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7606_WallRecylingCDLF_November2024_14_DayExceedanceNotification_FID1913905_20241118
Orlando, FL • Tampa, FL • Marietta, GA • Hickory, NC • Monroe, NC Statesville, NC • Tullytown, PA • Columbia, SC • Richmond, VA • Olympia, WA Page 1 of 3 5400 Glen Alden Drive Richmond VA 23231 P. 704.283.9765 F. 704.283.9755 www.integrityenvsol.com November 15, 2024 Mr. Ervin Lane, Hydrogeologist Compliance Unit North Carolina Department of Environmental Quality-DWM Solid Waste Section, 1646 Mail Service Center Raleigh, North Carolina 27699-1646 ervin.lane@deq.nc.gov Re: 14-Day Notification of Groundwater Protection Standard Exceedances Second Semi-annual 2024 Groundwater Monitoring Event Wall Recycling C&D Landfill, Permit No. 7606-CDLF-2001 Dear Mr. Lane: Integrity Environmental Solutions, (Integrity) is submitting this 14-day Notification of Groundwater Protection Standards (GPS) Exceedance, on behalf of Wall Recycling, LLC., (Wall) for the Wall Recycling C&D Landfill (Permit No. 7606-CDLF-2001). This notification is being submitted pursuant to the requirements of 15A NCAC 13B.0544(b)(7) of the North Carolina Administrative Code (NCAC) for the second semi-annual 2024 water quality monitoring event conducted by Integrity on September 3, 4, and 5, 2024. The final laboratory data packages (J23756-1 and J25266-1) for this event were dated October 11, 2024, and October 31, 2024 and were received from the laboratory via email on October 11, 2024 and November 1, 2024, respectively. With the construction of Cell 1B-1 beginning in August, prior to the semi-annual sampling event, monitoring wells MW-8, MW-15, MW-16, MW-17, and MW-19 were added to the compliance network that was required to be sampled during the event. Based on our review of the second semi-annual 2024 monitoring event laboratory certificates of analysis, prepared by Eurofins, the following GPS exceedances were identified Mr. Ervin Lane – NCDEQ November 15, 2024 Page 2 of 3 Constituent NC 2L Standard (ug/L) Monitoring Well 2SA 2024 Reported Concentration (ug/L) Cobalt 1 MW-16 4.0 J Iron 300 MW-8 510 MW-15 340 MW-16 450 MW-19 370 Manganese 50 MW-8 360 MW-15 440 MW-16 1300 MW-17 620 Note: ug/L = micrograms per liter J = Analyte concentration was between the laboratory detection limit and laboratory practical quantitation limit. The exceedances listed in this letter are represented by these new sampling locations, as there is no historical data to indicate previous exceedances of these parameters. This monitoring event occurred prior to the placement of waste in the new Cell 1B-1; therefore, these exceedances do not represent a release from the landfill but rather background conditions. The parameters that are exceeding have historically been observed in other monitoring wells within this monitoring system. Further, all reported concentrations at these wells are within historical ranges monitored at background well MW-1. Therefore, Wall will continue to monitor these points of compliance. A report documenting this demonstration will be submitted to the Division no later than 90 days from the date of this notification. ANALYTICAL REPORT PREPARED FOR Attn: Michele Clary Carlson Environmental Consultants 1127 Curtis Street Monroe, North Carolina 28112 Generated 10/11/2024 12:05:55 AM JOB DESCRIPTION 201.11.17/Asheboro C&D Landfill JOB NUMBER 752-23756-1 See page two for job notes and contact information. Cary NC 27511 Suite A 104 Woodwinds Industrial Court Eurofins Raleigh Page 1 of 124 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Eurofins Raleigh Eurofins Raleigh is a laboratory within Eurofins Environment Testing Southeast, LLC, a company within Eurofins Environment Testing Group of Companies Job Notes This report may not be reproduced except in full, and with written approval from the laboratory. The results relate only to the samples tested. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written approval of the laboratory. All questions should be directed to the Eurofins Environment Testing Southeast, LLC Project Manager. Authorization Generated 10/11/2024 12:05:55 AM Authorized for release by Noel Savoie, Project Manager I Noel.Savoie@et.eurofinsus.com (850)254-0107 Page 2 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Table of Contents Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Laboratory Job ID: 752-23756-1 Page 3 of 124 Eurofins Raleigh10/11/2024 Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1 Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3 Definitions/Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4 Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6 Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7 Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .13 Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .47 QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .50 QC Association Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .93 Lab Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .103 Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .110 Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .111 Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .112 Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .113 Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .119 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Definitions/Glossary Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Qualifiers GC/MS VOA Qualifier Description *+LCS and/or LCSD is outside acceptance limits, high biased. Qualifier *1 LCS/LCSD RPD exceeds control limits. B Compound was found in the blank and sample. J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value. HPLC/IC Qualifier Description J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value. Qualifier Metals Qualifier Description B Compound was found in the blank and sample. Qualifier J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value. General Chemistry Qualifier Description F1 MS and/or MSD recovery exceeds control limits. Qualifier HF Parameter with a holding time of 15 minutes. Test performed by laboratory at client's request. Sample was analyzed outside of hold time. J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value. Glossary These commonly used abbreviations may or may not be present in this report. ¤Listed under the "D" column to designate that the result is reported on a dry weight basis Abbreviation %R Percent Recovery CFL Contains Free Liquid CFU Colony Forming Unit CNF Contains No Free Liquid DER Duplicate Error Ratio (normalized absolute difference) Dil Fac Dilution Factor DL Detection Limit (DoD/DOE) DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample DLC Decision Level Concentration (Radiochemistry) EDL Estimated Detection Limit (Dioxin) LOD Limit of Detection (DoD/DOE) LOQ Limit of Quantitation (DoD/DOE) MCL EPA recommended "Maximum Contaminant Level" MDA Minimum Detectable Activity (Radiochemistry) MDC Minimum Detectable Concentration (Radiochemistry) MDL Method Detection Limit ML Minimum Level (Dioxin) MPN Most Probable Number MQL Method Quantitation Limit NC Not Calculated ND Not Detected at the reporting limit (or MDL or EDL if shown) NEG Negative / Absent POS Positive / Present PQL Practical Quantitation Limit PRES Presumptive QC Quality Control RER Relative Error Ratio (Radiochemistry) RL Reporting Limit or Requested Limit (Radiochemistry) RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin) TEQ Toxicity Equivalent Quotient (Dioxin) Eurofins Raleigh Page 4 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Definitions/Glossary Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Glossary (Continued) These commonly used abbreviations may or may not be present in this report. TNTC Too Numerous To Count Abbreviation Eurofins Raleigh Page 5 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Job Narrative752-23756-1 Analytical test results meet all requirements of the associated regulatory program listed on the Accreditation/Certification SummaryPageunlessotherwisenotedundertheindividualanalysis.Data qualifiers and/or narrative comments are included to explain any exceptions,if applicable. Matrix QC may not be reported if insufficient sample is provided or site-specific QC samples were not submitted.In these situations,to demonstrate precision and accuracy at a batch level,a LCS/LCSD may be performed,unless otherwise specified in the method.Surrogate and/or isotope dilution analyte recoveries (if applicable)which are outside of the QC window are confirmed unless attributed to a dilution or otherwise noted in the narrative. Regulated compliance samples (e.g.SDWA,NPDES)must comply with the associated agency requirements/permits. Receipt The samples were received on 9/4/2024 11:00 AM,9/5/2024 11:00 AM and 9/6/2024 9:30 AM.Unless otherwise noted below,the samples arrived in good condition,and,where required,properly preserved and on ice.The temperatures of the 5 coolers at receipt time were 2.7°C,2.7°C,3.1°C,3.2°C and 3.7°C. GC/MS VOA Method 8260D:The preservative used in the sample containers provided is not compatible with one of the Method 8260 analytes requested.The following sample was received preserved with hydrochloric acid :MW-19 (752-23756-1).The requested target analyte list includes 2-Chloroethyl vinyl ether,Acrolein and/or Acrylonitrile,acid-labile compounds that degrades in an acidic medium. Method 8260D:The CCV for analytical batch 752-8685 recovered outside control limits for the following analyte(s):2-Hexanone,Acrolein,Isobutyl alcohol and Vinyl acetate .These compounds have been identified as a poor performing analytes when analyzed using this method;therefore,re-extraction/re-analysis was not performed.These results have been reported and qualified.(CCVIS 752-8685/1005) Method 8260D:The %RPD of the laboratory control sample/laboratory control sample duplicate (LCS/LCSD)for analytical batch 752-8685 recovered outside control limits for the following analytes:1,2-Dichlorobenzene and Bromomethane.(LCS 752-8685/5) and (LCSD 752-8685/6) No additional analytical or quality issues were noted,other than those described above or in the Definitions/Glossary page. HPLC/IC No additional analytical or quality issues were noted,other than those described above or in the Definitions/Glossary page. Metals Method 6010:The method blank associated with prep batch 680-854930 and analytical batch 680-855104 contained a hit for Potassium above the method detection limit (MDL)but below the reporting limit (RL).Associated data with hits have been flagged with a B qualifier. No additional analytical or quality issues were noted,other than those described above or in the Definitions/Glossary page. General Chemistry Method SM4500_NO3_F:The matrix spike/matrix spike duplicate (MS/MSD)recoveries for analytical batch 752-8634 were outside advisory control limits for Nitrate-Nitrite.Sample matrix interference and/or non-homogeneity are suspected because the associated laboratory control sample (LCS)recovery is within acceptance limits. Method SM4500_NO2_F:The matrix spike/matrix spike duplicate (MS/MSD)recoveries for analytical batch 752-8670 were outside advisory control limits for Nitrite.Sample matrix interference and/or non-homogeneity are suspected because the associated laboratory control sample (LCS)recovery is within acceptance limits. No additional analytical or quality issues were noted,other than those described above or in the Definitions/Glossary page. Case Narrative Client: Carlson Environmental Consultants Job ID: 752-23756-1 Project: 201.11.17/Asheboro C&D Landfill Eurofins Raleigh Job ID: 752-23756-1 Eurofins Raleigh Page 6 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Detection Summary Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Client Sample ID: MW-19 Lab Sample ID: 752-23756-1 Chloride RL 0.50 mg/L MDL 0.20 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Total/NA12.8 300.0-1993 R2.1 Sulfate 1.0 mg/L0.40 Total/NA11.4 300.0-1993 R2.1 Hardness as calcium carbonate 3.3 mg/L3.3 Total/NA1432340B-2011 Barium 10 ug/L4.4 Total Recoverable 112 6010D Chromium 10 ug/L1.1 Total Recoverable 11.3 J B 6010D Fe 100 ug/L20 Total Recoverable 1370 6010D Manganese 10 ug/L1.3 Total Recoverable 120 6010D Potassium 1000 ug/L67 Total Recoverable 1270J 6010D Vanadium 10 ug/L1.0 Total Recoverable 11.3 J 6010D Alkalinity as CaCO3 to pH 4.5 5.5 mg/L2.2 Total/NA1812320B-2011 Nitrate as N 0.10 mg/L0.025 Total/NA10.11 Nitrate by calc Total Dissolved Solids 50 mg/L50 Total/NA1130SM 2540C Ferric Iron 0.10 mg/L0.10 Total/NA10.34 SM 3500 Ferrous Iron 0.10 mg/L0.025 Total/NA10.026 J HF SM 3500 FE D Nitrate Nitrite as N 0.10 mg/L0.041 Total/NA10.11 F1 SM 4500 NO3 F Client Sample ID: MW-4 Lab Sample ID: 752-23805-1 Chloromethane RL 1.0 ug/L MDL 0.13 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Total/NA1J0.58 8260D Chloride 0.50 mg/L0.20 Total/NA14.2 300.0-1993 R2.1 Barium 10 ug/L4.4 Total Recoverable 19.6 J 6010D Chromium 10 ug/L1.1 Total Recoverable 12.9 J 6010D Fe 100 ug/L20 Total Recoverable 1150 6010D Manganese 10 ug/L1.3 Total Recoverable 18.9 J 6010D Potassium 1000 ug/L67 Total Recoverable 1300J B 6010D Vanadium 10 ug/L1.0 Total Recoverable 11.4 J 6010D Alkalinity as CaCO3 to pH 4.5 5.5 mg/L2.2 Total/NA1272320B-2011 Ferric Iron 0.10 mg/L0.10 Total/NA10.15 SM 3500 Client Sample ID: MW-10A Lab Sample ID: 752-23805-2 Chloride RL 0.50 mg/L MDL 0.20 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Total/NA11.4 300.0-1993 R2.1 Sulfate 1.0 mg/L0.40 Total/NA12.3 300.0-1993 R2.1 Barium 10 ug/L4.4 Total Recoverable 113 6010D Cadmium 5.0 ug/L0.44 Total Recoverable 11.4 J 6010D Copper 20 ug/L3.2 Total Recoverable 15.0 J 6010D Fe 100 ug/L20 Total Recoverable 1410 6010D Eurofins Raleigh This Detection Summary does not include radiochemical test results. Page 7 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Detection Summary Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Client Sample ID: MW-10A (Continued)Lab Sample ID: 752-23805-2 Manganese RL 10 ug/L MDL 1.3 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Total Recoverable 149 6010D Potassium 1000 ug/L67 Total Recoverable 11000B 6010D Vanadium 10 ug/L1.0 Total Recoverable 11.0 J 6010D Zinc 20 ug/L8.7 Total Recoverable 115J 6010D Alkalinity as CaCO3 to pH 4.5 5.5 mg/L2.2 Total/NA14.8 J 2320B-2011 Sulfide 0.81 mg/L0.81 Total/NA11.4 4500 S2 F-2011 Ferric Iron 0.10 mg/L0.10 Total/NA10.41 SM 3500 Client Sample ID: MW-18 Lab Sample ID: 752-23805-3 1,4-Dioxane RL 0.50 ug/L MDL 0.32 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Total/NA10.87 8260D SIM 14D Chloride 2.5 mg/L1.0 Total/NA512300.0-1993 R2.1 Sulfate 5.0 mg/L2.0 Total/NA55.5 300.0-1993 R2.1 Barium 10 ug/L4.4 Total Recoverable 140 6010D Cobalt 10 ug/L1.4 Total Recoverable 15.3 J 6010D Fe 100 ug/L20 Total Recoverable 11300 6010D Manganese 10 ug/L1.3 Total Recoverable 11600 6010D Potassium 1000 ug/L67 Total Recoverable 13100B 6010D Vanadium 10 ug/L1.0 Total Recoverable 12.0 J 6010D Alkalinity as CaCO3 to pH 4.5 5.5 mg/L2.2 Total/NA1632320B-2011 Sulfide 0.81 mg/L0.81 Total/NA11.8 4500 S2 F-2011 Total Dissolved Solids 50 mg/L50 Total/NA1120SM 2540C Ferric Iron 0.10 mg/L0.10 Total/NA10.34 SM 3500 Ferrous Iron 0.10 mg/L0.025 Total/NA10.96 HF SM 3500 FE D Client Sample ID: SW-2 Lab Sample ID: 752-23805-4 Chloride RL 0.50 mg/L MDL 0.20 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Total/NA111300.0-1993 R2.1 Sulfate 1.0 mg/L0.40 Total/NA17.9 300.0-1993 R2.1 Hardness as calcium carbonate 3.3 mg/L3.3 Total/NA1472340B-2011 Barium 10 ug/L4.4 Total Recoverable 130 6010D Copper 20 ug/L3.2 Total Recoverable 14.2 J 6010D Fe 100 ug/L20 Total Recoverable 1620 6010D Manganese 10 ug/L1.3 Total Recoverable 164 6010D Potassium 1000 ug/L67 Total Recoverable 13600B 6010D Vanadium 10 ug/L1.0 Total Recoverable 12.1 J 6010D Zinc 20 ug/L8.7 Total Recoverable 110J 6010D Eurofins Raleigh This Detection Summary does not include radiochemical test results. Page 8 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Detection Summary Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Client Sample ID: SW-2 (Continued)Lab Sample ID: 752-23805-4 Alkalinity as CaCO3 to pH 4.5 RL 5.5 mg/L MDL 2.2 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Total/NA1532320B-2011 Sulfide 0.83 mg/L0.83 Total/NA11.7 4500 S2 F-2011 Nitrate as N 0.10 mg/L0.025 Total/NA10.13 Nitrate by calc Total Dissolved Solids 50 mg/L50 Total/NA180SM 2540C Ferric Iron 0.10 mg/L0.10 Total/NA10.58 SM 3500 Ferrous Iron 0.10 mg/L0.025 Total/NA10.039 J HF SM 3500 FE D Nitrate Nitrite as N 0.10 mg/L0.041 Total/NA10.13 SM 4500 NO3 F Client Sample ID: SW-3 Lab Sample ID: 752-23805-5 Chloride RL 0.50 mg/L MDL 0.20 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Total/NA112300.0-1993 R2.1 Sulfate 1.0 mg/L0.40 Total/NA18.5 300.0-1993 R2.1 Hardness as calcium carbonate 3.3 mg/L3.3 Total/NA11102340B-2011 Barium 10 ug/L4.4 Total Recoverable 135 6010D Fe 100 ug/L20 Total Recoverable 1560 6010D Manganese 10 ug/L1.3 Total Recoverable 191 6010D Potassium 1000 ug/L67 Total Recoverable 110000B 6010D Vanadium 10 ug/L1.0 Total Recoverable 12.6 J 6010D Alkalinity as CaCO3 to pH 4.5 5.5 mg/L2.2 Total/NA11102320B-2011 Sulfide 0.83 mg/L0.83 Total/NA11.5 4500 S2 F-2011 Total Dissolved Solids 50 mg/L50 Total/NA1150SM 2540C Ferric Iron 0.10 mg/L0.10 Total/NA10.53 SM 3500 Ferrous Iron 0.10 mg/L0.025 Total/NA10.033 J HF SM 3500 FE D Client Sample ID: Equipment Blank Lab Sample ID: 752-23805-6 Chloroform RL 1.0 ug/L MDL 0.18 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Total/NA1J0.23 8260D Chloride 0.50 mg/L0.20 Total/NA10.60 300.0-1993 R2.1 Sulfate 1.0 mg/L0.40 Total/NA10.43 J 300.0-1993 R2.1 Client Sample ID: MW-8 Lab Sample ID: 752-23805-7 1,4-Dioxane RL 0.50 ug/L MDL 0.32 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Total/NA10.66 8260D SIM 14D Chloride 0.50 mg/L0.20 Total/NA15.6 300.0-1993 R2.1 Sulfate 1.0 mg/L0.40 Total/NA14.4 300.0-1993 R2.1 Barium 10 ug/L4.4 Total Recoverable 121 6010D Fe 100 ug/L20 Total Recoverable 1510 6010D Manganese 10 ug/L1.3 Total Recoverable 1360 6010D Potassium 1000 ug/L67 Total Recoverable 1510J B 6010D Vanadium 10 ug/L1.0 Total Recoverable 11.3 J 6010D Alkalinity as CaCO3 to pH 4.5 5.5 mg/L2.2 Total/NA1452320B-2011 Total Dissolved Solids 50 mg/L50 Total/NA162SM 2540C Eurofins Raleigh This Detection Summary does not include radiochemical test results. Page 9 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Detection Summary Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Client Sample ID: MW-8 (Continued)Lab Sample ID: 752-23805-7 Ferric Iron RL 0.10 mg/L MDL 0.10 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Total/NA10.45 SM 3500 Ferrous Iron 0.10 mg/L0.025 Total/NA10.062 J HF SM 3500 FE D Client Sample ID: MW-15 Lab Sample ID: 752-23805-8 Chloride RL 0.50 mg/L MDL 0.20 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Total/NA16.9 300.0-1993 R2.1 Sulfate 1.0 mg/L0.40 Total/NA15.5 300.0-1993 R2.1 Barium 10 ug/L4.4 Total Recoverable 121 6010D Copper 20 ug/L3.2 Total Recoverable 13.2 J 6010D Fe 100 ug/L20 Total Recoverable 1340 6010D Manganese 10 ug/L1.3 Total Recoverable 1440 6010D Potassium 1000 ug/L67 Total Recoverable 11500B 6010D Vanadium 10 ug/L1.0 Total Recoverable 11.1 J 6010D Alkalinity as CaCO3 to pH 4.5 5.5 mg/L2.2 Total/NA1752320B-2011 Total Dissolved Solids 50 mg/L50 Total/NA1100SM 2540C Ferric Iron 0.10 mg/L0.10 Total/NA10.34 SM 3500 Client Sample ID: MW-16 Lab Sample ID: 752-23805-9 Chloride RL 0.50 mg/L MDL 0.20 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Total/NA116300.0-1993 R2.1 Sulfate 1.0 mg/L0.40 Total/NA111300.0-1993 R2.1 Barium 10 ug/L4.4 Total Recoverable 167 6010D Cobalt 10 ug/L1.4 Total Recoverable 14.0 J 6010D Copper 20 ug/L3.2 Total Recoverable 13.2 J 6010D Fe 100 ug/L20 Total Recoverable 1450 6010D Manganese 10 ug/L1.3 Total Recoverable 11300 6010D Potassium 1000 ug/L67 Total Recoverable 14100B 6010D Vanadium 10 ug/L1.0 Total Recoverable 11.1 J 6010D Zinc 20 ug/L8.7 Total Recoverable 112J 6010D Alkalinity as CaCO3 to pH 4.5 5.5 mg/L2.2 Total/NA1702320B-2011 Sulfide 0.83 mg/L0.83 Total/NA11.1 4500 S2 F-2011 Nitrate as N 0.10 mg/L0.025 Total/NA17.8 Nitrate by calc Total Dissolved Solids 50 mg/L50 Total/NA1180SM 2540C Ferric Iron 0.10 mg/L0.10 Total/NA10.40 SM 3500 Ferrous Iron 0.10 mg/L0.025 Total/NA10.052 J HF SM 3500 FE D Nitrate Nitrite as N 1.0 mg/L0.41 Total/NA107.8 SM 4500 NO3 F Eurofins Raleigh This Detection Summary does not include radiochemical test results. Page 10 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Detection Summary Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Client Sample ID: SW-1 Lab Sample ID: 752-23805-10 1,4-Dioxane RL 0.50 ug/L MDL 0.32 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Total/NA17.3 8260D SIM 14D Toluene 1.0 ug/L0.14 Total/NA10.33 J 8260D Chloride 0.50 mg/L0.20 Total/NA141300.0-1993 R2.1 Sulfate 1.0 mg/L0.40 Total/NA19.0 300.0-1993 R2.1 Hardness as calcium carbonate 3.3 mg/L3.3 Total/NA1762340B-2011 Barium 10 ug/L4.4 Total Recoverable 169 6010D Cobalt 10 ug/L1.4 Total Recoverable 126 6010D Fe 100 ug/L20 Total Recoverable 14900 6010D Manganese 10 ug/L1.3 Total Recoverable 14500 6010D Potassium 1000 ug/L67 Total Recoverable 12800B 6010D Zinc 20 ug/L8.7 Total Recoverable 121 6010D Alkalinity as CaCO3 to pH 4.5 5.5 mg/L2.2 Total/NA1832320B-2011 Total Dissolved Solids 50 mg/L50 Total/NA1170SM 2540C Ferric Iron 0.10 mg/L0.10 Total/NA14.8 SM 3500 Ferrous Iron 0.10 mg/L0.025 Total/NA10.058 J HF SM 3500 FE D Client Sample ID: MW-17 Lab Sample ID: 752-23869-1 Chloride RL 0.50 mg/L MDL 0.20 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Total/NA117300.0-1993 R2.1 Sulfate 1.0 mg/L0.40 Total/NA18.7 300.0-1993 R2.1 Hardness as calcium carbonate 3.3 mg/L3.3 Total/NA1582340B-2011 Barium 10 ug/L4.4 Total Recoverable 132 6010D Fe 100 ug/L20 Total Recoverable 167J 6010D Manganese 10 ug/L1.3 Total Recoverable 1620 6010D Potassium 1000 ug/L67 Total Recoverable 11200B 6010D Alkalinity as CaCO3 to pH 4.5 5.5 mg/L2.2 Total/NA1542320B-2011 Sulfide 0.81 mg/L0.81 Total/NA10.90 4500 S2 F-2011 Nitrate as N 0.10 mg/L0.025 Total/NA17.1 Nitrate by calc Total Dissolved Solids 50 mg/L50 Total/NA1180SM 2540C Nitrate Nitrite as N 0.50 mg/L0.21 Total/NA57.1 SM 4500 NO3 F Client Sample ID: MW-1 Lab Sample ID: 752-23869-2 Barium RL 10 ug/L MDL 4.4 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Total Recoverable 152 6010D Beryllium 4.0 ug/L0.30 Total Recoverable 10.35 J 6010D Cadmium 5.0 ug/L0.44 Total Recoverable 10.52 J 6010D Chromium 10 ug/L1.1 Total Recoverable 18.2 J 6010D Cobalt 10 ug/L1.4 Total Recoverable 110 6010D Eurofins Raleigh This Detection Summary does not include radiochemical test results. Page 11 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Detection Summary Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Client Sample ID: MW-1 (Continued)Lab Sample ID: 752-23869-2 Copper RL 20 ug/L MDL 3.2 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Total Recoverable 139 6010D Fe 100 ug/L20 Total Recoverable 111000 6010D Lead 10 ug/L6.6 Total Recoverable 110 6010D Manganese 10 ug/L1.3 Total Recoverable 1350 6010D Nickel 40 ug/L3.3 Total Recoverable 114J 6010D Potassium 1000 ug/L67 Total Recoverable 1880J B 6010D Vanadium 10 ug/L1.0 Total Recoverable 120 6010D Zinc 20 ug/L8.7 Total Recoverable 1130 6010D Total Dissolved Solids 50 mg/L50 Total/NA1200SM 2540C Ferric Iron 0.10 mg/L0.10 Total/NA111SM 3500 Client Sample ID: Trip Blank Lab Sample ID: 752-23869-3 Chloroform RL 1.0 ug/L MDL 0.18 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Total/NA1J B0.20 8260D Eurofins Raleigh This Detection Summary does not include radiochemical test results. Page 12 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23756-1Client Sample ID: MW-19 Matrix: WaterDate Collected: 09/03/24 14:53 Date Received: 09/04/24 11:00 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) RL MDL <0.32 0.50 0.32 ug/L 09/06/24 10:30 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,4-Dioxane 4-Bromofluorobenzene (Surr)93 46-154 09/06/24 10:30 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Method: SW846 8260D - Volatile Organic Compounds by GC/MS RL MDL <0.17 1.0 0.17 ug/L 09/10/24 20:08 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,1,1,2-Tetrachloroethane 1.0 0.12 ug/L 09/10/24 20:08 1<0.121,1,1-Trichloroethane 1.0 0.28 ug/L 09/10/24 20:08 1<0.281,1,2,2-Tetrachloroethane 1.0 0.14 ug/L 09/10/24 20:08 1<0.141,1,2-Trichloroethane 1.0 0.13 ug/L 09/10/24 20:08 1<0.131,1-Dichloroethane 1.0 0.21 ug/L 09/10/24 20:08 1<0.211,1-Dichloroethene 1.0 0.15 ug/L 09/10/24 20:08 1<0.151,1-Dichloropropene 1.0 0.49 ug/L 09/10/24 20:08 1<0.491,2,3-Trichloropropane 1.0 0.14 ug/L 09/10/24 20:08 1<0.141,2,4-Trichlorobenzene 1.0 0.48 ug/L 09/10/24 20:08 1<0.481,2-Dibromo-3-Chloropropane 1.0 0.66 ug/L 09/10/24 20:08 1<0.661,2-Dibromoethane 1.0 0.19 ug/L 09/10/24 20:08 1<0.19 *11,2-Dichlorobenzene 1.0 0.21 ug/L 09/10/24 20:08 1<0.211,2-Dichloroethane 1.0 0.10 ug/L 09/10/24 20:08 1<0.101,2-Dichloropropane 1.0 0.15 ug/L 09/10/24 20:08 1<0.151,3-Dichlorobenzene 1.0 0.16 ug/L 09/10/24 20:08 1<0.161,3-Dichloropropane 1.0 0.19 ug/L 09/10/24 20:08 1<0.191,4-Dichlorobenzene 1.0 0.28 ug/L 09/10/24 20:08 1<0.282,2-Dichloropropane 20 10 ug/L 09/10/24 20:08 1<102-Butanone (MEK) 5.0 0.88 ug/L 09/10/24 20:08 1<0.882-Hexanone 1.0 0.11 ug/L 09/10/24 20:08 1<0.113-Chloropropene 5.0 1.1 ug/L 09/10/24 20:08 1<1.14-Methyl-2-pentanone (MIBK) 20 10 ug/L 09/10/24 20:08 1<10Acetone 10 5.0 ug/L 09/10/24 20:08 1<5.0Acetonitrile 10 4.0 ug/L 09/10/24 20:08 1<4.0Acrolein 10 3.5 ug/L 09/10/24 20:08 1<3.5Acrylonitrile 1.0 0.15 ug/L 09/10/24 20:08 1<0.15Benzene 1.0 0.48 ug/L 09/10/24 20:08 1<0.48Bromochloromethane 1.0 0.17 ug/L 09/10/24 20:08 1<0.17Bromodichloromethane 1.0 0.22 ug/L 09/10/24 20:08 1<0.22Bromoform 1.0 0.14 ug/L 09/10/24 20:08 1<0.14 *1Bromomethane 5.0 1.5 ug/L 09/10/24 20:08 1<1.5Carbon disulfide 1.0 0.17 ug/L 09/10/24 20:08 1<0.17Carbon tetrachloride 1.0 0.17 ug/L 09/10/24 20:08 1<0.17Chlorobenzene 1.0 0.23 ug/L 09/10/24 20:08 1<0.23Chloroethane 1.0 0.18 ug/L 09/10/24 20:08 1<0.18Chloroform 1.0 0.13 ug/L 09/10/24 20:08 1<0.13Chloromethane 1.0 0.64 ug/L 09/10/24 20:08 1<0.64Chloroprene 1.0 0.15 ug/L 09/10/24 20:08 1<0.15cis-1,2-Dichloroethene 1.0 0.20 ug/L 09/10/24 20:08 1<0.20cis-1,3-Dichloropropene 1.0 0.17 ug/L 09/10/24 20:08 1<0.17Dibromochloromethane 1.0 0.27 ug/L 09/10/24 20:08 1<0.27Dibromomethane 1.0 0.20 ug/L 09/10/24 20:08 1<0.20Dichlorodifluoromethane Eurofins Raleigh Page 13 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23756-1Client Sample ID: MW-19 Matrix: WaterDate Collected: 09/03/24 14:53 Date Received: 09/04/24 11:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) RL MDL <0.38 1.0 0.38 ug/L 09/10/24 20:08 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Ethyl methacrylate 1.0 0.13 ug/L 09/10/24 20:08 1<0.13Ethylbenzene 1.0 0.22 ug/L 09/10/24 20:08 1<0.22Hexachlorobutadiene 5.0 1.7 ug/L 09/10/24 20:08 1<1.7Iodomethane 50 11 ug/L 09/10/24 20:08 1<11Isobutyl alcohol 10 4.9 ug/L 09/10/24 20:08 1<4.9Methacrylonitrile 1.0 0.51 ug/L 09/10/24 20:08 1<0.51Methyl methacrylate 1.0 0.23 ug/L 09/10/24 20:08 1<0.23Methylene Chloride 1.0 0.11 ug/L 09/10/24 20:08 1<0.11Naphthalene 10 5.0 ug/L 09/10/24 20:08 1<5.0Propionitrile 1.0 0.11 ug/L 09/10/24 20:08 1<0.11Styrene 1.0 0.17 ug/L 09/10/24 20:08 1<0.17Tetrachloroethene 1.0 0.53 ug/L 09/10/24 20:08 1<0.53Tetrahydrofuran 1.0 0.14 ug/L 09/10/24 20:08 1<0.14Toluene 1.0 0.21 ug/L 09/10/24 20:08 1<0.21trans-1,2-Dichloroethene 1.0 0.15 ug/L 09/10/24 20:08 1<0.15trans-1,3-Dichloropropene 1.0 0.70 ug/L 09/10/24 20:08 1<0.70trans-1,4-Dichloro-2-butene 1.0 0.15 ug/L 09/10/24 20:08 1<0.15Trichloroethene 1.0 0.24 ug/L 09/10/24 20:08 1<0.24Trichlorofluoromethane 5.0 0.95 ug/L 09/10/24 20:08 1<0.95Vinyl acetate 1.0 0.32 ug/L 09/10/24 20:08 1<0.32Vinyl chloride 3.0 0.45 ug/L 09/10/24 20:08 1<0.45Xylenes, Total 4-Bromofluorobenzene (Surr)76 53-136 09/10/24 20:08 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Dibromofluoromethane (Surr)100 09/10/24 20:08 167-129 Toluene-d8 (Surr)86 09/10/24 20:08 159-134 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography RL MDL 2.8 0.50 0.20 mg/L 09/11/24 16:12 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Chloride 1.0 0.40 mg/L 09/11/24 16:12 11.4Sulfate Method: SM 2340B-2011 - Total Hardness (as CaCO3) by calculation RL MDL 43 3.3 3.3 mg/L 09/11/24 11:32 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Hardness as calcium carbonate Method: SW846 6010D - Metals (ICP) - Total Recoverable RL MDL <6.4 20 6.4 ug/L 09/06/24 06:29 09/06/24 12:24 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Arsenic 10 4.4 ug/L 09/06/24 06:29 09/06/24 12:24 112Barium 4.0 0.30 ug/L 09/06/24 06:29 09/06/24 12:24 1<0.30Beryllium 5.0 0.44 ug/L 09/06/24 06:29 09/06/24 12:24 1<0.44Cadmium 10 1.1 ug/L 09/06/24 06:29 09/06/24 12:24 11.3 J BChromium 10 1.4 ug/L 09/06/24 06:29 09/06/24 12:24 1<1.4Cobalt 20 3.2 ug/L 09/06/24 06:29 09/06/24 12:24 1<3.2Copper 100 20 ug/L 09/06/24 06:29 09/06/24 12:24 1370Fe 10 6.6 ug/L 09/06/24 06:29 09/06/24 12:24 1<6.6Lead 10 1.3 ug/L 09/06/24 06:29 09/06/24 12:24 120Manganese 40 3.3 ug/L 09/06/24 06:29 09/06/24 12:24 1<3.3Nickel Eurofins Raleigh Page 14 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23756-1Client Sample ID: MW-19 Matrix: WaterDate Collected: 09/03/24 14:53 Date Received: 09/04/24 11:00 Method: SW846 6010D - Metals (ICP) - Total Recoverable (Continued) RL MDL 270 J 1000 67 ug/L 09/06/24 06:29 09/06/24 12:24 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Potassium 10 1.5 ug/L 09/06/24 06:29 09/06/24 12:24 1<1.5Silver 50 11 ug/L 09/06/24 06:29 09/06/24 12:24 1<11Tin 10 1.0 ug/L 09/06/24 06:29 09/06/24 12:24 11.3 JVanadium 20 8.7 ug/L 09/06/24 06:29 09/06/24 12:24 1<8.7Zinc Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable RL MDL <0.34 5.0 0.34 ug/L 09/06/24 06:29 09/09/24 17:46 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Antimony 2.5 0.99 ug/L 09/06/24 06:29 09/09/24 17:46 1<0.99Selenium 1.0 0.26 ug/L 09/06/24 06:29 09/09/24 17:46 1<0.26Thallium Method: SW846 7470A - Mercury (CVAA) RL MDL <0.080 0.20 0.080 ug/L 09/06/24 13:21 09/08/24 12:42 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Mercury General Chemistry RL MDL 81 5.5 2.2 mg/L 09/06/24 12:50 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Alkalinity as CaCO3 to pH 4.5 (SM 2320B-2011) 0.83 0.83 mg/L 09/06/24 14:16 1<0.83Sulfide (SM 4500 S2 F-2011) 0.10 0.025 mg/L 09/09/24 12:58 10.11Nitrate as N (SM Nitrate by calc) 50 50 mg/L 09/06/24 16:28 1130 0.10 0.10 mg/L 09/16/24 10:19 10.34Ferric Iron (SM 3500) 0.10 0.025 mg/L 09/07/24 10:44 10.026 J HFFerrous Iron (SM 3500 FE D) 0.10 0.041 mg/L 09/05/24 13:06 10.11 F1Nitrate Nitrite as N (SM 4500 NO3 F) 0.10 0.017 mg/L 09/04/24 15:41 1<0.017Nitrite as N (SM4500 NO2 F) Lab Sample ID: 752-23805-1Client Sample ID: MW-4 Matrix: GWDate Collected: 09/04/24 15:36 Date Received: 09/05/24 11:00 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) RL MDL <0.32 0.50 0.32 ug/L 09/07/24 11:58 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,4-Dioxane 4-Bromofluorobenzene (Surr)87 46-154 09/07/24 11:58 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Method: SW846 8260D - Volatile Organic Compounds by GC/MS RL MDL <0.17 1.0 0.17 ug/L 09/12/24 03:19 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,1,1,2-Tetrachloroethane 1.0 0.12 ug/L 09/12/24 03:19 1<0.121,1,1-Trichloroethane 1.0 0.28 ug/L 09/12/24 03:19 1<0.281,1,2,2-Tetrachloroethane 1.0 0.14 ug/L 09/12/24 03:19 1<0.141,1,2-Trichloroethane 1.0 0.13 ug/L 09/12/24 03:19 1<0.131,1-Dichloroethane 1.0 0.21 ug/L 09/12/24 03:19 1<0.211,1-Dichloroethene 1.0 0.15 ug/L 09/12/24 03:19 1<0.151,1-Dichloropropene 1.0 0.49 ug/L 09/12/24 03:19 1<0.491,2,3-Trichloropropane 1.0 0.14 ug/L 09/12/24 03:19 1<0.141,2,4-Trichlorobenzene 1.0 0.48 ug/L 09/12/24 03:19 1<0.481,2-Dibromo-3-Chloropropane Eurofins Raleigh Page 15 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-1Client Sample ID: MW-4 Matrix: GWDate Collected: 09/04/24 15:36 Date Received: 09/05/24 11:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) RL MDL <0.66 1.0 0.66 ug/L 09/12/24 03:19 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,2-Dibromoethane 1.0 0.19 ug/L 09/12/24 03:19 1<0.191,2-Dichlorobenzene 1.0 0.21 ug/L 09/12/24 03:19 1<0.211,2-Dichloroethane 1.0 0.10 ug/L 09/12/24 03:19 1<0.101,2-Dichloropropane 1.0 0.15 ug/L 09/12/24 03:19 1<0.151,3-Dichlorobenzene 1.0 0.16 ug/L 09/12/24 03:19 1<0.161,3-Dichloropropane 1.0 0.19 ug/L 09/12/24 03:19 1<0.191,4-Dichlorobenzene 1.0 0.28 ug/L 09/12/24 03:19 1<0.282,2-Dichloropropane 20 10 ug/L 09/12/24 03:19 1<102-Butanone (MEK) 5.0 0.88 ug/L 09/12/24 03:19 1<0.882-Hexanone 1.0 0.11 ug/L 09/12/24 03:19 1<0.113-Chloropropene 5.0 1.1 ug/L 09/12/24 03:19 1<1.14-Methyl-2-pentanone (MIBK) 20 10 ug/L 09/12/24 03:19 1<10Acetone 10 5.0 ug/L 09/12/24 03:19 1<5.0 *1Acetonitrile 10 4.0 ug/L 09/12/24 03:19 1<4.0Acrolein 10 3.5 ug/L 09/12/24 03:19 1<3.5Acrylonitrile 1.0 0.15 ug/L 09/12/24 03:19 1<0.15Benzene 1.0 0.48 ug/L 09/12/24 03:19 1<0.48Bromochloromethane 1.0 0.17 ug/L 09/12/24 03:19 1<0.17Bromodichloromethane 1.0 0.22 ug/L 09/12/24 03:19 1<0.22Bromoform 1.0 0.14 ug/L 09/12/24 03:19 1<0.14Bromomethane 5.0 1.5 ug/L 09/12/24 03:19 1<1.5Carbon disulfide 1.0 0.17 ug/L 09/12/24 03:19 1<0.17Carbon tetrachloride 1.0 0.17 ug/L 09/12/24 03:19 1<0.17Chlorobenzene 1.0 0.23 ug/L 09/12/24 03:19 1<0.23Chloroethane 1.0 0.18 ug/L 09/12/24 03:19 1<0.18Chloroform 1.0 0.13 ug/L 09/12/24 03:19 10.58 JChloromethane 1.0 0.64 ug/L 09/12/24 03:19 1<0.64Chloroprene 1.0 0.15 ug/L 09/12/24 03:19 1<0.15cis-1,2-Dichloroethene 1.0 0.20 ug/L 09/12/24 03:19 1<0.20cis-1,3-Dichloropropene 1.0 0.17 ug/L 09/12/24 03:19 1<0.17Dibromochloromethane 1.0 0.27 ug/L 09/12/24 03:19 1<0.27Dibromomethane 1.0 0.20 ug/L 09/12/24 03:19 1<0.20Dichlorodifluoromethane 1.0 0.38 ug/L 09/12/24 03:19 1<0.38Ethyl methacrylate 1.0 0.13 ug/L 09/12/24 03:19 1<0.13Ethylbenzene 1.0 0.22 ug/L 09/12/24 03:19 1<0.22Hexachlorobutadiene 5.0 1.7 ug/L 09/12/24 03:19 1<1.7Iodomethane 50 11 ug/L 09/12/24 03:19 1<11 *1Isobutyl alcohol 10 4.9 ug/L 09/12/24 03:19 1<4.9Methacrylonitrile 1.0 0.51 ug/L 09/12/24 03:19 1<0.51Methyl methacrylate 1.0 0.23 ug/L 09/12/24 03:19 1<0.23Methylene Chloride 1.0 0.11 ug/L 09/12/24 03:19 1<0.11Naphthalene 10 5.0 ug/L 09/12/24 03:19 1<5.0Propionitrile 1.0 0.11 ug/L 09/12/24 03:19 1<0.11Styrene 1.0 0.17 ug/L 09/12/24 03:19 1<0.17Tetrachloroethene 1.0 0.53 ug/L 09/12/24 03:19 1<0.53Tetrahydrofuran 1.0 0.14 ug/L 09/12/24 03:19 1<0.14Toluene 1.0 0.21 ug/L 09/12/24 03:19 1<0.21trans-1,2-Dichloroethene 1.0 0.15 ug/L 09/12/24 03:19 1<0.15trans-1,3-Dichloropropene Eurofins Raleigh Page 16 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-1Client Sample ID: MW-4 Matrix: GWDate Collected: 09/04/24 15:36 Date Received: 09/05/24 11:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) RL MDL <0.70 1.0 0.70 ug/L 09/12/24 03:19 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier trans-1,4-Dichloro-2-butene 1.0 0.15 ug/L 09/12/24 03:19 1<0.15Trichloroethene 1.0 0.24 ug/L 09/12/24 03:19 1<0.24Trichlorofluoromethane 5.0 0.95 ug/L 09/12/24 03:19 1<0.95Vinyl acetate 1.0 0.32 ug/L 09/12/24 03:19 1<0.32Vinyl chloride 3.0 0.45 ug/L 09/12/24 03:19 1<0.45Xylenes, Total 4-Bromofluorobenzene (Surr)78 53-136 09/12/24 03:19 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Dibromofluoromethane (Surr)104 09/12/24 03:19 167-129 Toluene-d8 (Surr)85 09/12/24 03:19 159-134 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography RL MDL 4.2 0.50 0.20 mg/L 09/14/24 20:12 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Chloride 1.0 0.40 mg/L 09/14/24 20:12 1<0.40Sulfate Method: SW846 6010D - Metals (ICP) - Total Recoverable RL MDL <6.4 20 6.4 ug/L 09/09/24 05:44 09/09/24 21:31 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Arsenic 10 4.4 ug/L 09/09/24 05:44 09/09/24 21:31 19.6 JBarium 4.0 0.30 ug/L 09/09/24 05:44 09/09/24 21:31 1<0.30Beryllium 5.0 0.44 ug/L 09/09/24 05:44 09/09/24 21:31 1<0.44Cadmium 10 1.1 ug/L 09/09/24 05:44 09/09/24 21:31 12.9 JChromium 10 1.4 ug/L 09/09/24 05:44 09/09/24 21:31 1<1.4Cobalt 20 3.2 ug/L 09/09/24 05:44 09/09/24 21:31 1<3.2Copper 100 20 ug/L 09/09/24 05:44 09/09/24 21:31 1150Fe 10 6.6 ug/L 09/09/24 05:44 09/09/24 21:31 1<6.6Lead 10 1.3 ug/L 09/09/24 05:44 09/09/24 21:31 18.9 JManganese 40 3.3 ug/L 09/09/24 05:44 09/09/24 21:31 1<3.3Nickel 1000 67 ug/L 09/09/24 05:44 09/09/24 21:31 1300J BPotassium 10 1.5 ug/L 09/09/24 05:44 09/09/24 21:31 1<1.5Silver 50 11 ug/L 09/09/24 05:44 09/09/24 21:31 1<11Tin 10 1.0 ug/L 09/09/24 05:44 09/09/24 21:31 11.4 JVanadium 20 8.7 ug/L 09/09/24 05:44 09/09/24 21:31 1<8.7Zinc Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable RL MDL <0.34 5.0 0.34 ug/L 09/09/24 05:44 09/09/24 23:29 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Antimony 2.5 0.99 ug/L 09/09/24 05:44 09/09/24 23:29 1<0.99Selenium 1.0 0.26 ug/L 09/09/24 05:44 09/09/24 23:29 1<0.26Thallium Method: SW846 7470A - Mercury (CVAA) RL MDL <0.080 0.20 0.080 ug/L 09/09/24 15:09 09/10/24 11:22 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Mercury General Chemistry RL MDL 27 5.5 2.2 mg/L 09/10/24 16:21 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Alkalinity as CaCO3 to pH 4.5 (SM 2320B-2011) 0.81 0.81 mg/L 09/11/24 15:20 1<0.81Sulfide (SM 4500 S2 F-2011) Eurofins Raleigh Page 17 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-1Client Sample ID: MW-4 Matrix: GWDate Collected: 09/04/24 15:36 Date Received: 09/05/24 11:00 General Chemistry (Continued) RL MDL <0.025 0.10 0.025 mg/L 09/09/24 12:58 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Nitrate as N (SM Nitrate by calc) 50 50 mg/L 09/06/24 16:28 1<50Total Dissolved Solids (SM 2540C) 0.10 0.10 mg/L 09/16/24 10:19 10.15Ferric Iron (SM 3500) 0.10 0.025 mg/L 09/07/24 10:44 1<0.025 HFFerrous Iron (SM 3500 FE D) 0.10 0.041 mg/L 09/09/24 10:41 1<0.041Nitrate Nitrite as N (SM 4500 NO3 F) 0.10 0.017 mg/L 09/05/24 17:36 1<0.017Nitrite as N (SM4500 NO2 F) Lab Sample ID: 752-23805-2Client Sample ID: MW-10A Matrix: GWDate Collected: 09/04/24 14:21 Date Received: 09/05/24 11:00 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) RL MDL <0.32 0.50 0.32 ug/L 09/07/24 12:24 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,4-Dioxane 4-Bromofluorobenzene (Surr)76 46-154 09/07/24 12:24 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Method: SW846 8260D - Volatile Organic Compounds by GC/MS RL MDL <0.17 1.0 0.17 ug/L 09/12/24 03:41 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,1,1,2-Tetrachloroethane 1.0 0.12 ug/L 09/12/24 03:41 1<0.121,1,1-Trichloroethane 1.0 0.28 ug/L 09/12/24 03:41 1<0.281,1,2,2-Tetrachloroethane 1.0 0.14 ug/L 09/12/24 03:41 1<0.141,1,2-Trichloroethane 1.0 0.13 ug/L 09/12/24 03:41 1<0.131,1-Dichloroethane 1.0 0.21 ug/L 09/12/24 03:41 1<0.211,1-Dichloroethene 1.0 0.15 ug/L 09/12/24 03:41 1<0.151,1-Dichloropropene 1.0 0.49 ug/L 09/12/24 03:41 1<0.491,2,3-Trichloropropane 1.0 0.14 ug/L 09/12/24 03:41 1<0.141,2,4-Trichlorobenzene 1.0 0.48 ug/L 09/12/24 03:41 1<0.481,2-Dibromo-3-Chloropropane 1.0 0.66 ug/L 09/12/24 03:41 1<0.661,2-Dibromoethane 1.0 0.19 ug/L 09/12/24 03:41 1<0.191,2-Dichlorobenzene 1.0 0.21 ug/L 09/12/24 03:41 1<0.211,2-Dichloroethane 1.0 0.10 ug/L 09/12/24 03:41 1<0.101,2-Dichloropropane 1.0 0.15 ug/L 09/12/24 03:41 1<0.151,3-Dichlorobenzene 1.0 0.16 ug/L 09/12/24 03:41 1<0.161,3-Dichloropropane 1.0 0.19 ug/L 09/12/24 03:41 1<0.191,4-Dichlorobenzene 1.0 0.28 ug/L 09/12/24 03:41 1<0.282,2-Dichloropropane 20 10 ug/L 09/12/24 03:41 1<102-Butanone (MEK) 5.0 0.88 ug/L 09/12/24 03:41 1<0.882-Hexanone 1.0 0.11 ug/L 09/12/24 03:41 1<0.113-Chloropropene 5.0 1.1 ug/L 09/12/24 03:41 1<1.14-Methyl-2-pentanone (MIBK) 20 10 ug/L 09/12/24 03:41 1<10Acetone 10 5.0 ug/L 09/12/24 03:41 1<5.0 *1Acetonitrile 10 4.0 ug/L 09/12/24 03:41 1<4.0Acrolein 10 3.5 ug/L 09/12/24 03:41 1<3.5Acrylonitrile 1.0 0.15 ug/L 09/12/24 03:41 1<0.15Benzene 1.0 0.48 ug/L 09/12/24 03:41 1<0.48Bromochloromethane 1.0 0.17 ug/L 09/12/24 03:41 1<0.17Bromodichloromethane 1.0 0.22 ug/L 09/12/24 03:41 1<0.22Bromoform Eurofins Raleigh Page 18 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-2Client Sample ID: MW-10A Matrix: GWDate Collected: 09/04/24 14:21 Date Received: 09/05/24 11:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) RL MDL <0.14 1.0 0.14 ug/L 09/12/24 03:41 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Bromomethane 5.0 1.5 ug/L 09/12/24 03:41 1<1.5Carbon disulfide 1.0 0.17 ug/L 09/12/24 03:41 1<0.17Carbon tetrachloride 1.0 0.17 ug/L 09/12/24 03:41 1<0.17Chlorobenzene 1.0 0.23 ug/L 09/12/24 03:41 1<0.23Chloroethane 1.0 0.18 ug/L 09/12/24 03:41 1<0.18Chloroform 1.0 0.13 ug/L 09/12/24 03:41 1<0.13Chloromethane 1.0 0.64 ug/L 09/12/24 03:41 1<0.64Chloroprene 1.0 0.15 ug/L 09/12/24 03:41 1<0.15cis-1,2-Dichloroethene 1.0 0.20 ug/L 09/12/24 03:41 1<0.20cis-1,3-Dichloropropene 1.0 0.17 ug/L 09/12/24 03:41 1<0.17Dibromochloromethane 1.0 0.27 ug/L 09/12/24 03:41 1<0.27Dibromomethane 1.0 0.20 ug/L 09/12/24 03:41 1<0.20Dichlorodifluoromethane 1.0 0.38 ug/L 09/12/24 03:41 1<0.38Ethyl methacrylate 1.0 0.13 ug/L 09/12/24 03:41 1<0.13Ethylbenzene 1.0 0.22 ug/L 09/12/24 03:41 1<0.22Hexachlorobutadiene 5.0 1.7 ug/L 09/12/24 03:41 1<1.7Iodomethane 50 11 ug/L 09/12/24 03:41 1<11 *1Isobutyl alcohol 10 4.9 ug/L 09/12/24 03:41 1<4.9Methacrylonitrile 1.0 0.51 ug/L 09/12/24 03:41 1<0.51Methyl methacrylate 1.0 0.23 ug/L 09/12/24 03:41 1<0.23Methylene Chloride 1.0 0.11 ug/L 09/12/24 03:41 1<0.11Naphthalene 10 5.0 ug/L 09/12/24 03:41 1<5.0Propionitrile 1.0 0.11 ug/L 09/12/24 03:41 1<0.11Styrene 1.0 0.17 ug/L 09/12/24 03:41 1<0.17Tetrachloroethene 1.0 0.53 ug/L 09/12/24 03:41 1<0.53Tetrahydrofuran 1.0 0.14 ug/L 09/12/24 03:41 1<0.14Toluene 1.0 0.21 ug/L 09/12/24 03:41 1<0.21trans-1,2-Dichloroethene 1.0 0.15 ug/L 09/12/24 03:41 1<0.15trans-1,3-Dichloropropene 1.0 0.70 ug/L 09/12/24 03:41 1<0.70trans-1,4-Dichloro-2-butene 1.0 0.15 ug/L 09/12/24 03:41 1<0.15Trichloroethene 1.0 0.24 ug/L 09/12/24 03:41 1<0.24Trichlorofluoromethane 5.0 0.95 ug/L 09/12/24 03:41 1<0.95Vinyl acetate 1.0 0.32 ug/L 09/12/24 03:41 1<0.32Vinyl chloride 3.0 0.45 ug/L 09/12/24 03:41 1<0.45Xylenes, Total 4-Bromofluorobenzene (Surr)78 53-136 09/12/24 03:41 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Dibromofluoromethane (Surr)105 09/12/24 03:41 167-129 Toluene-d8 (Surr)86 09/12/24 03:41 159-134 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography RL MDL 1.4 0.50 0.20 mg/L 09/14/24 20:18 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Chloride 1.0 0.40 mg/L 09/14/24 20:18 12.3Sulfate Method: SW846 6010D - Metals (ICP) - Total Recoverable RL MDL <6.4 20 6.4 ug/L 09/09/24 05:44 09/09/24 21:23 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Arsenic 10 4.4 ug/L 09/09/24 05:44 09/09/24 21:23 113Barium Eurofins Raleigh Page 19 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-2Client Sample ID: MW-10A Matrix: GWDate Collected: 09/04/24 14:21 Date Received: 09/05/24 11:00 Method: SW846 6010D - Metals (ICP) - Total Recoverable (Continued) RL MDL <0.30 4.0 0.30 ug/L 09/09/24 05:44 09/09/24 21:23 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Beryllium 5.0 0.44 ug/L 09/09/24 05:44 09/09/24 21:23 11.4 JCadmium 10 1.1 ug/L 09/09/24 05:44 09/09/24 21:23 1<1.1Chromium 10 1.4 ug/L 09/09/24 05:44 09/09/24 21:23 1<1.4Cobalt 20 3.2 ug/L 09/09/24 05:44 09/09/24 21:23 15.0 JCopper 100 20 ug/L 09/09/24 05:44 09/09/24 21:23 1410Fe 10 6.6 ug/L 09/09/24 05:44 09/09/24 21:23 1<6.6Lead 10 1.3 ug/L 09/09/24 05:44 09/09/24 21:23 149Manganese 40 3.3 ug/L 09/09/24 05:44 09/09/24 21:23 1<3.3Nickel 1000 67 ug/L 09/09/24 05:44 09/09/24 21:23 11000BPotassium 10 1.5 ug/L 09/09/24 05:44 09/09/24 21:23 1<1.5Silver 50 11 ug/L 09/09/24 05:44 09/09/24 21:23 1<11Tin 10 1.0 ug/L 09/09/24 05:44 09/09/24 21:23 11.0 JVanadium 20 8.7 ug/L 09/09/24 05:44 09/09/24 21:23 115JZinc Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable RL MDL <0.34 5.0 0.34 ug/L 09/09/24 05:44 09/09/24 23:26 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Antimony 2.5 0.99 ug/L 09/09/24 05:44 09/09/24 23:26 1<0.99Selenium 1.0 0.26 ug/L 09/09/24 05:44 09/09/24 23:26 1<0.26Thallium Method: SW846 7470A - Mercury (CVAA) RL MDL <0.080 0.20 0.080 ug/L 09/09/24 15:09 09/10/24 11:20 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Mercury General Chemistry RL MDL 4.8 J 5.5 2.2 mg/L 09/10/24 16:12 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Alkalinity as CaCO3 to pH 4.5 (SM 2320B-2011) 0.81 0.81 mg/L 09/11/24 15:20 11.4Sulfide (SM 4500 S2 F-2011) 0.10 0.025 mg/L 09/09/24 12:58 1<0.025Nitrate as N (SM Nitrate by calc) 50 50 mg/L 09/06/24 16:28 1<50Total Dissolved Solids (SM 2540C) 0.10 0.10 mg/L 09/16/24 10:19 10.41Ferric Iron (SM 3500) 0.10 0.025 mg/L 09/07/24 10:44 1<0.025 HFFerrous Iron (SM 3500 FE D) 0.10 0.041 mg/L 09/09/24 10:42 1<0.041Nitrate Nitrite as N (SM 4500 NO3 F) 0.10 0.017 mg/L 09/05/24 17:37 1<0.017Nitrite as N (SM4500 NO2 F) Lab Sample ID: 752-23805-3Client Sample ID: MW-18 Matrix: GWDate Collected: 09/04/24 10:30 Date Received: 09/05/24 11:00 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) RL MDL 0.87 0.50 0.32 ug/L 09/07/24 12:50 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,4-Dioxane 4-Bromofluorobenzene (Surr)79 46-154 09/07/24 12:50 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Method: SW846 8260D - Volatile Organic Compounds by GC/MS RL MDL <0.17 1.0 0.17 ug/L 09/12/24 04:03 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,1,1,2-Tetrachloroethane Eurofins Raleigh Page 20 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-3Client Sample ID: MW-18 Matrix: GWDate Collected: 09/04/24 10:30 Date Received: 09/05/24 11:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) RL MDL <0.12 1.0 0.12 ug/L 09/12/24 04:03 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,1,1-Trichloroethane 1.0 0.28 ug/L 09/12/24 04:03 1<0.281,1,2,2-Tetrachloroethane 1.0 0.14 ug/L 09/12/24 04:03 1<0.141,1,2-Trichloroethane 1.0 0.13 ug/L 09/12/24 04:03 1<0.131,1-Dichloroethane 1.0 0.21 ug/L 09/12/24 04:03 1<0.211,1-Dichloroethene 1.0 0.15 ug/L 09/12/24 04:03 1<0.151,1-Dichloropropene 1.0 0.49 ug/L 09/12/24 04:03 1<0.491,2,3-Trichloropropane 1.0 0.14 ug/L 09/12/24 04:03 1<0.141,2,4-Trichlorobenzene 1.0 0.48 ug/L 09/12/24 04:03 1<0.481,2-Dibromo-3-Chloropropane 1.0 0.66 ug/L 09/12/24 04:03 1<0.661,2-Dibromoethane 1.0 0.19 ug/L 09/12/24 04:03 1<0.191,2-Dichlorobenzene 1.0 0.21 ug/L 09/12/24 04:03 1<0.211,2-Dichloroethane 1.0 0.10 ug/L 09/12/24 04:03 1<0.101,2-Dichloropropane 1.0 0.15 ug/L 09/12/24 04:03 1<0.151,3-Dichlorobenzene 1.0 0.16 ug/L 09/12/24 04:03 1<0.161,3-Dichloropropane 1.0 0.19 ug/L 09/12/24 04:03 1<0.191,4-Dichlorobenzene 1.0 0.28 ug/L 09/12/24 04:03 1<0.282,2-Dichloropropane 20 10 ug/L 09/12/24 04:03 1<102-Butanone (MEK) 5.0 0.88 ug/L 09/12/24 04:03 1<0.882-Hexanone 1.0 0.11 ug/L 09/12/24 04:03 1<0.113-Chloropropene 5.0 1.1 ug/L 09/12/24 04:03 1<1.14-Methyl-2-pentanone (MIBK) 20 10 ug/L 09/12/24 04:03 1<10Acetone 10 5.0 ug/L 09/12/24 04:03 1<5.0 *1Acetonitrile 10 4.0 ug/L 09/12/24 04:03 1<4.0Acrolein 10 3.5 ug/L 09/12/24 04:03 1<3.5Acrylonitrile 1.0 0.15 ug/L 09/12/24 04:03 1<0.15Benzene 1.0 0.48 ug/L 09/12/24 04:03 1<0.48Bromochloromethane 1.0 0.17 ug/L 09/12/24 04:03 1<0.17Bromodichloromethane 1.0 0.22 ug/L 09/12/24 04:03 1<0.22Bromoform 1.0 0.14 ug/L 09/12/24 04:03 1<0.14Bromomethane 5.0 1.5 ug/L 09/12/24 04:03 1<1.5Carbon disulfide 1.0 0.17 ug/L 09/12/24 04:03 1<0.17Carbon tetrachloride 1.0 0.17 ug/L 09/12/24 04:03 1<0.17Chlorobenzene 1.0 0.23 ug/L 09/12/24 04:03 1<0.23Chloroethane 1.0 0.18 ug/L 09/12/24 04:03 1<0.18Chloroform 1.0 0.13 ug/L 09/12/24 04:03 1<0.13Chloromethane 1.0 0.64 ug/L 09/12/24 04:03 1<0.64Chloroprene 1.0 0.15 ug/L 09/12/24 04:03 1<0.15cis-1,2-Dichloroethene 1.0 0.20 ug/L 09/12/24 04:03 1<0.20cis-1,3-Dichloropropene 1.0 0.17 ug/L 09/12/24 04:03 1<0.17Dibromochloromethane 1.0 0.27 ug/L 09/12/24 04:03 1<0.27Dibromomethane 1.0 0.20 ug/L 09/12/24 04:03 1<0.20Dichlorodifluoromethane 1.0 0.38 ug/L 09/12/24 04:03 1<0.38Ethyl methacrylate 1.0 0.13 ug/L 09/12/24 04:03 1<0.13Ethylbenzene 1.0 0.22 ug/L 09/12/24 04:03 1<0.22Hexachlorobutadiene 5.0 1.7 ug/L 09/12/24 04:03 1<1.7Iodomethane 50 11 ug/L 09/12/24 04:03 1<11 *1Isobutyl alcohol 10 4.9 ug/L 09/12/24 04:03 1<4.9Methacrylonitrile 1.0 0.51 ug/L 09/12/24 04:03 1<0.51Methyl methacrylate Eurofins Raleigh Page 21 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-3Client Sample ID: MW-18 Matrix: GWDate Collected: 09/04/24 10:30 Date Received: 09/05/24 11:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) RL MDL <0.23 1.0 0.23 ug/L 09/12/24 04:03 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Methylene Chloride 1.0 0.11 ug/L 09/12/24 04:03 1<0.11Naphthalene 10 5.0 ug/L 09/12/24 04:03 1<5.0Propionitrile 1.0 0.11 ug/L 09/12/24 04:03 1<0.11Styrene 1.0 0.17 ug/L 09/12/24 04:03 1<0.17Tetrachloroethene 1.0 0.53 ug/L 09/12/24 04:03 1<0.53Tetrahydrofuran 1.0 0.14 ug/L 09/12/24 04:03 1<0.14Toluene 1.0 0.21 ug/L 09/12/24 04:03 1<0.21trans-1,2-Dichloroethene 1.0 0.15 ug/L 09/12/24 04:03 1<0.15trans-1,3-Dichloropropene 1.0 0.70 ug/L 09/12/24 04:03 1<0.70trans-1,4-Dichloro-2-butene 1.0 0.15 ug/L 09/12/24 04:03 1<0.15Trichloroethene 1.0 0.24 ug/L 09/12/24 04:03 1<0.24Trichlorofluoromethane 5.0 0.95 ug/L 09/12/24 04:03 1<0.95Vinyl acetate 1.0 0.32 ug/L 09/12/24 04:03 1<0.32Vinyl chloride 3.0 0.45 ug/L 09/12/24 04:03 1<0.45Xylenes, Total 4-Bromofluorobenzene (Surr)76 53-136 09/12/24 04:03 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Dibromofluoromethane (Surr)107 09/12/24 04:03 167-129 Toluene-d8 (Surr)86 09/12/24 04:03 159-134 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography RL MDL 12 2.5 1.0 mg/L 09/14/24 20:25 5 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Chloride 5.0 2.0 mg/L 09/14/24 20:25 55.5Sulfate Method: SW846 6010D - Metals (ICP) - Total Recoverable RL MDL <6.4 20 6.4 ug/L 09/09/24 05:44 09/09/24 21:21 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Arsenic 10 4.4 ug/L 09/09/24 05:44 09/09/24 21:21 140Barium 4.0 0.30 ug/L 09/09/24 05:44 09/09/24 21:21 1<0.30Beryllium 5.0 0.44 ug/L 09/09/24 05:44 09/09/24 21:21 1<0.44Cadmium 10 1.1 ug/L 09/09/24 05:44 09/09/24 21:21 1<1.1Chromium 10 1.4 ug/L 09/09/24 05:44 09/09/24 21:21 15.3 JCobalt 20 3.2 ug/L 09/09/24 05:44 09/09/24 21:21 1<3.2Copper 100 20 ug/L 09/09/24 05:44 09/09/24 21:21 11300Fe 10 6.6 ug/L 09/09/24 05:44 09/09/24 21:21 1<6.6Lead 10 1.3 ug/L 09/09/24 05:44 09/09/24 21:21 11600Manganese 40 3.3 ug/L 09/09/24 05:44 09/09/24 21:21 1<3.3Nickel 1000 67 ug/L 09/09/24 05:44 09/09/24 21:21 13100BPotassium 10 1.5 ug/L 09/09/24 05:44 09/09/24 21:21 1<1.5Silver 50 11 ug/L 09/09/24 05:44 09/09/24 21:21 1<11Tin 10 1.0 ug/L 09/09/24 05:44 09/09/24 21:21 12.0 JVanadium 20 8.7 ug/L 09/09/24 05:44 09/09/24 21:21 1<8.7Zinc Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable RL MDL <0.34 5.0 0.34 ug/L 09/09/24 05:44 09/09/24 23:23 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Antimony 2.5 0.99 ug/L 09/09/24 05:44 09/09/24 23:23 1<0.99Selenium 1.0 0.26 ug/L 09/09/24 05:44 09/09/24 23:23 1<0.26Thallium Eurofins Raleigh Page 22 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-3Client Sample ID: MW-18 Matrix: GWDate Collected: 09/04/24 10:30 Date Received: 09/05/24 11:00 Method: SW846 7470A - Mercury (CVAA) RL MDL <0.080 0.20 0.080 ug/L 09/09/24 15:09 09/10/24 11:18 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Mercury General Chemistry RL MDL 63 5.5 2.2 mg/L 09/10/24 16:46 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Alkalinity as CaCO3 to pH 4.5 (SM 2320B-2011) 0.81 0.81 mg/L 09/11/24 15:20 11.8Sulfide (SM 4500 S2 F-2011) 0.10 0.025 mg/L 09/09/24 12:58 1<0.025Nitrate as N (SM Nitrate by calc) 50 50 mg/L 09/06/24 16:28 1120 0.10 0.10 mg/L 09/16/24 10:19 10.34Ferric Iron (SM 3500) 0.10 0.025 mg/L 09/07/24 10:38 10.96 HFFerrous Iron (SM 3500 FE D) 0.10 0.041 mg/L 09/09/24 10:44 1<0.041Nitrate Nitrite as N (SM 4500 NO3 F) 0.10 0.017 mg/L 09/05/24 17:38 1<0.017Nitrite as N (SM4500 NO2 F) Lab Sample ID: 752-23805-4Client Sample ID: SW-2 Matrix: Surface WaterDate Collected: 09/04/24 13:02 Date Received: 09/05/24 11:00 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) RL MDL <0.32 0.50 0.32 ug/L 09/07/24 13:16 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,4-Dioxane 4-Bromofluorobenzene (Surr)78 46-154 09/07/24 13:16 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Method: SW846 8260D - Volatile Organic Compounds by GC/MS RL MDL <0.17 1.0 0.17 ug/L 09/12/24 04:25 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,1,1,2-Tetrachloroethane 1.0 0.12 ug/L 09/12/24 04:25 1<0.121,1,1-Trichloroethane 1.0 0.28 ug/L 09/12/24 04:25 1<0.281,1,2,2-Tetrachloroethane 1.0 0.14 ug/L 09/12/24 04:25 1<0.141,1,2-Trichloroethane 1.0 0.13 ug/L 09/12/24 04:25 1<0.131,1-Dichloroethane 1.0 0.21 ug/L 09/12/24 04:25 1<0.211,1-Dichloroethene 1.0 0.15 ug/L 09/12/24 04:25 1<0.151,1-Dichloropropene 1.0 0.49 ug/L 09/12/24 04:25 1<0.491,2,3-Trichloropropane 1.0 0.14 ug/L 09/12/24 04:25 1<0.141,2,4-Trichlorobenzene 1.0 0.48 ug/L 09/12/24 04:25 1<0.481,2-Dibromo-3-Chloropropane 1.0 0.66 ug/L 09/12/24 04:25 1<0.661,2-Dibromoethane 1.0 0.19 ug/L 09/12/24 04:25 1<0.191,2-Dichlorobenzene 1.0 0.21 ug/L 09/12/24 04:25 1<0.211,2-Dichloroethane 1.0 0.10 ug/L 09/12/24 04:25 1<0.101,2-Dichloropropane 1.0 0.15 ug/L 09/12/24 04:25 1<0.151,3-Dichlorobenzene 1.0 0.16 ug/L 09/12/24 04:25 1<0.161,3-Dichloropropane 1.0 0.19 ug/L 09/12/24 04:25 1<0.191,4-Dichlorobenzene 1.0 0.28 ug/L 09/12/24 04:25 1<0.282,2-Dichloropropane 20 10 ug/L 09/12/24 04:25 1<102-Butanone (MEK) 5.0 0.88 ug/L 09/12/24 04:25 1<0.882-Hexanone 1.0 0.11 ug/L 09/12/24 04:25 1<0.113-Chloropropene 5.0 1.1 ug/L 09/12/24 04:25 1<1.14-Methyl-2-pentanone (MIBK) 20 10 ug/L 09/12/24 04:25 1<10Acetone 10 5.0 ug/L 09/12/24 04:25 1<5.0 *1Acetonitrile Eurofins Raleigh Page 23 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-4Client Sample ID: SW-2 Matrix: Surface WaterDate Collected: 09/04/24 13:02 Date Received: 09/05/24 11:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) RL MDL <4.0 10 4.0 ug/L 09/12/24 04:25 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Acrolein 10 3.5 ug/L 09/12/24 04:25 1<3.5Acrylonitrile 1.0 0.15 ug/L 09/12/24 04:25 1<0.15Benzene 1.0 0.48 ug/L 09/12/24 04:25 1<0.48Bromochloromethane 1.0 0.17 ug/L 09/12/24 04:25 1<0.17Bromodichloromethane 1.0 0.22 ug/L 09/12/24 04:25 1<0.22Bromoform 1.0 0.14 ug/L 09/12/24 04:25 1<0.14Bromomethane 5.0 1.5 ug/L 09/12/24 04:25 1<1.5Carbon disulfide 1.0 0.17 ug/L 09/12/24 04:25 1<0.17Carbon tetrachloride 1.0 0.17 ug/L 09/12/24 04:25 1<0.17Chlorobenzene 1.0 0.23 ug/L 09/12/24 04:25 1<0.23Chloroethane 1.0 0.18 ug/L 09/12/24 04:25 1<0.18Chloroform 1.0 0.13 ug/L 09/12/24 04:25 1<0.13Chloromethane 1.0 0.64 ug/L 09/12/24 04:25 1<0.64Chloroprene 1.0 0.15 ug/L 09/12/24 04:25 1<0.15cis-1,2-Dichloroethene 1.0 0.20 ug/L 09/12/24 04:25 1<0.20cis-1,3-Dichloropropene 1.0 0.17 ug/L 09/12/24 04:25 1<0.17Dibromochloromethane 1.0 0.27 ug/L 09/12/24 04:25 1<0.27Dibromomethane 1.0 0.20 ug/L 09/12/24 04:25 1<0.20Dichlorodifluoromethane 1.0 0.38 ug/L 09/12/24 04:25 1<0.38Ethyl methacrylate 1.0 0.13 ug/L 09/12/24 04:25 1<0.13Ethylbenzene 1.0 0.22 ug/L 09/12/24 04:25 1<0.22Hexachlorobutadiene 5.0 1.7 ug/L 09/12/24 04:25 1<1.7Iodomethane 50 11 ug/L 09/12/24 04:25 1<11 *1Isobutyl alcohol 10 4.9 ug/L 09/12/24 04:25 1<4.9Methacrylonitrile 1.0 0.51 ug/L 09/12/24 04:25 1<0.51Methyl methacrylate 1.0 0.23 ug/L 09/12/24 04:25 1<0.23Methylene Chloride 1.0 0.11 ug/L 09/12/24 04:25 1<0.11Naphthalene 10 5.0 ug/L 09/12/24 04:25 1<5.0Propionitrile 1.0 0.11 ug/L 09/12/24 04:25 1<0.11Styrene 1.0 0.17 ug/L 09/12/24 04:25 1<0.17Tetrachloroethene 1.0 0.53 ug/L 09/12/24 04:25 1<0.53Tetrahydrofuran 1.0 0.14 ug/L 09/12/24 04:25 1<0.14Toluene 1.0 0.21 ug/L 09/12/24 04:25 1<0.21trans-1,2-Dichloroethene 1.0 0.15 ug/L 09/12/24 04:25 1<0.15trans-1,3-Dichloropropene 1.0 0.70 ug/L 09/12/24 04:25 1<0.70trans-1,4-Dichloro-2-butene 1.0 0.15 ug/L 09/12/24 04:25 1<0.15Trichloroethene 1.0 0.24 ug/L 09/12/24 04:25 1<0.24Trichlorofluoromethane 5.0 0.95 ug/L 09/12/24 04:25 1<0.95Vinyl acetate 1.0 0.32 ug/L 09/12/24 04:25 1<0.32Vinyl chloride 3.0 0.45 ug/L 09/12/24 04:25 1<0.45Xylenes, Total 4-Bromofluorobenzene (Surr)76 53-136 09/12/24 04:25 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Dibromofluoromethane (Surr)104 09/12/24 04:25 167-129 Toluene-d8 (Surr)87 09/12/24 04:25 159-134 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography RL MDL 11 0.50 0.20 mg/L 09/14/24 20:31 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Chloride Eurofins Raleigh Page 24 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-4Client Sample ID: SW-2 Matrix: Surface WaterDate Collected: 09/04/24 13:02 Date Received: 09/05/24 11:00 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography (Continued) RL MDL 7.9 1.0 0.40 mg/L 09/14/24 20:31 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Sulfate Method: SM 2340B-2011 - Total Hardness (as CaCO3) by calculation RL MDL 47 3.3 3.3 mg/L 09/17/24 12:06 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Hardness as calcium carbonate Method: SW846 6010D - Metals (ICP) - Total Recoverable RL MDL <6.4 20 6.4 ug/L 09/09/24 05:44 09/09/24 21:18 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Arsenic 10 4.4 ug/L 09/09/24 05:44 09/09/24 21:18 130Barium 4.0 0.30 ug/L 09/09/24 05:44 09/09/24 21:18 1<0.30Beryllium 5.0 0.44 ug/L 09/09/24 05:44 09/09/24 21:18 1<0.44Cadmium 10 1.1 ug/L 09/09/24 05:44 09/09/24 21:18 1<1.1Chromium 10 1.4 ug/L 09/09/24 05:44 09/09/24 21:18 1<1.4Cobalt 20 3.2 ug/L 09/09/24 05:44 09/09/24 21:18 14.2 JCopper 100 20 ug/L 09/09/24 05:44 09/09/24 21:18 1620Fe 10 6.6 ug/L 09/09/24 05:44 09/09/24 21:18 1<6.6Lead 10 1.3 ug/L 09/09/24 05:44 09/09/24 21:18 164Manganese 40 3.3 ug/L 09/09/24 05:44 09/09/24 21:18 1<3.3Nickel 1000 67 ug/L 09/09/24 05:44 09/09/24 21:18 13600BPotassium 10 1.5 ug/L 09/09/24 05:44 09/09/24 21:18 1<1.5Silver 50 11 ug/L 09/09/24 05:44 09/09/24 21:18 1<11Tin 10 1.0 ug/L 09/09/24 05:44 09/09/24 21:18 12.1 JVanadium 20 8.7 ug/L 09/09/24 05:44 09/09/24 21:18 110JZinc Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable RL MDL <0.34 5.0 0.34 ug/L 09/09/24 05:44 09/09/24 23:21 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Antimony 2.5 0.99 ug/L 09/09/24 05:44 09/09/24 23:21 1<0.99Selenium 1.0 0.26 ug/L 09/09/24 05:44 09/09/24 23:21 1<0.26Thallium Method: SW846 7470A - Mercury (CVAA) RL MDL <0.080 0.20 0.080 ug/L 09/09/24 15:09 09/10/24 11:07 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Mercury General Chemistry RL MDL 53 5.5 2.2 mg/L 09/10/24 16:38 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Alkalinity as CaCO3 to pH 4.5 (SM 2320B-2011) 0.83 0.83 mg/L 09/11/24 15:20 11.7Sulfide (SM 4500 S2 F-2011) 0.10 0.025 mg/L 09/09/24 12:58 10.13Nitrate as N (SM Nitrate by calc) 50 50 mg/L 09/06/24 16:28 180 0.10 0.10 mg/L 09/16/24 10:19 10.58Ferric Iron (SM 3500) 0.10 0.025 mg/L 09/07/24 10:44 10.039 J HFFerrous Iron (SM 3500 FE D) 0.10 0.041 mg/L 09/09/24 10:46 10.13Nitrate Nitrite as N (SM 4500 NO3 F) 0.10 0.017 mg/L 09/05/24 17:39 1<0.017Nitrite as N (SM4500 NO2 F) Eurofins Raleigh Page 25 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-5Client Sample ID: SW-3 Matrix: Surface WaterDate Collected: 09/04/24 16:10 Date Received: 09/05/24 11:00 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) RL MDL <0.32 0.50 0.32 ug/L 09/07/24 13:41 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,4-Dioxane 4-Bromofluorobenzene (Surr)78 46-154 09/07/24 13:41 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Method: SW846 8260D - Volatile Organic Compounds by GC/MS RL MDL <0.17 1.0 0.17 ug/L 09/12/24 04:47 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,1,1,2-Tetrachloroethane 1.0 0.12 ug/L 09/12/24 04:47 1<0.121,1,1-Trichloroethane 1.0 0.28 ug/L 09/12/24 04:47 1<0.281,1,2,2-Tetrachloroethane 1.0 0.14 ug/L 09/12/24 04:47 1<0.141,1,2-Trichloroethane 1.0 0.13 ug/L 09/12/24 04:47 1<0.131,1-Dichloroethane 1.0 0.21 ug/L 09/12/24 04:47 1<0.211,1-Dichloroethene 1.0 0.15 ug/L 09/12/24 04:47 1<0.151,1-Dichloropropene 1.0 0.49 ug/L 09/12/24 04:47 1<0.491,2,3-Trichloropropane 1.0 0.14 ug/L 09/12/24 04:47 1<0.141,2,4-Trichlorobenzene 1.0 0.48 ug/L 09/12/24 04:47 1<0.481,2-Dibromo-3-Chloropropane 1.0 0.66 ug/L 09/12/24 04:47 1<0.661,2-Dibromoethane 1.0 0.19 ug/L 09/12/24 04:47 1<0.191,2-Dichlorobenzene 1.0 0.21 ug/L 09/12/24 04:47 1<0.211,2-Dichloroethane 1.0 0.10 ug/L 09/12/24 04:47 1<0.101,2-Dichloropropane 1.0 0.15 ug/L 09/12/24 04:47 1<0.151,3-Dichlorobenzene 1.0 0.16 ug/L 09/12/24 04:47 1<0.161,3-Dichloropropane 1.0 0.19 ug/L 09/12/24 04:47 1<0.191,4-Dichlorobenzene 1.0 0.28 ug/L 09/12/24 04:47 1<0.282,2-Dichloropropane 20 10 ug/L 09/12/24 04:47 1<102-Butanone (MEK) 5.0 0.88 ug/L 09/12/24 04:47 1<0.882-Hexanone 1.0 0.11 ug/L 09/12/24 04:47 1<0.113-Chloropropene 5.0 1.1 ug/L 09/12/24 04:47 1<1.14-Methyl-2-pentanone (MIBK) 20 10 ug/L 09/12/24 04:47 1<10Acetone 10 5.0 ug/L 09/12/24 04:47 1<5.0 *1Acetonitrile 10 4.0 ug/L 09/12/24 04:47 1<4.0Acrolein 10 3.5 ug/L 09/12/24 04:47 1<3.5Acrylonitrile 1.0 0.15 ug/L 09/12/24 04:47 1<0.15Benzene 1.0 0.48 ug/L 09/12/24 04:47 1<0.48Bromochloromethane 1.0 0.17 ug/L 09/12/24 04:47 1<0.17Bromodichloromethane 1.0 0.22 ug/L 09/12/24 04:47 1<0.22Bromoform 1.0 0.14 ug/L 09/12/24 04:47 1<0.14Bromomethane 5.0 1.5 ug/L 09/12/24 04:47 1<1.5Carbon disulfide 1.0 0.17 ug/L 09/12/24 04:47 1<0.17Carbon tetrachloride 1.0 0.17 ug/L 09/12/24 04:47 1<0.17Chlorobenzene 1.0 0.23 ug/L 09/12/24 04:47 1<0.23Chloroethane 1.0 0.18 ug/L 09/12/24 04:47 1<0.18Chloroform 1.0 0.13 ug/L 09/12/24 04:47 1<0.13Chloromethane 1.0 0.64 ug/L 09/12/24 04:47 1<0.64Chloroprene 1.0 0.15 ug/L 09/12/24 04:47 1<0.15cis-1,2-Dichloroethene 1.0 0.20 ug/L 09/12/24 04:47 1<0.20cis-1,3-Dichloropropene 1.0 0.17 ug/L 09/12/24 04:47 1<0.17Dibromochloromethane 1.0 0.27 ug/L 09/12/24 04:47 1<0.27Dibromomethane 1.0 0.20 ug/L 09/12/24 04:47 1<0.20Dichlorodifluoromethane Eurofins Raleigh Page 26 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-5Client Sample ID: SW-3 Matrix: Surface WaterDate Collected: 09/04/24 16:10 Date Received: 09/05/24 11:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) RL MDL <0.38 1.0 0.38 ug/L 09/12/24 04:47 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Ethyl methacrylate 1.0 0.13 ug/L 09/12/24 04:47 1<0.13Ethylbenzene 1.0 0.22 ug/L 09/12/24 04:47 1<0.22Hexachlorobutadiene 5.0 1.7 ug/L 09/12/24 04:47 1<1.7Iodomethane 50 11 ug/L 09/12/24 04:47 1<11 *1Isobutyl alcohol 10 4.9 ug/L 09/12/24 04:47 1<4.9Methacrylonitrile 1.0 0.51 ug/L 09/12/24 04:47 1<0.51Methyl methacrylate 1.0 0.23 ug/L 09/12/24 04:47 1<0.23Methylene Chloride 1.0 0.11 ug/L 09/12/24 04:47 1<0.11Naphthalene 10 5.0 ug/L 09/12/24 04:47 1<5.0Propionitrile 1.0 0.11 ug/L 09/12/24 04:47 1<0.11Styrene 1.0 0.17 ug/L 09/12/24 04:47 1<0.17Tetrachloroethene 1.0 0.53 ug/L 09/12/24 04:47 1<0.53Tetrahydrofuran 1.0 0.14 ug/L 09/12/24 04:47 1<0.14Toluene 1.0 0.21 ug/L 09/12/24 04:47 1<0.21trans-1,2-Dichloroethene 1.0 0.15 ug/L 09/12/24 04:47 1<0.15trans-1,3-Dichloropropene 1.0 0.70 ug/L 09/12/24 04:47 1<0.70trans-1,4-Dichloro-2-butene 1.0 0.15 ug/L 09/12/24 04:47 1<0.15Trichloroethene 1.0 0.24 ug/L 09/12/24 04:47 1<0.24Trichlorofluoromethane 5.0 0.95 ug/L 09/12/24 04:47 1<0.95Vinyl acetate 1.0 0.32 ug/L 09/12/24 04:47 1<0.32Vinyl chloride 3.0 0.45 ug/L 09/12/24 04:47 1<0.45Xylenes, Total 4-Bromofluorobenzene (Surr)77 53-136 09/12/24 04:47 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Dibromofluoromethane (Surr)105 09/12/24 04:47 167-129 Toluene-d8 (Surr)85 09/12/24 04:47 159-134 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography RL MDL 12 0.50 0.20 mg/L 09/14/24 21:23 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Chloride 1.0 0.40 mg/L 09/14/24 21:23 18.5Sulfate Method: SM 2340B-2011 - Total Hardness (as CaCO3) by calculation RL MDL 110 3.3 3.3 mg/L 09/17/24 12:06 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Hardness as calcium carbonate Method: SW846 6010D - Metals (ICP) - Total Recoverable RL MDL <6.4 20 6.4 ug/L 09/09/24 05:44 09/09/24 21:11 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Arsenic 10 4.4 ug/L 09/09/24 05:44 09/09/24 21:11 135Barium 4.0 0.30 ug/L 09/09/24 05:44 09/09/24 21:11 1<0.30Beryllium 5.0 0.44 ug/L 09/09/24 05:44 09/09/24 21:11 1<0.44Cadmium 10 1.1 ug/L 09/09/24 05:44 09/09/24 21:11 1<1.1Chromium 10 1.4 ug/L 09/09/24 05:44 09/09/24 21:11 1<1.4Cobalt 20 3.2 ug/L 09/09/24 05:44 09/09/24 21:11 1<3.2Copper 100 20 ug/L 09/09/24 05:44 09/09/24 21:11 1560Fe 10 6.6 ug/L 09/09/24 05:44 09/09/24 21:11 1<6.6Lead 10 1.3 ug/L 09/09/24 05:44 09/09/24 21:11 191Manganese 40 3.3 ug/L 09/09/24 05:44 09/09/24 21:11 1<3.3Nickel Eurofins Raleigh Page 27 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-5Client Sample ID: SW-3 Matrix: Surface WaterDate Collected: 09/04/24 16:10 Date Received: 09/05/24 11:00 Method: SW846 6010D - Metals (ICP) - Total Recoverable (Continued) RL MDL 10000 B 1000 67 ug/L 09/09/24 05:44 09/09/24 21:11 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Potassium 10 1.5 ug/L 09/09/24 05:44 09/09/24 21:11 1<1.5Silver 50 11 ug/L 09/09/24 05:44 09/09/24 21:11 1<11Tin 10 1.0 ug/L 09/09/24 05:44 09/09/24 21:11 12.6 JVanadium 20 8.7 ug/L 09/09/24 05:44 09/09/24 21:11 1<8.7Zinc Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable RL MDL <0.34 5.0 0.34 ug/L 09/09/24 05:44 09/09/24 23:13 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Antimony 2.5 0.99 ug/L 09/09/24 05:44 09/09/24 23:13 1<0.99Selenium 1.0 0.26 ug/L 09/09/24 05:44 09/09/24 23:13 1<0.26Thallium Method: SW846 7470A - Mercury (CVAA) RL MDL <0.080 0.20 0.080 ug/L 09/09/24 15:09 09/10/24 11:26 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Mercury General Chemistry RL MDL 110 5.5 2.2 mg/L 09/10/24 16:30 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Alkalinity as CaCO3 to pH 4.5 (SM 2320B-2011) 0.83 0.83 mg/L 09/11/24 15:20 11.5Sulfide (SM 4500 S2 F-2011) 0.10 0.025 mg/L 09/09/24 12:58 1<0.025Nitrate as N (SM Nitrate by calc) 50 50 mg/L 09/06/24 16:28 1150 0.10 0.10 mg/L 09/16/24 10:19 10.53Ferric Iron (SM 3500) 0.10 0.025 mg/L 09/07/24 10:38 10.033 J HFFerrous Iron (SM 3500 FE D) 0.10 0.041 mg/L 09/09/24 10:48 1<0.041Nitrate Nitrite as N (SM 4500 NO3 F) 0.10 0.017 mg/L 09/05/24 17:40 1<0.017Nitrite as N (SM4500 NO2 F) Lab Sample ID: 752-23805-6Client Sample ID: Equipment Blank Matrix: GWDate Collected: 09/04/24 16:10 Date Received: 09/05/24 11:00 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) RL MDL <0.32 0.50 0.32 ug/L 09/07/24 11:33 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,4-Dioxane 4-Bromofluorobenzene (Surr)76 46-154 09/07/24 11:33 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Method: SW846 8260D - Volatile Organic Compounds by GC/MS RL MDL <0.17 1.0 0.17 ug/L 09/12/24 00:21 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,1,1,2-Tetrachloroethane 1.0 0.12 ug/L 09/12/24 00:21 1<0.121,1,1-Trichloroethane 1.0 0.28 ug/L 09/12/24 00:21 1<0.281,1,2,2-Tetrachloroethane 1.0 0.14 ug/L 09/12/24 00:21 1<0.141,1,2-Trichloroethane 1.0 0.13 ug/L 09/12/24 00:21 1<0.131,1-Dichloroethane 1.0 0.21 ug/L 09/12/24 00:21 1<0.211,1-Dichloroethene 1.0 0.15 ug/L 09/12/24 00:21 1<0.151,1-Dichloropropene 1.0 0.49 ug/L 09/12/24 00:21 1<0.491,2,3-Trichloropropane 1.0 0.14 ug/L 09/12/24 00:21 1<0.141,2,4-Trichlorobenzene 1.0 0.48 ug/L 09/12/24 00:21 1<0.481,2-Dibromo-3-Chloropropane Eurofins Raleigh Page 28 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-6Client Sample ID: Equipment Blank Matrix: GWDate Collected: 09/04/24 16:10 Date Received: 09/05/24 11:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) RL MDL <0.66 1.0 0.66 ug/L 09/12/24 00:21 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,2-Dibromoethane 1.0 0.19 ug/L 09/12/24 00:21 1<0.191,2-Dichlorobenzene 1.0 0.21 ug/L 09/12/24 00:21 1<0.211,2-Dichloroethane 1.0 0.10 ug/L 09/12/24 00:21 1<0.101,2-Dichloropropane 1.0 0.15 ug/L 09/12/24 00:21 1<0.151,3-Dichlorobenzene 1.0 0.16 ug/L 09/12/24 00:21 1<0.161,3-Dichloropropane 1.0 0.19 ug/L 09/12/24 00:21 1<0.191,4-Dichlorobenzene 1.0 0.28 ug/L 09/12/24 00:21 1<0.282,2-Dichloropropane 20 10 ug/L 09/12/24 00:21 1<102-Butanone (MEK) 5.0 0.88 ug/L 09/12/24 00:21 1<0.882-Hexanone 1.0 0.11 ug/L 09/12/24 00:21 1<0.113-Chloropropene 5.0 1.1 ug/L 09/12/24 00:21 1<1.14-Methyl-2-pentanone (MIBK) 20 10 ug/L 09/12/24 00:21 1<10Acetone 10 5.0 ug/L 09/12/24 00:21 1<5.0 *1Acetonitrile 10 4.0 ug/L 09/12/24 00:21 1<4.0Acrolein 10 3.5 ug/L 09/12/24 00:21 1<3.5Acrylonitrile 1.0 0.15 ug/L 09/12/24 00:21 1<0.15Benzene 1.0 0.48 ug/L 09/12/24 00:21 1<0.48Bromochloromethane 1.0 0.17 ug/L 09/12/24 00:21 1<0.17Bromodichloromethane 1.0 0.22 ug/L 09/12/24 00:21 1<0.22Bromoform 1.0 0.14 ug/L 09/12/24 00:21 1<0.14Bromomethane 5.0 1.5 ug/L 09/12/24 00:21 1<1.5Carbon disulfide 1.0 0.17 ug/L 09/12/24 00:21 1<0.17Carbon tetrachloride 1.0 0.17 ug/L 09/12/24 00:21 1<0.17Chlorobenzene 1.0 0.23 ug/L 09/12/24 00:21 1<0.23Chloroethane 1.0 0.18 ug/L 09/12/24 00:21 10.23 JChloroform 1.0 0.13 ug/L 09/12/24 00:21 1<0.13Chloromethane 1.0 0.64 ug/L 09/12/24 00:21 1<0.64Chloroprene 1.0 0.15 ug/L 09/12/24 00:21 1<0.15cis-1,2-Dichloroethene 1.0 0.20 ug/L 09/12/24 00:21 1<0.20cis-1,3-Dichloropropene 1.0 0.17 ug/L 09/12/24 00:21 1<0.17Dibromochloromethane 1.0 0.27 ug/L 09/12/24 00:21 1<0.27Dibromomethane 1.0 0.20 ug/L 09/12/24 00:21 1<0.20Dichlorodifluoromethane 1.0 0.38 ug/L 09/12/24 00:21 1<0.38Ethyl methacrylate 1.0 0.13 ug/L 09/12/24 00:21 1<0.13Ethylbenzene 1.0 0.22 ug/L 09/12/24 00:21 1<0.22Hexachlorobutadiene 5.0 1.7 ug/L 09/12/24 00:21 1<1.7Iodomethane 50 11 ug/L 09/12/24 00:21 1<11 *1Isobutyl alcohol 10 4.9 ug/L 09/12/24 00:21 1<4.9Methacrylonitrile 1.0 0.51 ug/L 09/12/24 00:21 1<0.51Methyl methacrylate 1.0 0.23 ug/L 09/12/24 00:21 1<0.23Methylene Chloride 1.0 0.11 ug/L 09/12/24 00:21 1<0.11Naphthalene 10 5.0 ug/L 09/12/24 00:21 1<5.0Propionitrile 1.0 0.11 ug/L 09/12/24 00:21 1<0.11Styrene 1.0 0.17 ug/L 09/12/24 00:21 1<0.17Tetrachloroethene 1.0 0.53 ug/L 09/12/24 00:21 1<0.53Tetrahydrofuran 1.0 0.14 ug/L 09/12/24 00:21 1<0.14Toluene 1.0 0.21 ug/L 09/12/24 00:21 1<0.21trans-1,2-Dichloroethene 1.0 0.15 ug/L 09/12/24 00:21 1<0.15trans-1,3-Dichloropropene Eurofins Raleigh Page 29 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-6Client Sample ID: Equipment Blank Matrix: GWDate Collected: 09/04/24 16:10 Date Received: 09/05/24 11:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) RL MDL <0.70 1.0 0.70 ug/L 09/12/24 00:21 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier trans-1,4-Dichloro-2-butene 1.0 0.15 ug/L 09/12/24 00:21 1<0.15Trichloroethene 1.0 0.24 ug/L 09/12/24 00:21 1<0.24Trichlorofluoromethane 5.0 0.95 ug/L 09/12/24 00:21 1<0.95Vinyl acetate 1.0 0.32 ug/L 09/12/24 00:21 1<0.32Vinyl chloride 3.0 0.45 ug/L 09/12/24 00:21 1<0.45Xylenes, Total 4-Bromofluorobenzene (Surr)74 53-136 09/12/24 00:21 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Dibromofluoromethane (Surr)103 09/12/24 00:21 167-129 Toluene-d8 (Surr)99 09/12/24 00:21 159-134 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography RL MDL 0.60 0.50 0.20 mg/L 09/14/24 21:42 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Chloride 1.0 0.40 mg/L 09/14/24 21:42 10.43 JSulfate Method: SW846 6010D - Metals (ICP) - Total Recoverable RL MDL <6.4 20 6.4 ug/L 09/09/24 05:44 09/09/24 21:43 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Arsenic 10 4.4 ug/L 09/09/24 05:44 09/09/24 21:43 1<4.4Barium 4.0 0.30 ug/L 09/09/24 05:44 09/09/24 21:43 1<0.30Beryllium 5.0 0.44 ug/L 09/09/24 05:44 09/09/24 21:43 1<0.44Cadmium 10 1.1 ug/L 09/09/24 05:44 09/09/24 21:43 1<1.1Chromium 10 1.4 ug/L 09/09/24 05:44 09/09/24 21:43 1<1.4Cobalt 20 3.2 ug/L 09/09/24 05:44 09/09/24 21:43 1<3.2Copper 100 20 ug/L 09/09/24 05:44 09/09/24 21:43 1<20Fe 10 6.6 ug/L 09/09/24 05:44 09/09/24 21:43 1<6.6Lead 10 1.3 ug/L 09/09/24 05:44 09/09/24 21:43 1<1.3Manganese 40 3.3 ug/L 09/09/24 05:44 09/09/24 21:43 1<3.3Nickel 1000 67 ug/L 09/09/24 05:44 09/09/24 21:43 1<67Potassium 10 1.5 ug/L 09/09/24 05:44 09/09/24 21:43 1<1.5Silver 50 11 ug/L 09/09/24 05:44 09/09/24 21:43 1<11Tin 10 1.0 ug/L 09/09/24 05:44 09/09/24 21:43 1<1.0Vanadium 20 8.7 ug/L 09/09/24 05:44 09/09/24 21:43 1<8.7Zinc Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable RL MDL <0.34 5.0 0.34 ug/L 09/09/24 05:44 09/09/24 23:47 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Antimony 2.5 0.99 ug/L 09/09/24 05:44 09/09/24 23:47 1<0.99Selenium 1.0 0.26 ug/L 09/09/24 05:44 09/09/24 23:47 1<0.26Thallium Method: SW846 7470A - Mercury (CVAA) RL MDL <0.080 0.20 0.080 ug/L 09/09/24 15:09 09/10/24 11:24 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Mercury General Chemistry RL MDL <2.2 5.5 2.2 mg/L 09/10/24 16:06 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Alkalinity as CaCO3 to pH 4.5 (SM 2320B-2011) 0.83 0.83 mg/L 09/11/24 15:20 1<0.83Sulfide (SM 4500 S2 F-2011) Eurofins Raleigh Page 30 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-6Client Sample ID: Equipment Blank Matrix: GWDate Collected: 09/04/24 16:10 Date Received: 09/05/24 11:00 General Chemistry (Continued) RL MDL <0.025 0.10 0.025 mg/L 09/09/24 12:58 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Nitrate as N (SM Nitrate by calc) 50 50 mg/L 09/06/24 16:28 1<50Total Dissolved Solids (SM 2540C) 0.10 0.10 mg/L 09/16/24 10:19 1<0.10Ferric Iron (SM 3500) 0.10 0.025 mg/L 09/07/24 10:44 1<0.025 HFFerrous Iron (SM 3500 FE D) 0.10 0.041 mg/L 09/09/24 10:50 1<0.041Nitrate Nitrite as N (SM 4500 NO3 F) 0.10 0.017 mg/L 09/05/24 17:41 1<0.017Nitrite as N (SM4500 NO2 F) Lab Sample ID: 752-23805-7Client Sample ID: MW-8 Matrix: GWDate Collected: 09/04/24 12:31 Date Received: 09/05/24 11:00 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) RL MDL 0.66 0.50 0.32 ug/L 09/07/24 14:07 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,4-Dioxane 4-Bromofluorobenzene (Surr)86 46-154 09/07/24 14:07 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Method: SW846 8260D - Volatile Organic Compounds by GC/MS RL MDL <0.17 1.0 0.17 ug/L 09/12/24 05:10 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,1,1,2-Tetrachloroethane 1.0 0.12 ug/L 09/12/24 05:10 1<0.121,1,1-Trichloroethane 1.0 0.28 ug/L 09/12/24 05:10 1<0.281,1,2,2-Tetrachloroethane 1.0 0.14 ug/L 09/12/24 05:10 1<0.141,1,2-Trichloroethane 1.0 0.13 ug/L 09/12/24 05:10 1<0.131,1-Dichloroethane 1.0 0.21 ug/L 09/12/24 05:10 1<0.211,1-Dichloroethene 1.0 0.15 ug/L 09/12/24 05:10 1<0.151,1-Dichloropropene 1.0 0.49 ug/L 09/12/24 05:10 1<0.491,2,3-Trichloropropane 1.0 0.14 ug/L 09/12/24 05:10 1<0.141,2,4-Trichlorobenzene 1.0 0.48 ug/L 09/12/24 05:10 1<0.481,2-Dibromo-3-Chloropropane 1.0 0.66 ug/L 09/12/24 05:10 1<0.661,2-Dibromoethane 1.0 0.19 ug/L 09/12/24 05:10 1<0.191,2-Dichlorobenzene 1.0 0.21 ug/L 09/12/24 05:10 1<0.211,2-Dichloroethane 1.0 0.10 ug/L 09/12/24 05:10 1<0.101,2-Dichloropropane 1.0 0.15 ug/L 09/12/24 05:10 1<0.151,3-Dichlorobenzene 1.0 0.16 ug/L 09/12/24 05:10 1<0.161,3-Dichloropropane 1.0 0.19 ug/L 09/12/24 05:10 1<0.191,4-Dichlorobenzene 1.0 0.28 ug/L 09/12/24 05:10 1<0.282,2-Dichloropropane 20 10 ug/L 09/12/24 05:10 1<102-Butanone (MEK) 5.0 0.88 ug/L 09/12/24 05:10 1<0.882-Hexanone 1.0 0.11 ug/L 09/12/24 05:10 1<0.113-Chloropropene 5.0 1.1 ug/L 09/12/24 05:10 1<1.14-Methyl-2-pentanone (MIBK) 20 10 ug/L 09/12/24 05:10 1<10Acetone 10 5.0 ug/L 09/12/24 05:10 1<5.0 *1Acetonitrile 10 4.0 ug/L 09/12/24 05:10 1<4.0Acrolein 10 3.5 ug/L 09/12/24 05:10 1<3.5Acrylonitrile 1.0 0.15 ug/L 09/12/24 05:10 1<0.15Benzene 1.0 0.48 ug/L 09/12/24 05:10 1<0.48Bromochloromethane 1.0 0.17 ug/L 09/12/24 05:10 1<0.17Bromodichloromethane 1.0 0.22 ug/L 09/12/24 05:10 1<0.22Bromoform Eurofins Raleigh Page 31 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-7Client Sample ID: MW-8 Matrix: GWDate Collected: 09/04/24 12:31 Date Received: 09/05/24 11:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) RL MDL <0.14 1.0 0.14 ug/L 09/12/24 05:10 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Bromomethane 5.0 1.5 ug/L 09/12/24 05:10 1<1.5Carbon disulfide 1.0 0.17 ug/L 09/12/24 05:10 1<0.17Carbon tetrachloride 1.0 0.17 ug/L 09/12/24 05:10 1<0.17Chlorobenzene 1.0 0.23 ug/L 09/12/24 05:10 1<0.23Chloroethane 1.0 0.18 ug/L 09/12/24 05:10 1<0.18Chloroform 1.0 0.13 ug/L 09/12/24 05:10 1<0.13Chloromethane 1.0 0.64 ug/L 09/12/24 05:10 1<0.64Chloroprene 1.0 0.15 ug/L 09/12/24 05:10 1<0.15cis-1,2-Dichloroethene 1.0 0.20 ug/L 09/12/24 05:10 1<0.20cis-1,3-Dichloropropene 1.0 0.17 ug/L 09/12/24 05:10 1<0.17Dibromochloromethane 1.0 0.27 ug/L 09/12/24 05:10 1<0.27Dibromomethane 1.0 0.20 ug/L 09/12/24 05:10 1<0.20Dichlorodifluoromethane 1.0 0.38 ug/L 09/12/24 05:10 1<0.38Ethyl methacrylate 1.0 0.13 ug/L 09/12/24 05:10 1<0.13Ethylbenzene 1.0 0.22 ug/L 09/12/24 05:10 1<0.22Hexachlorobutadiene 5.0 1.7 ug/L 09/12/24 05:10 1<1.7Iodomethane 50 11 ug/L 09/12/24 05:10 1<11 *1Isobutyl alcohol 10 4.9 ug/L 09/12/24 05:10 1<4.9Methacrylonitrile 1.0 0.51 ug/L 09/12/24 05:10 1<0.51Methyl methacrylate 1.0 0.23 ug/L 09/12/24 05:10 1<0.23Methylene Chloride 1.0 0.11 ug/L 09/12/24 05:10 1<0.11Naphthalene 10 5.0 ug/L 09/12/24 05:10 1<5.0Propionitrile 1.0 0.11 ug/L 09/12/24 05:10 1<0.11Styrene 1.0 0.17 ug/L 09/12/24 05:10 1<0.17Tetrachloroethene 1.0 0.53 ug/L 09/12/24 05:10 1<0.53Tetrahydrofuran 1.0 0.14 ug/L 09/12/24 05:10 1<0.14Toluene 1.0 0.21 ug/L 09/12/24 05:10 1<0.21trans-1,2-Dichloroethene 1.0 0.15 ug/L 09/12/24 05:10 1<0.15trans-1,3-Dichloropropene 1.0 0.70 ug/L 09/12/24 05:10 1<0.70trans-1,4-Dichloro-2-butene 1.0 0.15 ug/L 09/12/24 05:10 1<0.15Trichloroethene 1.0 0.24 ug/L 09/12/24 05:10 1<0.24Trichlorofluoromethane 5.0 0.95 ug/L 09/12/24 05:10 1<0.95Vinyl acetate 1.0 0.32 ug/L 09/12/24 05:10 1<0.32Vinyl chloride 3.0 0.45 ug/L 09/12/24 05:10 1<0.45Xylenes, Total 4-Bromofluorobenzene (Surr)75 53-136 09/12/24 05:10 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Dibromofluoromethane (Surr)102 09/12/24 05:10 167-129 Toluene-d8 (Surr)86 09/12/24 05:10 159-134 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography RL MDL 5.6 0.50 0.20 mg/L 09/14/24 21:48 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Chloride 1.0 0.40 mg/L 09/14/24 21:48 14.4Sulfate Method: SW846 6010D - Metals (ICP) - Total Recoverable RL MDL <6.4 20 6.4 ug/L 09/09/24 05:44 09/09/24 21:41 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Arsenic 10 4.4 ug/L 09/09/24 05:44 09/09/24 21:41 121Barium Eurofins Raleigh Page 32 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-7Client Sample ID: MW-8 Matrix: GWDate Collected: 09/04/24 12:31 Date Received: 09/05/24 11:00 Method: SW846 6010D - Metals (ICP) - Total Recoverable (Continued) RL MDL <0.30 4.0 0.30 ug/L 09/09/24 05:44 09/09/24 21:41 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Beryllium 5.0 0.44 ug/L 09/09/24 05:44 09/09/24 21:41 1<0.44Cadmium 10 1.1 ug/L 09/09/24 05:44 09/09/24 21:41 1<1.1Chromium 10 1.4 ug/L 09/09/24 05:44 09/09/24 21:41 1<1.4Cobalt 20 3.2 ug/L 09/09/24 05:44 09/09/24 21:41 1<3.2Copper 100 20 ug/L 09/09/24 05:44 09/09/24 21:41 1510Fe 10 6.6 ug/L 09/09/24 05:44 09/09/24 21:41 1<6.6Lead 10 1.3 ug/L 09/09/24 05:44 09/09/24 21:41 1360Manganese 40 3.3 ug/L 09/09/24 05:44 09/09/24 21:41 1<3.3Nickel 1000 67 ug/L 09/09/24 05:44 09/09/24 21:41 1510J BPotassium 10 1.5 ug/L 09/09/24 05:44 09/09/24 21:41 1<1.5Silver 50 11 ug/L 09/09/24 05:44 09/09/24 21:41 1<11Tin 10 1.0 ug/L 09/09/24 05:44 09/09/24 21:41 11.3 JVanadium 20 8.7 ug/L 09/09/24 05:44 09/09/24 21:41 1<8.7Zinc Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable RL MDL <0.34 5.0 0.34 ug/L 09/09/24 05:44 09/09/24 23:44 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Antimony 2.5 0.99 ug/L 09/09/24 05:44 09/09/24 23:44 1<0.99Selenium 1.0 0.26 ug/L 09/09/24 05:44 09/09/24 23:44 1<0.26Thallium Method: SW846 7470A - Mercury (CVAA) RL MDL <0.080 0.20 0.080 ug/L 09/10/24 10:23 09/10/24 15:37 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Mercury General Chemistry RL MDL 45 5.5 2.2 mg/L 09/10/24 17:03 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Alkalinity as CaCO3 to pH 4.5 (SM 2320B-2011) 0.81 0.81 mg/L 09/11/24 15:20 1<0.81Sulfide (SM 4500 S2 F-2011) 0.10 0.025 mg/L 09/09/24 12:58 1<0.025Nitrate as N (SM Nitrate by calc) 50 50 mg/L 09/06/24 16:28 162 0.10 0.10 mg/L 09/16/24 10:19 10.45Ferric Iron (SM 3500) 0.10 0.025 mg/L 09/07/24 10:38 10.062 J HFFerrous Iron (SM 3500 FE D) 0.10 0.041 mg/L 09/09/24 10:52 1<0.041Nitrate Nitrite as N (SM 4500 NO3 F) 0.10 0.017 mg/L 09/05/24 17:41 1<0.017Nitrite as N (SM4500 NO2 F) Lab Sample ID: 752-23805-8Client Sample ID: MW-15 Matrix: GWDate Collected: 09/04/24 12:42 Date Received: 09/05/24 11:00 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) RL MDL <0.32 0.50 0.32 ug/L 09/07/24 14:33 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,4-Dioxane 4-Bromofluorobenzene (Surr)84 46-154 09/07/24 14:33 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Method: SW846 8260D - Volatile Organic Compounds by GC/MS RL MDL <0.17 1.0 0.17 ug/L 09/12/24 05:32 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,1,1,2-Tetrachloroethane Eurofins Raleigh Page 33 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-8Client Sample ID: MW-15 Matrix: GWDate Collected: 09/04/24 12:42 Date Received: 09/05/24 11:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) RL MDL <0.12 1.0 0.12 ug/L 09/12/24 05:32 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,1,1-Trichloroethane 1.0 0.28 ug/L 09/12/24 05:32 1<0.281,1,2,2-Tetrachloroethane 1.0 0.14 ug/L 09/12/24 05:32 1<0.141,1,2-Trichloroethane 1.0 0.13 ug/L 09/12/24 05:32 1<0.131,1-Dichloroethane 1.0 0.21 ug/L 09/12/24 05:32 1<0.211,1-Dichloroethene 1.0 0.15 ug/L 09/12/24 05:32 1<0.151,1-Dichloropropene 1.0 0.49 ug/L 09/12/24 05:32 1<0.491,2,3-Trichloropropane 1.0 0.14 ug/L 09/12/24 05:32 1<0.141,2,4-Trichlorobenzene 1.0 0.48 ug/L 09/12/24 05:32 1<0.481,2-Dibromo-3-Chloropropane 1.0 0.66 ug/L 09/12/24 05:32 1<0.661,2-Dibromoethane 1.0 0.19 ug/L 09/12/24 05:32 1<0.191,2-Dichlorobenzene 1.0 0.21 ug/L 09/12/24 05:32 1<0.211,2-Dichloroethane 1.0 0.10 ug/L 09/12/24 05:32 1<0.101,2-Dichloropropane 1.0 0.15 ug/L 09/12/24 05:32 1<0.151,3-Dichlorobenzene 1.0 0.16 ug/L 09/12/24 05:32 1<0.161,3-Dichloropropane 1.0 0.19 ug/L 09/12/24 05:32 1<0.191,4-Dichlorobenzene 1.0 0.28 ug/L 09/12/24 05:32 1<0.282,2-Dichloropropane 20 10 ug/L 09/12/24 05:32 1<102-Butanone (MEK) 5.0 0.88 ug/L 09/12/24 05:32 1<0.882-Hexanone 1.0 0.11 ug/L 09/12/24 05:32 1<0.113-Chloropropene 5.0 1.1 ug/L 09/12/24 05:32 1<1.14-Methyl-2-pentanone (MIBK) 20 10 ug/L 09/12/24 05:32 1<10Acetone 10 5.0 ug/L 09/12/24 05:32 1<5.0 *1Acetonitrile 10 4.0 ug/L 09/12/24 05:32 1<4.0Acrolein 10 3.5 ug/L 09/12/24 05:32 1<3.5Acrylonitrile 1.0 0.15 ug/L 09/12/24 05:32 1<0.15Benzene 1.0 0.48 ug/L 09/12/24 05:32 1<0.48Bromochloromethane 1.0 0.17 ug/L 09/12/24 05:32 1<0.17Bromodichloromethane 1.0 0.22 ug/L 09/12/24 05:32 1<0.22Bromoform 1.0 0.14 ug/L 09/12/24 05:32 1<0.14Bromomethane 5.0 1.5 ug/L 09/12/24 05:32 1<1.5Carbon disulfide 1.0 0.17 ug/L 09/12/24 05:32 1<0.17Carbon tetrachloride 1.0 0.17 ug/L 09/12/24 05:32 1<0.17Chlorobenzene 1.0 0.23 ug/L 09/12/24 05:32 1<0.23Chloroethane 1.0 0.18 ug/L 09/12/24 05:32 1<0.18Chloroform 1.0 0.13 ug/L 09/12/24 05:32 1<0.13Chloromethane 1.0 0.64 ug/L 09/12/24 05:32 1<0.64Chloroprene 1.0 0.15 ug/L 09/12/24 05:32 1<0.15cis-1,2-Dichloroethene 1.0 0.20 ug/L 09/12/24 05:32 1<0.20cis-1,3-Dichloropropene 1.0 0.17 ug/L 09/12/24 05:32 1<0.17Dibromochloromethane 1.0 0.27 ug/L 09/12/24 05:32 1<0.27Dibromomethane 1.0 0.20 ug/L 09/12/24 05:32 1<0.20Dichlorodifluoromethane 1.0 0.38 ug/L 09/12/24 05:32 1<0.38Ethyl methacrylate 1.0 0.13 ug/L 09/12/24 05:32 1<0.13Ethylbenzene 1.0 0.22 ug/L 09/12/24 05:32 1<0.22Hexachlorobutadiene 5.0 1.7 ug/L 09/12/24 05:32 1<1.7Iodomethane 50 11 ug/L 09/12/24 05:32 1<11 *1Isobutyl alcohol 10 4.9 ug/L 09/12/24 05:32 1<4.9Methacrylonitrile 1.0 0.51 ug/L 09/12/24 05:32 1<0.51Methyl methacrylate Eurofins Raleigh Page 34 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-8Client Sample ID: MW-15 Matrix: GWDate Collected: 09/04/24 12:42 Date Received: 09/05/24 11:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) RL MDL <0.23 1.0 0.23 ug/L 09/12/24 05:32 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Methylene Chloride 1.0 0.11 ug/L 09/12/24 05:32 1<0.11Naphthalene 10 5.0 ug/L 09/12/24 05:32 1<5.0Propionitrile 1.0 0.11 ug/L 09/12/24 05:32 1<0.11Styrene 1.0 0.17 ug/L 09/12/24 05:32 1<0.17Tetrachloroethene 1.0 0.53 ug/L 09/12/24 05:32 1<0.53Tetrahydrofuran 1.0 0.14 ug/L 09/12/24 05:32 1<0.14Toluene 1.0 0.21 ug/L 09/12/24 05:32 1<0.21trans-1,2-Dichloroethene 1.0 0.15 ug/L 09/12/24 05:32 1<0.15trans-1,3-Dichloropropene 1.0 0.70 ug/L 09/12/24 05:32 1<0.70trans-1,4-Dichloro-2-butene 1.0 0.15 ug/L 09/12/24 05:32 1<0.15Trichloroethene 1.0 0.24 ug/L 09/12/24 05:32 1<0.24Trichlorofluoromethane 5.0 0.95 ug/L 09/12/24 05:32 1<0.95Vinyl acetate 1.0 0.32 ug/L 09/12/24 05:32 1<0.32Vinyl chloride 3.0 0.45 ug/L 09/12/24 05:32 1<0.45Xylenes, Total 4-Bromofluorobenzene (Surr)90 53-136 09/12/24 05:32 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Dibromofluoromethane (Surr)112 09/12/24 05:32 167-129 Toluene-d8 (Surr)78 09/12/24 05:32 159-134 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography RL MDL 6.9 0.50 0.20 mg/L 09/14/24 21:55 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Chloride 1.0 0.40 mg/L 09/14/24 21:55 15.5Sulfate Method: SW846 6010D - Metals (ICP) - Total Recoverable RL MDL <6.4 20 6.4 ug/L 09/09/24 05:44 09/09/24 21:38 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Arsenic 10 4.4 ug/L 09/09/24 05:44 09/09/24 21:38 121Barium 4.0 0.30 ug/L 09/09/24 05:44 09/09/24 21:38 1<0.30Beryllium 5.0 0.44 ug/L 09/09/24 05:44 09/09/24 21:38 1<0.44Cadmium 10 1.1 ug/L 09/09/24 05:44 09/09/24 21:38 1<1.1Chromium 10 1.4 ug/L 09/09/24 05:44 09/09/24 21:38 1<1.4Cobalt 20 3.2 ug/L 09/09/24 05:44 09/09/24 21:38 13.2 JCopper 100 20 ug/L 09/09/24 05:44 09/09/24 21:38 1340Fe 10 6.6 ug/L 09/09/24 05:44 09/09/24 21:38 1<6.6Lead 10 1.3 ug/L 09/09/24 05:44 09/09/24 21:38 1440Manganese 40 3.3 ug/L 09/09/24 05:44 09/09/24 21:38 1<3.3Nickel 1000 67 ug/L 09/09/24 05:44 09/09/24 21:38 11500BPotassium 10 1.5 ug/L 09/09/24 05:44 09/09/24 21:38 1<1.5Silver 50 11 ug/L 09/09/24 05:44 09/09/24 21:38 1<11Tin 10 1.0 ug/L 09/09/24 05:44 09/09/24 21:38 11.1 JVanadium 20 8.7 ug/L 09/09/24 05:44 09/09/24 21:38 1<8.7Zinc Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable RL MDL <0.34 5.0 0.34 ug/L 09/09/24 05:44 09/09/24 23:42 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Antimony 2.5 0.99 ug/L 09/09/24 05:44 09/09/24 23:42 1<0.99Selenium 1.0 0.26 ug/L 09/09/24 05:44 09/09/24 23:42 1<0.26Thallium Eurofins Raleigh Page 35 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-8Client Sample ID: MW-15 Matrix: GWDate Collected: 09/04/24 12:42 Date Received: 09/05/24 11:00 Method: SW846 7470A - Mercury (CVAA) RL MDL <0.080 0.20 0.080 ug/L 09/10/24 10:23 09/10/24 15:26 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Mercury General Chemistry RL MDL 75 5.5 2.2 mg/L 09/10/24 16:55 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Alkalinity as CaCO3 to pH 4.5 (SM 2320B-2011) 0.83 0.83 mg/L 09/11/24 15:20 1<0.83Sulfide (SM 4500 S2 F-2011) 0.10 0.025 mg/L 09/09/24 12:58 1<0.025Nitrate as N (SM Nitrate by calc) 50 50 mg/L 09/06/24 16:28 1100 0.10 0.10 mg/L 09/16/24 10:19 10.34Ferric Iron (SM 3500) 0.10 0.025 mg/L 09/07/24 10:38 1<0.025 HFFerrous Iron (SM 3500 FE D) 0.10 0.041 mg/L 09/09/24 10:53 1<0.041Nitrate Nitrite as N (SM 4500 NO3 F) 0.10 0.017 mg/L 09/05/24 17:42 1<0.017Nitrite as N (SM4500 NO2 F) Lab Sample ID: 752-23805-9Client Sample ID: MW-16 Matrix: GWDate Collected: 09/04/24 15:33 Date Received: 09/05/24 11:00 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) RL MDL <0.32 0.50 0.32 ug/L 09/07/24 14:59 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,4-Dioxane 4-Bromofluorobenzene (Surr)75 46-154 09/07/24 14:59 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Method: SW846 8260D - Volatile Organic Compounds by GC/MS RL MDL <0.17 1.0 0.17 ug/L 09/12/24 05:54 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,1,1,2-Tetrachloroethane 1.0 0.12 ug/L 09/12/24 05:54 1<0.121,1,1-Trichloroethane 1.0 0.28 ug/L 09/12/24 05:54 1<0.281,1,2,2-Tetrachloroethane 1.0 0.14 ug/L 09/12/24 05:54 1<0.141,1,2-Trichloroethane 1.0 0.13 ug/L 09/12/24 05:54 1<0.131,1-Dichloroethane 1.0 0.21 ug/L 09/12/24 05:54 1<0.211,1-Dichloroethene 1.0 0.15 ug/L 09/12/24 05:54 1<0.151,1-Dichloropropene 1.0 0.49 ug/L 09/12/24 05:54 1<0.491,2,3-Trichloropropane 1.0 0.14 ug/L 09/12/24 05:54 1<0.141,2,4-Trichlorobenzene 1.0 0.48 ug/L 09/12/24 05:54 1<0.481,2-Dibromo-3-Chloropropane 1.0 0.66 ug/L 09/12/24 05:54 1<0.661,2-Dibromoethane 1.0 0.19 ug/L 09/12/24 05:54 1<0.191,2-Dichlorobenzene 1.0 0.21 ug/L 09/12/24 05:54 1<0.211,2-Dichloroethane 1.0 0.10 ug/L 09/12/24 05:54 1<0.101,2-Dichloropropane 1.0 0.15 ug/L 09/12/24 05:54 1<0.151,3-Dichlorobenzene 1.0 0.16 ug/L 09/12/24 05:54 1<0.161,3-Dichloropropane 1.0 0.19 ug/L 09/12/24 05:54 1<0.191,4-Dichlorobenzene 1.0 0.28 ug/L 09/12/24 05:54 1<0.282,2-Dichloropropane 20 10 ug/L 09/12/24 05:54 1<102-Butanone (MEK) 5.0 0.88 ug/L 09/12/24 05:54 1<0.882-Hexanone 1.0 0.11 ug/L 09/12/24 05:54 1<0.113-Chloropropene 5.0 1.1 ug/L 09/12/24 05:54 1<1.14-Methyl-2-pentanone (MIBK) 20 10 ug/L 09/12/24 05:54 1<10Acetone 10 5.0 ug/L 09/12/24 05:54 1<5.0 *1Acetonitrile Eurofins Raleigh Page 36 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-9Client Sample ID: MW-16 Matrix: GWDate Collected: 09/04/24 15:33 Date Received: 09/05/24 11:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) RL MDL <4.0 10 4.0 ug/L 09/12/24 05:54 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Acrolein 10 3.5 ug/L 09/12/24 05:54 1<3.5Acrylonitrile 1.0 0.15 ug/L 09/12/24 05:54 1<0.15Benzene 1.0 0.48 ug/L 09/12/24 05:54 1<0.48Bromochloromethane 1.0 0.17 ug/L 09/12/24 05:54 1<0.17Bromodichloromethane 1.0 0.22 ug/L 09/12/24 05:54 1<0.22Bromoform 1.0 0.14 ug/L 09/12/24 05:54 1<0.14Bromomethane 5.0 1.5 ug/L 09/12/24 05:54 1<1.5Carbon disulfide 1.0 0.17 ug/L 09/12/24 05:54 1<0.17Carbon tetrachloride 1.0 0.17 ug/L 09/12/24 05:54 1<0.17Chlorobenzene 1.0 0.23 ug/L 09/12/24 05:54 1<0.23Chloroethane 1.0 0.18 ug/L 09/12/24 05:54 1<0.18Chloroform 1.0 0.13 ug/L 09/12/24 05:54 1<0.13Chloromethane 1.0 0.64 ug/L 09/12/24 05:54 1<0.64Chloroprene 1.0 0.15 ug/L 09/12/24 05:54 1<0.15cis-1,2-Dichloroethene 1.0 0.20 ug/L 09/12/24 05:54 1<0.20cis-1,3-Dichloropropene 1.0 0.17 ug/L 09/12/24 05:54 1<0.17Dibromochloromethane 1.0 0.27 ug/L 09/12/24 05:54 1<0.27Dibromomethane 1.0 0.20 ug/L 09/12/24 05:54 1<0.20Dichlorodifluoromethane 1.0 0.38 ug/L 09/12/24 05:54 1<0.38Ethyl methacrylate 1.0 0.13 ug/L 09/12/24 05:54 1<0.13Ethylbenzene 1.0 0.22 ug/L 09/12/24 05:54 1<0.22Hexachlorobutadiene 5.0 1.7 ug/L 09/12/24 05:54 1<1.7Iodomethane 50 11 ug/L 09/12/24 05:54 1<11 *1Isobutyl alcohol 10 4.9 ug/L 09/12/24 05:54 1<4.9Methacrylonitrile 1.0 0.51 ug/L 09/12/24 05:54 1<0.51Methyl methacrylate 1.0 0.23 ug/L 09/12/24 05:54 1<0.23Methylene Chloride 1.0 0.11 ug/L 09/12/24 05:54 1<0.11Naphthalene 10 5.0 ug/L 09/12/24 05:54 1<5.0Propionitrile 1.0 0.11 ug/L 09/12/24 05:54 1<0.11Styrene 1.0 0.17 ug/L 09/12/24 05:54 1<0.17Tetrachloroethene 1.0 0.53 ug/L 09/12/24 05:54 1<0.53Tetrahydrofuran 1.0 0.14 ug/L 09/12/24 05:54 1<0.14Toluene 1.0 0.21 ug/L 09/12/24 05:54 1<0.21trans-1,2-Dichloroethene 1.0 0.15 ug/L 09/12/24 05:54 1<0.15trans-1,3-Dichloropropene 1.0 0.70 ug/L 09/12/24 05:54 1<0.70trans-1,4-Dichloro-2-butene 1.0 0.15 ug/L 09/12/24 05:54 1<0.15Trichloroethene 1.0 0.24 ug/L 09/12/24 05:54 1<0.24Trichlorofluoromethane 5.0 0.95 ug/L 09/12/24 05:54 1<0.95Vinyl acetate 1.0 0.32 ug/L 09/12/24 05:54 1<0.32Vinyl chloride 3.0 0.45 ug/L 09/12/24 05:54 1<0.45Xylenes, Total 4-Bromofluorobenzene (Surr)62 53-136 09/12/24 05:54 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Dibromofluoromethane (Surr)113 09/12/24 05:54 167-129 Toluene-d8 (Surr)85 09/12/24 05:54 159-134 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography RL MDL 16 0.50 0.20 mg/L 09/14/24 22:01 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Chloride Eurofins Raleigh Page 37 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-9Client Sample ID: MW-16 Matrix: GWDate Collected: 09/04/24 15:33 Date Received: 09/05/24 11:00 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography (Continued) RL MDL 11 1.0 0.40 mg/L 09/14/24 22:01 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Sulfate Method: SW846 6010D - Metals (ICP) - Total Recoverable RL MDL <6.4 20 6.4 ug/L 09/09/24 05:44 09/09/24 21:36 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Arsenic 10 4.4 ug/L 09/09/24 05:44 09/09/24 21:36 167Barium 4.0 0.30 ug/L 09/09/24 05:44 09/09/24 21:36 1<0.30Beryllium 5.0 0.44 ug/L 09/09/24 05:44 09/09/24 21:36 1<0.44Cadmium 10 1.1 ug/L 09/09/24 05:44 09/09/24 21:36 1<1.1Chromium 10 1.4 ug/L 09/09/24 05:44 09/09/24 21:36 14.0 JCobalt 20 3.2 ug/L 09/09/24 05:44 09/09/24 21:36 13.2 JCopper 100 20 ug/L 09/09/24 05:44 09/09/24 21:36 1450Fe 10 6.6 ug/L 09/09/24 05:44 09/09/24 21:36 1<6.6Lead 10 1.3 ug/L 09/09/24 05:44 09/09/24 21:36 11300Manganese 40 3.3 ug/L 09/09/24 05:44 09/09/24 21:36 1<3.3Nickel 1000 67 ug/L 09/09/24 05:44 09/09/24 21:36 14100BPotassium 10 1.5 ug/L 09/09/24 05:44 09/09/24 21:36 1<1.5Silver 50 11 ug/L 09/09/24 05:44 09/09/24 21:36 1<11Tin 10 1.0 ug/L 09/09/24 05:44 09/09/24 21:36 11.1 JVanadium 20 8.7 ug/L 09/09/24 05:44 09/09/24 21:36 112JZinc Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable RL MDL <0.34 5.0 0.34 ug/L 09/09/24 05:44 09/09/24 23:39 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Antimony 2.5 0.99 ug/L 09/09/24 05:44 09/09/24 23:39 1<0.99Selenium 1.0 0.26 ug/L 09/09/24 05:44 09/09/24 23:39 1<0.26Thallium Method: SW846 7470A - Mercury (CVAA) RL MDL <0.080 0.20 0.080 ug/L 09/10/24 10:23 09/10/24 15:24 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Mercury General Chemistry RL MDL 70 5.5 2.2 mg/L 09/12/24 16:12 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Alkalinity as CaCO3 to pH 4.5 (SM 2320B-2011) 0.83 0.83 mg/L 09/11/24 15:20 11.1Sulfide (SM 4500 S2 F-2011) 0.10 0.025 mg/L 09/09/24 12:58 17.8Nitrate as N (SM Nitrate by calc) 50 50 mg/L 09/06/24 16:28 1180 0.10 0.10 mg/L 09/16/24 10:19 10.40Ferric Iron (SM 3500) 0.10 0.025 mg/L 09/07/24 10:38 10.052 J HFFerrous Iron (SM 3500 FE D) 1.0 0.41 mg/L 09/09/24 13:42 107.8Nitrate Nitrite as N (SM 4500 NO3 F) 0.10 0.017 mg/L 09/05/24 17:43 1<0.017Nitrite as N (SM4500 NO2 F) Lab Sample ID: 752-23805-10Client Sample ID: SW-1 Matrix: Surface WaterDate Collected: 09/04/24 11:00 Date Received: 09/05/24 11:00 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) RL MDL 7.3 0.50 0.32 ug/L 09/07/24 15:24 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,4-Dioxane Eurofins Raleigh Page 38 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-10Client Sample ID: SW-1 Matrix: Surface WaterDate Collected: 09/04/24 11:00 Date Received: 09/05/24 11:00 4-Bromofluorobenzene (Surr)77 46-154 09/07/24 15:24 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Method: SW846 8260D - Volatile Organic Compounds by GC/MS RL MDL <0.17 1.0 0.17 ug/L 09/12/24 06:16 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,1,1,2-Tetrachloroethane 1.0 0.12 ug/L 09/12/24 06:16 1<0.121,1,1-Trichloroethane 1.0 0.28 ug/L 09/12/24 06:16 1<0.281,1,2,2-Tetrachloroethane 1.0 0.14 ug/L 09/12/24 06:16 1<0.141,1,2-Trichloroethane 1.0 0.13 ug/L 09/12/24 06:16 1<0.131,1-Dichloroethane 1.0 0.21 ug/L 09/12/24 06:16 1<0.211,1-Dichloroethene 1.0 0.15 ug/L 09/12/24 06:16 1<0.151,1-Dichloropropene 1.0 0.49 ug/L 09/12/24 06:16 1<0.491,2,3-Trichloropropane 1.0 0.14 ug/L 09/12/24 06:16 1<0.141,2,4-Trichlorobenzene 1.0 0.48 ug/L 09/12/24 06:16 1<0.481,2-Dibromo-3-Chloropropane 1.0 0.66 ug/L 09/12/24 06:16 1<0.661,2-Dibromoethane 1.0 0.19 ug/L 09/12/24 06:16 1<0.191,2-Dichlorobenzene 1.0 0.21 ug/L 09/12/24 06:16 1<0.211,2-Dichloroethane 1.0 0.10 ug/L 09/12/24 06:16 1<0.101,2-Dichloropropane 1.0 0.15 ug/L 09/12/24 06:16 1<0.151,3-Dichlorobenzene 1.0 0.16 ug/L 09/12/24 06:16 1<0.161,3-Dichloropropane 1.0 0.19 ug/L 09/12/24 06:16 1<0.191,4-Dichlorobenzene 1.0 0.28 ug/L 09/12/24 06:16 1<0.282,2-Dichloropropane 20 10 ug/L 09/12/24 06:16 1<102-Butanone (MEK) 5.0 0.88 ug/L 09/12/24 06:16 1<0.882-Hexanone 1.0 0.11 ug/L 09/12/24 06:16 1<0.113-Chloropropene 5.0 1.1 ug/L 09/12/24 06:16 1<1.14-Methyl-2-pentanone (MIBK) 20 10 ug/L 09/12/24 06:16 1<10Acetone 10 5.0 ug/L 09/12/24 06:16 1<5.0 *1Acetonitrile 10 4.0 ug/L 09/12/24 06:16 1<4.0Acrolein 10 3.5 ug/L 09/12/24 06:16 1<3.5Acrylonitrile 1.0 0.15 ug/L 09/12/24 06:16 1<0.15Benzene 1.0 0.48 ug/L 09/12/24 06:16 1<0.48Bromochloromethane 1.0 0.17 ug/L 09/12/24 06:16 1<0.17Bromodichloromethane 1.0 0.22 ug/L 09/12/24 06:16 1<0.22Bromoform 1.0 0.14 ug/L 09/12/24 06:16 1<0.14Bromomethane 5.0 1.5 ug/L 09/12/24 06:16 1<1.5Carbon disulfide 1.0 0.17 ug/L 09/12/24 06:16 1<0.17Carbon tetrachloride 1.0 0.17 ug/L 09/12/24 06:16 1<0.17Chlorobenzene 1.0 0.23 ug/L 09/12/24 06:16 1<0.23Chloroethane 1.0 0.18 ug/L 09/12/24 06:16 1<0.18Chloroform 1.0 0.13 ug/L 09/12/24 06:16 1<0.13Chloromethane 1.0 0.64 ug/L 09/12/24 06:16 1<0.64Chloroprene 1.0 0.15 ug/L 09/12/24 06:16 1<0.15cis-1,2-Dichloroethene 1.0 0.20 ug/L 09/12/24 06:16 1<0.20cis-1,3-Dichloropropene 1.0 0.17 ug/L 09/12/24 06:16 1<0.17Dibromochloromethane 1.0 0.27 ug/L 09/12/24 06:16 1<0.27Dibromomethane 1.0 0.20 ug/L 09/12/24 06:16 1<0.20Dichlorodifluoromethane 1.0 0.38 ug/L 09/12/24 06:16 1<0.38Ethyl methacrylate 1.0 0.13 ug/L 09/12/24 06:16 1<0.13Ethylbenzene 1.0 0.22 ug/L 09/12/24 06:16 1<0.22Hexachlorobutadiene Eurofins Raleigh Page 39 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-10Client Sample ID: SW-1 Matrix: Surface WaterDate Collected: 09/04/24 11:00 Date Received: 09/05/24 11:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) RL MDL <1.7 5.0 1.7 ug/L 09/12/24 06:16 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Iodomethane 50 11 ug/L 09/12/24 06:16 1<11 *1Isobutyl alcohol 10 4.9 ug/L 09/12/24 06:16 1<4.9Methacrylonitrile 1.0 0.51 ug/L 09/12/24 06:16 1<0.51Methyl methacrylate 1.0 0.23 ug/L 09/12/24 06:16 1<0.23Methylene Chloride 1.0 0.11 ug/L 09/12/24 06:16 1<0.11Naphthalene 10 5.0 ug/L 09/12/24 06:16 1<5.0Propionitrile 1.0 0.11 ug/L 09/12/24 06:16 1<0.11Styrene 1.0 0.17 ug/L 09/12/24 06:16 1<0.17Tetrachloroethene 1.0 0.53 ug/L 09/12/24 06:16 1<0.53Tetrahydrofuran 1.0 0.14 ug/L 09/12/24 06:16 10.33 JToluene 1.0 0.21 ug/L 09/12/24 06:16 1<0.21trans-1,2-Dichloroethene 1.0 0.15 ug/L 09/12/24 06:16 1<0.15trans-1,3-Dichloropropene 1.0 0.70 ug/L 09/12/24 06:16 1<0.70trans-1,4-Dichloro-2-butene 1.0 0.15 ug/L 09/12/24 06:16 1<0.15Trichloroethene 1.0 0.24 ug/L 09/12/24 06:16 1<0.24Trichlorofluoromethane 5.0 0.95 ug/L 09/12/24 06:16 1<0.95Vinyl acetate 1.0 0.32 ug/L 09/12/24 06:16 1<0.32Vinyl chloride 3.0 0.45 ug/L 09/12/24 06:16 1<0.45Xylenes, Total 4-Bromofluorobenzene (Surr)70 53-136 09/12/24 06:16 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Dibromofluoromethane (Surr)106 09/12/24 06:16 167-129 Toluene-d8 (Surr)88 09/12/24 06:16 159-134 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography RL MDL 41 0.50 0.20 mg/L 09/14/24 22:08 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Chloride 1.0 0.40 mg/L 09/14/24 22:08 19.0Sulfate Method: SM 2340B-2011 - Total Hardness (as CaCO3) by calculation RL MDL 76 3.3 3.3 mg/L 09/17/24 12:06 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Hardness as calcium carbonate Method: SW846 6010D - Metals (ICP) - Total Recoverable RL MDL <6.4 20 6.4 ug/L 09/09/24 05:44 09/09/24 21:33 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Arsenic 10 4.4 ug/L 09/09/24 05:44 09/09/24 21:33 169Barium 4.0 0.30 ug/L 09/09/24 05:44 09/09/24 21:33 1<0.30Beryllium 5.0 0.44 ug/L 09/09/24 05:44 09/09/24 21:33 1<0.44Cadmium 10 1.1 ug/L 09/09/24 05:44 09/09/24 21:33 1<1.1Chromium 10 1.4 ug/L 09/09/24 05:44 09/09/24 21:33 126Cobalt 20 3.2 ug/L 09/09/24 05:44 09/09/24 21:33 1<3.2Copper 100 20 ug/L 09/09/24 05:44 09/09/24 21:33 14900Fe 10 6.6 ug/L 09/09/24 05:44 09/09/24 21:33 1<6.6Lead 10 1.3 ug/L 09/09/24 05:44 09/09/24 21:33 14500Manganese 40 3.3 ug/L 09/09/24 05:44 09/09/24 21:33 1<3.3Nickel 1000 67 ug/L 09/09/24 05:44 09/09/24 21:33 12800BPotassium 10 1.5 ug/L 09/09/24 05:44 09/09/24 21:33 1<1.5Silver 50 11 ug/L 09/09/24 05:44 09/09/24 21:33 1<11Tin Eurofins Raleigh Page 40 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23805-10Client Sample ID: SW-1 Matrix: Surface WaterDate Collected: 09/04/24 11:00 Date Received: 09/05/24 11:00 Method: SW846 6010D - Metals (ICP) - Total Recoverable (Continued) RL MDL <1.0 10 1.0 ug/L 09/09/24 05:44 09/09/24 21:33 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Vanadium 20 8.7 ug/L 09/09/24 05:44 09/09/24 21:33 121Zinc Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable RL MDL <0.34 5.0 0.34 ug/L 09/09/24 05:44 09/09/24 23:31 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Antimony 2.5 0.99 ug/L 09/09/24 05:44 09/09/24 23:31 1<0.99Selenium 1.0 0.26 ug/L 09/09/24 05:44 09/09/24 23:31 1<0.26Thallium Method: SW846 7470A - Mercury (CVAA) RL MDL <0.080 0.20 0.080 ug/L 09/10/24 10:23 09/10/24 15:22 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Mercury General Chemistry RL MDL 83 5.5 2.2 mg/L 09/12/24 16:03 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Alkalinity as CaCO3 to pH 4.5 (SM 2320B-2011) 0.86 0.86 mg/L 09/10/24 13:15 1<0.86Sulfide (SM 4500 S2 F-2011) 0.10 0.025 mg/L 09/09/24 12:58 1<0.025Nitrate as N (SM Nitrate by calc) 50 50 mg/L 09/06/24 16:28 1170 0.10 0.10 mg/L 09/16/24 10:19 14.8Ferric Iron (SM 3500) 0.10 0.025 mg/L 09/07/24 10:38 10.058 J HFFerrous Iron (SM 3500 FE D) 0.10 0.041 mg/L 09/09/24 11:23 1<0.041Nitrate Nitrite as N (SM 4500 NO3 F) 0.10 0.017 mg/L 09/05/24 17:44 1<0.017Nitrite as N (SM4500 NO2 F) Lab Sample ID: 752-23869-1Client Sample ID: MW-17 Matrix: WaterDate Collected: 09/05/24 10:51 Date Received: 09/06/24 09:30 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) RL MDL <0.32 0.50 0.32 ug/L 09/07/24 18:37 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,4-Dioxane 4-Bromofluorobenzene (Surr)100 46-154 09/07/24 18:37 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Method: SW846 8260D - Volatile Organic Compounds by GC/MS RL MDL <0.17 1.0 0.17 ug/L 09/13/24 05:12 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,1,1,2-Tetrachloroethane 1.0 0.12 ug/L 09/13/24 05:12 1<0.121,1,1-Trichloroethane 1.0 0.28 ug/L 09/13/24 05:12 1<0.281,1,2,2-Tetrachloroethane 1.0 0.14 ug/L 09/13/24 05:12 1<0.141,1,2-Trichloroethane 1.0 0.13 ug/L 09/13/24 05:12 1<0.131,1-Dichloroethane 1.0 0.21 ug/L 09/13/24 05:12 1<0.211,1-Dichloroethene 1.0 0.15 ug/L 09/13/24 05:12 1<0.151,1-Dichloropropene 1.0 0.49 ug/L 09/13/24 05:12 1<0.491,2,3-Trichloropropane 1.0 0.14 ug/L 09/13/24 05:12 1<0.141,2,4-Trichlorobenzene 1.0 0.48 ug/L 09/13/24 05:12 1<0.48 *11,2-Dibromo-3-Chloropropane 1.0 0.66 ug/L 09/13/24 05:12 1<0.661,2-Dibromoethane 1.0 0.19 ug/L 09/13/24 05:12 1<0.191,2-Dichlorobenzene 1.0 0.21 ug/L 09/13/24 05:12 1<0.211,2-Dichloroethane Eurofins Raleigh Page 41 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23869-1Client Sample ID: MW-17 Matrix: WaterDate Collected: 09/05/24 10:51 Date Received: 09/06/24 09:30 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) RL MDL <0.10 1.0 0.10 ug/L 09/13/24 05:12 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,2-Dichloropropane 1.0 0.15 ug/L 09/13/24 05:12 1<0.151,3-Dichlorobenzene 1.0 0.16 ug/L 09/13/24 05:12 1<0.161,3-Dichloropropane 1.0 0.19 ug/L 09/13/24 05:12 1<0.191,4-Dichlorobenzene 1.0 0.28 ug/L 09/13/24 05:12 1<0.282,2-Dichloropropane 20 10 ug/L 09/13/24 05:12 1<102-Butanone (MEK) 5.0 0.88 ug/L 09/13/24 05:12 1<0.882-Hexanone 1.0 0.11 ug/L 09/13/24 05:12 1<0.113-Chloropropene 5.0 1.1 ug/L 09/13/24 05:12 1<1.14-Methyl-2-pentanone (MIBK) 20 10 ug/L 09/13/24 05:12 1<10Acetone 10 5.0 ug/L 09/13/24 05:12 1<5.0Acetonitrile 10 4.0 ug/L 09/13/24 05:12 1<4.0Acrolein 10 3.5 ug/L 09/13/24 05:12 1<3.5Acrylonitrile 1.0 0.15 ug/L 09/13/24 05:12 1<0.15Benzene 1.0 0.48 ug/L 09/13/24 05:12 1<0.48Bromochloromethane 1.0 0.17 ug/L 09/13/24 05:12 1<0.17Bromodichloromethane 1.0 0.22 ug/L 09/13/24 05:12 1<0.22Bromoform 1.0 0.14 ug/L 09/13/24 05:12 1<0.14Bromomethane 5.0 1.5 ug/L 09/13/24 05:12 1<1.5Carbon disulfide 1.0 0.17 ug/L 09/13/24 05:12 1<0.17Carbon tetrachloride 1.0 0.17 ug/L 09/13/24 05:12 1<0.17Chlorobenzene 1.0 0.23 ug/L 09/13/24 05:12 1<0.23Chloroethane 1.0 0.18 ug/L 09/13/24 05:12 1<0.18Chloroform 1.0 0.13 ug/L 09/13/24 05:12 1<0.13Chloromethane 1.0 0.64 ug/L 09/13/24 05:12 1<0.64Chloroprene 1.0 0.20 ug/L 09/13/24 05:12 1<0.20cis-1,3-Dichloropropene 1.0 0.17 ug/L 09/13/24 05:12 1<0.17Dibromochloromethane 1.0 0.27 ug/L 09/13/24 05:12 1<0.27Dibromomethane 1.0 0.20 ug/L 09/13/24 05:12 1<0.20Dichlorodifluoromethane 1.0 0.38 ug/L 09/13/24 05:12 1<0.38Ethyl methacrylate 1.0 0.13 ug/L 09/13/24 05:12 1<0.13Ethylbenzene 1.0 0.22 ug/L 09/13/24 05:12 1<0.22Hexachlorobutadiene 5.0 1.7 ug/L 09/13/24 05:12 1<1.7Iodomethane 50 11 ug/L 09/13/24 05:12 1<11Isobutyl alcohol 10 4.9 ug/L 09/13/24 05:12 1<4.9Methacrylonitrile 1.0 0.51 ug/L 09/13/24 05:12 1<0.51Methyl methacrylate 1.0 0.23 ug/L 09/13/24 05:12 1<0.23Methylene Chloride 1.0 0.11 ug/L 09/13/24 05:12 1<0.11Naphthalene 10 5.0 ug/L 09/13/24 05:12 1<5.0Propionitrile 1.0 0.11 ug/L 09/13/24 05:12 1<0.11Styrene 1.0 0.17 ug/L 09/13/24 05:12 1<0.17Tetrachloroethene 1.0 0.53 ug/L 09/13/24 05:12 1<0.53Tetrahydrofuran 1.0 0.14 ug/L 09/13/24 05:12 1<0.14Toluene 1.0 0.21 ug/L 09/13/24 05:12 1<0.21trans-1,2-Dichloroethene 1.0 0.15 ug/L 09/13/24 05:12 1<0.15trans-1,3-Dichloropropene 1.0 0.70 ug/L 09/13/24 05:12 1<0.70trans-1,4-Dichloro-2-butene 1.0 0.15 ug/L 09/13/24 05:12 1<0.15Trichloroethene 1.0 0.24 ug/L 09/13/24 05:12 1<0.24Trichlorofluoromethane 5.0 0.95 ug/L 09/13/24 05:12 1<0.95Vinyl acetate Eurofins Raleigh Page 42 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23869-1Client Sample ID: MW-17 Matrix: WaterDate Collected: 09/05/24 10:51 Date Received: 09/06/24 09:30 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) RL MDL <0.32 1.0 0.32 ug/L 09/13/24 05:12 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Vinyl chloride 3.0 0.45 ug/L 09/13/24 05:12 1<0.45Xylenes, Total 4-Bromofluorobenzene (Surr)76 53-136 09/13/24 05:12 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Dibromofluoromethane (Surr)100 09/13/24 05:12 167-129 Toluene-d8 (Surr)84 09/13/24 05:12 159-134 Method: SW846 8260D - Volatile Organic Compounds by GC/MS - RA RL MDL <0.15 *+1.0 0.15 ug/L 09/13/24 23:14 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier cis-1,2-Dichloroethene 4-Bromofluorobenzene (Surr)81 53-136 09/13/24 23:14 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Dibromofluoromethane (Surr)115 09/13/24 23:14 167-129 Toluene-d8 (Surr)96 09/13/24 23:14 159-134 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography RL MDL 17 0.50 0.20 mg/L 09/17/24 14:19 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Chloride 1.0 0.40 mg/L 09/17/24 14:19 18.7Sulfate Method: SM 2340B-2011 - Total Hardness (as CaCO3) by calculation RL MDL 58 3.3 3.3 mg/L 09/17/24 12:06 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Hardness as calcium carbonate Method: SW846 6010D - Metals (ICP) - Total Recoverable RL MDL <6.4 20 6.4 ug/L 09/09/24 05:44 09/09/24 21:46 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Arsenic 10 4.4 ug/L 09/09/24 05:44 09/09/24 21:46 132Barium 4.0 0.30 ug/L 09/09/24 05:44 09/09/24 21:46 1<0.30Beryllium 5.0 0.44 ug/L 09/09/24 05:44 09/09/24 21:46 1<0.44Cadmium 10 1.1 ug/L 09/09/24 05:44 09/09/24 21:46 1<1.1Chromium 10 1.4 ug/L 09/09/24 05:44 09/09/24 21:46 1<1.4Cobalt 20 3.2 ug/L 09/09/24 05:44 09/09/24 21:46 1<3.2Copper 100 20 ug/L 09/09/24 05:44 09/09/24 21:46 167JFe 10 6.6 ug/L 09/09/24 05:44 09/09/24 21:46 1<6.6Lead 10 1.3 ug/L 09/09/24 05:44 09/09/24 21:46 1620Manganese 40 3.3 ug/L 09/09/24 05:44 09/09/24 21:46 1<3.3Nickel 1000 67 ug/L 09/09/24 05:44 09/09/24 21:46 11200BPotassium 10 1.5 ug/L 09/09/24 05:44 09/09/24 21:46 1<1.5Silver 50 11 ug/L 09/09/24 05:44 09/09/24 21:46 1<11Tin 10 1.0 ug/L 09/09/24 05:44 09/09/24 21:46 1<1.0Vanadium 20 8.7 ug/L 09/09/24 05:44 09/09/24 21:46 1<8.7Zinc Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable RL MDL <0.34 5.0 0.34 ug/L 09/09/24 05:44 09/09/24 23:49 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Antimony 2.5 0.99 ug/L 09/09/24 05:44 09/09/24 23:49 1<0.99Selenium 1.0 0.26 ug/L 09/09/24 05:44 09/09/24 23:49 1<0.26Thallium Eurofins Raleigh Page 43 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23869-1Client Sample ID: MW-17 Matrix: WaterDate Collected: 09/05/24 10:51 Date Received: 09/06/24 09:30 Method: SW846 7470A - Mercury (CVAA) RL MDL <0.080 0.20 0.080 ug/L 09/10/24 10:23 09/10/24 15:28 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Mercury General Chemistry RL MDL 54 5.5 2.2 mg/L 09/13/24 22:26 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Alkalinity as CaCO3 to pH 4.5 (SM 2320B-2011) 0.81 0.81 mg/L 09/12/24 14:23 10.90Sulfide (SM 4500 S2 F-2011) 0.10 0.025 mg/L 09/10/24 14:24 17.1Nitrate as N (SM Nitrate by calc) 50 50 mg/L 09/12/24 14:14 1180 0.10 0.10 mg/L 09/24/24 07:56 1<0.10Ferric Iron (SM 3500) 0.10 0.025 mg/L 09/19/24 13:34 1<0.025 HFFerrous Iron (SM 3500 FE D) 0.50 0.21 mg/L 09/09/24 13:46 57.1Nitrate Nitrite as N (SM 4500 NO3 F) 0.10 0.017 mg/L 09/06/24 16:01 1<0.017 F1Nitrite as N (SM4500 NO2 F) Lab Sample ID: 752-23869-2Client Sample ID: MW-1 Matrix: WaterDate Collected: 09/05/24 08:58 Date Received: 09/06/24 09:30 Method: SW846 6010D - Metals (ICP) - Total Recoverable RL MDL <6.4 20 6.4 ug/L 09/09/24 05:44 09/09/24 21:48 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Arsenic 10 4.4 ug/L 09/09/24 05:44 09/09/24 21:48 152Barium 4.0 0.30 ug/L 09/09/24 05:44 09/09/24 21:48 10.35 JBeryllium 5.0 0.44 ug/L 09/09/24 05:44 09/09/24 21:48 10.52 JCadmium 10 1.1 ug/L 09/09/24 05:44 09/09/24 21:48 18.2 JChromium 10 1.4 ug/L 09/09/24 05:44 09/09/24 21:48 110Cobalt 20 3.2 ug/L 09/09/24 05:44 09/09/24 21:48 139Copper 100 20 ug/L 09/09/24 05:44 09/09/24 21:48 111000Fe 10 6.6 ug/L 09/09/24 05:44 09/09/24 21:48 110Lead 10 1.3 ug/L 09/09/24 05:44 09/09/24 21:48 1350Manganese 40 3.3 ug/L 09/09/24 05:44 09/09/24 21:48 114JNickel 1000 67 ug/L 09/09/24 05:44 09/09/24 21:48 1880J BPotassium 10 1.5 ug/L 09/09/24 05:44 09/09/24 21:48 1<1.5Silver 50 11 ug/L 09/09/24 05:44 09/09/24 21:48 1<11Tin 10 1.0 ug/L 09/09/24 05:44 09/09/24 21:48 120Vanadium 20 8.7 ug/L 09/09/24 05:44 09/09/24 21:48 1130Zinc Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable RL MDL <0.34 5.0 0.34 ug/L 09/09/24 05:44 09/09/24 23:52 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Antimony 2.5 0.99 ug/L 09/09/24 05:44 09/09/24 23:52 1<0.99Selenium 1.0 0.26 ug/L 09/09/24 05:44 09/09/24 23:52 1<0.26Thallium Method: SW846 7470A - Mercury (CVAA) RL MDL <0.080 0.20 0.080 ug/L 09/10/24 10:23 09/10/24 15:30 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Mercury General Chemistry RL MDL <0.81 0.81 0.81 mg/L 09/12/24 14:23 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Sulfide (SM 4500 S2 F-2011) Eurofins Raleigh Page 44 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23869-2Client Sample ID: MW-1 Matrix: WaterDate Collected: 09/05/24 08:58 Date Received: 09/06/24 09:30 General Chemistry (Continued) RL MDL 200 50 50 mg/L 09/12/24 14:14 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Total Dissolved Solids (SM 2540C) 0.10 0.10 mg/L 09/24/24 07:56 111Ferric Iron (SM 3500) 0.10 0.025 mg/L 09/19/24 13:34 1<0.025 HFFerrous Iron (SM 3500 FE D) Lab Sample ID: 752-23869-3Client Sample ID: Trip Blank Matrix: WaterDate Collected: 09/05/24 00:00 Date Received: 09/06/24 09:30 Method: SW846 8260D - Volatile Organic Compounds by GC/MS RL MDL <0.17 1.0 0.17 ug/L 09/13/24 02:36 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,1,1,2-Tetrachloroethane 1.0 0.12 ug/L 09/13/24 02:36 1<0.121,1,1-Trichloroethane 1.0 0.28 ug/L 09/13/24 02:36 1<0.281,1,2,2-Tetrachloroethane 1.0 0.14 ug/L 09/13/24 02:36 1<0.141,1,2-Trichloroethane 1.0 0.13 ug/L 09/13/24 02:36 1<0.131,1-Dichloroethane 1.0 0.21 ug/L 09/13/24 02:36 1<0.211,1-Dichloroethene 1.0 0.15 ug/L 09/13/24 02:36 1<0.151,1-Dichloropropene 1.0 0.49 ug/L 09/13/24 02:36 1<0.491,2,3-Trichloropropane 1.0 0.14 ug/L 09/13/24 02:36 1<0.141,2,4-Trichlorobenzene 1.0 0.48 ug/L 09/13/24 02:36 1<0.48 *11,2-Dibromo-3-Chloropropane 1.0 0.66 ug/L 09/13/24 02:36 1<0.661,2-Dibromoethane 1.0 0.19 ug/L 09/13/24 02:36 1<0.191,2-Dichlorobenzene 1.0 0.21 ug/L 09/13/24 02:36 1<0.211,2-Dichloroethane 1.0 0.10 ug/L 09/13/24 02:36 1<0.101,2-Dichloropropane 1.0 0.15 ug/L 09/13/24 02:36 1<0.151,3-Dichlorobenzene 1.0 0.16 ug/L 09/13/24 02:36 1<0.161,3-Dichloropropane 1.0 0.19 ug/L 09/13/24 02:36 1<0.191,4-Dichlorobenzene 1.0 0.28 ug/L 09/13/24 02:36 1<0.282,2-Dichloropropane 20 10 ug/L 09/13/24 02:36 1<102-Butanone (MEK) 5.0 0.88 ug/L 09/13/24 02:36 1<0.882-Hexanone 1.0 0.11 ug/L 09/13/24 02:36 1<0.113-Chloropropene 5.0 1.1 ug/L 09/13/24 02:36 1<1.14-Methyl-2-pentanone (MIBK) 20 10 ug/L 09/13/24 02:36 1<10Acetone 10 5.0 ug/L 09/13/24 02:36 1<5.0Acetonitrile 10 4.0 ug/L 09/13/24 02:36 1<4.0Acrolein 10 3.5 ug/L 09/13/24 02:36 1<3.5Acrylonitrile 1.0 0.15 ug/L 09/13/24 02:36 1<0.15Benzene 1.0 0.48 ug/L 09/13/24 02:36 1<0.48Bromochloromethane 1.0 0.17 ug/L 09/13/24 02:36 1<0.17Bromodichloromethane 1.0 0.22 ug/L 09/13/24 02:36 1<0.22Bromoform 1.0 0.14 ug/L 09/13/24 02:36 1<0.14Bromomethane 5.0 1.5 ug/L 09/13/24 02:36 1<1.5Carbon disulfide 1.0 0.17 ug/L 09/13/24 02:36 1<0.17Carbon tetrachloride 1.0 0.17 ug/L 09/13/24 02:36 1<0.17Chlorobenzene 1.0 0.23 ug/L 09/13/24 02:36 1<0.23Chloroethane 1.0 0.18 ug/L 09/13/24 02:36 10.20 J BChloroform 1.0 0.13 ug/L 09/13/24 02:36 1<0.13Chloromethane 1.0 0.64 ug/L 09/13/24 02:36 1<0.64Chloroprene 1.0 0.15 ug/L 09/13/24 02:36 1<0.15cis-1,2-Dichloroethene 1.0 0.20 ug/L 09/13/24 02:36 1<0.20cis-1,3-Dichloropropene Eurofins Raleigh Page 45 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID: 752-23869-3Client Sample ID: Trip Blank Matrix: WaterDate Collected: 09/05/24 00:00 Date Received: 09/06/24 09:30 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) RL MDL <0.17 1.0 0.17 ug/L 09/13/24 02:36 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Dibromochloromethane 1.0 0.27 ug/L 09/13/24 02:36 1<0.27Dibromomethane 1.0 0.20 ug/L 09/13/24 02:36 1<0.20Dichlorodifluoromethane 1.0 0.38 ug/L 09/13/24 02:36 1<0.38Ethyl methacrylate 1.0 0.13 ug/L 09/13/24 02:36 1<0.13Ethylbenzene 1.0 0.22 ug/L 09/13/24 02:36 1<0.22Hexachlorobutadiene 5.0 1.7 ug/L 09/13/24 02:36 1<1.7Iodomethane 50 11 ug/L 09/13/24 02:36 1<11Isobutyl alcohol 10 4.9 ug/L 09/13/24 02:36 1<4.9Methacrylonitrile 1.0 0.51 ug/L 09/13/24 02:36 1<0.51Methyl methacrylate 1.0 0.23 ug/L 09/13/24 02:36 1<0.23Methylene Chloride 1.0 0.11 ug/L 09/13/24 02:36 1<0.11Naphthalene 10 5.0 ug/L 09/13/24 02:36 1<5.0Propionitrile 1.0 0.11 ug/L 09/13/24 02:36 1<0.11Styrene 1.0 0.17 ug/L 09/13/24 02:36 1<0.17Tetrachloroethene 1.0 0.53 ug/L 09/13/24 02:36 1<0.53Tetrahydrofuran 1.0 0.14 ug/L 09/13/24 02:36 1<0.14Toluene 1.0 0.21 ug/L 09/13/24 02:36 1<0.21trans-1,2-Dichloroethene 1.0 0.15 ug/L 09/13/24 02:36 1<0.15trans-1,3-Dichloropropene 1.0 0.70 ug/L 09/13/24 02:36 1<0.70trans-1,4-Dichloro-2-butene 1.0 0.15 ug/L 09/13/24 02:36 1<0.15Trichloroethene 1.0 0.24 ug/L 09/13/24 02:36 1<0.24Trichlorofluoromethane 5.0 0.95 ug/L 09/13/24 02:36 1<0.95Vinyl acetate 1.0 0.32 ug/L 09/13/24 02:36 1<0.32Vinyl chloride 3.0 0.45 ug/L 09/13/24 02:36 1<0.45Xylenes, Total 4-Bromofluorobenzene (Surr)75 53-136 09/13/24 02:36 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Dibromofluoromethane (Surr)98 09/13/24 02:36 167-129 Toluene-d8 (Surr)84 09/13/24 02:36 159-134 Eurofins Raleigh Page 46 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Surrogate Summary Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS Prep Type: Total/NAMatrix: GW Lab Sample ID Client Sample ID (53-136)(67-129)(59-134) BFB DBFM TOL 78 104 85752-23805-1 Percent Surrogate Recovery (Acceptance Limits) MW-4 78 105 86752-23805-2 MW-10A 76 107 86752-23805-3 MW-18 74 103 99752-23805-6 Equipment Blank 75 102 86752-23805-7 MW-8 90 112 78752-23805-8 MW-15 62 113 85752-23805-9 MW-16 Surrogate Legend BFB = 4-Bromofluorobenzene (Surr) DBFM = Dibromofluoromethane (Surr) TOL = Toluene-d8 (Surr) Method: 8260D - Volatile Organic Compounds by GC/MS Prep Type: Total/NAMatrix: Surface Water Lab Sample ID Client Sample ID (53-136)(67-129)(59-134) BFB DBFM TOL 76 104 87752-23805-4 Percent Surrogate Recovery (Acceptance Limits) SW-2 77 105 85752-23805-5 SW-3 70 106 88752-23805-10 SW-1 Surrogate Legend BFB = 4-Bromofluorobenzene (Surr) DBFM = Dibromofluoromethane (Surr) TOL = Toluene-d8 (Surr) Method: 8260D - Volatile Organic Compounds by GC/MS Prep Type: Total/NAMatrix: Water Lab Sample ID Client Sample ID (53-136)(67-129)(59-134) BFB DBFM TOL 76 100 86752-23756-1 Percent Surrogate Recovery (Acceptance Limits) MW-19 76 100 84752-23869-1 MW-17 81 115 96752-23869-1 - RA MW-17 75 98 84752-23869-3 Trip Blank 82 91 89LCS 752-8685/5 Lab Control Sample 70 95 93LCS 752-8723/4 Lab Control Sample 78 90 86LCS 752-8744/4 Lab Control Sample 90 103 103LCS 752-8754/4 Lab Control Sample 84 88 88LCSD 752-8685/6 Lab Control Sample Dup 81 101 107LCSD 752-8723/5 Lab Control Sample Dup 83 92 90LCSD 752-8744/5 Lab Control Sample Dup 84 97 95LCSD 752-8754/5 Lab Control Sample Dup 78 93 89MB 752-8685/9 Method Blank 81 109 91MB 752-8723/8 Method Blank 82 100 85MB 752-8744/8 Method Blank 79 105 94MB 752-8754/8 Method Blank 81 89 84MRL 752-8685/4 Lab Control Sample Eurofins Raleigh Page 47 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Surrogate Summary Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Prep Type: Total/NAMatrix: Water Lab Sample ID Client Sample ID (53-136)(67-129)(59-134) BFB DBFM TOL 66 96 93MRL 752-8723/3 Percent Surrogate Recovery (Acceptance Limits) Lab Control Sample 85 100 87MRL 752-8744/3 Lab Control Sample 82 101 93MRL 752-8754/3 Lab Control Sample Surrogate Legend BFB = 4-Bromofluorobenzene (Surr) DBFM = Dibromofluoromethane (Surr) TOL = Toluene-d8 (Surr) Method: 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Prep Type: Total/NAMatrix: GW Lab Sample ID Client Sample ID (46-154) BFB 87752-23805-1 Percent Surrogate Recovery (Acceptance Limits) MW-4 76752-23805-2 MW-10A 79752-23805-3 MW-18 76752-23805-6 Equipment Blank 86752-23805-7 MW-8 84752-23805-8 MW-15 75752-23805-9 MW-16 Surrogate Legend BFB = 4-Bromofluorobenzene (Surr) Method: 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Prep Type: Total/NAMatrix: Surface Water Lab Sample ID Client Sample ID (46-154) BFB 78752-23805-4 Percent Surrogate Recovery (Acceptance Limits) SW-2 78752-23805-5 SW-3 77752-23805-10 SW-1 Surrogate Legend BFB = 4-Bromofluorobenzene (Surr) Method: 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Prep Type: Total/NAMatrix: Water Lab Sample ID Client Sample ID (46-154) BFB 93752-23756-1 Percent Surrogate Recovery (Acceptance Limits) MW-19 100752-23869-1 MW-17 99LCS 680-854693/3 Lab Control Sample 100LCS 680-854841/3 Lab Control Sample 92LCSD 680-854693/4 Lab Control Sample Dup 91LCSD 680-854841/4 Lab Control Sample Dup 80MB 680-854693/5 Method Blank 81MB 680-854841/6 Method Blank Eurofins Raleigh Page 48 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Surrogate Summary Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Surrogate Legend BFB = 4-Bromofluorobenzene (Surr) Eurofins Raleigh Page 49 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS Client Sample ID: Method BlankLab Sample ID: MB 752-8685/9 Matrix: Water Prep Type: Total/NA Analysis Batch: 8685 RL MDL 1,1,1,2-Tetrachloroethane <0.17 1.0 0.17 ug/L 09/10/24 14:56 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier <0.12 0.121.0 ug/L 09/10/24 14:56 11,1,1-Trichloroethane <0.28 0.281.0 ug/L 09/10/24 14:56 11,1,2,2-Tetrachloroethane <0.14 0.141.0 ug/L 09/10/24 14:56 11,1,2-Trichloroethane <0.13 0.131.0 ug/L 09/10/24 14:56 11,1-Dichloroethane <0.21 0.211.0 ug/L 09/10/24 14:56 11,1-Dichloroethene <0.15 0.151.0 ug/L 09/10/24 14:56 11,1-Dichloropropene <0.49 0.491.0 ug/L 09/10/24 14:56 11,2,3-Trichloropropane <0.14 0.141.0 ug/L 09/10/24 14:56 11,2,4-Trichlorobenzene <0.48 0.481.0 ug/L 09/10/24 14:56 11,2-Dibromo-3-Chloropropane <0.66 0.661.0 ug/L 09/10/24 14:56 11,2-Dibromoethane <0.19 0.191.0 ug/L 09/10/24 14:56 11,2-Dichlorobenzene <0.21 0.211.0 ug/L 09/10/24 14:56 11,2-Dichloroethane <0.10 0.101.0 ug/L 09/10/24 14:56 11,2-Dichloropropane <0.15 0.151.0 ug/L 09/10/24 14:56 11,3-Dichlorobenzene <0.16 0.161.0 ug/L 09/10/24 14:56 11,3-Dichloropropane <0.19 0.191.0 ug/L 09/10/24 14:56 11,4-Dichlorobenzene <0.28 0.281.0 ug/L 09/10/24 14:56 12,2-Dichloropropane <10 1020 ug/L 09/10/24 14:56 12-Butanone (MEK) <0.88 0.885.0 ug/L 09/10/24 14:56 12-Hexanone <0.11 0.111.0 ug/L 09/10/24 14:56 13-Chloropropene <1.1 1.15.0 ug/L 09/10/24 14:56 14-Methyl-2-pentanone (MIBK) <10 1020 ug/L 09/10/24 14:56 1Acetone <5.0 5.010 ug/L 09/10/24 14:56 1Acetonitrile <4.0 4.010 ug/L 09/10/24 14:56 1Acrolein <3.5 3.510 ug/L 09/10/24 14:56 1Acrylonitrile <0.15 0.151.0 ug/L 09/10/24 14:56 1Benzene <0.48 0.481.0 ug/L 09/10/24 14:56 1Bromochloromethane <0.17 0.171.0 ug/L 09/10/24 14:56 1Bromodichloromethane <0.22 0.221.0 ug/L 09/10/24 14:56 1Bromoform <0.14 0.141.0 ug/L 09/10/24 14:56 1Bromomethane <1.5 1.55.0 ug/L 09/10/24 14:56 1Carbon disulfide <0.17 0.171.0 ug/L 09/10/24 14:56 1Carbon tetrachloride <0.17 0.171.0 ug/L 09/10/24 14:56 1Chlorobenzene <0.23 0.231.0 ug/L 09/10/24 14:56 1Chloroethane <0.18 0.181.0 ug/L 09/10/24 14:56 1Chloroform <0.13 0.131.0 ug/L 09/10/24 14:56 1Chloromethane <0.64 0.641.0 ug/L 09/10/24 14:56 1Chloroprene <0.15 0.151.0 ug/L 09/10/24 14:56 1cis-1,2-Dichloroethene <0.20 0.201.0 ug/L 09/10/24 14:56 1cis-1,3-Dichloropropene <0.17 0.171.0 ug/L 09/10/24 14:56 1Dibromochloromethane <0.27 0.271.0 ug/L 09/10/24 14:56 1Dibromomethane <0.20 0.201.0 ug/L 09/10/24 14:56 1Dichlorodifluoromethane <0.38 0.381.0 ug/L 09/10/24 14:56 1Ethyl methacrylate <0.13 0.131.0 ug/L 09/10/24 14:56 1Ethylbenzene <0.22 0.221.0 ug/L 09/10/24 14:56 1Hexachlorobutadiene <1.7 1.75.0 ug/L 09/10/24 14:56 1Iodomethane <11 1150 ug/L 09/10/24 14:56 1Isobutyl alcohol Eurofins Raleigh Page 50 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Method BlankLab Sample ID: MB 752-8685/9 Matrix: Water Prep Type: Total/NA Analysis Batch: 8685 RL MDL Methacrylonitrile <4.9 10 4.9 ug/L 09/10/24 14:56 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier <0.51 0.511.0 ug/L 09/10/24 14:56 1Methyl methacrylate <0.23 0.231.0 ug/L 09/10/24 14:56 1Methylene Chloride <0.11 0.111.0 ug/L 09/10/24 14:56 1Naphthalene <5.0 5.010 ug/L 09/10/24 14:56 1Propionitrile <0.11 0.111.0 ug/L 09/10/24 14:56 1Styrene <0.17 0.171.0 ug/L 09/10/24 14:56 1Tetrachloroethene <0.53 0.531.0 ug/L 09/10/24 14:56 1Tetrahydrofuran <0.14 0.141.0 ug/L 09/10/24 14:56 1Toluene <0.21 0.211.0 ug/L 09/10/24 14:56 1trans-1,2-Dichloroethene <0.15 0.151.0 ug/L 09/10/24 14:56 1trans-1,3-Dichloropropene <0.70 0.701.0 ug/L 09/10/24 14:56 1trans-1,4-Dichloro-2-butene <0.15 0.151.0 ug/L 09/10/24 14:56 1Trichloroethene <0.24 0.241.0 ug/L 09/10/24 14:56 1Trichlorofluoromethane <0.95 0.955.0 ug/L 09/10/24 14:56 1Vinyl acetate <0.32 0.321.0 ug/L 09/10/24 14:56 1Vinyl chloride <0.45 0.453.0 ug/L 09/10/24 14:56 1Xylenes, Total 4-Bromofluorobenzene (Surr)78 53-136 09/10/24 14:56 1 MB MB Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery 93 09/10/24 14:56 1Dibromofluoromethane (Surr)67-129 89 09/10/24 14:56 1Toluene-d8 (Surr)59-134 Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-8685/5 Matrix: Water Prep Type: Total/NA Analysis Batch: 8685 1,1,1,2-Tetrachloroethane 20.0 17.9 ug/L 89 71-120 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits 1,1,1-Trichloroethane 20.0 21.1 ug/L 105 72-143 1,1,2,2-Tetrachloroethane 20.0 16.8 ug/L 84 59-133 1,1,2-Trichloroethane 20.0 18.1 ug/L 91 67-120 1,1-Dichloroethane 20.0 18.8 ug/L 94 79-141 1,1-Dichloroethene 20.0 19.7 ug/L 98 75-133 1,1-Dichloropropene 20.0 20.6 ug/L 103 70-129 1,2,3-Trichloropropane 20.0 18.2 ug/L 91 69-127 1,2,4-Trichlorobenzene 20.0 20.4 ug/L 102 59-122 1,2-Dibromo-3-Chloropropane 20.0 21.5 ug/L 107 37-157 1,2-Dibromoethane 20.0 18.6 ug/L 93 66-123 1,2-Dichlorobenzene 20.0 17.4 ug/L 87 76-120 1,2-Dichloroethane 20.0 18.7 ug/L 93 72-151 1,2-Dichloropropane 20.0 18.4 ug/L 92 78-125 1,3-Dichlorobenzene 20.0 17.3 ug/L 87 76-120 1,3-Dichloropropane 20.0 17.0 ug/L 85 60-129 1,4-Dichlorobenzene 20.0 17.1 ug/L 85 76-122 2,2-Dichloropropane 20.0 21.5 ug/L 107 21-167 2-Butanone (MEK)40.0 44.6 ug/L 112 36-135 2-Hexanone 40.0 31.9 ug/L 80 36-191 Eurofins Raleigh Page 51 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-8685/5 Matrix: Water Prep Type: Total/NA Analysis Batch: 8685 3-Chloropropene 20.0 20.3 ug/L 101 17-147 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits 4-Methyl-2-pentanone (MIBK)40.0 35.6 ug/L 89 56-166 Acetone 40.0 40.8 ug/L 102 10-158 Acetonitrile 20.0 17.7 ug/L 89 10-200 Acrolein 40.0 30.6 ug/L 77 10-200 Acrylonitrile 60.0 55.9 ug/L 93 10-200 Benzene 20.0 18.2 ug/L 91 80-134 Bromochloromethane 20.0 19.9 ug/L 99 74-128 Bromodichloromethane 20.0 19.0 ug/L 95 72-129 Bromoform 20.0 19.7 ug/L 99 73-120 Bromomethane 20.0 16.1 ug/L 80 38-189 Carbon disulfide 20.0 21.7 ug/L 109 65-173 Carbon tetrachloride 20.0 20.6 ug/L 103 68-142 Chlorobenzene 20.0 17.8 ug/L 89 80-120 Chloroethane 20.0 16.6 ug/L 83 45-213 Chloroform 20.0 17.7 ug/L 89 78-138 Chloromethane 20.0 17.3 ug/L 87 56-171 Chloroprene 20.0 19.7 ug/L 98 33-148 cis-1,2-Dichloroethene 20.0 21.5 ug/L 108 69-120 cis-1,3-Dichloropropene 20.0 19.4 ug/L 97 63-125 Dibromochloromethane 20.0 18.8 ug/L 94 73-120 Dibromomethane 20.0 19.4 ug/L 97 76-124 Dichlorodifluoromethane 20.0 21.2 ug/L 106 25-161 Ethyl methacrylate 20.0 17.3 ug/L 86 51-120 Ethylbenzene 20.0 17.9 ug/L 90 68-124 Hexachlorobutadiene 20.0 21.7 ug/L 109 63-120 Iodomethane 20.0 18.1 ug/L 91 34-140 Isobutyl alcohol 20.0 15.4 J ug/L 77 10-200 Methacrylonitrile 20.0 19.1 ug/L 95 10-200 Methyl methacrylate 20.0 21.0 ug/L 105 48-126 Methylene Chloride 20.0 17.9 ug/L 90 68-128 Naphthalene 20.0 21.1 ug/L 105 50-127 Styrene 20.0 18.1 ug/L 91 73-120 Tetrachloroethene 20.0 18.4 ug/L 92 40-181 Tetrahydrofuran 20.0 16.2 ug/L 81 0-200 Toluene 20.0 17.5 ug/L 88 71-120 trans-1,2-Dichloroethene 20.0 20.3 ug/L 101 75-139 trans-1,3-Dichloropropene 20.0 19.9 ug/L 99 65-152 trans-1,4-Dichloro-2-butene 20.0 18.6 ug/L 93 10-142 Trichloroethene 20.0 18.7 ug/L 94 74-120 Trichlorofluoromethane 20.0 23.9 ug/L 119 68-183 Vinyl acetate 20.0 24.6 ug/L 123 10-198 Vinyl chloride 20.0 24.1 ug/L 121 49-150 Xylenes, Total 60.0 54.9 ug/L 92 77-121 4-Bromofluorobenzene (Surr)53 -136 Surrogate 82 LCS LCS Qualifier Limits%Recovery 91Dibromofluoromethane (Surr)67 -129 Eurofins Raleigh Page 52 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-8685/5 Matrix: Water Prep Type: Total/NA Analysis Batch: 8685 Toluene-d8 (Surr)59 -134 Surrogate 89 LCS LCS Qualifier Limits%Recovery Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-8685/6 Matrix: Water Prep Type: Total/NA Analysis Batch: 8685 1,1,1,2-Tetrachloroethane 20.0 17.6 ug/L 88 71-120 1 16 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD 1,1,1-Trichloroethane 20.0 20.0 ug/L 100 72-143 5 18 1,1,2,2-Tetrachloroethane 20.0 16.7 ug/L 83 59-133 1 16 1,1,2-Trichloroethane 20.0 18.0 ug/L 90 67-120 1 18 1,1-Dichloroethane 20.0 18.1 ug/L 90 79-141 4 19 1,1-Dichloroethene 20.0 19.1 ug/L 95 75-133 3 20 1,1-Dichloropropene 20.0 19.7 ug/L 99 70-129 4 17 1,2,3-Trichloropropane 20.0 18.4 ug/L 92 69-127 1 17 1,2,4-Trichlorobenzene 20.0 21.3 ug/L 107 59-122 4 17 1,2-Dibromo-3-Chloropropane 20.0 23.1 ug/L 116 37-157 7 18 1,2-Dibromoethane 20.0 18.7 ug/L 93 66-123 1 15 1,2-Dichlorobenzene 20.0 21.5 *1 ug/L 108 76-120 21 16 1,2-Dichloroethane 20.0 17.6 ug/L 88 72-151 6 16 1,2-Dichloropropane 20.0 17.7 ug/L 88 78-125 4 19 1,3-Dichlorobenzene 20.0 17.6 ug/L 88 76-120 1 17 1,3-Dichloropropane 20.0 17.2 ug/L 86 60-129 1 16 1,4-Dichlorobenzene 20.0 17.5 ug/L 88 76-122 3 16 2,2-Dichloropropane 20.0 20.2 ug/L 101 21-167 6 20 2-Butanone (MEK)40.0 46.1 ug/L 115 36-135 3 19 2-Hexanone 40.0 33.7 ug/L 84 36-191 6 17 3-Chloropropene 20.0 19.1 ug/L 95 17-147 6 19 4-Methyl-2-pentanone (MIBK)40.0 36.1 ug/L 90 56-166 2 19 Acetone 40.0 40.9 ug/L 102 10-158 0 78 Acetonitrile 20.0 16.3 ug/L 81 10-200 9 35 Acrolein 40.0 31.9 ug/L 80 10-200 4 50 Acrylonitrile 60.0 55.5 ug/L 92 10-200 1 36 Benzene 20.0 17.7 ug/L 89 80-134 3 17 Bromochloromethane 20.0 19.7 ug/L 99 74-128 1 18 Bromodichloromethane 20.0 18.5 ug/L 92 72-129 3 16 Bromoform 20.0 19.5 ug/L 97 73-120 1 44 Bromomethane 20.0 21.9 *1 ug/L 109 38-189 30 27 Carbon disulfide 20.0 21.4 ug/L 107 65-173 1 38 Carbon tetrachloride 20.0 20.2 ug/L 101 68-142 2 17 Chlorobenzene 20.0 18.0 ug/L 90 80-120 1 16 Chloroethane 20.0 16.8 ug/L 84 45-213 1 26 Chloroform 20.0 16.7 ug/L 84 78-138 6 17 Chloromethane 20.0 18.0 ug/L 90 56-171 4 28 Chloroprene 20.0 18.8 ug/L 94 33-148 4 19 cis-1,2-Dichloroethene 20.0 20.5 ug/L 102 69-120 5 18 cis-1,3-Dichloropropene 20.0 18.8 ug/L 94 63-125 3 17 Dibromochloromethane 20.0 18.7 ug/L 94 73-120 0 16 Eurofins Raleigh Page 53 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-8685/6 Matrix: Water Prep Type: Total/NA Analysis Batch: 8685 Dibromomethane 20.0 18.9 ug/L 94 76-124 3 15 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Dichlorodifluoromethane 20.0 21.8 ug/L 109 25-161 3 48 Ethyl methacrylate 20.0 17.9 ug/L 89 51-120 3 24 Ethylbenzene 20.0 18.1 ug/L 90 68-124 1 16 Hexachlorobutadiene 20.0 21.9 ug/L 109 63-120 1 19 Iodomethane 20.0 17.5 ug/L 88 34-140 3 15 Isobutyl alcohol 20.0 15.0 J ug/L 75 10-200 2 20 Methacrylonitrile 20.0 18.9 ug/L 94 10-200 1 50 Methyl methacrylate 20.0 20.7 ug/L 104 48-126 1 50 Methylene Chloride 20.0 17.7 ug/L 89 68-128 1 17 Naphthalene 20.0 19.5 ug/L 97 50-127 8 19 Styrene 20.0 18.4 ug/L 92 73-120 1 23 Tetrachloroethene 20.0 18.4 ug/L 92 40-181 0 26 Tetrahydrofuran 20.0 16.1 ug/L 81 0-200 1 50 Toluene 20.0 17.4 ug/L 87 71-120 1 17 trans-1,2-Dichloroethene 20.0 18.9 ug/L 94 75-139 7 19 trans-1,3-Dichloropropene 20.0 19.5 ug/L 97 65-152 2 16 trans-1,4-Dichloro-2-butene 20.0 20.0 ug/L 100 10-142 8 28 Trichloroethene 20.0 19.1 ug/L 96 74-120 2 22 Trichlorofluoromethane 20.0 23.2 ug/L 116 68-183 3 22 Vinyl acetate 20.0 21.4 ug/L 107 10-198 14 21 Vinyl chloride 20.0 24.4 ug/L 122 49-150 1 27 Xylenes, Total 60.0 56.4 ug/L 94 77-121 3 16 4-Bromofluorobenzene (Surr)53 -136 Surrogate 84 LCSD LCSD Qualifier Limits%Recovery 88Dibromofluoromethane (Surr)67 -129 88Toluene-d8 (Surr)59 -134 Client Sample ID: Lab Control SampleLab Sample ID: MRL 752-8685/4 Matrix: Water Prep Type: Total/NA Analysis Batch: 8685 1,1,1,2-Tetrachloroethane 1.00 0.758 J ug/L 76 Analyte MRL MRL DUnitResultQualifier %Rec Spike Added %Rec Limits 1,1,1-Trichloroethane 1.00 1.03 ug/L 103 1,1,2,2-Tetrachloroethane 1.00 0.924 J ug/L 92 1,1,2-Trichloroethane 1.00 0.795 J ug/L 80 1,1-Dichloroethane 1.00 0.959 J ug/L 96 1,1-Dichloroethene 1.00 0.943 J ug/L 94 1,1-Dichloropropene 1.00 0.918 J ug/L 92 1,2,3-Trichloropropane 1.00 0.952 J ug/L 95 1,2,4-Trichlorobenzene 1.00 1.13 ug/L 113 1,2-Dibromo-3-Chloropropane 1.00 0.770 J ug/L 77 1,2-Dibromoethane 1.00 0.782 J ug/L 78 1,2-Dichlorobenzene 1.00 1.15 ug/L 115 1,2-Dichloroethane 1.00 1.00 ug/L 100 1,2-Dichloropropane 1.00 0.778 J ug/L 78 Eurofins Raleigh Page 54 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Lab Control SampleLab Sample ID: MRL 752-8685/4 Matrix: Water Prep Type: Total/NA Analysis Batch: 8685 1,3-Dichlorobenzene 1.00 1.13 ug/L 113 Analyte MRL MRL DUnitResultQualifier %Rec Spike Added %Rec Limits 1,3-Dichloropropane 1.00 0.702 J ug/L 70 1,4-Dichlorobenzene 1.00 1.27 ug/L 127 2,2-Dichloropropane 1.00 0.948 J ug/L 95 2-Butanone (MEK)2.00 <10 ug/L 153 2-Hexanone 2.00 1.15 J ug/L 58 3-Chloropropene 1.00 0.794 J ug/L 79 4-Methyl-2-pentanone (MIBK)2.00 1.56 J ug/L 78 Acetone 2.00 <10 ug/L 0 Acetonitrile 10.0 9.40 J ug/L 94 Acrolein 5.00 5.15 J ug/L 103 Acrylonitrile 5.00 4.44 J ug/L 89 Benzene 1.00 0.929 J ug/L 93 Bromochloromethane 1.00 1.06 ug/L 106 Bromodichloromethane 1.00 0.897 J ug/L 90 Bromoform 1.00 0.947 J ug/L 95 Bromomethane 1.00 1.14 ug/L 114 Carbon disulfide 2.00 2.38 J ug/L 119 Carbon tetrachloride 1.00 0.958 J ug/L 96 Chlorobenzene 1.00 0.983 J ug/L 98 Chloroethane 1.00 0.739 J ug/L 74 Chloroform 1.00 1.10 ug/L 110 Chloromethane 1.00 0.649 J ug/L 65 Chloroprene 1.00 0.722 J ug/L 72 cis-1,2-Dichloroethene 1.00 0.898 J ug/L 90 cis-1,3-Dichloropropene 1.00 0.810 J ug/L 81 Dibromochloromethane 1.00 0.701 J ug/L 70 Dibromomethane 1.00 0.972 J ug/L 97 Dichlorodifluoromethane 1.00 1.36 ug/L 136 Ethyl methacrylate 1.00 0.546 J ug/L 55 Ethylbenzene 1.00 0.866 J ug/L 87 Hexachlorobutadiene 1.00 1.31 ug/L 131 Iodomethane 2.00 <1.7 ug/L 64 Isobutyl alcohol 20.0 16.1 J ug/L 80 Methacrylonitrile 10.0 8.38 J ug/L 84 Methyl methacrylate 1.00 0.837 J ug/L 84 Methylene Chloride 1.00 <0.23 ug/L 0 Naphthalene 1.00 0.817 J ug/L 82 Styrene 1.00 0.637 J ug/L 64 Tetrachloroethene 1.00 0.834 J ug/L 83 Tetrahydrofuran 1.00 0.948 J ug/L 95 Toluene 1.00 0.774 J ug/L 77 trans-1,2-Dichloroethene 1.00 1.07 ug/L 107 trans-1,3-Dichloropropene 1.00 0.708 J ug/L 71 trans-1,4-Dichloro-2-butene 1.00 1.11 ug/L 111 Trichloroethene 1.00 0.986 J ug/L 99 Trichlorofluoromethane 1.00 1.06 ug/L 106 Vinyl acetate 2.00 1.49 J ug/L 74 Vinyl chloride 1.00 1.04 ug/L 104 Eurofins Raleigh Page 55 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Lab Control SampleLab Sample ID: MRL 752-8685/4 Matrix: Water Prep Type: Total/NA Analysis Batch: 8685 Xylenes, Total 3.00 2.31 J ug/L 77 Analyte MRL MRL DUnitResultQualifier %Rec Spike Added %Rec Limits 4-Bromofluorobenzene (Surr)53 -136 Surrogate 81 MRL MRL Qualifier Limits%Recovery 89Dibromofluoromethane (Surr)67 -129 84Toluene-d8 (Surr)59 -134 Client Sample ID: Method BlankLab Sample ID: MB 752-8723/8 Matrix: Water Prep Type: Total/NA Analysis Batch: 8723 RL MDL 1,1,1,2-Tetrachloroethane <0.17 1.0 0.17 ug/L 09/11/24 23:37 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier <0.12 0.121.0 ug/L 09/11/24 23:37 11,1,1-Trichloroethane <0.28 0.281.0 ug/L 09/11/24 23:37 11,1,2,2-Tetrachloroethane <0.14 0.141.0 ug/L 09/11/24 23:37 11,1,2-Trichloroethane <0.13 0.131.0 ug/L 09/11/24 23:37 11,1-Dichloroethane <0.21 0.211.0 ug/L 09/11/24 23:37 11,1-Dichloroethene <0.15 0.151.0 ug/L 09/11/24 23:37 11,1-Dichloropropene <0.49 0.491.0 ug/L 09/11/24 23:37 11,2,3-Trichloropropane <0.14 0.141.0 ug/L 09/11/24 23:37 11,2,4-Trichlorobenzene <0.48 0.481.0 ug/L 09/11/24 23:37 11,2-Dibromo-3-Chloropropane <0.66 0.661.0 ug/L 09/11/24 23:37 11,2-Dibromoethane <0.19 0.191.0 ug/L 09/11/24 23:37 11,2-Dichlorobenzene <0.21 0.211.0 ug/L 09/11/24 23:37 11,2-Dichloroethane <0.10 0.101.0 ug/L 09/11/24 23:37 11,2-Dichloropropane <0.15 0.151.0 ug/L 09/11/24 23:37 11,3-Dichlorobenzene <0.16 0.161.0 ug/L 09/11/24 23:37 11,3-Dichloropropane <0.19 0.191.0 ug/L 09/11/24 23:37 11,4-Dichlorobenzene <0.28 0.281.0 ug/L 09/11/24 23:37 12,2-Dichloropropane <10 1020 ug/L 09/11/24 23:37 12-Butanone (MEK) <0.88 0.885.0 ug/L 09/11/24 23:37 12-Hexanone <0.11 0.111.0 ug/L 09/11/24 23:37 13-Chloropropene <1.1 1.15.0 ug/L 09/11/24 23:37 14-Methyl-2-pentanone (MIBK) <10 1020 ug/L 09/11/24 23:37 1Acetone <5.0 5.010 ug/L 09/11/24 23:37 1Acetonitrile <4.0 4.010 ug/L 09/11/24 23:37 1Acrolein <3.5 3.510 ug/L 09/11/24 23:37 1Acrylonitrile <0.15 0.151.0 ug/L 09/11/24 23:37 1Benzene <0.48 0.481.0 ug/L 09/11/24 23:37 1Bromochloromethane <0.17 0.171.0 ug/L 09/11/24 23:37 1Bromodichloromethane <0.22 0.221.0 ug/L 09/11/24 23:37 1Bromoform <0.14 0.141.0 ug/L 09/11/24 23:37 1Bromomethane <1.5 1.55.0 ug/L 09/11/24 23:37 1Carbon disulfide <0.17 0.171.0 ug/L 09/11/24 23:37 1Carbon tetrachloride <0.17 0.171.0 ug/L 09/11/24 23:37 1Chlorobenzene <0.23 0.231.0 ug/L 09/11/24 23:37 1Chloroethane <0.18 0.181.0 ug/L 09/11/24 23:37 1Chloroform Eurofins Raleigh Page 56 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Method BlankLab Sample ID: MB 752-8723/8 Matrix: Water Prep Type: Total/NA Analysis Batch: 8723 RL MDL Chloromethane <0.13 1.0 0.13 ug/L 09/11/24 23:37 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier <0.64 0.641.0 ug/L 09/11/24 23:37 1Chloroprene <0.15 0.151.0 ug/L 09/11/24 23:37 1cis-1,2-Dichloroethene <0.20 0.201.0 ug/L 09/11/24 23:37 1cis-1,3-Dichloropropene <0.17 0.171.0 ug/L 09/11/24 23:37 1Dibromochloromethane <0.27 0.271.0 ug/L 09/11/24 23:37 1Dibromomethane <0.20 0.201.0 ug/L 09/11/24 23:37 1Dichlorodifluoromethane <0.38 0.381.0 ug/L 09/11/24 23:37 1Ethyl methacrylate <0.13 0.131.0 ug/L 09/11/24 23:37 1Ethylbenzene <0.22 0.221.0 ug/L 09/11/24 23:37 1Hexachlorobutadiene <1.7 1.75.0 ug/L 09/11/24 23:37 1Iodomethane <11 1150 ug/L 09/11/24 23:37 1Isobutyl alcohol <4.9 4.910 ug/L 09/11/24 23:37 1Methacrylonitrile <0.51 0.511.0 ug/L 09/11/24 23:37 1Methyl methacrylate <0.23 0.231.0 ug/L 09/11/24 23:37 1Methylene Chloride <0.11 0.111.0 ug/L 09/11/24 23:37 1Naphthalene <5.0 5.010 ug/L 09/11/24 23:37 1Propionitrile <0.11 0.111.0 ug/L 09/11/24 23:37 1Styrene <0.17 0.171.0 ug/L 09/11/24 23:37 1Tetrachloroethene <0.53 0.531.0 ug/L 09/11/24 23:37 1Tetrahydrofuran <0.14 0.141.0 ug/L 09/11/24 23:37 1Toluene <0.21 0.211.0 ug/L 09/11/24 23:37 1trans-1,2-Dichloroethene <0.15 0.151.0 ug/L 09/11/24 23:37 1trans-1,3-Dichloropropene <0.70 0.701.0 ug/L 09/11/24 23:37 1trans-1,4-Dichloro-2-butene <0.15 0.151.0 ug/L 09/11/24 23:37 1Trichloroethene <0.24 0.241.0 ug/L 09/11/24 23:37 1Trichlorofluoromethane <0.95 0.955.0 ug/L 09/11/24 23:37 1Vinyl acetate <0.32 0.321.0 ug/L 09/11/24 23:37 1Vinyl chloride <0.45 0.453.0 ug/L 09/11/24 23:37 1Xylenes, Total 4-Bromofluorobenzene (Surr)81 53-136 09/11/24 23:37 1 MB MB Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery 109 09/11/24 23:37 1Dibromofluoromethane (Surr)67-129 91 09/11/24 23:37 1Toluene-d8 (Surr)59-134 Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-8723/4 Matrix: Water Prep Type: Total/NA Analysis Batch: 8723 1,1,1,2-Tetrachloroethane 20.0 18.6 ug/L 93 71-120 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits 1,1,1-Trichloroethane 20.0 22.2 ug/L 111 72-143 1,1,2,2-Tetrachloroethane 20.0 13.9 ug/L 69 59-133 1,1,2-Trichloroethane 20.0 18.5 ug/L 93 67-120 1,1-Dichloroethane 20.0 20.0 ug/L 100 79-141 1,1-Dichloroethene 20.0 20.5 ug/L 102 75-133 1,1-Dichloropropene 20.0 21.1 ug/L 106 70-129 1,2,3-Trichloropropane 20.0 15.4 ug/L 77 69-127 Eurofins Raleigh Page 57 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-8723/4 Matrix: Water Prep Type: Total/NA Analysis Batch: 8723 1,2,4-Trichlorobenzene 20.0 17.1 ug/L 85 59-122 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits 1,2-Dibromo-3-Chloropropane 20.0 17.1 ug/L 85 37-157 1,2-Dibromoethane 20.0 18.7 ug/L 94 66-123 1,2-Dichlorobenzene 20.0 18.6 ug/L 93 76-120 1,2-Dichloroethane 20.0 19.3 ug/L 96 72-151 1,2-Dichloropropane 20.0 18.9 ug/L 94 78-125 1,3-Dichlorobenzene 20.0 18.4 ug/L 92 76-120 1,3-Dichloropropane 20.0 18.0 ug/L 90 60-129 1,4-Dichlorobenzene 20.0 18.7 ug/L 93 76-122 2,2-Dichloropropane 20.0 20.4 ug/L 102 21-167 2-Butanone (MEK)40.0 41.3 ug/L 103 36-135 2-Hexanone 40.0 31.4 ug/L 78 36-191 3-Chloropropene 20.0 21.3 ug/L 106 17-147 4-Methyl-2-pentanone (MIBK)40.0 33.6 ug/L 84 56-166 Acetone 40.0 38.4 ug/L 96 10-158 Acetonitrile 20.0 18.1 ug/L 91 10-200 Acrolein 40.0 28.8 ug/L 72 10-200 Acrylonitrile 60.0 54.1 ug/L 90 10-200 Benzene 20.0 19.4 ug/L 97 80-134 Bromochloromethane 20.0 20.9 ug/L 104 74-128 Bromodichloromethane 20.0 20.2 ug/L 101 72-129 Bromoform 20.0 18.3 ug/L 91 73-120 Bromomethane 20.0 17.0 ug/L 85 38-189 Carbon disulfide 20.0 23.2 ug/L 116 65-173 Carbon tetrachloride 20.0 21.8 ug/L 109 68-142 Chlorobenzene 20.0 19.1 ug/L 95 80-120 Chloroethane 20.0 17.3 ug/L 86 45-213 Chloroform 20.0 18.7 ug/L 94 78-138 Chloromethane 20.0 17.1 ug/L 86 56-171 Chloroprene 20.0 20.4 ug/L 102 33-148 cis-1,2-Dichloroethene 20.0 22.5 ug/L 113 69-120 cis-1,3-Dichloropropene 20.0 19.4 ug/L 97 63-125 Dibromochloromethane 20.0 19.0 ug/L 95 73-120 Dibromomethane 20.0 20.0 ug/L 100 76-124 Dichlorodifluoromethane 20.0 20.6 ug/L 103 25-161 Ethyl methacrylate 20.0 17.9 ug/L 90 51-120 Ethylbenzene 20.0 19.6 ug/L 98 68-124 Hexachlorobutadiene 20.0 17.8 ug/L 89 63-120 Iodomethane 20.0 18.9 ug/L 94 34-140 Isobutyl alcohol 20.0 18.3 J ug/L 92 10-200 Methacrylonitrile 20.0 17.7 ug/L 88 10-200 Methyl methacrylate 20.0 20.1 ug/L 100 48-126 Methylene Chloride 20.0 18.2 ug/L 91 68-128 Naphthalene 20.0 19.1 ug/L 95 50-127 Styrene 20.0 18.8 ug/L 94 73-120 Tetrachloroethene 20.0 20.0 ug/L 100 40-181 Tetrahydrofuran 20.0 14.9 ug/L 75 0-200 Toluene 20.0 15.8 ug/L 79 71-120 trans-1,2-Dichloroethene 20.0 21.3 ug/L 106 75-139 Eurofins Raleigh Page 58 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-8723/4 Matrix: Water Prep Type: Total/NA Analysis Batch: 8723 trans-1,3-Dichloropropene 20.0 20.9 ug/L 104 65-152 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits trans-1,4-Dichloro-2-butene 20.0 15.5 ug/L 77 10-142 Trichloroethene 20.0 20.6 ug/L 103 74-120 Trichlorofluoromethane 20.0 22.7 ug/L 114 68-183 Vinyl acetate 20.0 20.9 ug/L 104 10-198 Vinyl chloride 20.0 22.3 ug/L 112 49-150 Xylenes, Total 60.0 60.0 ug/L 100 77-121 4-Bromofluorobenzene (Surr)53 -136 Surrogate 70 LCS LCS Qualifier Limits%Recovery 95Dibromofluoromethane (Surr)67 -129 93Toluene-d8 (Surr)59 -134 Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-8723/5 Matrix: Water Prep Type: Total/NA Analysis Batch: 8723 1,1,1,2-Tetrachloroethane 20.0 17.6 ug/L 88 71-120 5 16 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD 1,1,1-Trichloroethane 20.0 21.0 ug/L 105 72-143 5 18 1,1,2,2-Tetrachloroethane 20.0 13.9 ug/L 70 59-133 1 16 1,1,2-Trichloroethane 20.0 17.7 ug/L 88 67-120 5 18 1,1-Dichloroethane 20.0 19.0 ug/L 95 79-141 5 19 1,1-Dichloroethene 20.0 19.5 ug/L 98 75-133 5 20 1,1-Dichloropropene 20.0 19.7 ug/L 99 70-129 7 17 1,2,3-Trichloropropane 20.0 14.7 ug/L 74 69-127 4 17 1,2,4-Trichlorobenzene 20.0 15.9 ug/L 79 59-122 7 17 1,2-Dibromo-3-Chloropropane 20.0 15.4 ug/L 77 37-157 10 18 1,2-Dibromoethane 20.0 18.2 ug/L 91 66-123 3 15 1,2-Dichlorobenzene 20.0 17.1 ug/L 85 76-120 8 16 1,2-Dichloroethane 20.0 18.1 ug/L 91 72-151 6 16 1,2-Dichloropropane 20.0 17.9 ug/L 90 78-125 5 19 1,3-Dichlorobenzene 20.0 17.2 ug/L 86 76-120 7 17 1,3-Dichloropropane 20.0 17.1 ug/L 85 60-129 5 16 1,4-Dichlorobenzene 20.0 16.9 ug/L 84 76-122 10 16 2,2-Dichloropropane 20.0 19.4 ug/L 97 21-167 5 20 2-Butanone (MEK)40.0 39.8 ug/L 99 36-135 4 19 2-Hexanone 40.0 30.2 ug/L 75 36-191 4 17 3-Chloropropene 20.0 19.6 ug/L 98 17-147 8 19 4-Methyl-2-pentanone (MIBK)40.0 37.0 ug/L 92 56-166 10 19 Acetone 40.0 37.4 ug/L 93 10-158 3 78 Acetonitrile 20.0 12.5 *1 ug/L 63 10-200 36 35 Acrolein 40.0 26.4 ug/L 66 10-200 9 50 Acrylonitrile 60.0 52.0 ug/L 87 10-200 4 36 Benzene 20.0 18.0 ug/L 90 80-134 7 17 Bromochloromethane 20.0 20.0 ug/L 100 74-128 4 18 Bromodichloromethane 20.0 18.9 ug/L 94 72-129 7 16 Bromoform 20.0 19.0 ug/L 95 73-120 4 44 Eurofins Raleigh Page 59 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-8723/5 Matrix: Water Prep Type: Total/NA Analysis Batch: 8723 Bromomethane 20.0 17.3 ug/L 87 38-189 2 27 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Carbon disulfide 20.0 21.9 ug/L 110 65-173 5 38 Carbon tetrachloride 20.0 20.5 ug/L 102 68-142 6 17 Chlorobenzene 20.0 17.5 ug/L 88 80-120 9 16 Chloroethane 20.0 16.6 ug/L 83 45-213 4 26 Chloroform 20.0 18.3 ug/L 91 78-138 2 17 Chloromethane 20.0 15.0 ug/L 75 56-171 14 28 Chloroprene 20.0 18.9 ug/L 94 33-148 8 19 cis-1,2-Dichloroethene 20.0 20.8 ug/L 104 69-120 8 18 cis-1,3-Dichloropropene 20.0 20.7 ug/L 103 63-125 6 17 Dibromochloromethane 20.0 18.7 ug/L 94 73-120 1 16 Dibromomethane 20.0 19.2 ug/L 96 76-124 4 15 Dichlorodifluoromethane 20.0 19.0 ug/L 95 25-161 8 48 Ethyl methacrylate 20.0 16.7 ug/L 83 51-120 7 24 Ethylbenzene 20.0 17.6 ug/L 88 68-124 11 16 Hexachlorobutadiene 20.0 16.6 ug/L 83 63-120 7 19 Iodomethane 20.0 17.3 ug/L 87 34-140 8 15 Isobutyl alcohol 20.0 14.3 J *1 ug/L 72 10-200 25 20 Methacrylonitrile 20.0 17.3 ug/L 86 10-200 2 50 Methyl methacrylate 20.0 19.1 ug/L 96 48-126 5 50 Methylene Chloride 20.0 17.6 ug/L 88 68-128 4 17 Naphthalene 20.0 17.4 ug/L 87 50-127 9 19 Styrene 20.0 18.8 ug/L 94 73-120 0 23 Tetrachloroethene 20.0 19.0 ug/L 95 40-181 5 26 Tetrahydrofuran 20.0 14.9 ug/L 74 0-200 0 50 Toluene 20.0 17.7 ug/L 89 71-120 11 17 trans-1,2-Dichloroethene 20.0 20.1 ug/L 101 75-139 5 19 trans-1,3-Dichloropropene 20.0 19.3 ug/L 97 65-152 8 16 trans-1,4-Dichloro-2-butene 20.0 15.1 ug/L 75 10-142 2 28 Trichloroethene 20.0 19.1 ug/L 96 74-120 8 22 Trichlorofluoromethane 20.0 21.4 ug/L 107 68-183 6 22 Vinyl acetate 20.0 19.8 ug/L 99 10-198 6 21 Vinyl chloride 20.0 21.2 ug/L 106 49-150 5 27 Xylenes, Total 60.0 58.6 ug/L 98 77-121 2 16 4-Bromofluorobenzene (Surr)53 -136 Surrogate 81 LCSD LCSD Qualifier Limits%Recovery 101Dibromofluoromethane (Surr)67 -129 107Toluene-d8 (Surr)59 -134 Client Sample ID: Lab Control SampleLab Sample ID: MRL 752-8723/3 Matrix: Water Prep Type: Total/NA Analysis Batch: 8723 1,1,1,2-Tetrachloroethane 1.00 1.10 ug/L 110 Analyte MRL MRL DUnitResultQualifier %Rec Spike Added %Rec Limits 1,1,1-Trichloroethane 1.00 1.37 ug/L 137 1,1,2,2-Tetrachloroethane 1.00 1.00 ug/L 100 Eurofins Raleigh Page 60 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Lab Control SampleLab Sample ID: MRL 752-8723/3 Matrix: Water Prep Type: Total/NA Analysis Batch: 8723 1,1,2-Trichloroethane 1.00 1.15 ug/L 115 Analyte MRL MRL DUnitResultQualifier %Rec Spike Added %Rec Limits 1,1-Dichloroethane 1.00 1.33 ug/L 133 1,1-Dichloroethene 1.00 1.35 ug/L 135 1,1-Dichloropropene 1.00 1.29 ug/L 129 1,2,3-Trichloropropane 1.00 1.09 ug/L 109 1,2,4-Trichlorobenzene 1.00 1.55 ug/L 155 1,2-Dibromo-3-Chloropropane 1.00 1.09 ug/L 109 1,2-Dibromoethane 1.00 1.27 ug/L 127 1,2-Dichlorobenzene 1.00 1.50 ug/L 150 1,2-Dichloroethane 1.00 1.28 ug/L 128 1,2-Dichloropropane 1.00 1.13 ug/L 113 1,3-Dichlorobenzene 1.00 1.57 ug/L 157 1,3-Dichloropropane 1.00 1.19 ug/L 119 1,4-Dichlorobenzene 1.00 1.69 ug/L 169 2,2-Dichloropropane 1.00 1.10 ug/L 110 2-Butanone (MEK)2.00 <10 ug/L 115 2-Hexanone 2.00 1.79 J ug/L 89 3-Chloropropene 1.00 1.47 ug/L 147 4-Methyl-2-pentanone (MIBK)2.00 1.90 J ug/L 95 Acetone 2.00 <10 ug/L 11 Acetonitrile 10.0 12.4 ug/L 124 Acrolein 5.00 7.17 J ug/L 143 Acrylonitrile 5.00 5.52 J ug/L 110 Benzene 1.00 1.23 ug/L 123 Bromochloromethane 1.00 1.30 ug/L 130 Bromodichloromethane 1.00 1.31 ug/L 131 Bromoform 1.00 0.996 J ug/L 100 Bromomethane 1.00 1.62 ug/L 162 Carbon disulfide 2.00 3.17 J ug/L 159 Carbon tetrachloride 1.00 1.27 ug/L 127 Chlorobenzene 1.00 1.40 ug/L 140 Chloroethane 1.00 0.965 J ug/L 97 Chloroform 1.00 1.56 ug/L 156 Chloromethane 1.00 0.834 J ug/L 83 Chloroprene 1.00 1.05 ug/L 105 cis-1,2-Dichloroethene 1.00 1.38 ug/L 138 cis-1,3-Dichloropropene 1.00 1.12 ug/L 112 Dibromochloromethane 1.00 1.27 ug/L 127 Dibromomethane 1.00 1.37 ug/L 137 Dichlorodifluoromethane 1.00 1.57 ug/L 157 Ethyl methacrylate 1.00 0.866 J ug/L 87 Ethylbenzene 1.00 1.22 ug/L 122 Hexachlorobutadiene 1.00 1.68 ug/L 168 Iodomethane 2.00 1.87 J ug/L 94 Isobutyl alcohol 20.0 19.6 J ug/L 98 Methacrylonitrile 10.0 10.6 ug/L 106 Methyl methacrylate 1.00 0.956 J ug/L 96 Methylene Chloride 1.00 0.311 J ug/L 31 Naphthalene 1.00 1.16 ug/L 116 Eurofins Raleigh Page 61 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Lab Control SampleLab Sample ID: MRL 752-8723/3 Matrix: Water Prep Type: Total/NA Analysis Batch: 8723 Styrene 1.00 0.869 J ug/L 87 Analyte MRL MRL DUnitResultQualifier %Rec Spike Added %Rec Limits Tetrachloroethene 1.00 1.48 ug/L 148 Tetrahydrofuran 1.00 1.23 ug/L 123 Toluene 1.00 1.34 ug/L 134 trans-1,2-Dichloroethene 1.00 1.43 ug/L 143 trans-1,3-Dichloropropene 1.00 0.999 J ug/L 100 trans-1,4-Dichloro-2-butene 1.00 0.980 J ug/L 98 Trichloroethene 1.00 1.36 ug/L 136 Trichlorofluoromethane 1.00 1.17 ug/L 117 Vinyl acetate 2.00 0.975 J ug/L 49 Vinyl chloride 1.00 1.21 ug/L 121 Xylenes, Total 3.00 3.10 ug/L 103 4-Bromofluorobenzene (Surr)53 -136 Surrogate 66 MRL MRL Qualifier Limits%Recovery 96Dibromofluoromethane (Surr)67 -129 93Toluene-d8 (Surr)59 -134 Client Sample ID: Method BlankLab Sample ID: MB 752-8744/8 Matrix: Water Prep Type: Total/NA Analysis Batch: 8744 RL MDL 1,1,1,2-Tetrachloroethane <0.17 1.0 0.17 ug/L 09/13/24 02:14 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier <0.12 0.121.0 ug/L 09/13/24 02:14 11,1,1-Trichloroethane <0.28 0.281.0 ug/L 09/13/24 02:14 11,1,2,2-Tetrachloroethane <0.14 0.141.0 ug/L 09/13/24 02:14 11,1,2-Trichloroethane <0.13 0.131.0 ug/L 09/13/24 02:14 11,1-Dichloroethane <0.21 0.211.0 ug/L 09/13/24 02:14 11,1-Dichloroethene <0.15 0.151.0 ug/L 09/13/24 02:14 11,1-Dichloropropene <0.49 0.491.0 ug/L 09/13/24 02:14 11,2,3-Trichloropropane 0.140 J 0.141.0 ug/L 09/13/24 02:14 11,2,4-Trichlorobenzene <0.48 0.481.0 ug/L 09/13/24 02:14 11,2-Dibromo-3-Chloropropane <0.66 0.661.0 ug/L 09/13/24 02:14 11,2-Dibromoethane <0.19 0.191.0 ug/L 09/13/24 02:14 11,2-Dichlorobenzene <0.21 0.211.0 ug/L 09/13/24 02:14 11,2-Dichloroethane <0.10 0.101.0 ug/L 09/13/24 02:14 11,2-Dichloropropane <0.15 0.151.0 ug/L 09/13/24 02:14 11,3-Dichlorobenzene <0.16 0.161.0 ug/L 09/13/24 02:14 11,3-Dichloropropane <0.19 0.191.0 ug/L 09/13/24 02:14 11,4-Dichlorobenzene <0.28 0.281.0 ug/L 09/13/24 02:14 12,2-Dichloropropane <10 1020 ug/L 09/13/24 02:14 12-Butanone (MEK) <0.88 0.885.0 ug/L 09/13/24 02:14 12-Hexanone <0.11 0.111.0 ug/L 09/13/24 02:14 13-Chloropropene <1.1 1.15.0 ug/L 09/13/24 02:14 14-Methyl-2-pentanone (MIBK) <10 1020 ug/L 09/13/24 02:14 1Acetone <5.0 5.010 ug/L 09/13/24 02:14 1Acetonitrile <4.0 4.010 ug/L 09/13/24 02:14 1Acrolein Eurofins Raleigh Page 62 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Method BlankLab Sample ID: MB 752-8744/8 Matrix: Water Prep Type: Total/NA Analysis Batch: 8744 RL MDL Acrylonitrile <3.5 10 3.5 ug/L 09/13/24 02:14 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier <0.15 0.151.0 ug/L 09/13/24 02:14 1Benzene <0.48 0.481.0 ug/L 09/13/24 02:14 1Bromochloromethane <0.17 0.171.0 ug/L 09/13/24 02:14 1Bromodichloromethane <0.22 0.221.0 ug/L 09/13/24 02:14 1Bromoform <0.14 0.141.0 ug/L 09/13/24 02:14 1Bromomethane <1.5 1.55.0 ug/L 09/13/24 02:14 1Carbon disulfide <0.17 0.171.0 ug/L 09/13/24 02:14 1Carbon tetrachloride <0.17 0.171.0 ug/L 09/13/24 02:14 1Chlorobenzene <0.23 0.231.0 ug/L 09/13/24 02:14 1Chloroethane 0.292 J 0.181.0 ug/L 09/13/24 02:14 1Chloroform <0.13 0.131.0 ug/L 09/13/24 02:14 1Chloromethane <0.64 0.641.0 ug/L 09/13/24 02:14 1Chloroprene <0.15 0.151.0 ug/L 09/13/24 02:14 1cis-1,2-Dichloroethene <0.20 0.201.0 ug/L 09/13/24 02:14 1cis-1,3-Dichloropropene <0.17 0.171.0 ug/L 09/13/24 02:14 1Dibromochloromethane <0.27 0.271.0 ug/L 09/13/24 02:14 1Dibromomethane <0.20 0.201.0 ug/L 09/13/24 02:14 1Dichlorodifluoromethane <0.38 0.381.0 ug/L 09/13/24 02:14 1Ethyl methacrylate <0.13 0.131.0 ug/L 09/13/24 02:14 1Ethylbenzene <0.22 0.221.0 ug/L 09/13/24 02:14 1Hexachlorobutadiene <1.7 1.75.0 ug/L 09/13/24 02:14 1Iodomethane <11 1150 ug/L 09/13/24 02:14 1Isobutyl alcohol <4.9 4.910 ug/L 09/13/24 02:14 1Methacrylonitrile <0.51 0.511.0 ug/L 09/13/24 02:14 1Methyl methacrylate <0.23 0.231.0 ug/L 09/13/24 02:14 1Methylene Chloride <0.11 0.111.0 ug/L 09/13/24 02:14 1Naphthalene <5.0 5.010 ug/L 09/13/24 02:14 1Propionitrile <0.11 0.111.0 ug/L 09/13/24 02:14 1Styrene <0.17 0.171.0 ug/L 09/13/24 02:14 1Tetrachloroethene <0.53 0.531.0 ug/L 09/13/24 02:14 1Tetrahydrofuran 0.194 J 0.141.0 ug/L 09/13/24 02:14 1Toluene <0.21 0.211.0 ug/L 09/13/24 02:14 1trans-1,2-Dichloroethene <0.15 0.151.0 ug/L 09/13/24 02:14 1trans-1,3-Dichloropropene <0.70 0.701.0 ug/L 09/13/24 02:14 1trans-1,4-Dichloro-2-butene <0.15 0.151.0 ug/L 09/13/24 02:14 1Trichloroethene <0.24 0.241.0 ug/L 09/13/24 02:14 1Trichlorofluoromethane <0.95 0.955.0 ug/L 09/13/24 02:14 1Vinyl acetate <0.32 0.321.0 ug/L 09/13/24 02:14 1Vinyl chloride <0.45 0.453.0 ug/L 09/13/24 02:14 1Xylenes, Total 4-Bromofluorobenzene (Surr)82 53-136 09/13/24 02:14 1 MB MB Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery 100 09/13/24 02:14 1Dibromofluoromethane (Surr)67-129 85 09/13/24 02:14 1Toluene-d8 (Surr)59-134 Eurofins Raleigh Page 63 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-8744/4 Matrix: Water Prep Type: Total/NA Analysis Batch: 8744 1,1,1,2-Tetrachloroethane 20.0 18.6 ug/L 93 71-120 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits 1,1,1-Trichloroethane 20.0 22.1 ug/L 110 72-143 1,1,2,2-Tetrachloroethane 20.0 15.9 ug/L 79 59-133 1,1,2-Trichloroethane 20.0 17.4 ug/L 87 67-120 1,1-Dichloroethane 20.0 20.0 ug/L 100 79-141 1,1-Dichloroethene 20.0 20.1 ug/L 101 75-133 1,1-Dichloropropene 20.0 20.5 ug/L 102 70-129 1,2,3-Trichloropropane 20.0 17.9 ug/L 89 69-127 1,2,4-Trichlorobenzene 20.0 20.4 ug/L 102 59-122 1,2-Dibromo-3-Chloropropane 20.0 21.3 ug/L 106 37-157 1,2-Dibromoethane 20.0 18.1 ug/L 90 66-123 1,2-Dichlorobenzene 20.0 18.5 ug/L 92 76-120 1,2-Dichloroethane 20.0 18.7 ug/L 94 72-151 1,2-Dichloropropane 20.0 18.3 ug/L 92 78-125 1,3-Dichlorobenzene 20.0 18.6 ug/L 93 76-120 1,3-Dichloropropane 20.0 17.2 ug/L 86 60-129 1,4-Dichlorobenzene 20.0 18.2 ug/L 91 76-122 2,2-Dichloropropane 20.0 20.7 ug/L 103 21-167 2-Butanone (MEK)40.0 39.5 ug/L 99 36-135 2-Hexanone 40.0 30.1 ug/L 75 36-191 3-Chloropropene 20.0 21.3 ug/L 107 17-147 4-Methyl-2-pentanone (MIBK)40.0 32.2 ug/L 80 56-166 Acetone 40.0 38.2 ug/L 95 10-158 Acetonitrile 20.0 13.0 ug/L 65 10-200 Acrolein 40.0 29.4 ug/L 73 10-200 Acrylonitrile 60.0 51.8 ug/L 86 10-200 Benzene 20.0 18.9 ug/L 95 80-134 Bromochloromethane 20.0 20.1 ug/L 101 74-128 Bromodichloromethane 20.0 19.6 ug/L 98 72-129 Bromoform 20.0 19.1 ug/L 95 73-120 Bromomethane 20.0 19.9 ug/L 100 38-189 Carbon disulfide 20.0 22.9 ug/L 114 65-173 Carbon tetrachloride 20.0 21.5 ug/L 108 68-142 Chlorobenzene 20.0 18.8 ug/L 94 80-120 Chloroethane 20.0 17.7 ug/L 89 45-213 Chloroform 20.0 18.8 ug/L 94 78-138 Chloromethane 20.0 16.4 ug/L 82 56-171 Chloroprene 20.0 19.4 ug/L 97 33-148 cis-1,2-Dichloroethene 20.0 21.9 ug/L 109 69-120 cis-1,3-Dichloropropene 20.0 19.0 ug/L 95 63-125 Dibromochloromethane 20.0 19.2 ug/L 96 73-120 Dibromomethane 20.0 19.9 ug/L 99 76-124 Dichlorodifluoromethane 20.0 17.5 ug/L 88 25-161 Ethyl methacrylate 20.0 17.2 ug/L 86 51-120 Ethylbenzene 20.0 19.1 ug/L 96 68-124 Hexachlorobutadiene 20.0 22.5 ug/L 113 63-120 Iodomethane 20.0 20.1 ug/L 101 34-140 Isobutyl alcohol 20.0 14.2 J ug/L 71 10-200 Eurofins Raleigh Page 64 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-8744/4 Matrix: Water Prep Type: Total/NA Analysis Batch: 8744 Methacrylonitrile 20.0 16.8 ug/L 84 10-200 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Methyl methacrylate 20.0 18.7 ug/L 94 48-126 Methylene Chloride 20.0 18.5 ug/L 92 68-128 Naphthalene 20.0 19.9 ug/L 100 50-127 Styrene 20.0 19.4 ug/L 97 73-120 Tetrachloroethene 20.0 19.4 ug/L 97 40-181 Tetrahydrofuran 20.0 14.8 ug/L 74 0-200 Toluene 20.0 18.0 ug/L 90 71-120 trans-1,2-Dichloroethene 20.0 21.1 ug/L 105 75-139 trans-1,3-Dichloropropene 20.0 19.3 ug/L 96 65-152 trans-1,4-Dichloro-2-butene 20.0 17.8 ug/L 89 10-142 Trichloroethene 20.0 20.6 ug/L 103 74-120 Trichlorofluoromethane 20.0 21.5 ug/L 108 68-183 Vinyl acetate 20.0 19.2 ug/L 96 10-198 Vinyl chloride 20.0 25.7 ug/L 128 49-150 Xylenes, Total 60.0 59.9 ug/L 100 77-121 4-Bromofluorobenzene (Surr)53 -136 Surrogate 78 LCS LCS Qualifier Limits%Recovery 90Dibromofluoromethane (Surr)67 -129 86Toluene-d8 (Surr)59 -134 Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-8744/5 Matrix: Water Prep Type: Total/NA Analysis Batch: 8744 1,1,1,2-Tetrachloroethane 20.0 17.5 ug/L 87 71-120 6 16 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD 1,1,1-Trichloroethane 20.0 20.8 ug/L 104 72-143 6 18 1,1,2,2-Tetrachloroethane 20.0 15.2 ug/L 76 59-133 4 16 1,1,2-Trichloroethane 20.0 17.1 ug/L 86 67-120 2 18 1,1-Dichloroethane 20.0 19.2 ug/L 96 79-141 4 19 1,1-Dichloroethene 20.0 19.3 ug/L 96 75-133 4 20 1,1-Dichloropropene 20.0 19.3 ug/L 97 70-129 6 17 1,2,3-Trichloropropane 20.0 16.9 ug/L 85 69-127 5 17 1,2,4-Trichlorobenzene 20.0 18.7 ug/L 93 59-122 9 17 1,2-Dibromo-3-Chloropropane 20.0 16.5 *1 ug/L 82 37-157 25 18 1,2-Dibromoethane 20.0 17.6 ug/L 88 66-123 3 15 1,2-Dichlorobenzene 20.0 17.7 ug/L 89 76-120 4 16 1,2-Dichloroethane 20.0 18.0 ug/L 90 72-151 4 16 1,2-Dichloropropane 20.0 17.2 ug/L 86 78-125 7 19 1,3-Dichlorobenzene 20.0 17.9 ug/L 90 76-120 4 17 1,3-Dichloropropane 20.0 16.6 ug/L 83 60-129 3 16 1,4-Dichlorobenzene 20.0 17.2 ug/L 86 76-122 6 16 2,2-Dichloropropane 20.0 19.2 ug/L 96 21-167 8 20 2-Butanone (MEK)40.0 39.1 ug/L 98 36-135 1 19 2-Hexanone 40.0 29.3 ug/L 73 36-191 2 17 3-Chloropropene 20.0 20.2 ug/L 101 17-147 6 19 Eurofins Raleigh Page 65 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-8744/5 Matrix: Water Prep Type: Total/NA Analysis Batch: 8744 4-Methyl-2-pentanone (MIBK)40.0 31.5 ug/L 79 56-166 2 19 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Acetone 40.0 32.0 ug/L 80 10-158 17 78 Acetonitrile 20.0 12.7 ug/L 63 10-200 2 35 Acrolein 40.0 27.8 ug/L 70 10-200 5 50 Acrylonitrile 60.0 52.4 ug/L 87 10-200 1 36 Benzene 20.0 17.9 ug/L 89 80-134 6 17 Bromochloromethane 20.0 19.7 ug/L 99 74-128 2 18 Bromodichloromethane 20.0 18.7 ug/L 94 72-129 5 16 Bromoform 20.0 18.9 ug/L 95 73-120 1 44 Bromomethane 20.0 18.7 ug/L 94 38-189 6 27 Carbon disulfide 20.0 22.0 ug/L 110 65-173 4 38 Carbon tetrachloride 20.0 20.1 ug/L 101 68-142 7 17 Chlorobenzene 20.0 18.0 ug/L 90 80-120 5 16 Chloroethane 20.0 16.9 ug/L 85 45-213 5 26 Chloroform 20.0 18.1 ug/L 90 78-138 4 17 Chloromethane 20.0 14.6 ug/L 73 56-171 12 28 Chloroprene 20.0 18.3 ug/L 92 33-148 6 19 cis-1,2-Dichloroethene 20.0 20.9 ug/L 105 69-120 4 18 cis-1,3-Dichloropropene 20.0 18.1 ug/L 90 63-125 5 17 Dibromochloromethane 20.0 18.4 ug/L 92 73-120 5 16 Dibromomethane 20.0 19.0 ug/L 95 76-124 4 15 Dichlorodifluoromethane 20.0 19.7 ug/L 99 25-161 12 48 Ethyl methacrylate 20.0 16.5 ug/L 82 51-120 4 24 Ethylbenzene 20.0 18.2 ug/L 91 68-124 5 16 Hexachlorobutadiene 20.0 18.7 ug/L 94 63-120 19 19 Iodomethane 20.0 19.4 ug/L 97 34-140 3 15 Isobutyl alcohol 20.0 12.3 J ug/L 62 10-200 14 20 Methacrylonitrile 20.0 16.9 ug/L 85 10-200 1 50 Methyl methacrylate 20.0 19.1 ug/L 95 48-126 2 50 Methylene Chloride 20.0 18.2 ug/L 91 68-128 1 17 Naphthalene 20.0 23.8 ug/L 119 50-127 18 19 Styrene 20.0 18.2 ug/L 91 73-120 7 23 Tetrachloroethene 20.0 18.2 ug/L 91 40-181 6 26 Tetrahydrofuran 20.0 14.1 ug/L 70 0-200 5 50 Toluene 20.0 17.3 ug/L 86 71-120 4 17 trans-1,2-Dichloroethene 20.0 20.4 ug/L 102 75-139 3 19 trans-1,3-Dichloropropene 20.0 19.2 ug/L 96 65-152 0 16 trans-1,4-Dichloro-2-butene 20.0 16.7 ug/L 84 10-142 7 28 Trichloroethene 20.0 19.7 ug/L 98 74-120 5 22 Trichlorofluoromethane 20.0 21.1 ug/L 105 68-183 2 22 Vinyl acetate 20.0 18.2 ug/L 91 10-198 5 21 Vinyl chloride 20.0 22.2 ug/L 111 49-150 15 27 Xylenes, Total 60.0 56.5 ug/L 94 77-121 6 16 4-Bromofluorobenzene (Surr)53 -136 Surrogate 83 LCSD LCSD Qualifier Limits%Recovery 92Dibromofluoromethane (Surr)67 -129 90Toluene-d8 (Surr)59 -134 Eurofins Raleigh Page 66 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Lab Control SampleLab Sample ID: MRL 752-8744/3 Matrix: Water Prep Type: Total/NA Analysis Batch: 8744 1,1,1,2-Tetrachloroethane 1.00 1.22 ug/L 122 Analyte MRL MRL DUnitResultQualifier %Rec Spike Added %Rec Limits 1,1,1-Trichloroethane 1.00 1.59 ug/L 159 1,1,2,2-Tetrachloroethane 1.00 1.13 ug/L 113 1,1,2-Trichloroethane 1.00 1.12 ug/L 112 1,1-Dichloroethane 1.00 1.47 ug/L 147 1,1-Dichloroethene 1.00 1.50 ug/L 150 1,1-Dichloropropene 1.00 1.54 ug/L 154 1,2,3-Trichloropropane 1.00 1.26 ug/L 126 1,2,4-Trichlorobenzene 1.00 1.31 ug/L 131 1,2-Dibromo-3-Chloropropane 1.00 0.779 J ug/L 78 1,2-Dibromoethane 1.00 1.19 ug/L 119 1,2-Dichlorobenzene 1.00 1.29 ug/L 129 1,2-Dichloroethane 1.00 1.27 ug/L 127 1,2-Dichloropropane 1.00 1.20 ug/L 120 1,3-Dichlorobenzene 1.00 1.58 ug/L 158 1,3-Dichloropropane 1.00 1.15 ug/L 115 1,4-Dichlorobenzene 1.00 1.70 ug/L 170 2,2-Dichloropropane 1.00 1.33 ug/L 133 2-Butanone (MEK)2.00 <10 ug/L 144 2-Hexanone 2.00 1.56 J ug/L 78 3-Chloropropene 1.00 1.42 ug/L 142 4-Methyl-2-pentanone (MIBK)2.00 1.63 J ug/L 82 Acetone 2.00 <10 ug/L 54 Acetonitrile 10.0 11.1 ug/L 111 Acrolein 5.00 6.65 J ug/L 133 Acrylonitrile 5.00 5.71 J ug/L 114 Benzene 1.00 1.42 ug/L 142 Bromochloromethane 1.00 1.39 ug/L 139 Bromodichloromethane 1.00 1.26 ug/L 126 Bromoform 1.00 1.27 ug/L 127 Bromomethane 1.00 1.49 ug/L 149 Carbon disulfide 2.00 3.51 J ug/L 175 Carbon tetrachloride 1.00 1.48 ug/L 148 Chlorobenzene 1.00 1.53 ug/L 153 Chloroethane 1.00 1.16 ug/L 116 Chloroform 1.00 1.57 ug/L 157 Chloromethane 1.00 0.752 J ug/L 75 Chloroprene 1.00 1.24 ug/L 124 cis-1,2-Dichloroethene 1.00 1.44 ug/L 144 cis-1,3-Dichloropropene 1.00 1.10 ug/L 110 Dibromochloromethane 1.00 1.21 ug/L 121 Dibromomethane 1.00 1.28 ug/L 128 Dichlorodifluoromethane 1.00 1.41 ug/L 141 Ethyl methacrylate 1.00 0.882 J ug/L 88 Ethylbenzene 1.00 1.47 ug/L 147 Hexachlorobutadiene 1.00 1.50 ug/L 150 Iodomethane 2.00 2.28 J ug/L 114 Isobutyl alcohol 20.0 12.2 J ug/L 61 Eurofins Raleigh Page 67 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Lab Control SampleLab Sample ID: MRL 752-8744/3 Matrix: Water Prep Type: Total/NA Analysis Batch: 8744 Methacrylonitrile 10.0 10.4 ug/L 104 Analyte MRL MRL DUnitResultQualifier %Rec Spike Added %Rec Limits Methyl methacrylate 1.00 0.939 J ug/L 94 Methylene Chloride 1.00 0.427 J ug/L 43 Naphthalene 1.00 0.969 J ug/L 97 Styrene 1.00 1.37 ug/L 137 Tetrachloroethene 1.00 1.56 ug/L 156 Tetrahydrofuran 1.00 1.35 ug/L 135 Toluene 1.00 1.61 ug/L 161 trans-1,2-Dichloroethene 1.00 1.91 ug/L 191 trans-1,3-Dichloropropene 1.00 1.11 ug/L 111 trans-1,4-Dichloro-2-butene 1.00 1.12 ug/L 112 Trichloroethene 1.00 1.60 ug/L 160 Trichlorofluoromethane 1.00 1.31 ug/L 131 Vinyl acetate 2.00 1.62 J ug/L 81 Vinyl chloride 1.00 1.47 ug/L 147 Xylenes, Total 3.00 4.24 ug/L 141 4-Bromofluorobenzene (Surr)53 -136 Surrogate 85 MRL MRL Qualifier Limits%Recovery 100Dibromofluoromethane (Surr)67 -129 87Toluene-d8 (Surr)59 -134 Client Sample ID: Method BlankLab Sample ID: MB 752-8754/8 Matrix: Water Prep Type: Total/NA Analysis Batch: 8754 RL MDL 1,1,1,2-Tetrachloroethane <0.17 1.0 0.17 ug/L 09/13/24 19:10 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier <0.12 0.121.0 ug/L 09/13/24 19:10 11,1,1-Trichloroethane <0.28 0.281.0 ug/L 09/13/24 19:10 11,1,2,2-Tetrachloroethane <0.14 0.141.0 ug/L 09/13/24 19:10 11,1,2-Trichloroethane <0.13 0.131.0 ug/L 09/13/24 19:10 11,1-Dichloroethane <0.21 0.211.0 ug/L 09/13/24 19:10 11,1-Dichloroethene <0.15 0.151.0 ug/L 09/13/24 19:10 11,1-Dichloropropene <0.49 0.491.0 ug/L 09/13/24 19:10 11,2,3-Trichloropropane <0.14 0.141.0 ug/L 09/13/24 19:10 11,2,4-Trichlorobenzene <0.48 0.481.0 ug/L 09/13/24 19:10 11,2-Dibromo-3-Chloropropane <0.66 0.661.0 ug/L 09/13/24 19:10 11,2-Dibromoethane <0.19 0.191.0 ug/L 09/13/24 19:10 11,2-Dichlorobenzene <0.21 0.211.0 ug/L 09/13/24 19:10 11,2-Dichloroethane <0.10 0.101.0 ug/L 09/13/24 19:10 11,2-Dichloropropane <0.15 0.151.0 ug/L 09/13/24 19:10 11,3-Dichlorobenzene <0.16 0.161.0 ug/L 09/13/24 19:10 11,3-Dichloropropane <0.19 0.191.0 ug/L 09/13/24 19:10 11,4-Dichlorobenzene <0.28 0.281.0 ug/L 09/13/24 19:10 12,2-Dichloropropane <10 1020 ug/L 09/13/24 19:10 12-Butanone (MEK) <0.88 0.885.0 ug/L 09/13/24 19:10 12-Hexanone <0.11 0.111.0 ug/L 09/13/24 19:10 13-Chloropropene Eurofins Raleigh Page 68 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Method BlankLab Sample ID: MB 752-8754/8 Matrix: Water Prep Type: Total/NA Analysis Batch: 8754 RL MDL 4-Methyl-2-pentanone (MIBK)<1.1 5.0 1.1 ug/L 09/13/24 19:10 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier <10 1020 ug/L 09/13/24 19:10 1Acetone <5.0 5.010 ug/L 09/13/24 19:10 1Acetonitrile <4.0 4.010 ug/L 09/13/24 19:10 1Acrolein <3.5 3.510 ug/L 09/13/24 19:10 1Acrylonitrile <0.15 0.151.0 ug/L 09/13/24 19:10 1Benzene <0.48 0.481.0 ug/L 09/13/24 19:10 1Bromochloromethane <0.17 0.171.0 ug/L 09/13/24 19:10 1Bromodichloromethane <0.22 0.221.0 ug/L 09/13/24 19:10 1Bromoform <0.14 0.141.0 ug/L 09/13/24 19:10 1Bromomethane <1.5 1.55.0 ug/L 09/13/24 19:10 1Carbon disulfide <0.17 0.171.0 ug/L 09/13/24 19:10 1Carbon tetrachloride <0.17 0.171.0 ug/L 09/13/24 19:10 1Chlorobenzene <0.23 0.231.0 ug/L 09/13/24 19:10 1Chloroethane <0.18 0.181.0 ug/L 09/13/24 19:10 1Chloroform <0.13 0.131.0 ug/L 09/13/24 19:10 1Chloromethane <0.64 0.641.0 ug/L 09/13/24 19:10 1Chloroprene <0.15 0.151.0 ug/L 09/13/24 19:10 1cis-1,2-Dichloroethene <0.20 0.201.0 ug/L 09/13/24 19:10 1cis-1,3-Dichloropropene <0.17 0.171.0 ug/L 09/13/24 19:10 1Dibromochloromethane <0.27 0.271.0 ug/L 09/13/24 19:10 1Dibromomethane <0.20 0.201.0 ug/L 09/13/24 19:10 1Dichlorodifluoromethane <0.38 0.381.0 ug/L 09/13/24 19:10 1Ethyl methacrylate <0.13 0.131.0 ug/L 09/13/24 19:10 1Ethylbenzene <0.22 0.221.0 ug/L 09/13/24 19:10 1Hexachlorobutadiene <1.7 1.75.0 ug/L 09/13/24 19:10 1Iodomethane <11 1150 ug/L 09/13/24 19:10 1Isobutyl alcohol <4.9 4.910 ug/L 09/13/24 19:10 1Methacrylonitrile <0.51 0.511.0 ug/L 09/13/24 19:10 1Methyl methacrylate <0.23 0.231.0 ug/L 09/13/24 19:10 1Methylene Chloride <0.11 0.111.0 ug/L 09/13/24 19:10 1Naphthalene <5.0 5.010 ug/L 09/13/24 19:10 1Propionitrile <0.11 0.111.0 ug/L 09/13/24 19:10 1Styrene <0.17 0.171.0 ug/L 09/13/24 19:10 1Tetrachloroethene <0.53 0.531.0 ug/L 09/13/24 19:10 1Tetrahydrofuran <0.14 0.141.0 ug/L 09/13/24 19:10 1Toluene <0.21 0.211.0 ug/L 09/13/24 19:10 1trans-1,2-Dichloroethene <0.15 0.151.0 ug/L 09/13/24 19:10 1trans-1,3-Dichloropropene <0.70 0.701.0 ug/L 09/13/24 19:10 1trans-1,4-Dichloro-2-butene <0.15 0.151.0 ug/L 09/13/24 19:10 1Trichloroethene <0.24 0.241.0 ug/L 09/13/24 19:10 1Trichlorofluoromethane <0.95 0.955.0 ug/L 09/13/24 19:10 1Vinyl acetate <0.32 0.321.0 ug/L 09/13/24 19:10 1Vinyl chloride <0.45 0.453.0 ug/L 09/13/24 19:10 1Xylenes, Total 4-Bromofluorobenzene (Surr)79 53-136 09/13/24 19:10 1 MB MB Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery 105 09/13/24 19:10 1Dibromofluoromethane (Surr)67-129 Eurofins Raleigh Page 69 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Method BlankLab Sample ID: MB 752-8754/8 Matrix: Water Prep Type: Total/NA Analysis Batch: 8754 Toluene-d8 (Surr)94 59-134 09/13/24 19:10 1 MB MB Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-8754/4 Matrix: Water Prep Type: Total/NA Analysis Batch: 8754 1,1,1,2-Tetrachloroethane 20.0 18.6 ug/L 93 71-120 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits 1,1,1-Trichloroethane 20.0 24.3 ug/L 122 72-143 1,1,2,2-Tetrachloroethane 20.0 18.6 ug/L 93 59-133 1,1,2-Trichloroethane 20.0 19.6 ug/L 98 67-120 1,1-Dichloroethane 20.0 24.1 ug/L 121 79-141 1,1-Dichloroethene 20.0 24.4 ug/L 122 75-133 1,1-Dichloropropene 20.0 25.4 ug/L 127 70-129 1,2,3-Trichloropropane 20.0 18.0 ug/L 90 69-127 1,2,4-Trichlorobenzene 20.0 18.2 ug/L 91 59-122 1,2-Dibromo-3-Chloropropane 20.0 18.2 ug/L 91 37-157 1,2-Dibromoethane 20.0 19.2 ug/L 96 66-123 1,2-Dichlorobenzene 20.0 18.9 ug/L 94 76-120 1,2-Dichloroethane 20.0 20.6 ug/L 103 72-151 1,2-Dichloropropane 20.0 22.5 ug/L 113 78-125 1,3-Dichlorobenzene 20.0 18.6 ug/L 93 76-120 1,3-Dichloropropane 20.0 18.9 ug/L 94 60-129 1,4-Dichlorobenzene 20.0 18.5 ug/L 92 76-122 2,2-Dichloropropane 20.0 27.4 ug/L 137 21-167 2-Butanone (MEK)40.0 51.8 ug/L 129 36-135 2-Hexanone 40.0 38.1 ug/L 95 36-191 3-Chloropropene 20.0 26.0 ug/L 130 17-147 4-Methyl-2-pentanone (MIBK)40.0 42.7 ug/L 107 56-166 Acetone 40.0 49.2 ug/L 123 10-158 Acetonitrile 20.0 17.4 ug/L 87 10-200 Acrolein 40.0 38.1 ug/L 95 10-200 Acrylonitrile 60.0 70.2 ug/L 117 10-200 Benzene 20.0 22.6 ug/L 113 80-134 Bromochloromethane 20.0 22.9 ug/L 115 74-128 Bromodichloromethane 20.0 21.3 ug/L 106 72-129 Bromoform 20.0 19.4 ug/L 97 73-120 Bromomethane 20.0 21.2 ug/L 106 38-189 Carbon disulfide 20.0 27.0 ug/L 135 65-173 Carbon tetrachloride 20.0 22.7 ug/L 114 68-142 Chlorobenzene 20.0 19.4 ug/L 97 80-120 Chloroethane 20.0 22.2 ug/L 111 45-213 Chloroform 20.0 21.3 ug/L 106 78-138 Chloromethane 20.0 19.1 ug/L 95 56-171 Chloroprene 20.0 24.7 ug/L 123 33-148 cis-1,2-Dichloroethene 20.0 26.8 *+ug/L 134 69-120 cis-1,3-Dichloropropene 20.0 22.6 ug/L 113 63-125 Dibromochloromethane 20.0 19.0 ug/L 95 73-120 Eurofins Raleigh Page 70 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-8754/4 Matrix: Water Prep Type: Total/NA Analysis Batch: 8754 Dibromomethane 20.0 21.4 ug/L 107 76-124 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Dichlorodifluoromethane 20.0 26.9 ug/L 134 25-161 Ethyl methacrylate 20.0 19.7 ug/L 99 51-120 Ethylbenzene 20.0 20.5 ug/L 103 68-124 Hexachlorobutadiene 20.0 19.5 ug/L 97 63-120 Iodomethane 20.0 21.3 ug/L 106 34-140 Isobutyl alcohol 20.0 20.0 J ug/L 100 10-200 Methacrylonitrile 20.0 22.4 ug/L 112 10-200 Methyl methacrylate 20.0 23.6 ug/L 118 48-126 Methylene Chloride 20.0 22.3 ug/L 111 68-128 Naphthalene 20.0 19.7 ug/L 99 50-127 Styrene 20.0 20.4 ug/L 102 73-120 Tetrachloroethene 20.0 20.1 ug/L 101 40-181 Tetrahydrofuran 20.0 20.7 ug/L 104 0-200 Toluene 20.0 19.4 ug/L 97 71-120 trans-1,2-Dichloroethene 20.0 24.5 ug/L 123 75-139 trans-1,3-Dichloropropene 20.0 21.6 ug/L 108 65-152 trans-1,4-Dichloro-2-butene 20.0 20.7 ug/L 103 10-142 Trichloroethene 20.0 21.5 ug/L 108 74-120 Trichlorofluoromethane 20.0 24.8 ug/L 124 68-183 Vinyl acetate 20.0 30.9 ug/L 154 10-198 Vinyl chloride 20.0 20.7 ug/L 103 49-150 Xylenes, Total 60.0 63.0 ug/L 105 77-121 4-Bromofluorobenzene (Surr)53 -136 Surrogate 90 LCS LCS Qualifier Limits%Recovery 103Dibromofluoromethane (Surr)67 -129 103Toluene-d8 (Surr)59 -134 Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-8754/5 Matrix: Water Prep Type: Total/NA Analysis Batch: 8754 1,1,1,2-Tetrachloroethane 20.0 17.7 ug/L 89 71-120 5 16 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD 1,1,1-Trichloroethane 20.0 22.2 ug/L 111 72-143 9 18 1,1,2,2-Tetrachloroethane 20.0 18.0 ug/L 90 59-133 3 16 1,1,2-Trichloroethane 20.0 18.5 ug/L 93 67-120 6 18 1,1-Dichloroethane 20.0 22.3 ug/L 111 79-141 8 19 1,1-Dichloroethene 20.0 22.0 ug/L 110 75-133 10 20 1,1-Dichloropropene 20.0 23.5 ug/L 117 70-129 8 17 1,2,3-Trichloropropane 20.0 17.6 ug/L 88 69-127 2 17 1,2,4-Trichlorobenzene 20.0 17.8 ug/L 89 59-122 2 17 1,2-Dibromo-3-Chloropropane 20.0 18.7 ug/L 94 37-157 3 18 1,2-Dibromoethane 20.0 18.5 ug/L 93 66-123 4 15 1,2-Dichlorobenzene 20.0 18.3 ug/L 92 76-120 3 16 1,2-Dichloroethane 20.0 18.9 ug/L 94 72-151 9 16 1,2-Dichloropropane 20.0 20.8 ug/L 104 78-125 8 19 Eurofins Raleigh Page 71 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-8754/5 Matrix: Water Prep Type: Total/NA Analysis Batch: 8754 1,3-Dichlorobenzene 20.0 18.3 ug/L 92 76-120 1 17 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD 1,3-Dichloropropane 20.0 18.4 ug/L 92 60-129 3 16 1,4-Dichlorobenzene 20.0 18.0 ug/L 90 76-122 2 16 2,2-Dichloropropane 20.0 24.4 ug/L 122 21-167 12 20 2-Butanone (MEK)40.0 50.1 ug/L 125 36-135 3 19 2-Hexanone 40.0 37.3 ug/L 93 36-191 2 17 3-Chloropropene 20.0 23.7 ug/L 118 17-147 9 19 4-Methyl-2-pentanone (MIBK)40.0 41.2 ug/L 103 56-166 3 19 Acetone 40.0 47.6 ug/L 119 10-158 3 78 Acetonitrile 20.0 18.2 ug/L 91 10-200 5 35 Acrolein 40.0 35.4 ug/L 88 10-200 7 50 Acrylonitrile 60.0 68.2 ug/L 114 10-200 3 36 Benzene 20.0 20.5 ug/L 103 80-134 10 17 Bromochloromethane 20.0 21.7 ug/L 108 74-128 6 18 Bromodichloromethane 20.0 19.5 ug/L 97 72-129 9 16 Bromoform 20.0 19.2 ug/L 96 73-120 1 44 Bromomethane 20.0 19.7 ug/L 99 38-189 7 27 Carbon disulfide 20.0 24.8 ug/L 124 65-173 8 38 Carbon tetrachloride 20.0 20.5 ug/L 103 68-142 10 17 Chlorobenzene 20.0 18.4 ug/L 92 80-120 5 16 Chloroethane 20.0 19.0 ug/L 95 45-213 15 26 Chloroform 20.0 19.6 ug/L 98 78-138 8 17 Chloromethane 20.0 17.4 ug/L 87 56-171 9 28 Chloroprene 20.0 22.8 ug/L 114 33-148 8 19 cis-1,2-Dichloroethene 20.0 25.2 *+ug/L 126 69-120 6 18 cis-1,3-Dichloropropene 20.0 21.6 ug/L 108 63-125 4 17 Dibromochloromethane 20.0 18.5 ug/L 93 73-120 2 16 Dibromomethane 20.0 20.2 ug/L 101 76-124 6 15 Dichlorodifluoromethane 20.0 24.3 ug/L 121 25-161 10 48 Ethyl methacrylate 20.0 19.3 ug/L 97 51-120 2 24 Ethylbenzene 20.0 19.3 ug/L 96 68-124 6 16 Hexachlorobutadiene 20.0 18.0 ug/L 90 63-120 8 19 Iodomethane 20.0 18.9 ug/L 95 34-140 12 15 Isobutyl alcohol 20.0 22.8 J ug/L 114 10-200 13 20 Methacrylonitrile 20.0 21.7 ug/L 109 10-200 3 50 Methyl methacrylate 20.0 22.4 ug/L 112 48-126 5 50 Methylene Chloride 20.0 20.6 ug/L 103 68-128 8 17 Naphthalene 20.0 19.7 ug/L 98 50-127 0 19 Styrene 20.0 19.2 ug/L 96 73-120 6 23 Tetrachloroethene 20.0 18.9 ug/L 94 40-181 6 26 Tetrahydrofuran 20.0 20.0 ug/L 100 0-200 4 50 Toluene 20.0 18.5 ug/L 92 71-120 5 17 trans-1,2-Dichloroethene 20.0 22.5 ug/L 112 75-139 9 19 trans-1,3-Dichloropropene 20.0 20.7 ug/L 103 65-152 5 16 trans-1,4-Dichloro-2-butene 20.0 21.1 ug/L 105 10-142 2 28 Trichloroethene 20.0 19.9 ug/L 99 74-120 8 22 Trichlorofluoromethane 20.0 22.3 ug/L 111 68-183 11 22 Vinyl acetate 20.0 29.6 ug/L 148 10-198 4 21 Vinyl chloride 20.0 19.0 ug/L 95 49-150 8 27 Eurofins Raleigh Page 72 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-8754/5 Matrix: Water Prep Type: Total/NA Analysis Batch: 8754 Xylenes, Total 60.0 59.4 ug/L 99 77-121 6 16 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD 4-Bromofluorobenzene (Surr)53 -136 Surrogate 84 LCSD LCSD Qualifier Limits%Recovery 97Dibromofluoromethane (Surr)67 -129 95Toluene-d8 (Surr)59 -134 Client Sample ID: Lab Control SampleLab Sample ID: MRL 752-8754/3 Matrix: Water Prep Type: Total/NA Analysis Batch: 8754 1,1,1,2-Tetrachloroethane 1.00 1.13 ug/L 113 Analyte MRL MRL DUnitResultQualifier %Rec Spike Added %Rec Limits 1,1,1-Trichloroethane 1.00 1.55 ug/L 155 1,1,2,2-Tetrachloroethane 1.00 1.23 ug/L 123 1,1,2-Trichloroethane 1.00 1.39 ug/L 139 1,1-Dichloroethane 1.00 1.65 ug/L 165 1,1-Dichloroethene 1.00 1.73 ug/L 173 1,1-Dichloropropene 1.00 1.60 ug/L 160 1,2,3-Trichloropropane 1.00 1.27 ug/L 127 1,2,4-Trichlorobenzene 1.00 1.56 ug/L 156 1,2-Dibromo-3-Chloropropane 1.00 1.11 ug/L 111 1,2-Dibromoethane 1.00 1.25 ug/L 125 1,2-Dichlorobenzene 1.00 1.47 ug/L 147 1,2-Dichloroethane 1.00 1.36 ug/L 136 1,2-Dichloropropane 1.00 1.38 ug/L 138 1,3-Dichlorobenzene 1.00 1.55 ug/L 155 1,3-Dichloropropane 1.00 1.25 ug/L 125 1,4-Dichlorobenzene 1.00 1.69 ug/L 169 2,2-Dichloropropane 1.00 1.66 ug/L 166 2-Butanone (MEK)2.00 <10 ug/L 297 2-Hexanone 2.00 1.98 J ug/L 99 3-Chloropropene 1.00 1.49 ug/L 149 4-Methyl-2-pentanone (MIBK)2.00 2.14 J ug/L 107 Acetone 2.00 <10 ug/L 85 Acetonitrile 10.0 16.4 ug/L 164 Acrolein 5.00 9.34 J ug/L 187 Acrylonitrile 5.00 7.15 J ug/L 143 Benzene 1.00 1.44 ug/L 144 Bromochloromethane 1.00 1.39 ug/L 139 Bromodichloromethane 1.00 1.37 ug/L 137 Bromoform 1.00 1.16 ug/L 116 Bromomethane 1.00 1.37 ug/L 137 Carbon disulfide 2.00 3.61 J ug/L 181 Carbon tetrachloride 1.00 1.39 ug/L 139 Chlorobenzene 1.00 1.43 ug/L 143 Chloroethane 1.00 1.29 ug/L 129 Chloroform 1.00 1.68 ug/L 168 Eurofins Raleigh Page 73 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Lab Control SampleLab Sample ID: MRL 752-8754/3 Matrix: Water Prep Type: Total/NA Analysis Batch: 8754 Chloromethane 1.00 0.843 J ug/L 84 Analyte MRL MRL DUnitResultQualifier %Rec Spike Added %Rec Limits Chloroprene 1.00 1.36 ug/L 136 cis-1,2-Dichloroethene 1.00 1.73 ug/L 173 cis-1,3-Dichloropropene 1.00 1.29 ug/L 129 Dibromochloromethane 1.00 1.19 ug/L 119 Dibromomethane 1.00 1.40 ug/L 140 Dichlorodifluoromethane 1.00 1.56 ug/L 156 Ethyl methacrylate 1.00 1.02 ug/L 102 Ethylbenzene 1.00 1.38 ug/L 138 Hexachlorobutadiene 1.00 1.92 ug/L 192 Iodomethane 2.00 2.08 J ug/L 104 Isobutyl alcohol 20.0 28.7 J ug/L 143 Methacrylonitrile 10.0 13.1 ug/L 131 Methyl methacrylate 1.00 1.23 ug/L 123 Methylene Chloride 1.00 0.387 J ug/L 39 Naphthalene 1.00 1.19 ug/L 119 Styrene 1.00 1.07 ug/L 107 Tetrachloroethene 1.00 1.46 ug/L 146 Tetrahydrofuran 1.00 1.62 ug/L 162 Toluene 1.00 1.50 ug/L 150 trans-1,2-Dichloroethene 1.00 1.87 ug/L 187 trans-1,3-Dichloropropene 1.00 1.22 ug/L 122 trans-1,4-Dichloro-2-butene 1.00 1.46 ug/L 146 Trichloroethene 1.00 1.41 ug/L 141 Trichlorofluoromethane 1.00 1.22 ug/L 122 Vinyl acetate 2.00 2.57 J ug/L 128 Vinyl chloride 1.00 1.04 ug/L 104 Xylenes, Total 3.00 3.83 ug/L 128 4-Bromofluorobenzene (Surr)53 -136 Surrogate 82 MRL MRL Qualifier Limits%Recovery 101Dibromofluoromethane (Surr)67 -129 93Toluene-d8 (Surr)59 -134 Method: 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Client Sample ID: Method BlankLab Sample ID: MB 680-854693/5 Matrix: Water Prep Type: Total/NA Analysis Batch: 854693 RL MDL 1,4-Dioxane <0.32 0.50 0.32 ug/L 09/06/24 09:50 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier 4-Bromofluorobenzene (Surr)80 46-154 09/06/24 09:50 1 MB MB Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery Eurofins Raleigh Page 74 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 8260D SIM 14D - Volatile Organic Compounds (GC/MS) (Continued) Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-854693/3 Matrix: Water Prep Type: Total/NA Analysis Batch: 854693 1,4-Dioxane 5.00 4.76 ug/L 95 70-130 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits 4-Bromofluorobenzene (Surr)46 -154 Surrogate 99 LCS LCS Qualifier Limits%Recovery Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 680-854693/4 Matrix: Water Prep Type: Total/NA Analysis Batch: 854693 1,4-Dioxane 5.00 5.04 ug/L 101 70-130 6 30 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD 4-Bromofluorobenzene (Surr)46 -154 Surrogate 92 LCSD LCSD Qualifier Limits%Recovery Client Sample ID: Method BlankLab Sample ID: MB 680-854841/6 Matrix: Water Prep Type: Total/NA Analysis Batch: 854841 RL MDL 1,4-Dioxane <0.32 0.50 0.32 ug/L 09/07/24 11:07 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier 4-Bromofluorobenzene (Surr)81 46-154 09/07/24 11:07 1 MB MB Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-854841/3 Matrix: Water Prep Type: Total/NA Analysis Batch: 854841 1,4-Dioxane 5.00 4.57 ug/L 91 70-130 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits 4-Bromofluorobenzene (Surr)46 -154 Surrogate 100 LCS LCS Qualifier Limits%Recovery Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 680-854841/4 Matrix: Water Prep Type: Total/NA Analysis Batch: 854841 1,4-Dioxane 5.00 5.57 ug/L 111 70-130 20 30 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD 4-Bromofluorobenzene (Surr)46 -154 Surrogate 91 LCSD LCSD Qualifier Limits%Recovery Eurofins Raleigh Page 75 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 300.0-1993 R2.1 - Anions, Ion Chromatography Client Sample ID: Method BlankLab Sample ID: MB 680-855345/2 Matrix: Water Prep Type: Total/NA Analysis Batch: 855345 RL MDL Chloride <0.20 0.50 0.20 mg/L 09/11/24 11:15 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier <0.40 0.401.0 mg/L 09/11/24 11:15 1Sulfate Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-855345/3 Matrix: Water Prep Type: Total/NA Analysis Batch: 855345 Chloride 10.0 9.66 mg/L 97 90-110 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Sulfate 10.0 9.47 mg/L 95 90-110 Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 680-855345/4 Matrix: Water Prep Type: Total/NA Analysis Batch: 855345 Chloride 10.0 9.63 mg/L 96 90-110 0 15 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Sulfate 10.0 9.38 mg/L 94 90-110 1 15 Client Sample ID: Method BlankLab Sample ID: ICB 680-855859/10 MB Matrix: Water Prep Type: Total/NA Analysis Batch: 855859 RL MDL Chloride <0.20 0.50 0.20 mg/L 09/13/24 17:00 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier <0.40 0.401.0 mg/L 09/13/24 17:00 1Sulfate Client Sample ID: Method BlankLab Sample ID: MB 680-855904/54 Matrix: Water Prep Type: Total/NA Analysis Batch: 855904 RL MDL Chloride <0.20 0.50 0.20 mg/L 09/14/24 17:12 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier <0.40 0.401.0 mg/L 09/14/24 17:12 1Sulfate Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-855904/55 Matrix: Water Prep Type: Total/NA Analysis Batch: 855904 Chloride 10.0 10.1 mg/L 101 90-110 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Sulfate 10.0 9.61 mg/L 96 90-110 Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 680-855904/56 Matrix: Water Prep Type: Total/NA Analysis Batch: 855904 Chloride 10.0 10.1 mg/L 101 90-110 0 15 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Sulfate 10.0 9.59 mg/L 96 90-110 0 15 Eurofins Raleigh Page 76 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 300.0-1993 R2.1 - Anions, Ion Chromatography Client Sample ID: Method BlankLab Sample ID: MB 680-855951/84 Matrix: Water Prep Type: Total/NA Analysis Batch: 855951 RL MDL Chloride <0.20 0.50 0.20 mg/L 09/14/24 21:03 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier <0.40 0.401.0 mg/L 09/14/24 21:03 1Sulfate Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-855951/85 Matrix: Water Prep Type: Total/NA Analysis Batch: 855951 Chloride 10.0 10.1 mg/L 101 90-110 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Sulfate 10.0 9.43 mg/L 94 90-110 Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 680-855951/86 Matrix: Water Prep Type: Total/NA Analysis Batch: 855951 Chloride 10.0 10.2 mg/L 102 90-110 0 15 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Sulfate 10.0 9.63 mg/L 96 90-110 2 15 Client Sample ID: SW-3Lab Sample ID: 752-23805-5 MS Matrix: Surface Water Prep Type: Total/NA Analysis Batch: 855951 Chloride 12 10.0 20.6 mg/L 91 80-120 Analyte MS MS DUnitResultQualifier %Rec Spike Added Sample Result Sample Qualifier %Rec Limits Sulfate 8.5 10.0 18.6 mg/L 101 80-120 Client Sample ID: SW-3Lab Sample ID: 752-23805-5 MSD Matrix: Surface Water Prep Type: Total/NA Analysis Batch: 855951 Chloride 12 10.0 20.6 mg/L 91 80-120 0 15 Analyte MSD MSD DUnitResultQualifier %Rec Spike Added Sample Result Sample Qualifier %Rec Limits LimitRPD RPD Sulfate 8.5 10.0 18.6 mg/L 101 80-120 0 15 Client Sample ID: Method BlankLab Sample ID: MB 680-856213/8 Matrix: Water Prep Type: Total/NA Analysis Batch: 856213 RL MDL Chloride <0.20 0.50 0.20 mg/L 09/16/24 21:35 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier <0.40 0.401.0 mg/L 09/16/24 21:35 1Sulfate Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-856213/9 Matrix: Water Prep Type: Total/NA Analysis Batch: 856213 Chloride 10.0 10.5 mg/L 105 90-110 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Sulfate 10.0 10.3 mg/L 103 90-110 Eurofins Raleigh Page 77 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 300.0-1993 R2.1 - Anions, Ion Chromatography Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 680-856213/10 Matrix: Water Prep Type: Total/NA Analysis Batch: 856213 Chloride 10.0 10.0 mg/L 100 90-110 4 15 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Sulfate 10.0 9.82 mg/L 98 90-110 4 15 Method: 2340B-2011 - Total Hardness (as CaCO3) by calculation Client Sample ID: Method BlankLab Sample ID: MB 680-855350/1 Matrix: Water Prep Type: Total/NA Analysis Batch: 855350 RL MDL Hardness as calcium carbonate <3.3 3.3 3.3 mg/L 09/11/24 11:32 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Method BlankLab Sample ID: MB 680-856248/1 Matrix: Water Prep Type: Total/NA Analysis Batch: 856248 RL MDL Hardness as calcium carbonate <3.3 3.3 3.3 mg/L 09/17/24 12:06 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Method: 6010D - Metals (ICP) Client Sample ID: Method BlankLab Sample ID: MB 680-854685/1-A Matrix: Water Prep Type: Total Recoverable Analysis Batch: 854907 Prep Batch: 854685 RL MDL Arsenic <6.4 20 6.4 ug/L 09/06/24 06:29 09/06/24 12:10 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier <4.4 4.410 ug/L 09/06/24 06:29 09/06/24 12:10 1Barium <0.30 0.304.0 ug/L 09/06/24 06:29 09/06/24 12:10 1Beryllium <0.44 0.445.0 ug/L 09/06/24 06:29 09/06/24 12:10 1Cadmium 1.43 J 1.110 ug/L 09/06/24 06:29 09/06/24 12:10 1Chromium <1.4 1.410 ug/L 09/06/24 06:29 09/06/24 12:10 1Cobalt <3.2 3.220 ug/L 09/06/24 06:29 09/06/24 12:10 1Copper <20 20100 ug/L 09/06/24 06:29 09/06/24 12:10 1Fe <6.6 6.610 ug/L 09/06/24 06:29 09/06/24 12:10 1Lead <1.3 1.310 ug/L 09/06/24 06:29 09/06/24 12:10 1Manganese <3.3 3.340 ug/L 09/06/24 06:29 09/06/24 12:10 1Nickel <67 671000 ug/L 09/06/24 06:29 09/06/24 12:10 1Potassium <1.5 1.510 ug/L 09/06/24 06:29 09/06/24 12:10 1Silver <11 1150 ug/L 09/06/24 06:29 09/06/24 12:10 1Tin <1.0 1.010 ug/L 09/06/24 06:29 09/06/24 12:10 1Vanadium <8.7 8.720 ug/L 09/06/24 06:29 09/06/24 12:10 1Zinc Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-854685/2-A Matrix: Water Prep Type: Total Recoverable Analysis Batch: 854907 Prep Batch: 854685 Arsenic 100 98.2 ug/L 98 80-120 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Barium 100 104 ug/L 104 80-120 Eurofins Raleigh Page 78 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 6010D - Metals (ICP) (Continued) Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-854685/2-A Matrix: Water Prep Type: Total Recoverable Analysis Batch: 854907 Prep Batch: 854685 Beryllium 50.0 51.4 ug/L 103 80-120 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Cadmium 50.0 51.3 ug/L 103 80-120 Chromium 100 104 ug/L 104 80-120 Cobalt 50.0 51.9 ug/L 104 80-120 Copper 101 101 ug/L 100 80-120 Fe 5000 4970 ug/L 99 80-120 Lead 500 532 ug/L 106 80-120 Manganese 400 408 ug/L 102 80-120 Nickel 100 103 ug/L 103 80-120 Potassium 7000 6930 ug/L 99 80-120 Silver 50.0 48.6 ug/L 97 80-120 Tin 100 101 ug/L 101 80-120 Vanadium 100 102 ug/L 102 80-120 Zinc 100 97.1 ug/L 97 80-120 Client Sample ID: Method BlankLab Sample ID: MB 680-854930/1-A Matrix: Water Prep Type: Total Recoverable Analysis Batch: 855104 Prep Batch: 854930 RL MDL Arsenic <6.4 20 6.4 ug/L 09/09/24 05:44 09/09/24 21:06 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier <4.4 4.410 ug/L 09/09/24 05:44 09/09/24 21:06 1Barium <0.30 0.304.0 ug/L 09/09/24 05:44 09/09/24 21:06 1Beryllium <0.44 0.445.0 ug/L 09/09/24 05:44 09/09/24 21:06 1Cadmium <1.1 1.110 ug/L 09/09/24 05:44 09/09/24 21:06 1Chromium <1.4 1.410 ug/L 09/09/24 05:44 09/09/24 21:06 1Cobalt <3.2 3.220 ug/L 09/09/24 05:44 09/09/24 21:06 1Copper <20 20100 ug/L 09/09/24 05:44 09/09/24 21:06 1Fe <6.6 6.610 ug/L 09/09/24 05:44 09/09/24 21:06 1Lead <1.3 1.310 ug/L 09/09/24 05:44 09/09/24 21:06 1Manganese <3.3 3.340 ug/L 09/09/24 05:44 09/09/24 21:06 1Nickel 81.5 J 671000 ug/L 09/09/24 05:44 09/09/24 21:06 1Potassium <1.5 1.510 ug/L 09/09/24 05:44 09/09/24 21:06 1Silver <11 1150 ug/L 09/09/24 05:44 09/09/24 21:06 1Tin <1.0 1.010 ug/L 09/09/24 05:44 09/09/24 21:06 1Vanadium <8.7 8.720 ug/L 09/09/24 05:44 09/09/24 21:06 1Zinc Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-854930/2-A Matrix: Water Prep Type: Total Recoverable Analysis Batch: 855104 Prep Batch: 854930 Arsenic 100 98.2 ug/L 98 80-120 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Barium 100 104 ug/L 104 80-120 Beryllium 50.0 50.9 ug/L 102 80-120 Cadmium 50.0 51.6 ug/L 103 80-120 Chromium 100 104 ug/L 104 80-120 Cobalt 50.0 51.7 ug/L 103 80-120 Copper 101 100 ug/L 99 80-120 Eurofins Raleigh Page 79 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 6010D - Metals (ICP) (Continued) Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-854930/2-A Matrix: Water Prep Type: Total Recoverable Analysis Batch: 855104 Prep Batch: 854930 Fe 5000 4990 ug/L 100 80-120 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Lead 500 521 ug/L 104 80-120 Manganese 400 408 ug/L 102 80-120 Nickel 100 102 ug/L 102 80-120 Potassium 7000 7360 ug/L 105 80-120 Silver 50.0 50.5 ug/L 101 80-120 Tin 100 99.5 ug/L 100 80-120 Vanadium 100 101 ug/L 101 80-120 Zinc 100 97.4 ug/L 97 80-120 Client Sample ID: SW-3Lab Sample ID: 752-23805-5 MS Matrix: Surface Water Prep Type: Total Recoverable Analysis Batch: 855104 Prep Batch: 854930 Arsenic <6.4 100 102 ug/L 102 75-125 Analyte MS MS DUnitResultQualifier %Rec Spike Added Sample Result Sample Qualifier %Rec Limits Barium 35 100 137 ug/L 102 75-125 Beryllium <0.30 50.0 51.7 ug/L 103 75-125 Cadmium <0.44 50.0 51.9 ug/L 104 75-125 Chromium <1.1 100 105 ug/L 105 75-125 Cobalt <1.4 50.0 52.1 ug/L 104 75-125 Copper <3.2 101 107 ug/L 106 75-125 Fe 560 5000 5550 ug/L 100 75-125 Lead <6.6 500 523 ug/L 105 75-125 Manganese 91 400 492 ug/L 100 75-125 Nickel <3.3 100 104 ug/L 104 75-125 Potassium 10000 B 7000 16400 ug/L 91 75-125 Silver <1.5 50.0 51.2 ug/L 102 75-125 Tin <11 100 102 ug/L 102 75-125 Vanadium 2.6 J 100 103 ug/L 101 75-125 Zinc <8.7 100 98.6 ug/L 99 75-125 Client Sample ID: SW-3Lab Sample ID: 752-23805-5 MSD Matrix: Surface Water Prep Type: Total Recoverable Analysis Batch: 855104 Prep Batch: 854930 Arsenic <6.4 100 99.5 ug/L 100 75-125 2 20 Analyte MSD MSD DUnitResultQualifier %Rec Spike Added Sample Result Sample Qualifier %Rec Limits LimitRPD RPD Barium 35 100 138 ug/L 103 75-125 1 20 Beryllium <0.30 50.0 51.9 ug/L 104 75-125 0 20 Cadmium <0.44 50.0 51.9 ug/L 104 75-125 0 20 Chromium <1.1 100 105 ug/L 105 75-125 0 20 Cobalt <1.4 50.0 51.9 ug/L 104 75-125 1 20 Copper <3.2 101 106 ug/L 105 75-125 1 20 Fe 560 5000 5530 ug/L 99 75-125 0 20 Lead <6.6 500 526 ug/L 105 75-125 0 20 Manganese 91 400 492 ug/L 100 75-125 0 20 Nickel <3.3 100 104 ug/L 104 75-125 1 20 Potassium 10000 B 7000 16600 ug/L 95 75-125 2 20 Eurofins Raleigh Page 80 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 6010D - Metals (ICP) (Continued) Client Sample ID: SW-3Lab Sample ID: 752-23805-5 MSD Matrix: Surface Water Prep Type: Total Recoverable Analysis Batch: 855104 Prep Batch: 854930 Silver <1.5 50.0 51.6 ug/L 103 75-125 1 20 Analyte MSD MSD DUnitResultQualifier %Rec Spike Added Sample Result Sample Qualifier %Rec Limits LimitRPD RPD Tin <11 100 101 ug/L 101 75-125 0 20 Vanadium 2.6 J 100 103 ug/L 101 75-125 0 20 Zinc <8.7 100 99.7 ug/L 100 75-125 1 20 Method: 6020B - Metals (ICP/MS) Client Sample ID: Method BlankLab Sample ID: MB 680-854686/1-A Matrix: Water Prep Type: Total Recoverable Analysis Batch: 855105 Prep Batch: 854686 RL MDL Antimony <0.34 5.0 0.34 ug/L 09/06/24 06:29 09/09/24 17:33 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier <0.99 0.992.5 ug/L 09/06/24 06:29 09/09/24 17:33 1Selenium <0.26 0.261.0 ug/L 09/06/24 06:29 09/09/24 17:33 1Thallium Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-854686/2-A Matrix: Water Prep Type: Total Recoverable Analysis Batch: 855105 Prep Batch: 854686 Antimony 50.0 52.3 ug/L 105 80-120 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Selenium 100 110 ug/L 110 80-120 Thallium 50.0 53.0 ug/L 106 80-120 Client Sample ID: Method BlankLab Sample ID: MB 680-854931/1-A Matrix: Water Prep Type: Total Recoverable Analysis Batch: 855105 Prep Batch: 854931 RL MDL Antimony <0.34 5.0 0.34 ug/L 09/09/24 05:44 09/09/24 23:08 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier <0.99 0.992.5 ug/L 09/09/24 05:44 09/09/24 23:08 1Selenium <0.26 0.261.0 ug/L 09/09/24 05:44 09/09/24 23:08 1Thallium Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-854931/2-A Matrix: Water Prep Type: Total Recoverable Analysis Batch: 855105 Prep Batch: 854931 Antimony 50.0 54.1 ug/L 108 80-120 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Selenium 100 120 ug/L 120 80-120 Thallium 50.0 55.0 ug/L 110 80-120 Client Sample ID: SW-3Lab Sample ID: 752-23805-5 MS Matrix: Surface Water Prep Type: Total Recoverable Analysis Batch: 855105 Prep Batch: 854931 Antimony <0.34 50.0 53.1 ug/L 106 75-125 Analyte MS MS DUnitResultQualifier %Rec Spike Added Sample Result Sample Qualifier %Rec Limits Selenium <0.99 100 113 ug/L 113 75-125 Eurofins Raleigh Page 81 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 6020B - Metals (ICP/MS) (Continued) Client Sample ID: SW-3Lab Sample ID: 752-23805-5 MS Matrix: Surface Water Prep Type: Total Recoverable Analysis Batch: 855105 Prep Batch: 854931 Thallium <0.26 50.0 53.9 ug/L 108 75-125 Analyte MS MS DUnitResultQualifier %Rec Spike Added Sample Result Sample Qualifier %Rec Limits Client Sample ID: SW-3Lab Sample ID: 752-23805-5 MSD Matrix: Surface Water Prep Type: Total Recoverable Analysis Batch: 855105 Prep Batch: 854931 Antimony <0.34 50.0 52.2 ug/L 104 75-125 2 20 Analyte MSD MSD DUnitResultQualifier %Rec Spike Added Sample Result Sample Qualifier %Rec Limits LimitRPD RPD Selenium <0.99 100 112 ug/L 112 75-125 1 20 Thallium <0.26 50.0 54.1 ug/L 108 75-125 0 20 Method: 7470A - Mercury (CVAA) Client Sample ID: Method BlankLab Sample ID: MB 680-854797/1-A Matrix: Water Prep Type: Total/NA Analysis Batch: 854916 Prep Batch: 854797 RL MDL Mercury <0.080 0.20 0.080 ug/L 09/06/24 13:21 09/08/24 12:29 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-854797/2-A Matrix: Water Prep Type: Total/NA Analysis Batch: 854916 Prep Batch: 854797 Mercury 2.50 2.16 ug/L 86 80-120 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Client Sample ID: Method BlankLab Sample ID: MB 680-855068/1-A Matrix: Water Prep Type: Total/NA Analysis Batch: 855210 Prep Batch: 855068 RL MDL Mercury <0.080 0.20 0.080 ug/L 09/09/24 15:09 09/10/24 10:25 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-855068/2-A Matrix: Water Prep Type: Total/NA Analysis Batch: 855210 Prep Batch: 855068 Mercury 2.50 2.60 ug/L 104 80-120 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Client Sample ID: Method BlankLab Sample ID: MB 680-855144/1-A Matrix: Water Prep Type: Total/NA Analysis Batch: 855253 Prep Batch: 855144 RL MDL Mercury <0.080 0.20 0.080 ug/L 09/10/24 10:23 09/10/24 15:11 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Eurofins Raleigh Page 82 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 7470A - Mercury (CVAA) (Continued) Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-855144/2-A Matrix: Water Prep Type: Total/NA Analysis Batch: 855253 Prep Batch: 855144 Mercury 2.50 2.53 ug/L 101 80-120 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Method: 2320B-2011 - Alkalinity, Total Client Sample ID: Method BlankLab Sample ID: MB 680-854832/4 Matrix: Water Prep Type: Total/NA Analysis Batch: 854832 RL MDL Alkalinity as CaCO3 to pH 4.5 <2.2 5.5 2.2 mg/L 09/06/24 12:10 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-854832/6 Matrix: Water Prep Type: Total/NA Analysis Batch: 854832 Alkalinity as CaCO3 to pH 4.5 250 246 mg/L 98 90-112 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 680-854832/30 Matrix: Water Prep Type: Total/NA Analysis Batch: 854832 Alkalinity as CaCO3 to pH 4.5 250 248 mg/L 99 90-112 1 30 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Client Sample ID: Method BlankLab Sample ID: MB 680-855260/4 Matrix: Water Prep Type: Total/NA Analysis Batch: 855260 RL MDL Alkalinity as CaCO3 to pH 4.5 <2.2 5.5 2.2 mg/L 09/10/24 13:22 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-855260/6 Matrix: Water Prep Type: Total/NA Analysis Batch: 855260 Alkalinity as CaCO3 to pH 4.5 250 243 mg/L 97 90-112 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 680-855260/31 Matrix: Water Prep Type: Total/NA Analysis Batch: 855260 Alkalinity as CaCO3 to pH 4.5 250 249 mg/L 100 90-112 2 30 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Eurofins Raleigh Page 83 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 2320B-2011 - Alkalinity, Total (Continued) Client Sample ID: Method BlankLab Sample ID: MB 680-855666/4 Matrix: Water Prep Type: Total/NA Analysis Batch: 855666 RL MDL Alkalinity as CaCO3 to pH 4.5 <2.2 5.5 2.2 mg/L 09/12/24 12:28 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-855666/6 Matrix: Water Prep Type: Total/NA Analysis Batch: 855666 Alkalinity as CaCO3 to pH 4.5 250 245 mg/L 98 90-112 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 680-855666/31 Matrix: Water Prep Type: Total/NA Analysis Batch: 855666 Alkalinity as CaCO3 to pH 4.5 250 249 mg/L 100 90-112 2 30 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Client Sample ID: Method BlankLab Sample ID: MB 680-856089/4 Matrix: Water Prep Type: Total/NA Analysis Batch: 856089 RL MDL Alkalinity as CaCO3 to pH 4.5 <2.2 5.5 2.2 mg/L 09/13/24 18:49 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-856089/6 Matrix: Water Prep Type: Total/NA Analysis Batch: 856089 Alkalinity as CaCO3 to pH 4.5 250 246 mg/L 98 90-112 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 680-856089/31 Matrix: Water Prep Type: Total/NA Analysis Batch: 856089 Alkalinity as CaCO3 to pH 4.5 250 249 mg/L 100 90-112 1 30 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Method: 4500 S2 F-2011 - Sulfide, Total Client Sample ID: Method BlankLab Sample ID: MB 680-854807/1 Matrix: Water Prep Type: Total/NA Analysis Batch: 854807 RL MDL Sulfide <1.0 1.0 1.0 mg/L 09/06/24 14:15 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Eurofins Raleigh Page 84 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 4500 S2 F-2011 - Sulfide, Total (Continued) Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-854807/2 Matrix: Water Prep Type: Total/NA Analysis Batch: 854807 Sulfide 10.0 9.89 mg/L 99 75-125 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 680-854807/3 Matrix: Water Prep Type: Total/NA Analysis Batch: 854807 Sulfide 10.0 9.33 mg/L 93 75-125 6 30 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Client Sample ID: Lab Control SampleLab Sample ID: LLCS 680-854807/4 Matrix: Water Prep Type: Total/NA Analysis Batch: 854807 Sulfide 1.00 <1.0 mg/L 91 50-150 Analyte LLCS LLCS DUnitResultQualifier %Rec Spike Added %Rec Limits Client Sample ID: Method BlankLab Sample ID: MB 680-855208/1 Matrix: Water Prep Type: Total/NA Analysis Batch: 855208 RL MDL Sulfide <1.0 1.0 1.0 mg/L 09/10/24 13:15 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-855208/2 Matrix: Water Prep Type: Total/NA Analysis Batch: 855208 Sulfide 10.0 9.14 mg/L 91 75-125 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 680-855208/3 Matrix: Water Prep Type: Total/NA Analysis Batch: 855208 Sulfide 10.0 9.06 mg/L 91 75-125 1 30 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Client Sample ID: Method BlankLab Sample ID: MB 680-855425/1 Matrix: Water Prep Type: Total/NA Analysis Batch: 855425 RL MDL Sulfide <1.0 1.0 1.0 mg/L 09/11/24 15:20 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-855425/2 Matrix: Water Prep Type: Total/NA Analysis Batch: 855425 Sulfide 10.0 9.20 mg/L 92 75-125 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Eurofins Raleigh Page 85 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: 4500 S2 F-2011 - Sulfide, Total Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 680-855425/3 Matrix: Water Prep Type: Total/NA Analysis Batch: 855425 Sulfide 10.0 9.01 mg/L 90 75-125 2 30 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Client Sample ID: MW-4Lab Sample ID: 752-23805-1 DU Matrix: GW Prep Type: Total/NA Analysis Batch: 855425 Sulfide <0.81 0.888 mg/L NC 30 Analyte DU DU DUnitResultQualifier Sample Result Sample Qualifier LimitRPD RPD Client Sample ID: Method BlankLab Sample ID: MB 680-855601/1 Matrix: Water Prep Type: Total/NA Analysis Batch: 855601 RL MDL Sulfide <1.0 1.0 1.0 mg/L 09/12/24 14:23 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-855601/2 Matrix: Water Prep Type: Total/NA Analysis Batch: 855601 Sulfide 10.0 9.23 mg/L 92 75-125 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 680-855601/3 Matrix: Water Prep Type: Total/NA Analysis Batch: 855601 Sulfide 10.0 9.62 mg/L 96 75-125 4 30 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Method: SM 2540C - Solids, Total Dissolved (TDS) Client Sample ID: Method BlankLab Sample ID: MB 752-8639/1 Matrix: Water Prep Type: Total/NA Analysis Batch: 8639 RL MDL Total Dissolved Solids <50 50 50 mg/L 09/06/24 16:28 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-8639/2 Matrix: Water Prep Type: Total/NA Analysis Batch: 8639 Total Dissolved Solids 1000 1000 mg/L 100 90-110 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Eurofins Raleigh Page 86 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: SM 2540C - Solids, Total Dissolved (TDS) (Continued) Client Sample ID: Method BlankLab Sample ID: MB 752-8734/1 Matrix: Water Prep Type: Total/NA Analysis Batch: 8734 RL MDL Total Dissolved Solids <50 50 50 mg/L 09/12/24 14:14 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-8734/2 Matrix: Water Prep Type: Total/NA Analysis Batch: 8734 Total Dissolved Solids 1000 964 mg/L 96 90-110 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Client Sample ID: MW-17Lab Sample ID: 752-23869-1 DU Matrix: Water Prep Type: Total/NA Analysis Batch: 8734 Total Dissolved Solids 180 170 mg/L 3 10 Analyte DU DU DUnitResultQualifier Sample Result Sample Qualifier LimitRPD RPD Method: SM 3500 FE D - Iron, Ferrous Client Sample ID: Method BlankLab Sample ID: MB 680-855136/12 Matrix: Water Prep Type: Total/NA Analysis Batch: 855136 RL MDL Ferrous Iron <0.025 0.10 0.025 mg/L 09/07/24 10:38 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-855136/11 Matrix: Water Prep Type: Total/NA Analysis Batch: 855136 Ferrous Iron 2.00 1.84 mg/L 92 80-120 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Client Sample ID: MW-10ALab Sample ID: 752-23805-2 MS Matrix: GW Prep Type: Total/NA Analysis Batch: 855136 Ferrous Iron <0.025 HF 2.00 1.99 mg/L 99 80-120 Analyte MS MS DUnitResultQualifier %Rec Spike Added Sample Result Sample Qualifier %Rec Limits Client Sample ID: MW-10ALab Sample ID: 752-23805-2 MSD Matrix: GW Prep Type: Total/NA Analysis Batch: 855136 Ferrous Iron <0.025 HF 2.00 1.99 mg/L 100 80-120 0 20 Analyte MSD MSD DUnitResultQualifier %Rec Spike Added Sample Result Sample Qualifier %Rec Limits LimitRPD RPD Eurofins Raleigh Page 87 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: SM 3500 FE D - Iron, Ferrous (Continued) Client Sample ID: Method BlankLab Sample ID: MB 680-856727/22 Matrix: Water Prep Type: Total/NA Analysis Batch: 856727 RL MDL Ferrous Iron <0.025 0.10 0.025 mg/L 09/19/24 13:34 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-856727/21 Matrix: Water Prep Type: Total/NA Analysis Batch: 856727 Ferrous Iron 2.00 1.81 mg/L 91 80-120 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Client Sample ID: MW-17Lab Sample ID: 752-23869-1 MS Matrix: Water Prep Type: Total/NA Analysis Batch: 856727 Ferrous Iron <0.025 HF 2.00 1.88 mg/L 94 80-120 Analyte MS MS DUnitResultQualifier %Rec Spike Added Sample Result Sample Qualifier %Rec Limits Client Sample ID: MW-17Lab Sample ID: 752-23869-1 MSD Matrix: Water Prep Type: Total/NA Analysis Batch: 856727 Ferrous Iron <0.025 HF 2.00 1.98 mg/L 99 80-120 5 20 Analyte MSD MSD DUnitResultQualifier %Rec Spike Added Sample Result Sample Qualifier %Rec Limits LimitRPD RPD Method: SM 4500 NO3 F - Nitrogen, Nitrate Client Sample ID: Method BlankLab Sample ID: MB 752-8634/46 Matrix: Water Prep Type: Total/NA Analysis Batch: 8634 RL MDL Nitrate Nitrite as N <0.041 0.10 0.041 mg/L 09/05/24 12:53 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Method BlankLab Sample ID: MB 752-8634/71 Matrix: Water Prep Type: Total/NA Analysis Batch: 8634 RL MDL Nitrate Nitrite as N <0.041 0.10 0.041 mg/L 09/05/24 13:51 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-8634/47 Matrix: Water Prep Type: Total/NA Analysis Batch: 8634 Nitrate Nitrite as N 1.25 1.34 mg/L 107 90-110 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Eurofins Raleigh Page 88 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: SM 4500 NO3 F - Nitrogen, Nitrate (Continued) Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-8634/72 Matrix: Water Prep Type: Total/NA Analysis Batch: 8634 Nitrate Nitrite as N 1.25 1.31 mg/L 104 90-110 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-8634/98 Matrix: Water Prep Type: Total/NA Analysis Batch: 8634 Nitrate Nitrite as N 1.25 1.18 mg/L 95 90-110 10 10 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Client Sample ID: MW-19Lab Sample ID: 752-23756-1 MS Matrix: Water Prep Type: Total/NA Analysis Batch: 8634 Nitrate Nitrite as N 0.11 F1 0.521 0.567 F1 mg/L 88 90-110 Analyte MS MS DUnitResultQualifier %Rec Spike Added Sample Result Sample Qualifier %Rec Limits Client Sample ID: MW-19Lab Sample ID: 752-23756-1 MSD Matrix: Water Prep Type: Total/NA Analysis Batch: 8634 Nitrate Nitrite as N 0.11 F1 0.521 0.574 F1 mg/L 89 90-110 1 10 Analyte MSD MSD DUnitResultQualifier %Rec Spike Added Sample Result Sample Qualifier %Rec Limits LimitRPD RPD Client Sample ID: Method BlankLab Sample ID: MB 752-8687/46 Matrix: Water Prep Type: Total/NA Analysis Batch: 8687 RL MDL Nitrate Nitrite as N <0.041 0.10 0.041 mg/L 09/09/24 11:39 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Method BlankLab Sample ID: MB 752-8687/72 Matrix: Water Prep Type: Total/NA Analysis Batch: 8687 RL MDL Nitrate Nitrite as N <0.041 0.10 0.041 mg/L 09/09/24 13:19 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Method BlankLab Sample ID: MB 752-8687/8 Matrix: Water Prep Type: Total/NA Analysis Batch: 8687 RL MDL Nitrate Nitrite as N <0.041 0.10 0.041 mg/L 09/09/24 10:08 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-8687/47 Matrix: Water Prep Type: Total/NA Analysis Batch: 8687 Nitrate Nitrite as N 1.25 1.26 mg/L 100 90-110 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Eurofins Raleigh Page 89 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: SM 4500 NO3 F - Nitrogen, Nitrate Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-8687/73 Matrix: Water Prep Type: Total/NA Analysis Batch: 8687 Nitrate Nitrite as N 1.25 1.26 mg/L 101 90-110 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-8687/9 Matrix: Water Prep Type: Total/NA Analysis Batch: 8687 Nitrate Nitrite as N 1.25 1.23 mg/L 98 90-110 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-8687/86 Matrix: Water Prep Type: Total/NA Analysis Batch: 8687 Nitrate Nitrite as N 1.25 1.30 mg/L 104 90-110 3 10 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Method: SM4500 NO2 F - Nitrogen, Nitrite Client Sample ID: Method BlankLab Sample ID: MB 752-8630/18 Matrix: Water Prep Type: Total/NA Analysis Batch: 8630 RL MDL Nitrite as N <0.017 0.10 0.017 mg/L 09/04/24 15:26 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Method BlankLab Sample ID: MB 752-8630/8 Matrix: Water Prep Type: Total/NA Analysis Batch: 8630 RL MDL Nitrite as N <0.017 0.10 0.017 mg/L 09/04/24 15:16 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-8630/11 Matrix: Water Prep Type: Total/NA Analysis Batch: 8630 Nitrite as N 1.00 1.03 mg/L 103 90-110 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-8630/39 Matrix: Water Prep Type: Total/NA Analysis Batch: 8630 Nitrite as N 1.00 1.04 mg/L 104 90-110 1 10 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Eurofins Raleigh Page 90 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: SM4500 NO2 F - Nitrogen, Nitrite (Continued) Client Sample ID: Method BlankLab Sample ID: MB 752-8631/22 Matrix: Water Prep Type: Total/NA Analysis Batch: 8631 RL MDL Nitrite as N <0.017 0.10 0.017 mg/L 09/05/24 17:27 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Method BlankLab Sample ID: MB 752-8631/8 Matrix: Water Prep Type: Total/NA Analysis Batch: 8631 RL MDL Nitrite as N <0.017 0.10 0.017 mg/L 09/05/24 17:13 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-8631/11 Matrix: Water Prep Type: Total/NA Analysis Batch: 8631 Nitrite as N 1.00 0.965 mg/L 97 90-110 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-8631/47 Matrix: Water Prep Type: Total/NA Analysis Batch: 8631 Nitrite as N 1.00 1.01 mg/L 101 90-110 4 10 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Client Sample ID: Method BlankLab Sample ID: MB 752-8670/22 Matrix: Water Prep Type: Total/NA Analysis Batch: 8670 RL MDL Nitrite as N <0.017 0.10 0.017 mg/L 09/06/24 16:01 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Method BlankLab Sample ID: MB 752-8670/8 Matrix: Water Prep Type: Total/NA Analysis Batch: 8670 RL MDL Nitrite as N <0.017 0.10 0.017 mg/L 09/06/24 15:47 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-8670/11 Matrix: Water Prep Type: Total/NA Analysis Batch: 8670 Nitrite as N 1.00 0.973 mg/L 97 90-110 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-8670/36 Matrix: Water Prep Type: Total/NA Analysis Batch: 8670 Nitrite as N 1.00 0.986 mg/L 99 90-110 1 10 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Eurofins Raleigh Page 91 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method: SM4500 NO2 F - Nitrogen, Nitrite Client Sample ID: MW-17Lab Sample ID: 752-23869-1 MS Matrix: Water Prep Type: Total/NA Analysis Batch: 8670 Nitrite as N <0.017 F1 1.00 0.882 F1 mg/L 88 90-110 Analyte MS MS DUnitResultQualifier %Rec Spike Added Sample Result Sample Qualifier %Rec Limits Client Sample ID: MW-17Lab Sample ID: 752-23869-1 MSD Matrix: Water Prep Type: Total/NA Analysis Batch: 8670 Nitrite as N <0.017 F1 1.00 0.894 F1 mg/L 89 90-110 1 10 Analyte MSD MSD DUnitResultQualifier %Rec Spike Added Sample Result Sample Qualifier %Rec Limits LimitRPD RPD Eurofins Raleigh Page 92 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Association Summary Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill GC/MS VOA Analysis Batch: 8685 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 8260D752-23756-1 MW-19 Total/NA Water 8260DMB 752-8685/9 Method Blank Total/NA Water 8260DLCS 752-8685/5 Lab Control Sample Total/NA Water 8260DLCSD 752-8685/6 Lab Control Sample Dup Total/NA Water 8260DMRL 752-8685/4 Lab Control Sample Total/NA Analysis Batch: 8723 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch GW 8260D752-23805-1 MW-4 Total/NA GW 8260D752-23805-2 MW-10A Total/NA GW 8260D752-23805-3 MW-18 Total/NA Surface Water 8260D752-23805-4 SW-2 Total/NA Surface Water 8260D752-23805-5 SW-3 Total/NA GW 8260D752-23805-6 Equipment Blank Total/NA GW 8260D752-23805-7 MW-8 Total/NA GW 8260D752-23805-8 MW-15 Total/NA GW 8260D752-23805-9 MW-16 Total/NA Surface Water 8260D752-23805-10 SW-1 Total/NA Water 8260DMB 752-8723/8 Method Blank Total/NA Water 8260DLCS 752-8723/4 Lab Control Sample Total/NA Water 8260DLCSD 752-8723/5 Lab Control Sample Dup Total/NA Water 8260DMRL 752-8723/3 Lab Control Sample Total/NA Analysis Batch: 8744 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 8260D752-23869-1 MW-17 Total/NA Water 8260D752-23869-3 Trip Blank Total/NA Water 8260DMB 752-8744/8 Method Blank Total/NA Water 8260DLCS 752-8744/4 Lab Control Sample Total/NA Water 8260DLCSD 752-8744/5 Lab Control Sample Dup Total/NA Water 8260DMRL 752-8744/3 Lab Control Sample Total/NA Analysis Batch: 8754 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 8260D752-23869-1 - RA MW-17 Total/NA Water 8260DMB 752-8754/8 Method Blank Total/NA Water 8260DLCS 752-8754/4 Lab Control Sample Total/NA Water 8260DLCSD 752-8754/5 Lab Control Sample Dup Total/NA Water 8260DMRL 752-8754/3 Lab Control Sample Total/NA Analysis Batch: 854693 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 8260D SIM 14D752-23756-1 MW-19 Total/NA Water 8260D SIM 14DMB 680-854693/5 Method Blank Total/NA Water 8260D SIM 14DLCS 680-854693/3 Lab Control Sample Total/NA Water 8260D SIM 14DLCSD 680-854693/4 Lab Control Sample Dup Total/NA Analysis Batch: 854841 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch GW 8260D SIM 14D752-23805-1 MW-4 Total/NA GW 8260D SIM 14D752-23805-2 MW-10A Total/NA Eurofins Raleigh Page 93 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Association Summary Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill GC/MS VOA (Continued) Analysis Batch: 854841 (Continued) Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch GW 8260D SIM 14D752-23805-3 MW-18 Total/NA Surface Water 8260D SIM 14D752-23805-4 SW-2 Total/NA Surface Water 8260D SIM 14D752-23805-5 SW-3 Total/NA GW 8260D SIM 14D752-23805-6 Equipment Blank Total/NA GW 8260D SIM 14D752-23805-7 MW-8 Total/NA GW 8260D SIM 14D752-23805-8 MW-15 Total/NA GW 8260D SIM 14D752-23805-9 MW-16 Total/NA Surface Water 8260D SIM 14D752-23805-10 SW-1 Total/NA Water 8260D SIM 14D752-23869-1 MW-17 Total/NA Water 8260D SIM 14DMB 680-854841/6 Method Blank Total/NA Water 8260D SIM 14DLCS 680-854841/3 Lab Control Sample Total/NA Water 8260D SIM 14DLCSD 680-854841/4 Lab Control Sample Dup Total/NA HPLC/IC Analysis Batch: 855345 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 300.0-1993 R2.1752-23756-1 MW-19 Total/NA Water 300.0-1993 R2.1MB 680-855345/2 Method Blank Total/NA Water 300.0-1993 R2.1LCS 680-855345/3 Lab Control Sample Total/NA Water 300.0-1993 R2.1LCSD 680-855345/4 Lab Control Sample Dup Total/NA Analysis Batch: 855859 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 300.0-1993 R2.1ICB 680-855859/10 MB Method Blank Total/NA Analysis Batch: 855904 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch GW 300.0-1993 R2.1752-23805-1 MW-4 Total/NA GW 300.0-1993 R2.1752-23805-2 MW-10A Total/NA GW 300.0-1993 R2.1752-23805-3 MW-18 Total/NA Surface Water 300.0-1993 R2.1752-23805-4 SW-2 Total/NA Water 300.0-1993 R2.1MB 680-855904/54 Method Blank Total/NA Water 300.0-1993 R2.1LCS 680-855904/55 Lab Control Sample Total/NA Water 300.0-1993 R2.1LCSD 680-855904/56 Lab Control Sample Dup Total/NA Analysis Batch: 855951 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Surface Water 300.0-1993 R2.1752-23805-5 SW-3 Total/NA GW 300.0-1993 R2.1752-23805-6 Equipment Blank Total/NA GW 300.0-1993 R2.1752-23805-7 MW-8 Total/NA GW 300.0-1993 R2.1752-23805-8 MW-15 Total/NA GW 300.0-1993 R2.1752-23805-9 MW-16 Total/NA Surface Water 300.0-1993 R2.1752-23805-10 SW-1 Total/NA Water 300.0-1993 R2.1MB 680-855951/84 Method Blank Total/NA Water 300.0-1993 R2.1LCS 680-855951/85 Lab Control Sample Total/NA Water 300.0-1993 R2.1LCSD 680-855951/86 Lab Control Sample Dup Total/NA Surface Water 300.0-1993 R2.1752-23805-5 MS SW-3 Total/NA Surface Water 300.0-1993 R2.1752-23805-5 MSD SW-3 Total/NA Eurofins Raleigh Page 94 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Association Summary Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill HPLC/IC Analysis Batch: 856213 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 300.0-1993 R2.1752-23869-1 MW-17 Total/NA Water 300.0-1993 R2.1MB 680-856213/8 Method Blank Total/NA Water 300.0-1993 R2.1LCS 680-856213/9 Lab Control Sample Total/NA Water 300.0-1993 R2.1LCSD 680-856213/10 Lab Control Sample Dup Total/NA Metals Prep Batch: 854685 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 3005A752-23756-1 MW-19 Total Recoverable Water 3005AMB 680-854685/1-A Method Blank Total Recoverable Water 3005ALCS 680-854685/2-A Lab Control Sample Total Recoverable Prep Batch: 854686 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 3005A752-23756-1 MW-19 Total Recoverable Water 3005AMB 680-854686/1-A Method Blank Total Recoverable Water 3005ALCS 680-854686/2-A Lab Control Sample Total Recoverable Prep Batch: 854797 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 7470A752-23756-1 MW-19 Total/NA Water 7470AMB 680-854797/1-A Method Blank Total/NA Water 7470ALCS 680-854797/2-A Lab Control Sample Total/NA Analysis Batch: 854907 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 6010D 854685752-23756-1 MW-19 Total Recoverable Water 6010D 854685MB 680-854685/1-A Method Blank Total Recoverable Water 6010D 854685LCS 680-854685/2-A Lab Control Sample Total Recoverable Analysis Batch: 854916 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 7470A 854797752-23756-1 MW-19 Total/NA Water 7470A 854797MB 680-854797/1-A Method Blank Total/NA Water 7470A 854797LCS 680-854797/2-A Lab Control Sample Total/NA Prep Batch: 854930 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch GW 3005A752-23805-1 MW-4 Total Recoverable GW 3005A752-23805-2 MW-10A Total Recoverable GW 3005A752-23805-3 MW-18 Total Recoverable Surface Water 3005A752-23805-4 SW-2 Total Recoverable Surface Water 3005A752-23805-5 SW-3 Total Recoverable GW 3005A752-23805-6 Equipment Blank Total Recoverable GW 3005A752-23805-7 MW-8 Total Recoverable GW 3005A752-23805-8 MW-15 Total Recoverable GW 3005A752-23805-9 MW-16 Total Recoverable Surface Water 3005A752-23805-10 SW-1 Total Recoverable Water 3005A752-23869-1 MW-17 Total Recoverable Water 3005A752-23869-2 MW-1 Total Recoverable Eurofins Raleigh Page 95 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Association Summary Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Metals (Continued) Prep Batch: 854930 (Continued) Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 3005AMB 680-854930/1-A Method Blank Total Recoverable Water 3005ALCS 680-854930/2-A Lab Control Sample Total Recoverable Surface Water 3005A752-23805-5 MS SW-3 Total Recoverable Surface Water 3005A752-23805-5 MSD SW-3 Total Recoverable Prep Batch: 854931 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch GW 3005A752-23805-1 MW-4 Total Recoverable GW 3005A752-23805-2 MW-10A Total Recoverable GW 3005A752-23805-3 MW-18 Total Recoverable Surface Water 3005A752-23805-4 SW-2 Total Recoverable Surface Water 3005A752-23805-5 SW-3 Total Recoverable GW 3005A752-23805-6 Equipment Blank Total Recoverable GW 3005A752-23805-7 MW-8 Total Recoverable GW 3005A752-23805-8 MW-15 Total Recoverable GW 3005A752-23805-9 MW-16 Total Recoverable Surface Water 3005A752-23805-10 SW-1 Total Recoverable Water 3005A752-23869-1 MW-17 Total Recoverable Water 3005A752-23869-2 MW-1 Total Recoverable Water 3005AMB 680-854931/1-A Method Blank Total Recoverable Water 3005ALCS 680-854931/2-A Lab Control Sample Total Recoverable Surface Water 3005A752-23805-5 MS SW-3 Total Recoverable Surface Water 3005A752-23805-5 MSD SW-3 Total Recoverable Prep Batch: 855068 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch GW 7470A752-23805-1 MW-4 Total/NA GW 7470A752-23805-2 MW-10A Total/NA GW 7470A752-23805-3 MW-18 Total/NA Surface Water 7470A752-23805-4 SW-2 Total/NA Surface Water 7470A752-23805-5 SW-3 Total/NA GW 7470A752-23805-6 Equipment Blank Total/NA Water 7470AMB 680-855068/1-A Method Blank Total/NA Water 7470ALCS 680-855068/2-A Lab Control Sample Total/NA Analysis Batch: 855104 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch GW 6010D 854930752-23805-1 MW-4 Total Recoverable GW 6010D 854930752-23805-2 MW-10A Total Recoverable GW 6010D 854930752-23805-3 MW-18 Total Recoverable Surface Water 6010D 854930752-23805-4 SW-2 Total Recoverable Surface Water 6010D 854930752-23805-5 SW-3 Total Recoverable GW 6010D 854930752-23805-6 Equipment Blank Total Recoverable GW 6010D 854930752-23805-7 MW-8 Total Recoverable GW 6010D 854930752-23805-8 MW-15 Total Recoverable GW 6010D 854930752-23805-9 MW-16 Total Recoverable Surface Water 6010D 854930752-23805-10 SW-1 Total Recoverable Water 6010D 854930752-23869-1 MW-17 Total Recoverable Water 6010D 854930752-23869-2 MW-1 Total Recoverable Water 6010D 854930MB 680-854930/1-A Method Blank Total Recoverable Water 6010D 854930LCS 680-854930/2-A Lab Control Sample Total Recoverable Eurofins Raleigh Page 96 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Association Summary Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Metals (Continued) Analysis Batch: 855104 (Continued) Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Surface Water 6010D 854930752-23805-5 MS SW-3 Total Recoverable Surface Water 6010D 854930752-23805-5 MSD SW-3 Total Recoverable Analysis Batch: 855105 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 6020B 854686752-23756-1 MW-19 Total Recoverable GW 6020B 854931752-23805-1 MW-4 Total Recoverable GW 6020B 854931752-23805-2 MW-10A Total Recoverable GW 6020B 854931752-23805-3 MW-18 Total Recoverable Surface Water 6020B 854931752-23805-4 SW-2 Total Recoverable Surface Water 6020B 854931752-23805-5 SW-3 Total Recoverable GW 6020B 854931752-23805-6 Equipment Blank Total Recoverable GW 6020B 854931752-23805-7 MW-8 Total Recoverable GW 6020B 854931752-23805-8 MW-15 Total Recoverable GW 6020B 854931752-23805-9 MW-16 Total Recoverable Surface Water 6020B 854931752-23805-10 SW-1 Total Recoverable Water 6020B 854931752-23869-1 MW-17 Total Recoverable Water 6020B 854931752-23869-2 MW-1 Total Recoverable Water 6020B 854686MB 680-854686/1-A Method Blank Total Recoverable Water 6020B 854931MB 680-854931/1-A Method Blank Total Recoverable Water 6020B 854686LCS 680-854686/2-A Lab Control Sample Total Recoverable Water 6020B 854931LCS 680-854931/2-A Lab Control Sample Total Recoverable Surface Water 6020B 854931752-23805-5 MS SW-3 Total Recoverable Surface Water 6020B 854931752-23805-5 MSD SW-3 Total Recoverable Prep Batch: 855144 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch GW 7470A752-23805-7 MW-8 Total/NA GW 7470A752-23805-8 MW-15 Total/NA GW 7470A752-23805-9 MW-16 Total/NA Surface Water 7470A752-23805-10 SW-1 Total/NA Water 7470A752-23869-1 MW-17 Total/NA Water 7470A752-23869-2 MW-1 Total/NA Water 7470AMB 680-855144/1-A Method Blank Total/NA Water 7470ALCS 680-855144/2-A Lab Control Sample Total/NA Analysis Batch: 855210 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch GW 7470A 855068752-23805-1 MW-4 Total/NA GW 7470A 855068752-23805-2 MW-10A Total/NA GW 7470A 855068752-23805-3 MW-18 Total/NA Surface Water 7470A 855068752-23805-4 SW-2 Total/NA Surface Water 7470A 855068752-23805-5 SW-3 Total/NA GW 7470A 855068752-23805-6 Equipment Blank Total/NA Water 7470A 855068MB 680-855068/1-A Method Blank Total/NA Water 7470A 855068LCS 680-855068/2-A Lab Control Sample Total/NA Analysis Batch: 855253 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch GW 7470A 855144752-23805-7 MW-8 Total/NA GW 7470A 855144752-23805-8 MW-15 Total/NA Eurofins Raleigh Page 97 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Association Summary Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Metals (Continued) Analysis Batch: 855253 (Continued) Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch GW 7470A 855144752-23805-9 MW-16 Total/NA Surface Water 7470A 855144752-23805-10 SW-1 Total/NA Water 7470A 855144752-23869-1 MW-17 Total/NA Water 7470A 855144752-23869-2 MW-1 Total/NA Water 7470A 855144MB 680-855144/1-A Method Blank Total/NA Water 7470A 855144LCS 680-855144/2-A Lab Control Sample Total/NA Analysis Batch: 855350 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 2340B-2011752-23756-1 MW-19 Total/NA Water 2340B-2011MB 680-855350/1 Method Blank Total/NA Analysis Batch: 856248 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Surface Water 2340B-2011752-23805-4 SW-2 Total/NA Surface Water 2340B-2011752-23805-5 SW-3 Total/NA Surface Water 2340B-2011752-23805-10 SW-1 Total/NA Water 2340B-2011752-23869-1 MW-17 Total/NA Water 2340B-2011MB 680-856248/1 Method Blank Total/NA General Chemistry Analysis Batch: 8630 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water SM4500 NO2 F752-23756-1 MW-19 Total/NA Water SM4500 NO2 FMB 752-8630/18 Method Blank Total/NA Water SM4500 NO2 FMB 752-8630/8 Method Blank Total/NA Water SM4500 NO2 FLCS 752-8630/11 Lab Control Sample Total/NA Water SM4500 NO2 FLCSD 752-8630/39 Lab Control Sample Dup Total/NA Analysis Batch: 8631 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch GW SM4500 NO2 F752-23805-1 MW-4 Total/NA GW SM4500 NO2 F752-23805-2 MW-10A Total/NA GW SM4500 NO2 F752-23805-3 MW-18 Total/NA Surface Water SM4500 NO2 F752-23805-4 SW-2 Total/NA Surface Water SM4500 NO2 F752-23805-5 SW-3 Total/NA GW SM4500 NO2 F752-23805-6 Equipment Blank Total/NA GW SM4500 NO2 F752-23805-7 MW-8 Total/NA GW SM4500 NO2 F752-23805-8 MW-15 Total/NA GW SM4500 NO2 F752-23805-9 MW-16 Total/NA Surface Water SM4500 NO2 F752-23805-10 SW-1 Total/NA Water SM4500 NO2 FMB 752-8631/22 Method Blank Total/NA Water SM4500 NO2 FMB 752-8631/8 Method Blank Total/NA Water SM4500 NO2 FLCS 752-8631/11 Lab Control Sample Total/NA Water SM4500 NO2 FLCSD 752-8631/47 Lab Control Sample Dup Total/NA Analysis Batch: 8634 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water SM 4500 NO3 F752-23756-1 MW-19 Total/NA Water SM 4500 NO3 FMB 752-8634/46 Method Blank Total/NA Eurofins Raleigh Page 98 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Association Summary Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill General Chemistry (Continued) Analysis Batch: 8634 (Continued) Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water SM 4500 NO3 FMB 752-8634/71 Method Blank Total/NA Water SM 4500 NO3 FLCS 752-8634/47 Lab Control Sample Total/NA Water SM 4500 NO3 FLCS 752-8634/72 Lab Control Sample Total/NA Water SM 4500 NO3 FLCSD 752-8634/98 Lab Control Sample Dup Total/NA Water SM 4500 NO3 F752-23756-1 MS MW-19 Total/NA Water SM 4500 NO3 F752-23756-1 MSD MW-19 Total/NA Analysis Batch: 8639 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water SM 2540C752-23756-1 MW-19 Total/NA GW SM 2540C752-23805-1 MW-4 Total/NA GW SM 2540C752-23805-2 MW-10A Total/NA GW SM 2540C752-23805-3 MW-18 Total/NA Surface Water SM 2540C752-23805-4 SW-2 Total/NA Surface Water SM 2540C752-23805-5 SW-3 Total/NA GW SM 2540C752-23805-6 Equipment Blank Total/NA GW SM 2540C752-23805-7 MW-8 Total/NA GW SM 2540C752-23805-8 MW-15 Total/NA GW SM 2540C752-23805-9 MW-16 Total/NA Surface Water SM 2540C752-23805-10 SW-1 Total/NA Water SM 2540CMB 752-8639/1 Method Blank Total/NA Water SM 2540CLCS 752-8639/2 Lab Control Sample Total/NA Analysis Batch: 8655 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water Nitrate by calc752-23756-1 MW-19 Total/NA Analysis Batch: 8665 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch GW Nitrate by calc752-23805-1 MW-4 Total/NA GW Nitrate by calc752-23805-2 MW-10A Total/NA GW Nitrate by calc752-23805-3 MW-18 Total/NA Surface Water Nitrate by calc752-23805-4 SW-2 Total/NA Surface Water Nitrate by calc752-23805-5 SW-3 Total/NA GW Nitrate by calc752-23805-6 Equipment Blank Total/NA GW Nitrate by calc752-23805-7 MW-8 Total/NA GW Nitrate by calc752-23805-8 MW-15 Total/NA GW Nitrate by calc752-23805-9 MW-16 Total/NA Surface Water Nitrate by calc752-23805-10 SW-1 Total/NA Analysis Batch: 8670 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water SM4500 NO2 F752-23869-1 MW-17 Total/NA Water SM4500 NO2 FMB 752-8670/22 Method Blank Total/NA Water SM4500 NO2 FMB 752-8670/8 Method Blank Total/NA Water SM4500 NO2 FLCS 752-8670/11 Lab Control Sample Total/NA Water SM4500 NO2 FLCSD 752-8670/36 Lab Control Sample Dup Total/NA Water SM4500 NO2 F752-23869-1 MS MW-17 Total/NA Water SM4500 NO2 F752-23869-1 MSD MW-17 Total/NA Eurofins Raleigh Page 99 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Association Summary Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill General Chemistry Analysis Batch: 8687 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch GW SM 4500 NO3 F752-23805-1 MW-4 Total/NA GW SM 4500 NO3 F752-23805-2 MW-10A Total/NA GW SM 4500 NO3 F752-23805-3 MW-18 Total/NA Surface Water SM 4500 NO3 F752-23805-4 SW-2 Total/NA Surface Water SM 4500 NO3 F752-23805-5 SW-3 Total/NA GW SM 4500 NO3 F752-23805-6 Equipment Blank Total/NA GW SM 4500 NO3 F752-23805-7 MW-8 Total/NA GW SM 4500 NO3 F752-23805-8 MW-15 Total/NA GW SM 4500 NO3 F752-23805-9 MW-16 Total/NA Surface Water SM 4500 NO3 F752-23805-10 SW-1 Total/NA Water SM 4500 NO3 F752-23869-1 MW-17 Total/NA Water SM 4500 NO3 FMB 752-8687/46 Method Blank Total/NA Water SM 4500 NO3 FMB 752-8687/72 Method Blank Total/NA Water SM 4500 NO3 FMB 752-8687/8 Method Blank Total/NA Water SM 4500 NO3 FLCS 752-8687/47 Lab Control Sample Total/NA Water SM 4500 NO3 FLCS 752-8687/73 Lab Control Sample Total/NA Water SM 4500 NO3 FLCS 752-8687/9 Lab Control Sample Total/NA Water SM 4500 NO3 FLCSD 752-8687/86 Lab Control Sample Dup Total/NA Analysis Batch: 8694 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water Nitrate by calc752-23869-1 MW-17 Total/NA Analysis Batch: 8734 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water SM 2540C752-23869-1 MW-17 Total/NA Water SM 2540C752-23869-2 MW-1 Total/NA Water SM 2540CMB 752-8734/1 Method Blank Total/NA Water SM 2540CLCS 752-8734/2 Lab Control Sample Total/NA Water SM 2540C752-23869-1 DU MW-17 Total/NA Analysis Batch: 854807 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 4500 S2 F-2011752-23756-1 MW-19 Total/NA Water 4500 S2 F-2011MB 680-854807/1 Method Blank Total/NA Water 4500 S2 F-2011LCS 680-854807/2 Lab Control Sample Total/NA Water 4500 S2 F-2011LCSD 680-854807/3 Lab Control Sample Dup Total/NA Water 4500 S2 F-2011LLCS 680-854807/4 Lab Control Sample Total/NA Analysis Batch: 854832 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 2320B-2011752-23756-1 MW-19 Total/NA Water 2320B-2011MB 680-854832/4 Method Blank Total/NA Water 2320B-2011LCS 680-854832/6 Lab Control Sample Total/NA Water 2320B-2011LCSD 680-854832/30 Lab Control Sample Dup Total/NA Analysis Batch: 855136 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water SM 3500 FE D752-23756-1 MW-19 Total/NA GW SM 3500 FE D752-23805-1 MW-4 Total/NA GW SM 3500 FE D752-23805-2 MW-10A Total/NA Eurofins Raleigh Page 100 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Association Summary Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill General Chemistry (Continued) Analysis Batch: 855136 (Continued) Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch GW SM 3500 FE D752-23805-3 MW-18 Total/NA Surface Water SM 3500 FE D752-23805-4 SW-2 Total/NA Surface Water SM 3500 FE D752-23805-5 SW-3 Total/NA GW SM 3500 FE D752-23805-6 Equipment Blank Total/NA GW SM 3500 FE D752-23805-7 MW-8 Total/NA GW SM 3500 FE D752-23805-8 MW-15 Total/NA GW SM 3500 FE D752-23805-9 MW-16 Total/NA Surface Water SM 3500 FE D752-23805-10 SW-1 Total/NA Water SM 3500 FE DMB 680-855136/12 Method Blank Total/NA Water SM 3500 FE DLCS 680-855136/11 Lab Control Sample Total/NA GW SM 3500 FE D752-23805-2 MS MW-10A Total/NA GW SM 3500 FE D752-23805-2 MSD MW-10A Total/NA Analysis Batch: 855208 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Surface Water 4500 S2 F-2011752-23805-10 SW-1 Total/NA Water 4500 S2 F-2011MB 680-855208/1 Method Blank Total/NA Water 4500 S2 F-2011LCS 680-855208/2 Lab Control Sample Total/NA Water 4500 S2 F-2011LCSD 680-855208/3 Lab Control Sample Dup Total/NA Analysis Batch: 855260 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch GW 2320B-2011752-23805-1 MW-4 Total/NA GW 2320B-2011752-23805-2 MW-10A Total/NA GW 2320B-2011752-23805-3 MW-18 Total/NA Surface Water 2320B-2011752-23805-4 SW-2 Total/NA Surface Water 2320B-2011752-23805-5 SW-3 Total/NA GW 2320B-2011752-23805-6 Equipment Blank Total/NA GW 2320B-2011752-23805-7 MW-8 Total/NA GW 2320B-2011752-23805-8 MW-15 Total/NA Water 2320B-2011MB 680-855260/4 Method Blank Total/NA Water 2320B-2011LCS 680-855260/6 Lab Control Sample Total/NA Water 2320B-2011LCSD 680-855260/31 Lab Control Sample Dup Total/NA Analysis Batch: 855425 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch GW 4500 S2 F-2011752-23805-1 MW-4 Total/NA GW 4500 S2 F-2011752-23805-2 MW-10A Total/NA GW 4500 S2 F-2011752-23805-3 MW-18 Total/NA Surface Water 4500 S2 F-2011752-23805-4 SW-2 Total/NA Surface Water 4500 S2 F-2011752-23805-5 SW-3 Total/NA GW 4500 S2 F-2011752-23805-6 Equipment Blank Total/NA GW 4500 S2 F-2011752-23805-7 MW-8 Total/NA GW 4500 S2 F-2011752-23805-8 MW-15 Total/NA GW 4500 S2 F-2011752-23805-9 MW-16 Total/NA Water 4500 S2 F-2011MB 680-855425/1 Method Blank Total/NA Water 4500 S2 F-2011LCS 680-855425/2 Lab Control Sample Total/NA Water 4500 S2 F-2011LCSD 680-855425/3 Lab Control Sample Dup Total/NA GW 4500 S2 F-2011752-23805-1 DU MW-4 Total/NA Eurofins Raleigh Page 101 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Association Summary Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill General Chemistry Analysis Batch: 855601 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 4500 S2 F-2011752-23869-1 MW-17 Total/NA Water 4500 S2 F-2011752-23869-2 MW-1 Total/NA Water 4500 S2 F-2011MB 680-855601/1 Method Blank Total/NA Water 4500 S2 F-2011LCS 680-855601/2 Lab Control Sample Total/NA Water 4500 S2 F-2011LCSD 680-855601/3 Lab Control Sample Dup Total/NA Analysis Batch: 855666 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch GW 2320B-2011752-23805-9 MW-16 Total/NA Surface Water 2320B-2011752-23805-10 SW-1 Total/NA Water 2320B-2011MB 680-855666/4 Method Blank Total/NA Water 2320B-2011LCS 680-855666/6 Lab Control Sample Total/NA Water 2320B-2011LCSD 680-855666/31 Lab Control Sample Dup Total/NA Analysis Batch: 856052 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water SM 3500752-23756-1 MW-19 Total/NA GW SM 3500752-23805-1 MW-4 Total/NA GW SM 3500752-23805-2 MW-10A Total/NA GW SM 3500752-23805-3 MW-18 Total/NA Surface Water SM 3500752-23805-4 SW-2 Total/NA Surface Water SM 3500752-23805-5 SW-3 Total/NA GW SM 3500752-23805-6 Equipment Blank Total/NA GW SM 3500752-23805-7 MW-8 Total/NA GW SM 3500752-23805-8 MW-15 Total/NA GW SM 3500752-23805-9 MW-16 Total/NA Surface Water SM 3500752-23805-10 SW-1 Total/NA Water SM 3500752-23869-1 MW-17 Total/NA Water SM 3500752-23869-2 MW-1 Total/NA Analysis Batch: 856089 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 2320B-2011752-23869-1 MW-17 Total/NA Water 2320B-2011MB 680-856089/4 Method Blank Total/NA Water 2320B-2011LCS 680-856089/6 Lab Control Sample Total/NA Water 2320B-2011LCSD 680-856089/31 Lab Control Sample Dup Total/NA Analysis Batch: 856727 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water SM 3500 FE D752-23869-1 MW-17 Total/NA Water SM 3500 FE D752-23869-2 MW-1 Total/NA Water SM 3500 FE DMB 680-856727/22 Method Blank Total/NA Water SM 3500 FE DLCS 680-856727/21 Lab Control Sample Total/NA Water SM 3500 FE D752-23869-1 MS MW-17 Total/NA Water SM 3500 FE D752-23869-1 MSD MW-17 Total/NA Eurofins Raleigh Page 102 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Lab Chronicle Client: Carlson Environmental Consultants Job ID: 752-23756-1 Project/Site: 201.11.17/Asheboro C&D Landfill Client Sample ID: MW-19 Lab Sample ID: 752-23756-1 Matrix: WaterDate Collected: 09/03/24 14:53 Date Received: 09/04/24 11:00 Analysis 8260D RY18685 EET RAL Type Batch Batch MethodPrep Type LabAnalystRun Prepared or Analyzed Batch Number Dilution Factor Total/NA 09/10/24 20:08 Analysis 8260D SIM 14D 1 854693 MJY EET SAVTotal/NA 09/06/24 10:30 Analysis 300.0-1993 R2.1 1 855345 AF EET SAVTotal/NA 09/11/24 16:12 Analysis 2340B-2011 1 855350 BCB EET SAVTotal/NA 09/11/24 11:32 Prep 3005A 854685 RR EET SAVTotal Recoverable 09/06/24 06:29 Analysis 6010D 1 854907 BJB EET SAVTotal Recoverable 09/06/24 12:24 Prep 3005A 854686 RR EET SAVTotal Recoverable 09/06/24 06:29 Analysis 6020B 1 855105 BWR EET SAVTotal Recoverable 09/09/24 17:46 Prep 7470A 854797 MG EET SAVTotal/NA 09/06/24 13:21 Analysis 7470A 1 854916 BCB EET SAVTotal/NA 09/08/24 12:42 Analysis 2320B-2011 1 854832 PG EET SAVTotal/NA 09/06/24 12:50 Analysis 4500 S2 F-2011 1 854807 JAS EET SAVTotal/NA 09/06/24 14:16 Analysis Nitrate by calc 1 8655 ALG EET RALTotal/NA 09/09/24 12:58 Analysis SM 2540C 1 8639 CB EET RALTotal/NA 09/06/24 16:28 Analysis SM 3500 1 856052 ALG EET SAVTotal/NA 09/16/24 10:19 Analysis SM 3500 FE D 1 855136 KD EET SAVTotal/NA 09/07/24 10:44 Analysis SM 4500 NO3 F 1 8634 ME EET RALTotal/NA 09/05/24 13:06 Analysis SM4500 NO2 F 1 8630 ME EET RALTotal/NA 09/04/24 15:41 Client Sample ID: MW-4 Lab Sample ID: 752-23805-1 Matrix: GWDate Collected: 09/04/24 15:36 Date Received: 09/05/24 11:00 Analysis 8260D RY18723 EET RAL Type Batch Batch MethodPrep Type LabAnalystRun Prepared or Analyzed Batch Number Dilution Factor Total/NA 09/12/24 03:19 Analysis 8260D SIM 14D 1 854841 MJY EET SAVTotal/NA 09/07/24 11:58 Analysis 300.0-1993 R2.1 1 855904 KMB EET SAVTotal/NA 09/14/24 20:12 Prep 3005A 854930 RR EET SAVTotal Recoverable 09/09/24 05:44 Analysis 6010D 1 855104 BJB EET SAVTotal Recoverable 09/09/24 21:31 Prep 3005A 854931 RR EET SAVTotal Recoverable 09/09/24 05:44 Analysis 6020B 1 855105 BWR EET SAVTotal Recoverable 09/09/24 23:29 Prep 7470A 855068 MG EET SAVTotal/NA 09/09/24 15:09 Analysis 7470A 1 855210 BCB EET SAVTotal/NA 09/10/24 11:22 Analysis 2320B-2011 1 855260 PG EET SAVTotal/NA 09/10/24 16:21 Analysis 4500 S2 F-2011 1 855425 JAS EET SAVTotal/NA 09/11/24 15:20 Analysis Nitrate by calc 1 8665 ALG EET RALTotal/NA 09/09/24 12:58 Analysis SM 2540C 1 8639 CB EET RALTotal/NA 09/06/24 16:28 Analysis SM 3500 1 856052 ALG EET SAVTotal/NA 09/16/24 10:19 Analysis SM 3500 FE D 1 855136 KD EET SAVTotal/NA 09/07/24 10:44 Analysis SM 4500 NO3 F 1 8687 ME EET RALTotal/NA 09/09/24 10:41 Analysis SM4500 NO2 F 1 8631 ME EET RALTotal/NA 09/05/24 17:36 Eurofins Raleigh Page 103 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Lab Chronicle Client: Carlson Environmental Consultants Job ID: 752-23756-1 Project/Site: 201.11.17/Asheboro C&D Landfill Client Sample ID: MW-10A Lab Sample ID: 752-23805-2 Matrix: GWDate Collected: 09/04/24 14:21 Date Received: 09/05/24 11:00 Analysis 8260D RY18723 EET RAL Type Batch Batch MethodPrep Type LabAnalystRun Prepared or Analyzed Batch Number Dilution Factor Total/NA 09/12/24 03:41 Analysis 8260D SIM 14D 1 854841 MJY EET SAVTotal/NA 09/07/24 12:24 Analysis 300.0-1993 R2.1 1 855904 KMB EET SAVTotal/NA 09/14/24 20:18 Prep 3005A 854930 RR EET SAVTotal Recoverable 09/09/24 05:44 Analysis 6010D 1 855104 BJB EET SAVTotal Recoverable 09/09/24 21:23 Prep 3005A 854931 RR EET SAVTotal Recoverable 09/09/24 05:44 Analysis 6020B 1 855105 BWR EET SAVTotal Recoverable 09/09/24 23:26 Prep 7470A 855068 MG EET SAVTotal/NA 09/09/24 15:09 Analysis 7470A 1 855210 BCB EET SAVTotal/NA 09/10/24 11:20 Analysis 2320B-2011 1 855260 PG EET SAVTotal/NA 09/10/24 16:12 Analysis 4500 S2 F-2011 1 855425 JAS EET SAVTotal/NA 09/11/24 15:20 Analysis Nitrate by calc 1 8665 ALG EET RALTotal/NA 09/09/24 12:58 Analysis SM 2540C 1 8639 CB EET RALTotal/NA 09/06/24 16:28 Analysis SM 3500 1 856052 ALG EET SAVTotal/NA 09/16/24 10:19 Analysis SM 3500 FE D 1 855136 KD EET SAVTotal/NA 09/07/24 10:44 Analysis SM 4500 NO3 F 1 8687 ME EET RALTotal/NA 09/09/24 10:42 Analysis SM4500 NO2 F 1 8631 ME EET RALTotal/NA 09/05/24 17:37 Client Sample ID: MW-18 Lab Sample ID: 752-23805-3 Matrix: GWDate Collected: 09/04/24 10:30 Date Received: 09/05/24 11:00 Analysis 8260D RY18723 EET RAL Type Batch Batch MethodPrep Type LabAnalystRun Prepared or Analyzed Batch Number Dilution Factor Total/NA 09/12/24 04:03 Analysis 8260D SIM 14D 1 854841 MJY EET SAVTotal/NA 09/07/24 12:50 Analysis 300.0-1993 R2.1 5 855904 KMB EET SAVTotal/NA 09/14/24 20:25 Prep 3005A 854930 RR EET SAVTotal Recoverable 09/09/24 05:44 Analysis 6010D 1 855104 BJB EET SAVTotal Recoverable 09/09/24 21:21 Prep 3005A 854931 RR EET SAVTotal Recoverable 09/09/24 05:44 Analysis 6020B 1 855105 BWR EET SAVTotal Recoverable 09/09/24 23:23 Prep 7470A 855068 MG EET SAVTotal/NA 09/09/24 15:09 Analysis 7470A 1 855210 BCB EET SAVTotal/NA 09/10/24 11:18 Analysis 2320B-2011 1 855260 PG EET SAVTotal/NA 09/10/24 16:46 Analysis 4500 S2 F-2011 1 855425 JAS EET SAVTotal/NA 09/11/24 15:20 Analysis Nitrate by calc 1 8665 ALG EET RALTotal/NA 09/09/24 12:58 Analysis SM 2540C 1 8639 CB EET RALTotal/NA 09/06/24 16:28 Analysis SM 3500 1 856052 ALG EET SAVTotal/NA 09/16/24 10:19 Analysis SM 3500 FE D 1 855136 KD EET SAVTotal/NA 09/07/24 10:38 Analysis SM 4500 NO3 F 1 8687 ME EET RALTotal/NA 09/09/24 10:44 Analysis SM4500 NO2 F 1 8631 ME EET RALTotal/NA 09/05/24 17:38 Eurofins Raleigh Page 104 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Lab Chronicle Client: Carlson Environmental Consultants Job ID: 752-23756-1 Project/Site: 201.11.17/Asheboro C&D Landfill Client Sample ID: SW-2 Lab Sample ID: 752-23805-4 Matrix: Surface WaterDate Collected: 09/04/24 13:02 Date Received: 09/05/24 11:00 Analysis 8260D RY18723 EET RAL Type Batch Batch MethodPrep Type LabAnalystRun Prepared or Analyzed Batch Number Dilution Factor Total/NA 09/12/24 04:25 Analysis 8260D SIM 14D 1 854841 MJY EET SAVTotal/NA 09/07/24 13:16 Analysis 300.0-1993 R2.1 1 855904 KMB EET SAVTotal/NA 09/14/24 20:31 Analysis 2340B-2011 1 856248 BCB EET SAVTotal/NA 09/17/24 12:06 Prep 3005A 854930 RR EET SAVTotal Recoverable 09/09/24 05:44 Analysis 6010D 1 855104 BJB EET SAVTotal Recoverable 09/09/24 21:18 Prep 3005A 854931 RR EET SAVTotal Recoverable 09/09/24 05:44 Analysis 6020B 1 855105 BWR EET SAVTotal Recoverable 09/09/24 23:21 Prep 7470A 855068 MG EET SAVTotal/NA 09/09/24 15:09 Analysis 7470A 1 855210 BCB EET SAVTotal/NA 09/10/24 11:07 Analysis 2320B-2011 1 855260 PG EET SAVTotal/NA 09/10/24 16:38 Analysis 4500 S2 F-2011 1 855425 JAS EET SAVTotal/NA 09/11/24 15:20 Analysis Nitrate by calc 1 8665 ALG EET RALTotal/NA 09/09/24 12:58 Analysis SM 2540C 1 8639 CB EET RALTotal/NA 09/06/24 16:28 Analysis SM 3500 1 856052 ALG EET SAVTotal/NA 09/16/24 10:19 Analysis SM 3500 FE D 1 855136 KD EET SAVTotal/NA 09/07/24 10:44 Analysis SM 4500 NO3 F 1 8687 ME EET RALTotal/NA 09/09/24 10:46 Analysis SM4500 NO2 F 1 8631 ME EET RALTotal/NA 09/05/24 17:39 Client Sample ID: SW-3 Lab Sample ID: 752-23805-5 Matrix: Surface WaterDate Collected: 09/04/24 16:10 Date Received: 09/05/24 11:00 Analysis 8260D RY18723 EET RAL Type Batch Batch MethodPrep Type LabAnalystRun Prepared or Analyzed Batch Number Dilution Factor Total/NA 09/12/24 04:47 Analysis 8260D SIM 14D 1 854841 MJY EET SAVTotal/NA 09/07/24 13:41 Analysis 300.0-1993 R2.1 1 855951 KMB EET SAVTotal/NA 09/14/24 21:23 Analysis 2340B-2011 1 856248 BCB EET SAVTotal/NA 09/17/24 12:06 Prep 3005A 854930 RR EET SAVTotal Recoverable 09/09/24 05:44 Analysis 6010D 1 855104 BJB EET SAVTotal Recoverable 09/09/24 21:11 Prep 3005A 854931 RR EET SAVTotal Recoverable 09/09/24 05:44 Analysis 6020B 1 855105 BWR EET SAVTotal Recoverable 09/09/24 23:13 Prep 7470A 855068 MG EET SAVTotal/NA 09/09/24 15:09 Analysis 7470A 1 855210 BCB EET SAVTotal/NA 09/10/24 11:26 Analysis 2320B-2011 1 855260 PG EET SAVTotal/NA 09/10/24 16:30 Analysis 4500 S2 F-2011 1 855425 JAS EET SAVTotal/NA 09/11/24 15:20 Analysis Nitrate by calc 1 8665 ALG EET RALTotal/NA 09/09/24 12:58 Analysis SM 2540C 1 8639 CB EET RALTotal/NA 09/06/24 16:28 Analysis SM 3500 1 856052 ALG EET SAVTotal/NA 09/16/24 10:19 Analysis SM 3500 FE D 1 855136 KD EET SAVTotal/NA 09/07/24 10:38 Analysis SM 4500 NO3 F 1 8687 ME EET RALTotal/NA 09/09/24 10:48 Analysis SM4500 NO2 F 1 8631 ME EET RALTotal/NA 09/05/24 17:40 Eurofins Raleigh Page 105 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Lab Chronicle Client: Carlson Environmental Consultants Job ID: 752-23756-1 Project/Site: 201.11.17/Asheboro C&D Landfill Client Sample ID: Equipment Blank Lab Sample ID: 752-23805-6 Matrix: GWDate Collected: 09/04/24 16:10 Date Received: 09/05/24 11:00 Analysis 8260D RY18723 EET RAL Type Batch Batch MethodPrep Type LabAnalystRun Prepared or Analyzed Batch Number Dilution Factor Total/NA 09/12/24 00:21 Analysis 8260D SIM 14D 1 854841 MJY EET SAVTotal/NA 09/07/24 11:33 Analysis 300.0-1993 R2.1 1 855951 KMB EET SAVTotal/NA 09/14/24 21:42 Prep 3005A 854930 RR EET SAVTotal Recoverable 09/09/24 05:44 Analysis 6010D 1 855104 BJB EET SAVTotal Recoverable 09/09/24 21:43 Prep 3005A 854931 RR EET SAVTotal Recoverable 09/09/24 05:44 Analysis 6020B 1 855105 BWR EET SAVTotal Recoverable 09/09/24 23:47 Prep 7470A 855068 MG EET SAVTotal/NA 09/09/24 15:09 Analysis 7470A 1 855210 BCB EET SAVTotal/NA 09/10/24 11:24 Analysis 2320B-2011 1 855260 PG EET SAVTotal/NA 09/10/24 16:06 Analysis 4500 S2 F-2011 1 855425 JAS EET SAVTotal/NA 09/11/24 15:20 Analysis Nitrate by calc 1 8665 ALG EET RALTotal/NA 09/09/24 12:58 Analysis SM 2540C 1 8639 CB EET RALTotal/NA 09/06/24 16:28 Analysis SM 3500 1 856052 ALG EET SAVTotal/NA 09/16/24 10:19 Analysis SM 3500 FE D 1 855136 KD EET SAVTotal/NA 09/07/24 10:44 Analysis SM 4500 NO3 F 1 8687 ME EET RALTotal/NA 09/09/24 10:50 Analysis SM4500 NO2 F 1 8631 ME EET RALTotal/NA 09/05/24 17:41 Client Sample ID: MW-8 Lab Sample ID: 752-23805-7 Matrix: GWDate Collected: 09/04/24 12:31 Date Received: 09/05/24 11:00 Analysis 8260D RY18723 EET RAL Type Batch Batch MethodPrep Type LabAnalystRun Prepared or Analyzed Batch Number Dilution Factor Total/NA 09/12/24 05:10 Analysis 8260D SIM 14D 1 854841 MJY EET SAVTotal/NA 09/07/24 14:07 Analysis 300.0-1993 R2.1 1 855951 KMB EET SAVTotal/NA 09/14/24 21:48 Prep 3005A 854930 RR EET SAVTotal Recoverable 09/09/24 05:44 Analysis 6010D 1 855104 BJB EET SAVTotal Recoverable 09/09/24 21:41 Prep 3005A 854931 RR EET SAVTotal Recoverable 09/09/24 05:44 Analysis 6020B 1 855105 BWR EET SAVTotal Recoverable 09/09/24 23:44 Prep 7470A 855144 MG EET SAVTotal/NA 09/10/24 10:23 Analysis 7470A 1 855253 BCB EET SAVTotal/NA 09/10/24 15:37 Analysis 2320B-2011 1 855260 PG EET SAVTotal/NA 09/10/24 17:03 Analysis 4500 S2 F-2011 1 855425 JAS EET SAVTotal/NA 09/11/24 15:20 Analysis Nitrate by calc 1 8665 ALG EET RALTotal/NA 09/09/24 12:58 Analysis SM 2540C 1 8639 CB EET RALTotal/NA 09/06/24 16:28 Analysis SM 3500 1 856052 ALG EET SAVTotal/NA 09/16/24 10:19 Analysis SM 3500 FE D 1 855136 KD EET SAVTotal/NA 09/07/24 10:38 Analysis SM 4500 NO3 F 1 8687 ME EET RALTotal/NA 09/09/24 10:52 Analysis SM4500 NO2 F 1 8631 ME EET RALTotal/NA 09/05/24 17:41 Eurofins Raleigh Page 106 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Lab Chronicle Client: Carlson Environmental Consultants Job ID: 752-23756-1 Project/Site: 201.11.17/Asheboro C&D Landfill Client Sample ID: MW-15 Lab Sample ID: 752-23805-8 Matrix: GWDate Collected: 09/04/24 12:42 Date Received: 09/05/24 11:00 Analysis 8260D RY18723 EET RAL Type Batch Batch MethodPrep Type LabAnalystRun Prepared or Analyzed Batch Number Dilution Factor Total/NA 09/12/24 05:32 Analysis 8260D SIM 14D 1 854841 MJY EET SAVTotal/NA 09/07/24 14:33 Analysis 300.0-1993 R2.1 1 855951 KMB EET SAVTotal/NA 09/14/24 21:55 Prep 3005A 854930 RR EET SAVTotal Recoverable 09/09/24 05:44 Analysis 6010D 1 855104 BJB EET SAVTotal Recoverable 09/09/24 21:38 Prep 3005A 854931 RR EET SAVTotal Recoverable 09/09/24 05:44 Analysis 6020B 1 855105 BWR EET SAVTotal Recoverable 09/09/24 23:42 Prep 7470A 855144 MG EET SAVTotal/NA 09/10/24 10:23 Analysis 7470A 1 855253 BCB EET SAVTotal/NA 09/10/24 15:26 Analysis 2320B-2011 1 855260 PG EET SAVTotal/NA 09/10/24 16:55 Analysis 4500 S2 F-2011 1 855425 JAS EET SAVTotal/NA 09/11/24 15:20 Analysis Nitrate by calc 1 8665 ALG EET RALTotal/NA 09/09/24 12:58 Analysis SM 2540C 1 8639 CB EET RALTotal/NA 09/06/24 16:28 Analysis SM 3500 1 856052 ALG EET SAVTotal/NA 09/16/24 10:19 Analysis SM 3500 FE D 1 855136 KD EET SAVTotal/NA 09/07/24 10:38 Analysis SM 4500 NO3 F 1 8687 ME EET RALTotal/NA 09/09/24 10:53 Analysis SM4500 NO2 F 1 8631 ME EET RALTotal/NA 09/05/24 17:42 Client Sample ID: MW-16 Lab Sample ID: 752-23805-9 Matrix: GWDate Collected: 09/04/24 15:33 Date Received: 09/05/24 11:00 Analysis 8260D RY18723 EET RAL Type Batch Batch MethodPrep Type LabAnalystRun Prepared or Analyzed Batch Number Dilution Factor Total/NA 09/12/24 05:54 Analysis 8260D SIM 14D 1 854841 MJY EET SAVTotal/NA 09/07/24 14:59 Analysis 300.0-1993 R2.1 1 855951 KMB EET SAVTotal/NA 09/14/24 22:01 Prep 3005A 854930 RR EET SAVTotal Recoverable 09/09/24 05:44 Analysis 6010D 1 855104 BJB EET SAVTotal Recoverable 09/09/24 21:36 Prep 3005A 854931 RR EET SAVTotal Recoverable 09/09/24 05:44 Analysis 6020B 1 855105 BWR EET SAVTotal Recoverable 09/09/24 23:39 Prep 7470A 855144 MG EET SAVTotal/NA 09/10/24 10:23 Analysis 7470A 1 855253 BCB EET SAVTotal/NA 09/10/24 15:24 Analysis 2320B-2011 1 855666 PG EET SAVTotal/NA 09/12/24 16:12 Analysis 4500 S2 F-2011 1 855425 JAS EET SAVTotal/NA 09/11/24 15:20 Analysis Nitrate by calc 1 8665 ALG EET RALTotal/NA 09/09/24 12:58 Analysis SM 2540C 1 8639 CB EET RALTotal/NA 09/06/24 16:28 Analysis SM 3500 1 856052 ALG EET SAVTotal/NA 09/16/24 10:19 Analysis SM 3500 FE D 1 855136 KD EET SAVTotal/NA 09/07/24 10:38 Analysis SM 4500 NO3 F 10 8687 ME EET RALTotal/NA 09/09/24 13:42 Analysis SM4500 NO2 F 1 8631 ME EET RALTotal/NA 09/05/24 17:43 Eurofins Raleigh Page 107 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Lab Chronicle Client: Carlson Environmental Consultants Job ID: 752-23756-1 Project/Site: 201.11.17/Asheboro C&D Landfill Client Sample ID: SW-1 Lab Sample ID: 752-23805-10 Matrix: Surface WaterDate Collected: 09/04/24 11:00 Date Received: 09/05/24 11:00 Analysis 8260D RY18723 EET RAL Type Batch Batch MethodPrep Type LabAnalystRun Prepared or Analyzed Batch Number Dilution Factor Total/NA 09/12/24 06:16 Analysis 8260D SIM 14D 1 854841 MJY EET SAVTotal/NA 09/07/24 15:24 Analysis 300.0-1993 R2.1 1 855951 KMB EET SAVTotal/NA 09/14/24 22:08 Analysis 2340B-2011 1 856248 BCB EET SAVTotal/NA 09/17/24 12:06 Prep 3005A 854930 RR EET SAVTotal Recoverable 09/09/24 05:44 Analysis 6010D 1 855104 BJB EET SAVTotal Recoverable 09/09/24 21:33 Prep 3005A 854931 RR EET SAVTotal Recoverable 09/09/24 05:44 Analysis 6020B 1 855105 BWR EET SAVTotal Recoverable 09/09/24 23:31 Prep 7470A 855144 MG EET SAVTotal/NA 09/10/24 10:23 Analysis 7470A 1 855253 BCB EET SAVTotal/NA 09/10/24 15:22 Analysis 2320B-2011 1 855666 PG EET SAVTotal/NA 09/12/24 16:03 Analysis 4500 S2 F-2011 1 855208 JAS EET SAVTotal/NA 09/10/24 13:15 Analysis Nitrate by calc 1 8665 ALG EET RALTotal/NA 09/09/24 12:58 Analysis SM 2540C 1 8639 CB EET RALTotal/NA 09/06/24 16:28 Analysis SM 3500 1 856052 ALG EET SAVTotal/NA 09/16/24 10:19 Analysis SM 3500 FE D 1 855136 KD EET SAVTotal/NA 09/07/24 10:38 Analysis SM 4500 NO3 F 1 8687 ME EET RALTotal/NA 09/09/24 11:23 Analysis SM4500 NO2 F 1 8631 ME EET RALTotal/NA 09/05/24 17:44 Client Sample ID: MW-17 Lab Sample ID: 752-23869-1 Matrix: WaterDate Collected: 09/05/24 10:51 Date Received: 09/06/24 09:30 Analysis 8260D RY18744 EET RAL Type Batch Batch MethodPrep Type LabAnalystRun Prepared or Analyzed Batch Number Dilution Factor Total/NA 09/13/24 05:12 Analysis 8260D RA 1 8754 RY EET RALTotal/NA 09/13/24 23:14 Analysis 8260D SIM 14D 1 854841 MJY EET SAVTotal/NA 09/07/24 18:37 Analysis 300.0-1993 R2.1 1 856213 KMB EET SAVTotal/NA 09/17/24 14:19 Analysis 2340B-2011 1 856248 BCB EET SAVTotal/NA 09/17/24 12:06 Prep 3005A 854930 RR EET SAVTotal Recoverable 09/09/24 05:44 Analysis 6010D 1 855104 BJB EET SAVTotal Recoverable 09/09/24 21:46 Prep 3005A 854931 RR EET SAVTotal Recoverable 09/09/24 05:44 Analysis 6020B 1 855105 BWR EET SAVTotal Recoverable 09/09/24 23:49 Prep 7470A 855144 MG EET SAVTotal/NA 09/10/24 10:23 Analysis 7470A 1 855253 BCB EET SAVTotal/NA 09/10/24 15:28 Analysis 2320B-2011 1 856089 PG EET SAVTotal/NA 09/13/24 22:26 Analysis 4500 S2 F-2011 1 855601 JAS EET SAVTotal/NA 09/12/24 14:23 Analysis Nitrate by calc 1 8694 ALG EET RALTotal/NA 09/10/24 14:24 Analysis SM 2540C 1 8734 CB EET RALTotal/NA 09/12/24 14:14 Analysis SM 3500 1 856052 ALG EET SAVTotal/NA 09/24/24 07:56 Analysis SM 3500 FE D 1 856727 KD EET SAVTotal/NA 09/19/24 13:34 Analysis SM 4500 NO3 F 5 8687 ME EET RALTotal/NA 09/09/24 13:46 Eurofins Raleigh Page 108 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Lab Chronicle Client: Carlson Environmental Consultants Job ID: 752-23756-1 Project/Site: 201.11.17/Asheboro C&D Landfill Client Sample ID: MW-17 Lab Sample ID: 752-23869-1 Matrix: WaterDate Collected: 09/05/24 10:51 Date Received: 09/06/24 09:30 Analysis SM4500 NO2 F ME18670 EET RAL Type Batch Batch MethodPrep Type LabAnalystRun Prepared or Analyzed Batch Number Dilution Factor Total/NA 09/06/24 16:01 Client Sample ID: MW-1 Lab Sample ID: 752-23869-2 Matrix: WaterDate Collected: 09/05/24 08:58 Date Received: 09/06/24 09:30 Prep 3005A RR854930 EET SAV Type Batch Batch MethodPrep Type LabAnalystRun Prepared or Analyzed Batch Number Dilution Factor Total Recoverable 09/09/24 05:44 Analysis 6010D 1 855104 BJB EET SAVTotal Recoverable 09/09/24 21:48 Prep 3005A 854931 RR EET SAVTotal Recoverable 09/09/24 05:44 Analysis 6020B 1 855105 BWR EET SAVTotal Recoverable 09/09/24 23:52 Prep 7470A 855144 MG EET SAVTotal/NA 09/10/24 10:23 Analysis 7470A 1 855253 BCB EET SAVTotal/NA 09/10/24 15:30 Analysis 4500 S2 F-2011 1 855601 JAS EET SAVTotal/NA 09/12/24 14:23 Analysis SM 2540C 1 8734 CB EET RALTotal/NA 09/12/24 14:14 Analysis SM 3500 1 856052 ALG EET SAVTotal/NA 09/24/24 07:56 Analysis SM 3500 FE D 1 856727 KD EET SAVTotal/NA 09/19/24 13:34 Client Sample ID: Trip Blank Lab Sample ID: 752-23869-3 Matrix: WaterDate Collected: 09/05/24 00:00 Date Received: 09/06/24 09:30 Analysis 8260D RY18744 EET RAL Type Batch Batch MethodPrep Type LabAnalystRun Prepared or Analyzed Batch Number Dilution Factor Total/NA 09/13/24 02:36 Laboratory References: EET RAL = Eurofins Raleigh, 104 Woodwinds Industrial Court, Suite A, Cary, NC 27511, TEL (919)467-3090 EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL (912)354-7858 Eurofins Raleigh Page 109 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Accreditation/Certification Summary Client: Carlson Environmental Consultants Job ID: 752-23756-1 Project/Site: 201.11.17/Asheboro C&D Landfill Laboratory: Eurofins Raleigh Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below. Authority Program Identification Number Expiration Date North Carolina (WW/SW)State 591 12-31-24 Laboratory: Eurofins Savannah Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below. Authority Program Identification Number Expiration Date North Carolina (WW/SW)State 269 12-31-24 Eurofins Raleigh Page 110 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Method Summary Job ID: 752-23756-1Client: Carlson Environmental Consultants Project/Site: 201.11.17/Asheboro C&D Landfill Method Method Description LaboratoryProtocol SW8468260DVolatile Organic Compounds by GC/MS EET RAL SW8468260D SIM 14D Volatile Organic Compounds (GC/MS)EET SAV MCAWW300.0-1993 R2.1 Anions, Ion Chromatography EET SAV SM2340B-2011 Total Hardness (as CaCO3) by calculation EET SAV SW8466010DMetals (ICP)EET SAV SW8466020BMetals (ICP/MS)EET SAV SW8467470AMercury (CVAA)EET SAV SM2320B-2011 Alkalinity, Total EET SAV SM4500 S2 F-2011 Sulfide, Total EET SAV SMNitrate by calc Nitrogen, Nitrate-Nitrite EET RAL SMSM 2540C Solids, Total Dissolved (TDS)EET RAL SMSM 3500 Iron, Ferric EET SAV SMSM 3500 FE D Iron, Ferrous EET SAV SMSM 4500 NO3 F Nitrogen, Nitrate EET RAL SMSM4500 NO2 F Nitrogen, Nitrite EET RAL SW8463005APreparation, Total Recoverable or Dissolved Metals EET SAV SW8465030CPurge and Trap EET RAL SW8465030CPurge and Trap EET SAV SW8467470APreparation, Mercury EET SAV Protocol References: MCAWW = "Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And Subsequent Revisions. SM = "Standard Methods For The Examination Of Water And Wastewater" SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. Laboratory References: EET RAL = Eurofins Raleigh, 104 Woodwinds Industrial Court, Suite A, Cary, NC 27511, TEL (919)467-3090 EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL (912)354-7858 Eurofins Raleigh Page 111 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Sample Summary Client: Carlson Environmental Consultants Job ID: 752-23756-1 Project/Site: 201.11.17/Asheboro C&D Landfill Lab Sample ID Client Sample ID Matrix Collected Received 752-23756-1 MW-19 Water 09/03/24 14:53 09/04/24 11:00 752-23805-1 MW-4 GW 09/04/24 15:36 09/05/24 11:00 752-23805-2 MW-10A GW 09/04/24 14:21 09/05/24 11:00 752-23805-3 MW-18 GW 09/04/24 10:30 09/05/24 11:00 752-23805-4 SW-2 Surface Water 09/04/24 13:02 09/05/24 11:00 752-23805-5 SW-3 Surface Water 09/04/24 16:10 09/05/24 11:00 752-23805-6 Equipment Blank GW 09/04/24 16:10 09/05/24 11:00 752-23805-7 MW-8 GW 09/04/24 12:31 09/05/24 11:00 752-23805-8 MW-15 GW 09/04/24 12:42 09/05/24 11:00 752-23805-9 MW-16 GW 09/04/24 15:33 09/05/24 11:00 752-23805-10 SW-1 Surface Water 09/04/24 11:00 09/05/24 11:00 752-23869-1 MW-17 Water 09/05/24 10:51 09/06/24 09:30 752-23869-2 MW-1 Water 09/05/24 08:58 09/06/24 09:30 752-23869-3 Trip Blank Water 09/05/24 00:00 09/06/24 09:30 Eurofins RaleighPage 112 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Page 113 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Page 114 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Page 115 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Page 116 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Page 117 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Page 118 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Login Sample Receipt Checklist Client: Carlson Environmental Consultants Job Number: 752-23756-1 Login Number: 23756 Question Answer Comment Creator: Yonish, Rachel List Source: Eurofins Raleigh List Number: 1 TrueRadioactivity wasn't checked or is </= background as measured by a survey meter. TrueThe cooler's custody seal, if present, is intact. TrueSample custody seals, if present, are intact. TrueThe cooler or samples do not appear to have been compromised or tampered with. TrueSamples were received on ice. TrueCooler Temperature is acceptable. TrueCooler Temperature is recorded. TrueCOC is present. TrueCOC is filled out in ink and legible. TrueCOC is filled out with all pertinent information. TrueIs the Field Sampler's name present on COC? TrueThere are no discrepancies between the containers received and the COC. TrueSamples are received within Holding Time (excluding tests with immediate HTs) TrueSample containers have legible labels. TrueContainers are not broken or leaking. TrueSample collection date/times are provided. TrueAppropriate sample containers are used. TrueSample bottles are completely filled. TrueSample Preservation Verified. TrueThere is sufficient vol. for all requested analyses, incl. any requested MS/MSDs TrueContainers requiring zero headspace have no headspace or bubble is <6mm (1/4"). TrueMultiphasic samples are not present. TrueSamples do not require splitting or compositing. TrueResidual Chlorine Checked. Eurofins Raleigh Page 119 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Login Sample Receipt Checklist Client: Carlson Environmental Consultants Job Number: 752-23756-1 Login Number: 23756 Question Answer Comment Creator: Lincoln, Alyssa List Source: Eurofins Savannah List Creation: 09/05/24 01:53 PMList Number: 2 N/ARadioactivity wasn't checked or is </= background as measured by a survey meter. TrueThe cooler's custody seal, if present, is intact. TrueSample custody seals, if present, are intact. TrueThe cooler or samples do not appear to have been compromised or tampered with. TrueSamples were received on ice. TrueCooler Temperature is acceptable. TrueCooler Temperature is recorded. TrueCOC is present. TrueCOC is filled out in ink and legible. TrueCOC is filled out with all pertinent information. TrueIs the Field Sampler's name present on COC? TrueThere are no discrepancies between the containers received and the COC. TrueSamples are received within Holding Time (excluding tests with immediate HTs) TrueSample containers have legible labels. TrueContainers are not broken or leaking. TrueSample collection date/times are provided. TrueAppropriate sample containers are used. TrueSample bottles are completely filled. N/ASample Preservation Verified. TrueThere is sufficient vol. for all requested analyses, incl. any requested MS/MSDs N/AContainers requiring zero headspace have no headspace or bubble is <6mm (1/4"). TrueMultiphasic samples are not present. TrueSamples do not require splitting or compositing. N/AResidual Chlorine Checked. Eurofins Raleigh Page 120 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Login Sample Receipt Checklist Client: Carlson Environmental Consultants Job Number: 752-23756-1 Login Number: 23805 Question Answer Comment Creator: Yonish, Rachel List Source: Eurofins Raleigh List Number: 1 TrueRadioactivity wasn't checked or is </= background as measured by a survey meter. TrueThe cooler's custody seal, if present, is intact. TrueSample custody seals, if present, are intact. TrueThe cooler or samples do not appear to have been compromised or tampered with. TrueSamples were received on ice. TrueCooler Temperature is acceptable. TrueCooler Temperature is recorded. TrueCOC is present. TrueCOC is filled out in ink and legible. TrueCOC is filled out with all pertinent information. TrueIs the Field Sampler's name present on COC? TrueThere are no discrepancies between the containers received and the COC. TrueSamples are received within Holding Time (excluding tests with immediate HTs) TrueSample containers have legible labels. TrueContainers are not broken or leaking. TrueSample collection date/times are provided. TrueAppropriate sample containers are used. TrueSample bottles are completely filled. TrueSample Preservation Verified. TrueThere is sufficient vol. for all requested analyses, incl. any requested MS/MSDs TrueContainers requiring zero headspace have no headspace or bubble is <6mm (1/4"). TrueMultiphasic samples are not present. TrueSamples do not require splitting or compositing. TrueResidual Chlorine Checked. Eurofins Raleigh Page 121 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Login Sample Receipt Checklist Client: Carlson Environmental Consultants Job Number: 752-23756-1 Login Number: 23805 Question Answer Comment Creator: Lincoln, Alyssa List Source: Eurofins Savannah List Creation: 09/06/24 02:19 PMList Number: 2 N/ARadioactivity wasn't checked or is </= background as measured by a survey meter. TrueThe cooler's custody seal, if present, is intact. TrueSample custody seals, if present, are intact. TrueThe cooler or samples do not appear to have been compromised or tampered with. TrueSamples were received on ice. TrueCooler Temperature is acceptable. TrueCooler Temperature is recorded. TrueCOC is present. TrueCOC is filled out in ink and legible. TrueCOC is filled out with all pertinent information. TrueIs the Field Sampler's name present on COC? TrueThere are no discrepancies between the containers received and the COC. TrueSamples are received within Holding Time (excluding tests with immediate HTs) TrueSample containers have legible labels. TrueContainers are not broken or leaking. TrueSample collection date/times are provided. TrueAppropriate sample containers are used. TrueSample bottles are completely filled. N/ASample Preservation Verified. TrueThere is sufficient vol. for all requested analyses, incl. any requested MS/MSDs N/AContainers requiring zero headspace have no headspace or bubble is <6mm (1/4"). TrueMultiphasic samples are not present. TrueSamples do not require splitting or compositing. N/AResidual Chlorine Checked. Eurofins Raleigh Page 122 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Login Sample Receipt Checklist Client: Carlson Environmental Consultants Job Number: 752-23756-1 Login Number: 23869 Question Answer Comment Creator: Yonish, Rachel List Source: Eurofins Raleigh List Number: 1 TrueRadioactivity wasn't checked or is </= background as measured by a survey meter. TrueThe cooler's custody seal, if present, is intact. TrueSample custody seals, if present, are intact. TrueThe cooler or samples do not appear to have been compromised or tampered with. TrueSamples were received on ice. TrueCooler Temperature is acceptable. TrueCooler Temperature is recorded. TrueCOC is present. TrueCOC is filled out in ink and legible. TrueCOC is filled out with all pertinent information. TrueIs the Field Sampler's name present on COC? TrueThere are no discrepancies between the containers received and the COC. TrueSamples are received within Holding Time (excluding tests with immediate HTs) TrueSample containers have legible labels. TrueContainers are not broken or leaking. TrueSample collection date/times are provided. TrueAppropriate sample containers are used. TrueSample bottles are completely filled. TrueSample Preservation Verified. TrueThere is sufficient vol. for all requested analyses, incl. any requested MS/MSDs TrueContainers requiring zero headspace have no headspace or bubble is <6mm (1/4"). TrueMultiphasic samples are not present. TrueSamples do not require splitting or compositing. TrueResidual Chlorine Checked. Eurofins Raleigh Page 123 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Login Sample Receipt Checklist Client: Carlson Environmental Consultants Job Number: 752-23756-1 Login Number: 23869 Question Answer Comment Creator: Lincoln, Alyssa List Source: Eurofins Savannah List Creation: 09/07/24 12:23 PMList Number: 2 N/ARadioactivity wasn't checked or is </= background as measured by a survey meter. TrueThe cooler's custody seal, if present, is intact. TrueSample custody seals, if present, are intact. TrueThe cooler or samples do not appear to have been compromised or tampered with. TrueSamples were received on ice. TrueCooler Temperature is acceptable. TrueCooler Temperature is recorded. TrueCOC is present. TrueCOC is filled out in ink and legible. TrueCOC is filled out with all pertinent information. TrueIs the Field Sampler's name present on COC? TrueThere are no discrepancies between the containers received and the COC. TrueSamples are received within Holding Time (excluding tests with immediate HTs) TrueSample containers have legible labels. TrueContainers are not broken or leaking. TrueSample collection date/times are provided. TrueAppropriate sample containers are used. TrueSample bottles are completely filled. N/ASample Preservation Verified. TrueThere is sufficient vol. for all requested analyses, incl. any requested MS/MSDs N/AContainers requiring zero headspace have no headspace or bubble is <6mm (1/4"). TrueMultiphasic samples are not present. TrueSamples do not require splitting or compositing. N/AResidual Chlorine Checked. Eurofins Raleigh Page 124 of 124 10/11/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 ANALYTICAL REPORT PREPARED FOR Attn: Michele Clary Carlson Environmental Consultants 5400 Glen Alden Drive Richmond, Virginia 23231 Generated 10/31/2024 11:55:55 PM JOB DESCRIPTION C&D Landfill (formerly Gold Hill LF) JOB NUMBER 752-25266-1 See page two for job notes and contact information. Cary NC 27511 Suite A 104 Woodwinds Industrial Court Eurofins Raleigh Page 1 of 28 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Eurofins Raleigh Eurofins Raleigh is a laboratory within Eurofins Environment Testing Southeast, LLC, a company within Eurofins Environment Testing Group of Companies Job Notes This report may not be reproduced except in full, and with written approval from the laboratory. The results relate only to the samples tested. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written approval of the laboratory. All questions should be directed to the Eurofins Environment Testing Southeast, LLC Project Manager. Authorization Generated 10/31/2024 11:55:55 PM Authorized for release by Noel Savoie, Project Manager I Noel.Savoie@et.eurofinsus.com (850)254-0107 Page 2 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Table of Contents Client: Carlson Environmental Consultants Project/Site: C&D Landfill (formerly Gold Hill LF) Laboratory Job ID: 752-25266-1 Page 3 of 28 Eurofins Raleigh10/31/2024 Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1 Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3 Definitions/Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4 Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5 Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6 Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7 Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .9 QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .10 QC Association Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .20 Lab Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .22 Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .23 Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .24 Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .25 Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .26 Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .27 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Definitions/Glossary Job ID: 752-25266-1Client: Carlson Environmental Consultants Project/Site: C&D Landfill (formerly Gold Hill LF) Qualifiers GC/MS VOA Qualifier Description J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value. Qualifier General Chemistry Qualifier Description *1 LCS/LCSD RPD exceeds control limits. Qualifier F2 MS/MSD RPD exceeds control limits J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value. Glossary These commonly used abbreviations may or may not be present in this report. ☼Listed under the "D" column to designate that the result is reported on a dry weight basis Abbreviation %R Percent Recovery CFL Contains Free Liquid CFU Colony Forming Unit CNF Contains No Free Liquid DER Duplicate Error Ratio (normalized absolute difference) Dil Fac Dilution Factor DL Detection Limit (DoD/DOE) DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample DLC Decision Level Concentration (Radiochemistry) EDL Estimated Detection Limit (Dioxin) LOD Limit of Detection (DoD/DOE) LOQ Limit of Quantitation (DoD/DOE) MCL EPA recommended "Maximum Contaminant Level" MDA Minimum Detectable Activity (Radiochemistry) MDC Minimum Detectable Concentration (Radiochemistry) MDL Method Detection Limit ML Minimum Level (Dioxin) MPN Most Probable Number MQL Method Quantitation Limit NC Not Calculated ND Not Detected at the reporting limit (or MDL or EDL if shown) NEG Negative / Absent POS Positive / Present PQL Practical Quantitation Limit PRES Presumptive QC Quality Control RER Relative Error Ratio (Radiochemistry) RL Reporting Limit or Requested Limit (Radiochemistry) RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin) TEQ Toxicity Equivalent Quotient (Dioxin) TNTC Too Numerous To Count Eurofins Raleigh Page 4 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Job Narrative752-25266-1 Analytical test results meet all requirements of the associated regulatory program listed on the Accreditation/Certification SummaryPageunlessotherwisenotedundertheindividualanalysis.Data qualifiers and/or narrative comments are included to explain any exceptions,if applicable. Matrix QC may not be reported if insufficient sample is provided or site-specific QC samples were not submitted.In these situations,to demonstrate precision and accuracy at a batch level,a LCS/LCSD may be performed,unless otherwise specified in the method.Surrogate and/or isotope dilution analyte recoveries (if applicable)which are outside of the QC window are confirmed unless attributed to a dilution or otherwise noted in the narrative. Regulated compliance samples (e.g.SDWA,NPDES)must comply with the associated agency requirements/permits. Receipt The sample was received on 10/16/2024 10:30 AM.Unless otherwise noted below,the sample arrived in good condition,and, where required,properly preserved and on ice.The temperature of the cooler at receipt time was 3.0°C. GC/MS VOA No additional analytical or quality issues were noted,other than those described above or in the Definitions/Glossary page. HPLC/IC No additional analytical or quality issues were noted,other than those described above or in the Definitions/Glossary page. General Chemistry Method SM4500_NO3_F:The matrix spike /matrix spike duplicate (MS/MSD)recoveries and precision for analytical batch 752-9370 were outside control limits.Sample matrix interference and/or non-homogeneity are suspected because the associated laboratory control sample /laboratory sample control duplicate (LCS/LCSD)precision was within acceptance limits. No additional analytical or quality issues were noted,other than those described above or in the Definitions/Glossary page. Case Narrative Client: Carlson Environmental Consultants Job ID: 752-25266-1 Project: C&D Landfill (formerly Gold Hill LF) Eurofins Raleigh Job ID: 752-25266-1 Eurofins Raleigh Page 5 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Detection Summary Job ID: 752-25266-1Client: Carlson Environmental Consultants Project/Site: C&D Landfill (formerly Gold Hill LF) Client Sample ID: MW-1 Lab Sample ID: 752-25266-1 Chloride RL 0.50 mg/L MDL 0.20 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Total/NA111300.0-1993 R2.1 Sulfate 1.0 mg/L0.40 Total/NA14.5 300.0-1993 R2.1 Alkalinity as CaCO3 to pH 4.5 5.5 mg/L2.2 Total/NA11402320B-2011 Nitrate as N 0.10 mg/L0.025 Total/NA10.041 J Nitrate by calc Nitrate Nitrite as N 0.10 mg/L0.041 Total/NA10.041 J F2 SM 4500 NO3 F Eurofins Raleigh This Detection Summary does not include radiochemical test results. Page 6 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-25266-1Client: Carlson Environmental Consultants Project/Site: C&D Landfill (formerly Gold Hill LF) Lab Sample ID: 752-25266-1Client Sample ID: MW-1 Matrix: WaterDate Collected: 10/15/24 09:44 Date Received: 10/16/24 10:30 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) RL MDL <0.32 0.50 0.32 ug/L 10/17/24 20:05 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,4-Dioxane 4-Bromofluorobenzene (Surr)87 46-154 10/17/24 20:05 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Method: SW846 8260D - Volatile Organic Compounds by GC/MS RL MDL <0.17 1.0 0.17 ug/L 10/17/24 23:03 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1,1,1,2-Tetrachloroethane 1.0 0.12 ug/L 10/17/24 23:03 1<0.121,1,1-Trichloroethane 1.0 0.28 ug/L 10/17/24 23:03 1<0.281,1,2,2-Tetrachloroethane 1.0 0.14 ug/L 10/17/24 23:03 1<0.141,1,2-Trichloroethane 1.0 0.13 ug/L 10/17/24 23:03 1<0.131,1-Dichloroethane 1.0 0.21 ug/L 10/17/24 23:03 1<0.211,1-Dichloroethene 1.0 0.15 ug/L 10/17/24 23:03 1<0.151,1-Dichloropropene 1.0 0.49 ug/L 10/17/24 23:03 1<0.491,2,3-Trichloropropane 1.0 0.14 ug/L 10/17/24 23:03 1<0.141,2,4-Trichlorobenzene 1.0 0.48 ug/L 10/17/24 23:03 1<0.481,2-Dibromo-3-Chloropropane 1.0 0.66 ug/L 10/17/24 23:03 1<0.661,2-Dibromoethane 1.0 0.19 ug/L 10/17/24 23:03 1<0.191,2-Dichlorobenzene 1.0 0.21 ug/L 10/17/24 23:03 1<0.211,2-Dichloroethane 1.0 0.10 ug/L 10/17/24 23:03 1<0.101,2-Dichloropropane 1.0 0.15 ug/L 10/17/24 23:03 1<0.151,3-Dichlorobenzene 1.0 0.16 ug/L 10/17/24 23:03 1<0.161,3-Dichloropropane 1.0 0.19 ug/L 10/17/24 23:03 1<0.191,4-Dichlorobenzene 1.0 0.28 ug/L 10/17/24 23:03 1<0.282,2-Dichloropropane 20 10 ug/L 10/17/24 23:03 1<102-Butanone (MEK) 5.0 0.88 ug/L 10/17/24 23:03 1<0.882-Hexanone 1.0 0.11 ug/L 10/17/24 23:03 1<0.113-Chloropropene 5.0 1.1 ug/L 10/17/24 23:03 1<1.14-Methyl-2-pentanone (MIBK) 20 10 ug/L 10/17/24 23:03 1<10Acetone 10 5.0 ug/L 10/17/24 23:03 1<5.0Acetonitrile 10 4.0 ug/L 10/17/24 23:03 1<4.0Acrolein 10 3.5 ug/L 10/17/24 23:03 1<3.5Acrylonitrile 1.0 0.15 ug/L 10/17/24 23:03 1<0.15Benzene 1.0 0.48 ug/L 10/17/24 23:03 1<0.48Bromochloromethane 1.0 0.17 ug/L 10/17/24 23:03 1<0.17Bromodichloromethane 1.0 0.22 ug/L 10/17/24 23:03 1<0.22Bromoform 1.0 0.14 ug/L 10/17/24 23:03 1<0.14Bromomethane 5.0 1.5 ug/L 10/17/24 23:03 1<1.5Carbon disulfide 1.0 0.17 ug/L 10/17/24 23:03 1<0.17Carbon tetrachloride 1.0 0.17 ug/L 10/17/24 23:03 1<0.17Chlorobenzene 1.0 0.23 ug/L 10/17/24 23:03 1<0.23Chloroethane 1.0 0.18 ug/L 10/17/24 23:03 1<0.18Chloroform 1.0 0.13 ug/L 10/17/24 23:03 1<0.13Chloromethane 1.0 0.64 ug/L 10/17/24 23:03 1<0.64Chloroprene 1.0 0.15 ug/L 10/17/24 23:03 1<0.15cis-1,2-Dichloroethene 1.0 0.20 ug/L 10/17/24 23:03 1<0.20cis-1,3-Dichloropropene 1.0 0.17 ug/L 10/17/24 23:03 1<0.17Dibromochloromethane 1.0 0.27 ug/L 10/17/24 23:03 1<0.27Dibromomethane 1.0 0.20 ug/L 10/17/24 23:03 1<0.20Dichlorodifluoromethane Eurofins Raleigh Page 7 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Client Sample Results Job ID: 752-25266-1Client: Carlson Environmental Consultants Project/Site: C&D Landfill (formerly Gold Hill LF) Lab Sample ID: 752-25266-1Client Sample ID: MW-1 Matrix: WaterDate Collected: 10/15/24 09:44 Date Received: 10/16/24 10:30 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) RL MDL <0.38 1.0 0.38 ug/L 10/17/24 23:03 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Ethyl methacrylate 1.0 0.13 ug/L 10/17/24 23:03 1<0.13Ethylbenzene 1.0 0.22 ug/L 10/17/24 23:03 1<0.22Hexachlorobutadiene 5.0 1.7 ug/L 10/17/24 23:03 1<1.7Iodomethane 50 11 ug/L 10/17/24 23:03 1<11Isobutyl alcohol 10 4.9 ug/L 10/17/24 23:03 1<4.9Methacrylonitrile 1.0 0.51 ug/L 10/17/24 23:03 1<0.51Methyl methacrylate 1.0 0.23 ug/L 10/17/24 23:03 1<0.23Methylene Chloride 1.0 0.11 ug/L 10/17/24 23:03 1<0.11Naphthalene 10 5.0 ug/L 10/17/24 23:03 1<5.0Propionitrile 1.0 0.11 ug/L 10/17/24 23:03 1<0.11Styrene 1.0 0.17 ug/L 10/17/24 23:03 1<0.17Tetrachloroethene 1.0 0.53 ug/L 10/17/24 23:03 1<0.53Tetrahydrofuran 1.0 0.14 ug/L 10/17/24 23:03 1<0.14Toluene 1.0 0.21 ug/L 10/17/24 23:03 1<0.21trans-1,2-Dichloroethene 1.0 0.15 ug/L 10/17/24 23:03 1<0.15trans-1,3-Dichloropropene 1.0 0.70 ug/L 10/17/24 23:03 1<0.70trans-1,4-Dichloro-2-butene 1.0 0.15 ug/L 10/17/24 23:03 1<0.15Trichloroethene 1.0 0.24 ug/L 10/17/24 23:03 1<0.24Trichlorofluoromethane 5.0 0.95 ug/L 10/17/24 23:03 1<0.95Vinyl acetate 1.0 0.32 ug/L 10/17/24 23:03 1<0.32Vinyl chloride 3.0 0.45 ug/L 10/17/24 23:03 1<0.45Xylenes, Total 4-Bromofluorobenzene (Surr)107 53-136 10/17/24 23:03 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Dibromofluoromethane (Surr)110 10/17/24 23:03 167-129 Toluene-d8 (Surr)111 10/17/24 23:03 159-134 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography RL MDL 11 0.50 0.20 mg/L 10/25/24 18:41 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Chloride 1.0 0.40 mg/L 10/25/24 18:41 14.5Sulfate General Chemistry RL MDL 140 5.5 2.2 mg/L 10/18/24 21:05 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier Alkalinity as CaCO3 to pH 4.5 (SM 2320B-2011) 0.10 0.025 mg/L 10/25/24 09:56 10.041 JNitrate as N (SM Nitrate by calc) 0.10 0.041 mg/L 10/28/24 17:39 10.041 J F2Nitrate Nitrite as N (SM 4500 NO3 F) 0.10 0.017 mg/L 10/16/24 15:47 1<0.017Nitrite as N (SM4500 NO2 F) Eurofins Raleigh Page 8 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Surrogate Summary Job ID: 752-25266-1Client: Carlson Environmental Consultants Project/Site: C&D Landfill (formerly Gold Hill LF) Method: 8260D - Volatile Organic Compounds by GC/MS Prep Type: Total/NAMatrix: Water Lab Sample ID Client Sample ID (53-136)(67-129)(59-134) BFB DBFM TOL 107 110 111752-25266-1 Percent Surrogate Recovery (Acceptance Limits) MW-1 106 107 110LCS 752-9224/4 Lab Control Sample 106 108 111LCSD 752-9224/5 Lab Control Sample Dup 107 108 110MB 752-9224/9 Method Blank 108 110 111MRL 752-9224/6 Lab Control Sample Surrogate Legend BFB = 4-Bromofluorobenzene (Surr) DBFM = Dibromofluoromethane (Surr) TOL = Toluene-d8 (Surr) Method: 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Prep Type: Total/NAMatrix: Water Lab Sample ID Client Sample ID (46-154) BFB 87752-25266-1 Percent Surrogate Recovery (Acceptance Limits) MW-1 99LCS 680-860017/3 Lab Control Sample 111LCSD 680-860017/4 Lab Control Sample Dup 110MB 680-860017/5 Method Blank Surrogate Legend BFB = 4-Bromofluorobenzene (Surr) Eurofins Raleigh Page 9 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-25266-1Client: Carlson Environmental Consultants Project/Site: C&D Landfill (formerly Gold Hill LF) Method: 8260D - Volatile Organic Compounds by GC/MS Client Sample ID: Method BlankLab Sample ID: MB 752-9224/9 Matrix: Water Prep Type: Total/NA Analysis Batch: 9224 RL MDL 1,1,1,2-Tetrachloroethane <0.17 1.0 0.17 ug/L 10/17/24 16:12 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier <0.12 0.121.0 ug/L 10/17/24 16:12 11,1,1-Trichloroethane <0.28 0.281.0 ug/L 10/17/24 16:12 11,1,2,2-Tetrachloroethane <0.14 0.141.0 ug/L 10/17/24 16:12 11,1,2-Trichloroethane <0.13 0.131.0 ug/L 10/17/24 16:12 11,1-Dichloroethane <0.21 0.211.0 ug/L 10/17/24 16:12 11,1-Dichloroethene <0.15 0.151.0 ug/L 10/17/24 16:12 11,1-Dichloropropene <0.49 0.491.0 ug/L 10/17/24 16:12 11,2,3-Trichloropropane <0.14 0.141.0 ug/L 10/17/24 16:12 11,2,4-Trichlorobenzene <0.48 0.481.0 ug/L 10/17/24 16:12 11,2-Dibromo-3-Chloropropane <0.66 0.661.0 ug/L 10/17/24 16:12 11,2-Dibromoethane <0.19 0.191.0 ug/L 10/17/24 16:12 11,2-Dichlorobenzene <0.21 0.211.0 ug/L 10/17/24 16:12 11,2-Dichloroethane <0.10 0.101.0 ug/L 10/17/24 16:12 11,2-Dichloropropane <0.15 0.151.0 ug/L 10/17/24 16:12 11,3-Dichlorobenzene <0.16 0.161.0 ug/L 10/17/24 16:12 11,3-Dichloropropane <0.19 0.191.0 ug/L 10/17/24 16:12 11,4-Dichlorobenzene <0.28 0.281.0 ug/L 10/17/24 16:12 12,2-Dichloropropane <10 1020 ug/L 10/17/24 16:12 12-Butanone (MEK) <0.88 0.885.0 ug/L 10/17/24 16:12 12-Hexanone <0.11 0.111.0 ug/L 10/17/24 16:12 13-Chloropropene <1.1 1.15.0 ug/L 10/17/24 16:12 14-Methyl-2-pentanone (MIBK) <10 1020 ug/L 10/17/24 16:12 1Acetone <5.0 5.010 ug/L 10/17/24 16:12 1Acetonitrile <4.0 4.010 ug/L 10/17/24 16:12 1Acrolein <3.5 3.510 ug/L 10/17/24 16:12 1Acrylonitrile <0.15 0.151.0 ug/L 10/17/24 16:12 1Benzene <0.48 0.481.0 ug/L 10/17/24 16:12 1Bromochloromethane <0.17 0.171.0 ug/L 10/17/24 16:12 1Bromodichloromethane <0.22 0.221.0 ug/L 10/17/24 16:12 1Bromoform <0.14 0.141.0 ug/L 10/17/24 16:12 1Bromomethane <1.5 1.55.0 ug/L 10/17/24 16:12 1Carbon disulfide <0.17 0.171.0 ug/L 10/17/24 16:12 1Carbon tetrachloride <0.17 0.171.0 ug/L 10/17/24 16:12 1Chlorobenzene <0.23 0.231.0 ug/L 10/17/24 16:12 1Chloroethane <0.18 0.181.0 ug/L 10/17/24 16:12 1Chloroform <0.13 0.131.0 ug/L 10/17/24 16:12 1Chloromethane <0.64 0.641.0 ug/L 10/17/24 16:12 1Chloroprene <0.15 0.151.0 ug/L 10/17/24 16:12 1cis-1,2-Dichloroethene <0.20 0.201.0 ug/L 10/17/24 16:12 1cis-1,3-Dichloropropene <0.17 0.171.0 ug/L 10/17/24 16:12 1Dibromochloromethane <0.27 0.271.0 ug/L 10/17/24 16:12 1Dibromomethane <0.20 0.201.0 ug/L 10/17/24 16:12 1Dichlorodifluoromethane <0.38 0.381.0 ug/L 10/17/24 16:12 1Ethyl methacrylate <0.13 0.131.0 ug/L 10/17/24 16:12 1Ethylbenzene <0.22 0.221.0 ug/L 10/17/24 16:12 1Hexachlorobutadiene <1.7 1.75.0 ug/L 10/17/24 16:12 1Iodomethane <11 1150 ug/L 10/17/24 16:12 1Isobutyl alcohol Eurofins Raleigh Page 10 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-25266-1Client: Carlson Environmental Consultants Project/Site: C&D Landfill (formerly Gold Hill LF) Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Method BlankLab Sample ID: MB 752-9224/9 Matrix: Water Prep Type: Total/NA Analysis Batch: 9224 RL MDL Methacrylonitrile <4.9 10 4.9 ug/L 10/17/24 16:12 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier <0.51 0.511.0 ug/L 10/17/24 16:12 1Methyl methacrylate <0.23 0.231.0 ug/L 10/17/24 16:12 1Methylene Chloride <0.11 0.111.0 ug/L 10/17/24 16:12 1Naphthalene <5.0 5.010 ug/L 10/17/24 16:12 1Propionitrile <0.11 0.111.0 ug/L 10/17/24 16:12 1Styrene <0.17 0.171.0 ug/L 10/17/24 16:12 1Tetrachloroethene <0.53 0.531.0 ug/L 10/17/24 16:12 1Tetrahydrofuran <0.14 0.141.0 ug/L 10/17/24 16:12 1Toluene <0.21 0.211.0 ug/L 10/17/24 16:12 1trans-1,2-Dichloroethene <0.15 0.151.0 ug/L 10/17/24 16:12 1trans-1,3-Dichloropropene <0.70 0.701.0 ug/L 10/17/24 16:12 1trans-1,4-Dichloro-2-butene <0.15 0.151.0 ug/L 10/17/24 16:12 1Trichloroethene <0.24 0.241.0 ug/L 10/17/24 16:12 1Trichlorofluoromethane <0.95 0.955.0 ug/L 10/17/24 16:12 1Vinyl acetate <0.32 0.321.0 ug/L 10/17/24 16:12 1Vinyl chloride <0.45 0.453.0 ug/L 10/17/24 16:12 1Xylenes, Total 4-Bromofluorobenzene (Surr)107 53-136 10/17/24 16:12 1 MB MB Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery 108 10/17/24 16:12 1Dibromofluoromethane (Surr)67-129 110 10/17/24 16:12 1Toluene-d8 (Surr)59-134 Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-9224/4 Matrix: Water Prep Type: Total/NA Analysis Batch: 9224 1,1,1,2-Tetrachloroethane 20.0 20.0 ug/L 100 71 -120 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits 1,1,1-Trichloroethane 20.0 22.0 ug/L 110 72 -143 1,1,2,2-Tetrachloroethane 20.0 18.9 ug/L 94 59 -133 1,1,2-Trichloroethane 20.0 20.4 ug/L 102 67 -120 1,1-Dichloroethane 20.0 22.6 ug/L 113 79 -141 1,1-Dichloroethene 20.0 24.4 ug/L 122 75 -133 1,1-Dichloropropene 20.0 23.9 ug/L 119 70 -129 1,2,3-Trichloropropane 20.0 19.3 ug/L 97 69 -127 1,2,4-Trichlorobenzene 20.0 19.2 ug/L 96 59 -122 1,2-Dibromo-3-Chloropropane 20.0 18.8 ug/L 94 37 -157 1,2-Dibromoethane 20.0 19.4 ug/L 97 66 -123 1,2-Dichlorobenzene 20.0 20.5 ug/L 103 76 -120 1,2-Dichloroethane 20.0 19.7 ug/L 99 72 -151 1,2-Dichloropropane 20.0 20.4 ug/L 102 78 -125 1,3-Dichlorobenzene 20.0 20.9 ug/L 105 76 -120 1,3-Dichloropropane 20.0 18.9 ug/L 95 60 -129 1,4-Dichlorobenzene 20.0 19.8 ug/L 99 76 -122 2,2-Dichloropropane 20.0 22.5 ug/L 113 21 -167 2-Butanone (MEK)40.0 40.8 ug/L 102 36 -135 2-Hexanone 40.0 36.9 ug/L 92 36 -191 Eurofins Raleigh Page 11 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-25266-1Client: Carlson Environmental Consultants Project/Site: C&D Landfill (formerly Gold Hill LF) Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-9224/4 Matrix: Water Prep Type: Total/NA Analysis Batch: 9224 3-Chloropropene 20.0 22.3 ug/L 111 17 -147 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits 4-Methyl-2-pentanone (MIBK)40.0 39.2 ug/L 98 56 -166 Acetone 40.0 37.6 ug/L 94 10 -158 Acetonitrile 20.0 21.3 ug/L 107 10 -200 Acrolein 40.0 16.3 ug/L 41 10 -200 Acrylonitrile 60.0 47.8 ug/L 80 10 -200 Benzene 20.0 21.2 ug/L 106 80 -134 Bromochloromethane 20.0 22.3 ug/L 112 74 -128 Bromodichloromethane 20.0 19.7 ug/L 98 72 -129 Bromoform 20.0 20.1 ug/L 100 73 -120 Bromomethane 20.0 21.2 ug/L 106 38 -189 Carbon disulfide 20.0 32.2 ug/L 161 65 -173 Carbon tetrachloride 20.0 19.8 ug/L 99 68 -142 Chlorobenzene 20.0 20.6 ug/L 103 80 -120 Chloroethane 20.0 22.2 ug/L 111 45 -213 Chloroform 20.0 22.8 ug/L 114 78 -138 Chloromethane 20.0 21.3 ug/L 107 56 -171 Chloroprene 20.0 24.3 ug/L 122 33 -148 cis-1,2-Dichloroethene 20.0 23.8 ug/L 119 69 -120 cis-1,3-Dichloropropene 20.0 21.5 ug/L 108 63 -125 Dibromochloromethane 20.0 18.6 ug/L 93 73 -120 Dibromomethane 20.0 20.0 ug/L 100 76 -124 Dichlorodifluoromethane 20.0 22.2 ug/L 111 25 -161 Ethyl methacrylate 20.0 19.4 ug/L 97 51 -120 Ethylbenzene 20.0 21.8 ug/L 109 68 -124 Hexachlorobutadiene 20.0 21.5 ug/L 107 63 -120 Iodomethane 20.0 23.5 ug/L 118 34 -140 Isobutyl alcohol 20.0 22.9 J ug/L 115 10 -200 Methacrylonitrile 20.0 22.0 ug/L 110 10 -200 Methyl methacrylate 20.0 21.2 ug/L 106 48 -126 Methylene Chloride 20.0 22.1 ug/L 111 68 -128 Naphthalene 20.0 20.8 ug/L 104 50 -127 Styrene 20.0 19.9 ug/L 100 73 -120 Tetrachloroethene 20.0 20.8 ug/L 104 40 -181 Tetrahydrofuran 20.0 23.9 ug/L 119 0-200 Toluene 20.0 20.2 ug/L 101 71 -120 trans-1,2-Dichloroethene 20.0 22.3 ug/L 111 75 -139 trans-1,3-Dichloropropene 20.0 21.5 ug/L 108 65 -152 trans-1,4-Dichloro-2-butene 20.0 18.0 ug/L 90 10 -142 Trichloroethene 20.0 20.4 ug/L 102 74 -120 Trichlorofluoromethane 20.0 28.9 ug/L 145 68 -183 Vinyl acetate 20.0 24.5 ug/L 123 10 -198 Vinyl chloride 20.0 24.8 ug/L 124 49 -150 Xylenes, Total 60.0 62.5 ug/L 104 77 -121 4-Bromofluorobenzene (Surr)53 -136 Surrogate 106 LCS LCS Qualifier Limits%Recovery 107Dibromofluoromethane (Surr)67 -129 Eurofins Raleigh Page 12 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-25266-1Client: Carlson Environmental Consultants Project/Site: C&D Landfill (formerly Gold Hill LF) Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-9224/4 Matrix: Water Prep Type: Total/NA Analysis Batch: 9224 Toluene-d8 (Surr)59 -134 Surrogate 110 LCS LCS Qualifier Limits%Recovery Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-9224/5 Matrix: Water Prep Type: Total/NA Analysis Batch: 9224 1,1,1,2-Tetrachloroethane 20.0 19.7 ug/L 99 71 -120 2 16 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD 1,1,1-Trichloroethane 20.0 21.7 ug/L 108 72 -143 1 18 1,1,2,2-Tetrachloroethane 20.0 18.9 ug/L 94 59 -133 0 16 1,1,2-Trichloroethane 20.0 20.5 ug/L 103 67 -120 1 18 1,1-Dichloroethane 20.0 22.0 ug/L 110 79 -141 3 19 1,1-Dichloroethene 20.0 23.4 ug/L 117 75 -133 4 20 1,1-Dichloropropene 20.0 23.4 ug/L 117 70 -129 2 17 1,2,3-Trichloropropane 20.0 20.0 ug/L 100 69 -127 3 17 1,2,4-Trichlorobenzene 20.0 19.6 ug/L 98 59 -122 2 17 1,2-Dibromo-3-Chloropropane 20.0 19.2 ug/L 96 37 -157 2 18 1,2-Dibromoethane 20.0 19.3 ug/L 97 66 -123 0 15 1,2-Dichlorobenzene 20.0 20.0 ug/L 100 76 -120 3 16 1,2-Dichloroethane 20.0 19.7 ug/L 99 72 -151 0 16 1,2-Dichloropropane 20.0 20.0 ug/L 100 78 -125 2 19 1,3-Dichlorobenzene 20.0 20.6 ug/L 103 76 -120 2 17 1,3-Dichloropropane 20.0 19.0 ug/L 95 60 -129 0 16 1,4-Dichlorobenzene 20.0 19.3 ug/L 96 76 -122 3 16 2,2-Dichloropropane 20.0 21.8 ug/L 109 21 -167 3 20 2-Butanone (MEK)40.0 41.4 ug/L 104 36 -135 2 19 2-Hexanone 40.0 38.3 ug/L 96 36 -191 4 17 3-Chloropropene 20.0 23.2 ug/L 116 17 -147 4 19 4-Methyl-2-pentanone (MIBK)40.0 42.9 ug/L 107 56 -166 9 19 Acetone 40.0 40.3 ug/L 101 10 -158 7 78 Acetonitrile 20.0 21.1 ug/L 105 10 -200 1 35 Acrolein 40.0 15.3 ug/L 38 10 -200 7 50 Acrylonitrile 60.0 47.9 ug/L 80 10 -200 0 36 Benzene 20.0 22.1 ug/L 111 80 -134 4 17 Bromochloromethane 20.0 22.2 ug/L 111 74 -128 0 18 Bromodichloromethane 20.0 19.8 ug/L 99 72 -129 1 16 Bromoform 20.0 20.2 ug/L 101 73 -120 0 44 Bromomethane 20.0 20.5 ug/L 103 38 -189 3 27 Carbon disulfide 20.0 31.0 ug/L 155 65 -173 4 38 Carbon tetrachloride 20.0 20.0 ug/L 100 68 -142 1 17 Chlorobenzene 20.0 20.3 ug/L 101 80 -120 1 16 Chloroethane 20.0 19.9 ug/L 99 45 -213 11 26 Chloroform 20.0 22.6 ug/L 113 78 -138 1 17 Chloromethane 20.0 20.1 ug/L 100 56 -171 6 28 Chloroprene 20.0 24.1 ug/L 120 33 -148 1 19 cis-1,2-Dichloroethene 20.0 23.1 ug/L 115 69 -120 3 18 cis-1,3-Dichloropropene 20.0 21.0 ug/L 105 63 -125 2 17 Dibromochloromethane 20.0 18.6 ug/L 93 73 -120 0 16 Eurofins Raleigh Page 13 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-25266-1Client: Carlson Environmental Consultants Project/Site: C&D Landfill (formerly Gold Hill LF) Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-9224/5 Matrix: Water Prep Type: Total/NA Analysis Batch: 9224 Dibromomethane 20.0 20.4 ug/L 102 76 -124 2 15 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Dichlorodifluoromethane 20.0 22.7 ug/L 114 25 -161 2 48 Ethyl methacrylate 20.0 19.4 ug/L 97 51 -120 0 24 Ethylbenzene 20.0 21.2 ug/L 106 68 -124 3 16 Hexachlorobutadiene 20.0 20.6 ug/L 103 63 -120 4 19 Iodomethane 20.0 23.7 ug/L 118 34 -140 1 15 Isobutyl alcohol 20.0 18.8 J ug/L 94 10 -200 20 20 Methacrylonitrile 20.0 21.3 ug/L 107 10 -200 3 50 Methyl methacrylate 20.0 21.8 ug/L 109 48 -126 3 50 Methylene Chloride 20.0 21.4 ug/L 107 68 -128 3 17 Naphthalene 20.0 20.9 ug/L 105 50 -127 1 19 Styrene 20.0 19.8 ug/L 99 73 -120 1 23 Tetrachloroethene 20.0 20.8 ug/L 104 40 -181 0 26 Tetrahydrofuran 20.0 25.1 ug/L 126 0-200 5 50 Toluene 20.0 19.7 ug/L 99 71 -120 2 17 trans-1,2-Dichloroethene 20.0 21.4 ug/L 107 75 -139 4 19 trans-1,3-Dichloropropene 20.0 20.9 ug/L 104 65 -152 3 16 trans-1,4-Dichloro-2-butene 20.0 18.4 ug/L 92 10 -142 2 28 Trichloroethene 20.0 20.5 ug/L 103 74 -120 0 22 Trichlorofluoromethane 20.0 26.4 ug/L 132 68 -183 9 22 Vinyl acetate 20.0 22.4 ug/L 112 10 -198 9 21 Vinyl chloride 20.0 24.6 ug/L 123 49 -150 1 27 Xylenes, Total 60.0 61.2 ug/L 102 77 -121 2 16 4-Bromofluorobenzene (Surr)53 -136 Surrogate 106 LCSD LCSD Qualifier Limits%Recovery 108Dibromofluoromethane (Surr)67 -129 111Toluene-d8 (Surr)59 -134 Client Sample ID: Lab Control SampleLab Sample ID: MRL 752-9224/6 Matrix: Water Prep Type: Total/NA Analysis Batch: 9224 1,1,1,2-Tetrachloroethane 1.00 1.19 ug/L 119 Analyte MRL MRL DUnitResultQualifier %Rec Spike Added %Rec Limits 1,1,1-Trichloroethane 1.00 1.34 ug/L 134 1,1,2,2-Tetrachloroethane 1.00 0.978 J ug/L 98 1,1,2-Trichloroethane 1.00 0.984 J ug/L 98 1,1-Dichloroethane 1.00 1.40 ug/L 140 1,1-Dichloroethene 1.00 1.31 ug/L 131 1,1-Dichloropropene 1.00 1.02 ug/L 102 1,2,3-Trichloropropane 1.00 1.18 ug/L 118 1,2,4-Trichlorobenzene 1.00 1.52 ug/L 152 1,2-Dibromo-3-Chloropropane 1.00 1.22 ug/L 122 1,2-Dibromoethane 1.00 0.954 J ug/L 95 1,2-Dichlorobenzene 1.00 1.27 ug/L 127 1,2-Dichloroethane 1.00 1.22 ug/L 122 1,2-Dichloropropane 1.00 1.23 ug/L 123 Eurofins Raleigh Page 14 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-25266-1Client: Carlson Environmental Consultants Project/Site: C&D Landfill (formerly Gold Hill LF) Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Lab Control SampleLab Sample ID: MRL 752-9224/6 Matrix: Water Prep Type: Total/NA Analysis Batch: 9224 1,3-Dichlorobenzene 1.00 1.25 ug/L 125 Analyte MRL MRL DUnitResultQualifier %Rec Spike Added %Rec Limits 1,3-Dichloropropane 1.00 1.15 ug/L 115 1,4-Dichlorobenzene 1.00 1.23 ug/L 123 2,2-Dichloropropane 1.00 1.14 ug/L 114 2-Butanone (MEK)2.00 <10 ug/L 130 2-Hexanone 2.00 2.09 J ug/L 104 3-Chloropropene 1.00 1.62 ug/L 162 4-Methyl-2-pentanone (MIBK)2.00 2.17 J ug/L 108 Acetone 2.00 <10 ug/L 103 Acetonitrile 10.0 19.3 ug/L 193 Acrolein 5.00 4.21 J ug/L 84 Acrylonitrile 5.00 3.63 J ug/L 73 Benzene 1.00 1.28 ug/L 128 Bromochloromethane 1.00 1.28 ug/L 128 Bromodichloromethane 1.00 1.32 ug/L 132 Bromoform 1.00 0.586 J ug/L 59 Bromomethane 1.00 2.34 ug/L 234 Carbon disulfide 2.00 2.71 J ug/L 136 Carbon tetrachloride 1.00 0.325 J ug/L 33 Chlorobenzene 1.00 1.26 ug/L 126 Chloroethane 1.00 5.80 ug/L 580 Chloroform 1.00 1.93 ug/L 193 Chloromethane 1.00 0.682 J ug/L 68 Chloroprene 1.00 1.10 ug/L 110 cis-1,2-Dichloroethene 1.00 1.45 ug/L 145 cis-1,3-Dichloropropene 1.00 1.20 ug/L 120 Dibromochloromethane 1.00 1.27 ug/L 127 Dibromomethane 1.00 1.17 ug/L 117 Dichlorodifluoromethane 1.00 1.67 ug/L 167 Ethyl methacrylate 1.00 1.00 ug/L 100 Ethylbenzene 1.00 1.19 ug/L 119 Hexachlorobutadiene 1.00 1.20 ug/L 120 Iodomethane 2.00 4.08 J ug/L 204 Isobutyl alcohol 20.0 14.1 J ug/L 70 Methacrylonitrile 10.0 10.6 ug/L 106 Methyl methacrylate 1.00 1.01 ug/L 101 Methylene Chloride 1.00 1.66 ug/L 166 Naphthalene 1.00 1.71 ug/L 171 Styrene 1.00 1.25 ug/L 125 Tetrachloroethene 1.00 0.984 J ug/L 98 Tetrahydrofuran 1.00 1.77 ug/L 177 Toluene 1.00 1.26 ug/L 126 trans-1,2-Dichloroethene 1.00 1.44 ug/L 144 trans-1,3-Dichloropropene 1.00 1.14 ug/L 114 trans-1,4-Dichloro-2-butene 1.00 1.25 ug/L 125 Trichloroethene 1.00 1.28 ug/L 128 Trichlorofluoromethane 1.00 1.94 ug/L 194 Vinyl acetate 2.00 2.90 J ug/L 145 Vinyl chloride 1.00 1.26 ug/L 126 Eurofins Raleigh Page 15 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-25266-1Client: Carlson Environmental Consultants Project/Site: C&D Landfill (formerly Gold Hill LF) Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: Lab Control SampleLab Sample ID: MRL 752-9224/6 Matrix: Water Prep Type: Total/NA Analysis Batch: 9224 Xylenes, Total 3.00 3.85 ug/L 128 Analyte MRL MRL DUnitResultQualifier %Rec Spike Added %Rec Limits 4-Bromofluorobenzene (Surr)53 -136 Surrogate 108 MRL MRL Qualifier Limits%Recovery 110Dibromofluoromethane (Surr)67 -129 111Toluene-d8 (Surr)59 -134 Method: 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Client Sample ID: Method BlankLab Sample ID: MB 680-860017/5 Matrix: Water Prep Type: Total/NA Analysis Batch: 860017 RL MDL 1,4-Dioxane <0.32 0.50 0.32 ug/L 10/17/24 19:04 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier 4-Bromofluorobenzene (Surr)110 46-154 10/17/24 19:04 1 MB MB Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-860017/3 Matrix: Water Prep Type: Total/NA Analysis Batch: 860017 1,4-Dioxane 5.00 4.76 ug/L 95 70 -130 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits 4-Bromofluorobenzene (Surr)46 -154 Surrogate 99 LCS LCS Qualifier Limits%Recovery Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 680-860017/4 Matrix: Water Prep Type: Total/NA Analysis Batch: 860017 1,4-Dioxane 5.00 4.57 ug/L 91 70 -130 4 30 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD 4-Bromofluorobenzene (Surr)46 -154 Surrogate 111 LCSD LCSD Qualifier Limits%Recovery Method: 300.0-1993 R2.1 - Anions, Ion Chromatography Client Sample ID: Method BlankLab Sample ID: MB 680-861569/57 Matrix: Water Prep Type: Total/NA Analysis Batch: 861569 RL MDL Chloride <0.20 0.50 0.20 mg/L 10/25/24 16:21 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier <0.40 0.401.0 mg/L 10/25/24 16:21 1Sulfate Eurofins Raleigh Page 16 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-25266-1Client: Carlson Environmental Consultants Project/Site: C&D Landfill (formerly Gold Hill LF) Method: 300.0-1993 R2.1 - Anions, Ion Chromatography (Continued) Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-861569/30 Matrix: Water Prep Type: Total/NA Analysis Batch: 861569 Chloride 10.0 9.61 mg/L 96 90 -110 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Sulfate 10.0 9.69 mg/L 97 90 -110 Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 680-861569/58 Matrix: Water Prep Type: Total/NA Analysis Batch: 861569 Chloride 10.0 9.66 mg/L 97 90 -110 0 15 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Sulfate 10.0 9.77 mg/L 98 90 -110 1 15 Method: 2320B-2011 - Alkalinity, Total Client Sample ID: Method BlankLab Sample ID: MB 680-860414/4 Matrix: Water Prep Type: Total/NA Analysis Batch: 860414 RL MDL Alkalinity as CaCO3 to pH 4.5 <2.2 5.5 2.2 mg/L 10/18/24 19:33 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-860414/6 Matrix: Water Prep Type: Total/NA Analysis Batch: 860414 Alkalinity as CaCO3 to pH 4.5 250 246 mg/L 98 90 -112 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 680-860414/31 Matrix: Water Prep Type: Total/NA Analysis Batch: 860414 Alkalinity as CaCO3 to pH 4.5 250 254 mg/L 102 90 -112 3 30 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Method: SM 4500 NO3 F - Nitrogen, Nitrate Client Sample ID: Method BlankLab Sample ID: MB 752-9370/75 Matrix: Water Prep Type: Total/NA Analysis Batch: 9370 RL MDL Nitrate Nitrite as N <0.041 0.10 0.041 mg/L 10/28/24 17:02 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Method BlankLab Sample ID: MB 752-9370/8 Matrix: Water Prep Type: Total/NA Analysis Batch: 9370 RL MDL Nitrate Nitrite as N <0.041 0.10 0.041 mg/L 10/28/24 11:09 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Eurofins Raleigh Page 17 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-25266-1Client: Carlson Environmental Consultants Project/Site: C&D Landfill (formerly Gold Hill LF) Method: SM 4500 NO3 F - Nitrogen, Nitrate (Continued) Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-9370/76 Matrix: Water Prep Type: Total/NA Analysis Batch: 9370 Nitrate Nitrite as N 1.25 1.17 mg/L 93 90 -110 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-9370/9 Matrix: Water Prep Type: Total/NA Analysis Batch: 9370 Nitrate Nitrite as N 1.25 1.30 mg/L 104 90 -110 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-9370/45 Matrix: Water Prep Type: Total/NA Analysis Batch: 9370 Nitrate Nitrite as N 1.25 1.17 *1 mg/L 94 90 -110 11 10 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Client Sample ID: MW-1Lab Sample ID: 752-25266-1 MS Matrix: Water Prep Type: Total/NA Analysis Batch: 9370 Nitrate Nitrite as N 0.041 J F2 0.521 0.504 mg/L 97 90 -110 Analyte MS MS DUnitResultQualifier %Rec Spike Added Sample Result Sample Qualifier %Rec Limits Client Sample ID: MW-1Lab Sample ID: 752-25266-1 MSD Matrix: Water Prep Type: Total/NA Analysis Batch: 9370 Nitrate Nitrite as N 0.041 J F2 0.521 0.566 F2 mg/L 109 90 -110 12 10 Analyte MSD MSD DUnitResultQualifier %Rec Spike Added Sample Result Sample Qualifier %Rec Limits LimitRPD RPD Method: SM4500 NO2 F - Nitrogen, Nitrite Client Sample ID: Method BlankLab Sample ID: MB 752-9229/22 Matrix: Water Prep Type: Total/NA Analysis Batch: 9229 RL MDL Nitrite as N <0.017 0.10 0.017 mg/L 10/16/24 15:49 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Client Sample ID: Method BlankLab Sample ID: MB 752-9229/8 Matrix: Water Prep Type: Total/NA Analysis Batch: 9229 RL MDL Nitrite as N <0.017 0.10 0.017 mg/L 10/16/24 15:35 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier Eurofins Raleigh Page 18 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Sample Results Job ID: 752-25266-1Client: Carlson Environmental Consultants Project/Site: C&D Landfill (formerly Gold Hill LF) Method: SM4500 NO2 F - Nitrogen, Nitrite (Continued) Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-9229/11 Matrix: Water Prep Type: Total/NA Analysis Batch: 9229 Nitrite as N 1.00 0.962 mg/L 96 90 -110 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec Limits Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-9229/36 Matrix: Water Prep Type: Total/NA Analysis Batch: 9229 Nitrite as N 1.00 0.974 mg/L 97 90 -110 1 10 Analyte LCSD LCSD DUnitResultQualifier %Rec Spike Added %Rec Limits LimitRPD RPD Eurofins Raleigh Page 19 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Association Summary Job ID: 752-25266-1Client: Carlson Environmental Consultants Project/Site: C&D Landfill (formerly Gold Hill LF) GC/MS VOA Analysis Batch: 9224 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 8260D752-25266-1 MW-1 Total/NA Water 8260DMB 752-9224/9 Method Blank Total/NA Water 8260DLCS 752-9224/4 Lab Control Sample Total/NA Water 8260DLCSD 752-9224/5 Lab Control Sample Dup Total/NA Water 8260DMRL 752-9224/6 Lab Control Sample Total/NA Analysis Batch: 860017 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 8260D SIM 14D752-25266-1 MW-1 Total/NA Water 8260D SIM 14DMB 680-860017/5 Method Blank Total/NA Water 8260D SIM 14DLCS 680-860017/3 Lab Control Sample Total/NA Water 8260D SIM 14DLCSD 680-860017/4 Lab Control Sample Dup Total/NA HPLC/IC Analysis Batch: 861569 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 300.0-1993 R2.1752-25266-1 MW-1 Total/NA Water 300.0-1993 R2.1MB 680-861569/57 Method Blank Total/NA Water 300.0-1993 R2.1LCS 680-861569/30 Lab Control Sample Total/NA Water 300.0-1993 R2.1LCSD 680-861569/58 Lab Control Sample Dup Total/NA General Chemistry Analysis Batch: 9229 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water SM4500 NO2 F752-25266-1 MW-1 Total/NA Water SM4500 NO2 FMB 752-9229/22 Method Blank Total/NA Water SM4500 NO2 FMB 752-9229/8 Method Blank Total/NA Water SM4500 NO2 FLCS 752-9229/11 Lab Control Sample Total/NA Water SM4500 NO2 FLCSD 752-9229/36 Lab Control Sample Dup Total/NA Analysis Batch: 9327 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water Nitrate by calc752-25266-1 MW-1 Total/NA Analysis Batch: 9370 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water SM 4500 NO3 F752-25266-1 MW-1 Total/NA Water SM 4500 NO3 FMB 752-9370/75 Method Blank Total/NA Water SM 4500 NO3 FMB 752-9370/8 Method Blank Total/NA Water SM 4500 NO3 FLCS 752-9370/76 Lab Control Sample Total/NA Water SM 4500 NO3 FLCS 752-9370/9 Lab Control Sample Total/NA Water SM 4500 NO3 FLCSD 752-9370/45 Lab Control Sample Dup Total/NA Water SM 4500 NO3 F752-25266-1 MS MW-1 Total/NA Water SM 4500 NO3 F752-25266-1 MSD MW-1 Total/NA Analysis Batch: 860414 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 2320B-2011752-25266-1 MW-1 Total/NA Water 2320B-2011MB 680-860414/4 Method Blank Total/NA Water 2320B-2011LCS 680-860414/6 Lab Control Sample Total/NA Eurofins Raleigh Page 20 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 QC Association Summary Job ID: 752-25266-1Client: Carlson Environmental Consultants Project/Site: C&D Landfill (formerly Gold Hill LF) General Chemistry (Continued) Analysis Batch: 860414 (Continued) Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 2320B-2011LCSD 680-860414/31 Lab Control Sample Dup Total/NA Eurofins Raleigh Page 21 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Lab Chronicle Client: Carlson Environmental Consultants Job ID: 752-25266-1 Project/Site: C&D Landfill (formerly Gold Hill LF) Client Sample ID: MW-1 Lab Sample ID: 752-25266-1 Matrix: WaterDate Collected: 10/15/24 09:44 Date Received: 10/16/24 10:30 Analysis 8260D NTA19224 EET RAL Type Batch Batch MethodPrep Type LabAnalystRun Prepared or Analyzed Batch Number Dilution Factor Total/NA 10/17/24 23:03 Analysis 8260D SIM 14D 1 860017 MJY EET SAVTotal/NA 10/17/24 20:05 Analysis 300.0-1993 R2.1 1 861569 BS EET SAVTotal/NA 10/25/24 18:41 Analysis 2320B-2011 1 860414 PG EET SAVTotal/NA 10/18/24 21:05 Analysis Nitrate by calc 1 9327 LEB EET RALTotal/NA 10/25/24 09:56 Analysis SM 4500 NO3 F 1 9370 ME EET RALTotal/NA 10/28/24 17:39 Analysis SM4500 NO2 F 1 9229 CB EET RALTotal/NA 10/16/24 15:47 Laboratory References: EET RAL = Eurofins Raleigh, 104 Woodwinds Industrial Court, Suite A, Cary, NC 27511, TEL (919)467-3090 EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL (912)354-7858 Eurofins Raleigh Page 22 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Accreditation/Certification Summary Client: Carlson Environmental Consultants Job ID: 752-25266-1 Project/Site: C&D Landfill (formerly Gold Hill LF) Laboratory: Eurofins Raleigh Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below. Authority Program Identification Number Expiration Date North Carolina (WW/SW)State 591 12-31-24 Laboratory: Eurofins Savannah The accreditations/certifications listed below are applicable to this report. Authority Program Identification Number Expiration Date North Carolina (WW/SW)State 269 12-31-24 Eurofins Raleigh Page 23 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Method Summary Job ID: 752-25266-1Client: Carlson Environmental Consultants Project/Site: C&D Landfill (formerly Gold Hill LF) Method Method Description LaboratoryProtocol SW8468260DVolatile Organic Compounds by GC/MS EET RAL SW8468260D SIM 14D Volatile Organic Compounds (GC/MS)EET SAV MCAWW300.0-1993 R2.1 Anions, Ion Chromatography EET SAV SM2320B-2011 Alkalinity, Total EET SAV SMNitrate by calc Nitrogen, Nitrate-Nitrite EET RAL SMSM 4500 NO3 F Nitrogen, Nitrate EET RAL SMSM4500 NO2 F Nitrogen, Nitrite EET RAL SW8465030CPurge and Trap EET RAL SW8465030CPurge and Trap EET SAV Protocol References: MCAWW = "Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And Subsequent Revisions. SM = "Standard Methods For The Examination Of Water And Wastewater" SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. Laboratory References: EET RAL = Eurofins Raleigh, 104 Woodwinds Industrial Court, Suite A, Cary, NC 27511, TEL (919)467-3090 EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL (912)354-7858 Eurofins Raleigh Page 24 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Sample Summary Client: Carlson Environmental Consultants Job ID: 752-25266-1 Project/Site: C&D Landfill (formerly Gold Hill LF) Lab Sample ID Client Sample ID Matrix Collected Received 752-25266-1 MW-1 Water 10/15/24 09:44 10/16/24 10:30 Eurofins RaleighPage 25 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Page 26 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Login Sample Receipt Checklist Client: Carlson Environmental Consultants Job Number: 752-25266-1 Login Number: 25266 Question Answer Comment Creator: Yonish, Rachel List Source: Eurofins Raleigh List Number: 1 TrueRadioactivity wasn't checked or is </= background as measured by a survey meter. TrueThe cooler's custody seal, if present, is intact. TrueSample custody seals, if present, are intact. TrueThe cooler or samples do not appear to have been compromised or tampered with. TrueSamples were received on ice. TrueCooler Temperature is acceptable. TrueCooler Temperature is recorded. TrueCOC is present. TrueCOC is filled out in ink and legible. TrueCOC is filled out with all pertinent information. TrueIs the Field Sampler's name present on COC? TrueThere are no discrepancies between the containers received and the COC. TrueSamples are received within Holding Time (excluding tests with immediate HTs) TrueSample containers have legible labels. TrueContainers are not broken or leaking. TrueSample collection date/times are provided. TrueAppropriate sample containers are used. TrueSample bottles are completely filled. TrueSample Preservation Verified. TrueThere is sufficient vol. for all requested analyses, incl. any requested MS/MSDs TrueContainers requiring zero headspace have no headspace or bubble is <6mm (1/4"). TrueMultiphasic samples are not present. TrueSamples do not require splitting or compositing. TrueResidual Chlorine Checked. Eurofins Raleigh Page 27 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Login Sample Receipt Checklist Client: Carlson Environmental Consultants Job Number: 752-25266-1 Login Number: 25266 Question Answer Comment Creator: Lincoln, Alyssa List Source: Eurofins Savannah List Creation: 10/17/24 03:22 PMList Number: 2 N/ARadioactivity wasn't checked or is </= background as measured by a survey meter. TrueThe cooler's custody seal, if present, is intact. TrueSample custody seals, if present, are intact. TrueThe cooler or samples do not appear to have been compromised or tampered with. TrueSamples were received on ice. TrueCooler Temperature is acceptable. TrueCooler Temperature is recorded. TrueCOC is present. TrueCOC is filled out in ink and legible. TrueCOC is filled out with all pertinent information. TrueIs the Field Sampler's name present on COC? TrueThere are no discrepancies between the containers received and the COC. TrueSamples are received within Holding Time (excluding tests with immediate HTs) TrueSample containers have legible labels. TrueContainers are not broken or leaking. TrueSample collection date/times are provided. TrueAppropriate sample containers are used. TrueSample bottles are completely filled. N/ASample Preservation Verified. TrueThere is sufficient vol. for all requested analyses, incl. any requested MS/MSDs N/AContainers requiring zero headspace have no headspace or bubble is <6mm (1/4"). TrueMultiphasic samples are not present. TrueSamples do not require splitting or compositing. N/AResidual Chlorine Checked. Eurofins Raleigh Page 28 of 28 10/31/2024 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15