9214_HollySpringsCDLF_SoilAssessmentReport_DIN26156_20160525

2211 West Meadowview Rd.
Boone Building, Suite 101
Greensboro, NC 27407
tel: [phone]
fax: [phone]
www.JoyceEngineering.com

May 25, 2016

Matt Einsmann, P.E.
Environmental Manager
Republic Services
5111 Chin Page Road
Durham, NC 27703

Re: Surface Water and Soil Assessment Report
BFI-Holly Springs Disposal, Inc.; Permit No. 9214-CDLF-1993.
JOYCE Project No. 895.1602.12, Task No. 02

Dear Mr. Einsmann:

Joyce Engineering (JOYCE) presents this report on the results of surface water and soil sampling
conducted at the Holly Springs closed C&D landfill, Permit # 9214-CDLF-1993. The surface water
and soil sampling were in response to an Inspection Report issued by the North Carolina
Department of Environmental Quality (DEQ) on March 7, 2016. Two North Carolina
Environmental Monitoring Reporting Forms (EMRFs), one for the surface water sampling data and
one for the soil sampling data, are attached.

BACKGROUND
The Holly Springs Landfill is located at 4300 Old Holly Springs-Apex Road in Holly
Springs, North Carolina. The facility is a closed C&D landfill which stopped receiving waste in
December 2006, and closure certification was completed in January 2012. On March 1, 2016,
Republic contacted the North Carolina Department of Environmental Quality (NCDEQ), Division
of Waste Management (DWM), Solid Waste Section (SWS) to self-report an area of erosion and
soil discoloration in the northwest section of Cell 7, near the perimeter stormwater ditch. DWM
conducted an inspection on March 7, 2016, and issued an Inspection Report, which described the
area of erosion and soil discoloration.

The Inspection Report called for sampling of the soil and surface water in the vicinity of the
area of soil discoloration and erosion and requested a sampling plan be submitted to the SWS.
Surface water sampling was conducted on March 7, 2016. A Soil Assessment Plan (SAP) was
submitted to the NCDEQ on April 21, 2016, and the SAP was approved by the NCDEQ in a letter
dated April 22, 2016.

Mr. Matt Einsmann
May 25, 2016
Page 2 of 4

SURFACE WATER SAMPLING
JOYCE mobilized to the Holly Springs Landfill site on March 7, 2016, to collect surface water
samples from the creek that traverses the north side of the closed landfill. The creek runs between
two of the closed waste cells (Cells 6 and 7) and flows toward the west. The weather was sunny
and in the mid-60’s. The creek was within its normal channel and was flowing slowly. There was
significant leaf and other vegetative debris in the creek. There was no discharge to the creek from
the sediment trap on the perimeter stormwater ditch.

Three surface water samples, SW-2, SW-A, and SW-B, were collected from the locations shown on
Figure 1. The sampling order was upstream (SW-2) to downstream (SW-A and SW-B). SW-2 was
collected from a location upstream of the confluence of the outlet channel from the sediment trap
and the creek. The SW-2 location also serves as a routine monitoring point for the facility and is
sampled semiannually as part of the water quality monitoring program. SW-A was collected from a
location downstream of the confluence of the outlet channel from the sediment trap and the creek,
and SW-B was collected farther downstream near the fence that marks the facility property
boundary. A field blank consisting of laboratory-provided distilled water was also collected, and a
laboratory-prepared trip blank accompanied the samples.

The samples were collected directly from the flowing creek using laboratory-prepared sample
bottles in accordance with standard surface water sampling protocols. The samples were placed
immediately into a cooler with ice after collection. After collecting water samples, field parameters
were measured by placing the probes directly into the flowing water at each location. Field
parameters included pH, temperature, conductivity, turbidity, dissolved oxygen, and oxidation-
reduction potential (ORP). The field parameter data were recorded in the field logbook and on
surface water sampling log forms. The field log forms are included in Attachments A.

The samples were shipped under chain-of-custody control to Analytical Services, Inc. (ASI) for
analysis. The laboratory reported that the samples arrived in good condition, at proper temperature,
and within required hold times. The samples and the field blank were analyzed for the 40 CFR Part
258 Appendix I list of constituents, including volatile organic compounds (VOCs) and metals. The
trip blank was analyzed for Appendix I VOCs. The surface water samples were also analyzed for
the following water quality indicator parameters: alkalinity (as CaCO3), ammonia (as N), biological
oxygen demand (BOD), total phosphorus, chloride, and sulfate.

The laboratory analytical report was received on March 25, 2016, and is included in Attachment A.
Table 1 summarizes the detected constituents and indicator parameters for the three surface water
samples and compares them to the North Carolina Surface Water Standards found in 15A NCAC
2B (the NC2B standards). The NC2B standards for both fresh water aquatic life and human health
are included in Table 1.

One VOC, acetone (a common laboratory contaminant), was detected in all three samples at
estimated concentrations below the solid waste section reporting limit (SWSL). Acetone was not
detected in the blanks; however, the fact that it was detected both upstream and downstream of the
Mr. Matt Einsmann
May 25, 2016
Page 3 of 4

stained soil area suggests the possibility of laboratory or field contamination, or at least that it is not
related to the stained soil area.

Several metals, including arsenic, barium, chromium, lead, mercury, and selenium were detected in
one or more of the samples; however, all detections were estimated concentrations below the
SWSL. The indicator parameter results were generally consistent with moderately clean surface
water and did not indicate any major impairment. There was no significant difference in water
quality or constituent concentrations between the upstream (SW-2) and downstream (SW-A and
SW-B) samples. There were no quantified exceedances of any listed NC2B standards.

SOIL SAMPLING
JOYCE collected four soil samples in accordance with the approved SAP on April 26, 2016. Soil
samples were collected from three locations (SS-1, SS-2, and SS-3) near and
downgradient/downslope from the area of observed soil staining. In addition, JOYCE collected one
soil sample from an upgradient location (BG) to represent background soil conditions. The attached
Figure 1 shows the locations of the four soil samples, as well as the approximate flow path for
surface runoff in the perimeter ditch, through the sediment trap, and then down toward the creek.
SS-1 was collected from the bottom of the perimeter ditch at the nearest accessible spot
downgradient of the stained soil. SS-2 was collected from perimeter ditch about 50 feet
downgradient of SS-1, near the sedimentation trap. SS-3 was collected below the sedimentation
trap. At each of the four locations, JOYCE collected samples from a depth of approximately 12 to
24 inches below the ground surface.

All sampling was conducted by a licensed professional geologist. The soil samples were collected
using a stainless-steel hand auger. The sampling equipment was decontaminated before sampling
and between samples using standard decontamination procedures as described in the SAP. The
background sample (BG) was collected first, and then samples SS-3, SS-2, and SS-1, in that order.
The samples were placed in laboratory-prepared containers and put immediately into a cooler with
ice for transport to the laboratory.

The samples were transported under chain-of-custody control to Pace Analytical Services, Inc., in
Huntersville, North Carolina for analysis. The soil samples were analyzed for the NC Appendix I
list of solid waste constituents, including total metals by EPA Method 6010, and volatile organic
compounds (VOCs) by EPA Method 5035/8260, as well as for laboratory pH. The complete
laboratory analytical report and chain of custody are included as Attachment B.

Table 2 summarizes the analytical results for the soil samples and includes the Preliminary Soil
Remediation Goals (PSRGs) from the NCDEQ Inactive Hazardous Sites Branch. The soil
analytical results were compared to both the Industrial Health-based PSRG and the Protection of
Groundwater PSRG. Three VOCs (acetone, methylene chloride, and toluene) were detected in one
or more of the soil samples; however, none were in exceedance of the PSRGs. Acetone and
methylene chloride (common laboratory contaminants) were detected in the upgradient background
sample (BG) at similar concentrations as in the downgradient samples; therefore, we attribute them
Mr. Matt Einsmann
May 25, 2016
Page 4 of 4

to laboratory contamination. Toluene was detected at a low quantified concentration in SS-2;
however, it was orders of magnitude below either PSRG.

Three metals (arsenic, cobalt, and vanadium) were detected at concentrations above the lowest
PSRG in one or more of the downgradient soil samples; however, these three metals were also
detected in the background sample (BG), and cobalt and vanadium exceeded a PSRG in the
background sample (BG). All of the metals detections are within the range of concentrations that
occur naturally in the mineralogy of the North Carolina Piedmont soils (Reid, 1993).

The pH of the soil samples ranged from 5.0 to 8.0. The most acidic soil was the background
sample, and the most basic soil was SS-2. It is notable that the pH of SS-1, the sample nearest the
observed staining, was 7.2, essentially neutral. These pH values are with the normal range for
North Carolina Piedmont soils.

CONCLUSIONS
The results of surface water sampling did not indicate any impact to the surface water down stream
of the area of stained soil and erosion noted in the March 2016 NCDEQ Inspection Report. The
results of the Soil Assessment found only a few low-level VOC detections, most of which could be
due to laboratory contamination. No VOCs were detected above the PSRGs and metal detections
were comparable to naturally occurring minerals in piedmont soils. We recommend no further
action with regard to this incident. Please feel free to contact me at [phone] if you have any
questions or comments.

Respectfully,
JOYCE ENGINEERING

Van Burbach, Ph.D., P.G.
Senior Technical Consultant

Attachments: EMRF for Surface Water Samples (March 2016)
EMRF for Soil Samples (April 2016)
Figure 1 – Soil and Surface Water Sample Locations
Table 1 – Detected Constituents and Parameters in Surface Water Samples
Table 2 – Soil Analytical Results
Attachment A – Surface Water Sampling Logs and Laboratory Report
Attachment B – Soil Sampling Laboratory Report

Reference: Reid, Jeffery C. A Geochemical Atlas of North Carolina. North Carolina
Geological Survey, Bulletin 93. Raleigh, NC. 1993.

EMRFs

Figure

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(FEET)
GRAPHIC SCALE
804020

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-
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4
Joyce Engineering
SAMPLE ID PARAMETER RESULT UNITS SAMPLE DATE PSRG-IH PSRG-GW
BG Arsenic 1.2 mg/kg 4/26/2016 3.0 5.8
SS-1 Arsenic 3.9 mg/kg 4/26/2016 3.0 5.8
SS-2 Arsenic 3.0 mg/kg 4/26/2016 3.0 5.8
SS-3 Arsenic 9.1 mg/kg 4/26/2016 3.0 5.8
BG Barium 15.8 mg/kg 4/26/2016 44,000 580
SS-1 Barium 123 mg/kg 4/26/2016 44,000 580
SS-2 Barium 23.8 mg/kg 4/26/2016 44,000 580
SS-3 Barium 28.8 mg/kg 4/26/2016 44,000 580
BG Beryllium 0.10 mg/kg 4/26/2016 460 63
SS-1 Beryllium 0.25 mg/kg 4/26/2016 460 63
SS-2 Beryllium 0.14 mg/kg 4/26/2016 460 63
SS-3 Beryllium 0.48 mg/kg 4/26/2016 460 63
BG Chromium 3.1 mg/kg 4/26/2016 100,000 360,000
SS-1 Chromium 8.8 mg/kg 4/26/2016 100,000 360,000
SS-2 Chromium 5.1 mg/kg 4/26/2016 100,000 360,000
SS-3 Chromium 2.8 mg/kg 4/26/2016 100,000 360,000
BG Cobalt 1.4 mg/kg 4/26/2016 70 0.90
SS-1 Cobalt 4.4 mg/kg 4/26/2016 70 0.90
SS-2 Cobalt 2.5 mg/kg 4/26/2016 70 0.90
SS-3 Cobalt 2.0 mg/kg 4/26/2016 70 0.90
BG Copper 1.3 mg/kg 4/26/2016 9,400 700
SS-1 Copper 8.0 mg/kg 4/26/2016 9,400 700
SS-2 Copper 5.8 mg/kg 4/26/2016 9,400 700
SS-3 Copper 3.0 mg/kg 4/26/2016 9,400 700
BG Lead 3.7 mg/kg 4/26/2016 800 270
SS-1 Lead 9.2 mg/kg 4/26/2016 800 270
SS-2 Lead 6.4 mg/kg 4/26/2016 800 270
SS-3 Lead 7.8 mg/kg 4/26/2016 800 270
BG Nickel 1.7 mg/kg 4/26/2016 4,400 130
SS-1 Nickel 7.2 mg/kg 4/26/2016 4,400 130
SS-2 Nickel 4.2 mg/kg 4/26/2016 4,400 130
SS-3 Nickel 3.6 mg/kg 4/26/2016 4,400 130
SS-3 Selenium 0.36 J mg/kg 4/26/2016 1,200 2.1
BG Vanadium 7.1 mg/kg 4/26/2016 1,200 6.0
SS-1 Vanadium 19.0 mg/kg 4/26/2016 1,200 6.0
SS-2 Vanadium 10.4 mg/kg 4/26/2016 1,200 6.0
SS-3 Vanadium 10.2 mg/kg 4/26/2016 1,200 6.0
BG Zinc 4.4 mg/kg 4/26/2016 70,000 1,200
SS-1 Zinc 19.0 mg/kg 4/26/2016 70,000 1,200
SS-2 Zinc 29.9 mg/kg 4/26/2016 70,000 1,200
SS-3 Zinc 10.5 mg/kg 4/26/2016 70,000 1,200
BG Acetone 18.7 J µg/kg 4/26/2016 100,000,000 24,000
SS-2 Acetone 12.0 J µg/kg 4/26/2016 100,000,000 24,000
BG Methylene Chloride 1.8 J µg/kg 4/26/2016 640,000 23
SS-1 Methylene Chloride 1.7 J µg/kg 4/26/2016 640,000 23
SS-2 Methylene Chloride 1.5 J µg/kg 4/26/2016 640,000 23
SS-3 Methylene Chloride 2.8 J µg/kg 4/26/2016 640,000 23
SS-2 Toluene 4.8 µg/kg 4/26/2016 820,000 5,500
BG pH at 25 ºC 5.0 H6 S.U. 4/26/2016
SS-1 pH at 25 ºC 7.2 H6 S.U. 4/26/2016
SS-2 pH at 25 ºC 8.0 H6 S.U. 4/26/2016
SS-3 pH at 25 ºC 7.9 H6 S.U. 4/26/2016
BG Percent Moisture 11.0 % 4/26/2016
SS-1 Percent Moisture 15.8 % 4/26/2016
SS-2 Percent Moisture 13.6 % 4/26/2016
SS-3 Percent Moisture 13.3 % 4/26/2016
NOTES:mg/kg = milligrams per kilogram = parts per million.
µg/kg = micrograms per kilogram = parts per billion.
S.U. = standard units for pH.
% = percent.
PSRG = Preliminary Soil Remediation Goals (NC-DEQ Inactive Hazardous Sites Branch)
PSRG-IH = Industrial Health-based PSRG.
PSRG-GW = Protection of Groundwater PSRG.
Bold/Highlighted results exceed the lowest PSRG.
TABLE 2: Soil Analytical Results
Republic Services - Holly Springs Landfill
Permit No. 92-14
Joyce Engineering

Attachment A

ASI ANALYTICAL SERVICES, INC.
Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
Republic Services of North Carolina, LLC
Project: Holly Springs Surface Waters
Conover, NC 28613
1220 Commerce Street, SW
Mr. Matt Einsmann
We appreciate the opportunity to provide the analytical support for your project. The analytical results in this report are based upon information supplied by you, the
client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Analytical Services, Inc. certifies that the
following analytical results meet all requirements of the National Environmental Laboratory Accreditation Conference(NELAC).All test results relate only to the samples
analyzed.
Laboratory Report
Project #:[none]
Prepared For:
Attention:
March 25, 2016
Report Number:AZC0222
Approved:
This report may not be reproduced, except in full, without written approval from Analytical Services, Inc.Page 1 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
Sample ID Laboratory ID Matrix Date Sampled
ANALYTICAL REPORT FOR SAMPLES
Date Received
9214-SW2 AZC0222-01 03/07/16 10:30 03/08/16 10:05Surface Water
9214-SWA AZC0222-02 03/07/16 10:50 03/08/16 10:05Surface Water
9214-SWB AZC0222-03 03/07/16 11:00 03/08/16 10:05Surface Water
9214-Field Blank AZC0222-04 03/07/16 11:25 03/08/16 10:05Water
9214-Trip Blank AZC0222-05 03/07/16 07:45 03/08/16 10:05Water
Page 2 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
ResultAnalyte
SWSL/
RL
Prep
Method Qual DF Units Batch
Analytical
Method MDL CAS #Prep Date/Time Analysis
Date/Time
Client ID:
Date/Time Sampled:
Matrix:
Report No.:
Lab No:
Date/Time Received:
9214-SW2
Surface Water
AZC0222-01 AZC022203/07/16 10:30
Project:Holly Springs Surface Waters
03/08/16 10:05
General Chemistry
SM 2320 B 186000 ug/L1Alkalinity as CaCO3 1000 6030271SM 2320 B 1000 ALK 03/14/16 10:1503/14/16 10:15
EPA 350.1 1220 ug/L1Ammonia as N 100 6030361EPA 350.1 100 NA 03/17/16 11:0303/17/16 07:45
SM 5210 B 4000 ug/L1Biochemical Oxygen Demand 2000 BOD-3 6030186SM 5210 B 2000 E-10106 03/14/16 11:4503/09/16 07:00
SM 4500-P B,E 51.1 ug/L1.11Phosphorus-Total 22.2 6030465SM 4500-P B 22.2 7723-14-0 03/23/16 14:1803/22/16 11:18
Inorganic Anions
EPA 9056A 28000 ug/L1Chloride1000 6030167EPA 9056A 1000 16887-00-6 03/08/16 18:0803/08/16 18:08
EPA 9056A 130000 ug/L5Sulfate25000 6030167EPA 9056A 25000 14808-79-8 03/10/16 23:3703/10/16 23:37
Metals, Total
EPA 6020B 3.59 ug/L1Arsenic10.0 J 6030350EPA 3005A 0.75 7440-38-2 03/17/16 16:1203/17/16 09:45
EPA 6020B 67.6 ug/L1Barium100 J 6030350EPA 3005A 0.30 7440-39-3 03/17/16 16:1203/17/16 09:45
NDEPA 6020B ug/L1Cadmium1.00 6030350EPA 3005A 0.10 7440-43-9 03/17/16 16:1203/17/16 09:45
EPA 6020B 2.30 ug/L1Chromium10.0 J 6030350EPA 3005A 0.43 7440-47-3 03/17/16 16:1203/17/16 09:45
EPA 6020B 0.52 ug/L1Lead10.0 J 6030350EPA 3005A 0.08 7439-92-1 03/17/16 16:1203/17/16 09:45
EPA 6020B 1.44 ug/L1Selenium10.0 J 6030350EPA 3005A 0.85 7782-49-2 03/17/16 16:1203/17/16 09:45
NDEPA 6020B ug/L1Silver10.0 6030350EPA 3005A 0.22 7440-22-4 03/17/16 16:1203/17/16 09:45
NDEPA 7470A ug/L1Mercury0.200 6030375EPA 7470A 0.070 7439-97-6 03/18/16 15:0403/17/16 15:10
Volatile Organic Compounds by EPA 8260
EPA 8260B 7.2 ug/L1Acetone100 J 6030190EPA 5030B 4.9 67-64-1 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Acrylonitrile200 6030190EPA 5030B 1.8 107-13-1 03/09/16 17:3703/09/16 13:00
Page 3 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
ResultAnalyte SWSL/
RL
Prep
Method Qual DF Units Batch
Analytical
Method MDL CAS #Prep Date/Time Analysis
Date/Time
Client ID:
Date/Time Sampled:
Matrix:
Report No.:
Lab No:
Date/Time Received:
9214-SW2
Surface Water
AZC0222-01 AZC022203/07/16 10:30
Project:Holly Springs Surface Waters
03/08/16 10:05
Volatile Organic Compounds by EPA 8260
NDEPA 8260B ug/L1Benzene1.0 6030190EPA 5030B 0.2 71-43-2 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Bromochloromethane3.0 6030190EPA 5030B 0.7 74-97-5 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Bromodichloromethane1.0 6030190EPA 5030B 0.6 75-27-4 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Bromoform3.0 6030190EPA 5030B 0.5 75-25-2 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Bromomethane10 6030190EPA 5030B 0.8 74-83-9 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Carbon Disulfide 100 6030190EPA 5030B 0.9 75-15-0 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 6030190EPA 5030B 0.6 56-23-5 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Chlorobenzene3.0 6030190EPA 5030B 0.4 108-90-7 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Chloroethane10 6030190EPA 5030B 0.6 75-00-3 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Chloroform5.0 6030190EPA 5030B 0.3 67-66-3 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Chloromethane1.0 6030190EPA 5030B 0.4 74-87-3 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Dibromochloromethane3.0 6030190EPA 5030B 0.4 124-48-1 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 6030190EPA 5030B 2.0 96-12-8 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L11,2-Dibromoethane 1.0 6030190EPA 5030B 0.7 106-93-4 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Dibromomethane10 6030190EPA 5030B 0.7 74-95-3 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 6030190EPA 5030B 0.5 95-50-1 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 6030190EPA 5030B 0.2 106-46-7 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 6030190EPA 5030B 1.5 110-57-6 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L11,1-Dichloroethane 5.0 6030190EPA 5030B 0.4 75-34-3 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L11,2-Dichloroethane 1.0 6030190EPA 5030B 0.3 107-06-2 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L11,1-Dichloroethene 5.0 6030190EPA 5030B 0.5 75-35-4 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 6030190EPA 5030B 0.5 156-59-2 03/09/16 17:3703/09/16 13:00
Page 4 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
ResultAnalyte SWSL/
RL
Prep
Method Qual DF Units Batch
Analytical
Method MDL CAS #Prep Date/Time Analysis
Date/Time
Client ID:
Date/Time Sampled:
Matrix:
Report No.:
Lab No:
Date/Time Received:
9214-SW2
Surface Water
AZC0222-01 AZC022203/07/16 10:30
Project:Holly Springs Surface Waters
03/08/16 10:05
Volatile Organic Compounds by EPA 8260
NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 6030190EPA 5030B 0.5 156-60-5 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L11,2-Dichloropropane 1.0 6030190EPA 5030B 0.5 78-87-5 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 6030190EPA 5030B 0.4 10061-01-5 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 6030190EPA 5030B 0.4 10061-02-6 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Ethylbenzene1.0 6030190EPA 5030B 0.3 100-41-4 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Iodomethane10 6030190EPA 5030B 0.6 74-88-4 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Methyl Butyl Ketone
(2-Hexanone)50 6030190EPA 5030B 0.9 591-78-6 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Methylene Chloride 1.0 6030190EPA 5030B 0.5 75-09-2 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Methyl Ethyl Ketone
(2-Butanone)100 6030190EPA 5030B 1.1 78-93-3 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 6030190EPA 5030B 1.7 108-10-1 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Styrene1.0 6030190EPA 5030B 0.4 100-42-5 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 6030190EPA 5030B 0.5 630-20-6 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 6030190EPA 5030B 0.5 79-34-5 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Tetrachloroethene1.0 6030190EPA 5030B 0.4 127-18-4 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Toluene1.0 6030190EPA 5030B 0.3 108-88-3 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 6030190EPA 5030B 0.4 71-55-6 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 6030190EPA 5030B 0.8 79-00-5 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Trichloroethene1.0 6030190EPA 5030B 0.4 79-01-6 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Trichlorofluoromethane1.0 6030190EPA 5030B 0.5 75-69-4 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 6030190EPA 5030B 0.7 96-18-4 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Vinyl Acetate 50 6030190EPA 5030B 0.6 108-05-4 03/09/16 17:3703/09/16 13:00
Page 5 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
ResultAnalyte SWSL/
RL
Prep
Method Qual DF Units Batch
Analytical
Method MDL CAS #Prep Date/Time Analysis
Date/Time
Client ID:
Date/Time Sampled:
Matrix:
Report No.:
Lab No:
Date/Time Received:
9214-SW2
Surface Water
AZC0222-01 AZC022203/07/16 10:30
Project:Holly Springs Surface Waters
03/08/16 10:05
Volatile Organic Compounds by EPA 8260
NDEPA 8260B ug/L1Vinyl Chloride 1.0 6030190EPA 5030B 0.7 75-01-4 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Xylenes, total 5.0 6030190EPA 5030B 0.4 1330-20-7 03/09/16 17:3703/09/16 13:00
NDEPA 8260B ug/L1Tetrahydrofuran10 6030190EPA 5030B 1.5 109-99-9 03/09/16 17:3703/09/16 13:00
EPA 8260B 90 %Surr: Dibromofluoromethane 6030190EPA 5030B 1868-53-7 03/09/16 17:3703/09/16 13:0080-120
EPA 8260B 94 %Surr: 1,2-Dichloroethane-d4 6030190EPA 5030B 17060-07-0 03/09/16 17:3703/09/16 13:0078-120
EPA 8260B 99 %Surr: Toluene-d8 6030190EPA 5030B 2037-26-5 03/09/16 17:3703/09/16 13:0080-120
EPA 8260B 85 %Surr: 4-Bromofluorobenzene 6030190EPA 5030B 460-00-4 03/09/16 17:3703/09/16 13:0080-120
Page 6 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
ResultAnalyte SWSL/
RL
Prep
Method Qual DF Units Batch
Analytical
Method MDL CAS #Prep Date/Time Analysis
Date/Time
Client ID:
Date/Time Sampled:
Matrix:
Report No.:
Lab No:
Date/Time Received:
9214-SWA
Surface Water
AZC0222-02 AZC022203/07/16 10:50
Project:Holly Springs Surface Waters
03/08/16 10:05
General Chemistry
SM 2320 B 187000 ug/L1Alkalinity as CaCO3 1000 6030271SM 2320 B 1000 ALK 03/14/16 10:1503/14/16 10:15
EPA 350.1 1110 ug/L1Ammonia as N 100 6030361EPA 350.1 100 NA 03/17/16 11:0403/17/16 07:45
SM 5210 B 2000 ug/L1Biochemical Oxygen Demand 2000 BOD-3 6030186SM 5210 B 2000 E-10106 03/14/16 11:4503/09/16 07:00
SM 4500-P B,E 62.2 ug/L1.11Phosphorus-Total 22.2 6030465SM 4500-P B 22.2 7723-14-0 03/23/16 14:1803/22/16 11:18
Inorganic Anions
EPA 9056A 28000 ug/L1Chloride1000 6030167EPA 9056A 1000 16887-00-6 03/08/16 18:2803/08/16 18:28
EPA 9056A 120000 ug/L5Sulfate25000 6030167EPA 9056A 25000 14808-79-8 03/10/16 23:5703/10/16 23:57
Metals, Total
EPA 6020B 2.97 ug/L1Arsenic10.0 J 6030350EPA 3005A 0.75 7440-38-2 03/17/16 16:1703/17/16 09:45
EPA 6020B 66.6 ug/L1Barium100 J 6030350EPA 3005A 0.30 7440-39-3 03/17/16 16:1703/17/16 09:45
NDEPA 6020B ug/L1Cadmium1.00 6030350EPA 3005A 0.10 7440-43-9 03/17/16 16:1703/17/16 09:45
EPA 6020B 2.10 ug/L1Chromium10.0 J 6030350EPA 3005A 0.43 7440-47-3 03/17/16 16:1703/17/16 09:45
EPA 6020B 0.31 ug/L1Lead10.0 J 6030350EPA 3005A 0.08 7439-92-1 03/17/16 16:1703/17/16 09:45
NDEPA 6020B ug/L1Selenium10.0 6030350EPA 3005A 0.85 7782-49-2 03/17/16 16:1703/17/16 09:45
NDEPA 6020B ug/L1Silver10.0 6030350EPA 3005A 0.22 7440-22-4 03/17/16 16:1703/17/16 09:45
NDEPA 7470A ug/L1Mercury0.200 6030375EPA 7470A 0.070 7439-97-6 03/18/16 15:0603/17/16 15:10
Volatile Organic Compounds by EPA 8260
EPA 8260B 7.4 ug/L1Acetone100 J 6030190EPA 5030B 4.9 67-64-1 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Acrylonitrile200 6030190EPA 5030B 1.8 107-13-1 03/09/16 18:0703/09/16 13:00
Page 7 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
ResultAnalyte SWSL/
RL
Prep
Method Qual DF Units Batch
Analytical
Method MDL CAS #Prep Date/Time Analysis
Date/Time
Client ID:
Date/Time Sampled:
Matrix:
Report No.:
Lab No:
Date/Time Received:
9214-SWA
Surface Water
AZC0222-02 AZC022203/07/16 10:50
Project:Holly Springs Surface Waters
03/08/16 10:05
Volatile Organic Compounds by EPA 8260
NDEPA 8260B ug/L1Benzene1.0 6030190EPA 5030B 0.2 71-43-2 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Bromochloromethane3.0 6030190EPA 5030B 0.7 74-97-5 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Bromodichloromethane1.0 6030190EPA 5030B 0.6 75-27-4 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Bromoform3.0 6030190EPA 5030B 0.5 75-25-2 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Bromomethane10 6030190EPA 5030B 0.8 74-83-9 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Carbon Disulfide 100 6030190EPA 5030B 0.9 75-15-0 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 6030190EPA 5030B 0.6 56-23-5 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Chlorobenzene3.0 6030190EPA 5030B 0.4 108-90-7 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Chloroethane10 6030190EPA 5030B 0.6 75-00-3 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Chloroform5.0 6030190EPA 5030B 0.3 67-66-3 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Chloromethane1.0 6030190EPA 5030B 0.4 74-87-3 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Dibromochloromethane3.0 6030190EPA 5030B 0.4 124-48-1 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 6030190EPA 5030B 2.0 96-12-8 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L11,2-Dibromoethane 1.0 6030190EPA 5030B 0.7 106-93-4 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Dibromomethane10 6030190EPA 5030B 0.7 74-95-3 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 6030190EPA 5030B 0.5 95-50-1 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 6030190EPA 5030B 0.2 106-46-7 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 6030190EPA 5030B 1.5 110-57-6 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L11,1-Dichloroethane 5.0 6030190EPA 5030B 0.4 75-34-3 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L11,2-Dichloroethane 1.0 6030190EPA 5030B 0.3 107-06-2 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L11,1-Dichloroethene 5.0 6030190EPA 5030B 0.5 75-35-4 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 6030190EPA 5030B 0.5 156-59-2 03/09/16 18:0703/09/16 13:00
Page 8 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
ResultAnalyte SWSL/
RL
Prep
Method Qual DF Units Batch
Analytical
Method MDL CAS #Prep Date/Time Analysis
Date/Time
Client ID:
Date/Time Sampled:
Matrix:
Report No.:
Lab No:
Date/Time Received:
9214-SWA
Surface Water
AZC0222-02 AZC022203/07/16 10:50
Project:Holly Springs Surface Waters
03/08/16 10:05
Volatile Organic Compounds by EPA 8260
NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 6030190EPA 5030B 0.5 156-60-5 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L11,2-Dichloropropane 1.0 6030190EPA 5030B 0.5 78-87-5 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 6030190EPA 5030B 0.4 10061-01-5 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 6030190EPA 5030B 0.4 10061-02-6 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Ethylbenzene1.0 6030190EPA 5030B 0.3 100-41-4 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Iodomethane10 6030190EPA 5030B 0.6 74-88-4 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Methyl Butyl Ketone
(2-Hexanone)50 6030190EPA 5030B 0.9 591-78-6 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Methylene Chloride 1.0 6030190EPA 5030B 0.5 75-09-2 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Methyl Ethyl Ketone
(2-Butanone)100 6030190EPA 5030B 1.1 78-93-3 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 6030190EPA 5030B 1.7 108-10-1 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Styrene1.0 6030190EPA 5030B 0.4 100-42-5 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 6030190EPA 5030B 0.5 630-20-6 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 6030190EPA 5030B 0.5 79-34-5 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Tetrachloroethene1.0 6030190EPA 5030B 0.4 127-18-4 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Toluene1.0 6030190EPA 5030B 0.3 108-88-3 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 6030190EPA 5030B 0.4 71-55-6 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 6030190EPA 5030B 0.8 79-00-5 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Trichloroethene1.0 6030190EPA 5030B 0.4 79-01-6 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Trichlorofluoromethane1.0 6030190EPA 5030B 0.5 75-69-4 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 6030190EPA 5030B 0.7 96-18-4 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Vinyl Acetate 50 6030190EPA 5030B 0.6 108-05-4 03/09/16 18:0703/09/16 13:00
Page 9 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
ResultAnalyte SWSL/
RL
Prep
Method Qual DF Units Batch
Analytical
Method MDL CAS #Prep Date/Time Analysis
Date/Time
Client ID:
Date/Time Sampled:
Matrix:
Report No.:
Lab No:
Date/Time Received:
9214-SWA
Surface Water
AZC0222-02 AZC022203/07/16 10:50
Project:Holly Springs Surface Waters
03/08/16 10:05
Volatile Organic Compounds by EPA 8260
NDEPA 8260B ug/L1Vinyl Chloride 1.0 6030190EPA 5030B 0.7 75-01-4 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Xylenes, total 5.0 6030190EPA 5030B 0.4 1330-20-7 03/09/16 18:0703/09/16 13:00
NDEPA 8260B ug/L1Tetrahydrofuran10 6030190EPA 5030B 1.5 109-99-9 03/09/16 18:0703/09/16 13:00
EPA 8260B 89 %Surr: Dibromofluoromethane 6030190EPA 5030B 1868-53-7 03/09/16 18:0703/09/16 13:0080-120
EPA 8260B 94 %Surr: 1,2-Dichloroethane-d4 6030190EPA 5030B 17060-07-0 03/09/16 18:0703/09/16 13:0078-120
EPA 8260B 100 %Surr: Toluene-d8 6030190EPA 5030B 2037-26-5 03/09/16 18:0703/09/16 13:0080-120
EPA 8260B 86 %Surr: 4-Bromofluorobenzene 6030190EPA 5030B 460-00-4 03/09/16 18:0703/09/16 13:0080-120
Page 10 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
ResultAnalyte SWSL/
RL
Prep
Method Qual DF Units Batch
Analytical
Method MDL CAS #Prep Date/Time Analysis
Date/Time
Client ID:
Date/Time Sampled:
Matrix:
Report No.:
Lab No:
Date/Time Received:
9214-SWB
Surface Water
AZC0222-03 AZC022203/07/16 11:00
Project:Holly Springs Surface Waters
03/08/16 10:05
General Chemistry
SM 2320 B 220000 ug/L1Alkalinity as CaCO3 1000 6030271SM 2320 B 1000 ALK 03/14/16 10:1503/14/16 10:15
EPA 350.1 1490 ug/L1Ammonia as N 100 6030361EPA 350.1 100 NA 03/17/16 11:0503/17/16 07:45
SM 5210 B 2000 ug/L1Biochemical Oxygen Demand 2000 BOD-3 6030186SM 5210 B 2000 E-10106 03/14/16 11:4503/09/16 07:00
NDSM 4500-P B,E ug/L1.11Phosphorus-Total 22.2 6030465SM 4500-P B 22.2 7723-14-0 03/23/16 14:1803/22/16 11:18
Inorganic Anions
EPA 9056A 29000 ug/L1Chloride1000 6030167EPA 9056A 1000 16887-00-6 03/08/16 18:4903/08/16 18:49
EPA 9056A 130000 ug/L5Sulfate25000 6030167EPA 9056A 25000 14808-79-8 03/11/16 00:1803/11/16 00:18
Metals, Total
EPA 6020B 1.87 ug/L1Arsenic10.0 J 6030350EPA 3005A 0.75 7440-38-2 03/17/16 16:2103/17/16 09:45
EPA 6020B 65.7 ug/L1Barium100 J 6030350EPA 3005A 0.30 7440-39-3 03/17/16 16:2103/17/16 09:45
NDEPA 6020B ug/L1Cadmium1.00 6030350EPA 3005A 0.10 7440-43-9 03/17/16 16:2103/17/16 09:45
EPA 6020B 2.29 ug/L1Chromium10.0 J 6030350EPA 3005A 0.43 7440-47-3 03/17/16 16:2103/17/16 09:45
EPA 6020B 0.16 ug/L1Lead10.0 J 6030350EPA 3005A 0.08 7439-92-1 03/17/16 16:2103/17/16 09:45
EPA 6020B 1.17 ug/L1Selenium10.0 J 6030350EPA 3005A 0.85 7782-49-2 03/17/16 16:2103/17/16 09:45
NDEPA 6020B ug/L1Silver10.0 6030350EPA 3005A 0.22 7440-22-4 03/17/16 16:2103/17/16 09:45
EPA 7470A 0.081 ug/L1Mercury0.200 J 6030375EPA 7470A 0.070 7439-97-6 03/18/16 15:0903/17/16 15:10
Volatile Organic Compounds by EPA 8260
EPA 8260B 4.9 ug/L1Acetone100 J 6030190EPA 5030B 4.9 67-64-1 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Acrylonitrile200 6030190EPA 5030B 1.8 107-13-1 03/09/16 18:3703/09/16 13:00
Page 11 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
ResultAnalyte SWSL/
RL
Prep
Method Qual DF Units Batch
Analytical
Method MDL CAS #Prep Date/Time Analysis
Date/Time
Client ID:
Date/Time Sampled:
Matrix:
Report No.:
Lab No:
Date/Time Received:
9214-SWB
Surface Water
AZC0222-03 AZC022203/07/16 11:00
Project:Holly Springs Surface Waters
03/08/16 10:05
Volatile Organic Compounds by EPA 8260
NDEPA 8260B ug/L1Benzene1.0 6030190EPA 5030B 0.2 71-43-2 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Bromochloromethane3.0 6030190EPA 5030B 0.7 74-97-5 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Bromodichloromethane1.0 6030190EPA 5030B 0.6 75-27-4 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Bromoform3.0 6030190EPA 5030B 0.5 75-25-2 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Bromomethane10 6030190EPA 5030B 0.8 74-83-9 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Carbon Disulfide 100 6030190EPA 5030B 0.9 75-15-0 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 6030190EPA 5030B 0.6 56-23-5 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Chlorobenzene3.0 6030190EPA 5030B 0.4 108-90-7 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Chloroethane10 6030190EPA 5030B 0.6 75-00-3 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Chloroform5.0 6030190EPA 5030B 0.3 67-66-3 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Chloromethane1.0 6030190EPA 5030B 0.4 74-87-3 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Dibromochloromethane3.0 6030190EPA 5030B 0.4 124-48-1 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 6030190EPA 5030B 2.0 96-12-8 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L11,2-Dibromoethane 1.0 6030190EPA 5030B 0.7 106-93-4 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Dibromomethane10 6030190EPA 5030B 0.7 74-95-3 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 6030190EPA 5030B 0.5 95-50-1 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 6030190EPA 5030B 0.2 106-46-7 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 6030190EPA 5030B 1.5 110-57-6 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L11,1-Dichloroethane 5.0 6030190EPA 5030B 0.4 75-34-3 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L11,2-Dichloroethane 1.0 6030190EPA 5030B 0.3 107-06-2 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L11,1-Dichloroethene 5.0 6030190EPA 5030B 0.5 75-35-4 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 6030190EPA 5030B 0.5 156-59-2 03/09/16 18:3703/09/16 13:00
Page 12 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
ResultAnalyte SWSL/
RL
Prep
Method Qual DF Units Batch
Analytical
Method MDL CAS #Prep Date/Time Analysis
Date/Time
Client ID:
Date/Time Sampled:
Matrix:
Report No.:
Lab No:
Date/Time Received:
9214-SWB
Surface Water
AZC0222-03 AZC022203/07/16 11:00
Project:Holly Springs Surface Waters
03/08/16 10:05
Volatile Organic Compounds by EPA 8260
NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 6030190EPA 5030B 0.5 156-60-5 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L11,2-Dichloropropane 1.0 6030190EPA 5030B 0.5 78-87-5 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 6030190EPA 5030B 0.4 10061-01-5 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 6030190EPA 5030B 0.4 10061-02-6 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Ethylbenzene1.0 6030190EPA 5030B 0.3 100-41-4 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Iodomethane10 6030190EPA 5030B 0.6 74-88-4 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Methyl Butyl Ketone
(2-Hexanone)50 6030190EPA 5030B 0.9 591-78-6 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Methylene Chloride 1.0 6030190EPA 5030B 0.5 75-09-2 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Methyl Ethyl Ketone
(2-Butanone)100 6030190EPA 5030B 1.1 78-93-3 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 6030190EPA 5030B 1.7 108-10-1 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Styrene1.0 6030190EPA 5030B 0.4 100-42-5 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 6030190EPA 5030B 0.5 630-20-6 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 6030190EPA 5030B 0.5 79-34-5 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Tetrachloroethene1.0 6030190EPA 5030B 0.4 127-18-4 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Toluene1.0 6030190EPA 5030B 0.3 108-88-3 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 6030190EPA 5030B 0.4 71-55-6 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 6030190EPA 5030B 0.8 79-00-5 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Trichloroethene1.0 6030190EPA 5030B 0.4 79-01-6 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Trichlorofluoromethane1.0 6030190EPA 5030B 0.5 75-69-4 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 6030190EPA 5030B 0.7 96-18-4 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Vinyl Acetate 50 6030190EPA 5030B 0.6 108-05-4 03/09/16 18:3703/09/16 13:00
Page 13 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
ResultAnalyte SWSL/
RL
Prep
Method Qual DF Units Batch
Analytical
Method MDL CAS #Prep Date/Time Analysis
Date/Time
Client ID:
Date/Time Sampled:
Matrix:
Report No.:
Lab No:
Date/Time Received:
9214-SWB
Surface Water
AZC0222-03 AZC022203/07/16 11:00
Project:Holly Springs Surface Waters
03/08/16 10:05
Volatile Organic Compounds by EPA 8260
NDEPA 8260B ug/L1Vinyl Chloride 1.0 6030190EPA 5030B 0.7 75-01-4 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Xylenes, total 5.0 6030190EPA 5030B 0.4 1330-20-7 03/09/16 18:3703/09/16 13:00
NDEPA 8260B ug/L1Tetrahydrofuran10 6030190EPA 5030B 1.5 109-99-9 03/09/16 18:3703/09/16 13:00
EPA 8260B 91 %Surr: Dibromofluoromethane 6030190EPA 5030B 1868-53-7 03/09/16 18:3703/09/16 13:0080-120
EPA 8260B 93 %Surr: 1,2-Dichloroethane-d4 6030190EPA 5030B 17060-07-0 03/09/16 18:3703/09/16 13:0078-120
EPA 8260B 99 %Surr: Toluene-d8 6030190EPA 5030B 2037-26-5 03/09/16 18:3703/09/16 13:0080-120
EPA 8260B 87 %Surr: 4-Bromofluorobenzene 6030190EPA 5030B 460-00-4 03/09/16 18:3703/09/16 13:0080-120
Page 14 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
ResultAnalyte SWSL/
RL
Prep
Method Qual DF Units Batch
Analytical
Method MDL CAS #Prep Date/Time Analysis
Date/Time
Client ID:
Date/Time Sampled:
Matrix:
Report No.:
Lab No:
Date/Time Received:
9214-Field Blank
Water
AZC0222-04 AZC022203/07/16 11:25
Project:Holly Springs Surface Waters
03/08/16 10:05
Metals, Total
NDEPA 6020B ug/L1Arsenic10.0 6030350EPA 3005A 0.75 7440-38-2 03/17/16 16:2603/17/16 09:45
EPA 6020B 1.42 ug/L1Barium100 J 6030350EPA 3005A 0.30 7440-39-3 03/17/16 16:2603/17/16 09:45
NDEPA 6020B ug/L1Cadmium1.00 6030350EPA 3005A 0.10 7440-43-9 03/17/16 16:2603/17/16 09:45
NDEPA 6020B ug/L1Chromium10.0 6030350EPA 3005A 0.43 7440-47-3 03/17/16 16:2603/17/16 09:45
NDEPA 6020B ug/L1Lead10.0 6030350EPA 3005A 0.08 7439-92-1 03/17/16 16:2603/17/16 09:45
NDEPA 6020B ug/L1Selenium10.0 6030350EPA 3005A 0.85 7782-49-2 03/17/16 16:2603/17/16 09:45
NDEPA 6020B ug/L1Silver10.0 6030350EPA 3005A 0.22 7440-22-4 03/17/16 16:2603/17/16 09:45
NDEPA 7470A ug/L1Mercury0.200 6030375EPA 7470A 0.070 7439-97-6 03/18/16 15:1903/17/16 15:10
Volatile Organic Compounds by EPA 8260
NDEPA 8260B ug/L1Acetone100 6030190EPA 5030B 4.9 67-64-1 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Acrylonitrile200 6030190EPA 5030B 1.8 107-13-1 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Benzene1.0 6030190EPA 5030B 0.2 71-43-2 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Bromochloromethane3.0 6030190EPA 5030B 0.7 74-97-5 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Bromodichloromethane1.0 6030190EPA 5030B 0.6 75-27-4 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Bromoform3.0 6030190EPA 5030B 0.5 75-25-2 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Bromomethane10 6030190EPA 5030B 0.8 74-83-9 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Carbon Disulfide 100 6030190EPA 5030B 0.9 75-15-0 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 6030190EPA 5030B 0.6 56-23-5 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Chlorobenzene3.0 6030190EPA 5030B 0.4 108-90-7 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Chloroethane10 6030190EPA 5030B 0.6 75-00-3 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Chloroform5.0 6030190EPA 5030B 0.3 67-66-3 03/09/16 19:0603/09/16 13:00
Page 15 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
ResultAnalyte SWSL/
RL
Prep
Method Qual DF Units Batch
Analytical
Method MDL CAS #Prep Date/Time Analysis
Date/Time
Client ID:
Date/Time Sampled:
Matrix:
Report No.:
Lab No:
Date/Time Received:
9214-Field Blank
Water
AZC0222-04 AZC022203/07/16 11:25
Project:Holly Springs Surface Waters
03/08/16 10:05
Volatile Organic Compounds by EPA 8260
NDEPA 8260B ug/L1Chloromethane1.0 6030190EPA 5030B 0.4 74-87-3 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Dibromochloromethane3.0 6030190EPA 5030B 0.4 124-48-1 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 6030190EPA 5030B 2.0 96-12-8 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L11,2-Dibromoethane 1.0 6030190EPA 5030B 0.7 106-93-4 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Dibromomethane10 6030190EPA 5030B 0.7 74-95-3 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 6030190EPA 5030B 0.5 95-50-1 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 6030190EPA 5030B 0.2 106-46-7 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 6030190EPA 5030B 1.5 110-57-6 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L11,1-Dichloroethane 5.0 6030190EPA 5030B 0.4 75-34-3 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L11,2-Dichloroethane 1.0 6030190EPA 5030B 0.3 107-06-2 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L11,1-Dichloroethene 5.0 6030190EPA 5030B 0.5 75-35-4 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 6030190EPA 5030B 0.5 156-59-2 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 6030190EPA 5030B 0.5 156-60-5 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L11,2-Dichloropropane 1.0 6030190EPA 5030B 0.5 78-87-5 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 6030190EPA 5030B 0.4 10061-01-5 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 6030190EPA 5030B 0.4 10061-02-6 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Ethylbenzene1.0 6030190EPA 5030B 0.3 100-41-4 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Iodomethane10 6030190EPA 5030B 0.6 74-88-4 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Methyl Butyl Ketone
(2-Hexanone)50 6030190EPA 5030B 0.9 591-78-6 03/09/16 19:0603/09/16 13:00
EPA 8260B 1.2 ug/L1Methylene Chloride 1.0 6030190EPA 5030B 0.5 75-09-2 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Methyl Ethyl Ketone
(2-Butanone)100 6030190EPA 5030B 1.1 78-93-3 03/09/16 19:0603/09/16 13:00
Page 16 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
ResultAnalyte SWSL/
RL
Prep
Method Qual DF Units Batch
Analytical
Method MDL CAS #Prep Date/Time Analysis
Date/Time
Client ID:
Date/Time Sampled:
Matrix:
Report No.:
Lab No:
Date/Time Received:
9214-Field Blank
Water
AZC0222-04 AZC022203/07/16 11:25
Project:Holly Springs Surface Waters
03/08/16 10:05
Volatile Organic Compounds by EPA 8260
NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 6030190EPA 5030B 1.7 108-10-1 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Styrene1.0 6030190EPA 5030B 0.4 100-42-5 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 6030190EPA 5030B 0.5 630-20-6 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 6030190EPA 5030B 0.5 79-34-5 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Tetrachloroethene1.0 6030190EPA 5030B 0.4 127-18-4 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Toluene1.0 6030190EPA 5030B 0.3 108-88-3 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 6030190EPA 5030B 0.4 71-55-6 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 6030190EPA 5030B 0.8 79-00-5 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Trichloroethene1.0 6030190EPA 5030B 0.4 79-01-6 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Trichlorofluoromethane1.0 6030190EPA 5030B 0.5 75-69-4 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 6030190EPA 5030B 0.7 96-18-4 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Vinyl Acetate 50 6030190EPA 5030B 0.6 108-05-4 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Vinyl Chloride 1.0 6030190EPA 5030B 0.7 75-01-4 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Xylenes, total 5.0 6030190EPA 5030B 0.4 1330-20-7 03/09/16 19:0603/09/16 13:00
NDEPA 8260B ug/L1Tetrahydrofuran10 6030190EPA 5030B 1.5 109-99-9 03/09/16 19:0603/09/16 13:00
EPA 8260B 92 %Surr: Dibromofluoromethane 6030190EPA 5030B 1868-53-7 03/09/16 19:0603/09/16 13:0080-120
EPA 8260B 99 %Surr: 1,2-Dichloroethane-d4 6030190EPA 5030B 17060-07-0 03/09/16 19:0603/09/16 13:0078-120
EPA 8260B 99 %Surr: Toluene-d8 6030190EPA 5030B 2037-26-5 03/09/16 19:0603/09/16 13:0080-120
EPA 8260B 105 %Surr: 4-Bromofluorobenzene 6030190EPA 5030B 460-00-4 03/09/16 19:0603/09/16 13:0080-120
Page 17 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
ResultAnalyte SWSL/
RL
Prep
Method Qual DF Units Batch
Analytical
Method MDL CAS #Prep Date/Time Analysis
Date/Time
Client ID:
Date/Time Sampled:
Matrix:
Report No.:
Lab No:
Date/Time Received:
9214-Trip Blank
Water
AZC0222-05 AZC022203/07/16 07:45
Project:Holly Springs Surface Waters
03/08/16 10:05
Volatile Organic Compounds by EPA 8260
NDEPA 8260B ug/L1Acetone100 6030190EPA 5030B 4.9 67-64-1 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Acrylonitrile200 6030190EPA 5030B 1.8 107-13-1 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Benzene1.0 6030190EPA 5030B 0.2 71-43-2 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Bromochloromethane3.0 6030190EPA 5030B 0.7 74-97-5 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Bromodichloromethane1.0 6030190EPA 5030B 0.6 75-27-4 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Bromoform3.0 6030190EPA 5030B 0.5 75-25-2 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Bromomethane10 6030190EPA 5030B 0.8 74-83-9 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Carbon Disulfide 100 6030190EPA 5030B 0.9 75-15-0 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 6030190EPA 5030B 0.6 56-23-5 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Chlorobenzene3.0 6030190EPA 5030B 0.4 108-90-7 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Chloroethane10 6030190EPA 5030B 0.6 75-00-3 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Chloroform5.0 6030190EPA 5030B 0.3 67-66-3 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Chloromethane1.0 6030190EPA 5030B 0.4 74-87-3 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Dibromochloromethane3.0 6030190EPA 5030B 0.4 124-48-1 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 6030190EPA 5030B 2.0 96-12-8 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L11,2-Dibromoethane 1.0 6030190EPA 5030B 0.7 106-93-4 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Dibromomethane10 6030190EPA 5030B 0.7 74-95-3 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 6030190EPA 5030B 0.5 95-50-1 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 6030190EPA 5030B 0.2 106-46-7 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 6030190EPA 5030B 1.5 110-57-6 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L11,1-Dichloroethane 5.0 6030190EPA 5030B 0.4 75-34-3 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L11,2-Dichloroethane 1.0 6030190EPA 5030B 0.3 107-06-2 03/09/16 19:3603/09/16 13:00
Page 18 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
ResultAnalyte SWSL/
RL
Prep
Method Qual DF Units Batch
Analytical
Method MDL CAS #Prep Date/Time Analysis
Date/Time
Client ID:
Date/Time Sampled:
Matrix:
Report No.:
Lab No:
Date/Time Received:
9214-Trip Blank
Water
AZC0222-05 AZC022203/07/16 07:45
Project:Holly Springs Surface Waters
03/08/16 10:05
Volatile Organic Compounds by EPA 8260
NDEPA 8260B ug/L11,1-Dichloroethene 5.0 6030190EPA 5030B 0.5 75-35-4 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 6030190EPA 5030B 0.5 156-59-2 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 6030190EPA 5030B 0.5 156-60-5 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L11,2-Dichloropropane 1.0 6030190EPA 5030B 0.5 78-87-5 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 6030190EPA 5030B 0.4 10061-01-5 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 6030190EPA 5030B 0.4 10061-02-6 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Ethylbenzene1.0 6030190EPA 5030B 0.3 100-41-4 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Iodomethane10 6030190EPA 5030B 0.6 74-88-4 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Methyl Butyl Ketone
(2-Hexanone)50 6030190EPA 5030B 0.9 591-78-6 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Methylene Chloride 1.0 6030190EPA 5030B 0.5 75-09-2 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Methyl Ethyl Ketone
(2-Butanone)100 6030190EPA 5030B 1.1 78-93-3 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 6030190EPA 5030B 1.7 108-10-1 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Styrene1.0 6030190EPA 5030B 0.4 100-42-5 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 6030190EPA 5030B 0.5 630-20-6 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 6030190EPA 5030B 0.5 79-34-5 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Tetrachloroethene1.0 6030190EPA 5030B 0.4 127-18-4 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Toluene1.0 6030190EPA 5030B 0.3 108-88-3 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 6030190EPA 5030B 0.4 71-55-6 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 6030190EPA 5030B 0.8 79-00-5 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Trichloroethene1.0 6030190EPA 5030B 0.4 79-01-6 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Trichlorofluoromethane1.0 6030190EPA 5030B 0.5 75-69-4 03/09/16 19:3603/09/16 13:00
Page 19 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
ResultAnalyte SWSL/
RL
Prep
Method Qual DF Units Batch
Analytical
Method MDL CAS #Prep Date/Time Analysis
Date/Time
Client ID:
Date/Time Sampled:
Matrix:
Report No.:
Lab No:
Date/Time Received:
9214-Trip Blank
Water
AZC0222-05 AZC022203/07/16 07:45
Project:Holly Springs Surface Waters
03/08/16 10:05
Volatile Organic Compounds by EPA 8260
NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 6030190EPA 5030B 0.7 96-18-4 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Vinyl Acetate 50 6030190EPA 5030B 0.6 108-05-4 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Vinyl Chloride 1.0 6030190EPA 5030B 0.7 75-01-4 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Xylenes, total 5.0 6030190EPA 5030B 0.4 1330-20-7 03/09/16 19:3603/09/16 13:00
NDEPA 8260B ug/L1Tetrahydrofuran10 6030190EPA 5030B 1.5 109-99-9 03/09/16 19:3603/09/16 13:00
EPA 8260B 93 %Surr: Dibromofluoromethane 6030190EPA 5030B 1868-53-7 03/09/16 19:3603/09/16 13:0080-120
EPA 8260B 100 %Surr: 1,2-Dichloroethane-d4 6030190EPA 5030B 17060-07-0 03/09/16 19:3603/09/16 13:0078-120
EPA 8260B 99 %Surr: Toluene-d8 6030190EPA 5030B 2037-26-5 03/09/16 19:3603/09/16 13:0080-120
EPA 8260B 103 %Surr: 4-Bromofluorobenzene 6030190EPA 5030B 460-00-4 03/09/16 19:3603/09/16 13:0080-120
Page 20 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Qual Analyte
General Chemistry - Quality Control
Batch 6030186 - SM 5210 B
Blank (6030186-BLK1)Prepared: 03/09/16 Analyzed: 03/14/16
Biochemical Oxygen Demand ug/LND2000
LCS (6030186-BS1)Prepared: 03/09/16 Analyzed: 03/14/16
Biochemical Oxygen Demand ug/L1540002000 198000 BOD-385-11578
Duplicate (6030186-DUP1)Prepared: 03/09/16 Analyzed: 03/14/16 Source: AZC0213-02
Biochemical Oxygen Demand ug/L15400013000 166000 208
Batch 6030271 - SM 2320 B
Blank (6030271-BLK1)Prepared & Analyzed: 03/14/16
Alkalinity as CaCO3 ug/LND1000
LCS (6030271-BS1)Prepared & Analyzed: 03/14/16
Alkalinity as CaCO3 ug/L920001000 100000 85-11592
Duplicate (6030271-DUP1)Prepared & Analyzed: 03/14/16 Source: AZC0222-01
Alkalinity as CaCO3 ug/L1900001000 186000 102
Batch 6030361 - EPA 350.1
Blank (6030361-BLK1)Prepared & Analyzed: 03/17/16
Ammonia as N ug/LND100
LCS (6030361-BS1)Prepared & Analyzed: 03/17/16
Ammonia as N ug/L9570100 10000 90-11096
Page 21 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Qual Analyte
General Chemistry - Quality Control
Batch 6030361 - EPA 350.1
Matrix Spike (6030361-MS1)Prepared & Analyzed: 03/17/16 Source: AZC0389-09
Ammonia as N ug/L9660100 10000 267 90-11094
Matrix Spike (6030361-MS2)Prepared & Analyzed: 03/17/16 Source: AZC0357-01
Ammonia as N ug/L10600100 10000 341 90-110103
Batch 6030465 - SM 4500-P B
Blank (6030465-BLK1)Prepared: 03/22/16 Analyzed: 03/23/16
Phosphorus-Total ug/LND20.0
LCS (6030465-BS1)Prepared: 03/22/16 Analyzed: 03/23/16
Phosphorus-Total ug/L48920.0 500.00 88-11098
Matrix Spike (6030465-MS1)Prepared: 03/22/16 Analyzed: 03/23/16 Source: AZC0222-01
Phosphorus-Total ug/L63022.2 500.00 51.1 72-123116
Matrix Spike Dup (6030465-MSD1)Prepared: 03/22/16 Analyzed: 03/23/16 Source: AZC0222-01
Phosphorus-Total ug/L61422.2 500.00 51.1 1172-123113 3
Page 22 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Qual Analyte
Inorganic Anions - Quality Control
Batch 6030167 - EPA 9056A
Blank (6030167-BLK1)Prepared & Analyzed: 03/08/16
Chloride ug/LND1000
Sulfate ug/LND5000
LCS (6030167-BS1)Prepared & Analyzed: 03/08/16
Chloride ug/L98601000 10010 90-11098
Sulfate ug/L98405000 10010 90-11098
Matrix Spike (6030167-MS1)Prepared & Analyzed: 03/08/16 Source: AZC0222-03
Chloride ug/L362001000 10010 29400 QM-0590-11068
Sulfate ug/L1190005000 10010 122000 QM-0590-1100
Matrix Spike Dup (6030167-MSD1)Prepared & Analyzed: 03/08/16 Source: AZC0222-03
Chloride ug/L365001000 10010 29400 15 QM-0590-11071 0.7
Sulfate ug/L1190005000 10010 122000 15 QM-0590-1100 0.02
Page 23 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Qual Analyte
Metals, Total - Quality Control
Batch 6030350 - EPA 3005A
Blank (6030350-BLK1)Prepared & Analyzed: 03/17/16
Arsenic ug/LND10.0
Barium ug/LND100
Cadmium ug/LND1.00
Chromium ug/LND10.0
Lead ug/LND10.0
Selenium ug/LND10.0
Silver ug/LND10.0
LCS (6030350-BS1)Prepared & Analyzed: 03/17/16
Arsenic ug/L99.9 10.0 100.00 80-120100
Barium ug/L102100 100.00 80-120102
Cadmium ug/L99.0 1.00 100.00 80-12099
Chromium ug/L10810.0 100.00 80-120108
Lead ug/L10210.0 100.00 80-120102
Selenium ug/L10110.0 100.00 80-120101
Silver ug/L10010.0 100.00 80-120100
Matrix Spike (6030350-MS1)Prepared & Analyzed: 03/17/16 Source: AZC0222-03
Arsenic ug/L10610.0 100.00 1.87 75-125104
Barium ug/L176100 100.00 65.7 75-125111
Cadmium ug/L1001.00 100.00 ND 75-125100
Chromium ug/L10810.0 100.00 2.29 75-125106
Lead ug/L95.3 10.0 100.00 0.16 75-12595
Selenium ug/L10610.0 100.00 1.17 75-125104
Silver ug/L94.8 10.0 100.00 ND 75-12595
Matrix Spike Dup (6030350-MSD1)Prepared & Analyzed: 03/17/16 Source: AZC0222-03
Page 24 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Qual Analyte
Metals, Total - Quality Control
Batch 6030350 - EPA 3005A
Matrix Spike Dup (6030350-MSD1)Prepared & Analyzed: 03/17/16 Source: AZC0222-03
Arsenic ug/L10410.0 100.00 1.87 2075-125103 2
Barium ug/L168100 100.00 65.7 2075-125102 5
Cadmium ug/L98.0 1.00 100.00 ND 2075-12598 2
Chromium ug/L10510.0 100.00 2.29 2075-125102 3
Lead ug/L95.7 10.0 100.00 0.16 2075-12596 0.4
Selenium ug/L10410.0 100.00 1.17 2075-125103 2
Silver ug/L93.1 10.0 100.00 ND 2075-12593 2
Post Spike (6030350-PS1)Prepared & Analyzed: 03/17/16 Source: AZC0222-03
Arsenic ug/L108 100.00 1.87 80-120106
Barium ug/L170 100.00 65.7 80-120104
Cadmium ug/L101 100.00 0.01 80-120101
Chromium ug/L108 100.00 2.29 80-120105
Lead ug/L98.8 100.00 0.16 80-12099
Selenium ug/L106 100.00 1.17 80-120104
Silver ug/L94.7 100.00 0.02 80-12095
Batch 6030375 - EPA 7470A
Blank (6030375-BLK1)Prepared: 03/17/16 Analyzed: 03/18/16
Mercury ug/LND0.200
LCS (6030375-BS1)Prepared: 03/17/16 Analyzed: 03/18/16
Mercury ug/L2.13 0.200 2.5000 80-12085
Matrix Spike (6030375-MS1)Prepared: 03/17/16 Analyzed: 03/18/16 Source: AZC0222-01
Mercury ug/L2.03 0.200 2.5000 ND 75-12581
Page 25 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Qual Analyte
Metals, Total - Quality Control
Batch 6030375 - EPA 7470A
Matrix Spike Dup (6030375-MSD1)Prepared: 03/17/16 Analyzed: 03/18/16 Source: AZC0222-01
Mercury ug/L1.94 0.200 2.5000 ND 2075-12578 4
Post Spike (6030375-PS1)Prepared: 03/17/16 Analyzed: 03/18/16 Source: AZC0222-01
Mercury ug/L1.30 1.6667 0.038 QM-0580-12076
Page 26 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Qual Analyte
Volatile Organic Compounds by EPA 8260 - Quality Control
Batch 6030190 - EPA 5030B
Blank (6030190-BLK1)Prepared & Analyzed: 03/09/16
Acetone ug/LND100
Acrylonitrile ug/LND200
Benzene ug/LND1.0
Bromochloromethane ug/LND3.0
Bromodichloromethane ug/LND1.0
Bromoform ug/LND3.0
Bromomethane ug/LND10
Carbon Disulfide ug/LND100
Carbon Tetrachloride ug/LND1.0
Chlorobenzene ug/LND3.0
Chloroethane ug/LND10
Chloroform ug/LND5.0
Chloromethane ug/LND1.0
Dibromochloromethane ug/LND3.0
1,2-Dibromo-3-chloropropane ug/LND13
1,2-Dibromoethane ug/LND1.0
Dibromomethane ug/LND10
1,2-Dichlorobenzene ug/LND5.0
1,4-Dichlorobenzene ug/LND1.0
trans-1,4-Dichloro-2-butene ug/LND100
1,1-Dichloroethane ug/LND5.0
1,2-Dichloroethane ug/LND1.0
1,1-Dichloroethene ug/LND5.0
cis-1,2-Dichloroethene ug/LND5.0
trans-1,2-Dichloroethene ug/LND5.0
1,2-Dichloropropane ug/LND1.0
cis-1,3-Dichloropropene ug/LND1.0
Page 27 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Qual Analyte
Volatile Organic Compounds by EPA 8260 - Quality Control
Batch 6030190 - EPA 5030B
Blank (6030190-BLK1)Prepared & Analyzed: 03/09/16
trans-1,3-Dichloropropene ug/LND1.0
Ethylbenzene ug/LND1.0
Iodomethane ug/LND10
Methyl Butyl Ketone (2-Hexanone)ug/LND50
Methylene Chloride ug/LND1.0
Methyl Ethyl Ketone (2-Butanone)ug/LND100
4-Methyl-2-pentanone (MIBK)ug/LND100
Styrene ug/LND1.0
1,1,1,2-Tetrachloroethane ug/LND5.0
1,1,2,2-Tetrachloroethane ug/LND3.0
Tetrachloroethene ug/LND1.0
Toluene ug/LND1.0
1,1,1-Trichloroethane ug/LND1.0
1,1,2-Trichloroethane ug/LND1.0
Trichloroethene ug/LND1.0
Trichlorofluoromethane ug/LND1.0
1,2,3-Trichloropropane ug/LND1.0
Vinyl Acetate ug/LND50
Vinyl Chloride ug/LND1.0
Xylenes, total ug/LND5.0
Tetrahydrofuran ug/LND10
ug/L 50.000 80-120Surr: Dibromofluoromethane 9045
ug/L 50.000 78-120Surr: 1,2-Dichloroethane-d4 8944
ug/L 50.000 80-120Surr: Toluene-d8 9749
ug/L 50.000 80-120Surr: 4-Bromofluorobenzene 10352
Page 28 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Qual Analyte
Volatile Organic Compounds by EPA 8260 - Quality Control
Batch 6030190 - EPA 5030B
LCS (6030190-BS1)Prepared & Analyzed: 03/09/16
Benzene ug/L44 50.000 67-13488
Chlorobenzene ug/L49 50.000 69-12297
1,1-Dichloroethene ug/L40 50.000 58-14280
Toluene ug/L46 50.000 68-12791
Trichloroethene ug/L45 50.000 72-13290
ug/L 50.000 80-120Surr: Dibromofluoromethane 9849
ug/L 50.000 78-120Surr: 1,2-Dichloroethane-d4 9346
ug/L 50.000 80-120Surr: Toluene-d8 9950
ug/L 50.000 80-120Surr: 4-Bromofluorobenzene 9548
Matrix Spike (6030190-MS1)Prepared & Analyzed: 03/09/16 Source: AZC0180-11
Benzene ug/L42 50.000 ND 67-13484
Chlorobenzene ug/L55 50.000 ND 69-122110
1,1-Dichloroethene ug/L34 50.000 ND 58-14268
Toluene ug/L44 50.000 ND 68-12788
Trichloroethene ug/L43 50.000 ND 72-13286
ug/L 50.000 80-120Surr: Dibromofluoromethane 9145
ug/L 50.000 78-120Surr: 1,2-Dichloroethane-d4 9548
ug/L 50.000 80-120Surr: Toluene-d8 9849
ug/L 50.000 80-120Surr: 4-Bromofluorobenzene 10452
Matrix Spike Dup (6030190-MSD1)Prepared & Analyzed: 03/09/16 Source: AZC0180-11
Benzene ug/L47 50.000 ND 9 QR-0267-13494 12
Chlorobenzene ug/L58 50.000 ND 1369-122115 5
1,1-Dichloroethene ug/L40 50.000 ND 9 QR-0258-14280 16
Page 29 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Qual Analyte
Volatile Organic Compounds by EPA 8260 - Quality Control
Batch 6030190 - EPA 5030B
Matrix Spike Dup (6030190-MSD1)Prepared & Analyzed: 03/09/16 Source: AZC0180-11
Toluene ug/L50 50.000 ND 9 QR-0268-127101 13
Trichloroethene ug/L50 50.000 ND 11 QR-0272-132100 15
ug/L 50.000 80-120Surr: Dibromofluoromethane 8944
ug/L 50.000 78-120Surr: 1,2-Dichloroethane-d4 9648
ug/L 50.000 80-120Surr: Toluene-d8 9849
ug/L 50.000 80-120Surr: 4-Bromofluorobenzene 10552
Page 30 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
Laboratory Certifications
Code Description Number Expires
02069Louisiana 06/30/2016LA
381North Carolina 12/31/2016NC
E87315FL DOH (Non-Pot. Water, Solids) Eff:: 07/01/2015 06/30/2016NELAC
E87315FL DOH NELAC (Drinking Water) Eff: 07/01/2015 06/30/2016NELDW
98011001South Carolina 06/30/2016SC
T104704397-08-TXTexas 03/31/2016TX
1340Virginia 12/14/2016VA
Page 31 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
Legend
Defination of Laboratory Terms
- Not Detected at levels greater than or equal to SWSL/RLND
SWSL/RL
MDL
- NC DENR Solid Waste Section LImit/Reporting Limit (Adjusted for DF/Prep Factor)
- Method Detection Limit
Qualifiers
- Dilution FactorDF
QR-02 The RPD result exceeded the QC control limits; however, both percent recoveries were acceptable. Sample results for the QC batch were accepted based on
percent recoveries.
QM-05 The spike recovery was outside acceptance limits for the MS and/or MSD and/or PDS due to suspected matrix interference. Sample results for the QC batch
were accepted based on acceptable LCS recoveries.
J Estimated value less than Reporting Limit (RL) but greater than Method Detection Limit(MDL) (CLP J-Flag).
BOD-3 Lab Control (GGA) recovery was outside control limits biased low. Samples could not be reanalyzed due to holding time requirements. Batch associated
sample values are reported as estimated values with possible low bias.
Note: Unless otherwise noted, all results are reported on an as received basis.
Page 32 of 33
ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Matt Einsmann March 25, 2016
COC Goes Here
Page 33 of 33
LOG-IN CHECKLIST
Republic Services of North Carolina, LLC
Holly Springs Surface WatersProject:
Client:
Printed: 3/25/2016 10:07:53AM
Environmental Monitoring & Laboratory Analysis
[phone] FAX [phone]
110 Technology Parkway, Norcross, GA 30092
ANALYTICAL SERVICES, INC.ASI
Date Received:03/08/16 10:05 Logged In By:Charles Hawks
Work Order:AZC0222
OBSERVATIONS
Attn: Mr. Matt Einsmann
#Samples: 5 #Containers: 25
2.0 2.0
YES
Minimum Temp(C):Maximum Temp(C):
CHECKLIST ITEMS
COC included with Samples
Sample Container(s) Intact
Chain of Custody Complete
Sample Container(s) Match COC
Custody seal Intact
Temperature in Compliance
Sufficient Sample Volume for Analysis
Zero Headspace Maintained for VOA Analyses
Samples labeled preserved (If Applicable)
Samples received within Allowable Hold Times
Samples Received on Ice
Preservation Confirmed
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
Custody Seal(s) Used:Yes
Comments:
Page 1 of 1

Attachment B

#=CL#
May 23, 2016
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92295469
92295469
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
BFI HOLLY SPRINGS, NC
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on April 27, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc: Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 27
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92295469
BFI HOLLY SPRINGS, NC
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84Virginia/VELAP Certification #: 460221
Asheville Certification IDs2225 Riverside Drive, Asheville, NC 28804Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 27
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92295469
BFI HOLLY SPRINGS, NC
Lab ID Sample ID Matrix Date Collected Date Received
92295469001 SS-1 Solid 04/26/16 13:45 04/27/16 10:33
92295469002 SS-2 Solid 04/26/16 13:25 04/27/16 10:33
92295469003 SS-3 Solid 04/26/16 13:05 04/27/16 10:33
92295469004 BG Solid 04/26/16 12:40 04/27/16 10:33
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 27
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92295469
BFI HOLLY SPRINGS, NC
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92295469001 SS-1 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
EPA 9045 1 PASI-ATEP
92295469002 SS-2 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
EPA 9045 1 PASI-ATEP
92295469003 SS-3 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
EPA 9045 1 PASI-ATEP
92295469004 BG EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
EPA 9045 1 PASI-ATEP
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 27
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92295469
BFI HOLLY SPRINGS, NC
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92295469001 SS-1
Arsenic 3.9 mg/kg 05/05/16 15:090.70EPA 6010
Barium 123 mg/kg 05/05/16 15:090.35EPA 6010
Beryllium 0.25 mg/kg 05/05/16 15:090.070EPA 6010
Chromium 8.8 mg/kg 05/05/16 15:090.35EPA 6010
Cobalt 4.4 mg/kg 05/05/16 15:090.35EPA 6010
Copper 8.0 mg/kg 05/05/16 15:090.35EPA 6010
Lead 9.2 mg/kg 05/05/16 15:090.35EPA 6010
Nickel 7.2 mg/kg 05/05/16 15:090.35EPA 6010
Vanadium 19.0 mg/kg 05/05/16 15:090.35EPA 6010
Zinc 19.0 mg/kg 05/05/16 15:090.70EPA 6010
Methylene Chloride 1.7J ug/kg 04/28/16 18:287.9EPA 8260
Percent Moisture 15.8 %04/28/16 11:250.10ASTM D2974-87
pH at 25 Degrees C 7.2 Std. Units 05/05/16 16:15 H60.10EPA 9045
92295469002 SS-2
Arsenic 3.0 mg/kg 05/05/16 15:120.59EPA 6010
Barium 23.8 mg/kg 05/05/16 15:120.30EPA 6010
Beryllium 0.14 mg/kg 05/05/16 15:120.059EPA 6010
Chromium 5.1 mg/kg 05/05/16 15:120.30EPA 6010
Cobalt 2.5 mg/kg 05/05/16 15:120.30EPA 6010
Copper 5.8 mg/kg 05/05/16 15:120.30EPA 6010
Lead 6.4 mg/kg 05/05/16 15:120.30EPA 6010
Nickel 4.2 mg/kg 05/05/16 15:120.30EPA 6010
Vanadium 10.4 mg/kg 05/05/16 15:120.30EPA 6010
Zinc 29.9 mg/kg 05/05/16 15:120.59EPA 6010
Acetone 12.0J ug/kg 04/28/16 18:4834.7EPA 8260
Methylene Chloride 1.5J ug/kg 04/28/16 18:486.9EPA 8260
Toluene 4.8 ug/kg 04/28/16 18:481.7EPA 8260
Percent Moisture 13.6 %04/28/16 11:250.10ASTM D2974-87
pH at 25 Degrees C 8.0 Std. Units 05/05/16 16:15 H60.10EPA 9045
92295469003 SS-3
Arsenic 9.1 mg/kg 05/05/16 15:150.63EPA 6010
Barium 28.8 mg/kg 05/05/16 15:150.31EPA 6010
Beryllium 0.48 mg/kg 05/05/16 15:150.063EPA 6010
Chromium 2.8 mg/kg 05/05/16 15:150.31EPA 6010
Cobalt 2.0 mg/kg 05/05/16 15:150.31EPA 6010
Copper 3.0 mg/kg 05/05/16 15:150.31EPA 6010
Lead 7.8 mg/kg 05/05/16 15:150.31EPA 6010
Nickel 3.6 mg/kg 05/05/16 15:150.31EPA 6010
Selenium 0.36J mg/kg 05/05/16 15:150.63EPA 6010
Vanadium 10.2 mg/kg 05/05/16 15:150.31EPA 6010
Zinc 10.5 mg/kg 05/05/16 15:150.63EPA 6010
Methylene Chloride 2.8J ug/kg 04/28/16 19:089.0EPA 8260
Percent Moisture 13.3 %04/28/16 11:260.10ASTM D2974-87
pH at 25 Degrees C 7.9 Std. Units 05/05/16 16:15 H60.10EPA 9045
92295469004 BG
Arsenic 1.2 mg/kg 05/05/16 15:180.60EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 27
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92295469
BFI HOLLY SPRINGS, NC
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92295469004 BG
Barium 15.8 mg/kg 05/05/16 15:180.30EPA 6010
Beryllium 0.10 mg/kg 05/05/16 15:180.060EPA 6010
Chromium 3.1 mg/kg 05/05/16 15:180.30EPA 6010
Cobalt 1.4 mg/kg 05/05/16 15:180.30EPA 6010
Copper 1.3 mg/kg 05/05/16 15:180.30EPA 6010
Lead 3.7 mg/kg 05/05/16 15:180.30EPA 6010
Nickel 1.7 mg/kg 05/05/16 15:180.30EPA 6010
Vanadium 7.1 mg/kg 05/05/16 15:180.30EPA 6010
Zinc 4.4 mg/kg 05/05/16 15:180.60EPA 6010
Acetone 18.7J ug/kg 04/28/16 19:2834.0EPA 8260
Methylene Chloride 1.8J ug/kg 04/28/16 19:286.8EPA 8260
Percent Moisture 11.0 %04/28/16 11:260.10ASTM D2974-87
pH at 25 Degrees C 5.0 Std. Units 05/05/16 16:15 H60.10EPA 9045
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92295469
BFI HOLLY SPRINGS, NC
Sample: SS-1 Lab ID: 92295469001 Collected: 04/26/16 13:45 Received: 04/27/16 10:33 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Antimony ND mg/kg 05/05/16 15:09 7440-36-005/04/16 16:300.35 0.27 1
Arsenic 3.9 mg/kg 05/05/16 15:09 7440-38-205/04/16 16:300.70 0.35 1
Barium 123 mg/kg 05/05/16 15:09 7440-39-305/04/16 16:300.35 0.17 1
Beryllium 0.25 mg/kg 05/05/16 15:09 7440-41-705/04/16 16:300.070 0.035 1
Cadmium ND mg/kg 05/05/16 15:09 7440-43-905/04/16 16:300.070 0.035 1
Chromium 8.8 mg/kg 05/05/16 15:09 7440-47-305/04/16 16:300.35 0.17 1
Cobalt 4.4 mg/kg 05/05/16 15:09 7440-48-405/04/16 16:300.35 0.17 1
Copper 8.0 mg/kg 05/05/16 15:09 7440-50-805/04/16 16:300.35 0.17 1
Lead 9.2 mg/kg 05/05/16 15:09 7439-92-105/04/16 16:300.35 0.17 1
Nickel 7.2 mg/kg 05/05/16 15:09 7440-02-005/04/16 16:300.35 0.17 1
Selenium ND mg/kg 05/05/16 15:09 7782-49-205/04/16 16:300.70 0.35 1
Silver ND mg/kg 05/05/16 15:09 7440-22-405/04/16 16:300.35 0.17 1
Thallium ND mg/kg 05/05/16 15:09 7440-28-005/04/16 16:300.70 0.35 1
Vanadium 19.0 mg/kg 05/05/16 15:09 7440-62-205/04/16 16:300.35 0.17 1
Zinc 19.0 mg/kg 05/05/16 15:09 7440-66-605/04/16 16:300.70 0.35 1
Analytical Method: EPA 82608260/5035A Volatile Organics
Acetone ND ug/kg 04/28/16 18:28 67-64-1 M139.5 3.9 1
Acrylonitrile ND ug/kg 04/28/16 18:28 107-13-139.5 10.3 1
Benzene ND ug/kg 04/28/16 18:28 71-43-22.0 0.63 1
Bromochloromethane ND ug/kg 04/28/16 18:28 74-97-52.0 0.67 1
Bromodichloromethane ND ug/kg 04/28/16 18:28 75-27-42.0 0.75 1
Bromoform ND ug/kg 04/28/16 18:28 75-25-22.0 0.91 1
Bromomethane ND ug/kg 04/28/16 18:28 74-83-93.9 0.99 1
2-Butanone (MEK)ND ug/kg 04/28/16 18:28 78-93-3 M139.5 1.1 1
Carbon disulfide ND ug/kg 04/28/16 18:28 75-15-03.9 1.2 1
Carbon tetrachloride ND ug/kg 04/28/16 18:28 56-23-52.0 1.0 1
Chlorobenzene ND ug/kg 04/28/16 18:28 108-90-72.0 0.75 1
Chloroethane ND ug/kg 04/28/16 18:28 75-00-33.9 0.95 1
Chloroform ND ug/kg 04/28/16 18:28 67-66-32.0 0.63 1
Chloromethane ND ug/kg 04/28/16 18:28 74-87-33.9 0.95 1
1,2-Dibromo-3-chloropropane ND ug/kg 04/28/16 18:28 96-12-82.0 1.4 1
Dibromochloromethane ND ug/kg 04/28/16 18:28 124-48-12.0 0.71 1
1,2-Dibromoethane (EDB)ND ug/kg 04/28/16 18:28 106-93-42.0 0.71 1
Dibromomethane ND ug/kg 04/28/16 18:28 74-95-32.0 0.99 1
1,2-Dichlorobenzene ND ug/kg 04/28/16 18:28 95-50-12.0 0.75 1
1,4-Dichlorobenzene ND ug/kg 04/28/16 18:28 106-46-72.0 0.67 1
trans-1,4-Dichloro-2-butene ND ug/kg 04/28/16 18:28 110-57-62.0 1.4 1
1,1-Dichloroethane ND ug/kg 04/28/16 18:28 75-34-32.0 0.59 1
1,2-Dichloroethane ND ug/kg 04/28/16 18:28 107-06-22.0 0.87 1
1,1-Dichloroethene ND ug/kg 04/28/16 18:28 75-35-42.0 0.71 1
cis-1,2-Dichloroethene ND ug/kg 04/28/16 18:28 156-59-22.0 0.55 1
trans-1,2-Dichloroethene ND ug/kg 04/28/16 18:28 156-60-52.0 0.75 1
1,2-Dichloropropane ND ug/kg 04/28/16 18:28 78-87-52.0 0.67 1
cis-1,3-Dichloropropene ND ug/kg 04/28/16 18:28 10061-01-52.0 0.71 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92295469
BFI HOLLY SPRINGS, NC
Sample: SS-1 Lab ID: 92295469001 Collected: 04/26/16 13:45 Received: 04/27/16 10:33 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260/5035A Volatile Organics
trans-1,3-Dichloropropene ND ug/kg 04/28/16 18:28 10061-02-62.0 0.59 1
Ethylbenzene ND ug/kg 04/28/16 18:28 100-41-42.0 0.71 1
2-Hexanone ND ug/kg 04/28/16 18:28 591-78-6 M119.7 1.5 1
Iodomethane ND ug/kg 04/28/16 18:28 74-88-43.9 3.9 1
Methylene Chloride 1.7J ug/kg 04/28/16 18:28 75-09-27.9 1.2 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 04/28/16 18:28 108-10-119.7 1.5 1
Styrene ND ug/kg 04/28/16 18:28 100-42-52.0 0.71 1
1,1,1,2-Tetrachloroethane ND ug/kg 04/28/16 18:28 630-20-62.0 0.83 1
1,1,2,2-Tetrachloroethane ND ug/kg 04/28/16 18:28 79-34-52.0 0.75 1
Tetrachloroethene ND ug/kg 04/28/16 18:28 127-18-42.0 0.67 1
Toluene ND ug/kg 04/28/16 18:28 108-88-32.0 0.71 1
1,1,1-Trichloroethane ND ug/kg 04/28/16 18:28 71-55-62.0 0.71 1
1,1,2-Trichloroethane ND ug/kg 04/28/16 18:28 79-00-52.0 0.83 1
Trichloroethene ND ug/kg 04/28/16 18:28 79-01-62.0 0.83 1
Trichlorofluoromethane ND ug/kg 04/28/16 18:28 75-69-42.0 0.87 1
1,2,3-Trichloropropane ND ug/kg 04/28/16 18:28 96-18-42.0 0.63 1
Vinyl acetate ND ug/kg 04/28/16 18:28 108-05-419.7 3.5 1
Vinyl chloride ND ug/kg 04/28/16 18:28 75-01-43.9 0.71 1
Xylene (Total)ND ug/kg 04/28/16 18:28 1330-20-73.9 1.4 1
Surrogates
Toluene-d8 (S)100 %04/28/16 18:28 2037-26-570-130 1
4-Bromofluorobenzene (S)97 %04/28/16 18:28 460-00-470-130 1
1,2-Dichloroethane-d4 (S)92 %04/28/16 18:28 17060-07-070-132 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 15.8 %04/28/16 11:250.10 0.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 7.2 Std. Units 05/05/16 16:15 H60.10 0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92295469
BFI HOLLY SPRINGS, NC
Sample: SS-2 Lab ID: 92295469002 Collected: 04/26/16 13:25 Received: 04/27/16 10:33 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Antimony ND mg/kg 05/05/16 15:12 7440-36-005/04/16 16:300.30 0.23 1
Arsenic 3.0 mg/kg 05/05/16 15:12 7440-38-205/04/16 16:300.59 0.30 1
Barium 23.8 mg/kg 05/05/16 15:12 7440-39-305/04/16 16:300.30 0.15 1
Beryllium 0.14 mg/kg 05/05/16 15:12 7440-41-705/04/16 16:300.059 0.030 1
Cadmium ND mg/kg 05/05/16 15:12 7440-43-905/04/16 16:300.059 0.030 1
Chromium 5.1 mg/kg 05/05/16 15:12 7440-47-305/04/16 16:300.30 0.15 1
Cobalt 2.5 mg/kg 05/05/16 15:12 7440-48-405/04/16 16:300.30 0.15 1
Copper 5.8 mg/kg 05/05/16 15:12 7440-50-805/04/16 16:300.30 0.15 1
Lead 6.4 mg/kg 05/05/16 15:12 7439-92-105/04/16 16:300.30 0.15 1
Nickel 4.2 mg/kg 05/05/16 15:12 7440-02-005/04/16 16:300.30 0.15 1
Selenium ND mg/kg 05/05/16 15:12 7782-49-205/04/16 16:300.59 0.30 1
Silver ND mg/kg 05/05/16 15:12 7440-22-405/04/16 16:300.30 0.15 1
Thallium ND mg/kg 05/05/16 15:12 7440-28-005/04/16 16:300.59 0.30 1
Vanadium 10.4 mg/kg 05/05/16 15:12 7440-62-205/04/16 16:300.30 0.15 1
Zinc 29.9 mg/kg 05/05/16 15:12 7440-66-605/04/16 16:300.59 0.30 1
Analytical Method: EPA 82608260/5035A Volatile Organics
Acetone 12.0J ug/kg 04/28/16 18:48 67-64-134.7 3.5 1
Acrylonitrile ND ug/kg 04/28/16 18:48 107-13-134.7 9.0 1
Benzene ND ug/kg 04/28/16 18:48 71-43-21.7 0.56 1
Bromochloromethane ND ug/kg 04/28/16 18:48 74-97-51.7 0.59 1
Bromodichloromethane ND ug/kg 04/28/16 18:48 75-27-41.7 0.66 1
Bromoform ND ug/kg 04/28/16 18:48 75-25-21.7 0.80 1
Bromomethane ND ug/kg 04/28/16 18:48 74-83-93.5 0.87 1
2-Butanone (MEK)ND ug/kg 04/28/16 18:48 78-93-334.7 1.0 1
Carbon disulfide ND ug/kg 04/28/16 18:48 75-15-03.5 1.0 1
Carbon tetrachloride ND ug/kg 04/28/16 18:48 56-23-51.7 0.90 1
Chlorobenzene ND ug/kg 04/28/16 18:48 108-90-71.7 0.66 1
Chloroethane ND ug/kg 04/28/16 18:48 75-00-33.5 0.83 1
Chloroform ND ug/kg 04/28/16 18:48 67-66-31.7 0.56 1
Chloromethane ND ug/kg 04/28/16 18:48 74-87-33.5 0.83 1
1,2-Dibromo-3-chloropropane ND ug/kg 04/28/16 18:48 96-12-81.7 1.2 1
Dibromochloromethane ND ug/kg 04/28/16 18:48 124-48-11.7 0.62 1
1,2-Dibromoethane (EDB)ND ug/kg 04/28/16 18:48 106-93-41.7 0.62 1
Dibromomethane ND ug/kg 04/28/16 18:48 74-95-31.7 0.87 1
1,2-Dichlorobenzene ND ug/kg 04/28/16 18:48 95-50-11.7 0.66 1
1,4-Dichlorobenzene ND ug/kg 04/28/16 18:48 106-46-71.7 0.59 1
trans-1,4-Dichloro-2-butene ND ug/kg 04/28/16 18:48 110-57-61.7 1.2 1
1,1-Dichloroethane ND ug/kg 04/28/16 18:48 75-34-31.7 0.52 1
1,2-Dichloroethane ND ug/kg 04/28/16 18:48 107-06-21.7 0.76 1
1,1-Dichloroethene ND ug/kg 04/28/16 18:48 75-35-41.7 0.62 1
cis-1,2-Dichloroethene ND ug/kg 04/28/16 18:48 156-59-21.7 0.49 1
trans-1,2-Dichloroethene ND ug/kg 04/28/16 18:48 156-60-51.7 0.66 1
1,2-Dichloropropane ND ug/kg 04/28/16 18:48 78-87-51.7 0.59 1
cis-1,3-Dichloropropene ND ug/kg 04/28/16 18:48 10061-01-51.7 0.62 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92295469
BFI HOLLY SPRINGS, NC
Sample: SS-2 Lab ID: 92295469002 Collected: 04/26/16 13:25 Received: 04/27/16 10:33 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260/5035A Volatile Organics
trans-1,3-Dichloropropene ND ug/kg 04/28/16 18:48 10061-02-61.7 0.52 1
Ethylbenzene ND ug/kg 04/28/16 18:48 100-41-41.7 0.62 1
2-Hexanone ND ug/kg 04/28/16 18:48 591-78-617.4 1.4 1
Iodomethane ND ug/kg 04/28/16 18:48 74-88-43.5 3.4 1
Methylene Chloride 1.5J ug/kg 04/28/16 18:48 75-09-26.9 1.0 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 04/28/16 18:48 108-10-117.4 1.3 1
Styrene ND ug/kg 04/28/16 18:48 100-42-51.7 0.62 1
1,1,1,2-Tetrachloroethane ND ug/kg 04/28/16 18:48 630-20-61.7 0.73 1
1,1,2,2-Tetrachloroethane ND ug/kg 04/28/16 18:48 79-34-51.7 0.66 1
Tetrachloroethene ND ug/kg 04/28/16 18:48 127-18-41.7 0.59 1
Toluene 4.8 ug/kg 04/28/16 18:48 108-88-31.7 0.62 1
1,1,1-Trichloroethane ND ug/kg 04/28/16 18:48 71-55-61.7 0.62 1
1,1,2-Trichloroethane ND ug/kg 04/28/16 18:48 79-00-51.7 0.73 1
Trichloroethene ND ug/kg 04/28/16 18:48 79-01-61.7 0.73 1
Trichlorofluoromethane ND ug/kg 04/28/16 18:48 75-69-41.7 0.76 1
1,2,3-Trichloropropane ND ug/kg 04/28/16 18:48 96-18-41.7 0.56 1
Vinyl acetate ND ug/kg 04/28/16 18:48 108-05-417.4 3.1 1
Vinyl chloride ND ug/kg 04/28/16 18:48 75-01-43.5 0.62 1
Xylene (Total)ND ug/kg 04/28/16 18:48 1330-20-73.5 1.2 1
Surrogates
Toluene-d8 (S)101 %04/28/16 18:48 2037-26-570-130 1
4-Bromofluorobenzene (S)94 %04/28/16 18:48 460-00-470-130 1
1,2-Dichloroethane-d4 (S)94 %04/28/16 18:48 17060-07-070-132 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 13.6 %04/28/16 11:250.10 0.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 8.0 Std. Units 05/05/16 16:15 H60.10 0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92295469
BFI HOLLY SPRINGS, NC
Sample: SS-3 Lab ID: 92295469003 Collected: 04/26/16 13:05 Received: 04/27/16 10:33 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Antimony ND mg/kg 05/05/16 15:15 7440-36-005/04/16 16:300.31 0.24 1
Arsenic 9.1 mg/kg 05/05/16 15:15 7440-38-205/04/16 16:300.63 0.31 1
Barium 28.8 mg/kg 05/05/16 15:15 7440-39-305/04/16 16:300.31 0.16 1
Beryllium 0.48 mg/kg 05/05/16 15:15 7440-41-705/04/16 16:300.063 0.031 1
Cadmium ND mg/kg 05/05/16 15:15 7440-43-905/04/16 16:300.063 0.031 1
Chromium 2.8 mg/kg 05/05/16 15:15 7440-47-305/04/16 16:300.31 0.16 1
Cobalt 2.0 mg/kg 05/05/16 15:15 7440-48-405/04/16 16:300.31 0.16 1
Copper 3.0 mg/kg 05/05/16 15:15 7440-50-805/04/16 16:300.31 0.16 1
Lead 7.8 mg/kg 05/05/16 15:15 7439-92-105/04/16 16:300.31 0.16 1
Nickel 3.6 mg/kg 05/05/16 15:15 7440-02-005/04/16 16:300.31 0.16 1
Selenium 0.36J mg/kg 05/05/16 15:15 7782-49-205/04/16 16:300.63 0.31 1
Silver ND mg/kg 05/05/16 15:15 7440-22-405/04/16 16:300.31 0.16 1
Thallium ND mg/kg 05/05/16 15:15 7440-28-005/04/16 16:300.63 0.31 1
Vanadium 10.2 mg/kg 05/05/16 15:15 7440-62-205/04/16 16:300.31 0.16 1
Zinc 10.5 mg/kg 05/05/16 15:15 7440-66-605/04/16 16:300.63 0.31 1
Analytical Method: EPA 82608260/5035A Volatile Organics
Acetone ND ug/kg 04/28/16 19:08 67-64-145.2 4.5 1
Acrylonitrile ND ug/kg 04/28/16 19:08 107-13-145.2 11.7 1
Benzene ND ug/kg 04/28/16 19:08 71-43-22.3 0.72 1
Bromochloromethane ND ug/kg 04/28/16 19:08 74-97-52.3 0.77 1
Bromodichloromethane ND ug/kg 04/28/16 19:08 75-27-42.3 0.86 1
Bromoform ND ug/kg 04/28/16 19:08 75-25-22.3 1.0 1
Bromomethane ND ug/kg 04/28/16 19:08 74-83-94.5 1.1 1
2-Butanone (MEK)ND ug/kg 04/28/16 19:08 78-93-345.2 1.3 1
Carbon disulfide ND ug/kg 04/28/16 19:08 75-15-04.5 1.4 1
Carbon tetrachloride ND ug/kg 04/28/16 19:08 56-23-52.3 1.2 1
Chlorobenzene ND ug/kg 04/28/16 19:08 108-90-72.3 0.86 1
Chloroethane ND ug/kg 04/28/16 19:08 75-00-34.5 1.1 1
Chloroform ND ug/kg 04/28/16 19:08 67-66-32.3 0.72 1
Chloromethane ND ug/kg 04/28/16 19:08 74-87-34.5 1.1 1
1,2-Dibromo-3-chloropropane ND ug/kg 04/28/16 19:08 96-12-82.3 1.6 1
Dibromochloromethane ND ug/kg 04/28/16 19:08 124-48-12.3 0.81 1
1,2-Dibromoethane (EDB)ND ug/kg 04/28/16 19:08 106-93-42.3 0.81 1
Dibromomethane ND ug/kg 04/28/16 19:08 74-95-32.3 1.1 1
1,2-Dichlorobenzene ND ug/kg 04/28/16 19:08 95-50-12.3 0.86 1
1,4-Dichlorobenzene ND ug/kg 04/28/16 19:08 106-46-72.3 0.77 1
trans-1,4-Dichloro-2-butene ND ug/kg 04/28/16 19:08 110-57-62.3 1.6 1
1,1-Dichloroethane ND ug/kg 04/28/16 19:08 75-34-32.3 0.68 1
1,2-Dichloroethane ND ug/kg 04/28/16 19:08 107-06-22.3 0.99 1
1,1-Dichloroethene ND ug/kg 04/28/16 19:08 75-35-42.3 0.81 1
cis-1,2-Dichloroethene ND ug/kg 04/28/16 19:08 156-59-22.3 0.63 1
trans-1,2-Dichloroethene ND ug/kg 04/28/16 19:08 156-60-52.3 0.86 1
1,2-Dichloropropane ND ug/kg 04/28/16 19:08 78-87-52.3 0.77 1
cis-1,3-Dichloropropene ND ug/kg 04/28/16 19:08 10061-01-52.3 0.81 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92295469
BFI HOLLY SPRINGS, NC
Sample: SS-3 Lab ID: 92295469003 Collected: 04/26/16 13:05 Received: 04/27/16 10:33 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260/5035A Volatile Organics
trans-1,3-Dichloropropene ND ug/kg 04/28/16 19:08 10061-02-62.3 0.68 1
Ethylbenzene ND ug/kg 04/28/16 19:08 100-41-42.3 0.81 1
2-Hexanone ND ug/kg 04/28/16 19:08 591-78-622.6 1.8 1
Iodomethane ND ug/kg 04/28/16 19:08 74-88-44.5 4.5 1
Methylene Chloride 2.8J ug/kg 04/28/16 19:08 75-09-29.0 1.4 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 04/28/16 19:08 108-10-122.6 1.7 1
Styrene ND ug/kg 04/28/16 19:08 100-42-52.3 0.81 1
1,1,1,2-Tetrachloroethane ND ug/kg 04/28/16 19:08 630-20-62.3 0.95 1
1,1,2,2-Tetrachloroethane ND ug/kg 04/28/16 19:08 79-34-52.3 0.86 1
Tetrachloroethene ND ug/kg 04/28/16 19:08 127-18-42.3 0.77 1
Toluene ND ug/kg 04/28/16 19:08 108-88-32.3 0.81 1
1,1,1-Trichloroethane ND ug/kg 04/28/16 19:08 71-55-62.3 0.81 1
1,1,2-Trichloroethane ND ug/kg 04/28/16 19:08 79-00-52.3 0.95 1
Trichloroethene ND ug/kg 04/28/16 19:08 79-01-62.3 0.95 1
Trichlorofluoromethane ND ug/kg 04/28/16 19:08 75-69-42.3 0.99 1
1,2,3-Trichloropropane ND ug/kg 04/28/16 19:08 96-18-42.3 0.72 1
Vinyl acetate ND ug/kg 04/28/16 19:08 108-05-422.6 4.0 1
Vinyl chloride ND ug/kg 04/28/16 19:08 75-01-44.5 0.81 1
Xylene (Total)ND ug/kg 04/28/16 19:08 1330-20-74.5 1.6 1
Surrogates
Toluene-d8 (S)99 %04/28/16 19:08 2037-26-570-130 1
4-Bromofluorobenzene (S)99 %04/28/16 19:08 460-00-470-130 1
1,2-Dichloroethane-d4 (S)95 %04/28/16 19:08 17060-07-070-132 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 13.3 %04/28/16 11:260.10 0.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 7.9 Std. Units 05/05/16 16:15 H60.10 0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92295469
BFI HOLLY SPRINGS, NC
Sample: BG Lab ID: 92295469004 Collected: 04/26/16 12:40 Received: 04/27/16 10:33 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Antimony ND mg/kg 05/05/16 15:18 7440-36-005/04/16 16:300.30 0.24 1
Arsenic 1.2 mg/kg 05/05/16 15:18 7440-38-205/04/16 16:300.60 0.30 1
Barium 15.8 mg/kg 05/05/16 15:18 7440-39-305/04/16 16:300.30 0.15 1
Beryllium 0.10 mg/kg 05/05/16 15:18 7440-41-705/04/16 16:300.060 0.030 1
Cadmium ND mg/kg 05/05/16 15:18 7440-43-905/04/16 16:300.060 0.030 1
Chromium 3.1 mg/kg 05/05/16 15:18 7440-47-305/04/16 16:300.30 0.15 1
Cobalt 1.4 mg/kg 05/05/16 15:18 7440-48-405/04/16 16:300.30 0.15 1
Copper 1.3 mg/kg 05/05/16 15:18 7440-50-805/04/16 16:300.30 0.15 1
Lead 3.7 mg/kg 05/05/16 15:18 7439-92-105/04/16 16:300.30 0.15 1
Nickel 1.7 mg/kg 05/05/16 15:18 7440-02-005/04/16 16:300.30 0.15 1
Selenium ND mg/kg 05/05/16 15:18 7782-49-205/04/16 16:300.60 0.30 1
Silver ND mg/kg 05/05/16 15:18 7440-22-405/04/16 16:300.30 0.15 1
Thallium ND mg/kg 05/05/16 15:18 7440-28-005/04/16 16:300.60 0.30 1
Vanadium 7.1 mg/kg 05/05/16 15:18 7440-62-205/04/16 16:300.30 0.15 1
Zinc 4.4 mg/kg 05/05/16 15:18 7440-66-605/04/16 16:300.60 0.30 1
Analytical Method: EPA 82608260/5035A Volatile Organics
Acetone 18.7J ug/kg 04/28/16 19:28 67-64-134.0 3.4 1
Acrylonitrile ND ug/kg 04/28/16 19:28 107-13-134.0 8.8 1
Benzene ND ug/kg 04/28/16 19:28 71-43-21.7 0.54 1
Bromochloromethane ND ug/kg 04/28/16 19:28 74-97-51.7 0.58 1
Bromodichloromethane ND ug/kg 04/28/16 19:28 75-27-41.7 0.65 1
Bromoform ND ug/kg 04/28/16 19:28 75-25-21.7 0.78 1
Bromomethane ND ug/kg 04/28/16 19:28 74-83-93.4 0.85 1
2-Butanone (MEK)ND ug/kg 04/28/16 19:28 78-93-334.0 0.98 1
Carbon disulfide ND ug/kg 04/28/16 19:28 75-15-03.4 1.0 1
Carbon tetrachloride ND ug/kg 04/28/16 19:28 56-23-51.7 0.88 1
Chlorobenzene ND ug/kg 04/28/16 19:28 108-90-71.7 0.65 1
Chloroethane ND ug/kg 04/28/16 19:28 75-00-33.4 0.81 1
Chloroform ND ug/kg 04/28/16 19:28 67-66-31.7 0.54 1
Chloromethane ND ug/kg 04/28/16 19:28 74-87-33.4 0.81 1
1,2-Dibromo-3-chloropropane ND ug/kg 04/28/16 19:28 96-12-81.7 1.2 1
Dibromochloromethane ND ug/kg 04/28/16 19:28 124-48-11.7 0.61 1
1,2-Dibromoethane (EDB)ND ug/kg 04/28/16 19:28 106-93-41.7 0.61 1
Dibromomethane ND ug/kg 04/28/16 19:28 74-95-31.7 0.85 1
1,2-Dichlorobenzene ND ug/kg 04/28/16 19:28 95-50-11.7 0.65 1
1,4-Dichlorobenzene ND ug/kg 04/28/16 19:28 106-46-71.7 0.58 1
trans-1,4-Dichloro-2-butene ND ug/kg 04/28/16 19:28 110-57-61.7 1.2 1
1,1-Dichloroethane ND ug/kg 04/28/16 19:28 75-34-31.7 0.51 1
1,2-Dichloroethane ND ug/kg 04/28/16 19:28 107-06-21.7 0.75 1
1,1-Dichloroethene ND ug/kg 04/28/16 19:28 75-35-41.7 0.61 1
cis-1,2-Dichloroethene ND ug/kg 04/28/16 19:28 156-59-21.7 0.48 1
trans-1,2-Dichloroethene ND ug/kg 04/28/16 19:28 156-60-51.7 0.65 1
1,2-Dichloropropane ND ug/kg 04/28/16 19:28 78-87-51.7 0.58 1
cis-1,3-Dichloropropene ND ug/kg 04/28/16 19:28 10061-01-51.7 0.61 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 03:29 PM
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Huntersville, NC 28078
[phone]
Page 13 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92295469
BFI HOLLY SPRINGS, NC
Sample: BG Lab ID: 92295469004 Collected: 04/26/16 12:40 Received: 04/27/16 10:33 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260/5035A Volatile Organics
trans-1,3-Dichloropropene ND ug/kg 04/28/16 19:28 10061-02-61.7 0.51 1
Ethylbenzene ND ug/kg 04/28/16 19:28 100-41-41.7 0.61 1
2-Hexanone ND ug/kg 04/28/16 19:28 591-78-617.0 1.3 1
Iodomethane ND ug/kg 04/28/16 19:28 74-88-43.4 3.4 1
Methylene Chloride 1.8J ug/kg 04/28/16 19:28 75-09-26.8 1.0 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 04/28/16 19:28 108-10-117.0 1.3 1
Styrene ND ug/kg 04/28/16 19:28 100-42-51.7 0.61 1
1,1,1,2-Tetrachloroethane ND ug/kg 04/28/16 19:28 630-20-61.7 0.71 1
1,1,2,2-Tetrachloroethane ND ug/kg 04/28/16 19:28 79-34-51.7 0.65 1
Tetrachloroethene ND ug/kg 04/28/16 19:28 127-18-41.7 0.58 1
Toluene ND ug/kg 04/28/16 19:28 108-88-31.7 0.61 1
1,1,1-Trichloroethane ND ug/kg 04/28/16 19:28 71-55-61.7 0.61 1
1,1,2-Trichloroethane ND ug/kg 04/28/16 19:28 79-00-51.7 0.71 1
Trichloroethene ND ug/kg 04/28/16 19:28 79-01-61.7 0.71 1
Trichlorofluoromethane ND ug/kg 04/28/16 19:28 75-69-41.7 0.75 1
1,2,3-Trichloropropane ND ug/kg 04/28/16 19:28 96-18-41.7 0.54 1
Vinyl acetate ND ug/kg 04/28/16 19:28 108-05-417.0 3.0 1
Vinyl chloride ND ug/kg 04/28/16 19:28 75-01-43.4 0.61 1
Xylene (Total)ND ug/kg 04/28/16 19:28 1330-20-73.4 1.2 1
Surrogates
Toluene-d8 (S)99 %04/28/16 19:28 2037-26-570-130 1
4-Bromofluorobenzene (S)93 %04/28/16 19:28 460-00-470-130 1
1,2-Dichloroethane-d4 (S)95 %04/28/16 19:28 17060-07-070-132 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 11.0 %04/28/16 11:260.10 0.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 5.0 Std. Units 05/05/16 16:15 H60.10 0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92295469
BFI HOLLY SPRINGS, NC
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/21597
EPA 3050
EPA 6010
6010 MET
Associated Lab Samples: 92295469001, 92295469002, 92295469003, 92295469004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1725284
Associated Lab Samples:92295469001, 92295469002, 92295469003, 92295469004
Matrix: Solid
AnalyzedMDL
Antimony mg/kg ND 0.50 05/05/16 14:350.39
Arsenic mg/kg ND 1.0 05/05/16 14:350.50
Barium mg/kg ND 0.50 05/05/16 14:350.25
Beryllium mg/kg ND 0.10 05/05/16 14:350.050
Cadmium mg/kg ND 0.10 05/05/16 14:350.050
Chromium mg/kg ND 0.50 05/05/16 14:350.25
Cobalt mg/kg ND 0.50 05/05/16 14:350.25
Copper mg/kg ND 0.50 05/05/16 14:350.25
Lead mg/kg ND 0.50 05/05/16 14:350.25
Nickel mg/kg ND 0.50 05/05/16 14:350.25
Selenium mg/kg ND 1.0 05/05/16 14:350.50
Silver mg/kg ND 0.50 05/05/16 14:350.25
Thallium mg/kg ND 1.0 05/05/16 14:350.50
Vanadium mg/kg ND 0.50 05/05/16 14:350.25
Zinc mg/kg ND 1.0 05/05/16 14:350.50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1725285LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony mg/kg 49.350 99 80-120
Arsenic mg/kg 48.350 97 80-120
Barium mg/kg 49.550 99 80-120
Beryllium mg/kg 49.650 99 80-120
Cadmium mg/kg 49.650 99 80-120
Chromium mg/kg 50.250 100 80-120
Cobalt mg/kg 49.050 98 80-120
Copper mg/kg 50.150 100 80-120
Lead mg/kg 48.850 98 80-120
Nickel mg/kg 49.450 99 80-120
Selenium mg/kg 48.850 98 80-120
Silver mg/kg 25.225 101 80-120
Thallium mg/kg 48.550 97 80-120
Vanadium mg/kg 48.850 98 80-120
Zinc mg/kg 48.350 97 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92295469
BFI HOLLY SPRINGS, NC
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1725286MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92291659001
1725287
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony mg/kg M1,R141.4 45 75-12546 29 2030.6ND 18.7 14.0
Arsenic mg/kg R141.4 85 75-12587 27 2030.60.68 35.9 27.3
Barium mg/kg R141.4 98 75-12589 27 2030.615.0 55.6 42.2
Beryllium mg/kg R141.4 94 75-12593 31 2030.60.091 39.0 28.4
Cadmium mg/kg R141.4 92 75-12592 30 2030.6ND 38.3 28.2
Chromium mg/kg 41.4 94 75-125106 16 2030.64.6 43.4 36.9
Cobalt mg/kg R141.4 90 75-12589 31 2030.6ND 37.5 27.5
Copper mg/kg 41.4 96 75-125104 20 2030.64.1 43.7 35.8
Lead mg/kg R141.4 89 75-12591 24 2030.63.7 40.3 31.6
Nickel mg/kg R141.4 91 75-12592 29 2030.60.49 38.1 28.6
Selenium mg/kg R141.4 84 75-12581 33 2030.6ND 35.4 25.2
Silver mg/kg R120.7 94 75-12594 30 2015.3ND 19.5 14.4
Thallium mg/kg R141.4 87 75-12584 34 2030.6ND 36.3 25.9
Vanadium mg/kg M141.4 74 75-125129 16 2030.618.1 48.9 57.6
Zinc mg/kg R141.4 89 75-12591 26 2030.62.5 39.5 30.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92295469
BFI HOLLY SPRINGS, NC
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/36605
EPA 8260
EPA 8260
8260 MSV 5035A Volatile Organics
Associated Lab Samples: 92295469001, 92295469002, 92295469003, 92295469004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1722049
Associated Lab Samples:92295469001, 92295469002, 92295469003, 92295469004
Matrix: Solid
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/kg ND 6.9 04/28/16 15:292.9
1,1,1-Trichloroethane ug/kg ND 6.9 04/28/16 15:292.5
1,1,2,2-Tetrachloroethane ug/kg ND 6.9 04/28/16 15:292.6
1,1,2-Trichloroethane ug/kg ND 6.9 04/28/16 15:292.9
1,1-Dichloroethane ug/kg ND 6.9 04/28/16 15:292.1
1,1-Dichloroethene ug/kg ND 6.9 04/28/16 15:292.5
1,2,3-Trichloropropane ug/kg ND 6.9 04/28/16 15:292.2
1,2-Dibromo-3-chloropropane ug/kg ND 6.9 04/28/16 15:294.9
1,2-Dibromoethane (EDB)ug/kg ND 6.9 04/28/16 15:292.5
1,2-Dichlorobenzene ug/kg ND 6.9 04/28/16 15:292.6
1,2-Dichloroethane ug/kg ND 6.9 04/28/16 15:293.0
1,2-Dichloropropane ug/kg ND 6.9 04/28/16 15:292.3
1,4-Dichlorobenzene ug/kg ND 6.9 04/28/16 15:292.3
2-Butanone (MEK)ug/kg ND 137 04/28/16 15:294.0
2-Hexanone ug/kg ND 68.7 04/28/16 15:295.4
4-Methyl-2-pentanone (MIBK)ug/kg ND 68.7 04/28/16 15:295.1
Acetone ug/kg ND 137 04/28/16 15:2913.7
Acrylonitrile ug/kg ND 137 04/28/16 15:2935.7
Benzene ug/kg ND 6.9 04/28/16 15:292.2
Bromochloromethane ug/kg ND 6.9 04/28/16 15:292.3
Bromodichloromethane ug/kg ND 6.9 04/28/16 15:292.6
Bromoform ug/kg ND 6.9 04/28/16 15:293.2
Bromomethane ug/kg ND 13.7 04/28/16 15:293.4
Carbon disulfide ug/kg ND 13.7 04/28/16 15:294.1
Carbon tetrachloride ug/kg ND 6.9 04/28/16 15:293.6
Chlorobenzene ug/kg ND 6.9 04/28/16 15:292.6
Chloroethane ug/kg ND 13.7 04/28/16 15:293.3
Chloroform ug/kg ND 6.9 04/28/16 15:292.2
Chloromethane ug/kg ND 13.7 04/28/16 15:293.3
cis-1,2-Dichloroethene ug/kg ND 6.9 04/28/16 15:291.9
cis-1,3-Dichloropropene ug/kg ND 6.9 04/28/16 15:292.5
Dibromochloromethane ug/kg ND 6.9 04/28/16 15:292.5
Dibromomethane ug/kg ND 6.9 04/28/16 15:293.4
Ethylbenzene ug/kg ND 6.9 04/28/16 15:292.5
Iodomethane ug/kg ND 13.7 04/28/16 15:2913.6
Methylene Chloride ug/kg ND 27.5 04/28/16 15:294.1
Styrene ug/kg ND 6.9 04/28/16 15:292.5
Tetrachloroethene ug/kg ND 6.9 04/28/16 15:292.3
Toluene ug/kg ND 6.9 04/28/16 15:292.5
trans-1,2-Dichloroethene ug/kg ND 6.9 04/28/16 15:292.6
trans-1,3-Dichloropropene ug/kg ND 6.9 04/28/16 15:292.1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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[phone]
Page 17 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92295469
BFI HOLLY SPRINGS, NC
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1722049
Associated Lab Samples:92295469001, 92295469002, 92295469003, 92295469004
Matrix: Solid
AnalyzedMDL
trans-1,4-Dichloro-2-butene ug/kg ND 6.9 04/28/16 15:294.9
Trichloroethene ug/kg ND 6.9 04/28/16 15:292.9
Trichlorofluoromethane ug/kg ND 6.9 04/28/16 15:293.0
Vinyl acetate ug/kg ND 68.7 04/28/16 15:2912.1
Vinyl chloride ug/kg ND 13.7 04/28/16 15:292.5
Xylene (Total)ug/kg ND 13.7 04/28/16 15:294.9
1,2-Dichloroethane-d4 (S)%93 70-132 04/28/16 15:29
4-Bromofluorobenzene (S)%98 70-130 04/28/16 15:29
Toluene-d8 (S)%100 70-130 04/28/16 15:29
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1722050LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/kg 59.562.3 96 74-137
1,1,1-Trichloroethane ug/kg 59.262.3 95 67-140
1,1,2,2-Tetrachloroethane ug/kg 55.862.3 90 72-141
1,1,2-Trichloroethane ug/kg 61.062.3 98 78-138
1,1-Dichloroethane ug/kg 56.362.3 90 69-134
1,1-Dichloroethene ug/kg 58.762.3 94 67-138
1,2,3-Trichloropropane ug/kg 58.762.3 94 69-144
1,2-Dibromo-3-chloropropane ug/kg 61.062.3 98 65-140
1,2-Dibromoethane (EDB)ug/kg 60.762.3 97 77-135
1,2-Dichlorobenzene ug/kg 59.062.3 95 77-141
1,2-Dichloroethane ug/kg 55.562.3 89 65-137
1,2-Dichloropropane ug/kg 60.762.3 97 72-136
1,4-Dichlorobenzene ug/kg 60.362.3 97 76-138
2-Butanone (MEK)ug/kg 113J125 91 58-147
2-Hexanone ug/kg 124125 100 62-145
4-Methyl-2-pentanone (MIBK)ug/kg 124125 99 64-149
Acetone ug/kg 103J125 82 53-153
Acrylonitrile ug/kg 296312 95 56-153
Benzene ug/kg 61.362.3 98 73-135
Bromochloromethane ug/kg 62.862.3 101 73-134
Bromodichloromethane ug/kg 59.962.3 96 71-135
Bromoform ug/kg 59.362.3 95 66-141
Bromomethane ug/kg 70.862.3 114 53-160
Carbon disulfide ug/kg 63.462.3 102 63-140
Carbon tetrachloride ug/kg 58.962.3 95 60-145
Chlorobenzene ug/kg 59.662.3 96 78-130
Chloroethane ug/kg 63.762.3 102 64-149
Chloroform ug/kg 58.362.3 93 70-134
Chloromethane ug/kg 57.262.3 92 52-150
cis-1,2-Dichloroethene ug/kg 58.662.3 94 70-133
cis-1,3-Dichloropropene ug/kg 62.062.3 99 68-134
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 03:29 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92295469
BFI HOLLY SPRINGS, NC
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1722050LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromochloromethane ug/kg 61.862.3 99 71-138
Dibromomethane ug/kg 59.862.3 96 74-130
Ethylbenzene ug/kg 60.162.3 96 75-133
Iodomethane ug/kg 131125 105 69-144
Methylene Chloride ug/kg 62.762.3 101 45-154
Styrene ug/kg 59.962.3 96 79-137
Tetrachloroethene ug/kg 56.562.3 91 71-138
Toluene ug/kg 61.162.3 98 74-131
trans-1,2-Dichloroethene ug/kg 59.662.3 96 67-135
trans-1,3-Dichloropropene ug/kg 61.462.3 98 65-146
trans-1,4-Dichloro-2-butene ug/kg 53.562.3 86 70-130
Trichloroethene ug/kg 60.662.3 97 67-135
Trichlorofluoromethane ug/kg 60.962.3 98 59-144
Vinyl acetate ug/kg 101 F312581 40-160
Vinyl chloride ug/kg 62.562.3 100 56-141
Xylene (Total)ug/kg 175187 94 76-137
1,2-Dichloroethane-d4 (S)%93 70-132
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1722432MATRIX SPIKE SAMPLE:
MSSpike
Result
92295469001
1,1,1,2-Tetrachloroethane ug/kg 6.76.8 100 70-130ND
1,1,1-Trichloroethane ug/kg 6.16.8 91 70-130ND
1,1,2,2-Tetrachloroethane ug/kg 7.76.8 114 70-130ND
1,1,2-Trichloroethane ug/kg 7.76.8 114 70-130ND
1,1-Dichloroethane ug/kg 6.36.8 93 70-130ND
1,1-Dichloroethene ug/kg 6.36.8 93 49-180ND
1,2,3-Trichloropropane ug/kg 8.06.8 119 70-130ND
1,2-Dibromo-3-chloropropane ug/kg 8.76.8 129 70-130ND
1,2-Dibromoethane (EDB)ug/kg 8.06.8 118 70-130ND
1,2-Dichlorobenzene ug/kg 6.96.8 103 70-130ND
1,2-Dichloroethane ug/kg 6.96.8 102 70-130ND
1,2-Dichloropropane ug/kg 6.86.8 102 70-130ND
1,4-Dichlorobenzene ug/kg 7.16.8 106 70-130ND
2-Butanone (MEK)ug/kg 18.3J M113.4 136 70-130ND
2-Hexanone ug/kg 19.7 M113.4 147 70-130ND
4-Methyl-2-pentanone (MIBK)ug/kg 16.7J13.4 124 70-130ND
Acetone ug/kg 30.8J M113.4 229 70-130ND
Acrylonitrile ug/kg 39.933.6 119 70-130ND
Benzene ug/kg 6.86.8 101 50-166ND
Bromochloromethane ug/kg 7.46.8 110 70-130ND
Bromodichloromethane ug/kg 6.66.8 99 70-130ND
Bromoform ug/kg 7.16.8 106 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92295469
BFI HOLLY SPRINGS, NC
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1722432MATRIX SPIKE SAMPLE:
MSSpike
Result
92295469001
Bromomethane ug/kg 8.66.8 127 70-130ND
Carbon disulfide ug/kg 6.66.8 98 70-130ND
Carbon tetrachloride ug/kg 6.16.8 90 70-130ND
Chlorobenzene ug/kg 6.56.8 97 43-169ND
Chloroethane ug/kg 6.96.8 102 70-130ND
Chloroform ug/kg 6.66.8 97 70-130ND
Chloromethane ug/kg 6.06.8 90 70-130ND
cis-1,2-Dichloroethene ug/kg 6.66.8 98 70-130ND
cis-1,3-Dichloropropene ug/kg 6.56.8 97 70-130ND
Dibromochloromethane ug/kg 7.26.8 107 70-130ND
Dibromomethane ug/kg 7.26.8 108 70-130ND
Ethylbenzene ug/kg 6.56.8 96 70-130ND
Iodomethane ug/kg 14.113.4 105 70-130ND
Methylene Chloride ug/kg 9.16.8 111 70-1301.7J
Styrene ug/kg 6.56.8 97 70-130ND
Tetrachloroethene ug/kg 5.96.8 88 70-130ND
Toluene ug/kg 6.66.8 98 52-163ND
trans-1,2-Dichloroethene ug/kg 6.16.8 91 70-130ND
trans-1,3-Dichloropropene ug/kg 6.86.8 101 70-130ND
trans-1,4-Dichloro-2-butene ug/kg 7.66.8 112 70-130ND
Trichloroethene ug/kg 6.26.8 92 49-167ND
Trichlorofluoromethane ug/kg 6.56.8 97 70-130ND
Vinyl acetate ug/kg 15.9J13.4 119 70-130ND
Vinyl chloride ug/kg 6.76.8 99 70-130ND
1,2-Dichloroethane-d4 (S)%100 70-132
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92295484001
1722431SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/kg ND 30ND
1,1,1-Trichloroethane ug/kg ND 30ND
1,1,2,2-Tetrachloroethane ug/kg ND 30ND
1,1,2-Trichloroethane ug/kg ND 30ND
1,1-Dichloroethane ug/kg ND 30ND
1,1-Dichloroethene ug/kg ND 30ND
1,2,3-Trichloropropane ug/kg ND 30ND
1,2-Dibromo-3-chloropropane ug/kg ND 30ND
1,2-Dibromoethane (EDB)ug/kg ND 30ND
1,2-Dichlorobenzene ug/kg ND 30ND
1,2-Dichloroethane ug/kg ND 30ND
1,2-Dichloropropane ug/kg ND 30ND
1,4-Dichlorobenzene ug/kg ND 30ND
2-Butanone (MEK)ug/kg ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92295469
BFI HOLLY SPRINGS, NC
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92295484001
1722431SAMPLE DUPLICATE:
2-Hexanone ug/kg ND 30ND
4-Methyl-2-pentanone (MIBK)ug/kg ND 30ND
Acetone ug/kg 79.0J 30ND
Acrylonitrile ug/kg ND 30ND
Benzene ug/kg ND 30ND
Bromochloromethane ug/kg ND 30ND
Bromodichloromethane ug/kg ND 30ND
Bromoform ug/kg ND 30ND
Bromomethane ug/kg ND 30ND
Carbon disulfide ug/kg ND 30ND
Carbon tetrachloride ug/kg ND 30ND
Chlorobenzene ug/kg ND 30ND
Chloroethane ug/kg ND 30ND
Chloroform ug/kg ND 30ND
Chloromethane ug/kg ND 30ND
cis-1,2-Dichloroethene ug/kg ND 30ND
cis-1,3-Dichloropropene ug/kg ND 30ND
Dibromochloromethane ug/kg ND 30ND
Dibromomethane ug/kg ND 30ND
Ethylbenzene ug/kg ND 30ND
Iodomethane ug/kg ND 30ND
Methylene Chloride ug/kg 4.7J 3018.2J
Styrene ug/kg ND 30ND
Tetrachloroethene ug/kg ND 30ND
Toluene ug/kg ND 30ND
trans-1,2-Dichloroethene ug/kg ND 30ND
trans-1,3-Dichloropropene ug/kg ND 30ND
trans-1,4-Dichloro-2-butene ug/kg ND 30ND
Trichloroethene ug/kg ND 30ND
Trichlorofluoromethane ug/kg ND 30ND
Vinyl acetate ug/kg ND 30ND
Vinyl chloride ug/kg ND 30ND
Xylene (Total)ug/kg ND 30ND
1,2-Dichloroethane-d4 (S)%105 7100
4-Bromofluorobenzene (S)%100 398
Toluene-d8 (S)%101 399
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92295469
BFI HOLLY SPRINGS, NC
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
PMST/9014
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples: 92295469001, 92295469002, 92295469003, 92295469004
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92295484001
1721287SAMPLE DUPLICATE:
Percent Moisture %31.7 1 2531.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92295469
BFI HOLLY SPRINGS, NC
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/44674
EPA 9045
EPA 9045
9045 pH
Associated Lab Samples: 92295469001, 92295469002, 92295469003, 92295469004
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92295469001
1725634SAMPLE DUPLICATE:
pH at 25 Degrees C Std. Units 7.2 H60107.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 27
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92295469
BFI HOLLY SPRINGS, NC
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
The recovery of the second source standard used to verify the initial calibration curve for this analyte is outside the
laboratory's control limits. The result is estimated.F3
Analysis initiated outside of the 15 minute EPA required holding time.H6
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 27
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92295469
BFI HOLLY SPRINGS, NC
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92295469001 MPRP/21597 ICP/19382SS-1 EPA 3050 EPA 6010
92295469002 MPRP/21597 ICP/19382SS-2 EPA 3050 EPA 6010
92295469003 MPRP/21597 ICP/19382SS-3 EPA 3050 EPA 6010
92295469004 MPRP/21597 ICP/19382BGEPA 3050 EPA 6010
92295469001 MSV/36605SS-1 EPA 8260
92295469002 MSV/36605SS-2 EPA 8260
92295469003 MSV/36605SS-3 EPA 8260
92295469004 MSV/36605BGEPA 8260
92295469001 PMST/9014SS-1 ASTM D2974-87
92295469002 PMST/9014SS-2 ASTM D2974-87
92295469003 PMST/9014SS-3 ASTM D2974-87
92295469004 PMST/9014BGASTM D2974-87
92295469001 WET/44674SS-1 EPA 9045
92295469002 WET/44674SS-2 EPA 9045
92295469003 WET/44674SS-3 EPA 9045
92295469004 WET/44674BGEPA 9045
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 27
Page 26 of 27
Page 27 of 27