7301 Person County LF Nov 2024 Semi Annual GWM Report

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DENR USE ONLY ❑Paper Report [:]Electronic Data - Email CD (data loaded: Yes / No Doc/Event #:
NC DENR I I Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
Smith Gardner, Inc.
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Seth C. Rickerts, P.G.
E-mail: [e-mail]
Phone: [phone] x 135
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Person Co. Closed MSW Landfill Cedar Grove Ch Rd. Roxboro, NC 73-01 .0500 April 23, 2024
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring ❑X Detection Monitoring ❑X Assessment Monitoring Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells ❑
Leachate monitoring data El
water monitoring data
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Seth C. Rickerts, P.G. Project Geologist 919-828-0577 x 135
Facility tljiicgd dime (Print) Title 11/5/2024 (Area Code) Telephone Number
C.
Date
14 N. Boylan Avenue Raleigh, NC 27603
Facility Representative Address
F1370
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009
Affix NC Licensed/ Professional Geologist Seal
d�
SEAL 11/t%2&24
2758
y Ap*
LOCI
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Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
April 2024 Semi -Annual Groundwater Monitoring Report
Person County Landfill
NC Solid Waste Permit No. 73-01
Prepared for:
Person County Solid Waste Department
304 S. Morgan Street
Roxboro, North Carolina 27573
November 2024
Prepared by:
NCLIC.NO.F137O (ENGINEERING)
SMITH- GARDNER
14 N. Boylan Avenue, Raleigh NC 2?683 1 919.828.05??
© 2024 Smith Gardner, Inc.
This document is intended for the sole use of the client for which it was prepared and
for the purpose agreed on by the client and Smith Gardner, Inc.

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Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
April 2024 Semi -Annual Groundwater Monitoring Report
Person County Landfill
NC Solid Waste No. 73-01
Prepared For:
Person County
Roxboro, North Carolina
S+G Project No. Person-19-1
DocuSigned by:
E
can G. iZ1e",
3B8305C978EME6...
Seth C, Rickerts, P.G.
Project Geologist
DocuSigned by:
E
bal� Q. SimOL
B9779EBA711F488...
Joan A. Smyth, P.G.
Senior Hydrogeologist
November 2024
NC LIC. NO.F-1370 (ENGINEERING)
SMITH+GARONER
14 N. Boylan Avenue, Raleigh NC 2?603 1 919.828.057?
24

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Person County Landfill
NC Solid Waste No. 73-01
April 2024Groundwater Monitoring Report
Table of Contents
Page
1.0
INTRODUCTION......................................................................................................... 1
2.0
REGIONAL GEOLOGY.................................................................................................. 1
3.0
SAMPLING LOCATIONS.............................................................................................. 1
4.0
SAMPLING PROCEDURES.......................................................................................... 1
5.0
FIELD & LABORATORY DATA..................................................................................... 1
5.1 Field Results........................................................................................................... 1
5.2 Laboratory Analysis................................................................................................ 2
5.3 Laboratory Results................................................................................................. 2
5.3.1 Inorganic Constituents................................................................................ 2
5.3.2 Organic Constituents.................................................................................. 2
5.3.3 Surface Water Samples.............................................................................. 3
5.3.4 PFAS Analytical Results.............................................................................. 3
6.0
GROUNDWATER CHARACTERIZATION....................................................................... 3
7.0
ONGOING ASSESSMENT............................................................................................3
8.0
CONCLUSIONS...........................................................................................................4
FIGURE
Figure 1 Groundwater Potentiometric Map
TABLES
Table 1 Groundwater Elevation Data
Table 2 Field Parameters
Table 3 Analytical Monitoring Results
Table 4 PFAS Analytical Results
APPENDICES
Appendix A Well Logs
Appendix B Laboratory Analytical Reports
Appendix C Time vs Concentration Graphs
Person County Landfill April 2024 - Groundwater Monitoring Report
November 2024 Table of Contents Page i

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1.0 INTRODUCTION
The Person County Landfill (North Carolina Solid Waste Permit No. 73-011 is located northeast
of Roxboro on Cedar Grove Church Road between the intersections of Brann Farm Road and
Jack Brann Road. The landfill began as an approximately 88-acre undeveloped tract. In 1973
the site became the landfill for Person County. The property is composed of a closed unlined
municipal solid waste (MSW) landfill and a closed transfer station. The surrounding area is
currently developed as rural agricultural and residential. The site, which is composed of a
closed municipal solid waste (MSW) landfill and a closed C&D landfill performs semi-annual
groundwater monitoring in accordance with Solid Waste Section Rule 15A NCAC 1313.0600. This
report presents the semi-annual sampling results for the event conducted on April 23, 2024;
and includes a field procedure summary, laboratory analyses and groundwater characterization
for the site. The laboratory analytical results and a single -day potentiometric surface map are
also included.
2.0 REGIONAL GEOLOGY
The Person County Landfill is located near Roxboro, North Carolina in the Piedmont
Physiographic Province. Local soils are primarily fine silty clays to clayey silts. Bedrock has
been encountered in low-lying areas at the site at approximately 12 feet below grade.
Groundwater flows in the unconsolidated sediments above bedrock.
3.0 SAMPLING LOCATIONS
Samples were collected during this event by staff from Waypoint, Inc. from eleven monitoring
Locations. The locations sampled this event included eight wells (MW-1 through MW-7 and MW-
7D) and three surface water locations (SW-1 through SW-3). Available well logs are provided in
Appendix A and monitoring well locations can be found on Figure 1.
4.0 SAMPLING PROCEDURES
Prior to sample collection, the depth to water in each well was gauged. Measured depths to
water, collected prior to purging, are presented in Table 1.
Samples were collected in laboratory prepared containers for the specified analytical
procedures. Groundwater samples were properly preserved, placed on ice and transported to
the laboratory facility within the specified holding times for each analysis. As part of quality
control, a trip blank was analyzed for Appendix I volatile organic compounds (VOCs).
5.0 FIELD B LABORATORY DATA
5.1 Field Results
Temperature, pH, turbidity, and specific conductance were measured in the field at the
time of sampling via direct read instruments. The field parameter results are
summarized in Table 2 and have remained consistent with previously reported sampling
Person County Landfill April 2024- Groundwater Monitoring Report
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events. All groundwater samples except MW-1, MW-4, MW-6, and MW-7 exhibited
turbidities above 10 NTUs during this event.
5.2 Laboratory Analysis
The groundwater samples were transported to Waypoint Analytical. Samples were
analyzed for the Appendix I VOCs via EPA Test Method 8260B, for 1,4-dioxane by EPA
Test Method 8260 SIM, and Appendix I metals via EPA Test Method 200.8.
Samples were also analyzed by APPL Laboratories' for PFAS constituents by EPA
Method 1633 in response to the March 2023 NCDEQ requirement to sample all
monitoring wells at landfills for this list of constituents.
5.3 Laboratory Results
Analytical results were compared to 15A NCAC 2L.0200 (21- Standard and 2L Interim
Maximum Allowable Concentrations), Solid Waste Section established Groundwater
Protection Standards (GWP) for groundwater samples and the 15 A NCAC 2B Standard
for Class C waters (213 Standard) for surface water samples.
Most constituents were either below the method detection limit (MDL) or were identified
by the laboratory as a "J-value" indicating they were detected at a concentration
between the MDL and MRL (Method Reporting Limit). The laboratory analytical report is
included as Appendix B.
5.3.1 Inorganic Constituents
One inorganic constituent was detected above the NCAC 2L standard during this
event:
• Chromium (MW-4).
A table showing inorganic detections in groundwater is presented as Table 3.
5.3.2 Manic Constituents
Detected organic constituents are presented in Table 3. The following seven
constituents were detected above the 2L standard or NC Groundwater Protection
Standard this event:
• 1,1-Dichloroethane (MW-3);
• 1,2-cis-Dichloroethylene (MW-3);
• 1,2-Dichloropropane (MW-2, MW-3, and MW-5);
• Benzene (MW-3, and MW-5);
• Tetrachloroethylene (MW-2, MW-3, and MW-7D);
' APPL Laboratories, 908 N. Temperance Ave., Clovis, CA.
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• Trichloroethylene (MW-3); and
• Vinyl Chloride (MW-2, MW-3, MW-5, MW-7, and MW-7D).
5.3.3 Surface Water SaMD[es
No Appendix I list constituents were detected in surface water samples above
their NC2B standards this monitoring event. Detections are presented in Table 3.
5.3.4 PFAS Analvtical Results
Per- and Polyfluoroalkyl Substances (PFAS) are required to be sampled at all
solid waste sites after July 1, 2023 as directed in a March 13, 2023 NCDEQ
mem02. This semi-annual groundwater monitoring report represents the second
report for the Person County Landfill where PFAS analysis was performed. PFAS
constituents were detected in sampling locations MW-1, MW-2, MW-3, MW-4,
MW-5, MW-6, MW-7, MW-MW-7D, SW-1, SW-2, and SW-3 this event. Resampling
of MW-4 and MW-5 for PFAS was performed in August of 2024 to confirm the
results of the Spring sampling event. All PFAS constituents detected this
sampling event and during the resampling event are shown on Table 4.
6.0 GROUNDWATER CHARACTERIZATION
Groundwater elevations range across the site from approximately between elevation 550 ft.
amsl3 to approximately 610 ft. amsl. A potentiometric surface map was prepared from
groundwater elevation data collected this event. Data indicates groundwater is flowing to the
east and southeast toward Mayo Creek. The potentiometric surface map is presented as Figure
1.
7.0 ONGOING ASSESSMENT
Water quality monitoring has been conducted at the facility since approximately 1995 on a semi-
annual basis. Recent water quality monitoring events have reported concentrations of inorganic
and organic constituents that exceed water quality standards.
Two additional downgradient assessment monitoring wells were installed between MW-3 and
Mayo Creek in December 2019. MW-7 and MW-7D were constructed in accordance to 15A
NCAC 02C .0113, MW-7 and MW-7D are a nested pair of one shallow well (9' bgs) and one deep
well (17' bgs) to better monitor the vertical extent of groundwater contamination. An additional
surface water location was also sampled adjacent to assessment wells MW-7 and MW-7D to
further evaluate water quality in this area. An Assessment Evaluation Report was submitted to
the SWS under a separate letter in February 2023.
2 NCDEQ Memorandum. March 13, 2023, re: PFAS Monitoring Requirements for Solid Waste Sanitary Landfills. Ed
Mussler, Section Chief. FID: 1776799.
3 amsl — above mean sea level
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8.0 CONCLUSIONS
Laboratory results indicate that water quality at the Person County Landfill is generally
consistent with reported historical detections. One inorganic parameter, chromium, was found
to be in exceedance in groundwater well locations during this event, though turbidity was above
10 NTUs in four out of the eight wells sampled. Organic constituents, chlorinated solvents in
particular, are still being detected at the Person County Closed Landfill. Vinyl chloride is a
typical chlorinated solvent degradation end product and is likely evidence that reductive
dechlorination is occurring on site. MW-3 saw a high increase in VOC concentrations during this
event and will be closely monitored in the Fall 2024 event to confirm the veracity of the
concentrations.
As mentioned above, this is the second monitoring event in which PFAS constituents were
analyzed at the Person County Landfill. Several constituents falling under the PFAS class of
constituents were detected in samples collected during this event, with at least one PFAS
constituent detected in each sampling location monitored. Resampling of MW-4 and MW-5 after
the spring event confirmed the results from this monitoring event. The next groundwater
monitoring event is scheduled for the Fall of 2024. Results will be reported to NCDEQ after
receipt and analysis of laboratory data.
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FIGURE
April 2024 Groundwater Monitoring Report
Person County landfill
NC Solid Waste Permit No. 73-01

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TABLES
April 2024 Groundwater Monitoring Report
Person County Landfill
NC Solid Waste Permit No. 73-01

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SMITH GARDNER
ByDF
11te0531224
Ground
Well
Well
Total Well
TOC
Water Table
Screen
Lithologyof
Monitoring
Surface
Depth to
Location
Installation
Northing
Easting
Diameter
Depth (ft
Elevation (ft
Elevation (ft
Water (ft) s
Elevation (ft
Interval (ft
Screened
Date
( in
b s 6
g)
7
asl
m
b s
g)
s
b g)
Interval
amsl
MW-1
NA
960316.51
2022448.33
2.0
61.23
NA
648.29
40.32
607.97
NA
NA
MW-2
NA
958884.81
2023372.09
2.0
20.68
565.77
567.57
2.20
565.37
NA
NA
MW-3
NA
958074.38
2023433.77
2.0
22.37
563.76
565.51
4.90
560.61
NA
NA
MW-4
11/27/1995
959014.35
2022856.13
2.0
17.93
587.23
588.54
10.36
578.18
6' - 16'
Saprolite
MW-5
11/27/1995
958656.26
2023465.08
2.0
11.55
565.72
567.68
5.85
561.83
4' - 9'
Silty Clay
MW-6
11/27/1995
957812.59
2022789.32
2.0
12.95
571.58
573.45
6.06
567.39
6.5' - 11.5'
Saprolite
MW-7
12/5/2019
NA
NA
2.0
12.44
555"
559
6.71
552.29
4'- 9-
PWR
MW-71D
L 12/5/2019
NA
NA
2.0
21.32
555*
559
7.62
551.38
12'-17'
PWR/Rock
NOTE:
1.) NA = not available
2.) bgs = below ground surface
3.) amsl = above mean sea level
4.) Well depth and depth to water from Environment 1, Inc. report dated 05/17/2024, Client ID#6034
5.) GSE estimated from ground surface contours
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SMITH GARDNER
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1
-• fie
Monitoring
Location
pH (std units)
Conductivity @
25°C
(µmhos/cm )
Turbidity (NTU)
Temperature (°C)
M W-1
5.8
92
18.0
16
MW-2
6.8
1270
5.1
15
MW-3
5.9
360
4.5
15
MW-4
6.4
1397
65.0
16
MW-5
6.1
701
7.8
14
MW-6
5.6
69
24.5
14
MW-7
6.2
204
14.7
14
MW-7D
7.0
262
2.0
14
SW-1
6.9
62
-
19
SW- 2
6.7
216
-
19
SW- 3
1 6.6
1 158
1-
19
NOTE: Field data collected by Environment 1 personnel.
Data from Environment 1, Inc. report dated 05/17/2024, Client ID#6034
Bold indicates turbdity >10
By DJ F
Me05'312224
K Rqects\ GardAdEr Nkrftcn r# 2 GardufEr MTltcn rU Rpats\ Pm;w (h 13.$irg2(2Agwg2O24PasmGVWesAs(

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
SMITH GARDNER Tdie3 �°`
Etdytia MritairgFbsdts 04.0513YM
F§soi(hriylaidill
gcril 42024
Monitoring Results
Sample Date
Units
NC21-
NC2B
NC2B-P
4/23/2024
4/23/2024
4/23/2024
4/23/2024
4/23/2024
4/23/2024
4/23/2024
4/23/2024
4/23/2024
4/23/2024
4/23/2024
StationName
MW-1
MW-2
MW-3
MW-4
MW-5
MW-6
MW-7
MW-7D
SW-1
SW-2
SW-3
Metals
Arsenic
ug/1
10
150
0.28 J
0.32 J
5
0.36 J
0.71 J
0.2 J
0.32 J
2.7 J
1.7 J
1.2 J
Barium
ug/1
700
21000
35.9
42.2
7.8 J
72.2
54.8
19.2
30.4
6.9 J
128
95.8
48.8
Cadmium
ug/1
2
0.21 J
Chromium
ug/1
10
0.44 J
11
1.6 J
0.64 J
15
3.1 J
0.4 J
Lead
ug/1
15
25
1.11
0.15 J
1.11
1.3 J
19
2.9 J
0.4 J
Selenium
ug/1
20
5
0.52 J
0.71 J
Silver
ug/1
20
0.15 J
Other
1,1-Dichloroethane
ug/1
6
1.1
42.0
3.3
1.3
1.4
1,1-Dichloroethylene
u /1
350
0.83 J
1,2,4-Trichlorobenzene
ug/1
70
0.67 J
0.80 J
1,2-cis-Dichloroethylene
u /1
70
5.6
170
61.2
4.9
3.7
1.5
0.66 J
1,2-Dichloropropane
ug/1
0.6
2.8
2.7
0.74J
1,2-trans-Dichloroethylene
u /1
100
1.8
0.591
1,4-Dichlorobenzene
ug/1
6
2.1
2.9
0.34J
2.3
Benzene
ug/1
1
7.7
1.9
Chlorobenzene
ug/1
50
3.9
1.0
1
5.0
Chloroethane
ug/1
3000
4.0
1.6
Dichlorodifluoromethane
ug/1
1000
0.81 J
Diisopropyl Ether
ug/1
70
0.43 J
Methyl tert-Butyl Ether (MTBE)
ug/1
20
1.2
0.86 J
Tetrachloroethylene
u /1
0.7
1.5
37.6
0.50 J
3.8
Toluene
ug/1
600
0.45 J
Trichloroethylene
ug/I
3
0.53J
34.3
0.57J
1.7
1.2
Trichlorofluoromethane
ug/I
2000
1
1
0.78J
Mnyl chloride
ug/I
0.03
0.68 J
1 45.1
11.7
0.96 J
0.69 J
NOTES:
ug/L = micrograms per liter
BOLD = Constituent exceeds NCACO21- or G1AP regul atory I imits
SaD =Constituent exceeds NCACO2B m 2B Protection regulatory limits
J = Lab estimated concentration
BDL =constituent is below laboratorydetection limits
NA= Not Analyzed
MAcjedsl(inrrbtlaM1trdaircJ2OurLctefW ilairgRlsAs1Po�61.4�irg3¢m�ircj2Y4F8snfSVC�i�dsc

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
SMITH+GARONER '� �m
H�kgytia MiitairgF�alts �tima�
Rrs:n&rty1ad11
Fpi14n4
Monitoring Results
Sample Date
Units
4/23/2024
4/23/2024
4/23/2024
4/23/2024
8/27/2024
4/23/2024
8/27/2024
4/23/2024
4/23/2024
4/23/2024
4/23/2024
4/23/2024
4/23/2024
StationName
MW-1
MW-2
MW-3
MW-4
MW-4
MW-5
MW-5
MW-6
MW-7
MW-7D
SW-1
SW-2
SW-3
PFAS
Perfl uorobutanoic Acid (PFBA)
n /L
BDL
350
52
2000
1900
360
390
90
32
14
180
190
Perfluoropentanoic Acid (PFPeA)
ng/L
BDL
360
65
5900
4600
810
820
100
55
16
BDL
300
320
Perfluorohexanoic Acid PFHxA
n /L
0.111
1 950
250
1 18000
13000E
1800
1900B
1 83
150
68
6.4J
750
1 880
Perfl uoroheptanoicAcid (PFHpA)
ng/L
1 0.121R2J
660
80
22000AE
1 22000
2000
2100
31
130
1 27
9.2J
620
910
Perfl uorooctanoic acid PFOA
n /L
0.87 M14
1700 MI4
190 MI4
70000 AE
94000
4000 MI4
3600
200 MI4
530 MI4
76 MI4
22 J
2700
4000
Perfluorononanoic Acid (PFNA)
ng/L
BDL
10
0.94
360
9801
14
12
10
8.4
0.82
BDL
49M15
85M15
Perfl uorodecanoic Acid (PFDA)
n /L
BDL
BDL
BDL
8
BDL
BDL
BDL
3.9J
0.82
BDL
BDL
BDL
8.5M12J
Perfl uoroundecanoicAcid (PFUnA)
ng/L
BDL
BDL
BDL
1.6J
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Perfl uorobutane Sulfonic Acid PFBS
n /L
2.7
280
55
10000
7000
1100
880
740
130
31
8.3J
550
660
Perfl uoropentane sulfonic acid (PFPeS)
ng/L
0.111
210
21
10000
7300
500
410
190
69
20
BDL
330
390
Perfluorohexane Sulfonic Acid PFHxS
n /L
0.14 MI4 J
1 320
25 MI4
16000
16000
1 450
380
190 MI4
110
20
1 6.3 MI5 J
500
1 690 MI5
Perfluoroheptanesulfonicacid (PFHpS)
ng/L
I BDL
23
2.1
1500
1200
22
BDL
30
20
1.8
BDL
61
110
Perfluorooctanesulfonic acid PFOS
n /L
0.4
350
54
1 10000
11000
190
120
1100
600
130
65 M12
2100
3000
6:2Fluorotelomersulfonate(6:2FTS)
ng/L
BDL
BDL
0.30J
5.5J
BDL
BDL
2.4J
BDL
BDL
BDL
BDL
BDL
BDL
1H,1H,2H,2H- Perfl uorodecane sulfonic acid 8:2 FTS
n /L
BDL
BDL
BDL
BDL
BDL
BDL
0.591
BDL
I BDL
BDL
BDL
BDL
BDL
PerfluorooctaneSulfonamide(PFOSA)
ng/L
BDL
2.1M14J
0.58
44
BDL
4.3MI4
0.26J1
2.3M14J
7.7
2.2
BDL
35MI5
38
WrnethA perfluorooctanesulfonamidoaceticacid N-McFOSAA
n /L
BDL
BDL
2.3
78
BDL
13
10
BDL
7.4
BDL
BDL
36
45
Wethylperfluorooctanesulfonamidoaceticacid (NEtFOSAA)
ng/L
BDL
BDL
BDL
4.6MI4
BDL
BDL
I BDL
BDL
0.361R2MI5
I BDL
BDL
I BDL
BDL
Perfl uoro-3-metho ro anoicacid PFMOPrA
n /L
BDL
BDL
0.13J
4.9J
BDL
BDL
BDL
BDL
BDL
BDL
B
B
BDL
Perfl uoro(4-methoxybutanoic)acid (PFMOBA)
ng/L
BDL
BDL
0.19J
11
BDL
BDL
BDL
BDL
BDL
BDL
BELL
BELL
BDL
-3-oxahexanoicacid Gen
n/L
BDL
2.3JPerfuoro-2-meth
0.17
BD
BDL
BDL
BDL
BDL
0.28J
BDL
BDL
I BDL
BDL
NOTES:
ng/L = nanograms per liter
J = Lab estimated concentration
I Val us is EMPC(estimated maximum possible concentration).
BDL = constituent is below laboratory detection limits
IR2 = Ion ratio above the lower control limit
M12=Manual integration, non -target peak interference
MI4=Manual integration, peak unspl it
M15 = Manual integration, whole peak was not integrated
MI6=Manual integration, wrong peak integrated
AE=Added EIS
B =Detected in Method Blank
H Out of hol ding time
MR eciAG nw3aAtrimir_320.rw36Kb tairgr4iYd lasmm. 119nr920249arg2L4FiwnGWaJeads

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
AppendixA
Well Logs
April 2024 Groundwater Monitoring Reports
Person Closed landfill
NC Solid Waste Permit No. 73-01

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
This page intentionally left blank.

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
F41,�
i
6`
PERSON COU114TY
4s� COUNT �
WASTE MANAGEMENT DEPARTMENT
Person County Courthouse
Courthouse Square
Roxboro, North Carolina 27573-5597
[phone]
January 16, 1996
Mr. Jim Bateson
State of N.C. Department of Environment, Health and Natural Resources
Division of Solid Waste Management
Solid Waste Section
P.O. Box 27687
Raleigh, North Carolina 27611-7687
Dear Mr. Bateson:
Please find attached a revised copy of the Topographic Survey of Person County Sanitary
Landfill Phase III B Closure which includes the location and elevation of three new monitoring
wells. Also attached are the drilling records for the three wells. This information should satisfy
Item E of the Consent Agreement between Person County and the State of North Carolina
regarding the C&D Landfill which was executed in November, 1995. It is also my
understanding that all conditions have now been met for the closure of Phase III B of the Person
County Sanitary Landfill.
If any additional information is needed, please contact me.
Sincerely,
P"'� Y--, 4a'�-L
Paul L. Bailey, F.E. V
Solid Waste Director
PLB/ltp
Enclosures 2
cc: File (1)
a:lwslletter-2.sam

FOR OFFICE USE ONLY
Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
t Jii7.`: C:.Li; LJNA DEPARTMENT OF NATURAL RLSOUnOES AND COMMUNITY DEVELOPMENT
DIVIC ON OF ENVIRONh7EN7AL L ANAGE:,:=NT - GROVNDWATEA SECTION
;',O. BOX 27887 - RAL EIGH,N_C. 27C 11. PHONE [phone]
WELL CONSTRU'�Z'ION RECORD Mti) _ k+ %
Quad. No.
Lat.
Minor Basin
Basin Code
Header Ent.
Serial No.
Long. Pc
DRILLING CONTRACTOR I-lL� 1-t Ps.I_Lz�C� 5 �2V105
STATE WELL CONSTRUCTION
DPILLER REGISTRATION NUMBER PERMIT NUMBER:
1. WELL LOC 1TION: (Show sketch of the location below) p
Nearest To vn: 4gac2 County:
C�12avC .L} 4&k Depth
(Road, Cor munity, or Subdivision and Lot No.)
f } 6po a � - From To
2. OWNER _ // i-
ADDRESS _ �C�.Z 2"Aa._Gecy�5_1 6& /040
ten
;totreet or RIe No.) '72-'?3
City o Town Stale Zip Code
3. DATE DRIL _ED 1 USE OF WELL "Z
r. TOTAL DEF TH fCr CUTTINGS COLLECTED ❑ Yes DdNo 1 6 7
5. DOES WELT_ REPLACE EXISTING WELL? ❑ Yes X No
u. STATIC WE TER LEVEL: /0 FT. ❑ above TOP OF CASING,
below
TOP OF CASING IS � FT. AB VE LAND SURFACE.
7. YIELD (gpn-): METHOD OF TEST
8. WATER ZONES (depth):
3. CHLORINA7'ON: Type Amount
0. CASING:
Wall Thickness
Depth Diameter or Weight/Ft.
From .� To _ 40 Ft.__d�
From To Ft.^.
From To Ft.-
1. GROUT:
From
Depth
To
2
Material
FI:�:TI7On1/
From ©
To
Ft. &?n-tCie�T�
.2. SCREEN:
GW-1 Ent.
DRILLING LOG
Formation Description
1f additional space is needed use back of form.
Material
W,� LOCATION SKETCH
(Show direction and distance from at least two State Roads,
or other map reference points)
Method
P104g��_ �
40k_ -It%
Depth �� Diameter Slot Size Material
From �¢ To!t. Ft. in. o Ald in, JCS
From To Ft. _. in. in.
From. To Ft. in. in.
13. GRAVEL P -,CK:
Depth Size Material
From -'�Z � To & _ Ft. '/ 6A � C
From To F1
4. REMARKS:
I G ] HEREBY CERTIFY THAT THIS WELL WAS CONSTRU TED IN ACCORDANCE WITH 15 NCAC 2C, WELL CONSTRUCTION
ST, NDARDS, AND THAT A COPY OF THIS RECORD HA PROVi TO T WELL OWNER.
L i
SIGNATURE OF CONTRACTOR Ofi AGENT DATE
GW-1 Revised.. 1 W84 Submit original to Division of Environmental Management and copy to well owner.

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
.. L"" ­.,n,f-I—i Ur hA-L,;AL tI_t,tJurlGLt, AND COYV,!UNtTY DEVELO?h1t=NT
DMV ON OF PMRONNICNTAL MANAGEMENT - GROUNDWATER SECTION
1,.0. BOX 27687 - RALE30H.N.C. 27611. PHONE [phone]
WELL CONSTRUCTION RECORD Mid .�
FOR OFFICE USE ONLY
Quad. No. Serial No.
Lat. Long. pe
Minor Basin
Basin coda
Header Ent. GW-1 Ent.
DRILLING CONTRACTOR t+-L P - -l2ttlrtr.tC� rjL�etrlc�S
DRILLER REGISTRATION NUMBER ��r7 __ STATE WELL CONSTRUCTIONPERMIT NUMBER.
I. WELL LOCATION: (Show sketch of the location below)
Nearest To vn; K13.D tl?.0
E Ck4
(Road. Con munity, or Subdivision and Lot No.)
2. OWNER —
ADDRESS _ l C 2, CL�t�/}� C + ICE
Street or -Route No.
Al
3
City or Town State Zip Code
3. DATE DRIL _ED -7 S" USE OF WELL 4 A%/ 7-efe
4. TOTAL DEF TH CUTTINGS COLLECTED ❑ Yes Eg'No
5. DOES WELT_ REPLACE EXISTING WELL? ❑ Yes 6S No
6. STATIC WE TER LEVEL:--,? FT. [I above TOP OF CASING.
below
TOP OF CASING IS FT. A 0VE LAND SURFACE.
7. YIELD (gprr ): METHOD (:IF TEST
3. WATER ZONES (depth). -
:.I. CHLORINA','ON: Type
Amount
0. CASING:
Wall Thickness
Depth Diameter or Weight/Ft.
From To _ Fl._a,410
From To Ft.
From To Ft.
County: t tac 14
Depth DRILLING LOG
From pTo Formation Description
,�L4T-
CL
If additional space is needed use back of form.
Material
IC6 LOCATION SKETCH
(Show direction and distance from at least two Stale Roads,
or other map reference points)
1. GROUT:
Depth Material Method
From To__,'2- Fl—,&6 1MA11725
From To Ft. C -CIT AIJi�°L�
'2. SCREEN:
Depth Diameter Slot Size Material
From .�k To-_�L— Ft. .z ._ in. 110IO in_ �_
From To Ft. in, in.
From. To Ft. in. in.
3. GRAVEL P',CK:
Depth Size Material
From d9\ To r ` Ft. 4.1 _:S�b
From —To_ Ft..
4. REMARKS:
I C D HEREBY CERTIFY THAT THIS WELL WAS CONSTRU ED IN ACCORDANCE WITH 15 NCAC 2C, WELL CONSTRUCTION
ST, NDARDS, AND THAT A COPY Cl: THIS RECORD HAS , PROVI TO TN WELL OWNER. _
1.7a
SIGNATURE CIF CCNTRACTCR AGENT DATE
3W-1 Revised 11/84 Submit original to Division of Environmental Management and copy to well owner.

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
CARC Llrl:. DL?,1F77„ 7 T OF NAIV-1AL rtl:SOURCES AND COMIMUMTY DEVELOPMENT
DME ON OF L ,M11 JNMENTAL MANAGEMENT - GROUNDWATER SECTION
".O. BOX 27087 - RALEIGH.N.C_ 27(;11, PHONE [phone]C,3
WELL CONS T FUOT[Oj J RECORD
DRILLING CONTRACTOR ���t PS%��L►..1(} S._ d1c E5
DRILLER REGISTRATION NUMBER
I. WELL LOC 1TION. (Show pktch of the location below)
Nearest To vn: O I?Q
b- U 2- d5ZA22-
(Road. Con-.munity, or SPA�-
(vision and Lo I No.)
2. OWNER _ S as
ADDRESS- 647- (��tA-e-
nn(Street or Route No.)
x P—OP-0 ke Zz 73
Cit}dior-.State Zip Code
.3. DATE DRIL,-ED ! USE OF WELL AOAl-
TOTAL DEF TH CUTTINGS COLLECTED El Yes No
5. DOES WEL,, REPLACE EXISTING WELL? ❑ Yes WNo
5. STATIC Wf TER LEVEL: 4 FT. E3 above TOP OF CASING,
;9 below
TOP OF CASING IS FT. ABOVE LAND SURFACE.
7. YIELD (gprr ): METHOD OF TEST
S. WATER ZO:1ES (depth):
J. CHLORINA"ON: Type Amount
m
FOR OFFICE USE ONLY
Quad. No. Sedai 140.
Lat. Long. Pc
Minor Basin
Basin Coda
Header Ent.— GW-1 Ent._
STATE WELL CONSTRUCTION
PERMIT NUMBER:
County: -es,I
Depth DRILLING LOG
From To Formation Description
Y.
0. CASING:
Wa]i Thickness
_ tl additional space is needed use back of form.
Depth
diameter or Weight/Ft. Material
_
From
Q
�
LOCATION SKETCH
.
To Ft.
—V
(Show direction and distance from at least two State Roads,
From
To Ft.
or other map reference points) y f
From
To F t.--
—
1. GROUT:
Depth
Material Method
�'
BZNT��/ii �l4CD
From
To - �� Ft.
From
40
To.7,�' Ft.
6^^Ae�FT�_
2. SCREEN:
Depth
Diarleler
Slot Size Material
From To //
in. PI/C
From To
Ft.
in. in.
U
From _ T o
Ft. __
in. in.
t 3. GRAVEL P �CK:
VM1
Depth
Size
nJ
From To ,r.�
F1.1
!Material
JJ�7J7�
4
From To
Ft.�-
�}
:4. REMARKS:
ClFr-de-Z
I D D HERESY CERTIFY THAT THIS WELL WAS CONSTR CTED IN ACCOR ANCE WITH 15 NCAC 2C. WELL CCNSTRUCTION
ST, NDARDS, AND THAT A COPY OF THIS RECORD_ IAA EEC PROVIDED JHE VWLL OWNER.
�. /:2 �
SIGNATURE OF CONTRACTOR OR AENT DAT
GW-I revised 11/84 Submit original to Division of Environmental Management and copy to welt owner.

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
WL' LL l,VINL5I KU1 I IUI'N KLL l VKL
This form can be used for single or multiple wells
For Internal Use ONLY:
1. Well Contractor Information:
JEREMY RINGLER
Well Contractor Name
A - 4422
NC Well Contractor Certification Number
GEOLOGIC EXPLORATION, INC
Company Name
2. Well Construction Permit #:
List all applicable well construction permits (i.e. County, State, Variance, etc)
3. Well Use (check well use):
Water Supply Well:
❑Agricultural
❑Geothermal (Heating/Cooling Supply)
❑ hmdustrial/Commercial
❑ Irrigation
Non -Water Supply Well:
El Aquifer Recharge
El Aquifer Storage and Recovery
❑Aquifer Test
❑Experimental Technology
❑Geothermal (Closed Loop)
❑Geothermal (Heating/Cooling
❑Municipal/Public
El Residential Water Supply (single)
❑Residential Water Supply (shared)
El Groundwater Remediation
❑ Salinity Barrier
❑ Stormwater Drainage
❑Subsidence Control
❑Tracer
❑Other (explain under #21 F
4. Date Well(s) Completed: 12/05/19 Well ID# MW-6A
5a. Well Location:
PERSON COUNTY LANDFILL
Facility/Owner Name Facility ID# (if applicable)
542 CEDAR GROVE CHURCH ROAD ROXBORO 27574
Physical Address, City, and Zip
PERSON
County Parcel Identification No. (PIN)
5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees:
(if well field, one lat/long is sufficient)
360 23' 21.86" N 780 55' 26.07" W
6. Is (are) the well(s): ❑] Permanent or ❑Temporary
7. Is this a repair to an existing well: ❑Yes or ONo
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: 1
For multiple injection or non -water supply wells ONLY with the same construction, you can
submit one form.
9. Total well depth below land surface: 17.0 (ft.)
For multiple wells list all depths if different (example- 3@200' and 2@100')
10. Static water level below top of casing: 4.0 (ft.)
If water level is above casing, use "+"
11. Borehole diameter: 8.0/6.0 (in.)
12. Well construction method: AUGER/AIR
(i.e. auger, rotary, cable, direct push, etc.)
14. WATER ZONES
FROM
TO
DESCRIPTION
rt.
rt.
ft.
ft.
15. OUTER CASING for multi -cased wells OR LINER if applicable)
FROM
TO
DIAMETER
THICKNESS
MATERIAL
0.0 tL
10.0 tt•
6.0 i"
SCH 40
PVC
16. INNER CASING OR TUBING eother at closed -loop)
FROM
TO
DIAMETER
THICKNESS
MATERIAL
0.0 tf
12.0 tt•
2.0 "'
SCH 40
PVC
rt
rt
in.
17. SCREEN
FROM
TO
DIAMETER
SLOT SIZE
THICKNESS
MATERIAL
12.0 ft'
17.0 ft'
2.0 in.
.010
SCH 40
PVC*
ft.
ft,
in.
18. GROUT
FROM
TO
MATERIAL
EMPLACEMENT METHOD & AMOUNT
0.0 IL
ft-
8.0
PORTLANDBENTONITE
SLURRY
0.0 ft•
10.0 ft-
PORTLANDBENTONITE
SLURRY
rt
rt
19. SAND/GRAVEL PACK (if applicable)
FROM
TO
MATERIAL
EMPLACEMENT METHOD
11.0 tt•
17.0 tt•
20-40
FINE SILICA SAND
rt.
rt.
20. DRILLING LOG attach additional sheets if necessary)
FROM
TO
DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
0.0 tt•
5.0 tt•
BROWN SILT
5.0 tt
10.0
SILTY PWR
10.0 tt•
17.0 tt•
ROCK
rt.
ft.
rt.
rt.
ft.
fit.
rt.
fr.
21. REMARKS
BENTONITE SEAL FROM 8.0 TO 11.0 FEET
*PRE -PACK SCREEN*
22. Certification:
12/18/19
Signature of Certified Well Contractor Date
By signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a
copy of this record has been provided to the well owner.
23. Site diagram or additional well details:
You may use the back of this page to provide additional well site details or well
construction details. You may also attach additional pages if necessary.
SUBMITTAL INSTUCTIONS
24a. For All Wells: Submit this form within 30 days of completion of well
construction to the following:
Division of Water Quality, Information Processing Unit,
1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Iniection Wells: In addition to sending the form to the address in 24a
above, also submit a copy of this form within 30 days of completion of well
construction to the following:
Division of Water Quality, Underground Injection Control Program,
FOR WATER SUPPLY WELLS ONLY: 1636 Mail Service Center, Raleigh, NC 27699-1636
13a. Yield (gpm) Method of test: 24c. For Water Supply & Iniection Wells: In addition to sending the form to
the address(es) above, also submit one copy of this form within 30 days of
13b. Disinfection type: Amount: completion of well construction to the county health department of the county
where constructed.
Form GW-1 North Carolina Department of Environment and Natural Resources - Division of Water Quality Revised Jan. 2013

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
WL' LL l,VINL5 I KU%-I 1Vir KLL l VKL
This form can be used for single or multiple wells
For Internal Use ONLY:
1. Well Contractor Information:
JEREMY RINGLER
Well Contractor Name
A - 4422
NC Well Contractor Certification Number
GEOLOGIC EXPLORATION, INC
Company Name
2. Well Construction Permit #:
List all applicable well construction permits (i.e. County, State, Variance, etc)
3. Well Use (check well use):
Water Supply Well:
❑Agricultural
❑Geothermal (Heating/Cooling Supply)
❑ hmdustrial/Commercial
❑ Irrigation
Non -Water Supply Well:
El Aquifer Recharge
El Aquifer Storage and Recovery
❑Aquifer Test
❑Experimental Technology
❑Geothermal (Closed Loop)
❑Geothermal (Heating/Cooling
❑Municipal/Public
El Residential Water Supply (single)
❑Residential Water Supply (shared)
El Groundwater Remediation
❑ Salinity Barrier
❑ Stormwater Drainage
❑Subsidence Control
❑Tracer
❑Other (explain under #21 F
4. Date Well(s) Completed: 12/05/19 Well ID# MW-6B
5a. Well Location:
PERSON COUNTY LANDFILL
Facility/Owner Name Facility ID# (if applicable)
542 CEDAR GROVE CHURCH ROAD ROXBORO 27574
Physical Address, City, and Zip
PERSON
County Parcel Identification No. (PIN)
5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees:
(if well field, one lat/long is sufficient)
360 23' 21.86" N 780 55' 26.07" W
6. Is (are) the well(s): ❑] Permanent or ❑Temporary
7. Is this a repair to an existing well: ❑Yes or ONo
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8. Number of wells constructed:
For multiple injection or non -water supply wells ONLY with the same construction, you can
submit one form.
9. Total well depth below land surface: 9.0 (ft.)
For multiple wells list all depths if different (example- 3@200' and 2@100')
10. Static water level below top of casing: 4.0 (ft.)
If water level is above casing, use "+"
11. Borehole diameter: 8.0 (in.)
12. Well construction method: AUGER
(i.e. auger, rotary, cable, direct push, etc.)
14. WATER ZONES
FROM
TO
DESCRIPTION
rt.
rt.
ft.
ft.
15. OUTER CASING for multi -cased wells OR LINER if applicable
FROM
TO
DIAMETER
THICKNESSr
MATERIAL
fL
10.0 ft-6.0
i"
SCH 40
PVC
16. INNER CASING OR TUBING eother at closed -loop)
FROM
TO
DIAMETER
THICKNESS
MATERIAL
0.0 tf
4.0 tt•
2.0 "'
SCH 40
PVC
rt
rL
in.
17. SCREEN
FROM
TO
DIAMETER
SLOT SIZE
THICKNESS
MATERIAL
4.0 ft'
9.0 ft'
2.0 in.
.010
SCH 40
PVC*
ft.
ft,
in.
18. GROUT
FROM
TO
MATERIAL
EMPLACEMENT METHOD & AMOUNT
0.0 IL
3.0 ft-
PORTLANDBENTONITE
SLURRY
ft•
10.0 ft-
PORTLANDBENTONITE
SLURRY
rt.
rt.
19. SAND/GRAVEL PACK (if applicable)
FROM
TO
MATERIAL
EMPLACEMENT METHOD
3.5 tt•
9.0 tt•
20-40
FINE SILICA SAND
rt.
rt.
20. DRILLING LOG attach additional sheets if necessary)
FROM
TO
DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
0.0 tt•
5.0 tt•
BROWN SILT
5.0 tt
9.0
SILTY PWR
10.0 tt•
17.0 tt•
ROCK
rt.
ft.
rt.
rt.
ft.
fit.
rt.
fr.
21. REMARKS
BENTONITE SEAL FROM 3.0 TO 3.5 FEET
*PRE -PACK SCREEN*
22. Certification:
12/18/19
Signature of Certified Well Contractor Date
By signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a
copy of this record has been provided to the well owner.
23. Site diagram or additional well details:
You may use the back of this page to provide additional well site details or well
construction details. You may also attach additional pages if necessary.
SUBMITTAL INSTUCTIONS
24a. For All Wells: Submit this form within 30 days of completion of well
construction to the following:
Division of Water Quality, Information Processing Unit,
1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Iniection Wells: In addition to sending the form to the address in 24a
above, also submit a copy of this form within 30 days of completion of well
construction to the following:
Division of Water Quality, Underground Injection Control Program,
FOR WATER SUPPLY WELLS ONLY: 1636 Mail Service Center, Raleigh, NC 27699-1636
13a. Yield (gpm) Method of test: 24c. For Water Supply & Iniection Wells: In addition to sending the form to
the address(es) above, also submit one copy of this form within 30 days of
13b. Disinfection type: Amount: completion of well construction to the county health department of the county
where constructed.
Form GW-1 North Carolina Department of Environment and Natural Resources - Division of Water Quality Revised Jan. 2013

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Appendix
Laboratory Analytical Reports
April 2024 Groundwater Monitoring Report
Person County Landfill
NC Solid Waste Permit No. 73-01

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
This page intentionally left blank.

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
(2)
Waypoint Drinking Water ID: 37715
Wastewater ID: 10
ANALYTICAL
114 OAKMONT DRIVE PHONE [phone]
GREENVILLE, NC 27858 FAX [phone]
ID#: 6034
PERSON COUNTY
LANDFILL
MR. RAY FOUSHEE
SOLID WASTE COORDINATOR
DATE COLLECTED:
04/23/24
304 S. MORGAN
ST. ROOM
222
DATE REPORTED
05/17/24
ROXBORO, NC 27573
REVIEWED
BY:
MW-1
MW-2
MW-3
MW-4
MW-5
Analysis
Method
Date Analyst
Code
PARAMETERS
MDL
MRL
5.8
6.8
5.9
6.4
6.1
04/23/24 NNK
4500HB-11
PH (field measurement), Unite
0.28 J
0.32 J
5.0
0.36 J
04/29/24 NAB
EPA200.8
Arsenic, ug/1
0.13
5.0
--- U
42.2
7.8 J
72.2
54.8
04/29/24 NAB
EPA200.8
Barium, ug/l
0.14
10.0
35.9
U
--- U
--- U
04/29/24 NAB
EPA200.B
Cadmium, ug/1
0.19
1.0
0.21 J
--- U
---
11
--- U
04/29/24 NAB
EPA200.8
Total Chromium, ug/1
0.19
5.0
0.44 J
--- U
--- U
U
1.1 J
--- U
04/29/24 NAB
EPA200.8
Lead, ug/1
0.09
5.0
1.1 J
0.15 J
---
U
--- U
04/25/24 MTM
245.1 R3-94
Mercury, ug/l
0.08
0.20
--- U
--- U
--- U
U
---
0.52 J
--- U
04/29/24 NAB
EPA200.8
Selenium, ug/l
0.43
10.0
--- U
--- U
---
U
--- U
--- U
04/29/24 NAB
EPA200.8
Silver, ug/1
0.14
5.0
--- U
92
--- U
1270
---
360
1397
701
04/23/24 NNK
2510E-11
Conductivity (at 25c), uMhos/cm
1.0
1.0
16
14
04/23/24 NNK
2550B-10
Temperature, °C
16
40.32
15
2.20
15
4.90
10.36
5.85
04/23/24 NNK
Static Water Level, feet
61.23
20.6E
22.37
17.93
11.55
04/23/24 NNK
Well Depth, feet
1.0
18.0
5.10
4.51
65.0
7.80
04/23/24 NNK
2130E-11
Turbidity (Field), NTU
1.0
J = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits.

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Waypoint,
ANALYTICAL
114 OAKMONT DRIVE
GREENVILLE, NC 27858
PERSON COUNTY LANDFILL
MR. RAY FOUSHEE
SOLID WASTE COORDINATOR
304 S. MORGAN ST. ROOM 222
ROXBORO, NC 27573
MW-6
MW-7
MW-7D
PARAMETERS
MDL
MRL
PH (field measurement), Unite
5.6
6.2
7.0
Arsenic, ug/l
0.13
5.0
0.71J
0.20 J
0.32 J
Barium, ug/1
0.14
10.0
19.2
30.4
6.9 J
Cadmium, ug/1
0.19
1.0
--- U
--- U
---
Total Chromium, ug/l
0.19
5.0
1.6J
--- U
0.64
Lead, ug/1
0.09
5.0
1.3 J
--- U
---
Mercury, ug/l
0.08
0.20
--- U
--- U
---
Selenium, ug/l
0.43
10.0
--- U
--- U
---
Silver, ug/l
0.14
5.0
--- U
0.15 J
---
Conductivity (at 25c), uMhos/cm
1.0
1.0
69
204
262
Temperature, °C
14
14
14
Static Water Level, feet
6.06
6.71
7.62
Well Depth, feet
12.95
12.44
21.32
Turbidity (Field), NTU
1.0
1.0
24.5
14.7
1.98
Drinking Water ID: 37715
Wastewater ID: 10
PHONE [phone]
FAX [phone]
ID#: 6034
DATE COLLECTED: 04/23/24
DATE REPORTED : 05/17/24
REVIEWED BY:
SW-1
U
J
U
U
U
U
SW-2
Analysis
Method
Date Analyst
Code
6.9
6.7
04/23/24
NNK
4500HB-11
2.7 J
1.7 J
04/29/24
NAB
EPA200.8
128
95.8
04/29/24
NAB
EPA200.8
--- U
--- U
04/29/24
NAB
EPA200.8
15
3.1 J
04/29/24
NAB
EPA200.8
19
2.9J
04/29/24
NAB
EPA200.8
0.04 J
--- U
04/25/24
MTM
245.1 R3-94
0.71 J
--- U
04/29/24
NAB
BPA200.8
--- U
--- U
04/29/24
NAB
EPA200.8
62
216
04/23/24
NNK
251OB-11
19
19
04/23/24
NNK
2550E-10
04/23/24
NNK
04/23/24
NNK
04/23/24
NNK
213OB-11
J = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits.

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
(D
Waypoint.,
ANALYTICAL
114 OAKMONT DRIVE
GREENVILLE, NC 27858
PERSON COUNTY LANDFILL
MR. RAY FOUSHEE
SOLID WASTE COORDINATOR
304 S. MORGAN ST. ROOM 222
ROXBORO, NC 27573
Drinking Water ID: 37715
Wastewater ID: 10
PHONE [phone]
FAX [phone]
ID#: 6034
DATE COLLECTED: 04/23/24
DATE REPORTED : 05/17/24
REVIEWED BY:
SW-3
Trip
Analysis
Method
PARAMETERS
MDL
MRL
Blank
Date Analyst
Code
PH (field measurement), Unite
6.6
04/23/24
NNK
4500HB-11
Arsenic, ug/l
0.13
5.0
1.2 J
04/29/24
NAB
EPA200.8
Barium, ug/l
0.14
10.0
48.8
04/29/24
NAB
BPA200.8
Cadmium, ug/l
0.19
1.0
--- U
04/29/24
NAB
EPA200.8
Total Chromium, ug/l
0.19
5.0
0.40 J
04/29/24
NAB
EPA200.8
Lead, ug/l
0.09
5.0
0.40 J
04/29/24
NAB
EPA200.8
Mercury, ug/l
0.08
0.20
--- U
04/25/24
MTM
245.1 R3-94
Selenium, ug/l
0.43
10.0
--- U
04/29/24
NAB
EPA200.8
Silver, ug/1
0.14
5.0
--- U
04/29/24
NAB
EPA200.8
Conductivity (at 25c), uMhos/cm
1.0
1.0
158
04/23/24
NNK
251OB-11
19
04/23/24
NNK
2550E-10
Temperature, °C
J = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits.

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
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PARAMETERS/TESTS =
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Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
May 08, 2024
Ann Baynor
Waypoint Analytical
114 Oakmont Dr.
Greenville, NC 27858
RE: Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
Dear Ann Baynor:
Enclosed are the analytical results for sample(s) received by the laboratory on April 30, 2024. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Stephanie Knott
[e-mail]
704-977-0981
Project Manager
Enclosures
cc: Allen Clark
R. Litten
Halle Oliveira, Waypoint Analytical
Katie Vanderburg
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
VirginiaNELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92727878001
MW-1
Water
04/23/2414:08
04/30/24 10:25
92727878002
MW-2
Water
04/23/24 13:35
04/30/24 10:25
92727878003
MW-3
Water
04/23/2411:22
04/30/24 10:25
92727878004
MW-4
Water
04/23/2413:43
04/30/24 10:25
92727878005
MW-5
Water
04/23/2411:55
04/30/24 10:25
92727878006
MW-6
Water
04/23/24 12:29
04/30/24 10:25
92727878007
MW-7
Water
04/23/24 10:38
04/30/24 10:25
92727878008
MW-7D
Water
04/23/2410:20
04/30/24 10:25
92727878009
SW-1
Water
04/23/2414:20
04/30/24 10:25
92727878010
SW-2
Water
04/23/2411:20
04/30/24 10:25
92727878011
SW-3
Water
04/23/24 10:30
04/30/24 10:25
92727878012
TRIP BLANK
Water
04/23/24 00:00
04/30/24 10:25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4 Pace Analytical Services, LLC
�aceo 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
PERSON COUNTY LANDFILL
92727878
Analytes
Lab lD
Sample ID
Method
Analysts
Reported
Laboratory
92727878001
MW-1
EPA 8260D
LMB
68
PASI-C
92727878002
MW-2
EPA 8260D
LMB
68
PASI-C
92727878003
MW-3
EPA 8260D
LMB
68
PASI-C
92727878004
MW-4
EPA 8260D
LMB
68
PASI-C
92727878005
MW-5
EPA 8260D
LMB
68
PASI-C
92727878006
MW-6
EPA 8260D
LMB
68
PASI-C
92727878007
MW-7
EPA 8260D
LMB
68
PASI-C
92727878008
MW-7D
EPA 8260D
LMB
68
PASI-C
92727878009
SW-1
EPA 8260D
LMB
68
PASI-C
92727878010
SW-2
EPA 8260D
LMB
68
PASI-C
92727878011
SW-3
EPA 8260D
LMB
68
PASI-C
92727878012
TRIP BLANK
EPA 8260D
LMB
68
PASI-C
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
Sample: MW-1 Lab ID: 92727878001 Collected: 04/23/24 14:08 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
1,4-Dioxane (p-Dioxane)
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
p-Isopropyltoluene
Methylene Chloride
Date: 05/08/2024 08:03 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
5.1
1
04/30/24 22:23
67-64-1
ND
ug/L
10.0
1.8
1
04/30/24 22:23
107-13-1
ND
ug/L
1.0
0.34
1
04/30/24 22:23
71-43-2
ND
ug/L
1.0
0.29
1
04/30/24 22:23
108-86-1
ND
ug/L
1.0
0.47
1
04/30/24 22:23
74-97-5
ND
ug/L
1.0
0.31
1
04/30/24 22:23
75-27-4
ND
ug/L
1.0
0.34
1
04/30/24 22:23
75-25-2
ND
ug/L
2.0
1.7
1
04/30/24 22:23
74-83-9
ND
ug/L
5.0
4.0
1
04/30/24 22:23
78-93-3
ND
ug/L
2.0
0.36
1
04/30/24 22:23
75-15-0
ND
ug/L
1.0
0.33
1
04/30/24 22:23
56-23-5
ND
ug/L
1.0
0.28
1
04/30/24 22:23
108-90-7
ND
ug/L
1.0
0.65
1
04/30/24 22:23
75-00-3
ND
ug/L
1.0
0.43
1
04/30/24 22:23
67-66-3
ND
ug/L
1.0
0.54
1
04/30/24 22:23
74-87-3
ND
ug/L
1.0
0.32
1
04/30/24 22:23
95-49-8
ND
ug/L
1.0
0.32
1
04/30/24 22:23
106-43-4
ND
ug/L
2.0
0.34
1
04/30/24 22:23
96-12-8
ND
ug/L
1.0
0.36
1
04/30/24 22:23
124-48-1
ND
ug/L
1.0
0.27
1
04/30/24 22:23
106-93-4
ND
ug/L
1.0
0.39
1
04/30/24 22:23
74-95-3
ND
ug/L
1.0
0.34
1
04/30/24 22:23
95-50-1
ND
ug/L
1.0
0.34
1
04/30/24 22:23
541-73-1
ND
ug/L
1.0
0.33
1
04/30/24 22:23
106-46-7
ND
ug/L
1.0
0.56
1
04/30/24 22:23
110-57-6
ND
ug/L
1.0
0.35
1
04/30/24 22:23
75-71-8
ND
ug/L
1.0
0.37
1
04/30/24 22:23
75-34-3
ND
ug/L
1.0
0.32
1
04/30/24 22:23
107-06-2
ND
ug/L
1.0
0.35
1
04/30/24 22:23
75-35-4
ND
ug/L
1.0
0.38
1
04/30/24 22:23
156-59-2
ND
ug/L
1.0
0.40
1
04/30/24 22:23
156-60-5
ND
ug/L
1.0
0.36
1
04/30/24 22:23
78-87-5
ND
ug/L
1.0
0.28
1
04/30/24 22:23
142-28-9
ND
ug/L
1.0
0.39
1
04/30/24 22:23
594-20-7
ND
ug/L
1.0
0.43
1
04/30/24 22:23
563-58-6
ND
ug/L
1.0
0.36
1
04/30/24 22:23
10061-01-5
ND
ug/L
1.0
0.36
1
04/30/24 22:23
10061-02-6
ND
ug/L
1.0
0.31
1
04/30/24 22:23
108-20-3
ND
ug/L
150
38.7
1
04/30/24 22:23
123-91-1
ND
ug/L
1.0
0.30
1
04/30/24 22:23
100-41-4
ND
ug/L
2.0
1.5
1
04/30/24 22:23
87-68-3
ND
ug/L
5.0
0.48
1
04/30/24 22:23
591-78-6
ND
ug/L
20.0
9.7
1
04/30/24 22:23
74-88-4
ND
ug/L
1.0
0.41
1
04/30/24 22:23
99-87-6
ND
ug/L
5.0
2.0
1
04/30/24 22:23
75-09-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
M1
M1
I •il
M1,v1
M1,v1
M1
Page 5 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
Sample: MW-1 Lab ID: 92727878001 Collected: 04/23/24 14:08 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
5.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
1.0
95
%
70-130
102
%
70-130
102
%
70-130
2.7
1
04/30/24 22:23
108-10-1
0.42
1
04/30/24 22:23
1634-04-4
0.64
1
04/30/24 22:23
91-20-3
0.29
1
04/30/24 22:23
100-42-5
0.31
1
04/30/24 22:23
630-20-6
0.22
1
04/30/24 22:23
79-34-5
0.29
1
04/30/24 22:23
127-18-4
0.24
1
04/30/24 22:23
108-88-3
0.81
1
04/30/24 22:23
87-61-6
0.64
1
04/30/24 22:23
120-82-1
0.33
1
04/30/24 22:23
71-55-6
0.32
1
04/30/24 22:23
79-00-5
0.38
1
04/30/24 22:23
79-01-6
0.30
1
04/30/24 22:23
75-69-4 M 1
0.26
1
04/30/24 22:23
96-18-4
1.3
1
04/30/24 22:23
108-05-4
0.39
1
04/30/24 22:23
75-01-4
0.34
1
04/30/24 22:23
1330-20-7
0.71
1
04/30/24 22:23
179601-23-1
0.34
1
04/30/24 22:23
95-47-6
1 04/30/24 22:23 460-00-4
1 04/30/24 22:23 17060-07-0
1 04/30/24 22:23 2037-26-5
Sample: MW-2 Lab ID: 92727878002 Collected: 04/23/24 13:35 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Date: 05/08/2024 08:03 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
ND
ug/L
10.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
1.0
3.9
ug/L
1.0
5.1
1
04/30/24 22:42
67-64-1
1.8
1
04/30/24 22:42
107-13-1
0.34
1
04/30/24 22:42
71-43-2
0.29
1
04/30/24 22:42
108-86-1
0.47
1
04/30/24 22:42
74-97-5
0.31
1
04/30/24 22:42
75-27-4
0.34
1
04/30/24 22:42
75-25-2
1.7
1
04/30/24 22:42
74-83-9
4.0
1
04/30/24 22:42
78-93-3
0.36
1
04/30/24 22:42
75-15-0
0.33
1
04/30/24 22:42
56-23-5
0.28
1
04/30/24 22:42
108-90-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
Page 6 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
Sample: MW-2 Lab ID: 92727878002 Collected: 04/23/24 13:35 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
1,4-Dioxane (p-Dioxane)
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Date: 05/08/2024 08:03 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.65
1
04/30/24 22:42
75-00-3
ND
ug/L
1.0
0.43
1
04/30/24 22:42
67-66-3
ND
ug/L
1.0
0.54
1
04/30/24 22:42
74-87-3
ND
ug/L
1.0
0.32
1
04/30/24 22:42
95-49-8
ND
ug/L
1.0
0.32
1
04/30/24 22:42
106-43-4
ND
ug/L
2.0
0.34
1
04/30/24 22:42
96-12-8
ND
ug/L
1.0
0.36
1
04/30/24 22:42
124-48-1
ND
ug/L
1.0
0.27
1
04/30/24 22:42
106-93-4
ND
ug/L
1.0
0.39
1
04/30/24 22:42
74-95-3
ND
ug/L
1.0
0.34
1
04/30/24 22:42
95-50-1
ND
ug/L
1.0
0.34
1
04/30/24 22:42
541-73-1
2.1
ug/L
1.0
0.33
1
04/30/24 22:42
106-46-7
ND
ug/L
1.0
0.56
1
04/30/24 22:42
110-57-6
ND
ug/L
1.0
0.35
1
04/30/24 22:42
75-71-8
1.1
ug/L
1.0
0.37
1
04/30/24 22:42
75-34-3
ND
ug/L
1.0
0.32
1
04/30/24 22:42
107-06-2
ND
ug/L
1.0
0.35
1
04/30/24 22:42
75-35-4
5.6
ug/L
1.0
0.38
1
04/30/24 22:42
156-59-2
ND
ug/L
1.0
0.40
1
04/30/24 22:42
156-60-5
2.8
ug/L
1.0
0.36
1
04/30/24 22:42
78-87-5
ND
ug/L
1.0
0.28
1
04/30/24 22:42
142-28-9
ND
ug/L
1.0
0.39
1
04/30/24 22:42
594-20-7
ND
ug/L
1.0
0.43
1
04/30/24 22:42
563-58-6
ND
ug/L
1.0
0.36
1
04/30/24 22:42
10061-01-5
ND
ug/L
1.0
0.36
1
04/30/24 22:42
10061-02-6
ND
ug/L
1.0
0.31
1
04/30/24 22:42
108-20-3
ND
ug/L
150
38.7
1
04/30/24 22:42
123-91-1
ND
ug/L
1.0
0.30
1
04/30/24 22:42
100-41-4
ND
ug/L
2.0
1.5
1
04/30/24 22:42
87-68-3
ND
ug/L
5.0
0.48
1
04/30/24 22:42
591-78-6
ND
ug/L
20.0
9.7
1
04/30/24 22:42
74-88-4
ND
ug/L
1.0
0.41
1
04/30/24 22:42
99-87-6
ND
ug/L
5.0
2.0
1
04/30/24 22:42
75-09-2
ND
ug/L
5.0
2.7
1
04/30/24 22:42
108-10-1
ND
ug/L
1.0
0.42
1
04/30/24 22:42
1634-04-4
ND
ug/L
1.0
0.64
1
04/30/24 22:42
91-20-3
ND
ug/L
1.0
0.29
1
04/30/24 22:42
100-42-5
ND
ug/L
1.0
0.31
1
04/30/24 22:42
630-20-6
ND
ug/L
1.0
0.22
1
04/30/24 22:42
79-34-5
1.5
ug/L
1.0
0.29
1
04/30/24 22:42
127-18-4
ND
ug/L
1.0
0.24
1
04/30/24 22:42
108-88-3
ND
ug/L
1.0
0.81
1
04/30/24 22:42
87-61-6
ND
ug/L
1.0
0.64
1
04/30/24 22:42
120-82-1
ND
ug/L
1.0
0.33
1
04/30/24 22:42
71-55-6
ND
ug/L
1.0
0.32
1
04/30/24 22:42
79-00-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v1
v1
Page 7 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
Sample: MW-2 Lab ID: 92727878002 Collected: 04/23/24 13:35 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
0.53.1
ug/L
1.0
0.38
1
04/30/24 22:42
79-01-6
ND
ug/L
1.0
0.30
1
04/30/24 22:42
75-69-4
ND
ug/L
1.0
0.26
1
04/30/24 22:42
96-18-4
ND
ug/L
2.0
1.3
1
04/30/24 22:42
108-05-4
0.68J
ug/L
1.0
0.39
1
04/30/24 22:42
75-01-4
ND
ug/L
1.0
0.34
1
04/30/24 22:42
1330-20-7
ND
ug/L
2.0
0.71
1
04/30/24 22:42
179601-23-1
ND
ug/L
1.0
0.34
1
04/30/24 22:42
95-47-6
98
%
70-130
1
04/30/24 22:42
460-00-4
107
%
70-130
1
04/30/24 22:42
17060-07-0
100
%
70-130
1
04/30/24 22:42
2037-26-5
Sample: MW-3 Lab ID: 92727878003 Collected: 04/23/24 11:22 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Date: 05/08/2024 08:03 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
04/30/24 23:01
67-64-1
ND
ug/L
10.0
1.8
1
04/30/24 23:01
107-13-1
7.7
ug/L
1.0
0.34
1
04/30/24 23:01
71-43-2
ND
ug/L
1.0
0.29
1
04/30/24 23:01
108-86-1
ND
ug/L
1.0
0.47
1
04/30/24 23:01
74-97-5
ND
ug/L
1.0
0.31
1
04/30/24 23:01
75-27-4
ND
ug/L
1.0
0.34
1
04/30/24 23:01
75-25-2
ND
ug/L
2.0
1.7
1
04/30/24 23:01
74-83-9 v2
ND
ug/L
5.0
4.0
1
04/30/24 23:01
78-93-3
ND
ug/L
2.0
0.36
1
04/30/24 23:01
75-15-0
ND
ug/L
1.0
0.33
1
04/30/24 23:01
56-23-5
1.0
ug/L
1.0
0.28
1
04/30/24 23:01
108-90-7
4.0
ug/L
1.0
0.65
1
04/30/24 23:01
75-00-3
ND
ug/L
1.0
0.43
1
04/30/24 23:01
67-66-3
ND
ug/L
1.0
0.54
1
04/30/24 23:01
74-87-3
ND
ug/L
1.0
0.32
1
04/30/24 23:01
95-49-8
ND
ug/L
1.0
0.32
1
04/30/24 23:01
106-43-4
ND
ug/L
2.0
0.34
1
04/30/24 23:01
96-12-8
ND
ug/L
1.0
0.36
1
04/30/24 23:01
124-48-1
ND
ug/L
1.0
0.27
1
04/30/24 23:01
106-93-4
ND
ug/L
1.0
0.39
1
04/30/24 23:01
74-95-3
ND
ug/L
1.0
0.34
1
04/30/24 23:01
95-50-1
ND
ug/L
1.0
0.34
1
04/30/24 23:01
541-73-1
2.9
ug/L
1.0
0.33
1
04/30/24 23:01
106-46-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 8 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
Sample: MW-3 Lab ID: 92727878003 Collected: 04/23/24 11:22 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
1,4-Dioxane (p-Dioxane)
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 05/08/2024 08:03 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.56
1
04/30/24 23:01
110-57-6
ND
ug/L
1.0
0.35
1
04/30/24 23:01
75-71-8 v1
42.0
ug/L
1.0
0.37
1
04/30/24 23:01
75-34-3
ND
ug/L
1.0
0.32
1
04/30/24 23:01
107-06-2
0.83J
ug/L
1.0
0.35
1
04/30/24 23:01
75-35-4
170
ug/L
1.0
0.38
1
04/30/24 23:01
156-59-2
1.8
ug/L
1.0
0.40
1
04/30/24 23:01
156-60-5
2.7
ug/L
1.0
0.36
1
04/30/24 23:01
78-87-5
ND
ug/L
1.0
0.28
1
04/30/24 23:01
142-28-9
ND
ug/L
1.0
0.39
1
04/30/24 23:01
594-20-7 v1
ND
ug/L
1.0
0.43
1
04/30/24 23:01
563-58-6
ND
ug/L
1.0
0.36
1
04/30/24 23:01
10061-01-5
ND
ug/L
1.0
0.36
1
04/30/24 23:01
10061-02-6
0.43J
ug/L
1.0
0.31
1
04/30/24 23:01
108-20-3
ND
ug/L
150
38.7
1
04/30/24 23:01
123-91-1
ND
ug/L
1.0
0.30
1
04/30/24 23:01
100-41-4
ND
ug/L
2.0
1.5
1
04/30/24 23:01
87-68-3
ND
ug/L
5.0
0.48
1
04/30/24 23:01
591-78-6
ND
ug/L
20.0
9.7
1
04/30/24 23:01
74-88-4
ND
ug/L
1.0
0.41
1
04/30/24 23:01
99-87-6
ND
ug/L
5.0
2.0
1
04/30/24 23:01
75-09-2
ND
ug/L
5.0
2.7
1
04/30/24 23:01
108-10-1
1.2
ug/L
1.0
0.42
1
04/30/24 23:01
1634-04-4
ND
ug/L
1.0
0.64
1
04/30/24 23:01
91-20-3
ND
ug/L
1.0
0.29
1
04/30/24 23:01
100-42-5
ND
ug/L
1.0
0.31
1
04/30/24 23:01
630-20-6
ND
ug/L
1.0
0.22
1
04/30/24 23:01
79-34-5
37.6
ug/L
1.0
0.29
1
04/30/24 23:01
127-18-4
ND
ug/L
1.0
0.24
1
04/30/24 23:01
108-88-3
ND
ug/L
1.0
0.81
1
04/30/24 23:01
87-61-6
0.67J
ug/L
1.0
0.64
1
04/30/24 23:01
120-82-1
ND
ug/L
1.0
0.33
1
04/30/24 23:01
71-55-6
ND
ug/L
1.0
0.32
1
04/30/24 23:01
79-00-5
34.3
ug/L
1.0
0.38
1
04/30/24 23:01
79-01-6
ND
ug/L
1.0
0.30
1
04/30/24 23:01
75-69-4
ND
ug/L
1.0
0.26
1
04/30/24 23:01
96-18-4
ND
ug/L
2.0
1.3
1
04/30/24 23:01
108-05-4
45.1
ug/L
1.0
0.39
1
04/30/24 23:01
75-01-4
ND
ug/L
1.0
0.34
1
04/30/24 23:01
1330-20-7
ND
ug/L
2.0
0.71
1
04/30/24 23:01
179601-23-1
ND
ug/L
1.0
0.34
1
04/30/24 23:01
95-47-6
95
%
70-130
1
04/30/24 23:01
460-00-4
105
%
70-130
1
04/30/24 23:01
17060-07-0
100
%
70-130
1
04/30/24 23:01
2037-26-5
REPORT
OF LABORATORY ANALYSIS
This report shall not be reproduced,
except in full,
without the written
consent of Pace
Analytical Services, LLC.
Page 9 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
Sample: MW-4 Lab ID: 92727878004 Collected: 04/23/24 13:43 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
1,4-Dioxane (p-Dioxane)
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
p-Isopropyltoluene
Methylene Chloride
Date: 05/08/2024 08:03 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
5.1
1
04/30/24 23:19
67-64-1
ND
ug/L
10.0
1.8
1
04/30/24 23:19
107-13-1
ND
ug/L
1.0
0.34
1
04/30/24 23:19
71-43-2
ND
ug/L
1.0
0.29
1
04/30/24 23:19
108-86-1
ND
ug/L
1.0
0.47
1
04/30/24 23:19
74-97-5
ND
ug/L
1.0
0.31
1
04/30/24 23:19
75-27-4
ND
ug/L
1.0
0.34
1
04/30/24 23:19
75-25-2
ND
ug/L
2.0
1.7
1
04/30/24 23:19
74-83-9
ND
ug/L
5.0
4.0
1
04/30/24 23:19
78-93-3
ND
ug/L
2.0
0.36
1
04/30/24 23:19
75-15-0
ND
ug/L
1.0
0.33
1
04/30/24 23:19
56-23-5
ND
ug/L
1.0
0.28
1
04/30/24 23:19
108-90-7
ND
ug/L
1.0
0.65
1
04/30/24 23:19
75-00-3
ND
ug/L
1.0
0.43
1
04/30/24 23:19
67-66-3
ND
ug/L
1.0
0.54
1
04/30/24 23:19
74-87-3
ND
ug/L
1.0
0.32
1
04/30/24 23:19
95-49-8
ND
ug/L
1.0
0.32
1
04/30/24 23:19
106-43-4
ND
ug/L
2.0
0.34
1
04/30/24 23:19
96-12-8
ND
ug/L
1.0
0.36
1
04/30/24 23:19
124-48-1
ND
ug/L
1.0
0.27
1
04/30/24 23:19
106-93-4
ND
ug/L
1.0
0.39
1
04/30/24 23:19
74-95-3
ND
ug/L
1.0
0.34
1
04/30/24 23:19
95-50-1
ND
ug/L
1.0
0.34
1
04/30/24 23:19
541-73-1
0.34.1
ug/L
1.0
0.33
1
04/30/24 23:19
106-46-7
ND
ug/L
1.0
0.56
1
04/30/24 23:19
110-57-6
ND
ug/L
1.0
0.35
1
04/30/24 23:19
75-71-8
ND
ug/L
1.0
0.37
1
04/30/24 23:19
75-34-3
ND
ug/L
1.0
0.32
1
04/30/24 23:19
107-06-2
ND
ug/L
1.0
0.35
1
04/30/24 23:19
75-35-4
ND
ug/L
1.0
0.38
1
04/30/24 23:19
156-59-2
ND
ug/L
1.0
0.40
1
04/30/24 23:19
156-60-5
ND
ug/L
1.0
0.36
1
04/30/24 23:19
78-87-5
ND
ug/L
1.0
0.28
1
04/30/24 23:19
142-28-9
ND
ug/L
1.0
0.39
1
04/30/24 23:19
594-20-7
ND
ug/L
1.0
0.43
1
04/30/24 23:19
563-58-6
ND
ug/L
1.0
0.36
1
04/30/24 23:19
10061-01-5
ND
ug/L
1.0
0.36
1
04/30/24 23:19
10061-02-6
ND
ug/L
1.0
0.31
1
04/30/24 23:19
108-20-3
ND
ug/L
150
38.7
1
04/30/24 23:19
123-91-1
ND
ug/L
1.0
0.30
1
04/30/24 23:19
100-41-4
ND
ug/L
2.0
1.5
1
04/30/24 23:19
87-68-3
ND
ug/L
5.0
0.48
1
04/30/24 23:19
591-78-6
ND
ug/L
20.0
9.7
1
04/30/24 23:19
74-88-4
ND
ug/L
1.0
0.41
1
04/30/24 23:19
99-87-6
ND
ug/L
5.0
2.0
1
04/30/24 23:19
75-09-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v1
v1
Page 10 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
Sample: MW-4 Lab ID: 92727878004 Collected: 04/23/24 13:43 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
5.0
2.7
1
04/30/24 23:19
108-10-1
ND
ug/L
1.0
0.42
1
04/30/24 23:19
1634-04-4
ND
ug/L
1.0
0.64
1
04/30/24 23:19
91-20-3
ND
ug/L
1.0
0.29
1
04/30/24 23:19
100-42-5
ND
ug/L
1.0
0.31
1
04/30/24 23:19
630-20-6
ND
ug/L
1.0
0.22
1
04/30/24 23:19
79-34-5
ND
ug/L
1.0
0.29
1
04/30/24 23:19
127-18-4
ND
ug/L
1.0
0.24
1
04/30/24 23:19
108-88-3
ND
ug/L
1.0
0.81
1
04/30/24 23:19
87-61-6
ND
ug/L
1.0
0.64
1
04/30/24 23:19
120-82-1
ND
ug/L
1.0
0.33
1
04/30/24 23:19
71-55-6
ND
ug/L
1.0
0.32
1
04/30/24 23:19
79-00-5
ND
ug/L
1.0
0.38
1
04/30/24 23:19
79-01-6
ND
ug/L
1.0
0.30
1
04/30/24 23:19
75-69-4
ND
ug/L
1.0
0.26
1
04/30/24 23:19
96-18-4
ND
ug/L
2.0
1.3
1
04/30/24 23:19
108-05-4
ND
ug/L
1.0
0.39
1
04/30/24 23:19
75-01-4
ND
ug/L
1.0
0.34
1
04/30/24 23:19
1330-20-7
ND
ug/L
2.0
0.71
1
04/30/24 23:19
179601-23-1
ND
ug/L
1.0
0.34
1
04/30/24 23:19
95-47-6
98
%
70-130
1
04/30/24 23:19
460-00-4
106
%
70-130
1
04/30/24 23:19
17060-07-0
100
%
70-130
1
04/30/24 23:19
2037-26-5
Sample: MW-5 Lab ID: 92727878005 Collected: 04/23/24 11:55 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Date: 05/08/2024 08:03 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
ND
ug/L
10.0
1.9
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
1.0
5.0
ug/L
1.0
5.1
1
04/30/24 23:38
67-64-1
1.8
1
04/30/24 23:38
107-13-1
0.34
1
04/30/24 23:38
71-43-2
0.29
1
04/30/24 23:38
108-86-1
0.47
1
04/30/24 23:38
74-97-5
0.31
1
04/30/24 23:38
75-27-4
0.34
1
04/30/24 23:38
75-25-2
1.7
1
04/30/24 23:38
74-83-9
4.0
1
04/30/24 23:38
78-93-3
0.36
1
04/30/24 23:38
75-15-0
0.33
1
04/30/24 23:38
56-23-5
0.28
1
04/30/24 23:38
108-90-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
Page 11 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
Sample: MW-5 Lab ID: 92727878005 Collected: 04/23/24 11:55 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
1,4-Dioxane (p-Dioxane)
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Date: 05/08/2024 08:03 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
1.6
ug/L
1.0
0.65
1
04/30/24 23:38
75-00-3
ND
ug/L
1.0
0.43
1
04/30/24 23:38
67-66-3
ND
ug/L
1.0
0.54
1
04/30/24 23:38
74-87-3
ND
ug/L
1.0
0.32
1
04/30/24 23:38
95-49-8
ND
ug/L
1.0
0.32
1
04/30/24 23:38
106-43-4
ND
ug/L
2.0
0.34
1
04/30/24 23:38
96-12-8
ND
ug/L
1.0
0.36
1
04/30/24 23:38
124-48-1
ND
ug/L
1.0
0.27
1
04/30/24 23:38
106-93-4
ND
ug/L
1.0
0.39
1
04/30/24 23:38
74-95-3
ND
ug/L
1.0
0.34
1
04/30/24 23:38
95-50-1
ND
ug/L
1.0
0.34
1
04/30/24 23:38
541-73-1
2.3
ug/L
1.0
0.33
1
04/30/24 23:38
106-46-7
ND
ug/L
1.0
0.56
1
04/30/24 23:38
110-57-6
ND
ug/L
1.0
0.35
1
04/30/24 23:38
75-71-8
3.3
ug/L
1.0
0.37
1
04/30/24 23:38
75-34-3
ND
ug/L
1.0
0.32
1
04/30/24 23:38
107-06-2
ND
ug/L
1.0
0.35
1
04/30/24 23:38
75-35-4
61.2
ug/L
1.0
0.38
1
04/30/24 23:38
156-59-2
0.591
ug/L
1.0
0.40
1
04/30/24 23:38
156-60-5
0.74J
ug/L
1.0
0.36
1
04/30/24 23:38
78-87-5
ND
ug/L
1.0
0.28
1
04/30/24 23:38
142-28-9
ND
ug/L
1.0
0.39
1
04/30/24 23:38
594-20-7
ND
ug/L
1.0
0.43
1
04/30/24 23:38
563-58-6
ND
ug/L
1.0
0.36
1
04/30/24 23:38
10061-01-5
ND
ug/L
1.0
0.36
1
04/30/24 23:38
10061-02-6
ND
ug/L
1.0
0.31
1
04/30/24 23:38
108-20-3
ND
ug/L
150
38.7
1
04/30/24 23:38
123-91-1
ND
ug/L
1.0
0.30
1
04/30/24 23:38
100-41-4
ND
ug/L
2.0
1.5
1
04/30/24 23:38
87-68-3
ND
ug/L
5.0
0.48
1
04/30/24 23:38
591-78-6
ND
ug/L
20.0
9.7
1
04/30/24 23:38
74-88-4
ND
ug/L
1.0
0.41
1
04/30/24 23:38
99-87-6
ND
ug/L
5.0
2.0
1
04/30/24 23:38
75-09-2
ND
ug/L
5.0
2.7
1
04/30/24 23:38
108-10-1
0.86.1
ug/L
1.0
0.42
1
04/30/24 23:38
1634-04-4
ND
ug/L
1.0
0.64
1
04/30/24 23:38
91-20-3
ND
ug/L
1.0
0.29
1
04/30/24 23:38
100-42-5
ND
ug/L
1.0
0.31
1
04/30/24 23:38
630-20-6
ND
ug/L
1.0
0.22
1
04/30/24 23:38
79-34-5
ND
ug/L
1.0
0.29
1
04/30/24 23:38
127-18-4
ND
ug/L
1.0
0.24
1
04/30/24 23:38
108-88-3
ND
ug/L
1.0
0.81
1
04/30/24 23:38
87-61-6
0.801
ug/L
1.0
0.64
1
04/30/24 23:38
120-82-1
ND
ug/L
1.0
0.33
1
04/30/24 23:38
71-55-6
ND
ug/L
1.0
0.32
1
04/30/24 23:38
79-00-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v1
v1
Page 12 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
Sample: MW-5 Lab ID: 92727878005 Collected: 04/23/24 11:55 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
0.57J
ug/L
1.0
0.38
1
04/30/24 23:38
79-01-6
ND
ug/L
1.0
0.30
1
04/30/24 23:38
75-69-4
ND
ug/L
1.0
0.26
1
04/30/24 23:38
96-18-4
ND
ug/L
2.0
1.3
1
04/30/24 23:38
108-05-4
11.7
ug/L
1.0
0.39
1
04/30/24 23:38
75-01-4
ND
ug/L
1.0
0.34
1
04/30/24 23:38
1330-20-7
ND
ug/L
2.0
0.71
1
04/30/24 23:38
179601-23-1
ND
ug/L
1.0
0.34
1
04/30/24 23:38
95-47-6
95
%
70-130
1
04/30/24 23:38
460-00-4
105
%
70-130
1
04/30/24 23:38
17060-07-0
98
%
70-130
1
04/30/24 23:38
2037-26-5
Sample: MW-6 Lab ID: 92727878006 Collected: 04/23/24 12:29 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Date: 05/08/2024 08:03 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
04/30/24 23:57
67-64-1
ND
ug/L
10.0
1.8
1
04/30/24 23:57
107-13-1
ND
ug/L
1.0
0.34
1
04/30/24 23:57
71-43-2
ND
ug/L
1.0
0.29
1
04/30/24 23:57
108-86-1
ND
ug/L
1.0
0.47
1
04/30/24 23:57
74-97-5
ND
ug/L
1.0
0.31
1
04/30/24 23:57
75-27-4
ND
ug/L
1.0
0.34
1
04/30/24 23:57
75-25-2
ND
ug/L
2.0
1.7
1
04/30/24 23:57
74-83-9 v2
ND
ug/L
5.0
4.0
1
04/30/24 23:57
78-93-3
ND
ug/L
2.0
0.36
1
04/30/24 23:57
75-15-0
ND
ug/L
1.0
0.33
1
04/30/24 23:57
56-23-5
ND
ug/L
1.0
0.28
1
04/30/24 23:57
108-90-7
ND
ug/L
1.0
0.65
1
04/30/24 23:57
75-00-3
ND
ug/L
1.0
0.43
1
04/30/24 23:57
67-66-3
ND
ug/L
1.0
0.54
1
04/30/24 23:57
74-87-3
ND
ug/L
1.0
0.32
1
04/30/24 23:57
95-49-8
ND
ug/L
1.0
0.32
1
04/30/24 23:57
106-43-4
ND
ug/L
2.0
0.34
1
04/30/24 23:57
96-12-8
ND
ug/L
1.0
0.36
1
04/30/24 23:57
124-48-1
ND
ug/L
1.0
0.27
1
04/30/24 23:57
106-93-4
ND
ug/L
1.0
0.39
1
04/30/24 23:57
74-95-3
ND
ug/L
1.0
0.34
1
04/30/24 23:57
95-50-1
ND
ug/L
1.0
0.34
1
04/30/24 23:57
541-73-1
ND
ug/L
1.0
0.33
1
04/30/24 23:57
106-46-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 13 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
Sample: MW-6 Lab ID: 92727878006 Collected: 04/23/24 12:29 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
1,4-Dioxane (p-Dioxane)
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 05/08/2024 08:03 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.56
1
04/30/24 23:57
110-57-6
ND
ug/L
1.0
0.35
1
04/30/24 23:57
75-71-8 v1
ND
ug/L
1.0
0.37
1
04/30/24 23:57
75-34-3
ND
ug/L
1.0
0.32
1
04/30/24 23:57
107-06-2
ND
ug/L
1.0
0.35
1
04/30/24 23:57
75-35-4
ND
ug/L
1.0
0.38
1
04/30/24 23:57
156-59-2
ND
ug/L
1.0
0.40
1
04/30/24 23:57
156-60-5
ND
ug/L
1.0
0.36
1
04/30/24 23:57
78-87-5
ND
ug/L
1.0
0.28
1
04/30/24 23:57
142-28-9
ND
ug/L
1.0
0.39
1
04/30/24 23:57
594-20-7 v1
ND
ug/L
1.0
0.43
1
04/30/24 23:57
563-58-6
ND
ug/L
1.0
0.36
1
04/30/24 23:57
10061-01-5
ND
ug/L
1.0
0.36
1
04/30/24 23:57
10061-02-6
ND
ug/L
1.0
0.31
1
04/30/24 23:57
108-20-3
ND
ug/L
150
38.7
1
04/30/24 23:57
123-91-1
ND
ug/L
1.0
0.30
1
04/30/24 23:57
100-41-4
ND
ug/L
2.0
1.5
1
04/30/24 23:57
87-68-3
ND
ug/L
5.0
0.48
1
04/30/24 23:57
591-78-6
ND
ug/L
20.0
9.7
1
04/30/24 23:57
74-88-4
ND
ug/L
1.0
0.41
1
04/30/24 23:57
99-87-6
ND
ug/L
5.0
2.0
1
04/30/24 23:57
75-09-2
ND
ug/L
5.0
2.7
1
04/30/24 23:57
108-10-1
ND
ug/L
1.0
0.42
1
04/30/24 23:57
1634-04-4
ND
ug/L
1.0
0.64
1
04/30/24 23:57
91-20-3
ND
ug/L
1.0
0.29
1
04/30/24 23:57
100-42-5
ND
ug/L
1.0
0.31
1
04/30/24 23:57
630-20-6
ND
ug/L
1.0
0.22
1
04/30/24 23:57
79-34-5
ND
ug/L
1.0
0.29
1
04/30/24 23:57
127-18-4
ND
ug/L
1.0
0.24
1
04/30/24 23:57
108-88-3
ND
ug/L
1.0
0.81
1
04/30/24 23:57
87-61-6
ND
ug/L
1.0
0.64
1
04/30/24 23:57
120-82-1
ND
ug/L
1.0
0.33
1
04/30/24 23:57
71-55-6
ND
ug/L
1.0
0.32
1
04/30/24 23:57
79-00-5
ND
ug/L
1.0
0.38
1
04/30/24 23:57
79-01-6
ND
ug/L
1.0
0.30
1
04/30/24 23:57
75-69-4
ND
ug/L
1.0
0.26
1
04/30/24 23:57
96-18-4
ND
ug/L
2.0
1.3
1
04/30/24 23:57
108-05-4
ND
ug/L
1.0
0.39
1
04/30/24 23:57
75-01-4
ND
ug/L
1.0
0.34
1
04/30/24 23:57
1330-20-7
ND
ug/L
2.0
0.71
1
04/30/24 23:57
179601-23-1
ND
ug/L
1.0
0.34
1
04/30/24 23:57
95-47-6
95
%
70-130
1
04/30/24 23:57
460-00-4
106
%
70-130
1
04/30/24 23:57
17060-07-0
101
%
70-130
1
04/30/24 23:57
2037-26-5
REPORT
OF LABORATORY ANALYSIS
This report shall not be reproduced,
except in full,
without the written
consent of Pace
Analytical Services, LLC.
Page 14 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
Sample: MW-7 Lab ID: 92727878007 Collected: 04/23/24 10:38 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
1,4-Dioxane (p-Dioxane)
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
p-Isopropyltoluene
Methylene Chloride
Date: 05/08/2024 08:03 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
5.1
1
05/01/24 00:16
67-64-1
ND
ug/L
10.0
1.8
1
05/01/24 00:16
107-13-1
ND
ug/L
1.0
0.34
1
05/01/24 00:16
71-43-2
ND
ug/L
1.0
0.29
1
05/01/24 00:16
108-86-1
ND
ug/L
1.0
0.47
1
05/01/24 00:16
74-97-5
ND
ug/L
1.0
0.31
1
05/01/24 00:16
75-27-4
ND
ug/L
1.0
0.34
1
05/01/24 00:16
75-25-2
ND
ug/L
2.0
1.7
1
05/01/24 00:16
74-83-9
ND
ug/L
5.0
4.0
1
05/01/24 00:16
78-93-3
ND
ug/L
2.0
0.36
1
05/01/24 00:16
75-15-0
ND
ug/L
1.0
0.33
1
05/01/24 00:16
56-23-5
ND
ug/L
1.0
0.28
1
05/01/24 00:16
108-90-7
ND
ug/L
1.0
0.65
1
05/01/24 00:16
75-00-3
ND
ug/L
1.0
0.43
1
05/01/24 00:16
67-66-3
ND
ug/L
1.0
0.54
1
05/01/24 00:16
74-87-3
ND
ug/L
1.0
0.32
1
05/01/24 00:16
95-49-8
ND
ug/L
1.0
0.32
1
05/01/24 00:16
106-43-4
ND
ug/L
2.0
0.34
1
05/01/24 00:16
96-12-8
ND
ug/L
1.0
0.36
1
05/01/24 00:16
124-48-1
ND
ug/L
1.0
0.27
1
05/01/24 00:16
106-93-4
ND
ug/L
1.0
0.39
1
05/01/24 00:16
74-95-3
ND
ug/L
1.0
0.34
1
05/01/24 00:16
95-50-1
ND
ug/L
1.0
0.34
1
05/01/24 00:16
541-73-1
ND
ug/L
1.0
0.33
1
05/01/24 00:16
106-46-7
ND
ug/L
1.0
0.56
1
05/01/24 00:16
110-57-6
ND
ug/L
1.0
0.35
1
05/01/24 00:16
75-71-8
1.3
ug/L
1.0
0.37
1
05/01/24 00:16
75-34-3
ND
ug/L
1.0
0.32
1
05/01/24 00:16
107-06-2
ND
ug/L
1.0
0.35
1
05/01/24 00:16
75-35-4
4.9
ug/L
1.0
0.38
1
05/01/24 00:16
156-59-2
ND
ug/L
1.0
0.40
1
05/01/24 00:16
156-60-5
ND
ug/L
1.0
0.36
1
05/01/24 00:16
78-87-5
ND
ug/L
1.0
0.28
1
05/01/24 00:16
142-28-9
ND
ug/L
1.0
0.39
1
05/01/24 00:16
594-20-7
ND
ug/L
1.0
0.43
1
05/01/24 00:16
563-58-6
ND
ug/L
1.0
0.36
1
05/01/24 00:16
10061-01-5
ND
ug/L
1.0
0.36
1
05/01/24 00:16
10061-02-6
ND
ug/L
1.0
0.31
1
05/01/24 00:16
108-20-3
ND
ug/L
150
38.7
1
05/01/24 00:16
123-91-1
ND
ug/L
1.0
0.30
1
05/01/24 00:16
100-41-4
ND
ug/L
2.0
1.5
1
05/01/24 00:16
87-68-3
ND
ug/L
5.0
0.48
1
05/01/24 00:16
591-78-6
ND
ug/L
20.0
9.7
1
05/01/24 00:16
74-88-4
ND
ug/L
1.0
0.41
1
05/01/24 00:16
99-87-6
ND
ug/L
5.0
2.0
1
05/01/24 00:16
75-09-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v1
v1
Page 15 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
Sample: MW-7 Lab ID: 92727878007 Collected: 04/23/24 10:38 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
5.0
2.7
1
05/01/24 00:16
108-10-1
ND
ug/L
1.0
0.42
1
05/01/24 00:16
1634-04-4
ND
ug/L
1.0
0.64
1
05/01/24 00:16
91-20-3
ND
ug/L
1.0
0.29
1
05/01/24 00:16
100-42-5
ND
ug/L
1.0
0.31
1
05/01/24 00:16
630-20-6
ND
ug/L
1.0
0.22
1
05/01/24 00:16
79-34-5
0.501
ug/L
1.0
0.29
1
05/01/24 00:16
127-18-4
ND
ug/L
1.0
0.24
1
05/01/24 00:16
108-88-3
ND
ug/L
1.0
0.81
1
05/01/24 00:16
87-61-6
ND
ug/L
1.0
0.64
1
05/01/24 00:16
120-82-1
ND
ug/L
1.0
0.33
1
05/01/24 00:16
71-55-6
ND
ug/L
1.0
0.32
1
05/01/24 00:16
79-00-5
1.7
ug/L
1.0
0.38
1
05/01/24 00:16
79-01-6
ND
ug/L
1.0
0.30
1
05/01/24 00:16
75-69-4
ND
ug/L
1.0
0.26
1
05/01/24 00:16
96-18-4
ND
ug/L
2.0
1.3
1
05/01/24 00:16
108-05-4
0.96J
ug/L
1.0
0.39
1
05/01/24 00:16
75-01-4
ND
ug/L
1.0
0.34
1
05/01/24 00:16
1330-20-7
ND
ug/L
2.0
0.71
1
05/01/24 00:16
179601-23-1
ND
ug/L
1.0
0.34
1
05/01/24 00:16
95-47-6
98
%
70-130
1
05/01/24 00:16
460-00-4
103
%
70-130
1
05/01/24 00:16
17060-07-0
98
%
70-130
1
05/01/24 00:16
2037-26-5
Sample: MW-7D
Parameters
Lab ID:
Results
92727878008
Units
Collected:
Report
Limit
04/23/24 10:20
MDL DF
Received: 04/30/24 10:25 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical
Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
05/01/24 00:34
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
05/01/24 00:34
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
05/01/24 00:34
71-43-2
Bromobenzene
ND
ug/L
1.0
0.29
1
05/01/24 00:34
108-86-1
Bromochloromethane
ND
ug/L
1.0
0.47
1
05/01/24 00:34
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
05/01/24 00:34
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
05/01/24 00:34
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
05/01/24 00:34
74-83-9 v2
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
05/01/24 00:34
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
05/01/24 00:34
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
05/01/24 00:34
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
05/01/24 00:34
108-90-7
Date: 05/08/2024 08:03 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 16 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
Sample: MW-7D Lab ID: 92727878008 Collected: 04/23/24 10:20 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
1,4-Dioxane (p-Dioxane)
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Date: 05/08/2024 08:03 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.65
1
05/01/24 00:34
75-00-3
ND
ug/L
1.0
0.43
1
05/01/24 00:34
67-66-3
ND
ug/L
1.0
0.54
1
05/01/24 00:34
74-87-3
ND
ug/L
1.0
0.32
1
05/01/24 00:34
95-49-8
ND
ug/L
1.0
0.32
1
05/01/24 00:34
106-43-4
ND
ug/L
2.0
0.34
1
05/01/24 00:34
96-12-8
ND
ug/L
1.0
0.36
1
05/01/24 00:34
124-48-1
ND
ug/L
1.0
0.27
1
05/01/24 00:34
106-93-4
ND
ug/L
1.0
0.39
1
05/01/24 00:34
74-95-3
ND
ug/L
1.0
0.34
1
05/01/24 00:34
95-50-1
ND
ug/L
1.0
0.34
1
05/01/24 00:34
541-73-1
ND
ug/L
1.0
0.33
1
05/01/24 00:34
106-46-7
ND
ug/L
1.0
0.56
1
05/01/24 00:34
110-57-6
0.811
ug/L
1.0
0.35
1
05/01/24 00:34
75-71-8
1.4
ug/L
1.0
0.37
1
05/01/24 00:34
75-34-3
ND
ug/L
1.0
0.32
1
05/01/24 00:34
107-06-2
ND
ug/L
1.0
0.35
1
05/01/24 00:34
75-35-4
3.7
ug/L
1.0
0.38
1
05/01/24 00:34
156-59-2
ND
ug/L
1.0
0.40
1
05/01/24 00:34
156-60-5
ND
ug/L
1.0
0.36
1
05/01/24 00:34
78-87-5
ND
ug/L
1.0
0.28
1
05/01/24 00:34
142-28-9
ND
ug/L
1.0
0.39
1
05/01/24 00:34
594-20-7
ND
ug/L
1.0
0.43
1
05/01/24 00:34
563-58-6
ND
ug/L
1.0
0.36
1
05/01/24 00:34
10061-01-5
ND
ug/L
1.0
0.36
1
05/01/24 00:34
10061-02-6
ND
ug/L
1.0
0.31
1
05/01/24 00:34
108-20-3
ND
ug/L
150
38.7
1
05/01/24 00:34
123-91-1
ND
ug/L
1.0
0.30
1
05/01/24 00:34
100-41-4
ND
ug/L
2.0
1.5
1
05/01/24 00:34
87-68-3
ND
ug/L
5.0
0.48
1
05/01/24 00:34
591-78-6
ND
ug/L
20.0
9.7
1
05/01/24 00:34
74-88-4
ND
ug/L
1.0
0.41
1
05/01/24 00:34
99-87-6
ND
ug/L
5.0
2.0
1
05/01/24 00:34
75-09-2
ND
ug/L
5.0
2.7
1
05/01/24 00:34
108-10-1
ND
ug/L
1.0
0.42
1
05/01/24 00:34
1634-04-4
ND
ug/L
1.0
0.64
1
05/01/24 00:34
91-20-3
ND
ug/L
1.0
0.29
1
05/01/24 00:34
100-42-5
ND
ug/L
1.0
0.31
1
05/01/24 00:34
630-20-6
ND
ug/L
1.0
0.22
1
05/01/24 00:34
79-34-5
3.8
ug/L
1.0
0.29
1
05/01/24 00:34
127-18-4
ND
ug/L
1.0
0.24
1
05/01/24 00:34
108-88-3
ND
ug/L
1.0
0.81
1
05/01/24 00:34
87-61-6
ND
ug/L
1.0
0.64
1
05/01/24 00:34
120-82-1
ND
ug/L
1.0
0.33
1
05/01/24 00:34
71-55-6
ND
ug/L
1.0
0.32
1
05/01/24 00:34
79-00-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v1
v1
Page 17 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
Sample: MW-7D Lab ID: 92727878008 Collected: 04/23/24 10:20 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
1.2
ug/L
1.0
0.38
1
05/01/24 00:34
79-01-6
0.78J
ug/L
1.0
0.30
1
05/01/24 00:34
75-69-4
ND
ug/L
1.0
0.26
1
05/01/24 00:34
96-18-4
ND
ug/L
2.0
1.3
1
05/01/24 00:34
108-05-4
0.69.1
ug/L
1.0
0.39
1
05/01/24 00:34
75-01-4
ND
ug/L
1.0
0.34
1
05/01/24 00:34
1330-20-7
ND
ug/L
2.0
0.71
1
05/01/24 00:34
179601-23-1
ND
ug/L
1.0
0.34
1
05/01/24 00:34
95-47-6
99
%
70-130
1
05/01/24 00:34
460-00-4
101
%
70-130
1
05/01/24 00:34
17060-07-0
102
%
70-130
1
05/01/24 00:34
2037-26-5
Sample: SW-1 Lab ID: 92727878009 Collected: 04/23/24 14:20 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Date: 05/08/2024 08:03 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
05/01/24 00:53
67-64-1
ND
ug/L
10.0
1.8
1
05/01/24 00:53
107-13-1
ND
ug/L
1.0
0.34
1
05/01/24 00:53
71-43-2
ND
ug/L
1.0
0.29
1
05/01/24 00:53
108-86-1
ND
ug/L
1.0
0.47
1
05/01/24 00:53
74-97-5
ND
ug/L
1.0
0.31
1
05/01/24 00:53
75-27-4
ND
ug/L
1.0
0.34
1
05/01/24 00:53
75-25-2
ND
ug/L
2.0
1.7
1
05/01/24 00:53
74-83-9 v2
ND
ug/L
5.0
4.0
1
05/01/24 00:53
78-93-3
ND
ug/L
2.0
0.36
1
05/01/24 00:53
75-15-0
ND
ug/L
1.0
0.33
1
05/01/24 00:53
56-23-5
ND
ug/L
1.0
0.28
1
05/01/24 00:53
108-90-7
ND
ug/L
1.0
0.65
1
05/01/24 00:53
75-00-3
ND
ug/L
1.0
0.43
1
05/01/24 00:53
67-66-3
ND
ug/L
1.0
0.54
1
05/01/24 00:53
74-87-3
ND
ug/L
1.0
0.32
1
05/01/24 00:53
95-49-8
ND
ug/L
1.0
0.32
1
05/01/24 00:53
106-43-4
ND
ug/L
2.0
0.34
1
05/01/24 00:53
96-12-8
ND
ug/L
1.0
0.36
1
05/01/24 00:53
124-48-1
ND
ug/L
1.0
0.27
1
05/01/24 00:53
106-93-4
ND
ug/L
1.0
0.39
1
05/01/24 00:53
74-95-3
ND
ug/L
1.0
0.34
1
05/01/24 00:53
95-50-1
ND
ug/L
1.0
0.34
1
05/01/24 00:53
541-73-1
ND
ug/L
1.0
0.33
1
05/01/24 00:53
106-46-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 18 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
Sample: SW-1 Lab ID: 92727878009 Collected: 04/23/24 14:20 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
1,4-Dioxane (p-Dioxane)
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 05/08/2024 08:03 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.56
1
05/01/24 00:53
110-57-6
ND
ug/L
1.0
0.35
1
05/01/24 00:53
75-71-8 v1
ND
ug/L
1.0
0.37
1
05/01/24 00:53
75-34-3
ND
ug/L
1.0
0.32
1
05/01/24 00:53
107-06-2
ND
ug/L
1.0
0.35
1
05/01/24 00:53
75-35-4
ND
ug/L
1.0
0.38
1
05/01/24 00:53
156-59-2
ND
ug/L
1.0
0.40
1
05/01/24 00:53
156-60-5
ND
ug/L
1.0
0.36
1
05/01/24 00:53
78-87-5
ND
ug/L
1.0
0.28
1
05/01/24 00:53
142-28-9
ND
ug/L
1.0
0.39
1
05/01/24 00:53
594-20-7 v1
ND
ug/L
1.0
0.43
1
05/01/24 00:53
563-58-6
ND
ug/L
1.0
0.36
1
05/01/24 00:53
10061-01-5
ND
ug/L
1.0
0.36
1
05/01/24 00:53
10061-02-6
ND
ug/L
1.0
0.31
1
05/01/24 00:53
108-20-3
ND
ug/L
150
38.7
1
05/01/24 00:53
123-91-1
ND
ug/L
1.0
0.30
1
05/01/24 00:53
100-41-4
ND
ug/L
2.0
1.5
1
05/01/24 00:53
87-68-3
ND
ug/L
5.0
0.48
1
05/01/24 00:53
591-78-6
ND
ug/L
20.0
9.7
1
05/01/24 00:53
74-88-4
ND
ug/L
1.0
0.41
1
05/01/24 00:53
99-87-6
ND
ug/L
5.0
2.0
1
05/01/24 00:53
75-09-2
ND
ug/L
5.0
2.7
1
05/01/24 00:53
108-10-1
ND
ug/L
1.0
0.42
1
05/01/24 00:53
1634-04-4
ND
ug/L
1.0
0.64
1
05/01/24 00:53
91-20-3
ND
ug/L
1.0
0.29
1
05/01/24 00:53
100-42-5
ND
ug/L
1.0
0.31
1
05/01/24 00:53
630-20-6
ND
ug/L
1.0
0.22
1
05/01/24 00:53
79-34-5
ND
ug/L
1.0
0.29
1
05/01/24 00:53
127-18-4
ND
ug/L
1.0
0.24
1
05/01/24 00:53
108-88-3
ND
ug/L
1.0
0.81
1
05/01/24 00:53
87-61-6
ND
ug/L
1.0
0.64
1
05/01/24 00:53
120-82-1
ND
ug/L
1.0
0.33
1
05/01/24 00:53
71-55-6
ND
ug/L
1.0
0.32
1
05/01/24 00:53
79-00-5
ND
ug/L
1.0
0.38
1
05/01/24 00:53
79-01-6
ND
ug/L
1.0
0.30
1
05/01/24 00:53
75-69-4
ND
ug/L
1.0
0.26
1
05/01/24 00:53
96-18-4
ND
ug/L
2.0
1.3
1
05/01/24 00:53
108-05-4
ND
ug/L
1.0
0.39
1
05/01/24 00:53
75-01-4
ND
ug/L
1.0
0.34
1
05/01/24 00:53
1330-20-7
ND
ug/L
2.0
0.71
1
05/01/24 00:53
179601-23-1
ND
ug/L
1.0
0.34
1
05/01/24 00:53
95-47-6
94
%
70-130
1
05/01/24 00:53
460-00-4
103
%
70-130
1
05/01/24 00:53
17060-07-0
99
%
70-130
1
05/01/24 00:53
2037-26-5
REPORT
OF LABORATORY ANALYSIS
This report shall not be reproduced,
except in full,
without the written
consent of Pace
Analytical Services, LLC.
Page 19 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
Sample: SW-2 Lab ID: 92727878010 Collected: 04/23/24 11:20 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
1,4-Dioxane (p-Dioxane)
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
p-Isopropyltoluene
Methylene Chloride
Date: 05/08/2024 08:03 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
5.1
1
05/01/24 01:11
67-64-1
ND
ug/L
10.0
1.8
1
05/01/24 01:11
107-13-1
ND
ug/L
1.0
0.34
1
05/01/24 01:11
71-43-2
ND
ug/L
1.0
0.29
1
05/01/24 01:11
108-86-1
ND
ug/L
1.0
0.47
1
05/01/24 01:11
74-97-5
ND
ug/L
1.0
0.31
1
05/01/24 01:11
75-27-4
ND
ug/L
1.0
0.34
1
05/01/24 01:11
75-25-2
ND
ug/L
2.0
1.7
1
05/01/24 01:11
74-83-9
ND
ug/L
5.0
4.0
1
05/01/24 01:11
78-93-3
ND
ug/L
2.0
0.36
1
05/01/24 01:11
75-15-0
ND
ug/L
1.0
0.33
1
05/01/24 01:11
56-23-5
ND
ug/L
1.0
0.28
1
05/01/24 01:11
108-90-7
ND
ug/L
1.0
0.65
1
05/01/24 01:11
75-00-3
ND
ug/L
1.0
0.43
1
05/01/24 01:11
67-66-3
ND
ug/L
1.0
0.54
1
05/01/24 01:11
74-87-3
ND
ug/L
1.0
0.32
1
05/01/24 01:11
95-49-8
ND
ug/L
1.0
0.32
1
05/01/24 01:11
106-43-4
ND
ug/L
2.0
0.34
1
05/01/24 01:11
96-12-8
ND
ug/L
1.0
0.36
1
05/01/24 01:11
124-48-1
ND
ug/L
1.0
0.27
1
05/01/24 01:11
106-93-4
ND
ug/L
1.0
0.39
1
05/01/24 01:11
74-95-3
ND
ug/L
1.0
0.34
1
05/01/24 01:11
95-50-1
ND
ug/L
1.0
0.34
1
05/01/24 01:11
541-73-1
ND
ug/L
1.0
0.33
1
05/01/24 01:11
106-46-7
ND
ug/L
1.0
0.56
1
05/01/24 01:11
110-57-6
ND
ug/L
1.0
0.35
1
05/01/24 01:11
75-71-8
ND
ug/L
1.0
0.37
1
05/01/24 01:11
75-34-3
ND
ug/L
1.0
0.32
1
05/01/24 01:11
107-06-2
ND
ug/L
1.0
0.35
1
05/01/24 01:11
75-35-4
1.5
ug/L
1.0
0.38
1
05/01/24 01:11
156-59-2
ND
ug/L
1.0
0.40
1
05/01/24 01:11
156-60-5
ND
ug/L
1.0
0.36
1
05/01/24 01:11
78-87-5
ND
ug/L
1.0
0.28
1
05/01/24 01:11
142-28-9
ND
ug/L
1.0
0.39
1
05/01/24 01:11
594-20-7
ND
ug/L
1.0
0.43
1
05/01/24 01:11
563-58-6
ND
ug/L
1.0
0.36
1
05/01/24 01:11
10061-01-5
ND
ug/L
1.0
0.36
1
05/01/24 01:11
10061-02-6
ND
ug/L
1.0
0.31
1
05/01/24 01:11
108-20-3
ND
ug/L
150
38.7
1
05/01/24 01:11
123-91-1
ND
ug/L
1.0
0.30
1
05/01/24 01:11
100-41-4
ND
ug/L
2.0
1.5
1
05/01/24 01:11
87-68-3
ND
ug/L
5.0
0.48
1
05/01/24 01:11
591-78-6
ND
ug/L
20.0
9.7
1
05/01/24 01:11
74-88-4
ND
ug/L
1.0
0.41
1
05/01/24 01:11
99-87-6
ND
ug/L
5.0
2.0
1
05/01/24 01:11
75-09-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v1
v1
Page 20 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
Sample: SW-2 Lab ID: 92727878010 Collected: 04/23/24 11:20 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
5.0
2.7
1
05/01/24 01:11
108-10-1
ND
ug/L
1.0
0.42
1
05/01/24 01:11
1634-04-4
ND
ug/L
1.0
0.64
1
05/01/24 01:11
91-20-3
ND
ug/L
1.0
0.29
1
05/01/24 01:11
100-42-5
ND
ug/L
1.0
0.31
1
05/01/24 01:11
630-20-6
ND
ug/L
1.0
0.22
1
05/01/24 01:11
79-34-5
ND
ug/L
1.0
0.29
1
05/01/24 01:11
127-18-4
ND
ug/L
1.0
0.24
1
05/01/24 01:11
108-88-3
ND
ug/L
1.0
0.81
1
05/01/24 01:11
87-61-6
ND
ug/L
1.0
0.64
1
05/01/24 01:11
120-82-1
ND
ug/L
1.0
0.33
1
05/01/24 01:11
71-55-6
ND
ug/L
1.0
0.32
1
05/01/24 01:11
79-00-5
ND
ug/L
1.0
0.38
1
05/01/24 01:11
79-01-6
ND
ug/L
1.0
0.30
1
05/01/24 01:11
75-69-4
ND
ug/L
1.0
0.26
1
05/01/24 01:11
96-18-4
ND
ug/L
2.0
1.3
1
05/01/24 01:11
108-05-4
ND
ug/L
1.0
0.39
1
05/01/24 01:11
75-01-4
ND
ug/L
1.0
0.34
1
05/01/24 01:11
1330-20-7
ND
ug/L
2.0
0.71
1
05/01/24 01:11
179601-23-1
ND
ug/L
1.0
0.34
1
05/01/24 01:11
95-47-6
100
%
70-130
1
05/01/24 01:11
460-00-4
109
%
70-130
1
05/01/24 01:11
17060-07-0
97
%
70-130
1
05/01/24 01:11
2037-26-5
Sample: SW-3 Lab ID: 92727878011 Collected: 04/23/24 10:30 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Date: 05/08/2024 08:03 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
ND
ug/L
10.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
5.1
1
05/01/24 01:30
67-64-1
1.8
1
05/01/24 01:30
107-13-1
0.34
1
05/01/24 01:30
71-43-2
0.29
1
05/01/24 01:30
108-86-1
0.47
1
05/01/24 01:30
74-97-5
0.31
1
05/01/24 01:30
75-27-4
0.34
1
05/01/24 01:30
75-25-2
1.7
1
05/01/24 01:30
74-83-9
4.0
1
05/01/24 01:30
78-93-3
0.36
1
05/01/24 01:30
75-15-0
0.33
1
05/01/24 01:30
56-23-5
0.28
1
05/01/24 01:30
108-90-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
Page 21 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
Sample: SW-3 Lab ID: 92727878011 Collected: 04/23/24 10:30 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
1,4-Dioxane (p-Dioxane)
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Date: 05/08/2024 08:03 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.65
1
05/01/24 01:30
75-00-3
ND
ug/L
1.0
0.43
1
05/01/24 01:30
67-66-3
ND
ug/L
1.0
0.54
1
05/01/24 01:30
74-87-3
ND
ug/L
1.0
0.32
1
05/01/24 01:30
95-49-8
ND
ug/L
1.0
0.32
1
05/01/24 01:30
106-43-4
ND
ug/L
2.0
0.34
1
05/01/24 01:30
96-12-8
ND
ug/L
1.0
0.36
1
05/01/24 01:30
124-48-1
ND
ug/L
1.0
0.27
1
05/01/24 01:30
106-93-4
ND
ug/L
1.0
0.39
1
05/01/24 01:30
74-95-3
ND
ug/L
1.0
0.34
1
05/01/24 01:30
95-50-1
ND
ug/L
1.0
0.34
1
05/01/24 01:30
541-73-1
ND
ug/L
1.0
0.33
1
05/01/24 01:30
106-46-7
ND
ug/L
1.0
0.56
1
05/01/24 01:30
110-57-6
ND
ug/L
1.0
0.35
1
05/01/24 01:30
75-71-8
ND
ug/L
1.0
0.37
1
05/01/24 01:30
75-34-3
ND
ug/L
1.0
0.32
1
05/01/24 01:30
107-06-2
ND
ug/L
1.0
0.35
1
05/01/24 01:30
75-35-4
0.66J
ug/L
1.0
0.38
1
05/01/24 01:30
156-59-2
ND
ug/L
1.0
0.40
1
05/01/24 01:30
156-60-5
ND
ug/L
1.0
0.36
1
05/01/24 01:30
78-87-5
ND
ug/L
1.0
0.28
1
05/01/24 01:30
142-28-9
ND
ug/L
1.0
0.39
1
05/01/24 01:30
594-20-7
ND
ug/L
1.0
0.43
1
05/01/24 01:30
563-58-6
ND
ug/L
1.0
0.36
1
05/01/24 01:30
10061-01-5
ND
ug/L
1.0
0.36
1
05/01/24 01:30
10061-02-6
ND
ug/L
1.0
0.31
1
05/01/24 01:30
108-20-3
ND
ug/L
150
38.7
1
05/01/24 01:30
123-91-1
ND
ug/L
1.0
0.30
1
05/01/24 01:30
100-41-4
ND
ug/L
2.0
1.5
1
05/01/24 01:30
87-68-3
ND
ug/L
5.0
0.48
1
05/01/24 01:30
591-78-6
ND
ug/L
20.0
9.7
1
05/01/24 01:30
74-88-4
ND
ug/L
1.0
0.41
1
05/01/24 01:30
99-87-6
ND
ug/L
5.0
2.0
1
05/01/24 01:30
75-09-2
ND
ug/L
5.0
2.7
1
05/01/24 01:30
108-10-1
ND
ug/L
1.0
0.42
1
05/01/24 01:30
1634-04-4
ND
ug/L
1.0
0.64
1
05/01/24 01:30
91-20-3
ND
ug/L
1.0
0.29
1
05/01/24 01:30
100-42-5
ND
ug/L
1.0
0.31
1
05/01/24 01:30
630-20-6
ND
ug/L
1.0
0.22
1
05/01/24 01:30
79-34-5
ND
ug/L
1.0
0.29
1
05/01/24 01:30
127-18-4
0.45J
ug/L
1.0
0.24
1
05/01/24 01:30
108-88-3
ND
ug/L
1.0
0.81
1
05/01/24 01:30
87-61-6
ND
ug/L
1.0
0.64
1
05/01/24 01:30
120-82-1
ND
ug/L
1.0
0.33
1
05/01/24 01:30
71-55-6
ND
ug/L
1.0
0.32
1
05/01/24 01:30
79-00-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v1
v1
Page 22 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
Sample: SW-3 Lab ID: 92727878011 Collected: 04/23/24 10:30 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.38
1
05/01/24 01:30
79-01-6
ND
ug/L
1.0
0.30
1
05/01/24 01:30
75-69-4
ND
ug/L
1.0
0.26
1
05/01/24 01:30
96-18-4
ND
ug/L
2.0
1.3
1
05/01/24 01:30
108-05-4
ND
ug/L
1.0
0.39
1
05/01/24 01:30
75-01-4
ND
ug/L
1.0
0.34
1
05/01/24 01:30
1330-20-7
ND
ug/L
2.0
0.71
1
05/01/24 01:30
179601-23-1
ND
ug/L
1.0
0.34
1
05/01/24 01:30
95-47-6
97
%
70-130
1
05/01/24 01:30
460-00-4
108
%
70-130
1
05/01/24 01:30
17060-07-0
102
%
70-130
1
05/01/24 01:30
2037-26-5
Sample: TRIP BLANK Lab ID: 92727878012 Collected: 04/23/24 00:00 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Date: 05/08/2024 08:03 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
10.4J
ug/L
25.0
5.1
1
04/30/24 22:05
67-64-1
ND
ug/L
10.0
1.8
1
04/30/24 22:05
107-13-1
ND
ug/L
1.0
0.34
1
04/30/24 22:05
71-43-2
ND
ug/L
1.0
0.29
1
04/30/24 22:05
108-86-1
ND
ug/L
1.0
0.47
1
04/30/24 22:05
74-97-5
ND
ug/L
1.0
0.31
1
04/30/24 22:05
75-27-4
ND
ug/L
1.0
0.34
1
04/30/24 22:05
75-25-2
ND
ug/L
2.0
1.7
1
04/30/24 22:05
74-83-9 v2
ND
ug/L
5.0
4.0
1
04/30/24 22:05
78-93-3
ND
ug/L
2.0
0.36
1
04/30/24 22:05
75-15-0
ND
ug/L
1.0
0.33
1
04/30/24 22:05
56-23-5
ND
ug/L
1.0
0.28
1
04/30/24 22:05
108-90-7
ND
ug/L
1.0
0.65
1
04/30/24 22:05
75-00-3
ND
ug/L
1.0
0.43
1
04/30/24 22:05
67-66-3
ND
ug/L
1.0
0.54
1
04/30/24 22:05
74-87-3
ND
ug/L
1.0
0.32
1
04/30/24 22:05
95-49-8
ND
ug/L
1.0
0.32
1
04/30/24 22:05
106-43-4
ND
ug/L
2.0
0.34
1
04/30/24 22:05
96-12-8
ND
ug/L
1.0
0.36
1
04/30/24 22:05
124-48-1
ND
ug/L
1.0
0.27
1
04/30/24 22:05
106-93-4
ND
ug/L
1.0
0.39
1
04/30/24 22:05
74-95-3
ND
ug/L
1.0
0.34
1
04/30/24 22:05
95-50-1
ND
ug/L
1.0
0.34
1
04/30/24 22:05
541-73-1
ND
ug/L
1.0
0.33
1
04/30/24 22:05
106-46-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 23 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
Sample: TRIP BLANK Lab ID: 92727878012 Collected: 04/23/24 00:00 Received: 04/30/24 10:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
1,4-Dioxane (p-Dioxane)
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 05/08/2024 08:03 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.56
1
04/30/24 22:05
110-57-6
ND
ug/L
1.0
0.35
1
04/30/24 22:05
75-71-8 v1
ND
ug/L
1.0
0.37
1
04/30/24 22:05
75-34-3
ND
ug/L
1.0
0.32
1
04/30/24 22:05
107-06-2
ND
ug/L
1.0
0.35
1
04/30/24 22:05
75-35-4
ND
ug/L
1.0
0.38
1
04/30/24 22:05
156-59-2
ND
ug/L
1.0
0.40
1
04/30/24 22:05
156-60-5
ND
ug/L
1.0
0.36
1
04/30/24 22:05
78-87-5
ND
ug/L
1.0
0.28
1
04/30/24 22:05
142-28-9
ND
ug/L
1.0
0.39
1
04/30/24 22:05
594-20-7 v1
ND
ug/L
1.0
0.43
1
04/30/24 22:05
563-58-6
ND
ug/L
1.0
0.36
1
04/30/24 22:05
10061-01-5
ND
ug/L
1.0
0.36
1
04/30/24 22:05
10061-02-6
ND
ug/L
1.0
0.31
1
04/30/24 22:05
108-20-3
ND
ug/L
150
38.7
1
04/30/24 22:05
123-91-1
ND
ug/L
1.0
0.30
1
04/30/24 22:05
100-41-4
ND
ug/L
2.0
1.5
1
04/30/24 22:05
87-68-3
ND
ug/L
5.0
0.48
1
04/30/24 22:05
591-78-6
ND
ug/L
20.0
9.7
1
04/30/24 22:05
74-88-4
ND
ug/L
1.0
0.41
1
04/30/24 22:05
99-87-6
ND
ug/L
5.0
2.0
1
04/30/24 22:05
75-09-2
ND
ug/L
5.0
2.7
1
04/30/24 22:05
108-10-1
ND
ug/L
1.0
0.42
1
04/30/24 22:05
1634-04-4
ND
ug/L
1.0
0.64
1
04/30/24 22:05
91-20-3
ND
ug/L
1.0
0.29
1
04/30/24 22:05
100-42-5
ND
ug/L
1.0
0.31
1
04/30/24 22:05
630-20-6
ND
ug/L
1.0
0.22
1
04/30/24 22:05
79-34-5
ND
ug/L
1.0
0.29
1
04/30/24 22:05
127-18-4
ND
ug/L
1.0
0.24
1
04/30/24 22:05
108-88-3
ND
ug/L
1.0
0.81
1
04/30/24 22:05
87-61-6
ND
ug/L
1.0
0.64
1
04/30/24 22:05
120-82-1
ND
ug/L
1.0
0.33
1
04/30/24 22:05
71-55-6
ND
ug/L
1.0
0.32
1
04/30/24 22:05
79-00-5
ND
ug/L
1.0
0.38
1
04/30/24 22:05
79-01-6
ND
ug/L
1.0
0.30
1
04/30/24 22:05
75-69-4
ND
ug/L
1.0
0.26
1
04/30/24 22:05
96-18-4
ND
ug/L
2.0
1.3
1
04/30/24 22:05
108-05-4
ND
ug/L
1.0
0.39
1
04/30/24 22:05
75-01-4
ND
ug/L
1.0
0.34
1
04/30/24 22:05
1330-20-7
ND
ug/L
2.0
0.71
1
04/30/24 22:05
179601-23-1
ND
ug/L
1.0
0.34
1
04/30/24 22:05
95-47-6
94
%
70-130
1
04/30/24 22:05
460-00-4
104
%
70-130
1
04/30/24 22:05
17060-07-0
103
%
70-130
1
04/30/24 22:05
2037-26-5
REPORT
OF LABORATORY ANALYSIS
This report shall not be reproduced,
except in full,
without the written
consent of Pace
Analytical Services, LLC.
Page 24 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4 Pace Analytical Services, LLC
�aceo 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
QC Batch: 850910 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92727878001, 92727878002, 92727878003, 92727878004, 92727878005, 92727878006, 92727878007,
92727878008,92727878009,92727878010,92727878011,92727878012
METHOD BLANK: 4392102 Matrix: Water
Associated Lab Samples: 92727878001, 92727878002, 92727878003, 92727878004, 92727878005, 92727878006, 92727878007,
92727878008,92727878009,92727878010,92727878011,92727878012
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
04/30/24 20:50
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
04/30/24 20:50
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
04/30/24 20:50
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
04/30/24 20:50
1,1-Dichloroethane
ug/L
ND
1.0
0.37
04/30/24 20:50
1,1-Dichloroethene
ug/L
ND
1.0
0.35
04/30/24 20:50
1,1-Dichloropropene
ug/L
ND
1.0
0.43
04/30/24 20:50
1,2,3-Trichlorobenzene
ug/L
ND
1.0
0.81
04/30/24 20:50
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
04/30/24 20:50
1,2,4-Trichlorobenzene
ug/L
ND
1.0
0.64
04/30/24 20:50
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
04/30/24 20:50
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
04/30/24 20:50
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
04/30/24 20:50
1,2-Dichloroethane
ug/L
ND
1.0
0.32
04/30/24 20:50
1,2-Dichloropropane
ug/L
ND
1.0
0.36
04/30/24 20:50
1,3-Dichlorobenzene
ug/L
ND
1.0
0.34
04/30/24 20:50
1,3-Dichloropropane
ug/L
ND
1.0
0.28
04/30/24 20:50
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
04/30/24 20:50
1,4-Dioxane (p-Dioxane)
ug/L
ND
150
38.7
04/30/24 20:50
2,2-Dichloropropane
ug/L
ND
1.0
0.39
04/30/24 20:50
2-Butanone (MEK)
ug/L
ND
5.0
4.0
04/30/24 20:50
2-Chlorotoluene
ug/L
ND
1.0
0.32
04/30/24 20:50
2-Hexanone
ug/L
ND
5.0
0.48
04/30/24 20:50
4-Chlorotoluene
ug/L
ND
1.0
0.32
04/30/24 20:50
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
04/30/24 20:50
Acetone
ug/L
ND
25.0
5.1
04/30/24 20:50
Acrylonitrile
ug/L
ND
10.0
1.8
04/30/24 20:50
Benzene
ug/L
ND
1.0
0.34
04/30/24 20:50
Bromobenzene
ug/L
ND
1.0
0.29
04/30/24 20:50
Bromochloromethane
ug/L
ND
1.0
0.47
04/30/24 20:50
Bromodichloromethane
ug/L
ND
1.0
0.31
04/30/24 20:50
Bromoform
ug/L
ND
1.0
0.34
04/30/24 20:50
Bromomethane
ug/L
ND
2.0
1.7
04/30/24 20:50
Carbon disulfide
ug/L
ND
2.0
0.36
04/30/24 20:50
Carbon tetrachloride
ug/L
ND
1.0
0.33
04/30/24 20:50
Chlorobenzene
ug/L
ND
1.0
0.28
04/30/24 20:50
Chloroethane
ug/L
ND
1.0
0.65
04/30/24 20:50
Chloroform
ug/L
ND
1.0
0.43
04/30/24 20:50
Chloromethane
ug/L
ND
1.0
0.54
04/30/24 20:50
v1
v2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/08/2024 08:03 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4 Pace Analytical Services, LLC
�aceo 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
METHOD BLANK: 4392102 Matrix: Water
Associated Lab Samples: 92727878001, 92727878002, 92727878003, 92727878004, 92727878005, 92727878006, 92727878007,
92727878008,92727878009,92727878010,92727878011,92727878012
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
04/30/24 20:50
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
04/30/24 20:50
Dibromochloromethane
ug/L
ND
1.0
0.36
04/30/24 20:50
Dibromomethane
ug/L
ND
1.0
0.39
04/30/24 20:50
Dichlorodifluoromethane
ug/L
ND
1.0
0.35
04/30/24 20:50 v1
Diisopropyl ether
ug/L
ND
1.0
0.31
04/30/24 20:50
Ethylbenzene
ug/L
ND
1.0
0.30
04/30/24 20:50
Hexachloro-1,3-butadiene
ug/L
ND
2.0
1.5
04/30/24 20:50
lodomethane
ug/L
9.8J
20.0
9.7
04/30/24 20:50
m&p-Xylene
ug/L
ND
2.0
0.71
04/30/24 20:50
Methyl-tert-butyl ether
ug/L
ND
1.0
0.42
04/30/24 20:50
Methylene Chloride
ug/L
ND
5.0
2.0
04/30/24 20:50
Naphthalene
ug/L
ND
1.0
0.64
04/30/24 20:50
o-Xylene
ug/L
ND
1.0
0.34
04/30/24 20:50
p-Isopropyltoluene
ug/L
ND
1.0
0.41
04/30/24 20:50
Styrene
ug/L
ND
1.0
0.29
04/30/24 20:50
Tetrachloroethene
ug/L
ND
1.0
0.29
04/30/24 20:50
Toluene
ug/L
ND
1.0
0.24
04/30/24 20:50
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
04/30/24 20:50
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
04/30/24 20:50
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
04/30/24 20:50
Trichloroethene
ug/L
ND
1.0
0.38
04/30/24 20:50
Trichlorofluoromethane
ug/L
ND
1.0
0.30
04/30/24 20:50
Vinyl acetate
ug/L
ND
2.0
1.3
04/30/24 20:50
Vinyl chloride
ug/L
ND
1.0
0.39
04/30/24 20:50
Xylene (Total)
ug/L
ND
1.0
0.34
04/30/24 20:50
1,2-Dichloroethane-d4 (S)
%
103
70-130
04/30/24 20:50
4-Bromofluorobenzene (S)
%
97
70-130
04/30/24 20:50
Toluene-d8 (S)
%
100
70-130
04/30/24 20:50
LABORATORY CONTROL SAMPLE:
4392103
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
20
21.9
110
70-130
1,1,1-Trichloroethane
ug/L
20
21.7
109
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
19.0
95
70-130
1,1,2-Trichloroethane
ug/L
20
19.7
98
70-130
1,1-Dichloroethane
ug/L
20
20.4
102
70-130
1,1-Dichloroethene
ug/L
20
22.5
113
69-131
1,1-Dichloropropene
ug/L
20
20.9
104
70-132
1,2,3-Trichlorobenzene
ug/L
20
22.0
110
70-132
1,2,3-Trichloropropane
ug/L
20
19.0
95
70-130
1,2,4-Trichlorobenzene
ug/L
20
22.0
110
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/08/2024 08:03 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4 Pace Analytical Services, LLC
�aceo 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
LABORATORY CONTROL SAMPLE:
Parameter
4392103
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,2-Dibromo-3-chloropropane
ug/L
20
22.0
110
70-130
1,2-Dibromoethane (EDB)
ug/L
20
20.6
103
70-130
1,2-Dichlorobenzene
ug/L
20
21.8
109
70-130
1,2-Dichloroethane
ug/L
20
22.3
112
70-130
1,2-Dichloropropane
ug/L
20
19.7
98
70-130
1,3-Dichlorobenzene
ug/L
20
21.3
107
70-130
1,3-Dichloropropane
ug/L
20
19.6
98
70-130
1,4-Dichlorobenzene
ug/L
20
21.1
106
70-130
1,4-Dioxane(p-Dioxane)
ug/L
400
417
104
70-132
2,2-Dichloropropane
ug/L
20
24.9
125
69-130 v1
2-Butanone (MEK)
ug/L
40
40.3
101
67-133
2-Chlorotoluene
ug/L
20
20.9
105
70-130
2-Hexanone
ug/L
40
40.9
102
70-133
4-Chlorotoluene
ug/L
20
20.4
102
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
40
38.7
97
70-130
Acetone
ug/L
40
40.9
102
67-130
Acrylonitrile
ug/L
100
102
102
70-130
Benzene
ug/L
20
20.5
103
70-130
Bromobenzene
ug/L
20
20.1
100
70-130
Bromochloromethane
ug/L
20
22.1
110
70-130
Bromodichloromethane
ug/L
20
21.4
107
70-130
Bromoform
ug/L
20
21.4
107
70-133
Bromomethane
ug/L
20
14.9
74
41-148 v3
Carbon disulfide
ug/L
20
22.2
111
70-131
Carbon tetrachloride
ug/L
20
22.9
115
70-130
Chlorobenzene
ug/L
20
21.1
105
70-130
Chloroethane
ug/L
20
18.4
92
41-157
Chloroform
ug/L
20
20.8
104
70-130
Chloromethane
ug/L
20
24.0
120
59-141
cis-1,2-Dichloroethene
ug/L
20
20.2
101
70-130
cis-1,3-Dichloropropene
ug/L
20
20.2
101
70-130
Dibromochloromethane
ug/L
20
21.0
105
70-130
Dibromomethane
ug/L
20
20.6
103
70-130
Dichlorodifluoromethane
ug/L
20
27.0
135
54-147 v1
Diisopropyl ether
ug/L
20
20.8
104
70-130
Ethylbenzene
ug/L
20
21.4
107
70-130
Hexachloro-1,3-butadiene
ug/L
20
23.9
119
70-134
lodomethane
ug/L
40
43.4
109
57-140
m&p-Xylene
ug/L
40
43.0
107
70-130
Methyl-tert-butyl ether
ug/L
20
20.1
100
70-130
Methylene Chloride
ug/L
20
22.2
111
62-130
Naphthalene
ug/L
20
20.4
102
70-135
o-Xylene
ug/L
20
21.3
106
70-130
p-Isopropyltoluene
ug/L
20
21.5
108
70-130
Styrene
ug/L
20
21.6
108
70-130
Tetrachloroethene
ug/L
20
22.5
113
70-130
Toluene
ug/L
20
20.3
102
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/08/2024 08:03 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4 Pace Analytical Services, LLC
�aceo 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
LABORATORY CONTROL SAMPLE:
4392103
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
trans-1,2-Dichloroethene
ug/L
20
21.6
108
70-130
trans- 1,3-Dichloropropene
ug/L
20
21.4
107
70-130
trans-1,4-Dichloro-2-butene
ug/L
20
23.0
115
57-149
Trichloroethene
ug/L
20
21.7
109
70-130
Trichlorofluoromethane
ug/L
20
21.4
107
57-130
Vinyl acetate
ug/L
40
43.2
108
70-141
Vinyl chloride
ug/L
20
21.5
108
66-140
Xylene (Total)
ug/L
60
64.2
107
70-130
1,2-Dichloroethane-d4 (S)
%
100
70-130
4-Bromofluorobenzene (S)
%
97
70-130
Toluene-d8 (S)
%
97
70-130
MATRIX SPIKE SAMPLE:
4392104
92727878001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
27.7
138
70-146
1,1,1-Trichloroethane
ug/L
ND
20
28.4
142
70-150
1,1,2,2-Tetrachloroethane
ug/L
ND
20
24.1
121
66-144
1,1,2-Trichloroethane
ug/L
ND
20
25.2
126
70-142
1,1-Dichloroethane
ug/L
ND
20
27.9
139
68-150
1,1-Dichloroethene
ug/L
ND
20
30.6
153
64-162
1,1-Dichloropropene
ug/L
ND
20
29.5
147
70-160
1,2,3-Trichlorobenzene
ug/L
ND
20
28.7
143
66-151
1,2,3-Trichloropropane
ug/L
ND
20
25.8
129
66-144
1,2,4-Trichlorobenzene
ug/L
ND
20
28.7
143
69-147
1,2-Dibromo-3-chloropropane
ug/L
ND
20
27.1
136
62-146
1,2-Dibromoethane (EDB)
ug/L
ND
20
26.5
133
70-143
1,2-Dichlorobenzene
ug/L
ND
20
28.6
143
70-142 M1
1,2-Dichloroethane
ug/L
ND
20
28.2
141
68-145
1,2-Dichloropropane
ug/L
ND
20
25.9
130
70-144
1,3-Dichlorobenzene
ug/L
ND
20
27.8
139
70-142
1,3-Dichloropropane
ug/L
ND
20
24.8
124
70-141
1,4-Dichlorobenzene
ug/L
ND
20
28.7
143
70-140 M1
1,4-Dioxane (p-Dioxane)
ug/L
ND
400
533
133
66-151
2,2-Dichloropropane
ug/L
ND
20
34.4
172
58-160 M1
2-Butanone (MEK)
ug/L
ND
40
52.3
131
57-156
2-Chlorotoluene
ug/L
ND
20
27.9
140
70-148
2-Hexanone
ug/L
ND
40
53.3
133
62-153
4-Chlorotoluene
ug/L
ND
20
28.7
143
70-144
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
50.3
126
65-144
Acetone
ug/L
ND
40
50.3
126
49-162
Acrylonitrile
ug/L
ND
100
134
134
59-155
Benzene
ug/L
ND
20
27.0
135
68-144
Bromobenzene
ug/L
ND
20
25.8
129
70-144
Bromochloromethane
ug/L
ND
20
25.8
129
70-148
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/08/2024 08:03 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4 Pace Analytical Services, LLC
�aceo 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
MATRIX SPIKE SAMPLE:
4392104
92727878001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Bromodichloromethane
ug/L
ND
20
26.8
134
70-141
Bromoform
ug/L
ND
20
26.7
133
59-144
Bromomethane
ug/L
ND
20
22.9
114
23-190 v3
Carbon disulfide
ug/L
ND
20
30.3
152
64-160
Carbon tetrachloride
ug/L
ND
20
31.3
156
70-147 M1
Chlorobenzene
ug/L
ND
20
27.3
137
70-143
Chloroethane
ug/L
ND
20
23.9
119
55-190
Chloroform
ug/L
ND
20
27.8
138
67-148
Chloromethane
ug/L
ND
20
31.4
157
38-180
cis-1,2-Dichloroethene
ug/L
ND
20
26.8
134
67-151
cis-1,3-Dichloropropene
ug/L
ND
20
26.2
131
70-142
Dibromochloromethane
ug/L
ND
20
26.1
131
68-140
Dibromomethane
ug/L
ND
20
26.9
135
70-142
Dichlorodifluoromethane
ug/L
ND
20
45.0
225
15-200 M1,v1
Diisopropyl ether
ug/L
ND
20
27.1
135
62-149
Ethylbenzene
ug/L
ND
20
28.5
142
70-145
Hexachloro-1,3-butadiene
ug/L
ND
20
36.1
181
64-164 M1
lodomethane
ug/L
ND
40
54.1
135
37-160
m&p-Xylene
ug/L
ND
40
58.0
145
70-148
Methyl-tert-butyl ether
ug/L
ND
20
25.2
126
64-146
Methylene Chloride
ug/L
ND
20
25.7
128
54-149
Naphthalene
ug/L
ND
20
27.0
135
62-154
o-Xylene
ug/L
ND
20
27.8
139
70-145
p-Isopropyltoluene
ug/L
ND
20
29.8
149
70-153
Styrene
ug/L
ND
20
27.7
139
70-147
Tetrachloroethene
ug/L
ND
20
27.7
138
70-145
Toluene
ug/L
ND
20
26.5
133
65-146
trans-1,2-Dichloroethene
ug/L
ND
20
28.2
141
69-155
trans- 1,3-Dichloropropene
ug/L
ND
20
27.3
137
70-142
trans-1,4-Dichloro-2-butene
ug/L
ND
20
24.1
121
39-149
Trichloroethene
ug/L
ND
20
29.3
146
70-152
Trichlorofluoromethane
ug/L
ND
20
32.2
161
60-158 M1
Vinyl acetate
ug/L
ND
40
54.7
137
56-157
Vinyl chloride
ug/L
ND
20
30.7
154
51-178
Xylene (Total)
ug/L
ND
60
85.8
143
70-146
1,2-Dichloroethane-d4 (S)
%
100
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
96
70-130
SAMPLE DUPLICATE: 4392105
92727878002
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,1-Trichloroethane
ug/L
ND
ND
30
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/08/2024 08:03 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4 Pace Analytical Services, LLC
�aceo 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
SAMPLE DUPLICATE: 4392105
Parameter
Units
92727878002
Result
Dup
Result
RPD
Max
RPD Qualifiers
1,1,2-Trichloroethane
ug/L
ND
ND
30
1,1-Dichloroethane
ug/L
1.1
1.1
3
30
1,1-Dichloroethene
ug/L
ND
ND
30
1,1-Dichloropropene
ug/L
ND
ND
30
1,2,3-Trichlorobenzene
ug/L
ND
ND
30
1,2,3-Trichloropropane
ug/L
ND
ND
30
1,2,4-Trichlorobenzene
ug/L
ND
ND
30
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
30
1,2-Dibromoethane (EDB)
ug/L
ND
ND
30
1,2-Dichlorobenzene
ug/L
ND
ND
30
1,2-Dichloroethane
ug/L
ND
ND
30
1,2-Dichloropropane
ug/L
2.8
2.8
1
30
1,3-Dichlorobenzene
ug/L
ND
ND
30
1,3-Dichloropropane
ug/L
ND
ND
30
1,4-Dichlorobenzene
ug/L
2.1
2.0
4
30
1,4-Dioxane (p-Dioxane)
ug/L
ND
ND
30
2,2-Dichloropropane
ug/L
ND
ND
30
2-Butanone (MEK)
ug/L
ND
ND
30
2-Chlorotoluene
ug/L
ND
ND
30
2-Hexanone
ug/L
ND
ND
30
4-Chlorotoluene
ug/L
ND
ND
30
4-Methyl-2-pentanone (MIBK)
ug/L
ND
ND
30
Acetone
ug/L
ND
ND
30
Acrylonitrile
ug/L
ND
ND
30
Benzene
ug/L
ND
ND
30
Bromobenzene
ug/L
ND
ND
30
Bromochloromethane
ug/L
ND
ND
30
Bromodichloromethane
ug/L
ND
ND
30
Bromoform
ug/L
ND
ND
30
Bromomethane
ug/L
ND
ND
30 v2
Carbon disulfide
ug/L
ND
ND
30
Carbon tetrachloride
ug/L
ND
ND
30
Chlorobenzene
ug/L
3.9
3.8
2
30
Chloroethane
ug/L
ND
ND
30
Chloroform
ug/L
ND
ND
30
Chloromethane
ug/L
ND
ND
30
cis-1,2-Dichloroethene
ug/L
5.6
5.8
2
30
cis-1,3-Dichloropropene
ug/L
ND
ND
30
Dibromochloromethane
ug/L
ND
ND
30
Dibromomethane
ug/L
ND
ND
30
Dichlorodifluoromethane
ug/L
ND
ND
30 v1
Diisopropyl ether
ug/L
ND
ND
30
Ethylbenzene
ug/L
ND
ND
30
Hexachloro-1,3-butadiene
ug/L
ND
ND
30
lodomethane
ug/L
ND
ND
30
m&p-Xylene
ug/L
ND
ND
30
Methyl-tert-butyl ether
ug/L
ND
ND
30
Results presented on this page are in the units
indicated by the "Units" column except where an alternate unit is presented
to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/08/2024 08:03 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
SAMPLE DUPLICATE: 4392105
Parameter
Methylene Chloride
Naphthalene
o-Xylene
p-Isopropyltoluene
Styrene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans- 1,3-Dichloropropene
trans-1,4-Dichloro-2-butene
Trichloroethene
Trichlorofluoromethane
Vinyl acetate
Vinyl chloride
Xylene (Total)
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
QUALITY CONTROL DATA
Units
92727878002
Result
Dup
Result
ug/L
ND
ND
ug/L
ND
ND
ug/L
ND
ND
ug/L
ND
ND
ug/L
ND
ND
ug/L
1.5
1.7
ug/L
ND
ND
ug/L
ND
ND
ug/L
ND
ND
ug/L
ND
ND
ug/L
0.53J
ND
ug/L
ND
ND
ug/L
ND
ND
ug/L
0.68J
0.77J
ug/L
ND
ND
107
103
%
98
97
100
101
IVV
IN
Max
RPD
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/08/2024 08:03 PM without the written consent of Pace Analytical Services, LLC.
Page 31 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/08/2024 08:03 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 37

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
aceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: PERSON COUNTY LANDFILL
Pace Project No.: 92727878
Lab ID Sample ID QC Batch Method QC Batch
92727878001
MW-1
EPA 8260D
850910
92727878002
MW-2
EPA 8260D
850910
92727878003
MW-3
EPA 8260D
850910
92727878004
MW-4
EPA 8260D
850910
92727878005
MW-5
EPA 8260D
850910
92727878006
MW-6
EPA 8260D
850910
92727878007
MW-7
EPA 8260D
850910
92727878008
MW-7D
EPA 8260D
850910
92727878009
SW-1
EPA 8260D
850910
92727878010
SW-2
EPA 8260D
850910
92727878011
SW-3
EPA 8260D
850910
92727878012
TRIP BLANK
EPA 8260D
850910
Date: 05/08/2024 08:03 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical Method
Analytical
Batch
Page 33 of 37

I _'n I nr4i rw.. GIU%r_PPu_ui iIUi _nnaz . A3 Sample Condition Upon Receipt
Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4 —
_LlLG
Effective Date: 11/29/2023 4.16:30 PM
Laboratory receiving samples: �(
Asheville ❑ Eden❑ Greenwood ❑ Huntersville [�/� Raleigh[]Mechanicswillef-1
ConditionSample Client Name: W�1� �O# : 9272787 V
Upon Receipt Project q:
Courier. Fed Ex El UPS VUSPS Client`
Commercial ❑ Pace ❑ other: V g 1z"
❑ ,�,/ 192727878
Custody Sea] Present? ❑ Yes No Seals Intact? ❑ Yes ❑ No EI N/A L �j tA I
Date/Initials Person Examining Contents: `►� /
Packing Material: ❑ Bubble Wrap ❑ Bubble Bags ❑ None [!�' Other Biological Tissue Fyozen? I
1�' , ..
Therrnome;er: ,_//
IR Gun ID: �{�1 l Type of Ice: L�J Wer ❑ Blue ❑None
Correction Factor:
Cooler Temp: Add/Subtract ('C) Temp should be above freezing to 6'C
❑ Samples out of temp criteria. Sampfes on ice, cooling process
r'nnlar Tamp rh"PrIPH
USDA Regulated Sail ( JZ N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC Did samples originate from a foreign source {internationally,
fr_hPrk ma❑s1? M Yes ❑ N❑ including Hawaii and Puerto Mcol? ❑ Yes ❑ No
Comments/Discrepancy:
Chain of Custody Present?
Yes
❑ No
❑ N/A
1.
Samples Arrived within Hold Time?
Yes
❑ No
❑ N/A
2.
Short Hold Time Analysis (<72 hr.)?
❑ Yes
No
❑ N/A
3.
Rush Turn Around Time Re uested?
Yes
No
❑N/A
4.
Sufficient Volume?
,.,
t_JYes
❑No
El N/A
S.
Correct Containers Used?
E6es
❑No
❑N/A
S.
-Pace Containers Used?
21Yes
❑No
❑NIA
Containers Intact?
Ua<es
C No
❑ N/A
7.
Dissolved analysis: Samples Field Filtered?
❑Yes
❑No
IIN/A
B.
Sample Labels Match COC?
Yes
❑ No
❑ N/A
9.
l
-includes Date/Time/ID/Analysis— Matrix:
`�� 1
HeadspaceinVOAVials (>5-6mm)?
❑Yes
BNo
El N/A
10.
Trip Blank Present?
Yes
El No
❑ N/A
11.
Trip Blank Custody Seals Present?
©Yes
Sd No
❑ N/A
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Project Manager SRF Review:
Lot ID of split containers:
Date/Time:
Date:
Date:
Field Data Required? ❑ Yes ❑ No
Qualtrax ID: 69614 Paa e 1 of 2 Page 34 of 37

L{ V V
Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
"Check mark top half of box if pH and/or dechlorination is verified and
within the acceptance range for preservation samples.
Exceptions: VOA, Coliform, 70C.Oil and Grease, DRO18015 (slater) DOC• LLH&
"Bottom half of box is to list number of bottles
`*'Check all unpreserved Nitrates for chlorine
I
Project ii WU# : 9"_72 ■ 878
PM: SK Due Date: 05/09/24
CLIENT: 92-ENV 1
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Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Arnauni of Preser�rative T Lot 4
adjusted added
PSote- WIriv Lever there is a diScrepancyaffecting Mo;th Carolina corr.pliance samples. a copy or this loan 1-01 br sent to thn Nartl+ Carolina DE,IiR Certification Ofrice tr e
Out of hold, incorrect preserv1tive, out of temp, incorrect Conta-ncrs.
Qualtrait ID. 6961-4
Page 2 of 2
Page 35 of 37

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Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
�APPL
AGRICULTURE P. PRIORITY POLLUTANTS LABORATORIES
Da A METIRI GROUP COMPANY
May 16, 2024
Ann Baynor
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
RE: 6034 Person Co. Landfill
K I>Q'1'7
908 N. Temperance Ave., Clovis, CA 93611 - Phone [phone] - www.metirigroup.com
NELAP Certification Number: CA00046
DoD-ELAP Certification Number: 4064.01
State Certification Number:
Enclosed are the results of analyses for samples received by our laboratory on 4/26/2024. If you
have any questions concerning this report, please feel free to contact me.
I certify that this data package is in compliance with the terms and conditions of the contract, both
technically and for completeness, for other than the conditions detailed above. These test results
meet all requirements of NELAC and DoD QSM. Release of the hard copy has been authorized by
the Laboratory Manager or designee, as verified by the following signature.
Sincerely,
Chue Moua [e-mail]
Project Manager 559-862-2155
Page 1 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
Table of Contents
Cover Letter
Samples in Report
Case Narratives Analyses
Sample Results
Quality Assurance Results
Qualifiers and Definitions
Login Summary
Chain of Custody
Other Documents or Sub Lab Data
1
3
3
4
28
37
38
40
41
Page 2 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Work Order Case Narrative
For samples MW-4 and MW-5 the second collection bottle were shipped to PACE in South Carolina per the client's
request.
Analysis Case Narrative
EPA 1633: Manual integrations were performed for this method in accordance with APPL's SOP. Abbreviated flags for technical
justification are provided as data qualifiers.
Samples 02 - MW-2, 04 - MW-4, 05 - MW-5, and 06 - MW-6 were subsampled due to excessive TSS.
In sample 04 — MW-4, the results for the analytes PFHpA and PFOA come from a dilution where extracted internal standards
have been added. To prevent this in the future a smaller sample volume should be collected.
The extracted internal standards 13C8-PFOSA, D3-NMeFOSA, and D5-NEtFOSA recovered below the lower control limit in
sample 05 - MW-5.
The extracted internal standards D3-NMeFOSA and D5-NEtFOSA recovered below the lower control limit in the
BDD0558-BLK1.
The analytes 3:3FTCA and 5:3FTCA recovered below the lower control limit in the BDD0558-BS1. The extracted internal
standards D5-NEtFOSA recovered below the lower control limit.
The analytes 3:3FTCA, 5:3FTCA, and 7:3FTCA recovered below the lower control limit in the BDD0558-MRL1. The extracted
internal standards D5-NEtFOSA recovered below the lower control limit.
The analytes 3:3FTCA and 5:3FTCA recovered below the lower control limit in the BDD0559-MRL1.
Samples in this Report
Lab ID
Sample
Matrix
Date Sampled
Date Received
24DO199-01
MW-1
Water
04/23/2024
21:08
04/26/2024
24DO199-02
MW-2
Water
04/23/2024
13:35
04/26/2024
24DO199-03
MW-3
Water
04/23/2024
11:22
04/26/2024
24DO199-04
MW-4
Water
04/23/2024
13:43
04/26/2024
24DO199-05
MW-5
Water
04/23/2024
11:55
04/26/2024
24DO199-06
MW-6
Water
04/23/2024
12:29
04/26/2024
24DO199-07
MW-7
Water
04/23/2024
10:38
04/26/2024
24DO199-08
MW-7D
Water
04/23/2024
10:20
04/26/2024
24DO199-09
SW-1
Water
04/23/2024
14:20
04/26/2024
24DO199-10
SW-2
Water
04/23/2024
11:20
04/26/2024
24DO199-11
SW-3
Water
04/23/2024
10:30
04/26/2024
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is allowed, except in its entirety. Page 3 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Sample Results
Sample: MW-1
24DO199-01 (Water)
Date Prep
Analyte Result/Qual PQL MDL Units Analyzed DF Method Batch
Per- and Polyfluoroalkyl Substances
PFBA
ND
1.5
0.20
ng/L
05/10/24
1
EPA
1633
BDD0558
PFPeA
ND
0.75
0.061
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHxA
0.11
J
0.38
0.052
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHpA
0.12
IR2,1
0.38
0.039
ng/L
05/10/24
1
EPA
1633
BDD0558
PFOA
0.87
M14
0.38
0.14
ng/L
05/10/24
1
EPA
1633
BDD0558
PFNA
ND
0.38
0.077
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDA
ND
0.38
0.095
ng/L
05/10/24
1
EPA
1633
BDD0558
PFUnA
ND
0.38
0.15
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDoA
ND
0.38
0.11
ng/L
05/10/24
1
EPA
1633
BDD0558
PFTrDA
ND
0.38
0.19
ng/L
05/10/24
1
EPA
1633
BDD0558
PFTeDA
ND
0.38
0.19
ng/L
05/10/24
1
EPA
1633
BDD0558
PFBS
2.7
0.38
0.035
ng/L
05/10/24
1
EPA
1633
BDD0558
PFPeS
0.11
J
0.38
0.059
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHxS
0.14
MI4,3
0.38
0.030
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHpS
ND
0.38
0.048
ng/L
05/10/24
1
EPA
1633
BDD0558
PFOS
0.40
0.38
0.060
ng/L
05/10/24
1
EPA
1633
BDD0558
PFNS
ND
0.38
0.12
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDS
ND
0.38
0.14
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDoS
ND
0.38
0.12
ng/L
05/10/24
1
EPA
1633
BDD0558
4:2FTS
ND
1.5
0.27
ng/L
05/10/24
1
EPA
1633
BDD0558
6:2FTS
ND
1.5
0.30
ng/L
05/10/24
1
EPA
1633
BDD0558
8:2FTS
ND
1.5
0.077
ng/L
05/10/24
1
EPA
1633
BDD0558
PFOSA
ND
0.38
0.098
ng/L
05/10/24
1
EPA
1633
BDD0558
NMeFOSA
ND
1.5
0.45
ng/L
05/10/24
1
EPA
1633
BDD0558
NEtFOSA
ND
1.5
0.39
ng/L
05/10/24
1
EPA
1633
BDD0558
NMeFOSAA
ND
0.38
0.10
ng/L
05/10/24
1
EPA
1633
BDD0558
NEtFOSAA
ND
0.38
0.11
ng/L
05/10/24
1
EPA
1633
BDD0558
NMeFOSE
ND
1.5
0.95
ng/L
05/10/24
1
EPA
1633
BDD0558
NEtFOSE
ND
1.5
0.98
ng/L
05/10/24
1
EPA
1633
BDD0558
HFPO-DA
ND
0.75
0.16
ng/L
05/10/24
1
EPA
1633
BDD0558
ADONA
ND
0.75
0.12
ng/L
05/10/24
1
EPA
1633
BDD0558
PFEESA
ND
0.75
0.10
ng/L
05/10/24
1
EPA
1633
BDD0558
PFMPA
ND
0.75
0.051
ng/L
05/10/24
1
EPA
1633
BDD0558
PFMBA
ND
0.75
0.085
ng/L
05/10/24
1
EPA
1633
BDD0558
NFDHA
ND
0.75
0.28
ng/L
05/10/24
1
EPA
1633
BDD0558
9CI-PF30NS
ND
0.75
0.20
ng/L
05/10/24
1
EPA
1633
BDD0558
11CI-PF30UDS
ND
0.75
0.19
ng/L
05/10/24
1
EPA
1633
BDD0558
3:3FTCA
ND
1.5
0.54
ng/L
05/10/24
1
EPA
1633
BDD0558
5:3FTCA
ND
1.5
0.42
ng/L
05/10/24
1
EPA
1633
BDD0558
7:3FTCA
ND
1.5
0.52
ng/L
05/10/24
1
EPA
1633
BDD0558
- - - - - - - - - - - - - - - - - - -
Surrogate: 13C4-PFBA
- - - - -
92.3%
- - -
- - - -
5-130
- - - -
- - - - -
- - - - -
05110124
- - -
1
- -
EPA
- - -
1633
- - - - - -
Surrogate: 13C5-PFPPA
86.8%
40-130
05110124
1
EPA
1633
Surrogate: 13C5-PFHXA
97.1 %
40-130
05110124
1
EPA
1633
Surrogate: 13C4-PFMPA
98.6%
40-130
05110124
1
EPA
1633
Surrogate: 13C8-PFOA
87.9%
40-130
05110124
1
EPA
1633
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is allowed, except in its entirety. Page 4 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Sample Results
(Continued)
Sample: MW-1 (Continued)
24DO199-01 (Water)
Date Prep
Analyte Result/Qual PQL MDL Units Analyzed DF Method Batch
Per- and Polyfluoroalkyl Substances
(Continued)
Surrogate: 13C9-PFNA
90.4%
40-130
05110124
1
EPA 1633
Surrogate: 13C6-PFDA
87.7%
40-130
05110124
1
EPA 1633
Surrogate: 13C7-PFUnA
88.2%
30-130
05110124
1
EPA 1633
Surrogate: 13C2-PFDOA
86.1 %
10-130
05110124
1
EPA 1633
Surrogate: 13C2-PFTEDA
96.8%
10-130
05110124
1
EPA 1633
Surrogate: 13C3-PFBS
95.6%
40-135
05110124
1
EPA 1633
Surrogate: 13C3-PFHXS
96.1 %
40-130
05110124
1
EPA 1633
Surrogate: 13C8-PF05
86.5%
40-130
05110124
1
EPA 1633
Surrogate: 13C24-2FT5
125916
40-200
05110124
1
EPA 1633
Surrogate: 13C2-6.2FTS
97.4%
40-200
05110124
1
EPA 1633
Surrogate: 13C2-8.2FTS
98.2%
40-300
05110124
1
EPA 1633
Surrogate: 13C8-PFOSA
51.4%
40-130
05110124
1
EPA 1633
Surrogate: D3-NMEF05A
16.4%
10-130
05110124
1
EPA 1633
Surrogate: D5-NETFOSA
16.7910
10-130
05110124
1
EPA 1633
Surrogate: D3-NMEFOSAA
91.7%
40-170
05110124
1
EPA 1633
Surrogate: D5-NETFOSAA
86.5%
25-135
05110124
1
EPA 1633
Surrogate: D7-NMEF05E
37.7%
10-130
05110124
1
EPA 1633
Surrogate: D9-NETFOSE
34.5%
10-130
05110124
1
EPA 1633
Surrogate: 13C3-HFPO-DA
93.7%
40-130
05110124
1
EPA 1633
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is alloweo,except in its entirety. Page 5 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Sample Results
(Continued)
Sample: MW-2
24DO199-02 (Water)
Date Prep
Analyte Result/Qual PQL MDL Units Analyzed DF Method Batch
Per- and Polyfluoroalkyl Substances
PFBA
350
17
2.2
ng/L
05/10/24
1
EPA
1633
BDD0558
PFPeA
360
8.5
0.69
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHxA
950
4.3
0.59
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHpA
660
4.3
0.44
ng/L
05/10/24
1
EPA
1633
BDD0558
PFOA
1700 MI4
4.3
1.6
ng/L
05/10/24
1
EPA
1633
BDD0558
PFNA
10
4.3
0.87
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDA
ND
4.3
1.1
ng/L
05/10/24
1
EPA
1633
BDD0558
PFUnA
ND
4.3
1.7
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDoA
ND
4.3
1.2
ng/L
05/10/24
1
EPA
1633
BDD0558
PFTrDA
ND
4.3
2.2
ng/L
05/10/24
1
EPA
1633
BDD0558
PFTeDA
ND
4.3
2.1
ng/L
05/10/24
1
EPA
1633
BDD0558
PFBS
280
4.3
0.39
ng/L
05/10/24
1
EPA
1633
BDD0558
PFPeS
210
4.3
0.67
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHxS
320
4.3
0.34
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHpS
23
4.3
0.55
ng/L
05/10/24
1
EPA
1633
BDD0558
PFOS
350
4.3
0.68
ng/L
05/10/24
1
EPA
1633
BDD0558
PFNS
ND
4.3
1.3
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDS
ND
4.3
1.6
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDoS
ND
4.3
1.3
ng/L
05/10/24
1
EPA
1633
BDD0558
4:2FTS
ND
17
3.1
ng/L
05/10/24
1
EPA
1633
BDD0558
6:2FTS
ND
17
3.4
ng/L
05/10/24
1
EPA
1633
BDD0558
8:2FTS
ND
17
0.88
ng/L
05/10/24
1
EPA
1633
BDD0558
PFOSA
2.1 MI4,1
4.3
1.1
ng/L
05/10/24
1
EPA
1633
BDD0558
NMeFOSA
ND
17
5.1
ng/L
05/10/24
1
EPA
1633
BDD0558
NEtFOSA
ND
17
4.4
ng/L
05/10/24
1
EPA
1633
BDD0558
NMeFOSAA
ND
4.3
1.1
ng/L
05/10/24
1
EPA
1633
BDD0558
NEtFOSAA
ND
4.3
1.2
ng/L
05/10/24
1
EPA
1633
BDD0558
NMeFOSE
ND
17
11
ng/L
05/10/24
1
EPA
1633
BDD0558
NEtFOSE
ND
17
11
ng/L
05/10/24
1
EPA
1633
BDD0558
HFPO-DA
2.3 J
8.5
1.9
ng/L
05/10/24
1
EPA
1633
BDD0558
ADONA
ND
8.5
1.3
ng/L
05/10/24
1
EPA
1633
BDD0558
PFEESA
ND
8.5
1.2
ng/L
05/10/24
1
EPA
1633
BDD0558
PFMPA
ND
8.5
0.58
ng/L
05/10/24
1
EPA
1633
BDD0558
PFMBA
ND
8.5
0.97
ng/L
05/10/24
1
EPA
1633
BDD0558
NFDHA
ND
8.5
3.2
ng/L
05/10/24
1
EPA
1633
BDD0558
9CI-PF30NS
ND
8.5
2.2
ng/L
05/10/24
1
EPA
1633
BDD0558
11CI-PF30UDS
ND
8.5
2.2
ng/L
05/10/24
1
EPA
1633
BDD0558
3:3FTCA
ND
17
6.1
ng/L
05/10/24
1
EPA
1633
BDD0558
5:3FTCA
ND
17
4.7
ng/L
05/10/24
1
EPA
1633
BDD0558
7:3FTCA
ND
17
5.9
ng/L
05/10/24
1
EPA
1633
BDD0558
- - - - - - - - - - - - - - - - - - -
Surrogate: 13C4-PFBA
- - - - - - - -
30.3%
- - - - -
5-130
- - -
- - - - -
- - - - -
05110124
- - -
1
- -
EPA
- - -
1633
- - - - - -
Surrogate: 13C5-PFPPA
78.9%
40-130
05110124
1
EPA
1633
Surrogate: 13C5-PFHXA
88.4%
40-130
05110124
1
EPA
1633
Surrogate: 13C4-PFMPA
90.9%
40-130
05110124
1
EPA
1633
Surrogate: 13C8-PFOA
95.4%
40-130
05110124
1
EPA
1633
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is allowed, except in its entirety. Page 6 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Sample Results
(Continued)
Sample: MW-2 (Continued)
24DO199-02 (Water)
Date Prep
Analyte Result/Qual PQL MDL Units Analyzed DF Method Batch
Per- and Polyfluoroalkyl Substances
(Continued)
Surrogate: 13C9-PFNA
94.9%
40-130
05110124
1
EPA 1633
Surrogate: 13C6-PFDA
93.8%
40-130
05110124
1
EPA 1633
Surrogate: 13C7-PFUnA
89.4%
30-130
05110124
1
EPA 1633
Surrogate: 13C2-PFDOA
89.4%
10-130
05110124
1
EPA 1633
Surrogate: 13C2-PFTEDA
93.8%
10-130
05110124
1
EPA 1633
Surrogate: 13C3-PFBS
95.2%
40-135
05110124
1
EPA 1633
Surrogate: 13C3-PFHXS
97.9%
40-130
05110124
1
EPA 1633
Surrogate: 13C8-PF05
77.5%
40-130
05110124
1
EPA 1633
Surrogate: 13C24-2FT5
137916
40-200
05110124
1
EPA 1633
Surrogate: 13C2-6.2FTS
93.2%
40-200
05110124
1
EPA 1633
Surrogate: 13C2-8.2FTS
84.5%
40-300
05110124
1
EPA 1633
Surrogate: 13C8-PFOSA
48.8%
40-130
05110124
1
EPA 1633
Surrogate: D3-NMEF05A
15.1 %
10-130
05110124
1
EPA 1633
Surrogate: D5-NETFOSA
11.3910
10-130
05110124
1
EPA 1633
Surrogate: D3-NMEFOSAA
73.2%
40-170
05110124
1
EPA 1633
Surrogate: D5-NETFOSAA
68.6%
25-135
05110124
1
EPA 1633
Surrogate: D7-NMEF05E
37.9%
10-130
05110124
1
EPA 1633
Surrogate: D9-NETFOSE
34.5%
10-130
05110124
1
EPA 1633
Surrogate: 13C3-HFPO-DA
88.3%
40-130
05110124
1
EPA 1633
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is alloweo,except in its entirety. Page 7 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Sample Results
(Continued)
Sample: MW-3
24DO199-03 (Water)
Date Prep
Analyte Result/Qual PQL MDL Units Analyzed DF Method Batch
Per- and Polyfluoroalkyl Substances
PFBA
52
1.4
0.18
ng/L
05/10/24
1
EPA
1633
BDD0558
PFPeA
65
0.70
0.057
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHxA
250
3.5
0.48
ng/L
05/10/24
10
EPA
1633
BDD0558
PFHpA
80
0.35
0.036
ng/L
05/10/24
1
EPA
1633
BDD0558
PFOA
190
MI4
3.5
1.3
ng/L
05/10/24
10
EPA
1633
BDD0558
PFNA
0.94
0.35
0.071
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDA
ND
0.35
0.088
ng/L
05/10/24
1
EPA
1633
BDD0558
PFUnA
ND
0.35
0.14
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDoA
ND
0.35
0.098
ng/L
05/10/24
1
EPA
1633
BDD0558
PFTrDA
ND
0.35
0.18
ng/L
05/10/24
1
EPA
1633
BDD0558
PFTeDA
ND
0.35
0.17
ng/L
05/10/24
1
EPA
1633
BDD0558
PFBS
55
0.35
0.032
ng/L
05/10/24
1
EPA
1633
BDD0558
PFPeS
21
0.35
0.055
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHxS
25
MI4
0.35
0.028
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHpS
2.1
0.35
0.045
ng/L
05/10/24
1
EPA
1633
BDD0558
PFOS
54
0.35
0.055
ng/L
05/10/24
1
EPA
1633
BDD0558
PFNS
ND
0.35
0.11
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDS
ND
0.35
0.13
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDoS
ND
0.35
0.11
ng/L
05/10/24
1
EPA
1633
BDD0558
4:2FTS
ND
1.4
0.25
ng/L
05/10/24
1
EPA
1633
BDD0558
6:2FTS
0.30
J
1.4
0.27
ng/L
05/10/24
1
EPA
1633
BDD0558
8:2FTS
ND
1.4
0.072
ng/L
05/10/24
1
EPA
1633
BDD0558
PFOSA
0.58
0.35
0.091
ng/L
05/10/24
1
EPA
1633
BDD0558
NMeFOSA
ND
1.4
0.41
ng/L
05/10/24
1
EPA
1633
BDD0558
NEtFOSA
ND
1.4
0.36
ng/L
05/10/24
1
EPA
1633
BDD0558
NMeFOSAA
2.3
0.35
0.092
ng/L
05/10/24
1
EPA
1633
BDD0558
NEtFOSAA
ND
0.35
0.10
ng/L
05/10/24
1
EPA
1633
BDD0558
NMeFOSE
ND
1.4
0.88
ng/L
05/10/24
1
EPA
1633
BDD0558
NEtFOSE
ND
1.4
0.91
ng/L
05/10/24
1
EPA
1633
BDD0558
HFPO-DA
0.17
J
0.70
0.15
ng/L
05/10/24
1
EPA
1633
BDD0558
ADONA
ND
0.70
0.11
ng/L
05/10/24
1
EPA
1633
BDD0558
PFEESA
ND
0.70
0.095
ng/L
05/10/24
1
EPA
1633
BDD0558
PFMPA
0.13
J
0.70
0.047
ng/L
05/10/24
1
EPA
1633
BDD0558
PFM BA
0.19
J
0.70
0.079
ng/L
05/10/24
1
EPA
1633
BDD0558
NFDHA
ND
0.70
0.26
ng/L
05/10/24
1
EPA
1633
BDD0558
9CI-PF30NS
ND
0.70
0.18
ng/L
05/10/24
1
EPA
1633
BDD0558
11CI-PF30UDS
ND
0.70
0.18
ng/L
05/10/24
1
EPA
1633
BDD0558
3:3FTCA
ND
1.4
0.50
ng/L
05/10/24
1
EPA
1633
BDD0558
5:3FTCA
ND
1.4
0.39
ng/L
05/10/24
1
EPA
1633
BDD0558
7:3FTCA
ND
1.4
0.48
ng/L
05/10/24
1
EPA
1633
BDD0558
- - - - - - - - - - - - - - - - - - -
Surrogate: 13C4-PFBA
- - - - -
88.2 %
- - -
- - - -
5-130
- - - -
- - - - -
- - - - -
05110124
- - -
1
- -
EPA
- - -
1633
- - - - - -
Surrogate: 13C5-PFPPA
88.9%
40-130
05110124
1
EPA
1633
Surrogate: 13C5-PFHXA
87.6%
40-130
05110124
1
EPA
1633
Surrogate: 13C4-PFMPA
99.9%
40-130
05110124
1
EPA
1633
Surrogate: 13C8-PFOA
99.0%
40-130
05110124
1
EPA
1633
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is allowed, except in its entirety. Page 8 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Sample Results
(Continued)
Sample: MW-3 (Continued)
24DO199-03 (Water)
Date Prep
Analyte Result/Qual PQL MDL Units Analyzed DF Method Batch
Per- and Polyfluoroalkyl Substances
(Continued)
Surrogate: 13C9-PFNA
90.5%
40-130
05110124
1
EPA 1633
Surrogate: 13C6-PFDA
91.2%
40-130
05110124
1
EPA 1633
Surrogate: 13C7-PFUnA
90.1 %
30-130
05110124
1
EPA 1633
Surrogate: 13C2-PFDOA
78.5%
10-130
05110124
1
EPA 1633
Surrogate: 13C2-PFTEDA
82.2%
10-130
05110124
1
EPA 1633
Surrogate: 13C3-PFBS
92.8%
40-135
05110124
1
EPA 1633
Surrogate: 13C3-PFHXS
89.8%
40-130
05110124
1
EPA 1633
Surrogate: 13C8-PF05
84.1 %
40-130
05110124
1
EPA 1633
Surrogate: 13C24-2FT5
116%
40-200
05110124
1
EPA 1633
Surrogate: 13C2-6.2FTS
81.2%
40-200
05110124
1
EPA 1633
Surrogate: 13C2-8.2FTS
81.0%
40-300
05110124
1
EPA 1633
Surrogate: 13C8-PFOSA
45.8%
40-130
05110124
1
EPA 1633
Surrogate: D3-NMEF05A
15.1 %
10-130
05110124
1
EPA 1633
Surrogate: D5-NETFOSA
13.6910
10-130
05110124
1
EPA 1633
Surrogate: D3-NMEFOSAA
72.8910
40-170
05110124
1
EPA 1633
Surrogate: D5-NETFOSAA
64.4%
25-135
05110124
1
EPA 1633
Surrogate: D7-NMEF05E
36.2%
10-130
05110124
1
EPA 1633
Surrogate: D9-NETFOSE
30.9%
10-130
05110124
1
EPA 1633
Surrogate: 13C3-HFPO-DA
96.7%
40-130
05110124
1
EPA 1633
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is alloweo,except in its entirety. Page 9 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Sample Results
(Continued)
Sample: MW-4
24DO199-04 (Water)
Date Prep
Analyte Result/Qual PQL MDL Units Analyzed DF Method Batch
Per- and Polyfluoroalkyl Substances
PFBA
2000
16
2.0
ng/L
05/10/24
1
EPA
1633
BDD0558
PFPeA
5900
78
6.3
ng/L
05/10/24
10
EPA
1633
BDD0558
PFHxA
18000
39
5.3
ng/L
05/10/24
10
EPA
1633
BDD0558
PFHpA
22000
AE
390
40
ng/L
05/14/24
100
EPA
1633
BDD0558
PFOA
70000
AE
390
150
ng/L
05/14/24
100
EPA
1633
BDD0558
PFNA
360
3.9
0.79
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDA
8.0
3.9
0.98
ng/L
05/10/24
1
EPA
1633
BDD0558
PFUnA
1.6
J
3.9
1.6
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDoA
ND
3.9
1.1
ng/L
05/10/24
1
EPA
1633
BDD0558
PFTrDA
ND
3.9
2.0
ng/L
05/10/24
1
EPA
1633
BDD0558
PFTeDA
ND
3.9
1.9
ng/L
05/10/24
1
EPA
1633
BDD0558
PFBS
10000
39
3.6
ng/L
05/10/24
10
EPA
1633
BDD0558
PFPeS
10000
39
6.1
ng/L
05/10/24
10
EPA
1633
BDD0558
PFHxS
16000
39
3.1
ng/L
05/10/24
10
EPA
1633
BDD0558
PFHpS
1500
3.9
0.50
ng/L
05/10/24
1
EPA
1633
BDD0558
PFOS
10000
39
6.2
ng/L
05/10/24
10
EPA
1633
BDD0558
PFNS
ND
MI6,
3.9
1.2
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDS
ND
3.9
1.5
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDoS
ND
3.9
1.2
ng/L
05/10/24
1
EPA
1633
BDD0558
4:2FTS
ND
16
2.8
ng/L
05/10/24
1
EPA
1633
BDD0558
6:2FTS
5.5
J
16
3.0
ng/L
05/10/24
1
EPA
1633
BDD0558
8:2FTS
ND
16
0.80
ng/L
05/10/24
1
EPA
1633
BDD0558
PFOSA
44
3.9
1.0
ng/L
05/10/24
1
EPA
1633
BDD0558
NMeFOSA
ND
16
4.6
ng/L
05/10/24
1
EPA
1633
BDD0558
NEtFOSA
ND
16
4.0
ng/L
05/10/24
1
EPA
1633
BDD0558
NMeFOSAA
78
3.9
1.0
ng/L
05/10/24
1
EPA
1633
BDD0558
NEtFOSAA
4.6
MI4
3.9
1.1
ng/L
05/10/24
1
EPA
1633
BDD0558
NMeFOSE
ND
16
9.8
ng/L
05/10/24
1
EPA
1633
BDD0558
NEtFOSE
ND
16
10
ng/L
05/10/24
1
EPA
1633
BDD0558
HFPO-DA
7.0
J
7.8
1.7
ng/L
05/10/24
1
EPA
1633
BDD0558
ADONA
ND
7.8
1.2
ng/L
05/10/24
1
EPA
1633
BDD0558
PFEESA
ND
7.8
1.1
ng/L
05/10/24
1
EPA
1633
BDD0558
PFMPA
4.9
J
7.8
0.52
ng/L
05/10/24
1
EPA
1633
BDD0558
PFMBA
11
7.8
0.88
ng/L
05/10/24
1
EPA
1633
BDD0558
NFDHA
ND
7.8
2.9
ng/L
05/10/24
1
EPA
1633
BDD0558
9CI-PF30NS
ND
7.8
2.0
ng/L
05/10/24
1
EPA
1633
BDD0558
11CI-PF30UDS
ND
7.8
2.0
ng/L
05/10/24
1
EPA
1633
BDD0558
3:3FTCA
ND
16
5.6
ng/L
05/10/24
1
EPA
1633
BDD0558
5:3FTCA
ND
16
4.3
ng/L
05/10/24
1
EPA
1633
BDD0558
7:3FTCA
ND
16
5.4
ng/L
05/10/24
1
EPA
1633
BDD0558
- - - - - - - - - - - - - - - - - - -
Surrogate: 13C4-PFBA
- - - - -
97.6%
- - -
- - - - -
5-130
- - -
- - - - -
- - - - -
05110124
- - -
1
- -
EPA
- - -
1633
- - - - - -
Surrogate: 13C5-PFPPA
81.5%
40-130
05110124
1
EPA
1633
Surrogate: 13C5-PFHXA
72.9%
40-130
05110124
1
EPA
1633
Surrogate: 13C4-PFMPA
73.1 %
40-130
05110124
1
EPA
1633
Surrogate: 13C8-PFOA
93.7%
40-130
05110124
1
EPA
1633
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is allowed, except in its entirety. Page 10 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Sample Results
(Continued)
Sample: MW-4 (Continued)
24DO199-04 (Water)
Date Prep
Analyte Result/Qual PQL MDL Units Analyzed DF Method Batch
Per- and Polyfluoroalkyl Substances
(Continued)
Surrogate: 13C9-PFNA
92,9%
40-130
05110124
1
EPA 1633
Surrogate: 13C6-PFDA
94.5%
40-130
05110124
1
EPA 1633
Surrogate: 13C7-PFUnA
102%
30-130
05110124
1
EPA 1633
Surrogate: 13C2-PFDOA
104%
10-130
05110124
1
EPA 1633
Surrogate: 13C2-PFTEDA
109%
10-130
05110124
1
EPA 1633
Surrogate: 13C3-PFBS
91.2%
40-135
05110124
1
EPA 1633
Surrogate: 13C3-PFHXS
88.2%
40-130
05110124
1
EPA 1633
Surrogate: 13C8-PF05
93.0%
40-130
05110124
1
EPA 1633
Surrogate: 13C2-4:2FT5
155910
40-200
05110124
1
EPA 1633
Surrogate: 13C2-6.2FTS
135%
40-200
05110124
1
EPA 1633
Surrogate: 13C2-8.2FTS
120%
40-300
05110124
1
EPA 1633
Surrogate: 130-PFOSA
67.4%
40-130
05110124
1
EPA 1633
Surrogate: D3-NMEF05A
20.8%
10-130
05110124
1
EPA 1633
Surrogate: D5-NETFOSA
19.7910
10-130
05110124
1
EPA 1633
Surrogate: D3-NMEFOSAA
104 %
40-170
05110124
1
EPA 1633
Surrogate: D5-NETFOSAA
114%
25-135
05110124
1
EPA 1633
Surrogate: D7-NMEF05E
66.7%
10-130
05110124
1
EPA 1633
Surrogate: D9-NETFOSE
60.5%
10-130
05110124
1
EPA 1633
Surrogate: 13C3-HFPO-DA
108%
40-130
05110124
1
EPA 1633
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is alloweo,except in its entirety. Page 11 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Sample Results
(Continued)
Sample: MW-5
24DO199-05 (Water)
Date Prep
Analyte Result/Qual PQL MDL Units Analyzed DF Method Batch
Per- and Polyfluoroalkyl Substances
PFBA
360
16
2.0
ng/L
05/10/24
1
EPA
1633
BDD0558
PFPeA
810
7.8
0.64
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHxA
1800
3.9
0.54
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHpA
2000
39
4.0
ng/L
05/10/24
10
EPA
1633
BDD0558
PFOA
4000 MI4
39
15
ng/L
05/10/24
10
EPA
1633
BDD0558
PFNA
14
3.9
0.80
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDA
ND
3.9
0.99
ng/L
05/10/24
1
EPA
1633
BDD0558
PFUnA
ND
3.9
1.6
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDoA
ND
3.9
1.1
ng/L
05/10/24
1
EPA
1633
BDD0558
PFTrDA
ND
3.9
2.0
ng/L
05/10/24
1
EPA
1633
BDD0558
PFTeDA
ND
3.9
1.9
ng/L
05/10/24
1
EPA
1633
BDD0558
PFBS
1100
3.9
0.36
ng/L
05/10/24
1
EPA
1633
BDD0558
PFPeS
500
3.9
0.61
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHxS
450
3.9
0.31
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHpS
22
3.9
0.50
ng/L
05/10/24
1
EPA
1633
BDD0558
PFOS
190
3.9
0.62
ng/L
05/10/24
1
EPA
1633
BDD0558
PFNS
ND
3.9
1.2
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDS
ND
3.9
1.5
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDoS
ND
3.9
1.2
ng/L
05/10/24
1
EPA
1633
BDD0558
4:2FTS
ND
16
2.8
ng/L
05/10/24
1
EPA
1633
BDD0558
6:2FTS
ND
16
3.1
ng/L
05/10/24
1
EPA
1633
BDD0558
8:2FTS
ND
16
0.80
ng/L
05/10/24
1
EPA
1633
BDD0558
PFOSA
4.3 MI4
3.9
1.0
ng/L
05/10/24
1
EPA
1633
BDD0558
NMeFOSA
ND
16
4.6
ng/L
05/10/24
1
EPA
1633
BDD0558
NEtFOSA
ND
16
4.0
ng/L
05/10/24
1
EPA
1633
BDD0558
NMeFOSAA
13
3.9
1.0
ng/L
05/10/24
1
EPA
1633
BDD0558
NEtFOSAA
ND
3.9
1.1
ng/L
05/10/24
1
EPA
1633
BDD0558
NMeFOSE
ND
16
9.9
ng/L
05/10/24
1
EPA
1633
BDD0558
NEtFOSE
ND
16
10
ng/L
05/10/24
1
EPA
1633
BDD0558
HFPO-DA
ND
7.8
1.7
ng/L
05/10/24
1
EPA
1633
BDD0558
ADONA
ND
7.8
1.2
ng/L
05/10/24
1
EPA
1633
BDD0558
PFEESA
ND
7.8
1.1
ng/L
05/10/24
1
EPA
1633
BDD0558
PFMPA
ND
7.8
0.53
ng/L
05/10/24
1
EPA
1633
BDD0558
PFMBA
ND
7.8
0.89
ng/L
05/10/24
1
EPA
1633
BDD0558
NFDHA
ND
7.8
2.9
ng/L
05/10/24
1
EPA
1633
BDD0558
9CI-PF30NS
ND
7.8
2.0
ng/L
05/10/24
1
EPA
1633
BDD0558
11CI-PF30UDS
ND
7.8
2.0
ng/L
05/10/24
1
EPA
1633
BDD0558
3:3FTCA
ND
16
5.6
ng/L
05/10/24
1
EPA
1633
BDD0558
5:3FTCA
ND
16
4.3
ng/L
05/10/24
1
EPA
1633
BDD0558
7:3FTCA
ND
16
5.4
ng/L
05/10/24
1
EPA
1633
BDD0558
- - - - - - - - - - - - - - - - - - -
Surrogate: 13C4-PFBA
- - - - - - - -
86.4 %
- - - - -
5-130
- - -
- - - - -
- - - - -
05110124
- - -
1
- -
EPA
- - -
1633
- - - - - -
Surrogate: 13C5-PFPPA
83.6%
40-130
05110124
1
EPA
1633
Surrogate: 13C5-PFHXA
89.2%
40-130
05110124
1
EPA
1633
Surrogate: 13C4-PFMPA
93.4%
40-130
05110124
1
EPA
1633
Surrogate: 13C8-PFOA
96.9%
40-130
05110124
1
EPA
1633
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is allowed, except in its entirety. Page 12 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Sample Results
(Continued)
Sample: MW-5 (Continued)
24DO199-05 (Water)
Date Prep
Analyte Result/Qual PQL MDL Units Analyzed DF Method Batch
Per- and Polyfluoroalkyl Substances
(Continued)
Surrogate: 13C9-PFNA
92,6%
40-130
05110124
1
EPA 1633
Surrogate: 13C6-PFDA
96.9%
40-130
05110124
1
EPA 1633
Surrogate: 13C7-PFUnA
96.1 %
30-130
05110124
1
EPA 1633
Surrogate: 13C2-PFDOA
95.5%
10-130
05110124
1
EPA 1633
Surrogate: 13C2-PFTEDA
100%
10-130
05110124
1
EPA 1633
Surrogate: 13C3-PFBS
85.4%
40-135
05110124
1
EPA 1633
Surrogate: 13C3-PFHXS
93.3%
40-130
05110124
1
EPA 1633
Surrogate: 13C8-PF05
93.9%
40-130
05110124
1
EPA 1633
Surrogate: 13C24-2FT5
101 %
40-200
05110124
1
EPA 1633
Surrogate: 13C2-6.2FTS
90.9%
40-200
05110124
1
EPA 1633
Surrogate: 13C2-8.2FTS
90.9%
40-300
05110124
1
EPA 1633
Surrogate: 13C8-PFOSA
34.5% S1
40-130
05110124
1
EPA 1633
Surrogate: D3-NMEF05A
9.01 % Sl
10-130
05110124
1
EPA 1633
Surrogate: D5-NETF05A
6.60% S1
10-130
05110124
1
EPA 1633
Surrogate: D3-NMEFOSAA
89.5%
40-170
05110124
1
EPA 1633
Surrogate: D5-NETFOSAA
87.3%
25-135
05110124
1
EPA 1633
Surrogate: D7-NMEFOSE
28.6%
10-130
05110124
1
EPA 1633
Surrogate: D9-NETF05E
28.5%
10-130
05110124
1
EPA 1633
Surrogate: 13C3-HFPO-DA
92.3%
40-130
05110124
1
EPA 1633
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is alloweo,except in its entirety. Page 13 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Sample Results
(Continued)
Sample: MW-6
24DO199-06 (Water)
Date Prep
Analyte Result/Qual PQL MDL Units Analyzed DF Method Batch
Per- and Polyfluoroalkyl Substances
PFBA
90
17
2.2
ng/L
05/10/24
1
EPA
1633
BDD0558
PFPeA
100
8.5
0.69
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHxA
83
4.3
0.58
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHpA
31
4.3
0.44
ng/L
05/10/24
1
EPA
1633
BDD0558
PFOA
200
MI4
4.3
1.6
ng/L
05/10/24
1
EPA
1633
BDD0558
PFNA
10
4.3
0.87
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDA
3.9
J
4.3
1.1
ng/L
05/10/24
1
EPA
1633
BDD0558
PFUnA
ND
4.3
1.7
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDoA
ND
4.3
1.2
ng/L
05/10/24
1
EPA
1633
BDD0558
PFTrDA
ND
4.3
2.2
ng/L
05/10/24
1
EPA
1633
BDD0558
PFTeDA
ND
4.3
2.1
ng/L
05/10/24
1
EPA
1633
BDD0558
PFBS
740
4.3
0.39
ng/L
05/10/24
1
EPA
1633
BDD0558
PFPeS
190
4.3
0.67
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHxS
190
MI4
4.3
0.34
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHpS
30
4.3
0.55
ng/L
05/10/24
1
EPA
1633
BDD0558
PFOS
1100
4.3
0.68
ng/L
05/10/24
1
EPA
1633
BDD0558
PFNS
ND
4.3
1.3
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDS
ND
4.3
1.6
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDoS
ND
4.3
1.3
ng/L
05/10/24
1
EPA
1633
BDD0558
4:2FTS
ND
17
3.1
ng/L
05/10/24
1
EPA
1633
BDD0558
6:2FTS
ND
17
3.3
ng/L
05/10/24
1
EPA
1633
BDD0558
8:2FTS
ND
17
0.87
ng/L
05/10/24
1
EPA
1633
BDD0558
PFOSA
2.3
MI4,3
4.3
1.1
ng/L
05/10/24
1
EPA
1633
BDD0558
NMeFOSA
ND
17
5.0
ng/L
05/10/24
1
EPA
1633
BDD0558
NEtFOSA
ND
17
4.4
ng/L
05/10/24
1
EPA
1633
BDD0558
NMeFOSAA
ND
4.3
1.1
ng/L
05/10/24
1
EPA
1633
BDD0558
NEtFOSAA
ND
4.3
1.2
ng/L
05/10/24
1
EPA
1633
BDD0558
NMeFOSE
ND
17
11
ng/L
05/10/24
1
EPA
1633
BDD0558
NEtFOSE
ND
17
11
ng/L
05/10/24
1
EPA
1633
BDD0558
HFPO-DA
ND
8.5
1.9
ng/L
05/10/24
1
EPA
1633
BDD0558
ADONA
ND
8.5
1.3
ng/L
05/10/24
1
EPA
1633
BDD0558
PFEESA
ND
8.5
1.2
ng/L
05/10/24
1
EPA
1633
BDD0558
PFMPA
ND
8.5
0.57
ng/L
05/10/24
1
EPA
1633
BDD0558
PFMBA
ND
8.5
0.97
ng/L
05/10/24
1
EPA
1633
BDD0558
NFDHA
ND
8.5
3.2
ng/L
05/10/24
1
EPA
1633
BDD0558
9CI-PF30NS
ND
8.5
2.2
ng/L
05/10/24
1
EPA
1633
BDD0558
11CI-PF30UDS
ND
8.5
2.2
ng/L
05/10/24
1
EPA
1633
BDD0558
3:3FTCA
ND
17
6.1
ng/L
05/10/24
1
EPA
1633
BDD0558
5:3FTCA
ND
17
4.7
ng/L
05/10/24
1
EPA
1633
BDD0558
7:3FTCA
ND
17
5.9
ng/L
05/10/24
1
EPA
1633
BDD0558
- - - - - - - - - - - - - - - - - - -
Surrogate: 13C4-PFBA
- - - - -
91.9%
- - -
- - - - -
5-130
- - -
- - - - -
- - - - -
05110124
- - -
1
- -
EPA
- - -
1633
- - - - - -
Surrogate: 13C5-PFPPA
81.9%
40-130
05110124
1
EPA
1633
Surrogate: 13C5-PFHXA
89.3%
40-130
05110124
1
EPA
1633
Surrogate: 13C4-PFMPA
87.8%
40-130
05110124
1
EPA
1633
Surrogate: 13C8-PFOA
93.1 %
40-130
05110124
1
EPA
1633
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is allowed, except in its entirety. Page 14 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Sample Results
(Continued)
Sample: MW-6 (Continued)
24DO199-06 (Water)
Date Prep
Analyte Result/Qual PQL MDL Units Analyzed DF Method Batch
Per- and Polyfluoroalkyl Substances
(Continued)
Surrogate: 13C9-PFNA
89.1 %
40-130
05110124
1
EPA 1633
Surrogate: 13C6-PFDA
86.2%
40-130
05110124
1
EPA 1633
Surrogate: 13C7-PFUnA
75.6%
30-130
05110124
1
EPA 1633
Surrogate: 13C2-PFDOA
72.0%
10-130
05110124
1
EPA 1633
Surrogate: 13C2-PFTEDA
51.3%
10-130
05110124
1
EPA 1633
Surrogate: 13C3-PFBS
86.0%
40-135
05110124
1
EPA 1633
Surrogate: 13C3-PFHXS
92.2%
40-130
05110124
1
EPA 1633
Surrogate: 13C8-PF05
80.8%
40-130
05110124
1
EPA 1633
Surrogate: 13C24-2FT5
130%
40-200
05110124
1
EPA 1633
Surrogate: 13C2-6.2FTS
94.3%
40-200
05110124
1
EPA 1633
Surrogate: 13C2-8.2FTS
79.6%
40-300
05110124
1
EPA 1633
Surrogate: 13C8-PFOSA
45.6%
40-130
05110124
1
EPA 1633
Surrogate: D3-NMEF05A
29.4%
10-130
05110124
1
EPA 1633
Surrogate: D5-NETFOSA
25.391b
10-130
05110124
1
EPA 1633
Surrogate: D3-NMEFOSAA
66.6910
40-170
05110124
1
EPA 1633
Surrogate: D5-NETFOSAA
62.6%
25-135
05110124
1
EPA 1633
Surrogate: D7-NMEF05E
39.4%
10-130
05110124
1
EPA 1633
Surrogate: D9-NETFOSE
28.9%
10-130
05110124
1
EPA 1633
Surrogate: 13C3-HFPO-DA
84.8%
40-130
05110124
1
EPA 1633
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is alloweo,except in its entirety. Page 15 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Sample Results
(Continued)
Sample: MW-7
24DO199-07 (Water)
Date Prep
Analyte Result/Qual PQL MDL Units Analyzed DF Method Batch
Per- and Polyfluoroalkyl Substances
PFBA
32
1.4
0.19
ng/L
05/10/24
1
EPA
1633
BDD0558
PFPeA
55
0.72
0.058
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHxA
150
3.6
0.49
ng/L
05/10/24
10
EPA
1633
BDD0558
PFHpA
130
0.36
0.037
ng/L
05/10/24
1
EPA
1633
BDD0558
PFOA
530
MI4
3.6
1.4
ng/L
05/10/24
10
EPA
1633
BDD0558
PFNA
8.4
0.36
0.073
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDA
0.82
0.36
0.091
ng/L
05/10/24
1
EPA
1633
BDD0558
PFUnA
ND
0.36
0.14
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDoA
ND
0.36
0.10
ng/L
05/10/24
1
EPA
1633
BDD0558
PFTrDA
ND
0.36
0.18
ng/L
05/10/24
1
EPA
1633
BDD0558
PFTeDA
ND
0.36
0.18
ng/L
05/10/24
1
EPA
1633
BDD0558
PFBS
130
0.36
0.033
ng/L
05/10/24
1
EPA
1633
BDD0558
PFPeS
69
0.36
0.056
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHxS
110
0.36
0.028
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHpS
20
0.36
0.046
ng/L
05/10/24
1
EPA
1633
BDD0558
PFOS
600
3.6
0.57
ng/L
05/10/24
10
EPA
1633
BDD0558
PFNS
ND
MI6,
0.36
0.11
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDS
ND
0.36
0.14
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDoS
ND
0.36
0.11
ng/L
05/10/24
1
EPA
1633
BDD0558
4:2FTS
ND
1.4
0.26
ng/L
05/10/24
1
EPA
1633
BDD0558
6:2FTS
ND
1.4
0.28
ng/L
05/10/24
1
EPA
1633
BDD0558
8:2FTS
ND
1.4
0.073
ng/L
05/10/24
1
EPA
1633
BDD0558
PFOSA
7.7
0.36
0.093
ng/L
05/10/24
1
EPA
1633
BDD0558
NMeFOSA
ND
1.4
0.42
ng/L
05/10/24
1
EPA
1633
BDD0558
NEtFOSA
ND
1.4
0.37
ng/L
05/10/24
1
EPA
1633
BDD0558
NMeFOSAA
7.4
0.36
0.095
ng/L
05/10/24
1
EPA
1633
BDD0558
NEtFOSAA
0.36
IR2, MI5
0.36
0.10
ng/L
05/10/24
1
EPA
1633
BDD0558
NMeFOSE
ND
1.4
0.90
ng/L
05/10/24
1
EPA
1633
BDD0558
NEtFOSE
ND
1.4
0.94
ng/L
05/10/24
1
EPA
1633
BDD0558
HFPO-DA
0.28
J
0.72
0.16
ng/L
05/10/24
1
EPA
1633
BDD0558
ADONA
ND
0.72
0.11
ng/L
05/10/24
1
EPA
1633
BDD0558
PFEESA
ND
0.72
0.098
ng/L
05/10/24
1
EPA
1633
BDD0558
PFMPA
ND
0.72
0.048
ng/L
05/10/24
1
EPA
1633
BDD0558
PFMBA
ND
0.72
0.081
ng/L
05/10/24
1
EPA
1633
BDD0558
NFDHA
ND
0.72
0.27
ng/L
05/10/24
1
EPA
1633
BDD0558
9CI-PF30NS
ND
0.72
0.19
ng/L
05/10/24
1
EPA
1633
BDD0558
11CI-PF30UDS
ND
0.72
0.18
ng/L
05/10/24
1
EPA
1633
BDD0558
3:3FTCA
ND
1.4
0.51
ng/L
05/10/24
1
EPA
1633
BDD0558
5:3FTCA
ND
1.4
0.40
ng/L
05/10/24
1
EPA
1633
BDD0558
7:3FTCA
ND
1.4
0.50
ng/L
05/10/24
1
EPA
1633
BDD0558
- - - - - - - - - - - - - - - - - - -
Surrogate: 13C4-PFBA
- - - -
89.6%
- - - -
- - - -
5-130
- - - -
- - - - -
- - - - -
05110124
- - -
1
- -
EPA
- - -
1633
- - - - - -
Surrogate: 13C5-PFPPA
84.1 %
40-130
05110124
1
EPA
1633
Surrogate: 13C5-PFHXA
92.5%
40-130
05110124
1
EPA
1633
Surrogate: 13C4-PFMPA
98.7%
40-130
05110124
1
EPA
1633
Surrogate: 13C8-PFOA
95.6%
40-130
05110124
1
EPA
1633
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is allowed, except in its entirety. Page 16 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Sample Results
(Continued)
Sample: MW-7 (Continued)
24DO199-07 (Water)
Date Prep
Analyte Result/Qual PQL MDL Units Analyzed DF Method Batch
Per- and Polyfluoroalkyl Substances
(Continued)
Surrogate: 13C9-PFNA
95.3%
40-130
05110124
1
EPA 1633
Surrogate: 13C6-PFDA
95.1 %
40-130
05110124
1
EPA 1633
Surrogate: 13C7-PFUnA
96.4%
30-130
05110124
1
EPA 1633
Surrogate: 13C2-PFDOA
88.2%
10-130
05110124
1
EPA 1633
Surrogate: 13C2-PFTEDA
87.6%
10-130
05110124
1
EPA 1633
Surrogate: 13C3-PFBS
95.3%
40-135
05110124
1
EPA 1633
Surrogate: 13C3-PFHXS
102%
40-130
05110124
1
EPA 1633
Surrogate: 13C8-PF05
90.4%
40-130
05110124
1
EPA 1633
Surrogate: 13C24-2FT5
136%
40-200
05110124
1
EPA 1633
Surrogate: 13C2-6.2FTS
106%
40-200
05110124
1
EPA 1633
Surrogate: 13C2-8.2FTS
102%
40-300
05110124
1
EPA 1633
Surrogate: 13C8-PFOSA
77.4%
40-130
05110124
1
EPA 1633
Surrogate: D3-NMEF05A
25.1 %
10-130
05110124
1
EPA 1633
Surrogate: D5-NETFOSA
25.291b
10-130
05110124
1
EPA 1633
Surrogate: D3-NMEFOSAA
97.6910
40-170
05110124
1
EPA 1633
Surrogate: D5-NETFOSAA
105%
25-135
05110124
1
EPA 1633
Surrogate: D7-NMEF05E
55.7%
10-130
05110124
1
EPA 1633
Surrogate: D9-NETFOSE
46.7%
10-130
05110124
1
EPA 1633
Surrogate: 13C3-HFPO-DA
92.3%
40-130
05110124
1
EPA 1633
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is alloweo,except in its entirety. Page 17 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Sample Results
(Continued)
Sample: MW-7113
24DO199-08 (Water)
Date Prep
Analyte Result/Qual PQL MDL Units Analyzed DF Method Batch
Per- and Polyfluoroalkyl Substances
PFBA
14
1.4
0.19
ng/L
05/10/24
1
EPA
1633
BDD0558
PFPeA
16
0.72
0.058
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHxA
68
0.36
0.049
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHpA
27
0.36
0.037
ng/L
05/10/24
1
EPA
1633
BDD0558
PFOA
76 MI4
0.36
0.14
ng/L
05/10/24
1
EPA
1633
BDD0558
PFNA
0.82
0.36
0.073
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDA
ND
0.36
0.091
ng/L
05/10/24
1
EPA
1633
BDD0558
PFUnA
ND
0.36
0.14
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDoA
ND
0.36
0.10
ng/L
05/10/24
1
EPA
1633
BDD0558
PFTrDA
ND
0.36
0.18
ng/L
05/10/24
1
EPA
1633
BDD0558
PFTeDA
ND
0.36
0.18
ng/L
05/10/24
1
EPA
1633
BDD0558
PFBS
31
0.36
0.033
ng/L
05/10/24
1
EPA
1633
BDD0558
PFPeS
20
0.36
0.056
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHxS
20
0.36
0.028
ng/L
05/10/24
1
EPA
1633
BDD0558
PFHpS
1.8
0.36
0.046
ng/L
05/10/24
1
EPA
1633
BDD0558
PFOS
130
0.36
0.057
ng/L
05/10/24
1
EPA
1633
BDD0558
PFNS
ND
0.36
0.11
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDS
ND
0.36
0.14
ng/L
05/10/24
1
EPA
1633
BDD0558
PFDoS
ND
0.36
0.11
ng/L
05/10/24
1
EPA
1633
BDD0558
4:2FTS
ND
1.4
0.26
ng/L
05/10/24
1
EPA
1633
BDD0558
6:2FTS
ND
1.4
0.28
ng/L
05/10/24
1
EPA
1633
BDD0558
8:2FTS
ND
1.4
0.074
ng/L
05/10/24
1
EPA
1633
BDD0558
PFOSA
2.2
0.36
0.093
ng/L
05/10/24
1
EPA
1633
BDD0558
NMeFOSA
ND
1.4
0.42
ng/L
05/10/24
1
EPA
1633
BDD0558
NEtFOSA
ND
1.4
0.37
ng/L
05/10/24
1
EPA
1633
BDD0558
NMeFOSAA
ND
0.36
0.095
ng/L
05/10/24
1
EPA
1633
BDD0558
NEtFOSAA
ND
0.36
0.10
ng/L
05/10/24
1
EPA
1633
BDD0558
NMeFOSE
ND
1.4
0.91
ng/L
05/10/24
1
EPA
1633
BDD0558
NEtFOSE
ND
1.4
0.94
ng/L
05/10/24
1
EPA
1633
BDD0558
HFPO-DA
ND
0.72
0.16
ng/L
05/10/24
1
EPA
1633
BDD0558
ADONA
ND
0.72
0.11
ng/L
05/10/24
1
EPA
1633
BDD0558
PFEESA
ND
0.72
0.098
ng/L
05/10/24
1
EPA
1633
BDD0558
PFMPA
ND
0.72
0.048
ng/L
05/10/24
1
EPA
1633
BDD0558
PFMBA
ND
0.72
0.081
ng/L
05/10/24
1
EPA
1633
BDD0558
NFDHA
ND
0.72
0.27
ng/L
05/10/24
1
EPA
1633
BDD0558
9CI-PF30NS
ND
0.72
0.19
ng/L
05/10/24
1
EPA
1633
BDD0558
11CI-PF30UDS
ND
0.72
0.18
ng/L
05/10/24
1
EPA
1633
BDD0558
3:3FTCA
ND
1.4
0.52
ng/L
05/10/24
1
EPA
1633
BDD0558
5:3FTCA
ND
1.4
0.40
ng/L
05/10/24
1
EPA
1633
BDD0558
7:3FTCA
ND
1.4
0.50
ng/L
05/10/24
1
EPA
1633
BDD0558
- - - - - - - - - - - - - - - - - - -
Surrogate: 13C4-PFBA
- - - - - - - -
86.5%
- - - -
5-130
- - - -
- - - - -
- - - - -
05110124
- - -
1
- -
EPA
- - -
1633
- - - - - -
Surrogate: 13C5-PFPPA
90.0%
40-130
05110124
1
EPA
1633
Surrogate: 13C5-PFHXA
88.4%
40-130
05110124
1
EPA
1633
Surrogate: 13C4-PFMPA
101 %
40-130
05110124
1
EPA
1633
Surrogate: 13C8-PFOA
92.2%
40-130
05110124
1
EPA
1633
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is allowed, except in its entirety. Page 18 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Sample Results
(Continued)
Sample: MW-7113 (Continued)
24DO199-08 (Water)
Date Prep
Analyte Result/Qual PQL MDL Units Analyzed DF Method Batch
Per- and Polyfluoroalkyl Substances
(Continued)
Surrogate: 13C9-PFNA
87.8%
40-130
05110124
1
EPA 1633
Surrogate: 13C6-PFDA
84.1 %
40-130
05110124
1
EPA 1633
Surrogate: 13C7-PFUnA
86.3%
30-130
05110124
1
EPA 1633
Surrogate: 13C2-PFDOA
81.7%
10-130
05110124
1
EPA 1633
Surrogate: 13C2-PFTEDA
82.4%
10-130
05110124
1
EPA 1633
Surrogate: 13C3-PFBS
96.3%
40-135
05110124
1
EPA 1633
Surrogate: 13C3-PFHXS
91.7%
40-130
05110124
1
EPA 1633
Surrogate: 13C8-PF05
92.5%
40-130
05110124
1
EPA 1633
Surrogate: 13C24-2FT5
109%
40-200
05110124
1
EPA 1633
Surrogate: 13C2-6.2FTS
88.7%
40-200
05110124
1
EPA 1633
Surrogate: 13C2-8.2FTS
84.5%
40-300
05110124
1
EPA 1633
Surrogate: 13C8-PFOSA
56.6%
40-130
05110124
1
EPA 1633
Surrogate: D3-NMEF05A
17.1 %
10-130
05110124
1
EPA 1633
Surrogate: D5-NETFOSA
11.4910
10-130
05110124
1
EPA 1633
Surrogate: D3-NMEFOSAA
88.0910
40-170
05110124
1
EPA 1633
Surrogate: D5-NETFOSAA
86.4%
25-135
05110124
1
EPA 1633
Surrogate: D7-NMEF05E
39.5%
10-130
05110124
1
EPA 1633
Surrogate: D9-NETFOSE
35.0%
10-130
05110124
1
EPA 1633
Surrogate: 13C3-HFPO-DA
89.9%
40-130
05110124
1
EPA 1633
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is alloweo,except in its entirety. Page 19 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Sample Results
(Continued)
Sample: SW-1
24DO199-09 (Water)
Date Prep
Analyte Result/Qual PQL MDL Units Analyzed DF Method Batch
Per- and Polyfluoroalkyl Substances
PFBA
ND
130
17
ng/L
05/07/24
1
EPA
1633
BDD0559
PFPeA
ND
66
5.4
ng/L
05/07/24
1
EPA
1633
BDD0559
PFHxA
6.4
J
33
4.5
ng/L
05/07/24
1
EPA
1633
BDD0559
PFHpA
9.2
J
33
3.4
ng/L
05/07/24
1
EPA
1633
BDD0559
PFOA
22
J
33
13
ng/L
05/07/24
1
EPA
1633
BDD0559
PFNA
ND
33
6.7
ng/L
05/07/24
1
EPA
1633
BDD0559
PFDA
ND
33
8.4
ng/L
05/07/24
1
EPA
1633
BDD0559
PFUnA
ND
33
13
ng/L
05/07/24
1
EPA
1633
BDD0559
PFDoA
ND
33
9.2
ng/L
05/07/24
1
EPA
1633
BDD0559
PFTrDA
ND
33
17
ng/L
05/07/24
1
EPA
1633
BDD0559
PFTeDA
ND
33
16
ng/L
05/07/24
1
EPA
1633
BDD0559
PFBS
8.3
J
33
3.0
ng/L
05/07/24
1
EPA
1633
BDD0559
PFPeS
ND
33
5.2
ng/L
05/07/24
1
EPA
1633
BDD0559
PFHxS
6.3
MI5,3
33
2.6
ng/L
05/07/24
1
EPA
1633
BDD0559
PFHpS
ND
33
4.2
ng/L
05/07/24
1
EPA
1633
BDD0559
PFOS
65
MI2
33
5.2
ng/L
05/07/24
1
EPA
1633
BDD0559
PFNS
ND
33
10
ng/L
05/07/24
1
EPA
1633
BDD0559
PFDS
ND
33
12
ng/L
05/07/24
1
EPA
1633
BDD0559
PFDoS
ND
33
10
ng/L
05/07/24
1
EPA
1633
BDD0559
4:2FTS
ND
130
24
ng/L
05/07/24
1
EPA
1633
BDD0559
6:2FTS
ND
130
26
ng/L
05/07/24
1
EPA
1633
BDD0559
8:2FTS
ND
130
6.8
ng/L
05/07/24
1
EPA
1633
BDD0559
PFOSA
ND
33
8.6
ng/L
05/07/24
1
EPA
1633
BDD0559
NMeFOSA
ND
130
39
ng/L
05/07/24
1
EPA
1633
BDD0559
NEtFOSA
ND
130
34
ng/L
05/07/24
1
EPA
1633
BDD0559
NMeFOSAA
ND
33
8.7
ng/L
05/07/24
1
EPA
1633
BDD0559
NEtFOSAA
ND
33
9.5
ng/L
05/07/24
1
EPA
1633
BDD0559
NMeFOSE
ND
130
83
ng/L
05/07/24
1
EPA
1633
BDD0559
NEtFOSE
ND
130
86
ng/L
05/07/24
1
EPA
1633
BDD0559
HFPO-DA
ND
66
14
ng/L
05/07/24
1
EPA
1633
BDD0559
ADONA
ND
66
10
ng/L
05/07/24
1
EPA
1633
BDD0559
PFEESA
ND
66
9.0
ng/L
05/07/24
1
EPA
1633
BDD0559
PFMPA
ND
66
4.4
ng/L
05/07/24
1
EPA
1633
BDD0559
PFMBA
ND
66
7.5
ng/L
05/07/24
1
EPA
1633
BDD0559
NFDHA
ND
66
25
ng/L
05/07/24
1
EPA
1633
BDD0559
9CI-PF30NS
ND
66
17
ng/L
05/07/24
1
EPA
1633
BDD0559
11CI-PF30UDS
ND
66
17
ng/L
05/07/24
1
EPA
1633
BDD0559
3:3FTCA
ND
130
47
ng/L
05/07/24
1
EPA
1633
BDD0559
5:3FTCA
ND
130
37
ng/L
05/07/24
1
EPA
1633
BDD0559
7:3FTCA
ND
130
46
ng/L
05/07/24
1
EPA
1633
BDD0559
- - - - - - - - - - - - - - - - - - -
Surrogate: 13C4-PFBA
- - - - -
102 %
- - -
- - - - -
5-130
- - -
- - - - -
- - - - -
05107124
- - -
1
- -
EPA
- - -
1633
- - - - - -
Surrogate: 13C5-PFPPA
97.6%
40-130
05107124
1
EPA
1633
Surrogate: 13C5-PFHXA
101 %
40-130
05107124
1
EPA
1633
Surrogate: 13C4-PFMPA
102%
40-130
05107124
1
EPA
1633
Surrogate: 13C8-PFOA
97.6%
40-130
05107124
1
EPA
1633
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is allowed, except in its entirety. Page 20 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Sample Results
(Continued)
Sample: SW-1 (Continued)
24DO199-09 (Water)
Date Prep
Analyte Result/Qual PQL MDL Units Analyzed DF Method Batch
Per- and Polyfluoroalkyl Substances
(Continued)
Surrogate: 13C9-PFNA
98.2%
40-130
05107124
1
EPA 1633
Surrogate: 13C6-PFDA
94.0%
40-130
05107124
1
EPA 1633
Surrogate: 13C7-PFUnA
96.2%
30-130
05107124
1
EPA 1633
Surrogate: 13C2-PFDOA
93.9%
10-130
05107124
1
EPA 1633
Surrogate: 13C2-PFTEDA
82.5%
10-130
05107124
1
EPA 1633
Surrogate: 13C3-PFBS
99.3%
40-135
05107124
1
EPA 1633
Surrogate: 13C3-PFHXS
97.9%
40-130
05107124
1
EPA 1633
Surrogate: 13C8-PF05
86.1 %
40-130
05107124
1
EPA 1633
Surrogate: 13C24-2FT5
110%
40-200
05107124
1
EPA 1633
Surrogate: 13C2-6.2FTS
97.6%
40-200
05107124
1
EPA 1633
Surrogate: 13C2-8.2FTS
109%
40-300
05107124
1
EPA 1633
Surrogate: 13C8-PFOSA
55.4%
40-130
05107124
1
EPA 1633
Surrogate: D3-NMEF05A
30.9%
10-130
05107124
1
EPA 1633
Surrogate: D5-NETFOSA
31.4910
10-130
05107124
1
EPA 1633
Surrogate: D3-NMEFOSAA
84.5%
40-170
05107124
1
EPA 1633
Surrogate: D5-NETFOSAA
83.4%
25-135
05107124
1
EPA 1633
Surrogate: D7-NMEF05E
57.4%
10-130
05107124
1
EPA 1633
Surrogate: D9-NETFOSE
42.8%
10-130
05107124
1
EPA 1633
Surrogate: 13C3-HFPO-DA
94.3%
40-130
05107124
1
EPA 1633
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is alloweo,except in its entirety. Page 21 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Sample Results
(Continued)
Sample: SW-2
24DO199-10 (Water)
Date Prep
Analyte Result/Qual PQL MDL Units Analyzed DF Method Batch
Per- and Polyfluoroalkyl Substances
PFBA
180
85
11
ng/L
05/07/24
1
EPA
1633
BDD0559
PFPeA
300
42
3.4
ng/L
05/07/24
1
EPA
1633
BDD0559
PFHxA
750
21
2.9
ng/L
05/07/24
1
EPA
1633
BDD0559
PFHpA
620
21
2.2
ng/L
05/07/24
1
EPA
1633
BDD0559
PFOA
2700
21
8.1
ng/L
05/07/24
1
EPA
1633
BDD0559
PFNA
49 MI5
21
4.3
ng/L
05/07/24
1
EPA
1633
BDD0559
PFDA
ND
21
5.4
ng/L
05/07/24
1
EPA
1633
BDD0559
PFUnA
ND
21
8.5
ng/L
05/07/24
1
EPA
1633
BDD0559
PFDoA
ND
21
5.9
ng/L
05/07/24
1
EPA
1633
BDD0559
PFTrDA
ND
21
11
ng/L
05/07/24
1
EPA
1633
BDD0559
PFTeDA
ND
21
10
ng/L
05/07/24
1
EPA
1633
BDD0559
PFBS
550
21
1.9
ng/L
05/07/24
1
EPA
1633
BDD0559
PFPeS
330
21
3.3
ng/L
05/07/24
1
EPA
1633
BDD0559
PFHxS
500
21
1.7
ng/L
05/07/24
1
EPA
1633
BDD0559
PFHpS
61
21
2.7
ng/L
05/07/24
1
EPA
1633
BDD0559
PFOS
2100
21
3.4
ng/L
05/07/24
1
EPA
1633
BDD0559
PFNS
ND
21
6.5
ng/L
05/07/24
1
EPA
1633
BDD0559
PFDS
ND
21
8.0
ng/L
05/07/24
1
EPA
1633
BDD0559
PFDoS
ND
21
6.5
ng/L
05/07/24
1
EPA
1633
BDD0559
4:2FTS
ND
85
15
ng/L
05/07/24
1
EPA
1633
BDD0559
6:2FTS
ND
85
17
ng/L
05/07/24
1
EPA
1633
BDD0559
8:2FTS
ND
85
4.3
ng/L
05/07/24
1
EPA
1633
BDD0559
PFOSA
35 MI5
21
5.5
ng/L
05/07/24
1
EPA
1633
BDD0559
NMeFOSA
ND
85
25
ng/L
05/07/24
1
EPA
1633
BDD0559
NEtFOSA
ND
85
22
ng/L
05/07/24
1
EPA
1633
BDD0559
NMeFOSAA
36
21
5.6
ng/L
05/07/24
1
EPA
1633
BDD0559
NEtFOSAA
ND
21
6.1
ng/L
05/07/24
1
EPA
1633
BDD0559
NMeFOSE
ND
85
54
ng/L
05/07/24
1
EPA
1633
BDD0559
NEtFOSE
ND
85
55
ng/L
05/07/24
1
EPA
1633
BDD0559
HFPO-DA
ND
42
9.2
ng/L
05/07/24
1
EPA
1633
BDD0559
ADONA
ND
42
6.5
ng/L
05/07/24
1
EPA
1633
BDD0559
PFEESA
ND
42
5.8
ng/L
05/07/24
1
EPA
1633
BDD0559
PFMPA
ND
42
2.9
ng/L
05/07/24
1
EPA
1633
BDD0559
PFMBA
ND
42
4.8
ng/L
05/07/24
1
EPA
1633
BDD0559
NFDHA
ND
42
16
ng/L
05/07/24
1
EPA
1633
BDD0559
9CI-PF30NS
ND
42
11
ng/L
05/07/24
1
EPA
1633
BDD0559
11CI-PF30UDS
ND
42
11
ng/L
05/07/24
1
EPA
1633
BDD0559
3:3FTCA
ND
85
30
ng/L
05/07/24
1
EPA
1633
BDD0559
5:3FTCA
ND
85
23
ng/L
05/07/24
1
EPA
1633
BDD0559
7:3FTCA
ND
85
29
ng/L
05/07/24
1
EPA
1633
BDD0559
- - - - - - - - - - - - - - - - - - -
Surrogate: 13C4-PFBA
- - - - - - - -
94.2 %
- - - - -
5-130
- - -
- - - - -
- - - - -
05107124
- - -
1
- -
EPA
- - -
1633
- - - - - -
Surrogate: 13C5-PFPPA
96.8%
40-130
05107124
1
EPA
1633
Surrogate: 13C5-PFHXA
94.1 %
40-130
05107124
1
EPA
1633
Surrogate: 13C4-PFMPA
109%
40-130
05107124
1
EPA
1633
Surrogate: 13C8-PFOA
98.7%
40-130
05107124
1
EPA
1633
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is allowed, except in its entirety. Page 22 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Sample Results
(Continued)
Sample: SW-2 (Continued)
24DO199-10 (Water)
Date Prep
Analyte Result/Qual PQL MDL Units Analyzed DF Method Batch
Per- and Polyfluoroalkyl Substances
(Continued)
Surrogate: 13C9-PFNA
89.5%
40-130
05107124
1
EPA 1633
Surrogate: 13C6-PFDA
92.2%
40-130
05107124
1
EPA 1633
Surrogate: 13C7-PFUnA
90.6%
30-130
05107124
1
EPA 1633
Surrogate: 13C2-PFDOA
86.2%
10-130
05107124
1
EPA 1633
Surrogate: 13C2-PFTEDA
81.0%
10-130
05107124
1
EPA 1633
Surrogate: 13C3-PFBS
107%
40-135
05107124
1
EPA 1633
Surrogate: 13C3-PFHXS
106%
40-130
05107124
1
EPA 1633
Surrogate: 13C8-PF05
95.6%
40-130
05107124
1
EPA 1633
Surrogate: 13C24-2FT5
110%
40-200
05107124
1
EPA 1633
Surrogate: 13C2-6.2FTS
102%
40-200
05107124
1
EPA 1633
Surrogate: 13C2-8.2FTS
98.3%
40-300
05107124
1
EPA 1633
Surrogate: 13C8-PFOSA
40.5%
40-130
05107124
1
EPA 1633
Surrogate: D3-NMEF05A
24.3%
10-130
05107124
1
EPA 1633
Surrogate: D5-NETFOSA
25.1 %
10-130
05107124
1
EPA 1633
Surrogate: D3-NMEFOSAA
81.5%
40-170
05107124
1
EPA 1633
Surrogate: D5-NETFOSAA
75.7%
25-135
05107124
1
EPA 1633
Surrogate: D7-NMEF05E
44.6%
10-130
05107124
1
EPA 1633
Surrogate: D9-NETFOSE
35.1 %
10-130
05107124
1
EPA 1633
Surrogate: 13C3-HFPO-DA
89.6%
40-130
05107124
1
EPA 1633
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is alloweo,except in its entirety. Page 23 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Sample Results
(Continued)
Sample: SW-3
24DO199-11 (Water)
Date Prep
Analyte Result/Qual PQL MDL Units Analyzed DF Method Batch
Per- and Polyfluoroalkyl Substances
PFBA
190
98
13
ng/L
05/07/24
1
EPA
1633
BDD0559
PFPeA
320
49
4.0
ng/L
05/07/24
1
EPA
1633
BDD0559
PFHxA
880
25
3.4
ng/L
05/07/24
1
EPA
1633
BDD0559
PFHpA
910
25
2.5
ng/L
05/07/24
1
EPA
1633
BDD0559
PFOA
4000
25
9.4
ng/L
05/07/24
1
EPA
1633
BDD0559
PFNA
85 MI5
25
5.0
ng/L
05/07/24
1
EPA
1633
BDD0559
PFDA
8.5 MI2,3
25
6.2
ng/L
05/07/24
1
EPA
1633
BDD0559
PFUnA
ND
25
9.8
ng/L
05/07/24
1
EPA
1633
BDD0559
PFDoA
ND
25
6.9
ng/L
05/07/24
1
EPA
1633
BDD0559
PFTrDA
ND
25
13
ng/L
05/07/24
1
EPA
1633
BDD0559
PFTeDA
ND
25
12
ng/L
05/07/24
1
EPA
1633
BDD0559
PFBS
660
25
2.3
ng/L
05/07/24
1
EPA
1633
BDD0559
PFPeS
390
25
3.9
ng/L
05/07/24
1
EPA
1633
BDD0559
PFHxS
690 MI5
25
1.9
ng/L
05/07/24
1
EPA
1633
BDD0559
PFHpS
110
25
3.2
ng/L
05/07/24
1
EPA
1633
BDD0559
PFOS
3000
25
3.9
ng/L
05/07/24
1
EPA
1633
BDD0559
PFNS
ND
25
7.6
ng/L
05/07/24
1
EPA
1633
BDD0559
PFDS
ND
25
9.3
ng/L
05/07/24
1
EPA
1633
BDD0559
PFDoS
ND
25
7.6
ng/L
05/07/24
1
EPA
1633
BDD0559
4:2FTS
ND
98
18
ng/L
05/07/24
1
EPA
1633
BDD0559
6:2FTS
ND
98
19
ng/L
05/07/24
1
EPA
1633
BDD0559
8:2FTS
ND
98
5.0
ng/L
05/07/24
1
EPA
1633
BDD0559
PFOSA
38
25
6.4
ng/L
05/07/24
1
EPA
1633
BDD0559
NMeFOSA
ND
98
29
ng/L
05/07/24
1
EPA
1633
BDD0559
NEtFOSA
ND
98
25
ng/L
05/07/24
1
EPA
1633
BDD0559
NMeFOSAA
45
25
6.5
ng/L
05/07/24
1
EPA
1633
BDD0559
NEtFOSAA
ND
25
7.1
ng/L
05/07/24
1
EPA
1633
BDD0559
NMeFOSE
ND
98
62
ng/L
05/07/24
1
EPA
1633
BDD0559
NEtFOSE
ND
98
64
ng/L
05/07/24
1
EPA
1633
BDD0559
HFPO-DA
ND
49
11
ng/L
05/07/24
1
EPA
1633
BDD0559
ADONA
ND
49
7.6
ng/L
05/07/24
1
EPA
1633
BDD0559
PFEESA
ND
49
6.7
ng/L
05/07/24
1
EPA
1633
BDD0559
PFMPA
ND
49
3.3
ng/L
05/07/24
1
EPA
1633
BDD0559
PFMBA
ND
49
5.6
ng/L
05/07/24
1
EPA
1633
BDD0559
NFDHA
ND
49
18
ng/L
05/07/24
1
EPA
1633
BDD0559
9CI-PF30NS
ND
49
13
ng/L
05/07/24
1
EPA
1633
BDD0559
11CI-PF30UDS
ND
49
13
ng/L
05/07/24
1
EPA
1633
BDD0559
3:3FTCA
ND
98
35
ng/L
05/07/24
1
EPA
1633
BDD0559
5:3FTCA
ND
98
27
ng/L
05/07/24
1
EPA
1633
BDD0559
7:3FTCA
ND
98
34
ng/L
05/07/24
1
EPA
1633
BDD0559
- - - - - - - - - - - - - - - - - - -
Surrogate: 13C4-PFBA
- - - - - - - -
99.5%
- - - - -
5-130
- - -
- - - - -
- - - - -
05107124
- - -
1
- -
EPA
- - -
1633
- - - - - -
Surrogate: 13C5-PFPPA
101 %
40-130
05107124
1
EPA
1633
Surrogate: 13C5-PFHXA
100%
40-130
05107124
1
EPA
1633
Surrogate: 13C4-PFMPA
104%
40-130
05107124
1
EPA
1633
Surrogate: 13C8-PFOA
104%
40-130
05107124
1
EPA
1633
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is allowed, except in its entirety. Page 24 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Sample Results
(Continued)
Sample: SW-3 (Continued)
24DO199-11 (Water)
Date Prep
Analyte Result/Qual PQL MDL Units Analyzed DF Method Batch
Per- and Polyfluoroalkyl Substances
(Continued)
Surrogate: 13C9-PFNA
110%
40-130
05107124
1
EPA 1633
Surrogate: 13C6-PFDA
116%
40-130
05107124
1
EPA 1633
Surrogate: 13C7-PFUnA
113%
30-130
05107124
1
EPA 1633
Surrogate: 13C2-PFDOA
125%
10-130
05107124
1
EPA 1633
Surrogate: 13C2-PFTEDA
110%
10-130
05107124
1
EPA 1633
Surrogate: 13C3-PFBS
114%
40-135
05107124
1
EPA 1633
Surrogate: 13C3-PFHXS
111 %
40-130
05107124
1
EPA 1633
Surrogate: 13C8-PF05
99.2%
40-130
05107124
1
EPA 1633
Surrogate: 13C24-2FT5
118%
40-200
05107124
1
EPA 1633
Surrogate: 13C2-6.2FTS
101 %
40-200
05107124
1
EPA 1633
Surrogate: 13C2-8.2FTS
106%
40-300
05107124
1
EPA 1633
Surrogate: 130-PFOSA
65.8%
40-130
05107124
1
EPA 1633
Surrogate: D3-NMEF05A
45.0%
10-130
05107124
1
EPA 1633
Surrogate: D5-NETFOSA
46.8910
10-130
05107124
1
EPA 1633
Surrogate: D3-NMEFOSAA
89.4 %
40-170
05107124
1
EPA 1633
Surrogate: D5-NETFOSAA
93.6%
25-135
05107124
1
EPA 1633
Surrogate: D7-NMEF05E
94.5%
10-130
05107124
1
EPA 1633
Surrogate: D9-NETFOSE
64.0%
10-130
05107124
1
EPA 1633
Surrogate: 13C3-HFPO-DA
94.0%
40-130
05107124
1
EPA 1633
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is alloweo,except in its entirety. Page 25 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
PREPARATION BATCH SUMMARY
EPA 1633
Laboratory: APPL, LLC
Client: Waypoint Analytical
Batch: BDD0558 Batch Matrix: Water Preparation: EPA 1633
SAMPLE NAME LAB SAMPLE ID DATE PREPARED INITIAL VOL./WEIGHT FINAL VOL.
mL mL
MW-1
24DO199-01
05/03/24 15:45
531.51
2.00
MW-2
24DO199-02
05/03/24 15:45
46.82
2.00
MW-3
24DO199-03
05/03/24 15:45
572.98
2.00
MW-3
24DO199-03RE1
05/03/24 15:45
572.98
2.00
MW-4
24DO199-04
05/03/24 15:45
51.50
2.00
MW-4
24D0199-04RE1
05/03/24 15:45
51.50
2.00
MW-4
24D0199-04RE2
05/03/24 15:45
51.50
2.00
MW-5
24DO199-05
05/03/24 15:45
51.10
2.00
MW-5
24DO199-05RE1
05/03/24 15:45
51.10
2.00
MW-6
24DO199-06
05/03/24 15:45
46.98
2.00
MW-7
24DO199-07
05/03/24 15:45
558.89
2.00
MW-7
24DO199-07RE1
05/03/24 15:45
558.89
2.00
MW-7D
24DO199-08
05/03/24 15:45
557.72
2.00
Blank
BDD0558-BLK1
05/03/24 15:45
500.00
2.00
LCS
BDD0558-BSI
05/03/24 15:45
500.00
2.00
MRL Check
BDD0558-MRL1
05/03/24 15:45
500.00
2.00
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is allowed, except in its entirety. Page 26 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
PREPARATION BATCH SUMMARY
EPA 1633
Laboratory:
Client:
Batch:
APPL, LLC
Waypoint Analytical
BDD0559 Batch Matrix: Water
Preparation:
EPA 1633
SAMPLE NAME
LAB SAMPLE ID
DATE PREPARED
INITIAL VOL./WEIGHT
FINAL VOL.
mL
mL
SW-1
24DO199-09
05/02/24 10:57
6.07
2.00
SW-2
24DO199-10
05/02/24 10:57
9.45
2.00
SW-3
24DO199-11
05/02/24 10:57
8.13
2.00
Blank
BDD0559-BLKI
05/02/24 10:57
500.00
2.00
LCS
BDD0559-BSI
05/02/24 10:57
500.00
2.00
MRL Check
BDD0559-MRL 1
05/02/24 10:57
500.00
2.00
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is allowed, except in its entirety. Page 27 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Quality Control
Per- and Polyfluoroalkyl Substances
Spike Source %REC RPD
Analyte Result/ Qual PQL MDL Units Level Result %REC Limits RPD Limit
Method; EPA 1633
Batch; BDD0558 - EPA 1633
Blank (BDD0558-BLK1)
Prepared: 05/03/24
15:45 Analyzed: 05/09/24 23:07
PFBA
ND
1.6
0.21
ng/L
PFPeA
ND
0.80
0.065
ng/L
PFHxA
ND
0.40
0.055
ng/L
PFHpA
ND
0.40
0.041
ng/L
PFOA
ND
0.40
0.15
ng/L
PFNA
ND
0.40
0.082
ng/L
PFDA
ND
0.40
0.10
ng/L
PFUnA
ND
0.40
0.16
ng/L
PFDoA
ND
0.40
0.11
ng/L
PFTrDA
ND
0.40
0.20
ng/L
PFTeDA
ND
0.40
0.20
ng/L
PFBS
ND
0.40
0.037
ng/L
PFPeS
ND
0.40
0.063
ng/L
PFHxS
ND
0.40
0.032
ng/L
PFHpS
ND
0.40
0.051
ng/L
PFOS
ND
0.40
0.064
ng/L
PFNS
ND
0.40
0.12
ng/L
PFDS
ND
0.40
0.15
ng/L
PFDoS
ND
0.40
0.12
ng/L
4:2FTS
ND
1.6
0.29
ng/L
6:21FTS
ND
1.6
0.31
ng/L
8:2FTS
ND
1.6
0.082
ng/L
PFOSA
ND
0.40
0.10
ng/L
NMeFOSA
ND
1.6
0.47
ng/L
NEtFOSA
ND
1.6
0.41
ng/L
NMeFOSAA
ND
0.40
0.11
ng/L
NEtFOSAA
ND
0.40
0.11
ng/L
NMeFOSE
ND
1.6
1.0
ng/L
NEtFOSE
ND
1.6
1.0
ng/L
HFPO-DA
ND
0.80
0.17
ng/L
ADONA
ND
0.80
0.12
ng/L
PFEESA
ND
0.80
0.11
ng/L
PFMPA
ND
0.80
0.054
ng/L
PFMBA
ND
0.80
0.091
ng/L
NFDHA
ND
0.80
0.30
ng/L
9CI-PF30NS
ND
0.80
0.21
ng/L
11CI-PF30UDS
ND
0.80
0.21
ng/L
3:3FTCA
ND
1.6
0.57
ng/L
5:3FTCA
ND
1.6
0.44
ng/L
7:3FTCA
- - - - - - - - - - - - - - - -
ND
- - - - - - -
1.6
- - - -
0.55
- - -
ng/L
- - -
- - - - - - -
- - - - - -
- - - - - - - - - - - -
Surrogate:13C4-PFBA
26.4
ng/L
32.0
88.7
5-130
Surrogate:13C5-PFPEA
14.2
ng/L
16.0
88.8
40-130
Surrogate:13C5-PFHXA
7.85
ng/L
8.00
98.2
40-130
Surrogate:13C4-PFHPA
6.32
ng/L
8.00
104
40-130
Surrogate: 13C8-PFOA
7.48
ng/L
8.00
93.5
40-130
Surrogate:13C9-PFNA
3.29
ng/L
4.00
82.1
40-130
Surrogate:13C6-PFDA
3.73
ng/L
4.00
93.4
40-130
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is allowed, except in its entirety. Page 28 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Quality Control
(Continued)
Per- and Polyfluoroalkyl Substances (Continued)
Spike Source %REC RPD
Analyte Result/ Qual PQL MDL Units Level Result %REC Limits RPD Limit
Blank (B111311130558-BL111(3)
- - - - - - - - - - - - - -
- - - - - - - - -
- - - - - - -
Prepared: 05/03/24 15:45 Analyzed: 05/09/24 23:07
- - - - - - - - - - - - - - - - - - - - - - - - -
Surrogate: 13C7-PFUnA
3.99
ng/L
4.00
99.7
30-130
Surrogate:13C2-PFDOA
4.14
ng/L
4.00
103
10-130
Surrogate:13C2-PFTEDA
4.31
ng/L
4.00
108
10-130
Surrogate:13C3-PFBS
7.39
ng/L
8.00
92.4
40-135
Surrogate:13C3-PFHXS
7.43
ng/L
8.00
92.8
40-130
Surrogate:13C8-PFOS
7.58
ng/L
8.00
94.8
40-130
Surrogate:13C242FTS
16.3
ng/L
16.0
102
40-200
Surrogate:13C2-6:2FTS
14.5
ng/L
16.0
90.7
40-200
Surrogate:13C2-8.2FTS
12.9
ng/L
16.0
80.9
40-300
Surrogate:13C8-PFOSA
3.37
ng/L
8.00
42.2
40-130
Surrogate: D3-NMEFOSA
a773 51
ng/L
8.00
9.66
10-130
Surrogate: D5-NETF05A
0.463 51
ng/L
8.00
5.78
10-130
Surrogate: D3-NMEF05AA
13.8
ng/L
16.0
86.4
40-170
Surrogate: D5-NETF05AA
12.2
ng/L
16.0
76.0
25-135
Surrogate: D7-NMEF05E
20.4
ng/L
80.0
25.5
10-130
Surrogate: D9-NETF05E
20.0
ng/L
80.0
24.9
10-130
Surrogate:13C3-HFPO-DA
29.5
ng/L
32.0
92.2
40-130
LCS (BDD0558-BS1)
Prepared: 05/03/24
15:45 Analyzed: 05/09/24 23:28
PFBA
15.7
ng/L
16.0
98.4
70-140
PFPeA
8.07
ng/L
8.00
101
65-135
PFHxA
3.90
ng/L
4.00
97.6
70-145
PFHpA
4.32
ng/L
4.00
108
70-150
PFOA
4.08
ng/L
4.00
102
70-150
PFNA
4.04
ng/L
4.00
101
70-150
PFDA
4.33
ng/L
4.00
108
70-140
PFUnA
3.68
ng/L
4.00
91.9
70-145
PFDoA
3.99
ng/L
4.00
99.7
70-140
PFTrDA
4.20
ng/L
4.00
105
65-140
PFTeDA
4.05
ng/L
4.00
101
60-140
PFBS
3.48
ng/L
3.54
98.4
60-145
PFPeS
3.77
ng/L
3.76
100
65-140
PFHxS
3.63
ng/L
3.66
99.1
65-145
PFHpS
4.30
ng/L
3.82
112
70-150
PFOS
3.76
ng/L
3.72
101
55-150
PFNS
4.09
ng/L
3.84
106
65-145
PFDS
3.99
ng/L
3.86
103
60-145
PFDoS
4.02
ng/L
3.88
104
50-145
4:2FTS
14.9
ng/L
15.0
99.3
70-145
6:21FTS
15.5
ng/L
15.2
102
65-155
8:21FTS
15.3
ng/L
15.4
99.4
60-150
PFOSA
4.26
ng/L
4.00
107
70-145
NMeFOSA
18.1
ng/L
16.0
113
60-150
NEtFOSA
19.1
ng/L
16.0
119
65-145
NMeFOSAA
3.60
ng/L
4.00
90.1
50-140
NEtFOSAA
4.22
ng/L
4.00
105
70-145
NMeFOSE
15.0
ng/L
16.0
93.8
70-145
NEtFOSE
15.5
ng/L
16.0
97.1
70-135
HFPO-DA
4.02
ng/L
4.00
101
70-140
ADONA
3.85
ng/L
3.78
102
65-145
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety. Page 29 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Quality Control
(Continued)
Per- and Polyfluoroalkyl Substances (Continued)
Spike Source %REC RPD
Analyte Result/ Qual PQL MDL Units Level Result %REC Limits RPD Limit
LCS (BDD0558-BS1)
Prepared: 05/03/24 15:45 Analyzed: 05/09/24 23:28
PFEESA
6.97
ng/L
7.12
97.9
70-140
PFMPA
7.57
ng/L
8.00
94.6
55-140
PFMBA
7.42
ng/L
8.00
92.7
60-150
NFDHA
7.38
ng/L
8.00
92.3
50-150
9CI-PF30NS
3.91
ng/L
3.74
104
70-155
11CI-PF30UDS
4.09
ng/L
3.78
108
55-160
3:3FTCA
8.21 BS1
ng/L
16.0
51.3
65-130
5:3FTCA
9.60 BS1
ng/L
16.0
60.0
70-135
7:3FTCA
- - - - - - - - - - - - -
9.63
- - - - - - - - - - - - -
ng/L
- - - - - - -
16.0
- - - - - - -
60.2
- - - - - -
50-145
- - - - - - - - - - - -
Surrogate:13C4-PFBA
29.2
ng/L
32.0
91.2
5-130
Surrogate:13C5-PFPPA
14.7
ng/L
16.0
92.1
40-130
Surrogate:13C5-PFHXA
7.60
ng/L
8.00
95.0
40-130
Surrogate:13C4-PFMPA
7.79
ng/L
8.00
97.4
40-130
Surrogate:13C8-PFOA
7.35
ng/L
8.00
91.9
40-130
Surrogate:13C9-PFNA
3.68
ng/L
4.00
92.0
40-130
Surrogate:13C6-PFDA
4.00
ng/L
4.00
100
40-130
Surrogate:13C7-PFUnA
4.17
ng/L
4.00
104
30-130
Surrogate:13C2-PFDOA
4.14
ng/L
4.00
103
10-130
Surrogate: 130-PFTEDA
4,19
ng/L
4.00
105
10-130
Surrogate:13C3-PFBS
7.65
ng/L
8.00
95.6
40-135
Surrogate:13C3-PFHXS
7.75
ng/L
8.00
96.9
40-130
Surrogate:13C8-PFOS
7.61
ng/L
6.00
95.1
40-130
Surrogate:13C2-4.2FT5
17.2
ng/L
16.0
107
40-200
Surrogate:13C2-6:2FTS
14.7
ng/L
16.0
91.6
40-200
Surrogate:13C2-8:2FTS
14.9
ng/L
16.0
93.2
40-300
Surrogate:13C8-PFOSA
3.56
ng/L
8.00
44.5
40-130
Surrogate: D3-NMEFOSA
0.914
ng/L
8.00
11.4
10-130
Surrogate: D5-NETFOSA
0.696 SI
ng/L
8.00
6.70
10-130
Surrogate: D3-NMEFOSAA
14.2
ng/L
16.0
89.0
40-170
Surrogate: D5-NETFOSAA
13.4
ng/L
16.0
63.7
25-135
Surrogate: D7-NMEFOSE
23.1
ng/L
80.0
26.9
10-130
Surrogate: D9-NETFOSE
21.1
ng/L
80.0
26.4
10-130
Surrogate: 13C3-HFPO-DA
29.7
ng/L
32.0
92.7
40-130
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is allowed, except in its entirety. Page 30 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Quality Control
(Continued)
Per- and Polyfluoroalkyl Substances (Continued)
Spike Source %REC RPD
Analyte Result/ Qual PQL MDL Units Level Result %REC Limits RPD Limit
MRL Check (BDD0558-MRL1)
Prepared: 05/03/24 15:45 Analyzed: 05/09/24 23:50
PFBA
3.14
ng/L
3.20
98.0
70-140
PFPeA
1.54
ng/L
1.60
96.5
65-135
PFHxA
0.728
ng/L
0.800
91.0
70-145
PFHpA
0.729
ng/L
0.800
91.1
70-150
PFOA
0.914
ng/L
0.800
114
70-150
PFNA
0.758
ng/L
0.800
94.8
70-150
PFDA
0.702
ng/L
0.800
87.8
70-140
PFUnA
0.834
ng/L
0.800
104
70-145
PFDoA
0.736
ng/L
0.800
92.1
70-140
PFTrDA
0.812
ng/L
0.800
102
65-140
PFTeDA
0.708
ng/L
0.800
88.5
60-140
PFBS
0.662
ng/L
0.708
93.6
60-145
PFPeS
0.738
ng/L
0.752
98.1
65-140
PFHxS
0.742
ng/L
0.732
101
65-145
PFHpS
0.767
ng/L
0.764
100
70-150
PFOS
0.771 MI4
ng/L
0.744
104
55-150
PFNS
0.795
ng/L
0.768
104
65-145
PFDS
0.754
ng/L
0.772
97.6
60-145
PFDoS
0.745
ng/L
0.776
96.0
50-145
4:21FTS
2.64
ng/L
3.00
88.2
70-145
6:2FTS
2.74
ng/L
3.04
90.2
65-155
8:21FTS
2.64
ng/L
3.07
86.0
60-150
PFOSA
0.759
ng/L
0.800
94.9
70-145
NMeFOSA
2.48
ng/L
3.20
77.5
60-150
NEtFOSA
2.92
ng/L
3.20
91.3
65-145
NMeFOSAA
0.791 MI4
ng/L
0.800
98.8
50-140
NEtFOSAA
0.666 MI4
ng/L
0.800
83.2
70-145
NMeFOSE
2.68 MI4
ng/L
3.20
83.8
70-145
NEtFOSE
2.54 MI4
ng/L
3.20
79.3
70-135
HFPO-DA
0.7953
ng/L
0.800
99.4
70-140
ADONA
0.7173
ng/L
0.756
94.8
65-145
PFEESA
1.25
ng/L
1.42
87.5
70-140
PFMPA
1.38
ng/L
1.60
86.5
55-140
PFMBA
1.50
ng/L
1.60
94.0
60-150
NFDHA
1.26
ng/L
1.60
79.0
50-150
9CI-PF30NS
0.7863
ng/L
0.748
105
70-155
IICI-PF30UDS
0.7803
ng/L
0.756
103
55-160
3:31FTCA
1.03 BSI, 3
ng/L
3.20
32.2
65-130
5:3FTCA
1.87 BSI
ng/L
3.20
58.6
70-135
7:31FTCA
- - - - - - - - - - - - - - -
1.49 BSI, 3
- - - - - - - - - - -
ng/L
- - - - - - -
3.20
- - - - - - -
46.6
- - - - - -
50-145
- - - - - - - - - - - -
Surrogate: 13C4-PFBA
30.5
ng/L
32,0
95.4
5-130
Surrogate:13C5-PFMEA
14.9
ng/L
16.0
93.3
40-130
Surrogate:13C5-PFHXA
7.77
ng/L
8.00
97.1
40-130
Surrogate:13C4-PFMPA
7.82
ng/L
8.00
97.8
40-130
Surrogate.13C8-PFOA
7.65
ng/L
8.00
95.6
40-130
Surrogate:13C9-PFNA
3.72
ng/L
4.00
93.1
40-130
Surrogate:13C6-PFDA
3.88
ng/L
4.00
97.0
40-130
Surrogate:13C7-PFUnA
3.93
ng/L
4.00
98.4
30-130
Surrogate:13C2-PFDOA
3.80
ng/L
4.00
95.1
10-130
Surrogate:13C2-PFTEDA
4.23
ng/L
4.00
106
10-130
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety. Page 31 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Quality Control
(Continued)
Per- and Polyfluoroalkyl Substances (Continued)
Spike Source %REC RPD
Analyte Result/ Qual PQL MDL Units Level Result %REC Limits RPD Limit
MRL Check (BD1130558-114111111-1)
- - - - - - - - - - - -
- - - - - - - - -
- - - - - - -
Prepared: 05/03/24 15:45 Analyzed: 05/09/24 23:50
- - - - - - - - - - - - - - - - - - - - - - - - -
Surrogate.13C3-PFBS
8.07
ng/L
8.00
101
40-135
Surrogate.13C3-PFHXS
8.02
ng/L
8.00
100
40-130
Surrogate:13C8-PFOS
7.40
ng/L
8.00
92.5
40-130
Surrogate:13C242FTS
17.4
ng/L
16.0
109
40-200
5urrogate:13C2-6.2FT5
15.4
ng/L
16.0
96.0
40-200
5urrogate:13C2-8.2FT5
15.9
ng/L
16.0
99.1
40-300
5urrogate:13C8-PF05A
3.94
ng/L
8.00
49.3
40-130
Surrogate: D3-NMEFOSA
0,959
ng/L
8.00
12.0
10-130
Surrogate: D5-NETFOSA
0.703 S1
ng/L
8.00
8.78
10-130
Surrogate: D3-NMEFOSAA
13.7
ng/L
16.0
85.8
40-170
Surrogate: D5-NETFOSAA
13.6
ng/L
16.0
85.1
25-135
Surrogate: D7-NMEFOSE
28,0
ng/L
80.0
34.9
10-130
Surrogate: D9-NETF05E
25.8
ng/L
80.0
32.3
10-130
Surrogate.13C3-HFPO-DA
29.4
ng/L
32.0
92.0
40-130
Method; EPA 1633
Batch; BDD0559 - EPA 1633
Blank (BDD0559-BLK1)
Prepared: 05/02/24 10:57 Analyzed: 05/06/24 15:39
PFBA
ND
1.6
0.21
ng/L
PFPeA
ND
0.80
0.065
ng/L
PFHxA
ND
0.40
0.055
ng/L
PFHpA
ND
0.40
0.041
ng/L
PFOA
ND
0.40
0.15
ng/L
PFNA
ND
0.40
0.082
ng/L
PFDA
ND
0.40
0.10
ng/L
PFUnA
ND
0.40
0.16
ng/L
PFDoA
ND
0.40
0.11
ng/L
PFTrDA
ND
0.40
0.20
ng/L
PFTeDA
ND
0.40
0.20
ng/L
PFBS
ND
0.40
0.037
ng/L
PFPeS
ND
0.40
0.063
ng/L
PFHxS
ND
0.40
0.032
ng/L
PFHpS
ND
0.40
0.051
ng/L
PFOS
0.0898 IR2, MI5, 3
0.40
0.064
ng/L
PFNS
ND
0.40
0.12
ng/L
PFDS
ND
0.40
0.15
ng/L
PFDoS
ND
0.40
0.12
ng/L
4:2FTS
ND
1.6
0.29
ng/L
6:21FTS
ND
1.6
0.31
ng/L
8:21FTS
ND
1.6
0.082
ng/L
PFOSA
ND
0.40
0.10
ng/L
NMeFOSA
ND
1.6
0.47
ng/L
NEtFOSA
ND
1.6
0.41
ng/L
NMeFOSAA
ND
0.40
0.11
ng/L
NEtFOSAA
ND
0.40
0.11
ng/L
NMeFOSE
ND
1.6
1.0
ng/L
NEtFOSE
ND
1.6
1.0
ng/L
HFPO-DA
ND
0.80
0.17
ng/L
ADONA
ND
0.80
0.12
ng/L
The contents of this report apply to the sample(s) analyzed in
accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.
Page 32 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Quality Control
(Continued)
Per- and Polyfluoroalkyl Substances (Continued)
Spike Source %REC RPD
Analyte Result/ Qual PQL MDL Units Level Result %REC Limits RPD Limit
Blank (BDD0559-BLK1)
Prepared: 05/02/24 10:57 Analyzed: 05/06/24 15:39
PFEESA
ND
0.80
0.11
ng/L
PFMPA
ND
0.80
0.054
ng/L
PFMBA
ND
0.80
0.091
ng/L
NFDHA
ND
0.80
0.30
ng/L
9CI-PF30NS
ND
0.80
0.21
ng/L
11CI-PF30UDS
ND
0.80
0.21
ng/L
3:3FTCA
ND
1.6
0.57
ng/L
5:3FTCA
ND
1.6
0.44
ng/L
7:3FTCA
- - - - - - - - - - - - - -
ND
- - - - - - - - -
1.6
- - - -
0.55
- - -
ng/L
- - -
- - - - - - -
- - - - - -
- - - - - - - - - - - -
Surrogate: 13C4-PFBA
31.9
ng/L
32.0
99.8
5-130
Surrogate:13C5-PFPPA
16.5
ng/L
16.0
103
40-130
Surrogate:13C5-PFHXA
6.32
ng/L
8.00
104
40-130
Surrogate:13C4-PFMPA
7.96
ng/L
8.00
99.5
40-130
Surrogate:13C8-PFOA
7.66
ng/L
8.00
95.8
40-130
Surrogate:13C9-PFNA
3.68
ng/L
4.00
97.1
40-130
Surrogate:13C6-PFDA
4.13
ng/L
4.00
103
40-130
Surrogate:13C7-PFUnA
4.38
ng/L
4.00
110
30-130
Surrogate:13C2-PFDOA
4.69
ng/L
4.00
117
10-130
Surrogate:13C2-PFTEDA
4,82
ng/L
4.00
121
10-130
Surrogate:13C3-PFBS
8.31
ng/L
8.00
104
40-135
Surrogate: 13C3-PFHXS
8.39
ng/L
8.00
105
40-130
Surrogate:13C8-PFOS
7.23
ng/L
6.00
90.4
40-130
Surrogate:13C2-4.2FT5
17.2
ng/L
16.0
107
40-200
Surrogate:13C2-6:2FTS
15.0
ng/L
16.0
93.9
40-200
Surrogate:13C2-8:2FTS
16.1
ng/L
16.0
100
40-300
Surrogate:13C8-PFOSA
5.06
ng/L
8.00
63.2
40-130
Surrogate: D3-NMEFOSA
3.13
ng/L
8.00
39.1
10-130
Surrogate: D5-NETFOSA
3.08
ng/L
8.00
38.5
10-130
Surrogate: D3-NMEFOSAA
12.1
ng/L
16.0
75.5
40-170
Surrogate: D5-NETFOSAA
12.4
ng/L
16.0
77.5
25-135
Surrogate: D7-NMEFOSE
56.6
ng/L
80.0
70.7
10-130
Surrogate: D9-NETFOSE
37.6
ng/L
80.0
47.0
10-130
Surrogate: 13C3-HFPO-DA
30.0
ng/L
32.0
93.9
40-130
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is allowed, except in its entirety. Page 33 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Quality Control
(Continued)
Per- and Polyfluoroalkyl Substances (Continued)
Spike Source %REC RPD
Analyte Result/ Qual PQL MDL Units Level Result %REC Limits RPD Limit
LCS (BDD0559-BS1)
Prepared: 05/02/24 10:57 Analyzed: 05/06/24 16:00
PFBA
15.9
ng/L
16.0
99.5
70-140
PFPeA
7.58
ng/L
8.00
94.8
65-135
PFHxA
3.82
ng/L
4.00
95.6
70-145
PFHpA
3.52
ng/L
4.00
88.1
70-150
PFOA
4.57
ng/L
4.00
114
70-150
PFNA
4.14
ng/L
4.00
104
70-150
PFDA
3.88
ng/L
4.00
96.9
70-140
PFUnA
4.00
ng/L
4.00
100
70-145
PFDoA
3.91
ng/L
4.00
97.7
70-140
PFTrDA
3.89
ng/L
4.00
97.3
65-140
PFTeDA
3.88
ng/L
4.00
97.1
60-140
PFBS
3.35
ng/L
3.54
94.6
60-145
PFPeS
3.84
ng/L
3.76
102
65-140
PFHxS
3.54
ng/L
3.66
96.8
65-145
PFHpS
4.03
ng/L
3.82
106
70-150
PFOS
3.65
ng/L
3.72
98.1
55-150
PFNS
4.12
ng/L
3.84
107
65-145
PFDS
3.86
ng/L
3.86
100
60-145
PFDoS
3.94
ng/L
3.88
102
50-145
4:21FTS
14.8
ng/L
15.0
98.5
70-145
6:2FTS
13.9
ng/L
15.2
91.2
65-155
8:21FTS
16.6
ng/L
15.4
108
60-150
PFOSA
4.10
ng/L
4.00
103
70-145
NMeFOSA
17.5
ng/L
16.0
109
60-150
NEtFOSA
16.2
ng/L
16.0
101
65-145
NMeFOSAA
4.02
ng/L
4.00
101
50-140
NEtFOSAA
4.10 MI5
ng/L
4.00
103
70-145
NMeFOSE
11.6
ng/L
16.0
72.6
70-145
NEtFOSE
16.8
ng/L
16.0
105
70-135
HFPO-DA
4.09
ng/L
4.00
102
70-140
ADONA
3.90
ng/L
3.78
103
65-145
PFEESA
7.71
ng/L
7.12
108
70-140
PFMPA
7.31
ng/L
8.00
91.3
55-140
PFMBA
7.39
ng/L
8.00
92.4
60-150
NFDHA
7.76
ng/L
8.00
96.9
50-150
9CI-PF30NS
4.39
ng/L
3.74
117
70-155
11CI-PF30UDS
4.39
ng/L
3.78
116
55-160
3:31FTCA
12.9
ng/L
16.0
80.5
65-130
5:3FTCA
12.8
ng/L
16.0
79.9
70-135
7:31FTCA
- - - - - - - - - - - - -
13.4
- - - - - - - - - - - - -
ng/L
- - - - - - -
16.0
- - - - - - -
83.9
- - - - - -
50-145
- - - - - - - - - - - -
Surrogate:13C4-PFBA
36.4
ng/L
32.0
114
5-130
Surrogate:13C5-PFPEA
17.2
ng/L
16.0
108
40-130
Surrogate.13C5--PFHXA
8.55
ng/L
8.00
107
40-130
Surrogate:13C4-PFMPA
8.61
ng/L
8.00
108
40-130
Surrogate:13C8-PFOA
7.89
ng/L
8.00
98.6
40-130
Surrogate:13C9-PFNA
4.00
ng/L
4.00
100
40-130
Surrogate:13C6-PFDA
4.37
ng/L
4.00
109
40-130
Surrogate:13C7-PFUnA
4.11
ng/L
4.00
103
30-130
Surrogate:13C2-PFDOA
4.70
ng/L
4.00
117
10-130
Surrogate:13C2-PFTEDA
4.44
ng/L
4.00
111
10-130
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety. Page 34 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Quality Control
(Continued)
Per- and Polyfluoroalkyl Substances (Continued)
Spike Source %REC RPD
Analyte Result/ Qual PQL MDL Units Level Result %REC Limits RPD Limit
LCS (BDD0559-BS1)
- - - - - - - - -
- - - - - - - -
- - - - - - - -
Prepared: 05/02/24 10:57 Analyzed: 05/06/24 16:00
- - - - - - - - - - - - - - - - - - - - -
Surrogate.13C3-PFBS
8.94
ng/L
8.00
112
40-135
Surrogate.13C3-PFHXS
8.92
ng/L
8.00
112
40-130
Surrogate:13C8-PFOS
8.68
ng/L
8.00
109
40-130
Surrogate:13C242FTS
16.1
ng/L
16.0
100
40-200
5urrogate:13C2-6.2FT5
17.2
ng/L
16.0
107
40-200
5urrogate:13C2-8.2FT5
16.1
ng/L
16.0
101
40-300
5urrogate:13C8-PF05A
6.69
ng/L
8.00
83.6
40-130
Surrogate: D3-NMEFOSA
3.96
ng/L
8.00
49.5
10-130
Surrogate: D5-NETFOSA
3.88
ng/L
8.00
48.5
10-130
Surrogate: D3-NMEFOSAA
14.6
ng/L
16.0
91.1
40-170
Surrogate: D5-NETF05AA
14.6
ng/L
16.0
91.5
25-135
Surrogate: D7-NMEFOSE
77.1
ng/L
80.0
96.4
10-130
Surrogate: D9-NETF05E
51.5
ng/L
80.0
64.4
10-130
Surrcgate:13C3-HFPO-DA
32.3
ng/L
32.0
101
40-130
MRL Check (BDD0559-MRLS)
Prepared: 05/02/24 10:57 Analyzed: 05/06/24 16:21
PFBA
3.17
ng/L
3.20
99.1
70-140
PFPeA
1.45
ng/L
1.60
90.8
65-135
PFHxA
0.815
ng/L
0.800
102
70-145
PFHpA
0.646
ng/L
0.800
80.7
70-150
PFOA
0.769
ng/L
0.800
96.2
70-150
PFNA
0.792
ng/L
0.800
99.0
70-150
PFDA
0.763
ng/L
0.800
95.4
70-140
PFUnA
0.748
ng/L
0.800
93.5
70-145
PFDoA
0.838
ng/L
0.800
105
70-140
PFTrDA
0.715
ng/L
0.800
89.3
65-140
PFTeDA
0.825
ng/L
0.800
103
60-140
PFBS
0.669
ng/L
0.708
94.4
60-145
PFPeS
0.806
ng/L
0.752
107
65-140
PFHxS
0.625
ng/L
0.732
85.4
65-145
PFHpS
0.748
ng/L
0.764
97.9
70-150
PFOS
0.875
ng/L
0.744
118
55-150
PFNS
0.825
ng/L
0.768
107
65-145
PFDS
0.783
ng/L
0.772
101
60-145
PFDoS
0.749
ng/L
0.776
96.5
50-145
4:2FTS
2.97
ng/L
3.00
99.1
70-145
6:21FTS
2.79
ng/L
3.04
91.9
65-155
8:21FTS
2.89
ng/L
3.07
93.9
60-150
PFOSA
0.755
ng/L
0.800
94.4
70-145
NMeFOSA
3.42
ng/L
3.20
107
60-150
NEtFOSA
2.68
ng/L
3.20
83.7
65-145
NMeFOSAA
0.793 MI5
ng/L
0.800
99.1
50-140
NEtFOSAA
0.638IR2
ng/L
0.800
79.7
70-145
NMeFOSE
2.26 MI5
ng/L
3.20
70.6
70-145
NEtFOSE
3.09 MI5
ng/L
3.20
96.5
70-135
HFPO-DA
0.991
ng/L
0.800
124
70-140
ADONA
0.6931
ng/L
0.756
91.6
65-145
PFEESA
1.28
ng/L
1.42
90.1
70-140
PFMPA
1.32
ng/L
1.60
82.6
55-140
PFMBA
1.34
ng/L
1.60
83.9
60-150
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety. Page 35 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Quality Control
(Continued)
Per- and Polyfluoroalkyl Substances (Continued)
Spike Source %REC RPD
Analyte Result/ Qual PQL MDL Units Level Result %REC Limits RPD Limit
MRL Check (BDD0559-MRL1)
Prepared: 05/02/24 10:57 Analyzed: 05/06/24 16:21
NFDHA
1.26
ng/L
1.60
78.8
50-150
9CI-PF30NS
0.7971
ng/L
0.748
107
70-155
11CI-PF30UDS
0.835
ng/L
0.756
110
55-160
3:31FTCA
2.02 BS1
ng/L
3.20
63.0
65-130
5:31FTCA
2.20 BS1
ng/L
3.20
68.7
70-135
7:3FTCA
- - - - - - - - - - - - - - -
2.03
- - - - - - - - - - -
ng/L
- - - - - - -
3.20
- - - - - - -
63A
- - - - - -
50-145
- - - - - - - - - - - -
Surrogate.13C4-PFBA
32.5
ng/L
32.0
102
5-130
Surrogate.13C5--PFPEA
15.3
ng/L
16.0
95.6
40-130
Surrogate.13C5-PFHx4
7.61
ng/L
8.00
95.1
40-130
Surrogate. i3C4-PFHPA
8.05
ng/L
8.00
101
40-130
Surrogate.13C8-PFOA
7.95
ng/L
8.00
99.4
40-130
Surrogate.13C9-PFNA
4.13
ng/L
4.00
103
40-130
5urrogate:13C6-PFDA
4,25
ng/L
4.00
106
40-130
5urrogate:13C7--PFUnA
4.34
ng/L
4.00
109
30-130
5urrogate:13C2-PFDOA
4.53
ng/L
4.00
113
10-130
Surrogate: 13C2-PFTEDA
4.46
ng/L
4.00
111
10-130
5urrogate:130-PF85
8.69
ng/L
8.00
109
40-135
Surrogate.13C3-PFHXS
8.80
ng/L
8.00
110
40-130
5unrogate:130-PFOS
7.71
ng/L
8.00
96.4
40-130
Surrcgate:13C2-4:2FTS
16.7
ng/L
16.0
105
40-200
Surrogate:13C2-6:2FTS
16.8
ng/L
16.0
105
40-200
Surrogate.13C2-8.2FTS
16.6
ng/L
16.0
104
40-300
Surrogate.13C8-PFOSA
577
ng/L
8.00
72.2
40-130
Surrogate: D3-NMEFOSA
3.06
ng/L
8.00
38.2
10-130
Surrogate: D5-NETFOSA
3.28
ng/L
8.00
41.0
10-130
Surrogate.03-NMEFOSAA
14.6
ng/L
16.0
91.3
40-170
Surrogate: D5-NETFOSAA
14.0
ng/L
16.0
87.7
25-135
Surrogate: D7-NMEFOSE
65.5
ng/L
80.0
81.8
10-130
Surrogate: D9-NETFOSE
45.3
ng/L
80.0
56.7
10-130
5urrogate:13C3-HFPO-DA
28.3
ng/L
32.0
88.6
40-130
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety. Page 36 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Notes and Definitions
Item
Definition
AE
Added EIS
BSI
Blank spike recovered below the lower control limit
IR2
Ion ratio above the upper control limit
I
Estimated value
MI2
Manual integration, non -target peak interference
MI4
Manual integration, peak unsplit
MI5
Manual integration, whole peak was not integrated
MI6
Manual integration, wrong peak integrated
S1
Surrogate recovered below the lower control limit
U
Not detected
Dry
Sample results reported on a dry weight basis.
MDL
Method Detection Limit (only displays if reported to the MDL)
NO
Analyte NOT DETECTED at or above the reporting limit.
DF
Dilution Factor
DL
Detection Limit
RPD Relative Percent Difference
%REC Percent Recovery
Source Sample that was matrix spiked or duplicated.
PQL, Practical Quantitation Limit = Method Reporting Limit (MRL).
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is allowed, except in its entirety. Page 37 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-BO7C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
iAPPL
AGRICULTURE & PRIORITY POLLUTANTS LABORATORIES
09 A METIRI GROUP COMPANY
Project:
Project Number:
Project Manager:
PO Number:
Report To:
Waypoint Analytical
Ann Baynor
114 Oakmont Drive
Greenville, NC 27858
Phone: [phone]
Fax: [phone]
6034 Person Co. Landfill
6034 Person Co. Landfill
Chue Moua
WF6034042324
Invoice To:
Waypoint Analytical
Jerri Dawson
2790 Whitten Road
Memphis, TN 38133
Phone: [phone]
Fax: [phone]
Date Received: 04/26/2024 09:56 AM Logged In By: Sophia Herrera
Date Due: 05/10/2024 (10.00 day TAT) Received By: Terry Moren
Analysis Comments
24DO199-01 MW-1 [Water] Sampled 4/23/2024 9:08:0013M
1633 1633
24DO199-02 MW-2 [Water] Sampled 4/23/2024 1:35:OOPM
1633 1633
24DO199-03 MW-3 [Water] Sampled 4/23/2024 11:22:OOAM
1633 1633
24DO199-04 MW-4 [Water] Sampled 4/23/2024 1:43:001PM
1633 1633
24DO199-05 MW-5 [Water] Sampled 4/23/2024 11:55:00AM
1633 1633
24DO199-06 MW-6 [Water] Sampled 4/23/2024 12:29:OOPM
1633 1633
24DO199-07 MW-7 [Water] Sampled 4/23/2024 10:38:OOAM
1633 1633
24DO199-08 MW-7D [Water] Sampled 4/23/2024 10:20:OOAM
1633 1633
24DO199-09 SW-1 [Water] Sampled 4/23/2024 2:20:OOPM
1633 1633
24DO199-10 SW-2 [Water] Sampled 4/23/2024 11:20:OOAM
1633 1633
24DO199-11 SW-3 [Water] Sampled 4/23/2024 10:30:OOAM
1633 1633
Samples subcontracted to: Pace Lab - SC
24DO199-04 MW-4 [Water] Sampled 4/23/2024 1:43:OOPM
1633 Subcontract NONE
WORK ORDER
24D0199
Printed: 05/16/2024 10:47 am
Project: Person County landfill; STD TAT; L2 REPORT; NCDEQ ED
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is allowed, except in its entirety.
Page 38 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Waypoint Analytical Project: 6034 Person Co. Landfill
114 Oakmont Drive Project Number: 6034 Person Co. Landfill
Greenville, NC 27858 Project Manager: Ann Baynor Reported: 05/16/2024 10:47
Analysis
Comments
Samples subcontracted to: Pace Lab - SC
24DO199-05 MW-5 [Water] Sampled
4/23/2024 11:55:OOAM
1633 Subcontract
NONE
Project: Person County landfill; STD TAT; L2 REPORT; NCDEQ ED
24DO199
Sample Receipt Log
Default Cooler
Samples Received at: 1.3°C
Custody Seals
No
Were all containers sealed in separate bags?
Yes
Containers Intact
Yes
Did all containers arrive in good condition?
Yes
COC/Labels Agree
Yes
Correct containers/preserv.for tests indicated?
Yes
Preservation Confirmed
Yes
Sufficient volume sent for tests requested?
Yes
Received On Ice
Yes
VOA vials for volatiles analysis of water are bubb
Yes
Was a chain of custody received?
Yes
Sufficient remaining holding time for analyses?
Yes
COCs complete/signed in the appropriate places?
Yes
pH of non -VOA preserved containers documented?
No
Sample labels complete? Sample ID, date/time, etc.
Yes
Unpreserved vials received for VOA analysis?
No
Did all container labels agree with COCs?
Yes
If "yes", are unpreserved VOA vials noted on Work
No
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document
No duplication of this report is allowed, except in its entirety. Page 39 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
waypomt. —
Waypoint Analytical - Greenville
114 Oakmont Dr.
Greenville, NC 27858 DISINFECTION
www.WaypointAnalytical.com
Phone [phone] • Fax [phone] Ij CHLORINE
CLIENT: 6034 Week:5
PERSON COUNTY LANDFILL
MR. RAY FOUSHEE
SOLID WASTE COORDINATOR
304 S. MORGAN ST. ROOM 222
ROXBORO NC 27573
[phone]
SAMPLE LOCATION
MW-1
MW-2
MW-3
MW-4
MW-5
MW-6
MW-7
MW-7D
Sw-I
SW-2
SW-3
REL CUISHED BY
VR�LINQ I HED BY
R LINQUISHED BY
COLLECTION
DATE TIME
tip 9f
�� 35
2Z�
it -Z;"11
UV
NONE
�z
eo
uj O
Z �
C�
Z
cn
Cc
LU
J
O
O U
M O
H U
z
2 H
O ¢
tY _j
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n-o
0
0 0
`�" a
0
RECE1.YED BY (SIGH
RECEIVED BY (SIG.)
BY (SIG.)
CHAIN OF CUSTODY RECORD /2Lna IZICI
M
10 en
w
a
u81 r_/ i nvic COMMENTS: A 1
IN
1;77 Mw.i, Via,)
DATE/TIME -!
DATFJTIME MW -1 rA W -q/ m W
J
a
a
Q
O
w
m
m
cn
vAk (-I SCA
Table of Contents
t
Page 1 of 2
CHLORINE CHECK (LAB)
<0.5 mg/L - Yes (Y) or No (N)
pH CHECK (S.U.) (LAB)
CONTAINER TYPE, P/G
CHEMICAL PRESERVATION
C/'
A -NONE
D-NAOH
LU
LU
B-HNO3
E-HCL
LU
w
C - H2SO4
F - ZINC ACETATE/NAOH
G - NATHIOSULFATE
n
CLASSIFICATION:
Ij WASTEWATER(NPDES)
Ij DRINKINGWATER
DWR/GW
SOLID WASTE SECTION
CHAIN OF CUSTODY (SEAL) MAINTAINED
DURING SHIPMENT/DELIVERY
Q2 N
SAMPLES COLLECTED BY:
(Please Print) kejIo,,.\
p� rrcl� D. cInzw u.. TA11,04
A/, I r:- M
SAMPLES RECEIVED IN LAB AT 3 S °C
SAMPLES RECEIVED ON ICE:0 - NO
1z✓2� ,
PLEASE READ Instructions for completing this form on the reverse side. Sampler must place a "C" for composite sample or a "G" for Page 40 of 42
FORM #5 Grab sample in the blocks above for each parameter requested.

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Table of Contents
No Custody Seal
Page 41 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-BO7C-628B4E2B85E4
Table of Contents
AP P.L.
AGRICULTURE & PRIORITY POLLUTANTS LABORATORIES
ho A METIRI GROUP COMPANY
Sending Laboratory:
APPL, LLC
908 N. Temperance Ave.
Clovis, CA 93611
Phone: [phone]
Fax: [phone]
Project Manager: Chue Moua
SUBCONTRACT
ORDER
Subcontracted Laboratory:
Pace Lab - SC
106 Vantage Point Drive
West Columbia, SC 29172
Phone: [phone]
Fax:
Requires Foreign Soil Permit: 4as li®,
"'6 54'tM
Work Order: 24DO199
Analysis Comments
Sample ID: 24DO199-04 Water Sampled. • 0412312024 13.43
1633 Subcontract
Containers Supplied. -
Project: Person County landfill; STD TAT; L2 REPORT;
NCDEQ EDD; REPORT and INVOICE to SMITH GARDNER,
INC.
Sample ID: 24DO199-05 Water Sampled: 0412312024 11.55
1633 Subcontract Project: Person County landfill; STD TAT; L2 REPORT;
NCDEQ EDD; REPORT and INVOICE to SMITH GARDNER,
INC.
Containers Supplied.
Ref'. Dete: 06May24
Dep: Wgt: 10.00 LEIS
DV' -
Svcs: PRIORITY OVERNIGHT
TRC K: 71331004 2120
C 6
Date
SHIPPING: 66.13
SPECIAL: 11.75
HANDLING: 0.00
0.00 TOTAL: 79.88
Received By
Page 1 of 1
Date
Page 42 of 42

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
ti eurofins I U
Environment Testing
I ANALYTICAL REPORT C
PREPARED FOR
Attn: Joan Smyth
Smith Gardner Inc
14 N Boylan Avenue C
Raleigh, North Carolina 27603
Generated 9/6/2024 3:34:03 PM
JOB DESCRIPTION
Person County
JOB NUMBER
752-23537-1

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
This report may not be reproduced except in full, and with written approval from the laboratory. The results relate only to the
samples tested. For questions please contact the Project Manager at the e-mail address or telephone number listed on this
page.
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the
methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written
approval of the laboratory. All questions should be directed to the Eurofins Environment Testing Southeast, LLC Project
Manager.
Generated
,6#o Ut 9/6/2024 3:34:03 PM
Authorized for release by
Heather Trotter, Project Manager
Heather.Trotter(_)et.eurofinsus.com
[phone]
Eurofins Raleigh is a laboratory within Eurofins Environment Testing Southeast, LLC, a company within Eurofins Environment Testing Group of Companies
Page 2 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Client: Smith Gardner Inc
Project/Site: Person County
Table of Contents
Laboratory Job ID: 752-23537-1
Cover Page ..............................................
1
Table of Contents .........................................
3
Definitions/Glossary.......................................
4 L
Case Narrative ...........................................
5
Detection Summary ........................................
7
Client Sample Results ......................................
8
Isotope Dilution Summary ...................................
14
QC Sample Results ........................................
17
QC Association Summary ...................................
33 C
Lab Chronicle ............................................
34
Certification Summary ......................................
35
Method Summary .........................................
37
Sample Summary .........................................
38
Chain of Custody ..........................................
39
Receipt Checklists .........................................
41
Eurofins Raleigh
Page 3 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Definitions/Glossary
Client: Smith Gardner Inc Job ID: 752-23537-1
Project/Site: Person County
Qualifiers
LCMS
Qualifier Qualifier Description
LCS and/or LCSD is outside acceptance limits, low biased.
*+ LCS and/or LCSD is outside acceptance limits, high biased.
*1 LCS/LCSD RPD exceeds control limits.
B Compound was found in the blank and sample.
I Value is EMPC (estimated maximum possible concentration).
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Glossary
Abbreviation These commonly used abbreviations may or may not be present in this report.
c Listed under the "D" column to designate that the result is reported on a dry weight basis
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
oil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Lever'
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MOIL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins Raleigh
Page 4 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Case Narrative
Client: Smith Gardner Inc Job ID: 752-23537-1
Project: Person County
Job ID: 752-23537-1 Eurofins Raleigh
Job Narrative
752-23537-1 '
Analytical test results meet all requirements of the associated regulatory program listed on the Accreditation/Certification Summary
Page unless otherwise noted under the individual analysis. Data qualifiers and/or narrative comments are included to explain any
exceptions, if applicable.
Matrix QC may not be reported if insufficient sample is provided or site -specific QC samples were not submitted. In these
situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD may be performed, unless otherwise
specified in the method.
Surrogate and/or isotope dilution analyte recoveries (if applicable) which are outside of the QC window are confirmed
unless attributed to a dilution or otherwise noted in the narrative.
Regulated compliance samples (e.g. SDWA, NPDES) must comply with the associated agency requirements/permits.
Receipt
The samples were received on 8/27/2024 3:00 PM. Unless otherwise noted below, the samples arrived in good condition, and,
where required, properly preserved and on ice. The temperature of the cooler at receipt time was 3.8°C.
PFAS
Method 1633: The continuing calibration verification (CCV) associated with batch 680-854043 exhibited % difference of > 30% for
the following analyte(s)3-Perfluoroheptylpropanoic acid (7:3 FTCA); however, the results were within the LCS acceptance limits.
The EPA method requires that all target analytes in the continuing calibration verification standard be within 30% difference from
the initial calibration. According to the laboratory standard operating procedure, the continuing calibration is acceptable if it meets
the laboratory control sample acceptance criteria.
Method 1633: The laboratory control sample, the laboratory control sample duplicate, and low level laboratory control sample
(LCS/LCSD/LLCS) for preparation batch 680-853778 and analytical batch 680-854043 recovered outside control limits for the
following analyte(s): 9-Chlorohexadecafluoro-3-oxanonane-1-sulfonic acid(9CI-PF3ONS). 9-Chlorohexadecafluoro-3-
oxanonane-1-sulfonic acid (9CI-PF3ONS) has been identified as a poor performing analyte when analyzed using this method;
therefore, re-extraction/re-analysis was not performed.
Method 1633: The following sample was diluted due to the nature of the sample matrix: MW-4 (752-23537-1) at 500x. Elevated
reporting limits (RLs) are provided.
Method 1633: The following sample was diluted due to the nature of the sample matrix: MW-5 (752-23537-2) at 50x. Elevated
reporting limits (RLs) are provided.
Method 1633: The laboratory control sample, the laboratory control sample duplicate, and low level laboratory control sample
(LCS/LCSD/LLCS) for preparation batch 680-854427 and analytical batch 680-854573 recovered outside control limits for the
following analyte(s): Perfluorododecanesulfonic acid (PFDoS), 9-Chlorohexadecafluoro-3-oxanonane-1-sulfonic acid(9CI-PF3ONS)
and 11-Chloroeicosafluoro-3-oxaundecane-1-sulfonic acid (11Cl-PF30UdS). The analyte(s) has/have been identified as a poor
performing analyte when analyzed using this method; therefore, re-extraction/re-analysis was not performed.
Method 1633: The laboratory control sample duplicate (LCSD) for preparation batch 680-854427 and analytical batch 680-854573
recovered outside control limits for the following analytes: Perfluorodecanesulfonic acid (PFDS). A low-level LCS (LLCS), spiked at
the reporting limit (RL), was prepared with this batch. The affected target analytes recovered within acceptance limits; therefore,
the LLCS demonstrates the analytical system had sufficient sensitivity to detect the compounds had they been present. Since the
affected target compounds were not detected in the samples, the data have been reported and qualified.
Method 1633: The laboratory control sample duplicate (LCSD) for preparation batch 680-854427 and analytical batch 680-854573
recovered outside control limits for the following analytes: Perfluorotridecanoic acid (PFTrDA). These analytes were biased high in
the LCSD and were not detected in the associated samples; therefore, the data have been reported.
Method 1633: The method blank for preparation batch 680-854427 and analytical batch 680-854573 contained Perfluorohexanoic
acid (PFHxA) above the method detection limit. This target analyte concentration was less than the reporting limit (RL) in the
method blank; therefore, re -extraction and/or re -analysis of samples was not performed.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/ Glossary page.
Eurofins Raleigh
Page 5 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Case Narrative
Client: Smith Gardner Inc Job ID: 752-23537-1
Project: Person County
Job ID: 752-23537-1 (Continued) Eurofins Raleiah
0
Eurofins Raleigh
Page 6 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Detection Summary
Client: Smith Gardner Inc
Project/Site: Person County
Client Sample ID: MW-4
Job ID: 752-23537-1
Lab Sample ID: 752-23537-1
Analyte
Result
Qualifier
RL
MDL
Unit
Dil Fac D
Method
Prep Type
Perfluorobutanoic acid (PFBA) - RE
1900
1900
480
ng/L
1
1633
Total/NA
Perfluoropentanoic acid (PFPeA) - RE
4600
950
240
ng/L
1
1633
Total/NA
Perfluorohexanoic acid (PFHxA) - RE
13000
B
950
48
ng/L
1
1633
Total/NA
Perfluoroheptanoic acid (PFHpA) - RE
22000
950
240
ng/L
1
1633
Total/NA
Perfluorooctanoic acid (PFOA) - RE
94000
950
240
ng/L
1
1633
Total/NA
Perfluorononanoic acid (PFNA) - RE
980
1
950
48
ng/L
1
1633
Total/NA
Perfluorobutanesulfonic acid (PFBS) -
7000
950
240
ng/L
1
1633
Total/NA
RE
Perfluoropentanesulfonic acid
7300
950
48
ng/L
1
1633
Total/NA
(PFPeS) - RE
Perfluorohexanesulfonic acid (PFHxS)
16000
950
240
ng/L
1
1633
Total/NA
-RE
Perfluoroheptanesulfonic acid
1200
950
48
ng/L
1
1633
Total/NA
(PFHpS)-RE
Perfluorooctanesulfonic acid (PFOS) -
11000
950
240
ng/L
1
1633
Total/NA
RE
Client Sample ID: MW-5
Lab Sample ID: 752-23537-2
Analyte
Result
Qualifier
RL
MDL
Unit
oil Fac D
Method
Prep Type
Pernuorononanoic acid (PFNA)
12
1.4
0.071
ng/L
1
1633
Total/NA
Pernuorooctanesulfonic acid (PFOS)
120
1.4
0.36
ng/L
1
1633
Total/NA
1H,1H,2H,2H-PerFluorooctanesulfonic
2.4
J
2.8
0.36
ng/L
1
1633
Total/NA
acid (6:2 FTS)
1H,1H,2H,2H-PerFluorodecane
0.59
J
2.8
0.36
ng/L
1
1633
Total/NA
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
0.26
J 1
1.4
0.071
ng/L
1
1633
Total/NA
N-methylperfluorooctanesulfonamidoa
10
1.4
0.36
ng/L
1
1633
Total/NA
cetic acid (NMeFOSAA)
Perfluorobutanoic acid (PFBA) - RE
390
190
49
ng/L
1
1633
Total/NA
Perfluoropentanoic acid (PFPeA) - RE
820
97
24
ng/L
1
1633
Total/NA
Perfluorohexanoic acid (PFHxA) - RE
1900
B
97
4.9
ng/L
1
1633
Total/NA
Perfluoroheptanoic acid (PFHpA) - RE
2100
97
24
ng/L
1
1633
Total/NA
Perfluorooctanoic acid (PFOA) - RE
3600
97
24
ng/L
1
1633
Total/NA
Perfluorobutanesulfonic acid (PFBS) -
880
97
24
ng/L
1
1633
Total/NA
RE
Perfluoropentanesulfonic acid
410
97
4.9
ng/L
1
1633
Total/NA
(PFPeS) - RE
Perfluorohexanesulfonic acid (PFHxS)
380
97
24
ng/L
1
1633
Total/NA
RE
Client Sample ID: Field Blank
Lab
Sample
ID: 752-23537-3
[ No Detections
This Detection Summary does not include radiochemical test results.
Eurofins Raleigh
Page 7 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Person County
Job ID: 752-23537-1
Client Sample ID: MW-4 Lab Sample ID: 752-23537-1
Date Collected: 08/27/24 00:00 Matrix: Water
Date Received: 08/27/24 15:00
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Analyte Result Qualifier RL
- RE
MDL
Unit
D Prepared
Analyzed
Dil Fac
Perfluorobutanoic acid (PFBA)
1900
1900
480
ng/L
09/04/24 14:03
09/05/24 16:34
1
Perfluoropentanoic acid (PFPeA)
4600
950
240
ng/L
09/04/24 14:03
09/05/24 16:34
1
Perfluorohexanoic acid (PFHxA)
13000 B
950
48
ng/L
09/04/24 14:03
09/05/24 16:34
1
Perfluoroheptanoic acid (PFHpA)
22000
950
240
ng/L
09/04/24 14:03
09/05/24 16:34
1
Perfluorooctanoic acid (PFOA)
94000
950
240
ng/L
09/04/24 14:03
09/05/24 16:34
1
Perfluorononanoic acid (PFNA)
980 1
950
48
ng/L
09/04/24 14:03
09/05/24 16:34
1
Perfluorodecanoic acid (PFDA)
<48
950
48
ng/L
09/04/24 14:03
09/05/24 16:34
1
Perfluoroundecanoic acid (PFUnA)
<240
950
240
ng/L
09/04/24 14:03
09/05/24 16:34
1
Perfluorododecanoic acid (PFDoA)
<240
950
240
ng/L
09/04/24 14:03
09/05/24 16:34
1
Perfluorotridecanoic acid (PFTrDA)
<240 *+
950
240
ng/L
09/04/24 14:03
09/05/24 16:34
1
Perfluorotetradecanoic acid (PFTA)
<240
950
240
ng/L
09/04/24 14:03
09/05/24 16:34
1
Perfluorobutanesulfonic acid
7000
950
240
ng/L
09/04/24 14:03
09/05/24 16:34
1
(PFBS)
Perfluoropentanesulfonic acid
7300
950
48
ng/L
09/04/24 14:03
09/05/24 16:34
1
(PFPeS)
Perfluorohexanesulfonic acid
16000
950
240
ng/L
09/04/24 14:03
09/05/24 16:34
1
(PFHxS)
Perfluoroheptanesulfonic acid
1200
950
48
ng/L
09/04/24 14:03
09/05/24 16:34
1
(PFHpS)
Perfluorooctanesulfonic acid
11000
950
240
ng/L
09/04/24 14:03
09/05/24 16:34
1
(PFOS)
Perfluorononanesulfonic acid (PFNS)
<48
950
48
ng/L
09/04/24 14:03
09/05/24 16:34
1
Perfluorododecanesulfonic acid
<240 *- *1
950
240
ng/L
09/04/24 14:03
09/05/24 16:34
1
(PFDoS)
11-1,11-1,2H,21-1-Perfluorohexane
<240
1900
240
ng/L
09/04/24 14:03
09/05/24 16:34
1
sulfonic acid (4:2 FTS)
1H,1H,2H,2H-Perfluorooctanesulfonic
<240
1900
240
ng/L
09/04/24 14:03
09/05/24 16:34
1
acid (6:2 FTS)
11-1,11-1,2H,21-1-Perfluorodecane
<240
1900
240
ng/L
09/04/24 14:03
09/05/24 16:34
1
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<48
950
48
ng/L
09/04/24 14:03
09/05/24 16:34
1
N-methylperfluorooctane sulfonamide
<240
950
240
ng/L
09/04/24 14:03
09/05/24 16:34
1
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<240
950
240
ng/L
09/04/24 14:03
09/05/24 16:34
1
(NETOSA)
N-methylperfluorooctanesulfonamidoa
<240
950
240
ng/L
09/04/24 14:03
09/05/24 16:34
1
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<240
950
240
ng/L
09/04/24 14:03
09/05/24 16:34
1
etic acid (NEtFOSAA)
N-methylperfluorooctane
<950
4800
950
ng/L
09/04/24 14:03
09/05/24 16:34
1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<950
4800
950
ng/L
09/04/24 14:03
09/05/24 16:34
1
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide Dimer
<240
710
240
ng/L
09/04/24 14:03
09/05/24 16:34
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<240
950
240
ng/L
09/04/24 14:03
09/05/24 16:34
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<240
950
240
ng/L
09/04/24 14:03
09/05/24 16:34
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<240
950
240
ng/L
09/04/24 14:03
09/05/24 16:34
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<240 *-
950
240
ng/L
09/04/24 14:03
09/05/24 16:34
1
e-1-sulfonic acid (9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<360 *-
950
360
ng/L
09/04/24 14:03
09/05/24 16:34
1
e-1-sulfonic acid (11Cl-PF30UdS)
Eurofins Raleigh
Page 8 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Person County
F
Job ID: 752-23537-1
Client Sample ID: MW-4 Lab Sample ID: 752-23537-1
Date Collected: 08/27/24 00:00 Matrix: Water
Date Received: 08/27/24 15:00
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS - RE (Continued)
Analyte
Result Qualifier
RL
MDL
Unit
Perfluoro (2-ethoxyethane) sulfonic
<240
950
240
ng/L
acid (PFEESA)
3-Perfluoropropylpropanoic acid (3:3
<480
1900
480
ng/L
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<1300
4800
1300
ng/L
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<1300
4800
1300
ng/L
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<48 *-
950
48
ng/L
Perfluoro-3-methoxypropanoic acid
<240
950
240
ng/L
(PFMPA)
Isotope Dilution
%Recovery Qualifier
Limits
13C4 PFBA
73.1
5 - 130
13C5 PFPeA
80.0
40 - 130
13C5 PFHxA
77.5
40 - 130
13C4 PFHpA
76.4
40 - 130
13C8 PFOA
81.0
40 - 130
13C9 PFNA
89.1
40 - 130
13C6 PFDA
83.3
40 - 130
13C7 PFUnA
69.2
30 - 130
13C2 PFDoA
57.8
10 - 130
13C2 PFTeDA
44.6
10 - 130
13C3 PFBS
92.9
40 - 135
13C3 PFHxS
76.4
40 - 130
13C8 PFOS
97.5
40 - 130
13C8 FOSA
75.9
40 - 130
d3-NMeFOSAA
81.8
40 - 170
d5-NEtFOSAA
78.4
25 - 135
M2-4:2 FTS
103
40 - 200
M2-6:2 FTS
76.1
40 - 200
M2-8:2 FTS
128
40 - 300
13C3 HFPO-DA
93.4
40 - 130
d7-N-McFOSE-M
75.5
10 - 130
d9-N-EtFOSE-M
68.8
10 - 130
d5-NEtPFOSA
75.0
10 - 130
d3-NMePFOSA
73.1
10 - 130
D Prepared Analyzed Dil Fac
09/04/2414:03 09/05/2416:34 1
09/04/2414:03 09/05/2416:34 1
09/04/2414:03 09/05/2416:34
09/04/2414:03 09/05/2416:34
09/04/2414:03 09/05/2416:34
09/04/2414:03 09/05/2416:34
Prepared
Analyzed
09104124 14:03
09105124 16:34
09104124 14:03
09105124 16:34
09104124 14:03
09105124 16:34
09104124 14:03
09105124 16:34
09104124 14:03
09105124 16:34
09104124 14:03
09105124 16:34
09104124 14:03
09105124 16:34
09104124 14:03
09105124 16:34
09104124 14:03
09105124 16:34
09104124 14:03
09/05/24 16:34
09104124 14:03
09/05/24 16:34
09104124 14:03
09/05/24 16:34
09104124 14:03
09105124 16:34
09104124 14:03
09105124 16:34
09104124 14:03
09105124 16:34
09104124 14:03
09105124 16:34
09104124 14:03
09105124 16:34
09104124 14:03
09105124 16:34
09104124 14:03
09105124 16:34
09104124 14:03
09105124 16:34
09104124 14:03
09105124 16:34
09104124 14:03
09105124 16:34
09104124 14:03
09105124 16:34
09104124 14:03
09105124 16:34
Eurofins Raleigh
Page 9 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Person County
Job ID: 752-23537-1
Client Sample ID: MW-5 Lab Sample ID: 752-23537-2
Date Collected: 08/27/24 00:00 Matrix: Water
Date Received: 08/27/24 15:00
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Analyte
Result Qualifier
RL
Perfluorononanoic acid (PFNA)
12
1.4
Perfluorodecanoic acid (PFDA)
<0.071
1.4
Perfluoroundecanoic acid (PFUnA)
<0.36
1.4
Perfluorododecanoic acid (PFDoA)
<0.36
1.4
Perfluorotridecanoic acid (PFTrDA)
<0.36
1.4
Perfluorotetradecanoic acid (PFTA)
<0.36
1.4
Perfluoroheptanesulfonic acid
<0.071
1.4
(PFHpS)
Perfluorooctanesulfonic acid
120
1.4
(PFOS)
Perfluorononanesulfonic acid (PFNS)
<0.071
1.4
Perfluorododecanesulfonic acid
<0.36
1.4
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
<0.36
2.8
sulfonic acid (4:2 FTS)
1H,111,211,211-1-Perfluorooctane
2.4 J
2.8
sulfonic acid (6:2 FTS)
1H,1H,2H,2H-Perfluorodecane
0.59 J
2.8
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide
0.26 J 1
1.4
(PFOSA)
N-methylperfluorooctane sulfonamide
<0.36
1.4
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<0.36
1.4
(NEtFOSA)
N-methylperfluorooctanesulfona
10
1.4
midoacetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<0.36
1.4
etic acid (NEtFOSAA)
N-methylperfluorooctane
<1.4
7.1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<1.4
7.1
sulfonamidoethanol (NEtFOSE)
Perfluorodecanesulfonic acid (PFDS)
<0.071
1.4
Isotope Dilution
%Recovery Qualifier
Limits
13C9 PFNA
81.1
40 - 130
13C6 PFDA
72.2
40 - 130
13C7 PFUnA
59.1
30 - 130
13C2 PFDoA
56.9
10 - 130
13C2 PFTeDA
49.1
10 - 130
13C3 PFHxS
72.9
40 - 130
13C8 PFOS
91.0
40 - 130
13C8 FOSA
87.3
40 - 130
d3-NMeFOSAA
82.2
40 - 170
d5-NEtFOSAA
74.7
25 - 135
M2-4:2 FTS
102
40 - 200
M2-6:2 FTS
70.9
40 - 200
M2-8:2 FTS
92.2
40 - 300
d7-N-McFOSE-M
83.4
10 - 130
d9-N-EtFOSE-M
71.5
10 - 130
d5-NEtPFOSA
92.0
10 - 130
d3-NMePFOSA
84.1
10 - 130
MDL
Unit
D Prepared
Analyzed
0.071
ng/L
08/29/24 10:36
08/30/24
20:59
0.071
ng/L
08/29/24 10:36
08/30/24
20:59
0.36
ng/L
08/29/24 10:36
08/30/24
20:59
0.36
ng/L
08/29/24 10:36
08/30/24
20:59
0.36
ng/L
08/29/24 10:36
08/30/24
20:59
0.36
ng/L
08/29/24 10:36
08/30/24
20:59
0.071
ng/L
08/29/24 10:36
08/30/24
20:59
0.36
ng/L
08/29/24 10:36
08/30/24
20:59
0.071
ng/L
08/29/24 10:36
08/30/24
20:59
0.36
ng/L
08/29/24 10:36
08/30/24
20:59
0.36
ng/L
08/29/24 10:36
08/30/24
20:59
0.36
ng/L
08/29/24 10:36
08/30/24
20:59
0.36
ng/L
08/29/24 10:36
08/30/24
20:59
0.071
ng/L
08/29/24 10:36
08/30/24
20:59
0.36
ng/L
08/29/24 10:36
08/30/24
20:59
0.36
ng/L
08/29/24 10:36
08/30/24
20:59
0.36
ng/L
08/29/24 10:36
08/30/24
20:59
0.36
ng/L
08/29/24 10:36
08/30/24
20:59
1.4
ng/L
08/29/24 10:36
08/30/24
20:59
1.4
ng/L
08/29/24 10:36
08/30/24
20:59
0.071
ng/L
08/29/24 10:36
08/30/24
20:59
Prepared
Analyzed
08/29/24 10.36
08130124
20:59
08/29/24 10:36
08130124
20:59
08/29/24 10:36
08130124
20:59
08129124 10:36
08130124
20:59
08129124 10:36
08130124
20:59
08129124 10:36
08/30/24
20:59
08/29/24 10:36
08130124
20:59
08129124 10:36
08130124
20:59
08129124 10:36
08130124
20:59
08/29/24 10:36
08130124
20:59
08/29/24 10:36
08/30/24
20:59
08/29/24 10:36
08130124
20:59
08/29/24 10:36
08130124
20:59
08/29/24 10:36
08130124
20:59
08/29/24 10:36
08130124
20:59
08129124 10:36
08130124
20:59
08129124 10:36
08130124
20:59
Eurofins Raleigh
Page 10 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Person County
F
Job ID: 752-23537-1
Client Sample ID: MW-5
Date Collected: 08/27/24 00:00
Date Received: 08/27/24 15:00
Lab Sample ID: 752-23537-2
Matrix: Water
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
- RE
Analyte
Result Qualifier
RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Perfluorobutanoic acid (PFBA)
390
190
49
ng/L
09/04/24 14:03
09/05/24 16:50
1
Perfluoropentanoic acid (PFPeA)
820
97
24
ng/L
09/04/24 14:03
09/05/24 16:50
1
Perfluorohexanoic acid (PFHxA)
1900 B
97
4.9
ng/L
09/04/24 14:03
09/05/24 16:50
1
Perfluoroheptanoic acid (PFHpA)
2100
97
24
ng/L
09/04/24 14:03
09/05/24 16:50
1
Perfluorooctanoic acid (PFOA)
3600
97
24
ng/L
09/04/24 14:03
09/05/24 16:50
1
Perfluorobetanesulfonic acid
880
97
24
ng/L
09/04/24 14:03
09/05/24 16:50
1
(PFBS)
Perfluoropentanesulfonic acid
410
97
4.9
ng/L
09/04/24 14:03
09/05/24 16:50
1
(PFPeS)
Perfluorohexanesulfonic acid
380
97
24
ng/L
09/04/24 14:03
09/05/24 16:50
1
(PFHxS)
Hexafluoropropylene Oxide Dimer
<24
73
24
ng/L
09/04/24 14:03
09/05/24 16:50
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<24
97
24
ng/L
09/04/24 14:03
09/05/24 16:50
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<24
97
24
ng/L
09/04/24 14:03
09/05/24 16:50
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<24
97
24
ng/L
09/04/24 14:03
09/05/24 16:50
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<24 '-
97
24
ng/L
09/04/24 14:03
09/05/24 16:50
1
e-1-sulfonic acid (9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<37 `-
97
37
ng/L
09/04/24 14:03
09/05/24 16:50
1
e-1-sulfonic acid (11Cl-PF30UdS)
Perfluoro (2-ethoxyethane) sulfonic
<24
97
24
ng/L
09/04/24 14:03
09/05/24 16:50
1
acid (PFEESA)
3-Perfluoropropylpropanoic acid (3:3
<49
190
49
ng/L
09/04/24 14:03
09/05/24 16:50
1
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<130
490
130
ng/L
09/04/24 14:03
09/05/24 16:50
1
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<130
490
130
ng/L
09/04/24 14:03
09/05/24 16:50
1
FTCA)
Perfluoro-3-methoxypropanoic acid
<24
97
24
ng/L
09/04/24 14:03
09/05/24 16:50
1
(PFMPA)
Isotope Dilution
%Recovery Qualifier
Limits
Prepared
Analyzed
Dil Fac
13C4 PFBA
73.2
5-130
09104124 14:03
09/05/24 16:50
1
13C5 PFPeA
85.2
40 - 130
09/04/24 14:03
09/05/24 16:50
1
13C5 PFHxA
82.4
40 - 130
09/04/24 14:03
09/05/24 16:50
1
13C4 PFHpA
80.6
40 - 130
09104124 14:03
09105124 16:50
1
13CB PFOA
78.2
40 - 130
09104124 14:03
09105124 16:50
1
13C3 PFBS
91.9
40 - 135
09104124 14:03
09105124 16:50
1
13C3 PFHxS
72.9
40 - 130
09104124 14:03
09105124 16:50
1
13C3 HFPO-DA
93.0
40 - 130
09104124 14:03
09105124 16:50
1
Eurofins Raleigh
Page 11 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Person County
Job ID: 752-23537-1
Client Sample ID: Field Blank Lab Sample ID: 752-23537-3
Date Collected: 08/27/24 00:00 Matrix: Water
Date Received: 08/27/24 15:00
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Analyte Result Qualifier RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Perfluorobutanoic acid (PFBA)
<0.73
2.9
0.73
ng/L
08/29/24 10:36
08/30/24 21:15
1
Perfluoropentanoic acid (PFPeA)
<0.37
1.5
0.37
ng/L
08/29/24 10:36
08/30/24 21:15
1
Perfluorohexanoic acid (PFHxA)
<0.073
1.5
0.073
ng/L
08/29/24 10:36
08/30/24 21:15
1
Perfluoroheptanoic acid (PFHpA)
<0.37
1.5
0.37
ng/L
08/29/24 10:36
08/30/24 21:15
1
Perfluorooctanoic acid (PFOA)
<0.37
1.5
0.37
ng/L
08/29/24 10:36
08/30/24 21:15
1
Perfluoronenanoic acid (PFNA)
<0.073
1.5
0.073
ng/L
08/29/24 10:36
08/30/24 21:15
1
Perfluorodecanoic acid (PFDA)
<0.073
1.5
0.073
ng/L
08/29/24 10:36
08/30/24 21:15
1
Perfluoroundecanoic acid (PFUnA)
<0.37
1.5
0.37
ng/L
08/29/24 10:36
08/30/24 21:15
1
Perfluorododecanoic acid (PFDoA)
<0.37
1.5
0.37
ng/L
08/29/24 10:36
08/30/24 21:15
1
Perfluorotridecanoic acid (PFTrDA)
<0.37
1.5
0.37
ng/L
08/29/24 10:36
08/30/24 21:15
1
Perfluorotetradecanoic acid (PFTA)
<0.37
1.5
0.37
ng/L
08/29/24 10:36
08/30/24 21:15
1
Perfluorooutanesulfonic acid (PFBS)
<0.37
1.5
0.37
ng/L
08/29/24 10:36
08/30/24 21:15
1
Perfluoropentanesulfonic acid
<0.073
1.5
0.073
ng/L
08/29/24 10:36
08/30/24 21:15
1
(PFPeS)
Perfluorohexanesulfonic acid (PFHxS)
<0.37
1.5
0.37
ng/L
08/29/24 10:36
08/30/24 21:15
1
Perfluoroheptanesulfonic acid
<0.073
1.5
0.073
ng/L
08/29/24 10:36
08/30/24 21:15
1
(PFHpS)
Perfluorooctanesulfonic acid (PFOS)
<0.37
1.5
0.37
ng/L
08/29/24 10:36
08/30/24 21:15
1
Perfluorononanesulfonic acid (PFNS)
<0.073
1.5
0.073
ng/L
08/29/24 10:36
08/30/24 21:15
1
Perfluorododecanesulfonic acid
<0.37
1.5
0.37
ng/L
08/29/24 10:36
08/30/24 21:15
1
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
<0.37
2.9
0.37
ng/L
08/29/24 10:36
08/30/24 21:15
1
sulfonic acid (4:2 FTS)
1 H,1 H,2H,2H-Perfluorooctane sulfonic
<0.37
2.9
0.37
ng/L
08/29/24 10:36
08/30/24 21:15
1
acid (6:2 FTS)
1H,11H,21H,21H-Perfluorodecane
<0.37
2.9
0.37
ng/L
08/29/24 10:36
08/30/24 21:15
1
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.073
1.5
0.073
ng/L
08/29/24 10:36
08/30/24 21:15
1
N-methylperfluorooctane sulfonamide
<0.37
1.5
0.37
ng/L
08/29/24 10:36
08/30/24 21:15
1
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<0.37
1.5
0.37
ng/L
08/29/24 10:36
08/30/24 21:15
1
(N EtFOSA)
N-methylperfluorooctanesulfonamidoa
<0.37
1.5
0.37
ng/L
08/29/24 10:36
08/30/24 21:15
1
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<0.37
1.5
0.37
ng/L
08/29/24 10:36
08/30/24 21:15
1
etic acid (NEtFOSAA)
N-methylperfluorooctane
<1.5
7.3
1.5
ng/L
08/29/24 10:36
08/30/24 21:15
1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<1.5
7.3
1.5
ng/L
08/29/24 10:36
08/30/24 21:15
1
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide Dimer
<0.37
1.1
0.37
ng/L
08/29/24 10:36
08/30/24 21:15
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<0.37
1.5
0.37
ng/L
08/29/24 10:36
08/30/24 21:15
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<0.37
1.5
0.37
ng/L
08/29/24 10:36
08/30/24 21:15
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<0.37
1.5
0.37
ng/L
08/29/24 10:36
08/30/24 21:15
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<0.37 *-
1.5
0.37
ng/L
08/29/24 10:36
08/30/24 21:15
1
e-1-sulfonic acid(9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<0.55
1.5
0.55
ng/L
08/29/24 10:36
08/30/24 21:15
1
e-1-sulfonic acid (11Cl-PF30UdS)
Perfluoro (2-ethoxyethane) sulfonic
<0.37
1.5
0.37
ng/L
08/29/24 10:36
08/30/24 21:15
1
acid (PFEESA)
Eurofins Raleigh
Page 12 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Person County
F
Job ID: 752-23537-1
Client Sample ID: Field Blank Lab Sample ID: 752-23537-3
Date Collected: 08/27/24 00:00 Matrix: Water
Date Received: 08/27/24 15:00
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Analyte
Result Qualifier
RL
MDL
Unit
3-Perfluoropropylpropanoic acid (3:3
<0.73
2.9
0.73
ng/L
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<2.0
7.3
2.0
ng/L
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<2.0
7.3
2.0
ng/L
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.073
1.5
0.073
ng/L
Perfluoro-3-methoxypropanoic acid
<0.37
1.5
0.37
ng/L
(PFMPA)
Isotope Dilution
%Recovery Qualifier
Limits
13C4 PFBA
64.3
5 - 130
13C5 PFPeA
74.4
40 - 130
13C5 PFHxA
77.6
40 - 130
13C4 PFHpA
64.5
40 - 130
13C8 PFOA
73.8
40 - 130
13C9 PFNA
81.9
40 - 130
13C6 PFDA
72.3
40 - 130
13C7 PFUnA
56.0
30 - 130
13C2 PFDoA
55.8
10 - 130
13C2 PFTeDA
46.2
10 - 130
13C3 PFBS
87.6
40 - 135
13C3 PFHxS
73.6
40 - 130
13C8 PFOS
95.3
40 - 130
13C8 FOSA
89.9
40 - 130
d3-NMeFOSAA
82.3
40 - 170
d5-NEtFOSAA
72.8
25 - 135
M2-4:2 FTS
82.8
40 - 200
M2-6:2 FTS
74.0
40 - 200
M2-8:2 FTS
87.1
40 - 300
13C3 HFPO-DA
67.4
40 - 130
d7-N-McFOSE-M
85.2
10 - 130
d9-N-EtFOSE-M
80.1
10 - 130
d5-NEtPFOSA
94.6
10 - 130
d3-NMePFOSA
86.9
10 - 130
D Prepared Analyzed Dil Fac
08/29/24 10:36 08/30/24 21:15 1
•
08/29/24 10:36 08/30/24 21:15 1
08/29/24 10:36 08/30/24 21:15
08/29/24 10:36 08/30/24 21:15
08/29/24 10:36 08/30/24 21:15
Prepared
Analyzed
08129124 10:36
08130124 21:15
08129124 10:36
08130124 21:15
08/29/24 10:36
08130124 21:15
08/29/24 10:36
08130124 21:15
08129124 10:36
08130124 21:15
08129124 10:36
08130124 21:15
08/29/24 10:36
08/30/24 21:15
08/29/24 10:36
08/30/24 21:15
08/29/24 10:36
08/30/24 21:15
08/29/24 10:36
08130124 21:15
08/29/24 10:36
08130124 21:15
08/29/24 10:36
08130124 21:15
08129124 10:36
08130124 21:15
08129124 10:36
08130124 21:15
08129124 10:36
08130124 21:15
08/29/24 10:36
08130124 21:15
08129124 10:36
08130124 21:15
08/29/24 10:36
08130124 21:15
08/29/24 10:36
08130124 21:15
08/29/24 10:36
08130124 21:15
08/29/24 10:36
08130124 21:15
08/29/24 10:36
08130124 21:15
08/29/24 10:36
08130124 21:15
08/29/24 10:36
08130124 21:15
Eurofins Raleigh
Page 13 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Isotope Dilution Summary
Client: Smith Gardner Inc
Job ID: 752-23537-1
Project/Site: Person County
Method: 1633 - Per- and
Polyfluoroalkyl
Substances by LC/MS/MS
Matrix: Water
Prep Type: Total/NA
Percent Isotope
Dilution Recovery
(Acceptance Limits)
PFBA
PFPeA
13C5PHA
C4PFHA
C8PFOA
C9PFNA
C6PFDA
13C7PUA
Lab Sample ID
Client Sample ID
(5-130)
(40-130)
(40-130)
(40-130)
(40-130)
(40-130)
(40-130)
(30-130)
752-23537-1 - RE
MW-4
73.1
80.0
77.5
76.4
81.0
89.1
83.3
69.2
752-23537-2
MW-5
81.1
72.2
59.1
752-23537-2 - RE
MW-5
73.2
85.2
82.4
80.6
78.2
752-23537-3
Field Blank
64.3
74.4
77.6
64.5
73.8
81.9
72.3
56.0
LCS 680-853778/2-A
Lab Control Sample
69.2
82.7
78.2
72.3
75.8
88.3
75.4
66.8
LCS 680-854427/2-A
Lab Control Sample
73.4
81.8
80.2
81.9
79.6
89.3
85.1
72.2
LCSD 680-853778/3-A
Lab Control Sample Dup
66.5
77.9
73.1
68.8
70.6
85.3
71.0
63.3
LCSD 680-854427/3-A
Lab Control Sample Dup
72.6
81.4
83.6
79.5
78.0
92.2
81.6
69.2
MB 680-853778/1-A
Method Blank
69.1
79.0
76.5
71.4
71.7
88.5
75.2
67.2
MB 680-854427/1-A
Method Blank
74.6
80.7
83.9
84.5
80.7
93.0
88.2
73.1
Percent Isotope
Dilution Recovery (Acceptance Limits)
PFDoA
PFTDA
C3PFBS
C3PFHS
C8PFOS
PFOSA
d3NMFOS
d5NEFOS
Lab Sample ID
Client Sample ID
(10-130)
(10-130)
(40-135)
(40-130)
(40-130)
(40-130)
(40-170)
(25-135)
752-23537-1 - RE
MW-4
57.8
44.6
92.9
76.4
97.5
75.9
81.8
78.4
752-23537-2
MW-5
56.9
49.1
72.9
91.0
87.3
82.2
74.7
752-23537-2 - RE
MW-5
91.9
72.9
752-23537-3
Field Blank
55.8
46.2
87.6
73.6
95.3
89.9
82.3
72.8
LCS 680-853778/2-A
Lab Control Sample
67.8
59.1
89.6
73.6
91.5
93.9
90.8
79.9
LCS 680-854427/2-A
Lab Control Sample
57.3
43.8
94.1
78.2
97.6
71.1
81.7
73.9
LCSD 680-853778/3-A
Lab Control Sample Dup
63.8
53.9
87.2
72.2
87.1
97.7
93.5
81.2
LCSD 680-854427/3-A
Lab Control Sample Dup
55.3
30.1
86.4
73.3
92.2
71.2
75.5
68.9
MB 680-853778/1-A
Method Blank
67.7
64.7
92.7
76.5
96.2
97.9
97.4
85.7
MB 680-854427/1-A
Method Blank
58.6
35.3
89.0
74.6
102
71.9
83.3
75.5
Percent Isotope
Dilution Recovery
(Acceptance Limits)
M242FTS
M262FTS
M282FTS
HFPODA
NMFM
NEFM
d5NPFSA
d3NMFSA
Lab Sample ID
Client Sample ID
(40-200)
(40-200)
(40-300)
(40-130)
(10-130)
(10-130)
(10-130)
(10-130)
752-23537-1 - RE
MW-4
103
76.1
128
93.4
75.5
68.8
75.0
73.1
752-23537-2
MW-5
102
70.9
92.2
83.4
71.5
92.0
84.1
752-23537-2 - RE
MW-5
93.0
752-23537-3
Field Blank
82.8
74.0
87.1
67.4
85.2
80.1
94.6
86.9
LCS 680-853778/2-A
Lab Control Sample
84.8
76.8
99.3
79.3
99.7
85.6
101
94.5
LCS 680-854427/2-A
Lab Control Sample
89.1
67.0
137
90.7
76.8
64.5
60.8
61.2
LCSD 680-853778/3-A
Lab Control Sample Dup
83.8
77.6
97.7
75.0
104
89.4
110
96.5
LCSD 680-854427/3-A
Lab Control Sample Dup
85.8
68.7
135
92.3
76.1
65.1
59.9
58.9
MB 680-853778/1-A
Method Blank
93.4
84.4
106
77.5
103
94.2
106
101
MB 680-854427/1-A
Method Blank
93.5
71.5
153
95.6
76.5
70.0
65.6
64.0
Surrogate Legend
PFBA = 13C4 PFBA
PFPeA = 13C5 PFPeA
13C5PHA= 13C5 PFHxA
C4PFHA = 13C4 PFHpA
C8PFOA = 13C8 PFOA
C9PFNA = 13C9 PFNA
C6PFDA = 13C6 PFDA
13C7PUA= 13C7 PFUnA
PFDoA = 13C2 PFDoA
PFTDA= 13C2 PFTeDA
C3PFBS = 13C3 PFBS
Eurofins Raleigh
Page 14 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Isotope Dilution Summary
Client: Smith Gardner Inc
Project/Site: Person County
C3PFHS = 13C3 PFHxS
C8PFOS = 13C8 PFOS
PFOSA = 13C8 FOSA
d3NMFOS = d3-NMeFOSAA
d5NEFOS = d5-NEtFOSAA
M242FTS = M2-4:2 FTS
M262FTS = M2-6:2 FTS
M282FTS = M2-8:2 FTS
HFPODA= 13C3 HFPO-DA
NMFM = d7-N-McFOSE-M
NEFM = d9-N-EtFOSE-M
d5NPFSA = d5-NEtPFOSA
d3NMFSA = d3-NMePFOSA
Job ID: 752-23537-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Matrix: Water
Prep Type:
Total/NA
Percent Isotope Dilution Recovery
(Acceptance Limits)
PFBA
PFPeA 13C5PHA
C4PFHA
C8PFOA
C9PFNA
C6PFDA
13C7PUA
Lab Sample ID Client Sample ID
(25-130)
(40.130) (40-130)
(40.130)
(40-130)
(40.130)
(40-130)
(30.130)
LLCS 680-853778/4-A Lab Control Sample
67.3
81.8 76.7
71.4
74.1
86.8
75.7
66.7
LLCS 680-854427/4-A Lab Control Sample
74.0
77.2 79.1
79.3
77.7
90.3
86.4
72.6
Lab Sample ID Client Sample ID
LLCS 680-853778/4-A Lab Control Sample
LLCS 680-854427/4-A Lab Control Sample
Lab Sample ID
LLCS 680-853778/4-A
LLCS 680-854427/4-A
Surrogate Legend
PFBA = 13C4 PFBA
PFPeA= 13C5 PFPeA
13C5PHA = 13C5 PFHxA
C4PFHA= 13C4 PFHpA
C8PFOA = 13C8 PFOA
C9PFNA= 13C9 PFNA
C6PFDA= 13C6 PFDA
13C7PUA = 13C7 PFUnA
PFDoA = 13C2 PFDoA
PFTDA= 13C2 PFTeDA
C3PFBS = 13C3 PFBS
C3PFHS = 13C3 PFHxS
C8PFOS = 13C8 PFOS
PFOSA = 13C8 FOSA
d3NMFOS = d3-NMeFOSAA
d5NEFOS = d5-NEtFOSAA
M242FTS = M2-4:2 FTS
M262FTS = M2-6:2 FTS
M282FTS = M2-8:2 FTS
HFPODA= 13C3 HFPO-DA
NMFM = d7-N-McFOSE-M
NEFM = d9-N-EtFOSE-M
Percent Isotope Dilution Recovery (Acceptance Limits)
PFDoA
PFTDA
C3PFBS
C3PFHS
C8PFOS
PFOSA d3NMFOS
d5NEFOS
(10-130)
(10-130)
(40-135)
(40-130)
(40-130)
(40-130) (40-170)
(25-135)
67.7
60.2
91.2
76.0
99.8
101 100
87.5
57.7
36.9
91.1
73.2
100
69.5 84.4
78.7
Percent Isotope Dilution Recovery (Acceptance Limits)
M242FTS
M262FTS M282FTS
HFPODA
NMFM
NEFM d5NPFSA
d3NMFSA
Client Sample ID (40-200)
(40-200) (40-300)
(40-130)
(10-130)
(10-130) (10-130)
(10-130)
Lab Control Sample 92.7
82.9 106
78.0
111
92.6 113
108
Lab Control Sample 93.0
73.9 128
87.0
71.1
62.8 54.7
55.5
Page 15 of 42
Eurofins Raleigh
9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Isotope Dilution Summary
Client: Smith Gardner Inc Job ID: 752-23537-1
Project/Site: Person County
d5NPFSA = d5-NEtPFOSA
L d3NMFSA=d3-NMePFOSA
Eurofins Raleigh
Page 16 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Person County
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
C
Job ID: 752-23537-1
FLab Sample ID: MB 680-853778/1-A
Client Sample ID: Method
Blank
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 854043
Prep Batch:
853778
MB
MB
Analyte
Result
Qualifier RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Perfluorobutanoic acid (PFBA)
<1.0
4.0
1.0
ng/L
08/29/24 10:36
08/30/24 15:51
1
Perfluoropentanoic acid (PFPeA)
<0.50
2.0
0.50
ng/L
08/29/24 10:36
08/30/24 15:51
1
Perfluorohexanoic acid (PFHxA)
<0.10
2.0
0.10
ng/L
08/29/24 10:36
08/30/24 15:51
1
Perfluoroheptanoic acid (PFHpA)
<0.50
2.0
0.50
ng/L
08/29/24 10:36
08/30/24 15:51
1
Perfluorooctanoic acid (PFOA)
<0.50
2.0
0.50
ng/L
08/29/24 10:36
08/30/24 15:51
1
•
Perfluorononanoic acid (PFNA)
<0.10
2.0
0.10
ng/L
08/29/24 10:36
08/30/24 15:51
1
Perfluorodecanoic acid (PFDA)
<0.10
2.0
0.10
ng/L
08/29/24 10:36
08/30/24 15:51
1
Perfluoroundecanoic acid (PFUnA)
<0.50
2.0
0.50
ng/L
08/29/24 10:36
08/30/24 15:51
1
Perfluorododecanoic acid (PFDoA)
<0.50
2.0
0.50
ng/L
08/29/24 10:36
08/30/24 15:51
1
Perfluorotridecanoic acid (PFTrDA)
<0.50
2.0
0.50
ng/L
08/29/24 10:36
08/30/24 15:51
1
Perfluorotetradecanoic acid (PFTA)
<0.50
2.0
0.50
ng/L
08/29/24 10:36
08/30/24 15:51
1
Perfluorobutanesulfonic acid (PFBS)
<0.50
2.0
0.50
ng/L
08/29/24 10:36
08/30/24 15:51
1
Perfluoropentanesulfonic acid
<0.10
2.0
0.10
ng/L
08/29/24 10:36
08/30/24 15:51
1
(PFPeS)
Perfluorohexanesulfonic acid (PFHxS)
<0.50
2.0
0.50
ng/L
08/29/24 10:36
08/30/24 15:51
1
Perfluoroheptanesulfonic acid
<0.10
2.0
0.10
ng/L
08/29/24 10:36
08/30/24 15:51
1
(PFHpS)
Perfluorooctanesulfonic acid (PFOS)
<0.50
2.0
0.50
ng/L
08/29/24 10:36
08/30/24 15:51
1
Perfluorononanesulfonic acid (PFNS)
<0.10
2.0
0.10
ng/L
08/29/24 10:36
08/30/24 15:51
1
Perfluorododecanesulfonic acid
<0.50
2.0
0.50
ng/L
08/29/24 10:36
08/30/24 15:51
1
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
<0.50
4.0
0.50
ng/L
08/29/24 10:36
08/30/24 15:51
1
sulfonic acid (4:2 FTS)
1H,1H,2H,2H-Perfluorooctanesulfonic
<0.50
4.0
0.50
ng/L
08/2912410:36
08/3012415:51
1
acid (6:2 FTS)
1H,1H,2H,2H-Perfluorodecane
<0.50
4.0
0.50
ng/L
08/29/24 10:36
08/30/24 15:51
1
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.10
2.0
0.10
ng/L
08/29/24 10:36
08/30/24 15:51
1
N-methylperfluorooctane sulfonamide
<0.50
2.0
0.50
ng/L
08/29/24 10:36
08/30/24 15:51
1
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<0.50
2.0
0.50
ng/L
08/29/24 10:36
08/30/24 15:51
1
(NEtFOSA)
N-methylperfluorooctanesulfonamidoa
<0.50
2.0
0.50
ng/L
08/29/24 10:36
08/30/24 15:51
1
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<0.50
2.0
0.50
ng/L
08/29/24 10:36
08/30/24 15:51
1
etic acid (NEtFOSAA)
N-methylperfluorooctane
<2.0
10
2.0
ng/L
08/2912410:36
08/3012415:51
1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<2.0
10
2.0
ng/L
08/29/24 10:36
08/30/24 15:51
1
sulfonamidoethanol (NETOSE)
Hexafluoropropylene Oxide Dimer
<0.50
1.5
0.50
ng/L
08/29/24 10:36
08/30/24 15:51
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<0.50
2.0
0.50
ng/L
08/29/24 10:36
08/30/24 15:51
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<0.50
2.0
0.50
ng/L
08/29/24 10:36
08/30/24 15:51
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<0.50
2.0
0.50
ng/L
08/29/24 10:36
08/30/24 15:51
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<0.50
2.0
0.50
ng/L
08/29/24 10:36
08/30/24 15:51
1
e-1-sulfonic acid(9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<0.75
2.0
0.75
ng/L
08/29/24 10:36
08/30/24 15:51
1
e-1-sulfonic acid (11CI-PF30UdS)
Eurofins Raleigh
Page 17 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
QC Sample Results
Client: Smith Gardner Inc
Job ID: 752-23537-1
Project/Site: Person County
Method: 1633 - Per- and Polyfluoroalkyl Substances
by LC/MS/MS (Continued)
Lab Sample ID: MB 680-853778/1-A
Client Sample ID: Method Blank
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 854043
Prep Batch: 853778
MB
MB
Analyte
Result
Qualifier
RL
MDL Unit
D Prepared
Analyzed Dil Fac
Perfluoro (2-ethoxyethane) sulfonic
<0.50
2.0
0.50 ng/L
08/29/24 10:36
08/30/24 15:51 1
acid (PFEESA)
3-Perfluoropropylpropanoic acid (3:3
<1.0
4.0
1.0 ng/L
08/29/24 10:36
08/30/24 15:51 1
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<2.7
10
2.7 ng/L
08/29/24 10:36
08/30/24 15:51 1
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<2.7
10
2.7 ng/L
08/29/24 10:36
08/30/24 15:51 1
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.10
2.0
0.10 ng/L
08/29/24 10:36
08/30/24 15:51 1
Perfluoro-3-methoxypropanoic acid
<0.50
2.0
0.50 ng/L
08/29/24 10:36
08/30/24 15:51 1
(PFMPA)
MB
MB
Isotope Dilution
%Recovery
Qualifier
Limits
Prepared
Analyzed Dil Fac
13C4 PFBA
69.1
5 - 130
08/29/24 10:36
08/30/24 15:51 1
13C5 PFPeA
79.0
40 - 130
08/29/24 10:36
08130124 15:51 1
13C5 PFHxA
76.5
40 - 130
08/29/24 10:36
08/30/24 15:51 1
13C4 PFHpA
71.4
40 - 130
08/29/24 10:36
08/30/24 15:51 1
13C8 PFOA
71.7
40 - 130
08/29/24 10:36
08/30/24 15:51 1
13C9 PFNA
88.5
40 - 130
08/29/24 10:36
08/30/24 15:51 1
13C6 PFDA
75.2
40 - 130
08/29/24 10:36
08/30/24 15:51 1
13C7 PFUnA
67.2
30 - 130
08/29/24 10:36
08/30/24 15:51 1
13C2 PFDoA
67.7
10 - 130
08/29/24 10:36
08/30/24 15:51 1
13C2 PFTeDA
64.7
10 - 130
08129124 10:36
08130124 15:51 1
13C3 PFBS
92.7
40 - 135
08129124 10:36
08130124 15:51 1
13C3 PFHxS
76.5
40 - 130
08129124 10:36
08130124 15:51 1
13C8 PFOS
96.2
40 - 130
08/29/24 10:36
08/30/24 15:51 1
13C8 FOSA
97.9
40 - 130
08/29/24 10:36
08130124 15:51 1
d3-NMeFOSAA
97.4
40 - 170
08/29/24 10:36
08130124 15:51 1
d5-NEtFOSAA
85.7
25 - 135
08/29/24 10:36
08130124 15:51 1
M2-4:2 FTS
93.4
40 - 200
08/29/24 10:36
08/30/24 15:51 1
M2-6:2 FTS
84.4
40 - 200
08/29/24 10:36
08130124 15:51 1
M2-8:2 FTS
106
40 - 300
08/29/24 10.36
08/30/24 15:51 1
13C3 HFPO-DA
77.5
40 - 130
08/29/24 10.36
08/30/24 15:51 1
d7-N-McFOSE-M
103
10 - 130
08/29/24 10.36
08/30/24 15:51 1
d9-N-EtFOSE-M
94.2
10 - 130
08/29/24 10:36
08/30/24 15:51 1
d5-NEtPFOSA
106
10 - 130
08/29/24 10:36
08/30/24 15:51 1
d3-NMePFOSA
101
10 - 130
08/29/24 10:36
08130124 15:51 1
Lab Sample ID: LCS 680-853778/2-A
Client Sample ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 854043
Prep Batch: 853778
Spike
LCS LCS
%Rec
Analyte
Added
Result Qualifier Unit
D %Rec
Limits
Perfluorobutanoic acid (PFBA)
64.0
54.4 ng/L
85
70 - 140
Perfluoropentanoic acid (PFPeA)
32.0
29.2 ng/L
91
65 - 135
Perfluorohexanoic acid (PFHxA)
32.0
28.6 ng/L
89
70 - 145
Perfluoroheptanoic acid (PFHpA)
32.0
31.5 ng/L
98
70 - 150
Perfluorooctanoic acid (PFOA)
32.0
23.3 ng/L
73
70 - 150
Perfluorononanoic acid (PFNA)
32.0
25.6 ng/L
80
70 - 150
Perfluorodecanoic acid (PFDA)
32.0
31.9 ng/L
100
70 - 140
Eurofins Raleigh
Page 18 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Person County
F
Job ID: 752-23537-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LCS 680-853778/2-A
Client Sample
ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 854043
Prep Batch: 853778
Spike
LCS LCS
%Rec
Analyte
Added
Result Qualifier
Unit
D %Rec
Limits
Perfluoroundecanoic acid
32.0
32.8
ng/L
103
70 - 145
(PFUnA)
Perfluorododecanoic acid
32.0
29.3
ng/L
91
70 - 140
(PFDoA)
Perfluorotridecanoic acid
32.0
35.6
ng/L
111
65 - 140
(PFTrDA)
Perfluorotetradecanoic acid
32.0
28.7
ng/L
90
60 - 140
(PFTA)
Perfluorobutanesulfonic acid
28.4
24.8
ng/L
87
60 - 145
(PFBS)
Perfluoropentanesulfonic acid
30.1
31.2
ng/L
104
65 - 140
(PFPeS)
Perfluorohexanesulfonic acid
29.2
25.3
ng/L
87
65 - 145
(PFHxS)
Perfluoroheptanesulfonic acid
30.5
32.6
ng/L
107
70 - 150
(PFHpS)
Perfluorooctanesulfonic acid
29.8
28.2
ng/L
95
55 - 150
(PFOS)
Perfluorononanesulfonic acid
30.8
25.2
ng/L
82
65 - 145
(PFNS)
Perfluorododecanesulfonic acid
31.0
21.3
ng/L
69
50 - 145
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
60.0
55.4
ng/L
92
70-145
sulfonic acid (4:2 FTS)
1H,1H,21H,21H-Perfluorooctane
60.9
55.5
ng/L
91
65-155
sulfonic acid (6:2 FTS)
1 H,1 H,2H,2H-Perfluorodecane
61.4
49.7
ng/L
81
60-150
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide
32.0
28.2
ng/L
88
70 - 145
(PFOSA)
N-methylperfluorooctane
32.0
32.3
ng/L
101
60 - 150
sulfonamide (NMeFOSA)
N-ethylperfluorooctane
32.0
27.4
ng/L
86
65 - 145
sulfonamide (NEtFOSA)
N-methylperfluorooctanesulfona
32.0
38.7
ng/L
121
50 - 140
midoacetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonami
32.0
30.0
ng/L
94
70 - 145
doacetic acid (NEtFOSAA)
N-methylperfluorooctane
160
136
ng/L
85
70 - 145
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
160
175
ng/L
110
70 - 135
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide
24.0
21.0
ng/L
88
70 - 140
DimerAcid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic
30.3
27.5
ng/L
91
65 - 145
acid (ADONA)
Perfluoro-4-methoxybutanoic
32.0
30.1
ng/L
94
60 - 150
acid (PFMBA)
Nonafluoro-3,6-dioxaheptanoic
32.0
35.0
ng/L
109
50 - 150
acid (NFDHA)
9-Chlorohexadecafluoro-3-oxan
29.9
20.3 *-
ng/L
68
70 - 155
onane-1-sulfonic
acid(9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaund
30.2
20.2
ng/L
67
55-160
ecane-1-sulfonic acid
(11 CI-PHOWS)
Eurofins Raleigh
Page 19 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Person County
F
Job ID: 752-23537-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LCS 680-853778/2-A
Client Sample
ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 854043
Prep Batch: 853778
Spike
LCS
LCS
%Rec
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits
Perfluoro (2-ethoxyethane)
28.5
24.5
ng/L
86
70 - 140
sulfonic acid (PFEESA)
3-Perfluoropropylpropanoic acid
64.0
59.3
ng/L
93
65 - 130
(3:3 FTCA)
3-Perfluoropentylpropanoic acid
160
135
ng/L
84
70 - 135
(5:3 FTCA)
3-Perfluoroheptylpropanoic acid
160
99.2
ng/L
62
50 - 145
(7:3 FTCA)
Perfluorodecanesulfonic acid
30.8
26.6
ng/L
86
60 - 145
(PFDS)
Perfluoro-3-methoxypropanoic
32.0
31.3
ng/L
98
55 - 140
acid (PFMPA)
LCS LCS
Isotope Dilution %Recovery Qualifier
Limits
13C4 PFBA
69.2
5 - 130
13C5 PFPeA
82.7
40 - 130
13C5 PFHxA
78.2
40 - 130
13C4 PFHpA
72.3
40 - 130
13C8 PFOA
75.8
40 - 130
13C9 PFNA
88.3
40 - 130
13C6 PFDA
75.4
40 - 130
13C7 PFUnA
66.8
30 - 130
13C2 PFDoA
67.8
10 - 130
13C2 PFTeDA
59.1
10 - 130
13C3 PFBS
89.6
40 - 135
13C3 PFHxS
73.6
40 - 130
13C8 PFOS
91.5
40 - 130
13C8 FOSA
93.9
40 - 130
d3-NMeFOSAA
90.8
40 - 170
d5-NEtFOSAA
79.9
25 - 135
M2-4:2 FTS
84.8
40 - 200
M2-6:2 FTS
76.8
40 - 200
M2-8:2 FTS
99.3
40 - 300
13C3 HFPO-DA
79.3
40 - 130
d7-N-McFOSE-M
99.7
10 - 130
d9-N-EtFOSE-M
85.6
10 - 130
d5-NEtPFOSA
101
10 - 130
d3-NMePFOSA
94.5
10 - 130
Lab Sample ID: LCSD 680-853778/3-A
Client
Sample ID: Lab Control Sample Dup
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 854043
Prep Batch: 853778
Spike
LCSD
LCSD
%Rec RPD
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits RPD Limit
Perfluorobutanoic acid (PFBA)
64.0
58.3
ng/L
91
70 - 140 7 30
Perfluoropentanoic acid (PFPeA)
32.0
31.0
ng/L
97
65 - 135 6 30
Perfluorohexanoic acid (PFHxA)
32.0
30.2
ng/L
94
70 - 145 6 30
Perfluoroheptanoic acid (PFHpA)
32.0
32.8
ng/L
103
70 - 150 4 30
Perfluorooctanoic acid (PFOA)
32.0
24.7
ng/L
77
70 - 150 6 30
Perfluorononanoic acid (PFNA)
32.0
27.1
ng/L
85
70 - 150 6 30
Eurofins Raleigh
Page 20 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Person County
F
Job ID: 752-23537-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LCSD 680-853778/3-A
Client Sample ID: Lab Control
Sample Dup
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 854043
Prep Batch: 853778
Spike
LCSD LCSD
%Rec
RPD
Analyte
Added
Result Qualifier
Unit
D %Rec
Limits
RPD
Limit
Perfluorodecanoic acid (PFDA)
32.0
33.6
ng/L
105
70 - 140
5
30
Perfluoroundecanoic acid
32.0
35.2
ng/L
110
70 - 145
7
30
(PFUnA)
Perfluorododecanoic acid
32.0
31.2
ng/L
98
70 - 140
6
30
(PFDoA)
Perfluorotridecanoicacld
32.0
38.6
ng/L
121
65 - 140
8
30 �
(PFTrDA)
Perfluorotetradecanoic acid
32.0
30.0
ng/L
94
60 - 140
4
30
(PFTA)
Perfluorobutanesulfonic acid
28.4
26.0
ng/L
91
60 - 145
5
30
(PFBS)
Perfluoropentanesulfonic acid
30.1
32.5
ng/L
108
65 - 140
4
30
(PFPeS)
Perfluorohexanesulfonic acid
29.2
26.8
ng/L
92
65 - 145
6
30
(PFHxS)
Perfluoroheptanesulfonic acid
30.5
35.4
ng/L
116
70. 150
8
30
(PFHpS)
Perfluorooctanesulfonic acid
29.8
31.3
ng/L
105
55 - 150
10
30
(PFOS)
Perfluorononanesulfonic acid
30.8
27.3
ng/L
89
65 - 145
8
30
(PFNS)
Perfluorododecanesulfonic acid
31.0
22.5
ng/L
73
50 - 145
5
30
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
60.0
60.2
ng/L
100
70-145
8
30
sulfonic acid (4:2 FTS)
1H,11-1,2H,21-1-Perfluorooctane
60.9
58.6
ng/L
96
65-155
5
30
sulfonic acid (6:2 FTS)
1 H,1 H,2H,2H-Perfluorodecane
61.4
55.5
ng/L
90
60-150
11
30
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide
32.0
31.3
ng/L
98
70 - 145
10
30
(PFOSA)
N-methylperfluorooctane
32.0
35.8
ng/L
112
60 - 150
10
30
sulfonamide (NMeFOSA)
N-ethylperfluorooctane
32.0
28.8
ng/L
90
65 - 145
5
30
sulfonamide (NEtFOSA)
N-methylperfluorooctanesulfona
32.0
41.5
ng/L
130
50 - 140
7
30
midoacetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonami
32.0
32.0
ng/L
100
70 - 145
6
30
doacetic acid (NEtFOSAA)
N-methylperfluorooctane
160
153
ng/L
96
70 - 145
12
30
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
160
199
ng/L
125
70 - 135
13
30
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide
24.0
23.1
ng/L
96
70 - 140
9
30
DimerAcid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic
30.3
29.1
ng/L
96
65 - 145
6
30
acid (ADONA)
Perfluoro-4-methoxybutanoic
32.0
32.3
ng/L
101
60 - 150
7
30
acid (PFMBA)
Nonafluoro-3,6-dioxaheptanoic
32.0
38.4
ng/L
120
50 - 150
9
30
acid (NFDHA)
9-Chlorohexadecafluoro-3-oxan
29.9
20.1 1 '-
ng/L
67
70 - 155
1
30
onane-1-sulfonic
acid(9CI-PF30NS)
Eurofins Raleigh
Page 21 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Person County
F
Job ID: 752-23537-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LCSD 680-853778/3-A
Client
Sample ID: Lab Control Sample Dup
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 854043
Prep Batch: 853778
Spike
LCSD
LCSD
%Rec RPD
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits RPD Limit
11-Chloroeicosafluoro-3-oxaund
30.2
20.4
ng/L
68
55-160 1 30
ecane-1-sulfonic acid
(11 CI-PF3OUdS)
Perfluoro (2-ethoxyethane)
28.5
26.0
ng/L
91
70 - 140 6 30
sulfonic acid (PFEESA)
3-Perfluoropropylpropanoic acid
64.0
62.4
ng/L
97
65 - 130 5 30 •
(3:3 FTCA)
3-Perfluoropentylpropanoic acid
160
143
ng/L
89
70 - 135 6 30
(5:3 FTCA)
3-Perfluoroheptylpropanoic acid
160
108
ng/L
68
50 - 145 9 30
(7:3 FTCA)
Perfluorodecanesulfonic acid
30.8
29.0
ng/L
94
60 - 145 9 30
(PFDS)
Perfluoro-3-methoxypropanoic
32.0
33.4
ng/L
104
55 - 140 7 30
acid (PFMPA)
LCSD LCSD
Isotope Dilution %Recovery Qualifier
Limits
13C4 PFBA
66.5
5 - 130
13C5 PFPeA
77.9
40 - 130
13C5 PFHxA
73.1
40 - 130
13C4 PFHpA
68.8
40 - 130
13C8 PFOA
70.6
40 - 130
13C9 PFNA
85.3
40 - 130
13C6 PFDA
71.0
40 - 130
13C7 PFUnA
63.3
30 - 130
13C2 PFDoA
63.8
10 - 130
13C2 PFTeDA
53.9
10 - 130
13C3 PFBS
87.2
40 - 135
13C3 PFHxS
72.2
40 - 130
13C8 PFOS
87.1
40 - 130
13C8 FOSA
97.7
40 - 130
d3-NMeFOSAA
93.5
40 - 170
d5-NEtFOSAA
81.2
25 - 135
M2-4:2 FTS
83.8
40 - 200
M2-6:2 FTS
77.6
40 - 200
M2-8:2 FTS
97.7
40 - 300
13C3 HFPO-DA
75.0
40 - 130
d7-N-McFOSE-M
104
10 - 130
d9-N-EtFOSE-M
89.4
10 - 130
d5-NEtPFOSA
110
10 - 130
d3-NMePFOSA
96.5
10 - 130
Lab Sample ID: LLCS 680-853778/4-A
Client Sample
ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 854043
Prep Batch: 853778
Spike
LLCS
LLCS
%Rec
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits
Perfluorobutanoic acid (PFBA)
8.00
7.08
ng/L
88
70 - 140
Perfluoropentanoic acid (PFPeA)
4.00
3.71
ng/L
93
65 - 135
Perfluorohexanoic acid (PFHxA)
4.00
3.72
ng/L
93
70 - 145
Perfluoroheptanoic acid (PFHpA)
4.00
4.06
ng/L
101
70 - 150
Eurofins Raleigh
Page 22 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Person County
F
Job ID: 752-23537-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LLCS 680-853778/4-A
Client Sample
ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 854043
Prep Batch: 853778
Spike
LLCS LLCS
%Rec
Analyte
Added
Result Qualifier
Unit
D %Rec
Limits
Perfluorooctanoic acid (PFOA)
4.00
3.37
ng/L
84
70 - 150
Perfluorononanoic acid (PFNA)
4.00
3.32
ng/L
83
70 - 150
Perfluorodecanoic acid (PFDA)
4.00
3.89
ng/L
97
70 - 140
Perfluoroundecanoic acid
4.00
4.14
ng/L
104
70 - 145
(PFUnA)
Perfluorododecanoic acid
4.00
3.75
ng/L
94
70 - 140 •
(PFDoA)
Perfluorotridecanoic acid
4.00
4.36
ng/L
109
65 - 140
(PFTrDA)
Perfluorotetradecanoic acid
4.00
3.56
ng/L
89
60 - 140
(PFTA)
Perfluorobutanesulfonic acid
3.55
3.09
ng/L
87
60 - 145
(PFBS)
Perfluoropentanesulfonic acid
3.76
4.06
ng/L
108
65 - 140
(PFPeS)
Perfluorohexanesulfonic acid
3.65
3.15
ng/L
86
65 - 145
(PFHxS)
Perfluoroheptanesulfonic acid
3.82
3.84
ng/L
101
70 - 150
(PFHpS)
Perfluorooctanesulfonic acid
3.72
3.62
ng/L
97
55 - 150
(PFOS)
Perfluorononanesulfonic acid
3.85
3.19
ng/L
83
65 - 145
(PFNS)
Perfluorododecanesulfonic acid
3.87
2.66
ng/L
69
50 - 145
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
7.50
7.05
ng/L
94
70-145
sulfonic acid (4:2 FTS)
1H,11-1,2H,21-1-Perfluorooctane
7.62
8.39
ng/L
110
65-155
sulfonic acid (6:2 FTS)
1 H,1 H,2H,2H-Perfluorodecane
7.68
6.79
ng/L
88
60-150
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide
4.00
3.58
ng/L
90
70 - 145
(PFOSA)
N-methylperfluorooctane
4.00
4.11
ng/L
103
60 - 150
sulfonamide (NMeFOSA)
N-ethylperfluorooctane
4.00
3.36
ng/L
84
65 - 145
sulfonamide (NEtFOSA)
N-methylperfluorooctanesulfona
4.00
5.12
ng/L
128
50 - 140
midoacetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonami
4.00
3.80
ng/L
95
70 - 145
doacetic acid (NEtFOSAA)
N-methylperfluorooctane
20.0
16.2
ng/L
81
70 - 145
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
20.0
23.4
ng/L
117
70 - 135
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide
3.00
2.76
ng/L
92
70 - 140
DimerAcid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic
3.78
3.38
ng/L
89
65 - 145
acid (ADONA)
Perfluoro-4-methoxybutanoic
4.00
3.75
ng/L
94
60 - 150
acid (PFMBA)
Nonafluoro-3,6-dioxaheptanoic
4.00
3.96
ng/L
99
50 - 150
acid (NFDHA)
Eurofins Raleigh
Page 23 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Person County
Job ID: 752-23537-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by
LC/MS/MS (Continued)
Lab Sample ID: LLCS 680-853778/4-A
Client Sample ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 854043
Prep Batch: 853778
Spike
LLCS
LLCS
%Rec
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits
9-Chlorohexadecafluoro-3-oxan
3.74
2.56
1 "-
ng/L
69
70 - 155
onane-1-sulfonic
acid (9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaund
3.78
2.62
ng/L
69
55-160
ecane-1-sulfonic acid
(11 CI-PF3OUdS)
Perfluoro (2-ethoxyethane)
3.57
3.06
ng/L
86
70 - 140
sulfonic acid (PFEESA)
3-Perfluoropropylpropanoic acid
8.00
7.53
ng/L
94
65 - 130
(3:3 FTCA)
3-Perfluoropentylpropanoic acid
20.0
16.8
ng/L
84
70 - 135
(5:3 FTCA)
3-Perfluoroheptylpropanoic acid
20.0
12.7
ng/L
63
50 - 145
(7:3 FTCA)
Perfluorodecanesulfonic acid
3.86
3.35
ng/L
87
60 - 145
(PFDS)
Perfluoro-3-methoxypropanoic
4.00
3.94
ng/L
98
55 - 140
acid (PFMPA)
LLCS LLCS
Isotope Dilution %Recovery Qualifier
Limits
13C4 PFBA
67.3
25 - 130
13C5 PFPeA
81.8
40 - 130
13C5 PFHxA
76.7
40 - 130
13C4 PFHpA
71.4
40 - 130
13C8 PFOA
74.1
40 - 130
13C9 PFNA
86.8
40 - 130
13C6 PFDA
75.7
40 - 130
13C7 PFUnA
66.7
30 - 130
13C2 PFDoA
67.7
10 - 130
13C2 PFTeDA
60.2
10 - 130
13C3 PFBS
91.2
40 - 135
13C3 PFHxS
76.0
40 - 130
13C8 PFOS
99.8
40 - 130
13C8 FOSA
101
40 - 130
d3-NMeFOSAA
100
40 - 170
d5-NEtFOSAA
87.5
25 - 135
M2-4:2 FTS
92.7
40 - 200
M2-6:2 FTS
82.9
40 - 200
M2-8:2 FTS
106
40 - 300
13C3 HFPO-DA
78.0
40 - 130
d7-N-McFOSE-M
111
10 - 130
d9-N-EtFOSE-M
92.6
10 - 130
d5-NEtPFOSA
113
10 - 130
d3-NMePFOSA
108
10 - 130
Lab Sample ID: MB 680-854427/1-A
Client Sample ID: Method Blank
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 854573
Prep Batch: 854427
MB MB
Analyte
Result Qualifier
RL
MDL Unit
D Prepared
Analyzed Dil Fac
Perfluorobutanoic acid (PFBA)
<1.0
4.0
1.0 ng/L
09/04/24 14:03
09/05/24 13:45 1
Eurofins Raleigh
Page 24 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Person County
F
Job ID: 752-23537-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: MB 680-854427/1-A
Client Sample ID: Method
Blank
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 854573
Prep Batch:
854427
MB MB
Analyte
Result Qualifier
RL
MDL
unit
D Prepared
Analyzed
Dill Fac
Perfluoropentanoic acid (PFPeA)
<0.50
2.0
0.50
ng/L
09/04/24 14:03
09/05/24 13:45
1
Perfluorohexanoic acid (PFHxA)
0.178 J
2.0
0.10
ng/L
09/04/24 14:03
09/05/24 13:45
1
Perfluoroheptanoic acid (PFHpA)
<0.50
2.0
0.50
ng/L
09/04/24 14:03
09/05/24 13:45
1
Perfluorooctanoic acid (PFOA)
<0.50
2.0
0.50
ng/L
09/04/24 14:03
09/05/24 13:45
1
Perfluorononanoic acid (PFNA)
<0.10
2.0
0.10
ng/L
09/04/24 14:03
09/05/24 13:45
1
Perfluorodecanoic acid (PFDA)
<0.10
2.0
0.10
ng/L
09/04/24 14:03
09/05/24 13:45
1
Perfluoroundecanoic acid (PFUnA)
<0.50
2.0
0.50
ng/L
09/04/24 14:03
09/05/24 13:45
1
Perfluorododecanoic acid (PFDoA)
<0.50
2.0
0.50
ng/L
09/04/24 14:03
09/05/24 13:45
1
Perfluorotridecanoic acid (PFTrDA)
<0.50
2.0
0.50
ng/L
09/04/24 14:03
09/05/24 13:45
1
Perfluorotetradecanoic acid (PFTA)
<0.50
2.0
0.50
ng/L
09/04/24 14:03
09/05/24 13:45
1
Perfluorobutanesulfonic acid (PFBS)
<0.50
2.0
0.50
ng/L
09/04/24 14:03
09/05/24 13:45
1
Perfluoropentanesulfonic acid
<0.10
2.0
0.10
ng/L
09/04/24 14:03
09/05/24 13:45
1
(PFPeS)
Perfluorohexanesulfonic acid (PFHxS)
<0.50
2.0
0.50
ng/L
09/04/24 14:03
09/05/24 13:45
1
Perfluoroheptanesulfonic acid
<0.10
2.0
0.10
ng/L
09/04/24 14:03
09/05/24 13:45
1
(PFHpS)
Perfluorooctanesulfonic acid (PFOS)
<0.50
2.0
0.50
ng/L
09/04/24 14:03
09/05/24 13:45
1
Perfluorononanesulfonic acid (PFNS)
<0.10
2.0
0.10
ng/L
09/04/24 14:03
09/05/24 13:45
1
Perfluorododecanesulfonic acid
<0.50
2.0
0.50
ng/L
09/04/24 14:03
09/05/24 13:45
1
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
<0.50
4.0
0.50
ng/L
09/04/24 14:03
09/05/24 13:45
1
sulfonic acid (4:2 FTS)
1H,1H,2H,2H-Perfluorooctanesulfonic
<0.50
4.0
0.50
ng/L
09/04/24 14:03
09/05/24 13:45
1
acid (6:2 FTS)
1H,1H,2H,2H-Perfluorodecane
<0.50
4.0
0.50
ng/L
09/04/24 14:03
09/05/24 13:45
1
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.10
2.0
0.10
ng/L
09/04/24 14:03
09/05/24 13:45
1
N-methylperfluorooctane sulfonamide
<0.50
2.0
0.50
ng/L
09/04/24 14:03
09/05/24 13:45
1
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<0.50
2.0
0.50
ng/L
09/04/24 14:03
09/05/24 13:45
1
(NEtFOSA)
N-methylperfluorooctanesulfonamidoa
<0.50
2.0
0.50
ng/L
09/04/24 14:03
09/0512413:45
1
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<0.50
2.0
0.50
ng/L
09/04/24 14:03
09/05/24 13:45
1
etic acid (NEtFOSAA)
N-methylperfluorooctane
<2.0
10
2.0
ng/L
09/04/24 14:03
09/05/24 13:45
1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<2.0
10
2.0
ng/L
09/04/24 14:03
09/05/24 13:45
1
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide Dimer
<0.50
1.5
0.50
ng/L
09/04/24 14:03
09/05/24 13:45
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<0.50
2.0
0.50
ng/L
09/04/24 14:03
09/05/24 13:45
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<0.50
2.0
0.50
ng/L
09/04/24 14:03
09/05/24 13:45
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<0.50
2.0
0.50
ng/L
09/04/24 14:03
09/05/24 13:45
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<0.50
2.0
0.50
ng/L
09/04/24 14:03
09/05/24 13:45
1
e-1-sulfonic acid(9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<0.75
2.0
0.75
ng/L
09/04/24 14:03
09/05/24 13:45
1
e-1-sulfonic acid (110-MOWS)
Perfluoro (2-ethoxyethane) sulfonic
<0.50
2.0
0.50
ng/L
09/04/24 14:03
09/05/24 13:45
1
acid (PFEESA)
Eurofins Raleigh
Page 25 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Person County
Job ID: 752-23537-1
Method: 1633 - Per- and Polyfluoroalkyl Substances
by LC/MS/MS (Continued)
Lab Sample ID: MB 680-854427/1-A
Client Sample ID: Method Blank
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 854573
Prep Batch: 854427
MB
MB
Analyte
Result
Qualifier
RL
MDL Unit
D Prepared
Analyzed Dil Fac
3-Perfluoropropylpropanoic acid (3:3
<1.0
4.0
1.0 ng/L
09/04/24 14:03
09/05/24 13:45 1
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<2.7
10
2.7 ng/L
09/04/24 14:03
09/05/24 13:45 1
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<2.7
10
2.7 ng/L
09/04/24 14:03
09/05/24 13:45 1
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.10
2.0
0.10 ng/L
09/04/24 14:03
09/05/24 13:45 1
Perfluoro-3-methoxypropanoic acid
<0.50
2.0
0.50 ng/L
09/04/24 14:03
09/05/24 13:45 1
(PFMPA)
MB
MB
Isotope Dilution
%Recovery
Qualifier
Limits
Prepared
Analyzed Dil Fac
13C4 PFBA
74.6
5 - 130
09/04/24 14:03
09/05/24 13:45 1
13C5 PFPeA
80.7
40 - 130
09/04/24 14:03
09/05/24 13:45 1
13C5 PFHxA
83.9
40 - 130
09/04/24 14:03
09/05/24 13:45 1
13C4 PFHpA
84.5
40 - 130
09104124 14:03
09105124 13:45 1
13C8 PFOA
80.7
40 - 130
09104124 14:03
09105124 13:45 1
13C9 PFNA
93.0
40 - 130
09104124 14:03
09105124 13:45 1
13C6 PFDA
88.2
40 - 130
09104124 14:03
09105124 13:45 1
13C7 PFUnA
73.1
30 - 130
09104124 14:03
09105124 13:45 1
13C2 PFDoA
58.6
10 - 130
09104124 14:03
09105124 13:45 1
13C2 PFTeDA
35.3
10 - 130
09104124 14:03
09105124 13:45 1
13C3 PFBS
89.0
40 - 135
09104124 14:03
09105124 13:45 1
13C3 PFHxS
74.6
40 - 130
09104124 14:03
09105124 13:45 1
13C8 PFOS
102
40 - 130
09104124 14:03
09/05/24 13:45 1
13C8 FOSA
71.9
40 - 130
09104124 14:03
09/05/24 13:45 1
d3-NMeFOSAA
83.3
40 - 170
09104124 14:03
09/05/24 13:45 1
d5-NEtFOSAA
75.5
25 - 135
09/04/24 14:03
09/05/24 13:45 1
M2-4:2 FTS
93.5
40 - 200
09/04/24 14:03
09/05/24 13:45 1
M2-6:2 FTS
71.5
40 - 200
09/04/24 14:03
09/05/24 13:45 1
M2-8:2 FTS
153
40 - 300
09104124 14:03
09105124 13:45 1
13C3 HFPO-DA
95.6
40 - 130
09104124 14:03
09105124 13:45 1
d7-N-McFOSE-M
76.5
10 - 130
09104124 14:03
09105124 13:45 1
d9-N-EtFOSE-M
70.0
10 - 130
09104124 14:03
09105124 13:45 1
d5-NEtPFOSA
65.6
10 - 130
09104124 14:03
09105124 13:45 1
d3-NMePFOSA
64.0
10 - 130
09104124 14:03
09105124 13:45 1
Lab Sample ID: LCS 680-854427/2-A
Client Sample ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 854573
Prep Batch: 854427
Spike
LCS LCS
%Rec
Analyte
Added
Result Qualifier Unit
D %Rec
Limits
Perfluorobutanoic acid (PFBA)
64.0
54.0 ng/L
84
70 - 140
Perfluoropentanoic acid (PFPeA)
32.0
26.8 ng/L
84
65 - 135
Perfluorohexanoic acid (PFHxA)
32.0
27.4 ng/L
86
70 - 145
Perfluoroheptanoic acid (PFHpA)
32.0
27.5 ng/L
86
70 - 150
Perfluorooctanoic acid (PFOA)
32.0
23.5 ng/L
73
70 - 150
Perfluorononanoic acid (PFNA)
32.0
25.3 1 ng/L
79
70 - 150
Perfluorodecanoic acid (PFDA)
32.0
26.2 ng/L
82
70 - 140
Perfluoroundecanoic acid
32.0
28.5 ng/L
89
70 - 145
(PFUnA)
Eurofins Raleigh
Page 26 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Person County
F
Job ID: 752-23537-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LCS 680-854427/2-A
Client Sample
ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 854573
Prep Batch: 854427
Spike
LCS LCS
%Rec
Analyte
Added
Result Qualifier
Unit
D %Rec
Limits
Perfluorododecanoic acid
32.0
28.9
ng/L
90
70 - 140
(PFDoA)
Perfluorotridecanoic acid
32.0
34.5
ng/L
108
65 - 140
(PFTrDA)
Perfluorotetradecanoic acid
32.0
34.1
ng/L
106
60 - 140
(PFTA)
Perfluorobutanesulfonic acid
28.4
24.1
ng/L
85
60 - 145
(PFBS)
Perfluoropentanesulfonic acid
30.1
25.2
ng/L
84
65 - 140
(PFPeS)
Perfluorohexanesulfonic acid
29.2
25.6
ng/L
88
65 - 145
(PFHxS)
Perfluoroheptanesulfonic acid
30.5
29.6
ng/L
97
70 - 150
(PFHpS)
Perfluorooctanesulfonic acid
29.8
27.1
ng/L
91
55 - 150
(PFOS)
Perfluorononanesulfonic acid
30.8
25.4
ng/L
83
65 - 145
(PFNS)
Perfluorododecanesulfonic acid
31.0
15.7
ng/L
51
50 - 145
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
60.0
53.6
ng/L
89
70-145
sulfonic acid (4:2 FTS)
1 H,1 H,2H,2H-Perfluorooctane
60.9
62.3
ng/L
102
65-155
sulfonic acid (6:2 FTS)
1 H,1 H,2H,2H-Perfluorodecane
61.4
54.0
ng/L
88
60-150
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide
32.0
26.0
ng/L
81
70 - 145
(PFOSA)
N-methylperfluorooctane
32.0
30.0
ng/L
94
60 - 150
sulfonamide (NMeFOSA)
N-ethylperfluorooctane
32.0
26.1
ng/L
82
65 - 145
sulfonamide (NEtFOSA)
N-methylperfluorooctanesulfona
32.0
29.1
ng/L
91
50 - 140
midoacetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonami
32.0
27.7
ng/L
86
70 - 145
doacetic acid (NEtFOSAA)
N-methylperfluorooctane
160
127
ng/L
79
70 - 145
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
160
162
ng/L
101
70 - 135
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide
24.0
21.1
ng/L
88
70 - 140
DimerAcid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic
30.3
21.5
ng/L
71
65 - 145
acid (ADONA)
Perfluoro-4-methoxybutanoic
32.0
28.9
ng/L
90
60 - 150
acid (PFMBA)
Nonafluoro-3,6-dioxaheptanoic
32.0
28.4
ng/L
89
50 - 150
acid (NFDHA)
9-Chlorohexadecafluoro-3-oxan
29.9
20.4 `-
ng/L
68
70 - 155
onane-1-sulfonic
acid (9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaund
30.2
16.2 `-
ng/L
54
55-160
ecane-1-sulfonic acid
(11 CI-PF3OUdS)
Perfluoro (2-ethoxyethane)
28.5
27.4
ng/L
96
70 - 140
sulfonic acid (PFEESA)
Eurofins Raleigh
Page 27 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
QC Sample Results
Client: Smith Gardner Inc
Job ID: 752-23537-1
Project/Site: Person County
Method: 1633 - Per- and Polyfluoroalkyl
Substances by LC/MS/MS (Continued)
Lab Sample ID: LCS 680-854427/2-A
Client Sample
ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 854573
Prep Batch: 854427
Spike
LCS
LCS
%Rec
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits
3-Perfluoropropylpropanoic acid
64.0
51.5
ng/L
81
65 - 130
(3:3 FTCA)
3-Perfluoropentylpropanoic acid
160
150
ng/L
94
70 - 135
(5:3 FTCA)
3-Perfluoroheptylpropanoic acid
160
116
ng/L
73
50 - 145
(7:3 FTCA)
Perfluorodecanesulfonic acid
30.8
19.7
ng/L
64
60 - 145
(PFDS)
Perfluoro-3-methoxypropanoic
32.0
29.0
ng/L
91
55 - 140
acid (PFMPA)
LCS LCS
Isotope Dilution %Recovery Qualifier
Limits
13C4 PFBA
73.4
5 - 130
13C5 PFPeA
81.8
40 - 130
13C5 PFHxA
80.2
40 - 130
13C4 PFHpA
81.9
40 - 130
13C8 PFOA
79.6
40 - 130
13C9 PFNA
89.3
40 - 130
13C6 PFDA
85.1
40 - 130
13C7 PFUnA
72.2
30 - 130
13C2 PFDoA
57.3
10 - 130
13C2 PFTeDA
43.8
10 - 130
13C3 PFBS
94.1
40 - 135
13C3 PFHxS
78.2
40 - 130
13C8 PFOS
97.6
40 - 130
13C8 FOSA
71.1
40 - 130
d3-NMeFOSAA
81.7
40 - 170
d5-NEtFOSAA
73.9
25 - 135
M2-4:2 FTS
89.1
40 - 200
M2-6:2 FTS
67.0
40 - 200
M2-8:2 FTS
137
40 - 300
13C3 HFPO-DA
90.7
40 - 130
d7-N-McFOSE-M
76.8
10 - 130
d9-N-EtFOSE-M
64.5
10 - 130
d5-NEtPFOSA
60.8
10 - 130
d3-NMePFOSA
61.2
10 - 130
Lab Sample ID: LCSD 680-854427/3-A
Client
Sample ID: Lab Control Sample Dup
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 854573
Prep Batch: 854427
Spike
LCSD
LCSD
%Rec RPD
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits RPD Limit
Perfluorobutanoic acid (PFBA)
64.0
53.8
ng/L
84
70 - 140 0 30
Perfluoropentanoic acid (PFPeA)
32.0
26.9
ng/L
84
65 - 135 0 30
Perfluorohexanoic acid (PFHxA)
32.0
26.9
ng/L
84
70 - 145 2 30
Perfluoroheptanoic acid (PFHpA)
32.0
27.6
ng/L
86
70 - 150 1 30
Perfluorooctanoic acid (PFOA)
32.0
23.6
ng/L
74
70 - 150 0 30
Perfluorononanoic acid (PFNA)
32.0
24.4
1
ng/L
76
70 - 150 4 30
Perfluorodecanoic acid (PFDA)
32.0
26.5
ng/L
83
70 - 140 1 30
Eurofins Raleigh
Page 28 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
QC Sample Results
Client: Smith Gardner Inc Job ID: 752-23537-1
Project/Site: Person County
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LCSD 680-854427/3-A
Client Sample ID: Lab Control
Sample Dup
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 854573
Prep Batch: 854427
Spike
LCSD LCSD
%Rec
RPD
Analyte
Added
Result Qualifier
Unit
D %Rec
Limits
RPD
Limit
Perfluoroundecanoic acid
32.0
29.3
ng/L
91
70 - 145
2
30
(PFUnA)
Perfluorododecanoic acid
32.0
28.9
ng/L
90
70 - 140
0
30
(PFDoA)
Perfluorotridecanoic acid
32.0
45.5 *+
ng/L
142
65 - 140
27
30
(PFTrDA)
Perfluorotetradecanoic acid
32.0
32.0
ng/L
100
60 - 140
6
30
(PFTA)
Perfluorobutanesulfonic acid
28.4
25.2
ng/L
89
60 - 145
4
30
(PFBS)
Perfluoropentanesulfonic acid
30.1
26.3
ng/L
87
65 - 140
4
30
(PFPeS)
Perfluorohexanesulfonic acid
29.2
27.5
ng/L
94
65 - 145
7
30
(PFHxS)
Perfluoroheptanesulfonic acid
30.5
30.4
ng/L
100
70 - 150
3
30
(PFHpS)
Perfluorooctanesulfonic acid
29.8
27.0
ng/L
91
55 - 150
0
30
(PFOS)
Perfluorononanesulfonic acid
30.8
25.1
ng/L
82
65 - 145
1
30
(PFNS)
Perfluorododecanesulfonic acid
31.0
8.90 *- *1
ng/L
29
50 - 145
55
30
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
60.0
54.5
ng/L
91
70-145
2
30
sulfonic acid (4:2 FTS)
1H,11-1,2H,21-1-Perfluorooctane
60.9
58.8
ng/L
96
65-155
6
30
sulfonic acid (6:2 FTS)
1 H,1 H,2H,2H-Perfluorodecane
61.4
54.1
ng/L
88
60-150
0
30
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide
32.0
26.5
ng/L
83
70 - 145
2
30
(PFOSA)
N-methylperfluorooctane
32.0
30.5
ng/L
95
60 - 150
2
30
sulfonamide (NMeFOSA)
N-ethylperfluorooctane
32.0
28.3
ng/L
89
65 - 145
8
30
sulfonamide (NEtFOSA)
N-methylperfluorooctanesulfona
32.0
31.1
ng/L
97
50 - 140
7
30
midoacetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonami
32.0
28.5
ng/L
89
70 - 145
3
30
doacetic acid (NEtFOSAA)
N-methylperfluorooctane
160
130
ng/L
81
70 - 145
2
30
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
160
161
ng/L
101
70 - 135
1
30
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide
24.0
20.9
ng/L
87
70 - 140
1
30
DimerAcid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic
30.3
21.2
ng/L
70
65 - 145
1
30
acid (ADONA)
Perfluoro-4-methoxybutanoic
32.0
29.2
ng/L
91
60 - 150
1
30
acid (PFMBA)
Nonafluoro-3,6-dioxaheptanoic
32.0
27.7
ng/L
87
50 - 150
2
30
acid (NFDHA)
9-Chlorohexadecafluoro-3-oxan
29.9
18.5 *-
ng/L
62
70 - 155
10
30
onane-1-sulfonic
acid(9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaund
30.2
13.1 *-
ng/L
43
55-160
22
30
ecane-1-sulfonic acid
(11 CI-PHOWS)
Eurofins Raleigh
Page 29 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Person County
F
Job ID: 752-23537-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LCSD 680-854427/3-A
Client
Sample ID: Lab Control Sample Dup
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 854573
Prep Batch: 854427
Spike
LCSD LCSD
%Rec RPD
Analyte
Added
Result Qualifier
Unit
D %Rec
Limits RPD Limit
Perfluoro (2-ethoxyethane)
28.5
26.0
ng/L
91
70 - 140 5 30
sulfonic acid (PFEESA)
3-Perfluoropropylpropanoic acid
64.0
49.8
ng/L
78
65 - 130 3 30
(3:3 FTCA)
3-Perfluoropentylpropanoic acid
160
146
ng/L
91
70 - 135 2 30
(5:3 FTCA)
3-Perfluoroheptylpropanoic acid
160
110
ng/L
68
50 - 145 6 30
(7:3 FTCA)
Perfluorodecanesulfonic acid
30.8
18.2 *-
ng/L
59
60 - 145 8 30
(PFDS)
Perfluoro-3-methoxypropanoic
32.0
29.8
ng/L
93
55 - 140 3 30
acid (PFMPA)
LCSD LCSD
Isotope Dilution %Recovery Qualifier
Limits
13C4 PFBA
72.6
5 - 130
13C5 PFPeA
81.4
40 - 130
13C5 PFHxA
83.6
40 - 130
13C4 PFHpA
79.5
40 - 130
13C8 PFOA
78.0
40 - 130
13C9 PFNA
92.2
40 - 130
13C6 PFDA
81.6
40 - 130
13C7 PFUnA
69.2
30 - 130
13C2 PFDoA
55.3
10 - 130
13C2 PFTeDA
30.1
10 - 130
13C3 PFBS
86.4
40 - 135
13C3 PFHxS
73.3
40 - 130
13C8 PFOS
92.2
40 - 130
13C8 FOSA
71.2
40 - 130
d3-NMeFOSAA
75.5
40 - 170
d5-NEtFOSAA
68.9
25 - 135
M2-4:2 FTS
85.8
40 - 200
M2-6:2 FTS
68.7
40 - 200
M2-8:2 FTS
135
40 - 300
13C3 HFPO-DA
92.3
40 - 130
d7-N-McFOSE-M
76.1
10 - 130
d9-N-EtFOSE-M
65.1
10 - 130
d5-NEtPFOSA
59.9
10 - 130
d3-NMePFOSA
58.9
10 - 130
Lab Sample ID: LLCS 680-854427/4-A
Client Sample
ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 854573
Prep Batch: 854427
Spike
LLCS LLCS
%Rec
Analyte
Added
Result Qualifier
Unit
D %Rec
Limits
Perfluorobutanoic acid (PFBA)
8.00
7.05
ng/L
88
70 - 140
Perfluoropentanoic acid (PFPeA)
4.00
3.56
ng/L
89
65 - 135
Perfluorohexanoic acid (PFHxA)
4.00
3.94
ng/L
98
70 - 145
Perfluoroheptanoic acid (PFHpA)
4.00
3.61
ng/L
90
70 - 150
Perfluorooctanoic acid (PFOA)
4.00
3.49
ng/L
87
70 - 150
Perfluorononanoic acid (PFNA)
4.00
3.29 1
ng/L
82
70 - 150
Eurofins Raleigh
Page 30 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Person County
F
Job ID: 752-23537-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LLCS 680-854427/4-A
Client Sample
ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 854573
Prep Batch: 854427
Spike
LLCS LLCS
%Rec
Analyte
Added
Result Qualifier
Unit
D %Rec
Limits
Perfluorodecanoic acid (PFDA)
4.00
3.40
ng/L
85
70 - 140
Perfluoroundecanoic acid
4.00
3.82
ng/L
96
70 - 145
(PFUnA)
Perfluorododecanoic acid
4.00
3.93
ng/L
98
70 - 140
(PFDoA)
Perfluorotrdecanoic acid
4.00
5.27
ng/L
132
65 - 140 �
(PFTrDA)
Perfluorotetradecanoic acid
4.00
3.99
ng/L
100
60 - 140
(PFTA)
Perfluorobutanesulfonic acid
3.55
3.19
ng/L
90
60 - 145
(PFBS)
Perfluoropentanesulfonic acid
3.76
3.62
ng/L
96
65 - 140
(PFPeS)
Perfluorohexanesulfonic acid
3.65
3.71
ng/L
102
65 - 145
(PFHxS)
Perfluoroheptanesulfonic acid
3.82
3.91
ng/L
103
70 _ 150
(PFHpS)
Perfluorooctanesulfonic acid
3.72
3.95
ng/L
106
55 - 150
(PFOS)
Perfluorononanesulfonic acid
3.85
3.44
ng/L
89
65 - 145
(PFNS)
Perfluorododecanesulfonic acid
3.87
1.61 J *-
ng/L
42
50 - 145
(PFDoS)
1H,1H,2H,2H-Perfluorohexane
7.50
7.19 1
ng/L
96
70-145
sulfonic acid (4:2 FTS)
1H,1H,2H,2H-Perfluorooctane
7.62
8.32
ng/L
109
65-155
sulfonic acid (6:2 FTS)
1H,1H,2H,2H-Perfluorodecane
7.68
7.27
ng/L
95
60-150
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide
4.00
3.62
ng/L
90
70 - 145
(PFOSA)
N-methylperfluorooctane
4.00
3.50
ng/L
87
60 - 150
sulfonamide (NMeFOSA)
N-ethylperfluorooctane
4.00
3.43
ng/L
86
65 - 145
sulfonamide (NEtFOSA)
N-methylperfluorooctanesulfona
4.00
3.82
ng/L
96
50 - 140
midoacetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonami
4.00
3.29
ng/L
82
70 - 145
doacetic acid (NEtFOSAA)
N-methylperfluorooctane
20.0
17.9
ng/L
90
70 - 145
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
20.0
20.7
ng/L
103
70 - 135
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide
3.00
2.66 1
ng/L
89
70 - 140
DimerAcid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic
3.78
2.86
ng/L
76
65 - 145
acid (ADONA)
Perfluoro-4-methoxybutanoic
4.00
3.94
ng/L
99
60 - 150
acid (PFMBA)
Nonafluoro-3,6-dioxaheptanoic
4.00
4.08
ng/L
102
50 - 150
acid (NFDHA)
9-Chlorohexadecafluoro-3-oxan
3.74
2.47 *-
ng/L
66
70 - 155
onane-1-sulfonic
acid(9CI-PF30NS)
Eurofins Raleigh
Page 31 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Person County
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LLCS 680-854427/4-A
Matrix: Water
Analysis Batch: 854573
Spike
LLCS LLCS
Analyte
Added
Result Qualifier
Unit
11-Chloroeicosafluoro-3-oxaund
3.78
1.82 J *-
ng/L
ecane-1-sulfonic acid
(11 CI-PF3OUdS)
Perfluoro (2-ethoxyethane)
3.57
3.42
ng/L
sulfonic acid (PFEESA)
3-Perfluoropropylpropanoic acid
8.00
6.70
ng/L
(3:3 FTCA)
3-Perfluoropentylpropanoic acid
20.0
18.7
ng/L
(5:3 FTCA)
3-Perfluoroheptylpropanoic acid
20.0
14.0
ng/L
(7:3 FTCA)
Perfluorodecanesulfonic acid
3.86
2.62
ng/L
(PFDS)
Perfluoro-3-methoxypropanoic
4.00
3.84
ng/L
acid (PFMPA)
LLCS LLCS
Isotope Dilution
%Recovery Qualifier
Limits
13C4 PFBA
74.0
25 - 130
13C5 PFPeA
77.2
40 - 130
13C5 PFHxA
79.1
40 - 130
13C4 PFHpA
79.3
40 - 130
13C8 PFOA
77.7
40 - 130
13C9 PFNA
90.3
40 - 130
13C6 PFDA
86.4
40 - 130
13C7 PFUnA
72.6
30 - 130
13C2 PFDoA
57.7
10 - 130
13C2 PFTeDA
36.9
10 - 130
13C3 PFBS
91.1
40 - 135
13C3 PFHxS
73.2
40 - 130
13C8 PFOS
100
40 - 130
13C8 FOSA
69.5
40 - 130
d3-NMeFOSAA
84.4
40 - 170
d5-NEtFOSAA
78.7
25 - 135
M2-4:2 FTS
93.0
40 - 200
M2-6:2 FTS
73.9
40 - 200
M2-8:2 FTS
128
40 - 300
13C3 HFPO-DA
87.0
40 - 130
d7-N-McFOSE-M
71.1
10 - 130
d9-N-EtFOSE-M
62.8
10 - 130
d5-NEtPFOSA
54.7
10 - 130
d3-NMePFOSA
55.5
10 - 130
F
Job ID: 752-23537-1
Client Sample ID: Lab Control Sample
Prep Type: Total/NA
Prep Batch: 854427
%Rec
D %Rec
Limits
48
55-160
96
70 - 140
84
65-130
93
70 - 135
70
50 - 145
68
60 - 145
96
55-140
Eurofins Raleigh
Page 32 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
QC Association Summary
Client: Smith Gardner Inc
Job ID: 752-23537-1
Project/Site: Person County
LCMS
Prep Batch: 853778
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
752-23537-2
MW-5
Total/NA
Water
1633
752-23537-3
Field Blank
Total/NA
Water
1633
MB 680-853778/1-A
Method Blank
Total/NA
Water
1633
LCS 680-853778/2-A
Lab Control Sample
Total/NA
Water
1633
LCSD 680-853778/3-A
Lab Control Sample Dup
Total/NA
Water
1633
LLCS 680-853778/4-A
Lab Control Sample
Total/NA
Water
1633
Analysis Batch: 854043
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
752-23537-2
MW-5
Total/NA
Water
1633
853778
752-23537-3
Field Blank
Total/NA
Water
1633
853778
MB 680-853778/1-A
Method Blank
Total/NA
Water
1633
853778
LCS 680-853778/2-A
Lab Control Sample
Total/NA
Water
1633
853778
LCSD 680-853778/3-A
Lab Control Sample Dup
Total/NA
Water
1633
853778
LLCS 680-853778/4-A
Lab Control Sample
Total/NA
Water
1633
853778
Prep Batch: 854427
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
752-23537-1 - RE
MW-4
Total/NA
Water
1633
752-23537-2 - RE
MW-5
Total/NA
Water
1633
MB 680-854427/1-A
Method Blank
Total/NA
Water
1633
LCS 680-854427/2-A
Lab Control Sample
Total/NA
Water
1633
LCSD 680-854427/3-A
Lab Control Sample Dup
Total/NA
Water
1633
LLCS 680-854427/4-A
Lab Control Sample
Total/NA
Water
1633
Analysis Batch: 854573
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
752-23537-1 - RE
MW-4
Total/NA
Water
1633
854427
752-23537-2 - RE
MW-5
Total/NA
Water
1633
854427
MB 680-854427/1-A
Method Blank
Total/NA
Water
1633
854427
LCS 680-854427/2-A
Lab Control Sample
Total/NA
Water
1633
854427
LCSD 680-854427/3-A
Lab Control Sample Dup
Total/NA
Water
1633
854427
LLCS 680-854427/4-A
Lab Control Sample
Total/NA
Water
1633
854427
Eurofins Raleigh
Page 33 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Lab Chronicle
Client: Smith Gardner Inc
Project/Site: Person County
F
Job ID: 752-23537-1
Client Sample ID: MW-4
Lab Sample ID: 752-23537-1
Date Collected: 08/27/24 00:00
Matrix: Water
Date Received: 08/27/24 15:00
Batch
Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type
Method
Run
Factor
Amount
Amount
Number
or Analyzed Analyst Lab
Total/NA Prep
1633
RE
0.2626 mL
5 mL
854427
09/04/24 14:03 NG EET SAV
Total/NA Analysis
1633
RE
1
1 mL
1 mL
854573
09/05/24 16:34 SW EET SAV
Client Sample ID: MW-5
Lab Sample ID: 752-23537-2
Date Collected: 08/27/24 00:00
Matrix: Water
Date Received: 08/27/24 15:00
Batch
Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type
Method
Run
Factor
Amount
Amount
Number
or Analyzed Analyst Lab
Total/NA Prep
1633
RE
2.5655 mL
5 mL
854427
09/04/24 14:03 NG EET SAV
Total/NA Analysis
1633
RE
1
1 mL
1 mL
854573
09/05/24 16:50 SW EET SAV m
Total/NA Prep
1633
176 mL
5 mL
853778
08/29/24 10:36 MCH EET SAV
Total/NA Analysis
1633
1
1 mL
1 mL
854043
08/30/24 20:59 SW EET SAV
Client Sample ID: Field Blank
Lab Sample ID: 752-23537-3
Date Collected: 08/27/24 00:00
Matrix: Water
Date Received: 08/27/24 15:00
Batch
Batch
Dil Initial
Prep Type
Type
Method
Run Factor Amount
Total/NA
Prep
1633
171.2 mL
Total/NA
Analysis
1633
1 1 mL
Laboratory References:
EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL [phone]
Final
Batch
Prepared
Amount
Number
or Analyzed
Analyst Lab
5 mL
853778
08/29/24 10:36
MCH EET SAV
1 mL
854043
08/30/24 21:15
SW EET SAV
Page 34 of 42
Eurofins Raleigh
9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Accreditation/Certification Summary
Client: Smith Gardner Inc
Project/Site: Person County
Laboratory: Eurofins Savannah
Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.
Authority
Program
Identification Number Expiration Date
North Carolina (WW/SW)
State
269 12-31-24
The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes
for which the agency does not offer certification.
Analysis Method
Prep Method
Matrix
Analyte
1633
1633
Water
11-Chloroeicosafluoro-3-oxaundecane-1-s
ulfonic acid (11Cl-PF30UdS)
1633
1633
Water
1 H,1 H,2H,2H-Perfluorodecane sulfonic
acid (8:2 FTS)
1633
1633
Water
1 H,1 H,2H,2H-Perfluorohexane sulfonic
acid (4:2 FTS)
1633
1633
Water
1 H,1 H,2H,2H-Perfluorooctane sulfonic acid
(6:2 FTS)
1633
1633
Water
3-Perfluoroheptylpropanoic acid (7:3
FTCA)
1633
1633
Water
3-Perfluoropentylpropanoic acid (5:3
FTCA)
1633
1633
Water
3-Perfluoropropylpropanoic acid (3:3
FTCA)
1633
1633
Water
4,8-Dioxa-3H-perfluorononanoic acid
(ADONA)
1633
1633
Water
9-Chlorohexadecafluoro-3-oxanonane-1-s
ulfonic acid(9CI-PF30NS)
1633
1633
Water
Hexafluoropropylene Oxide Dimer Acid
(HFPO-DA)
1633
1633
Water
N-ethylperfluorooctane sulfonamide
(NEtFOSA)
1633
1633
Water
N-ethylperfluorooctane sulfonamidoethanol
(NEtFOSE)
1633
1633
Water
N-ethylperfluorooctanesulfonamidoacetic
acid (NEtFOSAA)
1633
1633
Water
N-methylperfluorooctane sulfonamide
(NMeFOSA)
1633
1633
Water
N-methylperfluorooctane
sulfonamidoethanol (NMeFOSE)
1633
1633
Water
N-methylperfluorooctanesulfonamidoacetic
acid (NMeFOSAA)
1633
1633
Water
Nonafluoro-3,6-dioxaheptanoic acid
(NFDHA)
1633
1633
Water
Perfluoro (2-ethoxyethane) sulfonic acid
(PFEESA)
1633
1633
Water
Perfluoro-3-methoxypropanoic acid
(PFMPA)
1633
1633
Water
Perfluoro-4-methoxybutanoic acid
(PFMBA)
1633
1633
Water
Perfluorobutanesulfonic acid (PFBS)
1633
1633
Water
Perfluorobutanoic acid (PFBA)
1633
1633
Water
Perfluorodecanesulfonic acid (PFDS)
1633
1633
Water
Perfluorodecanoic acid (PFDA)
1633
1633
Water
Perfluorododecanesulfonic acid (PFDoS)
1633
1633
Water
Perfluorododecanoic acid (PFDoA)
1633
1633
Water
Perfluoroheptanesulfonic acid (PFHpS)
1633
1633
Water
Perfluoroheptanoic acid (PFHpA)
1633
1633
Water
Perfluorohexanesulfonic acid (PFHxS)
1633
1633
Water
Perfluorohexanoic acid (PFHxA)
F
Job ID: 752-23537-1
Eurofins Raleigh
Page 35 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Accreditation/Certification Summary C
Client: Smith Gardner Inc Job ID: 752-23537-1
Project/Site: Person County
Laboratory: Eurofins Savannah (Continued)
Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.
Authority Program Identification Number Expiration Date
The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes
for which the agency does not offer certification.
Analysis Method
Prep Method
Matrix
Analyte
1633
1633
Water
Perfluorononanesulfonic acid (PFNS)
1633
1633
Water
Perfluorononanoic acid (PFNA)
1633
1633
Water
Perfluorooctanesulfonamide (PFOSA)
1633
1633
Water
Perfluorooctanesulfonic acid (PFOS)
1633
1633
Water
Perfluorooctanoic acid (PFOA)
1633
1633
Water
Perfluoropentanesulfonic acid (PFPeS)
1633
1633
Water
Perfluoropentanoic acid (PFPeA)
1633
1633
Water
Perfluorotetradecanoic acid (PFTA)
1633
1633
Water
Perfluorotridecanoic acid (PFTrDA)
1633
1633
Water
Perfluoroundecanoic acid (PFUnA)
Eurofins Raleigh
Page 36 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Method Summary
Client: Smith Gardner Inc
Project/Site: Person County
F
Job ID: 752-23537-1
Method
Method Description
Protocol
Laboratory
1633
1633
Per- and Polyfluoroalkyl Substances by LC/MS/MS
Solid -Phase Extraction (SPE)
EPA
EPA
EET SAV
EET SAV
Protocol References:
EPA = US Environmental Protection Agency
Laboratory References:
EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL [phone]
Eurofins Raleigh
Page 37 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Sample Summary
Client: Smith Gardner Inc
Project/Site: Person County
Job ID: 752-23537-1
Lab Sample ID Client Sample ID
Matrix
Collected
Received
752-23537-1 MW-4
Water
08/27/24 00:00
08/27/24 15:00
752-23537-2 MW-5
Water
08/27/24 00:00
08/27/24 15:00
752-23537-3 Field Blank
Water
08/27/24 00:00
08/27/24 15:00 L
Eurofins Raleigh
Page 38 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Eurofins Raleigh
104 Woodwinds Industrial Court Suite A
Cary, NC 27511
Phone: [phone]
Chain of Custody Record
tit eurofins I
Environment Testing
Sam I
Lab PM.
Carrier Tracking No(s):
COC No:
Client Information
V
Trotter, Heather
752-20005-5261.1
Client Contact
Daniel Pantaleo
Phone Q `
q `� — DZ ' 0 J}�
E-Mail:
i [e-mail]
State of Origin:
/
Page:
Page 1 of 1
Company:
PWSID:
Job #:
Smith Gardner Inc
Analysis Requested
Address:
Due Date Requested:
Preservation Codes:
14 N Boylan Avenue
I
N - None
City:
TAT Requested (days):
Raleigh
I
c919-828-0577(Tel)
L11.
state, Zip:
NC, 27603
Compllanu Project a Yes d NoPhone:
PO#:
Purchase Order not required
9
Email:
WO #:
[e-mail]
b
n
o
r
752-23537 COC
Project Name:
Project #:
Person County
75202483
•
E
N
I
`o
°
a
4
`O
E
Other:
Site:
SSOW#:
Sample
Matrix
Type
LL
I �.I
ae
o
Z
Sample
(C=comp,
3- ad,
o�..AAWda,
o
M
a
Sample Identification
Sample Date
Time
G= rab
eT-Tuau..A-A4
tZ
1°-
Special Instructions/Note:
P(r�eservation Code:
N
M W — w
$- Z'i-
0 5o
V
Water
Water
F til, WIWI,
0 "7,3'2-
1,b-ZD
Water
Initial Temperature: - _
°
Correction Factor: 0° � C
Corrected Temperature: �132
Temp IR Gun, C
RY SG P D�J LB
Initials:
I
Possible Hazard Identification
Sample Disposal (A fee may be assessed if samples are retained longer than 1 month)
Non -Hazard Flammable Skin Irritant Poison B ,Unknown Radiological
Return To ClientDisposal By Lab Archive For Months
Deliverable Requested: I, II, III, IV, Other (specify)
Special Instructions/QC Requirements:
Empty Kit Relinquished by:
Date: Time: 11viethod of shipment
Relinq b
DaterTme,
2 1-N L 00
Company
Received by:
G/
DateRm
Company
.t
.��t - oo
Relinquished by:
Date/Time:
Company
Received by:
Daterrme:
Company
Relinquished by:
Date/Time:
Company
Received by:
Date/Tme:
Company
Custody Seals Intact: Custody Seal No.:
Cooler Temperatures) °C and Other Remarks:
A Yes A No
Page 39 of 42 ver: 14/ 1'Y/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Eurofins Raleigh
104 Woodwinds Industrial Court Suite A
Cary, NC 27511
Phone:[phone]
Chain of Custody Record
tiff eurofins
Environment Testing
Sampler.
Lab PM:
Carrier Tracking No(s):
COC No:
Client Information Sub Contract Lab
Trotter, Heather
[e-mail]
752-3803.1
Client Contact
Phone:
E-Mail:
State of Origin:
Page:
Shipping/Receiving
North Carolina
Page 1 of 1
Company:
Accreditations Required (See note):
Job #:
Eurofins Environment Testing Southeast L
State - North Carolina (WW/SW)
752-23537-1
Address:
Due Date Requested:
Preservation Codes:
5102 LaRoche Avenue,
9/9/2024
Analysis
Requested
City
TAT Requested (days):
Savannah
9
State, Zip:
GA, 31404
y
Phone:
PO #:
912-354-7858(Tel) 912-352-0165(Fax)
o
Z
c
Email:
WO #:
a
Z
c
i
>A
Project Name:
Project 9:
Person County
75202483
m
E
m
e
`
c
Other.
Site:
SSOW#:
e
N
G
to
a
`o
Sample
Matrix
m
Nt
Type
(w- ."
1�
€
O
z
Sample
(C=comp,
s- 114J,
o-, .101,,
32
Sa>�e Identification - Client ID Lab ID
Sam le Date
Time
G= rab
eT-n..v. Ak
E
IL
- .61
1
1
Special Instructions/Note:
Preservation Code:
MW4 (752-23537-1)
8/27/24
Eastern
G
Water
X
2
MW-5 (752-23537-2)
8/27/24
Eastern
G
Water
X
j 2
Field Blank (752-23537-3)
8/27/24
Eastern
G
Water
X
12
Now Since laboratory accreditations are subject to change, Eurofins Environment Testing Southeast, LLC places the ownership of method, analyte & accreditation compliance upon our subcontract laboratories. This sample shipment is forwarded under chalnofcustody. If the laboratory
does not currently maintain accreditation in the State of Origin listed above for anatysLslteststmatrix being analyzed, the samples must be shipped back to the Eurofins Environment Testing Southeast LLC laboratory or other instructions will be provided. Any changes to accreditation
status should be brought to Eurofins Environment Testing Southeast, LLC attentlon Immediately. If all requested accreditation are current to date, return the signed Chain of Custody attesting to said compliance to Eurofins Environment Testing Southeast, LLC.
Possible Hazard Identification
Sample Disposal (A fee may be assessed if samples are retained longer than 1 month)
= 0
Unconfirmed
Return To Client Disposal By Lab Archive For Months
Deliverable Requested: I, II, III, IV, Other (specify) Primary Deliverable Rank: 2
Special Instructions/QC Requirements:
'
Empty Kit Relinquished by:
Date: Time
Pod of Shipment
Relinquished by:
Datamme:
Company
Received by,;._� �j /%'
D 7
A 1012,
D12,
Company
Relinquished by:
DateMme:
Company
Received by:
DateRme: '
Company
Relinquished by:
Date/Time:
Company
Received by:
DateTme:
Company
Custody Seals Intact: Custody Seal No.:
Cooler Tempereture(s) °C and Other Remarks:
e Yes � No
/
Page 40 of 42 Ver: 05/06/202 t/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Client: Smith Gardner Inc
Login Number: 23537
List Number: 1
Creator: Yonish, Rachel
Question
Login Sample Receipt Checklist
Answer Comment
Radioactivity wasn't checked or is </= background as measured by a survey
True
meter.
The cooler's custody seal, if present, is intact.
True
Sample custody seals, if present, are intact.
True
The cooler or samples do not appear to have been compromised or
True
tampered with.
Samples were received on ice.
True
Cooler Temperature is acceptable.
True
Cooler Temperature is recorded.
True
COC is present.
True
COC is filled out in ink and legible.
True
COC is filled out with all pertinent information.
True
Is the Field Sampler's name present on COC?
True
There are no discrepancies between the containers received and the COC.
True
Samples are received within Holding Time (excluding tests with immediate
True
HTs)
Sample containers have legible labels.
True
Containers are not broken or leaking.
True
Sample collection date/times are provided.
True
Appropriate sample containers are used.
True
Sample bottles are completely filled.
True
Sample Preservation Verified.
True
There is sufficient vol. for all requested analyses, incl. any requested
True
MS/MSDs
Containers requiring zero headspace have no headspace or bubble is
True
<6mm (1/4").
Multiphasic samples are not present.
True
Samples do not require splitting or compositing.
True
Residual Chlorine Checked.
True
Job Number: 752-23537-1
List Source: Eurofins Raleigh
L
Eurofins Raleigh
Page 41 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Client: Smith Gardner Inc
Login Number: 23537
List Number: 2
Creator: Lincoln, Alyssa
Question
Login Sample Receipt Checklist
Answer Comment
Radioactivity wasn't checked or is </= background as measured by a survey
N/A
meter.
The cooler's custody seal, if present, is intact.
True
Sample custody seals, if present, are intact.
True
The cooler or samples do not appear to have been compromised or
True
tampered with.
Samples were received on ice.
True
Cooler Temperature is acceptable.
True
Cooler Temperature is recorded.
True
COC is present.
True
COC is filled out in ink and legible.
True
COC is filled out with all pertinent information.
True
Is the Field Sampler's name present on COC?
True
There are no discrepancies between the containers received and the COC.
True
Samples are received within Holding Time (excluding tests with immediate
True
HTs)
Sample containers have legible labels.
True
Containers are not broken or leaking.
True
Sample collection date/times are provided.
True
Appropriate sample containers are used.
True
Sample bottles are completely filled.
True
Sample Preservation Verified.
N/A
There is sufficient vol. for all requested analyses, incl. any requested
True
MS/MSDs
Containers requiring zero headspace have no headspace or bubble is
N/A
<6mm (1/4").
Multiphasic samples are not present.
True
Samples do not require splitting or compositing.
True
Residual Chlorine Checked.
N/A
Job Number: 752-23537-1
List Source: Eurofins Savannah
List Creation: 08/28/24 01:04 PM
Eurofins Raleigh
Page 42 of 42 9/6/2024

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Appendix C
Time Vs Concentration Graphs
April 2024 Groundwater Monitoring Report
Person County Landfill
NC Solid Waste Permit No. 73-01

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
This page intentionally left blank.

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
1,2-Dichloropropane
3.5

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
60
50
40
a�a
c
0
-M 30
v 20
10
0
1,4-Dioxane
n n n n W W o0 00 CO o0 Ol Ol Ol 01 O1 Q1 'O O O O O O c-I c-1 c-I N N N N N fV M M M M M V V
cO-I rO-I rO-I cO-I cOi rO-I cO-I cOi rO-I cO-I aO-I rO-I cO-I cO-I N N N N N N r-j r4 r-4 CN N N N N N N N N N 1-4 r4 N 1-40 0 O 0 O O O O O 0 O O 0 O O O 0 O O O O O 0
O O O O O
N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N
\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \
c-1 ci .-i a -I ci .-i a -I ci c-I c-I c-1 c-I c-I ci ci ci ci ci c-I a -I ci r-I a -I c-1 a-i .-i ci ci .-i c-1 ci c-I a -I ci c-I ci ci a-i .-i c-1 c-I c-I
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c-I c-I r-I r-I ci ci c-I
Date
—MW-2 —MW-3 —MW-5 —MW-7 —MW-7D —21-Standard

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
9
8
7
M:
0.
c 5
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v
c
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I� n n n W 00 00 00 00 00 01 O1 O1 O1 Ol Ol O O O O O O c-I c-I " ci " c4 N N N N N N M M M M M M V V
0 0 0 0 0 0 0 0 N N N N N N N N N N N N N N N N N N N N N N N N N N
O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O
N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N
\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \
c-I ci ci r-I ci ci ci a —I a —I a —I a —I c-I c-I ci ci ci ci ci ci a —I a —I c-I c-I c-I c-I ci ci ci ci ci ci a —I a —I c-I c-I c-I ci ci ci ci ci ci
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Date
-MW-3 -MW-S -MW-7 -21-Standard

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
40
35
30
25
c
0
m 20
c
w
V
o 15
u
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Tetrachloroethene
Oyu O,� O,$ O,� O,� Oyu O,0) O,0) O,(� O,C5 O,Oj O,O OHO OHO OHO OHO OHO
Date
—MW-2 —MW-3 —MW-S —MW-7 —MW-7D —2LStandard

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
40
35
30
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c
0
m 20
rc
a,
u
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r, r` n n 00 00 00 00 00 00 Q1 m Ol Ol m 01 O O O O O O .--1 a -I a -I .-I .-I c-I N N N N N N M M M M M M V
N N N N N N N N N N N N N N N N N N N N N
O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O
N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N
\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \
ti ti ti N ti ti ti
Date
-MW-2 -MW-3 -MW-5 -MW-7 -MW-7D -2LStandard

Docusign Envelope ID: C215FF15-CBAA-4252-B07C-628B4E2B85E4
Vinyl Chloride
50
45
40
35
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c
0
25
rc
a
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0
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15
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Oy1 Oy1 OS, O,y1 O,% 6N QN, QN, QN, (SN O,O O,O Oho O,O QN, QN, (9 O,tO (9 (ST OTti (9 61 (Sy (Sy O�y (:lv 6V (:v 6V 01 OtL OtL OIL O1� Ot3 O1� OtS OAS O1� OtP OtP
h�ti\�1�ti9 �\y9 �\y\'L y\y9 �\y9 91�y9 �\y9 �\y9 y\y9 �\y9 91�ti\� 99 9 999 9 ti�ti9 y�ti9 3�ti9 h�ti\�1�ti9 ��ti\�y��ti9 y�ti9 3�ti95�ti\�1�ti\� O�ti\�y��ti\�
Date
—MW-2 —MW-3 —MW-5 — MW-7 —MW-7D —2LStandard