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HomeMy WebLinkAbout4304_CentralCarolinaTire_Phase3_April2016_1stSemiAnnual_DIN26133_20160520 11112 BRANDING IRON PLACE, WENDELL, NC 27591 919-366-3663 Office ● 919-995-0363 Cell ● nautilusgeocon@gmail.com Explanatory Text for Notification Table Central Carolina Tire Monofill Landfill Phase III Cameron, Harnett, NC Permit # 43-04 April 13, 2016 Water Quality Monitoring The results of the April 2016 groundwater and surface water quality monitoring conducted at the Central Carolina Tire Monofill Landfill are generally consistent with the results of previous monitoring conducted at the site. No RCRA metals were reported in the surface water samples at concentrations that exceed the 15A NCAC 2L .0202 groundwater quality standards or the 15A NCAC 2B surface water quality standards. In addition, no Appendix I VOCs were detected in any of the surface water or groundwater samples collected from the site in April 2016. The concentrations of mercury reported in the groundwater samples collected from background monitoring well MW-10 (1.70 µg/L) and compliance monitoring well MW-11 (1.20 µg/L) slightly exceed the 15A NCAC 2L groundwater quality standard of 1.0 µg/L. The April 2016 monitoring event is the second event in which mercury was reported at a concentration in excess of the 15A NCAC 2L groundwater quality standard at background well MW-10 and the first event in which mercury was reported at a concentration in excess of the 15A NCAC 2L groundwater quality standard at compliance well MW-11. Monitoring well MW-11 is located hydraulically down gradient from background monitoring well MW-10. Inasmuch as the reported concentration of mercury at MW-10 is higher than that at MW-11, it is concluded that the source of mercury in groundwater is located hydraulically up gradient of the landfill and not related to operation of the landfill. None of the other reported concentrations of metals detected in any of the groundwater samples exceed the corresponding 15A NCAC 2L .0202 groundwater quality standards. 11112 BRANDING IRON PLACE, WENDELL, NC 27591 919-366-3663 Office ● 919-995-0363 Cell ● nautilusgeocon@gmail.com May 17, 2016 Ms. Elizabeth S. Werner, Hydrogeologist North Carolina Department of Environmental Quality Division of Waste Management Solid Waste Section 1646 Mail Service Center Raleigh, NC 27699-1646 RE: Report of Results Semi-Annual Groundwater and Surface Water Monitoring: April 2016 Central Carolina Tire Monofill Landfill Phase III Cameron, Harnett County, NC Permit # 43-04 Dear Ms. Werner: This report presents the results of semi-annual groundwater and surface water quality monitoring conducted at the landfill site referenced above (Figure 1) in April 2016. The scope of work performed included sampling and laboratory analysis of groundwater samples from eight on-site monitoring wells (MW-10 through MW-14 and MW-16 through MW-18) and one surface water sample (SW-1 (EXP)). It is noted that monitoring well MW-17 was abandoned on August 30, 2011 and replaced with monitoring well MW-17AR in accordance with the facility Water Quality Monitoring Plan submitted as part of the Application for Permit Amendment 5-Year Phase (2011-2016) prepared by Garrett & Moore, Inc. The Water Quality Monitoring Plan was approved by the NCDEQ, Division of Waste Management (DWM), Solid Waste Section (SWS), in a letter to Central Carolina Tire Holdings, LLC dated August 10, 2011. The groundwater and surface water samples were collected in accordance with the NCDEQ, DWM, SWS Guidelines for Groundwater, Soil, and Surface Water Sampling Document and the facility Water Quality Monitoring Plan. The sampling and data collection methods, as well as the current and historical results of field and laboratory testing of the water samples, are presented in the following sections. – 2 – May 17, 2016 11112 BRANDING IRON PLACE, WENDELL, NC 27591 919-366-3663 Office ● 919-995-0363 Cell ● nautilusgeocon@gmail.com 1.0 POTENTIOMETRIC PATTERN AND GROUNDWATER FLOW Groundwater levels were gauged in the site groundwater monitoring wells on April 13, 2016 as part of the site monitoring. Depths to groundwater were measured using an electronic water level probe that was thoroughly decontaminated between wells with a non-phosphate soap and water wash followed in order by multiple rinses with distilled water, an isopropyl alcohol rinse, and multiple distilled water rinses. Depth to groundwater measurements were made after the wells were opened for a sufficient period of time to allow water levels to equilibrate with atmospheric pressure. The locations of the site monitoring wells are depicted in Figure 2. Groundwater elevation data collected at the monitoring wells on April 13, 2016 are presented in Table 1. The depth to groundwater across the site, as measured in the Type II groundwater monitoring wells on April 13, 2016, ranged from 2.74 feet (MW-12) to 16.43 feet (MW- 16) below grade, which is consistent with the surface topography. A water-table elevation contour map that was developed based on the April 13, 2016 groundwater-gauging data for the Type II monitoring wells is presented as Figure 3. The pattern of the water-table contours indicates that the horizontal component of shallow groundwater flow at the site is generally to the southeast, which is consistent with the surface topography and drainage features at the site. The hydraulic gradient of the water table across the site, based on the data depicted in Figure 3, varies from approximately 0.004 ft/ft in the northern part of the site to 0.013 ft./ft. in the southeastern part of the site. 2.0 RESULTS OF GROUNDWATER AND SURFACE WATER SAMPLING AND ANALYSIS Groundwater samples were collected from the site monitoring wells and a surface water sample was collected from the on-site location on April 13, 2016 for laboratory analysis to monitor the quality of groundwater and surface water at the site. The groundwater and surface water samples were collected and handled in accordance with the sampling protocols included in the site Water Quality Monitoring Plan as well as the SWS Guidelines for Groundwater, Soil, and Surface Water Sampling Document. It is noted that monitoring well MW-10 serves as the upgradient, natural background well for the facility, and monitoring wells MW-11 through MW-14 and MW-16 through MW-18 serve as the downgradient monitoring wells. All reusable sampling equipment was properly – 3 – May 17, 2016 11112 BRANDING IRON PLACE, WENDELL, NC 27591 919-366-3663 Office ● 919-995-0363 Cell ● nautilusgeocon@gmail.com decontaminated between sampling locations with a non-phosphate soap and water wash, followed by multiple rinses with distilled water. New disposable nitrile or latex gloves were worn during all sampling activities. Disposable sampling equipment/material was discarded after each use. Prior to groundwater sampling, all monitoring wells were purged using pre-cleaned Teflon-lined disposable polyethylene tubing connected to a peristaltic pump under low flow conditions. During purging, measurements were made in the field of the pH, temperature, specific conductance and turbidity of the groundwater collected from the monitoring wells, in accordance with SWS requirements. The results of the field analyses of these parameters are presented in Table 1. Copies of Groundwater Sampling Forms containing pertinent information recorded in the field during purging and sampling at each groundwater monitoring well are presented in Appendix A. The results of the field-measured water-quality parameters indicate that the values measured in groundwater collected from the site monitoring wells were generally within the applicable stabilization criteria (see Groundwater Sampling Forms). Groundwater at the site is acidic to moderately acidic based on the pH values measured in the field (4.20 to 5.05). Specific conductance values ranged from 17 (MW-13) to 183 (MW-10) µS/cm in groundwater. Turbidity values ranged from 1.1 (MW-18) to 56.9 (MW-12) NTUs. A surface water sample was collected from monitoring location SW-1 (EXP), which is located approximately 280 feet southeast of the planned limits of scrap tire disposal along the primary drainage feature that bisects the southeastern portion of the Phase III landfill footprint. The sampling location is depicted in Figure 2. The surface water sample was collected in accordance with the protocol presented in the SWS Guidelines for Groundwater, Soil, and Surface Water Sampling Document. All groundwater and surface water samples were analyzed at a North Carolina-certified laboratory for Appendix I volatile organic compounds (VOCs) by SW 846 Method 8260 and the 8 RCRA metals by EPA 6000/7000 series methods. Summarized results of laboratory analyses for groundwater and surface water samples collected from the site on April 13, 2016 are presented in Table 2. Summarized historical groundwater and surface water quality data for the site are presented in Table 3. Copies of the original laboratory reports are included in Appendix B. – 4 – May 17, 2016 11112 BRANDING IRON PLACE, WENDELL, NC 27591 919-366-3663 Office ● 919-995-0363 Cell ● nautilusgeocon@gmail.com The laboratory analytical results for the surface water sample (SW-1 (EXP)) collected from the site indicate that no Appendix I VOCs were reported in the sample. Low levels of arsenic, barium, cadmium, chromium, lead, selenium and silver were reported in surface water sample SW-1 (EXP), however, the reported concentrations were well below the corresponding 15A NCAC 2L groundwater quality standards and the 15A NCAC 2B surface water standards applicable to the site. The laboratory analytical results for the groundwater samples collected from the site monitoring wells in April 13, 2016 indicate that no Appendix I VOCs were reported in any of the groundwater samples. The results of the metals analyses of the groundwater samples indicate that arsenic was reported in five of the samples, barium, cadmium, and lead were reported in all of the samples, chromium and selenium were reported in six of the samples, and mercury and silver were reported in three of the samples. The concentrations of mercury reported in the groundwater samples collected from background monitoring well MW-10 (1.70 µg/L) and compliance monitoring well MW-11 (1.20 µg/L) slightly exceed the 15A NCAC 2L groundwater quality standard of 1.0 µg/L. Monitoring well MW-11 is located hydraulically down gradient from background monitoring well MW-10. Inasmuch as the reported concentration of mercury at MW-10 is higher than that at MW-11, it is concluded that the source of mercury in groundwater is located hydraulically up gradient of the landfill and not related to operation of the landfill. None of the other reported concentrations of metals detected in any of the groundwater samples exceed the corresponding 15A NCAC 2L .0202 groundwater quality standards. 3.0 CONCLUSIONS AND RECOMMENDATIONS The results of the April 2016 groundwater and surface water quality monitoring conducted at the Central Carolina Tire Monofill Landfill are generally consistent with the results of previous monitoring conducted at the site. No RCRA metals were reported in the surface water samples at concentrations that exceed the 15A NCAC 2L .0202 groundwater quality standards or the 15A NCAC 2B surface water quality standards. In addition, no Appendix I VOCs were detected in any of the surface water or groundwater samples collected from the site in April 2016. The concentrations of mercury reported in the groundwater samples collected from background monitoring well MW-10 (1.70 µg/L) and compliance monitoring well MW-11 – 5 – May 17, 2016 11112 BRANDING IRON PLACE, WENDELL, NC 27591 919-366-3663 Office ● 919-995-0363 Cell ● nautilusgeocon@gmail.com (1.20 µg/L) slightly exceed the 15A NCAC 2L groundwater quality standard of 1.0 µg/L. The April 2016 monitoring event is the second event in which mercury was reported at a concentration in excess of the 15A NCAC 2L groundwater quality standard at background well MW-10 and the first event in which mercury was reported at a concentration in excess of the 15A NCAC 2L groundwater quality standard at compliance well MW-11. Monitoring well MW-11 is located hydraulically down gradient from background monitoring well MW-10. Inasmuch as the reported concentration of mercury at MW-10 is higher than that at MW-11, it is concluded that the source of mercury in groundwater is located hydraulically up gradient of the landfill and not related to operation of the landfill. None of the other reported concentrations of metals detected in any of the groundwater samples exceed the corresponding 15A NCAC 2L .0202 groundwater quality standards. If you have any questions or require further assistance regarding this report, please call me at 919-995-0363. The next water quality monitoring event for the Central Carolina Tire Monofill Landfill is scheduled for October 2016. Sincerely, Brian S. Boutin, P.G. Consulting Geologist Cc: Tim McNeil, Central Carolina Holdings, Inc. Vance Moore, Garrett and Moore, Inc. Craig Fortner, Garrett & Moore, Inc. Drawn by: Reviewed by: Drawing #: Drawing Date: 1 SITE LOCATION MAP Central Carolina Tire Monofill Landfill Harnett County, North Carolina Source: USGS 7.5’ Topographic Quadrangle Series Murchisontown, NC 2010 Figure No. Project #: Scale: USGS 1:24,000 05/31/2012 N 11112 Branding Iron Place Wendell, NC 27591 Office: (919) 366-3663 Cell: (919) 995-0363 Central Carolina Tire 333 334 335 336 337 338 339 339 340 34 0 34 1 34 1 34 2 34 2 34 3 34 3 34 4 (344.24) (337.78) (331.71) (329.50) (337.67) (344.16) (343.29) (336.63) MW-10 27.0 2.0 356.28 353.74 12.04 344.24 19.0 5.05 183 6.1 MW-11 23.8 2.0 347.80 345.70 10.02 337.78 19.4 4.38 41 1.4 MW-12 21.6 2.0 336.58 334.45 4.87 331.71 18.3 4.36 21 56.9 MW-13 20.6 2.0 339.47 337.36 9.97 329.50 15.5 4.35 17 7 MW-14 12.6 2.0 344.12 341.86 6.45 337.67 16.7 4.77 45 5.1 MW-16 28.9 2.0 362.53 360.59 18.37 344.16 18.9 4.20 36 4.9 MW-17AR 20.0 2.0 352.99 350.70 9.70 343.29 16.9 4.59 60 25 MW-18 14.8 2.0 344.71 342.45 8.08 336.63 20.7 4.24 52 1.1 Notes:MSL = Mean Sea Level BTOC = Below Top of Casing GW = Groundwater S.C. = Specific Conductance ntu = Nephelometric Turbidity Units Monitoring well construction data taken from October-December 2006 Sampling Event Monitoring Report prepared by Withers & Ravenel. Well Depth (Feet BTOC)pH S.C. umhos/cm Permit # 43-04 Monitoring Well and Groundwater Data Table 1 April 2016 Sampling Event Central Carolina Tire Monofill Landfill Phase III Harnett County, North Carolina Well Identity Temp. Co April 13, 2016 Well Diameter (Inches) Field Parameters Turbidity (ntu) Ground Surface Elevation (Feet MSL) Groundwater Elevation (Feet MSL) Depth to Groundwater (Feet BTOC) Top of Casing Elevation (Feet MSL) ORGANIC CONSTITUENTS GWP Std NCAC 2L STD (ug/L)(ug/L)(ug/L) Acetone ND ND ND ND ND ND ND ND ND NE 6000 Acrylonitrile ND ND ND ND ND ND ND ND ND NE NE Benzene ND ND ND ND ND ND ND ND ND NE 1 Bromochloromethane ND ND ND ND ND ND ND ND ND 0.6 NE Bromodichloromethane ND ND ND ND ND ND ND ND ND NE 0.6 Bromoform (Tribromoethane)ND ND ND ND ND ND ND ND ND NE 4 Bromomethane (Methyl Bromide)ND ND ND ND ND ND ND ND ND 10 10 2-Butanone (MEK), (Methyl Ethyl Ketone)ND ND ND ND ND ND ND ND ND NE 4000 Carbon Disulfide ND ND ND ND ND ND ND ND ND NE 700 Carbon Tetrachloride ND ND ND ND ND ND ND ND ND NE 0.3 Chlorobenzene ND ND ND ND ND ND ND ND ND NE 50 Chloroethane (Ethyl Chloride)ND ND ND ND ND ND ND ND ND NE 3000 Chloroform (Trichloromethane)ND ND ND ND ND ND ND ND ND NE 70 1,2-Dibromo-3-Chloropropane (DBCP)ND ND ND ND ND ND ND ND ND NE 0.04 Dibromochloromethane (Chlorodibromomethane)ND ND ND ND ND ND ND ND ND 0.41 0.4 1,2,-Dibromoethane (Ethylene Dibromide)ND ND ND ND ND ND ND ND ND NE 0.02 Dibromomethane (Methylene Bromide)ND ND ND ND ND ND ND ND ND 5.5 70 1,2-Dichlorobenzene (O-Dichlorobenzene)ND ND ND ND ND ND ND ND ND NE 20 1,3-Dichlorobenzene (M-Dichlorobenzene)ND ND ND ND ND ND ND ND ND NE 200 1,4-Dichlorobenzene (P-Dichlorobenzene)ND ND ND ND ND ND ND ND ND NE 6 Trans-1,4-Dichloro-2-butene ND ND ND ND ND ND ND ND ND NE NE 1,1-Dichloroethane ND ND ND ND ND ND ND ND ND NE 6 1,2-Dichloroethane (Ethylene Dichloride)ND ND ND ND ND ND ND ND ND NE 0.4 1,1-Dichloroethene (Vinylidene Chloride)ND ND ND ND ND ND ND ND ND NE 7 1,2-Dichloroethene (cis and trans isomers)ND ND ND ND ND ND ND ND ND 60 60 1,2-Dichloropropane (Propylene Dichloride)ND ND ND ND ND ND ND ND ND NE 0.6 1,1-Dichloropropene ND ND ND ND ND ND ND ND ND NE NE 1,3-Dichloropropene (cis and trans isomers)ND ND ND ND ND ND ND ND ND NE 0.4 Ethylbenzene ND ND ND ND ND ND ND ND ND NE 600 Iodomethane (Methyl Iodide)ND ND ND ND ND ND ND ND ND NE NE 2-Hexanone (Methyl Butyl Ketone)ND ND ND ND ND ND ND ND ND NE 280 Methyl Chloride (Chloromethane)ND ND ND ND ND ND ND ND ND NE 3 Methylene Chloride (Dichloromethane)ND ND ND ND ND ND ND ND ND NE 5 4-Methyl-2-Pentanone (Methyl Isobutyl Ketone)ND ND ND ND ND ND ND ND ND 560 NE Styrene ND ND ND ND ND ND ND ND ND NE 70 1,1,1,2-Tetrachloroethane ND ND ND ND ND ND ND ND ND 1 1 1,1,2,2-Tetrachloroethane ND ND ND ND ND ND ND ND ND 0.18 0.2 Tetrachloroethene (Tetrachloroethylene), (PCE)ND ND ND ND ND ND ND ND ND NE 0.7 Toluene ND ND ND ND ND ND ND ND ND NE 600 1,1,1-Trichloroethane (Methylchloroform)ND ND ND ND ND ND ND ND ND NE 200 1,1,2-Trichloroethane ND ND ND ND ND ND ND ND ND 0.6 0.6 Trichloroethene (Trichloroethylene), (TCE)ND ND ND ND ND ND ND ND ND NE 3 Trichlorofluoromethane (CFC-11) ND ND ND ND ND ND ND ND ND NE 2000 1,2,3-Trichloropropane ND ND ND ND ND ND ND ND ND NE 0.005 Vinyl Acetate ND ND ND ND ND ND ND ND ND 88 88 Vinyl Chloride ND ND ND ND ND ND ND ND ND NE 0.03 Total Xylenes ND ND ND ND ND ND ND ND ND NE 500 INORGANIC CONSTITUENTS GWP Std NCAC 2L STD (in ug/L)(ug/L)(ug/L) Arsenic 0.59 J 0.64 J 0.48 J 4.0 ND ND 0.47 J 0.75 J ND NE 10 Barium 45 36 54 11 7 34 37 37 59 NE 700 Cadmium 0.10 J 0.086 J 0.16 J 0.088 J 0.089 J 0.097 J 0.11 J 0.094 J 0.11 J NE 2 Chromium 0.79 J ND 0.54 J 3.9 ND 0.51 J 0.63 J 2.5 0.60 J NE 10 Lead 1.1 0.26 J 0.69 J 1.7 0.27 J 0.27 J 0.71 J 1.4 0.94 J NE 15 Mercury ND 1.70 1.20 ND ND ND 0.45 ND ND NE 1 Selenium 0.36 J 8.4 0.98 J 0.72 J ND ND 0.42 J 0.52 J 0.79 J NE 20 Silver 0.018 J ND ND 0.013 J ND ND ND 0.017 J 0.038 J NE 20 Notes: Values in boldface exceed the corresponding 15A NCAC 2L .0202 groundwater quality standard for Class GA groundwater.J = Estimated value above laboratory method detection limit and below SWSL or reporting limit. NCAC 2L STD = North Carolina Groundwater Standard established in Title 15A of North Carolina Administrative Code Subchapter 2L B = Analyte found in associated field and/or laboratory blank. GWP Std = Solid Waste Section Groundwater Protection Standard NE = No standard established. ND = None detected above laboratory method detection limit. MW-10 MW-12 Permit # 43-04 NS = Not Sampled, No sample exists for this sampling period MW-17ARMW-11 MW-18 Table 2 SW-1 (EXP)MW-13 MW-14 Central Carolina Tire Monofill Landfill Phase III, Harnett County, NC Laboratory Results for Surface Water and Groundwater Samples October 1, 2015 October 2015 Sampling Event MW-16 Page 1 of 2 Sampling Date:2L Standard 10/24/07 4/29/08 10/14/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/26/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 Well No:MW-10 Arsenic 10 ND ND 1.91 J 2.25 J ND ND 1.5 J ND ND 1.40 1.90 1.80 ND 1.10 ND 1.60 0.77 J 0.64 JBarium70078.0 J 39.2 JB 53.8 JB 63.3 JB 27.8 JB 22.0 0.17 J 32.0 25.0 33.0 17.0 40.0 18.0 29.0 39.0 29.0 40.0 36 Cadmium 2 ND ND ND ND ND ND 0.69 J ND ND ND ND 0.094 J ND 0.049 J ND ND 0.052 J 0.086 JChromium101.46 J 2.47 JB 1.45 JB 3.01 JB 2.86 JB 0.55 J ND ND 8.4 BJ ND 2.7 B ND ND ND ND 0.26 J 0.51 J ND Lead 15 5.11 J 4.90 J ND ND ND 0.71 J ND ND 0.95 J 0.21 J 0.28 J 0.2 J 0.26 J 0.33 J ND 0.18 J 0.32 J 0.26 J Mercury 1 ND ND ND 0.281 J ND ND ND ND 0.019 J ND ND ND 0.18 J 0.34 0.15 J 1.80 0.23 1.70Selenium20NDNDNDNDNDND10.00 ND ND 7.20 6.50 7.70 2.00 3.80 3.50 8.60 6.00 8.4 Silver 20 ND 2.37 JB 3.41 JB ND ND ND ND ND 0.45 J ND 0.18 J ND ND 0.056 J ND ND ND NDAcetone6000ND1.83 JB ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform 4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.10 ND ND NDTrichloroethene3NDNDND0.380 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene 600 ND ND 5.54 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Sampling Date:2L Standard 10/24/07 4/29/08 10/15/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/26/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16Well No:MW-11 Arsenic 10 2.59 J ND ND 2.43 J ND ND ND ND ND ND ND ND 0.37 J ND ND ND ND 0.48 JBarium70019.5 J 55.1 JB 44.6 JB 60.5 JB 29.6 JB 65.0 51.0 33.0 25.0 27.0 28.0 28.0 29.0 63.0 23.0 55.0 43.0 54.0 Cadmium 2 ND ND ND ND ND ND 2.1 ND 0.27 J ND ND 0.061 J 1.4 ND ND ND 0.14 J 0.16 JChromium101.31 J 6.94 JB 1.35 JB 3.99 JB 3.42 JB ND 1.5 J ND 7.2 B ND 2.8 B 1.1 B ND ND ND ND 0.64 J 0.54 J Lead 15 ND 10.60 ND 5.01 JB ND ND 0.81 J ND 0.89 J 0.30 J 0.38 J 0.37 J 0.88 J 0.20 J 0.21 J 0.22 J 0.60 J 0.69 JMercury1NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND0.86 1.20 Selenium 20 ND ND ND ND ND ND ND ND 0.47 J 0.70 J 1.00 0.62 J ND ND ND ND 0.83 J 0.98 JSilver20ND2.03 JB 3.91 JB 1.49 JB 1.56 JB ND ND ND 0.33 J ND ND ND ND ND ND ND ND ND Methylene Chloride 5 ND ND 0.830 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Sampling Date:2L Standard 10/24/07 4/29/08 10/15/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/27/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 Well No:MW-12 Arsenic 10 ND 2.32 J ND 3.00 J ND ND ND ND 0.12 J 0.38 J ND ND 2.70 0.83 J 14.00 0.63 J 2.10 4.00Barium70097.8 J 46.2 JB 23.8 JB 56.2 JB 24.8 JB 5.7 J 11 J 14.0 16.0 15.0 13.0 15.0 17.0 9.0 22.0 8.9 15.0 11.0 Cadmium 2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.18 J 0.088 JChromium103.04 J 11.6 B 3.25 JB 7.16 JB 4.08 JB 1.6 J 2 J ND 5.60 ND 3.6 B 1.6 B 0.95 J 0.47 J 2.40 1.30 5.70 3.90 Lead 15 ND 6.31 J 4.80 J 9.68 JB ND 0.81 J 2 J ND 0.62 J 0.64 J 0.96 J 0.41 J 1.70 0.49 J 1.60 0.90 J 2.40 1.70Mercury1NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND0.12 J ND Selenium 20 ND 7.32 J ND ND ND ND ND ND ND ND ND 0.34 J ND ND ND ND ND 0.72 J Silver 20 ND 1.93 JB 4.01 JB 1.82 JB ND ND ND ND ND ND ND ND ND ND ND ND ND 0.013 JAcetone6000NDNDNDNDNDNDNDNDNDNDNDNDNDND6.60 ND ND ND Chloroform 70 0.150 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDMethylene Chloride 5 ND ND 0.390 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Butanone (MEK)4000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 9.80 ND ND NDToluene600ND0.510 JB 0.510 JB ND ND ND ND ND ND ND ND ND ND ND 4.5 ND ND ND Sampling Date:2L Standard 10/24/07 4/29/08 10/15/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/27/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 Well No:MW-13Arsenic 10 3.79 J ND ND ND ND 3.1 J ND ND ND ND 0.60 J ND 0.50 J ND ND ND ND ND Barium 700 9.36 J 19.8 JB 14.9 JB 18.5 JB 8.7 JB 7.4 J 4.8 J 6.3 J 7.5 3.9 J 6.0 7.1 11.0 4.5 J 4.2 J 4.9 J 13.0 7.0Cadmium2NDNDNDNDNDNDND0.19 J ND ND ND ND ND ND ND ND 0.10 J 0.089 J Chromium 10 3.26 J 3.07 JB ND 3.60 JB 3.05 JB 2.1 J 1.3 J ND 3.6 B ND 2.6 B 1.1 B ND ND ND ND 1.50 NDLead15ND8.32 J 4.75 J 7.51 JB ND ND ND ND 0.41 J 0.24 J 0.21 J 0.18 J 0.83 J 0.12 J 0.26 J ND 1.1 0.27 J Mercury 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.068 J NDSelenium20NDNDNDNDNDNDNDNDNDNDND0.36 J ND ND ND ND ND ND Silver 20 ND 2.88 JB 3.65 JB 1.12 JB 0.78 JB ND ND ND ND ND ND ND ND ND ND ND ND NDBromoform4NDNDNDND0.27 J ND ND ND ND ND ND ND ND ND ND ND ND ND Sampling Date:2L Standard 10/24/07 4/29/08 10/15/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/26/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 Well No:MW-14 Arsenic 10 3.12 J ND ND 2.50 J ND ND 1.9 J ND ND 0.12 J 0.30 J ND ND ND ND ND ND NDBarium700113.0 180 B 185 B 177 B 159 B 130.0 91.0 110.0 87.0 110.0 100.0 80.0 67.0 38.0 26.0 28.0 42.0 34.0 Cadmium 2 ND ND ND ND 0.22 J ND 0.34 J ND ND ND ND 0.18 J 0.27 J ND ND ND 0.074 J 0.097 JChromium101.46 J 4.86 JB 1.77 JB 3.80 JB 5.02 JB 0.9 J 1.6 J ND 6.9 B ND 2.4 B 1.2 B ND ND ND ND 0.80 J 0.51 J Lead 15 3.62 J 8.51 J 5.06 J 3.74 JB 8.24 J 1.7 J 1.7 J 1.4 J 1.80 1.60 1.70 0.82 J 1.10 0.43 J 0.035 J 0.22 J 0.94 J 0.27 J Mercury 1 ND ND ND ND ND ND ND ND 0.019 J ND ND ND ND ND ND ND ND NDSelenium20NDNDNDNDNDNDNDNDNDNDND0.80 J ND 0.16 J ND ND ND ND Silver 20 ND 1.99 JB 3.11 JB 1.29 JB ND ND ND ND ND ND ND 0.12 J ND ND ND ND ND NDAcetone60008.25 JB ND ND ND ND ND ND ND ND ND ND ND ND ND 15.00 ND ND ND Bromoform 4 ND ND ND ND 0.18 J ND ND ND ND ND ND ND ND ND ND ND ND NDMethylene Chloride 5 ND ND 0.560 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Sampling Date:2L Standard 10/24/07 4/29/08 10/15/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/26/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 Well No:MW-16Arsenic 10 1.86 J ND ND 4.76 JB ND ND ND ND 0.67 J ND 0.41 J ND 0.44 J ND ND ND ND 0.47 J Barium 700 8.81 J 69.8 JB 31.1 JB 28.8 JB 16.3 JB 27.0 19 J 24.0 38.0 33.0 31.0 38.0 48.0 41.0 42.0 35.0 37.0 37.0Cadmium2NDNDNDNDNDND0.66 J ND ND ND ND 0.14 J 0.037 J ND ND ND 0.053 J 0.11 J Chromium 10 ND 3.07 JB 1.87 JB 3.99 JB 2.76 JB 1.0 J 1.5 J ND 8.7 B ND 2.5 B 1.2 B ND ND ND ND 0.83 J 0.63 JLead15ND8.15 J ND 4.74 JB ND 1.1 J ND ND 0.66 J 0.41 J 0.55 J 0.55 J 0.97 J 0.49 J 0.49 J 0.37 J 0.56 J 0.71 J Mercury 1 ND ND 0.114 J ND ND ND ND 0.092 J 0.17 J ND ND ND ND 0.028 J 0.15 J ND 0.46 0.45Selenium20NDNDNDND2.9 J ND ND ND 0.48 J 0.97 J 0.69 J 0.24 J ND ND ND ND ND 0.42 J Silver 20 ND 1.66 JB 4.10 JB 1.85 JB 0.86 JB ND ND ND ND ND ND ND ND ND ND ND ND NDAcetone6000ND2.42 JB ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform 4 ND ND ND ND 1.06 J ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane 0.4 ND ND ND ND 0.25 J ND ND ND ND ND ND ND ND ND ND ND ND NDMethylene Chloride 5 ND ND 0.560 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NOTES: Results in parts per billion (ppb) ND - Not Detected above the laboratory method detection limit or practical quantitation limit (results prior to April 2007). NA - Not analyzed for or not available Values in boldface exceed the corresponding 15A NCAC 2L .0202 groundwater quality standards. Results for sampling conducted prior to April 2007 as presented in previous GW reports prepared by Withers & Ravenel. J = Estimated value above laboratory method detection limit and below SWSL or reporting limit. B = Analyte found in associated field and/or laboratory blank. Table 3 Historical Summary of Constituent Detections Central Carolina Tire Monofill Landfill Phase III Permit # 43-04 Harnett County, North Carolina Page 2 of 2 Sampling Date:2L Standard 10/24/07 4/29/08 10/15/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/27/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16Well No:MW-17AR*Arsenic 10 ND ND ND 5.63 J ND ND ND ND ND ND ND ND 0.46 J 0.95 J ND ND ND 0.75 J Barium 700 91.7 J 71.9 JB 89.5 JB 56.4 JB 68.6 JB 35.0 41.0 41.0 90.0 30.0 120.0 130.0 110.0 25.0 110.0 150.0 110.0 37.0Cadmium2NDNDNDNDNDNDNDNDNDND0.24 J 0.17 J 0.086 J ND 0.093 J ND 0.11 J 0.094 J Chromium 10 1.76 J 2.47 JB ND 3.90 JB 2.58 JB ND 1.6 J ND 4.90 ND 2.6 B 1.2 B ND 2.30 0.32 J 1.10 1.50 2.50Lead15ND5.88 J ND ND ND ND ND ND 1.00 1.30 1.70 1.40 1.50 1.90 2.00 1.90 2.10 1.40 Mercury 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDSelenium20NDNDNDNDNDNDNDNDND0.76 J 0.72 J 0.51 J ND ND ND ND ND 0.52 J Silver 20 ND 2.26 JB 4.19 JB 1.51 JB 0.84 JB ND ND ND ND ND ND 0.041 J ND ND ND ND ND 0.017 JBromoform4NDNDNDND0.27 J ND ND ND ND ND ND ND ND ND ND ND ND ND Methylene Chloride 5 ND ND 0.450 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDToluene600NDNDNDNDNDNDNDND0.58 ND ND ND ND ND ND ND ND ND Sampling Date:2L Standard 10/24/07 4/29/08 10/15/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/26/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 Well No:MW-18 Arsenic 10 4.49 J ND ND 2.22 J ND ND ND ND ND 0.34 J 0.60 J ND 0.37 J 0.51 J ND ND 0.84 J NDBarium70026.3 J 43.1 JB 43.8 JB 48.6 JB 48.4 JB 41.0 41.0 46.0 41.0 40.0 41.0 39.0 57.0 31.0 46.0 43.0 55.0 59.0 Cadmium 2 ND ND ND ND ND ND ND 0.23 J ND ND ND ND 0.050 J 0.039 J ND ND 0.081 J 0.11 J Chromium 10 ND 2.32 JB 1.25 JB 3.90 JB 3.51 JB ND 1.5 J ND 4.70 ND 2.5 B 1.0 B ND ND ND 0.38 J 0.63 J 0.60 JLead154.04 J 4.07 J ND 6.38 JB ND 0.96 J 2.3 J ND 0.56 J 0.47 J 0.53 J 0.50 J 0.77 J 0.56 J 0.61 J 0.45 J 0.84 J 0.94 J Mercury 1 ND ND ND ND ND ND ND ND ND ND ND 0.39 0.37 0.029 J 0.26 0.14 J 0.014 J NDSelenium20NDNDNDNDNDNDNDNDND0.67 J 0.75 J 0.92 J ND 0.22 J ND 1.90 4.20 0.79 J Silver 20 ND 2.07 JB 3.72 JB 1.69 JB 0.95 JB ND ND ND ND ND ND ND ND ND ND ND ND 0.038 J 60 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.75 NDMethylene Chloride 5 ND ND 0.910 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Sampling Date:2L Standard 10/24/07 4/29/08 10/14/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/26/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 Well No:SW-1(Exp)Arsenic 10 4.32 J ND ND 1.96 J ND ND ND ND 0.79 J 0.23 J ND ND ND ND ND ND 0.35 J 0.59 J Barium 700 36.2 J 44.4 JB 17.9 JB 21.7 JB 10.5 JB 12.00 9.5 J 13.00 33.00 21.00 21.00 26.00 43.00 34.00 30.00 43.00 33.00 45.00Cadmium2NDNDNDNDNDND0.2 J ND ND 0.31 J ND ND ND ND ND ND 0.049 J 0.10 J Chromium 10 1.61 J 1.73 JB ND 2.71 JB 2.58 JB ND 1.3 J ND 8.30 ND 4.7 B 1.4 B ND ND ND ND 0.68 J 0.79 JLead154.88 J 6.43 J ND 4.49 JB ND 0.76 J ND 0.83 J 7.50 0.95 J 0.44 J ND 1.10 0.27 J 0.35 J ND 0.43 J 1.10 Mercury 1 ND ND ND ND ND ND ND ND 0.23 ND ND ND ND ND ND ND ND ND Selenium 20 ND ND ND ND ND ND ND ND 0.79 J 1.10 1.00 0.68 J ND 0.22 J ND 1.40 0.86 J 0.36 JSilver20ND2.53 JB 3.75 JB 1.66 JB 0.98 JB ND ND ND ND 0.22 J ND ND ND ND ND ND ND 0.018 J Styrene 70 0.260 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NOTES: Results in parts per billion (ppb) ND - Not Detected above the laboratory method detection limit or practical quantitation limit (results prior to April 2007).* - Monitoring well MW-17 was abandoned on August 30, 2011 to make way for landfill expansion NA - Not analyzed for or not available and was replaced by monitoring well MW-17AR located outside the expansion footprint. Values in boldface exceed the corresponding 15A NCAC 2L .0202 groundwater quality standards. Results for sampling conducted prior to April 2007 as presented in previous GW reports prepared by Withers & Ravenel. J = Estimated value above laboratory method detection limit and below SWSL or reporting limit. B = Analyte found in associated field and/or laboratory blank. Table 3 (Continued) Historical Summary of Constituent Detections Central Carolina Tire Monofill Landfill Phase III (Planned) Permit # 43-04 1,2-Dichloroethene (cis and trans isomers) Harnett County, North Carolina 11112 BRANDING IRON PLACE, WENDELL, NC 27591 919-366-3663 Office ● 919-995-0363 Cell ● nautilusgeocon@gmail.com APPENDIX A Groundwater Sampling Forms EFM EQU PMENT CALIBRATION FORM Profect#: eC a',r.t-Client:^, llrs INSTRUMENT: Y\T fTC SERIAL No.: lo t-l too 't'l :- INSTRUMENT: Mt^)rooQ SERIAL NO.: OOJ Calibration Recorded eillfr Lot# SeEt.io Exp: gi3iir-7 Exp: 'ri3rllu Exp: rl:'tir 4b" /, ce'Gheck 7.0 c loC:' Lot# grsl Exp: tol:,\r1 Calibration Recorded EFM EQUI MENT Project #: CALIBRATION FORM r.,{r6t' Tr,GClient: uh<nt u.t { INSTRUMENT: V i r-)r 1 \'- INSTRUMENT: SERIAL NO.:A - g' \-- Galibration Recorded Bv 5 L V{izl i ;Lot# 2 \ic.t 1?c* Exp: .l l: rl) : ?lr, llt*a,1 9-r-,l,)i {s t'1 Y',/ Lot# 8'tSl Exp: tol:,\11 Air Temp= /.\-^ ? Air Temo= t f Calibration Recorded Date: 4l t3 /16 Time: Start c,RPC am/pm Finish o tsE am/pm INA TIRE, PERMIT #4304 4Collector(s)1J Leave; D Hill Client. NAUTILUS Project No: CENTRAL Site Location: CAMERON, NC Weather Conds: fv, r ,r v S-Y'- No. of Containers Groun Water Sample Collection Record l/Piezo lD: ;A,'v ^17 Wett K Piezometer ! e. LeJgtn of Water Column - ' r' S- 1a-b; f. Calculated WellVolume (see back) | . a) WELL PURGING DATA a. Purge Method FLOW Pumping Rate: / C' O ml/min b. Acceptance Criteria (from workplan) - Minimum Required Pu Volume (@ _NA_ well volumes) _NA. - Maximum Allowable Tu ity NTUs 10%- Stabilization of Make Model WATER LEVEL DATA: (measured a. TotalWell Length t.'a i^A b. Water Table Depth 6 , c/ f c. Field Testing Equipment e. Acceptance criteria Has required volume Has required turbidity Have parameters stab lf no or NiA - SAMPLE COLLECTION: Comments Top of Casing) c. Casing Material _pvc_ d. Casing Diameter _2"_ removed n reached below. PERISTALTIC PUMP Serial NumberYSI 556 a.i l:t cl *t c 5- Yes,&fr* No N/An!nnDN Signature ,.'": :-U +2,.1.,r, |Xe.-Date .-4t r)/16 OLOGIC Date: 4/ (5 /16 NATIRE, PERM]T #/3O4 Time. Start c,g /O am/pm Collector(s) 6 j L..avei,1)_ nitt Client NAUTILUS Project No: QENIEALCAB Site Location: CAMERON, NC Weather Conds: \Lrre nj r/ <-- 7 4304- '\nW I Groun Water Sample Collection Record ID:,,t''-/.-3 Well ry Piezometer tr e. Length of Water Column i C . t.?(a-b) WATER LEVEL DATA: (measured Top of Casing) a. Total Well Lengtn .tc. fO c. Casing Material _pvc- d. Casing Diameter _2"- removed reached PERISTALTIC PUMP Yes,6*tu b. Water Table Depth .-{ i 1 c. Field Testing Equi e. Acceptance criteria Has required volume Has required turbidity Have parameters lfnoorN/A-E SAMPLE COLLEGTION: Serial NumberYSI 556 c.'(l<t t( 7t'.l No N/ANDDDDD t16 f. Calculated WellVolume (see back) i -7 WELL PURGING DATA a. Purge Method OW FLOW Pumping 3s1"' '3. c(: ml/min b. Acceptance Criteria (from workplan) - Minimum Required Pu Volume (@ _NA_- well volumes) --NA - Maximum Allowable T N/A NTUs --aCYo - Stabilization of Make Model Comments Date_41 ('\ Groun Water Sample Collection Record 7Tl Lv, -/. Well F- Piezometer n Length of Water Column I ('-- ( -3 1a-O; Calculated WellVolume (see back) -" I WATER LEVEL DATA: (measured a. TotalWell Lengtn tt .? C b. Water Table Depth WELL PURGING DATA a. Purge Method - Stabilization of c. Field Testing Equipment e. Acceptance criteria Has required volume Has required turbidity Have parameters stabi lf no or N/A - Expla SAMPLE GOLLEGTION: Comments Signature .4, b. Acceptance Criteria defi (from workplan) - Minimum Required P - Maximum Allowable T Top of Casing) c. Casing Material _pvc_ d. Casing Diameter 2"_ FLOW Pumping Rate: l( C mt/min 10 o/o : Make Model it removed reached PERISTALTIC PUMP YesffiE-tu Serial Number No N/ADNnntrr LOGIC_ Dale'. q 13 /16 TIRE, PEEMIf #904 Time: Start z'cr'C: am/pm Client: NAUTILUS Project No: CENTML Site Location: CAMERON, NC Weather Conds: lur.JnrV ( z No. of Containers 4304-Mta"'ri- RCRA METALS a./:':Date_4| (3 116 PERr\nr#4304 ?''J: S,iJdkam/pm Finish l9& am/pm Client: NAUTILUS Project No: CENTRAL Site Location: CAMERON, NC Collector(sf, -Jlbqvel r/ ?- \-- Container T 500 ml PI-ASTIC WATER LEVEL DATA: (measured Top of Casing) a. Totalwell Length i f --LC c. Casing Material -pvc- d. Casing Diameter -2- removed reached PERISTALT]C PUMP a. Purge Method FLOW Pumping Rate: i '1L' mlimin b. Acceptance Criteria (from workplan) - Minimum Required Pu Volume (@ _NA-- well volumes) _NA - Maximum Allowable T N/A NTUs--fi-Yo- Stabilization of Make Model Ground Water Sample Collection Record o llJ:/v\vL' - i g Wett*T Piezometer I e. Length of Water Column ? " i a 1a-01 f. Calculated WellVolume (see back) f - '+ Serial Number b, WaterTable Depth 1 ' CrK WELL PURGING DATA c. Field Testing Equipment e. Acceptance criteria Has required volume Has required turbidi$ Have parameters lf no or N/A - Expla SAMPLE COLLECTION: Comments Yesw+W No N/AurtrtrDf, Signature Date_41 [7 116 CENTRAL CAROL Site Location: CAMERON. NC therConds: -rL .tr'Ntz - i' ;EOLOGIC Date: 4l i Z nA NA TIRE, PERMIT #4304 Time: Start t 3 t .?- am/pm Finish lYrO am/pm Collector(s) J Leaver-D Hill WATER LEVEL DATA: (measured Top of Casing)Well k Piezometer D e. Lengthof WaterColumn 13 - <1 @-b) f. Calculated WellVolume (see back) .? - 2- Grou Water Sample Collection Record f,tU''-'^ t ( Serial Number WELL PURGING DATA a. Purge Method FLOW Pumping Rate: i C'C,-mumin b. Acceptance Criteria (from workplan) - Minimum Required Pu Volume (@ _NA_well volumes) _NA - Maximum Allowable T itv N/A NTUs - Stabilization of pa 10 o/o Make ModelYSI 556 a. Total Well Length a 3 t f b. Water Table Depth iC" c; ,?- c. Field Testing Equipment e. Acceptance criteria Has required volume Has required turbidity Have parameters stabil lfnoorN/A-E below. SAMPLE COLLECTION: Comments c. Casing Material pvc-- d. Casing Diameter _2'_ PERISTALTIC PUMP Yes4W W c?A* tc,r.(c'T 1 ..1 'lt 1r'I ( t,u/ removed reached No N/AuINDDX Signature Date q {'< /16 OGIC Date. 4l i'7 116 TIRE, PERMIT #4304 Time: 513;1 I Y z?* am/pm Collector(sl J Leaver,t Hill Client: NAUTILUS Project No: CEI!I841 Site Location: CAMERON, NC Weather Conds. \v;J^rL/ i'.' lC r.:C.) No. of Containers 4304- rtqw't'] 4304- /4wtt ,,4 500 ml PI-ASTIC WATER LEVEL DATA: (measured Top of Casing) lllPiezo lD: .t'tt,i-'- - 1 ^l ? wel 6 Piezometer tr e. Length of Water Column i'C .? C (a-O) f. Calculated WellVolume (see back) t ,-l Grou Water Sample Collection Record a. Total Well Length .Q.b , Y O b. Water Table Depth ti :l O c. Casing Material _pvc_ d. Casing Diameter _2"_ WELL PURGING DATA a. Purge Method OW FLOW Pumping nate '? t)()ml/min b. Acceptance Criteria - Minimum Required (from workplan) Volume (@ _NA_ well volumes) _-NA. - Maximum Allowable T ity N/A NTUs 10%- Stabilization of par c. Field Testing Equipment : Make Model e. Acceptance criteria Serial NumberYSr 556 O(i/.:Ic / .j. .i Yeg&& No N/ANt]TNtrnE_ Has required volume Has required turbidity removed reached Have parameters lf no or N/A - Expla below. SAMPLE COLLECTION:PERISTALTIC PUMP Comments Date_4| lj t16 OLOGIC Date. 4l 13 t16 NW304 Time: Start t t3?am/Pm Finish /C -i c am/pm Collector(s). J Leavq,)D Hill Client: NAUTILUS Project No: CE_NfB L Site Location: CAMERON, NC Weather Conds: lr-,,.vnry ?c' liPiezo I /t\Lw - i 6 Grou Water Sample Collection Record WATER LEVEL DATA: (measured Top of Casing)Well # Piezometer tr e. Length of Water Column ? , 8'l f. Calculated WellVolume lsee back) 1 " a. TotatwellLength .?.tr LC b. Water Table Depth i ? .i1 WELL PURGING DATA c. Field Testing e. Acceptance criteria Has required volume Has required turbidity Have parameters lf no or N/A - SAMPLE COLLECTION: Comments c. Casing Material _pvc_ d. Casing Diameter _2_ removed reached below. PERISTALTIC PUMP Make Model Serial NumberYSI 556 [,,i/r*t+t,ic,i' (a-b) a. Purge Method OW FLOW Pumping 331s' .?c'( ' ml/min b. Acceptance Criteria (from workplan) - Minimum Required P Volume (@ _NA_ well volumes) _NA - Maximum Allowable T N/A NTUs ---Tc-Yo - Stabilization of Yes No N/Agutr#nn.wnn Signature -.4 -2 Date- 4/ t3 116 Groun Water Sample Collection Record WATER LEVEL DATA: (measured Top of Casing) a. TotalWellLengtn 4C &, b. WaterTable Depth i7 .C + ength of WELL PURGING DATA a. Purge Method OW FLOW Pumping P"1"' ,r{- (l mVmin b. Acceptance Criteria (from workplan) - Minimum Required Pu Volume (@ _NA_ well volumes)_NA - Maximum Allowable T N/A NTUs--Ao/o- Stabilization of Used: Make ModelYSI 556 f,"(/<tc_( 7.'' j OGIC Date: 4l ('3 /16 NA T|RE, pEnnrttr *+go+ Time: Start I C 7c' am/pm L ,so Collector(s)i'J Leavbio Hill Client: NAUTILUS Project No: CENTRAL Site Location: CAMERQN, NC Weather Conds: \.t' 4344- ALt t e ID:/t\Lv' - / C) Piezometer n WaterColumn I ? . Y C ta-ol f. Calculated WellVolume (see back) ? , tl Serial Number Well e.Lc. Casing Material d. Casing Diameter _pvc_ _2"_ c. Field Testing E e. Acceptance criteria Has required volume Has required turbidity n removed reached No N/AntrDDDTHave parameters lf no or N/A -below SAMPLE COLLECTION: Yes*wW Method: PERISTALTIC PUMP Comments Date 4t t'3 t16 OLOGIC Date: 4/t 3 /16 Time: start 163{ am/pmPrqect No: CENIE L Site Location: CAMERON, NC RCRA METALS500 ml PLASTIC Grou Water Sample Collection Record Top of Casing)Well n tD: p(J-f Piezometer tlWATER LEVEL DATA: (measured a. Totalwell Lengtn I[)' oc2 b, water rable Depth {, / I, - Maximum Allowable T - Stabilization of c. Field Testing EquipmentlUsed: e. Acceptance criteria c. Casing Material pvc d. Casing Diameter -2- removed reached PERISTALTIC PUMP N/A NTUs3o/o Make Model Serial NumberYSI 556 iofl(oeVqtt Has required volume Has required turbidity Have parameters s lf no or N/A -below. SAMPLE COLLECTION: Comments Yes No N/AfliltrEft tr.EDI e. Length of water cotumn t.{' (t O-ol f. Calculated WellVolume (see back) I .-S? WELL PURGING DATA a. Purge Method oW FLOW Pumping aate: I O(2 -mvmin b. Acceptance Criteria (from workplan) - Minimum Required Pu Volume (@ _NA_ well volumes)-NA Signature Date_4t I ) t16 11112 BRANDING IRON PLACE, WENDELL, NC 27591 919-366-3663 Office ● 919-995-0363 Cell ● nautilusgeocon@gmail.com APPENDIX B Laboratory Reports And Chain-of-Custody Records Page 1 of 60 Page 2 of 60 Page 3 of 60 Page 4 of 60 Page 5 of 60 Page 6 of 60 Page 7 of 60 Page 8 of 60 Page 9 of 60 Page 10 of 60 Page 11 of 60 Page 12 of 60 Page 13 of 60 Page 14 of 60 Page 15 of 60 Page 16 of 60 Page 17 of 60 Page 18 of 60 Page 19 of 60 Page 20 of 60 Page 21 of 60 Page 22 of 60 Page 23 of 60 Page 24 of 60 Page 25 of 60 Page 46 of 60 Page 47 of 60 Page 48 of 60 Page 49 of 60 Page 50 of 60 Page 51 of 60 Page 52 of 60 Page 53 of 60 Page 54 of 60 Page 55 of 60 Page 56 of 60 Page 57 of 60 Page 58 of 60 Page 59 of 60 Page 60 of 60 Page 1 of 60 Page 2 of 60 Page 3 of 60 Page 4 of 60 Page 5 of 60 Page 6 of 60 Page 7 of 60 Page 8 of 60 Page 9 of 60 Page 10 of 60 Page 11 of 60 Page 12 of 60 Page 13 of 60 Page 14 of 60 Page 15 of 60 Page 16 of 60 Page 17 of 60 Page 18 of 60 Page 19 of 60 Page 20 of 60 Page 21 of 60 Page 22 of 60 Page 23 of 60 Page 24 of 60 Page 25 of 60 Page 26 of 60 Page 27 of 60 Page 28 of 60 Page 29 of 60 Page 30 of 60 Page 31 of 60 Page 32 of 60 Page 33 of 60 Page 34 of 60 Page 35 of 60 Page 36 of 60 Page 37 of 60 Page 38 of 60 Page 39 of 60 Page 40 of 60 Page 41 of 60 Page 42 of 60 Page 43 of 60 Page 44 of 60 Page 45 of 60 Page 46 of 60 Page 47 of 60 Page 48 of 60 Page 49 of 60 Page 50 of 60 Page 51 of 60 Page 52 of 60 Page 53 of 60 Page 54 of 60 Page 55 of 60 Page 56 of 60 Page 57 of 60 Page 58 of 60 Page 59 of 60 Page 60 of 60