone mg/l 5.0 NE ND ND ND ND Iodomethane mg/l 5.0 NE ND ND ND ND Dichloromethane (Methylene chloride)mg/l 1.0 NE ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 NE ND ND ND ND 4-Methyl-2-Pentanone mg/l 5.0 NE ND ND ND ND Styrene mg/l 1.0 NE ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NE ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1.0 4 ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1.0 3.3 ND ND ND ND Toluene mg/l 1.0 0.36 ND ND ND ND 1,1,1-Trichloroethane mg/l 1.0 NE ND ND ND ND 1,1,2-Trichloroethane mg/l 1.0 NE ND ND ND ND Trichloroethene (-ethylene)mg/l 1.0 30 ND ND ND ND Trichlorofluoromethane mg/l 1.0 NE ND ND ND ND 1,2,3-Trichloropropane mg/l 1.0 NE ND ND ND ND Vinyl acetate mg/l 2.0 NE ND ND ND ND Vinyl chloride mg/l 1.0 2.4 ND ND ND ND Total Xylenes mg/l 2.0 NE ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (8-26-13) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (2-20-14) TEST UNITS MDL MRL US-1 DS-1 DS-2 DS-3 pH pH units (on-site)-<6.0; >9.0 6.6 7.1 7.3 7.1 Specific Conductance mmhos/cm (on-site)-NE 68 54 74 80 Temperature °C (on-site)-29 12.2 13.2 11.9 12.3 Turbidity NTU (on-site)-50 4.61 3.41 4.38 4.92 Total Antimony (Sb)mg/l 5.0 NE ND ND ND ND Total Arsenic (As)mg/l 5.0 10 ND ND ND ND Total Barium (Ba)mg/l 5.0 NE 39.6 40.6 43.8 46.6 Total Beryllium (Be)mg/l 1.0 6.5 ND ND ND ND Total Cadmium (Cd)mg/l 1.0 0.4 ND ND ND ND Total Chromium (Cr)mg/l 5.0 50 ND ND ND ND Total Cobalt (Co)mg/l 5.0 NE ND ND ND ND Total Copper (Cu)mg/l 5.0 7 ND ND ND ND Total Lead (Pb)mg/l 5.0 25 ND ND ND ND Total Mercury (Hg)mg/l 0.20 0.012 ND ND ND ND Total Nickel (Ni)mg/l 5.0 88 ND ND ND ND Total Selenium (Se)mg/l 10.0 5 ND ND ND ND Total Silver (Ag)mg/l 5.0 0.06 ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND Total Vanadium (V)mg/l 5.0 NE ND ND ND ND Total Zinc (Zn)mg/l 10.0 50 ND ND ND ND Acetone mg/l 25 NE ND ND ND ND Acrylonitrile mg/l 10.0 NE ND ND ND ND Benzene mg/l 1.0 51 ND ND ND ND Bromochloromethane mg/l 1.0 NE ND ND ND ND Bromodichloromethane mg/l 1.0 NE ND ND ND ND Bromoform mg/l 1.0 NE ND ND ND ND Carbon Disulfide mg/l 2.0 NE ND ND ND ND Bromomethane (Methylbromide)mg/l 2.0 NE ND ND ND ND Carbon tetrachloride mg/l 1.0 1.6 ND ND ND ND Chlorobenzene (mono)mg/l 1.0 NE ND ND ND ND Chloroethane mg/l 1.0 NE ND ND ND ND Chloroform mg/l 1.0 NE ND ND ND ND Chloromethane (Methylchloride)mg/l 1.0 NE ND ND ND ND Dibromochloromethane mg/l 1.0 NE ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5.0 NE ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 NE ND ND ND ND Dibromomethane mg/l 1.0 NE ND ND ND ND 1,2-Dichlorobenzene mg/l 1.0 NE ND ND ND ND 1,4-Dichlorobenzene mg/l 1.0 NE ND ND ND ND trans-1,4-Dichloro-2butene mg/l 1.0 NE ND ND ND ND 1,1-Dichloroethane mg/l 1.0 NE ND ND ND ND 1,2-Dichloroethane mg/l 1.0 NE ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 NE ND ND ND ND 1,2-Dichloropropane mg/l 1.0 NE ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND ND Ethylbenzene mg/l 1.0 NE ND ND ND ND 2-Hexanone mg/l 5.0 NE ND ND ND ND Iodomethane mg/l 5.0 NE ND ND ND ND Dichloromethane (Methylene chloride)mg/l 1.0 NE ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 NE ND ND ND ND 4-Methyl-2-Pentanone mg/l 5.0 NE ND ND ND ND Styrene mg/l 1.0 NE ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NE ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1.0 4 ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1.0 3.3 ND ND ND ND Toluene mg/l 1.0 0.36 ND ND ND ND 1,1,1-Trichloroethane mg/l 1.0 NE ND ND ND ND 1,1,2-Trichloroethane mg/l 1.0 NE ND ND ND ND Trichloroethene (-ethylene)mg/l 1.0 30 ND ND ND ND Trichlorofluoromethane mg/l 1.0 NE ND ND ND ND 1,2,3-Trichloropropane mg/l 1.0 NE ND ND ND ND Vinyl acetate mg/l 2.0 NE ND ND ND ND Vinyl chloride mg/l 1.0 2.4 ND ND ND ND Total Xylenes mg/l 2.0 NE ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (2-20-14) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (8-28-14) TEST UNITS MDL MRL US-1 DS-1 DS-2 DS-3 pH pH units (on-site)-<6.0; >9.0 7.6 7.5 7.2 7.5 Specific Conductance mmhos/cm (on-site)-NE 91 88 94 105 Temperature °C (on-site)-29 21.1 22.3 22.3 22.6 Turbidity NTU (on-site)-50 6.79 10.04 4.11 5.44 Total Antimony (Sb)mg/l 5.0 NE ND ND ND ND Total Arsenic (As)mg/l 10.0 10 ND ND ND ND Total Barium (Ba)mg/l 5.0 NE 47.4 46.2 45.4 54.7 Total Beryllium (Be)mg/l 1.0 6.5 ND ND ND ND Total Cadmium (Cd)mg/l 1.0 0.4 ND ND ND ND Total Chromium (Cr)mg/l 5.0 50 ND ND ND ND Total Cobalt (Co)mg/l 5.0 NE ND ND ND ND Total Copper (Cu)mg/l 5.0 7 ND ND ND ND Total Lead (Pb)mg/l 5.0 25 ND ND ND ND Total Mercury (Hg)mg/l NT 0.012 NT NT NT NT Total Nickel (Ni)mg/l 5.0 88 ND ND ND ND Total Selenium (Se)mg/l 10.0 5 ND ND ND ND Total Silver (Ag)mg/l 5.0 0.06 ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND Total Vanadium (V)mg/l 5.0 NE ND ND ND ND Total Zinc (Zn)mg/l 10.0 50 ND ND ND ND Acetone mg/l 25 NE ND ND ND ND Acrylonitrile mg/l 10.0 NE ND ND ND ND Benzene mg/l 1.0 51 ND ND ND ND Bromochloromethane mg/l 1.0 NE ND ND ND ND Bromodichloromethane mg/l 1.0 NE ND ND ND ND Bromoform mg/l 1.0 NE ND ND ND ND Carbon Disulfide mg/l 2.0 NE ND ND ND ND Bromomethane (Methylbromide)mg/l 2.0 NE ND ND ND ND Carbon tetrachloride mg/l 1.0 1.6 ND ND ND ND Chlorobenzene (mono)mg/l 1.0 NE ND ND ND ND Chloroethane mg/l 1.0 NE ND ND ND ND Chloroform mg/l 1.0 NE ND ND ND ND Chloromethane (Methylchloride)mg/l 1.0 NE ND ND ND ND Dibromochloromethane mg/l 1.0 NE ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 2.0 NE ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 NE ND ND ND ND Dibromomethane mg/l 1.0 NE ND ND ND ND 1,2-Dichlorobenzene mg/l 1.0 NE ND ND ND ND 1,4-Dichlorobenzene mg/l 1.0 NE ND ND ND ND trans-1,4-Dichloro-2butene mg/l 1.0 NE ND ND ND ND 1,1-Dichloroethane mg/l 1.0 NE ND ND ND ND 1,2-Dichloroethane mg/l 1.0 NE ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 NE ND ND ND ND 1,2-Dichloropropane mg/l 1.0 NE ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND ND Ethylbenzene mg/l 1.0 NE ND ND ND ND 2-Hexanone mg/l 5.0 NE ND ND ND ND Iodomethane mg/l 5.0 NE ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2.0 NE ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 NE ND ND ND ND 4-Methyl-2-Pentanone mg/l 5.0 NE ND ND ND ND Styrene mg/l 1.0 NE ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NE ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1.0 4 ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1.0 3.3 ND ND ND ND Toluene mg/l 1.0 0.36 ND ND ND ND 1,1,1-Trichloroethane mg/l 1.0 NE ND ND ND ND 1,1,2-Trichloroethane mg/l 1.0 NE ND ND ND ND Trichloroethene (-ethylene)mg/l 1.0 30 ND ND ND ND Trichlorofluoromethane mg/l 1.0 NE ND ND ND ND 1,2,3-Trichloropropane mg/l 1.0 NE ND ND ND ND Vinyl acetate mg/l 2.0 NE ND ND ND ND Vinyl chloride mg/l 1.0 2.4 ND ND ND ND Total Xylenes mg/l 2.0 NE ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (8-28-14) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (2-20-15) TEST UNITS MDL MRL US-1 DS-1 DS-2 DS-3 pH pH units (on-site)-<6.0; >9.0 6.9 7 7.1 7.1 Specific Conductance mmhos/cm (on-site)-NE 78 78 81 87 Temperature °C (on-site)-29 2.1 1.5 2.9 2.7 Turbidity NTU (on-site)-50 0.5 0.47 2.26 2.26 Total Antimony (Sb)mg/l 5.0 NE ND ND ND ND Total Arsenic (As)mg/l 10.0 10 ND ND ND ND Total Barium (Ba)mg/l 5.0 NE 36.1 39.9 41.6 43.4 Total Beryllium (Be)mg/l 1.0 6.5 ND ND ND ND Total Cadmium (Cd)mg/l 1.0 0.4 ND ND ND ND Total Chromium (Cr)mg/l 5.0 50 ND ND ND ND Total Cobalt (Co)mg/l 5.0 NE ND ND ND ND Total Copper (Cu)mg/l 5.0 7 ND ND ND ND Total Lead (Pb)mg/l 5.0 25 ND ND ND ND Total Mercury (Hg)mg/l NT 0.012 NT NT NT NT Total Nickel (Ni)mg/l 5.0 88 ND ND ND ND Total Selenium (Se)mg/l 10.0 5 ND ND ND ND Total Silver (Ag)mg/l 5.0 0.06 ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND Total Vanadium (V)mg/l 5.0 NE ND ND ND ND Total Zinc (Zn)mg/l 10.0 50 ND ND ND ND Acetone mg/l 25 NE ND ND ND ND Acrylonitrile mg/l 10.0 NE ND ND ND ND Benzene mg/l 1.0 51 ND ND ND ND Bromochloromethane mg/l 1.0 NE ND ND ND ND Bromodichloromethane mg/l 1.0 NE ND ND ND ND Bromoform mg/l 1.0 NE ND ND ND ND Carbon Disulfide mg/l 2.0 NE ND ND ND ND Bromomethane (Methylbromide)mg/l 2.0 NE ND ND ND ND Carbon tetrachloride mg/l 1.0 1.6 ND ND ND ND Chlorobenzene (mono)mg/l 1.0 NE ND ND ND ND Chloroethane mg/l 1.0 NE ND ND ND ND Chloroform mg/l 1.0 NE ND ND ND ND Chloromethane (Methylchloride)mg/l 1.0 NE ND ND ND ND Dibromochloromethane mg/l 1.0 NE ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 2.0 NE ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 NE ND ND ND ND Dibromomethane mg/l 1.0 NE ND ND ND ND 1,2-Dichlorobenzene mg/l 1.0 NE ND ND ND ND 1,4-Dichlorobenzene mg/l 1.0 NE ND ND ND ND trans-1,4-Dichloro-2butene mg/l 1.0 NE ND ND ND ND 1,1-Dichloroethane mg/l 1.0 NE ND ND ND ND 1,2-Dichloroethane mg/l 1.0 NE ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 NE ND ND ND ND 1,2-Dichloropropane mg/l 1.0 NE ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND ND Ethylbenzene mg/l 1.0 NE ND ND ND ND 2-Hexanone mg/l 5.0 NE ND ND ND ND Iodomethane mg/l 5.0 NE ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2.0 NE ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 NE ND ND ND ND 4-Methyl-2-Pentanone mg/l 5.0 NE ND ND ND ND Styrene mg/l 1.0 NE ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NE ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1.0 4 ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1.0 3.3 ND ND ND ND Toluene mg/l 1.0 0.36 ND ND ND ND 1,1,1-Trichloroethane mg/l 1.0 NE ND ND ND ND 1,1,2-Trichloroethane mg/l 1.0 NE ND ND ND ND Trichloroethene (-ethylene)mg/l 1.0 30 ND ND ND ND Trichlorofluoromethane mg/l 1.0 NE ND ND ND ND 1,2,3-Trichloropropane mg/l 1.0 NE ND ND ND ND Vinyl acetate mg/l 2.0 NE ND ND ND ND Vinyl chloride mg/l 1.0 2.4 ND ND ND ND Total Xylenes mg/l 2.0 NE ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (2-20-15) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (8-25-15) TEST UNITS MDL MRL US-1 DS-1 DS-2 DS-3 pH pH units (on-site)-<6.0; >9.0 7.68 6.32 6.65 6.92 Specific Conductance mmhos/cm (on-site)-NE 84.4 72.1 81.1 102.8 Temperature °C (on-site)-29 20.5 16.9 16.8 25.6 Turbidity NTU (on-site)-50 26 34 13 29 Total Antimony (Sb)mg/l 5.0 NE ND ND ND ND Total Arsenic (As)mg/l 10.0 10 ND ND ND ND Total Barium (Ba)mg/l 5.0 NE 40 44.0 42.0 38.0 Total Beryllium (Be)mg/l 1.0 6.5 ND ND ND ND Total Cadmium (Cd)mg/l 1.0 0.4 ND ND ND ND Total Chromium (Cr)mg/l 5.0 50 ND ND ND ND Total Cobalt (Co)mg/l 5.0 NE ND ND ND ND Total Copper (Cu)mg/l 5.0 7 ND ND ND ND Total Lead (Pb)mg/l 5.0 25 ND ND ND ND Total Mercury (Hg)mg/l NT 0.012 NT NT NT NT Total Nickel (Ni)mg/l 5.0 88 ND ND ND ND Total Selenium (Se)mg/l 10.0 5 ND ND ND ND Total Silver (Ag)mg/l 5.0 0.06 ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND Total Vanadium (V)mg/l 5.0 NE ND ND ND ND Total Zinc (Zn)mg/l 10.0 50 ND ND ND ND Acetone mg/l 25 NE ND ND ND ND Acrylonitrile mg/l 10.0 NE ND ND ND ND Benzene mg/l 1.0 51 ND ND ND ND Bromochloromethane mg/l 1.0 NE ND ND ND ND Bromodichloromethane mg/l 1.0 NE ND ND ND ND Bromoform mg/l 1.0 NE ND ND ND ND Carbon Disulfide mg/l 2.0 NE ND ND ND ND Bromomethane (Methylbromide)mg/l 2.0 NE ND ND ND ND Carbon tetrachloride mg/l 1.0 1.6 ND ND ND ND Chlorobenzene (mono)mg/l 1.0 NE ND ND ND ND Chloroethane mg/l 1.0 NE ND ND ND ND Chloroform mg/l 1.0 NE ND ND ND ND Chloromethane (Methylchloride)mg/l 1.0 NE ND ND ND ND Dibromochloromethane mg/l 1.0 NE ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 2.0 NE ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 NE ND ND ND ND Dibromomethane mg/l 1.0 NE ND ND ND ND 1,2-Dichlorobenzene mg/l 1.0 NE ND ND ND ND 1,4-Dichlorobenzene mg/l 1.0 NE ND ND ND ND trans-1,4-Dichloro-2butene mg/l 1.0 NE ND ND ND ND 1,1-Dichloroethane mg/l 1.0 NE ND ND ND ND 1,2-Dichloroethane mg/l 1.0 NE ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 NE ND ND ND ND 1,2-Dichloropropane mg/l 1.0 NE ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND ND Ethylbenzene mg/l 1.0 NE ND ND ND ND 2-Hexanone mg/l 5.0 NE ND ND ND ND Iodomethane mg/l 5.0 NE ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2.0 NE ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 NE ND ND ND ND 4-Methyl-2-Pentanone mg/l 5.0 NE ND ND ND ND Styrene mg/l 1.0 NE ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NE ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1.0 4 ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1.0 3.3 ND ND ND ND Toluene mg/l 1.0 0.36 ND ND ND ND 1,1,1-Trichloroethane mg/l 1.0 NE ND ND ND ND 1,1,2-Trichloroethane mg/l 1.0 NE ND ND ND ND Trichloroethene (-ethylene)mg/l 1.0 30 ND ND ND ND Trichlorofluoromethane mg/l 1.0 NE ND ND ND ND 1,2,3-Trichloropropane mg/l 1.0 NE ND ND ND ND Vinyl acetate mg/l 2.0 NE ND ND ND ND Vinyl chloride mg/l 1.0 2.4 ND ND ND ND Total Xylenes mg/l 2.0 NE ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (8-25-15) Closed Francis Farm Landfill - Haywood Co., NC Surface Water Sampling Event (3-17-16) TEST UNITS MDL MRL US-1 DS-1 DS-2 DS-3 pH pH units (on-site)-<6.0; >9.0 6.32 6.83 6.63 6.14 Specific Conductance mmhos/cm (on-site)-NE 68.3 67.3 79 83.3 Temperature °C (on-site)-29 15.0 16.1 12.2 15.5 Turbidity NTU (on-site)-50 7.8 12.6 18.0 10.7 Total Antimony (Sb)mg/l 5.0 NE ND ND ND ND Total Arsenic (As)mg/l 10.0 10 ND ND ND ND Total Barium (Ba)mg/l 5.0 NE 35 36.0 44.0 41.0 Total Beryllium (Be)mg/l 1.0 6.5 ND ND ND ND Total Cadmium (Cd)mg/l 1.0 0.4 ND ND ND ND Total Chromium (Cr)mg/l 5.0 50 ND ND ND ND Total Cobalt (Co)mg/l 5.0 NE ND ND ND ND Total Copper (Cu)mg/l 5.0 7 ND ND ND ND Total Lead (Pb)mg/l 5.0 25 ND ND ND ND Total Mercury (Hg)mg/l NT 0.012 NT NT NT NT Total Nickel (Ni)mg/l 5.0 88 ND ND ND ND Total Selenium (Se)mg/l 10.0 5 ND ND ND ND Total Silver (Ag)mg/l 5.0 0.06 ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND Total Vanadium (V)mg/l 5.0 NE ND ND ND ND Total Zinc (Zn)mg/l 10.0 50 ND ND ND ND Acetone mg/l 25 NE ND ND ND ND Acrylonitrile mg/l 10.0 NE ND ND ND ND Benzene mg/l 1.0 51 ND ND ND ND Bromochloromethane mg/l 1.0 NE ND ND ND ND Bromodichloromethane mg/l 1.0 NE ND ND ND ND Bromoform mg/l 1.0 NE ND ND ND ND Carbon Disulfide mg/l 2.0 NE ND ND ND ND Bromomethane (Methylbromide)mg/l 2.0 NE ND ND ND ND Carbon tetrachloride mg/l 1.0 1.6 ND ND ND ND Chlorobenzene (mono)mg/l 1.0 NE ND ND ND ND Chloroethane mg/l 1.0 NE ND ND ND ND Chloroform mg/l 1.0 NE ND ND ND ND Chloromethane (Methylchloride)mg/l 1.0 NE ND ND ND ND Dibromochloromethane mg/l 1.0 NE ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 2.0 NE ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1.0 NE ND ND ND ND Dibromomethane mg/l 1.0 NE ND ND ND ND 1,2-Dichlorobenzene mg/l 1.0 NE ND ND ND ND 1,4-Dichlorobenzene mg/l 1.0 NE ND ND ND ND trans-1,4-Dichloro-2butene mg/l 1.0 NE ND ND ND ND 1,1-Dichloroethane mg/l 1.0 NE ND ND ND ND 1,2-Dichloroethane mg/l 1.0 NE ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1.0 NE ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1.0 NE ND ND ND ND 1,2-Dichloropropane mg/l 1.0 NE ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1.0 NE ND ND ND ND Ethylbenzene mg/l 1.0 NE ND ND ND ND 2-Hexanone mg/l 5.0 NE ND ND ND ND Iodomethane mg/l 5.0 NE ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2.0 NE ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5.0 NE ND ND ND ND 4-Methyl-2-Pentanone mg/l 5.0 NE ND ND ND ND Styrene mg/l 1.0 NE ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1.0 NE ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1.0 4 ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1.0 3.3 ND ND ND ND Toluene mg/l 1.0 0.36 ND ND ND ND 1,1,1-Trichloroethane mg/l 1.0 NE ND ND ND ND 1,1,2-Trichloroethane mg/l 1.0 NE ND ND ND ND Trichloroethene (-ethylene)mg/l 1.0 30 ND ND ND ND Trichlorofluoromethane mg/l 1.0 NE ND ND ND ND 1,2,3-Trichloropropane mg/l 1.0 NE ND ND ND ND Vinyl acetate mg/l 2.0 NE ND ND ND ND Vinyl chloride mg/l 1.0 2.4 ND ND ND ND Total Xylenes mg/l 2.0 NE ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. Shaded cells indicated exceedances of MCLs. NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit ND = Not Detected at the MRL; "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are not presented on this spreadsheet. NS = Not Sampled NT = Not Tested NP = Not Present during sampling event 1957-48 Francis Farm SW Stats 1st 2016.xlsx (3-17-16) APPENDIX C LABORATORY ANALYTICAL RESULTS Table 5A Groundwater Sampling Matrix Closed Francis Farm Landfill Haywood County, North Carolina Permit Number 44-03 BLE Project No. J13-1957-39 Lat. North Long. West App II VOCs SVOCs App I Total Metals Dissolved Metals Pesticides Herbicides PCBs Sulfide Cyanide Well (dd)(dd)EPA 8260 EPA 8270 EPA 6010 EPA 6010/7470 EPA 8081 EPA 8151 EPA 8082 SM 4500-S2D SM 4500-CN-E MW-1 35.505892476 82.958166600 No No No No No No No No No MW-1A 35.506035959 82.958960455 Yes No Yes No No No No No Yes MW-2A 35.505447169 82.956471743 Yes No Yes No Yes No No No Yes MW-3A 35.504302294 82.955704601 Yes No Yes No No No No No Yes MW-4 35.502840483 82.958258973 Yes No Yes No Yes No No No No MW-5 35.502464177 82.958501150 Yes No Yes No No No No No Yes MW-6 35.507007166 82.958723254 Yes No Yes No No No No No Yes MW-7 35.506667347 82.957305699 Yes No Yes No Yes No No No Yes MW-8 35.506214483 82.955920712 Yes No Yes No No No No No Yes MW-9 35.505397531 82.954853325 Yes No Yes No Yes No No No No MW-10 35.504410017 82.954568656 Yes No Yes No No No No No No MW-11 35.503120939 82.957171928 Yes No Yes No Yes No No No Yes MW-12 35.501892082 82.958559051 Yes No Yes No No No No No No MW-13 35.502673138 82.959775795 Yes No Yes No Yes No No No Yes MW-14 35.504089518 82.959967696 Yes No Yes No Yes No No No Yes MW-14D 35.504044931 82.959967268 Yes No Yes No No No No No No MW-15 35.505323343 82.959552125 Yes No Yes No No No No No Yes MW-16 35.502159358 82.960874268 Yes No Yes No No No No No No MW-16D 35.502129896 82.960839270 Yes No Yes No No No No No No MW-17 35.503598911 82.961884951 Yes No Yes No No No No No No MW-18 35.504737902 82.961677540 Yes No Yes No No No No No No MW-19 35.507123544 82.957192901 Yes No Yes No Yes No No No No MW-19D 35.507088639 82.957213494 Yes No Yes No Yes No No No No MW-20 35.504496365 82.954109418 Yes No Yes No No No No No No MW-20D 35.504495795 82.954138746 Yes No Yes No No No No No No MW-21 35.502956636 82.955043604 Yes No Yes No No No No No No MW-22 35.501647029 82.963316321 Yes No Yes No No No No No No MW-23 35.507695290 82.956901959 Yes No Yes No No No No No No MW-23D 35.507731029 82.956882336 Yes No Yes No No No No No No MW-24 35.504639177 82.953652291 Yes No Yes No No No No No No MW-25 35.503043453 82.957808429 Yes No Yes No Yes No No No No Notes: (1) MW-1 is typically dry and cannot be sampled (2) VOCs = Volatile Organic Compounds (Appendix II List) (3) SVOCs = Semi-Volatile Organic Compounds (4) Total metals includes 15 metals (excludes mercury) (5) EPA or SM #### = Environmental Protection Agency or Standard Method analysis method code (6) GPS coordinates converted from N&E survey data provided by McGill Associates (7) dd - decimal degrees Table 5A GW Matrix of FFLF Assessment Tables Feb 2014 1957-39.xlsx Prepared by: AWA Checked by: MSP Table 5B Surface Water Sampling Matrix Closed Francis Farm Landfill Haywood County, North Carolina Permit Number 44-03 BLE Project No. J13-1957-39 Lat. North Long. West App II VOCs App I Total Metals Pesticides Cyanide pH Sp. Cond.Temp. Location (dd)(dd)EPA 8260 EPA 6010 EPA 8081 SM 4500-CN-E Field Field Field US-1 35.50145 82.95387 Yes Yes Yes Yes Yes Yes Yes DS-1 35.50449 82.95406 Yes Yes Yes Yes Yes Yes Yes DS-2 35.50726 82.95746 Yes Yes Yes Yes Yes Yes Yes DS-3 35.50513 82.96319 Yes Yes Yes Yes Yes Yes Yes Notes: (1) VOCs = Volatile Organic Compounds (Appendix II List) (2) Total metals includes 15 metals (excludes mercury) (3) EPA or SM #### = Environmental Protection Agency or Standard Method analysis method code (4) GPS coordinates measured by BLE via hand-held GPS receiver on January 16, 2014 (5) dd - decimal degrees Table 5B SW Matrix of FFLF Assessment Tables Feb 2014 1957-39.xlsx Prepared by: AWA Checked by: MSP SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Haywood County 215 N. Main Street Waynesville, NC 28786 Attention: David Francis RC18024Lot Number: Francis Farm Landfill Semi-AnnualProject Name: 03/28/2016Date Completed: Lucas Odom Project Manager This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. Page: 1 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. Case Narrative Haywood County Lot Number: RC18024 SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. VOCs by GC/MS Samples -001 through -005 have been analyzed twice. The initial run was at no dilution and the second run was at a 5X dilution. The initial run yielded a detection for Isobutyl Alcohol due to suspected instrument contamination. The samples were reanalyzed confirming instrument contamination. The best run has been reported. The LCS associated with batch 99475 recovered three compounds above method criteria. No corrective action is required as all associated samples are non-detect for these three compounds. Pesticides by GC Due to matrix interferences, samples -003, -007, -014, -015, and -023 were analyzed at a 10X dilution. All target compounds are non-detect at the reported dilution. Review of historical data has also yielded similar matrix interferences. Cyanide Due to matrix interferences, the MS/MSD associated with batch 99062 recovered Cyanide marginally above method criteria. The affected sample is non-detect for Cyanide. Page: 2 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Haywood County Lot Number: RC18024 Sample Number Sample ID Matrix Date Sampled Date Received 001 03/17/2016 0905MW-5 Aqueous 03/18/2016 002 03/17/2016 1900MW-6 Aqueous 03/18/2016 003 03/17/2016 1742MW-7 Aqueous 03/18/2016 004 03/17/2016 1850MW-8 Aqueous 03/18/2016 005 03/17/2016 1815MW-9 Aqueous 03/18/2016 006 03/17/2016 1842MW-10 Aqueous 03/18/2016 007 03/16/2016 1537MW-11 Aqueous 03/18/2016 008 03/16/2016 1557MW-12 Aqueous 03/18/2016 009 03/16/2016 1610MW-15 Aqueous 03/18/2016 010 03/17/2016 0755MW-16 Aqueous 03/18/2016 011 03/16/2016 1815MW-16D Aqueous 03/18/2016 012 03/16/2016 1654MW-17 Aqueous 03/18/2016 013 03/16/2016 1918MW-18 Aqueous 03/18/2016 014 03/17/2016 1135MW-19 Aqueous 03/18/2016 015 03/17/2016 1130MW-19D Aqueous 03/18/2016 016 03/17/2016 1830MW-20 Aqueous 03/18/2016 017 03/18/2016 0840MW-20D Aqueous 03/18/2016 018 03/17/2016 1725MW-21 Aqueous 03/18/2016 019 03/16/2016 1936MW-22 Aqueous 03/18/2016 020 03/17/2016 1800MW-23 Aqueous 03/18/2016 021 03/17/2016 1244MW-23D Aqueous 03/18/2016 022 03/17/2016 1605MW-24 Aqueous 03/18/2016 023 03/16/2016 1525MW-25 Aqueous 03/18/2016 024 03/17/2016 1710US-1 Aqueous 03/18/2016 025 03/17/2016 1430DS-1 Aqueous 03/18/2016 026 03/17/2016 1100DS-2 Aqueous 03/18/2016 027 03/16/2016 1834DS-3 Aqueous 03/18/2016 028 03/16/2016 1935FIELD BLANK Aqueous 03/18/2016 029 03/17/2016 1730FIELD BLANK Aqueous 03/18/2016 030 03/18/2016 0845FIELD BLANK Aqueous 03/18/2016 031 03/18/2016TRIP BLANK Aqueous 03/18/2016 (31 samples) Page: 3 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Haywood County Lot Number: RC18024 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 MW-5 Aqueous Benzene 8260B 1.5 ug/L 6 001 MW-5 Aqueous 1,1-Dichloroethane 8260B 4.7 ug/L 7 001 MW-5 Aqueous cis-1,2-Dichloroethene 8260B 2.8 ug/L 7 001 MW-5 Aqueous Tetrachloroethene 8260B 3.3 ug/L 7 001 MW-5 Aqueous Trichloroethene 8260B 1.7 ug/L 7 001 MW-5 Aqueous Barium 6010C 0.19 mg/L 8 002 MW-6 Aqueous Zinc 6010C 0.050 mg/L 11 003 MW-7 Aqueous Chlorobenzene 8260B 1.4 ug/L 12 003 MW-7 Aqueous 1,2-Dichlorobenzene 8260B 3.0 ug/L 13 003 MW-7 Aqueous 1,4-Dichlorobenzene 8260B 2.4 ug/L 13 003 MW-7 Aqueous 1,1-Dichloroethane 8260B 2.8 ug/L 13 003 MW-7 Aqueous 1,2-Dichloroethane 8260B 1.8 ug/L 13 003 MW-7 Aqueous cis-1,2-Dichloroethene 8260B 1.9 ug/L 13 003 MW-7 Aqueous Barium 6010C 0.26 mg/L 14 004 MW-8 Aqueous Barium 6010C 0.025 mg/L 18 005 MW-9 Aqueous 1,1-Dichloroethane 8260B 1.6 ug/L 20 005 MW-9 Aqueous cis-1,2-Dichloroethene 8260B 1.7 ug/L 20 005 MW-9 Aqueous Barium 6010C 0.069 mg/L 21 006 MW-10 Aqueous 1,1-Dichloroethane 8260B 1.8 ug/L 24 006 MW-10 Aqueous cis-1,2-Dichloroethene 8260B 1.8 ug/L 24 006 MW-10 Aqueous Barium 6010C 0.072 mg/L 25 007 MW-11 Aqueous 1,2-Dichlorobenzene 8260B 3.6 ug/L 27 007 MW-11 Aqueous 1,4-Dichlorobenzene 8260B 1.1 ug/L 27 007 MW-11 Aqueous 1,1-Dichloroethane 8260B 6.8 ug/L 27 007 MW-11 Aqueous cis-1,2-Dichloroethene 8260B 16 ug/L 27 007 MW-11 Aqueous Trichloroethene 8260B 1.1 ug/L 27 007 MW-11 Aqueous Barium 6010C 0.054 mg/L 28 008 MW-12 Aqueous Barium 6010C 0.16 mg/L 32 009 MW-15 Aqueous 1,2-Dichlorobenzene 8260B 8.9 ug/L 34 009 MW-15 Aqueous 1,4-Dichlorobenzene 8260B 1.4 ug/L 34 009 MW-15 Aqueous cis-1,2-Dichloroethene 8260B 4.4 ug/L 34 009 MW-15 Aqueous Barium 6010C 0.038 mg/L 35 010 MW-16 Aqueous Barium 6010C 0.15 mg/L 38 010 MW-16 Aqueous Zinc 6010C 0.026 mg/L 38 011 MW-16D Aqueous 1,1-Dichloroethane 8260B 1.5 ug/L 40 011 MW-16D Aqueous Barium 6010C 0.040 mg/L 41 011 MW-16D Aqueous Chromium 6010C 0.015 mg/L 41 011 MW-16D Aqueous Zinc 6010C 0.026 mg/L 41 012 MW-17 Aqueous Barium 6010C 0.17 mg/L 44 012 MW-17 Aqueous Chromium 6010C 0.025 mg/L 44 012 MW-17 Aqueous Copper 6010C 0.012 mg/L 44 012 MW-17 Aqueous Zinc 6010C 0.022 mg/L 44 013 MW-18 Aqueous Barium 6010C 0.081 mg/L 47 014 MW-19 Aqueous 1,1-Dichloroethane 8260B 2.2 ug/L 49 014 MW-19 Aqueous 1,2-Dichloroethane 8260B 1.3 ug/L 49 Page: 4 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Executive Summary (Continued) Lot Number: RC18024 Sample Sample ID Matrix Parameter Method Result Q Units Page 014 MW-19 Aqueous Barium 6010C 0.11 mg/L 50 014 MW-19 Aqueous Zinc 6010C 0.072 mg/L 51 015 MW-19D Aqueous Barium 6010C 0.29 mg/L 54 015 MW-19D Aqueous Zinc 6010C 0.045 mg/L 55 016 MW-20 Aqueous 1,1-Dichloroethane 8260B 1.1 ug/L 57 016 MW-20 Aqueous Barium 6010C 0.025 mg/L 58 017 MW-20D Aqueous 1,1-Dichloroethane 8260B 1.4 ug/L 60 017 MW-20D Aqueous cis-1,2-Dichloroethene 8260B 1.0 ug/L 60 017 MW-20D Aqueous Barium 6010C 0.088 mg/L 61 017 MW-20D Aqueous Zinc 6010C 0.034 mg/L 61 018 MW-21 Aqueous Barium 6010C 0.043 mg/L 64 019 MW-22 Aqueous Barium 6010C 0.069 mg/L 67 020 MW-23 Aqueous Barium 6010C 0.097 mg/L 70 021 MW-23D Aqueous Barium 6010C 0.068 mg/L 73 022 MW-24 Aqueous Barium 6010C 0.033 mg/L 76 023 MW-25 Aqueous Benzene 8260B 1.7 ug/L 77 023 MW-25 Aqueous 1,4-Dichlorobenzene 8260B 1.4 ug/L 77 023 MW-25 Aqueous 1,1-Dichloroethane 8260B 11 ug/L 78 023 MW-25 Aqueous cis-1,2-Dichloroethene 8260B 8.0 ug/L 78 023 MW-25 Aqueous Tetrachloroethene 8260B 1.5 ug/L 78 023 MW-25 Aqueous Trichloroethene 8260B 1.7 ug/L 78 023 MW-25 Aqueous Barium 6010C 0.032 mg/L 79 023 MW-25 Aqueous Zinc 6010C 0.047 mg/L 80 024 US-1 Aqueous Barium 6010C 0.035 mg/L 83 025 DS-1 Aqueous Barium 6010C 0.036 mg/L 87 026 DS-2 Aqueous Barium 6010C 0.044 mg/L 91 027 DS-3 Aqueous Barium 6010C 0.041 mg/L 95 (72 detections) Page: 5 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-5 RC18024-001 03/17/2016 0905 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/17/2016 0905 CAE 1 (Specific Con) 120.1 1 03/17/2016 0905 CAE 1 (Temperature ) SM 2550B-2000 1 03/17/2016 0905 CAE 1 (Turbidity - ) 180.1 1 03/17/2016 0905 CAE 1 10-204-00-1-X (Cyanide - To) SM 4500-CN E-1 03/22/2016 2054 MJI 03/22/2016 1435 99062 AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 5.64 1su Specific Conductance - Field 120.1 179 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 12.1 1° C Turbidity - Field 180.1 33 1NTU1.0 Cyanide - Total 57-12-5 SM 4500-CN ND 1mg/L0.010 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1155 RAG 99005 2 5030B 8260B 5 03/24/2016 0437 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B 1.5 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 6 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-5 RC18024-001 03/17/2016 0905 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1155 RAG 99005 2 5030B 8260B 5 03/24/2016 0437 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B 4.7 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B 2.8 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 2ug/L250 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B 3.3 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B 1.7 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 7 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-5 RC18024-001 03/17/2016 0905 03/18/2016 Aqueous AcceptanceAcceptanceRun 2Run 1 Surrogate Q % Recovery Limits % Recovery LimitsQ 1,2-Dichloroethane-d4 95 70-130 111 70-130 Bromofluorobenzene 110 70-130 108 70-130 Toluene-d8 108 70-130 102 70-130 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 1843 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.19 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C ND 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 8 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-6 RC18024-002 03/17/2016 1900 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/17/2016 0941 CAE 1 (Specific Con) 120.1 1 03/17/2016 0941 CAE 1 (Temperature ) SM 2550B-2000 1 03/17/2016 0941 CAE 1 (Turbidity - ) 180.1 1 03/17/2016 0941 CAE 1 10-204-00-1-X (Cyanide - To) SM 4500-CN E-1 03/22/2016 2059 MJI 03/22/2016 1435 99062 AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 5.45 1su Specific Conductance - Field 120.1 71.8 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 10.8 1° C Turbidity - Field 180.1 1000 1NTU1.0 Cyanide - Total 57-12-5 SM 4500-CN ND 1mg/L0.010 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1218 RAG 99005 2 5030B 8260B 5 03/24/2016 0501 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 9 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-6 RC18024-002 03/17/2016 1900 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1218 RAG 99005 2 5030B 8260B 5 03/24/2016 0501 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 2ug/L250 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 10 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-6 RC18024-002 03/17/2016 1900 03/18/2016 Aqueous AcceptanceAcceptanceRun 2Run 1 Surrogate Q % Recovery Limits % Recovery LimitsQ 1,2-Dichloroethane-d4 97 70-130 108 70-130 Bromofluorobenzene 109 70-130 107 70-130 Toluene-d8 108 70-130 100 70-130 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 1914 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C ND 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C 0.050 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 11 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-7 RC18024-003 03/17/2016 1742 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/17/2016 1010 CAE 1 (Specific Con) 120.1 1 03/17/2016 1010 CAE 1 (Temperature ) SM 2550B-2000 1 03/17/2016 1010 CAE 1 (Turbidity - ) 180.1 1 03/17/2016 1010 CAE 1 10-204-00-1-X (Cyanide - To) SM 4500-CN E-1 03/22/2016 2059 MJI 03/22/2016 1435 99062 AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 5.96 1su Specific Conductance - Field 120.1 359 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 13.2 1° C Turbidity - Field 180.1 1000 1NTU1.0 Cyanide - Total 57-12-5 SM 4500-CN ND 1mg/L0.010 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1241 RAG 99005 2 5030B 8260B 5 03/24/2016 0523 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B 1.4 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 12 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-7 RC18024-003 03/17/2016 1742 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1241 RAG 99005 2 5030B 8260B 5 03/24/2016 0523 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,2-Dichlorobenzene 95-50-1 8260B 3.0 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 1,4-Dichlorobenzene 106-46-7 8260B 2.4 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B 2.8 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B 1.8 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B 1.9 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 2ug/L250 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 13 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-7 RC18024-003 03/17/2016 1742 03/18/2016 Aqueous AcceptanceAcceptanceRun 2Run 1 Surrogate Q % Recovery Limits % Recovery LimitsQ 1,2-Dichloroethane-d4 95 70-130 111 70-130 Bromofluorobenzene 110 70-130 107 70-130 Toluene-d8 106 70-130 99 70-130 Organochlorine Pesticides by GC Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3520C 8081B 10 03/24/2016 1048 PMS 03/22/2016 1630 99070 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Aldrin 309-00-2 8081B ND 1ug/L0.40 gamma-BHC (Lindane)58-89-9 8081B ND 1ug/L0.40 alpha-BHC 319-84-6 8081B ND 1ug/L0.40 beta-BHC 319-85-7 8081B ND 1ug/L0.40 delta-BHC 319-86-8 8081B ND 1ug/L0.40 Chlordane 57-74-9 8081B ND 1ug/L4.0 4,4'-DDD 72-54-8 8081B ND 1ug/L0.40 4,4'-DDE 72-55-9 8081B ND 1ug/L0.40 4,4'-DDT 50-29-3 8081B ND 1ug/L0.40 Dieldrin 60-57-1 8081B ND 1ug/L0.40 Endosulfan I 959-98-8 8081B ND 1ug/L0.40 Endosulfan II 33213-65-9 8081B ND 1ug/L0.40 Endosulfan sulfate 1031-07-8 8081B ND 1ug/L0.40 Endrin 72-20-8 8081B ND 1ug/L0.40 Endrin aldehyde 7421-93-4 8081B ND 1ug/L0.40 Heptachlor 76-44-8 8081B ND 1ug/L0.40 Heptachlor epoxide 1024-57-3 8081B ND 1ug/L0.40 Methoxychlor 72-43-5 8081B ND 1ug/L1.6 Toxaphene 8001-35-2 8081B ND 1ug/L4.0 AcceptanceRun 1 Surrogate Q % Recovery Limits Decachlorobiphenyl 60 10-122 Tetrachloro-m-xylene 116 46-119 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 1918 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.26 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 14 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-7 RC18024-003 03/17/2016 1742 03/18/2016 Aqueous ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 1918 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C ND 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 15 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-8 RC18024-004 03/17/2016 1850 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/17/2016 1625 CAE 1 (Specific Con) 120.1 1 03/17/2016 1625 CAE 1 (Temperature ) SM 2550B-2000 1 03/17/2016 1625 CAE 1 (Turbidity - ) 180.1 1 03/17/2016 1625 CAE 1 10-204-00-1-X (Cyanide - To) SM 4500-CN E-1 03/22/2016 2059 MJI 03/22/2016 1435 99062 AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 5.95 1su Specific Conductance - Field 120.1 191 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 11.8 1° C Turbidity - Field 180.1 180 1NTU1.0 Cyanide - Total 57-12-5 SM 4500-CN ND 1mg/L0.010 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1304 RAG 99005 2 5030B 8260B 5 03/24/2016 0546 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 16 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-8 RC18024-004 03/17/2016 1850 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1304 RAG 99005 2 5030B 8260B 5 03/24/2016 0546 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 2ug/L250 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 17 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-8 RC18024-004 03/17/2016 1850 03/18/2016 Aqueous AcceptanceAcceptanceRun 2Run 1 Surrogate Q % Recovery Limits % Recovery LimitsQ 1,2-Dichloroethane-d4 97 70-130 111 70-130 Bromofluorobenzene 109 70-130 108 70-130 Toluene-d8 106 70-130 101 70-130 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 1922 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.025 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C ND 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 18 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-9 RC18024-005 03/17/2016 1815 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/17/2016 1330 CAE 1 (Specific Con) 120.1 1 03/17/2016 1330 CAE 1 (Temperature ) SM 2550B-2000 1 03/17/2016 1330 CAE 1 (Turbidity - ) 180.1 1 03/17/2016 1330 CAE AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 5.7 1su Specific Conductance - Field 120.1 114 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 11.6 1° C Turbidity - Field 180.1 420 1NTU1.0 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1327 RAG 99005 2 5030B 8260B 5 03/24/2016 0610 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 19 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-9 RC18024-005 03/17/2016 1815 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1327 RAG 99005 2 5030B 8260B 5 03/24/2016 0610 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B 1.6 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B 1.7 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 2ug/L250 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 20 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-9 RC18024-005 03/17/2016 1815 03/18/2016 Aqueous AcceptanceAcceptanceRun 2Run 1 Surrogate Q % Recovery Limits % Recovery LimitsQ 1,2-Dichloroethane-d4 98 70-130 110 70-130 Bromofluorobenzene 110 70-130 109 70-130 Toluene-d8 108 70-130 103 70-130 Organochlorine Pesticides by GC Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3520C 8081B 1 03/24/2016 1103 PMS 03/22/2016 1630 99070 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Aldrin 309-00-2 8081B ND 1ug/L0.040 gamma-BHC (Lindane)58-89-9 8081B ND 1ug/L0.040 alpha-BHC 319-84-6 8081B ND 1ug/L0.040 beta-BHC 319-85-7 8081B ND 1ug/L0.040 delta-BHC 319-86-8 8081B ND 1ug/L0.040 Chlordane 57-74-9 8081B ND 1ug/L0.40 4,4'-DDD 72-54-8 8081B ND 1ug/L0.040 4,4'-DDE 72-55-9 8081B ND 1ug/L0.040 4,4'-DDT 50-29-3 8081B ND 1ug/L0.040 Dieldrin 60-57-1 8081B ND 1ug/L0.040 Endosulfan I 959-98-8 8081B ND 1ug/L0.040 Endosulfan II 33213-65-9 8081B ND 1ug/L0.040 Endosulfan sulfate 1031-07-8 8081B ND 1ug/L0.040 Endrin 72-20-8 8081B ND 1ug/L0.040 Endrin aldehyde 7421-93-4 8081B ND 1ug/L0.040 Heptachlor 76-44-8 8081B ND 1ug/L0.040 Heptachlor epoxide 1024-57-3 8081B ND 1ug/L0.040 Methoxychlor 72-43-5 8081B ND 1ug/L0.16 Toxaphene 8001-35-2 8081B ND 1ug/L0.40 AcceptanceRun 1 Surrogate Q % Recovery Limits Decachlorobiphenyl 71 10-122 Tetrachloro-m-xylene 83 46-119 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 1927 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.069 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 21 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-9 RC18024-005 03/17/2016 1815 03/18/2016 Aqueous ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 1927 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C ND 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 22 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-10 RC18024-006 03/17/2016 1842 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/16/2016 1525 CAE 1 (Specific Con) 120.1 1 03/17/2016 1525 CAE 1 (Temperature ) SM 2550B-2000 1 03/17/2016 1525 CAE 1 (Turbidity - ) 180.1 1 03/17/2016 1525 CAE AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 5.37 1su Specific Conductance - Field 120.1 61.2 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 11.6 1° C Turbidity - Field 180.1 890 1NTU1.0 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1350 RAG 99005 2 5030B 8260B 1 03/24/2016 0112 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 23 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-10 RC18024-006 03/17/2016 1842 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1350 RAG 99005 2 5030B 8260B 1 03/24/2016 0112 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B 1.8 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B 1.8 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 2ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 24 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-10 RC18024-006 03/17/2016 1842 03/18/2016 Aqueous AcceptanceAcceptanceRun 2Run 1 Surrogate Q % Recovery Limits % Recovery LimitsQ 1,2-Dichloroethane-d4 98 70-130 107 70-130 Bromofluorobenzene 111 70-130 108 70-130 Toluene-d8 108 70-130 101 70-130 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 1931 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.072 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C ND 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 25 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-11 RC18024-007 03/16/2016 1537 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/16/2016 1505 CAE 1 (Specific Con) 120.1 1 03/16/2016 1505 CAE 1 (Temperature ) SM 2550B-2000 1 03/16/2016 1505 CAE 1 (Turbidity - ) 180.1 1 03/16/2016 1505 CAE 1 10-204-00-1-X (Cyanide - To) SM 4500-CN E-1 03/22/2016 2059 MJI 03/22/2016 1435 99062 AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 6.85 1su Specific Conductance - Field 120.1 450 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 16.8 1° C Turbidity - Field 180.1 15 1NTU1.0 Cyanide - Total 57-12-5 SM 4500-CN ND 1mg/L0.010 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1413 RAG 99005 2 5030B 8260B 1 03/24/2016 0135 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 26 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-11 RC18024-007 03/16/2016 1537 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1413 RAG 99005 2 5030B 8260B 1 03/24/2016 0135 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,2-Dichlorobenzene 95-50-1 8260B 3.6 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 1,4-Dichlorobenzene 106-46-7 8260B 1.1 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B 6.8 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B 16 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 2ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B 1.1 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 27 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-11 RC18024-007 03/16/2016 1537 03/18/2016 Aqueous AcceptanceAcceptanceRun 2Run 1 Surrogate Q % Recovery Limits % Recovery LimitsQ 1,2-Dichloroethane-d4 96 70-130 110 70-130 Bromofluorobenzene 111 70-130 108 70-130 Toluene-d8 105 70-130 102 70-130 Organochlorine Pesticides by GC Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3520C 8081B 10 03/24/2016 1147 PMS 03/22/2016 1630 99070 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Aldrin 309-00-2 8081B ND 1ug/L0.40 gamma-BHC (Lindane)58-89-9 8081B ND 1ug/L0.40 alpha-BHC 319-84-6 8081B ND 1ug/L0.40 beta-BHC 319-85-7 8081B ND 1ug/L0.40 delta-BHC 319-86-8 8081B ND 1ug/L0.40 Chlordane 57-74-9 8081B ND 1ug/L4.0 4,4'-DDD 72-54-8 8081B ND 1ug/L0.40 4,4'-DDE 72-55-9 8081B ND 1ug/L0.40 4,4'-DDT 50-29-3 8081B ND 1ug/L0.40 Dieldrin 60-57-1 8081B ND 1ug/L0.40 Endosulfan I 959-98-8 8081B ND 1ug/L0.40 Endosulfan II 33213-65-9 8081B ND 1ug/L0.40 Endosulfan sulfate 1031-07-8 8081B ND 1ug/L0.40 Endrin 72-20-8 8081B ND 1ug/L0.40 Endrin aldehyde 7421-93-4 8081B ND 1ug/L0.40 Heptachlor 76-44-8 8081B ND 1ug/L0.40 Heptachlor epoxide 1024-57-3 8081B ND 1ug/L0.40 Methoxychlor 72-43-5 8081B ND 1ug/L1.6 Toxaphene 8001-35-2 8081B ND 1ug/L4.0 AcceptanceRun 1 Surrogate Q % Recovery Limits Decachlorobiphenyl 48 10-122 Tetrachloro-m-xylene 100 46-119 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 1936 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.054 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 28 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-11 RC18024-007 03/16/2016 1537 03/18/2016 Aqueous ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 1936 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C ND 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 29 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-12 RC18024-008 03/16/2016 1557 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/16/2016 1320 CAE 1 (Specific Con) 120.1 1 03/16/2016 1320 CAE 1 (Temperature ) SM 2550B-2000 1 03/16/2016 1320 CAE 1 (Turbidity - ) 180.1 1 03/16/2016 1320 CAE AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 6.43 1su Specific Conductance - Field 120.1 85.6 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 13.3 1° C Turbidity - Field 180.1 130 1NTU1.0 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1436 RAG 99005 2 5030B 8260B 1 03/24/2016 0157 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 30 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-12 RC18024-008 03/16/2016 1557 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1436 RAG 99005 2 5030B 8260B 1 03/24/2016 0157 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 2ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 31 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-12 RC18024-008 03/16/2016 1557 03/18/2016 Aqueous AcceptanceAcceptanceRun 2Run 1 Surrogate Q % Recovery Limits % Recovery LimitsQ 1,2-Dichloroethane-d4 100 70-130 112 70-130 Bromofluorobenzene 111 70-130 108 70-130 Toluene-d8 105 70-130 101 70-130 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 1940 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.16 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C ND 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 32 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-15 RC18024-009 03/16/2016 1610 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/16/2016 1120 CAE 1 (Specific Con) 120.1 1 03/16/2016 1120 CAE 1 (Temperature ) SM 2550B-2000 1 03/16/2016 1120 CAE 1 (Turbidity - ) 180.1 1 03/16/2016 1120 CAE 1 10-204-00-1-X (Cyanide - To) SM 4500-CN E-1 03/22/2016 2140 MJI 03/22/2016 1435 99062 AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 7.77 1su Specific Conductance - Field 120.1 553 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 14.8 1° C Turbidity - Field 180.1 110 1NTU1.0 Cyanide - Total 57-12-5 SM 4500-CN ND 1mg/L0.010 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1459 RAG 99005 2 5030B 8260B 1 03/24/2016 0220 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 33 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-15 RC18024-009 03/16/2016 1610 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1459 RAG 99005 2 5030B 8260B 1 03/24/2016 0220 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,2-Dichlorobenzene 95-50-1 8260B 8.9 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 1,4-Dichlorobenzene 106-46-7 8260B 1.4 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B 4.4 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 2ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 34 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-15 RC18024-009 03/16/2016 1610 03/18/2016 Aqueous AcceptanceAcceptanceRun 2Run 1 Surrogate Q % Recovery Limits % Recovery LimitsQ 1,2-Dichloroethane-d4 96 70-130 111 70-130 Bromofluorobenzene 106 70-130 107 70-130 Toluene-d8 105 70-130 102 70-130 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 1944 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.038 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C ND 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 35 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-16 RC18024-010 03/17/2016 0755 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/16/2016 1753 CAE 1 (Specific Con) 120.1 1 03/16/2016 1753 CAE 1 (Temperature ) SM 2550B-2000 1 03/16/2016 1753 CAE 1 (Turbidity - ) 180.1 1 03/16/2016 1753 CAE AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 6.5 1su Specific Conductance - Field 120.1 103 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 14.9 1° C Turbidity - Field 180.1 1000 1NTU1.0 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1522 RAG 99005 2 5030B 8260B 1 03/24/2016 0243 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 36 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-16 RC18024-010 03/17/2016 0755 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1522 RAG 99005 2 5030B 8260B 1 03/24/2016 0243 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 2ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 37 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-16 RC18024-010 03/17/2016 0755 03/18/2016 Aqueous AcceptanceAcceptanceRun 2Run 1 Surrogate Q % Recovery Limits % Recovery LimitsQ 1,2-Dichloroethane-d4 98 70-130 109 70-130 Bromofluorobenzene 107 70-130 109 70-130 Toluene-d8 108 70-130 102 70-130 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 1949 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.15 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C 0.026 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 38 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-16D RC18024-011 03/16/2016 1815 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/16/2016 1755 CAE 1 (Specific Con) 120.1 1 03/16/2016 1755 CAE 1 (Temperature ) SM 2550B-2000 1 03/16/2016 1755 CAE 1 (Turbidity - ) 180.1 1 03/16/2016 1755 CAE AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 7.22 1su Specific Conductance - Field 120.1 203 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 18.5 1° C Turbidity - Field 180.1 13 1NTU1.0 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1545 RAG 99005 2 5030B 8260B 1 03/24/2016 0306 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 39 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-16D RC18024-011 03/16/2016 1815 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1545 RAG 99005 2 5030B 8260B 1 03/24/2016 0306 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B 1.5 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 2ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 40 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-16D RC18024-011 03/16/2016 1815 03/18/2016 Aqueous AcceptanceAcceptanceRun 2Run 1 Surrogate Q % Recovery Limits % Recovery LimitsQ 1,2-Dichloroethane-d4 97 70-130 109 70-130 Bromofluorobenzene 108 70-130 109 70-130 Toluene-d8 107 70-130 101 70-130 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 2002 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.040 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C 0.015 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C 0.026 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 41 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-17 RC18024-012 03/16/2016 1654 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/16/2016 1654 CAE 1 (Specific Con) 120.1 1 03/16/2016 1654 CAE 1 (Temperature ) SM 2550B-2000 1 03/16/2016 1654 CAE 1 (Turbidity - ) 180.1 1 03/16/2016 1654 CAE AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 6.00 1su Specific Conductance - Field 120.1 92.6 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 13.5 1° C Turbidity - Field 180.1 81 1NTU1.0 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1608 RAG 99005 2 5030B 8260B 1 03/24/2016 0329 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 42 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-17 RC18024-012 03/16/2016 1654 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1608 RAG 99005 2 5030B 8260B 1 03/24/2016 0329 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 2ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 43 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-17 RC18024-012 03/16/2016 1654 03/18/2016 Aqueous AcceptanceAcceptanceRun 2Run 1 Surrogate Q % Recovery Limits % Recovery LimitsQ 1,2-Dichloroethane-d4 98 70-130 111 70-130 Bromofluorobenzene 110 70-130 105 70-130 Toluene-d8 106 70-130 98 70-130 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 2006 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.17 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C 0.025 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C 0.012 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C 0.022 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 44 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-18 RC18024-013 03/16/2016 1918 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/16/2016 1918 CAE 1 (Specific Con) 120.1 1 03/16/2016 1918 CAE 1 (Temperature ) SM 2550B-2000 1 03/16/2016 1918 CAE 1 (Turbidity - ) 180.1 1 03/16/2016 1918 CAE AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 5.7 1su Specific Conductance - Field 120.1 60.8 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 13.3 1° C Turbidity - Field 180.1 9.4 1NTU1.0 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1631 RAG 99005 2 5030B 8260B 1 03/24/2016 0352 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 45 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-18 RC18024-013 03/16/2016 1918 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1631 RAG 99005 2 5030B 8260B 1 03/24/2016 0352 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 2ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 46 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-18 RC18024-013 03/16/2016 1918 03/18/2016 Aqueous AcceptanceAcceptanceRun 2Run 1 Surrogate Q % Recovery Limits % Recovery LimitsQ 1,2-Dichloroethane-d4 97 70-130 109 70-130 Bromofluorobenzene 108 70-130 105 70-130 Toluene-d8 107 70-130 99 70-130 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 2011 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.081 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C ND 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 47 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-19 RC18024-014 03/17/2016 1135 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/16/2016 1040 CAE 1 (Specific Con) 120.1 1 03/16/2016 1040 CAE 1 (Temperature ) SM 2550B-2000 1 03/16/2016 1040 CAE 1 (Turbidity - ) 180.1 1 03/16/2016 1040 CAE AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 5.76 1su Specific Conductance - Field 120.1 184 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 12.1 1° C Turbidity - Field 180.1 980 1NTU1.0 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1654 RAG 99005 2 5030B 8260B 1 03/24/2016 0415 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 48 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-19 RC18024-014 03/17/2016 1135 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/22/2016 1654 RAG 99005 2 5030B 8260B 1 03/24/2016 0415 ECP 99192 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B 2.2 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B 1.3 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 2ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 49 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-19 RC18024-014 03/17/2016 1135 03/18/2016 Aqueous AcceptanceAcceptanceRun 2Run 1 Surrogate Q % Recovery Limits % Recovery LimitsQ 1,2-Dichloroethane-d4 94 70-130 108 70-130 Bromofluorobenzene 106 70-130 108 70-130 Toluene-d8 102 70-130 102 70-130 Organochlorine Pesticides by GC Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3520C 8081B 10 03/24/2016 1202 PMS 03/22/2016 1630 99070 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Aldrin 309-00-2 8081B ND 1ug/L0.40 gamma-BHC (Lindane)58-89-9 8081B ND 1ug/L0.40 alpha-BHC 319-84-6 8081B ND 1ug/L0.40 beta-BHC 319-85-7 8081B ND 1ug/L0.40 delta-BHC 319-86-8 8081B ND 1ug/L0.40 Chlordane 57-74-9 8081B ND 1ug/L4.0 4,4'-DDD 72-54-8 8081B ND 1ug/L0.40 4,4'-DDE 72-55-9 8081B ND 1ug/L0.40 4,4'-DDT 50-29-3 8081B ND 1ug/L0.40 Dieldrin 60-57-1 8081B ND 1ug/L0.40 Endosulfan I 959-98-8 8081B ND 1ug/L0.40 Endosulfan II 33213-65-9 8081B ND 1ug/L0.40 Endosulfan sulfate 1031-07-8 8081B ND 1ug/L0.40 Endrin 72-20-8 8081B ND 1ug/L0.40 Endrin aldehyde 7421-93-4 8081B ND 1ug/L0.40 Heptachlor 76-44-8 8081B ND 1ug/L0.40 Heptachlor epoxide 1024-57-3 8081B ND 1ug/L0.40 Methoxychlor 72-43-5 8081B ND 1ug/L1.6 Toxaphene 8001-35-2 8081B ND 1ug/L4.0 AcceptanceRun 1 Surrogate Q % Recovery Limits Decachlorobiphenyl 75 10-122 Tetrachloro-m-xylene 103 46-119 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 2015 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.11 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 50 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-19 RC18024-014 03/17/2016 1135 03/18/2016 Aqueous ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 2015 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C 0.072 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 51 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-19D RC18024-015 03/17/2016 1130 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/17/2016 1124 CAE 1 (Specific Con) 120.1 1 03/17/2016 1124 CAE 1 (Temperature ) SM 2550B-2000 1 03/17/2016 1124 CAE 1 (Turbidity - ) 180.1 1 03/17/2016 1124 CAE AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 6.15 1su Specific Conductance - Field 120.1 550 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 14.4 1° C Turbidity - Field 180.1 4.6 1NTU1.0 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/23/2016 2255 ECP 99192 2 5030B 8260B 1 03/25/2016 1522 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 2ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 52 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-19D RC18024-015 03/17/2016 1130 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/23/2016 2255 ECP 99192 2 5030B 8260B 1 03/25/2016 1522 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 1ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 53 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-19D RC18024-015 03/17/2016 1130 03/18/2016 Aqueous AcceptanceAcceptanceRun 2Run 1 Surrogate Q % Recovery Limits % Recovery LimitsQ 1,2-Dichloroethane-d4 109 70-130 111 70-130 Bromofluorobenzene 106 70-130 117 70-130 Toluene-d8 100 70-130 110 70-130 Organochlorine Pesticides by GC Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3520C 8081B 10 03/24/2016 1217 PMS 03/22/2016 1630 99070 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Aldrin 309-00-2 8081B ND 1ug/L0.40 gamma-BHC (Lindane)58-89-9 8081B ND 1ug/L0.40 alpha-BHC 319-84-6 8081B ND 1ug/L0.40 beta-BHC 319-85-7 8081B ND 1ug/L0.40 delta-BHC 319-86-8 8081B ND 1ug/L0.40 Chlordane 57-74-9 8081B ND 1ug/L4.0 4,4'-DDD 72-54-8 8081B ND 1ug/L0.40 4,4'-DDE 72-55-9 8081B ND 1ug/L0.40 4,4'-DDT 50-29-3 8081B ND 1ug/L0.40 Dieldrin 60-57-1 8081B ND 1ug/L0.40 Endosulfan I 959-98-8 8081B ND 1ug/L0.40 Endosulfan II 33213-65-9 8081B ND 1ug/L0.40 Endosulfan sulfate 1031-07-8 8081B ND 1ug/L0.40 Endrin 72-20-8 8081B ND 1ug/L0.40 Endrin aldehyde 7421-93-4 8081B ND 1ug/L0.40 Heptachlor 76-44-8 8081B ND 1ug/L0.40 Heptachlor epoxide 1024-57-3 8081B ND 1ug/L0.40 Methoxychlor 72-43-5 8081B ND 1ug/L1.6 Toxaphene 8001-35-2 8081B ND 1ug/L4.0 AcceptanceRun 1 Surrogate Q % Recovery Limits Decachlorobiphenyl 60 10-122 Tetrachloro-m-xylene 84 46-119 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 2019 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.29 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 54 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-19D RC18024-015 03/17/2016 1130 03/18/2016 Aqueous ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 2019 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C 0.045 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 55 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-20 RC18024-016 03/17/2016 1830 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/17/2016 1417 CAE 1 (Specific Con) 120.1 1 03/17/2016 1417 CAE 1 (Temperature ) SM 2550B-2000 1 03/17/2016 1417 CAE 1 (Turbidity - ) 180.1 1 03/17/2016 1417 CAE AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 6.14 1su Specific Conductance - Field 120.1 64.6 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 14.3 1° C Turbidity - Field 180.1 1000 1NTU1.0 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/23/2016 2318 ECP 99192 2 5030B 8260B 1 03/25/2016 1543 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 2ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 56 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-20 RC18024-016 03/17/2016 1830 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/23/2016 2318 ECP 99192 2 5030B 8260B 1 03/25/2016 1543 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B 1.1 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 1ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 57 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-20 RC18024-016 03/17/2016 1830 03/18/2016 Aqueous AcceptanceAcceptanceRun 2Run 1 Surrogate Q % Recovery Limits % Recovery LimitsQ 1,2-Dichloroethane-d4 110 70-130 113 70-130 Bromofluorobenzene 108 70-130 117 70-130 Toluene-d8 101 70-130 112 70-130 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 2024 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.025 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C ND 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 58 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-20D RC18024-017 03/18/2016 0840 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/17/2016 1441 CAE 1 (Specific Con) 120.1 1 03/17/2016 1441 CAE 1 (Temperature ) SM 2550B-2000 1 03/17/2016 1441 CAE 1 (Turbidity - ) 180.1 1 03/17/2016 1441 CAE AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 6.48 1su Specific Conductance - Field 120.1 97.8 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 13.9 1° C Turbidity - Field 180.1 1000 1NTU1.0 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/23/2016 2341 ECP 99192 2 5030B 8260B 1 03/25/2016 1605 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 2ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 59 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-20D RC18024-017 03/18/2016 0840 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/23/2016 2341 ECP 99192 2 5030B 8260B 1 03/25/2016 1605 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B 1.4 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B 1.0 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 1ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 60 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-20D RC18024-017 03/18/2016 0840 03/18/2016 Aqueous AcceptanceAcceptanceRun 2Run 1 Surrogate Q % Recovery Limits % Recovery LimitsQ 1,2-Dichloroethane-d4 109 70-130 106 70-130 Bromofluorobenzene 109 70-130 114 70-130 Toluene-d8 103 70-130 110 70-130 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 2028 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.088 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C 0.034 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 61 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-21 RC18024-018 03/17/2016 1725 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/17/2016 1655 CAE 1 (Specific Con) 120.1 1 03/17/2016 1655 CAE 1 (Temperature ) SM 2550B-2000 1 03/17/2016 1655 CAE 1 (Turbidity - ) 180.1 1 03/17/2016 1655 CAE AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 4.98 1su Specific Conductance - Field 120.1 19.2 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 13.8 1° C Turbidity - Field 180.1 250 1NTU1.0 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/24/2016 0003 ECP 99192 2 5030B 8260B 1 03/25/2016 1627 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 2ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 62 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-21 RC18024-018 03/17/2016 1725 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/24/2016 0003 ECP 99192 2 5030B 8260B 1 03/25/2016 1627 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 1ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 63 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-21 RC18024-018 03/17/2016 1725 03/18/2016 Aqueous AcceptanceAcceptanceRun 2Run 1 Surrogate Q % Recovery Limits % Recovery LimitsQ 1,2-Dichloroethane-d4 111 70-130 100 70-130 Bromofluorobenzene 108 70-130 114 70-130 Toluene-d8 103 70-130 108 70-130 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 2033 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.043 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C ND 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 64 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-22 RC18024-019 03/16/2016 1936 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/16/2016 1222 CAE 1 (Specific Con) 120.1 1 03/16/2016 1222 CAE 1 (Temperature ) SM 2550B-2000 1 03/16/2016 1222 CAE 1 (Turbidity - ) 180.1 1 03/16/2016 1222 CAE AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 5.59 1su Specific Conductance - Field 120.1 66.8 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 12.3 1° C Turbidity - Field 180.1 550 1NTU1.0 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/25/2016 1648 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 65 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-22 RC18024-019 03/16/2016 1936 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/25/2016 1648 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 1ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 66 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-22 RC18024-019 03/16/2016 1936 03/18/2016 Aqueous AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 109 70-130 Bromofluorobenzene 112 70-130 Toluene-d8 108 70-130 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 2037 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.069 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C ND 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 67 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-23 RC18024-020 03/17/2016 1800 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/17/2016 1230 CAE 1 (Specific Con) 120.1 1 03/17/2016 1230 CAE 1 (Temperature ) SM 2550B-2000 1 03/17/2016 1230 CAE 1 (Turbidity - ) 180.1 1 03/17/2016 1230 CAE AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 5.9 1su Specific Conductance - Field 120.1 87.2 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 12.7 1° C Turbidity - Field 180.1 56 1NTU1.0 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/25/2016 1710 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 68 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-23 RC18024-020 03/17/2016 1800 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/25/2016 1710 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 1ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 69 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-23 RC18024-020 03/17/2016 1800 03/18/2016 Aqueous AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 100 70-130 Bromofluorobenzene 110 70-130 Toluene-d8 106 70-130 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/22/2016 2041 NCM 03/19/2016 1211 98843 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.097 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C ND 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 70 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-23D RC18024-021 03/17/2016 1244 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/17/2016 1244 CAE 1 (Specific Con) 120.1 1 03/17/2016 1244 CAE 1 (Temperature ) SM 2550B-2000 1 03/17/2016 1244 CAE 1 (Turbidity - ) 180.1 1 03/17/2016 1244 CAE AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 6.53 1su Specific Conductance - Field 120.1 116 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 15.3 1° C Turbidity - Field 180.1 4.4 1NTU1.0 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/25/2016 1732 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 71 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-23D RC18024-021 03/17/2016 1244 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/25/2016 1732 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 1ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 72 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-23D RC18024-021 03/17/2016 1244 03/18/2016 Aqueous AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 106 70-130 Bromofluorobenzene 117 70-130 Toluene-d8 109 70-130 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/23/2016 1359 NCM 03/21/2016 0923 98884 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.068 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C ND 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 73 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-24 RC18024-022 03/17/2016 1605 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/17/2016 1555 CAE 1 (Specific Con) 120.1 1 03/17/2016 1555 CAE 1 (Temperature ) SM 2550B-2000 1 03/17/2016 1555 CAE 1 (Turbidity - ) 180.1 1 03/17/2016 1555 CAE AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 5.68 1su Specific Conductance - Field 120.1 38.5 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 14.1 1° C Turbidity - Field 180.1 88 1NTU1.0 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/25/2016 1753 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 74 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-24 RC18024-022 03/17/2016 1605 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/25/2016 1753 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 1ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 75 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-24 RC18024-022 03/17/2016 1605 03/18/2016 Aqueous AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 106 70-130 Bromofluorobenzene 114 70-130 Toluene-d8 108 70-130 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/23/2016 1404 NCM 03/21/2016 0923 98884 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.033 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C ND 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 76 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-25 RC18024-023 03/16/2016 1525 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/16/2016 1525 CAE 1 (Specific Con) 120.1 1 03/16/2016 1525 CAE 1 (Temperature ) SM 2550B-2000 1 03/16/2016 1525 CAE 1 (Turbidity - ) 180.1 1 03/16/2016 1525 CAE AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 5.69 1su Specific Conductance - Field 120.1 524 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 16.8 1° C Turbidity - Field 180.1 14 1NTU1.0 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/25/2016 1815 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B 1.7 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 1,4-Dichlorobenzene 106-46-7 8260B 1.4 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 77 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-25 RC18024-023 03/16/2016 1525 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/25/2016 1815 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B 11 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B 8.0 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 1ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B 1.5 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B 1.7 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 78 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-25 RC18024-023 03/16/2016 1525 03/18/2016 Aqueous AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 109 70-130 Bromofluorobenzene 117 70-130 Toluene-d8 111 70-130 Organochlorine Pesticides by GC Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3520C 8081B 10 03/24/2016 1231 PMS 03/22/2016 1630 99070 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Aldrin 309-00-2 8081B ND 1ug/L0.40 gamma-BHC (Lindane)58-89-9 8081B ND 1ug/L0.40 alpha-BHC 319-84-6 8081B ND 1ug/L0.40 beta-BHC 319-85-7 8081B ND 1ug/L0.40 delta-BHC 319-86-8 8081B ND 1ug/L0.40 Chlordane 57-74-9 8081B ND 1ug/L4.0 4,4'-DDD 72-54-8 8081B ND 1ug/L0.40 4,4'-DDE 72-55-9 8081B ND 1ug/L0.40 4,4'-DDT 50-29-3 8081B ND 1ug/L0.40 Dieldrin 60-57-1 8081B ND 1ug/L0.40 Endosulfan I 959-98-8 8081B ND 1ug/L0.40 Endosulfan II 33213-65-9 8081B ND 1ug/L0.40 Endosulfan sulfate 1031-07-8 8081B ND 1ug/L0.40 Endrin 72-20-8 8081B ND 1ug/L0.40 Endrin aldehyde 7421-93-4 8081B ND 1ug/L0.40 Heptachlor 76-44-8 8081B ND 1ug/L0.40 Heptachlor epoxide 1024-57-3 8081B ND 1ug/L0.40 Methoxychlor 72-43-5 8081B ND 1ug/L1.6 Toxaphene 8001-35-2 8081B ND 1ug/L4.0 AcceptanceRun 1 Surrogate Q % Recovery Limits Decachlorobiphenyl 82 10-122 Tetrachloro-m-xylene 114 46-119 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/23/2016 1408 NCM 03/21/2016 0923 98884 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.032 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 79 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County MW-25 RC18024-023 03/16/2016 1525 03/18/2016 Aqueous ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/23/2016 1408 NCM 03/21/2016 0923 98884 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C 0.047 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 80 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County US-1 RC18024-024 03/17/2016 1710 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/17/2016 1710 CAE 1 (Specific Con) 120.1 1 03/17/2016 1710 CAE 1 (Temperature ) SM 2550B-2000 1 03/17/2016 1710 CAE 1 (Turbidity - ) 180.1 1 03/17/2016 1710 CAE 1 10-204-00-1-X (Cyanide - To) SM 4500-CN E-1 03/24/2016 2141 MJI 03/24/2016 1856 99272 AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 6.32 1su Specific Conductance - Field 120.1 68.3 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 15.0 1° C Turbidity - Field 180.1 7.8 1NTU1.0 Cyanide - Total 57-12-5 SM 4500-CN ND 1mg/L0.010 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/25/2016 1837 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 81 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County US-1 RC18024-024 03/17/2016 1710 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/25/2016 1837 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 1ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 82 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County US-1 RC18024-024 03/17/2016 1710 03/18/2016 Aqueous AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 105 70-130 Bromofluorobenzene 111 70-130 Toluene-d8 107 70-130 Organochlorine Pesticides by GC Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3520C 8081B 1 03/24/2016 1246 PMS 03/22/2016 1630 99070 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Aldrin 309-00-2 8081B ND 1ug/L0.040 gamma-BHC (Lindane)58-89-9 8081B ND 1ug/L0.040 alpha-BHC 319-84-6 8081B ND 1ug/L0.040 beta-BHC 319-85-7 8081B ND 1ug/L0.040 delta-BHC 319-86-8 8081B ND 1ug/L0.040 Chlordane 57-74-9 8081B ND 1ug/L0.40 4,4'-DDD 72-54-8 8081B ND 1ug/L0.040 4,4'-DDE 72-55-9 8081B ND 1ug/L0.040 4,4'-DDT 50-29-3 8081B ND 1ug/L0.040 Dieldrin 60-57-1 8081B ND 1ug/L0.040 Endosulfan I 959-98-8 8081B ND 1ug/L0.040 Endosulfan II 33213-65-9 8081B ND 1ug/L0.040 Endosulfan sulfate 1031-07-8 8081B ND 1ug/L0.040 Endrin 72-20-8 8081B ND 1ug/L0.040 Endrin aldehyde 7421-93-4 8081B ND 1ug/L0.040 Heptachlor 76-44-8 8081B ND 1ug/L0.040 Heptachlor epoxide 1024-57-3 8081B ND 1ug/L0.040 Methoxychlor 72-43-5 8081B ND 1ug/L0.16 Toxaphene 8001-35-2 8081B ND 1ug/L0.40 AcceptanceRun 1 Surrogate Q % Recovery Limits Decachlorobiphenyl 82 10-122 Tetrachloro-m-xylene 85 46-119 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/23/2016 1421 NCM 03/21/2016 0923 98884 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.035 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 83 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County US-1 RC18024-024 03/17/2016 1710 03/18/2016 Aqueous ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/23/2016 1421 NCM 03/21/2016 0923 98884 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C ND 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 84 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County DS-1 RC18024-025 03/17/2016 1430 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/17/2016 1430 CAE 1 (Specific Con) 120.1 1 03/17/2016 1430 CAE 1 (Temperature ) SM 2550B-2000 1 03/17/2016 1430 CAE 1 (Turbidity - ) 180.1 1 03/17/2016 1430 CAE 1 10-204-00-1-X (Cyanide - To) SM 4500-CN E-1 03/24/2016 2141 MJI 03/24/2016 1856 99272 AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 6.83 1su Specific Conductance - Field 120.1 67.3 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 16.1 1° C Turbidity - Field 180.1 13 1NTU1.0 Cyanide - Total 57-12-5 SM 4500-CN ND 1mg/L0.010 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/25/2016 1858 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 85 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County DS-1 RC18024-025 03/17/2016 1430 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/25/2016 1858 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 1ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 86 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County DS-1 RC18024-025 03/17/2016 1430 03/18/2016 Aqueous AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 105 70-130 Bromofluorobenzene 110 70-130 Toluene-d8 105 70-130 Organochlorine Pesticides by GC Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3520C 8081B 1 03/24/2016 1301 PMS 03/22/2016 1630 99070 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Aldrin 309-00-2 8081B ND 1ug/L0.040 gamma-BHC (Lindane)58-89-9 8081B ND 1ug/L0.040 alpha-BHC 319-84-6 8081B ND 1ug/L0.040 beta-BHC 319-85-7 8081B ND 1ug/L0.040 delta-BHC 319-86-8 8081B ND 1ug/L0.040 Chlordane 57-74-9 8081B ND 1ug/L0.40 4,4'-DDD 72-54-8 8081B ND 1ug/L0.040 4,4'-DDE 72-55-9 8081B ND 1ug/L0.040 4,4'-DDT 50-29-3 8081B ND 1ug/L0.040 Dieldrin 60-57-1 8081B ND 1ug/L0.040 Endosulfan I 959-98-8 8081B ND 1ug/L0.040 Endosulfan II 33213-65-9 8081B ND 1ug/L0.040 Endosulfan sulfate 1031-07-8 8081B ND 1ug/L0.040 Endrin 72-20-8 8081B ND 1ug/L0.040 Endrin aldehyde 7421-93-4 8081B ND 1ug/L0.040 Heptachlor 76-44-8 8081B ND 1ug/L0.040 Heptachlor epoxide 1024-57-3 8081B ND 1ug/L0.040 Methoxychlor 72-43-5 8081B ND 1ug/L0.16 Toxaphene 8001-35-2 8081B ND 1ug/L0.40 AcceptanceRun 1 Surrogate Q % Recovery Limits Decachlorobiphenyl 83 10-122 Tetrachloro-m-xylene 87 46-119 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/23/2016 1430 NCM 03/21/2016 0923 98884 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.036 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 87 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County DS-1 RC18024-025 03/17/2016 1430 03/18/2016 Aqueous ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/23/2016 1430 NCM 03/21/2016 0923 98884 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C ND 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 88 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County DS-2 RC18024-026 03/17/2016 1100 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/17/2016 1100 CAE 1 (Specific Con) 120.1 1 03/17/2016 1100 CAE 1 (Temperature ) SM 2550B-2000 1 03/17/2016 1100 CAE 1 (Turbidity - ) 180.1 1 03/17/2016 1100 CAE 1 10-204-00-1-X (Cyanide - To) SM 4500-CN E-1 03/24/2016 2141 MJI 03/24/2016 1856 99272 AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 6.63 1su Specific Conductance - Field 120.1 79.0 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 12.2 1° C Turbidity - Field 180.1 18 1NTU1.0 Cyanide - Total 57-12-5 SM 4500-CN ND 1mg/L0.010 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/25/2016 1944 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 89 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County DS-2 RC18024-026 03/17/2016 1100 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/25/2016 1944 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 1ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 90 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County DS-2 RC18024-026 03/17/2016 1100 03/18/2016 Aqueous AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 117 70-130 Bromofluorobenzene 115 70-130 Toluene-d8 109 70-130 Organochlorine Pesticides by GC Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3520C 8081B 1 03/24/2016 1316 PMS 03/22/2016 1630 99070 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Aldrin 309-00-2 8081B ND 1ug/L0.040 gamma-BHC (Lindane)58-89-9 8081B ND 1ug/L0.040 alpha-BHC 319-84-6 8081B ND 1ug/L0.040 beta-BHC 319-85-7 8081B ND 1ug/L0.040 delta-BHC 319-86-8 8081B ND 1ug/L0.040 Chlordane 57-74-9 8081B ND 1ug/L0.40 4,4'-DDD 72-54-8 8081B ND 1ug/L0.040 4,4'-DDE 72-55-9 8081B ND 1ug/L0.040 4,4'-DDT 50-29-3 8081B ND 1ug/L0.040 Dieldrin 60-57-1 8081B ND 1ug/L0.040 Endosulfan I 959-98-8 8081B ND 1ug/L0.040 Endosulfan II 33213-65-9 8081B ND 1ug/L0.040 Endosulfan sulfate 1031-07-8 8081B ND 1ug/L0.040 Endrin 72-20-8 8081B ND 1ug/L0.040 Endrin aldehyde 7421-93-4 8081B ND 1ug/L0.040 Heptachlor 76-44-8 8081B ND 1ug/L0.040 Heptachlor epoxide 1024-57-3 8081B ND 1ug/L0.040 Methoxychlor 72-43-5 8081B ND 1ug/L0.16 Toxaphene 8001-35-2 8081B ND 1ug/L0.40 AcceptanceRun 1 Surrogate Q % Recovery Limits Decachlorobiphenyl 84 10-122 Tetrachloro-m-xylene 87 46-119 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/23/2016 1434 NCM 03/21/2016 0923 98884 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.044 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 91 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County DS-2 RC18024-026 03/17/2016 1100 03/18/2016 Aqueous ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/23/2016 1434 NCM 03/21/2016 0923 98884 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C ND 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 92 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County DS-3 RC18024-027 03/16/2016 1834 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH - Field) SM 4500-H B-2011 1 03/16/2016 1834 CAE 1 (Specific Con) 120.1 1 03/16/2016 1834 CAE 1 (Temperature ) SM 2550B-2000 1 03/16/2016 1834 CAE 1 (Turbidity - ) 180.1 1 03/16/2016 1834 CAE 1 10-204-00-1-X (Cyanide - To) SM 4500-CN E-1 03/24/2016 2147 MJI 03/24/2016 1856 99272 AnalyticalCAS Parameter Number Method Result Q PQL Units Run pH - Field SM 4500-H B 6.14 1su Specific Conductance - Field 120.1 83.3 1umhos/cm1.00 Temperature - Field (NC)SM 2550B-20 15.5 1° C Turbidity - Field 180.1 11 1NTU1.0 Cyanide - Total 57-12-5 SM 4500-CN ND 1mg/L0.010 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/25/2016 2006 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 93 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County DS-3 RC18024-027 03/16/2016 1834 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/25/2016 2006 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 1ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 94 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County DS-3 RC18024-027 03/16/2016 1834 03/18/2016 Aqueous AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 115 70-130 Bromofluorobenzene 115 70-130 Toluene-d8 108 70-130 Organochlorine Pesticides by GC Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3520C 8081B 1 03/24/2016 1330 PMS 03/22/2016 1630 99070 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Aldrin 309-00-2 8081B ND 1ug/L0.040 gamma-BHC (Lindane)58-89-9 8081B ND 1ug/L0.040 alpha-BHC 319-84-6 8081B ND 1ug/L0.040 beta-BHC 319-85-7 8081B ND 1ug/L0.040 delta-BHC 319-86-8 8081B ND 1ug/L0.040 Chlordane 57-74-9 8081B ND 1ug/L0.40 4,4'-DDD 72-54-8 8081B ND 1ug/L0.040 4,4'-DDE 72-55-9 8081B ND 1ug/L0.040 4,4'-DDT 50-29-3 8081B ND 1ug/L0.040 Dieldrin 60-57-1 8081B ND 1ug/L0.040 Endosulfan I 959-98-8 8081B ND 1ug/L0.040 Endosulfan II 33213-65-9 8081B ND 1ug/L0.040 Endosulfan sulfate 1031-07-8 8081B ND 1ug/L0.040 Endrin 72-20-8 8081B ND 1ug/L0.040 Endrin aldehyde 7421-93-4 8081B ND 1ug/L0.040 Heptachlor 76-44-8 8081B ND 1ug/L0.040 Heptachlor epoxide 1024-57-3 8081B ND 1ug/L0.040 Methoxychlor 72-43-5 8081B ND 1ug/L0.16 Toxaphene 8001-35-2 8081B ND 1ug/L0.40 AcceptanceRun 1 Surrogate Q % Recovery Limits Decachlorobiphenyl 83 10-122 Tetrachloro-m-xylene 85 46-119 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/23/2016 1443 NCM 03/21/2016 0923 98884 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C 0.041 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 95 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County DS-3 RC18024-027 03/16/2016 1834 03/18/2016 Aqueous ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/23/2016 1443 NCM 03/21/2016 0923 98884 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C ND 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 96 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County FIELD BLANK RC18024-028 03/16/2016 1935 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 10-204-00-1-X (Cyanide - To) SM 4500-CN E-1 03/24/2016 2147 MJI 03/24/2016 1856 99272 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Cyanide - Total 57-12-5 SM 4500-CN ND 1mg/L0.010 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/25/2016 2028 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 97 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County FIELD BLANK RC18024-028 03/16/2016 1935 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/25/2016 2028 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 1ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 111 70-130 Bromofluorobenzene 112 70-130 Toluene-d8 108 70-130 Organochlorine Pesticides by GC Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3520C 8081B 1 03/24/2016 1345 PMS 03/22/2016 1630 99070 AnalyticalCAS Parameter Number Method Result Q PQL Units Run J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 98 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County FIELD BLANK RC18024-028 03/16/2016 1935 03/18/2016 Aqueous Organochlorine Pesticides by GC Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3520C 8081B 1 03/24/2016 1345 PMS 03/22/2016 1630 99070 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Aldrin 309-00-2 8081B ND 1ug/L0.040 gamma-BHC (Lindane)58-89-9 8081B ND 1ug/L0.040 alpha-BHC 319-84-6 8081B ND 1ug/L0.040 beta-BHC 319-85-7 8081B ND 1ug/L0.040 delta-BHC 319-86-8 8081B ND 1ug/L0.040 Chlordane 57-74-9 8081B ND 1ug/L0.40 4,4'-DDD 72-54-8 8081B ND 1ug/L0.040 4,4'-DDE 72-55-9 8081B ND 1ug/L0.040 4,4'-DDT 50-29-3 8081B ND 1ug/L0.040 Dieldrin 60-57-1 8081B ND 1ug/L0.040 Endosulfan I 959-98-8 8081B ND 1ug/L0.040 Endosulfan II 33213-65-9 8081B ND 1ug/L0.040 Endosulfan sulfate 1031-07-8 8081B ND 1ug/L0.040 Endrin 72-20-8 8081B ND 1ug/L0.040 Endrin aldehyde 7421-93-4 8081B ND 1ug/L0.040 Heptachlor 76-44-8 8081B ND 1ug/L0.040 Heptachlor epoxide 1024-57-3 8081B ND 1ug/L0.040 Methoxychlor 72-43-5 8081B ND 1ug/L0.16 Toxaphene 8001-35-2 8081B ND 1ug/L0.40 AcceptanceRun 1 Surrogate Q % Recovery Limits Decachlorobiphenyl 64 10-122 Tetrachloro-m-xylene 85 46-119 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/23/2016 1448 NCM 03/21/2016 0923 98884 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C ND 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 99 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County FIELD BLANK RC18024-028 03/16/2016 1935 03/18/2016 Aqueous ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/23/2016 1448 NCM 03/21/2016 0923 98884 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C ND 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 100 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County FIELD BLANK RC18024-029 03/17/2016 1730 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 10-204-00-1-X (Cyanide - To) SM 4500-CN E-1 03/24/2016 2147 MJI 03/24/2016 1856 99272 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Cyanide - Total 57-12-5 SM 4500-CN ND 1mg/L0.010 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/25/2016 2049 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 101 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County FIELD BLANK RC18024-029 03/17/2016 1730 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/25/2016 2049 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 1ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 114 70-130 Bromofluorobenzene 112 70-130 Toluene-d8 109 70-130 Organochlorine Pesticides by GC Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3520C 8081B 1 03/24/2016 1400 PMS 03/22/2016 1630 99070 AnalyticalCAS Parameter Number Method Result Q PQL Units Run J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 102 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County FIELD BLANK RC18024-029 03/17/2016 1730 03/18/2016 Aqueous Organochlorine Pesticides by GC Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3520C 8081B 1 03/24/2016 1400 PMS 03/22/2016 1630 99070 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Aldrin 309-00-2 8081B ND 1ug/L0.040 gamma-BHC (Lindane)58-89-9 8081B ND 1ug/L0.040 alpha-BHC 319-84-6 8081B ND 1ug/L0.040 beta-BHC 319-85-7 8081B ND 1ug/L0.040 delta-BHC 319-86-8 8081B ND 1ug/L0.040 Chlordane 57-74-9 8081B ND 1ug/L0.40 4,4'-DDD 72-54-8 8081B ND 1ug/L0.040 4,4'-DDE 72-55-9 8081B ND 1ug/L0.040 4,4'-DDT 50-29-3 8081B ND 1ug/L0.040 Dieldrin 60-57-1 8081B ND 1ug/L0.040 Endosulfan I 959-98-8 8081B ND 1ug/L0.040 Endosulfan II 33213-65-9 8081B ND 1ug/L0.040 Endosulfan sulfate 1031-07-8 8081B ND 1ug/L0.040 Endrin 72-20-8 8081B ND 1ug/L0.040 Endrin aldehyde 7421-93-4 8081B ND 1ug/L0.040 Heptachlor 76-44-8 8081B ND 1ug/L0.040 Heptachlor epoxide 1024-57-3 8081B ND 1ug/L0.040 Methoxychlor 72-43-5 8081B ND 1ug/L0.16 Toxaphene 8001-35-2 8081B ND 1ug/L0.40 AcceptanceRun 1 Surrogate Q % Recovery Limits Decachlorobiphenyl 59 10-122 Tetrachloro-m-xylene 85 46-119 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/23/2016 1452 NCM 03/21/2016 0923 98884 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C ND 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 103 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County FIELD BLANK RC18024-029 03/17/2016 1730 03/18/2016 Aqueous ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/23/2016 1452 NCM 03/21/2016 0923 98884 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C ND 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 104 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County FIELD BLANK RC18024-030 03/18/2016 0845 03/18/2016 Aqueous Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 10-204-00-1-X (Cyanide - To) SM 4500-CN E-1 03/24/2016 2147 MJI 03/24/2016 1856 99272 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Cyanide - Total 57-12-5 SM 4500-CN ND 1mg/L0.010 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/25/2016 2147 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 105 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County FIELD BLANK RC18024-030 03/18/2016 0845 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/25/2016 2147 RAG 99362 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 1ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 119 70-130 Bromofluorobenzene 117 70-130 Toluene-d8 111 70-130 Organochlorine Pesticides by GC Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3520C 8081B 1 03/24/2016 1415 PMS 03/22/2016 1630 99070 AnalyticalCAS Parameter Number Method Result Q PQL Units Run J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 106 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County FIELD BLANK RC18024-030 03/18/2016 0845 03/18/2016 Aqueous Organochlorine Pesticides by GC Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3520C 8081B 1 03/24/2016 1415 PMS 03/22/2016 1630 99070 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Aldrin 309-00-2 8081B ND 1ug/L0.040 gamma-BHC (Lindane)58-89-9 8081B ND 1ug/L0.040 alpha-BHC 319-84-6 8081B ND 1ug/L0.040 beta-BHC 319-85-7 8081B ND 1ug/L0.040 delta-BHC 319-86-8 8081B ND 1ug/L0.040 Chlordane 57-74-9 8081B ND 1ug/L0.40 4,4'-DDD 72-54-8 8081B ND 1ug/L0.040 4,4'-DDE 72-55-9 8081B ND 1ug/L0.040 4,4'-DDT 50-29-3 8081B ND 1ug/L0.040 Dieldrin 60-57-1 8081B ND 1ug/L0.040 Endosulfan I 959-98-8 8081B ND 1ug/L0.040 Endosulfan II 33213-65-9 8081B ND 1ug/L0.040 Endosulfan sulfate 1031-07-8 8081B ND 1ug/L0.040 Endrin 72-20-8 8081B ND 1ug/L0.040 Endrin aldehyde 7421-93-4 8081B ND 1ug/L0.040 Heptachlor 76-44-8 8081B ND 1ug/L0.040 Heptachlor epoxide 1024-57-3 8081B ND 1ug/L0.040 Methoxychlor 72-43-5 8081B ND 1ug/L0.16 Toxaphene 8001-35-2 8081B ND 1ug/L0.40 AcceptanceRun 1 Surrogate Q % Recovery Limits Decachlorobiphenyl 73 10-122 Tetrachloro-m-xylene 91 46-119 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/23/2016 1457 NCM 03/21/2016 0923 98884 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Antimony 7440-36-0 6010C ND 1mg/L0.020 Arsenic 7440-38-2 6010C ND 1mg/L0.015 Barium 7440-39-3 6010C ND 1mg/L0.025 Beryllium 7440-41-7 6010C ND 1mg/L0.0050 Cadmium 7440-43-9 6010C ND 1mg/L0.0050 Chromium 7440-47-3 6010C ND 1mg/L0.010 Cobalt 7440-48-4 6010C ND 1mg/L0.025 Copper 7440-50-8 6010C ND 1mg/L0.010 Lead 7439-92-1 6010C ND 1mg/L0.010 Nickel 7440-02-0 6010C ND 1mg/L0.040 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 107 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County FIELD BLANK RC18024-030 03/18/2016 0845 03/18/2016 Aqueous ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6010C 1 03/23/2016 1457 NCM 03/21/2016 0923 98884 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Selenium 7782-49-2 6010C ND 1mg/L0.020 Silver 7440-22-4 6010C ND 1mg/L0.010 Thallium 7440-28-0 6010C ND 1mg/L0.050 Vanadium 7440-62-2 6010C ND 1mg/L0.050 Zinc 7440-66-6 6010C ND 1mg/L0.020 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 108 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County TRIP BLANK RC18024-031 03/18/2016 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/28/2016 1038 ALL 99475 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Acetone 67-64-1 8260B ND 1ug/L20 Acetonitrile 75-05-8 8260B ND 1ug/L20 Acrolein 107-02-8 8260B ND 1ug/L20 Acrylonitrile 107-13-1 8260B ND 1ug/L20 Benzene 71-43-2 8260B ND 1ug/L1.0 Bromochloromethane 74-97-5 8260B ND 1ug/L1.0 Bromodichloromethane 75-27-4 8260B ND 1ug/L1.0 Bromoform 75-25-2 8260B ND 1ug/L1.0 Bromomethane (Methyl bromide)74-83-9 8260B ND 1ug/L2.0 2-Butanone (MEK)78-93-3 8260B ND 1ug/L10 Carbon disulfide 75-15-0 8260B ND 1ug/L1.0 Carbon tetrachloride 56-23-5 8260B ND 1ug/L1.0 2-Chloro-1,3-Butadiene (Chloroprene)126-99-8 8260B ND 1ug/L5.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 Chloroethane 75-00-3 8260B ND 1ug/L2.0 Chloroform 67-66-3 8260B ND 1ug/L1.0 Chloromethane (Methyl chloride)74-87-3 8260B ND 1ug/L1.0 3-Chloropropene (Allyl chloride)107-05-1 8260B ND 1ug/L2.0 1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B ND 1ug/L1.0 Dibromochloromethane 124-48-1 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 Dibromomethane (Methylene bromide)74-95-3 8260B ND 1ug/L1.0 trans-1,4-Dichloro-2-butene 110-57-6 8260B ND 1ug/L2.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Dichlorodifluoromethane 75-71-8 8260B ND 1ug/L2.0 1,1-Dichloroethane 75-34-3 8260B ND 1ug/L1.0 1,2-Dichloroethane 107-06-2 8260B ND 1ug/L1.0 1,1-Dichloroethene 75-35-4 8260B ND 1ug/L1.0 cis-1,2-Dichloroethene 156-59-2 8260B ND 1ug/L1.0 trans-1,2-Dichloroethene 156-60-5 8260B ND 1ug/L1.0 1,2-Dichloropropane 78-87-5 8260B ND 1ug/L1.0 1,3-Dichloropropane 142-28-9 8260B ND 1ug/L1.0 2,2-Dichloropropane 594-20-7 8260B ND 1ug/L1.0 1,1-Dichloropropene 563-58-6 8260B ND 1ug/L2.0 cis-1,3-Dichloropropene 10061-01-5 8260B ND 1ug/L1.0 trans-1,3-Dichloropropene 10061-02-6 8260B ND 1ug/L1.0 Ethyl methacrylate 97-63-2 8260B ND 1ug/L5.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 109 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Haywood County TRIP BLANK RC18024-031 03/18/2016 03/18/2016 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 03/28/2016 1038 ALL 99475 AnalyticalCAS Parameter Number Method Result Q PQL Units Run 2-Hexanone 591-78-6 8260B ND 1ug/L10 Isobutyl alcohol 78-83-1 8260B ND 1ug/L50 Methacrylonitrile 126-98-7 8260B ND 1ug/L5.0 Methyl iodide (Iodomethane)74-88-4 8260B ND 1ug/L5.0 Methyl methacrylate 80-62-6 8260B ND 1ug/L5.0 4-Methyl-2-pentanone 108-10-1 8260B ND 1ug/L10 Methylene chloride 75-09-2 8260B ND 1ug/L1.0 Propionitrile (Ethyl cyanide)107-12-0 8260B ND 1ug/L20 Styrene 100-42-5 8260B ND 1ug/L1.0 1,1,1,2-Tetrachloroethane 630-20-6 8260B ND 1ug/L1.0 1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 1ug/L1.0 Tetrachloroethene 127-18-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 1,1,1-Trichloroethane 71-55-6 8260B ND 1ug/L1.0 1,1,2-Trichloroethane 79-00-5 8260B ND 1ug/L1.0 Trichloroethene 79-01-6 8260B ND 1ug/L1.0 Trichlorofluoromethane 75-69-4 8260B ND 1ug/L1.0 1,2,3-Trichloropropane 96-18-4 8260B ND 1ug/L1.0 Vinyl acetate 108-05-4 8260B ND 1ug/L5.0 Vinyl chloride 75-01-4 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 113 70-130 Bromofluorobenzene 116 70-130 Toluene-d8 109 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 110 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. QC Summary Page: 111 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - MB Batch:Prep Method: Prep Date: Sample ID:RQ99062-001 99062 10-204-00-1-X 03/22/2016 1435Analytical Method:SM 4500-CN E-2011 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Cyanide - Total ND 03/22/2016 20470.010 mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 112 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - LCS Batch:Prep Method: Prep Date: Sample ID:RQ99062-002 99062 10-204-00-1-X 03/22/2016 1435Analytical Method:SM 4500-CN E-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Cyanide - Total 0.092 03/22/2016 2047920.10 90-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 113 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - MS Batch:Prep Method: Prep Date: Sample ID:RC18024-009MS 99062 10-204-00-1-X 03/22/2016 1435Analytical Method:SM 4500-CN E-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Cyanide - Total 0.12 03/22/2016 2140N1150.10 90-110ND1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 114 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - MSD Batch:Prep Method: Prep Date: Sample ID:RC18024-009MD 99062 10-204-00-1-X 03/22/2016 1435Analytical Method:SM 4500-CN E-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Cyanide - Total 0.11 03/22/2016 2140N1110.10 90-1103.9 20ND1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 115 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - MB Batch:Prep Method: Prep Date: Sample ID:RQ99272-001 99272 10-204-00-1-X 03/24/2016 1856Analytical Method:SM 4500-CN E-2011 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Cyanide - Total ND 03/24/2016 21410.010 mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 116 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - LCS Batch:Prep Method: Prep Date: Sample ID:RQ99272-002 99272 10-204-00-1-X 03/24/2016 1856Analytical Method:SM 4500-CN E-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Cyanide - Total 0.095 03/24/2016 2141950.10 90-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 117 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - MS Batch:Prep Method: Prep Date: Sample ID:RC18024-024MS 99272 10-204-00-1-X 03/24/2016 1856Analytical Method:SM 4500-CN E-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Cyanide - Total 0.095 03/24/2016 2141950.10 90-110ND1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 118 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - MSD Batch:Prep Method: Prep Date: Sample ID:RC18024-024MD 99272 10-204-00-1-X 03/24/2016 1856Analytical Method:SM 4500-CN E-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Cyanide - Total 0.098 03/24/2016 2141980.10 90-1102.5 20ND1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 119 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - MB Batch:Prep Method: Sample ID:RQ99005-001 99005 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Acetone ND 03/22/2016 094620ug/L1 Acetonitrile ND 03/22/2016 094620ug/L1 Acrolein ND 03/22/2016 094620ug/L1 Acrylonitrile ND 03/22/2016 094620ug/L1 Benzene ND 03/22/2016 09461.0 ug/L1 Bromochloromethane ND 03/22/2016 09461.0 ug/L1 Bromodichloromethane ND 03/22/2016 09461.0 ug/L1 Bromoform ND 03/22/2016 09461.0 ug/L1 Bromomethane (Methyl bromide)ND 03/22/2016 09462.0 ug/L1 2-Butanone (MEK)ND 03/22/2016 094610ug/L1 Carbon disulfide ND 03/22/2016 09461.0 ug/L1 Carbon tetrachloride ND 03/22/2016 09461.0 ug/L1 2-Chloro-1,3-Butadiene (Chloroprene)ND 03/22/2016 09465.0 ug/L1 Chlorobenzene ND 03/22/2016 09461.0 ug/L1 Chloroethane ND 03/22/2016 09462.0 ug/L1 Chloroform ND 03/22/2016 09461.0 ug/L1 Chloromethane (Methyl chloride)ND 03/22/2016 09461.0 ug/L1 3-Chloropropene (Allyl chloride)ND 03/22/2016 09462.0 ug/L1 1,2-Dibromo-3-chloropropane (DBCP)ND 03/22/2016 09461.0 ug/L1 Dibromochloromethane ND 03/22/2016 09461.0 ug/L1 1,2-Dibromoethane (EDB)ND 03/22/2016 09461.0 ug/L1 Dibromomethane (Methylene bromide)ND 03/22/2016 09461.0 ug/L1 trans-1,4-Dichloro-2-butene ND 03/22/2016 09462.0 ug/L1 1,2-Dichlorobenzene ND 03/22/2016 09461.0 ug/L1 1,3-Dichlorobenzene ND 03/22/2016 09461.0 ug/L1 1,4-Dichlorobenzene ND 03/22/2016 09461.0 ug/L1 Dichlorodifluoromethane ND 03/22/2016 09462.0 ug/L1 1,1-Dichloroethane ND 03/22/2016 09461.0 ug/L1 1,2-Dichloroethane ND 03/22/2016 09461.0 ug/L1 cis-1,2-Dichloroethene ND 03/22/2016 09461.0 ug/L1 trans-1,2-Dichloroethene ND 03/22/2016 09461.0 ug/L1 1,1-Dichloroethene ND 03/22/2016 09461.0 ug/L1 1,3-Dichloropropane ND 03/22/2016 09461.0 ug/L1 1,2-Dichloropropane ND 03/22/2016 09461.0 ug/L1 2,2-Dichloropropane ND 03/22/2016 09461.0 ug/L1 cis-1,3-Dichloropropene ND 03/22/2016 09461.0 ug/L1 trans-1,3-Dichloropropene ND 03/22/2016 09461.0 ug/L1 1,1-Dichloropropene ND 03/22/2016 09462.0 ug/L1 Ethyl methacrylate ND 03/22/2016 09465.0 ug/L1 Ethylbenzene ND 03/22/2016 09461.0 ug/L1 2-Hexanone ND 03/22/2016 094610ug/L1 Methacrylonitrile ND 03/22/2016 09465.0 ug/L1 Methyl iodide (Iodomethane)ND 03/22/2016 09465.0 ug/L1 Methyl methacrylate ND 03/22/2016 09465.0 ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 120 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - MB Batch:Prep Method: Sample ID:RQ99005-001 99005 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil 4-Methyl-2-pentanone ND 03/22/2016 094610ug/L1 Methylene chloride ND 03/22/2016 09461.0 ug/L1 Propionitrile (Ethyl cyanide)ND 03/22/2016 094620ug/L1 Styrene ND 03/22/2016 09461.0 ug/L1 1,1,1,2-Tetrachloroethane ND 03/22/2016 09461.0 ug/L1 1,1,2,2-Tetrachloroethane ND 03/22/2016 09461.0 ug/L1 Tetrachloroethene ND 03/22/2016 09461.0 ug/L1 Toluene ND 03/22/2016 09461.0 ug/L1 1,1,1-Trichloroethane ND 03/22/2016 09461.0 ug/L1 1,1,2-Trichloroethane ND 03/22/2016 09461.0 ug/L1 Trichloroethene ND 03/22/2016 09461.0 ug/L1 Trichlorofluoromethane ND 03/22/2016 09461.0 ug/L1 1,2,3-Trichloropropane ND 03/22/2016 09461.0 ug/L1 Vinyl acetate ND 03/22/2016 09465.0 ug/L1 Vinyl chloride ND 03/22/2016 09461.0 ug/L1 Xylenes (total)ND 03/22/2016 09461.0 ug/L1 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 112 70-130 1,2-Dichloroethane-d4 94 70-130 Toluene-d8 105 70-130 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 121 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - LCS Batch:Prep Method: Sample ID:RQ99005-002 99005 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Acetone 76 03/22/2016 08537610060-1401 Acetonitrile 420 03/22/2016 08538550060-1401 Acrolein 620 03/22/2016 085312350060-1401 Acrylonitrile 100 03/22/2016 085310110070-1301 Benzene 59 03/22/2016 08531175070-1301 Bromochloromethane 48 03/22/2016 0853955070-1301 Bromodichloromethane 57 03/22/2016 08531135070-1301 Bromoform 53 03/22/2016 08531055070-1301 Bromomethane (Methyl bromide)50 03/22/2016 08531005060-1401 2-Butanone (MEK)95 03/22/2016 08539510060-1401 Carbon disulfide 61 03/22/2016 08531225060-1401 Carbon tetrachloride 54 03/22/2016 08531085070-1301 2-Chloro-1,3-Butadiene (Chloroprene)62 03/22/2016 08531255070-1301 Chlorobenzene 51 03/22/2016 08531025070-1301 Chloroethane 57 03/22/2016 08531155060-1401 Chloroform 54 03/22/2016 08531085070-1301 Chloromethane (Methyl chloride)58 03/22/2016 08531165060-1401 3-Chloropropene (Allyl chloride)65 03/22/2016 08531295070-1301 1,2-Dibromo-3-chloropropane (DBCP)44 03/22/2016 0853885070-1301 Dibromochloromethane 50 03/22/2016 08531015070-1301 1,2-Dibromoethane (EDB)49 03/22/2016 0853985070-1301 Dibromomethane (Methylene bromide)51 03/22/2016 08531015070-1301 trans-1,4-Dichloro-2-butene 51 03/22/2016 08531025034-1421 1,2-Dichlorobenzene 49 03/22/2016 0853975070-1301 1,3-Dichlorobenzene 48 03/22/2016 0853955070-1301 1,4-Dichlorobenzene 46 03/22/2016 0853915070-1301 Dichlorodifluoromethane 58 03/22/2016 08531165060-1401 1,1-Dichloroethane 60 03/22/2016 08531215070-1301 1,2-Dichloroethane 46 03/22/2016 0853925070-1301 cis-1,2-Dichloroethene 53 03/22/2016 08531075070-1301 trans-1,2-Dichloroethene 55 03/22/2016 08531115070-1301 1,1-Dichloroethene 59 03/22/2016 08531175070-1301 1,3-Dichloropropane 51 03/22/2016 08531025070-1301 1,2-Dichloropropane 58 03/22/2016 08531155070-1301 2,2-Dichloropropane 64 03/22/2016 08531275070-1301 cis-1,3-Dichloropropene 58 03/22/2016 08531165070-1301 trans-1,3-Dichloropropene 55 03/22/2016 08531095070-1301 1,1-Dichloropropene 57 03/22/2016 08531135070-1301 Ethyl methacrylate 59 03/22/2016 08531185070-1301 Ethylbenzene 55 03/22/2016 08531115070-1301 2-Hexanone 97 03/22/2016 08539710060-1401 Methacrylonitrile 270 03/22/2016 085310825070-1301 Methyl iodide (Iodomethane)50 03/22/2016 08531005070-1301 Methyl methacrylate 47 03/22/2016 0853935070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 122 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - LCS Batch:Prep Method: Sample ID:RQ99005-002 99005 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) 4-Methyl-2-pentanone 100 03/22/2016 085310110060-1401 Methylene chloride 58 03/22/2016 08531165070-1301 Propionitrile (Ethyl cyanide)510 03/22/2016 085310250070-1301 Styrene 58 03/22/2016 08531175070-1301 1,1,1,2-Tetrachloroethane 51 03/22/2016 08531035070-1301 1,1,2,2-Tetrachloroethane 50 03/22/2016 08531015060-1401 Tetrachloroethene 57 03/22/2016 08531145070-1301 Toluene 58 03/22/2016 08531155070-1301 1,1,1-Trichloroethane 56 03/22/2016 08531125070-1301 1,1,2-Trichloroethane 48 03/22/2016 0853965070-1301 Trichloroethene 47 03/22/2016 0853945070-1301 Trichlorofluoromethane 58 03/22/2016 08531165070-1301 1,2,3-Trichloropropane 46 03/22/2016 0853915070-1301 Vinyl acetate 50 03/22/2016 08531005060-1401 Vinyl chloride 62 03/22/2016 08531245070-1301 Xylenes (total)120 03/22/2016 085311810070-1301 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 107 70-130 1,2-Dichloroethane-d4 89 70-130 Toluene-d8 106 70-130 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 123 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - MB Batch:Prep Method: Sample ID:RQ99192-001 99192 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Acetone ND 03/23/2016 221620ug/L1 Acrolein ND 03/23/2016 221620ug/L1 Acrylonitrile ND 03/23/2016 221620ug/L1 Benzene ND 03/23/2016 22161.0 ug/L1 Bromochloromethane ND 03/23/2016 22161.0 ug/L1 Bromodichloromethane ND 03/23/2016 22161.0 ug/L1 Bromoform ND 03/23/2016 22161.0 ug/L1 Bromomethane (Methyl bromide)ND 03/23/2016 22162.0 ug/L1 2-Butanone (MEK)ND 03/23/2016 221610ug/L1 Carbon disulfide ND 03/23/2016 22161.0 ug/L1 Carbon tetrachloride ND 03/23/2016 22161.0 ug/L1 2-Chloro-1,3-Butadiene (Chloroprene)ND 03/23/2016 22165.0 ug/L1 Chlorobenzene ND 03/23/2016 22161.0 ug/L1 Chloroethane ND 03/23/2016 22162.0 ug/L1 Chloroform ND 03/23/2016 22161.0 ug/L1 Chloromethane (Methyl chloride)ND 03/23/2016 22161.0 ug/L1 3-Chloropropene (Allyl chloride)ND 03/23/2016 22162.0 ug/L1 1,2-Dibromo-3-chloropropane (DBCP)ND 03/23/2016 22161.0 ug/L1 Dibromochloromethane ND 03/23/2016 22161.0 ug/L1 1,2-Dibromoethane (EDB)ND 03/23/2016 22161.0 ug/L1 Dibromomethane (Methylene bromide)ND 03/23/2016 22161.0 ug/L1 trans-1,4-Dichloro-2-butene ND 03/23/2016 22162.0 ug/L1 1,4-Dichlorobenzene ND 03/23/2016 22161.0 ug/L1 1,2-Dichlorobenzene ND 03/23/2016 22161.0 ug/L1 1,3-Dichlorobenzene ND 03/23/2016 22161.0 ug/L1 Dichlorodifluoromethane ND 03/23/2016 22162.0 ug/L1 1,2-Dichloroethane ND 03/23/2016 22161.0 ug/L1 1,1-Dichloroethane ND 03/23/2016 22161.0 ug/L1 trans-1,2-Dichloroethene ND 03/23/2016 22161.0 ug/L1 1,1-Dichloroethene ND 03/23/2016 22161.0 ug/L1 cis-1,2-Dichloroethene ND 03/23/2016 22161.0 ug/L1 2,2-Dichloropropane ND 03/23/2016 22161.0 ug/L1 1,2-Dichloropropane ND 03/23/2016 22161.0 ug/L1 1,3-Dichloropropane ND 03/23/2016 22161.0 ug/L1 trans-1,3-Dichloropropene ND 03/23/2016 22161.0 ug/L1 1,1-Dichloropropene ND 03/23/2016 22162.0 ug/L1 cis-1,3-Dichloropropene ND 03/23/2016 22161.0 ug/L1 Ethyl methacrylate ND 03/23/2016 22165.0 ug/L1 Ethylbenzene ND 03/23/2016 22161.0 ug/L1 2-Hexanone ND 03/23/2016 221610ug/L1 Isobutyl alcohol ND 03/23/2016 221650ug/L1 Methacrylonitrile ND 03/23/2016 22165.0 ug/L1 Methyl iodide (Iodomethane)ND 03/23/2016 22165.0 ug/L1 Methyl methacrylate ND 03/23/2016 22165.0 ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 124 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - MB Batch:Prep Method: Sample ID:RQ99192-001 99192 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil 4-Methyl-2-pentanone ND 03/23/2016 221610ug/L1 Methylene chloride ND 03/23/2016 22161.0 ug/L1 Propionitrile (Ethyl cyanide)ND 03/23/2016 221620ug/L1 Styrene ND 03/23/2016 22161.0 ug/L1 1,1,2,2-Tetrachloroethane ND 03/23/2016 22161.0 ug/L1 1,1,1,2-Tetrachloroethane ND 03/23/2016 22161.0 ug/L1 Tetrachloroethene ND 03/23/2016 22161.0 ug/L1 Toluene ND 03/23/2016 22161.0 ug/L1 1,1,2-Trichloroethane ND 03/23/2016 22161.0 ug/L1 1,1,1-Trichloroethane ND 03/23/2016 22161.0 ug/L1 Trichloroethene ND 03/23/2016 22161.0 ug/L1 Trichlorofluoromethane ND 03/23/2016 22161.0 ug/L1 1,2,3-Trichloropropane ND 03/23/2016 22161.0 ug/L1 Vinyl acetate ND 03/23/2016 22165.0 ug/L1 Vinyl chloride ND 03/23/2016 22161.0 ug/L1 Xylenes (total)ND 03/23/2016 22161.0 ug/L1 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 108 70-130 1,2-Dichloroethane-d4 108 70-130 Toluene-d8 101 70-130 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 125 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - LCS Batch:Prep Method: Sample ID:RQ99192-002 99192 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Acetone 120 03/23/2016 211712510060-1401 Acrolein 540 03/23/2016 211710850060-1401 Acrylonitrile 100 03/23/2016 211710110070-1301 Benzene 52 03/23/2016 21171055070-1301 Bromochloromethane 48 03/23/2016 2117975070-1301 Bromodichloromethane 54 03/23/2016 21171075070-1301 Bromoform 48 03/23/2016 2117975070-1301 Bromomethane (Methyl bromide)59 03/23/2016 21171185060-1401 2-Butanone (MEK)98 03/23/2016 21179810060-1401 Carbon disulfide 51 03/23/2016 21171015060-1401 Carbon tetrachloride 53 03/23/2016 21171065070-1301 2-Chloro-1,3-Butadiene (Chloroprene)59 03/23/2016 21171185070-1301 Chlorobenzene 53 03/23/2016 21171065070-1301 Chloroethane 52 03/23/2016 21171035060-1401 Chloroform 53 03/23/2016 21171065070-1301 Chloromethane (Methyl chloride)54 03/23/2016 21171085060-1401 3-Chloropropene (Allyl chloride)53 03/23/2016 21171055070-1301 1,2-Dibromo-3-chloropropane (DBCP)57 03/23/2016 21171145070-1301 Dibromochloromethane 51 03/23/2016 21171025070-1301 1,2-Dibromoethane (EDB)53 03/23/2016 21171065070-1301 Dibromomethane (Methylene bromide)54 03/23/2016 21171075070-1301 trans-1,4-Dichloro-2-butene 44 03/23/2016 2117895034-1421 1,4-Dichlorobenzene 52 03/23/2016 21171045070-1301 1,2-Dichlorobenzene 56 03/23/2016 21171115070-1301 1,3-Dichlorobenzene 54 03/23/2016 21171075070-1301 Dichlorodifluoromethane 54 03/23/2016 21171085060-1401 1,2-Dichloroethane 54 03/23/2016 21171085070-1301 1,1-Dichloroethane 54 03/23/2016 21171095070-1301 trans-1,2-Dichloroethene 51 03/23/2016 21171035070-1301 1,1-Dichloroethene 51 03/23/2016 21171015070-1301 cis-1,2-Dichloroethene 47 03/23/2016 2117945070-1301 2,2-Dichloropropane 50 03/23/2016 2117995070-1301 1,2-Dichloropropane 51 03/23/2016 21171015070-1301 1,3-Dichloropropane 56 03/23/2016 21171125070-1301 trans-1,3-Dichloropropene 55 03/23/2016 21171105070-1301 1,1-Dichloropropene 53 03/23/2016 21171055070-1301 cis-1,3-Dichloropropene 53 03/23/2016 21171065070-1301 Ethyl methacrylate 51 03/23/2016 21171015070-1301 Ethylbenzene 53 03/23/2016 21171065070-1301 2-Hexanone 110 03/23/2016 211711010060-1401 Isobutyl alcohol 610 03/23/2016 211712250070-1301 Methacrylonitrile 270 03/23/2016 211710925070-1301 Methyl iodide (Iodomethane)51 03/23/2016 21171015070-1301 Methyl methacrylate 52 03/23/2016 21171045070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 126 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - LCS Batch:Prep Method: Sample ID:RQ99192-002 99192 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) 4-Methyl-2-pentanone 110 03/23/2016 211710910060-1401 Methylene chloride 55 03/23/2016 21171095070-1301 Propionitrile (Ethyl cyanide)550 03/23/2016 211711050070-1301 Styrene 52 03/23/2016 21171045070-1301 1,1,2,2-Tetrachloroethane 53 03/23/2016 21171075060-1401 1,1,1,2-Tetrachloroethane 53 03/23/2016 21171065070-1301 Tetrachloroethene 55 03/23/2016 21171105070-1301 Toluene 52 03/23/2016 21171045070-1301 1,1,2-Trichloroethane 49 03/23/2016 2117985070-1301 1,1,1-Trichloroethane 52 03/23/2016 21171035070-1301 Trichloroethene 49 03/23/2016 2117985070-1301 Trichlorofluoromethane 51 03/23/2016 21171025070-1301 1,2,3-Trichloropropane 58 03/23/2016 21171165070-1301 Vinyl acetate 48 03/23/2016 2117965060-1401 Vinyl chloride 51 03/23/2016 21171035070-1301 Xylenes (total)110 03/23/2016 211711010070-1301 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 106 70-130 1,2-Dichloroethane-d4 105 70-130 Toluene-d8 101 70-130 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 127 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - MS Batch:Prep Method: Sample ID:RC18024-015MS 99192 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(ug/L)(ug/L)(ug/L) Acetone 130 03/24/2016 065512710060-140ND1 Acrolein 430 03/24/2016 06558650026-134ND1 Acrylonitrile 97 03/24/2016 06559710070-122ND1 Benzene 54 03/24/2016 06551075072-127ND1 Bromochloromethane 50 03/24/2016 06551005070-130ND1 Bromodichloromethane 55 03/24/2016 06551095071-143ND1 Bromoform 44 03/24/2016 0655875065-131ND1 Bromomethane (Methyl bromide)64 03/24/2016 06551285036-168ND1 2-Butanone (MEK)100 03/24/2016 065510210060-140ND1 Carbon disulfide 47 03/24/2016 0655945060-140ND1 Carbon tetrachloride 55 03/24/2016 06551095037-166ND1 2-Chloro-1,3-Butadiene (Chloroprene)63 03/24/2016 06551265070-130ND1 Chlorobenzene 55 03/24/2016 06551095078-129ND1 Chloroethane 58 03/24/2016 06551155060-140ND1 Chloroform 56 03/24/2016 06551125063-123ND1 Chloromethane (Methyl chloride)62 03/24/2016 06551245020-158ND1 3-Chloropropene (Allyl chloride)48 03/24/2016 0655975070-130ND1 1,2-Dibromo-3-chloropropane (DBCP)58 03/24/2016 06551165070-130ND1 Dibromochloromethane 49 03/24/2016 0655995074-134ND1 1,2-Dibromoethane (EDB)54 03/24/2016 06551085070-130ND1 Dibromomethane (Methylene bromide)54 03/24/2016 06551095070-130ND1 trans-1,4-Dichloro-2-butene 29 03/24/2016 0655585034-142ND1 1,2-Dichlorobenzene 56 03/24/2016 06551125070-130ND1 1,3-Dichlorobenzene 53 03/24/2016 06551065070-130ND1 1,4-Dichlorobenzene 53 03/24/2016 06551065070-130ND1 Dichlorodifluoromethane 61 03/24/2016 06551225010-158ND1 1,1-Dichloroethane 58 03/24/2016 06551165069-132ND1 1,2-Dichloroethane 57 03/24/2016 06551135059-143ND1 1,1-Dichloroethene 53 03/24/2016 06551065050-132ND1 cis-1,2-Dichloroethene 49 03/24/2016 0655975070-130ND1 trans-1,2-Dichloroethene 54 03/24/2016 06551075067-141ND1 1,2-Dichloropropane 52 03/24/2016 06551035071-126ND1 1,3-Dichloropropane 57 03/24/2016 06551135070-130ND1 2,2-Dichloropropane 52 03/24/2016 06551055070-130ND1 1,1-Dichloropropene 56 03/24/2016 06551115070-130ND1 cis-1,3-Dichloropropene 51 03/24/2016 06551025069-130ND1 trans-1,3-Dichloropropene 53 03/24/2016 06551065073-131ND1 Ethyl methacrylate 51 03/24/2016 06551025070-130ND1 Ethylbenzene 55 03/24/2016 06551105079-132ND1 2-Hexanone 110 03/24/2016 065511510060-140ND1 Isobutyl alcohol 650 03/24/2016 065513050070-130ND1 Methacrylonitrile 280 03/24/2016 065511025070-130ND1 Methyl iodide (Iodomethane)54 03/24/2016 06551095070-130ND1 Methyl methacrylate 52 03/24/2016 06551045070-130ND1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 128 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - MS Batch:Prep Method: Sample ID:RC18024-015MS 99192 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(ug/L)(ug/L)(ug/L) 4-Methyl-2-pentanone 110 03/24/2016 065511010060-140ND1 Methylene chloride 57 03/24/2016 06551145069-129ND1 Propionitrile (Ethyl cyanide)560 03/24/2016 065511150070-130ND1 Styrene 52 03/24/2016 06551045070-130ND1 1,1,1,2-Tetrachloroethane 53 03/24/2016 06551065070-130ND1 1,1,2,2-Tetrachloroethane 53 03/24/2016 06551055060-155ND1 Tetrachloroethene 55 03/24/2016 06551105070-130ND1 Toluene 54 03/24/2016 06551085075-125ND1 1,1,1-Trichloroethane 58 03/24/2016 06551165077-132ND1 1,1,2-Trichloroethane 49 03/24/2016 0655995077-132ND1 Trichloroethene 49 03/24/2016 0655975073-124ND1 Trichlorofluoromethane 60 03/24/2016 06551215041-173ND1 1,2,3-Trichloropropane 57 03/24/2016 06551155070-130ND1 Vinyl acetate 40 03/24/2016 0655805060-140ND1 Vinyl chloride 58 03/24/2016 06551155029-159ND1 Xylenes (total)110 03/24/2016 065511210070-130ND1 Surrogate Q % Rec Acceptance Limit 1,2-Dichloroethane-d4 107 70-130 Bromofluorobenzene 107 70-130 Toluene-d8 101 70-130 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 129 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - Duplicate Batch:Prep Method: Sample ID:RC18024-016DU 99192 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q Analysis Date% RPD % RPD Limit Sample Amount Dil(ug/L)(ug/L) Acetone ND 03/24/2016 06320.00 20ND1 Acrolein ND 03/24/2016 06320.00 20ND1 Acrylonitrile ND 03/24/2016 06320.00 20ND1 Benzene ND 03/24/2016 06320.00 20ND1 Bromochloromethane ND 03/24/2016 06320.00 20ND1 Bromodichloromethane ND 03/24/2016 06320.00 20ND1 Bromoform ND 03/24/2016 06320.00 20ND1 Bromomethane (Methyl bromide)ND 03/24/2016 06320.00 20ND1 2-Butanone (MEK)ND 03/24/2016 06320.00 20ND1 Carbon disulfide ND 03/24/2016 06320.00 20ND1 Carbon tetrachloride ND 03/24/2016 06320.00 20ND1 2-Chloro-1,3-Butadiene (Chloroprene)ND 03/24/2016 06320.00 20ND1 Chlorobenzene ND 03/24/2016 06320.00 20ND1 Chloroethane ND 03/24/2016 06320.00 20ND1 Chloroform ND 03/24/2016 06320.00 20ND1 Chloromethane (Methyl chloride)ND 03/24/2016 06320.00 20ND1 3-Chloropropene (Allyl chloride)ND 03/24/2016 06320.00 20ND1 1,2-Dibromo-3-chloropropane (DBCP)ND 03/24/2016 06320.00 20ND1 Dibromochloromethane ND 03/24/2016 06320.00 20ND1 1,2-Dibromoethane (EDB)ND 03/24/2016 06320.00 20ND1 Dibromomethane (Methylene bromide)ND 03/24/2016 06320.00 20ND1 trans-1,4-Dichloro-2-butene ND 03/24/2016 06320.00 20ND1 1,2-Dichlorobenzene ND 03/24/2016 06320.00 20ND1 1,3-Dichlorobenzene ND 03/24/2016 06320.00 20ND1 1,4-Dichlorobenzene ND 03/24/2016 06320.00 20ND1 Dichlorodifluoromethane ND 03/24/2016 06320.00 20ND1 1,1-Dichloroethane 1.2 03/24/2016 06326.0 201.1 1 1,2-Dichloroethane ND 03/24/2016 06320.00 20ND1 1,1-Dichloroethene ND 03/24/2016 06320.00 20ND1 cis-1,2-Dichloroethene ND 03/24/2016 06320.00 20ND1 trans-1,2-Dichloroethene ND 03/24/2016 06320.00 20ND1 1,2-Dichloropropane ND 03/24/2016 06320.00 20ND1 1,3-Dichloropropane ND 03/24/2016 06320.00 20ND1 2,2-Dichloropropane ND 03/24/2016 06320.00 20ND1 1,1-Dichloropropene ND 03/24/2016 06320.00 20ND1 cis-1,3-Dichloropropene ND 03/24/2016 06320.00 20ND1 trans-1,3-Dichloropropene ND 03/24/2016 06320.00 20ND1 Ethyl methacrylate ND 03/24/2016 06320.00 20ND1 Ethylbenzene ND 03/24/2016 06320.00 20ND1 2-Hexanone ND 03/24/2016 06320.00 20ND1 Isobutyl alcohol ND 03/24/2016 06320.00 20ND1 Methacrylonitrile ND 03/24/2016 06320.00 20ND1 Methyl iodide (Iodomethane)ND 03/24/2016 06320.00 20ND1 Methyl methacrylate ND 03/24/2016 06320.00 20ND1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 130 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - Duplicate Batch:Prep Method: Sample ID:RC18024-016DU 99192 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q Analysis Date% RPD % RPD Limit Sample Amount Dil(ug/L)(ug/L) 4-Methyl-2-pentanone ND 03/24/2016 06320.00 20ND1 Methylene chloride ND 03/24/2016 06320.00 20ND1 Propionitrile (Ethyl cyanide)ND 03/24/2016 06320.00 20ND1 Styrene ND 03/24/2016 06320.00 20ND1 1,1,1,2-Tetrachloroethane ND 03/24/2016 06320.00 20ND1 1,1,2,2-Tetrachloroethane ND 03/24/2016 06320.00 20ND1 Tetrachloroethene ND 03/24/2016 06320.00 20ND1 Toluene ND 03/24/2016 06320.00 20ND1 1,1,1-Trichloroethane ND 03/24/2016 06320.00 20ND1 1,1,2-Trichloroethane ND 03/24/2016 06320.00 20ND1 Trichloroethene ND 03/24/2016 06320.00 20ND1 Trichlorofluoromethane ND 03/24/2016 06320.00 20ND1 1,2,3-Trichloropropane ND 03/24/2016 06320.00 20ND1 Vinyl acetate ND 03/24/2016 06320.00 20ND1 Vinyl chloride ND 03/24/2016 06320.00 20ND1 Xylenes (total)ND 03/24/2016 06320.00 20ND1 Surrogate Q % Rec Acceptance Limit 1,2-Dichloroethane-d4 110 70-130 Bromofluorobenzene 107 70-130 Toluene-d8 100 70-130 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 131 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - MB Batch:Prep Method: Sample ID:RQ99362-001 99362 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Acetone ND 03/25/2016 144920ug/L1 Acetonitrile ND 03/25/2016 144920ug/L1 Acrolein ND 03/25/2016 144920ug/L1 Acrylonitrile ND 03/25/2016 144920ug/L1 Benzene ND 03/25/2016 14491.0 ug/L1 Bromochloromethane ND 03/25/2016 14491.0 ug/L1 Bromodichloromethane ND 03/25/2016 14491.0 ug/L1 Bromoform ND 03/25/2016 14491.0 ug/L1 Bromomethane (Methyl bromide)ND 03/25/2016 14492.0 ug/L1 2-Butanone (MEK)ND 03/25/2016 144910ug/L1 Carbon disulfide ND 03/25/2016 14491.0 ug/L1 Carbon tetrachloride ND 03/25/2016 14491.0 ug/L1 2-Chloro-1,3-Butadiene (Chloroprene)ND 03/25/2016 14495.0 ug/L1 Chlorobenzene ND 03/25/2016 14491.0 ug/L1 Chloroethane ND 03/25/2016 14492.0 ug/L1 Chloroform ND 03/25/2016 14491.0 ug/L1 Chloromethane (Methyl chloride)ND 03/25/2016 14491.0 ug/L1 3-Chloropropene (Allyl chloride)ND 03/25/2016 14492.0 ug/L1 1,2-Dibromo-3-chloropropane (DBCP)ND 03/25/2016 14491.0 ug/L1 Dibromochloromethane ND 03/25/2016 14491.0 ug/L1 1,2-Dibromoethane (EDB)ND 03/25/2016 14491.0 ug/L1 Dibromomethane (Methylene bromide)ND 03/25/2016 14491.0 ug/L1 trans-1,4-Dichloro-2-butene ND 03/25/2016 14492.0 ug/L1 1,4-Dichlorobenzene ND 03/25/2016 14491.0 ug/L1 1,3-Dichlorobenzene ND 03/25/2016 14491.0 ug/L1 1,2-Dichlorobenzene ND 03/25/2016 14491.0 ug/L1 Dichlorodifluoromethane ND 03/25/2016 14492.0 ug/L1 1,1-Dichloroethane ND 03/25/2016 14491.0 ug/L1 1,2-Dichloroethane ND 03/25/2016 14491.0 ug/L1 cis-1,2-Dichloroethene ND 03/25/2016 14491.0 ug/L1 1,1-Dichloroethene ND 03/25/2016 14491.0 ug/L1 trans-1,2-Dichloroethene ND 03/25/2016 14491.0 ug/L1 1,3-Dichloropropane ND 03/25/2016 14491.0 ug/L1 2,2-Dichloropropane ND 03/25/2016 14491.0 ug/L1 1,2-Dichloropropane ND 03/25/2016 14491.0 ug/L1 trans-1,3-Dichloropropene ND 03/25/2016 14491.0 ug/L1 cis-1,3-Dichloropropene ND 03/25/2016 14491.0 ug/L1 1,1-Dichloropropene ND 03/25/2016 14492.0 ug/L1 Ethyl methacrylate ND 03/25/2016 14495.0 ug/L1 Ethylbenzene ND 03/25/2016 14491.0 ug/L1 2-Hexanone ND 03/25/2016 144910ug/L1 Isobutyl alcohol ND 03/25/2016 144950ug/L1 Methacrylonitrile ND 03/25/2016 14495.0 ug/L1 Methyl iodide (Iodomethane)ND 03/25/2016 14495.0 ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 132 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - MB Batch:Prep Method: Sample ID:RQ99362-001 99362 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methyl methacrylate ND 03/25/2016 14495.0 ug/L1 4-Methyl-2-pentanone ND 03/25/2016 144910ug/L1 Methylene chloride ND 03/25/2016 14491.0 ug/L1 Propionitrile (Ethyl cyanide)ND 03/25/2016 144920ug/L1 Styrene ND 03/25/2016 14491.0 ug/L1 1,1,1,2-Tetrachloroethane ND 03/25/2016 14491.0 ug/L1 1,1,2,2-Tetrachloroethane ND 03/25/2016 14491.0 ug/L1 Tetrachloroethene ND 03/25/2016 14491.0 ug/L1 Toluene ND 03/25/2016 14491.0 ug/L1 1,1,2-Trichloroethane ND 03/25/2016 14491.0 ug/L1 1,1,1-Trichloroethane ND 03/25/2016 14491.0 ug/L1 Trichloroethene ND 03/25/2016 14491.0 ug/L1 Trichlorofluoromethane ND 03/25/2016 14491.0 ug/L1 1,2,3-Trichloropropane ND 03/25/2016 14491.0 ug/L1 Vinyl acetate ND 03/25/2016 14495.0 ug/L1 Vinyl chloride ND 03/25/2016 14491.0 ug/L1 Xylenes (total)ND 03/25/2016 14491.0 ug/L1 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 118 70-130 1,2-Dichloroethane-d4 105 70-130 Toluene-d8 111 70-130 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 133 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - LCS Batch:Prep Method: Sample ID:RQ99362-002 99362 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Acetone 120 03/25/2016 140511510060-1401 Acetonitrile 540 03/25/2016 140510850060-1401 Acrolein 590 03/25/2016 140511750060-1401 Acrylonitrile 110 03/25/2016 140511410070-1301 Benzene 52 03/25/2016 14051045070-1301 Bromochloromethane 56 03/25/2016 14051135070-1301 Bromodichloromethane 54 03/25/2016 14051095070-1301 Bromoform 53 03/25/2016 14051065070-1301 Bromomethane (Methyl bromide)48 03/25/2016 1405955060-1401 2-Butanone (MEK)120 03/25/2016 140511610060-1401 Carbon disulfide 52 03/25/2016 14051045060-1401 Carbon tetrachloride 56 03/25/2016 14051125070-1301 2-Chloro-1,3-Butadiene (Chloroprene)58 03/25/2016 14051175070-1301 Chlorobenzene 54 03/25/2016 14051085070-1301 Chloroethane 51 03/25/2016 14051025060-1401 Chloroform 55 03/25/2016 14051115070-1301 Chloromethane (Methyl chloride)47 03/25/2016 1405945060-1401 3-Chloropropene (Allyl chloride)52 03/25/2016 14051045070-1301 1,2-Dibromo-3-chloropropane (DBCP)54 03/25/2016 14051085070-1301 Dibromochloromethane 55 03/25/2016 14051095070-1301 1,2-Dibromoethane (EDB)56 03/25/2016 14051125070-1301 Dibromomethane (Methylene bromide)55 03/25/2016 14051095070-1301 trans-1,4-Dichloro-2-butene 52 03/25/2016 14051035034-1421 1,4-Dichlorobenzene 53 03/25/2016 14051075070-1301 1,3-Dichlorobenzene 54 03/25/2016 14051085070-1301 1,2-Dichlorobenzene 57 03/25/2016 14051145070-1301 Dichlorodifluoromethane 48 03/25/2016 1405955060-1401 1,1-Dichloroethane 56 03/25/2016 14051135070-1301 1,2-Dichloroethane 51 03/25/2016 14051035070-1301 cis-1,2-Dichloroethene 53 03/25/2016 14051075070-1301 1,1-Dichloroethene 55 03/25/2016 14051105070-1301 trans-1,2-Dichloroethene 53 03/25/2016 14051055070-1301 1,3-Dichloropropane 53 03/25/2016 14051075070-1301 2,2-Dichloropropane 50 03/25/2016 14051015070-1301 1,2-Dichloropropane 54 03/25/2016 14051085070-1301 trans-1,3-Dichloropropene 53 03/25/2016 14051065070-1301 cis-1,3-Dichloropropene 53 03/25/2016 14051075070-1301 1,1-Dichloropropene 54 03/25/2016 14051075070-1301 Ethyl methacrylate 55 03/25/2016 14051105070-1301 Ethylbenzene 54 03/25/2016 14051095070-1301 2-Hexanone 110 03/25/2016 140510910060-1401 Isobutyl alcohol 540 03/25/2016 140510850070-1301 Methacrylonitrile 310 03/25/2016 140512225070-1301 Methyl iodide (Iodomethane)53 03/25/2016 14051075070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 134 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - LCS Batch:Prep Method: Sample ID:RQ99362-002 99362 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methyl methacrylate 55 03/25/2016 14051105070-1301 4-Methyl-2-pentanone 110 03/25/2016 140511410060-1401 Methylene chloride 55 03/25/2016 14051105070-1301 Propionitrile (Ethyl cyanide)620 03/25/2016 140512450070-1301 Styrene 55 03/25/2016 14051105070-1301 1,1,1,2-Tetrachloroethane 55 03/25/2016 14051105070-1301 1,1,2,2-Tetrachloroethane 56 03/25/2016 14051125060-1401 Tetrachloroethene 57 03/25/2016 14051155070-1301 Toluene 53 03/25/2016 14051055070-1301 1,1,2-Trichloroethane 52 03/25/2016 14051055070-1301 1,1,1-Trichloroethane 55 03/25/2016 14051105070-1301 Trichloroethene 51 03/25/2016 14051025070-1301 Trichlorofluoromethane 50 03/25/2016 14051005070-1301 1,2,3-Trichloropropane 56 03/25/2016 14051125070-1301 Vinyl acetate 55 03/25/2016 14051115060-1401 Vinyl chloride 51 03/25/2016 14051025070-1301 Xylenes (total)110 03/25/2016 140511210070-1301 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 113 70-130 1,2-Dichloroethane-d4 105 70-130 Toluene-d8 108 70-130 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 135 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - Duplicate Batch:Prep Method: Sample ID:RC18024-019DU 99362 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q Analysis Date% RPD % RPD Limit Sample Amount Dil(ug/L)(ug/L) Acetone ND 03/25/2016 21470.00 20ND1 Acetonitrile ND 03/25/2016 21470.00 20ND1 Acrolein ND 03/25/2016 21470.00 20ND1 Acrylonitrile ND 03/25/2016 21470.00 20ND1 Benzene ND 03/25/2016 21470.00 20ND1 Bromochloromethane ND 03/25/2016 21470.00 20ND1 Bromodichloromethane ND 03/25/2016 21470.00 20ND1 Bromoform ND 03/25/2016 21470.00 20ND1 Bromomethane (Methyl bromide)ND 03/25/2016 21470.00 20ND1 2-Butanone (MEK)ND 03/25/2016 21470.00 20ND1 Carbon disulfide ND 03/25/2016 21470.00 20ND1 Carbon tetrachloride ND 03/25/2016 21470.00 20ND1 2-Chloro-1,3-Butadiene (Chloroprene)ND 03/25/2016 21470.00 20ND1 Chlorobenzene ND 03/25/2016 21470.00 20ND1 Chloroethane ND 03/25/2016 21470.00 20ND1 Chloroform ND 03/25/2016 21470.00 20ND1 Chloromethane (Methyl chloride)ND 03/25/2016 21470.00 20ND1 3-Chloropropene (Allyl chloride)ND 03/25/2016 21470.00 20ND1 1,2-Dibromo-3-chloropropane (DBCP)ND 03/25/2016 21470.00 20ND1 Dibromochloromethane ND 03/25/2016 21470.00 20ND1 1,2-Dibromoethane (EDB)ND 03/25/2016 21470.00 20ND1 Dibromomethane (Methylene bromide)ND 03/25/2016 21470.00 20ND1 trans-1,4-Dichloro-2-butene ND 03/25/2016 21470.00 20ND1 1,2-Dichlorobenzene ND 03/25/2016 21470.00 20ND1 1,3-Dichlorobenzene ND 03/25/2016 21470.00 20ND1 1,4-Dichlorobenzene ND 03/25/2016 21470.00 20ND1 Dichlorodifluoromethane ND 03/25/2016 21470.00 20ND1 1,1-Dichloroethane ND 03/25/2016 21470.00 20ND1 1,2-Dichloroethane ND 03/25/2016 21470.00 20ND1 1,1-Dichloroethene ND 03/25/2016 21470.00 20ND1 cis-1,2-Dichloroethene ND 03/25/2016 21470.00 20ND1 trans-1,2-Dichloroethene ND 03/25/2016 21470.00 20ND1 1,2-Dichloropropane ND 03/25/2016 21470.00 20ND1 1,3-Dichloropropane ND 03/25/2016 21470.00 20ND1 2,2-Dichloropropane ND 03/25/2016 21470.00 20ND1 1,1-Dichloropropene ND 03/25/2016 21470.00 20ND1 cis-1,3-Dichloropropene ND 03/25/2016 21470.00 20ND1 trans-1,3-Dichloropropene ND 03/25/2016 21470.00 20ND1 Ethyl methacrylate ND 03/25/2016 21470.00 20ND1 Ethylbenzene ND 03/25/2016 21470.00 20ND1 2-Hexanone ND 03/25/2016 21470.00 20ND1 Isobutyl alcohol ND 03/25/2016 21470.00 20ND1 Methacrylonitrile ND 03/25/2016 21470.00 20ND1 Methyl iodide (Iodomethane)ND 03/25/2016 21470.00 20ND1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 136 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - Duplicate Batch:Prep Method: Sample ID:RC18024-019DU 99362 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q Analysis Date% RPD % RPD Limit Sample Amount Dil(ug/L)(ug/L) Methyl methacrylate ND 03/25/2016 21470.00 20ND1 4-Methyl-2-pentanone ND 03/25/2016 21470.00 20ND1 Methylene chloride ND 03/25/2016 21470.00 20ND1 Propionitrile (Ethyl cyanide)ND 03/25/2016 21470.00 20ND1 Styrene ND 03/25/2016 21470.00 20ND1 1,1,1,2-Tetrachloroethane ND 03/25/2016 21470.00 20ND1 1,1,2,2-Tetrachloroethane ND 03/25/2016 21470.00 20ND1 Tetrachloroethene ND 03/25/2016 21470.00 20ND1 Toluene ND 03/25/2016 21470.00 20ND1 1,1,1-Trichloroethane ND 03/25/2016 21470.00 20ND1 1,1,2-Trichloroethane ND 03/25/2016 21470.00 20ND1 Trichloroethene ND 03/25/2016 21470.00 20ND1 Trichlorofluoromethane ND 03/25/2016 21470.00 20ND1 1,2,3-Trichloropropane ND 03/25/2016 21470.00 20ND1 Vinyl acetate ND 03/25/2016 21470.00 20ND1 Vinyl chloride ND 03/25/2016 21470.00 20ND1 Xylenes (total)ND 03/25/2016 21470.00 20ND1 Surrogate Q % Rec Acceptance Limit 1,2-Dichloroethane-d4 119 70-130 Bromofluorobenzene 117 70-130 Toluene-d8 111 70-130 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 137 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - MS Batch:Prep Method: Sample ID:RC18024-020MS 99362 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(ug/L)(ug/L)(ug/L) Acetone 110 03/25/2016 220811410060-140ND1 Acetonitrile 580 03/25/2016 220811650060-140ND1 Acrolein 550 03/25/2016 220810950026-134ND1 Acrylonitrile 110 03/25/2016 220810610070-122ND1 Benzene 54 03/25/2016 22081075072-127ND1 Bromochloromethane 55 03/25/2016 22081115070-130ND1 Bromodichloromethane 57 03/25/2016 22081135071-143ND1 Bromoform 52 03/25/2016 22081055065-131ND1 Bromomethane (Methyl bromide)57 03/25/2016 22081135036-168ND1 2-Butanone (MEK)120 03/25/2016 220811810060-140ND1 Carbon disulfide 58 03/25/2016 22081155060-140ND1 Carbon tetrachloride 63 03/25/2016 22081275037-166ND1 2-Chloro-1,3-Butadiene (Chloroprene)65 03/25/2016 22081295070-130ND1 Chlorobenzene 56 03/25/2016 22081125078-129ND1 Chloroethane 59 03/25/2016 22081185060-140ND1 Chloroform 58 03/25/2016 22081165063-123ND1 Chloromethane (Methyl chloride)58 03/25/2016 22081165020-158ND1 3-Chloropropene (Allyl chloride)53 03/25/2016 22081075070-130ND1 1,2-Dibromo-3-chloropropane (DBCP)55 03/25/2016 22081105070-130ND1 Dibromochloromethane 55 03/25/2016 22081105074-134ND1 1,2-Dibromoethane (EDB)57 03/25/2016 22081145070-130ND1 Dibromomethane (Methylene bromide)56 03/25/2016 22081125070-130ND1 trans-1,4-Dichloro-2-butene 47 03/25/2016 2208945034-142ND1 1,2-Dichlorobenzene 57 03/25/2016 22081155070-130ND1 1,3-Dichlorobenzene 55 03/25/2016 22081095070-130ND1 1,4-Dichlorobenzene 55 03/25/2016 22081105070-130ND1 Dichlorodifluoromethane 66 03/25/2016 22081315010-158ND1 1,1-Dichloroethane 59 03/25/2016 22081185069-132ND1 1,2-Dichloroethane 54 03/25/2016 22081085059-143ND1 1,1-Dichloroethene 59 03/25/2016 22081195050-132ND1 cis-1,2-Dichloroethene 54 03/25/2016 22081095070-130ND1 trans-1,2-Dichloroethene 55 03/25/2016 22081105067-141ND1 1,2-Dichloropropane 54 03/25/2016 22081085071-126ND1 1,3-Dichloropropane 54 03/25/2016 22081095070-130ND1 2,2-Dichloropropane 61 03/25/2016 22081225070-130ND1 1,1-Dichloropropene 58 03/25/2016 22081165070-130ND1 cis-1,3-Dichloropropene 55 03/25/2016 22081105069-130ND1 trans-1,3-Dichloropropene 53 03/25/2016 22081065073-131ND1 Ethyl methacrylate 55 03/25/2016 22081105070-130ND1 Ethylbenzene 57 03/25/2016 22081145079-132ND1 2-Hexanone 110 03/25/2016 220811210060-140ND1 Isobutyl alcohol 550 03/25/2016 220811050070-130ND1 Methacrylonitrile 290 03/25/2016 220811725070-130ND1 Methyl iodide (Iodomethane)57 03/25/2016 22081145070-130ND1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 138 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - MS Batch:Prep Method: Sample ID:RC18024-020MS 99362 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(ug/L)(ug/L)(ug/L) Methyl methacrylate 56 03/25/2016 22081135070-130ND1 4-Methyl-2-pentanone 120 03/25/2016 220811710060-140ND1 Methylene chloride 57 03/25/2016 22081145069-129ND1 Propionitrile (Ethyl cyanide)590 03/25/2016 220811750070-130ND1 Styrene 57 03/25/2016 22081145070-130ND1 1,1,1,2-Tetrachloroethane 58 03/25/2016 22081155070-130ND1 1,1,2,2-Tetrachloroethane 54 03/25/2016 22081085060-155ND1 Tetrachloroethene 63 03/25/2016 22081255070-130ND1 Toluene 55 03/25/2016 22081095075-125ND1 1,1,1-Trichloroethane 63 03/25/2016 22081275077-132ND1 1,1,2-Trichloroethane 53 03/25/2016 22081065077-132ND1 Trichloroethene 54 03/25/2016 22081095073-124ND1 Trichlorofluoromethane 64 03/25/2016 22081285041-173ND1 1,2,3-Trichloropropane 55 03/25/2016 22081115070-130ND1 Vinyl acetate 52 03/25/2016 22081045060-140ND1 Vinyl chloride 61 03/25/2016 22081225029-159ND1 Xylenes (total)120 03/25/2016 220811810070-130ND1 Surrogate Q % Rec Acceptance Limit 1,2-Dichloroethane-d4 106 70-130 Bromofluorobenzene 112 70-130 Toluene-d8 108 70-130 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 139 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - MB Batch:Prep Method: Sample ID:RQ99475-001 99475 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Acetone ND 03/28/2016 094220ug/L1 Acetonitrile ND 03/28/2016 094220ug/L1 Acrolein ND 03/28/2016 094220ug/L1 Acrylonitrile ND 03/28/2016 094220ug/L1 Benzene ND 03/28/2016 09421.0 ug/L1 Bromochloromethane ND 03/28/2016 09421.0 ug/L1 Bromodichloromethane ND 03/28/2016 09421.0 ug/L1 Bromoform ND 03/28/2016 09421.0 ug/L1 Bromomethane (Methyl bromide)ND 03/28/2016 09422.0 ug/L1 2-Butanone (MEK)ND 03/28/2016 094210ug/L1 Carbon disulfide ND 03/28/2016 09421.0 ug/L1 Carbon tetrachloride ND 03/28/2016 09421.0 ug/L1 2-Chloro-1,3-Butadiene (Chloroprene)ND 03/28/2016 09425.0 ug/L1 Chlorobenzene ND 03/28/2016 09421.0 ug/L1 Chloroethane ND 03/28/2016 09422.0 ug/L1 Chloroform ND 03/28/2016 09421.0 ug/L1 Chloromethane (Methyl chloride)ND 03/28/2016 09421.0 ug/L1 3-Chloropropene (Allyl chloride)ND 03/28/2016 09422.0 ug/L1 1,2-Dibromo-3-chloropropane (DBCP)ND 03/28/2016 09421.0 ug/L1 Dibromochloromethane ND 03/28/2016 09421.0 ug/L1 1,2-Dibromoethane (EDB)ND 03/28/2016 09421.0 ug/L1 Dibromomethane (Methylene bromide)ND 03/28/2016 09421.0 ug/L1 trans-1,4-Dichloro-2-butene ND 03/28/2016 09422.0 ug/L1 1,4-Dichlorobenzene ND 03/28/2016 09421.0 ug/L1 1,3-Dichlorobenzene ND 03/28/2016 09421.0 ug/L1 1,2-Dichlorobenzene ND 03/28/2016 09421.0 ug/L1 Dichlorodifluoromethane ND 03/28/2016 09422.0 ug/L1 1,1-Dichloroethane ND 03/28/2016 09421.0 ug/L1 1,2-Dichloroethane ND 03/28/2016 09421.0 ug/L1 cis-1,2-Dichloroethene ND 03/28/2016 09421.0 ug/L1 1,1-Dichloroethene ND 03/28/2016 09421.0 ug/L1 trans-1,2-Dichloroethene ND 03/28/2016 09421.0 ug/L1 1,3-Dichloropropane ND 03/28/2016 09421.0 ug/L1 2,2-Dichloropropane ND 03/28/2016 09421.0 ug/L1 1,2-Dichloropropane ND 03/28/2016 09421.0 ug/L1 trans-1,3-Dichloropropene ND 03/28/2016 09421.0 ug/L1 cis-1,3-Dichloropropene ND 03/28/2016 09421.0 ug/L1 1,1-Dichloropropene ND 03/28/2016 09422.0 ug/L1 Ethyl methacrylate ND 03/28/2016 09425.0 ug/L1 Ethylbenzene ND 03/28/2016 09421.0 ug/L1 2-Hexanone ND 03/28/2016 094210ug/L1 Isobutyl alcohol ND 03/28/2016 094250ug/L1 Methacrylonitrile ND 03/28/2016 09425.0 ug/L1 Methyl iodide (Iodomethane)ND 03/28/2016 09425.0 ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 140 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - MB Batch:Prep Method: Sample ID:RQ99475-001 99475 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methyl methacrylate ND 03/28/2016 09425.0 ug/L1 4-Methyl-2-pentanone ND 03/28/2016 094210ug/L1 Methylene chloride ND 03/28/2016 09421.0 ug/L1 Propionitrile (Ethyl cyanide)ND 03/28/2016 094220ug/L1 Styrene ND 03/28/2016 09421.0 ug/L1 1,1,1,2-Tetrachloroethane ND 03/28/2016 09421.0 ug/L1 1,1,2,2-Tetrachloroethane ND 03/28/2016 09421.0 ug/L1 Tetrachloroethene ND 03/28/2016 09421.0 ug/L1 Toluene ND 03/28/2016 09421.0 ug/L1 1,1,2-Trichloroethane ND 03/28/2016 09421.0 ug/L1 1,1,1-Trichloroethane ND 03/28/2016 09421.0 ug/L1 Trichloroethene ND 03/28/2016 09421.0 ug/L1 Trichlorofluoromethane ND 03/28/2016 09421.0 ug/L1 1,2,3-Trichloropropane ND 03/28/2016 09421.0 ug/L1 Vinyl acetate ND 03/28/2016 09425.0 ug/L1 Vinyl chloride ND 03/28/2016 09421.0 ug/L1 Xylenes (total)ND 03/28/2016 09421.0 ug/L1 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 119 70-130 1,2-Dichloroethane-d4 114 70-130 Toluene-d8 110 70-130 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 141 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - LCS Batch:Prep Method: Sample ID:RQ99475-002 99475 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Acetone 140 03/28/2016 084614010060-1401 Acetonitrile 560 03/28/2016 084611150060-1401 Acrolein 680 03/28/2016 084613550060-1401 Acrylonitrile 140 03/28/2016 0846N13710070-1301 Benzene 55 03/28/2016 08461105070-1301 Bromochloromethane 61 03/28/2016 08461225070-1301 Bromodichloromethane 61 03/28/2016 08461225070-1301 Bromoform 59 03/28/2016 08461185070-1301 Bromomethane (Methyl bromide)56 03/28/2016 08461115060-1401 2-Butanone (MEK)130 03/28/2016 084613410060-1401 Carbon disulfide 60 03/28/2016 08461205060-1401 Carbon tetrachloride 60 03/28/2016 08461205070-1301 2-Chloro-1,3-Butadiene (Chloroprene)65 03/28/2016 08461295070-1301 Chlorobenzene 59 03/28/2016 08461175070-1301 Chloroethane 58 03/28/2016 08461155060-1401 Chloroform 60 03/28/2016 08461215070-1301 Chloromethane (Methyl chloride)57 03/28/2016 08461145060-1401 3-Chloropropene (Allyl chloride)57 03/28/2016 08461135070-1301 1,2-Dibromo-3-chloropropane (DBCP)61 03/28/2016 08461215070-1301 Dibromochloromethane 59 03/28/2016 08461195070-1301 1,2-Dibromoethane (EDB)61 03/28/2016 08461215070-1301 Dibromomethane (Methylene bromide)60 03/28/2016 08461215070-1301 trans-1,4-Dichloro-2-butene 60 03/28/2016 08461215034-1421 1,4-Dichlorobenzene 57 03/28/2016 08461155070-1301 1,3-Dichlorobenzene 57 03/28/2016 08461135070-1301 1,2-Dichlorobenzene 60 03/28/2016 08461195070-1301 Dichlorodifluoromethane 58 03/28/2016 08461165060-1401 1,1-Dichloroethane 61 03/28/2016 08461225070-1301 1,2-Dichloroethane 58 03/28/2016 08461175070-1301 cis-1,2-Dichloroethene 56 03/28/2016 08461135070-1301 1,1-Dichloroethene 57 03/28/2016 08461145070-1301 trans-1,2-Dichloroethene 56 03/28/2016 08461135070-1301 1,3-Dichloropropane 59 03/28/2016 08461185070-1301 2,2-Dichloropropane 58 03/28/2016 08461165070-1301 1,2-Dichloropropane 58 03/28/2016 08461165070-1301 trans-1,3-Dichloropropene 59 03/28/2016 08461175070-1301 cis-1,3-Dichloropropene 59 03/28/2016 08461185070-1301 1,1-Dichloropropene 57 03/28/2016 08461145070-1301 Ethyl methacrylate 60 03/28/2016 08461205070-1301 Ethylbenzene 57 03/28/2016 08461155070-1301 2-Hexanone 130 03/28/2016 084612810060-1401 Isobutyl alcohol 640 03/28/2016 084612950070-1301 Methacrylonitrile 350 03/28/2016 0846N13825070-1301 Methyl iodide (Iodomethane)58 03/28/2016 08461175070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 142 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Volatile Organic Compounds by GC/MS - LCS Batch:Prep Method: Sample ID:RQ99475-002 99475 5030B Analytical Method:8260B Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methyl methacrylate 64 03/28/2016 08461285070-1301 4-Methyl-2-pentanone 130 03/28/2016 084613210060-1401 Methylene chloride 58 03/28/2016 08461175070-1301 Propionitrile (Ethyl cyanide)670 03/28/2016 0846N13450070-1301 Styrene 59 03/28/2016 08461175070-1301 1,1,1,2-Tetrachloroethane 59 03/28/2016 08461185070-1301 1,1,2,2-Tetrachloroethane 59 03/28/2016 08461185060-1401 Tetrachloroethene 61 03/28/2016 08461225070-1301 Toluene 57 03/28/2016 08461145070-1301 1,1,2-Trichloroethane 57 03/28/2016 08461135070-1301 1,1,1-Trichloroethane 61 03/28/2016 08461225070-1301 Trichloroethene 55 03/28/2016 08461105070-1301 Trichlorofluoromethane 60 03/28/2016 08461195070-1301 1,2,3-Trichloropropane 62 03/28/2016 08461235070-1301 Vinyl acetate 61 03/28/2016 08461225060-1401 Vinyl chloride 57 03/28/2016 08461145070-1301 Xylenes (total)120 03/28/2016 084612010070-1301 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 114 70-130 1,2-Dichloroethane-d4 112 70-130 Toluene-d8 111 70-130 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 143 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Organochlorine Pesticides by GC - MB Batch:Prep Method: Prep Date: Sample ID:RQ99070-001 99070 3520C 03/22/2016 1630Analytical Method:8081B Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil 4,4'-DDD ND 03/24/2016 10180.040 ug/L1 4,4'-DDE ND 03/24/2016 10180.040 ug/L1 4,4'-DDT ND 03/24/2016 10180.040 ug/L1 Aldrin ND 03/24/2016 10180.040 ug/L1 alpha-BHC ND 03/24/2016 10180.040 ug/L1 beta-BHC ND 03/24/2016 10180.040 ug/L1 Chlordane ND 03/24/2016 10180.40 ug/L1 delta-BHC ND 03/24/2016 10180.040 ug/L1 Dieldrin ND 03/24/2016 10180.040 ug/L1 Endosulfan I ND 03/24/2016 10180.040 ug/L1 Endosulfan II ND 03/24/2016 10180.040 ug/L1 Endosulfan sulfate ND 03/24/2016 10180.040 ug/L1 Endrin ND 03/24/2016 10180.040 ug/L1 Endrin aldehyde ND 03/24/2016 10180.040 ug/L1 gamma-BHC (Lindane)ND 03/24/2016 10180.040 ug/L1 Heptachlor ND 03/24/2016 10180.040 ug/L1 Heptachlor epoxide ND 03/24/2016 10180.040 ug/L1 Methoxychlor ND 03/24/2016 10180.16 ug/L1 Toxaphene ND 03/24/2016 10180.40 ug/L1 Surrogate Q % Rec Acceptance Limit Decachlorobiphenyl 78 10-122 Tetrachloro-m-xylene 81 46-119 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 144 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Organochlorine Pesticides by GC - LCS Batch:Prep Method: Prep Date: Sample ID:RQ99070-002 99070 3520C 03/22/2016 1630Analytical Method:8081B Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) 4,4'-DDD 0.75 03/24/2016 1033940.80 70-1301 4,4'-DDE 0.74 03/24/2016 1033930.80 70-1301 4,4'-DDT 0.80 03/24/2016 10331000.80 70-1301 Aldrin 0.69 03/24/2016 1033870.80 70-1301 alpha-BHC 0.75 03/24/2016 1033940.80 70-1301 beta-BHC 0.68 03/24/2016 1033850.80 70-1301 delta-BHC 0.72 03/24/2016 1033910.80 70-1301 Dieldrin 0.76 03/24/2016 1033950.80 70-1301 Endosulfan I 0.71 03/24/2016 1033880.80 70-1301 Endosulfan II 0.70 03/24/2016 1033870.80 70-1301 Endosulfan sulfate 0.77 03/24/2016 1033960.80 70-1301 Endrin 0.76 03/24/2016 1033950.80 70-1301 Endrin aldehyde 0.65 03/24/2016 1033810.80 70-1301 gamma-BHC (Lindane)0.74 03/24/2016 1033930.80 70-1301 Heptachlor 0.75 03/24/2016 1033940.80 70-1301 Heptachlor epoxide 0.73 03/24/2016 1033910.80 70-1301 Methoxychlor 0.76 03/24/2016 1033950.80 70-1301 Surrogate Q % Rec Acceptance Limit Decachlorobiphenyl 79 10-122 Tetrachloro-m-xylene 87 46-119 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 145 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Organochlorine Pesticides by GC - MS Batch:Prep Method: Prep Date: Sample ID:RC18024-005MS 99070 3520C 03/22/2016 1630Analytical Method:8081B Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(ug/L)(ug/L)(ug/L) Aldrin 0.69 03/24/2016 1117860.80 70-130ND1 gamma-BHC (Lindane)0.74 03/24/2016 1117920.80 70-130ND1 alpha-BHC 0.75 03/24/2016 1117940.80 70-130ND1 beta-BHC 0.68 03/24/2016 1117850.80 70-130ND1 delta-BHC 0.72 03/24/2016 1117900.80 70-130ND1 4,4'-DDD 0.75 03/24/2016 1117930.80 70-130ND1 4,4'-DDE 0.75 03/24/2016 1117930.80 70-130ND1 4,4'-DDT 0.79 03/24/2016 1117990.80 70-130ND1 Dieldrin 0.76 03/24/2016 1117950.80 70-130ND1 Endosulfan I 0.71 03/24/2016 1117880.80 70-130ND1 Endosulfan II 0.69 03/24/2016 1117870.80 70-130ND1 Endosulfan sulfate 0.78 03/24/2016 1117970.80 70-130ND1 Endrin 0.75 03/24/2016 1117940.80 70-130ND1 Endrin aldehyde 0.63 03/24/2016 1117790.80 70-130ND1 Heptachlor 0.73 03/24/2016 1117910.80 70-130ND1 Heptachlor epoxide 0.72 03/24/2016 1117910.80 70-130ND1 Methoxychlor 0.76 03/24/2016 1117950.80 70-130ND1 Surrogate Q % Rec Acceptance Limit Decachlorobiphenyl 81 10-122 Tetrachloro-m-xylene 85 46-119 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 146 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Organochlorine Pesticides by GC - MSD Batch:Prep Method: Prep Date: Sample ID:RC18024-005MD 99070 3520C 03/22/2016 1630Analytical Method:8081B Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD Limit Sample Amount Dil(ug/L)(ug/L)(ug/L) Aldrin 0.71 03/24/2016 1132890.80 70-1302.6 30ND1 gamma-BHC (Lindane)0.77 03/24/2016 1132960.80 70-1303.8 30ND1 alpha-BHC 0.78 03/24/2016 1132970.80 70-1303.5 30ND1 beta-BHC 0.70 03/24/2016 1132880.80 70-1303.8 30ND1 delta-BHC 0.75 03/24/2016 1132940.80 70-1304.4 30ND1 4,4'-DDD 0.77 03/24/2016 1132970.80 70-1303.6 30ND1 4,4'-DDE 0.77 03/24/2016 1132970.80 70-1303.7 30ND1 4,4'-DDT 0.84 03/24/2016 11321040.80 70-1305.2 30ND1 Dieldrin 0.79 03/24/2016 1132990.80 70-1304.0 30ND1 Endosulfan I 0.74 03/24/2016 1132920.80 70-1303.9 30ND1 Endosulfan II 0.73 03/24/2016 1132910.80 70-1304.6 30ND1 Endosulfan sulfate 0.80 03/24/2016 11321010.80 70-1303.4 30ND1 Endrin 0.79 03/24/2016 1132980.80 70-1304.3 30ND1 Endrin aldehyde 0.69 03/24/2016 1132860.80 70-1308.4 30ND1 Heptachlor 0.76 03/24/2016 1132950.80 70-1304.0 30ND1 Heptachlor epoxide 0.75 03/24/2016 1132940.80 70-1303.9 30ND1 Methoxychlor 0.80 03/24/2016 1132990.80 70-1304.8 30ND1 Surrogate Q % Rec Acceptance Limit Decachlorobiphenyl 82 10-122 Tetrachloro-m-xylene 86 46-119 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 147 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-AES - MB Batch:Prep Method: Prep Date: Sample ID:RQ98843-001 98843 3005A 03/19/2016 1211Analytical Method:6010C Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Antimony ND 03/22/2016 18350.020 mg/L1 Arsenic ND 03/22/2016 18350.015 mg/L1 Barium ND 03/22/2016 18350.025 mg/L1 Beryllium ND 03/22/2016 18350.0050 mg/L1 Cadmium ND 03/22/2016 18350.0050 mg/L1 Chromium ND 03/22/2016 18350.010 mg/L1 Cobalt ND 03/22/2016 18350.025 mg/L1 Copper ND 03/22/2016 18350.010 mg/L1 Lead ND 03/22/2016 18350.010 mg/L1 Nickel ND 03/22/2016 18350.040 mg/L1 Selenium ND 03/22/2016 18350.020 mg/L1 Silver ND 03/22/2016 18350.010 mg/L1 Thallium ND 03/22/2016 18350.050 mg/L1 Vanadium ND 03/22/2016 18350.050 mg/L1 Zinc ND 03/22/2016 18350.020 mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 148 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-AES - LCS Batch:Prep Method: Prep Date: Sample ID:RQ98843-002 98843 3005A 03/19/2016 1211Analytical Method:6010C Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Antimony 0.39 03/22/2016 1839980.40 80-1201 Arsenic 0.39 03/22/2016 1839970.40 80-1201 Barium 2.0 03/22/2016 1839992.0 80-1201 Beryllium 1.9 03/22/2016 1839972.0 80-1201 Cadmium 0.39 03/22/2016 1839980.40 80-1201 Chromium 2.1 03/22/2016 18391032.0 80-1201 Cobalt 2.0 03/22/2016 18391002.0 80-1201 Copper 2.1 03/22/2016 18391032.0 80-1201 Lead 0.42 03/22/2016 18391040.40 80-1201 Nickel 2.0 03/22/2016 18391022.0 80-1201 Selenium 0.40 03/22/2016 1839990.40 80-1201 Silver 0.42 03/22/2016 18391050.40 80-1201 Thallium 0.85 03/22/2016 18391060.80 80-1201 Vanadium 2.0 03/22/2016 18391002.0 80-1201 Zinc 2.0 03/22/2016 18391002.0 80-1201 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 149 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-AES - MS Batch:Prep Method: Prep Date: Sample ID:RC18024-001MS 98843 3005A 03/19/2016 1211Analytical Method:6010C Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Antimony 0.40 03/22/2016 18521010.40 75-125ND1 Arsenic 0.39 03/22/2016 1852990.40 75-125ND1 Barium 2.2 03/22/2016 18521012.0 75-1250.19 1 Beryllium 2.0 03/22/2016 18521022.0 75-125ND1 Cadmium 0.40 03/22/2016 18521000.40 75-125ND1 Chromium 2.0 03/22/2016 18521022.0 75-125ND1 Cobalt 2.0 03/22/2016 18521022.0 75-125ND1 Copper 2.1 03/22/2016 18521032.0 75-125ND1 Lead 0.42 03/22/2016 18521050.40 75-125ND1 Nickel 2.1 03/22/2016 18521032.0 75-125ND1 Selenium 0.41 03/22/2016 18521020.40 75-125ND1 Silver 0.41 03/22/2016 18521020.40 75-125ND1 Thallium 0.86 03/22/2016 18521080.80 75-125ND1 Vanadium 2.0 03/22/2016 18521012.0 75-125ND1 Zinc 2.0 03/22/2016 18521022.0 75-125ND1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 150 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-AES - MSD Batch:Prep Method: Prep Date: Sample ID:RC18024-001MD 98843 3005A 03/19/2016 1211Analytical Method:6010C Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Antimony 0.40 03/22/2016 1856990.40 75-1251.6 20ND1 Arsenic 0.39 03/22/2016 1856980.40 75-1250.58 20ND1 Barium 2.2 03/22/2016 18561022.0 75-1250.81 200.19 1 Beryllium 2.0 03/22/2016 18561022.0 75-1250.29 20ND1 Cadmium 0.40 03/22/2016 1856990.40 75-1250.38 20ND1 Chromium 2.0 03/22/2016 18561022.0 75-1250.13 20ND1 Cobalt 2.0 03/22/2016 18561022.0 75-1250.26 20ND1 Copper 2.1 03/22/2016 18561032.0 75-1250.55 20ND1 Lead 0.42 03/22/2016 18561040.40 75-1250.68 20ND1 Nickel 2.0 03/22/2016 18561022.0 75-1250.68 20ND1 Selenium 0.40 03/22/2016 18561000.40 75-1251.6 20ND1 Silver 0.41 03/22/2016 18561030.40 75-1250.51 20ND1 Thallium 0.86 03/22/2016 18561070.80 75-1250.54 20ND1 Vanadium 2.0 03/22/2016 18561012.0 75-1250.67 20ND1 Zinc 2.0 03/22/2016 18561012.0 75-1251.2 20ND1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 151 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-AES - MB Batch:Prep Method: Prep Date: Sample ID:RQ98884-001 98884 3005A 03/21/2016 923Analytical Method:6010C Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Antimony ND 03/23/2016 13510.020 mg/L1 Arsenic ND 03/23/2016 13510.015 mg/L1 Barium ND 03/23/2016 13510.025 mg/L1 Beryllium ND 03/23/2016 13510.0050 mg/L1 Cadmium ND 03/23/2016 13510.0050 mg/L1 Chromium ND 03/23/2016 13510.010 mg/L1 Cobalt ND 03/23/2016 13510.025 mg/L1 Copper ND 03/23/2016 13510.010 mg/L1 Lead ND 03/23/2016 13510.010 mg/L1 Nickel ND 03/23/2016 13510.040 mg/L1 Selenium ND 03/23/2016 13510.020 mg/L1 Silver ND 03/23/2016 13510.010 mg/L1 Thallium ND 03/23/2016 13510.050 mg/L1 Vanadium ND 03/23/2016 13510.050 mg/L1 Zinc ND 03/23/2016 13510.020 mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 152 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. ICP-AES - LCS Batch:Prep Method: Prep Date: Sample ID:RQ98884-002 98884 3005A 03/21/2016 923Analytical Method:6010C Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Antimony 0.41 03/23/2016 13551020.40 80-1201 Arsenic 0.40 03/23/2016 13551000.40 80-1201 Barium 2.0 03/23/2016 13551022.0 80-1201 Beryllium 2.1 03/23/2016 13551032.0 80-1201 Cadmium 0.41 03/23/2016 13551010.40 80-1201 Chromium 2.1 03/23/2016 13551042.0 80-1201 Cobalt 2.0 03/23/2016 13551022.0 80-1201 Copper 2.1 03/23/2016 13551052.0 80-1201 Lead 0.42 03/23/2016 13551040.40 80-1201 Nickel 2.1 03/23/2016 13551032.0 80-1201 Selenium 0.42 03/23/2016 13551050.40 80-1201 Silver 0.41 03/23/2016 13551030.40 80-1201 Thallium 0.87 03/23/2016 13551080.80 80-1201 Vanadium 2.0 03/23/2016 13551022.0 80-1201 Zinc 2.0 03/23/2016 13551012.0 80-1201 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 153 of 153 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Chain of Custody and Miscellaneous Documents 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. APPENDIX D STATISTICAL CALCULATIONS Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 COMPOUND TOTAL ND DETECTED %ND STATISTICAL TEST Total Antimony 207 206 1 99.5%Poisson Prediction Limits Total Arsenic 225 214 11 95.1%Poisson Prediction Limits Total Barium 225 2 223 0.9%ANOVA Total Beryllium 207 202 5 97.6%Poisson Prediction Limits Total Cadmium 225 221 4 98.2%Poisson Prediction Limits Total Chromium 225 159 66 70.7%Kruskal-Wallis Total Cobalt 207 174 33 84.1%Kruskal-Wallis Total Copper 207 169 38 81.6%Kruskal-Wallis Total Lead 225 208 17 92.4%Poisson Prediction Limits Total Nickel 209 165 44 78.9%Kruskal-Wallis Total Selenium 223 220 3 98.7%Poisson Prediction Limits Total Silver 225 224 1 99.6%Poisson Prediction Limits Total Thallium 207 206 1 99.5%Poisson Prediction Limits Total Vanadium 207 153 54 73.9%Kruskal-Wallis Total Zinc 207 116 91 56.0%Kruskal-Wallis Benzene 222 197 25 88.7%Poisson Prediction Limits Carbon Disulfide 222 220 2 99.1%Poisson Prediction Limits Chlorobenzene 222 208 14 93.7%Poisson Prediction Limits Chloroethane 222 195 27 87.8%Poisson Prediction Limits Chloroform 222 220 2 99.1%Poisson Prediction Limits 1,2-Dichlorobenzene 222 177 45 79.7%Poisson Prediction Limits 1,4-Dichlorobenzene 222 177 45 79.7%Poisson Prediction Limits 1,1-Dichloroethane 222 124 98 55.9%Kruskal-Wallis 1,2-Dichloroethane 222 197 25 88.7%Poisson Prediction Limits 1,1-Dichloroethene 222 221 1 99.5%Poisson Prediction Limits cis-1,2-Dichloroethene 222 128 94 57.7%Kruskal-Wallis cis-1,3-Dichloropropene 222 221 1 99.5%Poisson Prediction Limits Dichloromethane 222 210 12 94.6%Poisson Prediction Limits Tetrachloroethene 222 189 33 85.1%Kruskal-Wallis Trichloroethene 222 189 33 85.1%Kruskal-Wallis Trichlorofluoromethane 221 219 2 99.1%Poisson Prediction Limits Total Xylenes 222 219 3 98.6%Poisson Prediction Limits Naphthalene 143 140 3 97.9%Poisson Prediction Limits Sampling Event # Detected LEGEND FOR THE FOLLOWING PAGES: N 1 0 ND = Not Detected at the method detection limit N 2 0 MCL = Maximum Contaminant Level ; NCAC 2L Standard N 3 0 NE = Not Established; NC has not established a MCL N 4 0 NP = Not Present during sampling event N 5 5 NS = Not Sampled N 6 5 NT = Not Tested N 7 5 NA = information Not Available N 8 11 MDL = Method Detection Limit N 9 9 "J" flagged values are not statisatically analyzed N 10 9 N 11 10 N 12 5 N 13 3 N 14 3 N 15 1 N 16 8 N 17 8 N 18 7 N 19 8 Methods 1957-48 Francis Farm GW Stats 1st 2016.xlsm 1 N 20 8 N 21 8 N 22 9 N 23 67 N 24 60 N 25 80 N 26 83 N 27 100 N 28 121 N 29 100 N 30 91 N 31 102 N 32 63 N 33 68 Total Detected Concentrations (per compound) = 1057 Total Detected Concentrations (per event) = 1057 Are all accounted for ?Yes Statistical Package Prepared By: IAI Statistical Package Checked By: MSP Methods 1957-48 Francis Farm GW Stats 1st 2016.xlsm 2 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Total Antimony (Sb) NC MCL (mg/l):Not Established Method:Poisson Prediction Limits Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/09/04 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/04 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/05 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 09/01/05 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/16/06 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/30/06 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/26/07 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/13/07 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/11/08 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/25/08 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/23/09 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/24/09 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/22/10 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/30/10 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/22/11 ND ND ND ND ND 5.1 ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/22/11 ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/22/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 5 08/29/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 5 02/18/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND 5 08/26/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND 5 02/20/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5 08/28/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5 03/20/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5 08/26/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 20 03/17/16 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 0. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 10 Tn1 = 32.5 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =10 Tn1 = 32.5 t [9,.01] =2.821 c =0.1 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Tn2 = 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 T*k =9.0 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Antimony (PPL) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 1 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Total Antimony (Sb) NC MCL (mg/l):Not Established Method:Poisson Prediction Limits Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 03/19/01 NP 11 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/27/02 NP 25 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/24/03 NP 23 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/11/03 NP 9.9 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/09/04 NP 8.3 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/16/04 NP 6.1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/14/05 NP 6.2 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 09/01/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/16/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/30/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/26/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/13/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/11/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/25/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/23/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/24/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/22/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/30/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/22/11 ND ND ND ND ND 5.8 ND 5.3 ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/22/11 ND ND ND 8.7 ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/22/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 5 08/29/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP 11.2 NP ND NP NP NP NP NP 5 02/18/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND 10 08/26/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND 10 02/20/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 10 08/28/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 10 03/20/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 10 08/26/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 15 03/17/16 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 10 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 0. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 10 Tn1 = 42.5 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =10 Tn1 = 42.5 t [9,.01] =2.821 c =0.1 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Tn2 = 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 T*k =10.8 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Arsenic (PPL) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 2 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Total Barium (Ba) NC MCL (mg/l):700 Method:ANOVA Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 2/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 8/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 2/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 8/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 3/19/01 NP 2000 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 8/27/02 NP 2800 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 2/24/03 NP 2500 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 8/11/03 NP 1200 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/9/04 NP 890 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 8/16/04 NP 1100 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/14/05 NP 520 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 9/1/05 NP 330 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/16/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 8/30/06 NP 250 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/26/07 NP 280 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 8/13/07 NP 208 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/11/08 NP 238 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 8/25/08 NP 195 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/23/09 NP 270 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 8/24/09 NP 264 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/22/10 NP 260 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 8/30/10 NP 246 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/22/11 197 237 54 213 72.8 1190 193 138 68.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 8/22/11 191 280 66.8 1640 76.4 202 71.9 104 57.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/22/12 196 214 48.7 207 62.7 126 102 90.2 49.9 249 NP 93.5 135 141 NP 80.3 NP 56.3 NP NP NP NP NP 5 8/29/12 335 289 42.8 224 67.4 106 110 106 64 184 NP 96.2 83.7 137 NP 615 NP 51 NP NP NP NP NP 5 2/18/13 216 229 16.2 200 41.3 75.7 86 95.5 42.6 118 56.1 65.6 91.5 131 265 100 54.5 45.6 103 1470 NP 31.6 64.6 5 8/26/13 207 255 23.7 204 50.7 79.8 77.5 111 45.1 97.1 36.4 48.8 135 112 264 58.9 253 49.6 96.6 283 NP 42 106 5 2/20/14 185 210 16.8 214 13 92.5 97.3 85.3 40.1 176 38.6 48.8 80.1 183 278 32.5 109 122 74.7 86.9 70.8 42.8 19.2 5 8/28/14 339 199 39.2 183 34.2 54.4 67.6 82.3 38 134 32.5 60 92.8 136 272 46.3 119 28.5 80 107 69.2 22.7 30.8 5 3/20/15 138 171 60.5 181 25.8 137 87.2 55.4 46.9 171 32.7 45.1 68 136 271 68.3 187 32.3 67.1 198 73.5 27.2 32.9 5 8/26/15 150 160 64 170 91 68 97 52 53 200 62 72 92 140 270 54 66 50 120 110 66 63 45 25 3/17/16 160 190 ND 260 25 69 72 54 38 150 40 170 81 110 290 25 88 43 69 97 68 33 32 5 If not detected (ND), use the natural log of half of the detection limit. ni =11 29 11 11 11 11 11 11 11 9 7 9 9 9 7 9 7 9 7 7 5 7 7 Xi. =58.3951 165.91 37.4513 60.595 41.6968 52.4932 49.779 48.8171 42.6995 45.5978 26.0596 38.3791 40.8036 44.1394 39.2595 38.2366 32.9002 34.9886 31.1286 36.6395 21.2033 25.0126 25.9799 1038.2 = X.. Xi.bar =5.30865 5.72103 3.40466 5.50864 3.79062 4.77211 4.52537 4.43792 3.88177 5.06642 3.7228 4.26435 4.53373 4.90437 5.6085 4.24851 4.70002 3.88763 4.44694 5.23422 4.24066 3.57323 3.71142 4.61 = X..bar std dev =0.28801 1.24051 0.97113 0.6385 0.59763 0.85256 0.29154 0.3231 0.20382 0.28625 0.25571 0.42607 0.23148 0.1474 0.03207 0.921 0.54551 0.40972 0.22053 1.00314 0.04074 0.33713 0.56048 ni*(Xi.bar-X..bar)2 =5.30688 35.5356 16.0893 8.80277 7.45878 0.27474 0.08655 0.3413 5.8988 1.84159 5.56052 1.10074 0.05808 0.7585 6.92233 1.20271 0.05172 4.74945 0.19551 2.69209 0.69716 7.58344 5.70338 (Xi.2/ni) =309.999 949.175 127.509 333.796 158.056 250.503 225.268 216.646 165.75 231.017 97.0146 163.662 184.993 216.476 220.187 162.448 154.632 136.023 138.427 191.779 89.9161 89.3757 96.4225 SS df MS F Fc SSw 118.912 22 5.40509 11.8034 1.47 SS_error 92.5013 202 0.45793 SSt 211.413 224 The calculated F statistic is 11.80. The tabulated Fc value with 22 and 202 degrees of freedom and the a=0.05 level is 1.47 (Table 2 of IFG). Since the calculated value of F exceeds the tabulated value of Fc, the hypothesis of equal means must be rejected, and post hoc comparisons are necessary (see below). Barium (ANOVA) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 3 of 96 Bonferroni t-statistics MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Xbari = avg per well =5.50864 3.40466 5.50864 3.79062 4.77211 4.52537 4.43792 3.88177 5.06642 3.7228 4.26435 4.53373 4.90437 5.6085 4.24851 4.70002 3.88763 4.44694 5.23422 4.24066 3.57323 3.71142 Dw = Xbari - Xbarup =0.20 -1.904 0.19999 -1.518 -0.5365 -0.7833 -0.8707 -1.4269 -0.2422 -1.5859 -1.0443 -0.7749 -0.4043 0.29985 -1.0601 -0.6086 -1.421 -0.8617 -0.0744 -1.068 -1.7354 -1.5972 i = [MS-error*( 1/nup + 1/ni )]^0.5 =0.19526 0.19526 0.19526 0.19526 0.19526 0.19526 0.19526 0.19526 0.20582 0.22141 0.20582 0.20582 0.20582 0.22141 0.20582 0.22141 0.20582 0.22141 0.22141 0.24699 0.22141 0.22141 Di = SEi * tc =0.45496 0.45496 0.45496 0.45496 0.45496 0.45496 0.45496 0.45496 0.47957 0.51587 0.47957 0.47957 0.47957 0.51587 0.47957 0.51587 0.47957 0.51587 0.51587 0.57548 0.51587 0.51587 Statistical Significance ?---------------------- If SSI, is current event above MCL?---------------------- 11 = nup 5.31 = Xbarup(average background) 0.4579 = MS_error 202 = degrees of freedom 22 = m (number of compliance wells) 2.33 = tc (from Table 3 of IFG) The F test was significant at the 5% level. The Bonferroni multiple comparisons procedure was then used to determine for which wells there was statistically significant evidence of contamination. If the calculated Dw value exceeds the corresponding Di value, it can be concluded that there is significant evidence of contamination. Dw does not exceed the corresponding Di values. Therefore, there is no significant evidence of contamination. Barium (ANOVA) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 4 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Total Barium (Ba) NC MCL (mg/l):700 Method:Levene's Test for Homogeneity Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 2/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 8/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 2/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 8/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 3/19/01 NP 2000 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 8/27/02 NP 2800 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 2/24/03 NP 2500 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 8/11/03 NP 1200 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/9/04 NP 890 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 8/16/04 NP 1100 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/14/05 NP 520 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 9/1/05 NP 330 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/16/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 8/30/06 NP 250 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/26/07 NP 280 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 8/13/07 NP 208 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/11/08 NP 238 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 8/25/08 NP 195 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/23/09 NP 270 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 8/24/09 NP 264 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/22/10 NP 260 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 8/30/10 NP 246 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/22/11 197 237 54 213 72.8 1190 193 138 68.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 8/22/11 191 280 66.8 1640 76.4 202 71.9 104 57.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/22/12 196 214 48.7 207 62.7 126 102 90.2 49.9 249 NP 93.5 135 141 NP 80.3 NP 56.3 NP NP NP NP NP 5 8/29/12 335 289 42.8 224 67.4 106 110 106 64 184 NP 96.2 83.7 137 NP 615 NP 51 NP NP NP NP NP 5 2/18/13 216 229 16.2 200 41.3 75.7 86 95.5 42.6 118 56.1 65.6 91.5 131 265 100 54.5 45.6 103 1470 NP 31.6 64.6 5 8/26/13 207 255 23.7 204 50.7 79.8 77.5 111 45.1 97.1 36.4 48.8 135 112 264 58.9 253 49.6 96.6 283 NP 42 106 5 2/20/14 185 210 16.8 214 13 92.5 97.3 85.3 40.1 176 38.6 48.8 80.1 183 278 32.5 109 122 74.7 86.9 70.8 42.8 19.2 5 8/28/14 339 199 39.2 183 34.2 54.4 67.6 82.3 38 134 32.5 60 92.8 136 272 46.3 119 28.5 80 107 69.2 22.7 30.8 5 3/20/15 138 171 60.5 181 25.8 137 87.2 55.4 46.9 171 32.7 45.1 68 136 271 68.3 187 32.3 67.1 198 73.5 27.2 32.9 5 8/26/15 150 160 64 170 91 68 97 52 53 200 62 72 92 140 270 54 66 50 120 110 66 63 45 25 3/17/16 160 190 ND 260 25 69 72 54 38 150 40 170 81 110 290 25 88 43 69 97 68 33 32 5 If not detected (ND), use half of the detection limit. bar zi =47.074 495.33 18.076 237.09 21.021 180.35 21.236 20.653 8.3686 35.173 9.3918 28.081 17.575 12.469 6.3673 109.99 54.163 16.002 16.571 324 2.12 10.11 21.763 ni * bar zi 2 =24376 7E+06 3594.2 618333 4860.9 357789 4960.8 4692 770.37 11134 617.45 7097.1 2780 1399.3 283.8 108885 20536 2304.7 1922.3 734851 22.472 715.51 3315.5 bar z =74.478 N =225 SS df MS F Ratio F critical Between Wells 8E+06 22 353741 1.51 1.47 Error 5E+07 202 233641 Total 5E+07 224 Since the F-ratio = 1.51 exceeds the tabulated value of F-critical = 1.47 (see Table 2 of IFG) with 22 and 202 df, the assumption of equal variances should be rejected. Re-test the data set using the natural log of the above values. Ba (Hom) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 5 of 96 bar zi =0.2025 0.7263 0.7146 0.3538 0.4847 0.556 0.2025 0.2521 0.1664 0.2246 0.2025 0.3243 0.1651 0.0931 0.023 0.5927 0.4124 0.2543 0.1863 0.7212 0.0303 0.2622 0.4297 ni * bar zi 2 =0.4509 15.298 5.6177 1.3769 2.5842 3.4001 0.4511 0.6991 0.3047 0.4541 0.287 0.9467 0.2454 0.078 0.0037 3.1614 1.1908 0.5821 0.2429 3.6406 0.0046 0.4812 1.2927 bar z =0.3296 N =225 SS df MS F Ratio F critical Between Wells 18.351 22 0.83 0.89 1.47 Error 188.49 202 0.93 Total 206.84 224 Since the F-ratio = 0.89 does not exceed the tabulated value of F-critical = 1.47 (see Table 2 of IFG) with 22 and 202 df, the assumption of equal means should be accepted. Proceed with further statistical tests using the log-transformed values shown above. Ba (Hom) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 6 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Total Barium (Ba) NC MCL (mg/l):700 Method:Skewness Test for Normality Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 2/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 8/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 2/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 8/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 3/19/01 NP 2000 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 8/27/02 NP 2800 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 2/24/03 NP 2500 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 8/11/03 NP 1200 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/9/04 NP 890 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 8/16/04 NP 1100 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/14/05 NP 520 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 9/1/05 NP 330 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/16/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 8/30/06 NP 250 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/26/07 NP 280 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 8/13/07 NP 208 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/11/08 NP 238 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 8/25/08 NP 195 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/23/09 NP 270 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 8/24/09 NP 264 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/22/10 NP 260 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 8/30/10 NP 246 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/22/11 197 237 54 213 72.8 1190 193 138 68.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 8/22/11 191 280 66.8 1640 76.4 202 71.9 104 57.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 2/22/12 196 214 48.7 207 62.7 126 102 90.2 49.9 249 NP 93.5 135 141 NP 80.3 NP 56.3 NP NP NP NP NP 5 8/29/12 335 289 42.8 224 67.4 106 110 106 64 184 NP 96.2 83.7 137 NP 615 NP 51 NP NP NP NP NP 5 2/18/13 216 229 16.2 200 41.3 75.7 86 95.5 42.6 118 56.1 65.6 91.5 131 265 100 54.5 45.6 103 1470 NP 31.6 64.6 5 8/26/13 207 255 23.7 204 50.7 79.8 77.5 111 45.1 97.1 36.4 48.8 135 112 264 58.9 253 49.6 96.6 283 NP 42 106 5 2/20/14 185 210 16.8 214 13 92.5 97.3 85.3 40.1 176 38.6 48.8 80.1 183 278 32.5 109 122 74.7 86.9 70.8 42.8 19.2 5 8/28/14 339 199 39.2 183 34.2 54.4 67.6 82.3 38 134 32.5 60 92.8 136 272 46.3 119 28.5 80 107 69.2 22.7 30.8 5 3/20/15 138 171 60.5 181 25.8 137 87.2 55.4 46.9 171 32.7 45.1 68 136 271 68.3 187 32.3 67.1 198 73.5 27.2 32.9 5 8/26/15 150 160 64 170 91 68 97 52 53 200 62 72 92 140 270 54 66 50 120 110 66 63 45 25 3/17/16 160 190 ND 260 25 69 72 54 38 150 40 170 81 110 290 25 88 43 69 97 68 33 32 5 If not detected (ND), use half of the detection limit. Xbar =180.37 SD =336.13 N =225 1/NSi(Xi-Xbar)3 =2E+08 g1=5.2849 Since the Coefficient of Skewness of 5.28 is greater than 1.0, the data appear to be significantly skewed. Do not assume that the data follow a Normal distribution. Perform the Skewness Test on the natural log of the values. Xbar =4.6141 SD =0.9715 N =225 1/NSi(Xi-Xbar)3 =0.2538 Ba (Norm) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 7 of 96 g1=0.2787 Since the Coefficient of Skewness of 0.28 is less than 1.0, the data appear not to be significantly skewed. Proceed with further statistical tests using the log-transformed values shown above. Ba (Norm) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 8 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Total Beryllium (Be) NC MCL (mg/l):Not Established Method:Poisson Prediction Limits Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/09/04 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/04 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/05 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 09/01/05 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/16/06 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/30/06 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/26/07 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/13/07 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/11/08 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/25/08 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/23/09 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/24/09 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/22/10 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/30/10 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/22/11 ND ND ND ND ND 3.6 ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/22/11 ND ND ND 2.4 ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 08/29/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP 1.1 NP ND NP NP NP NP NP 1 02/18/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2.5 NP ND ND 1 08/26/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.1 ND ND ND NP ND ND 1 02/20/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 08/28/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 03/20/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 08/26/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5 03/17/16 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 0. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 10 Tn1 = 7 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =10 Tn1 = 7 t [9,.01] =2.821 c =0.1 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Tn2 = 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 T*k =3.6 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Beryllium (PPL) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 9 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Total Cadmium (Cd) NC MCL (mg/l):2 Method:Poisson Prediction Limits Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 03/19/01 NP 18 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 08/27/02 NP 21 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 02/24/03 NP 19 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 08/11/03 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/09/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/16/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/14/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 09/01/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/16/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/30/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/26/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/13/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/11/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/25/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/23/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/24/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/30/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/11 ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/22/11 ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 08/29/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 02/18/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2.4 NP ND ND 1 08/26/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND 1 02/20/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 08/28/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 03/20/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 08/26/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5 03/17/16 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 0. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 10 Tn1 = 7 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =10 Tn1 = 7 t [9,.01] =2.821 c =0.1 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Tn2 = 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 T*k =3.6 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Cadmium (PPL) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 10 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Total Chromium (Cr) NC MCL (mg/l):10 Method:Kruskal-Wallis Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 20 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 20 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 20 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 20 03/19/01 NP 140 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 20 08/27/02 NP 210 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 20 02/24/03 NP 200 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 20 08/11/03 NP 81 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 02/09/04 NP 57 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 08/16/04 NP 52 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 02/14/05 NP 11 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 09/01/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 02/16/06 NP 16 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 08/30/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 02/26/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/13/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/11/08 NP 6.3 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/25/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/23/09 NP 7.2 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/24/09 NP 6.5 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/22/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/30/10 NP 8.8 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/22/11 8.1 ND ND ND 6.3 161 17.6 ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/22/11 8.3 ND ND 105 ND 19.3 ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/22/12 11.1 ND ND 5.2 6.9 10.6 6.2 ND ND 5.7 NP ND 7.3 ND NP 6.4 NP ND NP NP NP NP NP 5 08/29/12 40.2 7.1 6.1 9.7 ND 7.9 6.5 ND ND ND NP ND ND ND NP 56.3 NP ND NP NP NP NP NP 5 02/18/13 16 ND ND ND ND ND ND ND ND ND 6 1.7 2.6 ND ND 7 ND ND ND 292 NP ND 51.4 5 08/26/13 6 ND ND ND ND ND ND ND ND ND ND ND 6.6 ND ND ND 23.8 ND ND 40.6 NP ND 151 5 02/20/14 6.5 ND ND ND ND ND ND ND ND 5.6 ND ND ND ND ND ND 10.8 11 ND ND ND ND ND 5 08/28/14 20.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 11.6 ND ND ND ND ND 8.8 5 03/20/15 5.1 ND 6.9 ND 6.2 12.4 ND ND ND ND ND ND ND ND ND 6 17.3 ND ND 24.7 ND ND 12 5 08/26/15 ND ND ND ND 16 ND ND ND ND ND 25 ND ND ND ND ND ND ND ND 11 ND ND ND 10 03/17/16 ND ND ND ND ND ND ND ND ND ND 15 25 ND ND ND ND ND ND ND ND ND ND ND 5 Ni 11 29 11 11 11 11 11 11 11 9 7 9 9 9 7 9 7 9 7 7 5 7 7 sum of rank values (Ri)1855.0 3895.0 1068.5 1212.0 1284.5 1483.0 1191.5 880.0 880.0 889.0 897.5 930.5 1003.0 720.0 560.0 1138.0 1041.0 834.0 560.0 1081.0 400.0 560.0 1061.5 avg rank value (Rbar)168.6 134.3 97.1 110.2 116.8 134.8 108.3 80.0 80.0 98.8 128.2 103.4 111.4 80.0 80.0 126.4 148.7 92.7 80.0 154.4 80.0 80.0 151.6 Number of each rank value Rank Value rank value of NDs =2 16 9 8 7 6 8 11 11 7 4 7 6 9 7 5 3 8 7 3 5 7 3 80 rank value of 1.7s =0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 160 rank value of 2.6s =0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 161 rank value of 5.1s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 162 rank value of 5.2s =0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 163 rank value of 5.6s =0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 164 rank value of 5.7s =0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 165 rank value of 6s =1 0 0 0 0 0 0 0 0 0 1 0 0 0 0 1 0 0 0 0 0 0 0 167 rank value of 6.1s =0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 169 rank value of 6.2s =0 0 0 0 1 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 170.5 rank value of 6.3s =0 1 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 172.5 rank value of 6.4s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 174 Chromium (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 11 of 96 rank value of 6.5s =1 1 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 176 rank value of 6.6s =0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 178 rank value of 6.9s =0 0 1 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 179.5 rank value of 7s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 181 rank value of 7.1s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 182 rank value of 7.2s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 183 rank value of 7.3s =0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 184 rank value of 7.9s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 185 rank value of 8.1s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 186 rank value of 8.3s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 187 rank value of 8.8s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 188.5 rank value of 9.7s =0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 190 rank value of 10.6s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 191 rank value of 10.8s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 192 rank value of 11s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 1 0 0 0 194 rank value of 11.1s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 196 rank value of 11.6s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 197 rank value of 12s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 198 rank value of 12.4s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 199 rank value of 15s =0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 200 rank value of 16s =1 1 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 202 rank value of 17.3s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 204 rank value of 17.6s =0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 205 rank value of 19.3s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 206 rank value of 20.4s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 207 rank value of 23.8s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 208 rank value of 24.7s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 209 rank value of 25s =0 0 0 0 0 0 0 0 0 0 1 1 0 0 0 0 0 0 0 0 0 0 0 210.5 rank value of 40.2s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 212 rank value of 40.6s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 213 rank value of 51.4s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 214 rank value of 52s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 215 rank value of 56.3s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 216 rank value of 57s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 217 rank value of 81s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 218 rank value of 105s =0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 219 rank value of 140s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 220 rank value of 151s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 221 rank value of 161s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 222 rank value of 200s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 223 rank value of 210s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 224 rank value of 292s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 225 n =11 29 11 11 11 11 11 11 11 9 7 9 9 9 7 9 7 9 7 7 5 7 7 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SKi=1 (Ri2)/Ni]} -3(N+1) Well = Background MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Ri2/Ni = 312820.5 523139 103790 133540 149995 199935 129061 70400 70400 87813.4 115072 96203.4 111779 57600 44800 143894 154812 77284 44800 166937 32000 44800 160969 Ni bg = 11 N = 225 H = 37.48 Chromium (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 12 of 96 Adjust H for ties: Ti =4019646 sum of T1..T10 H' = H/(1-(Ti/(N3-N))) H' =57.92 Chi-square =33.92 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 12df at the 5% significance level from Table 1 of the IFG. The value is 33.92 which is less than H' =57.92. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Rbar (well x) = 134.3 97.1 110.2 116.8 134.8 108.3 80.0 80.0 98.8 128.2 103.4 111.4 80.0 80.0 126.4 148.7 92.7 80.0 154.4 80.0 80.0 151.6 avg Rbar (background) = 168.6 168.6 168.6 168.6 168.6 168.6 168.6 168.6 168.6 168.6 168.6 168.6 168.6 168.6 168.6 168.6 168.6 168.6 168.6 168.6 168.6 168.6 Dx = -34.3 -71.5 -58.5 -51.9 -33.8 -60.3 -88.6 -88.6 -69.9 -40.4 -65.2 -57.2 -88.6 -88.6 -42.2 -19.9 -76.0 -88.6 -14.2 -88.6 -88.6 -17.0 Cx = 53.7 64.7 64.7 64.7 64.7 64.7 64.7 64.7 68.2 73.3 68.2 68.2 68.2 73.3 68.2 73.3 68.2 73.3 73.3 81.8 73.3 73.3 Statistical Significance ?---------------------- If SSI, is current event above MCL?---------------------- Compare each difference (Dx) with the corresponding critical value (Cx). No compliance well's difference between average ranks exceeded its corresponding critical value at a 5% significance level. Therefore, we conclude that significant evidence of contamination does not exist at the 5% significance level. Chromium (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 13 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Total Cobalt (Co) NC MCL (mg/l):NE Method:Kruskal-Wallis Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/09/04 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/04 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/05 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 09/01/05 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/16/06 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/30/06 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/26/07 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/13/07 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/11/08 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/25/08 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/23/09 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/24/09 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/22/10 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/30/10 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/22/11 9.8 16.8 ND 5.4 ND 40.5 5.2 9.4 ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/22/11 ND 9.7 ND 43.1 ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/22/12 ND 5.8 ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 5 08/29/12 11.7 17.3 ND 5.1 ND ND ND ND ND ND NP ND ND ND NP 21.4 NP ND NP NP NP NP NP 5 02/18/13 7 14.8 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 72.7 NP ND ND 5 08/26/13 5.8 26.6 ND ND ND ND ND 5.3 ND ND ND ND 7.4 ND 13.3 ND 23.7 ND 5.4 22 NP ND ND 5 02/20/14 ND 6.9 ND ND ND ND ND ND ND ND ND ND ND 10.2 13.9 ND ND 6 ND ND ND ND ND 5 08/28/14 ND 8.1 ND ND ND ND ND ND ND ND ND ND ND ND 11.6 ND ND ND ND ND ND ND ND 5 03/20/15 ND 5.3 ND ND ND ND ND ND ND ND ND ND ND ND 12.6 ND ND ND ND 5.6 ND ND ND 5 08/26/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 25 03/17/16 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5 Ni 11 11 11 11 11 11 11 11 11 9 7 9 9 9 7 9 7 9 7 7 5 7 7 sum of rank values (Ri)1366.0 1899.0 962.5 1260.5 962.5 1080.0 1051.0 1154.0 962.5 787.5 612.5 787.5 887.0 892.0 1043.5 901.0 728.0 884.0 704.5 940.0 437.5 612.5 612.5 avg rank value (Rbar)124.2 172.6 87.5 114.6 87.5 98.2 95.5 104.9 87.5 87.5 87.5 87.5 98.6 99.1 149.1 100.1 104.0 98.2 100.6 134.3 87.5 87.5 87.5 Number of each rank value Rank Value rank value of NDs =7 2 11 8 11 10 10 9 11 9 7 9 8 8 3 8 6 8 6 4 5 7 7 87.5 rank value of 5.1s =0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 175 rank value of 5.2s =0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 176 rank value of 5.3s =0 1 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 177.5 rank value of 5.4s =0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 179.5 rank value of 5.6s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 181 rank value of 5.8s =1 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 182.5 rank value of 6s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 184 rank value of 6.9s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 185 rank value of 7s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 186 rank value of 7.4s =0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 187 rank value of 8.1s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 188 rank value of 9.4s =0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 189 rank value of 9.7s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 190 rank value of 9.8s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 191 rank value of 10.2s =0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 192 rank value of 11.6s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 193 rank value of 11.7s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 194 rank value of 12.6s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 195 rank value of 13.3s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 196 rank value of 13.9s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 197 rank value of 14.8s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 198 rank value of 16.8s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 199 rank value of 17.3s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 200 rank value of 21.4s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 201 rank value of 22s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 202 rank value of 23.7s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 203 rank value of 26.6s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 204 Cobalt (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 14 of 96 rank value of 40.5s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 205 rank value of 43.1s =0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 206 rank value of 72.7s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 207 n =11 11 11 11 11 11 11 11 11 9 7 9 9 9 7 9 7 9 7 7 5 7 7 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SKi=1 (Ri2)/Ni]} -3(N+1) Well = Background MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Ri2/Ni = 169632.4 327836 84218.8 144442 84218.8 106036 100418 121065 84218.8 68906.3 53593.8 68906.3 87418.8 88407.1 155556 90200.1 75712 86828.4 70902.9 126229 38281.3 53593.8 53593.8 Ni bg = 11 N = 207 H = 28.23 Adjust H for ties: Ti =5267868 sum of T1..T4 H' = H/(1-(Ti/(N3-N))) H' =69.53 Chi-square =33.92 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 12df at the 5% significance level from Table 1 of the IFG. The value is 33.92 which is less than H' =69.53. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Rbar (well x) = 172.6 87.5 114.6 87.5 98.2 95.5 104.9 87.5 87.5 87.5 87.5 98.6 99.1 149.1 100.1 104.0 98.2 100.6 134.3 87.5 87.5 87.5 avg Rbar (background) = 124.2 124.2 124.2 124.2 124.2 124.2 124.2 124.2 124.2 124.2 124.2 124.2 124.2 124.2 124.2 124.2 124.2 124.2 124.2 124.2 124.2 124.2 Dx = 48.5 -36.7 -9.6 -36.7 -26.0 -28.6 -19.3 -36.7 -36.7 -36.7 -36.7 -25.6 -25.1 24.9 -24.1 -20.2 -26.0 -23.5 10.1 -36.7 -36.7 -36.7 Cx = 59.5 59.5 59.5 59.5 59.5 59.5 59.5 59.5 62.7 67.5 62.7 62.7 62.7 67.5 62.7 67.5 62.7 67.5 67.5 75.3 67.5 67.5 Statistical Significance ?---------------------- If SSI, is current event above MCL?---------------------- Compare each difference (Dx) with the corresponding critical value (Cx). No compliance well's difference between average ranks exceeded its corresponding critical value at a 5% significance level. Therefore, we conclude that significant evidence of contamination does not exist at the 5% significance level. Cobalt (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 15 of 96 Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Total Copper (Cu) NC MCL (mg/l):1,000 Method:Kruskal-Wallis Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/09/04 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/04 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/05 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 09/01/05 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/16/06 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/30/06 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/26/07 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/13/07 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/11/08 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/25/08 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/23/09 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/24/09 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/22/10 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/30/10 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/22/11 ND 155 ND ND ND 64.3 10.7 ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/22/11 ND 7.3 ND 125 ND 7.9 ND 7.5 ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/22/12 8.3 ND ND ND 5.7 6.9 ND ND ND 6.8 NP ND 5.4 ND NP 7.4 NP ND NP NP NP NP NP 5 08/29/12 17.3 16.2 ND 5.6 ND ND 5 ND ND ND NP ND ND ND NP 78.5 NP ND NP NP NP NP NP 5 02/18/13 9 7.3 ND ND ND ND ND ND ND ND ND ND ND ND ND 8.8 ND ND ND 207 NP ND 12.3 5 08/26/13 6.3 8.4 ND ND ND ND ND ND ND ND ND ND 5.6 ND ND ND 28 ND ND 25.9 NP ND ND 5 02/20/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 10.8 8.3 ND ND ND ND ND 5 08/28/14 7.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 13.1 ND ND ND ND ND ND 5 03/20/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 6.8 21.2 ND ND 16.9 ND ND ND 5 08/26/15 ND ND ND 11 ND ND 12 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 10 03/17/16 ND ND ND ND ND ND ND ND ND ND ND 12 ND ND ND ND ND ND ND ND ND ND ND 5 Ni 11 11 11 11 11 11 11 11 11 9 7 9 9 9 7 9 7 9 7 7 5 7 7 sum of rank values (Ri)1441.5 1459.0 935.0 1249.5 1024.0 1245.0 1233.5 1032.0 935.0 856.5 595.0 873.5 938.5 765.0 595.0 1174.5 1044.0 865.5 595.0 946.0 425.0 595.0 705.0 avg rank value (Rbar)131.0 132.6 85.0 113.6 93.1 113.2 112.1 93.8 85.0 95.2 85.0 97.1 104.3 85.0 85.0 130.5 149.1 96.2 85.0 135.1 85.0 85.0 100.7 Number of each rank value Rank Value rank value of NDs =6 6 11 8 10 8 8 10 11 8 7 8 7 9 7 5 3 8 7 4 5 7 6 85 rank value of 5s =0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 170 rank value of 5.4s =0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 171 rank value of 5.6s =0 0 0 1 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 172.5 rank value of 5.7s =0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 174 rank value of 6.3s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 175 rank value of 6.8s =0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 1 0 0 0 0 0 0 0 176.5 rank value of 6.9s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 178 rank value of 7.3s =0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 179.5 rank value of 7.4s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 181 rank value of 7.5s =0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 182 rank value of 7.6s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 183 Copper (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 16 of 96 rank value of 7.9s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 184 rank value of 8.3s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 185.5 rank value of 8.4s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 187 rank value of 8.8s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 188 rank value of 9s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 189 rank value of 10.7s =0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 190 rank value of 10.8s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 191 rank value of 11s =0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 192 rank value of 12s =0 0 0 0 0 0 1 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 193.5 rank value of 12.3s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 195 rank value of 13.1s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 196 rank value of 16.2s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 197 rank value of 16.9s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 198 rank value of 17.3s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 199 rank value of 21.2s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 200 rank value of 25.9s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 201 rank value of 28s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 202 rank value of 64.3s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 203 rank value of 78.5s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 204 rank value of 125s =0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 205 rank value of 155s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 206 rank value of 207s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 207 n =11 11 11 11 11 11 11 11 11 9 7 9 9 9 7 9 7 9 7 7 5 7 7 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SKi=1 (Ri2)/Ni]} -3(N+1) Well = Background MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Ri2/Ni = 188902.0 193516 79475 141932 95325.1 140911 138320 96820.4 79475 81510.3 50575 84778 97864.7 65025 50575 153272 155705 83232.3 50575 127845 36125 50575 71003.6 Ni bg = 11 N = 207 H = 20.74 Adjust H for ties: Ti =4826670 sum of T1..T6 H' = H/(1-(Ti/(N3-N))) H' =45.51 Chi-square =33.92 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 12df at the 5% significance level from Table 1 of the IFG. The value is 33.92 which is less than H' =45.51. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Copper (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 17 of 96 Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Rbar (well x) = 132.6 85.0 113.6 93.1 113.2 112.1 93.8 85.0 95.2 85.0 97.1 104.3 85.0 85.0 130.5 149.1 96.2 85.0 135.1 85.0 85.0 100.7 avg Rbar (background) = 131.0 131.0 131.0 131.0 131.0 131.0 131.0 131.0 131.0 131.0 131.0 131.0 131.0 131.0 131.0 131.0 131.0 131.0 131.0 131.0 131.0 131.0 Dx = 1.6 -46.0 -17.5 -38.0 -17.9 -18.9 -37.2 -46.0 -35.9 -46.0 -34.0 -26.8 -46.0 -46.0 -0.5 18.1 -34.9 -46.0 4.1 -46.0 -46.0 -30.3 Cx = 59.5 59.5 59.5 59.5 59.5 59.5 59.5 59.5 62.7 67.5 62.7 62.7 62.7 67.5 62.7 67.5 62.7 67.5 67.5 75.3 67.5 67.5 Statistical Significance ?---------------------- If SSI, is current event above MCL?---------------------- Compare each difference (Dx) with the corresponding critical value (Cx). No compliance well's difference between average ranks exceeded its corresponding critical value at a 5% significance level. Therefore, we conclude that significant evidence of contamination does not exist at the 5% significance level. Copper (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 18 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Total Lead (Pb) NC MCL (mg/l):15 Method:Poisson Prediction Limits Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 03/19/01 NP 38 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 08/27/02 NP 47 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 02/24/03 NP 41 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 08/11/03 NP 30 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/09/04 NP 18 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/16/04 NP 23 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/14/05 NP 7.9 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 09/01/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/16/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/30/06 NP 6.5 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/26/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/13/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/11/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/25/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/23/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/24/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/22/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/30/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/22/11 ND 7.2 ND ND ND 16.2 6.3 ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/22/11 ND ND ND 37.2 ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/22/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 5 08/29/12 9.2 ND ND ND ND ND ND ND ND ND NP ND ND ND NP 13.3 NP ND NP NP NP NP NP 5 02/18/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5.4 NP ND ND 5 08/26/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5.7 ND ND ND NP ND ND 5 02/20/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5 08/28/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5 03/20/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 6.3 ND ND ND ND ND ND 5 08/26/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 10 03/17/16 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 0. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 10 Tn1 = 34.2 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =10 Tn1 = 34.2 t [9,.01] =2.821 c =0.1 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Tn2 = 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 T*k =9.3 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Lead (PPL) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 19 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Total Nickel (Ni) NC MCL (mg/l):100 Method:Kruskal-Wallis Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 50 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 50 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 50 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 50 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 50 08/27/02 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 50 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 50 08/11/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 50 02/09/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 50 08/16/04 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 50 02/14/05 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 50 09/01/05 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 50 02/16/06 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 50 08/30/06 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 50 02/26/07 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 50 08/13/07 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/11/08 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/25/08 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/23/09 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/24/09 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/22/10 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/30/10 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/22/11 7.6 5.4 8 ND ND 97.3 8.4 ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/22/11 7.7 7.4 5.5 62.1 ND 10.9 ND 5.2 ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/22/12 9.6 ND ND ND ND 5 ND ND ND ND NP ND 6.2 ND NP 5.9 NP ND NP NP NP NP NP 5 08/29/12 22.3 9.2 ND 5.5 ND ND ND ND ND ND NP ND ND ND NP 60.8 NP ND NP NP NP NP NP 5 02/18/13 11.3 6 ND ND ND ND ND ND ND ND ND ND ND ND 6.6 8.4 ND ND ND 104 NP ND 18.5 5 08/26/13 5.1 8.1 ND ND ND ND ND ND ND ND ND ND 6.3 ND 6.2 ND 11.7 ND ND 14.3 NP ND ND 5 02/20/14 8 ND ND ND ND ND ND ND ND ND ND ND ND ND 6.5 ND ND ND ND ND ND ND ND 5 08/28/14 17.3 5.5 ND ND ND ND ND ND ND ND ND ND ND ND 11.2 ND 6.9 ND ND ND ND ND ND 5 03/20/15 13.2 5.2 ND ND ND 6.5 ND ND ND ND ND ND ND ND 13 ND 10.7 ND ND 10.2 ND ND 8.8 5 08/26/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 40 03/17/16 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5 Ni 11 13 11 11 11 11 11 11 11 9 7 9 9 9 7 9 7 9 7 7 5 7 7 sum of rank values (Ri)1888.5 1746.5 1105.5 1126.0 913.0 1330.5 1019.5 998.5 913.0 747.0 581.0 747.0 935.5 747.0 1100.0 1067.5 908.0 747.0 581.0 937.0 415.0 581.0 810.0 avg rank value (Rbar)171.7 134.3 100.5 102.4 83.0 121.0 92.7 90.8 83.0 83.0 83.0 83.0 103.9 83.0 157.1 118.6 129.7 83.0 83.0 133.9 83.0 83.0 115.7 Number of each rank value Rank Value rank value of NDs =2 6 9 9 11 7 10 10 11 9 7 9 7 9 2 6 4 9 7 4 5 7 5 83 rank value of 5s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 166 rank value of 5.1s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 167 rank value of 5.2s =0 1 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 168.5 rank value of 5.4s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 170 rank value of 5.5s =0 1 1 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 172 rank value of 5.9s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 174 rank value of 6s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 175 rank value of 6.2s =0 0 0 0 0 0 0 0 0 0 0 0 1 0 1 0 0 0 0 0 0 0 0 176.5 rank value of 6.3s =0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 178 rank value of 6.5s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 179.5 rank value of 6.6s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 181 rank value of 6.9s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 182 rank value of 7.4s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 183 rank value of 7.6s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 184 rank value of 7.7s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 185 rank value of 8s =1 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 186.5 rank value of 8.1s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 188 rank value of 8.4s =0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 189.5 rank value of 8.8s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 191 rank value of 9.2s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 192 rank value of 9.6s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 193 rank value of 10.2s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 194 rank value of 10.7s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 195 rank value of 10.9s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 196 rank value of 11.2s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 197 rank value of 11.3s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 198 rank value of 11.7s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 199 Nickel (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 20 of 96 rank value of 13s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 200 rank value of 13.2s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 201 rank value of 14.3s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 202 rank value of 17.3s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 203 rank value of 18.5s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 204 rank value of 22.3s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 205 rank value of 60.8s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 206 rank value of 62.1s =0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 207 rank value of 97.3s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 208 rank value of 104s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 209 n =11 13 11 11 11 11 11 11 11 9 7 9 9 9 7 9 7 9 7 7 5 7 7 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SKi=1 (Ri2)/Ni]} -3(N+1) Well = Background MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 2 MW - 2 3 MW - 2 4 MW - 2 5 Ri2/Ni = 324221.1 234636 111103 115261 75779 160930 94489.1 90636.6 75779 62001 48223 62001 97240 62001 172857 126617 117781 62001 48223 48223 125424 48223 93728.6 Ni bg = 11 N = 209 H = 41.87 Adjust H for ties: Ti =4492014 sum of T1..T7 H' = H/(1-(Ti/(N3-N))) H' =82.44 Chi-square =33.92 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 12df at the 5% significance level from Table 1 of the IFG. The value is 33.92 which is less than H' =82.44. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 2 MW - 2 3 MW - 2 4 MW - 2 5 Rbar (well x) = 134.3 100.5 102.4 83.0 121.0 92.7 90.8 83.0 83.0 83.0 83.0 103.9 83.0 157.1 118.6 129.7 83.0 83.0 83.0 133.9 83.0 115.7 avg Rbar (background) = 171.7 171.7 171.7 171.7 171.7 171.7 171.7 171.7 171.7 171.7 171.7 171.7 171.7 171.7 171.7 171.7 171.7 171.7 171.7 171.7 171.7 171.7 Dx = -37.3 -71.2 -69.3 -88.7 -50.7 -79.0 -80.9 -88.7 -88.7 -88.7 -88.7 -67.7 -88.7 -14.5 -53.1 -42.0 -88.7 -88.7 -88.7 -37.8 -88.7 -56.0 Cx = 57.7 60.1 60.1 60.1 60.1 60.1 60.1 60.1 63.3 68.1 63.3 63.3 63.3 68.1 63.3 68.1 63.3 68.1 68.1 68.1 68.1 68.1 Statistical Significance ?---------------------- If SSI, is current event above MCL?---------------------- Compare each difference (Dx) with the corresponding critical value (Cx). No compliance well's difference between average ranks exceeded its corresponding critical value at a 5% significance level. Therefore, we conclude that significant evidence of contamination does not exist at the 5% significance level. Nickel (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 21 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Total Selenium (Se) NC MCL (mg/l):20 Method:Poisson Prediction Limits Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 03/19/01 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/11/03 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/09/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/16/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/14/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 09/01/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/16/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/30/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/26/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 08/13/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 02/11/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 08/25/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 02/23/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 08/24/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 02/22/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 08/30/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 02/22/11 ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 08/22/11 ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 02/22/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 10 08/29/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 10 02/18/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND 10 08/26/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 67.9 NP ND ND 10 02/20/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 10 08/28/14 ND ND ND ND ND ND ND ND 15 ND ND ND ND ND ND ND ND ND ND ND ND ND 12 10 03/20/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 10 08/26/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 20 03/17/16 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 10 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 0. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 10 Tn1 = 55 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =10 Tn1 = 55 t [9,.01] =2.821 c =0.1 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Tn2 = 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 T*k =12.8 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Selenium (PPL) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 22 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Total Silver (Ag) NC MCL (mg/l):20 Method:Poisson Prediction Limits Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 50 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 50 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 50 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 50 03/19/01 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 50 08/27/02 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 50 02/24/03 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 50 08/11/03 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 02/09/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 08/16/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 02/14/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 09/01/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 02/16/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 08/30/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 02/26/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/13/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/11/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/25/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/23/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/24/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/22/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/30/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/22/11 ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/22/11 ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/22/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 5 08/29/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 5 02/18/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND 5 08/26/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 102 NP ND ND 5 02/20/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5 08/28/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5 03/20/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5 08/26/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 10 03/17/16 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 0. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 10 Tn1 = 27.5 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =10 Tn1 = 27.5 t [9,.01] =2.821 c =0.1 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Tn2 = 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 T*k =8.1 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Silver (PPL) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 23 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Total Thallum (Th) NC MCL (mg/l):Not Established Method:Poisson Prediction Limits Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/09/04 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/04 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/05 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 09/01/05 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/16/06 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/30/06 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/26/07 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/13/07 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/11/08 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/25/08 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/23/09 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/24/09 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/22/10 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/30/10 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/22/11 ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/22/11 ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/22/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 5 08/29/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 5 02/18/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND 5 08/26/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND 5 02/20/14 ND ND ND ND ND 6.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5 08/28/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5 03/20/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5 08/26/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 50 03/17/16 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 0. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 10 Tn1 = 49.3 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =10 Tn1 = 49.3 t [9,.01] =2.821 c =0.1 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Tn2 = 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 T*k =11.9 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Thallium (PPL) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 24 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Total Vanadium (V) NC MCL (mg/l):Not Established Method:Kruskal-Wallis Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/09/04 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/04 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/05 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 09/01/05 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/16/06 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/30/06 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/26/07 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/13/07 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/11/08 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/25/08 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/23/09 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/24/09 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/22/10 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/30/10 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/22/11 7.8 ND ND ND 5.6 205 22.8 ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/22/11 8.1 ND ND 185 ND 23.1 ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/22/12 14.1 ND ND ND 8.8 12.5 8.6 ND ND 11 NP ND 9.8 6.1 NP 7.6 NP ND NP NP NP NP NP 5 08/29/12 49 14.7 ND 9.9 ND 10.6 10 ND ND 5.5 NP ND ND ND NP 86.2 NP ND NP NP NP NP NP 5 02/18/13 20.8 ND ND ND 5.3 ND ND ND ND ND ND ND ND ND ND 10.6 5.1 ND ND 393 NP ND 24.5 5 08/26/13 6.8 ND ND ND ND 6 ND ND ND ND ND ND 8.8 ND ND 5.8 37.2 ND ND ND NP ND ND 5 02/20/14 7.4 ND ND ND ND 6.5 7.6 ND ND 12.8 ND ND ND ND ND ND 15.8 16.5 ND 5.3 ND ND 9.2 5 08/28/14 24.8 ND ND ND ND ND ND ND ND 7.3 ND ND ND ND ND ND 17.3 ND ND 15.4 ND ND 5.3 5 03/20/15 5.8 ND 8.9 ND ND 14.3 5.2 ND ND 10.9 ND ND ND ND ND 8.1 27.2 ND ND 42.9 ND ND ND 5 08/26/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 50 03/17/16 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5 Ni 11 11 11 11 11 11 11 11 11 9 7 9 9 9 7 9 7 9 7 7 5 7 7 sum of rank values (Ri)1778.0 960.0 947.0 1078.0 1108.5 1596.5 1337.5 847.0 847.0 1190.0 539.0 693.0 893.5 780.0 539.0 1198.0 1095.0 809.0 539.0 988.0 385.0 539.0 841.0 avg rank value (Rbar)161.6 87.3 86.1 98.0 100.8 145.1 121.6 77.0 77.0 132.2 77.0 77.0 99.3 86.7 77.0 133.1 156.4 89.9 77.0 141.1 77.0 77.0 120.1 Number of each rank value Rank Value rank value of NDs =2 10 10 9 8 4 6 11 11 4 7 9 7 8 7 4 2 8 7 3 5 7 4 77 rank value of 5.1s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 154 rank value of 5.2s =0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 155 rank value of 5.3s =0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 1 157 rank value of 5.5s =0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 159 rank value of 5.6s =0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 160 rank value of 5.8s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 161.5 rank value of 6s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 163 rank value of 6.1s =0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 164 rank value of 6.5s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 165 rank value of 6.8s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 166 rank value of 7.3s =0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 167 rank value of 7.4s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 168 rank value of 7.6s =0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 169.5 rank value of 7.8s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 171 rank value of 8.1s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 172.5 rank value of 8.6s =0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 174 rank value of 8.8s =0 0 0 0 1 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 175.5 rank value of 8.9s =0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 177 rank value of 9.2s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 178 rank value of 9.8s =0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 179 rank value of 9.9s =0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 180 rank value of 10s =0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 181 rank value of 10.6s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 182.5 rank value of 10.9s =0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 184 rank value of 11s =0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 185 rank value of 12.5s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 186 rank value of 12.8s =0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 187 Vanadium (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 25 of 96 rank value of 14.1s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 188 rank value of 14.3s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 189 rank value of 14.7s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 190 rank value of 15.4s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 191 rank value of 15.8s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 192 rank value of 16.5s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 193 rank value of 17.3s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 194 rank value of 20.8s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 195 rank value of 22.8s =0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 196 rank value of 23.1s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 197 rank value of 24.5s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 198 rank value of 24.8s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 199 rank value of 27.2s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 200 rank value of 37.2s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 201 rank value of 42.9s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 202 rank value of 49s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 203 rank value of 86.2s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 204 rank value of 185s =0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 205 rank value of 205s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 206 rank value of 393s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 207 n =11 11 11 11 11 11 11 11 11 9 7 9 9 9 7 9 7 9 7 7 5 7 7 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SKi=1 (Ri2)/Ni]} -3(N+1) Well = Background MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Ri2/Ni = 287389.5 83781.8 81528.1 105644 111707 231710 162628 65219 65219 157344 41503 53361 88704.7 67600 41503 159467 171289 72720.1 41503 139449 29645 41503 101040 Ni bg = 11 N = 207 H = 45.30 Adjust H for ties: Ti =3581478 sum of T1..T7 H' = H/(1-(Ti/(N3-N))) H' =75.99 Chi-square =33.92 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 12df at the 5% significance level from Table 1 of the IFG. The value is 33.92 which is less than H' =75.99. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Rbar (well x) = 87.3 86.1 98.0 100.8 145.1 121.6 77.0 77.0 132.2 77.0 77.0 99.3 86.7 77.0 133.1 156.4 89.9 77.0 141.1 77.0 77.0 120.1 avg Rbar (background) = 161.6 161.6 161.6 161.6 161.6 161.6 161.6 161.6 161.6 161.6 161.6 161.6 161.6 161.6 161.6 161.6 161.6 161.6 161.6 161.6 161.6 161.6 Dx = -74.4 -75.5 -63.6 -60.9 -16.5 -40.0 -84.6 -84.6 -29.4 -84.6 -84.6 -62.4 -75.0 -84.6 -28.5 -5.2 -71.7 -84.6 -20.5 -84.6 -84.6 -41.5 Cx = 59.5 59.5 59.5 59.5 59.5 59.5 59.5 59.5 62.7 67.5 62.7 62.7 62.7 67.5 62.7 67.5 62.7 67.5 67.5 75.3 67.5 67.5 Statistical Significance ?---------------------- If SSI, is current event above MCL?---------------------- Compare each difference (Dx) with the corresponding critical value (Cx). No compliance well's difference between average ranks exceeded its corresponding critical value at a 5% significance level. Therefore, we conclude that significant evidence of contamination does not exist at the 5% significance level. Vanadium (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 26 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Total Zinc (Zn) NC MCL (mg/l):1000 Method:Kruskal-Wallis Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/09/04 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/04 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/05 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 09/01/05 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/16/06 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/30/06 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/26/07 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/13/07 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/11/08 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/25/08 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/23/09 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/24/09 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/22/10 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/30/10 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/22/11 26.5 90.4 ND 19.8 ND 162 36.7 10.3 ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 08/22/11 ND 16.9 ND 283 ND 15.9 ND 50.6 ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 02/22/12 10.9 ND 10.4 16.7 16.8 23.1 31.8 ND ND 21.4 NP 12.4 17.2 24.3 NP 26.9 NP 15.3 NP NP NP NP NP 10 08/29/12 21 12.7 37.8 20.3 14.5 10.4 19.5 ND ND ND NP ND ND 13.6 NP 198 NP 11.7 NP NP NP NP NP 10 02/18/13 13.6 11.5 19.5 ND 20.2 ND ND ND ND ND ND ND 12.4 ND ND 24.8 21.4 ND ND 195 NP ND 39.2 10 08/26/13 11 29 34.3 10.8 14.1 11.6 17.1 ND ND ND ND ND 21.8 22.1 102 45 129 11.4 25.5 ND NP 34.7 12.1 10 02/20/14 ND ND ND 54 ND ND ND ND ND 14 ND ND ND 12.5 ND ND 42.2 22.2 35.2 ND ND 13.8 ND 10 08/28/14 20.7 ND 83 ND ND ND ND ND ND 11.8 ND ND 10.4 ND ND ND 27.7 ND ND ND ND ND ND 10 03/20/15 21.2 ND 39.4 ND ND 14.5 ND 19.6 ND 61.5 ND ND ND 57.3 18.8 26.7 48.1 ND 16.7 112 ND ND 15 10 08/26/15 ND ND 27 ND 67 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 20 03/17/16 ND ND 50 ND ND ND ND ND ND 26 26 22 ND 72 45 ND 34 ND ND ND ND ND 47 10 Ni 11 11 11 11 11 11 11 11 11 9 7 9 9 9 7 9 7 9 7 7 5 7 7 sum of rank values (Ri)1259.5 1133.0 1562.0 1269.0 1126.5 1190.0 1070.0 931.0 643.5 1026.0 521.5 703.0 853.0 1166.0 773.5 1143.5 1155.0 850.5 729.5 699.5 292.5 609.5 820.5 avg rank value (Rbar)114.5 103.0 142.0 115.4 102.4 108.2 97.3 84.6 58.5 114.0 74.5 78.1 94.8 129.6 110.5 127.1 165.0 94.5 104.2 99.9 58.5 87.1 117.2 Number of each rank value Rank Value rank value of NDs =4 6 3 5 6 5 7 8 11 4 6 7 5 3 4 4 1 5 4 5 5 5 3 58.5 rank value of 10.3s =0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 117 rank value of 10.4s =0 0 1 0 0 1 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 119 rank value of 10.8s =0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 121 rank value of 10.9s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 122 rank value of 11s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 123 rank value of 11.4s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 124 rank value of 11.5s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 125 rank value of 11.6s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 126 rank value of 11.7s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 127 rank value of 11.8s =0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 128 rank value of 12.1s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 129 Zinc (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 27 of 96 rank value of 12.4s =0 0 0 0 0 0 0 0 0 0 0 1 1 0 0 0 0 0 0 0 0 0 0 130.5 rank value of 12.5s =0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 132 rank value of 12.7s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 133 rank value of 13.6s =1 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 134.5 rank value of 13.8s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 136 rank value of 14s =0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 137 rank value of 14.1s =0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 138 rank value of 14.5s =0 0 0 0 1 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 139.5 rank value of 15s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 141 rank value of 15.3s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 142 rank value of 15.9s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 143 rank value of 16.7s =0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 144.5 rank value of 16.8s =0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 146 rank value of 16.9s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 147 rank value of 17.1s =0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 148 rank value of 17.2s =0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 149 rank value of 18.8s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 150 rank value of 19.5s =0 0 1 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 151.5 rank value of 19.6s =0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 153 rank value of 19.8s =0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 154 rank value of 20.2s =0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 155 rank value of 20.3s =0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 156 rank value of 20.7s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 157 rank value of 21s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 158 rank value of 21.2s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 159 rank value of 21.4s =0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 1 0 0 0 0 0 0 160.5 rank value of 21.8s =0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 162 rank value of 22s =0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 163 rank value of 22.1s =0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 164 rank value of 22.2s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 165 rank value of 23.1s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 166 rank value of 24.3s =0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 167 rank value of 24.8s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 168 rank value of 25.5s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 169 rank value of 26s =0 0 0 0 0 0 0 0 0 1 1 0 0 0 0 0 0 0 0 0 0 0 0 170.5 rank value of 26.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 172 rank value of 26.7s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 173 rank value of 26.9s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 174 rank value of 27s =0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 175 rank value of 27.7s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 176 rank value of 29s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 177 rank value of 31.8s =0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 178 rank value of 34s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 179 rank value of 34.3s =0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 180 rank value of 34.7s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 181 rank value of 35.2s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 182 rank value of 36.7s =0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 183 rank value of 37.8s =0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 184 rank value of 39.2s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 185 rank value of 39.4s =0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 186 rank value of 42.2s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 187 rank value of 45s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 1 0 0 0 0 0 0 0 188.5 rank value of 47s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 190 rank value of 48.1s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 191 rank value of 50s =0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 192 rank value of 50.6s =0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 193 rank value of 54s =0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 194 rank value of 57.3s =0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 195 rank value of 61.5s =0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 196 rank value of 67s =0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 197 rank value of 72s =0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 198 rank value of 83s =0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 199 rank value of 90.4s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 200 Zinc (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 28 of 96 rank value of 102s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 201 rank value of 112s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 202 rank value of 129s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 203 rank value of 162s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 204 rank value of 195s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 205 rank value of 198s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 206 rank value of 283s =0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 207 n =11 11 11 11 11 11 11 11 11 9 7 9 9 9 7 9 7 9 7 7 5 7 7 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SK i=1 (Ri 2)/Ni]} -3(N+1) Well = Background MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Ri2/Ni = 144212.8 116699 221804 146396 115364 128736 104082 78796.5 37644.8 116964 38851.8 54912.1 80845.4 151062 85471.8 145288 190575 80372.3 76024.3 69900 17111.3 53070 96174.3 Ni bg = 11 N = 207 H = 31.06 Adjust H for ties: Ti =1560852 sum of T1..T10 H' = H/(1-(Ti/(N3-N))) H' =37.69 Chi-square =33.92 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 12df at the 5% significance level from Table 1 of the IFG. The value is 33.92 which is less than H' =37.69. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Rbar (well x) = 103.0 142.0 115.4 102.4 108.2 97.3 84.6 58.5 114.0 74.5 78.1 94.8 129.6 110.5 127.1 165.0 94.5 104.2 99.9 58.5 87.1 117.2 avg Rbar (background) = 114.5 114.5 114.5 114.5 114.5 114.5 114.5 114.5 114.5 114.5 114.5 114.5 114.5 114.5 114.5 114.5 114.5 114.5 114.5 114.5 114.5 114.5 Dx = -11.5 27.5 0.9 -12.1 -6.3 -17.2 -29.9 -56.0 -0.5 -40.0 -36.4 -19.7 15.1 -4.0 12.6 50.5 -20.0 -10.3 -14.6 -56.0 -27.4 2.7 Cx = 59.5 59.5 59.5 59.5 59.5 59.5 59.5 59.5 62.7 67.5 62.7 62.7 62.7 67.5 62.7 67.5 62.7 67.5 67.5 75.3 67.5 67.5 Statistical Significance ?---------------------- If SSI, is current event above MCL?---------------------- Compare each difference (Dx) with the corresponding critical value (Cx). No compliance well's difference between average ranks exceeded its corresponding critical value at a 5% significance level. Therefore, we conclude that significant evidence of contamination Zinc (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 29 of 96 does not exist at the 5% significance level. Zinc (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 30 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Benzene NC MCL (mg/l):1 Method:Poisson Prediction Limits Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NP 9 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/09/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/16/04 NP 6.1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/14/05 NP 7.1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 09/01/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/16/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/30/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/26/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/13/07 NP 1.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/11/08 NP 2 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/25/08 NP 2.3 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/23/09 NP 2.1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/24/09 NP 3 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/10 NP 3.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/30/10 NP 4.8 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/11 ND 5.1 ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/22/11 ND 4.2 ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/12 ND 3.9 ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 08/29/12 ND 3.3 ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 02/18/13 ND 4.1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND 1 08/26/13 ND 3.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND 8.6 1 02/20/14 ND 4.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5.7 1 08/28/14 ND 3.2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 1 03/20/15 ND 1.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 08/26/15 ND 1.2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 03/17/16 ND 1.5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.7 1 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 0. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 10 Tn1 = 5 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =10 Tn1 = 5 t [9,.01] =2.821 c =0.1 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Tn2 = 1.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.7 T*k =3.0 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Benzene (PPL) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 31 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Carbon Disulfide NC MCL (mg/l):700 Method:Poisson Prediction Limits Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 02/09/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 08/16/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 02/14/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 100 09/01/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 02/16/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 08/30/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 02/26/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 08/13/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 02/11/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 08/25/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 02/23/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 08/24/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 02/22/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 08/30/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 02/22/11 ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 08/22/11 ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 02/22/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 2 08/29/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 2 02/18/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND 3.9 2 08/26/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND 5.8 2 02/20/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2 08/28/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2 03/20/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2 08/26/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 03/17/16 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 0. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 10 Tn1 = 9.5 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =10 Tn1 = 9.5 t [9,.01] =2.821 c =0.1 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Tn2 = 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 T*k =4.3 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Carbon Disulfide (PPL) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 32 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Chlorobenzene NC MCL (mg/l):50 Method:Poisson Prediction Limits Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/09/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/16/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/14/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 09/01/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/16/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/30/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/26/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/13/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/11/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/25/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/23/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/24/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/30/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/11 ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/22/11 ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 08/29/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 02/18/13 ND ND ND 1.1 ND ND ND ND ND ND ND ND ND ND 2.3 ND ND ND ND ND NP ND ND 1 08/26/13 ND ND ND 1.2 ND ND ND ND ND ND ND ND ND ND 2.3 ND ND ND ND ND NP ND ND 1 02/20/14 ND ND ND 1.2 ND ND ND ND ND ND ND ND ND 1.8 2 ND ND ND ND ND ND ND ND 1 08/28/14 ND ND ND 1.3 ND ND ND ND ND ND ND ND ND ND 2.3 ND ND ND ND ND ND ND ND 1 03/20/15 ND ND ND 1.1 ND ND ND ND ND ND ND ND ND ND 2.1 ND ND ND ND ND ND ND ND 1 08/26/15 ND ND ND 1.2 ND ND ND ND ND ND ND ND ND ND 2.2 ND ND ND ND ND ND ND ND 1 03/17/16 ND ND ND 1.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 0. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 10 Tn1 = 5 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =10 Tn1 = 5 t [9,.01] =2.821 c =0.1 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Tn2 = 0.5 0.5 1.4 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 T*k =3.0 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Chlorobenzene (PPL) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 33 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Chloroethane NC MCL (mg/l):3000 Method:Poisson Prediction Limits Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NP 33 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 02/09/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 08/16/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 02/14/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 09/01/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 02/16/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 08/30/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 02/26/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 08/13/07 NP 2.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/11/08 NP 2.5 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/25/08 NP 2.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/23/09 NP 2.1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/24/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/10 NP 3.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/30/10 NP 4.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/11 ND 4 ND 1.3 ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/22/11 ND 2.9 ND 1.2 ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/12 ND 2.3 ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 08/29/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 02/18/13 ND 2.4 ND 1.3 ND ND ND ND ND ND ND ND ND ND 2.1 ND ND ND ND ND NP ND ND 1 08/26/13 ND 2.1 ND 1.5 ND ND ND ND ND ND ND ND ND ND 2.8 ND ND ND ND ND NP ND 2.4 1 02/20/14 ND 1.4 ND 1.2 ND ND ND ND ND ND ND ND ND 1.7 1.6 ND ND ND ND ND ND ND ND 1 08/28/14 ND 1.8 ND 1.8 ND ND ND ND ND ND ND ND ND ND 2.6 ND ND ND ND ND ND ND ND 1 03/20/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2 ND ND ND ND ND ND ND ND 1 08/26/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2 03/17/16 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 0. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 10 Tn1 = 5.5 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =10 Tn1 = 5.5 t [9,.01] =2.821 c =0.1 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Tn2 = 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 T*k =3.2 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Chloroethane (PPL) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 34 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Chloroform NC MCL (mg/l):70 Method:Poisson Prediction Limits Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/09/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/16/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/14/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 09/01/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/16/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/30/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/26/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/13/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/11/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/25/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/23/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/24/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/30/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/11 ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/22/11 ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 08/29/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 02/18/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND 1 08/26/13 ND ND ND ND ND ND ND ND ND 2.3 ND ND ND ND ND ND ND ND ND ND NP ND ND 1 02/20/14 ND ND ND ND ND ND ND ND ND 1.4 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 08/28/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 03/20/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 08/26/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 03/17/16 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 0. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 10 Tn1 = 5 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =10 Tn1 = 5 t [9,.01] =2.821 c =0.1 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Tn2 = 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 T*k =3.0 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Chloroform (PPL) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 35 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:1,2-Dichlorobenzene NC MCL (mg/l):20 Method:Poisson Prediction Limits Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/09/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/16/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/14/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 09/01/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/16/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/30/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/26/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/13/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/11/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/25/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/23/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/24/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/30/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/11 ND ND ND 1.4 ND ND ND 4.2 3.3 NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/22/11 ND ND ND 1.5 ND ND ND 4 2.8 NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/12 ND ND ND 1.6 ND ND ND 5 4 ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 08/29/12 ND ND ND 1.6 ND ND ND 5.9 4.4 ND NP ND ND 1.2 NP ND NP ND NP NP NP NP NP 1 02/18/13 ND ND ND 2.2 ND ND ND 5.9 9.2 ND ND ND ND 1.1 3.2 ND ND ND ND ND NP ND ND 1 08/26/13 ND ND ND 2.6 ND ND ND 4.2 8.2 ND ND ND ND 1.2 3.4 ND ND ND ND ND NP ND ND 1 02/20/14 ND ND ND 2.8 ND ND ND 3.3 7.2 ND ND ND ND 3.1 3.3 ND ND ND ND ND ND ND ND 1 08/28/14 ND ND ND 2.6 ND ND ND 2.5 6.3 ND ND ND ND 1.5 3.4 ND ND ND ND ND ND ND ND 1 03/20/15 ND ND ND 1.9 ND ND ND 1.9 5.7 ND ND ND ND 1.1 3.2 ND ND ND ND ND ND ND ND 1 08/26/15 ND ND ND 2.7 ND ND ND ND 7.6 ND ND ND ND 1.6 3.7 ND ND ND ND ND ND ND ND 1 03/17/16 ND ND ND 3 ND ND ND 3.6 8.9 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 0. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 10 Tn1 = 5 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =10 Tn1 = 5 t [9,.01] =2.821 c =0.1 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Tn2 = 0.5 0.5 3 0.5 0.5 0.5 3.6 8.9 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 T*k =3.0 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was exceeded in one, or more of the wells, Wilcoxon Rank Sum Tests must be performed to test the possibility that the detected concentrations are statistically significant. 1,2-DCB (PPL) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 36 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:1,2-Dichlorobenzene NC MCL (mg/l):20 Method:Wilcoxon Rank Sum Background:MW-12 MW - 1 2 MW - 1 1 MD L 02/18/99 NP NP NT 08/16/99 NP NP NT 02/14/00 NP NP NT 08/14/00 NP NP NT 03/19/01 NP NP NT 08/27/02 NP NP NT 02/24/03 NP NP NT 08/11/03 NP NP 5 02/09/04 NP NP 5 08/16/04 NP NP 5 02/14/05 NP NP 5 09/01/05 NP NP 5 02/16/06 NP NP 5 08/30/06 NP NP 5 02/26/07 NP NP 5 08/13/07 NP NP 1 02/11/08 NP NP 1 08/25/08 NP NP 1 02/23/09 NP NP 1 08/24/09 NP NP 1 02/22/10 NP NP 1 08/30/10 NP NP 1 02/22/11 ND 4.2 1 08/22/11 ND 4 1 02/22/12 ND 5 1 08/29/12 ND 5.9 1 02/18/13 ND 5.9 1 08/26/13 ND 4.2 1 02/20/14 ND 3.3 1 08/28/14 ND 2.5 1 03/20/15 ND 1.9 1 08/26/15 ND ND 1 03/17/16 ND 3.6 1 1) Rank the N = 22 observations from the smallest to the largest from background wells and compliance well MW-11. n =11 m =11 N =22 Ci (MW-11) =181.5 # samples =11 11 sum of rank values (Ri) =71.5 181.5 avg rank value (Rbar) =6.5 16.5 Number of each rank value Rank Value rank value of NDs =11 1 6.5 rank value of 1.9s =0 1 13 rank value of 2.5s =0 1 14 rank value of 3.3s =0 1 15 rank value of 3.6s =0 1 16 1,2-DCB (Wil 11) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 37 of 96 rank value of 4s =0 1 17 rank value of 4.2s =0 2 18.5 rank value of 5s =0 1 20 rank value of 5.9s =0 2 21.5 0 0 0 0 0 0 0 0 0 # samples =11 11 2) Compute the Wilcoxon statistic by adding up the compliance well ranks and subtracting n/(n+1)/2. W = Ci - 1/2(n(n+1)) W = 115.5 3) Compute the expected value and standard deviation of W. E(W) = 1/2mn SD(W) = ((mn(N+1)/12)*(1-Sg i=1 (ti 3 - ti)/(N3 - N)))0.5 E(W) = 60.5 Adjustment for tie values: SD(W) = 13.936 4) Form the appropriate Z-score. Z = (W - E(W) - 0.5)/SD(W) Z = 3.911 5) Compare the observed Z-score to the upper 0.01 percentile of the normal distribution. Z = 3.911 Z0.01 = 2.326 Since Z is greater, there is significant evidence of contamination at the compliance well at the 1 percent significance level. 1,2-DCB (Wil 11) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 38 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:1,2-Dichlorobenzene NC MCL (mg/l):20 Method:Wilcoxon Rank Sum Background:MW-12 MW - 1 2 MW - 1 5 MD L 02/18/99 NP NP NT 08/16/99 NP NP NT 02/14/00 NP NP NT 08/14/00 NP NP NT 03/19/01 NP NP NT 08/27/02 NP NP NT 02/24/03 NP NP NT 08/11/03 NP NP 5 02/09/04 NP NP 5 08/16/04 NP NP 5 02/14/05 NP NP 5 09/01/05 NP NP 5 02/16/06 NP NP 5 08/30/06 NP NP 5 02/26/07 NP NP 5 08/13/07 NP NP 1 02/11/08 NP NP 1 08/25/08 NP NP 1 02/23/09 NP NP 1 08/24/09 NP NP 1 02/22/10 NP NP 1 08/30/10 NP NP 1 02/22/11 ND 3.3 1 08/22/11 ND 2.8 1 02/22/12 ND 4 1 08/29/12 ND 4.4 1 02/18/13 ND 9.2 1 08/26/13 ND 8.2 1 02/20/14 ND 7.2 1 08/28/14 ND 6.3 1 03/20/15 ND 5.7 1 08/26/15 ND 7.6 1 03/17/16 ND 8.9 1 1) Rank the N = 22 observations from the smallest to the largest from background wells and compliance well MW-15. n =11 m =11 N =22 Ci (MW-15) =187.0 # samples =11 11 sum of rank values (Ri) =66.0 187.0 avg rank value (Rbar) =6.0 17.0 Number of each rank value Rank Value rank value of NDs =11 0 6 rank value of 2.8s =0 1 12 rank value of 3.3s =0 1 13 rank value of 4s =0 1 14 rank value of 4.4s =0 1 15 1,2-DCB (Wil 15) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 39 of 96 rank value of 5.7s =0 1 16 rank value of 6.3s =0 1 17 rank value of 7.2s =0 1 18 rank value of 7.6s =0 1 19 rank value of 8.2s =0 1 20 rank value of 8.9s =0 1 21 rank value of 9.2s =0 1 22 # samples =11 11 2) Compute the Wilcoxon statistic by adding up the compliance well ranks and subtracting n/(n+1)/2. W = Ci - 1/2(n(n+1)) W = 121 3) Compute the expected value and standard deviation of W. E(W) = 1/2mn SD(W) = ((mn(N+1)/12)*(1-Sg i=1 (ti 3 - ti)/(N3 - N)))0.5 E(W) = 60.5 Adjustment for tie values: SD(W) = 14.252 4) Form the appropriate Z-score. Z = (W - E(W) - 0.5)/SD(W) Z = 4.210 5) Compare the observed Z-score to the upper 0.01 percentile of the normal distribution. Z = 4.210 Z0.01 = 2.326 Since Z is greater, there is significant evidence of contamination at the compliance well at the 1 percent significance level. 1,2-DCB (Wil 15) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 40 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:1,4-Dichlorobenzene NC MCL (mg/l):6 Method:Poisson Prediction Limits Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/09/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/16/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/14/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 09/01/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/16/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/30/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/26/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/13/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/11/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/25/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/23/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/24/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/30/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/11 ND 1.3 ND 1.7 ND ND ND 1.4 ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/22/11 ND 1.1 ND 1.6 ND ND ND 1.5 ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/12 ND ND ND 1.6 ND ND ND 1.6 ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 08/29/12 ND ND ND 1.4 ND ND ND 1.8 ND ND NP ND ND 1.3 NP ND NP ND NP NP NP NP NP 1 02/18/13 ND 1.1 ND 1.9 ND ND ND 1.6 1.6 ND ND ND ND 1.1 2.7 ND ND ND ND ND NP ND ND 1 08/26/13 ND 1.1 ND 2.2 ND ND ND 1.5 1.1 ND ND ND ND 1.2 3 ND ND ND ND ND NP ND 3.9 1 02/20/14 ND 1.4 ND 2.3 ND ND ND 1 ND ND ND ND ND 2.8 2.5 ND ND ND ND ND ND ND 2.8 1 08/28/14 ND ND ND 2.3 ND ND ND ND ND ND ND ND ND 1.8 3 ND ND ND ND ND ND ND 1.4 1 03/20/15 ND ND ND 2 ND ND ND ND ND ND ND ND ND 1.3 2.8 ND ND ND ND ND ND ND 1.2 1 08/26/15 ND ND ND 2.2 ND ND ND ND ND ND ND ND ND 1.6 3 ND ND ND ND ND ND ND ND 1 03/17/16 ND ND ND 2.4 ND ND ND 1.1 1.4 ND ND ND ND ND ND ND ND ND ND ND ND ND 1.4 1 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 0. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 10 Tn1 = 5 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =10 Tn1 = 5 t [9,.01] =2.821 c =0.1 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Tn2 = 0.5 0.5 2.4 0.5 0.5 0.5 1.1 1.4 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.4 T*k =3.0 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. 1,4-DCB (PPL) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 41 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:1,1-Dichloroethane NC MCL (mg/l):6 Method:Kruskal-Wallis Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NP 23 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/09/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/16/04 NP 12 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/14/05 NP 15 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 09/01/05 NP 10 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/16/06 NP 7.1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/30/06 NP 5.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/26/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/13/07 NP 4.3 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/11/08 NP 4.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/25/08 NP 5.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/23/09 NP 5.2 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/24/09 NP 7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/10 NP 10.1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/30/10 NP 11.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/11 ND 12.9 ND 4.4 ND ND 3.1 7.5 1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/22/11 ND 9.6 ND 4.6 ND 1.5 2.8 9.6 ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/12 ND 8.1 ND 3 ND ND 2.1 8.5 ND 1.8 NP ND ND 3.4 NP ND NP ND NP NP NP NP NP 1 08/29/12 ND 7.4 ND 2.6 ND ND 1.8 6.8 ND 1.6 NP ND ND 4.5 NP ND NP ND NP NP NP NP NP 1 02/18/13 ND 7.9 ND 2.9 ND ND 1.8 5.7 ND ND 1.1 ND ND 3.6 3.4 ND ND ND ND ND NP ND 3.1 1 08/26/13 ND 7.8 ND 2.6 ND ND 1.5 6.6 ND ND 1.1 ND ND 2.8 2.7 ND ND ND ND ND NP ND 16.3 1 02/20/14 ND 6.8 ND 2.3 ND ND 1.1 5.2 ND ND 1.2 ND ND 3.4 2.3 ND 1.1 ND ND ND ND ND 8.7 1 08/28/14 ND 8.1 ND 3 ND 1.1 1.6 6 ND ND 1.4 ND ND 3.9 2.9 ND 1.2 ND ND ND ND ND 14.7 1 03/20/15 ND 4.3 ND 2.4 ND ND 1.6 5 ND ND 1.2 ND ND 3 2.4 ND 1 ND ND ND ND ND 10.9 1 08/26/15 ND 4.1 ND 2.8 ND 1.1 1.5 6.8 ND ND 1.5 ND ND 3.8 2.7 ND ND ND ND ND ND ND 9.1 1 03/17/16 ND 4.7 ND 2.8 ND 1.6 1.8 6.8 ND ND 1.5 ND ND 2.2 ND 1.1 1.4 ND ND ND ND ND 11 1 Ni 11 26 11 11 11 11 11 11 11 9 7 9 9 9 7 9 7 9 7 7 5 7 7 sum of rank values (Ri)687.5 4949.0 687.5 1825.5 687.5 984.0 1638.5 2163.0 750.5 732.5 949.5 562.5 562.5 1547.5 1035.0 630.0 715.5 562.5 437.5 437.5 312.5 437.5 1457.5 avg rank value (Rbar)62.5 190.3 62.5 166.0 62.5 89.5 149.0 196.6 68.2 81.4 135.6 62.5 62.5 171.9 147.9 70.0 102.2 62.5 62.5 62.5 62.5 62.5 208.2 Number of each rank value Rank Value rank value of NDs =11 2 11 0 11 7 0 0 10 7 0 9 9 0 1 8 3 9 7 7 5 7 0 62.5 rank value of 1s =0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 1 0 0 0 0 0 0 125.5 rank value of 1.1s =0 0 0 0 0 2 1 0 0 0 2 0 0 0 0 1 1 0 0 0 0 0 0 130 rank value of 1.2s =0 0 0 0 0 0 0 0 0 0 2 0 0 0 0 0 1 0 0 0 0 0 0 135 rank value of 1.4s =0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 1 0 0 0 0 0 0 137.5 rank value of 1.5s =0 0 0 0 0 1 2 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 141 rank value of 1.6s =0 0 0 0 0 1 2 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 145.5 rank value of 1.8s =0 0 0 0 0 0 3 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 149.5 rank value of 2.1s =0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 152 rank value of 2.2s =0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 153 rank value of 2.3s =0 0 0 1 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 154.5 rank value of 2.4s =0 0 0 1 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 156.5 1,1-DCA (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 42 of 96 rank value of 2.6s =0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 158.5 rank value of 2.7s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 0 0 0 0 0 0 0 0 160.5 rank value of 2.8s =0 0 0 2 0 0 1 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 163.5 rank value of 2.9s =0 0 0 1 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 166.5 rank value of 3s =0 0 0 2 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 169 rank value of 3.1s =0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 171.5 rank value of 3.4s =0 0 0 0 0 0 0 0 0 0 0 0 0 2 1 0 0 0 0 0 0 0 0 174 rank value of 3.6s =0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 176 rank value of 3.8s =0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 177 rank value of 3.9s =0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 178 rank value of 4.1s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 179 rank value of 4.3s =0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 180.5 rank value of 4.4s =0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 182 rank value of 4.5s =0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 183 rank value of 4.6s =0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 184 rank value of 4.7s =0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 185.5 rank value of 5s =0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 187 rank value of 5.2s =0 1 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 188.5 rank value of 5.4s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 190 rank value of 5.7s =0 1 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 191.5 rank value of 6s =0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 193 rank value of 6.6s =0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 194 rank value of 6.8s =0 1 0 0 0 0 0 3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 196.5 rank value of 7s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 199 rank value of 7.1s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 200 rank value of 7.4s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 201 rank value of 7.5s =0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 202 rank value of 7.8s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 203 rank value of 7.9s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 204 rank value of 8.1s =0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 205.5 rank value of 8.5s =0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 207 rank value of 8.7s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 208 rank value of 9.1s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 209 rank value of 9.6s =0 1 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 210.5 rank value of 10s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 212 rank value of 10.1s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 213 rank value of 10.9s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 214 rank value of 11s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 215 rank value of 11.7s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 216 rank value of 12s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 217 rank value of 12.9s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 218 rank value of 14.7s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 219 rank value of 15s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 220 rank value of 16.3s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 221 rank value of 23s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 222 n =11 26 11 11 11 11 11 11 11 9 7 9 9 9 7 9 7 9 7 7 5 7 7 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SKi=1 (Ri2)/Ni]} -3(N+1) Well = Background MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 1,1-DCA (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 43 of 96 Ri2/Ni = 42968.8 942023 42968.8 302950 42968.8 88023.3 244062 425324 51204.6 59617.4 128793 35156.3 35156.3 266084 153032 44100 73134.3 35156.3 27343.8 27343.8 19531.3 27343.8 303472 Ni bg = 11 N = 222 H = 159.45 Adjust H for ties: Ti =1907352 sum of T1..T24 H' = H/(1-(Ti/(N3-N))) H' =193.11 Chi-square =33.92 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 12df at the 5% significance level from Table 1 of the IFG. The value is 33.92 which is less than H' =193.11. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =42968.8 Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Rbar (well x) = 190.3 62.5 166.0 62.5 89.5 149.0 196.6 68.2 81.4 135.6 62.5 62.5 171.9 147.9 70.0 102.2 62.5 62.5 62.5 62.5 62.5 208.2 avg Rbar (background) = 62.5 62.5 62.5 62.5 62.5 62.5 62.5 62.5 62.5 62.5 62.5 62.5 62.5 62.5 62.5 62.5 62.5 62.5 62.5 62.5 62.5 62.5 Dx = 127.8 0.0 103.5 0.0 27.0 86.5 134.1 5.7 18.9 73.1 0.0 0.0 109.4 85.4 7.5 39.7 0.0 0.0 0.0 0.0 0.0 145.7 Cx = 53.8 63.8 63.8 63.8 63.8 63.8 63.8 63.8 67.3 72.4 67.3 67.3 67.3 72.4 67.3 72.4 67.3 72.4 72.4 80.7 72.4 72.4 Statistical Significance ?Yes -Yes --Yes Yes --Yes --Yes Yes -------Yes If SSI, is current event above MCL?No -No --No Yes --No --No No -------Yes Compare each difference (Dx) with the corresponding critical value (Cx). The Dx value for the above indicated wells do exceed the corresponding Cx value. Therefore, we conclude that the concentration of 1,1-Dichloroethane averaged over these compliance wells are significantly greater than that of the background wells. Shewart-CUSUM Control Charts or Wilcoxon Rank Sum Tests should be performed for each failing well to check for statistical significance. 1,1-DCA (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 44 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:1,1-Dichloroethane NC MCL (mg/l):6 Method:Wilcoxon Rank Sum Background:MW-12 MW - 1 2 MW - 5 MD L 02/18/99 NP NS NT 08/16/99 NP NS NT 02/14/00 NP NS NT 08/14/00 NP NT NT 03/19/01 NP NT NT 08/27/02 NP NT NT 02/24/03 NP NT NT 08/11/03 NP 23 5 02/09/04 NP ND 5 08/16/04 NP 12 5 02/14/05 NP 15 5 09/01/05 NP 10 5 02/16/06 NP 7.1 5 08/30/06 NP 5.7 5 02/26/07 NP ND 5 08/13/07 NP 4.3 1 02/11/08 NP 4.7 1 08/25/08 NP 5.4 1 02/23/09 NP 5.2 1 08/24/09 NP 7 1 02/22/10 NP 10.1 1 08/30/10 NP 11.7 1 02/22/11 ND 12.9 1 08/22/11 ND 9.6 1 02/22/12 ND 8.1 1 08/29/12 ND 7.4 1 02/18/13 ND 7.9 1 08/26/13 ND 7.8 1 02/20/14 ND 6.8 1 08/28/14 ND 8.1 1 03/20/15 ND 4.3 1 08/26/15 ND 4.1 1 03/17/16 ND 4.7 1 1) Rank the N = 37 observations from the smallest to the largest from background wells and compliance well MW-5. n =26 m =11 N =37 Ci (MW-5) =626.0 # samples =11 26 sum of rank values (Ri) =77.0 626.0 avg rank value (Rbar) =7.0 24.1 Number of each rank value Rank Value rank value of NDs =11 2 7 rank value of 4.1s =0 1 14 rank value of 4.3s =0 2 15.5 rank value of 4.7s =0 2 17.5 rank value of 5.2s =0 1 19 1,1-DCA (Wil 5) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 45 of 96 rank value of 5.4s =0 1 20 rank value of 5.7s =0 1 21 rank value of 6.8s =0 1 22 rank value of 7s =0 1 23 rank value of 7.1s =0 1 24 rank value of 7.4s =0 1 25 rank value of 7.8s =0 1 26 rank value of 7.9s =0 1 27 rank value of 8.1s =0 2 28.5 rank value of 9.6s =0 1 30 rank value of 10s =0 1 31 rank value of 10.1s =0 1 32 rank value of 11.7s =0 1 33 rank value of 12s =0 1 34 rank value of 12.9s =0 1 35 rank value of 15s =0 1 36 rank value of 23s =0 1 37 # samples =11 26 2) Compute the Wilcoxon statistic by adding up the compliance well ranks and subtracting n/(n+1)/2. W = Ci - 1/2(n(n+1)) W = 275 3) Compute the expected value and standard deviation of W. E(W) = 1/2mn SD(W) = ((mn(N+1)/12)*(1-Sg i=1 (ti 3 - ti)/(N3 - N)))0.5 E(W) = 143 Adjustment for tie values: SD(W) = 29.432 4) Form the appropriate Z-score. Z = (W - E(W) - 0.5)/SD(W) Z = 4.468 5) Compare the observed Z-score to the upper 0.01 percentile of the normal distribution. Z = 4.468 Z0.01 = 2.326 Since Z is greater, there is significant evidence of contamination at the compliance well at the 1 percent significance level. 1,1-DCA (Wil 5) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 46 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:1,1-Dichloroethane NC MCL (mg/l):6 Method:Wilcoxon Rank Sum Background:MW-12 MW - 1 2 MW - 7 MD L 02/18/99 NP NP NT 08/16/99 NP NP NT 02/14/00 NP NP NT 08/14/00 NP NP NT 03/19/01 NP NP NT 08/27/02 NP NP NT 02/24/03 NP NP NT 08/11/03 NP NP 5 02/09/04 NP NP 5 08/16/04 NP NP 5 02/14/05 NP NP 5 09/01/05 NP NP 5 02/16/06 NP NP 5 08/30/06 NP NP 5 02/26/07 NP NP 5 08/13/07 NP NP 1 02/11/08 NP NP 1 08/25/08 NP NP 1 02/23/09 NP NP 1 08/24/09 NP NP 1 02/22/10 NP NP 1 08/30/10 NP NP 1 02/22/11 ND 4.4 1 08/22/11 ND 4.6 1 02/22/12 ND 3 1 08/29/12 ND 2.6 1 02/18/13 ND 2.9 1 08/26/13 ND 2.6 1 02/20/14 ND 2.3 1 08/28/14 ND 3 1 03/20/15 ND 2.4 1 08/26/15 ND 2.8 1 03/17/16 ND 2.8 1 1) Rank the N = 22 observations from the smallest to the largest from background wells and compliance well MW-7. n =11 m =11 N =22 Ci (MW-7) =187.0 # samples =11 11 sum of rank values (Ri) =66.0 187.0 avg rank value (Rbar) =6.0 17.0 Number of each rank value Rank Value rank value of NDs =11 0 6 rank value of 2.3s =0 1 12 rank value of 2.4s =0 1 13 rank value of 2.6s =0 2 14.5 rank value of 2.8s =0 2 16.5 1,1-DCA (Wil 7) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 47 of 96 rank value of 2.9s =0 1 18 rank value of 3s =0 2 19.5 rank value of 4.4s =0 1 21 rank value of 4.6s =0 1 22 0 0 0 0 0 0 0 0 0 # samples =11 11 2) Compute the Wilcoxon statistic by adding up the compliance well ranks and subtracting n/(n+1)/2. W = Ci - 1/2(n(n+1)) W = 121 3) Compute the expected value and standard deviation of W. E(W) = 1/2mn SD(W) = ((mn(N+1)/12)*(1-Sg i=1 (ti 3 - ti)/(N3 - N)))0.5 E(W) = 60.5 Adjustment for tie values: SD(W) = 14.238 4) Form the appropriate Z-score. Z = (W - E(W) - 0.5)/SD(W) Z = 4.214 5) Compare the observed Z-score to the upper 0.01 percentile of the normal distribution. Z = 4.214 Z0.01 = 2.326 Since Z is greater, there is significant evidence of contamination at the compliance well at the 1 percent significance level. 1,1-DCA (Wil 7) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 48 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:1,1-Dichloroethane NC MCL (mg/l):6 Method:Wilcoxon Rank Sum Background:MW-12 MW - 1 2 MW - 1 0 MD L 02/18/99 NP NP NT 08/16/99 NP NP NT 02/14/00 NP NP NT 08/14/00 NP NP NT 03/19/01 NP NP NT 08/27/02 NP NP NT 02/24/03 NP NP NT 08/11/03 NP NP 5 02/09/04 NP NP 5 08/16/04 NP NP 5 02/14/05 NP NP 5 09/01/05 NP NP 5 02/16/06 NP NP 5 08/30/06 NP NP 5 02/26/07 NP NP 5 08/13/07 NP NP 1 02/11/08 NP NP 1 08/25/08 NP NP 1 02/23/09 NP NP 1 08/24/09 NP NP 1 02/22/10 NP NP 1 08/30/10 NP NP 1 02/22/11 ND 3.1 1 08/22/11 ND 2.8 1 02/22/12 ND 2.1 1 08/29/12 ND 1.8 1 02/18/13 ND 1.8 1 08/26/13 ND 1.5 1 02/20/14 ND 1.1 1 08/28/14 ND 1.6 1 03/20/15 ND 1.6 1 08/26/15 ND 1.5 1 03/17/16 ND 1.8 1 1) Rank the N = 22 observations from the smallest to the largest from background wells and compliance well MW-10. n =11 m =11 N =22 Ci (MW-10) =187.0 # samples =11 11 sum of rank values (Ri) =66.0 187.0 avg rank value (Rbar) =6.0 17.0 Number of each rank value Rank Value rank value of NDs =11 0 6 rank value of 1.1s =0 1 12 rank value of 1.5s =0 2 13.5 rank value of 1.6s =0 2 15.5 rank value of 1.8s =0 3 18 1,1-DCA (Wil 10) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 49 of 96 rank value of 2.1s =0 1 20 rank value of 2.8s =0 1 21 rank value of 3.1s =0 1 22 0 0 0 0 0 0 0 0 0 0 0 0 # samples =11 11 2) Compute the Wilcoxon statistic by adding up the compliance well ranks and subtracting n/(n+1)/2. W = Ci - 1/2(n(n+1)) W = 121 3) Compute the expected value and standard deviation of W. E(W) = 1/2mn SD(W) = ((mn(N+1)/12)*(1-Sg i=1 (ti 3 - ti)/(N3 - N)))0.5 E(W) = 60.5 Adjustment for tie values: SD(W) = 14.224 4) Form the appropriate Z-score. Z = (W - E(W) - 0.5)/SD(W) Z = 4.218 5) Compare the observed Z-score to the upper 0.01 percentile of the normal distribution. Z = 4.218 Z0.01 = 2.326 Since Z is greater, there is significant evidence of contamination at the compliance well at the 1 percent significance level. 1,1-DCA (Wil 10) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 50 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:1,1-Dichloroethane NC MCL (mg/l):6 Method:Wilcoxon Rank Sum Background:MW-12 MW - 1 2 MW - 1 1 MD L 02/18/99 NP NP NT 08/16/99 NP NP NT 02/14/00 NP NP NT 08/14/00 NP NP NT 03/19/01 NP NP NT 08/27/02 NP NP NT 02/24/03 NP NP NT 08/11/03 NP NP 5 02/09/04 NP NP 5 08/16/04 NP NP 5 02/14/05 NP NP 5 09/01/05 NP NP 5 02/16/06 NP NP 5 08/30/06 NP NP 5 02/26/07 NP NP 5 08/13/07 NP NP 1 02/11/08 NP NP 1 08/25/08 NP NP 1 02/23/09 NP NP 1 08/24/09 NP NP 1 02/22/10 NP NP 1 08/30/10 NP NP 1 02/22/11 ND 7.5 1 08/22/11 ND 9.6 1 02/22/12 ND 8.5 1 08/29/12 ND 6.8 1 02/18/13 ND 5.7 1 08/26/13 ND 6.6 1 02/20/14 ND 5.2 1 08/28/14 ND 6 1 03/20/15 ND 5 1 08/26/15 ND 6.8 1 03/17/16 ND 6.8 1 1) Rank the N = 22 observations from the smallest to the largest from background wells and compliance well MW-11. n =11 m =11 N =22 Ci (MW-11) =187.0 # samples =11 11 sum of rank values (Ri) =66.0 187.0 avg rank value (Rbar) =6.0 17.0 Number of each rank value Rank Value rank value of NDs =11 0 6 rank value of 5s =0 1 12 rank value of 5.2s =0 1 13 rank value of 5.7s =0 1 14 rank value of 6s =0 1 15 1,1-DCA (Wil 11) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 51 of 96 rank value of 6.6s =0 1 16 rank value of 6.8s =0 3 18 rank value of 7.5s =0 1 20 rank value of 8.5s =0 1 21 rank value of 9.6s =0 1 22 0 0 0 0 0 0 # samples =11 11 2) Compute the Wilcoxon statistic by adding up the compliance well ranks and subtracting n/(n+1)/2. W = Ci - 1/2(n(n+1)) W = 121 3) Compute the expected value and standard deviation of W. E(W) = 1/2mn SD(W) = ((mn(N+1)/12)*(1-Sg i=1 (ti 3 - ti)/(N3 - N)))0.5 E(W) = 60.5 Adjustment for tie values: SD(W) = 14.233 4) Form the appropriate Z-score. Z = (W - E(W) - 0.5)/SD(W) Z = 4.216 5) Compare the observed Z-score to the upper 0.01 percentile of the normal distribution. Z = 4.216 Z0.01 = 2.326 Since Z is greater, there is significant evidence of contamination at the compliance well at the 1 percent significance level. 1,1-DCA (Wil 11) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 52 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:1,1-Dichloroethane NC MCL (mg/l):6 Method:Wilcoxon Rank Sum Background:MW-12 MW - 1 2 MW - 1 6 D MD L 02/18/99 NP NP NT 08/16/99 NP NP NT 02/14/00 NP NP NT 08/14/00 NP NP NT 03/19/01 NP NP NT 08/27/02 NP NP NT 02/24/03 NP NP NT 08/11/03 NP NP 5 02/09/04 NP NP 5 08/16/04 NP NP 5 02/14/05 NP NP 5 09/01/05 NP NP 5 02/16/06 NP NP 5 08/30/06 NP NP 5 02/26/07 NP NP 5 08/13/07 NP NP 1 02/11/08 NP NP 1 08/25/08 NP NP 1 02/23/09 NP NP 1 08/24/09 NP NP 1 02/22/10 NP NP 1 08/30/10 NP NP 1 02/22/11 ND NP 1 08/22/11 ND NP 1 02/22/12 ND NP 1 08/29/12 ND NP 1 02/18/13 ND 1.1 1 08/26/13 ND 1.1 1 02/20/14 ND 1.2 1 08/28/14 ND 1.4 1 03/20/15 ND 1.2 1 08/26/15 ND 1.5 1 03/17/16 ND 1.5 1 1) Rank the N = 18 observations from the smallest to the largest from background wells and compliance well MW-16D. n =7 m =11 N =18 Ci (MW-16D) =105.0 # samples =11 7 sum of rank values (Ri) =66.0 105.0 avg rank value (Rbar) =6.0 15.0 Number of each rank value Rank Value rank value of NDs =11 0 6 rank value of 1.1s =0 2 12.5 rank value of 1.2s =0 2 14.5 rank value of 1.4s =0 1 16 rank value of 1.5s =0 2 17.5 1,1-DCA (Wil 16D) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 53 of 96 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 # samples =11 7 2) Compute the Wilcoxon statistic by adding up the compliance well ranks and subtracting n/(n+1)/2. W = Ci - 1/2(n(n+1)) W = 77 3) Compute the expected value and standard deviation of W. E(W) = 1/2mn SD(W) = ((mn(N+1)/12)*(1-Sg i=1 (ti 3 - ti)/(N3 - N)))0.5 E(W) = 38.5 Adjustment for tie values: SD(W) = 9.688 4) Form the appropriate Z-score. Z = (W - E(W) - 0.5)/SD(W) Z = 3.922 5) Compare the observed Z-score to the upper 0.01 percentile of the normal distribution. Z = 3.922 Z0.01 = 2.326 Since Z is greater, there is significant evidence of contamination at the compliance well at the 1 percent significance level. 1,1-DCA (Wil 16D) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 54 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:1,1-Dichloroethane NC MCL (mg/l):6 Method:Wilcoxon Rank Sum Background:MW-12 MW - 1 2 MW - 1 9 MD L 02/18/99 NP NP NT 08/16/99 NP NP NT 02/14/00 NP NP NT 08/14/00 NP NP NT 03/19/01 NP NP NT 08/27/02 NP NP NT 02/24/03 NP NP NT 08/11/03 NP NP 5 02/09/04 NP NP 5 08/16/04 NP NP 5 02/14/05 NP NP 5 09/01/05 NP NP 5 02/16/06 NP NP 5 08/30/06 NP NP 5 02/26/07 NP NP 5 08/13/07 NP NP 1 02/11/08 NP NP 1 08/25/08 NP NP 1 02/23/09 NP NP 1 08/24/09 NP NP 1 02/22/10 NP NP 1 08/30/10 NP NP 1 02/22/11 ND NP 1 08/22/11 ND NP 1 02/22/12 ND 3.4 1 08/29/12 ND 4.5 1 02/18/13 ND 3.6 1 08/26/13 ND 2.8 1 02/20/14 ND 3.4 1 08/28/14 ND 3.9 1 03/20/15 ND 3 1 08/26/15 ND 3.8 1 03/17/16 ND 2.2 1 1) Rank the N = 20 observations from the smallest to the largest from background wells and compliance well MW-19. n =9 m =11 N =20 Ci (MW-19) =144.0 # samples =11 9 sum of rank values (Ri) =66.0 144.0 avg rank value (Rbar) =6.0 16.0 Number of each rank value Rank Value rank value of NDs =11 0 6 rank value of 2.2s =0 1 12 rank value of 2.8s =0 1 13 rank value of 3s =0 1 14 rank value of 3.4s =0 2 15.5 1,1-DCA (Wil 19) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 55 of 96 rank value of 3.6s =0 1 17 rank value of 3.8s =0 1 18 rank value of 3.9s =0 1 19 rank value of 4.5s =0 1 20 0 0 0 0 0 0 0 0 0 # samples =11 9 2) Compute the Wilcoxon statistic by adding up the compliance well ranks and subtracting n/(n+1)/2. W = Ci - 1/2(n(n+1)) W = 99 3) Compute the expected value and standard deviation of W. E(W) = 1/2mn SD(W) = ((mn(N+1)/12)*(1-Sg i=1 (ti 3 - ti)/(N3 - N)))0.5 E(W) = 49.5 Adjustment for tie values: SD(W) = 12.019 4) Form the appropriate Z-score. Z = (W - E(W) - 0.5)/SD(W) Z = 4.077 5) Compare the observed Z-score to the upper 0.01 percentile of the normal distribution. Z = 4.077 Z0.01 = 2.326 Since Z is greater, there is significant evidence of contamination at the compliance well at the 1 percent significance level. 1,1-DCA (Wil 19) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 56 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:1,1-Dichloroethane NC MCL (mg/l):6 Method:Wilcoxon Rank Sum Background:MW-12 MW - 1 2 MW - 1 9 D MD L 02/18/99 NP NP NT 08/16/99 NP NP NT 02/14/00 NP NP NT 08/14/00 NP NP NT 03/19/01 NP NP NT 08/27/02 NP NP NT 02/24/03 NP NP NT 08/11/03 NP NP 5 02/09/04 NP NP 5 08/16/04 NP NP 5 02/14/05 NP NP 5 09/01/05 NP NP 5 02/16/06 NP NP 5 08/30/06 NP NP 5 02/26/07 NP NP 5 08/13/07 NP NP 1 02/11/08 NP NP 1 08/25/08 NP NP 1 02/23/09 NP NP 1 08/24/09 NP NP 1 02/22/10 NP NP 1 08/30/10 NP NP 1 02/22/11 ND NP 1 08/22/11 ND NP 1 02/22/12 ND NP 1 08/29/12 ND NP 1 02/18/13 ND 3.4 1 08/26/13 ND 2.7 1 02/20/14 ND 2.3 1 08/28/14 ND 2.9 1 03/20/15 ND 2.4 1 08/26/15 ND 2.7 1 03/17/16 ND ND 1 1) Rank the N = 18 observations from the smallest to the largest from background wells and compliance well MW-19D. n =7 m =11 N =18 Ci (MW-19D) =99.5 # samples =11 7 sum of rank values (Ri) =71.5 99.5 avg rank value (Rbar) =6.5 14.2 Number of each rank value Rank Value rank value of NDs =11 1 6.5 rank value of 2.3s =0 1 13 rank value of 2.4s =0 1 14 rank value of 2.7s =0 2 15.5 rank value of 2.9s =0 1 17 1,1-DCA (Wil 19D) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 57 of 96 rank value of 3.4s =0 1 18 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 # samples =11 7 2) Compute the Wilcoxon statistic by adding up the compliance well ranks and subtracting n/(n+1)/2. W = Ci - 1/2(n(n+1)) W = 71.5 3) Compute the expected value and standard deviation of W. E(W) = 1/2mn SD(W) = ((mn(N+1)/12)*(1-Sg i=1 (ti 3 - ti)/(N3 - N)))0.5 E(W) = 38.5 Adjustment for tie values: SD(W) = 9.263 4) Form the appropriate Z-score. Z = (W - E(W) - 0.5)/SD(W) Z = 3.509 5) Compare the observed Z-score to the upper 0.01 percentile of the normal distribution. Z = 3.509 Z0.01 = 2.326 Since Z is greater, there is significant evidence of contamination at the compliance well at the 1 percent significance level. 1,1-DCA (Wil 19D) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 58 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:1,1-Dichloroethane NC MCL (mg/l):6 Method:Wilcoxon Rank Sum Background:MW-12 MW - 1 2 MW - 2 5 MD L 02/18/99 NP NP NT 08/16/99 NP NP NT 02/14/00 NP NP NT 08/14/00 NP NP NT 03/19/01 NP NP NT 08/27/02 NP NP NT 02/24/03 NP NP NT 08/11/03 NP NP 5 02/09/04 NP NP 5 08/16/04 NP NP 5 02/14/05 NP NP 5 09/01/05 NP NP 5 02/16/06 NP NP 5 08/30/06 NP NP 5 02/26/07 NP NP 5 08/13/07 NP NP 1 02/11/08 NP NP 1 08/25/08 NP NP 1 02/23/09 NP NP 1 08/24/09 NP NP 1 02/22/10 NP NP 1 08/30/10 NP NP 1 02/22/11 ND NP 1 08/22/11 ND NP 1 02/22/12 ND NP 1 08/29/12 ND NP 1 02/18/13 ND 3.1 1 08/26/13 ND 16.3 1 02/20/14 ND 8.7 1 08/28/14 ND 14.7 1 03/20/15 ND 10.9 1 08/26/15 ND 9.1 1 03/17/16 ND 11 1 1) Rank the N = 18 observations from the smallest to the largest from background wells and compliance well MW-25. n =7 m =11 N =18 Ci (MW-25) =105.0 # samples =11 7 sum of rank values (Ri) =66.0 105.0 avg rank value (Rbar) =6.0 15.0 Number of each rank value Rank Value rank value of NDs =11 0 6 rank value of 3.1s =0 1 12 rank value of 8.7s =0 1 13 rank value of 9.1s =0 1 14 rank value of 10.9s =0 1 15 1,1-DCA (Wil 25) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 59 of 96 rank value of 11s =0 1 16 rank value of 14.7s =0 1 17 rank value of 16.3s =0 1 18 0 0 0 0 0 0 0 0 0 0 0 0 # samples =11 7 2) Compute the Wilcoxon statistic by adding up the compliance well ranks and subtracting n/(n+1)/2. W = Ci - 1/2(n(n+1)) W = 77 3) Compute the expected value and standard deviation of W. E(W) = 1/2mn SD(W) = ((mn(N+1)/12)*(1-Sg i=1 (ti 3 - ti)/(N3 - N)))0.5 E(W) = 38.5 Adjustment for tie values: SD(W) = 9.708 4) Form the appropriate Z-score. Z = (W - E(W) - 0.5)/SD(W) Z = 3.914 5) Compare the observed Z-score to the upper 0.01 percentile of the normal distribution. Z = 3.914 Z0.01 = 2.326 Since Z is greater, there is significant evidence of contamination at the compliance well at the 1 percent significance level. 1,1-DCA (Wil 25) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 60 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:1,2-Dichloroethane NC MCL (mg/l):0.4 Method:Poisson Prediction Limits Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/09/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/16/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/14/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 09/01/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/16/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/30/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/26/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/13/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/11/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/25/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/23/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/24/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/30/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/11 ND ND ND 3 ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/22/11 ND ND ND 3.2 ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/12 ND ND ND 2.2 ND ND ND ND ND ND NP ND ND 3.2 NP ND NP ND NP NP NP NP NP 1 08/29/12 ND ND ND 1.7 ND ND ND ND ND ND NP ND ND 3.9 NP ND NP ND NP NP NP NP NP 1 02/18/13 ND ND ND 2.2 ND ND ND ND ND ND ND ND ND 3 3.7 ND ND ND ND ND NP ND ND 1 08/26/13 ND ND ND 1.9 ND ND ND ND ND ND ND ND ND 2.5 3 ND ND ND ND ND NP ND ND 1 02/20/14 ND ND ND 1.7 ND ND ND ND ND ND ND ND ND 3 2.6 ND ND ND ND ND ND ND ND 1 08/28/14 ND ND ND 2 ND ND ND ND ND ND ND ND ND 3 3 ND ND ND ND ND ND ND ND 1 03/20/15 ND ND ND 1.8 ND ND ND ND ND ND ND ND ND 2.6 3 ND ND ND ND ND ND ND ND 1 08/26/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 2.7 2.8 ND ND ND ND ND ND ND ND 1 03/17/16 ND ND ND 1.8 ND ND ND ND ND ND ND ND ND 1.3 ND ND ND ND ND ND ND ND ND 1 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 0. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 10 Tn1 = 5 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =10 Tn1 = 5 t [9,.01] =2.821 c =0.1 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Tn2 = 0.5 0.5 1.8 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.3 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 T*k =3.0 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. 1,2-DCA (PPL) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 61 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:1,1-Dichloroethene NC MCL (mg/l):7 Method:Poisson Prediction Limits Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/09/04 NP 11 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/16/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/14/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 09/01/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/16/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/30/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/26/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/13/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/11/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/25/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/23/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/24/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/30/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/11 ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/22/11 ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 08/29/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 02/18/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND 1 08/26/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND 1 02/20/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 08/28/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 03/20/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 08/26/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 03/17/16 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 0. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 10 Tn1 = 5 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =10 Tn1 = 5 t [9,.01] =2.821 c =0.1 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Tn2 = 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 T*k =3.0 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. 1,1-DCE (PPL) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 62 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:cis-1,2-Dichloroethene NC MCL (mg/l):70 Method:Kruskal-Wallis Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NP 21 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/09/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/16/04 NP 15 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/14/05 NP 20 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 09/01/05 NP 13 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/16/06 NP 7.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/30/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/26/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/13/07 NP 4.3 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/11/08 NP 4.5 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/25/08 NP 5.8 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/23/09 NP 5.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/24/09 NP 7.1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/10 NP 7.8 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/30/10 NP 6.1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/11 ND 14.4 ND 2.7 ND ND 2.3 10.9 8.9 NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/22/11 ND 11.5 ND 3.6 ND 2.3 2.1 10.1 7.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/12 ND 10.2 ND 2.4 ND ND 1.7 10.6 9 1.5 NP ND ND 1.3 NP ND NP ND NP NP NP NP NP 1 08/29/12 ND 8 ND 2.2 ND 1.6 1.3 15.1 5.3 1.2 NP ND ND 1.3 NP ND NP ND NP NP NP NP NP 1 02/18/13 ND 10.4 ND 2.6 ND ND 1.6 17.3 10.6 ND ND ND ND 1.1 ND ND ND ND ND ND NP ND 2 1 08/26/13 ND 8.6 ND 1.8 ND 1.1 1.4 17.2 4.5 ND ND ND ND 1.1 ND ND ND ND ND ND NP ND 23.2 1 02/20/14 ND 10.2 ND 1.6 ND 1 1.2 14.8 3.7 ND ND ND ND 1.9 ND ND ND ND ND ND ND ND 14.1 1 08/28/14 ND 7.9 ND 2.4 ND 1.5 1.6 17.4 3 ND 1 ND ND 1.7 ND ND 1.1 ND ND ND ND ND 14.8 1 03/20/15 ND 2.9 ND 1.8 ND ND 1.4 12.2 1.8 ND ND ND ND 1.3 ND ND ND ND ND ND ND ND 9.2 1 08/26/15 ND 2.4 ND 2.6 ND 1.3 1.3 12 2.2 ND ND ND ND 1.9 ND ND ND ND ND ND ND ND 5.2 1 03/17/16 ND 2.8 ND 1.9 ND 1.7 1.8 16 4.4 ND ND ND ND ND ND ND 1 ND ND ND ND ND 8 1 Ni 11 26 11 11 11 11 11 11 11 9 7 9 9 9 7 9 7 9 7 7 5 7 7 sum of rank values (Ri)709.5 4662.5 709.5 1818.0 709.5 1277.5 1644.5 2320.0 2007.0 734.5 517.0 580.5 580.5 1226.0 451.5 580.5 586.0 580.5 451.5 451.5 322.5 451.5 1381.0 avg rank value (Rbar)64.5 179.3 64.5 165.3 64.5 116.1 149.5 210.9 182.5 81.6 73.9 64.5 64.5 136.2 64.5 64.5 83.7 64.5 64.5 64.5 64.5 64.5 197.3 Number of each rank value Rank Value rank value of NDs =11 3 11 0 11 4 0 0 0 7 6 9 9 1 7 9 5 9 7 7 5 7 0 64.5 rank value of 1s =0 0 0 0 0 1 0 0 0 0 1 0 0 0 0 0 1 0 0 0 0 0 0 130 rank value of 1.1s =0 0 0 0 0 1 0 0 0 0 0 0 0 2 0 0 1 0 0 0 0 0 0 133.5 rank value of 1.2s =0 0 0 0 0 0 1 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 136.5 rank value of 1.3s =0 0 0 0 0 1 2 0 0 0 0 0 0 3 0 0 0 0 0 0 0 0 0 140.5 rank value of 1.4s =0 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 144.5 rank value of 1.5s =0 0 0 0 0 1 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 146.5 rank value of 1.6s =0 0 0 1 0 1 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 149.5 rank value of 1.7s =0 0 0 0 0 1 1 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 153 rank value of 1.8s =0 0 0 2 0 0 1 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 156.5 rank value of 1.9s =0 0 0 1 0 0 0 0 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0 160 rank value of 2s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 162 rank value of 2.1s =0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 163 rank value of 2.2s =0 0 0 1 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 164.5 rank value of 2.3s =0 0 0 0 0 1 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 166.5 rank value of 2.4s =0 1 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 169 rank value of 2.6s =0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 171.5 rank value of 2.7s =0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 173 rank value of 2.8s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 174 rank value of 2.9s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 175 rank value of 3s =0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 176 rank value of 3.6s =0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 177 rank value of 3.7s =0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 178 rank value of 4.3s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 179 rank value of 4.4s =0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 180 rank value of 4.5s =0 1 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 181.5 rank value of 5.2s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 183 rank value of 5.3s =0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 184 cis 1,2-DCE (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 63 of 96 rank value of 5.4s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 185 rank value of 5.8s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 186 rank value of 6.1s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 187 rank value of 7.1s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 188 rank value of 7.4s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 189 rank value of 7.7s =0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 190 rank value of 7.8s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 191 rank value of 7.9s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 192 rank value of 8s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 193.5 rank value of 8.6s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 195 rank value of 8.9s =0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 196 rank value of 9s =0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 197 rank value of 9.2s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 198 rank value of 10.1s =0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 199 rank value of 10.2s =0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 200.5 rank value of 10.4s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 202 rank value of 10.6s =0 0 0 0 0 0 0 1 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 203.5 rank value of 10.9s =0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 205 rank value of 11.5s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 206 rank value of 12s =0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 207 rank value of 12.2s =0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 208 rank value of 13s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 209 rank value of 14.1s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 210 rank value of 14.4s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 211 rank value of 14.8s =0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 212.5 rank value of 15s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 214 rank value of 15.1s =0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 215 rank value of 16s =0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 216 rank value of 17.2s =0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 217 rank value of 17.3s =0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 218 rank value of 17.4s =0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 219 rank value of 20s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 220 rank value of 21s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 221 rank value of 23.2s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 222 n =11 26 11 11 11 11 11 11 11 9 7 9 9 9 7 9 7 9 7 7 5 7 7 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SKi=1 (Ri2)/Ni]} -3(N+1) Well = Background MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Ri2/Ni = 45762.8 836112 45762.8 300466 45762.8 148364 245853 489309 366186 59943.4 38184.1 37442.3 37442.3 167008 29121.8 37442.3 49056.6 37442.3 29121.8 29121.8 20801.3 29121.8 272452 Ni bg = 11 N = 222 H = 154.48 Adjust H for ties: Ti =2097576 sum of T1..T20 H' = H/(1-(Ti/(N3-N))) H' =191.13 Chi-square =33.92 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 12df at the 5% significance level from Table 1 of the IFG. The value is 33.92 which is less than H' =191.13. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) cis 1,2-DCE (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 64 of 96 Well =MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Rbar (well x) = 179.327 64.5 165.273 64.5 116.136 149.5 210.909 182.455 81.6111 73.8571 64.5 64.5 136.222 64.5 64.5 83.7143 64.5 64.5 64.5 64.5 64.5 197.286 avg Rbar (background) = 64.5 64.5 64.5 64.5 64.5 64.5 64.5 64.5 64.5 64.5 64.5 64.5 64.5 64.5 64.5 64.5 64.5 64.5 64.5 64.5 64.5 64.5 Dx = 114.827 0 100.773 0 51.6364 85 146.409 117.955 17.1111 9.35714 0 0 71.7222 0 0 19.2143 0 0 0 0 0 132.786 Cx = 53.8285 63.8135 63.8135 63.8135 63.8135 63.8135 63.8135 63.8135 67.2654 72.3578 67.2654 67.2654 67.2654 72.3578 67.2654 72.3578 67.2654 72.3578 72.3578 80.7185 72.3578 72.3578 Statistical Significance ?Yes -Yes --Yes Yes Yes ----Yes --------Yes If SSI, is current event above MCL?No -No --No No No ----No --------No Compare each difference (Dx) with the corresponding critical value (Cx). The Dx value for the above indicated wells do exceed the corresponding Cx value. Therefore, we conclude that the concentration of cis-1,2-Dichloroethene averaged over these compliance wells are significantly greater than that of the background wells. Shewart-CUSUM Control Charts or Wilcoxon Rank Sum Tests should be performed for each failing well to check for statistical significance. cis 1,2-DCE (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 65 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:cis-1,2-Dichloroethene NC MCL (mg/l):70 Method:Wilcoxon Rank Sum Background:MW-12 MW - 1 2 MW - 7 MD L 02/18/99 NP NP NT 08/16/99 NP NP NT 02/14/00 NP NP NT 08/14/00 NP NP NT 03/19/01 NP NP NT 08/27/02 NP NP NT 02/24/03 NP NP NT 08/11/03 NP NP 5 02/09/04 NP NP 5 08/16/04 NP NP 5 02/14/05 NP NP 5 09/01/05 NP NP 5 02/16/06 NP NP 5 08/30/06 NP NP 5 02/26/07 NP NP 5 08/13/07 NP NP 1 02/11/08 NP NP 1 08/25/08 NP NP 1 02/23/09 NP NP 1 08/24/09 NP NP 1 02/22/10 NP NP 1 08/30/10 NP NP 1 02/22/11 ND 2.7 1 08/22/11 ND 3.6 1 02/22/12 ND 2.4 1 08/29/12 ND 2.2 1 02/18/13 ND 2.6 1 08/26/13 ND 1.8 1 02/20/14 ND 1.6 1 08/28/14 ND 2.4 1 03/20/15 ND 1.8 1 08/26/15 ND 2.6 1 03/17/16 ND 1.9 1 1) Rank the N = 22 observations from the smallest to the largest from background wells and compliance well MW-7. n =11 m =11 N =22 Ci (MW-7) =187.0 # samples =11 11 sum of rank values (Ri) =66.0 187.0 avg rank value (Rbar) =6.0 17.0 Number of each rank value Rank Value rank value of NDs =11 0 6 rank value of 1.6s =0 1 12 rank value of 1.8s =0 2 13.5 rank value of 1.9s =0 1 15 rank value of 2.2s =0 1 16 cis 1,2-DCE (Wil 7) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 66 of 96 rank value of 2.4s =0 2 17.5 rank value of 2.6s =0 2 19.5 rank value of 2.7s =0 1 21 rank value of 3.6s =0 1 22 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 # samples =11 11 2) Compute the Wilcoxon statistic by adding up the compliance well ranks and subtracting n/(n+1)/2. W = Ci - 1/2(n(n+1)) W = 121 3) Compute the expected value and standard deviation of W. E(W) = 1/2mn SD(W) = ((mn(N+1)/12)*(1-Sg i=1 (ti 3 - ti)/(N3 - N)))0.5 E(W) = 60.5 Adjustment for tie values: SD(W) = 14.238 4) Form the appropriate Z-score. Z = (W - E(W) - 0.5)/SD(W) Z = 4.214 5) Compare the observed Z-score to the upper 0.01 percentile of the normal distribution. Z = 4.214 Z0.01 = 2.326 Since Z is greater, there is significant evidence of contamination at the compliance well at the 1 percent significance level. cis 1,2-DCE (Wil 7) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 67 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:cis-1,2-Dichloroethene NC MCL (mg/l):70 Method:Wilcoxon Rank Sum Background:MW-12 MW - 1 2 MW - 1 0 MD L 02/18/99 NP NP NT 08/16/99 NP NP NT 02/14/00 NP NP NT 08/14/00 NP NP NT 03/19/01 NP NP NT 08/27/02 NP NP NT 02/24/03 NP NP NT 08/11/03 NP NP 5 02/09/04 NP NP 5 08/16/04 NP NP 5 02/14/05 NP NP 5 09/01/05 NP NP 5 02/16/06 NP NP 5 08/30/06 NP NP 5 02/26/07 NP NP 5 08/13/07 NP NP 1 02/11/08 NP NP 1 08/25/08 NP NP 1 02/23/09 NP NP 1 08/24/09 NP NP 1 02/22/10 NP NP 1 08/30/10 NP NP 1 02/22/11 ND 2.3 1 08/22/11 ND 2.1 1 02/22/12 ND 1.7 1 08/29/12 ND 1.3 1 02/18/13 ND 1.6 1 08/26/13 ND 1.4 1 02/20/14 ND 1.2 1 08/28/14 ND 1.6 1 03/20/15 ND 1.4 1 08/26/15 ND 1.3 1 03/17/16 ND 1.8 1 1) Rank the N = 22 observations from the smallest to the largest from background wells and compliance well MW-10. n =11 m =11 N =22 Ci (MW-10) =187.0 # samples =11 11 sum of rank values (Ri) =66.0 187.0 avg rank value (Rbar) =6.0 17.0 Number of each rank value Rank Value rank value of NDs =11 0 6 rank value of 1.2s =0 1 12 rank value of 1.3s =0 2 13.5 rank value of 1.4s =0 2 15.5 rank value of 1.6s =0 2 17.5 cis 1,2-DCE (Wil 10) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 68 of 96 rank value of 1.7s =0 1 19 rank value of 1.8s =0 1 20 rank value of 2.1s =0 1 21 rank value of 2.3s =0 1 22 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 # samples =11 11 2) Compute the Wilcoxon statistic by adding up the compliance well ranks and subtracting n/(n+1)/2. W = Ci - 1/2(n(n+1)) W = 121 3) Compute the expected value and standard deviation of W. E(W) = 1/2mn SD(W) = ((mn(N+1)/12)*(1-Sg i=1 (ti 3 - ti)/(N3 - N)))0.5 E(W) = 60.5 Adjustment for tie values: SD(W) = 14.238 4) Form the appropriate Z-score. Z = (W - E(W) - 0.5)/SD(W) Z = 4.214 5) Compare the observed Z-score to the upper 0.01 percentile of the normal distribution. Z = 4.214 Z0.01 = 2.326 Since Z is greater, there is significant evidence of contamination at the compliance well at the 1 percent significance level. cis 1,2-DCE (Wil 10) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 69 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:cis-1,2-Dichloroethene NC MCL (mg/l):70 Method:Wilcoxon Rank Sum Background:MW-12 MW - 1 2 MW - 1 1 MD L 02/18/99 NP NP NT 08/16/99 NP NP NT 02/14/00 NP NP NT 08/14/00 NP NP NT 03/19/01 NP NP NT 08/27/02 NP NP NT 02/24/03 NP NP NT 08/11/03 NP NP 5 02/09/04 NP NP 5 08/16/04 NP NP 5 02/14/05 NP NP 5 09/01/05 NP NP 5 02/16/06 NP NP 5 08/30/06 NP NP 5 02/26/07 NP NP 5 08/13/07 NP NP 1 02/11/08 NP NP 1 08/25/08 NP NP 1 02/23/09 NP NP 1 08/24/09 NP NP 1 02/22/10 NP NP 1 08/30/10 NP NP 1 02/22/11 ND 10.9 1 08/22/11 ND 10.1 1 02/22/12 ND 10.6 1 08/29/12 ND 15.1 1 02/18/13 ND 17.3 1 08/26/13 ND 17.2 1 02/20/14 ND 14.8 1 08/28/14 ND 17.4 1 03/20/15 ND 12.2 1 08/26/15 ND 12 1 03/17/16 ND 16 1 1) Rank the N = 22 observations from the smallest to the largest from background wells and compliance well MW-11. n =11 m =11 N =22 Ci (MW-11) =187.0 # samples =11 11 sum of rank values (Ri) =66.0 187.0 avg rank value (Rbar) =6.0 17.0 Number of each rank value Rank Value rank value of NDs =11 0 6 rank value of 10.1s =0 1 12 rank value of 10.6s =0 1 13 rank value of 10.9s =0 1 14 rank value of 12s =0 1 15 cis 1,2-DCE (Wil 11) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 70 of 96 rank value of 12.2s =0 1 16 rank value of 14.8s =0 1 17 rank value of 15.1s =0 1 18 rank value of 16s =0 1 19 rank value of 17.2s =0 1 20 rank value of 17.3s =0 1 21 rank value of 17.4s =0 1 22 # samples =11 11 2) Compute the Wilcoxon statistic by adding up the compliance well ranks and subtracting n/(n+1)/2. W = Ci - 1/2(n(n+1)) W = 121 3) Compute the expected value and standard deviation of W. E(W) = 1/2mn SD(W) = ((mn(N+1)/12)*(1-Sg i=1 (ti 3 - ti)/(N3 - N)))0.5 E(W) = 60.5 Adjustment for tie values: SD(W) = 14.252 4) Form the appropriate Z-score. Z = (W - E(W) - 0.5)/SD(W) Z = 4.210 5) Compare the observed Z-score to the upper 0.01 percentile of the normal distribution. Z = 4.210 Z0.01 = 2.326 Since Z is greater, there is significant evidence of contamination at the compliance well at the 1 percent significance level. cis 1,2-DCE (Wil 11) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 71 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:cis-1,2-Dichloroethene NC MCL (mg/l):70 Method:Wilcoxon Rank Sum Background:MW-12 MW - 1 2 MW - 1 5 MD L 02/18/99 NP NP NT 08/16/99 NP NP NT 02/14/00 NP NP NT 08/14/00 NP NP NT 03/19/01 NP NP NT 08/27/02 NP NP NT 02/24/03 NP NP NT 08/11/03 NP NP 5 02/09/04 NP NP 5 08/16/04 NP NP 5 02/14/05 NP NP 5 09/01/05 NP NP 5 02/16/06 NP NP 5 08/30/06 NP NP 5 02/26/07 NP NP 5 08/13/07 NP NP 1 02/11/08 NP NP 1 08/25/08 NP NP 1 02/23/09 NP NP 1 08/24/09 NP NP 1 02/22/10 NP NP 1 08/30/10 NP NP 1 02/22/11 ND 8.9 1 08/22/11 ND 7.7 1 02/22/12 ND 9 1 08/29/12 ND 5.3 1 02/18/13 ND 10.6 1 08/26/13 ND 4.5 1 02/20/14 ND 3.7 1 08/28/14 ND 3 1 03/20/15 ND 1.8 1 08/26/15 ND 2.2 1 03/17/16 ND 4.4 1 1) Rank the N = 22 observations from the smallest to the largest from background wells and compliance well MW-15. n =11 m =11 N =22 Ci (MW-15) =187.0 # samples =11 11 sum of rank values (Ri) =66.0 187.0 avg rank value (Rbar) =6.0 17.0 Number of each rank value Rank Value rank value of NDs =11 0 6 rank value of 1.8s =0 1 12 rank value of 2.2s =0 1 13 rank value of 3s =0 1 14 rank value of 3.7s =0 1 15 cis 1,2-DCE (Wil 15) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 72 of 96 rank value of 4.4s =0 1 16 rank value of 4.5s =0 1 17 rank value of 5.3s =0 1 18 rank value of 7.7s =0 1 19 rank value of 8.9s =0 1 20 rank value of 9s =0 1 21 rank value of 10.6s =0 1 22 # samples =11 11 2) Compute the Wilcoxon statistic by adding up the compliance well ranks and subtracting n/(n+1)/2. W = Ci - 1/2(n(n+1)) W = 121 3) Compute the expected value and standard deviation of W. E(W) = 1/2mn SD(W) = ((mn(N+1)/12)*(1-Sg i=1 (ti 3 - ti)/(N3 - N)))0.5 E(W) = 60.5 Adjustment for tie values: SD(W) = 14.252 4) Form the appropriate Z-score. Z = (W - E(W) - 0.5)/SD(W) Z = 4.210 5) Compare the observed Z-score to the upper 0.01 percentile of the normal distribution. Z = 4.210 Z0.01 = 2.326 Since Z is greater, there is significant evidence of contamination at the compliance well at the 1 percent significance level. cis 1,2-DCE (Wil 15) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 73 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:cis-1,2-Dichloroethene NC MCL (mg/l):70 Method:Wilcoxon Rank Sum Background:MW-12 MW - 1 2 MW - 1 9 MD L 02/18/99 NP NP NT 08/16/99 NP NP NT 02/14/00 NP NP NT 08/14/00 NP NP NT 03/19/01 NP NP NT 08/27/02 NP NP NT 02/24/03 NP NP NT 08/11/03 NP NP 5 02/09/04 NP NP 5 08/16/04 NP NP 5 02/14/05 NP NP 5 09/01/05 NP NP 5 02/16/06 NP NP 5 08/30/06 NP NP 5 02/26/07 NP NP 5 08/13/07 NP NP 1 02/11/08 NP NP 1 08/25/08 NP NP 1 02/23/09 NP NP 1 08/24/09 NP NP 1 02/22/10 NP NP 1 08/30/10 NP NP 1 02/22/11 ND NP 1 08/22/11 ND NP 1 02/22/12 ND 1.3 1 08/29/12 ND 1.3 1 02/18/13 ND 1.1 1 08/26/13 ND 1.1 1 02/20/14 ND 1.9 1 08/28/14 ND 1.7 1 03/20/15 ND 1.3 1 08/26/15 ND 1.9 1 03/17/16 ND ND 1 1) Rank the N = 20 observations from the smallest to the largest from background wells and compliance well MW-19. n =9 m =11 N =20 Ci (MW-19) =138.5 # samples =11 9 sum of rank values (Ri) =71.5 138.5 avg rank value (Rbar) =6.5 15.4 Number of each rank value Rank Value rank value of NDs =11 1 6.5 rank value of 1.1s =0 2 13.5 rank value of 1.3s =0 3 16 rank value of 1.7s =0 1 18 rank value of 1.9s =0 2 19.5 cis 1,2-DCE (Wil 19) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 74 of 96 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 # samples =11 9 2) Compute the Wilcoxon statistic by adding up the compliance well ranks and subtracting n/(n+1)/2. W = Ci - 1/2(n(n+1)) W = 93.5 3) Compute the expected value and standard deviation of W. E(W) = 1/2mn SD(W) = ((mn(N+1)/12)*(1-Sg i=1 (ti 3 - ti)/(N3 - N)))0.5 E(W) = 49.5 Adjustment for tie values: SD(W) = 11.628 4) Form the appropriate Z-score. Z = (W - E(W) - 0.5)/SD(W) Z = 3.741 5) Compare the observed Z-score to the upper 0.01 percentile of the normal distribution. Z = 3.741 Z0.01 = 2.326 Since Z is greater, there is significant evidence of contamination at the compliance well at the 1 percent significance level. cis 1,2-DCE (Wil 19) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 75 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:cis-1,2-Dichloroethene NC MCL (mg/l):70 Method:Wilcoxon Rank Sum Background:MW-12 MW - 1 2 MW - 2 5 MD L 02/18/99 NP NP NT 08/16/99 NP NP NT 02/14/00 NP NP NT 08/14/00 NP NP NT 03/19/01 NP NP NT 08/27/02 NP NP NT 02/24/03 NP NP NT 08/11/03 NP NP 5 02/09/04 NP NP 5 08/16/04 NP NP 5 02/14/05 NP NP 5 09/01/05 NP NP 5 02/16/06 NP NP 5 08/30/06 NP NP 5 02/26/07 NP NP 5 08/13/07 NP NP 1 02/11/08 NP NP 1 08/25/08 NP NP 1 02/23/09 NP NP 1 08/24/09 NP NP 1 02/22/10 NP NP 1 08/30/10 NP NP 1 02/22/11 ND NP 1 08/22/11 ND NP 1 02/22/12 ND NP 1 08/29/12 ND NP 1 02/18/13 ND 2 1 08/26/13 ND 23.2 1 02/20/14 ND 14.1 1 08/28/14 ND 14.8 1 03/20/15 ND 9.2 1 08/26/15 ND 5.2 1 03/17/16 ND 8 1 1) Rank the N = 18 observations from the smallest to the largest from background wells and compliance well MW-25. n =7 m =11 N =18 Ci (MW-25) =105.0 # samples =11 7 sum of rank values (Ri) =66.0 105.0 avg rank value (Rbar) =6.0 15.0 Number of each rank value Rank Value rank value of NDs =11 0 6 rank value of 2s =0 1 12 rank value of 5.2s =0 1 13 rank value of 8s =0 1 14 rank value of 9.2s =0 1 15 cis 1,2-DCE (Wil 25) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 76 of 96 rank value of 14.1s =0 1 16 rank value of 14.8s =0 1 17 rank value of 23.2s =0 1 18 0 0 0 0 0 0 0 0 0 0 0 0 # samples =11 7 2) Compute the Wilcoxon statistic by adding up the compliance well ranks and subtracting n/(n+1)/2. W = Ci - 1/2(n(n+1)) W = 77 3) Compute the expected value and standard deviation of W. E(W) = 1/2mn SD(W) = ((mn(N+1)/12)*(1-Sg i=1 (ti 3 - ti)/(N3 - N)))0.5 E(W) = 38.5 Adjustment for tie values: SD(W) = 9.708 4) Form the appropriate Z-score. Z = (W - E(W) - 0.5)/SD(W) Z = 3.914 5) Compare the observed Z-score to the upper 0.01 percentile of the normal distribution. Z = 3.914 Z0.01 = 2.326 Since Z is greater, there is significant evidence of contamination at the compliance well at the 1 percent significance level. cis 1,2-DCE (Wil 25) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 77 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:cis-1,3-Dichloropropene NC MCL (mg/l):0.4 Method:Poisson Prediction Limits Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/09/04 NP 8.1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/16/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 02/14/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 09/01/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/16/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/30/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/26/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/13/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/11/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/25/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/23/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/24/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/30/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/11 ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/22/11 ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 08/29/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 02/18/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND 1 08/26/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND 1 02/20/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 08/28/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 03/20/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 08/26/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 03/17/16 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 0. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 10 Tn1 = 5 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =10 Tn1 = 5 t [9,.01] =2.821 c =0.1 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Tn2 = 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 T*k =3.0 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. cis 1,3-DCP (PPL) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 78 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Dichloromethane NC MCL (mg/l):5 Method:Poisson Prediction Limits Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NP 21 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/09/04 NP 8.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/16/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 02/14/05 NP 12 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 09/01/05 NP 7.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/16/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/30/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/26/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/13/07 NP 2.9 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 02/11/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 08/25/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 02/23/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 08/24/09 NP 2.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 02/22/10 NP 2.9 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 08/30/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 02/22/11 ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 08/22/11 ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 02/22/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 2 08/29/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 02/18/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND 2.4 1 08/26/13 ND 2.9 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND 28.3 1 02/20/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 08/28/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5.5 2 03/20/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4.9 1 08/26/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 03/17/16 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 0. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 10 Tn1 = 7 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =10 Tn1 = 7 t [9,.01] =2.821 c =0.1 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Tn2 = 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 T*k =3.6 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. DCM (PPL) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 79 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Tetrachloroethene NC MCL (mg/l):0.7 Method:Kruskal-Wallis Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 4 MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NP 8.9 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/09/04 NP 6.2 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/16/04 NP 5.8 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/14/05 NP 6.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 09/01/05 NP 5.4 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/16/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/30/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/26/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/13/07 NP 3.6 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/11/08 NP 3.5 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/25/08 NP 3.9 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/23/09 NP 3.9 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/24/09 NP 4.2 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/10 NP 5.1 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/30/10 NP 6.3 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/11 ND 5.6 ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/22/11 ND 4.6 ND ND ND 1.2 ND 1 ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/12 ND 3.7 ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 08/29/12 ND 3.7 ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 02/18/13 ND 4.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND 1 08/26/13 ND 4.4 ND ND ND ND ND 1 ND ND ND ND ND ND ND ND ND ND ND ND NP ND 3.3 1 02/20/14 ND 5.1 ND ND ND ND ND 1.1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.3 1 08/28/14 ND 4.2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.6 1 03/20/15 ND 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 1 08/26/15 ND 2.6 ND ND ND ND ND 1.1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 03/17/16 ND 3.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.5 1 Ni 11 26 11 11 11 11 11 11 11 9 7 9 9 9 7 9 7 9 7 7 5 7 7 sum of rank values (Ri)1045.0 5135.5 1045.0 1045.0 1045.0 1145.0 1045.0 1434.0 1045.0 855.0 665.0 855.0 855.0 855.0 665.0 855.0 665.0 855.0 665.0 665.0 475.0 665.0 1173.5 avg rank value (Rbar)95.0 197.5 95.0 95.0 95.0 104.1 95.0 130.4 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 167.6 Number of each rank value Rank Value rank value of NDs =11 3 11 11 11 10 11 7 11 9 7 9 9 9 7 9 7 9 7 7 5 7 2 95 rank value of 1s =0 0 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 191 rank value of 1.1s =0 0 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 193.5 rank value of 1.2s =0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 195 rank value of 1.3s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 196 rank value of 1.5s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 197 rank value of 1.6s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 198 rank value of 2.6s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 199 rank value of 3s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 200 rank value of 3.3s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 201.5 rank value of 3.5s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 203 rank value of 3.6s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 204 PCE (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 80 of 96 rank value of 3.7s =0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 205.5 rank value of 3.9s =0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 207.5 rank value of 4.2s =0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 209.5 rank value of 4.4s =0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 211.5 rank value of 4.6s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 213 rank value of 5.1s =0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 214.5 rank value of 5.4s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 216 rank value of 5.6s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 217 rank value of 5.8s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 218 rank value of 6.2s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 219 rank value of 6.3s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 220 rank value of 6.4s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 221 rank value of 8.9s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 222 n =11 26 11 11 11 11 11 11 11 9 7 9 9 9 7 9 7 9 7 7 5 7 7 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SK i=1 (Ri 2)/Ni]} -3(N+1) Well = Background MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 4 MW - 2 4 MW - 2 5 Ri2/Ni = 99275.0 1014360 99275 99275 99275 119184 99275 186941 99275 81225 63175 81225 81225 81225 63175 81225 63175 81225 63175 63175 45125 63175 196729 Ni bg = 11 N = 222 H = 64.10 Adjust H for ties: Ti =6751146 sum of T1..T9 H' = H/(1-(Ti/(N3-N))) H' =167.38 Chi-square =33.92 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 12df at the 5% significance level from Table 1 of the IFG. The value is 33.92 which is less than H' =167.38. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution PCE (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 81 of 96 from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 4 MW - 2 4 MW - 2 5 Rbar (well x) = 197.5 95.0 95.0 95.0 104.1 95.0 130.4 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 167.6 avg Rbar (background) = 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 Dx = 102.5 0.0 0.0 0.0 9.1 0.0 35.4 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 72.6 Cx = 53.8 63.8 63.8 63.8 63.8 63.8 63.8 63.8 67.3 72.4 67.3 67.3 67.3 72.4 67.3 72.4 67.3 72.4 72.4 80.7 72.4 72.4 Statistical Significance ?Yes --------------------Yes If SSI, is current event above MCL?Yes --------------------Yes Compare each difference (Dx) with the corresponding critical value (Cx). The Dx value for the above indicated wells do exceed the corresponding Cx value. Therefore, we conclude that the concentration of Tetrachloroethene averaged over these compliance wells are significantly greater than that of the background wells. Shewart-CUSUM Control Charts or Wilcoxon Rank Sum Tests should be performed for each failing well to check for statistical significance. PCE (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 82 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Tetrachloroethene NC MCL (mg/l):0.7 Method:Wilcoxon Rank Sum Background:MW-12 MW - 1 2 MW - 5 MD L 02/18/99 NP NS NT 08/16/99 NP NS NT 02/14/00 NP NS NT 08/14/00 NP NT NT 03/19/01 NP NT NT 08/27/02 NP NT NT 02/24/03 NP NT NT 08/11/03 NP 8.9 5 02/09/04 NP 6.2 5 08/16/04 NP 5.8 5 02/14/05 NP 6.4 5 09/01/05 NP 5.4 5 02/16/06 NP ND 5 08/30/06 NP ND 5 02/26/07 NP ND 5 08/13/07 NP 3.6 1 02/11/08 NP 3.5 1 08/25/08 NP 3.9 1 02/23/09 NP 3.9 1 08/24/09 NP 4.2 1 02/22/10 NP 5.1 1 08/30/10 NP 6.3 1 02/22/11 ND 5.6 1 08/22/11 ND 4.6 1 02/22/12 ND 3.7 1 08/29/12 ND 3.7 1 02/18/13 ND 4.4 1 08/26/13 ND 4.4 1 02/20/14 ND 5.1 1 08/28/14 ND 4.2 1 03/20/15 ND 3 1 08/26/15 ND 2.6 1 03/17/16 ND 3.3 1 1) Rank the N = 37 observations from the smallest to the largest from background wells and compliance well MW-5. n =26 m =11 N =37 Ci (MW-5) =620.5 # samples =11 26 sum of rank values (Ri) =82.5 620.5 avg rank value (Rbar) =7.5 23.9 Number of each rank value Rank Value rank value of NDs =11 3 7.5 rank value of 2.6s =0 1 15 rank value of 3s =0 1 16 rank value of 3.3s =0 1 17 rank value of 3.5s =0 1 18 PCE (Wil 5) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 83 of 96 rank value of 3.6s =0 1 19 rank value of 3.7s =0 2 20.5 rank value of 3.9s =0 2 22.5 rank value of 4.2s =0 2 24.5 rank value of 4.4s =0 2 26.5 rank value of 4.6s =0 1 28 rank value of 5.1s =0 2 29.5 rank value of 5.4s =0 1 31 rank value of 5.6s =0 1 32 rank value of 5.8s =0 1 33 rank value of 6.2s =0 1 34 rank value of 6.3s =0 1 35 rank value of 6.4s =0 1 36 rank value of 8.9s =0 1 37 0 0 0 0 0 0 0 0 0 # samples =11 26 2) Compute the Wilcoxon statistic by adding up the compliance well ranks and subtracting n/(n+1)/2. W = Ci - 1/2(n(n+1)) W = 269.5 3) Compute the expected value and standard deviation of W. E(W) = 1/2mn SD(W) = ((mn(N+1)/12)*(1-Sg i=1 (ti 3 - ti)/(N3 - N)))0.5 E(W) = 143 Adjustment for tie values: SD(W) = 29.262 4) Form the appropriate Z-score. Z = (W - E(W) - 0.5)/SD(W) Z = 4.306 5) Compare the observed Z-score to the upper 0.01 percentile of the normal distribution. Z = 4.306 Z0.01 = 2.326 Since Z is greater, there is significant evidence of contamination at the compliance well at the 1 percent significance level. PCE (Wil 5) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 84 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Tetrachloroethene NC MCL (mg/l):0.7 Method:Wilcoxon Rank Sum Background:MW-12 MW - 1 2 MW - 2 5 MD L 02/18/99 NP NP NT 08/16/99 NP NP NT 02/14/00 NP NP NT 08/14/00 NP NP NT 03/19/01 NP NP NT 08/27/02 NP NP NT 02/24/03 NP NP NT 08/11/03 NP NP 5 02/09/04 NP NP 5 08/16/04 NP NP 5 02/14/05 NP NP 5 09/01/05 NP NP 5 02/16/06 NP NP 5 08/30/06 NP NP 5 02/26/07 NP NP 5 08/13/07 NP NP 1 02/11/08 NP NP 1 08/25/08 NP NP 1 02/23/09 NP NP 1 08/24/09 NP NP 1 02/22/10 NP NP 1 08/30/10 NP NP 1 02/22/11 ND NP 1 08/22/11 ND NP 1 02/22/12 ND NP 1 08/29/12 ND NP 1 02/18/13 ND ND 1 08/26/13 ND 3.3 1 02/20/14 ND 1.3 1 08/28/14 ND 1.6 1 03/20/15 ND 1 1 08/26/15 ND ND 1 03/17/16 ND 1.5 1 1) Rank the N = 18 observations from the smallest to the largest from background wells and compliance well MW-25. n =7 m =11 N =18 Ci (MW-25) =94.0 # samples =11 7 sum of rank values (Ri) =77.0 94.0 avg rank value (Rbar) =7.0 13.4 Number of each rank value Rank Value rank value of NDs =11 2 7 rank value of 1s =0 1 14 rank value of 1.3s =0 1 15 rank value of 1.5s =0 1 16 rank value of 1.6s =0 1 17 PCE (Wil 25) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 85 of 96 rank value of 3.3s =0 1 18 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 # samples =11 7 2) Compute the Wilcoxon statistic by adding up the compliance well ranks and subtracting n/(n+1)/2. W = Ci - 1/2(n(n+1)) W = 66 3) Compute the expected value and standard deviation of W. E(W) = 1/2mn SD(W) = ((mn(N+1)/12)*(1-Sg i=1 (ti 3 - ti)/(N3 - N)))0.5 E(W) = 38.5 Adjustment for tie values: SD(W) = 8.725 4) Form the appropriate Z-score. Z = (W - E(W) - 0.5)/SD(W) Z = 3.095 5) Compare the observed Z-score to the upper 0.01 percentile of the normal distribution. Z = 3.095 Z0.01 = 2.326 Since Z is greater, there is significant evidence of contamination at the compliance well at the 1 percent significance level. PCE (Wil 25) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 86 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Trichloroethene NC MCL (mg/l):3 Method:Kruskal-Wallis Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NP 11 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/09/04 NP 6.2 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/16/04 NP 5.5 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/14/05 NP 7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 09/01/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/16/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/30/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/26/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 08/13/07 NP 2.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/11/08 NP 2.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/25/08 NP 3 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/23/09 NP 3 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/24/09 NP 3.5 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/10 NP 4.7 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/30/10 NP 5.8 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/11 ND 4.8 ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/22/11 ND 3.7 ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/12 ND 3.6 ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 08/29/12 ND 3.4 ND ND ND ND ND 1.1 ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 02/18/13 ND 3.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND 1 08/26/13 ND 3.8 ND ND ND ND ND 1.1 ND ND ND ND ND ND ND ND ND ND ND ND NP ND 3.7 1 02/20/14 ND 4.1 ND ND ND ND ND 1.2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.9 1 08/28/14 ND 3.6 ND ND ND ND ND 1.1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2.2 1 03/20/15 ND 2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.3 1 08/26/15 ND 1.6 ND ND ND ND ND 1.1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 03/17/16 ND 1.7 ND ND ND ND ND 1.1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.7 1 Ni 11 26 11 11 11 11 11 11 11 9 7 9 9 9 7 9 7 9 7 7 5 7 7 sum of rank values (Ri)1045.0 5014.0 1045.0 1045.0 1045.0 1045.0 1045.0 1630.0 1045.0 855.0 665.0 855.0 855.0 855.0 665.0 855.0 665.0 855.0 665.0 665.0 475.0 665.0 1199.0 avg rank value (Rbar)95.0 192.8 95.0 95.0 95.0 95.0 95.0 148.2 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 171.3 Number of each rank value Rank Value rank value of NDs =11 4 11 11 11 11 11 5 11 9 7 9 9 9 7 9 7 9 7 7 5 7 2 95 rank value of 1.1s =0 0 0 0 0 0 0 5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 192 rank value of 1.2s =0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 195 rank value of 1.3s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 196 rank value of 1.6s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 197 rank value of 1.7s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 198.5 rank value of 1.9s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 200 rank value of 2s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 201 rank value of 2.2s =0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 202 rank value of 2.7s =0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 203.5 rank value of 3s =0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 205.5 rank value of 3.3s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 207 TCE (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 87 of 96 rank value of 3.4s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 208 rank value of 3.5s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 209 rank value of 3.6s =0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 210.5 rank value of 3.7s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 212.5 rank value of 3.8s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 214 rank value of 4.1s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 215 rank value of 4.7s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 216 rank value of 4.8s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 217 rank value of 5.5s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 218 rank value of 5.8s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 219 rank value of 6.2s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 220 rank value of 7s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 221 rank value of 11s =0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 222 n =11 26 11 11 11 11 11 11 11 9 7 9 9 9 7 9 7 9 7 7 5 7 7 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SK i=1 (Ri 2)/Ni]} -3(N+1) Well = Background MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Ri2/Ni = 99275.0 966931 99275 99275 99275 99275 99275 241536 99275 81225 63175 81225 81225 81225 63175 81225 63175 81225 63175 63175 45125 63175 205372 Ni bg = 11 N = 222 H = 63.10 Adjust H for ties: Ti =6751230 sum of T1..T7 H' = H/(1-(Ti/(N3-N))) H' =164.79 Chi-square =33.92 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 12df at the 5% significance level from Table 1 of the IFG. The value is 33.92 which is less than H' =164.79. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data TCE (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 88 of 96 Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Rbar (well x) = 192.8 95.0 95.0 95.0 95.0 95.0 148.2 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 171.3 avg Rbar (background) = 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 95.0 Dx = 97.8 0.0 0.0 0.0 0.0 0.0 53.2 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 76.3 Cx = 53.8 63.8 63.8 63.8 63.8 63.8 63.8 63.8 67.3 72.4 67.3 67.3 67.3 72.4 67.3 72.4 67.3 72.4 72.4 80.7 72.4 72.4 Statistical Significance ?Yes --------------------Yes If SSI, is current event above MCL?No --------------------No Compare each difference (Dx) with the corresponding critical value (Cx). The Dx value for the above indicated wells do exceed the corresponding Cx value. Therefore, we conclude that the concentration of Trichloroethene averaged over these compliance wells are significantly greater than that of the background wells. Shewart-CUSUM Control Charts or Wilcoxon Rank Sum Tests should be performed for each failing well to check for statistical significance. TCE (K-W) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 89 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Trichloroethene NC MCL (mg/l):3 Method:Wilcoxon Rank Sum Background:MW-12 MW - 1 2 MW - 5 MD L 02/18/99 NP NS NT 08/16/99 NP NS NT 02/14/00 NP NS NT 08/14/00 NP NT NT 03/19/01 NP NT NT 08/27/02 NP NT NT 02/24/03 NP NT NT 08/11/03 NP 11 5 02/09/04 NP 6.2 5 08/16/04 NP 5.5 5 02/14/05 NP 7 5 09/01/05 NP ND 5 02/16/06 NP ND 5 08/30/06 NP ND 5 02/26/07 NP ND 5 08/13/07 NP 2.7 1 02/11/08 NP 2.7 1 08/25/08 NP 3 1 02/23/09 NP 3 1 08/24/09 NP 3.5 1 02/22/10 NP 4.7 1 08/30/10 NP 5.8 1 02/22/11 ND 4.8 1 08/22/11 ND 3.7 1 02/22/12 ND 3.6 1 08/29/12 ND 3.4 1 02/18/13 ND 3.3 1 08/26/13 ND 3.8 1 02/20/14 ND 4.1 1 08/28/14 ND 3.6 1 03/20/15 ND 2 1 08/26/15 ND 1.6 1 03/17/16 ND 1.7 1 1) Rank the N = 37 observations from the smallest to the largest from background wells and compliance well MW-5. n =26 m =11 N =37 Ci (MW-5) =615.0 # samples =11 26 sum of rank values (Ri) =88.0 615.0 avg rank value (Rbar) =8.0 23.7 Number of each rank value Rank Value rank value of NDs =11 4 8 rank value of 1.6s =0 1 16 rank value of 1.7s =0 1 17 rank value of 2s =0 1 18 rank value of 2.7s =0 2 19.5 TCE (Wil 5) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 90 of 96 rank value of 3s =0 2 21.5 rank value of 3.3s =0 1 23 rank value of 3.4s =0 1 24 rank value of 3.5s =0 1 25 rank value of 3.6s =0 2 26.5 rank value of 3.7s =0 1 28 rank value of 3.8s =0 1 29 rank value of 4.1s =0 1 30 rank value of 4.7s =0 1 31 rank value of 4.8s =0 1 32 rank value of 5.5s =0 1 33 rank value of 5.8s =0 1 34 rank value of 6.2s =0 1 35 rank value of 7s =0 1 36 rank value of 11s =0 1 37 # samples =11 26 2) Compute the Wilcoxon statistic by adding up the compliance well ranks and subtracting n/(n+1)/2. W = Ci - 1/2(n(n+1)) W = 264 3) Compute the expected value and standard deviation of W. E(W) = 1/2mn SD(W) = ((mn(N+1)/12)*(1-Sg i=1 (ti 3 - ti)/(N3 - N)))0.5 E(W) = 143 Adjustment for tie values: SD(W) = 29.073 4) Form the appropriate Z-score. Z = (W - E(W) - 0.5)/SD(W) Z = 4.145 5) Compare the observed Z-score to the upper 0.01 percentile of the normal distribution. Z = 4.145 Z0.01 = 2.326 Since Z is greater, there is significant evidence of contamination at the compliance well at the 1 percent significance level. TCE (Wil 5) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 91 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Trichloroethene NC MCL (mg/l):3 Method:Wilcoxon Rank Sum Background:MW-12 MW - 1 2 MW - 2 5 MD L 02/18/99 NP NP NT 08/16/99 NP NP NT 02/14/00 NP NP NT 08/14/00 NP NP NT 03/19/01 NP NP NT 08/27/02 NP NP NT 02/24/03 NP NP NT 08/11/03 NP NP 5 02/09/04 NP NP 5 08/16/04 NP NP 5 02/14/05 NP NP 5 09/01/05 NP NP 5 02/16/06 NP NP 5 08/30/06 NP NP 5 02/26/07 NP NP 5 08/13/07 NP NP 1 02/11/08 NP NP 1 08/25/08 NP NP 1 02/23/09 NP NP 1 08/24/09 NP NP 1 02/22/10 NP NP 1 08/30/10 NP NP 1 02/22/11 ND NP 1 08/22/11 ND NP 1 02/22/12 ND NP 1 08/29/12 ND NP 1 02/18/13 ND ND 1 08/26/13 ND 3.7 1 02/20/14 ND 1.9 1 08/28/14 ND 2.2 1 03/20/15 ND 1.3 1 08/26/15 ND ND 1 03/17/16 ND 1.7 1 1) Rank the N = 18 observations from the smallest to the largest from background wells and compliance well MW-25. n =7 m =11 N =18 Ci (MW-25) =94.0 # samples =11 7 sum of rank values (Ri) =77.0 94.0 avg rank value (Rbar) =7.0 13.4 Number of each rank value Rank Value rank value of NDs =11 2 7 rank value of 1.3s =0 1 14 rank value of 1.7s =0 1 15 rank value of 1.9s =0 1 16 rank value of 2.2s =0 1 17 TCE (Wil 25) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 92 of 96 rank value of 3.7s =0 1 18 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 # samples =11 7 2) Compute the Wilcoxon statistic by adding up the compliance well ranks and subtracting n/(n+1)/2. W = Ci - 1/2(n(n+1)) W = 66 3) Compute the expected value and standard deviation of W. E(W) = 1/2mn SD(W) = ((mn(N+1)/12)*(1-Sg i=1 (ti 3 - ti)/(N3 - N)))0.5 E(W) = 38.5 Adjustment for tie values: SD(W) = 8.725 4) Form the appropriate Z-score. Z = (W - E(W) - 0.5)/SD(W) Z = 3.095 5) Compare the observed Z-score to the upper 0.01 percentile of the normal distribution. Z = 3.095 Z0.01 = 2.326 Since Z is greater, there is significant evidence of contamination at the compliance well at the 1 percent significance level. TCE (Wil 25) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 93 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Trichlorofluoromethane NC MCL (mg/l):2000 Method:Poisson Prediction Limits Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 02/09/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 08/16/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/14/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 09/01/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 02/16/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 08/30/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 02/26/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 08/13/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/11/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/25/08 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/23/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/24/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/30/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/11 ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 08/22/11 ND ND ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 1 02/22/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP 3.8 NP 3.8 NP NP NP NP NP 1 08/29/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 02/18/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND 1 08/26/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND 1 02/20/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 08/28/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 03/20/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 08/26/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 03/17/16 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 0. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 10 Tn1 = 5 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =10 Tn1 = 5 t [9,.01] =2.821 c =0.1 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Tn2 = 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 T*k =3.0 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Trichlorofluoromethane (PPL) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 94 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Total Xylenes NC MCL (mg/l):500 Method:Poisson Prediction Limits Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NP NS NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NP NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 02/09/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 08/16/04 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 02/14/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 5 09/01/05 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 02/16/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 08/30/06 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 02/26/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 10 08/13/07 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 02/11/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 08/25/08 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 3 02/23/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 08/24/09 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 02/22/10 NP ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 08/30/10 NP 2 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 02/22/11 ND 2.5 ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 08/22/11 ND 2.1 ND ND ND ND ND ND ND NP NP NP NP NP NP NP NP NP NP NP NP NP NP 2 02/22/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 2 08/29/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 2 02/18/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND 2 08/26/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND 2 02/20/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2 08/28/14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2 03/20/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2 08/26/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 03/17/16 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 0. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 10 Tn1 = 9.5 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =10 Tn1 = 9.5 t [9,.01] =2.821 c =0.1 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Tn2 = 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 T*k =4.3 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Xylenes (PPL) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 95 of 96 Haywood County Closed Landfill, Francis Farm Haywood County, North Carolina BLE Project Number J15-1957-48 Compound:Napthalene NC MCL (mg/l):6 Method:Poisson Prediction Limits Background:MW-12 MW - 1 2 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 MD L 02/18/99 NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/99 NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/00 NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/14/00 NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 03/19/01 NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/27/02 NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/24/03 NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/11/03 NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/09/04 NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/16/04 NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/14/05 NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 09/01/05 NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/16/06 NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/30/06 NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/26/07 NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/13/07 NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/11/08 NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/25/08 NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/23/09 NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/24/09 NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/22/10 NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/30/10 NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/22/11 NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 08/22/11 NT NT NT NT NT NT NT NT NT NP NP NP NP NP NP NP NP NP NP NP NP NP NP NT 02/22/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 08/29/12 ND ND ND ND ND ND ND ND ND ND NP ND ND ND NP ND NP ND NP NP NP NP NP 1 02/18/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND ND 1 08/26/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NP ND 7.7 1 02/20/14 ND ND 1.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 8.9 1 08/28/14 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT 03/20/15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 08/26/15 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT 03/17/16 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 0. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 6 Tn1 = 3 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =6 Tn1 = 3 t [5,.01] =3.365 c =0.167 MW - 5 MW - 6 MW - 7 MW - 8 MW - 9 MW - 1 0 MW - 1 1 MW - 1 5 MW - 1 6 MW - 1 6 D MW - 1 7 MW - 1 8 MW - 1 9 MW - 1 9 D MW - 2 0 MW - 2 0 D MW - 2 1 MW - 2 2 MW - 2 3 MW - 2 3 D MW - 2 4 MW - 2 5 Tn2 = 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 T*k =4.2 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Naphthalene (PPL) 1957-48 Francis Farm GW Stats 1st 2016.xlsm Page 96 of 96