1809_DukeMarshallFGD_March2016_1stSemiAnnual_DIN26339_20160601

Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Marshall Steam Station FGD Residue Landfill Phase 1, Cell 1 Permit No. 1809
March 2016 Sampling EventReport VERIFICATION

Marshall Steam Station
Semiannual Groundwater
Monitoring Report
FGD Residue Landfill, Phase 1, Cell 1
Permit No. 1809
March 2016 Sampling Event
June 10, 2016

Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Marshall Steam Station FGD Residue Landfill Phase 1, Cell 1 Permit No. 1809
March 2016 Sampling EventContents

ii
Contents
Page
Report Verification ......................................................................................................................... i
Contents ........................................................................................................................................ ii
Section 1 – Background ................................................................................................................ 1
Section 2 – Methods ..................................................................................................................... 3
2.1 Sampling and Analysis Methods .................................................................................... 3
2.2 Statement of Work .......................................................................................................... 3
Section 3 - Results ........................................................................................................................ 4
3.1 Site Groundwater Flow ................................................................................................... 4
3.2 Analytical Results ........................................................................................................... 4

FIGURES
1. Site Location Map
2. Sample Locations
3. Generalized Groundwater Surface Contours
TABLES
1. Well Construction Information
2. Groundwater Flow Velocities
3. Field Data Parameters
4. Field and Analytical Results
5. Field and Analytical Results that Equal or Exceed NCAC 2L Groundwater Quality
Standards
6. Leachate Field and Analytical Results
APPENDICES
A. Field Sampling Forms
B. Laboratory Report and Chain-of-Custody Forms
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Marshall Steam Station FGD Residue Landfill Phase 1, Cell 1 Permit No. 1809
March 2016 Sampling EventSection 1 – BACKGROUND

1
Section 1 – Background
Marshall Steam Station (Marshall) is owned and operated by Duke Energy Carolinas, LLC
(Duke Energy). The Marshall plant has a generating capacity of 2090 megawatts of electric
power by the combustion of coal. The plant is located in Catawba County, North Carolina, on
Lake Norman and is in the Piedmont physiographic region.
The flue gas desulfurization (FGD) landfill is located northwest of the power plant and west of
the Marshall ash basin as shown on Figure 1. In general, the topography of the landfill site
slopes from the west-northwest to the east-southeast towards the Marshall ash basin.
The landfill is permitted to receive FGD residue (gypsum), clarifier sludge, fly ash, bottom ash,
construction and demolition (C&D) waste, asbestos waste, mill rejects (pyrites), waste limestone
material, land clearing and inert debris, boiler slag, ball mill rejects, sand blast material, and coal
waste. The clarifier sludge is generated from the FGD wastewater treatment system. Only Cell 1
of the landfill has been constructed and is in operation. Cell 1 is approximately 18 acres in area.
The landfill is constructed with an engineered liner system. Contact stormwater and leachate
are collected in the lined Cell 1 and then piped to the ash basin. The landfill began receiving
waste in 2007.
The subsurface conditions at the site consist of residual soils and partially weathered rock which
have been formed by the in-place weathering of the parent rock. These materials are underlain
by bedrock. The site hydrogeological description and information on the monitoring wells can be
found in the Groundwater Sampling and Analysis Plan.1
The monitoring system for the Marshall FGD Landfill, Phase 1, Cell 1 consists the following:
Monitoring Wells: MS-8
MS-9
MS-10
MS-11
MS-12
MS-13
MS-14
MS-15
MS-16

Surface Water Sample: SW-1

Leachate Sample: C-1

The locations of the wells, surface water sample location, and the leachate sampling location
are shown on Figure 2. Table 1 presents well construction information for the landfill monitoring
wells. The leachate sampling requirement was added in the revised Permit to Operate for the
1 Marshall Steam Station Flue Gas Desulfurization (FGD) Residue Landfill Phase 1, Cell 1 Permit No.
1809 Groundwater Sampling and Analysis Plan. Dated August 19, 2011.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Marshall Steam Station FGD Residue Landfill Phase 1, Cell 1 Permit No. 1809
March 2016 Sampling EventSection 1 – BACKGROUND

2
Marshall FGD Landfill2 in September 2011. Due to landfill operations, the historical leachate
collection area is no longer accessible as of the September 2014 sampling event. A new
collection point for leachate sample C-1 has been established northwest of the landfill at the
outlet of the leachate discharge pipe.
Well MS-8 is located north of the landfill and, according to the Groundwater Sampling and
Analysis Plan, is the background monitoring well for the site.
Surface water sample location SW-1 is a groundwater seep and the analytical results are
compared to Title 15A, North Carolina Administrative Code (NCAC), Subchapter 2L Standards
(2L Standards) for Class GA groundwater.
2 Attachment 3 – Conditions of Operating Permit, Part I: General Facility Conditions, Monitoring and
Reporting Requirements, #13.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Marshall Steam Station FGD Residue Landfill Phase 1, Cell 1 Permit No. 1809
March 2016 Sampling EventSection 2 – METHODS

3
Section 2 – Methods
2.1 Sampling and Analysis Methods
Groundwater sampling and documentation of sampling activities were performed by Duke
Energy personnel (Field Certification #5193) according to the North Carolina Solid Waste
Management Guidelines. Copies of the field sampling forms are included in Appendix A. The
parameters and constituents reported were selected by Duke Energy and the NCDEQ Division
of Solid Waste and were analyzed by Duke Energy Analytical Laboratory (North Carolina
Laboratory Certification #248).
The samples were analyzed for the following constituents and/or parameters:
 Barium, boron, copper, iron, manganese, nickel, silver, and zinc using Solid Waste (SW)
Method 6010D
 Arsenic, cadmium, chromium, lead, and selenium using SW Method 6020B
 Mercury using U.S. Environmental Protection Agency (EPA) Method 7470A
 Total dissolved solids using Standard Method (SM) 2540C
 Chloride, fluoride, nitrate as nitrogen, and sulfate using EPA Method 9056A
2.2 Statement of Work
HDR completed the following tasks:
 Received field sampling information provided by Duke Energy (performed by Duke
Energy personnel) for monitoring wells MS-8, MS-9, MS-10, MS-11, MS-12, MS-13,
MS-14, MS-15, and MS-16, surface water sampling location SW-1, and leachate
sampling location C1. The samples were collected on March 21, 2016, and HDR
received the data on April 6, 2016. The field sampling forms are included in Appendix A.
 Reviewed the laboratory analytical results for samples. The EDD provided by Duke
Energy was adapted to conform to the format requirements of the North Carolina
Department of Environmental Quality (NCDEQ) EDD template. HDR added an italicized
J’ data qualifier (J’) to indicate a concentration that is equal to or greater than the
laboratory’s method reporting limit (MRL) but less than the Solid Waste Section Limit3
(SWSL). A copy of the original EDD is retained in HDR’s files.
 Developed a generalized groundwater surface contour map using map data and
groundwater elevation data supplied by Duke Energy. Calculated groundwater flow
velocities based on groundwater surface contours.
 Prepared and submitted this Semiannual Groundwater Monitoring Report to Duke
Energy.
3 The Solid Waste Section Limit (SWSL) is defined by NCDEQ as the lowest amount of analyte in a
sample that can be quantitatively determined with suitable precision and accuracy. The SWSL is the
concentration below which reported results must be qualified as estimated. NCDEQ Division of Waste
Management Memorandum dated February 23, 2007.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Marshall Steam Station FGD Residue Landfill Phase 1, Cell 1 Permit No. 1809
March 2016 Sampling EventSection 3 - RESULTS

4
Section 3 - Results
3.1 Site Groundwater Flow
Generalized groundwater surface contours for the site are shown on Figure 3. These contours
were developed using groundwater elevations measured in the wells on the date of sampling.
Calculated groundwater flow velocities are presented in Table 2.
Groundwater flow in the area of the landfill is generally from areas of higher topography located
to the north and west of the landfill, toward the Marshall ash basin, located to the east of the
landfill. To a lesser extent, some component of groundwater flow is expected to be toward
surface water sample location SW-1.
3.2 Analytical Results
A summary of the field data is presented in Table 3.
The field and analytical results of the groundwater samples collected at the monitoring wells are
summarized in Table 4. The analysis results for these locations are compared to the 2L
Standards. Concentrations with values that attain or exceed the 2L Standards are noted on
Table 4 by bold font. A summary of the analytical results that attain or exceed the 2L Standards
and a preliminary analysis of the cause and significance of the exceedances is presented in
Table 5.
The field and analytical results for the leachate sampling are summarized in Table 6.
Analytical results with values that equal or are greater than the SWSLs are noted on Tables 4
and 6 by gray cells.
Selected samples were diluted as is normal laboratory practice to bring samples to the
calibrated range of the analysis. Specifics regarding the samples that were diluted, including the
dilution amount, are reported in the EDD.
The laboratory report and chain-of-custody forms are located in Appendix B.
HDR previously prepared and submitted an assessment to NCDEQ on historical exceedances
of 2L Standards at this landfill (Groundwater Assessment Marshall Steam Station FGD Landfill,
Phase 1, Cell 1, July 12, 2012). The report assessed 2L Standard exceedances chromium at
MS-15; iron at MS-8, MS-10, MS-11, MS-16, and SW-1; manganese at MS-16; and pH at MS-8,
MS-10, MS-11, MS-12, MS-13, MS-14, MS-15, MS-16, and SW-1. The assessment report
concluded for the period of analytical results reviewed, that the exceedances of the 2L
Standards at the site were naturally occurring and are not related to impacts from the landfill.

FIGURES

TABLES
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(f
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Page 1 of 1
Ta
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e

3

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D
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P
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I
D
WE
L
L
DE
P
T
H
(f
e
e
t
)
DE
P
T
H

T
O
WA
T
E
R
(fe
e
t
)
WA
T
E
R
EL
E
V
.
(f
e
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t
)
pH (SU)TURBIDITY (NTU)ORP (mV-NHE)
AP
P
E
A
R
A
N
C
E
DO (mg/L)
OD
O
R
PU
R
G
E
ME
T
H
O
D

PU
M
P

RA
T
E
(m
L
/
m
i
n
)
WE
L
L
VO
L
U
M
E
(g
a
l
l
o
n
s
)
EV
A
C
VO
L
U
M
E
(g
a
l
l
o
n
s
)
EV
A
C
(y
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s
/
n
o
)
TE
M
P
(d
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g

C
)
SP
E
C
I
F
I
C
CO
N
D
U
C
T
A
N
C
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(µ
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m
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Page 1 of 1
Ta
b
l
e

4

-

G
r
o
u
n
d
w
a
t
e
r

F
i
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l
d

a
n
d

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
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s
Du
k
e

E
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r
g
y

C
a
r
o
l
i
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a
s
,

L
L
C
/
M
a
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s
h
a
l
l

S
t
e
a
m

S
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R
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L
a
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f
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Ph
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1
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µ
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8

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l
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v
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l

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41
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g
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(
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No
t
e
s
:

1
.

C
o
n
c
e
n
t
r
a
t
i
o
n
s

p
r
e
s
e
n
t
e
d

i
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m
i
c
r
o
g
r
a
m
s

p
e
r

l
i
t
e
r

(
µ
g
/
L
)
.

2
.

S
U

i
n
d
i
c
a
t
e
s

S
t
a
n
d
a
r
d

U
n
i
t
s
.

3
.

µ
Լ /c
m

i
n
d
i
c
a
t
e
s

m
i
c
r
o
m
h
o
s

p
e
r

c
e
n
t
i
m
e
t
e
r
.

4
.

S
W
S

I
D

i
s

t
h
e

S
o
l
i
d

W
a
s
t
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S
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c
t
i
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n

I
d
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n
t
i
f
i
c
a
t
i
o
n

N
u
m
b
e
r
.

5
.

M
D
L

i
s

t
h
e

l
a
b
o
r
a
t
o
r
y

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.

T
h
e

M
D
L

v
a
l
u
e
s

p
r
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s
e
n
t
e
d

a
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f
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s
a
m
p
l
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s

n
o
t

d
i
l
u
t
e
d

b
y

t
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e

l
a
b
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a
t
o
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d
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r
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g

a
n
a
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y
s
i
s
.

6
.

S
W
S
L

i
s

t
h
e

S
o
l
i
d

W
a
s
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e

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c
t
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m
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t
.

N
C
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d
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f
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a
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l
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a
m
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o
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a
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n

a

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a
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p
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t
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c
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q
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w
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s
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a
b
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p
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c
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s
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n

a
n
d

a
c
c
u
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a
c
y
.

7
.

1
5
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N
C
A
C

2
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S
t
a
n
d
a
r
d

r
e
f
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s

t
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l
a
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s

G
A

S
t
a
n
d
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s

a
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f
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1
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N
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A
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0
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L

.
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G
r
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d
w
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S
t
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,

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a
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1
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8
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L

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m
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m

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4
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,

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u
b
p
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G
,

§
1
4
1
.
6
2
.

9
.

*

C
o
n
c
e
n
t
r
a
t
i
o
n

l
i
s
t
e
d

i
s

a

s
e
c
o
n
d
a
r
y

m
a
x
i
m
u
m

c
o
n
t
a
m
i
n
a
n
t

l
e
v
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l

(
S
M
C
L
)
.

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M
C
L
s

a
r
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e
s
t
a
b
l
i
s
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d

b
y

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P
A

i
n

t
h
e

N
a
t
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o
n
a
l

S
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c
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d
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D
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k
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W
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l
a
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f
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d

i
n

4
0

C
F
R

§
1
4
3
.
3
.
10
.

N
E

i
n
d
i
c
a
t
e
s

n
o
t

e
s
t
a
b
l
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s
h
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d
.

N
A

i
n
d
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c
a
t
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s

n
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t

a
n
a
l
y
z
e
d
.

N
S

i
n
d
i
c
a
t
e
s

a

s
a
m
p
l
e

w
a
s

n
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t

c
o
l
l
e
c
t
e
d
.

B
l
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

t
h
a
t

t
h
e
r
e

i
s

n
o

i
n
f
o
r
m
a
t
i
o
n

r
e
l
e
v
a
n
t

t
o

t
h
e

r
e
s
p
e
c
t
i
v
e

r
o
w
.
11
.

G
r
a
y
e
d

v
a
l
u
e
s

i
n
d
i
c
a
t
e

v
a
l
u
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s

t
h
a
t

e
q
u
a
l

o
r

a
r
e

g
r
e
a
t
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r

t
h
a
n

t
h
e

S
W
S
L
.
12
.

B
o
l
d

v
a
l
u
e
s

i
n
d
i
c
a
t
e

v
a
l
u
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s

t
h
a
t

a
t
t
a
i
n

o
r

e
x
c
e
e
d

t
h
e

1
5
A

N
C
A
C

2
L

S
t
a
n
d
a
r
d
.
13
.

Q
u
a
l
i
f
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e
r
s

i
n

n
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n
-
i
t
a
l
i
c
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d

t
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t

a
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l
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b
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d
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q
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.

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s

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.

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Page 2 of 4
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1

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5
Page 1 of 1
Ta
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10
No
t
e
s
:
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.

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o
n
c
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n
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r
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t
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s

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m
s

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t
e
r

(
µ
g
/
L
)
.
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.

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U

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n
d
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c
a
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e
s

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n
d
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r
d

U
n
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t
s
.
3
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µ
Լ /c
m

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n
d
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c
a
t
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s

m
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c
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m
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s

p
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n
t
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m
e
t
e
r
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.

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t
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t
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n

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m
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r
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5
.

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l
a
b
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t
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y

m
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d

d
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t
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n

l
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m
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t
.

6
.

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t
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l
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d

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a
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n

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i
m
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t
.

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d
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f
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s
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m
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t

c
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n

b
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n

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.
8
.

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.

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r
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Page 1 of 1

A
Appendix A
Field Sampling Forms

ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬▬►0.0 0.0 ▬/▬►0.0
SS 226.3 ▬▬►227 220.4 ▬/▬►227
SS 72.7 ▬/▬►75 73.1 ▬/▬►75
SS ▬/▬►▬/▬►
B (7.00)6.90 ▬▬►7.02 7.08 ▬/▬►7.02
B (4.00)3.98 ▬▬►4.00 4.07 ▬/▬►4.00
B (10.00)10.23 ▬/▬►10.04 10.26 ▬/▬►10.06
20.72 20.28
pH Check B (7.00)▬▬►
Time:
SS (7.00)439 ▬▬►439 437 ▬/▬►440
SS (4.00)N/A ▬/▬►469 N/A ▬/▬►470
Zobell's 20.67 20.27
W 8.80 8.90
W 8.90 9.00
AW 8.80 ▬▬►8.85 8.99 ▬/▬►8.95
SS 55.8 ▬/▬►56.0 54.8 ▬/▬►56.0
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 742.4 (mmHg)Ending BP 745.1
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
ORP Temp.ORP Temp.
Calibration Pass
TURB
(ntu)Calibration Accepted Calibration Accepted
DO
(mg/L)Calibration Accepted
Buffer Temp.
ORP
(mV)
Calibration Accepted Calibration Pass
pH
(units)
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Buffer Temp.Buffer Temp.
Parameter Calibration Results Calibration Results
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)
Instrument Zeroed Zero Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Calibration Date / Time 21-Mar-16 515 22-Mar-16 510
CALIBRATION BP (mmHg)741.7 CALIBRATION BP (mmHg)748.3
COLLECTORS:LDC, PSP, HET SURFACE UNIT SERIAL #:0662
ANALYZER MODEL#:HL4 400437
PROCEDURE #:HYDROLAB 3210.5 VALIDATED BY:
FIELD SAMPLING CALIBRATION FORM
STUDY:MARSHALL STEAM STATION - FGD GROUNDWATER MONITORING
DATE (s):March 21, 2016 SURFACE UNIT READER:LDC
OTHER EQUIPMENT:TURBIDIMETER NO.2 - 3260-GW Clear, breezy, 35 to 50 deg F
ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬▬►0.0 0.0 ▬/▬►0.0
SS 224.3 ▬▬►227 221.9 ▬/▬►227
SS 74.4 ▬/▬►75 77.1 ▬/▬►75
SS ▬/▬►▬/▬►
B (7.00)7.10 ▬▬►7.02 7.07 ▬/▬►7.02
B (4.00)3.92 ▬▬►4.00 4.05 ▬/▬►4.00
B (10.00)10.06 ▬/▬►10.04 10.11 ▬/▬►10.06
20.85 20.37
pH Check B (7.00)▬▬►
Time:
SS (7.00)440 ▬▬►439 437 ▬/▬►440
SS (4.00)N/A ▬/▬►469 N/A ▬/▬►469
Zobell's 20.77 20.33
W 8.80 8.90
W 8.90 9.00
AW 8.81 ▬▬►8.85 9.06 ▬/▬►8.95
SS 53.4 ▬/▬►53.5 52.9 ▬/▬►53.5
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 742.4 (mmHg)Ending BP 745.1
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
ORP Temp.ORP Temp.
Calibration Pass
TURB
(ntu)Calibration Accepted Calibration Accepted
DO
(mg/L)Calibration Accepted
Buffer Temp.
ORP
(mV)
Calibration Accepted Calibration Pass
pH
(units)
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Buffer Temp.Buffer Temp.
Parameter Calibration Results Calibration Results
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)
Instrument Zeroed Zero Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Calibration Date / Time 21-Mar-16 455 22-Mar-16 455
CALIBRATION BP (mmHg)741.7 CALIBRATION BP (mmHg)748.3
COLLECTORS:LDC, PSP, HET SURFACE UNIT SERIAL #:0722
ANALYZER MODEL#:HL4 400440
PROCEDURE #:HYDROLAB 3210.5 VALIDATED BY:
FIELD SAMPLING CALIBRATION FORM
STUDY:MARSHALL STEAM STATION - FGD GROUNDWATER MONITORING
DATE (s):March 21, 2016 SURFACE UNIT READER:PSP
OTHER EQUIPMENT:TURBIDIMETER NO.1 - 3260-GW Clear, breezy, 35 to 50 deg F
41.58 51.58
35 (psi)15 (sec)(sec)
(gal)
0.97 (gal)
@
QC By:Sample preservation verified to pH
(units)< 2.0
SAMPLING NOTES
Tag getting hard to read.
ADDITIONAL WELL CONDITION NOTESWELL CONDITION
PROTECTIVE CASING
WELL PAD
WELL TAG
Good Condition
Good Condition
Good Condition
Damaged / Illegible
WELL CASING
LDC N/A
TOTAL PURGE
VOLUME
3.50
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY
0.50 NO 13.49 40 5.84 11.6 372 7.00
0.580.75 48.02 NO
0.75 48.78 NO 13.78 41 5.86 0.46
0.50 NO 13.50 41 5.86 14.8 368 6.55
41 5.87 40.4
(recalculates on
current water
level)(deg C)(umho/cm)(SU)(NTU)(mV-NHE)(mg/L)
21.0 357 6.22 0.67
SAMPLING EQUIPMENT
TUBING DIAMETER (in)1/2 OD
QED T1200
PURGE COMPLETE TEMP SPECIFIC pH TURBIDITY
WATER ELEVATION (ft msl)826.73
APPEARANCE
DETECTED ODOR None
Normal
WATER LEVEL
AFTER PURGE *
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88
WELL DEPTH (ft TOC)
WELL DIAMETER (in)MIDDLE OF WETTED SCREEN (ft toc)
WELL VOL
SCREEN INTERVAL (ft TOC)TO
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)45.61 WATER COLUMN (ft)5.97
EQUIPMENT INFORMATION
LEVEL METER SERIAL#26054
50.60PUMP INTAKE DEPTH (ft TOC)51.58
TOC ELEV (ft msl)
GS ELEV (ft msl)
872.34
869.35
WELL/LOCATION NAME MS-8
FIELD CREW LDC, PSP, HET
MONITORING WELL INFORMATION
2
N/A
PROCEDURE NO 3175.3DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID
PROJECT NAME FGD LANDFILL GROUNDWATER
SAMPLING DATE(s)21-Mar-2016
48.60
PURGE METHOD
Conventional
DISCHARGERECHARGEPRESSURE 5
PUMP CONTROLLER SETTINGS
0.1631CONVERSION FACTOR
Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
0.97WELL VOLUME
(gal)
ORP
(ft)(YES/NO)
1.00 47.48 NO 14.84 43 5.88
14.47
VOLUME EVACUATION COND.
3/21/2016 0825
DATE TIME
DISSOLVED
OXYGEN
31.1 364 6.29
5.91357
43.00 53.00
25 (psi)8 (sec)(sec)
(gal)
@
QC By:
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)21-Mar-2016 WELL/LOCATION NAME MS-9
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)868.04 MIDDLE OF WETTED SCREEN (ft toc)48.00
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)53.00 GS ELEV (ft msl)865.36 PUMP INTAKE DEPTH (ft TOC)52.00
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 7
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)42.58 WATER COLUMN (ft)10.42 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)825.46 WELL VOLUME 1.70
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
8:50 44.21 520 15.45 91 6.38 4.2 302 7.36 N/A
8:45 44.21 520 15.38 96 6.44 3.7 285 6.72
N/A
9:00 44.21 520 15.46 90 6.45 4.0 298 7.92 N/A
8:55 44.21 520 15.44 95 6.48 3.7 300 7.85
N/A
9:10 44.21 520 15.45 78 6.31 4.0 304 8.03 N/A
9:05 44.21 520 15.39 80 6.37 4.1 302 8.03
N/A9:15 44.21 520 15.44 80 6.38 3.8 303 8.04
DRAW-DOWN 1.63 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.50 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 4.65 (gal)LDC 3/21/2016 0920 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
13.34 23.34
10 (psi)5 (sec)(sec)
(gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE VOLUME 1.75 (gal)LDC 3/21/2016 1000 NA
DRAW-DOWN 0.39 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.25 (gal)SAMPLE COLLECTED BY DATE TIME
N/A9:55 17.18 280 14.26 19 4.89 19.6 445 6.41
N/A
9:50 17.18 280 14.34 19 4.88 19.3 442 6.27 N/A
9:45 17.18 280 14.33 19 4.88 21.9 438 6.33
N/A
9:40 17.18 280 14.39 18 4.87 13.4 432 6.19 N/A
9:35 17.18 280 14.51 20 4.72 5.3 425 6.16
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)16.79 WATER COLUMN (ft)6.55 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)834.50 WELL VOLUME 1.07
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)851.29 MIDDLE OF WETTED SCREEN (ft toc)20.07
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)23.34 GS ELEV (ft msl)848.29 PUMP INTAKE DEPTH (ft TOC)22.30
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)21-Mar-2016 WELL/LOCATION NAME MS-10
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
32.72 42.72
20 (psi)10 (sec)(sec)
(gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE VOLUME 2.85 (gal)PSP /HET 3/21/2016 0815 NA
DRAW-DOWN 0.76 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 1.50 (gal)SAMPLE COLLECTED BY DATE TIME
N/A
8:10 33.62 336 13.69 54 5.07 3.7 417 7.86 N/A
8:05 33.62 336 13.72 56 5.04 4.3 413 7.86
N/A
8:00 33.62 336 13.73 57 5.02 5.8 409 7.88 N/A
7:55 33.62 336 13.65 62 4.98 5.1 403 7.89
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)32.86 WATER COLUMN (ft)9.86 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)826.92 WELL VOLUME 1.61
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
28650 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)859.78 MIDDLE OF WETTED SCREEN (ft toc)37.79
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)42.72 GS ELEV (ft msl)856.87 PUMP INTAKE DEPTH (ft TOC)41.70
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)21-Mar-2016 WELL/LOCATION NAME MS-11
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
21.09 31.09
15 (psi)10 (sec)(sec)
(gal)
1.52 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
4.75 PSP / HET 3/21/2016 0855 N/A
1.50 NO 14.19 26 4.83 6.6 512 8.11
1.50 NO 14.21 26 4.83 9.0 508 8.16
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.75 NO 14.15 26 4.83 19.5 495
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
8.29
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)21.80 WATER COLUMN (ft)9.29 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)813.86 WELL VOLUME 1.52
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
28650 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)835.66 MIDDLE OF WETTED SCREEN (ft toc)26.45
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)31.09 GS ELEV (ft msl)832.70 PUMP INTAKE DEPTH (ft TOC)30.10
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)21-Mar-2016 WELL/LOCATION NAME MS-12
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
31.52 41.52
23 (psi)10 (sec)(sec)
(gal)
2.16 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
6.75 PSP / HET 3/21/2016 1005 N/A
2.25 NO 13.90 67 5.29 2.8 427 5.10
2.25 NO 13.88 68 5.31 3.1 414 5.20
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
2.25 NO 13.93 68 5.35 3.2 369
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
5.32
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)28.30 WATER COLUMN (ft)13.22 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)813.60 WELL VOLUME 2.16
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
28650 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)841.90 MIDDLE OF WETTED SCREEN (ft toc)36.52
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)41.52 GS ELEV (ft msl)839.19 PUMP INTAKE DEPTH (ft TOC)40.50
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)21-Mar-2016 WELL/LOCATION NAME MS-13
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
34.38 44.38
25 (psi)10 (sec)(sec)
(gal)
1.41 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition Could not inspect pad due to amount of dirt covering.
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
4.50 LDC 3/21/2016 1200 N/A
1.50 NO 14.68 55 5.86 5.6 355 7.09
1.50 NO 14.56 55 5.87 4.2 370 7.15
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.50 NO 14.62 56 5.90 4.8 379
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
7.10
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)35.71 WATER COLUMN (ft)8.67 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)808.36 WELL VOLUME 1.41
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)844.07 MIDDLE OF WETTED SCREEN (ft toc)40.05
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)44.38 GS ELEV (ft msl)841.27 PUMP INTAKE DEPTH (ft TOC)43.40
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)21-Mar-2016 WELL/LOCATION NAME MS-14
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
53.08 63.08
30 (psi)12 (sec)(sec)
(gal)
1.82 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
9.00 LDC 3/21/2016 1110 N/A
1.50 NO 15.51 135 6.51 3.3 377 7.01
1.50 NO 15.47 138 6.57 3.0 373 6.99
2.00 55.20 NO 15.51 143 6.74 3.6 363 6.96 1.29
2.00 NO 15.59 140 7.41 3.9 345 7.09
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
2.00 NO 15.60 169 6.93 3.6 367
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
7.20
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)51.94 WATER COLUMN (ft)11.14 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)809.53 WELL VOLUME 1.82
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 8
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)861.47 MIDDLE OF WETTED SCREEN (ft toc)58.08
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)63.08 GS ELEV (ft msl)858.42 PUMP INTAKE DEPTH (ft TOC)62.10
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)21-Mar-2016 WELL/LOCATION NAME MS-15
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
27.46 37.46
18 (psi)10 (sec)(sec)
(gal)
2.15 (gal)
@
QC By:
SAMPLING NOTES
After 1st well volume, water level drops below top of pump and well considered evacuated.
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
6.00 PSP / HET 3/21/2016 1120 N/A
0.50 YES 15.77 112 6.08 40.1 421 8.04
0.75 BELOW PUMP NO 15.68 114 6.09 73.1 425 7.38
0.94
1.00 33.31 NO 15.82 119 5.94 70.2 437 6.04 0.68
1.50 31.70 NO 15.86 122 5.92 30.7 434 5.61
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
2.25 28.90 NO 15.67 114 6.02 5.5 420
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
6.52 1.40
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)24.27 WATER COLUMN (ft)13.19 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)812.71 WELL VOLUME 2.15
Well evacuated @1115 hrs on 3/21/16 PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
28650 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)836.98 MIDDLE OF WETTED SCREEN (ft toc)32.46
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)37.46 GS ELEV (ft msl)834.25 PUMP INTAKE DEPTH (ft TOC)36.50
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)21-Mar-2016 WELL/LOCATION NAME MS-16
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
N/A
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SAMPLING NOTES
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
0920
348 6.68
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 9.61 35 5.33 10.5
TIME
PSP / HET 3/21/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)N/A Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME N/A
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)N/A
SCREEN LENGTH (ft)N/A ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)N/A GS ELEV (ft msl)822.26 PUMP INTAKE DEPTH (ft TOC)N/A
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)21-Mar-2016 WELL/LOCATION NAME SW-1
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
N/A
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.3
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP, HET
SAMPLING DATE(s)21-Mar-2016 WELL/LOCATION NAME C1-LEACHATE
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)N/A
SCREEN LENGTH (ft)N/A ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)N/A GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
N/A
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)N/A Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
PSP / HET 3/21/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 15.32 4326 4.57 19.1
1020
482 9.15
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
Sample untreated leachate from leachate piping at SE corner of landfill
PERMIT #
MS-8 MS-9 MS-10 MS-11 MS-12 MS-13 MS-14 MS-15 MS-16 SW-1
YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES N/A
YES YES YES YES YES YES YES YES YES N/A
YES YES YES YES YES YES YES YES YES N/A
YES YES YES YES YES YES SEE NOTE YES YES N/A
YES YES YES YES YES YES YES YES YES N/A
YES YES YES YES YES YES YES YES YES N/A
N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
YES YES YES YES YES YES YES YES N/A
SEE NOTE
NORTH CAROLINA GROUNDWATER SAMPLING SITE CHECKLIST
LOCATION / SITE MARSHALL STEAM STATION - FGD LANDFILL GROUNDWATER MONITORING 18-09 SAMPLE DATE March 21, 2016
SITE CONTACT Scott La Sala, Christopher Randazzo FIELD CREW LDC, PSP, HET
WEATHER Clear, breezy, 35 to 50 deg F
WELL LOCK CONDITION
PAGE 1 OF 1
ACCESS TO WELLS
Access cleared into well
Access cleared around well
Tall grass or weeds - needs mowing
Road washing out / muddy / needs grading
Fallen tree blocking access
WELL SECURITY
Well found locked
Well found unlocked
Undermined / washing out
Lock in good condition
Lock rusted, difficult to open / needs replacing
Replaced damaged lock
WELL CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
CONCRETE PADS
Pad in good condition
Minor cracks
Major cracks / broken / repair required
Replaced damaged well cap
Fire ants around concrete pad
WELL PROTECTIVE CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
Broken hinge on protective lid
Wasp nest inside protective casing
Ants inside protective casing
WELL CAPS
Well cap in good conditon
Damaged / needs replacement
Lacks required information - Completion date
FLUSH MOUNT WELLS
Vault in good condition
Water inside vault
Vault bolt holes broken or stripped
Bolts stripped
Vault lid cracked or broken
WELL ID TAGS
Well tag in good condition
Well tag missing
Well tag damaged / illegible
Lacks required information - Driller Reg #
Lacks required information - Total well depth
Lacks required information - Depth to screen
Lacks required information - Non potable tag
NOTE:MS-8 tag becoming difficult to read. MS-14 concrete pad could not be inspected due to dirt build up around well protective casing.
WELL DEPTH TO WATER Purge AVG *WELL EVAC SPECIFIC
WELL DEPTH WATER ELEV.Method PMP RATE VOL VOL EVAC TEMP CONDUCTANCE pH TURBIDITY ORP DODATENO.(feet-toc)(feet-toc)(feet)APPEARANCE ODOR (ml/min)(gal)(gal)(yes/no)(deg C)(umho/cm)(units)(NTU)(mV-NHE)(mg/l)
3/21/2016 MS-8 51.58 45.61 826.73 Normal None C N/A 0.97 3.50 NO 13.49 40 5.8 11.6 372 7.00
3/21/2016 MS-9 53.00 42.58 825.46 Normal None LF 520 1.70 4.65 N/A 15.44 80 6.4 3.8 303 8.04
3/21/2016 MS-10 23.34 16.79 834.50 Normal None LF 280 1.07 1.75 N/A 14.26 19 4.9 19.6 445 6.41
3/21/2016 MS-11 42.72 32.86 826.92 Normal None LF 336 1.61 2.85 N/A 13.69 54 5.1 3.7 417 7.86
3/21/2016 MS-12 31.09 21.80 813.86 Normal None C N/A 1.52 4.75 NO 14.19 26 4.8 6.6 512 8.11
3/21/2016 MS-13 41.52 28.30 813.60 Normal None C N/A 2.16 6.75 NO 13.90 67 5.3 2.8 427 5.10
3/21/2016 MS-14 44.38 35.71 808.36 Normal None C N/A 1.41 4.50 NO 14.68 55 5.9 5.6 355 7.09
3/21/2016 MS-15 63.08 51.94 809.53 Normal None C N/A 1.82 9.00 NO 15.51 135 6.5 3.3 377 7.01
3/21/2016 MS-16 37.46 24.27 812.71 Normal None C N/A 2.15 6.00 YES 15.77 112 6.1 40.1 421 8.04
3/21/2016 SW-1 N/A N/A N/A Normal None NP N/A N/A N/A N/A 9.61 35 5.3 10.5 348 6.68
3/21/2016 C1-LEACHATE N/A N/A N/A Normal None NP N/A N/A N/A N/A 15.32 4326 4.6 19.1 482 9.15
Purge Methods
LF = Low Flow
LF(M) = Low Flow (Mod.)
C = Connventional
NP = No Purge
EOP = Equip. Only Purge
LO = Level Only
* = Applicable to LF & LF(M) Purging Only
MARSHALL STEAM STATION
FGD LANDFILL GROUNDWATER
GROUNDWATER MONITORING FIELD DATA
PERMIT #18-09

B
Appendix B
Laboratory Report and
Chain-of-Custody Forms

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16020402
Project Name:MARSHALL - GW FGD LANDFILL
Lab Contact:Peggy Kendall
Date:4/1/2016
Customer Address:8320 NC Hwy 150 East
Customer Name(s):Chuck Campbell, Ed Sullivan, Tim Hunsucker
Mail Code: Marshall Steam Station
Terrell, NC 28682
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Peggy Kendall
Page 1 of 26
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016004528 MARSHALL 21-Mar-16 8:25 AM LDC MS-8
2016004529 MARSHALL 21-Mar-16 9:20 AM LDC MS-9
2016004530 MARSHALL 21-Mar-16 10:00 AM LDC MS-10
2016004531 MARSHALL 21-Mar-16 8:15 AM PSP MS-11
2016004532 MARSHALL 21-Mar-16 8:55 AM PSP MS-12
2016004533 MARSHALL 21-Mar-16 10:05 AM PSP MS-13
2016004534 MARSHALL 21-Mar-16 12:00 PM LDC MS-14
2016004535 MARSHALL 21-Mar-16 11:10 AM LDC MS-15
2016004536 MARSHALL 21-Mar-16 11:20 AM PSP MS-16
2016004537 MARSHALL 21-Mar-16 9:20 AM PSP SW-1
2016004538 MARSHALL 21-Mar-16 10:20 AM PSP C1 LEACHATE
2016004539 MARSHALL 21-Mar-16 12:05 PM PSP FIELD BLANK
12 Total Samples
Page 2 of 26
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:4/1/2016
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020402
2016004528
Collection Date:21-Mar-16 8:25 AM
Site:MS-8
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)18 mg/L
(CaCO3)
SM 2320B 03/23/2016 10:34 CJELLIO51
INORGANIC IONS BY IC
Chloride 1.3 mg/L EPA 9056A 03/22/2016 08:48 BGN90340.1 1
Fluoride 0.15 mg/L EPA 9056A 03/22/2016 08:48 BGN90340.1 1
Nitrate 0.52 mg/L EPA 9056A 03/22/2016 08:48 BGN90340.1 1
Nitrate as N 0.12 mg-N/L EPA 9056A 03/22/2016 08:48 BGN90340.023 1
Sulfate 0.14 mg/L EPA 9056A 03/22/2016 08:48 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 03/22/2016 14:31 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.039 mg/L SW 6010D 03/30/2016 11:26 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 03/30/2016 11:26 JJMACKE0.05 1
Calcium (Ca)3.01 mg/L SW 6010D 03/30/2016 11:26 JJMACKE0.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 03/30/2016 11:26 JJMACKE0.005 1
Iron (Fe)0.526 mg/L SW 6010D 03/30/2016 11:26 JJMACKE0.01 1
Magnesium (Mg)1.47 mg/L SW 6010D 03/30/2016 11:26 JJMACKE0.005 1
Manganese (Mn)0.005 mg/L SW 6010D 03/30/2016 11:26 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 03/30/2016 11:26 JJMACKE0.005 1
Potassium (K)1.05 mg/L SW 6010D 03/30/2016 11:26 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 03/30/2016 11:26 JJMACKE0.005 1
Sodium (Na)4.14 mg/L SW 6010D 03/30/2016 11:26 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 03/30/2016 11:26 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 03/30/2016 16:18 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 03/30/2016 16:18 JAHERMA11
Chromium (Cr)4.67 ug/L SW 6020B 03/30/2016 16:18 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 03/30/2016 16:18 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 03/30/2016 16:18 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 64 mg/L SM2540C 03/22/2016 14:20 PARMSTR251
Page 4 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020402
2016004529
Collection Date:21-Mar-16 9:20 AM
Site:MS-9
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)39 mg/L
(CaCO3)
SM 2320B 03/23/2016 07:47 CJELLIO201
INORGANIC IONS BY IC
Chloride 1.2 mg/L EPA 9056A 03/22/2016 09:39 BGN90340.1 1
Fluoride 0.15 mg/L EPA 9056A 03/22/2016 09:39 BGN90340.1 1
Nitrate 0.78 mg/L EPA 9056A 03/22/2016 09:39 BGN90340.1 1
Nitrate as N 0.18 mg-N/L EPA 9056A 03/22/2016 09:39 BGN90340.023 1
Sulfate 0.31 mg/L EPA 9056A 03/22/2016 09:39 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 03/22/2016 14:39 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.039 mg/L SW 6010D 03/30/2016 11:15 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 03/30/2016 11:15 JJMACKE0.05 1
Calcium (Ca)10.4 mg/L SW 6010D 03/30/2016 11:15 JJMACKE0.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 03/30/2016 11:15 JJMACKE0.005 1
Iron (Fe)0.063 mg/L SW 6010D 03/30/2016 11:15 JJMACKE0.01 1
Magnesium (Mg)1.13 mg/L SW 6010D 03/30/2016 11:15 JJMACKE0.005 1
Manganese (Mn)0.007 mg/L SW 6010D 03/30/2016 11:15 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 03/30/2016 11:15 JJMACKE0.005 1
Potassium (K)1.19 mg/L SW 6010D 03/30/2016 11:15 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 03/30/2016 11:15 JJMACKE0.005 1
Sodium (Na)3.92 mg/L SW 6010D 03/30/2016 11:15 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 03/30/2016 11:15 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 03/30/2016 16:50 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 03/30/2016 16:50 JAHERMA11
Chromium (Cr)1.98 ug/L SW 6020B 03/30/2016 16:50 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 03/30/2016 16:50 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 03/30/2016 16:50 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 71 mg/L SM2540C 03/22/2016 14:20 PARMSTR251
Page 5 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020402
2016004530
Collection Date:21-Mar-16 10:00 AM
Site:MS-10
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 03/23/2016 10:34 CJELLIO51
INORGANIC IONS BY IC
Chloride 1.5 mg/L EPA 9056A 03/22/2016 09:55 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 03/22/2016 09:55 BGN90340.1 1
Nitrate 3.1 mg/L EPA 9056A 03/22/2016 09:55 BGN90340.1 1
Nitrate as N 0.70 mg-N/L EPA 9056A 03/22/2016 09:55 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 03/22/2016 09:55 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 03/22/2016 14:41 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.145 mg/L SW 6010D 03/30/2016 11:30 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 03/30/2016 11:30 JJMACKE0.05 1
Calcium (Ca)0.249 mg/L SW 6010D 03/30/2016 11:30 JJMACKE0.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 03/30/2016 11:30 JJMACKE0.005 1
Iron (Fe)0.644 mg/L SW 6010D 03/30/2016 11:30 JJMACKE0.01 1
Magnesium (Mg)0.513 mg/L SW 6010D 03/30/2016 11:30 JJMACKE0.005 1
Manganese (Mn)0.038 mg/L SW 6010D 03/30/2016 11:30 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 03/30/2016 11:30 JJMACKE0.005 1
Potassium (K)0.962 mg/L SW 6010D 03/30/2016 11:30 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 03/30/2016 11:30 JJMACKE0.005 1
Sodium (Na)2.07 mg/L SW 6010D 03/30/2016 11:30 JJMACKE0.05 1
Zinc (Zn)0.010 mg/L SW 6010D 03/30/2016 11:30 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 03/30/2016 16:56 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 03/30/2016 16:56 JAHERMA11
Chromium (Cr)< 1 ug/L SW 6020B 03/30/2016 16:56 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 03/30/2016 16:56 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 03/30/2016 16:56 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 41 mg/L SM2540C 03/22/2016 14:20 PARMSTR251
Page 6 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020402
2016004531
Collection Date:21-Mar-16 8:15 AM
Site:MS-11
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)7.3 mg/L
(CaCO3)
SM 2320B 03/23/2016 10:34 CJELLIO51
INORGANIC IONS BY IC
Chloride 7.5 mg/L EPA 9056A 03/22/2016 10:12 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 03/22/2016 10:12 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 03/22/2016 10:12 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 03/22/2016 10:12 BGN90340.023 1
Sulfate 3.7 mg/L EPA 9056A 03/22/2016 10:12 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 03/22/2016 14:44 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.097 mg/L SW 6010D 03/30/2016 11:34 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 03/30/2016 11:34 JJMACKE0.05 1
Calcium (Ca)1.50 mg/L SW 6010D 03/30/2016 11:34 JJMACKE0.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 03/30/2016 11:34 JJMACKE0.005 1
Iron (Fe)0.284 mg/L SW 6010D 03/30/2016 11:34 JJMACKE0.01 1
Magnesium (Mg)1.12 mg/L SW 6010D 03/30/2016 11:34 JJMACKE0.005 1
Manganese (Mn)0.015 mg/L SW 6010D 03/30/2016 11:34 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 03/30/2016 11:34 JJMACKE0.005 1
Potassium (K)1.86 mg/L SW 6010D 03/30/2016 11:34 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 03/30/2016 11:34 JJMACKE0.005 1
Sodium (Na)5.49 mg/L SW 6010D 03/30/2016 11:34 JJMACKE0.05 1
Zinc (Zn)0.007 mg/L SW 6010D 03/30/2016 11:34 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 03/30/2016 17:01 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 03/30/2016 17:01 JAHERMA11
Chromium (Cr)3.22 ug/L SW 6020B 03/30/2016 17:01 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 03/30/2016 17:01 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 03/30/2016 17:01 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 47 mg/L SM2540C 03/22/2016 14:20 PARMSTR251
Page 7 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020402
2016004532
Collection Date:21-Mar-16 8:55 AM
Site:MS-12
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 03/23/2016 10:34 CJELLIO51
INORGANIC IONS BY IC
Chloride 3.4 mg/L EPA 9056A 03/22/2016 10:29 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 03/22/2016 10:29 BGN90340.1 1
Nitrate 0.89 mg/L EPA 9056A 03/22/2016 10:29 BGN90340.1 1
Nitrate as N 0.20 mg-N/L EPA 9056A 03/22/2016 10:29 BGN90340.023 1
Sulfate 0.16 mg/L EPA 9056A 03/22/2016 10:29 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 03/22/2016 14:46 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.080 mg/L SW 6010D 03/30/2016 11:38 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 03/30/2016 11:38 JJMACKE0.05 1
Calcium (Ca)0.187 mg/L SW 6010D 03/30/2016 11:38 JJMACKE0.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 03/30/2016 11:38 JJMACKE0.005 1
Iron (Fe)0.108 mg/L SW 6010D 03/30/2016 11:38 JJMACKE0.01 1
Magnesium (Mg)0.576 mg/L SW 6010D 03/30/2016 11:38 JJMACKE0.005 1
Manganese (Mn)0.017 mg/L SW 6010D 03/30/2016 11:38 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 03/30/2016 11:38 JJMACKE0.005 1
Potassium (K)2.08 mg/L SW 6010D 03/30/2016 11:38 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 03/30/2016 11:38 JJMACKE0.005 1
Sodium (Na)2.08 mg/L SW 6010D 03/30/2016 11:38 JJMACKE0.05 1
Zinc (Zn)0.007 mg/L SW 6010D 03/30/2016 11:38 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 03/30/2016 17:06 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 03/30/2016 17:06 JAHERMA11
Chromium (Cr)< 1 ug/L SW 6020B 03/30/2016 17:06 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 03/30/2016 17:06 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 03/30/2016 17:06 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 28 mg/L SM2540C 03/22/2016 14:20 PARMSTR251
Page 8 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020402
2016004533
Collection Date:21-Mar-16 10:05 AM
Site:MS-13
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)18 mg/L
(CaCO3)
SM 2320B 03/23/2016 10:34 CJELLIO51
INORGANIC IONS BY IC
Chloride 3.0 mg/L EPA 9056A 03/22/2016 10:46 BGN90340.1 1
Fluoride 0.12 mg/L EPA 9056A 03/22/2016 10:46 BGN90340.1 1
Nitrate 9.0 mg/L EPA 9056A 03/22/2016 10:46 BGN90340.1 1
Nitrate as N 2.0 mg-N/L EPA 9056A 03/22/2016 10:46 BGN90340.023 1
Sulfate 0.31 mg/L EPA 9056A 03/22/2016 10:46 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 03/22/2016 14:48 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.095 mg/L SW 6010D 03/30/2016 11:42 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 03/30/2016 11:42 JJMACKE0.05 1
Calcium (Ca)5.07 mg/L SW 6010D 03/30/2016 11:42 JJMACKE0.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 03/30/2016 11:42 JJMACKE0.005 1
Iron (Fe)0.119 mg/L SW 6010D 03/30/2016 11:42 JJMACKE0.01 1
Magnesium (Mg)1.24 mg/L SW 6010D 03/30/2016 11:42 JJMACKE0.005 1
Manganese (Mn)0.009 mg/L SW 6010D 03/30/2016 11:42 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 03/30/2016 11:42 JJMACKE0.005 1
Potassium (K)2.36 mg/L SW 6010D 03/30/2016 11:42 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 03/30/2016 11:42 JJMACKE0.005 1
Sodium (Na)4.52 mg/L SW 6010D 03/30/2016 11:42 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 03/30/2016 11:42 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 03/30/2016 17:23 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 03/30/2016 17:23 JAHERMA11
Chromium (Cr)< 1 ug/L SW 6020B 03/30/2016 17:23 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 03/30/2016 17:23 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 03/30/2016 17:23 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 53 mg/L SM2540C 03/22/2016 14:20 PARMSTR251
Page 9 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020402
2016004534
Collection Date:21-Mar-16 12:00 PM
Site:MS-14
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)27 mg/L
(CaCO3)
SM 2320B 03/23/2016 07:47 CJELLIO201
INORGANIC IONS BY IC
Chloride 1.00 mg/L EPA 9056A 03/22/2016 11:03 BGN90340.1 1
Fluoride 0.13 mg/L EPA 9056A 03/22/2016 11:03 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 03/22/2016 11:03 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 03/22/2016 11:03 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 03/22/2016 11:03 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 03/22/2016 14:51 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.047 mg/L SW 6010D 03/30/2016 11:53 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 03/30/2016 11:53 JJMACKE0.05 1
Calcium (Ca)3.87 mg/L SW 6010D 03/30/2016 11:53 JJMACKE0.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 03/30/2016 11:53 JJMACKE0.005 1
Iron (Fe)0.186 mg/L SW 6010D 03/30/2016 11:53 JJMACKE0.01 1
Magnesium (Mg)0.916 mg/L SW 6010D 03/30/2016 11:53 JJMACKE0.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 03/30/2016 11:53 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 03/30/2016 11:53 JJMACKE0.005 1
Potassium (K)1.52 mg/L SW 6010D 03/30/2016 11:53 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 03/30/2016 11:53 JJMACKE0.005 1
Sodium (Na)6.40 mg/L SW 6010D 03/30/2016 11:53 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 03/30/2016 11:53 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 03/30/2016 17:28 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 03/30/2016 17:28 JAHERMA11
Chromium (Cr)< 1 ug/L SW 6020B 03/30/2016 17:28 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 03/30/2016 17:28 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 03/30/2016 17:28 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 68 mg/L SM2540C 03/22/2016 14:20 PARMSTR251
Page 10 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020402
2016004535
Collection Date:21-Mar-16 11:10 AM
Site:MS-15
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)64 mg/L
(CaCO3)
SM 2320B 03/23/2016 07:47 CJELLIO201
INORGANIC IONS BY IC
Chloride 2.9 mg/L EPA 9056A 03/22/2016 11:20 BGN90340.1 1
Fluoride 0.12 mg/L EPA 9056A 03/22/2016 11:20 BGN90340.1 1
Nitrate 1.7 mg/L EPA 9056A 03/22/2016 11:20 BGN90340.1 1
Nitrate as N 0.39 mg-N/L EPA 9056A 03/22/2016 11:20 BGN90340.023 1
Sulfate 1.3 mg/L EPA 9056A 03/22/2016 11:20 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 03/22/2016 14:53 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.093 mg/L SW 6010D 03/30/2016 11:57 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 03/30/2016 11:57 JJMACKE0.05 1
Calcium (Ca)16.6 mg/L SW 6010D 03/30/2016 11:57 JJMACKE0.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 03/30/2016 11:57 JJMACKE0.005 1
Iron (Fe)0.031 mg/L SW 6010D 03/30/2016 11:57 JJMACKE0.01 1
Magnesium (Mg)3.82 mg/L SW 6010D 03/30/2016 11:57 JJMACKE0.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 03/30/2016 11:57 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 03/30/2016 11:57 JJMACKE0.005 1
Potassium (K)2.30 mg/L SW 6010D 03/30/2016 11:57 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 03/30/2016 11:57 JJMACKE0.005 1
Sodium (Na)4.73 mg/L SW 6010D 03/30/2016 11:57 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 03/30/2016 11:57 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 03/30/2016 17:50 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 03/30/2016 17:50 JAHERMA11
Chromium (Cr)25.8 ug/L SW 6020B 03/30/2016 17:50 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 03/30/2016 17:50 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 03/30/2016 17:50 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 100 mg/L SM2540C 03/22/2016 14:20 PARMSTR251
Page 11 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020402
2016004536
Collection Date:21-Mar-16 11:20 AM
Site:MS-16
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)56 mg/L
(CaCO3)
SM 2320B 03/23/2016 07:47 CJELLIO201
INORGANIC IONS BY IC
Chloride 1.6 mg/L EPA 9056A 03/22/2016 12:27 BGN90340.1 1
Fluoride 0.23 mg/L EPA 9056A 03/22/2016 12:27 BGN90340.1 1
Nitrate 0.94 mg/L EPA 9056A 03/22/2016 12:27 BGN90340.1 1
Nitrate as N 0.21 mg-N/L EPA 9056A 03/22/2016 12:27 BGN90340.023 1
Sulfate 0.50 mg/L EPA 9056A 03/22/2016 12:27 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 03/22/2016 14:56 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.120 mg/L SW 6010D 03/30/2016 12:08 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 03/30/2016 12:08 JJMACKE0.05 1
Calcium (Ca)9.54 mg/L SW 6010D 03/30/2016 12:08 JJMACKE0.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 03/30/2016 12:08 JJMACKE0.005 1
Iron (Fe)1.56 mg/L SW 6010D 03/30/2016 12:08 JJMACKE0.01 1
Magnesium (Mg)4.55 mg/L SW 6010D 03/30/2016 12:08 JJMACKE0.005 1
Manganese (Mn)0.020 mg/L SW 6010D 03/30/2016 12:08 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 03/30/2016 12:08 JJMACKE0.005 1
Potassium (K)2.39 mg/L SW 6010D 03/30/2016 12:08 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 03/30/2016 12:08 JJMACKE0.005 1
Sodium (Na)7.92 mg/L SW 6010D 03/30/2016 12:08 JJMACKE0.05 1
Zinc (Zn)0.007 mg/L SW 6010D 03/30/2016 12:08 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 03/30/2016 17:55 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 03/30/2016 17:55 JAHERMA11
Chromium (Cr)3.66 ug/L SW 6020B 03/30/2016 17:55 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 03/30/2016 17:55 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 03/30/2016 17:55 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 110 mg/L SM2540C 03/22/2016 14:20 PARMSTR251
Page 12 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020402
2016004537
Collection Date:21-Mar-16 9:20 AM
Site:SW-1
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 03/23/2016 10:34 CJELLIO51
INORGANIC IONS BY IC
Chloride 3.2 mg/L EPA 9056A 03/22/2016 13:18 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 03/22/2016 13:18 BGN90340.1 1
Nitrate 0.29 mg/L EPA 9056A 03/22/2016 13:18 BGN90340.1 1
Nitrate as N 0.07 mg-N/L EPA 9056A 03/22/2016 13:18 BGN90340.023 1
Sulfate 4.5 mg/L EPA 9056A 03/22/2016 13:18 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 03/22/2016 15:08 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.065 mg/L SW 6010D 03/30/2016 12:12 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 03/30/2016 12:12 JJMACKE0.05 1
Calcium (Ca)1.47 mg/L SW 6010D 03/30/2016 12:12 JJMACKE0.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 03/30/2016 12:12 JJMACKE0.005 1
Iron (Fe)0.969 mg/L SW 6010D 03/30/2016 12:12 JJMACKE0.01 1
Magnesium (Mg)1.18 mg/L SW 6010D 03/30/2016 12:12 JJMACKE0.005 1
Manganese (Mn)0.185 mg/L SW 6010D 03/30/2016 12:12 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 03/30/2016 12:12 JJMACKE0.005 1
Potassium (K)1.94 mg/L SW 6010D 03/30/2016 12:12 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 03/30/2016 12:12 JJMACKE0.005 1
Sodium (Na)1.45 mg/L SW 6010D 03/30/2016 12:12 JJMACKE0.05 1
Zinc (Zn)0.006 mg/L SW 6010D 03/30/2016 12:12 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 03/30/2016 18:00 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 03/30/2016 18:00 JAHERMA11
Chromium (Cr)< 1 ug/L SW 6020B 03/30/2016 18:00 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 03/30/2016 18:00 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 03/30/2016 18:00 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 37 mg/L SM2540C 03/22/2016 14:20 PARMSTR251
Page 13 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020402
2016004538
Collection Date:21-Mar-16 10:20 AM
Site:C1 LEACHATE
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)< 20 mg/L
(CaCO3)
SM 2320B 03/23/2016 07:47 CJELLIO201
INORGANIC IONS BY IC
Chloride 390 mg/L EPA 9056A 03/22/2016 15:16 BGN903450500
Fluoride 4.0 mg/L EPA 9056A 03/22/2016 15:16 BGN90342.5 25
Nitrate 22 mg/L EPA 9056A 03/22/2016 15:16 BGN90342.5 25
Nitrate as N 5.0 mg-N/L EPA 9056A 03/22/2016 15:16 BGN90340.023 1
Sulfate 2500 mg/L EPA 9056A 03/22/2016 15:16 BGN903450500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 03/22/2016 14:58 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.024 mg/L SW 6010D 03/30/2016 12:16 JJMACKE0.005 1
Boron (B)35.1 mg/L SW 6010D 03/30/2016 12:16 JJMACKE0.5 10
Calcium (Ca)552 mg/L SW 6010D 03/30/2016 12:16 JJMACKE0.1 10
Copper (Cu)< 0.005 mg/L SW 6010D 03/30/2016 12:16 JJMACKE0.005 1
Iron (Fe)148 mg/L SW 6010D 03/30/2016 12:16 JJMACKE0.1 10
Magnesium (Mg)188 mg/L SW 6010D 03/30/2016 12:16 JJMACKE0.05 10
Manganese (Mn)4.78 mg/L SW 6010D 03/30/2016 12:16 JJMACKE0.005 1
Nickel (Ni)0.127 mg/L SW 6010D 03/30/2016 12:16 JJMACKE0.005 1
Potassium (K)62.9 mg/L SW 6010D 03/30/2016 12:16 JJMACKE110
Silver (Ag)< 0.005 mg/L SW 6010D 03/30/2016 12:16 JJMACKE0.005 1
Sodium (Na)106 mg/L SW 6010D 03/30/2016 12:16 JJMACKE0.5 10
Zinc (Zn)0.182 mg/L SW 6010D 03/30/2016 12:16 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 10 ug/L SW 6020B 03/30/2016 18:06 JAHERMA1010
Cadmium (Cd)< 10 ug/L SW 6020B 03/30/2016 18:06 JAHERMA1010
Chromium (Cr)< 10 ug/L SW 6020B 03/30/2016 18:06 JAHERMA1010
Lead (Pb)< 10 ug/L SW 6020B 03/30/2016 18:06 JAHERMA1010
Selenium (Se)478 ug/L SW 6020B 03/30/2016 18:06 JAHERMA1010
TOTAL DISSOLVED SOLIDS
TDS 4100 mg/L SM2540C 03/22/2016 14:20 PARMSTR5001
Page 14 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020402
2016004539
Collection Date:21-Mar-16 12:05 PM
Site:FIELD BLANK
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)< 20 mg/L
(CaCO3)
SM 2320B 03/23/2016 07:47 CJELLIO201
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 9056A 03/22/2016 08:30 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 03/22/2016 08:30 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 03/22/2016 08:30 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 03/22/2016 08:30 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 03/22/2016 08:30 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 03/22/2016 15:15 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L SW 6010D 03/30/2016 12:20 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 03/30/2016 12:20 JJMACKE0.05 1
Calcium (Ca)0.010 mg/L SW 6010D 03/30/2016 12:20 JJMACKE0.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 03/30/2016 12:20 JJMACKE0.005 1
Iron (Fe)< 0.01 mg/L SW 6010D 03/30/2016 12:20 JJMACKE0.01 1
Magnesium (Mg)< 0.005 mg/L SW 6010D 03/30/2016 12:20 JJMACKE0.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 03/30/2016 12:20 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 03/30/2016 12:20 JJMACKE0.005 1
Potassium (K)< 0.1 mg/L SW 6010D 03/30/2016 12:20 JJMACKE0.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 03/30/2016 12:20 JJMACKE0.005 1
Sodium (Na)< 0.05 mg/L SW 6010D 03/30/2016 12:20 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 03/30/2016 12:20 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 03/30/2016 18:11 JAHERMA11
Cadmium (Cd)< 1 ug/L SW 6020B 03/30/2016 18:11 JAHERMA11
Chromium (Cr)< 1 ug/L SW 6020B 03/30/2016 18:11 JAHERMA11
Lead (Pb)< 1 ug/L SW 6020B 03/30/2016 18:11 JAHERMA11
Selenium (Se)< 1 ug/L SW 6020B 03/30/2016 18:11 JAHERMA11
Page 15 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020402
Q16030463 ALK_FIX4.5 ALKALINITY (FIXED END POINT 4.5)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16020402 -- 2016004529
Alkalinity (mg/L CaCO3)0.617mg/L
(CaCO3)
-139.2
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3)54.3 99.2mg/L
(CaCO3)
-12080153.9
Page 16 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020402
Q16030470 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16020402 -- 2016004530
Alkalinity (mg/L CaCO3)0mg/L
(CaCO3)
-11.84
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3)10.86 89mg/L
(CaCO3)
-1208019.66
Page 17 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020402
Q16030443 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0318 mg/L -10.0318 0.1 < 1/2 RDL
Fluoride 0.0318 mg/L -10.0318 0.1 < 1/2 RDL
Nitrate 0.0246 mg/L -10.0246 0.1 < 1/2 RDL
Sulfate -0.0223 mg/L -1-0.0223 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 6.59 5 106mg/L -1208016.59
Fluoride 5.32 5 103mg/L -1208015.32
Nitrate 5.64 5 102mg/L -1208015.64
Sulfate 5.31 5 103mg/L -1208015.31
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 6.59 5 106 0.0471mg/L -1208016.59
Fluoride 5.32 5 103 0.0929mg/L -1208015.32
Nitrate 5.63 5 102 0.106mg/L -1208015.63
Sulfate 5.3 5 103 0.155mg/L -1208015.3
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 7.03 5 109mg/L -1208017.03
Fluoride 5.38 5 103mg/L -1208015.38
Nitrate 6.11 5 103mg/L -1208016.11
Sulfate 5.71 5 104mg/L -1208015.71
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 7.07 5 109 0.851mg/L -1208017.07
Fluoride 5.41 5 104 0.662mg/L -1208015.41
Nitrate 6.12 5 104 0.22mg/L -1208016.12
Sulfate 5.73 5 104 0.393mg/L -1208015.73
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.07 5 101mg/L -1208015.07
Fluoride 5.19 5 104mg/L -1208015.19
Nitrate 5.05 5 101mg/L -1208015.05
Sulfate 5.02 5 100mg/L -1208015.02
Page 18 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020402
Q16030453 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) -0.007 ug/L -1-0.007 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.002 ug/L -10.002 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2 2 100ug/L -1208012
Mercury (Hg) 2 2 100ug/L -1158512
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16020402 -- 2016004528
Mercury (Hg) 0.97 1 97.7ug/L -1307010.97
Mercury (Hg) 0.97 1 97.7ug/L -1257510.97
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16020402 -- 2016004528
Mercury (Hg) 0.973 1 98 0.307ug/L -1257510.973
Mercury (Hg) 0.973 1 98 0.307ug/L -1307010.973
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16020402 -- 2016004537
Mercury (Hg) 0.971 1 96.6ug/L -1307010.971
Mercury (Hg) 0.971 1 96.6ug/L -1257510.971
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16020402 -- 2016004537
Mercury (Hg) 0.954 1 94.9 1.78ug/L -1257510.954
Mercury (Hg) 0.954 1 94.9 1.78ug/L -1307010.954
Page 19 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020402
Q16030541 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) -0.000082 mg/L -1-0.000082 0.005 < 1/2 RDL
Boron (B) 0.00155 mg/L -10.00155 0.05 < 1/2 RDL
Calcium (Ca) 0.00346 mg/L -10.00346 0.01 < 1/2 RDL
Copper (Cu) 0.000445 mg/L -10.000445 0.005 < 1/2 RDL
Iron (Fe) 0.000142 mg/L -10.000142 0.01 < 1/2 RDL
Magnesium (Mg) 0.00235 mg/L -10.00235 0.005 < 1/2 RDL
Manganese (Mn) -0.000286 mg/L -1-0.000286 0.005 < 1/2 RDL
Nickel (Ni) -0.000573 mg/L -1-0.000573 0.005 < 1/2 RDL
Potassium (K) -0.0109 mg/L -1-0.0109 0.1 < 1/2 RDL
Silver (Ag) 0.000253 mg/L -10.000253 0.005 < 1/2 RDL
Sodium (Na) 0.00155 mg/L -10.00155 0.05 < 1/2 RDL
Zinc (Zn) 0.00225 mg/L -10.00225 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 5.09 5 102mg/L -1208015.09
Boron (B) 4.93 5 98.5mg/L -1208014.93
Calcium (Ca) 4.84 5 96.8mg/L -1208014.84
Copper (Cu) 4.98 5 99.7mg/L -1208014.98
Iron (Fe) 4.88 5 97.7mg/L -1208014.88
Magnesium (Mg) 5.11 5 102mg/L -1208015.11
Manganese (Mn) 5.09 5 102mg/L -1208015.09
Nickel (Ni) 4.92 5 98.4mg/L -1208014.92
Potassium (K) 4.98 5 99.5mg/L -1208014.98
Silver (Ag) 0.501 0.5 100mg/L -1208010.501
Sodium (Na) 5.02 5 100mg/L -1208015.02
Zinc (Zn) 5 5 99.9mg/L -1208015
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16020402 -- 2016004529
Barium (Ba) 5.3 5 105mg/L -1257515.3
Boron (B) 5.07 5 101mg/L -1257515.07
Calcium (Ca) 15.7 5 105mg/L -12575115.7
Copper (Cu) 5.12 5 102mg/L -1257515.12
Iron (Fe) 5.09 5 101mg/L -1257515.09
Magnesium (Mg) 6.42 5 106mg/L -1257516.42
Manganese (Mn) 5.25 5 105mg/L -1257515.25
Nickel (Ni) 5.05 5 101mg/L -1257515.05
Potassium (K) 6.37 5 104mg/L -1257516.37
Silver (Ag) 0.508 0.5 101mg/L -1257510.508
Page 20 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020402
Q16030541 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16020402 -- 2016004529
Sodium (Na) 9.2 5 106mg/L -1257519.2
Zinc (Zn) 5.17 5 103mg/L -1257515.17
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16020402 -- 2016004529
Barium (Ba) 5.2 5 103 1.86mg/L -1257515.2
Boron (B) 5 5 99.9 1.37mg/L -1257515
Calcium (Ca) 15.4 5 99.3 5.16mg/L -12575115.4
Copper (Cu) 5.01 5 100 2.15mg/L -1257515.01
Iron (Fe) 5 5 98.8 1.77mg/L -1257515
Magnesium (Mg) 6.33 5 104 1.85mg/L -1257516.33
Manganese (Mn) 5.16 5 103 1.77mg/L -1257515.16
Nickel (Ni) 4.97 5 99.3 1.78mg/L -1257514.97
Potassium (K) 6.24 5 101 2.39mg/L -1257516.24
Silver (Ag) 0.501 0.5 100 1.38mg/L -1257510.501
Sodium (Na) 9.03 5 102 3.43mg/L -1257519.03
Zinc (Zn) 5.07 5 101 1.92mg/L -1257515.07
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16020402 -- 2016004535
Barium (Ba) 4.95 5 97.1mg/L -1257514.95
Boron (B) 4.76 5 95mg/L -1257514.76
Calcium (Ca) 20.7 5 81.7mg/L -12575120.7
Copper (Cu) 4.76 5 95.1mg/L -1257514.76
Iron (Fe) 4.71 5 93.7mg/L -1257514.71
Magnesium (Mg) 8.39 5 91.4mg/L -1257518.39
Manganese (Mn) 4.88 5 97.6mg/L -1257514.88
Nickel (Ni) 4.7 5 93.9mg/L -1257514.7
Potassium (K) 7.01 5 94.4mg/L -1257517.01
Silver (Ag) 0.474 0.5 94.7mg/L -1257510.474
Sodium (Na) 9.46 5 94.7mg/L -1257519.46
Zinc (Zn) 4.79 5 95.7mg/L -1257514.79
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16020402 -- 2016004535
Barium (Ba) 5.22 5 103 5.49mg/L -1257515.22
Boron (B) 4.97 5 99.2 4.37mg/L -1257514.97
Calcium (Ca) 21.9 5 106 25.7mg/L -12575121.9
Copper (Cu) 5 5 99.9 4.92mg/L -1257515
Iron (Fe) 4.96 5 98.6 5.14mg/L -1257514.96
Page 21 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020402
Q16030541 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16020402 -- 2016004535
Magnesium (Mg) 8.88 5 101 10.1mg/L -1257518.88
Manganese (Mn) 5.13 5 103 5mg/L -1257515.13
Nickel (Ni) 4.94 5 98.7 4.96mg/L -1257514.94
Potassium (K) 7.36 5 101 7.01mg/L -1257517.36
Silver (Ag) 0.497 0.5 99.3 4.82mg/L -1257510.497
Sodium (Na) 9.92 5 104 9.18mg/L -1257519.92
Zinc (Zn) 5.04 5 101 5.13mg/L -1257515.04
Page 22 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020402
Q16030544 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As) -0.0011 ug/L -1-0.0011 1 < 1/2 RDL
Cadmium (Cd) -0.0008 ug/L -1-0.0008 1 < 1/2 RDL
Chromium (Cr) -0.0725 ug/L -1-0.0725 1 < 1/2 RDL
Lead (Pb) -0.0029 ug/L -1-0.0029 1 < 1/2 RDL
Selenium (Se) 0.0074 ug/L -10.0074 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As) 51.3 50 103ug/L -12080151.3
Cadmium (Cd) 52 50 104ug/L -12080152
Chromium (Cr) 51.7 50 103ug/L -12080151.7
Lead (Pb) 51.6 50 103ug/L -12080151.6
Selenium (Se) 49 50 98ug/L -12080149
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16020402 -- 2016004528
Arsenic (As) 48.6 50 96.9ug/L -12080148.6
Cadmium (Cd) 50.3 50 101ug/L -12080150.3
Chromium (Cr) 55 50 101ug/L -12080155
Lead (Pb) 50.6 50 101ug/L -12080150.6
Selenium (Se) 49.4 50 98.8ug/L -12080149.4
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16020402 -- 2016004528
Arsenic (As) 49.4 50 98.5 1.6ug/L -12080149.4
Cadmium (Cd) 50.8 50 102 0.978ug/L -12080150.8
Chromium (Cr) 55.8 50 102 1.56ug/L -12080155.8
Lead (Pb) 51.5 50 102 1.68ug/L -12080151.5
Selenium (Se) 50.9 50 102 2.97ug/L -12080150.9
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16020402 -- 2016004532
Arsenic (As) 48.1 50 96.1ug/L -12080148.1
Cadmium (Cd) 49.5 50 98.9ug/L -12080149.5
Chromium (Cr) 50.7 50 100ug/L -12080150.7
Lead (Pb) 50.1 50 99.7ug/L -12080150.1
Selenium (Se) 47.8 50 95.5ug/L -12080147.8
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16020402 -- 2016004532
Arsenic (As) 47.6 50 95.2 0.881ug/L -12080147.6
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Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020402
Q16030544 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16020402 -- 2016004532
Cadmium (Cd) 49.5 50 98.9 0.0372ug/L -12080149.5
Chromium (Cr) 50.4 50 99.7 0.635ug/L -12080150.4
Lead (Pb) 50 50 99.6 0.117ug/L -12080150
Selenium (Se) 48 50 96 0.525ug/L -12080148
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Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020402
Q16030448 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16020402 -- 2016004528
TDS 1.55mg/L -165
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16020402 -- 2016004529
TDS 1.42mg/L -170
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 96mg/L -11090196
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