AS-1478_16199_CA_CSA_20230607_Revised Addendum

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]

June 7, 2023

Ms. Katie Bernal
NCDEQ-UST Section
Asheville Regional Office
2090 US Highway 70
Swannanoa, NC 28778

Re: Comprehensive Site Assessment Addendum Report
November 2022 – January 2023
Former Philbeck’s Amoco
1319 South Post Road
Shelby, Cleveland County
North Carolina
Facility ID Number: 00-0-0000012594
Incident Number: 16199
GRI Project Number: 5888

Dear Ms. Bernal,

Please find enclosed the referenced report for the abovementioned site.
If you have any questions, please contact Sam McKay at 704-845-4010.

Sincerely,
Geological Resources, Inc.

Leslie Maxtone-Graham
Administrative Assistant

Enclosure

Cc: Ms. Kay Piercy; Arey Oil Company, Inc., file

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Engineering Certification: C-2727 • Geology Certification: C-127
Comprehensive Site Assessment Addendum Report
November 2022 - January 2023
Former Philbeck’s Amoco
1319 South Post Road
Shelby, Cleveland County
North Carolina
Facility ID Number: 00-0-0000012594
Incident Number: 16199
GRI Project Number: 5888

Prepared for:

Ms. Kay Piercy
Arey Oil Company, Inc.
P.O. Box 2529
Shelby, North Carolina 28151

June 7, 2023

Project Manager Report Writer

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Addendum Report
Prepared on: June 7, 2023 Former Philbeck’s Amoco
Project Manager: Samuel L. McKay, III, P.G. GRI Project No. 5888
i
EXECUTIVE SUMMARY
Former Philbeck’s Amoco is located at 1319 South Post Road in Shelby, Cleveland County, North Carolina.
The site is currently owned by Hanumanta, LLC and was a former petroleum retail facility originally
operated by Arey Oil Company. Petroleum-contaminated soil was discovered at the site during UST
closure activities in November and December 1995. Currently, one compartmentalized UST is present at
the site. GRI personnel were able to confirm the site is currently being used as a petroleum retail facility,
convenience store, and a residence. The surrounding properties are a mixture of multi-family and single-
family residential properties, with a few commercial properties. According to the information determined
during updated receptor survey activities conducted on March 14, 2022, eighteen properties assumed to
have water supply wells were identified within 1,000 feet of the site. Two water supply wells (WSW-15
and WSW-16) are located within 250’ of the source area. The properties associated with water supply
wells (WSW-15 and WSW-16) are connected to municipal water and the wells are not potable. Water
supply well WSW-14 is located approximately 340 feet east of the source area and is active and potable.

On May 17, 1996, one monitoring well (MW-1) was installed and sampled as part of LSA activities. Based
on the results of the LSA activities, a CSA was required. CSA activities were conducted by Southeastern
Geological Services between December 1996 and June, 1997.

On December 15, 1997, a previous consultant submitted a CAP that proposed to install a soil vapor
extraction and air sparge system to reduce petroleum contamination in soil and ground water. Another
previous consultant submitted a CAP Addendum in November 1998 which proposed to excavate and
remediate soil from the source area. On November 23 and 24, 1998, 389.41 tons of petroleum-
contaminated soil were excavated from the release area.

On November 8, 2022, two additional Type II monitoring wells (MW-12 and MW-13) were installed at the
site. Soil samples were collected from approximately 17 and 16 feet BGS during the installation of
monitoring wells MW-12 and MW-13, respectively, and submitted for laboratory analysis. The
concentration of benzene, toluene, xylenes, naphthalene, n-propylbenzene, p-isopropyltoluene, 1,2,4-
trimethylbenzene, 1,3,5-trimethylbenzene, 1-methylnaphthalene, C9-C10 aromatics, and C11-C22
aromatics in soil sample MW-13 exceeded the MCCs. All contaminant concentrations were below the
residential SCLs.

On December 13, 2022, one 8-hour AFVR event was conducted at monitoring well MW-1A on the site. A
total of 463 gallons of petroleum-contaminated ground water was removed from MW-1A during this
event. Approximately 1.04 gallons of vapor-phase hydrocarbons were removed from MW-1A during the
event. No liquid free product was encountered during the AFVR. On January 16, 2023, approximately 30
days post-AFVR, a comprehensive ground water sampling event was conducted at the site. The
contaminant concentrations of benzene, toluene, ethylbenzene, xylenes, MTBE, naphthalene, 2-
hexanone, MIBK, isopropylbenzene, n-propylbenzene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene,
1-methylnaphthalene, 2-methylnaphthalene, C5-C8 aliphatics, C9-C12 aliphatics, C9-C10 aromatics,
and/or C11-C22 aromatics in the ground water samples collected from MW-1A, MW-5, and MW-13

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Addendum Report
Prepared on: June 7, 2023 Former Philbeck’s Amoco
Project Manager: Samuel L. McKay, III, P.G. GRI Project No. 5888
ii
exceeded the MACs. Although the concentrations of MIBK and 2-hexanone exceeded the MACs, these
contaminants are not petroleum constituents. The concentrations of benzene reported in the ground
water samples collected from MW-1A and MW-13 exceeded the GCLs. Free product has not been
observed at the site.

Based on observations made during previous and current assessment activities, surficial soils observed at
the site consist of silty clays and silty sands. Bedrock was encountered at approximately 90 feet BGS during
the installation of MW-5 by a previous consultant. Ground water flow was generally to the northeast. The
horizontal hydraulic gradient across the site was calculated between MW-7 and MW-12 and was
approximately 0.022 feet per foot. The vertical gradient was calculated between MW-5 and MW-11 and
was approximately 0.060 feet per foot in the downward direction. Rising head slug tests were conducted
on MW-1, MW-3, and MW-4 on June 1, 1997 by a previous consultant.

Based on this information, the risk classification for the site should remain High. Municipal water
connection agreements should be sent to the residents and owners of WSW-14. Water supply wells WSW-
14, 15, and 16 should be abandoned in order to lower the risk ranking of the site. Additional
recommendations for corrective action can be made once it is determined whether WSW-14 will connect
to municipal water and if WSW-15 and WSW-16 can be abandoned. A longer period AFVR or MMPE event
should be conducted at the site to lower concentrations of dissolved phase product in the groundwater
at monitoring wells MW-1A and MW-13. A feasibility study should be conducted to determine the best
course of action for incident closure.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Addendum Report
Prepared on: June 7, 2023 Former Philbeck’s Amoco
Project Manager: Samuel L. McKay, III, P.G. GRI Project No. 5888
iii
SITE INFORMATION
1. Site Identification
 Former Philbeck’s Amoco (Facility ID 00-0-0000012594)
 Incident Number 16199 – High Risk (H260D)
 Location of Source Area: 1319 South Post Road
Shelby, NC 28152
Cleveland County
35.250494°N, 81.506816°W (Topographical Map)
2. Information about Contacts Associated with the Leaking UST System

UST/AST Owner
Arey Oil Company, Inc.
1906 East Dixon Boulevard
Shelby, NC 28152
Email Unknown
704-482-1445

UST/AST Operator
Arey Oil Company, Inc.
1906 East Dixon Boulevard
Shelby, NC 28152
Email Unknown
704-482-1445

Property Owner
Hanumanta, LLC
401 Black Oak Court
Spartanburg, SC 29306
Email Unknown
Phone No. Unknown

Property Occupant
Hanumanta, LLC
401 Black Oak Court
Spartanburg, SC 29306
Email Unknown
Phone No. Unknown

Consultant/Contractor
Geological Resources, Inc.
3502 Hayes Road
Monroe, NC 28110
[e-mail]
704-845-4010

Analytical Laboratory
Waypoint Analytical, LLC
449 Springbrook Road,
Charlotte, NC 28217
State Cert. No. 37735 and 402
704-529-6364
3. Information about Release
 Release was discovered on November 28, 1995
 An unknown amount of product was released from the leaking UST System
 One compartmentalized gasoline UST is currently in use at the site.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Addendum Report
Prepared on: June 7, 2023 Former Philbeck’s Amoco
Project Manager: Samuel L. McKay, III, P.G. GRI Project No. 5888
iv
ACRONYMS
ACM: Asbestos Containing Materials
AFVR: Aggressive Fluid-Vapor Recovery
ARR: Acknowledgement of Report Receipt
AS: Air Sparging
AST: Aboveground Storage Tank
ASTM: American Society for Testing and
Materials
BGS: Below Ground Surface
CAP: Corrective Action Plan
CFR: Code of Federal Regulations
CSA: Comprehensive Site Assessment
DPE: Dual Phase Extraction
DRO: Total Petroleum Hydrocarbons Diesel
Range Organics
DWM: Division of Waste Management
DWR: Department of Water Resources
EPA: Environmental Protection Agency
EPH: Extractible Petroleum Hydrocarbons
ESA: Environmental Site Assessment
GCL: Gross Contamination Level
GRI: Geological Resources, Inc.
GRO: Total Petroleum Hydrocarbons
Gasoline Range Organics
LSA: Limited Site Assessment
MAC: Maximum Allowable Concentration as
specified in T15A NCAC 2L.0202
MADEP: Massachusetts Department of
Environmental Protection
MCC: Maximum Contaminant
Concentrations
MMPE: Mobile Multi-Phase Extraction
NAPL: Non-Aqueous Phase Liquid, “Free
Product”
NCDEQ: North Carolina Department of
Environmental Quality
NCDOT: North Carolina Department of
Transportation
NFA: Notice of No Further Action
NORR: Notice of Regulatory Requirements
NOV: Notice of Violation
NPDES: National Pollutant Discharge
Elimination System
NRP: Notice of Residual Petroleum
O&M: Operation and Maintenance
PAHs: Polynuclear Aromatic Hydrocarbons
PCA: Pre-Construction Assessment
RAL: Regulatory Action Level
SCLs: Soil Cleanup Level
SPCC: Spill Prevention Control and
Countermeasures
SVE: Soil Vapor Extraction
SVOCs: Semi-Volatile Organic Compounds
SWPPP: Stormwater Pollution Prevention Plan
TCLP: Toxicity Characteristic Leaching
Procedure (EPA Method SW-846 1311)
TOC: Top of Casing
TPH: Total Petroleum Hydrocarbons
USGS: United States Geological Survey
UST: Underground Storage Tank
UVF: Ultraviolet Fluorescence
VOCs: Volatile Organic Compounds
VPH: Volatile Petroleum Hydrocarbons

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Addendum Report
Prepared on: June 7, 2023 Former Philbeck’s Amoco
Project Manager: Samuel L. McKay, III, P.G. GRI Project No. 5888
TABLE OF CONTENTS
EXECUTIVE SUMMARY ....................................................................................................................... i
SITE INFORMATION ........................................................................................................................... iii
ACRONYMS ....................................................................................................................................... iv
1.0 SITE HISTORY AND CHARACTERIZATION ...................................................................................1
2.0 RECEPTOR INFORMATION ........................................................................................................3
3.0 LAND USE ................................................................................................................................3
4.0 SOIL ASSESSMENT ...................................................................................................................4
5.0 GROUND WATER ASSESSMENT ................................................................................................5
6.0 HYDROGEOLOGIC INVESTIGATION ...........................................................................................7
7.0 REGIONAL GEOLOGY AND HYDROGEOLOGY .............................................................................7
8.0 SITE GEOLOGY AND HYDROGEOLOGY ......................................................................................7
9.0 DISCUSSION ............................................................................................................................8
10.0 CONCLUSIONS AND RECOMMENDATIONS ...............................................................................8
11.0 LIMITATIONS ...........................................................................................................................9
12.0 REFERENCES .......................................................................................................................... 10

FIGURES
Figure 1: Site Location Map
Figure 2: Site Map
Figure 3A: Site Vicinity Map
Figure 3B: Zoning Map
Figure 4: Soil Sample Location Map
Figure 5: Soil Quality Map
Figure 6: Cross-Section A-A’
Figure 7: Cross-Section B-B’
Figure 8: Ground Water Quality Map
Figure 9: Benzene Isoconcentration Map
Figure 10: Toluene Isoconcentration Map
Figure 11: Ethylbenzene Isoconcentration Map
Figure 12: Xylenes Isoconcentration Map
Figure 13: MTBE Isoconcentration Map
Figure 14: Naphthalene Isoconcentration Map
Figure 15: Benzene Isoconcentration Map – Telescoping Well
Figure 16: MTBE Isoconcentration Map – Telescoping Well
Figure 17: Water Table Surface Map

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Addendum Report
Prepared on: June 7, 2023 Former Philbeck’s Amoco
Project Manager: Samuel L. McKay, III, P.G. GRI Project No. 5888
TABLES
Table 1: UST Owner and Operator Information
Table 2: UST System Information
Table 3: Receptor Information
Table 4: Adjacent Property Owner Information
Table 5: Land Use Information
Table 6: Summary of Soil Sample Analytical Results
Table 7: Summary of Ground Water Sample Analytical Results
Table 8: Free Product Recovery Results
Table 9: Free Product Recovery Event Information
Table 10: Free Product Recovery Cost Summary
Table 11: Well Construction and Gauging Information

APPENDICES
Appendix A: State Correspondence
Appendix B: Historical Soil Information
Appendix C: Laboratory Analytical Reports
Appendix D: Historical Slug Test Data
Appendix E: AFVR Event Data Sheet and Disposal Manifest
Appendix F: Well Permit, Well Construction Records, and Subsurface Logs

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Addendum Report
Prepared on: June 7, 2023 Former Philbeck’s Amoco
Project Manager: Samuel L. McKay, III, P.G. GRI Project No. 5888
1
1.0 SITE HISTORY AND CHARACTERIZATION
GRI presents the results Comprehensive Site Assessment Addendum through the November 2022
monitoring well installation and soil sampling event, the December 2022 AFVR, and the January 2023
comprehensive ground water sampling event at the Former Philbeck’s Amoco site. The site is located at
1319 South Post Road in Shelby, Cleveland County, North Carolina. A topographic map showing the
general site location and the surrounding area is included as Figure 1. These activities were conducted in
accordance with GRI Proposal No. 22-336, which was submitted to the NCDEQ on August 4, 2022, and was
approved as Task Authorization No. 16199-21 on August 19, 2022. Three change orders were submitted
to NCDEQ on September 16, 2022, November 8, 2022, and November 21, 2022, and were approved as
Task Authorization Nos. 16199-21.1, 16199-21.2, and 16199-21.3 on September 29, 2022, November 9,
2022, and November 30, 2022, respectively. State correspondence is included as Appendix A.

The site is currently owned by Hanumanta LLC and is a former and current petroleum retail facility.
Petroleum-contaminated soil was discovered at the site during UST closure activities in November and
December 1995. Currently, one compartmentalized gasoline UST is in use at the site. UST owner/operator
information and UST system information are included as Tables 1 and 2, respectively. The Registered
Tank Report is shown below:

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Addendum Report
Prepared on: June 7, 2023 Former Philbeck’s Amoco
Project Manager: Samuel L. McKay, III, P.G. GRI Project No. 5888
2
According to the LSA report from Southeastern Geological Services, soil contamination was noted beneath
all four gasoline tanks during UST removal activities conducted in November and December, 1995. On
November 23 and 24, 1998, 389.41 tons of petroleum-contaminated soil were removed from the site. The
UST basins were all excavated to a depth of approximately 13 feet BGS, whereupon ground water was
encountered. The samples indicated the presence of gasoline contamination in the soil beneath both UST
basins, which also extended into the water table. A release was reported on November 29, 1995.

Southeastern Geological Services conducted UST Removal, LSA, and CSA activities at the site between
November 1995 and June 1997. Nine Type II monitoring wells (MW-1 through MW-4 and MW-6 through
MW-10) and one Type III telescoping well (MW-5) were installed at the site during LSA and CSA activities.
Seven soil borings were advanced to a depth of 10 feet BGS in the vicinity of both former UST basins. Two
additional monitoring wells (MW-11 and MW-12) were installed after CSA activities and MW-X was
installed as part of Pre-CAP activities. CAP addendum activities were conducted by Delta Environmental
Consultants, Inc. in November 1998. During CAP Addendum activities, 389.41 tons of petroleum-
contaminated soil were removed from the site. Monitoring wells MW-1 and MW-12 were destroyed
during soil excavation activities. A replacement Type II monitoring well (MW-1A) was installed in the
southern UST basin on December 28, 1998.

GRI personnel conducted ground water sampling and updated receptor survey activities on January 19,
2022. However, due to snow cover, an additional ground water monitoring event and updated receptor
survey were conducted on March 14, 2022. Eighteen properties assumed to have water supply wells were
identified within 1,500 feet of the site. One water supply well (WSW-14) is active and potable, and two
water supply wells (WSW-15 and WSW-16) are located within 250 feet of the source area.

On November 8, 2022, two additional Type II monitoring wells (MW-12 and MW-13) were installed at the
site. Both MW-12 and MW-13 were installed downgradient of the UST basin and were each completed to
30 feet BGS with a 10-foot screened interval. Soil samples were collected from approximately 17 and 16
feet BGS during the installation of monitoring wells MW-12 and MW-13, respectively, and submitted for
laboratory analysis. The concentration of benzene, toluene, xylenes, naphthalene, n-propylbenzene, p-
isopropyltoluene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, 1-methylnaphthalene, C9-C10
aromatics, and C11-C22 aromatics in soil sample MW-13 exceeded the MCCs. All contaminant
concentrations were below the residential SCLs.

An 8-hour AFVR event was conducted on MW-1A on December 13, 2022. A total of 463 gallons of
petroleum-contaminated ground water was removed from MW-1A during this event. Approximately 1.04
gallons of vapor-phase hydrocarbons were removed from MW-1A during the event. No liquid free product
was encountered during the AFVR.

Between November 8, 2022 and January 16, 2023, GRI personnel sampled monitoring wells MW-1, MW-
3 through MW-5, MW-7, MW-8, MW-10 through MW-13, and MW-X, and water supply wells WSW-14,
WSW-15, and WSW-16. The concentrations of benzene, toluene, ethylbenzene, xylenes, MTBE,
naphthalene, 2-hexanone, MIBK, isopropylbenzene, n-propylbenzene, 1,2,4-trimethylbenzene, 1,3,5-

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Addendum Report
Prepared on: June 7, 2023 Former Philbeck’s Amoco
Project Manager: Samuel L. McKay, III, P.G. GRI Project No. 5888
3
trimethylbenzene, 1-methylnaphthalene, 2-methylnaphthalene, C5-C8 aliphatics, C9-C12 aliphatics, C9-
C10 aromatics, and/or C11-C22 aromatics reported in the ground water samples collected from MW-1A,
MW-5, and MW-13 exceeded the MACs. Although the concentrations of MIBK and 2-hexanone exceeded
the MACs, these contaminants are not petroleum constituents. The concentrations of benzene reported
in the ground water samples collected from MW-1A and MW-13 exceeded the GCL. A Site Map showing
the locations of the monitoring wells and the structures on-site has been included as Figure 2.
2.0 RECEPTOR INFORMATION
Water Supply Wells:
According to the information determined during the updated receptor survey activities, eighteen water
supply wells were identified within 1,500 feet of the site. Of these, only one (WSW-14) is known to be
active and potable. The properties that contain water supply wells WSW-15 and WSW-16 were confirmed
by Cleveland County Water to be serviced by municipal water. A table summarizing the Water Supply Well
owner information is included as Table 3. A Site Vicinity Map showing the locations of the water supply
wells is included as Figure 3A.

Public Water Supplies:
Public water is available to the site and to most of the surrounding properties within 1,000 feet of the
source area.

Surface Water:
No surface water bodies were identified within 1,500-feet of the source area.

Wellhead Protection Areas:
On January 16, 2023, GRI personnel accessed the NCDEQ SWAP Program’s website to identify wellhead
protection areas in the vicinity of the subject site. The site is not located within a wellhead protection
area.

Deep Aquifers in the Coastal Plain Physiographic Region:
The site is not located in the Coastal Plain Physiographic Region.

Subsurface Structures:
No structures with basements were observed in the vicinity of the source area. Utilities in the source area
are located along South Post Road and Tower Drive and do not appear to intersect the seasonal high-
water table.
3.0 LAND USE
The site is currently an active petroleum retail facility and convenience store. The closest primary
residence is located on an adjacent property approximately 60 feet south of the source area. The
adjoining properties are residential. According to the Cleveland County Official Zoning Map, the
surrounding areas are zoned business and residential. Adjacent property owner information and land use

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Addendum Report
Prepared on: June 7, 2023 Former Philbeck’s Amoco
Project Manager: Samuel L. McKay, III, P.G. GRI Project No. 5888
4
information are summarized in Tables 4 and 5. A Site Vicinity Map showing the adjacent properties and
a Zoning Map showing the zoning information are included as Figures 3A and 3B, respectively.
4.0 SOIL ASSESSMENT
Soil samples were taken during UST closure/LSA activities conducted by Southeast Geological Services in
1995 and 1996. Between November 28, 1995, and December 22, 1995, ten soil samples were collected
from beneath the former USTs at depths ranging from 5 to 13 feet BGS. Soil samples 1 and 3 through 8
exceeded the applicable standards for TPH. Additionally, between December 3, 1995, and May 9, 1996,
seven soil borings (SB-1 through SB-7) were each advanced to 10 feet BGS approximately 5 feet off the
former UST basins, and soil samples (SB-1-7’ through SB-7-7’) were collected from each boring at 7 feet
BGS. The concentrations of TPH-GRO and DRO in the soil samples were beneath the laboratory detection
limits. The soil samples suggested that the soil contamination was restricted exclusively to the UST basins.
Historical soil information is included as Appendix B.

On November 8, 2022, two Type II monitoring wells (MW-12 and MW-13) were installed at the site. Soil
samples were collected during the installation of monitoring wells MW-12 and MW-13 above the water
table in the smear zone at approximately 17’ and 16’ BGS, respectively. The soil samples (MW-12 and
MW-13) were submitted for laboratory analyses of VOCs by EPA Method 8260D, SVOCs by EPA Method
8270E, and MADEP VPH and EPH. Clean, disposable nitrile gloves were used for the collection of the soil
samples. The samples were collected in laboratory supplied containers and shipped to the laboratory in
a cooler following proper chain-of-custody procedures.

The concentrations of benzene, toluene, xylenes, naphthalene, n-propylbenzene, p-isopropyltoluene,
1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, 1-methylnaphthalene, 2-methylnaphthalene, C9-C10
aromatics, and C11-C22 aromatics exceeded the MCCs in the soil sample collected from soil sample MW-
13. All contaminant concentrations were below the residential SCLs. The soil sampling analytical results
are presented in Table 6. A Soil Sample Location Map and a Soil Quality Map with the results of the 2022
soil sampling event are included as Figures 4 and 5. A copy of the laboratory report for the soil samples is
included as Appendix C. A summary of the soil sampling data from the November 2022 CSA addendum
activities is shown below:

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RALs NE NE NE NE NE NE
Soil to Water MCCs (mg/kg) 0.0072 5.4 8 6 0.085 0.2
Residential SCLs (mg/kg) 12 1,250 60.3 3,120 156 5.5
MW-12 17 <0.0008 <0.0009 <0.0008 <0.0007 <0.0008 <0.001
MW-13 16 0.266 9.29 5.22 28.4 <0.020 3.63

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Addendum Report
Prepared on: June 7, 2023 Former Philbeck’s Amoco
Project Manager: Samuel L. McKay, III, P.G. GRI Project No. 5888
5
5.0 GROUND WATER ASSESSMENT
On May 17, 1996, one Type II monitoring well (MW-1) was installed adjacent to the southern UST basin
during LSA activities. Subsequent ground water sampling indicated that ground water contamination in
MW-1 exceeded the GCLs. Based on the results of the LSA, a CSA was required.

Between December 13, 1996 and June 24, 1997, eight additional Type II monitoring wells (MW-2 through
MW-4, MW-6 through MW-10) and one Type III monitoring well (MW-5) were installed at the site during
CSA activities. During CSA activities at the site, all wells were sampled. MW-3 and MW-4 had MAC
exceedances for several BTEX constituents. MW-1 and still had GCL exceedances. Based on the results of
the CSA, additional assessment was required.

Five additional Type II monitoring wells (MW-11, MW-12, MW-13, MW-X, and MW-1A) were installed at
the site after CSA activities. Monitoring wells MW-11 and MW-12 were installed on October 21, 1997,
MW-13 was installed on March 29, 1998, and MW-1A was installed on December 28, 1998. Well
construction data for MW-X is unknown. Monitoring wells MW-1 and MW-12 were destroyed during CAP
Addendum activities, and MW-1A was installed as a replacement for MW-1. Monitoring wells MW-2 and
MW-9 have been abandoned and monitoring well MW-13 has not been found and is assumed to be
destroyed.

An 8-hour AFVR event was conducted on MW-1A on December 13, 2022. Approximately 463 gallons of
petroleum contact water were recovered from the well. Approximately 1.04 gallons of vapor-phase
hydrocarbons were removed from MW-1A during the event. No liquid product was identified in the tanker
after the AFVR was completed. The AFVR was cut 20 minutes short due to equipment malfunction. The
AFVR Event Data Sheet and disposal manifest are included as Appendix D.

On November 8, 2022, two additional Type II monitoring wells (MW-12 and MW-13) were installed at the
site. MW-12 and MW-13 were each installed to a depth of 30 feet BGS, with a 10-foot screened interval.
On November 8, 2022, water supply wells WSW-14, WSW-15, and WSW-16 were sampled. The
concentrations of bromodichloromethane exceeded the MACs in WSW-15 and WSW-16. However,
bromodichloromethane is not a petroleum constituent, so these exceedances are not related to this
release. All other contaminant concentrations in the ground water samples were below the MACs.

On January 16, 2023, monitoring wells MW-1A, MW-3 through MW-5, MW-7, MW-8, MW-10 through
MW-13, and MW-X were gauged, purged, and sampled. MW-6 was not found. the top-of-casing elevation
for MW-X has not been obtained, so its ground water elevation data is not calculable. All samples were
analyzed for VOCs by EPA Method 6200B. Monitoring wells MW-12 and MW-13 were submitted for
analysis of SVOCs by EPA Method 625.1, lead by EPA Method 6010, EDB by EPA Method 504.1, and MADEP
EPH and VPH. The contaminant concentrations of benzene, toluene, ethylbenzene, xylenes, MTBE,
naphthalene, 2-hexanone, MIBK, isopropylbenzene, n-propylbenzene, 1,2,4-trimethylbenzene, 1,3,5-
trimethylbenzene, 1-methylnaphthalene, 2-methylnaphthalene, C5-C8 aliphatics, C9-C12 aliphatics, C9-
C10 aromatics, and/or C11-C22 aromatics reported in the ground water samples collected from MW-1R,
MW-5, and MW-13 exceeded the MACs. Although the concentrations of MIBK and 2-hexanone exceeded

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Addendum Report
Prepared on: June 7, 2023 Former Philbeck’s Amoco
Project Manager: Samuel L. McKay, III, P.G. GRI Project No. 5888
6
the MACs, these contaminants are not petroleum constituents. The concentrations of benzene reported
in the ground water samples collected from MW-1A and MW-13 exceeded the GCL. A summary of the
January 16, 2023, ground water analytical data is shown below:

Contaminant
of Concern 
Be
n
z
e
n
e

To
l
u
e
n
e

Et
h
y
l
b
e
n
z
e
n
e
Xy
l
e
n
e
s

MT
B
E

Na
p
h
t
h
a
l
e
n
e

Well
ID
MACs (μg/l) 1 600 600 500 20 6
GCL (μg/l) 5,000 260,000 80,000 50,000 20,000 6,000
MW-1A 6,990 6,450 2,900 13,700 4,200 1,180
MW-3 3.23 J <1.70 <2.1 <1.40 <4.70
MW-4 <0.220 <0.170 <0.21 <0.140 <0.470
MW-5 8.99 0.359 J <0.170 1.22 J 247 0.494 J
MW-6 NS NS NS NS NS
MW-7 <0.220 <0.170 <0.21 <1.40 <0.470
MW-8 <0.220 <0.170 <0.21 <1.40 <0.470
MW-10 <0.220 <0.170 <0.21 <0.140 <0.470
MW-11 0.507 0.339 J 1.69 J 0.278 J <0.470
MW-12 <0.220 <0.170 <0.21 <0.140 <0.470
MW-13 8,510 48,100 2,750 13,700 1,040 642
MW-X 0.554 <0.170 <0.21 <0.140 <0.470

All samples were collected in accordance with the NCDEQ guidelines. Clean, disposable bailers and nitrile
gloves were used for the collection of the ground water samples. The samples were collected in
laboratory supplied containers and shipped to the laboratory in a cooler following proper chain-of-custody
procedures. A laboratory supplied trip blank was included in the sample cooler. No detectable
concentrations of requested method constituents were reported in the trip blank.

The locations of the monitoring wells are shown on Figure 2. Well construction records and boring logs
for the monitoring wells installed during the CSA addendum activities have been included as Appendix E.

Cross sections A-A’ and B-B’ are included as Figures 6 and 7; the lines of cross section are included on
Figure 2. A Ground Water Quality Map for the January 2023 comprehensive ground water sampling event
is included as Figure 8. Contaminant-specific isoconcentration maps for benzene, toluene, ethylbenzene,
xylenes, MTBE, and naphthalene for the Type II monitoring wells are included as Figures 9 through 14.
Contaminant-specific isoconcentration maps for benzene and MTBE for the Type III monitoring well are
included as Figures 15 and 16. A summary of laboratory analyses for the ground water samples collected
during the CSA addendum activities is included as Table 7. A copy of the laboratory report for the ground
water samples is included as Appendix C.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Addendum Report
Prepared on: June 7, 2023 Former Philbeck’s Amoco
Project Manager: Samuel L. McKay, III, P.G. GRI Project No. 5888
7
6.0 HYDROGEOLOGIC INVESTIGATION
The depths to ground water in the Type II monitoring wells (MW-1A, MW-3 through MW-5, MW-7, MW-
8, MW-10 through MW-13, and MW-X), measured on January 16, 2023, ranged from 10.29 to 17.94 feet
below the tops of well casings. Monitoring well MW-6 was not found, so it could not be gauged, and the
top-of-casing elevation for MW-X has not been obtained, so its ground water elevation data is not
calculable. Ground water elevations at the site, based on an assumed datum of 100.00 feet, ranged from
81.18 to 86.87 feet relative to a temporary benchmark. Based on this information, the ground water flow
direction was generally toward the northeast. The horizontal hydraulic gradient across the site was
calculated between MW-7 and MW-12 and was approximately 0.022 feet per foot. The vertical gradient
was calculated between MW-5 and MW-11 and was approximately 0.060 feet per foot in the downward
direction. A summary of ground water elevation data obtained during assessment activities to date is
presented in Table 12. A Water Table Surface Map based on the January 16, 2023, gauging data is
included as Figure 17.

Rising head slug tests were conducted on MW-1, MW-3, and MW-4 on June 1, 1997 by a previous
consultant. Historical slug test data is included as Appendix D.
7.0 REGIONAL GEOLOGY AND HYDROGEOLOGY
According to the 1985 Geologic Map of North Carolina, the site is in the Inner Piedmont. The bedrock is
biotite gneiss and schist with small masses of granitic rock. The surficial aquifer in the vicinity of site
directly overlies saprolites that grade into fractured bedrock. The soils in the area are the result of in-
place weathering of the underlying bedrock. The soils become saprolitic with depth until grading into the
underlying fractured rocks at approximately 90 feet BGS.

8.0 SITE GEOLOGY AND HYDROGEOLOGY
Based on observations made during former and current assessment activities, surficial soils observed at
the site consisted of various silts, silty clays, and silty sands. Bedrock was encountered at approximately
90 feet BGS during the installation of MW-5 by a previous consultant. A summary of the current ground
water gauging data is shown below:
Well ID
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
(ft.)
Depth to
Water from
Top of Casing
(feet)
Free
Product
(ft.)
Ground
Water
Elevation
(ft.)
MW-1A 15 - 31 31 100.04 16.46 --- 83.58
MW-3 13 - 23 23 98.25 14.43 --- 83.82
MW-4 13 - 23 23 97.27 13.36 --- 83.91
MW-5 93 - 103 103 101.07 22.51 --- 78.56
MW-6 10.5 - 20.5 20.5 95.84 NM --- NM
MW-7 9.5 - 19.5 19.5 95.38 10.67 --- 84.71
MW-8 9.5 - 19.5 19.5 97.16 10.29 --- 86.87
MW-10 10.5 - 20.5 20.5 98.98 17.06 --- 81.92
MW-11 15 - 25 25 100.86 17.31 --- 83.55
MW-12 20 - 35 35 99.11 17.94 --- 81.18
MW-13 20 – 30 30 99.12 16.66 --- 83.27
MW-X 20 - 30 30 99.93 15.54 --- NM

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Addendum Report
Prepared on: June 7, 2023 Former Philbeck’s Amoco
Project Manager: Samuel L. McKay, III, P.G. GRI Project No. 5888
8

On January 16, 2023, monitoring wells MW-1A, MW-3 through MW-5, MW-7, MW-8, MW-10 through
MW-13, and MW-X were gauged, purged, and sampled. MW-6 was not found. The top-of-casing elevation
for MW-X has not been obtained, so its ground water elevation data is not calculable. Depths to ground
water in the Type II monitoring wells ranged from 10.29 to 17.94 feet below the tops of well casings.
Ground water elevations at the site, based on an assumed datum of 100.00 feet, ranged from 81.18 to
86.87 feet below TOC. Ground water flow was generally toward the northeast.
9.0 DISCUSSION
According to the CSA report from Southeastern Geological Services, soil contamination was noted
beneath all four tanks in both UST basins during UST removal activities conducted in November and
December, 1995. The UST basins were excavated to depths of approximately 13 feet BGS, whereupon
ground water was encountered. Soil analysis indicated that the gasoline contamination was limited only
to the tank basins but had also extended into the water table. A release was reported on November 29,
1995.

In total, fourteen Type II monitoring wells and one Type III telescoping well have been installed to
determine the horizontal and vertical extent of the release. Currently, only eleven Type II and one Type III
monitoring wells are accessible at the site. No free product has been observed at the site. Monitoring
wells MW-1A and MW-13 contained the highest ground water contamination levels during the CSA
addendum activities with the reported concentrations of benzene exceeding the GCLs. Based on the
current risk ranking of the site, the contaminant plume is sufficiently delineated horizontally and vertically.

The risk ranking for the site has been established as high due to the presence of GCL exceedances and an
active, potable water supply well located within 500 feet of the source area. In order to lower the risk
ranking of the site, ground water concentrations must be reduced to levels below the GCLs and the
property containing the potable water supply well WSW-14 should be connected to municipal water, and
the water supply well WSW-14 should be abandoned. Permission to abandon WSW-15 and WSW-16, both
located within 250’ of the source area, should be requested.
10.0 CONCLUSIONS AND RECOMMENDATIONS
 Ground water flow direction is to the northeast, away from the active potable water supply well
(WSW-14). The horizontal hydraulic gradient across the site was calculated between MW-7 and
MW-12 and was approximately 0.022 feet per foot. The vertical gradient was calculated between
MW-5 and MW-11 and was approximately 0.060 feet per foot in the downward direction.
 The ground water contaminant plume is reasonably defined vertically and horizontally.
 On November 8, 2022, two Type II monitoring wells (MW-12 and MW-13) were installed at the
site. Soil samples were collected during the installation of monitoring wells MW-12 and MW-13
and were submitted for laboratory analyses of VOCs by EPA Method 8260D, SVOCs by EPA
Method 8270E, and MADEP VPH and EPH. The concentrations of benzene, toluene, xylenes,
naphthalene, n-propylbenzene, p-isopropyltoluene, 1,2,4-trimethylbenzene, 1,3,5-
trimethylbenzene, 1-methylnaphthalene, 2-methylnaphthalene, C9-C10 aromatics, and C11-C22

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Addendum Report
Prepared on: June 7, 2023 Former Philbeck’s Amoco
Project Manager: Samuel L. McKay, III, P.G. GRI Project No. 5888
9
aromatics exceeded the MCCs in the soil sample collected from soil sample MW-13. All
contaminant concentrations were below the residential SCLs.
 On December 13, 2022 an 8-hour AFVR event was conducted on MW-1A. Approximately 463
gallons of petroleum contact water were recovered from the well. Approximately 1.04 gallons of
vapor-phase hydrocarbons were removed from MW-1A during the event. No liquid product was
identified in the tanker after the AFVR was completed.
 On January 16, 2023, monitoring wells MW-1A, MW-3 through MW-5, MW-7, MW-8, MW-10
through MW-13, and MW-X were gauged, purged, and sampled. MW-6 was not found. The top-
of-casing elevation for MW-X has not been obtained, so its ground water elevation data is not
calculable. All samples were analyzed for VOCs by EPA Method 6200B. Monitoring wells MW-12
and MW-13 were submitted for analyses of SVOCs by EPA Method 625.1, lead by EPA Method
6010, EDB by EPA Method 504.1, and MADEP EPH and VPH. The contaminant concentrations of
benzene, toluene, ethylbenzene, xylenes, MTBE, naphthalene, 2-hexanone, MIBK,
isopropylbenzene, n-propylbenzene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, 1-
methylnaphthalene, 2-methylnaphthalene, C5-C8 aliphatics, C9-C12 aliphatics, C9-C10 aromatics,
and/or C11-C22 aromatics reported in the ground water samples collected from MW-1A, MW-5,
and MW-13 exceeded the MACs. Although the concentrations of MIBK and 2-hexanone exceeded
the MACs, these contaminants are not petroleum constituents. The concentrations of benzene
reported in the ground water samples collected from MW-1A and MW-13 exceeded the GCL.
 Based on this information, the risk classification for the site should remain High. Municipal water
connection agreements should be sent to the residents and owners of WSW-14. Water supply
wells WSW-14, WSW-15, and WSW-16 should be abandoned in order to lower the risk ranking of
the site. Additional recommendations for corrective action can be made once it is determined
whether WSW-14 will connect to municipal water and if WSW-15 and WSW-16 can be abandoned.
A longer period AFVR or MMPE event should be conducted at the site to lower concentrations of
dissolved phase product in the groundwater at monitoring wells MW-1A and MW-13. A feasibility
study should be conducted to determine the best course of action for incident closure.
11.0 LIMITATIONS
This report has been prepared for the exclusive use of Arey Oil Company, Inc. for specific application to
the referenced site in Cleveland County, North Carolina. The assessment was conducted based on the
scope of work and level of effort desired by the NCDEQ and with resources adequate only for that scope
of work. Our findings have been developed in accordance with generally accepted standards of
environmental practices in the State of North Carolina, available information, and our professional
judgment. No other warranty is expressed or implied.

The data that is presented in this report is indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would
be interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from this data.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Addendum Report
Prepared on: June 7, 2023 Former Philbeck’s Amoco
Project Manager: Samuel L. McKay, III, P.G. GRI Project No. 5888
10
12.0 REFERENCES
Comprehensive Site Assessment, Philbeck’s Amoco, Southeastern Geological Services, Inc., July 3, 1997
Corrective Action Plan, Philbeck’s Amoco, Southeastern Geological Services, Inc., December 15, 1997
Department of Natural Resources and Community Development, 1985, Geologic Map of North Carolina,
1 sheet
Fetter, C. W., 1988, Applied Hydrogeology, Second Edition, Macmillan Publishing Company, 592 p.
Ground Water Monitoring Report, Former Philbeck’s Amoco, Geological Resources, Inc., February 25,
2022
Initial Site Characterization; Extent of Soil Contamination; Initial Groundwater Sampling, Philbeck’s
Amoco, Southeastern Geological Services, Inc., June 19, 1996
North Carolina Department of Environment and Natural Resources, 2000, Ground Water Section
Guidelines for the Investigation and Remediation of Soil and Ground Water, 79 p.
North Carolina Department of Environmental Quality, Division of Waste Management – UST Section
Assessment Guidelines: Petroleum and Hazardous Substances UST Releases; Petroleum Non-UST
Releases, January 19, 2021 Version
Pre-Cap Monitoring Report, Philbeck’s Amoco, Southeastern Geological Services, Inc., May 6, 1998
Tank Closure Report, Philbeck’s Amoco, Southeastern Geological Services, Inc., January 25, 1996
Semi-Annual Project Status Report, Arey Oil Company/Philbeck’s Amoco, Delta Environmental
Consultants, Inc., March 15, 1999

FIGURES
SITE LOCATION
Figure 1
Site Location
Former Philbeck’s Amoco
1319 South Post Road
Shelby, North Carolina
Cleveland County
Incident No. 16199
GRI Project No. 5888
500 M
2000 FT
Date: 01/08/2022 Location: 35.250494° N -81.506816° W
D
a
d
X
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SITE
2555250743
2555154877
255524
2555155318
2555255817
2555158502
2555158732
2555159255
2555157268
2555258161
2555245891
2555259315
2555351240
2555248818
2555245652
255
5
3
5
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255
5
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2555243834
2555250624
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2555247549
2555255613
WSW-9
WSW-8
WSW-7
WSW-6
WSW-5
WSW-4 WSW-3
WSW-2
WSW-1
WSW-18
WSW-17
WSW-16
WSW-15
WSW-14
WSW-13
WSW-12
WSW-11
WSW-10
PO
S
T

R
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BE
A
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JOE'S LAKE RD
CAM
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A
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GRADY PL
1,500-FOOT RADIUS
³
0 300150
Feet
1 inch = 300 feet
LEGEND
"J Water Supply Well
roads
streams
Well Owners and Adjacent Parcels
parcels
5 248
"J
"J
"J"J
"J
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SITE
WSW-9
WSW-8
WSW-7
WSW-6
WSW-5
WSW-4 WSW-3
WSW-2
WSW-1
WSW-18
WSW-17
WSW-16
WSW-15
WSW-14
WSW-13
WSW-12
WSW-11
WSW-10
PO
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A
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GRADY PL
1,500-FOOT RADIUS
³
0 300150
Feet
1 inch = 300 feet
LEGEND
"J Water Supply Well
roads
streams
ZONING - RESIDENTIAL
ZONING - NEIGHBORHOOD BUSINESS - CU
ZONING - RO-CU RESIDENTIAL
ZONING - MANUFACTURED HOME PARKS
ZONING - GENERAL BUSINESS
parcels
Receptor Code
X
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TABLES
UST ID Number A1, A1B, A1C Facility ID Number
Owner or Operator?
Owner/Operator
UST ID Number 2 Facility ID Number
Owner/Operator
UST ID Number Facility ID Number
Owner or Operator?
UST ID Number Facility ID Number
Owner or Operator?
UST ID Number Facility ID Number
Owner or Operator?
UST ID Number Facility ID Number
Owner or Operator?
Address Telephone Number
2530 Taylor Road, Shelby, NC 28152 704-300-6004
00-0-0000012594
Name of Owner or Operator Dates of Ownership / Operation
Richard Campbell 08/16/2001 - 06/03/2011
06/03/2011 - current
Address Telephone Number
2603 East Cherokee Street, Blacksburg, SC 29702 704-734-7439
Unknown
Telephone Number
TABLE 1
UST OWNER/OPERATOR INFORMATION
FORMER PHILBECK'S AMOCO (INCIDENT NO. 16199)
00-0-0000012594
Harold Philbeck 12/27/1995 - 08/16/2001
1906 East Dixon Boulevard, Shelby, NC 28152
00-0-0000012594
Name of Owner or Operator Dates of Ownership / Operation
Robert Heath
Name of Owner or Operator Dates of Ownership / Operation
Address Telephone Number
1906 East Dixon Boulevard, Shelby, NC 28152 704-482-1445
Name of Owner or Operator Dates of Ownership / Operation
Address Telephone Number
1906 East Dixon Boulevard, Shelby, NC 28152 704-482-1445
Name of Owner or Operator Dates of Ownership / Operation
Address Telephone Number
1906 East Dixon Boulevard, Shelby, NC 28152 704-482-1445
Page 1 of 1
Date: 02/01/2022
Was Release
Associated
with UST
(Yes / No)
A1C Gasoline NA 12,000 12/27/1995 Single Wall FRP Unknown Other Current No
A1B Gasoline NA 8,000 12/27/1995 Single Wall FRP Unknown Other Current No
A1 Gasoline NA 8,000 12/27/1995 Single Wall FRP Unknown Other Current No
4 NA Gasoline 2,000 5/6/1962 Single Wall Steel Unknown Single Wall Steel Yes
3 NA Gasoline 1,000 5/6/1962 Single Wall Steel Unknown Single Wall Steel Yes
2 NA Gasoline 6,000 5/2/1978 Single Wall Steel Unknown Single Wall Steel Yes
1 NA Gasoline 4,000 5/4/1969 Single Wall Steel Unknown Single Wall Steel Yes
TABLE 2
UST SYSTEM INFORMATION
FORMER PHILBECK'S AMOCO (INCIDENT NO. 16199)
Status
of
UST
UST
ID
No.
Current
or Most
Recent
Contents
Previous
Contents
Capacity
(gallons)
Date
Installed
Construction
Details
Tank
Dimensions
Description of
Associated
Product Piping
and
Pumps
00-0-0000012594
Page 1 of 1
Facility ID # : 00-0-0000012594
Well ID. Parcel ID No.Well Owner Mailing Address Well Address (Potable / Non-
Potable
Connected to
Municipal Water
Yes/No
source area of
WSW-1 2555245428 Brandon J. and Jordan L. Smith Non-Potable Yes ~1325' SE
WSW-2 2555245652 Terrie Lemons Gibson Unknown Unknown ~1235' SE
WSW-3 2555245891 Cyd Warren Non-Potable Yes ~1,135' SE
WSW-4 2555243834 Daniel H. & Ashley Dyer Blanton Unknown Yes ~1,020' SE
WSW-5 2555247549 Kevin Scott Mayhue Unknown Unknown ~1,440' SE
WSW-6 2555248818 Casey R. & Ansley B. Vaughn Unknown Yes ~1,323' SE
WSW-7 2555258161 Neal Emanuel & Teressa G. Vassey Unknown Yes ~1,250' E
WSW-8 2555259315 Haley M. Wilson Unknown Yes ~1,230' E
WSW-9 2555351240 Erin Bailey & Joshua Ray Page Unknown Unknown ~1,420' E
WSW-10 2555351419 Robert G. & Tammy Wills Unknown Unknown ~1,340' E
WSW-11 2555350506 Christopher S. Gantt Non-Potable Yes ~1,220' E
WSW-12 2555255613 Betty B. Rogers Non-Potable Yes ~805' E
WSW-13 2555255817 David W. McEntire Non-Potable Yes ~740' NE
WSW-14 2555250458 Samuel S. & Kimberley S. Davis Potable No ~340' E
WSW-15 2555158732 First Choice Properties Unknown yes ~170' NE
WSW-16 2555250624 William B. Ivie Unknown yes ~250' NE
WSW-17 2555157268 Ronald K. Church Unknown No ~380' S
WSW-18 Priscilla P. Kendrick Unknown Yes ~320' SW
Figure 3A.
TABLE 3
RECEPTOR INFORMATION
FORMER PHILBECK'S AMOCO (INCIDENT NO. 16199)
Date: 02/01/2022
Page 1 of 1
Date: 02/01/2022 Facility ID # : 00-0-0000012594
Parcel Number Owner Name Address
2555158502 (Site)Hanumanta LLC 1319 South Post Road
Shelby, NC 28152
2555154877 John Michael & Patti H. Thompson 102 10 Kenwall Village Drive
Shelby, NC 28152
2555155318 Priscilla P. Kendrick 1322 South Post Road
Shelby, NC 28152
2555157268 Ronald Keith Church 1401 South Post Road
Shelby, NC 28152
2555159459 Sonya Russ & Tony Jo Nalley 2105 Tower Drive
Shelby, NC 28152
2555250624 William Brian Ivie 1842 Beaman Street
Shelby, NC 28152
2555159255 Ronald Keith Church 2106 Tower Drive
Shelby, NC 28152
2555158732 First Choice Properties 1313 South Post Road
Shelby, NC 28152
Figure 3A.
TABLE 4
ADJACENT PROPERTY OWNER INFORMATION
FORMER PHILBECK'S AMOCO (INCIDENT NO. 16199)
Page 1 of 1
Date: 02/01/2022 Facility ID # : 00-0-0000012594
Map ID No. Land Use Feature Zoning Description Address
Distance from
Source Area
(feet)
1 Alexander Youth Network General Business Therapy Center 1201 S. Post Rd. Shelby, NC ~1,500
n/a Residential Residential n/a n/a
n/a RO-CU Residential Residential n/a n/a
n/a n/a n/a
n/a Neighborhood Business Neighborhood Business n/a n/a
n/a General Business General Business n/a n/a
Figure 3B.
TABLE 5
LAND USE INFORMATION
FORMER PHILBECK'S AMOCO (INCIDENT NO. 16199 )
Page 1 of 1
Date: 01/13/23 Facility ID #: 0-012594
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NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE
0.0072 5.4 8 6 0.085 0.2 1.4 0.12 6.6 6.6 0.054 1.5 68 540 31 540 NE 31
12 1,250 60.3 3,120 156 5.5 1,560 1,560 156 156 22.8 62.5 625 1,500 469 1,560 31,200 469
MW-12 11/08/22 17 <0.0008 <0.0009 <0.0008 <0.0007 <0.0008 <0.001 <0.0007 <0.001 <0.0007 <0.0007 <0.144 <0.136 <1.66 <6.21 <0.850 <12.6 <16.6 <19.3
MW-13 11/08/22 16 0.266 9.29 5.22 28.4 <0.020 3.63 4.29 0.440 28.4 7.88 1.02 1.94 48.4 <5.98 64.5 168 <16.0 51.1 JNotes:• Results reported in mg/kg (milligrams per kilograms)
• Trip Blank results reported in ug/l (micrograms per liter)
• ft-BGS: feet below ground surface.• RAL: Regulatory Action Level.• MCCs: Maximum Contaminant Concentrations (soils).• SCLs: Soil Cleanup Levels.
• < : Less than the method detection limit specified in the laboratory report
• Concentrations in bold face type indicate the soil to water MCCs were below the reported concentrations.
• Concentrations in italic type indicate the Residential SCLs were below the report concentrations.
• NE: Not Established
• NR: Not Requested.
MADEP EPH
Residential SCLs (mg/kg)
RAL (mg/kg)
Soil to Water MCC (mg/kg)
Analytical Method MADEP VPHEPA Method 8270EPA Method 8260B
Page 1 of 1
EPA
Method
504.1
EPA
Method
6010/3030C
Well
ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 0.6 40 100 70 70 400 400 1 30 0.02 15 400 700 200
5,000 260,000 80,000 50,000 20,000 6,000 NE 40,000 100,000 25,000 26,100 28,500 24,100 1,000 12,000 50 15,000 NE NE NE
6,020 10,800 3,360 16,500 2,490 1,750 ***105 J 342 4,230 1,180
6,990 6,450 2,900 13,700 4,200 1,180 141 102 322 3,230 989
1.2
3.3 31.6
13.3 180
8.99 247
8,510 48,100 2,750 13,700 1,040 642 193 102 117 286 2,150 530 41.2 78.0 23,200 14,600 5,560
4.09 **
4.24 **
Trip Blank
MW-1A
MW-3
MW-4
MW-5
MW-6
MW-7
MW-8
MW-10
MW-11
MW-X
Field Blank
Date: 02/06/2023
Analytical Method
EPA Method 6200B MADEP Method VPH
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
FORMER PHILBECK'S AMOCO (INCIDENT NO. 16199)
EPA 625.1
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Page 1 of 1
Date: 01/13/23
Method of Measurement:
Well ID (gas, diesel,
etc.)
Date of Recovery
(mm/dd/yy)
Free Product
Recovery
Method*
Casing
Diameter
(inches)
Product
Thickness
before
Recovery
(feet)
Thickness
after
(feet)
Amount of
Liquid
(gallons)
Amount of
Product
Recovered
as Liquid
(gallons)
MW-1A Gasoline 12/13/22 AFVR 2 --- --- 463 0.0
Disposal Manifest and/or Field Notes).
TABLE 8
FREE PRODUCT RECOVERY RESULTS
FORMER PHILBECK'S AMOCO (INCIDENT NO. 16199)
Facility ID#:
Page 1 of 1
Date: 01/18/23
Well ID Date (mm/dd/yy)
Product
Recovery
Method*
Average
Effluent
Velocity
(ft/min)
Average
Effluent
Temperature
(°F)
Average
Effluent
Concentration
(ppm)
Amount of
Vaporized
Product
(gallons)
Amount of
Liquid
Recovered
(gallons)
Amount of
Product
Recovered as
Liquid
(gallons)
Total Amount
of Product
Recovered
(gallons)
1.04 463 0 1.04
TABLE 9
FREE PRODUCT RECOVERY EVENT INFORMATION
FORMER PHILBECK'S AMOCO (INCIDENT NO. 16199)
Facility ID #:
Totals
Page 1 of 1
Date: 01/18/23 Facility ID #: 0-012594
Wells Included in
Event
Product
Recovery
Method*
Date of Event
(mm/dd/yy)
Total Amount of
Free Product plus
Ground Water
Recovered
Cost of Free
Product
Recovery
Event
Cost Per
Gallon (total
fluids)
Comments
MW-1A AFVR 12/13/2022 464.04 $1,681.15 $3.62
464.04 $1,681.15 $3.62
Notes:
• *: Bailing, Skimming, Aggressive Fluid Vapor Recovery (AFVR), Mobile Multiphase Extraction (MMPE)
• Total Amount of Free Product Recovered = Amount of Vaporized Product + Amount of Product Recovered as Liquid
• Cost of Free Product Recovery Event includes supervision, travel, mileage, per diem, subcontractor costs, MMPE sampling, MMPE sampling analytical, report
preparation (pre-2015 only) and project management.
TOTAL (to date)
Page 1 of 1
Date: 02/06/2023
Well ID
Date
Installed
(m/dd/yy)
Date Water
Level
Measured
(m/dd/yy)
Well
Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft. BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
(ft.)
Depth to
Water from
Top of Casing
(feet)
Free Product
(ft.)
Ground
Water
Elevation (ft.)
Comments
01/19/22 19.21 ---80.83
03/14/22 16.74 ---83.3
01/16/23 16.46 ---83.58
01/19/22 17.63 ---80.62 obstructed
03/14/22 14.95 ---83.30
01/16/23 14.43 ---83.82
01/19/22 NM ---NM not found
03/14/22 13.99 ---83.28
01/16/23 13.36 ---83.91
01/19/22 24.52 ---76.55
03/14/22 21.83 ---79.24
01/16/23 22.51 ---78.56
01/19/22 NM ---NM not found
03/14/22 13.42 ---82.42
01/16/23 NM ---NM
01/19/22 15.07 ---80.31
03/14/22 11.68 ---83.70
01/16/23 10.67 ---84.71
01/19/22 15.33 ---81.83
03/14/22 12.13 ---85.03
01/16/23 10.29 ---86.87
01/19/22 NM ---NM not found
03/14/22 18.11 ---80.87
01/16/23 17.06 ---81.92
01/19/22 20.16 ---80.70
03/14/22 17.79 ---83.07
01/16/23 17.31 ---83.55
MW-12 11/8/2022 01/16/23 20 20-30 30 99.12 17.94 ---81.18
MW-13 11/8/2022 01/16/23 20 20-30 30 99.93 16.66 ---83.27
01/19/22 18.71 ---NM dry
03/14/22 16.03 ---NM
01/16/23 15.54 ---NM
Notes:
Unknown Unknown Unknown NM
MW-10 6/24/1997
MW-11 10/21/1997
MW-X Unknown
15 15-25 25 100.86
MW-3 12/13/1996
MW-4 12/13/1996
MW-5 1/31/1997
MW-6 6/24/1997
MW-7 6/24/1997
MW-8 6/24/1997 9.5 9.5-19.5 19.5 97.16
10.5 10.5-20.5 20.5 98.98
10.5 10.5-20.5 20.5 95.84
9.5 9.5-19.5 19.5 95.38
13-23 23 97.27
98 98-103 103 101.07
TABLE 11
WELL CONSTRUCTION AND GAUGING INFORMATION
FORMER PHILBECK'S AMOCO (INCIDENT NO. 16199)
Facility ID # : 00-0-0000012594
MW-1A 12/28/1998 15 15-31 31 100.04
13 13-23 23 98.25
13
Page 1 of 1

APPENDICES

APPENDIX A
State Correspondence

May 9, 2022
Ms. Kay Piercy Arey Oil Company, Inc PO Box 2529
Shelby, NC 28151
Re: Notice of Regulatory Requirements 15A NCAC 2L .0407(b) and (d) Risk-based Assessment and Corrective Action for Petroleum Underground Storage Tanks
Former Philbeck’s AMOCO 1319 South Post Road, Shelby Cleveland County
Incident No. 16199 (AS-1478)
Risk Classification: High, H-260-D Dear Ms. Piercy: The Division of Waste Management, Underground Storage Tank (UST) Section, is in receipt
of the Ground Water Monitoring Report, dated February 25, 2022, and the May 3, 2022 Ground Water Monitoring and Updated Receptor Report, prepared by Geological Resources, Inc., (GRI) on behalf of Arey Oil Company, Inc. (Arey Oil). The Reports were reviewed and will be maintained in the Asheville Regional Office.

The Reports confirmed the presence of petroleum-related compounds (benzene, and methyl-tert-butyl ether – MTBE) above the Title 15A of the North Carolina Administrative Code (NCAC) Subchapter 02L .0202 groundwater quality (2L Standards) in the bedrock groundwater monitoring well MW-5. The Reports also document the presence of private water supply wells (e.g., WSW-14, WSW-15, and WSW-16) near the Site. These water supply wells shall by sampled for regulated
compounds by Arey Oil. If the water supply wells are not in use, or if the owner agrees to be connected to municipal/county water, the costs for well abandonment and water connection are reimbursable via the Leaking Petroleum Underground Storage Tank Cleanup Funds program (State Trust Fund).

This office agrees with the recommended installation of an additional downgradient well located north of MW-10. An additional groundwater monitoring well should also be installed between MW-1A and MW-3 to further delineate soil and groundwater conditions downgradient of the former UST basin. These efforts should be conducted as part of a Comprehensive Site Assessment (CSA)

Addendum. Should Arey Oil choose to do so, an Aggressive Fluid Vapor Recovery (AVFR) or a Mobile Multi-Phase Extraction (MMPE) event may be completed in the interim prior to completing
the CSA Addendum field activities. Please prepare and submit a Pre-Approval Task Authorization (PATA) within 30 days of this letter and complete the approved PATA activities within 90 days from final approval to proceed. Groundwater monitoring well installation will require well permits and property owner signature(s) are
required per 15A NCAC 02C .0105 (3a). Because a release or discharge has been confirmed, a Licensed Geologist or a Professional Engineer, certified by the State of North Carolina, is required to prepare, and certify all reports submitted to the Department in accordance with Title 15A NCAC 2L .0103(e) and 2L .0111(b).

If you have any questions regarding the actions that must be taken or the rules mentioned in this letter, please contact me at [phone]. Sincerely,

Brett Engard, P.G. Hydrogeologist Asheville Regional Office, UST Section Division of Waste Management, NCDEQ
cc: Akash Brahmbhatt, C/O Hanumanta, LLC. 3241 NC 126, Morganton, NC 28655 Robert Arey, Jr., President, Arey Oil Company, Inc. – [e-mail] Samuel McKay, III, Project Manager, Geological Resources, Inc., [e-mail]

Site Name City / County /Cleveland Incident #16199
Resp Pty Name / Contact /Incident Mgr Region ASH
RP Type (Owner/Operator / Landowner / Attny-in-fact)Change Order?Prev. TA #20
Consultant / Project Mgr /Sam McKay
Telephone / Fax Number /
Project Mgr Email
Proposal# / Scope Dates /
Has STF Eligibility Been Determined? (Y/N)Site Status
With Claim: [ ] All Main Consultant/Contractor invoices attached?[ ] Proof of payment attached directly to the front of each invoice?
w
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De
d
?
Task #Lab /
SubCode RO

A
u
t
h
Proposed
Rate/Price
(Consultant)CO

A
u
t
h Proposed Task
Subtotal
(Consultant)
Final
Preapproved
Subtotal
(UST Section)
Claimed
Amount3
(Consultant)
1.050 agreements
3.080 1 / permit $250.00 $250.00 /
3.101 40 / feet $12.50 $500.00 /
3.113 40 / feet $50.00 $2,000.00 /
3.118 40 / feet $5.00 $200.00 /
3.351 2 / wells $80.00 $160.00 /
3.397 1 / Mobe $100.00 $100.00 /
3.398 1 / Mobe $350.00 $350.00 /
4.031 18 / wells $110.00 $1,980.00 /
4.041 3 / wells $75.00 $225.00 /
4.090 #272 25 / samples $66.00 $1,650.00 /
4.090 #280 2 / samples $45.00 $90.00 /
4.090 #301 2 / samples $208.00 $416.00 /
4.090 #330 2 / samples $14.00 $28.00 /
4.090 #341 2 / samples $56.00 $112.00 /
4.090 #342 2 / samples $100.00 $200.00 /
4.090 #409 2 / samples $84.00 $168.00 /
4.090 #410 2 / samples $187.00 $374.00 /
4.090 #421 2 / samples $58.00 $116.00 /
4.090 #422 2 / samples $100.00 $200.00 /
4.091 3 /shipments $60.00 $180.00 /
6.060 1 / report $1,400.00 $1,400.00 /
6.190 1 / Letter $500.00 $500.00 /
7.420 1 / event $2,325.00 $2,325.00 /
7.420 1 / event $1,500.00 $1,500.00 /
7.420 1 / event $2,500.00 $2,500.00 /
7.420 5000 / gallons $0.35 $1,750.00 /
7.420 5000 / gallons $0.25 $1,250.00
12.030 4 / nights $151.00 $604.00
12.050 5 / trips $250.00 $1,250.00
12.055 5 / trips $50.00 $250.00
Requested Preapproved Claimed3
TOTAL:$0.00 TOTAL:
Total Standard Costs (Not Third Party)$23,528.00 $0.00 Total Standard Costs
$0.00 $0.00
Process Tracking 8/4/2022
TA Submittal:by:(PM)(Reserved for RO)
RO Review:by:(IM)Joint UST Preapproval Confirmed By:Date1
CO Review:by:(STF)RP or Designee Receipt Confirmed By:Date 4
1 - This ePATA expires one year from the Joint UST Preapproval date. This does not extend, alter, or supersede any regulatory deadlines (e.g., NORR's, NOV's, Enforcements, etc.)
2 - THE ONE YEAR STATUTE OF LIMITATIONS APPLIES TO EACH INDIVIDUAL TASK. Costs must be claimed within one year of completion of that task to be reimbursable.
3 - Only Tasks included on this ePATA may be claimed. Do not include other Tasks or claimed costs (i.e., Claim preparation) that were not preapproved or the claim will be returned.
4 - Preapproval is not valid (i.e., claimable) until receipt is signed as 'Confirmed' by the RP or their designee and returned to the Trust Fund within a week of approval. Signature
indicates acknowledgement of the tasks and amounts approved. Any objections/appeals must be submitted via Change Order prior to work proceeding. Scope/cost
negotiations do not supersede other regulatory deadlines as described in #1 above. Also, any ePATA that has been signed as 'Confirmed' by both the UST Section and RP
is not to be modified without written consent by all signatories.
5 - Tasks approved on Directed - CAB Only ePATAs must be performed in accordance with all applicable rules, statutes, and RRD Task Scopes of Work to be reimbursed in full.
DIRECTED COSTS
Shelby
(Must Complete with Claim Submittal)(See Instructions / RRD for Tasks requiring Preapproval / Task Authorization)
Owner/Operator
704-845-4010
(Reserved for Incident Manager)
PREAPPROVAL / TASK AUTHORIZATION
Former Philbeck's Amoco
Note:This Electronic Preapproval Task Authorization (ePATA) shall be used to receive preapproval from the UST Section. A proposal,including maps and figures,must be
attached to elaborate on the costs for the tasks listed below that describes the scope of work and the rationale for the proposed activities.If,following completion of this ePATA,
you discover that unexpected tasks must be performed, incurring costs for tasks not originally included with this form, you must complete and submit a separate ePATA request
designated as a "Change Order" in the provided space above prior to conducting those tasks. Include a copy of the prior ePATA form for confirmation. Please attach this form to
the cover of the corresponding claim when requesting reimbursement. IMPORTANT:Only one claim may be submitted per ePATA and all work on the ePATA must have been
completed within 12months ofthe completion date ofthe FIRSTcompletedtask to remain within theStatute of Limitations. All ePATAssubmitted within a claim are closed with that
claim, and may not be re-used in a separate submittal, even for costs or tasks that were not originally claimed. Final reimbursement of costs associated with the Total Claimed
amount below may be affected by the eligibility status of the site (i.e., deductibles, apportionment, etc.), and the documentary validation of incurred costs as reasonable and
necessary expenses per 15A NCAC 2P .0402 and .0404.
SLM
Proposed
Units / Type
(Consultant)
Brett Engard
Yes
22-336 8/1/2022
704-845-4012
Dates of Work
(Consultant)
Started1 / Completed2
[e-mail]
Arey Oil Company Kay Piercy
Geological Resources, Inc.
ELECTRONIC PREAPPROVAL TASK AUTHORIZATION FORM
Dept of Environmental Quality - Division of Waste Management
Site Name City / County /Cleveland Incident #16199
Resp Pty Name / Contact Incident Mgr Region ASH
RP Type (Owner/Operator / Landowner / Attny-in-fact)Change Order?Prev. TA #20
Consultant / Project Mgr /Samuel L McKay, III
Telephone / Fax Number /Task Authorization Number:21 ChangeOrd:1
Project Mgr Email Site Risk / Rank / Abatement:H260D RRA Date:9/28/2021
Proposal# / Scope Dates /% Commercial (C=100%, NC=0%, Both=1%-99%)
Has STF Eligibility Been Determined? (Y/N)Site Status (Active or NFA Date)
With Claim: [ ] All Main Consultant/Contractor invoices attached?[ ] Proof of payment attached directly to the front of each invoice?
w Important: The date of reimbursement is dependent on the Trust Fund balance. There may be a delay in the reimbursement of claims for work under this ePATA.
3r
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D
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?
Task #Lab /
SubCode RO

A
u
t
h
Proposed
Rate/Price
(Consultant)CO

A
u
t
h
Proposed Task
Subtotal
(Consultant)
Final
Preapproved
Subtotal
(UST Section)
Claimed
Amount3
(Consultant)
2.082 8 /hours Y $93.00 y $744.00 $744.00 /
2.084 1 /mob Y $250.00 y $250.00 $250.00 /
2.084 8 /hours Y $125.00 y $1,000.00 $1,000.00 /
2.084 1500 /gallons Y $0.35 y $525.00 $525.00 /
12.050 1 /trip Y $250.00 y $250.00 $250.00 /
12.055 1 /trip Y $50.00 y $50.00 $50.00 /
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
Requested Preapproved Claimed3
TOTAL:$2,819.00 $2,819.00 TOTAL:
Total Standard Costs (Not Third Party)$2,819.00 $2,819.00 Total Standard Costs
Total applied as Third Party Deductible/Damage Costs $0.00 $0.00 Total Third Pty Costs
Process Tracking (Date)
TA Submittal:9/16/22 by:(PM)(Reserved for RO)
RO Review:9/16/22 by:(IM)Joint UST Preapproval Confirmed By:Date1 9/29/2022
CO Review:9/21/22 by:(STF)RP or Designee Receipt Confirmation By:Date 4 9/30/2022
1 - This ePATA expires one year from the Joint UST Preapproval date. This does not extend, alter, or supersede any regulatory deadlines (e.g., NORR's, NOV's, Enforcements, etc.)
2 - THE ONE YEAR STATUTE OF LIMITATIONS APPLIES TO EACH INDIVIDUAL TASK. Costs must be claimed within one year of completion of that task to be reimbursable.
3 - Only Tasks included on this ePATA may be claimed. Do not include other Tasks or claimed costs (i.e., Claim preparation) that were not preapproved or the claim will be returned.
4 - Preapproval is not valid (i.e., claimable) until receipt is signed as 'Confirmed' by the RP or their designee and returned to the Trust Fund within a week of approval. Signature
indicates acknowledgement of the tasks and amounts approved. Any objections/appeals must be submitted via Change Order prior to work proceeding. Scope/cost
negotiations do not supersede other regulatory deadlines as described in #1 above. Also, any ePATA that has been signed as 'Confirmed' by both the UST Section and RP
is not to be modified without written consent by all signatories.
5 - Tasks approved on Directed - CAB Only ePATAs must be performed in accordance with all applicable rules, statutes, and RRD Task Scopes of Work to be reimbursed in full.
DWM/UST ePATA 4/1/2022
SLM
Proposed
Units / Type
(Consultant)
Brett Engard
ActiveYES
22-658 September-December, 2022
704-845-4012
Dates of Work
(Consultant)
Started1 / Completed2
FINAL REIMBURSEMENT
100.00%
YES
[e-mail]
Kay Piercy Arey Oil Company, Inc.
Geological Resources, Inc.
DIRECTED COSTS
Sam McKay
Shelby
(Must Complete with Claim Submittal)(See Instructions / RRD for Tasks requiring Preapproval / Task Authorization)
Owner/Operator
704-845-4010
(Reserved for Incident Manager)
PREAPPROVAL / TASK AUTHORIZATION
Former Philbeck's Amoco
Note: This Electronic Preapproval Task Authorization (ePATA) shall be used to receive preapproval from the UST Section. A proposal,including maps and figures,must be
attached to elaborate on the costs for the tasks listed below that describes the scope of work and the rationale for the proposed activities.If, following completion of this ePATA,
you discover that unexpected tasks must be performed, incurring costs for tasks not originally included with this form, you must complete and submit a separate ePATA request
designated as a "Change Order"in the provided space above prior to conducting those tasks. Include a copy of the prior ePATA form for confirmation. Please attach this form to
the cover of the corresponding claim when requesting reimbursement. IMPORTANT:Only one claim may be submitted per ePATA and all work on the ePATA must have been
completed within 12 monthsof the completion date ofthe FIRSTcompleted taskto remain within the Statute of Limitations. All ePATAs submitted within a claim are closed with that
claim, and may not be re-used in a separate submittal,even for costs or tasks that were not originally claimed. Final reimbursement of costs associated with the Total Claimed
amount below may be affected by the eligibility status of the site (i.e., deductibles, apportionment, etc.), and the documentary validation of incurred costs as reasonable and
necessary expenses per 15A NCAC 2P .0402 and .0404.
BRE
HB
(Initials)
Brett Engard
ELECTRONIC PREAPPROVAL TASK AUTHORIZATION FORM
Dept of Environmental Quality -Division of Waste Management
Site Name City / County Incident #16199
Resp Pty Name / Contact Incident Mgr Region ASH
(Owner/Operator / Landowner / Attny-in-fact)Change Order?Prev. TA #21.1
Consultant / Project Mgr Samuel L McKay, III
Telephone / Fax Number Task Authorization Number:21 ChangeOrd:2
Project Mgr Email Site Risk / Rank / Abatement:H260D RRA Date:9/28/2021
Proposal# / Scope Dates % Commercial (C=100%, NC=0%, Both=1%-99%)
Has STF Eligibility Been Determined? (Y/N)Site Status (Active or NFA Date)
With Claim: [ ] All Main Consultant/Contractor invoices attached?[ ] Proof of payment attached directly to the front of each invoice?
w Important: The date of reimbursement is dependent on the Trust Fund balance. There may be a delay in the reimbursement of claims for work under this ePATA.
3r
d

P
t
y

D
e
d?
Task #Lab /
SubCode
RO

A
u
t
h
Proposed
Rate/Price
(Consultant)CO

A
u
t
h
Proposed Task
Subtotal
(Consultant)
Final
Preapproved
Subtotal
(UST Section)
Claimed
Amount3
(Consultant)
3.101 20 / foot Y $12.50 y $250.00 $250.00 /
3.113 20 / foot Y $50.00 y $1,000.00 $1,000.00 /
3.118 20 / foot Y $5.00 y $100.00 $100.00 /
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
Requested Preapproved Claimed3
TOTAL:$1,350.00 TOTAL:
Total Standard Costs (Not Third Party)$1,350.00 $1,350.00 Total Standard Costs
Total applied as Third Party Deductible/Damage Costs $0.00 $0.00 Total Third Pty Costs
Process Tracking (Date)
TA Submittal: 11/8/22 by:(PM)(Reserved for RO)
RO Review:11/8/22 by:(IM)Joint UST Preapproval Confirmed By:
CO Review: 11/9/22 by:(STF)RP or Designee Receipt Confirmation By:4
1 - This ePATA expires one year from the Joint UST Preapproval date. This does not extend, alter, or supersede any regulatory deadlines (e.g., NORR's, NOV's, Enforcements, etc.)
DWM/UST ePATA 4/1/2022
SLM
Proposed
Units / Type
(Consultant)
Brett Engard
ActiveYES
22-798 November, 2022
704-845-4012
Dates of Work
(Consultant)
Started1 / Completed2
100.00%
YES
[e-mail]
Arey Oil Company, Inc.Kay Piercy
Geological Resources, Inc.
DIRECTED COSTS
(Must Complete with Claim Submittal)(See Instructions / RRD for Tasks requiring Preapproval / Task Authorization)
Owner/Operator
704-845-4010
(Reserved for Incident Manager)
PREAPPROVAL / TASK AUTHORIZATION
Former Philbeck's Amoco
Note: This Electronic Preapproval Task Authorization (ePATA) shall be used to receive preapproval from the UST Section. A proposal,including maps andfigures,must be attached to
elaborate on the costs for the tasks listed below that describes the scope of work and the rationale for the proposed activities.If,following completion of this ePATA, you discover that
unexpected tasks must be performed, incurring costs for tasks not originally included with this form, you must complete and submit a separate ePATA request designated as a "Change
Order" in the provided space above prior to conducting those tasks. Include a copy of the prior ePATA form for confirmation. Please attach this form to the cover of the corresponding
claim when requesting reimbursement. IMPORTANT:Only one claim may be submitted per ePATA and all work on the ePATA must have been completed within 12 months of the
completion date of the FIRST completed task to remain within the Statute of Limitations. All ePATAs submitted within a claim are closed with that claim, and may not be re-used in a
separate submittal, even for costs or tasks that were not originally claimed. Final reimbursement of costs associated with the Total Claimed amount below may be affected by the
eligibility status of the site (i.e., deductibles, apportionment, etc.), and the documentary validation of incurred costs as reasonable and necessary expenses per 15A NCAC 2P .0402 and
.0404.
BRE
TC
(Initials)
Brett Engard
ELECTRONIC PREAPPROVAL TASK AUTHORIZATION FORM
Dept of Environmental Quality - Division of Waste Management
Site Name City / County /Cleveland Incident #16199
Resp Pty Name / Contact Incident Mgr Region ASH
RP Type (Owner/Operator / Landowner / Attny-in-fact)Change Order?Prev. TA #21.2
Consultant / Project Mgr /Samuel L. McKay, III
Telephone / Fax Number /21 3
Project Mgr Email H-260-D RRA Date:9/28/2021
Proposal# / Scope Dates /% Commercial (C=100%, NC=0%, Both=1%-99%)
Has STF Eligibility Been Determined? (Y/N)Site Status (Active or NFA Date)
With Claim: [ ] All Main Consultant/Contractor invoices attached?[ ] Proof of payment attached directly to the front of each invoice?
w
3r
d

P
ty

D
e
d
?
Task #Lab /
SubCode RO

Au
t
h
Proposed
Rate/Price
(Consultant)CO

Au
t
h
Proposed Task
Subtotal
(Consultant)
Final
Preapproved
Subtotal
(UST Section)
Claimed
Amount3
(Consultant)
2.084
2.084 8 / hour Y $20.00 Y $160.00 $160.00 /
12.030 1 / night Y $155.00 Y $155.00 $155.00 /
12.030 1 / night Y $155.00 Y $155.00 $155.00 /
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
Requested Preapproved Claimed
TOTAL:$570.00 $570.00 TOTAL:
Total Standard Costs (Not Third Party)$570.00 $570.00 Total Standard Costs
Total applied as Third Party Deductible/Damage Costs $0.00 $0.00 Total Third Pty Costs
Process Tracking (Date)
TA Submittal:11/21/22 by:(PM)(Reserved for RO)
RO Review: 11/22/22 by:(IM)Joint UST Preapproval Confirmed By:Date 11/30/2022
CO Review: 11/29/22 by:(STF)RP or Designee Receipt Confirmation By:Date 4
1 - This ePATA expires one year from the Joint UST Preapproval date. This does not extend, alter, or supersede any regulatory deadlines (e.g., NORR's, NOV's, Enforcements, etc.)
2 - THE ONE YEAR STATUTE OF LIMITATIONS APPLIES TO EACH INDIVIDUAL TASK. Costs must be claimed within one year of completion of that task to be reimbursable.
3 - Only Tasks included on this ePATA may be claimed. Do not include other Tasks or claimed costs (i.e., Claim preparation) that were not preapproved or the claim will be returned.
4 - Preapproval is not valid (i.e., claimable) until receipt is signed as 'Confirmed' by the RP or their designee and returned to the Trust Fund within a week of approval. Signature
indicates acknowledgement of the tasks and amounts approved. Any objections/appeals must be submitted via Change Order prior to work proceeding. Scope/cost
negotiations do not supersede other regulatory deadlines as described in #1 above. Also, any ePATA that has been signed as 'Confirmed' by both the UST Section and RP
is not to be modified without written consent by all signatories.
5 - Tasks approved on Directed - CAB Only ePATAs must be performed in accordance with all applicable rules, statutes, and RRD Task Scopes of Work to be reimbursed in full.
DWM/UST ePATA 4/1/2022
SLM
Proposed
Units / Type
(Consultant)
Brett Engard
ACTIVEYes
22-851 November, 2022
704-845-4012
Dates of Work
(Consultant)
Started1 / Completed2
100.00%
Yes
[e-mail]
Arey Oil Company Kay Piercy
Geological Resources, Inc.
Shelby
(Must Complete with Claim Submittal)(See Instructions / RRD for Tasks requiring Preapproval / Task Authorization)
Owner/Operator
704-845-4010
(Reserved for Incident Manager)
PREAPPROVAL / TASK AUTHORIZATION
Former Philbeck's Amoco
Note: This Electronic Preapproval Task Authorization (ePATA) shall be used to receive preapproval from the UST Section. A proposal,including maps and figures,must be attached
to elaborate on the costs for the tasks listed below that describes the scope of work and the rationale for the proposed activities.If, following completion of this ePATA, you
discover that unexpected tasks must be performed, incurring costs for tasks not originally included with this form, you must complete and submit a separate ePATA request
designated as a "Change Order" in the provided space above prior to conducting those tasks. Include a copy of the prior ePATA form for confirmation. Please attach this form to
the cover of the corresponding claim when requesting reimbursement. IMPORTANT:Only one claim may be submitted per ePATA and all work on the ePATA must have been
completed within 12months of the completion dateof the FIRST completed taskto remainwithin theStatute of Limitations. All ePATAs submitted within a claim are closed with that
claim, and may not be re-used in a separate submittal, even for costs or tasks that were not originally claimed. Final reimbursement of costs associated with the Total Claimed
amount below may be affected by the eligibility status of the site (i.e., deductibles, apportionment, etc.), and the documentary validation of incurred costs as reasonable and
necessary expenses per 15A NCAC 2P .0402 and .0404.
CEL
WER
(Initials)
Caroline LaFond
ELECTRONIC PREAPPROVAL TASK AUTHORIZATION FORM
Dept of Environmental Quality - Division of Waste Management
11-30-2022
5888 Received NOV 30 2022

APPENDIX B
Historical Soil Quality Information

APPENDIX C
Laboratory Analytical Reports

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

11/19/2022
Geological Resources, Inc. Sam McKay
3502 Hayes Road Monroe, NC, 28110
Ref: Analytical Testing
Lab Report Number: 22-314-0102 Client Project Description: Former Philbecks Amoco
GRI #5888 Project Number: GRI #
Dear Sam McKay:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 11/10/2022 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love Project Manager
Page 1 of 77
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2022402State ProgramNorth Carolina
07/31/202399012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/22-314-0102
Page 2 of 77
Report Number:
Sample Summary Table
Client Project Description:
22-314-0102
Former Philbecks Amoco
GRI #5888
Lab No Client Sample ID Matrix Date Collected Date Received
11/08/2022 08:30Solids 92825 MW-12 11/10/2022 13:44
11/08/2022 09:45Solids 92826 MW-13 11/10/2022 13:44
11/08/2022 14:55Aqueous 92827 WSW-14 11/10/2022 13:44
11/08/2022 15:05Aqueous 92828 WSW-15 11/10/2022 13:44
11/08/2022 14:50Aqueous 92829 WSW-16 11/10/2022 13:44
11/08/2022 07:15Aqueous 92830 11/10/2022 13:44
Page 3 of 77
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-314-0102
Report Limit
Project:Former Philbecks Amoco
V 92825MW-12
J0.015 11/11/2022 12:148260DAcetonemg/Kg - dry 0.003
26.6 11/14/2022 18:08SW-DRYWT Moisture %
V 92826MW-13
0.266 11/11/2022 12:418260DBenzenemg/Kg - dry 0.019
2.02 11/11/2022 12:418260Dn-Butylbenzene mg/Kg - dry 0.016
0.830 11/11/2022 12:418260Dsec-Butyl benzene mg/Kg - dry 0.018
5.22 11/11/2022 12:418260DEthylbenzenemg/Kg - dry 0.019
1.26 11/11/2022 12:418260Dn-Hexane mg/Kg - dry 0.021
0.863 11/11/2022 12:418260DIsopropylbenzenemg/Kg - dry 0.015
0.440 11/11/2022 12:418260D4-Isopropyl toluene mg/Kg - dry 0.042
3.63 11/11/2022 12:418260DNaphthalenemg/Kg - dry 0.032
4.29 11/11/2022 12:418260Dn-Propylbenzene mg/Kg - dry 0.017
J0.078 11/11/2022 12:418260DStyrenemg/Kg - dry 0.046
9.29 11/11/2022 12:418260DToluenemg/Kg - dry 0.021
28.4 11/11/2022 13:098260D1,2,4-Trimethylbenzene mg/Kg - dry 0.161
7.88 11/11/2022 12:418260D1,3,5-Trimethylbenzene mg/Kg - dry 0.017
8.41 11/11/2022 12:418260Do-Xylene mg/Kg - dry 0.016
20.1 11/11/2022 12:418260Dm,p-Xylene mg/Kg - dry 0.041
28.4 11/11/2022 12:418260DXylene (Total)mg/Kg - dry 0.016
1.02 11/17/2022 18:048270E1-Methylnaphthalene mg/Kg - dry 0.138
1.94 11/17/2022 18:048270E2-Methylnaphthalene mg/Kg - dry 0.131
1.55 11/17/2022 18:048270ENaphthalenemg/Kg - dry 0.188
48.4 11/11/2022 12:41CALCULATIONAliphatic C5-C8 (Adjusted)mg/Kg - dry 1.60
64.5 11/11/2022 12:55CALCULATIONAromatic C9-C10 (Adjusted)mg/Kg - dry 0.817
J51.1 11/16/2022 16:39CALCULATIONAromatic C11-C22 (Adjusted)mg/Kg - dry 18.6
168 11/16/2022 16:39MADEP-EPH Aliphatic C9-C18 mg/Kg - dry 12.1
J52.7 11/16/2022 16:39MADEP-EPH Aromatic C11-C22 mg/Kg - dry 18.6
57.9 11/11/2022 12:55MADEP-VPH Aliphatic C5-C8 mg/Kg - dry 1.60
103 11/11/2022 12:55MADEP-VPH Aliphatic C9-C12 mg/Kg - dry 5.98
64.5 11/11/2022 12:55MADEP-VPH Aromatic C9-C10 mg/Kg - dry 0.817
23.7 11/14/2022 18:08SW-DRYWT Moisture %
V 92827WSW-14
1.64 11/18/2022 01:336200BMethyl tert-butyl ether (MTBE)µg/L 0.140
J0.446 11/18/2022 01:336200B1,2,4-Trimethylbenzene µg/L 0.190
J0.261 11/18/2022 01:336200Bo-Xylene µg/L 0.210
Page 4 of 77
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-314-0102
Report Limit
Project:Former Philbecks Amoco
V 92827WSW-14
J0.261 11/18/2022 01:336200BXylene (Total)µg/L 0.210
V 92828WSW-15
4.09 11/18/2022 02:436200BBromodichloromethaneµg/L 0.160
32.6 11/18/2022 02:436200BChloroformµg/L 0.220
V 92829WSW-16
4.24 11/18/2022 01:566200BBromodichloromethaneµg/L 0.160
40.2 11/18/2022 01:566200BChloroformµg/L 0.220
Page 5 of 77

Client: Geological Resources, Inc. CASE NARRATIVE
Project: Former Philbecks Amoco Lab Report Number: 22-314-0102
Date: 11/18/2022
Semivolatile Organic Compounds - GC/MS Method 8270E Sample 93010 (SB-3-20') Analyte: Benzoic Acid QC Batch No: V26590/V26440 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.

Page 6 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:MW-12
92825 Matrix:
11/8/2022 8:30
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
26.6 %Moisture 1 11/14/22 18:08 SW-DRYWTAMB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 7 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:MW-12
92825 Matrix:
11/8/2022 8:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 LOW
8260D Prep Batch(es):11/11/22 08:00
0.015 J mg/Kg - dry 0.003 0.027Acetone 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.027Acrolein 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.027Acrylonitrile 1 11/11/22 12:14 V26294TBL
<0.0008 mg/Kg - dry 0.0008 0.006Benzene 1 11/11/22 12:14 V26294TBL
<0.0007 mg/Kg - dry 0.0007 0.006Bromobenzene 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.006Bromochloromethane 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.006Bromodichloromethane 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.006Bromoform 1 11/11/22 12:14 V26294TBL
<0.002 mg/Kg - dry 0.002 0.013Bromomethane 1 11/11/22 12:14 V26294TBL
<0.0007 mg/Kg - dry 0.0007 0.006n-Butylbenzene 1 11/11/22 12:14 V26294TBL
<0.0008 mg/Kg - dry 0.0008 0.006sec-Butyl benzene 1 11/11/22 12:14 V26294TBL
<0.0007 mg/Kg - dry 0.0007 0.006tert-Butyl benzene 1 11/11/22 12:14 V26294TBL
<0.0009 mg/Kg - dry 0.0009 0.006Carbon Disulfide 1 11/11/22 12:14 V26294TBL
<0.002 mg/Kg - dry 0.002 0.006Carbon Tetrachloride 1 11/11/22 12:14 V26294TBL
<0.0009 mg/Kg - dry 0.0009 0.006Chlorobenzene 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.006Chlorodibromomethane 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.013Chloroethane 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.006Chloroform 1 11/11/22 12:14 V26294TBL
<0.0009 mg/Kg - dry 0.0009 0.013Chloromethane 1 11/11/22 12:14 V26294TBL
<0.0007 mg/Kg - dry 0.0007 0.0062-Chlorotoluene 1 11/11/22 12:14 V26294TBL
<0.0005 mg/Kg - dry 0.0005 0.0064-Chlorotoluene 1 11/11/22 12:14 V26294TBL
<0.0010 mg/Kg - dry 0.0010 0.006Di-Isopropyl Ether (DIPE)1 11/11/22 12:14 V26294TBL
<0.0006 mg/Kg - dry 0.0006 0.0131,2-Dibromo-3-Chloropropane 1 11/11/22 12:14 V26294TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 8 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:MW-12
92825 Matrix:
11/8/2022 8:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 LOW
8260D Prep Batch(es):11/11/22 08:00
<0.0008 mg/Kg - dry 0.0008 0.0061,2-Dibromoethane 1 11/11/22 12:14 V26294TBL
<0.0008 mg/Kg - dry 0.0008 0.006Dibromomethane 1 11/11/22 12:14 V26294TBL
<0.0004 mg/Kg - dry 0.0004 0.0061,2-Dichlorobenzene 1 11/11/22 12:14 V26294TBL
<0.0005 mg/Kg - dry 0.0005 0.0061,3-Dichlorobenzene 1 11/11/22 12:14 V26294TBL
<0.0008 mg/Kg - dry 0.0008 0.0061,4-Dichlorobenzene 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.013Dichlorodifluoromethane 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.0061,1-Dichloroethane 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.0061,2-Dichloroethane 1 11/11/22 12:14 V26294TBL
<0.0010 mg/Kg - dry 0.0010 0.0061,1-Dichloroethene 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.006cis-1,2-Dichloroethene 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.006trans-1,2-Dichloroethene 1 11/11/22 12:14 V26294TBL
<0.0006 mg/Kg - dry 0.0006 0.0061,2-Dichloropropane 1 11/11/22 12:14 V26294TBL
<0.0007 mg/Kg - dry 0.0007 0.0061,3-Dichloropropane 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.0062,2-Dichloropropane 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.0061,1-Dichloropropene 1 11/11/22 12:14 V26294TBL
<0.0007 mg/Kg - dry 0.0007 0.006cis-1,3-Dichloropropene 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.006trans-1,3-Dichloropropene 1 11/11/22 12:14 V26294TBL
<0.019 mg/Kg - dry 0.019 0.340Ethanol 1 11/11/22 12:14 V26294TBL
<0.0008 mg/Kg - dry 0.0008 0.006Ethylbenzene 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.068Ethyl Tertiary Butyl Ether (ETBE)1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.013Hexachlorobutadiene 1 11/11/22 12:14 V26294TBL
<0.0009 mg/Kg - dry 0.0009 0.013n-Hexane 1 11/11/22 12:14 V26294TBL
<0.0008 mg/Kg - dry 0.0008 0.0272-Hexanone 1 11/11/22 12:14 V26294TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 9 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:MW-12
92825 Matrix:
11/8/2022 8:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 LOW
8260D Prep Batch(es):11/11/22 08:00
<0.0006 mg/Kg - dry 0.0006 0.006Isopropylbenzene 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.0064-Isopropyl toluene 1 11/11/22 12:14 V26294TBL
<0.0009 mg/Kg - dry 0.0009 0.027Methyl Ethyl Ketone (MEK)1 11/11/22 12:14 V26294TBL
<0.0008 mg/Kg - dry 0.0008 0.006Methyl tert-butyl ether (MTBE)1 11/11/22 12:14 V26294TBL
<0.020 mg/Kg - dry 0.020 0.0274-Methyl-2-Pentanone 1 11/11/22 12:14 V26294TBL
<0.002 mg/Kg - dry 0.002 0.013Methylene Chloride 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.013Naphthalene 1 11/11/22 12:14 V26294TBL
<0.0007 mg/Kg - dry 0.0007 0.006n-Propylbenzene 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.006Styrene 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.272tert-Butyl Alcohol (TBA)1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.544tert-Butyl formate (TBF)1 11/11/22 12:14 V26294TBL
<0.0006 mg/Kg - dry 0.0006 0.544tert-Amyl Alcohol (TAA)1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.136tert-Amyl Methyl Ether (TAME)1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.0061,1,1,2-Tetrachloroethane 1 11/11/22 12:14 V26294TBL
<0.0004 mg/Kg - dry 0.0004 0.0061,1,2,2-Tetrachloroethane 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.006 1 11/11/22 12:14 V26294TBL
<0.0009 mg/Kg - dry 0.0009 0.006 1 11/11/22 12:14 V26294TBL
<0.0007 mg/Kg - dry 0.0007 0.0131,2,3-Trichlorobenzene 1 11/11/22 12:14 V26294TBL
<0.0009 mg/Kg - dry 0.0009 0.0131,2,4-Trichlorobenzene 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.0061,1,1-Trichloroethane 1 11/11/22 12:14 V26294TBL
<0.0006 mg/Kg - dry 0.0006 0.0061,1,2-Trichloroethane 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.006 1 11/11/22 12:14 V26294TBL
<0.002 mg/Kg - dry 0.002 0.013 1 11/11/22 12:14 V26294TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 10 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:MW-12
92825 Matrix:
11/8/2022 8:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 LOW
8260D Prep Batch(es):11/11/22 08:00
<0.0010 mg/Kg - dry 0.0010 0.0061,2,3-Trichloropropane 1 11/11/22 12:14 V26294TBL
<0.0007 mg/Kg - dry 0.0007 0.0061,2,4-Trimethylbenzene 1 11/11/22 12:14 V26294TBL
<0.0007 mg/Kg - dry 0.0007 0.0061,3,5-Trimethylbenzene 1 11/11/22 12:14 V26294TBL
<0.0006 mg/Kg - dry 0.0006 0.013Vinyl Acetate 1 11/11/22 12:14 V26294TBL
<0.0007 mg/Kg - dry 0.0007 0.013Vinyl Chloride 1 11/11/22 12:14 V26294TBL
<0.0007 mg/Kg - dry 0.0007 0.006o-Xylene 1 11/11/22 12:14 V26294TBL
<0.001 mg/Kg - dry 0.001 0.013m,p-Xylene 1 11/11/22 12:14 V26294TBL
<0.0007 mg/Kg - dry 0.0007 0.006Xylene (Total)1 11/11/22 12:14 V26294
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: Toluene-d8
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):11/15/22 11:15
<0.158 mg/Kg - dry 0.158 0.899Acenaphthene 1 11/17/22 15:04 V26590JMV
<0.143 mg/Kg - dry 0.143 0.899Acenaphthylene 1 11/17/22 15:04 V26590JMV
<0.207 mg/Kg - dry 0.207 0.899Aniline 1 11/17/22 15:04 V26590JMV
<0.194 mg/Kg - dry 0.194 0.899Anthracene 1 11/17/22 15:04 V26590JMV
<0.189 mg/Kg - dry 0.189 0.899Benzo(a)anthracene 1 11/17/22 15:04 V26590JMV
<0.200 mg/Kg - dry 0.200 0.899Benzo(a)pyrene 1 11/17/22 15:04 V26590JMV
<0.198 mg/Kg - dry 0.198 0.899Benzo(b)fluoranthene 1 11/17/22 15:04 V26590JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 11 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:MW-12
92825 Matrix:
11/8/2022 8:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):11/15/22 11:15
<0.185 mg/Kg - dry 0.185 0.899Benzo(g,h,i)perylene 1 11/17/22 15:04 V26590JMV
<0.186 mg/Kg - dry 0.186 0.899Benzo(k)fluoranthene 1 11/17/22 15:04 V26590JMV
<0.790 mg/Kg - dry 0.790 2.72Benzoic Acid 1 11/17/22 15:04 V26590JMV
<0.143 mg/Kg - dry 0.143 0.899Benzyl alcohol 1 11/17/22 15:04 V26590JMV
<0.160 mg/Kg - dry 0.160 0.899Bis(2-Chloroethoxy)methane 1 11/17/22 15:04 V26590JMV
<0.145 mg/Kg - dry 0.145 0.899Bis(2-Chloroethyl)ether 1 11/17/22 15:04 V26590JMV
<0.185 mg/Kg - dry 0.185 0.449Bis(2-Chloroisopropyl)ether 1 11/17/22 15:04 V26590JMV
<0.163 mg/Kg - dry 0.163 0.899Bis(2-ethylhexyl)phthalate 1 11/17/22 15:04 V26590JMV
<0.148 mg/Kg - dry 0.148 0.8994-Bromophenyl phenyl ether 1 11/17/22 15:04 V26590JMV
<0.153 mg/Kg - dry 0.153 0.449Butyl benzyl phthalate 1 11/17/22 15:04 V26590JMV
<0.125 mg/Kg - dry 0.125 0.8994-Chloro-3-methylphenol 1 11/17/22 15:04 V26590JMV
<0.152 mg/Kg - dry 0.152 0.4494-Chloroaniline 1 11/17/22 15:04 V26590JMV
<0.158 mg/Kg - dry 0.158 0.8992-Chloronaphthalene 1 11/17/22 15:04 V26590JMV
<0.133 mg/Kg - dry 0.133 0.8992-Chlorophenol 1 11/17/22 15:04 V26590JMV
<0.171 mg/Kg - dry 0.171 1.364-Chlorophenyl phenyl ether 1 11/17/22 15:04 V26590JMV
<0.193 mg/Kg - dry 0.193 0.899Chrysene 1 11/17/22 15:04 V26590JMV
<0.313 mg/Kg - dry 0.313 0.899Dibenz(a,h)anthracene 1 11/17/22 15:04 V26590JMV
<0.162 mg/Kg - dry 0.162 0.899Dibenzofuran 1 11/17/22 15:04 V26590JMV
<0.128 mg/Kg - dry 0.128 0.8991,2-Dichlorobenzene 1 11/17/22 15:04 V26590JMV
<0.132 mg/Kg - dry 0.132 0.8991,3-Dichlorobenzene 1 11/17/22 15:04 V26590JMV
<0.132 mg/Kg - dry 0.132 0.4491,4-Dichlorobenzene 1 11/17/22 15:04 V26590JMV
<0.200 mg/Kg - dry 0.200 0.8993,3'-Dichlorobenzidine 1 11/17/22 15:04 V26590JMV
<0.130 mg/Kg - dry 0.130 0.8992,4-Dichlorophenol 1 11/17/22 15:04 V26590JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 12 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:MW-12
92825 Matrix:
11/8/2022 8:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):11/15/22 11:15
<0.245 mg/Kg - dry 0.245 0.899Diethyl phthalate 1 11/17/22 15:04 V26590JMV
<0.237 mg/Kg - dry 0.237 0.899Dimethyl phthalate 1 11/17/22 15:04 V26590JMV
<0.147 mg/Kg - dry 0.147 0.4492,4-Dimethylphenol 1 11/17/22 15:04 V26590JMV
<0.145 mg/Kg - dry 0.145 0.899Di-n-butyl phthalate 1 11/17/22 15:04 V26590JMV
<0.326 mg/Kg - dry 0.326 2.044,6-Dinitro-2-methylphenol 1 11/17/22 15:04 V26590JMV
<0.708 mg/Kg - dry 0.708 2.042,4-Dinitrophenol 1 11/17/22 15:04 V26590JMV
<0.131 mg/Kg - dry 0.131 0.8992,4-Dinitrotoluene 1 11/17/22 15:04 V26590JMV
<0.147 mg/Kg - dry 0.147 0.8992,6-Dinitrotoluene 1 11/17/22 15:04 V26590JMV
<0.194 mg/Kg - dry 0.194 0.449Di-n-Octyl Phthalate 1 11/17/22 15:04 V26590JMV
<0.167 mg/Kg - dry 0.167 0.899Fluoranthene 1 11/17/22 15:04 V26590JMV
<0.174 mg/Kg - dry 0.174 0.899Fluorene 1 11/17/22 15:04 V26590JMV
<0.144 mg/Kg - dry 0.144 0.899Hexachlorobenzene 1 11/17/22 15:04 V26590JMV
<0.132 mg/Kg - dry 0.132 0.899Hexachlorobutadiene 1 11/17/22 15:04 V26590JMV
<0.213 mg/Kg - dry 0.213 0.899Hexachlorocyclopentadiene 1 11/17/22 15:04 V26590JMV
<0.107 mg/Kg - dry 0.107 0.899Hexachloroethane 1 11/17/22 15:04 V26590JMV
<0.243 mg/Kg - dry 0.243 0.899Indeno(1,2,3-cd)pyrene 1 11/17/22 15:04 V26590JMV
<0.260 mg/Kg - dry 0.260 0.899Isophorone 1 11/17/22 15:04 V26590JMV
<0.144 mg/Kg - dry 0.144 0.8991-Methylnaphthalene 1 11/17/22 15:04 V26590JMV
<0.136 mg/Kg - dry 0.136 0.8992-Methylnaphthalene 1 11/17/22 15:04 V26590JMV
<0.132 mg/Kg - dry 0.132 0.8992-Methylphenol 1 11/17/22 15:04 V26590JMV
<0.115 mg/Kg - dry 0.115 0.8993&4 Methylphenol 1 11/17/22 15:04 V26590JMV
<0.196 mg/Kg - dry 0.196 0.899Naphthalene 1 11/17/22 15:04 V26590JMV
<0.131 mg/Kg - dry 0.131 0.8992-Nitroaniline 1 11/17/22 15:04 V26590JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 13 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:MW-12
92825 Matrix:
11/8/2022 8:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):11/15/22 11:15
<0.163 mg/Kg - dry 0.163 0.8993-Nitroaniline 1 11/17/22 15:04 V26590JMV
<0.127 mg/Kg - dry 0.127 0.4494-Nitroaniline 1 11/17/22 15:04 V26590JMV
<0.158 mg/Kg - dry 0.158 0.449Nitrobenzene 1 11/17/22 15:04 V26590JMV
<0.120 mg/Kg - dry 0.120 0.8992-Nitrophenol 1 11/17/22 15:04 V26590JMV
<0.159 mg/Kg - dry 0.159 0.8994-Nitrophenol 1 11/17/22 15:04 V26590JMV
<0.358 mg/Kg - dry 0.358 0.899N-Nitrosodimethylamine 1 11/17/22 15:04 V26590JMV
<0.246 mg/Kg - dry 0.246 0.899N-Nitrosodiphenylamine 1 11/17/22 15:04 V26590JMV
<0.160 mg/Kg - dry 0.160 0.899N-Nitroso-di-n-propylamine 1 11/17/22 15:04 V26590JMV
<0.472 mg/Kg - dry 0.472 1.36Pentachlorophenol 1 11/17/22 15:04 V26590JMV
<0.283 mg/Kg - dry 0.283 0.899Phenanthrene 1 11/17/22 15:04 V26590JMV
<0.152 mg/Kg - dry 0.152 0.899Phenol 1 11/17/22 15:04 V26590JMV
<0.182 mg/Kg - dry 0.182 0.899Pyrene 1 11/17/22 15:04 V26590JMV
<0.107 mg/Kg - dry 0.107 0.449Pyridine 1 11/17/22 15:04 V26590JMV
<0.145 mg/Kg - dry 0.145 0.8991,2,4-Trichlorobenzene 1 11/17/22 15:04 V26590JMV
<0.131 mg/Kg - dry 0.131 0.8992,4,5-Trichlorophenol 1 11/17/22 15:04 V26590JMV
<0.131 mg/Kg - dry 0.131 0.8992,4,6-Trichlorophenol 1 11/17/22 15:04 V26590JMV
Surrogate: Phenol-d5
Surrogate: 2-Fluorobiphenyl
Surrogate: 2-Fluorophenol
Surrogate: Nitrobenzene-d5
Surrogate: 4-Terphenyl-d14
Surrogate: 2,4,6-Tribromophenol
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 14 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:MW-12
92825 Matrix:
11/8/2022 8:30
Solids
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<1.66 mg/Kg - dry 1.66 10.9Aliphatic C5-C8 (Adjusted)1 11/11/22 12:14
<6.21 mg/Kg - dry 6.21 10.9Aliphatics C9-C12 (Adjusted)1 11/11/22 12:14
<0.850 mg/Kg - dry 0.850 10.9Aromatic C9-C10 (Adjusted)100 11/11/22 12:31
<19.3 mg/Kg - dry 19.3 68.3Aromatic C11-C22 (Adjusted)1 11/16/22 16:02
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):11/14/22 11:00
<12.6 mg/Kg - dry 12.6 68.3Aliphatic C9-C18 1 11/16/22 16:02 V26522JLK
<16.6 mg/Kg - dry 16.6 68.3Aliphatic C19-C36 1 11/16/22 16:02 V26522JLK
<19.3 mg/Kg - dry 19.3 68.3Aromatic C11-C22 1 11/16/22 16:02 V26522JLK
Surrogate: 2-Bromonaphthalene
Surrogate: Chlorooctadecane
Surrogate: OTP Surrogate
Surrogate: 2-Fluorobiphenyl
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):11/11/22 08:00
<1.66 mg/Kg - dry 1.66 10.9Aliphatic C5-C8 100 11/11/22 12:31 V26292TBL
<6.21 mg/Kg - dry 6.21 10.9Aliphatic C9-C12 100 11/11/22 12:31 V26292TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 15 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:MW-12
92825 Matrix:
11/8/2022 8:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):11/11/22 08:00
<0.850 mg/Kg - dry 0.850 10.9Aromatic C9-C10 100 11/11/22 12:31 V26292TBL
Surrogate: 2,5-Dibromotoluene (FID)
Surrogate: 2,5-Dibromotoluene (PID)
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 16 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:MW-13
92826 Matrix:
11/8/2022 9:45
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
23.7 %Moisture 1 11/14/22 18:08 SW-DRYWTAMB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 17 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:MW-13
92826 Matrix:
11/8/2022 9:45
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 MED
8260D Prep Batch(es):11/11/22 08:00
<0.078 mg/Kg - dry 0.078 0.655Acetone 50 11/11/22 12:41 V26296TBL
<0.039 mg/Kg - dry 0.039 0.655Acrolein 50 11/11/22 12:41 V26296TBL
<0.024 mg/Kg - dry 0.024 0.655Acrylonitrile 50 11/11/22 12:41 V26296TBL
0.266 mg/Kg - dry 0.019 0.163Benzene 50 11/11/22 12:41 V26296TBL
<0.016 mg/Kg - dry 0.016 0.163Bromobenzene 50 11/11/22 12:41 V26296TBL
<0.026 mg/Kg - dry 0.026 0.163Bromochloromethane 50 11/11/22 12:41 V26296TBL
<0.039 mg/Kg - dry 0.039 0.163Bromodichloromethane 50 11/11/22 12:41 V26296TBL
<0.033 mg/Kg - dry 0.033 0.163Bromoform 50 11/11/22 12:41 V26296TBL
<0.059 mg/Kg - dry 0.059 0.327Bromomethane 50 11/11/22 12:41 V26296TBL
2.02 mg/Kg - dry 0.016 0.163n-Butylbenzene 50 11/11/22 12:41 V26296TBL
0.830 mg/Kg - dry 0.018 0.163sec-Butyl benzene 50 11/11/22 12:41 V26296TBL
<0.016 mg/Kg - dry 0.016 0.163tert-Butyl benzene 50 11/11/22 12:41 V26296TBL
<0.020 mg/Kg - dry 0.020 0.163Carbon Disulfide 50 11/11/22 12:41 V26296TBL
<0.051 mg/Kg - dry 0.051 0.163Carbon Tetrachloride 50 11/11/22 12:41 V26296TBL
<0.022 mg/Kg - dry 0.022 0.163Chlorobenzene 50 11/11/22 12:41 V26296TBL
<0.029 mg/Kg - dry 0.029 0.163Chlorodibromomethane 50 11/11/22 12:41 V26296TBL
<0.029 mg/Kg - dry 0.029 0.327Chloroethane 50 11/11/22 12:41 V26296TBL
<0.034 mg/Kg - dry 0.034 0.163Chloroform 50 11/11/22 12:41 V26296TBL
<0.020 mg/Kg - dry 0.020 0.327Chloromethane 50 11/11/22 12:41 V26296TBL
<0.016 mg/Kg - dry 0.016 0.1632-Chlorotoluene 50 11/11/22 12:41 V26296TBL
<0.012 mg/Kg - dry 0.012 0.1634-Chlorotoluene 50 11/11/22 12:41 V26296TBL
<0.023 mg/Kg - dry 0.023 0.163Di-Isopropyl Ether (DIPE)50 11/11/22 12:41 V26296TBL
<0.014 mg/Kg - dry 0.014 0.3271,2-Dibromo-3-Chloropropane 50 11/11/22 12:41 V26296TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 18 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:MW-13
92826 Matrix:
11/8/2022 9:45
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 MED
8260D Prep Batch(es):11/11/22 08:00
<0.019 mg/Kg - dry 0.019 0.1631,2-Dibromoethane 50 11/11/22 12:41 V26296TBL
<0.032 mg/Kg - dry 0.032 0.163Dibromomethane 50 11/11/22 12:41 V26296TBL
<0.010 mg/Kg - dry 0.010 0.1631,2-Dichlorobenzene 50 11/11/22 12:41 V26296TBL
<0.012 mg/Kg - dry 0.012 0.1631,3-Dichlorobenzene 50 11/11/22 12:41 V26296TBL
<0.019 mg/Kg - dry 0.019 0.1631,4-Dichlorobenzene 50 11/11/22 12:41 V26296TBL
<0.043 mg/Kg - dry 0.043 0.327Dichlorodifluoromethane 50 11/11/22 12:41 V26296TBL
<0.026 mg/Kg - dry 0.026 0.1631,1-Dichloroethane 50 11/11/22 12:41 V26296TBL
<0.045 mg/Kg - dry 0.045 0.1631,2-Dichloroethane 50 11/11/22 12:41 V26296TBL
<0.023 mg/Kg - dry 0.023 0.1631,1-Dichloroethene 50 11/11/22 12:41 V26296TBL
<0.025 mg/Kg - dry 0.025 0.163cis-1,2-Dichloroethene 50 11/11/22 12:41 V26296TBL
<0.034 mg/Kg - dry 0.034 0.163trans-1,2-Dichloroethene 50 11/11/22 12:41 V26296TBL
<0.014 mg/Kg - dry 0.014 0.1631,2-Dichloropropane 50 11/11/22 12:41 V26296TBL
<0.018 mg/Kg - dry 0.018 0.1631,3-Dichloropropane 50 11/11/22 12:41 V26296TBL
<0.041 mg/Kg - dry 0.041 0.1632,2-Dichloropropane 50 11/11/22 12:41 V26296TBL
<0.024 mg/Kg - dry 0.024 0.1631,1-Dichloropropene 50 11/11/22 12:41 V26296TBL
<0.017 mg/Kg - dry 0.017 0.163cis-1,3-Dichloropropene 50 11/11/22 12:41 V26296TBL
<0.026 mg/Kg - dry 0.026 0.163trans-1,3-Dichloropropene 50 11/11/22 12:41 V26296TBL
<0.475 mg/Kg - dry 0.475 8.19Ethanol 50 11/11/22 12:41 V26296TBL
5.22 mg/Kg - dry 0.019 0.163Ethylbenzene 50 11/11/22 12:41 V26296TBL
<0.027 mg/Kg - dry 0.027 3.28Ethyl Tertiary Butyl Ether (ETBE)50 11/11/22 12:41 V26296TBL
<0.025 mg/Kg - dry 0.025 0.327Hexachlorobutadiene 50 11/11/22 12:41 V26296TBL
1.26 mg/Kg - dry 0.021 0.327n-Hexane 50 11/11/22 12:41 V26296TBL
<0.020 mg/Kg - dry 0.020 0.6552-Hexanone 50 11/11/22 12:41 V26296TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 19 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:MW-13
92826 Matrix:
11/8/2022 9:45
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 MED
8260D Prep Batch(es):11/11/22 08:00
0.863 mg/Kg - dry 0.015 0.163Isopropylbenzene 50 11/11/22 12:41 V26296TBL
0.440 mg/Kg - dry 0.042 0.1634-Isopropyl toluene 50 11/11/22 12:41 V26296TBL
<0.021 mg/Kg - dry 0.021 0.655Methyl Ethyl Ketone (MEK)50 11/11/22 12:41 V26296TBL
<0.020 mg/Kg - dry 0.020 0.163Methyl tert-butyl ether (MTBE)50 11/11/22 12:41 V26296TBL
<0.491 mg/Kg - dry 0.491 0.6554-Methyl-2-Pentanone 50 11/11/22 12:41 V26296TBL
<0.048 mg/Kg - dry 0.048 0.163Methylene Chloride 50 11/11/22 12:41 V26296TBL
3.63 mg/Kg - dry 0.032 0.327Naphthalene 50 11/11/22 12:41 V26296TBL
4.29 mg/Kg - dry 0.017 0.163n-Propylbenzene 50 11/11/22 12:41 V26296TBL
0.078 J mg/Kg - dry 0.046 0.163Styrene 50 11/11/22 12:41 V26296TBL
<0.032 mg/Kg - dry 0.032 6.55tert-Butyl Alcohol (TBA)50 11/11/22 12:41 V26296TBL
<0.035 mg/Kg - dry 0.035 13.1tert-Butyl formate (TBF)50 11/11/22 12:41 V26296TBL
<0.014 mg/Kg - dry 0.014 13.1tert-Amyl Alcohol (TAA)50 11/11/22 12:41 V26296TBL
<0.024 mg/Kg - dry 0.024 3.28tert-Amyl Methyl Ether (TAME)50 11/11/22 12:41 V26296TBL
<0.034 mg/Kg - dry 0.034 0.1631,1,1,2-Tetrachloroethane 50 11/11/22 12:41 V26296TBL
<0.010 mg/Kg - dry 0.010 0.1631,1,2,2-Tetrachloroethane 50 11/11/22 12:41 V26296TBL
<0.029 mg/Kg - dry 0.029 0.163 50 11/11/22 12:41 V26296TBL
9.29 mg/Kg - dry 0.021 0.163 50 11/11/22 12:41 V26296TBL
<0.017 mg/Kg - dry 0.017 0.3271,2,3-Trichlorobenzene 50 11/11/22 12:41 V26296TBL
<0.020 mg/Kg - dry 0.020 0.3271,2,4-Trichlorobenzene 50 11/11/22 12:41 V26296TBL
<0.047 mg/Kg - dry 0.047 0.1631,1,1-Trichloroethane 50 11/11/22 12:41 V26296TBL
<0.015 mg/Kg - dry 0.015 0.1631,1,2-Trichloroethane 50 11/11/22 12:41 V26296TBL
<0.030 mg/Kg - dry 0.030 0.163 50 11/11/22 12:41 V26296TBL
<0.068 mg/Kg - dry 0.068 0.327 50 11/11/22 12:41 V26296TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 20 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:MW-13
92826 Matrix:
11/8/2022 9:45
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 MED
8260D Prep Batch(es):11/11/22 08:00
<0.023 mg/Kg - dry 0.023 0.1631,2,3-Trichloropropane 50 11/11/22 12:41 V26296TBL
28.4 mg/Kg - dry 0.161 1.641,2,4-Trimethylbenzene 500 11/11/22 13:09 V26296TBL
7.88 mg/Kg - dry 0.017 0.1631,3,5-Trimethylbenzene 50 11/11/22 12:41 V26296TBL
<0.015 mg/Kg - dry 0.015 0.327Vinyl Acetate 50 11/11/22 12:41 V26296TBL
<0.015 mg/Kg - dry 0.015 0.327Vinyl Chloride 50 11/11/22 12:41 V26296TBL
8.41 mg/Kg - dry 0.016 0.163o-Xylene 50 11/11/22 12:41 V26296TBL
20.1 mg/Kg - dry 0.041 0.327m,p-Xylene 50 11/11/22 12:41 V26296TBL
28.4 mg/Kg - dry 0.016 0.163Xylene (Total)50 11/11/22 12:41 V26296
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: Toluene-d8
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: Toluene-d8
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):11/15/22 11:15
<0.152 mg/Kg - dry 0.152 0.866Acenaphthene 1 11/17/22 18:04 V26590JMV
<0.137 mg/Kg - dry 0.137 0.866Acenaphthylene 1 11/17/22 18:04 V26590JMV
<0.199 mg/Kg - dry 0.199 0.866Aniline 1 11/17/22 18:04 V26590JMV
<0.187 mg/Kg - dry 0.187 0.866Anthracene 1 11/17/22 18:04 V26590JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 21 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:MW-13
92826 Matrix:
11/8/2022 9:45
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):11/15/22 11:15
<0.182 mg/Kg - dry 0.182 0.866Benzo(a)anthracene 1 11/17/22 18:04 V26590JMV
<0.192 mg/Kg - dry 0.192 0.866Benzo(a)pyrene 1 11/17/22 18:04 V26590JMV
<0.191 mg/Kg - dry 0.191 0.866Benzo(b)fluoranthene 1 11/17/22 18:04 V26590JMV
<0.178 mg/Kg - dry 0.178 0.866Benzo(g,h,i)perylene 1 11/17/22 18:04 V26590JMV
<0.179 mg/Kg - dry 0.179 0.866Benzo(k)fluoranthene 1 11/17/22 18:04 V26590JMV
<0.760 mg/Kg - dry 0.760 2.62Benzoic Acid 1 11/17/22 18:04 V26590JMV
<0.137 mg/Kg - dry 0.137 0.866Benzyl alcohol 1 11/17/22 18:04 V26590JMV
<0.154 mg/Kg - dry 0.154 0.866Bis(2-Chloroethoxy)methane 1 11/17/22 18:04 V26590JMV
<0.140 mg/Kg - dry 0.140 0.866Bis(2-Chloroethyl)ether 1 11/17/22 18:04 V26590JMV
<0.178 mg/Kg - dry 0.178 0.432Bis(2-Chloroisopropyl)ether 1 11/17/22 18:04 V26590JMV
<0.157 mg/Kg - dry 0.157 0.866Bis(2-ethylhexyl)phthalate 1 11/17/22 18:04 V26590JMV
<0.142 mg/Kg - dry 0.142 0.8664-Bromophenyl phenyl ether 1 11/17/22 18:04 V26590JMV
<0.148 mg/Kg - dry 0.148 0.432Butyl benzyl phthalate 1 11/17/22 18:04 V26590JMV
<0.121 mg/Kg - dry 0.121 0.8664-Chloro-3-methylphenol 1 11/17/22 18:04 V26590JMV
<0.146 mg/Kg - dry 0.146 0.4324-Chloroaniline 1 11/17/22 18:04 V26590JMV
<0.152 mg/Kg - dry 0.152 0.8662-Chloronaphthalene 1 11/17/22 18:04 V26590JMV
<0.128 mg/Kg - dry 0.128 0.8662-Chlorophenol 1 11/17/22 18:04 V26590JMV
<0.165 mg/Kg - dry 0.165 1.314-Chlorophenyl phenyl ether 1 11/17/22 18:04 V26590JMV
<0.186 mg/Kg - dry 0.186 0.866Chrysene 1 11/17/22 18:04 V26590JMV
<0.301 mg/Kg - dry 0.301 0.866Dibenz(a,h)anthracene 1 11/17/22 18:04 V26590JMV
<0.155 mg/Kg - dry 0.155 0.866Dibenzofuran 1 11/17/22 18:04 V26590JMV
<0.123 mg/Kg - dry 0.123 0.8661,2-Dichlorobenzene 1 11/17/22 18:04 V26590JMV
<0.127 mg/Kg - dry 0.127 0.8661,3-Dichlorobenzene 1 11/17/22 18:04 V26590JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 22 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:MW-13
92826 Matrix:
11/8/2022 9:45
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):11/15/22 11:15
<0.127 mg/Kg - dry 0.127 0.4321,4-Dichlorobenzene 1 11/17/22 18:04 V26590JMV
<0.192 mg/Kg - dry 0.192 0.8663,3'-Dichlorobenzidine 1 11/17/22 18:04 V26590JMV
<0.125 mg/Kg - dry 0.125 0.8662,4-Dichlorophenol 1 11/17/22 18:04 V26590JMV
<0.235 mg/Kg - dry 0.235 0.866Diethyl phthalate 1 11/17/22 18:04 V26590JMV
<0.228 mg/Kg - dry 0.228 0.866Dimethyl phthalate 1 11/17/22 18:04 V26590JMV
<0.141 mg/Kg - dry 0.141 0.4322,4-Dimethylphenol 1 11/17/22 18:04 V26590JMV
<0.140 mg/Kg - dry 0.140 0.866Di-n-butyl phthalate 1 11/17/22 18:04 V26590JMV
<0.314 mg/Kg - dry 0.314 1.974,6-Dinitro-2-methylphenol 1 11/17/22 18:04 V26590JMV
<0.681 mg/Kg - dry 0.681 1.972,4-Dinitrophenol 1 11/17/22 18:04 V26590JMV
<0.126 mg/Kg - dry 0.126 0.8662,4-Dinitrotoluene 1 11/17/22 18:04 V26590JMV
<0.141 mg/Kg - dry 0.141 0.8662,6-Dinitrotoluene 1 11/17/22 18:04 V26590JMV
<0.187 mg/Kg - dry 0.187 0.432Di-n-Octyl Phthalate 1 11/17/22 18:04 V26590JMV
<0.161 mg/Kg - dry 0.161 0.866Fluoranthene 1 11/17/22 18:04 V26590JMV
<0.167 mg/Kg - dry 0.167 0.866Fluorene 1 11/17/22 18:04 V26590JMV
<0.138 mg/Kg - dry 0.138 0.866Hexachlorobenzene 1 11/17/22 18:04 V26590JMV
<0.128 mg/Kg - dry 0.128 0.866Hexachlorobutadiene 1 11/17/22 18:04 V26590JMV
<0.205 mg/Kg - dry 0.205 0.866Hexachlorocyclopentadiene 1 11/17/22 18:04 V26590JMV
<0.103 mg/Kg - dry 0.103 0.866Hexachloroethane 1 11/17/22 18:04 V26590JMV
<0.234 mg/Kg - dry 0.234 0.866Indeno(1,2,3-cd)pyrene 1 11/17/22 18:04 V26590JMV
<0.250 mg/Kg - dry 0.250 0.866Isophorone 1 11/17/22 18:04 V26590JMV
1.02 mg/Kg - dry 0.138 0.8661-Methylnaphthalene 1 11/17/22 18:04 V26590JMV
1.94 mg/Kg - dry 0.131 0.8662-Methylnaphthalene 1 11/17/22 18:04 V26590JMV
<0.127 mg/Kg - dry 0.127 0.8662-Methylphenol 1 11/17/22 18:04 V26590JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 23 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:MW-13
92826 Matrix:
11/8/2022 9:45
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):11/15/22 11:15
<0.111 mg/Kg - dry 0.111 0.8663&4 Methylphenol 1 11/17/22 18:04 V26590JMV
1.55 mg/Kg - dry 0.188 0.866Naphthalene 1 11/17/22 18:04 V26590JMV
<0.126 mg/Kg - dry 0.126 0.8662-Nitroaniline 1 11/17/22 18:04 V26590JMV
<0.157 mg/Kg - dry 0.157 0.8663-Nitroaniline 1 11/17/22 18:04 V26590JMV
<0.122 mg/Kg - dry 0.122 0.4324-Nitroaniline 1 11/17/22 18:04 V26590JMV
<0.152 mg/Kg - dry 0.152 0.432Nitrobenzene 1 11/17/22 18:04 V26590JMV
<0.116 mg/Kg - dry 0.116 0.8662-Nitrophenol 1 11/17/22 18:04 V26590JMV
<0.153 mg/Kg - dry 0.153 0.8664-Nitrophenol 1 11/17/22 18:04 V26590JMV
<0.344 mg/Kg - dry 0.344 0.866N-Nitrosodimethylamine 1 11/17/22 18:04 V26590JMV
<0.237 mg/Kg - dry 0.237 0.866N-Nitrosodiphenylamine 1 11/17/22 18:04 V26590JMV
<0.154 mg/Kg - dry 0.154 0.866N-Nitroso-di-n-propylamine 1 11/17/22 18:04 V26590JMV
<0.454 mg/Kg - dry 0.454 1.31Pentachlorophenol 1 11/17/22 18:04 V26590JMV
<0.272 mg/Kg - dry 0.272 0.866Phenanthrene 1 11/17/22 18:04 V26590JMV
<0.146 mg/Kg - dry 0.146 0.866Phenol 1 11/17/22 18:04 V26590JMV
<0.175 mg/Kg - dry 0.175 0.866Pyrene 1 11/17/22 18:04 V26590JMV
<0.103 mg/Kg - dry 0.103 0.432Pyridine 1 11/17/22 18:04 V26590JMV
<0.140 mg/Kg - dry 0.140 0.8661,2,4-Trichlorobenzene 1 11/17/22 18:04 V26590JMV
<0.126 mg/Kg - dry 0.126 0.8662,4,5-Trichlorophenol 1 11/17/22 18:04 V26590JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 24 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:MW-13
92826 Matrix:
11/8/2022 9:45
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):11/15/22 11:15
<0.126 mg/Kg - dry 0.126 0.8662,4,6-Trichlorophenol 1 11/17/22 18:04 V26590JMV
Surrogate: Phenol-d5
Surrogate: 2-Fluorobiphenyl
Surrogate: 2-Fluorophenol
Surrogate: Nitrobenzene-d5
Surrogate: 4-Terphenyl-d14
Surrogate: 2,4,6-Tribromophenol
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 25 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:MW-13
92826 Matrix:
11/8/2022 9:45
Solids
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
48.4 mg/Kg - dry 1.60 10.5Aliphatic C5-C8 (Adjusted)100 11/11/22 12:41
<5.98 mg/Kg - dry 5.98 10.5Aliphatics C9-C12 (Adjusted)100 11/11/22 12:41
64.5 mg/Kg - dry 0.817 10.5Aromatic C9-C10 (Adjusted)100 11/11/22 12:55
51.1 J mg/Kg - dry 18.6 65.7Aromatic C11-C22 (Adjusted)1 11/16/22 16:39
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):11/14/22 11:00
168 mg/Kg - dry 12.1 65.7Aliphatic C9-C18 1 11/16/22 16:39 V26522JLK
<16.0 mg/Kg - dry 16.0 65.7Aliphatic C19-C36 1 11/16/22 16:39 V26522JLK
52.7 J mg/Kg - dry 18.6 65.7Aromatic C11-C22 1 11/16/22 16:39 V26522JLK
Surrogate: 2-Bromonaphthalene
Surrogate: Chlorooctadecane
Surrogate: OTP Surrogate
Surrogate: 2-Fluorobiphenyl
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):11/11/22 08:00
57.9 mg/Kg - dry 1.60 10.5Aliphatic C5-C8 100 11/11/22 12:55 V26292TBL
103 mg/Kg - dry 5.98 10.5Aliphatic C9-C12 100 11/11/22 12:55 V26292TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 26 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:MW-13
92826 Matrix:
11/8/2022 9:45
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):11/11/22 08:00
64.5 mg/Kg - dry 0.817 10.5Aromatic C9-C10 100 11/11/22 12:55 V26292TBL
Surrogate: 2,5-Dibromotoluene (FID)
Surrogate: 2,5-Dibromotoluene (PID)
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 27 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:WSW-14
92827 Matrix:
11/8/2022 14:55
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):11/17/22 14:00
<1.80 µg/L 1.80 10.0Acetone 1 11/18/22 01:33 V26615MSA
<0.180 µg/L 0.180 0.500Benzene 1 11/18/22 01:33 V26615MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 11/18/22 01:33 V26615MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 11/18/22 01:33 V26615MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 11/18/22 01:33 V26615MSA
<1.50 µg/L 1.50 5.00Bromoform 1 11/18/22 01:33 V26615MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 11/18/22 01:33 V26615MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 11/18/22 01:33 V26615MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 11/18/22 01:33 V26615MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 11/18/22 01:33 V26615MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 11/18/22 01:33 V26615MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 11/18/22 01:33 V26615MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 11/18/22 01:33 V26615MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 11/18/22 01:33 V26615MSA
<0.220 µg/L 0.220 0.500Chloroform 1 11/18/22 01:33 V26615MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 11/18/22 01:33 V26615MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 11/18/22 01:33 V26615MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 11/18/22 01:33 V26615MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 11/18/22 01:33 V26615MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 11/18/22 01:33 V26615MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 11/18/22 01:33 V26615MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 11/18/22 01:33 V26615MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 11/18/22 01:33 V26615MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 28 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:WSW-14
92827 Matrix:
11/8/2022 14:55
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):11/17/22 14:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 11/18/22 01:33 V26615MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 11/18/22 01:33 V26615MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 11/18/22 01:33 V26615MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 11/18/22 01:33 V26615MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 11/18/22 01:33 V26615MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 11/18/22 01:33 V26615MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 11/18/22 01:33 V26615MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 11/18/22 01:33 V26615MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 11/18/22 01:33 V26615MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 11/18/22 01:33 V26615MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 11/18/22 01:33 V26615MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 11/18/22 01:33 V26615MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 11/18/22 01:33 V26615MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 11/18/22 01:33 V26615MSA
<42.0 µg/L 42.0 200Ethanol 1 11/18/22 01:33 V26615MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 11/18/22 01:33 V26615MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 11/18/22 01:33 V26615MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 11/18/22 01:33 V26615MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 11/18/22 01:33 V26615MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 11/18/22 01:33 V26615MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 11/18/22 01:33 V26615MSA
1.64 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 11/18/22 01:33 V26615MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 11/18/22 01:33 V26615MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 29 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:WSW-14
92827 Matrix:
11/8/2022 14:55
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):11/17/22 14:00
<0.330 µg/L 0.330 2.00Methylene Chloride 1 11/18/22 01:33 V26615MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 11/18/22 01:33 V26615MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 11/18/22 01:33 V26615MSA
<0.220 µg/L 0.220 0.500Styrene 1 11/18/22 01:33 V26615MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 11/18/22 01:33 V26615MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 11/18/22 01:33 V26615MSA
<0.220 µg/L 0.220 0.500 1 11/18/22 01:33 V26615MSA
<0.220 µg/L 0.220 0.500 1 11/18/22 01:33 V26615MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 11/18/22 01:33 V26615MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 11/18/22 01:33 V26615MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 11/18/22 01:33 V26615MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 11/18/22 01:33 V26615MSA
<0.180 µg/L 0.180 0.500 1 11/18/22 01:33 V26615MSA
<0.180 µg/L 0.180 0.500 1 11/18/22 01:33 V26615MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 11/18/22 01:33 V26615MSA
0.446 J µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 11/18/22 01:33 V26615MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 11/18/22 01:33 V26615MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 11/18/22 01:33 V26615MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 11/18/22 01:33 V26615MSA
0.261 J µg/L 0.210 0.500o-Xylene 1 11/18/22 01:33 V26615MSA
<0.420 µg/L 0.420 1.00m,p-Xylene 1 11/18/22 01:33 V26615MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 30 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:WSW-14
92827 Matrix:
11/8/2022 14:55
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):11/17/22 14:00
0.261 J µg/L 0.210 0.500Xylene (Total)1 11/18/22 01:33 V26615
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 31 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:WSW-15
92828 Matrix:
11/8/2022 15:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):11/17/22 14:00
<1.80 µg/L 1.80 10.0Acetone 1 11/18/22 02:43 V26615MSA
<0.180 µg/L 0.180 0.500Benzene 1 11/18/22 02:43 V26615MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 11/18/22 02:43 V26615MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 11/18/22 02:43 V26615MSA
4.09 µg/L 0.160 0.500Bromodichloromethane 1 11/18/22 02:43 V26615MSA
<1.50 µg/L 1.50 5.00Bromoform 1 11/18/22 02:43 V26615MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 11/18/22 02:43 V26615MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 11/18/22 02:43 V26615MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 11/18/22 02:43 V26615MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 11/18/22 02:43 V26615MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 11/18/22 02:43 V26615MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 11/18/22 02:43 V26615MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 11/18/22 02:43 V26615MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 11/18/22 02:43 V26615MSA
32.6 µg/L 0.220 0.500Chloroform 1 11/18/22 02:43 V26615MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 11/18/22 02:43 V26615MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 11/18/22 02:43 V26615MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 11/18/22 02:43 V26615MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 11/18/22 02:43 V26615MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 11/18/22 02:43 V26615MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 11/18/22 02:43 V26615MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 11/18/22 02:43 V26615MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 11/18/22 02:43 V26615MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 32 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:WSW-15
92828 Matrix:
11/8/2022 15:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):11/17/22 14:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 11/18/22 02:43 V26615MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 11/18/22 02:43 V26615MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 11/18/22 02:43 V26615MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 11/18/22 02:43 V26615MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 11/18/22 02:43 V26615MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 11/18/22 02:43 V26615MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 11/18/22 02:43 V26615MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 11/18/22 02:43 V26615MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 11/18/22 02:43 V26615MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 11/18/22 02:43 V26615MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 11/18/22 02:43 V26615MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 11/18/22 02:43 V26615MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 11/18/22 02:43 V26615MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 11/18/22 02:43 V26615MSA
<42.0 µg/L 42.0 200Ethanol 1 11/18/22 02:43 V26615MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 11/18/22 02:43 V26615MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 11/18/22 02:43 V26615MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 11/18/22 02:43 V26615MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 11/18/22 02:43 V26615MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 11/18/22 02:43 V26615MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 11/18/22 02:43 V26615MSA
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 11/18/22 02:43 V26615MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 11/18/22 02:43 V26615MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 33 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:WSW-15
92828 Matrix:
11/8/2022 15:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):11/17/22 14:00
<0.330 µg/L 0.330 2.00Methylene Chloride 1 11/18/22 02:43 V26615MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 11/18/22 02:43 V26615MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 11/18/22 02:43 V26615MSA
<0.220 µg/L 0.220 0.500Styrene 1 11/18/22 02:43 V26615MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 11/18/22 02:43 V26615MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 11/18/22 02:43 V26615MSA
<0.220 µg/L 0.220 0.500 1 11/18/22 02:43 V26615MSA
<0.220 µg/L 0.220 0.500 1 11/18/22 02:43 V26615MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 11/18/22 02:43 V26615MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 11/18/22 02:43 V26615MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 11/18/22 02:43 V26615MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 11/18/22 02:43 V26615MSA
<0.180 µg/L 0.180 0.500 1 11/18/22 02:43 V26615MSA
<0.180 µg/L 0.180 0.500 1 11/18/22 02:43 V26615MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 11/18/22 02:43 V26615MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 11/18/22 02:43 V26615MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 11/18/22 02:43 V26615MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 11/18/22 02:43 V26615MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 11/18/22 02:43 V26615MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 11/18/22 02:43 V26615MSA
<0.420 µg/L 0.420 1.00m,p-Xylene 1 11/18/22 02:43 V26615MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 34 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:WSW-15
92828 Matrix:
11/8/2022 15:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):11/17/22 14:00
<0.21 µg/L 0.210 0.500Xylene (Total)1 11/18/22 02:43 V26615
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 35 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:WSW-16
92829 Matrix:
11/8/2022 14:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):11/17/22 14:00
<1.80 µg/L 1.80 10.0Acetone 1 11/18/22 01:56 V26615MSA
<0.180 µg/L 0.180 0.500Benzene 1 11/18/22 01:56 V26615MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 11/18/22 01:56 V26615MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 11/18/22 01:56 V26615MSA
4.24 µg/L 0.160 0.500Bromodichloromethane 1 11/18/22 01:56 V26615MSA
<1.50 µg/L 1.50 5.00Bromoform 1 11/18/22 01:56 V26615MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 11/18/22 01:56 V26615MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 11/18/22 01:56 V26615MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 11/18/22 01:56 V26615MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 11/18/22 01:56 V26615MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 11/18/22 01:56 V26615MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 11/18/22 01:56 V26615MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 11/18/22 01:56 V26615MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 11/18/22 01:56 V26615MSA
40.2 µg/L 0.220 0.500Chloroform 1 11/18/22 01:56 V26615MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 11/18/22 01:56 V26615MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 11/18/22 01:56 V26615MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 11/18/22 01:56 V26615MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 11/18/22 01:56 V26615MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 11/18/22 01:56 V26615MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 11/18/22 01:56 V26615MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 11/18/22 01:56 V26615MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 11/18/22 01:56 V26615MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 36 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:WSW-16
92829 Matrix:
11/8/2022 14:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):11/17/22 14:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 11/18/22 01:56 V26615MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 11/18/22 01:56 V26615MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 11/18/22 01:56 V26615MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 11/18/22 01:56 V26615MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 11/18/22 01:56 V26615MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 11/18/22 01:56 V26615MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 11/18/22 01:56 V26615MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 11/18/22 01:56 V26615MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 11/18/22 01:56 V26615MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 11/18/22 01:56 V26615MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 11/18/22 01:56 V26615MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 11/18/22 01:56 V26615MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 11/18/22 01:56 V26615MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 11/18/22 01:56 V26615MSA
<42.0 µg/L 42.0 200Ethanol 1 11/18/22 01:56 V26615MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 11/18/22 01:56 V26615MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 11/18/22 01:56 V26615MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 11/18/22 01:56 V26615MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 11/18/22 01:56 V26615MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 11/18/22 01:56 V26615MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 11/18/22 01:56 V26615MSA
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 11/18/22 01:56 V26615MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 11/18/22 01:56 V26615MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 37 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:WSW-16
92829 Matrix:
11/8/2022 14:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):11/17/22 14:00
<0.330 µg/L 0.330 2.00Methylene Chloride 1 11/18/22 01:56 V26615MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 11/18/22 01:56 V26615MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 11/18/22 01:56 V26615MSA
<0.220 µg/L 0.220 0.500Styrene 1 11/18/22 01:56 V26615MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 11/18/22 01:56 V26615MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 11/18/22 01:56 V26615MSA
<0.220 µg/L 0.220 0.500 1 11/18/22 01:56 V26615MSA
<0.220 µg/L 0.220 0.500 1 11/18/22 01:56 V26615MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 11/18/22 01:56 V26615MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 11/18/22 01:56 V26615MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 11/18/22 01:56 V26615MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 11/18/22 01:56 V26615MSA
<0.180 µg/L 0.180 0.500 1 11/18/22 01:56 V26615MSA
<0.180 µg/L 0.180 0.500 1 11/18/22 01:56 V26615MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 11/18/22 01:56 V26615MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 11/18/22 01:56 V26615MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 11/18/22 01:56 V26615MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 11/18/22 01:56 V26615MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 11/18/22 01:56 V26615MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 11/18/22 01:56 V26615MSA
<0.420 µg/L 0.420 1.00m,p-Xylene 1 11/18/22 01:56 V26615MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 38 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:WSW-16
92829 Matrix:
11/8/2022 14:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):11/17/22 14:00
<0.21 µg/L 0.210 0.500Xylene (Total)1 11/18/22 01:56 V26615
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 39 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:Trip Blank
92830 Matrix:
11/8/2022 7:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):11/17/22 14:00
<1.80 µg/L 1.80 10.0Acetone 1 11/18/22 00:22 V26615MSA
<0.180 µg/L 0.180 0.500Benzene 1 11/18/22 00:22 V26615MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 11/18/22 00:22 V26615MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 11/18/22 00:22 V26615MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 11/18/22 00:22 V26615MSA
<1.50 µg/L 1.50 5.00Bromoform 1 11/18/22 00:22 V26615MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 11/18/22 00:22 V26615MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 11/18/22 00:22 V26615MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 11/18/22 00:22 V26615MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 11/18/22 00:22 V26615MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 11/18/22 00:22 V26615MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 11/18/22 00:22 V26615MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 11/18/22 00:22 V26615MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 11/18/22 00:22 V26615MSA
<0.220 µg/L 0.220 0.500Chloroform 1 11/18/22 00:22 V26615MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 11/18/22 00:22 V26615MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 11/18/22 00:22 V26615MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 11/18/22 00:22 V26615MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 11/18/22 00:22 V26615MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 11/18/22 00:22 V26615MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 11/18/22 00:22 V26615MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 11/18/22 00:22 V26615MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 11/18/22 00:22 V26615MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 40 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:Trip Blank
92830 Matrix:
11/8/2022 7:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):11/17/22 14:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 11/18/22 00:22 V26615MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 11/18/22 00:22 V26615MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 11/18/22 00:22 V26615MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 11/18/22 00:22 V26615MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 11/18/22 00:22 V26615MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 11/18/22 00:22 V26615MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 11/18/22 00:22 V26615MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 11/18/22 00:22 V26615MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 11/18/22 00:22 V26615MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 11/18/22 00:22 V26615MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 11/18/22 00:22 V26615MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 11/18/22 00:22 V26615MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 11/18/22 00:22 V26615MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 11/18/22 00:22 V26615MSA
<42.0 µg/L 42.0 200Ethanol 1 11/18/22 00:22 V26615MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 11/18/22 00:22 V26615MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 11/18/22 00:22 V26615MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 11/18/22 00:22 V26615MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 11/18/22 00:22 V26615MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 11/18/22 00:22 V26615MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 11/18/22 00:22 V26615MSA
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 11/18/22 00:22 V26615MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 11/18/22 00:22 V26615MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 41 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:Trip Blank
92830 Matrix:
11/8/2022 7:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):11/17/22 14:00
<0.330 µg/L 0.330 2.00Methylene Chloride 1 11/18/22 00:22 V26615MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 11/18/22 00:22 V26615MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 11/18/22 00:22 V26615MSA
<0.220 µg/L 0.220 0.500Styrene 1 11/18/22 00:22 V26615MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 11/18/22 00:22 V26615MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 11/18/22 00:22 V26615MSA
<0.220 µg/L 0.220 0.500 1 11/18/22 00:22 V26615MSA
<0.220 µg/L 0.220 0.500 1 11/18/22 00:22 V26615MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 11/18/22 00:22 V26615MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 11/18/22 00:22 V26615MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 11/18/22 00:22 V26615MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 11/18/22 00:22 V26615MSA
<0.180 µg/L 0.180 0.500 1 11/18/22 00:22 V26615MSA
<0.180 µg/L 0.180 0.500 1 11/18/22 00:22 V26615MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 11/18/22 00:22 V26615MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 11/18/22 00:22 V26615MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 11/18/22 00:22 V26615MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 11/18/22 00:22 V26615MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 11/18/22 00:22 V26615MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 11/18/22 00:22 V26615MSA
<0.420 µg/L 0.420 1.00m,p-Xylene 1 11/18/22 00:22 V26615MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 42 of 77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-314-0102
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Project ID :
GRI #5888 Received : 11/10/2022
Former Philbecks Amoco
Report Date : 11/19/2022
Sample ID :
Lab No :
Sampled:Trip Blank
92830 Matrix:
11/8/2022 7:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):11/17/22 14:00
<0.21 µg/L 0.210 0.500Xylene (Total)1 11/18/22 00:22 V26615
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 43 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V26615QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V26613
Associated Lab Samples: 92827, 92828, 92829, 92830
Lab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
11/17/22 23:1210.01.80<1.80µg/LAcetone
11/17/22 23:120.5000.180<0.180µg/LBenzene
11/17/22 23:120.5000.210<0.210µg/LBromobenzene
11/17/22 23:121.000.420<0.420µg/LBromochloromethane
11/17/22 23:120.5000.160<0.160µg/LBromodichloromethane
11/17/22 23:125.001.50<1.50µg/LBromoform
11/17/22 23:121.000.280<0.280µg/LBromomethane
11/17/22 23:120.5000.180<0.180µg/Ln-Butylbenzene
11/17/22 23:120.5000.200<0.200µg/Lsec-Butyl benzene
11/17/22 23:122.000.920<0.920µg/Ltert-Butyl benzene
11/17/22 23:120.5000.180<0.180µg/LCarbon Tetrachloride
11/17/22 23:120.5000.190<0.190µg/LChlorobenzene
11/17/22 23:120.5000.190<0.190µg/LChlorodibromomethane
11/17/22 23:121.000.430<0.430µg/LChloroethane
11/17/22 23:120.5000.220<0.220µg/LChloroform
11/17/22 23:120.5000.220<0.220µg/LChloromethane
11/17/22 23:120.5000.200<0.200µg/L2-Chlorotoluene
11/17/22 23:120.5000.200<0.200µg/L4-Chlorotoluene
11/17/22 23:120.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
11/17/22 23:122.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
11/17/22 23:120.5000.200<0.200µg/L1,2-Dibromoethane
11/17/22 23:120.5000.230<0.230µg/LDibromomethane
11/17/22 23:120.5000.220<0.220µg/L1,2-Dichlorobenzene
11/17/22 23:120.5000.190<0.190µg/L1,3-Dichlorobenzene
11/17/22 23:120.5000.210<0.210µg/L1,4-Dichlorobenzene
11/17/22 23:125.001.20<1.20µg/LDichlorodifluoromethane
11/17/22 23:120.5000.240<0.240µg/L1,1-Dichloroethane
Page 1 of 32Date:11/19/2022 10:28 AM
Page 44 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V26615QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V26613
Associated Lab Samples: 92827, 92828, 92829, 92830
Lab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
11/17/22 23:120.5000.150<0.150µg/L1,2-Dichloroethane
11/17/22 23:120.5000.150<0.150µg/L1,1-Dichloroethene
11/17/22 23:120.5000.200<0.200µg/Lcis-1,2-Dichloroethene
11/17/22 23:120.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
11/17/22 23:120.5000.190<0.190µg/L1,2-Dichloropropane
11/17/22 23:120.5000.130<0.130µg/L1,3-Dichloropropane
11/17/22 23:122.000.210<0.210µg/L2,2-Dichloropropane
11/17/22 23:120.5000.200<0.200µg/L1,1-Dichloropropene
11/17/22 23:120.5000.210<0.210µg/Lcis-1,3-Dichloropropene
11/17/22 23:120.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
11/17/22 23:1220042.0<42.0µg/LEthanol
11/17/22 23:120.5000.170<0.170µg/LEthylbenzene
11/17/22 23:123.000.350<0.350µg/LHexachlorobutadiene
11/17/22 23:121.000.380<0.380µg/L2-Hexanone
11/17/22 23:120.5000.180<0.180µg/LIsopropylbenzene
11/17/22 23:120.5000.089<0.089µg/L4-Isopropyl toluene
11/17/22 23:125.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
11/17/22 23:121.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
11/17/22 23:121.000.078<0.078µg/L4-Methyl-2-Pentanone
11/17/22 23:122.000.330<0.330µg/LMethylene Chloride
11/17/22 23:121.000.470<0.470µg/LNaphthalene
11/17/22 23:120.5000.190<0.190µg/Ln-Propylbenzene
11/17/22 23:120.5000.220<0.220µg/LStyrene
11/17/22 23:120.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
11/17/22 23:120.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
11/17/22 23:120.5000.220<0.220µg/LTetrachloroethene
11/17/22 23:120.5000.220<0.220µg/LToluene
Page 2 of 32Date:11/19/2022 10:28 AM
Page 45 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V26615QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V26613
Associated Lab Samples: 92827, 92828, 92829, 92830
Lab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
11/17/22 23:120.5000.380<0.380µg/L1,2,3-Trichlorobenzene
11/17/22 23:120.5000.310<0.310µg/L1,2,4-Trichlorobenzene
11/17/22 23:120.5000.160<0.160µg/L1,1,1-Trichloroethane
11/17/22 23:120.5000.096<0.096µg/L1,1,2-Trichloroethane
11/17/22 23:120.5000.180<0.180µg/LTrichloroethene
11/17/22 23:120.5000.180<0.180µg/LTrichlorofluoromethane
11/17/22 23:120.5000.270<0.270µg/L1,2,3-Trichloropropane
11/17/22 23:120.5000.190<0.190µg/L1,2,4-Trimethylbenzene
11/17/22 23:120.5000.180<0.180µg/L1,3,5-Trimethylbenzene
11/17/22 23:125.001.00<1.00µg/LVinyl Acetate
11/17/22 23:120.5000.170<0.170µg/LVinyl Chloride
11/17/22 23:120.5000.210<0.210µg/Lo-Xylene
11/17/22 23:121.000.420<0.420µg/Lm,p-Xylene
11/17/22 23:124-Bromofluorobenzene (S)101 70-130
11/17/22 23:12Dibromofluoromethane (S)99.0 70-130
11/17/22 23:121,2-Dichloroethane - d4 (S)95.6 70-130
11/17/22 23:12Toluene-d8 (S)100 70-130
LCS-V26613 LCSD-V26613Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
37.1 92.795.538.240.0µg/LAcetone 40-160 2.9 20.0
21.3 10711222.320.0µg/LBenzene 70-130 4.5 20.0
20.6 10310921.820.0µg/LBromobenzene 70-130 5.6 20.0
21.5 10810721.320.0µg/LBromochloromethane 70-130 0.9 20.0
20.7 10410621.120.0µg/LBromodichloromethane 70-130 1.9 20.0
Page 3 of 32Date:11/19/2022 10:28 AM
Page 46 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V26615QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V26613
LCS-V26613 LCSD-V26613Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.9 11011122.120.0µg/LBromoform 70-130 0.9 20.0
24.4 12212725.420.0µg/LBromomethane 60-140 4.0 20.0
21.0 10510921.720.0µg/Ln-Butylbenzene 70-130 3.2 20.0
20.7 10410821.520.0µg/Lsec-Butyl benzene 70-130 3.7 20.0
21.4 10710921.820.0µg/Ltert-Butyl benzene 70-130 1.8 20.0
21.5 10811122.220.0µg/LCarbon Tetrachloride 70-130 3.2 20.0
21.1 10610821.520.0µg/LChlorobenzene 70-130 1.8 20.0
21.0 10511122.120.0µg/LChlorodibromomethane 70-130 5.1 20.0
20.9 10511122.220.0µg/LChloroethane 60-140 6.0 20.0
21.3 10711122.120.0µg/LChloroform 70-130 3.6 20.0
19.7 98.510320.520.0µg/LChloromethane 60-140 3.9 20.0
21.3 10711022.020.0µg/L2-Chlorotoluene 70-130 3.2 20.0
20.5 10310621.120.0µg/L4-Chlorotoluene 70-130 2.8 20.0
20.8 10411021.920.0µg/LDi-Isopropyl Ether (DIPE)70-130 5.1 20.0
22.3 11211823.620.0µg/L1,2-Dibromo-3-Chloropropane 70-130 5.6 20.0
22.4 11211122.220.0µg/L1,2-Dibromoethane 70-130 0.8 20.0
21.4 10710921.720.0µg/LDibromomethane 70-130 1.3 20.0
21.6 10811122.120.0µg/L1,2-Dichlorobenzene 70-130 2.2 20.0
21.9 11011122.220.0µg/L1,3-Dichlorobenzene 70-130 1.3 20.0
20.7 10410921.820.0µg/L1,4-Dichlorobenzene 70-130 5.1 20.0
24.3 12212524.920.0µg/LDichlorodifluoromethane 60-140 2.4 20.0
20.2 10111222.320.0µg/L1,1-Dichloroethane 70-130 9.8 20.0
20.5 10310520.920.0µg/L1,2-Dichloroethane 70-130 1.9 20.0
21.1 10610821.520.0µg/L1,1-Dichloroethene 70-130 1.8 20.0
20.4 10211122.220.0µg/Lcis-1,2-Dichloroethene 70-130 8.4 20.0
20.1 10110521.020.0µg/Ltrans-1,2-Dichloroethene 70-130 4.3 20.0
Page 4 of 32Date:11/19/2022 10:28 AM
Page 47 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V26615QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V26613
LCS-V26613 LCSD-V26613Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.3 10211021.920.0µg/L1,2-Dichloropropane 70-130 7.5 20.0
21.0 10510721.320.0µg/L1,3-Dichloropropane 70-130 1.4 20.0
20.9 10510921.720.0µg/L2,2-Dichloropropane 70-130 3.7 20.0
22.7 11411723.320.0µg/L1,1-Dichloropropene 70-130 2.6 20.0
21.2 10611122.220.0µg/Lcis-1,3-Dichloropropene 70-130 4.6 20.0
22.0 11011422.720.0µg/Ltrans-1,3-Dichloropropene 70-130 3.1 20.0
549 110102510500µg/LEthanol 60-140 7.3 20.0
21.2 10610921.720.0µg/LEthylbenzene 70-130 2.3 20.0
23.0 11511222.320.0µg/LHexachlorobutadiene 70-130 3.0 20.0
19.8 99.010120.120.0µg/L2-Hexanone 60-140 1.5 20.0
21.6 10811122.120.0µg/LIsopropylbenzene 70-130 2.2 20.0
21.8 10911322.520.0µg/L4-Isopropyl toluene 70-130 3.1 20.0
20.9 10511222.320.0µg/LMethyl Ethyl Ketone (MEK)60-140 6.4 20.0
21.0 10510621.220.0µg/LMethyl tert-butyl ether (MTBE)70-130 0.9 20.0
21.5 10811022.020.0µg/L4-Methyl-2-Pentanone 60-140 2.2 20.0
20.7 10410821.620.0µg/LMethylene Chloride 70-130 4.2 20.0
24.6 12312324.620.0µg/LNaphthalene 70-130 0.0 20.0
21.3 10710821.620.0µg/Ln-Propylbenzene 70-130 1.3 20.0
21.0 10510420.720.0µg/LStyrene 70-130 1.4 20.0
22.0 11011222.320.0µg/L1,1,1,2-Tetrachloroethane 70-130 1.3 20.0
23.0 11511522.920.0µg/L1,1,2,2-Tetrachloroethane 70-130 0.4 20.0
21.8 10911122.220.0µg/LTetrachloroethene 70-130 1.8 20.0
21.3 10710921.820.0µg/LToluene 70-130 2.3 20.0
23.9 12011422.720.0µg/L1,2,3-Trichlorobenzene 70-130 5.1 20.0
22.0 11011322.620.0µg/L1,2,4-Trichlorobenzene 70-130 2.6 20.0
23.1 11611723.320.0µg/L1,1,1-Trichloroethane 70-130 0.8 20.0
Page 5 of 32Date:11/19/2022 10:28 AM
Page 48 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V26615QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V26613
LCS-V26613 LCSD-V26613Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.2 10610921.820.0µg/L1,1,2-Trichloroethane 70-130 2.7 20.0
21.3 10711122.220.0µg/LTrichloroethene 70-130 4.1 20.0
21.8 10911823.520.0µg/LTrichlorofluoromethane 60-140 7.5 20.0
20.3 10211422.820.0µg/L1,2,3-Trichloropropane 70-130 11.6 20.0
20.8 10410721.420.0µg/L1,2,4-Trimethylbenzene 70-130 2.8 20.0
21.0 10510921.720.0µg/L1,3,5-Trimethylbenzene 70-130 3.2 20.0
22.7 11412023.920.0µg/LVinyl Acetate 60-140 5.1 20.0
21.8 10911523.020.0µg/LVinyl Chloride 60-140 5.3 20.0
20.7 10410521.020.0µg/Lo-Xylene 70-130 1.4 20.0
43.3 10811144.540.0µg/Lm,p-Xylene 70-130 2.7 20.0
99.61004-Bromofluorobenzene (S)70-130
106104Dibromofluoromethane (S)70-130
1011011,2-Dichloroethane - d4 (S)70-130
99.4101Toluene-d8 (S)70-130
Page 6 of 32Date:11/19/2022 10:28 AM
Page 49 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V26294QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V26293
Associated Lab Samples: 92825
Lab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
11/11/22 11:190.0200.002<0.002mg/KgAcetone
11/11/22 11:190.0200.001<0.001mg/KgAcrolein
11/11/22 11:190.0200.0008<0.0008mg/KgAcrylonitrile
11/11/22 11:190.0050.0006<0.0006mg/KgBenzene
11/11/22 11:190.0050.0005<0.0005mg/KgBromobenzene
11/11/22 11:190.0050.0008<0.0008mg/KgBromochloromethane
11/11/22 11:190.0050.001<0.001mg/KgBromodichloromethane
11/11/22 11:190.0050.001<0.001mg/KgBromoform
11/11/22 11:190.0100.001<0.001mg/KgBromomethane
11/11/22 11:190.0050.0005<0.0005mg/Kgn-Butylbenzene
11/11/22 11:190.0050.0006<0.0006mg/Kgsec-Butyl benzene
11/11/22 11:190.0050.0005<0.0005mg/Kgtert-Butyl benzene
11/11/22 11:190.0050.0006<0.0006mg/KgCarbon Disulfide
11/11/22 11:190.0050.001<0.001mg/KgCarbon Tetrachloride
11/11/22 11:190.0050.0007<0.0007mg/KgChlorobenzene
11/11/22 11:190.0050.0009<0.0009mg/KgChlorodibromomethane
11/11/22 11:190.0100.0009<0.0009mg/KgChloroethane
11/11/22 11:190.0050.001<0.001mg/KgChloroform
11/11/22 11:190.0100.0006<0.0006mg/KgChloromethane
11/11/22 11:190.0050.0005<0.0005mg/Kg2-Chlorotoluene
11/11/22 11:190.0050.0004<0.0004mg/Kg4-Chlorotoluene
11/11/22 11:190.0050.0007<0.0007mg/KgDi-Isopropyl Ether (DIPE)
11/11/22 11:190.0100.0004<0.0004mg/Kg1,2-Dibromo-3-Chloropropane
11/11/22 11:190.0050.0006<0.0006mg/Kg1,2-Dibromoethane
11/11/22 11:190.0050.0006<0.0006mg/KgDibromomethane
11/11/22 11:190.0050.0003<0.0003mg/Kg1,2-Dichlorobenzene
11/11/22 11:190.0050.0004<0.0004mg/Kg1,3-Dichlorobenzene
Page 7 of 32Date:11/19/2022 10:28 AM
Page 50 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V26294QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V26293
Associated Lab Samples: 92825
Lab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
11/11/22 11:190.0050.0006<0.0006mg/Kg1,4-Dichlorobenzene
11/11/22 11:190.0100.001<0.001mg/KgDichlorodifluoromethane
11/11/22 11:190.0050.0008<0.0008mg/Kg1,1-Dichloroethane
11/11/22 11:190.0050.001<0.001mg/Kg1,2-Dichloroethane
11/11/22 11:190.0050.0007<0.0007mg/Kg1,1-Dichloroethene
11/11/22 11:190.0050.0008<0.0008mg/Kgcis-1,2-Dichloroethene
11/11/22 11:190.0050.001<0.001mg/Kgtrans-1,2-Dichloroethene
11/11/22 11:190.0050.0004<0.0004mg/Kg1,2-Dichloropropane
11/11/22 11:190.0050.0006<0.0006mg/Kg1,3-Dichloropropane
11/11/22 11:190.0050.001<0.001mg/Kg2,2-Dichloropropane
11/11/22 11:190.0050.0008<0.0008mg/Kg1,1-Dichloropropene
11/11/22 11:190.0050.0005<0.0005mg/Kgcis-1,3-Dichloropropene
11/11/22 11:190.0050.0008<0.0008mg/Kgtrans-1,3-Dichloropropene
11/11/22 11:190.2500.014<0.014mg/KgEthanol
11/11/22 11:190.0050.0006<0.0006mg/KgEthylbenzene
11/11/22 11:190.0500.0008<0.0008mg/KgEthyl Tertiary Butyl Ether (ETBE)
11/11/22 11:190.0100.0008<0.0008mg/KgHexachlorobutadiene
11/11/22 11:190.0100.0007<0.0007mg/Kgn-Hexane
11/11/22 11:190.0200.0006<0.0006mg/Kg2-Hexanone
11/11/22 11:190.0050.0005<0.0005mg/KgIsopropylbenzene
11/11/22 11:190.0050.001<0.001mg/Kg4-Isopropyl toluene
11/11/22 11:190.0200.0007<0.0007mg/KgMethyl Ethyl Ketone (MEK)
11/11/22 11:190.0050.0006<0.0006mg/KgMethyl tert-butyl ether (MTBE)
11/11/22 11:190.0200.015<0.015mg/Kg4-Methyl-2-Pentanone
11/11/22 11:190.0100.001<0.001mg/KgMethylene Chloride
11/11/22 11:190.0100.0010<0.0010mg/KgNaphthalene
11/11/22 11:190.0050.0005<0.0005mg/Kgn-Propylbenzene
Page 8 of 32Date:11/19/2022 10:28 AM
Page 51 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V26294QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V26293
Associated Lab Samples: 92825
Lab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
11/11/22 11:190.0050.001<0.001mg/KgStyrene
11/11/22 11:190.2000.0010<0.0010mg/Kgtert-Butyl Alcohol (TBA)
11/11/22 11:190.4000.001<0.001mg/Kgtert-Butyl formate (TBF)
11/11/22 11:190.4000.0004<0.0004mg/Kgtert-Amyl Alcohol (TAA)
11/11/22 11:190.1000.0007<0.0007mg/Kgtert-Amyl Methyl Ether (TAME)
11/11/22 11:190.0050.001<0.001mg/Kg1,1,1,2-Tetrachloroethane
11/11/22 11:190.0050.0003<0.0003mg/Kg1,1,2,2-Tetrachloroethane
11/11/22 11:190.0050.0009<0.0009mg/KgTetrachloroethene
11/11/22 11:190.0050.0007<0.0007mg/KgToluene
11/11/22 11:190.0100.0005<0.0005mg/Kg1,2,3-Trichlorobenzene
11/11/22 11:190.0100.0006<0.0006mg/Kg1,2,4-Trichlorobenzene
11/11/22 11:190.0050.001<0.001mg/Kg1,1,1-Trichloroethane
11/11/22 11:190.0050.0005<0.0005mg/Kg1,1,2-Trichloroethane
11/11/22 11:190.0050.0009<0.0009mg/KgTrichloroethene
11/11/22 11:190.0100.002<0.002mg/KgTrichlorofluoromethane
11/11/22 11:190.0050.0007<0.0007mg/Kg1,2,3-Trichloropropane
11/11/22 11:190.0050.0005<0.0005mg/Kg1,2,4-Trimethylbenzene
11/11/22 11:190.0050.0005<0.0005mg/Kg1,3,5-Trimethylbenzene
11/11/22 11:190.0100.0005<0.0005mg/KgVinyl Acetate
11/11/22 11:190.0100.0005<0.0005mg/KgVinyl Chloride
11/11/22 11:190.0050.0005<0.0005mg/Kgo-Xylene
11/11/22 11:190.0100.001<0.001mg/Kgm,p-Xylene
11/11/22 11:194-Bromofluorobenzene (S)101 70-130
11/11/22 11:19Dibromofluoromethane (S)101 84-123
11/11/22 11:19Toluene-d8 (S)101 76-129
Page 9 of 32Date:11/19/2022 10:28 AM
Page 52 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V26294QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V26293
LCS-V26293 LCSD-V26293Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.111 1111150.1150.100mg/KgAcetone 29-198 3.5 20
0.103 10393.90.0930.100mg/KgAcrolein 70-130 9.2 20
0.101 10198.30.0980.100mg/KgAcrylonitrile 65-134 2.7 20
0.049 99.61020.0510.050mg/KgBenzene 74-127 2.5 20
0.048 97.094.60.0470.050mg/KgBromobenzene 73-125 2.5 20
0.049 98.294.80.0470.050mg/KgBromochloromethane 72-134 3.5 20
0.049 98.695.00.0470.050mg/KgBromodichloromethane 75-122 3.7 20
0.045 90.892.20.0460.050mg/KgBromoform 66-135 1.5 20
0.044 89.490.40.0450.050mg/KgBromomethane 20-180 1.1 20
0.050 1021010.0500.050mg/Kgn-Butylbenzene 65-135 0.9 20
0.050 10098.20.0490.050mg/Kgsec-Butyl benzene 66-131 2.0 20
0.048 97.094.20.0470.050mg/Kgtert-Butyl benzene 67-132 2.9 20
0.047 94.495.20.0470.050mg/KgCarbon Disulfide 61-129 0.8 20
0.044 89.291.60.0450.050mg/KgCarbon Tetrachloride 64-143 2.6 20
0.047 95.696.80.0480.050mg/KgChlorobenzene 74-118 1.2 20
0.044 88.292.00.0460.050mg/KgChlorodibromomethane 73-122 4.2 20
0.045 90.497.60.0480.050mg/KgChloroethane 33-149 7.6 20
0.050 10197.80.0480.050mg/KgChloroform 73-127 3.0 20
0.041 83.884.20.0420.050mg/KgChloromethane 45-143 0.4 20
0.048 97.098.60.0490.050mg/Kg2-Chlorotoluene 67-124 1.6 20
0.048 97.298.80.0490.050mg/Kg4-Chlorotoluene 71-126 1.6 20
0.053 1071070.0530.050mg/KgDi-Isopropyl Ether (DIPE)59-159 0.3 20
0.042 84.678.40.0390.050mg/Kg1,2-Dibromo-3-Chloropropane 55-157 7.6 20
0.047 95.893.40.0460.050mg/Kg1,2-Dibromoethane 70-132 2.5 20
0.048 97.891.60.0450.050mg/KgDibromomethane 74-133 6.5 20
0.050 10097.20.0480.050mg/Kg1,2-Dichlorobenzene 72-123 2.8 20
Page 10 of 32Date:11/19/2022 10:28 AM
Page 53 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V26294QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V26293
LCS-V26293 LCSD-V26293Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.049 99.898.40.0490.050mg/Kg1,3-Dichlorobenzene 71-120 1.4 20
0.047 95.893.80.0460.050mg/Kg1,4-Dichlorobenzene 71-123 2.1 20
0.043 86.692.00.0460.050mg/KgDichlorodifluoromethane 26-146 6.0 20
0.048 97.499.40.0490.050mg/Kg1,1-Dichloroethane 74-127 2.0 20
0.052 1051040.0510.050mg/Kg1,2-Dichloroethane 68-128 0.9 20
0.049 98.298.80.0490.050mg/Kg1,1-Dichloroethene 67-149 0.6 20
0.047 95.498.60.0490.050mg/Kgcis-1,2-Dichloroethene 76-134 3.2 20
0.046 93.896.60.0480.050mg/Kgtrans-1,2-Dichloroethene 73-132 2.9 20
0.050 10199.60.0490.050mg/Kg1,2-Dichloropropane 73-130 1.3 20
0.049 98.41020.0510.050mg/Kg1,3-Dichloropropane 75-124 3.7 20
0.049 98.21050.0520.050mg/Kg2,2-Dichloropropane 50-142 6.5 20
0.048 97.21010.0500.050mg/Kg1,1-Dichloropropene 71-130 4.2 20
0.051 10298.80.0490.050mg/Kgcis-1,3-Dichloropropene 71-125 3.1 20
0.051 1031050.0520.050mg/Kgtrans-1,3-Dichloropropene 68-123 2.3 20
1.24 99.299.21.241.25mg/KgEthanol 70-130 0.0 20
0.047 94.696.00.0480.050mg/KgEthylbenzene 74-128 1.4 20
0.104 1041050.1050.100mg/KgEthyl Tertiary Butyl Ether (ETBE)70-130 0.9 20
0.047 95.492.40.0460.050mg/KgHexachlorobutadiene 64-125 3.1 20
0.050 10297.80.0480.050mg/Kgn-Hexane 70-130 3.8 20
0.054 1091090.0540.050mg/Kg2-Hexanone 61-157 0.1 20
0.046 93.291.80.0450.050mg/KgIsopropylbenzene 68-126 1.5 20
0.049 98.499.60.0490.050mg/Kg4-Isopropyl toluene 68-129 1.2 20
0.048 96.61030.0510.050mg/KgMethyl Ethyl Ketone (MEK)63-149 6.0 20
0.049 98.699.20.0490.050mg/KgMethyl tert-butyl ether (MTBE)70-130 0.6 20
0.049 99.41010.0500.050mg/Kg4-Methyl-2-Pentanone 57-162 1.9 20
0.049 98.61000.0500.050mg/KgMethylene Chloride 74-129 1.8 20
Page 11 of 32Date:11/19/2022 10:28 AM
Page 54 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V26294QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V26293
LCS-V26293 LCSD-V26293Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.047 95.890.60.0450.050mg/KgNaphthalene 57-157 5.5 20
0.049 99.095.60.0470.050mg/Kgn-Propylbenzene 67-130 3.4 20
0.049 99.499.60.0490.050mg/KgStyrene 77-121 0.2 20
0.088 88.589.30.0890.100mg/Kgtert-Butyl Alcohol (TBA)70-130 0.8 20
0.106 1061060.1060.100mg/Kgtert-Butyl formate (TBF)70-130 0.0 20
0.047 94.298.20.0490.050mg/Kgtert-Amyl Alcohol (TAA)70-130 4.1 20
0.102 1021010.1010.100mg/Kgtert-Amyl Methyl Ether (TAME)70-130 0.9 20
0.045 90.692.00.0460.050mg/Kg1,1,1,2-Tetrachloroethane 72-115 1.5 20
0.046 92.886.20.0430.050mg/Kg1,1,2,2-Tetrachloroethane 56-126 7.3 20
0.047 94.296.80.0480.050mg/KgTetrachloroethene 68-130 2.7 20
0.048 96.696.80.0480.050mg/KgToluene 71-129 0.2 20
0.048 96.897.00.0480.050mg/Kg1,2,3-Trichlorobenzene 68-130 0.2 20
0.050 1001000.0500.050mg/Kg1,2,4-Trichlorobenzene 66-125 0.0 20
0.047 95.496.60.0480.050mg/Kg1,1,1-Trichloroethane 67-131 1.2 20
0.048 97.095.80.0470.050mg/Kg1,1,2-Trichloroethane 70-133 1.2 20
0.047 94.493.80.0460.050mg/KgTrichloroethene 75-133 0.6 20
0.045 91.297.20.0480.050mg/KgTrichlorofluoromethane 44-146 6.3 20
0.045 90.284.20.0420.050mg/Kg1,2,3-Trichloropropane 60-137 6.8 20
0.049 98.094.60.0470.050mg/Kg1,2,4-Trimethylbenzene 69-129 3.5 20
0.048 96.896.80.0480.050mg/Kg1,3,5-Trimethylbenzene 69-128 0.0 20
0.042 84.689.80.0440.050mg/KgVinyl Acetate 60-140 5.9 20
0.049 99.01010.0500.050mg/KgVinyl Chloride 48-147 2.1 20
0.049 98.296.60.0480.050mg/Kgo-Xylene 74-126 1.6 20
0.096 96.199.80.0990.100mg/Kgm,p-Xylene 75-124 3.7 20
97.894.84-Bromofluorobenzene (S)70-130
103101Dibromofluoromethane (S)84-123
Page 12 of 32Date:11/19/2022 10:28 AM
Page 55 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V26294QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V26293
LCS-V26293 LCSD-V26293Laboratory Control Sample & LCSD
LCSD
ResultParameter
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
103102Toluene-d8 (S)76-129
Page 13 of 32Date:11/19/2022 10:28 AM
Page 56 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V26296QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 MED
QC Prep:V26295
Associated Lab Samples: 92826
Lab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
11/11/22 11:190.0200.002<0.002mg/KgAcetone
11/11/22 11:190.0200.001<0.001mg/KgAcrolein
11/11/22 11:190.0200.0008<0.0008mg/KgAcrylonitrile
11/11/22 11:190.0050.0006<0.0006mg/KgBenzene
11/11/22 11:190.0050.0005<0.0005mg/KgBromobenzene
11/11/22 11:190.0050.0008<0.0008mg/KgBromochloromethane
11/11/22 11:190.0050.001<0.001mg/KgBromodichloromethane
11/11/22 11:190.0050.001<0.001mg/KgBromoform
11/11/22 11:190.0100.001<0.001mg/KgBromomethane
11/11/22 11:190.0050.0005<0.0005mg/Kgn-Butylbenzene
11/11/22 11:190.0050.0006<0.0006mg/Kgsec-Butyl benzene
11/11/22 11:190.0050.0005<0.0005mg/Kgtert-Butyl benzene
11/11/22 11:190.0050.0006<0.0006mg/KgCarbon Disulfide
11/11/22 11:190.0050.001<0.001mg/KgCarbon Tetrachloride
11/11/22 11:190.0050.0007<0.0007mg/KgChlorobenzene
11/11/22 11:190.0050.0009<0.0009mg/KgChlorodibromomethane
11/11/22 11:190.0100.0009<0.0009mg/KgChloroethane
11/11/22 11:190.0050.001<0.001mg/KgChloroform
11/11/22 11:190.0100.0006<0.0006mg/KgChloromethane
11/11/22 11:190.0050.0005<0.0005mg/Kg2-Chlorotoluene
11/11/22 11:190.0050.0004<0.0004mg/Kg4-Chlorotoluene
11/11/22 11:190.0050.0007<0.0007mg/KgDi-Isopropyl Ether (DIPE)
11/11/22 11:190.0100.0004<0.0004mg/Kg1,2-Dibromo-3-Chloropropane
11/11/22 11:190.0050.0006<0.0006mg/Kg1,2-Dibromoethane
11/11/22 11:190.0050.0010<0.0010mg/KgDibromomethane
11/11/22 11:190.0050.0003<0.0003mg/Kg1,2-Dichlorobenzene
11/11/22 11:190.0050.0004<0.0004mg/Kg1,3-Dichlorobenzene
Page 14 of 32Date:11/19/2022 10:28 AM
Page 57 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V26296QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 MED
QC Prep:V26295
Associated Lab Samples: 92826
Lab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
11/11/22 11:190.0050.0006<0.0006mg/Kg1,4-Dichlorobenzene
11/11/22 11:190.0100.001<0.001mg/KgDichlorodifluoromethane
11/11/22 11:190.0050.0008<0.0008mg/Kg1,1-Dichloroethane
11/11/22 11:190.0050.001<0.001mg/Kg1,2-Dichloroethane
11/11/22 11:190.0050.0007<0.0007mg/Kg1,1-Dichloroethene
11/11/22 11:190.0050.0008<0.0008mg/Kgcis-1,2-Dichloroethene
11/11/22 11:190.0050.001<0.001mg/Kgtrans-1,2-Dichloroethene
11/11/22 11:190.0050.0004<0.0004mg/Kg1,2-Dichloropropane
11/11/22 11:190.0050.0006<0.0006mg/Kg1,3-Dichloropropane
11/11/22 11:190.0050.001<0.001mg/Kg2,2-Dichloropropane
11/11/22 11:190.0050.0008<0.0008mg/Kg1,1-Dichloropropene
11/11/22 11:190.0050.0005<0.0005mg/Kgcis-1,3-Dichloropropene
11/11/22 11:190.0050.0008<0.0008mg/Kgtrans-1,3-Dichloropropene
11/11/22 11:190.2500.014<0.014mg/KgEthanol
11/11/22 11:190.0050.0006<0.0006mg/KgEthylbenzene
11/11/22 11:190.1000.0008<0.0008mg/KgEthyl Tertiary Butyl Ether (ETBE)
11/11/22 11:190.0100.0008<0.0008mg/KgHexachlorobutadiene
11/11/22 11:190.0100.0007<0.0007mg/Kgn-Hexane
11/11/22 11:190.0200.0006<0.0006mg/Kg2-Hexanone
11/11/22 11:190.0050.0005<0.0005mg/KgIsopropylbenzene
11/11/22 11:190.0050.001<0.001mg/Kg4-Isopropyl toluene
11/11/22 11:190.0200.0007<0.0007mg/KgMethyl Ethyl Ketone (MEK)
11/11/22 11:190.0050.0006<0.0006mg/KgMethyl tert-butyl ether (MTBE)
11/11/22 11:190.0050.001<0.001mg/KgMethylene Chloride
11/11/22 11:190.0100.0010<0.0010mg/KgNaphthalene
11/11/22 11:190.0050.0005<0.0005mg/Kgn-Propylbenzene
11/11/22 11:190.0050.001<0.001mg/KgStyrene
Page 15 of 32Date:11/19/2022 10:28 AM
Page 58 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V26296QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 MED
QC Prep:V26295
Associated Lab Samples: 92826
Lab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
11/11/22 11:190.2000.0010<0.0010mg/Kgtert-Butyl Alcohol (TBA)
11/11/22 11:190.4000.001<0.001mg/Kgtert-Butyl formate (TBF)
11/11/22 11:190.4000.0004<0.0004mg/Kgtert-Amyl Alcohol (TAA)
11/11/22 11:190.1000.0007<0.0007mg/Kgtert-Amyl Methyl Ether (TAME)
11/11/22 11:190.0050.001<0.001mg/Kg1,1,1,2-Tetrachloroethane
11/11/22 11:190.0050.0003<0.0003mg/Kg1,1,2,2-Tetrachloroethane
11/11/22 11:190.0050.0009<0.0009mg/KgTetrachloroethene
11/11/22 11:190.0050.0007<0.0007mg/KgToluene
11/11/22 11:190.0100.0005<0.0005mg/Kg1,2,3-Trichlorobenzene
11/11/22 11:190.0100.0006<0.0006mg/Kg1,2,4-Trichlorobenzene
11/11/22 11:190.0050.001<0.001mg/Kg1,1,1-Trichloroethane
11/11/22 11:190.0050.0005<0.0005mg/Kg1,1,2-Trichloroethane
11/11/22 11:190.0050.0009<0.0009mg/KgTrichloroethene
11/11/22 11:190.0100.002<0.002mg/KgTrichlorofluoromethane
11/11/22 11:190.0050.0007<0.0007mg/Kg1,2,3-Trichloropropane
11/11/22 11:190.0050.0005<0.0005mg/Kg1,2,4-Trimethylbenzene
11/11/22 11:190.0050.0005<0.0005mg/Kg1,3,5-Trimethylbenzene
11/11/22 11:190.0100.0005<0.0005mg/KgVinyl Acetate
11/11/22 11:190.0100.0005<0.0005mg/KgVinyl Chloride
11/11/22 11:190.0050.0005<0.0005mg/Kgo-Xylene
11/11/22 11:190.0100.001<0.001mg/Kgm,p-Xylene
11/11/22 11:194-Bromofluorobenzene (S)101 70-130
11/11/22 11:19Dibromofluoromethane (S)101 70-130
11/11/22 11:19Toluene-d8 (S)101 76-129
Page 16 of 32Date:11/19/2022 10:28 AM
Page 59 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V26296QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 MED
QC Prep:V26295
LCS-V26295 LCSD-V26295Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.111 1111150.1150.100mg/KgAcetone 29-198 3.5 20
0.103 10393.90.0930.100mg/KgAcrolein 70-130 9.2 20
0.101 10198.30.0980.100mg/KgAcrylonitrile 65-134 2.7 20
0.049 99.61020.0510.050mg/KgBenzene 74-127 2.5 20
0.048 97.094.60.0470.050mg/KgBromobenzene 73-125 2.5 20
0.049 98.294.80.0470.050mg/KgBromochloromethane 72-134 3.5 20
0.049 98.695.00.0470.050mg/KgBromodichloromethane 75-122 3.7 20
0.045 90.892.20.0460.050mg/KgBromoform 66-135 1.5 20
0.044 89.490.40.0450.050mg/KgBromomethane 20-180 1.1 20
0.050 1021010.0500.050mg/Kgn-Butylbenzene 65-135 0.9 20
0.050 10098.20.0490.050mg/Kgsec-Butyl benzene 66-131 2.0 20
0.048 97.094.20.0470.050mg/Kgtert-Butyl benzene 67-132 2.9 20
0.047 94.495.20.0470.050mg/KgCarbon Disulfide 61-129 0.8 20
0.044 89.291.60.0450.050mg/KgCarbon Tetrachloride 64-143 2.6 20
0.047 95.696.80.0480.050mg/KgChlorobenzene 74-118 1.2 20
0.044 88.292.00.0460.050mg/KgChlorodibromomethane 73-122 4.2 20
0.045 90.497.60.0480.050mg/KgChloroethane 33-149 7.6 20
0.050 10197.80.0480.050mg/KgChloroform 73-127 3.0 20
0.041 83.884.20.0420.050mg/KgChloromethane 45-143 0.4 20
0.048 97.098.60.0490.050mg/Kg2-Chlorotoluene 67-124 1.6 20
0.048 97.298.80.0490.050mg/Kg4-Chlorotoluene 71-126 1.6 20
0.053 1071070.0530.050mg/KgDi-Isopropyl Ether (DIPE)59-159 0.3 20
0.042 84.678.40.0390.050mg/Kg1,2-Dibromo-3-Chloropropane 55-157 7.6 20
0.047 95.893.40.0460.050mg/Kg1,2-Dibromoethane 70-132 2.5 20
0.048 97.891.60.0450.050mg/KgDibromomethane 74-133 6.5 20
0.050 10097.20.0480.050mg/Kg1,2-Dichlorobenzene 72-123 2.8 20
Page 17 of 32Date:11/19/2022 10:28 AM
Page 60 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V26296QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 MED
QC Prep:V26295
LCS-V26295 LCSD-V26295Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.049 99.898.40.0490.050mg/Kg1,3-Dichlorobenzene 71-120 1.4 20
0.047 95.893.80.0460.050mg/Kg1,4-Dichlorobenzene 71-123 2.1 20
0.043 86.692.00.0460.050mg/KgDichlorodifluoromethane 26-146 6.0 20
0.048 97.499.40.0490.050mg/Kg1,1-Dichloroethane 74-127 2.0 20
0.052 1051040.0510.050mg/Kg1,2-Dichloroethane 68-128 0.9 20
0.049 98.298.80.0490.050mg/Kg1,1-Dichloroethene 67-149 0.6 20
0.047 95.498.60.0490.050mg/Kgcis-1,2-Dichloroethene 76-134 3.2 20
0.046 93.896.60.0480.050mg/Kgtrans-1,2-Dichloroethene 73-132 2.9 20
0.050 10199.60.0490.050mg/Kg1,2-Dichloropropane 73-130 1.3 20
0.049 98.41020.0510.050mg/Kg1,3-Dichloropropane 75-124 3.7 20
0.049 98.21050.0520.050mg/Kg2,2-Dichloropropane 50-142 6.5 20
0.048 97.21010.0500.050mg/Kg1,1-Dichloropropene 71-130 4.2 20
0.051 10298.80.0490.050mg/Kgcis-1,3-Dichloropropene 71-125 3.1 20
0.051 1031050.0520.050mg/Kgtrans-1,3-Dichloropropene 68-123 2.3 20
1.24 99.299.21.241.25mg/KgEthanol 70-130 0.0 20
0.047 94.696.00.0480.050mg/KgEthylbenzene 74-128 1.4 20
0.104 1041050.1050.100mg/KgEthyl Tertiary Butyl Ether (ETBE)70-130 0.9 20
0.047 95.492.40.0460.050mg/KgHexachlorobutadiene 64-125 3.1 20
0.050 10297.80.0480.050mg/Kgn-Hexane 70-130 3.8 20
0.054 1091090.0540.050mg/Kg2-Hexanone 61-157 0.1 20
0.046 93.291.80.0450.050mg/KgIsopropylbenzene 68-126 1.5 20
0.049 98.499.60.0490.050mg/Kg4-Isopropyl toluene 68-129 1.2 20
0.048 96.61030.0510.050mg/KgMethyl Ethyl Ketone (MEK)63-149 6.0 20
0.049 98.699.20.0490.050mg/KgMethyl tert-butyl ether (MTBE)70-130 0.6 20
0.049 98.61000.0500.050mg/KgMethylene Chloride 74-129 1.8 20
0.047 95.890.60.0450.050mg/KgNaphthalene 57-157 5.5 20
Page 18 of 32Date:11/19/2022 10:28 AM
Page 61 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V26296QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 MED
QC Prep:V26295
LCS-V26295 LCSD-V26295Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.049 99.095.60.0470.050mg/Kgn-Propylbenzene 67-130 3.4 20
0.049 99.499.60.0490.050mg/KgStyrene 77-121 0.2 20
0.088 88.589.30.0890.100mg/Kgtert-Butyl Alcohol (TBA)70-130 0.8 20
0.106 1061060.1060.100mg/Kgtert-Butyl formate (TBF)70-130 0.0 20
0.047 94.298.20.0490.050mg/Kgtert-Amyl Alcohol (TAA)70-130 4.1 20
0.102 1021010.1010.100mg/Kgtert-Amyl Methyl Ether (TAME)70-130 0.9 20
0.045 90.692.00.0460.050mg/Kg1,1,1,2-Tetrachloroethane 72-115 1.5 20
0.046 92.886.20.0430.050mg/Kg1,1,2,2-Tetrachloroethane 56-126 7.3 20
0.047 94.296.80.0480.050mg/KgTetrachloroethene 68-130 2.7 20
0.048 96.696.80.0480.050mg/KgToluene 71-129 0.2 20
0.048 96.897.00.0480.050mg/Kg1,2,3-Trichlorobenzene 68-130 0.2 20
0.050 1001000.0500.050mg/Kg1,2,4-Trichlorobenzene 66-125 0.0 20
0.047 95.496.60.0480.050mg/Kg1,1,1-Trichloroethane 67-131 1.2 20
0.048 97.095.80.0470.050mg/Kg1,1,2-Trichloroethane 70-133 1.2 20
0.047 94.493.80.0460.050mg/KgTrichloroethene 75-133 0.6 20
0.045 91.297.20.0480.050mg/KgTrichlorofluoromethane 44-146 6.3 20
0.045 90.284.20.0420.050mg/Kg1,2,3-Trichloropropane 60-137 6.8 20
0.049 98.094.60.0470.050mg/Kg1,2,4-Trimethylbenzene 69-129 3.5 20
0.048 96.896.80.0480.050mg/Kg1,3,5-Trimethylbenzene 69-128 0.0 20
0.042 84.689.80.0440.050mg/KgVinyl Acetate 60-140 5.9 20
0.049 99.01010.0500.050mg/KgVinyl Chloride 48-147 2.1 20
0.049 98.296.60.0480.050mg/Kgo-Xylene 74-126 1.6 20
0.096 96.199.80.0990.100mg/Kgm,p-Xylene 75-124 3.7 20
97.894.84-Bromofluorobenzene (S)70-130
103101Dibromofluoromethane (S)70-130
Page 19 of 32Date:11/19/2022 10:28 AM
Page 62 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V26296QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 MED
QC Prep:V26295
LCS-V26295 LCSD-V26295Laboratory Control Sample & LCSD
LCSD
ResultParameter
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
103102Toluene-d8 (S)76-129
Page 20 of 32Date:11/19/2022 10:28 AM
Page 63 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V26590QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V26440
Associated Lab Samples: 92825, 92826
Lab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
11/17/22 12:260.6600.116<0.116mg/KgAcenaphthene
11/17/22 12:260.6600.105<0.105mg/KgAcenaphthylene
11/17/22 12:260.6600.152<0.152mg/KgAniline
11/17/22 12:260.6600.143<0.143mg/KgAnthracene
11/17/22 12:260.6600.139<0.139mg/KgBenzo(a)anthracene
11/17/22 12:260.6600.147<0.147mg/KgBenzo(a)pyrene
11/17/22 12:260.6600.146<0.146mg/KgBenzo(b)fluoranthene
11/17/22 12:260.6600.136<0.136mg/KgBenzo(g,h,i)perylene
11/17/22 12:260.6600.137<0.137mg/KgBenzo(k)fluoranthene
11/17/22 12:262.000.580<0.580mg/KgBenzoic Acid
11/17/22 12:260.6600.105<0.105mg/KgBenzyl alcohol
11/17/22 12:260.6600.118<0.118mg/KgBis(2-Chloroethoxy)methane
11/17/22 12:260.6600.107<0.107mg/KgBis(2-Chloroethyl)ether
11/17/22 12:260.3300.136<0.136mg/KgBis(2-Chloroisopropyl)ether
11/17/22 12:260.6600.120<0.120mg/KgBis(2-ethylhexyl)phthalate
11/17/22 12:260.6600.109<0.109mg/Kg4-Bromophenyl phenyl ether
11/17/22 12:260.3300.113<0.113mg/KgButyl benzyl phthalate
11/17/22 12:260.6600.092<0.092mg/Kg4-Chloro-3-methylphenol
11/17/22 12:260.3300.112<0.112mg/Kg4-Chloroaniline
11/17/22 12:260.6600.116<0.116mg/Kg2-Chloronaphthalene
11/17/22 12:260.6600.098<0.098mg/Kg2-Chlorophenol
11/17/22 12:261.000.126<0.126mg/Kg4-Chlorophenyl phenyl ether
11/17/22 12:260.6600.142<0.142mg/KgChrysene
11/17/22 12:260.6600.230<0.230mg/KgDibenz(a,h)anthracene
11/17/22 12:260.6600.119<0.119mg/KgDibenzofuran
11/17/22 12:260.6600.094<0.094mg/Kg1,2-Dichlorobenzene
11/17/22 12:260.6600.097<0.097mg/Kg1,3-Dichlorobenzene
Page 21 of 32Date:11/19/2022 10:28 AM
Page 64 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V26590QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V26440
Associated Lab Samples: 92825, 92826
Lab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
11/17/22 12:260.3300.097<0.097mg/Kg1,4-Dichlorobenzene
11/17/22 12:260.6600.147<0.147mg/Kg3,3'-Dichlorobenzidine
11/17/22 12:260.6600.095<0.095mg/Kg2,4-Dichlorophenol
11/17/22 12:260.6600.180<0.180mg/KgDiethyl phthalate
11/17/22 12:260.6600.174<0.174mg/KgDimethyl phthalate
11/17/22 12:260.3300.108<0.108mg/Kg2,4-Dimethylphenol
11/17/22 12:260.6600.107<0.107mg/KgDi-n-butyl phthalate
11/17/22 12:261.500.240<0.240mg/Kg4,6-Dinitro-2-methylphenol
11/17/22 12:261.500.520<0.520mg/Kg2,4-Dinitrophenol
11/17/22 12:260.6600.096<0.096mg/Kg2,4-Dinitrotoluene
11/17/22 12:260.6600.108<0.108mg/Kg2,6-Dinitrotoluene
11/17/22 12:260.3300.143<0.143mg/KgDi-n-Octyl Phthalate
11/17/22 12:260.6600.123<0.123mg/KgFluoranthene
11/17/22 12:260.6600.128<0.128mg/KgFluorene
11/17/22 12:260.6600.106<0.106mg/KgHexachlorobenzene
11/17/22 12:260.6600.097<0.097mg/KgHexachlorobutadiene
11/17/22 12:260.6600.157<0.157mg/KgHexachlorocyclopentadiene
11/17/22 12:260.6600.079<0.079mg/KgHexachloroethane
11/17/22 12:260.6600.179<0.179mg/KgIndeno(1,2,3-cd)pyrene
11/17/22 12:260.6600.191<0.191mg/KgIsophorone
11/17/22 12:260.6600.106<0.106mg/Kg1-Methylnaphthalene
11/17/22 12:260.6600.100<0.100mg/Kg2-Methylnaphthalene
11/17/22 12:260.6600.097<0.097mg/Kg2-Methylphenol
11/17/22 12:260.6600.084<0.084mg/Kg3&4 Methylphenol
11/17/22 12:260.6600.144<0.144mg/KgNaphthalene
11/17/22 12:260.6600.096<0.096mg/Kg2-Nitroaniline
11/17/22 12:260.6600.120<0.120mg/Kg3-Nitroaniline
Page 22 of 32Date:11/19/2022 10:28 AM
Page 65 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V26590QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V26440
Associated Lab Samples: 92825, 92826
Lab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
11/17/22 12:260.3300.093<0.093mg/Kg4-Nitroaniline
11/17/22 12:260.3300.116<0.116mg/KgNitrobenzene
11/17/22 12:260.6600.088<0.088mg/Kg2-Nitrophenol
11/17/22 12:260.6600.117<0.117mg/Kg4-Nitrophenol
11/17/22 12:260.6600.263<0.263mg/KgN-Nitrosodimethylamine
11/17/22 12:260.6600.181<0.181mg/KgN-Nitrosodiphenylamine
11/17/22 12:260.6600.118<0.118mg/KgN-Nitroso-di-n-propylamine
11/17/22 12:261.000.347<0.347mg/KgPentachlorophenol
11/17/22 12:260.6600.208<0.208mg/KgPhenanthrene
11/17/22 12:260.6600.112<0.112mg/KgPhenol
11/17/22 12:260.6600.134<0.134mg/KgPyrene
11/17/22 12:260.3300.079<0.079mg/KgPyridine
11/17/22 12:260.6600.107<0.107mg/Kg1,2,4-Trichlorobenzene
11/17/22 12:260.6600.096<0.096mg/Kg2,4,5-Trichlorophenol
11/17/22 12:260.6600.096<0.096mg/Kg2,4,6-Trichlorophenol
11/17/22 12:262-Fluorobiphenyl (S)92.8 44-115
11/17/22 12:262-Fluorophenol (S)80.1 35-115
11/17/22 12:26Nitrobenzene-d5 (S)83.2 37-122
11/17/22 12:264-Terphenyl-d14 (S)99.4 54-127
11/17/22 12:262,4,6-Tribromophenol (S)80.7 39-132
11/17/22 12:26Phenol-d5 (S)75.9 34-121
LCS-V26440Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
91.61.531.67mg/KgAcenaphthene 40-123
91.61.531.67mg/KgAcenaphthylene 32-132
Page 23 of 32Date:11/19/2022 10:28 AM
Page 66 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V26590QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V26440
LCS-V26440Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
1332.221.67mg/KgAniline 12-197
96.41.611.67mg/KgAnthracene 47-123
94.01.571.67mg/KgBenzo(a)anthracene 49-126
1031.721.67mg/KgBenzo(a)pyrene 45-129
1001.671.67mg/KgBenzo(b)fluoranthene 45-132
91.61.531.67mg/KgBenzo(g,h,i)perylene 43-134
99.41.661.67mg/KgBenzo(k)fluoranthene 47-132
45.30.7571.67mg/KgBenzoic Acid 10-83
86.21.441.67mg/KgBenzyl alcohol 29-122
81.41.361.67mg/KgBis(2-Chloroethoxy)methane 36-121
77.81.301.67mg/KgBis(2-Chloroethyl)ether 31-120
85.61.431.67mg/KgBis(2-Chloroisopropyl)ether 33-131
1011.691.67mg/KgBis(2-ethylhexyl)phthalate 51-133
95.81.601.67mg/Kg4-Bromophenyl phenyl ether 46-124
1001.671.67mg/KgButyl benzyl phthalate 48-132
78.41.311.67mg/Kg4-Chloro-3-methylphenol 45-122
81.41.361.67mg/Kg4-Chloroaniline 17-106
92.81.551.67mg/Kg2-Chloronaphthalene 41-114
87.41.461.67mg/Kg2-Chlorophenol 34-121
95.21.591.67mg/Kg4-Chlorophenyl phenyl ether 45-121
94.61.581.67mg/KgChrysene 50-124
76.61.281.67mg/KgDibenz(a,h)anthracene 45-134
90.41.511.67mg/KgDibenzofuran 44-120
77.21.291.67mg/Kg1,2-Dichlorobenzene 33-117
75.41.261.67mg/Kg1,3-Dichlorobenzene 30-115
76.01.271.67mg/Kg1,4-Dichlorobenzene 31-115
80.21.341.67mg/Kg3,3'-Dichlorobenzidine 22-121
Page 24 of 32Date:11/19/2022 10:28 AM
Page 67 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V26590QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V26440
LCS-V26440Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
82.61.381.67mg/Kg2,4-Dichlorophenol 40-122
96.41.611.67mg/KgDiethyl phthalate 50-124
95.81.601.67mg/KgDimethyl phthalate 48-124
1071.781.67mg/Kg2,4-Dimethylphenol 30-127
1021.701.67mg/KgDi-n-butyl phthalate 51-128
86.81.451.67mg/Kg4,6-Dinitro-2-methylphenol 29-132
85.01.421.67mg/Kg2,4-Dinitrophenol 27-129
92.21.541.67mg/Kg2,4-Dinitrotoluene 48-126
94.01.571.67mg/Kg2,6-Dinitrotoluene 46-124
1011.691.67mg/KgDi-n-Octyl Phthalate 45-140
89.21.491.67mg/KgFluoranthene 50-127
94.01.571.67mg/KgFluorene 43-125
95.81.601.67mg/KgHexachlorobenzene 45-122
77.21.291.67mg/KgHexachlorobutadiene 32-123
80.81.351.67mg/KgHexachlorocyclopentadiene 32-117
77.21.291.67mg/KgHexachloroethane 28-117
88.61.481.67mg/KgIndeno(1,2,3-cd)pyrene 45-133
63.41.061.67mg/KgIsophorone 30-122
75.41.261.67mg/Kg1-Methylnaphthalene 40-119
75.41.261.67mg/Kg2-Methylnaphthalene 38-122
89.21.491.67mg/Kg2-Methylphenol 32-122
80.21.341.67mg/Kg3&4 Methylphenol 34-119
76.01.271.67mg/KgNaphthalene 35-123
97.61.631.67mg/Kg2-Nitroaniline 44-127
94.01.571.67mg/Kg3-Nitroaniline 33-119
1011.681.67mg/Kg4-Nitroaniline 63-147
71.21.191.67mg/KgNitrobenzene 34-122
Page 25 of 32Date:11/19/2022 10:28 AM
Page 68 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V26590QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V26440
LCS-V26440Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
75.41.261.67mg/Kg2-Nitrophenol 36-123
97.01.621.67mg/Kg4-Nitrophenol 30-132
66.41.111.67mg/KgN-Nitrosodimethylamine 10-146
1141.901.67mg/KgN-Nitrosodiphenylamine 38-127
83.21.391.67mg/KgN-Nitroso-di-n-propylamine 36-120
1131.881.67mg/KgPentachlorophenol 25-133
94.61.581.67mg/KgPhenanthrene 50-121
80.21.341.67mg/KgPhenol 34-121
93.41.561.67mg/KgPyrene 47-127
51.50.8611.67mg/KgPyridine 10-80
74.21.241.67mg/Kg1,2,4-Trichlorobenzene 34-118
89.81.501.67mg/Kg2,4,5-Trichlorophenol 41-124
91.61.531.67mg/Kg2,4,6-Trichlorophenol 39-126
97.02-Fluorobiphenyl (S)44-115
81.32-Fluorophenol (S)35-115
74.2Nitrobenzene-d5 (S)37-122
1034-Terphenyl-d14 (S)54-127
86.42,4,6-Tribromophenol (S)39-132
76.2Phenol-d5 (S)34-121
V 93010-MS-V26440 V 93010-MSD-V26440Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
1.56 93.41.591.661.67<0.116mg/KgAcenaphthene 95.7 40-123 1.9 20
1.53 91.61.541.661.67<0.105mg/KgAcenaphthylene 92.7 32-132 0.6 20
2.42 1452.161.661.67<0.152mg/KgAniline 130 12-197 11.3 20
Page 26 of 32Date:11/19/2022 10:28 AM
Page 69 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V26590QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V26440
V 93010-MS-V26440 V 93010-MSD-V26440Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
1.67 1001.651.661.67<0.143mg/KgAnthracene 99.3 47-123 1.2 20
1.61 96.41.611.661.67<0.139mg/KgBenzo(a)anthracene 96.9 49-126 0.0 20
1.79 1071.781.661.67<0.147mg/KgBenzo(a)pyrene 107 45-129 0.5 20
1.70 1021.691.661.67<0.146mg/KgBenzo(b)fluoranthene 102 45-132 0.5 20
1.58 94.61.591.661.67<0.136mg/KgBenzo(g,h,i)perylene 95.7 43-134 0.6 20
1.72 1031.741.661.67<0.137mg/KgBenzo(k)fluoranthene 105 47-132 1.1 20
1.36 81.41.381.661.67<0.580mg/KgBenzoic Acid 83.1 10-83 1.4 20
1.53 91.61.531.661.67<0.105mg/KgBenzyl alcohol 92.1 29-122 0.0 20
1.42 85.01.421.661.67<0.118mg/KgBis(2-Chloroethoxy)methane 85.5 36-121 0.0 20
1.28 76.61.521.661.67<0.107mg/KgBis(2-Chloroethyl)ether 91.5 31-120 17.1 20
1.52 91.01.581.661.67<0.136mg/KgBis(2-Chloroisopropyl)ether 95.1 33-131 3.8 20
1.75 1051.751.661.67<0.120mg/KgBis(2-ethylhexyl)phthalate 105 51-133 0.0 20
1.69 1011.661.661.67<0.109mg/Kg4-Bromophenyl phenyl ether 100 46-124 1.7 20
1.74 1041.751.661.67<0.113mg/KgButyl benzyl phthalate 105 48-132 0.5 20
1.37 82.01.371.661.67<0.092mg/Kg4-Chloro-3-methylphenol 82.5 45-122 0.0 20
1.39 83.21.351.661.67<0.112mg/Kg4-Chloroaniline 81.3 17-106 2.9 20
1.56 93.41.601.661.67<0.116mg/Kg2-Chloronaphthalene 96.3 41-114 2.5 20
1.50 89.81.521.661.67<0.098mg/Kg2-Chlorophenol 91.5 34-121 1.3 20
1.59 95.21.621.661.67<0.126mg/Kg4-Chlorophenyl phenyl ether 97.5 45-121 1.8 20
1.63 97.61.651.661.67<0.142mg/KgChrysene 99.3 50-124 1.2 20
1.47 88.01.411.661.67<0.230mg/KgDibenz(a,h)anthracene 84.9 45-134 4.1 20
1.53 91.61.561.661.67<0.119mg/KgDibenzofuran 93.9 44-120 1.9 20
1.44 86.21.431.661.67<0.094mg/Kg1,2-Dichlorobenzene 86.1 33-117 0.6 20
1.39 83.21.421.661.67<0.097mg/Kg1,3-Dichlorobenzene 85.5 30-115 2.1 20
1.38 82.61.411.661.67<0.097mg/Kg1,4-Dichlorobenzene 84.9 31-115 2.1 20
1.41 84.41.381.661.67<0.147mg/Kg3,3'-Dichlorobenzidine 83.1 22-121 2.1 20
Page 27 of 32Date:11/19/2022 10:28 AM
Page 70 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V26590QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V26440
V 93010-MS-V26440 V 93010-MSD-V26440Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
1.39 83.21.411.661.67<0.095mg/Kg2,4-Dichlorophenol 84.9 40-122 1.4 20
1.62 97.01.631.661.67<0.180mg/KgDiethyl phthalate 98.1 50-124 0.6 20
1.62 97.01.641.661.67<0.174mg/KgDimethyl phthalate 98.7 48-124 1.2 30
1.82 1091.821.661.67<0.108mg/Kg2,4-Dimethylphenol 110 30-127 0.0 20
1.77 1061.761.661.67<0.107mg/KgDi-n-butyl phthalate 106 51-128 0.5 20
1.58 94.61.581.661.67<0.240mg/Kg4,6-Dinitro-2-methylphenol 95.1 29-132 0.0 20
1.69 1011.751.661.67<0.520mg/Kg2,4-Dinitrophenol 105 27-129 3.4 20
1.57 94.01.581.661.67<0.096mg/Kg2,4-Dinitrotoluene 95.1 48-126 0.6 20
1.61 96.41.641.661.67<0.108mg/Kg2,6-Dinitrotoluene 98.7 46-124 1.8 20
1.78 1071.801.661.67<0.143mg/KgDi-n-Octyl Phthalate 108 45-140 1.1 20
1.53 91.61.541.661.67<0.123mg/KgFluoranthene 92.7 50-127 0.6 20
1.57 94.01.601.661.67<0.128mg/KgFluorene 96.3 43-125 1.8 20
1.66 99.41.651.661.67<0.106mg/KgHexachlorobenzene 99.3 45-122 0.6 20
1.32 79.01.321.661.67<0.097mg/KgHexachlorobutadiene 79.5 32-123 0.0 20
1.45 86.81.481.661.67<0.157mg/KgHexachlorocyclopentadiene 89.1 32-117 2.0 20
1.39 83.21.431.661.67<0.079mg/KgHexachloroethane 86.1 28-117 2.8 20
1.55 92.81.521.661.67<0.179mg/KgIndeno(1,2,3-cd)pyrene 91.5 45-133 1.9 20
1.12 67.01.131.661.67<0.191mg/KgIsophorone 68.0 30-122 0.8 20
1.32 79.01.341.661.67<0.106mg/Kg1-Methylnaphthalene 80.7 40-119 1.5 20
1.36 81.41.381.661.67<0.100mg/Kg2-Methylnaphthalene 83.1 38-122 1.4 20
1.51 90.41.541.661.67<0.097mg/Kg2-Methylphenol 92.7 32-122 1.9 20
1.36 81.41.401.661.67<0.084mg/Kg3&4 Methylphenol 84.3 34-119 2.8 20
1.34 80.21.341.661.67<0.144mg/KgNaphthalene 80.7 35-123 0.0 20
1.68 1011.661.661.67<0.096mg/Kg2-Nitroaniline 100 44-127 1.1 20
1.55 92.81.551.661.67<0.120mg/Kg3-Nitroaniline 93.3 33-119 0.0 20
1.65 98.81.661.661.67<0.093mg/Kg4-Nitroaniline 100 63-147 0.6 20
Page 28 of 32Date:11/19/2022 10:28 AM
Page 71 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V26590QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V26440
V 93010-MS-V26440 V 93010-MSD-V26440Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
1.27 76.01.261.661.67<0.116mg/KgNitrobenzene 75.9 34-122 0.7 20
1.29 77.21.321.661.67<0.088mg/Kg2-Nitrophenol 79.5 32-123 2.2 20
1.68 1011.721.661.67<0.117mg/Kg4-Nitrophenol 104 30-132 2.3 20
1.24 74.21.291.661.67<0.263mg/KgN-Nitrosodimethylamine 77.7 10-146 3.9 30
2.00 1201.981.661.67<0.181mg/KgN-Nitrosodiphenylamine 119 38-127 1.0 20
1.56 93.41.561.661.67<0.118mg/KgN-Nitroso-di-n-propylamine 93.9 36-120 0.0 20
2.06 1232.031.661.67<0.347mg/KgPentachlorophenol 122 25-133 1.4 20
1.66 99.41.631.661.67<0.208mg/KgPhenanthrene 98.1 50-121 1.8 20
1.37 82.01.421.661.67<0.112mg/KgPhenol 85.5 34-121 3.5 20
1.65 98.81.651.661.67<0.134mg/KgPyrene 99.3 47-127 0.0 20
1.05 62.80.9931.661.67<0.079mg/KgPyridine 59.8 10-80 5.5 20
1.25 74.81.311.661.67<0.107mg/Kg1,2,4-Trichlorobenzene 78.9 34-118 4.6 20
1.54 92.21.581.661.67<0.096mg/Kg2,4,5-Trichlorophenol 95.1 41-124 2.5 20
1.56 93.41.571.661.67<0.096mg/Kg2,4,6-Trichlorophenol 94.5 39-126 0.6 20
96.42-Fluorobiphenyl (S)98.1 44-115
79.82-Fluorophenol (S)80.4 35-115
78.4Nitrobenzene-d5 (S)79.5 37-122
1074-Terphenyl-d14 (S)106 54-127
88.52,4,6-Tribromophenol (S)87.3 39-132
78.0Phenol-d5 (S)77.7 34-121
Page 29 of 32Date:11/19/2022 10:28 AM
Page 72 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Massachusetts EPH
MADEP-EPH
V26522QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAEPH (Prep)
QC Prep:V26393
Associated Lab Samples: 92825, 92826
Lab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
11/16/22 14:1350.09.20<9.20mg/KgAliphatic C9-C18
11/16/22 14:1350.012.2<12.2mg/KgAliphatic C19-C36
11/16/22 14:1350.014.2<14.2mg/KgAromatic C11-C22
11/16/22 14:132-Fluorobiphenyl (S)108 40-140
11/16/22 14:132-Bromonaphthalene (S)106 40-140
11/16/22 14:13Chlorooctadecane (S)80.5 40-140
11/16/22 14:13OTP Surrogate (S)89.0 40-140
LCS-V26393 LCSD-V26393Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
37.8 63.068.841.360.0mg/KgAliphatic C9-C18 40-140 8.8 50
64.1 80.183.066.480.0mg/KgAliphatic C19-C36 40-140 3.5 50
178 105118200170mg/KgAromatic C11-C22 40-140 11.6 50
93.51032-Fluorobiphenyl (S)40-140
91.51012-Bromonaphthalene (S)40-140
81.585.0Chlorooctadecane (S)40-140
81.090.0OTP Surrogate (S)40-140
Page 30 of 32Date:11/19/2022 10:28 AM
Page 73 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V26292QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V26291
Associated Lab Samples: 92825, 92826
Lab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
11/11/22 12:078.001.22<1.22mg/KgAliphatic C5-C8
11/11/22 12:078.004.56<4.56mg/KgAliphatic C9-C12
11/11/22 12:078.000.624<0.624mg/KgAromatic C9-C10
11/11/22 12:072,5-Dibromotoluene (FID) (S)81.1 70-130
11/11/22 12:072,5-Dibromotoluene (PID) (S)79.9 70-130
LCS-V26291 LCSD-V26291Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
32.8 10310132.332.0mg/KgAliphatic C5-C8 70-130 1.5 50
33.4 10410333.032.0mg/KgAliphatic C9-C12 70-130 1.2 50
10.4 97.196.210.310.7mg/KgAromatic C9-C10 70-130 0.9 50
93.494.32,5-Dibromotoluene (FID) (S)70-130
86.481.82,5-Dibromotoluene (PID) (S)70-130
Page 31 of 32Date:11/19/2022 10:28 AM
Page 74 of 77
Quality Control Data
22-314-0102Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
Dry Weight Determination
SW-DRYWT
V26396QC Analytical Batch:
Analysis Method:
Analysis Description:
V 92845-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 11/14/22 18:080.911.011.1%Moisture
V 93098-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 11/14/22 18:080.235.935.8%Moisture
Page 32 of 32Date:11/19/2022 10:28 AM
Page 75 of 77
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:22-314-0102
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT-15 2.0 C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)?Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
ü
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)ü
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angela D Overcash Date & Time:11/10/2022 14:08:40
Special precautions or instructions included?
Comments:
Page 76 of 77
Page 77 of 77

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

2/3/2023
Geological Resources, Inc. Sam McKay
3502 Hayes Road Monroe, NC, 28110
Ref: Analytical Testing
Lab Report Number: 23-020-0019 Client Project Description: Former Philbecks Amoco
GRI #5888
Dear Sam McKay:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 1/20/2023 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love Project Manager
Page 1 of 111
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2023402State ProgramNorth Carolina
07/31/202399012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/23-020-0019
Page 2 of 111
Report Number:
Sample Summary Table
Client Project Description:
23-020-0019
Former Philbecks Amoco
GRI #5888
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
01/16/2023 12:28Aqueous 98090 MW-1A 01/20/2023 13:28
01/16/2023 12:40Aqueous 98091 MW-3 01/20/2023 13:28
01/16/2023 11:45Aqueous 98092 MW-4 01/20/2023 13:28
01/16/2023 12:21Aqueous 98093 MW-5 01/20/2023 13:28
01/16/2023 11:50Aqueous 98094 MW-7 01/20/2023 13:28
01/16/2023 12:31Aqueous 98095 MW-8 01/20/2023 13:28
01/16/2023 12:10Aqueous 98096 MW-10 01/20/2023 13:28
01/16/2023 12:15Aqueous 98097 MW-11 01/20/2023 13:28
01/16/2023 12:00Aqueous 98098 MW-X 01/20/2023 13:28
01/16/2023 15:50Aqueous 98099 MW-12 01/20/2023 13:28
01/16/2023 15:50Aqueous 98099 MW-12 01/20/2023 13:28 6010D
01/16/2023 16:10Aqueous 98100 MW-13 01/20/2023 13:28
01/16/2023 16:10Aqueous 98100 MW-13 01/20/2023 13:28 6010D
01/16/2023Aqueous 98101 01/20/2023 13:28
Eurofins - Savannah: Eurofins Environmental Testing Southeast, Savannah, Savannah, GA
Page 3 of 111
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-020-0019
Report Limit
Project:Former Philbecks Amoco
V 98090MW-1A
6990 01/27/2023 10:516200BBenzeneµg/L 18.0
J45.6 01/27/2023 10:516200Bn-Butylbenzene µg/L 18.0
50.9 01/27/2023 10:516200BDi-Isopropyl Ether (DIPE)µg/L 50.0
2900 01/27/2023 10:516200BEthylbenzeneµg/L 17.0
141 01/27/2023 10:516200B2-Hexanone µg/L 38.0
102 01/27/2023 10:516200BIsopropylbenzeneµg/L 18.0
685 01/27/2023 10:516200BMethyl Ethyl Ketone (MEK)µg/L 71.0
4200 01/27/2023 10:516200BMethyl tert-butyl ether (MTBE)µg/L 14.0
1180 01/27/2023 10:516200BNaphthaleneµg/L 47.0
322 01/27/2023 10:516200Bn-Propylbenzene µg/L 19.0
J34.4 01/27/2023 10:516200BStyreneµg/L 22.0
6450 01/27/2023 10:516200BTolueneµg/L 22.0
3230 01/27/2023 10:516200B1,2,4-Trimethylbenzene µg/L 19.0
989 01/27/2023 10:516200B1,3,5-Trimethylbenzene µg/L 18.0
3300 01/27/2023 10:516200Bo-Xylene µg/L 21.0
10400 01/27/2023 10:516200Bm,p-Xylene µg/L 42.0
13700 01/27/2023 10:516200BXylene (Total)µg/L 21.0
V 98091MW-3
J2.86 01/27/2023 10:026200Bn-Butylbenzene µg/L 1.80
J4.29 01/27/2023 10:026200Bsec-Butyl benzene µg/L 2.00
J2.25 01/27/2023 10:026200Bn-Propylbenzene µg/L 1.90
J3.23 01/27/2023 10:026200BTolueneµg/L 2.20
V 98093MW-5
29.4 01/27/2023 05:326200BAcetoneµg/L 1.80
8.99 01/27/2023 05:326200BBenzeneµg/L 0.180
28.7 01/27/2023 05:326200BDi-Isopropyl Ether (DIPE)µg/L 0.500
247 01/28/2023 08:236200BMethyl tert-butyl ether (MTBE)µg/L 1.40
J0.494 01/27/2023 05:326200BNaphthaleneµg/L 0.470
J0.359 01/27/2023 05:326200BTolueneµg/L 0.220
J0.227 01/27/2023 05:326200B1,2,4-Trimethylbenzene µg/L 0.190
0.669 01/27/2023 05:326200Bo-Xylene µg/L 0.210
J0.549 01/27/2023 05:326200Bm,p-Xylene µg/L 0.420
J1.22 01/27/2023 05:326200BXylene (Total)µg/L 0.210
V 98097MW-11
J0.432 01/27/2023 07:106200BBenzeneµg/L 0.180
Page 4 of 111
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-020-0019
Report Limit
Project:Former Philbecks Amoco
V 98097MW-11
J0.339 01/27/2023 07:106200BEthylbenzeneµg/L 0.170
J0.278 01/27/2023 07:106200BMethyl tert-butyl ether (MTBE)µg/L 0.140
0.507 01/27/2023 07:106200BTolueneµg/L 0.220
0.692 01/27/2023 07:106200B1,2,4-Trimethylbenzene µg/L 0.190
J0.233 01/27/2023 07:106200B1,3,5-Trimethylbenzene µg/L 0.180
J0.470 01/27/2023 07:106200Bo-Xylene µg/L 0.210
1.22 01/27/2023 07:106200Bm,p-Xylene µg/L 0.420
J1.69 01/27/2023 07:106200BXylene (Total)µg/L 0.210
V 98098MW-X
0.554 01/27/2023 07:346200BTolueneµg/L 0.220
V 98099MW-12
See Attached6010DLead mg/L
J2.29 01/23/2023 17:14625.1 Benzoic Acid µg/L 1.23
J1.17 01/23/2023 17:14625.1 Benzyl alcohol µg/L 0.764
V 98100MW-13
See Attached6010DLead mg/L
8510 01/27/2023 11:156200BBenzeneµg/L 18.0
53.6 01/27/2023 11:156200BDi-Isopropyl Ether (DIPE)µg/L 50.0
2750 01/27/2023 11:156200BEthylbenzeneµg/L 17.0
193 01/27/2023 11:156200B2-Hexanone µg/L 38.0
117 01/27/2023 11:156200BIsopropylbenzeneµg/L 18.0
1040 01/27/2023 11:156200BMethyl tert-butyl ether (MTBE)µg/L 14.0
102 01/27/2023 11:156200B4-Methyl-2-Pentanone µg/L 7.80
642 01/27/2023 11:156200BNaphthaleneµg/L 47.0
286 01/27/2023 11:156200Bn-Propylbenzene µg/L 19.0
48100 01/28/2023 10:256200BTolueneµg/L 220
2150 01/27/2023 11:156200B1,2,4-Trimethylbenzene µg/L 19.0
530 01/27/2023 11:156200B1,3,5-Trimethylbenzene µg/L 18.0
4380 01/27/2023 11:156200Bo-Xylene µg/L 21.0
9270 01/27/2023 11:156200Bm,p-Xylene µg/L 42.0
13700 01/27/2023 11:156200BXylene (Total)µg/L 21.0
41.2 01/23/2023 17:37625.1 1-Methylnaphthalene µg/L 1.21
78.0 01/23/2023 17:37625.1 2-Methylnaphthalene µg/L 0.709
430 01/24/2023 11:14625.1 Naphthalene µg/L 3.10
23200 01/24/2023 18:27CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 1150
Page 5 of 111
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-020-0019
Report Limit
Project:Former Philbecks Amoco
V 98100MW-13
14600 01/24/2023 18:27CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 2580
5560 01/24/2023 18:27CALCULATIONAromatic C9-C10 (Adjusted)µg/L 402
501 01/23/2023 17:37CALCULATIONAromatic C11-C22 (Adjusted)µg/L 63.2
931 01/31/2023 12:59MADEP-EPH Aromatic C11-C22 µg/L 63.2
79800 01/24/2023 18:27MADEP-VPH Aliphatic C5-C8 µg/L 1150
36600 01/24/2023 18:27MADEP-VPH Aliphatic C9-C12 µg/L 2580
5560 01/24/2023 18:27MADEP-VPH Aromatic C9-C10 µg/L 402
V 98101TB
J0.402 01/27/2023 04:186200BMethylene Chloride µg/L 0.330
Page 6 of 111

Client: Geological Resources, Inc. CASE NARRATIVE
Project: Former Philbecks Amoco Lab Report Number: 23-020-0019
Date: 2/3/2023
EDB and DBCP by Microextraction GC/ECD Method EPA-504.1 Analyte: 1,2-Dibromoethane QC Batch No: V29192/V29170 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. 625.1 - Base/Neutrals and Acids by GC/MS Method 625.1 Analyte: Benzidine
QC Batch No: V29124/V29089 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Volatile Organic Compounds - GC/MS Method 6200B Sample 98091 (MW-3) QC Batch No: V29218/V29217
The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly.
Analyte: Vinyl acetate QC Batch No: V29218/V29217
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Vinyl acetate QC Batch No: V29281/V29217 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.

Page 7 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-1A
98090 Matrix:
1/16/2023 12:28
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<180 µg/L 180 1000Acetone 100 01/27/23 10:51 V29218MSA
6990 µg/L 18.0 50.0Benzene 100 01/27/23 10:51 V29218MSA
<21.0 µg/L 21.0 50.0Bromobenzene 100 01/27/23 10:51 V29218MSA
<42.0 µg/L 42.0 100Bromochloromethane 100 01/27/23 10:51 V29218MSA
<16.0 µg/L 16.0 50.0Bromodichloromethane 100 01/27/23 10:51 V29218MSA
<150 µg/L 150 500Bromoform 100 01/27/23 10:51 V29218MSA
<28.0 µg/L 28.0 100Bromomethane 100 01/27/23 10:51 V29218MSA
45.6 J µg/L 18.0 50.0n-Butylbenzene 100 01/27/23 10:51 V29218MSA
<20.0 µg/L 20.0 50.0sec-Butyl benzene 100 01/27/23 10:51 V29218MSA
<92.0 µg/L 92.0 200tert-Butyl benzene 100 01/27/23 10:51 V29218MSA
<18.0 µg/L 18.0 50.0Carbon Tetrachloride 100 01/27/23 10:51 V29218MSA
<19.0 µg/L 19.0 50.0Chlorobenzene 100 01/27/23 10:51 V29218MSA
<19.0 µg/L 19.0 50.0Chlorodibromomethane 100 01/27/23 10:51 V29218MSA
<43.0 µg/L 43.0 100Chloroethane 100 01/27/23 10:51 V29218MSA
<22.0 µg/L 22.0 50.0Chloroform 100 01/27/23 10:51 V29218MSA
<22.0 µg/L 22.0 50.0Chloromethane 100 01/27/23 10:51 V29218MSA
<20.0 µg/L 20.0 50.02-Chlorotoluene 100 01/27/23 10:51 V29218MSA
<20.0 µg/L 20.0 50.04-Chlorotoluene 100 01/27/23 10:51 V29218MSA
50.9 µg/L 50.0 50.0Di-Isopropyl Ether (DIPE)100 01/27/23 10:51 V29218MSA
<110 µg/L 110 2001,2-Dibromo-3-Chloropropane 100 01/27/23 10:51 V29218MSA
<20.0 µg/L 20.0 50.01,2-Dibromoethane 100 01/27/23 10:51 V29218MSA
<23.0 µg/L 23.0 50.0Dibromomethane 100 01/27/23 10:51 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 8 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-1A
98090 Matrix:
1/16/2023 12:28
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<22.0 µg/L 22.0 50.01,2-Dichlorobenzene 100 01/27/23 10:51 V29218MSA
<19.0 µg/L 19.0 50.01,3-Dichlorobenzene 100 01/27/23 10:51 V29218MSA
<21.0 µg/L 21.0 50.01,4-Dichlorobenzene 100 01/27/23 10:51 V29218MSA
<120 µg/L 120 500Dichlorodifluoromethane 100 01/27/23 10:51 V29218MSA
<24.0 µg/L 24.0 50.01,1-Dichloroethane 100 01/27/23 10:51 V29218MSA
<15.0 µg/L 15.0 50.01,2-Dichloroethane 100 01/27/23 10:51 V29218MSA
<15.0 µg/L 15.0 50.01,1-Dichloroethene 100 01/27/23 10:51 V29218MSA
<20.0 µg/L 20.0 50.0cis-1,2-Dichloroethene 100 01/27/23 10:51 V29218MSA
<18.0 µg/L 18.0 50.0trans-1,2-Dichloroethene 100 01/27/23 10:51 V29218MSA
<19.0 µg/L 19.0 50.01,2-Dichloropropane 100 01/27/23 10:51 V29218MSA
<13.0 µg/L 13.0 50.01,3-Dichloropropane 100 01/27/23 10:51 V29218MSA
<21.0 µg/L 21.0 2002,2-Dichloropropane 100 01/27/23 10:51 V29218MSA
<20.0 µg/L 20.0 50.01,1-Dichloropropene 100 01/27/23 10:51 V29218MSA
<21.0 µg/L 21.0 50.0cis-1,3-Dichloropropene 100 01/27/23 10:51 V29218MSA
<15.0 µg/L 15.0 50.0trans-1,3-Dichloropropene 100 01/27/23 10:51 V29218MSA
<4200 µg/L 4200 20000Ethanol 100 01/27/23 10:51 V29218MSA
2900 µg/L 17.0 50.0Ethylbenzene 100 01/27/23 10:51 V29218MSA
<35.0 µg/L 35.0 300Hexachlorobutadiene 100 01/27/23 10:51 V29218MSA
141 µg/L 38.0 1002-Hexanone 100 01/27/23 10:51 V29218MSA
102 µg/L 18.0 50.0Isopropylbenzene 100 01/27/23 10:51 V29218MSA
<8.90 µg/L 8.90 50.04-Isopropyl toluene 100 01/27/23 10:51 V29218MSA
685 µg/L 71.0 500Methyl Ethyl Ketone (MEK)100 01/27/23 10:51 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 9 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-1A
98090 Matrix:
1/16/2023 12:28
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
4200 µg/L 14.0 100Methyl tert-butyl ether (MTBE)100 01/27/23 10:51 V29218MSA
<7.80 µg/L 7.80 1004-Methyl-2-Pentanone 100 01/27/23 10:51 V29218MSA
<33.0 µg/L 33.0 200Methylene Chloride 100 01/27/23 10:51 V29218MSA
1180 µg/L 47.0 100Naphthalene 100 01/27/23 10:51 V29218MSA
322 µg/L 19.0 50.0n-Propylbenzene 100 01/27/23 10:51 V29218MSA
34.4 J µg/L 22.0 50.0Styrene 100 01/27/23 10:51 V29218MSA
<16.0 µg/L 16.0 50.01,1,1,2-Tetrachloroethane 100 01/27/23 10:51 V29218MSA
<16.0 µg/L 16.0 50.01,1,2,2-Tetrachloroethane 100 01/27/23 10:51 V29218MSA
<22.0 µg/L 22.0 50.0 100 01/27/23 10:51 V29218MSA
6450 µg/L 22.0 50.0 100 01/27/23 10:51 V29218MSA
<38.0 µg/L 38.0 50.01,2,3-Trichlorobenzene 100 01/27/23 10:51 V29218MSA
<31.0 µg/L 31.0 50.01,2,4-Trichlorobenzene 100 01/27/23 10:51 V29218MSA
<16.0 µg/L 16.0 50.01,1,1-Trichloroethane 100 01/27/23 10:51 V29218MSA
<9.60 µg/L 9.60 50.01,1,2-Trichloroethane 100 01/27/23 10:51 V29218MSA
<18.0 µg/L 18.0 50.0 100 01/27/23 10:51 V29218MSA
<18.0 µg/L 18.0 50.0 100 01/27/23 10:51 V29218MSA
<27.0 µg/L 27.0 50.01,2,3-Trichloropropane 100 01/27/23 10:51 V29218MSA
3230 µg/L 19.0 50.01,2,4-Trimethylbenzene 100 01/27/23 10:51 V29218MSA
989 µg/L 18.0 50.01,3,5-Trimethylbenzene 100 01/27/23 10:51 V29218MSA
<100 µg/L 100 500Vinyl Acetate 100 01/27/23 10:51 V29218MSA
<17.0 µg/L 17.0 50.0Vinyl Chloride 100 01/27/23 10:51 V29218MSA
3300 µg/L 21.0 50.0o-Xylene 100 01/27/23 10:51 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 10 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-1A
98090 Matrix:
1/16/2023 12:28
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
10400 µg/L 42.0 100m,p-Xylene 100 01/27/23 10:51 V29218MSA
13700 µg/L 21.0 50.0Xylene (Total)100 01/27/23 10:51 V29218
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 11 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-3
98091 Matrix:
1/16/2023 12:40
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<18.0 µg/L 18.0 100Acetone 10 01/27/23 10:02 V29218MSA
<1.80 µg/L 1.80 5.00Benzene 10 01/27/23 10:02 V29218MSA
<2.10 µg/L 2.10 5.00Bromobenzene 10 01/27/23 10:02 V29218MSA
<4.20 µg/L 4.20 10.0Bromochloromethane 10 01/27/23 10:02 V29218MSA
<1.60 µg/L 1.60 5.00Bromodichloromethane 10 01/27/23 10:02 V29218MSA
<15.0 µg/L 15.0 50.0Bromoform 10 01/27/23 10:02 V29218MSA
<2.80 µg/L 2.80 10.0Bromomethane 10 01/27/23 10:02 V29218MSA
2.86 J µg/L 1.80 5.00n-Butylbenzene 10 01/27/23 10:02 V29218MSA
4.29 J µg/L 2.00 5.00sec-Butyl benzene 10 01/27/23 10:02 V29218MSA
<9.20 µg/L 9.20 20.0tert-Butyl benzene 10 01/27/23 10:02 V29218MSA
<1.80 µg/L 1.80 5.00Carbon Tetrachloride 10 01/27/23 10:02 V29218MSA
<1.90 µg/L 1.90 5.00Chlorobenzene 10 01/27/23 10:02 V29218MSA
<1.90 µg/L 1.90 5.00Chlorodibromomethane 10 01/27/23 10:02 V29218MSA
<4.30 µg/L 4.30 10.0Chloroethane 10 01/27/23 10:02 V29218MSA
<2.20 µg/L 2.20 5.00Chloroform 10 01/27/23 10:02 V29218MSA
<2.20 µg/L 2.20 5.00Chloromethane 10 01/27/23 10:02 V29218MSA
<2.00 µg/L 2.00 5.002-Chlorotoluene 10 01/27/23 10:02 V29218MSA
<2.00 µg/L 2.00 5.004-Chlorotoluene 10 01/27/23 10:02 V29218MSA
<5.00 µg/L 5.00 5.00Di-Isopropyl Ether (DIPE)10 01/27/23 10:02 V29218MSA
<11.0 µg/L 11.0 20.01,2-Dibromo-3-Chloropropane 10 01/27/23 10:02 V29218MSA
<2.00 µg/L 2.00 5.001,2-Dibromoethane 10 01/27/23 10:02 V29218MSA
<2.30 µg/L 2.30 5.00Dibromomethane 10 01/27/23 10:02 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 12 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-3
98091 Matrix:
1/16/2023 12:40
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<2.20 µg/L 2.20 5.001,2-Dichlorobenzene 10 01/27/23 10:02 V29218MSA
<1.90 µg/L 1.90 5.001,3-Dichlorobenzene 10 01/27/23 10:02 V29218MSA
<2.10 µg/L 2.10 5.001,4-Dichlorobenzene 10 01/27/23 10:02 V29218MSA
<12.0 µg/L 12.0 50.0Dichlorodifluoromethane 10 01/27/23 10:02 V29218MSA
<2.40 µg/L 2.40 5.001,1-Dichloroethane 10 01/27/23 10:02 V29218MSA
<1.50 µg/L 1.50 5.001,2-Dichloroethane 10 01/27/23 10:02 V29218MSA
<1.50 µg/L 1.50 5.001,1-Dichloroethene 10 01/27/23 10:02 V29218MSA
<2.00 µg/L 2.00 5.00cis-1,2-Dichloroethene 10 01/27/23 10:02 V29218MSA
<1.80 µg/L 1.80 5.00trans-1,2-Dichloroethene 10 01/27/23 10:02 V29218MSA
<1.90 µg/L 1.90 5.001,2-Dichloropropane 10 01/27/23 10:02 V29218MSA
<1.30 µg/L 1.30 5.001,3-Dichloropropane 10 01/27/23 10:02 V29218MSA
<2.10 µg/L 2.10 20.02,2-Dichloropropane 10 01/27/23 10:02 V29218MSA
<2.00 µg/L 2.00 5.001,1-Dichloropropene 10 01/27/23 10:02 V29218MSA
<2.10 µg/L 2.10 5.00cis-1,3-Dichloropropene 10 01/27/23 10:02 V29218MSA
<1.50 µg/L 1.50 5.00trans-1,3-Dichloropropene 10 01/27/23 10:02 V29218MSA
<420 µg/L 420 2000Ethanol 10 01/27/23 10:02 V29218MSA
<1.70 µg/L 1.70 5.00Ethylbenzene 10 01/27/23 10:02 V29218MSA
<3.50 µg/L 3.50 30.0Hexachlorobutadiene 10 01/27/23 10:02 V29218MSA
<3.80 µg/L 3.80 10.02-Hexanone 10 01/27/23 10:02 V29218MSA
<1.80 µg/L 1.80 5.00Isopropylbenzene 10 01/27/23 10:02 V29218MSA
<0.890 µg/L 0.890 5.004-Isopropyl toluene 10 01/27/23 10:02 V29218MSA
<7.10 µg/L 7.10 50.0Methyl Ethyl Ketone (MEK)10 01/27/23 10:02 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 13 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-3
98091 Matrix:
1/16/2023 12:40
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<1.40 µg/L 1.40 10.0Methyl tert-butyl ether (MTBE)10 01/27/23 10:02 V29218MSA
<0.780 µg/L 0.780 10.04-Methyl-2-Pentanone 10 01/27/23 10:02 V29218MSA
<3.30 µg/L 3.30 20.0Methylene Chloride 10 01/27/23 10:02 V29218MSA
<4.70 µg/L 4.70 10.0Naphthalene 10 01/27/23 10:02 V29218MSA
2.25 J µg/L 1.90 5.00n-Propylbenzene 10 01/27/23 10:02 V29218MSA
<2.20 µg/L 2.20 5.00Styrene 10 01/27/23 10:02 V29218MSA
<1.60 µg/L 1.60 5.001,1,1,2-Tetrachloroethane 10 01/27/23 10:02 V29218MSA
<1.60 µg/L 1.60 5.001,1,2,2-Tetrachloroethane 10 01/27/23 10:02 V29218MSA
<2.20 µg/L 2.20 5.00 10 01/27/23 10:02 V29218MSA
3.23 J µg/L 2.20 5.00 10 01/27/23 10:02 V29218MSA
<3.80 µg/L 3.80 5.001,2,3-Trichlorobenzene 10 01/27/23 10:02 V29218MSA
<3.10 µg/L 3.10 5.001,2,4-Trichlorobenzene 10 01/27/23 10:02 V29218MSA
<1.60 µg/L 1.60 5.001,1,1-Trichloroethane 10 01/27/23 10:02 V29218MSA
<0.960 µg/L 0.960 5.001,1,2-Trichloroethane 10 01/27/23 10:02 V29218MSA
<1.80 µg/L 1.80 5.00 10 01/27/23 10:02 V29218MSA
<1.80 µg/L 1.80 5.00 10 01/27/23 10:02 V29218MSA
<2.70 µg/L 2.70 5.001,2,3-Trichloropropane 10 01/27/23 10:02 V29218MSA
<1.90 µg/L 1.90 5.001,2,4-Trimethylbenzene 10 01/27/23 10:02 V29218MSA
<1.80 µg/L 1.80 5.001,3,5-Trimethylbenzene 10 01/27/23 10:02 V29218MSA
<10.0 µg/L 10.0 50.0Vinyl Acetate 10 01/27/23 10:02 V29218MSA
<1.70 µg/L 1.70 5.00Vinyl Chloride 10 01/27/23 10:02 V29218MSA
<2.10 µg/L 2.10 5.00o-Xylene 10 01/27/23 10:02 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 14 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-3
98091 Matrix:
1/16/2023 12:40
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<4.20 µg/L 4.20 10.0m,p-Xylene 10 01/27/23 10:02 V29218MSA
<2.1 µg/L 2.10 5.00Xylene (Total)10 01/27/23 10:02 V29218
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 15 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-4
98092 Matrix:
1/16/2023 11:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<1.80 µg/L 1.80 10.0Acetone 1 01/27/23 05:07 V29218MSA
<0.180 µg/L 0.180 0.500Benzene 1 01/27/23 05:07 V29218MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 01/27/23 05:07 V29218MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 01/27/23 05:07 V29218MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 01/27/23 05:07 V29218MSA
<1.50 µg/L 1.50 5.00Bromoform 1 01/27/23 05:07 V29218MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 01/27/23 05:07 V29218MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 01/27/23 05:07 V29218MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 01/27/23 05:07 V29218MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 01/27/23 05:07 V29218MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 01/27/23 05:07 V29218MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 01/27/23 05:07 V29218MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 01/27/23 05:07 V29218MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 01/27/23 05:07 V29218MSA
<0.220 µg/L 0.220 0.500Chloroform 1 01/27/23 05:07 V29218MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 01/27/23 05:07 V29218MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 01/27/23 05:07 V29218MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 01/27/23 05:07 V29218MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 01/27/23 05:07 V29218MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 01/27/23 05:07 V29218MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 01/27/23 05:07 V29218MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 01/27/23 05:07 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 16 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-4
98092 Matrix:
1/16/2023 11:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 01/27/23 05:07 V29218MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 01/27/23 05:07 V29218MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 01/27/23 05:07 V29218MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 01/27/23 05:07 V29218MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 01/27/23 05:07 V29218MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 01/27/23 05:07 V29218MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 01/27/23 05:07 V29218MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 01/27/23 05:07 V29218MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 01/27/23 05:07 V29218MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 01/27/23 05:07 V29218MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 01/27/23 05:07 V29218MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 01/27/23 05:07 V29218MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 01/27/23 05:07 V29218MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 01/27/23 05:07 V29218MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 01/27/23 05:07 V29218MSA
<42.0 µg/L 42.0 200Ethanol 1 01/27/23 05:07 V29218MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 01/27/23 05:07 V29218MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 01/27/23 05:07 V29218MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 01/27/23 05:07 V29218MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 01/27/23 05:07 V29218MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 01/27/23 05:07 V29218MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 01/27/23 05:07 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 17 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-4
98092 Matrix:
1/16/2023 11:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 01/27/23 05:07 V29218MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 01/27/23 05:07 V29218MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 01/27/23 05:07 V29218MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 01/27/23 05:07 V29218MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 01/27/23 05:07 V29218MSA
<0.220 µg/L 0.220 0.500Styrene 1 01/27/23 05:07 V29218MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 01/27/23 05:07 V29218MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 01/27/23 05:07 V29218MSA
<0.220 µg/L 0.220 0.500 1 01/27/23 05:07 V29218MSA
<0.220 µg/L 0.220 0.500 1 01/27/23 05:07 V29218MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 01/27/23 05:07 V29218MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 01/27/23 05:07 V29218MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 01/27/23 05:07 V29218MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 01/27/23 05:07 V29218MSA
<0.180 µg/L 0.180 0.500 1 01/27/23 05:07 V29218MSA
<0.180 µg/L 0.180 0.500 1 01/27/23 05:07 V29218MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 01/27/23 05:07 V29218MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 01/27/23 05:07 V29218MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 01/27/23 05:07 V29218MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 01/27/23 05:07 V29218MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 01/27/23 05:07 V29218MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 01/27/23 05:07 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 18 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-4
98092 Matrix:
1/16/2023 11:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 01/27/23 05:07 V29218MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 01/27/23 05:07 V29218
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 19 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-5
98093 Matrix:
1/16/2023 12:21
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00 V29274 01/27/23 09:00
29.4 µg/L 1.80 10.0Acetone 1 01/27/23 05:32 V29218MSA
8.99 µg/L 0.180 0.500Benzene 1 01/27/23 05:32 V29218MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 01/27/23 05:32 V29218MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 01/27/23 05:32 V29218MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 01/27/23 05:32 V29218MSA
<1.50 µg/L 1.50 5.00Bromoform 1 01/27/23 05:32 V29218MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 01/27/23 05:32 V29218MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 01/27/23 05:32 V29218MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 01/27/23 05:32 V29218MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 01/27/23 05:32 V29218MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 01/27/23 05:32 V29218MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 01/27/23 05:32 V29218MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 01/27/23 05:32 V29218MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 01/27/23 05:32 V29218MSA
<0.220 µg/L 0.220 0.500Chloroform 1 01/27/23 05:32 V29218MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 01/27/23 05:32 V29218MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 01/27/23 05:32 V29218MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 01/27/23 05:32 V29218MSA
28.7 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 01/27/23 05:32 V29218MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 01/27/23 05:32 V29218MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 01/27/23 05:32 V29218MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 01/27/23 05:32 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 20 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-5
98093 Matrix:
1/16/2023 12:21
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00 V29274 01/27/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 01/27/23 05:32 V29218MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 01/27/23 05:32 V29218MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 01/27/23 05:32 V29218MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 01/27/23 05:32 V29218MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 01/27/23 05:32 V29218MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 01/27/23 05:32 V29218MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 01/27/23 05:32 V29218MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 01/27/23 05:32 V29218MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 01/27/23 05:32 V29218MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 01/27/23 05:32 V29218MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 01/27/23 05:32 V29218MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 01/27/23 05:32 V29218MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 01/27/23 05:32 V29218MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 01/27/23 05:32 V29218MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 01/27/23 05:32 V29218MSA
<42.0 µg/L 42.0 200Ethanol 1 01/27/23 05:32 V29218MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 01/27/23 05:32 V29218MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 01/27/23 05:32 V29218MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 01/27/23 05:32 V29218MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 01/27/23 05:32 V29218MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 01/27/23 05:32 V29218MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 01/27/23 05:32 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 21 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-5
98093 Matrix:
1/16/2023 12:21
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00 V29274 01/27/23 09:00
247 µg/L 1.40 10.0Methyl tert-butyl ether (MTBE)10 01/28/23 08:23 V29281ENM
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 01/27/23 05:32 V29218MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 01/27/23 05:32 V29218MSA
0.494 J µg/L 0.470 1.00Naphthalene 1 01/27/23 05:32 V29218MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 01/27/23 05:32 V29218MSA
<0.220 µg/L 0.220 0.500Styrene 1 01/27/23 05:32 V29218MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 01/27/23 05:32 V29218MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 01/27/23 05:32 V29218MSA
<0.220 µg/L 0.220 0.500 1 01/27/23 05:32 V29218MSA
0.359 J µg/L 0.220 0.500 1 01/27/23 05:32 V29218MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 01/27/23 05:32 V29218MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 01/27/23 05:32 V29218MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 01/27/23 05:32 V29218MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 01/27/23 05:32 V29218MSA
<0.180 µg/L 0.180 0.500 1 01/27/23 05:32 V29218MSA
<0.180 µg/L 0.180 0.500 1 01/27/23 05:32 V29218MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 01/27/23 05:32 V29218MSA
0.227 J µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 01/27/23 05:32 V29218MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 01/27/23 05:32 V29218MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 01/27/23 05:32 V29218MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 01/27/23 05:32 V29218MSA
0.669 µg/L 0.210 0.500o-Xylene 1 01/27/23 05:32 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 22 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-5
98093 Matrix:
1/16/2023 12:21
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00 V29274 01/27/23 09:00
0.549 J µg/L 0.420 1.00m,p-Xylene 1 01/27/23 05:32 V29218MSA
1.22 J µg/L 0.210 0.500Xylene (Total)1 01/27/23 05:32 V29218
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 23 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-7
98094 Matrix:
1/16/2023 11:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<1.80 µg/L 1.80 10.0Acetone 1 01/27/23 05:56 V29218MSA
<0.180 µg/L 0.180 0.500Benzene 1 01/27/23 05:56 V29218MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 01/27/23 05:56 V29218MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 01/27/23 05:56 V29218MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 01/27/23 05:56 V29218MSA
<1.50 µg/L 1.50 5.00Bromoform 1 01/27/23 05:56 V29218MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 01/27/23 05:56 V29218MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 01/27/23 05:56 V29218MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 01/27/23 05:56 V29218MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 01/27/23 05:56 V29218MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 01/27/23 05:56 V29218MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 01/27/23 05:56 V29218MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 01/27/23 05:56 V29218MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 01/27/23 05:56 V29218MSA
<0.220 µg/L 0.220 0.500Chloroform 1 01/27/23 05:56 V29218MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 01/27/23 05:56 V29218MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 01/27/23 05:56 V29218MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 01/27/23 05:56 V29218MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 01/27/23 05:56 V29218MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 01/27/23 05:56 V29218MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 01/27/23 05:56 V29218MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 01/27/23 05:56 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 24 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-7
98094 Matrix:
1/16/2023 11:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 01/27/23 05:56 V29218MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 01/27/23 05:56 V29218MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 01/27/23 05:56 V29218MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 01/27/23 05:56 V29218MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 01/27/23 05:56 V29218MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 01/27/23 05:56 V29218MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 01/27/23 05:56 V29218MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 01/27/23 05:56 V29218MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 01/27/23 05:56 V29218MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 01/27/23 05:56 V29218MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 01/27/23 05:56 V29218MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 01/27/23 05:56 V29218MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 01/27/23 05:56 V29218MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 01/27/23 05:56 V29218MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 01/27/23 05:56 V29218MSA
<42.0 µg/L 42.0 200Ethanol 1 01/27/23 05:56 V29218MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 01/27/23 05:56 V29218MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 01/27/23 05:56 V29218MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 01/27/23 05:56 V29218MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 01/27/23 05:56 V29218MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 01/27/23 05:56 V29218MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 01/27/23 05:56 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 25 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-7
98094 Matrix:
1/16/2023 11:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 01/27/23 05:56 V29218MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 01/27/23 05:56 V29218MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 01/27/23 05:56 V29218MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 01/27/23 05:56 V29218MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 01/27/23 05:56 V29218MSA
<0.220 µg/L 0.220 0.500Styrene 1 01/27/23 05:56 V29218MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 01/27/23 05:56 V29218MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 01/27/23 05:56 V29218MSA
<0.220 µg/L 0.220 0.500 1 01/27/23 05:56 V29218MSA
<0.220 µg/L 0.220 0.500 1 01/27/23 05:56 V29218MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 01/27/23 05:56 V29218MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 01/27/23 05:56 V29218MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 01/27/23 05:56 V29218MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 01/27/23 05:56 V29218MSA
<0.180 µg/L 0.180 0.500 1 01/27/23 05:56 V29218MSA
<0.180 µg/L 0.180 0.500 1 01/27/23 05:56 V29218MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 01/27/23 05:56 V29218MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 01/27/23 05:56 V29218MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 01/27/23 05:56 V29218MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 01/27/23 05:56 V29218MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 01/27/23 05:56 V29218MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 01/27/23 05:56 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 26 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-7
98094 Matrix:
1/16/2023 11:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 01/27/23 05:56 V29218MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 01/27/23 05:56 V29218
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 27 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-8
98095 Matrix:
1/16/2023 12:31
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<1.80 µg/L 1.80 10.0Acetone 1 01/27/23 06:21 V29218MSA
<0.180 µg/L 0.180 0.500Benzene 1 01/27/23 06:21 V29218MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 01/27/23 06:21 V29218MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 01/27/23 06:21 V29218MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 01/27/23 06:21 V29218MSA
<1.50 µg/L 1.50 5.00Bromoform 1 01/27/23 06:21 V29218MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 01/27/23 06:21 V29218MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 01/27/23 06:21 V29218MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 01/27/23 06:21 V29218MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 01/27/23 06:21 V29218MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 01/27/23 06:21 V29218MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 01/27/23 06:21 V29218MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 01/27/23 06:21 V29218MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 01/27/23 06:21 V29218MSA
<0.220 µg/L 0.220 0.500Chloroform 1 01/27/23 06:21 V29218MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 01/27/23 06:21 V29218MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 01/27/23 06:21 V29218MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 01/27/23 06:21 V29218MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 01/27/23 06:21 V29218MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 01/27/23 06:21 V29218MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 01/27/23 06:21 V29218MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 01/27/23 06:21 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 28 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-8
98095 Matrix:
1/16/2023 12:31
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 01/27/23 06:21 V29218MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 01/27/23 06:21 V29218MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 01/27/23 06:21 V29218MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 01/27/23 06:21 V29218MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 01/27/23 06:21 V29218MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 01/27/23 06:21 V29218MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 01/27/23 06:21 V29218MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 01/27/23 06:21 V29218MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 01/27/23 06:21 V29218MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 01/27/23 06:21 V29218MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 01/27/23 06:21 V29218MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 01/27/23 06:21 V29218MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 01/27/23 06:21 V29218MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 01/27/23 06:21 V29218MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 01/27/23 06:21 V29218MSA
<42.0 µg/L 42.0 200Ethanol 1 01/27/23 06:21 V29218MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 01/27/23 06:21 V29218MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 01/27/23 06:21 V29218MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 01/27/23 06:21 V29218MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 01/27/23 06:21 V29218MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 01/27/23 06:21 V29218MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 01/27/23 06:21 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 29 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-8
98095 Matrix:
1/16/2023 12:31
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 01/27/23 06:21 V29218MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 01/27/23 06:21 V29218MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 01/27/23 06:21 V29218MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 01/27/23 06:21 V29218MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 01/27/23 06:21 V29218MSA
<0.220 µg/L 0.220 0.500Styrene 1 01/27/23 06:21 V29218MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 01/27/23 06:21 V29218MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 01/27/23 06:21 V29218MSA
<0.220 µg/L 0.220 0.500 1 01/27/23 06:21 V29218MSA
<0.220 µg/L 0.220 0.500 1 01/27/23 06:21 V29218MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 01/27/23 06:21 V29218MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 01/27/23 06:21 V29218MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 01/27/23 06:21 V29218MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 01/27/23 06:21 V29218MSA
<0.180 µg/L 0.180 0.500 1 01/27/23 06:21 V29218MSA
<0.180 µg/L 0.180 0.500 1 01/27/23 06:21 V29218MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 01/27/23 06:21 V29218MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 01/27/23 06:21 V29218MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 01/27/23 06:21 V29218MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 01/27/23 06:21 V29218MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 01/27/23 06:21 V29218MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 01/27/23 06:21 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 30 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-8
98095 Matrix:
1/16/2023 12:31
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 01/27/23 06:21 V29218MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 01/27/23 06:21 V29218
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 31 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-10
98096 Matrix:
1/16/2023 12:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<1.80 µg/L 1.80 10.0Acetone 1 01/27/23 06:45 V29218MSA
<0.180 µg/L 0.180 0.500Benzene 1 01/27/23 06:45 V29218MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 01/27/23 06:45 V29218MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 01/27/23 06:45 V29218MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 01/27/23 06:45 V29218MSA
<1.50 µg/L 1.50 5.00Bromoform 1 01/27/23 06:45 V29218MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 01/27/23 06:45 V29218MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 01/27/23 06:45 V29218MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 01/27/23 06:45 V29218MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 01/27/23 06:45 V29218MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 01/27/23 06:45 V29218MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 01/27/23 06:45 V29218MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 01/27/23 06:45 V29218MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 01/27/23 06:45 V29218MSA
<0.220 µg/L 0.220 0.500Chloroform 1 01/27/23 06:45 V29218MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 01/27/23 06:45 V29218MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 01/27/23 06:45 V29218MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 01/27/23 06:45 V29218MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 01/27/23 06:45 V29218MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 01/27/23 06:45 V29218MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 01/27/23 06:45 V29218MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 01/27/23 06:45 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 32 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-10
98096 Matrix:
1/16/2023 12:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 01/27/23 06:45 V29218MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 01/27/23 06:45 V29218MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 01/27/23 06:45 V29218MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 01/27/23 06:45 V29218MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 01/27/23 06:45 V29218MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 01/27/23 06:45 V29218MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 01/27/23 06:45 V29218MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 01/27/23 06:45 V29218MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 01/27/23 06:45 V29218MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 01/27/23 06:45 V29218MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 01/27/23 06:45 V29218MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 01/27/23 06:45 V29218MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 01/27/23 06:45 V29218MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 01/27/23 06:45 V29218MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 01/27/23 06:45 V29218MSA
<42.0 µg/L 42.0 200Ethanol 1 01/27/23 06:45 V29218MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 01/27/23 06:45 V29218MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 01/27/23 06:45 V29218MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 01/27/23 06:45 V29218MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 01/27/23 06:45 V29218MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 01/27/23 06:45 V29218MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 01/27/23 06:45 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 33 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-10
98096 Matrix:
1/16/2023 12:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 01/27/23 06:45 V29218MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 01/27/23 06:45 V29218MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 01/27/23 06:45 V29218MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 01/27/23 06:45 V29218MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 01/27/23 06:45 V29218MSA
<0.220 µg/L 0.220 0.500Styrene 1 01/27/23 06:45 V29218MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 01/27/23 06:45 V29218MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 01/27/23 06:45 V29218MSA
<0.220 µg/L 0.220 0.500 1 01/27/23 06:45 V29218MSA
<0.220 µg/L 0.220 0.500 1 01/27/23 06:45 V29218MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 01/27/23 06:45 V29218MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 01/27/23 06:45 V29218MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 01/27/23 06:45 V29218MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 01/27/23 06:45 V29218MSA
<0.180 µg/L 0.180 0.500 1 01/27/23 06:45 V29218MSA
<0.180 µg/L 0.180 0.500 1 01/27/23 06:45 V29218MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 01/27/23 06:45 V29218MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 01/27/23 06:45 V29218MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 01/27/23 06:45 V29218MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 01/27/23 06:45 V29218MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 01/27/23 06:45 V29218MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 01/27/23 06:45 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 34 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-10
98096 Matrix:
1/16/2023 12:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 01/27/23 06:45 V29218MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 01/27/23 06:45 V29218
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 35 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-11
98097 Matrix:
1/16/2023 12:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<1.80 µg/L 1.80 10.0Acetone 1 01/27/23 07:10 V29218MSA
0.432 J µg/L 0.180 0.500Benzene 1 01/27/23 07:10 V29218MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 01/27/23 07:10 V29218MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 01/27/23 07:10 V29218MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 01/27/23 07:10 V29218MSA
<1.50 µg/L 1.50 5.00Bromoform 1 01/27/23 07:10 V29218MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 01/27/23 07:10 V29218MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 01/27/23 07:10 V29218MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 01/27/23 07:10 V29218MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 01/27/23 07:10 V29218MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 01/27/23 07:10 V29218MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 01/27/23 07:10 V29218MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 01/27/23 07:10 V29218MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 01/27/23 07:10 V29218MSA
<0.220 µg/L 0.220 0.500Chloroform 1 01/27/23 07:10 V29218MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 01/27/23 07:10 V29218MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 01/27/23 07:10 V29218MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 01/27/23 07:10 V29218MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 01/27/23 07:10 V29218MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 01/27/23 07:10 V29218MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 01/27/23 07:10 V29218MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 01/27/23 07:10 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 36 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-11
98097 Matrix:
1/16/2023 12:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 01/27/23 07:10 V29218MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 01/27/23 07:10 V29218MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 01/27/23 07:10 V29218MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 01/27/23 07:10 V29218MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 01/27/23 07:10 V29218MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 01/27/23 07:10 V29218MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 01/27/23 07:10 V29218MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 01/27/23 07:10 V29218MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 01/27/23 07:10 V29218MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 01/27/23 07:10 V29218MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 01/27/23 07:10 V29218MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 01/27/23 07:10 V29218MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 01/27/23 07:10 V29218MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 01/27/23 07:10 V29218MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 01/27/23 07:10 V29218MSA
<42.0 µg/L 42.0 200Ethanol 1 01/27/23 07:10 V29218MSA
0.339 J µg/L 0.170 0.500Ethylbenzene 1 01/27/23 07:10 V29218MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 01/27/23 07:10 V29218MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 01/27/23 07:10 V29218MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 01/27/23 07:10 V29218MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 01/27/23 07:10 V29218MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 01/27/23 07:10 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 37 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-11
98097 Matrix:
1/16/2023 12:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
0.278 J µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 01/27/23 07:10 V29218MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 01/27/23 07:10 V29218MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 01/27/23 07:10 V29218MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 01/27/23 07:10 V29218MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 01/27/23 07:10 V29218MSA
<0.220 µg/L 0.220 0.500Styrene 1 01/27/23 07:10 V29218MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 01/27/23 07:10 V29218MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 01/27/23 07:10 V29218MSA
<0.220 µg/L 0.220 0.500 1 01/27/23 07:10 V29218MSA
0.507 µg/L 0.220 0.500 1 01/27/23 07:10 V29218MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 01/27/23 07:10 V29218MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 01/27/23 07:10 V29218MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 01/27/23 07:10 V29218MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 01/27/23 07:10 V29218MSA
<0.180 µg/L 0.180 0.500 1 01/27/23 07:10 V29218MSA
<0.180 µg/L 0.180 0.500 1 01/27/23 07:10 V29218MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 01/27/23 07:10 V29218MSA
0.692 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 01/27/23 07:10 V29218MSA
0.233 J µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 01/27/23 07:10 V29218MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 01/27/23 07:10 V29218MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 01/27/23 07:10 V29218MSA
0.470 J µg/L 0.210 0.500o-Xylene 1 01/27/23 07:10 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 38 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-11
98097 Matrix:
1/16/2023 12:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
1.22 µg/L 0.420 1.00m,p-Xylene 1 01/27/23 07:10 V29218MSA
1.69 J µg/L 0.210 0.500Xylene (Total)1 01/27/23 07:10 V29218
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 39 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-X
98098 Matrix:
1/16/2023 12:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<1.80 µg/L 1.80 10.0Acetone 1 01/27/23 07:34 V29218MSA
<0.180 µg/L 0.180 0.500Benzene 1 01/27/23 07:34 V29218MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 01/27/23 07:34 V29218MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 01/27/23 07:34 V29218MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 01/27/23 07:34 V29218MSA
<1.50 µg/L 1.50 5.00Bromoform 1 01/27/23 07:34 V29218MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 01/27/23 07:34 V29218MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 01/27/23 07:34 V29218MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 01/27/23 07:34 V29218MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 01/27/23 07:34 V29218MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 01/27/23 07:34 V29218MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 01/27/23 07:34 V29218MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 01/27/23 07:34 V29218MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 01/27/23 07:34 V29218MSA
<0.220 µg/L 0.220 0.500Chloroform 1 01/27/23 07:34 V29218MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 01/27/23 07:34 V29218MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 01/27/23 07:34 V29218MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 01/27/23 07:34 V29218MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 01/27/23 07:34 V29218MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 01/27/23 07:34 V29218MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 01/27/23 07:34 V29218MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 01/27/23 07:34 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 40 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-X
98098 Matrix:
1/16/2023 12:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 01/27/23 07:34 V29218MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 01/27/23 07:34 V29218MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 01/27/23 07:34 V29218MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 01/27/23 07:34 V29218MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 01/27/23 07:34 V29218MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 01/27/23 07:34 V29218MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 01/27/23 07:34 V29218MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 01/27/23 07:34 V29218MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 01/27/23 07:34 V29218MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 01/27/23 07:34 V29218MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 01/27/23 07:34 V29218MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 01/27/23 07:34 V29218MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 01/27/23 07:34 V29218MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 01/27/23 07:34 V29218MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 01/27/23 07:34 V29218MSA
<42.0 µg/L 42.0 200Ethanol 1 01/27/23 07:34 V29218MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 01/27/23 07:34 V29218MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 01/27/23 07:34 V29218MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 01/27/23 07:34 V29218MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 01/27/23 07:34 V29218MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 01/27/23 07:34 V29218MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 01/27/23 07:34 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 41 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-X
98098 Matrix:
1/16/2023 12:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 01/27/23 07:34 V29218MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 01/27/23 07:34 V29218MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 01/27/23 07:34 V29218MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 01/27/23 07:34 V29218MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 01/27/23 07:34 V29218MSA
<0.220 µg/L 0.220 0.500Styrene 1 01/27/23 07:34 V29218MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 01/27/23 07:34 V29218MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 01/27/23 07:34 V29218MSA
<0.220 µg/L 0.220 0.500 1 01/27/23 07:34 V29218MSA
0.554 µg/L 0.220 0.500 1 01/27/23 07:34 V29218MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 01/27/23 07:34 V29218MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 01/27/23 07:34 V29218MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 01/27/23 07:34 V29218MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 01/27/23 07:34 V29218MSA
<0.180 µg/L 0.180 0.500 1 01/27/23 07:34 V29218MSA
<0.180 µg/L 0.180 0.500 1 01/27/23 07:34 V29218MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 01/27/23 07:34 V29218MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 01/27/23 07:34 V29218MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 01/27/23 07:34 V29218MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 01/27/23 07:34 V29218MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 01/27/23 07:34 V29218MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 01/27/23 07:34 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 42 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-X
98098 Matrix:
1/16/2023 12:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 01/27/23 07:34 V29218MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 01/27/23 07:34 V29218
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 43 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-12
98099 Matrix:
1/16/2023 15:50
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
See Attached mg/L 0.006Lead 1 6010DBKN
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 44 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-12
98099 Matrix:
1/16/2023 15:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<1.80 µg/L 1.80 10.0Acetone 1 01/27/23 07:59 V29218MSA
<0.180 µg/L 0.180 0.500Benzene 1 01/27/23 07:59 V29218MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 01/27/23 07:59 V29218MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 01/27/23 07:59 V29218MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 01/27/23 07:59 V29218MSA
<1.50 µg/L 1.50 5.00Bromoform 1 01/27/23 07:59 V29218MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 01/27/23 07:59 V29218MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 01/27/23 07:59 V29218MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 01/27/23 07:59 V29218MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 01/27/23 07:59 V29218MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 01/27/23 07:59 V29218MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 01/27/23 07:59 V29218MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 01/27/23 07:59 V29218MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 01/27/23 07:59 V29218MSA
<0.220 µg/L 0.220 0.500Chloroform 1 01/27/23 07:59 V29218MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 01/27/23 07:59 V29218MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 01/27/23 07:59 V29218MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 01/27/23 07:59 V29218MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 01/27/23 07:59 V29218MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 01/27/23 07:59 V29218MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 01/27/23 07:59 V29218MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 01/27/23 07:59 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 45 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-12
98099 Matrix:
1/16/2023 15:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 01/27/23 07:59 V29218MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 01/27/23 07:59 V29218MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 01/27/23 07:59 V29218MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 01/27/23 07:59 V29218MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 01/27/23 07:59 V29218MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 01/27/23 07:59 V29218MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 01/27/23 07:59 V29218MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 01/27/23 07:59 V29218MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 01/27/23 07:59 V29218MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 01/27/23 07:59 V29218MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 01/27/23 07:59 V29218MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 01/27/23 07:59 V29218MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 01/27/23 07:59 V29218MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 01/27/23 07:59 V29218MSA
<42.0 µg/L 42.0 200Ethanol 1 01/27/23 07:59 V29218MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 01/27/23 07:59 V29218MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 01/27/23 07:59 V29218MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 01/27/23 07:59 V29218MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 01/27/23 07:59 V29218MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 01/27/23 07:59 V29218MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 01/27/23 07:59 V29218MSA
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 01/27/23 07:59 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 46 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-12
98099 Matrix:
1/16/2023 15:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 01/27/23 07:59 V29218MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 01/27/23 07:59 V29218MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 01/27/23 07:59 V29218MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 01/27/23 07:59 V29218MSA
<0.220 µg/L 0.220 0.500Styrene 1 01/27/23 07:59 V29218MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 01/27/23 07:59 V29218MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 01/27/23 07:59 V29218MSA
<0.220 µg/L 0.220 0.500 1 01/27/23 07:59 V29218MSA
<0.220 µg/L 0.220 0.500 1 01/27/23 07:59 V29218MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 01/27/23 07:59 V29218MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 01/27/23 07:59 V29218MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 01/27/23 07:59 V29218MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 01/27/23 07:59 V29218MSA
<0.180 µg/L 0.180 0.500 1 01/27/23 07:59 V29218MSA
<0.180 µg/L 0.180 0.500 1 01/27/23 07:59 V29218MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 01/27/23 07:59 V29218MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 01/27/23 07:59 V29218MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 01/27/23 07:59 V29218MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 01/27/23 07:59 V29218MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 01/27/23 07:59 V29218MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 01/27/23 07:59 V29218MSA
<0.420 µg/L 0.420 1.00m,p-Xylene 1 01/27/23 07:59 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 47 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-12
98099 Matrix:
1/16/2023 15:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<0.21 µg/L 0.210 0.500Xylene (Total)1 01/27/23 07:59 V29218KCC
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):01/23/23 09:08
<0.336 µg/L 0.336 2.23Acenaphthene 1 01/23/23 17:14 V29124JMV
<0.331 µg/L 0.331 2.23Acenaphthylene 1 01/23/23 17:14 V29124JMV
<0.932 µg/L 0.932 2.23Anthracene 1 01/23/23 17:14 V29124JMV
<1.48 µg/L 1.48 11.2Benzidine 1 01/23/23 17:14 V29124JMV
<0.710 µg/L 0.710 2.23Benzo(a)anthracene 1 01/23/23 17:14 V29124JMV
<1.14 µg/L 1.14 2.23Benzo(a)pyrene 1 01/23/23 17:14 V29124JMV
<2.78 µg/L 2.78 5.59Benzo(b)fluoranthene 1 01/23/23 17:14 V29124JMV
<1.13 µg/L 1.13 5.59Benzo(g,h,i)perylene 1 01/23/23 17:14 V29124JMV
<2.22 µg/L 2.22 5.59Benzo(k)fluoranthene 1 01/23/23 17:14 V29124JMV
2.29 J µg/L 1.23 11.2Benzoic Acid 1 01/23/23 17:14 V29124JMV
1.17 J µg/L 0.764 5.59Benzyl alcohol 1 01/23/23 17:14 V29124JMV
<0.523 µg/L 0.523 5.59Bis(2-Chloroethoxy)methane 1 01/23/23 17:14 V29124JMV
<1.16 µg/L 1.16 5.59Bis(2-Chloroethyl)ether 1 01/23/23 17:14 V29124JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 48 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-12
98099 Matrix:
1/16/2023 15:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):01/23/23 09:08
<1.21 µg/L 1.21 5.59Bis(2-Chloroisopropyl)ether 1 01/23/23 17:14 V29124JMV
<26.9 µg/L 26.9 55.9Bis(2-ethylhexyl)phthalate 1 01/23/23 17:14 V29124JMV
<1.24 µg/L 1.24 5.594-Bromophenyl phenyl ether 1 01/23/23 17:14 V29124JMV
<2.05 µg/L 2.05 5.59Butyl benzyl phthalate 1 01/23/23 17:14 V29124JMV
<1.32 µg/L 1.32 5.594-Chloro-3-methylphenol 1 01/23/23 17:14 V29124JMV
<8.23 µg/L 8.23 22.32-Chloronaphthalene 1 01/23/23 17:14 V29124JMV
<1.05 µg/L 1.05 11.22-Chlorophenol 1 01/23/23 17:14 V29124JMV
<1.91 µg/L 1.91 5.594-Chlorophenyl phenyl ether 1 01/23/23 17:14 V29124JMV
<0.451 µg/L 0.451 2.23Chrysene 1 01/23/23 17:14 V29124JMV
<0.483 µg/L 0.483 2.23Dibenz(a,h)anthracene 1 01/23/23 17:14 V29124JMV
<0.957 µg/L 0.957 5.59Dibenzofuran 1 01/23/23 17:14 V29124JMV
<2.24 µg/L 2.24 5.591,2-Dichlorobenzene 1 01/23/23 17:14 V29124JMV
<2.24 µg/L 2.24 5.591,3-Dichlorobenzene 1 01/23/23 17:14 V29124JMV
<2.29 µg/L 2.29 5.591,4-Dichlorobenzene 1 01/23/23 17:14 V29124JMV
<2.11 µg/L 2.11 5.593,3'-Dichlorobenzidine 1 01/23/23 17:14 V29124JMV
<1.64 µg/L 1.64 11.22,4-Dichlorophenol 1 01/23/23 17:14 V29124JMV
<0.832 µg/L 0.832 5.59Diethyl phthalate 1 01/23/23 17:14 V29124JMV
<1.05 µg/L 1.05 5.59Dimethyl phthalate 1 01/23/23 17:14 V29124JMV
<1.75 µg/L 1.75 22.32,4-Dimethylphenol 1 01/23/23 17:14 V29124JMV
<2.30 µg/L 2.30 5.59Di-n-butyl phthalate 1 01/23/23 17:14 V29124JMV
<2.32 µg/L 2.32 11.24,6-Dinitro-2-methylphenol 1 01/23/23 17:14 V29124JMV
<2.15 µg/L 2.15 11.22,4-Dinitrophenol 1 01/23/23 17:14 V29124JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 49 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-12
98099 Matrix:
1/16/2023 15:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):01/23/23 09:08
<1.24 µg/L 1.24 5.592,4-Dinitrotoluene 1 01/23/23 17:14 V29124JMV
<0.904 µg/L 0.904 5.592,6-Dinitrotoluene 1 01/23/23 17:14 V29124JMV
<1.84 µg/L 1.84 5.59Di-n-Octyl Phthalate 1 01/23/23 17:14 V29124JMV
<0.278 µg/L 0.278 2.23Fluoranthene 1 01/23/23 17:14 V29124JMV
<0.899 µg/L 0.899 2.23Fluorene 1 01/23/23 17:14 V29124JMV
<1.09 µg/L 1.09 5.59Hexachlorobenzene 1 01/23/23 17:14 V29124JMV
<3.05 µg/L 3.05 5.59Hexachlorobutadiene 1 01/23/23 17:14 V29124JMV
<2.29 µg/L 2.29 5.59Hexachlorocyclopentadiene 1 01/23/23 17:14 V29124JMV
<1.97 µg/L 1.97 5.59Hexachloroethane 1 01/23/23 17:14 V29124JMV
<0.531 µg/L 0.531 2.23Indeno(1,2,3-cd)pyrene 1 01/23/23 17:14 V29124JMV
<0.496 µg/L 0.496 5.59Isophorone 1 01/23/23 17:14 V29124JMV
<1.27 µg/L 1.27 2.231-Methylnaphthalene 1 01/23/23 17:14 V29124JMV
<0.742 µg/L 0.742 2.232-Methylnaphthalene 1 01/23/23 17:14 V29124JMV
<0.811 µg/L 0.811 2.23Naphthalene 1 01/23/23 17:14 V29124JMV
<1.01 µg/L 1.01 5.59Nitrobenzene 1 01/23/23 17:14 V29124JMV
<0.551 µg/L 0.551 5.592-Nitrophenol 1 01/23/23 17:14 V29124JMV
<1.38 µg/L 1.38 11.24-Nitrophenol 1 01/23/23 17:14 V29124JMV
<1.23 µg/L 1.23 5.59N-Nitrosodiphenylamine 1 01/23/23 17:14 V29124JMV
<0.716 µg/L 0.716 5.59N-Nitroso-di-n-propylamine 1 01/23/23 17:14 V29124JMV
<1.60 µg/L 1.60 5.59Pentachlorophenol 1 01/23/23 17:14 V29124JMV
<0.477 µg/L 0.477 2.23Phenanthrene 1 01/23/23 17:14 V29124JMV
<0.727 µg/L 0.727 5.59Phenol 1 01/23/23 17:14 V29124JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 50 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-12
98099 Matrix:
1/16/2023 15:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):01/23/23 09:08
<0.483 µg/L 0.483 2.23Pyrene 1 01/23/23 17:14 V29124JMV
<2.47 µg/L 2.47 5.591,2,4-Trichlorobenzene 1 01/23/23 17:14 V29124JMV
<1.48 µg/L 1.48 5.592,4,6-Trichlorophenol 1 01/23/23 17:14 V29124JMV
Surrogate: Phenol-d5
Surrogate: 2-Fluorobiphenyl
Surrogate: 2-Fluorophenol
Surrogate: Nitrobenzene-d5
Surrogate: 4-Terphenyl-d14
Surrogate: 2,4,6-Tribromophenol
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):01/26/23 08:18
<0.0206 µg/L 0.02061,2-Dibromoethane 1 01/26/23 11:07 V29192AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 51 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-12
98099 Matrix:
1/16/2023 15:50
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 01/23/23 13:30
<25.8 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 01/23/23 13:30
<4.02 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 01/23/23 13:30
<61.4 µg/L 61.4 251Aromatic C11-C22 (Adjusted)1 01/23/23 17:14
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):01/26/23 09:00
<28.4 µg/L 28.4 352Aliphatic C9-C18 1 01/31/23 12:23 V29350AMP
<125 µg/L 125 503Aliphatic C19-C36 1 01/31/23 12:23 V29350AMP
<61.4 µg/L 61.4 251Aromatic C11-C22 1 01/31/23 12:23 V29350AMP
Surrogate: 2-Bromonaphthalene
Surrogate: Chlorooctadecane
Surrogate: OTP Surrogate
Surrogate: 2-Fluorobiphenyl
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):01/23/23 08:00
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 01/23/23 13:30 V29084TBL
<25.8 µg/L 25.8 50.0Aliphatic C9-C12 1 01/23/23 13:30 V29084TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 52 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-12
98099 Matrix:
1/16/2023 15:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):01/23/23 08:00
<4.02 µg/L 4.02 50.0Aromatic C9-C10 1 01/23/23 13:30 V29084TBL
Surrogate: 2,5-Dibromotoluene (FID)
Surrogate: 2,5-Dibromotoluene (PID)
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 53 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-13
98100 Matrix:
1/16/2023 16:10
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
See Attached mg/L 0.006Lead 1 6010DBKN
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 54 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-13
98100 Matrix:
1/16/2023 16:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00 V29274 01/27/23 09:00
<180 µg/L 180 1000Acetone 100 01/27/23 11:15 V29218MSA
8510 µg/L 18.0 50.0Benzene 100 01/27/23 11:15 V29218MSA
<21.0 µg/L 21.0 50.0Bromobenzene 100 01/27/23 11:15 V29218MSA
<42.0 µg/L 42.0 100Bromochloromethane 100 01/27/23 11:15 V29218MSA
<16.0 µg/L 16.0 50.0Bromodichloromethane 100 01/27/23 11:15 V29218MSA
<150 µg/L 150 500Bromoform 100 01/27/23 11:15 V29218MSA
<28.0 µg/L 28.0 100Bromomethane 100 01/27/23 11:15 V29218MSA
<18.0 µg/L 18.0 50.0n-Butylbenzene 100 01/27/23 11:15 V29218MSA
<20.0 µg/L 20.0 50.0sec-Butyl benzene 100 01/27/23 11:15 V29218MSA
<92.0 µg/L 92.0 200tert-Butyl benzene 100 01/27/23 11:15 V29218MSA
<18.0 µg/L 18.0 50.0Carbon Tetrachloride 100 01/27/23 11:15 V29218MSA
<19.0 µg/L 19.0 50.0Chlorobenzene 100 01/27/23 11:15 V29218MSA
<19.0 µg/L 19.0 50.0Chlorodibromomethane 100 01/27/23 11:15 V29218MSA
<43.0 µg/L 43.0 100Chloroethane 100 01/27/23 11:15 V29218MSA
<22.0 µg/L 22.0 50.0Chloroform 100 01/27/23 11:15 V29218MSA
<22.0 µg/L 22.0 50.0Chloromethane 100 01/27/23 11:15 V29218MSA
<20.0 µg/L 20.0 50.02-Chlorotoluene 100 01/27/23 11:15 V29218MSA
<20.0 µg/L 20.0 50.04-Chlorotoluene 100 01/27/23 11:15 V29218MSA
53.6 µg/L 50.0 50.0Di-Isopropyl Ether (DIPE)100 01/27/23 11:15 V29218MSA
<110 µg/L 110 2001,2-Dibromo-3-Chloropropane 100 01/27/23 11:15 V29218MSA
<23.0 µg/L 23.0 50.0Dibromomethane 100 01/27/23 11:15 V29218MSA
<22.0 µg/L 22.0 50.01,2-Dichlorobenzene 100 01/27/23 11:15 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 55 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-13
98100 Matrix:
1/16/2023 16:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00 V29274 01/27/23 09:00
<19.0 µg/L 19.0 50.01,3-Dichlorobenzene 100 01/27/23 11:15 V29218MSA
<21.0 µg/L 21.0 50.01,4-Dichlorobenzene 100 01/27/23 11:15 V29218MSA
<120 µg/L 120 500Dichlorodifluoromethane 100 01/27/23 11:15 V29218MSA
<24.0 µg/L 24.0 50.01,1-Dichloroethane 100 01/27/23 11:15 V29218MSA
<15.0 µg/L 15.0 50.01,2-Dichloroethane 100 01/27/23 11:15 V29218MSA
<15.0 µg/L 15.0 50.01,1-Dichloroethene 100 01/27/23 11:15 V29218MSA
<20.0 µg/L 20.0 50.0cis-1,2-Dichloroethene 100 01/27/23 11:15 V29218MSA
<18.0 µg/L 18.0 50.0trans-1,2-Dichloroethene 100 01/27/23 11:15 V29218MSA
<19.0 µg/L 19.0 50.01,2-Dichloropropane 100 01/27/23 11:15 V29218MSA
<13.0 µg/L 13.0 50.01,3-Dichloropropane 100 01/27/23 11:15 V29218MSA
<21.0 µg/L 21.0 2002,2-Dichloropropane 100 01/27/23 11:15 V29218MSA
<20.0 µg/L 20.0 50.01,1-Dichloropropene 100 01/27/23 11:15 V29218MSA
<21.0 µg/L 21.0 50.0cis-1,3-Dichloropropene 100 01/27/23 11:15 V29218MSA
<15.0 µg/L 15.0 50.0trans-1,3-Dichloropropene 100 01/27/23 11:15 V29218MSA
<4200 µg/L 4200 20000Ethanol 100 01/27/23 11:15 V29218MSA
2750 µg/L 17.0 50.0Ethylbenzene 100 01/27/23 11:15 V29218MSA
<35.0 µg/L 35.0 300Hexachlorobutadiene 100 01/27/23 11:15 V29218MSA
193 µg/L 38.0 1002-Hexanone 100 01/27/23 11:15 V29218MSA
117 µg/L 18.0 50.0Isopropylbenzene 100 01/27/23 11:15 V29218MSA
<8.90 µg/L 8.90 50.04-Isopropyl toluene 100 01/27/23 11:15 V29218MSA
<71.0 µg/L 71.0 500Methyl Ethyl Ketone (MEK)100 01/27/23 11:15 V29218MSA
1040 µg/L 14.0 100Methyl tert-butyl ether (MTBE)100 01/27/23 11:15 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 56 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-13
98100 Matrix:
1/16/2023 16:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00 V29274 01/27/23 09:00
102 µg/L 7.80 1004-Methyl-2-Pentanone 100 01/27/23 11:15 V29218MSA
<33.0 µg/L 33.0 200Methylene Chloride 100 01/27/23 11:15 V29218MSA
642 µg/L 47.0 100Naphthalene 100 01/27/23 11:15 V29218MSA
286 µg/L 19.0 50.0n-Propylbenzene 100 01/27/23 11:15 V29218MSA
<22.0 µg/L 22.0 50.0Styrene 100 01/27/23 11:15 V29218MSA
<16.0 µg/L 16.0 50.01,1,1,2-Tetrachloroethane 100 01/27/23 11:15 V29218MSA
<16.0 µg/L 16.0 50.01,1,2,2-Tetrachloroethane 100 01/27/23 11:15 V29218MSA
<22.0 µg/L 22.0 50.0 100 01/27/23 11:15 V29218MSA
48100 µg/L 220 500 1000 01/28/23 10:25 V29281ENM
<38.0 µg/L 38.0 50.01,2,3-Trichlorobenzene 100 01/27/23 11:15 V29218MSA
<31.0 µg/L 31.0 50.01,2,4-Trichlorobenzene 100 01/27/23 11:15 V29218MSA
<16.0 µg/L 16.0 50.01,1,1-Trichloroethane 100 01/27/23 11:15 V29218MSA
<9.60 µg/L 9.60 50.01,1,2-Trichloroethane 100 01/27/23 11:15 V29218MSA
<18.0 µg/L 18.0 50.0 100 01/27/23 11:15 V29218MSA
<18.0 µg/L 18.0 50.0 100 01/27/23 11:15 V29218MSA
<27.0 µg/L 27.0 50.01,2,3-Trichloropropane 100 01/27/23 11:15 V29218MSA
2150 µg/L 19.0 50.01,2,4-Trimethylbenzene 100 01/27/23 11:15 V29218MSA
530 µg/L 18.0 50.01,3,5-Trimethylbenzene 100 01/27/23 11:15 V29218MSA
<100 µg/L 100 500Vinyl Acetate 100 01/27/23 11:15 V29218MSA
<17.0 µg/L 17.0 50.0Vinyl Chloride 100 01/27/23 11:15 V29218MSA
4380 µg/L 21.0 50.0o-Xylene 100 01/27/23 11:15 V29218MSA
9270 µg/L 42.0 100m,p-Xylene 100 01/27/23 11:15 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 57 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-13
98100 Matrix:
1/16/2023 16:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00 V29274 01/27/23 09:00
13700 µg/L 21.0 50.0Xylene (Total)100 01/27/23 11:15 V29218KCC
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):01/23/23 09:08
<0.321 µg/L 0.321 2.13Acenaphthene 1 01/23/23 17:37 V29124JMV
<0.316 µg/L 0.316 2.13Acenaphthylene 1 01/23/23 17:37 V29124JMV
<0.890 µg/L 0.890 2.13Anthracene 1 01/23/23 17:37 V29124JMV
<1.40 µg/L 1.40 10.6Benzidine 1 01/23/23 17:37 V29124JMV
<0.678 µg/L 0.678 2.13Benzo(a)anthracene 1 01/23/23 17:37 V29124JMV
<1.09 µg/L 1.09 2.13Benzo(a)pyrene 1 01/23/23 17:37 V29124JMV
<2.65 µg/L 2.65 5.32Benzo(b)fluoranthene 1 01/23/23 17:37 V29124JMV
<1.07 µg/L 1.07 5.32Benzo(g,h,i)perylene 1 01/23/23 17:37 V29124JMV
<2.12 µg/L 2.12 5.32Benzo(k)fluoranthene 1 01/23/23 17:37 V29124JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 58 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-13
98100 Matrix:
1/16/2023 16:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):01/23/23 09:08
<1.17 µg/L 1.17 10.6Benzoic Acid 1 01/23/23 17:37 V29124JMV
<0.727 µg/L 0.727 5.32Benzyl alcohol 1 01/23/23 17:37 V29124JMV
<0.497 µg/L 0.497 5.32Bis(2-Chloroethoxy)methane 1 01/23/23 17:37 V29124JMV
<1.11 µg/L 1.11 5.32Bis(2-Chloroethyl)ether 1 01/23/23 17:37 V29124JMV
<1.15 µg/L 1.15 5.32Bis(2-Chloroisopropyl)ether 1 01/23/23 17:37 V29124JMV
<25.6 µg/L 25.6 53.2Bis(2-ethylhexyl)phthalate 1 01/23/23 17:37 V29124JMV
<1.18 µg/L 1.18 5.324-Bromophenyl phenyl ether 1 01/23/23 17:37 V29124JMV
<1.95 µg/L 1.95 5.32Butyl benzyl phthalate 1 01/23/23 17:37 V29124JMV
<1.26 µg/L 1.26 5.324-Chloro-3-methylphenol 1 01/23/23 17:37 V29124JMV
<7.86 µg/L 7.86 21.32-Chloronaphthalene 1 01/23/23 17:37 V29124JMV
<0.994 µg/L 0.994 10.62-Chlorophenol 1 01/23/23 17:37 V29124JMV
<1.82 µg/L 1.82 5.324-Chlorophenyl phenyl ether 1 01/23/23 17:37 V29124JMV
<0.431 µg/L 0.431 2.13Chrysene 1 01/23/23 17:37 V29124JMV
<0.462 µg/L 0.462 2.13Dibenz(a,h)anthracene 1 01/23/23 17:37 V29124JMV
<0.910 µg/L 0.910 5.32Dibenzofuran 1 01/23/23 17:37 V29124JMV
<2.13 µg/L 2.13 5.321,2-Dichlorobenzene 1 01/23/23 17:37 V29124JMV
<2.13 µg/L 2.13 5.321,3-Dichlorobenzene 1 01/23/23 17:37 V29124JMV
<2.18 µg/L 2.18 5.321,4-Dichlorobenzene 1 01/23/23 17:37 V29124JMV
<2.01 µg/L 2.01 5.323,3'-Dichlorobenzidine 1 01/23/23 17:37 V29124JMV
<1.55 µg/L 1.55 10.62,4-Dichlorophenol 1 01/23/23 17:37 V29124JMV
<0.792 µg/L 0.792 5.32Diethyl phthalate 1 01/23/23 17:37 V29124JMV
<0.999 µg/L 0.999 5.32Dimethyl phthalate 1 01/23/23 17:37 V29124JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 59 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-13
98100 Matrix:
1/16/2023 16:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):01/23/23 09:08
<1.67 µg/L 1.67 21.32,4-Dimethylphenol 1 01/23/23 17:37 V29124JMV
<2.19 µg/L 2.19 5.32Di-n-butyl phthalate 1 01/23/23 17:37 V29124JMV
<2.19 µg/L 2.19 10.64,6-Dinitro-2-methylphenol 1 01/23/23 17:37 V29124JMV
<2.04 µg/L 2.04 10.62,4-Dinitrophenol 1 01/23/23 17:37 V29124JMV
<1.18 µg/L 1.18 5.322,4-Dinitrotoluene 1 01/23/23 17:37 V29124JMV
<0.860 µg/L 0.860 5.322,6-Dinitrotoluene 1 01/23/23 17:37 V29124JMV
<1.76 µg/L 1.76 5.32Di-n-Octyl Phthalate 1 01/23/23 17:37 V29124JMV
<0.266 µg/L 0.266 2.13Fluoranthene 1 01/23/23 17:37 V29124JMV
<0.859 µg/L 0.859 2.13Fluorene 1 01/23/23 17:37 V29124JMV
<1.04 µg/L 1.04 5.32Hexachlorobenzene 1 01/23/23 17:37 V29124JMV
<2.90 µg/L 2.90 5.32Hexachlorobutadiene 1 01/23/23 17:37 V29124JMV
<2.18 µg/L 2.18 5.32Hexachlorocyclopentadiene 1 01/23/23 17:37 V29124JMV
<1.87 µg/L 1.87 5.32Hexachloroethane 1 01/23/23 17:37 V29124JMV
<0.508 µg/L 0.508 2.13Indeno(1,2,3-cd)pyrene 1 01/23/23 17:37 V29124JMV
<0.472 µg/L 0.472 5.32Isophorone 1 01/23/23 17:37 V29124JMV
41.2 µg/L 1.21 2.131-Methylnaphthalene 1 01/23/23 17:37 V29124JMV
78.0 µg/L 0.709 2.132-Methylnaphthalene 1 01/23/23 17:37 V29124JMV
430 µg/L 3.10 8.51Naphthalene 4 01/24/23 11:14 V29124JMV
<0.962 µg/L 0.962 5.32Nitrobenzene 1 01/23/23 17:37 V29124JMV
<0.524 µg/L 0.524 5.322-Nitrophenol 1 01/23/23 17:37 V29124JMV
<1.30 µg/L 1.30 10.64-Nitrophenol 1 01/23/23 17:37 V29124JMV
<1.17 µg/L 1.17 5.32N-Nitrosodiphenylamine 1 01/23/23 17:37 V29124JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 60 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-13
98100 Matrix:
1/16/2023 16:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):01/23/23 09:08
<0.682 µg/L 0.682 5.32N-Nitroso-di-n-propylamine 1 01/23/23 17:37 V29124JMV
<1.52 µg/L 1.52 5.32Pentachlorophenol 1 01/23/23 17:37 V29124JMV
<0.455 µg/L 0.455 2.13Phenanthrene 1 01/23/23 17:37 V29124JMV
<0.692 µg/L 0.692 5.32Phenol 1 01/23/23 17:37 V29124JMV
<0.462 µg/L 0.462 2.13Pyrene 1 01/23/23 17:37 V29124JMV
<2.35 µg/L 2.35 5.321,2,4-Trichlorobenzene 1 01/23/23 17:37 V29124JMV
<1.40 µg/L 1.40 5.322,4,6-Trichlorophenol 1 01/23/23 17:37 V29124JMV
Surrogate: Phenol-d5
Surrogate: 2-Fluorobiphenyl
Surrogate: 2-Fluorophenol
Surrogate: Nitrobenzene-d5
Surrogate: 4-Terphenyl-d14
Surrogate: 2,4,6-Tribromophenol
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):01/26/23 08:18
<0.0209 µg/L 0.02091,2-Dibromoethane 1 01/26/23 11:43 V29192AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 61 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-13
98100 Matrix:
1/16/2023 16:10
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
23200 µg/L 1150 5000Aliphatic C5-C8 (Adjusted)100 01/24/23 18:27
14600 µg/L 2580 5000Aliphatics C9-C12 (Adjusted)100 01/24/23 18:27
5560 µg/L 402 5000Aromatic C9-C10 (Adjusted)100 01/24/23 18:27
501 µg/L 63.2 258Aromatic C11-C22 (Adjusted)1 01/23/23 17:37
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):01/26/23 09:00
<29.1 µg/L 29.1 361Aliphatic C9-C18 1 01/31/23 12:59 V29350AMP
<128 µg/L 128 515Aliphatic C19-C36 1 01/31/23 12:59 V29350AMP
931 µg/L 63.2 258Aromatic C11-C22 1 01/31/23 12:59 V29350AMP
Surrogate: 2-Bromonaphthalene
Surrogate: Chlorooctadecane
Surrogate: OTP Surrogate
Surrogate: 2-Fluorobiphenyl
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):01/24/23 08:00
79800 µg/L 1150 5000Aliphatic C5-C8 100 01/24/23 18:27 V29105TBL
36600 µg/L 2580 5000Aliphatic C9-C12 100 01/24/23 18:27 V29105TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 62 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:MW-13
98100 Matrix:
1/16/2023 16:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):01/24/23 08:00
5560 µg/L 402 5000Aromatic C9-C10 100 01/24/23 18:27 V29105TBL
Surrogate: 2,5-Dibromotoluene (FID)
Surrogate: 2,5-Dibromotoluene (PID)
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 63 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:TB
98101 Matrix:
1/16/2023 0:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<1.80 µg/L 1.80 10.0Acetone 1 01/27/23 04:18 V29218MSA
<0.180 µg/L 0.180 0.500Benzene 1 01/27/23 04:18 V29218MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 01/27/23 04:18 V29218MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 01/27/23 04:18 V29218MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 01/27/23 04:18 V29218MSA
<1.50 µg/L 1.50 5.00Bromoform 1 01/27/23 04:18 V29218MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 01/27/23 04:18 V29218MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 01/27/23 04:18 V29218MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 01/27/23 04:18 V29218MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 01/27/23 04:18 V29218MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 01/27/23 04:18 V29218MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 01/27/23 04:18 V29218MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 01/27/23 04:18 V29218MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 01/27/23 04:18 V29218MSA
<0.220 µg/L 0.220 0.500Chloroform 1 01/27/23 04:18 V29218MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 01/27/23 04:18 V29218MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 01/27/23 04:18 V29218MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 01/27/23 04:18 V29218MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 01/27/23 04:18 V29218MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 01/27/23 04:18 V29218MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 01/27/23 04:18 V29218MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 01/27/23 04:18 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 64 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:TB
98101 Matrix:
1/16/2023 0:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 01/27/23 04:18 V29218MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 01/27/23 04:18 V29218MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 01/27/23 04:18 V29218MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 01/27/23 04:18 V29218MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 01/27/23 04:18 V29218MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 01/27/23 04:18 V29218MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 01/27/23 04:18 V29218MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 01/27/23 04:18 V29218MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 01/27/23 04:18 V29218MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 01/27/23 04:18 V29218MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 01/27/23 04:18 V29218MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 01/27/23 04:18 V29218MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 01/27/23 04:18 V29218MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 01/27/23 04:18 V29218MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 01/27/23 04:18 V29218MSA
<42.0 µg/L 42.0 200Ethanol 1 01/27/23 04:18 V29218MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 01/27/23 04:18 V29218MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 01/27/23 04:18 V29218MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 01/27/23 04:18 V29218MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 01/27/23 04:18 V29218MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 01/27/23 04:18 V29218MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 01/27/23 04:18 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 65 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:TB
98101 Matrix:
1/16/2023 0:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 01/27/23 04:18 V29218MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 01/27/23 04:18 V29218MSA
0.402 J µg/L 0.330 2.00Methylene Chloride 1 01/27/23 04:18 V29218MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 01/27/23 04:18 V29218MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 01/27/23 04:18 V29218MSA
<0.220 µg/L 0.220 0.500Styrene 1 01/27/23 04:18 V29218MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 01/27/23 04:18 V29218MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 01/27/23 04:18 V29218MSA
<0.220 µg/L 0.220 0.500 1 01/27/23 04:18 V29218MSA
<0.220 µg/L 0.220 0.500 1 01/27/23 04:18 V29218MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 01/27/23 04:18 V29218MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 01/27/23 04:18 V29218MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 01/27/23 04:18 V29218MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 01/27/23 04:18 V29218MSA
<0.180 µg/L 0.180 0.500 1 01/27/23 04:18 V29218MSA
<0.180 µg/L 0.180 0.500 1 01/27/23 04:18 V29218MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 01/27/23 04:18 V29218MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 01/27/23 04:18 V29218MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 01/27/23 04:18 V29218MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 01/27/23 04:18 V29218MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 01/27/23 04:18 V29218MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 01/27/23 04:18 V29218MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 66 of 111
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-020-0019
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5888 Received : 01/20/2023
Former Philbecks Amoco
Report Date : 02/03/2023
Sample ID :
Lab No :
Sampled:TB
98101 Matrix:
1/16/2023 0:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):01/26/23 14:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 01/27/23 04:18 V29218MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 01/27/23 04:18 V29218
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 67 of 111
Sample ID Report Lab NoLRB23‐020‐0019 LRB‐V29089
Paramater Result Units
Dilution 
Factor Method Analysis Date/Time Analyst Batch ID
Toluene 31.3 ug/L 1 625.1 1/23/2023 16:05 JMV V29124
Sample ID Report Lab No
MW‐12 23‐020‐0019 V 98099
Paramater Result Units
Dilution 
Factor Method Analysis Date/Time Analyst Batch ID
Hexadecanoic Acid 29.9 ug/L 1 625.1 1/23/2023 17:14 JMV V29124
Sample ID Report Lab No
MW‐13 23‐020‐0019 V 98100
Paramater Result Units
Dilution 
Factor Method Analysis Date/Time Analyst Batch ID
Methyl Pentanol 590 ug/L 1 625.1 1/23/2023 17:37 JMV V29124
Toluene 2100 ug/L 1 625.1 1/23/2023 17:37 JMV V29124
Methyl Cyclopentanol 330 ug/L 1 625.1 1/23/2023 17:37 JMV V29124
Ethylbenzene 770 ug/L 1 625.1 1/23/2023 17:37 JMV V29124
Dimethyl Benzene 1100 ug/L 1 625.1 1/23/2023 17:37 JMV V29124
Ethyl Methyl Benzene 530 ug/L 1 625.1 1/23/2023 17:37 JMV V29124
Trimethyl Benzene 740 ug/L 1 625.1 1/23/2023 17:37 JMV V29124
Page 68 of 111
Library Search Compound Report
Data Path : S:\SMS\SMS-G\DATA\012323\
Data File : G012323-04.D
Acq On : 23 Jan 2023 16:05
Operator : JVOGEL
Sample : LRB-V29089
Misc :
ALS Vial : 3 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-G\METHOD\G011823_WAYPOINT FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: LSCINT.P
*********************************************************************
Peak Number 1 Toluene Concentration Rank 1
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
1.699 31.33 ppb 867162 1,4-Dichlorobenzene-d4 3.216
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Toluene 92 C7H8 000108-88-3 94
2 Toluene 92 C7H8 000108-88-3 91
3 Toluene 92 C7H8 000108-88-3 91
4 Toluene 92 C7H8 000108-88-3 90
5 1,3,5-Cycloheptatriene 92 C7H8 000544-25-2 90
0 10 20 30 40 50 60 70 80 90 1000
5000
m/z-->
bundance Scan 71 (1.699 min): G012323-04.D\data.ms (-62) (-)91.0
65.039.1 51.0 74.0
0 10 20 30 40 50 60 70 80 90 1000
5000
m/z-->
bundance #109011: Toluene 91.0
39.0 65.051.027.0 77.01.0 15.0
0 10 20 30 40 50 60 70 80 90 1000
5000
m/z-->
bundance #109012: Toluene 91.0
39.0 65.051.027.0 77.0
0 10 20 30 40 50 60 70 80 90 1000
5000
m/z-->
bundance #109014: Toluene 91.0
65.039.0 51.027.0 77.0
1.40 1.60 1.80 2.00
m/z 91.05 100.00%
1.40 1.60 1.80 2.00
m/z 92.10 61.90%
1.40 1.60 1.80 2.00
m/z 65.00 14.04%
1.40 1.60 1.80 2.00
m/z 39.10 12.80%
1.40 1.60 1.80 2.00
m/z 63.00 10.54%
G011823_WAYPOINT FL.M Wed Jan 25 11:07:19 2023 Page: 3Page 69 of 111
Library Search Compound Report
Data Path : S:\SMS\SMS-G\DATA\012323\
Data File : G012323-07.D
Acq On : 23 Jan 2023 17:14
Operator : JVOGEL
Sample : V 98099-V29089
Misc :
ALS Vial : 6 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-G\METHOD\G011823_WAYPOINT FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: LSCINT.P
*********************************************************************
Peak Number 2 n-Hexadecanoic acid Concentration Rank 7
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
7.610 29.91 ppb 1226400 Phenanthrene-d10 7.075
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 n-Hexadecanoic acid 256 C16H32O2 000057-10-3 99
2 n-Hexadecanoic acid $$ Hexadecan... 256 C16H32O2 000057-10-3 95
3 n-Hexadecanoic acid 256 C16H32O2 000057-10-3 94
4 Tetradecanoic acid 228 C14H28O2 000544-63-8 80
5 Pentadecanoic acid $$ Pentadecyl... 242 C15H30O2 001002-84-2 74
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 3200
5000
m/z-->
bundance Scan 1076 (7.610 min): G012323-07.D\data.ms (-1071) (-)43.0 73.0
129.1
256.1213.2157.1185.1101.0 331.7284.3
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 3200
5000
m/z-->
bundance #123965: n-Hexadecanoic acid43.0 73.0
256.0129.0
213.0157.0101.0 185.0
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 3200
5000
m/z-->
bundance#57109: n-Hexadecanoic acid $$ Hexadecanoic acid $$ n-Hexadecoic a43.0 73.0
129.0 256.0213.0101.0 157.0185.0
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 3200
5000
m/z-->
bundance #123964: n-Hexadecanoic acid43.0 73.0
129.0
213.0 256.0101.0 171.0
7.20 7.40 7.60 7.80 8.00
m/z 43.05 100.00%
7.20 7.40 7.60 7.80 8.00
m/z 60.00 94.50%
7.20 7.40 7.60 7.80 8.00
m/z 73.00 88.25%
7.20 7.40 7.60 7.80 8.00
m/z 57.05 83.78%
7.20 7.40 7.60 7.80 8.00
m/z 55.10 80.93%
G011823_WAYPOINT FL.M Wed Feb 01 10:04:56 2023 Page: 5Page 70 of 111
Library Search Compound Report
Data Path : S:\SMS\SMS-G\DATA\012323\
Data File : G012323-08.D
Acq On : 23 Jan 2023 17:37
Operator : JVOGEL
Sample : V 98100-V29089
Misc :
ALS Vial : 7 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-G\METHOD\G011823_WAYPOINT FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: LSCINT.P
*********************************************************************
Peak Number 1 2-Pentanol, 2-methyl-Concentration Rank 5
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
1.540 590.16 ppb 25341300 1,4-Dichlorobenzene-d4 3.228
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 2-Pentanol, 2-methyl-102 C6H14O 000590-36-3 83
2 2-Pentanol, 2-methyl- $$ 2-Hydro... 102 C6H14O 000590-36-3 78
3 2-Pentanol, 2-methyl-102 C6H14O 000590-36-3 78
4 2-Pentanol, 2-methyl-102 C6H14O 000590-36-3 72
5 2-Butanol, 2,3-dimethyl-102 C6H14O 000594-60-5 50
20 40 60 80 100 120 140 160 1800
5000
m/z-->
bundance Scan 44 (1.540 min): G012323-08.D\data.ms (-33) (-)59.1
43.1 87.1
175.8126.9102.1 141.8
20 40 60 80 100 120 140 160 1800
5000
m/z-->
bundance #109760: 2-Pentanol, 2-methyl-59.0
87.0
43.027.0 102.0
20 40 60 80 100 120 140 160 1800
5000
m/z-->
bundance#2124: 2-Pentanol, 2-methyl- $$ 2-Hydroxy-2-methylpentane $$ 2-Methy59.0
87.043.0
27.0
20 40 60 80 100 120 140 160 1800
5000
m/z-->
bundance #109759: 2-Pentanol, 2-methyl-59.0
87.041.0
1.40 1.60 1.80
m/z 59.10 100.00%
1.40 1.60 1.80
m/z 45.10 34.15%
1.40 1.60 1.80
m/z 43.10 25.84%
1.40 1.60 1.80
m/z 87.10 24.60%
1.40 1.60 1.80
m/z 41.10 20.24%
G011823_WAYPOINT FL.M Wed Feb 01 10:05:45 2023 Page: 4Page 71 of 111
Library Search Compound Report
Data Path : S:\SMS\SMS-G\DATA\012323\
Data File : G012323-08.D
Acq On : 23 Jan 2023 17:37
Operator : JVOGEL
Sample : V 98100-V29089
Misc :
ALS Vial : 7 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-G\METHOD\G011823_WAYPOINT FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: LSCINT.P
*********************************************************************
Peak Number 2 Toluene Concentration Rank 1
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
1.705 2115.32 ppb 90830700 1,4-Dichlorobenzene-d4 3.228
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Toluene 92 C7H8 000108-88-3 91
2 Toluene 92 C7H8 000108-88-3 90
3 Toluene 92 C7H8 000108-88-3 90
4 1,5-Hexadien-3-yne, 2-methyl- $$... 92 C7H8 000820-54-2 87
5 1,5-Hexadien-3-yne, 2-methyl- 92 C7H8 000820-54-2 87
0 50 100 150 200 250 3000
5000
m/z-->
bundance Scan 72 (1.705 min): G012323-08.D\data.ms (-52) (-)91.2
39.1
128.0 164.9 344.
0 50 100 150 200 250 3000
5000
m/z-->
bundance #109011: Toluene91.0
39.0
1.0
0 50 100 150 200 250 3000
5000
m/z-->
bundance #109012: Toluene91.0
39.0
0 50 100 150 200 250 3000
5000
m/z-->
bundance #109014: Toluene91.0
39.0
1.40 1.60 1.80 2.00
m/z 91.20 100.00%
1.40 1.60 1.80 2.00
m/z 92.20 88.30%
1.40 1.60 1.80 2.00
m/z 65.05 47.75%
1.40 1.60 1.80 2.00
m/z 63.10 35.24%
1.40 1.60 1.80 2.00
m/z 39.10 32.56%
G011823_WAYPOINT FL.M Wed Feb 01 10:05:46 2023 Page: 5Page 72 of 111
Library Search Compound Report
Data Path : S:\SMS\SMS-G\DATA\012323\
Data File : G012323-08.D
Acq On : 23 Jan 2023 17:37
Operator : JVOGEL
Sample : V 98100-V29089
Misc :
ALS Vial : 7 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-G\METHOD\G011823_WAYPOINT FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: LSCINT.P
*********************************************************************
Peak Number 3 Cyclopentanol, 1-methyl- Concentration Rank 8
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
1.840 329.18 ppb 14134700 1,4-Dichlorobenzene-d4 3.228
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Cyclopentanol, 1-methyl-100 C6H12O 001462-03-9 83
2 Cyclopentanol, 1-methyl- $$ 1-Hy... 100 C6H12O 001462-03-9 83
3 1-Penten-3-ol, 4-methyl-100 C6H12O 004798-45-2 50
4 Cyclopentanol, 1-methyl-100 C6H12O 001462-03-9 45
5 1-Methoxycyclohexane 114 C7H14O 000931-56-6 40
10 20 30 40 50 60 70 80 90 100 110 1200
5000
m/z-->
bundance Scan 95 (1.840 min): G012323-08.D\data.ms (-91) (-)71.1
58.1
43.1
85.1
114.199.0
10 20 30 40 50 60 70 80 90 100 110 1200
5000
m/z-->
bundance #109498: Cyclopentanol, 1-methyl-71.043.0
58.0
85.0
100.0
10 20 30 40 50 60 70 80 90 100 110 1200
5000
m/z-->
bundance#1825: Cyclopentanol, 1-methyl- $$ 1-Hydroxy-1-methylcyclopentane $$ 71.0
43.0
58.0
85.027.015.0 100.0
10 20 30 40 50 60 70 80 90 100 110 1200
5000
m/z-->
bundance #109588: 1-Penten-3-ol, 4-methyl-71.0
43.0
27.0 53.0 85.0 100.015.0
1.60 1.80 2.00 2.20
m/z 71.10 100.00%
1.60 1.80 2.00 2.20
m/z 58.10 52.95%
1.60 1.80 2.00 2.20
m/z 43.10 26.88%
1.60 1.80 2.00 2.20
m/z 85.10 15.55%
1.60 1.80 2.00 2.20
m/z 57.10 14.80%
G011823_WAYPOINT FL.M Wed Feb 01 10:05:47 2023 Page: 6Page 73 of 111
Library Search Compound Report
Data Path : S:\SMS\SMS-G\DATA\012323\
Data File : G012323-08.D
Acq On : 23 Jan 2023 17:37
Operator : JVOGEL
Sample : V 98100-V29089
Misc :
ALS Vial : 7 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-G\METHOD\G011823_WAYPOINT FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: LSCINT.P
*********************************************************************
Peak Number 5 Ethylbenzene Concentration Rank 3
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
2.252 768.72 ppb 33008100 1,4-Dichlorobenzene-d4 3.228
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Ethylbenzene 106 C8H10 000100-41-4 91
2 Ethylbenzene $$ Benzene, ethyl- ... 106 C8H10 000100-41-4 87
3 Ethylbenzene 106 C8H10 000100-41-4 87
4 p-Xylene 106 C8H10 000106-42-3 83
5 Benzene, 1,2-dimethyl-106 C8H10 000095-47-6 76
0 20 40 60 80 100 120 140 160 180 200 220 2400
5000
m/z-->
bundance Scan 165 (2.252 min): G012323-08.D\data.ms (-155) (-)91.0
51.0
253.115.1 141.0 169.9
0 20 40 60 80 100 120 140 160 180 200 220 2400
5000
m/z-->
bundance #110007: Ethylbenzene91.0
51.027.01.0
0 20 40 60 80 100 120 140 160 180 200 220 2400
5000
m/z-->
bundance#2448: Ethylbenzene $$ Benzene, ethyl- $$ Ethylbenzol $$ EB $$ Phen91.0
51.027.0
0 20 40 60 80 100 120 140 160 180 200 220 2400
5000
m/z-->
bundance #110008: Ethylbenzene91.0
51.0
27.0
2.00 2.20 2.40 2.60
m/z 91.05 100.00%
2.00 2.20 2.40 2.60
m/z 106.10 54.17%
2.00 2.20 2.40 2.60
m/z 51.05 23.25%
2.00 2.20 2.40 2.60
m/z 65.10 19.09%
2.00 2.20 2.40 2.60
m/z 77.05 16.14%
G011823_WAYPOINT FL.M Wed Feb 01 10:05:50 2023 Page: 8Page 74 of 111
Library Search Compound Report
Data Path : S:\SMS\SMS-G\DATA\012323\
Data File : G012323-08.D
Acq On : 23 Jan 2023 17:37
Operator : JVOGEL
Sample : V 98100-V29089
Misc :
ALS Vial : 7 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-G\METHOD\G011823_WAYPOINT FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: LSCINT.P
*********************************************************************
Peak Number 6 Benzene, 1,3-dimethyl-Concentration Rank 2
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
2.463 1079.70 ppb 46361500 1,4-Dichlorobenzene-d4 3.228
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Benzene, 1,3-dimethyl-106 C8H10 000108-38-3 90
2 p-Xylene 106 C8H10 000106-42-3 76
3 Benzene, 1,2-dimethyl-106 C8H10 000095-47-6 62
4 p-Xylene $$ Benzene, 1,4-dimethy... 106 C8H10 000106-42-3 59
5 Cyclopentene, 1-ethenyl-3-methyl... 106 C8H10 061142-07-2 52
20 40 60 80 100 120 140 160 180 2000
5000
m/z-->
bundance Scan 201 (2.463 min): G012323-08.D\data.ms (-192) (-)91.2
51.1
74.0 108.1 126.8 166.9144.9 207.1
20 40 60 80 100 120 140 160 180 2000
5000
m/z-->
bundance #110011: Benzene, 1,3-dimethyl-91.0
51.027.0 74.0
20 40 60 80 100 120 140 160 180 2000
5000
m/z-->
bundance #110024: p-Xylene91.0
51.027.0 74.0
20 40 60 80 100 120 140 160 180 2000
5000
m/z-->
bundance #110026: Benzene, 1,2-dimethyl-91.0
39.0 65.0 108.0
2.20 2.40 2.60 2.80
m/z 91.15 100.00%
2.20 2.40 2.60 2.80
m/z 106.15 80.83%
2.20 2.40 2.60 2.80
m/z 105.10 52.31%
2.20 2.40 2.60 2.80
m/z 77.05 38.45%
2.20 2.40 2.60 2.80
m/z 51.10 31.68%
G011823_WAYPOINT FL.M Wed Feb 01 10:05:51 2023 Page: 9Page 75 of 111
Library Search Compound Report
Data Path : S:\SMS\SMS-G\DATA\012323\
Data File : G012323-08.D
Acq On : 23 Jan 2023 17:37
Operator : JVOGEL
Sample : V 98100-V29089
Misc :
ALS Vial : 7 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-G\METHOD\G011823_WAYPOINT FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: LSCINT.P
*********************************************************************
Peak Number 8 Benzene, 1-ethyl-3-methyl- Concentration Rank 6
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
2.887 532.89 ppb 22881900 1,4-Dichlorobenzene-d4 3.228
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Benzene, 1-ethyl-3-methyl-120 C9H12 000620-14-4 91
2 Benzene, 1-ethyl-2-methyl- $$ To... 120 C9H12 000611-14-3 87
3 Benzene, 1-ethyl-4-methyl- $$ To... 120 C9H12 000622-96-8 87
4 Benzene, 1-ethyl-2-methyl-120 C9H12 000611-14-3 87
5 Benzene, 1-ethyl-4-methyl-120 C9H12 000622-96-8 87
10 20 30 40 50 60 70 80 90 1001101201301401501601700
5000
m/z-->
bundance Scan 273 (2.887 min): G012323-08.D\data.ms (-267) (-)105.1
120.1
77.0 91.151.1
37.1 146.9 167.8
10 20 30 40 50 60 70 80 90 1001101201301401501601700
5000
m/z-->
bundance #111392: Benzene, 1-ethyl-3-methyl-105.0
120.077.0 91.051.027.0
10 20 30 40 50 60 70 80 90 1001101201301401501601700
5000
m/z-->
bundance#4792: Benzene, 1-ethyl-2-methyl- $$ Toluene, o-ethyl- $$ o-Ethylmethyl105.0
120.0
39.0 91.077.063.025.0
10 20 30 40 50 60 70 80 90 1001101201301401501601700
5000
m/z-->
bundance#4800: Benzene, 1-ethyl-4-methyl- $$ Toluene, p-ethyl- $$ p-Ethylmethyl105.0
120.0
77.039.0 91.063.025.0
2.60 2.80 3.00 3.20
m/z 105.10 100.00%
2.60 2.80 3.00 3.20
m/z 120.10 55.92%
2.60 2.80 3.00 3.20
m/z 77.05 24.41%
2.60 2.80 3.00 3.20
m/z 106.05 19.13%
2.60 2.80 3.00 3.20
m/z 79.05 18.29%
G011823_WAYPOINT FL.M Wed Feb 01 10:05:53 2023 Page: 11Page 76 of 111
Library Search Compound Report
Data Path : S:\SMS\SMS-G\DATA\012323\
Data File : G012323-08.D
Acq On : 23 Jan 2023 17:37
Operator : JVOGEL
Sample : V 98100-V29089
Misc :
ALS Vial : 7 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-G\METHOD\G011823_WAYPOINT FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: LSCINT.P
*********************************************************************
Peak Number 10 Benzene, 1,2,3-trimethyl- $... Concentration Rank 4
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
3.110 741.03 ppb 31819600 1,4-Dichlorobenzene-d4 3.228
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Benzene, 1,2,3-trimethyl- $$ Hem... 120 C9H12 000526-73-8 87
2 Benzene, 1-ethyl-2-methyl-120 C9H12 000611-14-3 81
3 Benzene, 1-ethyl-2-methyl-120 C9H12 000611-14-3 81
4 Benzene, 1-ethyl-2-methyl-120 C9H12 000611-14-3 81
5 Benzene, 1-ethyl-3-methyl-120 C9H12 000620-14-4 76
20 40 60 80 100 120 140 160 1800
5000
m/z-->
bundance Scan 311 (3.110 min): G012323-08.D\data.ms (-301) (-)105.2
120.1
77.0
51.0
36.0 135.0 182.0
20 40 60 80 100 120 140 160 1800
5000
m/z-->
bundance#4803: Benzene, 1,2,3-trimethyl- $$ Hemimellitene $$ 1,2,3-Trimethylbe105.0
120.0
77.039.0 62.015.0
20 40 60 80 100 120 140 160 1800
5000
m/z-->
bundance #111384: Benzene, 1-ethyl-2-methyl-105.0
120.0
77.039.0 59.0
20 40 60 80 100 120 140 160 1800
5000
m/z-->
bundance #111386: Benzene, 1-ethyl-2-methyl-105.0
120.0
77.044.0 59.0
2.80 3.00 3.20 3.40
m/z 105.15 100.00%
2.80 3.00 3.20 3.40
m/z 120.05 78.71%
2.80 3.00 3.20 3.40
m/z 77.05 33.28%
2.80 3.00 3.20 3.40
m/z 119.05 33.20%
2.80 3.00 3.20 3.40
m/z 91.10 28.20%
G011823_WAYPOINT FL.M Wed Feb 01 10:05:56 2023 Page: 13Page 77 of 111
ANALYTICAL REPORT
PREPARED FOR
Attn: PM Group NC
Waypoint Analytical, Inc.
449 Springbrook Road
Charlotte, North Carolina 28217
Generated 1/28/2023 2:27:42 PM
JOB DESCRIPTION
23-020-0019
JOB NUMBER
680-229518-1
See page two for job notes and contact information.
Savannah GA 31404
5102 LaRoche Avenue
Eurofins Savannah
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Eurofins Savannah
Eurofins Savannah is a laboratory within Eurofins Environment Testing Southeast, LLC, a company within Eurofins Environment Testing Group of Companies
Job Notes
The test results in this report meet NELAP requirements for parameters for which accreditation is required or available. Any
exceptions to the NELAP requirements are noted. Results pertain only to samples listed in this report. This report may not be
reproduced, except in full, without the written approval of the laboratory. Questions should be directed to the person who
signed this report.
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the
methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written
approval of the laboratory. All questions should be directed to the Eurofins Environment Testing Southeast, LLC Project
Manager.
Authorization
Generated
1/28/2023 2:27:42 PM
Authorized for release by
John Andros, Project Manager I
[e-mail]
[phone]
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Definitions/Glossary
Job ID: 680-229518-1Client: Waypoint Analytical, Inc.
Project/Site: 23-020-0019
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins Savannah
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Sample Summary
Client: Waypoint Analytical, Inc.Job ID: 680-229518-1
Project/Site: 23-020-0019
Lab Sample ID Client Sample ID Matrix Collected Received
680-229518-1 MW-12 / 98099 Water 01/16/23 15:50 01/24/23 10:30
680-229518-2 MW-13 / 98100 Water 01/16/23 16:10 01/24/23 10:30
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Case Narrative
Client: Waypoint Analytical, Inc.Job ID: 680-229518-1
Project/Site: 23-020-0019
Job ID: 680-229518-1
Laboratory: Eurofins Savannah
Narrative
Job Narrative
680-229518-1
Receipt
The samples were received on 1/24/2023 10:30 AM. Unless otherwise noted below, the samples arrived in good condition, and, where
required, properly preserved and on ice. The temperature of the cooler at receipt time was 0.6°C
Metals
No additional analytical or quality issues were noted, other than those described above or in the Definitions/ Glossary page.
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Client Sample Results
Job ID: 680-229518-1Client: Waypoint Analytical, Inc.
Project/Site: 23-020-0019
Lab Sample ID: 680-229518-1Client Sample ID: MW-12 / 98099
Matrix: WaterDate Collected: 01/16/23 15:50
Date Received: 01/24/23 10:30
Method: SW846 6010D - Metals (ICP) - Total Recoverable
RL MDL
ND 10.0 ug/L 01/25/23 07:01 01/26/23 13:57 1
Analyte Dil FacAnalyzedPreparedUnitDResult Qualifier
Lead
Eurofins Savannah
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Client Sample Results
Job ID: 680-229518-1Client: Waypoint Analytical, Inc.
Project/Site: 23-020-0019
Lab Sample ID: 680-229518-2Client Sample ID: MW-13 / 98100
Matrix: WaterDate Collected: 01/16/23 16:10
Date Received: 01/24/23 10:30
Method: SW846 6010D - Metals (ICP) - Total Recoverable
RL MDL
ND 10.0 ug/L 01/25/23 07:01 01/26/23 14:06 1
Analyte Dil FacAnalyzedPreparedUnitDResult Qualifier
Lead
Eurofins Savannah
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QC Sample Results
Job ID: 680-229518-1Client: Waypoint Analytical, Inc.
Project/Site: 23-020-0019
Method: 6010D - Metals (ICP)
Client Sample ID: Method BlankLab Sample ID: MB 680-760420/1-A
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 760778 Prep Batch: 760420
RL MDL
Lead ND 10.0 ug/L 01/25/23 07:01 01/26/23 13:21 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-760420/2-A
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 760778 Prep Batch: 760420
Lead 505 517.4 ug/L 103 80 -120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec
Limits
Client Sample ID: Matrix SpikeLab Sample ID: 680-229512-A-1-B MS
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 760778 Prep Batch: 760420
Lead ND 505 510.5 ug/L 101 75 -125
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 680-229512-A-1-C MSD
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 760778 Prep Batch: 760420
Lead ND 505 521.8 ug/L 103 75 -125 2 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits LimitRPD
RPD
Eurofins Savannah
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QC Association Summary
Job ID: 680-229518-1Client: Waypoint Analytical, Inc.
Project/Site: 23-020-0019
Metals
Prep Batch: 760420
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3005A680-229518-1 MW-12 / 98099 Total Recoverable
Water 3005A680-229518-2 MW-13 / 98100 Total Recoverable
Water 3005AMB 680-760420/1-A Method Blank Total Recoverable
Water 3005ALCS 680-760420/2-A Lab Control Sample Total Recoverable
Water 3005A680-229512-A-1-B MS Matrix Spike Total Recoverable
Water 3005A680-229512-A-1-C MSD Matrix Spike Duplicate Total Recoverable
Analysis Batch: 760778
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6010D 760420680-229518-1 MW-12 / 98099 Total Recoverable
Water 6010D 760420680-229518-2 MW-13 / 98100 Total Recoverable
Water 6010D 760420MB 680-760420/1-A Method Blank Total Recoverable
Water 6010D 760420LCS 680-760420/2-A Lab Control Sample Total Recoverable
Water 6010D 760420680-229512-A-1-B MS Matrix Spike Total Recoverable
Water 6010D 760420680-229512-A-1-C MSD Matrix Spike Duplicate Total Recoverable
Eurofins Savannah
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Lab Chronicle
Client: Waypoint Analytical, Inc.Job ID: 680-229518-1
Project/Site: 23-020-0019
Client Sample ID: MW-12 / 98099 Lab Sample ID: 680-229518-1
Matrix: WaterDate Collected: 01/16/23 15:50
Date Received: 01/24/23 10:30
Prep 3005A RR01/25/23 07:01 EET SAV760420
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total Recoverable 50 mL 50 mL
Analysis 6010D 1 760778 01/26/23 13:57 BCB EET SAVTotal Recoverable
ICPHInstrument ID:
Client Sample ID: MW-13 / 98100 Lab Sample ID: 680-229518-2
Matrix: WaterDate Collected: 01/16/23 16:10
Date Received: 01/24/23 10:30
Prep 3005A RR01/25/23 07:01 EET SAV760420
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total Recoverable 50 mL 50 mL
Analysis 6010D 1 760778 01/26/23 14:06 BCB EET SAVTotal Recoverable
ICPHInstrument ID:
Laboratory References:
EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL [phone]
Eurofins Savannah
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Accreditation/Certification Summary
Client: Waypoint Analytical, Inc.Job ID: 680-229518-1
Project/Site: 23-020-0019
Laboratory: Eurofins Savannah
The accreditations/certifications listed below are applicable to this report.
Authority Program Identification Number Expiration Date
North Carolina (WW/SW)State 269 12-31-23
South Carolina State 98001 06-30-23
Eurofins Savannah
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Method Summary
Job ID: 680-229518-1Client: Waypoint Analytical, Inc.
Project/Site: 23-020-0019
Method Method Description LaboratoryProtocol
SW8466010DMetals (ICP)EET SAV
SW8463005APreparation, Total Recoverable or Dissolved Metals EET SAV
Protocol References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL [phone]
Eurofins Savannah
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Login Sample Receipt Checklist
Client: Waypoint Analytical, Inc.Job Number: 680-229518-1
Login Number: 229518
Question Answer Comment
Creator: Sims, Robert D
List Source: Eurofins Savannah
List Number: 1
N/ARadioactivity wasn't checked or is </= background as measured by a survey
meter.
TrueThe cooler's custody seal, if present, is intact.
TrueSample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or
tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate
HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
TrueSample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
N/AContainers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
Eurofins Savannah
Page 14 of 14 1/28/2023
1
2
3
4
5
6
7
8
9
10
11
12
Page 91 of 111
Quality Control Data
23-020-0019Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29218QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29217
Associated Lab Samples: 98090, 98091, 98092, 98093, 98094, 98095, 98096, 98097, 98098, 98099, 98100, 98101
LRB-V29217 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
01/27/23 03:5410.01.80<1.80µg/LAcetone
01/27/23 03:540.5000.180<0.180µg/LBenzene
01/27/23 03:540.5000.210<0.210µg/LBromobenzene
01/27/23 03:541.000.420<0.420µg/LBromochloromethane
01/27/23 03:540.5000.160<0.160µg/LBromodichloromethane
01/27/23 03:545.001.50<1.50µg/LBromoform
01/27/23 03:541.000.280<0.280µg/LBromomethane
01/27/23 03:540.5000.180<0.180µg/Ln-Butylbenzene
01/27/23 03:540.5000.200<0.200µg/Lsec-Butyl benzene
01/27/23 03:542.000.920<0.920µg/Ltert-Butyl benzene
01/27/23 03:540.5000.180<0.180µg/LCarbon Tetrachloride
01/27/23 03:540.5000.190<0.190µg/LChlorobenzene
01/27/23 03:540.5000.190<0.190µg/LChlorodibromomethane
01/27/23 03:541.000.430<0.430µg/LChloroethane
01/27/23 03:540.5000.220<0.220µg/LChloroform
01/27/23 03:540.5000.220<0.220µg/LChloromethane
01/27/23 03:540.5000.200<0.200µg/L2-Chlorotoluene
01/27/23 03:540.5000.200<0.200µg/L4-Chlorotoluene
01/27/23 03:540.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
01/27/23 03:542.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
01/27/23 03:540.5000.200<0.200µg/L1,2-Dibromoethane
01/27/23 03:540.5000.230<0.230µg/LDibromomethane
01/27/23 03:540.5000.220<0.220µg/L1,2-Dichlorobenzene
01/27/23 03:540.5000.190<0.190µg/L1,3-Dichlorobenzene
01/27/23 03:540.5000.210<0.210µg/L1,4-Dichlorobenzene
01/27/23 03:545.001.20<1.20µg/LDichlorodifluoromethane
01/27/23 03:540.5000.240<0.240µg/L1,1-Dichloroethane
Page 1 of 17Date:02/03/2023 05:16 PM
Page 92 of 111
Quality Control Data
23-020-0019Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29218QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29217
Associated Lab Samples: 98090, 98091, 98092, 98093, 98094, 98095, 98096, 98097, 98098, 98099, 98100, 98101
LRB-V29217 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
01/27/23 03:540.5000.150<0.150µg/L1,2-Dichloroethane
01/27/23 03:540.5000.150<0.150µg/L1,1-Dichloroethene
01/27/23 03:540.5000.200<0.200µg/Lcis-1,2-Dichloroethene
01/27/23 03:540.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
01/27/23 03:540.5000.190<0.190µg/L1,2-Dichloropropane
01/27/23 03:540.5000.130<0.130µg/L1,3-Dichloropropane
01/27/23 03:542.000.210<0.210µg/L2,2-Dichloropropane
01/27/23 03:540.5000.200<0.200µg/L1,1-Dichloropropene
01/27/23 03:540.5000.210<0.210µg/Lcis-1,3-Dichloropropene
01/27/23 03:540.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
01/27/23 03:5420042.0<42.0µg/LEthanol
01/27/23 03:540.5000.170<0.170µg/LEthylbenzene
01/27/23 03:543.000.350<0.350µg/LHexachlorobutadiene
01/27/23 03:541.000.380<0.380µg/L2-Hexanone
01/27/23 03:540.5000.180<0.180µg/LIsopropylbenzene
01/27/23 03:540.5000.089<0.089µg/L4-Isopropyl toluene
01/27/23 03:545.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
01/27/23 03:541.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
01/27/23 03:541.000.078<0.078µg/L4-Methyl-2-Pentanone
01/27/23 03:542.000.330<0.330µg/LMethylene Chloride
01/27/23 03:541.000.470<0.470µg/LNaphthalene
01/27/23 03:540.5000.190<0.190µg/Ln-Propylbenzene
01/27/23 03:540.5000.220<0.220µg/LStyrene
01/27/23 03:540.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
01/27/23 03:540.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
01/27/23 03:540.5000.220<0.220µg/L
01/27/23 03:540.5000.220<0.220µg/L
Page 2 of 17Date:02/03/2023 05:16 PM
Page 93 of 111
Quality Control Data
23-020-0019Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29218QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29217
Associated Lab Samples: 98090, 98091, 98092, 98093, 98094, 98095, 98096, 98097, 98098, 98099, 98100, 98101
LRB-V29217 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
01/27/23 03:540.5000.380<0.380µg/L1,2,3-Trichlorobenzene
01/27/23 03:540.5000.310<0.310µg/L1,2,4-Trichlorobenzene
01/27/23 03:540.5000.160<0.160µg/L1,1,1-Trichloroethane
01/27/23 03:540.5000.096<0.096µg/L1,1,2-Trichloroethane
01/27/23 03:540.5000.180<0.180µg/L
01/27/23 03:540.5000.180<0.180µg/L
01/27/23 03:540.5000.270<0.270µg/L1,2,3-Trichloropropane
01/27/23 03:540.5000.190<0.190µg/L1,2,4-Trimethylbenzene
01/27/23 03:540.5000.180<0.180µg/L1,3,5-Trimethylbenzene
01/27/23 03:545.001.00<1.00µg/LVinyl Acetate
01/27/23 03:540.5000.170<0.170µg/LVinyl Chloride
01/27/23 03:540.5000.210<0.210µg/Lo-Xylene
01/27/23 03:541.000.420<0.420µg/Lm,p-Xylene
01/27/23 03:544-Bromofluorobenzene (S)102 70-130
01/27/23 03:54Dibromofluoromethane (S)90.6 70-130
01/27/23 03:541,2-Dichloroethane - d4 (S)87.4 70-130
01/27/23 03:54 106 70-130
LCS-V29217 LCSD-V29217Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
31.0 77.581.532.640.0µg/LAcetone 40-160 5.0 20.0
18.4 92.092.518.520.0µg/LBenzene 70-130 0.5 20.0
17.6 88.087.517.520.0µg/LBromobenzene 70-130 0.5 20.0
18.2 91.096.519.320.0µg/LBromochloromethane 70-130 5.8 20.0
18.8 94.093.518.720.0µg/LBromodichloromethane 70-130 0.5 20.0
Page 3 of 17Date:02/03/2023 05:16 PM
Page 94 of 111
Quality Control Data
23-020-0019Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29218QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29217
LCS-V29217 LCSD-V29217Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.0 10098.519.720.0µg/LBromoform 70-130 1.5 20.0
13.9 69.574.014.820.0µg/LBromomethane 60-140 6.2 20.0
18.6 93.095.019.020.0µg/Ln-Butylbenzene 70-130 2.1 20.0
18.5 92.595.019.020.0µg/Lsec-Butyl benzene 70-130 2.6 20.0
18.9 94.595.519.120.0µg/Ltert-Butyl benzene 70-130 1.0 20.0
20.1 10110120.120.0µg/LCarbon Tetrachloride 70-130 0.0 20.0
19.2 96.098.519.720.0µg/LChlorobenzene 70-130 2.5 20.0
19.2 96.097.019.420.0µg/LChlorodibromomethane 70-130 1.0 20.0
20.0 10010821.520.0µg/LChloroethane 60-140 7.2 20.0
19.2 96.010120.120.0µg/LChloroform 70-130 4.5 20.0
17.3 86.587.517.520.0µg/LChloromethane 60-140 1.1 20.0
18.5 92.595.519.120.0µg/L2-Chlorotoluene 70-130 3.1 20.0
18.5 92.598.019.620.0µg/L4-Chlorotoluene 70-130 5.7 20.0
18.9 94.597.019.420.0µg/LDi-Isopropyl Ether (DIPE)70-130 2.6 20.0
17.1 85.590.018.020.0µg/L1,2-Dibromo-3-Chloropropane 70-130 5.1 20.0
18.7 93.593.018.620.0µg/L1,2-Dibromoethane 70-130 0.5 20.0
17.3 86.587.017.420.0µg/LDibromomethane 70-130 0.5 20.0
19.6 98.099.019.820.0µg/L1,2-Dichlorobenzene 70-130 1.0 20.0
19.1 95.598.019.620.0µg/L1,3-Dichlorobenzene 70-130 2.5 20.0
19.3 96.598.019.620.0µg/L1,4-Dichlorobenzene 70-130 1.5 20.0
19.4 97.010020.020.0µg/LDichlorodifluoromethane 60-140 3.0 20.0
18.7 93.597.019.420.0µg/L1,1-Dichloroethane 70-130 3.6 20.0
18.1 90.590.518.120.0µg/L1,2-Dichloroethane 70-130 0.0 20.0
18.9 94.599.519.920.0µg/L1,1-Dichloroethene 70-130 5.1 20.0
18.6 93.097.519.520.0µg/Lcis-1,2-Dichloroethene 70-130 4.7 20.0
17.1 85.599.519.920.0µg/Ltrans-1,2-Dichloroethene 70-130 15.1 20.0
Page 4 of 17Date:02/03/2023 05:16 PM
Page 95 of 111
Quality Control Data
23-020-0019Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29218QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29217
LCS-V29217 LCSD-V29217Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
18.1 90.593.518.720.0µg/L1,2-Dichloropropane 70-130 3.2 20.0
17.9 89.592.018.420.0µg/L1,3-Dichloropropane 70-130 2.7 20.0
16.1 80.584.516.920.0µg/L2,2-Dichloropropane 70-130 4.8 20.0
19.8 99.099.519.920.0µg/L1,1-Dichloropropene 70-130 0.5 20.0
18.2 91.089.017.820.0µg/Lcis-1,3-Dichloropropene 70-130 2.2 20.0
18.1 90.592.518.520.0µg/Ltrans-1,3-Dichloropropene 70-130 2.1 20.0
390 78.088.4442500µg/LEthanol 60-140 12.5 20.0
18.5 92.596.019.220.0µg/LEthylbenzene 70-130 3.7 20.0
21.7 10910621.120.0µg/LHexachlorobutadiene 70-130 2.8 20.0
14.8 74.074.014.820.0µg/L2-Hexanone 60-140 0.0 20.0
18.9 94.598.019.620.0µg/LIsopropylbenzene 70-130 3.6 20.0
18.9 94.596.519.320.0µg/L4-Isopropyl toluene 70-130 2.0 20.0
14.4 72.070.014.020.0µg/LMethyl Ethyl Ketone (MEK)60-140 2.8 20.0
16.9 84.589.517.920.0µg/LMethyl tert-butyl ether (MTBE)70-130 5.7 20.0
14.5 72.573.514.720.0µg/L4-Methyl-2-Pentanone 60-140 1.3 20.0
17.5 87.595.019.020.0µg/LMethylene Chloride 70-130 8.2 20.0
18.0 90.087.017.420.0µg/LNaphthalene 70-130 3.3 20.0
18.3 91.594.518.920.0µg/Ln-Propylbenzene 70-130 3.2 20.0
19.6 98.098.019.620.0µg/LStyrene 70-130 0.0 20.0
20.5 10310220.320.0µg/L1,1,1,2-Tetrachloroethane 70-130 0.9 20.0
17.3 86.585.017.020.0µg/L1,1,2,2-Tetrachloroethane 70-130 1.7 20.0
19.0 95.010120.120.0µg/L 70-130 5.6 20.0
18.0 90.094.018.820.0µg/L 70-130 4.3 20.0
20.0 10096.019.220.0µg/L1,2,3-Trichlorobenzene 70-130 4.0 20.0
20.0 10096.019.220.0µg/L1,2,4-Trichlorobenzene 70-130 4.0 20.0
18.2 91.097.019.420.0µg/L1,1,1-Trichloroethane 70-130 6.3 20.0
Page 5 of 17Date:02/03/2023 05:16 PM
Page 96 of 111
Quality Control Data
23-020-0019Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29218QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29217
LCS-V29217 LCSD-V29217Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
17.9 89.590.018.020.0µg/L1,1,2-Trichloroethane 70-130 0.5 20.0
18.9 94.510120.220.0µg/L 70-130 6.6 20.0
19.6 98.010120.220.0µg/L 60-140 3.0 20.0
16.8 84.079.015.820.0µg/L1,2,3-Trichloropropane 70-130 6.1 20.0
18.7 93.596.519.320.0µg/L1,2,4-Trimethylbenzene 70-130 3.1 20.0
18.8 94.097.019.420.0µg/L1,3,5-Trimethylbenzene 70-130 3.1 20.0
16.3 81.563.512.720.0µg/LVinyl Acetate 60-140 24.8*20.0
19.1 95.510220.320.0µg/LVinyl Chloride 60-140 6.0 20.0
18.5 92.593.518.720.0µg/Lo-Xylene 70-130 1.0 20.0
38.1 95.297.238.940.0µg/Lm,p-Xylene 70-130 2.0 20.0
96.699.44-Bromofluorobenzene (S)70-130
10399.2Dibromofluoromethane (S)70-130
93.891.21,2-Dichloroethane - d4 (S)70-130
102103 70-130
Page 6 of 17* QC Fail Date:02/03/2023 05:16 PM
Page 97 of 111
Quality Control Data
23-020-0019Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29281QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29274
Associated Lab Samples: 98093, 98100
LRB-V29274 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
01/28/23 03:051.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
01/28/23 03:050.5000.220<0.220µg/L
01/28/23 03:054-Bromofluorobenzene (S)97.8 70-130
01/28/23 03:05Dibromofluoromethane (S)97.4 70-130
01/28/23 03:051,2-Dichloroethane - d4 (S)91.2 70-130
01/28/23 03:05 102 70-130
LCS-V29274 LCSD-V29274Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.3 96.594.518.920.0µg/LMethyl tert-butyl ether (MTBE)70-130 2.0 20.0
20.0 10089.017.820.0µg/L 70-130 11.6 20.0
10998.64-Bromofluorobenzene (S)70-130
10699.8Dibromofluoromethane (S)70-130
93.695.61,2-Dichloroethane - d4 (S)70-130
98.095.6 70-130
Page 7 of 17Date:02/03/2023 05:16 PM
Page 98 of 111
Quality Control Data
23-020-0019Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V29124QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V29089
Associated Lab Samples: 98099, 98100
LRB-V29089 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
01/23/23 16:052.000.302<0.302µg/LAcenaphthene
01/23/23 16:052.000.297<0.297µg/LAcenaphthylene
01/23/23 16:052.000.836<0.836µg/LAnthracene
01/23/23 16:0510.01.32<1.32µg/LBenzidine
01/23/23 16:052.000.637<0.637µg/LBenzo(a)anthracene
01/23/23 16:052.001.02<1.02µg/LBenzo(a)pyrene
01/23/23 16:055.002.49<2.49µg/LBenzo(b)fluoranthene
01/23/23 16:055.001.01<1.01µg/LBenzo(g,h,i)perylene
01/23/23 16:055.001.99<1.99µg/LBenzo(k)fluoranthene
01/23/23 16:0510.01.10<1.10µg/LBenzoic Acid
01/23/23 16:055.000.684<0.684µg/LBenzyl alcohol
01/23/23 16:055.000.468<0.468µg/LBis(2-Chloroethoxy)methane
01/23/23 16:055.001.04<1.04µg/LBis(2-Chloroethyl)ether
01/23/23 16:055.001.08<1.08µg/LBis(2-Chloroisopropyl)ether
01/23/23 16:0550.024.0<24.0µg/LBis(2-ethylhexyl)phthalate
01/23/23 16:055.001.11<1.11µg/L4-Bromophenyl phenyl ether
01/23/23 16:055.001.83<1.83µg/LButyl benzyl phthalate
01/23/23 16:055.001.18<1.18µg/L4-Chloro-3-methylphenol
01/23/23 16:0520.07.38<7.38µg/L2-Chloronaphthalene
01/23/23 16:0510.00.938<0.938µg/L2-Chlorophenol
01/23/23 16:055.001.71<1.71µg/L4-Chlorophenyl phenyl ether
01/23/23 16:052.000.405<0.405µg/LChrysene
01/23/23 16:052.000.434<0.434µg/LDibenz(a,h)anthracene
01/23/23 16:055.000.856<0.856µg/LDibenzofuran
01/23/23 16:055.002.00<2.00µg/L1,2-Dichlorobenzene
01/23/23 16:055.002.00<2.00µg/L1,3-Dichlorobenzene
01/23/23 16:055.002.05<2.05µg/L1,4-Dichlorobenzene
Page 8 of 17Date:02/03/2023 05:16 PM
Page 99 of 111
Quality Control Data
23-020-0019Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V29124QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V29089
Associated Lab Samples: 98099, 98100
LRB-V29089 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
01/23/23 16:055.001.89<1.89µg/L3,3'-Dichlorobenzidine
01/23/23 16:0510.01.46<1.46µg/L2,4-Dichlorophenol
01/23/23 16:055.000.745<0.745µg/LDiethyl phthalate
01/23/23 16:055.000.939<0.939µg/LDimethyl phthalate
01/23/23 16:0520.01.57<1.57µg/L2,4-Dimethylphenol
01/23/23 16:055.002.06<2.06µg/LDi-n-butyl phthalate
01/23/23 16:0510.02.07<2.07µg/L4,6-Dinitro-2-methylphenol
01/23/23 16:0510.01.92<1.92µg/L2,4-Dinitrophenol
01/23/23 16:055.001.11<1.11µg/L2,4-Dinitrotoluene
01/23/23 16:055.000.809<0.809µg/L2,6-Dinitrotoluene
01/23/23 16:055.001.65<1.65µg/LDi-n-Octyl Phthalate
01/23/23 16:052.000.250<0.250µg/LFluoranthene
01/23/23 16:052.000.807<0.807µg/LFluorene
01/23/23 16:055.000.979<0.979µg/LHexachlorobenzene
01/23/23 16:055.002.73<2.73µg/LHexachlorobutadiene
01/23/23 16:055.002.05<2.05µg/LHexachlorocyclopentadiene
01/23/23 16:055.001.76<1.76µg/LHexachloroethane
01/23/23 16:052.000.477<0.477µg/LIndeno(1,2,3-cd)pyrene
01/23/23 16:055.000.444<0.444µg/LIsophorone
01/23/23 16:052.001.14<1.14µg/L1-Methylnaphthalene
01/23/23 16:052.000.666<0.666µg/L2-Methylnaphthalene
01/23/23 16:052.000.728<0.728µg/LNaphthalene
01/23/23 16:055.000.905<0.905µg/LNitrobenzene
01/23/23 16:055.000.493<0.493µg/L2-Nitrophenol
01/23/23 16:0510.01.23<1.23µg/L4-Nitrophenol
01/23/23 16:055.001.10<1.10µg/LN-Nitrosodiphenylamine
01/23/23 16:055.000.641<0.641µg/LN-Nitroso-di-n-propylamine
Page 9 of 17Date:02/03/2023 05:16 PM
Page 100 of 111
Quality Control Data
23-020-0019Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V29124QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V29089
Associated Lab Samples: 98099, 98100
LRB-V29089 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
01/23/23 16:055.001.43<1.43µg/LPentachlorophenol
01/23/23 16:052.000.428<0.428µg/LPhenanthrene
01/23/23 16:055.000.651<0.651µg/LPhenol
01/23/23 16:052.000.434<0.434µg/LPyrene
01/23/23 16:055.002.21<2.21µg/L1,2,4-Trichlorobenzene
01/23/23 16:055.001.32<1.32µg/L2,4,6-Trichlorophenol
01/23/23 16:052-Fluorobiphenyl (S)71.4 49-118
01/23/23 16:052-Fluorophenol (S)42.7 22-84
01/23/23 16:05Nitrobenzene-d5 (S)71.4 43-123
01/23/23 16:054-Terphenyl-d14 (S)85.4 49-151
01/23/23 16:052,4,6-Tribromophenol (S)81.8 31-144
01/23/23 16:05Phenol-d5 (S)29.7 10-63
LCS-V29089 LCSD-V29089Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
38.4 76.871.435.750.0µg/LAcenaphthene 47-145 7.2 20.0
39.3 78.672.636.350.0µg/LAcenaphthylene 33-145 7.9 20.0
43.3 86.683.241.650.0µg/LAnthracene 27-133 4.0 20.0
14.0 28.040.820.450.0µg/LBenzidine 15-150 37.2*20.0
42.7 85.484.042.050.0µg/LBenzo(a)anthracene 33-143 1.6 20.0
50.1 10096.248.150.0µg/LBenzo(a)pyrene 17-163 4.0 20.0
46.9 93.889.644.850.0µg/LBenzo(b)fluoranthene 24-159 4.5 20.0
36.3 72.671.635.850.0µg/LBenzo(g,h,i)perylene 10-219 1.3 20.0
42.0 84.083.041.550.0µg/LBenzo(k)fluoranthene 11-162 1.1 20.0
22.8 45.639.019.550.0µg/LBenzoic Acid 10-125 15.6 20.0
Page 10 of 17* QC Fail Date:02/03/2023 05:16 PM
Page 101 of 111
Quality Control Data
23-020-0019Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V29124QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V29089
LCS-V29089 LCSD-V29089Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
32.9 65.861.430.750.0µg/LBenzyl alcohol 16-107 6.9 20.0
36.8 73.665.432.750.0µg/LBis(2-Chloroethoxy)methane 33-184 11.7 20.0
30.3 60.654.227.150.0µg/LBis(2-Chloroethyl)ether 12-158 11.1 20.0
31.1 62.256.228.150.0µg/LBis(2-Chloroisopropyl)ether 36-166 10.1 20.0
49.9 99.897.248.650.0µg/LBis(2-ethylhexyl)phthalate 10-158 2.6 20.0
42.4 84.878.239.150.0µg/L4-Bromophenyl phenyl ether 53-127 8.0 20.0
48.6 97.295.847.950.0µg/LButyl benzyl phthalate 10-152 1.4 20.0
42.1 84.277.238.650.0µg/L4-Chloro-3-methylphenol 22-147 8.6 20.0
35.5 71.064.632.350.0µg/L2-Chloronaphthalene 60-118 9.4 20.0
28.8 57.652.626.350.0µg/L2-Chlorophenol 23-134 9.0 20.0
40.5 81.077.238.650.0µg/L4-Chlorophenyl phenyl ether 25-158 4.8 20.0
43.2 86.485.042.550.0µg/LChrysene 17-168 1.6 20.0
35.7 71.468.434.250.0µg/LDibenz(a,h)anthracene 10-227 4.2 20.0
39.2 78.475.437.750.0µg/LDibenzofuran 39-114 3.9 20.0
24.7 49.443.621.850.0µg/L1,2-Dichlorobenzene 32-129 12.4 20.0
24.5 49.043.421.750.0µg/L1,3-Dichlorobenzene 20-124 12.1 20.0
24.0 48.043.021.550.0µg/L1,4-Dichlorobenzene 20-124 10.9 20.0
36.6 73.271.635.850.0µg/L3,3'-Dichlorobenzidine 10-262 2.2 20.0
35.5 71.061.830.950.0µg/L2,4-Dichlorophenol 39-135 13.8 20.0
43.9 87.886.643.350.0µg/LDiethyl phthalate 10-114 1.3 20.0
42.4 84.883.041.550.0µg/LDimethyl phthalate 10-112 2.1 20.0
39.8 79.673.036.550.0µg/L2,4-Dimethylphenol 32-119 8.6 20.0
49.8 99.697.048.550.0µg/LDi-n-butyl phthalate 10-118 2.6 20.0
47.7 95.487.643.850.0µg/L4,6-Dinitro-2-methylphenol 10-181 8.5 20.0
52.0 10491.245.650.0µg/L2,4-Dinitrophenol 10-191 13.1 20.0
51.4 10398.449.250.0µg/L2,4-Dinitrotoluene 39-139 4.3 20.0
Page 11 of 17Date:02/03/2023 05:16 PM
Page 102 of 111
Quality Control Data
23-020-0019Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V29124QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V29089
LCS-V29089 LCSD-V29089Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
56.2 11210652.850.0µg/L2,6-Dinitrotoluene 50-158 6.2 20.0
49.7 99.497.448.750.0µg/LDi-n-Octyl Phthalate 10-146 2.0 20.0
43.2 86.483.241.650.0µg/LFluoranthene 26-137 3.7 20.0
41.3 82.679.439.750.0µg/LFluorene 59-121 3.9 20.0
42.4 84.881.040.550.0µg/LHexachlorobenzene 10-152 4.5 20.0
26.6 53.244.622.350.0µg/LHexachlorobutadiene 24-116 17.5 20.0
20.0 40.032.816.450.0µg/LHexachlorocyclopentadiene 32-117 19.7 20.0
23.2 46.440.220.150.0µg/LHexachloroethane 40-113 14.3 20.0
47.0 94.094.247.150.0µg/LIndeno(1,2,3-cd)pyrene 10-171 0.2 20.0
25.9 51.847.423.750.0µg/LIsophorone 21-196 8.8 20.0
33.4 66.859.029.550.0µg/L1-Methylnaphthalene 40-135 12.4 20.0
31.3 62.656.228.150.0µg/L2-Methylnaphthalene 18-121 10.7 20.0
30.5 61.054.227.150.0µg/LNaphthalene 21-133 11.8 20.0
34.7 69.460.830.450.0µg/LNitrobenzene 35-180 13.2 20.0
36.9 73.863.031.550.0µg/L2-Nitrophenol 29-182 15.7 20.0
17.3 34.632.416.250.0µg/L4-Nitrophenol 10-132 6.5 20.0
52.4 10510250.950.0µg/LN-Nitrosodiphenylamine 69-152 2.9 20.0
34.9 69.864.832.450.0µg/LN-Nitroso-di-n-propylamine 10-230 7.4 20.0
52.2 10496.648.350.0µg/LPentachlorophenol 14-176 7.7 20.0
43.5 87.085.442.750.0µg/LPhenanthrene 54-120 1.8 20.0
14.3 28.625.412.750.0µg/LPhenol 10-112 11.8 20.0
43.6 87.287.043.550.0µg/LPyrene 52-115 0.2 20.0
27.3 54.648.424.250.0µg/L1,2,4-Trichlorobenzene 44-142 12.0 20.0
40.9 81.874.837.450.0µg/L2,4,6-Trichlorophenol 37-144 8.9 20.0
66.662.82-Fluorobiphenyl (S)49-118
37.534.52-Fluorophenol (S)22-84
Page 12 of 17Date:02/03/2023 05:16 PM
Page 103 of 111
Quality Control Data
23-020-0019Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V29124QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V29089
LCS-V29089 LCSD-V29089Laboratory Control Sample & LCSD
LCSD
ResultParameter
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
66.259.4Nitrobenzene-d5 (S)43-123
86.886.64-Terphenyl-d14 (S)49-151
97.493.22,4,6-Tribromophenol (S)31-144
26.624.7Phenol-d5 (S)10-63
Page 13 of 17Date:02/03/2023 05:16 PM
Page 104 of 111
Quality Control Data
23-020-0019Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
EDB and DBCP by Microextraction GC/ECD
EPA-504.1
V29192QC Analytical Batch(es):
Analysis Method:
Analysis Description:
EPA-504.1(PREP)
QC Prep:V29170
Associated Lab Samples: 98099, 98100
LRB-V29170 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
01/26/23 10:140.0200< 0.0200µg/L1,2-Dibromoethane
LCS-V29170 LCSD-V29170Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.230 92.01160.2900.250µg/L1,2-Dibromoethane 70-130 23.0*20.0
V 98100-DUP-V29170Duplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 01/26/23 12:010.9< 0.0207< 0.0207µg/L1,2-Dibromoethane
V 98099-MS-V29170Matrix Spike
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
0.258 1000.258< 0.0206µg/L1,2-Dibromoethane 70-130
Page 14 of 17* QC Fail Date:02/03/2023 05:16 PM
Page 105 of 111
Quality Control Data
23-020-0019Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Massachusetts EPH
MADEP-EPH
V29350QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAEPH (Prep)
QC Prep:V29185
Associated Lab Samples: 98099, 98100
LRB-V29185 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
01/31/23 10:3435028.2<28.2µg/LAliphatic C9-C18
01/31/23 10:34500124<124µg/LAliphatic C19-C36
01/31/23 10:3425061.2<61.2µg/LAromatic C11-C22
01/31/23 10:342-Fluorobiphenyl (S)112 40-140
01/31/23 10:342-Bromonaphthalene (S)109 40-140
01/31/23 10:34Chlorooctadecane (S)91.5 40-140
01/31/23 10:34OTP Surrogate (S)92.5 40-140
LCS-V29185 LCSD-V29185Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
418 69.665.5393600µg/LAliphatic C9-C18 40-140 6.1 50.0
798 99.791.5732800µg/LAliphatic C19-C36 40-140 8.6 50.0
1750 10393.515901700µg/LAromatic C11-C22 40-140 9.5 50.0
1071022-Fluorobiphenyl (S)40-140
1061012-Bromonaphthalene (S)40-140
98.098.5Chlorooctadecane (S)40-140
86.581.0OTP Surrogate (S)40-140
Page 15 of 17Date:02/03/2023 05:16 PM
Page 106 of 111
Quality Control Data
23-020-0019Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V29084QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V29083
Associated Lab Samples: 98099
LRB-V29083 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
01/23/23 13:0650.011.5<11.5µg/LAliphatic C5-C8
01/23/23 13:0650.025.8<25.8µg/LAliphatic C9-C12
01/23/23 13:0650.04.02<4.02µg/LAromatic C9-C10
01/23/23 13:062,5-Dibromotoluene (FID) (S)89.7 70-130
01/23/23 13:062,5-Dibromotoluene (PID) (S)86.3 70-130
LCS-V29083 LCSD-V29083Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
346 115112335300µg/LAliphatic C5-C8 70-130 3.2 50.0
346 115117352300µg/LAliphatic C9-C12 70-130 1.7 50.0
112 112109109100µg/LAromatic C9-C10 70-130 2.7 50.0
81.581.02,5-Dibromotoluene (FID) (S)70-130
77.077.92,5-Dibromotoluene (PID) (S)70-130
Page 16 of 17Date:02/03/2023 05:16 PM
Page 107 of 111
Quality Control Data
23-020-0019Report No:
Project Description:
Client ID:Geological Resources, Inc.
Former Philbecks Amoco
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V29105QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V29104
Associated Lab Samples: 98100
LRB-V29104 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
01/24/23 10:2950.011.5<11.5µg/LAliphatic C5-C8
01/24/23 10:2950.025.8<25.8µg/LAliphatic C9-C12
01/24/23 10:2950.04.02<4.02µg/LAromatic C9-C10
01/24/23 10:292,5-Dibromotoluene (FID) (S)88.5 70-130
01/24/23 10:292,5-Dibromotoluene (PID) (S)86.6 70-130
LCS-V29104 LCSD-V29104Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
336 112111333300µg/LAliphatic C5-C8 70-130 0.8 50.0
353 118119356300µg/LAliphatic C9-C12 70-130 0.8 50.0
117 117115115100µg/LAromatic C9-C10 70-130 1.7 50.0
87.185.42,5-Dibromotoluene (FID) (S)70-130
79.978.92,5-Dibromotoluene (PID) (S)70-130
Page 17 of 17Date:02/03/2023 05:16 PM
Page 108 of 111
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:23-020-0019
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 1.8C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)?Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:01/20/2023 16:18:29
Special precautions or instructions included?
Comments:
Page 109 of 111
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APPENDIX D
Historical Slug Test Data

APPENDIX E
AFVR Event Data Sheet and Disposal Manifest
Site Name:12594
Extraction Well(s):2"
4
Date :12/13/22 Start Time :8:00 End Time :16:00
Frequency
(min)Time Vacuum
(in. of Hg)
Exhaust
Velocity
(ft/min)
Temperature
(°F)
Rel. Humidity
(%)
OVA
(ppm)
0 8:00 26.0 457 46.5 97.5 143.0
15 8:15 26.0 488 49.3 98.8 267.0
30 8:30 26.0 490 69.8 100.0 497.0
45 8:45 26.0 451 81.9 99.2 380.0
60 9:00 26.0 537 100.4 100.0 198.0
75 9:15 26.0 479 81.9 100.0 177.0
90 9:30 26.0 442 89.4 98,9 352.1
105 9:45 26.0 412 81.7 99.2 399.1
120 10:00 26.0 502 92.4 100.0 378.4
150 10:30 26.0 436 107.8 89.7 601.8
180 11:00 26.0 316 88.7 94.8 395.7
210 11:30 26.0 345 90.2 97.2 412.2
240 12:00 26.0 313 93.3 72.9 372.3
270 12:30 26.0 361 103.2 85.2 351.5
300 13:00 26.0 359 99.2 90.1 306.9
330 13:30 26.0 254 95.1 82.3 336.2
360 14:00 26.0 330 101.0 89.7 341.8
390 14:30 26.0 389 110.2 92.3 378.4
420 15:00 26.0 348 115.4 95.6 307.5
450 15:30 26.0 351 120.7 96.3 320.1
Total Fluids Recovered (in gallons) :
Total Product Recovered (in gallons) :
Note: Take all the readings listed below every 15 minutes for the first 2 hours of the AFVR and every
30 minutes thereafter.
100 cfm @ 27" HgBlower Specifications For Vacuum Truck (e.g: 2500 cfm @ 24 in. of Hg):
1.04
AGGRESSIVE FLUID VAPOR RECOVERY EVENT - DATA SHEET
Diameter of Exhaust Stack (inches) :
Cert
Geological Resources, Inc.
Test Conducted By (AFVR Contractor):
Test Supervised By (Consultant):
463
Former Philbeck's Amoco Incident Number:
Inner Dia. of Well (inches):MW-1A
Site Name:12594
Extraction Well(s):2"
4
Date :12/13/22 Start Time :8:00 End Time :16:00
100 cfm @ 27" HgBlower Specifications For Vacuum Truck (e.g: 2500 cfm @ 24 in. of Hg):
AGGRESSIVE FLUID VAPOR RECOVERY EVENT - DATA SHEET
Diameter of Exhaust Stack (inches) :
Cert
Geological Resources, Inc.
Test Conducted By (AFVR Contractor):
Test Supervised By (Consultant):
Former Philbeck's Amoco Incident Number:
Inner Dia. of Well (inches):MW-1A
AFVR Well Obs. Well 1 Obs. Well 2 Obs. Well 3 Obs. Well 4
Well Name MW-1A
Diameter 2"Distance from
AFVR Well (ft)0
Frequency
(min)Time MW-1A
Pre AFVR 7:40
60 9:00
120 10:00
180 11:00
240 12:00
300 13:00
360 14:00
420 15:00
460 15:40
16:00
Note: Record water levels in Vacuum Well at start and end of AFVR. Record Water Levels in a few
Observation Wells periodically (hourly during event) and at end of event.
Depth to Water Measurements (in feet)
Site Name:12594
Extraction Well(s):2
4
Date:Start Time:End Time :
Date Time (in. Hg)
Velocity
(ft/min)
Pipe ID
(in.)
Temp
(°F)
Rel Humid
(%)
Water Vapor
(%)
Flow
(DSCFM)
8:00 26.0 457 4 46.5 97.5 0.0068 41
8:15 26.0 488 4 49.3 98.8 0.0076 44
8:30 26.0 490 4 69.8 100.0 0.0162 42
8:45 26.0 451 4 81.9 99.2 0.0244 37
9:00 26.0 537 4 100.4 100.0 0.0452 42
9:15 26.0 479 4 81.9 100.0 0.0246 40
9:30 26.0 442 4 89.4 98,9 0.3125 25
9:45 26.0 412 4 81.7 99.2 0.0242 34
10:00 26.0 502 4 92.4 100.0 0.0349 40
10:30 26.0 436 4 107.8 89.7 0.0514 34
11:00 26.0 316 4 88.7 94.8 0.0293 26
11:30 26.0 345 4 90.2 97.2 0.0315 28
12:00 26.0 313 4 93.3 72.9 0.0262 25
12:30 26.0 361 4 103.2 85.2 0.0422 28
13:00 26.0 359 4 99.2 90.1 0.0392 28
13:30 26.0 254 4 95.1 82.3 0.0314 20
14:00 26.0 330 4 101.0 89.7 0.0414 26
14:30 26.0 389 4 110.2 92.3 0.0571 30
15:00 26.0 348 4 115.4 95.6 0.0698 26
15:30 26.0 351 4 120.7 96.3 0.0831 26
NOTES
Qstd = (1-Water Vapor) * velocity * (PI * (diameter/24)^2) * (528°R/(Temp + 460)) (DSCFM)
Vacuum = The level of vacuum being applied should be recorded from the vacuum truck tank (inches of Hg)
Velocity = The rate at which air flows is measured at the blower discharge piping (anemometer or pitot tube)
Pipe ID = The inside diameter of the blower discharge piping (from the vacuum truck)
Temperature = The temperature of the air stream exiting the blower discharge piping (dry bulb temp., in deg.°F)
Relative humidity = The % relative humidity of the air stream exiting the blower discharge piping
Water Vapor in % = Pounds of water per pound of dry air, derived from the Psychrometric chart
(temp Vs relative humidity)
DSCFM = Dry Standard Cubic Feet Per Minute
12/13/22
922Site Elevation (feet):
16:008:0012/13/22
AGGRESSIVE FLUID VAPOR RECOVERY EVENT - CALCULATIONS
Former Philbeck's Amoco
Blower Specifications For Vacuum Truck (e.g: 2500 cfm @ 24 in. of Hg):100 cfm @ 27" Hg
Test Conducted By (AFVR Contractor):
Test Supervised By (Consultant):
Cert
Geological Resources, Inc.
Diameter of Exhaust Stack (inches) :
Inner Dia. of Well (inches):MW-1A
Incident Number:
Site Name:12594
Extraction Well(s):2
4
Date:Start Time:End Time :
922Site Elevation (feet):
16:008:0012/13/22
AGGRESSIVE FLUID VAPOR RECOVERY EVENT - CALCULATIONS
Former Philbeck's Amoco
Blower Specifications For Vacuum Truck (e.g: 2500 cfm @ 24 in. of Hg):100 cfm @ 27" Hg
Test Conducted By (AFVR Contractor):
Test Supervised By (Consultant):
Cert
Geological Resources, Inc.
Diameter of Exhaust Stack (inches) :
Inner Dia. of Well (inches):MW-1A
Incident Number:
Elapsed Time
(min)
Flow
(DSCFM)
PPM
measured
(ppm)
K
(#C-gas)PPMg Cg:m
(mg/dsm^3)
Cg
(lb/dscf)
PMRg
(lb/hr)
PMR
(lb)
0 41 143.0 4 572.0 3,041.79 0.00018990 0.47 0.00
15 44 267.0 4 1,068.0 5,679.43 0.00035457 0.93 0.23
30 42 497.0 4 1,988.0 10,571.83 0.00066000 1.66 0.42
45 37 380.0 4 1,520.0 8,083.09 0.00050463 1.13 0.28
60 42 198.0 4 792.0 4,211.72 0.00026294 0.67 0.17
75 40 177.0 4 708.0 3,765.02 0.00023505 0.56 0.14
90 25 352.1 4 1,408.4 7,489.62 0.00046758 0.71 0.18
105 34 399.1 4 1,596.4 8,489.37 0.00052999 1.09 0.27
120 40 378.4 4 1,513.6 8,049.06 0.00050250 1.22 0.30
150 34 601.8 4 2,407.2 12,801.06 0.00079917 1.61 0.80
180 26 395.7 4 1,582.8 8,417.05 0.00052548 0.81 0.41
210 28 412.2 4 1,648.8 8,768.03 0.00054739 0.92 0.46
240 25 372.3 4 1,489.2 7,919.30 0.00049440 0.75 0.38
270 28 351.5 4 1,406.0 7,476.86 0.00046678 0.79 0.40
300 28 306.9 4 1,227.6 6,528.16 0.00040755 0.69 0.35
330 20 336.2 4 1,344.8 7,151.41 0.00044646 0.55 0.27
360 26 341.8 4 1,367.2 7,270.53 0.00045390 0.71 0.35
390 30 378.4 4 1,513.6 8,049.06 0.00050250 0.89 0.45
420 26 307.5 4 1,230.0 6,540.92 0.00040835 0.64 0.32
450 26 320.1 4 1,280.4 6,808.94 0.00042508 0.65 0.33
Total emissions (gal): 1.04 Total emissions (lbs): 6.50
NOTES
PPM measured = Actual measurements (ppm) taken with a OVA or TVA at the blower discharge piping
K = Number of carbons in calibration gas: (Methane K = 1, or Propane K = 3, or Isobutylene K = 4, or Hexane K = 6)
PPMg = PPMv, Volumetric concentration as gasoline emission, dry basis at STP
Cg:m = mg/dsm3, mass concentration of gasoline emission
Mg = 128 mg/mg-mole, molecular weight of gasoline (this value may vary depending on contaminant)
K3 = 24.07 dsm^3/1E6 mg-mole, mass to volume conversion factor at STP
Cg = lb/dcsf, mass concentration of gasoline emission, dry basis at STP
PMRg = lb/hr, pollutant mass removal rate of gasoline emission
PMR = pollutant mass removal of gasoline emission over time
EQUATIONS
PPMg = PPM measured * K
Cg:m = PPMg * (Mg / K3)
Cg = Cg:m * 62.43E-09 lb-m^3/mg-ft^3
PMRg = Cg * Qstd * 60 min/hr
PMR = PMRg * ((T2 - T1) / 60)
Total emmissions (gal) = Total emmissions (lbs)/6.25

APPENDIX F
Well Permit, Well Construction Records, and Subsurface Logs

North Carolina Department of Environmental Quality | Division of Water Resources
Mooresville Regional Office | 601 East Center Avenue, Suite 301 | Mooresville, NC 28115
704.663.1699
October 31, 2022

Ms. Kay Piercy (via email)
Arey Oil Company, Inc.
1906 E. Dixon Blvd.
Shelby, NC 28152

RE: Monitoring Well Construction Permit
Permit # WM0301238
Former Philbeck’s Amoco
1319 S. Post Rd., Shelby
Cleveland County

Dear Ms. Piercy,

In accordance with your completed application received on October 28, 2022, we are forwarding herewith
Monitoring Well Construction Permit Numbered WM0301238 and issued for the construction of two (2)
monitoring wells located near the subject site in Shelby, Cleveland County.

This Permit will be effective for one year from the date of issuance and shall be subject to the conditions and
limitations as specified therein.

Should you have any questions, please contact Edward Watson at [phone], or by email at
[e-mail].

Sincerely,

Andrew H. Pitner, P.G. Interim Regional Supervisor
Mooresville Regional Office
Water Quality Regional Operations Section
Division of Water Resources

CC: WQROS, Central Office (via Laserfiche)
Sam McKay, Geological Resources (via email)

NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY DIVISION OF WATER RESOURCES
PERMIT FOR THE CONSTRUCTION OF A MONITORING WELL
In accordance with the provisions of Article 7, Chapter 87, North Carolina General Statutes, and other applicable Laws, Rules and Regulations. PERMISSION IS HEREBY GRANTED TO
Arey Oil Company, Inc. (Geological Resources, Inc. as Agent)

FOR THE CONSTRUCTION OF A MONITOR WELL SYSTEM consisting of two (2) monitoring wells owned by Arey Oil Company, Inc. at the subject site located at 1319 South Post Road, Shelby, Cleveland County. This Permit is issued in accordance with the application received on October 28, 2022, in conformity with specifications and supporting data, all of which are filed with the Department of Environmental Quality and are considered integral parts of this Permit. This Permit is for well construction only and does not waive any provision or requirement of any other applicable law or
regulation. Construction of any well under this Permit shall be in strict compliance with the North Carolina Well Construction Regulations and Standards (15A NCAC 02C .0100), and other State and Local Laws and regulations pertaining to well construction. If any requirements or limitations specified in this Permit are unacceptable, you have a right to an adjudicatory hearing upon written request within 30 days of receipt of this Permit. The request must be in the form of a written petition conforming to Chapter 150B of the North Carolina General Statutes and filed with the Office of Administrative Hearings, 6714 Mail Service Center, Raleigh, North Carolina 27699-6714. Unless such a demand is made, this Permit is final and binding. This Permit will be effective for one year from the date of its issuance and shall be subject to other specified conditions, limitations, or exceptions as follows: 1. Issuance of this Permit does not obligate reimbursement from State trust funds, if these wells are being installed as part of an investigation for contamination from an underground storage tank or dry cleaner incident. 2. Issuance of this Permit does not supersede any other agreement, permit, or requirement issued by another agency. 3. The well(s) shall be located and constructed as shown on the attachments submitted as part of the Permit application. 4. Each well shall have a Well Contractor Identification Plate in accordance with 15A NCAC 02C .0108(o). 5. Well construction records (GW-1) for each well shall be submitted to the Division of Water Resources’ Information Processing Unit within 30 days of the well completion. 6. When the well is discontinued or abandoned, it shall be abandoned in accordance with 15A NCAC 02C .0113 and a well abandonment record (GW-30) shall be submitted to the Division of Water Resources’ Information Processing Unit within 30 days of the well abandonment. 7. If the well penetrates any water-bearing zone that contains contaminated waters, the upper three feet of the well shall be grouted within one day after the casing is set or the well abandoned. 8. Temporary wells must be permanently abandoned or converted to a permanent well within seven days (168 hours) of completion of drilling the borehole. Permit issued the 31st day of October 2022

FOR THE NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION _______________________________________________
Andrew H. Pitner, P.G., Assistant Regional Supervisor Division of Water Resources By Authority of the Environmental Management Commission Permit No. # WM0301238
Geological Resources, Inc.Phone:[phone]
3502 Hayes Road Fax:[phone]
Monroe, NC 28110
Project Former Philbeck's Amoco Project #5888
Address 1319 South Post Road, Shelby, NC 28151
Boring Number MW-12 Date Drilled
Sample Method Grab Drilling Method 6" SSA
Completion Details Well installed to 30' with 10' of screen, flush mounted
Driller Matt Steele License #4548-A Log By Jase C. Bowers
Boring Lab Sample PID GW USCS
Sample Type ppm depth class From To Color Moisture Odor
0 0.0 0.5
0.5 15.0 Red Dry None
2
4
6
8
10

12
14
15.0 25.0 Red Moist None
16
MW-12 Grab
18
20
22

24
25.0 30.0 White Saturated None
26
28

30 BORING TERMINATED. Well set to 30' with 10' of screen
Sandy Clay
Silty Clay
Depth (feet)
SUBSURFACE LOG
Soil Type
Silty Clay
Topsoil
LITHOLOGY
11/08/22
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
_______________
Matt Steele
4548-A
Geological Resources, Inc.
WM0301238
4
11/8/22 MW-12
Former Philbeck's Amoco 00-0-0000012594
1319 South Post Road, Shelby, NC 28151
Cleveland 2555158502
35.250494 81.506816
4
4
1
30
Not Measured
6
6" Solid Stem Augers
0 20 2 Sch 40 PVC
20 30 2 0.010 Sch 40 PVC
0 16 grout pour
16 18 bentonite pour
18 30 #2 Sand Pour
0 0.5 Topsoil
0.5 15 Dry Red Silty Clay
15 25 Moist Red Silty Clay
25 30 Saturated White Sandy Clay
Saturated at around 25' bgs
11/22/22
Geological Resources, Inc.Phone:[phone]
3502 Hayes Road Fax:[phone]
Monroe, NC 28110
Project Former Philbeck's Amoco Project #5888
Address 1319 South Post Road, Shelby, NC 28151
Boring Number MW-13 Date Drilled
Sample Method Grab Drilling Method 6" SSA
Completion Details Well installed to 30' with 10' of screen, flush mounted
Driller Matt Steele License #4548-A Log By Jase C. Bowers
Boring Lab Sample PID GW USCS
Sample Type ppm depth class From To Color Moisture Odor
0 0.0 0.5
0.5 5.0 Light Brown Dry None
2
4
5.0 18.0 Red Dry None
6
8
10

12
14
16 MW-13 Grab

18 18.0 25.0 Light Brown Moist None
20
22

24
25.0 30.0 Red Saturated None
26
28

30
SUBSURFACE LOG
Depth (feet)LITHOLOGY
Soil Type
Asphalt
Silty Sand
Silt
Silt
11/08/22
BORING TERMINATED. Well set to 30' with 10' of screen
Silt
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
_______________
Matt Steele
4548-A
Geological Resources, Inc.
WM0301238
4
11/8/22 MW-13
Former Philbeck's Amoco 00-0-0000012594
1319 South Post Road, Shelby, NC 28151
Cleveland 2555158502
35.250494 81.506816
4
4
1
30
Not Measured
6
6" Solid Stem Augers
0 20 2 Sch 40 PVC
20 30 2 0.010 Sch 40 PVC
0 16 grout pour
16 18 bentonite pour
18 30 #2 Sand Pour
0 0.5 Asphalt
0.5 5 Dry light Brown Silty Sand
5 18 Dry Red Silt
18 25 Moist light Brown Silt
25 30 Saturated Red Silt
Saturated at around 25' bgs
11/22/22