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HomeMy WebLinkAboutWS-3097_8863_CA_OTH_20250122_respondence-to-GW sampliong1 Gene Mao From:Gene Mao Sent:Wednesday, January 22, 2025 3:20 PM To:James Dodson Subject:RE: Re: Church Street Family Fare #172 - Facility ID 00-0-00000009710-Gwtr Resample event James, I thought I responded to your email after reviewing your sampling report. Because of no GCL detection in the your latest sampling results for MW-01A and an existing NRP recorded June 15, 2015 for incident #8863, no additional work is needed unless new release is reported. Thank you. From: James Dodson <jdodson@earthsys.net> Sent: Wednesday, January 22, 2025 10:19 AM To: Gene Mao <GMAO@guilfordcountync.gov> Subject: FW: Re: Church Street Family Fare #172 - Facility ID 00-0-00000009710-Gwtr Resample event *WARNING* This email originated outside Guilford County's email system. *WARNING* Do not click unrecognized links or attachments. When in doubt, use the Phish Alert Report button. Gene, Had you ever made a decision regarding this site? The re-sample event was performed so that you could decide if a new incident should be started or if the site would close under the existing NRP for the property. Please let me know the outcome so I can decide what to do about the site monitor well. Thanks. James Dodson, P.G. | Operations Manager - Carolinas | jdodson@earthsys.net | ESNC Environmental Consulting, P.C. 1408 Christian Avenue Suite 11 | Durham, NC 27705 T. 919.910.7767 | M. 919.356.0236 From: James Dodson Sent: Wednesday, August 21, 2024 10:04 AM 2 To: GMAO@guilfordcountync.gov Subject: Re: Church Street Family Fare #172 - Facility ID 00-0-00000009710-Gwtr Resample event Hi Gene, Please see attached the results of a groundwater resample event at the above referenced facility,. The sample was collected based upon electronic correspondence from the Guilford County DHHS. Let me know if you have any questions. Thanks. James Dodson, P.G. | Operations Manager - Carolinas | jdodson@earthsys.net | ESNC Environmental Consulting, P.C. 1408 Christian Avenue Suite 11 | Durham, NC 27705 T. 919.910.7767 | M. 919.356.0236 1408 Christian Avenue, Suite 11, Durham, NC 27705-2909 Florida • North Dakota • New Jersey • Colorado • Texas • New York • Pennsylvania • North Carolina August 21, 2024 Mr. Gene Mao Guilford County Department of Health and Human Services 400 West Market Street, Suite 300 Greensboro, NC 27401 Reference: Site Check – Miscellaneous Groundwater Re-sample/Monitoring Letter Report Church Street Family Fare BP #172: M.M. Fowler, Inc. (Facility ID No. 00-0-0000009710) 2750 North Church Street, Greensboro, Guilford County, NC 27405 Former UST Incident Number(s): #8863 (Speedway #8165) Dear Mr. Mao: Please find enclosed the results for the re-sampling of a groundwater monitoring well, MW-1A, installed during site check activities at the above referenced site. The well was re-sampled based upon electronic communication from the Guilford County Department of Health and Human Services (DHHS) on July 30, 2024, requesting that the previously detected target compounds and reported concentrations be verified. ESNC Environmental Consulting, P.C. (ESNC) mobilized to the site on August 8, 2024, to resample MW-1A. MW-1A’s groundwater was measured for depth-to-water (DTW) and for the presence of PSH using a SolinstTM oil/water IFP accurate to 0.01 feet. DTW in MW-1A was measured at 27.67 below top of casing (BTOC). PSH was not monitored to be present. Following the monitoring, MW-1A was purged of three to five well volumes with disposable polyethylene bailers and nylon string. The well was then allowed to recharge within 95% of its pre-development depth to water prior to sampling. One groundwater sample was collected from the well and was analyzed by EPA Method 6200B for Volatile Organic Compounds (VOCs). The laboratory analytical results for the August 8, 2024, re-sample event for MW-1A is tabulated on the attached Table 6 and the complete laboratory analytical report with supporting COC documentation are included with this correspondence. Groundwater analysis by EPA Method 6200B confirmed the presence of the previously identified target compounds in the groundwater. The reported concentrations were like those previously reported. For the August 6, 2024, sample event the concentrations of Benzene, 1,2,4-Trimethylbenzene, 1,3,5- Trimethylbenzene, n–Propylbenzene and Naphthalene were reported above the corresponding NCAC 2L Groundwater Quality Standards (GWQSs). No detected compound was reported more than the Gross Contamination Levels (GCLs). DATE: 8/2024 Incident Number/Name: I. EPA 6200B ANALYTICAL RESULTS We l l I D Da t e Be n z e n e MW-1A 5/8/2024 1,200 3,690 432 1,970 26.6 120 464 108 28.9 12.0 71.1 56.2 5.9 BRL BRL 161 7/16/2024 46 J 9.5 J 27 J 290 BRL 28 J 1,300 520 33 J 12.0 140 24 J BRL 6.4 J BRL NA 8/8/2024 39 J 9.0 J 13 J 220 BRL 22 J 1,700 740 42 J BRL 180 21 J BRL 48 J 39 J NA NCAC 2L GWS 1 600 600 500 20 70 400 400 70 70 70 6 70 25 70 40 GCL Standard 5,000 260,000 80,000 50,000 20,000 70,000 28,500 24,100 30,500 5,900 26,100 6,000 8,800 11,700 70,000 40,000 II. MADEP VPH ANALYTICAL RESULTS We l l I D Da t e C5 - C 8 A l i p h a t i c s C9 - C 1 8 A l i p h a t i c s ( C 9 - C 1 2 Ali p h a t i c s + C 9 - C 1 8 A l i p h a t i c s ) C1 9 - C 3 6 A l i p h a t i c s C9 - C 2 2 A r o m a t i c s ( C 9 - C 1 0 Ar o m a t i c s + C 1 1 - C 2 2 A r o m a t i c s ) MW-1A 5/8/2024 BRL BRL NA BRL 7/16/2024 NA NA NA NA NCAC 2L Standard 400 700 10,000 200 GCL Standard NS NS NS NS III. Total Lead We l l ID Da t e PB MW-1A 5/8/2024 BRL 7/16/2024 NA NCAC 2L Standard 15 GCL Standard 15,000 IV. EPA 504.1 We l l ID Da t e ED B MW-1A 5/8/2024 BRL 7/16/2024 NA NCAC 2L Standard 0.02GCL Standard 50 NOTES: 1.) All reported concentrations in ug/L. 2.) Bold Font indicates exceedance of the NCAC 2L Groundwater Standard (GWS). 3.) Concentrations followed by a "J" indicate an estimated value between the Reporting Limit and the Method Detection Limit. 4.) NA denotes not analyzed. 5.) BRL denotes concentration below the reporting limits as stated on analytical report. Te r t A m y l A l c o h o l ( T A A ) unassigned / Church Street FF #172 Table 6. Groundwater Laboratory Analytical Results Summary M.M. Fowler, Inc. : Church Street Family Fare BP #172 2750 North Church Street, Greensboro, Guilford County, NC 27405 Facility ID No. 00-0-0000009710 ESNC Project No. 7925 Detected Compounds To l u e n e Et h y l b e n z e n e Xy l e n e s ( T o t a l ) MT B E 1, 2 , 4 - T r i m e t h y l b e n z e n e IP E 1, 3 , 5 - T r i m e t h y l b e n z e n e Is o p r o p y l b e n z e n e Ch l o r o f o r m n- P r o p y l b e n z e n e Na p h t h a l e n e n- B u t y l b e n z e n e se c - B u t y l b e n z e n e 4- I s o p r o p y l t o l u e n e Page 1 of 1 APPROXIMATE SCALE IN FEET 0.0 500 1500 3000 PORTION OF GREENSBORO, NORTH CAROLINA 7.5 MINUTE SERIES USGS TOPOGRAPHIC MAPS (2019) 1,000 FOOT RADIUS SITELOCATION CHURCH STREET FAMILY FARE #172 - M.M. FOWLER, INC. 2750 NORTH CHURCH STREET, GREENSBORO, GUILFORD COUNTY, NC 27405 FIGURE 1: SITE TOPOGRAPHY VICINITY MAP DRAWN BY: JJD DATE: 3/20/2024 ESNC JOB 7925 N EXPLANATION 0.0 10 20 40 APPROXIMATE SCALE IN FEET FIGURE 3: SITE MAP WITH ATTEMPTED SOIL BORINGS AND MONITOR WELL LOCATION CHURCH STREET FAMILY FARE #172 2750 NORTH CHURCH STREET, GREENSBORO, GUILFORD COUNTY, NC 27405 MODIFIED BY: JJD DATE: 7/23/2024 PROJECT NO: 7925 SB-1 SB-1 MW-1A SB-3 SB-2 SB-4 ATTEMPTED SOIL SAMPLE LOCATION MONITOR WELL LOCATION MW-1A ANALYTICAL REPORT PREPARED FOR Attn: Justin Abreu Earth Systems LLC 1408 Christain Ave Suite 811 Durham, North Carolina 27705 Generated 8/15/2024 8:50:35 AM JOB DESCRIPTION Church St FF/BP #172 JOB NUMBER 752-22856-1 See page two for job notes and contact information. Cary NC 27511 Suite A 104 Woodwinds Industrial Court Eurofins Raleigh Page 1 of 22 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Eurofins Raleigh Eurofins Raleigh is a laboratory within Eurofins Environment Testing Southeast, LLC, a company within Eurofins Environment Testing Group of Companies Job Notes This report may not be reproduced except in full, and with written approval from the laboratory. The results relate only to the samples tested. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written approval of the laboratory. All questions should be directed to the Eurofins Environment Testing Southeast, LLC Project Manager. Authorization Generated 8/15/2024 8:50:35 AM Authorized for release by Nikita Kuruganty, Project Manager Nikita.Kuruganty@et.eurofinsus.com (912)354-7858 Page 2 of 22 8/15/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Table of Contents Client: Earth Systems LLC Project/Site: Church St FF/BP #172 Laboratory Job ID: 752-22856-1 Page 3 of 22 Eurofins Raleigh8/15/2024 Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1 Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3 Definitions/Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4 Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5 Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6 Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7 Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .9 QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .10 QC Association Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .16 Lab Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .17 Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .18 Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .19 Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .20 Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .21 Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .22 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Definitions/Glossary Job ID: 752-22856-1Client: Earth Systems LLC Project/Site: Church St FF/BP #172 Qualifiers GC/MS VOA Qualifier Description *+LCS and/or LCSD is outside acceptance limits, high biased. Qualifier J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value. Glossary These commonly used abbreviations may or may not be present in this report. ¤Listed under the "D" column to designate that the result is reported on a dry weight basis Abbreviation %R Percent Recovery CFL Contains Free Liquid CFU Colony Forming Unit CNF Contains No Free Liquid DER Duplicate Error Ratio (normalized absolute difference) Dil Fac Dilution Factor DL Detection Limit (DoD/DOE) DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample DLC Decision Level Concentration (Radiochemistry) EDL Estimated Detection Limit (Dioxin) LOD Limit of Detection (DoD/DOE) LOQ Limit of Quantitation (DoD/DOE) MCL EPA recommended "Maximum Contaminant Level" MDA Minimum Detectable Activity (Radiochemistry) MDC Minimum Detectable Concentration (Radiochemistry) MDL Method Detection Limit ML Minimum Level (Dioxin) MPN Most Probable Number MQL Method Quantitation Limit NC Not Calculated ND Not Detected at the reporting limit (or MDL or EDL if shown) NEG Negative / Absent POS Positive / Present PQL Practical Quantitation Limit PRES Presumptive QC Quality Control RER Relative Error Ratio (Radiochemistry) RL Reporting Limit or Requested Limit (Radiochemistry) RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin) TEQ Toxicity Equivalent Quotient (Dioxin) TNTC Too Numerous To Count Eurofins Raleigh Page 4 of 22 8/15/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Job Narrative752-22856-1 Analytical test results meet all requirements of the associated regulatory program listed on the Accreditation/Certification SummaryPageunlessotherwisenotedundertheindividualanalysis.Data qualifiers and/or narrative comments are included to explain any exceptions,if applicable. Matrix QC may not be reported if insufficient sample is provided or site-specific QC samples were not submitted.In these situations,to demonstrate precision and accuracy at a batch level,a LCS/LCSD may be performed,unless otherwise specified in the method.Surrogate and/or isotope dilution analyte recoveries (if applicable)which are outside of the QC window are confirmed unless attributed to a dilution or otherwise noted in the narrative. Receipt The sample was received on 8/8/2024 12:55 PM.Unless otherwise noted below,the sample arrived in good condition,and,where required,properly preserved and on ice.The temperature of the cooler at receipt time was 4.8°C. GC/MS VOAMethodSM6200_B:The following sample was diluted to bring the concentration of target analytes within the calibration range: MW-1A (752-22856-1).Elevated reporting limits (RLs)are provided. No additional analytical or quality issues were noted,other than those described above or in the Definitions/Glossary page. Case Narrative Client: Earth Systems LLC Job ID: 752-22856-1 Project: Church St FF/BP #172 Eurofins Raleigh Job ID: 752-22856-1 Eurofins Raleigh Page 5 of 22 8/15/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Detection Summary Job ID: 752-22856-1Client: Earth Systems LLC Project/Site: Church St FF/BP #172 Client Sample ID: MW-1A Lab Sample ID: 752-22856-1 Isopropyl ether - DL RL 50 ug/L MDL 11 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Total/NA50J22SM6200-B Chloroform - DL 50 ug/L4.2 Total/NA5039JSM6200-B Benzene - DL 50 ug/L2.5 Total/NA5039JSM6200-B Toluene - DL 50 ug/L2.7 Total/NA509.0 J SM6200-B Ethylbenzene - DL 50 ug/L5.0 Total/NA5013JSM6200-B m,p-Xylenes - DL 100 ug/L9.0 Total/NA50190SM6200-B o-Xylene - DL 50 ug/L4.4 Total/NA5029JSM6200-B 4-Isopropyltoluene - DL 50 ug/L3.3 Total/NA5048JSM6200-B N-Propylbenzene - DL 50 ug/L3.7 Total/NA50180SM6200-B 1,3,5-Trimethylbenzene - DL 50 ug/L5.0 Total/NA50740SM6200-B 1,2,4-Trimethylbenzene - DL 50 ug/L3.4 Total/NA501700SM6200-B Isopropylbenzene - DL 50 ug/L6.5 Total/NA5042JSM6200-B Xylenes, Total - DL 50 ug/L11 Total/NA50220SM6200-B Naphthalene - DL 50 ug/L4.3 Total/NA5021JSM6200-B Eurofins Raleigh This Detection Summary does not include radiochemical test results. Page 6 of 22 8/15/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-22856-1Client: Earth Systems LLC Project/Site: Church St FF/BP #172 Lab Sample ID: 752-22856-1Client Sample ID: MW-1A Matrix: WaterDate Collected: 08/08/24 10:28 Date Received: 08/08/24 12:55 Method: SM6200-B - Volatile Organic Compounds - DL RL MDL <4.6 50 4.6 ug/L 08/13/24 19:56 50 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Dichlorodifluoromethane 50 2.5 ug/L 08/13/24 19:56 50<2.5Chloromethane 50 4.2 ug/L 08/13/24 19:56 50<4.2Vinyl chloride 50 14 ug/L 08/13/24 19:56 50<14Bromomethane 50 9.0 ug/L 08/13/24 19:56 50<9.0Chloroethane 50 7.5 ug/L 08/13/24 19:56 50<7.5Trichlorofluoromethane 50 7.5 ug/L 08/13/24 19:56 50<7.51,1-Dichloroethene 100 3.5 ug/L 08/13/24 19:56 50<3.5Methylene Chloride 50 6.0 ug/L 08/13/24 19:56 50<6.0Methyl tert-butyl ether 50 5.5 ug/L 08/13/24 19:56 50<5.5trans-1,2-Dichloroethene 50 2.5 ug/L 08/13/24 19:56 50<2.51,1-Dichloroethane 50 11 ug/L 08/13/24 19:56 5022JIsopropyl ether 50 3.8 ug/L 08/13/24 19:56 50<3.8cis-1,2-Dichloroethene 50 6.0 ug/L 08/13/24 19:56 50<6.02,2-Dichloropropane 50 5.5 ug/L 08/13/24 19:56 50<5.5Bromochloromethane 50 4.2 ug/L 08/13/24 19:56 5039JChloroform 50 7.5 ug/L 08/13/24 19:56 50<7.51,1,1-Trichloroethane 50 3.2 ug/L 08/13/24 19:56 50<3.21,1-Dichloropropene 50 4.1 ug/L 08/13/24 19:56 50<4.1Carbon tetrachloride 50 4.1 ug/L 08/13/24 19:56 50<4.11,2-Dichloroethane 50 2.5 ug/L 08/13/24 19:56 5039JBenzene 50 6.5 ug/L 08/13/24 19:56 50<6.5Trichloroethene 50 4.9 ug/L 08/13/24 19:56 50<4.91,2-Dichloropropane 50 6.5 ug/L 08/13/24 19:56 50<6.5Dibromomethane 50 5.0 ug/L 08/13/24 19:56 50<5.0Bromodichloromethane 50 3.7 ug/L 08/13/24 19:56 50<3.7cis-1,3-Dichloropropene 50 2.7 ug/L 08/13/24 19:56 509.0 JToluene 50 4.0 ug/L 08/13/24 19:56 50<4.0trans-1,3-Dichloropropene 50 3.4 ug/L 08/13/24 19:56 50<3.41,1,2-Trichloroethane 50 7.5 ug/L 08/13/24 19:56 50<7.51,3-Dichloropropane 50 5.0 ug/L 08/13/24 19:56 50<5.0Tetrachloroethene 50 3.4 ug/L 08/13/24 19:56 50<3.4Dibromochloromethane 50 21 ug/L 08/13/24 19:56 50<211,2-Dibromoethane 50 3.5 ug/L 08/13/24 19:56 50<3.5Chlorobenzene 50 4.6 ug/L 08/13/24 19:56 50<4.61,1,1,2-Tetrachloroethane 50 5.0 ug/L 08/13/24 19:56 5013JEthylbenzene 50 18 ug/L 08/13/24 19:56 50<18 *+Freon 113 100 9.0 ug/L 08/13/24 19:56 50190m,p-Xylenes 50 4.4 ug/L 08/13/24 19:56 5029Jo-Xylene 50 4.1 ug/L 08/13/24 19:56 50<4.1Styrene 50 10 ug/L 08/13/24 19:56 50<10Bromoform 50 3.3 ug/L 08/13/24 19:56 5048J4-Isopropyltoluene 50 4.3 ug/L 08/13/24 19:56 50<4.31,1,2,2-Tetrachloroethane 50 6.5 ug/L 08/13/24 19:56 50<6.5Bromobenzene 50 7.5 ug/L 08/13/24 19:56 50<7.51,2,3-Trichloropropane 50 3.7 ug/L 08/13/24 19:56 50180N-Propylbenzene 50 5.0 ug/L 08/13/24 19:56 50<5.02-Chlorotoluene 50 5.0 ug/L 08/13/24 19:56 507401,3,5-Trimethylbenzene 50 5.0 ug/L 08/13/24 19:56 50<5.04-Chlorotoluene Eurofins Raleigh Page 7 of 22 8/15/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-22856-1Client: Earth Systems LLC Project/Site: Church St FF/BP #172 Lab Sample ID: 752-22856-1Client Sample ID: MW-1A Matrix: WaterDate Collected: 08/08/24 10:28 Date Received: 08/08/24 12:55 Method: SM6200-B - Volatile Organic Compounds - DL (Continued) RL MDL <4.7 50 4.7 ug/L 08/13/24 19:56 50 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier tert-Butylbenzene 50 3.4 ug/L 08/13/24 19:56 5017001,2,4-Trimethylbenzene 50 2.7 ug/L 08/13/24 19:56 50<2.7sec-Butylbenzene 50 4.6 ug/L 08/13/24 19:56 50<4.61,3-Dichlorobenzene 50 6.5 ug/L 08/13/24 19:56 5042JIsopropylbenzene 50 5.0 ug/L 08/13/24 19:56 50<5.01,4-Dichlorobenzene 50 3.7 ug/L 08/13/24 19:56 50<3.7n-Butylbenzene 50 2.6 ug/L 08/13/24 19:56 50<2.61,2-Dichlorobenzene 50 24 ug/L 08/13/24 19:56 50<241,2-Dibromo-3-Chloropropane 50 4.9 ug/L 08/13/24 19:56 50<4.91,2,4-Trichlorobenzene 50 7.5 ug/L 08/13/24 19:56 50<7.5Hexachlorobutadiene 50 11 ug/L 08/13/24 19:56 50220Xylenes, Total 50 13 ug/L 08/13/24 19:56 50<131,2,3-Trichlorobenzene 50 4.3 ug/L 08/13/24 19:56 5021JNaphthalene Toluene-d8 (Surr)96 70-130 08/13/24 19:56 50 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery 4-Bromofluorobenzene (Surr)87 08/13/24 19:56 5070-130 Dibromofluoromethane (Surr)100 08/13/24 19:56 5070-130 Eurofins Raleigh Page 8 of 22 8/15/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Surrogate Summary Job ID: 752-22856-1Client: Earth Systems LLC Project/Site: Church St FF/BP #172 Method: SM6200-B - Volatile Organic Compounds Prep Type: Total/NAMatrix: Water Lab Sample ID Client Sample ID (70-130)(70-130)(70-130) TOL BFB DBFM 96 87 100752-22856-1 - DL Percent Surrogate Recovery (Acceptance Limits) MW-1A 95 94 94LCS 752-8342/8 Lab Control Sample 88 84 86LCSD 752-8342/9 Lab Control Sample Dup 91 83 96MB 752-8342/12 Method Blank 93 85 95MRL 752-8342/7 Lab Control Sample Surrogate Legend TOL = Toluene-d8 (Surr) BFB = 4-Bromofluorobenzene (Surr) DBFM = Dibromofluoromethane (Surr) Eurofins Raleigh Page 9 of 22 8/15/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-22856-1Client: Earth Systems LLC Project/Site: Church St FF/BP #172 Method: SM6200-B - Volatile Organic Compounds Client Sample ID: Method BlankLab Sample ID: MB 752-8342/12 Matrix: Water Prep Type: Total/NA Analysis Batch: 8342 RL MDL Dichlorodifluoromethane <0.091 1.0 0.091 ug/L 08/13/24 15:29 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier <0.050 0.0501.0 ug/L 08/13/24 15:29 1Chloromethane <0.083 0.0831.0 ug/L 08/13/24 15:29 1Vinyl chloride <0.28 0.281.0 ug/L 08/13/24 15:29 1Bromomethane <0.18 0.181.0 ug/L 08/13/24 15:29 1Chloroethane <0.15 0.151.0 ug/L 08/13/24 15:29 1Trichlorofluoromethane <0.15 0.151.0 ug/L 08/13/24 15:29 11,1-Dichloroethene <0.070 0.0702.0 ug/L 08/13/24 15:29 1Methylene Chloride <0.12 0.121.0 ug/L 08/13/24 15:29 1Methyl tert-butyl ether <0.11 0.111.0 ug/L 08/13/24 15:29 1trans-1,2-Dichloroethene <0.050 0.0501.0 ug/L 08/13/24 15:29 11,1-Dichloroethane <0.21 0.211.0 ug/L 08/13/24 15:29 1Isopropyl ether <0.075 0.0751.0 ug/L 08/13/24 15:29 1cis-1,2-Dichloroethene <0.12 0.121.0 ug/L 08/13/24 15:29 12,2-Dichloropropane <0.11 0.111.0 ug/L 08/13/24 15:29 1Bromochloromethane <0.083 0.0831.0 ug/L 08/13/24 15:29 1Chloroform <0.15 0.151.0 ug/L 08/13/24 15:29 11,1,1-Trichloroethane <0.063 0.0631.0 ug/L 08/13/24 15:29 11,1-Dichloropropene <0.082 0.0821.0 ug/L 08/13/24 15:29 1Carbon tetrachloride <0.082 0.0821.0 ug/L 08/13/24 15:29 11,2-Dichloroethane <0.050 0.0501.0 ug/L 08/13/24 15:29 1Benzene <0.13 0.131.0 ug/L 08/13/24 15:29 1Trichloroethene <0.098 0.0981.0 ug/L 08/13/24 15:29 11,2-Dichloropropane <0.13 0.131.0 ug/L 08/13/24 15:29 1Dibromomethane <0.10 0.101.0 ug/L 08/13/24 15:29 1Bromodichloromethane <0.073 0.0731.0 ug/L 08/13/24 15:29 1cis-1,3-Dichloropropene <0.053 0.0531.0 ug/L 08/13/24 15:29 1Toluene <0.080 0.0801.0 ug/L 08/13/24 15:29 1trans-1,3-Dichloropropene <0.068 0.0681.0 ug/L 08/13/24 15:29 11,1,2-Trichloroethane <0.15 0.151.0 ug/L 08/13/24 15:29 11,3-Dichloropropane <0.099 0.0991.0 ug/L 08/13/24 15:29 1Tetrachloroethene <0.067 0.0671.0 ug/L 08/13/24 15:29 1Dibromochloromethane <0.42 0.421.0 ug/L 08/13/24 15:29 11,2-Dibromoethane <0.069 0.0691.0 ug/L 08/13/24 15:29 1Chlorobenzene <0.091 0.0911.0 ug/L 08/13/24 15:29 11,1,1,2-Tetrachloroethane <0.10 0.101.0 ug/L 08/13/24 15:29 1Ethylbenzene <0.35 0.351.0 ug/L 08/13/24 15:29 1Freon 113 <0.18 0.182.0 ug/L 08/13/24 15:29 1m,p-Xylenes <0.088 0.0881.0 ug/L 08/13/24 15:29 1o-Xylene <0.082 0.0821.0 ug/L 08/13/24 15:29 1Styrene <0.20 0.201.0 ug/L 08/13/24 15:29 1Bromoform <0.066 0.0661.0 ug/L 08/13/24 15:29 14-Isopropyltoluene <0.085 0.0851.0 ug/L 08/13/24 15:29 11,1,2,2-Tetrachloroethane <0.13 0.131.0 ug/L 08/13/24 15:29 1Bromobenzene <0.15 0.151.0 ug/L 08/13/24 15:29 11,2,3-Trichloropropane <0.073 0.0731.0 ug/L 08/13/24 15:29 1N-Propylbenzene <0.10 0.101.0 ug/L 08/13/24 15:29 12-Chlorotoluene <0.10 0.101.0 ug/L 08/13/24 15:29 11,3,5-Trimethylbenzene Eurofins Raleigh Page 10 of 22 8/15/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-22856-1Client: Earth Systems LLC Project/Site: Church St FF/BP #172 Method: SM6200-B - Volatile Organic Compounds (Continued) Client Sample ID: Method BlankLab Sample ID: MB 752-8342/12 Matrix: Water Prep Type: Total/NA Analysis Batch: 8342 RL MDL 4-Chlorotoluene <0.10 1.0 0.10 ug/L 08/13/24 15:29 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier <0.094 0.0941.0 ug/L 08/13/24 15:29 1tert-Butylbenzene <0.067 0.0671.0 ug/L 08/13/24 15:29 11,2,4-Trimethylbenzene <0.053 0.0531.0 ug/L 08/13/24 15:29 1sec-Butylbenzene <0.092 0.0921.0 ug/L 08/13/24 15:29 11,3-Dichlorobenzene <0.13 0.131.0 ug/L 08/13/24 15:29 1Isopropylbenzene <0.10 0.101.0 ug/L 08/13/24 15:29 11,4-Dichlorobenzene <0.074 0.0741.0 ug/L 08/13/24 15:29 1n-Butylbenzene <0.052 0.0521.0 ug/L 08/13/24 15:29 11,2-Dichlorobenzene <0.48 0.481.0 ug/L 08/13/24 15:29 11,2-Dibromo-3-Chloropropane 0.106 J 0.0971.0 ug/L 08/13/24 15:29 11,2,4-Trichlorobenzene <0.15 0.151.0 ug/L 08/13/24 15:29 1Hexachlorobutadiene <0.22 0.221.0 ug/L 08/13/24 15:29 1Xylenes, Total <0.25 0.251.0 ug/L 08/13/24 15:29 11,2,3-Trichlorobenzene <0.086 0.0861.0 ug/L 08/13/24 15:29 1Naphthalene Toluene-d8 (Surr)91 70-130 08/13/24 15:29 1 MB MB Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery 83 08/13/24 15:29 14-Bromofluorobenzene (Surr)70-130 96 08/13/24 15:29 1Dibromofluoromethane (Surr)70-130 Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-8342/8 Matrix: Water Prep Type: Total/NA Analysis Batch: 8342 Dichlorodifluoromethane 20.0 24.1 ug/L 120 60-140 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Chloromethane 20.0 19.1 ug/L 96 60-140 Vinyl chloride 20.0 22.6 ug/L 113 60-140 Bromomethane 20.0 16.1 ug/L 80 60-140 Chloroethane 20.0 19.8 ug/L 99 60-140 Trichlorofluoromethane 20.0 23.1 ug/L 115 60-140 1,1-Dichloroethene 20.0 23.0 ug/L 115 70-130 Methylene Chloride 20.0 21.9 ug/L 109 70-130 Methyl tert-butyl ether 20.0 23.7 ug/L 118 70-130 trans-1,2-Dichloroethene 20.0 21.8 ug/L 109 70-130 1,1-Dichloroethane 20.0 21.7 ug/L 108 70-130 Isopropyl ether 20.0 23.5 ug/L 118 70-130 cis-1,2-Dichloroethene 20.0 24.3 ug/L 121 70-130 2,2-Dichloropropane 20.0 25.1 ug/L 126 70-130 Bromochloromethane 20.0 21.3 ug/L 107 70-130 Chloroform 20.0 19.3 ug/L 96 70-130 1,1,1-Trichloroethane 20.0 22.9 ug/L 115 70-130 1,1-Dichloropropene 20.0 22.7 ug/L 113 70-130 Carbon tetrachloride 20.0 23.1 ug/L 116 70-130 1,2-Dichloroethane 20.0 21.3 ug/L 107 70-130 Benzene 20.0 21.3 ug/L 107 70-130 Trichloroethene 20.0 21.5 ug/L 108 70-130 Eurofins Raleigh Page 11 of 22 8/15/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-22856-1Client: Earth Systems LLC Project/Site: Church St FF/BP #172 Method: SM6200-B - Volatile Organic Compounds (Continued) Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-8342/8 Matrix: Water Prep Type: Total/NA Analysis Batch: 8342 1,2-Dichloropropane 20.0 21.2 ug/L 106 70-130 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Dibromomethane 20.0 22.1 ug/L 111 70-130 Bromodichloromethane 20.0 22.2 ug/L 111 70-130 cis-1,3-Dichloropropene 20.0 23.7 ug/L 118 70-130 Toluene 20.0 20.5 ug/L 102 70-130 trans-1,3-Dichloropropene 20.0 23.8 ug/L 119 70-130 1,1,2-Trichloroethane 20.0 21.0 ug/L 105 70-130 1,3-Dichloropropane 20.0 20.6 ug/L 103 70-130 Tetrachloroethene 20.0 22.0 ug/L 110 70-130 Dibromochloromethane 20.0 21.7 ug/L 109 70-130 1,2-Dibromoethane 20.0 21.5 ug/L 107 70-130 Chlorobenzene 20.0 21.2 ug/L 106 70-130 1,1,1,2-Tetrachloroethane 20.0 21.0 ug/L 105 70-130 Ethylbenzene 20.0 22.8 ug/L 114 70-130 Freon 113 40.0 57.6 *+ug/L 144 70-130 m,p-Xylenes 40.0 47.5 ug/L 119 70-130 o-Xylene 20.0 22.9 ug/L 115 70-130 Styrene 20.0 23.4 ug/L 117 70-130 Bromoform 20.0 22.8 ug/L 114 70-130 4-Isopropyltoluene 20.0 20.1 ug/L 101 70-130 1,1,2,2-Tetrachloroethane 20.0 21.0 ug/L 105 70-130 Bromobenzene 20.0 22.4 ug/L 112 70-130 1,2,3-Trichloropropane 20.0 21.0 ug/L 105 70-130 N-Propylbenzene 20.0 24.3 ug/L 121 70-130 2-Chlorotoluene 20.0 22.0 ug/L 110 70-130 1,3,5-Trimethylbenzene 20.0 22.7 ug/L 113 70-130 4-Chlorotoluene 20.0 22.2 ug/L 111 70-130 tert-Butylbenzene 20.0 23.7 ug/L 118 70-130 1,2,4-Trimethylbenzene 20.0 23.3 ug/L 117 70-130 sec-Butylbenzene 20.0 25.6 ug/L 128 70-130 1,3-Dichlorobenzene 20.0 21.5 ug/L 108 70-130 Isopropylbenzene 20.0 24.8 ug/L 124 70-130 1,4-Dichlorobenzene 20.0 21.1 ug/L 105 70-130 n-Butylbenzene 20.0 24.0 ug/L 120 70-130 1,2-Dichlorobenzene 20.0 21.2 ug/L 106 70-130 1,2-Dibromo-3-Chloropropane 20.0 23.1 ug/L 115 70-130 1,2,4-Trichlorobenzene 20.0 22.8 ug/L 114 70-130 Hexachlorobutadiene 20.0 22.6 ug/L 113 70-130 Xylenes, Total 60.0 70.4 ug/L 117 70-130 1,2,3-Trichlorobenzene 20.0 22.4 ug/L 112 70-130 Naphthalene 20.0 24.5 ug/L 123 70-130 Toluene-d8 (Surr)70 -130 Surrogate 95 LCS LCS Qualifier Limits%Recovery 944-Bromofluorobenzene (Surr)70 -130 94Dibromofluoromethane (Surr)70 -130 Eurofins Raleigh Page 12 of 22 8/15/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-22856-1Client: Earth Systems LLC Project/Site: Church St FF/BP #172 Method: SM6200-B - Volatile Organic Compounds (Continued) Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-8342/9 Matrix: Water Prep Type: Total/NA Analysis Batch: 8342 Dichlorodifluoromethane 20.0 21.8 ug/L 109 60-140 10 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Chloromethane 20.0 18.3 ug/L 91 60-140 5 Vinyl chloride 20.0 20.2 ug/L 101 60-140 11 Bromomethane 20.0 15.2 ug/L 76 60-140 6 Chloroethane 20.0 15.8 ug/L 79 60-140 23 Trichlorofluoromethane 20.0 20.8 ug/L 104 60-140 10 1,1-Dichloroethene 20.0 20.5 ug/L 103 70-130 11 Methylene Chloride 20.0 19.7 ug/L 99 70-130 10 Methyl tert-butyl ether 20.0 22.1 ug/L 111 70-130 7 trans-1,2-Dichloroethene 20.0 19.9 ug/L 100 70-130 9 1,1-Dichloroethane 20.0 19.6 ug/L 98 70-130 10 Isopropyl ether 20.0 21.9 ug/L 110 70-130 7 cis-1,2-Dichloroethene 20.0 22.5 ug/L 112 70-130 8 2,2-Dichloropropane 20.0 22.7 ug/L 113 70-130 10 Bromochloromethane 20.0 20.0 ug/L 100 70-130 6 Chloroform 20.0 17.6 ug/L 88 70-130 9 1,1,1-Trichloroethane 20.0 20.9 ug/L 104 70-130 9 1,1-Dichloropropene 20.0 20.4 ug/L 102 70-130 11 Carbon tetrachloride 20.0 21.2 ug/L 106 70-130 9 1,2-Dichloroethane 20.0 20.1 ug/L 101 70-130 6 Benzene 20.0 19.6 ug/L 98 70-130 8 Trichloroethene 20.0 19.5 ug/L 97 70-130 10 1,2-Dichloropropane 20.0 19.6 ug/L 98 70-130 8 Dibromomethane 20.0 20.3 ug/L 101 70-130 9 Bromodichloromethane 20.0 20.2 ug/L 101 70-130 9 cis-1,3-Dichloropropene 20.0 21.6 ug/L 108 70-130 9 Toluene 20.0 19.4 ug/L 97 70-130 6 trans-1,3-Dichloropropene 20.0 22.9 ug/L 114 70-130 4 1,1,2-Trichloroethane 20.0 19.5 ug/L 98 70-130 7 1,3-Dichloropropane 20.0 19.2 ug/L 96 70-130 7 Tetrachloroethene 20.0 20.3 ug/L 102 70-130 8 Dibromochloromethane 20.0 20.6 ug/L 103 70-130 5 1,2-Dibromoethane 20.0 20.1 ug/L 101 70-130 6 Chlorobenzene 20.0 19.6 ug/L 98 70-130 8 1,1,1,2-Tetrachloroethane 20.0 19.7 ug/L 99 70-130 7 Ethylbenzene 20.0 21.2 ug/L 106 70-130 7 Freon 113 40.0 52.2 *+ug/L 131 70-130 10 m,p-Xylenes 40.0 44.0 ug/L 110 70-130 8 o-Xylene 20.0 21.3 ug/L 107 70-130 7 Styrene 20.0 21.8 ug/L 109 70-130 7 Bromoform 20.0 21.5 ug/L 107 70-130 6 4-Isopropyltoluene 20.0 18.6 ug/L 93 70-130 8 1,1,2,2-Tetrachloroethane 20.0 20.1 ug/L 101 70-130 5 Bromobenzene 20.0 20.8 ug/L 104 70-130 8 1,2,3-Trichloropropane 20.0 19.4 ug/L 97 70-130 8 N-Propylbenzene 20.0 22.6 ug/L 113 70-130 7 2-Chlorotoluene 20.0 20.7 ug/L 104 70-130 6 1,3,5-Trimethylbenzene 20.0 21.4 ug/L 107 70-130 6 Eurofins Raleigh Page 13 of 22 8/15/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-22856-1Client: Earth Systems LLC Project/Site: Church St FF/BP #172 Method: SM6200-B - Volatile Organic Compounds (Continued) Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-8342/9 Matrix: Water Prep Type: Total/NA Analysis Batch: 8342 4-Chlorotoluene 20.0 20.9 ug/L 104 70-130 6 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD tert-Butylbenzene 20.0 22.1 ug/L 110 70-130 7 1,2,4-Trimethylbenzene 20.0 22.0 ug/L 110 70-130 6 sec-Butylbenzene 20.0 23.7 ug/L 118 70-130 8 1,3-Dichlorobenzene 20.0 20.4 ug/L 102 70-130 5 Isopropylbenzene 20.0 23.0 ug/L 115 70-130 8 1,4-Dichlorobenzene 20.0 19.9 ug/L 99 70-130 6 n-Butylbenzene 20.0 22.0 ug/L 110 70-130 9 1,2-Dichlorobenzene 20.0 20.2 ug/L 101 70-130 5 1,2-Dibromo-3-Chloropropane 20.0 21.8 ug/L 109 70-130 6 1,2,4-Trichlorobenzene 20.0 21.9 ug/L 109 70-130 4 Hexachlorobutadiene 20.0 20.7 ug/L 104 70-130 9 Xylenes, Total 60.0 65.3 ug/L 109 70-130 8 1,2,3-Trichlorobenzene 20.0 21.8 ug/L 109 70-130 3 Naphthalene 20.0 23.7 ug/L 119 70-130 3 Toluene-d8 (Surr)70 -130 Surrogate 88 LCSD LCSD Qualifier Limits%Recovery 844-Bromofluorobenzene (Surr)70 -130 86Dibromofluoromethane (Surr)70 -130 Client Sample ID: Lab Control SampleLab Sample ID: MRL 752-8342/7 Matrix: Water Prep Type: Total/NA Analysis Batch: 8342 Dichlorodifluoromethane 1.00 1.43 ug/L 143 Analyte MRL MRL DUnitResultQualifier %Rec Spike Added %Rec Limits Chloromethane 1.00 1.45 ug/L 145 Vinyl chloride 1.00 1.18 ug/L 118 Bromomethane 1.00 1.85 ug/L 185 Chloroethane 1.00 1.06 ug/L 106 Trichlorofluoromethane 1.00 1.28 ug/L 128 1,1-Dichloroethene 1.00 1.55 ug/L 155 Methylene Chloride 1.00 0.458 J ug/L 46 Methyl tert-butyl ether 1.00 1.21 ug/L 121 trans-1,2-Dichloroethene 1.00 1.61 ug/L 161 1,1-Dichloroethane 1.00 1.43 ug/L 143 Isopropyl ether 1.00 1.20 ug/L 120 cis-1,2-Dichloroethene 1.00 1.48 ug/L 148 2,2-Dichloropropane 1.00 1.43 ug/L 143 Bromochloromethane 1.00 1.34 ug/L 134 Chloroform 1.00 1.47 ug/L 147 1,1,1-Trichloroethane 1.00 1.51 ug/L 151 1,1-Dichloropropene 1.00 1.44 ug/L 144 Carbon tetrachloride 1.00 1.28 ug/L 128 1,2-Dichloroethane 1.00 1.34 ug/L 134 Benzene 1.00 1.39 ug/L 139 Trichloroethene 1.00 1.51 ug/L 151 Eurofins Raleigh Page 14 of 22 8/15/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-22856-1Client: Earth Systems LLC Project/Site: Church St FF/BP #172 Method: SM6200-B - Volatile Organic Compounds (Continued) Client Sample ID: Lab Control SampleLab Sample ID: MRL 752-8342/7 Matrix: Water Prep Type: Total/NA Analysis Batch: 8342 1,2-Dichloropropane 1.00 1.31 ug/L 131 Analyte MRL MRL DUnitResultQualifier %Rec Spike Added %Rec Limits Dibromomethane 1.00 1.38 ug/L 138 Bromodichloromethane 1.00 1.25 ug/L 125 cis-1,3-Dichloropropene 1.00 1.15 ug/L 115 Toluene 1.00 1.48 ug/L 148 trans-1,3-Dichloropropene 1.00 1.11 ug/L 111 1,1,2-Trichloroethane 1.00 1.19 ug/L 119 1,3-Dichloropropane 1.00 1.17 ug/L 117 Tetrachloroethene 1.00 1.60 ug/L 160 Dibromochloromethane 1.00 1.12 ug/L 112 1,2-Dibromoethane 1.00 1.13 ug/L 113 Chlorobenzene 1.00 1.48 ug/L 148 1,1,1,2-Tetrachloroethane 1.00 1.17 ug/L 117 Ethylbenzene 1.00 1.46 ug/L 146 Freon 113 1.00 1.53 ug/L 153 m,p-Xylenes 2.00 2.86 ug/L 143 o-Xylene 1.00 1.27 ug/L 127 Styrene 1.00 1.20 ug/L 120 Bromoform 1.00 1.12 ug/L 112 4-Isopropyltoluene 1.00 1.91 ug/L 191 1,1,2,2-Tetrachloroethane 1.00 1.23 ug/L 123 Bromobenzene 1.00 1.44 ug/L 144 1,2,3-Trichloropropane 1.00 1.26 ug/L 126 N-Propylbenzene 1.00 1.63 ug/L 163 2-Chlorotoluene 1.00 1.47 ug/L 147 1,3,5-Trimethylbenzene 1.00 1.38 ug/L 138 4-Chlorotoluene 1.00 1.52 ug/L 152 tert-Butylbenzene 1.00 1.41 ug/L 141 1,2,4-Trimethylbenzene 1.00 1.38 ug/L 138 sec-Butylbenzene 1.00 1.48 ug/L 148 1,3-Dichlorobenzene 1.00 1.61 ug/L 161 Isopropylbenzene 1.00 1.37 ug/L 137 1,4-Dichlorobenzene 1.00 1.71 ug/L 171 n-Butylbenzene 1.00 1.71 ug/L 171 1,2-Dichlorobenzene 1.00 1.52 ug/L 152 1,2-Dibromo-3-Chloropropane 1.00 1.27 ug/L 127 1,2,4-Trichlorobenzene 1.00 1.77 ug/L 177 Hexachlorobutadiene 1.00 2.09 ug/L 209 Xylenes, Total 3.00 4.13 ug/L 138 1,2,3-Trichlorobenzene 1.00 1.68 ug/L 168 Naphthalene 1.00 1.26 ug/L 126 Toluene-d8 (Surr)70 -130 Surrogate 93 MRL MRL Qualifier Limits%Recovery 854-Bromofluorobenzene (Surr)70 -130 95Dibromofluoromethane (Surr)70 -130 Eurofins Raleigh Page 15 of 22 8/15/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Association Summary Job ID: 752-22856-1Client: Earth Systems LLC Project/Site: Church St FF/BP #172 GC/MS VOA Analysis Batch: 8342 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water SM6200-B752-22856-1 - DL MW-1A Total/NA Water SM6200-BMB 752-8342/12 Method Blank Total/NA Water SM6200-BLCS 752-8342/8 Lab Control Sample Total/NA Water SM6200-BLCSD 752-8342/9 Lab Control Sample Dup Total/NA Water SM6200-BMRL 752-8342/7 Lab Control Sample Total/NA Eurofins Raleigh Page 16 of 22 8/15/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Lab Chronicle Client: Earth Systems LLC Job ID: 752-22856-1 Project/Site: Church St FF/BP #172 Client Sample ID: MW-1A Lab Sample ID: 752-22856-1 Matrix: WaterDate Collected: 08/08/24 10:28 Date Received: 08/08/24 12:55 Analysis SM6200-B RY50DL8342 EET RAL Type Batch Batch MethodPrep Type LabAnalystRun Prepared or Analyzed Batch Number Dilution Factor Total/NA 08/13/24 19:56 Laboratory References: EET RAL = Eurofins Raleigh, 104 Woodwinds Industrial Court, Suite A, Cary, NC 27511, TEL (919)467-3090 Eurofins Raleigh Page 17 of 22 8/15/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Accreditation/Certification Summary Client: Earth Systems LLC Job ID: 752-22856-1 Project/Site: Church St FF/BP #172 Laboratory: Eurofins Raleigh All accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report. Authority Program Identification Number Expiration Date Florida NELAP E87610 06-30-25 North Carolina (DW)State 37724 07-31-25 North Carolina (WW/SW)State 591 12-31-24 Virginia NELAP 460146 06-14-25 Eurofins Raleigh Page 18 of 22 8/15/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Method Summary Job ID: 752-22856-1Client: Earth Systems LLC Project/Site: Church St FF/BP #172 Method Method Description LaboratoryProtocol SMSM6200-B Volatile Organic Compounds EET RAL SMSM6200-B Purge and Trap EET RAL Protocol References: SM = "Standard Methods For The Examination Of Water And Wastewater" Laboratory References: EET RAL = Eurofins Raleigh, 104 Woodwinds Industrial Court, Suite A, Cary, NC 27511, TEL (919)467-3090 Eurofins Raleigh Page 19 of 22 8/15/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Sample Summary Client: Earth Systems LLC Job ID: 752-22856-1 Project/Site: Church St FF/BP #172 Lab Sample ID Client Sample ID Matrix Collected Received 752-22856-1 MW-1A Water 08/08/24 10:28 08/08/24 12:55 Eurofins RaleighPage 20 of 22 8/15/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Page 21 of 22 8/15/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Login Sample Receipt Checklist Client: Earth Systems LLC Job Number: 752-22856-1 Login Number: 22856 Question Answer Comment Creator: Barnes, Sara List Source: Eurofins Raleigh List Number: 1 TrueRadioactivity wasn't checked or is </= background as measured by a survey meter. TrueThe cooler's custody seal, if present, is intact. TrueSample custody seals, if present, are intact. TrueThe cooler or samples do not appear to have been compromised or tampered with. TrueSamples were received on ice. TrueCooler Temperature is acceptable. TrueCooler Temperature is recorded. TrueCOC is present. TrueCOC is filled out in ink and legible. TrueCOC is filled out with all pertinent information. TrueIs the Field Sampler's name present on COC? TrueThere are no discrepancies between the containers received and the COC. TrueSamples are received within Holding Time (excluding tests with immediate HTs) TrueSample containers have legible labels. TrueContainers are not broken or leaking. TrueSample collection date/times are provided. TrueAppropriate sample containers are used. TrueSample bottles are completely filled. TrueSample Preservation Verified. TrueThere is sufficient vol. for all requested analyses, incl. any requested MS/MSDs TrueContainers requiring zero headspace have no headspace or bubble is <6mm (1/4"). TrueMultiphasic samples are not present. TrueSamples do not require splitting or compositing. TrueResidual Chlorine Checked. Eurofins Raleigh Page 22 of 22 8/15/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 From:Gene Mao To:James Dodson Subject:FW: Site Check Report Revised - Church Street Family Fare BP #172 - Greensboro, NC - Fac ID 00-0-0000009710 Date:Tuesday, July 30, 2024 8:28:18 AM Attachments:image157046.png image159996.png image036961.png image409473.png image508995.png image842130.png image199228.png image719377.png image970450.png image203580.png Speedway 8165 vs Family Fare 172.pdf James, I suggest taking a GW sample from MW-1A in mid-August to see the contamination levels. If they are low, I will not make a new release incident. Let me know if you have any question. Thank you. Gene Mao​​​​ Hydrogeologist Public Health Guilford County Government 400 West Market Street, Greensboro, NC 27401 336-641-3589 | m: 336-451-7638 | f: 336-641-4812 GMAO@guilfordcountync.gov | www.guilfordcountync.gov From: Gene Mao <GMAO@guilfordcountync.gov> Sent: Monday, July 29, 2024 3:49 PM To: James Dodson <jdodson@earthsys.net> Cc: Brown, James <james.brown@deq.nc.gov> Subject: RE: Site Check Report Revised - Church Street Family Fare BP #172 - Greensboro, NC - Fac ID 00-0-0000009710 James Dodson; I have reviewed the groundwater sampling results from MW-1A for Family Fare #172. Additionally, I examined the groundwater monitoring well (MW) network, flow direction, and sampling results for the last sampling event in December 2014 before incident closure for Speedway #8165. Here are the key findings: MW-1, located downgradient from the underground storage tank (UST) basin at the Speedway facility, exhibited high benzene concentration. Groundwater flowed westerly in December 2014. Benzene levels were less than 100 ppb in MW-2 and below 2L in all other upgradient and cross-gradient wells. MW-1A, situated immediately downgradient from former MW-2, detected benzene at 1200 ppb in May 2024, indicating a new release at the site. Although benzene concentration decreased significantly in July 2024, additional sampling events are necessary before no further action can be considered. Thank you. Gene Mao​​​​ Hydrogeologist Public Health Guilford County Government 400 West Market Street, Greensboro, NC 27401 336-641-3589 | m: 336-451-7638 | f: 336-641-4812 GMAO@guilfordcountync.gov | www.guilfordcountync.gov From: James Dodson <jdodson@earthsys.net> Sent: Friday, July 26, 2024 10:09 AM To: Brown, James <james.brown@deq.nc.gov> Cc: Gene Mao <GMAO@guilfordcountync.gov> Subject: Re: Site Check Report Revised - Church Street Family Fare BP #172 - Greensboro, NC - Fac ID 00-0-0000009710 *WARNING* This email originated outside Guilford County'semail system. *WARNING*Do not click unrecognized links or attachments. When in doubt, usethe Phish Alert Report button. Hi James and Gene, Please find attached a copy of the above referenced revised report. The report has been revisedsince the original site check activities were inadvertently performed for the westernmost regularunleaded gasoline spill bucket instead of the westernmost regular unleaded gasoline UST STPsump. Please let me know if you have any questions. Thanks. James Dodson, P.G. | Operations Manager - Carolinas | jdodson@earthsys.net |ESNC Environmental Consulting, P.C.1408 Christian Avenue Suite 11 | Durham, NC 27705 T. 919.910.7767 | M. 919.356.0236