1812_DukeMarshall_Feb2016_1stSemiAnnualLeachate_DIN26340_20160418

15A NCAC 2L 
.0202 Standard
Cell 1 Cell 2
Arsenic 10 109 112
Barium 700 61 44
Boron 700 38,400 41,000
Cadmium 2 3.76 4.27
Chloride 250 mg/L 22.2 mg/L 29.2 mg/L
Chromium 10 < 5< 5
Copper 1 mg/L 0.059 mg/L 0.076 mg/L
Fluoride 2 mg/L 3.55 mg/L 3.81 mg/L
Iron 300 360 43.1
Lead 15 3.2 4.82
Manganese 50 43,000 32,500
Mercury 1< 0.05 < 0.05
Nickel 100 165 212
Nitrate as N 10 mg/L 10.6 mg/L 20.5 mg/L
pH 6.5‐8.5 4.44 4.22
Selenium 20 128 153
Silver 20 < 5< 5
Sulfate 250 mg/L 1750 mg/L 1810 mg/L
Temperature (°C)n/a °C 16.32 16.94
TDS 500 mg/L 2740 mg/L 2770 mg/L
Zinc 1 mg/L 0.348 mg/L 0.37 mg/L
Table 1
Leachate Analytical Data
Industrial Landfill No. 1 (Permit No. 1812)
Marshall Steam Station
NOTE:  15A NCAC 2L .0202 Standards are provided only for reference.  
Analytical results are for landfill leachate, which is NOT bound by state 
groundwater or surface water standards.  Landfill leachate is conveyed to the 
station's ash impoundment, which discharges via a NPDES permitted outfall.
Constituent (ug/L)
Analytical Result (ug/L)
2/28/2016

Attachment 1
Marshall Industrial Landfill No. 1
Semi-Annual Monitoring Event
Leachate Analytical Results
February 28, 2016
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16020214
Project Name:MARSHALL - GW INDUSTRIAL LANDFILL 1
Lab Contact:Peggy Kendall
Date:3/17/2016
Customer Address:8320 NC Hwy 150 East
Customer Name(s):Chuck Campbell, Tim Hunsucker, Sean De Neale
Mail Code: Marshall Steam Station
Terrell, NC 28682
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Peggy Kendall
Page 1 of 14
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016003770 MARSHALL 28-Feb-16 11:35 AM LDC CELL 1 LEACHATE
2016003771 MARSHALL 28-Feb-16 11:15 AM LDC CELL 2 LEACHATE
2016003772 MARSHALL 28-Feb-16 11:45 AM LDC FIELD BLANK
3 Total Samples
Page 2 of 14
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:3/17/2016
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 14
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020214
2016003770
Collection Date:28-Feb-16 11:35 AM
Site:CELL 1 LEACHATE
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 02/29/2016 10:06 CJELLIO51
INORGANIC IONS BY IC
Chloride 22 mg/L EPA 9056A 02/29/2016 12:59 BGN90342.5 25
Fluoride 3.6 mg/L EPA 9056A 02/29/2016 12:59 BGN90342.5 25
Nitrate 47 mg/L EPA 9056A 02/29/2016 12:59 BGN90342.5 25
Nitrate as N 11 mg-N/L EPA 9056A 02/29/2016 12:59 BGN90340.023 1
Sulfate 1800 mg/L EPA 9056A 02/29/2016 12:59 BGN903450500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7040A 03/10/2016 10:17 LSTARL10.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.061 mg/L SW 6010D 03/10/2016 10:58 MHH71310.005 1
Boron (B)38.4 mg/L SW 6010D 03/10/2016 10:58 MHH71310.5 10
Calcium (Ca)270 mg/L SW 6010D 03/10/2016 10:58 MHH71310.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 03/10/2016 10:58 MHH71310.005 1
Copper (Cu)0.059 mg/L SW 6010D 03/10/2016 10:58 MHH71310.005 1
Iron (Fe)0.360 mg/L SW 6010D 03/10/2016 10:58 MHH71310.01 1
Magnesium (Mg)126 mg/L SW 6010D 03/10/2016 10:58 MHH71310.05 10
Manganese (Mn)43.0 mg/L SW 6010D 03/10/2016 10:58 MHH71310.05 10
Nickel (Ni)0.165 mg/L SW 6010D 03/10/2016 10:58 MHH71310.005 1
Potassium (K)84.6 mg/L SW 6010D 03/10/2016 10:58 MHH7131110
Silver (Ag)< 0.005 mg/L SW 6010D 03/10/2016 10:58 MHH71310.005 1
Sodium (Na)160 mg/L SW 6010D 03/10/2016 10:58 MHH71310.5 10
Zinc (Zn)0.348 mg/L SW 6010D 03/10/2016 10:58 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)109 ug/L SW 6020B 03/16/2016 13:36 JAHERMA11
Cadmium (Cd)3.76 ug/L SW 6020B 03/16/2016 13:36 JAHERMA11
Lead (Pb)3.20 ug/L SW 6020B 03/16/2016 13:36 JAHERMA11
Selenium (Se)128 ug/L SW 6020B 03/16/2016 13:36 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 2700 mg/L SM2540C 02/29/2016 15:10 CJELLIO1251
Page 4 of 14
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020214
2016003771
Collection Date:28-Feb-16 11:15 AM
Site:CELL 2 LEACHATE
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 02/29/2016 10:06 CJELLIO51
INORGANIC IONS BY IC
Chloride 29 mg/L EPA 9056A 02/29/2016 13:16 BGN90342.5 25
Fluoride 3.8 mg/L EPA 9056A 02/29/2016 13:16 BGN90342.5 25
Nitrate 91 mg/L EPA 9056A 02/29/2016 13:16 BGN90342.5 25
Nitrate as N 21 mg-N/L EPA 9056A 02/29/2016 13:16 BGN90340.023 1
Sulfate 1800 mg/L EPA 9056A 02/29/2016 13:16 BGN903450500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7040A 03/10/2016 10:22 LSTARL10.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.044 mg/L SW 6010D 03/10/2016 11:03 MHH71310.005 1
Boron (B)41.0 mg/L SW 6010D 03/10/2016 11:03 MHH71310.5 10
Calcium (Ca)286 mg/L SW 6010D 03/10/2016 11:03 MHH71310.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 03/10/2016 11:03 MHH71310.005 1
Copper (Cu)0.076 mg/L SW 6010D 03/10/2016 11:03 MHH71310.005 1
Iron (Fe)0.043 mg/L SW 6010D 03/10/2016 11:03 MHH71310.01 1
Magnesium (Mg)118 mg/L SW 6010D 03/10/2016 11:03 MHH71310.05 10
Manganese (Mn)32.5 mg/L SW 6010D 03/10/2016 11:03 MHH71310.05 10
Nickel (Ni)0.212 mg/L SW 6010D 03/10/2016 11:03 MHH71310.005 1
Potassium (K)71.0 mg/L SW 6010D 03/10/2016 11:03 MHH7131110
Silver (Ag)< 0.005 mg/L SW 6010D 03/10/2016 11:03 MHH71310.005 1
Sodium (Na)181 mg/L SW 6010D 03/10/2016 11:03 MHH71310.5 10
Zinc (Zn)0.370 mg/L SW 6010D 03/10/2016 11:03 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)112 ug/L SW 6020B 03/16/2016 13:41 JAHERMA11
Cadmium (Cd)4.27 ug/L SW 6020B 03/16/2016 13:41 JAHERMA11
Lead (Pb)4.82 ug/L SW 6020B 03/16/2016 13:41 JAHERMA11
Selenium (Se)153 ug/L SW 6020B 03/16/2016 13:41 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 2800 mg/L SM2540C 02/29/2016 15:10 CJELLIO1251
Page 5 of 14
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020214
2016003772
Collection Date:28-Feb-16 11:45 AM
Site:FIELD BLANK
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 02/29/2016 10:06 CJELLIO51
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 9056A 02/29/2016 11:17 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 02/29/2016 11:17 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 02/29/2016 11:17 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 02/29/2016 11:17 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 02/29/2016 11:17 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7040A 03/10/2016 10:25 LSTARL10.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L SW 6010D 03/10/2016 10:54 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 03/10/2016 10:54 MHH71310.05 1
Calcium (Ca)0.012 mg/L SW 6010D 03/10/2016 10:54 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 03/10/2016 10:54 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 03/10/2016 10:54 MHH71310.005 1
Iron (Fe)< 0.01 mg/L SW 6010D 03/10/2016 10:54 MHH71310.01 1
Magnesium (Mg)< 0.005 mg/L SW 6010D 03/10/2016 10:54 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 03/10/2016 10:54 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 03/10/2016 10:54 MHH71310.005 1
Potassium (K)< 0.1 mg/L SW 6010D 03/10/2016 10:54 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 03/10/2016 10:54 MHH71310.005 1
Sodium (Na)< 0.05 mg/L SW 6010D 03/10/2016 10:54 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 03/10/2016 10:54 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 03/16/2016 13:51 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 03/16/2016 13:51 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 03/16/2016 13:51 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 03/16/2016 13:51 JAHERMA11
Page 6 of 14
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020214
Q16020546 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16020214 -- 2016003771
Alkalinity (mg/L CaCO3)0mg/L
(CaCO3)
-10
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3)10.86 87.1mg/L
(CaCO3)
-1208019.45
Page 7 of 14
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020214
Q16020535 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride -0.0009 mg/L -1-0.0009 0.1 < 1/2 RDL
Fluoride 0.0372 mg/L -10.0372 0.1 < 1/2 RDL
Nitrate 0.0179 mg/L -10.0179 0.1 < 1/2 RDL
Sulfate -0.0113 mg/L -1-0.0113 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 4.83 5 96.1mg/L -1208014.83
Fluoride 4.89 5 96.9mg/L -1208014.89
Nitrate 4.74 5 94mg/L -1208014.74
Sulfate 6.38 5 92.4mg/L -1208016.38
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 4.85 5 96.3 0.22mg/L -1208014.85
Fluoride 4.87 5 96.5 0.397mg/L -1208014.87
Nitrate 4.74 5 94.1 0.14mg/L -1208014.74
Sulfate 6.39 5 92.5 0.177mg/L -1208016.39
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 4.81 5 96.3mg/L -1208014.81
Fluoride 4.77 5 95.4mg/L -1208014.77
Nitrate 4.77 5 95.4mg/L -1208014.77
Sulfate 4.8 5 96mg/L -1208014.8
Page 8 of 14
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020214
Q16030238 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.006 ug/L -10.006 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg)1 100ug/L -1307010.969
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg)1 99.7 0.7ug/L -10.962
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg)2 98.4ug/L -1158511.97
Mercury (Hg)2 98.4ug/L -1208011.97
Page 9 of 14
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020214
Q16030189 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) 0.000299 mg/L -10.000299 0.005 < 1/2 RDL
Boron (B) 0.00124 mg/L -10.00124 0.05 < 1/2 RDL
Calcium (Ca) 0.00627 mg/L -10.00627 0.01 > 1/2 RDL
Chromium (Cr) -0.000452 mg/L -1-0.000452 0.005 < 1/2 RDL
Copper (Cu) -0.000297 mg/L -10.0005 0.005 < 1/2 RDL
Iron (Fe) 0.00224 mg/L -10.00224 0.01 < 1/2 RDL
Magnesium (Mg) -0.00394 mg/L -1-0.00394 0.005 < 1/2 RDL
Manganese (Mn) 0.000201 mg/L -10.000201 0.005 < 1/2 RDL
Nickel (Ni) 0.000089 mg/L -10.000089 0.005 < 1/2 RDL
Potassium (K) -0.00318 mg/L -1-0.00318 0.1 < 1/2 RDL
Silver (Ag) 0.000399 mg/L -10.000399 0.005 < 1/2 RDL
Sodium (Na) -0.000472 mg/L -1-0.000472 0.05 < 1/2 RDL
Zinc (Zn) 0.000337 mg/L -10.000337 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 5.03 5 101mg/L -1208015.03
Boron (B) 4.97 5 99.4mg/L -1208014.97
Calcium (Ca) 5.07 5 101mg/L -1208015.07
Chromium (Cr) 5.03 5 101mg/L -1208015.03
Copper (Cu) 4.99 5 99.4mg/L -1208014.97
Iron (Fe) 5.02 5 100mg/L -1208015.02
Magnesium (Mg) 5.1 5 102mg/L -1208015.1
Manganese (Mn) 5.05 5 101mg/L -1208015.05
Nickel (Ni) 5.12 5 102mg/L -1208015.12
Potassium (K) 5.01 5 100mg/L -1208015.01
Silver (Ag) 0.487 0.5 97.5mg/L -1208010.487
Sodium (Na) 4.96 5 99.3mg/L -1208014.96
Zinc (Zn) 5.13 5 103mg/L -1208015.13
Final QualifierDilMeasuredUnits:Parameter
LCSD # 1
RPD% Recovery LCL UCLSpike
Barium (Ba) 5.09 5 102 1.11mg/L -1208015.09
Boron (B) 5.02 5 100 0.961mg/L -1208015.02
Calcium (Ca) 5.14 5 103 1.41mg/L -1208015.14
Chromium (Cr) 5.1 5 102 1.38mg/L -1208015.1
Copper (Cu) 5.07 5 101 1.2mg/L -1208015.03
Iron (Fe) 5.09 5 102 1.31mg/L -1208015.09
Magnesium (Mg) 5.18 5 104 1.5mg/L -1208015.18
Manganese (Mn) 5.13 5 103 1.41mg/L -1208015.13
Page 10 of 14
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020214
Q16030189 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
LCSD # 1
RPD% Recovery LCL UCLSpike
Nickel (Ni) 5.2 5 104 1.57mg/L -1208015.2
Potassium (K) 5.08 5 102 1.37mg/L -1208015.08
Silver (Ag) 0.48 0.5 96 1.59mg/L -1208010.48
Sodium (Na) 5.04 5 101 1.46mg/L -1208015.04
Zinc (Zn) 5.2 5 104 1.43mg/L -1208015.2
Page 11 of 14
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020214
Q16030209 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As) -0.0009 ug/L -1-0.0009 1 < 1/2 RDL
Cadmium (Cd) 0 ug/L -10 1 < 1/2 RDL
Lead (Pb) 0.0018 ug/L -10.0018 1 < 1/2 RDL
Selenium (Se) -0.0737 ug/L -1-0.0737 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As) 48.1 50 96.2ug/L -12080148.1
Cadmium (Cd) 48.9 50 97.9ug/L -12080148.9
Lead (Pb) 48.6 50 97.2ug/L -12080148.6
Selenium (Se) 47.4 50 94.8ug/L -12080147.4
Final QualifierDilMeasuredUnits:Parameter
LCSD # 1
RPD% Recovery LCL UCLSpike
Arsenic (As) 98 100 98 1.85ug/L -12080198
Cadmium (Cd) 98.4 100 98.4 0.528ug/L -12080198.4
Lead (Pb) 97.9 100 97.9 0.728ug/L -12080197.9
Selenium (Se) 96.6 100 96.6 1.84ug/L -12080196.6
Page 12 of 14
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020214
Q16020552 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16020002 -- 2016002867
TDS 7.84mg/L -153
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 95mg/L -11090195
Page 13 of 14
Page 14 of 14

Attachment 2
Marshall Industrial Landfill No. 1
Semi-Annual Monitoring Event
Leachate Field Results
February 28, 2016
ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬/▬►0.0 0.0 ▬/▬►0.0
SS 2211.0 ▬▬►2200 2196.0 ▬/▬►2200
SS 716.1 ▬/▬►720 715.8 ▬/▬►720
SS ▬/▬►▬/▬►
B (7.00)6.96 ▬▬►7.02 7.01 ▬/▬►7.02
B (4.00)4.02 ▬▬►4.00 3.99 ▬/▬►4.00
B (10.00)10.04 ▬/▬►10.06 10.04 ▬/▬►10.06
20.32 19.94
pH Check B (7.00)▬▬►
Time:
SS (7.00)295 ▬▬►294 291 ▬/▬►295
SS (4.00)N/A ▬/▬►469 N/A ▬/▬►470
QuinHydrone 20.34 19.85
W 9.00 8.90
W 9.00 8.90
AW 8.92 ▬▬►9.00 8.87 ▬/▬►8.90
SS 55.0 ▬/▬►54.3 55.4 ▬/▬►54.3
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
FIELD SAMPLING CALIBRATION FORM
STUDY:MARSHALL STEAM STATION - INDUSTRIAL WASTE LANDFILL 1 GROUNDWATER MONITORING
DATE (s):February 28, 2016 SURFACE UNIT READER:LDC
OTHER EQUIPMENT:TURBIDIMETER NO.2 - 3260-GW Clear, slight breeze, 55 deg F
COLLECTORS:LDC SURFACE UNIT SERIAL #:S05042
ANALYZER MODEL#:MS5 66121
PROCEDURE #:HYDROLAB 3210.5 VALIDATED BY:
Calibration Date / Time 28-Feb-16 945 29-Feb-16 600
CALIBRATION BP (mmHg)747.5 CALIBRATION BP (mmHg)740.1
Parameter Calibration Results Calibration Results
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)
Instrument Zeroed Zero Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
pH
(units)
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Buffer Temp.Buffer Temp.
Buffer Temp.
ORP (mV)Calibration Accepted Calibration Pass
ORP Temp.ORP Temp.
Calibration Pass
TURB
(ntu)Calibration Accepted Calibration Accepted
DO
(mg/L)Calibration Accepted
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 745.7 (mmHg)Ending BP 745.7
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
0.00 0.00
(psi)(sec)(sec)
(gal)
(ft)=(in)@
QC By:
DATE TIME
7.33
2/28/2016 1135
PURGE METHOD
No Purge
DISCHARGERECHARGEPRESSURE
PUMP CONTROLER SETTINGS
N/ACONVERSION FACTOR
Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
N/AWELL VOLUME
FIELD CREW LDC
MONITORING WELL INFORMATION
N/A
PROCEDURE NO 3175.2DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
SITE NAME MARSHALL STEAM STATION PERMIT #18-12 SITE ID
PROJECT NAME INDUSTRIAL LANDFILL 1
SAMPLING DATE(s)28-Feb-2016
PUMP INTAKE DEPTH (ft TOC)
TOC ELEV (ft msl)
GS ELEV (ft msl)
WELL/LOCATION NAME CELL 1 LEACHATE
SCREEN LENGTH (ft)ELEV REF
WELL DEPTH (ft TOC)
WELL DIAMETER (in)MIDDLE OF WETTED SCREEN (ft toc)
SCREEN INTERVAL (ft TOC)TO
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)N/A
EQUIPMENT INFORMATION
LEVEL METER SERIAL#N/A SAMPLING EQUIPMENT
TUBING DIAMETER (in)
GRAB
WATER ELEVATION (ft msl)N/A
APPEARANCE
DETECTED ODOR None
Normal
SPECIFIC pH TURBIDITY ORP DISSOLVED HYDRASLEEVE DEPLOYED DATE TEMP
(inches)(ft TOC)(deg C)(umho/cm)(SU)(NTU)(mV-NHE)(mg/L)
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
LDC N/A
Deployed Water Column In Screen
Above Top Of HydrasleeveTop Weight
NO PURGE SAMPLE CHLORINE
(mg/l)SAMPLE COLLECTED BY
N/AN/A N/A N/A 16.32 3001 4.44 22.0 785
WELL CASING
WELL CONDITION
PROTECTIVE CASING
WELL PAD
WELL TAG
Sample preservation verified to pH
(units)< 2.0
SAMPLING NOTES
Allow system to flush for several minutes prior to sampling - watch for low level alarm during pumping.
ADDITIONAL WELL CONDITION NOTES
0.00 0.00
(psi)(sec)(sec)
(gal)
(ft)=(in)@
QC By:
SITE NAME MARSHALL STEAM STATION PERMIT #18-12 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME INDUSTRIAL LANDFILL 1 FIELD CREW LDC
SAMPLING DATE(s)28-Feb-2016 WELL/LOCATION NAME CELL 2 LEACHATE
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)
PUMP CONTROLER SETTINGS
PRESSURE RECHARGE DISCHARGE
N/A SAMPLING EQUIPMENT GRAB PURGE METHOD
TUBING DIAMETER (in)No Purge
DETECTED ODOR None CONVERSION FACTOR N/A
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)N/A Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)N/A WELL VOLUME N/A
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
LDC 2/28/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 16.94 2983 4.22 3.0
1115
766 5.53
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
Allow system to flush for several minutes prior to sampling - watch for low level alarm during pumping.
WELL DEPTH TO WATER Purge AVG *WELL EVAC SPECIFIC
WELL DEPTH WATER ELEV.Method PMP RATE VOL VOL EVAC TEMP CONDUCTANCE pH TURBIDITY ORP DODATENO.(feet-toc)(feet-toc)(feet)APPEARANCE ODOR (ml/min)(gal)(gal)(yes/no)(deg C)(umho/cm)(units)(NTU)(mV-NHE)(mg/l)
2/28/2016 CELL 1 LEACHATE 0.00 N/A N/A Normal None NP N/A N/A N/A 16.32 3001 4.4 22.0 785 7.332/28/2016 CELL 2 LEACHATE 0.00 N/A N/A Normal None NP N/A N/A N/A 16.94 2983 4.2 3.0 766 5.53
Purge Methods
LF = Low FlowLF(M) = Low Flow (Mod.)C = Connventional
NP = No Purge
EOP = Equip. Only PurgeLO = Level Only
* = Applicable to LF & LF(M) Purging Only
MARSHALL STEAM STATION
INDUSTRIAL LANDFILL 1
GROUNDWATER MONITORING FIELD DATA
PERMIT #18-12