RA-1391_8975_CA_RPTS_20221007_MRP

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]

October 7, 2022

Ms. Carrie Stone
NCDEQ, UST Section
Washington Regional Office
943 Washington Square Mall
Washington, North Carolina 27889

Re: Ground Water Monitoring Report September 2022
Rich Square Tire Center
413 East Jackson Street
Rich Square, Northampton County,
North Carolina
Incident Number: 8975
GRI Project Number: 3398

Dear Ms. Edwards,

Please find enclosed the referenced report for the above-mentioned site.

If you have any questions, please contact William Regenthal at 704.845.4010.

Sincerely,
Geological Resources, Inc.

Johanna Moats
AP/AR Coordinator

Enclosure

Cc. Mr. Wood Beasley, Beasley Enterprises, Inc., file

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Groundwater Monitoring Report
September 2022
Rich Square Tire Center
413 East Jackson Street
Rich Square, Northampton County
North Carolina
Facility ID Number: 00-0-0000030781
Incident Number: 8975
GRI Project Number: 3398

Prepared for:

North East Oil Company, Inc.
Post Office Box 1386
Ahoskie, North Carolina 27910

October 7, 2022

William Regenthal, P.G.
Project Manager
AJ Discepolo, G.I.T.
Staff Scientist

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Groundwater Monitoring Report
Prepared on: October 7, 2022 Rich Square Tire Center
Project Manager: William Regenthal, P.G. GRI Project No. 3398
i
SITE INFORMATION
1. Site Identification
 Rich Square Tire Center (Facility ID 00-0-0000030781)
 Incident Number 8975 – Intermediate Risk (I150D)
 Location of Source Area: 413 East Jackson Street
Rich Square, NC 28314
Northampton County
36.2719950°N, 77.2744100°W (Topographical Map)
2. Information about Contacts Associated with the Leaking UST System

UST Owner
North East Oil Company, Inc.
Post Office Box 1386
Ahoskie, NC 27910
[e-mail]
252-398-6022

UST Operator
North East Oil Company, Inc.
Post Office Box 1386
Ahoskie, NC 27910
[e-mail]
252-398-6022

Property Owner
James Thomas Boone
Post Office Box 149
Rich Square, NC 27869
Email Unknown
Phone No. Unknown

Property Occupant
Boone’s Tire Center
413 East Jackson Street
Rich Square, NC 28314
Email Unknown
252-539-2597

Consultant/Contractor
Geological Resources, Inc.
3502 Hayes Road
Monroe, NC 28110
[e-mail]
704-845-4010

Analytical Laboratory
SGS North America, Inc.
Vineland Road, Suite C-15
Orlando, FL 32811
State Certification No. 573
407-425-6700
3. Information about Release
 Release was discovered on March 24, 1992
 An unknown amount of product was released from the leaking UST System
 Two 1,000-gallon and one 550-gallon gasoline USTs were removed from the site in March 1992

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Groundwater Monitoring Report
Prepared on: October 7, 2022 Rich Square Tire Center
Project Manager: William Regenthal, P.G. GRI Project No. 3398
ii
EXECUTIVE SUMMARY
Rich Square Tire Center is located at 413 East Jackson Street in Rich Square, Northampton County, North
Carolina. The site is a former petroleum retail facility currently owned by John Thomas Boone and
operates as a service station. The adjoining properties are a mixture of commercial and residential
properties. According to the information determined during receptor survey activities, the municipal
water supply well for the Town of Rich Square was identified within 1,000 feet of the site. Public water is
available to the site and surrounding properties within a 1,500-foot radius of the site.

A CAP was submitted in April 1995 for the site. The CAP proposed a pump and treat system consisting of
an oil water separator with granular activated carbon filtration. The CAP has not been fully implemented.

On September 13, 2022, six monitoring wells were gauged, purged and/or sampled. Free product was
observed in MW-12R and MW-13, therefore, MW-12R and MW-13 were not sampled during the
September gauging event. Concentrations of individual BTEX constituents, naphthalene, n-
propylbenzene, methyl chloride, and 1,2,4-trimethylbenzene that exceeded the MACs were reported in
the ground water samples collected from MW-3 and MW-7. No reported concentrations exceeded the
GCLs.

During the September 2022 sampling event, approximately 1.00 gallons of product/water mix were
removed from MW-12R by hand bailing. Of the 1.00 gallons of liquids removed, approximately 0.25
gallons were free product.

Based on this information, the risk classification for the site should remain intermediate risk. Free product
recovery should continue at the site in addition to semi-annual sampling. The next sampling event is
tentatively scheduled for March 2023.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Groundwater Monitoring Report
Prepared on: October 7, 2022 Rich Square Tire Center
Project Manager: William Regenthal, P.G. GRI Project No. 3398
iii
ACRONYMS
ACM: Asbestos Containing Materials
AFVR: Aggressive Fluid-Vapor Recovery
ARR: Acknowledgement of Report Receipt
AS: Air Sparging
AST: Aboveground Storage Tank
ASTM: American Society for Testing and
Materials
BGS: Below Ground Surface
CAP: Corrective Action Plan
CFR: Code of Federal Regulations
CSA: Comprehensive Site Assessment
DPE: Dual Phase Extraction
DRO: Total Petroleum Hydrocarbons Diesel
Range Organics
DWM: Division of Waste Management
DWR: Department of Water Resources
EPA: Environmental Protection Agency
EPH: Extractible Petroleum Hydrocarbons
ESA: Environmental Site Assessment
GCL: Gross Contamination Level
GRI: Geological Resources, Inc.
GRO: Total Petroleum Hydrocarbons
Gasoline Range Organics
HERR: HAZMAT Emergency Response and
Remediation, Inc.
LSA: Limited Site Assessment
MAC: Maximum Allowable Concentration as
specified in T15A NCAC 2L.0202
MADEP: Massachusetts Department of
Environmental Protection
MCC: Maximum Contaminant Concentrations
MMPE: Mobile Multi-Phase Extraction
NAPL: Non-Aqueous Phase Liquid, “Free
Product”
NCDEQ: North Carolina Department of
Environmental Quality
NCDOT: North Carolina Department of
Transportation
NFA: Notice of No Further Action
NORR: Notice of Regulatory Requirements
NOV: Notice of Violation
NPDES: National Pollutant Discharge
Elimination System
NRP: Notice of Residual Petroleum
O&M: Operation and Maintenance
PAHs: Polynuclear Aromatic Hydrocarbons
PCA: Pre-Construction Assessment
RAL: Regulatory Action Level
SCLs: Soil Cleanup Level
SPCC: Spill Prevention Control and
Countermeasures
SVE: Soil Vapor Extraction
SVOCs: Semi-Volatile Organic Compounds
SWPPP: Stormwater Pollution Prevention Plan
TCLP: Toxicity Characteristic Leaching
Procedure (EPA Method SW-846 1311)
TOC: Top of Casing
TPH: Total Petroleum Hydrocarbons
USGS: United States Geological Survey
UST: Underground Storage Tank
UVF: Ultraviolet Fluorescence
VOCs: Volatile Organic Compounds
VPH: Volatile Petroleum Hydrocarbons

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Groundwater Monitoring Report
Prepared on: October 7, 2022 Rich Square Tire Center
Project Manager: William Regenthal, P.G. GRI Project No. 3398
TABLE OF CONTENTS
SITE INFORMATION ............................................................................................................................ i
EXECUTIVE SUMMARY ....................................................................................................................... ii
ACRONYMS ....................................................................................................................................... iii
1.0 SITE HISTORY AND CHARACTERIZATION ...................................................................................1
2.0 PRESENTATION OF CURRENT SITE ASSESSMENT INFORMATION/ COMPARISON TO HISTORICAL
ASSESSMENT INFORMATION ...................................................................................................2
3.0 FREE PRODUCT REMOVAL ........................................................................................................3
4.0 NATURAL ATTENUATION / NATURAL SOURCE ZONE DEPLETION STATUS ..................................4
5.0 CONCLUSIONS .........................................................................................................................4
6.0 LIMITATIONS ...........................................................................................................................4
7.0 STATEMENTS AND CERTIFICATION ...........................................................................................4

FIGURES
Figure 1: Site Location Map
Figure 2: Site Vicinity Map
Figure 3: Site Map
Figure 4: Water Table Surface Map
Figure 5: Groundwater Quality Map
Figure 6: Contaminant Mass Area Map

TABLES
Table 1: UST Owner and Operator Information
Table 2: UST System Information
Table 3: Water Supply Well Information
Table 4: Adjacent Property Owner Information
Table 5: Well Construction and Gauging Information
Table 6: Summary of Ground Water Sample Analytical Results
Table 7: Free Product Recovery Results
Table 8: Free Product Recovery Event Information
Table 9: Free Product Recovery Cost Summary

APPENDICES
Appendix A: State Correspondence
Appendix B: Laboratory Report – Ground Water Samples

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Groundwater Monitoring Report
Prepared on: October 7, 2022 Rich Square Tire Center
Project Manager: William Regenthal, P.G. GRI Project No. 3398
1
1.0 SITE HISTORY AND CHARACTERIZATION
GRI presents the results of the September 2022 ground water sampling event at the Rich Square Tire
Center site; located at 413 East Jackson Street in Rich Square, Northampton County, North Carolina (Figure
1). These activities were conducted in accordance with GRI Proposal No. 22-064, which was submitted to
NCDEQ on January 21, 2022, and was approved as Task Authorization No. 8975-17 on January 26, 2022.
State correspondence has been included as Appendix A.

The site is currently owned by James Boone and operates as a service station. The site was formerly
operated by North East Oil Company, Inc. as a petroleum retail facility. According to the available
information, a petroleum release occurred from a UST system consisting of two 1,000-gallon and one 550-
gallon gasoline USTs that were removed from the site on March 24, 1992. UST owner/operator
information and UST system information are included as Tables 1 and 2, respectively. The Registered
Tank Report is shown below:

Previous assessment and/or remediation activities began at the site in 1992 and were completed by
Coastal Environmental Services, Inc. (CES). Past assessment activities included the installation and
sampling of fifteen Type II monitoring wells (MW-1 through MW-6 and MW-8 through MW-16) and one
Type III monitoring well (MW-7). Please note, MW-2, MW-6, MW-9, MW-10 and MW-14 have not been
located and are assumed to have been destroyed. The adjoining properties are a mixture of commercial
and residential use properties. Municipal water is available to the site and all properties in the
surrounding area. The site risk classification is currently ranked as intermediate risk; however, one
potable municipal water supply well is located within a 1,000-foot radius of the site. Water supply well
information is presented in Table 3. Adjacent property owner information is presented in Table 4. A Site
Vicinity Map showing the locations of the water supply well and property boundaries is included as Figure
2.

A CAP was submitted in April 1995 for the site. The CAP proposed a pump and treat system consisting of
an oil water separator with granular activated carbon filtration. The CAP has not been fully implemented.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Groundwater Monitoring Report
Prepared on: October 7, 2022 Rich Square Tire Center
Project Manager: William Regenthal, P.G. GRI Project No. 3398
2
Previous free product removal activities included hand bailing, the use of absorbent socks and three AFVR
events. Past assessment activities were conducted by CES. GRI cannot verify the accuracy of past reports,
but for the purpose of this report, they are assumed to be correct. Please refer to past submittals for
further historical information regarding the incident.

On March 6 and 7, 2019, GRI supervised the excavation of contaminated soil from an area on site
surrounding MW-12. A total of 129.36 tons of contaminated soil was removed from the site during this
excavation. A Site Map showing the locations of the monitoring wells and the structures on-site has been
included as Figure 3.

2.0 PRESENTATION OF CURRENT SITE ASSESSMENT INFORMATION/ COMPARISON TO HISTORICAL
ASSESSMENT INFORMATION
On September 13, 2022, five Type II monitoring wells (MW-1, MW-3, MW-11, MW-12R and MW-13) and
one Type III monitoring well (MW-7) were gauged, purged and/or sampled. Free product thicknesses of
0.22 and 0.03 feet, respectively, were observed in MW-12R and MW-13, therefore, MW-12R and MW-13
were not sampled during the September gauging event. Depths to ground water in the Type II monitoring
wells ranged from 11.79 feet to 14.00 feet below the tops of well casings. Ground water elevations in the
Type II monitoring wells ranged from 85.95 feet to 98.04 feet. Ground water flow was generally to the
northwest with a horizontal gradient of approximately 0.09 feet per foot. The vertical gradient between
paired wells MW-3 and MW-7 was approximately 0.52 feet per foot in the upward direction. Well
construction and gauging information is presented in Table 5. A Water Table Surface Map based on the
Type II monitoring wells is included as Figure 4. A summary of the current ground water gauging data is
shown below:

Well ID
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(feet)
Free
Product
Thickness
(ft.)
Ground
Water
Elevation
(ft.)
MW-1 9 - 29 29 100.00 14.00 --- 86.00
MW-3 14 - 24 24 99.83 13.88 --- 85.95
MW-7 40 - 45 45 100.02 1.98 --- 98.04
MW-11 8 - 18 18 99.57 11.79 --- 87.78
MW-12R 8 - 18 18 99.89 11.97 0.22 88.11
MW-13 8 - 18 18 99.86 13.83 0.03 86.06

Ground water samples collected from the monitoring wells were submitted for laboratory analyses using
EPA Method 6200B. Concentrations of individual BTEX constituents, naphthalene isopropylbenzene, n-
propylbenzene, methyl chloride, and 1,2,4-trimethylbenzene that exceeded the MACs were reported in
the ground water samples collected from MW-3 and MW-7. No concentrations exceeded the GCLs.
Please note, free product was observed in MW-12R and MW-13. A summary of the analytical results for
ground water samples collected on September 13, 2022, is presented in Table 6. A Ground Water Quality
Map based on the September 2022 data is included as Figure 5. A complete report of laboratory analyses

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Groundwater Monitoring Report
Prepared on: October 7, 2022 Rich Square Tire Center
Project Manager: William Regenthal, P.G. GRI Project No. 3398
3
of the ground water samples collected from the monitoring wells during the September 2022 sampling
event has been included as Appendix B. A summary of the current ground water analytical data is shown
below:
Contaminant
of Concern 
Be
n
z
e
n
e

To
l
u
e
n
e

Et
h
y
l
b
e
n
z
e
n
e

Xy
l
e
n
e
s

MT
B
E

Na
p
h
t
h
a
l
e
n
e

Well
ID
MACs (mg/l) 1 600 600 500 20 6
GCL (mg/l) 5,000 260,000 80000 50000 20,000 6,000
MW-1 <0.13 <0.13 <0.13 <0.25 1.5 <0.13
MW-3 1,770 5,560 1,230 6,550 <25 131
MW-7 59.7 <0.13 1.3 2.1 <0.13 0.62
MW-11 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13
MW-12R FP FP FP FP FP FP
MW-13 FP FP FP FP FP FP

The baseline contaminant mass at the site was determined based on the total BTEX, MTBE and
naphthalene concentrations from the February 2015 ground water sampling event as well as the
maximum historical water column height observed in each area. The contaminant plume was divided into
two areas (Areas 1 and 2) based on the benzene concentrations during the February 2015 ground water
sampling event. Please note, contaminant mass was not calculated during the September 2022 sampling
event due to the presence of free product in MW-12R and MW-13. It is likely that past AFVR events have
pulled contamination and free product into the March 2019 excavation basin. A map of the contaminant
mass areas has been included as Figure 6.

The site is located in the Coastal Plain Physiographic Province of North Carolina. The water table has a
seasonal high depth to water of approximately 5 to 13 feet bgs.
3.0 FREE PRODUCT REMOVAL
Free product has historically been present in MW-12R. Free product thicknesses of 0.22 and 0.03 feet,
respectively, were observed in MW-12R and MW-13 during the September 2022 sampling event. Free
product was hand bailed from MW-12R on September 13, 2022. A total of 1.00 gallons of free product
and water was removed from MW-12 via hand bailing. Of the 1.00 gallons of free product and water mix,
an estimated 0.25 gallons were free product. The recovered liquids were transferred to a 55-gallon drum
that has been staged onsite. Free product recovery should continue at the site until free product is no
longer present.

Past free product recovery events conducted between March 2016 and September 2022 include two hand
bailing events, five AFVR events and the deployment of absorbent booms. A total of 1,382.50 gallons of
liquids have been recovered between March 2016 and September 2022. During the recovery events, a
total of 2.32 gallons of liquid and vapor phase free product have been recovered. Free product recovery
events are summarized in Tables 7, 8 and 9. Upon completion of the September 2022 sampling event, an
absorbent sock was reinstalled in MW-12R.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Groundwater Monitoring Report
Prepared on: October 7, 2022 Rich Square Tire Center
Project Manager: William Regenthal, P.G. GRI Project No. 3398
4
4.0 NATURAL ATTENUATION / NATURAL SOURCE ZONE DEPLETION STATUS
Free product recovery events are being conducted at the site as the primary method of corrective action.
No natural attenuation monitoring plan was established in the April 1995 CAP.
5.0 CONCLUSIONS
 On September 13, 2022, five Type II and one Type III monitoring wells were gauged, purged and/or
sampled. Free product was observed in MW-12R and MW-13, therefore, MW-12R and MW-13
were not sampled during the September gauging event. Ground water flow was generally to the
northwest with a horizontal gradient of approximately 0.09 feet per foot. The vertical gradient
between paired wells MW-3 and MW-7 was approximately 0.52 feet per foot in the upward
direction.
 Concentrations of individual BTEX constituents, naphthalene, isopropylbenzene, n-
propylbenzene, methyl chloride, and 1,2,4-trimethylbenzene that exceeded the MACs were
reported in the ground water samples collected from MW-3 and MW-7. Please note, free product
was observed in MW-12R and MW-13. No reported concentrations exceeded the GCLs.
 A total of 1.00 gallons of liquids, including 0.25 gallons of free product, was recovered from MW-
12R via hand bailing on September 13, 2022.
 Based on this information, the risk classification for the site should remain intermediate risk. Free
product recovery should continue at the site in addition to semi-annual sampling. The next
sampling event is tentatively scheduled for March 2023.
6.0 LIMITATIONS
This report has been prepared for the exclusive use of North East Oil Company, Inc. for specific application
to the referenced site in Northampton County, North Carolina. The assessment was conducted based on
the scope of work and level of effort desired by NCDEQ and with resources adequate only for that scope
of work. Our findings have been developed in accordance with generally accepted standards of
environmental practices in the State of North Carolina, available information, and our professional
judgment. No other warranty is expressed or implied.

The data that are presented in this report are indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would
be interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from these data.
7.0 STATEMENTS AND CERTIFICATION
1 Enter the date the monitoring report was due. n/a Will this report be submitted after the
established due date?
YES NO
2 Was any required information from the above template missing from this report? YES NO
IF the answer to question #1 or# 2 is “YES”, please provide additional information in this cell to explain
what was missing and why.

FIGURES
Copyright (C) 2009 MyTopo, 2006-2017 TomTom
SCALE 1:24000
0 1000 2000 3000 4000 5000
FEET
Declination
MN 10.13° W
MN
Location: 036.2719950° N 077.2744100° WDate: 12/01/17
Scale: 1 inch = 2,000 ft.
Copyright (C) 2009 MyTopo
Figure 1
Beasley Enterprises, Inc.
413 East Jackson Street, Rich Square, Northampton
County, NC
Incident No. 8975
GRI Project No. 3398
2

TABLES
UST ID Number 1-3 Facility ID Number
Owner or Operator?
Owner/Operator
Telephone Number
TABLE 1
UST OWNER/OPERATOR INFORMATION
RICH SQUARE TIRE CENTER (INCIDENT #: 8975)
PO Box 1386, Ahoskie, NC 27910 1-252-398-6022
00-0-0000030781
Name of Owner or Operator Dates of Ownership / Operation
Eastern Fuels Inc.09/27/1966 - 03/24/1992
Address
Page 1 of 1
Date: 01/22/20 Facility ID # : 00-0-0000030781
Was Release
Associated
with UST
System?
(Yes / No)
1 Gasoline 1,000 9/27/1966 Single Wall Steel 46" x 12'Single Wall Steel removed
3/24/92 Yes
2 Gasoline 1,000 9/27/1966 Single Wall Steel 46" x 12'Single Wall Steel removed
3/24/92 Yes
3 Gasoline 550 9/27/1966 Single Wall Steel 45.5" x 76"Single Wall Steel removed
3/24/92 Yes
Construction
Details
Tank
Dimensions
Description of
Associated
Product Piping
and
Pumps
TABLE 2
UST SYSTEM INFORMATION
RICH SQUARE TIRE CENTER (INCIDENT #: 8975)
Status
of
UST
UST
ID
No.
Current
or Most
Recent
Contents
Capacity
(gallons)
Date
Installed
Page 1 of 1
Date: 03/18/14
Parcel ID No.Well Owner Address
Well Use
(Potable /
Non-Potable
etc.)
Well
Depth
(ft. BGS)
Type of
Well
(Drilled/
Bored)
Well
Casing
Depth
(ft. BGS)
Well Screen
Interval
(x to y ft.
BGS)
Distance
from
source area
of release
(ft.)
5902-82-1620 Town of Rich Square Post Office Box 336 Rich
Square, NC 27869 Potable Unknown Unknown Unknown Unknown ~770' NW
Notes:
• Water supply wells are keyed to Figure 2.
• Ft. BGS : Feet below ground surface
TABLE 3
WATER SUPPLY WELL INFORMATION
RICH SQUARE TIRE CENTER (INCIDENT #: 8975)
Facility ID # : 00-0-0000030781
Date: 02/14/20 Facility ID #: 00-0-0000030781
5902-82-7402 (Site)James Thomas Boone Post Office Box 149
Rich Square, NC 27869
5902-82-5445 First Baptist Church
5902-82-6742 First Baptist Church Trustees
5902-82-4199 Wilma A King 2902 Reynolda Circle
Durham, NC 27712
5902-82-6143 Gary and Nelda Helmer 416 East Jackson Street
Rich Square, NC 27869
5902-82-7048 Blair J Britt 420 East Jackson Street
Rich Square, NC 27869
5902-82-7490 Rodney and Pamela Majette Post Office Box 811
Rich Square, NC 27869
5902-73-4838 Jackie Bennett Gillam 2387 Tar Landing Road
Williamston, NC 27892
Post Office Box 525
Rich Square, NC 27869
TABLE 4
ADJACENT PROPERTY OWNER INFORMATION
RICH SQUARE TIRE CENTER (INCIDENT #: 8975)
Parcel ID No.Property Owner Name Mailing Address
Page 1 of 1
Date: 09/16/22 Facility ID #: 00-0-0000030781
03/04/14 12.89 ---87.11
02/12/15 12.05 ---87.95
10/06/15 13.70 ---86.30
03/31/16 8.92 ---91.08
10/18/16 8.94 ---91.06
04/19/17 11.14 ---88.86
11/14/17 12.30 ---87.70
01/07/20 13.07 ---86.93
02/24/21 5.67 ---94.33
09/07/21 10.04 ---89.96
09/13/22 14.00 ---86.00
MW-2 06/30/92 03/04/14 14 14 - 24 24 100.18 NM NM NM Not Found
03/04/14 100.10 12.65 ---87.45
02/12/15 11.91 ---87.92
10/06/15 13.54 ---86.29
03/31/16 8.81 ---91.02
10/18/16 8.78 ---91.05
04/19/17 11.03 ---88.80
11/14/17 12.12 ---87.71
04/02/19 7.93 ---91.90
01/07/20 12.91 ---86.92
02/24/21 5.52 ---94.31
09/07/21 9.92 ---89.91
09/13/22 13.88 ---85.95
03/04/14 100.01 NM NM NM Not Found
02/12/15 5.26 ---94.66
10/06/15 9.80 ---90.12
03/31/16 3.82 ---96.10
10/18/16 6.25 ---93.67
04/19/17 5.20 ---94.72
11/14/17 5.24 ---94.68
01/07/20 6.14 ---93.78
02/24/21 2.41 ---97.51
03/04/14 99.95 11.03 ---88.92
02/12/15 11.23 ---88.77
10/06/15 12.48 ---87.52
03/31/16 10.29 ---89.71
10/18/16 10.01 ---89.99
04/19/17 9.95 ---90.05
11/14/17 11.42 ---88.58
01/07/20 11.93 ---88.07
02/24/21 5.03 ---94.97
MW-6 11/04/92 03/04/14 8 8 - 18 18 99.79 NM NM NM Not Found
03/04/14 12.73 ---87.29
10/06/15 13.63 ---86.39
03/31/16 8.94 ---91.08
10/18/16 8.86 ---91.16
04/19/17 11.11 ---88.91
11/14/17 12.25 ---87.77
01/07/20 3.56 ---96.46
02/24/21 3.20 ---96.82
09/07/21 0.52 ---99.50
09/13/22 1.98 ---98.04
03/04/14 99.83 12.99 ---86.84
02/12/15 11.36 ---88.46
10/06/15 13.90 ---85.92
03/31/16 9.95 ---89.87
10/18/16 9.86 ---89.96
04/19/17 10.89 ---88.93
11/14/17 11.82 ---88.00
01/07/20 13.59 ---86.23
02/24/21 5.15 ---94.67
MW-9 03/09/95 03/04/14 8 8 - 18 18 98.45 NM NM NM Not Found
MW-10 03/09/95 03/04/14 8 8 - 18 18 98.50 NM NM NM Not Found
02/12/15 12.82 ---86.75
10/06/15 12.94 ---86.63
03/31/16 8.09 ---91.48
10/18/16 8.68 ---90.89
04/19/17 10.11 ---89.46
11/14/17 11.04 ---88.53
01/07/20 12.40 ---87.17
02/24/21 6.74 ---92.83
09/07/21 9.16 ---90.41
09/13/22 11.79 ---87.78
100.0240 - 4540
99.57188 - 18802/11/15
MW-1
99.832414 - 2414MW-3 06/30/92
100.00299 - 29906/29/92
TABLE 5
WELL CONSTRUCTION AND GAUGING INFORMATION
RICH SQUARE TIRE CENTER (INCIDENT NO. 8975)
11/03/92MW-4
MW-8
188 - 18
99.92188 - 18
99.822212 - 22
45
Bottom of
Well
(ft. BGS)
Top of
Casing
Elevation*
(ft.)
Depth to
Water from
Top of
Casing
(ft.)
Free Product
Thickness
(ft.)
Ground
Water
Elevation*
(ft.)
CommentsWell ID
Date
Installed
(mm/dd/yy)
Date Water
Level
Measured
(mm/dd/yy
)
Well Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
8
1203/06/95
100.00811/03/92MW-5
MW-7 11/06/92
MW-11
Page 1 of 2
Date: 09/16/22 Facility ID #: 00-0-0000030781
TABLE 5
WELL CONSTRUCTION AND GAUGING INFORMATION
RICH SQUARE TIRE CENTER (INCIDENT NO. 8975)
Bottom of
Well
(ft. BGS)
Top of
Casing
Elevation*
(ft.)
Depth to
Water from
Top of
Casing
(ft.)
Free Product
Thickness
(ft.)
Ground
Water
Elevation*
(ft.)
CommentsWell ID
Date
Installed
(mm/dd/yy)
Date Water
Level
Measured
(mm/dd/yy
)
Well Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
02/12/15 9.08 ---90.85
10/06/15 13.92 0.12 86.11
03/31/16 9.07 0.30 91.12
09/15/16 11.87 0.56 88.54 Before AFVR
09/15/16 8.31 0.30 91.88 After AFVR
03/14/17 11.38 0.38 88.88 Before AFVR
03/14/17 8.20 0.14 91.85 After AFVR
04/19/17 11.19 0.10 88.83
10/11/17 12.09 0.37 88.16 Before AFVR
10/11/17 9.29 ---90.64 After AFVR
11/14/17 12.63 0.59 87.81
09/07/21 9.71 0.08 90.29
04/02/19 9.23 ---90.66
11/25/19 9.02 ---90.87 Before AFVR
11/25/19 12.79 ---87.10 After AFVR
01/07/20 11.36 ---88.53
01/20/21 9.31 ---90.58 Before AFVR
01/20/21 12.52 ---87.37 After AFVR
02/24/21 6.99 0.06 92.95
09/13/22 11.97 0.22 88.11
02/12/15 17.12 ---82.74
10/06/15 11.39 ---88.47
03/31/16 7.32 ---92.54
09/15/16 10.13 ---89.73 Before AFVR
09/15/16 8.17 ---91.69 After AFVR
10/18/16 10.48 ---89.38 Before AFVR
03/14/17 8.36 ---91.50 After AFVR
03/14/17 8.36 ---91.50
03/14/07 8.20 ---91.66
04/19/17 10.77 ---89.09
10/11/17 11.42 ---88.44 Before AFVR
10/11/17 8.14 ---91.72 After AFVR
11/14/17 12.09 ---87.77
04/02/19 6.93 ---92.93
11/25/19 12.63 ---87.23 Before AFVR
11/25/19 9.77 ---90.09 After AFVR
01/07/20 12.84 ---87.02
01/20/21 9.39 ---90.47 Before AFVR
01/20/21 10.25 ---89.61 After AFVR
02/24/21 5.51 ---94.35
09/07/21 9.69 ---90.17
09/13/22 13.83 0.03 86.06
02/12/15 11.13 ---88.22
10/06/15 12.70 ---86.65
03/31/16 7.79 ---91.56
10/18/16 7.97 ---91.38
04/19/17 9.37 ---89.98
11/14/17 11.23 ---88.12
04/02/19 NM NM NM Not Located
01/07/20 NM NM NM Not Located
09/13/22 NM NM NM Not Located
10/06/15 17.44 ---81.82
03/31/16 9.47 ---89.79
10/18/16 8.44 ---90.82
04/19/17 10.90 ---88.36
11/14/17 5.27 ---93.99
04/02/19 3.35 ---95.91
01/07/20 3.74 ---95.52
02/24/21 0.99 ---98.27
10/06/15 16.83 ---82.38
03/31/16 4.95 ---94.26
10/18/16 6.09 ---93.12
04/19/17 6.12 ---93.09
11/14/17 4.66 ---94.55
04/02/19 2.74 ---96.47
01/07/20 4.23 ---94.98
02/24/21 0.38 ---98.83
Notes:
• Top of Casing and well construction information obtained prior to February 2015 was from the report titled 'Comprehensive Site Assessment
Report', dated May 15, 1995 by Coastal Environmental Services, Inc.
MW-12R
99.35188 - 18802/11/15MW-14
99.86188 - 18802/11/15MW-13
99.89804/02/19 188 - 18
99.93188 - 188
MW-16
99.26188 - 18810/01/15MW-15
99.21188 - 18810/01/15
• ft BGS : feet below ground surface
• NM: Not measured.
02/11/15MW-12
Page 2 of 2
Date: 10/04/22 Facility ID # : 00-0-0000030781
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 70 70 400 400 400 700 200
5,000 260,000 80,000 50,000 20,000 6,000 30,500 26,100 28,500 24,100 NE NE NE
03/04/14 0.13 J 0.47 J 0.34 J 2.1 2.5 1.3 <0.10 0.12 J 1.9 0.71 <35 <35 <35
02/12/15 <0.17 <0.17 <0.15 <0.43 1.2 <0.12 <0.12 <0.16 <0.14 <0.14 <35 <35 <35
10/06/15 <0.17 <0.17 <0.15 <0.43 1.0 <0.12 <0.12 <0.16 <0.14 <0.14 <35 <35 <35
03/31/16 <0.13 <0.13 <0.13 <0.31 0.65 0.18 J <0.13 <0.13 <0.13 <0.13 NS NS NS
10/18/16 <0.13 <0.13 <0.13 <0.31 0.67 <0.13 <0.13 <0.13 <0.13 <0.13 NS NS NS
04/19/17 <0.13 <0.13 <0.13 <0.25 0.85 <0.13 <0.13 <0.13 <0.13 <0.13 NS NS NS
11/14/17 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR
01/07/20 <0.13 <0.13 <0.13 <0.25 0.81 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR
02/24/21 <0.13 <0.13 <0.13 <0.25 1.1 <0.13 NR NR NR NR NR NR NR
09/07/21 <0.13 <0.13 <0.13 <0.25 0.14 J <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR
09/13/22 <0.13 <0.13 <0.13 <0.25 1.5 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR
MW-2 03/04/14
03/04/14 4,620 8,390 1,920 11,200 255 499 59.0 152 1,790 652 12,700 <1,800 7,610
02/12/15 1,870 2,310 1,030 3,790 99.2 209 36.8 96.6 731 223 6,170 <700 5,500
10/06/15 692 3,090 523 3,760 <16 81.8 <12 21.2 J 419 148 6,300 810 J 1,670
03/31/16 1,870 4,050 441 4,270 79.7 202 9.3 J 17.1 J 652 242 NS NS NS
10/18/16 496 1,390 304 1,670 15.0 J 61.8 8.0 J 19.6 J 233 78.6 NS NS NS
04/19/17 2,950 7,490 1,570 7,920 135 331 40.1 J 93.8 1,110 363 NS NS NS
11/14/17 2,180 3,790 1,730 6,580 108 348 74.7 185 1,360 477 NR NR NR
04/02/19 2,780 6,290 1,140 9,190 90.3 J 224 27.1 J 72.1 J 1,010 332 NR NR NR
01/07/20 1,680 4,290 1,620 8,640 <13 262 43.3 J 99.3 1,130 386 NR NR NR
02/24/21 566 942 561 1,840 <3.1 100 NR NR NR NR NR NR NR
09/07/21 473 1,410 541 2,800 <6.3 109 20.2 J 52.5 464 149 NR NR NR
09/13/22 1,770 5,560 1,230 6,550 <25 131 25.2 J 76.5 J 696 210 NR NR NR
03/04/14 NS NS NS NS NS NS NS NS NS NS NS NS NS
02/12/15 <0.17 <0.17 <0.15 <0.43 0.65 <0.12 <0.12 <0.16 <0.14 <0.14 <35 <35 <35
10/06/15 <0.17 <0.17 <0.15 <0.43 0.81 <0.12 <0.12 <0.16 <0.14 <0.14 <35 <35 <35
03/31/16 <0.13 <0.13 <0.13 <0.31 0.74 <0.13 <0.13 <0.13 <0.13 <0.13 NS NS NS
10/18/16 <0.13 <0.13 <0.13 <0.31 1.0 <0.13 <0.13 <0.13 <0.13 <0.13 NS NS NS
04/19/17 <0.13 <0.13 <0.13 <0.25 0.74 <0.13 <0.13 <0.13 <0.13 <0.13 NS NS NS
11/14/17 <0.13 <0.13 <0.13 <0.25 0.88 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR
01/07/20 <0.13 <0.13 <0.13 <0.25 0.66 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR
02/24/21 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 NR NR NR NR NR NR NR
03/04/14 <0.10 <0.10 <0.10 <0.20 0.25 J <0.10 <0.10 <0.10 <0.10 <0.10 <35 <35 <35
02/12/15 <0.17 <0.17 <0.15 <0.43 0.21 J <0.12 <0.12 <0.16 <0.14 <0.14 <35 <35 <35
10/06/15 <0.17 <0.17 <0.15 <0.43 0.27 J <0.12 <0.12 <0.16 <0.14 <0.14 <35 <35 <35
03/31/16 <0.13 <0.13 <0.13 <0.31 0.13 J <0.13 <0.13 <0.13 <0.13 <0.13 NS NS NS
10/18/16 <0.13 <0.13 <0.13 <0.31 0.14 J <0.13 <0.13 <0.13 <0.13 <0.13 NS NS NS
04/19/17 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NS NS NS
11/14/17 <0.13 <0.13 <0.13 <0.25 0.24 J <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR
01/07/20 <0.13 <0.13 <0.13 <0.25 0.21 J <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR
02/24/21 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 NR NR NR NR NR NR NR
MW-6 03/04/14
03/04/14 0.59 0.20 J 1.1 3.0 <0.10 <0.10 <0.10 0.25 J 0.37 J 0.35 J <35 <35 <35
02/12/15 NS NS NS NS NS NS NS NS NS NS NS NS NS
10/06/15 0.29 J 0.25 J 0.63 4.6 <0.16 3.1 0.29 J 0.95 6.5 2.4 <35 38.1 J 46.6 J
03/31/16 0.22 J <0.13 0.38 J 0.81 J <0.13 <0.13 <0.13 <0.13 0.18 J <0.13 NS NS NS
10/18/16 40.2 1.8 30.3 26.6 <0.13 1.2 0.81 3.0 12.3 1.0 NS NS NS
04/19/17 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NS NS NS
11/14/17 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR
01/07/20 0.61 <0.13 0.52 0.58 J <0.13 <0.13 <0.13 <0.13 0.32 J <0.13 NR NR NR
02/24/21 0.22 J <0.13 0.22 J <0.25 <0.13 <0.13 NR NR NR NR NR NR NR
09/07/21 71.2 2.9 127 16.4 <0.25 12.5 5.1 17.0 84.1 0.31 J NR NR NR
09/13/22 59.7 <0.13 1.3 2.1 <0.13 0.62 3.7 11.3 0.16 J 0.22 J NR NR NR
03/04/14 <0.10 <0.10 <0.10 <0.20 1.7 <0.10 <0.10 <0.10 <0.10 <0.10 <35 <35 <35
02/12/15 <0.17 <0.17 <0.15 <0.43 1.0 <0.12 <0.12 <0.16 <0.14 <0.14 <35 <35 <35
10/06/15 <0.17 <0.17 <0.15 <0.43 0.73 <0.12 <0.12 <0.16 <0.14 <0.14 <35 <35 <35
03/31/16 <0.13 <0.13 <0.13 <0.31 1.1 <0.13 <0.13 <0.13 <0.13 <0.13 NS NS NS
10/18/16 <0.13 <0.13 <0.13 <0.31 1.0 <0.13 <0.13 <0.13 <0.13 <0.13 NS NS NS
04/19/17 <0.13 <0.13 <0.13 <0.25 0.87 0.29 J <0.13 <0.13 <0.13 <0.13 NS NS NS
11/14/17 <0.13 <0.13 <0.13 <0.25 1.2 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR
01/07/20 <0.13 <0.13 <0.13 <0.25 0.76 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR
02/24/21 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 NR NR NR NR NR NR NR
MW-9 03/04/14
MW-10 03/04/14
MW-1
MW-7
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
MW-8
MW-4
MW-5
MW-3
C5
-
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8

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MAC (µg/l)
GCL (µg/l)
Na
p
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Is
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Contaminant of Concern

TABLE 6
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
RICH SQUARE TIRE CENTER (INCIDENT NO. 8975)
Analytical Method EPA Method 6200B MADEP Method VPH
Page 1 of 3
Date: 10/04/22 Facility ID # : 00-0-0000030781
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 70 70 400 400 400 700 200
5,000 260,000 80,000 50,000 20,000 6,000 30,500 26,100 28,500 24,100 NE NE NE
C5
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MAC (µg/l)
GCL (µg/l)
Na
p
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Contaminant of Concern

TABLE 6
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
RICH SQUARE TIRE CENTER (INCIDENT NO. 8975)
Analytical Method EPA Method 6200B MADEP Method VPH
02/12/15 <0.17 0.28 J <0.15 <0.43 <0.16 <0.12 <0.12 <0.16 <0.14 <0.14 <35 <35 <35
10/06/15 <0.17 <0.17 <0.15 <0.43 <0.16 <0.12 <0.12 <0.16 <0.14 <0.14 <35 <35 <35
03/31/16 <0.13 <0.13 <0.13 <0.31 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NS NS NS
10/18/16 <0.13 <0.13 <0.13 <0.31 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NS NS NS
04/19/17 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NS NS NS
11/14/17 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR
01/07/20 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR
02/24/21 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 NR NR NR NR NR NR NR
09/07/21 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR
09/13/22 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR
02/12/15 3,840 3,220 1,810 8,820 160 846 171 250 1,470 455 25,700 <35 7,300 J
10/06/15 FP FP FP FP FP FP FP FP FP FP FP FP FP
03/31/16 FP FP FP FP FP FP FP FP FP FP FP FP FP
10/18/16 FP FP FP FP FP FP FP FP FP FP FP FP FP
04/19/17 FP FP FP FP FP FP FP FP FP FP FP FP FP
11/14/17 FP FP FP FP FP FP FP FP FP FP FP FP FP
04/02/19 803 833 1,060 3,670 <3.1 180 164 213 1,110 400 NR NR NR
01/07/20 295 25.3 267 684 <1.3 49.0 62.8 71.6 443 212 NR NR NR
01/20/21 2,050 1,850 1,680 6,820 <13 227 NR NR NR NR NR NR NR
02/24/21 FP FP FP FP FP FP FP FP FP FP FP FP FP
09/07/21 FP FP FP FP FP FP FP FP FP FP FP FP FP
09/13/22 FP FP FP FP FP FP FP FP FP FP FP FP FP
02/12/15 4,050 534 1,000 3,210 31.9 207 119 229 953 362 5,610 <35 7,230
10/06/15 4,440 3,170 1,420 6,430 360 238 66.9 141 814 283 14,100 2,280 3,160
03/31/16 5,360 3,740 1,620 7,760 404 311 72.5 J 127 852 265 NS NS NS
10/18/16 4,440 1,800 1,040 6,320 350 261 56.3 114 1,230 428 NS NS NS
04/19/17 4,620 2,090 1,420 6,990 301 289 84.6 146 1,240 432 NS NS NS
11/14/17 4,190 469 1,360 5,890 248 385 95.2 178 1,240 460 NR NR NR
04/02/19 4,680 898 1,750 6,760 285 307 72.7 153 1,100 371 NR NR NR
01/07/20 5,490 832 1,870 6,950 289 337 104 179 1,350 477 NR NR NR
01/20/21 4,630 2,350 1,570 7,210 335 320 NR NR NR NR NR NR NR
02/24/21 4,080 1,240 1,240 5,280 235 202 NR NR NR NR NR NR NR
09/07/21 3,670 1,860 1,540 6,610 313 439 84.3 162 1,470 484 NR NR NR
09/13/22 FP FP FP FP FP FP FP FP FP FP FP FP FP
02/12/15 401 5.6 229 380 2.5 76.3 69.7 73.3 170 109 2,580 <35 2,170
10/06/15 431 7.2 125 222 <0.82 98.6 55.4 33.4 104 49.8 4,400 410 J 1,140
03/31/16 212 5.3 50.7 111 <1.3 37.6 22.9 13.3 38.4 18.1 NS NS NS
10/18/16 167 1.7 45.8 35.0 <0.13 44.0 28.3 13.4 29.6 12.5 NS NS NS
04/19/17 263 3.3 58.4 46.2 0.74 42.9 34.2 17.4 32.1 12.0 NS NS NS
11/14/17 126 0.56 29.2 15.1 0.17 J 28.3 19.0 9.3 14.8 3.8 NR NR NR
04/02/19 NS NS NS NS NS NS NS NS NS NS NS NS NS
01/07/20 NS NS NS NS NS NS NS NS NS NS NS NS NS
09/13/22
10/06/15 NS NS NS NS NS NS NS NS NS NS NS NS NS
03/31/16 <0.13 <0.13 <0.13 <0.31 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NS NS NS
10/18/16 <0.13 <0.13 <0.13 <0.31 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NS NS NS
04/19/17 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NS NS NS
11/14/17 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR
04/02/19 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR
01/07/20 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR
02/24/21 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 NR NR NR NR NR NR NR
10/06/15 <0.17 <0.17 <0.15 <0.43 <0.16 <0.12 <0.12 <0.16 <0.14 <0.14 <35 <35 <35
03/31/16 <0.13 <0.13 <0.13 <0.31 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NS NS NS
10/18/16 <0.13 <0.13 <0.13 <0.31 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NS NS NS
04/19/17 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NS NS NS
11/14/17 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR
04/02/19 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR
01/07/20 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR
02/24/21 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 NR NR NR NR NR NR NR
MW-11
MW-12R
MW-16
MW-12
MW-15
Not Found
MW-13
MW-14
Page 2 of 3
Date: 10/04/22 Facility ID # : 00-0-0000030781
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 70 70 400 400 400 700 200
5,000 260,000 80,000 50,000 20,000 6,000 30,500 26,100 28,500 24,100 NE NE NE
C5
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5
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
1,
2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
MAC (µg/l)
GCL (µg/l)
Na
p
h
t
h
a
l
e
n
e
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e
n-
P
r
o
p
y
l
b
e
n
z
e
n
e
Contaminant of Concern

TABLE 6
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
RICH SQUARE TIRE CENTER (INCIDENT NO. 8975)
Analytical Method EPA Method 6200B MADEP Method VPH
Trip Blank 09/13/22 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR
Notes:
• Results reported in µg/l (micrograms per liter).
• MAC: Maximum allowable concentrations specified in T15A NCAC 2L.0202.
• GCL : Gross contamination level.
• Concentrations in bold face type indicate the reported concentrations exceeded the MACs.
• Concentrations in italics indicate the reported concentrations exceeded the GCLs.
• Concentrations of methyl chloride 170 µg/l in MW-3 that exceeded the MAC were reported in the ground water sample collected on September 13, 2022.
• < : Less than the method detection limit specified in the laboratory report
• J: Estimated value.
• NS: Not sampled.
• NR: Analyses not requested.
• Please see the laboratory report for other detectable contaminant constituents that did not exceed the MACs.
Page 3 of 3
Date: 10/05/22
Method of Measurement:
Well ID Product Type
(gas, diesel, etc.)
Date of
Recovery
(mm/dd/yy)
Free Product
Recovery
Method*
Casing
Diameter
(inches)
Product Thickness
before Recovery
(feet)
Product Thickness
after Recovery
(feet)
Amount of Liquid
Recovered
(gallons)
Amount of
Product
Recovered
(gallons)
MW-12 03/31/16 Hand Bailing 2 0.30 0.00 0.50 0.25
MW-12 0.56 0.30
MW-13 0.00 0.00
MW-12 03/31/16 -
04/19/17
Absorbent
Boom 2 0.30 0.10 0.24 0.24
MW-12 0.38 0.30
MW-13 0.00 0.00
MW-12 0.37 0.00
MW-13 0.00 0.00
MW-12 04/19/17 -
11/14/17
Absorbent
Boom 2 0.10 0.37 0.26 0.26
MW-12R
MW-13
MW-12R
MW-13
MW-12R 09/07/21 Hand Bailing 2 0.08 0.00 0.50 0.25
MW-12R 09/13/22 Hand Bailing 2 0.22 0.00 1.00 0.25
Notes :
• *: Bailing, Skimming, Aggressive Fluid Vapor Recovery (AFVR), Mobile Multiphase Extraction (MMPE)
• Amount of Liquid Recovered (gallons) includes Total liquids (Water and Free Product) as indicated on Disposal Manifest
• Amount of Product Recovered (in gallons) includes only the volume of free product in the tanker at the end of the event
(based on Disposal Manifest and Field Notes).
• NM: Not measured.
Gasoline
TABLE 7
FREE PRODUCT RECOVERY RESULTS
Interface probe at top-of-casing
09/15/16 AFVR 2 530
RICH SQUARE TIRE CENTER (INCIDENT NO. 8975)
0
Facilty ID #: 00-0-0000030781
0
AFVR
0.00
329
10/11/17 0
0.0011/25/19 AFVR 2 0.00
293
191.00
0.000.00
2
37.00
0.00
03/14/17 AFVR 2
01/20/21 2AFVR
Page 1 of 1
Date: 10/05/22
MW-12 03/31/16 Hand Bailing ------------0.50 0.25 0.25
MW-12
MW-13
MW-12 03/31/16 -
04/19/17
Absorbent
Boom ------------0.24 0.24 0.24
MW-12
MW-13
MW-12
MW-13
MW-12 04/19/17 -
11/14/17
Absorbent
Boom ------------0.26 0.26 0.26
MW-12
MW-13
MW-12
MW-13
MW-12R 09/07/21 Hand Bailing ------------0.50 0.25 0.25
MW-12R 09/13/22 Hand Bailing ------------1.00 0.25 0.25
1.32 1,382.50 1.25 2.57
Notes:
• *: Bailing, Skimming, Aggressive Fluid Vapor Recovery (AFVR), Mobile Multiphase Extraction (MMPE)
• Amount of Vaporized Product (in gallons) is based on Vapor Emissions Summary Sheet, = lbs emitted/6.25
• Amount of Liquid Recovered includes Total liquids (Water and Free Product) as indicated on Disposal Manifest.
• Amount of Product Recovered as Liquid includes only the volume of free product in the tanker at the end of the event (based on Disposal
Manifest and/or Field Notes).
• Total Amount of Product Recovered = Amount of Vaporized Product + Amount of Product Recovered as Liquid
• Total Fluids Removed = Amount of Vaporized Product + Amount of Liquid Recovered
49.81,346.00AFVR01/20/21 0.060.0037.000.062.4
Total To Date 1,382.50 2.57
530.00 0.00 0.67
Totals
SUMMARY OF FLUID REMOVAL
Summary Total Fluids Removed (in gallons)Total Amount of Product Removed (in gallons)
0.67
Current Event 1.00 0.25
09/15/16
TABLE 8
FREE PRODUCT RECOVERY EVENT INFORMATION
RICH SQUARE TIRE CENTER (INCIDENT NO. 8975)
Well ID Date
(mm/dd/yy)
Product
Recovery
Method*
Average
Effluent
Velocity
(ft/min)
Average
Effluent
Temperature
(°F)
Average Effluent
Concentration
(ppm)
Amount of
Liquid
Recovered
(gallons)
Amount of
Product
Recovered as
Liquid
(gallons)
Total Amount
of Product
Recovered
(gallons)
Facility ID#: 00-0-0000030781
Amount of
Vaporized
Product
(gallons)
03/14/17 AFVR 1,316.05 76.01 17.81 0.29 329.00 0.00 0.29
AFVR 685.81 75.87 92.89
199.181,255.29AFVR10/11/17 0.230.00293.000.2318.04
0.07 191.00 0.00 0.0711/25/19 AFVR 1,594.00 64.1 9.2
Page 1 of 1
Date: 10/05/22
Wells Included in
Event
Product
Recovery
Method*
Date of Event
(mm/dd/yy)
Total Amount of Free
Product plus Ground
Water
Recovered(gallons)
Cost of Free
Product Recovery
Event
Cost Per Gallon
(total liquids)
MW-12 & MW-13 AFVR 09/15/16 530.67 $2,255.22 $4.25
MW-12 Absorbent
Boom
03/31/16 -
04/19/17 0.24 $98.85 $411.88
MW-12 & MW-13 AFVR 03/14/17 329.29 $2,129.15 $6.47
MW-12 & MW-13 AFVR 10/11/17 293.23 $2,116.55 $7.22
MW-12 Absorbent
Boom
04/19/17 -
11/14/17 0.26 ------
MW-12R & MW-13 AFVR 11/25/19 191.07 $2,080.85 $10.89
MW-12R & MW-13 AFVR 01/20/21 37.02 $2,170.95 $58.64
MW-12R Hand Bailing 09/07/21 0.50 $90.00 $180.00
MW-12R Hand Bailing/
Absorbant Sock 09/13/22 1.00 $127.09 $127.09
1,383.28 $10,851.57 $7.84
Notes:
• *: Bailing, Skimming, Aggressive Fluid Vapor Recovery (AFVR), Mobile Multiphase Extraction (MMPE)
• Total Amount of Free Product Recovered = Amount of Vaporized Product + Amount of Product Recovered as Liquid
• Cost of Free Product Recovery Event includes supervision, travel, mileage, per diem, subcontractor costs, report preparation and
project management.
Cost per gallon for the event is based on a
total volume of 530.67 gallons of
contaminated water and vaporized
product.
TOTAL (to date)
Facility ID#: 00-0-0000030781
TABLE 9
FREE PRODUCT RECOVERY COST SUMMARY
RICH SQUARE TIRE CENTER (INCIDENT NO. 8975)
Comments
Cost per gallon for the event is based on a
total volume of 329.29 gallons of
contaminated water and vaporized
product.
Cost per gallon for the event is based on a
total volume of 0.24 gallons of product
removed by the absorbent boom that was
installed in MW-12 on 03/31/16.
Cost per gallon for the event is based on a
total volume of 293.23 gallons of
contaminated water and vaporized
product.
Absorbent boom left in well from past
sampling event; no cost associated with
this boom.
Cost per gallon for the event is based on a
total volume of 191.07 gallons of
contaminated water and vaporized
product.
Cost per gallon for the event is based on a
total volume of 37.02 gallons of
contaminated water and vaporized
product.
Hand bailed liquid during sampling event;1
gallon of FP/water recovered. Absorbant
sock installed.
Hand bailed liquid during sampling even;
0.50 gallons of FP/water recovered.
Page 1 of 1

APPENDICES

APPENDIX A
State Correspondence
3398 Received JAN 27 2022

APPENDIX B
Laboratory Reports – Ground Water Samples
09/28/22
Technical Report for
GRI (Geological Resources Inc.)
Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
3398
SGS Job Number: FA98898
Sampling Date: 09/13/22
Report to:
GRI
3502 Hayes Rd
Monroe, NC 28110
[e-mail]; [e-mail];
[e-mail]; [e-mail]
ATTN: William Regenthall
Total number of pages in report:
Certifications: FL(E83510), LA(03051), KS(E-10327), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AL, AK, AR, CT, IA, KY, MA, MI. MS, ND, NH, NV, OK, OR, IL, UT, VT, WA, WI, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc.  4405 Vineland Road  Suite C-15  Orlando, FL 32811  tel: [phone]  fax: [phone]
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Muna Mohammed 407-425-6700
Norm Farmer
Technical Director
Orlando, FL 09/28/22
e-Hardcopy 2.0
Automated Report
34
SGS is the sole authority for authorizing edits or modifications to this document.
Unauthorized modification of this report is strictly prohibited.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions
The results set forth herein are provided by SGS North America Inc.
Please share your ideas about
how we can serve you better at:
[e-mail]
1 of 34
FA98898
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................6
3.1: FA98898-1: MW-1 ........................................................................................................7
3.2: FA98898-2: MW-3 ........................................................................................................10
3.3: FA98898-3: MW-7 ........................................................................................................13
3.4: FA98898-4: MW-11 ......................................................................................................16
3.5: FA98898-5: TRIP BLANK ...........................................................................................19
Section 4: Misc. Forms ............................................................................................................22
4.1: Chain of Custody ...........................................................................................................23
Section 5: MS Volatiles - QC Data Summaries .....................................................................25
5.1: Method Blank Summary ................................................................................................26
5.2: Blank Spike Summary ...................................................................................................29
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................32
1
2
3
4
5
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FA98898
SGS North America Inc.
Sample Summary
GRI (Geological Resources Inc.)
Job No:FA98898
Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
Project No: 3398
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
This report contains results reported as ND = Not detected. The following applies:
Organics ND = Not detected above the MDL
FA98898-1 09/13/22 12:15 BH 09/14/22 AQ Ground Water MW-1
FA98898-2 09/13/22 12:25 BH 09/14/22 AQ Ground Water MW-3
FA98898-3 09/13/22 12:35 BH 09/14/22 AQ Ground Water MW-7
FA98898-4 09/13/22 12:45 BH 09/14/22 AQ Ground Water MW-11
FA98898-5 09/13/22 00:00 BH 09/14/22 AQ Trip Blank Water TRIP BLANK
3 of 34
FA98898
1
Summary of Hits Page 1 of 2
Job Number:FA98898
Account:GRI (Geological Resources Inc.)
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
Collected:09/13/22
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA98898-1 MW-1
1,2-Dichloroethane 0.24 J 0.50 0.13 ug/l SM 6200B
Methylene Chloride a 3.0 B 2.0 1.0 ug/l SM 6200B
Methyl Tert Butyl Ether 1.5 0.50 0.13 ug/l SM 6200B
FA98898-2 MW-3
Benzene 1770 100 25 ug/l SM 6200B
Ethylbenzene 1230 100 25 ug/l SM 6200B
Isopropylbenzene 25.2 J 100 25 ug/l SM 6200B
Methyl Chloride b 170 100 40 ug/l SM 6200B
Methylene Chloride a 830 B 400 200 ug/l SM 6200B
Naphthalene 131 100 25 ug/l SM 6200B
n-Propylbenzene 76.5 J 100 25 ug/l SM 6200B
Toluene 5560 100 25 ug/l SM 6200B
1,2,4-Trimethylbenzene 696 100 25 ug/l SM 6200B
1,3,5-Trimethylbenzene 210 100 25 ug/l SM 6200B
m,p-Xylene 4410 200 25 ug/l SM 6200B
o-Xylene 2140 100 25 ug/l SM 6200B
FA98898-3 MW-7
Benzene 59.7 1.0 0.25 ug/l SM 6200B
sec-Butylbenzene 0.59 0.50 0.13 ug/l SM 6200B
Chloroethane 0.62 0.50 0.20 ug/l SM 6200B
Ethylbenzene 1.3 0.50 0.13 ug/l SM 6200B
Isopropylbenzene 3.7 0.50 0.13 ug/l SM 6200B
p-Isopropyltoluene 0.37 J 0.50 0.13 ug/l SM 6200B
Methyl Chloride c 0.57 0.50 0.20 ug/l SM 6200B
Methylene Chloride a 2.9 B 2.0 1.0 ug/l SM 6200B
Naphthalene 0.62 0.50 0.13 ug/l SM 6200B
n-Propylbenzene 11.3 0.50 0.13 ug/l SM 6200B
1,2,4-Trimethylbenzene 0.16 J 0.50 0.13 ug/l SM 6200B
1,3,5-Trimethylbenzene 0.22 J 0.50 0.13 ug/l SM 6200B
o-Xylene 2.1 0.50 0.13 ug/l SM 6200B
FA98898-4 MW-11
Methylene Chloride a 2.6 B 2.0 1.0 ug/l SM 6200B
FA98898-5 TRIP BLANK
Methylene Chloride a 3.3 B 2.0 1.0 ug/l SM 6200B
4 of 34
FA98898
2
Summary of Hits Page 2 of 2
Job Number:FA98898
Account:GRI (Geological Resources Inc.)
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
Collected:09/13/22
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
(a) Associated CCV and BS outside control limits high. Suspected laboratory contaminant.
(b) Associated CCV outside control limits high.
(c) Associated CCV outside control limits high. Compound was below calibration range in higher dilution.
5 of 34
FA98898
2
SGS North America Inc.
Sample Results
Report of Analysis
Orlando, FL
Section 3
6 of 34
FA98898
3
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:MW-1
Lab Sample ID:FA98898-1 Date Sampled:09/13/22
Matrix:AQ - Ground Water Date Received:09/14/22
Method:SM 6200B Percent Solids:n/a
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0234439.D 1 09/21/22 18:42 SS n/a n/a VA3238
Run #2 a A0234491.D 1 09/23/22 20:00 SS n/a n/a VA3241
Purge Volume
Run #1 10.0 ml
Run #2 10.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane b ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane 0.24 0.50 0.13 ug/l J
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
7 of 34
FA98898
3
3.
1
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:MW-1
Lab Sample ID:FA98898-1 Date Sampled:09/13/22
Matrix:AQ - Ground Water Date Received:09/14/22
Method:SM 6200B Percent Solids:n/a
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide b ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride b ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide c ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride d 3.0 2.0 1.0 ug/l B
1634-04-4 Methyl Tert Butyl Ether 1.5 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 105%105%70-130%
17060-07-0 1,2-Dichloroethane-D4 111%107%70-130%
2037-26-5 Toluene-D8 101%99%70-130%
460-00-4 4-Bromofluorobenzene 106%106%70-130%
(a) Confirmation run for internal standard areas.
(b) Associated CCV outside control limits high, sample is ND.
(c) Associated BS recovery outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
8 of 34
FA98898
3
3.
1
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:MW-1
Lab Sample ID:FA98898-1 Date Sampled:09/13/22
Matrix:AQ - Ground Water Date Received:09/14/22
Method:SM 6200B Percent Solids:n/a
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
(d) Associated CCV and BS outside control limits high. Suspected laboratory contaminant.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
9 of 34
FA98898
3
3.
1
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:MW-3
Lab Sample ID:FA98898-2 Date Sampled:09/13/22
Matrix:AQ - Ground Water Date Received:09/14/22
Method:SM 6200B Percent Solids:n/a
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0234440.D 200 09/21/22 19:05 SS n/a n/a VA3238
Run #2 a A0234492.D 200 09/23/22 20:22 SS n/a n/a VA3241
Purge Volume
Run #1 10.0 ml
Run #2 10.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 1770 100 25 ug/l
108-86-1 Bromobenzene ND 100 25 ug/l
74-97-5 Bromochloromethane ND 100 25 ug/l
75-27-4 Bromodichloromethane ND 100 25 ug/l
75-25-2 Bromoform ND 100 25 ug/l
104-51-8 n-Butylbenzene ND 100 25 ug/l
135-98-8 sec-Butylbenzene ND 100 25 ug/l
98-06-6 tert-Butylbenzene ND 100 25 ug/l
56-23-5 Carbon Tetrachloride ND 100 25 ug/l
108-90-7 Chlorobenzene ND 100 25 ug/l
75-00-3 Chloroethane ND 100 40 ug/l
67-66-3 Chloroform ND 100 25 ug/l
95-49-8 o-Chlorotoluene ND 100 25 ug/l
106-43-4 p-Chlorotoluene ND 100 25 ug/l
124-48-1 Dibromochloromethane ND 100 25 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 100 49 ug/l
106-93-4 1,2-Dibromoethane ND 100 25 ug/l
75-71-8 Dichlorodifluoromethane b ND 100 40 ug/l
95-50-1 1,2-Dichlorobenzene ND 100 25 ug/l
541-73-1 1,3-Dichlorobenzene ND 100 25 ug/l
106-46-7 1,4-Dichlorobenzene ND 100 25 ug/l
75-34-3 1,1-Dichloroethane ND 100 25 ug/l
107-06-2 1,2-Dichloroethane ND 100 25 ug/l
75-35-4 1,1-Dichloroethylene ND 100 25 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 100 25 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 100 25 ug/l
78-87-5 1,2-Dichloropropane ND 100 25 ug/l
142-28-9 1,3-Dichloropropane ND 100 25 ug/l
594-20-7 2,2-Dichloropropane ND 100 25 ug/l
563-58-6 1,1-Dichloropropene ND 100 25 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 100 25 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 100 25 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Client Sample ID:MW-3
Lab Sample ID:FA98898-2 Date Sampled:09/13/22
Matrix:AQ - Ground Water Date Received:09/14/22
Method:SM 6200B Percent Solids:n/a
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 100 25 ug/l
100-41-4 Ethylbenzene 1230 100 25 ug/l
87-68-3 Hexachlorobutadiene ND 100 25 ug/l
98-82-8 Isopropylbenzene 25.2 100 25 ug/l J
99-87-6 p-Isopropyltoluene ND 100 25 ug/l
74-83-9 Methyl Bromide b ND 100 40 ug/l
74-87-3 Methyl Chloride c 170 100 40 ug/l
74-95-3 Methylene Bromide d ND 100 25 ug/l
75-09-2 Methylene Chloride e 830 400 200 ug/l B
1634-04-4 Methyl Tert Butyl Ether ND 100 25 ug/l
91-20-3 Naphthalene 131 100 25 ug/l
103-65-1 n-Propylbenzene 76.5 100 25 ug/l J
100-42-5 Styrene ND 100 25 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 100 25 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 100 25 ug/l
127-18-4 Tetrachloroethylene ND 100 25 ug/l
108-88-3 Toluene 5560 100 25 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 100 25 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 100 25 ug/l
71-55-6 1,1,1-Trichloroethane ND 100 25 ug/l
79-00-5 1,1,2-Trichloroethane ND 100 25 ug/l
79-01-6 Trichloroethylene ND 100 25 ug/l
75-69-4 Trichlorofluoromethane ND 100 40 ug/l
96-18-4 1,2,3-Trichloropropane ND 100 25 ug/l
95-63-6 1,2,4-Trimethylbenzene 696 100 25 ug/l
108-67-8 1,3,5-Trimethylbenzene 210 100 25 ug/l
75-01-4 Vinyl Chloride ND 100 25 ug/l
m,p-Xylene 4410 200 25 ug/l
95-47-6 o-Xylene 2140 100 25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 103%101%70-130%
17060-07-0 1,2-Dichloroethane-D4 110%105%70-130%
2037-26-5 Toluene-D8 107%104%70-130%
460-00-4 4-Bromofluorobenzene 104%104%70-130%
(a) Confirmation run.
(b) Associated CCV outside control limits high, sample is ND.
(c) Associated CCV outside control limits high.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Client Sample ID:MW-3
Lab Sample ID:FA98898-2 Date Sampled:09/13/22
Matrix:AQ - Ground Water Date Received:09/14/22
Method:SM 6200B Percent Solids:n/a
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
(d) Associated BS recovery outside control limits high, sample is ND.
(e) Associated CCV and BS outside control limits high. Suspected laboratory contaminant.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 3
Client Sample ID:MW-7
Lab Sample ID:FA98898-3 Date Sampled:09/13/22
Matrix:AQ - Ground Water Date Received:09/14/22
Method:SM 6200B Percent Solids:n/a
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0234444.D 1 09/21/22 20:37 SS n/a n/a VA3238
Run #2 A0234497.D 2 09/23/22 22:16 SS n/a n/a VA3241
Purge Volume
Run #1 10.0 ml
Run #2 10.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 59.7 a 1.0 0.25 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene 0.59 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane 0.62 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane b ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 3
Client Sample ID:MW-7
Lab Sample ID:FA98898-3 Date Sampled:09/13/22
Matrix:AQ - Ground Water Date Received:09/14/22
Method:SM 6200B Percent Solids:n/a
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene 1.3 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene 3.7 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene 0.37 0.50 0.13 ug/l J
74-83-9 Methyl Bromide b ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride c 0.57 0.50 0.20 ug/l
74-95-3 Methylene Bromide d ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride e 2.9 2.0 1.0 ug/l B
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene 0.62 0.50 0.13 ug/l
103-65-1 n-Propylbenzene 11.3 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene 0.16 0.50 0.13 ug/l J
108-67-8 1,3,5-Trimethylbenzene 0.22 0.50 0.13 ug/l J
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene 2.1 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 100%99%70-130%
17060-07-0 1,2-Dichloroethane-D4 106%102%70-130%
2037-26-5 Toluene-D8 105%102%70-130%
460-00-4 4-Bromofluorobenzene 103%107%70-130%
(a) Result is from Run# 2
(b) Associated CCV outside control limits high, sample is ND.
(c) Associated CCV outside control limits high. Compound was below calibration range in higher dilution.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Client Sample ID:MW-7
Lab Sample ID:FA98898-3 Date Sampled:09/13/22
Matrix:AQ - Ground Water Date Received:09/14/22
Method:SM 6200B Percent Solids:n/a
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
(d) Associated BS recovery outside control limits high, sample is ND.
(e) Associated CCV and BS outside control limits high. Suspected laboratory contaminant.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 3
Client Sample ID:MW-11
Lab Sample ID:FA98898-4 Date Sampled:09/13/22
Matrix:AQ - Ground Water Date Received:09/14/22
Method:SM 6200B Percent Solids:n/a
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0234445.D 1 09/21/22 21:00 SS n/a n/a VA3238
Run #2 a A0234498.D 1 09/23/22 22:39 SS n/a n/a VA3241
Purge Volume
Run #1 10.0 ml
Run #2 10.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane b ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 3
Client Sample ID:MW-11
Lab Sample ID:FA98898-4 Date Sampled:09/13/22
Matrix:AQ - Ground Water Date Received:09/14/22
Method:SM 6200B Percent Solids:n/a
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide b ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride b ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide c ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride d 2.6 2.0 1.0 ug/l B
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 103%102%70-130%
17060-07-0 1,2-Dichloroethane-D4 108%105%70-130%
2037-26-5 Toluene-D8 105%102%70-130%
460-00-4 4-Bromofluorobenzene 104%106%70-130%
(a) Confirmation run.
(b) Associated CCV outside control limits high, sample is ND.
(c) Associated BS recovery outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 3 of 3
Client Sample ID:MW-11
Lab Sample ID:FA98898-4 Date Sampled:09/13/22
Matrix:AQ - Ground Water Date Received:09/14/22
Method:SM 6200B Percent Solids:n/a
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
(d) Associated CCV and BS outside control limits high. Suspected laboratory contaminant.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Client Sample ID:TRIP BLANK
Lab Sample ID:FA98898-5 Date Sampled:09/13/22
Matrix:AQ - Trip Blank Water Date Received:09/14/22
Method:SM 6200B Percent Solids:n/a
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0234435.D 1 09/21/22 17:10 SS n/a n/a VA3238
Run #2 a A0234488.D 1 09/23/22 18:52 SS n/a n/a VA3241
Purge Volume
Run #1 10.0 ml
Run #2 10.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane b ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 3
Client Sample ID:TRIP BLANK
Lab Sample ID:FA98898-5 Date Sampled:09/13/22
Matrix:AQ - Trip Blank Water Date Received:09/14/22
Method:SM 6200B Percent Solids:n/a
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide b ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride b ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide c ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride d 3.3 2.0 1.0 ug/l B
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 104%103%70-130%
17060-07-0 1,2-Dichloroethane-D4 108%104%70-130%
2037-26-5 Toluene-D8 107%106%70-130%
460-00-4 4-Bromofluorobenzene 104%104%70-130%
(a) Confirmation run for internal standard areas.
(b) Associated CCV outside control limits high, sample is ND.
(c) Associated BS recovery outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 3 of 3
Client Sample ID:TRIP BLANK
Lab Sample ID:FA98898-5 Date Sampled:09/13/22
Matrix:AQ - Trip Blank Water Date Received:09/14/22
Method:SM 6200B Percent Solids:n/a
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
(d) Associated CCV and BS outside control limits high. Suspected laboratory contaminant.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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SGS North America Inc.
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
 Chain of Custody
Orlando, FL
Section 4
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FA98898: Chain of Custody
Page 1 of 2
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Job Number:FA98898 Client:GEOLOGICAL RESOURCES INC.
Date / Time Received:9/14/2022 9:30:00 AM Delivery Method:FEDEX
Project:RICH SQUARE TIRE CENTRE
Airbill #'s:1009 6378 4482
Cooler Information
1. Custody Seals Present
2. Custody Seals Intact
4. Cooler temp verification
3. Temp criteria achieved
5. Cooler media
IR Gun
Ice (Bag)
Trip Blank Information
1. Trip Blank present / cooler
2. Trip Blank listed on COC
2. Samples preserved properly
Sample Information
1. Sample labels present on bottles
5. Sample recvd within HT
4. Condition of sample
3. Sufficient volume/containers recvd for analysis:
Intact
Comments
SM001Rev. Date 05/24/17
SGS Sample Receipt Summary
Cooler Temps (Raw Measured) °C:
Cooler Temps (Corrected) °C:
Cooler 1: (0.4);
Cooler 1: (1.0);
3. Type Of TB Received
W or S N/A
6. Dates/Times/IDs on COC match Sample Label
7. VOCs have headspace
8. Bottles received for unspecified tests
9. Compositing instructions clear
10. Voa Soil Kits/Jars received past 48hrs?
11. % Solids Jar received?
Misc. Information
25-Gram 5-GramNumber of Encores:Number of 5035 Field Kits:Number of Lab Filtered Metals:
Test Strip Lot #s:pH 0-3 230315 pH 10-12 219813A Other: (Specify)
Y or N N/A
Y or N
Therm ID:IR 1; Therm CF:0.6; # of Coolers:1
Y or N N/A
12. Residual Chlorine Present?
Residual Chlorine Test Strip Lot #:
Technician:Reviewer:CARLOSD Date:Date:9/14/2022 9:30:00 AM
FA98898: Chain of Custody
Page 2 of 2
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SGS North America Inc.
MS Volatiles
QC Data Summaries
Includes the following where applicable:
 Method Blank Summaries
 Blank Spike Summaries
 Matrix Spike and Duplicate Summaries
Orlando, FL
Section 5
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Method Blank Summary Page 1 of 2
Job Number:FA98898
Account:GRINCC GRI (Geological Resources Inc.)
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3238-MB A0234434.D 1 09/21/22 SS n/a n/a VA3238
The QC reported here applies to the following samples:Method: SM 6200B
FA98898-1, FA98898-2, FA98898-3, FA98898-4, FA98898-5
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
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Method Blank Summary Page 2 of 2
Job Number:FA98898
Account:GRINCC GRI (Geological Resources Inc.)
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3238-MB A0234434.D 1 09/21/22 SS n/a n/a VA3238
The QC reported here applies to the following samples:Method: SM 6200B
FA98898-1, FA98898-2, FA98898-3, FA98898-4, FA98898-5
CAS No.Compound Result RL MDL Units Q
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride 3.5 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 101%70-130%
17060-07-0 1,2-Dichloroethane-D4 107%70-130%
2037-26-5 Toluene-D8 108%70-130%
460-00-4 4-Bromofluorobenzene 104%70-130%
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Method Blank Summary Page 1 of 1
Job Number:FA98898
Account:GRINCC GRI (Geological Resources Inc.)
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3241-MB A0234487.D 1 09/23/22 SS n/a n/a VA3241
The QC reported here applies to the following samples:Method: SM 6200B
FA98898-3
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 102%70-130%
17060-07-0 1,2-Dichloroethane-D4 104%70-130%
2037-26-5 Toluene-D8 105%70-130%
460-00-4 4-Bromofluorobenzene 105%70-130%
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Blank Spike Summary Page 1 of 2
Job Number:FA98898
Account:GRINCC GRI (Geological Resources Inc.)
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3238-BS A0234432.D 1 09/21/22 SS n/a n/a VA3238
The QC reported here applies to the following samples:Method: SM 6200B
FA98898-1, FA98898-2, FA98898-3, FA98898-4, FA98898-5
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 10.4 104 70-130
108-86-1 Bromobenzene 10 8.9 89 70-130
74-97-5 Bromochloromethane 10 9.6 96 70-130
75-27-4 Bromodichloromethane 10 10.3 103 70-130
75-25-2 Bromoform 10 8.9 89 70-130
104-51-8 n-Butylbenzene 10 10 100 70-130
135-98-8 sec-Butylbenzene 10 11.4 114 70-130
98-06-6 tert-Butylbenzene 10 10.6 106 70-130
56-23-5 Carbon Tetrachloride 10 11.8 118 70-130
108-90-7 Chlorobenzene 10 9.9 99 70-130
75-00-3 Chloroethane 10 17.8 178*60-140
67-66-3 Chloroform 10 10.4 104 70-130
95-49-8 o-Chlorotoluene 10 11.0 110 70-130
106-43-4 p-Chlorotoluene 10 10.5 105 70-130
124-48-1 Dibromochloromethane 10 9.3 93 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 10.4 104 70-130
106-93-4 1,2-Dibromoethane 10 9.8 98 70-130
75-71-8 Dichlorodifluoromethane 10 11.3 113 60-140
95-50-1 1,2-Dichlorobenzene 10 9.9 99 70-130
541-73-1 1,3-Dichlorobenzene 10 10.0 100 70-130
106-46-7 1,4-Dichlorobenzene 10 10 100 70-130
75-34-3 1,1-Dichloroethane 10 11.4 114 70-130
107-06-2 1,2-Dichloroethane 10 10 100 70-130
75-35-4 1,1-Dichloroethylene 10 11.3 113 70-130
156-59-2 cis-1,2-Dichloroethylene 10 10.2 102 70-130
156-60-5 trans-1,2-Dichloroethylene 10 11.0 110 70-130
78-87-5 1,2-Dichloropropane 10 10.2 102 70-130
142-28-9 1,3-Dichloropropane 10 9.6 96 70-130
594-20-7 2,2-Dichloropropane 10 9.9 99 70-130
563-58-6 1,1-Dichloropropene 10 10.7 107 70-130
10061-01-5 cis-1,3-Dichloropropene 10 9.3 93 70-130
10061-02-6 trans-1,3-Dichloropropene 10 10 100 70-130
108-20-3 Di-Isopropyl Ether 10 10.2 102 70-130
100-41-4 Ethylbenzene 10 10.5 105 70-130
87-68-3 Hexachlorobutadiene 10 8.3 83 70-130
98-82-8 Isopropylbenzene 10 10.6 106 70-130
* = Outside of Control Limits.
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Blank Spike Summary Page 2 of 2
Job Number:FA98898
Account:GRINCC GRI (Geological Resources Inc.)
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3238-BS A0234432.D 1 09/21/22 SS n/a n/a VA3238
The QC reported here applies to the following samples:Method: SM 6200B
FA98898-1, FA98898-2, FA98898-3, FA98898-4, FA98898-5
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
99-87-6 p-Isopropyltoluene 10 10.3 103 70-130
74-83-9 Methyl Bromide 10 16.4 164*60-140
74-87-3 Methyl Chloride 10 13.9 139 60-140
74-95-3 Methylene Bromide 10 9.5 95 70-130
75-09-2 Methylene Chloride 10 13.4 134*70-130
1634-04-4 Methyl Tert Butyl Ether 10 10.9 109 70-130
91-20-3 Naphthalene 10 9.4 94 70-130
103-65-1 n-Propylbenzene 10 11.1 111 70-130
100-42-5 Styrene 10 9.7 97 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 10.3 103 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 11.0 110 70-130
127-18-4 Tetrachloroethylene 10 9.6 96 70-130
108-88-3 Toluene 10 10.2 102 70-130
87-61-6 1,2,3-Trichlorobenzene 10 8.7 87 70-130
120-82-1 1,2,4-Trichlorobenzene 10 8.8 88 70-130
71-55-6 1,1,1-Trichloroethane 10 10.7 107 70-130
79-00-5 1,1,2-Trichloroethane 10 10.4 104 70-130
79-01-6 Trichloroethylene 10 10.2 102 70-130
75-69-4 Trichlorofluoromethane 10 10.7 107 60-140
96-18-4 1,2,3-Trichloropropane 10 9.5 95 70-130
95-63-6 1,2,4-Trimethylbenzene 10 10.8 108 70-130
108-67-8 1,3,5-Trimethylbenzene 10 10.5 105 70-130
75-01-4 Vinyl Chloride 10 11.0 110 60-140
m,p-Xylene 20 20.4 102 70-130
95-47-6 o-Xylene 10 10.6 106 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 100%70-130%
17060-07-0 1,2-Dichloroethane-D4 103%70-130%
2037-26-5 Toluene-D8 103%70-130%
460-00-4 4-Bromofluorobenzene 101%70-130%
* = Outside of Control Limits.
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Blank Spike Summary Page 1 of 1
Job Number:FA98898
Account:GRINCC GRI (Geological Resources Inc.)
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3241-BS A0234485.D 1 09/23/22 SS n/a n/a VA3241
The QC reported here applies to the following samples:Method: SM 6200B
FA98898-3
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 10.1 101 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 99%70-130%
17060-07-0 1,2-Dichloroethane-D4 99%70-130%
2037-26-5 Toluene-D8 102%70-130%
460-00-4 4-Bromofluorobenzene 103%70-130%
* = Outside of Control Limits.
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Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FA98898
Account:GRINCC GRI (Geological Resources Inc.)
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA98898-2MS A0234441.D 200 09/21/22 SS n/a n/a VA3238
FA98898-2MSD A0234442.D 200 09/21/22 SS n/a n/a VA3238
FA98898-2 A0234440.D 200 09/21/22 SS n/a n/a VA3238
The QC reported here applies to the following samples:Method: SM 6200B
FA98898-1, FA98898-2, FA98898-3, FA98898-4, FA98898-5
FA98898-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 1770 2000 3740 99 2000 3950 109 5 70-130/20
108-86-1 Bromobenzene ND 2000 1700 85 2000 1850 93 8 70-130/20
74-97-5 Bromochloromethane ND 2000 1760 88 2000 1970 99 11 70-130/20
75-27-4 Bromodichloromethane ND 2000 1980 99 2000 2220 111 11 70-130/20
75-25-2 Bromoform ND 2000 1780 89 2000 1930 97 8 70-130/20
104-51-8 n-Butylbenzene ND 2000 1930 97 2000 2120 106 9 70-130/20
135-98-8 sec-Butylbenzene ND 2000 2250 113 2000 2400 120 6 70-130/20
98-06-6 tert-Butylbenzene ND 2000 2120 106 2000 2270 114 7 70-130/20
56-23-5 Carbon Tetrachloride ND 2000 2190 110 2000 2420 121 10 70-130/20
108-90-7 Chlorobenzene ND 2000 1910 96 2000 2080 104 9 70-130/20
75-00-3 Chloroethane ND 2000 3700 185*2000 4770 239*25*60-140/20
67-66-3 Chloroform ND 2000 2010 101 2000 2160 108 7 70-130/20
95-49-8 o-Chlorotoluene ND 2000 2160 108 2000 2350 118 8 70-130/20
106-43-4 p-Chlorotoluene ND 2000 1960 98 2000 2170 109 10 70-130/20
124-48-1 Dibromochloromethane ND 2000 1780 89 2000 1960 98 10 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 2000 2070 104 2000 2280 114 10 70-130/20
106-93-4 1,2-Dibromoethane ND 2000 1730 87 2000 1960 98 12 70-130/20
75-71-8 Dichlorodifluoromethane ND 2000 2150 108 2000 2690 135 22*60-140/20
95-50-1 1,2-Dichlorobenzene ND 2000 1890 95 2000 2060 103 9 70-130/20
541-73-1 1,3-Dichlorobenzene ND 2000 1920 96 2000 2090 105 8 70-130/20
106-46-7 1,4-Dichlorobenzene ND 2000 1860 93 2000 2050 103 10 70-130/20
75-34-3 1,1-Dichloroethane ND 2000 2220 111 2000 2390 120 7 70-130/20
107-06-2 1,2-Dichloroethane ND 2000 1910 96 2000 2110 106 10 70-130/20
75-35-4 1,1-Dichloroethylene ND 2000 2300 115 2000 2350 118 2 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 2000 1890 95 2000 2100 105 11 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 2000 2260 113 2000 2300 115 2 70-130/20
78-87-5 1,2-Dichloropropane ND 2000 1960 98 2000 2140 107 9 70-130/20
142-28-9 1,3-Dichloropropane ND 2000 1780 89 2000 1960 98 10 70-130/20
594-20-7 2,2-Dichloropropane ND 2000 1780 89 2000 2010 101 12 70-130/20
563-58-6 1,1-Dichloropropene ND 2000 2000 100 2000 2220 111 10 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 2000 1750 88 2000 1970 99 12 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 2000 1850 93 2000 2050 103 10 70-130/20
108-20-3 Di-Isopropyl Ether ND 2000 2000 100 2000 2140 107 7 70-130/20
100-41-4 Ethylbenzene 1230 2000 3280 103 2000 3460 112 5 70-130/20
87-68-3 Hexachlorobutadiene ND 2000 1620 81 2000 1740 87 7 70-130/20
98-82-8 Isopropylbenzene 25.2 J 2000 2060 102 2000 2240 111 8 70-130/20
* = Outside of Control Limits.
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Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FA98898
Account:GRINCC GRI (Geological Resources Inc.)
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA98898-2MS A0234441.D 200 09/21/22 SS n/a n/a VA3238
FA98898-2MSD A0234442.D 200 09/21/22 SS n/a n/a VA3238
FA98898-2 A0234440.D 200 09/21/22 SS n/a n/a VA3238
The QC reported here applies to the following samples:Method: SM 6200B
FA98898-1, FA98898-2, FA98898-3, FA98898-4, FA98898-5
FA98898-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
99-87-6 p-Isopropyltoluene ND 2000 1980 99 2000 2140 107 8 70-130/20
74-83-9 Methyl Bromide ND 2000 4550 228*2000 4360 218*4 60-140/20
74-87-3 Methyl Chloride 170 2000 3220 153*2000 3470 165*7 60-140/20
74-95-3 Methylene Bromide ND 2000 1820 91 2000 2030 102 11 70-130/20
75-09-2 Methylene Chloride 830 B 2000 2920 105 2000 2990 108 2 70-130/20
1634-04-4 Methyl Tert Butyl Ether ND 2000 2010 101 2000 2310 116 14 70-130/20
91-20-3 Naphthalene 131 2000 1930 90 2000 2180 102 12 70-130/20
103-65-1 n-Propylbenzene 76.5 J 2000 2180 105 2000 2400 116 10 70-130/20
100-42-5 Styrene ND 2000 1820 91 2000 2010 101 10 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 2000 2000 100 2000 2140 107 7 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 2000 2140 107 2000 2350 118 9 70-130/20
127-18-4 Tetrachloroethylene ND 2000 1840 92 2000 1950 98 6 70-130/20
108-88-3 Toluene 5560 2000 7070 76 2000 7300 87 3 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 2000 1640 82 2000 1820 91 10 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 2000 1660 83 2000 1850 93 11 70-130/20
71-55-6 1,1,1-Trichloroethane ND 2000 1990 100 2000 2200 110 10 70-130/20
79-00-5 1,1,2-Trichloroethane ND 2000 2040 102 2000 2170 109 6 70-130/20
79-01-6 Trichloroethylene ND 2000 1970 99 2000 2130 107 8 70-130/20
75-69-4 Trichlorofluoromethane ND 2000 2250 113 2000 2630 132 16 60-140/20
96-18-4 1,2,3-Trichloropropane ND 2000 1730 87 2000 1950 98 12 70-130/20
95-63-6 1,2,4-Trimethylbenzene 696 2000 2980 114 2000 3190 125 7 70-130/20
108-67-8 1,3,5-Trimethylbenzene 210 2000 2310 105 2000 2490 114 8 70-130/20
75-01-4 Vinyl Chloride ND 2000 2240 112 2000 2750 138 20 60-140/20
m,p-Xylene 4410 4000 8290 97 4000 8740 108 5 70-130/20
95-47-6 o-Xylene 2140 2000 4220 104 2000 4440 115 5 70-130/20
CAS No.Surrogate Recoveries MS MSD FA98898-2 Limits
1868-53-7 Dibromofluoromethane 99%99%103%70-130%
17060-07-0 1,2-Dichloroethane-D4 100%105%110%70-130%
2037-26-5 Toluene-D8 105%104%107%70-130%
460-00-4 4-Bromofluorobenzene 99%101%104%70-130%
* = Outside of Control Limits.
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Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1
Job Number:FA98898
Account:GRINCC GRI (Geological Resources Inc.)
Project:Rich Square Tire Center; 413 E Jackson St, Rich Square, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA98898-2MS A0234493.D 200 09/23/22 SS n/a n/a VA3241
FA98898-2MSD A0234494.D 200 09/23/22 SS n/a n/a VA3241
FA98898-2 a A0234492.D 200 09/23/22 SS n/a n/a VA3241
The QC reported here applies to the following samples:Method: SM 6200B
FA98898-3
FA98898-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 1670 2000 3690 101 2000 3740 104 1 70-130/20
CAS No.Surrogate Recoveries MS MSD FA98898-2 Limits
1868-53-7 Dibromofluoromethane 97%99%101%70-130%
17060-07-0 1,2-Dichloroethane-D4 97%98%105%70-130%
2037-26-5 Toluene-D8 100%102%104%70-130%
460-00-4 4-Bromofluorobenzene 101%103%104%70-130%
(a) Confirmation run.
* = Outside of Control Limits.
34 of 34
FA98898
5
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2