6004_Duke_McGuire_LF1_July2024_WQMR_FID1914093_20241118

DUKE
ENERGY,
November 18, 2024
North Carolina Department of Environmental Quality
Division of Waste Management
Solid Waste Section
1646 Mail Service Center
Raleigh, North Carolina 28778
Attn: Ms. Sarah Moutos (submitted electronically)
Re: Semi -Annual Water Quality Monitoring Report — July 2024
Duke Energy Carolinas, LLC
McGuire Nuclear Station
Landfill No. 1 (Unlined), Permit #60-04
Dear Ms. Moutos:
Duke Energy
McGuire Nuclear Station
12700 Hagers Ferry Road
Huntersville, NC 28078
Duke Energy is providing the result of semi-annual water quality monitoring for the Duke Energy Carolinas, McGuire,
Landfill No. 1 (Unlined), located near Huntersville, North Carolina.
On July 22-25, 2024, groundwater and surface water samples were collected in accordance with the McGuire Landfill No.
1 Sampling and Analysis Plan.
A summary of the field data is presented in Table 3. The groundwater sampling field and analytical results are summarized
in Table 4. The analytical results for the constituents are compared to the groundwater standards found in Title 15A NCAC
02L .0202 (2L Standards). Results with values that attain or exceed the 2L Standards (or outside of 2L Standard range for
pH) are indicated on Table 4 by yellow highlighting. A summary of the analytical results that attain or exceed the 2L
Standards (or outside of 2L Standard range for pH) and a preliminary analysis of the cause and significance of such
occurrences are presented in Table 5.
The surface water field and analytical results are summarized in Table 6. The surface water analytical results for the
constituents are compared to the surface water standards found in Title 15A NCAC 02B .0211 (213 Standard) for Class C
WS-IV waters. No 2B Standards were exceeded during the July 2024 monitoring event.
Duke Energy personnel sample designated groundwater and surface water locations at McGuire Landfill No. 1 (Unlined)
semi-annually during January and July. The next water quality monitoring event is planned for January 2025 with a report
of monitoring results to follow.
If you need additional information regarding this submittal, please contact Ashley Healy at Ashley. Healveduke-energy.com
or [phone].
!incer All
rBrent Bare
Duke Energy
McGuire Nuclear Station
Plant Manager
www.duke-energy.com Page 1 of 1

�R USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #:
NC DENR I IEnvironmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
S&ME, Inc. (Consultant for Duke Energy)
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Julie P. Robertson, P.G. Phone: [phone]
E-mail: [e-mail]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Duke Energy Carolinas, LLC 12700 Hagers Ferry Road 6004 .0500 July 22, 23, 25, 2024
McGuire, Landfill No. 1 (Unlined) Huntersville, NC 28078
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring x❑ Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells ❑
Leachate monitoring data
Surface water monitoring data ❑
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
RX Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Julie P. Robertson, P.G. Principal Geologist 704-523-4726
Title (Area Code) Telephone Number
November 13, 2024 Affix NC Licensed/ Professional Geologist Seal
Signature Date
2016 Ayrsley Town Blvd., Suite 2-A, Charlotte, North Carolina 28273
Facility Representative Address
S&ME Engineering License # F-0176, S&ME Geology License# C-145
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009

Semi -Annual Water Quality Monitoring Report
July 2024 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 1
(Unlined) Permit No. 6004
Mecklenburg County, North Carolina
S&ME Project No. 23350793, Ph.775B

REPORT VERIFICATION
PROJECT: SEMI-ANNUAL WATER QUALITY MONITORING REPORT
DUKE ENERGY CAROLINAS, MCGUIRE, LANDFILL NO. 1
(UNLINED) PERMIT NO. 6004
S&ME PROJECT NO. 23350793, PH. 775B
TITLE: JULY 2024 SAMPLING EVENT
This document has been reviewed for accuracy and quality commensurate with the intended
application.
Prepared by:
Approved by: (-- fz�
Project Manager: Julie P. Robertson, PG
Date: 11 /13/2024
Date: 11 /13/2024
Licensed Geologist Seal:
S&ME, Inc.
2016 Ayrsley Town Blvd., Suite 2-A
Charlotte, North Carolina 28273
North Carolina Geological Corporation Number C-145
S&ME, Inc. 12016 Ayrsley Town Blvd., Suite 2-A I Charlotte, NC 282731 p 704.523.4726 1 www.smeinc.com

Semi -Annual Water Quality Monitoring Report — July 2024 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 1
(Unlined) Permit No. 6004 I I
S&ME Project No. 23350793, Ph. 775B
Table of Contents
1.0 Background........................................................................................................................1
1.1 Site Description...............................................................................................................................1
1.2 Hydrologic Setting.........................................................................................................................1
1.3 Monitoring Program......................................................................................................................1
2.0 Methods..............................................................................................................................2
2.1 Sampling and Analysis Methods.................................................................................................2
2.1.1 Groundwater and Surface Water......................................................................................................2
2.1.2 Radiological Samples.........................................................................................................................3
2.2 Statement of Work..........................................................................................................................3
3.0 Results.................................................................................................................................4
3.1 Site Groundwater Flow.................................................................................................................4
3.2 Analytical Results...........................................................................................................................4
3.2.1 Groundwater.....................................................................................................................................4
3.2.2 Surface Water....................................................................................................................................5
3.2.3 Radiological Samples.........................................................................................................................5
3.2.4 Quality Assurance / Quality Control..............................................................................................5
November 13, 2024 ii

Semi -Annual Water Quality Monitoring Report — July 2024 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 1
(Unlined) Permit No. 6004
S&ME Project No. 23350793, Ph. 775B
Appendices
Appendix I — Figures
Figure 1
Figure 2
Figure 3
Appendix II — Tables
Table 1
Table 2
Table 3
Table 4
Table 5
Table 6
Table 7
Site Location Map
Sample Locations
Shallow Groundwater Contour Map
Well Construction Information
Groundwater Flow Velocities
Field Data Parameters
Groundwater Field and Analytical Results
Results that Equal or Exceed 15A NCAC 2L Groundwater Standards
Surface Water Field and Analytical Results
Radiological Analytical Results
Appendix III — Field Sampling Forms
Appendix IV — Laboratory Reports and Chain -of -Custody Forms
s
=0
November 13, 2024

Semi -Annual Water Quality Monitoring Report — July 2024 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 1 �r
(Unlined) Permit No. 6004
S&ME Project No. 23350793, Ph. 775B
1.0 Background
1.1 Site Description
The Duke Energy Carolinas, McGuire, Landfill #1 (Unlined)' (hereafter, landfill) is located at the McGuire Nuclear
Station in Mecklenburg County, North Carolina. The landfill is permitted under North Carolina Department of
Environmental Quality (NCDEQ) Solid Waste Permit No. 6004-INDUS and is closed and no longer accepts waste.
The landfill and surrounding areas are shown on Figure 1 in Appendix I. The approximate limit of waste is shown
in Figures 2 and 3 in Appendix I.
1.2 Hydrologic Setting
The closed landfill is located south of North Carolina (NC) Highway 73, east of the Catawba River, and northwest
of Cashion Road as shown on Figures 1 and 2 in Appendix I. Cashion Road runs along a topographic divide with
topography sloping away from the road to the northwest and to the southeast. There is one surface water
drainage feature north of the landfill that drains northwest to the Catawba River as depicted on Figure 2 in
Appendix I. The Catawba River is classified as a Class C Water Supply -IV source (WS-IV).
1.3 Monitoring Program
As described in the Sampling and Analysis Plan (SAP) dated May 13, 2022, the current monitoring system at the
landfill consists of the following:
Monitoring Wells: MW-1
MW-4R
MW-1 D
MW-4DR
MW-2A
MW-413RR
MW-2D
MW-11
MW-3
MW-11 D
MW-3D
MW-11 BR
MW-313R
MW-12
MW-4
MW-12D
MW-4D
MW-13D
MW-413R
MW-13BR
Surface Water Sample Location: SW-1
' In response to the North Carolina Division of Public Health, Radiation Protection Section, November 77, 2006 letter to Duke
Energy, LLC, Duke Energy offered to indicate the landfill as unlined in reports.
November 13, 2024 1

Semi -Annual Water Quality Monitoring Report — July 2024 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 1 �r
(Unlined) Permit No. 6004
S&ME Project No. 23350793, Ph. 775B
Monitoring wells were originally installed as well pairs, consisting of one shallow well and one deep well (with the
exception of monitoring well MW-13D, which is accompanied by a bedrock well rather than a shallow well).
Shallow wells were installed with screened intervals set to bracket the water table at the time of installation. Deep
wells were constructed so that the bottom of the screen is located within residual soils just above auger refusal
and are designated with "D" to represent the deeper well within each well pair. Wells designated with "BR"
represent wells constructed so that the bottom of the screen is located within fractured bedrock.
Monitoring wells MW-4R and MW-4DR ("R" designation indicates replacement wells) were installed in 2013 near
the landfill review boundary to replace wells MW-4 and MW-4D, which are approximately 15 feet outside of the
limits of waste for the landfill. At the request of NCDEQ Solid Waste Section (NCDEQ-SWS), monitoring wells MW-
4 and MW-41D continue to be sampled along with the replacement wells.
In late 2020, six deep and bedrock monitoring wells (MW-3BR, MW-413R, MW-4BRR, MW-11 BR, MW-13D, and
MW-13BR) were installed as part of a site characterization study, and have been included with the semi-annual
sampling regime since the July 2022 sampling event. Monitoring well construction information is summarized in
Table 1 in Appendix II and monitoring well locations are shown on Figure 2 in Appendix I.
Surface water sample location SW-1 is collected from the unnamed stream (north of the landfill), upstream of the
confluence with the surface water drainage feature that ultimately discharges to the Catawba River as shown on
Figure 2 in Appendix I. SW-1 is the designated background sampling location for this monitoring program.
2.0 Methods
2.1 Sampling and Analysis Methods
Groundwater and surface water sampling activities were performed by Duke Energy Groundwater Science Group
(Duke Energy Carolinas Field Certification #99046001), in general accordance with the North Carolina Solid Waste
Management Guidelines. Copies of the July 2024 field sampling forms are included in Appendix III. The
parameters and constituents reported were selected in accordance with the SAP and the NCDEQ Division of Waste
Management, Solid Waste Section Guidelines. Groundwater and surface water samples were analyzed by the Duke
Energy Analytical Laboratory (North Carolina Laboratory Certification #248), Pace Analytical Services (North
Carolina Laboratory Certification #375), and EnRad Laboratories. The laboratory reports and chain -of -custody
forms are included in Appendix IV.
2.1.1 Groundwater and Surface Water
The groundwater and surface water samples were analyzed for the following parameters using the following
analytical methods in accordance with the SAP:
Barium, calcium, magnesium, potassium, and sodium using SW-846 EPA Test Method 6010D
Arsenic, cadmium, chromium, lead, selenium, and silver using SW-846 EPA Test Method 6020B
• Chloride and Sulfate using SW-846 EPA Test Method 9056A
November 13, 2024

Semi -Annual Water Quality Monitoring Report — July 2024 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 1
(Unlined) Permit No. 6004
S&ME Project No. 23350793, Ph. 775B
• Alkalinity using Standard Method (SM) 2320B
• 1,4-Dioxane using SW-846 EPA Test Method 8260D (SIM)
• Volatile organic compounds (VOCs) using SW-846 EPA Test Method 8260D2
It should be noted that mercury (using SW-846 EPA Test Method 7470A) is a parameter that each groundwater
and surface water sample are analyzed for, per the SAP; however, during the July 2024 sampling event, laboratory
error resulted in the exclusion of mercury from the list of sample parameters, therefore no analysis for mercury
was performed on the samples collected in July 2024. Duke Energy notified NCDEQ-SWS of the inadvertent
omission of mercury from the list of parameters analyzed in the groundwater and surface water samples collected
in July 2024 via email on November 111", 2024. Historically, mercury has not been detected at levels of concern for
the site (during the January 2024 sampling event, mercury was not detected in any of the groundwater or surface
water samples).
The surface water sample was also field -filtered using a 0.45-micron in -line filter and dissolved analyses were
performed for the following constituents:
• Arsenic, cadmium, chromium, lead, and silver using SW-846 Method 6020B
2.1.2 Radiological Samples
In accordance with the requirements of the Radioactive Materials License No. 060-0379-7 issued by the North
Carolina Department of Health and Human Services Radiation Protection Section, the following radiological
analyses were performed on groundwater and surface water samples:
• Gross alpha and beta radioactivity using ASTM Method D7283-173
• Tritium using ASTM Method D4107-084
• Gamma radioactivity for select isotopes using EPA Method 901.1
2.2 Statement of Work
S&ME completed the following tasks:
• Received field sampling data from Duke Energy (performed by Duke Energy Groundwater Sciences Group)
for monitoring wells MW-1, MW-1 D, MW-2A, MW-2D, MW-3, MW-3D, MW-313R, MW-4, MW-4D, MW-4R,
MW-4DR, MW-4BRR, MW-11, MW-11 D, MW-12, MW12D, MW-13D, MW-1313R, and surface water sample
z Laboratory analytical methods for VOCs have changed from SW-846 EPA Test Method 8260E to SW-846 EPA Test Method
8260D.
3 Laboratory analytical methods for gross alpha and beta radioactivity have changed from EPA 900ISM71108 to ASTM D7283-17.
4 Laboratory analytical methods for Tritium have changed from EPA 906.0 Modified to ASTM D4707-0&
November 13, 2024

Semi -Annual Water Quality Monitoring Report — July 2024 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 1 �r
(Unlined) Permit No. 6004
S&ME Project No. 23350793, Ph. 775B
location SW-1. The samples were collected between July 22nd and 23rd, 2024. It was noted that MW- 13D
and MW-13BR were re -sampled on July 2511, 2024 due to improper sample storage following the initial
collection of groundwater samples on July 2311, 2024 (no radiological samples required resampling on July
251"). S&ME received the laboratory analytical data from Duke Energy via e-mail correspondence from
Courtney Murphy (Duke Energy) to Jasmine Tayouga (S&ME) on October 2911, 2024.
• Reviewed the laboratory analytical results and the Electronic Data Deliverables (EDDs) provided by Duke
Energy for the samples noted above.
• Developed a shallow groundwater contour map and calculated groundwater flow velocities using survey
data and groundwater levels measured by Duke Energy Groundwater Sciences Group.
3.0 Results
3.1 Site Groundwater Flow
Shallow groundwater surface contours and groundwater flow direction in the vicinity of the landfill are shown on
Figure 3 in Appendix I. These contours were developed using the depth to groundwater measurements in the
shallow wells on the date of sampling and top of well casing elevations. Calculated groundwater flow velocities
are presented on Table 2 in Appendix II.
Based on groundwater elevations calculated for the July 2024 sampling event, groundwater flow is generally from
the southeast to the northwest toward the Catawba River.
3.2 Analytical Results
3.2.1 Groundwater
Laboratory results for groundwater samples were compared to the Title 15A NCAC Subchapter 2L Standards (2L
Standards) to evaluate compliance with NCDEQ groundwater quality standards. In one or more wells, pH
measurements were reported outside of the 2L Standard range. Concentrations greater than their respective 2L
Standards were reported in one or more wells for the following constituents: methylene chloride,
tetrachloroethylene (PCE), trichloroethene (TCE), sulfate, and vinyl chloride.
The concentrations greater than the 2L Standard (with the exception of pH) were detected in MW-3BR, MW-4,
MW-4D, MW-413R, and MW-4BRR. It should be noted that MW-4, MW-4D, and MW-4BR are located adjacent to
5 Please note that periodically, shallow monitoring well MW-72 is not used to produce groundwater contours. MW-12 was used to
produce groundwater contours for the July 2022, January 2023, and July 2023 Sampling Events. MW- 72 was not used to produce
groundwater contours in the January 2024 report and this July 2024 report. Historically, MW- 72 has experienced water level
elevation fluctuations not typical of normal seasonal variations. Duke Energy is currently evaluating the water level data and the
need for future abandonment and/or replacement.
November 13, 2024 4

Semi -Annual Water Quality Monitoring Report — July 2024 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 1 �r
(Unlined) Permit No. 6004
S&ME Project No. 23350793, Ph. 775B
the landfill limits of waste boundary; while MW-3BR and MW-4BRR are located adjacent to the landfill review
boundary.
A summary of field data parameters recorded prior to sample collection is presented in Table 3 in Appendix II. A
summary of groundwater analytical results for the current sampling event is presented in Table 4 in Appendix II.
A summary of the groundwater analytical results that equal or exceed the 2L Standards and a comparison to
historical concentration ranges are presented in Table 5 in Appendix II.
3.2.2 Surface Water
Laboratory results for the surface water sample (SW-1) were compared to the Title 15A NCAC Subchapter 2B
Standards (213 Standards) for Class C WS-IV waters to evaluate compliance with established criteria. A summary of
field data parameters recorded prior to surface water sample collection is presented in Table 3 in Appendix II. A
summary of surface water analytical results for the July 2024 sampling event is presented in Table 6 in Appendix
3.2.3 Radiological Samples
The results of the radiological analyses are presented in Table 7 in Appendix II. A copy of the laboratory report
has been submitted to the North Carolina Department of Health and Human Services Radiation Protection Section
for reference and is also included in this report in Appendix IV. S&ME did not evaluate this data.
3.2.4 Quality Assurance / Quality Control
Field -performed quality assurance and quality control (QA/QC) consisted of the collection and analysis of two field
blanks (one on each day of sampling) to evaluate if contamination was imparted to the samples by the sample
container, preservative, or other exogenous sources. One field duplicate sample per day was also collected as a
measure of sampling and analytical precision. Field blank and field duplicate samples were not collected on July
25t", 2024 during the re -sampling of MW-13D and MW-1313R. Samples for the monitoring wells and surface water
location were submitted to Duke Energy Analytical Laboratories on July 23rd, 2024; the MW-13D and MW-13BR re -
samples were submitted on July 251", 2024.
One trip blank was transported with each set of samples to evaluate the effects of shipping and laboratory sources
of contamination for Volatile Organic Compounds (VOCs). No VOCs were detected at concentrations above the
laboratory Method Reporting Limit (MRL) in the trip blank samples, nor in either of the field blank samples.
Select samples were diluted, as is normal laboratory practice, to bring samples within the calibrated range of the
analysis. Specifics regarding the samples that were diluted, including the dilution amount, are reported in the
laboratory report. Additional QA/QC data, laboratory analyses, and chain -of -custody forms are included in
Appendix IV.
November 13, 2024

Appendices

Appendix I - Figures

MW-13D
MW-13BRmw
O P �� MW
"'' MW
MW-4R 400MW-4
MW-4DR • O MW-4D
MW-4BRR� MW-4BR
LANDFILL
NO. 1
MW-11BR
MW-11 0
MW-11D
®( MW-1
O M11% MW-1D
Henry Harrison
Stillwell Dr,
NOTES:
GIS BASE LAYERS WERE OBTAINED FROM THE OWNER AND ESRI. THIS MAP IS FOR
INFORMATIONAL PURPOSES ONLY. ALL FEATURE LOCATIONS DISPLAYED ARE
APPROXIMATED. THEY ARE NOT BASED ON CIVIL SURVEY INFORMATION, UNLESS STATED
OTHERWISE.
0 400 800
GRAPHIC SCALE
(IN FEET)
LANDFILL
NO.2
SW-1
v
LEGEND
• GROUNDWATER MONITORING WELL LOCATIONS
0 SURFACE WATER SAMPLE LOCATION
1110-0—►STREAMS WITH FLOW DIRECTION
0 WATERBODIES
LANDFILL NO. 1 COMPLIANCE BOUNDARY
LANDFILL NO. 1 LIMITS OF WASTE
LANDFILL NO. 1 REVIEW BOUNDARY
DUKE ENERGY PROPERTY BOUNDARY
LANDFILL NO. 2
STREETS
2' CONTOURS
10' CONTOURS
z
O
U
0
W
W
1
04
H
►i
cr- Q
w Z
d
O
O
z Q
V
J
J �
0 0
Z 0
Q Z
J
w ~
Z
O
c� V
G
N
Q m
z_ z
J W
O �G
CIL V
Q w
V
V
w
z
w
w
0
SCALE:
1 " = 400 '
DATE:
10-10-2024
PROJECT NUMBER:
23350793,PH.775B
FIGURE NO
04

® 4AW-3
r.11e® 6�lm1
0
0000
' /,0-
�' MW-4 'o�
,1VIW-4111 676.�/ 0
4674.67 ..
/ O MW-2A'.
68702 �.
e a
/ _ 0 LANDFIL -o-
.1000
000,
\l000
•10,
o,
MW-1
/ 699.77
J V_
693.14 �°lyf 'Now -oft�,,_, �a
MW-12 " ����°O ���
702.61
NOTES:
GIS BASE LAYERS WERE OBTAINED FROM THE OWNER AND ESRI. THIS MAP IS FOR INFORMATIONAL PURPOSES ONLY. ALL FEATURE
LOCATIONS DISPLAYED ARE APPROXIMATED. THEY ARE NOT BASED ON CIVIL SURVEY INFORMATION, UNLESS STATED OTHERWISE.
MW-12 WAS NOT USED TO PRODUCE GROUNDWATER CONTOURS IN THIS JULY 2024 REPORT. HISTORICALLY, MW-12 HAS EXPERIENCED
WATER LEVEL ELEVATION FLUCTUATIONS NOT TYPICAL OF NORMAL SEASONAL VARIATIONS.
200 400
GRAPHIC SCALE (IN FEET)
Stillwell
II'
LEGEND
(D SHALLOW GROUNDWATER MONITORING LOCATION
10-10—► STREAMS WITH FLOW DIRECTION
—► GROUNDWATER FLOW DIRECTION
-- • GROUNDWATER CONTOUR - JULY 2024
LANDFILL NO. 1 COMPLIANCE BOUNDARY
LANDFILL NO. 1 LIMITS OF WASTE
- � � — LANDFILL NO. 1 REVIEW BOUNDARY
DUKE ENERGY PROPERTY BOUNDARY
STREETS
2' CONTOURS
10' CONTOURS
v
o
0
Q0
� O
O 2
H cl�
Q
z
J
O
Q
V
O
z
z
D
O
V
l7
m
z
w
J
Y
V
w
FO
SCALE:
1=200'
DATE:
10-10-2024
PROJECT NUMBER:
23350793,PH.775B
FIGURE NO
3

Appendix II - Tables

Table 1: Well Construction Information
Landfill No. 1 (Unlined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station III E
S&ME Project No: 23350793, Ph.77513
Well ID
MW-1
Install Date
..
07/18/89
GPS Coordinates
35.41146'-80.94761'
Survey Elevations
729.58 730.23
Height
Above
Ground
0.65
FM
luly 22-21, 2024
30.46 699.77
Total Well
DepthWell
Below
Top of
Casing
68.55
Screen Interval
•
58.55 to 68.55
Geology in
Screen
Interval
SAP
Well
Diameter
2
Casing
Type
S774 PPVC
MW-1 D
07/20/89
35.41147'
-80.94760'
729.75
730.61
0.86
31.46
699.15
88.22
78.22
to
88.22
SAP
2
Sch. 40 PVC
MW-2A
07/21/89
35.41306'
-80.94905'
736.96
739.67
2.71
52.65
687.02
77.57
67.57
to
77.57
SAP
2
Sch. 40 PVC
MW-2D
07/20/89
35.41308'
-80.94909'
737.41
740.77
3.36
50.05
690.72
108.82
98.82
to
108.82
PWR
2
Sch. 40 PVC
MW-3
07/10/89
35.41407'
-80.95049'
724.98
728.43
3.45
56.55
671.88
73.64
63.64
to
73.64
SAP
2
Sch. 40 PVC
MW-3D
1 07/10/89
35.41407'
-80.95050'
724.98
728.39
3.41
56.65
671.74
90.19
80.19
1 to
90.19
PWR
2
Sch. 40 PVC
MW-313R
10/13/20
35.41395'
-080.95069'
732.94
735.94
3.00
63.29
672.65
133.93
128.93
to
133.93
PWR
2
Sch. 40 PVC
MW-4
07/06/89
35.41349'
-80.95115'
738.40
741.13
2.73
64.55
676.58
74.15
64.15
to
74.15
SAP
2
Sch. 40 PVC
MW-4D
07/06/89
35.41348'
-80.95117'
738.25
740.58
2.33
64.70
675.88
102.24
92.24
to
102.24
SAP/PWR
2
Sch. 40 PVC
MW-4R
12/04/13
35.41341 °
-80.95161 °
711.15
713.87
2.72
39.20
674.67
45.73
30.73
to
45.73
SAP
2
Sch. 40 PVC
MW-413R
10/16/20
35.41348'
-80.95113
739.09
741.97
2.88
69.62
672.35
179.08
174.08
to
179.08
PWR
2
Sch. 40 PVC
MW-4DR
12/04/13
35.41340'
-80.95162'
711.15
713.75
2.60
39.35
674.40
90.40
75.40
to
90.40
SAP
2
Sch. 40 PVC
MW-413RR
10/13/20
35.41343'
-80.95161'
710.82
713.94
3.12
49.65
664.29
156.56
151.56
to
156.56
PWR
2
Sch. 40 PVC
MW-11
12/15/04
35.41138'
-80.95050'
720.10
722.60
2.50
29.46
693.14
38.45
23.45
to
38.45
SAP
2
Sch. 40 PVC
MW-11 D
12/15/04
35.41139'
-80.95047'
720.84
723.14
2.30
30.68
692.46
101.55
91.55
to
101.55
SAP
2
Sch. 40 PVC
MW-11BR
10/28/20
35.41146'
-80.95042'
723.65
726.66
3.01
35.49
691.17
205.13
200.13
to
205.13
PWR
2
Sch. 40 PVC
MW-12
12/15/04
35.41100'
-80.94917'
722.21
724.81
2.60
22.20
702.61
29.49
14.49
to
29.49
SAP
2
Sch. 40 PVC
MW-12D
12/15/04
35.41101 °
-80.94921 °
722.21
724.77
2.56
26.95
697.82
68.42
58.42
to
68.42
PWR
2
Sch. 40 PVC
MW-13D
09/22/20
35.41390'
-80.95136'
712.40
715.36
2.96
43.95
671.41
95.00
85.00
to
95.00
PWR
2
Sch. 40 PVC
MW-13BR
10/12/20
35.41387'
-80.95136'
711.49
714.40
2.91
50.89
663.51
164.45
159.45
to
164.45
PWR
2
Sch. 40 PVC
Notes:
(1)
0.010 Slot
0.010-Inch Machine -Slotted Pipe
(11)
Elevations based on NAVD88 vertical datum.
(2)
DTW
Depth to Water
(12)
Horizontal coordinates based on NAD83 datum.
(3)
Ground
Ground Surface
(13)
Top of casing and ground surface elevations from 2015 re -survey by Providence Land Group and
(4)
GW ELEV.
Groundwater Elevation
2020 survey by Wood.
(5)
PVC
Polyvinyl Chloride
(14)
MW-13D and MW-13BR were re -sampled on July 25, 2024, water levels shown above were
(6)
PWR
Partially Weathered Rock
recorded on July 25, 2024.
(7)
TOC
Top of Casing
(8)
SAP
Saprolite
(9)
Sch. 40
Schedule 40 Pipe
(10)
Total well depths
from 2015 and 2020 well depth confirmations.

REIM
Table 2: Groundwater Flow Velocities
Landfill No. 1 (Unlined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
S&ME Project No: 23350793, Ph.77513
Notes•
(1) Hydraulic gradient calculated by measuring linear distance through monitoring wells (generally perpendicular) from selected
groundwater contours.
(2) Hydraulic gradients and groundwater velocities are approximate.
(3) Hydraulic Conductivity and effective porosity are mean values for soil/saprolite taken from "Groundwater Protection Initiative
Site Characterization Report" for McGuire Nuclear Station dated June 30, 2008 by S&ME, Inc.
(4) Seepage velocity equation used to calculate groundwater flow velocity v = (K*i)/ne

Table 3: Field Data Parameters
Landfill No. 1 (Unlined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
S&ME Project No: 23350793, Ph.77513
Well ID
MW-1
Well
Date Depth
Below
•
7/23/2024 68.55
Depth to
Water
Below •
30.46
Groundwater
Elevation
699.77
Appearance
Normal
Odor Purge
..
None LF
July 22-23,
Average
Pump Rate
300
2024
Well
Volume
6.21
EVAC
Volume
4.30
EVAC
No
Temperature
18.49
Specific
Conductivity
113
PH
6.04
Turbidity
7.9
ORP
238
Dissolved
Oxygen
0.51
MW-1 D
7/23/2024
88.22
31.46
699.15
Normal
None
LF
400
9.26
2.50
No
17.38
106
6.07
4.7
253
0.42
MW-2A
7/22/2024
77.57
52.65
687.02
Normal
None
LF
280
4.06
0.90
No
19.00
157
6.13
0.9
343
2.38
MW-21D
7/22/2024
108.82
50.05
690.72
Normal
None
EOP
360
9.59
0.75
No
18.00
50
6.35
6.9
280
8.67
MW-3
7/22/2024
73.64
56.55
671.88
Normal
None
LF
300
2.79
2.70
No
19.00
69
5.66
3.9
451
6.97
MW-31D
7/22/2024
90.19
56.65
671.74
Normal
None
LF
360
5.47
2.45
No
17.00
129
6.09
1.4
337
3.18
MW-3BR
7/22/2024
133.93
63.29
672.65
Normal
None
LF
200
11.52
2.85
No
19.00
191
6.70
4.9
107
0.42
MW-4
7/22/2024
74.15
64.55
676.58
Normal
None
EOP
200
1.57
0.55
No
19.00
136
5.36
1.8
383
0.41
MW-41D
7/22/20241
102.24
64.7
675.88
Normal
None
LF
150
6.12
0.50
No
19.00
297
5.82
0.6
162
0.62
MW-4R
7/23/2024
45.73
39.20
674.67
Normal
None
LF
200
1.07
0.70
No
19.00
103
5.90
3.2
345
6.27
MW-4BR
7/22/2024
179.08
69.62
672.35
Normal
None
LF
100
17.85
1.35
No
26.00
320
9.88
1.0
129
0.72
MW-4DR
7/23/2024
90.40
39.35
674.40
Normal
None
LF
200
8.33
2.80
No
21.00
130
7.10
1.2
325
2.71
MW-4BRR
7/23/2024
156.56
49.65
664.29
Normal
None
LF
150
17.44
2.20
No
20.00
3,663
11.57
1.0
118
0.75
MW-11
7/22/20241
38.45
29.46
693.14
Normal
None
LF
400
1.47
1.65
No
15.76
81
5.77
8.7
188
0.32
MW-11 D
7/22/2024
101.55
30.68
692.46
Normal
None
LF
400
11.56
11.55
No
16.60
28
5.59
9.6
414
7.15
MW-11 BR
7/22/2024
205.13
35.49
691.17
Normal
None
LF
320
27.67
3.55
No
16.93
113
7.56
2.5
334
4.01
MW-12
7/22/2024
29.49
22.2
702.61
Turbid
None
LF
150
1.19
3.50
No
17.77
17
5.05
172.0
487
7.85
MW-12D
7/22/2024
68.42
26.95
697.82
Normal
None
LF
210
6.76
1.85
No
16.57
92
6.21
8.7
384
6.13
MW-13D
7/25/20241
95.00
43.95
671.41
Normal
None
LF
400
8.33
2.65
No
17.02
83
6.05
1.4
396
7.72
MW-13BR
7/25/2024
164.45
50.89
663.51
Normal
None
LF
120
18.52
0.45
No
22.54
188
7.01
1.1
364
5.47
SW-1
7/23/20241
NA
I NA
I NA
I Normal
I None
SWS
I NA
I NA
I NA
I NA
1 22.54
105
1 6.70
1 35.0
1 272
1 7.71
Notes•
(1)
°C
degrees Celsius
(2)
ft
feet
(3)
gal
gallons
(4)
µU/cm
micromhos per centimeter
(5)
mg/L
milligrams per liter
(6)
mL/min
milliliters per minute
(7)
mV-NHE
millivolts - normal hydrogen electrode
(8)
NA
not applicable
(9)
NTU
nephelometric turbidity unit
(10)
SU
standard units
(11)
TOC
top of casing
(12) Elevations based on NAVD88 vertical datum
(13) Purge methods: LF = Low Flow (average pump rate applicable to LF purging only); EOP = Equipment Only Purge; SWS = Surface Water Sample.
(14) EVAC indicates whether the water level in the well was drawn down to the level of the pump during purging and also the total amount purged from the well.
(15) Field sampling performed by Duke Energy Groundwater Science Group.
(16) MW-13D and MW-13BR were re -sampled on July 25, 2024, field parameters shown above are from samples collected on July 25, 2024.

Table 4: Groundwater Field and Analytical Results
Landfill No. 1 (Unlined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
S&ME Project No: 23350793, Ph.77513
Parameter
oil
Field pH
Units
lhmm�
SU
1�
6.04 6.07 6.13 6.35 5.66 6.09 6.70 5.36
5.82
July 22-23,
9.88
2024
jd����M
5.90 7.10 11.57
sws
Groundwater 15A NCAC
MDL Protection 2L Federal
(GWPS) A
5.77 5.59 7.56 5.05 6.21 6.59 7.24 NE 6.5 - 8.5 6.5 - 8.5*
Specific Conductance
µu/cm
113 106 157 50 69 129 191 136
297
320
103 130
3,663
81 28 113 17 92 94 206 NE NE
NE
Temperature
°C
18 17 19 18 19 17 19 19
19
26
19 21
20
16 17 17 18 17 19 20 NE NE
NE
M-Dichloroethane
µg/L
0.37 U
0.37 U
0.37 U
0.37 U
0.37 U
0.37 U
1.10
0.37 U
0.37 U
0.69 J
0.37 U
0.37 U
0.37 U
0.37 U
0.37 U
0.37 U
0.37 U
0.37 U
0.37 U
0.37 U
0.37
NE
6
NE
cis-1,2,-Dichloroethylene
µg/L
0.38 U
0.38 U
0.38 U
0.38 U
0.38 U
2.40
7.20
0.38 U
34.5
10.6
0.38 U
1.8
1.2
0.38 U
0.38 U
0.38 U
0.38 U
0.38 U
0.38 U
2.8
0.38
NE
70
NE
Acetone
µg/L
5.1U
5.1U
5.1U
5.1U
5.1U
5.1U
5.1U
5.1U
5.1U
5.1U
5.1U
5.1U
28.4
5.1U
5.1U
5.1U
5.1U
5.1U
5.1U
5.1U
5.1
NE
6,000
NE
Benzene
µg/L
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.43 J
0.34 U
0.91 J
0.43 J
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34
NE
1
NE
Carbon Disulfide
µg/L
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.48 J
0.40 U
0.40 U
8.2
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.36
NE
700
NE
Methylene Chloride
y
µg/L
2.OU
2.OU
2.OU
2.OU
2.OU
2.OU
17.9
gC9,L1,v1
2.0U
2.0U
11.4
gC9,L1,v1
2.0U
2.0U
2.0U
2.0U
2.0U
2.0U
2.0U
2.0U
2.0U
2.0U
2.0
NE
5
NE
Tetrachloroethylene
µg/L
0.29 U
0.29 U
0.29 U
0.29 U
0.29 U
0.29 U
0.79 J
0.90 J
0.58 J
0.29 U
0.29 U
0.29 U
0.29 U
0.29 U
0.29 U
0.29 U
0.29 U
0.29 U
0.29 U
0.29 U
0.29
NE
0.7
NE
Toluene
µg/L
0.24 U
0.24 U
0.24 U
0.24 U
0.24 U
0.24 U
0.24 U
0.24 U
0.56 J
0.24 U
0.24 U
0.24 U
0.24 U
0.24 U
0.24 U
0.24 U
0.24 U
0.24 U
0.24 U
0.24 U
0.24
NE
600
NE
Trichloroethylene
µg/L
0.38 U
0.38 U
0.38 U
0.38 U
0.38 U
0.38 U
2.4
0.38 U
3.8
1.4
0.57 J
0.90 J
0.38 U
0.38 U
0.38 U
0.38 U
0.38 U
0.38 U
0.38 U
0.38 U
0.38
NE
3
NE
Vinyl Chloride
µg/L
0.39 U
0.39 U
0.39 U
0.39 U
0.39 U
0.39 U
0.39 U
0.39 U
0.58 J
0.39 U
0.39 U
0.39 U
0.39 U
0.39 U
0.39 U
0.39 U
0.39 U
0.39 U
0.39 U
0.39 U
0.39
NE
0.03
NE
X lenes (total)
Ng/L
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
1 108
0.34 U
31.2
Mercury
6.8
Method
0.34 U
EPA 7470A
0.34 U
0.58 J
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
3.9
0.34
NE
500
NE
M"
Mercury Ng/L
Mercury Not Analyzed in July 2024 - See Notes
NE
1
NE
I&I
LTA 1:
Alkalinity (CaCo) Ng/L 52,000 48,000 73,000 24,900 36,000 72,000 110,000 80,000 150,000 130,000
53,000 000 580,000 23,100 9,680 52,000 1700 U 42,000 47,000 100,000 1700 NE NE NE 76,
Chloride
Ng/L
2,700
2,400 1,100 1,200 1,100 1,400 2,200 2,100
1,900 2,800
3,300
1,700 27,000 4,700 1,300 1,500 2,300 3,900 1,400 1,900
15.4 NE
250,000
250,000*
Sulfate
Ng/L
490
500 970 370 670 750 3,700 700
300 15,000
350
990 850,000 760 410 2,100 640 60 J 320 6,200
42.8 NE
250,000
250,000*
1:
Arsenic
µg/L
0.212 J
0.197 J
0.111 U
0.764 J
0.111 U
0.140 J
0.269 J
0.111 U
0.210 J
0.330 J
0.111 U
0.111 U
3.99
0.450 J
0.111 U
0.160 J
0.787 J
0.111 U
0.117 J
0.194 J
0.111
NE
10
10
Cadmium
µg/L
0.032 U
0.032 U
0.032 U
0.032 U
0.039 J
0.032 U
0.032 U
0.131 J
0.032 U
0.032 U
0.032 U
0.032 U
0.032 U
0.032 U
0.032 U
0.032 U
0.032 U
0.032 U
0.032 U
0.032 U
0.032
NE
2
5
Chromium
µg/L
0.257 J
0.293 J
0.856 J
1.46
0.593 J
0.529 J
0.280 J
0.294 J
0.282 J
1.09
0.747 J
1.10
0.225 J
0.372 J
0.711 J
0.877 J
4.12
0.573 J
0.660 J
0.185 U
0.185
NE
10
100
Lead
µg/L
0.059 J
0.037 U
1.83
0.366 J
11.8
0.037 U
0.062 J
0.037 U
0.047 J
0.037 U
0.065 J
0.073 J
0.065 J
0.609 J
0.079 J
0.037 U
3.21
0.150 J
0.242 J
0.010 J
0.037
NE
15
15
Selenium
µg/L
0.193 U
0.193 U
0.193 U
0.193 U
0.193 U
0.193 U
0.193 U
0.193 U
0.193 U
0.193 U
0.193 U
0.193 U
0.217 J
0.193 U
0.193 U
0.193 U
0.193 U
0.193 U
0.193 U
0.193 U
0.193
NE
1 20
50
Silver
I µg/L
1 0.035 U
0.035 U
0.035 U
0.050 J
0.035 U
0.035 U
0.035 U
0.035 U
0.035 U
I 0.035 U
0.035 U
0.035 U
0.035 U
0.035 U
0.035 U
0.035 U
0.035 U
0.035 U
0.035 U
0.035 U
0.035
NE
20
100*
Barium µg/L
229 113 42
16 45
39 88 75
r
17 49 14 15 14
25
14 17
2 J 2 NE 700 2,000
61
17
9
Calcium
µg/L
7,460
8,310
16,700
5,510
6,750
16,200
25,400
12,600
29,800
5,790
8,900
17,400
1,530
1,030
1,840
10,100
964
11,000
9,770
26,500
12
NE
NE
NE
Magnesium
µg/L
3,370
2,860
4,060
1,610
2,910
4,960
6,470
12,200
15,400
1,960
7,410
5,220
11 J
1,140
1,060
2,230
817
1,780
3,630
5,660
8
NE
NE
NE
Potassium
µg/L
1,300
1,220
4,200
414
1,840
11120
4,810
537
822
42,900
244
809
161,000
172
207
1,360
579
360
596
2,510
31
NE
NE
NE
Sodium
µg/L
6,170
6,830
6,800
5,260
3,960
6,520
10,600
1,930
4,720
38,400
2,290
7,130
568,000
3,850
2,600
8,810
1,290
7,170
5,010
8,500
17
NE
NE
NE
Notes:
(1) Samples were collected by Duke Energy Groundwater Sciences Group.
(2) MDL refers to the laboratory Method Detection Limit.
(3) SWS Groundwater Protection Standard (GWPS) refers to the North Carolina Groundwater Protected Standards calculated by North Carolina Department of Environmental
Quality (NCDEQ), Solid Waste Section (SWS) for constituents with no established 15A NCAC 2L Standard (last amended on October 15, 2018).
(4) 15A NCAC 2L Standard refers to Class GA Standards as found in 15A NCAC 02L .0202 Groundwater Quality Standards (last amended on April 1, 2022).
(5) Federal Maximum Contaminant Level (MCL) as found in National Primary Drinking Water Regulations, 40 CFR, Subpart G, §141.62.
(6) * Concentration listed is a secondary MCL (MCL) as found in National Secondary Drinking Water Regulations, 40 CFR, Subpart A, §143.3.
(7) NE = Not Established.
(8) Yellow highlighted cells indicate concentrations equal to or greater than the 15A NCAC 2L Standard (for pH yellow highlighting indicates a measurement outside the 15A
NCAC 2L range).
(9) Bolded values indicate concentrations equal to or greater than the Federal MCL (for pH bolded values indicate a measurement outside of the Federal MCL range).
(10) J = estimated concentrations which are greater than the M DL but are less than the laboratory Method Reporting Limit (MRL).
(11) U = constituent detected at or below the laboratory MDL.
(12) B = analyte detected in associated method blank.
(13) C9 = common laboratory contaminant.
(14) L1 = analyte recovery in the Laboratory Control Sample (LCS) was above QC limits. Detections may be biased high.
(15) v1 = continuing calibration verification was above the method acceptance limit. Detections may be biased high.
(16) Sulfate concentrations at MW-4BR and MW-4BRR were analyzed at dilution.
(17) Chloride concentrations at MW-4, MW-4D, and MW-4BRR were analyzed at dilution.
(18) Potassium concentrations at MW-4BRR were analyzed at dilution.
(19) Sodium concentrations at MW-4BRR were analyzed at dilution.
(20) SU = Standard Units.
(21) µU/cm = micromhos per centimeter.
(22) *C = degrees Celsius.
(23) µg/L = micrograms per liter.
(24) Due to laboratory error, mercury was excluded from the parameter list for July 2024 samples; no analysis performed.
(25) MW-13D and MW-13BR were re -sampled on July 25, 2024, analytical results shown above are for the samples collected on July 25,
2024.

Table 5: Results that Equal or Exceed 15A NCAC 2L Groundwater Standards
Landfill No. 1 (Unlined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station I 1
S&ME Project No: 23350793, Ph.7756
ararne
Lp 1
Field pH
pie :1D
0
SU
SA NCAC 2L
Standard
6.5 - 8.5
Histo
to
is Intratio
Conce tratio
Range
5.88 - 7.00
Cause and Significance
pH in MW-1 is consistent with the historical concentration range at monitoring well.
MW-1
6.04
MW-1 D
6.07
5.90 - 7.00
pH in MW-1 D is consistent with the historical concentration range at monitoring well.
MW-2A
6.13
6.12 - 6.50
pH in MW-2A is consistent with the historical concentration range at monitoring well.
MW-2D
6.35
6.20 - 7.60
pH in MW-2D is consistent with the historical concentration range at monitoring well.
MW-3
5.66
5.70 - 7.50
pH in MW-3 is lower than historical concentration range at monitoring well.
MW-3D
6.09
6.25 - 6.61
pH in MW-3D is lower than historical concentration range at monitoring well.
MW-4
5.36
5.30 - 8.10
pH in MW- 4 is consistent with historical concentration range at monitoring well.
MW-4R
5.90
5.90 - 6.88
pH in MW-4R is consistent with historical concentration range at monitoring well.
MW-41D
5.82
6.01 - 7.10
pH in MW-41D is lower than historical concentration range at monitoring well.
MW-4BR
9.88
8.75 - 10.46
pH in MW-4BR is consistent with historical concentration range at monitoring well.
MW-4BRR
11.57
11.29 - 12.28
pH in MW-4BRR is consistent with historical concentration range at monitoring well.
MW-11
5.77
5.13 - 8.10
pH in MW-11 is consistent with historical concentration range at monitoring well.
MW-11 D
5.59
5.48 - 5.96
pH in MW-11 D is consistent with the historical concentration range at monitoring well.
MW-12
5.05
4.71 - 5.56
pH in MW-12 is consistent with historical concentration range at monitoring well.
MW-12D
6.21
6.00 - 6.41
pH in MW-12D is consistent with the historical concentration range at monitoring well.
Methylene ChlorideRM
W-3BR
17.9 B,C9,L1,v1
fag/L
5
8.80 - 16.9
Methylene Chloride in MW-3BR is higher than historical concentration range at monitoring well.
W-4BR
11.4 B,C9,L1,v1
g/L
4.5-11.4
Methylene Chloride in MW-4BR is consistent with historical concentration range at monitoring well. .
Tetrachloroethylene
MW-3BR
0.79 J
pg/L
0.7
0.40 - 0.69
ITetrachloroethylene in MW-3BR is higher than historical concentration range at monitoring well.
MW-4
0.90 J
pg/L
1 0.88 - 2.50
ITetrachloroethylene in MW-4 is consistent with historical concentration range at monitoring well.
Trichloroethene
MW-4D
3.8
pg/L
3
1 0.58 - 5.88
ITrichloroethene in MW-4D is consistent with historical concentration range at monitoring well.
Sulfate
MW-4BRR
850,000
fag/L
250,000
1 710,000 - 1,400,000
JSulfate in MW-4BRR is consistent with historical concentration range at monitoring well
Vinyl Chloride
MW-4D
0.58 J
p /L
0.03
1 0.45 - 0.90
JVinyl Chloride in MW-4D is consistent with historical concentration range at monitoring well.
Notes:
(1) 15A NCAC 2L Standard refers to Class GA Standards as found in 15A NCAC 02L .0202 Groundwater Quality Standards (last amended on April 1, 2022).
(2) Historical Concentration Range based on data in Duke Energy Carolinas, LLC (Duke Energy) analytical results database.
(3) SU = Standard units.
(4) pg/L = micrograms per liter.
(5) J = estimated concentrations which are greater than the laboratory Method Detection Limit (MDL), but are less than the laboratory Method Reporting Limit (MRL).
(6) B = analyte detected in associated method blank.
(7) C9 = common laboratory contaminant.
(8) L1 = analyte recovery in the Laboratory Control Sample (LCS) was above QC limits. Detections may be biased high.
(9) v1 = continuing calibration verification was above the method acceptance limit. Detections may be biased high.

Table 6: Surface Water Field and Analytical Results
Landfill No. 1 (Unlined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
S&ME Project No: 23350793, Ph.775B
Parameter
Field pH
Units
SU
July 23, 2024
6.70
MDL
- - -
15A NCAC 2B
Standard
6.0 - 9.0
Fe era MCL
6.5 - 8.5*
Specific Conductance
µu/cm
105
- - -
NE
NE
Dissolved Oxygen
mg/L
7.71
- - -
> 4.0
NE
Temperature
I °C
22.54
- - - 32
NE
Volatile Organic Compounds were not detected during the July 2024 Sampling Event
Alkalinity (CaCO3)
I µg/L
48,000
1,700
NE
NE
Chloride
µg/L
2,200
15.4
250,000
250,000*
Sulfate
µg/L
1,500
42.8
250,000
250,000*
qW
Arsenic
Mercury Not Analyzed in July 2024 -
Total Recoverable Metals Method
µg/L 0.319 J
See Notes
SW .0is
0.111
10
10
Arsenic, dissolved
µg/L
0.331 J
0.111
150
10
Chromium
µg/L
0.787 J
0.185
183A
100
Chromium, dissolved
µg/L
0.885 J
0.185
NE
NE
Lead
I µg/L
1 0.365 J
1 0.037
14A
15
Lead, dissolved
Barium
Recoverable
I µg/L
Metals
µg/L
1 0.370 J
MethodTotal
36
SW
1 0.037
.00.
2
0.54A
1,000
15
2,000
Calcium
µg/L
10,700
12
NE
NE
Magnesium
µg/L
4,000
8
NE
NE
Potassium
µg/L
1,440
31
NE
NE
Sodium
µ /L
4,880
17
NE
NE
Notes:
(1) Samples were collected by Duke Energy Groundwater Sciences Group.
(2) MDL refers to the laboratory Method Detection Limit.
(3) 15A NCAC 2B Standard (last amended on September 1, 2022) refers to 15A NCAC 02B 0.0211 Fresh Surface Water Quality
Standards for Class C Waters, and 15A NCAC 02B 0.0216 - Fresh Surface Water Quality Standards for Class WS-IV Waters.
(4) Federal Maximum Contaminant Level (MCL) as found in National Primary Drinking Water Regulations, 40 CFR, Subpart G,
§ 141.62.
(5) * Concentration listed is a secondary MCL (MCL) as found in National Secondary Drinking Water Regulations, 40 CFR, Subpart
A, §143.3.
(6) ^ = Hardness -dependent 15A NCAC 2B Standards derived using equations specified in the 15 NCAC 02B Standards Table
(last amended on July 26, 2021). The values shown rely upon an assumed in -stream default hardness of 25 milligrams per liter
(mg/L) for the chronic standard. An exceedance of the criterion shown does not establish that an in -stream exceedance has
(7) NE = Not Established.
(8) J = estimated concentrations which are greater than the MDL but are less than the laboratory Method Reporting Limit (MRL).
(9) U = constituent detected at or below the laboratory MDL.
(10) SU = Standard Units.
(11) µU/cm = micromhos per centimeter.
(12) °C = degrees Celsius.
(13) µg/L = micrograms per liter.
(14) Due to laboratory error, mercury was excluded from the parameter list for July 2024 samples; no analysis performed.

Table 7: Radiological Analytical Results
Landfill No. 1 (Unlined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
S&ME Project No: 23350793, Ph.775B
= 0r
III
RadiologicalData
Liter (pCi/Q
< 4.51 E-01
< 4.50E-01
MIL
< 4.51 E-01
< 4.40E-01
<
4.4701
=6=A
5.74E-01
< 5.68E-01
=4ALmw-
5.66E-01
< 4.38E-01
July
7.36E-01
22-23, 2024
< 4.40E-01
.•
< 4.40E-01
MW-4BRR
< 5.90E-01
<
MW-11
4.49E-01
MW-11D
1.06E+00
MqW==W-
< 4.50E-01
< 4.50E-01
< 4.50E-01
<
13D
4.50E-01
MW�-
<
1 A3=
4.50E-01
< 4.40E-01
Alpha
Ba-La-140
< 8.09E+00
< 6.55E+00
< 8.68E+00
< 6.94E+00
<
7.24E+00
< 6.17E+00
< 8.26E+00
< 9.56E+00
< 7.91 E+00
<
1.16E+01
< 6.77E+00
< 8.18E+00
< 7.21 E+00
<
9.14E+00
< 9.01 E+00
< 7.47E+00
< 9.21 E+00
< 9.55E+00
<
6.70E+00
<
3.91 E+00
< 8.12E+00
Be-7
< 5.20E+01
< 4.80E+01
< 4.14E+01
< 5.94E+01
<
4.40E+01
< 3.99E+01
< 4.11 E+01
< 3.99E+01
< 3.90E+01
<
5.83E+01
< 4.74E+01
< 5.10E+01
< 4.30E+01
<
4.45E+01
< 4.89E+01
< 4.19E+01
< 5.51 E+01
< 5.82E+01
<
4.13E+01
<
4.51 E+01
< 4.02E+01
Beta
4.34E+00
4.16E+00
6.61E+00
3.39E+00
<
3.19E+00
3.58E+00
7.98E+00
< 3.19E+00
< 3.19E+00
2.73E+01
3.73E+00
3.73E+00
1.09E+02
<
3.07E+00
5.30E+00
3.80E+00
< 3.07E+00
3.73E+00
<
3.07E+00
3.64E+00
< 3.19E+00
Co-58
< 6.41 E+00
< 5.18E+00
< 4.66E+00
< 4.89E+00
<
5.51 E+00
< 5.23E+00
< 7.61 E+00
< 5.43E+00
< 4.53E+00
<
5.90E+00
< 5.56E+00
< 6.12E+00
< 3.81 E+00
<
6.08E+00
< 6.29E+00
< 5.22E+00
< 7.00E+00
< 6.54E+00
<
5.93E+00
<
5.33E+00
< 5.02E+00
Co-60
< 8.37E+00
< 6.15E+00
< 4.94E+00
< 6.02E+00
<
6.06E+00
< 6.16E+00
< 6.66E+00
< 6.51E+00
< 7.31E+00
<
7.29E+00
< 5.94E+00
< 7.53E+00
< 6.86E+00
<
3.03E+00
< 4.63E+00
< 7.72E+00
< 6.99E+00
< 8.00E+00
<
7.02E+00
<
5.68E+00
< 7.16E+00
Cs-134
< 7.97E+00
< 7.74E+00
< 6.17E+00
< 7.32E+00
<
7.42E+00
< 7.41E+00
< 7.84E+00
< 6.28E+00
< 6.62E+00
<
8.55E+00
< 5.54E+00
< 7.06E+00
< 6.59E+00
<
6.39E+00
< 6.61E+00
< 7.90E+00
< 7.49E+00
< 6.85E+00
<
5.54E+00
<
6.98E+00
< 4.78E+00
Cs-137
< 6.45E+00
< 5.97E+00
< 5.56E+00
< 7.30E+00
<
6.45E+00
< 5.81 E+00
< 5.84E+00
< 4.88E+00
< 5.57E+00
<
7.95E+00
< 5.03E+00
< 5.04E+00
< 4.53E+00
<
5.56E+00
< 6.29E+00
< 5.97E+00
< 6.98E+00
< 6.59E+00
<
5.99E+00
<
5.74E+00
< 5.14E+00
Fe-59
< 1.45E+01
< 1.26E+01
< 1.33E+01
< 1.17E+01
<
1.15E+01
< 1.36E+01
< 1.12E+01
< 1.19E+01
< 1.03E+01
<
1.10E+01
< 1.16E+01
< 1.34E+01
< 6.06E+00
<
1.10E+01
< 1.14E+01
< 1.14E+01
< 1.35E+01
< 8.81 E+00
<
1.29E+01
<
1.16E+01
< 1.02E+01
1-131
< 5.95E+00
< 7.26E+00
< 6.12E+00
< 8.19E+00
<
6.45E+00
< 6.54E+00
< 7.95E+00
< 5.96E+00
< 5.74E+00
<
9.36E+00
< 6.29E+00
< 6.39E+00
< 6.88E+00
<
7.21 E+00
< 6.87E+00
< 6.38E+00
< 7.83E+00
< 8.46E+00
<
6.08E+00
<
6.36E+00
< 6.44E+00
K-40
1.32E+02
1.34E+02
1.19E+02
< 1.51 E+02
1.24E+02
< 1.10E+02
2.21 E+02
< 1.26E+02
7.53E+01
2.14E+02
1.12E+02
2.22E+02
2.85E+02
2.01 E+02
1.23E+02
1.03E+02
2.55E+02
1.19E+02
1.72E+02
1.41 E+02
< 1.06E+02
Mn-54
< 7.09E+00
< 7.16E+00
< 4.38E+00
< 6.09E+00
<
6.78E+00
< 5.40E+00
< 5.38E+00
< 5.40E+00
< 5.16E+00
<
7.44E+00
< 6.13E+00
< 6.56E+00
< 6.54E+00
<
5.87E+00
< 4.53E+00
< 5.59E+00
< 6.50E+00
< 6.09E+00
<
7.39E+00
<
4.50E+00
< 6.43E+00
Nb-95
< 6.73E+00
< 5.04E+00
< 6.48E+00
< 6.84E+00
<
7.88E+00
< 5.33E+00
< 5.71 E+00
< 4.49E+00
< 6.30E+00
<
6.99E+00
< 6.45E+00
< 5.96E+00
< 5.34E+00
<
5.23E+00
< 8.00E+00
< 4.71 E+00
< 7.72E+00
< 8.14E+00
<
6.11 E+00
<
5.70E+00
< 5.11 E+00
Tritium (H3GW)
< -2.00E+01
< -2.00E+01
< -4.20E+01
< -1.80E+01
<
-5.00E+01
< 2.50E+00
< 2.00E+01
< 4.76E+01
< -1.00E+01
<
4.95E+01
< -1.20E+02
< -7.50E+00
< -5.40E+01
<
-5.90E+01
< 5.35E+00
< 1.87E+01
< -5.40E+01
< -1.90E+01
<
1.50E+01
<
7.52E+01
< 2.98E+01
Zn-65
< 1.47E+01
< 1.35E+01
< 1.15E+01
< 1.41E+01
<
1.37E+01
< 1.20E+01
< 1.34E+01
< 1.14E+01
< 1.29E+01
<
1.28E+01
< 1.39E+01
< 1.02E+01
< 1.15E+01
<
1.32E+01
< 9.91E+00
< 8.65E+00
< 1.34E+01
< 1.06E+01
<
1.17E+01
I <
1.18E+01
< 9.06E+00
Zr-95
< 1.20E+01
< 8.27E+00
< 1.12E+01
< 1.11 E+01
<
9.20E+00
< 9.77E+00
< 1.19E+01
< 8.36E+00
< 1.03E+01
I <1
1.27E+01
< 1.12E+01
< 1.32E+01
< 9.18E+00
<
9.95E+00
< 9.57E+00
< 1.07E+01
< 1.32E+01
< 1.14E+01
<
1.03E+01
I <1
1.05E+01
< 9.85E+00
Notes•
(1) pCi/L = picocuries per liter
(2) < = less than
(3) Radiological samples collected from MW-13D and MW-13BR were analyzed from initial samples collected on July 23, 2024 (samples for each non -radiological parameter were re -collected on July 25, 2024)

Appendix III - Field Sampling Forms

FIELD SAMPLING CALIBRATION FORM
STUDY:
MCGUIRE NUCLEAR STATION - NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
DATE (s):
July 22-23, 2024
SURFACE UNIT READER: EHS
COLLECTORS: EHS
SURFACE UNIT SERIAL #: 950
ANALYZER MODEL#: ST MP
ANALYZER SERIAL #: 877813
OTHER EQUIPMENT: ruReIDlMereRNo.s-wR-0007o
WEATHER CONDITIONS:
70s-80s,raining/overcast
HYDROLAB PROCEDURE #: 3210.7 VALIDATED BY:
EHS 7/29/24
Calibration Date / Time
DATE: 22-Jul-24
TIME: 7:30
DATE: 23-Jul-24
TIME: 7:45
CALIBRATION BP (mmHg)
743.13
CALIBRATION BP (mmHg)
742.39
Calibation
Instrument
Standard
Instrument
Standard
Parameter
Calibration Results
Calibration Results
Standard
Value
Value
Value
Value
SS
0.0 -►
0.0
INSTRUMENT ZEROED
0.0 -/-►
0.0
INSTRUMENT ZEROED
SPEC. COND.
SS
735.5 -►
720
CALIBRATION ACCEPTED
729.9 -/-►
720
CALIBRATION ACCEPTED
(US/cm)
SS
230.1 -/-►
227
CALIBRATION ACCEPTED
225.7 -/-►
227
1 CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
SS
-/-►
1410
-/-►
1410
CHECK (uS/cm)
SS
B (7.00)
7.08 -►
7.01
CALIBRATION ACCEPTED
7.07 -/-►
7.01
CALIBRATION ACCEPTED
pH
B (4.00)
4.10 -►
4.00
CALIBRATION ACCEPTED
4.06 -/-►
4.00
CALIBRATION ACCEPTED
(units)
B (10.00)
10.09 -/-►
10.03
CALIBRATION ACCEPTED
10.05 -/-►
10.03
CALIBRATION ACCEPTED
Buffer Temp.
22.34
Buffer Temp.
21.83
pH Check
B (7.00)
-►
Buffer Temp.
7.13
0.00
Time:
0
430 -►
436
CALIBRATION ACCEPTED
430 -/-►
436
CALIBRATION ACCEPTED
ORP
N/A -/-►
N/A
N/A -/-►
N/A
Zobell's
ORP Temp.
22.12
ORP Temp.
22.12
0
TEMP(C°)
21.87
21.56
BP (mmHg)
743.13
742.39
COND
0.00
0.00
DO
100 % mg/L
8.61 -►
8.57
CALIBRATION ACCEPTED
8.64 -/-►
8.61
CALIBRATION ACCEPTED
(mg/L)
After Cal
8.60
100.40
After Cal % SAT
8.65
100.48
After Cal % SAT
LCS
8.60
100.40
CALIBRATION PASS
8.65
100.48
CALIBRATION PASS
LCSD
8.60
0.00
CALIBRATION PASS
8.65
0.00
CALIBRATION PASS
0 TURB
(ntu)
SS
10.0 -/-►
10.0
CALIBRATION ACCEPTED
10.1 -/-►
10.0
CALIBRATION ACCEPTED
Temp Cert Device #
TEMP
NISI
N/A -/-►
N/A
Adjustment Not Available
N/A -/-►
N/A
Adjustment Not Available
(deg C)
INSTRUMENT MAINTENANCE
DATE / TIME
Conductance Subsystem
pH Subsystem
❑
Cleaned Electrodes
❑ Cleaned Electrodes
❑
Tested - OK
❑ Replaced ref Electrode KCL
❑
See Notes
❑ Replaced Ref. Electrode
Tip
❑ Tested - OK
❑ See Notes
Oxidation Reduction Subsystem
Temperature Subsystem
❑
Cleaned Electrode
❑ Cleaned Electrode
❑
Tested - OK ❑
See Notes
❑ Tested - OK ❑
See Notes
Dissolved Oxygen Subsystem
❑
Replaced Teflon Membrane
❑ Cleaned Electrode
❑
Replaced DO electrolyte
❑ See Notes
Field Barometric Pressure
Beginning BP
(mmHg)
Ending BP
(mmHg)
KEY:
B = Buffer
LCS = Lab Control Standard -► = Adjusted To
SS = Standard solution
LCSD = Lab Control Standard Duplicate -/-►= Not Adjusted To
N/A = Not Applicable
W = Winkler
BP = Barometric Pressure
AW = Average Winkler
NOTES:

FIELD SAMPLING CALIBRATION FORM
STUDY:
MCGUIRE NUCLEAR STATION - NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
DATE (s):
July 22, 2024
SURFACE UNIT READER: NDR
COLLECTORS: NDR
SURFACE UNIT SERIAL #: 950
ANALYZER MODEL#: ST MP
ANALYZER SERIAL #: 968373
OTHER EQUIPMENT: ruRBIDIMETER No.s-wR-0007o
WEATHER CONDITIONS:
70s-80s, overcast/partly cloudy
HYDROLAB PROCEDURE #: 3210.7 VALIDATED BY:
EHS 7/24/24
Calibration Date / Time
DATE: 22-Jul-24
TIME: 8:53
DATE: 23-Jul-24
TIME: 8:04
CALIBRATION BP (mmHg)
742.00
CALIBRATION BP (mmHg)
743.00
Calibation
Instrument
Standard
Instrument
Standard
Parameter
Calibration Results
Calibration Results
Standard
Value
Value
Value
Value
SS
0.0 -►
0.0
INSTRUMENT ZEROED
0.0 -/-►
0.0
INSTRUMENT ZEROED
SPEC. COND.
SS
691.0 -►
720
CALIBRATION ACCEPTED
735.0 -/-►
720
CALIBRATION ACCEPTED
(US/cm)
SS
1 219.0 -/-►
227
CALIBRATION ACCEPTED
227.0 -/-►
227
1 CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
SS
-/-►
1410
-/-►
1410
CHECK (uS/cm)
SS
B (7.00)
7.00 -►
7.01
CALIBRATION ACCEPTED
7.10 -/-►
7.00
CALIBRATION ACCEPTED
pH
B (4.00)
3.98 -►
4.00
CALIBRATION ACCEPTED
3.99 -/-►
4.00
CALIBRATION ACCEPTED
(units)
B (10.00)
10.05 -/-►
10.03
CALIBRATION ACCEPTED
10.02 -/-►
10.01
CALIBRATION ACCEPTED
Buffer Temp.
22.00
Buffer Temp.
24.00
pH Check
B (7.00)
-►
Buffer Temp.
7.13
0.00
Time:
0
370 -►
434
CALIBRATION ACCEPTED
364 -/-►
429
CALIBRATION ACCEPTED
ORP
N/A -/-►
N/A
N/A -/-►
N/A
Zobell's
ORP Temp.
23.00
ORP Temp.
25.00
0
TEMP(C°)
23.00
25.00
BP (mmHg)
742.00
743.00
COND
0.00
0.00
DO
100 % mg/L
8.30 -►
8.37
CALIBRATION ACCEPTED
7.88 -/-►
8.07
CALIBRATION ACCEPTED
(mg/L)
After Cal
8.33
99.53
After Cal % SAT
7.88
97.61
After Cal % SAT
LCS
8.33
99.53
CALIBRATION PASS
7.88
97.61
CALIBRATION PASS
LCSD
8.33
0.00
CALIBRATION PASS
7.88
0.00
CALIBRATION PASS
0 TURB
(ntu)
SS
5.4 -/-0-5.5
CALIBRATION ACCEPTED
5.3 -/-N.5.5
CALIBRATION ACCEPTED
Temp Cert Device #
TEMP
NISI
N/A -/-►
N/A
Adjustment Not Available
N/A -/-►
N/A
Adjustment Not Available
(deg C)
INSTRUMENT MAINTENANCE
DATE / TIME
Conductance Subsystem
pH Subsystem
❑
Cleaned Electrodes
❑ Cleaned Electrodes
❑
Tested - OK
❑ Replaced ref Electrode KCL
See Notes
El Replaced Ref. Electrode
Tip
❑ Tested - OK
❑ See Notes
Oxidation Reduction Subsystem
Temperature Subsystem
❑
Cleaned Electrode
❑ Cleaned Electrode
❑
Tested - OK ❑
See Notes
❑ Tested - OK ❑
See Notes
Dissolved Oxygen Subsystem
❑
Replaced Teflon Membrane
❑ Cleaned Electrode
❑
Replaced DO electrolyte
❑ See Notes
Field Barometric Pressure
Beginning BP
(mmHg)
Ending BP
(mmHg)
KEY:
B = Buffer
LCS = Lab Control Standard -► = Adjusted To
SS = Standard solution
LCSD = Lab Control Standard Duplicate -/-►= Not Adjusted To
N/A = Not Applicable
W = Winkler
BP = Barometric Pressure
AW = Average Winkler
NOTES:

FIELD SAMPLING CALIBRATION FORM
STUDY:
MCGUIRE NUCLEAR STATION - NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
DATE (s):
July 22-23, 2024
SURFACE UNIT READER: HJS
COLLECTORS: EHS
SURFACE UNIT SERIAL #: 950
ANALYZER MODEL#: ST MP
ANALYZER SERIAL #: 877813
OTHER EQUIPMENT: ruReIDlMereRNo.s-wR-0007o
WEATHER CONDITIONS:
70s-80s,raining/overcast
HYDROLAB PROCEDURE #: 3210.7 VALIDATED BY:
EHS 7/28/24
Calibration Date / Time
DATE: 22-Jul-24
TIME: 815
DATE: 23-Jul-24
TIME: 8:40
CALIBRATION BP (mmHg)
757.00
CALIBRATION BP (mmHg)
746.00
Calibation
Instrument
Standard
Instrument
Standard
Parameter
Calibration Results
Calibration Results
Standard
Value
Value
Value
Value
SS
0.0 -►
0.0
INSTRUMENT ZEROED
0.0 -/-►
0.0
INSTRUMENT ZEROED
SPEC. COND.
SS
1407.0 -►
1410
CALIBRATION ACCEPTED
1412.0 -/-►
1410
CALIBRATION ACCEPTED
(US/cm)
SS
150.0 -/-►
150
1 CALIBRATION ACCEPTED 11
148.0 -/-►
150
1 CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
SS
150.0 -/-►
150
CALIBRATION ACCEPTED
-/-►
1410
CHECK (uS/cm)
SS
B (7.00)
7.02 -►
7.00
CALIBRATION ACCEPTED
7.01 -/-►
7.00
CALIBRATION ACCEPTED
pH
B (4.00)
4.04 -►
4.00
CALIBRATION ACCEPTED
4.01 -/-►
4.00
CALIBRATION ACCEPTED
(units)
B (10.00)
9.99 -/-►
10.00
CALIBRATION ACCEPTED
10.06 -/-►
10.00
CALIBRATION ACCEPTED
Buffer Temp.
25.00
Buffer Temp.
25.00
pH Check
B (7.00)
7.00 -►
Buffer Temp.
7.00
25.00
Calibration Accepted
Time:
0
433 -►
434
CALIBRATION ACCEPTED
433.0 -/-►
434
CALIBRATION ACCEPTED
ORP
N/A -/-►
N/A
N/A -/_►
N/A
Zobell's
ORP Temp.
23.00
ORP Temp.
23.00
0
TEMP(C°)
23.00
26.00
BP (mmHg)
757.00
746.00
COND
0.00
0.00
DO
100 % mg/L
97.90 -►
8.54
CALIBRATION ACCEPTED
7.72 -/-►
7.96
CALIBRATION ACCEPTED
(mg/L)
After Cal
98.80
1156.45
After Cal % SAT
After Cal % SAT
LCS
7.72
97.00
CALIBRATION FAIL
LCSD
7.72
0.00
CALIBRATION PASS
0 TURB
(ntu)
SS
5.5 -/-►
5.7
CALIBRATION ACCEPTED
-/-►
Temp Cert Device #
TEMP
NISI
N/A -/-►
N/A
Adjustment Not Available
N/A -/-►
N/A
Adjustment Not Available
(deg C)
INSTRUMENT MAINTENANCE
DATE / TIME
Conductance Subsystem
pH Subsystem
❑
Cleaned Electrodes
❑ Cleaned Electrodes
❑
Tested - OK
❑ Replaced ref Electrode KCL
❑
See Notes
❑ Replaced Ref. Electrode
Tip
❑ Tested - OK
❑ See Notes
Oxidation Reduction Subsystem
Temperature Subsystem
❑
Cleaned Electrode
❑ Cleaned Electrode
❑
Tested - OK ❑
See Notes
❑ Tested - OK ❑
See Notes
Dissolved Oxygen Subsystem
❑
Replaced Teflon Membrane
❑ Cleaned Electrode
❑
Replaced DO electrolyte
❑ See Notes
Field Barometric Pressure
Beginning BP
(mmHg)
Ending BP
(mmHg)
KEY:
B = Buffer
LCS = Lab Control Standard -► = Adjusted To
SS = Standard solution
LCSD = Lab Control Standard Duplicate -/-►= Not Adjusted To
N/A = Not Applicable
W = Winkler
BP = Barometric Pressure
AW = Average Winkler
NOTES:

FIELD SAMPLING CALIBRATION FORM
STUDY:
MCGUIRE NUCLEAR STATION - NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
DATE (s):
July 22-23, 2024
SURFACE UNIT READER: HJS
COLLECTORS:
EHS
SURFACE UNIT SERIAL #: 950
ANALYZER MODEL#:
ST MP
ANALYZER SERIAL #: 877813
OTHER EQUIPMENT:
ruRBIDIMETER No.s-wR-0007o
WEATHER CONDITIONS:
70s-80s, partly cloudy
HYDROLAB PROCEDURE #: 3210.7 VALIDATED BY:
EHS 7/29/24
Calibration Date / Time
DATE: 23-Jul-24
TIME: 840
DATE: 23-Jul-24
TIME: 3:00
CALIBRATION BP (mmHg)
746.00
CALIBRATION BP (mmHg)
741.00
Calibation
Instrument
Standard
Instrument
Standard
Parameter
Calibration Results
Calibration Results
Standard
Value
Value
Value
Value
SS
0.0 -/-►
0.0
INSTRUMENT ZEROED
0.0 -/-►
0.0
INSTRUMENT ZEROED
SPEC. COND.
SS
1412.0 -►
1410
CALIBRATION ACCEPTED
1405.0 -/-►
1410
CALIBRATION ACCEPTED
(US/cm)
SS
148.0 -/-►
150
1 CALIBRATION ACCEPTED 11
151.0 -/-►
150
1 CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
SS
151.0 -/-►
150
CALIBRATION ACCEPTED
-/-►
1410
CHECK (uS/cm)
SS
B (7.00)
7.01 -►
7.00
CALIBRATION ACCEPTED
6.99 -/-►
7.00
CALIBRATION ACCEPTED
pH
B (4.00)
4.01 -►
4.00
CALIBRATION ACCEPTED
4.04 -/-►
4.00
CALIBRATION ACCEPTED
(units)
B (10.00)
10.06 -/-►
10.00
CALIBRATION ACCEPTED
10.02 -/-►
9.99
CALIBRATION ACCEPTED
Buffer Temp.
25.00
Buffer Temp.
26.00
pH Check
B (7.00)
7.00 -►
Buffer Temp.
7.00
24.00
Calibration Accepted
Time:
0
433 -►
434
CALIBRATION ACCEPTED
428.0 -/-►
427
CALIBRATION ACCEPTED
ORP
N/A -/-►
N/A
N/A -/-►
N/A
Zobell's
ORP Temp.
23.00
ORP Temp.
26.00
0
TEMP(Co)
26.00
26.00
BP (mmHg)
746.00
741.00
COND
0.00
0.00
DO
100 % mg/L
7.72 -►
7.96
CALIBRATION ACCEPTED
7.85 -/-►
7.90
CALIBRATION ACCEPTED
(mg/L)
After Cal
7.72
97.00
After Cal % SAT
7.85
99.32
After Cal % SAT
LCS
7.72
97.00
CALIBRATION FAIL
7.85
99.32
CALIBRATION PASS
LCSD
7.72
0.00
CALIBRATION PASS
7.85
0.00
CALIBRATION PASS
0 TURB
(ntu)
SS
5.5 -/-►
5.7
CALIBRATION ACCEPTED
5.6 -/-►
5.7
CALIBRATION ACCEPTED
Temp Cert Device #
TEMP
NISI
N/A -/-►
N/A
Adjustment Not Available
N/A -/-►
N/A
Adjustment Not Available
(deg C)
INSTRUMENT MAINTENANCE
DATE / TIME
Conductance Subsystem
pH Subsystem
❑
Cleaned Electrodes
❑ Cleaned Electrodes
❑
Tested - OK
❑ Replaced ref Electrode KCL
❑
See Notes
❑ Replaced Ref. Electrode
Tip
❑ Tested - OK
❑ See Notes
Oxidation Reduction Subsystem
Temperature Subsystem
❑
Cleaned Electrode
❑ Cleaned Electrode
❑
Tested - OK
❑
See Notes
❑ Tested - OK ❑
See Notes
Dissolved Oxygen Subsystem
❑
Replaced Teflon Membrane
❑ Cleaned Electrode
❑
Replaced DO electrolyte
❑ See Notes
Field Barometric Pressure
Beginning BP
(mmHg)
Ending BP
(mmHg)
KEY:
B = Buffer
LCS = Lab Control Standard -► = Adjusted To
SS = Standard solution
LCSD = Lab Control Standard Duplicate -/-►= Not Adjusted To
N/A = Not Applicable
W = Winkler
BP = Barometric Pressure
AW = Average Winkler
NOTES:

FIELD SAMPLING CALIBRATION FORM
STUDY:
MCGUIRE NUCLEAR STATION - NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
DATE (s):
July 22-23, 2024
SURFACE UNIT READER: EHS
COLLECTORS: EHS
SURFACE UNIT SERIAL #: 950
ANALYZER MODEL#: ST MP
ANALYZER SERIAL #: 877813
OTHER EQUIPMENT: ruRBIDIMETER No.s-wR-0007o
WEATHER CONDITIONS:
70s-80s, partly cloudy
HYDROLAB PROCEDURE #: 3210.7 VALIDATED BY:
EHS 7/29/24
Calibration Date / Time
DATE: 23-Jul-24
TIME: 7:45
DATE: 23-Jul-24
TIME: 3:15
CALIBRATION BP (mmHg)
742.89
CALIBRATION BP (mmHg)
740.39
Calibation
Instrument
Standard
Instrument
Standard
Parameter
Calibration Results
Calibration Results
Standard
Value
Value
Value
Value
SS
0.0 -/-►
0.0
INSTRUMENT ZEROED
0.0 -/-►
0.0
INSTRUMENT ZEROED
SPEC. COND.
SS
729.9 -►
720
CALIBRATION ACCEPTED
723.5 -/-►
720
CALIBRATION ACCEPTED
(US/cm)
SS
1 225.7 -/-►
227
1 CALIBRATION ACCEPTED 11
231.7 -/-►
227
1 CALIBRATION ACCEPTED
Specific conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
SS
-/-►
1410
-/-►
1410
CHECK (uS/cm)
SS
B (7.00)
7.07 -►
7.01
CALIBRATION ACCEPTED
7.00 -/-►
7.01
CALIBRATION ACCEPTED
pH
B (4.00)
4.06 -►
4.00
CALIBRATION ACCEPTED
4.03 -/-►
4.00
CALIBRATION ACCEPTED
(units)
B (10.00)
10.05 -/-►
10.03
CALIBRATION ACCEPTED
10.05 -/-►
10.02
CALIBRATION ACCEPTED
Buffer Temp.
21.83
Buffer Temp.
22.76
pH Check
B (7.00)
-►
Buffer Temp.
7.13
0.00
Time:
0
430 -►
436
CALIBRATION ACCEPTED
433 -/-►
434
CALIBRATION ACCEPTED
ORP
N/A -/-►
N/A
N/A -/-►
N/A
Zobell's
ORP Temp.
22.12
ORP Temp.
22.99
0
TEMP(Co)
21.56
22.31
BP (mmHg)
742.89
740.39
COND
0.00
0.00
DO
100 % mg/L
8.64 -►
8.61
CALIBRATION ACCEPTED
8.50 -/-►
8.46
CALIBRATION ACCEPTED
(mg/L)
After Cal
8.65
100.41
After Cal % SAT
8.50
100.45
After Cal % SAT
LCS
8.65
100.41
CALIBRATION PASS
8.50
100.45
CALIBRATION PASS
LCSD
8.65
0.00
CALIBRATION PASS
8.50
0.00
CALIBRATION PASS
0 TURB
(ntu)
SS
10.1 -/-►
10.0
CALIBRATION ACCEPTED
10.0 -/-►
10.0
CALIBRATION ACCEPTED
Temp Cert Device #
TEMP
NISI
N/A -/-►
N/A
Adjustment Not Available
N/A -/-►
N/A
Adjustment Not Available
(deg C)
INSTRUMENT MAINTENANCE
DATE / TIME
Conductance Subsystem
pH Subsystem
❑
Cleaned Electrodes
❑ Cleaned Electrodes
❑
Tested - OK
❑ Replaced ref Electrode KCL
❑
See Notes
❑ Replaced Ref. Electrode
Tip
❑ Tested - OK
❑ See Notes
Oxidation Reduction Subsystem
Temperature Subsystem
❑
Cleaned Electrode
❑ Cleaned Electrode
❑
Tested - OK ❑
See Notes
❑ Tested - OK ❑
See Notes
Dissolved Oxygen Subsystem
❑
Replaced Teflon Membrane
❑ Cleaned Electrode
❑
Replaced DO electrolyte
❑ See Notes
Field Barometric Pressure
Beginning BP
(mmHg)
Ending BP
(mmHg)
KEY:
B = Buffer
LCS = Lab Control Standard -► = Adjusted To
SS = Standard solution
LCSD = Lab Control Standard Duplicate -/-►= Not Adjusted To
N/A = Not Applicable
W = Winkler
BP = Barometric Pressure
AW = Average Winkler
NOTES:

FIELD SAMPLING CALIBRATION FORM
STUDY:
MCGUIRE NUCLEAR STATION - NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
DATE (s):
July 25, 2024
SURFACE UNIT READER: EHS
COLLECTORS: EHS
SURFACE UNIT SERIAL #: 950
ANALYZER MODEL#: ST MP
ANALYZER SERIAL #: 877813
OTHER EQUIPMENT: ruReIDlMereRNo.s-wR-0007o
WEATHER CONDITIONS:
raining/overcast-70s
HYDROLAB PROCEDURE #: 3210.7 VALIDATED BY:
EHS 7/25/24
Calibration Date / Time
DATE: 25-Jul-24
TIME: 12:30
DATE: 25-Jul-24
TIME: 2:53
CALIBRATION BP (mmHg)
745.50
CALIBRATION BP (mmHg)
745.37
Calibation
Instrument
Standard
Instrument
Standard
Parameter
Calibration Results
Calibration Results
Standard
Value
Value
Value
Value
SS
0.0 -►
0.0
INSTRUMENT ZEROED
0.0 -/-►
0.0
INSTRUMENT ZEROED
SPEC. COND.
SS
718.9 -►
720
CALIBRATION ACCEPTED
732.1 -/-►
720
CALIBRATION ACCEPTED
(US/cm)
SS
224.4 -/-►
227
CALIBRATION ACCEPTED
230.9 -/-►
227
1 CALIBRATION ACCEPTED
Specific conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
SS
-/-►
1410
-/-►
1410
CHECK (uS/cm)
SS
B (7.00)
6.99 -►
7.02
CALIBRATION ACCEPTED
7.04 -/-►
7.02
CALIBRATION ACCEPTED
pH
B (4.00)
4.00 -►
4.00
CALIBRATION ACCEPTED
4.00 -/-►
4.00
CALIBRATION ACCEPTED
(units)
B (10.00)
10.05 -/-►
10.07
CALIBRATION ACCEPTED
10.07 -/-►
10.06
CALIBRATION ACCEPTED
Buffer Temp.
19.42
Buffer Temp.
19.65
pH Check
B (7.00)
-►
Buffer Temp.
7.13
0.00
Time:
0
446 -►
442
CALIBRATION ACCEPTED
443 -/-►
441
CALIBRATION ACCEPTED
ORP
N/A -/-►
N/A
N/A -/-►
N/A
Zobell's
ORP Temp.
19.45
ORP Temp.
20.00
0
TEMP(C°)
19.36
19.51
BP (mmHg)
745.50
745.37
COND
0.00
0.00
DO
100 % mg/L
9.17 -►
9.03
CALIBRATION ACCEPTED
9.10 -/-►
9.00
CALIBRATION ACCEPTED
(mg/L)
After Cal
9.09
100.67
After Cal % SAT
9.09
100.99
After Cal % SAT
LCS
9.09
100.67
CALIBRATION PASS
9.09
100.99
CALIBRATION PASS
LCSD
9.09
0.00
CALIBRATION PASS
9.09
0.00
CALIBRATION PASS
0 TURB
(ntu)
SS
10.0 -/-►
10.0
CALIBRATION ACCEPTED
10.1 -/-►
10.0
CALIBRATION ACCEPTED
Temp Cert Device #
TEMP
NISI
N/A -/-►
N/A
Adjustment Not Available
N/A -/-►
N/A
Adjustment Not Available
(deg C)
INSTRUMENT MAINTENANCE
DATE / TIME
Conductance Subsystem
pH Subsystem
❑
Cleaned Electrodes
❑ Cleaned Electrodes
Tested - OK
❑ Replaced ref Electrode KCL
See Notes
❑ Replaced Ref. Electrode
Tip
❑ Tested - OK
❑ See Notes
Oxidation Reduction Subsystem
Temperature Subsystem
❑
Cleaned Electrode
❑ Cleaned Electrode
Tested - OK ❑
See Notes
Tested - OK ❑
See Notes
Dissolved Oxygen Subsystem
❑
Replaced Teflon Membrane
❑ Cleaned Electrode
Replaced DO electrolyte
❑ See Notes
Field Barometric Pressure
Beginning BP
(mmHg)
Ending BP
(mmHg)
KEY:
B = Buffer
LCS = Lab Control Standard -► = Adjusted To
SS = Standard solution
LCSD = Lab Control Standard Duplicate -/-►= Not Adjusted To
N/A = Not Applicable
W = Winkler
BP = Barometric Pressure
AW = Average Winkler
NOTES:

'f� DUKE DUKE ENERGY DUKE
� ENERGY GROUNDWATER MONITORING DATA SHEET - ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s)
22-Jul-2024 =❑ 23-Jul-2024 U
WELL/LOCATION NAME
MW-1
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
730.23
729.58
NAVD 88
MIDDLE OF WETTED SCREEN (ft toc)
63.55
WELL DEPTH (ft TOC)
68.55
GS ELEV (ft msl)
PUMP INTAKE DEPTH (ft TOC)
68.05
SCREEN LENGTH (ft)
10
ELEV REF
SCREEN INTERVAL (ft TOC) 58.55 I TO 68.55
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) DISCHARGE (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
30.46
WATER COLUMN (ft) 38.09
WATER ELEVATION (ft msl)
699.77
WELL VOLUME (gal) 6.21
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg Q
o
SPECIFIC
COND.
(umho/cm)
0
pH
(Su)
0
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
9:45
32.75
400
17.47
113
6.06
157.0
245
0.99
N/A
10:02
31.70
300
18.53
113
6.03
7.6
239
0.55
N/A
10:05
31.70
300
18.48
113
6.03
6.7
239
0.52
N/A
10:08
31.70
300
18.49
113
6.04
7.9
238
0.51
N/A
DRAW -DOWN
1.24
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
2.00
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
4.30
(gal)
7/23/2024 @ 1010
0
Sample preservation verified to pH
E
EHS 7/29/24 (units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
EGAMMA ❑✓ H3 BORON [3R 89/90 ❑✓ GROSS ALPH/BETA []Fe 55 ❑Ni 63 [-]IODINE 131 [,104,CL 04LPHA SPEC
dvIETALS EP_ALK ❑CO2 dtSK 175 [Z/OC's ❑FPH-DRO
❑VIETALS a03-N, CL, F, SO4, F_ALK ❑FDS
❑METALS ❑V03-N, CL, SO4 [:]F_ALK ❑LDS/TSS [�)tADIUM 226/228
/ELL PAD
Good Condition
/ELL CAPS
Well cap in good conditon
/ELL CASING
Good Condition
CCESS TO WELLS
Access cleared into well
ROTECTIVE CASING
Casing in good condition
-USH MOUNT WELLS
/ELL TAG
Well tag in good condition
CCESS AROUND WELL
Access cleared around well
/ELL SECURITY
Well found locked
/ELL LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION P
II Impacted By Silting: I NO

'f� DUKE DUKE ENERGY DUKE
ENERGY GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s)
22-Jul-2024 =❑ 23-Jul-2024 U
WELL/LOCATION NAME
MW-1D
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
730.61
729.75
NAVD 88
MIDDLE OF WETTED SCREEN (ft toc)
83.22
WELL DEPTH (ft TOC)
88.22
GS ELEV (ft msl)
PUMP INTAKE DEPTH (ft TOC)
87.72
SCREEN LENGTH (ft)
10
ELEV REF
SCREEN INTERVAL (ft TOC) 78.22 I TO 88.22
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) DISCHARGE (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
31.46
WATER COLUMN (ft) 56.76
WATER ELEVATION (ft msl)
699.15
WELL VOLUME (gal) 9.26
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(degQ
o
SPECIFIC
COND.
(umho/cm)
0
pH
(Su)
0
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
10:38
36.15
400
16.92
103
6.10
9.1
261
0.50
N/A
10:41
1 36.15
400
17.11
105
6.08
5.0
1 258
0.40
N/A
10:44
36.15
400
17.45
105
6.07
5.8
256
0.41
N/A
10:47
36.15
400
17.38
106
6.07
4.7
253
0.42
N/A
DRAW -DOWN
4.69
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
1.50
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
2.50
(gal)
7/23/2024 @ 1050
0
Sample preservation verified to pH
E
EHS 7/29/24 (units) IE70771
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
EGAMMA ❑✓ H3 BORON [3R 89/90 ❑✓ GROSS ALPH/BETA []Fe 55 ❑Ni 63 [-]IODINE 131 [,104,CL 04LPHA SPEC
dvIETALS EP_ALK ❑CO2 dtSK 175 [Z/OC's ❑FPH-DRO
❑VIETALS a03-N, CL, F, SO4, F_ALK ❑FDS
❑METALS ❑V03-N, CL, SO4 [:]F_ALK ❑LDS/TSS [�)tADIUM 226/228
/ELL PAD
Good Condition
/ELL CAPS
Well cap in good conditon
/ELL CASING
Good Condition
CCESS TO WELLS
Access cleared into well
ROTECTIVE CASING
Casing in good condition
-USH MOUNT WELLS
/ELL TAG
Well tag in good condition
CCESS AROUND WELL
Access cleared around well
/ELL SECURITY
Well found locked
/ELL LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION P
II Impacted By Silting: I NO

'f� DUKE DUKE ENERGY DUKE
� ENERGY GROUNDWATER MONITORING DATA SHEET - ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
NDR
SAMPLING DATE(s)
z El
22-Jul-2024
WELL/LOCATION NAME
MW-2A
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
739.67
736.96
NAVD 88
MIDDLE OF WETTED SCREEN (ft toc)
72.57
WELL DEPTH (ft TOC)
77.57
GS ELEV (ft msl)
PUMP INTAKE DEPTH (ft TOC)
77.07
SCREEN LENGTH (ft)
10
ELEV REF
SCREEN INTERVAL (ft TOC) 67.57 TO 77.57
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) I DISCHARGE (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL IFPURGE
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
52.65
=11WATER
COLUMN (ft) 24.92
WATER ELEVATION (ft msl)
687.02
WELL VOLUME (gal) 4.06
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(degQ
o
SPECIFIC
COND.
(umho/cm)
0
pH
(Su)
0
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
10:28
55.90
280
19.00
157
6.14
1.4
354
2.57
N/A
10:31
55.90
280
19.00
157
6.14
1.0
347
2.47
N/A
10:34
55.90
280
19.00
157
6.13
0.9
343
2.38
N/A
DRAW -DOWN
3.25
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
0.45
(gal)
SAMPLE COLLECTED BY
NDR
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
0.90
(gal)
7/22/2024 @ 10:40
0
Sample preservation verified to pH
E
EHS 7/24/24 (units) < 2.0
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
❑� GAMMA ❑✓ H3 []BORON ❑SR 89/90 ❑✓ GROSS ALPH/BETA ❑Fe 55 ❑Ni 63 [-]IODINE 131 ❑✓ SO4,CL ❑ALPHA SPEC
❑� METALS ❑� F_ALK ❑CO2 ❑RSK 175 [Z/OC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
[-]METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting: NO
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
PROTECTIVE CASING Casing in good condition
I MOUNT WELLS
TAG
Well tag in good condition
iS AROUND WELL
Access cleared around well
SECURITY
Well found locked
LOCK CONDITION
Lock in good condition
SAMPLING NOTES

DUKE DUKE ENERGY DUKE
ENERGY GROUNDWATER MONITORING DATA SHEET- ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR EQUIPMENT PURGE ONLY SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
NDR
SAMPLING DATE(s)
22-Jul-2024
WELL/LOCATION NAME
MW-2D
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
740.77
MIDDLE OF WETTED SCREEN (ft toc)
103.82
WELL DEPTH (ft TOC)
108.82
GS ELEV (ft msl)
737.41
PUMP INTAKE DEPTH (ft TOC)
108.32
SCREEN LENGTH (ft)
10
ELEV REF
NAVD 88
SCREEN INTERVAL (ft TOC) 98.82 TO 108.82
EQUIPMENT INFORMATION
Pump Condition
Good
F SAMPLING EQUIPMENT
QED T1200
TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE 1 50 1 (psi) RECHARGE 1 5 (sec) DISCHARGE 10 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
I WELL USE
PURGE METHOD
STICKUP WELL
MONITORING WELL Ell
NUCLEAR LANDFILL
Equip. Only Purge
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ftTOC)
50.05
WATER COLUMN (ft)
58.77
WATER ELEVATION (ft msl)
1 690.72
11WELL
VOLUME (gal)
9.59
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
INITIAL
WATER LEVEL
(ft)
FLOW
RATE
(ml/min)
FINAL
WATER LEVEL
(ft)
0
TEMP
(deg C)
0
SPECIFIC
COND.
(umho/cm)
0
pH
(SU)
0
TURBIDITY
(NTU)
❑
ORP
(mV -NEH)
❑
DISSOLVED
OXYGEN
(mg/L)
❑
50.05
360
61.79
18.00
50
6.35
6.9
280
8.67
N/A
If Evacuated And It Is Requiered To Return To Sample, Enter The Date, Time, And
Water Level To The Right Before Sampling to Determine Recharge.
DATE:
TIME:
WATER LEVEL:
Well Vol.:
Evacuated:
N/A
N/A
Sample:
Tubing Volume
2353
(ml) INITIAL PURGE VOL. EQUIPMENT PURGE ONLY SAMPLE
CHLORINE (mg /I)
Pump (Bladder) Volume
495
(ml) 0.75 SAMPLE COLLECTED BY
(ml) — 0.75 (gal) NDR
DATE TIME
Total Purge Volume
2848
7/22/2024 1 @ 09:55
1 0
QC By: I EHS 7/24/24
Sample preservation verified to pH
(units) IEEE]
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
❑J GAMMA ❑� H3 ❑BORON ❑SR 89/90 ❑� GROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 ❑� SO4,CL ❑ALPHA SPEC
[,]METALS [,IF_ALK ❑CO2 ❑RSK 175 [�]/OC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS
WELL CONDITION
/ELL PAD
Good Condition
/ELL CAPS
Well cap in good conditon
/ELL CASING
Good Condition
CCESS TO WELLS
Access cleared into well
ROTECTIVE CASING
Casing in good condition
I MOUNT WELLS
TAG
Well tag in good condition
iS AROUND WELL
Access cleared around well
SECURITY
Well found locked
LOCK CONDITION
Lock in good condition
❑RADIUM 226/228
SAMPLING NOTES
ADDITIONAL WELL CONDITION NOTES
I Impacted By Silting: I NO

'f� DUDE DUKE ENERGY DUKE
� ENERGY GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s)
22-Jul-2024 =❑ 23-Jul-2024 U
WELL/LOCATION NAME
MW-3
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
728.43
724.98
NAVD 88
MIDDLE OF WETTED SCREEN (ft toc)
68.64
WELL DEPTH (ft TOC)
73.64
GS ELEV (ft msl)
PUMP INTAKE DEPTH (ft TOC)
73.14
SCREEN LENGTH (ft)
10
ELEV REF
SCREEN INTERVAL (ft TOC) 63.64 TO 73.64
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) DISCHARGE (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
66.55
WATER COLUMN (ft) 1 17.09
WATER ELEVATION (ft msl)
671.88
WELL VOLUME (gal) 2.71
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑�
TEMP
(degQ
n
SPECIFIC
COND.
(umho/cm)
n
pH
(Su)
❑�
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
1:04
58.80
300
21.00
64
5.56
18.9
458
5.61
N/A
1:10
1 58.80
300
19.00
66
5.60
1 8.1
460
6.19
N/A
1:15
58.80
300
20.00
66
5.61
5.5
450
6.99
N/A
1:20
58.80
300
22.00
68
5.63
4.0
450
6.92
N/A
1:25
58.80
300
19.00
69
5.66
3.9
451
6.97
N/A
DRAW -DOWN
2.25
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
1.00
(gal)
SAMPLE COLLECTED BY
HJS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
2.70
(gal)
7/22/2024 @ 1325
0
Sample preservation verified to pH
E
EHS 7/25/24 (units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
❑✓ GAMMA 0H3 ❑BORON ❑SR 89/90 ❑✓ GROSS ALPH/BETA ❑Fe 55 ❑Ni 63 [-]IODINE 131 ❑504,CL ❑ALPHA SPEC
❑� METALS ❑� F_ALK ❑CO2 ❑RSK 175 [Z/OC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
[]METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
/ELL PAD
Good Condition
/ELL CAPS
Well cap in good conditon
/ELL CASING
Good Condition
CCESS TO WELLS
Access cleared into well
ROTECTIVE CASING
Casing in good condition
-USH MOUNT WELLS
/ELL TAG
Well tag in good condition
CCESS AROUND WELL
Access cleared around well
/ELL SECURITY
Well found locked
/ELL LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION P
II Impacted By Silting: I NO

'f� DUKE DUKE ENERGY DUKE
ENERGY GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s)
2vJul-2024 =❑ 23-Jul-2024 U
WELL/LOCATION NAME
MW-3D
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
728.39
724.98
NAVD 88
MIDDLE OF WETTED SCREEN (ft toc)
85.19
WELL DEPTH (ft TOC)
90.19
GS ELEV (ft msl)
PUMP INTAKE DEPTH (ft TOC)
89.69
SCREEN LENGTH (ft)
10
ELEV REF
SCREEN INTERVAL (ftj2SL____j 80.19 1 TO 90.19
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) DISCHARGE (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
56.65
WATER COLUMN (ft) 33.54
WATER ELEVATION (ft msl)
671.74
WELL VOLUME (gal) 5.47
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg Q
o
SPECIFIC
COND.
(umho/cm)
0
pH
(Su)
0
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
2:05
58.70
360
18.00
131
6.06
1.8
350
3.78
N/A
2:10
58.70
360
17.00
130
6.04
2.0
349
3.25
N/A
2:15
58.70
360
17.00
130
6.05
1.7
344
3.18
N/A
2:20
58.70
360
17.00
129
6.09
1.4
337
3.18
N/A
DRAW -DOWN
2.05
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
1.00
(gal)
SAMPLE COLLECTED BY
HJS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
2.45
(gal)
7/22/2024 @ 1420
0
Sample preservation verified to pH
E
EHS 7/25/24 (units) IE70771
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
❑✓ GAMMA 0H3 ❑BORON ❑SR 89/90 ❑✓ GROSS ALPH/BETA ❑Fe 55 ❑Ni 63 [-]IODINE 131 ❑504,CL ❑ALPHA SPEC
❑� METALS ❑� F_ALK ❑CO2 ❑RSK 175 [Z/OC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
[]METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
/ELL PAD
Good Condition
/ELL CAPS
Well cap in good conditon
/ELL CASING
Good Condition
CCESS TO WELLS
Access cleared into well
ROTECTIVE CASING
Casing in good condition
-USH MOUNT WELLS
/ELL TAG
Well tag in good condition
CCESS AROUND WELL
Access cleared around well
/ELL SECURITY
Well found locked
/ELL LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION P
II Impacted By Silting: I NO

'f� DUKE
DUKE DUKE ENERGY
ENERGY GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
NDR
SAMPLING DATE(s)
z El
22-Jul-2024
WELL/LOCATION NAME
OW-3BR
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
735.94
732.94
I NAVD 88
MIDDLE OF WETTED SCREEN (ft toc)
131.43
WELL DEPTH (ft TOC)
133.93
GS ELEV (ft msl)
PUMP INTAKE DEPTH (ft TOC)
130.00
SCREEN LENGTH (ft)
5
ELEV REF
SCREEN INTERVAL (ft TOC) 128.93 1 TO 133.93
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1250 TUBING DIAMETER (in) 1/4 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
FD-20240722-1 taken
PRESSURE (psi) RECHARGE (sec) DISCHARGE I #N/A (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
63.29
WATER COLUMN (ft) 70.64
WATER ELEVATION (ft msl)
672.65
WELL VOLUME (gal) 11.52
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg Q
o
SPECIFIC
COND.
(umho/cm)
0
pH
(su)
0
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
12:45
67.75
200
18.00
196
6.72
9.2
92
0.44
N/A
12:48
1 67.75
200
19.00
193
6.71
6.8
101
0.42
N/A
12:51
67.75
200
19.00
191
6.70
4.9
107
0.42
N/A
DRAW -DOWN
4.46
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
2.50
(gal)
SAMPLE COLLECTED BY
NDR
DATE TIME
CHLORINE (mg/I)
TOTAL PURGE VOLUME
2.85
(gal)
7/22/2024 @ 13:00
0
Sample preservation verified to pH
E
EHS 7/24/24 (units) < 2.0
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
❑� GAMMA ❑✓ H3 []BORON ❑SR 89/90 ❑✓ GROSS ALPH/BETA ❑Fe 55 ❑Ni 63 [-]IODINE 131 ❑✓ SO4,CL ❑ALPHA SPEC
OMETALS 0F_ALK ❑CO2 ❑RSK 175 [Z/OC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
[-]METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting: NO
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
PROTECTIVE CASING Casing in good condition
I MOUNT WELLS
TAG
Well tag in good condition
iS AROUND WELL
Access cleared around well
SECURITY
Well found locked
LOCK CONDITION
Lock in good condition
SAMPLING NOTES

DUKE DUKE ENERGY
ENERGY GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR EQUIPMENT PURGE ONLY SAMPLING
DUDE
ENERGY
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s)
22-Jul-2024 23-Jul-2024 p
WELL/LOCATION NAME
MW-4
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
741.13
MIDDLE OF WETTED SCREEN (ft toc)
69.35
WELL DEPTH (ft TOC)
74.15
GS ELEV (ft msl)
738.40
PUMP INTAKE DEPTH (ft TOC)
73.65
SCREEN LENGTH (ft)
10
ELEV REF
NAVD 88
SCREEN INTERVAL (ft TOC) 64.15 TO 74.15
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT
QED T1200
TUBING DIAMETER (in)
1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE 45 1 (psi) RECHARGE 1 45 (sec) DISCHARGE 15 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
I WELL USE
PURGE METHOD
STICKUP WELL
MONITORING WELL �ElNUCLEAR
LANDFILL
Equip. Only Purge
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ftTOC)
64.55
WATER COLUMN (ft)
9.60
WATER ELEVATION (ft msl)
676.58
11WELL
VOLUME (gal)
1.57
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
INITIAL
WATER LEVEL
(ft)
FLOW
RATE
(ml/min)
FINAL
WATER LEVEL
(ft)
0
TEMP
(deg C)
0
SPECIFIC
COND.
(umho/cm)
0
pH
(Su)
0
TURBIDITY
(NTU)
❑
ORP
(mV -NEH)
❑
DISSOLVED
OXYGEN
(mg/L)
❑
64.55
200
70.20
19.00
136
5.36
1.8
383
0.41
N/A
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE:
TIME:
WATER LEVEL:
Well Vol.:
Evacuated:
N/A
N/A
Sampled:
Tubing Volume
1600
(ml) INITIAL PURGE . EQUIPMENT PURGE ONLY SAMPLE
CHLORINE (mg/I)
Pump (Bladder) Volume
495
(MI) 0.55 SAMPLE COLLECTED BY
(ml) — 0.55 l) HJS
�(g-
DATE TIME
Total Purge Volume
2095
1 7/22/2024 @ 1521
1 0
QC By: I EHS 7/25/24
Sample preservation verified to pH
< 2.0
(units)11
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
❑1 GAMMA 71-13 ❑BORON ❑SR 89/90 ❑� GROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 ❑� SO4,CL ❑ALPHA SPEC
[,]METALS ❑F_ALK ❑✓ CO2 ❑RSK 175 [�]/OC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK OTDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION
PAD
Good Condition
CAPS
Well cap in good conditon
CASING
Good Condition
iS TO WELLS
Access cleared into well
=CTIVE CASING
Casing in good condition
I MOUNT WELLS
TAG
Well tag in good condition
iS AROUND WELL
Access cleared around well
SECURITY
Well found locked
LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION NOTES
I Impacted By Silting: I NO

'�� DUKE DUKE ENERGY f4 DUKE
� ENERGY GROUNDWATER MONITORING DATA SHEET ENER{C
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s)
2vJul-2024 =❑ 23-Jul-2024 U
WELL/LOCATION NAME
MW-4D
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
740.58
738.25
NAVD 88
MIDDLE OF WETTED SCREEN (ft toc)
97.24
WELL DEPTH (ft TOC)
102.24
GS ELEV (ft msl)
PUMP INTAKE DEPTH (ft TOC)
101.74
SCREEN LENGTH (ft)
10
ELEV REF
SCREEN INTERVAL (ft TOC) 92.24 I TO 102.24
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE 1 60 (psi) RECHARGE (sec) DISCHARGE (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
64.70
WATER COLUMN (ft) 37.54
WATER ELEVATION (ft msl)
675.88
WELL VOLUME (gal) 6.12
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg Q
o
SPECIFIC
COND.
(umho/cm)
0
pH
(Su)
0
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
3:53
65.90
150
20.00
253
6.67
1.7
376
6.67
N/A
3:56
1 66.70
150
18.00
293
5.83
1 1.5
165
1.07
N/A
3:59
66.70
150
19.00
297
5.81
2.0
161
0.69
N/A
4:02
66.75
150
19.00
297
5.81
0.8
161
0.66
N/A
4:05
66.75
150
19.00
297
5.82
0.6
162
0.62
N/A
DRAW -DOWN
2.05
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
0.01
(gal)
SAMPLE COLLECTED BY
hjs
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
0.50
(gal)
7/22/2024 a@ 4:05
0
Sample preservation verified to pH
E
EHS 7/25/24 (units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
❑✓ GAMMA 0H3 ❑BORON ❑SR 89/90 ❑✓ GROSS ALPH/BETA ❑Fe 55 ❑Ni 63 [-]IODINE 131 ❑504,CL ❑ALPHA SPEC
❑� METALS ❑� F_ALK ❑CO2 ❑RSK 175 [Z/OC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
[]METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
/ELL PAD
Good Condition
/ELL CAPS
Well cap in good conditon
/ELL CASING
Good Condition
CCESS TO WELLS
Access cleared into well
ROTECTIVE CASING
Casing in good condition
-USH MOUNT WELLS
/ELL TAG
Well tag in good condition
CCESS AROUND WELL
Access cleared around well
/ELL SECURITY
Well found locked
/ELL LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION P
II Impacted By Silting: I NO

'f� DUKE DUKE ENERGY DUKE
ENERGY GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
NDR
SAMPLING DATE(s)
El
22-Jul-2024 €
WELL/LOCATION NAME
MW-4BR
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
741.97
739.09
NAVD 88
MIDDLE OF WETTED SCREEN (ft toc)
176.58
WELL DEPTH (ft TOC)
179.08
GS ELEV (ft msl)
PUMP INTAKE DEPTH (ft TOC)
175.00
SCREEN LENGTH (ft)
5
ELEV REF
SCREEN INTERVAL (ft IRSL_____L 174.08 TO 179.08
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1250 TUBING DIAMETER (in) 1/4 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) I DISCHARGE #N/A (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL IFPURGE
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
69.62
WATER COLUMN (ft) 109.46
WATER ELEVATION (ft msl)
672.35
WELL VOLUME (gal) 17.85
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg Q
o
SPECIFIC
COND.
(umho/cm)
0
pH
(Su)
0
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
15:50
71.50
100
26.00
321
9.91
1.6
123
0.77
N/A
15:53
1 71.50
100
26.00
320
9.89
1.9
127
0.75
N/A
15:56
71.50
100
26.00
320
9.88
1.0
129
0.72
N/A
DRAW -DOWN
1.88
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
1.15
(gal)
SAMPLE COLLECTED BY
NDR
DATE TIME
CHLORINE (mg/I)
TOTAL PURGE VOLUME
1.35
(gal)
7/22/2024 @ 16:00
0
Sample preservation verified to pH
E
EHS 7/24/24 (units) < 2.0
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
❑� GAMMA ❑✓ H3 []BORON ❑SR 89/90 ❑✓ GROSS ALPH/BETA ❑Fe 55 ❑Ni 63 [-]IODINE 131 ❑✓ SO4,CL ❑ALPHA SPEC
OMETALS 0F_ALK ❑CO2 ❑RSK 175 [Z/OC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
[-]METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting: NO
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
PROTECTIVE CASING Casing in good condition
I MOUNT WELLS
TAG
Well tag in good condition
iS AROUND WELL
Access cleared around well
SECURITY
Well found locked
LOCK CONDITION
Lock in good condition
SAMPLING NOTES

'f� DUKE DUKE ENERGY f4 DUKE
� ENERGY GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s)
2vJul-2024 23-Jul-2024 U
WELL/LOCATION NAME
MW-4R
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
713.87
711.15
NAVD 88
MIDDLE OF WETTED SCREEN (ft toc)
42.47
WELL DEPTH (ft TOC)
45.73
GS ELEV (ft msl)
PUMP INTAKE DEPTH (ft TOC)
45.23
SCREEN LENGTH (ft)
15
ELEV REF
SCREEN INTERVAL (ft TOC) 30.73 I TO 1 45.73
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) DISCHARGE (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
39.20
WATER COLUMN (ft) 6.53
WATER ELEVATION (ft msl)
674.67
WELL VOLUME (gal) 1.07
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg Q
o
SPECIFIC
COND.
(umho/cm)
0
pH
(Su)
0
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
11:16
40.04
200
19.00
121
6.20
3.0
308
4.94
N/A
11:19
1 40.10
200
19.00
118
6.18
1 2.8
313
5.19
N/A
11:20
40.10
200
19.00
108
6.05
3.3
332
5.92
N/A
11:23
40.10
200
19.00
104
5.97
2.8
343
6.20
N/A
11:26
40.10
200
19.00
106
5.98
2.5
344
6.25
N/A
11:29
40.10
200
19.00
103
5.90
3.2
345
6.27
N/A
DRAW -DOWN
0.90
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
0.01
(gal)
SAMPLE COLLECTED BY
HJS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
0.70
(gal)
7/23/2024 @ 1129
0
Sample preservation verified to pH
E
EHS 7/25/24 (units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
❑✓ GAMMA 0H3 ❑BORON ❑SR 89/90 ❑✓ GROSS ALPH/BETA ❑Fe 55 ❑Ni 63 [-]IODINE 131 ❑504,CL ❑ALPHA SPEC
❑� METALS ❑� F_ALK ❑CO2 ❑RSK 175 [Z/OC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
[]METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
/ELL PAD
Good Condition
/ELL CAPS
Well cap in good conditon
/ELL CASING
Good Condition
CCESS TO WELLS
Access cleared into well
ROTECTIVE CASING
Casing in good condition
-USH MOUNT WELLS
/ELL TAG
Well tag in good condition
CCESS AROUND WELL
Access cleared around well
/ELL SECURITY
Well found locked
/ELL LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION P
II Impacted By Silting: I NO

'�� DUKE DUKE ENERGY f4 DUKE
� ENERGY GROUNDWATER MONITORING DATA SHEET ENER{C
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(5)
2vJul-2024 23-Jul-2024 U
WELL/LOCATION NAME
MW-4DR
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
113.75
711.15
NAVD 88
MIDDLE OF WETTED SCREEN (ft toc)
82.90
WELL DEPTH (ft TOC)
90.40
GS ELEV (ft msl)
PUMP INTAKE DEPTH (ft TOC)
89.90
SCREEN LENGTH (ft)
15
ELEV REF
SCREEN INTERVAL (ft TOC) 75.40 1 TO 90.40
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE 1 60 (psi) RECHARGE (sec) DISCHARGE (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
39.35
WATER COLUMN (ft) 51.05
WATER ELEVATION (ft msl)
674.40
WELL VOLUME (gal) 813:
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg Q
o
SPECIFIC
COND.
(umho/cm)
0
pH
(Su)
0
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
10:30
39.70
200
25.00
133
7.22
0.9
350
2.99
N/A
10:35
1 39.78
200
21.00
141
7.15
1.0
331
2.73
N/A
10:40
39.82
200
21.00
141
7.12
1.4
327
2.61
N/A
10:45
39.82
200
21.00
130
7.10
1.2
325
2.71
N/A
DRAW -DOWN
0.47
(ft)
INITIAL PURGE VOLUME
2.00
(gal)
SAMPLE COLLECTED BY
HJS
I DATE TIME
CHLORINE (mg/I)
TOTAL PURGE VOLUME
2.80
(gal)
7/23/2024 @ 1045
0
Sample preservation verified to pH
E
EHS 7/25/24 (units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
❑✓ GAMMA 0H3 ❑BORON ❑SR 89/90 ❑✓ GROSS ALPH/BETA ❑Fe 55 ❑Ni 63 [-]IODINE 131 ❑504,CL ❑ALPHA SPEC
❑� METALS ❑� F_ALK ❑CO2 ❑RSK 175 [Z/OC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
[]METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
/ELL PAD
Good Condition
/ELL CAPS
Well cap in good conditon
/ELL CASING
Good Condition
CCESS TO WELLS
Access cleared into well
ROTECTIVE CASING
Casing in good condition
-USH MOUNT WELLS
/ELL TAG
Well tag in good condition
CCESS AROUND WELL
Access cleared around well
/ELL SECURITY
Well found locked
/ELL LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION P
II Impacted By Silting: 1 NO

'f� DUKE DUKE ENERGY DUKE
ENERGY GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s)
2vJul-2024 23-Jul-2024 U
WELL/LOCATION NAME
MW-4BRR
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
713.94
710.82
NAVD 88
MIDDLE OF WETTED SCREEN (ft toc)
154.06
WELL DEPTH (ft TOC)
156.56
GS ELEV (ft msl)
PUMP INTAKE DEPTH (ft TOC)
152.00
SCREEN LENGTH (ft)
5
ELEV REF
SCREEN INTERVAL (ft TOC) 151.56 1 TO 156.56
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1250 TUBING DIAMETER (in) 1/40D
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) DISCHARGE I #N/A (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
49.65
WATER COLUMN (ft) 106.91
WATER ELEVATION (ft msl)
664.29
WELL VOLUME (gal) 17.44
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(degQ
o
SPECIFIC
COND.
(umho/cm)
0
pH
(Su)
0
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
9:06
50.01
150
20.00
4303
11.59
0.9
104
2.92
N/A
9:55
50.01
150
20.00
3657
11.57
1.1
119
0.65
N/A
9:58
50.01
150
20.00
3663
11.57
0.8
118
0.73
N/A
10:01
50.01
150
20.00
3663
11.57
1.0
118
0.75
N/A
DRAW -DOWN
0.36
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
0.01
(gal)
SAMPLE COLLECTED BY
HJS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
2.20
(gal)
7/23/2024 @ 1001
0
Sample preservation verified to pH
E
EHS 7/25/24 (units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
❑✓ GAMMA 0H3 ❑BORON ❑SR 89/90 ❑✓ GROSS ALPH/BETA ❑Fe 55 ❑Ni 63 [-]IODINE 131 ❑504,CL ❑ALPHA SPEC
OMETALS 0F_ALK ❑CO2 ❑RSK 175 [Z/OC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
[]METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
/ELL PAD
Good Condition
/ELL CAPS
Well cap in good conditon
/ELL CASING
Good Condition
CCESS TO WELLS
Access cleared into well
ROTECTIVE CASING
Casing in good condition
-USH MOUNT WELLS
/ELL TAG
Well tag in good condition
CCESS AROUND WELL
Access cleared around well
/ELL SECURITY
Well found locked
/ELL LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION P
II Impacted By Silting: I NO
A

'f� DUKE DUKE ENERGY DUKE
� ENERGY GROUNDWATER MONITORING DATA SHEET - ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s)
2vJul-2024 =❑ 23-Jul-2024 U
WELL/LOCATION NAME
MW-11
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
722.60
720.10
NAVD 88
MIDDLE OF WETTED SCREEN (ft toc)
33.96
WELL DEPTH (ft TOC)
38.45
GS ELEV (ft msl)
PUMP INTAKE DEPTH (ft TOC)
37.95
SCREEN LENGTH (ft)
15
ELEV REF
SCREEN INTERVAL (ft TOC) 23.45 TO 38.45
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) DISCHARGE (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
29.46
WATER COLUMN (ft) 8.99
WATER ELEVATION (ft msl)
693.14
WELL VOLUME (gal) 1.47
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(degQ
o
SPECIFIC
COND.
(umho/cm)
0
pH
(Su)
0
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
9:48
34.00
400
15.59
84
5.83
11.3
193
0.29
N/A
9:51
1 34.00
400
15.68
83
5.81
9.6
1 189
0.29
N/A
9:54
34.00
400
15.76
81
5.77
8.7
188
0.32
N/A
DRAW -DOWN
4.54
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
1.00
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
1.65
(gal)
7/22/2024 @ 1000
0
Sample preservation verified to pH
E
EHS 7/29/24 (units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
EGAMMA ❑✓ H3 BORON [3R 89/90 ❑✓ GROSS ALPH/BETA []Fe 55 ❑Ni 63 [-]IODINE 131 [,104,CL 04LPHA SPEC
dvIETALS EP_ALK ❑CO2 dtSK 175 [Z/OC's ❑FPH-DRO
❑VIETALS a03-N, CL, F, SO4, F_ALK ❑FDS
❑METALS ❑V03-N, CL, SO4 [:]F_ALK ❑LDS/TSS [�)tADIUM 226/228
/ELL PAD
Good Condition
/ELL CAPS
Well cap in good conditon
/ELL CASING
Good Condition
CCESS TO WELLS
Access cleared into well
ROTECTIVE CASING
Casing in good condition
-USH MOUNT WELLS
/ELL TAG
Well tag in good condition
CCESS AROUND WELL
Access cleared around well
/ELL SECURITY
Well found locked
/ELL LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION P
II Impacted By Silting: I NO

'f� DUKE
DUKE DUKE ENERGY
ENERGY GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s)
2vJul-2024 =❑ 23-Jul-2024 U
WELL/LOCATION NAME
MW-11D
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
723.14
720.84
NAVD 88
MIDDLE OF WETTED SCREEN (ft toc)
96.55
WELL DEPTH (ft TOC)
101.55
GS ELEV (ft msl)
PUMP INTAKE DEPTH (ft TOC)
101.05
SCREEN LENGTH (ft)
10
ELEV REF
SCREEN INTERVAL (ft TOC) 91.55 I TO 101.55
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) DISCHARGE (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
30.68
WATER COLUMN (ft) 70.87
WATER ELEVATION (ft msl)
692.46
WELL VOLUME (gal) 11.56
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg Q
o
SPECIFIC
COND.
(umho/cm)
0
pH
(Su)
0
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
10:35
35.31
400
15.94
29
5.67
37.7
340
7.32
N/A
11:03
1 34.43
300
16.42
27
5.60
1 90.8
392
7.36
N/A
11:52
32.70
400
16.48
26
5.61
87.8
398
7.30
N/A
12:12
35.15
400
16.19
26
5.59
31.8
412
7.19
N/A
12:15
35.15
400
16.16
26
5.58
19.2
413
7.17
N/A
12:18
35.15
400
16.13
28
5.59
16.3
412
7.15
N/A
12:21
35.15
400
16.12
28
5.58
14.5
414
7.21
N/A
12:24
35.15
400
16.13
27
5.59
11.1
413
7.14
N/A
12:27
35.15
400
16.60
28
5.59
9.6
414
7.15
N/A
DRAW -DOWN
4.47
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
CHLORINE (mg/1)
0
INITIAL PURGE VOLUME
1.00
(gal)
SAMPLE COLLECTED BY
DATE TIME
TOTAL PURGE VOLUME
11.55
(gal)
EHS
7/22/2024 @ 1230
Sample preservation verified to pH
E
EHS 7/29/24 (units) E2.071
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
EGAMMA ❑✓ H3 BORON [3R 89/90 ❑✓ GROSS ALPH/BETA []Fe 55 ❑Ni 63 [-]IODINE 131 [,104,CL 04LPHA SPEC
dvIETALS EP_ALK ❑CO2 dtSK 175 [Z/OC's ❑FPH-DRO
❑VIETALS a03-N, CL, F, SO4, F_ALK ❑FDS
❑METALS ❑V03-N, CL, SO4 [:]F_ALK ❑LDS/TSS [�)tADIUM 226/228
/ELL PAD
Good Condition
/ELL CAPS
Well cap in good conditon
/ELL CASING
Good Condition
CCESS TO WELLS
Access cleared into well
ROTECTIVE CASING
Casing in good condition
-USH MOUNT WELLS
/ELL TAG
Well tag in good condition
CCESS AROUND WELL
Access cleared around well
/ELL SECURITY
Well found locked
/ELL LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION P
II Impacted By Silting: I NO
amp off after 11:20-11:45, due to pump complications

'f� DUKE DUKE ENERGY f4 DUKE
� ENERGY GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s)
2vJul-2024 =❑ 23-Jul-2024 U
WELL/LOCATION NAME
MW-11BR
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
726.66
723.65
I NAVD 88
MIDDLE OF WETTED SCREEN (ft toc)
202.63
WELL DEPTH (ft TOC)
205.13
GS ELEV (ft msl)
PUMP INTAKE DEPTH (ft TOC)
202.00
SCREEN LENGTH (ft)
5
ELEV REF
SCREEN INTERVAL (ft TOC) 200.13 I TO 205.13
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1250 TUBING DIAMETER (in) 1/40D
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) DISCHARGE I #N/A (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
35.49
WATER COLUMN (ft) 169.64
WATER ELEVATION (ft msl)
691.17
WELL VOLUME (gal) 27.67
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg Q
o
SPECIFIC
COND.
(umho/cm)
0
pH
(Su)
0
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
1:13
37.04
320
16.92
118
7.53
6.3
330
3.81
N/A
1:16
1 37.04
320
16.86
115
7.56
1 3.5
332
3.93
N/A
1:19
37.04
320
16.93
113
7.56
2.5
334
4.01
N/A
DRAW -DOWN
1.55
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
3.00
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
3.55
(gal)
7/22/2024 @ 1320
0
Sample preservation verified to pH
E
EHS 7/29/24 (units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
LLOAMMA Di3 ❑30RON [3R89/90 DSR05SALPH/BETA ❑=e55 Ni63 -JODINE131 ✓D04,CL ❑4LPHASPEC
DvIETALS E=_ALK a02 ❑tSK 175 D✓OC's ❑FPH-DRO
❑VIETALS ❑V03-N, CL, F, SO4, F_ALK DDS
❑METALS ❑V03-N, CL, SO4 EJ_ALK ❑fDS/TSS ❑tADIUM 226/228
/ELL PAD
Good Condition
/ELL CAPS
Well cap in good conditon
/ELL CASING
Good Condition
CCESS TO WELLS
Access cleared into well
ROTECTIVE CASING
Casing in good condition
-USH MOUNT WELLS
/ELL TAG
Well tag in good condition
CCESS AROUND WELL
Access cleared around well
/ELL SECURITY
Well found locked
/ELL LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION P
II Impacted By Silting: I NO
A

'f� DUKE DUKE ENERGY DUKE
ENERGY GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s)
711
22-Jul-2024 =❑ 23-Jul-2024 U
WELL/LOCATION NAME
MW-12
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
724.81
722.21
NAVD 88
MIDDLE OF WETTED SCREEN (ft toc)
25.85
WELL DEPTH (ft TOC)
29.49
GS ELEV (ft msl)
PUMP INTAKE DEPTH (ft TOC)
28.99
SCREEN LENGTH (ft)
15
ELEV REF
SCREEN INTERVAL (ft TOC) 14.49 TO 29.49
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) DISCHARGE (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
22.20
WATER COLUMN (ft) 7.29
WATER ELEVATION (ft msl)
702.61
WELL VOLUME (gal) 1.19
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Turbid
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
0
TEMP
(deg Q
0
SPECIFIC
COND.
(umho/cm)
0
pH
(Su)
0
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
1:59
22.80
160
16.66
16
5.46
153.0
431
7.55
N/A
2:48
24.70
150
17.14
16
5.00
1 167.0
471
6.56
N/A
2:51
24.95
150
17.06
16
4.99
170.0
480
6.35
N/A
3:05
25.72
150
17.61
16
5.02
159.0
480
7.79
N/A
3:08
25.71
150
17.83
16
5.05
159.0
473
7.87
N/A
3:11
25.71
150
17.77
17
5.05
172.0
487
7.85
N/A
DRAW -DOWN
3.51
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
0.50
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/I)
TOTAL PURGE VOLUME
3.50
(gal)
7/22/2024 @ 1520
0
Sample preservation verified to pH
E
EHS 7/29/24 (units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
EGAMMA ❑✓ H3 BORON [3R 89/90 ❑✓ GROSS ALPH/BETA []Fe 55 ❑Ni 63 [-]IODINE 131 [,104,CL 04LPHA SPEC
DVIETALS EP_ALK ❑CO2 dtSK 175 [Z/OC's ❑FPH-DRO
❑VIETALS a03-N, CL, F, SO4, F_ALK ❑FDS
❑METALS ❑V03-N, CL, SO4 [:]F_ALK ❑LDS/TSS =tADIUM 226/228
WELL PAD
WELL CAPS
WELL CASING
ACCESS TO WELLS
PROTECTIVE CASING
FLUSH MOUNT WELLS
WELL TAG
ACCESS AROUND WELL
WELL SECURITY
WELL LOCK CONDITION
Good Condition
Well cap in good conditon
Good Condition
Access cleared into well
Casing in good condition
Well tag in good condition
Access cleared around well
Well found locked
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION P
II Impacted By Silting: I NO
at High to
to well not stablizing and going to go

'f� DUKE DUKE ENERGY DUKE
VERY
ENERGY GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s)
2vJul-2024 =❑ 23-Jul-2024 U
WELL/LOCATION NAME
MW-12D
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
724.77
722.21
NAVD 88
MIDDLE OF WETTED SCREEN (ft toc)
63.42
WELL DEPTH (ft TOC)
68.42
GS ELEV (ft msl)
PUMP INTAKE DEPTH (ft TOC)
67.92
SCREEN LENGTH (ft)
10
ELEV REF
SCREEN INTERVAL (ft TOC) 58.42 I TO 68.42
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) DISCHARGE (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
26.95
WATER COLUMN (ft) 41.47
WATER ELEVATION (ft msl)
697.82
WELL VOLUME (gal) 6.76
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg Q
o
SPECIFIC
COND.
(umho/cm)
0
pH
(Su)
0
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
2:13
27.75
210
16.61
92
6.21
11.7
384
6.21
N/A
2:16
27.75
210
16.65
92
6.21
9.9
384
6.15
N/A
2:19
27.75
210
16.57
92
6.21
8.7
384
6.13
N/A
DRAW -DOWN
0.80
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
1.50
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
1.85
(gal)
7/22/2024 @ 1420
0
Sample preservation verified to pH
E
EHS 7/29/24 (units) E70771
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
EGAMMA ❑✓ H3 BORON [3R 89/90 ❑✓ GROSS ALPH/BETA []Fe 55 ❑Ni 63 [-]IODINE 131 [,104,CL 04LPHA SPEC
DVIETALS EP_ALK ❑CO2 dtSK 175 [Z/OC's ❑FPH-DRO
❑VIETALS a03-N, CL, F, SO4, F_ALK ❑FDS
❑METALS ❑V03-N, CL, SO4 [:]F_ALK ❑LDS/TSS [�)tADIUM 226/228
/ELL PAD
Good Condition
/ELL CAPS
Well cap in good conditon
/ELL CASING
Good Condition
CCESS TO WELLS
Access cleared into well
ROTECTIVE CASING
Casing in good condition
-USH MOUNT WELLS
/ELL TAG
Well tag in good condition
CCESS AROUND WELL
Access cleared around well
/ELL SECURITY
Well found locked
/ELL LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION P
II Impacted By Silting: I NO

'f� DUKE DUKE ENERGY
ENERGY GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(5)
22-Jul-2024 =❑ 23-Jul-2024 U
WELL/LOCATION NAME
MW-13D
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
715.36
712.40
NAVD 88
MIDDLE OF WETTED SCREEN (ft toc)
90.00
WELL DEPTH (ft TOC)
95.00
GS ELEV (ft msl)
PUMP INTAKE DEPTH (ft TOC)
90.00
SCREEN LENGTH (ft)
10
ELEV REF
SCREEN INTERVAL (ft TOC) 85.00 1 TO 95.00
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1250 TUBING DIAMETER (in) 1/4 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) DISCHARGE I #N/A (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
43.85
WATER COLUMN (ft) 51.15
WATER ELEVATION (ft msl)
671.51
WELL VOLUME (gal) 8.34
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg C)
o
SPECIFIC
COND.
(umho/cm)
0
pH
(Su)
0
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
12:52
44.98
360
19.35
94
6.63
1.7
306
7.92
N/A
12:55
1 44.98
360
19.42
93
6.62
1.5
307
7.68
N/A
12:58
44.98
360
19.35
93
6.61
1.4
309
7.69
N/A
13:01
44.98
360
19.05
94
6.59
1.2
313
7.72
N/A
DRAW -DOWN
1.13
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
2.00
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
2.90
(gal)
7/23/2024 @ 1305
0
Sample preservation verified to pH
E
EHS 7/29/24 (units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
EGAMMA ❑✓ H3 BORON [3R 89/90 ❑✓ GROSS ALPH/BETA []Fe 55 ❑Ni 63 [-]IODINE 131 [,104,CL 04LPHA SPEC
DVIETALS EP_ALK ❑CO2 dtSK 175 [Z/OC's ❑FPH-DRO
❑VIETALS a03-N, CL, F, SO4, F_ALK ❑FDS
❑METALS ❑V03-N, CL, SO4 [:]F_ALK ❑LDS/TSS [�)tADIUM 226/228
/ELL PAD
Good Condition
/ELL CAPS
Well cap in good conditon
/ELL CASING
Good Condition
CCESS TO WELLS
Access cleared into well
ROTECTIVE CASING
Casing in good condition
-USH MOUNT WELLS
/ELL TAG
Well tag in good condition
CCESS AROUND WELL
Access cleared around well
/ELL SECURITY
Well found locked
/ELL LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION P
II Impacted By Silting: I NO
A

'f� DUKE DUKE ENERGY DUKE
ENERGY GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s)
22-Jul-2024 =❑ 23-Jul-2024 U
WELL/LOCATION NAME
MW-13BR
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
714.40
711.49
I NAVD 88
MIDDLE OF WETTED SCREEN (ft toc)
161.95
WELL DEPTH (ft TOC)
164.45
GS ELEV (ft msl)
PUMP INTAKE DEPTH (ft TOC)
161.00
SCREEN LENGTH (ft)
5
ELEV REF
SCREEN INTERVAL (ft TOC) 159.45 I TO 164.45
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1250 TUBING DIAMETER (in) 1/4OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) DISCHARGE I #N/A (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
52.30
WATER COLUMN (ft) 112.15
WATER ELEVATION (ft msl)
662.10
WELL VOLUME (gal) 18.29
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg Q
o
SPECIFIC
COND.
(umho/cm)
0
pH
(Su)
0
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
12:31
53.65
120
21.28
204
7.19
6.6
200
5.68
N/A
12:34
1 53.65
120
19.73
207
7.22
2.3
138
1.83
N/A
12:37
53.65
120
19.64
206
7.23
2.3
132
1.70
N/A
12:40
53.65
120
19.59
206
7.24
1.8
123
1.66
N/A
DRAW -DOWN
1.35
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
0.20
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
0.50
(gal)
7/23/2024 @ 1245
0
Sample preservation verified to pH
E
EHS 7/29/24 (units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
EGAMMA ❑✓ H3 BORON [3R 89/90 ❑✓ GROSS ALPH/BETA []Fe 55 ❑Ni 63 [-]IODINE 131 [,104,CL 04LPHA SPEC
DVIETALS EP_ALK ❑CO2 dtSK 175 [Z/OC's ❑FPH-DRO
❑VIETALS a03-N, CL, F, SO4, F_ALK ❑FDS
❑METALS ❑V03-N, CL, SO4 [:]F_ALK ❑LDS/TSS =tADIUM 226/228
/ELL PAD
Good Condition
/ELL CAPS
Well cap in good conditon
/ELL CASING
Good Condition
CCESS TO WELLS
Access cleared into well
ROTECTIVE CASING
Casing in good condition
-USH MOUNT WELLS
/ELL TAG
Well tag in good condition
CCESS AROUND WELL
Access cleared around well
/ELL SECURITY
Well found locked
/ELL LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION P
II Impacted By Silting: I NO
A

'f� DUKE DUKE ENERGY DUKE
� ENERGY GROUNDWATER MONITORING DATA SHEET ENER+C
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(5)
El El
25-Jul-2024
WELL/LOCATION NAME
MW-13D
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
715.36
MIDDLE OF WETTED SCREEN (ft toc)
90.00
WELL DEPTH (ft TOC)
95.00
GS ELEV (ft msl)
712.40
PUMP INTAKE DEPTH (ft TOC)
90.00
SCREEN LENGTH (ft)
10
ELEV REF
NAVD 88
SCREEN INTERVAL (ft TOC) 85.00 1 TO 1 95.00
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1250 TUBING DIAMETER (in) 1/4 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) DISCHARGE (sec)
NO PFAS or EN RAD
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
43.95
WATER COLUMN (ft) 51.05
WATER ELEVATION (ft msl)
671.41
WELL VOLUME (gal) 8.33
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(degQ
o
SPECIFIC
COND.
(umho/cm)
o
pH
(su)
n
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
1:52
45.85
400
17.07
83
6.11
2.8
391
7.71
N/A
1:55
1 45.85
400
17.02
83
6.09
1.9
1 394
7.76
N/A
1:58
45.85
400
17.02
83
6.05
1.4
396
7.72
N/A
DRAW -DOWN
1.90
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
2.00
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
2.65
(gal)
7/25/2024 @ 1400
0
Sample preservation verified to pH
E
EHS 7/25/24 (units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
❑✓ GAMMA PH3 []BORON ❑SR 89/90 ❑✓ GROSS ALPH/BETA ❑Fe 55 ❑Ni 63 [_]IODINE 131 ❑504,CL ❑ALPHA SPEC
❑� METALS ❑� F_ALK ❑CO2 ❑RSK 175 [Z/OC's ❑TPH-DRO
[-]METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
/ELL PAD
Good Condition
/ELL CAPS
Well cap in good conditon
/ELL CASING
Good Condition
CCESS TO WELLS
Access cleared into well
ROTECTIVE CASING
Casing in good condition
-USH MOUNT WELLS
/ELL TAG
Well tag in good condition
CCESS AROUND WELL
Access cleared around well
/ELL SECURITY
Well found locked
/ELL LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION P
II Impacted By Silting: 1 NO
A

'f� DUKE DUKE ENERGY ! DUKE
� ENERGY GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s)
El El
25-Jul-2024
WELL/LOCATION NAME
MW-13BR
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
714.40
711.49
I NAVD 88
MIDDLE OF WETTED SCREEN (ft toc)
161.95
WELL DEPTH (ft TOC)
164.45
GS ELEV (ft msl)
PUMP INTAKE DEPTH (ft TOC)
161.00
SCREEN LENGTH (ft)
5
ELEV REF
SCREEN INTERVAL (ft TOC) 159.45 I TO 1 164.45
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1250 TUBING DIAMETER (in) 1/40D
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) DISCHARGE (sec)
NO PFAS or EN RAD
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
50.89
WATER COLUMN (ft) 113.56
WATER ELEVATION (ft msl)
663.S1
WELL VOLUME (gal) 18.52
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg Q
o
SPECIFIC
COND.
(umho/cm)
0
pH
(Su)
0
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
1:39
52.09
120
23.02
187
7.08
1.5
366
5.48
N/A
1:42
1 52.09
120
22.64
188
7.05
1.2
365
5.56
N/A
1:45
52.09
120
22.54
188
7.01
1.1
364
5.47
N/A
DRAW -DOWN
1.20
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
0.25
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
0.45
(gal)
7/25/2024 @ 1350
0
Sample preservation verified to pH
E
EHS 7/25/24 (units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
❑✓ GAMMA PH3 []BORON ❑SR 89/90 ❑✓ GROSS ALPH/BETA ❑Fe 55 ❑Ni 63 [_]IODINE 131 ❑504,CL ❑ALPHA SPEC
❑� METALS ❑� F_ALK ❑CO2 ❑RSK 175 [Z/OC's ❑TPH-DRO
[-]METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
/ELL PAD
Good Condition
/ELL CAPS
Well cap in good conditon
/ELL CASING
Good Condition
CCESS TO WELLS
Access cleared into well
ROTECTIVE CASING
Casing in good condition
-USH MOUNT WELLS
/ELL TAG
Well tag in good condition
CCESS AROUND WELL
Access cleared around well
/ELL SECURITY
Well found locked
/ELL LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION P
II Impacted By Silting: I NO
A

DUKE DUKE ENERGY
ENERGY SURFACE WATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR SURFACE WATER SAMPLING
DUKE
NERD
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s)
22-Jul-2024 23-Jul-2024 L
WELL/LOCATION NAME
SW-1
SURFACE WATER LOCATION
INFORMATION
LOCATION TYPE:
STREAM
WAS WATER PRESENT:
I YES
WAS THERE A NOTICABLE FLOW:
YES
SAMPLING METHOD:
PERISTALTIC PUMP
LOCATION ENVIRONMENT:
I WOODED
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
ELL USE
PURGE METHOD
EEEEE�-
Surface Water Sample
SAMPLING INFORMATION
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
DEPTH OF
INTAKE
(METERS)
TEMP
(deg C)
SPECIFIC
COND.
(umho/cm)
pH
(SU)
TURBIDITY
(NTU)
ORP
(mV-NEH)
DISSOLVED
OXYGEN
(mg/L)
0.01
22.54
105
6.70
35.0
272
7.71
N/A
FLOW
CONDITIONS:
3.00 gallons purge, flowing
JRFACE WATER SAMPLE
CHLORINE (mg/1)
SAMPLE COLLECTED BY
EHS
DATE TIME
7/23/2024 @ 1120
1 0
::011
EHS 7/29/24
Sample preservation verified to pH
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
❑GAMMA 71-13 ❑BORON E:�R 89/90 ❑✓ GROSS ALPH/BETA ❑Fe 55 [—]Ni 63 (IODINE 131 ❑504,CL [-]ALPHA SPEC
[,]METALS ❑i F_ALK ❑CO2 ❑RSK 175 [,IVOC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Well Impacted By Silting: N/A
WELL CAPS
WELL CASING
ACCESS TO WELLS Access cleared into well
PROTECTIVE CASING
FLUSH MOUNT WELLS
WELL TAG
ACCESS AROUND WELL Access cleared around well
WELL SECURITY
WELL LOCK CONDITION
SAMPLING NOTES

NORTH CAROLINA GROUNDWATER SAMPLING SITE CHECK LIST
SITE: MCGUIRE NUCLEAR STATION SAMPLE DATE July 22-23, 2024
PROJECT: NUCLEAR LANDFILL I GROUNDWATER MONITORING PROGRAM FIELD CREW EHS
SITE CONTACT John Ballard
WEATHER 7/22/2024 70s-80s, raining/overcast 7/23/2024 70s-80s, partly cloudy
PAGE 1 OF 1
MW-1
MW-ID
MW-2A
MW-2D
MW-3
MW-3D
MW-4
MW-4D
MW-4R
MW-4DR
MW-11
MW-11D
MW-12
MW-12D
SW-1
ACCESS TO WELLS
Access cleared into well
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
Access cleared around well
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
Tall grass or weeds - needs mowing
Road washing out / muddy / needs grading
Fallen tree blocking access
WELL DEPTH
Well impacted by silting
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
N/A
WELL SECURITY
Well found locked
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
Well found unlocked
WELL LOCK CONDITION
Lock in good condition
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
Lock rusted, difficult to open / needs replacing
Replaced damaged lock
WELL CASINGS
Casing in good condition
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
Damaged casing / still functional
Damaged casing / repair required
CONCRETE PADS
Pad in good condition
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
Minor cracks
Major cracks / broken / repair required
Undermined / washing out
Fire ants around concrete pad
WELL PROTECTIVE CASINGS
pr
Casing in good condition
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
Damaged casing / still functional
Damaged casing / repair required
Broken hinge on protective lid
Wasp nest inside protective casing
Ants inside protective casing
WELL CAPS
Well cap in good conditon
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
Damaged / needs replacement
Replaced damaged well cap
FLUSH MOUNT WELLS
Vault in good condition
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Water inside vault
Vault bolt holes broken or stripped
Bolts stripped
Vault lid cracked or broken
WELL ID TAGS
Well tag in good condition
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
Well tag missing
Well tag damaged / illegible
Lacks required information - Driller Reg ft
Lacks required information - Completion date
Lacks required information -Total well depth
Lacks required information - Depth to screen
Lacks required info - Casing depth / diam.
Lacks required information -Screen interval
Lacks required information - Static WL/date
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Lacks required information - Non potable tag
NOTE:

MCGUIRE NUCLEAR STATION
NUCLEAR
LANDFILL 1 GROUNDWATER
MONITORING PROGRAM
GROUNDWATER MONITORING
FIELD DATA
PERMIT # 60-04
Purge Methods
LF = Low Flow
C = Connventional
EOP = Equip. Only Purge
LO = Level Only
NP = No Pure
LF(M) = Low Flow (Mod.)
Applicable
to LF & LF(M) Purging Only
WELL
DEPTH TO
WATER
PUMP
WELL
EVAC
SPECIFIC
DATE
WELL
DEPTH
WATER
ELEV.
APPEARANCE
ODOR
PURGE RATE
VOL.
VOL.
EVAC
TEMP.
CONDUCTANCE
pH
TURBIDITY
ORP
DO
NO
(ft -TOC)
(g-TOC)
00
METHOD (MI/Min)
(gal)
(gal)
(YES/NO)
(deg.
(umho/cm)
(units)
(NTU's)
(mV-NHE)
(mg/L)
7/23/2024
MW-1
68.55
30.46
699.77
Normal
None
LF 325.00
6.21
4.30
N/A
18.49
113
6.04
7.9
238
0.51
7/23/2024
MW-1D
88.22
31.46
699.15
Normal
None
LF 400.00
9.26
2.50
N/A
17.38
106
6.07
4.7
253
0.42
7/22/2024
MW-2A
77.57
52.65
687.02
Normal
None
LF 280.00
4.06
0.90
N/A
19.00
157
6.13
0.9
343
2.38
7/22/2024
MW-2D
108.82
50.05
690.72
Normal
None
EOP N/A
9.59
0.75
N/A
18.00
50
6.35
6.9
280
8.67
7/22/2024
MW-3
73.64
56.55
671.88
Normal
None
LF 300.00
2.79
2.70
N/A
19.00
69
5.66
3.9
451
6.97
7/22/2024
MW-3D
90.19
56.65
671.74
Normal
None
LF 360.00
5.47
2.45
N/A
17.00
129
6.09
1.4
337
3.18
7/22/2024
MW-4
74.15
64.55
676.58
Normal
None
EOP N/A
1.57
0.55
N/A
19.00
136
5.36
1.8
383
0.41
7/22/2024
MW-4D
102.24
64.70
675.88
Normal
None
LF 150.00
6.12
0.50
N/A
19.00
297
5.82
0.6
162
0.62
7/23/2024
MW-4R
45.73
39.20
674.67
Normal
None
LF 200.00
1.07
0.70
N/A
19.00
103
5.90
3.2
345
6.27
7/23/2024
MW-4DR
90.40
39.35
674.40
Normal
None
LF 200.00
8.33
2.80
N/A
21.00
130
7.10
1.2
325
2.71
7/22/2024
MW-11
38.45
29.46
693.14
Normal
None
LF 400.00
1.47
1.65
N/A
15.76
81
5.77
8.7
188
0.32
7/22/2024
MW-11 D
101.55
30.68
692.46
Normal
None
LF 388.89
11.56
11.55
N/A
16.60
28
5.59
9.6
414
7.15
7/22/2024
MW-12
29.49
22.20
702.61
Turbid
None
LF 151.67
1.19
3.50
N/A
17.77
17
5.05
172.0
487
7.85
7/22/2024
MW-12D
68.42
26.95
697.82
Normal
None
LF 210.00
6.76
1.85
N/A
16.57
92
6.21
8.7
384
6.13
7/23/2024
SW-1
0.00
Normal
None
SWS N/A
N/A
N/A
22.54
105
6.70
35.0
272
7.71
7/22/2024
MW-3BR
133.93
63.29
672.65
Normal
None
LF 200.00
11.52
2.85
N/A
19.00
191
6.70
4.9
107
0.42
7/22/2024
MW-4BR
179.08
69.62
672.35
Normal
None
LF 100.00
17.85
1.35
N/A
26.00
320
9.88
1.0
129
0.72
7/23/2024
MW-4BRR
156.56
49.65
664.29
Normal
None
LF 150.00
17.44
2.20
N/A
20.00
3663
11.57
1.0
118
0.75

Appendix IV - Laboratory Reports and Chain -of -Custody Forms

4 DUE
Analytical Laboratory
ENERGY,
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number:
J24070005
Project Name:
MCGUIRE - GW LF1
Task Code:
LF
Customer Name(s):
A Healy, B Moeller, DOBrien,J Stowe, E Smith
Customer Address:
McGuire Nuclear Station
13225 Hagers Ferry Rd
Mail Code: MG01CH
Huntersville, NC 28078-8985
Lab Contact:
Peggy Kendall Phone: [phone]
Report Authorized By:
&V. 4(.jS,,, Date: 8/19/2024
(Signature)
Peggy endall
Program Comments:
Page 1 of 152
Note: MW-13D and MW-13BR were originally collected 7/23/2024. The job order was pre -logged and sample containers
received after sample collection were already labeled. Samples were checked in and placed in lab storage awaiting analysis.
The sample containers associated with these locations could not be located by the analyst for testing. After investigation, it was
determined the cooler containing these locations was never submitted to the lab. These locations were re -sampled 7/25/2024.
QC Note: Please refer to the vendor lab case narrative for a detailed explanation concerning any qualifiers applied to the data.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions: Page 2 of 152
Sample ID
Plant/Station
Collection
Date and Time
Collected By
Sample Description
2024016757
MCGUIRE
23-Jul-24
10:10 AM
Ethan Smith
MNS MW-1
2024016758
MCGUIRE
23-Jul-24
10:50 AM
Ethan Smith
MNS MW-1 D
2024016759
MCGUIRE
22-Jul-24
10:40 AM
Noah Rubin
MNS MW-2A
2024016760
MCGUIRE
22-Jul-24
9:55 AM
Noah Rubin
MNS MW-2D
2024016761
MCGUIRE
22-Jul-24
1:25 PM
Haley Seaton
MNS_MW-3
2024016762
MCGUIRE
22-Jul-24
2:20 PM
Haley Seaton
MNS_MW-3D
2024016763
MCGUIRE
22-Jul-24
3:21 PM
Haley Seaton
MNS_MW-4
2024016764
MCGUIRE
22-Jul-24
4:05 PM
Haley Seaton
MNS_MW-4D
2024016765
MCGUIRE
22-Jul-24
10:00 AM
Ethan Smith
MNS MW-11
2024016766
MCGUIRE
22-Jul-24
12:30 PM
Ethan Smith
MNS MW-11D
2024016767
MCGUIRE
22-Jul-24
3:20 PM
Ethan Smith
MNS MW-12
2024016768
MCGUIRE
22-Jul-24
2:20 PM
Ethan Smith
MNS MW-12D
2024016769
MCGUIRE
23-Jul-24
11:20 AM
Ethan Smith
MNS SW-1
2024016770
MCGUIRE
23-Jul-24
11:29 AM
Haley Seaton
MNS_MW-4R
2024016771
MCGUIRE
23-Jul-24
10:45 AM
Haley Seaton
MNS_MW-4DR
2024016772
MCGUIRE
22-Jul-24
8:00 AM
Ethan Smith
MNS TB
2024016776
MCGUIRE
22-Jul-24
10:45 AM
Ethan Smith
MNS FB-20240722-1045
2024016777
MCGUIRE
23-Jul-24
10:00 AM
Ethan Smith
MNS FB-20240723-1000
2024016780
MCGUIRE
22-Jul-24
Noah Rubin
MNS FD-20240722-1
2024016781
MCGUIRE
23-Jul-24
Haley Seaton
MNS_FD-20240723-1
2024016782
MCGUIRE
22-Jul-24
1:00 PM
Noah Rubin
MNS MW-3BR
2024016783
MCGUIRE
22-Jul-24
4:00 PM
Noah Rubin
MNS MW-4BR
2024016784
MCGUIRE
23-Jul-24
10:01 AM
Haley Seaton
MNS_MW-4BRR
2024016785
MCGUIRE
22-Jul-24
1:20 PM
Ethan Smith
MNS MW-11BR
2024016786
MCGUIRE
25-Jul-24
2:00 PM
Ethan Smith
MNS MW-13D
2024016794
MCGUIRE
25-Jul-24
1:50 PM
Ethan Smith
MNS MW-13BR
2024019554
MCGUIRE
25-Jul-24
1:00 PM
Ethan Smith
MNS TB-20240725-1300
27 Total Samples

Page 3 of 152
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals❑ Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
❑d Job Summary Report
❑� Sample Identification
❑� Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
❑� Analytical Laboratory QC Report
❑d Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑� Chain of Custody
❑� Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 8/19/2024

Certificate of Laboratory Analysis Page 4 of 152
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS MW-1 Sample #: 2024016757
Collection Date: 07/23/2024 10:10 AM Loc code: MNS MW-1 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
ALKALINITY (FIXED END POINT 4.5) - 024070506
Total Alkalinity as CaCO3 52 mg/L 20 1.7 1 SM 2320B 07/31/2024 08:24 JMVOGEL
(CaCO3)
INORGANIC IONS BY IC - Q24070416
Chloride
2.7
mg/L
0.5
0.0154
5
EPA 9056A
07/25/2024 14:10
BGN9034
Sulfate
0.49
mg/L
0.1
0.0428
1
EPA 9056A
07/25/2024 14:10
BGN9034
TOTAL RECOVERABLE METALS BY ICP - Q24070437
Barium (Ba)
0.229
mg/L
0.005
0.002
1
SW 601OD
07/30/2024 10:29
CELL106
Calcium (Ca)
7.46
mg/L
0.05
0.012
1
SW 601OD
07/30/2024 10:29
CELL106
Magnesium (Mg)
3.37
mg/L
0.02
0.008
1
SW 601OD
07/30/2024 10:29
CELL106
Potassium (K)
1.30
mg/L
0.1
0.031
1
SW 601OD
07/30/2024 10:29
CELL106
Sodium (Na)
6.17
mg/L
0.05
0.017
1
SW 601OD
07/30/2024 10:29
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070445
Arsenic (As)
0.212 J
ug/L
1
0.111
1
SW 6020B
07/29/2024 16:05
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
07/29/2024 16:05
MHALL3
Chromium (Cr)
0.257 J
ug/L
1
0.185
1
SW 6020E
07/29/2024 16:05
MHALL3
Lead (Pb)
0.059 J
ug/L
1
0.037
1
SW 6020E
07/29/2024 16:05
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
07/29/2024 16:05
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020E
07/29/2024 16:05
MHALL3
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS MW-1 D
Collection Date: 07/23/2024 10:50 AM Loc code: MNS MW-1 D
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24070506
Total Alkalinity as CaCO3 48 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24070416
Chloride
2.4
mg/L
0.1
0.0154
1
Sulfate
0.50
mg/L
0.1
0.0428
1
TOTAL RECOVERABLE METALS BY ICP - Q24070437
Barium (Ba)
0.113
mg/L
0.005
0.002
1
Calcium (Ca)
8.31
mg/L
0.05
0.012
1
Magnesium (Mg)
2.86
mg/L
0.02
0.008
1
Potassium (K)
1.22
mg/L
0.1
0.031
1
Sodium (Na)
6.83
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070445
Arsenic (As)
0.197 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.293 J
ug/L
1
0.185
1
Lead (Pb)
0.037 U
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Sample #: 2024016758
Matrix: GW RCRA
Page 5 of 152
Method Analysis Date/Time Analyst
SM 2320B 07/31/2024 08:28 JMVOGEL
EPA 9056A
07/25/2024 11:38
BGN9034
EPA 9056A
07/25/2024 11:38
BGN9034
SW 601OD
07/30/2024 10:42
CELL106
SW 601OD
07/30/2024 10:42
CELL106
SW 601OD
07/30/2024 10:42
CELL106
SW 601OD
07/30/2024 10:42
CELL106
SW 601OD
07/30/2024 10:42
CELL106
SW 6020B
07/29/2024 15:40
MHALL3
SW 6020B
07/29/2024 15:40
MHALL3
SW 6020E
07/29/2024 15:40
MHALL3
SW 6020E
07/29/2024 15:40
MHALL3
SW 6020B
07/29/2024 15:40
MHALL3
SW 6020E
07/29/2024 15:40
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS MW-2A
Collection Date: 07/22/2024 10:40 AM Loc code: MNS MW-2A
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24070506
Total Alkalinity as CaCO3 73 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24070416
Chloride
1.1
mg/L
0.1
0.0154
1
Sulfate
0.97
mg/L
0.1
0.0428
1
TOTAL RECOVERABLE METALS BY ICP - Q24070437
Barium (Ba)
0.042
mg/L
0.005
0.002
1
Calcium (Ca)
16.7
mg/L
0.05
0.012
1
Magnesium (Mg)
4.06
mg/L
0.02
0.008
1
Potassium (K)
4.20
mg/L
0.1
0.031
1
Sodium (Na)
6.80
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070445
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.856 J
ug/L
1
0.185
1
Lead (Pb)
1.83
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Sample #: 2024016759
Matrix: GW RCRA
Page 6 of 152
Method Analysis Date/Time Analyst
SM 2320B 07/31/2024 08:32 JMVOGEL
EPA 9056A
07/25/2024 11:53
BGN9034
EPA 9056A
07/25/2024 11:53
BGN9034
SW 601OD
07/30/2024 10:47
CELL106
SW 601OD
07/30/2024 10:47
CELL106
SW 601OD
07/30/2024 10:47
CELL106
SW 601OD
07/30/2024 10:47
CELL106
SW 601OD
07/30/2024 10:47
CELL106
SW 6020B
07/29/2024 16:13
MHALL3
SW 6020B
07/29/2024 16:13
MHALL3
SW 6020E
07/29/2024 16:13
MHALL3
SW 6020E
07/29/2024 16:13
MHALL3
SW 6020B
07/29/2024 16:13
MHALL3
SW 6020E
07/29/2024 16:13
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS MW-2D
Collection Date: 07/22/2024 09:55 AM Loc code: MNS MW-2D
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q24070435
Total Alkalinity as CaCO3 24.9 mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24070416
Chloride
1.2
mg/L
0.1
0.0154
1
Sulfate
0.37
mg/L
0.1
0.0428
1
TOTAL RECOVERABLE METALS BY ICP - Q24070437
Barium (Ba)
0.016
mg/L
0.005
0.002
1
Calcium (Ca)
5.51
mg/L
0.05
0.012
1
Magnesium (Mg)
1.61
mg/L
0.02
0.008
1
Potassium (K)
0.414
mg/L
0.1
0.031
1
Sodium (Na)
5.26
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070445
Arsenic (As)
0.164 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
1.46
ug/L
1
0.185
1
Lead (Pb)
0.366 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.05 J
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Sample #: 2024016760
Matrix: GW RCRA
Page 7 of 152
Method Analysis Date/Time Analyst
SM 2320134d 07/26/2024 08:31 SNEGLIA
EPA 9056A
07/25/2024 12:09
BGN9034
EPA 9056A
07/25/2024 12:09
BGN9034
SW 601OD
07/30/2024 10:51
CELL106
SW 601OD
07/30/2024 10:51
CELL106
SW 601OD
07/30/2024 10:51
CELL106
SW 601OD
07/30/2024 10:51
CELL106
SW 601OD
07/30/2024 10:51
CELL106
SW 6020B
07/29/2024 16:21
MHALL3
SW 6020B
07/29/2024 16:21
MHALL3
SW 6020E
07/29/2024 16:21
MHALL3
SW 6020E
07/29/2024 16:21
MHALL3
SW 6020B
07/29/2024 16:21
MHALL3
SW 6020E
07/29/2024 16:21
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS MW-3
Collection Date: 07/22/2024 01:25 PM Loc code: MNS MW-3
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24070506
Total Alkalinity as CaCO3 36 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24070416
Chloride
1.1
mg/L
0.1
0.0154
1
Sulfate
0.67
mg/L
0.1
0.0428
1
TOTAL RECOVERABLE METALS BY ICP - Q24070437
Barium (Ba)
0.045
mg/L
0.005
0.002
1
Calcium (Ca)
6.75
mg/L
0.05
0.012
1
Magnesium (Mg)
2.91
mg/L
0.02
0.008
1
Potassium (K)
1.84
mg/L
0.1
0.031
1
Sodium (Na)
3.96
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070445
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Cadmium (Cd)
0.039 J
ug/L
1
0.032
1
Chromium (Cr)
0.593 J
ug/L
1
0.185
1
Lead (Pb)
11.8
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Sample #: 2024016761
Matrix: GW RCRA
Page 8 of 152
Method Analysis Date/Time Analyst
SM 2320B 07/31/2024 08:37 JMVOGEL
EPA 9056A
07/25/2024 12:24
BGN9034
EPA 9056A
07/25/2024 12:24
BGN9034
SW 601OD
07/30/2024 10:55
CELL106
SW 601OD
07/30/2024 10:55
CELL106
SW 601OD
07/30/2024 10:55
CELL106
SW 601OD
07/30/2024 10:55
CELL106
SW 601OD
07/30/2024 10:55
CELL106
SW 6020B
07/29/2024 16:30
MHALL3
SW 6020B
07/29/2024 16:30
MHALL3
SW 6020E
07/29/2024 16:30
MHALL3
SW 6020E
07/29/2024 16:30
MHALL3
SW 6020B
07/29/2024 16:30
MHALL3
SW 6020E
07/29/2024 16:30
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS MW-3D
Collection Date: 07/22/2024 02:20 PM Loc code: MNS MW-3D
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24070506
Total Alkalinity as CaCO3 72 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24070416
Chloride
1.4
mg/L
0.1
0.0154
1
Sulfate
0.75
mg/L
0.1
0.0428
1
TOTAL RECOVERABLE METALS BY ICP - Q24070437
Barium (Ba)
0.039
mg/L
0.005
0.002
1
Calcium (Ca)
16.2
mg/L
0.05
0.012
1
Magnesium (Mg)
4.96
mg/L
0.02
0.008
1
Potassium (K)
1.12
mg/L
0.1
0.031
1
Sodium (Na)
6.52
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070445
Arsenic (As)
0.14 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.529 J
ug/L
1
0.185
1
Lead (Pb)
0.037 U
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Sample #: 2024016762
Matrix: GW RCRA
Page 9 of 152
Method Analysis Date/Time Analyst
SM 2320B 07/31/2024 08:41 JMVOGEL
EPA 9056A
07/25/2024 12:39
BGN9034
EPA 9056A
07/25/2024 12:39
BGN9034
SW 601OD
07/30/2024 10:59
CELL106
SW 601OD
07/30/2024 10:59
CELL106
SW 601OD
07/30/2024 10:59
CELL106
SW 601OD
07/30/2024 10:59
CELL106
SW 601OD
07/30/2024 10:59
CELL106
SW 6020B
07/29/2024 16:38
MHALL3
SW 6020B
07/29/2024 16:38
MHALL3
SW 6020E
07/29/2024 16:38
MHALL3
SW 6020E
07/29/2024 16:38
MHALL3
SW 6020B
07/29/2024 16:38
MHALL3
SW 6020E
07/29/2024 16:38
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 10 of 152
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS MW-4 Sample #: 2024016763
Collection Date: 07/22/2024 03:21 PM Loc code: MNS MW-4 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
ALKALINITY (FIXED END POINT 4.5) - 024070506
Total Alkalinity as CaCO3 80 mg/L 20 1.7 1 SM 2320B 07/31/2024 08:45 JMVOGEL
(CaCO3)
INORGANIC IONS BY IC - Q24070416
Chloride
2.1
mg/L
0.5
0.0154
5
EPA 9056A
07/25/2024 14:55
BGN9034
Sulfate
0.70
mg/L
0.1
0.0428
1
EPA 9056A
07/25/2024 14:55
BGN9034
TOTAL RECOVERABLE METALS BY ICP - Q24070437
Barium (Ba)
0.075
mg/L
0.005
0.002
1
SW 601OD
07/30/2024 11:04
CELL106
Calcium (Ca)
12.6
mg/L
0.05
0.012
1
SW 601OD
07/30/2024 11:04
CELL106
Magnesium (Mg)
12.2
mg/L
0.02
0.008
1
SW 601OD
07/30/2024 11:04
CELL106
Potassium (K)
0.537
mg/L
0.1
0.031
1
SW 601OD
07/30/2024 11:04
CELL106
Sodium (Na)
1.93
mg/L
0.05
0.017
1
SW 601OD
07/30/2024 11:04
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070445
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
07/29/2024 16:47
MHALL3
Cadmium (Cd)
0.131 J
ug/L
1
0.032
1
SW 6020B
07/29/2024 16:47
MHALL3
Chromium (Cr)
0.294 J
ug/L
1
0.185
1
SW 6020E
07/29/2024 16:47
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020E
07/29/2024 16:47
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
07/29/2024 16:47
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020E
07/29/2024 16:47
MHALL3
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS MW-4D
Collection Date: 07/22/2024 04:05 PM Loc code: MNS MW-4D
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24070506
Total Alkalinity as CaCO3 150 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24070416
Chloride
1.9
mg/L
0.5
0.0154
5
Sulfate
0.30
mg/L
0.1
0.0428
1
TOTAL RECOVERABLE METALS BY ICP - Q24070437
Barium (Ba)
0.061
mg/L
0.005
0.002
1
Calcium (Ca)
29.8
mg/L
0.05
0.012
1
Magnesium (Mg)
15.4
mg/L
0.02
0.008
1
Potassium (K)
0.822
mg/L
0.1
0.031
1
Sodium (Na)
4.72
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070445
Arsenic (As)
0.21 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.282 J
ug/L
1
0.185
1
Lead (Pb)
0.047 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 11 of 152
Sample #: 2024016764
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320B 07/31/2024 08:49 JMVOGEL
EPA 9056A
07/25/2024 13:55
BGN9034
EPA 9056A
07/25/2024 13:55
BGN9034
SW 601OD
07/30/2024 11:08
CELL106
SW 601OD
07/30/2024 11:08
CELL106
SW 601OD
07/30/2024 11:08
CELL106
SW 601OD
07/30/2024 11:08
CELL106
SW 601OD
07/30/2024 11:08
CELL106
SW 6020B
07/29/2024 17:20
MHALL3
SW 6020B
07/29/2024 17:20
MHALL3
SW 6020E
07/29/2024 17:20
MHALL3
SW 6020E
07/29/2024 17:20
MHALL3
SW 6020B
07/29/2024 17:20
MHALL3
SW 6020E
07/29/2024 17:20
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS MW-11
Collection Date: 07/22/2024 10:00 AM Loc code: MNS MW-11
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q24070435
Total Alkalinity as CaCO3 23.1 mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24070416
Chloride
4.7
mg/L
0.5
0.0154
5
Sulfate
0.76
mg/L
0.1
0.0428
1
TOTAL RECOVERABLE METALS BY ICP - Q24070437
Barium (Ba)
0.014
mg/L
0.005
0.002
1
Calcium (Ca)
1.03
mg/L
0.05
0.012
1
Magnesium (Mg)
1.14
mg/L
0.02
0.008
1
Potassium (K)
0.172
mg/L
0.1
0.031
1
Sodium (Na)
3.85
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070445
Arsenic (As)
0.45 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.372 J
ug/L
1
0.185
1
Lead (Pb)
0.609 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 12 of 152
Sample #: 2024016765
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320134d 07/26/2024 08:38 SNEGLIA
EPA 9056A
07/29/2024 11:32
BGN9034
EPA 9056A
07/29/2024 11:32
BGN9034
SW 601OD
07/30/2024 11:12
CELL106
SW 601OD
07/30/2024 11:12
CELL106
SW 601OD
07/30/2024 11:12
CELL106
SW 601OD
07/30/2024 11:12
CELL106
SW 601OD
07/30/2024 11:12
CELL106
SW 6020B
07/29/2024 17:28
MHALL3
SW 6020B
07/29/2024 17:28
MHALL3
SW 6020E
07/29/2024 17:28
MHALL3
SW 6020E
07/29/2024 17:28
MHALL3
SW 6020B
07/29/2024 17:28
MHALL3
SW 6020E
07/29/2024 17:28
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS MW-11 D
Collection Date: 07/22/2024 12:30 PM Loc code: MNS MW-11 D
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q24070435
Total Alkalinity as CaCO3 9.68 mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24070416
Chloride
1.3
mg/L
0.1
0.0154
1
Sulfate
0.41
mg/L
0.1
0.0428
1
TOTAL RECOVERABLE METALS BY ICP - Q24070437
Barium (Ba)
0.015
mg/L
0.005
0.002
1
Calcium (Ca)
1.84
mg/L
0.05
0.012
1
Magnesium (Mg)
1.06
mg/L
0.02
0.008
1
Potassium (K)
0.207
mg/L
0.1
0.031
1
Sodium (Na)
2.60
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070445
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.711 J
ug/L
1
0.185
1
Lead (Pb)
0.079 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 13 of 152
Sample #: 2024016766
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320134d 07/26/2024 08:45 SNEGLIA
EPA 9056A
07/25/2024 16:25
BGN9034
EPA 9056A
07/25/2024 16:25
BGN9034
SW 601OD
07/30/2024 11:16
CELL106
SW 601OD
07/30/2024 11:16
CELL106
SW 601OD
07/30/2024 11:16
CELL106
SW 601OD
07/30/2024 11:16
CELL106
SW 601OD
07/30/2024 11:16
CELL106
SW 6020B
07/29/2024 17:37
MHALL3
SW 6020B
07/29/2024 17:37
MHALL3
SW 6020E
07/29/2024 17:37
MHALL3
SW 6020E
07/29/2024 17:37
MHALL3
SW 6020B
07/29/2024 17:37
MHALL3
SW 6020E
07/29/2024 17:37
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS MW-12
Collection Date: 07/22/2024 03:20 PM Loc code: MNS MW-12
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q24070435
Total Alkalinity as CaCO3 1.7 U mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24070416
Chloride
2.3
mg/L
0.1
0.0154
1
Sulfate
0.64
mg/L
0.1
0.0428
1
TOTAL RECOVERABLE METALS BY ICP - Q24070437
Barium (Ba)
0.025
mg/L
0.005
0.002
1
Calcium (Ca)
0.964
mg/L
0.05
0.012
1
Magnesium (Mg)
0.817
mg/L
0.02
0.008
1
Potassium (K)
0.579
mg/L
0.1
0.031
1
Sodium (Na)
1.29
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070445
Arsenic (As)
0.787 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
4.12
ug/L
1
0.185
1
Lead (Pb)
3.21
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 14 of 152
Sample #: 2024016767
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320134d 07/26/2024 08:52 SNEGLIA
EPA 9056A
07/25/2024 16:40
BGN9034
EPA 9056A
07/25/2024 16:40
BGN9034
SW 601OD
07/30/2024 11:28
CELL106
SW 601OD
07/30/2024 11:28
CELL106
SW 601OD
07/30/2024 11:28
CELL106
SW 601OD
07/30/2024 11:28
CELL106
SW 601OD
07/30/2024 11:28
CELL106
SW 6020B
07/29/2024 17:45
MHALL3
SW 6020B
07/29/2024 17:45
MHALL3
SW 6020E
07/29/2024 17:45
MHALL3
SW 6020E
07/29/2024 17:45
MHALL3
SW 6020B
07/29/2024 17:45
MHALL3
SW 6020E
07/29/2024 17:45
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS MW-12D
Collection Date: 07/22/2024 02:20 PM Loc code: MNS MW-12D
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24070506
Total Alkalinity as CaCO3 42 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24070416
Chloride
3.9
mg/L
0.1
0.0154
1
Sulfate
0.06 J
mg/L
0.1
0.0428
1
TOTAL RECOVERABLE METALS BY ICP - Q24070437
Barium (Ba)
0.014
mg/L
0.005
0.002
1
Calcium (Ca)
11.0
mg/L
0.05
0.012
1
Magnesium (Mg)
1.78
mg/L
0.02
0.008
1
Potassium (K)
0.360
mg/L
0.1
0.031
1
Sodium (Na)
7.17
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070445
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.573 J
ug/L
1
0.185
1
Lead (Pb)
0.15 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 15 of 152
Sample #: 2024016768
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320B 07/31/2024 08:54 JMVOGEL
EPA 9056A
07/25/2024 16:55
BGN9034
EPA 9056A
07/25/2024 16:55
BGN9034
SW 601OD
07/30/2024 11:32
CELL106
SW 601OD
07/30/2024 11:32
CELL106
SW 601OD
07/30/2024 11:32
CELL106
SW 601OD
07/30/2024 11:32
CELL106
SW 601OD
07/30/2024 11:32
CELL106
SW 6020B
07/29/2024 17:54
MHALL3
SW 6020B
07/29/2024 17:54
MHALL3
SW 6020E
07/29/2024 17:54
MHALL3
SW 6020E
07/29/2024 17:54
MHALL3
SW 6020B
07/29/2024 17:54
MHALL3
SW 6020E
07/29/2024 17:54
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS SW-1
Collection Date: 07/23/2024 11:20 AM Loc code: MNS SW-1
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24070506
Total Alkalinity as CaCO3 48 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24070416
Chloride
2.2
mg/L
0.1
0.0154
1
Sulfate
1.5
mg/L
0.1
0.0428
1
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED) - Q24070485
Barium (Ba)
0.035
mg/L
0.005
0.002
1
TOTAL RECOVERABLE METALS BY ICP - Q24070437
Barium (Ba)
0.036
mg/L
0.005
0.002
1
Calcium (Ca)
10.7
mg/L
0.05
0.012
1
Magnesium (Mg)
4.00
mg/L
0.02
0.008
1
Potassium (K)
1.44
mg/L
0.1
0.031
1
Sodium (Na)
4.88
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) -
Q24070487
Arsenic (As)
0.331 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.885 J
ug/L
1
0.185
1
Lead (Pb)
0.37 J
ug/L
1
0.037
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070445
Arsenic (As)
0.319 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.787 J
ug/L
1
0.185
1
Lead (Pb)
0.365 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 16 of 152
Sample #: 2024016769
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320B 07/31/2024 08:58 JMVOGEL
EPA 9056A
07/25/2024 17:10
BGN9034
EPA 9056A
07/25/2024 17:10
BGN9034
SW 601OD
07/31/2024 13:29
CELL106
SW 601OD
07/30/2024 11:36
CELL106
SW 601OD
07/30/2024 11:36
CELL106
SW 601OD
07/30/2024 11:36
CELL106
SW 601OD
07/30/2024 11:36
CELL106
SW 601OD
07/30/2024 11:36
CELL106
SW 6020B
07/31/2024 16:04
MHALL3
SW 6020B
07/31/2024 16:04
MHALL3
SW 6020E
07/31/2024 16:04
MHALL3
SW 6020B
07/31/2024 16:04
MHALL3
SW 6020E
07/31/2024 16:04
MHALL3
SW 6020B
07/29/2024 18:02
MHALL3
SW 6020B
07/29/2024 18:02
MHALL3
SW 6020B
07/29/2024 18:02
MHALL3
SW 6020E
07/29/2024 18:02
MHALL3
SW 6020B
07/29/2024 18:02
MHALL3
SW 6020B
07/29/2024 18:02
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 17 of 152
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS MW-4R Sample #: 2024016770
Collection Date: 07/23/2024 11:29 AM Loc code: MNS MW-4R Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
ALKALINITY (FIXED END POINT 4.5) - Q24070506
Total Alkalinity as CaCO3 53 mg/L 20 1.7 1 SM 2320B 07/31/2024 09:03 JMVOGEL
(CaCO3)
INORGANIC IONS BY IC - Q24070416
Chloride
3.3
mg/L
0.1
0.0154
1
EPA 9056A
07/25/2024 17:26
BGN9034
Sulfate
0.35
mg/L
0.1
0.0428
1
EPA 9056A
07/25/2024 17:26
BGN9034
TOTAL RECOVERABLE METALS BY ICP - Q24070462
Barium (Ba)
0.009
mg/L
0.005
0.002
1
SW 601OD
07/30/2024 14:25
CELL106
Calcium (Ca)
8.90
mg/L
0.05
0.012
1
SW 601OD
07/30/2024 14:25
CELL106
Magnesium (Mg)
7.41
mg/L
0.02
0.008
1
SW 601OD
07/30/2024 14:25
CELL106
Potassium (K)
0.244
mg/L
0.1
0.031
1
SW 601OD
07/30/2024 14:25
CELL106
Sodium (Na)
2.29
mg/L
0.05
0.017
1
SW 601OD
07/30/2024 14:25
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070464
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
07/30/2024 14:59
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
07/30/2024 14:59
MHALL3
Chromium (Cr)
0.747 J
ug/L
1
0.185
1
SW 6020E
07/30/2024 14:59
MHALL3
Lead (Pb)
0.065 J
ug/L
1
0.037
1
SW 6020E
07/30/2024 14:59
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
07/30/2024 14:59
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020E
07/30/2024 14:59
MHALL3
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS MW-4DR
Collection Date: 07/23/2024 10:45 AM Loc code: MNS MW-4DR
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24070506
Total Alkalinity as CaCO3 76 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24070416
Chloride
1.7
mg/L
0.1
0.0154
1
Sulfate
0.99
mg/L
0.1
0.0428
1
TOTAL RECOVERABLE METALS BY ICP - Q24070462
Barium (Ba)
0.017
mg/L
0.005
0.002
1
Calcium (Ca)
17.4
mg/L
0.05
0.012
1
Magnesium (Mg)
5.22
mg/L
0.02
0.008
1
Potassium (K)
0.809
mg/L
0.1
0.031
1
Sodium (Na)
7.13
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070464
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
1.10
ug/L
1
0.185
1
Lead (Pb)
0.073 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 18 of 152
Sample #: 2024016771
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320B 07/31/2024 09:07 JMVOGEL
EPA 9056A
07/25/2024 17:41
BGN9034
EPA 9056A
07/25/2024 17:41
BGN9034
SW 601OD
07/30/2024 14:37
CELL106
SW 601OD
07/30/2024 14:37
CELL106
SW 601OD
07/30/2024 14:37
CELL106
SW 601OD
07/30/2024 14:37
CELL106
SW 601OD
07/30/2024 14:37
CELL106
SW 6020B
07/30/2024 14:33
MHALL3
SW 6020B
07/30/2024 14:33
MHALL3
SW 6020E
07/30/2024 14:33
MHALL3
SW 6020E
07/30/2024 14:33
MHALL3
SW 6020B
07/30/2024 14:33
MHALL3
SW 6020E
07/30/2024 14:33
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS TB
Collection Date: 07/22/2024 08:00 AM Loc code: MNS TB
Analyte Result Units Qualifiers RDL MDL DF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 19 of 152
Sample #: 2024016772
Matrix: GW RCRA
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis Page 20 of 152
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS FB-20240722-1045 Field Blank Sample #: 2024016776
Collection Date: 07/22/2024 10:45 AM Loc code: MNS QA Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
LOW LEVEL ALKALINITY (FIXED END POINT) - Q24070435
Total Alkalinity as CaCO3 1.7 U mg/L 5 1.7 1 SM 2320134d 07/26/2024 08:58 SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24070416
Chloride
0.04 J
mg/L
0.1
0.0154
1
EPA 9056A
07/25/2024 17:56
BGN9034
Sulfate
0.0428 U
mg/L
0.1
0.0428
1
EPA 9056A
07/25/2024 17:56
BGN9034
TOTAL RECOVERABLE METALS BY ICP - Q24070462
Barium (Ba)
0.002 U
mg/L
0.005
0.002
1
SW 601 OD
07/30/2024 14:42
CELLI06
Calcium (Ca)
0.025 J
mg/L
0.05
0.012
1
SW 601 OD
07/30/2024 14:42
CELLI06
Magnesium (Mg)
0.008 U
mg/L
0.02
0.008
1
SW 601 OD
07/30/2024 14:42
CELLI06
Potassium (K)
0.031 U
mg/L
0.1
0.031
1
SW 601 OD
07/30/2024 14:42
CELLI06
Sodium (Na)
0.017 U
mg/L
0.05
0.017
1
SW 601 OD
07/30/2024 14:42
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070464
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
07/30/2024 15:08
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
07/30/2024 15:08
MHALL3
Chromium (Cr)
0.229 J
ug/L
1
0.185
1
SW 6020E
07/30/2024 15:08
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020E
07/30/2024 15:08
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
07/30/2024 15:08
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020E
07/30/2024 15:08
MHALL3
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 21 of 152
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS FB-20240723-1000 Field Blank Sample #: 2024016777
Collection Date: 07/23/2024 10:00 AM Loc code: MNS QA Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
LOW LEVEL ALKALINITY (FIXED END POINT) - Q24070435
Total Alkalinity as CaCO3 1.7 U mg/L 5 1.7 1 SM 2320134d 07/26/2024 09:03 SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24070416
Chloride
0.04 J
mg/L
0.1
0.0154
1
EPA 9056A
07/25/2024 18:11
BGN9034
Sulfate
0.0428 U
mg/L
0.1
0.0428
1
EPA 9056A
07/25/2024 18:11
BGN9034
TOTAL RECOVERABLE METALS BY ICP - Q24070462
Barium (Ba)
0.002 U
mg/L
0.005
0.002
1
SW 601 OD
07/30/2024 14:46
CELLI06
Calcium (Ca)
0.046 J
mg/L
0.05
0.012
1
SW 601 OD
07/30/2024 14:46
CELLI06
Magnesium (Mg)
0.008 U
mg/L
0.02
0.008
1
SW 601 OD
07/30/2024 14:46
CELLI06
Potassium (K)
0.031 U
mg/L
0.1
0.031
1
SW 601 OD
07/30/2024 14:46
CELLI06
Sodium (Na)
0.017 U
mg/L
0.05
0.017
1
SW 601 OD
07/30/2024 14:46
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070464
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
07/30/2024 15:16
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
07/30/2024 15:16
MHALL3
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
SW 6020E
07/30/2024 15:16
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020E
07/30/2024 15:16
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
07/30/2024 15:16
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020E
07/30/2024 15:16
MHALL3
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 22 of 152
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS_FD-20240722-1 Duplicate Sample #: 2024016780
Collection Date: 07/22/2024 Loc code: MNS FD Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
LOW LEVEL ALKALINITY (FIXED END POINT) - Q24070435
Total Alkalinity as CaCO3 106 mg/L 5 1.7 1 SM 2320134d 07/26/2024 09:09 SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24070416
Chloride
2.0
mg/L
0.1
0.0154
1
EPA 9056A
07/25/2024 13:24
BGN9034
Sulfate
3.6
mg/L
0.1
0.0428
1
EPA 9056A
07/25/2024 13:24
BGN9034
TOTAL RECOVERABLE METALS BY ICP - Q24070462
Barium (Ba)
0.090
mg/L
0.005
0.002
1
SW 601 OD
07/31/2024 08:03
CELLI06
Calcium (Ca)
25.6
mg/L
0.05
0.012
1
SW 601 OD
07/31/2024 08:03
CELLI06
Magnesium (Mg)
6.65
mg/L
0.02
0.008
1
SW 601 OD
07/31/2024 08:03
CELLI06
Potassium (K)
4.54
mg/L
0.1
0.031
1
SW 601 OD
07/31/2024 08:03
CELLI06
Sodium (Na)
10.7
mg/L
0.05
0.017
1
SW 601 OD
07/31/2024 08:03
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070464
Arsenic (As)
0.262 J
ug/L
1
0.111
1
SW 6020B
07/30/2024 15:24
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
07/30/2024 15:24
MHALL3
Chromium (Cr)
0.242 J
ug/L
1
0.185
1
SW 6020E
07/30/2024 15:24
MHALL3
Lead (Pb)
0.063 J
ug/L
1
0.037
1
SW 6020E
07/30/2024 15:24
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
07/30/2024 15:24
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020E
07/30/2024 15:24
MHALL3
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 23 of 152
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS_FD-20240723-1
Duplicate
Sample #:
2024016781
Collection Date: 07/23/2024
Loc code: MNS FD
Matrix:
GW RCRA
Analyte Result Units Qualifiers RDL MDL
DF Method
Analysis Date/Time Analyst
ALKALINITY (FIXED END POINT 4.5)
- Q24070506
Total Alkalinity as CaCO3
76 mg/L 20 1.7
1 SM 2320B
07/31/2024 09:11 JMVOGEL
(CaCO3)
INORGANIC IONS BY IC - Q24070416
Chloride
1.8
mg/L
0.1
0.0154
1
EPA 9056A
07/25/2024 13:40
BGN9034
Sulfate
1.00
mg/L
0.1
0.0428
1
EPA 9056A
07/25/2024 13:40
BGN9034
TOTAL RECOVERABLE METALS BY ICP - Q24070462
Barium (Ba)
0.018
mg/L
0.005
0.002
1
SW 601OD
07/30/2024 14:54
CELL106
Calcium (Ca)
17.5
mg/L
0.05
0.012
1
SW 601OD
07/30/2024 14:54
CELL106
Magnesium (Mg)
5.27
mg/L
0.02
0.008
1
SW 601OD
07/30/2024 14:54
CELL106
Potassium (K)
0.808
mg/L
0.1
0.031
1
SW 601OD
07/30/2024 14:54
CELL106
Sodium (Na)
7.12
mg/L
0.05
0.017
1
SW 601OD
07/30/2024 14:54
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070464
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
07/30/2024 15:33
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
07/30/2024 15:33
MHALL3
Chromium (Cr)
1.10
ug/L
1
0.185
1
SW 6020E
07/30/2024 15:33
MHALL3
Lead (Pb)
0.103 J
ug/L
1
0.037
1
SW 6020E
07/30/2024 15:33
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
07/30/2024 15:33
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020E
07/30/2024 15:33
MHALL3
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS MW-3BR
Collection Date: 07/22/2024 01:00 PM Loc code: MNS MW-3BR
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24070506
Total Alkalinity as CaCO3 110 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24070416
Chloride
2.2
mg/L
0.1
0.0154
1
Sulfate
3.7
mg/L
0.1
0.0428
1
TOTAL RECOVERABLE METALS BY ICP - Q24070462
Barium (Ba)
0.088
mg/L
0.005
0.002
1
Calcium (Ca)
25.4
mg/L
0.05
0.012
1
Magnesium (Mg)
6.47
mg/L
0.02
0.008
1
Potassium (K)
4.81
mg/L
0.1
0.031
1
Sodium (Na)
10.6
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070464
Arsenic (As)
0.269 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.28 J
ug/L
1
0.185
1
Lead (Pb)
0.062 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 24 of 152
Sample #: 2024016782
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320B 07/31/2024 09:16 JMVOGEL
EPA 9056A
07/25/2024 18:26
BGN9034
EPA 9056A
07/25/2024 18:26
BGN9034
SW 601OD
07/30/2024 15:06
CELL106
SW 601OD
07/30/2024 15:06
CELL106
SW 601OD
07/30/2024 15:06
CELL106
SW 601OD
07/30/2024 15:06
CELL106
SW 601OD
07/30/2024 15:06
CELL106
SW 6020B
07/30/2024 15:41
MHALL3
SW 6020B
07/30/2024 15:41
MHALL3
SW 6020E
07/30/2024 15:41
MHALL3
SW 6020E
07/30/2024 15:41
MHALL3
SW 6020B
07/30/2024 15:41
MHALL3
SW 6020E
07/30/2024 15:41
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS MW-4BR
Collection Date: 07/22/2024 04:00 PM Loc code: MNS MW-4BR
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24070506
Total Alkalinity as CaCO3 130 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24070416
Chloride
2.8
mg/L
0.1
0.0154
1
Sulfate
15
mg/L
0.5
0.0428
5
TOTAL RECOVERABLE METALS BY ICP - Q24070462
Barium (Ba)
0.017
mg/L
0.005
0.002
1
Calcium (Ca)
5.79
mg/L
0.05
0.012
1
Magnesium (Mg)
1.96
mg/L
0.02
0.008
1
Potassium (K)
42.9
mg/L
1
0.031
10
Sodium (Na)
38.4
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070464
Arsenic (As)
0.33 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
1.09
ug/L
1
0.185
1
Lead (Pb)
0.037 U
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 25 of 152
Sample #: 2024016783
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320B 07/31/2024 09:20 JMVOGEL
EPA 9056A
07/25/2024 20:41
BGN9034
EPA 9056A
07/25/2024 20:41
BGN9034
SW 601OD
07/30/2024 15:10
CELL106
SW 601OD
07/30/2024 15:10
CELL106
SW 601OD
07/30/2024 15:10
CELL106
SW 601OD
07/30/2024 15:10
CELL106
SW 601OD
07/30/2024 15:10
CELL106
SW 6020B
07/30/2024 15:49
MHALL3
SW 6020B
07/30/2024 15:49
MHALL3
SW 6020E
07/30/2024 15:49
MHALL3
SW 6020E
07/30/2024 15:49
MHALL3
SW 6020B
07/30/2024 15:49
MHALL3
SW 6020E
07/30/2024 15:49
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS MW-4BRR
Collection Date: 07/23/2024 10:01 AM Loc code: MNS MW-4BRR
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24070506
Total Alkalinity as CaCO3 580 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24070416
Chloride
27
mg/L
2
0.0154
20
Sulfate
850
mg/L
20
0.0428
200
TOTAL RECOVERABLE METALS BY ICP - Q24070462
Barium (Ba)
0.049
mg/L
0.005
0.002
1
Calcium (Ca)
1.53
mg/L
0.05
0.012
1
Magnesium (Mg)
0.011 J
mg/L
0.02
0.008
1
Potassium (K)
161
mg/L
1
0.031
10
Sodium (Na)
568
mg/L
0.5
0.017
10
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070464
Arsenic (As)
3.99
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.225 J
ug/L
1
0.185
1
Lead (Pb)
0.065 J
ug/L
1
0.037
1
Selenium (Se)
0.217 J
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 26 of 152
Sample #: 2024016784
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320B 07/31/2024 09:25 JMVOGEL
EPA 9056A
07/25/2024 21:27
BGN9034
EPA 9056A
07/25/2024 21:27
BGN9034
SW 601OD
07/30/2024 15:15
CELL106
SW 601OD
07/30/2024 15:15
CELL106
SW 601OD
07/30/2024 15:15
CELL106
SW 601OD
07/30/2024 15:15
CELL106
SW 601OD
07/30/2024 15:15
CELL106
SW 6020B
07/30/2024 15:58
MHALL3
SW 6020B
07/30/2024 15:58
MHALL3
SW 6020E
07/30/2024 15:58
MHALL3
SW 6020E
07/30/2024 15:58
MHALL3
SW 6020B
07/30/2024 15:58
MHALL3
SW 6020E
07/30/2024 15:58
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS MW-11 BR
Collection Date: 07/22/2024 01:20 PM Loc code: MNS MW-11 BR
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24070506
Total Alkalinity as CaCO3 52 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24070416
Chloride
1.5
mg/L
0.1
0.0154
1
Sulfate
2.1
mg/L
0.1
0.0428
1
TOTAL RECOVERABLE METALS BY ICP - Q24070462
Barium (Ba)
0.014
mg/L
0.005
0.002
1
Calcium (Ca)
10.1
mg/L
0.05
0.012
1
Magnesium (Mg)
2.23
mg/L
0.02
0.008
1
Potassium (K)
1.36
mg/L
0.1
0.031
1
Sodium (Na)
8.81
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070464
Arsenic (As)
0.16 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.877 J
ug/L
1
0.185
1
Lead (Pb)
0.037 U
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 27 of 152
Sample #: 2024016785
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320B 07/31/2024 09:31 JMVOGEL
EPA 9056A
07/25/2024 20:26
BGN9034
EPA 9056A
07/25/2024 20:26
BGN9034
SW 601OD
07/30/2024 15:19
CELL106
SW 601OD
07/30/2024 15:19
CELL106
SW 601OD
07/30/2024 15:19
CELL106
SW 601OD
07/30/2024 15:19
CELL106
SW 601OD
07/30/2024 15:19
CELL106
SW 6020B
07/30/2024 16:06
MHALL3
SW 6020B
07/30/2024 16:06
MHALL3
SW 6020E
07/30/2024 16:06
MHALL3
SW 6020E
07/30/2024 16:06
MHALL3
SW 6020B
07/30/2024 16:06
MHALL3
SW 6020E
07/30/2024 16:06
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS MW-13D
Collection Date: 07/25/2024 02:00 PM Loc code: MNS MW-13D
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24070506
Total Alkalinity as CaCO3 47 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24070483
Chloride
1.4
mg/L
0.1
0.0154
1
Sulfate
0.32
mg/L
0.1
0.0428
1
TOTAL RECOVERABLE METALS BY ICP - Q24070462
Barium (Ba)
0.017
mg/L
0.005
0.002
1
Calcium (Ca)
9.77
mg/L
0.05
0.012
1
Magnesium (Mg)
3.63
mg/L
0.02
0.008
1
Potassium (K)
0.596
mg/L
0.1
0.031
1
Sodium (Na)
5.01
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070464
Arsenic (As)
0.117 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.66 J
ug/L
1
0.185
1
Lead (Pb)
0.242 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 28 of 152
Sample #: 2024016786
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320B 07/31/2024 10:12 JMVOGEL
EPA 9056A
07/30/2024 15:42
BGN9034
EPA 9056A
07/30/2024 15:42
BGN9034
SW 601OD
07/30/2024 15:23
CELL106
SW 601OD
07/30/2024 15:23
CELL106
SW 601OD
07/30/2024 15:23
CELL106
SW 601OD
07/30/2024 15:23
CELL106
SW 601OD
07/30/2024 15:23
CELL106
SW 6020B
07/30/2024 16:40
MHALL3
SW 6020B
07/30/2024 16:40
MHALL3
SW 6020E
07/30/2024 16:40
MHALL3
SW 6020E
07/30/2024 16:40
MHALL3
SW 6020B
07/30/2024 16:40
MHALL3
SW 6020E
07/30/2024 16:40
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS MW-13BR
Collection Date: 07/25/2024 01:50 PM Loc code: MNS MW-13BR
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24070506
Total Alkalinity as CaCO3 100 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24070483
Chloride
1.9
mg/L
0.1
0.0154
1
Sulfate
6.2
mg/L
0.1
0.0428
1
TOTAL RECOVERABLE METALS BY ICP - Q24070462
Barium (Ba)
0.002 J
mg/L
0.005
0.002
1
Calcium (Ca)
26.5
mg/L
0.05
0.012
1
Magnesium (Mg)
5.66
mg/L
0.02
0.008
1
Potassium (K)
2.51
mg/L
0.1
0.031
1
Sodium (Na)
8.50
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24070464
Arsenic (As)
0.194 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
Lead (Pb)
0.1 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 29 of 152
Sample #: 2024016794
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320B 07/31/2024 10:17 JMVOGEL
EPA 9056A
07/30/2024 15:57
BGN9034
EPA 9056A
07/30/2024 15:57
BGN9034
SW 601 OD
07/31/2024 08:05
CELL106
SW 601 OD
07/31/2024 08:05
CELL106
SW 601 OD
07/31/2024 08:05
CELL106
SW 601 OD
07/31/2024 08:05
CELL106
SW 601 OD
07/31/2024 08:05
CELL106
SW 6020B
07/30/2024 16:48
MHALL3
SW 6020B
07/30/2024 16:48
MHALL3
SW 6020E
07/30/2024 16:48
MHALL3
SW 6020E
07/30/2024 16:48
MHALL3
SW 6020B
07/30/2024 16:48
MHALL3
SW 6020E
07/30/2024 16:48
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24070005
Site: MNS_TB-20240725-1300 Trip Blank
Collection Date: 07/25/2024 01:00 PM Loc code: MNS TB
Analyte Result Units Qualifiers RDL MDL DF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 30 of 152
Sample #: 2024019554
Matrix: GW RCRA
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an estimate.

Certificate of Laboratory Analysis Page 31 of 152
This report shall not be reproduced, except in full.
Order # J24070005
Level II QC Summary
Q24070506 ALK FIX4.5 ALKALINITY (FIXED END POINT 4.5)
Duplicate # 1
Parameter Measured Final
Total Alkalinity as CaCO3 50.8
LCS # 1
Parameter Measured Final
Total Alkalinity as CaCO3 106
Parent Sample: J24070005 -- 2024016757
Units Dil MDL RPD
mg/L 1 1.7 1.52
(CaCO3)
Units Dil MDL Spike % Recovery LCL UCL
mg/L 1 1.7 104 102 85 115
(CaCO3)
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 32 of 152
This report shall not be reproduced, except in full.
Order # J24070005
Level II QC Summary
Q24070435 ALK LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Duplicate # 1
Parent Sample: J24070005 -- 2024016780
Parameter Measured
Final
Units
Dil
MDL RPD Qualifier
Total Alkalinity as CaCO3
109
mg/L
1
1.7 2.84
LCS # 1
Parameter Measured
Final
Units
Dil
MDL Spike % Recovery LCL UCL Qualifier
Total Alkalinity as CaCO3
99.3
mg/L
1
1.7 104 95.5 85 115
(CaCO3)

Certificate of Laboratory Analysis Page 33 of 152
This report shall not be reproduced, except in full.
Order # J24070005
Level II QC Summary
Q24070416 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Sulfate
0.001
0.001
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S Ike
% Recovery
LCL UCL
Qualifier
Chloride
5.07
5.07
mg/L
1
0.0154
5
101
80 120
Sulfate
5.2
5.2
mg/L
1
0.0428
5
104
80 120
MS # 1
Parent Sample:
J24070005 -- 2024016757
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Chloride
1.5
7.52
mg/L
5
0.0154
5
97.1
80 120
Sulfate
5.56
5.56
mg/L
1
0.0428
5
101
80 120
MSD # 1
Parent Sample:
J24070005 -- 2024016757
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Chloride
1.51
7.56
mg/L
5
0.0154
5
97.9
80 120 0.531
Sulfate
5.6
5.6
mg/L
1
0.0428
5
102
80 120 0.86
MS # 2
Parent Sample:
J24070005 -- 2024016783
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Chloride
7.75
7.75
mg/L
1
0.0154
5
99.8
80 120
Sulfate
4
20
mg/L
5
0.0428
5
98
80 120
MSD # 2
Parent Sample:
J24070005 -- 2024016783
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Chloride
7.76
7.76
mg/L
1
0.0154
5
100
80 120 0.168
Sulfate
4
20
mg/L
5
0.0428
5
98.3
80 120 0.075

Certificate of Laboratory Analysis Page 34 of 152
This report shall not be reproduced, except in full.
Order # J24070005
Level II QC Summary
Q24070483 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Sulfate
0.03
0.03
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S Ike
% Recovery
LCL
UCL
Chloride
4.94
4.94
mg/L
1
0.0154
5
98.8
80
120
Sulfate
5.06
5.06
mg/L
1
0.0428
5
101
80
120
MS # 1
Parent Sample:
J24070716 -- 2024019733
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Chloride
1.07
21.4
mg/L
20
0.0154
5
93.6
80
120
Sulfate
4.55
91
mg/L
20
0.0428
5
70.8
80
120
MSD # 1
Parent Sample:
J24070716 -- 2024019733
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Chloride
1.07
21.3
mg/L
20
0.0154
5
92.4
80
120 0.281
Sulfate
4.54
90.7
mg/L
20
0.0428
5
65.2
80
120 0.308
Qualifiers:
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate
to the spike level. The associated Laboratory Control Spike recovery was acceptable.
Qualifier
Qualifier
Qualifier
M4
Qualifier
M4

Certificate of Laboratory Analysis Page 35 of 152
This report shall not be reproduced, except in full.
Order # J24070005
Level II QC Summary
Q24070485 ICP_DIS_TRM TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
-0.000027
-0.000027
mg/L
1
0.002
0.005
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
4.92
4.92
mg/L
1
0.002
5
98.4
80
120
MS # 1
Parent Sample:
J24070005 -- 2024016769
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
5
5
mg/L
1
0.002
5
99.2
70
130
MSD # 1
Parent Sample:
J24070005 -- 2024016769
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Barium (Ba)
4.91
4.91
mg/L
1
0.002
5
97.5
70
130 1.72
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 36 of 152
This report shall not be reproduced, except in full.
Order # J24070005
Level II QC Summary
Q24070437 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
0.00006
0.00006
mg/L
1
0.002
0.005
< MDL
Calcium (Ca)
0.00592
0.00592
mg/L
1
0.012
0.05
< MDL
Magnesium (Mg)
-0.00402
-0.00402
mg/L
1
0.008
0.02
< MDL
Potassium (K)
-0.00878
-0.00878
mg/L
1
0.031
0.1
< MDL
Sodium (Na)
-0.0204
-0.0204
mg/L
1
0.017
0.05
< MDL
LCS # 1
MS # 1
Parameter
Measured
Final
Units
Barium (Ba)
5.2
5.2
mg/L
Calcium (Ca)
5.04
5.04
mg/L
Magnesium (Mg)
5.18
5.18
mg/L
Potassium (K)
5.12
5.12
mg/L
Sodium (Na)
5
5
mg/L
Parameter
Measured
Final
Units
Barium (Ba)
5.45
5.45
mg/L
Calcium (Ca)
12.8
12.8
mg/L
Magnesium (Mg)
8.43
8.43
mg/L
Potassium (K)
6.44
6.44
mg/L
Sodium (Na)
11.2
11.2
mg/L
MSD # 1
Parameter
Measured
Final
Units
Barium (Ba)
5.45
5.45
mg/L
Calcium (Ca)
12.7
12.7
mg/L
Magnesium (Mg)
8.37
8.37
mg/L
Potassium (K)
6.4
6.4
mg/L
Sodium (Na)
11.2
11.2
mg/L
Dil
MDL
Spike
% Recovery
LCL
UCL
1
0.002
5
104
80
120
1
0.012
5
101
80
120
1
0.008
5
104
80
120
1
0.031
5
102
80
120
1
0.017
5
99.9
80
120
Parent Sample:
J24070005
-- 2024016757
Dil
MDL
Spike
% Recovery
LCL
UCL
1
0.002
5
104
75
125
1
0.012
5
106
75
125
1
0.008
5
101
75
125
1
0.031
5
103
75
125
1
0.017
5
101
75
125
Parent Sample:
J24070005
-- 2024016757
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
1
0.002
5
104
75
125
0.0367
1
0.012
5
105
75
125
0.534
1
0.008
5
100
75
125
0.679
1
0.031
5
102
75
125
0.608
1
0.017
5
101
75
125
0.116
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 37 of 152
This report shall not be reproduced, except in full.
Order # J24070005
Level II QC Summary
Q24070462 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
0.000022
0.000022
mg/L
1
0.002
0.005
< MDL
Calcium (Ca)
0.00347
0.00347
mg/L
1
0.012
0.05
< MDL
Magnesium (Mg)
-0.000449
-0.000449
mg/L
1
0.008
0.02
< MDL
Potassium (K)
-0.00973
-0.00973
mg/L
1
0.031
0.1
< MDL
Sodium (Na)
-0.0359
-0.0359
mg/L
1
0.017
0.05
< MDL
LCS # 1
MS # 1
Parameter
Measured
Final
Units
Barium (Ba)
4.99
4.99
mg/L
Calcium (Ca)
4.78
4.78
mg/L
Magnesium (Mg)
4.91
4.91
mg/L
Potassium (K)
4.87
4.87
mg/L
Sodium (Na)
4.74
4.74
mg/L
Parameter
Measured
Final
Units
Barium (Ba)
5.25
5.25
mg/L
Calcium (Ca)
14.4
14.4
mg/L
Magnesium (Mg)
12.6
12.6
mg/L
Potassium (K)
5.42
5.42
mg/L
Sodium (Na)
7.49
7.49
mg/L
MSD # 1
Parameter
Measured
Final
Units
Barium (Ba)
5.13
5.13
mg/L
Calcium (Ca)
14.2
14.2
mg/L
Magnesium (Mg)
12.4
12.4
mg/L
Potassium (K)
5.31
5.31
mg/L
Sodium (Na)
7.37
7.37
mg/L
Dil
MDL
Spike
% Recovery
LCL
UCL
1
0.002
5
99.8
80
120
1
0.012
5
95.6
80
120
1
0.008
5
98.1
80
120
1
0.031
5
97.5
80
120
1
0.017
5
94.7
80
120
Parent Sample:
J24070005
-- 2024016770
Dil
MDL
Spike
% Recovery
LCL
UCL
1
0.002
5
105
75
125
1
0.012
5
110
75
125
1
0.008
5
103
75
125
1
0.031
5
103
75
125
1
0.017
5
104
75
125
Parent Sample:
J24070005
-- 2024016770
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
1
0.002
5
102
75
125
2.18
1
0.012
5
106
75
125
1.31
1
0.008
5
100
75
125
1.29
1
0.031
5
101
75
125
1.94
1
0.017
5
102
75
125
1.6
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 38 of 152
This report shall not be reproduced, except in full.
Order # J24070005
Level II QC Summary
Q24070487 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Blank # 1
LCS # 1
Parameter
Measured
Final
Arsenic (As)
0.007
0.007
Cadmium (Cd)
0.008
0.008
Chromium (Cr)
0.011
0.011
Lead (Pb)
0.008
0.008
Silver (Ag)
0.001
0.001
Parameter
Measured
Final
Arsenic (As)
49.7
49.7
Cadmium (Cd)
50.9
50.9
Chromium (Cr)
50.7
50.7
Lead (Pb)
51.1
51.1
Silver (Ag)
52.7
52.7
LCSD # 1
Units
Dil
MDL
RDL
Relative Concentration
ug/L
1
0.111
1
< MDL
ug/L
1
0.032
1
< MDL
ug/L
1
0.185
1
< MDL
ug/L
1
0.037
1
< MDL
ug/L
1
0.035
1
< MDL
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
ug/L
1
0.111
50
99.4
80
120
ug/L
1
0.032
50
102
80
120
ug/L
1
0.185
50
101
80
120
ug/L
1
0.037
50
102
80
120
ug/L
1
0.035
50
105
80
120
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Arsenic (As)
49.9
49.9
ug/L
1
0.111
50
99.8
80
120
0.371
Cadmium (Cd)
52.1
52.1
ug/L
1
0.032
50
104
80
120
2.36
Chromium (Cr)
52.3
52.3
ug/L
1
0.185
50
105
80
120
3.11
Lead (Pb)
51.8
51.8
ug/L
1
0.037
50
104
80
120
1.27
Silver (Ag)
53.4
53.4
ug/L
1
0.035
50
107
80
120
1.43
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 39 of 152
This report shall not be reproduced, except in full.
Order # J24070005
Level II QC Summary
Q24070445 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
LCS # 1
MS # 1
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Arsenic (As)
0.02
0.02
ug/L
1
0.111
1
< MDL
Cadmium (Cd)
0.002
0.002
ug/L
1
0.032
1
< MDL
Chromium (Cr)
0.159
0.159
ug/L
1
0.185
1
< MDL
Lead (Pb)
0.011
0.011
ug/L
1
0.037
1
< MDL
Selenium (Se)
0.005
0.005
ug/L
1
0.193
1
< MDL
Silver (Ag)
0.001
0.001
ug/L
1
0.035
1
< MDL
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Arsenic (As)
55.6
55.6
ug/L
1
0.111
50
111
80
120
Cadmium (Cd)
48.8
48.8
ug/L
1
0.032
50
97.6
80
120
Chromium (Cr)
47.4
47.4
ug/L
1
0.185
50
94.8
80
120
Lead (Pb)
49.7
49.7
ug/L
1
0.037
50
99.4
80
120
Selenium (Se)
52.1
52.1
ug/L
1
0.193
50
104
80
120
Silver (Ag)
48.2
48.2
ug/L
1
0.035
50
96.4
80
120
Parent Sample:
J24070005 -- 2024016758
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
Arsenic (As)
54.6
54.6
ug/L
1
0.111
50
109
75
125
Cadmium (Cd)
48.8
48.8
ug/L
1
0.032
50
97.5
75
125
Chromium (Cr)
47.5
47.5
ug/L
1
0.185
50
94.4
75
125
Lead (Pb)
48.7
48.7
ug/L
1
0.037
50
97.4
75
125
Selenium (Se)
51.1
51.1
ug/L
1
0.193
50
102
75
125
Silver (Ag)
48.4
48.4
ug/L
1
0.035
50
96.7
75
125
Parent Sample:
J24070005 -- 2024016758
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
RPD
Arsenic (As)
54.9
54.9
ug/L
1
0.111
50
109
75
125
0.554
Cadmium (Cd)
49.2
49.2
ug/L
1
0.032
50
98.4
75
125
0.888
Chromium (Cr)
48.5
48.5
ug/L
1
0.185
50
96.5
75
125
2.16
Lead (Pb)
49.2
49.2
ug/L
1
0.037
50
98.4
75
125
1.05
Selenium (Se)
51.8
51.8
ug/L
1
0.193
50
104
75
125
1.36
Silver (Ag)
48.4
48.4
ug/L
1
0.035
50
96.9
75
125
0.163
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 40 of 152
This report shall not be reproduced, except in full.
Order # J24070005
Level II QC Summary
Q24070464 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
LCS # 1
MS # 1
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Arsenic (As)
0.014
0.014
ug/L
1
0.111
1
< MDL
Cadmium (Cd)
0.001
0.001
ug/L
1
0.032
1
< MDL
Chromium (Cr)
-0.002
-0.002
ug/L
1
0.185
1
< MDL
Lead (Pb)
0.021
0.021
ug/L
1
0.037
1
< MDL
Selenium (Se)
0.173
0.173
ug/L
1
0.193
1
< MDL
Silver (Ag)
0.001
0.001
ug/L
1
0.035
1
< MDL
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Arsenic (As)
50
50
ug/L
1
0.111
50
100
80
120
Cadmium (Cd)
49.8
49.8
ug/L
1
0.032
50
99.7
80
120
Chromium (Cr)
49.5
49.5
ug/L
1
0.185
50
99
80
120
Lead (Pb)
50.5
50.5
ug/L
1
0.037
50
101
80
120
Selenium (Se)
48.4
48.4
ug/L
1
0.193
50
96.7
80
120
Silver (Ag)
51.2
51.2
ug/L
1
0.035
50
102
80
120
Parent Sample:
J24070005 -- 2024016771
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
Arsenic (As)
49.4
49.4
ug/L
1
0.111
50
98.6
75
125
Cadmium (Cd)
49.1
49.1
ug/L
1
0.032
50
98.3
75
125
Chromium (Cr)
50.3
50.3
ug/L
1
0.185
50
98.3
75
125
Lead (Pb)
49.5
49.5
ug/L
1
0.037
50
98.9
75
125
Selenium (Se)
47.7
47.7
ug/L
1
0.193
50
95.2
75
125
Silver (Ag)
49.5
49.5
ug/L
1
0.035
50
98.9
75
125
Parent Sample:
J24070005 -- 2024016771
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
RPD
Arsenic (As)
49.3
49.3
ug/L
1
0.111
50
98.3
75
125
0.334
Cadmium (Cd)
48.9
48.9
ug/L
1
0.032
50
97.8
75
125
0.422
Chromium (Cr)
49.6
49.6
ug/L
1
0.185
50
97.1
75
125
1.25
Lead (Pb)
49.2
49.2
ug/L
1
0.037
50
98.3
75
125
0.652
Selenium (Se)
47.1
47.1
ug/L
1
0.193
50
94
75
125
1.34
Silver (Ag)
49.4
49.4
ug/L
1
0.035
50
98.7
75
125
0.243
Qualifier
Qualifier
Qualifier
Qualifier

ace
Pace Analytical Services, LLC
P98904K WY&W e. Suite 100
Huntersville, NC 28078
[phone]
August 07, 2024
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory between July 24, 2024 and July 26, 2024. The
results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC
Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace National - Mt. Juliet
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
wa- 'emu
Angela Baioni for
Lord Patton
[e-mail]
828-417-6055
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 107

ace
Pace Analytical Services, LLC
PaaR049r&y,'�e. Suite 100
Huntersville, NC 28078
[phone]
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Pace Analytical Services National
12065 Lebanon Road, Mt. Juliet, TN 37122
Alabama Certification #: 40660
Alaska Certification 17-026
Arizona Certification #: AZ0612
Arkansas Certification #: 88-0469
California Certification #: 2932
Canada Certification #: 1461.01
Colorado Certification #: TN00003
Connecticut Certification #: PH-0197
DOD Certification: #1461.01
EPA# TN00003
Florida Certification #: E87487
Georgia DW Certification #: 923
Georgia Certification: NELAP
Idaho Certification #: TN00003
Illinois Certification #: 200008
Indiana Certification #: C-TN-01
Iowa Certification #: 364
Kansas Certification #: E-10277
Kentucky UST Certification #: 16
Kentucky Certification #: 90010
Louisiana Certification #: A130792
Louisiana DW Certification #: LA180010
Maine Certification #: TN0002
Maryland Certification #: 324
Massachusetts Certification #: M-TNO03
Michigan Certification #: 9958
Minnesota Certification #: 047-999-395
Mississippi Certification #: TN00003
Missouri Certification #: 340
Montana Certification M CERT0086
Nebraska Certification #: NE-OS-15-05
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
CERTIFICATIONS
Nevada Certification #: TN-03-2002-34
New Hampshire Certification #: 2975
New Jersey Certification #: TNO02
New Mexico DW Certification
New York Certification #: 11742
North Carolina Aquatic Toxicity Certification #: 41
North Carolina Drinking Water Certification #: 21704
North Carolina Environmental Certificate #: 375
North Dakota Certification #: R-140
Ohio VAP Certification #: CL0069
Oklahoma Certification #: 9915
Oregon Certification #: TN200002
Pennsylvania Certification #: 68-02979
Rhode Island Certification #: LA000356
South Carolina Certification #: 84004
South Dakota Certification
Tennessee DW/Chem/Micro Certification #: 2006
Texas Certification #: T 104704245-17-14
Texas Mold Certification #: LAB0152
USDA Soil Permit #: P330-15-00234
Utah Certification #: TN00003
Virginia Certification #: VT2006
Vermont Dept. of Health: ID# VT-2006
Virginia Certification #: 460132
Washington Certification #: C847
West Virginia Certification #: 233
Wisconsin Certification #: 998093910
Wyoming UST Certification #: via A21LA 2926.01
A21-A-ISO 17025 Certification #: 1461.01
A21-A-ISO 17025 Certification #: 1461.02
AIHA-LAP/LLC EMLAP Certification #:100789
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water* LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 107

ace
Pace Analytical Services, LLC
P989041 WeYde. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92743836001
MW-1
Water
07/23/2410:10
07/24/24 14:25
92743836002
MW-1D
Water
07/23/2410:50
07/24/24 14:25
92743836003
MW-2A
Water
07/22/2410:40
07/24/24 14:25
92743836004
MW-211)
Water
07/22/24 09:55
07/24/24 14:25
92743836005
MW-3
Water
07/22/2413:25
07/24/24 14:25
92743836006
MW-313
Water
07/22/2414:20
07/24/24 14:25
92743836007
MW-4
Water
07/22/2415:21
07/24/24 14:25
92743836008
MW-41D
Water
07/22/2416:05
07/24/24 14:25
92743836009
MW-11
Water
07/22/2410:00
07/24/24 14:25
92743836010
MW-11D
Water
07/22/2412:30
07/24/24 14:25
92743836011
MW-12
Water
07/22/2415:20
07/24/24 14:25
92743836012
MW-12D
Water
07/22/2414:20
07/24/24 14:25
92743836013
SW-1
Water
07/23/2411:20
07/24/24 14:25
92743836014
MW-4R
Water
07/23/2411:29
07/24/24 14:25
92743836015
MW-4DR
Water
07/23/2410:45
07/24/24 14:25
92743836016
MNS TB-20240722-0800
Water
07/22/24 08:00
07/24/24 14:25
92743836017
MNS FB-20240722-1045
Water
07/22/2410:45
07/24/24 14:25
92743836018
MNS FB-20240723-1000
Water
07/23/2410:00
07/24/24 14:25
92743836019
MNS FD-20240722-1
Water
07/22/24 00:00
07/24/24 14:25
92743836020
MNS FD-20240723-1
Water
07/23/24 00:00
07/24/24 14:25
92743836021
MW-3BR
Water
07/22/2413:00
07/24/24 14:25
92743836022
MW-4BR
Water
07/22/2416:00
07/24/24 14:25
92743836023
MW-4BRR
Water
07/23/2410:01
07/24/24 14:25
92743836024
MW-11BR
Water
07/22/2413:20
07/24/24 14:25
92743836025
MW-13D
Water
07/25/2414:00
07/26/2413:00
92743836026
MW-13BR
Water
07/25/2413:50
07/26/2413:00
92743836027
MNS TB-20240725-1300
Water
07/25/2413:00
07/26/24 13:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 107

ace
Pace Analytical Services, LLC
P989041 WMr e. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J24070005 MNS Landfill #1
92743836
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92743836001
MW-1
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
SAS
50
PASI-C
92743836002
MW-1D
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
SAS
50
PASI-C
92743836003
MW-2A
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
TMK
50
PASI-C
92743836004
MW-2D
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
TMK
50
PASI-C
92743836005
MW-3
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
TMK
50
PASI-C
92743836006
MW-3D
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
TMK
50
PASI-C
92743836007
MW-4
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
TMK
50
PASI-C
92743836008
MW-4D
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
TMK
50
PASI-C
92743836009
MW-11
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
TMK
50
PASI-C
92743836010
MW-11D
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
TMK
50
PASI-C
92743836011
MW-12
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
TMK
50
PASI-C
92743836012
MW-12D
EPA 8260D by SIM
JAH
2
PAN
EPA 8260D
TMK
50
PASI-C
92743836013
SW-1
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
TMK
50
PASI-C
92743836014
MW-4R
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
TMK
50
PASI-C
92743836015
MW-4DR
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
TMK
50
PASI-C
92743836016
MNS_TB-20240722-0800
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
JJK
50
PASI-C
92743836017
MNS_FB-20240722-1045
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
JJK
50
PASI-C
92743836018
MNS_FB-20240723-1000
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
SAS
50
PASI-C
92743836019
MNS_FD-20240722-1
EPA 8260D by SIM
DWR
2
PAN
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 107

ace
Pace Analytical Services, LLC
P989041 Ydr e. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
J24070005 MNS Landfill #1
Pace Project No.:
92743836
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
EPA 8260D
JJK
50
PASI-C
92743836020
MNS_FD-20240723-1
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
SAS
50
PASI-C
92743836021
MW-3BR
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
JJK
50
PASI-C
92743836022
MW-4BR
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
JJK
50
PASI-C
92743836023
MW-4BRR
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
SAS
50
PASI-C
92743836024
MW-11BR
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
JJK
50
PASI-C
92743836025
MW-13D
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
TMK
50
PASI-C
92743836026
MW-13BR
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
TMK
50
PASI-C
92743836027
MNS_TB-20240725-1300
EPA 8260D by SIM
DWR
2
PAN
EPA 8260D
TMK
50
PASI-C
PAN = Pace National - Mt. Juliet
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 5 of 107

ace
Pace Analytical Services, LLC
Pdag04�y&� e. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
J24070005 MNS Landfill #1
92743836
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92743836006
MW-3D
EPA 8260D
cis-1,2-Dichloroethene
2.4
ug/L
1.0
08/01/24 21:49
92743836007
MW-4
EPA 8260D
Tetrachloroethene
0.901
ug/L
1.0
08/01/24 22:08
92743836008
MW-411)
EPA 8260D
Benzene
0.91 J
ug/L
1.0
08/02/24 21:49
EPA 8260D
cis-1,2-Dichloroethene
34.5
ug/L
1.0
08/02/24 21:49
EPA 8260D
Tetrachloroethene
0.58J
ug/L
1.0
08/02/24 21:49
EPA 8260D
Toluene
0.56J
ug/L
1.0
08/02/24 21:49
EPA 8260D
Trichloroethene
3.8
ug/L
1.0
08/02/24 21:49
EPA 8260D
Vinyl chloride
0.58J
ug/L
1.0
08/02/24 21:49
EPA 8260D
Xylene (Total)
31.2
ug/L
1.0
08/02/24 21:49
92743836014
MW-4R
EPA 8260D
Trichloroethene
0.57J
ug/L
1.0
08/02/24 21:11
92743836015
MW-4DR
EPA 8260D
cis-1,2-Dichloroethene
1.8
ug/L
1.0
08/02/24 21:30
EPA 8260D
Trichloroethene
0.901
ug/L
1.0
08/02/24 21:30
92743836019
MNS FD-20240722-1
EPA 8260D
Benzene
0.47J
ug/L
1.0
08/01/24 09:27
EPA 8260D
1,1-Dichloroethane
1.1
ug/L
1.0
08/01/24 09:27
EPA 8260D
cis-1,2-Dichloroethene
7.9
ug/L
1.0
08/01/24 09:27
EPA 8260D
Methylene Chloride
19.1
ug/L
5.0
08/01/24 09:27 B,C9,L1,v1
EPA 8260D
Tetrachloroethene
0.891
ug/L
1.0
08/01/24 09:27
EPA 8260D
Trichloroethene
2.6
ug/L
1.0
08/01/24 09:27
EPA 8260D
Trichlorofluoromethane
0.32J
ug/L
1.0
08/01/24 09:27
EPA 8260D
Xylene (Total)
115
ug/L
1.0
08/01/24 09:27
92743836020
MNS FD-20240723-1
EPA 8260D
1,1-Dichloroethane
0.41J
ug/L
1.0
08/02/24 02:30
EPA 8260D
cis-1,2-Dichloroethene
1.9
ug/L
1.0
08/02/24 02:30
EPA 8260D
Trichloroethene
0.82J
ug/L
1.0
08/02/24 02:30
92743836021
MW-36111
EPA 8260D
Benzene
0.43J
ug/L
1.0
08/01/2410:22
EPA 8260D
1,1-Dichloroethane
1.1
ug/L
1.0
08/01/2410:22
EPA 8260D
cis-1,2-Dichloroethene
7.2
ug/L
1.0
08/01/2410:22
EPA 8260D
Methylene Chloride
17.9
ug/L
5.0
08/01/2410:22 B,C9,L1,v1
EPA 8260D
Tetrachloroethene
0.79J
ug/L
1.0
08/01/2410:22
EPA 8260D
Trichloroethene
2.4
ug/L
1.0
08/01/2410:22
EPA 8260D
Xylene (Total)
108
ug/L
1.0
08/01/2410:22
92743836022
MW-4BR
EPA 8260D
Benzene
0.43J
ug/L
1.0
08/01/2410:40
EPA 8260D
Carbon disulfide
0.48J
ug/L
2.0
08/01/24 10:40
EPA 8260D
1,1-Dichloroethane
0.69J
ug/L
1.0
08/01/2410:40
EPA 8260D
cis-1,2-Dichloroethene
10.6
ug/L
1.0
08/01/2410:40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 107

ace
Pace Analytical Services, LLC
P98904t WeYde. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
J24070005 MNS Landfill #1
92743836
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92743836022
MW-413R
EPA 8260D
Methylene Chloride
11.4
ug/L
5.0
08/01/2410:40 B,C9,L1,v1
EPA 8260D
Trichloroethene
1.4
ug/L
1.0
08/01/2410:40
EPA 8260D
Xylene (Total)
6.8
ug/L
1.0
08/01/2410:40
92743836023
MW-4BRR
EPA 8260D
Acetone
28.4
ug/L
25.0
08/02/24 02:48
EPA 8260D
Carbon disulfide
8.2
ug/L
2.0
08/02/24 02:48
EPA 8260D
cis-1,2-Dichloroethene
1.2
ug/L
1.0
08/02/24 02:48
EPA 8260D
Xylene (Total)
0.58J
ug/L
1.0
08/02/24 02:48
92743836026
MW-13BR
EPA 8260D
cis-1,2-Dichloroethene
2.8
ug/L
1.0
08/03/24 20:46
EPA 8260D
Xylene (Total)
3.9
ug/L
1.0
08/03/24 20:46
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 107

ace
Pace Analytical Services, LLC
P98904t WeYde. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Method: EPA 8260D by SIM
Description: VOA (GC/MS) 8260D-SIM
Client: Duke Energy
Date: August 07, 2024
General Information:
27 samples were analyzed for EPA 8260D by SIM by Pace National Mt. Juliet. All samples were received in acceptable condition with
any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of
this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 8 of 107

ace
Pace Analytical Services, LLC
P98904t WeYde. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Method: EPA 8260D
Description: 8260D MSV Low Level
Client: Duke Energy
Date: August 07, 2024
General Information:
27 samples were analyzed for EPA 8260D by Pace Analytical Services Charlotte. All samples were received in acceptable condition
with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end
of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
QC Batch: 872095
v2: The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated
samples and the sensitivity of the instrument was verified with a reporting limit check standard.
• BLANK (Lab ID: 4493320)
• lodomethane
• trans-1,4-Dichloro-2-butene
• DUP (Lab ID: 4493323)
• Bromomethane
• lodomethane
• trans-1,4-Dichloro-2-butene
• MW-11 (Lab ID: 92743836009)
• lodomethane
• trans-1,4-Dichloro-2-butene
• MW-11D (Lab ID: 92743836010)
• lodomethane
• trans-1,4-Dichloro-2-butene
• MW-12 (Lab ID: 92743836011)
• lodomethane
• trans-1,4-Dichloro-2-butene
• MW-12D (Lab ID: 92743836012)
• lodomethane
• trans-1,4-Dichloro-2-butene
• MW-2A (Lab ID: 92743836003)
• lodomethane
• trans-1,4-Dichloro-2-butene
• MW-21D (Lab ID: 92743836004)
• lodomethane
• trans-1,4-Dichloro-2-butene
• MW-3 (Lab ID: 92743836005)
• lodomethane
• trans-1,4-Dichloro-2-butene
• MW-31D (Lab ID: 92743836006)
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 9 of 107

ace
Pace Analytical Services, LLC
P��R05t WydW e. Suite 100
�J Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Method: EPA 8260D
Description: 8260D MSV Low Level
Client: Duke Energy
Date: August 07, 2024
QC Batch: 872095
v2: The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated
samples and the sensitivity of the instrument was verified with a reporting limit check standard.
• lodomethane
• trans-1,4-Dichloro-2-butene
• MW-4 (Lab ID: 92743836007)
• lodomethane
• trans-1,4-Dichloro-2-butene
• SW-1 (Lab ID: 92743836013)
• lodomethane
• trans-1,4-Dichloro-2-butene
v3: The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated
samples may have low bias.
• LCS (Lab ID: 4493321)
• lodomethane
• trans-1,4-Dichloro-2-butene
• MS (Lab ID: 4493322)
• Bromomethane
• lodomethane
• trans-1,4-Dichloro-2-butene
QC Batch: 872357
v1: The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated
samples may have a high bias.
• BLANK (Lab ID: 4494341)
• Methylene Chloride
• LCS (Lab ID: 4494342)
• Methylene Chloride
• MNS_FB-20240722-1045 (Lab ID: 92743836017)
• Methylene Chloride
• MNS_FD-20240722-1 (Lab ID: 92743836019)
• Methylene Chloride
• MNS_TB-20240722-0800 (Lab ID: 92743836016)
• Methylene Chloride
• MW-11BR (Lab ID: 92743836024)
• Methylene Chloride
• MW-3BR (Lab ID: 92743836021)
• Methylene Chloride
• MW-4BR (Lab ID: 92743836022)
• Methylene Chloride
v2: The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated
samples and the sensitivity of the instrument was verified with a reporting limit check standard.
• DUP (Lab ID: 4494344)
• lodomethane
• MW-11BR (Lab ID: 92743836024)
• lodomethane
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 10 of 107

ace
Pace Analytical Services, LLC
PdaRyiir6fy�e. Suite 100
�J Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Method: EPA 8260D
Description: 8260D MSV Low Level
Client: Duke Energy
Date: August 07, 2024
QC Batch: 872357
v3: The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated
samples may have low bias.
• MNS_FD-20240722-1 (Lab ID: 92743836019)
• Iodomethane
• MS (Lab ID: 4494343)
• Iodomethane
QC Batch: 872652
v2: The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated
samples and the sensitivity of the instrument was verified with a reporting limit check standard.
• DUP (Lab ID: 4495792)
• Acetone
• Bromomethane
• Chloroethane
• Methylene Chloride
v3: The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated
samples may have low bias.
• MS (Lab ID: 4495791)
• Acetone
• Bromomethane
• Chloroethane
Methylene Chloride
QC Batch: 872676
v2: The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated
samples and the sensitivity of the instrument was verified with a reporting limit check standard.
• BLANK (Lab ID: 4495930)
• Iodomethane
• MW-41D (Lab ID: 92743836008)
• Iodomethane
• MW-4DR (Lab ID: 92743836015)
• Iodomethane
• MW-4R (Lab ID: 92743836014)
• Iodomethane
v3: The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated
samples may have low bias.
• LCS (Lab ID: 4495931)
• Iodomethane
• MS (Lab ID: 4495932)
• Methylene Chloride
• MSD (Lab ID: 4495933)
• Methylene Chloride
• MW-4R (Lab ID: 92743836014)
• Methylene Chloride
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 11 of 107

ace
Pace Analytical Services, LLC
PAR&Wyd�e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Method: EPA 8260D
Description: 8260D MSV Low Level
Client: Duke Energy
Date: August 07, 2024
QC Batch: 873044
v2: The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated
samples and the sensitivity of the instrument was verified with a reporting limit check standard.
• BLANK (Lab ID: 4497678)
• Bromomethane
• Chloromethane
• DUP (Lab ID: 4497681)
• Methylene Chloride
• MNS_TB-20240725-1300 (Lab ID: 92743836027)
• Bromomethane
• Chloromethane
• MW-13BR (Lab ID: 92743836026)
• Bromomethane
• Chloromethane
• MW-13D (Lab ID: 92743836025)
• Bromomethane
• Chloromethane
v3: The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated
samples may have low bias.
• LCS (Lab ID: 4497679)
• Bromomethane
• Chloromethane
• MS (Lab ID: 4497680)
• Methylene Chloride
• MW-13D (Lab ID: 92743836025)
• Methylene Chloride
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
QC Batch: 872357
B: Analyte was detected in the associated method blank.
• BLANK for HBN 872357 [MSV/9776 (Lab ID: 4494341)
• Methylene Chloride
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 12 of 107

ace
Pace Analytical Services, LLC
P98906rwyd�e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Method: EPA 8260D
Description: 8260D MSV Low Level
Client: Duke Energy
Date: August 07, 2024
QC Batch: 872357
L1: Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples
may be biased high.
• LCS (Lab ID: 4494342)
• Methylene Chloride
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 872676
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92743836014
R1: RPD value was outside control limits.
• MSD (Lab ID: 4495933)
• trans-1,4-Dichloro-2-butene
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: 872357
C9: Common Laboratory Contaminant.
• BLANK (Lab ID: 4494341)
• Methylene Chloride
• MNS_FD-20240722-1 (Lab ID: 92743836019)
• Methylene Chloride
• MW-3BR (Lab ID: 92743836021)
• Methylene Chloride
• MW-4BR (Lab ID: 92743836022)
• Methylene Chloride
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 13 of 107

ace
Pace Analytical Services, LLC
Pdag0Aiirpy&�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-1 Lab ID: 92743836001 Collected: 07/23/24 10:10 Received: 07/24/24 14:25 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
1,4-Dioxane (p-Dioxane)
ND
mg/L
0.00300
0.000597
1 07/29/24 15:40
07/29/24 15:40
123-91-1
Surrogates
Toluene-d8 (S)
94.4
%
77.0-127
1 07/29/24 15:40
07/29/24 15:40
2037-26-5
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
08/02/24 00:41
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
08/02/24 00:41
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
08/02/24 00:41
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
08/02/24 00:41
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
08/02/24 00:41
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
08/02/24 00:41
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
08/02/24 00:41
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
08/02/24 00:41
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
08/02/24 00:41
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
08/02/24 00:41
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
08/02/24 00:41
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
08/02/24 00:41
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
08/02/24 00:41
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
08/02/24 00:41
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
08/02/24 00:41
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
08/02/24 00:41
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
08/02/24 00:41
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
08/02/24 00:41
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
08/02/24 00:41
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
08/02/24 00:41
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
08/02/24 00:41
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
08/02/24 00:41
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
08/02/24 00:41
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
08/02/24 00:41
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
08/02/24 00:41
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
08/02/24 00:41
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
08/02/24 00:41
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
08/02/24 00:41
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
08/02/24 00:41
10061-02-6
Ethylbenzene
ND
ug/L
1.0
0.30
1
08/02/24 00:41
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
08/02/24 00:41
591-78-6
Iodomethane
ND
ug/L
20.0
9.7
1
08/02/24 00:41
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
08/02/24 00:41
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
08/02/24 00:41
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
08/02/24 00:41
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
08/02/24 00:41
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
08/02/24 00:41
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
08/02/24 00:41
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
08/02/24 00:41
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 107

ace
Pace Analytical Services, LLC
PAROAirwy�e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-1
Lab ID:
92743836001
Collected:
07/23/24 10:10
Received: 07/24/24 14:25 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/02/24 00:41
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/02/24 00:41
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
08/02/24 00:41
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/02/24 00:41
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/02/24 00:41
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/02/24 00:41
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/02/24 00:41
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
08/02/24 00:41
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
100
%
70-130
1
08/02/24 00:41
460-00-4
1,2-Dichloroethane-d4 (S)
96
%
70-130
1
08/02/24 00:41
17060-07-0
Toluene-d8 (S)
97
%
70-130
1
08/02/24 00:41
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 15 of 107

ace
Pace Analytical Services, LLC
pdagVirpy�e. Suite 100
��JJ Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-11) Lab ID: 92743836002 Collected: 07/23/24 10:50 Received: 07/24/24 14:25 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
1,4-Dioxane (p-Dioxane)
ND
mg/L
0.00300
0.000597
1 07/29/24 16:01
07/29/24 16:01
123-91-1
Surrogates
Toluene-d8 (S)
94.4
%
77.0-127
1 07/29/24 16:01
07/29/24 16:01
2037-26-5
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
08/02/24 00:59
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
08/02/24 00:59
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
08/02/24 00:59
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
08/02/24 00:59
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
08/02/24 00:59
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
08/02/24 00:59
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
08/02/24 00:59
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
08/02/24 00:59
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
08/02/24 00:59
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
08/02/24 00:59
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
08/02/24 00:59
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
08/02/24 00:59
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
08/02/24 00:59
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
08/02/24 00:59
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
08/02/24 00:59
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
08/02/24 00:59
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
08/02/24 00:59
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
08/02/24 00:59
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
08/02/24 00:59
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
08/02/24 00:59
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
08/02/24 00:59
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
08/02/24 00:59
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
08/02/24 00:59
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
08/02/24 00:59
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
08/02/24 00:59
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
08/02/24 00:59
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
08/02/24 00:59
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
08/02/24 00:59
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
08/02/24 00:59
10061-02-6
Ethylbenzene
ND
ug/L
1.0
0.30
1
08/02/24 00:59
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
08/02/24 00:59
591-78-6
Iodomethane
ND
ug/L
20.0
9.7
1
08/02/24 00:59
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
08/02/24 00:59
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
08/02/24 00:59
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
08/02/24 00:59
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
08/02/24 00:59
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
08/02/24 00:59
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
08/02/24 00:59
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
08/02/24 00:59
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC.
Page 16 of 107

ace
Pace Analytical Services, LLC
Pdagvrwyd�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MWAD
Lab ID:
92743836002
Collected:
07/23/24 10:50
Received: 07/24/24 14:25 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/02/24 00:59
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/02/24 00:59
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
08/02/24 00:59
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/02/24 00:59
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/02/24 00:59
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/02/24 00:59
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/02/24 00:59
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
08/02/24 00:59
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
100
%
70-130
1
08/02/24 00:59
460-00-4
1,2-Dichloroethane-d4 (S)
102
%
70-130
1
08/02/24 00:59
17060-07-0
Toluene-d8 (S)
98
%
70-130
1
08/02/24 00:59
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 17 of 107

ace
Pace Analytical Services, LLC
PARWWyd�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-2A Lab ID: 92743836003 Collected: 07/22/24 10:40 Received: 07/24/24 14:25 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 08/07/2024 06:04 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND mg/L 0.00300 0.000597 1 07/29/2416:23 07/29/2416:23 123-91-1
94.4
%
77.0-127
1
07/29/2416:23 07/29/2416:23
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
08/01/24 20:53
67-64-1
ND
ug/L
10.0
1.8
1
08/01/24 20:53
107-13-1
ND
ug/L
1.0
0.34
1
08/01/24 20:53
71-43-2
ND
ug/L
1.0
0.47
1
08/01/24 20:53
74-97-5
ND
ug/L
1.0
0.31
1
08/01/24 20:53
75-27-4
ND
ug/L
1.0
0.34
1
08/01/24 20:53
75-25-2
ND
ug/L
2.0
1.7
1
08/01/24 20:53
74-83-9
ND
ug/L
5.0
4.0
1
08/01/24 20:53
78-93-3
ND
ug/L
2.0
0.36
1
08/01/24 20:53
75-15-0
ND
ug/L
1.0
0.33
1
08/01/24 20:53
56-23-5
ND
ug/L
1.0
0.28
1
08/01/24 20:53
108-90-7
ND
ug/L
1.0
0.65
1
08/01/24 20:53
75-00-3
ND
ug/L
1.0
0.43
1
08/01/24 20:53
67-66-3
ND
ug/L
1.0
0.54
1
08/01/24 20:53
74-87-3
ND
ug/L
2.0
0.34
1
08/01/24 20:53
96-12-8
ND
ug/L
1.0
0.36
1
08/01/24 20:53
124-48-1
ND
ug/L
1.0
0.27
1
08/01/24 20:53
106-93-4
ND
ug/L
1.0
0.39
1
08/01/24 20:53
74-95-3
ND
ug/L
1.0
0.34
1
08/01/24 20:53
95-50-1
ND
ug/L
1.0
0.33
1
08/01/24 20:53
106-46-7
ND
ug/L
1.0
0.56
1
08/01/24 20:53
110-57-6
ND
ug/L
1.0
0.37
1
08/01/24 20:53
75-34-3
ND
ug/L
1.0
0.32
1
08/01/24 20:53
107-06-2
ND
ug/L
1.0
0.35
1
08/01/24 20:53
75-35-4
ND
ug/L
1.0
0.38
1
08/01/24 20:53
156-59-2
ND
ug/L
1.0
0.40
1
08/01/24 20:53
156-60-5
ND
ug/L
1.0
0.36
1
08/01/24 20:53
78-87-5
ND
ug/L
1.0
0.36
1
08/01/24 20:53
10061-01-5
ND
ug/L
1.0
0.36
1
08/01/24 20:53
10061-02-6
ND
ug/L
1.0
0.30
1
08/01/24 20:53
100-41-4
ND
ug/L
5.0
0.48
1
08/01/24 20:53
591-78-6
ND
ug/L
20.0
9.7
1
08/01/24 20:53
74-88-4
ND
ug/L
5.0
2.0
1
08/01/24 20:53
75-09-2
ND
ug/L
5.0
2.7
1
08/01/24 20:53
108-10-1
ND
ug/L
1.0
0.29
1
08/01/24 20:53
100-42-5
ND
ug/L
1.0
0.31
1
08/01/24 20:53
630-20-6
ND
ug/L
1.0
0.22
1
08/01/24 20:53
79-34-5
ND
ug/L
1.0
0.29
1
08/01/24 20:53
127-18-4
ND
ug/L
1.0
0.24
1
08/01/24 20:53
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
Page 18 of 107

ace
Pace Analytical Services, LLC
PARO WydW e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-2A
Lab ID:
92743836003
Collected:
07/22/24 10:40
Received: 07/24/24 14:25 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/01/24 20:53
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/01/24 20:53
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
08/01/24 20:53
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/01/24 20:53
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/01/24 20:53
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/01/24 20:53
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/01/24 20:53
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
08/01/24 20:53
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
97
%
70-130
1
08/01/24 20:53
460-00-4
1,2-Dichloroethane-d4 (S)
97
%
70-130
1
08/01/24 20:53
17060-07-0
Toluene-d8 (S)
98
%
70-130
1
08/01/24 20:53
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 19 of 107

ace
Pace Analytical Services, LLC
P989%larwyd�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-21) Lab ID: 92743836004 Collected: 07/22/24 09:55 Received: 07/24/24 14:25 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 08/07/2024 06:04 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND mg/L 0.00300 0.000597 1 07/29/2416:58 07/29/2416:58 123-91-1
94.4
%
77.0-127
1
07/29/2416:58 07/29/2416:58
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
08/01/24 21:11
67-64-1
ND
ug/L
10.0
1.8
1
08/01/24 21:11
107-13-1
ND
ug/L
1.0
0.34
1
08/01/24 21:11
71-43-2
ND
ug/L
1.0
0.47
1
08/01/24 21:11
74-97-5
ND
ug/L
1.0
0.31
1
08/01/24 21:11
75-27-4
ND
ug/L
1.0
0.34
1
08/01/24 21:11
75-25-2
ND
ug/L
2.0
1.7
1
08/01/24 21:11
74-83-9
ND
ug/L
5.0
4.0
1
08/01/24 21:11
78-93-3
ND
ug/L
2.0
0.36
1
08/01/24 21:11
75-15-0
ND
ug/L
1.0
0.33
1
08/01/24 21:11
56-23-5
ND
ug/L
1.0
0.28
1
08/01/24 21:11
108-90-7
ND
ug/L
1.0
0.65
1
08/01/24 21:11
75-00-3
ND
ug/L
1.0
0.43
1
08/01/24 21:11
67-66-3
ND
ug/L
1.0
0.54
1
08/01/24 21:11
74-87-3
ND
ug/L
2.0
0.34
1
08/01/24 21:11
96-12-8
ND
ug/L
1.0
0.36
1
08/01/24 21:11
124-48-1
ND
ug/L
1.0
0.27
1
08/01/24 21:11
106-93-4
ND
ug/L
1.0
0.39
1
08/01/24 21:11
74-95-3
ND
ug/L
1.0
0.34
1
08/01/24 21:11
95-50-1
ND
ug/L
1.0
0.33
1
08/01/24 21:11
106-46-7
ND
ug/L
1.0
0.56
1
08/01/24 21:11
110-57-6
ND
ug/L
1.0
0.37
1
08/01/24 21:11
75-34-3
ND
ug/L
1.0
0.32
1
08/01/24 21:11
107-06-2
ND
ug/L
1.0
0.35
1
08/01/24 21:11
75-35-4
ND
ug/L
1.0
0.38
1
08/01/24 21:11
156-59-2
ND
ug/L
1.0
0.40
1
08/01/24 21:11
156-60-5
ND
ug/L
1.0
0.36
1
08/01/24 21:11
78-87-5
ND
ug/L
1.0
0.36
1
08/01/24 21:11
10061-01-5
ND
ug/L
1.0
0.36
1
08/01/24 21:11
10061-02-6
ND
ug/L
1.0
0.30
1
08/01/24 21:11
100-41-4
ND
ug/L
5.0
0.48
1
08/01/24 21:11
591-78-6
ND
ug/L
20.0
9.7
1
08/01/24 21:11
74-88-4
ND
ug/L
5.0
2.0
1
08/01/24 21:11
75-09-2
ND
ug/L
5.0
2.7
1
08/01/24 21:11
108-10-1
ND
ug/L
1.0
0.29
1
08/01/24 21:11
100-42-5
ND
ug/L
1.0
0.31
1
08/01/24 21:11
630-20-6
ND
ug/L
1.0
0.22
1
08/01/24 21:11
79-34-5
ND
ug/L
1.0
0.29
1
08/01/24 21:11
127-18-4
ND
ug/L
1.0
0.24
1
08/01/24 21:11
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
Page 20 of 107

ace
Pace Analytical Services, LLC
Pdagmirpy�e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-211)
Lab ID:
92743836004
Collected:
07/22/24 09:55
Received: 07/24/24 14:25 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/01/24 21:11
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/01/24 21:11
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
08/01/24 21:11
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/01/24 21:11
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/01/24 21:11
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/01/24 21:11
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/01/24 21:11
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
08/01/24 21:11
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
96
%
70-130
1
08/01/24 21:11
460-00-4
1,2-Dichloroethane-d4 (S)
98
%
70-130
1
08/01/24 21:11
17060-07-0
Toluene-d8 (S)
97
%
70-130
1
08/01/24 21:11
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 21 of 107

ace
Pace Analytical Services, LLC
PAR19r6fy�e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-3 Lab ID: 92743836005 Collected: 07/22/24 13:25 Received: 07/24/24 14:25 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 08/07/2024 06:04 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND mg/L 0.00300 0.000597 1 07/29/2417:20 07/29/2417:20 123-91-1
94.4
%
77.0-127
1
07/29/2417:20 07/29/2417:20
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
08/01/24 21:30
67-64-1
ND
ug/L
10.0
1.8
1
08/01/24 21:30
107-13-1
ND
ug/L
1.0
0.34
1
08/01/24 21:30
71-43-2
ND
ug/L
1.0
0.47
1
08/01/24 21:30
74-97-5
ND
ug/L
1.0
0.31
1
08/01/24 21:30
75-27-4
ND
ug/L
1.0
0.34
1
08/01/24 21:30
75-25-2
ND
ug/L
2.0
1.7
1
08/01/24 21:30
74-83-9
ND
ug/L
5.0
4.0
1
08/01/24 21:30
78-93-3
ND
ug/L
2.0
0.36
1
08/01/24 21:30
75-15-0
ND
ug/L
1.0
0.33
1
08/01/24 21:30
56-23-5
ND
ug/L
1.0
0.28
1
08/01/24 21:30
108-90-7
ND
ug/L
1.0
0.65
1
08/01/24 21:30
75-00-3
ND
ug/L
1.0
0.43
1
08/01/24 21:30
67-66-3
ND
ug/L
1.0
0.54
1
08/01/24 21:30
74-87-3
ND
ug/L
2.0
0.34
1
08/01/24 21:30
96-12-8
ND
ug/L
1.0
0.36
1
08/01/24 21:30
124-48-1
ND
ug/L
1.0
0.27
1
08/01/24 21:30
106-93-4
ND
ug/L
1.0
0.39
1
08/01/24 21:30
74-95-3
ND
ug/L
1.0
0.34
1
08/01/24 21:30
95-50-1
ND
ug/L
1.0
0.33
1
08/01/24 21:30
106-46-7
ND
ug/L
1.0
0.56
1
08/01/24 21:30
110-57-6
ND
ug/L
1.0
0.37
1
08/01/24 21:30
75-34-3
ND
ug/L
1.0
0.32
1
08/01/24 21:30
107-06-2
ND
ug/L
1.0
0.35
1
08/01/24 21:30
75-35-4
ND
ug/L
1.0
0.38
1
08/01/24 21:30
156-59-2
ND
ug/L
1.0
0.40
1
08/01/24 21:30
156-60-5
ND
ug/L
1.0
0.36
1
08/01/24 21:30
78-87-5
ND
ug/L
1.0
0.36
1
08/01/24 21:30
10061-01-5
ND
ug/L
1.0
0.36
1
08/01/24 21:30
10061-02-6
ND
ug/L
1.0
0.30
1
08/01/24 21:30
100-41-4
ND
ug/L
5.0
0.48
1
08/01/24 21:30
591-78-6
ND
ug/L
20.0
9.7
1
08/01/24 21:30
74-88-4
ND
ug/L
5.0
2.0
1
08/01/24 21:30
75-09-2
ND
ug/L
5.0
2.7
1
08/01/24 21:30
108-10-1
ND
ug/L
1.0
0.29
1
08/01/24 21:30
100-42-5
ND
ug/L
1.0
0.31
1
08/01/24 21:30
630-20-6
ND
ug/L
1.0
0.22
1
08/01/24 21:30
79-34-5
ND
ug/L
1.0
0.29
1
08/01/24 21:30
127-18-4
ND
ug/L
1.0
0.24
1
08/01/24 21:30
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
Page 22 of 107

ace
Pace Analytical Services, LLC
P989%,sr6fyd�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-3
Lab ID:
92743836005
Collected:
07/22/24 13:25
Received: 07/24/24 14:25 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/01/24 21:30
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/01/24 21:30
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
08/01/24 21:30
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/01/24 21:30
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/01/24 21:30
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/01/24 21:30
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/01/24 21:30
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
08/01/24 21:30
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
08/01/24 21:30
460-00-4
1,2-Dichloroethane-d4 (S)
96
%
70-130
1
08/01/24 21:30
17060-07-0
Toluene-d8 (S)
98
%
70-130
1
08/01/24 21:30
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 23 of 107

ace
Pace Analytical Services, LLC
pdagl py&�e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-31) Lab ID: 92743836006 Collected: 07/22/24 14:20 Received: 07/24/24 14:25 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 08/07/2024 06:04 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND mg/L 0.00300 0.000597 1 07/29/2417:42 07/29/2417:42 123-91-1
94.4
%
77.0-127
1
07/29/2417:42 07/29/2417:42
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
08/01/24 21:49
67-64-1
ND
ug/L
10.0
1.8
1
08/01/24 21:49
107-13-1
ND
ug/L
1.0
0.34
1
08/01/24 21:49
71-43-2
ND
ug/L
1.0
0.47
1
08/01/24 21:49
74-97-5
ND
ug/L
1.0
0.31
1
08/01/24 21:49
75-27-4
ND
ug/L
1.0
0.34
1
08/01/24 21:49
75-25-2
ND
ug/L
2.0
1.7
1
08/01/24 21:49
74-83-9
ND
ug/L
5.0
4.0
1
08/01/24 21:49
78-93-3
ND
ug/L
2.0
0.36
1
08/01/24 21:49
75-15-0
ND
ug/L
1.0
0.33
1
08/01/24 21:49
56-23-5
ND
ug/L
1.0
0.28
1
08/01/24 21:49
108-90-7
ND
ug/L
1.0
0.65
1
08/01/24 21:49
75-00-3
ND
ug/L
1.0
0.43
1
08/01/24 21:49
67-66-3
ND
ug/L
1.0
0.54
1
08/01/24 21:49
74-87-3
ND
ug/L
2.0
0.34
1
08/01/24 21:49
96-12-8
ND
ug/L
1.0
0.36
1
08/01/24 21:49
124-48-1
ND
ug/L
1.0
0.27
1
08/01/24 21:49
106-93-4
ND
ug/L
1.0
0.39
1
08/01/24 21:49
74-95-3
ND
ug/L
1.0
0.34
1
08/01/24 21:49
95-50-1
ND
ug/L
1.0
0.33
1
08/01/24 21:49
106-46-7
ND
ug/L
1.0
0.56
1
08/01/24 21:49
110-57-6
ND
ug/L
1.0
0.37
1
08/01/24 21:49
75-34-3
ND
ug/L
1.0
0.32
1
08/01/24 21:49
107-06-2
ND
ug/L
1.0
0.35
1
08/01/24 21:49
75-35-4
2.4
ug/L
1.0
0.38
1
08/01/24 21:49
156-59-2
ND
ug/L
1.0
0.40
1
08/01/24 21:49
156-60-5
ND
ug/L
1.0
0.36
1
08/01/24 21:49
78-87-5
ND
ug/L
1.0
0.36
1
08/01/24 21:49
10061-01-5
ND
ug/L
1.0
0.36
1
08/01/24 21:49
10061-02-6
ND
ug/L
1.0
0.30
1
08/01/24 21:49
100-41-4
ND
ug/L
5.0
0.48
1
08/01/24 21:49
591-78-6
ND
ug/L
20.0
9.7
1
08/01/24 21:49
74-88-4
ND
ug/L
5.0
2.0
1
08/01/24 21:49
75-09-2
ND
ug/L
5.0
2.7
1
08/01/24 21:49
108-10-1
ND
ug/L
1.0
0.29
1
08/01/24 21:49
100-42-5
ND
ug/L
1.0
0.31
1
08/01/24 21:49
630-20-6
ND
ug/L
1.0
0.22
1
08/01/24 21:49
79-34-5
ND
ug/L
1.0
0.29
1
08/01/24 21:49
127-18-4
ND
ug/L
1.0
0.24
1
08/01/24 21:49
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
Page 24 of 107

ace
Pace Analytical Services, LLC
PARNr6fy�e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-311)
Lab ID:
92743836006
Collected:
07/22/24 14:20
Received: 07/24/24 14:25 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/01/24 21:49
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/01/24 21:49
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
08/01/24 21:49
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/01/24 21:49
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/01/24 21:49
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/01/24 21:49
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/01/24 21:49
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
08/01/24 21:49
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
100
%
70-130
1
08/01/24 21:49
460-00-4
1,2-Dichloroethane-d4 (S)
94
%
70-130
1
08/01/24 21:49
17060-07-0
Toluene-d8 (S)
97
%
70-130
1
08/01/24 21:49
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 25 of 107

ace
Pace Analytical Services, LLC
Pdag%larpy&�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-4 Lab ID: 92743836007 Collected: 07/22/24 15:21 Received: 07/24/24 14:25 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 08/07/2024 06:04 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND mg/L 0.00300 0.000597 1 07/29/2418:03 07/29/2418:03 123-91-1
94.3
%
77.0-127
1
07/29/2418:03 07/29/2418:03
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
08/01/24 22:08
67-64-1
ND
ug/L
10.0
1.8
1
08/01/24 22:08
107-13-1
ND
ug/L
1.0
0.34
1
08/01/24 22:08
71-43-2
ND
ug/L
1.0
0.47
1
08/01/24 22:08
74-97-5
ND
ug/L
1.0
0.31
1
08/01/24 22:08
75-27-4
ND
ug/L
1.0
0.34
1
08/01/24 22:08
75-25-2
ND
ug/L
2.0
1.7
1
08/01/24 22:08
74-83-9
ND
ug/L
5.0
4.0
1
08/01/24 22:08
78-93-3
ND
ug/L
2.0
0.36
1
08/01/24 22:08
75-15-0
ND
ug/L
1.0
0.33
1
08/01/24 22:08
56-23-5
ND
ug/L
1.0
0.28
1
08/01/24 22:08
108-90-7
ND
ug/L
1.0
0.65
1
08/01/24 22:08
75-00-3
ND
ug/L
1.0
0.43
1
08/01/24 22:08
67-66-3
ND
ug/L
1.0
0.54
1
08/01/24 22:08
74-87-3
ND
ug/L
2.0
0.34
1
08/01/24 22:08
96-12-8
ND
ug/L
1.0
0.36
1
08/01/24 22:08
124-48-1
ND
ug/L
1.0
0.27
1
08/01/24 22:08
106-93-4
ND
ug/L
1.0
0.39
1
08/01/24 22:08
74-95-3
ND
ug/L
1.0
0.34
1
08/01/24 22:08
95-50-1
ND
ug/L
1.0
0.33
1
08/01/24 22:08
106-46-7
ND
ug/L
1.0
0.56
1
08/01/24 22:08
110-57-6
ND
ug/L
1.0
0.37
1
08/01/24 22:08
75-34-3
ND
ug/L
1.0
0.32
1
08/01/24 22:08
107-06-2
ND
ug/L
1.0
0.35
1
08/01/24 22:08
75-35-4
ND
ug/L
1.0
0.38
1
08/01/24 22:08
156-59-2
ND
ug/L
1.0
0.40
1
08/01/24 22:08
156-60-5
ND
ug/L
1.0
0.36
1
08/01/24 22:08
78-87-5
ND
ug/L
1.0
0.36
1
08/01/24 22:08
10061-01-5
ND
ug/L
1.0
0.36
1
08/01/24 22:08
10061-02-6
ND
ug/L
1.0
0.30
1
08/01/24 22:08
100-41-4
ND
ug/L
5.0
0.48
1
08/01/24 22:08
591-78-6
ND
ug/L
20.0
9.7
1
08/01/24 22:08
74-88-4
ND
ug/L
5.0
2.0
1
08/01/24 22:08
75-09-2
ND
ug/L
5.0
2.7
1
08/01/24 22:08
108-10-1
ND
ug/L
1.0
0.29
1
08/01/24 22:08
100-42-5
ND
ug/L
1.0
0.31
1
08/01/24 22:08
630-20-6
ND
ug/L
1.0
0.22
1
08/01/24 22:08
79-34-5
0.901
ug/L
1.0
0.29
1
08/01/24 22:08
127-18-4
ND
ug/L
1.0
0.24
1
08/01/24 22:08
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
Page 26 of 107

ace
Pace Analytical Services, LLC
P989%1?r6fyd�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-4
Lab ID:
92743836007
Collected:
07/22/24 15:21
Received: 07/24/24 14:25 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/01/24 22:08
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/01/24 22:08
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
08/01/24 22:08
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/01/24 22:08
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/01/24 22:08
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/01/24 22:08
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/01/24 22:08
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
08/01/24 22:08
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
97
%
70-130
1
08/01/24 22:08
460-00-4
1,2-Dichloroethane-d4 (S)
98
%
70-130
1
08/01/24 22:08
17060-07-0
Toluene-d8 (S)
98
%
70-130
1
08/01/24 22:08
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 27 of 107

ace
Pace Analytical Services, LLC
P9891618r6fYd�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-41) Lab ID: 92743836008 Collected: 07/22/24 16:05 Received: 07/24/24 14:25 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National
- Mt. Juliet
1,4-Dioxane (p-Dioxane)
ND
mg/L
0.00300
0.000597
1 07/29/24 18:25
07/29/24 18:25
123-91-1
Surrogates
Toluene-d8 (S)
97.0
%
77.0-127
1 07/29/24 18:25
07/29/24 18:25
2037-26-5
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
08/02/24 21:49
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
08/02/24 21:49
107-13-1
Benzene
0.911
ug/L
1.0
0.34
1
08/02/24 21:49
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
08/02/24 21:49
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
08/02/24 21:49
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
08/02/24 21:49
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
08/02/24 21:49
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
08/02/24 21:49
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
08/02/24 21:49
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
08/02/24 21:49
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
08/02/24 21:49
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
08/02/24 21:49
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
08/02/24 21:49
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
08/02/24 21:49
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
08/02/24 21:49
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
08/02/24 21:49
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
08/02/24 21:49
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
08/02/24 21:49
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
08/02/24 21:49
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
08/02/24 21:49
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
08/02/24 21:49
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
08/02/24 21:49
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
08/02/24 21:49
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
08/02/24 21:49
75-35-4
cis-1,2-Dichloroethene
34.5
ug/L
1.0
0.38
1
08/02/24 21:49
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
08/02/24 21:49
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
08/02/24 21:49
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
08/02/24 21:49
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
08/02/24 21:49
10061-02-6
Ethylbenzene
ND
ug/L
1.0
0.30
1
08/02/24 21:49
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
08/02/24 21:49
591-78-6
Iodomethane
ND
ug/L
20.0
9.7
1
08/02/24 21:49
74-88-4 v2
Methylene Chloride
ND
ug/L
5.0
2.0
1
08/02/24 21:49
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
08/02/24 21:49
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
08/02/24 21:49
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
08/02/24 21:49
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
08/02/24 21:49
79-34-5
Tetrachloroethene
0.58J
ug/L
1.0
0.29
1
08/02/24 21:49
127-18-4
Toluene
0.56J
ug/L
1.0
0.24
1
08/02/24 21:49
108-88-3
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced,
except in full,
Date: 08/07/2024 06:04 PM
without the written consent of
Pace Analytical Services, LLC.
Page 28 of 107

ace
Pace Analytical Services, LLC
P989%6irwy�e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-411)
Lab ID:
92743836008
Collected:
07/22/24 16:05
Received: 07/24/24 14:25 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/02/24 21:49
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/02/24 21:49
79-00-5
Trichloroethene
3.8
ug/L
1.0
0.38
1
08/02/24 21:49
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/02/24 21:49
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/02/24 21:49
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/02/24 21:49
108-05-4
Vinyl chloride
0.581
ug/L
1.0
0.39
1
08/02/24 21:49
75-01-4
Xylene (Total)
31.2
ug/L
1.0
0.34
1
08/02/24 21:49
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
98
%
70-130
1
08/02/24 21:49
460-00-4
1,2-Dichloroethane-d4 (S)
98
%
70-130
1
08/02/24 21:49
17060-07-0
Toluene-d8 (S)
97
%
70-130
1
08/02/24 21:49
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 29 of 107

ace
Pace Analytical Services, LLC
P9890/tbirwyd�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-11 Lab ID: 92743836009 Collected: 07/22/24 10:00 Received: 07/24/24 14:25 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 08/07/2024 06:04 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND mg/L 0.00300 0.000597 1 07/29/2418:46 07/29/2418:46 123-91-1
94.4
%
77.0-127
1
07/29/2418:46 07/29/2418:46
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
08/01/24 22:26
67-64-1
ND
ug/L
10.0
1.8
1
08/01/24 22:26
107-13-1
ND
ug/L
1.0
0.34
1
08/01/24 22:26
71-43-2
ND
ug/L
1.0
0.47
1
08/01/24 22:26
74-97-5
ND
ug/L
1.0
0.31
1
08/01/24 22:26
75-27-4
ND
ug/L
1.0
0.34
1
08/01/24 22:26
75-25-2
ND
ug/L
2.0
1.7
1
08/01/24 22:26
74-83-9
ND
ug/L
5.0
4.0
1
08/01/24 22:26
78-93-3
ND
ug/L
2.0
0.36
1
08/01/24 22:26
75-15-0
ND
ug/L
1.0
0.33
1
08/01/24 22:26
56-23-5
ND
ug/L
1.0
0.28
1
08/01/24 22:26
108-90-7
ND
ug/L
1.0
0.65
1
08/01/24 22:26
75-00-3
ND
ug/L
1.0
0.43
1
08/01/24 22:26
67-66-3
ND
ug/L
1.0
0.54
1
08/01/24 22:26
74-87-3
ND
ug/L
2.0
0.34
1
08/01/24 22:26
96-12-8
ND
ug/L
1.0
0.36
1
08/01/24 22:26
124-48-1
ND
ug/L
1.0
0.27
1
08/01/24 22:26
106-93-4
ND
ug/L
1.0
0.39
1
08/01/24 22:26
74-95-3
ND
ug/L
1.0
0.34
1
08/01/24 22:26
95-50-1
ND
ug/L
1.0
0.33
1
08/01/24 22:26
106-46-7
ND
ug/L
1.0
0.56
1
08/01/24 22:26
110-57-6
ND
ug/L
1.0
0.37
1
08/01/24 22:26
75-34-3
ND
ug/L
1.0
0.32
1
08/01/24 22:26
107-06-2
ND
ug/L
1.0
0.35
1
08/01/24 22:26
75-35-4
ND
ug/L
1.0
0.38
1
08/01/24 22:26
156-59-2
ND
ug/L
1.0
0.40
1
08/01/24 22:26
156-60-5
ND
ug/L
1.0
0.36
1
08/01/24 22:26
78-87-5
ND
ug/L
1.0
0.36
1
08/01/24 22:26
10061-01-5
ND
ug/L
1.0
0.36
1
08/01/24 22:26
10061-02-6
ND
ug/L
1.0
0.30
1
08/01/24 22:26
100-41-4
ND
ug/L
5.0
0.48
1
08/01/24 22:26
591-78-6
ND
ug/L
20.0
9.7
1
08/01/24 22:26
74-88-4
ND
ug/L
5.0
2.0
1
08/01/24 22:26
75-09-2
ND
ug/L
5.0
2.7
1
08/01/24 22:26
108-10-1
ND
ug/L
1.0
0.29
1
08/01/24 22:26
100-42-5
ND
ug/L
1.0
0.31
1
08/01/24 22:26
630-20-6
ND
ug/L
1.0
0.22
1
08/01/24 22:26
79-34-5
ND
ug/L
1.0
0.29
1
08/01/24 22:26
127-18-4
ND
ug/L
1.0
0.24
1
08/01/24 22:26
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
Page 30 of 107

ace
Pace Analytical Services, LLC
PdagoAirpy�e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-11
Lab ID:
92743836009
Collected:
07/22/24 10:00
Received: 07/24/24 14:25 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/01/24 22:26
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/01/24 22:26
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
08/01/24 22:26
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/01/24 22:26
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/01/24 22:26
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/01/24 22:26
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/01/24 22:26
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
08/01/24 22:26
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
102
%
70-130
1
08/01/24 22:26
460-00-4
1,2-Dichloroethane-d4 (S)
100
%
70-130
1
08/01/24 22:26
17060-07-0
Toluene-d8 (S)
96
%
70-130
1
08/01/24 22:26
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 31 of 107

ace
Pace Analytical Services, LLC
Pdagohrwy�e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-11D Lab ID: 92743836010 Collected: 07/22/24 12:30 Received: 07/24/24 14:25 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 08/07/2024 06:04 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND mg/L 0.00300 0.000597 1 07/29/2419:08 07/29/2419:08 123-91-1
94.2
%
77.0-127
1
07/29/2419:08 07/29/2419:08
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
08/01/24 22:45
67-64-1
ND
ug/L
10.0
1.8
1
08/01/24 22:45
107-13-1
ND
ug/L
1.0
0.34
1
08/01/24 22:45
71-43-2
ND
ug/L
1.0
0.47
1
08/01/24 22:45
74-97-5
ND
ug/L
1.0
0.31
1
08/01/24 22:45
75-27-4
ND
ug/L
1.0
0.34
1
08/01/24 22:45
75-25-2
ND
ug/L
2.0
1.7
1
08/01/24 22:45
74-83-9
ND
ug/L
5.0
4.0
1
08/01/24 22:45
78-93-3
ND
ug/L
2.0
0.36
1
08/01/24 22:45
75-15-0
ND
ug/L
1.0
0.33
1
08/01/24 22:45
56-23-5
ND
ug/L
1.0
0.28
1
08/01/24 22:45
108-90-7
ND
ug/L
1.0
0.65
1
08/01/24 22:45
75-00-3
ND
ug/L
1.0
0.43
1
08/01/24 22:45
67-66-3
ND
ug/L
1.0
0.54
1
08/01/24 22:45
74-87-3
ND
ug/L
2.0
0.34
1
08/01/24 22:45
96-12-8
ND
ug/L
1.0
0.36
1
08/01/24 22:45
124-48-1
ND
ug/L
1.0
0.27
1
08/01/24 22:45
106-93-4
ND
ug/L
1.0
0.39
1
08/01/24 22:45
74-95-3
ND
ug/L
1.0
0.34
1
08/01/24 22:45
95-50-1
ND
ug/L
1.0
0.33
1
08/01/24 22:45
106-46-7
ND
ug/L
1.0
0.56
1
08/01/24 22:45
110-57-6
ND
ug/L
1.0
0.37
1
08/01/24 22:45
75-34-3
ND
ug/L
1.0
0.32
1
08/01/24 22:45
107-06-2
ND
ug/L
1.0
0.35
1
08/01/24 22:45
75-35-4
ND
ug/L
1.0
0.38
1
08/01/24 22:45
156-59-2
ND
ug/L
1.0
0.40
1
08/01/24 22:45
156-60-5
ND
ug/L
1.0
0.36
1
08/01/24 22:45
78-87-5
ND
ug/L
1.0
0.36
1
08/01/24 22:45
10061-01-5
ND
ug/L
1.0
0.36
1
08/01/24 22:45
10061-02-6
ND
ug/L
1.0
0.30
1
08/01/24 22:45
100-41-4
ND
ug/L
5.0
0.48
1
08/01/24 22:45
591-78-6
ND
ug/L
20.0
9.7
1
08/01/24 22:45
74-88-4
ND
ug/L
5.0
2.0
1
08/01/24 22:45
75-09-2
ND
ug/L
5.0
2.7
1
08/01/24 22:45
108-10-1
ND
ug/L
1.0
0.29
1
08/01/24 22:45
100-42-5
ND
ug/L
1.0
0.31
1
08/01/24 22:45
630-20-6
ND
ug/L
1.0
0.22
1
08/01/24 22:45
79-34-5
ND
ug/L
1.0
0.29
1
08/01/24 22:45
127-18-4
ND
ug/L
1.0
0.24
1
08/01/24 22:45
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
Page 32 of 107

ace
Pace Analytical Services, LLC
Pdago �irwy�e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-11D
Lab ID:
92743836010
Collected:
07/22/24 12:30
Received: 07/24/24 14:25 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/01/24 22:45
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/01/24 22:45
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
08/01/24 22:45
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/01/24 22:45
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/01/24 22:45
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/01/24 22:45
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/01/24 22:45
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
08/01/24 22:45
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
97
%
70-130
1
08/01/24 22:45
460-00-4
1,2-Dichloroethane-d4 (S)
98
%
70-130
1
08/01/24 22:45
17060-07-0
Toluene-d8 (S)
98
%
70-130
1
08/01/24 22:45
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 33 of 107

ace
Pace Analytical Services, LLC
pdagO�irpy�e. Suite 100
��JJ Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-12 Lab ID: 92743836011 Collected: 07/22/24 15:20 Received: 07/24/24 14:25 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 08/07/2024 06:04 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND mg/L 0.00300 0.000597 1 07/29/2419:30 07/29/2419:30 123-91-1
94.3
%
77.0-127
1
07/29/2419:30 07/29/2419:30
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
08/01/24 23:04
67-64-1
ND
ug/L
10.0
1.8
1
08/01/24 23:04
107-13-1
ND
ug/L
1.0
0.34
1
08/01/24 23:04
71-43-2
ND
ug/L
1.0
0.47
1
08/01/24 23:04
74-97-5
ND
ug/L
1.0
0.31
1
08/01/24 23:04
75-27-4
ND
ug/L
1.0
0.34
1
08/01/24 23:04
75-25-2
ND
ug/L
2.0
1.7
1
08/01/24 23:04
74-83-9
ND
ug/L
5.0
4.0
1
08/01/24 23:04
78-93-3
ND
ug/L
2.0
0.36
1
08/01/24 23:04
75-15-0
ND
ug/L
1.0
0.33
1
08/01/24 23:04
56-23-5
ND
ug/L
1.0
0.28
1
08/01/24 23:04
108-90-7
ND
ug/L
1.0
0.65
1
08/01/24 23:04
75-00-3
ND
ug/L
1.0
0.43
1
08/01/24 23:04
67-66-3
ND
ug/L
1.0
0.54
1
08/01/24 23:04
74-87-3
ND
ug/L
2.0
0.34
1
08/01/24 23:04
96-12-8
ND
ug/L
1.0
0.36
1
08/01/24 23:04
124-48-1
ND
ug/L
1.0
0.27
1
08/01/24 23:04
106-93-4
ND
ug/L
1.0
0.39
1
08/01/24 23:04
74-95-3
ND
ug/L
1.0
0.34
1
08/01/24 23:04
95-50-1
ND
ug/L
1.0
0.33
1
08/01/24 23:04
106-46-7
ND
ug/L
1.0
0.56
1
08/01/24 23:04
110-57-6
ND
ug/L
1.0
0.37
1
08/01/24 23:04
75-34-3
ND
ug/L
1.0
0.32
1
08/01/24 23:04
107-06-2
ND
ug/L
1.0
0.35
1
08/01/24 23:04
75-35-4
ND
ug/L
1.0
0.38
1
08/01/24 23:04
156-59-2
ND
ug/L
1.0
0.40
1
08/01/24 23:04
156-60-5
ND
ug/L
1.0
0.36
1
08/01/24 23:04
78-87-5
ND
ug/L
1.0
0.36
1
08/01/24 23:04
10061-01-5
ND
ug/L
1.0
0.36
1
08/01/24 23:04
10061-02-6
ND
ug/L
1.0
0.30
1
08/01/24 23:04
100-41-4
ND
ug/L
5.0
0.48
1
08/01/24 23:04
591-78-6
ND
ug/L
20.0
9.7
1
08/01/24 23:04
74-88-4
ND
ug/L
5.0
2.0
1
08/01/24 23:04
75-09-2
ND
ug/L
5.0
2.7
1
08/01/24 23:04
108-10-1
ND
ug/L
1.0
0.29
1
08/01/24 23:04
100-42-5
ND
ug/L
1.0
0.31
1
08/01/24 23:04
630-20-6
ND
ug/L
1.0
0.22
1
08/01/24 23:04
79-34-5
ND
ug/L
1.0
0.29
1
08/01/24 23:04
127-18-4
ND
ug/L
1.0
0.24
1
08/01/24 23:04
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
Page 34 of 107

ace
Pace Analytical Services, LLC
Pdagomrwy�e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-12
Lab ID:
92743836011
Collected:
07/22/24 15:20
Received: 07/24/24 14:25 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/01/24 23:04
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/01/24 23:04
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
08/01/24 23:04
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/01/24 23:04
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/01/24 23:04
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/01/24 23:04
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/01/24 23:04
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
08/01/24 23:04
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
96
%
70-130
1
08/01/24 23:04
460-00-4
1,2-Dichloroethane-d4 (S)
95
%
70-130
1
08/01/24 23:04
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
08/01/24 23:04
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 35 of 107

ace
Pace Analytical Services, LLC
pdagOMrpy�e. Suite 100
��JJ Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-12D Lab ID: 92743836012 Collected: 07/22/24 14:20 Received: 07/24/24 14:25 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 08/07/2024 06:04 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND mg/L 0.00300 0.000597 1 08/05/2415:15 08/05/2415:15 123-91-1
99.0
%
77.0-127
1
08/05/2415:15 08/05/2415:15
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
08/01/24 23:23
67-64-1
ND
ug/L
10.0
1.8
1
08/01/24 23:23
107-13-1
ND
ug/L
1.0
0.34
1
08/01/24 23:23
71-43-2
ND
ug/L
1.0
0.47
1
08/01/24 23:23
74-97-5
ND
ug/L
1.0
0.31
1
08/01/24 23:23
75-27-4
ND
ug/L
1.0
0.34
1
08/01/24 23:23
75-25-2
ND
ug/L
2.0
1.7
1
08/01/24 23:23
74-83-9
ND
ug/L
5.0
4.0
1
08/01/24 23:23
78-93-3
ND
ug/L
2.0
0.36
1
08/01/24 23:23
75-15-0
ND
ug/L
1.0
0.33
1
08/01/24 23:23
56-23-5
ND
ug/L
1.0
0.28
1
08/01/24 23:23
108-90-7
ND
ug/L
1.0
0.65
1
08/01/24 23:23
75-00-3
ND
ug/L
1.0
0.43
1
08/01/24 23:23
67-66-3
ND
ug/L
1.0
0.54
1
08/01/24 23:23
74-87-3
ND
ug/L
2.0
0.34
1
08/01/24 23:23
96-12-8
ND
ug/L
1.0
0.36
1
08/01/24 23:23
124-48-1
ND
ug/L
1.0
0.27
1
08/01/24 23:23
106-93-4
ND
ug/L
1.0
0.39
1
08/01/24 23:23
74-95-3
ND
ug/L
1.0
0.34
1
08/01/24 23:23
95-50-1
ND
ug/L
1.0
0.33
1
08/01/24 23:23
106-46-7
ND
ug/L
1.0
0.56
1
08/01/24 23:23
110-57-6
ND
ug/L
1.0
0.37
1
08/01/24 23:23
75-34-3
ND
ug/L
1.0
0.32
1
08/01/24 23:23
107-06-2
ND
ug/L
1.0
0.35
1
08/01/24 23:23
75-35-4
ND
ug/L
1.0
0.38
1
08/01/24 23:23
156-59-2
ND
ug/L
1.0
0.40
1
08/01/24 23:23
156-60-5
ND
ug/L
1.0
0.36
1
08/01/24 23:23
78-87-5
ND
ug/L
1.0
0.36
1
08/01/24 23:23
10061-01-5
ND
ug/L
1.0
0.36
1
08/01/24 23:23
10061-02-6
ND
ug/L
1.0
0.30
1
08/01/24 23:23
100-41-4
ND
ug/L
5.0
0.48
1
08/01/24 23:23
591-78-6
ND
ug/L
20.0
9.7
1
08/01/24 23:23
74-88-4
ND
ug/L
5.0
2.0
1
08/01/24 23:23
75-09-2
ND
ug/L
5.0
2.7
1
08/01/24 23:23
108-10-1
ND
ug/L
1.0
0.29
1
08/01/24 23:23
100-42-5
ND
ug/L
1.0
0.31
1
08/01/24 23:23
630-20-6
ND
ug/L
1.0
0.22
1
08/01/24 23:23
79-34-5
ND
ug/L
1.0
0.29
1
08/01/24 23:23
127-18-4
ND
ug/L
1.0
0.24
1
08/01/24 23:23
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
Page 36 of 107

ace
Pace Analytical Services, LLC
Pdagonrwy�e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-12D
Lab ID:
92743836012
Collected:
07/22/24 14:20
Received: 07/24/24 14:25 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/01/24 23:23
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/01/24 23:23
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
08/01/24 23:23
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/01/24 23:23
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/01/24 23:23
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/01/24 23:23
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/01/24 23:23
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
08/01/24 23:23
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
97
%
70-130
1
08/01/24 23:23
460-00-4
1,2-Dichloroethane-d4 (S)
98
%
70-130
1
08/01/24 23:23
17060-07-0
Toluene-d8 (S)
97
%
70-130
1
08/01/24 23:23
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 37 of 107

ace
Pace Analytical Services, LLC
Pdago �irwy�e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: SW-1 Lab ID: 92743836013 Collected: 07/23/24 11:20 Received: 07/24/24 14:25 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 08/07/2024 06:04 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND mg/L 0.00300 0.000597 1 07/29/24 20:38 07/29/24 20:38 123-91-1
93.8
%
77.0-127
1
07/29/24 20:38 07/29/24 20:38
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
08/01/24 23:41
67-64-1
ND
ug/L
10.0
1.8
1
08/01/24 23:41
107-13-1
ND
ug/L
1.0
0.34
1
08/01/24 23:41
71-43-2
ND
ug/L
1.0
0.47
1
08/01/24 23:41
74-97-5
ND
ug/L
1.0
0.31
1
08/01/24 23:41
75-27-4
ND
ug/L
1.0
0.34
1
08/01/24 23:41
75-25-2
ND
ug/L
2.0
1.7
1
08/01/24 23:41
74-83-9
ND
ug/L
5.0
4.0
1
08/01/24 23:41
78-93-3
ND
ug/L
2.0
0.36
1
08/01/24 23:41
75-15-0
ND
ug/L
1.0
0.33
1
08/01/24 23:41
56-23-5
ND
ug/L
1.0
0.28
1
08/01/24 23:41
108-90-7
ND
ug/L
1.0
0.65
1
08/01/24 23:41
75-00-3
ND
ug/L
1.0
0.43
1
08/01/24 23:41
67-66-3
ND
ug/L
1.0
0.54
1
08/01/24 23:41
74-87-3
ND
ug/L
2.0
0.34
1
08/01/24 23:41
96-12-8
ND
ug/L
1.0
0.36
1
08/01/24 23:41
124-48-1
ND
ug/L
1.0
0.27
1
08/01/24 23:41
106-93-4
ND
ug/L
1.0
0.39
1
08/01/24 23:41
74-95-3
ND
ug/L
1.0
0.34
1
08/01/24 23:41
95-50-1
ND
ug/L
1.0
0.33
1
08/01/24 23:41
106-46-7
ND
ug/L
1.0
0.56
1
08/01/24 23:41
110-57-6
ND
ug/L
1.0
0.37
1
08/01/24 23:41
75-34-3
ND
ug/L
1.0
0.32
1
08/01/24 23:41
107-06-2
ND
ug/L
1.0
0.35
1
08/01/24 23:41
75-35-4
ND
ug/L
1.0
0.38
1
08/01/24 23:41
156-59-2
ND
ug/L
1.0
0.40
1
08/01/24 23:41
156-60-5
ND
ug/L
1.0
0.36
1
08/01/24 23:41
78-87-5
ND
ug/L
1.0
0.36
1
08/01/24 23:41
10061-01-5
ND
ug/L
1.0
0.36
1
08/01/24 23:41
10061-02-6
ND
ug/L
1.0
0.30
1
08/01/24 23:41
100-41-4
ND
ug/L
5.0
0.48
1
08/01/24 23:41
591-78-6
ND
ug/L
20.0
9.7
1
08/01/24 23:41
74-88-4
ND
ug/L
5.0
2.0
1
08/01/24 23:41
75-09-2
ND
ug/L
5.0
2.7
1
08/01/24 23:41
108-10-1
ND
ug/L
1.0
0.29
1
08/01/24 23:41
100-42-5
ND
ug/L
1.0
0.31
1
08/01/24 23:41
630-20-6
ND
ug/L
1.0
0.22
1
08/01/24 23:41
79-34-5
ND
ug/L
1.0
0.29
1
08/01/24 23:41
127-18-4
ND
ug/L
1.0
0.24
1
08/01/24 23:41
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
Page 38 of 107

ace
Pace Analytical Services, LLC
Pdagohrwy�e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: SW-1
Lab ID:
92743836013
Collected:
07/23/24 11:20
Received: 07/24/24 14:25 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/01/24 23:41
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/01/24 23:41
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
08/01/24 23:41
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/01/24 23:41
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/01/24 23:41
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/01/24 23:41
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/01/24 23:41
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
08/01/24 23:41
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
98
%
70-130
1
08/01/24 23:41
460-00-4
1,2-Dichloroethane-d4 (S)
98
%
70-130
1
08/01/24 23:41
17060-07-0
Toluene-d8 (S)
97
%
70-130
1
08/01/24 23:41
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 39 of 107

ace
Pace Analytical Services, LLC
Pdagvrwy�e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-4R Lab ID: 92743836014 Collected: 07/23/24 11:29 Received: 07/24/24 14:25 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 08/07/2024 06:04 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND mg/L 0.00300 0.000597 1 08/02/2417:00 08/02/2417:00 123-91-1
96.9
%
77.0-127
1
08/02/2417:00 08/02/2417:00
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
08/02/24 21:11
67-64-1
ND
ug/L
10.0
1.8
1
08/02/24 21:11
107-13-1
ND
ug/L
1.0
0.34
1
08/02/24 21:11
71-43-2
ND
ug/L
1.0
0.47
1
08/02/24 21:11
74-97-5
ND
ug/L
1.0
0.31
1
08/02/24 21:11
75-27-4
ND
ug/L
1.0
0.34
1
08/02/24 21:11
75-25-2
ND
ug/L
2.0
1.7
1
08/02/24 21:11
74-83-9
ND
ug/L
5.0
4.0
1
08/02/24 21:11
78-93-3
ND
ug/L
2.0
0.36
1
08/02/24 21:11
75-15-0
ND
ug/L
1.0
0.33
1
08/02/24 21:11
56-23-5
ND
ug/L
1.0
0.28
1
08/02/24 21:11
108-90-7
ND
ug/L
1.0
0.65
1
08/02/24 21:11
75-00-3
ND
ug/L
1.0
0.43
1
08/02/24 21:11
67-66-3
ND
ug/L
1.0
0.54
1
08/02/24 21:11
74-87-3
ND
ug/L
2.0
0.34
1
08/02/24 21:11
96-12-8
ND
ug/L
1.0
0.36
1
08/02/24 21:11
124-48-1
ND
ug/L
1.0
0.27
1
08/02/24 21:11
106-93-4
ND
ug/L
1.0
0.39
1
08/02/24 21:11
74-95-3
ND
ug/L
1.0
0.34
1
08/02/24 21:11
95-50-1
ND
ug/L
1.0
0.33
1
08/02/24 21:11
106-46-7
ND
ug/L
1.0
0.56
1
08/02/24 21:11
110-57-6
ND
ug/L
1.0
0.37
1
08/02/24 21:11
75-34-3
ND
ug/L
1.0
0.32
1
08/02/24 21:11
107-06-2
ND
ug/L
1.0
0.35
1
08/02/24 21:11
75-35-4
ND
ug/L
1.0
0.38
1
08/02/24 21:11
156-59-2
ND
ug/L
1.0
0.40
1
08/02/24 21:11
156-60-5
ND
ug/L
1.0
0.36
1
08/02/24 21:11
78-87-5
ND
ug/L
1.0
0.36
1
08/02/24 21:11
10061-01-5
ND
ug/L
1.0
0.36
1
08/02/24 21:11
10061-02-6
ND
ug/L
1.0
0.30
1
08/02/24 21:11
100-41-4
ND
ug/L
5.0
0.48
1
08/02/24 21:11
591-78-6
ND
ug/L
20.0
9.7
1
08/02/24 21:11
74-88-4
ND
ug/L
5.0
2.0
1
08/02/24 21:11
75-09-2
ND
ug/L
5.0
2.7
1
08/02/24 21:11
108-10-1
ND
ug/L
1.0
0.29
1
08/02/24 21:11
100-42-5
ND
ug/L
1.0
0.31
1
08/02/24 21:11
630-20-6
ND
ug/L
1.0
0.22
1
08/02/24 21:11
79-34-5
ND
ug/L
1.0
0.29
1
08/02/24 21:11
127-18-4
ND
ug/L
1.0
0.24
1
08/02/24 21:11
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
R1
v2
v3
Page 40 of 107

ace
Pace Analytical Services, LLC
PdaR0gfir6fy&�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-4R
Lab ID:
92743836014
Collected:
07/23/24 11:29
Received: 07/24/24 14:25 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/02/24 21:11
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/02/24 21:11
79-00-5
Trichloroethene
0.57J
ug/L
1.0
0.38
1
08/02/24 21:11
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/02/24 21:11
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/02/24 21:11
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/02/24 21:11
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/02/24 21:11
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
08/02/24 21:11
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
98
%
70-130
1
08/02/24 21:11
460-00-4
1,2-Dichloroethane-d4 (S)
99
%
70-130
1
08/02/24 21:11
17060-07-0
Toluene-d8 (S)
97
%
70-130
1
08/02/24 21:11
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 41 of 107

ace
Pace Analytical Services, LLC
P98 Mr6fY&�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-4DR Lab ID: 92743836015 Collected: 07/23/24 10:45 Received: 07/24/24 14:25 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National
- Mt. Juliet
1,4-Dioxane (p-Dioxane)
ND
mg/L
0.00300
0.000597
1 08/02/24 17:22
08/02/24 17:22
123-91-1
Surrogates
Toluene-d8 (S)
96.6
%
77.0-127
1 08/02/24 17:22
08/02/24 17:22
2037-26-5
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
08/02/24 21:30
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
08/02/24 21:30
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
08/02/24 21:30
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
08/02/24 21:30
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
08/02/24 21:30
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
08/02/24 21:30
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
08/02/24 21:30
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
08/02/24 21:30
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
08/02/24 21:30
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
08/02/24 21:30
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
08/02/24 21:30
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
08/02/24 21:30
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
08/02/24 21:30
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
08/02/24 21:30
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
08/02/24 21:30
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
08/02/24 21:30
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
08/02/24 21:30
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
08/02/24 21:30
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
08/02/24 21:30
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
08/02/24 21:30
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
08/02/24 21:30
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
08/02/24 21:30
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
08/02/24 21:30
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
08/02/24 21:30
75-35-4
cis-1,2-Dichloroethene
1.8
ug/L
1.0
0.38
1
08/02/24 21:30
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
08/02/24 21:30
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
08/02/24 21:30
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
08/02/24 21:30
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
08/02/24 21:30
10061-02-6
Ethylbenzene
ND
ug/L
1.0
0.30
1
08/02/24 21:30
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
08/02/24 21:30
591-78-6
Iodomethane
ND
ug/L
20.0
9.7
1
08/02/24 21:30
74-88-4 v2
Methylene Chloride
ND
ug/L
5.0
2.0
1
08/02/24 21:30
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
08/02/24 21:30
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
08/02/24 21:30
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
08/02/24 21:30
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
08/02/24 21:30
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
08/02/24 21:30
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
08/02/24 21:30
108-88-3
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced,
except in full,
Date: 08/07/2024 06:04 PM
without the written consent of
Pace Analytical Services, LLC.
Page 42 of 107

ace
Pace Analytical Services, LLC
PARO WydW e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-4DR
Lab ID:
92743836015
Collected:
07/23/24 10:45
Received: 07/24/24 14:25 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/02/24 21:30
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/02/24 21:30
79-00-5
Trichloroethene
0.901
ug/L
1.0
0.38
1
08/02/24 21:30
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/02/24 21:30
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/02/24 21:30
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/02/24 21:30
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/02/24 21:30
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
08/02/24 21:30
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
98
%
70-130
1
08/02/24 21:30
460-00-4
1,2-Dichloroethane-d4 (S)
102
%
70-130
1
08/02/24 21:30
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
08/02/24 21:30
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 43 of 107

ace
Pace Analytical Services, LLC
P9�J 8M,r6fy&�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MNS_TB-20240722-0800 Lab ID: 92743836016 Collected: 07/22/24 08:00 Received: 07/24/24 14:25 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 08/07/2024 06:04 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND mg/L 0.00300 0.000597 1 08/02/2415:24 08/02/2415:24 123-91-1
96.7
%
77.0-127
1
08/02/2415:24 08/02/2415:24
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
08/01/24 08:51
67-64-1
ND
ug/L
10.0
1.8
1
08/01/24 08:51
107-13-1
ND
ug/L
1.0
0.34
1
08/01/24 08:51
71-43-2
ND
ug/L
1.0
0.47
1
08/01/24 08:51
74-97-5
ND
ug/L
1.0
0.31
1
08/01/24 08:51
75-27-4
ND
ug/L
1.0
0.34
1
08/01/24 08:51
75-25-2
ND
ug/L
2.0
1.7
1
08/01/24 08:51
74-83-9
ND
ug/L
5.0
4.0
1
08/01/24 08:51
78-93-3
ND
ug/L
2.0
0.36
1
08/01/24 08:51
75-15-0
ND
ug/L
1.0
0.33
1
08/01/24 08:51
56-23-5
ND
ug/L
1.0
0.28
1
08/01/24 08:51
108-90-7
ND
ug/L
1.0
0.65
1
08/01/24 08:51
75-00-3
ND
ug/L
1.0
0.43
1
08/01/24 08:51
67-66-3
ND
ug/L
1.0
0.54
1
08/01/24 08:51
74-87-3
ND
ug/L
2.0
0.34
1
08/01/24 08:51
96-12-8
ND
ug/L
1.0
0.36
1
08/01/24 08:51
124-48-1
ND
ug/L
1.0
0.27
1
08/01/24 08:51
106-93-4
ND
ug/L
1.0
0.39
1
08/01/24 08:51
74-95-3
ND
ug/L
1.0
0.34
1
08/01/24 08:51
95-50-1
ND
ug/L
1.0
0.33
1
08/01/24 08:51
106-46-7
ND
ug/L
1.0
0.56
1
08/01/24 08:51
110-57-6
ND
ug/L
1.0
0.37
1
08/01/24 08:51
75-34-3
ND
ug/L
1.0
0.32
1
08/01/24 08:51
107-06-2
ND
ug/L
1.0
0.35
1
08/01/24 08:51
75-35-4
ND
ug/L
1.0
0.38
1
08/01/24 08:51
156-59-2
ND
ug/L
1.0
0.40
1
08/01/24 08:51
156-60-5
ND
ug/L
1.0
0.36
1
08/01/24 08:51
78-87-5
ND
ug/L
1.0
0.36
1
08/01/24 08:51
10061-01-5
ND
ug/L
1.0
0.36
1
08/01/24 08:51
10061-02-6
ND
ug/L
1.0
0.30
1
08/01/24 08:51
100-41-4
ND
ug/L
5.0
0.48
1
08/01/24 08:51
591-78-6
ND
ug/L
20.0
9.7
1
08/01/24 08:51
74-88-4
ND
ug/L
5.0
2.0
1
08/01/24 08:51
75-09-2 L1,v1
ND
ug/L
5.0
2.7
1
08/01/24 08:51
108-10-1
ND
ug/L
1.0
0.29
1
08/01/24 08:51
100-42-5
ND
ug/L
1.0
0.31
1
08/01/24 08:51
630-20-6
ND
ug/L
1.0
0.22
1
08/01/24 08:51
79-34-5
ND
ug/L
1.0
0.29
1
08/01/24 08:51
127-18-4
ND
ug/L
1.0
0.24
1
08/01/24 08:51
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 44 of 107

ace
Pace Analytical Services, LLC
P98 Mr6fY&�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MNS_TB-20240722-0800
Lab ID:
92743836016
Collected:
07/22/24
08:00
Received: 07/24/24 14:25 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/01/24 08:51
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/01/24 08:51
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
08/01/24 08:51
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/01/24 08:51
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/01/24 08:51
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/01/24 08:51
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/01/24 08:51
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
08/01/24 08:51
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
97
%
70-130
1
08/01/24 08:51
460-00-4
1,2-Dichloroethane-d4 (S)
99
%
70-130
1
08/01/24 08:51
17060-07-0
Toluene-d8 (S)
100
%
70-130
1
08/01/24 08:51
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 45 of 107

ace
Pace Analytical Services, LLC
pdagVirpy�e. Suite 100
��JJ Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MNS_FB-20240722-1045 Lab ID: 92743836017 Collected: 07/22/24 10:45 Received: 07/24/24 14:25 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 08/07/2024 06:04 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND mg/L 0.00300 0.000597 1 08/02/2416:16 08/02/2416:16 123-91-1
97.0
%
77.0-127
1
08/02/2416:16 08/02/2416:16
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
08/01/24 09:09
67-64-1
ND
ug/L
10.0
1.8
1
08/01/24 09:09
107-13-1
ND
ug/L
1.0
0.34
1
08/01/24 09:09
71-43-2
ND
ug/L
1.0
0.47
1
08/01/24 09:09
74-97-5
ND
ug/L
1.0
0.31
1
08/01/24 09:09
75-27-4
ND
ug/L
1.0
0.34
1
08/01/24 09:09
75-25-2
ND
ug/L
2.0
1.7
1
08/01/24 09:09
74-83-9
ND
ug/L
5.0
4.0
1
08/01/24 09:09
78-93-3
ND
ug/L
2.0
0.36
1
08/01/24 09:09
75-15-0
ND
ug/L
1.0
0.33
1
08/01/24 09:09
56-23-5
ND
ug/L
1.0
0.28
1
08/01/24 09:09
108-90-7
ND
ug/L
1.0
0.65
1
08/01/24 09:09
75-00-3
ND
ug/L
1.0
0.43
1
08/01/24 09:09
67-66-3
ND
ug/L
1.0
0.54
1
08/01/24 09:09
74-87-3
ND
ug/L
2.0
0.34
1
08/01/24 09:09
96-12-8
ND
ug/L
1.0
0.36
1
08/01/24 09:09
124-48-1
ND
ug/L
1.0
0.27
1
08/01/24 09:09
106-93-4
ND
ug/L
1.0
0.39
1
08/01/24 09:09
74-95-3
ND
ug/L
1.0
0.34
1
08/01/24 09:09
95-50-1
ND
ug/L
1.0
0.33
1
08/01/24 09:09
106-46-7
ND
ug/L
1.0
0.56
1
08/01/24 09:09
110-57-6
ND
ug/L
1.0
0.37
1
08/01/24 09:09
75-34-3
ND
ug/L
1.0
0.32
1
08/01/24 09:09
107-06-2
ND
ug/L
1.0
0.35
1
08/01/24 09:09
75-35-4
ND
ug/L
1.0
0.38
1
08/01/24 09:09
156-59-2
ND
ug/L
1.0
0.40
1
08/01/24 09:09
156-60-5
ND
ug/L
1.0
0.36
1
08/01/24 09:09
78-87-5
ND
ug/L
1.0
0.36
1
08/01/24 09:09
10061-01-5
ND
ug/L
1.0
0.36
1
08/01/24 09:09
10061-02-6
ND
ug/L
1.0
0.30
1
08/01/24 09:09
100-41-4
ND
ug/L
5.0
0.48
1
08/01/24 09:09
591-78-6
ND
ug/L
20.0
9.7
1
08/01/24 09:09
74-88-4
ND
ug/L
5.0
2.0
1
08/01/24 09:09
75-09-2 L1,v1
ND
ug/L
5.0
2.7
1
08/01/24 09:09
108-10-1
ND
ug/L
1.0
0.29
1
08/01/24 09:09
100-42-5
ND
ug/L
1.0
0.31
1
08/01/24 09:09
630-20-6
ND
ug/L
1.0
0.22
1
08/01/24 09:09
79-34-5
ND
ug/L
1.0
0.29
1
08/01/24 09:09
127-18-4
ND
ug/L
1.0
0.24
1
08/01/24 09:09
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 46 of 107

ace
Pace Analytical Services, LLC
Pdagvrwy�e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MNS_FB-20240722-1045
Lab ID:
92743836017
Collected:
07/22/24
10:45
Received: 07/24/24 14:25 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/01/24 09:09
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/01/24 09:09
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
08/01/24 09:09
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/01/24 09:09
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/01/24 09:09
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/01/24 09:09
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/01/24 09:09
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
08/01/24 09:09
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
96
%
70-130
1
08/01/24 09:09
460-00-4
1,2-Dichloroethane-d4 (S)
100
%
70-130
1
08/01/24 09:09
17060-07-0
Toluene-d8 (S)
100
%
70-130
1
08/01/24 09:09
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 47 of 107

ace
Pace Analytical Services, LLC
PARO WydW e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MNS_FB-20240723-1000 Lab ID: 92743836018 Collected: 07/23/24 10:00 Received: 07/24/24 14:25 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 08/07/2024 06:04 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND mg/L 0.00300 0.000597 1 08/02/2416:38 08/02/2416:38 123-91-1
96.6
%
77.0-127
1
08/02/2416:38 08/02/2416:38
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
08/01/24 22:52
67-64-1
ND
ug/L
10.0
1.8
1
08/01/24 22:52
107-13-1
ND
ug/L
1.0
0.34
1
08/01/24 22:52
71-43-2
ND
ug/L
1.0
0.47
1
08/01/24 22:52
74-97-5
ND
ug/L
1.0
0.31
1
08/01/24 22:52
75-27-4
ND
ug/L
1.0
0.34
1
08/01/24 22:52
75-25-2
ND
ug/L
2.0
1.7
1
08/01/24 22:52
74-83-9
ND
ug/L
5.0
4.0
1
08/01/24 22:52
78-93-3
ND
ug/L
2.0
0.36
1
08/01/24 22:52
75-15-0
ND
ug/L
1.0
0.33
1
08/01/24 22:52
56-23-5
ND
ug/L
1.0
0.28
1
08/01/24 22:52
108-90-7
ND
ug/L
1.0
0.65
1
08/01/24 22:52
75-00-3
ND
ug/L
1.0
0.43
1
08/01/24 22:52
67-66-3
ND
ug/L
1.0
0.54
1
08/01/24 22:52
74-87-3
ND
ug/L
2.0
0.34
1
08/01/24 22:52
96-12-8
ND
ug/L
1.0
0.36
1
08/01/24 22:52
124-48-1
ND
ug/L
1.0
0.27
1
08/01/24 22:52
106-93-4
ND
ug/L
1.0
0.39
1
08/01/24 22:52
74-95-3
ND
ug/L
1.0
0.34
1
08/01/24 22:52
95-50-1
ND
ug/L
1.0
0.33
1
08/01/24 22:52
106-46-7
ND
ug/L
1.0
0.56
1
08/01/24 22:52
110-57-6
ND
ug/L
1.0
0.37
1
08/01/24 22:52
75-34-3
ND
ug/L
1.0
0.32
1
08/01/24 22:52
107-06-2
ND
ug/L
1.0
0.35
1
08/01/24 22:52
75-35-4
ND
ug/L
1.0
0.38
1
08/01/24 22:52
156-59-2
ND
ug/L
1.0
0.40
1
08/01/24 22:52
156-60-5
ND
ug/L
1.0
0.36
1
08/01/24 22:52
78-87-5
ND
ug/L
1.0
0.36
1
08/01/24 22:52
10061-01-5
ND
ug/L
1.0
0.36
1
08/01/24 22:52
10061-02-6
ND
ug/L
1.0
0.30
1
08/01/24 22:52
100-41-4
ND
ug/L
5.0
0.48
1
08/01/24 22:52
591-78-6
ND
ug/L
20.0
9.7
1
08/01/24 22:52
74-88-4
ND
ug/L
5.0
2.0
1
08/01/24 22:52
75-09-2
ND
ug/L
5.0
2.7
1
08/01/24 22:52
108-10-1
ND
ug/L
1.0
0.29
1
08/01/24 22:52
100-42-5
ND
ug/L
1.0
0.31
1
08/01/24 22:52
630-20-6
ND
ug/L
1.0
0.22
1
08/01/24 22:52
79-34-5
ND
ug/L
1.0
0.29
1
08/01/24 22:52
127-18-4
ND
ug/L
1.0
0.24
1
08/01/24 22:52
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 48 of 107

ace
Pace Analytical Services, LLC
P98 Mr6fY&�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MNS_FB-20240723-1000
Lab ID:
92743836018
Collected:
07/23/24
10:00
Received: 07/24/24 14:25 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/01/24 22:52
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/01/24 22:52
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
08/01/24 22:52
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/01/24 22:52
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/01/24 22:52
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/01/24 22:52
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/01/24 22:52
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
08/01/24 22:52
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
98
%
70-130
1
08/01/24 22:52
460-00-4
1,2-Dichloroethane-d4 (S)
102
%
70-130
1
08/01/24 22:52
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
08/01/24 22:52
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 49 of 107

ace
Pace Analytical Services, LLC
Pdagvirwy�e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MNS_FD-20240722-1 Lab ID: 92743836019 Collected: 07/22/24 00:00 Received: 07/24/24 14:25 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Date: 08/07/2024 06:04 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND mg/L 0.00300 0.000597 1 08/02/2417:44 08/02/2417:44 123-91-1
96.7
%
77.0-127
1
08/02/2417:44 08/02/2417:44
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
08/01/24 09:27
67-64-1
ND
ug/L
10.0
1.8
1
08/01/24 09:27
107-13-1
0.47J
ug/L
1.0
0.34
1
08/01/24 09:27
71-43-2
ND
ug/L
1.0
0.47
1
08/01/24 09:27
74-97-5
ND
ug/L
1.0
0.31
1
08/01/24 09:27
75-27-4
ND
ug/L
1.0
0.34
1
08/01/24 09:27
75-25-2
ND
ug/L
2.0
1.7
1
08/01/24 09:27
74-83-9
ND
ug/L
5.0
4.0
1
08/01/24 09:27
78-93-3
ND
ug/L
2.0
0.36
1
08/01/24 09:27
75-15-0
ND
ug/L
1.0
0.33
1
08/01/24 09:27
56-23-5
ND
ug/L
1.0
0.28
1
08/01/24 09:27
108-90-7
ND
ug/L
1.0
0.65
1
08/01/24 09:27
75-00-3
ND
ug/L
1.0
0.43
1
08/01/24 09:27
67-66-3
ND
ug/L
1.0
0.54
1
08/01/24 09:27
74-87-3
ND
ug/L
2.0
0.34
1
08/01/24 09:27
96-12-8
ND
ug/L
1.0
0.36
1
08/01/24 09:27
124-48-1
ND
ug/L
1.0
0.27
1
08/01/24 09:27
106-93-4
ND
ug/L
1.0
0.39
1
08/01/24 09:27
74-95-3
ND
ug/L
1.0
0.34
1
08/01/24 09:27
95-50-1
ND
ug/L
1.0
0.33
1
08/01/24 09:27
106-46-7
ND
ug/L
1.0
0.56
1
08/01/24 09:27
110-57-6
1.1
ug/L
1.0
0.37
1
08/01/24 09:27
75-34-3
ND
ug/L
1.0
0.32
1
08/01/24 09:27
107-06-2
ND
ug/L
1.0
0.35
1
08/01/24 09:27
75-35-4
7.9
ug/L
1.0
0.38
1
08/01/24 09:27
156-59-2
ND
ug/L
1.0
0.40
1
08/01/24 09:27
156-60-5
ND
ug/L
1.0
0.36
1
08/01/24 09:27
78-87-5
ND
ug/L
1.0
0.36
1
08/01/24 09:27
10061-01-5
ND
ug/L
1.0
0.36
1
08/01/24 09:27
10061-02-6
ND
ug/L
1.0
0.30
1
08/01/24 09:27
100-41-4
ND
ug/L
5.0
0.48
1
08/01/24 09:27
591-78-6
ND
ug/L
20.0
9.7
1
08/01/24 09:27
74-88-4 v3
19.1
ug/L
5.0
2.0
1
08/01/24 09:27
75-09-2 B,C9,
L1,v1
ND
ug/L
5.0
2.7
1
08/01/24 09:27
108-10-1
ND
ug/L
1.0
0.29
1
08/01/24 09:27
100-42-5
ND
ug/L
1.0
0.31
1
08/01/24 09:27
630-20-6
ND
ug/L
1.0
0.22
1
08/01/24 09:27
79-34-5
0.89J
ug/L
1.0
0.29
1
08/01/24 09:27
127-18-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 50 of 107

ace
Pace Analytical Services, LLC
Pdagmir6fy�e. Suite 100
��JJ Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MNS_FD-20240722-1
Lab ID:
92743836019
Collected:
07/22/24
00:00
Received: 07/24/24 14:25 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
Toluene
ND
ug/L
1.0
0.24
1
08/01/24 09:27
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/01/24 09:27
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/01/24 09:27
79-00-5
Trichloroethene
2.6
ug/L
1.0
0.38
1
08/01/24 09:27
79-01-6
Trichlorofluoromethane
0.32J
ug/L
1.0
0.30
1
08/01/24 09:27
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/01/24 09:27
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/01/24 09:27
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/01/24 09:27
75-01-4
Xylene (Total)
115
ug/L
1.0
0.34
1
08/01/24 09:27
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
96
%
70-130
1
08/01/24 09:27
460-00-4
1,2-Dichloroethane-d4 (S)
100
%
70-130
1
08/01/24 09:27
17060-07-0
Toluene-d8 (S)
102
%
70-130
1
08/01/24 09:27
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 51 of 107

ace
Pace Analytical Services, LLC
PAAYWY&e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MNS_FD-20240723-1 Lab ID: 92743836020 Collected: 07/23/24 00:00 Received: 07/24/24 14:25 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 08/07/2024 06:04 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND mg/L 0.00300 0.000597 1 08/02/2418:36 08/02/2418:36 123-91-1
96.1
%
77.0-127
1
08/02/2418:36 08/02/2418:36
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
08/02/24 02:30
67-64-1
ND
ug/L
10.0
1.8
1
08/02/24 02:30
107-13-1
ND
ug/L
1.0
0.34
1
08/02/24 02:30
71-43-2
ND
ug/L
1.0
0.47
1
08/02/24 02:30
74-97-5
ND
ug/L
1.0
0.31
1
08/02/24 02:30
75-27-4
ND
ug/L
1.0
0.34
1
08/02/24 02:30
75-25-2
ND
ug/L
2.0
1.7
1
08/02/24 02:30
74-83-9
ND
ug/L
5.0
4.0
1
08/02/24 02:30
78-93-3
ND
ug/L
2.0
0.36
1
08/02/24 02:30
75-15-0
ND
ug/L
1.0
0.33
1
08/02/24 02:30
56-23-5
ND
ug/L
1.0
0.28
1
08/02/24 02:30
108-90-7
ND
ug/L
1.0
0.65
1
08/02/24 02:30
75-00-3
ND
ug/L
1.0
0.43
1
08/02/24 02:30
67-66-3
ND
ug/L
1.0
0.54
1
08/02/24 02:30
74-87-3
ND
ug/L
2.0
0.34
1
08/02/24 02:30
96-12-8
ND
ug/L
1.0
0.36
1
08/02/24 02:30
124-48-1
ND
ug/L
1.0
0.27
1
08/02/24 02:30
106-93-4
ND
ug/L
1.0
0.39
1
08/02/24 02:30
74-95-3
ND
ug/L
1.0
0.34
1
08/02/24 02:30
95-50-1
ND
ug/L
1.0
0.33
1
08/02/24 02:30
106-46-7
ND
ug/L
1.0
0.56
1
08/02/24 02:30
110-57-6
0.41J
ug/L
1.0
0.37
1
08/02/24 02:30
75-34-3
ND
ug/L
1.0
0.32
1
08/02/24 02:30
107-06-2
ND
ug/L
1.0
0.35
1
08/02/24 02:30
75-35-4
1.9
ug/L
1.0
0.38
1
08/02/24 02:30
156-59-2
ND
ug/L
1.0
0.40
1
08/02/24 02:30
156-60-5
ND
ug/L
1.0
0.36
1
08/02/24 02:30
78-87-5
ND
ug/L
1.0
0.36
1
08/02/24 02:30
10061-01-5
ND
ug/L
1.0
0.36
1
08/02/24 02:30
10061-02-6
ND
ug/L
1.0
0.30
1
08/02/24 02:30
100-41-4
ND
ug/L
5.0
0.48
1
08/02/24 02:30
591-78-6
ND
ug/L
20.0
9.7
1
08/02/24 02:30
74-88-4
ND
ug/L
5.0
2.0
1
08/02/24 02:30
75-09-2
ND
ug/L
5.0
2.7
1
08/02/24 02:30
108-10-1
ND
ug/L
1.0
0.29
1
08/02/24 02:30
100-42-5
ND
ug/L
1.0
0.31
1
08/02/24 02:30
630-20-6
ND
ug/L
1.0
0.22
1
08/02/24 02:30
79-34-5
ND
ug/L
1.0
0.29
1
08/02/24 02:30
127-18-4
ND
ug/L
1.0
0.24
1
08/02/24 02:30
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 52 of 107

ace
Pace Analytical Services, LLC
P98906r6fY�e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MNS_FD-20240723-1
Lab ID:
92743836020
Collected:
07/23/24
00:00
Received: 07/24/24 14:25 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/02/24 02:30
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/02/24 02:30
79-00-5
Trichloroethene
0.82J
ug/L
1.0
0.38
1
08/02/24 02:30
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/02/24 02:30
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/02/24 02:30
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/02/24 02:30
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/02/24 02:30
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
08/02/24 02:30
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
100
%
70-130
1
08/02/24 02:30
460-00-4
1,2-Dichloroethane-d4 (S)
96
%
70-130
1
08/02/24 02:30
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
08/02/24 02:30
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 53 of 107

ace
Pace Analytical Services, LLC
Pdag0Aiirpy&�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-3BR Lab ID: 92743836021 Collected: 07/22/24 13:00 Received: 07/24/24 14:25 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National
- Mt. Juliet
1,4-Dioxane (p-Dioxane)
ND
mg/L
0.00300
0.000597
1 08/02/24 19:40
08/02/24 19:40
123-91-1
Surrogates
Toluene-d8 (S)
96.5
%
77.0-127
1 08/02/24 19:40
08/02/24 19:40
2037-26-5
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
08/01/24 10:22
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
08/01/24 10:22
107-13-1
Benzene
0.43J
ug/L
1.0
0.34
1
08/01/24 10:22
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
08/01/24 10:22
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
08/01/24 10:22
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
08/01/24 10:22
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
08/01/24 10:22
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
08/01/24 10:22
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
08/01/24 10:22
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
08/01/24 10:22
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
08/01/24 10:22
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
08/01/24 10:22
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
08/01/24 10:22
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
08/01/24 10:22
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
08/01/24 10:22
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
08/01/24 10:22
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
08/01/24 10:22
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
08/01/24 10:22
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
08/01/24 10:22
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
08/01/24 10:22
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
08/01/24 10:22
110-57-6
1,1-Dichloroethane
1.1
ug/L
1.0
0.37
1
08/01/24 10:22
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
08/01/24 10:22
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
08/01/24 10:22
75-35-4
cis-1,2-Dichloroethene
7.2
ug/L
1.0
0.38
1
08/01/24 10:22
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
08/01/24 10:22
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
08/01/24 10:22
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
08/01/24 10:22
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
08/01/24 10:22
10061-02-6
Ethylbenzene
ND
ug/L
1.0
0.30
1
08/01/24 10:22
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
08/01/24 10:22
591-78-6
Iodomethane
ND
ug/L
20.0
9.7
1
08/01/24 10:22
74-88-4
Methylene Chloride
17.9
ug/L
5.0
2.0
1
08/01/24 10:22
75-09-2 B,C9,
L1,v1
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
08/01/24 10:22
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
08/01/24 10:22
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
08/01/24 10:22
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
08/01/24 10:22
79-34-5
Tetrachloroethene
0.79J
ug/L
1.0
0.29
1
08/01/24 10:22
127-18-4
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced,
except in full,
Date: 08/07/2024 06:04 PM
without the written consent of
Pace Analytical Services, LLC.
Page 54 of 107

ace
Pace Analytical Services, LLC
P98 90r6fy&�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-313R
Lab ID:
92743836021
Collected:
07/22/24 13:00
Received: 07/24/24 14:25 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
Toluene
ND
ug/L
1.0
0.24
1
08/01/24 10:22
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/01/24 10:22
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/01/24 10:22
79-00-5
Trichloroethene
2.4
ug/L
1.0
0.38
1
08/01/24 10:22
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/01/24 10:22
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/01/24 10:22
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/01/24 10:22
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/01/24 10:22
75-01-4
Xylene (Total)
108
ug/L
1.0
0.34
1
08/01/24 10:22
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
98
%
70-130
1
08/01/24 10:22
460-00-4
1,2-Dichloroethane-d4 (S)
100
%
70-130
1
08/01/24 10:22
17060-07-0
Toluene-d8 (S)
100
%
70-130
1
08/01/24 10:22
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 55 of 107

ace
Pace Analytical Services, LLC
Pdagvirwy�e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-41BR Lab ID: 92743836022 Collected: 07/22/24 16:00 Received: 07/24/24 14:25 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National
- Mt. Juliet
1,4-Dioxane (p-Dioxane)
ND
mg/L
0.00300
0.000597
1 08/02/24 20:02
08/02/24 20:02
123-91-1
Surrogates
Toluene-d8 (S)
96.8
%
77.0-127
1 08/02/24 20:02
08/02/24 20:02
2037-26-5
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
08/01/24 10:40
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
08/01/24 10:40
107-13-1
Benzene
0.43J
ug/L
1.0
0.34
1
08/01/24 10:40
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
08/01/24 10:40
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
08/01/24 10:40
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
08/01/24 10:40
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
08/01/24 10:40
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
08/01/24 10:40
78-93-3
Carbon disulfide
0.48J
ug/L
2.0
0.36
1
08/01/24 10:40
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
08/01/24 10:40
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
08/01/24 10:40
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
08/01/24 10:40
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
08/01/24 10:40
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
08/01/24 10:40
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
08/01/24 10:40
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
08/01/24 10:40
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
08/01/24 10:40
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
08/01/24 10:40
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
08/01/24 10:40
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
08/01/24 10:40
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
08/01/24 10:40
110-57-6
1,1-Dichloroethane
0.69J
ug/L
1.0
0.37
1
08/01/24 10:40
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
08/01/24 10:40
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
08/01/24 10:40
75-35-4
cis-1,2-Dichloroethene
10.6
ug/L
1.0
0.38
1
08/01/24 10:40
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
08/01/24 10:40
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
08/01/24 10:40
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
08/01/24 10:40
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
08/01/24 10:40
10061-02-6
Ethylbenzene
ND
ug/L
1.0
0.30
1
08/01/24 10:40
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
08/01/24 10:40
591-78-6
Iodomethane
ND
ug/L
20.0
9.7
1
08/01/24 10:40
74-88-4
Methylene Chloride
11.4
ug/L
5.0
2.0
1
08/01/24 10:40
75-09-2 B,C9,
L1,v1
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
08/01/24 10:40
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
08/01/24 10:40
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
08/01/24 10:40
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
08/01/24 10:40
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
08/01/24 10:40
127-18-4
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced,
except in full,
Date: 08/07/2024 06:04 PM
without the written consent of
Pace Analytical Services, LLC.
Page 56 of 107

ace
Pace Analytical Services, LLC
P9891*rwyd�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-4BR
Lab ID:
92743836022
Collected:
07/22/24 16:00
Received: 07/24/24 14:25 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
Toluene
ND
ug/L
1.0
0.24
1
08/01/24 10:40
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/01/24 10:40
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/01/24 10:40
79-00-5
Trichloroethene
1.4
ug/L
1.0
0.38
1
08/01/24 10:40
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/01/24 10:40
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/01/24 10:40
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/01/24 10:40
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/01/24 10:40
75-01-4
Xylene (Total)
6.8
ug/L
1.0
0.34
1
08/01/24 10:40
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
97
%
70-130
1
08/01/24 10:40
460-00-4
1,2-Dichloroethane-d4 (S)
100
%
70-130
1
08/01/24 10:40
17060-07-0
Toluene-d8 (S)
100
%
70-130
1
08/01/24 10:40
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 57 of 107

ace
Pace Analytical Services, LLC
P98 90Ar6fY&�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-4BRR Lab ID: 92743836023 Collected: 07/23/24 10:01 Received: 07/24/24 14:25 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
1,4-Dioxane (p-Dioxane)
ND
mg/L
0.00300
0.000597
1 08/02/24 20:24
08/02/24 20:24
123-91-1
Surrogates
Toluene-d8 (S)
96.4
%
77.0-127
1 08/02/24 20:24
08/02/24 20:24
2037-26-5
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
28.4
ug/L
25.0
5.1
1
08/02/24 02:48
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
08/02/24 02:48
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
08/02/24 02:48
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
08/02/24 02:48
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
08/02/24 02:48
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
08/02/24 02:48
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
08/02/24 02:48
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
08/02/24 02:48
78-93-3
Carbon disulfide
8.2
ug/L
2.0
0.36
1
08/02/24 02:48
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
08/02/24 02:48
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
08/02/24 02:48
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
08/02/24 02:48
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
08/02/24 02:48
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
08/02/24 02:48
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
08/02/24 02:48
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
08/02/24 02:48
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
08/02/24 02:48
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
08/02/24 02:48
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
08/02/24 02:48
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
08/02/24 02:48
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
08/02/24 02:48
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
08/02/24 02:48
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
08/02/24 02:48
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
08/02/24 02:48
75-35-4
cis-1,2-Dichloroethene
1.2
ug/L
1.0
0.38
1
08/02/24 02:48
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
08/02/24 02:48
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
08/02/24 02:48
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
08/02/24 02:48
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
08/02/24 02:48
10061-02-6
Ethylbenzene
ND
ug/L
1.0
0.30
1
08/02/24 02:48
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
08/02/24 02:48
591-78-6
Iodomethane
ND
ug/L
20.0
9.7
1
08/02/24 02:48
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
08/02/24 02:48
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
08/02/24 02:48
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
08/02/24 02:48
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
08/02/24 02:48
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
08/02/24 02:48
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
08/02/24 02:48
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
08/02/24 02:48
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC.
Page 58 of 107

ace
Pace Analytical Services, LLC
P98906ir6fy�e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-4BRR
Lab ID:
92743836023
Collected:
07/23/24 10:01
Received: 07/24/24 14:25 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/02/24 02:48
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/02/24 02:48
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
08/02/24 02:48
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/02/24 02:48
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/02/24 02:48
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/02/24 02:48
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/02/24 02:48
75-01-4
Xylene (Total)
0.581
ug/L
1.0
0.34
1
08/02/24 02:48
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
102
%
70-130
1
08/02/24 02:48
460-00-4
1,2-Dichloroethane-d4 (S)
97
%
70-130
1
08/02/24 02:48
17060-07-0
Toluene-d8 (S)
102
%
70-130
1
08/02/24 02:48
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 59 of 107

ace
Pace Analytical Services, LLC
Padgwrwyd�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-11BR Lab ID: 92743836024 Collected: 07/22/24 13:20 Received: 07/24/24 14:25 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National
- Mt. Juliet
1,4-Dioxane (p-Dioxane)
ND
mg/L
0.00300
0.000597
1 08/02/24 20:46
08/02/24 20:46
123-91-1
Surrogates
Toluene-d8 (S)
96.4
%
77.0-127
1 08/02/24 20:46
08/02/24 20:46
2037-26-5
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
08/01/24 09:45
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
08/01/24 09:45
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
08/01/24 09:45
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
08/01/24 09:45
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
08/01/24 09:45
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
08/01/24 09:45
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
08/01/24 09:45
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
08/01/24 09:45
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
08/01/24 09:45
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
08/01/24 09:45
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
08/01/24 09:45
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
08/01/24 09:45
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
08/01/24 09:45
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
08/01/24 09:45
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
08/01/24 09:45
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
08/01/24 09:45
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
08/01/24 09:45
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
08/01/24 09:45
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
08/01/24 09:45
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
08/01/24 09:45
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
08/01/24 09:45
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
08/01/24 09:45
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
08/01/24 09:45
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
08/01/24 09:45
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
08/01/24 09:45
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
08/01/24 09:45
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
08/01/24 09:45
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
08/01/24 09:45
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
08/01/24 09:45
10061-02-6
Ethylbenzene
ND
ug/L
1.0
0.30
1
08/01/24 09:45
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
08/01/24 09:45
591-78-6
Iodomethane
ND
ug/L
20.0
9.7
1
08/01/24 09:45
74-88-4 v2
Methylene Chloride
ND
ug/L
5.0
2.0
1
08/01/24 09:45
75-09-2 L1,v1
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
08/01/24 09:45
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
08/01/24 09:45
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
08/01/24 09:45
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
08/01/24 09:45
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
08/01/24 09:45
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
08/01/24 09:45
108-88-3
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced,
except in full,
Date: 08/07/2024 06:04 PM
without the written consent of
Pace Analytical Services, LLC.
Page 60 of 107

ace
Pace Analytical Services, LLC
Padgwlir6fy&�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-11BR
Lab ID:
92743836024
Collected:
07/22/24 13:20
Received: 07/24/24 14:25 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/01/24 09:45
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/01/24 09:45
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
08/01/24 09:45
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/01/24 09:45
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/01/24 09:45
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/01/24 09:45
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/01/24 09:45
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
08/01/24 09:45
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
94
%
70-130
1
08/01/24 09:45
460-00-4
1,2-Dichloroethane-d4 (S)
98
%
70-130
1
08/01/24 09:45
17060-07-0
Toluene-d8 (S)
100
%
70-130
1
08/01/24 09:45
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 61 of 107

ace
Pace Analytical Services, LLC
Padg ifyd�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-13D Lab ID: 92743836025 Collected: 07/25/24 14:00 Received: 07/26/24 13:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 08/07/2024 06:04 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND mg/L 0.00300 0.000597 1 08/02/24 22:15 08/02/24 22:15 123-91-1
96.0
%
77.0-127
1
08/02/24 22:15 08/02/24 22:15
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
08/03/24 20:08
67-64-1
ND
ug/L
10.0
1.8
1
08/03/24 20:08
107-13-1
ND
ug/L
1.0
0.34
1
08/03/24 20:08
71-43-2
ND
ug/L
1.0
0.47
1
08/03/24 20:08
74-97-5
ND
ug/L
1.0
0.31
1
08/03/24 20:08
75-27-4
ND
ug/L
1.0
0.34
1
08/03/24 20:08
75-25-2
ND
ug/L
2.0
1.7
1
08/03/24 20:08
74-83-9
ND
ug/L
5.0
4.0
1
08/03/24 20:08
78-93-3
ND
ug/L
2.0
0.36
1
08/03/24 20:08
75-15-0
ND
ug/L
1.0
0.33
1
08/03/24 20:08
56-23-5
ND
ug/L
1.0
0.28
1
08/03/24 20:08
108-90-7
ND
ug/L
1.0
0.65
1
08/03/24 20:08
75-00-3
ND
ug/L
1.0
0.43
1
08/03/24 20:08
67-66-3
ND
ug/L
1.0
0.54
1
08/03/24 20:08
74-87-3
ND
ug/L
2.0
0.34
1
08/03/24 20:08
96-12-8
ND
ug/L
1.0
0.36
1
08/03/24 20:08
124-48-1
ND
ug/L
1.0
0.27
1
08/03/24 20:08
106-93-4
ND
ug/L
1.0
0.39
1
08/03/24 20:08
74-95-3
ND
ug/L
1.0
0.34
1
08/03/24 20:08
95-50-1
ND
ug/L
1.0
0.33
1
08/03/24 20:08
106-46-7
ND
ug/L
1.0
0.56
1
08/03/24 20:08
110-57-6
ND
ug/L
1.0
0.37
1
08/03/24 20:08
75-34-3
ND
ug/L
1.0
0.32
1
08/03/24 20:08
107-06-2
ND
ug/L
1.0
0.35
1
08/03/24 20:08
75-35-4
ND
ug/L
1.0
0.38
1
08/03/24 20:08
156-59-2
ND
ug/L
1.0
0.40
1
08/03/24 20:08
156-60-5
ND
ug/L
1.0
0.36
1
08/03/24 20:08
78-87-5
ND
ug/L
1.0
0.36
1
08/03/24 20:08
10061-01-5
ND
ug/L
1.0
0.36
1
08/03/24 20:08
10061-02-6
ND
ug/L
1.0
0.30
1
08/03/24 20:08
100-41-4
ND
ug/L
5.0
0.48
1
08/03/24 20:08
591-78-6
ND
ug/L
20.0
9.7
1
08/03/24 20:08
74-88-4
ND
ug/L
5.0
2.0
1
08/03/24 20:08
75-09-2
ND
ug/L
5.0
2.7
1
08/03/24 20:08
108-10-1
ND
ug/L
1.0
0.29
1
08/03/24 20:08
100-42-5
ND
ug/L
1.0
0.31
1
08/03/24 20:08
630-20-6
ND
ug/L
1.0
0.22
1
08/03/24 20:08
79-34-5
ND
ug/L
1.0
0.29
1
08/03/24 20:08
127-18-4
ND
ug/L
1.0
0.24
1
08/03/24 20:08
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
v3
Page 62 of 107

ace
Pace Analytical Services, LLC
Padg iwyd�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-13D
Lab ID:
92743836025
Collected:
07/25/24 14:00
Received: 07/26/24 13:00 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/03/24 20:08
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/03/24 20:08
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
08/03/24 20:08
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/03/24 20:08
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/03/24 20:08
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/03/24 20:08
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/03/24 20:08
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
08/03/24 20:08
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
98
%
70-130
1
08/03/24 20:08
460-00-4
1,2-Dichloroethane-d4 (S)
96
%
70-130
1
08/03/24 20:08
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
08/03/24 20:08
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 63 of 107

ace
Pace Analytical Services, LLC
Padgaffl�lrwyd�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-13BR Lab ID: 92743836026 Collected: 07/25/24 13:50 Received: 07/26/24 13:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 08/07/2024 06:04 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND mg/L 0.00300 0.000597 1 08/02/24 22:37 08/02/24 22:37 123-91-1
96.2
%
77.0-127
1
08/02/24 22:37 08/02/24 22:37
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
08/03/24 20:46
67-64-1
ND
ug/L
10.0
1.8
1
08/03/24 20:46
107-13-1
ND
ug/L
1.0
0.34
1
08/03/24 20:46
71-43-2
ND
ug/L
1.0
0.47
1
08/03/24 20:46
74-97-5
ND
ug/L
1.0
0.31
1
08/03/24 20:46
75-27-4
ND
ug/L
1.0
0.34
1
08/03/24 20:46
75-25-2
ND
ug/L
2.0
1.7
1
08/03/24 20:46
74-83-9
ND
ug/L
5.0
4.0
1
08/03/24 20:46
78-93-3
ND
ug/L
2.0
0.36
1
08/03/24 20:46
75-15-0
ND
ug/L
1.0
0.33
1
08/03/24 20:46
56-23-5
ND
ug/L
1.0
0.28
1
08/03/24 20:46
108-90-7
ND
ug/L
1.0
0.65
1
08/03/24 20:46
75-00-3
ND
ug/L
1.0
0.43
1
08/03/24 20:46
67-66-3
ND
ug/L
1.0
0.54
1
08/03/24 20:46
74-87-3
ND
ug/L
2.0
0.34
1
08/03/24 20:46
96-12-8
ND
ug/L
1.0
0.36
1
08/03/24 20:46
124-48-1
ND
ug/L
1.0
0.27
1
08/03/24 20:46
106-93-4
ND
ug/L
1.0
0.39
1
08/03/24 20:46
74-95-3
ND
ug/L
1.0
0.34
1
08/03/24 20:46
95-50-1
ND
ug/L
1.0
0.33
1
08/03/24 20:46
106-46-7
ND
ug/L
1.0
0.56
1
08/03/24 20:46
110-57-6
ND
ug/L
1.0
0.37
1
08/03/24 20:46
75-34-3
ND
ug/L
1.0
0.32
1
08/03/24 20:46
107-06-2
ND
ug/L
1.0
0.35
1
08/03/24 20:46
75-35-4
2.8
ug/L
1.0
0.38
1
08/03/24 20:46
156-59-2
ND
ug/L
1.0
0.40
1
08/03/24 20:46
156-60-5
ND
ug/L
1.0
0.36
1
08/03/24 20:46
78-87-5
ND
ug/L
1.0
0.36
1
08/03/24 20:46
10061-01-5
ND
ug/L
1.0
0.36
1
08/03/24 20:46
10061-02-6
ND
ug/L
1.0
0.30
1
08/03/24 20:46
100-41-4
ND
ug/L
5.0
0.48
1
08/03/24 20:46
591-78-6
ND
ug/L
20.0
9.7
1
08/03/24 20:46
74-88-4
ND
ug/L
5.0
2.0
1
08/03/24 20:46
75-09-2
ND
ug/L
5.0
2.7
1
08/03/24 20:46
108-10-1
ND
ug/L
1.0
0.29
1
08/03/24 20:46
100-42-5
ND
ug/L
1.0
0.31
1
08/03/24 20:46
630-20-6
ND
ug/L
1.0
0.22
1
08/03/24 20:46
79-34-5
ND
ug/L
1.0
0.29
1
08/03/24 20:46
127-18-4
ND
ug/L
1.0
0.24
1
08/03/24 20:46
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
Page 64 of 107

ace
Pace Analytical Services, LLC
Padgamiwyd�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MW-13BR
Lab ID:
92743836026
Collected:
07/25/24 13:50
Received: 07/26/24 13:00 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/03/24 20:46
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/03/24 20:46
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
08/03/24 20:46
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/03/24 20:46
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/03/24 20:46
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/03/24 20:46
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/03/24 20:46
75-01-4
Xylene (Total)
3.9
ug/L
1.0
0.34
1
08/03/24 20:46
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
08/03/24 20:46
460-00-4
1,2-Dichloroethane-d4 (S)
95
%
70-130
1
08/03/24 20:46
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
08/03/24 20:46
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 65 of 107

ace
Pace Analytical Services, LLC
Padgaftiwyd�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MNS_TB-20240725-1300 Lab ID: 92743836027 Collected: 07/25/24 13:00 Received: 07/26/24 13:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 08/07/2024 06:04 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND mg/L 0.00300 0.000597 1 08/02/2415:53 08/02/2415:53 123-91-1
96.5
%
77.0-127
1
08/02/2415:53 08/02/2415:53
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
08/03/2419:49
67-64-1
ND
ug/L
10.0
1.8
1
08/03/2419:49
107-13-1
ND
ug/L
1.0
0.34
1
08/03/2419:49
71-43-2
ND
ug/L
1.0
0.47
1
08/03/2419:49
74-97-5
ND
ug/L
1.0
0.31
1
08/03/2419:49
75-27-4
ND
ug/L
1.0
0.34
1
08/03/2419:49
75-25-2
ND
ug/L
2.0
1.7
1
08/03/2419:49
74-83-9
ND
ug/L
5.0
4.0
1
08/03/2419:49
78-93-3
ND
ug/L
2.0
0.36
1
08/03/2419:49
75-15-0
ND
ug/L
1.0
0.33
1
08/03/2419:49
56-23-5
ND
ug/L
1.0
0.28
1
08/03/2419:49
108-90-7
ND
ug/L
1.0
0.65
1
08/03/2419:49
75-00-3
ND
ug/L
1.0
0.43
1
08/03/2419:49
67-66-3
ND
ug/L
1.0
0.54
1
08/03/2419:49
74-87-3
ND
ug/L
2.0
0.34
1
08/03/2419:49
96-12-8
ND
ug/L
1.0
0.36
1
08/03/2419:49
124-48-1
ND
ug/L
1.0
0.27
1
08/03/2419:49
106-93-4
ND
ug/L
1.0
0.39
1
08/03/2419:49
74-95-3
ND
ug/L
1.0
0.34
1
08/03/2419:49
95-50-1
ND
ug/L
1.0
0.33
1
08/03/2419:49
106-46-7
ND
ug/L
1.0
0.56
1
08/03/2419:49
110-57-6
ND
ug/L
1.0
0.37
1
08/03/2419:49
75-34-3
ND
ug/L
1.0
0.32
1
08/03/2419:49
107-06-2
ND
ug/L
1.0
0.35
1
08/03/2419:49
75-35-4
ND
ug/L
1.0
0.38
1
08/03/2419:49
156-59-2
ND
ug/L
1.0
0.40
1
08/03/2419:49
156-60-5
ND
ug/L
1.0
0.36
1
08/03/2419:49
78-87-5
ND
ug/L
1.0
0.36
1
08/03/2419:49
10061-01-5
ND
ug/L
1.0
0.36
1
08/03/2419:49
10061-02-6
ND
ug/L
1.0
0.30
1
08/03/2419:49
100-41-4
ND
ug/L
5.0
0.48
1
08/03/2419:49
591-78-6
ND
ug/L
20.0
9.7
1
08/03/2419:49
74-88-4
ND
ug/L
5.0
2.0
1
08/03/2419:49
75-09-2
ND
ug/L
5.0
2.7
1
08/03/2419:49
108-10-1
ND
ug/L
1.0
0.29
1
08/03/2419:49
100-42-5
ND
ug/L
1.0
0.31
1
08/03/2419:49
630-20-6
ND
ug/L
1.0
0.22
1
08/03/2419:49
79-34-5
ND
ug/L
1.0
0.29
1
08/03/2419:49
127-18-4
ND
ug/L
1.0
0.24
1
08/03/2419:49
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
Page 66 of 107

ace
Pace Analytical Services, LLC
Padg"rwYd�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Sample: MNS_TB-20240725-1300
Lab ID:
92743836027
Collected:
07/25/24
13:00
Received: 07/26/24 13:00 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
08/03/24 19:49
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
08/03/24 19:49
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
08/03/24 19:49
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
08/03/24 19:49
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
08/03/24 19:49
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
08/03/24 19:49
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
08/03/24 19:49
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
08/03/24 19:49
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
98
%
70-130
1
08/03/24 19:49
460-00-4
1,2-Dichloroethane-d4 (S)
99
%
70-130
1
08/03/24 19:49
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
08/03/24 19:49
2037-26-5
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 67 of 107

ace
Pace Analytical Services, LLC
Padg iwyd�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
QC Batch: 2332057 Analysis Method: EPA 8260D by SIM
QC Batch Method: 8260B-SIM Analysis Description: VOA (GC/MS) 8260D-SIM
Laboratory: Pace National - Mt. Juliet
Associated Lab Samples: 92743836001, 92743836002, 92743836003, 92743836004, 92743836005, 92743836006, 92743836007,
92743836008,92743836009,92743836010,92743836011,92743836013
METHOD BLANK: R4102630-1 Matrix: Water
Associated Lab Samples: 92743836001, 92743836002, 92743836003, 92743836004, 92743836005, 92743836006, 92743836007,
92743836008,92743836009,92743836010,92743836011,92743836013
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane) mg/L ND 0.00300 0.000597 07/29/24 11:46
Toluene-d8 (S) % 95.4 77.0-127 07/29/24 11:46
LABORATORY CONTROL SAMPLE: R4102630-2
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) mg/L 0.0500 0.0428 85.6 55.0-138
Toluene-d8 (S) % 94.6 77.0-127
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC.
Page 68 of 107

ace
Pace Analytical Services, LLC
Padg"rwyd�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
QC Batch: 2335267 Analysis Method: EPA 8260D by SIM
QC Batch Method: 8260B-SIM Analysis Description: VOA (GC/MS) 8260D-SIM
Laboratory: Pace National - Mt. Juliet
Associated Lab Samples: 92743836014, 92743836015, 92743836016, 92743836017, 92743836018, 92743836019, 92743836020,
92743836021,92743836022,92743836023,92743836024,92743836025,92743836026,92743836027
METHOD BLANK: R4102618-3 Matrix: Water
Associated Lab Samples: 92743836014, 92743836015, 92743836016, 92743836017, 92743836018, 92743836019, 92743836020,
92743836021,92743836022,92743836023,92743836024,92743836025,92743836026,92743836027
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane) mg/L ND 0.00300 0.000597 08/02/24 13:43
Toluene-d8 (S) % 96.8 77.0-127 08/02/24 13:43
LABORATORY CONTROL SAMPLE & LCSD: R4102618-1
R4102618-2
Spike
LCS LCSD
LCS
LCSD
% Rec Max
Parameter Units Conc.
Result Result
% Rec
% Rec
Limits RPD RPD Qualifiers
1,4-Dioxane (p-Dioxane) mg/L 0.0500
0.0378 0.0397
75.6
79.4
55.0-138 4.90 24
Toluene-d8 (S) %
96.9
96.9
77.0-127
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 69 of 107

ace
Pace Analytical Services, LLC
Padgop1biwyd�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
QC Batch: 2336472 Analysis Method: EPA 8260D by SIM
QC Batch Method: 8260B-SIM Analysis Description: VOA (GC/MS) 8260D-SIM
Laboratory: Pace National - Mt. Juliet
Associated Lab Samples: 92743836012
METHOD BLANK: R4102811-3 Matrix: Water
Associated Lab Samples: 92743836012
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane) mg/L ND 0.00300 0.000597 08/05/24 14:25
Toluene-d8 (S) % 99.3 77.0-127 08/05/24 14:25
LABORATORY CONTROL SAMPLE & LCSD:
R4102811-1
R4102811-2
Spike
LCS LCSD
LCS LCSD
% Rec Max
Parameter
Units Conc.
Result Result
% Rec % Rec
Limits RPD RPD Qualifiers
1,4-Dioxane (p-Dioxane)
mg/L 0.0500
0.0496 0.0505
99.2 101
55.0-138 1.80 24
Toluene-d8 (S)
%
99.4 99.5
77.0-127
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC.
Page 70 of 107

ace
Pace Analytical Services, LLC
Padgop1y6fy&�.. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
QC Batch: 872095 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92743836003, 92743836004, 92743836005, 92743836006, 92743836007, 92743836009, 92743836010,
92743836011,92743836012,92743836013
METHOD BLANK: 4493320 Matrix: Water
Associated Lab Samples: 92743836003, 92743836004, 92743836005, 92743836006, 92743836007, 92743836009, 92743836010,
92743836011,92743836012,92743836013
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
08/01/24 14:19
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
08/01/24 14:19
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
08/01/24 14:19
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
08/01/24 14:19
1,1-Dichloroethane
ug/L
ND
1.0
0.37
08/01/24 14:19
1,1-Dichloroethene
ug/L
ND
1.0
0.35
08/01/24 14:19
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
08/01/24 14:19
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
08/01/24 14:19
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
08/01/24 14:19
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
08/01/24 14:19
1,2-Dichloroethane
ug/L
ND
1.0
0.32
08/01/24 14:19
1,2-Dichloropropane
ug/L
ND
1.0
0.36
08/01/24 14:19
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
08/01/24 14:19
2-Butanone (MEK)
ug/L
ND
5.0
4.0
08/01/24 14:19
2-Hexanone
ug/L
ND
5.0
0.48
08/01/24 14:19
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
08/01/24 14:19
Acetone
ug/L
ND
25.0
5.1
08/01/24 14:19
Acrylonitrile
ug/L
ND
10.0
1.8
08/01/24 14:19
Benzene
ug/L
ND
1.0
0.34
08/01/24 14:19
Bromochloromethane
ug/L
ND
1.0
0.47
08/01/24 14:19
Bromodichloromethane
ug/L
ND
1.0
0.31
08/01/24 14:19
Bromoform
ug/L
ND
1.0
0.34
08/01/24 14:19
Bromomethane
ug/L
ND
2.0
1.7
08/01/24 14:19
Carbon disulfide
ug/L
ND
2.0
0.36
08/01/24 14:19
Carbon tetrachloride
ug/L
ND
1.0
0.33
08/01/24 14:19
Chlorobenzene
ug/L
ND
1.0
0.28
08/01/24 14:19
Chloroethane
ug/L
ND
1.0
0.65
08/01/24 14:19
Chloroform
ug/L
ND
1.0
0.43
08/01/24 14:19
Chloromethane
ug/L
ND
1.0
0.54
08/01/24 14:19
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
08/01/24 14:19
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
08/01/24 14:19
Dibromochloromethane
ug/L
ND
1.0
0.36
08/01/24 14:19
Dibromomethane
ug/L
ND
1.0
0.39
08/01/24 14:19
Ethylbenzene
ug/L
ND
1.0
0.30
08/01/24 14:19
lodomethane
ug/L
ND
20.0
9.7
08/01/24 14:19 v2
Methylene Chloride
ug/L
ND
5.0
2.0
08/01/24 14:19
Styrene
ug/L
ND
1.0
0.29
08/01/24 14:19
Tetrachloroethene
ug/L
ND
1.0
0.29
08/01/24 14:19
Toluene
ug/L
ND
1.0
0.24
08/01/24 14:19
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 71 of 107

ace
Pace Analytical Services, LLC
Padgom yd�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
METHOD BLANK: 4493320 Matrix: Water
Associated Lab Samples: 92743836003, 92743836004, 92743836005, 92743836006, 92743836007, 92743836009, 92743836010,
92743836011,92743836012,92743836013
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
08/01/24 14:19
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
08/01/24 14:19
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
08/01/24 14:19 v2
Trichloroethene
ug/L
ND
1.0
0.38
08/01/24 14:19
Trichlorofluoromethane
ug/L
ND
1.0
0.30
08/01/24 14:19
Vinyl acetate
ug/L
ND
2.0
1.3
08/01/24 14:19
Vinyl chloride
ug/L
ND
1.0
0.39
08/01/24 14:19
Xylene (Total)
ug/L
ND
1.0
0.34
08/01/24 14:19
1,2-Dichloroethane-d4 (S)
%
99
70-130
08/01/24 14:19
4-Bromofluorobenzene (S)
%
100
70-130
08/01/24 14:19
Toluene-d8 (S)
%
97
70-130
08/01/24 14:19
LABORATORY CONTROL SAMPLE:
4493321
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
20
19.2
96
70-130
1,1,1-Trichloroethane
ug/L
20
17.2
86
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
19.7
99
70-130
1,1,2-Trichloroethane
ug/L
20
17.7
88
70-130
1,1-Dichloroethane
ug/L
20
17.7
88
70-130
1,1-Dichloroethene
ug/L
20
16.5
83
69-131
1,2,3-Trichloropropane
ug/L
20
19.7
98
70-130
1,2-Dibromo-3-chloropropane
ug/L
20
20.1
100
70-130
1,2-Dibromoethane (EDB)
ug/L
20
18.7
94
70-130
1,2-Dichlorobenzene
ug/L
20
20.6
103
70-130
1,2-Dichloroethane
ug/L
20
18.7
93
70-130
1,2-Dichloropropane
ug/L
20
18.0
90
70-130
1,4-Dichlorobenzene
ug/L
20
20.9
104
70-130
2-Butanone (MEK)
ug/L
40
35.5
89
67-133
2-Hexanone
ug/L
40
40.9
102
70-133
4-Methyl-2-pentanone (MIBK)
ug/L
40
37.3
93
70-130
Acetone
ug/L
40
38.0
95
67-130
Acrylonitrile
ug/L
100
83.9
84
70-130
Benzene
ug/L
20
18.4
92
70-130
Bromochloromethane
ug/L
20
18.8
94
70-130
Bromodichloromethane
ug/L
20
17.3
86
70-130
Bromoform
ug/L
20
18.0
90
70-133
Bromomethane
ug/L
20
15.8
79
41-148
Carbon disulfide
ug/L
20
18.1
90
70-131
Carbon tetrachloride
ug/L
20
17.7
88
70-130
Chlorobenzene
ug/L
20
20.2
101
70-130
Chloroethane
ug/L
20
14.9
74
41-157
Chloroform
ug/L
20
18.2
91
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 72 of 107

ace
Pace Analytical Services, LLC
Padgop1ls�yd�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
LABORATORY CONTROL SAMPLE:
Parameter
4493321
Units
Spike LCS
Conc. Result
Chloromethane
ug/L
20
cis-1,2-Dichloroethene
ug/L
20
cis-1,3-Dichloropropene
ug/L
20
Dibromochloromethane
ug/L
20
Dibromomethane
ug/L
20
Ethylbenzene
ug/L
20
lodomethane
ug/L
40
Methylene Chloride
ug/L
20
Styrene
ug/L
20
Tetrachloroethene
ug/L
20
Toluene
ug/L
20
trans-1,2-Dichloroethene
ug/L
20
trans- 1,3-Dichloropropene
ug/L
20
trans-1,4-Dichloro-2-butene
ug/L
20
Trichloroethene
ug/L
20
Trichlorofluoromethane
ug/L
20
Vinyl acetate
ug/L
40
Vinyl chloride
ug/L
20
Xylene (Total)
ug/L
60
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
LCS
% Rec
% Rec
Limits Qualifiers
16.4
82
59-141
17.9
90
70-130
18.4
92
70-130
18.6
93
70-130
19.2
96
70-130
19.6
98
70-130
32.4
81
57-140 v3
16.7
84
62-130
19.7
98
70-130
17.6
88
70-130
18.5
93
70-130
17.2
86
70-130
19.9
99
70-130
14.5
72
57-149 v3
19.5
97
70-130
15.6
78
57-130
37.1
93
70-141
15.7
78
66-140
58.2
97
70-130
94
70-130
98
70-130
96
70-130
MATRIX SPIKE SAMPLE:
Parameter
4493322
Units
92743805012
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
24.2
121
70-146
1,1,1-Trichloroethane
ug/L
ND
20
23.5
118
70-150
1,1,2,2-Tetrachloroethane
ug/L
ND
20
23.7
118
66-144
1,1,2-Trichloroethane
ug/L
ND
20
21.2
106
70-142
1,1-Dichloroethane
ug/L
ND
20
23.5
117
68-150
1,1-Dichloroethene
ug/L
ND
20
23.2
116
64-162
1,2,3-Trichloropropane
ug/L
ND
20
23.7
118
66-144
1,2-Dibromo-3-chloropropane
ug/L
ND
20
22.2
111
62-146
1,2-Dibromoethane (EDB)
ug/L
ND
20
23.5
118
70-143
1,2-Dichlorobenzene
ug/L
ND
20
24.3
122
70-142
1,2-Dichloroethane
ug/L
ND
20
23.5
117
68-145
1,2-Dichloropropane
ug/L
ND
20
22.9
115
70-144
1,4-Dichlorobenzene
ug/L
ND
20
24.7
123
70-140
2-Butanone (MEK)
ug/L
ND
40
44.1
110
57-156
2-Hexanone
ug/L
ND
40
48.8
122
62-153
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
45.6
114
65-144
Acetone
ug/L
ND
40
43.4
108
49-162
Acrylonitrile
ug/L
ND
100
99.8
100
59-155
Benzene
ug/L
ND
20
23.6
118
68-144
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 73 of 107

ace
Pace Analytical Services, LLC
Pad8opoirwYd�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
MATRIX SPIKE SAMPLE:
4493322
92743805012
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Bromochloromethane
ug/L
ND
20
24.0
120
70-148
Bromodichloromethane
ug/L
ND
20
22.5
112
70-141
Bromoform
ug/L
ND
20
22.1
110
59-144
Bromomethane
ug/L
ND
20
17.7
89
23-190 v3
Carbon disulfide
ug/L
ND
20
23.5
117
64-160
Carbon tetrachloride
ug/L
ND
20
23.8
119
70-147
Chlorobenzene
ug/L
ND
20
25.0
125
70-143
Chloroethane
ug/L
ND
20
20.4
102
55-190
Chloroform
ug/L
ND
20
23.1
115
67-148
Chloromethane
ug/L
ND
20
22.2
111
38-180
cis-1,2-Dichloroethene
ug/L
ND
20
22.5
113
67-151
cis-1,3-Dichloropropene
ug/L
ND
20
23.8
119
70-142
Dibromochloromethane
ug/L
ND
20
23.4
117
68-140
Dibromomethane
ug/L
ND
20
22.8
114
70-142
Ethylbenzene
ug/L
ND
20
25.0
125
70-145
lodomethane
ug/L
ND
40
44.3
111
37-160 v3
Methylene Chloride
ug/L
ND
20
21.4
107
54-149
Styrene
ug/L
ND
20
24.4
122
70-147
Tetrachloroethene
ug/L
ND
20
23.0
115
70-145
Toluene
ug/L
ND
20
23.4
117
65-146
trans-1,2-Dichloroethene
ug/L
ND
20
23.3
117
69-155
trans- 1,3-Dichloropropene
ug/L
ND
20
23.8
119
70-142
trans-1,4-Dichloro-2-butene
ug/L
ND
20
15.8
79
39-149 v3
Trichloroethene
ug/L
ND
20
24.7
123
70-152
Trichlorofluoromethane
ug/L
ND
20
21.9
109
60-158
Vinyl acetate
ug/L
ND
40
44.8
112
56-157
Vinyl chloride
ug/L
ND
20
22.0
110
51-178
Xylene (Total)
ug/L
ND
60
73.8
123
70-146
1,2-Dichloroethane-d4 (S)
%
100
70-130
4-Bromofluorobenzene (S)
%
102
70-130
Toluene-d8 (S)
%
98
70-130
SAMPLE DUPLICATE: 4493323
Parameter
Units
92743805013
Result
Dup
Result RPD
Max
RPD Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,1-Trichloroethane
ug/L
ND
ND
30
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,2-Trichloroethane
ug/L
ND
ND
30
1,1-Dichloroethane
ug/L
1.8
1.8 3
30
1,1-Dichloroethene
ug/L
ND
0.71J
30
1,2,3-Trichloropropane
ug/L
ND
ND
30
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
30
1,2-Dibromoethane (EDB)
ug/L
ND
ND
30
1,2-Dichlorobenzene
ug/L
ND
ND
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC.
Page 74 of 107

ace
Pace Analytical Services, LLC
Padgom yd�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
SAMPLE DUPLICATE: 4493323
Parameter
Units
92743805013
Result
Dup
Result RPD
Max
RPD
1,2-Dichloroethane
ug/L
ND
ND
30
1,2-Dichloropropane
ug/L
ND
ND
30
1,4-Dichlorobenzene
ug/L
ND
ND
30
2-Butanone (MEK)
ug/L
ND
ND
30
2-Hexanone
ug/L
ND
ND
30
4-Methyl-2-pentanone (MIBK)
ug/L
ND
ND
30
Acetone
ug/L
ND
ND
30
Acrylonitrile
ug/L
ND
ND
30
Benzene
ug/L
ND
ND
30
Bromochloromethane
ug/L
ND
ND
30
Bromodichloromethane
ug/L
ND
ND
30
Bromoform
ug/L
ND
ND
30
Bromomethane
ug/L
ND
ND
30 v2
Carbon disulfide
ug/L
ND
ND
30
Carbon tetrachloride
ug/L
ND
ND
30
Chlorobenzene
ug/L
ND
ND
30
Chloroethane
ug/L
ND
ND
30
Chloroform
ug/L
ND
ND
30
Chloromethane
ug/L
ND
ND
30
cis-1,2-Dichloroethene
ug/L
ND
ND
30
cis-1,3-Dichloropropene
ug/L
ND
ND
30
Dibromochloromethane
ug/L
ND
ND
30
Dibromomethane
ug/L
ND
ND
30
Ethylbenzene
ug/L
ND
ND
30
lodomethane
ug/L
ND
ND
30 v2
Methylene Chloride
ug/L
ND
ND
30
Styrene
ug/L
ND
ND
30
Tetrachloroethene
ug/L
ND
ND
30
Toluene
ug/L
ND
ND
30
trans-1,2-Dichloroethene
ug/L
ND
ND
30
trans- 1,3-Dichloropropene
ug/L
ND
ND
30
trans-1,4-Dichloro-2-butene
ug/L
ND
ND
30 v2
Trichloroethene
ug/L
ND
ND
30
Trichlorofluoromethane
ug/L
ND
ND
30
Vinyl acetate
ug/L
ND
ND
30
Vinyl chloride
ug/L
ND
ND
30
Xylene (Total)
ug/L
ND
ND
30
1,2-Dichloroethane-d4 (S)
%
100
98
4-Bromofluorobenzene (S)
%
100
97
Toluene-d8 (S)
%
97
99
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC.
Page 75 of 107

ace
Pace Analytical Services, LLC
Padgop* yd�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
QC Batch: 872357 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92743836016, 92743836017, 92743836019, 92743836021, 92743836022, 92743836024
METHOD BLANK: 4494341 Matrix: Water
Associated Lab Samples: 92743836016, 92743836017, 92743836019, 92743836021, 92743836022, 92743836024
Blank Reporting
Parameter Units Result Limit MDL Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
08/01/24 01:35
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
08/01/24 01:35
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
08/01/24 01:35
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
08/01/24 01:35
1,1-Dichloroethane
ug/L
ND
1.0
0.37
08/01/24 01:35
1,1-Dichloroethene
ug/L
ND
1.0
0.35
08/01/24 01:35
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
08/01/24 01:35
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
08/01/24 01:35
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
08/01/24 01:35
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
08/01/24 01:35
1,2-Dichloroethane
ug/L
ND
1.0
0.32
08/01/24 01:35
1,2-Dichloropropane
ug/L
ND
1.0
0.36
08/01/24 01:35
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
08/01/24 01:35
2-Butanone (MEK)
ug/L
ND
5.0
4.0
08/01/24 01:35
2-Hexanone
ug/L
ND
5.0
0.48
08/01/24 01:35
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
08/01/24 01:35
Acetone
ug/L
ND
25.0
5.1
08/01/24 01:35
Acrylonitrile
ug/L
ND
10.0
1.8
08/01/24 01:35
Benzene
ug/L
ND
1.0
0.34
08/01/24 01:35
Bromochloromethane
ug/L
ND
1.0
0.47
08/01/24 01:35
Bromodichloromethane
ug/L
ND
1.0
0.31
08/01/24 01:35
Bromoform
ug/L
ND
1.0
0.34
08/01/24 01:35
Bromomethane
ug/L
ND
2.0
1.7
08/01/24 01:35
Carbon disulfide
ug/L
ND
2.0
0.36
08/01/24 01:35
Carbon tetrachloride
ug/L
ND
1.0
0.33
08/01/24 01:35
Chlorobenzene
ug/L
ND
1.0
0.28
08/01/24 01:35
Chloroethane
ug/L
ND
1.0
0.65
08/01/24 01:35
Chloroform
ug/L
ND
1.0
0.43
08/01/24 01:35
Chloromethane
ug/L
ND
1.0
0.54
08/01/24 01:35
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
08/01/24 01:35
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
08/01/24 01:35
Dibromochloromethane
ug/L
ND
1.0
0.36
08/01/24 01:35
Dibromomethane
ug/L
ND
1.0
0.39
08/01/24 01:35
Ethylbenzene
ug/L
ND
1.0
0.30
08/01/24 01:35
lodomethane
ug/L
ND
20.0
9.7
08/01/24 01:35
Methylene Chloride
ug/L
2.9J
5.0
2.0
08/01/24 01:35
Styrene
ug/L
ND
1.0
0.29
08/01/24 01:35
Tetrachloroethene
ug/L
ND
1.0
0.29
08/01/24 01:35
Toluene
ug/L
ND
1.0
0.24
08/01/24 01:35
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
08/01/24 01:35
Qualifiers
C9,v1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 76 of 107

ace
Pace Analytical Services, LLC
Padgom yd�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
METHOD BLANK: 4494341 Matrix: Water
Associated Lab Samples: 92743836016, 92743836017, 92743836019, 92743836021, 92743836022, 92743836024
Blank Reporting
Parameter Units Result Limit MDL Analyzed
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
08/01/24 01:35
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
08/01/24 01:35
Trichloroethene
ug/L
ND
1.0
0.38
08/01/24 01:35
Trichlorofluoromethane
ug/L
ND
1.0
0.30
08/01/24 01:35
Vinyl acetate
ug/L
ND
2.0
1.3
08/01/24 01:35
Vinyl chloride
ug/L
ND
1.0
0.39
08/01/24 01:35
Xylene (Total)
ug/L
ND
1.0
0.34
08/01/24 01:35
1,2-Dichloroethane-d4 (S)
%
100
70-130
08/01/24 01:35
4-Bromofluorobenzene (S)
%
97
70-130
08/01/24 01:35
Toluene-d8 (S)
%
100
70-130
08/01/24 01:35
LABORATORY CONTROL SAMPLE:
Parameter
4494342
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1,2-Tetrachloroethane
ug/L
20
20.9
104
70-130
1,1,1-Trichloroethane
ug/L
20
21.2
106
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
21.6
108
70-130
1,1,2-Trichloroethane
ug/L
20
21.4
107
70-130
1,1-Dichloroethane
ug/L
20
21.4
107
70-130
1,1-Dichloroethene
ug/L
20
22.2
111
69-131
1,2,3-Trichloropropane
ug/L
20
22.0
110
70-130
1,2-Dibromo-3-chloropropane
ug/L
20
21.8
109
70-130
1,2-Dibromoethane (EDB)
ug/L
20
21.9
109
70-130
1,2-Dichlorobenzene
ug/L
20
21.6
108
70-130
1,2-Dichloroethane
ug/L
20
21.6
108
70-130
1,2-Dichloropropane
ug/L
20
21.5
108
70-130
1,4-Dichlorobenzene
ug/L
20
21.2
106
70-130
2-Butanone (MEK)
ug/L
40
43.0
108
67-133
2-Hexanone
ug/L
40
44.3
111
70-133
4-Methyl-2-pentanone (MIBK)
ug/L
40
42.4
106
70-130
Acetone
ug/L
40
43.9
110
67-130
Acrylonitrile
ug/L
100
98.5
99
70-130
Benzene
ug/L
20
21.7
108
70-130
Bromochloromethane
ug/L
20
21.4
107
70-130
Bromodichloromethane
ug/L
20
21.0
105
70-130
Bromoform
ug/L
20
20.2
101
70-133
Bromomethane
ug/L
20
20.2
101
41-148
Carbon disulfide
ug/L
20
21.8
109
70-131
Carbon tetrachloride
ug/L
20
20.9
105
70-130
Chlorobenzene
ug/L
20
21.7
109
70-130
Chloroethane
ug/L
20
19.2
96
41-157
Chloroform
ug/L
20
21.0
105
70-130
Chloromethane
ug/L
20
23.9
119
59-141
cis-1,2-Dichloroethene
ug/L
20
21.0
105
70-130
Qualifiers
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 77 of 107

Pace Analytical Services, LLC
ace-
^ Padgom yd�e. Suite 100
ae - Huntersville, NC 28078
�.+f LJ [phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
LABORATORY CONTROL SAMPLE:
Parameter
4494342
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
cis-1,3-Dichloropropene
ug/L
20
20.7
104
70-130
Dibromochloromethane
ug/L
20
21.0
105
70-130
Dibromomethane
ug/L
20
21.3
107
70-130
Ethylbenzene
ug/L
20
21.7
109
70-130
lodomethane
ug/L
40
40.7
102
57-140
Methylene Chloride
ug/L
20
52.2
261
62-130 L1,v1
Styrene
ug/L
20
21.3
107
70-130
Tetrachloroethene
ug/L
20
20.2
101
70-130
Toluene
ug/L
20
21.4
107
70-130
trans-1,2-Dichloroethene
ug/L
20
21.6
108
70-130
trans- 1,3-Dichloropropene
ug/L
20
20.9
105
70-130
trans-1,4-Dichloro-2-butene
ug/L
20
14.6
73
57-149
Trichloroethene
ug/L
20
22.1
110
70-130
Trichlorofluoromethane
ug/L
20
19.7
99
57-130
Vinyl acetate
ug/L
40
44.6
111
70-141
Vinyl chloride
ug/L
20
21.4
107
66-140
Xylene (Total)
ug/L
60
64.7
108
70-130
1,2-Dichloroethane-d4 (S)
%
102
70-130
4-Bromofluorobenzene (S)
%
102
70-130
Toluene-d8 (S)
%
99
70-130
MATRIX SPIKE SAMPLE:
Parameter
4494343
Units
92743836019
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
22.2
111
70-146
1,1,1-Trichloroethane
ug/L
ND
20
24.1
121
70-150
1,1,2,2-Tetrachloroethane
ug/L
ND
20
23.3
117
66-144
1,1,2-Trichloroethane
ug/L
ND
20
23.2
116
70-142
1,1-Dichloroethane
ug/L
1.1
20
25.4
121
68-150
1,1-Dichloroethene
ug/L
ND
20
26.6
132
64-162
1,2,3-Trichloropropane
ug/L
ND
20
23.4
117
66-144
1,2-Dibromo-3-chloropropane
ug/L
ND
20
22.9
115
62-146
1,2-Dibromoethane (EDB)
ug/L
ND
20
23.1
116
70-143
1,2-Dichlorobenzene
ug/L
ND
20
23.3
116
70-142
1,2-Dichloroethane
ug/L
ND
20
24.1
121
68-145
1,2-Dichloropropene
ug/L
ND
20
23.6
118
70-144
1,4-Dichlorobenzene
ug/L
ND
20
23.6
118
70-140
2-Butanone (MEK)
ug/L
ND
40
49.3
123
57-156
2-Hexanone
ug/L
ND
40
46.6
116
62-153
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
46.7
117
65-144
Acetone
ug/L
ND
40
46.6
117
49-162
Acrylonitrile
ug/L
ND
100
107
107
59-155
Benzene
ug/L
0.47J
20
24.4
120
68-144
Bromochloromethane
ug/L
ND
20
23.2
116
70-148
Bromodichloromethane
ug/L
ND
20
22.6
113
70-141
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 78 of 107

ace
Pace Analytical Services, LLC
Padgom yd�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
MATRIX SPIKE SAMPLE:
Parameter
4494343
Units
92743836019
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
Bromoform
ug/L
ND
20
21.4
107
59-144
Bromomethane
ug/L
ND
20
20.8
104
23-190
Carbon disulfide
ug/L
ND
20
25.3
126
64-160
Carbon tetrachloride
ug/L
ND
20
24.3
122
70-147
Chlorobenzene
ug/L
ND
20
23.8
119
70-143
Chloroethane
ug/L
ND
20
22.2
111
55-190
Chloroform
ug/L
ND
20
23.9
120
67-148
Chloromethane
ug/L
ND
20
24.8
124
38-180
cis-1,2-Dichloroethene
ug/L
7.9
20
30.9
115
67-151
cis-1,3-Dichloropropene
ug/L
ND
20
22.7
114
70-142
Dibromochloromethane
ug/L
ND
20
21.7
109
68-140
Dibromomethane
ug/L
ND
20
23.3
116
70-142
Ethylbenzene
ug/L
ND
20
23.6
118
70-145
lodomethane
ug/L
ND
40
33.6
83
37-160 v3
Methylene Chloride
ug/L
19.1
20
40.8
109
54-149
Styrene
ug/L
ND
20
23.6
118
70-147
Tetrachloroethene
ug/L
0.891
20
24.0
116
70-145
Toluene
ug/L
ND
20
24.0
119
65-146
trans-1,2-Dichloroethene
ug/L
ND
20
24.2
121
69-155
trans- 1,3-Dichloropropene
ug/L
ND
20
23.6
118
70-142
trans-1,4-Dichloro-2-butene
ug/L
ND
20
13.4
67
39-149
Trichloroethene
ug/L
2.6
20
27.8
126
70-152
Trichlorofluoromethane
ug/L
0.32J
20
26.1
129
60-158
Vinyl acetate
ug/L
ND
40
47.3
118
56-157
Vinyl chloride
ug/L
ND
20
23.4
117
51-178
Xylene (Total)
ug/L
115
60
187
120
70-146
1,2-Dichloroethane-d4 (S)
%
103
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
99
70-130
SAMPLE DUPLICATE: 4494344
Parameter
Units
92743836024
Result
Dup
Result RPD
Max
RPD Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,1-Trichloroethane
ug/L
ND
ND
30
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,2-Trichloroethane
ug/L
ND
ND
30
1,1-Dichloroethane
ug/L
ND
ND
30
1,1-Dichloroethene
ug/L
ND
ND
30
1,2,3-Trichloropropane
ug/L
ND
ND
30
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
30
1,2-Dibromoethane (EDB)
ug/L
ND
ND
30
1,2-Dichlorobenzene
ug/L
ND
ND
30
1,2-Dichloroethane
ug/L
ND
ND
30
1,2-Dichloropropene
ug/L
ND
ND
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC.
Page 79 of 107

ace
Pace Analytical Services, LLC
Padgap)aiwyd�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
SAMPLE DUPLICATE: 4494344
Parameter
Units
92743836024
Result
Dup
Result RPD
Max
RPD
1,4-Dichlorobenzene
ug/L
ND
ND
30
2-Butanone (MEK)
ug/L
ND
ND
30
2-Hexanone
ug/L
ND
ND
30
4-Methyl-2-pentanone (MIBK)
ug/L
ND
ND
30
Acetone
ug/L
ND
ND
30
Acrylonitrile
ug/L
ND
ND
30
Benzene
ug/L
ND
ND
30
Bromochloromethane
ug/L
ND
ND
30
Bromodichloromethane
ug/L
ND
ND
30
Bromoform
ug/L
ND
ND
30
Bromomethane
ug/L
ND
ND
30
Carbon disulfide
ug/L
ND
ND
30
Carbon tetrachloride
ug/L
ND
ND
30
Chlorobenzene
ug/L
ND
ND
30
Chloroethane
ug/L
ND
ND
30
Chloroform
ug/L
ND
ND
30
Chloromethane
ug/L
ND
ND
30
cis-1,2-Dichloroethene
ug/L
ND
ND
30
cis-1,3-Dichloropropene
ug/L
ND
ND
30
Dibromochloromethane
ug/L
ND
ND
30
Dibromomethane
ug/L
ND
ND
30
Ethylbenzene
ug/L
ND
ND
30
lodomethane
ug/L
ND
ND
30 v2
Methylene Chloride
ug/L
ND
ND
30
Styrene
ug/L
ND
ND
30
Tetrachloroethene
ug/L
ND
ND
30
Toluene
ug/L
ND
ND
30
trans-1,2-Dichloroethene
ug/L
ND
ND
30
trans- 1,3-Dichloropropene
ug/L
ND
ND
30
trans-1,4-Dichloro-2-butene
ug/L
ND
ND
30
Trichloroethene
ug/L
ND
ND
30
Trichlorofluoromethane
ug/L
ND
ND
30
Vinyl acetate
ug/L
ND
ND
30
Vinyl chloride
ug/L
ND
ND
30
Xylene (Total)
ug/L
ND
ND
30
1,2-Dichloroethane-d4 (S)
%
98
100
4-Bromofluorobenzene (S)
%
94
96
Toluene-d8 (S)
%
100
100
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC.
Page 80 of 107

ace
Pace Analytical Services, LLC
Padg"lirpy&�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
QC Batch: 872652 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92743836001, 92743836002, 92743836018, 92743836020, 92743836023
METHOD BLANK: 4495789 Matrix: Water
Associated Lab Samples: 92743836001, 92743836002, 92743836018, 92743836020, 92743836023
Blank Reporting
Parameter Units Result Limit MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
08/01/24 22:34
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
08/01/24 22:34
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
08/01/24 22:34
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
08/01/24 22:34
1,1-Dichloroethane
ug/L
ND
1.0
0.37
08/01/24 22:34
1,1-Dichloroethene
ug/L
ND
1.0
0.35
08/01/24 22:34
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
08/01/24 22:34
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
08/01/24 22:34
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
08/01/24 22:34
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
08/01/24 22:34
1,2-Dichloroethane
ug/L
ND
1.0
0.32
08/01/24 22:34
1,2-Dichloropropane
ug/L
ND
1.0
0.36
08/01/24 22:34
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
08/01/24 22:34
2-Butanone (MEK)
ug/L
ND
5.0
4.0
08/01/24 22:34
2-Hexanone
ug/L
ND
5.0
0.48
08/01/24 22:34
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
08/01/24 22:34
Acetone
ug/L
ND
25.0
5.1
08/01/24 22:34
Acrylonitrile
ug/L
ND
10.0
1.8
08/01/24 22:34
Benzene
ug/L
ND
1.0
0.34
08/01/24 22:34
Bromochloromethane
ug/L
ND
1.0
0.47
08/01/24 22:34
Bromodichloromethane
ug/L
ND
1.0
0.31
08/01/24 22:34
Bromoform
ug/L
ND
1.0
0.34
08/01/24 22:34
Bromomethane
ug/L
ND
2.0
1.7
08/01/24 22:34
Carbon disulfide
ug/L
ND
2.0
0.36
08/01/24 22:34
Carbon tetrachloride
ug/L
ND
1.0
0.33
08/01/24 22:34
Chlorobenzene
ug/L
ND
1.0
0.28
08/01/24 22:34
Chloroethane
ug/L
ND
1.0
0.65
08/01/24 22:34
Chloroform
ug/L
ND
1.0
0.43
08/01/24 22:34
Chloromethane
ug/L
ND
1.0
0.54
08/01/24 22:34
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
08/01/24 22:34
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
08/01/24 22:34
Dibromochloromethane
ug/L
ND
1.0
0.36
08/01/24 22:34
Dibromomethane
ug/L
ND
1.0
0.39
08/01/24 22:34
Ethylbenzene
ug/L
ND
1.0
0.30
08/01/24 22:34
lodomethane
ug/L
ND
20.0
9.7
08/01/24 22:34
Methylene Chloride
ug/L
ND
5.0
2.0
08/01/24 22:34
Styrene
ug/L
ND
1.0
0.29
08/01/24 22:34
Tetrachloroethene
ug/L
ND
1.0
0.29
08/01/24 22:34
Toluene
ug/L
ND
1.0
0.24
08/01/24 22:34
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
08/01/24 22:34
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 81 of 107

ace
Pace Analytical Services, LLC
Padg"rwyd�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
METHOD BLANK: 4495789 Matrix: Water
Associated Lab Samples: 92743836001, 92743836002, 92743836018, 92743836020, 92743836023
Blank Reporting
Parameter Units Result Limit MDL
Analyzed
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
08/01/24 22:34
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
08/01/24 22:34
Trichloroethene
ug/L
ND
1.0
0.38
08/01/24 22:34
Trichlorofluoromethane
ug/L
ND
1.0
0.30
08/01/24 22:34
Vinyl acetate
ug/L
ND
2.0
1.3
08/01/24 22:34
Vinyl chloride
ug/L
ND
1.0
0.39
08/01/24 22:34
Xylene (Total)
ug/L
ND
1.0
0.34
08/01/24 22:34
1,2-Dichloroethane-d4 (S)
%
95
70-130
08/01/24 22:34
4-Bromofluorobenzene (S)
%
99
70-130
08/01/24 22:34
Toluene-d8 (S)
%
100
70-130
08/01/24 22:34
LABORATORY CONTROL SAMPLE:
Parameter
4495790
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1,2-Tetrachloroethane
ug/L
20
18.6
93
70-130
1,1,1-Trichloroethane
ug/L
20
18.7
93
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
17.6
88
70-130
1,1,2-Trichloroethane
ug/L
20
18.2
91
70-130
1,1-Dichloroethane
ug/L
20
19.6
98
70-130
1,1-Dichloroethene
ug/L
20
19.1
95
69-131
1,2,3-Trichloropropane
ug/L
20
17.9
89
70-130
1,2-Dibromo-3-chloropropane
ug/L
20
20.2
101
70-130
1,2-Dibromoethane (EDB)
ug/L
20
18.2
91
70-130
1,2-Dichlorobenzene
ug/L
20
18.7
94
70-130
1,2-Dichloroethane
ug/L
20
20.0
100
70-130
1,2-Dichloropropane
ug/L
20
18.4
92
70-130
1,4-Dichlorobenzene
ug/L
20
18.3
91
70-130
2-Butanone (MEK)
ug/L
40
37.0
93
67-133
2-Hexanone
ug/L
40
38.0
95
70-133
4-Methyl-2-pentanone (MIBK)
ug/L
40
37.5
94
70-130
Acetone
ug/L
40
38.3
96
67-130
Acrylonitrile
ug/L
100
101
101
70-130
Benzene
ug/L
20
19.3
97
70-130
Bromochloromethane
ug/L
20
20.5
102
70-130
Bromodichloromethane
ug/L
20
17.8
89
70-130
Bromoform
ug/L
20
16.3
81
70-133
Bromomethane
ug/L
20
15.0
75
41-148
Carbon disulfide
ug/L
20
14.7
73
70-131
Carbon tetrachloride
ug/L
20
17.0
85
70-130
Chlorobenzene
ug/L
20
18.8
94
70-130
Chloroethane
ug/L
20
14.2
71
41-157
Chloroform
ug/L
20
18.0
90
70-130
Chloromethane
ug/L
20
17.6
88
59-141
cis-1,2-Dichloroethene
ug/L
20
19.1
96
70-130
Qualifiers
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 82 of 107

ace
Pace Analytical Services, LLC
Padg iwYd�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
LABORATORY CONTROL SAMPLE:
4495790
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
cis-1,3-Dichloropropene
ug/L
20
18.0
90
70-130
Dibromochloromethane
ug/L
20
17.6
88
70-130
Dibromomethane
ug/L
20
19.9
100
70-130
Ethylbenzene
ug/L
20
17.7
89
70-130
lodomethane
ug/L
40
33.9
85
57-140
Methylene Chloride
ug/L
20
20.5
102
62-130
Styrene
ug/L
20
18.9
95
70-130
Tetrachloroethene
ug/L
20
17.2
86
70-130
Toluene
ug/L
20
18.7
94
70-130
trans-1,2-Dichloroethene
ug/L
20
19.8
99
70-130
trans- 1,3-Dichloropropene
ug/L
20
18.3
91
70-130
trans-1,4-Dichloro-2-butene
ug/L
20
21.2
106
57-149
Trichloroethene
ug/L
20
18.7
93
70-130
Trichlorofluoromethane
ug/L
20
15.7
78
57-130
Vinyl acetate
ug/L
40
38.7
97
70-141
Vinyl chloride
ug/L
20
16.9
85
66-140
Xylene (Total)
ug/L
60
53.8
90
70-130
1,2-Dichloroethane-d4 (S)
%
98
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
96
70-130
MATRIX SPIKE SAMPLE:
4495791
92744559002
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
24.9
124
70-146
1,1,1-Trichloroethane
ug/L
ND
20
24.4
122
70-150
1,1,2,2-Tetrachloroethane
ug/L
ND
20
23.3
116
66-144
1,1,2-Trichloroethane
ug/L
ND
20
23.8
119
70-142
1,1-Dichloroethane
ug/L
ND
20
23.5
117
68-150
1,1-Dichloroethene
ug/L
ND
20
23.9
119
64-162
1,2,3-Trichloropropane
ug/L
ND
20
22.7
114
66-144
1,2-Dibromo-3-chloropropane
ug/L
ND
20
23.4
117
62-146
1,2-Dibromoethane (EDB)
ug/L
ND
20
24.6
123
70-143
1,2-Dichlorobenzene
ug/L
ND
20
23.3
117
70-142
1,2-Dichloroethane
ug/L
ND
20
21.5
107
68-145
1,2-Dichloropropene
ug/L
ND
20
23.7
119
70-144
1,4-Dichlorobenzene
ug/L
ND
20
22.9
114
70-140
2-Butanone (MEK)
ug/L
ND
40
44.2
110
57-156
2-Hexanone
ug/L
ND
40
47.6
119
62-153
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
45.3
113
65-144
Acetone
ug/L
ND
40
37.4
94
49-162 v3
Acrylonitrile
ug/L
ND
100
118
118
59-155
Benzene
ug/L
ND
20
24.8
124
68-144
Bromochloromethane
ug/L
ND
20
24.5
123
70-148
Bromodichloromethane
ug/L
ND
20
24.5
123
70-141
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 83 of 107

ace
Pace Analytical Services, LLC
Padfftirwyd�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
MATRIX SPIKE SAMPLE:
Parameter
4495791
Units
92744559002
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
Bromoform
ug/L
ND
20
24.8
124
59-144
Bromomethane
ug/L
ND
20
15.2
76
23-190 v3
Carbon disulfide
ug/L
ND
20
22.4
112
64-160
Carbon tetrachloride
ug/L
ND
20
24.5
123
70-147
Chlorobenzene
ug/L
ND
20
24.5
122
70-143
Chloroethane
ug/L
ND
20
20.9
105
55-190 v3
Chloroform
ug/L
ND
20
22.8
114
67-148
Chloromethane
ug/L
ND
20
22.6
113
38-180
cis-1,2-Dichloroethene
ug/L
ND
20
23.6
118
67-151
cis-1,3-Dichloropropene
ug/L
ND
20
24.3
121
70-142
Dibromochloromethane
ug/L
ND
20
25.0
125
68-140
Dibromomethane
ug/L
ND
20
24.3
121
70-142
Ethylbenzene
ug/L
ND
20
25.0
125
70-145
lodomethane
ug/L
ND
40
38.4
96
37-160
Methylene Chloride
ug/L
ND
20
20.4
102
54-149 v3
Styrene
ug/L
ND
20
25.7
129
70-147
Tetrachloroethene
ug/L
ND
20
25.4
127
70-145
Toluene
ug/L
ND
20
24.5
123
65-146
trans-1,2-Dichloroethene
ug/L
ND
20
24.5
122
69-155
trans- 1,3-Dichloropropene
ug/L
ND
20
24.0
120
70-142
trans-1,4-Dichloro-2-butene
ug/L
ND
20
22.5
113
39-149
Trichloroethene
ug/L
ND
20
25.6
128
70-152
Trichlorofluoromethane
ug/L
ND
20
22.6
113
60-158
Vinyl acetate
ug/L
ND
40
43.7
109
56-157
Vinyl chloride
ug/L
ND
20
22.4
112
51-178
Xylene (Total)
ug/L
ND
60
76.8
128
70-146
1,2-Dichloroethane-d4 (S)
%
88
70-130
4-Bromofluorobenzene (S)
%
101
70-130
Toluene-d8 (S)
%
97
70-130
SAMPLE DUPLICATE: 4495792
Parameter
Units
92743836020
Result
Dup
Result RPD
Max
RPD Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,1-Trichloroethane
ug/L
ND
ND
30
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,2-Trichloroethane
ug/L
ND
ND
30
1,1-Dichloroethane
ug/L
0.41J
ND
30
1,1-Dichloroethene
ug/L
ND
ND
30
1,2,3-Trichloropropane
ug/L
ND
ND
30
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
30
1,2-Dibromoethane (EDB)
ug/L
ND
ND
30
1,2-Dichlorobenzene
ug/L
ND
ND
30
1,2-Dichloroethane
ug/L
ND
ND
30
1,2-Dichloropropene
ug/L
ND
ND
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC.
Page 84 of 107

ace
Pace Analytical Services, LLC
Padg"ifyd�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
SAMPLE DUPLICATE: 4495792
Parameter
Units
92743836020
Result
Dup
Result
1,4-Dichlorobenzene
ug/L
ND
ND
2-Butanone (MEK)
ug/L
ND
ND
2-Hexanone
ug/L
ND
ND
4-Methyl-2-pentanone (MIBK)
ug/L
ND
ND
Acetone
ug/L
ND
ND
Acrylonitrile
ug/L
ND
ND
Benzene
ug/L
ND
ND
Bromochloromethane
ug/L
ND
ND
Bromodichloromethane
ug/L
ND
ND
Bromoform
ug/L
ND
ND
Bromomethane
ug/L
ND
ND
Carbon disulfide
ug/L
ND
ND
Carbon tetrachloride
ug/L
ND
ND
Chlorobenzene
ug/L
ND
ND
Chloroethane
ug/L
ND
ND
Chloroform
ug/L
ND
ND
Chloromethane
ug/L
ND
ND
cis-1,2-Dichloroethene
ug/L
1.9
1.9
cis-1,3-Dichloropropene
ug/L
ND
ND
Dibromochloromethane
ug/L
ND
ND
Dibromomethane
ug/L
ND
ND
Ethylbenzene
ug/L
ND
ND
lodomethane
ug/L
ND
ND
Methylene Chloride
ug/L
ND
ND
Styrene
ug/L
ND
ND
Tetrachloroethene
ug/L
ND
ND
Toluene
ug/L
ND
ND
trans-1,2-Dichloroethene
ug/L
ND
ND
trans- 1,3-Dichloropropene
ug/L
ND
ND
trans-1,4-Dichloro-2-butene
ug/L
ND
ND
Trichloroethene
ug/L
0.82J
0.911
Trichlorofluoromethane
ug/L
ND
ND
Vinyl acetate
ug/L
ND
ND
Vinyl chloride
ug/L
ND
ND
Xylene (Total)
ug/L
ND
ND
1,2-Dichloroethane-d4 (S)
%
96
87
4-Bromofluorobenzene (S)
%
100
93
Toluene-d8 (S)
%
99
98
Max
RPD RPD
3
30
30
30
30
30 v2
30
30
30
30
30
30 v2
30
30
30
30 v2
30
30
30
30
30
30
30
30
30 v2
30
30
30
30
30
30
30
30
30
30
30
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC.
Page 85 of 107

ace
Pace Analytical Services, LLC
Pa88TAiwYd�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
QC Batch: 872676 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92743836008, 92743836014, 92743836015
METHOD BLANK: 4495930 Matrix:
Associated Lab Samples: 92743836008, 92743836014, 92743836015
Blank
Parameter Units Result
Water
Reporting
Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
08/02/24 14:18
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
08/02/24 14:18
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
08/02/24 14:18
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
08/02/24 14:18
1,1-Dichloroethane
ug/L
ND
1.0
0.37
08/02/24 14:18
1,1-Dichloroethene
ug/L
ND
1.0
0.35
08/02/24 14:18
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
08/02/24 14:18
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
08/02/24 14:18
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
08/02/24 14:18
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
08/02/24 14:18
1,2-Dichloroethane
ug/L
ND
1.0
0.32
08/02/24 14:18
1,2-Dichloropropane
ug/L
ND
1.0
0.36
08/02/24 14:18
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
08/02/24 14:18
2-Butanone (MEK)
ug/L
ND
5.0
4.0
08/02/24 14:18
2-Hexanone
ug/L
ND
5.0
0.48
08/02/24 14:18
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
08/02/24 14:18
Acetone
ug/L
ND
25.0
5.1
08/02/24 14:18
Acrylonitrile
ug/L
ND
10.0
1.8
08/02/24 14:18
Benzene
ug/L
ND
1.0
0.34
08/02/24 14:18
Bromochloromethane
ug/L
ND
1.0
0.47
08/02/24 14:18
Bromodichloromethane
ug/L
ND
1.0
0.31
08/02/24 14:18
Bromoform
ug/L
ND
1.0
0.34
08/02/24 14:18
Bromomethane
ug/L
ND
2.0
1.7
08/02/24 14:18
Carbon disulfide
ug/L
ND
2.0
0.36
08/02/24 14:18
Carbon tetrachloride
ug/L
ND
1.0
0.33
08/02/24 14:18
Chlorobenzene
ug/L
ND
1.0
0.28
08/02/24 14:18
Chloroethane
ug/L
ND
1.0
0.65
08/02/24 14:18
Chloroform
ug/L
ND
1.0
0.43
08/02/24 14:18
Chloromethane
ug/L
ND
1.0
0.54
08/02/24 14:18
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
08/02/24 14:18
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
08/02/24 14:18
Dibromochloromethane
ug/L
ND
1.0
0.36
08/02/24 14:18
Dibromomethane
ug/L
ND
1.0
0.39
08/02/24 14:18
Ethylbenzene
ug/L
ND
1.0
0.30
08/02/24 14:18
lodomethane
ug/L
ND
20.0
9.7
08/02/24 14:18 v2
Methylene Chloride
ug/L
ND
5.0
2.0
08/02/24 14:18
Styrene
ug/L
ND
1.0
0.29
08/02/24 14:18
Tetrachloroethene
ug/L
ND
1.0
0.29
08/02/24 14:18
Toluene
ug/L
ND
1.0
0.24
08/02/24 14:18
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
08/02/24 14:18
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 86 of 107

ace
Pace Analytical Services, LLC
Padg"rwyd�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
METHOD BLANK: 4495930 Matrix:
Associated Lab Samples: 92743836008, 92743836014, 92743836015
Blank
Parameter Units Result
Water
Reporting
Limit
MDL
Analyzed
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
08/02/24 14:18
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
08/02/24 14:18
Trichloroethene
ug/L
ND
1.0
0.38
08/02/24 14:18
Trichlorofluoromethane
ug/L
ND
1.0
0.30
08/02/24 14:18
Vinyl acetate
ug/L
ND
2.0
1.3
08/02/24 14:18
Vinyl chloride
ug/L
ND
1.0
0.39
08/02/24 14:18
Xylene (Total)
ug/L
ND
1.0
0.34
08/02/24 14:18
1,2-Dichloroethane-d4 (S)
%
97
70-130
08/02/24 14:18
4-Bromofluorobenzene (S)
%
97
70-130
08/02/24 14:18
Toluene-d8 (S)
%
97
70-130
08/02/24 14:18
LABORATORY CONTROL SAMPLE:
Parameter
4495931
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1,2-Tetrachloroethane
ug/L
20
18.0
90
70-130
1,1,1-Trichloroethane
ug/L
20
16.8
84
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
19.1
95
70-130
1,1,2-Trichloroethane
ug/L
20
16.8
84
70-130
1,1-Dichloroethane
ug/L
20
17.4
87
70-130
1,1-Dichloroethene
ug/L
20
16.8
84
69-131
1,2,3-Trichloropropane
ug/L
20
19.2
96
70-130
1,2-Dibromo-3-chloropropane
ug/L
20
20.3
102
70-130
1,2-Dibromoethane (EDB)
ug/L
20
18.7
93
70-130
1,2-Dichlorobenzene
ug/L
20
19.8
99
70-130
1,2-Dichloroethane
ug/L
20
18.0
90
70-130
1,2-Dichloropropane
ug/L
20
17.9
89
70-130
1,4-Dichlorobenzene
ug/L
20
20.2
101
70-130
2-Butanone (MEK)
ug/L
40
35.2
88
67-133
2-Hexanone
ug/L
40
39.8
99
70-133
4-Methyl-2-pentanone (MIBK)
ug/L
40
37.2
93
70-130
Acetone
ug/L
40
36.3
91
67-130
Acrylonitrile
ug/L
100
80.5
81
70-130
Benzene
ug/L
20
18.2
91
70-130
Bromochloromethane
ug/L
20
17.5
87
70-130
Bromodichloromethane
ug/L
20
17.3
87
70-130
Bromoform
ug/L
20
17.6
88
70-133
Bromomethane
ug/L
20
15.5
78
41-148
Carbon disulfide
ug/L
20
17.3
86
70-131
Carbon tetrachloride
ug/L
20
17.8
89
70-130
Chlorobenzene
ug/L
20
19.4
97
70-130
Chloroethane
ug/L
20
15.5
77
41-157
Chloroform
ug/L
20
17.6
88
70-130
Chloromethane
ug/L
20
16.8
84
59-141
cis-1,2-Dichloroethene
ug/L
20
16.5
82
70-130
Qualifiers
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 87 of 107

Pace Analytical Services, LLC
/'� Padg iwY�e. Suite 100
ace-
e - Huntersville, NC 28078
.+f LJ [phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
LABORATORY CONTROL SAMPLE:
Parameter
4495931
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
cis-1,3-Dichloropropene
ug/L
20
17.5
87
70-130
Dibromochloromethane
ug/L
20
17.9
89
70-130
Dibromomethane
ug/L
20
18.4
92
70-130
Ethylbenzene
ug/L
20
18.6
93
70-130
lodomethane
ug/L
40
30.0
75
57-140 v3
Methylene Chloride
ug/L
20
15.7
79
62-130
Styrene
ug/L
20
18.9
95
70-130
Tetrachloroethene
ug/L
20
17.8
89
70-130
Toluene
ug/L
20
18.2
91
70-130
trans-1,2-Dichloroethene
ug/L
20
16.4
82
70-130
trans- 1,3-Dichloropropene
ug/L
20
18.8
94
70-130
trans-1,4-Dichloro-2-butene
ug/L
20
12.4
62
57-149
Trichloroethene
ug/L
20
18.5
92
70-130
Trichlorofluoromethane
ug/L
20
15.9
80
57-130
Vinyl acetate
ug/L
40
36.4
91
70-141
Vinyl chloride
ug/L
20
15.9
80
66-140
Xylene (Total)
ug/L
60
56.6
94
70-130
1,2-Dichloroethane-d4 (S)
%
96
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
99
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4495932
MS
92743836014 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
4495933
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
23.1
22.8
116
114
70-146
1
30
1,1,1-Trichloroethane
ug/L
ND
20
20
22.3
21.1
111
105
70-150
6
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
23.0
22.7
115
114
66-144
1
30
1,1,2-Trichloroethane
ug/L
ND
20
20
20.6
20.4
103
102
70-142
1
30
1,1-Dichloroethane
ug/L
ND
20
20
22.6
22.0
113
110
68-150
3
30
1,1-Dichloroethene
ug/L
ND
20
20
21.4
21.5
107
108
64-162
1
30
1,2,3-Trichloropropane
ug/L
ND
20
20
23.5
22.3
117
112
66-144
5
30
1,2-Dibromo-3-
ug/L
ND
20
20
23.7
22.8
119
114
62-146
4
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
23.4
22.9
117
114
70-143
2
30
1,2-Dichlorobenzene
ug/L
ND
20
20
23.8
22.9
119
114
70-142
4
30
1,2-Dichloroethane
ug/L
ND
20
20
22.3
22.1
111
110
68-145
1
30
1,2-Dichloropropane
ug/L
ND
20
20
22.6
21.8
113
109
70-144
3
30
1,4-Dichlorobenzene
ug/L
ND
20
20
24.1
24.0
120
120
70-140
0
30
2-Butanone (MEK)
ug/L
ND
40
40
45.9
44.4
115
111
57-156
3
30
2-Hexanone
ug/L
ND
40
40
50.8
49.9
127
125
62-153
2
30
4-Methyl-2-pentanone
ug/L
ND
40
40
46.1
44.9
115
112
65-144
3
30
(MIBK)
Acetone ug/L ND 40 40 45.5 44.9 114 112 49-162 1 30
Acrylonitrile ug/L ND 100 100 104 98.2 104 98 59-155 5 30
Benzene ug/L ND 20 20 22.9 22.7 115 113 68-144 1 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 88 of 107

ace
Pace Analytical Services, LLC
Padg"ifyd�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4495932
MS
92743836014 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
4495933
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
Bromochloromethane
ug/L
ND
20
20
21.8
21.5
109
108
70-148
1
30
Bromodichloromethane
ug/L
ND
20
20
20.9
20.7
104
103
70-141
1
30
Bromoform
ug/L
ND
20
20
21.2
20.7
106
103
59-144
2
30
Bromomethane
ug/L
ND
20
20
18.0
18.1
90
91
23-190
1
30
Carbon disulfide
ug/L
ND
20
20
22.4
20.9
112
104
64-160
7
30
Carbon tetrachloride
ug/L
ND
20
20
23.8
22.1
119
111
70-147
7
30
Chlorobenzene
ug/L
ND
20
20
24.3
23.9
122
119
70-143
2
30
Chloroethane
ug/L
ND
20
20
17.9
18.0
90
90
55-190
0
30
Chloroform
ug/L
ND
20
20
21.9
21.3
109
106
67-148
3
30
Chloromethane
ug/L
ND
20
20
21.1
20.4
105
102
38-180
3
30
cis-1,2-Dichloroethene
ug/L
ND
20
20
21.9
21.3
110
107
67-151
3
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
23.0
22.3
115
112
70-142
3
30
Dibromochloromethane
ug/L
ND
20
20
22.3
21.9
112
109
68-140
2
30
Dibromomethane
ug/L
ND
20
20
21.7
22.8
109
114
70-142
5
30
Ethylbenzene
ug/L
ND
20
20
24.1
23.9
121
119
70-145
1
30
lodomethane
ug/L
ND
40
40
43.7
40.2
109
101
37-160
8
30
Methylene Chloride
ug/L
ND
20
20
21.2
19.9
106
100
54-149
6
30 v3
Styrene
ug/L
ND
20
20
23.2
22.8
116
114
70-147
2
30
Tetrachloroethene
ug/L
ND
20
20
22.1
22.2
110
111
70-145
1
30
Toluene
ug/L
ND
20
20
23.0
22.3
115
111
65-146
3
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
22.6
20.9
113
104
69-155
8
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
23.2
22.5
116
112
70-142
3
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
16.9
23.2
85
116
39-149
31
30 R1
Trichloroethene
ug/L
0.57J
20
20
24.2
23.4
118
114
70-152
4
30
Trichlorofluoromethane
ug/L
ND
20
20
20.9
20.1
105
101
60-158
4
30
Vinyl acetate
ug/L
ND
40
40
43.0
40.6
108
102
56-157
6
30
Vinyl chloride
ug/L
ND
20
20
21.0
20.0
105
100
51-178
5
30
Xylene (Total)
ug/L
ND
60
60
71.1
69.5
119
116
70-146
2
30
1,2-Dichloroethane-d4 (S)
%
97
94
70-130
4-Bromofluorobenzene (S)
%
98
100
70-130
Toluene-d8 (S)
%
98
98
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC.
Page 89 of 107

ace
Pace Analytical Services, LLC
Pa880plaiwYd�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
QC Batch: 873044 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92743836025, 92743836026, 92743836027
METHOD BLANK: 4497678 Matrix:
Associated Lab Samples: 92743836025, 92743836026, 92743836027
Blank
Parameter Units Result
Water
Reporting
Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
08/03/24 13:35
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
08/03/24 13:35
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
08/03/24 13:35
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
08/03/24 13:35
1,1-Dichloroethane
ug/L
ND
1.0
0.37
08/03/24 13:35
1,1-Dichloroethene
ug/L
ND
1.0
0.35
08/03/24 13:35
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
08/03/24 13:35
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
08/03/24 13:35
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
08/03/24 13:35
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
08/03/24 13:35
1,2-Dichloroethane
ug/L
ND
1.0
0.32
08/03/24 13:35
1,2-Dichloropropane
ug/L
ND
1.0
0.36
08/03/24 13:35
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
08/03/24 13:35
2-Butanone (MEK)
ug/L
ND
5.0
4.0
08/03/24 13:35
2-Hexanone
ug/L
ND
5.0
0.48
08/03/24 13:35
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
08/03/24 13:35
Acetone
ug/L
ND
25.0
5.1
08/03/24 13:35
Acrylonitrile
ug/L
ND
10.0
1.8
08/03/24 13:35
Benzene
ug/L
ND
1.0
0.34
08/03/24 13:35
Bromochloromethane
ug/L
ND
1.0
0.47
08/03/24 13:35
Bromodichloromethane
ug/L
ND
1.0
0.31
08/03/24 13:35
Bromoform
ug/L
ND
1.0
0.34
08/03/24 13:35
Bromomethane
ug/L
ND
2.0
1.7
08/03/24 13:35
Carbon disulfide
ug/L
ND
2.0
0.36
08/03/24 13:35
Carbon tetrachloride
ug/L
ND
1.0
0.33
08/03/24 13:35
Chlorobenzene
ug/L
ND
1.0
0.28
08/03/24 13:35
Chloroethane
ug/L
ND
1.0
0.65
08/03/24 13:35
Chloroform
ug/L
ND
1.0
0.43
08/03/24 13:35
Chloromethane
ug/L
ND
1.0
0.54
08/03/24 13:35
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
08/03/24 13:35
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
08/03/24 13:35
Dibromochloromethane
ug/L
ND
1.0
0.36
08/03/24 13:35
Dibromomethane
ug/L
ND
1.0
0.39
08/03/24 13:35
Ethylbenzene
ug/L
ND
1.0
0.30
08/03/24 13:35
lodomethane
ug/L
ND
20.0
9.7
08/03/24 13:35
Methylene Chloride
ug/L
ND
5.0
2.0
08/03/24 13:35
Styrene
ug/L
ND
1.0
0.29
08/03/24 13:35
Tetrachloroethene
ug/L
ND
1.0
0.29
08/03/24 13:35
Toluene
ug/L
ND
1.0
0.24
08/03/24 13:35
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
08/03/24 13:35
v2
v2
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 90 of 107

ace
Pace Analytical Services, LLC
Padg"lirpy&�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
METHOD BLANK: 4497678 Matrix:
Associated Lab Samples: 92743836025, 92743836026, 92743836027
Blank
Parameter Units Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
08/03/24 13:35
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
08/03/24 13:35
Trichloroethene
ug/L
ND
1.0
0.38
08/03/24 13:35
Trichlorofluoromethane
ug/L
ND
1.0
0.30
08/03/24 13:35
Vinyl acetate
ug/L
ND
2.0
1.3
08/03/24 13:35
Vinyl chloride
ug/L
ND
1.0
0.39
08/03/24 13:35
Xylene (Total)
ug/L
ND
1.0
0.34
08/03/24 13:35
1,2-Dichloroethane-d4 (S)
%
99
70-130
08/03/24 13:35
4-Bromofluorobenzene (S)
%
99
70-130
08/03/24 13:35
Toluene-d8 (S)
%
100
70-130
08/03/24 13:35
LABORATORY CONTROL SAMPLE:
Parameter
4497679
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
20
18.9
94
70-130
1,1,1-Trichloroethane
ug/L
20
16.6
83
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
19.5
97
70-130
1,1,2-Trichloroethane
ug/L
20
16.8
84
70-130
1,1-Dichloroethane
ug/L
20
17.2
86
70-130
1,1-Dichloroethene
ug/L
20
16.8
84
69-131
1,2,3-Trichloropropane
ug/L
20
20.0
100
70-130
1,2-Dibromo-3-chloropropane
ug/L
20
19.0
95
70-130
1,2-Dibromoethane (EDB)
ug/L
20
19.3
97
70-130
1,2-Dichlorobenzene
ug/L
20
19.5
97
70-130
1,2-Dichloroethane
ug/L
20
17.8
89
70-130
1,2-Dichloropropane
ug/L
20
17.9
90
70-130
1,4-Dichlorobenzene
ug/L
20
19.9
100
70-130
2-Butanone (MEK)
ug/L
40
37.1
93
67-133
2-Hexanone
ug/L
40
41.9
105
70-133
4-Methyl-2-pentanone (MIBK)
ug/L
40
41.0
102
70-130
Acetone
ug/L
40
38.3
96
67-130
Acrylonitrile
ug/L
100
87.7
88
70-130
Benzene
ug/L
20
17.6
88
70-130
Bromochloromethane
ug/L
20
18.2
91
70-130
Bromodichloromethane
ug/L
20
17.2
86
70-130
Bromoform
ug/L
20
17.8
89
70-133
Bromomethane
ug/L
20
13.3
66
41-148 v3
Carbon disulfide
ug/L
20
16.2
81
70-131
Carbon tetrachloride
ug/L
20
18.5
93
70-130
Chlorobenzene
ug/L
20
19.2
96
70-130
Chloroethane
ug/L
20
14.5
73
41-157
Chloroform
ug/L
20
17.4
87
70-130
Chloromethane
ug/L
20
16.0
80
59-141 v3
cis-1,2-Dichloroethene
ug/L
20
17.0
85
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 91 of 107

Pace Analytical Services, LLC
/'� Padg iwY�e. Suite 100
ace-
e - Huntersville, NC 28078
.+f LJ [phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
LABORATORY CONTROL SAMPLE:
Parameter
4497679
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
cis-1,3-Dichloropropene
ug/L
20
19.0
95
70-130
Dibromochloromethane
ug/L
20
18.2
91
70-130
Dibromomethane
ug/L
20
18.4
92
70-130
Ethylbenzene
ug/L
20
18.9
94
70-130
lodomethane
ug/L
40
33.3
83
57-140
Methylene Chloride
ug/L
20
15.7
78
62-130
Styrene
ug/L
20
18.9
94
70-130
Tetrachloroethene
ug/L
20
17.5
87
70-130
Toluene
ug/L
20
18.0
90
70-130
trans-1,2-Dichloroethene
ug/L
20
16.8
84
70-130
trans- 1,3-Dichloropropene
ug/L
20
18.9
95
70-130
trans-1,4-Dichloro-2-butene
ug/L
20
15.3
76
57-149
Trichloroethene
ug/L
20
18.7
94
70-130
Trichlorofluoromethane
ug/L
20
15.9
79
57-130
Vinyl acetate
ug/L
40
37.5
94
70-141
Vinyl chloride
ug/L
20
14.6
73
66-140
Xylene (Total)
ug/L
60
56.4
94
70-130
1,2-Dichloroethane-d4 (S)
%
99
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
98
70-130
MATRIX SPIKE SAMPLE:
Parameter
4497680
Units
92743836025
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
23.5
118
70-146
1,1,1-Trichloroethane
ug/L
ND
20
21.4
107
70-150
1,1,2,2-Tetrachloroethane
ug/L
ND
20
22.7
113
66-144
1,1,2-Trichloroethane
ug/L
ND
20
20.5
103
70-142
1,1-Dichloroethane
ug/L
ND
20
21.8
109
68-150
1,1-Dichloroethene
ug/L
ND
20
21.8
109
64-162
1,2,3-Trichloropropane
ug/L
ND
20
22.7
114
66-144
1,2-Dibromo-3-chloropropane
ug/L
ND
20
22.5
112
62-146
1,2-Dibromoethane (EDB)
ug/L
ND
20
23.4
117
70-143
1,2-Dichlorobenzene
ug/L
ND
20
24.2
121
70-142
1,2-Dichloroethane
ug/L
ND
20
21.6
108
68-145
1,2-Dichloropropene
ug/L
ND
20
22.4
112
70-144
1,4-Dichlorobenzene
ug/L
ND
20
24.5
122
70-140
2-Butanone (MEK)
ug/L
ND
40
43.1
108
57-156
2-Hexanone
ug/L
ND
40
48.6
121
62-153
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
44.7
112
65-144
Acetone
ug/L
ND
40
42.5
106
49-162
Acrylonitrile
ug/L
ND
100
98.7
99
59-155
Benzene
ug/L
ND
20
22.7
113
68-144
Bromochloromethane
ug/L
ND
20
22.3
111
70-148
Bromodichloromethane
ug/L
ND
20
20.9
105
70-141
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 92 of 107

ace
Pace Analytical Services, LLC
Padg ifyd�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
MATRIX SPIKE SAMPLE:
Parameter
4497680
Units
92743836025
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
Bromoform
ug/L
ND
20
20.7
103
59-144
Bromomethane
ug/L
ND
20
19.7
98
23-190
Carbon disulfide
ug/L
ND
20
22.4
112
64-160
Carbon tetrachloride
ug/L
ND
20
23.5
118
70-147
Chlorobenzene
ug/L
ND
20
24.5
123
70-143
Chloroethane
ug/L
ND
20
19.2
96
55-190
Chloroform
ug/L
ND
20
19.9
100
67-148
Chloromethane
ug/L
ND
20
20.6
103
38-180
cis-1,2-Dichloroethene
ug/L
ND
20
21.5
107
67-151
cis-1,3-Dichloropropene
ug/L
ND
20
22.4
112
70-142
Dibromochloromethane
ug/L
ND
20
22.3
111
68-140
Dibromomethane
ug/L
ND
20
22.5
113
70-142
Ethylbenzene
ug/L
ND
20
24.2
121
70-145
lodomethane
ug/L
ND
40
39.1
98
37-160
Methylene Chloride
ug/L
ND
20
19.8
99
54-149 v3
Styrene
ug/L
ND
20
23.3
117
70-147
Tetrachloroethene
ug/L
ND
20
22.6
113
70-145
Toluene
ug/L
ND
20
23.0
115
65-146
trans-1,2-Dichloroethene
ug/L
ND
20
21.6
108
69-155
trans- 1,3-Dichloropropene
ug/L
ND
20
22.8
114
70-142
trans-1,4-Dichloro-2-butene
ug/L
ND
20
16.8
84
39-149
Trichloroethene
ug/L
ND
20
24.2
121
70-152
Trichlorofluoromethane
ug/L
ND
20
20.7
104
60-158
Vinyl acetate
ug/L
ND
40
40.4
101
56-157
Vinyl chloride
ug/L
ND
20
20.1
100
51-178
Xylene (Total)
ug/L
ND
60
71.8
120
70-146
1,2-Dichloroethane-d4 (S)
%
96
70-130
4-Bromofluorobenzene (S)
%
101
70-130
Toluene-d8 (S)
%
99
70-130
SAMPLE DUPLICATE: 4497681
Parameter
Units
92745323001
Result
Dup
Result RPD
Max
RPD Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,1-Trichloroethane
ug/L
ND
ND
30
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,2-Trichloroethane
ug/L
ND
ND
30
1,1-Dichloroethane
ug/L
ND
ND
30
1,1-Dichloroethene
ug/L
ND
ND
30
1,2,3-Trichloropropane
ug/L
ND
ND
30
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
30
1,2-Dibromoethane (EDB)
ug/L
ND
ND
30
1,2-Dichlorobenzene
ug/L
ND
ND
30
1,2-Dichloroethane
ug/L
ND
ND
30
1,2-Dichloropropene
ug/L
ND
ND
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC.
Page 93 of 107

ace
Pace Analytical Services, LLC
Padg"tirwyd�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
SAMPLE DUPLICATE: 4497681
Parameter
Units
92745323001
Result
1,4-Dichlorobenzene
ug/L
ND
2-Butanone (MEK)
ug/L
ND
2-Hexanone
ug/L
ND
4-Methyl-2-pentanone (MIBK)
ug/L
ND
Acetone
ug/L
ND
Acrylonitrile
ug/L
ND
Benzene
ug/L
ND
Bromochloromethane
ug/L
ND
Bromodichloromethane
ug/L
ND
Bromoform
ug/L
ND
Bromomethane
ug/L
ND
Carbon disulfide
ug/L
3.3
Carbon tetrachloride
ug/L
ND
Chlorobenzene
ug/L
ND
Chloroethane
ug/L
ND
Chloroform
ug/L
ND
Chloromethane
ug/L
ND
cis-1,2-Dichloroethene
ug/L
ND
cis-1,3-Dichloropropene
ug/L
ND
Dibromochloromethane
ug/L
ND
Dibromomethane
ug/L
ND
Ethylbenzene
ug/L
ND
lodomethane
ug/L
ND
Methylene Chloride
ug/L
ND
Styrene
ug/L
ND
Tetrachloroethene
ug/L
ND
Toluene
ug/L
ND
trans-1,2-Dichloroethene
ug/L
ND
trans- 1,3-Dichloropropene
ug/L
ND
trans-1,4-Dichloro-2-butene
ug/L
ND
Trichloroethene
ug/L
ND
Trichlorofluoromethane
ug/L
ND
Vinyl acetate
ug/L
ND
Vinyl chloride
ug/L
ND
Xylene (Total)
ug/L
ND
1,2-Dichloroethane-d4 (S)
%
100
4-Bromofluorobenzene (S)
%
98
Toluene-d8 (S)
%
97
Dup
Result RPD
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
103
98
99
0
Max
RPD
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30 v2
30
30
30
30
30
30
30
30
30
30
30
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC.
Page 94 of 107

Pace Analytical Services, LLC
/'� PaWiwy�e. Suite 100
ace-
e - Huntersville, NC 28078
.+f LJ [phone]
QUALIFIERS
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
B Analyte was detected in the associated method blank.
C9 Common Laboratory Contaminant.
L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.
R1 RPD value was outside control limits.
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2024 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 95 of 107

ace
Pace Analytical Services, LLC
Padg iwyd�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Lab ID
92743836001
92743836002
92743836003
92743836004
92743836005
92743836006
92743836007
92743836008
92743836009
92743836010
92743836011
92743836012
92743836013
92743836014
92743836015
92743836016
92743836017
92743836018
92743836019
92743836020
92743836021
92743836022
92743836023
92743836024
92743836025
92743836026
92743836027
92743836001
92743836002
92743836003
92743836004
92743836005
92743836006
92743836007
92743836008
92743836009
92743836010
92743836011
92743836012
92743836013
92743836014
92743836015
92743836016
92743836017
Sample ID
MW-1
MW-1 D
MW-2A
MW-2D
MW-3
MW-3D
MW-4
MW-4D
MW-11
MW-11 D
MW-12
MW-12D
�yq�Qi
MW-4R
MW-4DR
M N S_T B-20240722-0800
M N S_F B-20240722-1045
M N S_F B-20240723-1000
MNS_FD-20240722-1
MNS_FD-20240723-1
MW-3BR
MW-4BR
MW-4BRR
MW-11 BR
MW-13D
MW-13BR
M N S_TB-20240725-1300
MW-1
MW-1 D
MW-2A
MW-2D
MW-3
MW-3D
MW-4
MW-4D
MW-11
MW-11 D
MW-12
MW-12D
SW-1
MW-4R
MW-4DR
M NS_TB-20240722-0800
M N S_F B-20240722-1045
Date: 08/07/2024 06:04 PM
QC Batch Method
8260D-SIM
8260D-SIM
8260D-SIM
8260D-SIM
8260D-SIM
8260D-SIM
8260D-SIM
8260D-SIM
8260D-SIM
8260D-SIM
8260D-SIM
8260D-SIM
8260D-SIM
8260D-SIM
8260D-SIM
8260D-SIM
8260D-SIM
8260D-SIM
8260D-SIM
8260D-SIM
8260D-SIM
8260D-SIM
8260D-SIM
8260D-SIM
8260D-SIM
8260D-SIM
8260D-SIM
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
QC Batch
2332057
2332057
2332057
2332057
2332057
2332057
2332057
2332057
2332057
2332057
2332057
2336472
2332057
2335267
2335267
2335267
2335267
2335267
2335267
2335267
2335267
2335267
2335267
2335267
2335267
2335267
2335267
872652
872652
872095
872095
872095
872095
872095
872676
872095
872095
872095
872095
872095
872676
872676
872357
872357
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical Method
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
EPA 8260D by SIM
Analytical
Batch
2332057
2332057
2332057
2332057
2332057
2332057
2332057
2332057
2332057
2332057
2332057
2336472
2332057
2335267
2335267
2335267
2335267
2335267
2335267
2335267
2335267
2335267
2335267
2335267
2335267
2335267
2335267
Page 96 of 107

ace
Pace Analytical Services, LLC
Padg iwYd�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J24070005 MNS Landfill #1
Pace Project No.: 92743836
Lab ID
Sample ID
QC Batch Method
QC Batch
92743836018
MNS FB-20240723-1000
EPA 8260D
872652
92743836019
MNS FD-20240722-1
EPA 8260D
872357
92743836020
MNS FD-20240723-1
EPA 8260D
872652
92743836021
MW-3BR
EPA 8260D
872357
92743836022
MW-4BR
EPA 8260D
872357
92743836023
MW-4BRR
EPA 8260D
872652
92743836024
MW-11BR
EPA 8260D
872357
92743836025
MW-13D
EPA 8260D
873044
92743836026
MW-13BR
EPA 8260D
873044
92743836027
MNS TB-20240725-1300
EPA 8260D
873044
Date: 08/07/2024 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical Method
Analytical
Batch
Page 97 of 107

DC#y Title: ENV-FRM-HUN1-0083 05_Sample Condition Upon Receipt
Ce P ge 138 of 152
Effective Date: 05/24/2024
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersville❑
Sample Condition
• • Project #t: Client Name: r WO# : 92743836
� i +
Courier: ❑F d Ex ❑UPS ❑USPS ❑ClienC I� III I II I III I I II III
El commercial Pace ❑Other:
92743936
Custody Seal Present? ❑Yes QNo Seals Intact?
❑Yes []NO ❑N/A
Packing Material: ❑Bubble Wrap [[Subbie Bags ❑None ❑
Thermometer:
❑ IR Gun ID: qxV011,7
Type of ice: wet
Correction Factor:
CaoferTemp: Add/Subtract (°C) = )
Cooler Temp Corrected ('Q
USDA Regulated Soil ( []"N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC
Other
Date/Initials Person Examining Contents i V
Biological Tissue Frozen? r
[-]Yes [:]No QN/A "{\
❑Blue ❑None
Temp should be above freezing to 6'C
[]Samples out of temp criteria. Samples on ice, cooling process
has begun
Did samples originate from a forei¢n source (internationaliv.
(check maps)? ❑Yes ❑No
including Hawaii and Puerto Rico)? [-]Yes ❑No
Comments/Discrepancy:
Chain of Custody Present?
Yez
❑No
[]N/A
1.
Samples Arrived within Hold Time?
❑Yes
❑No
❑N/A
2.
Short Hold Time Analysis 1<72 hr.)?
❑Yes
QNo
❑N/A
I
Rush Turn Around Time Requested?
\\i Yes
QNo
❑N/A
4.
Sufficient Volume?
©Yes
[-]No
❑N/A
5.
Correct Containers Used?
-Pace Containers Used?
[�Yp
[3Yes
[]No
[:]No
❑N/A
[]N/A
_
6.
I. Containers Intact?
E Yes
❑No
❑N/A
7.
Dissolved analysis: Samples Field Filtered?
[]Yes
❑No
oN/A
8.
Sample Labels Match CDC?
-Includes Date/Time/ID/Analysis Matrix:
❑Yes
❑No
❑N/A
9.
Headspace in VOA Vials (>5-6mm)?
❑Yes
QNo
❑N/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
[]Yes
❑Yes
QNo
❑No
❑N/A
�M1f%A
11.
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATIONJRESOLUTION
Person contacted:
Project Manager SCURF Review:
Project Manager SRF Review:
Lot ID of split containers:
Date/Time:
Date:
Date:
Field Data Required? ❑Yes ❑No
Page 98 of 107
Qualtrax 11D� 69614 Page 1 of 2

�a?ce
DC#_Title: ENV-FRM-HUN1-0083 v05_Sample Condition Upon Receipt
P ae 139 of 152
Effective Date: 05/24/2024
'Check mark top half of box if pH and/or dechlorination is verified and within the
acceptance range for preservation samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
•'Bottom half of box is to list number of bottles
* "Check all unpreserved Nitrates for chlorine
W0*1:92743836
Project # PM. LJP Due Date: 08/07/24
CLIENT: 92-Duke Ener
Laboratory
4Receiving Lacation. Asheville ❑ Eden❑ Greenwood ❑ Huntersville ❑ Raleigh[] Mechanicsville❑ Atlanta❑ Kernersville❑
Client VauN Profile/EZ (Circle one) Notes
c
u
x
?
FF
a
q
2
E
a
D
9
p
n
O
n
n 7
m
Y
:?
a
Q+
91
Z
2
_
n
7
A
L
N
SSn
1
6
ppF
VI
a
pE
8
7
d
`m
_
4
-�Mi
V)
4
aE
a
E
!}�JIf
L
E SyS
W LL
d
.�1
i7
a`
N
l7
ppE
m
C7
`m
ti
-
E
M
6
E
O�1
Q
E
lO2J1
Q
f
P
7
j
>
Q
E u
Y a
E
N
E
N
E
m
ppE
4
E
a
E
C
CC
i
1
2
J\
3
/
6
7
U'
9
�,N
11
j
pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
rime preservation
adjusted
Amount of Preservative
added
Lot N
Note: whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina 0E NR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
JPa� of 107
Qualtrax 1D: 69614 Page 2 of 2

ace -
DC# Title: ENV-FRM-HUN1-0083 v05—Sample Condition Upon Receipt
Effective Date: 05/24/2024
'Check mark top half of box if pH and/or dechtorination is verified and within the
acceptance range for preservation samples. Project #
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
"Bottom half of box is to list number of bottles
'Check all unpreserved Nitrates for chlorine
140 of 152
Laboratory Receiving Location: Asheville ❑ Eden[] Greenwood ❑ Huntersville © Raleigh❑ Mechanicsville❑ Atlanta❑ Xernersville
Client % ' i� Profile/EZ (Circle one) Notes
$
c
8.
c
ii
°��`
v
z
u
2
m
x m
ti
y
u
$
a
n
j
n
L
s
Y
E
d
r"'v
u
a
Y4
`i
z
Q
p
.C..
Z
Q
Q
z
Q
4
v y
Y
R V
sr
L
m
i
Y
Q
ti
Q
a
C
z
v
c
m
m
Q
C
E
C
Q
E
6
E
E
C
E
7
E
7
>
E
d
A
x }
E
h
E
w
m
E
4
E
}
E
E3
cc
1
j
2
4
N
N
S
6N
-N
7
a
�Q
I
thin
1D
�
I
t�
11
iz
pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot p
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DENR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
}
PaEe 100 of 107
Qualtrax ID: 69614 Page 2 of 2

Page 141 of 152
�aceAnatyfrca!
Date:
7 Z zit
Sample Receiving Non -Conformance Form (NCF)
f_ ` Evaluated by: ,q j� Affi W0# : 9274 4A- e
Client: �� #' !-- ►� l f' r �. w'
PM: L,lP Due Date: 08/07/24
CLIENT: 92—Duke Ener
1. If Chain -of -Custody (COC) is not received: contact client and if necessary, fill out a COC and indicate that it was tolled out by
lab personnel. Note issues on this NCF.
2. If COG is incomalete. check aDDlicable issues below and add details where aooronriate:
Collection date/time missing or
Analyses or analytes: missing or
Samples listed on COC do not match samples
incorrect
clarification needed
received (missing. additional, etc.
Sample Us on COC do not
match sample labels
Required trip blanks were not received
Required signatures are missing
Comments/Details/Other Issues not listed above:
on7ad�lej MW-Zn� � �i1VY`' K
3. SamDle integrity issues: check aoolicable issues below and add details where anorooriate:
Samples: Condition needs to be brought to
Samples: Past holding time
lab ersonnel's attention details below
Preservation: Improper
Temperature: not within acceptance criteria (typically
Samples: Not field filtered
Containers: Broken or compromised
0-8C
Samples: Insufficient volume
received
Containers: Incorrect
Temperature: Samples arrived frozen
Samples: Cooler damaged or
Custody Seals: Missing or compromised on
compromised
samples, trip blanks or coolers
ls received with improper heads ace
Samples: contain chlorine or
rOt
sulfides
PackingMateriL Insufficient/Improper
er:
Comments/Details:
4. If SamDles not Dreserved oroneriv and SamDle Receivina adiusts oH. add details below:
Sample ID.
DatelTime:
Amount/type pres added:
Preserved by:
Initial and Final H:
Lot # of pres added:
Sample ID:
Date/Time:
Amount/typo pres added:
Preserved by:
Initial and Final H:
I Lot # of pres added:
Sample ID:
Date/Time:
Amount/type pres added:
Preserved by:
Initial and Final H:
Lot # of pres added:
5. Client Contact: If client is contacted for any issue listed above, fill in details below:
Client: Contactedper:
PM Initials: I Datel-rime:
Client Comments/Instructions:
F-ALL-C-01 1 -rev.00, 05Jul2018
Page 101 of 107

�ce
DC#_Title: ENV-FRM-HUN1-0083 05_5ample Condition Upon Receipt
PLae 142 of 152
Effective Date: 05/24/2024
Laboratory receiving Samples: -
Asheville ❑ Eden❑ Greenwood ❑ Huntersville !❑Raleigh❑ Mechanicsville❑ Atlanta[] Kernersville❑
Sample Condition I Client Name:
Upon Receipt DAL Cneo Project #;
Courier: ❑Fed ❑UP$ UPS ❑Client
❑ Commercial Df ace ❑Other:
Custody Seal Present? es ❑No Seals Intact? Fe es ❑No ❑N/A
Date/Initials Person Examining Contents:
PackingMaterial: ubble Wrap ? ��-` — ! p ❑Bobbie Bags ❑None ❑ Other Biological Tissue Frozen.
Thermometer; ❑Yes ❑No (i1N/A
El IR Gun ID: Type of Ice: QW15' ❑Blue []Noner
Correction Factor:
Cooler Temp: ' Add/5ubtract ("C) Temp should be above freezing to 6"C
❑Samples out of temp criteria. Samples an ice, cooling process
Cooler Temp Corrected {°Cj:—r has begun
USDA Regulated Soil (❑ N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC Did samples originate from a foreign source (internationally,
(check maps)? UYes LjNo
including Hawaii and Puerto Rico)? LJYes LJNo
Comments/Discrepancy:
Chain of Custody Present?
es
❑No
❑N/A
1.
Samples Arrived within Hold Time?
es
❑No
❑N/A
_
2.
Short Hold Time Analysis (02 hr.)?
❑Yes
No
❑N/A
3.
Rush Turn Around Time Requested?
Dyes
❑N/A
4.
Sufficient Volume?
[]No
❑N/A
S.
Correct Containers Used?
-Pace Containers Used?
b"s
es
❑No
No
❑N/A
❑N/A
6.
7.
Containers Intact? 42es ❑No ❑N/A
Dissolved analysis: Samples Field Filtered?
❑Yes
❑No
/A
8.
9.
Sample Labels Match COC? Ux.. ❑No ❑NIA
-Includes Date/Time/ID/Analysis Matrix:
i Headspace in VOA Viais (>5-6mm)?
❑Yes
[]No
El N/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
❑Yes
❑Yes
[]No
❑No
❑N/A
❑N/A
11,
CDMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Project Manager SRF Review:
Lot ID of split containers:
Date/Time:
Date:
Date:
Field Data Required? LjYes "No
Page 102 of 107
Qualtrax ID:69614 Page 1 of 2

ace
I DC#_Title: ENV-FRM-HUN1-0083 v05_5ample Condition Upon Receipt
P ae 143 of 152
Effective Date: 05/24/2024
'Check mark top half of box if pH and/or dechlorination is verified and within the
acceptance range for preservation samples. Project #
Exceptions: VOA, Coliform, TOC, oil and Grease, DRO/8615 lwaterj DOC, LLHg
"Bottom half of box is to list number of bottles
`Check all unpreserved Nitrates for Chlorine
r
Laboratory ReceivgLocation: Asheville ❑ Eden[] Greenwood ❑ Huntersville d Raleigh[] Mechanicsville
Client , 61 - Profile/EZ {Circle one} Notes
AtlantaLj Kernersvilt
T
m
z
m
x
=
w
C
G
7
c
u
j
=
J
s
=
Z
r�s
q
O
sl LL
c
q
N
a
S
Z
C
C
o
Q
j
.y.
..
E
a
E
a
¢
4
¢
n
E
=
u
E
E
E
E o
a
L
E
a`
E
u
m
m
m
m
m
m
m
}i
¢
Lj
Q
LPC
>
Y 9
a
H
m
a
i
ca
CC
1
4---
��
2
i
I
IYn�
3
4
6
7
8
9
1D
11
112
pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted Time preservation
adjusted
Amount of Preservative
added
Lot 9
i
Note: whenever there is a discrepancy attecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DENR Certiticat ion Orlice ii.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Qualtrax ID: 69614 Page 2 of 2 Page 103 of 107

_ CHAIN OF CUSTODY RECORD AND.R_EQ_U_ EST FORM -- .gage 144 of 152
Anal I�
Duke Energy Analytical Laeoral4ry __._._._._._._._._._._._._._._._._._._._._._._.-,_._._._._._._._._._.i... ..... .. Use ..,._. ._._ ._._._._._._._._._._._-_._._,
O
DUKE AN" cod•MooW 111ulMkrr74e51 i iorder# J24070005 Matrix WATER NC_ Page _1 of_3_
:. a..a U1.+MOF�
`�7/ 13339 Har•rr Ferry Nd i i SC ; DISTRIBUTION O
ENERGY xune•nw., N. e. zamr
Oa4t nn-524e s' SAMPLE PROGRAM 1
; IL•gg•d By D TI • ! ORIGINAL to LAB. COPY to CLie8T
r,,:gwlsleae�a._....
I,„._._ I..._._._._._._._._._._._._._ ._.. Ground Water_X_ NPDES_ _ _ _ _ _ _ — _
Ph —No; IV•ndor: trap• r Drinking
Project Name MNS LANDFILL #1 Permit 960-04 � p,ACE / g Water_ UST_ N
RCRA Waste _ Updated, 6113123 07
i.-- Cool•r T•mP.151_.._.._._.._.._.._.._.._.._.._.._.._.._.._.._.._. _.._.._.._.._.._.. _.._....) to
Client Ethan Smith 1 Bryan Moeller!
CourtneyMurphy1 Ashley Healy No PO 5 �� Flltratlon {0.45 umI 4PiL n Iltered 4 Filtered
Operating Unit: 20036 Process: BLDFL.GN Account: Preservative 'Me17, ICE HNO2 „U@k. ICE I ICE ICE
n ..w
Project: Activity l0: Facility ID: Container Volume (mL) do 600 40 Soo Soo
G
Program 7 EquiS Task Code: rLfTask Code: Container Type
- a
a M m S w 4 U
u 0
pU
Q gg w V F N m 0 )(- ^ Ill
Customer to complete oN a z rh a m m U
q Na: 0.�2'_ V LL_ O
Sample Description or ID P PPrePrin[o non-slvodod areas. ! a • — X m a m ti Z g a N V
-- " C 1C I
y 4 je D
— _ p 0. JU __ q C
i SAMPLE Ep Collection Information u + 3 Y o n e W .rs rt^ rl V JI v OJ ` o m n m
'•
i NUMBER i O nl - -- Y a S a L: ^-
r
1—'�--I Date Time Printed Name SI tore u o` 7 m a a f �. U C e it to a u Q to U `.'E $
2024016757 ;
MNS_MW-1
[�
�dl�
X
3
1
3
t
e
2024016758
MNS_MW-1 D�
165 a
X
3
1
3
1
e
2024016759
MNS MW-2A
7
��
11�Y� �1A�4n
X
3
1
3
1
8
2024016760
— -
MNS_MW-2D
7
Q JS
bdR lri
X
3
1
3
1
8
2024016761
MN$_MW-3
MNS_MW-30
MNS_MW-4
_ ?Jzs
Q bh
6
X
X
X
f Z
3
3
1
1
1
3
3
3
1
1
1
8
8
B
i 2024016762
2024016763 ;
2024016764
MNS
IGbs
q{
alb
X
3
1
3
1
8
2024016765
MNS-MW-11
Y
100o
*
X
3
1
3
1
6
2024016766
MNS_MW-11D
MNS_MW-12
2 -t
f�
1 U—SL~,4^
CClp�,
J
. t
X
X
3
3
1
1
3
3
i
1
8
s
2024016767 !
i 2024016768 i
MNS MW-12Dc{
j 0
X
1
3
1
e
i'
2024016769
MNS_SW-1
X
3
1
3
1
2024016770 i
MNS_MW-4R
MNS_MW-0DR
� L
�
I
16
X
X
3
3
1
1
3
3
1
1
2024016771
i
I I
111
TOTALf CONTAINERS
45
1$ 0
45
4
0
Rellnquis a By
DatelTime
Acce �y:
Date171me
m
_
Ral quiche Da ime
Accepted By: Dilemma
21 Days
ot_c
a In u ad By DatelTime
Accepted By:
4 7TIma
$
L
14 pays
am
tv
Sea acked Datarrime
Staled/Lock Opened By W me
:
C.?
'7 Days
E w
0
Comments
m
a
'Other
*Add. Cost WIII Apply
t�

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
nuke Energy Analytical Laboratory i i Anal ical Laborato Use Onl T y o
i` Mall C• Is MEOW Bulldl,U 74ntl I Matrix WATER NC 9 _
DUKE
Ild!'•Order#J24071)UU5 :••,w,amwu„F,em i Page IBUT 3 w
, 6C: I DIsrRlsunoN o
quaMnmll<, N.C.N. c. Hors
'r ENERGY mmmyll 240
i
; i�6� ay & 3ma ORIGINAL to LAB, COPY to CLIENT
vs4ns6P4s SAMPLE PROGRAM
- CD
L_._._._._._._._._._._._._._._._............ F........... Ground Water X NPUES_
Phone N-: ;Vendor: Pa Dunkin
Project Name MNS LANDFILL #1 Permit #60-04 iPo I _.._.._.._.-_ _ g Water
Waste_ _ UST ' .- ---._kK.
* y'.I--- a_.._.._.
Client Ethan Smith ! BryaR Moeller 1 , +'i CE
Courtney Murphy! Ashley Healy PO Filtration (0.45 um) B Unfiltered b Ffltered
Operating Unit: 20036 Process: BLDFLGN Account: ? 1 ■ 546' 2 1 Preservative'HCL, ICE HNO3 HCL, ICE ICE FCE
Project: Activity 10: Facility ID: Container Volume (mL) 40 500 40 500 500
Gg
Program I EquiS Task Coda: Sub-ProgremlTosk Code: Container Type
as
15
ILLS
C„sromnr to complete ell approprialo non-shnded nrons. a vffi2 17i : o z• e K 05 V ;p U Z o
Sample Description or ID ��ro av$ • o v I— 0
_ Q
a a` m p 11 j 0.-. a
LL
i SAMPLE IC i e m o w 7` o m .0 ❑ W L �- U
Y d 4.
Collection Information Tn
ODate
NUMBER i p8 a n
Time Prlrsted Namc Si nature m 4 a o u ^ ri Vl a o 4 rn U
T
2024016772 ;
MNS_TB-ZoN67� _ off
7 q
6
oh �{
x
3
3
N/A
6
2024016773
MNS_TB
x
3
3
NIA
6
2024016774 '
MNS_TB
X
3
3
NIA
6
2024016775 '
MNS_TB
X
3
3
NIA
6
i 2024016776 !
MNS_F,1444Qx2- Idi5
5
644wli, 5mlifv
X
3
1
3
i
NIA
8
i 2024016777
�i
MNS_Ffi12,151,41low
Zti
060
y
X
3
1
3
i
WA
8
2024016776 ;
MNS_FB
X
3
i
3
1
NIA
8
2024016779
MNS_FB
A
X
3
1
3
1 1
NIA
8
2024016780
MNS_FD-ZOzKo72Z._ (
2Z It(
X
3
1
3
1
N/A
8
i 2024016781
MNS_F6»ZOZ40-1Z3—r
T
,,.•
� �y_L�-
X
3
1
3
1
NIA
8
0
0
i i
0
I 1
0
6
n
k Yl t
i i
V
0 ! `I
0
TOTAL # CONTAINERS
30
6 0
30
0
72
Relinquish d 8y
DatefTime
Accepted By:
/DallIme
Q� (`
9r
/%Jr
umaround
Relinquh;hed OateMme
Aet:epled By: DalelTime
zt Days
a m
Relinquished By D teMme
Accepted By: Da me
7L
L
E
14 Days
2�
.�
ro 0
t: v
Sea ocke y atefTkme
SealedlLock Opened By Dilemma
a
'7 Days
-o
� v
Comments
o
'Other
Add_ Co!;[ Will Apply
U
Total 72

Duke Energy Analytical Laboratory
f DUKE
ENERGY
Melt Coae MG07A2 leuaelnp 7uoli , i
„""H.aenr.ryen
aum.rsane, N. C. zrp7e i
nwye7aszes ,
Fa.: w e73fie3e
Project Name MNS LANDFILL #1 Permit #60.04 �• p«
Client Ethan Smith I Bryan Moeller IF
Courtney Murphy ! Ashley Heal
Operating Unit: 20036 Procase; BLDFLGN Account:
Project: Activity ID: Facility In:
C00_
Program I EQuIS Task Code: Sub-Progremrrask Code:
----------------------
i SAMPLE to i
i NUMBER
2024016782
By
By
/ /
By
Sample Description or ID
11BR
13D
13BR
DatelTlme
---_- CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
.- -.- -.-._ -.-.-.-.-.-.- _._.-._._.-._....-
-Anal I--- L------ -- Use Only. .
- ------...............................
-
'Order# J24070005
Matrix WATER
NC
sc
�Lepped By
SAMPLE PROGRAM
i
!Vendor: Paoe
Ground Water _X_
Drinking Water
NPDES
UST
PACEeeal.rr.mP.i91_.._
.RCRA Warta_
PO 11546721
Filtration (0.45 um)
4
Unfiltered
Preservative HCL, ICE
HNO3
HCL, ICE
ICE
ICE
Container Volume (mL) 40
Soo
40
500
Soo
Container Type
a
o
Q
Customor to complete aft eppreprlare noa shadod
a
areas. Cox a toi
oam�
-: `
m
ro m u
X to
W'
u U
W
Z
Collection Information
z
E w U. m
a0.�—aN
3 a X n a
om oa
y
ur,
Yl V
�lU
YI v
o
x a
Date Printed Name
Si re G O m 4 ei
"o' C-,e ti
y E fn
4 U
Q uu)
U a
1?Time
l 3 0
Noattv
c6b l i1
x
3
1
3
1
06
Wa4k
IN6-ty,
x
3
1
3
1
3
o0
Q(
eA6w
x
3
1
3
1
—
r 320
_
jM11�j
x
3
1
a
1
f�
MJ7d
�.
X
3
1
3
1
17+1S
�
ir4etn.. C--A
X
3
1
3
1
By:
By��� �
TOTAL # CONTAINERS
f Daterriale SealedlLocR Opened By
16C--WIk q•TV y yw-y6kY<-- 6,)v rq : t(•57
7.
16
16 D
I 1a
6
l 0
naja>Trne
E
DetelTime
c
mm
�
Datel7ime
p h
e
�E
a
Datefrlme
a..
E 'w
L• �
0
U
Page 146 of 152 0
Page _3_ of _3_ CD
DISTRIBUTION w
ORIGINAL to LAB, COPY to CLIEq
0
4
Requested Tumaround
21 DaysQ��j
14 Days 5i "rY '7 Days
'Other
Add. Cost Will Apply
Total E

Duke Energy Analytical Laboratory
4 DUKE
MW C•d• MGO]A2 tanlidine peal
ENERGY
r»la lr. ao
iea.ur.vawi.. 14.a. c. e. uOTa
pwl a�es2aa
_ _
Fa:- a a'rasasa ----------
Project Name MNS LANDFILL #1 Permit #60.04 F%— na.
Client Ethan Smith I Bryan Moeller I
Courtney Murphy 1 Ashley
Heal
Operating Unit: 20036
Process: BLOFLGN
Account:
Project:
Program! EOuiS
Facility ID:
&GR0
!Task Code;
Sample Description or ID
..........................._._._
CHAIN OF CUSTODY RECORD AND ANALYSISREQUEST FORM
_._._._ _. Anal icai Laboratory _ ---- ---'---------'---._....---'-'-'-----'-'--'---'-'-'-'-----'-....-'---'-'-F
!Order #J24070005
Matrix WATER
NC
i
S_ ;
i4.deyzz--Ze
7iT �J��j 7
SAMPLE PROGRAM
!V•ndar:P
Ground Water
_X_
NPDES_
PACE
❑rinkin Water_
9 RCRA Waste
UST
�P6 a
Cool. T•m C
_.._.._.._ ._.._.._.._.._ ._.._eL.i_.._.._.
_.._.._.._.._.._.._.._.__..................._.._.._.._.._.._.._-._
7
PO 59,bi `
Filtration a.45um
[ f
i1
Unfiltered
Preservative HCL, ICE
HNO3
HCL, ICE
ICE ICE
Container Volume ImLI 40
500
40
500 50o
Container Type
6 na
p
Customer to camplere all appropriate
Q w b
non-shadad areas. = a .5
_'
o = - ¢ T
p
L N m
do p
O
N x W
U ,�
y
a m rc ty m
ra _ 4 V
O n3 A
K LLt -
ige 147 of 152
Page -1— of _I_ CD
DISTRIBUTION p
ORIGINAL to LAB, COPY to CLIJENT
O
b Filtered
a
Collection information
u$
t
u
w K =
S a x .g. Q a
to 00 O
U
J
aD
OJ d
9
Data
Time
Printed Name
Signature
a
ti
5 m ¢ a
"� �. ,, u`
-orm
r- �M in
¢ O
xt
6 m
U a
MNS_MW-13D
7 LI a`
�'
X
3
1
3
1
8
MNS MW-13BR
-
Sa
7 q
X
3
1
3
1
S
MN5_TB-2�Zqb'r !yam j- 1aQt�
AVzq
17,615
1 X 1
3
3 1
6
TOTAL / CONTAINERS I I I 9 1 2 1 0 9
0
0
a
0
a
0
a
a
0
a
a
0
0
0
0
2 0 a +,4-, a a a 22
Requested Turnaround Total E22
Re1i 'xh
DatelTime
Accepted By;
atelTim
C
_
�/
Relinquished B DatelTime
Accepted By: Date[T me
�`
-2
E E
c
m3
y1, o
21 Days
14 Days
Re nqm y o
Accepted �yi /� rGut,. ! wmlTltne
J.1! %L Ul'1 X,'
/ :1V c/'�`li
SeaOLocked By Data/Time
SealedlLock Opened By Date/Time { 02 �� _
�•
�E w
m z
7 Days
Comments
G
�
'Other
h
t�
'Add. Cost Wi11 Apply

CHAIN OF CUSTODY RECORD AND ANALYSIS_ REQUEST FORM
Duke Energy Analytical Laboratory .! i------------------------------•-------•---•-•-•----------•-•------Anal Analytical Laboratory Use Only --------.-.---------.-----------.-----------.-----------.---------.-'i
Page 148 of 152
y
r`i� DUKE
Mu Cone MC03A2 (Uldine 74e51
j iOrder # J24070005
Matrix WATER
s,mNi.. o win,m a r nm ��—
; Page _t_ of 3_
ENERGY
13339HagerareryRtl
Hisreenrlik. n. C. Yaela
, ;
SC_
DISTRIBUTION
!7041 ar3-s24a
f Lowed By
Tie
SAMPLE PROGRAM
! ORIGINAL to LAB, COPY to CLIENT
t._._._._._._._._._._._._._._._._._
_._._._._._._vax:.(foala71AV� _,-,_,__,1
'
Ground Water X_ NPDES
E
Project Name MNS LANDFILL #1 Permit #60-04
Raona Nam'
Client Ethan Smith / Bryan Moeller!
Courtne Murphy ! Ashley Heal
Operating Unit 20036
Process: BLDFLGN
Account:
Project:
Activity ID:
Facility10:
MCGO
Program ! €QuIS Task Code:
Sub-ProgramlTask Code:
.V.ndor. Pan r Drinking Water_ UST_
PACEWasie
4f ` Filtration (0.45 umj b n Iltered 8
Pa 115 ;PiL
i Preservative 'hit-, I.E iiNc3 .-Wft. ICE ICE ICE
Container Volume (mL) 1 40 500 40 $00 500
Container Type
Cusromer to complete all approienare non -shaded areas.
Sample Description or ID
i SAMPLE ID- i Collection Information
i NUMBER i Date Time Printed Name Sin ra
c
a rn J
YYr
0
7 m¢ a
a
d 1tl a
f m x 4 p
a —
0. _ -
a a =^N
o u Y o'a.
a u`
c
C N y
co B
K to
? m o IL
a N
y
O
y .
J t?
Q U
k V
li
JIB
Ylg
6 cOOUi
tL
_
o
2 a
U Y
Z
a
E
ci
a
202244016 5
MNS_MW-1
[!
10110
?k;?V1
%
3
1
3
1
2024016-158
MNS_MW-1D
MAIN�b5�
X
3
1
3
1
2024016759 !
MNS_MW-2A
�(�
[JMv� L'11A in
X
3
1
3
1
2024016760 !,
MNS_MW-2D
71llal
011155
r
OOl R 1p
x
3
1
3
1
i 2024016761 !
MNS_MW-3
;25
6n
X
�Z
1
3
1
i 2024016762 i
MNS_MW-3❑
NLQ
Ha;l
X
3
1
3
1
2024016763
MNS_MW-4
15211
Qle
X
3
1
3
1
2024016764
MNs_MW-4D
��Oty
X
3
1
3
1
2024016765
MNS_MW-11
9
X
3
1
3
1
2024016766 ;
MNS_MW-11D
GR WiL
X
3
1
3
1
! 2024016767 ,!
MNs_MW-12
r
Sk
x
3
1
3
1
i 2024016768 i
MNS_MW-12D
0
X
/%
1
3
1
i 2024016769 i
MNS_SW-1
X
3
1
3
1
j 2024016770 i
MNS_MW4R
S§zAdj
%
3
1
3
i
2024016771 ;
MNS-MW-4DR
/7%1ft i
I&LI S
ti.ia.��a S� jei�
X
3
1
3
1
By Datell7me
By DaWTime r Accepted By:
ly Daterrime SealoWl-ock Opened By
Comments
Filtered
u`
ooau
ww a
M ur c
LLEmen �
1
0
0
TOTALS CONTAINERS
I
I
I 45
I 16 I _0 _
L 45
I 11
I 4
0
I 0
I 01
0-
1 0
I i
121
Datelln
y
J
J�
v
a
E
Requested Turnaround
Total 12i
DatelTime
H a
21 Days
m
a
E
1/
14 Days f
Date)Tima
e �
a a
DatelTime
a m
'7 Days
£ m
� b
m
o
•Other
'Add Cost Will Apply
U

CHAIN OF CUSTODY RECORD AND ANALYSIS_ REQUEST FORM
.
Duke Energy An...... Laboratory - i i „ ,-'-._._._._._._._._._._._._._ --- 'cal Laboratory UseOnly'------.-.-------.-.~_._.-.-.-.-.-------.-.-•-•-------.-.---------. Page 149 of 152
Ana
.' DUKE M.aCndeMG0342 Iauualep7mat ' 'Order# J24070005 Matrix WATER Samp..Npauee:� sc_ PDISTRIBUTION
ENERGY 133]9 II , N.C.250
Nune..avllk, N. 2 26e7a I I ! ORIGINAL to LAB, COPY to CLIENT
past qa-a2m ILoeeed By i me SAMPLE PROGRAM
gar;gwtaje-seas Ground Water �X_ NPDES_
Project Name MNS LANDFILL #1 Permit #60-04
Phone Ne
Client Ethan Smith I Bryan Moeller I
Courtney Murphy I Ashley Hea
Operating Unit: 20036 Process: BL.OFLGN
Account:
Projeck: Activity ID:
Facility ID:
Program I EQuiS Task Code:
Sub�ProgramlTask Code!
Relinquished Bi
SeallLucked By
Sample Description or ID
MN$ TB+Za,Na700
MNS_TB
MNS TB
MNS-TB
MNS-F&.11g4 7 - 1045
MNS-FB-26rV6JLS - Imo_
MNS FB
-7-* (67Z7,-
-7A7tJ1.-"IL—
DatelTirne
DatudTime
.Vendor: PaM Dnnlung Water_ UST_
PACE RCRA Waste _
Cooler TemP.LR}_.._.--.-......_.._.._.._.._.._..-.._.._.._.._.._.._..-.�.-....-......_.�..-
Filtration (0.45 um) b Unfiltered
PO11546721 Preservative MCL, ICE NNO] MCL ICE lCE ICE
d Filtered �n
- - Container Volume (mL)
Container Type
rc
40
500
40
500
500
_
4 e
w
u
9 m a a
fm=4lZ
reoem
.-0'o4
a¢ m r w°
i Y a
f° u r e cS
o
m
C N df
IN
y
N V- y
O
m
ui
J C7
6 u
x U
YI
4 N
LU
a
= d
t? .d..
c
U
o
~
Cusrprner to complero aft appropne[e non -shaded areas
c N
Collection Information
E
'n
Time
Printed Name
Signature
U
[j
V
X
3
3
NIA
8
X
3
3
WA
6
9
X
3
3
NIA
6
X
3
3
NIA
6
IL{
5
X
3
1
3
1
NIA
8
x
too
t
X
3
t
3
1
NIA
8
X
3
1
3
1
NIA
8
X
3
1
3
1
NIA
8
tq
��
X
3
1
3
1
NIA
8
X
3
1
3
1
NIA
8
D
0
0
0
4
0
0
0
TOTAL a CONTAINERS
30
6 0
30
0
6
0
D
0
0
1 0
1 0
0
72
atemme
'v
c
Sc
a R
e E
R
c
E'n
�a
u
c
U
Requested Turnaround
21 Days
14 Days
4 Days
Other
"Add. Cost Will Apply
Total 72
By: Datamme
gy; Datel Time
ck Opened 8 DatefTime
P y

Duke Energy Analytical Laboratory i
s 'DUKE
M.n caa. rncosa2 Buadlnn 7106) I
ENERGY
,�=ta Mae.rs r. y.. ,
Hunters.11k. N. [. 18076 I
ITea, 516u'245 I
_ + J _ _
'Project
Fax:. L. BTa-La ._._._._._.J
Name MNS LANDFILL Ail Permit #60-04 N—No:
Client Ethan Smith ! Bryan Moeller /
Courtney Murphy ! Ashley Healy
Operating Unit: 20036 Pmcasa: BLDFLGN Account:
Project: Activity ID: Facility ID:
Program I EQuIS Task Code: Sub-0rogram/Task Code:
Sample Description or ID
SAMPLE ID i
NUMBER i
2024016782 i MNS_MW-3BR
024016783 MNS_MW-4BR
024016784 MNS_MW-4BRP
024016786 i MKS_MW-11BR
2
2
2
CHAIN OF CUSTODY RECORD AND ANALYSIS_ REQUEST FORM
._._._._._._._._._._._._....................
._._...._._...._._._._._._.
Anal i--- Laboratory U3B Onl+.»._._-_-_._-_._._._._._._._._._._._._._._._._._._._._._._._.-
;order# J24070005
Matrix WATER
s.npe.onp�uenytrom
NC
sc_
—
Logged 0y
�]
SAMPLE PROGRAM
•
/
Ground Water_X
NPDES_
.Vander: Pace
,)
Drinking Water_
UST_
����
/
'._.._"_. _ .'.._.._ Coolsr,T�mP.ir)_.._.._.
_.._.._.._..�.._..—._.._.._.._.._.
RCRA Waste
Filtration (0.45 um)
4
Unfiltered
PO 11546721
Preservative
MCL, ICE
HNO3
HCL, SCE
loci
}CE
................
Container Volume (mL►
40
Sao
40
50o
Soo
Container Type
_ a
�mxw`y1`
t]
O
'
¢ w
Kon Q�
al
ri
xU
Customer to
Z
complete all appropriate n—shaded areas. a m
a yr
o z —
tCE do
C
Collection Information
£ A.0
T p1 .c
o°
a a g a` q
u Y n a.
e6 l] ai
?r y
YI U
`
,��
arl
Time
Printed Name
m a
ri C u
N(o
Q U)Date
�{
b in
x
'
3
'150006
Yuk 1r1K
x
3
1
3
1
Ql Crl�h
x
3
1
3
1
i 57-0
104U
x
3
1
3
1
Page 150 of 152
Page _3_ of 3_
DISTRIBUTION
ORIGINAL to LAB, COPY to CLIENT
b Filtered
C
a
0
r
0
I I I I I TOTAL t CONTAINERS I I 1 18 1 6 1 0 1 18 1 6 1 0 1 0 10 1 0 1 0 1 0 1 B 1 D 1 48 1
Re' uis _ _ _ _ .. _ _- DatelTime
Yfl
A By: ❑ !Time
y,
c
Requested TurnaroundAk
21 Days
elinquleh y Dat !Tim
y
Accepted Byy
m
a
C/
Days
Relinquished By DatelTme
Aceeptad By: OatefTime
. E
o m
a
14
9 Days
SeallLocked By DatBlTime
SeatedlLook Opened By DatalTme
m
- ro
E
.Other
'Add. Cast Will Appiy
comments' e - ilk. qR 1,�11 1(.57
U
Total❑

D�� Duke Energy Avail icat Laboratory
'# Mall Code MG03A2 laulldlrq 7405) I
y Rd
ENERGY' 1333,
W."Iu., 280
xrrrrl.r:.lu., N.C.n. c, xadre I
pal n5a245
I._._._._._ ....................... -_ -_ _ FW.L7a1675303d._._._._._.J
Project Name MNS LANDFILL #1Permit 960-04 Ph.-Noc
Client Ethan Smith! Bryan Moeller
Courtney Murphy 1 Ashley ally
Operating Unit: 20036 Pracesa: BLDFLGN Account:
Project: Activity ID: Facility ID:
Program I EQWS Task Cade: Sub-ProgramlTask Code:
SAMPLE ID
NUMBER
2024016786
2024016794
•. 2024019554 •.
l I
-----------------
< i
I
1 1
lE
l 1
E I
I 1
l i
I
I
I I
I l
1 1
l
l 1
1
I 1
�1
f 1
Sample Description or ID
TB 2oZq07"Z5-1300
CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
-._._._._._._._._._._._._._._._._._._._._.---------------------------------
Laboratory Use Only._._._._._._._._._._._._._._._._._._._._-_-----------------------_
Anal i._
# J24070005 Matrix WATER NC
sNrlFky adpinstlnp From $C_
By a T / e( �� /� SAMPLE PROGRAM
Ground Water_X_ NPDES _
P I Onnking Water_ UST_
PACE tool. T.m c RCRA Waste
_.._.._.._ ._.._.._.._.._.._. _eL.]_.._.._._-._.._.._.._.._.._.._.._.._.._.. ...............................
PO 115467/1 Filtration (0.45 um) Unfiltered
PreserVatiVe HCL, ICE HNO3 HCL, ICE ICE ICE
�.. ..._.._..___ E
Container Volume (mL) 40 500 40 Soo Soo
Container 1
CuMMOr to complete all appropriate non -shaded areas.
ype
m«=a
a
3
Ko e0] V
al
o
mrc
W
w
r«�a"m
uW=� m
oaf -aw
saxoga
ee0 allo u
X w� Ip
°m Od
"'
a
k—
Y�
KV
IL=
�IU
Ylv
2
a
09L
ti
°mas
��o� o
r—M En
Cti
au)
V a
X
3
1
3
1
X
3
1
3
1
/y
y
X
3
3
u/1L
Page 151 of 152
Page _1_ of _1_
DISTRIBUTION
ORIGINAL to LAB, COPY to CLIENT
r}
Filtered
0
F
I I TOTAL C CONTAINERS I I I 9 I 2 I 0 I B 1 2 I 0 0 10 l 0 l 0 10 I 0 I 0 I 22 I
Reli Ish
c DatelTime
Accepted By:
atelTim
Requested Turnaround
LJ
�F !
Relinquished B DatelTime
Accepted By: DatelTime
� v
m c
m �
a o
21 Days l �
Re Inqw yf5atetTime
Accepted By: DatelTime
m
E
m ?
a m
14 Days
SeallLocked By DatelTime
Seal"Look Opened By DatelTime
'7 Days
E w
u. y
- v
m
Comments
o
"Other
Add. Cost Will Apply
v
Total E

Page 152 of 152
McGuire Landfill #1
COMPOUNDS REQUIRED FOR 8260 ANALYSES NC SWSL Std. Required MRL*
* MRL must meet or be
COMPOUND
CASSNo.
below the SWSL Std.
Acetone
67-64-1
100
Acrylonitrile
107-13-1
200
Benzene
71-43-2
1
Bromochloromethane
74-97-5
3
Bromodichtoromethane
75-27-4
1
Bromoform; Tribromomethane
75-25-2
3
Carbon disulfide
75-15-0
100
Carbon tetrachloride
56-23-5
1
Chlorobenzene
108-90-7
3
Chloroethane; Ethyl chloride
75-00-3
10
Chloroform; Trichloromethane
67-66-3
5
Dibromochloromethane; Chlorodibromomethane
124-48-1
1
1.2-Dibromo-3-chlorpropane; DBCP
96-12-8
1
1,2-Dibromoethane; Ethylene dibromide, EDB
106-93-4
1
o-Dichlorobenzene; 1,2-Dichlorobenzene
95-50-1
5
p-Dichlorobenzene; 1,4-Dichlorobenzene
106-46-7
1
trans-1,4-Dichloro-2-butene
110-57-6
100
1,1-Dichloroethane; Ethylidene chloride
75-34-3
5
1,2-Dichloroethane; Ethlyene dichloride
1 07-06-2
1
1,1-Dichloroethylene; 1 -1 -Dichloroethene; Vinylidene chloride
75-35-4
5
cis- 1,2-Dichloroethylene; cis-1,2-Dichloroethene
156-59-2
5
trans-1,2-Dichloroethylene; trans-1,2-Dichloroethene
156-60-5
5
1,2-Dichlorpropane; Propylene dichloride
78-87-5
1
cis-1,3-Dichiorpropene
10061-01-
1
trans-1,3-Dichlorpropene
10061-02-
1
Ethylbenzene
100-41-4
1
2-hexanone; Methyl butyl ketone
591-78-6
50
Methyl bromide; Bromomethane
74-83-9
10
Methyl chloride; Chloromethane
74-87-3
1
Methylene bromide Dibromomethane
74-95-3
10
Methylene chloride; Dichloromethane
75-09-2
1
Methyl ethyl ketone; MEK; 2-Butanone
78-93-3
100
Methyl iodide; lodomethane
74-88-4
10
4-Methyl-2-peniancre; Methyl isobutyl isobutyl ketone
108-10-1
100
Styrene
100-42-5
1
1.1,1,2-Tetrachloreethane
630-20-6
5
1,1,2,2-Tetrachloroethane
79-34-5
1
Tetrachloroethylene; Tetracholorethene; Perchloroethylene
127-18-4
1
Toluene
108-88-3
1
1,1,1-Trochlorethane; Methylchtoroform
71-55-6
1
1,1,2-Trichloroethane
79-00-5
5
Trichloroethylene; Trichlorethene
79-01-6
1
Trichlorotluoromethane, CFC-11
75-69-4
1
1,2,3-Trichloropropane
96-18-4
1
Vinyl acetate
108-05-4
50
Vinyl chloride
75-01-4
1
xylenes
1330-20-
4

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 614257
Location: MW-11
BRML1 [ MNS Landfill 1 / MW-11 BR (LANDFILL)]
Collection
Start: 7/22/2024
13:20:00
Job: MNSGW20245
Collection
End: 7/22/2024
13:20:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.50E-01
0.00E+00
4.50E-01
<3
LLD OK
Beta
3.80E+00
4.11 E+00
3.07E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.59E+00
0.00E+00
5.59E+00
<15
<1000
LLD OK
Co-58
<5.22E+00
0.00E+00
5.22E+00
<15
<1000
LLD OK
Fe-59
<1.14E+01
0.00E+00
1.14E+01
<30
<400
LLD OK
Co-60
<7.72E+00
0.00E+00
7.72E+00
<15
<300
LLD OK
Zn-65
<8.65E+00
0.00E+00
8.65E+00
<30
<300
LLD OK
Zr-95
<1.07E+01
0.00E+00
1.07E+01
<15
<400
LLD OK
Nb-95
<4.71 E+00
0.00E+00
4.71 E+00
<15
<400
LLD OK
1-131
<6.38E+00
0.00E+00
6.38E+00
<15
LLD OK
Cs-134
<7.90E+00
0.00E+00
7.90E+00
<15
<30
LLD OK
Cs-137
<5.97E+00
0.00E+00
5.97E+00
<18
<50
LLD OK
Bala-140
<7.47E+00
0.00E+00
7.47E+00
<15
<200
LLD OK
Be-7
<4.19E+01
0.00E+00
4.19E+01
K-40
1.03E+02
6.14E+01
8.49E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<1.87E+01
0.00E+00
2.02E+02
<250
<20000
LLD OK
Report Generated @ 10/29/2024 13:02:23 EnRad Laboratory Page 1 of 21
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 1 of 23 - 10/29/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 614258
Location: MW-11D_ML1
[ MNS Landfill
1 / MW-11D
(LANDFILL)]
Collection
Start: 7/22/2024
12:30:00
Job: MNSGW20245
Collection
End: 7/22/2024
12:30:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
1.06E+00
7.23E-01
4.51 E-01
<3
LLD OK
Beta
5.30E+00
4.15E+00
3.07E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<4.53E+00
0.00E+00
4.53E+00
<15
<1000
LLD OK
Co-58
<6.29E+00
0.00E+00
6.29E+00
<15
<1000
LLD OK
Fe-59
<1.14E+01
0.00E+00
1.14E+01
<30
<400
LLD OK
Co-60
<4.63E+00
0.00E+00
4.63E+00
<15
<300
LLD OK
Zn-65
<9.91 E+00
0.00E+00
9.91 E+00
<30
<300
LLD OK
Zr-95
<9.57E+00
0.00E+00
9.57E+00
<15
<400
LLD OK
Nb-95
<8.00E+00
0.00E+00
8.00E+00
<15
<400
LLD OK
1-131
<6.87E+00
0.00E+00
6.87E+00
<15
LLD OK
Cs-134
<6.61 E+00
0.00E+00
6.61 E+00
<15
<30
LLD OK
Cs-137
<6.29E+00
0.00E+00
6.29E+00
<18
<50
LLD OK
Bala-140
<9.01 E+00
0.00E+00
9.01 E+00
<15
<200
LLD OK
Be-7
<4.89E+01
0.00E+00
4.89E+01
K-40
1.23E+02
5.86E+01
6.95E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<5.35E+00
0.00E+00
2.02E+02
<250
<20000
LLD OK
Report Generated @ 10/29/2024 13:02:23 EnRad Laboratory Page 2 of 21
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 2 of 23 - 10/29/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 614259
Location: MW-11_ML1
[MNS Landfill 1 / MW-11 (LANDFILL)]
Collection
Start: 7/22/2024
10:00:00
Job: MNSGW20245
Collection
End: 7/22/2024
10:00:00
GW Ground
Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.49E-01
0.00E+00
4.49E-01
<3
LLD OK
Beta
<3.07E+00
0.00E+00
3.07E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.87E+00
0.00E+00
5.87E+00
<15
<1000
LLD OK
Co-58
<6.08E+00
0.00E+00
6.08E+00
<15
<1000
LLD OK
Fe-59
<1.10E+01
0.00E+00
1.10E+01
<30
<400
LLD OK
Co-60
<3.03E+00
0.00E+00
3.03E+00
<15
<300
LLD OK
Zn-65
<1.32E+01
0.00E+00
1.32E+01
<30
<300
LLD OK
Zr-95
<9.95E+00
0.00E+00
9.95E+00
<15
<400
LLD OK
Nb-95
<5.23E+00
0.00E+00
5.23E+00
<15
<400
LLD OK
1-131
<7.21 E+00
0.00E+00
7.21 E+00
<15
LLD OK
Cs-134
<6.39E+00
0.00E+00
6.39E+00
<15
<30
LLD OK
Cs-137
<5.56E+00
0.00E+00
5.56E+00
<18
<50
LLD OK
Bala-140
<9.14E+00
0.00E+00
9.14E+00
<15
<200
LLD OK
Be-7
<4.45E+01
0.00E+00
4.45E+01
K-40
2.01 E+02
6.67E+01
6.02E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-5.9E+01
0.00E+00
2.01 E+02
<250
<20000
LLD OK
Report Generated @ 10/29/2024 13:02:23 EnRad Laboratory Page 3 of 21
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 3 of 23 - 10/29/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 614260
Location: MW-12D_ML1
[ MNS Landfill
1 / MW-12D (LANDFILL)]
Collection
Start: 7/22/2024
14:20:00
Job: MNSGW20245
Collection
End: 7/22/2024
14:20:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.50E-01
0.00E+00
4.50E-01
<3
LLD OK
Beta
3.73E+00
4.11 E+00
3.07E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.09E+00
0.00E+00
6.09E+00
<15
<1000
LLD OK
Co-58
<6.54E+00
0.00E+00
6.54E+00
<15
<1000
LLD OK
Fe-59
<8.81 E+00
0.00E+00
8.81 E+00
<30
<400
LLD OK
Co-60
<8.00E+00
0.00E+00
8.00E+00
<15
<300
LLD OK
Zn-65
<1.06E+01
0.00E+00
1.06E+01
<30
<300
LLD OK
Zr-95
<1.14E+01
0.00E+00
1.14E+01
<15
<400
LLD OK
Nb-95
<8.14E+00
0.00E+00
8.14E+00
<15
<400
LLD OK
1-131
<8.46E+00
0.00E+00
8.46E+00
<15
LLD OK
Cs-134
<6.85E+00
0.00E+00
6.85E+00
<15
<30
LLD OK
Cs-137
<6.59E+00
0.00E+00
6.59E+00
<18
<50
LLD OK
Bala-140
<9.55E+00
0.00E+00
9.55E+00
<15
<200
LLD OK
Be-7
<5.82E+01
0.00E+00
5.82E+01
K-40
1.19E+02
6.35E+01
8.16E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-1.9E+01
0.00E+00
2.02E+02
<250
<20000
LLD OK
Report Generated @ 10/29/2024 13:02:23 EnRad Laboratory Page 4 of 21
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 4 of 23 - 10/29/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 614261
Location: MW-12_ML1 [ MNS Landfill 1 / MW-12 (LANDFILL)]
Collection
Start: 7/22/2024
15:20:00
Job: MNSGW20245
Collection
End: 7/22/2024
15:20:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.50E-01
0.00E+00
4.50E-01
<3
LLD OK
Beta
<3.07E+00
0.00E+00
3.07E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.50E+00
0.00E+00
6.50E+00
<15
<1000
LLD OK
Co-58
<7.00E+00
0.00E+00
7.00E+00
<15
<1000
LLD OK
Fe-59
<1.35E+01
0.00E+00
1.35E+01
<30
<400
LLD OK
Co-60
<6.99E+00
0.00E+00
6.99E+00
<15
<300
LLD OK
Zn-65
<1.34E+01
0.00E+00
1.34E+01
<30
<300
LLD OK
Zr-95
<1.32E+01
0.00E+00
1.32E+01
<15
<400
LLD OK
Nb-95
<7.72E+00
0.00E+00
7.72E+00
<15
<400
LLD OK
1-131
<7.83E+00
0.00E+00
7.83E+00
<15
LLD OK
Cs-134
<7.49E+00
0.00E+00
7.49E+00
<15
<30
LLD OK
Cs-137
<6.98E+00
0.00E+00
6.98E+00
<18
<50
LLD OK
Bala-140
<9.21 E+00
0.00E+00
9.21 E+00
<15
<200
LLD OK
Be-7
<5.51 E+01
0.00E+00
5.51 E+01
K-40
2.55E+02
7.18E+01
4.67E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-5.4E+01
0.00E+00
2.02E+02
<250
<20000
LLD OK
Report Generated @ 10/29/2024 13:02:23 EnRad Laboratory Page 5 of 21
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 5 of 23 - 10/29/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 614262
Location: MW-13BRML1
[ MNS Landfill 1 / MW-13BR (LANDFILL)]
Collection
Start: 7/23/2024
12:45:00
Job: MNSGW20245
Collection
End: 7/23/2024
12:45:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.50E-01
0.00E+00
4.50E-01
<3
LLD OK
Beta
3.64E+00
4.11 E+00
3.07E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<4.50E+00
0.00E+00
4.50E+00
<15
<1000
LLD OK
Co-58
<5.33E+00
0.00E+00
5.33E+00
<15
<1000
LLD OK
Fe-59
<1.16E+01
0.00E+00
1.16E+01
<30
<400
LLD OK
Co-60
<5.68E+00
0.00E+00
5.68E+00
<15
<300
LLD OK
Zn-65
<1.18E+01
0.00E+00
1.18E+01
<30
<300
LLD OK
Zr-95
<1.05E+01
0.00E+00
1.05E+01
<15
<400
LLD OK
Nb-95
<5.70E+00
0.00E+00
5.70E+00
<15
<400
LLD OK
1-131
<6.36E+00
0.00E+00
6.36E+00
<15
LLD OK
Cs-134
<6.98E+00
0.00E+00
6.98E+00
<15
<30
LLD OK
Cs-137
<5.74E+00
0.00E+00
5.74E+00
<18
<50
LLD OK
Bala-140
<3.91 E+00
0.00E+00
3.91 E+00
<15
<200
LLD OK
Be-7
<4.51 E+01
0.00E+00
4.51 E+01
K-40
1.41 E+02
6.06E+01
7.00E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<7.52E+01
0.00E+00
1.92E+02
<250
<20000
LLD OK
Report Generated @ 10/29/2024 13:02:23 EnRad Laboratory Page 6 of 21
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 6 of 23 - 10/29/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 614263
Location: MW-13D_ML1
[ MNS Landfill
1 / MW-13D (LANDFILL)]
Collection
Start: 7/23/2024
13:05:00
Job: MNSGW20245
Collection
End: 7/23/2024
13:05:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.50E-01
0.00E+00
4.50E-01
<3
LLD OK
Beta
<3.07E+00
0.00E+00
3.07E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<7.39E+00
0.00E+00
7.39E+00
<15
<1000
LLD OK
Co-58
<5.93E+00
0.00E+00
5.93E+00
<15
<1000
LLD OK
Fe-59
<1.29E+01
0.00E+00
1.29E+01
<30
<400
LLD OK
Co-60
<7.02E+00
0.00E+00
7.02E+00
<15
<300
LLD OK
Zn-65
<1.17E+01
0.00E+00
1.17E+01
<30
<300
LLD OK
Zr-95
<1.03E+01
0.00E+00
1.03E+01
<15
<400
LLD OK
Nb-95
<6.11 E+00
0.00E+00
6.11 E+00
<15
<400
LLD OK
1-131
<6.08E+00
0.00E+00
6.08E+00
<15
LLD OK
Cs-134
<5.54E+00
0.00E+00
5.54E+00
<15
<30
LLD OK
Cs-137
<5.99E+00
0.00E+00
5.99E+00
<18
<50
LLD OK
Bala-140
<6.70E+00
0.00E+00
6.70E+00
<15
<200
LLD OK
Be-7
<4.13E+01
0.00E+00
4.13E+01
K-40
1.72E+02
7.04E+01
8.24E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<1.50E+01
0.00E+00
1.92E+02
<250
<20000
LLD OK
Report Generated @ 10/29/2024 13:02:23 EnRad Laboratory Page 7 of 21
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 7 of 23 - 10/29/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 614264
Location: MW-1D_ML1 [ MNS Landfill
1 / MW-1D (LANDFILL)]
Collection
Start: 7/23/2024 10:50:00
Job: MNSGW20245
Collection
End: 7/23/2024 10:50:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.50E-01
0.00E+00
4.50E-01
<3
LLD OK
Beta
4.16E+00
4.12E+00
3.07E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<7.16E+00
0.00E+00
7.16E+00
<15
<1000
LLD OK
Co-58
<5.18E+00
0.00E+00
5.18E+00
<15
<1000
LLD OK
Fe-59
<1.26E+01
0.00E+00
1.26E+01
<30
<400
LLD OK
Co-60
<6.15E+00
0.00E+00
6.15E+00
<15
<300
LLD OK
Zn-65
<1.35E+01
0.00E+00
1.35E+01
<30
<300
LLD OK
Zr-95
<8.27E+00
0.00E+00
8.27E+00
<15
<400
LLD OK
Nb-95
<5.04E+00
0.00E+00
5.04E+00
<15
<400
LLD OK
1-131
<7.26E+00
0.00E+00
7.26E+00
<15
LLD OK
Cs-134
<7.74E+00
0.00E+00
7.74E+00
<15
<30
LLD OK
Cs-137
<5.97E+00
0.00E+00
5.97E+00
<18
<50
LLD OK
Bala-140
<6.55E+00
0.00E+00
6.55E+00
<15
<200
LLD OK
Be-7
<4.80E+01
0.00E+00
4.80E+01
K-40
1.34E+02
5.94E+01
6.85E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-2.0E+01
0.00E+00
1.90E+02
<250
<20000
LLD OK
Report Generated @ 10/29/2024 13:02:23 EnRad Laboratory Page 8 of 21
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 8 of 23 - 10/29/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 614265
Location: MW-1_ML1
[MNS Landfill 1 / MW-1 (LANDFILL)]
Collection
Start: 7/23/2024 10:10:00
Job: MNSGW20245
Collection
End: 7/23/2024 10:10:00
GW Ground
Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.51 E-01
0.00E+00
4.51 E-01
<3
LLD OK
Beta
4.34E+00
4.13E+00
3.07E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<7.09E+00
0.00E+00
7.09E+00
<15
<1000
LLD OK
Co-58
<6.41 E+00
0.00E+00
6.41 E+00
<15
<1000
LLD OK
Fe-59
<1.45E+01
0.00E+00
1.45E+01
<30
<400
LLD OK
Co-60
<8.37E+00
0.00E+00
8.37E+00
<15
<300
LLD OK
Zn-65
<1.47E+01
0.00E+00
1.47E+01
<30
<300
LLD OK
Zr-95
<1.20E+01
0.00E+00
1.20E+01
<15
<400
LLD OK
Nb-95
<6.73E+00
0.00E+00
6.73E+00
<15
<400
LLD OK
1-131
<5.95E+00
0.00E+00
5.95E+00
<15
LLD OK
Cs-134
<7.97E+00
0.00E+00
7.97E+00
<15
<30
LLD OK
Cs-137
<6.45E+00
0.00E+00
6.45E+00
<18
<50
LLD OK
Bala-140
<8.09E+00
0.00E+00
8.09E+00
<15
<200
LLD OK
Be-7
<5.20E+01
0.00E+00
5.20E+01
K-40
1.32E+02
7.79E+01
1.12E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-2.0E+01
0.00E+00
1.92E+02
<250
<20000
LLD OK
Report Generated @ 10/29/2024 13:02:23 EnRad Laboratory Page 9 of 21
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 9 of 23 - 10/29/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 614266
Location: MW-2A_ML1 [ MNS Landfill 1 / MW-2A (LANDFILL)]
Collection
Start: 7/22/2024 10:40:00
Job: MNSGW20245
Collection
End: 7/22/2024 10:40:00
GW Ground Water
ALPHABETA
Gross Alpha
/ Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.51 E-01
0.00E+00 4.51 E-01
<3
LLD OK
Beta
6.61 E+00
4.18E+00 3.07E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<4.38E+00
0.00E+00 4.38E+00
<15
<1000 LLD OK
Co-58
<4.66E+00
0.00E+00 4.66E+00
<15
<1000 LLD OK
Fe-59
<1.33E+01
0.00E+00 1.33E+01
<30
<400 LLD OK
Co-60
<4.94E+00
0.00E+00 4.94E+00
<15
<300 LLD OK
Zn-65
<1.15E+01
0.00E+00 1.15E+01
<30
<300 LLD OK
Zr-95
<1.12E+01
0.00E+00 1.12E+01
<15
<400 LLD OK
Nb-95
<6.48E+00
0.00E+00 6.48E+00
<15
<400 LLD OK
1-131
<6.12E+00
0.00E+00 6.12E+00
<15
LLD OK
Cs-134
<6.17E+00
0.00E+00 6.17E+00
<15
<30 LLD OK
Cs-137
<5.56E+00
0.00E+00 5.56E+00
<18
<50 LLD OK
Bala-140
<8.68E+00
0.00E+00 8.68E+00
<15
<200 LLD OK
Be-7
<4.14E+01
0.00E+00 4.14E+01
K-40
1.19E+02
6.48E+01 8.76E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-4.2E+01
0.00E+00 1.89E+02
<250
<20000 LLD OK
Report Generated @ 10/29/2024 13:02:23
EnRad Laboratory
Page 10 of 21
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 10 of 23 - 10/29/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 614267
Location: MW-2D_ML1 [ MNS Landfill
1 / MW-2D (LANDFILL)]
Collection
Start: 7/22/2024 09:55:00
Job: MNSGW20245
Collection
End: 7/22/2024 09:55:00
GW Ground Water
ALPHABETA
Gross Alpha
/ Beta Analysis in Water and Effluent Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.40E-01
0.00E+00 4.40E-01
<3
LLD OK
Beta
3.39E+00
4.26E+00 3.19E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.09E+00
0.00E+00 6.09E+00
<15
<1000 LLD OK
Co-58
<4.89E+00
0.00E+00 4.89E+00
<15
<1000 LLD OK
Fe-59
<1.17E+01
0.00E+00 1.17E+01
<30
<400 LLD OK
Co-60
<6.02E+00
0.00E+00 6.02E+00
<15
<300 LLD OK
Zn-65
<1.41 E+01
0.00E+00 1.41 E+01
<30
<300 LLD OK
Zr-95
<1.11 E+01
0.00E+00 1.11 E+01
<15
<400 LLD OK
Nb-95
<6.84E+00
0.00E+00 6.84E+00
<15
<400 LLD OK
1-131
<8.19E+00
0.00E+00 8.19E+00
<15
LLD OK
Cs-134
<7.32E+00
0.00E+00 7.32E+00
<15
<30 LLD OK
Cs-137
<7.30E+00
0.00E+00 7.30E+00
<18
<50 LLD OK
Bala-140
<6.94E+00
0.00E+00 6.94E+00
<15
<200 LLD OK
Be-7
<5.94E+01
0.00E+00 5.94E+01
K-40
<1.51 E+02
0.00E+00 1.51 E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-1.8E+01
0.00E+00 1.92E+02
<250
<20000 LLD OK
Report Generated @ 10/29/2024 13:02:23
EnRad Laboratory
Page 11 of 21
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 11 of 23 - 10/29/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 614268
Location: MW-3BR_ML1 [ MNS Landfill 1 / MW-3BR (LANDFILL)]
Collection
Start: 7/22/2024 13:00:00
Job: MNSGW20245
Collection
End: 7/22/2024 13:00:00
GW Ground Water
ALPHABETA
Gross Alpha
/ Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
5.68E-01
6.42E-01 4.43E-01
<3
LLD OK
Beta
7.98E+00
4.35E+00 3.19E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.38E+00
0.00E+00 5.38E+00
<15
<1000 LLD OK
Co-58
<7.61 E+00
0.00E+00 7.61 E+00
<15
<1000 LLD OK
Fe-59
<1.12E+01
0.00E+00 1.12E+01
<30
<400 LLD OK
Co-60
<6.66E+00
0.00E+00 6.66E+00
<15
<300 LLD OK
Zn-65
<1.34E+01
0.00E+00 1.34E+01
<30
<300 LLD OK
Zr-95
<1.19E+01
0.00E+00 1.19E+01
<15
<400 LLD OK
Nb-95
<5.71 E+00
0.00E+00 5.71 E+00
<15
<400 LLD OK
1-131
<7.95E+00
0.00E+00 7.95E+00
<15
LLD OK
Cs-134
<7.84E+00
0.00E+00 7.84E+00
<15
<30 LLD OK
Cs-137
<5.84E+00
0.00E+00 5.84E+00
<18
<50 LLD OK
Bala-140
<8.26E+00
0.00E+00 8.26E+00
<15
<200 LLD OK
Be-7
<4.11 E+01
0.00E+00 4.11 E+01
K-40
2.21 E+02
8.86E+01 1.13E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<2.00E+01
0.00E+00 1.91 E+02
<250
<20000 LLD OK
Report Generated @ 10/29/2024 13:02:23
EnRad Laboratory
Page 12 of 21
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 12 of 23 - 10/29/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 614269
Location: MW-3D_ML1 [ MNS Landfill
1 / MW-3D (LANDFILL)]
Collection
Start: 7/22/2024 14:20:00
Job: MNSGW20245
Collection
End: 7/22/2024 14:20:00
GW Ground Water
ALPHABETA
Gross Alpha
/ Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
5.74E-01
6.40E-01 4.40E-01
<3
LLD OK
Beta
3.58E+00
4.26E+00 3.19E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.40E+00
0.00E+00 5.40E+00
<15
<1000 LLD OK
Co-58
<5.23E+00
0.00E+00 5.23E+00
<15
<1000 LLD OK
Fe-59
<1.36E+01
0.00E+00 1.36E+01
<30
<400 LLD OK
Co-60
<6.16E+00
0.00E+00 6.16E+00
<15
<300 LLD OK
Zn-65
<1.20E+01
0.00E+00 1.20E+01
<30
<300 LLD OK
Zr-95
<9.77E+00
0.00E+00 9.77E+00
<15
<400 LLD OK
Nb-95
<5.33E+00
0.00E+00 5.33E+00
<15
<400 LLD OK
1-131
<6.54E+00
0.00E+00 6.54E+00
<15
LLD OK
Cs-134
<7.41 E+00
0.00E+00 7.41 E+00
<15
<30 LLD OK
Cs-137
<5.81 E+00
0.00E+00 5.81 E+00
<18
<50 LLD OK
Bala-140
<6.17E+00
0.00E+00 6.17E+00
<15
<200 LLD OK
Be-7
<3.99E+01
0.00E+00 3.99E+01
K-40
<1.10E+02
0.00E+00 1.10E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<2.50E+00
0.00E+00 1.91 E+02
<250
<20000 LLD OK
Report Generated @ 10/29/2024 13:02:23
EnRad Laboratory
Page 13 of 21
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 13 of 23 - 10/29/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 614270
Location: MW-3_ML1 [ MNS Landfill 1 / MW-3 (LANDFILL)]
Collection
Start: 7/22/2024 13:25:00
Job: MNSGW20245
Collection
End: 7/22/2024 13:25:00
GW Ground Water
ALPHABETA
Gross Alpha
/ Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.40E-01
0.00E+00 4.40E-01
<3
LLD OK
Beta
<3.19E+00
0.00E+00 3.19E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.78E+00
0.00E+00 6.78E+00
<15
<1000 LLD OK
Co-58
<5.51 E+00
0.00E+00 5.51 E+00
<15
<1000 LLD OK
Fe-59
<1.15E+01
0.00E+00 1.15E+01
<30
<400 LLD OK
Co-60
<6.06E+00
0.00E+00 6.06E+00
<15
<300 LLD OK
Zn-65
<1.37E+01
0.00E+00 1.37E+01
<30
<300 LLD OK
Zr-95
<9.20E+00
0.00E+00 9.20E+00
<15
<400 LLD OK
Nb-95
<7.88E+00
0.00E+00 7.88E+00
<15
<400 LLD OK
1-131
<6.45E+00
0.00E+00 6.45E+00
<15
LLD OK
Cs-134
<7.42E+00
0.00E+00 7.42E+00
<15
<30 LLD OK
Cs-137
<6.45E+00
0.00E+00 6.45E+00
<18
<50 LLD OK
Bala-140
<7.24E+00
0.00E+00 7.24E+00
<15
<200 LLD OK
Be-7
<4.40E+01
0.00E+00 4.40E+01
K-40
1.24E+02
6.93E+01 9.53E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-5.0E+01
0.00E+00 1.89E+02
<250
<20000 LLD OK
Report Generated @ 10/29/2024 13:02:23
EnRad Laboratory
Page 14 of 21
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 14 of 23 - 10/29/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 614271
Location: MW-4BRRML1 [ MNS Landfill 1 / MW-4BRR (LANDFILL)]
Collection
Start: 7/23/2024 10:01:00
Job: MNSGW20245
Collection
End: 7/23/2024 10:01:00
GW Ground Water
ALPHABETA
Gross Alpha
/ Beta Analysis in Water and Effluent Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<5.90E-01
0.00E+00 5.90E-01
<3
LLD OK
Beta
1.09E+02
5.93E+00 3.84E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.54E+00
0.00E+00 6.54E+00
<15
<1000 LLD OK
Co-58
<3.81 E+00
0.00E+00 3.81 E+00
<15
<1000 LLD OK
Fe-59
<6.06E+00
0.00E+00 6.06E+00
<30
<400 LLD OK
Co-60
<6.86E+00
0.00E+00 6.86E+00
<15
<300 LLD OK
Zn-65
<1.15E+01
0.00E+00 1.15E+01
<30
<300 LLD OK
Zr-95
<9.18E+00
0.00E+00 9.18E+00
<15
<400 LLD OK
Nb-95
<5.34E+00
0.00E+00 5.34E+00
<15
<400 LLD OK
1-131
<6.88E+00
0.00E+00 6.88E+00
<15
LLD OK
Cs-134
<6.59E+00
0.00E+00 6.59E+00
<15
<30 LLD OK
Cs-137
<4.53E+00
0.00E+00 4.53E+00
<18
<50 LLD OK
Bala-140
<7.21 E+00
0.00E+00 7.21 E+00
<15
<200 LLD OK
Be-7
<4.30E+01
0.00E+00 4.30E+01
K-40
2.85E+02
8.70E+01 9.15E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-5.4E+01
0.00E+00 1.89E+02
<250
<20000 LLD OK
Report Generated @ 10/29/2024 13:02:23
EnRad Laboratory
Page 15 of 21
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 15 of 23 - 10/29/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 614272
Location: MW-4BR_ML1 [ MNS Landfill 1 / MW-4BR (LANDFILL)]
Collection
Start: 7/22/2024 16:00:00
Job: MNSGW20245
Collection
End: 7/22/2024 16:00:00
GW Ground Water
ALPHABETA
Gross Alpha
/ Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
7.36E-01
6.80E-01 4.54E-01
<3
LLD OK
Beta
2.73E+01
4.74E+00 3.19E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<7.44E+00
0.00E+00 7.44E+00
<15
<1000 LLD OK
Co-58
<5.90E+00
0.00E+00 5.90E+00
<15
<1000 LLD OK
Fe-59
<1.10E+01
0.00E+00 1.10E+01
<30
<400 LLD OK
Co-60
<7.29E+00
0.00E+00 7.29E+00
<15
<300 LLD OK
Zn-65
<1.28E+01
0.00E+00 1.28E+01
<30
<300 LLD OK
Zr-95
<1.27E+01
0.00E+00 1.27E+01
<15
<400 LLD OK
Nb-95
<6.99E+00
0.00E+00 6.99E+00
<15
<400 LLD OK
1-131
<9.36E+00
0.00E+00 9.36E+00
<15
LLD OK
Cs-134
<8.55E+00
0.00E+00 8.55E+00
<15
<30 LLD OK
Cs-137
<7.95E+00
0.00E+00 7.95E+00
<18
<50 LLD OK
Bala-140
<1.16E+01
0.00E+00 1.16E+01
<15
<200 LLD OK
Be-7
<5.83E+01
0.00E+00 5.83E+01
K-40
2.14E+02
9.41 E+01 1.24E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<4.95E+01
0.00E+00 1.89E+02
<250
<20000 LLD OK
Report Generated @ 10/29/2024 13:02:23
EnRad Laboratory
Page 16 of 21
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 16 of 23 - 10/29/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 614273
Location: MW-4DR_ML1 [ MNS Landfill 1 / MW-4DR (LANDFILL)]
Collection
Start: 7/23/2024 10:45:00
Job: MNSGW20245
Collection
End: 7/23/2024 10:45:00
GW Ground Water
ALPHABETA
Gross Alpha
/ Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.40E-01
0.00E+00 4.40E-01
<3
LLD OK
Beta
3.73E+00
4.27E+00 3.19E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.56E+00
0.00E+00 6.56E+00
<15
<1000 LLD OK
Co-58
<6.12E+00
0.00E+00 6.12E+00
<15
<1000 LLD OK
Fe-59
<1.34E+01
0.00E+00 1.34E+01
<30
<400 LLD OK
Co-60
<7.53E+00
0.00E+00 7.53E+00
<15
<300 LLD OK
Zn-65
<1.02E+01
0.00E+00 1.02E+01
<30
<300 LLD OK
Zr-95
<1.32E+01
0.00E+00 1.32E+01
<15
<400 LLD OK
Nb-95
<5.96E+00
0.00E+00 5.96E+00
<15
<400 LLD OK
1-131
<6.39E+00
0.00E+00 6.39E+00
<15
LLD OK
Cs-134
<7.06E+00
0.00E+00 7.06E+00
<15
<30 LLD OK
Cs-137
<5.04E+00
0.00E+00 5.04E+00
<18
<50 LLD OK
Bala-140
<8.18E+00
0.00E+00 8.18E+00
<15
<200 LLD OK
Be-7
<5.10E+01
0.00E+00 5.10E+01
K-40
2.22E+02
7.34E+01 7.73E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-7.5E+00
0.00E+00 1.91 E+02
<250
<20000 LLD OK
Report Generated @ 10/29/2024 13:02:23
EnRad Laboratory
Page 17 of 21
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 17 of 23 - 10/29/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 614274
Location: MW-4D_ML1 [ MNS Landfill
1 / MW-4D (LANDFILL)]
Collection
Start: 7/22/2024 16:05:00
Job: MNSGW20245
Collection
End: 7/22/2024 16:05:00
GW Ground Water
ALPHABETA
Gross Alpha
/ Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.38E-01
0.00E+00 4.38E-01
<3
LLD OK
Beta
<3.19E+00
0.00E+00 3.19E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.16E+00
0.00E+00 5.16E+00
<15
<1000 LLD OK
Co-58
<4.53E+00
0.00E+00 4.53E+00
<15
<1000 LLD OK
Fe-59
<1.03E+01
0.00E+00 1.03E+01
<30
<400 LLD OK
Co-60
<7.31 E+00
0.00E+00 7.31 E+00
<15
<300 LLD OK
Zn-65
<1.29E+01
0.00E+00 1.29E+01
<30
<300 LLD OK
Zr-95
<1.03E+01
0.00E+00 1.03E+01
<15
<400 LLD OK
Nb-95
<6.30E+00
0.00E+00 6.30E+00
<15
<400 LLD OK
1-131
<5.74E+00
0.00E+00 5.74E+00
<15
LLD OK
Cs-134
<6.62E+00
0.00E+00 6.62E+00
<15
<30 LLD OK
Cs-137
<5.57E+00
0.00E+00 5.57E+00
<18
<50 LLD OK
Bala-140
<7.91 E+00
0.00E+00 7.91 E+00
<15
<200 LLD OK
Be-7
<3.90E+01
0.00E+00 3.90E+01
K-40
7.53E+01
5.87E+01 8.81 E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-1.0E+01
0.00E+00 1.91 E+02
<250
<20000 LLD OK
Report Generated @ 10/29/2024 13:02:23
EnRad Laboratory
Page 18 of 21
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 18 of 23 - 10/29/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 614275
Location: MW-4R_ML1 [ MNS Landfill
1 / MW-4R (LANDFILL)]
Collection
Start: 7/23/2024 11:29:00
Job: MNSGW20245
Collection
End: 7/23/2024 11:29:00
GW Ground Water
ALPHABETA
Gross Alpha
/ Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.40E-01
0.00E+00 4.40E-01
<3
LLD OK
Beta
3.73E+00
4.27E+00 3.19E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.13E+00
0.00E+00 6.13E+00
<15
<1000 LLD OK
Co-58
<5.56E+00
0.00E+00 5.56E+00
<15
<1000 LLD OK
Fe-59
<1.16E+01
0.00E+00 1.16E+01
<30
<400 LLD OK
Co-60
<5.94E+00
0.00E+00 5.94E+00
<15
<300 LLD OK
Zn-65
<1.39E+01
0.00E+00 1.39E+01
<30
<300 LLD OK
Zr-95
<1.12E+01
0.00E+00 1.12E+01
<15
<400 LLD OK
Nb-95
<6.45E+00
0.00E+00 6.45E+00
<15
<400 LLD OK
1-131
<6.29E+00
0.00E+00 6.29E+00
<15
LLD OK
Cs-134
<5.54E+00
0.00E+00 5.54E+00
<15
<30 LLD OK
Cs-137
<5.03E+00
0.00E+00 5.03E+00
<18
<50 LLD OK
Bala-140
<6.77E+00
0.00E+00 6.77E+00
<15
<200 LLD OK
Be-7
<4.74E+01
0.00E+00 4.74E+01
K-40
1.12E+02
5.90E+01 7.53E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-1.2E+02
0.00E+00 1.89E+02
<250
<20000 LLD OK
Report Generated @ 10/29/2024 13:02:23
EnRad Laboratory
Page 19 of 21
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 19 of 23 - 10/29/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 614276
Location: MW-4_ML1 [ MNS Landfill 1 / MW-4 (LANDFILL)]
Collection
Start: 7/22/2024 15:21:00
Job: MNSGW20245
Collection
End: 7/22/2024 15:21:00
GW Ground Water
ALPHABETA
Gross Alpha
/ Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
5.66E-01
6.38E-01 4.39E-01
<3
LLD OK
Beta
<3.19E+00
0.00E+00 3.19E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.40E+00
0.00E+00 5.40E+00
<15
<1000 LLD OK
Co-58
<5.43E+00
0.00E+00 5.43E+00
<15
<1000 LLD OK
Fe-59
<1.19E+01
0.00E+00 1.19E+01
<30
<400 LLD OK
Co-60
<6.51 E+00
0.00E+00 6.51 E+00
<15
<300 LLD OK
Zn-65
<1.14E+01
0.00E+00 1.14E+01
<30
<300 LLD OK
Zr-95
<8.36E+00
0.00E+00 8.36E+00
<15
<400 LLD OK
Nb-95
<4.49E+00
0.00E+00 4.49E+00
<15
<400 LLD OK
1-131
<5.96E+00
0.00E+00 5.96E+00
<15
LLD OK
Cs-134
<6.28E+00
0.00E+00 6.28E+00
<15
<30 LLD OK
Cs-137
<4.88E+00
0.00E+00 4.88E+00
<18
<50 LLD OK
Bala-140
<9.56E+00
0.00E+00 9.56E+00
<15
<200 LLD OK
Be-7
<3.99E+01
0.00E+00 3.99E+01
K-40
<1.26E+02
0.00E+00 1.26E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<4.76E+01
0.00E+00 1.92E+02
<250
<20000 LLD OK
Report Generated @ 10/29/2024 13:02:23
EnRad Laboratory
Page 20 of 21
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 20 of 23 - 10/29/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 614277
Location: SW-1_ML1
[MNS Landfill 1 / SW-1 (LANDFILL)]
Collection
Start: 7/23/2024 11:20:00
Job: MNSGW20245
Collection
End: 7/23/2024 11:20:00
GW Ground Water
ALPHABETA
Gross Alpha
/ Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.40E-01
0.00E+00 4.40E-01
<3
LLD OK
Beta
<3.19E+00
0.00E+00 3.19E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.43E+00
0.00E+00 6.43E+00
<15
<1000 LLD OK
Co-58
<5.02E+00
0.00E+00 5.02E+00
<15
<1000 LLD OK
Fe-59
<1.02E+01
0.00E+00 1.02E+01
<30
<400 LLD OK
Co-60
<7.16E+00
0.00E+00 7.16E+00
<15
<300 LLD OK
Zn-65
<9.06E+00
0.00E+00 9.06E+00
<30
<300 LLD OK
Zr-95
<9.85E+00
0.00E+00 9.85E+00
<15
<400 LLD OK
Nb-95
<5.11 E+00
0.00E+00 5.11 E+00
<15
<400 LLD OK
1-131
<6.44E+00
0.00E+00 6.44E+00
<15
LLD OK
Cs-134
<4.78E+00
0.00E+00 4.78E+00
<15
<30 LLD OK
Cs-137
<5.14E+00
0.00E+00 5.14E+00
<18
<50 LLD OK
Bala-140
<8.12E+00
0.00E+00 8.12E+00
<15
<200 LLD OK
Be-7
<4.02E+01
0.00E+00 4.02E+01
K-40
<1.06E+02
0.00E+00 1.06E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<2.98E+01
0.00E+00 1.90E+02
<250
<20000 LLD OK
Report Generated @ 10/29/2024
13:02:23
EnRad Laboratory
Page 21 of 21
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 21 of 23 - 10/29/2024

.A.. n11KF CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
7 — Duke Energy EnRad Labaratdrlas
ENERGY MaD Coda MGQ3A2 tBuilding 14de1
EnRad Laboratory Use On
19
1JMS # MN5GW20245
Sample Class:
Drlglnsdng He C
i i
13339 Hagera Ferry Rd
DISTRIBUTION
Hurltersville, N. C. 2807B !
GRoIjNDWA7ER
sc
From —
ORIGINAL to IAB.
Logped BYAm nda P
Pope
Date a Tlare &aerie o7:3s
98C 875.5371 i
I }
swKs BxoGrwl
COPY to CLIENT
i_-•_ Fax: 198LiZ675.55fi9 ___ __ _j
eruun4 Wuer�
�dKS
Dnnking Wsrer_
i)Pmjsct Name;
2}Phone Ne:
Venef
cooler Temp ICI
MNS LANDFILL #1 PERMIT # 60-04
98u 875.6267
usr_
Rs•vi.=.ni 11.14'21.
ItCRA wens
3)Client
4}Fax No:
PC e
Bryan Moeller I Ethan Smith 1 Ashley Healy
"Preserr.:i•HCL
L Hr517, 3-HNo�
4alca :rNona
3)BuSIness Link: 20036
8)Pracew
71Resp. To:
Mike
J
BLDFLGN
MC88
Valium
E
$
1
Qo
S
_
=
8)Tmk ID: 9)Activay ID: I0"MI Code:
MGe3A3
CustomertD_camolete all aoorapriare Nam sr Anew areas_
M
IJ
c P .,
m
U
a
ry
Lae USE ONLY !
N
1eCollection Information
13Sample Description or ID
Lab
Z.
F
in
a
1!0
ID j
Date
Time
Signature
614265 i
MNS_MW-1
7AVEa[1616
x
1
1
1
1
1
1
1
1 3
614264 !
!.
MNS_MW-1D
7
1650
x
1
1
1 1
3
614266
MNS_MW-2A
7IZZAq
frivg
x
1
1
1
3
614267
MNS_MW-2D
Q
x
7
1
1
3
614270
MNS_MW-3
MNS_MW-3D
7
ZA W4I
Ltze
x
x
1
1 1
1
1
1
1
1
3
3
614269 1
614276 S.
MNS_MW-4
7
x
11
1
1
3
614275 ; g
MNS_MW-4R
y ►;
({21
x
1
1
1
3
614274 v
MNS_MW-41)
7Za 4
x
1
1
1
3
614273 i
MNS_MW-4DR
7 Z,t(
+QHJ
x
1
1
1
3
614259 B
•6
MINIS _MW-11
'7lowx
1
1
1
3
514258 : e
MNS MW-11D
MNS—MW-12
]
7 tW =1340
D
3
SK5
x
x
1
1
1
1
1
1
3
3
614261 it
614260 iE
MNS_MW-12D
7 2 ZK
4U
W
x
1
1
1
3
614277 f
MNS SW-1
7 t,
{
x
11111
1
3
:U
1
Customer to sign & date below
21IRaiin uish By FF Smith
DatelTme ■ccepted
Violet M. GregaryDatenims
7 G
t 1
�1 I e I u
r-i
aRequsstad Turnaround
21)Re lnquished By
a imB
ccepted Bir
W arrime
146spe J
21)Rellnqulshad By
Datemme Accepted
By:
DA*Mme
y®ga
S
'7 Days
23)Soallocked Sy
bawnMe SaaledlLock
Opened By
Data .n.
g a48
Hr
24)C om rnents; SAMPLES NOT ACIDIFIED IN THE FIELD - EH Smith
E
9
'Other
!y
Add Cast WIll Apply
EnRad Laboratories - Page 22 of 23 - 10/29/2024

!_ ry ivr. CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
�...�.� i Duke Energy EnRad Laboratories i
ENERGY. Mail Code M003A2 (Building 7405)
EnRad Lahardto Use Only
_ aPage 2
L1MS # MNSGW2024$
Sample Class:
GROUNDWATER
O a9
FromORIGINAL
He ,
Ec
i
13339 Nagers FerryRd
__2_ of
DISTRIBUTION
Huntersvllfe, N. C. 28070 !
to LAB.
Loyyed By Amanda Pope
pare a T[me W2e124 07:36
{960) 876.6371
aeNPL6 PRaOruw
COPY to CLIENT
i_ Fax: t9B0�876di669 •._••_.___•j
Ground water-=_
WIDEs—
O-" water
1)Pr "t Name:
2)Phone No:
vonder
Cooler Temp (Cl
MNS LANDFILL #1 PERMIT # 64-04
UST _
fxcre+. waste_
Rewmed 17/14/20
3)Client
Wax No:
PO P
Bryan IMoellerI Ethan Smith IAshl" Neaiy
"Preas+v.:ti�ICL
2-IA0, 3-mo,
4=ke S+Nona
5)aualnees Unit: 20036
6)Process:
7)Resp, To:
MR P
BLDFLGN
MC00
Volume
E
c
E
E
B)Task ID: 9)Aetivity ID: 10)M0 Code:
MG03A3
i..--,_
&�t6IR.Q#p�o cemafete alf aaR,lfrR[I�QH4drR� areas.
W.. � i
03
a
C-6
LAB USE ONLY!
¢
N
'Collection Information
1i i "Sample Description or ID
2
F
D
Lab ID !
Date
Time
Signature
t!'
614268
MNS_MW 3BR
7
j O4)
x
1
1
1
3
614272 !
MNS_MW-4BR
7 4
00
x
4
1
7
3
614271 •,
MNS_MW-4BRR
$
/Qs f
x
1
1
1
3
614257
MNS_MW-11 BR
a(
Z a
x
1
1
1
3
614263
MNS_MW-13D
�t7
5
x
1
1
1
3
614262 i
MNS—MW-13Bf2
1214SX
1
1 1
1
3
Ig
:g
:E
•a
:s
rL
�Q
:8
iE
t�
Ig
o
14T-
.`a
a
_
Customer to sign & date below
21)R*hnuisb&d Rx E ah
DteMrneAccepted
y:
!
n3l�
VioletYG epo
A3
nRvquevwd Turnaround
3jRellnpuished By
c
a
74 Days It
21Pelinq u ished By
Detel7ime Accepted
sy:
DateMme
logy
a
n w
'7 pays
23pallLocked By
Datomme SealedlLock
Opened By
Detemme
a;
- 441 Nr
6 •
24)Com m e nts: SAMPLES NOT ACIDIFIED IN THE FIELDD FH Smithy-
Et
�-
! j p�/J F, j
fAw- (ev, �}� �' q❑ rnNj�i�IC1E ` il,t�yl �� • ! I•S7
1"
i
'amer
/
w
O
Add. Cost WIII Apply
EnRad Laboratories - Page 23 of 23 - 10/29/2024