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PRLF594_20240723_RI Summary Report_SUM-A
REMEDIAL INVESTIGATION SUMMARY REPORT Old Richmond County Landfill Rockingham, Richmond County, North Carolina Site ID No. NONCD0000594 State Contract No. 017012 Task Order 594SUM-A Prepared By: Submitted To: North Carolina Department of Environmental Quality Division of Waste Management ______________________________ Inactive Hazardous Sites Branch Laura I. de Sosua Superfund Section Staff Scientist Pre-Regulatory Landfill Unit 1646 Mail Service Center Raleigh, North Carolina 27699-1646 ______________________________ Timothy D. Grant, P.G. Project Manager N.C. Professional Geologist #1412 Prepared By: ATC Associates of North Carolina, P.C. 2725 East Millbrook Road, Suite 121 Raleigh, North Carolina 27604 Phone: (919) 871-0999 Fax: (919) 871-0335 July 23, 2024 Old Richmond County LF Task Order 594SUM-A 1 TABLE OF CONTENTS Contents 1.0 INTRODUCTION ....................................................................................................... 4 2.0 SENSITIVE ENVIRONMENTS ................................................................................ 5 3.0 GEOPHYSICAL SURVEY ........................................................................................ 5 4.0 SITE GEOLOGY AND HYDROGEOLGY ............................................................. 6 5.0 NATURAL AND ANTHROPOGENIC BACKGROUND ...................................... 6 6.0 WASTE DISPOSAL AREA........................................................................................ 8 7.0 MEDIA CHARACTERIZATION ............................................................................. 8 7.1 Above Ground Vapor Survey ............................................................................... 8 7.2 Waste Characterization......................................................................................... 9 7.2.1 Surface Waste ................................................................................................ 9 7.2.2 Waste Characterization Borings ............................................................... 10 7.2.3 Waste and Soil Analytical Results ............................................................. 10 7.3 Evaluation of Existing Soil Cover for use as the Permanent Cover System 111 7.4 Surface Water/Sediment/Seep Investigation ................................................... 122 7.5 Groundwater Investigation ................................................................................. 13 7.5.1 Temporary Monitoring Well Installation ................................................. 13 7.5.2 Groundwater Sampling ............................................................................ 133 7.5.3 Comparison of Background Concentrations to Groundwater Results 133 7.6 Potable Water Supply Well Sampling ............................................................... 14 7.6.1 Potable Water Supply Well Analytical Results ....................................... 14 7.7 Landfill Gas Probe Installation and Monitoring ............................................ 144 7.7.1 Landfill Gas Survey .................................................................................. 144 7.7.2 Landfill Gas Probe Sampling .................................................................... 15 7.7.3 Landfill Gas Probe Analytical Results ...................................................... 15 8.0 EVALUATION OF PRELIMINARY SOIL REMEDIATION GOALS (PSRGS) .............................................................................................. 155 9.0 DEQ RISK CALCULATOR RESULTS ............................................................... 155 10.0 SOLE USE STATEMENT AND CERTIFICATION .......................................... 16 11.0 REFERENCES ........................................................................................................ 16 Old Richmond County LF Task Order 594SUM-A 2 FIGURES Figure 1 Site Map Figure 2 Waste Disposal Area Delineation Borings Figure 3 Above Ground Vapor Survey Figure 4 Waste and Soil Boring Exceedances Figure 5 Soil Cover Thickness Figure 6 Waste Thickness Figure 7 Evaluation of Existing Soil Cover Figure 8 Surface Water/Sediment/Spring Investigation Figure 9 Groundwater Investigation – Potentiometric Contour Map Figure 10 Groundwater Investigation - Exceedance Map Figure 11 Potable Water Supply Well Map Figure 12 Landfill Gas Probe Results TABLES Table 1 Waste Disposal Area Delineation Borings Table 2 Above Ground Vapor Survey Table 3 Waste and Soil Characterization Borings Table 4 Evaluation of Existing Soil Cover Table 5 Surface Water – Natural Attenuation Parameters Table 6 Surface Water Investigation Table 7 Sediment Investigation Table 8 Well Construction Table 9 Groundwater Investigation Table 10 Potable Water Supply Well Sampling Table 11 Landfill Gas Survey Results Table 12 Soil Gas Probe Results APPENDICES Appendix A Risk Calculator Appendix B Certification Old Richmond County LF Task Order 594SUM-A 3 ACRONYMS ATC ATC Associates of North Carolina, P.C. bgs below ground surface ft feet IHSB Inactive Hazardous Sites Branch NCDEQ North Carolina Department of Environmental Quality NCDOT North Carolina Department of Transportation DPH Division of Public Health DPT Direct Push Technology DWR Division of Water Resources IDW Investigative Derived Waste NURE National Uranium Reconnaissance Evaluation NWI National Wetland Inventory PCBs Polychlorinated Biphenyls PID Photoionization Detector PIN Parcel Identification Number PSRG Preliminary Soil Remediation Goal RI Remedial Investigation SVOC Semivolatile Organic Compound TCE Trichloroethylene TICs Tentatively Identified Compounds TMW Temporary Monitoring Well μg/m3 micrograms per cubic meter Unit Pre-Regulatory Landfill Unit USDA United States Department of Agriculture USEPA United States Environmental Protection Agency USGS United States Geological Survey VOC Volatile Organic Compound WDA Waste Disposal Area WSW Water Supply Well 2B Standard Title 15A NCAC 2B .0200 Surface Water Standard 2L Standard Title 15A NCAC 2L .0202 Groundwater Standard Old Richmond County LF Task Order 594SUM-A 4 1.0 INTRODUCTION ATC Associates of North Carolina, P.C. (ATC) has prepared this Remedial Investigation (RI) Summary Report for the Old Richmond County Landfill in Rockingham, Richmond County, North Carolina (ID No. NONCD0000594). This report provides an executive summary of remedial investigation activities performed to delineate areas of concern at the subject site to date. For the purposes of this report, the waste disposal area (WDA) as defined by the results of the previous delineation phase will be referred to collectively as the "Site." The property under investigation that the site contains will be referred to as the "subject property." The site is located in Rockingham, North Carolina to the east of Poppyseed Drive. The waste disposal area lies entirely within one parcel (Richmond County Parcel Identification Number [PIN] 746502854954). A topographic and a site map are included as Figure 1, respectively. ATC performed the field activities at the site between April 2019 and January 2021. All work was performed at the subject property located at 166 Poppy Seed Drive. The field activities included the following tasks, itemized by Task Order: 594DP-1–Waste Disposal Area Delineation. 594DP-2–Above-Ground Vapor Survey. 594DP-3–Waste Characterization. 594DP-4–Groundwater Investigation. 594DP-5–Landfill Gas Probe Installation and Sampling. 594DP-6–Soil Cover Investigation. 594DP-7–Surveying. 594DP-8– Included site mapping for surface debris and tree coverage, additional waste and 1,4-dioxane delineation, additional landfill gas probe installation and sampling, review of background data, and preparation of risk calculators. 594DP-10 – Additional landfill gas probe sampling, gas probe field screening, and gas probe abandonment. 594DP-11 - Remaining gas probe abandonment. 594FP-3 – Sensitive environment, water supply well, and surface water survey. 594WS-1 – Water supply well sampling. Old Richmond County LF Task Order 594SUM-A 5 2.0 SENSITIVE ENVIRONMENTS ATC performed a review of potential sensitive environments within 500 feet of the approximated waste disposal boundary. The review was initiated after additional soil borings to further define the waste boundary from the 2012 geophysical investigation delineation boundary. This allowed for the waste delineation boundary to define the boundary conditions of the 500-foot radius. The survey was performed in accordance with guidelines provided by the Inactive Hazardous Sites Branch (IHSB) Guidelines for Addressing Pre-Regulatory Landfills and Dumps, November 2015. Wetlands were identified within 500 feet of the approximated waste disposal boundary. According to the National Wetlands Inventory (NWI) map shows wetlands both northeast and southeast of the Site as shown on Figure 1. The one to the northeast is identified as freshwater forested/shrub wetland while the one to the southeast is classified as a riverine wetland. This is also shown as a perennial stream on the United States Geologic Survey (USGS) topographic map. A small spring, shown on Figure 1, is located southeast of WDA-A, drains into this feature. The spring channel is shallow (2-3 inches) and is not well defined, ranging from 1 to 3 feet in width. No other sensitive environments were identified within 500 feet of the waste disposal boundary. 3.0 GEOPHYSICAL SURVEY ATC conducted a file review of the 2012 Geophysical Report prepared by Geo Solutions Ltd. (GeoSolutions, 2012). The 2012 geophysical report was associated with investigations for the former NCDOT facility, located east of the Old Richmond County Landfill. Findings from the geophysical survey identified two areas of waste, Area A and Area B. Area A represents the more significant portion of the existing waste and covers approximately 5.5 acres. Area B has a linear structure less than one acre in size and lies just south of Area A. Based on the GPR data of the survey, the waste is detected at a minimum depth of 8 feet below ground surface. Old Richmond County LF Task Order 594SUM-A 6 4.0 SITE GEOLOGY AND HYDROGEOLGY According to the North Carolina Geologic Map (1985), the site is located within the Middendorf Formation of the Inner Coastal Plain Physiographic Province. The Cretaceous Middendorf Formation is comprised commonly of cross-bedded, very coarse- to fine- grained gray to pale gray feldspathic quartz sands and sandstone with kaolinitic clay and sandy clay lenses. This formation is fluvial in origin. The United States Department of Agriculture (USDA) indicates the site is predominantly Walkulla and Candor soils. These soils are comprised of sand, loamy sand, and sandy clay loam (USDA, 2019). The Black Creek Aquifer is a regional aquifer that extends through the area of the subject property. The regional hydrogeological framework of the subject site is consistent with that of the North Carolina Sandhills. The Sand Hills and consists of gently rolling topography. The Black Creek confining unit is thinnest in the Sand Hills area; approximately 10 feet thickness (CLP Services, 2012). Based on data collected from monitoring wells, groundwater at the site is encountered at depths ranging from approximately 8.83 to 31.39 feet (ft) below ground surface (bgs). Groundwater at the site flows towards the southeast, towards the wetlands thar lie southeast of the site. 5.0 NATURAL AND ANTHROPOGENIC BACKGROUND Because of limited space on the site property to obtain background samples without the influence of the landfill, ATC reviewed the available public records to determine natural inorganic background levels for the area. The following sources were used for determining natural background concentrations: United States Geological Survey (USGS) National Uranium Reconnaissance Evaluation (NURE) database for surface water and sediment, North Carolina Department of Health and Human Services, Division of Public Health (DPH) well water data for groundwater in Richmond County, Analytical results from TMW-4 (groundwater) and from soil samples collected from soil borings outside of the waste Disposal Area (WDA), Old Richmond County LF Task Order 594SUM-A 7 Reports from the assessment at North Carolina Department of Transportation (NCDOT) Asphalt Site #3/Brown Paving (NONCD0002164). Background sediment concentrations were obtained from nearby sample locations in the NURE database. This data indicates that arsenic concentrations in sediment ranged from 1 to 3 mg/kg and iron concentrations ranged from 10,000 to 20,000 mg/kg. For background soil concentrations, analytical data from the 10 soil borings (SB-11 to SB-15 and SB-17 to SB-21) advanced outside of the WDA was used. Borings SB-10 and SB-16 were advanced within the WDA. Arsenic concentrations in these samples ranged from 0.442 milligrams/kilograms (mg/kg) to 9.21 mg/kg, iron concentrations ranged from 2,030 to 14,600 mg/kg, and total chromium ranged from 2.75 to 18.5 mg/kg. Thallium was not detected in any of the samples nor were background concentrations available from public records. Groundwater data from the remedial investigation conducted at the former NCDOT site located west of the Site shows arsenic concentrations ranged from non-detect to 900 ug/L; iron ranged from 74 to 1,250,000 ug/L, and manganese ranged from 4.0 to 313 ug/L. A report (Report of Findings, CLP Services, P.C., October 2012) does indicate that groundwater flow from the NCDOT is radial with flow towards the southwest and southeast towards the Site. A trichloroethylene (TCE) plume is shown extending under Highway 220 which is located west of the Site. TCE was not detected in the monitoring wells installed between the highway and the Site and TCE was not detected in any groundwater samples collected from the Site or any of the water supply wells sampled. TMW-4 was located upgradient from the WDA and therefore could be considered representative of background. The following constituents were detected in the well: iron – 141 ug/L, manganese – 51.2 ug/L. The DPH well database Richmond County shows iron concentrations ranging from 25 to 12,350 ug/L and manganese ranging from 15 to 2,260 ug/L. The samples from this database were likely collected from various depths and may not represent the surficial aquifer. There was no resource available to determine background air concentrations. Old Richmond County LF Task Order 594SUM-A 8 6.0 WASTE DISPOSAL AREA Fifty-three soil borings were advanced at eighteen locations (B-1 through B-18) at the site using hollow-stem auger drilling methods to delineate the waste boundary. Borings were advanced to 10 or 15 feet below ground surface (bgs) or until waste or refusal was encountered. At locations around the residential structure not accessible to a drill rig, eleven hand auger borings (HA-1 through HA-11) were advanced to a depth of 6 feet or until waste or refusal was encountered. If waste was encountered, then another boring or borings were advanced away from the suspected waste boundary until no waste was encountered. Conversely, if no waste was found, then the borings were advanced in direction of the waste boundary until waste was encountered. Drill cuttings were screened for volatile organic compounds (VOCs) using a photoionization detector (PID). No elevated PID readings were recorded in any of the delineation borings. Borings indicate that two separate waste disposal areas are on the site property (PIN 746502854954). Waste Disposal Area A (WDA-A) is the larger of the two and covers an area of approximately 4.7 acres with a maximum thickness of 6.5 feet and an average thickness of 3.4 feet (approximately 26,000 cubic yards of waste); Waste Disposal Area B (WDA-B) covers approximately 0.2 acres with a maximum thickness of 10 feet and an average of 5.6 feet (approximately 1,900 cubic yards of waste). Soil and waste descriptions for the delineation borings are included in Table 1, and waste delineation boring locations are shown on Figure 2. 7.0 MEDIA CHARACTERIZATION 7.1 Above Ground Vapor Survey An above-ground vapor survey was conducted across the waste disposal area as identified during waste disposal boundary delineation, and around the adjacent house. To perform the survey, ATC used field instruments to measure target landfill gases and other parameters at 38 locations on 100-foot centers. The target parameters included methane, oxygen, carbon dioxide, hydrogen sulfide, volatile organic compounds (VOCs), temperature, humidity, and barometric pressure. Each instrument was calibrated per the manufacturer’s specifications and Old Richmond County LF Task Order 594SUM-A 9 bump tests were conducted to ensure proper calibration. No elevated concentrations were detected with the exception of a small VOC detection (0.2 ppm) at AGV-35. The sample locations are shown in Figure 3. Field readings are summarized on Table 2. 7.2 Waste Characterization 7.2.1 Surface Waste A site walkover was conducted to document the volume and type of surface waste, assess the composition of a berm noted in a previous report, and determine the number of mature trees to address during the remedy. One small area of exposed waste, identified as Surface Waste-1 on Figure 1, was noted during the site walkover. The waste was located in some depressions and consisted of metal scraps and broken glass. Due to the small volume, it is not likely to be sufficient enough to be considered for recovery and recycling. The berm, identified as Berm-1 on Figure 1, was approximately 30 ft x 30 ft and slightly elevated above the surrounding ground. Hand augers were advanced along the berm and encountered refusal, likely on some debris, at a depth of one foot. The abandoned cars seen in Figure 1, in the northeast corner of WDA-A, have been removed as of August 2020. The site walkover performed in August 2020 also included an assessment of the existing ground cover of the WDA. The majority of WDA-A is wooded with approximately 1.5 acres of yard or pasture. There are approximately 250 mature trees in WDA-A. Mature tree is defined as a tree that is greater than six inches in diameter. WDA-B is approximately 0.2 acres and contains a mix of trees and grass and is located in the front yard. There are approximately 20 mature trees in this area. The wooded areas can be seen in Figure 1. As shown in Figure 1, a residential structure is partially located on WDA-B. The structure is a mobile home which rest on a foundation of cinder blocks and has a wooden porch on both the north and east sides. The foundation is enclosed by aluminum siding. Behind the house and to the east, there are two storage sheds that rest directly on the ground and have dirt floors. There is a third smaller shed constructed of aluminum, at the southeast corner of the house Old Richmond County LF Task Order 594SUM-A 10 that is on a wood floor and foundation. The house is on County water and has a septic field southeast of the structure. 7.2.2 Waste Characterization Borings Nine soil borings (SB-1 through SB-21) were advanced within WDA-A and two soil borings (SB-10 and SB-16) were advanced within WDA-B using solid-stem auger and direct-push drilling methods to characterize the waste. Once results were received from the initial delineation, further sampling was conducted to delineate the extent of contamination outside of the known WDA. Eleven soil borings (SB-11 through SB-15, SB-17 though SB-21) were advanced using direct push technology. Waste consisted of mainly cloth, glass, metal, plastic, and various other debris. A summary of the lithologic descriptions is included in Table 1 and boring locations are shown on Figure 2. For each of the borings noted above, a photoionization detector (PID) was used to screen the zone within each sample core. Only the location of the first sample collected in each boring was based on the PID readings. The PID readings are included in Table 3. Samples were submitted to a North Carolina certified laboratory for the following analysis: Volatile Organic Compounds (VOCs) by EPA Method 8260 1,4 Dioxane by Method 8260 SIM. Semi-volatile organic compounds (SVOCs) by EPA Method 8270 Inorganic hazardous substances by EPA Method 6020 (antimony, arsenic, beryllium, cadmium, chromium, copper, iron, lead, manganese, nickel, selenium, silver, thallium, and zinc) Mercury by Method 7470/7471 7.2.3 Waste and Soil Analytical Results 2-Butanone was detected in one of the trip blanks that accompanied the second phase of sampling. It was also detected in one of the laboratory method blanks indicating that it is a laboratory contaminant. It was also detected in some of the samples, but all concentrations were below the Residential PSRG. Concentrations of lead, zinc, and toluene were detected in Old Richmond County LF Task Order 594SUM-A 11 one field blank. Acetophenone was detected in both a field blank and equipment blank and one of the soil samples but at concentrations well below the Residential PSRG. The following were detected in one or more samples above the Residential Preliminary Soil Remediation Goal (PSRGs) and natural background levels discussed in Section 2.0: Parameter Sample ID Iron SB-3(6-8), SB-3(9-10), SB-6(4.5-5.5), SB-6(5.5-6.5), SB-16(6-7), SB-16 (9-10), SB-20(7-8). SB-21(5-6), SB-21(7-8) Hexavalent Chromium SB-1(6-7), SB-1(7-8), SB-2(6.5-8.5), SB-3(6-8), SB-3(9-10), SB-4(4-5), SB-4(5-8), SB-5(3-4), SB-6(4.5-5.5), SB-7(6-7), SB-7(7-8) PAHs SB-2(4.5-5.5), SB-2 (6.5-8.5), SB-4(4-5), SB-5(3-4), SB-5(6-8), SB-5(8-9) Waste and soil laboratory analytical results are summarized in Table 3 and exceedances above background are shown in Figure 4. Data from these borings and the soil cover borings, discussed in Section 7.2.2, was used to create the soil cover thickness figure presented in Figure 5 and the waste thickness figure shown in Figure 6. This figure was also used to determine the volume of waste for each WDA which is presented below: Area A – 26,000 cubic yards Area B – 1,900 cubic yards 7.3 Evaluation of Existing Soil Cover for use as the Permanent Cover System To evaluate the use of the existing cover soils, 25 hand auger borings were advanced across the WDA. The borings were advanced to a depth of three feet or until waste was encountered. If the soil cover thickness was greater than two feet, samples were collected at 6 and 18 inches. Samples were submitted to a North Carolina certified laboratory for the same methods mentioned in Section 7.2.2, except the following was additionally included: Hexavalent Chromium by Method 218.1/7199 Old Richmond County LF Task Order 594SUM-A 12 Ammonia by EPA Method SM 4500. Nitrate and Sulfate by EPA Methods 300 Polychlorinated Biphenyls (PCBs) by Method 8082 Arsenic was detected in all samples, except for SC-3 (1.5), at a concentration above the Residential PSRG. The concentrations range from 0.595 mg/kg to 3.84 mg/kg, which is within the range for background discussed in Section 2.0. Thallium was detected in six samples at concentrations above the Residential PSRG. Background concentrations for Thallium were not available. The four samples with the highest total chromium concentration were also analyzed for hexavalent chromium. Hexavalent chromium was detected in one sample (SC-8 0.5’) at a concentration of 0.547 mg/kg which is above Residential PSRG. The analytical results are summarized in Table 4 and are shown on Figure 7. All borings that were advanced within the waste boundary were used to determine soil cover thickness and are included in Table 1. Soil cover ranged from 12 inches to over 36 inches and the distribution of the soil cover thickness is shown in Figure 5. 7.4 Surface Water/Sediment/Seep Investigation Surface water and sediment samples were collected from the two locations shown in Figure 8. To reduce turbidity, surface water samples for metals analysis were initially placed in an unpreserved container and allowed to settle. Field parameters are provided in Table 5. Field instruments were calibrated in field each day prior to sample collection. Surface water/sediment samples were submitted to the laboratory for analyses by the methods outlined in Section 7.2.2. Iron was the only constituent detected in concentrations in both surface water samples above the 2B Standard. The concentration was below the background concentration for iron in the NURE database. Given the shallow depth of the spring, it is applicable to use the NURE database as representative of background. The sediment analytical results were compared to the Inactive Hazardous Sites Branch (IHSB) Residential PSRG. Arsenic was detected in both samples at a concentration above the Old Richmond County LF Task Order 594SUM-A 13 residential PSRG Standard but below the naturally occurring background concentrations from the NURE database. Surface water and sediment locations are shown in Figure 8. A summary of the detected constituents are provided in Tables 6 and 7. 7.5 Groundwater Investigation 7.5.1 Temporary Monitoring Well Installation Seven temporary monitoring wells (TMW-1 through TMW-7) were installed at the site. Depth to groundwater ranged from 8 to 31 feet below ground surface and groundwater flow is to the southeast towards the stream discussed in Section 4.0. Groundwater elevation data and well construction details are summarized in Table 8. Well locations and the potentiometric contour map are shown on Figure 9. After sample collection, the wells were properly abandoned by the North Carolina licensed drilling contractor. 7.5.2 Groundwater Sampling Groundwater samples were collected from the each of the temporary monitoring wells for analysis of VOCs plus tentatively identified compounds (TICs), SVOCs plus TICs, metals including mercury, 1,4-Dioxane, PCBs, ammonia, nitrate, and sulfate. Samples were also collected for hexavalent chromium analysis but were placed on hold until the total chromium results were known. Laboratory data is summarized in Table 9 and exceedances above 2L and/or background concentrations are presented in Figure 10. 7.5.3 Comparison of Background Concentrations to Groundwater Results Manganese and iron were detected in one or more samples in concentrations above the 2L Standard. Manganese was detected above the 2L Standard in the background well (TMW-4), but since this well is located approximately 100 feet upgradient of the WDA, concentrations in this well are considered background. TMW-1 and TMW-2 concentrations were above the TMW-4 concentration. Chromium was detected in two wells but at concentrations below the 2L Standard so hexavalent chromium samples were not analyzed. Old Richmond County LF Task Order 594SUM-A 14 7.6 Potable Water Supply Well Sampling A groundwater sample was collected from the water supply well located at 183 Northside Drive (WSW-4). The location is shown in Figure 11. The sample was analyzed for the same methods mentioned in Section 7.3, except the Polychlorinated Biphenyls (PCBs) by Method 8082 was not included in the analysis. 7.6.1 Potable Water Supply Well Analytical Results ATC has compared the results of the sampling to the United States Environmental Protection Agency (EPA) Maximum Contaminant Levels (MCLs) and the Title 15A NCAC 2L .0202 Groundwater Standards (2L Standards). The results of the sampling indicated that concentrations of manganese were detected above the 2L Standard in both the parent and duplicate samples collected from the 183 Northside Drive well. The concentrations of iron and sulfate detected in this sample were below the EPA MCL and the 2L Standards. Water supply well laboratory data is summarized in Table 12. 7.7 Landfill Gas Probe Installation and Monitoring Eighteen landfill gas probes (GP-1 through GP-18) were installed by a North Carolina licensed drilling contractor using DPT methods. The locations of gas probes are shown on Figure 12. 7.7.1 Landfill Gas Survey A landfill gas survey was conducted on the existing gas probes and the newly installed gas probe. Methane was not detected during either phase of the investigation. VOC concentrations ranged from 0.0 to 2.2 ppm. Landfill gas survey data are summarized in Table 11 and are included on Figure 12 ATC attempted to sample gas probes GP-10, GP-15, GP 18, and GP-17 in January 2022, however these gas probes were either removed by the property owner or damaged. All other gas probes were property abandoned at the site (14 total). Old Richmond County LF Task Order 594SUM-A 15 7.7.2 Landfill Gas Probe Sampling ATC collected soil gas samples from the 13 landfill gas probes (GP-1 through GP-4 and GP- 10 through GP-18). The samples were analyzed for VOCs by EPA Method TO-15. 7.7.3 Landfill Gas Probe Analytical Results Only bromodichloromethane and chloroform were detected in concentrations above the IHSB Residential Soil Gas Screening Levels (SGSLs) in GP-17 sample. GP-17 is located near the sheds in the backyard and is well outside of the WDA. Since these constituents are also found in treated potable water, their presence is likely from use of county water for irrigation. Also, a small above-ground pool was previously located in the backyard. The former location of the pool is shown in Figure 12. Other constituents were detected above laboratory detection limits, but concentrations were below their respective SGSL. Soil gas analytical results are summarized in Table 12 and are shown in Figure 12. 8.0 EVALUATION OF PRELIMINARY SOIL REMEDIATION GOALS (PSRGS) Soil and sediment analytical results for this RI summary report were initially compared to unrestricted-use Preliminary Soil Remediation Goals (PSRGs) established by the North Carolina Inactive Hazardous Sites Branch (IHSB). 9.0 DEQ RISK CALCULATOR RESULTS Based on the conceptual site model for this site, ATC concluded there is sufficient data to evaluate risk to specific exposure pathways identified for the site. ATC has completed a risk assessment utilizing the NCDEQ’s Risk Calculator. The entire site was designated as Exposure Unit #1. The risk calculator assessed risks for soil combined pathways for a resident, non-residential worker, construction worker, recreator, and trespasser, groundwater use for a resident and non-residential worker, surface water exposure for a recreator or trespasser, and indoor inhalation for a resident or non-residential worker. For each pathway, the exposure point concentrations were the maximum concentration for each detected compound for the most conservative scenario. Furthermore, the indoor Old Richmond County LF Task Order 594SUM-A 16 inhalation pathway was assessed using soil gas data collected at the site. Risk exceedances were identified for a resident for the soil combined pathway. Risk exceedances were not identified for the remaining pathways. The risk calculator is included in Appendix A. 10.0 SOLE USE STATEMENT AND CERTIFICATION The report was prepared solely for the intended use of NCDEQ Pre-Regulatory Landfill Unit performed in the scope of work for Task Order 594SUM-A. Use of this document for other purposes is at the sole risk of the user. The certification is included in Appendix B. 11.0 REFERENCES ATC Associates of North Carolina, P.C. Remedial Investigation-Water Supply Well Sampling- Letter Report–594WS-1. August 24, 2020. ATC Associates of North Carolina, P.C. Remedial Investigation-Additional Media Sampling–594DP-9. November 26, 2021. ATC Associates of North Carolina, P.C. Letter Report for Task–594DP-10. February 23, 2022. CLP Services, P.C. (CLP) Report of Findings In Situ Biorememdiation Pilot Testing UIC Permit No. WI0600032 & Underground Injection Control Permit Application for Full-Scale Treatment & Corrective Action Plan. NCDOT Priority Site No. 3, Richmond County, North Carolina, October 2012. Geo Solutions Limited, Inc. Geophysical Evaluation of a NCDOT site near Rockingham, North Carolina. September 17, 2012. North Carolina Geological Survey, 1985, Geologic Map of North Carolina: Raleigh, North Carolina Department of Natural Resources and Community Development, Geological Survey Section, scale 1:500,000, in color. United States Department of Agriculture (USDA), 2019, Web Soil Survey (WSS). TABLES TABLE 1 WASTE DISPOSAL AREA DELINEATION BORINGS Old Richmond County LF NONCD0000594 Rockingham, Richmond County, North Carolina BORING ID SOIL COVER THICKNESS (FEET BGS) WASTE THICKNESS (FEET) WASTE TYPE LITHOLOGIC DESCRIPTION DATE OF BOREHOLE ADVANCEMENT BOREHOLE DEPTH (FEET BGS) LATITUDE LONGITUDE B-1A ≥10 0 NONE Tan and reddish tan SAND 4/22/2019 10 34.9999117 -79.7750471 B-1B ≥10 0 NONE Organic topsoil, brownish tan, tan, and reddish tan SAND, reddish tan CLAYEY SAND 4/22/2019 10 34.9999077 -79.7750137 B-1C 2 Refusal Cloth, Glass, Metal, Plastic Organic topsoil, reddish tan SAND, brownish tan CLAYEY SAND 4/22/2019 2 34.9998915 -79.7749340 B-2A ≥10 0 NONE Reddish tan, tan, and tannish brown SAND 4/22/2019 10 34.9995103 -79.7749962 B-2B ≥10 0 NONE Tannish brown and tan SAND, reddish brown CLAYEY SAND 4/22/2019 10 34.9995473 -79.7749452 B-2C 2.5 Refusal Plastic, Glass Reddish tan SAND, reddish tan CLAYEY SAND 4/22/2019 2.5 34.9995745 -79.7749115 B-3A ≥10 0 NONE Reddish brown and tannish brown SAND, reddishtan CLAYEY SAND 4/22/2019 10 34.9996603 -79.7743691 B-3B 3 Refusal Metal, Aluminum Can, Rubber, Yarn, Plastic Brown organic topsoil, tannish brown SAND, reddish tan CLAYEY SAND 4/22/2019 3 34.9996084 -79.7743536 B-3C ≥15 0 NONE Brown and brownish Tan SILTY SAND, tan SAND, brownish red CLAYEY SAND 5/9/2019 15 34.9995359 -79.7743277 B-3D 4 8 Metal, Plastic, Glass, Fabric Brown SILTY SAND, reddish brown SAND, red and light brown CLAYEY SAND 5/9/2019 20 34.9994895 -79.7743043 B-3E ≥15 0 NONE Brown, tannish brown, and reddish brown SILTY SAND, tan SAND 5/15/2019 15 34.9994170 -79.7742411 B-4A ≥10 0 NONE Reddish tan and tan SAND, reddish brown CLAYEY SAND 4/22/2019 10 34.9997949 -79.7737628 B-4B 1.25 Refusal Glass, Rusted Metal, Plastic Brown organic topsoil, tannish brown SAND 4/22/2019 1.25 34.9998358 -79.7737622 B-5A 1.5 Refusal Rubber, Plastic, Tile Tannish brown SAND 4/22/2019 1.5 34.9999711 -79.7732864 B-5B 1 Refusal Plastic, Cloth Tannish brown SAND 4/22/2019 1.5 34.9999097 -79.7732426 B-5C ≥10 0 NONE Tannish brown and tan SAND, reddish tan CLAYEY SAND 4/22/2019 10 34.9998547 -79.7731614 B-6A ≥10 0 NONE Brown organic topsoil, tan and tannish brown SAND 4/22/2019 10 34.9999571 -79.7725490 B-6B 1 Refusal Yarn Reddish tan SAND 4/22/2019 1 35.0000292 -79.7726133 B-7A 1 Refusal Cloth, Yarn Brown organic topsoil, reddish tan SAND 4/22/2019 1 35.0002147 -79.7723644 B-7B ≥10 0 NONE Brown organic topsoil, reddish tan SAND 4/22/2019 10 35.0001731 -79.7722829 B-8A ≥10 0 NONE Brown organic topsoil, reddish brown CLAYEY SAND, reddish brown SAND, light brown Tan SILTY SAND 4/23/2019 10 35.0005106 -79.7725290 B-8B 5.5 1.5*Insulation, Yarn, Cloth, Tile Brown organic topsoil, reddish brown CLAYEY SAND, reddish brown and tannish brown SAND 4/23/2019 7 35.0005088 -79.7726271 B-9A ≥10 0 NONE Reddish brown and tannish brown SAND 4/23/2019 10 35.0007788 -79.7727000 B-9B 1 2*Plastic, Glass, Metal, Yarn or Insulation, Plastic Straws Tannish brown and brown SAND 4/23/2019 3 35.0007193 -79.7727235 B-10A ≥10 0 NONE Brown SAND, reddish brown CLAYEY SAND, pink to reddish brown CLAYEY SILTY SAND 4/23/2019 10 35.0006027 -79.7731421 B-10B ≥5 0 NONE Brown SAND, tannish brown SAND, reddish brown CLAYEY SAND 4/23/2019 5 35.0006531 -79.7731241 B-10C 3 1.5*Rusted Metal Brown SAND, reddish brown CLAYEY SAND 4/23/2019 4.5 35.0007207 -79.7731683 B-11A 1.25 Refusal Plastic, Glass, Metal, Insulation Tannish brown SAND 4/23/2019 1.25 35.0005197 -79.7737975 B-11B ≥10 0 NONE Tannish brown and tan SAND, reddish brown CLAYEY SAND 4/23/2019 10 35.0005941 -79.7737628 B-12A 2.5 Refusal Plastic, Rusted Metal, Concrete Dark brown organic topsoil, tannish brown and brown SAND 4/23/2019 2.5 35.0004684 -79.7740105 B-12B ≥10 0 NONE Light brown organic topsoil, tannish brown, tan, and reddish brown SAND, reddish brown CLAYEY SAND 4/23/2019 10 35.0005392 -79.7740036 B-13A 1.5 Refusal Rubber Tannish brown and brown SAND 4/23/2019 1.5 35.0003231 -79.7745956 B-13B ≥10 0 NONE Tan and tannish brown SAND 4/23/2019 10 35.0003887 -79.7746111 B-14A 1.5 0.5*Plastic, Rusted Metal, Brick, Glass Brown SAND 4/23/2019 2 35.0002359 -79.7748378 B-14B ≥10 0 NONE Brown organic topsoil, tan and tannish brown SAND 4/23/2019 10 35.0002950 -79.7748678 B-15A 2 10 Plastic, Glass, Fabric, Metal, Yarn Brown SILTY SAND, tan and reddish tan SAND, brownish red CLAYEY SAND 5/9/2019 15 34.9993367 -79.7744977 B-15B ≥15 0 NONE Dark brownand brown SILTY SAND, tan and reddish tan SAND 5/9/2019 15 34.9994761 -79.7745365 B-16A ≥10 0 NONE Brown, tannish brown, reddish brown SILTY SAND 5/13/2019 10 34.9992651 -79.7749610 B-16B 6 10 Plastic, Fabric, Metal, Yarn, Rock Fragments Brown, tannish brown, reddish brown SILTY SAND, pinkish brown SILTY SAND 5/13/2019 20 34.9993370 -79.7747265 B-16C ≥15 0 NONE Brown, tannish brown, reddish brown SILTY SAND, tan SAND 5/13/2019 15 34.9992483 -79.7747123 B-16D ≥10 0 NONE Brown and tannish brown SILTY SAND, tan SAND 5/15/2019 10 34.9995154 -79.7746849 B-17A 4 4 Glass, Metal, Burnt Wood Brown and tanish brown SAND, reddish brown SILTY SAND 7/20/2020 15 34.9994990 -79.7741292 B-17B ≥15 0 NONE Brown, tannish brown, tan SAND, reddish brown SILTY SAND 7/20/2020 15 34.9995129 -79.7740291 B-17C 4 4 Plastic, Glass, Metal Tannish brown SAND, reddish brown SILTY SAND 7/20/2020 15 34.9995745 -79.7740419 B-17D 3 4 Plastic, Metal, Yarn, Cloth Brown SAND 7/20/2020 7 34.9996244 -79.7739648 B-17E 2.5 5.5 Metal, Glass, Plastic, Yarn Brown SAND 7/20/2020 8 34.9996667 -79.7739038 B-17F ≥15 0 NONE Brown and tan SAND 7/20/2020 15 34.9996749 -79.7739807 B-17G ≥15 0 NONE Brown and tan SAND 7/20/2020 15 34.9997724 -79.7738017 B-17H ≥15 0 NONE Brown and tan SAND 7/21/2020 15 34.9996417 -79.7740993 B-17I 4 2*Metal, Glass, Burnt Wood Brown and dark brown SAND 7/21/2020 6 34.9995878 -79.7739506 B-17J ≥15 0 NONE Brown and tan SAND 7/21/2020 15 34.9995412 -79.7739426 B-18A ≥10 0 NONE Brown SAND, reddish brown CLAYEY SAND 7/24/2020 10 35.0008036 -79.7730047 TABLE 1 WASTE DISPOSAL AREA DELINEATION BORINGS Old Richmond County LF NONCD0000594 Rockingham, Richmond County, North Carolina BORING ID SOIL COVER THICKNESS (FEET BGS) WASTE THICKNESS (FEET) WASTE TYPE LITHOLOGIC DESCRIPTION DATE OF BOREHOLE ADVANCEMENT BOREHOLE DEPTH (FEET BGS) LATITUDE LONGITUDE B-18B 4 1*Plastic, Metal, Glass Brown SAND, dark brown SILTY SAND 7/24/2020 5 35.0007880 -79.7729987 HA-1 2.5 Refusal Metal, Glass Brown SAND 7/20/2020 2.5 34.9996672 -79.7738665 HA-2 2 0.5*Metal, Glass Brown SAND 7/20/2020 2.5 34.9996373 -79.7738662 HA-3 ≥2.5 0 NONE Brown, tan, and gray SAND, reddish brown CLAYEY SAND, white and reddish white SANDY SILT 7/20/2020 2.5 34.9996036 -79.7738662 HA-4 ≥6 0 NONE Brown and tan SAND 7/20/2020 6 34.9995619 -79.7738634 HA-5 ≥6 0 NONE Tannish brown and tan SAND 7/20/2020 6 34.9995251 -79.7738937 HA-6 ≥6 0 NONE Brown and tan SAND 7/20/2020 6 34.9994944 -79.7738598 HA-7 1.5 0.5*Glass, Styrofoam, Metal Brown SAND 7/20/2020 2 34.9996899 -79.7738417 HA-8 6 0 NONE Tannish brown and tan SAND 7/20/2020 6 34.9997145 -79.7738010 HA-9 ≥6 0 NONE Brown and tan SAND 7/20/2020 6 34.9997011 -79.7737351 HA-10 ≥6 0 NONE Brown and tan SAND 7/20/2020 6 34.9996344 -79.7737499 HA-11 ≥6 0 NONE Brown and tan SAND 7/20/2020 6 34.9996907 -79.7737923 SB-1 4 4 Plastic, Glass, Metal Brownish and reddish tan SAND, reddish tan, brown, and gray SILTY SAND 5/6/2019 15 34.9996619 -79.7747945 SB-2 2.5 6.5 Metal, Glass, Plastic, Cloth Brown SAND, Brown and reddish tan CLAYEY SAND 5/6/2019 15 35.0001860 -79.7748127 SB-3 5 5 Metal, Glass, Plastic Brown and tan SAND, reddish tan, white, and pink CLAYEY SAND, dark brown and black SILTY SAND, reddish brown SANDY CLAY 5/6/2019 15 35.0003501 -79.7742016 SB-4 2 6 Metal, Glass, Plastic, Yarn, Cloth, Rubber Brown and reddish tan SAND, reddish tan and brown CLAYEY SAND 5/6/2019 15 34.9998971 -79.7738348 SB-5 3 5 Metal, Plastic, Tile, Rubber Brownish tan and tan SAND, Reddish tan, brown, dark brown SILTY SAND, white, pink, and tan CLAYEY SAND 5/7/2019 15 35.0001794 -79.7735926 SB-6 2.5 4 Metal, Plastic, Cloth Brown SAND, Reddish tan, brown, and white SILTY SAND, tan, white, and pink CLAYEY SAND 5/7/2019 15 35.0004915 -79.7734991 SB-7 5 2.5 Metal, Plastic, Cloth, Yarn Brown and reddish tan SAND, grayish brown SILTY SAND 5/7/2019 15 35.0006331 -79.7728195 SB-8 2 3 Aluminum, Plastic, Yarn Brown, reddish tan, and tan SAND, reddish tan and brown SILTY SAND 5/8/2018 15 35.0001331 -79.7726894 SB-9 1.5 5.5 Metal, Plastic, Fabric, Yarn, Glass Brown, tan, and light brown SAND, reddish tan SILTY SAND 5/8/2019 25 35.0000023 -79.7732490 SB-10 4 4 Burnt paper, Plastic Brown, dark brown, and black SAND 7/21/2020 8 34.9995932 -79.7739564 SB-11 ≥10 0 NONE Brown, reddish brown, and tan SAND 7/22/2020 10 34.9995811 -79.7750917 SB-12 ≥11 0 NONE Brown and tan SAND 7/22/2020 11 34.9999581 -79.7749990 SB-13 ≥11 0 NONE Brown and tan SAND 7/22/2020 11 35.0002501 -79.7749584 SB-14 ≥11 0 NONE Brown and tan SAND 7/22/2020 11 35.0003525 -79.7747540 SB-15 ≥11 0 NONE Brown and tan SAND 7/22/2020 11 35.0006700 -79.7740353 SB-16 5 3 Glass, Plastic, Burnt wood Brown SAND, dark brown and black SILTY SAND, brown CLAYEY SAND 7/23/2020 10 34.9994227 -79.7744081 SB-17 ≥10 0 NONE Brown and tan SAND 7/23/2020 10 34.9995381 -79.7733536 SB-18 2 3 Glass, Plastic, Burnt wood Brown and tan SAND, dark brown and black SILTY SAND 7/23/2020 10 34.9997145 -79.7737922 SB-19 ≥10 0 NONE Tan SAND, brown CLAYEY SAND 7/23/2020 10 34.9999664 -79.7722003 SB-20 ≥12 0 NONE Brown SAND, reddish brown CLAYEY SAND 7/23/2020 12 35.0005709 -79.7722033 SB-21 ≥12 0 NONE Brown and tan SAND, reddish brown CLAYEY SAND 7/23/2020 12 35.0008169 -79.7730091 Notes 1.) bgs = below ground surface 2.) * - unable to determine total waste thickness due to refusal PID CO2 O2 H2S Barometric Pressure Temp Relative Humidity (ppm)(%Vol)(%LEL)(%Vol)(%Vol)(ppm)(inches Hg)(°F)(%) AGV-1 4/25/2019 14:08 0.0 0.0 0 0.0 20.2 0 29.34 81.5 21.3 AGV-2 4/25/2019 14:10 0.0 0.0 0 0.0 20.1 0 --- AGV-3 4/25/2019 14:13 0.0 0.0 0 0.0 20.1 0 --- AGV-4 4/25/2019 14:16 0.0 0.0 0 0.0 20.1 0 --- AGV-5 4/25/2019 14:18 0.0 0.0 0 0.0 20.1 0 --- AGV-6 4/25/2019 14:20 0.0 0.0 0 0.0 20.1 0 --- AGV-7 4/25/2019 14:22 0.0 0.0 0 0.0 20.1 0 --- AGV-8 4/25/2019 14:24 0.0 0.0 0 0.0 20.3 0 --- AGV-9 4/25/2019 14:25 0.0 0.0 0 0.0 20.2 0 --- AGV-10 4/25/2019 14:27 0.0 0.0 0 0.0 20.4 0 --- AGV-11 4/25/2019 14:33 0.0 0.0 0 0.0 20.3 0 --- AGV-12 4/25/2019 14:36 0.0 0.0 0 0.0 20.3 0 --- AGV-13 4/25/2019 14:38 0.0 0.0 0 0.0 20.4 0 --- AGV-14 4/25/2019 14:42 0.0 0.0 0 0.0 20.4 0 --- AGV-15 4/25/2019 14:44 0.0 0.0 0 0.0 20.4 0 --- AGV-16 4/25/2019 14:47 0.0 0.0 0 0.0 20.5 0 --- AGV-17 4/25/2019 14:49 0.0 0.0 0 0.0 20.5 0 --- AGV-18 4/25/2019 14:52 0.0 0.0 0 0.0 20.5 0 --- AGV-19 4/25/2019 14:54 0.0 0.0 0 0.0 20.4 0 --- AGV-20 4/25/2019 14:56 0.0 0.0 0 0.0 20.5 0 --- AGV-21 4/25/2019 15:00 0.0 0.0 0 0.0 20.6 0 --- AGV-22 4/25/2019 15:02 0.0 0.0 0 0.0 20.6 0 --- AGV-23 4/25/2019 15:05 0.0 0.0 0 0.0 20.6 0 29.34 73.8 31.6 AGV-24 4/25/2019 15:07 0.0 0.0 0 0.0 20.6 0 --- AGV-25 4/25/2019 15:10 0.0 0.0 0 0.0 20.6 0 --- AGV-26 4/25/2019 15:13 0.0 0.0 0 0.0 20.7 0 --- AGV-27 4/25/2019 15:15 0.0 0.0 0 0.0 20.7 0 --- AGV-28 4/25/2019 15:18 0.0 0.0 0 0.0 20.7 0 --- AGV-29 4/25/2019 15:22 0.0 0.0 0 0.0 20.6 0 --- AGV-30 4/25/2019 15:24 0.0 0.0 0 0.0 20.6 0 --- AGV-31 4/25/2019 15:27 0.0 0.0 0 0.0 20.5 0 --- AGV-32 4/25/2019 15:29 0.0 0.0 0 0.0 20.3 0 --- AGV-33 4/25/2019 15:33 0.0 0.0 0 0.0 20.4 0 --- AGV-34 4/25/2019 15:36 0.0 0.0 0 0.0 20.5 0 --- AGV-35 4/25/2019 15:38 0.2 0.0 0 0.0 20.5 0 --- AGV-36 4/25/2019 15:41 0.0 0.0 0 0.0 20.5 0 --- AGV-37 4/25/2019 15:45 0.0 0.0 0 0.0 20.6 0 --- AGV-38 4/25/2019 15:47 0.0 0.0 0 0.0 20.5 0 --- Notes: 1.) LEL = Lower Explosive Limit. Readings which exceeded the LEL of 5% for Methane are recorded as ">." 2.) Hg = Mercury. 3.) ppm = Parts Per Million. SAMPLE ID DATE TIME CH4 Page 1 of 1 Rockingham, Richmond County, North Carolina NONCD0000594 Old Richmond County LF ABOVE GROUND VAPOR SURVEY TABLE 2 TABLE 3 WASTE and SOIL CHARACTERIZATION ANALYTICAL RESULTS Old Richmond County Landfill NONCD0000594 Rockingham, Richmond County, North Carolina SAMPLE ID SB-1 (6-7)P SB-1 (7-8)B SB-1 (8-9)N SB-2 (4.5-5.5)P SB-2 (6.5-8.5)B DUP-1 SB-2 (9.5-10.5)N SB-3 (6-8)P SB-3 (9-10)B SB-3 (10-11)N SB-4 (4-5)P SB-4 (5-8)B SB-4 (8-9)N Latitude Longitude PID Readings 0.5 0.1 0.0 4.7 2.2 2.2 1.2 30.7 16.9 3.5 20.6 35.1 3.9 Sample Date 05/06/19 05/06/19 05/06/19 05/06/19 05/06/19 05/06/19 05/06/19 05/06/19 05/06/19 05/06/19 05/07/19 05/07/19 05/07/19 Antimony 6.3 0.262 J 0.245 J 0.201 J 0.959 0.399 J 0.709 BDL 0.395 J 0.202 J BDL 0.971 2.12 BDL Arsenic 0.68 1.38 1.64 2.00 2.79 2.17 2.37 1.48 4.55 4.59 3.63 1.50 1.34 1.30 Beryllium 31 0.241 J 0.237 J 0.127 J 0.207 J 0.172 J 0.187 J 0.154 J 0.171 J 0.164 J 0.146 J 0.0933 J 0.0798 J BDL Cadmium 14 0.177 J 0.273 J 0.0881 J 0.607 0.245 J 0.265 J BDL 0.153 J BDL BDL 0.205 J 0.862 BDL Total Chromium 23,000 12.2 18.0 8.13 11.1 8.78 9.21 5.60 21.2 22.5 12.9 5.66 6.61 3.56 Copper 630 10.6 8.19 6.14 25.5 8.34 8.27 3.66 9.70 11.0 3.72 14.9 15.0 1.42 Iron 11,000 5190 5790 7970 14300 8610 9150 5160 15700 16200 8530 9060 6340 2480 Lead 400 42.2 58.4 10.5 42.1 30.5 26.4 4.01 10.1 9.44 4.36 8.76 24.8 1.32 Manganese 380 25.6 20.5 25.2 77.2 36.4 42.9 16.3 21.7 18.0 6.25 31.7 30.8 1.60 Nickel 310 2.72 2.21 2.28 6.32 3.64 3.86 2.23 4.02 3.75 1.72 3.44 3.40 0.477 J Selenium 78 0.441 J 0.475 J 0.326 J 0.385 J 0.287 J 0.405 J 0.452 J 0.520 J 0.471 J 0.267 J 0.338 J BDL 0.489 J Silver 78 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Thallium 0.16 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Zinc 4,700 45.4 36.3 24.3 98.0 40.0 56.5 9.72 55.3 56.5 8.16 26.1 105 2.45 J Mercury by Method 7471 (mg/kg) Mercury 2.3 0.0247J 0.0244 0.0222 BDL 0.0294 0.0375 0.0279 0.0617 0.0409 0.0248 0.0258 0.0274 0.0136 Hexavalent Chromium by Method 7199 (mg/kg) Hexavalent Chromium 0.31 0.367J 0.384J BDL BDL 0.403J 0.830J 0.272J 1.02J 0.405J BDL 0.412J 0.543J BDL Volatile Organic Compounds by Method 8260D (mg/kg) Acetone 12,000 0.0169J 0.0128J BDL 0.0402J 0.0402J 0.0229J 0.0115J 0.017J 0.098J 0.0146J BDL BDL BDL Benzene 1.2 BDL BDL BDL 0.013 0.023J 0.007 BDL BDL BDL BDL BDL BDL BDL Carbon Disulfide 160 BDL BDL BDL 0.063J BDL 0.0268 BDL BDL BDL BDL BDL BDL BDL Chlorobenzene 58 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1,3-Dichlorobenzene NE BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1,4-Dichlorobenzene 2.8 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL cis-1,2-Dichloroethylene 31 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Ethylbenzene 6.1 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 2-Butanone (MEK)5,500 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 2-Hexanone 42 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 4-Methyl-2-pentanone (MIBK)7,000 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Naphthalene 2.1 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Styrene 1,200 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Tetrachloroethylene 17 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Trichloroethylene 0.87 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Toluene 990 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Xylenes (total)120 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1,2,3-Trimethylbenzene 70 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Notes: 1. mg/kg = Milligrams per kilogram.7. NA - Not analyzed 2. (6-7) indicates depth below ground surface. 8. NE - Residential PSRG not established. 3. Rationale for selected sampling interval - P = highest PID reading; 9. North Carolina Department of Environmental Quality Preliminary B = bottom of waste; N = native soil Soil Remediation Goals (June 2021) 4. BDL = Below Detection Limit 10. PID = Photoionization detector readings in parts per million. 5. B = The same analyte is found in the associated blank.11. BOLD = exceedances of the Residential Health Based PSRGs 6. J = The identificaion of the analyte is acceptable; the reported value standards and background is an estimate. 35.000186 35.0003501 Metals by Method 6020B (mg/kg) -79.7747945 -79.7748127 -79.7742016 -79.7738348 Residential Health Based PSRG (mg/kg) 34.9996619 34.9998971 TABLE 3 WASTE and SOIL CHARACTERIZATION ANALYTICAL RESULTS Old Richmond County Landfill NONCD0000594 Rockingham, Richmond County, North Carolina SAMPLE ID SB-1 (6-7)P SB-1 (7-8)B SB-1 (8-9)N SB-2 (4.5-5.5)P SB-2 (6.5-8.5)B DUP-1 SB-2 (9.5-10.5)N SB-3 (6-8)P SB-3 (9-10)B SB-3 (10-11)N SB-4 (4-5)P SB-4 (5-8)B SB-4 (8-9)N Latitude Longitude PID Readings 0.5 0.1 0.0 4.7 2.2 2.2 1.2 30.7 16.9 3.5 20.6 35.1 3.9 Sample Date 05/06/19 05/06/19 05/06/19 05/06/19 05/06/19 05/06/19 05/06/19 05/06/19 05/06/19 05/06/19 05/07/19 05/07/19 05/07/19 35.000186 35.0003501 -79.7747945 -79.7748127 -79.7742016 -79.7738348 Residential Health Based PSRG (mg/kg) 34.9996619 34.9998971 Volatile Organic Compounds by Method 8260D-SIM (mg/kg) 1,4-Dioxane 5.4 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Semi Volatile Organic Compounds by Method 8270E (mg/kg) Acenaphthene 720 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Acetophenone 1,600 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Acenaphthylene NE BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Anthracene 3,600 BDL BDL BDL 1.3J BDL BDL BDL BDL BDL BDL BDL BDL BDL Benzo(a)anthracene 1.1 BDL BDL BDL 5.15 BDL 1.85 BDL BDL BDL BDL 1.7J BDL BDL Benzo(b)fluoranthene 1.1 BDL BDL BDL 7.90 BDL 2.82 BDL BDL BDL BDL BDL BDL BDL Benzo(g,h,i)perylene NE BDL BDL BDL 4.69 BDL 1.71J BDL BDL BDL BDL BDL BDL BDL Benzo(a)pyrene 0.11 BDL BDL BDL 5.03 BDL 1.92 BDL BDL BDL BDL BDL BDL BDL Benzo(k)Fluoranthene 1.1 BDL BDL BDL 2.44J BDL 1.14J BDL BDL BDL BDL 2.13J BDL BDL Biphenyl NE BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Carbazole NE BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Caprolactam 6,300 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Chrysene 110 BDL BDL BDL 5.34 BDL 1.94 BDL BDL BDL BDL 1.82J BDL BDL Dibenz(a,h)Anthracene 11 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Dibenzofuran 15 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Fluoranthene 480 BDL BDL BDL 9.36 BDL 3.21 BDL BDL BDL BDL 2.71J BDL BDL Fluorene 480 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Indeno(1,2,3-cd)pyrene 1.1 BDL BDL BDL 3.82 BDL 1.48J BDL BDL BDL BDL BDL BDL BDL 2-Methylnaphthalene 48 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Naphthalene 4.1 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Phenanthrene NE BDL BDL BDL 5.29 BDL 1.78 BDL BDL BDL BDL 0.946J BDL BDL Bis(2-ethylhexyl)phthalate 450 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Di-n-butyl phthalate 1,300 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Pyrene 360 BDL BDL BDL 7.32 BDL 2.43 BDL BDL BDL BDL 2.06J BDL BDL 2-Methylphenol 630 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 3&4-Methyl Phenol 630 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 2,4-Dimethylphenol 250 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Phenol 3,800 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Wet Chemistry by Method 350.1 and 9056A (mg/kg) Ammonia NE BDL 10.1 10.4 10.1 10.9 9.7 9.7 10.2 10.8 11.0 9.8 10.4 10.7 Nitrate as (N)25,000 BDL 4.3 4.2 4.2 4.3 4.2 4.2 4.4 4.7 4.7 4.3 4.4 4.2 Sulfate NE 73.2 29.1J 37.0J 78.8 63.4 62.3 34.9J 43.9J 52.5J 39.4J 31.0J 30.9J BDL Notes: 1. mg/kg = Milligrams per kilogram.7. NA - Not analyzed 2. (6-7) indicates depth below ground surface. 8. NE - Residential PSRG not established. 3. Rationale for selected sampling interval - P = highest PID reading; 9. North Carolina Department of Environmental Quality Preliminary B = bottom of waste; N = native soil Soil Remediation Goals (June 2021) 4. BDL = Below Detection Limit 10. PID = Photoionization detector readings in parts per million. 5. B = The same analyte is found in the associated blank.11. BOLD = exceedances of the Residential Health Based PSRGs 6. J = The identificaion of the analyte is acceptable; the reported value standards and background is an estimate. TABLE 3 WASTE and SOIL CHARACTERIZATION ANALYTICAL RESULTS Old Richmond County Landfill NONCD0000594 Rockingham, Richmond County, North Carolina SAMPLE ID Latitude Longitude PID Readings Sample Date Antimony 6.3 Arsenic 0.68 Beryllium 31 Cadmium 14 Total Chromium 23,000 Copper 630 Iron 11,000 Lead 400 Manganese 380 Nickel 310 Selenium 78 Silver 78 Thallium 0.16 Zinc 4,700 Mercury by Method 7471 (mg/kg) Mercury 2.3 Hexavalent Chromium by Method 7199 (mg/kg) Hexavalent Chromium 0.31 Volatile Organic Compounds by Method 8260D (mg/kg) Acetone 12,000 Benzene 1.2 Carbon Disulfide 160 Chlorobenzene 58 1,3-Dichlorobenzene NE 1,4-Dichlorobenzene 2.8 cis-1,2-Dichloroethylene 31 Ethylbenzene 6.1 2-Butanone (MEK)5,500 2-Hexanone 42 4-Methyl-2-pentanone (MIBK)7,000 Naphthalene 2.1 Styrene 1,200 Tetrachloroethylene 17 Trichloroethylene 0.87 Toluene 990 Xylenes (total)120 1,2,3-Trimethylbenzene 70 Metals by Method 6020B (mg/kg) Residential Health Based PSRG (mg/kg) SB-5 (3-4)P DUP-2 SB-5 (6-8)B SB-5 (8-9)N SB-6 (4.5-5.5)P SB-6 (5.5-6.5)B SB-6 (8.5-10.5)N SB-7 (6-7)P SB-7 (7-8)B SB-7 (11-12)N SB-8 (2-3)P SB-8 (4-5)B SB-8 (8-10)N SB-9 (3.5-4.5)P SB-9 (6.5-7.5)B SB-9 (8.5-10)N 21.1 21.1 8.2 5.3 8 12.1 16.5 4.1 19.2 11.8 42 8.6 9.7 5.7 2.7 2.3 05/07/19 05/07/19 05/07/19 05/07/19 05/07/19 05/07/19 05/07/19 05/07/19 05/07/19 05/07/19 05/08/19 05/08/19 05/08/19 05/08/19 05/08/19 05/08/19 0.468 J 0.239 J 1.00 0.657 BDL BDL BDL 0.839 0.553 J BDL 0.445J 0.213J BDL 0.52 BDL BDL 3.78 3.52 2.76 2.56 5.32 5.30 2.37 3.50 3.51 4.88 2.76 3.56 1.48 1.64 0.466J 0.542J 0.125 J 0.127 J 0.166 J 0.179 J 0.134 J 0.141 J 0.0806 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0904 J 0.295 J 0.338 J BDL BDL BDL 0.797 0.565 J BDL BDL BDL BDL 0.398J BDL BDL 15.6 13.2 11.6 11.7 22.8 25.6 17.6 12.3 11.4 14.7 9.18 41.9 5.88 12.3 2.51 1.6 7.11 6.06 11.4 6.58 8.00 7.55 3.90 45.1 27.0 4.97 5.44 2.92 1.88 5.96 1.31 1.15J 12300 11200 9440 8880 16100 17200 6730 11,200 10,300 7,880 6,040 7,200 3,510 6,180 1,020 1,220 7.10 6.27 11.8 15.9 5.22 5.02 2.77 14.0 9.50 2.13 13.60 7.97 2.13 6.12 1.23 1.4 13.3 11.2 15.9 13.6 14.2 10.3 6.87 37.7 30.2 6.02 15.4 11.2 5.25 27.3 2.76 3.06 3.90 2.31 2.75 5.55 3.53 2.94 1.63 3.26 2.80 0.774 1.13 2.81 0.971 3.58 0.39 .506J 0.484 J 0.261 J 0.568 0.425 J 0.294 J 0.222 J BDL 0.523 J 0.353 J 0.880 0.372J 1.21 0.256J 0.353J 0.37 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 20.1 17.0 28.7 27.9 12.6 7.10 3.04 J 173 125 4.64 J 22 28.8 2.91 248 3.82 6.77 0.0389 0.0358 0.0244 0.0273 0.0442 0.0420 0.0244 0.0532 0.0469 0.0173J 0.0328 0.0204J 0.0109J 0.18 .00767J 0.0134J 0.642J BDL BDL BDL 0.514J BDL BDL 0.574J 0.421J BDL BDL BDL BDL BDL BDL BDL 0.091J BDL BDL BDL 0.0666J 0.0124J 0.0364J BDL BDL 0.022J BDL 0.0136J 0.0136J 0.0501J 0.002J 0.0121J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.025J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Notes: 1. mg/kg = Milligrams per kilogram.7. NA - Not analyzed 2. (6-7) indicates depth below ground surface. 8. NE - Residential PSRG not established. 3. Rationale for selected sampling interval - P = highest PID reading; 9. North Carolina Department of Environmental Quality Preliminary B = bottom of waste; N = native soil Soil Remediation Goals (June 2021) 4. BDL = Below Detection Limit 10. PID = Photoionization detector readings in parts per million. 5. B = The same analyte is found in the associated blank.11. BOLD = exceedances of the Residential Health Based PSRGs 6. J = The identificaion of the analyte is acceptable; the reported value standards and background is an estimate. -79.7735926 -79.7734991 -79.7728195 -79.7726894 -79.773249 35.0001794 35.0004915 35.0006331 35.0001331 35.0000023 TABLE 3 WASTE and SOIL CHARACTERIZATION ANALYTICAL RESULTS Old Richmond County Landfill NONCD0000594 Rockingham, Richmond County, North Carolina SAMPLE ID Latitude Longitude PID Readings Sample Date Residential Health Based PSRG (mg/kg) Volatile Organic Compounds by Method 8260D-SIM (mg/kg) 1,4-Dioxane 5.4 Semi Volatile Organic Compounds by Method 8270E (mg/kg) Acenaphthene 720 Acetophenone 1,600 Acenaphthylene NE Anthracene 3,600 Benzo(a)anthracene 1.1 Benzo(b)fluoranthene 1.1 Benzo(g,h,i)perylene NE Benzo(a)pyrene 0.11 Benzo(k)Fluoranthene 1.1 Biphenyl NE Carbazole NE Caprolactam 6,300 Chrysene 110 Dibenz(a,h)Anthracene 11 Dibenzofuran 15 Fluoranthene 480 Fluorene 480 Indeno(1,2,3-cd)pyrene 1.1 2-Methylnaphthalene 48 Naphthalene 4.1 Phenanthrene NE Bis(2-ethylhexyl)phthalate 450 Di-n-butyl phthalate 1,300 Pyrene 360 2-Methylphenol 630 3&4-Methyl Phenol 630 2,4-Dimethylphenol 250 Phenol 3,800 Wet Chemistry by Method 350.1 and 9056A (mg/kg) Ammonia NE Nitrate as (N)25,000 Sulfate NE SB-5 (3-4)P DUP-2 SB-5 (6-8)B SB-5 (8-9)N SB-6 (4.5-5.5)P SB-6 (5.5-6.5)B SB-6 (8.5-10.5)N SB-7 (6-7)P SB-7 (7-8)B SB-7 (11-12)N SB-8 (2-3)P SB-8 (4-5)B SB-8 (8-10)N SB-9 (3.5-4.5)P SB-9 (6.5-7.5)B SB-9 (8.5-10)N 21.1 21.1 8.2 5.3 8 12.1 16.5 4.1 19.2 11.8 42 8.6 9.7 5.7 2.7 2.3 05/07/19 05/07/19 05/07/19 05/07/19 05/07/19 05/07/19 05/07/19 05/07/19 05/07/19 05/07/19 05/08/19 05/08/19 05/08/19 05/08/19 05/08/19 05/08/19 -79.7735926 -79.7734991 -79.7728195 -79.7726894 -79.773249 35.0001794 35.0004915 35.0006331 35.0001331 35.0000023 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.179J 52.8 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1.96J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.3850 BDL 19.9 509J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.8 0.830J 35.9 1.07J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 46.3 1.34J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.477 BDL 0.791J 0.791J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.731 BDL 37.5 1.05J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 3.57J 0.934J 16.5 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 23.2 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.158J BDL 3.21J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.768 0.8J 34.5 1.12J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 5.48 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 2.62J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1.59 1.67J 108 2.52 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.169J BDL 7.58 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.46 BDL 21.7 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 11.5J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 9.19J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1.35 1.38J 7.47 1.95 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1.26J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1.18 1.32J 74.40 2.11 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 9.7 10.9 11.3 10.6 9.0 11.4 10.1 9.3 9.6 7.2 10.2 10.3 10.4 9.9 8.7 7.40 4.3 4.3 4.4 4.5 4.3 4.6 4.3 4.1 4.2 4.3 4.2 4.2 4.2 4.1 3.9 3.60 46.2J 56 113 133 BDL BDL BDL 71.4 84.4 35.7J 30.3J BDL 44.3J 30.2J BDL BDL Notes: 1. mg/kg = Milligrams per kilogram.7. NA - Not analyzed 2. (6-7) indicates depth below ground surface. 8. NE - Residential PSRG not established. 3. Rationale for selected sampling interval - P = highest PID reading; 9. North Carolina Department of Environmental Quality Preliminary B = bottom of waste; N = native soil Soil Remediation Goals (June 2021) 4. BDL = Below Detection Limit 10. PID = Photoionization detector readings in parts per million. 5. B = The same analyte is found in the associated blank.11. BOLD = exceedances of the Residential Health Based PSRGs 6. J = The identificaion of the analyte is acceptable; the reported value standards and background is an estimate. TABLE 3 WASTE and SOIL CHARACTERIZATION ANALYTICAL RESULTS Old Richmond County Landfill NONCD0000594 Rockingham, Richmond County, North Carolina SAMPLE ID Latitude Longitude PID Readings Sample Date Antimony 6.3 Arsenic 0.68 Beryllium 31 Cadmium 14 Total Chromium 23,000 Copper 630 Iron 11,000 Lead 400 Manganese 380 Nickel 310 Selenium 78 Silver 78 Thallium 0.16 Zinc 4,700 Mercury by Method 7471 (mg/kg) Mercury 2.3 Hexavalent Chromium by Method 7199 (mg/kg) Hexavalent Chromium 0.31 Volatile Organic Compounds by Method 8260D (mg/kg) Acetone 12,000 Benzene 1.2 Carbon Disulfide 160 Chlorobenzene 58 1,3-Dichlorobenzene NE 1,4-Dichlorobenzene 2.8 cis-1,2-Dichloroethylene 31 Ethylbenzene 6.1 2-Butanone (MEK)5,500 2-Hexanone 42 4-Methyl-2-pentanone (MIBK)7,000 Naphthalene 2.1 Styrene 1,200 Tetrachloroethylene 17 Trichloroethylene 0.87 Toluene 990 Xylenes (total)120 1,2,3-Trimethylbenzene 70 Metals by Method 6020B (mg/kg) Residential Health Based PSRG (mg/kg) SB-10 (5-6)P SB-11 (6-7)P SB-11 (7-8)B SB-11 (8-9)N DUP-B SB-12 (2.5-3.5)P SB-12 (6.5-8.5)B SB-12 (9.5-10.5)N SB-13 (4.5-5.5)P SB-13 (6.5-8.5)B SB-13 (9.5-10.5)N 34.99959318 -79.77395642 9.8 0.5 0.5 0.5 36.1 2.6 2.5 3.9 3.6 3.7 07/21/2020 07/22/2020 07/22/2020 07/22/2020 07/22/2020 07/22/2020 07/22/2020 07/22/2020 07/22/2020 07/22/2020 07/22/2020 2.90J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1.86 1.88 2.65 2.48 2.42 1.26 3.43 2.22 1.04 1.74 1.09 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 7.97 6.43 10.6 9.32 9.33 4.44J 13.3 9.10 3.87J 5.60 3.79J 12.1 5.41 7.43 6.17 6.86 2.77J 8.31 6.34 2.73J 4.80J 3.07J 7,420 4,240 6,840 6,040 6,170 3,380 9,100 6,530 3,040 4,470 2,970 26.0 2.43 2.37 1.78J 2.18J 2.34 3.24 1.51J 1.43J 1.85J 1.27J 33.9 8.00 10.1 9.19 9.68 10.5 14.7 10.3 17.0 11.9 8.95 3.37 1.54J 2.06J 1.99J 2.15J 1.68J 3.02 2.21J 1.43J 2.09J 1.27J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 75.6 BDL BDL BDL BDL BDL 10.7J BDL BDL BDL BDL NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.115 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.00831 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.124BJ 0.0868BJ 0.0888BJ 0.102BJ 0.122BJ 0.101BJ 0.0967BJ 0.104BJ 0.0936BJ 0.0892BJ 0.0931BJ BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.00652J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0191 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0540 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0195 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Notes: 1. mg/kg = Milligrams per kilogram.7. NA - Not analyzed 2. (6-7) indicates depth below ground surface. 8. NE - Residential PSRG not established. 3. Rationale for selected sampling interval - P = highest PID reading; 9. North Carolina Department of Environmental Quality Preliminary B = bottom of waste; N = native soil Soil Remediation Goals (June 2021) 4. BDL = Below Detection Limit 10. PID = Photoionization detector readings in parts per million. 5. B = The same analyte is found in the associated blank.11. BOLD = exceedances of the Residential Health Based PSRGs 6. J = The identificaion of the analyte is acceptable; the reported value standards and background is an estimate. 34.99995809 35.0002501 -79.77495837-79.77509169 -79.77499903 34.99958108 TABLE 3 WASTE and SOIL CHARACTERIZATION ANALYTICAL RESULTS Old Richmond County Landfill NONCD0000594 Rockingham, Richmond County, North Carolina SAMPLE ID Latitude Longitude PID Readings Sample Date Residential Health Based PSRG (mg/kg) Volatile Organic Compounds by Method 8260D-SIM (mg/kg) 1,4-Dioxane 5.4 Semi Volatile Organic Compounds by Method 8270E (mg/kg) Acenaphthene 720 Acetophenone 1,600 Acenaphthylene NE Anthracene 3,600 Benzo(a)anthracene 1.1 Benzo(b)fluoranthene 1.1 Benzo(g,h,i)perylene NE Benzo(a)pyrene 0.11 Benzo(k)Fluoranthene 1.1 Biphenyl NE Carbazole NE Caprolactam 6,300 Chrysene 110 Dibenz(a,h)Anthracene 11 Dibenzofuran 15 Fluoranthene 480 Fluorene 480 Indeno(1,2,3-cd)pyrene 1.1 2-Methylnaphthalene 48 Naphthalene 4.1 Phenanthrene NE Bis(2-ethylhexyl)phthalate 450 Di-n-butyl phthalate 1,300 Pyrene 360 2-Methylphenol 630 3&4-Methyl Phenol 630 2,4-Dimethylphenol 250 Phenol 3,800 Wet Chemistry by Method 350.1 and 9056A (mg/kg) Ammonia NE Nitrate as (N)25,000 Sulfate NE SB-10 (5-6)P SB-11 (6-7)P SB-11 (7-8)B SB-11 (8-9)N DUP-B SB-12 (2.5-3.5)P SB-12 (6.5-8.5)B SB-12 (9.5-10.5)N SB-13 (4.5-5.5)P SB-13 (6.5-8.5)B SB-13 (9.5-10.5)N 34.99959318 -79.77395642 9.8 0.5 0.5 0.5 36.1 2.6 2.5 3.9 3.6 3.7 07/21/2020 07/22/2020 07/22/2020 07/22/2020 07/22/2020 07/22/2020 07/22/2020 07/22/2020 07/22/2020 07/22/2020 07/22/2020 34.99995809 35.0002501 -79.77495837-79.77509169 -79.77499903 34.99958108 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0333J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NA NA NA NA NA NA NA NA NA NA 0.699J NA NA NA NA NA NA NA NA NA NA 42.4J NA NA NA NA NA NA NA NA NA NA Notes: 1. mg/kg = Milligrams per kilogram.7. NA - Not analyzed 2. (6-7) indicates depth below ground surface. 8. NE - Residential PSRG not established. 3. Rationale for selected sampling interval - P = highest PID reading; 9. North Carolina Department of Environmental Quality Preliminary B = bottom of waste; N = native soil Soil Remediation Goals (June 2021) 4. BDL = Below Detection Limit 10. PID = Photoionization detector readings in parts per million. 5. B = The same analyte is found in the associated blank.11. BOLD = exceedances of the Residential Health Based PSRGs 6. J = The identificaion of the analyte is acceptable; the reported value standards and background is an estimate. TABLE 3 WASTE and SOIL CHARACTERIZATION ANALYTICAL RESULTS Old Richmond County Landfill NONCD0000594 Rockingham, Richmond County, North Carolina SAMPLE ID Latitude Longitude PID Readings Sample Date Antimony 6.3 Arsenic 0.68 Beryllium 31 Cadmium 14 Total Chromium 23,000 Copper 630 Iron 11,000 Lead 400 Manganese 380 Nickel 310 Selenium 78 Silver 78 Thallium 0.16 Zinc 4,700 Mercury by Method 7471 (mg/kg) Mercury 2.3 Hexavalent Chromium by Method 7199 (mg/kg) Hexavalent Chromium 0.31 Volatile Organic Compounds by Method 8260D (mg/kg) Acetone 12,000 Benzene 1.2 Carbon Disulfide 160 Chlorobenzene 58 1,3-Dichlorobenzene NE 1,4-Dichlorobenzene 2.8 cis-1,2-Dichloroethylene 31 Ethylbenzene 6.1 2-Butanone (MEK)5,500 2-Hexanone 42 4-Methyl-2-pentanone (MIBK)7,000 Naphthalene 2.1 Styrene 1,200 Tetrachloroethylene 17 Trichloroethylene 0.87 Toluene 990 Xylenes (total)120 1,2,3-Trimethylbenzene 70 Metals by Method 6020B (mg/kg) Residential Health Based PSRG (mg/kg) SB-14 (2.5-3.5)P SB-14 (6.5-8.5)B SB-14 (9.5-10.5)N SB-15 (6-7)P SB-15 (9-10)B SB-15 (10-11)N SB-16 (6-7)P SB-16 (7-8)B SB-16 (9-10)N DUP-C SB-17 (3.5-4.5)P SB-17 (6.5-7.5)B SB-17 (8.5-10)N 25.7 2.8 3.3 7.8 3.3 3.8 1.7 2.0 1.8 3.8 3.1 3.4 07/22/2020 07/22/2020 07/22/2020 07/22/2020 07/22/2020 07/22/2020 07/23/2020 07/23/2020 07/23/2020 07/23/2020 7/23/2020 7/23/2020 7/23/2020 BDL BDL BDL BDL BDL BDL 5.26 BDL BDL 4.71 BDL BDL BDL 1.08 1.39 0.918J 0.884J 2.67 0.572J 3.81 4.75 3.94 3.17 0.882J 0.442J 1.00J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 2.72 BDL BDL 2.36 BDL BDL BDL 4.43J 5.81 4.07J 4.53J 9.23 2.34J 21.9 14.4 11.9 20.6 3.10J BDL 2.91J BDL 3.89J BDL 2.95J 6.81 BDL 121 9.86 4.82J 85.8 BDL BDL BDL 3,180 3,710 2,070 2,030 6,990 1,190 39,600 8,520 7,240 44,500 2,640 898 2,070 2.36 1.48J 1.10J 1.71J 4.30 1.27J 154 3.96 3.51 64.7 2.28 BDL 1.33J 11.6 8.05 5.78 7.39 18.1 3.64 304 10.0 9.19 270 8.99 2.72 3.51 1.88J 1.72J BDL BDL 3.95 BDL 36.6 2.31J 1.64J 36.5 1.38J BDL BDL BDL BDL BDL BDL BDL BDL BDL 3.59 2.74 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 12.8J BDL 502 9.28J BDL 387 BDL BDL BDL NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.534 0.000865J BDL 0.583 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.00315J 0.000401J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.00357J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0372 BDL BDL 0.0107 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 2.06 0.00239J BDL 0.719 BDL BDL BDL BDL BDL BDL 0.0746J 0.0820J BDL BDL BDL BDL 0.120J BDL 0.0945J 0.0934J BDL BDL BDL BDL BDL BDL 0.0287J BDL BDL 0.0140J BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.120 BDL BDL 0.0417 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.187 BDL BDL 0.0199J BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0147J 0.000443J BDL 0.0103J 0.00107J BDL BDL BDL BDL BDL BDL BDL BDL 0.0791 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.00165J BDL BDL 0.048 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.993 0.00164J BDL 0.471 BDL BDL BDL 0.00101J BDL BDL BDL BDL BDL 0.853 BDL BDL 0.264 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.129 BDL BDL 0.0549 BDL BDL BDL Notes: 1. mg/kg = Milligrams per kilogram.7. NA - Not analyzed 2. (6-7) indicates depth below ground surface. 8. NE - Residential PSRG not established. 3. Rationale for selected sampling interval - P = highest PID reading; 9. North Carolina Department of Environmental Quality Preliminary B = bottom of waste; N = native soil Soil Remediation Goals (June 2021) 4. BDL = Below Detection Limit 10. PID = Photoionization detector readings in parts per million. 5. B = The same analyte is found in the associated blank.11. BOLD = exceedances of the Residential Health Based PSRGs 6. J = The identificaion of the analyte is acceptable; the reported value standards and background is an estimate. 35.00035249 35.00067002 34.99942272 34.99953812 -79.77440811 -79.77335356-79.77475405 -79.77403529 TABLE 3 WASTE and SOIL CHARACTERIZATION ANALYTICAL RESULTS Old Richmond County Landfill NONCD0000594 Rockingham, Richmond County, North Carolina SAMPLE ID Latitude Longitude PID Readings Sample Date Residential Health Based PSRG (mg/kg) Volatile Organic Compounds by Method 8260D-SIM (mg/kg) 1,4-Dioxane 5.4 Semi Volatile Organic Compounds by Method 8270E (mg/kg) Acenaphthene 720 Acetophenone 1,600 Acenaphthylene NE Anthracene 3,600 Benzo(a)anthracene 1.1 Benzo(b)fluoranthene 1.1 Benzo(g,h,i)perylene NE Benzo(a)pyrene 0.11 Benzo(k)Fluoranthene 1.1 Biphenyl NE Carbazole NE Caprolactam 6,300 Chrysene 110 Dibenz(a,h)Anthracene 11 Dibenzofuran 15 Fluoranthene 480 Fluorene 480 Indeno(1,2,3-cd)pyrene 1.1 2-Methylnaphthalene 48 Naphthalene 4.1 Phenanthrene NE Bis(2-ethylhexyl)phthalate 450 Di-n-butyl phthalate 1,300 Pyrene 360 2-Methylphenol 630 3&4-Methyl Phenol 630 2,4-Dimethylphenol 250 Phenol 3,800 Wet Chemistry by Method 350.1 and 9056A (mg/kg) Ammonia NE Nitrate as (N)25,000 Sulfate NE SB-14 (2.5-3.5)P SB-14 (6.5-8.5)B SB-14 (9.5-10.5)N SB-15 (6-7)P SB-15 (9-10)B SB-15 (10-11)N SB-16 (6-7)P SB-16 (7-8)B SB-16 (9-10)N DUP-C SB-17 (3.5-4.5)P SB-17 (6.5-7.5)B SB-17 (8.5-10)N 25.7 2.8 3.3 7.8 3.3 3.8 1.7 2.0 1.8 3.8 3.1 3.4 07/22/2020 07/22/2020 07/22/2020 07/22/2020 07/22/2020 07/22/2020 07/23/2020 07/23/2020 07/23/2020 07/23/2020 7/23/2020 7/23/2020 7/23/2020 35.00035249 35.00067002 34.99942272 34.99953812 -79.77440811 -79.77335356-79.77475405 -79.77403529 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.910 BDL BDL 1.89J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0190J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0282J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0127J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0177J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.118J BDL BDL 0.317J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0400J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0424J BDL BDL 0.0863J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0819J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0433J BDL BDL 0.181J BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.154 BDL BDL 0.477 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.114 BDL BDL 0.260J BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.269J BDL BDL 3.54J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0346J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.151J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.409J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.106J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 2.08J BDL BDL BDL NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Notes: 1. mg/kg = Milligrams per kilogram.7. NA - Not analyzed 2. (6-7) indicates depth below ground surface. 8. NE - Residential PSRG not established. 3. Rationale for selected sampling interval - P = highest PID reading; 9. North Carolina Department of Environmental Quality Preliminary B = bottom of waste; N = native soil Soil Remediation Goals (June 2021) 4. BDL = Below Detection Limit 10. PID = Photoionization detector readings in parts per million. 5. B = The same analyte is found in the associated blank.11. BOLD = exceedances of the Residential Health Based PSRGs 6. J = The identificaion of the analyte is acceptable; the reported value standards and background is an estimate. TABLE 3 WASTE and SOIL CHARACTERIZATION ANALYTICAL RESULTS Old Richmond County Landfill NONCD0000594 Rockingham, Richmond County, North Carolina SAMPLE ID Latitude Longitude PID Readings Sample Date Antimony 6.3 Arsenic 0.68 Beryllium 31 Cadmium 14 Total Chromium 23,000 Copper 630 Iron 11,000 Lead 400 Manganese 380 Nickel 310 Selenium 78 Silver 78 Thallium 0.16 Zinc 4,700 Mercury by Method 7471 (mg/kg) Mercury 2.3 Hexavalent Chromium by Method 7199 (mg/kg) Hexavalent Chromium 0.31 Volatile Organic Compounds by Method 8260D (mg/kg) Acetone 12,000 Benzene 1.2 Carbon Disulfide 160 Chlorobenzene 58 1,3-Dichlorobenzene NE 1,4-Dichlorobenzene 2.8 cis-1,2-Dichloroethylene 31 Ethylbenzene 6.1 2-Butanone (MEK)5,500 2-Hexanone 42 4-Methyl-2-pentanone (MIBK)7,000 Naphthalene 2.1 Styrene 1,200 Tetrachloroethylene 17 Trichloroethylene 0.87 Toluene 990 Xylenes (total)120 1,2,3-Trimethylbenzene 70 Metals by Method 6020B (mg/kg) Residential Health Based PSRG (mg/kg) SB-18 (2-3)P SB-18 (5-6)B SB-18 (8-9)N DUP-D SB-19 (2-3)P SB-19 (4-5)B SB-19 (8-10)N SB-20 (6-7)P SB-20 (7-8)B SB-20 (10-12)N SB-21 (5-6)P SB-21 (7-8)B SB-21 (11-12)N 56.9 8.6 2.7 3.2 2.6 0.7 2.8 1.9 1.6 1,270 191.7 106.9 7/23/2020 7/23/2020 7/23/2020 07/29/2020 07/23/2020 07/23/2020 07/23/2020 07/23/2020 07/23/2020 07/23/2020 07/23/2020 07/23/2020 07/22/2020 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1.06 1.04 1.31 0.894J 0.944J 0.958J 3.45 3.22 9.21 3.13 6.22 7.70 5.21 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 7.00 7.65 3.54J 2.75J 4.10J 3.39J 8.63 12.8 18.5 10.3 27.0 17.8 10.7 BDL 2.87J BDL BDL 2.84J BDL 4.98J 4.93J 6.10 4.24J 9.76 6.29 4.03J 1,850 1,940 3,090 2,640 2,360 1,990 5,790 7,140 14,600 6,950 16,100 20,500 11,800 BDL 1.57J BDL 1.76J 2.71 1.38J 2.39 3.52 4.41 4.01 7.00 4.86 3.25 6.93 7.37 6.24 9.66 7.16 3.94 8.76 7.61 7.91 7.16 13.3 9.54 4.87 2.43J 3.06 BDL BDL BDL BDL 2.02J 2.08J 2.29J 2.15J 4.33 1.91J BDL BDL BDL BDL BDL BDL BDL BDL BDL 14.4 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 16.7J BDL BDL NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0576 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0963J 0.0895J 0.0963J 0.101J BDL 0.0700J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.00411J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.00178J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Notes: 1. mg/kg = Milligrams per kilogram.7. NA - Not analyzed 2. (6-7) indicates depth below ground surface. 8. NE - Residential PSRG not established. 3. Rationale for selected sampling interval - P = highest PID reading; 9. North Carolina Department of Environmental Quality Preliminary B = bottom of waste; N = native soil Soil Remediation Goals (June 2021) 4. BDL = Below Detection Limit 10. PID = Photoionization detector readings in parts per million. 5. B = The same analyte is found in the associated blank.11. BOLD = exceedances of the Residential Health Based PSRGs 6. J = The identificaion of the analyte is acceptable; the reported value standards and background is an estimate. -79.7730091-79.77379224 -79.77220029 -79.77220327 35.0008168734.99971451 34.99996645 35.00057092 TABLE 3 WASTE and SOIL CHARACTERIZATION ANALYTICAL RESULTS Old Richmond County Landfill NONCD0000594 Rockingham, Richmond County, North Carolina SAMPLE ID Latitude Longitude PID Readings Sample Date Residential Health Based PSRG (mg/kg) Volatile Organic Compounds by Method 8260D-SIM (mg/kg) 1,4-Dioxane 5.4 Semi Volatile Organic Compounds by Method 8270E (mg/kg) Acenaphthene 720 Acetophenone 1,600 Acenaphthylene NE Anthracene 3,600 Benzo(a)anthracene 1.1 Benzo(b)fluoranthene 1.1 Benzo(g,h,i)perylene NE Benzo(a)pyrene 0.11 Benzo(k)Fluoranthene 1.1 Biphenyl NE Carbazole NE Caprolactam 6,300 Chrysene 110 Dibenz(a,h)Anthracene 11 Dibenzofuran 15 Fluoranthene 480 Fluorene 480 Indeno(1,2,3-cd)pyrene 1.1 2-Methylnaphthalene 48 Naphthalene 4.1 Phenanthrene NE Bis(2-ethylhexyl)phthalate 450 Di-n-butyl phthalate 1,300 Pyrene 360 2-Methylphenol 630 3&4-Methyl Phenol 630 2,4-Dimethylphenol 250 Phenol 3,800 Wet Chemistry by Method 350.1 and 9056A (mg/kg) Ammonia NE Nitrate as (N)25,000 Sulfate NE SB-18 (2-3)P SB-18 (5-6)B SB-18 (8-9)N DUP-D SB-19 (2-3)P SB-19 (4-5)B SB-19 (8-10)N SB-20 (6-7)P SB-20 (7-8)B SB-20 (10-12)N SB-21 (5-6)P SB-21 (7-8)B SB-21 (11-12)N 56.9 8.6 2.7 3.2 2.6 0.7 2.8 1.9 1.6 1,270 191.7 106.9 7/23/2020 7/23/2020 7/23/2020 07/29/2020 07/23/2020 07/23/2020 07/23/2020 07/23/2020 07/23/2020 07/23/2020 07/23/2020 07/23/2020 07/22/2020 -79.7730091-79.77379224 -79.77220029 -79.77220327 35.0008168734.99971451 34.99996645 35.00057092 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.00982J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.00737J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.246J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Notes: 1. mg/kg = Milligrams per kilogram.7. NA - Not analyzed 2. (6-7) indicates depth below ground surface. 8. NE - Residential PSRG not established. 3. Rationale for selected sampling interval - P = highest PID reading; 9. North Carolina Department of Environmental Quality Preliminary B = bottom of waste; N = native soil Soil Remediation Goals (June 2021) 4. BDL = Below Detection Limit 10. PID = Photoionization detector readings in parts per million. 5. B = The same analyte is found in the associated blank.11. BOLD = exceedances of the Residential Health Based PSRGs 6. J = The identificaion of the analyte is acceptable; the reported value standards and background is an estimate. PARAMETER SAMPLE DATE Method 6020B / Method 7471B Antimony 6.3 BDL 0.178 J 0.283 J BDL 0.354 J 0.222 J BDL BDL 0.482 J BDL BDL 0.363 J BDL BDL Arsenic 0.68 1.41 1.72 1.26 1.19 1.12 1.68 0.995 0.595 2.45 1.24 1.71 1.15 0.917 1.17 Beryllium 31 0.0982 J 0.0745 J 0.408 J 0.126 J 0.141 J 0.691 0.0733 J 0.0628 J 0.637 0.214 J 0.133 J 0.110 J 0.0970 J 0.116 J Cadmium 14 BDL 1.69 0.422 J BDL 0.171 J 0.629 BDL BDL 0.630 0.160 J BDL BDL BDL BDL Total Chromium 23,000 5.57 20.1 3.99 4.80 3.98 5.32 4.23 2.89 9.06 5.32 6.44 5.11 3.56 7.04 Hexavalent Chromium 0.31 NA NA NA NA NA NA NA NA NA NA NA NA NA NA Copper 630 2.80 5.23 2.46 2.35 3.38 3.10 3.01 1.61 7.84 2.29 3.56 2.52 2.72 3.06 Iron 11,000 3,540 4,950 2,340 3,100 3,060 3,160 2,930 1,710 5,850 3,680 4,510 3,780 2,350 3,720 Lead 400 3.94 68.5 3.80 3.94 3.69 4.02 2.96 2.39 27.5 3.38 4.25 3.22 2.08 22.0 Manganese 380 8.83 16.8 11.1 11.0 39.1 15.1 9.51 9.31 15.8 8.93 19.7 11.7 7.88 13.7 Mercury 2.3 0.0206 B J 0.304 0.0217 B 0.0218 B 0.0275 B J 0.0203 B J 0.0311 B 0.0174 B J 0.0263 B 0.0289 B 0.0201 B J 0.0198 B J 0.0118 B J 0.0209 B J Nickel 310 2.01 2.53 2.44 2.50 2.72 3.48 3.63 2.03 4.83 2.94 2.33 2.58 1.50 2.81 Selenium 78 0.319 J 0.218 J 0.450 J 0.245 J BDL 0.793 BDL BDL 0.518 J 0.333 J 0.303 J 0.216 J BDL 0.279 J Silver 78 BDL BDL 0.238 J BDL BDL 0.323 J BDL BDL 0.354 J BDL BDL BDL BDL BDL Thallium 0.16 BDL BDL 0.480 J BDL BDL 0.658 BDL BDL 0.677 0.195 J BDL BDL BDL BDL Zinc 4,700 9.96 67.2 10.9 10.4 32.7 12.9 8.80 6.46 32.5 9.13 14.8 8.02 5.46 11.5 EPA 350.1 / EPA 353.2 / EPA 9056 Nitrogen, Ammonia 6,200,000,000 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Nitrogen, Nitrate 25,000 BDL BDL BDL BDL 0.0114 BDL BDL BDL BDL BDL 0.0058 BDL BDL BDL Sulfate NE 0.0301 J BDL BDL 0.0284 J BDL BDL BDL 0.0828 0.0527 J BDL BDL BDL 0.0599 BDL EPA 8082A PCB-1248 (Aroclor 1248)0.23 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL PCB-1254 (Aroclor 1254)0.23 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0721 BDL BDL BDL EPA 8260D 2-Butanone (MEK)5,500 BDL BDL BDL BDL 0.0072 J BDL BDL BDL BDL BDL BDL BDL BDL BDL Acetone 12,000 BDL 0.0115 J BDL BDL 0.201 0.0383 J 0.0110 J BDL 0.0118 J BDL BDL BDL BDL BDL Methyl acetate 16,000 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Methylene Chloride 58 0.0041 J BDL 0.0042 J 0.0036 J 0.0057 J 0.0043 J 0.0040 J BDL 0.0045 J 0.0041 J BDL BDL BDL BDL EPA 8270E No Analytes Detected 3.) Values reported in mg/kg (milligrams per kilogram). 6.) B = The same analyte is found in the associated blank. 7.) BDL = Below Detection Limit 9) Background concentration of Arsenic ranges from 0.442 to 9.21 mg/kg. 8.) Chromium PSRG value based on Chromium (III). 5/20/2019 5/20/2019 5/20/2019 5/20/2019 5/20/2019 5/20/2019 5/20/2019 5/20/20195/20/2019 5/21/2019 5/20/2019 5/20/2019 5/20/2019 5/20/2019 SC-2 (1.5)SC-3 (0.5)SC-3 (1.5)SC-4 (0.5)SC-5 (0.5)SC-6 (0.5)SC-6 (1.5)SC-7 (0.5)SC-7 (1.5) 2.) Bold = Indicates concentrations above the corresponding PSRG. SC-2 (0.5) 1.) PSRG = North Carolina Department of Environmental Quality Preliminary Soil Remediation (June 2021). 5.) J = The identification of the analyte is acceptable; the reported value is an estimate. Residential Preliminary PSRG (mg/kg) DUP-3 DUP-4 SC-1 (0.5)SC-1 (1.5) Page 1 of 3 Rockingham, Richmond County, North Carolina NONCD0000594 Old Richmond County LF EVALUATION OF WDA EXISTING SOIL COVER FOR USE AS THE PERMANENT COVER SYSTEM TABLE 4 PARAMETER SAMPLE DATE Method 6020B / Method 7471B Antimony 6.3 Arsenic 0.68 Beryllium 31 Cadmium 14 Total Chromium 23,000 Hexavalent Chromium 0.31 Copper 630 Iron 11,000 Lead 400 Manganese 380 Mercury 2.3 Nickel 310 Selenium 78 Silver 78 Thallium 0.16 Zinc 4,700 EPA 350.1 / EPA 353.2 / EPA 9056 Nitrogen, Ammonia 6,200,000,000 Nitrogen, Nitrate 25,000 Sulfate NE EPA 8082A PCB-1248 (Aroclor 1248)0.23 PCB-1254 (Aroclor 1254)0.23 EPA 8260D 2-Butanone (MEK)5,500 Acetone 12,000 Methyl acetate 16,000 Methylene Chloride 58 EPA 8270E No Analytes Detected 3.) Values reported in mg/kg (milligrams per kilogram). 6.) B = The same analyte is found in the associated blank. 7.) BDL = Below Detection Limit 9) Background concentration of Arsenic ranges from 0.442 to 9.21 mg/kg. 8.) Chromium PSRG value based on Chromium (III). 2.) Bold = Indicates concentrations above the corresponding PSRG. 1.) PSRG = North Carolina Department of Environmental Quality Preliminary Soil Remediation (June 2021). 5.) J = The identification of the analyte is acceptable; the reported value is an estimate. Residential Preliminary PSRG (mg/kg) BDL BDL BDL 0.225 J BDL BDL BDL BDL BDL BDL 0.231 J BDL BDL BDL 3.27 1.44 1.20 1.31 2.21 2.48 3.84 1.51 2.91 3.49 2.75 2.10 0.772 0.829 0.164 J BDL BDL BDL 0.0770 J 0.106 J 0.106 J BDL 0.0910 J 0.355 J 0.516 J 0.0764 J 0.112 J 0.0838 J BDL 0.515 J BDL BDL BDL BDL BDL BDL BDL 0.338 J 0.502 J BDL BDL BDL 10.5 6.56 4.41 5.80 7.57 9.87 15.6 6.32 12.4 13.9 9.16 6.24 3.99 3.57 0.547 J NA NA NA NA NA BDL NA BDL BDL NA NA NA NA 3.61 2.91 2.54 2.31 5.55 5.15 5.79 1.94 4.64 5.28 3.71 3.17 1.60 2.01 7,120 3,260 2,980 3,660 4,190 6,530 9,530 3,750 7,480 8,290 5,040 4,380 2,350 2,120 2.36 19.7 6.21 2.70 3.87 3.33 3.91 2.45 3.83 4.08 4.54 2.57 2.21 2.74 5.69 6.79 6.24 4.73 7.63 7.48 8.54 5.36 8.61 9.05 5.34 7.21 5.86 30.1 0.0174 B J 0.144 0.0335 B 0.0119 B J 0.0484 0.0254 B 0.0267 B 0.0168 B J 0.0272 B 0.0458 0.0233 B 0.0142 B J 0.0427 0.0135 B J 2.08 1.60 1.41 1.49 2.31 2.62 3.14 2.22 2.66 3.29 2.76 1.27 1.88 1.66 0.358 J 0.252 J 0.333 J BDL 0.259 J 0.275 J 0.560 BDL 0.328 J 0.504 J 0.868 0.409 J BDL 0.226 J BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.182 J 0.303 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.396 J 0.508 J BDL BDL BDL 5.42 23.0 5.70 4.04 J 11.4 8.50 13.8 5.65 8.25 8.29 7.74 5.77 6.57 15.5 BDL BDL BDL BDL 0.0440 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0347 J BDL BDL BDL 0.0612 0.0336 J 0.0673 0.0443 J 0.0483 J 0.0388 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0293 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0657 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0123 J BDL BDL 0.249 BDL BDL BDL 0.0123 J BDL BDL 0.0183 J 0.0377 J BDL BDL BDL BDL BDL 0.0084 J BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0043 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 5/21/2019 5/21/2019 5/21/2019 5/21/20195/21/2019 5/21/2019 5/21/2019 5/21/2019 5/21/2019 5/21/20195/21/20195/20/2019 5/21/2019 5/21/2019 SC-10 (1.5)SC-11 (0.5)SC-11 (1.5)SC-12 (0.5)SC-12 (1.5)SC-13 (0.5)SC-13 (1.5)SC-14 (0.5)SC-15 (0.5)SC-16 (0.5)SC-17 (0.5)SC-10 (0.5)SC-8 (0.5)SC-9 (0.5) Page 2 of 3 Rockingham, Richmond County, North Carolina NONCD0000594 Old Richmond County LF EVALUATION OF WDA EXISTING SOIL COVER FOR USE AS THE PERMANENT COVER SYSTEM TABLE 4 PARAMETER SAMPLE DATE Method 6020B / Method 7471B Antimony 6.3 Arsenic 0.68 Beryllium 31 Cadmium 14 Total Chromium 23,000 Hexavalent Chromium 0.31 Copper 630 Iron 11,000 Lead 400 Manganese 380 Mercury 2.3 Nickel 310 Selenium 78 Silver 78 Thallium 0.16 Zinc 4,700 EPA 350.1 / EPA 353.2 / EPA 9056 Nitrogen, Ammonia 6,200,000,000 Nitrogen, Nitrate 25,000 Sulfate NE EPA 8082A PCB-1248 (Aroclor 1248)0.23 PCB-1254 (Aroclor 1254)0.23 EPA 8260D 2-Butanone (MEK)5,500 Acetone 12,000 Methyl acetate 16,000 Methylene Chloride 58 EPA 8270E No Analytes Detected 3.) Values reported in mg/kg (milligrams per kilogram). 6.) B = The same analyte is found in the associated blank. 7.) BDL = Below Detection Limit 9) Background concentration of Arsenic ranges from 0.442 to 9.21 mg/kg. 8.) Chromium PSRG value based on Chromium (III). 2.) Bold = Indicates concentrations above the corresponding PSRG. 1.) PSRG = North Carolina Department of Environmental Quality Preliminary Soil Remediation (June 2021). 5.) J = The identification of the analyte is acceptable; the reported value is an estimate. Residential Preliminary PSRG (mg/kg) BDL BDL BDL 0.105 BDL BDL 0.274 J BDL BDL BDL BDL 1.47 1.06 1.36 1.37 1.29 0.901 1.17 0.558 J 1.20 1.09 1.62 0.158 J 0.120 J 0.108 J 0.137 0.140 J 0.0846 J 0.0711 J BDL 0.0705 J BDL BDL BDL BDL BDL 0.0382 BDL BDL BDL BDL BDL BDL BDL 6.81 4.74 5.76 4.53 4.06 3.05 3.60 1.91 3.72 2.97 4.87 NA NA NA NA NA NA NA NA NA NA NA 2.87 2.45 2.84 2.27 2.46 1.53 1.95 0.866 J 2.35 1.58 2.51 5,330 3,700 4,740 4,040 3,670 2,630 2,830 1,420 3,630 2,740 3,470 4.20 7.87 4.31 3.22 3.44 2.04 2.15 0.722 2.17 4.40 1.71 18.2 20.5 26.1 18.7 17.1 10.0 7.01 4.18 10.4 13.0 2.97 0.0353 B 0.0253 B 0.0225 B 0.0227 0.0188 J 0.0148 J 0.0162 J 0.00617 J 0.0274 0.0204 J 0.530 3.46 2.36 3.36 1.68 1.56 1.16 1.12 0.525 J 1.35 1.11 0.687 0.256 J 0.250 J 0.365 J 0.272 0.251 J BDL BDL BDL BDL 0.233 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0907 BDL BDL BDL BDL BDL BDL BDL 10.7 14.8 14.0 5.34 7.20 3.70 J 4.56 J 1.80 J 10.6 7.79 6.31 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0691 0.0698 0.0939 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0340 J 0.0745 J 0.0415 J 0.0375 J 0.0667 J BDL 0.0309 J BDL 0.0855 J 0.0540 J 0.0701 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0078 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 5/21/2019 5/21/2019 5/21/20195/21/2019 5/21/2019 5/21/2019 5/21/2019 5/21/2019 5/21/20195/21/2019 5/21/2019 SC-23 (1.5)SC-24 (0.5)SC-24 (1.5)SC-25 (0.5)SC-19 (0.5)SC-20 (0.5)SC-21 (0.5)SC-22 (0.5)SC-22 (1.5)SC-23 (0.5)SC-18 (0.5) Page 3 of 3 Rockingham, Richmond County, North Carolina NONCD0000594 Old Richmond County LF EVALUATION OF WDA EXISTING SOIL COVER FOR USE AS THE PERMANENT COVER SYSTEM TABLE 4 PARAMETER SW-1 SW-2 SAMPLE DATE 4/4/2019 4/4/2019 SAMPLE TIME 10:10 13:30 Temperature ° C 13.6 23.7 Conductivity μs/cm2 175.2 NR Specific Conductance μs/cm2 223.7 222.2 pH std unit 6.53 6.54 Oxidation Reduction Potential (ORP)mV 118.5 4.9 Dissolved Oxygen (DO)mg/L 6.79 4.90 Turbidity (no decant)NTU 6.77 16.9 Turbidity (post decant)NTU NA 12.4 Notes: 1.) NR = Not Recorded 2.) NA = Not Applicable Unit YSI Multiparameter Meter: Professional Plus 2100Q Portable Turbidimeter Page 1 of 1 Rockingham, Richmond County, North Carolina NONCD0000594 Old Richmond County LF NATURAL ATTENUATION PARAMETERS SURFACE WATER TABLE 5 TABLE 6 SURFACE WATER INVESTIGATION Old Richmond County LF NONCD0000594 Rockingham, Richmond County, North Carolina PARAMETER SW-1 SW-DUP (SW-1 DUP)SW-2 EB-1 SAMPLE DATE 4/4/2019 4/4/2019 4/4/2019 4/4/2019 Nitrogen, Ammonia 1900a BDL 0.062 J 0.066 J BDL Arsenic 150b 0.25 0.24 0.35 BDL Copper 1.96c 0.26 J 0.27 J 0.47 J BDL Iron 1,000d 1,180 1,170 2,120 27.6 J Lead 0.35c 0.17 0.092 J 0.16 BDL Manganese 100e 74.9 74.6 132 1.2 Nickel 11.57c 0.29 J 0.29 J 0.30 J 0.32 J Selenium 5 0.088 J 0.080 J 0.089 J BDL Zinc 26.21c BDL BDL 1.6 J 82.4 1,4-Dichlorobenzene 900e 2.7 J 2.9 J 2.7 J 2.4 J Nitrate as N NE 260 260 150 NA Sulfate NE 34,400 34,700 43,100 NA Hexavalent Chromium-Low Level 11b 0.0545 J NA BDL NA Carcinogenic 1.70E-06 Non Carcinogenic 5.20E-02 Notes: 1.) Values reported in µg/L (micrograms per liter). 2.) NC 2B Standard = Title 15A NCAC 2B Surface Water Standard, unless otherwise noted. 9.) Bold = Indicates concentrations above the corresponding standard. 10.) NE = Not Established. 11.) J = The identification of the analyte is acceptable; the reported value is an estimate. 12.) BDL = Below Detection Limit. 13.) NA = Not Analyzed. 8.) e = EPA Nationally Recommended Water Quality Criteria for Aquatic Life & Human Health Class C Fish Consumption Standards. NC 2B Standards (µg/L) Analytical Method EPA 9056A Analytical Method EPA 8270E Metals (ICPMS) by Analytical Method 6020B Ammonia by Analytical Method EPA 350.1 Wet Chemistry by Method 218.6 3.) The sampled surface water body is not classified by the NCDEQ’s Department of Water Resources. However, the surface water body is a tributary which drains into the Hitchcock Creek which is a Class C surface water body. Therefore, Class C standards are used in this table. 4.) a = NC 2B Standard not listed for constituent. Standard used from the EPA document titled "Final Aquatic Life Ambient Water Quality Criteria For Ammonia-Freshwater 2013." The EPA's national recommended final acute ambient water quality criteria (AWQC) for protecting freshwater organisms from potential effects of ammonia is 17,000 µg/L total ammonia nitrogen (TAN) and the final chronic AWQC for ammonia is 1,900 µg/L TAN at pH 7.0 and temperature 20 °C. 5.) b = Chronic NC 2B Standard for Class C waters. 6.) c = Calculated Chronic NC 2B Standard based on the Equations for Hardness-Dependent Metals. An average hardness value of 16.914 is used based on data collected from 3/22/1983 to 12/19/1996 at the NCDEQ’s Ambient Monitoring (AM) Station Q9660000. This AM station is located on Hitchcock Creek, downgradient from sampled surface water body. 7.) d = EPA Nationally Recommended Water Quality Criteria for Aquatic Life & Human Health Class C Aquatic Life Standards. NCDEQ Risk Calculator Direct Contact - Recreator Page 1 of 1 PARAMETER SED-1 SED-DUP (SED-1 DUP)SED-2 SAMPLE DATE 4/4/2019 4/4/2019 4/4/2019 2-Butanone (MEK)5,500 0.0076 J 0.0086 J BDL Acetone 12,000 0.0855 J 0.0450 J BDL Methylene Chloride 58 0.0266 0.0150 J 0.399 J 2-Furanmethanol, 5-ethen NE NR NR 0.637 J 4,4,8-Trimethyltricyclo NE 0.270 J NR 0.882 J Unknown NE 0.274 J 1.520 J 0.830 J Unknown NE 0.441 J NR 0.481 J Unknown NE NR NR 2.080 J Sulfate NE 0.0446 J 0.0476 J 0.220 Mercury 2.3 0.0415 0.0472 0.0669 Arsenic (BG - 1-3 mg/kg)0.68 1.15 1.61 1.79 Beryllium 31 0.128 J BDL 0.148 J Chromium 23,000 5.55 4.62 5.03 Copper 630 3.15 3.51 2.94 Iron 11,000 2,810 3,270 5,720 Lead 250 9.30 8.70 6.30 Manganese 380 21.6 29.6 34.6 Nickel 310 1.65 1.44 1.88 Selenium 78 0.844 J 0.384 J 1.10 Zinc 4,700 8.45 J 5.02 J 5.27 J Hexavalent Chromium 0.31 BDL NA BDL Notes: 1.) Values reported in mg/kg (milligrams per kilogram). 2.) PSRG = North Carolina Department of Environmental Quality Preliminary Soil Remediation Goal (June 2021 2021). 3.) Bold = Indicates concentrations above the respective Residential Health Based PSRG. 4.) BG - Naturally occuring arsenic concentrations in the area range from 1 to 3 mg/kg (USGS NURE database) 5.) J = The identification of the analyte is acceptable; the reported value is an estimate. 6.) BDL = Below Detection Limit. 7.) NE = Not Established. 8.) NR = Not Reported. 9.) Chromium PSRG value based on Chromium (III). 10.) Background concentration for Aresenic ranged from 1 to 3 mg/kg. IC Anions by Analytical Method EPA 9056 Mercury by Method 7471B Metals (ICPMS) by Method 6020B Wet Chemistry by Method 7199 Residential Health Based PSRG (mg/kg) Volatile Organics by Analytical Method EPA 8260D Tentatively Identified Compounds by Analytical Method EPA 8270E Page 1 of 1 Rockingham, Richmond County, North Carolina NONCD0000594 Old Richmond County LF SEDIMENT INVESTIGATION TABLE 7 TM-1 5/8/2019 5/13/2019 35.0005927 -79.7723234 2 10-20 20.00 386.51 11.75 374.76 TM-2 5/8/2019 5/13/2019 34.9999201 -79.7723514 2 5-15 15.00 375.93 8.83 367.10 TM-3 5/8/2019 5/13/2019 34.9996910 -79.7730492 2 16-26 26.00 388.12 19.24 368.88 TM-4 5/8/2019 5/13/2019 34.9995567 79.7753909 2 24-34 34.00 415.51 31.39 384.12 TM-5 5/8/2019 5/13/2019 34.9993056 79.7744184 2 20-30 30.00 401.55 20.34 381.21 TM-6 5/8/2019 5/13/2019 35.0006693 79.7734874 2 25-35 35.00 409.53 26.62 382.91 TM-7 5/8/2019 5/13/2019 35.0004366 79.7744934 2 15-25 25.00 395.74 16.94 378.80 Notes: 1.) GPS coordinates tied to the World Geodectic System (WGS84). 2.) Groundwater elevations and contours tied to WGS 84 Datum. Groundwater Elevation (feet) Monitoring Well ID Date Installed Date Measured Latitude Longitude Well Casing Diameter (inches) Screen Interval (feet) Well Depth (feet) Top of Casing Elevation (feet)Depth to Water (feet) Rockingham, Richmond County, North Carolina NONCD0000594 Old Richmond County LF GROUNDWATER INVESTIGATION - WELL CONSTRUCTION TABLE 8 TABLE 9 GROUNDWATER ANALYTICAL DATA Old Richmond County Landfill NONCD0000594 Rockingham, Richmond County, North Carolina PARAMETER TMW-1 TMW-2 TMW-3 TMW-4 TMW-5 DUP-B (Dup to TW-5)TMW-6 TMW-7 DUP-C (Dup to TW-7) SAMPLE DATE 5/14/2019 5/14/2019 5/14/2019 5/13/2019 5/13/2019 5/13/2019 5/13/2019 5/14/2019 5/14/2019 PCBs Aroclor’s via USEPA Method 8082A (Unit-specified change from PCBs and congeners by EPA Method 1668) in μg/L No analytes detected above laboratory detection limits. METALS (ICPMS) by Method 6020B in μg/L Arsenic 10 0.27 0.16 BDL 0.16 0.82 0.14 0.19 0.26 0.36 Cadmium 2 0.57 BDL BDL BDL BDL BDL BDL BDL BDL Chromium 10 BDL BDL BDL BDL 2.3 BDL BDL 0.51 0.87 Copper 1,000 29.5 40.4 BDL 32.5 2.2 39.0 38.4 61.9 115 Iron 300 58.3 251 27.7 J 141 1,090 202 298 145 355 Lead 15 0.20 0.22 BDL 0.11 2.2 0.10 0.13 0.23 0.74 Manganese 50 91.7 74.4 0.55 51.2 35.9 16.4 16.2 43.2 7.2 Nickel 100 4.9 1.4 BDL 4.2 2.0 1.1 1.1 3.0 0.91 Selenium 20 0.18 J 0.084 J BDL 0.17 J 0.22 J 0.095 J 0.088 J 0.80 0.11 J Zinc 1,000 135 30.2 BDL 31.3 6.3 26.6 26.4 30.8 55.1 MERCURY by Method 7470A in μg/L No analytes detected above laboratory detection limits. SEMI-VOLATILE ORGANIC COMPOUNDS (GC/MS) by EPA 8270E by SIM in μg/L 2-Methylnaphthalene 30 BDL BDL 0.010 J BDL 0.011 J BDL 0.0084 J BDL 0.0098 J Fluoranthene 300 BDL BDL 0.020 J BDL BDL BDL BDL BDL BDL TENTATIVELY IDENTIFIED COMPOUNDS - SVOCS (GC/MS) by Method 8270E in μg/L 1,2:4,5-Dibenzopyrene NE NA NA NA 6.1 J 9.0 J NA NA NA NA Hexadecanoic acid NE NA NA NA NA NA NA 6.2 J 6.7 J NA Undecane NE NA NA NA 6.1 J 5.7 J NA 6.4 J NA NA Unknown NE NA NA NA NA 7.2 J 5.3 J 6.3 J 8.5 J NA Unknown NE NA NA NA NA 5.6 J NA 5.0 J NA NA VOLATILE ORGANIC COMPOUNDS (GC/MS) by Method 8260D in μg/L 1,4-Dioxane (p-Dioxane)3 BDL BDL BDL 1.4 J BDL BDL BDL BDL BDL Acetone 6,000 10.6 J BDL 27.8 BDL BDL BDL BDL BDL BDL Toluene 600 BDL BDL BDL BDL 0.54 J 0.51 J BDL BDL BDL TENTATIVELY IDENTIFIED COMPOUNDS - VOCS (GC/MS) by Method 8260D in μg/L Isopropyl Alcohol NE 18.4 J NA 66.5 J NA 6.6 J NA NA NA NA Unknown NE 38.0 J 44.4 J 39.2 J 17.2 J 29.5 J 30.1 J 49.3 J 17.8 J 16.8 J Unknown NE NA 19.6 J NA NA NA 8.0 J 18.3 J 114 J 142 J Unknown NE NA 16.0 J NA NA NA NA NA NA NA NITRATE & SULFATE in μg/L by Method 9056A in μg/L Nitrate as N 10,000 5,000 8,500 3,500 72 J 2,200 2,200 4,800 850 850 Sulfate 250,000 600 J 68,300 12,200 800 J 10,200 10,600 880 J BDL BDL ADDITIONAL ANALYTES by EPA 350.1 Rev 2.0 1993 in μg/L Nitrogen, Ammonia 1,500 BDL 54 J 200 BDL BDL BDL BDL BDL BDL Carcinogenic 1.90E-05 Non Carcinogenic 9.20E-01 Carcinogenic 3.80E-06 Non Carcinogenic 1.50E-01 Notes: 1.) Values reported in µg/L (micrograms per liter). 2.) NC 2L Standards = 15A NCAC 02L .0202 Groundwater Quality Standards established by North Carolina Department of Environmental Quality in 2013. 3.) Bold = Indicates concentrations above the corresponding 2L Standard. 4.) J = Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. 5.) NE = Not Established 6.) BDL = Not Detected at or above adjusted reporting limit. 7.) NA = Not Applicable NC 2L STANDARDS (μg/L) NCDEQ Risk Calculator Direct Contact - Residential Groundwater Use Direct Contact - Non Residential Groundwater Use Page 1 of 1 TABLE 10 POTABLE WATER SUPPLY WELL SAMPLING Old Richmond County LF NONCD0000594 Rockingham, Richmond County, North Carolina WSW-4 DUP-A 34.9972141 34.9972141 -79.7721421 -79.7721421 7/15/2020 7/15/2020 µg/L µg/L 300 300 113 ND 50 50 90.4 88.6 250,000 250,000 4,970 J 5,000 Notes: 1. μg/L = Micrograms per liter. 2. ND = Below Laboratory Reporting Limit. 3. J = Concentration estimate above method detection limit, but below reporting limit. 4. BOLD = Values above MCLs for drinking water or NC 2L Standard for groundwater. 15A NCAC 02L Groundwater Standards (µg/L) Sulfate SAMPLE ID Latitude Longitude Sample Date Constituents Iron Manganese Metals by Method 6020B Method 9056A Maximum Contaminant Levels for Drinking Water (µg/L) VOCs Carbon Dioxide Oxygen Hydrogen Sulfide Barometric Pressure Relative Humidity Temperature (ppm)(%Vol)(%LEL)(µg/m³)(%Vol)(%Vol)(ppm)(inches Hg)(%)(°F) BG-1 7/29/2020 12:49 0.1 0.0 0.0 0.00 0.0 20.7 0 29.58 52.4 98 5/16/2019 8:43 0.1 0.0 0.0 0.00 5.4 15.6 1 29.62 55.6 58.1 7/29/2020 12:52 0.2 0.0 0.0 0.00 4.6 16.5 0 5/16/2019 8:49 1.1 0.0 0.0 0.00 1.9 19.1 0 7/29/2020 12:56 0.1 0.0 0.0 0.00 1.4 19.4 0 5/16/2019 8:55 0.9 0.0 0.0 0.00 3.5 17.5 0 7/29/2020 13:00 0.1 0.0 0.0 0.00 2.6 18.7 0 5/16/2019 9:00 0.6 0.0 0.0 0.00 11.9 9.4 0 7/29/2020 13:04 0.1 0.0 0.0 0.00 11.6 10.3 0 5/16/2019 9:04 0.7 0.0 0.0 0.00 13.1 6.6 0 7/29/2020 13:08 0.3 0.0 0.0 0.00 12.3 9.1 0 5/16/2019 9:07 0.7 0.0 0.0 0.00 0.6 20.7 0 7/29/2020 13:12 0.0 0.0 0.0 0.00 0.6 20.1 0 5/16/2019 9:12 0.2 0.0 0.0 0.00 9.3 11.0 0 7/29/2020 13:16 0.1 0.0 0.0 0.00 3.6 17.3 0 5/16/2019 9:15 0.4 0.0 0.0 0.00 3.9 17.3 0 7/29/2020 13:20 0.0 0.0 0.0 0.00 2.3 18.7 0 5/16/2019 9:21 2.2 0.0 0.0 0.00 4.5 17.1 0 7/29/2020 13:24 0.0 0.0 0.0 0.00 4.0 17.3 0 5/16/2019 9:27 1.0 0.0 0.0 0.00 1.5 20.2 0 7/29/2020 13:27 0.1 0.0 0.0 0.00 1.0 20.1 0 GP-11 7/29/2020 13:33 0.2 0.0 0.0 0.00 0.4 20.6 0 GP-12 7/29/2020 13:36 0.1 0.0 0.0 0.00 0.8 20.3 0 GP-13 7/29/2020 13:38 0.1 0.0 0.0 0.00 0.4 20.7 0 GP-14 7/29/2020 13:42 0.1 0.0 0.0 0.00 0.5 20.6 0 GP-15 7/29/2020 13:46 0.2 0.0 0.0 0.00 1.4 19.8 0 29.58 64.4 92 GP-16 7/29/2020 13:49 0.1 0.0 0.0 0.00 7.9 13.6 0 GP-17 7/29/2020 13:54 0.2 0.0 0.0 0.00 0.4 20.8 0 GP-18 7/29/2020 13:57 0.2 0.0 0.0 0.00 0.2 21.1 0 DUP-D 7/29/2020 14:00 0.3 0.0 0.0 0.00 1.4 19.9 0 Notes: 1.) VOCs = Volatile Organic Compounds. 2.) LEL = Lower Explosive Limit. Readings which exceeded the LEL of 5% for Methane are recorded as ">100." 3.) µg/m³ = Micrograms per cubic meter. 4.) Hg = Mercury. 5.) ppm = Parts Per Million. 6.) Methane (µg/m³) calculated using the following forumla: = [(% by volume)*10,000*16.04 / 24.45]*1000, where 16.04 grams/mol is the molecular weight of Methane and 24.45 is a conversion factor that represents the volume of one mole of gas in liters. SAMPLE ID DATE TIME Methane GP-1 GP-2 GP-3 GP-4 GP-5 GP-10 GP-9 GP-6 GP-7 GP-8 Rockingham, Richmond County, North Carolina NONCD0000594 Old Richmond County LF LANDFILL GAS SURVEY RESULTS TABLE 11 TABLE 12 SOIL GAS PROBE RESULTS Old Richmond County Landfill NONCD0000594 Rockingham, Richmond County, North Carolina GP-1 GP-2 GP-3 GP-4 GP-10 DUP-C (GP-10)GP-11 GP-12 GP-13 GP-14 GP-15 GP-16 GP-17 GP-18 34.9996710 35.0002161 35.0003549 34.9999160 34.9996020 34.9996020 34.9995681 34.9999680 35.0002408 35.0003574 34.9996765 34.9994157 34.9995341 34.9996601 -79.7747728 -79.7748066 -79.7742352 -79.7738618 -79.7738855 -79.7738855 -79.7750967 -79.7749930 -79.7749779 -79.7747336 -79.7738622 -79.7744226 -79.7733378 -79.7737415 7/28/2020 7/28/2020 7/28/2020 7/28/2020 7/27/2020 7/27/2020 7/27/2020 7/27/2020 7/27/2020 7/27/2020 7/27/2020 7/28/2020 7/28/2020 7/28/2020 µg/m3 µg/m3 µg/m3 µg/m3 µg/m3 µg/m3 µg/m3 µg/m3 µg/m3 µg/m3 µg/m3 µg/m3 µg/m3 µg/m3 35,000 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 2.93 BDL BDL NE BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 5.80 BDL BDL 420 6.97 21.0 36.6 3.75 21.4 25.3 13.4 3.06 9.72 5.40 2.83 2.89 6.82 7.51 NE 51.0 3.57 9.44 70.6 BDL BDL 7.20 6.41 BDL 2.38 2.75 14.0 BDL BDL 420 1.59 4.29 7.56 BDL 4.23 5.06 2.77 BDL 2.14 1.04 BDL BDL 1.63 1.51 NE BDL BDL BDL BDL 10.5 12.5 BDL BDL 2.00 BDL BDL BDL BDL BDL 19 1.02 BDL BDL BDL BDL BDL 1.07 BDL 2.40 BDL BDL BDL BDL BDL 35,000 7.25 3.75 BDL BDL BDL BDL 7.7 BDL 7.61 4.28 BDL BDL BDL 5.54 1,400 12.8 13.3 12.3 12.9 3.12 BDL 34.9 21.5 12.0 8.78 6.61 31.5 25.1 27.3 NE 5.06 8.98 14.5 2.29 10.1 11.8 7.56 2.12 6.38 3.94 2.03 1.89 4.73 3.74 220,000 49.0 18.0 8.13 9.67 18.2 14.4 39.2 16.0 34.2 15.7 22.5 12.4 28.5 27.1 12 BDL BDL BDL BDL BDL BDL BDL BDL 0.920 BDL BDL BDL BDL BDL 2.5 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 10.8 BDL 4,900 8.43 8.93 BDL 9.00 3.17 3.67 20.6 12.7 8.06 6.88 8.03 6.75 11.3 4.42 350 BDL 1.48 2.07 1.90 BDL BDL BDL 1.52 BDL BDL BDL BDL 1.9 2.05 4.1 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 243 BDL 630 0.832 0.744 0.777 BDL 1.10 1.77 0.787 BDL 1.16 1.01 BDL 1.81 0.494 1.47 NE BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 4.84 0.860 700 239 5.19 16.1 43.6 5.34 5.49 9.69 6.78 3.4 3.35 7.27 33.6 2.86 3.16 NE 39.8 35.1 28.3 29.4 25.3 17.0 40.0 40.7 35.3 15.4 104 45.3 42.8 120 37 BDL BDL BDL BDL 0.897 0.897 1.47 BDL 1.28 0.889 1.45 BDL 0.932 BDL 2,800 BDL BDL BDL BDL BDL BDL 1.10 BDL 1.1 BDL BDL BDL BDL BDL 700 3.23 BDL BDL 2.38 3.56 3.42 5.07 3.07 4.94 2.78 3.20 1.96 3.46 2.63 3,400 BDL 4.48 1.74 1.00 12.3 BDL BDL BDL BDL BDL BDL 0.944 4.97 BDL 4,900 13.0 2.30 3.30 BDL 26.0 8.74 9.52 BDL 29.9 17.0 3.39 BDL 5.22 BDL 700 1.45 0.915 0.889 1.32 1.59 1.57 3.70 1.80 3.11 2.75 1.76 1.27 1.72 1.55 21,000 3.27 B 1.54 B 1.72 B 1.81 B 1.96 B 1.98 B 2.19 B 1.37 B 1.86 B 2.19 B 2.41 B 2.03 B 1.54 B 1.70 B 7,000 1.17 BDL 1.09 1.11 BDL 0.923 5.19 1.11 1.89 1.26 1.55 1.01 1.16 1.23 280 21.8 19.5 50.2 15.1 3.16 4.64 2.51 21.7 1.91 BDL 5.09 46.2 132 8.96 NE 3.83 BDL BDL BDL BDL BDL BDL BDL 6.55 BDL BDL BDL BDL BDL 35,000 3.43 1.90 1.52 2.28 4.52 3.02 3.64 2.52 4.11 2.61 3.62 2.23 3.68 2.88 NE BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 2.03 BDL BDL 14 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1.32 7.13 BDL Trichlorofluoromethane NE 142 10.3 95.5 127 4.13 4.34 7.53 5.00 2.37 3.47 9.33 26.2 1.68 1.92 6.50E-05 3.70E-01 5.00E-06 3.00E-02 Notes: 1. μg/m3 - Micrograms per Cubic Meter. 2. B - The same analyte is found in the associated blank. 3. BDL - Below detection limit 4. SGSL - North Carolina Department of Environmental Quality Residential Soil Gas Screening Levels (updated July 2020). 5. - Bold - concentration exceeds Residential SGSL 6. NE - Residential SGSL Not Established. Carcinogenic Non Carcinogenic Vapor Intrusion - Non Residential Soil Gas to Indoor Air Carcinogenic Non Carcinogenic Toluene trans-1,2-Dichloroethene Trichloroethylene Vapor Intrusion - Residential Soil Gas to Indoor Air n-Hexane o-Xylene Propene Styrene Tetrachloroethylene Tetrahydrofuran NCDEQ Risk Calculator Methylene Chloride Bromodichloromethane Carbon disulfide Chlorobenzene Chloroform Chloromethane cis-1,2-Dichloroethene Dichlorodifluoromethane Ethanol Ethylbenzene Heptane m&p-Xylene Benzene 1,1,1-Trichloroethane 1,1,2-Trichlorotrifluoroethane 1,2,4-Trimethylbenzene 1,2-Dichlorotetrafluoroethane 1,3,5-Trimethylbenzene 1,3-Dichlorobenzene 1,4-Dioxane 2-Butanone (MEK) 2-Propanol 4-Ethyltoluene Acetone SAMPLE ID Residential SGSLs (µg/m3) Latitude Longitude Sample Date Constituents FIGURES PO P P Y S E E D D R I V E WASTE DISPOSAL AREA A (4.683 ACRES) WOODED TREE AREA (2.95 ACRES) X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E HO U S E TR A I L E R W W W W W W W W W W W W W W W W W W W W W W W W W W W W W W W W W W W W T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T W W W W W W W W W W W W W W W W W W W W W W W W W W W OHE OH E OH E OH E OH E OH E OH E OH E OH E OH E OH E OH E OH E OH E OH E OH E OH E OHE OHE OHE OHE OHE OHE OHE OHE OHE OHE OHE OHE OHE OHE OHE SUBJECT PROPERTY N/FDAVID M. TARLTON & WIFE, TAMMIE J. TARLTON PIN # 746502854954 DB 1368 PG 124 DB 1733 PG 360 PLAT 783 PAGE Q 14.158 ACRES (616,711 SF) THIS PORTION OF THE SUBJECT PROPERTY DESCRIBED IN DB 1733 PG 360 PROPERTY NOTE: RICHMOND COUNTY GIS SHOWS THIS AREA BEING A PORTION OF THE SUBJECT PROPERTY, BUT THE SURVEYOR FOUND NO LEGAL REFERENCE FOR A RECOMBINATION OF THE LEGAL LOTS. THIS AREA WAS ACQUIRED BY THE TARLTON'S BY WAY OF THE SAME DEED THAT IS REFERENCED FOR THE PROPERTY LYING SOUTH OF THE SUBJECT PROPERTY. GIS LINE ONLY - SHOWN APPROXIMATE 410 410 410 400 400 390 390 380 390 380 390 390 390 412 41 4 41 6 408 406 404 402 398 396 394 392 388 386 384 382 408 406 404 402 400 394 398402 39 6 394 392 392 394 396 38 8 378 382 384 38638 2 38 4 388 39 2 384 384 384 386 38 8 402 396 398 398 386 P P P P NOTE: ALL LOCATIONS ARE APPROXIMATE TOPOGRAPHIC CONTOUR LEGEND: RICHMOND COUNTY PARCELS SITE PROPERTY LINE T T E E TELEPHONE LINE ELECTRICAL UNDERGROUND OHU OVERHEAD UTILITY W W WATER LINE X X FENCE/ELECTRIC FENCE UTILITY POLEP 410 WASTE DISPOSAL AREA B (0.210 ACRES) WOODED TREE AREA (0.19 ACRES) S SEPTIC SYSTEM & LEACH FIELD X X X XXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXX X X X X X X XXXXXXXXXXXXXXXXXXXXXXX SURFACE WASTE 1 WETLAND/STREAM BOUNDARY BERM-1 AUTOMOBILES HAVE BEEN REMOVED DEPRESSION IMAGERY PROVIDED BY MAP DATA © 2019 GOOGLE, INEGI SCALE: 1" = 100' 100 0 25 1005075 N SPRING Figure: Dra w i n g F i l e : Pr o j e c t N u m b e r : Ck d . B y : Dr n . B y : Ap p ' d B y : Ck d . D a t e : Scale: Date: H: \ 2 0 2 0 \ O T H E R O F F I C E S \ N O R T H C A R O L I N A \ N C D E N R P R E - R E G U L A T O R Y L A N D F I L L \ O L D R I C H M O N D C O . L A N D F I L L \ P R L U 0 5 9 4 C - S I T E . D W G , FI G 1 SI T E M A P NO T E S : 1. Fe a t u r e s s h o w n a r e n o t a n a u t h o r i t a t i v e l o c a t i o n , n o r a r e t h e y p r e s e n t e d to a s t a t e d a c c u r a c y . 2. St r e a m / W e t l a n d l o c a t i o n p r o v i d e d b y N a t i o n a l W e t l a n d s I n v e n t o r y . 3. Se e r e p o r t f o r T a s k O r d e r 5 9 4 W S - 1 f o r w a t e r s u p p l y w e l l l o c a t i o n s . CO O R D I N A T E S Y S T E M : NA D 1 9 8 3 N O R T H C A R O L I N A S T A T E P L A N E F I P S 3 2 0 0 , U S S U R V E Y F E E T 06/14/2021 SE E L O W E R L E F T OL D R I C H M O N D C O U N T Y L F RO C K I N G H A M , R I C H M O N D C O U N T Y , N O R T H C A R O L I N A PR L U 0 5 9 4 C AS SHOWN DH SL 1 360 360 37 0 370 370 380 380 380 380 380 39 0 39 0400410420 362 362 364 364 366 366 366 366 36 8 368 368 37 2 372 372 37 4 374 374 37 6 376 376 378 378 37 8 37 8 378 38 2 382 38 4 384386 38 6 38 8 38 8 39 2 39 2394 39 4 396 39 6 398402404406408412 41 4 414416 416 418 418 PO P P Y S E E D D R I V E HA-5 HA-6 HA-4 HA-3HA-2HA-1 HA-7 HA-11 HA-8 HA-9 HA-10 X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X GIS LINE ONLY - SHOWN APPROXIMATE 410 410 410 400 400 390 390 380 390 380 390 390 390 412 41 4 41 6 408 406 404 402 398 396 394 392 388 386 384 382 408 406 404 402 400 394 398402 39 6 394 392 392 394 396 38 8 378 382 384 38638 2 38 4 388 39 2 384 384 384 386 38 8 402 396 398 398 386 B-18B B-18A B-17G B-17A B-17B B-17JB-17C B-17H B-17F B-17D B-17I B-17E B-10A B-10B B-10C B-9A B-9B B-8B B-8A B-7B B-6B B-6A B-5A B-5B B-5C B-4A B-4B B-3B B-3A B-2A B-2B B-2C B-1CB-1A B-1B B-14A B-14B B-13A B-13B B-12A B-11A B-11BB-12B B-3C B-3D B-3E B-15B B-15A B-16D B-16B B-16C B-16A WASTE DISPOSAL AREA A WASTE DISPOSAL AREA B SCALE: 1" = 100' 100 0 25 1005075 N NOTE: ALL LOCATIONS ARE APPROXIMATE TOPOGRAPHIC CONTOUR LEGEND: RICHMOND COUNTY PARCELS SITE PROPERTY LINE 410 HA-1 HAND AUGER Boring Identification B-13B SOIL BORING Boring Identification WETLAND/STREAM BOUNDARY STRUCTURES ROADS B-7A BERM-1 Figure: Dra w i n g F i l e : Pr o j e c t N u m b e r : Ck d . B y : Dr n . B y : Ap p ' d B y : Ck d . D a t e : Scale: Date: H: \ 2 0 2 0 \ O T H E R O F F I C E S \ N O R T H C A R O L I N A \ N C D E N R P R E - R E G U L A T O R Y L A N D F I L L \ O L D R I C H M O N D C O . L A N D F I L L \ P R L U 0 5 9 4 C - H A 1 . D W G , FIG 2 WA S T E D I S P O S A L A R E A D E L I N E A T I O N B O R I N G S 07/15/2021 SE E L O W E R L E F T OL D R I C H M O N D C O U N T Y L A N D F I L L RO C K I N G H A M , R I C H M O N D C O U N T Y , N O R T H C A R O L I N A PR L U 0 5 9 4 C AS SHOWN DH SL 2 NO T E S : 1. Fe a t u r e s s h o w n a r e n o t a n a u t h o r i t a t i v e l o c a t i o n , n o r a r e t h e y p r e s e n t e d to a s t a t e d a c c u r a c y . CO O R D I N A T E S Y S T E M : NA D 1 9 8 3 N O R T H C A R O L I N A S T A T E P L A N E F I P S 3 2 0 0 , U S S U R V E Y F E E T PO P P Y S E E D D R I V E HO U S E TR A I L E R GIS LINE ONLY - SHOWN APPROXIMATE 410 410 410 400 400 390 390 380 390 380 390 390 390 412 41 4 41 6 408 406 404 402 398 396 394 392 388 386 384 382 408 406 404 402 400 394 398402 39 6 394 392 392 394 396 38 8 378 382 384 38638 2 38 4 388 39 2 384 384 384 386 38 8 402 396 398 398 386 WASTE DISPOSAL AREA B AGV-7 AGV-8 AGV-9 AGV-10 AGV-13 AGV-12 AGV-11 AGV-26 AGV-25 AGV-29 AGV-32 AGV-33 AGV-30AGV-31 AGV-34 AGV-28 AGV-27 AGV-35 AGV-36 AGV-24 AGV-23 AGV-14 AGV-4 AGV-15 AGV-22 AGV-21 AGV-6 AGV-5 AGV-2AGV-1 AGV-17AGV-18 AGV-16 AGV-20 AGV-19 AGV-37 AGV-38 AGV-3 WASTE DISPOSAL AREA A 360 360 37 0 370 370 380 380 380 380 380 39 0 39 0400410420 362 362 364 364 366 366 366 366 36 8 368 368 37 2 372 372 37 4 374 374 37 6 376 376 378 378 37 8 37 8 378 38 2 382 38 4 384386 38 6 38 8 38 8 39 2 39 2394 39 4 396 39 6 398402404406408412 41 4 414416 416 418 418 NOTE: ALL LOCATIONS ARE APPROXIMATE TOPOGRAPHIC CONTOUR LEGEND: RICHMOND COUNTY PARCELS SITE PROPERTY LINE 410 AGV-1 ABOVE GROUND VAPOR POINT Point Identification WETLAND/STREAM BOUNDARY SCALE: 1" = 100' 100 0 25 1005075 N STRUCTURES ROADS PID -0.2 ppm Figure: Dra w i n g F i l e : Pr o j e c t N u m b e r : Ck d . B y : Dr n . B y : Ap p ' d B y : Ck d . D a t e : Scale: Date: H: \ 2 0 2 0 \ O T H E R O F F I C E S \ N O R T H C A R O L I N A \ N C D E N R P R E - R E G U L A T O R Y L A N D F I L L \ O L D R I C H M O N D C O . L A N D F I L L \ P R L U 0 5 9 4 C - V A P O R . D W G , FI G 1 0 AB O V E G R O U N D V A P O R S U R V E Y NO T E S : 1. Fe a t u r e s s h o w n a r e n o t a n a u t h o r i t a t i v e l o c a t i o n , n o r a r e t h e y p r e s e n t e d to a s t a t e d a c c u r a c y . CO O R D I N A T E S Y S T E M : NA D 1 9 8 3 N O R T H C A R O L I N A S T A T E P L A N E F I P S 3 2 0 0 , U S S U R V E Y F E E T 07/08/2021 SE E L O W E R L E F T OL D R I C H M O N D C O U N T Y L F RO C K I N G H A M , R I C H M O N D C O U N T Y , N O R T H C A R O L I N A PR L U 0 5 9 4 C AS SHOWN DH SL 3 PO P P Y S E E D D R I V E X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X HO U S E TR A I L E R THIS PORTION OF THE SUBJECT PROPERTY DESCRIBED IN DB 1733 PG 360 GIS LINE ONLY - SHOWN APPROXIMATE 410 410 410 400 400 390 390 380 390 380 390 390 390 412 41 4 41 6 408 406 404 402 398 396 394 392 388 386 384 382 408 406 404 402 400 394 398402 39 6 394 392 392 394 396 38 8 378 382 384 38638 2 38 4 388 39 2 384 384 384 386 38 8 402 396 398 398 386 WASTE DISPOSAL AREA B X X X XXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXX X X X X X X XXXXXXXXXXXXXXXXXXXXXXX SB-17 SB-16 SB-11 SB-12 SB-13 SB-14 SB-15 B-18B B-18A SB-21 SB-20 SB-19 SB-18 B-17G B-17A B-17B B-17J B-17C B-17H B-17F B-17D B-17ISB-10 B-17E B-10A B-10B B-10C B-9A B-9B B-8B B-8A B-7B B-6B B-6AB-5A B-5B B-5C B-4A B-4B B-3B B-3A B-2A B-2B B-2C B-1CB-1A B-1B B-14A B-14B B-13A B-13B SB-3 B-12A B-11A B-11B B-12B SB-2 SB-6 SB-7 SB-8 SB-9 SB-5 SB-4 SB-1 B-7A BERM-1 B-15A B-15B B-16D B-16B B-16CB-16A B-3C B-3D B-3E WASTE DISPOSAL AREA A SCALE: 1" = 100' 100 0 25 1005075 N NOTE: ALL LOCATIONS ARE APPROXIMATE TOPOGRAPHIC CONTOUR LEGEND: RICHMOND COUNTY PARCELS SITE PROPERTY LINE 410 SOIL BORING LOCATION Boring Identification SB-11 X X FENCE WETLAND/STREAM BOUNDARY STRUCTURES ROADS Figure: Dra w i n g F i l e : Pr o j e c t N u m b e r : Ck d . B y : Dr n . B y : Ap p ' d B y : Ck d . D a t e : Scale: Date: H: \ 2 0 2 0 \ O T H E R O F F I C E S \ N O R T H C A R O L I N A \ N C D E N R P R E - R E G U L A T O R Y L A N D F I L L \ O L D R I C H M O N D C O . L A N D F I L L \ P R L U 0 5 9 4 C - W A S T E 6 . D W G , FI G 6 WA S T E A N D S O I L B O R I N G E X C E E D A N C E S NO T E S : 1. Fe a t u r e s s h o w n a r e n o t a n a u t h o r i t a t i v e l o c a t i o n , n o r a r e t h e y p r e s e n t e d to a s t a t e d a c c u r a c y . 2. = E x c e e d a n c e s o f t h e R e s i d e n t i a l H e a l t h B a s e d P S R G s St a n d a r d s . 3. mg / k g = m i l l i g r a m s p e r k i l o g r a m . 4. J = E s t i m a t e d v a l u e b e t w e e n t h e l a b o r a t o r y r e p o r t i n g a n d m e t h o d de t e c t i o n l i m i t s . 5. W = W a s t e 6. NG = N a t i v e G r o u n d CO O R D I N A T E S Y S T E M : NA D 1 9 8 3 N O R T H C A R O L I N A S T A T E P L A N E F I P S 3 2 0 0 , U S S U R V E Y F E E T 07/14/2021 SE E L O W E R L E F T OL D R I C H M O N D C O U N T Y L F RO C K I N G H A M , R I C H M O N D C O U N T Y , N O R T H C A R O L I N A PR L U 0 5 9 4 C AS SHOWN DH SL 4 BO L D PO P P Y S E E D D R I V E SB-16 HA-2 HA-1 HA-7 SB-3 SB-2 SB-6 SB-7 SB-8 SB-9 SB-5 SB-1 GIS LINE ONLY - SHOWN APPROXIMATE B-18B B-17A B-17C B-17D B-17I SB-10 B-17E B-10B B-10C B-9B B-8B B-6B B-5A B-5B B-4B B-3B B-2C B-1C B-14A B-13A B-12A B-11A SB-4 B-3DB-15A B-16B WASTE DISPOSAL AREA A WASTE DISPOSAL AREA B B-7A SC-1 SC-2 SC-3 SC-4 SC-5 SC-6 SC-7 SC-8 SC-9 SC-10 SC-11 SC-12 SC-13 SC-14 SC-15 SC-16 SC-17 SC-18 SC-19 SC-20 SC-21 SC-22 SC-23 SC-24 SC-25 15" 15" 12" 12" 18" 21" 36" 18"36" 12"36" 18" 36" 21" 12" 12" 18" 15" 24" 36" 12" 15" 36" 36" 36" 18" 30" 24" BERM-112" 48"48" 48" 36" 15" 18" 36" 48" 48" 24" 72" 30" 48" 24" 18"30" 18" 60" 30" 15" 36" 18" 18" 12" 12" 24" 12" 66" 12" 60" 48" 60" 36" 30" 60" 18"0"-18" SCALE: 1" = 100' 100 0 25 1005075 N NOTE: ALL LOCATIONS ARE APPROXIMATE TOPOGRAPHIC CONTOUR LEGEND: RICHMOND COUNTY PARCELS SITE PROPERTY LINE HA-1 HAND AUGER Boring Identification SOIL COVER POINTSSC-22 Well Identification Soil Cover Thickness 36" 18" < 36" SOIL COVER THICKNESS 0" < 18" SOIL COVER THICKNESS WETLAND/STREAM BOUNDARY STRUCTURES ROADS Figure: Dra w i n g F i l e : Pr o j e c t N u m b e r : Ck d . B y : Dr n . B y : Ap p ' d B y : Ck d . D a t e : Scale: Date: H: \ 2 0 2 0 \ O T H E R O F F I C E S \ N O R T H C A R O L I N A \ N C D E N R P R E - R E G U L A T O R Y L A N D F I L L \ O L D R I C H M O N D C O . L A N D F I L L \ P R L U 0 5 9 4 C - W A S T E 7 . D W G , FI G 4 SO I L C O V E R T H I C K N E S S 07/01/2021 SE E L O W E R L E F T OL D R I C H M O N D C O U N T Y L F RO C K I N G H A M , R I C H M O N D C O U N T Y , N O R T H C A R O L I N A PR L U 0 5 9 4 C AS SHOWN DH SL 5 NO T E S : 1. Fe a t u r e s s h o w n a r e n o t a n a u t h o r i t a t i v e l o c a t i o n , n o r a r e t h e y p r e s e n t e d to a s t a t e d a c c u r a c y . 2. Fig u r e u p d a t e d i n a c c o r d a n c e t o T a s k O r d e r 5 9 4 D P - 8 , S u b t a s k F . 3. Wa s t e d i s p o s a l a r e a b o u n d a r y u p d a t e d f r o m r e c e n t w a s t e d e l i n e a t i o n ac t i v i t i e s . CO O R D I N A T E S Y S T E M : NA D 1 9 8 3 N O R T H C A R O L I N A S T A T E P L A N E F I P S 3 2 0 0 , U S S U R V E Y F E E T PO P P Y S E E D D R I V E HO U S E TR A I L E R GIS LINE ONLY - SHOWN APPROXIMATE WASTE DISPOSAL AREA B (0.210 ACRES) (WASTE VOLUME = 1,900 yd^³) WASTE DISPOSAL AREA A (4.683 ACRES) (WASTE VOLUME = 29,900 yd^³) BERM-1 SB-17 SB-16 B-18B B-17A B-17C B-17D B-17I SB-10 B-17E B-10C B-9B B-8B B-14A SB-3 SB-2 SB-6 SB-7 SB-8 SB-9 SB-5 SB-4 SB-1 B-15A B-16B B-3D 5.0 0.5 6.5 4.0 10 10 8.0 3.0 4.0 4.0 2.0 4.0 5.5 6.0 4.0 5.5 3.0 1.5 2.5 2.0 1.0 5.0 2.0 1.5 SCALE: 1" = 100' 100 0 25 1005075 N TOPOGRAPHIC CONTOUR LEGEND: RICHMOND COUNTY PARCELS SITE PROPERTY LINE SOIL BORING LOCATIONSB-7 Boring Identification Soil Cover Thickness 7.5' < 10 WASTE THICKNESS 5' < 7.5' WASTE THICKNESS 2.5' < 5' WASTE THICKNESS 0' < 2.5' WASTE THICKNESS NOTE: ALL LOCATIONS ARE APPROXIMATE 2.5 WETLAND/STREAM BOUNDARY STRUCTURES ROADS Figure: Dra w i n g F i l e : Pr o j e c t N u m b e r : Ck d . B y : Dr n . B y : Ap p ' d B y : Ck d . D a t e : Scale: Date: H: \ 2 0 2 0 \ O T H E R O F F I C E S \ N O R T H C A R O L I N A \ N C D E N R P R E - R E G U L A T O R Y L A N D F I L L \ O L D R I C H M O N D C O . L A N D F I L L \ P R L U 0 5 9 4 C - W A S T E 8 . D W G , FI G 5 WA S T E T H I C K N E S S NO T E S : 1. Fe a t u r e s s h o w n a r e n o t a n a u t h o r i t a t i v e l o c a t i o n , n o r a r e t h e y p r e s e n t e d to a s t a t e d a c c u r a c y . CO O R D I N A T E S Y S T E M : NA D 1 9 8 3 N O R T H C A R O L I N A S T A T E P L A N E F I P S 3 2 0 0 , U S S U R V E Y F E E T 07/15/2021 SE E L O W E R L E F T OL D R I C H M O N D C O U N T Y L F RO C K I N G H A M , R I C H M O N D C O U N T Y , N O R T H C A R O L I N A PR L U 0 5 9 4 C AS SHOWN DH SL 6 PO P P Y S E E D D R I V E HA-2 HA-1 HA-7 GIS LINE ONLY - SHOWN APPROXIMATE 410 410 410 400 400 390 390 380 390 380 390 390 390 412 41 4 41 6 408 406 404 402 398 396 394 392 388 386 384 382 408 406 404 402 400 394 398402 39 6 394 392 392 394 396 38 8 378 382 384 38638 2 38 4 388 39 2 384 384 384 386 38 8 402 396 398 398 386 WASTE DISPOSAL AREA A WASTE DISPOSAL AREA B SC-1 SC-2 SC-3 SC-4 SC-5 SC-6 SC-7 SC-8 SC-9 SC-10 SC-11 SC-12 SC-13 SC-14 SC-15 SC-16 SC-17 SC-18 SC-19 SC-20 SC-21 SC-22 SC-23 SC-24 SC-25 1.25 1.25 1.0 1.0 1.5 1.75 >3.0 2.5 >3.0 1.0 >3.0 2.5 >3.0 1.75 1.0 1.0 2.5 1.25 2.5 >3.0 1.0 1.25 >3.0 >3.0 >3.0 1.5 2.5 2.0 SCALE: 1" = 100' 100 0 25 1005075 N NOTE: ALL LOCATIONS ARE APPROXIMATE TOPOGRAPHIC CONTOUR LEGEND: RICHMOND COUNTY PARCELS SITE PROPERTY LINE 410 HA-1 HAND AUGER Boring Identification SOIL COVER POINTSSC-22 Well Identification Soil Cover Thickness >3.0 WETLAND/STREAM BOUNDARY STRUCTURES ROADS Figure: Dra w i n g F i l e : Pr o j e c t N u m b e r : Ck d . B y : Dr n . B y : Ap p ' d B y : Ck d . D a t e : Scale: Date: H: \ 2 0 2 0 \ O T H E R O F F I C E S \ N O R T H C A R O L I N A \ N C D E N R P R E - R E G U L A T O R Y L A N D F I L L \ O L D R I C H M O N D C O . L A N D F I L L \ P R L U 0 5 9 4 C - S O I L C O V E R E X . D W G , FI G 3 EV A L U A T I O N O F W D A E X I S T I N G S O I L C O V E R FO R U S E A S T H E P E R M A N E N T C O V E R S Y S T E M 07/01/2021 SE E L O W E R L E F T OL D R I C H M O N D C O U N T Y L F RO C K I N G H A M , R I C H M O N D C O U N T Y , N O R T H C A R O L I N A PR L U 0 5 9 4 C AS SHOWN DH SL 7 NO T E S : 1. Fe a t u r e s s h o w n a r e n o t a n a u t h o r i t a t i v e l o c a t i o n , n o r a r e t h e y p r e s e n t e d to a s t a t e d a c c u r a c y . 2. Fig u r e u p d a t e d o n ( 0 8 / 2 7 / 2 0 2 0 ) i n a c c o r d a n c e t o r e q u e s t f r o m T a s k Or d e r 5 9 4 D P - 8 , S u b t a s k F . CO O R D I N A T E S Y S T E M : NA D 1 9 8 3 N O R T H C A R O L I N A S T A T E P L A N E F I P S 3 2 0 0 , U S S U R V E Y F E E T PO P P Y S E E D D R I V E SW/ SED-2 SW/ SED-1 HO U S E TR A I L E R GIS LINE ONLY - SHOWN APPROXIMATE 410 410 410 400 400 390 390 380 390 380 390 390 390 412 41 4 41 6 408 406 404 402 398 396 394 392 388 386 384 382 408 406 404 402 400 394 398402 39 6 394 392 392 394 396 38 8 378 382 384 38638 2 38 4 388 392 384 384 384 386 38 8 402 396 398 398 386 360 360 37 0 370 370 380 380 380 380 380 39 0 39 0400410420 362 362 364 364 366 366 366 366 36 8 368 368 37 2 372 372 37 4 374 374 37 6 376 376 378 378 37 8 37 8 378 38 2 382 38 4 384386 38 6 38 8 38 8 39 2 39 2394 39 4 396 39 6 398402404406408412 41 4 414416 416 418 418 SPRING SCALE: 1" = 100' 100 0 25 1005075 N NOTE: ALL LOCATIONS ARE APPROXIMATE TOPOGRAPHIC CONTOUR LEGEND: RICHMOND COUNTY PARCELS SITE PROPERTY LINE 410 WETLAND/STREAM BOUNDARY SW/SED-2 SURFACE WATER / SEDIMENT SAMPLE Sample Identification STRUCTURES ROADS WASTE DISPOSAL AREA B WASTE DISPOSAL AREA A Figure: Dra w i n g F i l e : Pr o j e c t N u m b e r : Ck d . B y : Dr n . B y : Ap p ' d B y : Ck d . D a t e : Scale: Date: H: \ 2 0 2 0 \ O T H E R O F F I C E S \ N O R T H C A R O L I N A \ N C D E N R P R E - R E G U L A T O R Y L A N D F I L L \ O L D R I C H M O N D C O . L A N D F I L L \ P R L U 0 5 9 4 C - S E D D P - 1 . D W G , FI G 7 SU R F A C E W A T E R / S E D I M E N T I N V E S T I G A T I O N EX C E E D A N C E M A P NO T E S : 1. Fe a t u r e s s h o w n a r e n o t a n a u t h o r i t a t i v e l o c a t i o n , n o r a r e t h e y p r e s e n t e d to a s t a t e d a c c u r a c y . 2. We t l a n d s w e r e p r o v i d e d b y t h e N a t i o n a l W e t l a n d s I n v e n t o r y . 3. De t e c t e d c o n c e n t r a t i o n s b e l o w b a c k g r o u n d . CO O R D I N A T E S Y S T E M : NA D 1 9 8 3 N O R T H C A R O L I N A S T A T E P L A N E F I P S 3 2 0 0 , U S S U R V E Y F E E T 07/08/2021 SE E L O W E R L E F T OL D R I C H M O N D C O U N T Y L F RO C K I N G H A M , R I C H M O N D C O U N T Y , N O R T H C A R O L I N A PR L U 0 5 9 4 C AS SHOWN DH SL 8 PO P P Y S E E D D R I V E HO U S E TR A I L E R GIS LINE ONLY - SHOWN APPROXIMATE 410 410 410 400 400 390 390 380 390 380 390 390 390 412 41 4 41 6 408 406 404 402 398 396 394 392 388 386 384 382 408 406 404 402 400 394 398402 39 6 394 392 392 394 396 38 8 378 382 384 38638 2 38 4 388 39 2 384 384 384 386 38 8 402 396 398 398 386 TMW-4 TMW-3 TMW-2 TMW-1 TMW-7 TMW-6 TMW-5 382.91 384.12 381.21 368.88 367.10 374.76 378.80 38 4 38 2 38 0 378 376 374 372 370 368 360 360 37 0 370 370 380 380 380 380 380 39 0 39 0400410420 362 362 364 364 366 366 366 366 36 8 368 368 37 2 372 372 37 4 374 374 37 6 376 376 378 378 37 8 37 8 378 38 2 382 38 4 384386 38 6 38 8 38 8 39 2 39 2394 39 4 396 39 6 398402404406408412 41 4 414416 416 418 418 NOTE: ALL LOCATIONS ARE APPROXIMATE TOPOGRAPHIC CONTOUR LEGEND: RICHMOND COUNTY PARCELS SITE PROPERTY LINE 410 370 GROUNDWATER ELEVATION CONTOUR (DASHED WHERE INFERRED) GROUNDWATER FLOW DIRECTION TMW-2 367.10 MONITORING WELL Well Identification Relative Groundwater Elevation (ft) WETLAND/STREAM BOUNDARY STRUCTURES ROADS SCALE: 1" = 100' 100 0 25 1005075 N WASTE DISPOSAL AREA B WASTE DISPOSAL AREA A Figure: Dra w i n g F i l e : Pr o j e c t N u m b e r : Ck d . B y : Dr n . B y : Ap p ' d B y : Ck d . D a t e : Scale: Date: H: \ 2 0 2 0 \ O T H E R O F F I C E S \ N O R T H C A R O L I N A \ N C D E N R P R E - R E G U L A T O R Y L A N D F I L L \ O L D R I C H M O N D C O . L A N D F I L L \ P R L U 0 5 9 4 C - P O T . D W G , FI G 8 GR O U N D W A T E R I N V E S T I G A T I O N PO T E N T I O N M E T R I C C O N T O U R M A P NO T E S : 1. Fe a t u r e s s h o w n a r e n o t a n a u t h o r i t a t i v e l o c a t i o n , n o r a r e t h e y p r e s e n t e d to a s t a t e d a c c u r a c y . 2. Gr o u n d w a t e r e l e v a t i o n s m e a s u r e d 5 / 1 3 / 2 0 1 9 . CO O R D I N A T E S Y S T E M : NA D 1 9 8 3 N O R T H C A R O L I N A S T A T E P L A N E F I P S 3 2 0 0 , U S S U R V E Y F E E T 07/08/2021 SE E L O W E R L E F T OL D R I C H M O N D C O U N T Y L F RO C K I N G H A M , R I C H M O N D C O U N T Y , N O R T H C A R O L I N A PR L U 0 5 9 4 C AS SHOWN DH SL 9 360 360 37 0 370 370 380 380 380 380 380 39 0 39 0400410420 362 362 364 364 366 366 366 366 36 8 368 368 37 2 372 372 37 4 374 374 37 6 376 376 378 378 37 8 37 8 378 38 2 382 38 4 384386 38 6 38 8 38 8 39 2 39 2394 39 4 396 39 6 398402404406408412 41 4 414416 416 418 418 PO P P Y S E E D D R I V E HO U S E TR A I L E R GIS LINE ONLY - SHOWN APPROXIMATE 410 410 410 400 400 390 390 380 390 380 390 390 390 412 41 4 41 6 408 406 404 402 398 396 394 392 388 386 384 382 408 406 404 402 400 394 398402 39 6 394 392 392 394 396 38 8 378 382 384 38638 2 38 4 388 39 2 384 384 384 386 38 8 402 396 398 398 386 P WASTE DISPOSAL AREA B TMW-4 TMW-3 TMW-2 TMW-1 TMW-7 TMW-6 TMW-5 WASTE DISPOSAL AREA A NOTE: ALL LOCATIONS ARE APPROXIMATE TOPOGRAPHIC CONTOUR LEGEND: RICHMOND COUNTY PARCELS SITE PROPERTY LINE 410 TMW-1 MONITORING WELL Well Identification WETLAND/STREAM BOUNDARY STRUCTURES ROADS SCALE: 1" = 100' 100 0 25 1005075 N Figure: Dra w i n g F i l e : Pr o j e c t N u m b e r : Ck d . B y : Dr n . B y : Ap p ' d B y : Ck d . D a t e : Scale: Date: H: \ 2 0 2 0 \ O T H E R O F F I C E S \ N O R T H C A R O L I N A \ N C D E N R P R E - R E G U L A T O R Y L A N D F I L L \ O L D R I C H M O N D C O . L A N D F I L L \ P R L U 0 5 9 4 C - C O C G W . D W G , FIG 9 GR O U N D W A T E R I N V E S T I V A T I O N NO T E S : 1. Fe a t u r e s s h o w n a r e n o t a n a u t h o r i t a t i v e l o c a t i o n , n o r a r e t h e y p r e s e n t e d to a s t a t e d a c c u r a c y . CO O R D I N A T E S Y S T E M : NA D 1 9 8 3 N O R T H C A R O L I N A S T A T E P L A N E F I P S 3 2 0 0 , U S S U R V E Y F E E T 07/08/2021 SE E L O W E R L E F T OL D R I C H M O N D C O U N T Y L F RO C K I N G H A M , R I C H M O N D C O U N T Y , N O R T H C A R O L I N A PR L U 0 5 9 4 C AS SHOWN DH SL 10 320 32 0 33 0 330 340 340 340 34 0 340 340 340 340 340 340 340 350 350 350 350 35 0 350 350 350 36 0 360 360 360 360 360360 36 0 360 360 360 360 360 37 0 370 370 370 370 370 370 370 38 0 380 380 380 380 380 380 38 0 380 380 380 38 0 380 380 390 390 390 390 390 39 0 390 390 390 39 0 390 390 39 0 400 400 40 0 400 40 0 400 400 40 0 400 400 400 40 0 400 400 40 0 410 41 0 41 0 41 0 410 410 410 410 41 0 42 0 420 420 42 0 420 420 420 420 42042 0 42 0 43043 0 430 440440 440LEGEND: RICHMOND COUNTY PARCELS NOTE: ALL LOCATIONS ARE APPROXIMATE TOPOGRAPHIC CONTOUR WASTE DISPOSAL AREA Well Identification WSW-5 FIRE HYDRANT WSW-4 WSW-3 WSW-6 WSW-5 WSW-1 WSW-2 WSW-7 430 WASTE DISPOSAL AREA A (4.683 ACRES) WASTE DISPOSAL AREA B (0.210 ACRES) 1,000 FT. OFFSET NOT SAMPLED WATER SUPPLY WELL Well Identification WSW-4 SAMPLED WATER SUPPLY WELL Figure: Dra w i n g F i l e : Pr o j e c t N u m b e r : Ck d . B y : Dr n . B y : Ap p ' d B y : Ck d . D a t e : Scale: Date: H: \ 2 0 2 0 \ O T H E R O F F I C E S \ N O R T H C A R O L I N A \ N C D E N R P R E - R E G U L A T O R Y L A N D F I L L \ O L D R I C H M O N D C O . L A N D F I L L \ P R L U 0 5 9 4 B - W S W . D W G , FI G 1 PO T A B L E W A T E R S U P P L Y W E L L M A P 08/24/2020 SE E L O W E R L E F T OL D R I C H M O N D C O U N T Y L A N D F I L L RO C K I N G H A M , R I C H M O N D C O U N T Y , N O R T H C A R O L I N A PR L U 0 5 9 4 B AS SHOWN DH SL 11 NO T E S : 1. Fe a t u r e s s h o w n a r e n o t a n a u t h o r i t a t i v e l o c a t i o n , n o r a r e t h e y p r e s e n t e d to a s t a t e d a c c u r a c y . 2. BO L D v a l u e s i n d i c a t e e x c e e d a n c e s t o t h e 1 5 N C A C Ø2 L G r o u n d w a t e r Sta n d a r d s . CO O R D I N A T E S Y S T E M : NA D 1 9 8 3 N O R T H C A R O L I N A S T A T E P L A N E F I P S 3 2 0 0 , U S S U R V E Y F E E T PO P P Y S E E D D R I V E GP-3 GP-2 GP-11 GP-4 GP-8 GP-7 GP-6 GP-5 GP-10 GP-9 X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X HO U S E TR A I L E R GIS LINE ONLY - SHOWN APPROXIMATE 410 410 410 400 400 390 390 380 390 380 390 390 390 412 41 4 41 6 408 406 404 402 398 396 394 392 388 386 384 382 408 406 404 402 400 394 398402 39 6 394 392 392 394 396 38 8 378 382 384 38638 2 38 4 388 39 2 384 384 384 386 38 8 402 396 398 398 386 GP-15 GP-18 GP-17 GP-12 GP-13 GP-14 X X X XXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXX X X X X X X XXXXXXXXXXXXXXXXXXXXXXX GP-16 GP-1 360 360 37 0 370 370 380 380 380 380 380 39 0 39 0400410420 362 362 364 364 366 366 366 366 36 8 368 368 37 2 372 372 37 4 374 374 37 6 376 376 378 378 37 8 37 8 378 38 2 382 38 4 384386 38 6 38 8 38 8 39 2 39 2394 39 4 396 39 6 398402404406408412 41 4 414416 416 418 418 NOTE: ALL LOCATIONS ARE APPROXIMATE TOPOGRAPHIC CONTOUR LEGEND: RICHMOND COUNTY PARCELS SITE PROPERTY LINE 410 LANDFILL GAS MONITORING POINTGP-1 Point Identification WETLAND/STREAM BOUNDARY SCALE: 1" = 100' 100 0 25 1005075 N STRUCTURES ROADS DISPOSAL WASTE AREA A DISPOSAL WASTE AREA B Figure: Dra w i n g F i l e : Pr o j e c t N u m b e r : Ck d . B y : Dr n . B y : Ap p ' d B y : Ck d . D a t e : Scale: Date: H: \ 2 0 2 0 \ O T H E R O F F I C E S \ N O R T H C A R O L I N A \ N C D E N R P R E - R E G U L A T O R Y L A N D F I L L \ O L D R I C H M O N D C O . L A N D F I L L \ P R L U 0 5 9 4 C - G P . D W G , FI G 1 1 LA N D F I L L G A S P R O B E R E S U L T S 07/14/2021 SE E L O W E R L E F T OL D R I C H M O N D C O U N T Y L F RO C K I N G H A M , R I C H M O N D C O U N T Y , N O R T H C A R O L I N A PR L U 0 5 9 4 C AS SHOWN DH SL 12 NO T E S : 1. Fe a t u r e s s h o w n a r e n o t a n a u t h o r i t a t i v e l o c a t i o n , n o r a r e t h e y p r e s e n t e d to a s t a t e d a c c u r a c y . 2. Re a d i n g c o l l e c t e d 7 / 2 9 / 2 0 2 0 . CO O R D I N A T E S Y S T E M : NA D 1 9 8 3 N O R T H C A R O L I N A S T A T E P L A N E F I P S 3 2 0 0 , U S S U R V E Y F E E T APPENDIX A Risk Calculator TABLE 1 SOIL EXPOSURE POINT CONCENTRATIONS Old Richmond County LF NONCD0000594 Rockingham, Richmond County, North Carolina PARAMETER SAMPLE DATE Antimony 0.283 J BDL BDL 0.354 J 0.222 J BDL BDL 0.482 J BDL BDL 0.363 J BDL BDL Arsenic 1.26 1.41 1.19 1.12 1.68 0.995 0.595 2.45 1.24 1.71 1.15 0.917 1.17 Beryllium 0.408 J 0.0982 J 0.126 J 0.141 J 0.691 0.0733 J 0.0628 J 0.637 0.214 J 0.133 J 0.110 J 0.0970 J 0.116 J Cadmium 0.422 J BDL BDL 0.171 J 0.629 BDL BDL 0.630 0.160 J BDL BDL BDL BDL Chromium 3.99 5.57 4.80 3.98 5.32 4.23 2.89 9.06 5.32 6.44 5.11 3.56 7.04 Hexavalent Chromium NA NA NA NA NA NA NA NA NA NA NA NA NA Copper 2.46 2.80 2.35 3.38 3.10 3.01 1.61 7.84 2.29 3.56 2.52 2.72 3.06 Iron 2,340 3,540 3,100 3,060 3,160 2,930 1,710 5,850 3,680 4,510 3,780 2,350 3,720 Lead 3.80 3.94 3.94 3.69 4.02 2.96 2.39 27.5 3.38 4.25 3.22 2.08 22.0 Manganese 11.1 8.83 11.0 39.1 15.1 9.51 9.31 15.8 8.93 19.7 11.7 7.88 13.7 Mercury 0.0217 B 0.0206 B J 0.0218 B 0.0275 B J 0.0203 B J 0.0311 B 0.0174 B J 0.0263 B 0.0289 B 0.0201 B J 0.0198 B J 0.0118 B J 0.0209 B J Nickel 2.44 2.01 2.50 2.72 3.48 3.63 2.03 4.83 2.94 2.33 2.58 1.50 2.81 Selenium 0.450 J 0.319 J 0.245 J BDL 0.793 BDL BDL 0.518 J 0.333 J 0.303 J 0.216 J BDL 0.279 J Silver 0.238 J BDL BDL BDL 0.323 J BDL BDL 0.354 J BDL BDL BDL BDL BDL Thallium 0.480 J BDL BDL BDL 0.658 BDL BDL 0.677 0.195 J BDL BDL BDL BDL Zinc 10.9 9.96 10.4 32.7 12.9 8.80 6.46 32.5 9.13 14.8 8.02 5.46 11.5 Nitrogen, Ammonia BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Nitrogen, Nitrate BDL BDL BDL 0.0114 BDL BDL BDL BDL BDL 0.0058 BDL BDL BDL Sulfate BDL 0.0301 J 0.0284 J BDL BDL BDL 0.0828 0.0527 J BDL BDL BDL 0.0599 BDL PCB-1248 (Aroclor 1248)BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL PCB-1254 (Aroclor 1254)BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0721 BDL BDL BDL 2-Butanone (MEK)BDL BDL BDL 0.0072 J BDL BDL BDL BDL BDL BDL BDL BDL BDL Acetone BDL BDL BDL 0.201 0.0383 J 0.0110 J BDL 0.0118 J BDL BDL BDL BDL BDL Methyl acetate BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Methylene Chloride 0.0042 J 0.0041 J 0.0036 J 0.0057 J 0.0043 J 0.0040 J BDL 0.0045 J 0.0041 J BDL BDL BDL BDL Method 6020B / Method 7471B / Method 7199 EPA 350.1 / EPA 353.2 / EPA 9056 EPA 8082A EPA 8260D DUP-3 (SC-1 (0.5)) 5/20/2019 5/20/20195/20/2019 5/20/2019 5/20/2019 5/20/2019 5/20/2019 5/20/2019 SC-2 (1.5)SC-3 (0.5)SC-3 (1.5)SC-4 (0.5)SC-5 (0.5)SC-6 (0.5)SC-1 (0.5)SC-1 (1.5)SC-2 (0.5) 5/20/2019 5/20/2019 5/20/2019 5/20/2019 SC-6 (1.5)SC-7 (0.5)SC-7 (1.5) 5/20/2019 Page 1 of 9 TABLE 1 SOIL EXPOSURE POINT CONCENTRATIONS Old Richmond County LF NONCD0000594 Rockingham, Richmond County, North Carolina PARAMETER SAMPLE DATE Antimony BDL BDL 0.178 J BDL 0.225 J BDL BDL BDL BDL BDL BDL 0.231 J BDL BDL BDL Arsenic 3.27 1.44 1.72 1.20 1.31 2.21 2.48 3.84 1.51 2.91 3.49 2.75 2.10 0.772 0.829 Beryllium 0.164 J BDL 0.0745 J BDL BDL 0.0770 J 0.106 J 0.106 J BDL 0.0910 J 0.355 J 0.516 J 0.0764 J 0.112 J 0.0838 J Cadmium BDL 0.515 J 1.69 BDL BDL BDL BDL BDL BDL BDL 0.338 J 0.502 J BDL BDL BDL Chromium 10.5 6.56 20.1 4.41 5.80 7.57 9.87 15.6 6.32 12.4 13.9 9.16 6.24 3.99 3.57 Hexavalent Chromium 0.547 J T8 NA NA NA NA NA NA BDL T8 NA BDL T8 BDL T8 NA NA NA NA Copper 3.61 2.91 5.23 2.54 2.31 5.55 5.15 5.79 1.94 4.64 5.28 3.71 3.17 1.60 2.01 Iron 7,120 3,260 4,950 2,980 3,660 4,190 6,530 9,530 3,750 7,480 8,290 5,040 4,380 2,350 2,120 Lead 2.36 19.7 68.5 6.21 2.70 3.87 3.33 3.91 2.45 3.83 4.08 4.54 2.57 2.21 2.74 Manganese 5.69 6.79 16.8 6.24 4.73 7.63 7.48 8.54 5.36 8.61 9.05 5.34 7.21 5.86 30.1 Mercury 0.0174 B J 0.144 0.304 0.0335 B 0.0119 B J 0.0484 0.0254 B 0.0267 B 0.0168 B J 0.0272 B 0.0458 0.0233 B 0.0142 B J 0.0427 0.0135 B J Nickel 2.08 1.60 2.53 1.41 1.49 2.31 2.62 3.14 2.22 2.66 3.29 2.76 1.27 1.88 1.66 Selenium 0.358 J 0.252 J 0.218 J 0.333 J BDL 0.259 J 0.275 J 0.560 BDL 0.328 J 0.504 J 0.868 0.409 J BDL 0.226 J Silver BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.182 J 0.303 J BDL BDL BDL Thallium BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.396 J 0.508 J BDL BDL BDL Zinc 5.42 23.0 67.2 5.70 4.04 J 11.4 8.50 13.8 5.65 8.25 8.29 7.74 5.77 6.57 15.5 Nitrogen, Ammonia BDL BDL BDL BDL BDL 0.0440 BDL BDL BDL BDL BDL BDL BDL BDL BDL Nitrogen, Nitrate BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Sulfate 0.0347 J BDL BDL BDL BDL 0.0612 0.0336 J 0.0673 0.0443 J 0.0483 J 0.0388 J BDL BDL BDL BDL PCB-1248 (Aroclor 1248)BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0293 J BDL BDL BDL BDL PCB-1254 (Aroclor 1254)BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 2-Butanone (MEK)BDL BDL BDL BDL BDL 0.0657 J BDL BDL BDL BDL BDL BDL BDL BDL BDL Acetone BDL 0.0123 J 0.0115 J BDL BDL 0.249 BDL BDL BDL 0.0123 J BDL BDL 0.0183 J 0.0377 J BDL Methyl acetate BDL BDL BDL BDL BDL 0.0084 J BDL BDL BDL BDL BDL BDL BDL BDL BDL Methylene Chloride 0.0043 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 5/21/2019 5/21/2019 5/21/2019 5/21/2019 SC-8 (0.5)SC-9 (0.5) Method 6020B / Method 7471B / Method 7199 EPA 350.1 / EPA 353.2 / EPA 9056 EPA 8082A EPA 8260D DUP-4 (SC-9 (0.5)) 5/21/2019 5/21/2019 5/21/2019 5/21/2019 5/21/20195/21/2019 5/21/20195/20/2019 5/21/2019 5/21/2019 5/21/2019 SC-13 (1.5)SC-14 (0.5)SC-15 (0.5)SC-16 (0.5)SC-17 (0.5)SC-10 (1.5)SC-11 (0.5)SC-11 (1.5)SC-12 (0.5)SC-12 (1.5)SC-13 (0.5)SC-10 (0.5) Page 2 of 9 TABLE 1 SOIL EXPOSURE POINT CONCENTRATIONS Old Richmond County LF NONCD0000594 Rockingham, Richmond County, North Carolina PARAMETER SAMPLE DATE Antimony BDL BDL BDL 0.105 BDL BDL 0.274 J BDL BDL BDL BDL NR NR NR 0.482 Arsenic 1.47 1.06 1.36 1.37 1.29 0.901 1.17 0.558 J 1.20 1.09 1.62 1.15 1.61 1.79 3.84 Beryllium 0.158 J 0.120 J 0.108 J 0.137 0.140 J 0.0846 J 0.0711 J BDL 0.0705 J BDL BDL 0.128 J BDL 0.148 J 0.691 Cadmium BDL BDL BDL 0.0382 BDL BDL BDL BDL BDL BDL BDL NR NR NR 1.69 Chromium 6.81 4.74 5.76 4.53 4.06 3.05 3.60 1.91 3.72 2.97 4.87 5.55 4.62 5.03 20.1 Hexavalent Chromium NA NA NA NA NA NA NA NA NA NA NA BDL NA BDL 0.547 Copper 2.87 2.45 2.84 2.27 2.46 1.53 1.95 0.866 J 2.35 1.58 2.51 3.15 3.51 2.94 7.84 Iron 5,330 3,700 4,740 4,040 3,670 2,630 2,830 1,420 3,630 2,740 3,470 2,810 3,270 5,720 9,350 Lead 4.20 7.87 4.31 3.22 3.44 2.04 2.15 0.722 2.17 4.40 1.71 9.30 8.70 6.30 68.5 Manganese 18.2 20.5 26.1 18.7 17.1 10.0 7.01 4.18 10.4 13.0 2.97 21.6 29.6 34.6 39.1 Mercury 0.0353 B 0.0253 B 0.0225 B 0.0227 0.0188 J 0.0148 J 0.0162 J 0.00617 J 0.0274 0.0204 J 0.530 0.0415 0.0472 0.0669 0.53 Nickel 3.46 2.36 3.36 1.68 1.56 1.16 1.12 0.525 J 1.35 1.11 0.687 1.65 1.44 1.88 4.83 Selenium 0.256 J 0.250 J 0.365 J 0.272 0.251 J BDL BDL BDL BDL 0.233 J BDL 0.844 J 0.384 J 1.10 1.1 Silver BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.354 Thallium BDL BDL BDL 0.0907 BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.677 Zinc 10.7 14.8 14.0 5.34 7.20 3.70 J 4.56 J 1.80 J 10.6 7.79 6.31 8.45 J 5.02 J 5.27 J 67.2 Nitrogen, Ammonia BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.044 Nitrogen, Nitrate BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.0114 Sulfate BDL BDL BDL BDL BDL BDL BDL BDL 0.0691 0.0698 0.0939 0.0446 J 0.0476 J 0.220 0.22 PCB-1248 (Aroclor 1248)BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.0293 PCB-1254 (Aroclor 1254)BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.0721 2-Butanone (MEK)BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0076 J 0.0086 J BDL 0.0657 Acetone 0.0340 J 0.0745 J 0.0415 J 0.0375 J 0.0667 J BDL 0.0309 J BDL 0.0855 J 0.0540 J 0.0701 J 0.0855 J 0.0450 J BDL 0.249 Methyl acetate BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0078 J NR NR NR 0.0084 Methylene Chloride BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0266 0.0150 J 0.399 J 0.399 4/4/2019 4/4/2019 4/4/2019 Exposure Point Concentration SC-23 (1.5)SC-24 (0.5)SC-24 (1.5)SC-25 (0.5)SC-23 (0.5) Method 6020B / Method 7471B / Method 7199 EPA 350.1 / EPA 353.2 / EPA 9056 EPA 8082A EPA 8260D SED-1 SED-DUP (SED-1 SUP)SED-2 5/21/2019 5/21/2019 5/21/20195/21/2019 5/21/2019 5/21/2019 5/21/2019 5/21/2019 5/21/20195/21/2019 5/21/2019 SC-22 (0.5)SC-22 (1.5)SC-18 (0.5)SC-19 (0.5)SC-20 (0.5)SC-21 (0.5) Page 3 of 9 TABLE 1 SOIL EXPOSURE POINT CONCENTRATIONS Old Richmond County LF NONCD0000594 Rockingham, Richmond County, North Carolina PARAMETER SAMPLE DATE Method 6020B / Method 7471B / Method 7199 DUP-3 (SC-1 (0.5)) 5/20/2019 5/20/20195/20/2019 5/20/2019 5/20/2019 5/20/2019 5/20/2019 5/20/2019 SC-2 (1.5)SC-3 (0.5)SC-3 (1.5)SC-4 (0.5)SC-5 (0.5)SC-6 (0.5)SC-1 (0.5)SC-1 (1.5)SC-2 (0.5) 5/20/2019 5/20/2019 5/20/2019 5/20/2019 SC-6 (1.5)SC-7 (0.5)SC-7 (1.5) 5/20/2019 .alpha.-Pinene BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.234 J BDL BDL BDL 11H-Dibenzo[b,e][1,4]dia BDL BDL 0.0057 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1-Octen-3-ol BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1R-.alpha.-Pinene BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 2-Furanmethanol, 5-ethen NR NR NR NR NR NR NR NR NR NR NR NR NR 2,5-Dimethoxy-4-(methylsu BDL 0.0282 J BDL BDL 0.0230 J BDL BDL BDL BDL BDL BDL BDL BDL 2-Pentene BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 2-Pentene, (E)-BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 2-Pentene, (Z)-BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 3-Hydroxymandelic acid, BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 4,4,8-Trimethyltricyclo NR NR NR NR NR NR NR NR NR NR NR NR NR 4-Hydroxymandelic acid, BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 4-Iodo-3-methoxyamphetami BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Benzaldehyde, 2,4-bis(tr 0.0087 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Benzeneethanamine, N-[(p BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Benzoic acid, 2-[(trimet BDL BDL BDL BDL 0.0074 J BDL BDL BDL BDL BDL BDL BDL BDL Butanal, 3-methyl-BDL BDL BDL 0.0143 J BDL BDL BDL BDL BDL BDL BDL BDL BDL Butane BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Butane, 2-methyl-BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Cyclopropane, 1,2-dimeth BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Cyclotrisiloxane, hexame BDL 0.0084 J 0.011 J 0.0142 J 0.0140 J BDL BDL 0.0065 J BDL BDL BDL BDL BDL Dodecanoic acid, 11-amino BDL BDL BDL 0.0621 J BDL BDL BDL BDL BDL BDL BDL BDL BDL Fluoxetine BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Isobutane BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Pentane BDL BDL BDL 0.0064 J BDL BDL BDL BDL BDL BDL BDL BDL BDL p-Trimethylsilyloxypheny BDL 0.0054 J BDL 0.0072 J BDL BDL BDL BDL BDL BDL BDL BDL BDL Silane, 1,4-phenylenebis 0.0175 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL .beta.-Sitosterol BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL .gamma.-Sitosterol BDL BDL BDL 30.200 J BDL BDL BDL BDL BDL BDL BDL BDL BDL 1,2:4,5-Dibenzopyrene 1.260 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 14-Pentadecenoic acid BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1-Heneicosyl formate BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1-Heptadecene BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1-Phenanthrenecarboxyli BDL BDL BDL 8.29 J BDL BDL BDL BDL BDL BDL BDL BDL BDL 3-Eicosene, (E)-BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 4-Tetradecanol BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 9-Octadecenamide, (Z)-BDL BDL BDL BDL BDL 0.242 J BDL 0.205 J 0.225 J BDL BDL BDL BDL a'-Neogammacer-22(29)-e BDL BDL BDL 11.200 J BDL BDL BDL BDL BDL BDL BDL BDL BDL Cyclohexane, 1-(1,5-dim BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Cyclononasiloxane, octa BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Cyclotetracosane BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Cyclotetradecane BDL BDL BDL 0.594 J BDL BDL BDL BDL BDL BDL BDL BDL BDL Friedelan-3-one BDL BDL BDL BDL 1.250 J BDL BDL BDL BDL BDL BDL BDL BDL EPA 8260D TICs Page 4 of 9 TABLE 1 SOIL EXPOSURE POINT CONCENTRATIONS Old Richmond County LF NONCD0000594 Rockingham, Richmond County, North Carolina PARAMETER SAMPLE DATE 5/21/2019 5/21/2019 5/21/2019 5/21/2019 SC-8 (0.5)SC-9 (0.5) Method 6020B / Method 7471B / Method 7199 DUP-4 (SC-9 (0.5)) 5/21/2019 5/21/2019 5/21/2019 5/21/2019 5/21/20195/21/2019 5/21/20195/20/2019 5/21/2019 5/21/2019 5/21/2019 SC-13 (1.5)SC-14 (0.5)SC-15 (0.5)SC-16 (0.5)SC-17 (0.5)SC-10 (1.5)SC-11 (0.5)SC-11 (1.5)SC-12 (0.5)SC-12 (1.5)SC-13 (0.5)SC-10 (0.5) .alpha.-Pinene BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 11H-Dibenzo[b,e][1,4]dia BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1-Octen-3-ol BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1R-.alpha.-Pinene BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0259 J BDL BDL BDL BDL BDL 2-Furanmethanol, 5-ethen NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR 2,5-Dimethoxy-4-(methylsu 0.0298 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 2-Pentene BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 2-Pentene, (E)-BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 2-Pentene, (Z)-BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 3-Hydroxymandelic acid, BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0064 J BDL 4,4,8-Trimethyltricyclo NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR 4-Hydroxymandelic acid, BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 4-Iodo-3-methoxyamphetami BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Benzaldehyde, 2,4-bis(tr BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Benzeneethanamine, N-[(p BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Benzoic acid, 2-[(trimet BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Butanal, 3-methyl-BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Butane BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Butane, 2-methyl-BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Cyclopropane, 1,2-dimeth BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Cyclotrisiloxane, hexame BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0149 J 0.0175 J Dodecanoic acid, 11-amino BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Fluoxetine BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Isobutane BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Pentane BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL p-Trimethylsilyloxypheny BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0075 J Silane, 1,4-phenylenebis BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL .beta.-Sitosterol BDL BDL BDL 1.020 J BDL 0.386 J BDL BDL BDL BDL BDL BDL BDL BDL BDL .gamma.-Sitosterol BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1,2:4,5-Dibenzopyrene BDL BDL 3.680 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 14-Pentadecenoic acid BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1-Heneicosyl formate BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1-Heptadecene BDL BDL BDL BDL 0.221 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1-Phenanthrenecarboxyli BDL BDL BDL BDL 0.767 J 0.551 J BDL BDL BDL 0.269 J BDL BDL BDL 0.200 J BDL 3-Eicosene, (E)-BDL BDL BDL 0.482 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 4-Tetradecanol BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 9-Octadecenamide, (Z)-BDL BDL BDL BDL BDL BDL BDL 0.239 J BDL BDL 0.913 J 0.187 J BDL BDL BDL a'-Neogammacer-22(29)-e BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Cyclohexane, 1-(1,5-dim BDL BDL BDL BDL BDL 0.373 J BDL BDL BDL BDL BDL BDL BDL BDL BDL Cyclononasiloxane, octa BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Cyclotetracosane BDL BDL BDL 1.10 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Cyclotetradecane BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Friedelan-3-one BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL EPA 8260D TICs Page 5 of 9 TABLE 1 SOIL EXPOSURE POINT CONCENTRATIONS Old Richmond County LF NONCD0000594 Rockingham, Richmond County, North Carolina PARAMETER SAMPLE DATE 4/4/2019 4/4/2019 4/4/2019 Exposure Point Concentration SC-23 (1.5)SC-24 (0.5)SC-24 (1.5)SC-25 (0.5)SC-23 (0.5) Method 6020B / Method 7471B / Method 7199 SED-1 SED-DUP (SED-1 SUP)SED-2 5/21/2019 5/21/2019 5/21/20195/21/2019 5/21/2019 5/21/2019 5/21/2019 5/21/2019 5/21/20195/21/2019 5/21/2019 SC-22 (0.5)SC-22 (1.5)SC-18 (0.5)SC-19 (0.5)SC-20 (0.5)SC-21 (0.5) .alpha.-Pinene BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.234 11H-Dibenzo[b,e][1,4]dia BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.0057 1-Octen-3-ol BDL BDL BDL BDL BDL BDL BDL BDL 0.0094 J BDL 0.0049 J NR NR NR 0.0094 1R-.alpha.-Pinene BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.0259 2-Furanmethanol, 5-ethen NR NR NR NR NR NR NR NR NR NR NR NR NR 0.637 J 0.637 2,5-Dimethoxy-4-(methylsu BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.0298 2-Pentene BDL BDL BDL BDL BDL BDL 0.0085 J BDL BDL BDL BDL NR NR NR 0.0085 2-Pentene, (E)-BDL BDL BDL BDL BDL BDL 0.0101 J BDL BDL BDL BDL NR NR NR 0.0101 2-Pentene, (Z)-BDL BDL BDL BDL BDL BDL BDL BDL 0.0062 J BDL BDL NR NR NR 0.0062 3-Hydroxymandelic acid, BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.0064 4,4,8-Trimethyltricyclo NR NR NR NR NR NR NR NR NR NR NR 0.270 J NR 0.882 J 0.882 4-Hydroxymandelic acid, BDL BDL BDL BDL BDL BDL 0.0057 J BDL BDL BDL BDL NR NR NR 0.0057 4-Iodo-3-methoxyamphetami BDL BDL BDL BDL BDL BDL BDL BDL 0.0293 J BDL BDL NR NR NR 0.0293 Benzaldehyde, 2,4-bis(tr BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.0087 Benzeneethanamine, N-[(p BDL 0.0067 J BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.0067 Benzoic acid, 2-[(trimet 0.0057 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.0074 Butanal, 3-methyl-BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.0143 Butane BDL BDL BDL 0.0116 J BDL 0.0081 J BDL 0.0062 J 0.0176 J BDL BDL NR NR NR 0.0176 Butane, 2-methyl-BDL BDL BDL 0.0053 J 0.0224 J 0.0334 J 0.0899 J 0.0190 J 0.0628 J 0.0120 J 0.0065 J NR NR NR 0.0899 Cyclopropane, 1,2-dimeth BDL BDL BDL BDL BDL BDL BDL BDL 0.0084 J BDL BDL NR NR NR 0.0084 Cyclotrisiloxane, hexame 0.0110 J 0.0121 J 0.0076 J BDL BDL BDL 0.0109 J 0.0065 J 0.0157 J 0.0071 J 0.0050 J NR NR NR 0.0175 Dodecanoic acid, 11-amino BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.0621 Fluoxetine BDL BDL BDL BDL BDL 0.026 J BDL BDL BDL BDL BDL NR NR NR 0.026 Isobutane BDL BDL BDL BDL BDL BDL 0.0069 J BDL BDL BDL BDL NR NR NR 0.0069 Pentane BDL BDL BDL BDL 0.0097 J 0.0136 J 0.0549 J 0.0117 J 0.0394 J 0.0073 J BDL NR NR NR 0.0549 p-Trimethylsilyloxypheny BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.0075 Silane, 1,4-phenylenebis BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.0175 .beta.-Sitosterol BDL 0.417 J BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 1.02 .gamma.-Sitosterol BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.268 J NR NR NR 30.2 1,2:4,5-Dibenzopyrene BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 3.68 14-Pentadecenoic acid BDL 0.298 J BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.298 1-Heneicosyl formate BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.189 J BDL NR NR NR 0.189 1-Heptadecene BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.221 1-Phenanthrenecarboxyli BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 8.29 3-Eicosene, (E)-BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.482 4-Tetradecanol BDL 0.190 J BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.19 9-Octadecenamide, (Z)-BDL 0.306 J BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.913 a'-Neogammacer-22(29)-e BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 11.2 Cyclohexane, 1-(1,5-dim BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.373 Cyclononasiloxane, octa BDL BDL BDL BDL BDL BDL BDL BDL 0.202 J BDL BDL NR NR NR 0.202 Cyclotetracosane BDL 0.173 J BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 1.1 Cyclotetradecane BDL 0.321 J BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.594 Friedelan-3-one BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 1.25 EPA 8260D TICs Page 6 of 9 TABLE 1 SOIL EXPOSURE POINT CONCENTRATIONS Old Richmond County LF NONCD0000594 Rockingham, Richmond County, North Carolina PARAMETER SAMPLE DATE Method 6020B / Method 7471B / Method 7199 DUP-3 (SC-1 (0.5)) 5/20/2019 5/20/20195/20/2019 5/20/2019 5/20/2019 5/20/2019 5/20/2019 5/20/2019 SC-2 (1.5)SC-3 (0.5)SC-3 (1.5)SC-4 (0.5)SC-5 (0.5)SC-6 (0.5)SC-1 (0.5)SC-1 (1.5)SC-2 (0.5) 5/20/2019 5/20/2019 5/20/2019 5/20/2019 SC-6 (1.5)SC-7 (0.5)SC-7 (1.5) 5/20/2019 Hexadecanoic acid BDL 0.258 J BDL BDL 0.258 J BDL BDL BDL BDL BDL BDL BDL BDL Hexadecanol BDL BDL BDL 0.304 J BDL BDL BDL BDL BDL BDL BDL BDL BDL Hop-22(29)-en-3.beta.-o BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Isoheptadecanol BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Longipinane, (E)-BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL n-Hexadecanoic acid 0.354 J BDL 0.238 J 0.891 J BDL BDL BDL BDL BDL 0.255 J 0.323 J 0.184 J 0.370 J Octadecanoic acid BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.298 J Oleic Acid BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Stigmast-4-en-3-one BDL BDL BDL 4.740 J BDL BDL BDL BDL BDL BDL BDL BDL BDL Stigmasterol, 22,23-dih BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Tetradecanoic acid BDL BDL BDL BDL BDL 0.243 J BDL BDL BDL BDL BDL BDL BDL Tridecanoic acid BDL BDL BDL BDL BDL BDL 0.180 J BDL 0.260 J BDL BDL BDL BDL 8.) Exposure Point Concentration is the maximum concentration for each detected compound 12.) Total chromium is to only be entered as Cr III in the risk calculator if the total is within natural background levels. The NURE database indicates background levels ranging from 5-168 mg/kg and the highest concentration is 20.1 mg/kg. 13.) The DUP-4 sample indicated the highest chromium concentration. Because it is a duplicate, it was not analyzed for hexavalent chromium. ATC recognizes this as a data gap. 9.) NR = Not analyzed or not detected 10.) =Maximum concentration detected 1.) PSRG = North Carolina Department of Environmental Quality Preliminary Soil Remediation (Feb. 2018). 2.) Bold = Indicates concentrations above the corresponding PSRG. 3.) Values reported in mg/kg (milligrams per kilogram). 5.) J = The identification of the analyte is acceptable; the reported value is an estimate. 6.) B = The same analyte is found in the associated blank. 7.) BDL = Below Detection Limit EPA 8260D TICs (continued) 11.) =Compound not listed in risk calculator Page 7 of 9 TABLE 1 SOIL EXPOSURE POINT CONCENTRATIONS Old Richmond County LF NONCD0000594 Rockingham, Richmond County, North Carolina PARAMETER SAMPLE DATE 5/21/2019 5/21/2019 5/21/2019 5/21/2019 SC-8 (0.5)SC-9 (0.5) Method 6020B / Method 7471B / Method 7199 DUP-4 (SC-9 (0.5)) 5/21/2019 5/21/2019 5/21/2019 5/21/2019 5/21/20195/21/2019 5/21/20195/20/2019 5/21/2019 5/21/2019 5/21/2019 SC-13 (1.5)SC-14 (0.5)SC-15 (0.5)SC-16 (0.5)SC-17 (0.5)SC-10 (1.5)SC-11 (0.5)SC-11 (1.5)SC-12 (0.5)SC-12 (1.5)SC-13 (0.5)SC-10 (0.5) Hexadecanoic acid BDL 2.560 J BDL BDL BDL 0.373 J BDL BDL BDL BDL BDL 0.251 J BDL BDL BDL Hexadecanol BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Hop-22(29)-en-3.beta.-o BDL BDL BDL 0.775 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Isoheptadecanol BDL BDL BDL BDL 0.207 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Longipinane, (E)-BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL n-Hexadecanoic acid BDL BDL BDL 0.405 J 0.303 J BDL 0.242 J 0.196 J BDL BDL 0.230 J BDL 0.271 J BDL 0.189 J Octadecanoic acid BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Oleic Acid BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Stigmast-4-en-3-one BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Stigmasterol, 22,23-dih BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.625 J BDL BDL BDL BDL BDL Tetradecanoic acid BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Tridecanoic acid BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 8.) Exposure Point Concentration is the maximum concentration for each detected compound 12.) Total chromium is to only be entered as Cr III in the risk calculator if the total is within natural background levels. The NURE database indicates background levels ranging from 5-168 mg/kg and the highest concentration is 20.1 mg/kg. 13.) The DUP-4 sample indicated the highest chromium concentration. Because it is a duplicate, it was not analyzed for hexavalent chromium. ATC recognizes this as a data gap. 9.) NR = Not analyzed or not detected 10.) =Maximum concentration detected 1.) PSRG = North Carolina Department of Environmental Quality Preliminary Soil Remediation (Feb. 2018). 2.) Bold = Indicates concentrations above the corresponding PSRG. 3.) Values reported in mg/kg (milligrams per kilogram). 5.) J = The identification of the analyte is acceptable; the reported value is an estimate. 6.) B = The same analyte is found in the associated blank. 7.) BDL = Below Detection Limit EPA 8260D TICs (continued) 11.) =Compound not listed in risk calculator Page 8 of 9 TABLE 1 SOIL EXPOSURE POINT CONCENTRATIONS Old Richmond County LF NONCD0000594 Rockingham, Richmond County, North Carolina PARAMETER SAMPLE DATE 4/4/2019 4/4/2019 4/4/2019 Exposure Point Concentration SC-23 (1.5)SC-24 (0.5)SC-24 (1.5)SC-25 (0.5)SC-23 (0.5) Method 6020B / Method 7471B / Method 7199 SED-1 SED-DUP (SED-1 SUP)SED-2 5/21/2019 5/21/2019 5/21/20195/21/2019 5/21/2019 5/21/2019 5/21/2019 5/21/2019 5/21/20195/21/2019 5/21/2019 SC-22 (0.5)SC-22 (1.5)SC-18 (0.5)SC-19 (0.5)SC-20 (0.5)SC-21 (0.5) Hexadecanoic acid BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.186 J BDL NR NR NR 2.56 Hexadecanol BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.304 Hop-22(29)-en-3.beta.-o BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.775 Isoheptadecanol BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.207 Longipinane, (E)-BDL BDL BDL BDL 0.846 J BDL BDL BDL BDL BDL BDL NR NR NR 0.846 n-Hexadecanoic acid BDL 0.371 J 0.180 J 0.198 J BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.891 Octadecanoic acid BDL BDL BDL BDL 0.478 J BDL BDL BDL BDL BDL 0.229 J NR NR NR 0.478 Oleic Acid BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.184 J NR NR NR 0.184 Stigmast-4-en-3-one BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 4.74 Stigmasterol, 22,23-dih BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.625 Tetradecanoic acid BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.243 Tridecanoic acid BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NR NR NR 0.26 8.) Exposure Point Concentration is the maximum concentration for each detected compound 12.) Total chromium is to only be entered as Cr III in the risk calculator if the total is within natural background levels. The NURE database indicates background levels ranging from 5-168 mg/kg and the highest concentration is 20.1 mg/kg. 13.) The DUP-4 sample indicated the highest chromium concentration. Because it is a duplicate, it was not analyzed for hexavalent chromium. ATC recognizes this as a data gap. 1.) PSRG = North Carolina Department of Environmental Quality Preliminary Soil Remediation (Feb. 2018). 2.) Bold = Indicates concentrations above the corresponding PSRG. 3.) Values reported in mg/kg (milligrams per kilogram). 5.) J = The identification of the analyte is acceptable; the reported value is an estimate. 6.) B = The same analyte is found in the associated blank. 7.) BDL = Below Detection Limit 9.) NR = Not analyzed or not detected 10.) =Maximum concentration detected EPA 8260D TICs (continued) 11.) =Compound not listed in risk calculator Page 9 of 9 TABLE 2 GROUNDWATER EXPOSURE POINT CONCENTRATIONS Old Richmond County Landfill NONCD0000594 Rockingham, Richmond County, North Carolina PARAMETER TMW-1 TMW-2 TMW-3 TMW-4 TMW-5 DUP-B (Dup to TW- 5) TMW-6 TMW-7 DUP-C (Dup to TW- 7) SAMPLE DATE 5/14/2019 5/14/2019 5/14/2019 5/13/2019 5/13/2019 5/13/2019 5/13/2019 5/14/2019 5/14/2019 Arsenic 0.27 0.16 BDL 0.16 0.82 0.14 0.19 0.26 0.36 0.82 Cadmium 0.57 BDL BDL BDL BDL BDL BDL BDL BDL 0.57 Chromium BDL BDL BDL BDL 2.3 BDL BDL 0.51 0.87 2.3 Copper 29.5 40.4 BDL 32.5 2.2 39 38.4 61.9 115 115 Iron 58.3 251 27.7 J 141 1,090 202 298 145 355 1,090 Lead 0.2 0.22 BDL 0.11 2.2 0.1 0.13 0.23 0.74 2.2 Manganese 91.7 74.4 0.55 51.2 35.9 16.4 16.2 43.2 7.2 91.7 Nickel 4.9 1.4 BDL 4.2 2 1.1 1.1 3 0.91 4.9 Selenium 0.18 J 0.084 J BDL 0.17 J 0.22 J 0.095 J 0.088 J 0.8 0.11 J 0.8 Zinc 135 30.2 BDL 31.3 6.3 26.6 26.4 30.8 55.1 135 2-Methylnaphthalene BDL BDL 0.010 J BDL 0.011 J BDL 0.0084 J BDL 0.0098 J 0.011 Fluoranthene BDL BDL 0.020 J BDL BDL BDL BDL BDL BDL 0.02 1,2:4,5-Dibenzopyrene NA NA NA 6.1 J 9.0 J NA NA NA NA 9 Hexadecanoic acid NA NA NA NA NA NA 6.2 J 6.7 J NA 6.7 Undecane NA NA NA 6.1 J 5.7 J NA 6.4 J NA NA 6.4 1,4-Dioxane (p-Dioxane)BDL BDL BDL 1.4 J BDL BDL BDL BDL BDL 1.4 Acetone 10.6 J BDL 27.8 BDL BDL BDL BDL BDL BDL 27.8 Toluene BDL BDL BDL BDL 0.54 J 0.51 J BDL BDL BDL 0.54 Isopropyl Alcohol 18.4 J NA 66.5 J NA 6.6 J NA NA NA NA 66.5 Nitrate as N 5,000 8,500 3,500 72 J 2,200 2,200 4,800 850 850 8,500 Sulfate 600 J 68,300 12,200 800 J 10,200 10,600 880 J BDL BDL 68,300 Nitrogen, Ammonia BDL 54 J 200 BDL BDL BDL BDL BDL BDL 200 Notes: 1.) Values reported in µg/L (micrograms per liter). 2.) 2L Standards = 15A NCAC 02L .0202 Groundwater Quality Standards established by North Carolina Department of Environmental Quality in 2013. 3.) Bold = Indicates concentrations above the corresponding 2L Standard. 4.) J = Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. 5.) NE = Not Established 6.) BDL = Not Detected at or above adjusted reporting limit. 7.) NA = Not Analyzed 8.) Exposure Point Concentration is the maximum concentration for each detected compound 9.) =Maximum concentration detected 10.) =Compound not listed in risk calculator Exposure Point Concentration ADDITIONAL ANALYTES by EPA 350.1 Rev 2.0 1993 in μg/L NITRATE & SULFATE in μg/L by Method 9056A in μg/L TENTATIVELY IDENTIFIED COMPOUNDS - VOCS (GC/MS) by Method 8260D in μg/L VOLATILE ORGANIC COMPOUNDS (GC/MS) by Method 8260D in μg/L TENTATIVELY IDENTIFIED COMPOUNDS - SVOCS (GC/MS) by Method 8270E in μg/L SEMI-VOLATILE ORGANIC COMPOUNDS (GC/MS) by EPA 8270E by SIM in μg/L METALS (ICPMS) by Method 6020B in μg/L Page 1 of 1 TABLE 3 SURFACE WATER EXPOSURE POINT CONCENTRATIONS Old Richmond County Landfill NONCD0000594 Rockingham, Richmond County, North Carolina PARAMETER SW-1 SW-DUP (SW-1 DUP)SW-2 SAMPLE DATE 4/4/2019 4/4/2019 4/4/2019 Nitrogen, Ammonia BDL 0.062 J 0.066 J 0.066 Arsenic 0.25 0.24 0.35 0.35 Copper 0.26 J 0.27 J 0.47 J 0.47 Iron 1,180 1,170 2,120 2,120 Lead 0.17 0.092 J 0.16 0.17 Manganese 74.9 74.6 132 132 Nickel 0.29 J 0.29 J 0.30 J 0.3 Selenium 0.088 J 0.080 J 0.089 J 0.089 Zinc BDL BDL 1.6 J 1.6 1,4-Dichlorobenzene 2.7 J 2.9 J 2.7 J 2.9 Nitrate as N 260 260 150 260 Sulfate 34,400 34,700 43,100 43,100 Hexavalent Chromium-Low Level 0.0545 J NA BDL 0.0545 Notes: 1.) Values reported in µg/L (micrograms per liter). 2.) Bold = Indicates concentrations above the corresponding standard. 3.) J = The identification of the analyte is acceptable; the reported value is an estimate. 4.) BDL = Below Detection Limit. 5.) NA = Not Analyzed. 6.) Exposure Point Concentration is the maximum concentration for each detected compound 7.) =Maximum concentration detected 8.) =Compound not listed in risk calculator Exposure Point Concentration Metals (ICPMS) by Analytical Method 6020B Ammonia by Analytical Method EPA 350.1 Analytical Method EPA 8270E Analytical Method EPA 9056A Wet Chemistry by Method 218.6 Page 1 of 1 TABLE 4 LANDFILL GAS EXPOSURE POINT CONCENTRATIONS Old Richmond County LF NONCD0000594 Rockingham, Richmond County, North Carolina GP-1 GP-2 GP-3 GP-4 GP-10 DUP-C (GP-10 DUP)GP-11 GP-12 GP-13 GP-14 GP-15 GP-16 GP-17 GP-18 7/28/2020 7/28/2020 7/28/2020 7/28/2020 7/27/2020 7/27/2020 7/27/2020 7/27/2020 7/27/2020 7/27/2020 7/27/2020 7/28/2020 7/28/2020 7/28/2020 ND ND ND ND ND ND ND ND ND ND ND 2.93 ND ND 2.93 ND ND ND ND ND ND ND ND ND ND ND 5.80 ND ND 5.8 6.97 21.0 36.6 3.75 21.4 25.3 13.4 3.06 9.72 5.40 2.83 2.89 6.82 7.51 36.6 51.0 3.57 9.44 70.6 ND ND 7.20 6.41 ND 2.38 2.75 14.0 ND ND 70.6 1.59 4.29 7.56 ND 4.23 5.06 2.77 ND 2.14 1.04 ND ND 1.63 1.51 7.56 ND ND ND ND 10.5 12.5 ND ND 2.00 ND ND ND ND ND 12.5 1.02 ND ND ND ND ND 1.07 ND 2.40 ND ND ND ND ND 2.4 7.25 3.75 ND ND ND ND 7.7 ND 7.61 4.28 ND ND ND 5.54 7.7 12.8 13.3 12.3 12.9 3.12 ND 34.9 21.5 12.0 8.78 6.61 31.5 25.1 27.3 34.9 5.06 8.98 14.5 2.29 10.1 11.8 7.56 2.12 6.38 3.94 2.03 1.89 4.73 3.74 14.5 49.0 18.0 8.13 9.67 18.2 14.4 39.2 16.0 34.2 15.7 22.5 12.4 28.5 27.1 49 ND ND ND ND ND ND ND ND 0.920 ND ND ND ND ND 0.92 ND ND ND ND ND ND ND ND ND ND ND ND 10.8 ND 10.8 8.43 8.93 ND 9.00 3.17 3.67 20.6 12.7 8.06 6.88 8.03 6.75 11.3 4.42 20.6 ND 1.48 2.07 1.90 ND ND ND 1.52 ND ND ND ND 1.9 2.05 2.07 ND ND ND ND ND ND ND ND ND ND ND ND 243 ND 243 0.832 0.744 0.777 ND 1.10 1.77 0.787 ND 1.16 1.01 ND 1.81 0.494 1.47 1.81 ND ND ND ND ND ND ND ND ND ND ND ND 4.84 0.860 4.84 239 5.19 16.1 43.6 5.34 5.49 9.69 6.78 3.4 3.35 7.27 33.6 2.86 3.16 239 39.8 35.1 28.3 29.4 25.3 17.0 40.0 40.7 35.3 15.4 104 45.3 42.8 120 120 ND ND ND ND 0.897 0.897 1.47 ND 1.28 0.889 1.45 ND 0.932 ND 1.47 ND ND ND ND ND ND 1.10 ND 1.1 ND ND ND ND ND 1.1 3.23 ND ND 2.38 3.56 3.42 5.07 3.07 4.94 2.78 3.20 1.96 3.46 2.63 5.07 1.45 0.915 0.889 1.32 1.59 1.57 3.70 1.80 3.11 2.75 1.76 1.27 1.72 1.55 3.7 ND 4.48 1.74 1.00 12.3 ND ND ND ND ND ND 0.944 4.97 ND 12.3 13.0 2.30 3.30 ND 26.0 8.74 9.52 ND 29.9 17.0 3.39 ND 5.22 ND 29.9 3.27 B 1.54 B 1.72 B 1.81 B 1.96 B 1.98 B 2.19 B 1.37 B 1.86 B 2.19 B 2.41 B 2.03 B 1.54 B 1.70 B 3.27 1.17 ND 1.09 1.11 ND 0.923 5.19 1.11 1.89 1.26 1.55 1.01 1.16 1.23 5.19 21.8 19.5 50.2 15.1 3.16 4.64 2.51 21.7 1.91 ND 5.09 46.2 132 8.96 132 3.83 ND ND ND ND ND ND ND 6.55 ND ND ND ND ND 6.55 3.43 1.90 1.52 2.28 4.52 3.02 3.64 2.52 4.11 2.61 3.62 2.23 3.68 2.88 4.52 ND ND ND ND ND ND ND ND ND ND ND 2.03 ND ND 2.03 ND ND ND ND ND ND ND ND ND ND ND 1.32 7.13 ND 7.13 Trichlorofluoromethane 142 10.3 95.5 127 4.13 4.34 7.53 5.00 2.37 3.47 9.33 26.2 1.68 1.92 142 Notes: 1.) ND = Not Detected 2.) B = The same analyte is found in the associated blank. 3.) Bold values exceed North Carolina Department of Environmental Quality Residential Soil Gas Screening Levels (updated July 2020). 4.) Exposure Point Concentration is the maximum concentration for each detected compound 5.) Concentrations reported in micrograms per cubic meter (µg/m3) 6.) =Maximum concentration detected 7.) =Compound not listed in risk calculator 8.77 PARAMETER Sample Date 1,1,1-Trichloroethane 1,1,2-Trichlorotrifluoroethane 1,2,4-Trimethylbenzene Dichlorodifluoromethane Ethanol Ethylbenzene Heptane 1,2-Dichlorotetrafluoroethane cis-1,2-Dichloroethene 1,4-Dioxane 2-Butanone (MEK) 2-Propanol 4-Ethyltoluene Acetone Benzene Bromodichloromethane Carbon disulfide 1,3,5-Trimethylbenzene 1,3-Dichlorobenzene m&p-Xylene Methylene Chloride Exposure Point Concentration Volatile Organic Compounds by Method TO-15 Trichloroethylene n-Hexane o-Xylene Propene Styrene Tetrachloroethylene Tetrahydrofuran Chlorobenzene Chloroform Chloromethane Toluene trans-1,2-Dichloroethene PR O J E C T N O . NO T E S : 1. Fe a t u r e s s h o w n a r e n o t a n a u t h o r i t a t i v e l o c a t i o n , n o r a r e t h e y pr e s e n t e d t o a s t a t e d a c c u r a c y . DA T E TIT L E SC A L E RE V . B Y PR E P . B Y CA D F I L E CO O R D I N A T E S Y S T E M : NA D 1 9 8 3 N O R T H C A R O L I N A S T A T E P L A N E F I P S 3 2 0 0 , U S SU R V E Y F E E T (9 1 9 ) 8 7 1 - 0 9 9 9 Ra l e i g h , N o r t h C a r o l i n a , 2 7 6 0 4 AT C A s s o c i a t e s o f N o r t h C a r o l i n a , P . C . PR O J E C T N O . NO T E S : 1. Fe a t u r e s s h o w n a r e n o t a n a u t h o r i t a t i v e l o c a t i o n , n o r a r e t h e y pr e s e n t e d t o a s t a t e d a c c u r a c y . DA T E TIT L E SC A L E RE V . B Y PR E P . B Y CA D F I L E CO O R D I N A T E S Y S T E M : NA D 1 9 8 3 N O R T H C A R O L I N A S T A T E P L A N E F I P S 3 2 0 0 , U S SU R V E Y F E E T (9 1 9 ) 8 7 1 - 0 9 9 9 Ra l e i g h , N o r t h C a r o l i n a , 2 7 6 0 4 AT C A s s o c i a t e s o f N o r t h C a r o l i n a , P . C . PO P P Y S E E D D R I V E SCALE: 1" = 100' 100 0 25 1005075 N SW/ SED-2 SW/ SED-1 GP-3 GP-2 GP-11 GP-4 GP-8 GP-7 GP-6 GP-5 GP-10 DISPOSAL WASTE AREA A 4.683 ACRES GP-9 X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X HO U S E TR A I L E R CANOPY SUBJECT PROPERTY N/FDAVID M. TARLTON & WIFE, TAMMIE J. TARLTON PIN # 746502854954 DB 1368 PG 124 DB 1733 PG 360 PLAT 783 PAGE Q 14.158 ACRES (616,711 SF) THIS PORTION OF THE SUBJECT PROPERTY DESCRIBED IN DB 1733 PG 360 N/FDAVID M. TARLTON & WIFE, TAMMIE J. TARLTON DB 1712 PG 411 PLAT SLIDE 3 MAP "B" (LOTS 5 & 6, BLOCK A) PROPERTY NOTE: RICHMOND COUNTY GIS SHOWS THIS AREA BEING A PORTION OF THE SUBJECT PROPERTY, BUT THE SURVEYOR FOUND NO LEGAL REFERENCE FOR A RECOMBINATION OF THE LEGAL LOTS. THIS AREA WAS ACQUIRED BY THE TARLTON'S BY WAY OF THE SAME DEED THAT IS REFERENCED FOR THE PROPERTY LYING SOUTH OF THE SUBJECT PROPERTY. GIS LINE ONLY - SHOWN APPROXIMATE 410 410 410 400 400 390 390 380 390 380 390 390 390 41 2 414 416 408 406 404 402 398 39 6 394 392 388 386 384 382 408 406 404 402 400 39 4 398402 396 394 392 392 394 396 388 378 382 384 386382 38 4 388 392 384 384 384 386 388 402 396 398 398 386 NOTE: ALL LOCATIONS ARE APPROXIMATE TOPOGRAPHIC CONTOUR LEGEND: RICHMOND COUNTY PARCELS SITE PROPERTY LINE X X 410 DISPOSAL WASTE AREA B 0.210 ACRES LANDFILL GAS MONITORING POINTGP-1 Point Identification GP-15 GP-18 GP-17 GP-12 GP-13 GP-14 X X X XXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXX X X X X X X XXXXXXXXXXXXXXXXXXXXXXX GP-16 SURFACE WASTE 1 SW/SED-2 SURFACE WATER / SEDIMENT SAMPLE Sample Identification Figure: Dra w i n g F i l e : Pr o j e c t N u m b e r : Ck d . B y : Dr n . B y : Ap p ' d B y : Ck d . D a t e : Scale: Date: H: \ 2 0 2 0 \ O T H E R O F F I C E S \ N O R T H C A R O L I N A \ N C D E N R P R E - R E G U L A T O R Y L A N D F I L L \ O L D R I C H M O N D C O . L A N D F I L L \ P R L U 0 5 9 4 C - G P . D W G , FI G 5 LA N D F I L L G A S P R O B E M A P 09/17/2020 SE E L O W E R L E F T OL D R I C H M O N D C O U N T Y L F RO C K I N G H A M , R I C H M O N D C O U N T Y , N O R T H C A R O L I N A PR L U 0 5 9 4 C AS SHOWN DH SL 5 NO T E S : 1. Fe a t u r e s s h o w n a r e n o t a n a u t h o r i t a t i v e l o c a t i o n , n o r a r e t h e y p r e s e n t e d to a s t a t e d a c c u r a c y . CO O R D I N A T E S Y S T E M : NA D 1 9 8 3 N O R T H C A R O L I N A S T A T E P L A N E F I P S 3 2 0 0 , U S S U R V E Y F E E T Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Exposure Unit #1 - Resident, Non-Residential, & Recreator North Carolina Department of Environmental Quality Risk Calculator Old Richmond County Landfill Rockingham, Richmond County, North Carolina Pre-Regulatory Landfill Unit NONCD0000594 July 2020 May 2020 EPA RSL Table 12/7/2020 Prepared By:ATC Associates of North Carolina, P.C. 2727 E. Millbrook Road, Ste 121, Raleigh, NC 27604 Pre-Regulatory Landfill Unit North Carolina DEQ Risk Calculator Table of Contents Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Resident, Non-Residential, & Recreator Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Resident, Non-Residential, & Recreator Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 1 70 80 330 1 250 8 3527 0.3 50 100 19652 2.5 0.71 1 20 350 24 6032 0.07 0.54 1 70 80 2373 0.2 200 6365 0.78 Input Form 1B Exposure Unit ID: Exposure Unit #1 - Resident, Non-Residential, & Recreator Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: Exposure Unit #1 - Resident, Non-Residential, & Recreator Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Contaminant Migration Parameters Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Resident, Non-Residential, & Recreator Parameter Default Value Site Specific Value Justification Distance to Protection of Groundwater Point of Exposure (POEgw) (feet) 0 0 Distance to Protection of Surface Water Point of Exposure (POEsw) (feet) 0 0 Depth to Base of Affected Soils (ds) (cm)1244 183 ATC used the maximum soil cover depth within the landfill unit (6 feet, 182.88 cm) as the depth of the affected soils. Length of Affected Soil Parallel to Assumed GW Flow Direction (L) (cm) Site-specific value required Areal extent of soil contamination range 0.5-500 (As) (acres) 0.5 4.9 ATC used the entire waste disposal unit as the areal extent of soil contamination Fraction of vegetative cover (V) (unitless)0.5 1.0 The entire waste disposal unit is covered with vegetation. 0.15 (soil to outdoor air pathway) 0.07 This value is based on the average of all laboratory reported moisture content values for soil samples collected at the site. 0.3 (soil to groundwater pathway) 0.3 0.28 (soil to outdoor air pathway) 0.36 This value is based on the total soil porosity minus the water filled soil porosity. 0.13 (soil to groundwater pathway) 0.13 Provide justification for the contaminant migration parameters used. Water Filled Soil Porosity (θw) (unitless) Air Filled Soil Porosity (θa) (unitless) Input Form 1C North Carolina DEQ Risk Calculator Contaminant Migration Parameters Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Resident, Non-Residential, & Recreator Parameter Default Value Site Specific Value Justification Provide justification for the contaminant migration parameters used. Input Form 1C Total Soil Porosity (n) (unitless)0.43 0.43 Total porosity has not been measured at this site. The soil is predominantly classified as a silty sand. Therefore, ATC used a published value of fine-grained sand (McWorter and Sunada, 1997.) Dry Soil Bulk Density (ρb) (g/cm3)1.5 1.66 Dry bulk density has not been measured at this site. The soil is predominantly classified as a silty sand. Therefore, ATC used a published value sand (US EPA, 2004). Net Infiltration Rate (I) (cm/yr)66 66 0.006 (soil to outdoor air pathway) 0.006 The default value was used as fraction organic carbon has not been measured at the site. 0.002 (soil leaching to groundwater pathway) 0.002 Aquifer Hydraulic Conductivity (K) (cm/d) Site-specific value required Hydraulic Gradient (i) (unitless) Site-specific value required Average Groundwater Temperature (Tgw) (°C)25 25 Aquifer Thickness (da) (cm)Site-specific value required Groundwater Source Thickness (Sd) (cm) Site-specific value required Groundwater Source Width (Sw) (cm) Site-specific value required Fraction Organic Carbon (foc) (unitless) North Carolina DEQ Risk Calculator Contaminant Migration Parameters Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Resident, Non-Residential, & Recreator Parameter Default Value Site Specific Value Justification Provide justification for the contaminant migration parameters used. Input Form 1C Plume Thickness at GW/SW Discharge (δsw) (cm) Site-specific value required Plume Width at GW/SW Discharge (Wgwsw) (cm) Site-specific value required Surface Water Flowrate at GW/SW Discharge (Qsw) (cm3/d) Site-specific value required North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Resident, Non-Residential, & Recreator Exposure Point Concentration (mg/kg) Notes:CAS Number Chemical Units 0.249 See Table 1 67-64-1 Acetone mg/kg 0.482 See Table 1 7440-36-0 Antimony (metallic)mg/kg 3.84 See Table 1 7440-38-2 Arsenic, Inorganic mg/kg 0.691 See Table 1 7440-41-7 Beryllium and compounds mg/kg 1.69 See Table 1 7440-43-9 Cadmium (Diet)mg/kg 20.1 See Table 1 16065-83-1 Chromium(III), Insoluble Salts mg/kg 0.547 See Table 1 18540-29-9 Chromium(VI)mg/kg 7.84 See Table 1 7440-50-8 Copper mg/kg 9350 See Table 1 7439-89-6 Iron mg/kg 68.5 See Table 1 7439-92-1 ~Lead and Compounds mg/kg 39.1 See Table 1 7439-96-5 Manganese (Non-diet)mg/kg 0.53 See Table 1 7439-97-6 ~Mercury (elemental)mg/kg 0.0084 See Table 1 79-20-9 Methyl Acetate mg/kg 0.0657 See Table 1 78-93-3 Methyl Ethyl Ketone (2-Butanone)mg/kg 0.399 See Table 1 75-09-2 Methylene Chloride mg/kg 4.83 See Table 1 7440-02-0 Nickel Soluble Salts mg/kg 0.0549 See Table 1 109-66-0 Pentane, n-mg/kg 0.0293 See Table 1 12672-29-6 ~Aroclor 1248 mg/kg 0.0721 See Table 1 11097-69-1 ~Aroclor 1254 mg/kg 1.1 See Table 1 7782-49-2 Selenium mg/kg 0.354 See Table 1 7440-22-4 Silver mg/kg 0.677 See Table 1 7440-28-0 Thallium (Soluble Salts)mg/kg 67.2 See Table 1 7440-66-6 Zinc and Compounds mg/kg Input Form 2A Soil Exposure Point Concentration Table Description of Exposure Point Concentration Selection: Exposure point concentrations are the maximum concentration for each detected compound listed in the risk calculator. North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Resident, Non-Residential, & Recreator Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/L)Notes:CAS Number Chemical Units 27.8 See Table 2 67-64-1 Acetone ug/L 0.82 See Table 2 7440-38-2 Arsenic, Inorganic ug/L 0.57 See Table 2 7440-43-9 Cadmium (Diet)ug/L 2.3 See Table 2 16065-83-1 Chromium(III), Insoluble Salts ug/L 115 See Table 2 7440-50-8 Copper ug/L 1.4 See Table 2 123-91-1 Dioxane, 1,4-ug/L 6.7 See Table 2 124-04-9 Hexanedioic Acid ug/L 1090 See Table 2 7439-89-6 Iron ug/L 66.5 See Table 2 67-63-0 Isopropanol ug/L 2.2 See Table 2 7439-92-1 ~Lead and Compounds ug/L 91.7 See Table 2 7439-96-5 Manganese (Diet)ug/L 4.9 See Table 2 7440-02-0 Nickel Soluble Salts ug/L 8500 See Table 2 14797-55-8 Nitrate ug/L 0.02 See Table 2 206-44-0 ~Fluoranthene ug/L 0.011 See Table 2 91-57-6 ~Methylnaphthalene, 2-ug/L 0.8 See Table 2 7782-49-2 Selenium ug/L 0.54 See Table 2 108-88-3 Toluene ug/L 135 See Table 2 7440-66-6 Zinc and Compounds ug/L Input Form 2B Groundwater Exposure Point Concentration Table Exposure point concentrations are the maximum concentration for each detected compound listed in the risk calculator. North Carolina DEQ Risk Calculator Exposure Point Concentrations Input Form 2C Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Resident, Non-Residential, & Recreator Surface Water Exposure Point Concentration Table Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/L) Notes:CAS Number Chemical Units 0.35 See Table 3 7440-38-2 Arsenic, Inorganic ug/L 0.0545 See Table 3 18540-29-9 Chromium(VI)ug/L 0.47 See Table 3 7440-50-8 Copper ug/L 2.9 See Table 3 106-46-7 Dichlorobenzene, 1,4-ug/L 2120 See Table 3 7439-89-6 Iron ug/L 0.17 See Table 3 7439-92-1 ~Lead and Compounds ug/L 132 See Table 3 7439-96-5 Manganese (Diet)ug/L 0.3 See Table 3 7440-02-0 Nickel Soluble Salts ug/L 260 See Table 3 14797-55-8 Nitrate ug/L 0.089 See Table 3 7782-49-2 Selenium ug/L 1.6 See Table 3 7440-66-6 Zinc and Compounds ug/L Exposure point concentrations are the maximum concentration for each detected compound listed in the risk calculator. North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Resident, Non-Residential, & Recreator Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Units 49 See Table 4 67-64-1 Acetone ug/m3 0.92 See Table 4 71-43-2 Benzene ug/m3 10.8 See Table 4 75-27-4 Bromodichloromethane ug/m3 20.6 See Table 4 75-15-0 Carbon Disulfide ug/m3 2.07 See Table 4 108-90-7 Chlorobenzene ug/m3 243 See Table 4 67-66-3 Chloroform ug/m3 1.81 See Table 4 74-87-3 Chloromethane ug/m3 239 See Table 4 75-71-8 Dichlorodifluoromethane ug/m3 4.84 See Table 4 156-59-2 Dichloroethylene, 1,2-cis-ug/m3 2.03 See Table 4 156-60-5 Dichloroethylene, 1,2-trans-ug/m3 2.4 See Table 4 123-91-1 Dioxane, 1,4-ug/m3 1.47 See Table 4 100-41-4 Ethylbenzene ug/m3 6.55 See Table 4 109-99-9 ~Tetrahydrofuran ug/m3 1.1 See Table 4 142-82-5 Heptane, N-ug/m3 29.9 See Table 4 110-54-3 Hexane, N-ug/m3 34.9 See Table 4 67-63-0 Isopropanol ug/m3 7.7 See Table 4 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 12.3 See Table 4 75-09-2 Methylene Chloride ug/m3 3.27 See Table 4 115-07-1 Propylene ug/m3 5.19 See Table 4 100-42-5 Styrene ug/m3 132 See Table 4 127-18-4 Tetrachloroethylene ug/m3 4.52 See Table 4 108-88-3 Toluene ug/m3 5.8 See Table 4 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 2.93 See Table 4 71-55-6 Trichloroethane, 1,1,1-ug/m3 7.13 See Table 4 79-01-6 Trichloroethylene ug/m3 142 See Table 4 75-69-4 Trichlorofluoromethane ug/m3 36.6 See Table 4 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 7.56 See Table 4 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 8.77 See Table 4 1330-20-7 Xylenes ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Exposure point concentrations are the maximum concentration for each detected compound listed in the risk calculator. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Resident, Non-Residential, & Recreator Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil 7.9E-06 1.4E+00 YES Groundwater Use*1.9E-05 9.2E-01 NO Soil 1.5E-06 1.1E-01 NO Groundwater Use*3.8E-06 1.5E-01 NO Construction Worker Soil 4.0E-07 5.7E-01 NO Soil 4.4E-06 7.2E-01 NO Surface Water*1.7E-06 5.2E-02 NO Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 6.5E-05 3.7E-01 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 5.0E-06 3.0E-02 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Direct Contact - Resident Soil Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Resident, Non-Residential, & Recreator * - Note that inhalation on this calculator refers to outdoor inhalation of volatiles and particulates, not indoor inhalation associated with vapor intrusion. CAS #Chemical Name: Ingestion Concentration (mg/kg) Dermal Concentration (mg/kg) Inhalation Concentration (mg/kg)* Ingestion Carcinogenic Risk Dermal Carcinogenic Risk Inhalation Carcinogenic Risk* Calculated Carcinogenic Risk Ingestion Hazard Quotient Dermal Hazard Quotient Inhalation Hazard Quotient* Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 0.249 0.249 0.249 3.5E-06 5.9E-07 4.1E-06 7440-36-0 Antimony (metallic)0.482 0.482 0.482 1.5E-02 7.7E-11 1.5E-02 7440-38-2 Arsenic, Inorganic 3.84 3.84 3.84 5.0E-06 7.0E-07 2.9E-13 5.7E-06 9.8E-02 1.2E-02 1.2E-08 1.1E-01 7440-41-7 Beryllium and compounds 0.691 0.691 0.691 2.9E-14 2.9E-14 4.4E-03 1.6E-09 4.4E-03 7440-43-9 Cadmium (Diet)1.69 1.69 1.69 5.4E-14 5.4E-14 2.2E-02 2.1E-03 8.1E-09 2.4E-02 16065-83-1 Chromium(III), Insoluble Salts 20.1 20.1 20.1 1.7E-04 1.7E-04 18540-29-9 Chromium(VI)0.547 0.547 0.547 1.8E-06 2.3E-12 1.8E-06 2.3E-03 2.6E-10 2.3E-03 7440-50-8 Copper 7.84 7.84 7.84 2.5E-03 2.5E-03 7439-89-6 Iron 9350 9350 9350 1.7E-01 1.7E-01 7439-92-1 ~Lead and Compounds 68.5 68.5 68.5 <SL**<SL**<SL** 7439-96-5 Manganese (Non-diet)39.1 39.1 39.1 2.1E-02 3.7E-08 2.1E-02 7439-97-6 ~Mercury (elemental)0.53 0.53 0.53 1.1E-01 1.1E-01 79-20-9 Methyl Acetate 0.0084 0.0084 0.0084 1.1E-07 1.1E-07 78-93-3 Methyl Ethyl Ketone (2-Butanone)0.0657 0.0657 0.0657 1.4E-06 9.6E-07 2.4E-06 75-09-2 Methylene Chloride 0.399 0.399 0.399 5.2E-09 3.0E-10 5.5E-09 8.5E-04 4.9E-05 9.0E-04 7440-02-0 Nickel Soluble Salts 4.83 4.83 4.83 2.2E-14 2.2E-14 3.1E-03 2.6E-09 3.1E-03 109-66-0 Pentane, n-0.0549 0.0549 0.0549 4.0E-06 4.0E-06 12672-29-6 ~Aroclor 1248 0.0293 0.0293 0.0293 8.4E-08 3.3E-08 2.6E-08 1.4E-07 11097-69-1 ~Aroclor 1254 0.0721 0.0721 0.0721 2.1E-07 8.2E-08 3.8E-08 3.3E-07 4.6E-02 1.5E-02 6.1E-02 7782-49-2 Selenium 1.1 1.1 1.1 2.8E-03 2.6E-12 2.8E-03 7440-22-4 Silver 0.354 0.354 0.354 9.1E-04 9.1E-04 7440-28-0 Thallium (Soluble Salts)0.677 0.677 0.677 8.7E-01 8.7E-01 7440-66-6 Zinc and Compounds 67.2 67.2 67.2 2.9E-03 2.9E-03 Cumulative:7.9E-06 1.4E+00 Output Form 2A ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate cancer risk or hazard quotient. Lead concentrations are compared to the EPA screening level of 400 mg/kg for residential soil. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Direct Contact - Resident Groundwater Use Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Resident, Non-Residential, & Recreator * - Note that inhalation on this calculator refers to inhalation associated with tapwater use, not inhalation associated with vapor intrusion from subsurface groundwater sources. CAS #Chemical Name: Ingestion Concentration (ug/L) Dermal Concentration (ug/L) Inhalation Concentration (ug/L)* Ingestion Carcinogenic Risk Dermal Carcinogenic Risk Inhalation Carcinogenic Risk* Calculated Carcinogenic Risk Ingestion Hazard Quotient Dermal Hazard Quotient Inhalation Hazard Quotient* Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 27.8 27.8 27.8 1.5E-03 6.3E-06 4.3E-04 2.0E-03 7440-38-2 Arsenic, Inorganic 0.82 0.82 0.82 1.6E-05 8.4E-08 1.6E-05 1.4E-01 6.0E-04 1.4E-01 7440-43-9 Cadmium (Diet)0.57 0.57 0.57 2.8E-02 2.8E-02 16065-83-1 Chromium(III), Insoluble Salts 2.3 2.3 2.3 7.6E-05 2.6E-05 1.0E-04 7440-50-8 Copper 115 115 115 1.4E-01 6.3E-04 1.4E-01 123-91-1 Dioxane, 1,4-1.4 1.4 1.4 1.8E-06 6.2E-09 1.2E-06 3.0E-06 2.3E-03 7.3E-06 2.2E-02 2.5E-02 124-04-9 Hexanedioic Acid 6.7 6.7 6.7 1.7E-04 6.2E-07 1.7E-04 7439-89-6 Iron 1090 1090 1090 7.8E-02 3.4E-04 7.8E-02 67-63-0 Isopropanol 66.5 66.5 66.5 1.7E-03 1.0E-05 1.6E-01 1.6E-01 7439-92-1 ~Lead and Compounds 2.2 2.2 2.2 <SL**<SL**<SL** 7439-96-5 Manganese (Diet)91.7 91.7 91.7 3.3E-02 3.3E-02 7440-02-0 Nickel Soluble Salts 4.9 4.9 4.9 1.2E-02 2.7E-04 1.2E-02 14797-55-8 Nitrate 8500 8500 8500 2.6E-01 1.2E-03 2.7E-01 206-44-0 ~Fluoranthene 0.02 0.02 0.02 2.5E-05 2.5E-05 91-57-6 ~Methylnaphthalene, 2-0.011 0.011 0.011 1.4E-04 1.7E-04 3.1E-04 7782-49-2 Selenium 0.8 0.8 0.8 8.0E-03 3.5E-05 8.0E-03 108-88-3 Toluene 0.54 0.54 0.54 3.4E-04 1.0E-04 5.2E-05 4.9E-04 7440-66-6 Zinc and Compounds 135 135 135 2.2E-02 5.9E-05 2.2E-02 Cumulative:1.9E-05 9.2E-01 Output Form 2B ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate cancer risk or hazard quotient. Lead concentrations are compared to the EPA Action Level of 15 μg/L. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Direct Contact - Non-Residential Worker Soil Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Resident, Non-Residential, & Recreator * - Note that inhalation on this calculator refers to outdoor inhalation of volatiles and particulates, not indoor inhalation associated with vapor intrusion. CAS #Chemical Name: Ingestion Concentration (mg/kg) Dermal Concentration (mg/kg) Inhalation Concentration (mg/kg)* Ingestion Carcinogenic Risk Dermal Carcinogenic Risk Inhalation Carcinogenic Risk Calculated Carcinogenic Risk Ingestion Hazard Quotient Dermal Hazard Quotient Inhalation Hazard Quotient Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 0.249 0.249 0.249 2.4E-07 1.4E-07 3.8E-07 7440-36-0 Antimony (metallic)0.482 0.482 0.482 1.0E-03 1.8E-11 1.0E-03 7440-38-2 Arsenic, Inorganic 3.84 3.84 3.84 1.1E-06 2.2E-07 6.7E-14 1.3E-06 6.6E-03 1.4E-03 2.9E-09 8.0E-03 7440-41-7 Beryllium and compounds 0.691 0.691 0.691 6.7E-15 6.7E-15 3.0E-04 3.9E-10 3.0E-04 7440-43-9 Cadmium (Diet)1.69 1.69 1.69 1.2E-14 1.2E-14 1.4E-03 2.4E-04 1.9E-09 1.7E-03 16065-83-1 Chromium(III), Insoluble Salts 20.1 20.1 20.1 1.1E-05 1.1E-05 18540-29-9 Chromium(VI)0.547 0.547 0.547 8.4E-08 1.9E-13 8.4E-08 1.6E-04 6.2E-11 1.6E-04 7440-50-8 Copper 7.84 7.84 7.84 1.7E-04 1.7E-04 7439-89-6 Iron 9350 9350 9350 1.1E-02 1.1E-02 7439-92-1 ~Lead and Compounds 68.5 68.5 68.5 <SL**<SL**<SL** 7439-96-5 Manganese (Non-diet)39.1 39.1 39.1 1.4E-03 8.9E-09 1.4E-03 7439-97-6 ~Mercury (elemental)0.53 0.53 0.53 2.6E-02 2.6E-02 79-20-9 Methyl Acetate 0.0084 0.0084 0.0084 7.2E-09 7.2E-09 78-93-3 Methyl Ethyl Ketone (2-Butanone)0.0657 0.0657 0.0657 9.4E-08 2.3E-07 3.2E-07 75-09-2 Methylene Chloride 0.399 0.399 0.399 2.4E-10 2.5E-11 2.7E-10 5.7E-05 1.2E-05 6.9E-05 7440-02-0 Nickel Soluble Salts 4.83 4.83 4.83 5.1E-15 5.1E-15 2.1E-04 6.1E-10 2.1E-04 109-66-0 Pentane, n-0.0549 0.0549 0.0549 9.6E-07 9.6E-07 12672-29-6 ~Aroclor 1248 0.0293 0.0293 0.0293 1.8E-08 1.1E-08 5.9E-09 3.4E-08 11097-69-1 ~Aroclor 1254 0.0721 0.0721 0.0721 4.4E-08 2.6E-08 8.8E-09 7.9E-08 3.1E-03 1.8E-03 4.9E-03 7782-49-2 Selenium 1.1 1.1 1.1 1.9E-04 6.3E-13 1.9E-04 7440-22-4 Silver 0.354 0.354 0.354 6.1E-05 6.1E-05 7440-28-0 Thallium (Soluble Salts)0.677 0.677 0.677 5.8E-02 5.8E-02 7440-66-6 Zinc and Compounds 67.2 67.2 67.2 1.9E-04 1.9E-04 Cumulative:1.5E-06 1.1E-01 Output Form 2C ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate cancer risk or hazard quotient. Lead concentrations are compared to the EPA screening level of 800 mg/kg for commercial/industrial soil. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Direct Contact - Non-Residential Worker Groundwater Use Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Resident, Non-Residential, & Recreator * - Note that inhalation on this calculator refers to inhalation associated with tapwater use, not inhalation associated with vapor intrusion from subsurface groundwater sources. CAS #Chemical Name: Ingestion Concentration (ug/L) Dermal Concentration (ug/L) Inhalation Concentration (ug/L)* Ingestion Carcinogenic Risk Dermal Carcinogenic Risk Inhalation Carcinogenic Risk Calculated Carcinogenic Risk Ingestion Hazard Quotient Dermal Hazard Quotient Inhalation Hazard Quotient Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 27.8 27.8 27.8 2.2E-04 3.0E-06 1.0E-04 3.2E-04 7440-38-2 Arsenic, Inorganic 0.82 0.82 0.82 3.1E-06 5.0E-08 3.2E-06 1.9E-02 3.1E-04 2.0E-02 7440-43-9 Cadmium (Diet)0.57 0.57 0.57 4.1E-03 4.1E-03 16065-83-1 Chromium(III), Insoluble Salts 2.3 2.3 2.3 1.1E-05 1.3E-05 2.4E-05 7440-50-8 Copper 115 115 115 2.0E-02 3.2E-04 2.1E-02 123-91-1 Dioxane, 1,4-1.4 1.4 1.4 3.6E-07 3.6E-09 2.9E-07 6.4E-07 3.3E-04 3.4E-06 5.3E-03 5.7E-03 124-04-9 Hexanedioic Acid 6.7 6.7 6.7 2.4E-05 2.8E-07 2.4E-05 7439-89-6 Iron 1090 1090 1090 1.1E-02 1.8E-04 1.1E-02 67-63-0 Isopropanol 66.5 66.5 66.5 2.4E-04 4.9E-06 3.8E-02 3.8E-02 7439-92-1 ~Lead and Compounds 2.2 2.2 2.2 <SL**<SL**<SL** 7439-96-5 Manganese (Diet)91.7 91.7 91.7 4.7E-03 4.7E-03 7440-02-0 Nickel Soluble Salts 4.9 4.9 4.9 1.7E-03 1.4E-04 1.9E-03 14797-55-8 Nitrate 8500 8500 8500 3.8E-02 6.0E-04 3.8E-02 206-44-0 ~Fluoranthene 0.02 0.02 0.02 3.6E-06 3.6E-06 91-57-6 ~Methylnaphthalene, 2-0.011 0.011 0.011 2.0E-05 7.8E-05 9.7E-05 7782-49-2 Selenium 0.8 0.8 0.8 1.1E-03 1.8E-05 1.2E-03 108-88-3 Toluene 0.54 0.54 0.54 4.8E-05 4.7E-05 1.2E-05 1.1E-04 7440-66-6 Zinc and Compounds 135 135 135 3.2E-03 3.0E-05 3.2E-03 Cumulative:3.8E-06 1.5E-01 Output Form 2D ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate cancer risk or hazard quotient. Lead concentrations are compared to the EPA Action Level of 15 μg/L. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Direct Contact - Construction Worker Soil Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Resident, Non-Residential, & Recreator * - Note that inhalation on this calculator refers to outdoor inhalation of volatiles and particulates, not indoor inhalation associated with vapor intrusion. CAS #Chemical Name: Ingestion Concentration (mg/kg) Dermal Concentration (mg/kg) Inhalation Concentration (mg/kg)* Ingestion Carcinogenic Risk Dermal Carcinogenic Risk Inhalation Carcinogenic Risk Calculated Carcinogenic Risk Ingestion Hazard Quotient Dermal Hazard Quotient Inhalation Hazard Quotient Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 0.249 0.249 0.249 3.7E-07 2.1E-06 2.5E-06 7440-36-0 Antimony (metallic)0.482 0.482 0.482 3.6E-03 1.1E-04 3.7E-03 7440-38-2 Arsenic, Inorganic 3.84 3.84 3.84 1.4E-07 2.2E-08 5.1E-08 2.1E-07 2.3E-02 3.6E-03 5.8E-02 8.4E-02 7440-41-7 Beryllium and compounds 0.691 0.691 0.691 5.1E-09 5.1E-09 4.1E-04 7.8E-03 8.2E-03 7440-43-9 Cadmium (Diet)1.69 1.69 1.69 9.4E-09 9.4E-09 1.0E-02 1.3E-03 3.8E-02 4.9E-02 16065-83-1 Chromium(III), Insoluble Salts 20.1 20.1 20.1 3.9E-05 9.0E-04 9.4E-04 18540-29-9 Chromium(VI)0.547 0.547 0.547 1.1E-08 1.4E-07 1.5E-07 3.2E-04 4.1E-04 7.3E-04 7440-50-8 Copper 7.84 7.84 7.84 2.3E-03 2.3E-03 7439-89-6 Iron 9350 9350 9350 3.9E-02 3.9E-02 7439-92-1 ~Lead and Compounds 68.5 68.5 68.5 <SL**<SL**<SL** 7439-96-5 Manganese (Non-diet)39.1 39.1 39.1 4.8E-03 1.8E-01 1.8E-01 7439-97-6 ~Mercury (elemental)0.53 0.53 0.53 1.3E-01 1.3E-01 79-20-9 Methyl Acetate 0.0084 0.0084 0.0084 2.5E-08 3.7E-05 3.7E-05 78-93-3 Methyl Ethyl Ketone (2-Butanone)0.0657 0.0657 0.0657 9.7E-08 1.9E-05 1.9E-05 75-09-2 Methylene Chloride 0.399 0.399 0.399 3.2E-11 2.6E-11 5.8E-11 2.0E-05 1.8E-04 2.0E-04 7440-02-0 Nickel Soluble Salts 4.83 4.83 4.83 3.9E-09 3.9E-09 7.1E-04 5.4E-03 6.1E-03 109-66-0 Pentane, n-0.0549 0.0549 0.0549 2.6E-06 2.6E-06 12672-29-6 ~Aroclor 1248 0.0293 0.0293 0.0293 2.4E-09 1.1E-09 1.2E-09 4.6E-09 11097-69-1 ~Aroclor 1254 0.0721 0.0721 0.0721 5.8E-09 2.6E-09 1.8E-09 1.0E-08 7.1E-03 3.2E-03 1.0E-02 7782-49-2 Selenium 1.1 1.1 1.1 6.5E-04 1.2E-05 6.6E-04 7440-22-4 Silver 0.354 0.354 0.354 2.1E-04 2.1E-04 7440-28-0 Thallium (Soluble Salts)0.677 0.677 0.677 5.0E-02 5.0E-02 7440-66-6 Zinc and Compounds 67.2 67.2 67.2 6.6E-04 6.6E-04 Cumulative:4.0E-07 5.7E-01 Output Form 2E ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate cancer risk or hazard quotient. Lead concentrations are compared to the EPA screening level of 800 mg/kg for commercial/industrial soil. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Direct Contact - Recreator/Trespasser Soil Output Form 2F Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Resident, Non-Residential, & Recreator * - Note that inhalation on this calculator refers to outdoor inhalation of volatiles and particulates, not indoor inhalation associated with vapor intrusion. Receptor Type:Recreator CAS #Chemical Name: Ingestion Concentration (mg/kg) Dermal Concentration (mg/kg) Inhalation Concentration (mg/kg)* Ingestion Carcinogenic Risk Dermal Carcinogenic Risk Inhalation Carcinogenic Risk Calculated Carcinogenic Risk Ingestion Hazard Quotient Dermal Hazard Quotient Inhalation Hazard Quotient Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 0.249 0.249 0.249 2.0E-06 2.7E-08 2.0E-06 7440-36-0 Antimony (metallic)0.482 0.482 0.482 8.6E-03 3.6E-12 8.6E-03 7440-38-2 Arsenic, Inorganic 3.84 3.84 3.84 2.8E-06 3.9E-07 1.4E-14 3.2E-06 5.5E-02 6.5E-03 5.7E-10 6.1E-02 7440-41-7 Beryllium and compounds 0.691 0.691 0.691 1.4E-15 1.4E-15 2.5E-03 7.7E-11 2.5E-03 7440-43-9 Cadmium (Diet)1.69 1.69 1.69 2.5E-15 2.5E-15 1.2E-02 1.1E-03 3.7E-10 1.3E-02 16065-83-1 Chromium(III), Insoluble Salts 20.1 20.1 20.1 9.5E-05 9.5E-05 18540-29-9 Chromium(VI)0.547 0.547 0.547 9.9E-07 1.0E-13 9.9E-07 1.3E-03 1.2E-11 1.3E-03 7440-50-8 Copper 7.84 7.84 7.84 1.4E-03 1.4E-03 7439-89-6 Iron 9350 9350 9350 9.5E-02 9.5E-02 7439-92-1 ~Lead and Compounds 68.5 68.5 68.5 <SL**<SL**<SL** 7439-96-5 Manganese (Non-diet)39.1 39.1 39.1 1.2E-02 1.7E-09 1.2E-02 7439-97-6 ~Mercury (elemental)0.53 0.53 0.53 5.0E-03 5.0E-03 79-20-9 Methyl Acetate 0.0084 0.0084 0.0084 6.0E-08 6.0E-08 78-93-3 Methyl Ethyl Ketone (2-Butanone)0.0657 0.0657 0.0657 7.8E-07 4.5E-08 8.2E-07 75-09-2 Methylene Chloride 0.399 0.399 0.399 2.9E-09 1.4E-11 2.9E-09 4.7E-04 2.3E-06 4.8E-04 7440-02-0 Nickel Soluble Salts 4.83 4.83 4.83 1.0E-15 1.0E-15 1.7E-03 1.2E-10 1.7E-03 109-66-0 Pentane, n-0.0549 0.0549 0.0549 1.9E-07 1.9E-07 12672-29-6 ~Aroclor 1248 0.0293 0.0293 0.0293 4.7E-08 1.8E-08 1.2E-09 6.7E-08 11097-69-1 ~Aroclor 1254 0.0721 0.0721 0.0721 1.2E-07 4.6E-08 1.8E-09 1.6E-07 2.6E-02 8.5E-03 3.4E-02 7782-49-2 Selenium 1.1 1.1 1.1 1.6E-03 1.2E-13 1.6E-03 7440-22-4 Silver 0.354 0.354 0.354 5.0E-04 5.0E-04 7440-28-0 Thallium (Soluble Salts)0.677 0.677 0.677 4.8E-01 4.8E-01 7440-66-6 Zinc and Compounds 67.2 67.2 67.2 1.6E-03 1.6E-03 Cumulative:4.4E-06 7.2E-01 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate cancer risk or hazard quotient. Lead concentrations are compared to the EPA screening level of 400 mg/kg for residential soil. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Direct Contact - Recreator/Trespasser Surface Water Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Resident, Non-Residential, & Recreator Receptor Type:Recreator CAS #Chemical Name: Ingestion Concentration (ug/L) Dermal Concentration (ug/L) Ingestion Carcinogenic Risk Dermal Contact Carcinogenic Risk Calculated Carcinogenic Risk Ingestion Hazard Quotient Dermal Contact Hazard Quotient Calculated Non- Carcinogenic Hazard Quotient 7440-38-2 Arsenic, Inorganic 0.35 0.35 5.9E-07 6.0E-08 6.5E-07 1.0E-02 5.3E-04 1.1E-02 18540-29-9 Chromium(VI)0.0545 0.0545 1.3E-07 7.8E-07 9.1E-07 1.6E-04 6.6E-04 8.2E-04 7440-50-8 Copper 0.47 0.47 1.0E-04 5.3E-06 1.1E-04 106-46-7 Dichlorobenzene, 1,4-2.9 2.9 1.8E-08 1.3E-07 1.5E-07 3.7E-04 1.4E-03 1.8E-03 7439-89-6 Iron 2120 2120 2.7E-02 1.4E-03 2.8E-02 7439-92-1 ~Lead and Compounds 0.17 0.17 7439-96-5 Manganese (Diet)132 132 8.3E-03 8.3E-03 7440-02-0 Nickel Soluble Salts 0.3 0.3 1.3E-04 3.4E-05 1.7E-04 14797-55-8 Nitrate 260 260 1.4E-03 7.4E-05 1.5E-03 7782-49-2 Selenium 0.089 0.089 1.6E-04 8.1E-06 1.7E-04 7440-66-6 Zinc and Compounds 1.6 1.6 4.7E-05 1.5E-06 4.9E-05 Cumulative:1.7E-06 5.2E-02 Output Form 2G North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Resident, Non-Residential, & Recreator CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 49 1.47 -6.5E+03 4.5E-05 71-43-2 Benzene 0.92 0.0276 3.6E-01 6.3E+00 7.7E-08 8.8E-04 75-27-4 Bromodichloromethane 10.8 0.324 7.6E-02 -4.3E-06 75-15-0 Carbon Disulfide 20.6 0.618 -1.5E+02 8.5E-04 108-90-7 Chlorobenzene 2.07 0.0621 -1.0E+01 1.2E-03 67-66-3 Chloroform 243 7.29 1.2E-01 2.0E+01 6.0E-05 7.1E-02 74-87-3 Chloromethane 1.81 0.0543 -1.9E+01 5.8E-04 75-71-8 Dichlorodifluoromethane 239 7.17 -2.1E+01 6.9E-02 156-59-2 Dichloroethylene, 1,2-cis-4.84 0.1452 -- 156-60-5 Dichloroethylene, 1,2-trans-2.03 0.0609 -- 123-91-1 Dioxane, 1,4-2.4 0.072 5.6E-01 6.3E+00 1.3E-07 2.3E-03 100-41-4 Ethylbenzene 1.47 0.0441 1.1E+00 2.1E+02 3.9E-08 4.2E-05 109-99-9 ~Tetrahydrofuran 6.55 0.1965 -4.2E+02 9.4E-05 142-82-5 Heptane, N-1.1 0.033 -8.3E+01 7.9E-05 110-54-3 Hexane, N-29.9 0.897 -1.5E+02 1.2E-03 67-63-0 Isopropanol 34.9 1.047 -4.2E+01 5.0E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone)7.7 0.231 -1.0E+03 4.4E-05 75-09-2 Methylene Chloride 12.3 0.369 1.0E+02 1.3E+02 3.6E-09 5.9E-04 115-07-1 Propylene 3.27 0.0981 -6.3E+02 3.1E-05 100-42-5 Styrene 5.19 0.1557 -2.1E+02 1.5E-04 127-18-4 Tetrachloroethylene 132 3.96 1.1E+01 8.3E+00 3.7E-07 9.5E-02 108-88-3 Toluene 4.52 0.1356 -1.0E+03 2.6E-05 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-5.8 0.174 -1.0E+03 3.3E-05 71-55-6 Trichloroethane, 1,1,1-2.93 0.0879 -1.0E+03 1.7E-05 79-01-6 Trichloroethylene 7.13 0.2139 4.8E-01 4.2E-01 4.5E-07 1.0E-01 75-69-4 Trichlorofluoromethane 142 4.26 -- 95-63-6 Trimethylbenzene, 1,2,4-36.6 1.098 -1.3E+01 1.8E-02 108-67-8 Trimethylbenzene, 1,3,5-7.56 0.2268 -1.3E+01 3.6E-03 1330-20-7 Xylenes 8.77 0.2631 -2.1E+01 2.5E-03 Cumulative:6.5E-05 3.7E-01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Resident, Non-Residential, & Recreator CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 49 0.49 -2.7E+04 3.6E-06 71-43-2 Benzene 0.92 0.0092 1.6E+00 2.6E+01 5.9E-09 7.0E-05 75-27-4 Bromodichloromethane 10.8 0.108 3.3E-01 -3.3E-07 75-15-0 Carbon Disulfide 20.6 0.206 -6.1E+02 6.7E-05 108-90-7 Chlorobenzene 2.07 0.0207 -4.4E+01 9.5E-05 67-66-3 Chloroform 243 2.43 5.3E-01 8.6E+01 4.6E-06 5.7E-03 74-87-3 Chloromethane 1.81 0.0181 -7.9E+01 4.6E-05 75-71-8 Dichlorodifluoromethane 239 2.39 -8.8E+01 5.5E-03 156-59-2 Dichloroethylene, 1,2-cis-4.84 0.0484 -- 156-60-5 Dichloroethylene, 1,2-trans-2.03 0.0203 -- 123-91-1 Dioxane, 1,4-2.4 0.024 2.5E+00 2.6E+01 9.8E-09 1.8E-04 100-41-4 Ethylbenzene 1.47 0.0147 4.9E+00 8.8E+02 3.0E-09 3.4E-06 109-99-9 ~Tetrahydrofuran 6.55 0.0655 -1.8E+03 7.5E-06 142-82-5 Heptane, N-1.1 0.011 -3.5E+02 6.3E-06 110-54-3 Hexane, N-29.9 0.299 -6.1E+02 9.8E-05 67-63-0 Isopropanol 34.9 0.349 -1.8E+02 4.0E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)7.7 0.077 -4.4E+03 3.5E-06 75-09-2 Methylene Chloride 12.3 0.123 1.2E+03 5.3E+02 1.0E-10 4.7E-05 115-07-1 Propylene 3.27 0.0327 -2.6E+03 2.5E-06 100-42-5 Styrene 5.19 0.0519 -8.8E+02 1.2E-05 127-18-4 Tetrachloroethylene 132 1.32 4.7E+01 3.5E+01 2.8E-08 7.5E-03 108-88-3 Toluene 4.52 0.0452 -4.4E+03 2.1E-06 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-5.8 0.058 -4.4E+03 2.6E-06 71-55-6 Trichloroethane, 1,1,1-2.93 0.0293 -4.4E+03 1.3E-06 79-01-6 Trichloroethylene 7.13 0.0713 3.0E+00 1.8E+00 2.4E-08 8.1E-03 75-69-4 Trichlorofluoromethane 142 1.42 -- 95-63-6 Trimethylbenzene, 1,2,4-36.6 0.366 -5.3E+01 1.4E-03 108-67-8 Trimethylbenzene, 1,3,5-7.56 0.0756 -5.3E+01 2.9E-04 1330-20-7 Xylenes 8.77 0.0877 -8.8E+01 2.0E-04 Cumulative:5.0E-06 3.0E-02 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Exposure Unit #1 - Trespasser North Carolina Department of Environmental Quality Risk Calculator Old Richmond County Landfill Rockingham, Richmond County, North Carolina Pre-Regulatory Landfill Unit NONCD0000594 July 2020 May 2020 EPA RSL Table 12/7/2020 Prepared By:ATC Associates of North Carolina, P.C. 2727 E. Millbrook Road, Ste 121, Raleigh, NC 27604 Pre-Regulatory Landfill Unit North Carolina DEQ Risk Calculator Table of Contents Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Trespasser Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Trespasser Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 1 70 80 330 1 250 8 3527 0.3 50 100 19652 2.5 0.71 1 20 350 24 6032 0.07 0.54 1 70 80 2373 0.2 200 6365 0.78 Input Form 1B Exposure Unit ID: Exposure Unit #1 - Trespasser Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: Exposure Unit #1 - Trespasser Default Value Recreator Trespasser Lifetime (LT) (years)70 NA NA Averaging Time (AT) (days/yr)365 NA NA Body Weight (BW) (kg)15 NA NA Exposure Duration 0-2 (ED) (yr)2 NA NA Exposure Duration 2-6 (ED) (yr)4 NA NA Exposure Frequency (EF) (d/yr)195 NA NA Exposure Time (ET) (hr)2 NA NA Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA NA Soil Adherence Factor (AF) (mg/cm2)0.2 NA NA Soil Ingestion Rate (IRS) (mg/day)200 NA NA Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA NA Water Ingestion Rate (IRW) (L/hr)0.124 NA NA Water Exposure Time (ETevent) (hr/event)2 NA NA Water Event Frequency (EV) (events/day)1 NA NA Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 45 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 0 Exposure Frequency (EF) (d/yr)195 90 90 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.2 Soil Ingestion Rate (IRS) (mg/day)100 200 200 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.071 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Contaminant Migration Parameters Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Trespasser Parameter Default Value Site Specific Value Justification Distance to Protection of Groundwater Point of Exposure (POEgw) (feet) 0 0 Distance to Protection of Surface Water Point of Exposure (POEsw) (feet) 0 0 Depth to Base of Affected Soils (ds) (cm)1244 183 ATC used the maximum soil cover depth within the landfill unit (6 feet, 182.88 cm) as the depth of the affected soils. Length of Affected Soil Parallel to Assumed GW Flow Direction (L) (cm) Site-specific value required Areal extent of soil contamination range 0.5-500 (As) (acres) 0.5 4.9 ATC used the entire waste disposal unit as the areal extent of soil contamination Fraction of vegetative cover (V) (unitless)0.5 1.0 The entire waste disposal unit is covered with vegetation. 0.15 (soil to outdoor air pathway) 0.07 This value is based on the average of all laboratory reported moisture content values for soil samples collected at the site. 0.3 (soil to groundwater pathway) 0.3 0.28 (soil to outdoor air pathway) 0.36 This value is based on the total soil porosity minus the water filled soil porosity. 0.13 (soil to groundwater pathway) 0.13 Provide justification for the contaminant migration parameters used. Water Filled Soil Porosity (θw) (unitless) Air Filled Soil Porosity (θa) (unitless) Input Form 1C North Carolina DEQ Risk Calculator Contaminant Migration Parameters Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Trespasser Parameter Default Value Site Specific Value Justification Provide justification for the contaminant migration parameters used. Input Form 1C Total Soil Porosity (n) (unitless)0.43 0.43 Total porosity has not been measured at this site. The soil is predominantly classified as a silty sand. Therefore, ATC used a published value of fine-grained sand (McWorter and Sunada, 1997.) Dry Soil Bulk Density (ρb) (g/cm3)1.5 1.66 Dry bulk density has not been measured at this site. The soil is predominantly classified as a silty sand. Therefore, ATC used a published value sand (US EPA, 2004). Net Infiltration Rate (I) (cm/yr)66 66 0.006 (soil to outdoor air pathway) 0.006 The default value was used as fraction organic carbon has not been measured at the site. 0.002 (soil leaching to groundwater pathway) 0.002 Aquifer Hydraulic Conductivity (K) (cm/d) Site-specific value required Hydraulic Gradient (i) (unitless) Site-specific value required Average Groundwater Temperature (Tgw) (°C)25 25 Aquifer Thickness (da) (cm)Site-specific value required Groundwater Source Thickness (Sd) (cm) Site-specific value required Groundwater Source Width (Sw) (cm) Site-specific value required Fraction Organic Carbon (foc) (unitless) North Carolina DEQ Risk Calculator Contaminant Migration Parameters Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Trespasser Parameter Default Value Site Specific Value Justification Provide justification for the contaminant migration parameters used. Input Form 1C Plume Thickness at GW/SW Discharge (δsw) (cm) Site-specific value required Plume Width at GW/SW Discharge (Wgwsw) (cm) Site-specific value required Surface Water Flowrate at GW/SW Discharge (Qsw) (cm3/d) Site-specific value required North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Trespasser Exposure Point Concentration (mg/kg) Notes:CAS Number Chemical Units 0.249 See Table 1 67-64-1 Acetone mg/kg 0.482 See Table 1 7440-36-0 Antimony (metallic)mg/kg 3.84 See Table 1 7440-38-2 Arsenic, Inorganic mg/kg 0.691 See Table 1 7440-41-7 Beryllium and compounds mg/kg 1.69 See Table 1 7440-43-9 Cadmium (Diet)mg/kg 20.1 See Table 1 16065-83-1 Chromium(III), Insoluble Salts mg/kg 0.547 See Table 1 18540-29-9 Chromium(VI)mg/kg 7.84 See Table 1 7440-50-8 Copper mg/kg 9350 See Table 1 7439-89-6 Iron mg/kg 68.5 See Table 1 7439-92-1 ~Lead and Compounds mg/kg 39.1 See Table 1 7439-96-5 Manganese (Non-diet)mg/kg 0.53 See Table 1 7439-97-6 ~Mercury (elemental)mg/kg 0.0084 See Table 1 79-20-9 Methyl Acetate mg/kg 0.0657 See Table 1 78-93-3 Methyl Ethyl Ketone (2-Butanone)mg/kg 0.399 See Table 1 75-09-2 Methylene Chloride mg/kg 4.83 See Table 1 7440-02-0 Nickel Soluble Salts mg/kg 0.0549 See Table 1 109-66-0 Pentane, n-mg/kg 0.0293 See Table 1 12672-29-6 ~Aroclor 1248 mg/kg 0.0721 See Table 1 11097-69-1 ~Aroclor 1254 mg/kg 1.1 See Table 1 7782-49-2 Selenium mg/kg 0.354 See Table 1 7440-22-4 Silver mg/kg 0.677 See Table 1 7440-28-0 Thallium (Soluble Salts)mg/kg 67.2 See Table 1 7440-66-6 Zinc and Compounds mg/kg Input Form 2A Soil Exposure Point Concentration Table Description of Exposure Point Concentration Selection: Exposure point concentrations are the maximum concentration for each detected compound listed in the risk calculator. North Carolina DEQ Risk Calculator Exposure Point Concentrations Input Form 2C Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Trespasser Surface Water Exposure Point Concentration Table Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/L) Notes:CAS Number Chemical Units 0.35 See Table 3 7440-38-2 Arsenic, Inorganic ug/L 0.0545 See Table 3 18540-29-9 Chromium(VI)ug/L 0.47 See Table 3 7440-50-8 Copper ug/L 2.9 See Table 3 106-46-7 Dichlorobenzene, 1,4-ug/L 2120 See Table 3 7439-89-6 Iron ug/L 0.17 See Table 3 7439-92-1 ~Lead and Compounds ug/L 132 See Table 3 7439-96-5 Manganese (Diet)ug/L 0.3 See Table 3 7440-02-0 Nickel Soluble Salts ug/L 260 See Table 3 14797-55-8 Nitrate ug/L 0.089 See Table 3 7782-49-2 Selenium ug/L 1.6 See Table 3 7440-66-6 Zinc and Compounds ug/L Exposure point concentrations are the maximum concentration for each detected compound listed in the risk calculator. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Trespasser Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil 8.9E-07 1.2E-01 NO Surface Water*3.2E-07 6.2E-03 NO Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Direct Contact - Recreator/Trespasser Soil Output Form 2F Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Trespasser * - Note that inhalation on this calculator refers to outdoor inhalation of volatiles and particulates, not indoor inhalation associated with vapor intrusion. Receptor Type:Trespasser CAS #Chemical Name: Ingestion Concentration (mg/kg) Dermal Concentration (mg/kg) Inhalation Concentration (mg/kg)* Ingestion Carcinogenic Risk Dermal Carcinogenic Risk Inhalation Carcinogenic Risk Calculated Carcinogenic Risk Ingestion Hazard Quotient Dermal Hazard Quotient Inhalation Hazard Quotient Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 0.249 0.249 0.249 3.0E-07 1.3E-08 3.2E-07 7440-36-0 Antimony (metallic)0.482 0.482 0.482 1.3E-03 1.6E-12 1.3E-03 7440-38-2 Arsenic, Inorganic 3.84 3.84 3.84 5.4E-07 1.6E-07 2.4E-15 7.0E-07 8.4E-03 2.5E-03 2.6E-10 1.1E-02 7440-41-7 Beryllium and compounds 0.691 0.691 0.691 2.4E-16 2.4E-16 3.8E-04 3.5E-11 3.8E-04 7440-43-9 Cadmium (Diet)1.69 1.69 1.69 4.4E-16 4.4E-16 1.9E-03 4.5E-04 1.7E-10 2.3E-03 16065-83-1 Chromium(III), Insoluble Salts 20.1 20.1 20.1 1.5E-05 1.5E-05 18540-29-9 Chromium(VI)0.547 0.547 0.547 1.3E-07 2.0E-14 1.3E-07 2.0E-04 5.6E-12 2.0E-04 7440-50-8 Copper 7.84 7.84 7.84 2.1E-04 2.1E-04 7439-89-6 Iron 9350 9350 9350 1.5E-02 1.5E-02 7439-92-1 ~Lead and Compounds 68.5 68.5 68.5 <SL**<SL**<SL** 7439-96-5 Manganese (Non-diet)39.1 39.1 39.1 1.8E-03 8.0E-10 1.8E-03 7439-97-6 ~Mercury (elemental)0.53 0.53 0.53 2.3E-03 2.3E-03 79-20-9 Methyl Acetate 0.0084 0.0084 0.0084 9.2E-09 9.2E-09 78-93-3 Methyl Ethyl Ketone (2-Butanone)0.0657 0.0657 0.0657 1.2E-07 2.1E-08 1.4E-07 75-09-2 Methylene Chloride 0.399 0.399 0.399 3.7E-10 2.7E-12 3.8E-10 7.3E-05 1.0E-06 7.4E-05 7440-02-0 Nickel Soluble Salts 4.83 4.83 4.83 1.8E-16 1.8E-16 2.6E-04 5.5E-11 2.6E-04 109-66-0 Pentane, n-0.0549 0.0549 0.0549 8.6E-08 8.6E-08 12672-29-6 ~Aroclor 1248 0.0293 0.0293 0.0293 9.2E-09 7.7E-09 2.1E-10 1.7E-08 11097-69-1 ~Aroclor 1254 0.0721 0.0721 0.0721 2.3E-08 1.9E-08 3.2E-10 4.2E-08 4.0E-03 3.3E-03 7.3E-03 7782-49-2 Selenium 1.1 1.1 1.1 2.4E-04 5.6E-14 2.4E-04 7440-22-4 Silver 0.354 0.354 0.354 7.8E-05 7.8E-05 7440-28-0 Thallium (Soluble Salts)0.677 0.677 0.677 7.4E-02 7.4E-02 7440-66-6 Zinc and Compounds 67.2 67.2 67.2 2.5E-04 2.5E-04 Cumulative:8.9E-07 1.2E-01 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate cancer risk or hazard quotient. Lead concentrations are compared to the EPA screening level of 400 mg/kg for residential soil. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Direct Contact - Recreator/Trespasser Surface Water Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: NONCD0000594 Exposure Unit ID: Exposure Unit #1 - Trespasser Receptor Type:Trespasser CAS #Chemical Name: Ingestion Concentration (ug/L) Dermal Concentration (ug/L) Ingestion Carcinogenic Risk Dermal Contact Carcinogenic Risk Calculated Carcinogenic Risk Ingestion Hazard Quotient Dermal Contact Hazard Quotient Calculated Non- Carcinogenic Hazard Quotient 7440-38-2 Arsenic, Inorganic 0.35 0.35 5.8E-08 1.6E-08 7.5E-08 9.1E-04 2.5E-04 1.2E-03 18540-29-9 Chromium(VI)0.0545 0.0545 9.1E-09 2.0E-07 2.1E-07 1.4E-05 3.1E-04 3.3E-04 7440-50-8 Copper 0.47 0.47 9.1E-06 2.5E-06 1.2E-05 106-46-7 Dichlorobenzene, 1,4-2.9 2.9 1.7E-09 3.6E-08 3.8E-08 3.2E-05 6.7E-04 7.1E-04 7439-89-6 Iron 2120 2120 2.4E-03 6.5E-04 3.0E-03 7439-92-1 ~Lead and Compounds 0.17 0.17 7439-96-5 Manganese (Diet)132 132 7.3E-04 7.3E-04 7440-02-0 Nickel Soluble Salts 0.3 0.3 1.2E-05 1.6E-05 2.8E-05 14797-55-8 Nitrate 260 260 1.3E-04 3.5E-05 1.6E-04 7782-49-2 Selenium 0.089 0.089 1.4E-05 3.8E-06 1.8E-05 7440-66-6 Zinc and Compounds 1.6 1.6 4.1E-06 6.9E-07 4.8E-06 Cumulative:3.2E-07 6.2E-03 Output Form 2G North Carolina DEQ Risk Calculator APPENDIX B Certification