8807_Transylvania County Solid Waste_SoilAssesRpt_26226_20160513

2211 West Meadowview Rd. Boone Building, Suite 101 Greensboro, NC 27407 tel: [phone] fax: [phone]
www.JoyceEngineering.com
May 13, 2016

Mr. Ervin Lane
North Carolina Department of Environmental Quality
Division of Waste Management/ Solid Waste Section
1646 Mail Service Center Raleigh, North Carolina 27699-1646

RE: Soil Assessment Report
Woodruff Landfill, Transylvania County; Permit No. 88-07 MSWLF-1990.
JOYCE Project No. 336.1601.12, Tasks No. 03
Dear Mr. Lane:

On behalf of Transylvania County, Joyce Engineering (JOYCE) presents this report on the results of a soil assessment conducted at the Woodruff Landfill, Permit # 88-07, in response
to a Notice of Violation (NOV) issued by the North Carolina Department of Environmental
Quality (DEQ) Solid Waste Section (SWS) on April 5, 2016. The NOV was issued due to
evidence of a release of leachate from a landfill working face and into the stormwater ditch
observed during facility inspections conducted by the SWS on March 18, 2016.
BACKGROUND
The Woodruff Landfill is owned and operated by Transylvania County. The landfill is
located in Rosman, North Carolina. During an inspection of the facility on March 18, 2016, the
SWS inspectors observed a release of leachate from the working face and into to the stormwater
ditch. The April 5th NOV called for the Transylvania County to contact you within 10‐days of receipt of the Notice of Violation, to determine the requirements for a soil sampling plan to
investigate the extent of the leachate release and corrective measures. JOYCE submitted a Soil
Assessment Plan (SAP) on April 12, 2016, and it was approved on April 13, 2016. Surface
water sampling was not included in the assessment plan. The nearest surface water, Woodruff
Branch, is approximately 300 feet from the area of observed leachate release and no evidence indicated that any leachate had migrated to the surface water body.

SOIL SAMPLING
JOYCE collected soil samples from the site in accordance with the SAP approved on
April 13, 2016. The sampling was conducted in the area shown on the bottom photo on page 6 of the Facility Compliance Inspection Report (FCIR) dated March 18, 2016. Soil samples were
collected from three locations within the apparent leachate impact area. Soil samples SS-1,
Mr. Ervin Lane
May 13, 2016
Page 1 of 3

SS-2, and SS-3 were collected at 10, 20, and 30 feet, respectively, downgradient from the edge of waste. In addition, JOYCE collected one soil sample from an upgradient location (SS-4) to
represent background soil conditions. The background sample was collected near the property
line, approximately 15 feet west from MW-3. At each of the four locations, a soil sample was
collected from a depth of 12-24 inches. The soil sampling was conducted in the following order: the background first, followed by the presumed least contaminated to the presumed most contaminated.

All sampling was conducted under the supervision of a licensed professional geologist.
The soil samples were collected using a stainless-steel hand auger. The sampling equipment was decontaminated before sampling and between samples using standard decontamination procedures as described in the SAP. Personnel wore disposable nitrile gloves when handling soil
samples. All samples were placed in laboratory-prepared sample containers and put immediately
into a cooler with ice for transport to the laboratory.

SOIL ANALYSES
The soil samples were transported under chain-of-custody control to Pace Analytical
Services, Inc. in Huntersville, North Carolina for analysis. The soil samples were analyzed for
the NC Appendix I volatile organic compounds (VOCs) by EPA Method 5035/8260 and metals
by EPA Method 6010. The results are summarized in Table 1 and the complete laboratory analytical report and chain of custody are attached.

COMPARISON TO PRELIMINARY SOIL REMEDIATION GOALS
Table 1 summarizes the soil analytical results for the soil samples and includes the
Preliminary Soil Remediation Goals (PSRGs) from the NCDEQ Inactive Hazardous Sites Branch. The soil analytical results were compared to both the Residential Health-based PSRG
and the Protection of Groundwater PSRG.

Two metals (arsenic and cobalt) were detected in Sample SS-1 at concentrations above
the lowest applicable PSRG. The SS-1 result for arsenic (1.1 mg/kg) exceeds the PSRG Residential Health Based Soil Remediation goal of 0.68 mg/kg, and the Cobalt result (1.1 mg/kg)
exceeds the PSRG Protection of Groundwater goal of 0.9 mg/kg. Neither arsenic nor cobalt was
detected in the background sample (SS-4) or the samples farther from the waste (SS-2 and SS-3).
All of the metals detections were within the range of concentrations that occur naturally in the
mineralogy of the North Carolina Piedmont soils (Reid, 1993).
The only VOC detected in any of the soil samples was toluene at 2.9 µg/kg in Sample
SS-1. The toluene concentration in SS-1 was 3-5 orders of magnitude below the Residential
Health-based PSRG (818 mg/kg) and the Protection of Groundwater PSRG (5.5 mg/kg).

Mr. Ervin Lane
May 13, 2016
Page 2 of 3

DISCUSSION
The arsenic and cobalt concentrations near the impact area sample were marginally
higher than the PSGR goals and these metals were not detected in the background sample;
indicating that they may be due to leachate impact; however, they are within the range that occur
naturally. Typical arsenic concentrations in Piedmont and Blue Ridge area soils are 4-40 mg/kg and cobalt 5-10 mg/kg (Reid, 1993). Arsenic and Cobalt are not very mobile and are not likely
to leach from the soil to the groundwater in significant quantities, especially from such a small
impacted area.

The only VOC detection (toluene in SS-1) was several orders of magnitude below the applicable PSRGs, and it was not detected in the samples that were farther downgradient. This
indicates that any impact to the site soils from the reported leachate release was very minimal
both in concentration and extent.

The nearest surface water is the head of Woodruff Branch, located over 300 feet west of the apparent impact area, and groundwater is approximately at 15 to 20 feet deep in the vicinity
of the apparent impact area. Given the low concentrations and very limited area of impacted
soil, we believe there is little or no chance of impact to either surface water or groundwater.

We recommend no further action with regard to this incident. Please feel free to contact me at [phone] if you have any questions or comments.

Respectfully,
JOYCE ENGINEERING

Hannu Kemppinen, P.G.
Senior Project Consultant

Attachments: Table 1
Page 6 of 3/18/2016 FCIR
Laboratory Report
Ref.: Reid, Jeffery C. A Geochemical Atlas of North Carolina. North Carolina
Geological Survey, Bulletin 93. Raleigh, NC. 1993.

Copy: Jeff Brookshire, Transylvania County

SAMPLE
ID
CAS
Number
SWS
ID PARAMETER PSRG-RH
mg/kg
PSRG-PGW
mg/kg
RESULT
mg/kg METHOD MDL
mg/kg
MRL
mg/kg
8807-SS1 7440-38-2 14 Arsenic 0.68 5.8 1.10 EPA 6010 0.35 0.69
8807-SS1 7440-39-3 15 Barium 3,000 580 34.6 EPA 6010 0.17 0.35
8807-SS1 7440-41-7 23 Beryllium 32 63 0.34 EPA 6010 0.035 0.069
8807-SS1 7440-47-3 51 Chromium 24,000 360,000 1.10 EPA 6010 0.17 0.35
8807-SS1 7440-48-4 53 Cobalt 4.6 0.90 1.10 EPA 6010 0.17 0.35
8807-SS1 7440-50-8 54 Copper 620 700 0.98 EPA 6010 0.17 0.35
8807-SS1 7439-92-1 131 Lead 400 270 13.1 EPA 6010 0.17 0.35
8807-SS1 7440-02-0 152 Nickel 300 130 1.10 EPA 6010 0.17 0.35
8807-SS1 7440-62-2 209 Vanadium 78 6 3.00 EPA 6010 0.17 0.35
8807-SS1 7440-66-6 213 Zinc 4,600 1,200 29.8 EPA 6010 0.35 0.69
8807-SS1 108-88-3 196 Toluene 818 5.5 0.00 EPA 8260 0.81 2.3
8807-SS2 7440-39-3 15 Barium 3,000 580 51.1 EPA 6010 2.1 4.2
8807-SS2 7440-41-7 23 Beryllium 32 63 0.85 EPA 6010 0.42 0.84
8807-SS2 7439-92-1 131 Lead 400 270 10.2 EPA 6010 2.1 4.2
8807-SS2 7440-66-6 213 Zinc 4,600 1,200 12.4 EPA 6010 4.2 8.4
8807-SS3 7440-39-3 15 Barium 3,000 580 30.9 EPA 6010 1.1 2.1
8807-SS3 7440-41-7 23 Beryllium 32 63 0.43 EPA 6010 0.21 0.43
8807-SS3 7440-50-8 54 Copper 620 700 3.40 EPA 6010 1.1 2.1
8807-SS3 7439-92-1 131 Lead 400 270 11.0 EPA 6010 1.1 2.1
8807-SS3 7440-62-2 209 Vanadium 78 6 4.60 EPA 6010 1.1 2.1
8807-SS3 7440-66-6 213 Zinc 4,600 1,200 28.8 EPA 6010 2.1 4.3
8807-SS4 7440-39-3 15 Barium 3,000 580 44.9 EPA 6010 0.84 1.7
8807-SS4 7440-41-7 23 Beryllium 32 63 0.48 EPA 6010 0.17 0.34
8807-SS4 7440-50-8 54 Copper 620 700 1.80 EPA 6010 0.84 1.7
8807-SS4 7439-92-1 131 Lead 400 270 12.5 EPA 6010 0.84 1.7
8807-SS4 7440-62-2 209 Vanadium 78 6 4.30 EPA 6010 0.84 1.7
8807-SS4 7440-66-6 213 Zinc 4,600 1,200 55.5 EPA 6010 1.7 3.4
NOTES:All results in milligrams/kilogram = mg/kg = parts per million.
PSRG = Preliminary Soil Remediation Goals (NC-DEQ Inactive Hazardous Sites Branch)
PSRG-RH = Residential Health-Based PSRG.
PSRG-PGW = Protection of Groundwater PSRG.
MDL = Method detection limit.
MRL = Method reporting limit.
TABLE 1 - WOODRUFF LANDFILL SOIL ASSESSMENT SUMMARY
Woodruff Landfill, Permit 88-07
Transyvania County
JOYCE Engineering
FACILITY COMPLIANCE INSPECTION REPORT
Division of Waste Management
Solid Waste Section
Page 6 of 12

Near vertical working face.
Working face.
15A NCAC 13B.1626(11)(c) Methods such as fencing and diking shall be provided within the area to confine solid waste
subject to be blown by the wind. At the conclusion of each day of operation, all windblown material resulting from the
#=CL#
May 05, 2016
LIMS USE: FR - ALEX EVERHART
LIMS OBJECT ID: 92295599
92295599
Project:
Pace Project No.:
RE:
Mr. Alex Everhart
Joyce Engineering-NC
2211 W. Meadowview Road
Suite 101
Greensboro, NC 27407
TRANSYLVANIA SOIL SAMPLES
Dear Mr. Everhart:
Enclosed are the analytical results for sample(s) received by the laboratory on April 28, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc:Mr. Van Burbach, Joyce Engineering-NC
Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 27
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92295599
TRANSYLVANIA SOIL SAMPLES
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84Virginia/VELAP Certification #: 460221
Asheville Certification IDs2225 Riverside Drive, Asheville, NC 28804Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 27
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92295599
TRANSYLVANIA SOIL SAMPLES
Lab ID Sample ID Matrix Date Collected Date Received
92295599001 8807-SS1 Solid 04/28/16 10:13 04/28/16 13:30
92295599002 8807-SS2 Solid 04/28/16 10:27 04/28/16 13:30
92295599003 8807-SS3 Solid 04/28/16 10:37 04/28/16 13:30
92295599004 8807-SS4 Solid 04/28/16 10:43 04/28/16 13:30
92295599005 TRIP BLANK Solid 04/26/16 06:30 04/28/16 13:30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 27
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92295599
TRANSYLVANIA SOIL SAMPLES
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92295599001 8807-SS1 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
92295599002 8807-SS2 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
92295599003 8807-SS3 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
92295599004 8807-SS4 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
92295599005 TRIP BLANK EPA 8260 50 PASI-CDLK
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 27
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92295599
TRANSYLVANIA SOIL SAMPLES
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92295599001 8807-SS1
Arsenic 1.1 mg/kg 05/03/16 17:510.69EPA 6010
Barium 34.6 mg/kg 05/03/16 17:510.35EPA 6010
Beryllium 0.34 mg/kg 05/03/16 17:510.069EPA 6010
Chromium 1.1 mg/kg 05/03/16 17:510.35EPA 6010
Cobalt 1.1 mg/kg 05/03/16 17:510.35EPA 6010
Copper 0.98 mg/kg 05/03/16 17:510.35EPA 6010
Lead 13.1 mg/kg 05/03/16 17:510.35EPA 6010
Nickel 1.1 mg/kg 05/03/16 17:510.35EPA 6010
Vanadium 3.0 mg/kg 05/03/16 17:510.35EPA 6010
Zinc 29.8 mg/kg 05/03/16 17:510.69EPA 6010
Acetone 33.9J ug/kg 04/29/16 14:30 M145.2EPA 8260
Toluene 2.9 ug/kg 04/29/16 14:302.3EPA 8260
Percent Moisture 10 %05/02/16 06:420.10ASTM D2974-87
92295599002 8807-SS2
Barium 51.1 mg/kg 05/05/16 14:204.2EPA 6010
Beryllium 0.85 mg/kg 05/05/16 14:200.84EPA 6010
Lead 10.2 mg/kg 05/05/16 14:204.2EPA 6010
Zinc 12.4 mg/kg 05/05/16 14:208.4EPA 6010
Percent Moisture 8.2 %05/02/16 06:420.10ASTM D2974-87
92295599003 8807-SS3
Arsenic 2.5J mg/kg 05/04/16 14:034.3EPA 6010
Barium 30.9 mg/kg 05/04/16 14:032.1EPA 6010
Beryllium 0.43 mg/kg 05/04/16 14:030.43EPA 6010
Chromium 2.1J mg/kg 05/04/16 14:032.1EPA 6010
Cobalt 1.1J mg/kg 05/04/16 14:032.1EPA 6010
Copper 3.4 mg/kg 05/04/16 14:032.1EPA 6010
Lead 11.0 mg/kg 05/04/16 14:032.1EPA 6010
Nickel 1.5J mg/kg 05/04/16 14:032.1EPA 6010
Vanadium 4.6 mg/kg 05/04/16 14:032.1EPA 6010
Zinc 28.8 mg/kg 05/04/16 14:034.3EPA 6010
Percent Moisture 17.6 %05/02/16 06:420.10ASTM D2974-87
92295599004 8807-SS4
Arsenic 2.2J mg/kg 05/04/16 14:063.4EPA 6010
Barium 44.9 mg/kg 05/04/16 14:061.7EPA 6010
Beryllium 0.48 mg/kg 05/04/16 14:060.34EPA 6010
Chromium 1.4J mg/kg 05/04/16 14:061.7EPA 6010
Cobalt 1.3J mg/kg 05/04/16 14:061.7EPA 6010
Copper 1.8 mg/kg 05/04/16 14:061.7EPA 6010
Lead 12.5 mg/kg 05/04/16 14:061.7EPA 6010
Nickel 1.5J mg/kg 05/04/16 14:061.7EPA 6010
Vanadium 4.3 mg/kg 05/04/16 14:061.7EPA 6010
Zinc 55.5 mg/kg 05/04/16 14:063.4EPA 6010
Percent Moisture 11.2 %05/02/16 06:430.10ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92295599
TRANSYLVANIA SOIL SAMPLES
Sample:8807-SS1 Lab ID:92295599001 Collected:04/28/16 10:13 Received:04/28/16 13:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Antimony ND mg/kg 05/03/16 17:51 7440-36-005/03/16 08:300.35 0.27 1
Arsenic 1.1 mg/kg 05/03/16 17:51 7440-38-205/03/16 08:300.69 0.35 1
Barium 34.6 mg/kg 05/03/16 17:51 7440-39-305/03/16 08:300.35 0.17 1
Beryllium 0.34 mg/kg 05/03/16 17:51 7440-41-705/03/16 08:300.069 0.035 1
Cadmium ND mg/kg 05/03/16 17:51 7440-43-905/03/16 08:300.069 0.035 1
Chromium 1.1 mg/kg 05/03/16 17:51 7440-47-305/03/16 08:300.35 0.17 1
Cobalt 1.1 mg/kg 05/03/16 17:51 7440-48-405/03/16 08:300.35 0.17 1
Copper 0.98 mg/kg 05/03/16 17:51 7440-50-805/03/16 08:300.35 0.17 1
Lead 13.1 mg/kg 05/03/16 17:51 7439-92-105/03/16 08:300.35 0.17 1
Nickel 1.1 mg/kg 05/03/16 17:51 7440-02-005/03/16 08:300.35 0.17 1
Selenium ND mg/kg 05/03/16 17:51 7782-49-205/03/16 08:300.69 0.35 1
Silver ND mg/kg 05/03/16 17:51 7440-22-405/03/16 08:300.35 0.17 1
Thallium ND mg/kg 05/03/16 17:51 7440-28-005/03/16 08:300.69 0.35 1
Vanadium 3.0 mg/kg 05/03/16 17:51 7440-62-205/03/16 08:300.35 0.17 1
Zinc 29.8 mg/kg 05/03/16 17:51 7440-66-605/03/16 08:300.69 0.35 1
Analytical Method: EPA 82608260/5035A Volatile Organics
Acetone 33.9J ug/kg 04/29/16 14:30 67-64-1 M145.2 4.5 1
Acrylonitrile ND ug/kg 04/29/16 14:30 107-13-145.2 11.7 1
Benzene ND ug/kg 04/29/16 14:30 71-43-22.3 0.72 1
Bromochloromethane ND ug/kg 04/29/16 14:30 74-97-52.3 0.77 1
Bromodichloromethane ND ug/kg 04/29/16 14:30 75-27-42.3 0.86 1
Bromoform ND ug/kg 04/29/16 14:30 75-25-22.3 1.0 1
Bromomethane ND ug/kg 04/29/16 14:30 74-83-94.5 1.1 1
2-Butanone (MEK)ND ug/kg 04/29/16 14:30 78-93-345.2 1.3 1
Carbon disulfide ND ug/kg 04/29/16 14:30 75-15-04.5 1.4 1
Carbon tetrachloride ND ug/kg 04/29/16 14:30 56-23-52.3 1.2 1
Chlorobenzene ND ug/kg 04/29/16 14:30 108-90-72.3 0.86 1
Chloroethane ND ug/kg 04/29/16 14:30 75-00-34.5 1.1 1
Chloroform ND ug/kg 04/29/16 14:30 67-66-32.3 0.72 1
Chloromethane ND ug/kg 04/29/16 14:30 74-87-34.5 1.1 1
1,2-Dibromo-3-chloropropane ND ug/kg 04/29/16 14:30 96-12-82.3 1.6 1
Dibromochloromethane ND ug/kg 04/29/16 14:30 124-48-12.3 0.81 1
1,2-Dibromoethane (EDB)ND ug/kg 04/29/16 14:30 106-93-42.3 0.81 1
Dibromomethane ND ug/kg 04/29/16 14:30 74-95-32.3 1.1 1
1,2-Dichlorobenzene ND ug/kg 04/29/16 14:30 95-50-1 M12.3 0.86 1
1,4-Dichlorobenzene ND ug/kg 04/29/16 14:30 106-46-7 M12.3 0.77 1
trans-1,4-Dichloro-2-butene ND ug/kg 04/29/16 14:30 110-57-62.3 1.6 1
1,1-Dichloroethane ND ug/kg 04/29/16 14:30 75-34-32.3 0.68 1
1,2-Dichloroethane ND ug/kg 04/29/16 14:30 107-06-22.3 0.99 1
1,1-Dichloroethene ND ug/kg 04/29/16 14:30 75-35-42.3 0.81 1
cis-1,2-Dichloroethene ND ug/kg 04/29/16 14:30 156-59-22.3 0.63 1
trans-1,2-Dichloroethene ND ug/kg 04/29/16 14:30 156-60-52.3 0.86 1
1,2-Dichloropropane ND ug/kg 04/29/16 14:30 78-87-52.3 0.77 1
cis-1,3-Dichloropropene ND ug/kg 04/29/16 14:30 10061-01-52.3 0.81 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/05/2016 04:43 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92295599
TRANSYLVANIA SOIL SAMPLES
Sample:8807-SS1 Lab ID:92295599001 Collected:04/28/16 10:13 Received:04/28/16 13:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260/5035A Volatile Organics
trans-1,3-Dichloropropene ND ug/kg 04/29/16 14:30 10061-02-62.3 0.68 1
Ethylbenzene ND ug/kg 04/29/16 14:30 100-41-42.3 0.81 1
2-Hexanone ND ug/kg 04/29/16 14:30 591-78-6 M122.6 1.8 1
Iodomethane ND ug/kg 04/29/16 14:30 74-88-44.5 4.5 1
Methylene Chloride ND ug/kg 04/29/16 14:30 75-09-29.0 1.4 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 04/29/16 14:30 108-10-122.6 1.7 1
Styrene ND ug/kg 04/29/16 14:30 100-42-5 M12.3 0.81 1
1,1,1,2-Tetrachloroethane ND ug/kg 04/29/16 14:30 630-20-62.3 0.95 1
1,1,2,2-Tetrachloroethane ND ug/kg 04/29/16 14:30 79-34-52.3 0.86 1
Tetrachloroethene ND ug/kg 04/29/16 14:30 127-18-42.3 0.77 1
Toluene 2.9 ug/kg 04/29/16 14:30 108-88-32.3 0.81 1
1,1,1-Trichloroethane ND ug/kg 04/29/16 14:30 71-55-62.3 0.81 1
1,1,2-Trichloroethane ND ug/kg 04/29/16 14:30 79-00-52.3 0.95 1
Trichloroethene ND ug/kg 04/29/16 14:30 79-01-62.3 0.95 1
Trichlorofluoromethane ND ug/kg 04/29/16 14:30 75-69-42.3 0.99 1
1,2,3-Trichloropropane ND ug/kg 04/29/16 14:30 96-18-42.3 0.72 1
Vinyl acetate ND ug/kg 04/29/16 14:30 108-05-422.6 4.0 1
Vinyl chloride ND ug/kg 04/29/16 14:30 75-01-44.5 0.81 1
Xylene (Total)ND ug/kg 04/29/16 14:30 1330-20-74.5 1.6 1
Surrogates
Toluene-d8 (S)100 %04/29/16 14:30 2037-26-570-130 1
4-Bromofluorobenzene (S)97 %04/29/16 14:30 460-00-470-130 1
1,2-Dichloroethane-d4 (S)98 %04/29/16 14:30 17060-07-070-132 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 10 %05/02/16 06:420.10 0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/05/2016 04:43 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92295599
TRANSYLVANIA SOIL SAMPLES
Sample:8807-SS2 Lab ID:92295599002 Collected:04/28/16 10:27 Received:04/28/16 13:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Antimony ND mg/kg 05/05/16 14:20 7440-36-005/03/16 08:304.2 3.3 10
Arsenic ND mg/kg 05/05/16 14:20 7440-38-205/03/16 08:308.4 4.2 10
Barium 51.1 mg/kg 05/05/16 14:20 7440-39-305/03/16 08:304.2 2.1 10
Beryllium 0.85 mg/kg 05/05/16 14:20 7440-41-705/03/16 08:300.84 0.42 10
Cadmium ND mg/kg 05/05/16 14:20 7440-43-905/03/16 08:300.84 0.42 10
Chromium ND mg/kg 05/05/16 14:20 7440-47-305/03/16 08:304.2 2.1 10
Cobalt ND mg/kg 05/05/16 14:20 7440-48-405/03/16 08:304.2 2.1 10
Copper ND mg/kg 05/05/16 14:20 7440-50-805/03/16 08:304.2 2.1 10
Lead 10.2 mg/kg 05/05/16 14:20 7439-92-105/03/16 08:304.2 2.1 10
Nickel ND mg/kg 05/05/16 14:20 7440-02-005/03/16 08:304.2 2.1 10
Selenium ND mg/kg 05/05/16 14:20 7782-49-205/03/16 08:308.4 4.2 10
Silver ND mg/kg 05/05/16 14:20 7440-22-405/03/16 08:304.2 2.1 10
Thallium ND mg/kg 05/05/16 14:20 7440-28-005/03/16 08:308.4 4.2 10
Vanadium ND mg/kg 05/05/16 14:20 7440-62-205/03/16 08:304.2 2.1 10
Zinc 12.4 mg/kg 05/05/16 14:20 7440-66-605/03/16 08:308.4 4.2 10
Analytical Method: EPA 82608260/5035A Volatile Organics
Acetone ND ug/kg 04/29/16 14:50 67-64-155.8 5.6 1
Acrylonitrile ND ug/kg 04/29/16 14:50 107-13-155.8 14.5 1
Benzene ND ug/kg 04/29/16 14:50 71-43-22.8 0.89 1
Bromochloromethane ND ug/kg 04/29/16 14:50 74-97-52.8 0.95 1
Bromodichloromethane ND ug/kg 04/29/16 14:50 75-27-42.8 1.1 1
Bromoform ND ug/kg 04/29/16 14:50 75-25-22.8 1.3 1
Bromomethane ND ug/kg 04/29/16 14:50 74-83-95.6 1.4 1
2-Butanone (MEK)ND ug/kg 04/29/16 14:50 78-93-355.8 1.6 1
Carbon disulfide ND ug/kg 04/29/16 14:50 75-15-05.6 1.7 1
Carbon tetrachloride ND ug/kg 04/29/16 14:50 56-23-52.8 1.5 1
Chlorobenzene ND ug/kg 04/29/16 14:50 108-90-72.8 1.1 1
Chloroethane ND ug/kg 04/29/16 14:50 75-00-35.6 1.3 1
Chloroform ND ug/kg 04/29/16 14:50 67-66-32.8 0.89 1
Chloromethane ND ug/kg 04/29/16 14:50 74-87-35.6 1.3 1
1,2-Dibromo-3-chloropropane ND ug/kg 04/29/16 14:50 96-12-82.8 2.0 1
Dibromochloromethane ND ug/kg 04/29/16 14:50 124-48-12.8 1.0 1
1,2-Dibromoethane (EDB)ND ug/kg 04/29/16 14:50 106-93-42.8 1.0 1
Dibromomethane ND ug/kg 04/29/16 14:50 74-95-32.8 1.4 1
1,2-Dichlorobenzene ND ug/kg 04/29/16 14:50 95-50-12.8 1.1 1
1,4-Dichlorobenzene ND ug/kg 04/29/16 14:50 106-46-72.8 0.95 1
trans-1,4-Dichloro-2-butene ND ug/kg 04/29/16 14:50 110-57-62.8 2.0 1
1,1-Dichloroethane ND ug/kg 04/29/16 14:50 75-34-32.8 0.84 1
1,2-Dichloroethane ND ug/kg 04/29/16 14:50 107-06-22.8 1.2 1
1,1-Dichloroethene ND ug/kg 04/29/16 14:50 75-35-42.8 1.0 1
cis-1,2-Dichloroethene ND ug/kg 04/29/16 14:50 156-59-22.8 0.78 1
trans-1,2-Dichloroethene ND ug/kg 04/29/16 14:50 156-60-52.8 1.1 1
1,2-Dichloropropane ND ug/kg 04/29/16 14:50 78-87-52.8 0.95 1
cis-1,3-Dichloropropene ND ug/kg 04/29/16 14:50 10061-01-52.8 1.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/05/2016 04:43 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92295599
TRANSYLVANIA SOIL SAMPLES
Sample:8807-SS2 Lab ID:92295599002 Collected:04/28/16 10:27 Received:04/28/16 13:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260/5035A Volatile Organics
trans-1,3-Dichloropropene ND ug/kg 04/29/16 14:50 10061-02-62.8 0.84 1
Ethylbenzene ND ug/kg 04/29/16 14:50 100-41-42.8 1.0 1
2-Hexanone ND ug/kg 04/29/16 14:50 591-78-627.9 2.2 1
Iodomethane ND ug/kg 04/29/16 14:50 74-88-45.6 5.5 1
Methylene Chloride ND ug/kg 04/29/16 14:50 75-09-211.2 1.7 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 04/29/16 14:50 108-10-127.9 2.1 1
Styrene ND ug/kg 04/29/16 14:50 100-42-52.8 1.0 1
1,1,1,2-Tetrachloroethane ND ug/kg 04/29/16 14:50 630-20-62.8 1.2 1
1,1,2,2-Tetrachloroethane ND ug/kg 04/29/16 14:50 79-34-52.8 1.1 1
Tetrachloroethene ND ug/kg 04/29/16 14:50 127-18-42.8 0.95 1
Toluene ND ug/kg 04/29/16 14:50 108-88-32.8 1.0 1
1,1,1-Trichloroethane ND ug/kg 04/29/16 14:50 71-55-62.8 1.0 1
1,1,2-Trichloroethane ND ug/kg 04/29/16 14:50 79-00-52.8 1.2 1
Trichloroethene ND ug/kg 04/29/16 14:50 79-01-62.8 1.2 1
Trichlorofluoromethane ND ug/kg 04/29/16 14:50 75-69-42.8 1.2 1
1,2,3-Trichloropropane ND ug/kg 04/29/16 14:50 96-18-42.8 0.89 1
Vinyl acetate ND ug/kg 04/29/16 14:50 108-05-427.9 4.9 1
Vinyl chloride ND ug/kg 04/29/16 14:50 75-01-45.6 1.0 1
Xylene (Total)ND ug/kg 04/29/16 14:50 1330-20-75.6 2.0 1
Surrogates
Toluene-d8 (S)101 %04/29/16 14:50 2037-26-570-130 1
4-Bromofluorobenzene (S)96 %04/29/16 14:50 460-00-470-130 1
1,2-Dichloroethane-d4 (S)92 %04/29/16 14:50 17060-07-070-132 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 8.2 %05/02/16 06:420.10 0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/05/2016 04:43 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92295599
TRANSYLVANIA SOIL SAMPLES
Sample:8807-SS3 Lab ID:92295599003 Collected:04/28/16 10:37 Received:04/28/16 13:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Antimony ND mg/kg 05/04/16 14:03 7440-36-005/03/16 08:302.1 1.7 5
Arsenic 2.5J mg/kg 05/04/16 14:03 7440-38-205/03/16 08:304.3 2.1 5
Barium 30.9 mg/kg 05/04/16 14:03 7440-39-305/03/16 08:302.1 1.1 5
Beryllium 0.43 mg/kg 05/04/16 14:03 7440-41-705/03/16 08:300.43 0.21 5
Cadmium ND mg/kg 05/04/16 14:03 7440-43-905/03/16 08:300.43 0.21 5
Chromium 2.1J mg/kg 05/04/16 14:03 7440-47-305/03/16 08:302.1 1.1 5
Cobalt 1.1J mg/kg 05/04/16 14:03 7440-48-405/03/16 08:302.1 1.1 5
Copper 3.4 mg/kg 05/04/16 14:03 7440-50-805/03/16 08:302.1 1.1 5
Lead 11.0 mg/kg 05/04/16 14:03 7439-92-105/03/16 08:302.1 1.1 5
Nickel 1.5J mg/kg 05/04/16 14:03 7440-02-005/03/16 08:302.1 1.1 5
Selenium ND mg/kg 05/04/16 14:03 7782-49-205/03/16 08:304.3 2.1 5
Silver ND mg/kg 05/04/16 14:03 7440-22-405/03/16 08:302.1 1.1 5
Thallium ND mg/kg 05/04/16 14:03 7440-28-005/03/16 08:304.3 2.1 5
Vanadium 4.6 mg/kg 05/04/16 14:03 7440-62-205/03/16 08:302.1 1.1 5
Zinc 28.8 mg/kg 05/04/16 14:03 7440-66-605/03/16 08:304.3 2.1 5
Analytical Method: EPA 82608260/5035A Volatile Organics
Acetone ND ug/kg 04/29/16 15:10 67-64-150.9 5.1 1
Acrylonitrile ND ug/kg 04/29/16 15:10 107-13-150.9 13.2 1
Benzene ND ug/kg 04/29/16 15:10 71-43-22.5 0.81 1
Bromochloromethane ND ug/kg 04/29/16 15:10 74-97-52.5 0.87 1
Bromodichloromethane ND ug/kg 04/29/16 15:10 75-27-42.5 0.97 1
Bromoform ND ug/kg 04/29/16 15:10 75-25-22.5 1.2 1
Bromomethane ND ug/kg 04/29/16 15:10 74-83-95.1 1.3 1
2-Butanone (MEK)ND ug/kg 04/29/16 15:10 78-93-350.9 1.5 1
Carbon disulfide ND ug/kg 04/29/16 15:10 75-15-05.1 1.5 1
Carbon tetrachloride ND ug/kg 04/29/16 15:10 56-23-52.5 1.3 1
Chlorobenzene ND ug/kg 04/29/16 15:10 108-90-72.5 0.97 1
Chloroethane ND ug/kg 04/29/16 15:10 75-00-35.1 1.2 1
Chloroform ND ug/kg 04/29/16 15:10 67-66-32.5 0.81 1
Chloromethane ND ug/kg 04/29/16 15:10 74-87-35.1 1.2 1
1,2-Dibromo-3-chloropropane ND ug/kg 04/29/16 15:10 96-12-82.5 1.8 1
Dibromochloromethane ND ug/kg 04/29/16 15:10 124-48-12.5 0.92 1
1,2-Dibromoethane (EDB)ND ug/kg 04/29/16 15:10 106-93-42.5 0.92 1
Dibromomethane ND ug/kg 04/29/16 15:10 74-95-32.5 1.3 1
1,2-Dichlorobenzene ND ug/kg 04/29/16 15:10 95-50-12.5 0.97 1
1,4-Dichlorobenzene ND ug/kg 04/29/16 15:10 106-46-72.5 0.87 1
trans-1,4-Dichloro-2-butene ND ug/kg 04/29/16 15:10 110-57-62.5 1.8 1
1,1-Dichloroethane ND ug/kg 04/29/16 15:10 75-34-32.5 0.76 1
1,2-Dichloroethane ND ug/kg 04/29/16 15:10 107-06-22.5 1.1 1
1,1-Dichloroethene ND ug/kg 04/29/16 15:10 75-35-42.5 0.92 1
cis-1,2-Dichloroethene ND ug/kg 04/29/16 15:10 156-59-22.5 0.71 1
trans-1,2-Dichloroethene ND ug/kg 04/29/16 15:10 156-60-52.5 0.97 1
1,2-Dichloropropane ND ug/kg 04/29/16 15:10 78-87-52.5 0.87 1
cis-1,3-Dichloropropene ND ug/kg 04/29/16 15:10 10061-01-52.5 0.92 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/05/2016 04:43 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92295599
TRANSYLVANIA SOIL SAMPLES
Sample:8807-SS3 Lab ID:92295599003 Collected:04/28/16 10:37 Received:04/28/16 13:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260/5035A Volatile Organics
trans-1,3-Dichloropropene ND ug/kg 04/29/16 15:10 10061-02-62.5 0.76 1
Ethylbenzene ND ug/kg 04/29/16 15:10 100-41-42.5 0.92 1
2-Hexanone ND ug/kg 04/29/16 15:10 591-78-625.4 2.0 1
Iodomethane ND ug/kg 04/29/16 15:10 74-88-45.1 5.0 1
Methylene Chloride ND ug/kg 04/29/16 15:10 75-09-210.2 1.5 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 04/29/16 15:10 108-10-125.4 1.9 1
Styrene ND ug/kg 04/29/16 15:10 100-42-52.5 0.92 1
1,1,1,2-Tetrachloroethane ND ug/kg 04/29/16 15:10 630-20-62.5 1.1 1
1,1,2,2-Tetrachloroethane ND ug/kg 04/29/16 15:10 79-34-52.5 0.97 1
Tetrachloroethene ND ug/kg 04/29/16 15:10 127-18-42.5 0.87 1
Toluene ND ug/kg 04/29/16 15:10 108-88-32.5 0.92 1
1,1,1-Trichloroethane ND ug/kg 04/29/16 15:10 71-55-62.5 0.92 1
1,1,2-Trichloroethane ND ug/kg 04/29/16 15:10 79-00-52.5 1.1 1
Trichloroethene ND ug/kg 04/29/16 15:10 79-01-62.5 1.1 1
Trichlorofluoromethane ND ug/kg 04/29/16 15:10 75-69-42.5 1.1 1
1,2,3-Trichloropropane ND ug/kg 04/29/16 15:10 96-18-42.5 0.81 1
Vinyl acetate ND ug/kg 04/29/16 15:10 108-05-425.4 4.5 1
Vinyl chloride ND ug/kg 04/29/16 15:10 75-01-45.1 0.92 1
Xylene (Total)ND ug/kg 04/29/16 15:10 1330-20-75.1 1.8 1
Surrogates
Toluene-d8 (S)99 %04/29/16 15:10 2037-26-570-130 1
4-Bromofluorobenzene (S)97 %04/29/16 15:10 460-00-470-130 1
1,2-Dichloroethane-d4 (S)98 %04/29/16 15:10 17060-07-070-132 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 17.6 %05/02/16 06:420.10 0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/05/2016 04:43 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92295599
TRANSYLVANIA SOIL SAMPLES
Sample:8807-SS4 Lab ID:92295599004 Collected:04/28/16 10:43 Received:04/28/16 13:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Antimony ND mg/kg 05/04/16 14:06 7440-36-005/03/16 08:301.7 1.3 5
Arsenic 2.2J mg/kg 05/04/16 14:06 7440-38-205/03/16 08:303.4 1.7 5
Barium 44.9 mg/kg 05/04/16 14:06 7440-39-305/03/16 08:301.7 0.84 5
Beryllium 0.48 mg/kg 05/04/16 14:06 7440-41-705/03/16 08:300.34 0.17 5
Cadmium ND mg/kg 05/04/16 14:06 7440-43-905/03/16 08:300.34 0.17 5
Chromium 1.4J mg/kg 05/04/16 14:06 7440-47-305/03/16 08:301.7 0.84 5
Cobalt 1.3J mg/kg 05/04/16 14:06 7440-48-405/03/16 08:301.7 0.84 5
Copper 1.8 mg/kg 05/04/16 14:06 7440-50-805/03/16 08:301.7 0.84 5
Lead 12.5 mg/kg 05/04/16 14:06 7439-92-105/03/16 08:301.7 0.84 5
Nickel 1.5J mg/kg 05/04/16 14:06 7440-02-005/03/16 08:301.7 0.84 5
Selenium ND mg/kg 05/04/16 14:06 7782-49-205/03/16 08:303.4 1.7 5
Silver ND mg/kg 05/04/16 14:06 7440-22-405/03/16 08:301.7 0.84 5
Thallium ND mg/kg 05/04/16 14:06 7440-28-005/03/16 08:303.4 1.7 5
Vanadium 4.3 mg/kg 05/04/16 14:06 7440-62-205/03/16 08:301.7 0.84 5
Zinc 55.5 mg/kg 05/04/16 14:06 7440-66-605/03/16 08:303.4 1.7 5
Analytical Method: EPA 82608260/5035A Volatile Organics
Acetone ND ug/kg 04/29/16 15:29 67-64-182.7 8.3 1
Acrylonitrile ND ug/kg 04/29/16 15:29 107-13-182.7 21.5 1
Benzene ND ug/kg 04/29/16 15:29 71-43-24.1 1.3 1
Bromochloromethane ND ug/kg 04/29/16 15:29 74-97-54.1 1.4 1
Bromodichloromethane ND ug/kg 04/29/16 15:29 75-27-44.1 1.6 1
Bromoform ND ug/kg 04/29/16 15:29 75-25-24.1 1.9 1
Bromomethane ND ug/kg 04/29/16 15:29 74-83-98.3 2.1 1
2-Butanone (MEK)ND ug/kg 04/29/16 15:29 78-93-382.7 2.4 1
Carbon disulfide ND ug/kg 04/29/16 15:29 75-15-08.3 2.5 1
Carbon tetrachloride ND ug/kg 04/29/16 15:29 56-23-54.1 2.2 1
Chlorobenzene ND ug/kg 04/29/16 15:29 108-90-74.1 1.6 1
Chloroethane ND ug/kg 04/29/16 15:29 75-00-38.3 2.0 1
Chloroform ND ug/kg 04/29/16 15:29 67-66-34.1 1.3 1
Chloromethane ND ug/kg 04/29/16 15:29 74-87-38.3 2.0 1
1,2-Dibromo-3-chloropropane ND ug/kg 04/29/16 15:29 96-12-84.1 3.0 1
Dibromochloromethane ND ug/kg 04/29/16 15:29 124-48-14.1 1.5 1
1,2-Dibromoethane (EDB)ND ug/kg 04/29/16 15:29 106-93-44.1 1.5 1
Dibromomethane ND ug/kg 04/29/16 15:29 74-95-34.1 2.1 1
1,2-Dichlorobenzene ND ug/kg 04/29/16 15:29 95-50-14.1 1.6 1
1,4-Dichlorobenzene ND ug/kg 04/29/16 15:29 106-46-74.1 1.4 1
trans-1,4-Dichloro-2-butene ND ug/kg 04/29/16 15:29 110-57-64.1 3.0 1
1,1-Dichloroethane ND ug/kg 04/29/16 15:29 75-34-34.1 1.2 1
1,2-Dichloroethane ND ug/kg 04/29/16 15:29 107-06-24.1 1.8 1
1,1-Dichloroethene ND ug/kg 04/29/16 15:29 75-35-44.1 1.5 1
cis-1,2-Dichloroethene ND ug/kg 04/29/16 15:29 156-59-24.1 1.2 1
trans-1,2-Dichloroethene ND ug/kg 04/29/16 15:29 156-60-54.1 1.6 1
1,2-Dichloropropane ND ug/kg 04/29/16 15:29 78-87-54.1 1.4 1
cis-1,3-Dichloropropene ND ug/kg 04/29/16 15:29 10061-01-54.1 1.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/05/2016 04:43 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92295599
TRANSYLVANIA SOIL SAMPLES
Sample:8807-SS4 Lab ID:92295599004 Collected:04/28/16 10:43 Received:04/28/16 13:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260/5035A Volatile Organics
trans-1,3-Dichloropropene ND ug/kg 04/29/16 15:29 10061-02-64.1 1.2 1
Ethylbenzene ND ug/kg 04/29/16 15:29 100-41-44.1 1.5 1
2-Hexanone ND ug/kg 04/29/16 15:29 591-78-641.4 3.2 1
Iodomethane ND ug/kg 04/29/16 15:29 74-88-48.3 8.2 1
Methylene Chloride ND ug/kg 04/29/16 15:29 75-09-216.5 2.5 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 04/29/16 15:29 108-10-141.4 3.1 1
Styrene ND ug/kg 04/29/16 15:29 100-42-54.1 1.5 1
1,1,1,2-Tetrachloroethane ND ug/kg 04/29/16 15:29 630-20-64.1 1.7 1
1,1,2,2-Tetrachloroethane ND ug/kg 04/29/16 15:29 79-34-54.1 1.6 1
Tetrachloroethene ND ug/kg 04/29/16 15:29 127-18-44.1 1.4 1
Toluene ND ug/kg 04/29/16 15:29 108-88-34.1 1.5 1
1,1,1-Trichloroethane ND ug/kg 04/29/16 15:29 71-55-64.1 1.5 1
1,1,2-Trichloroethane ND ug/kg 04/29/16 15:29 79-00-54.1 1.7 1
Trichloroethene ND ug/kg 04/29/16 15:29 79-01-64.1 1.7 1
Trichlorofluoromethane ND ug/kg 04/29/16 15:29 75-69-44.1 1.8 1
1,2,3-Trichloropropane ND ug/kg 04/29/16 15:29 96-18-44.1 1.3 1
Vinyl acetate ND ug/kg 04/29/16 15:29 108-05-441.4 7.3 1
Vinyl chloride ND ug/kg 04/29/16 15:29 75-01-48.3 1.5 1
Xylene (Total)ND ug/kg 04/29/16 15:29 1330-20-78.3 3.0 1
Surrogates
Toluene-d8 (S)100 %04/29/16 15:29 2037-26-570-130 1
4-Bromofluorobenzene (S)89 %04/29/16 15:29 460-00-470-130 1
1,2-Dichloroethane-d4 (S)98 %04/29/16 15:29 17060-07-070-132 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 11.2 %05/02/16 06:430.10 0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/05/2016 04:43 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92295599
TRANSYLVANIA SOIL SAMPLES
Sample:TRIP BLANK Lab ID:92295599005 Collected:04/26/16 06:30 Received:04/28/16 13:30 Matrix:Solid
Results reported on a "wet-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260/5035A Volatile Organics
Acetone ND ug/kg 04/29/16 15:49 67-64-110010.0 1
Acrylonitrile ND ug/kg 04/29/16 15:49 107-13-110026.0 1
Benzene ND ug/kg 04/29/16 15:49 71-43-25.0 1.6 1
Bromochloromethane ND ug/kg 04/29/16 15:49 74-97-55.0 1.7 1
Bromodichloromethane ND ug/kg 04/29/16 15:49 75-27-45.0 1.9 1
Bromoform ND ug/kg 04/29/16 15:49 75-25-25.0 2.3 1
Bromomethane ND ug/kg 04/29/16 15:49 74-83-910.0 2.5 1
2-Butanone (MEK)ND ug/kg 04/29/16 15:49 78-93-31002.9 1
Carbon disulfide ND ug/kg 04/29/16 15:49 75-15-010.0 3.0 1
Carbon tetrachloride ND ug/kg 04/29/16 15:49 56-23-55.0 2.6 1
Chlorobenzene ND ug/kg 04/29/16 15:49 108-90-75.0 1.9 1
Chloroethane ND ug/kg 04/29/16 15:49 75-00-310.0 2.4 1
Chloroform ND ug/kg 04/29/16 15:49 67-66-35.0 1.6 1
Chloromethane ND ug/kg 04/29/16 15:49 74-87-310.0 2.4 1
1,2-Dibromo-3-chloropropane ND ug/kg 04/29/16 15:49 96-12-85.0 3.6 1
Dibromochloromethane ND ug/kg 04/29/16 15:49 124-48-15.0 1.8 1
1,2-Dibromoethane (EDB)ND ug/kg 04/29/16 15:49 106-93-45.0 1.8 1
Dibromomethane ND ug/kg 04/29/16 15:49 74-95-35.0 2.5 1
1,2-Dichlorobenzene ND ug/kg 04/29/16 15:49 95-50-15.0 1.9 1
1,4-Dichlorobenzene ND ug/kg 04/29/16 15:49 106-46-75.0 1.7 1
trans-1,4-Dichloro-2-butene ND ug/kg 04/29/16 15:49 110-57-65.0 3.6 1
1,1-Dichloroethane ND ug/kg 04/29/16 15:49 75-34-35.0 1.5 1
1,2-Dichloroethane ND ug/kg 04/29/16 15:49 107-06-25.0 2.2 1
1,1-Dichloroethene ND ug/kg 04/29/16 15:49 75-35-45.0 1.8 1
cis-1,2-Dichloroethene ND ug/kg 04/29/16 15:49 156-59-25.0 1.4 1
trans-1,2-Dichloroethene ND ug/kg 04/29/16 15:49 156-60-55.0 1.9 1
1,2-Dichloropropane ND ug/kg 04/29/16 15:49 78-87-55.0 1.7 1
cis-1,3-Dichloropropene ND ug/kg 04/29/16 15:49 10061-01-55.0 1.8 1
trans-1,3-Dichloropropene ND ug/kg 04/29/16 15:49 10061-02-65.0 1.5 1
Ethylbenzene ND ug/kg 04/29/16 15:49 100-41-45.0 1.8 1
2-Hexanone ND ug/kg 04/29/16 15:49 591-78-650.0 3.9 1
Iodomethane ND ug/kg 04/29/16 15:49 74-88-410.0 9.9 1
Methylene Chloride ND ug/kg 04/29/16 15:49 75-09-220.0 3.0 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 04/29/16 15:49 108-10-150.0 3.7 1
Styrene ND ug/kg 04/29/16 15:49 100-42-55.0 1.8 1
1,1,1,2-Tetrachloroethane ND ug/kg 04/29/16 15:49 630-20-65.0 2.1 1
1,1,2,2-Tetrachloroethane ND ug/kg 04/29/16 15:49 79-34-55.0 1.9 1
Tetrachloroethene ND ug/kg 04/29/16 15:49 127-18-45.0 1.7 1
Toluene ND ug/kg 04/29/16 15:49 108-88-35.0 1.8 1
1,1,1-Trichloroethane ND ug/kg 04/29/16 15:49 71-55-65.0 1.8 1
1,1,2-Trichloroethane ND ug/kg 04/29/16 15:49 79-00-55.0 2.1 1
Trichloroethene ND ug/kg 04/29/16 15:49 79-01-65.0 2.1 1
Trichlorofluoromethane ND ug/kg 04/29/16 15:49 75-69-45.0 2.2 1
1,2,3-Trichloropropane ND ug/kg 04/29/16 15:49 96-18-45.0 1.6 1
Vinyl acetate ND ug/kg 04/29/16 15:49 108-05-450.0 8.8 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/05/2016 04:43 PM
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Page 14 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92295599
TRANSYLVANIA SOIL SAMPLES
Sample:TRIP BLANK Lab ID:92295599005 Collected:04/26/16 06:30 Received:04/28/16 13:30 Matrix:Solid
Results reported on a "wet-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260/5035A Volatile Organics
Vinyl chloride ND ug/kg 04/29/16 15:49 75-01-410.0 1.8 1
Xylene (Total)ND ug/kg 04/29/16 15:49 1330-20-710.0 3.6 1
Surrogates
Toluene-d8 (S)102 %04/29/16 15:49 2037-26-570-130 1
4-Bromofluorobenzene (S)98 %04/29/16 15:49 460-00-470-130 1
1,2-Dichloroethane-d4 (S)96 %04/29/16 15:49 17060-07-070-132 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/05/2016 04:43 PM
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[phone]
Page 15 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92295599
TRANSYLVANIA SOIL SAMPLES
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/21570
EPA 3050
EPA 6010
6010 MET
Associated Lab Samples:92295599001, 92295599002, 92295599003, 92295599004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1723658
Associated Lab Samples:92295599001, 92295599002, 92295599003, 92295599004
Matrix:Solid
AnalyzedMDL
Antimony mg/kg ND 0.50 05/03/16 17:170.39
Arsenic mg/kg ND 1.0 05/03/16 17:170.50
Barium mg/kg ND 0.50 05/03/16 17:170.25
Beryllium mg/kg ND 0.10 05/03/16 17:170.050
Cadmium mg/kg ND 0.10 05/03/16 17:170.050
Chromium mg/kg ND 0.50 05/03/16 17:170.25
Cobalt mg/kg ND 0.50 05/03/16 17:170.25
Copper mg/kg ND 0.50 05/03/16 17:170.25
Lead mg/kg ND 0.50 05/03/16 17:170.25
Nickel mg/kg ND 0.50 05/03/16 17:170.25
Selenium mg/kg ND 1.0 05/03/16 17:170.50
Silver mg/kg ND 0.50 05/03/16 17:170.25
Thallium mg/kg ND 1.0 05/03/16 17:170.50
Vanadium mg/kg ND 0.50 05/03/16 17:170.25
Zinc mg/kg ND 1.0 05/03/16 17:170.50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1723659LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony mg/kg 50.850 102 80-120
Arsenic mg/kg 48.650 97 80-120
Barium mg/kg 50.650 101 80-120
Beryllium mg/kg 50.650 101 80-120
Cadmium mg/kg 50.850 102 80-120
Chromium mg/kg 50.450 101 80-120
Cobalt mg/kg 50.550 101 80-120
Copper mg/kg 50.850 102 80-120
Lead mg/kg 50.150 100 80-120
Nickel mg/kg 50.650 101 80-120
Selenium mg/kg 50.650 101 80-120
Silver mg/kg 25.425 102 80-120
Thallium mg/kg 49.850 100 80-120
Vanadium mg/kg 50.450 101 80-120
Zinc mg/kg 50.450 101 80-120
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/05/2016 04:43 PM
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Page 16 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92295599
TRANSYLVANIA SOIL SAMPLES
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1723660MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92295779008
1723661
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony mg/kg M145.3 69 75-12567 6 2044.11.2 32.7 30.9
Arsenic mg/kg 45.3 94 75-12592 5 2044.13.1 45.8 43.7
Barium mg/kg M145.3 99 75-12565 12 2044.193.3 138 122
Beryllium mg/kg 45.3 96 75-12595 4 2044.10.25 43.9 42.0
Cadmium mg/kg 45.3 97 75-12598 3 2044.10.42 44.6 43.5
Chromium mg/kg 45.3 117 75-12591 14 2044.148.0 101 88.1
Cobalt mg/kg M145.3 80 75-12573 7 2044.121.9 58.2 54.2
Copper mg/kg 45.3 105 75-12599 5 2044.138.0 85.6 81.7
Lead mg/kg M145.3 71 75-12521 7 2044.1294 326 303
Nickel mg/kg 45.3 97 75-12592 6 2044.115.0 59.1 55.5
Selenium mg/kg 45.3 91 75-12591 2 2044.1ND 41.9 40.9
Silver mg/kg 22.7 95 75-12595 3 2022.1ND 21.5 20.9
Thallium mg/kg 45.3 84 75-12584 3 2044.1ND 38.1 37.0
Vanadium mg/kg M145.3 114 75-12574 15 2044.184.0 136 117
Zinc mg/kg 45.3 95 75-12588 1 2044.1355 398 393
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/05/2016 04:43 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92295599
TRANSYLVANIA SOIL SAMPLES
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/36614
EPA 8260
EPA 8260
8260 MSV 5035A Volatile Organics
Associated Lab Samples:92295599001, 92295599002, 92295599003, 92295599004, 92295599005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1722665
Associated Lab Samples:92295599001, 92295599002, 92295599003, 92295599004, 92295599005
Matrix:Solid
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/kg ND 5.1 04/29/16 12:022.2
1,1,1-Trichloroethane ug/kg ND 5.1 04/29/16 12:021.9
1,1,2,2-Tetrachloroethane ug/kg ND 5.1 04/29/16 12:022.0
1,1,2-Trichloroethane ug/kg ND 5.1 04/29/16 12:022.2
1,1-Dichloroethane ug/kg ND 5.1 04/29/16 12:021.5
1,1-Dichloroethene ug/kg ND 5.1 04/29/16 12:021.9
1,2,3-Trichloropropane ug/kg ND 5.1 04/29/16 12:021.6
1,2-Dibromo-3-chloropropane ug/kg ND 5.1 04/29/16 12:023.7
1,2-Dibromoethane (EDB)ug/kg ND 5.1 04/29/16 12:021.9
1,2-Dichlorobenzene ug/kg ND 5.1 04/29/16 12:022.0
1,2-Dichloroethane ug/kg ND 5.1 04/29/16 12:022.3
1,2-Dichloropropane ug/kg ND 5.1 04/29/16 12:021.7
1,4-Dichlorobenzene ug/kg ND 5.1 04/29/16 12:021.7
2-Butanone (MEK)ug/kg ND 103 04/29/16 12:023.0
2-Hexanone ug/kg ND 51.4 04/29/16 12:024.0
4-Methyl-2-pentanone (MIBK)ug/kg ND 51.4 04/29/16 12:023.8
Acetone ug/kg ND 103 04/29/16 12:0210.3
Acrylonitrile ug/kg ND 103 04/29/16 12:0226.7
Benzene ug/kg ND 5.1 04/29/16 12:021.6
Bromochloromethane ug/kg ND 5.1 04/29/16 12:021.7
Bromodichloromethane ug/kg ND 5.1 04/29/16 12:022.0
Bromoform ug/kg ND 5.1 04/29/16 12:022.4
Bromomethane ug/kg ND 10.3 04/29/16 12:022.6
Carbon disulfide ug/kg ND 10.3 04/29/16 12:023.1
Carbon tetrachloride ug/kg ND 5.1 04/29/16 12:022.7
Chlorobenzene ug/kg ND 5.1 04/29/16 12:022.0
Chloroethane ug/kg ND 10.3 04/29/16 12:022.5
Chloroform ug/kg ND 5.1 04/29/16 12:021.6
Chloromethane ug/kg ND 10.3 04/29/16 12:022.5
cis-1,2-Dichloroethene ug/kg ND 5.1 04/29/16 12:021.4
cis-1,3-Dichloropropene ug/kg ND 5.1 04/29/16 12:021.9
Dibromochloromethane ug/kg ND 5.1 04/29/16 12:021.9
Dibromomethane ug/kg ND 5.1 04/29/16 12:022.6
Ethylbenzene ug/kg ND 5.1 04/29/16 12:021.9
Iodomethane ug/kg ND 10.3 04/29/16 12:0210.2
Methylene Chloride ug/kg ND 20.6 04/29/16 12:023.1
Styrene ug/kg ND 5.1 04/29/16 12:021.9
Tetrachloroethene ug/kg ND 5.1 04/29/16 12:021.7
Toluene ug/kg ND 5.1 04/29/16 12:021.9
trans-1,2-Dichloroethene ug/kg ND 5.1 04/29/16 12:022.0
trans-1,3-Dichloropropene ug/kg ND 5.1 04/29/16 12:021.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/05/2016 04:43 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92295599
TRANSYLVANIA SOIL SAMPLES
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1722665
Associated Lab Samples:92295599001, 92295599002, 92295599003, 92295599004, 92295599005
Matrix:Solid
AnalyzedMDL
trans-1,4-Dichloro-2-butene ug/kg ND 5.1 04/29/16 12:023.7
Trichloroethene ug/kg ND 5.1 04/29/16 12:022.2
Trichlorofluoromethane ug/kg ND 5.1 04/29/16 12:022.3
Vinyl acetate ug/kg ND 51.4 04/29/16 12:029.1
Vinyl chloride ug/kg ND 10.3 04/29/16 12:021.9
Xylene (Total)ug/kg ND 10.3 04/29/16 12:023.7
1,2-Dichloroethane-d4 (S)%92 70-132 04/29/16 12:02
4-Bromofluorobenzene (S)%96 70-130 04/29/16 12:02
Toluene-d8 (S)%100 70-130 04/29/16 12:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1722666LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/kg 58.064.8 90 74-137
1,1,1-Trichloroethane ug/kg 56.864.8 88 67-140
1,1,2,2-Tetrachloroethane ug/kg 56.364.8 87 72-141
1,1,2-Trichloroethane ug/kg 60.164.8 93 78-138
1,1-Dichloroethane ug/kg 56.464.8 87 69-134
1,1-Dichloroethene ug/kg 56.964.8 88 67-138
1,2,3-Trichloropropane ug/kg 59.664.8 92 69-144
1,2-Dibromo-3-chloropropane ug/kg 60.464.8 93 65-140
1,2-Dibromoethane (EDB)ug/kg 59.264.8 91 77-135
1,2-Dichlorobenzene ug/kg 62.164.8 96 77-141
1,2-Dichloroethane ug/kg 54.164.8 84 65-137
1,2-Dichloropropane ug/kg 60.064.8 93 72-136
1,4-Dichlorobenzene ug/kg 62.564.8 97 76-138
2-Butanone (MEK)ug/kg 113J130 87 58-147
2-Hexanone ug/kg 125130 97 62-145
4-Methyl-2-pentanone (MIBK)ug/kg 126130 97 64-149
Acetone ug/kg 100J130 77 53-153
Acrylonitrile ug/kg 288324 89 56-153
Benzene ug/kg 59.864.8 92 73-135
Bromochloromethane ug/kg 60.864.8 94 73-134
Bromodichloromethane ug/kg 59.164.8 91 71-135
Bromoform ug/kg 58.764.8 91 66-141
Bromomethane ug/kg 68.664.8 106 53-160
Carbon disulfide ug/kg 61.764.8 95 63-140
Carbon tetrachloride ug/kg 57.564.8 89 60-145
Chlorobenzene ug/kg 57.364.8 88 78-130
Chloroethane ug/kg 60.864.8 94 64-149
Chloroform ug/kg 55.564.8 86 70-134
Chloromethane ug/kg 58.864.8 91 52-150
cis-1,2-Dichloroethene ug/kg 56.064.8 87 70-133
cis-1,3-Dichloropropene ug/kg 60.364.8 93 68-134
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/05/2016 04:43 PM
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Page 19 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92295599
TRANSYLVANIA SOIL SAMPLES
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1722666LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromochloromethane ug/kg 59.264.8 91 71-138
Dibromomethane ug/kg 58.364.8 90 74-130
Ethylbenzene ug/kg 57.864.8 89 75-133
Iodomethane ug/kg 129130 100 69-144
Methylene Chloride ug/kg 56.664.8 87 45-154
Styrene ug/kg 59.564.8 92 79-137
Tetrachloroethene ug/kg 52.964.8 82 71-138
Toluene ug/kg 60.364.8 93 74-131
trans-1,2-Dichloroethene ug/kg 56.764.8 88 67-135
trans-1,3-Dichloropropene ug/kg 59.664.8 92 65-146
trans-1,4-Dichloro-2-butene ug/kg 56.564.8 87 70-130
Trichloroethene ug/kg 60.364.8 93 67-135
Trichlorofluoromethane ug/kg 51.364.8 79 59-144
Vinyl acetate ug/kg 85.1 F31306640-160
Vinyl chloride ug/kg 60.764.8 94 56-141
Xylene (Total)ug/kg 172194 88 76-137
1,2-Dichloroethane-d4 (S)%91 70-132
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1722949MATRIX SPIKE SAMPLE:
MSSpike
Result
92295599001
1,1,1,2-Tetrachloroethane ug/kg 8.610.8 80 70-130ND
1,1,1-Trichloroethane ug/kg 9.410.8 87 70-130ND
1,1,2,2-Tetrachloroethane ug/kg 8.710.8 81 70-130ND
1,1,2-Trichloroethane ug/kg 10.210.8 95 70-130ND
1,1-Dichloroethane ug/kg 9.210.8 86 70-130ND
1,1-Dichloroethene ug/kg 9.510.8 89 49-180ND
1,2,3-Trichloropropane ug/kg 10.310.8 96 70-130ND
1,2-Dibromo-3-chloropropane ug/kg 10.310.8 96 70-130ND
1,2-Dibromoethane (EDB)ug/kg 9.810.8 91 70-130ND
1,2-Dichlorobenzene ug/kg 6.3 M110.8 59 70-130ND
1,2-Dichloroethane ug/kg 10.110.8 94 70-130ND
1,2-Dichloropropane ug/kg 9.810.8 92 70-130ND
1,4-Dichlorobenzene ug/kg 6.6 M110.8 61 70-130ND
2-Butanone (MEK)ug/kg 27.1J21.4 126 70-130ND
2-Hexanone ug/kg 52.2 M121.4 243 70-130ND
4-Methyl-2-pentanone (MIBK)ug/kg 25.6J21.4 120 70-130ND
Acetone ug/kg 74.5 M121.4 189 70-13033.9J
Acrylonitrile ug/kg 54.153.6 101 70-130ND
Benzene ug/kg 9.710.8 91 50-166ND
Bromochloromethane ug/kg 10.810.8 101 70-130ND
Bromodichloromethane ug/kg 9.310.8 86 70-130ND
Bromoform ug/kg 8.110.8 76 70-130ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/05/2016 04:43 PM
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Huntersville, NC 28078
[phone]
Page 20 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92295599
TRANSYLVANIA SOIL SAMPLES
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1722949MATRIX SPIKE SAMPLE:
MSSpike
Result
92295599001
Bromomethane ug/kg 12.910.8 120 70-130ND
Carbon disulfide ug/kg 9.910.8 93 70-130ND
Carbon tetrachloride ug/kg 8.710.8 81 70-130ND
Chlorobenzene ug/kg 8.110.8 75 43-169ND
Chloroethane ug/kg 10.610.8 99 70-130ND
Chloroform ug/kg 9.610.8 90 70-130ND
Chloromethane ug/kg 9.510.8 88 70-130ND
cis-1,2-Dichloroethene ug/kg 9.110.8 84 70-130ND
cis-1,3-Dichloropropene ug/kg 9.010.8 84 70-130ND
Dibromochloromethane ug/kg 9.210.8 86 70-130ND
Dibromomethane ug/kg 10.510.8 98 70-130ND
Ethylbenzene ug/kg 8.710.8 81 70-130ND
Iodomethane ug/kg 21.321.4 99 70-130ND
Methylene Chloride ug/kg 11.810.8 104 70-130ND
Styrene ug/kg 6.6 M110.8 62 70-130ND
Tetrachloroethene ug/kg 7.910.8 74 70-130ND
Toluene ug/kg 16.610.8 128 52-1632.9
trans-1,2-Dichloroethene ug/kg 9.310.8 87 70-130ND
trans-1,3-Dichloropropene ug/kg 8.710.8 81 70-130ND
trans-1,4-Dichloro-2-butene ug/kg 9.210.8 86 70-130ND
Trichloroethene ug/kg 9.110.8 85 49-167ND
Trichlorofluoromethane ug/kg 8.510.8 79 70-130ND
Vinyl acetate ug/kg 20.1J21.4 94 70-130ND
Vinyl chloride ug/kg 10.310.8 96 70-130ND
1,2-Dichloroethane-d4 (S)%104 70-132
4-Bromofluorobenzene (S)%92 70-130
Toluene-d8 (S)%97 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92295660001
1722948SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/kg ND 30ND
1,1,1-Trichloroethane ug/kg ND 30ND
1,1,2,2-Tetrachloroethane ug/kg ND 30ND
1,1,2-Trichloroethane ug/kg ND 30ND
1,1-Dichloroethane ug/kg ND 30ND
1,1-Dichloroethene ug/kg ND 30ND
1,2,3-Trichloropropane ug/kg ND 30ND
1,2-Dibromo-3-chloropropane ug/kg ND 30ND
1,2-Dibromoethane (EDB)ug/kg ND 30ND
1,2-Dichlorobenzene ug/kg ND 30ND
1,2-Dichloroethane ug/kg ND 30ND
1,2-Dichloropropane ug/kg ND 30ND
1,4-Dichlorobenzene ug/kg ND 30ND
2-Butanone (MEK)ug/kg ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/05/2016 04:43 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92295599
TRANSYLVANIA SOIL SAMPLES
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92295660001
1722948SAMPLE DUPLICATE:
2-Hexanone ug/kg ND 30ND
4-Methyl-2-pentanone (MIBK)ug/kg ND 30ND
Acetone ug/kg ND 30ND
Acrylonitrile ug/kg ND 30ND
Benzene ug/kg ND 30ND
Bromochloromethane ug/kg ND 30ND
Bromodichloromethane ug/kg ND 30ND
Bromoform ug/kg ND 30ND
Bromomethane ug/kg ND 30ND
Carbon disulfide ug/kg ND 30ND
Carbon tetrachloride ug/kg ND 30ND
Chlorobenzene ug/kg ND 30ND
Chloroethane ug/kg ND 30ND
Chloroform ug/kg ND 30ND
Chloromethane ug/kg ND 30ND
cis-1,2-Dichloroethene ug/kg ND 30ND
cis-1,3-Dichloropropene ug/kg ND 30ND
Dibromochloromethane ug/kg ND 30ND
Dibromomethane ug/kg ND 30ND
Ethylbenzene ug/kg ND 30ND
Iodomethane ug/kg ND 30ND
Methylene Chloride ug/kg ND 30ND
Styrene ug/kg ND 30ND
Tetrachloroethene ug/kg ND 30ND
Toluene ug/kg ND 30ND
trans-1,2-Dichloroethene ug/kg ND 30ND
trans-1,3-Dichloropropene ug/kg ND 30ND
trans-1,4-Dichloro-2-butene ug/kg ND 30ND
Trichloroethene ug/kg ND 30ND
Trichlorofluoromethane ug/kg ND 30ND
Vinyl acetate ug/kg ND 30ND
Vinyl chloride ug/kg ND 30ND
Xylene (Total)ug/kg ND 30ND
1,2-Dichloroethane-d4 (S)%112 393
4-Bromofluorobenzene (S)%100 1398
Toluene-d8 (S)%101 15100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/05/2016 04:43 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92295599
TRANSYLVANIA SOIL SAMPLES
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
PMST/9017
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples:92295599001, 92295599002, 92295599003, 92295599004
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92295649001
1723202SAMPLE DUPLICATE:
Percent Moisture %14.0 11 2515.6
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92295547001
1723203SAMPLE DUPLICATE:
Percent Moisture %22.8 8 2521.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/05/2016 04:43 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 27
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92295599
TRANSYLVANIA SOIL SAMPLES
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
The recovery of the second source standard used to verify the initial calibration curve for this analyte is outside the
laboratory's control limits. The result is estimated.F3
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/05/2016 04:43 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 27
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92295599
TRANSYLVANIA SOIL SAMPLES
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92295599001 MPRP/21570 ICP/193708807-SS1 EPA 3050 EPA 6010
92295599002 MPRP/21570 ICP/193708807-SS2 EPA 3050 EPA 6010
92295599003 MPRP/21570 ICP/193708807-SS3 EPA 3050 EPA 6010
92295599004 MPRP/21570 ICP/193708807-SS4 EPA 3050 EPA 6010
92295599001 MSV/366148807-SS1 EPA 8260
92295599002 MSV/366148807-SS2 EPA 8260
92295599003 MSV/366148807-SS3 EPA 8260
92295599004 MSV/366148807-SS4 EPA 8260
92295599005 MSV/36614TRIP BLANK EPA 8260
92295599001 PMST/90178807-SS1 ASTM D2974-87
92295599002 PMST/90178807-SS2 ASTM D2974-87
92295599003 PMST/90178807-SS3 ASTM D2974-87
92295599004 PMST/90178807-SS4 ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/05/2016 04:43 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 27
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