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HomeMy WebLinkAbout8202_Surry_MtAiry_MSWLF_CDLF_May2024GW_FID1903132_20241017Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
DENR USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #:
NC DENR I I Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
Smith Gardner, Inc.
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Seth C. Rickerts, P. G.
E-mail: seth@smithgardnerinc.com
Phone: 919-828-0577 x135
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Surry County Closed C&D and 237 Landfill Road Mt. Airy, NC 27030 86-02 .1600 April 29 - May 2, 2024
Closed MSW Landfill
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring ❑X Detection Monitoring ❑X Assessment Monitoring ❑X Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells ❑
Leachate monitoring data El
water monitoring data
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Seth C. Rickerts, P.G. Project Geologist 919-828-0577 x 135
ftt tt h* Name (Print) Title (Area Code) Telephone Number
Stan G. ItZ 1 , 10/17/2024 Affix NC Licensed/ Professional Geologist Seal
Date
14 N. Boylan Ave, Raleigh, NC 27603
Facility Representative Address
F1370
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009
O10,
SEAL
2758 10�7�2024
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Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
May 2024 Semi -Annual Groundwater Monitoring, Report
Surry County Closed C&D/MSW Landfill Facility
Solid Waste Permit No. 86-02
Prepared for:
Surry County Closed CRD/MSW Landfill
237 Landfill Road
Mt. Airy, North Carolina
r
N IRC
1770
October 2024
Prepared by:
NEEIC NE.F-13?9 (ENGINEERING)
SMITH+GARONER
14 N. Boylan Avenue, Raleigh NC 27603 1 919.828EW?
O 2024 Smith Gardner, Inc.
This document is intended for the sole use of the client for which it was prepared and
for the purpose agreed on by the client and Smith Gardner, Inc.
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
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May 2024 Semi -Annual Groundwater Monitoring Report
Surry County Landfill Facility
Solid Waste Permit No. 86-02
Prepared For:
Surry County Closed C&D/MSW Landfill
Mt. Airy, North Carolina
S+6 Project No. Surry-21-1
E
1`Z.hi e.i V {QVLi�l�ie.0
DOCUSigned by:
5DD73DOAEAB2442...
Daniel J. Pantaleo
Environmental Technician
DocuSigned by:
E
can G. ItZ 1 ,
3B8305C978EA4E6...
Seth C. Rickerts, P.G.
Project Geologist
October 2024
� 4 ��Ei'v's"•• ri'�
SEAL ;v
10/17,
a 2758
NC LIC NU-00 (ENGINEERING)
SMITH GARDNER
14 N. Boylan Avenue, Raleigh NC 27603 1 Y]9.e28,0577
024
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Surry County Closed CS0/MSW Landfill
Mt. Airy, North Carolina
May 2024 Semi -Annual Groundwater Monitoring Report
Table of Contents
Paqe
1.0
INTRODUCTION--------------------------------------------------------------------------------------------------------- 1
2.0
BACKGROUND...........................................................................................................1
3.0
SITE GEOLOGY........................................................................................................... 1
4.0
MONITORING NETWORK............................................................................................2
5.0
SAMPLING PROCEDURES..........................................................................................2
6.0
FIELD AND LABORATORY RESULTS.......................................................................... 2
6.1 Field Results........................................................................................................... 2
6.2 Laboratory Analysis................................................................................................ 3
6.3 Laboratory Results................................................................................................. 3
6.3.1 Inorganic Constituents................................................................................ 3
6.3.2 Organic Constituents.................................................................................. 3
6.3.3 Surface Water Results................................................................................ 4
6.3.4 PFAS Analytical Results.............................................................................. 4
7.0
GROUNDWATER CHARACTERIZATION....................................................................... 4
8.0
CONCLUSIONS ........................................................................................................... 5
FIGURES
Figure 1 Potentiometric Surface Map
TABLES
Table 1
Monitoring Network Details
Table 2
Field Parameter Data
Table 3
Detected Constituents
Table 4
PFAS Detections
Table 5
Groundwater Velocity
APPENDICES
Appendix A Monitoring Well Information
Appendix B Laboratory Analytical Report
Surry County Closed CGO/MSW landfill May 2024 Semi -Annual Groundwater Monitoring Report
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October 2024 Table of Contents Page iii
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1.0 INTRODUCTION
Smith Gardner, Inc. (S+G) is pleased to present the semi-annual sampling report for the Surry
County Closed C&D over MSW Landfill facility, Solid Waste Permit #86-02 Located at 237 Landfill
Road in Mt. Airy, North Carolina. The Surry County Closed C&D/MSW Landfill is required to
submit semi-annual groundwater monitoring reports in accordance with Solid Waste Section
Rule 15A NCAC 13B .1632. This report presents the semi-annual groundwater monitoring results
for the event conducted April 30 - May 2, 2024, and includes a field procedure summary,
Laboratory analyses, and groundwater characterization for the facility.
2.0 BACKGROUND
Groundwater quality has been monitored at this facility at least semi-annually since 1989 with
historical data available since 1994. The Surry County Closed C&D/MSW Landfill Facility consists
of a two -unit unlined MSW landfill overlain by lined C&D landfill. C&D waste was accepted at this
Landfill until it's closing on June 1, 2008. To betterassess historical compliance exceedances, two
documents were drafted by MESCO, Inc. as requested by NCDEQ:
An Alternative Source Demonstration (ASD), which established Site Maximum Allowable
Contaminate (SMAC) regulatory compliance levels for three metals (cadmium, cobalt, vanadium),
was approved by the NCDEQ on April 20, 2020 (FID:1395468). The compliance levels calculated in
the ASD are used in this report as the new exceedance levels for their respective constituents.
A corrective action plan' to remediate volatile organic compounds (VOCs) in groundwater is
ongoing within three areas of concern (AOC) as described in the most recent Corrective Action
Evaluation Report (CAER)2, these three areas are MW-11, "Northern", and "Southern". Enhanced
bioremediation via substrate and tracer injection was implemented in May 2011 with assessment
and MNA monitoring to continue at select wells as described in the Water Quality Monitoring
Plana. The CAER prepared in 2019 evaluated the effectiveness of remedial actions to date and
ongoing monitored natural attenuation. This report indicated that MNA is an effective and ongoing
strategy for the site. Notwithstanding any changes to NCDEQ requirements, a third
comprehensive CAER is to be submitted to the SWS on or before April 1, 2025.
3.0 SITE GEOLOGY
The Surry County Closed C&D/MSW Landfill, located in the Piedmont -Blue Ridge geologic
province within the Inner Piedmont Belt, is underlain by the Banded Gneiss Formation. This
formation as described in the Geologic Map of North Carolina (1985) is "Interlayered with calc-
silicate rock, metaconglomerate, amphibolite, sillimanite-mica schist, and granitic rock"
Located in the western portion of the piedmont physiographic province, elevations range from
930 feet above mean sea level along the Stoney Creek to 1170 ft amsl at the peak of the landfill.
Unnamed creeks and streams run along the eastern and western sides of the landfill, flowing
south into the Stoney Creek. Flowing southeast, the Stoney Creek divides the landfill facility
Corrective Action Plan, March 2010, MESCO, FID 73320
'Corrective Action Evaluation Report, April 2019, MESCO, F I D 1320112
'Water Quality Sampling and Analysis Plan, April 2019, MESCO FID1320110
Surry County Closed CBD/MSW Landfill May 2024 Semi -Annual Groundwater Monitoring Report
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between the closed C&D/MSW units and the active MSW units (Permit #86-06) before discharging
into the Ararat River.
4.0 MONITORING NETWORK
The groundwater monitoring network comprises 17 total well monitoring locations (MW-1, MW-
3R, MW-6, MW-7, MW-9, MW-11, MW-12S, MW-13, MW-14, MW-15, MW-16, MW-17, MW-19, MW-
20, MW-21, MW-22, and MW-23) with seven wells associated with the assessment network (MW-
1, MW-9, MW-11, MW-14, MW-15, MW-16, and MW-21), and four surface water locations (SW-1,
SW-2, SW-3, SW-4), located both up and downstream from the landfill on Stoney Creek.
Monitoring well MW-1 serves as the background well for the site, however, it should be noted that
MW-11 is hydraulically upgradient of the waste units. Six injection wells are also present onsite
OW-1 - IW-6) however, these wells are not monitored due to the presence of injectant residue.
Table 1 presents the monitoring network details including well construction information and the
primary monitoring focus. Sampling locations are shown on Figure 1. Monitoring well
construction information is presented in Appendix A.
5.0 SAMPLING PROCEDURES
The sampling event, performed by Smith Gardner, Inc. personnel April 30 - May 2, 2024, was
conducted in accordance with the approved site Water Quality Monitoring Plano. Sampling
methods followed the protocol outlined in the North Carolina Water Quality Monitoring Guidance
Document' for Solid Waste Facilities (NCDENR, DWM). The depth to water in each well was
gauged prior to sampling. Groundwater elevation data is presented in Table 1.
Sampleswere collected in laboratory prepared containers forthe specified analytical procedures.
Samples were collected via new factory sealed HDPE bailers. Surface water samples were
grabbed from previously determined monitoring locations.
Groundwater samples were properly preserved (according to their specified method), placed on
ice, and transported to a NC certified laboratory facilitywithin the specified holding times for each
analysis.
6.0 FIELD AND LABORATORY RESULTS
6.1 Field Results
Temperature, pH, turbidity and specific conductance were measured in the field via direct
read instruments. In general, field parameter results remained consistent with
previously reported sampling events. Field parameter results are summarized in Table 2.
Eight monitoring wells exhibited turbidities less than 10 NTUs during this event.
4 Water Quality Sampling and Analysis Plan, April 2019, MESCO FID1320110
5 Solid Waste Section Guidelines for Groundwater, Soil and Surface Water Sampling, State of North Carolina, Department of
Environment and Natural Resources, Division of Waste Management, Solid Waste Section, Rev 4-08.
Surry County Closed CBD/MSW Landfill May 2024 Semi -Annual Groundwater Monitoring Report
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6.2 Laboratory Analysis
Collected samples were transported to Waypoint Laboratories, Inc., a North Carolina
certified laboratory (NC Certification #377351 located in Charlotte, NC for analysis. All
monitoring wells and surface water locations were analyzed for Appendix I metals, VOCs,
and 1,4 dioxane. Additionally, monitoring wells included in the assessment network were
analyzed for Appendix 11 metals and VOC's. Laboratory analysis was conducted via the SWS
approved methods listed in the laboratory report.
Samples were also analyzed by Eurofins Environment Testing for PFAS constituents by
draft EPA Method 1633 in response to recent NCDEQ requirements to sample all
monitoring wells at landfills for this list of constituents. Analysis for PFAS constituents
was performed via the EPA approved methods identified in the laboratory report.
The laboratory analytical report is included as Appendix B.
6.3 Laboratory Results
Laboratory analytical results were compared with the 15A NCAC 2L 0200 Groundwater
Standard (2L Standard), Solid Waste Section Groundwater Protection (GWP) Standards,
and 2020 Site specific Maximum Allowable Concentrations (SMACs)6. Surface water
results were compared with the NCAC 2B Standard for Class C waters (213 Standard).
Most constituents with detectable concentrations were reported as "J-Values". Waypoint
Laboratory defines "J-values" as detected above the method detection limit but below the
Reporting Limit; therefore, result is an estimated concentration. Reporting Limits are
defined in the laboratory analytical report, included as Appendix B.
6.3.1 Inorganic Constituents
Four inorganic constituents were detected in collected samples above its 2L
Standard when analyzed for total metals this event:
• Cadmium (MW-9);
• Chromium (MW-13, MW-14, MW-15, MW-19, MW-20, and, MW-23);
• Cobalt (MW-3R, MW-6, MW-7, MW-9, MW-11, MW-13, MW-14, MW-16,
MW-17, MW-19, and MW-20); and
• Vanadium (MW-15, and MW-19).
Detected inorganic constituents are presented in Table 3. These constituents are
Likely influenced by the elevated sample turbidities. Elevated turbidity can bias
analytical results for inorganic constituents high, due to the presence of metals
naturally in soils. HDPE single use bailers were used during this event to
minimize possible impact to detected PFAS concentrations due to sampling
b Email from SWS to Jessica Montgomery Re: Alternative Source Demonstration -Addendum Total Metals,
04/07/2020 (FID 1395428)
Surry County Closed CBD/MSW Landfill May 2024 Semi -Annual Groundwater Monitoring Report
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methods. Additional efforts will be made during future sampling events to
further reduce sample turbidity as HDPE bailers will continue to be used.
6.3.2 Organic Constituents
Five volatile organic constituents were detected above their 2L Standards in
samples collected this event:
• 1,2-Dichloroethane (MW-3R, MW-15, and MW-16);
• 1,2-Dichloropropane (MW-16);
• 1,4-Dioxane (MW-9, MW-13, MW-17, and MW-21);
• Benzene (MW-3R, and MW-20);
• Vinyl chloride (MW-3R, MW-9, MW-15, MW-16, and MW-20).
Organic constituent detections are summarized in Table 3.
6.3.3 Surface Water Results
One Inorganic constituent was detected in surface water samples collected this
event that exceeded its NC213 standard:
• Cobalt (SW-2 and SW-3).
No collected surface water samples contained organic constituents at
concentrations above their 2B Standard this event. Available analytical results are
summarized in Table 3.
6.3.4 PFAS Analvtical Results
Per- and Polyfluoroalkyl Substances (PFAS) are required to be sampled at all
solid waste sites after July 1, 2023 as directed in a March 13, 2023 NCDEQ memo
titled "PFAS Monitoring Requirements for Solid Waste Sanitary Landfills". This
semi-annual water quality monitoring report represents the second report for
the Surry County MSW Landfill where PFAS analysis was performed
During this event PFAS constituents were detected in monitoring wells and
surface water locations. All detected PFAS constituents are summarized in
Table 4.
7.0 GROUNDWATER CHARACTERIZATION
A potentiometric surface map was prepared from groundwater data collected during this event.
Data indicates groundwater is flowing generally to the south and southeast towards Stoney Creek
and the Ararat River, which is consistent with groundwater flow patterns previously detected for
the site. The potentiometric surface map is included as Figure 1.
Surry County Closed CBD/MSW Landfill May 2024 Semi -Annual Groundwater Monitoring Report
October 2024
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Groundwater flow velocities during the sampling event were calculated for monitoring wells using
the equation:
V = Ki/n
where: K = hydraulic conductivity
i = groundwater gradient
n = effective porosity
Groundwater flow velocities average at 1.04xl0-' feet/day. These calculated flow velocities are
included in Table 5.
8.0 CONCLUSIONS
When compared to historic data and previous groundwater monitoring reports, the Surry County
C&D/MSW Landfill shows generally stable groundwater quality. The organic constituents that are
detected are primarily chlorinated solvents and their associated daughter products. The presence
of these daughter products indicate attenuation via reductive dichlorination is ongoing and
monitored natural attenuation continues to be a viable mechanism of remediation at the site. This
event exhibited an atypical number of inorganic constituent exceedances, this can most likely be
attributed to elevated sample turbidities due to the use of bailers as the primary sampling
method. Elevated turbidity can bias inorganic analytical results high due to metals naturally
occurring in soils.
As mentioned above, this is the second monitoring event in which PFAS constituents were
analyzed at the Closed C&D / MSW Surry County Landfill. PFAS constituents were detected in
samples collected during this event.
The next semi-annual sampling event is tentatively scheduled for Fall 2024. Results will be
reported to NCDEQ following laboratory analytical data review.
Surry County Closed CBD/MSW Landfill May 2024 Semi -Annual Groundwater Monitoring Report
October 2024
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FIGURE
May 2024 Semi -Annual Monitoring Report
Surry County Closed CRD/MSW landfill
NC Solid Waste Permit No. 86-02
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w , LEGEND
--milt Z*tip I PROPERTY LINE
;1 WASTE BOUNDARY
� � / / / �7 � //// /�7 \ \ POTENTIOMETRIC CONTOUR
PROP - \ \ _ \ 1 _ \ / / \\ \\ \ (DASHED WHERE INFERRED)
\ DIRECTION OF GROUNDWATER FLOW
TOC=1025.80 / L� \�` I \��\�\\ \\� \ I I s \ CDMW -1 C&D MONITORING WELL
DTW=13.06 MW-1 MSW MONITORING WELL
\ o�- /�\ \\\\\\\\\ / ///� GWE=1012.74\\\\\\\\\ \\�\\\ \ \\
\ _ � \ / - - - \\ \\ \ \ �\ SW-1 A SURFACE WATER MONITORING LOCATION
-- IW-1 INJECTION WELL
L____ \\ \ \\\ \\\\ \ MW-13 /\
\\��\ \�\\ \TOC=1008.4a MGP-1 METHANE GAS PROBE
/I))) 1 \ \ ` \ \ ��. DTW=25.89
I I \ 1 � ,� / / /j// / / I \ TOC TOP OF CASING ELEVATION
ivy- IN GWE=982.59 DTW DEPTH TO WATER MEASUREMENT
J// \ _- i , /�/� /�_ - \ \ /� •\\ OWE GROUNDWATER ELEVATION
_ - - - J j / / L� \ \�\� \\\\� J MW-21 (*INDICATES NOT USED FOR CONTOURING)
_MG - R� \ l' \�-_TOC=965.36 �'/ % j j (..lam /,�/ ,�////� e- \
_DTW=5.83
IW-2, \ �\ \ = GWE=959.53� / MW-23 =
IIII\TOC-955.31 _-11\���
1 I J ( (MW-1 \ \\DTW=7.46 I I
TOC=1134.35 r`� \\ ` \�\\ \\ / \ 1� \� \GWE=947.85- \II IIII I I 1
DTW=24.22 \
1\ GWE=1110.13' 1 \\\ \ \ \ \\\\\\ \\ I
I \l \\ I/ \ TOC=1018.80
��DTW=27.22
(MW-11 1 GP 4GWE=991.58 \ I ) �� ) 1 \\\\V\\\\\\\\
I ITOC--
1151.80 -6 SW-4
\\\ \
DTW=21.92
- I\� (\l I \ IW-5\ MW_ 15I \\
9.88 TOC=1075.96GWE=112\\\\l DTW=52.82
GWE=1023.14'/
/
MGP-5;///
" � s j/
iavS -2 MW-22TOC=946.27
OC=953.40� DTW=9.60 \1 I \
1\ �SW-C�
DTW=5.86 \
.GWE=936.67, ij
MGP- // / SW-3'jGWE=947.54=
\ \\ \ \\ \
TOC=1073.50\\\\\\\\
DTW=11.20 TOC=965.43//l/���I
\ \ \ \\\ -
NOTES GWE-- \ - 1062.30 MW-6 ___ - �� _ \ \ \\ ) DTW-9.39
1. DEPTH TO WATER MEASUREMENTS TAKEN BY S+G PERSONNEL �� � TOC=1067.67 \ \� ��I �LL`-GWE=956,04'
IN APRIL/MAY OF 2024. 1AW-9
DTW=22.34
GWE=1045.33 MW-3R
DTW=31.88 MW-20 / _\\ \ \
GWE=1062.19 T0C=1082.19 TOC=1017.50//�/\\= J �j j f (\\\\ \\\�\��\\\� \--\ \\ \
REFERENCES DTW=30.65 //��� �\- \ \\ O\
DTW=18.40 GWE=986.85
WINMW-16
1. EXISTING TOPOGRAPHY FROM DRAG "CONSTRUCTION �� / /
GWE=1063.79 �� �TOC=999.54 \\ /�// % // / ✓/� 1)%)r) %Jf ) \ ��\\\\
PLAN -PHASE 4 OVERALL FACILITY PLAN" DATED 8/3/2018
PREPARED BY MUNICIPAL ENGINEERING SERVICES COMPANY, PA,
GARNER, NC.
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TABLES
May 2024 Semi -Annual Monitoring Report
Surry County Closed CRD/MSW landfill
NC Solid Waste Permit No. 86-02
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SMITH GARDNER
ByM
ate05'Z(Y2 24
"• .: .1►i
Well ID
Well
Installation
Date
Latitude
Longitude
Well
Diameter
(inches)
Total Well
Depth (ft.
bgs)
Ground
Surface
Elevation
amsl)
T()C
Elevation
(ft. amsl)
Depth to
Water"
(ft.)
Groundwater
Elevation
(ft. amsl)
Screen
Interval (ft.
b s
)(ft.
Screen Geology
MW-1
11/28/89
36.439211
-80.568133
2
40.0
1133.15
1134.35
24.22
1110.13
30-40
Clay
MW-3R
9/27/94
36.434725
-80.571989
2
101.0
1015.00
1017.50
30.65
986.85
86.0-101.0
Rock
MW-6
9/7/94
36.437431
-80.571067
2
29.7
1065.61
1067.67
22.34
1045.33
14.7-29.7
Rock
MW-7
8/23/94
36.438439
-80.570722
2
23.0
1071.50
1073.50
11.20
1062.30
8.0-23.0
Rock
MW-9
8/22/94
36.439289
-80.571508
2
43.8
1092.07
1094.07
31.88
1062.19
28.8-43.8
Rock
M W-11
8/ 15/ 94
36.441589
- 80.569558
2
40.0
1150.40
1151.80
21.92
1129.88
25.0- 40.0
Rock
MW-12S
5/31/01
36.435942
-80.567972
2
51.0
1023.25
1025.80
13.06
1012.74
11.0-51.0
Rock
MW-13
5/30/06
36.435036
-80.568183
2
35.8
1005.75
1008.48
25.89
982.59
20.8-35.8
Saprolite
MW-14
5/30/06
36.434267
-80.569239
2
48.0
1016.11
1018.80
27.22
991.58
33.0-48.0
Rock
MW-15
6/22/06
36.433797
-80.570467
2
57.0
1073.23
1075.96
52.82
1023.14
42.0-57.0
Rock
MW-16
6/21/06
36.434536
-80.572117
2
36.3
996.67
999.54
24.76
974.78
21.3-36.3
Rock
MW-17
6/01/07
36.433558
-80.572517
2
15.3
962.26
965.43
9.39
956.04
5.3-15.3
Rock
MW-19
6/01/07
36.432231
-80.570556
2
17.1
942.97
946.27
9.60
936.67
7.1-17.1
PWR
M W- 20
6/01/07
36.439025
- 80.571650
2
25.6
1079.12
1082.19
18.40
1063.79
10.6- 25.6
Rock
MW-21
6/01/07
36.434214
-80.568717
2
15.4
962.22
965.36
5.83
959.53
5.4-15.4
Saprolite/PWR
MW-22
6/01/07
36.432928
-80.571678
2
16.0
950.23
953.40
5.86
947.54
6.0-16.0
Saprolite
M W- 23
6/01/07
36.432828
- 80.569156
2
17.1
952.09
955.31
7.46
947.85
7.1-17.1
Sandy Si It
Notes: NM = Not measured
amsl = above mean sea level
bgs = below ground surface
Well construction information from well logs (provided in Appendix A)
* Depth to water measured from TOC
M Rgedsl Oa rd&de' piton rrj 2 Ci;aniAde' K tntcnrg Rpots1 SrryCirt� 7.,Qor g2Q24\ 3rryCi irty$irg2M4T@1es
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
SMITH GARDNER
Bf.Mf
0 . �. .
• t� :. 11
Well ID
pH (Std. Units)
Conductivity
(umhos)
Temperature
(Degrees C)
Turbidity (NTU)
DO
ORP
M W-1
5.45
96.6
22.3
7.57
- 0.2
77.6
M W- 3R
5.94
490.3
17.4
52.2
3.4
55.8
M W- 6
5.86
155.2
16
6.9
2.96
70.7
M W- 7
5.59
263
18.5
1.87
2.9
105.1
M W- 9
6.12
412.9
20.8
6.7
1.72
- 25.5
M W-11
5.22
142.7
21.3
2.42
- 0.02
90.6
M W-12S
7.05
271.7
16.1
36.6
0.65
61.3
M W-13
5.44
262
16.3
2.58
2.72
80.6
M W-14
5.37
93.2
17
21
3.09
45.6
M W-15
5.47
124.4
23.4
32.1
2.18
79.7
M W-16
5.56
554
21.6
40.6
2.24
20.9
M W-17
5.92
283.7
15.2
33
6.13
114.9
M W-19
5.41
44.8
15.6
122
4.98
85.5
M W- 20
5.74
241.3
16.7
71.9
1.5
83.4
M W- 21
5.13
174.8
20.7
9.89
3.78
- 71.3
M W- 22
5.71
267.2
15.7
9.87
1.27
110
M W- 23
5.63
56.7
15.7
305
5.66
70.9
SW-1
6.91
74
17.4
2.41
5.32
-10.1
SW-2
6.32
138.3
16.5
4.3
6.71
- 61.7
SW-3
6.86
312.8
18.7
30.6
- 0.03
14.4
SW-4
6.91
64.9
18.7
5.23
5.69
95
Data col Iected by S+G personnel
SW-1 was not sampled during this event due to dry conditions
Bold indicates samples with turbidity>10 NTUs
RRgeds\Gaxd&etan/tntcirr,2Gznivn taMxitairigPgmts\s-nyart)�7.,1�xirxg232A3nyQ^,' airig2324-Hdes
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
SMITH GARDNER
Monitorina Results
T2de3
Adytird Results
arryQv86-02
,otil29-MV2,2024
W.Iff
DtaMffa24
Sample Date
Units
NC21L
NC2B
SMAC
5/2/2024
4/30/2024
4/30/2024
4/30/2024
5/2/2024
5/2/2024
4/30/2024
4/30/2024
5/2/2024
5/2/2024
5/2/2024
4/30/2024
4/30/2024
4/30/2024
5/1/2024
4/30/2024
4/30/2024
5/1/2024
5/2/2024
5/2/2024
4/30/2024
StationName
MW-1
MW-3R
MW-6
MW-7
MW-9
MW-11
MW-12S
MW-13
MW-14
MW-15
MW-16
MW-17
MW-19
MW-20
MW-21
MW-22
MW-23
SW-1
SW-2
SW-3
SW-4
Inorganics
Arsenic
ug/I
10
150
0.552 J
0.857 J
0.661 J
0.582 J
0.516 J
0.328 J
0.336 J
0.402 J
0.755 J
0.514 J
0.404 J
0.439 J
Barium
ug/I
700
21000
57.0
126
63.0
62.7
64.8
34.4
19.6
173
107
241
106
45.1
276
105
56.6
41.9
181
20.5
26.7
41.9
16.2
Beryllium
ug/I
4
0.109 J
0.112 J
1.05
1.32
1.86
0.281 J
0.689 J
2.37
0.739 J
0.190 J
0.784 J
Cadmium
ug/I
2
8
68.8
0.509 J
1.48
Chromium
ug/I
10
0.748 J
4.41 B
2.26 B
2.83 B
1.70
0.851 J
3.11 B
12.7
17.1
43.9
1.67
7.99 B
45.0
10.0
2.62
2.51 B
14.4
0.478 J
0.560 J
0.866 J
1.09 B
Cobalt
ug/I
1
4
11
1.71
246
27.2
91.8
152
48.4
1.05
22.8
25.5
8.10
270
17.8
15.4
201
6.48
3.55
4.35
0.226 J
31.2
22.2
1.26
Copper
ug/I
1000
3.1
1.24
2.65
0.508 J
1.13
8.66
1.15
1.70
6.17
10.7
17.8
9.34
3.91
24.3
3.56
3.52
2.14
4.47
0.676 J
0.489 J
0.693 J
0.615 J
Lead
ug/I
15
1.07
0.286 J
1.51
0.635 J
6.75
4.23
9.96
0.808 J
1.73
10.6
3.28
0.687 J
6.19
Mercury
ug/I
1
0.100 J
Nickel
ug/I
100
88
1.90
25.0
2.18
3.55
20.7
3.95
2.62
7.67
13.1
16.2
13.6
6.82
15.7
12.3
3.01
1.62
6.16
1.11
2.13
0.192 J
Selenium
ug/I
20
1.14
1.16
0.731 J
1.11
1.71
1.12
1.37
Silver
ug/I
20
0.229 J
0.528 J
0.0657 J
0.0804 J
0.0890 J
0.0795 J
Thallium
ug/I
2
0.47
0.610 J
0.289 J
0.537 J
0.110 J
0.280 J
0.278 J
0.577 J
0.293 J
0.0908 J
0.572 J
1.55
0.0758 J
0.0999 J
0.117 J
0.123 J
Tin
ug/I
2000
1.87 JB
3.29 JB
5.55 B
Vanadium
ug/I
7
27
2.64 JB
0.854 J
1.76 JB
2.29 J
12.5
26.3
59.5
6.92
55.9
9.42
4.43 JB
19.4
1.86 JB
1.50 JB
Zinc
ug/I
1000
81
10.8
14.2
14.0
9.87 J
310
6.82 J
37.1
47.3
108
14.3
17.6
95.4
39.7
10.1
6.36 J
26.9
5.11 J
Organics
1,1-Dichloroethane
ug/I
6
0.816
1.83
0.498 J
1.84
4.63
0.366 J
0.353 J
1.35
0.701
1,2,4-Trichlorobenzene
ug/I
70
0.380 J
1,2-cis-Dichloroethylene
ug/I
70
720
11.0
42.4
0.246J
7.40
5.73
27.9
10.1
0.838
11.7
7.88
2.47
1,2-Dichloroethane
ug/I
0.4
1.92
0.956
1.18
1,2-Dichloropropane
ug/I
0.6
0.328 J
0.242 J
0.682
1,2-trans-Dichloroethylene
ug/I
100
0.316J
0.486J
1,4-Dichlorobenzene
ug/I
6
4.33 J
1.111
3.20 J
4.68 J
1,4-Dioxane
ug/I
3
2.43
1.76 J
4.00
7.08
2.29
8.19
2.74
6.10
2.27
5.67
2,4,5-Trichlorophenoxypropionic acid
ug/I
50
0.1667
Acetone
ug/I
6000
2000
2.44 J
1.911
2.83 J
2.18 J
2.88 J
2.90 J
2.70 J
Benzene
ug/I
1
1.33
2.42
0.287 J
0.353 J
0.663
1.53
Chlorobenzene
ug/I
50
5.63
2.57
1.60
3.62
3.36
1.80
Chl oroet hane
ug/ I
3000
2.87
0.468 J
Diethyl phthalate
ug/I
6000
1.49J
o-Dichlorobenzene
ug/I
20
1.81 J
0.278J
0.428J
1.49
Picloram
ug/I
0.06644 JO
Tetrachloroethylene
ug/I
0.7
0.287 J
Toluene
ug/I
600
0.463 J
Tetrahydrofuran
ug/I
2000
24.0
9.54 J
7.59 J
1.55 J
Trichloroethylene
ug/I
3
0.484 J
2.23
0.269 J
Vinyl chloride
ug/I
0.03
2.4
5.91
26.0
3.83
2.09
6.63
0.776
MNA Parameters
Alkalinity, Total (as CaCO3)
ug/I
26000
69000
34000
32000
45000
1.55E+05
29000
Biochemical Oxygen Demand (BOD)
ug/I
6700
Chloride
ug/I
250000
3010
37300
5970
3630
1490
41000
28700
COD - Chemical Oxygen Demand
ug/I
16000 J
21000 J
21000 J
Ethane
ug/I
44.2
Ethene
ug/I
3.87 J
Ferrous Iron
mg/I
23.5 H
0.22 H
1.81 H
49.9 H
Methane
ug/I
2430
413
6.08 J
978
173
Nitrate (as N)
ug/I
10000
1130
62.0 J
128
70.0 J
67.0 J
75.0 J
279
Sulfate
ug/I
250000
10900
1850 J
28600
4510
3510
7930
4460
Total Organic Carbon
ug/I
1040
4110
2490
1040
3800
1400
NOTES:
ug/L =micrograms per liter
SMAC = Site Maxi m um AI I owabl a Contam i nant Level
BOLD = Constituent exceeds NCA002L or GWP regulatory limits
BOLD = Constituent exceeds NCA002B or 2B Protection regulatory limits
J = Lab estimated concentration
BDL =constituent is below laboratory detection limits
NA = Not Analyzed
Q= RPD 140 % dual column
B=Analyte detected in blank
ARgei§0o-niAdaMntoircc.23inLA6aMntmrgRp3ts\SvyQL7*drg�WSffyQuty!*nrg2T4TEl-1g
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
SMITH GARDNER
Monitoring Results
Tade4
MEAdyticd FbsJts
aryQy86-02
P0129-K&VZ2024
Sample Date
Units
5/2/2024
4/29/2024
4/29/2024
4/29/2024
5/2/2024
5/2/2024
4/29/2024
4/29/2024
5/2/2024
4/29/2024
4/29/2024
4/29/2024
5/1/2024
4/29/2024
4/29/2024
5/1/2024
5/2/2024
4/29/2024
StationName
MW-1
MW-3R
MW-6
MW-7
MW-9
MW-11
MW-12S
MW-13
MW-14
MW-17
MW-19
MW-20
MW-21
MW-22
MW-23
SW-1
SW-2
SW-4
PFAS
Perfl uorobutanoic Acid (PFBA)
n /L
4.7
29 J
13
32
16
14
8.4
29
3.5
21
11
24
5.4
1.2 J
6.1
2 J
Perfluoro entanoicAcid PFPeA
n /L
26
72
4.6
47
27
42
3
Perfluorohexanoic Acid PFHxA
n /L
1.8
67
29
75
17
4.7
6.5
130
14
59
6.7
11
120
16
6.4 J
3.7
3.3
3.8
Perfl uorohe tanoic Acid PFH A
n /L
1.71
16 J
16
45
6.5
3
1.8
17
2.31
15
3.9 J
15
1.8
0.55 J
1.7
1.4
Perfl uorooctanoic acid PFOA
n /L
4.4
25
38
110
6.4
5
1.9
17
1.9
19
3.9 J
13
3.6
0.89 J
1.3 J
2.3
PerfluorononanoicAcid PFNA
n /L
1.11
2.8
0.39J
0.12J
PerfluorodecanoicAcid (PFDA)
n /L
0.57J'+
Perfl uorobutane Sulfonic Acid PFBS
n /L
1.9
8.4
11
1.5
1.9
6.1
0.61 J
14
1.6 J
1.11
1.11
0.78 J
1.2 J
Perfl uoro entane sulfonic acid PFPeS
n /L
0.4 J
2.1 J
5.6
9.4
0.37 J
1.4
9.4
0.83 J
1.6
0.41 J
0.16 J
0.31 J
0.62 J
Perfl uorohexane Sulfonic Acid PFHxS
n /L
1.9
22
25
31
1.8 J
1.5
9.2
0.94 J
39
1.11
8.2
0.95 J
0.72 J
0.54 J
2.4
Perfluorohe tane sulfonic acid PFH S
n /L
1.11
Perfl uorooctanesulfonic acid PFOS
n /L
11
25
0.85 J
39
0.61 J *+ B
2.3
6:2 Fluorotelomer sulfonate 6:2 FTS
n /L
1.7 J
4.4
11
0.9 J
N-meth I perfluorooctane sulfonamidoacetic acid N-McFOSAA
n /L
0.83 J
N-ethyl perfluorooctane sulfonamidoacetic acid NEtFOSAA
n /L
0.8 J
NOTES:
ng/L = nanograms per liter
J = Lab estimated concentration
BDL =constituent is below laboratory detection limits
*+= LCS and/or LCSD is outside acceptance limits, high biased
B = Compound was found in the blank and sample
B,r.DJ:
DfaMOY2124
MRgeisl ffMntoircj23 rdAetff ntmrgRp3ts\3myQL74*gn W SffyQu-ty*rg2124TE-lg
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
SMITH GARDNER
Monitoring
Location
Water Table
Elevation ft. amsl �
Hydraulic
Conductivity
Effective Porosity
Hydraulic
Gradient ft./ft.
(cm/sec)
Groundwater
Velocity cm/sec
y
Groundwater
Velocit ft/day)
y
MW-1
1108.62
4.30E-05
15
0.0600
1.72E-07
4.88E-04
MW-3R
984.13
2.40E-04
5
0.1600
7.68E-06
2.18E-02
MW-7
1060.55
8.1OE- 04
15
0.0400
2.16E-06
6.12E-03
MW-9
1061.64
1.90E-04
15
0.0100
1.27E-07
3.59E-04
MW-11
1002.56
3.1OE- 04
5
0.0700
4.34E-06
1.23E-02
MW-12S
991.44
1.30E-06
3
0.1400
6.07E-08
1.72E-04
MW-13
991.44
2.06E-04
23
0.0900
8.06E-07
2.28E-03
MW-14
1034.05
7.45E-03
3
0.2100
5.22E-04
1.48E+00
MW-15
947.16
7.21E-05
3
0.1100
2.64E-06
7.49E-03
M W-16
938.83
2.82E- 05
3
0.0500
4.70E- 07
1.33 E- 03
M W-17
972.29
2.94E- 04
3
0.0400
3.92 E- 06
1.11 E- 02
M W-19
948.93
1.1OE- 03
3
0.0900
3.30E- 05
9.35 E- 02
MW-20
947.45
1.92E-04
3
0.0400
2.56E-06
7.26E-03
M W- 21
946.70
1.28E- 03
3
0.0100
4.27E- 06
1.21 E- 02
MW-22
948.93
9.88E-04
15
0.0600
3.95E-06
1.12E-02
MW-23
947.45
3.04E-04
15
0.0800
1.62E-06
4.60E-03
Average: 1.04E-01
NOTE:
Bj.SJ
ate 1y 19 Z24
Values for hydraulic conductivity determined via slug test by GAI, MESCO, or Joyce.
Hydrologic gradient from water levels recorded on April 29 - May 2, 2024
Wells screened entirely in rock were not utilized for gradients. Screens that traverse both rock and regolith assumed flow in regolith dominates
Hydraulic Conducitivity value and flow rate for MW-14 was considered an outlier; therefore not included in the average or maximum.
NA= Not available/applicable
Velocity Calculated from V=K*i/n
V= velocity
K = Hydraulic Conductivity
i = Gradient
n = Porosity
RRgerfslGa d&de'pitonnj2C3aniAde'MntcnrgRpotsl rryQri-�7.,Qorg2M4\3nyCtirty$ing2M4T@1es
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
This page intentionally left blank.
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Appendix A
Monitoring Well Information
May 2024 Semi -Annual Monitoring Report
Surry County Closed CRD/MSW landfill
NC Solid Waste Permit No. 86-02
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
This page intentionally left blank.
Docusign Envelope ID: 889599EA-C817-4865-93DD-1 B8535D719AE
NON ESIDENT L WELL CONSTRUCTION RECORD
c North Carolina Department of Environment and Natural Resources- DMsion of Water Quality
�,. 2663
WELL CONTRACTOR CERTIFICATION #
1. WELL CONTRACTOR:
Derry Huneycu t _ Well Contractor Contractor (Individual) Name
Derry's Welt Drillinrl Inc. _
Well Contractor Company Name
44283-A NC 24/27/73
Street Address
Albemarle NC 28001
City orTown State Zip Code
7[ 04_} 982-9070
Area code Phone number
2. WELL INFORMATION:
WELL CONSTRUCTION 1
OTHER ASSOCIATED PERMIT#{if applicable} WIQ400176
SITE WELL ID #(Jf applicable) 1W-1
3. WELL USE (Check One Box) Monitoring ❑ MunicipallPublic
Industrial/Commercial0 Agricultural ❑ Recovery d Injection Wf
Irrigation❑ Other ❑ (list use)
DATE DRILLED10/28/11.
4. WELL LOCATION-
419 Landfill Road
(Street Name, Numbers, Community, Subdivision, Lot No., Parcel, Zip Code)
CITY; Ararat COUNTY SLirrV
TOPOGRAPHIC 1 LAND SETTING: (check appropriate box)
USlope ❑Valley ❑Flat t&ldge []Other
K jg$TCD 36 AAAA&AAnnnnnAI CL R OR 3�4nnnn CC
MMF1$TCD75 •AAAA&AAAAAAAA( CL ROR 80HP 43AnnA CC
Latitudellongitude source: VGPS Qrepogmphie map
(location of wel/ must be shown on a USGS topo map andattached to
this fom7 if not using GPS)
5. FACILITY tName of the lousiness Where the well is located.)
S rr11 .n- Closed MSW_ I_F_ _
Facility Name Facility ID# (if applicable)
419 Landfill Road
Street Address
City or Town State Zip Code
Contact Name
PO Box 1542
Mailing Address
Mount Aim __NQ 27030
CityorTown State Zip Code
( 313 401-8378
Area code Phone number
IW-1
d. TOP OF CASING is 3.00 FT. Above Land Surface'
'Tap of casing terminated atior below land surface may require
a variance in accordance with 15A NCAC 2C .0118.
: e. YIELD (gpm): na METHOD OF TEST
f. DISINFECTION- Type na
Amount na
g. WATER ZONES (depth):
Top 75'�(2) Bottom 7T�{7] _ Top
Bottom
Top Bottom Top
Bottom
Top Bottom Top
Bottom
Thickness)
:7. CASING: Depth Diameter
Weight Material
- Top '+3.00 Bottom 61.40 Ft. 2"
sch 40 PVC
Top Bottom Ft.
= Top Bottom Ft.
- 8. GROAT: Depth Material
Method
Top 57,00 Bottom 60.00 Ft. Bent. Chips
Gravity
Top 0 Bottom 57.00 Ft. Neat Cement
Tremie_ -_
Top Bottom Ft,
9. SCREEN: Depth Diameter Slot Size Material
Tap 61.40 Bottom 81.40Rt 2 in. 0.02 in. PVC
= Top Bottom Ft. in. in. High Flaw
Top Bottom Ft, in. in. 118"Spadn�
10. SANDIGRAVEL PACK:
Depth Size
Top 60.00 Bottom 84.00 FLU$
Top Bottom R.
Top Bottom Ft,
11. DRILLING LOG
Top Bottom
0 141.00
41.00 J 43.00
4100 1 47.00
47.00 184.00
. 1
63 1 63.50
70 1 70.50
75 1 77
80 / 80.50
. 1
= 12. REMARKS:
Material
Filter $and
Formation Description
Soil: Sandy Silt, Brown
PWR: Brown, Hi h Density
Sa route; Brown
Rock: Gneiss. Gray
Fracture
Fracture
Fracture
Fracture
6. WELL DETAILS: 100 HERE8Y CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH
-t5q p2C,W)LLCONSTRUCTIt?N 7ANpgR0S,AN➢THATAC0P OFTHIS
a. TOTAL DEPTH: 81.40` RE NAS eEEN PRp DTp E WEI1 pWNER.
b. DOES WELL REPLACE EXISTING WELL? YES ❑ NO d NATUR F CERTIFI D LL CO CTCR DATE
c. WATER LEVEL Below Top of casing: 53.00 T�FT. Derry L Huneycutt
(Use "+' if Above Top of Casing) = PRINTED NAME OF PERSON CONSTRUCTING THE WELL
ForSubmitwithin 30 days of completion to: Division oQuality
isif Water Qli Information Processing, GW 16
Y P tY " 9 Rev. Rev. 11p8
1617 Mail Service Center, Raleigh, INC 27699-161, Phone : (919) 807-6300
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
MW-
N: C- Department of Human Reeoureta ( z-
❑ivision of Health Services r
` WELL COMPLETION RECORD I
lfl7 ',Izr- VI4zC 4? I
COMPLETE ALL INFORMATION REQUESTED BELOW FOR EACH WELL INSTALLED, AND RETURN FORM TO TF-IFN.C-
DEPARTMENT OF HUMAN RESOURCES, SOLID AND HAZARDOUS WASTE MANAGEMENT BRANCH,
P. O. BOX 2091, RALEIGH, N.C. 27602
NAME OF SITE: PERMIT NO.:
C lY
ADDRESS: OWNER (print):
( C:I Iz- ley C,(v ( Y
DRILLING CONTRACTOR: REGISTRATION NO.-
lJ7 l"Afl 6 J?- -d G72- f
Casing Type:
G._ dia.
r+
-� in.
Grout Depth_
from 0 - - to 2 5 fr., dia.
I` in.
Casing Depth:
from 12 to - -I el - ft. - dia.
2 - in.
Btruonite 5t21:
from Z 9 to -3 0 ft. - dia.
G �` in.
Screen Type:
e j dia.
�_ in.
Sand/Gravel PK.-
from 3 ° to �_ ft. - dia.
{ _ in.
Screen Depth:
from' ' to _j�o ' ft. - dia.
in.
Torsi Well Depth:
from Q_ to �-4-0 ft. - dia.
in.
Static Water I -eves:
r
� feet from top of
casing
Date Measured — /—
/—
Yield (gpm): Method of Testing: Casing is _}�_ �w feet above land surface
DRILLING LOG
DEPTH
FROM TO FORMATION DESCRIPTION
rQ-
REM ARKS:
DATE: ' - L
f I IS 3 " 2 (6,81)
SMd & H..dw. Wine Mtr+re c &-Kh
LOCATION SKETCH I
(show distance co numbered roads, or other map reference points)!
7z Zafz-
�S
5IGNATURF-
�`"�fjs3 "; �� p>E xz �.. s� Q�r r 77r�^-�-r •r- - �c�.
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
Originally MW-2
Now I W-2
' WELL COMPLETION RECORD
/A/t 7 /)I eZr �,I-21— .4P, 2
4PLETE ALL INFORMATION REQUESTED BELOW FOR EACH WELL i!NSTALLED. AND RETURN FORA.{ TOTEHE N-C.
kRTMENT OF HUMAN RESOURCES, SOLID AND HAZARDOUS WASTE MANAGEMENT BRANCH,
BOX 2C91. RALEIGH, N.C. 27602
AE OF SITE: PERMIT NO.: [�
]RESS: OWNER (print):
7c �
j� , 1 a [r Iz-I � o� s u C .z 7r��7 �
LUNG CONTRACTOR: REGISiYiATiON NO.:
G � G G'� In .J � �� � -Tr-��7��
ig Type: V dia. "in. Grout Depth: from Ll=' to - 2�7 ft. -dia. in.
ig Depth: from 0 to ft. - dia. ..-ItL in. Bentanite Seal: From tv _ Ft. •dia. = in.
°n Type: 0 r dia. ,k "In. in. Send/Gravel PK: from to ��•? ft. • dia. !� in.
m Depth: from 40 to 0 0 k. - dia. —L-2 in. Total Well Depth: from �_ to ft. • dia. 4, " in.
c Water Lcvel: ---- - feet from tap of casing Date Measured
i (gpm): Method of Testing: a-4� Casing is _ _ I «feet above land surface
LOCATION SKETCH
(show distance to numbered roads, or other map referrnre painu
MARKS:
,,TE: SIGNATURI=:
—� �..... ...o. o���...��� .,�. .....�.. a.,u .,� gun, w. o.�....��� ..................... ............... J .. a w.arr..r
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
M W-3
North Carolina - Department of Environment, Health, and Natural Resources
Division of Environmental Management - Groundwater Section
P.O. Box 29535 - Raleigh, N.C. 27626-0535
Phone (919) 733.3221
WELL CONSTRUCTION RECORD
DRILLING CONTRACTOR: GA-1 Consultants
FOR OFFICE USE ONLY
QUAD. NO. SERIAL NO.
Lat Long. RO
Minor Basin
Basin Cade
Header Ent GW-1 Ent
STATE WELL CONSTRUCTION
DRILLER REGISTRATION NUMBER. 446 PERMIT NUMBER-
I-
WELL LOCATION: (Shaw sketch of the location below)
Nearest Town: Mt' Airy County.
Surry
SR 2015
(Road, Community, or Subdivision and Lot No.)
DEPTH
DRILLING LOG
2.
OWNER Surry County Attn: ,ferry Snow _
From To
Formation Description
ADDRESS PC, Box 706
0 - 13
Red clay
(Street cr Route No.)
Dobson NC 27017
13 - 16
Extremely weathered
City or Town State Zip Code
3.
DATE DRILLED 9-27-94 USE OF WELL Monitoringschist
4.
TOTAL DEPTH 103'
5.
CUTTINGS COLLECTED YES Q NO[o
16 - 30.7
Slightly weathered
6.
DOES WELL REPLACE EXISTING WELL? YFS U NO[]
schist
7.
STATIC WATER LEVEL Below Top of Casing: ±70-5 FT.
(Use',' it Above Top of Casing)
30.7 — 102
SChiSt
S.
TOP OF CASING IS 2.5 FT. Above Land Surface'
' Casing Terminated atfor halow land surface is It}egat unless a variance is issued
in
axordanca with 15A NCAC 2C .0118
N/A
9.
YIELD (gpm): METHOD OF TEST
10.
WATER ZONES (depth): 85 to 102 ft
11.
CHLORINATION: Type NSA Amount
If additional space is needed
use back of form
12. CASING
WaI[ Thickness
2.5 Depth86 Diameter or Weight/Ft. Material
From To Ft. 2" Sch 4Q PVC
From To Ft.
From To Ft.
13. GROUT
LOCATION SKETCH
(Show direction and distance from at least two State
Roads, or other map reference points)
SR 2C15
Depth Material Method
From 0 To 80 Ft. neat cernent rho ti
From _ 80 To 82.6 Ft, bentonite pellets_
14. SCREEN:
Depth Diameter Slot Size
From To 101 Ft 2 in. .010
From To Ft. in.
From -To Ft. in.
15. SANDIGRAVEL PACK:
Depth Sze
From 82.6 To 102 Ft.
From To Ft.
1�. REMARKS:Monitoring Well 3R _
Material
in. PVC
in.
in.
Material
silica
N �<--
Water first encountered at 85 to 95 ft
I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15A NCAC 2C, WELL
CONSTRUCTION STANDARDS, AND THAT A COPY OF THIS RECORD HAS BEEN PROVIDED TO THE WELL OWNER.
l
SIGNATUR OF CONTRACTOR oR AGENT D►(
�...: :ml 1n 11:.ricinn nF L;; .j nnma n=1 ASannnamanf anri nn.... .n .....n ...
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Originally MW-3RS
Now IW-3
MONITORING WELL
��� ■ 'err
CONSTRUCTION LOG ENGINEERING, INC
PROJECT: _Mt. Airy Water Ouality Assessment MONITORING WELL ID: MW-3RS
LOCATION: Mt. Aia, NC - CONSTRUCTION DATE:: 5117J2�41
STAND PIPE CONSTRUCTION
MEASURING POINT ELEVATION 1020.57 ft AMSL
GEOLOGIC UNITS
PAD DIMENSIONS 3 feet x 3 feet
GROUND SURFACE ELEVATION 10.18.24 ft AMSL
BOREHOLE DIAMETER 9 inches to 14 feet below grade
4 inches from 14 feet to bottom
ANNULAR SPACE SEAL
TYPE OF SEAL Roanoke Portland Cement
Tremiie grouted
RISER TYPE PVC
RISER DIAMETER 2 inches
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Originally MW-4
Now IW-4
North Carolina - Department of Environment, Health, and Natural Resources
Division of Environmental Management - Groundwater Section
P.D. Box 29535 - Raleigh, N.C. 27626-0535
Phone (919) 733.3221
WELL CONSTRUCTION RECORD
DRILLING CONTRACTOR: GAI Consultants
FOR OFFICE USE ONLY
QUAD.NO. SERIAL NO.
Lat Long. RO
Minor Basin
Basin Cade
Header Ent GW-t Ent
STATE WELL CONSTRUCTION
DRILLER REGISTRATION NUMBER: PERMIT NUMBER: N/A
1. WELL LOCATION: (Show sketch of the location below)
Nearest Town: Mount Airy -County-.---- Surry
SR 2015
(Road, Community, or Subdivision and Lot No.)
2. OWNER Surry County
ADDRESS PO Box 706
(Street or Route No.)
Dobson NC 27017
City or Town State Zip Code
3. DATE DRILLED 8-30-94 USE OF WELL Monitoring
4. TOTAL DEPTH 56.4'
5. CUTTINGS COLLECTED YES ❑ NOEX:
6. DOES WELL REPLACE EXISTING WELL? YES C NOnx
7. STATIC WATER LEVEL Below Top of Casing: 35 FT.
(Liss '." if Above Top of Casing)
S. TOP OF CASING IS 2 FT. Above Land Surface'
' Casing Terminated at/or below land surface is illegal unless a variance is issued
in accordance with 15A HCAC 20 .0118
9. YIELD (gpm):—METHOD OF TEST
10. WATER ZONES (depth): 46 to 56.4 ft
11. CHLORINATION: Tyre
12. CASING:
etef
From +2 DToth 40.4 Ft. pi 2 1
From To Ft.
From To Ft.
13. GROUT:
Depth
From 0 To 38 Ft.
From _ 35 To 39 Ft.
14. SCREEN:
Amount
Wall Thickness
or WeighUFt. Material
Sch 40 PVC
Material
Cement
Bentonite
DEPTH
From To
0 - 5
5-56.4
DRILLING LOG
Formation Description
Sandy silt with
trace clay
Gray garnet mica
schist with quartz
veins
If additional space is needed use back of form
LOCATION SKI='TCH_
(Show direction and distance from at least two State
Roads, or other map reference points)
SR 2015
Method
Grout / l
Pellet
Depth Diameter Slot Size Material
From 40.4 To 55.4 Ft 2 in. -010 in. PVC
From To Ft. in, in.
From To Ft. in. in.
15. SAMMIr-'RAVEL PACK:
Depth Size Material
From 39 To 56.4 Ft 2 Sand
From To Ft. N <--
16, REMARKS: Mcnitorinq Well 4 Water first encountered at 46 ft
1 ❑O HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15A HCAC 2C, WELL
CONSTRUCTION STANDARDS, AND THAT A COPY OF THIS RECORD HAS BEEN PROVIDED TO THE WELL OWNER
I4 //0
SIGNATUR OF CONTRACTOR OR AGENT DATE
r;W-1 RFV WWI gnhrnit 'nod to Division of Emiror.mentai Manacernent and copy to well owner
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Originally MW-5
Now IW-5
North Carolina - Department of Environment, Health. and Natural Resources
❑ivision of Environmental Management - Groundwater Section
P.O. Box 29535 - Raleigh, N.C. 27626.0535
Phone (919) 733-3221
WELL CONSTRUCTION RECORD
DF31LLING CONTRACTOR: GAI Consultants
FOR OFFICE USE ONLY
QUAD. NO, SERIAL NO.
Lat Lang. RO
Minor Basin
Basin Code
Headet Ent GW-1 Ent
STATE WELL CONSTRUCTION
DRILLER REGISTRATION NUMBER: 446 PERMIT NUMBER: NSA
1. WELL LOCATION: (Show sketch of the location below)
Nearest Town: Mount Airy County: 5urry
SR 2015
(Road, Community, or Subdivision and Lot No-)
2. OWNER SurEy County
ADDRESS PO Box 706
[street or Route No.)
Dobson NC 27017
City or Town State Zia Code
3. DATE DRILLEL' 8-27-94 USE OF WELL Monitoring
4. TOTALDEPTH 64•l
5. CUTTINGS COLLECTED YES ❑ NOFX_I
6. DOES WELL REPLACE EXISTING WELL? YES C NOI�x
7. STATIC WATER LEVEL eeiow Top of Casing: 39.5 FT.
[Use'+' if Above Top oI Casing]
S. TOP OF CASING IS 2 FT. Above Land Surface'
Casing Terminated at/or below land surface is I fiegat unless a variance Is issued
in accordance with 15A NCAC 2C ,0118
9. YIELD (gpm): METHCD OF TEST
10. WATER ZONES (depth): 51 to 64.7 ft
t. CHLORINATION: Type
12, CASING:
Amount
Wail Thickness
Depth Darnetef or eig4�t, Material
From +2 To 48 Ft. 1r
From To Ft.
From To Ft.
13. GROUT:
DEPTH
From TO
0 - 5
5 - 16
16-64.7
DRILLING LOG
Formation Description
Red clay
Tan sandy silt
Gray garnet mica
schist with granite
intrusions
If additional space is needed use back of form
LOCATION SKETCH
(Shaw direction and distance from at least two State
Roans. cr other map reference points}
SR 2015
Depth Material Method
From 0 To 45 Ft. Cement Grout
From 45 To 46 Ft. Bentonite Pellet ,
14. SCREEN:
Depth Diameter Slot Size Material
From 48 To 63 Ft 2 in. .014 in. PVC Cir:
From To Ft. in. in.
From To Ft. in. in,
15. SAND/GRAVEL PACK:
Depth Size Material
From 46 To 64.7 Ft, 2 Sand
From To Ft. N 4--
16.REMARKS. Monitoring Well 5 Water first encountered at 51 _ft
I Da HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15A NCAC 2C, W£LL
CONSTRUCTION STANDARDS, AND THAT A COPY OF THIS RECORD HAS BEEN PROVIDED TO THE WELL OWNER,
r
SIGN iT E OF CONTRACTOR OR AGeNT tDA
GW•t REV. 991 Su nrta+nal. to Civaicr.. of Ettvtrormental Aianaaemem and coat/ 10 well owner
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
MW-
North Carolina - Department of Environment, Health, and Natural Resources
Division of Environmental Management • Groundwater Section
P.O. Box 29535 - Raleigh, N.C. 27626-0535
Phone (919) 733-3221
WELL CONSTRUCTION RECORD
DRILLING CONTRACTOR: CAI Consultants
FOR OFFICE USE ONLY
QUAD. NO, SERIAL NO.
L.at Long. RO
l 'WX3-r Basin
Bas;n Cade
Header Ent GW-1 Ent
STATE WELL CONSTRUCTIONDRILLER REGISTRATION NUMBER: 445 PERMIT NUMBER, NSA
1. WELL LOCATION: (Shaw sketch of the location below)
Nearest Town:_ Mount Airy . County: Surry
SR 2015
(Road, Community, or SuodMsion and Lot No-)
2. OWNER Su -cry County
ADDRESS PO Box 706
(St(eet or Route No.)
Dobson NC 27017
City or Town State Zio Code
3. DATE DRILLED 9-7-94 USE OF WELL Monitoring
4, TOTAL DEPTH 30.7
5. CUTTINGS COLLECTED YES ii NOr
6. DOES WELL REPLACE EXISTING WELL? YES l NO7-5q
7, STATIC WATER LEVEL Below Top of Casing: 22.55 FT.
(Use '+" ii Above Top of Casing)
8. TOP OF CASING IS 2 FT. Above Land Surface'
'Casing Terminated atlor below land surface is illegal unless a variance is issued
in accordance with 15A NCAC 2C .01I8
9. YIELD (gpm):_METHOD OF TES
10. WATER ZONES tdepth}: 20.55 to 30.7—Ft—
;1. CHLORINATION: Type
12- CASING:
Depth
From +2
To ---14-7 Ft.
From
To
Ft.
From
To
Ft,
13. GROUT:
Depth
From 0
To 12
Ft
From 12
To 13
Ft.
14. SCREEN:
Amount
Wall Thickness
4io Weigh I21 PVC
Material Method
Cement Grout
Bentonite Pellet
Depth Diameter Slot Size Material
From 14.7 To 29.7 Ft 2 in. .010 in_ PVC
From To Ft. in- in.
From To Ft. in. in.
15, SAND/GRAVEL PACK:
Depth Size Material
From 13.0 To 30.7 Ft 2 Sand
From T6 Ft. N 4-
16. REMARKS: monitorim Well 6 T _
DEPTH
Flom To
0 — 15.5
15.5 — 30.7
DRILLING LOG
Formation Description
Brown to tan sandy
silt: with trace clay
Gray garnet mica
schist with granite
intrusions .5—l'
thick
If additional space is needed use back cf form
LOCATION SKETCH
{Show direction and distance from at:east Iwo State
Roans. or other map reference pvnts)
5R 2015
100 HERESY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITHA SA NCAC 2C. WELL
CONSTRUCTION STANDARDS, AND THAT A COPY OF THIS RECORD HAS BEEN PROVIDED TO THE WELL OWNER.
t I/C)
SfGN 7T1JF0 OF (CONTRACTOR GR AGENT r DArE
3WA REV. 9'91 Sut:mtt of uboral 10 ':)NIr,10C of E: TV If QZ%nental Manace ment and coov to wen owne•
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
MW-
North Carciina - Department of Environment, Health, and Natural Resources
pivision of Environmental Management - Groundwater Section
P.O. Box 29535 - Raleigh, N.C. 27626-0535
Phone (919) 733-3221
WELL CONSTRUCTION RECORD
DRILLING CONTRACTOR: CAI Consultants
FOR OFFICE USE ONLY
Ol1A0. NO, SERIAL NO.
Lat Larg. RO .
Minor Basin
P. cue
Header Ent nw-t ErrL
STATE WELL CONSTRUCTION
DRILLER REGISTRATION NUMBER: �� PERMIT NUMBER_ NIA
1. WELL LOCATION: (Show sketch of the location below)
Nearest Town: Mount Airy � County: Burry
5R 2015
(Road, Community, or Subdivision and Lot No.)
DEPTH
2.
OWNER Surry County
From To
ADDRESS PO Box 706
1 _ 5
(Street or Route No.)
Dobson NC 27017
5 — 10
City or Town State Zip Code
3.
DATE DRILLED 8-23-94 USE OF WELL Monitoring
4.
TOTAL DEPTH 24
5,
CUTTINGS COLLECTED YES I—� NOFxj
10 — 15
6.
DOES WELL REPLACE EXISTING WELL? YES = NO�x
7.
STATIC WATER LEVEL Below Top of Casing: 12.75 FT.
(Use '*'if Above Top of Casing)
1.8
15 — 18.5
B.
TOP CIF CASING IS FT. Above Land Surface"
'Casing Terminated aver below land surface is illegal unless a variance fs issued
18.5 — 24
In
accordance with 15A NCAC 2C .0118
9.
YIELD (gpm):. , METHOD OF TEST
10.
WATERZONES (depth): 10.95 to 24 ft
r 1. CHLORINATION: Type
12. CASING:
Depth
From +1.8
To 8
From
To —
From
To-
13. GROUT:
Depth
From 0
To 6
From 6
To 7
14. SCREEN:
Amount
Wall Thickness
❑iameter or WeighuFt. Material
F t. 2 IT Sch 40 PVC
Ft.
Ft.
Material Method
Ft. Cement Grout
Ft. Bentonite Pellet
Depth Diameter
From 8 To 23 Ft 2 in
From TO 1-t. in
From To Ft. In
15. SANDIGRAVEL PACK:
Depth Size
From 7 To 24 Ft. 2
From To Ft..
16. REMARKS: Monitorinq Well 7
Slot Size Material
.010 in. PVC
in.
in.
Material
Sand
DRILLING LOG
Formation Description
Tan sandy silt
Brown clayey silt w/
rock fragments
Orange clayey _sand
medium to coarse
Brown sandy silt
Gray schist
If additional space is needed use back cf for,
LOCATIQSKE'TCH
(Show direction and distance from at least two State
Raaos. or other map reference polrrts)
SR 2015
;1
1
.IW
N <—
I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15A NCAC 2C. WELL
CONSTRUCTION STANDARDS, AND THAT A COPY OF THIS RECORD HAS BEEN PROVIDED TO THE WELL Ol'JNER.
SIGNA T UR OF CONTRACTOR CrR AGENT DATE
3W-1 REV 9:95 S: i:mu ar[ainal to DiLLsk]n of Erwrrormensal hianaoemem and ccoy to gall jwne:
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Originally MW-8
Now IW-6
North Carolina - Department of Environment. Health, and Natural Resources
Division of Environmental Management - Groundwater Section
P.O. 8ox 29-935 . Raleigh, N.C. 27526-0535
Phone (919) 733-3221
WELL CONSTRUCTION RECORD
')RILLING CONTRACTOR: GAi Consultants
FOR CFRCE USE ONLY
QUAd. NO- SERIAL NO.
Lat Long. RO
Minor Basin
Basin Code
Header Ent GW 1 Ent
STATE WELL CONSTRUCTION
DRILLER REGISTRATION NUMBER: 446 PERMIT NUMBER: NSA
1.
WELL LOCATION: (Show sketch of the location below)
Nearest Town: Mount Airy County:
Surry
SR 2015
(Road, Community, or Subdivision and Lot No-)
DEPTH DRILLING LOG
2
OWNER Surry Country
FromFormation an
Pfl Sax 706
ADDRESS. ..,_ , ,�,_, ,.�
0 — 45o Tan tobrown sandy
(Street or Route No.)
silt
Dobson NC 27017
City or Town State Zip Code
8--16-94 Monitoring
45 — 55.3 Gray schist
3.
DATE DRILLED USE OF WELL
4.
TOTAL DEPTH 55.3
5.
CUTTINGS COLLECTED YES ❑ NO
6.
DOES WELL REPLACE EXISTING WELL? YES C NOC
7,
STATIC WATER LEVEL Below Top of Casing: 41.1 FT.
(Use ': if Above Top of Casing)
8.
TOP OF CASING IS 2. 3 IFT. Above Land Surface
• Casing Terminated at/or Below land surface is illegal untess a variance is issued
In
accordance with 15A NCAC 2C .0118
9.
YIELD (gpm):, METHOD OF TEST
10.
',HATER ZONES (depth): 38.8 to 55.3 ft:
'.1.
CHLORINATION: Type . Amount
If additional space is needed use back of form
2.
CASING.
LOCATION SKETCH
Wall Thickness
+2.3 Deptf'L39 Diameter or weighv t- Material
4�
(Show direction and distance from at least two State
From To Ft. 2 SCh PVC
Roacs, or other map reference po'nts)
From To Ft.
From To Ft.
SR 2015
13.
GROUT:
.�
Depth Material Method
From _ 0 _ To 36 Ft. Cement Grout
From 36 To 37 Ft. Sentonite Pellet
14. SCREEN:
Depth Diameter
From 39 To 54 Ft 2 in.
From To Ft. in.
From To Ft. in.
15. SANDiGRAVEL PACK:
Depth
From 37 To 55.3 Ft
From To Ft.
16. REMARKS: Monitorinc
Size
2
Slot Size Material
-010 in. PVC
in.
in.
Material
Sand
Wei 8
1
Mrr1 8v7:::
N c---
I Da HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15A NCAC 2C. WELL
CONSTRUCTION STANDARDS, AND THAT A COPY OF THIS RECORD HAS BEEN PROVIDED TO THE WELL OWNER.
SIG�NATUR OF CONTRACTOR Gr3 AGENT r3ArE
GW•1 REV 9131 rn+t anal t; �i� sar al E:virormewai'.'anaaen-er:! anai:cv t:! •rre:! .—nor
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
MW-
North Carolina - Department of Environment, Health, and Natural Resources
Division of Environmental Management - Groundwater Section
P.O. Sox 29535 - Raleigh, N.C. 27826.0535
Phone (919) 733.3221
WELL CONSTRUCTION RECORD
'RILLING CONTRACTOR: GAI Consultants
OR OFRCE USE ONLY
QUAD. NO, SERIAL NO.
Lat Long. R4
Minor Basin
Basin code
Header Ent Gw-1 Ern
STATE WELL CONSTRUCTION
DRILLER REGISTRATION NUMBER: 445 PERMIT NUMBER: N/A
1 . WELL LOCATION: (Shaw sketch of the location below)
Nearest Town: Mount Airy County: Surry
SR 2015
(Road, Community, or Subdivision and Lot No.) DEPTH DRILLING LOG
2. OWNER Surry County
PO Box 709 From To Formation Description
ADDRESS _ 0 - 43.8 Brown to tan sandy
(Street or Route No,)
Dodson NC 27017
City or Town State Zip Code
3. DATE DRILLED 8-22-94 USE OF WELL Monitoring
4. TOTALDEPTH PTM 43.8
5. CUTTINGS COLLECTED YES 7 NOF—XI
6. DOES WELL REPLACE EXISTING WELL? YES F—; N0
7. STATIC WATER LEVEL Seicw Top of Casing: 35.7 FT.
{Use'+" if Above Top of casing]
8. TOP OF CASING IS 2' 3 FT. Above Land Surface"
'Casing Terminated aVor below land surface is illegal unless a variance is issued
in accordance with 15A NCAC 2C .0118
9. YIELD [gpm]:—METHOD OF TEST
10. WATER ZONES (depth): 1 3-4 ro 43_A ft --
i. CHLORINATION: Tyne
CASING:
Amount
Wall Thickness
+2 3 Depth L$. S Diarreter or WeighvFt. Material
From To Ft. 2" 5ch 40 PVC
From To Ft.
From —To Ft.
13. GROUT:
Depth Material Method
From 4 To 25.5 Ft. Cement Grout
From 25.5 To 26.5 Ft. Bentonite Pellet
14. SCREEN:
Depth
From
2-8 8To 43-$ Ft
From
To Ft,
From
To Ft.
15, SAND/GRAVEL PACK:
Depth
From
26.5 To 43.8
From
To
16. REMARKS.
monitori.
Diameter Slot Size Material
2 in. .010 in. PVC
in. in.
in. in. _--
Size Material
Ft. 2 Sand
Ft.
n Well 9
silt
If additional space is needed use rack of form
LOCATION SKETCH
(Show direction and distance from at least two State
Roaas. cr other map reference points)
SR 2015
N 4--
1 00 HERESY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15A NCAC 2C, WELL
CONSTRUCTION STANCARDS, AND THAT A COPY OF THIS RECORO HAS SEEN PROVIDED TO THE WELL CANNER
SIGNATURE CONTRACTOR CR AGENT E
GW-1 REV 9•'91 ��,.nit n�i_ aE t� _iv sion- o: E:" vpro^.^cnri, '.'Znacemer.� ono cno•: �-Nnr-r
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
North Carolina - Department of Environment. Health, and Natural (Resources
Division of Environmental Management - Groundwater Section
P.O. Box 29535 • Raleigh, N.C. 27626-0535
Phone (919) 733.3221
WELL CONSTRUCTION RECORD
DRILLING CONTRACTOR: GAI Consultants
aU►w. NO.
Lat
Minor Basin
Basin Code
Header Ent_
FOR OFFICE USE ONLY
SEAIAL NO-
_ Long- RO
STATE WELL CONSTRUCTION
DRILLER REGISTRATION NUMBER: 446 PERMIT NUMBER: N7A
1. WELL LOCATION: (Show sketch of the location betow)
Nearest Town: _ Mount Airy _ County. Surry
SR 2015
(Road, Community, or Subdivision and Lot No.)
2. OWNER Surry County
ADDRESS PO Box 706
{Sheet or Route Na-)
Dobson NC 27017
City or Town - State Zip Code
3. DATE DRILLED 8-15-94 USE OF WELL Monitoring
4. TOrAL DEPTH 41'
5. CUTTINGS COLLECTED YES 7 NO
6. DOES WELL REPLACE EXISTING WELL? YES E] NOQX
7. STATIC WATER LEVEL Below Top of Casing: 20.92 FT-
(Use'�" if Above Top of Casing)
S. TOP OF CASING IS 1-5 FT. Aborts Land Surface'
Casing Terminated avor below land surface is illegal unless a Variance is Issued
in accordance with 15A NCAC ZC .o118
9. YIELD {gpm}:_METHOD OF' EST
10. 14VATFR ZONES (depth): 36 to 41 ft
11. CHLORINATION: Type
.2. CASING:
Depth
From +1.5 To 25 Ft,
From To FL
From -TO Ft.
13. GROUT
❑epth
From 0 To 22 Ft.
From 22 To 23 Ft
14. SCREEN:
Amount
DEPTH
From To
0-17.5
GW-t EnL
DRILLING LOG
Formation Description
Red to brown sandy
silt with trace clay
Gray garnet mica
schist
If additional space is needed use back of farm
LOCATION SKETCH
(Shaw direction and distance from at least two State
Roads, or other map reference points)
SR 2015
MW 11
1ti
Depth Diameter Slot Size Material
From 25 To 40 Ft Z in. •010 in. PVC
From To Ft. in. in.
From To Ft. in. in.
15. SAND/GRAVEL PACK:
Depth Size Material
From 23 To 41 Ft 2 Sand
From To Ft. N
16. REMARKS: monit-oring Well 11 Water first encountered at 36 ff
Wail Thickness
Diameter or WeighvFt- Material
2" Sch 40 PVC
Material Method
Cement Grout
Bentonite Pellet
I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 1 SA NCAC 2C. WELL
CONSTRUCTION STANDARDS, ANO THAT A COPY OF THIS RECORD HAS BEEN PROVIDED TO THE WELL OWNER.
�.(—
ZI07
L,;7
SIGNATUR F CONTRACTOR CR AGENT APE
GW-i REV 991 3::'_:m-1 ra3 to vi�isjor. ri E:",or:-. enta:'.'anaoerranz nra e:o: Na, .•N�r'
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
MW-12
MONITORING WELL
10I01��1914n•P1Kim
PROJECT: Mt. Airy Water Quality Assessment
LOCATION. Mt. Airy, NC
RAO&IkAumm
ENGINEERING, INC.
MONITORING WELL ID: MW-12S
CONSTRUCTION DATE: 5/31/2001
STAND PIPE CONSTRUCTION
MEASURING POINT ELEVATION 1025,80 ft AMSL
GEOLOGIC UNITS
PAD DIMENSIONS 3 feet x 3 feet
__1w _____ GROUND SURFACE ELEVATION 1023. ft AMSL
BOREHOLE DIAMETER 9 n_ches to 5 feet Jcw grade
4 inches from 5 feet to ❑
ANNULAR SPACE SEAL
TYPE OF SEAL Roanrzke Rortland Cement
RISER TYPE PVC
RISER DIAMETER 2 inches
TOP OF FILTER PACK SEAL
ELEVATION 1 17.25 ft AMSL
DEPTH B feet
FILTER PACK SEAL TYPE ShUr Plug 318 inch chi s
TOP OF FILTER PACK
ELEVATION 1014. ft AMSL
DEPTH 9.2 f9e
FILTER PACK TYPE 43 aradpd well sand
FILTER LACK SOURCE 05L
TOP OF SCREEN
ELEVATION i 012.25 ft AIMS
DEPTH 11 feet
SCREEN TYPE V
SCREEN DIAMETER 2 inches _
SLOT SIZE 0.01 d inch
BOTTOM OF SCREEN
.. ELEVATION 972.25 ft AMSL
DEPTH 51 feet
*.--BOTTOM OF BOREHOLE
ELEVATION 972.25 fit AMSL
DEPTH 51 feet
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
MW-12
MONITORING WELL
CONSTRUCTION LOG
PROJECT: Mt. Airy Water Quality Assessment
LOCATION: Mt. Airy,, NC �
ram► ■ rr�■�r
ENGINEERING, INC
MONITORING WELL ID:
CONSTRUCTION DATE.
STAND PIPE CONSTRUCTION
MW-12D
6/30/2001
MEASURING POINT ELEVATION 1027 �OL
PAD DIMENSIONS 3.feet x 3 feet
GROUND SURFACE ELEVATION 1023.75 ft AMSL
BOREHOLE DIAMETER 9 inches to 5 feet below grade
4 inches from 5 feet to bottom
ANNULAR SPACE SEAL
TYPE OF SEAL Roanoke Portland Cement
jr_mie arouted
RISER TYPE PVC
RISER DIAMETER 2 in
TOP OF FILTER PACK SEAL
ELEVATION 939.75 DEPTH ft AMSL
84 feet
FILTER PACK SEAL TYPE Shur Plua 318 inch chips
TOP OF FILTER PACK
ELEVATION 939.65 ft AMSL
DEPTH 87.1q feet
FILTER PACK TYPE k r r�gri well sand _
FILTER PACK SOURCE BSI _
TOP OF SCREEN
ELEVATION 933.75 AMSL
DEPTH 90 feet
SCREEN TYPE PVC
SCREEN DIAMETER 2 inches
SLOT SIZE 0.010 inch
BOTTOM OF SCREEN
ELEVATION 923.75 #t AMSL_
DEPTH 10Q feet
��-BOTTOM OF BOREHOLE
ELEVATION 923.75 ft AMSL
DEPTH 100 Feet
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
LOG OF BORING: MW-13
Surry County Closed, Mt. Airy
Project No. G06061.0
Drilling contractor: ❑errys Well Drilling
Date started: 5/30/2006
Surface elevation:
1005.75 ft (MSL)
Drill rig & method: 7.75" OD HSA
Date ended: 5/30/2006
Top of pipe elevation:
1008.48 ft (MSL)
Lagged by: J. Pfohl
Completion depth: 44.00 ft
Depth to water (TOB):
32.00 ft
Stickup height: 2.73 ft
Depth to water (24hrs):
24.17 ft
0 _
m
Well Diagram
u
ao
E
E
Description of Material & Remarks
o
N
N rn
CU
N
a
Y
Saprolite - Silty Sand
s
s
0
F
-
10
m
a
cLa
1'5
(V
m
0
m
m
20
=
25
Q
a
a
$
a
c
t
�
�
N
30
0
Water observed while drilling
s
N
35
40
m
�
m
m
C
m
Auger Refusal - Top of Competent Rock 961.75 ft. amsl.
45
Boring terminated at 44.0 feet
Municipal Engineering Services Company, P.A.
Operation/Construction Managers Civil/Sanitary EngineersEnvironmental Studies Page 1 of 1
PO Box 97, Gamer, Nodh CarokRa 27529 (919) 772-5393PO Box 349, Boone, North Carolina 28507 (828) 062-1767
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
LOG OF BORING: MW-14
Surry County Closed, Mt. Airy
Project No. G06061.0
Drilling contractor: ❑errys Well Drilling
Date started: 5/30/2006
Surface elevation:
1016.11 ft (MSL)
Drill rig & method: 7.75" OD HSAf6" OD DTH
Date ended: 5/30/2006
Top of pipe elevation:
1018.80 ft (MSL)
Logged by: J. Pfohl
Completion depth: 48.00 ft
Depth to water (TQB):
38.00 ft
Stickup height: 2.69 ft
Depth to water (24hrs):
38.50 ft
o
u
rn
m _
CL 75
E
r° >1
m
E
CU
Description of Material & Remarks
Well Diagram
N
Q
3
V
5
10
15
20
25
30
35
40
45
50
Saprolite - Silty Sand
----------------------------------------------------
Auger Refusal - Top of Competent Rock 1012.11 ft amsl
Schist, tan interlayered with saprolite, highly fractured.
-----------------------------------------------------
Gneiss- gray moderatley hard
Schist - brown, fractured
----------------------------------------------------
Gneiss
Schlst - brown, dry
Gneiss
----------------------------------------------------
Schist
Groundwater observed - solvent odor
-----------------------------------------------------
Gneiss
�
m
m
c�
C
0
m
o
a
N
c
�i
a
(V
o
a
0
0
0
0
fJ
—
Boring terminated at 48.0 feet
Municipal Engineering Services Company, P.A.
Operation/Construction Managers Civil/Sanitary EngineersEnvironmental Studies Page 1 of 1
PO Box 97, Gamer, Nodh CarokRa 27529 (919) 772-5393PO Box 349, Boone, North Carolina 28507 (828) 062-1767
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
LOG OF BORING: MW-15
Surry County Closed, Mt. Airy
Project No. G06061.0
Drilling contractor: Derrys Well Drilling
Date started: 6/22/2006
Surface elevation:
1073.23 ft (MSL)
Drill rig & method: 7.75" OD HSA14" OD DTH
Date ended: 6/22/2006
Top of pipe elevation:
1075.96 ft (MSL)
Lagged by: J. Pfohl
Completion depth: 57.00 ft
Depth to water (TOB):
49.50 ft
Stickup height: 2.73 ft
Depth to water (24hrs):
49.74 ft
t
❑
u
U%
m _
ao
E
.o n.
(�]
m
E
ro
Description of Material & Remarks
Saprolite - Silty Sand
----------------------------------------------------
PWR - Hard Drilling
- -------------------------------------------------
Auger Refusal - Top of Competent Rock 1045.23 ft amsl - Schist
---------------------- ------------------------------
Highly weathered rock
Returned to competent rock
Well
Diagram
N
Q
Y
5
10
15
r�
20
25
J-
30
35
40
45
50
55
60
3
O
m
m
U
m
0
m
I
IL
a
co
`
p�
N
�
a
a
N
a
t
0
o
N
0
c
0
N
Boring terminated at 57.0 feet
Municipal Engineering Services Company, P.A.
Operation/Construction Managers Civil/Sanitary EngineersEnvironmental Studies Page 1 of 1
PO Box 97, Gamer, Nodh CarokRa 27529 (919) 772-5393PO Box 349, Boone, North Carolina 28507 (828) 062-1767
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
LOG OF BORING: MW-16
Surry County Closed. Mt. Airy Project No. G06061.0
Drilling contractor: ❑errys Well Drilling Date started: 6/21 /2006 Surface elevation: 996.67 tt (MSL)
Drill rig & method: 7.75" OD HSAf4" OD DTH Date ended: 6/21 /2006 Top of pipe elevation: 999.54 ft (MSL)
Lagged by: J. Pfohl Completion depth: 36.28 ft Depth to water (TQB):
Stickup height: 2.87 ft Depth to water (24hrs): 26.94 ft
t
o
u
N
m _
ao
E
N rn
m
E
c
Description of Material & Remarks
Well Diagram
N
Q
3
Y
5
10
1'5
20
25
30
35
40
45
Saprolite - Silty Sand
------------------------------------------------
Auaer Refusal - Top of Competent Rock 987.67 ft amsl
Gneiss/Schist
Boring terminated at 36.3 feet
Xx
om
`-
a
(V
c
0
m
m
r'!aj
— a
a o
a �
c
Vi N
0
0
0
- o
fJ
Municipal Engineering Services Company, P.A.
Operation/Construction Managers Civil/Sanitary EngineersEnvironmental Studies Page 1 of 1
PO Box 97, Gamer, Nodh CarokRa 27529 (919) 772-5393PO Box 349, Boone, North Carolina 28507 (828) 062-1767
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
LOG OF BORING: MW-17
Surry County, Mt. Airy Closed Project No. G07063.0
Drilling contractor: Derry's Well Drilling Date started: 6/1/2007 Surface elevation: 962.26 ft (MSL)
Drill rig & method: 5.5" DTH Date ended: 6/112007 Top of pipe elevation: 965.43 ft (MSL)
Lagged by: J. Pfohl Completion depth: 15.32 ft Depth to water (TQB): 9.48 ft
Stickup height: 3.17 ft Depth to water (24hrs): 8.83 ft
u
m _
ao
m
Well Diagram
t
E
E
Description of Material & Remarks
F
❑
rn
•o n.
rn 0
ro
c
3
V
I-
Gniess; grey, competent
3 f6
a
m $
o �
5
c vy
m
(yV
Q
a
r z
mr
10
`� o
C
N
N >
a
N o
vt �
t
1'5
Boring terminated at 15.3 feet
20
25
30
35
40
45
Municipal Engineering Services Company, P.A.
Operation/Construction Managers Civil/Sanitary EngineersEnvironmental Studies Page 1 of 1
PO Box 97, Gamer, Nodh CarokRa 27529 (919) 772-5393PO Box 349, Boone, North Carolina 28507 (828) 062-1767
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
LOG OF BORING: MW-18
Surry County, Mt. Airy Closed Project No. G07061.0
Drilling contractor: Derry's Well Drilling Date started: 6/1/2007 Surface elevation:
Drill rig & method: 7.75 ❑D HSA wl SS Date ended: 6/112007 Top of pipe elevation:
Lagged by: J. Pfohl Completion depth: 18.15 ft Depth to water (TOB): 10.18 ft
Stickup height: Depth to water (24hrs): 9.98 ft
t
o
u
N
1
65
0 _
ap
E
N rn
m
E
CU
Description of Material & Remarks
Silty Sand; Dark brown with red clay nodules+ micaceous, moist
---- ------------------------------------------------
Silty SandlSaprolite; moderate brown, few angular schist fragments,
Well Diagram
a
5
dense relic structure, micaceous, moist
m
�
0 U
r�
C6 N
89110
:::::::::;
Silty SandlSaprolite; dark brown, angular schist fragments, defined relic
structure, micaceous, moist
a
10
— �
r �
cam+ o
IL
a
5015
J
Silty SandlSaprolite; same as above with more schist fragments, slightly
N
x
weathered rock, wet
a
1'5
�
u
N
Boring terminated at 18.1 feet
20
25
30
35
40
45
Municipal Engineering Services Corrurpany, P.A.
Operation/Construction Managers Civil/Sanitary Eng;neersEnvironmental Studies Page 1 of 1
PO Box 97, Gamer, !North CarokRa 27529 (919) 772-5393PO Box 349, Boone, North Carolina 28507 (828) 062-1767
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
LOG OF BORING: MW-19
Surry County, Mt. Airy Closed
Project No. G07063.0
Drilling contractor: Derry's Well Drilling
Date started: 6/1/2007
Surface elevation:
942.97 ft (MSL)
Drill rig & method: 7.75 HSA w/SS, 5.5 DTH
Date ended: 6/112007
Top of pipe elevation:
946.27 ft (MSL)
Lagged by: J. Pfohl
Completion depth: 17.10 ft
Depth to water JOB):
10.03 ft
Stickup height: 3.30 ft
Depth to water (24hrs):
9.57 ft
u
m _
ao
m
Well Diagram
E
E
Description of Material & Remarks
❑
rn
•o n.
rn 0
ro
co
V
c
3
V
21
Sandy Silt; dark brown, with few black root fragments, high organic
UVmicaceous, moist
o
a
� o
5
= a
o r
m
HSA Reiusal on Rock seam (begin DTH)
°' N
50/3
..
PW R; moderately weathered rock, schist, brown, micaceous, dry
n
10
r = o
v c
5012
NO Recovery - PW R; moderately weathered rock, brown, schist
� c
N - o
a
0
a
TOP OF COMPETENT ROCK = 925.89 ft amsl
Boring terminated at 17.1 feet
20
25
30
35
40
45
Municipal Engineering Services Company, P.A.
Operation/Construction Managers Civil/Sanitary EngineersEnvironmental Studies Page 1 of 1
PO Box 97, Gamer, Nodh CarokRa 27529 (919) 772-5393PO Box 349, Boone, North Carolina 28507 (828) 062-1767
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
LOG OF BORING: MW-20
Surry County, Mt. Airy Closed
Project No. G07061.0
Drilling contractor: Derry's Well Drilling
Date started: 6/1/2007
Surface elevation:
1079.12 ft (MSL)
Drill rig & method: 5.5 DTH w/SS
Date ended: 6/1/2007
Top of pipe elevation:
1082.19 ft (MSL)
Lagged by: J. Pfohl
Completion depth: 25.64 ft
Depth to water JOB):
20.93 ft
Stickup height: 3.07 ft
Depth to water (24hrs):
19.53 ft
u
0 _
ao
m
Well Diagram
E
E
Description of Material & Remarks
❑
rn
.o n.
rn 0
ro
co
Q
3
V
1
Silty Sand with Clay; red -brown, moderately cohesive, moist
sale
Silty Sand/Saprolite; dense angular rock fragments, few black silt
partings, micaceous, dry
5
----------------------------------------------------
v
t
HSA Refusal - TOP OF COMPETENT ROCK = 1072.12 ft amsl
o N
Gneiss grey competent, no evident fractures
10
1'5
m
o-
groundwater encountered
o
N
a
.g o
c
m
rA o
a �
20
o
a
r
N
25
Boring terminated at 25.6 feet
30
35
40
45
Municipal Engineering Services Company, P.A.
Operation/Construction Managers Civil/Sanitary EngineersEnvironmental Studies Page 1 of 1
PO Box 97, Gamer, Nodh CarokRa 27529 (919) 772-5393PO Box 349, Boone, North Carolina 28507 (828) 062-1767
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
LOG OF BORING: MW-21
Surry County, Mt. Airy Closed
Project No. G07063.0
Drilling contractor: Derry's Well Drilling
Date started:
6/1/2007
Surface elevation:
962.22 ft (MSL)
Drill rig & method: 7.5 OD HSA w/SS, 5.5 DTH
Date ended:
6/1/2007
Top of pipe elevation:
965.36 ft (MSL)
Logged by: J. Pfohl
Completion depth:
15.41 ft
Depth to water (TOB):
6.23 ft
Stickup height:
3.14 ft
Depth to water (24hrs):
6.10 ft
Cr_1
a
0 _
ao
m
Well Diagram
t
E
E
Description of Material & Remarks
a
❑
to
•o n.
rn 0F
ro
3
J�
Silty Sand; dark brown, micaceous, high organic content, few angular
V
14
schist fragments, moist
°
c� o
ro a
o
o �
c =
5
-----------------------------------------------------
HSA Refusal on rock seam
m N
----------------------------------------------------
Sandy Silt/Saprolite; relict structure, wet, almost PWR
r o
N
10
----------------------------------------------------
TOP OF COMPETENT ROCK = 952.22 ft amsl
a o
P
W
� a
0
a
large fracture - water encountered
N
15
Boring terminated at 15.4 feet
20
25
30
35
40
45
Municipal Engineering Services Company, P.A.
Operation/Construction Managers Civil/Sanitary EngineersEnvironmental Studies Page 1 of 1
PO Box 97, Gamer, Nodh CarokRa 27529 (919) 772-5393PO Box 349, Boone, North Carolina 28507 (828) 062-1767
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
LOG OF BORING: MW-22
Surry County, Mt. Airy Closed Project No. G07063.0
Drilling contractor: Derry's Well Drilling Date started: 6/1/2007 Surface elevation: 950.23 tt (MSL)
Drill rig & method: 5.5 OD DTH Date ended: 6/1/2007 Top of pipe elevation: 953.40 ft (MSL)
Lagged by: J. Pfohl Completion depth: 16.04 ft Depth to water (TOB): 4.63 ft
Stickup height: 3.17 ft Depth to water (24hrs): 4.60 ft
u
_
ao
m
Well Diagram
t
E
E
Description of Material & Remarks
F
❑
rn
•o n.
rn 0
ro
co
7
3
Sandy Silt; dark brown, few black root fragments, high organic content,
V
3
micaceous, moist
U
550/¢X
Sandy Silt/Saprolite; moderately brown, dense, several angular rock
5
fragments, moist, heavily weathered rock
fJ
8.3
Sandy Silt; same as above, wet
01
Q
a
10
m w
o
o
m
Vj o
a 7
a
5013
TOP OF COMPETENT ROCK = 936.23 ft amsl; moderately weathered
15
gneiss, wet
Boring terminated at 16.0 feet
20
25
30
35
40
45
Municipal Engineering Services Company, P.A.
Operation/Construction Managers Civil/Sanitary EngineersEnvironmental Studies Page 1 of 1
PO Box 97, Gamer, Nodh CarokRa 27529 (919) 772-5393PO Box 349, Boone, North Carolina 28507 (828) 062-1767
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
LOG OF BORING: MW-23
Surry County, Mt. Airy Closed Project No. G07063.0
Drilling contractor: Derry's Well Drilling Date started: 6/1/2007 Surface elevation: 952.09 tt (MSL)
Drill rig & method: 7.75 ❑D HSA w1SS Date ended: 6/112007 Top of pipe elevation: 955.31 ft (MSL)
Lagged by: J. Pfohl Completion depth: 17.10 ft Depth to water (TOB): 8.19 ft
Stickup height: 3.22 ft Depth to water (24hrs): 8.16 ft
❑
u
rn
m _
ao
E
•o n.
rn 0
m
E
ro
Description of Material & Remarks
Well Diagram
V
3
V
2
Sandy Silt with clay; red -brown, relict structure, organic debris, moist
3 N
_O i6
(J
33
Sandy Silt; dark brown, few balck organic silt nodules, micaceous, moist
o
�
a
o r
m
07 (V
3s
Sandy Silt; same as above, wet
i a
n
10
Y o
IL
v c
� c
41
Sandy Silt; moderate brown, few angular schist fragments, micaceous,
co
a
1'5
wet
�
N
Boring terminated at 17.1 feet
20
25
30
35
40
45
Municipal Engineering Services Campany, P.A.
Operation/Construction Managers Civil/Sanitary EngirieersEnvironmentai Studies Page 1 of 1
PO Box 97, Gamer, Nodh CarokRa 27529 (919) 772-5393PO Box 349, Boone, Noah Carolina 28607 (828) 262-1767
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
Mw. 13
3.
NON-RESIDENTIAL ONRESIDENTIAL WELL CONSTRUCTION RECORD
North Carolina Department of Environment and Natural Resources- Division of Water Quality
WELL CONTRACTOR CERTIFICATION # 2663
1. WELL CONTRACTOR:
Derry Huneycutt
Well Contractor (Individual) Name
Derry's Well Drilling
Well Contractor Company Name
STREET ADDRESS 44283-A NC 24/27/73
Albemarle NC 28002
City or Town State Zip Code
704 - 982-3070
Area code- Phone number
2. WELL INFORMATION:
SITE WELL ID #(if applicable)
STATE WELL PERMIT#(if applicable)
DWQ or OTHER PERMIT #(if applicable)
WELL USE (Check Applicable Box) Monitoring © Municipal/Public ❑
Industrial/Commercial ❑ Agricultural ❑ Recovery ❑ Injection ❑
Irrigation❑ Other ❑ (list use)
DATE DRILLED 5/30/06
TIME COMPLETED 2:30
3. WELL LOCATION:
CITY: Ararat
AM❑ PMO
COUNTY NC
419 Landfill Road 27007
(Street Name, Numbers, Community, Subdivision, Lot No., Parcel, Zip Code)
TOPOGRAPHIC / LAND SETTING:
®Slope ❑ Valley ❑ Flat ❑ Ridge ❑ Other
(check appropriate box)
LATITUDE May be in degr'es,
minutes, seconds or
LONGITUDE SC 3�L -Of,�W 1 in a decimal format
Latitude/longitude source: gGPS ❑Topographic map
(location of well must be shown on a USGS topo map and
attached to this form if not using GPS)
4. FACILITY- is the name of the business where the well is located.
FACILITY ID #(if applicable)
NAME OF FACILITY Surry Co. Closed Landfill
STREET ADDRESS 419 Landfill Road
Ararat NC 27007
City or Town State Zip Code
CONTACT PERSON Mr. Jerry Snow
MAILING ADDRESS PO Box 1542
Mount Airy NC 27030
City or Town State Zip Code
33( 6 _)_ 401-8376
Area code - Phone number
S. WELL DETAILS:
a. TOTAL DEPTH: 35.78'
b. DOES WELL REPLACE EXISTING WELL? YES ❑ NO B
c. WATER LEVEL Below Top of Casing: 26.90 FT.
(Use "+" if Above Top of Casing)
d. TOP OF CASING IS 3.00 FT. Above Land Surface"
'Top of casing terminated at/or below land surface may require
a variance in accordance with 15A NCAC2C .0118.
e. YIELD (gpm): na METHOD OF TEST na
f. DISINFECTION: Type na Amount na
g. WATER ZONES (depth):
From To From To
From To From To
From To From To
6. CASING: Thickness/
Depth Diameter Weft X Material
at rial
From 0 To 20.78 Ft. 2" sc
From To Ft.
From To Ft.
7. GROUT: Depth Material Method
From 0 To 16.5 Ft Neat Cement Tremie
From 16.5 To�— Ft. 316" Bentonite Chips Pour
From 35.78 To 44 Ft Neat Cement Tremie
8. SCREEN: Depth Diameter Slot Size Material
From 20.78 To 35.78 Ft.2" in. 0.10 in. PVC
From To Ft. in. in.
From To Ft. in. in.
9. SAND/GRAVEL PACK:
Depth Size Material
From 19.5 To 35.78 Ft. #2 Filter Sand
From To Ft.
From To Ft.
10. DRILLING LOG
From To Formation Description
0 44 SwUrol;fP.
11. REMARKS:
MW-13 Installed as type II MW for monitoring downgradient of closed MSWLF
I DO HEREBY C FY THAT TH WELL WAS CONSTRUCTED IN ACCORDANCE WITH
15A NCAC 2C LL C TR ON STANDARDS, AND THAT A COPY OF THIS
RECOR H EES OVI 0THE WELL OWNER.
7/1/06
SIGNA E OF CERTOIED WELL CONTRACTOR DATE
©l retldvAevi ✓#
PRINTECINAME OF PERSON CONSTRUCTING THE WELL
Submit the original to the Division of Water Quality within 30 days. Attn: Information Mgt., Form GWAb
1617 Mail Service Center —Raleigh, INC 27699-1617 Phone No. (919) 733-7016 ext 668. Rev. 7/05
Docusign Envelolpe ID: 889599EA-C817-4865-93DD-lB8535D719AE
s srrMW 14
1 r ONlIESIDENTIAL WELL CONSTRUCTION RECORD
North Carolina Department of Environment and Natural. Resources- Division of Water Quality
WELL CONTRACTOR CERTIFICATION # 2663
>«,•'
1. WELL CONTRACTOR:
Derry Huneycutt
Well Contractor (Individuall Name
Derry's Well Drilling
Well Contractor Company Name
STREET ADDRESS 44283-A NC 24/27/73
Albemarle NC 28002
City or Town State Zip Code
70L 4_)_ 982-3070
Area code Phone number
2. WELL INFORMATION:
SITE WELL ID #(if applicable)
STATE WELL PERMIT#(if applicable)
DWQ or 01fHER PERMIT #(if applicable)
WELL USE (Check Applicable Box) Monitoring © Municipal/Public ❑
Industrial/Commercial ❑ Agricultural ❑ Recovery ❑ Injection ❑
Irrigation[] Other ❑ (list use)
DATE DRILLED 5/30/06
TIME COMIPLETED 6:30 AM ❑ PM O
3. WELL LOQATION:
CITY: Ara�lrat COUNTY NC
419 Landfill Road 27007
(Street Nartie, Numbers, Community, Subdi�sion, Lot No., Parcel, Zip Code)
TOPOGR IIPHIC / LAND SETTING:
❑ Slope ❑alley & Flat ❑ Ridge [I Other
(heck appropriate box)
LATITUDE 3b'aE 03.1315 May be in degrees,
minutes, seconds or
LONGITUDE 0 � 011e3fhl T in a decimal format
Latitude/longitude source: aGPS ❑Topographic map
(location of well must be shown on a USGS topo map and
attached to this form if not using GPS)
4. FACILITY1 is the name of the business where the well is located.
FACILITY11D #(if applicable)
NAME OFI FACILITY Surry Co. Closed Landfill
STREET ADDRESS 419 Landfill Road
Ararat NC 27007
City or Town State Zip Code
CONTACT PERSON Mr. Jerry Snow
MAILING ADDRESS PO Box 1542
Mount Airy NC 27030
City
or Town State Zip Code
( 336
j_ 401-8376
Phone number
Area codes(-
5. WELL DETAILS:
TOTAL
DEPTH: 48.03'
a.
b. DOES
WELL REPLACE EXISTING WELL? YES ❑ NO p
c. WATE
LEVEL Below Top of Casing: 41.19 FT.
(Use "+" if Above Top of Casing)
d. TOP OF CASING IS 3.00 FT. Above Land Surface'
'Top of casing terminated at/or below land surface may require
a variance in accordance with 15A NCAC 2C .0118.
e. YIELD (gpm): na METHOD OF TEST na
f. DISINFECTION: Type na Amount na
g. WATER ZONES (depth):
From 38.18 To From To
From To From To
From To From To
6. CASING: Thickness/
Depth Diameter WehV Material P
From 0 To 33.03 Ft. 2" sc
From To Ft.
From To Ft.
7. GROUT: Depth Material Method
From 0 To 29.5 Ft. Neat Cement Tremie
From 29•5 Tom— Ft. 3/8" Bentonite chips Pour
From To Ft.
8. SCREEN: Depth Diameter Slot Size Material
From 33.03 To 48.03 Ft.2" in. 0.10 in. PVC
From To Ft. in. in.
From To Ft. in. in.
9. SAND/GRAVEL PACK:
Depth Size Material
From 32 To 48.03 Ft. #2 Filter Sand
From To Ft.
From To Ft.
10. DRILLING LOG
From To Formation Description
0 6 Soil
6 48.03 PWR to Rock
11. REMARKS:
MW-14 Installed as type II MW for monitoring downg radiant of closed MSWLF
I DO HEREBY CXDFY THAT THIS E L WAS CONSTRUCTED IN ACCORDANCE WITH
15A NCAC 2C LL CON UC O STANDARDS, AND THAT A COPY OF THIS
RECORD EN PPAIDE HE WELL OWNER.
7/1/06
SI U O CE IF DWELL CONTRACTOR DATE
D1101 R. "n cv c "rt
PRINTEP NAME OF PERSON CONSTRUCTING THE WELL
Submit the original to the Division of Water Quality within 30 days. Attn: Information Mgt., Form Gw-1b
1617 Mail Service Center — Raleigh, NC 27699-1617 Phone No. (919) 733-7016 ext 668. Rev. 7/05
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
4r, Tt
<,
NONRESIDENTIAL ' WELL CONSTRUCTION RECORD (AW
North Carolina Department of Environment and Natural Resources -Division of Water Quality
WELL CONTRACTOR CERTIFICATION # 2663
1. WELL C
NTRACTOR:
Derry H
neycutt
Well Contractor
(Individual) Name
Derry's
ell Drilling
Well Con ractor
Company Name
STREET
DDRESS 44283-A NC 24/27/73
NC 28002
Albema le
ty
or Town State Zip Code
_ 982-3070
od
Phone number
2. IN
ORMATION:
W
LL ID #(if applicable)
E
ELL PERMIT#(if applicable)
or
THEIR PERMIT #(if applicable)
WSE (Check
Jad
Applicable Box) Monitoring © Municipal/Public ❑
Indl/C
mmercial ❑ Agricultural ❑ Recovery ❑ Injection ❑
on
Other ❑ (list use)
DR
LLED 6/22/06
CO
PLETED 8:30 AM❑ PM3.
LO
ATION:
Ar
rat COUNTY NC
419 Land
ill Road 27007
(Street Na
e, Numbers, Community, Subdivision, Lot No., Parcel, Zip Code)
TOPOGR
PHIC / LAND SETTING:
IIII Slope ❑
Valley ❑ Flat ❑ Ridge ❑ Other
LATITUD
LONGITU
check appropriate box)
3 UI . i May be in degrees,
minutes, seconds or
E !LO i 3 • i� 3� in a decimal format
Latitude/1
ngitude source: 4GPS ❑Topographic map
11ocatio
of well must be shown on a USGS topo map and
attach
d to this form f not using GPS)
4. FACILITY
is the name of the business where the well is located.
FACILITY
ID #(if applicable)
NAME OF
FACILITY Surry Co. Closed Landfill
DDRESS 419 Landfill Road
STREET
NC 27007
Ararat
City or
own State Zip Code
CONTACT
PERSON Mr. Jerry Snow
DDRESS PO Box 1542
MAILING
NC 27030
Mount Ai
City o
Town State Zip Code
( 336 )
401-8376
Area code
Phone number
5. WELL DETAILS:
a. TOTAL
EPTH: 56.98'
b. DOES
ELL REPLACE EXISTING WELL? YES ❑ NO
c. WATER
LEVEL Below Top of Casing: 52.47 FT.
(Use "+" if Above Top of Casing)
d. TOP OF CASING IS 3.00 FT. Above Land Surface*
*Top of casing terminated at/or below land surface may require
a variance in accordance with 15A NCAC 2C .0118.
e. YIELD (gpm): na METHOD OF TEST na
f. DISINFECTION: Type na Amount na
g. WATER ZONES (depth):
From 49.47 To From To
From To From To
From To From To
6. CASING: Thickness/
Depth Diameter WeigMaterial
From 0 To 41.98 Ft. 2" sat PVC
From To Ft.
From To Ft.
7. GROUT: Depth Material Method
From 0 To 37.5 Ft Neat Cement Tremie
From 37.5 Tom" Ft. 318" Bentonite Chips Pour
From To Ft.
8. SCREEN: Depth Diameter Slot Size Material
From 41.98 To 56.98 Ft.2" in. 0.10 in. PVC
From To Ft. in. in.
From To Ft. in. in.
9. SANDIGRAVEL PACK:
Depth Size Material
From 40.38 To 56.98 Ft. #2 Filter Sand
From To Ft.
From To Ft.
10. DRILLING LOG
From To Formation Description
0 28 Soil
28 56.98 Rock
11. REMARKS:
MW-15 Installed as type II MW for monitoring downgradient of closed MSWLF
I DO HEREBY CE YTHAT THIS ELL WAS CONSTRUCTED IN ACCORDANCE WITH
t5A NCAC 2C, WL
CO RUCT STANDARDS, AND THAT A COPY OF THIS
RECORD N P TR E WELL OWNER.
7/1 /06
SIG A U OF CERTI D WELL CONTRACTOR DATE
pert v
PRINT D NAME 09 PERSON CONSTRUCTING THE WELL
Submit the riginal to the Division of Water Quality within 30 days. Attn: Information Mgt., Form GW-1b
1617 Mail Se ice Center— Raleigh, NC 27699-1617 Phone No. (919) 733-7015 ext 568, Rev. 7105
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
S1A P
k551
NONRESIDENTIAL WELL CONSTRUCTION RECORD
I N YI.
ti;!/ North Carolina Department of Envirorunent and Natural Resources- Division of Water Quality
WELL CONTRACTOR CERTIFICATION # 2663
1. WELL CONTRACTOR:
Derry Huneycutt
Well Contractor (Individual) Name
Derry's Well Drilling
Well Contractor Company Name
STREET ADDRESS 44283-A NC 24/27/73
Albemarle NC 28002
City or Town State Zip Code
70( 4 mil- 982-3070
Area code- Phone number
2. WELL INFORMATION:
SITE WELL ID #(if applicable)
STATE WELL PERMIT#(if applicable)
DWQ or OTHER PERMIT #(if applicable)
WELL USE (Check Applicable Box) Monitoring © Municipal/Public ❑
Industrial/Commercial ❑ Agricultural ❑ Recovery ❑ Injection ❑
Irrigation❑ Other ❑ (list use)
DATE DRILLED 6/21/06
TIME COMPLETED 8:15 AMU PM EI
3. WELL LOCATION:
CITY: Ararat COUNTY NC
419 Landfill Road 27007
(Street Name, Numbers, Community, Subdi\hsion, Lot No., Parcel, Zip Code)
TOPOGRAPHIC / LAND SETTING:
*Slope Walley ❑Flat ❑Ridge ❑ Other
(check appropriate box)
LATITUDE _21 '16 ©ti . Cg10k May be in degrees,
minutes, seconds or
LONGITUDE ,O Q in a decimal format
Latitude/longitude source: mGPS ❑Topographic map
(location of well must be shown on a USGS topo map and
attached to this form if not using GPS)
4. FACILITY- is the name of the business where the well is located.
FACILITY ID #(if applicable)
NAME OF FACILITY Surry Co. Closed Landfill
STREET ADDRESS 419 Landfill Road
Ararat NC 27007
City or Town State Zip Code
CONTACT PERSON Mr. Jerry Snow
MAILING ADDRESS PO Box 1542
Mount Airy NC 27030
City or Town State Zip Code
( 336 )- 401-8376
Area code - Phone number
5. WELL DETAILS:
a. TOTAL DEPTH: 36.28'
In. DOES WELL REPLACE EXISTING WELL? YES ❑ NO E9
c. WATER LEVEL Below Top of Casing: 26.94 FT.
(Use "+" if Above Top of Casing)
d. TOP OF CASING IS 3.00 FT. Above Land Surface*
*Top of casing terminated at/or below land surface may require
a variance in accordance with 15A NCAC 2C .0118.
e. YIELD (gpm): na METHOD OF TEST na
f. DISINFECTION: Type na Amount na
g. WATER ZONES (depth):
From 23.94 To From To
From To From To
From To From To
6. CASING: Thickness/
Depth Diameter We' hb Material
From 0 To 21.28 Ft. 2" sc 4 PVC
From To Ft.
From Tc Ft.
7. GROUT: Depth Material Method
From 0 To 18.25 Ft Neat Cement Tremie
From 18.25 Tom— Ft. 3l8" Sentonite Chips Pour
From To Ft.
8. SCREEN: Depth Diameter Slot Size Material
From 21.28 To 36.28 Ft.2" in. 0.10 in PVC
From To Ft. in. in.
From To Ft. in. in.
9. SANDIGRAVEL PACK:
Depth Size Material
From 20.5 To 36.28 Ft, #2 Filter Sand
From To Ft. -
From Tc Ft.
10. DRILLING LOG
From To Formation Description
0 9 Soil
9 36.28 Rock; Gneiss
11. REMARKS:
MW-16 Installed as type II MW for monitoring downgradient of closed MSWLF
I DO HEREBY C FY THAT IS L AS CONSTRUCTED IN ACCORDANCE WITH
15A NCAC 2C LL CO uc-n ANDARDS, AND THAT A COPY OF THIS
RECORD EENP DED T WELLER.
I
7/1/06
SIGNATL,PE OF CERTIFI ELL CONTRACTOR DATE
I)srh/ yn'LV &-
PRINTE NAME OFIPERSON CONSTRUCTING THE WELL
Submit the original to the Division of Water Quality within 30 days. Attn: information. Mgt., Form GW-1b
1617 Mail Service Center — Raleigh, NC 27699-1617 Phone No. (919) 733.7015 ext 568. Rev. 7/05
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
SI ire
NONRESIDENTIAL WELL CONSTRUCTION RECORD
y: Ir o North Carolina Department of Environment and Natural Resources- Division of Water Quality
�`� • > ? WELL CONTRACTOR CERTIFICATION # 2663
1. WELL CONTRACTOR:
Derry Huneycutt
Well Contractor (Individual) Name
Derry's Well Drilling Inc.
Well Contractor Company Name
STREETADDRESS 44283-A NC 24/27/73
Albemarle NC 28002
City or Town State Zip Code
704 )- 982-9070
Area code- Phone number
2. WELL INFORMATION:
SITE WELL ID #(if applicable) MW-17
WELL CONSTRUCTION PERMIT#(if applicable)
OTHER ASSOCIATED PERMIT #(if applicable)
3. WELL USE (Check Applicable Box) Monitoring❑ Municipal/Public❑
Industrial/Commercial❑ Agricultural❑ Recovery❑ Injection❑
Irdgation0 OtherO (list use)
DATE DRILLED 6/1/07
TIME COMPLETED 9:30 AMIN PM❑
4. WELL LOCATION:
CITY: Ararat COUNTY NC
419 Landfill Rd. a7007
(Street Name, Numbers, Community, Subdivision, Lot No., Parcel, Zip Code)
TOPOGRAPHIC / LAND SETTING:
❑ Slope I Valley ❑ Flat ❑ Ridge ❑ Other
(check appropriate box)
May be in degrees,
LATITUDE 36.4338922 minutes, seconds or
LONGITUDE 80.572245 in a decimal format
Latitude/longitude source: 5 GPS ❑ Topographic map
(location of well must be shown on a USGS topo map and
attached to this form if not using GPS)
5. FACILITY- is the name of the business where the well is located.
FACILITY ID #(if applicable)
NAME OF FACILITY Slurry Co. Closed MSWLF
STREETADDRESS 419 Landfill Rd.
Ararat NC 27007
City or Town State Zip Code
CONTACT PERSON Mr. Jerry Snow
MAILING ADDRESS PO BOX 1542
Mount Airy NC 27030
City or Town State Zip Code
(336 )-401-8376
Area code - Phone number
6. WELL DETAILS:
a. TOTAL DEPTH: 15.32
b. DOES WELL REPLACE EXISTING WELL? YES❑ NOS
c. WATER LEVEL Below Top of Casing: 8.83 FT.
(Use "+" if Above Top of Casing)
d. TOP OF CASING IS 3.00 FT. Above Land Surface"
"Top of casing terminated aUor below land surface may require
a variance in accordance with 15A NCAC 2C .0118.
e. YIELD (gpm): na METHOD OF TEST na
f. DISINFECTION: Type na Amount na
g. WATER ZONES (depth):
From 10 To 10.5 From To
From To From To
From To From To
7. CASING: IThickness/
Depth lameter Wei hhV� Material
From-0 To 5•32 Ft. SCf`140 PVC
From To Ft.
From To Ft.
8. GROUT: Depth Material Method
From 0 To 3 Ft. Neat Cement Pour
From--3 To 5.10 Ft. 3/8" Bent. Chips Pour
From To Ft.
9. SCREEN: Depth Diameter Slot Size Material
From 5.32 To 15.32 Ft. 2 in. 0.01 in. PVC
From To Ft. in. in.
From To Ft. in. - in.
10. SAND/GRAVEL PACK:
Depth Size Material
From 5.)() To 15.31 Ft. #2 �FilteF Sand --
From To Ft.
From To Ft.
11.DRILLING LOG
From To Formation Description
0 IS•31 Rock } Gr.:V Gneiss
12. REMARKS:
FIRg
�+^wngradient of closed N4S1A1LF
I DO HEREBY CE Y THAT THIS WEL AS CONSTRUCTED IN ACCORDANCE WITH
15A NCAC 2C, L PRO CONS UCTION TANDARDS, AND THAT A COPY OF THIS
RECORD H S N EDT E WELL OW
SIGNA R OF CERTI IE EL CONTRACTOR DATE
Decn� 1.- 4t,li2(1CA
PRINTED E OF PERSON C STRUCTING THE WELL
Submit the original to the Division of Water Quality within 30 days. Attn: Information Mgt., Form GW-1b
1617 Mail Service Center — Raleigh, NC 27699-1617 Phone No. (919) 733-7015 ext 568. Rev. 3/07
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
NONRESIDENTIAL WELL CONSTRUCTION RECORD
North Carolina Department of Environment and Natural Resources- Division of Water Quality
WELL CONTRACTOR CERTIFICATION # 2663
1. WELL CONTRACTOR:
Derry Huneycutt
Well Contractor (Individual) Name
Derry's Well Drilling Inc.
Well Contractor Company Name
STREET ADDRESS 44283-A NC 24/27/73
Albemarle NC 28002
City or Town State Zip Code
7( 04 )- 982-9070
Area code- Phone number
2. WELL INFORMATION:
SITE WELL ID #(if applicable) MWA 8
WELL CONSTRUCTION PERMIT#(if applicable)
OTHER ASSOCIATED PERMIT #(if applicable)
3. WELL USE (Check Applicable Box) Monitoring0 Municipal/Public❑
Industrial/Commercial❑ Agricultural❑ Recovery[] Injection❑
Irrigation0 OtherO (list use)
DATE DRILLED 6/1/07
TIME COMPLETED 1 :20 AM❑ PM®
4. WELL LOCATION:
CITY: Ararat COUNTY NC
419 Landfill Rd. a100 7
(Street Name, Numbers, Community, Subdivision, Lot No., Parcel, Zip Code)
TOPOGRAPHIC / LAND SETTING:
❑ Slope i Valley ❑ Flat ❑ Ridge 0 Other
(check appropriate box)
May be in degrees,
LATITUDE 36.433015639 minutes, seconds or
LONGITUDE 80.572032 in a decimal format
Latitude/longitude source: 0 GPS ❑ Topographic map
(location of well must be shown on a USGS topo map and
attached to this form if not using GPS)
5. FACILITY- is the name of the business where the well is located.
FACILITY ID #(if applicable)
NAME OF FACILITY Surry Co. Closed MSWLF
STREET ADDRESS 419 Landfill Rd.
Ararat NC 27007
City or Town State Zip Code
CONTACT PERSON Mr. Jerry Snow
MAILING ADDRESS PO Box 1542
Mount Airy NC 27030
City or Town State Zip Code
(336 )-401-8376
Area code - Phone number
6. WELL DETAILS:
a. TOTAL DEPTH: 18.15
b. DOES WELL REPLACE EXISTING WELL? YES❑ NOO
c. WATER LEVEL Below Top of Casing: 9.98 FT.
(Use "+" if Above Top of Casing)
d. TOP OF CASING IS 3.00 FT. Above Land Surface*
*Top of casing terminated at/or below land surface may require
a variance in accordance with 15A NCAC 2C .0118.
e. YIELD (gpm): na METHOD OF TEST na
f. DISINFECTION: Type na Amount na
g. WATER ZONES (depth):
From 6.98 To 18.15 From To
From To From To
From To From To
7. CASING: Thickness/
Depth lameter Weight Material
From 0 To 8.15 Ft, i tic:nl+u F'VU
From To Ft.
From To Ft.
8. GROUT: Depth Material Method
From 0 To 5 Ft. Neat Cement Tremie
From_5 To 7 Ft. 3/8" Bent. Chi Pour
From To Ft.
9. SCREEN: Depth Diameter Slot Size Material
From 8.15 To 18.15 Ft. 2 in. 0.01 in. PVC
From To Ft. in. in.
From To Ft. in. in.
10. SAND/GRAVEL PACK:
Depth Size Material
From 7 To 1% J S Ft. #2 Foke.
Sand
From To Ft.
From To Ft.
11.DRILLING LOG
From To Formation Description
O 3.5 $, S f
3.5 t�•Ig
1'N4 P r� [n1 [ iJI t0�
12. REMARKS:
MIN 1 o Installed as type tt 11411Ar f„r menit9finQ
Agra iient of closed 44SC A/I F
I DO HEREBY C FY THAT THIS W L WAS CONSTRUCTED IN ACCORDANCE WITH
15A NCAC 2C L CON RU I STANDARDS, A THAT A COPY OF THIS
RECORp EN P IDE T THE WELL OWN
V-a8-0
SIGNA UR F CERTI IED LL CONTRACTOR DATE
L - hu
PRINTED N ME OF PERSON CO STRUCTING THE WELL
Submit the original to the Division of Water Quality within 30 days. Attn: Information Mgt., Form GW-1b
1617 Mail Service Center — Raleigh, NC 27699-1617 Phone No. (919) 733-7015 ext 568. Rev. 3/07
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
NON-RESIDENTIAL
1 � ONRESIDENTIAL WELL CONSTRUCTION RECORD
..
North Carolina Department of Environment and Natural Resources- Division of Water Quality
WELL CONTRACTOR CERTIFICATION # 2663
1. WELL CONTRACTOR:
Derry Huneycutt
Well Contractor (Individual) Name
Derry's Well Drilling Inc.
Well Contractor Company Name
STREET ADDRESS 44283-A NC 24/27/73
Albemarle NC 28002
City or Town State Zip Code
7( 04 )- 982-9070
Area code- Phone number
2. WELL INFORMATION:
SITE WELL ID #(if applicable) MW-19
WELL CONSTRUCTION PERMIT#(if applicable)
OTHER ASSOCIATED PERMIT #(if applicable)
3. WELL USE (Check Applicable Box) Monitoring11 Municipal/Public❑
Industrial/Commercial❑ Agricultural[] Recovery❑ Injection❑
Irrigationp Other[] (list use)
DATE DRILLED 6/1/07 -
TIME COMPLETED 11:50 AM® PM❑
4. WELL LOCATION:
CITY: Ararat COUNTY NC
419 Landfill Rd. a 7 00 %
(Street Name, Numbers, Community, Subdivision, Lot No., Parcel, Zip Code)
TOPOGRAPHIC / LAND SETTING:
❑ Slope It Valley ❑ Flat ❑ Ridge ❑ Other
(check appropriate box)
36.433015639 May e in degrees,
LATITUDE _ _ minutes, seconds or
LONGITUDE 80.572032 in a decimal format
Latitude/longitude source: 0 GPS ❑ Topographic map
(location of well must be shown on a USGS topo map and
attached to this form if not using GPS)
5. FACILITY- is the name of the business where the wall is located.
FACILITY ID #(if applicable)
NAME OF FACILITY Slurry Co. Closed MSWLF
STREET ADDRESS 419 Landfill Rd.
Ararat NC 27007
City or Town State Zip Code
CONTACT PERSON Mr. Jerry Snow
MAILING ADDRESS PO Box 1542
Mount Airy NC 27030
City or Town State Zip Code
( 336 )- 401-8376
Area code - Phone number
6. WELL DETAILS:
a. TOTAL DEPTH: 17.10
b. DOES WELL REPLACE EXISTING WELL? YES❑ NON
c. WATER LEVEL Below Top of Casing: 9.57 FT.
(Use "+" if Above Top of Casing)
d. TOP OF CASING IS 3.00 FT. Above Land Surface'
"Top of casing terminated at/or below land surface may require
a variance in accordance with 15A NCAC 2C .0118.
e. YIELD (gpm): na METHOD OF TEST na
f. DISINFECTION: Type na Amount na
g. WATER ZONES (depth):
From 10 To 17.10 From To
From To From To
From To From To
7. CASING: Thickness/
Depth plameter Weight Material
From 0 To 7.10 Ft. 2 scn4u F'Vl;
From To Ft.
From To Ft.
8. GROUT: Depth Material Method
From 0 To 4 Ft. Neat Cement Tremie
From_4_ To_6 Ft. 3/8" Bent. Chips Pour
From To Ft.
9. SCREEN: Depth Diameter Slot Size Material
From 7.10 To 17.10 Ft. 2 in. 0.01 in, PVC
From To Ft. in. in.
From To Ft. in. in.
10. SAND/GRAVEL PACK:
Depth Size Material
From 6 To 17.10 Ft. #2 Filter Sand
From To Ft. —
From —To— Ft.
11.DRILLING LOG
From To Formation Description
0 6S S
6S 4.9 a
4.9 17-16
12. REMARKS:
rlou�Tadiont of closed N4S%A1I_F
I DO HEREBY C IFY THAT THIS LL WAS CONSTRUCTED IN ACCORDANCE WITH.
15A NCAC 2C LL CO TR TI N STANDARDS, AND THAT A COPY OF THIS
RECORD H EN P VID T THE WELL O Q /�
O'V C
SIGN U OF CERTIFIEC&VELL CONTRACTOR DATE
PRINTED NA E OF PERSON CON T UCTING THE WELL
Submit the original to the Division of Water Quality within 30 days. Attn: Information Mgt., Form GW-1b
1617 Mail Service Center— Raleigh, NC 27699-1617 Phone No. (919) 733-7015 ext 568. Rev. 3/07
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
NONRESIDENTIAL WELL CONSTRUCTION RECORD
t
�lI y
North Carolina Department of Environment and Natural Resources- Division of Water Quality
WELL CONTRACTOR CERTIFICATION # 2663
1. WELL CONTRACTOR:
Derry Huneycutt
Well Contractor (Individual) Name
Derry's Well Drilling Inc.
Well Contractor Company Name
STREETADDRESS 44283-A NC 24/27/73
Albemarle NC 28002
City or Town State Zip Code
7( 04 )- 982-9070
Area code- Phone number
2. WELL INFORMATION:
SITE WELL ID #(if applicable) MW-20
WELL CONSTRUCTION PERMIT#(if applicable)
OTHER ASSOCIATED PERMIT #(if applicable)
3. WELL USE (Check Applicable Box) Monitoring® Municipal/Public❑
Industrial/Commercial❑ Agricultural❑ Recovery❑ Injection[]
Irrigation❑ Other❑ (list use)
DATE DRILLED 6/1/07
TIME COMPLETED 10:30 AMO PM❑
4. WELL LOCATION:
CITY: Ararat COUNTY NC
419 Landfill Rd. a 7 0 0 7
(Street Name, Numbers, Community, Subdivision, Lot No., Parcel, Zip Code)
TOPOGRAPHIC / LAND SETTING:
❑ Slope 0 Valley ❑ Flat ❑ Ridge ❑ Other
(check appropriate box)
May be in degrees,
LATITUDE 36.4326887 minutes, seconds or
LONGITUDE 80.56910777 in a decimalfornat
Latitude/longitude source: 0 GPS ❑ Topographic map
(location of well must be shown on a USGS topo map and
attached to this form if not using GPS)
5. FACILITY- is the name of the business where the well is located.
FACILITY ID #(if applicable)
NAME OF FACILITY Surry Co. Closed MSWLF
STREET ADDRESS 419 Landfill Rd.
Ararat NC 27007
City or Town State Zip Code
CONTACT PERSON Mr. Jerry Snow
MAILING ADDRESS PO BOX 1542
Mount Airy NC 27030
City or Town State Zip Code
33(_ 6 )- 401-8376
Area code - Phone number
6. WELL DETAILS:
a. TOTAL DEPTH: 25.64
b. DOES WELL REPLACE EXISTING WELL? YES❑ NOO
c. WATER LEVEL Below Top of Casing: 19.53 FT.
(Use "+" if Above Top of Casing)
d. TOP OF CASING IS 3.00 FT. Above Land Surface*
*Top of casing terminated at/or below land Surface may require
- a variance in accordance with 15A NCAC2C .0118.
e. YIELD (gpm): na METHOD OF TEST na
f. DISINFECTION: Type na Amount na
g. WATER ZONES (depth):
From 17 To 17.5 From To
From To From To
From To From To
7. CASING: Thickness/
Depth plameter Weight Material
From To 10.64Ft,2
From To Ft.
From To Ft.
8. GROUT: Depth Material Method
From 0 To 7 Ft. Neat Cement Tremie
From 7 To 9.5 Ft. 3/8" Bent. Chips Pour
From To Ft.
9. SCREEN: Depth Diameter Slot Size Material
From 10.64 To 25.64 Ft. 2 in. 0.01 in. PVC
From To Ft. in. in.
From To Ft. in. in.
10. SAND/GRAVEL PACK:
Depth Size Material
From 9.5 To a5.bq Ft. #2 filter Sand
From To Ft. -
From -To- Ft.-
1 I.DRILLING LOG
From To Formation Description
0 S. 8 raw✓i
7 ]S.(, _124 011=3S co'
12. REMARKS:
downgradient of clesgd MSWLF
I DO HEREBY CE Y THAT THIS W L WAS CONSTRUCTED IN ACCORDANCE WITH
I5A NCAC 2C, CON RU TI STANDARDS, AND THAT A COPY OF THIS
RECORD A N P IDE T T HE WELL OWNE
SIGN UR F C R IE WELL CONTRACTOR DATE
Oefro L 1 I u neu{ fE
PRINTED qPE OF PERSON CQJSTRUCTING THE WELL
Submit the original to the Division of Water Quality within 30 days. Attn: Information Mgt., Form GW-1b
1617 Mail Service Center — Raleigh, NC 27699-1617 Phone No, (919) 733-7015 ext 568. Rev. 3/07
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
`y. NONRESIDENTIAL WELL CONSTRUCTION RECORD
North Carolina Department of Environment and Natural Resources- Division of Water Quality
d,
� r
WELL CONTRACTOR CERTIFICATION # 2663
1. WELL CONTRACTOR:
Derry Huneycutt
Well Contractor (Individual) Name
Derry's Well Drilling Inc.
Well Contractor Company Name
STREET ADDRESS 44283-A NC 24/27/73
Albemarle NC. 28002
City or Town State Zip Code
7( 04 )- 982-9070
Area code- Phone number
2. WELL INFORMATION:
SITE WELL ID *(if applicable) MW-21
WELL CONSTRUCTION PERMIT#(if applicable)
OTHER ASSOCIATED PERMIT #(if applicable)
3. WELL USE (Check Applicable Box) MonitoringEj Municipal/Public❑
Industrial/Commercial❑ Agricultural❑ Recovery❑ Injection❑
Irrigationp Other❑ (list use)
DATE DRILLED 6/1/07
TIME COMPLETED 3:30 AM❑ PMO
4. WELL LOCATION:
CITY: Ararat COUNTY NC
419 Landfill Rd. 27007
(Street Name, Numbers, Community, Subdivision, Lot No., Parcel, Zip Code)
TOPOGRAPHIC / LAND SETTING:
❑ Slope II Valley ❑ Flat ❑ Ridge 0 Other
(check appropriate box)
36.434277833 May e in degrees,
LATITUDE minutes, seconds or
LONGITUDE 80.568596 in a decimal format
Latitude/longitude source: 0 GPS 0 Topographic map
(location of well must be shown on a USGS topo map and
attached to this form if not using GPS)
5. FACILITY- is the name of the business where the well is located.
FACILITY ID #(if applicable)
NAME OF FACILITY Surry Co. Closed MSWLF
STREET ADDRESS 419 Landfill Rd.
Ararat NC 27007
City or Town State Zip Code
CONTACT PERSON Mr. Jerry Snow
MAILING ADDRESS PO BOX 1542
Mount Airy NC 27030
City or Town State Zip Code
336 )-401-8376
Area code - Phone number
6. WELL DETAILS:
a. TOTAL DEPTH: 15.41
b. DOES WELL REPLACE EXISTING WELL? YES❑ NOD
c. WATER LEVEL Below Top of Casing: 6.10 FT.
(Use "+" if Above Top of Casing)
d. TOP OF CASING IS 3.00 FT. Above Land Surface'
'Top of casing terminated at/or below land surface may require
a variance in accordance with 15A NCAC 2C .0118.
e. YIELD (gpm): na METHOD OF TEST na
f. DISINFECTION: Type na Amount na
g. WATER ZONES (depth):
From 6 To 6.50 . From To
From To From To
From To From To
7. CASING: Thickness/
Depth Diameter Weight Material
From 0 To 5.41 Ft. 4 5un1+U 21VU
From To Ft.
From To Ft.
8. GROUT: Depth Material Method
From 0 To 3 Ft. Neat Cement Tremie
From 3 To 5 Ft. 3/8" Bent. Chi Pour
From To Ft.
9. SCREEN: Depth Diameter Slot Size Material
From 5.41 To 15.41 Ft. 2 in. 0.01 in. PVC
From To Ft. in. in.
From To Ft in. in.
10. SAND/GRAVEL PACK:
Depth Size Material
From 5 To 15.11 Ft. #2 `ilte, S^>a„v---
From 15.41 To IID Ft. � S
From To Ft.
11.13RILLING LOG
From To Formation Description
a
S 6.
16 Sa t
16 It, a PwjRt,,
12. REMARKS:
WA -21 Installed as type II MW for menitering
doWngradient-a# clesed MSWLF.
11
1 DO HEREBY C FY THA THI LL WAS CONSTRUCTED IN ACCORDANCE WITH
15A NCAC 2C LL CO RU STANDARDS, AND THAT A COPY OF THIS
RECOR H EN P to THE WELL NE
-ov-
SIGOTL&E OF CERT WELL CONTRACTOR DATE
PRINTED NAIU OF PERSON COKVRUCTING THE WELL
Submit the original to the Division of Water Quality within 30 days. Attn: Information Mgt., Form GW-1b
1617 Mail Service Center— Raleigh, NC 27699-1617 Phone No. (919) 733-7015 ext 568. Rev. 3/07
Docusign Envelope ID
1. WELL CONTRACTOR:
Derry Huneycutt
Well Contractor (Individual) Name
Derry's Well Drilling Inc.
Well Contractor Company Name
STREET ADDRESS 44283-A NC 24/27/73
Albemarle NC 28002
City or Town State Zip Code
7( 04 )- 982-9070
Area code- Phone number
2. WELL INFORMATION:
SITE WELL ID #(if applicable) MW-22
WELL CONSTRUCTION PERMIT#(if applicable)
OTHER ASSOCIATED PERMIT #(if applicable)
3. WELL USE (Check Applicable Box) Monitoring Municipal/Public❑
Industrial/Commercial❑ Agricultural❑ Recovery(] Injection❑
Irrigationp Other❑ (list use)
DATE DRILLED 6/1/07
TIME COMPLETED 2:00 AM❑ PM❑
4. WELL LOCATION:
CITY: Ararat COUNTY NC
419 Landfill Rd. 27007
(Street Name, Numbers, Community, Subdivision, Lot No., Parcel, Zip Code)
TOPOGRAPHIC I LAND SETTING:
❑ Slope ■ Valley ❑ Flat ❑ Ridge ❑ Other
(check appropriate box)
36.435334111 May e in degrees,
LATITUDE _ _ minutes, seconds or
LONGITUDE 80.567269 in a decimal format
Latitude/longitude source: ® GPS ❑ Topographic map
(location of well must be shown on a USGS topo map and
attached to this form if not using GPS)
5. FACILITY- is the name of the business where the well is located.
FACILITY ID #(if applicable)
NAME OF FACILITY Surry Co. Closed MSWLF
STREET ADDRESS 419 Landfill Rd.
Ararat NC 27007
City or Town State Zip Code
CONTACT PERSON Mr. Jerry Snow
MAILING ADDRESS PO Box 1542
Mount Airy NC 27030
City or Town State Zip Code
33( 6 _)- 401-8376
Area code - Phone number
6. WELL DETAILS:
a. TOTAL DEPTH: 16.04
b. DOES WELL REPLACE EXISTING WELL? YES❑ NOD
c. WATER LEVEL Below Top of Casing: 4.60 FT
(Use "+" if Above Top of Casing)
889599EA-C817-4865-93DD-1 B8535D719AE
NONRESIDENTIAL WELL CONSTRUCTION RECORD
North Carolina Department of Environment and Natural Resources- Division of Water Quality
WELL CONTRACTOR CERTIFICATION # 2663
d. TOP OF CASING IS 3.00 FT, Above Land Surface'
'Top of casing terminated at/or below land surface may require
a variance in accordance with 15A NCAC 2C .0118.
e. YIELD (gpm): na METHOD OF TEST na
f. DISINFECTION: Type na Amount na
g. WATER ZONES (depth):
From 1.60 To >16.04 From To
From To From To
From To From To
7. CASING: Thickness/
Depth Diameter Weight Material
From 0 To 6.04 Ft. 4 sL n�+v t'Vl
From To Ft.
From To Ft.
8. GROUT: Depth Material Method
From 0 To 3. Ft. Neat Cement Tremie
From 3 To 5 Ft. 3/8" Bent. Chi Pour
From To Ft.
9. SCREEN: Depth Diameter Slot Size Material
From 6.04 To 16.04 Ft. 2 in. 0.01 in. PVC
From To Ft. in. in.
From To Ft. in. in.
10. SAND/GRAVEL PACK:
Depth Size Material
From 5 Toj(04 Ft. #2 Rlter SaAd
From To Ft.
From To Ft.
11.DRILLING LOG
From To Formati n Descri tion
3.5 I16,44 n.
12. REMARKS:
downgradient of dared MS)IAILF
I DO H/C12
FY THA THIS - LL WAS CONSTRUCTED IN ACCORDANCE WITH
15A NCCO R T N STANDARDSAND THAT A COPY OF THIS
RECORP VID D THE ER.
SIGNATU OF CERTIFI WELL CONTRACTOR DATE
An
cu
PRINTED E OF PERSON CON TRUCTING THE WELL
Submit the original to the Division of Water Quality within 30 days. Attn: Information Mgt., Form GW-1b
1617 Mail Service Center — Raleigh, NC 276.99-1617 Phone No. (919) 733-7015 ext 568. Rev. 3/07
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
S�:9rki
y n NONRESIDENTIAL WELL CONSTRUCTION RECORD
North Carolina Department of Environment and Natural Resources- Division of Water Quality
WELL CONTRACTOR CERTIFICATION # 2663
1. WELL CONTRACTOR:
Derry Huneycutt
Well Contractor (Individual) Name
Derry's Well Drilling Inc:
Well Contractor Company Name
STREET ADDRESS 44283-A NC 24/27/73
Albemarle NC 28002
City or Town State Zip Code
7( 04 )- 982-9070
Area code- Phone number
2. WELL INFORMATION:
SITE WELL ID #(if applicable) MW-23
WELL CONSTRUCTION PERMIT#(if applicable)
OTHER ASSOCIATED PERMIT #(if applicable)
3. WELL USE (Check Applicable Box) Monitoring® Municipal/Public❑
Industrial/Commercial❑ Agricultural❑ Recovery❑ Injection❑
Irrigation❑ Other❑ (list use)
DATE DRILLED 6/1/07
TIME COMPLETED 4:20 AM❑ PMO
4. WELL LOCATION:
CITY: Ararat COUNTY NC
419 Landfill Rd. 27007
(Street Name, Numbers, Community, Subdivision, Lot No., Parcel, Zip Code)
TOPOGRAPHIC / LAND SETTING:
❑ Slope ® Valley ❑ Flat ❑ Ridge ❑ Other
(check appropriate box) May be in degrees,
LATITUDE 36.439015556 minutes, seconds or
LONGITUDE 80.571788 in a decimal format
Latitude/longitude source: 0 GPS 0 Topographic map
(location of well must be shown on a USGS topo map and
attached to this form if not using GPS)
5. FACILITY- is the name of the business where the well is located.
FACILITY ID #(if applicable)
NAME OF FACILITY Surry CO. Closed MSWLF
STREET ADDRESS 419 Landfill Rd.
Ararat NC 27007
City or Town State Zip Code
CONTACT PERSON -Mr. Jerry Snow
MAILING ADDRESS PO BOX 1542
Mount Airy NC 27030
City or Town State Zip Code
(336 )- 401-8376
Area code - Phone number
6. WELL DETAILS:
a. TOTAL DEPTH: 17.10
b. DOES WELL REPLACE EXISTING WELL? YES❑ NOO
c. WATER LEVEL Below Top of Casing: 8.16 FT.
(Use "+" if Above Top of Casing)
d. TOP OF CASING IS 3.00
FT. Above Land Surface*
*Top of casing terminated at/or below land surface may require
a variance in accordance with
15A NCAC 2C .0118.
e. YIELD (gpm): na
METHOD OF TEST na
f. DISINFECTION: Type na
Amount na
g. WATER ZONES (depth):
From 5.16 To 17.10
From To
From To
From To
From To
From To
7. CASING:
Thickness/
0
Depth
7.10
pIameter Weight
Material
From
To
Ft. 2 s(:nl+u
t'VU
From
To
Ft.
From
To
Ft.
8. GROUT:
Depth
Material
Method
From 0
To 4
Ft. Neat Cement
Tremie
From-4
To 6.05
Ft, 3/8" Bent. Chits
Pour
From
To
Ft.
9. SCREEN:
Depth
Diameter Slot Size
Material
From 7.10
To 17.10
Ft. 2 in. 0.01 in.
PVC
From
To
Ft. in. in.
From
To
Ft. in. in.
10. SAND/GRAVEL PACK:
Depth
_
Size Material
From 6, 05
To) 7.10 Ft. #2 Filter Sand
From
To
Ft.
From
To
Ft.
11.DRILLING LOG
From To Formation Description
0 3S
3,S i3.lb ,
Xjs.
12. REMARKS:
dowAgradient of closed MSWI I=
I DO HEREBY IFY THA THIS W L WAS CONST CTED IN ACCORDANCE WITH
15A NCAC 2 LL CO RU T STANDARDS D THAT A COPY OF THIS
RECOR EEN P ID �'T TH W
SIG`9ATUfW OF C RTIF WELL CONTRACTOR DATE
OF PERSON CONSTRUCTING
Submit the original to the Division of Water Quality within 30 days. Attn: Information Mgt., Form GW-1b
1617 Mail Service Center — Raleigh, NC 27699-1617 Phone No. (919) 733-7015 ext 568. Rev. 3107
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Appendix
Laboratory Analytical Report
May 2024 Semi -Annual Monitoring Report
Surry County Closed CAD/MSW Landfill
NC Solid Waste Permit No. 86-02
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
This page intentionally left blank
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
Waypoint
ANALYTICAL
5/31 /2024
Smith & Gardner, Inc.
Seth C. Rickerts
14 N. Boylan Avenue
Raleigh, NC, 27603
449 5pringbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Ref: Analytical Testing
Lab Report Number: 24-124-0102
Client Project Description: Surry County C&D/MSW Spring
Dear Seth C. Rickerts:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 5/3/2024 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2021) unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
a'-1
Angela D Overcash
Senior Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Charlotte, NC 28217
Waypoint, 449 Springbrook Rd, Ch
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State
Program
Lab ID
Expiration Date
North Carolina
State Program
37735
07/31/2024
North Carolina
State Program
402
12/31/2024
South Carolina
State Program
99012
07/31/2024
South Carolina
State Program
99012
12/31/2024
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2025
Arkansas
State Program
88-0650
02/07/2025
California
State Program
2904
06/30/2024
Florida
State Program - NELAP
E871157
06/30/2024
Georgia
State Program
C044
11/14/2025
Georgia
State Program
04015
06/30/2024
Illinois
State Program - NELAP
200078
10/31/2024
Kentucky
State Program
80215
06/30/2024
Kentucky
State Program
KY90047
12/31/2024
Louisiana
State Program - NELAP
LA037
12/31/2024
Louisiana
State Program - NELAP
04015
06/30/2024
Mississippi
State Program
MS
11/14/2025
North Carolina
State Program
47701
07/31/2024
North Carolina
State Program
415
12/31/2024
Pennsylvania
State Program - NELAP
68-03195
05/31/2025
South Carolina
State Program
84002
06/30/2024
Tennessee
State Program
02027
11/14/2025
Texas
State Program - NELAP
T104704180
09/30/2024
Virginia
State Program
00106
06/30/2024
Virginia
State Program - NELAP
460181
09/14/2024
Page 1 of 1 00016/24-124-0102
Page 2 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
(2)
Charlotte, NC 28217
Waypoint. 449 Springbrook Rd, Ch
Main 704.529.6364
ANALYTICAL www.waypointana lyti ca Isom
Sample Summary Table
Report Number:
Client Project Description:
24-124-0102
Surry County C&D/MSW Spring
Lab No
Client Sample ID
Matrix
Date Collected
Date Received
Method
Lab ID
92542
MW-21
Aqueous
05/01/2024 15:45
05/03/2024 12:30
SUBCONTRACT
92542
MW-21
Aqueous
05/01/2024 15:45
05/03/2024 12:30
92542
MW-21
Aqueous
05/01/2024 15:45
05/03/2024 12:30
AM23G
Pace -LA
92542
MW-21
Aqueous
05/01/2024 15:45
05/03/2024 12:30
RSK-175
Pace -LA
92542
MW-21
Aqueous
05/01/2024 15:45
05/03/2024 12:30
8151A
WP MTN
92542
MW-21
Aqueous
05/01/2024 15:45
05/03/2024 12:30
8270D
WP MTN
92542
MW-21
Aqueous
05/01/2024 15:45
05/03/2024 12:30
531OC-2011
WP MTN
92542
MW-21
Aqueous
05/01/2024 15:45
05/03/2024 12:30
8270D
WP MTN
92542
MW-21
Aqueous
05/01/2024 15:45
05/03/2024 12:30
6020E
WP MTN
92542
MW-21
Aqueous
05/01/2024 15:45
05/03/2024 12:30
7470A
WP MTN
92542
MW-21
Aqueous
05/01/2024 15:45
05/03/2024 12:30
8270C
WP MTN
92543
SW-1
Aqueous
05/01/2024 12:30
05/03/2024 12:30
92543
SW-1
Aqueous
05/01/2024 12:30
05/03/2024 12:30
6020E
WP MTN
92544
MW-9
Aqueous
05/02/2024 11:00
05/03/2024 12:30
SUBCONTRACT
92544
MW-9
Aqueous
05/02/2024 11:00
05/03/2024 12:30
92544
MW-9
Aqueous
05/02/2024 11:00
05/03/2024 12:30
AM23G
Pace -LA
92544
MW-9
Aqueous
05/02/2024 11:00
05/03/2024 12:30
RSK-175
Pace -LA
92544
MW-9
Aqueous
05/02/2024 11:00
05/03/2024 12:30
8270C
WP MTN
92544
MW-9
Aqueous
05/02/2024 11:00
05/03/2024 12:30
8270D
WP MTN
92544
MW-9
Aqueous
05/02/2024 11:00
05/03/2024 12:30
8151A
WP MTN
92544
MW-9
Aqueous
05/02/2024 11:00
05/03/2024 12:30
7470A
WP MTN
92544
MW-9
Aqueous
05/02/2024 11:00
05/03/2024 12:30
8270D
WP MTN
92544
MW-9
Aqueous
05/02/2024 11:00
05/03/2024 12:30
6020E
WP MTN
92544
MW-9
Aqueous
05/02/2024 11:00
05/03/2024 12:30
531OC-2011
WP MTN
92545
SW-2
Aqueous
05/02/2024 10:15
05/03/2024 12:30
92545
SW-2
Aqueous
05/02/2024 10:15
05/03/2024 12:30
6020E
WP MTN
: Air Technology Laboratories, City of Industry, CA
Pace -LA: Pace Analytical Services, Inc. - LA, Baton Rouge, LA
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 3 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
(2)
Charlotte, NC 28217
Waypoint. 449 Springbrook Rd, Ch
Main 704.529.6364
ANALYTICAL www.waypointana lyti ca Isom
Sample Summary Table
Report Number:
Client Project Description:
24-124-0102
Surry County C&D/MSW Spring
Lab No
Client Sample ID
Matrix
Date Collected
Date Received
Method
Lab ID
92546
MW-1
Aqueous
05/02/2024 12:30
05/03/2024 12:30
SUBCONTRACT
92546
MW-1
Aqueous
05/02/2024 12:30
05/03/2024 12:30
92546
MW-1
Aqueous
05/02/2024 12:30
05/03/2024 12:30
AM23G
Pace -LA
92546
MW-1
Aqueous
05/02/2024 12:30
05/03/2024 12:30
RSK-175
Pace -LA
92546
MW-1
Aqueous
05/02/2024 12:30
05/03/2024 12:30
531OC-2011
WP MTN
92546
MW-1
Aqueous
05/02/2024 12:30
05/03/2024 12:30
8270C
WP MTN
92546
MW-1
Aqueous
05/02/2024 12:30
05/03/2024 12:30
8270D
WP MTN
92546
MW-1
Aqueous
05/02/2024 12:30
05/03/2024 12:30
8270D
WP MTN
92546
MW-1
Aqueous
05/02/2024 12:30
05/03/2024 12:30
8151A
WP MTN
92546
MW-1
Aqueous
05/02/2024 12:30
05/03/2024 12:30
7470A
WP MTN
92546
MW-1
Aqueous
05/02/2024 12:30
05/03/2024 12:30
6020E
WP MTN
92547
MW-11
Aqueous
05/02/2024 13:30
05/03/2024 12:30
SUBCONTRACT
92547
MW-11
Aqueous
05/02/2024 13:30
05/03/2024 12:30
92547
MW-11
Aqueous
05/02/2024 13:30
05/03/2024 12:30
RSK-175
Pace -LA
92547
MW-11
Aqueous
05/02/2024 13:30
05/03/2024 12:30
AM23G
Pace -LA
92547
MW-11
Aqueous
05/02/2024 13:30
05/03/2024 12:30
8270C
WP MTN
92547
MW-11
Aqueous
05/02/2024 13:30
05/03/2024 12:30
8270D
WP MTN
92547
MW-11
Aqueous
05/02/2024 13:30
05/03/2024 12:30
8270D
WP MTN
92547
MW-11
Aqueous
05/02/2024 13:30
05/03/2024 12:30
8151A
WP MTN
92547
MW-11
Aqueous
05/02/2024 13:30
05/03/2024 12:30
7470A
WP MTN
92547
MW-11
Aqueous
05/02/2024 13:30
05/03/2024 12:30
6020E
WP MTN
92547
MW-11
Aqueous
05/02/2024 13:30
05/03/2024 12:30
531OC-2011
WP MTN
92548
MW-16
Aqueous
05/02/2024 14:45
05/03/2024 12:30
92548
MW-16
Aqueous
05/02/2024 14:45
05/03/2024 12:30
RSK-175
Pace -LA
92548
MW-16
Aqueous
05/02/2024 14:45
05/03/2024 12:30
AM23G
Pace -LA
92548
MW-16
Aqueous
05/02/2024 14:45
05/03/2024 12:30
8270C
WP MTN
: Air Technology Laboratories, City of Industry, CA
Pace -LA: Pace Analytical Services, Inc. - LA, Baton Rouge, LA
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 4 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
(2)
Charlotte, NC 28217
Waypoint. 449 Springbrook Rd, Ch
Main 704.529.6364
ANALYTICAL www.waypointana lyti ca Isom
Sample Summary Table
Report Number:
Client Project Description:
24-124-0102
Surry County C&D/MSW Spring
Lab No
Client Sample ID
Matrix
Date Collected
Date Received
Method
Lab ID
92548
MW-16
Aqueous
05/02/2024 14:45
05/03/2024 12:30
8270D
WP MTN
92548
MW-16
Aqueous
05/02/2024 14:45
05/03/2024 12:30
8270D
WP MTN
92548
MW-16
Aqueous
05/02/2024 14:45
05/03/2024 12:30
8151A
WP MTN
92548
MW-16
Aqueous
05/02/2024 14:45
05/03/2024 12:30
7470A
WP MTN
92548
MW-16
Aqueous
05/02/2024 14:45
05/03/2024 12:30
6020E
WP MTN
92548
MW-16
Aqueous
05/02/2024 14:45
05/03/2024 12:30
531OC-2011
WP MTN
92549
MW-15
Aqueous
05/02/2024 14:15
05/03/2024 12:30
92549
MW-15
Aqueous
05/02/2024 14:15
05/03/2024 12:30
RSK-175
Pace -LA
92549
MW-15
Aqueous
05/02/2024 14:15
05/03/2024 12:30
AM23G
Pace -LA
92549
MW-15
Aqueous
05/02/2024 14:15
05/03/2024 12:30
6020E
WP MTN
92549
MW-15
Aqueous
05/02/2024 14:15
05/03/2024 12:30
531OC-2011
WP MTN
92549
MW-15
Aqueous
05/02/2024 14:15
05/03/2024 12:30
8270C
WP MTN
92549
MW-15
Aqueous
05/02/2024 14:15
05/03/2024 12:30
8270D
WP MTN
92549
MW-15
Aqueous
05/02/2024 14:15
05/03/2024 12:30
8270D
WP MTN
92549
MW-15
Aqueous
05/02/2024 14:15
05/03/2024 12:30
8151A
WP MTN
92549
MW-15
Aqueous
05/02/2024 14:15
05/03/2024 12:30
7470A
WP MTN
92550
MW-14
Aqueous
05/02/2024 14:30
05/03/2024 12:30
92550
MW-14
Aqueous
05/02/2024 14:30
05/03/2024 12:30
RSK-175
Pace -LA
92550
MW-14
Aqueous
05/02/2024 14:30
05/03/2024 12:30
AM23G
Pace -LA
92550
MW-14
Aqueous
05/02/2024 14:30
05/03/2024 12:30
8270C
WP MTN
92550
MW-14
Aqueous
05/02/2024 14:30
05/03/2024 12:30
8270D
WP MTN
92550
MW-14
Aqueous
05/02/2024 14:30
05/03/2024 12:30
8270D
WP MTN
92550
MW-14
Aqueous
05/02/2024 14:30
05/03/2024 12:30
8151A
WP MTN
92550
MW-14
Aqueous
05/02/2024 14:30
05/03/2024 12:30
7470A
WP MTN
92550
MW-14
Aqueous
05/02/2024 14:30
05/03/2024 12:30
6020E
WP MTN
92550
MW-14
Aqueous
05/02/2024 14:30
05/03/2024 12:30
531OC-2011
WP MTN
: Air Technology Laboratories, City of Industry, CA
Pace -LA: Pace Analytical Services, Inc. - LA, Baton Rouge, LA
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 5 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
(2)
Charlotte, NC 28217
Waypoint. 449 Springbrook Rd, Ch
Main 704.529.6364
ANALYTICAL www.waypointana lyti ca Isom
Sample Summary Table
Report Number: 24-124-0102
Client Project Description: Surry County C&D/MSW Spring
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
92551
SW-3
Aqueous
05/02/2024 15:50
05/03/2024
12:30
92551
SW-3
Aqueous
05/02/2024 15:50
05/03/2024
12:30 6020B WP MTN
92552
Trip Blank
Aqueous
05/01/2024
05/03/2024
12:30
: Air Technology Laboratories, City of Industry, CA
Pace -LA: Pace Analytical Services, Inc. - LA, Baton Rouge, LA
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 6 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypoint'(2)
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lytica Isom
Summary of Detected
Project: Surry County C&D/MSW Spring
Report Number: 24-124-0102
Client Sample ID Lab Sample ID
Method Parameters
Result Units Report Limit Analyzed
MW-21
V 92542
2320B-2011
Alkalinity (as CaCO3)
29000
pq/L
800
05/08/2024
15:40
5310C-2011
TOC
1400
Ng/L
720
05/09/2024
01:59
6020B
Arsenic
0.514
pq/L
0.297
05/10/2024
21:45
6020B
Barium
56.6
pg/L
0.453
05/10/2024
21:45
6020B
Beryllium
0.190
pq/L
0.102
05/10/2024
21:45
6020B
Chromium
2.62
pg/L
0.346
05/10/2024
21:45
6020B
Cobalt
6.48
pq/L
0.060
05/10/2024
21:45
6020B
Copper
3.52
pg/L
0.489
05/10/2024
21:45
6020B
Lead
0.687
pq/L
0.264
05/10/2024
21:45
6020B
Nickel
3.01
pg/L
0.182
05/10/2024
21:45
6020B
Thallium
0.0758
pq/L
0.0610
05/10/2024
21:45
6020B
Vanadium
4.43
pg/L
0.767
05/10/2024
21:45
6020B
Zinc
10.1
pq/L
4.67
05/10/2024
21:45
8260D
Acetone
2.18
pg/L
1.80
05/10/2024
06:49
8260D
1,1-Dichloroethane
0.701
pq/L
0.240
05/10/2024
06:49
8260D
cis-1,2-Dichloroethene
7.88
Ng/L
0.200
05/10/2024
06:49
8260D
Trichloroethene
0.269
pq/L
0.180
05/10/2024
06:49
8260D SIM
1,4-Dioxane
6.10
pg/L
0.139
05/06/2024
19:49
9056A
Chloride
28700
pq/L
500
05/03/202414:04
9056A
Nitrate (NO3-N)
279
Ng/L
50.0
05/03/2024
14:04
9056A
Sulfate
4460
pq/L
600
05/03/202414:04
SW-1
V 92543
6020B
Arsenic
0.404
Ng/L
0.297
05/10/2024
21:56
6020B
Barium
20.5
pq/L
0.453
05/10/2024
21:56
6020B
Chromium
0.478
Ng/L
0.346
05/10/2024
21:56
6020B
Cobalt
0.226
pq/L
0.060
05/10/2024
21:56
6020B
Copper
0.676
Ng/L
0.489
05/10/2024
21:56
6020B
Vanadium
1.86
pq/L
0.767
05/10/2024
21:56
8260D
Acetone
2.88
Ng/L
1.80
05/10/2024
07:14
MW-9
V 92544
2320B-2011
Alkalinity (as CaCO3)
69000
pq/L
800
05/08/2024
15:40
5210B-2015
Biochemical Oxygen Demand (5-day)
6700
pg/L
2000
05/03/2024
10:39
5220D-2011
COD (Chemical Oxygen Demand)
21000
pq/L
15000
05/09/2024
11:25
5310C-2011
TOC
4110
Ng/L
720
05/09/2024
02:38
6020B
Arsenic
0.661
pq/L
0.297
05/10/2024
21:59
6020B
Barium
64.8
Ng/L
0.453
05/10/2024
21:59
Qualifiers
t
0
J
J
JB
J
J
0
J
J
J
JB
J
0
J
Page 7 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypoint'(2)
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lytica Isom
Summary of Detected
Project: Surry County C&D/MSW Spring
Report Number: 24-124-0102
Client Sample ID Lab Sample ID
Method Parameters
Result Units Report Limit Analyzed
MW-9
V 92544
6020B
Beryllium
0.112
pq/L
0.102
05/10/2024
21:59
6020B
Cadmium
68.8
Ng/L
0.350
05/10/2024
21:59
6020B
Chromium
1.70
pq/L
0.346
05/10/2024
21:59
6020B
Cobalt
152
pg/L
0.060
05/10/2024
21:59
6020B
Copper
8.66
pq/L
0.489
05/10/2024
21:59
6020B
Lead
1.51
pg/L
0.264
05/10/2024
21:59
6020B
Nickel
20.7
pq/L
0.182
05/10/2024
21:59
6020B
Thallium
0.537
pg/L
0.0610
05/10/2024
21:59
6020B
Vanadium
1.76
pq/L
0.767
05/10/2024
21:59
6020B
Zinc
310
pg/L
4.67
05/10/2024
21:59
8151A
2,4,5-TP(Silvex)
0.1667
pq/L
0.01650
05/14/202422:52
8260D
Benzene
2.42
pg/L
0.180
05/10/2024
07:39
8260D
Chlorobenzene
2.57
pq/L
0.190
05/10/2024
07:39
8260D
Chloroethane
2.87
pg/L
0.430
05/10/2024
07:39
8260D
1,2-Dichlorobenzene
2.18
pq/L
0.220
05/10/2024
07:39
8260D
1,4-Dichlorobenzene
6.14
Ng/L
0.210
05/10/2024
07:39
8260D
1,1-Dichloroethane
1.83
pq/L
0.240
05/10/2024
07:39
8260D
cis- 1,2-Dichloroethene
42.4
pg/L
0.200
05/10/2024
07:39
8260D
trans-1,2-Dichloroethene
0.316
pq/L
0.180
05/10/2024
07:39
8260D
Tetrahydrofuran
9.54
Ng/L
1.50
05/10/2024
07:39
8260D
Vinyl Chloride
26.0
pq/L
0.170
05/10/2024
07:39
8260D SIM
1,4-Dioxane
4.00
Ng/L
0.139
05/06/2024
20:39
8270D
1,2-Dichlorobenzene
1.81
pq/L
0.466
05/08/2024
20:59
8270D
1,4-Dichlorobenzene
4.33
Ng/L
0.405
05/08/2024
20:59
8270D
Diethyl phthalate
1.49
pq/L
0.686
05/08/2024
20:59
9056A
Chloride
37300
Ng/L
500
05/03/202417:06
9056A
Nitrate (NO3-N)
62.0
pq/L
50.0
05/03/2024
17:06
9056A
Sulfate
1850
Ng/L
600
05/03/202417:06
RSK-175
Ethane
44.2
pq/L
2.67
05/06/202414:43
RSK-175
Ethene
3.87
Ng/L
2.28
05/06/202414:43
RSK-175
Methane
2430
pq/L
25.1
05/06/202415:22
SM-3500-Fe-B
Ferrous Iron
23.5
mg/L
1.25
05/03/2024
13:40
SW-2
V 92545
6020B
Arsenic
0.439
pq/L
0.297
05/10/2024
22:03
6020B
Barium
26.7
Ng/L
0.453
05/10/2024
22:03
6020B
Chromium
0.560
pq/L
0.346
05/10/2024
22:03
Qualifiers
L
J
JB
J
J
J
J
J
J
J
J
H
J
J
Page 8 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
W Waypoint,,
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Summary of Detected
Project: Surry County C&D/MSW Spring
Report Number: 24-124-0102
Client Sample ID Lab Sample ID
Method Parameters
Result Units Report Limit Analyzed Qualifiers
SW-2
V 92545
6020B
Cobalt
31.2
pg/L
0.060
05/10/2024 22:03
6020E
Copper
0.489
pg/L
0.489
05/10/2024 22:03
6020E
Nickel
1.11
pg/L
0.182
05/10/2024 22:03
6020E
Vanadium
1.50
pg/L
0.767
05/10/2024 22:03
6020E
Zinc
5.11
pg/L
4.67
05/10/2024 22:03
8260D
Acetone
2.90
pg/L
1.80
05/10/2024 08:04
8260D
1,4-Dichlorobenzene
0.296
pg/L
0.210
05/10/2024 08:04
8260D
cis- 1,2-Dichloroethene
2.47
pg/L
0.200
05/10/2024 08:04
8260D
Vinyl Chloride
0.776
pg/L
0.170
05/10/2024 08:04
8260D SIM
1,4-Dioxane
2.27
pg/L
0.139
05/06/2024 21:05
MW-1
V 92546
2320E-2011
Alkalinity (as CaCO3)
26000
pg/L
800
05/08/2024 15:40
5220D-2011
COD (Chemical Oxygen Demand)
16000
pg/L
15000
05/09/2024 11:25
5310C-2011
TOC
1040
pg/L
720
05/09/2024 03:16
6020E
Arsenic
0.552
pg/L
0.297
05/10/2024 22:06
6020E
Barium
57.0
pg/L
0.453
05/10/2024 22:06
6020E
Chromium
0.748
pg/L
0.346
05/10/2024 22:06
6020E
Cobalt
1.71
pg/L
0.060
05/10/2024 22:06
6020E
Copper
1.24
pg/L
0.489
05/10/2024 22:06
6020E
Nickel
1.90
pg/L
0.182
05/10/2024 22:06
6020E
Vanadium
2.64
pg/L
0.767
05/10/2024 22:06
6020E
Zinc
10.8
pg/L
4.67
05/10/2024 22:06
8260D
Acetone
2.44
pg/L
1.80
05/10/2024 08:29
8260D
Tetrahydrofuran
24.0
pg/L
1.50
05/10/2024 08:29
9056A
Chloride
3010
pg/L
500
05/03/202416:53
9056A
Nitrate (NO3-N)
1130
pg/L
50.0
05/03/2024 16:53
9056A
Sulfate
10900
pg/L
600
05/03/202416:53
MW-11
V 92547
2320E-2011
Alkalinity (as CaCO3)
34000
pg/L
800
05/08/2024 15:40
5310C-2011
TOC
2490
pg/L
720
05/09/2024 03:54
6020E
Barium
34.4
pg/L
0.453
05/14/2024 00:35
6020B
Chromium
0.851
pg/L
0.346
05/14/202419:26
6020E
Cobalt
48.4
pg/L
0.060
05/14/2024 00:35
6020B
Copper
1.15
pg/L
0.489
05/14/2024 00:35
6020E
Nickel
3.95
pg/L
0.182
05/14/202419:26
6020B
Thallium
0.110
pg/L
0.0610
05/14/2024 00:35
0
JB
J
J
J
J
0
Page 9 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypoint'(2)
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lytica Isom
Summary of Detected
Project: Surry County C&D/MSW Spring
Report Number: 24-124-0102
Client Sample ID Lab Sample ID
Method Parameters
Result Units Report Limit Analyzed
MW-11
V 92547
8151A
Picloram
0.06644
pq/L
0.04618
05/14/202423:42
8260D
Acetone
1.91
Ng/L
1.80
05/10/2024
08:54
8260D
Benzene
0.287
pq/L
0.180
05/10/2024
08:54
8260D
Chlorobenzene
1.60
pg/L
0.190
05/10/2024
08:54
8260D
1,4-Dichlorobenzene
2.00
pq/L
0.210
05/10/2024
08:54
8260D
cis-1,2-Dichloroethene
0.246
pg/L
0.200
05/10/2024
08:54
8260D
1,2-Dichloropropane
0.328
pq/L
0.190
05/10/2024
08:54
8270D
1,4-Dichlorobenzene
1.11
pg/L
0.405
05/08/2024
21:41
9056A
Chloride
5970
pq/L
500
05/03/202417:18
9056A
Nitrate (NO3-N)
128
pg/L
50.0
05/03/2024
17:18
9056A
Sulfate
28600
pq/L
600
05/03/202417:18
RSK-175
Methane
413
pg/L
2.51
05/06/202413:51
SM-3500-Fe-13
Ferrous Iron
0.22
mg/L
0.05
05/03/2024
13:40
MW-16
V 92548
2320B-2011
Alkalinity (as CaCO3)
155000
Ng/L
1000
05/08/2024
15:40
5310C-2011
TOC
3800
pq/L
720
05/09/2024
04:32
6020B
Arsenic
0.336
Ng/L
0.297
05/14/2024
00:50
6020B
Barium
106
pq/L
0.453
05/14/2024
00:50
6020B
Beryllium
0.281
Ng/L
0.102
05/14/2024
00:50
6020B
Chromium
1.67
pq/L
0.346
05/14/2024
00:50
6020B
Cobalt
270
Ng/L
0.060
05/14/2024
00:50
6020B
Copper
9.34
pq/L
0.489
05/14/2024
00:50
6020B
Lead
0.808
Ng/L
0.264
05/14/2024
00:50
6020B
Nickel
13.6
pq/L
0.182
05/14/2024
00:50
6020B
Silver
0.0804
Ng/L
0.0570
05/14/202419:31
6020B
Tin
5.55
pq/L
1.44
05/14/2024
00:50
6020B
Thallium
0.293
Ng/L
0.0610
05/14/2024
00:50
6020B
Zinc
14.3
pq/L
4.67
05/14/202419:31
7470A
Mercury (Total)
0.100
Ng/L
0.100
05/13/2024
14:53
8260D
Acetone
2.83
pq/L
1.80
05/10/2024
09:19
8260D
Benzene
0.663
Ng/L
0.180
05/10/2024
09:19
8260D
Chlorobenzene
3.36
pq/L
0.190
05/10/2024
09:19
8260D
1,2-Dichlorobenzene
0.428
pg/L
0.220
05/10/2024
09:19
8260D
1,4-Dichlorobenzene
7.28
pq/L
0.210
05/10/2024
09:19
8260D
1,1-Dichloroethane
0.366
pg/L
0.240
05/10/2024
09:19
8260D
1,2-Dichloroethane
1.18
pg/L
0.150
05/10/2024
09:19
Qualifiers
JQ
J
J
I
H
0
J
0
J
B
J
I
0
J
Page 10 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypoint'(2)
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lytica Isom
Summary of Detected
Project: Surry County C&D/MSW Spring
Report Number: 24-124-0102
Client Sample ID Lab Sample ID
Method Parameters
MW-16 V 92548
Result Units Report Limit Analyzed Qualifiers
8260D
cis-1,2-Dichloroethene
10.1
pq/L
0.200
05/10/2024
09:19
8260D
1,2-Dichloropropane
0.682
Ng/L
0.190
05/10/2024
09:19
8260D
1,2,4-Trichlorobenzene
0.380
pq/L
0.310
05/10/2024
09:19
8260D
Vinyl Chloride
2.09
pg/L
0.170
05/10/2024
09:19
8260D SIM
1,4-Dioxane
2.29
pq/L
0.139
05/07/2024
11:35
8270D
1,4-Dichlorobenzene
4.68
pg/L
0.405
05/08/2024
22:02
9056A
Chloride
41000
pq/L
500
05/03/202417:55
9056A
Nitrate (NO3-N)
75.0
pg/L
50.0
05/03/2024
17:55
9056A
Sulfate
7930
pq/L
600
05/03/202417:55
RSK-175
Methane
173
pg/L
2.51
05/06/202414:04
SM-3500-Fe-13
Ferrous Iron
49.9
mg/L
1.25
05/03/2024
13:40
MW-15
V 92549
2320B-2011
Alkalinity (as CaCO3)
45000
Ng/L
800
05/08/2024
15:40
5220D-2011
COD (Chemical Oxygen Demand)
21000
pq/L
15000
05/09/2024
11:25
5310C-2011
TOC
1040
Ng/L
720
05/09/2024
06:27
6020B
Arsenic
0.328
pq/L
0.297
05/14/2024
00:54
6020B
Barium
241
Ng/L
0.453
05/14/2024
00:54
6020B
Beryllium
1.86
pq/L
0.102
05/14/2024
00:54
6020B
Cadmium
0.509
Ng/L
0.350
05/14/202419:45
6020B
Chromium
43.9
pq/L
0.346
05/14/2024
00:54
6020B
Cobalt
8.10
Ng/L
0.060
05/14/2024
00:54
6020B
Copper
17.8
pq/L
0.489
05/14/2024
00:54
6020B
Lead
9.96
Ng/L
0.264
05/14/2024
00:54
6020B
Nickel
16.2
pq/L
0.182
05/14/2024
00:54
6020B
Selenium
0.731
Ng/L
0.703
05/14/2024
00:54
6020B
Silver
0.0657
pq/L
0.0570
05/14/202419:45
6020B
Tin
3.29
Ng/L
1.44
05/14/2024
00:54
6020B
Thallium
0.577
pq/L
0.0610
05/14/2024
00:54
6020B
Vanadium
59.5
Ng/L
0.767
05/14/2024
00:54
6020B
Zinc
108
pq/L
4.67
05/14/202419:45
8260D
Benzene
0.353
Ng/L
0.180
05/10/2024
09:45
8260D
Chlorobenzene
3.62
pq/L
0.190
05/10/2024
09:45
8260D
Chloroethane
0.468
pg/L
0.430
05/10/2024
09:45
8260D
1,2-Dichlorobenzene
0.278
pq/L
0.220
05/10/2024
09:45
8260D
1,4-Dichlorobenzene
5.75
pg/L
0.210
05/10/2024
09:45
8260D
1,1-Dichloroethane
4.63
pg/L
0.240
05/10/2024
09:45
0
J
0
I:
J
0
J
J
J
JB
J
0
0
Page 11 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
W Waypoint,,
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Summary of Detected
Project: Surry County C&D/MSW Spring
Report Number: 24-124-0102
Client Sample ID Lab Sample ID
Method Parameters
Result Units Report Limit Analyzed
MW-15
V 92549
8260D
1,2-Dichloroethane
0.956
pg/L
0.150
05/10/2024 09:45
8260D
cis- 1,2-Dichloroethene
27.9
pg/L
0.200
05/10/2024 09:45
8260D
trans- 1,2-Dichloroethene
0.486
pg/L
0.180
05/10/2024 09:45
8260D
1,2-Dichloropropane
0.242
pg/L
0.190
05/10/2024 09:45
8260D
Trichloroethene
2.23
pg/L
0.180
05/10/2024 09:45
8260D
Vinyl Chloride
3.83
pg/L
0.170
05/10/2024 09:45
8270D
1,4-Dichlorobenzene
3.20
pg/L
0.405
05/08/2024 22:23
9056A
Chloride
1490
pg/L
500
05/03/202417:43
9056A
Nitrate (NO3-N)
67.0
pg/L
50.0
05/03/2024 17:43
9056A
Sulfate
3510
pg/L
600
05/03/202417:43
RSK-175
Methane
978
pg/L
2.51
05/06/202414:17
SM-3500-Fe-B
Ferrous Iron
1.81
mg/L
0.05
05/03/2024 13:40
MW-14
V 92550
2320E-2011
Alkalinity (as CaCO3)
32000
pg/L
800
05/08/2024 15:40
6020B
Arsenic
0.516
pg/L
0.297
05/14/2024 00:59
6020E
Barium
107
pg/L
0.453
05/14/2024 00:59
6020B
Beryllium
1.32
pg/L
0.102
05/14/2024 00:59
6020B
Chromium
17.1
pg/L
0.346
05/14/2024 00:59
6020B
Cobalt
25.5
pg/L
0.060
05/14/2024 00:59
6020B
Copper
10.7
pg/L
0.489
05/14/2024 00:59
6020B
Lead
4.23
pg/L
0.264
05/14/2024 00:59
6020B
Nickel
13.1
pg/L
0.182
05/14/2024 00:59
6020B
Silver
0.528
pg/L
0.0570
05/14/202419:51
6020E
Tin
1.87
pg/L
1.44
05/14/2024 00:59
6020B
Thallium
0.278
pg/L
0.0610
05/14/2024 00:59
6020B
Vanadium
26.3
pg/L
0.767
05/14/2024 00:59
6020B
Zinc
47.3
pg/L
4.67
05/14/202419:51
8260D
1,1-Dichloroethane
1.84
pg/L
0.240
05/10/202410:10
8260D
cis- 1,2-Dichloroethene
5.73
pg/L
0.200
05/10/202410:10
8260D
Tetrachloroethene
0.287
pg/L
0.220
05/10/202410:10
8260D
Trichloroethene
0.484
pg/L
0.180
05/10/202410:10
9056A
Chloride
3630
pg/L
500
05/03/202417:31
9056A
Nitrate (NO3-N)
70.0
pg/L
50.0
05/03/2024 17:31
9056A
Sulfate
4510
pg/L
600
05/03/202417:31
RSK-175
Methane
6.08
Ng/L
2.51
05/06/202414:30
Qualifiers
I
0
I
H
0
J
JB
J
I
0
J
Page 12 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypoint, (2)
449 Springbrook
Rd, Ch
Charlotte, NC
28217
Main 704.529.6364
ANALYTICAL
www.way po i nta n a lyti c a I -co m
Summary of Detected Analytes
Project:
Surry County C&D/MSW Spring
Report Number: 24-124-0102
Client Sample ID Lab Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
SW-3
V 92551
6020B
Barium
41.9
pq/L
0.453
05/14/2024 01:04
6020B
Chromium
0.866
Ng/L
0.346
05/14/2024 01:04
J
6020B
Cobalt
22.2
pq/L
0.060
05/14/2024 01:04
6020B
Copper
0.693
pg/L
0.489
05/14/2024 01:04
J
6020B
Nickel
2.13
pq/L
0.182
05/14/2024 01:04
6020B
Thallium
0.123
pg/L
0.0610
05/14/2024 01:04
J
8260D
Acetone
2.70
pq/L
1.80
05/10/202410:35
J
8260D
Tetrahydrofuran
1.55
pg/L
1.50
05/10/202410:35
J
8260D SIM
1,4-Dioxane
5.67
pg/L
0.139
05/07/2024 11:08
Trip Blank
V 92552
8260D
Acetone
2.23
pg/L
1.80
05/10/2024 06:23
J
Page 13 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102
REPOR T OF A NA L YSIS
Lab No : 92542
Matrix: Aqueous
Sample ID: MW-21
Sampled: 5/1/2024 15:45
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Sulfate
4460
Ng/L
600
2000
1
05/03/2414:04
NDL
9056A
Ferrous Iron
<0.05 H
mg/L
0.05
0.20
1
05/03/24 13:40
GOB
SM-3500-Fe-B
Ethane
<2.67
Ng/L
2.67
10.0
1
05/06/24 13:25
TBL
RSK-175
Ethene
<2.28
ug/L
2.28
10.0
1
05/06/24 13:25
TBL
RSK-175
Hydrogen
<10.0
Ng/L
10.0
1
05/14/24 14:27
ADO
RSK-175
Methane
<2.51
ug/L
2.51
10.0
1
05/06/24 13:25
TBL
RSK-175
1,4-Dioxane
6.10
Ng/L
0.139
2.00
1
05/06/24 19:49
TBL
8260D SIM
1,4-Naphthoquinone
<10.0 M
ug/L
10.0
10.0
1
05/08/24 20:38
SMB
8270D
1-Naphthylamine
<10.0
Ng/L
10.0
10.0
1
05/08/24 20:38
SMB
8270D
2-Acetylaminofluorene
<10.0
ug/L
10.0
10.0
1
05/08/24 20:38
SMB
8270D
2-Naphthylamine
<10.0
Ng/L
10.0
10.0
1
05/08/24 20:38
SMB
8270D
3-Methylcholanthrene
<10.0
ug/L
10.0
10.0
1
05/08/24 20:38
SMB
8270D
4-Aminobiphenyl
<10.0
Ng/L
10.0
10.0
1
05/08/24 20:38
SMB
8270D
5-Nitro-o-toluidine
<10.0
ug/L
10.0
10.0
1
05/08/24 20:38
SMB
8270D
7,12-Di methyl benz(a)anth racene <10.0
Ng/L
10.0
10.0
1
05/08/24 20:38
SMB
8270D
Diallate
<10.0
ug/L
10.0
10.0
1
05/08/24 20:38
SMB
8270D
Hexachloropropene
<10.0
Ng/L
10.0
10.0
1
05/08/24 20:38
SMB
8270D
Isosafrole
<10.0
ug/L
10.0
10.0
1
05/08/24 20:38
SMB
8270D
Methapyrilene
<10.0
Ng/L
10.0
20.0
1
05/08/24 20:38
SMB
8270D
N-Nitrosomethylethylamine
<10.0
ug/L
10.0
10.0
1
05/08/24 20:38
SMB
8270D
N-Nitrosomorpholine
<10.0
Ng/L
10.0
10.0
1
05/08/24 20:38
SMB
8270D
N-Nitrosopyrrolidine
<10.0
ug/L
10.0
10.0
1
05/08/24 20:38
SMB
8270D
N-Nitrosopiperidine
<10.0
Ng/L
10.0
10.0
1
05/08/24 20:38
SMB
8270D
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum
value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 14 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102
REPOR T OF A NA L YSIS
Lab No : 92542
Matrix: Aqueous
Sample ID: MW-21
Sampled: 5/1/2024 15:45
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
0,0,0-Triethyl Phosphorothioate
<0.330
Ng/L
0.330
1.00
1
05/08/24 19:32
SMB
8270C
o-Toluidine
<10.0
u9/L
10.0
10.0
1
05/08/24 20:38
SMB
8270D
p-Dimethylaminoazobenzene
<10.0
Ng/L
10.0
10.0
1
05/08/24 20:38
SMB
8270D
p-Phenylenediamine
<10.0 M
u9/L
10.0
10.0
1
05/08/24 20:38
SMB
8270D
Pronamide
<10.0
Ng/L
10.0
10.0
1
05/08/24 20:38
SMB
8270D
Safrole
<10.0
u9/L
10.0
10.0
1
05/08/24 20:38
SMB
8270D
Thionazine
<0.330
Ng/L
0.330
1.00
1
05/08/2419:32
SMB
8270C
Alkalinity (as CaCO3)
29000
u9/L
800
5000
1
05/08/24 15:40
RLW
2320B-2011
Biochemical Oxygen Demand (5-day)
<2000
N9/L
2000
2000
1
05/03/24 10:39
MLW
521OB-2015
Chloride
28700
u9/L
500
1000
1
05/03/2414:04
NDL
9056A
Cyanide, Total
<12.0
N9/L
12.0
25.0
1
05/14/24 14:05
RLW
9014
COD (Chemical Oxygen Demand)
<15000
u9/L
15000
30000
1
05/09/24 11:25
SLO
5220D-2011
Nitrate (NO3-N)
279
N9/L
50.0
100
1
05/03/24 14:04
NDL
9056A
TOC
1400
u9/L
720
1000
1
05/09/24 01:59
AT
531OC-2011
Sulfide
<830
N9/L
830
2000
1
05/06/2414:53
GOB
4500S2F-2011
Antimony
<0.618
u9/L
0.618
1.00
1
05/10/24 21:45
TJS
6020B
Arsenic
0.5143
N9/L
0.297
1.00
1
05/10/24 21:45
TJS
6020B
Barium
56.6
u9/L
0.453
1.00
1
05/10/24 21:45
TJS
6020B
Beryllium
0.1903
N9/L
0.102
1.00
1
05/10/24 21:45
TJS
6020B
Cadmium
<0.350
u9/L
0.350
1.00
1
05/10/24 21:45
TJS
6020B
Chromium
2.62
N9/L
0.346
1.00
1
05/10/24 21:45
TJS
6020B
Cobalt
6.48
u9/L
0.060
1.00
1
05/10/24 21:45
TJS
6020B
Copper
3.52
N9/L
0.489
1.00
1
05/10/24 21:45
TJS
6020B
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum
value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 15 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92542
Sample ID: MW-21
Matrix: Aqueous
Sampled: 5/1/2024 15:45
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Lead
0.6873
Ng/L
0.264
1.00
1
05/10/24 21:45
TJS
6020E
Mercury (Total)
<0.100
ug/L
0.100
0.200
1
05/10/24 14:24
FDS
7470A
Nickel
3.01
Ng/L
0.182
1.00
1
05/10/24 21:45
TJS
6020E
Selenium
<0.703
ug/L
0.703
1.00
1
05/10/24 21:45
TJS
6020B
Silver
<0.0570
Ng/L
0.0570
1.00
1
05/10/24 21:45
TJS
6020E
Tin
<1.44
ug/L
1.44
5.00
1
05/13/2416:39
TJS
6020B
Thallium
0.07583
Ng/L
0.0610
1.00
1
05/10/24 21:45
TJS
6020B
Vanadium
4.43 JB
ug/L
0.767
5.00
1
05/10/24 21:45
TJS
6020B
Zinc
10.1
Ng/L
4.67
10.0
1
05/10/24 21:45
TJS
6020B
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor H Beyond holding time
J Estimated value M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 16 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92542
Matrix: Aqueous
Sample ID: MW-21
Sampled: 5/1/2024 15:45
Analytical Method:
8081B
Prep Batch(es):
V46914
05/07/24 10:07
Prep Method:
3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Aldrin
<0.0152
Ng/L
0.0152
0.0500
1
05/16/24 00:47
TJW
V47319
alpha-BHC
<0.0063
ug/L
0.0063
0.0500
1
05/16/24 00:47
TJW
V47319
beta-BHC
<0.0111
Ng/L
0.0111
0.0500
1
05/16/24 00:47
TJW
V47319
delta-BHC
<0.0082
ug/L
0.0082
0.0500
1
05/16/24 00:47
TJW
V47319
Chlordane
<0.180
Ng/L
0.180
0.500
1
05/16/24 00:47
TJW
V47319
alpha -Chlordane
<0.0186
ug/L
0.0186
0.100
1
05/16/24 00:47
TJW
V47319
gamma -Chlordane
<0.0231
Ng/L
0.0231
0.100
1
05/16/24 00:47
TJW
V47319
4,4'-DDD
<0.0265
ug/L
0.0265
0.100
1
05/16/24 00:47
TJW
V47319
4,4'-DDE
<0.0218
Ng/L
0.0218
0.100
1
05/16/24 00:47
TJW
V47319
4,4'-DDT
<0.0176
ug/L
0.0176
0.100
1
05/16/24 00:47
TJW
V47319
Dieldrin
<0.0137
Ng/L
0.0137
0.0500
1
05/16/24 00:47
TJW
V47319
EndosulfanI
<0.0160
ug/L
0.0160
0.0500
1
05/16/24 00:47
TJW
V47319
Endosulfan II
<0.0121
Ng/L
0.0121
0.0500
1
05/16/24 00:47
TJW
V47319
Endosulfan Sulfate
<0.0165
ug/L
0.0165
0.0500
1
05/16/24 00:47
TJW
V47319
Endrin
<0.0136
Ng/L
0.0136
0.0500
1
05/16/24 00:47
TJW
V47319
Endrin Aldehyde
<0.0158
ug/L
0.0158
0.0500
1
05/16/24 00:47
TJW
V47319
Endrin Ketone
<0.0181
Ng/L
0.0181
0.100
1
05/16/24 00:47
TJW
V47319
gamma-BHC
<0.0061
ug/L
0.0061
0.0500
1
05/16/24 00:47
TJW
V47319
Heptachlor
<0.0130
Ng/L
0.0130
0.0500
1
05/16/24 00:47
TJW
V47319
Heptachlor Epoxide
<0.0224
ug/L
0.0224
0.100
1
05/16/24 00:47
TJW
V47319
Methoxychlor
<0.0179
Ng/L
0.0179
0.100
1
05/16/24 00:47
TJW
V47319
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 17 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102
REPOR T OF A NA L YSIS
Lab No : 92542
Matrix: Aqueous
Sample ID: MW-21
Sampled: 5/1/2024
15:45
Analytical Method: 8081B
Prep Batch(es):
V46914
05/07/24 10:07
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF Date / Time By
Analytical
Analyzed
Batch
Toxaphene
<0.350
Ng/L
0.350
1.00
1 05/16/24 00:47 TJW
V47319
Surrogate: Decachlorobiphenyl
107
Limits:
13-186%
1 05/16/24 00:47 TJW
V47319
Surrogate: Tetrachloro-m-xylene
102
Limits:
40-134%
1 05/16/24 00:47 TJW
V47319
Analytical Method: 8082A
Prep Batch(es):
V46915
05/07/24 10:07
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF Date / Time By
Analytical
Analyzed
Batch
Aroclor 1016
<0.210
u9/L
0.210
0.500
1 05/16/24 18:04 TJW
V47358
Aroclor1221
<0.110
Ng/L
0.110
1.00
1 05/16/24 18:04 TJW
V47358
Aroclor1232
<0.160
u9/L
0.160
0.500
1 05/16/24 18:04 TJW
V47358
Aroclor1242
<0.140
Ng/L
0.140
0.500
1 05/16/24 18:04 TJW
V47358
Aroclor 1248
<0.140
u9/L
0.140
0.500
1 05/16/24 18:04 TJW
V47358
Aroclor1254
<0.160
Ng/L
0.160
0.500
1 05/16/24 18:04 TJW
V47358
Aroclor 1260
<0.495
u9/L
0.495
1.00
1 05/16/24 18:04 TJW
V47358
Surrogate: Decachlorobiphenyl
123
Limits:
32-178%
1 05/16/24 18:04 TJW
8082A
Surrogate: Tetrachloro-m-xylene
76.7
Limits:
30-161%
1 05/16/24 18:04 TJW
8082A
Analytical Method: 8151A
Prep Batch(es):
L749368
05/08/24 16:00
Prep Method: 8151A
Test
Results
Units
MDL
MQL
DF Date / Time By
Analytical
Analyzed
Batch
2,4-D
<0.2099
ug/L
0.2099
0.2525
1 05/15/24 06:20 SWB
L750463
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 18 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
01186
Smith & Gardner, Inc.
Project
Seth C. Rickerts
14 N. Boylan Avenue
Information
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Surry County C&D/MSW Spring
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Report Date : 05/31/2024
Received : 05/03/2024
Lab No : 92542
Sample ID: MW-21
Matrix: Aqueous
Sampled: 5/1/2024 15:45
Analytical Method: 8151A
Prep Batch(es):
L749368
05/08/24 16:00
Prep Method: 8151A
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Dalapon
<0.5201
Ng/L
0.5201
0.5556
1
05/15/24 06:20
SWB
L750463
2,4-DB
<0.1378
ug/L
0.1378
0.2525
1
05/15/24 06:20
SWB
L750463
Dicamba
<0.05757
Ng/L
0.05757
0.1010
1
05/15/24 06:20
SWB
L750463
Dichlorprop
<0.08038
ug/L
0.08038
0.1010
1
05/15/24 06:20
SWB
L750463
Dinoseb
<0.02724
Ng/L
0.02724
0.1010
1
05/15/24 06:20
SWB
L750463
MCPA
<19.17
ug/L
19.17
50.51
1
05/15/24 06:20
SWB
L750463
MCPP
<11.87
Ng/L
11.87
50.51
1
05/15/24 06:20
SWB
L750463
Picloram
<0.04573
ug/L
0.04573
0.1010
1
05/15/24 06:20
SWB
L750463
2,4,5-T
<0.1012
Ng/L
0.1012
0.1263
1
05/15/24 06:20
SWB
L750463
2,4,5-TP (Silvex)
<0.01650
ug/L
0.01650
0.1010
1
05/15/24 06:20
SWB
L750463
Surrogate: DCAA
164.0 *
Limits:
20-150%
1 05/15/24 06:20 SWB
L750463
Analytical Method: 8260D
Prep Batch(es):
V47200
05/09/24 14:00
V47336
05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
2.183
ug/L
1.80
5.00
1 05/10/24 06:49 MSA
V47202
Acetonitrile
<10.0
Ng/L
10.0
10.0
1 05/15/2414:50 MSA
V47337
Acrolein
<2.00
ug/L
2.00
5.00
1 05/10/24 06:49 MSA
V47202
Acrylonitrile
<0.230
Ng/L
0.230
5.00
1 05/10/24 06:49 MSA
V47202
Allyl Chloride
<0.579
ug/L
0.579
10.0
1 05/15/24 14:50 MSA
V47337
Benzene
<0.180
Ng/L
0.180
0.500
1 05/10/24 06:49 MSA
V47202
Bromochloromethane
<0.420
ug/L
0.420
1.00
1 05/10/24 06:49 MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 19 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92542
Matrix: Aqueous
Sample ID: MW-21
Sampled: 5/1/2024 15:45
Analytical Method: 8260D
Prep Batch(es):
V47200
05/09/24 14:00
V47336
05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
05/10/24 06:49
MSA
V47202
Bromoform
<1.50
ug/L
1.50
5.00
1
05/10/24 06:49
MSA
V47202
Bromomethane
<0.280
Ng/L
0.280
1.00
1
05/10/24 06:49
MSA
V47202
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
05/10/24 06:49
MSA
V47202
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
05/10/24 06:49
MSA
V47202
Chlorobenzene
<0.190
ug/L
0.190
0.500
1
05/10/24 06:49
MSA
V47202
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
05/10/24 06:49
MSA
V47202
Chloroethane
<0.430
ug/L
0.430
1.00
1
05/10/24 06:49
MSA
V47202
Chloroform
<0.220
Ng/L
0.220
0.500
1
05/10/24 06:49
MSA
V47202
Chloromethane
<0.220
ug/L
0.220
0.500
1
05/10/24 06:49
MSA
V47202
Chloroprene
<0.450
Ng/L
0.450
10.0
1
05/15/24 14:50
MSA
V47337
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
05/10/24 06:49
MSA
V47202
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
05/10/24 06:49
MSA
V47202
Dibromomethane
<0.230
ug/L
0.230
0.500
1
05/10/24 06:49
MSA
V47202
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
05/10/24 06:49
MSA
V47202
1,2-Dichlorobenzene
<0.220
ug/L
0.220
0.500
1
05/10/24 06:49
MSA
V47202
1,3-Dichlorobenzene
<0.190
Ng/L
0.190
0.500
1
05/10/24 06:49
MSA
V47202
1,4-Dichlorobenzene
<0.210
ug/L
0.210
0.500
1
05/10/24 06:49
MSA
V47202
Dichlorodifluoromethane
<1.20
Ng/L
1.20
5.00
1
05/10/24 06:49
MSA
V47202
1,1-Dichloroethane
0.701
ug/L
0.240
0.500
1
05/10/24 06:49
MSA
V47202
1,2-Dichloroethane
<0.150
Ng/L
0.150
0.500
1
05/10/24 06:49
MSA
V47202
1,1-Dichloroethene
<0.150
ug/L
0.150
0.500
1
05/10/24 06:49
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 20 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92542
Matrix: Aqueous
Sample ID: MW-21
Sampled: 5/1/2024 15:45
Analytical Method: 8260D
Prep Batch(es):
V47200
05/09/24 14:00
V47336
05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
cis- 1,2-Dich loroethene
7.88
Ng/L
0.200
0.500
1
05/10/24 06:49
MSA
V47202
trans- 1.2-Dichloroethene
<0.180
ug/L
0.180
0.500
1
05/10/24 06:49
MSA
V47202
1,2-Dichloropropane
<0.190
Ng/L
0.190
0.500
1
05/10/24 06:49
MSA
V47202
1,3-Dichloropropane
<0.130
ug/L
0.130
0.500
1
05/10/24 06:49
MSA
V47202
2,2-Dichloropropane
<0.210
Ng/L
0.210
2.00
1
05/10/24 06:49
MSA
V47202
1,1-Dichloropropene
<0.200
ug/L
0.200
0.500
1
05/10/24 06:49
MSA
V47202
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
05/10/24 06:49
MSA
V47202
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
05/10/24 06:49
MSA
V47202
Ethyl Methacrylate
<1.62
Ng/L
1.62
10.0
1
05/15/24 14:50
MSA
V47337
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
05/10/24 06:49
MSA
V47202
Hexachlorobutadiene
<0.350
Ng/L
0.350
2.00
1
05/10/24 06:49
MSA
V47202
2-Hexanone
<0.380
ug/L
0.380
5.00
1
05/10/24 06:49
MSA
V47202
Iodomethane
<0.054
Ng/L
0.054
0.500
1
05/10/24 06:49
MSA
V47202
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
05/10/24 06:49
MSA
V47202
Methacrylonitrile
<10.0
Ng/L
10.0
10.0
1
05/15/2414:50
MSA
V47337
4-Methyl-2-Pentanone
<1.00
ug/L
1.00
5.00
1
05/10/24 06:49
MSA
V47202
Methylene Chloride
<0.330
Ng/L
0.330
1.00
1
05/10/24 06:49
MSA
V47202
Naphthalene
<0.470
ug/L
0.470
1.00
1
05/10/24 06:49
MSA
V47202
Propionitrile
<10.0
Ng/L
10.0
10.0
1
05/15/2414:50
MSA
V47337
Styrene
<0.220
ug/L
0.220
0.500
1
05/10/24 06:49
MSA
V47202
1,1,1,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
05/10/24 06:49
MSA
V47202
1,1,2,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
05/10/24 06:49
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 21 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92542
Matrix: Aqueous
Sample ID: MW-21
Sampled: 5/1/2024
15:45
Analytical Method: 8260D
Prep Batch(es):
V47200 05/09/24 14:00
V47336 05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Tetrachloroethene
<0.220
Ng/L
0.220 0.500
1
05/10/24 06:49 MSA
V47202
Tetrahydrofuran
<1.50
ug/L
1.50 10.0
1
05/10/24 06:49 MSA
V47202
Toluene
<0.220
Ng/L
0.220 0.500
1
05/10/24 06:49 MSA
V47202
1,2,4-Trichlorobenzene
<0.310
ug/L
0.310 1.00
1
05/10/24 06:49 MSA
V47202
1,1,1-Trichloroethane
<0.160
Ng/L
0.160 0.500
1
05/10/24 06:49 MSA
V47202
1,1,2-Trichloroethane
<0.096
ug/L
0.096 0.500
1
05/10/24 06:49 MSA
V47202
Trichloroethene
0.2693
Ng/L
0.180 0.500
1
05/10/24 06:49 MSA
V47202
Trichlorofluoromethane
<0.180
ug/L
0.180 0.500
1
05/10/24 06:49 MSA
V47202
1,2,3-Trichloropropane
<0.270
Ng/L
0.270 1.00
1
05/10/24 06:49 MSA
V47202
Vinyl Acetate
<1.00 M
ug/L
1.00 2.00
1
05/10/24 06:49 MSA
V47202
Vinyl Chloride
<0.170
Ng/L
0.170 0.500
1
05/10/24 06:49 MSA
V47202
o-Xylene
<0.210
ug/L
0.210 0.500
1
05/10/24 06:49 MSA
V47202
m,p-Xylene
<0.420
Ng/L
0.420 1.00
1
05/10/24 06:49 MSA
V47202
Xylene (Total)
<0.21
ug/L
0.210 0.500
1
05/10/24 06:49 KCC
V47202
Surrogate: 4-Bromofluorobenzene
100
Limits: 80-124%
1 05/10/24 06:49 MSA
V47202
Surrogate: Dibromofluoromethane
102
Limits: 75-129%
1 05/10/24 06:49 MSA
V47202
Surrogate: 1,2-Dichloroethane - d4
99.0
Limits: 63-136%
1 05/10/24 06:49 MSA
V47202
Surrogate: Toluene-d8
99.4
Limits: 77-123%
1 05/10/24 06:49 MSA
V47202
Surrogate:4-Bromofluorobenzene
100
Limits:80-124%
1 05/15/24 14:50 MSA
V47337
Surrogate: Dibromofluoromethane
103
Limits: 75-129%
1 05/15/24 14:50 MSA
V47337
Surrogate: 1,2-Dichloroethane - d4
105
Limits: 63-136%
1 05/15/24 14:50 MSA
V47337
Surrogate: Toluene-d8
107
Limits: 77-123%
1 05/15/24 14:50 MSA
V47337
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 22 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
01186
Smith & Gardner, Inc.
Project
Seth C. Rickerts
14 N. Boylan Avenue
Information
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Surry County C&D/MSW Spring
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Report Date : 05/31/2024
Received : 05/03/2024
Lab No : 92542 Matrix: Aqueous
Sample ID: MW-21 Sampled: 5/1/2024 15:45
Analytical Method: 8270C Prep Batch(es): L749277 05/08/24 12:10
Prep Method: 3510C
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Dimethoate
<0.713
Ng/L
0.713
1.00
1
05/08/24 19:32
SMB
L749502
Disulfoton
<0.466
ug/L
0.466
1.00
1
05/08/24 19:32
SMB
L749502
Ethyl Parathion
<0.568
Ng/L
0.568
1.00
1
05/08/24 19:32
SMB
L749502
Famphur
<0.512
ug/L
0.512
1.00
1
05/08/24 19:32
SMB
L749502
Methyl Parathion
<0.805
Ng/L
0.805
1.00
1
05/08/24 19:32
SMB
L749502
Phorate
<0.659
ug/L
0.659
1.00
1
05/08/24 19:32
SMB
L749502
Surrogate: Tributyl phosphate
74.5
Limits:
50-150%
1 05/08/24 19:32 SMB
8270C
Surrogate: Triphenyl phosphate
87.5
Limits:
50-150%
1 05/08/24 19:32 SMB
8270C
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,3-Dinitrobenzene
<0.904
ug/L
0.904
10.0
1
05/08/24 20:38
SMB
L749499
1,3,5-Trinitrobenzene
<10.0
Ng/L
10.0
10.0
1
05/08/24 20:38
SMB
L749501
Acenaphthene
<0.563
ug/L
0.563
2.00
1
05/08/24 20:38
SMB
L749499
Acenaphthylene
<0.562
Ng/L
0.562
2.00
1
05/08/24 20:38
SMB
L749499
Acetophenone
<0.689
ug/L
0.689
5.00
1
05/08/24 20:38
SMB
L749499
Anthracene
<0.536
Ng/L
0.536
2.00
1
05/08/24 20:38
SMB
L749499
Benzo(a)anthracene
<0.520
ug/L
0.520
2.00
1
05/08/24 20:38
SMB
L749499
Benzo(a)pyrene
<0.511
Ng/L
0.511
2.00
1
05/08/24 20:38
SMB
L749499
Benzo(b)fluoranthene
<0.631
ug/L
0.631
2.00
1
05/08/24 20:38
SMB
L749499
Benzo(g,h,i)perylene
<0.507
Ng/L
0.507
2.00
1
05/08/24 20:38
SMB
L749499
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 23 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92542
Matrix: Aqueous
Sample ID: MW-21
Sampled: 5/1/2024 15:45
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Benzo(k)fluoranthene
<0.575
Ng/L
0.575
2.00
1
05/08/24 20:38
SMB
L749499
Benzyl alcohol
<1.02
ug/L
1.02
10.0
1
05/08/24 20:38
SMB
L749499
Bis(2-Chloroethoxy)methane
<0.592
Ng/L
0.592
5.00
1
05/08/24 20:38
SMB
L749499
Bis(2-Chloroethyl)ether
<0.627
ug/L
0.627
5.00
1
05/08/24 20:38
SMB
L749499
Bis(2-Chloroisopropyl)ether
<0.656
Ng/L
0.656
5.00
1
05/08/24 20:38
SMB
L749499
Bis(2-ethylhexyl)phthalate
<0.796
ug/L
0.796
5.00
1
05/08/24 20:38
SMB
L749499
4-Bromophenyl phenyl ether
<0.567
Ng/L
0.567
5.00
1
05/08/24 20:38
SMB
L749499
Butyl benzyl phthalate
<0.756
ug/L
0.756
5.00
1
05/08/24 20:38
SMB
L749499
4-Chloro-3-methylphenol
<0.550
Ng/L
0.550
5.00
1
05/08/24 20:38
SMB
L749499
4-Chloroaniline
<0.530
ug/L
0.530
5.00
1
05/08/24 20:38
SMB
L749499
Chlorobenzilate
<0.999
Ng/L
0.999
5.00
1
05/08/24 20:38
SMB
L749499
2-Chloronaphthalene
<0.560
ug/L
0.560
5.00
1
05/08/24 20:38
SMB
L749499
2-Chlorophenol
<0.457
Ng/L
0.457
5.00
1
05/08/24 20:38
SMB
L749499
4-Chlorophenyl phenyl ether
<0.615
ug/L
0.615
5.00
1
05/08/24 20:38
SMB
L749499
Chrysene
<0.550
Ng/L
0.550
2.00
1
05/08/24 20:38
SMB
L749499
Dibenz(a,h)anthracene
<0.460
ug/L
0.460
2.00
1
05/08/24 20:38
SMB
L749499
Dibenzofuran
<0.584
Ng/L
0.584
5.00
1
05/08/24 20:38
SMB
L749499
1,2-Dichlorobenzene
<0.466
ug/L
0.466
5.00
1
05/08/24 20:38
SMB
L749499
1,3-Dichlorobenzene
<0.436
Ng/L
0.436
5.00
1
05/08/24 20:38
SMB
L749499
1,4-Dichlorobenzene
<0.405
ug/L
0.405
5.00
1
05/08/24 20:38
SMB
L749499
3,3'-Dichlorobenzidine
<10.3
Ng/L
10.3
20.0
1
05/08/24 20:38
SMB
L749499
2,4-Dichlorophenol
<0.606
ug/L
0.606
5.00
1
05/08/24 20:38
SMB
L749499
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 24 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92542
Matrix: Aqueous
Sample ID: MW-21
Sampled: 5/1/2024 15:45
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
2,6-Dichlorophenol
<0.655
Ng/L
0.655
5.00
1
05/08/24 20:38
SMB
L749499
Diethyl phthalate
<0.686
ug/L
0.686
5.00
1
05/08/24 20:38
SMB
L749499
Dimethyl phthalate
<0.652
Ng/L
0.652
5.00
1
05/08/24 20:38
SMB
L749499
3,3' Dimethylbenzidine
<9.01
ug/L
9.01
10.0
1
05/08/24 20:38
SMB
L749499
2,4-Dimethyl phenol
<0.620
Ng/L
0.620
5.00
1
05/08/24 20:38
SMB
L749499
Di-n-butyl phthalate
<0.740
ug/L
0.740
5.00
1
05/08/24 20:38
SMB
L749499
4,6-Dinitro-2- methyl phenol
<6.08
Ng/L
6.08
10.0
1
05/08/24 20:38
SMB
L749499
2,4-Dinitrophenol
<18.9
ug/L
18.9
20.0
1
05/08/24 20:38
SMB
L749499
2,4-Dinitrotoluene
<0.911
Ng/L
0.911
5.00
1
05/08/24 20:38
SMB
L749499
2,6-Dinitrotoluene
<0.734
ug/L
0.734
5.00
1
05/08/24 20:38
SMB
L749499
Di-n-Octyl Phthalate
<1.32
Ng/L
1.32
5.00
1
05/08/24 20:38
SMB
L749499
Ethyl methanesulfonate
<0.660
ug/L
0.660
5.00
1
05/08/24 20:38
SMB
L749499
Fluoranthene
<0.583
Ng/L
0.583
2.00
1
05/08/24 20:38
SMB
L749499
Fluorene
<0.617
ug/L
0.617
2.00
1
05/08/24 20:38
SMB
L749499
Hexachlorobenzene
<0.537
Ng/L
0.537
5.00
1
05/08/24 20:38
SMB
L749499
Hexachlorobutadiene
<0.411
ug/L
0.411
5.00
1
05/08/24 20:38
SMB
L749499
Hexachlorocyclopentadiene
<0.889
Ng/L
0.889
5.00
1
05/08/24 20:38
SMB
L749499
Hexachloroethane
<0.482
ug/L
0.482
5.00
1
05/08/24 20:38
SMB
L749499
Indeno(1,2,3-cd)pyrene
<0.490
Ng/L
0.490
2.00
1
05/08/24 20:38
SMB
L749499
Isodrin
<10.0
ug/L
10.0
10.0
1
05/08/24 20:38
SMB
L749501
Isophorone
<0.591
Ng/L
0.591
5.00
1
05/08/24 20:38
SMB
L749499
Kepone
<10.0 M
ug/L
10.0
10.0
1
05/08/24 20:38
SMB
L749501
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 25 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92542
Matrix: Aqueous
Sample ID: MW-21
Sampled: 5/1/2024 15:45
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Methyl methanesulfonate
<0.746
Ng/L
0.746
5.00
1
05/08/24 20:38
SMB
L749499
2-Methylnaphthalene
<0.569
ug/L
0.569
2.00
1
05/08/24 20:38
SMB
L749499
2-Methylphenol
<0.449
Ng/L
0.449
5.00
1
05/08/24 20:38
SMB
L749499
3&4 Methylphenol
<0.453
ug/L
0.453
5.00
1
05/08/24 20:38
SMB
L749499
Naphthalene
<1.70
Ng/L
1.70
2.00
1
05/08/24 20:38
SMB
L749499
2-Nitroaniline
<0.766
ug/L
0.766
5.00
1
05/08/24 20:38
SMB
L749499
3-Nitroaniline
<0.912
Ng/L
0.912
10.0
1
05/08/24 20:38
SMB
L749499
4-Nitroaniline
<12.5
ug/L
12.5
20.0
1
05/08/24 20:38
SMB
L749499
Nitrobenzene
<0.715
Ng/L
0.715
5.00
1
05/08/24 20:38
SMB
L749499
2-Nitrophenol
<0.728
ug/L
0.728
5.00
1
05/08/24 20:38
SMB
L749499
4-Nitrophenol
<1.94
Ng/L
1.94
10.0
1
05/08/24 20:38
SMB
L749499
N-Nitrosodimethylamine
<0.295
ug/L
0.295
5.00
1
05/08/24 20:38
SMB
L749499
N-Nitrosodiphenylamine
<0.487
Ng/L
0.487
10.0
1
05/08/24 20:38
SMB
L749499
N-Nitrosodiethylamine
<0.535
ug/L
0.535
5.00
1
05/08/24 20:38
SMB
L749499
N-Nitroso-di-n-butylamine
<0.699
Ng/L
0.699
5.00
1
05/08/24 20:38
SMB
L749499
N-Nitroso-di-n-propylamine
<0.678
ug/L
0.678
5.00
1
05/08/24 20:38
SMB
L749499
Pentachlorobenzene
<0.574
Ng/L
0.574
10.0
1
05/08/24 20:38
SMB
L749499
Pentachloronitrobenzene
<0.569
ug/L
0.569
5.00
1
05/08/24 20:38
SMB
L749499
Pentachlorophenol
<1.23
Ng/L
1.23
10.0
1
05/08/24 20:38
SMB
L749499
Phenacetin
<0.693
ug/L
0.693
5.00
1
05/08/24 20:38
SMB
L749499
Phenanthrene
<0.582
Ng/L
0.582
2.00
1
05/08/24 20:38
SMB
L749499
Phenol
<0.258
ug/L
0.258
5.00
1
05/08/24 20:38
SMB
L749499
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 26 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
01186
Smith & Gardner, Inc.
Project
Seth C. Rickerts
14 N. Boylan Avenue
Information
Raleigh , NC 27603
Report Number : 24-124-0102
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Surry County C&D/MSW Spring
REPORT OF ANAL YSIS
Report Date : 05/31/2024
Received : 05/03/2024
Lab No : 92542 Matrix: Aqueous
Sample ID: MW-21 Sampled: 5/1/2024 15:45
Analytical Method: 8270D
Prep Method: 3510C
Test Results
Pyrene
<0.680
1,2,4,5-Tetrachlorobenzene
<0.463
2,3,4,6-Tetrachlorophenol
<0.570
1,2,4-Trichlorobenzene
<0.433
2,4,5-Trichlorophenol
<0.611
2,4,6-Trichlorophenol
<0.539
Surrogate: 2-Fluorobiphenyl
Surrogate: 2-Fluorophenol
Surrogate: Nitrobenzene-d5
Surrogate: Phenol-d6
Surrogate: 4-Terphenyl-d 14
Surrogate: 2,4,6-Tribromophenol
Prep Batch(es): L749275 05/08/24 12:10
Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.680 2.00
Pg/L
0.463 5.00
Ng/L
0.570 5.00
ug/L
0.433 5.00
Ng/L
0.611 5.00
Pg/L
0.539 5.00
61.1
Limits: 24-93%
31.0
Limits: 10-44%
57.7
Limits: 20-91%
22.2
Limits: 7-32%
68.6
Limits: 35-126%
65.3
Limits: 39-110%
1 05/08/24 20:38 SMB
L749499
1 05/08/24 20:38 SMB
L749499
1 05/08/24 20:38 SMB
L749499
1 05/08/24 20:38 SMB
L749499
1 05/08/24 20:38 SMB
L749499
1 05/08/24 20:38 SMB
L749499
1 05/08/24 20:38 SMB
L749499
1 05/08/24 20:38 SMB
L749499
1 05/08/24 20:38 SMB
L749499
1 05/08/24 20:38 SMB
L749499
1 05/08/24 20:38 SMB
L749499
1 05/08/24 20:38 SMB
L749499
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor H Beyond holding time
J Estimated value M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 27 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92543
Sample ID: SW-1
Matrix: Aqueous
Sampled: 5/1/2024 12:30
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
1,4-Dioxane
<0.139
Ng/L
0.139
2.00
1
05/06/24 20:14
TBL
8260D SIM
Antimony
<0.618
u9/L
0.618
1.00
1
05/10/24 21:56
TJS
6020B
Arsenic
0.4043
Ng/L
0.297
1.00
1
05/10/24 21:56
TJS
6020E
Barium
20.5
u9/L
0.453
1.00
1
05/10/24 21:56
TJS
6020B
Beryllium
<0.102
Ng/L
0.102
1.00
1
05/10/24 21:56
TJS
6020E
Cadmium
<0.350
u9/L
0.350
1.00
1
05/10/24 21:56
TJS
6020B
Chromium
0.4783
N9/L
0.346
1.00
1
05/10/24 21:56
TJS
6020E
Cobalt
0.226 J
u9/L
0.060
1.00
1
05/10/24 21:56
TJS
6020B
Copper
0.6763
N9/L
0.489
1.00
1
05/10/24 21:56
TJS
6020E
Lead
<0.264
u9/L
0.264
1.00
1
05/10/24 21:56
TJS
6020B
Nickel
<0.182
N9/L
0.182
1.00
1
05/10/24 21:56
TJS
6020E
Selenium
<0.703
u9/L
0.703
1.00
1
05/10/24 21:56
TJS
6020B
Silver
<0.0570
N9/L
0.0570
1.00
1
05/10/24 21:56
TJS
6020E
Thallium
<0.0610
u9/L
0.0610
1.00
1
05/10/24 21:56
TJS
6020B
Vanadium
1.86 JB
N9/L
0.767
5.00
1
05/10/24 21:56
TJS
6020B
Zinc
<4.67
ug/L
4.67
10.0
1
05/10/24 21:56
TJS
6020B
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor H Beyond holding time
J Estimated value M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 28 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92543
Matrix: Aqueous
Sample ID: SW-1
Sampled: 5/1/2024 12:30
Analytical Method: 8260D
Prep Batch(es):
V47200
05/09/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
2.883
Ng/L
1.80
5.00
1
05/10/24 07:14
MSA
V47202
Acrylonitrile
<0.230
ug/L
0.230
5.00
1
05/10/24 07:14
MSA
V47202
Benzene
<0.180
Ng/L
0.180
0.500
1
05/10/24 07:14
MSA
V47202
Bromochloromethane
<0.420
ug/L
0.420
1.00
1
05/10/24 07:14
MSA
V47202
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
05/10/24 07:14
MSA
V47202
Bromoform
<1.50
ug/L
1.50
5.00
1
05/10/24 07:14
MSA
V47202
Bromomethane
<0.280
Ng/L
0.280
1.00
1
05/10/24 07:14
MSA
V47202
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
05/10/24 07:14
MSA
V47202
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
05/10/24 07:14
MSA
V47202
Chlorobenzene
<0.190
ug/L
0.190
0.500
1
05/10/24 07:14
MSA
V47202
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
05/10/24 07:14
MSA
V47202
Chloroethane
<0.430
ug/L
0.430
1.00
1
05/10/24 07:14
MSA
V47202
Chloroform
<0.220
Ng/L
0.220
0.500
1
05/10/24 07:14
MSA
V47202
Chloromethane
<0.220
ug/L
0.220
0.500
1
05/10/24 07:14
MSA
V47202
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
05/10/24 07:14
MSA
V47202
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
05/10/24 07:14
MSA
V47202
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
05/10/24 07:14
MSA
V47202
Dibromomethane
<0.230
ug/L
0.230
0.500
1
05/10/24 07:14
MSA
V47202
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
05/10/24 07:14
MSA
V47202
1,2-Dichlorobenzene
<0.220
ug/L
0.220
0.500
1
05/10/24 07:14
MSA
V47202
1,4-Dichlorobenzene
<0.210
Ng/L
0.210
0.500
1
05/10/24 07:14
MSA
V47202
Dichlorodifluoromethane
<1.20
ug/L
1.20
5.00
1
05/10/24 07:14
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 29 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92543
Matrix: Aqueous
Sample ID: SW-1
Sampled: 5/1/2024 12:30
Analytical Method: 8260D
Prep Batch(es):
V47200
05/09/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
05/10/24 07:14
MSA
V47202
1,2-Dichloroethane
<0.150
ug/L
0.150
0.500
1
05/10/24 07:14
MSA
V47202
1,1-Dichloroethene
<0.150
Ng/L
0.150
0.500
1
05/10/24 07:14
MSA
V47202
cis- 1,2-Dich loroethene
<0.200
ug/L
0.200
0.500
1
05/10/24 07:14
MSA
V47202
trans-1,2-Dichloroethene
<0.180
Ng/L
0.180
0.500
1
05/10/24 07:14
MSA
V47202
1,2-Dichloropropane
<0.190
ug/L
0.190
0.500
1
05/10/24 07:14
MSA
V47202
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
05/10/24 07:14
MSA
V47202
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
05/10/24 07:14
MSA
V47202
1,4-Dioxane
<16.0
Ng/L
16.0
150
1
05/10/24 07:14
MSA
V47202
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
05/10/24 07:14
MSA
V47202
2-Hexanone
<0.380
Ng/L
0.380
5.00
1
05/10/24 07:14
MSA
V47202
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
05/10/24 07:14
MSA
V47202
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
05/10/24 07:14
MSA
V47202
Methylene Chloride
<0.330
ug/L
0.330
1.00
1
05/10/24 07:14
MSA
V47202
Styrene
<0.220
Ng/L
0.220
0.500
1
05/10/24 07:14
MSA
V47202
1,1,1,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
05/10/24 07:14
MSA
V47202
1,1,2,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
05/10/24 07:14
MSA
V47202
Tetrachloroethene
<0.220
ug/L
0.220
0.500
1
05/10/24 07:14
MSA
V47202
Tetrahydrofuran
<1.50
Ng/L
1.50
10.0
1
05/10/24 07:14
MSA
V47202
Toluene
<0.220
ug/L
0.220
0.500
1
05/10/24 07:14
MSA
V47202
1,1,1-Trichloroethane
<0.160
Ng/L
0.160
0.500
1
05/10/24 07:14
MSA
V47202
1,1,2-Trichloroethane
<0.096
ug/L
0.096
0.500
1
05/10/24 07:14
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 30 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
01186
Smith & Gardner, Inc.
Project
Seth C. Rickerts
14 N. Boylan Avenue
Information
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Surry County C&D/MSW Spring
Report Date : 05/31/2024
Received : 05/03/2024
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92543 Matrix: Aqueous
Sample ID: SW-1 Sampled: 5/1/2024 12:30
Analytical Method: 8260D
Prep Method: 5030E
Test Results
Trichloroethene
<0.180
Trichlorofluoromethane
<0.180
1,2,3-Trichloropropane
<0.270
Vinyl Acetate
<1.00 M
Vinyl Chloride
<0.170
o-Xylene
<0.210
m,p-Xylene
<0.420
Xylene (Total)
<0.21
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Prep Batch(es): V47200 05/09/24 14:00
Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.180 0.500
Pg/L
0.180 0.500
Ng/L
0.270 1.00
Pg/L
1.00 2.00
Ng/L
0.170 0.500
Pg/L
0.210 0.500
Ng/L
0.420 1.00
Pg/L
0.210 0.500
101
Limits: 80-124%
101
Limits: 75-129%
100
Limits: 63-136%
99.6
Limits: 77-123%
1 05/10/24 07:14 MSA V47202
1 05/10/24 07:14 MSA V47202
1 05/10/24 07:14 MSA V47202
1 05/10/24 07:14 MSA V47202
1 05/10/24 07:14 MSA V47202
1 05/10/24 07:14 MSA V47202
1 05/10/24 07:14 MSA V47202
1 05/10/24 07:14 KCC V47202
1 05/10/24 07:14 MSA V47202
1 05/10/24 07:14 MSA V47202
1 05/10/24 07:14 MSA V47202
1 05/10/24 07:14 MSA V47202
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor H Beyond holding time
J Estimated value M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 31 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102
REPOR T OF A NA L YSIS
Lab No : 92544
Matrix: Aqueous
Sample ID: MW-9
Sampled: 5/2/2024 11:00
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Sulfate
18503
Ng/L
600
2000
1
05/03/24 17:06
NDL
9056A
Ferrous Iron
23.5 H
mg/L
1.25
5.00
1
05/03/24 13:40
GOB
SM-3500-Fe-B
Ethane
44.2
Ng/L
2.67
10.0
1
05/06/24 14:43
TBL
RSK-175
Ethene
3.873
ug/L
2.28
10.0
1
05/06/24 14:43
TBL
RSK-175
Hydrogen
<10.0
Ng/L
10.0
1
05/14/24 14:37
ADO
RSK-175
Methane
2430
ug/L
25.1
100
10
05/06/24 15:22
TBL
RSK-175
1,4-Dioxane
4.00
Ng/L
0.139
2.00
1
05/06/24 20:39
TBL
8260D SIM
1,4-Naphthoquinone
<10.1 M
ug/L
10.1
10.1
1
05/08/24 20:59
SMB
8270D
1-Naphthylamine
<10.1
Ng/L
10.1
10.1
1
05/08/24 20:59
SMB
8270D
2-Acetylaminofluorene
<10.1
ug/L
10.1
10.1
1
05/08/24 20:59
SMB
8270D
2-Naphthylamine
<10.1
Ng/L
10.1
10.1
1
05/08/24 20:59
SMB
8270D
3-Methylcholanthrene
<10.1
ug/L
10.1
10.1
1
05/08/24 20:59
SMB
8270D
4-Aminobiphenyl
<10.1
Ng/L
10.1
10.1
1
05/08/24 20:59
SMB
8270D
5-Nitro-o-toluidine
<10.1
ug/L
10.1
10.1
1
05/08/24 20:59
SMB
8270D
7,12-Di methyl benz(a)anth racene <10.1
Ng/L
10.1
10.1
1
05/08/24 20:59
SMB
8270D
Diallate
<10.1
ug/L
10.1
10.1
1
05/08/24 20:59
SMB
8270D
Hexachloropropene
<10.1
Ng/L
10.1
10.1
1
05/08/24 20:59
SMB
8270D
Isosafrole
<10.1
ug/L
10.1
10.1
1
05/08/24 20:59
SMB
8270D
Methapyrilene
<10.1
Ng/L
10.1
20.2
1
05/08/24 20:59
SMB
8270D
N-Nitrosomethylethylamine
<10.1
ug/L
10.1
10.1
1
05/08/24 20:59
SMB
8270D
N-Nitrosomorpholine
<10.1
Ng/L
10.1
10.1
1
05/08/24 20:59
SMB
8270D
N-Nitrosopyrrolidine
<10.1
ug/L
10.1
10.1
1
05/08/24 20:59
SMB
8270D
N-Nitrosopiperidine
<10.1
Ng/L
10.1
10.1
1
05/08/24 20:59
SMB
8270D
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum
value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 32 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102
REPOR T OF A NA L YSIS
Lab No : 92544
Matrix: Aqueous
Sample ID: MW-9
Sampled: 5/2/2024 11:00
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
0,0,0-Triethyl Phosphorothioate
<0.333
Ng/L
0.333
1.01
1
05/08/24 19:45
SMB
8270C
o-Toluidine
<10.1
u9/L
10.1
10.1
1
05/08/24 20:59
SMB
8270D
p-Dimethylaminoazobenzene
<10.1
Ng/L
10.1
10.1
1
05/08/24 20:59
SMB
8270D
p-Phenylenediamine
<10.1 M
u9/L
10.1
10.1
1
05/08/24 20:59
SMB
8270D
Pronamide
<10.1
Ng/L
10.1
10.1
1
05/08/24 20:59
SMB
8270D
Safrole
<10.1
u9/L
10.1
10.1
1
05/08/24 20:59
SMB
8270D
Thionazine
<0.333
Ng/L
0.333
1.01
1
05/08/2419:45
SMB
8270C
Alkalinity (as CaCO3)
69000
u9/L
800
5000
1
05/08/24 15:40
RLW
2320B-2011
Biochemical Oxygen Demand (5-day)
6700
N9/L
2000
2000
1
05/03/24 10:39
MLW
521OB-2015
Chloride
37300
u9/L
500
1000
1
05/03/2417:06
NDL
9056A
Cyanide, Total
<12.0
N9/L
12.0
25.0
1
05/14/24 14:05
RLW
9014
COD (Chemical Oxygen Demand)
21000 J
u9/L
15000
30000
1
05/09/24 11:25
SLO
5220D-2011
Nitrate (NO3-N)
62.0 J
N9/L
50.0
100
1
05/03/24 17:06
NDL
9056A
TOC
4110
u9/L
720
1000
1
05/09/24 02:38
AT
531OC-2011
Sulfide
<830
N9/L
830
2000
1
05/06/2414:53
GOB
4500S2F-2011
Antimony
<0.618
u9/L
0.618
1.00
1
05/10/24 21:59
TJS
6020B
Arsenic
0.661 J
N9/L
0.297
1.00
1
05/10/24 21:59
TJS
6020B
Barium
64.8
u9/L
0.453
1.00
1
05/10/24 21:59
TJS
6020B
Beryllium
0.112 J
N9/L
0.102
1.00
1
05/10/24 21:59
TJS
6020B
Cadmium
68.8
u9/L
0.350
1.00
1
05/10/24 21:59
TJS
6020B
Chromium
1.70
N9/L
0.346
1.00
1
05/10/24 21:59
TJS
6020B
Cobalt
152
u9/L
0.060
1.00
1
05/10/24 21:59
TJS
6020B
Copper
8.66
N9/L
0.489
1.00
1
05/10/24 21:59
TJS
6020B
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum
value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 33 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92544
Sample ID: MW-9
Matrix: Aqueous
Sampled: 5/2/2024 11:00
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Lead
1.51
Ng/L
0.264
1.00
1
05/10/24 21:59
TJS
6020E
Mercury (Total)
<0.100
ug/L
0.100
0.200
1
05/13/24 14:49
FDS
7470A
Nickel
20.7
Ng/L
0.182
1.00
1
05/10/24 21:59
TJS
6020E
Selenium
<0.703
ug/L
0.703
1.00
1
05/10/24 21:59
TJS
6020B
Silver
<0.0570
Ng/L
0.0570
1.00
1
05/10/24 21:59
TJS
6020E
Tin
<1.44
ug/L
1.44
5.00
1
05/13/2416:43
TJS
6020B
Thallium
0.5373
Ng/L
0.0610
1.00
1
05/10/24 21:59
TJS
6020B
Vanadium
1.76 JB
ug/L
0.767
5.00
1
05/10/24 21:59
TJS
6020B
Zinc
310
Ng/L
4.67
10.0
1
05/10/24 21:59
TJS
6020B
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor H Beyond holding time
J Estimated value M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 34 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92544
Matrix: Aqueous
Sample ID: MW-9
Sampled: 5/2/2024 11:00
Analytical Method:
8081B
Prep Batch(es):
V46914
05/07/24 10:07
Prep Method:
3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Aldrin
<0.0152
Ng/L
0.0152
0.0500
1
05/16/24 01:01
TJW
V47319
alpha-BHC
<0.0063
ug/L
0.0063
0.0500
1
05/16/24 01:01
TJW
V47319
beta-BHC
<0.0111
Ng/L
0.0111
0.0500
1
05/16/24 01:01
TJW
V47319
delta-BHC
<0.0082
ug/L
0.0082
0.0500
1
05/16/24 01:01
TJW
V47319
Chlordane
<0.180
Ng/L
0.180
0.500
1
05/16/24 01:01
TJW
V47319
alpha -Chlordane
<0.0186
ug/L
0.0186
0.100
1
05/16/24 01:01
TJW
V47319
gamma -Chlordane
<0.0231
Ng/L
0.0231
0.100
1
05/16/24 01:01
TJW
V47319
4,4'-DDD
<0.0265
ug/L
0.0265
0.100
1
05/16/24 01:01
TJW
V47319
4,4'-DDE
<0.0218
Ng/L
0.0218
0.100
1
05/16/24 01:01
TJW
V47319
4,4'-DDT
<0.0176
ug/L
0.0176
0.100
1
05/16/24 01:01
TJW
V47319
Dieldrin
<0.0137
Ng/L
0.0137
0.0500
1
05/16/24 01:01
TJW
V47319
EndosulfanI
<0.0160
ug/L
0.0160
0.0500
1
05/16/24 01:01
TJW
V47319
Endosulfan II
<0.0121
Ng/L
0.0121
0.0500
1
05/16/24 01:01
TJW
V47319
Endosulfan Sulfate
<0.0165
ug/L
0.0165
0.0500
1
05/16/24 01:01
TJW
V47319
Endrin
<0.0136
Ng/L
0.0136
0.0500
1
05/16/24 01:01
TJW
V47319
Endrin Aldehyde
<0.0158
ug/L
0.0158
0.0500
1
05/16/24 01:01
TJW
V47319
Endrin Ketone
<0.0181
Ng/L
0.0181
0.100
1
05/16/24 01:01
TJW
V47319
gamma-BHC
<0.0061
ug/L
0.0061
0.0500
1
05/16/24 01:01
TJW
V47319
Heptachlor
<0.0130
Ng/L
0.0130
0.0500
1
05/16/24 01:01
TJW
V47319
Heptachlor Epoxide
<0.0224
ug/L
0.0224
0.100
1
05/16/24 01:01
TJW
V47319
Methoxychlor
<0.0179
Ng/L
0.0179
0.100
1
05/16/24 01:01
TJW
V47319
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 35 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102
REPOR T OF A NA L YSIS
Lab No : 92544
Matrix: Aqueous
Sample ID: MW-9
Sampled: 5/2/2024
11:00
Analytical Method: 8081B
Prep Batch(es):
V46914
05/07/24 10:07
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF Date / Time By
Analytical
Analyzed
Batch
Toxaphene
<0.350
Ng/L
0.350
1.00
1 05/16/24 01:01 TJW
V47319
Surrogate: Decachlorobiphenyl
82.2
Limits:
13-186%
1 05/16/24 01:01 TJW
V47319
Surrogate: Tetrachloro-m-xylene
119
Limits:
40-134%
1 05/16/24 01:01 TJW
V47319
Analytical Method: 8082A
Prep Batch(es):
V46915
05/07/24 10:07
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF Date / Time By
Analytical
Analyzed
Batch
Aroclor 1016
<0.210
ug/L
0.210
0.500
1 05/16/24 18:17 TJW
V47358
Aroclor1221
<0.110
Ng/L
0.110
1.00
1 05/16/24 18:17 TJW
V47358
Aroclor1232
<0.160
ug/L
0.160
0.500
1 05/16/24 18:17 TJW
V47358
Aroclor1242
<0.140
Ng/L
0.140
0.500
1 05/16/24 18:17 TJW
V47358
Aroclor 1248
<0.140
ug/L
0.140
0.500
1 05/16/24 18:17 TJW
V47358
Aroclor1254
<0.160
Ng/L
0.160
0.500
1 05/16/24 18:17 TJW
V47358
Aroclor 1260
<0.495
ug/L
0.495
1.00
1 05/16/24 18:17 TJW
V47358
Surrogate: Decachlorobiphenyl
91.3
Limits:
32-178%
1 05/16/24 18:17 TJW
8082A
Surrogate: Tetrachloro-m-xylene
92.9
Limits:
30-161%
1 05/16/24 18:17 TJW
8082A
Analytical Method: 8151A
Prep Batch(es):
L749619
05/09/24 13:10
Prep Method: 8151A
Test
Results
Units
MDL
MQL
DF Date / Time By
Analytical
Analyzed
Batch
2,4-D
<0.2099
ug/L
0.2099
0.2525
1 05/14/24 22:52 SWB
L750458
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 36 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92544
Matrix: Aqueous
Sample ID: MW-9
Sampled: 5/2/2024
11:00
Analytical Method:
8151A
Prep Batch(es):
L749619
05/09/24 13:10
Prep Method:
8151A
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Dalapon
<0.5201
Ng/L
0.5201
0.5556
1
05/14/24 22:52
SWB
L750458
2,4-DB
<0.1378
ug/L
0.1378
0.2525
1
05/14/24 22:52
SWB
L750458
Dicamba
<0.05757
Ng/L
0.05757
0.1010
1
05/14/24 22:52
SWB
L750458
Dichlorprop
<0.08038
ug/L
0.08038
0.1010
1
05/14/24 22:52
SWB
L750458
Dinoseb
<0.02724
Ng/L
0.02724
0.1010
1
05/14/24 22:52
SWB
L750458
MCPA
<19.17
ug/L
19.17
50.51
1
05/14/24 22:52
SWB
L750458
MCPP
<11.87
Ng/L
11.87
50.51
1
05/14/24 22:52
SWB
L750458
Picloram
<0.04573
ug/L
0.04573
0.1010
1
05/14/24 22:52
SWB
L750458
2,4,5-T
<0.1012
Ng/L
0.1012
0.1263
1
05/14/24 22:52
SWB
L750458
2,4,5-TP (Silvex)
0.1667
ug/L
0.01650
0.1010
1
05/14/24 22:52
SWB
L750458
Surrogate: DCAA
104.1
Limits:
20-150%
1 05/14/24 22:52 SWB
L750458
Analytical Method:
8260D
Prep Batch(es):
V47200
05/09/24 14:00
V47336
05/14/24 14:00
Prep Method:
5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
ug/L
1.80
5.00
1
05/10/24 07:39
MSA
V47202
Acetonitrile
<10.0
Ng/L
10.0
10.0
1
05/15/2415:15
MSA
V47337
Acrolein
<2.00
ug/L
2.00
5.00
1
05/10/24 07:39
MSA
V47202
Acrylonitrile
<0.230
Ng/L
0.230
5.00
1
05/10/24 07:39
MSA
V47202
Allyl Chloride
<0.579
ug/L
0.579
10.0
1
05/15/24 15:15
MSA
V47337
Benzene
2.42
Ng/L
0.180
0.500
1
05/10/24 07:39
MSA
V47202
Bromochloromethane
<0.420
ug/L
0.420
1.00
1
05/10/24 07:39
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 37 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92544
Matrix: Aqueous
Sample ID: MW-9
Sampled: 5/2/2024 11:00
Analytical Method: 8260D
Prep Batch(es):
V47200
05/09/24 14:00
V47336
05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
05/10/24 07:39
MSA
V47202
Bromoform
<1.50
ug/L
1.50
5.00
1
05/10/24 07:39
MSA
V47202
Bromomethane
<0.280
Ng/L
0.280
1.00
1
05/10/24 07:39
MSA
V47202
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
05/10/24 07:39
MSA
V47202
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
05/10/24 07:39
MSA
V47202
Chlorobenzene
2.57
ug/L
0.190
0.500
1
05/10/24 07:39
MSA
V47202
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
05/10/24 07:39
MSA
V47202
Chloroethane
2.87
ug/L
0.430
1.00
1
05/10/24 07:39
MSA
V47202
Chloroform
<0.220
Ng/L
0.220
0.500
1
05/10/24 07:39
MSA
V47202
Chloromethane
<0.220
ug/L
0.220
0.500
1
05/10/24 07:39
MSA
V47202
Chloroprene
<0.450
Ng/L
0.450
10.0
1
05/15/24 15:15
MSA
V47337
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
05/10/24 07:39
MSA
V47202
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
05/10/24 07:39
MSA
V47202
Dibromomethane
<0.230
ug/L
0.230
0.500
1
05/10/24 07:39
MSA
V47202
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
05/10/24 07:39
MSA
V47202
1,2-Dichlorobenzene
2.18
ug/L
0.220
0.500
1
05/10/24 07:39
MSA
V47202
1,3-Dichlorobenzene
<0.190
Ng/L
0.190
0.500
1
05/10/24 07:39
MSA
V47202
1,4-Dichlorobenzene
6.14
ug/L
0.210
0.500
1
05/10/24 07:39
MSA
V47202
Dichlorodifluoromethane
<1.20
Ng/L
1.20
5.00
1
05/10/24 07:39
MSA
V47202
1,1-Dichloroethane
1.83
ug/L
0.240
0.500
1
05/10/24 07:39
MSA
V47202
1,2-Dichloroethane
<0.150
Ng/L
0.150
0.500
1
05/10/24 07:39
MSA
V47202
1,1-Dichloroethene
<0.150
ug/L
0.150
0.500
1
05/10/24 07:39
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 38 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92544
Matrix: Aqueous
Sample ID: MW-9
Sampled: 5/2/2024 11:00
Analytical Method: 8260D
Prep Batch(es):
V47200
05/09/24 14:00
V47336
05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
cis- 1,2-Dich loroethene
42.4
Ng/L
0.200
0.500
1
05/10/24 07:39
MSA
V47202
trans- 1.2-Dichloroethene
0.3163
ug/L
0.180
0.500
1
05/10/24 07:39
MSA
V47202
1,2-Dichloropropane
<0.190
Ng/L
0.190
0.500
1
05/10/24 07:39
MSA
V47202
1,3-Dichloropropane
<0.130
ug/L
0.130
0.500
1
05/10/24 07:39
MSA
V47202
2,2-Dichloropropane
<0.210
Ng/L
0.210
2.00
1
05/10/24 07:39
MSA
V47202
1,1-Dichloropropene
<0.200
ug/L
0.200
0.500
1
05/10/24 07:39
MSA
V47202
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
05/10/24 07:39
MSA
V47202
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
05/10/24 07:39
MSA
V47202
Ethyl Methacrylate
<1.62
Ng/L
1.62
10.0
1
05/15/24 15:15
MSA
V47337
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
05/10/24 07:39
MSA
V47202
Hexachlorobutadiene
<0.350
Ng/L
0.350
2.00
1
05/10/24 07:39
MSA
V47202
2-Hexanone
<0.380
ug/L
0.380
5.00
1
05/10/24 07:39
MSA
V47202
Iodomethane
<0.054
Ng/L
0.054
0.500
1
05/10/24 07:39
MSA
V47202
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
05/10/24 07:39
MSA
V47202
Methacrylonitrile
<10.0
Ng/L
10.0
10.0
1
05/15/2415:15
MSA
V47337
4-Methyl-2-Pentanone
<1.00
ug/L
1.00
5.00
1
05/10/24 07:39
MSA
V47202
Methylene Chloride
<0.330
Ng/L
0.330
1.00
1
05/10/24 07:39
MSA
V47202
Naphthalene
<0.470
ug/L
0.470
1.00
1
05/10/24 07:39
MSA
V47202
Propionitrile
<10.0
Ng/L
10.0
10.0
1
05/15/2415:15
MSA
V47337
Styrene
<0.220
ug/L
0.220
0.500
1
05/10/24 07:39
MSA
V47202
1,1,1,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
05/10/24 07:39
MSA
V47202
1,1,2,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
05/10/24 07:39
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 39 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92544
Matrix: Aqueous
Sample ID: MW-9
Sampled: 5/2/2024
11:00
Analytical Method: 8260D
Prep Batch(es):
V47200 05/09/24 14:00
V47336 05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Tetrachloroethene
<0.220
Ng/L
0.220 0.500
1
05/10/24 07:39 MSA
V47202
Tetrahydrofuran
9.543
ug/L
1.50 10.0
1
05/10/24 07:39 MSA
V47202
Toluene
<0.220
Ng/L
0.220 0.500
1
05/10/24 07:39 MSA
V47202
1,2,4-Trichlorobenzene
<0.310
ug/L
0.310 1.00
1
05/10/24 07:39 MSA
V47202
1,1,1-Trichloroethane
<0.160
Ng/L
0.160 0.500
1
05/10/24 07:39 MSA
V47202
1,1,2-Trichloroethane
<0.096
ug/L
0.096 0.500
1
05/10/24 07:39 MSA
V47202
Trichloroethene
<0.180
Ng/L
0.180 0.500
1
05/10/24 07:39 MSA
V47202
Trichlorofluoromethane
<0.180
ug/L
0.180 0.500
1
05/10/24 07:39 MSA
V47202
1,2,3-Trichloropropane
<0.270
Ng/L
0.270 1.00
1
05/10/24 07:39 MSA
V47202
Vinyl Acetate
<1.00 M
ug/L
1.00 2.00
1
05/10/24 07:39 MSA
V47202
Vinyl Chloride
26.0
Ng/L
0.170 0.500
1
05/10/24 07:39 MSA
V47202
o-Xylene
<0.210
ug/L
0.210 0.500
1
05/10/24 07:39 MSA
V47202
m,p-Xylene
<0.420
Ng/L
0.420 1.00
1
05/10/24 07:39 MSA
V47202
Xylene (Total)
<0.21
ug/L
0.210 0.500
1
05/10/24 07:39 KCC
V47202
Surrogate: 4-Bromofluorobenzene
101
Limits: 80-124%
1 05/10/24 07:39 MSA
V47202
Surrogate: Dibromofluoromethane
102
Limits: 75-129%
1 05/10/24 07:39 MSA
V47202
Surrogate: 1,2-Dichloroethane - d4
98.4
Limits: 63-136%
1 05/10/24 07:39 MSA
V47202
Surrogate: Toluene-d8
99.2
Limits: 77-123%
1 05/10/24 07:39 MSA
V47202
Surrogate:4-Bromofluorobenzene
101
Limits:80-124%
1 05/15/24 15:15 MSA
V47337
Surrogate: Dibromofluoromethane
104
Limits: 75-129%
1 05/15/24 15:15 MSA
V47337
Surrogate: 1,2-Dichloroethane - d4
105
Limits: 63-136%
1 05/15/24 15:15 MSA
V47337
Surrogate: Toluene-d8
107
Limits: 77-123%
1 05/15/24 15:15 MSA
V47337
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 40 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
01186
Smith & Gardner, Inc.
Project
Seth C. Rickerts
14 N. Boylan Avenue
Information
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Surry County C&D/MSW Spring
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Report Date : 05/31/2024
Received : 05/03/2024
Lab No : 92544 Matrix: Aqueous
Sample ID: MW-9 Sampled: 5/2/2024 11:00
Analytical Method: 8270C Prep Batch(es): L749277 05/08/24 12:10
Prep Method: 3510C
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Dimethoate
<0.720
Ng/L
0.720
1.01
1
05/08/24 19:45
SMB
L749502
Disulfoton
<0.470
ug/L
0.470
1.01
1
05/08/24 19:45
SMB
L749502
Ethyl Parathion
<0.573
Ng/L
0.573
1.01
1
05/08/24 19:45
SMB
L749502
Famphur
<0.517
ug/L
0.517
1.01
1
05/08/24 19:45
SMB
L749502
Methyl Parathion
<0.813
Ng/L
0.813
1.01
1
05/08/24 19:45
SMB
L749502
Phorate
<0.665
ug/L
0.665
1.01
1
05/08/24 19:45
SMB
L749502
Surrogate: Tributyl phosphate
78.7
Limits:
50-150%
1 05/08/24 19:45
SMB
8270C
Surrogate: Triphenyl phosphate
91.6
Limits:
50-150%
1 05/08/24 19:45
SMB
8270C
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,3-Dinitrobenzene
<0.904
ug/L
0.904
10.0
1
05/08/24 20:59
SMB
L749499
1,3,5-Trinitrobenzene
<10.1
Ng/L
10.1
10.1
1
05/08/24 20:59
SMB
L749501
Acenaphthene
<0.563
ug/L
0.563
2.00
1
05/08/24 20:59
SMB
L749499
Acenaphthylene
<0.562
Ng/L
0.562
2.00
1
05/08/24 20:59
SMB
L749499
Acetophenone
<0.689
ug/L
0.689
5.00
1
05/08/24 20:59
SMB
L749499
Anthracene
<0.536
Ng/L
0.536
2.00
1
05/08/24 20:59
SMB
L749499
Benzo(a)anthracene
<0.520
ug/L
0.520
2.00
1
05/08/24 20:59
SMB
L749499
Benzo(a)pyrene
<0.511
Ng/L
0.511
2.00
1
05/08/24 20:59
SMB
L749499
Benzo(b)fluoranthene
<0.631
ug/L
0.631
2.00
1
05/08/24 20:59
SMB
L749499
Benzo(g,h,i)perylene
<0.507
Ng/L
0.507
2.00
1
05/08/24 20:59
SMB
L749499
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 41 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92544
Matrix: Aqueous
Sample ID: MW-9
Sampled: 5/2/2024 11:00
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Benzo(k)fluoranthene
<0.575
Ng/L
0.575
2.00
1
05/08/24 20:59
SMB
L749499
Benzyl alcohol
<1.02
ug/L
1.02
10.0
1
05/08/24 20:59
SMB
L749499
Bis(2-Chloroethoxy)methane
<0.592
Ng/L
0.592
5.00
1
05/08/24 20:59
SMB
L749499
Bis(2-Chloroethyl)ether
<0.627
ug/L
0.627
5.00
1
05/08/24 20:59
SMB
L749499
Bis(2-Chloroisopropyl)ether
<0.656
Ng/L
0.656
5.00
1
05/08/24 20:59
SMB
L749499
Bis(2-ethylhexyl)phthalate
<0.796
ug/L
0.796
5.00
1
05/08/24 20:59
SMB
L749499
4-Bromophenyl phenyl ether
<0.567
Ng/L
0.567
5.00
1
05/08/24 20:59
SMB
L749499
Butyl benzyl phthalate
<0.756
ug/L
0.756
5.00
1
05/08/24 20:59
SMB
L749499
4-Chloro-3-methylphenol
<0.550
Ng/L
0.550
5.00
1
05/08/24 20:59
SMB
L749499
4-Chloroaniline
<0.530
ug/L
0.530
5.00
1
05/08/24 20:59
SMB
L749499
Chlorobenzilate
<0.999
Ng/L
0.999
5.00
1
05/08/24 20:59
SMB
L749499
2-Chloronaphthalene
<0.560
ug/L
0.560
5.00
1
05/08/24 20:59
SMB
L749499
2-Chlorophenol
<0.457
Ng/L
0.457
5.00
1
05/08/24 20:59
SMB
L749499
4-Chlorophenyl phenyl ether
<0.615
ug/L
0.615
5.00
1
05/08/24 20:59
SMB
L749499
Chrysene
<0.550
Ng/L
0.550
2.00
1
05/08/24 20:59
SMB
L749499
Dibenz(a,h)anthracene
<0.460
ug/L
0.460
2.00
1
05/08/24 20:59
SMB
L749499
Dibenzofuran
<0.584
Ng/L
0.584
5.00
1
05/08/24 20:59
SMB
L749499
1,2-Dichlorobenzene
1.81 J
ug/L
0.466
5.00
1
05/08/24 20:59
SMB
L749499
1,3-Dichlorobenzene
<0.436
Ng/L
0.436
5.00
1
05/08/24 20:59
SMB
L749499
1,4-Dichlorobenzene
4.33 J
ug/L
0.405
5.00
1
05/08/24 20:59
SMB
L749499
3,3'-Dichlorobenzidine
<10.3
Ng/L
10.3
20.0
1
05/08/24 20:59
SMB
L749499
2,4-Dichlorophenol
<0.606
ug/L
0.606
5.00
1
05/08/24 20:59
SMB
L749499
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 42 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92544
Matrix: Aqueous
Sample ID: MW-9
Sampled: 5/2/2024 11:00
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
2,6-Dichlorophenol
<0.655
Ng/L
0.655
5.00
1
05/08/24 20:59
SMB
L749499
Diethyl phthalate
1.493
ug/L
0.686
5.00
1
05/08/24 20:59
SMB
L749499
Dimethyl phthalate
<0.652
Ng/L
0.652
5.00
1
05/08/24 20:59
SMB
L749499
3,3' Dimethylbenzidine
<9.01
ug/L
9.01
10.0
1
05/08/24 20:59
SMB
L749499
2,4-Dimethyl phenol
<0.620
Ng/L
0.620
5.00
1
05/08/24 20:59
SMB
L749499
Di-n-butyl phthalate
<0.740
ug/L
0.740
5.00
1
05/08/24 20:59
SMB
L749499
4,6-Dinitro-2- methyl phenol
<6.08
Ng/L
6.08
10.0
1
05/08/24 20:59
SMB
L749499
2,4-Dinitrophenol
<18.9
ug/L
18.9
20.0
1
05/08/24 20:59
SMB
L749499
2,4-Dinitrotoluene
<0.911
Ng/L
0.911
5.00
1
05/08/24 20:59
SMB
L749499
2,6-Dinitrotoluene
<0.734
ug/L
0.734
5.00
1
05/08/24 20:59
SMB
L749499
Di-n-Octyl Phthalate
<1.32
Ng/L
1.32
5.00
1
05/08/24 20:59
SMB
L749499
Ethyl methanesulfonate
<0.660
ug/L
0.660
5.00
1
05/08/24 20:59
SMB
L749499
Fluoranthene
<0.583
Ng/L
0.583
2.00
1
05/08/24 20:59
SMB
L749499
Fluorene
<0.617
ug/L
0.617
2.00
1
05/08/24 20:59
SMB
L749499
Hexachlorobenzene
<0.537
Ng/L
0.537
5.00
1
05/08/24 20:59
SMB
L749499
Hexachlorobutadiene
<0.411
ug/L
0.411
5.00
1
05/08/24 20:59
SMB
L749499
Hexachlorocyclopentadiene
<0.889
Ng/L
0.889
5.00
1
05/08/24 20:59
SMB
L749499
Hexachloroethane
<0.482
ug/L
0.482
5.00
1
05/08/24 20:59
SMB
L749499
Indeno(1,2,3-cd)pyrene
<0.490
Ng/L
0.490
2.00
1
05/08/24 20:59
SMB
L749499
Isodrin
<10.1
ug/L
10.1
10.1
1
05/08/24 20:59
SMB
L749501
Isophorone
<0.591
Ng/L
0.591
5.00
1
05/08/24 20:59
SMB
L749499
Kepone
<10.1 M
ug/L
10.1
10.1
1
05/08/24 20:59
SMB
L749501
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 43 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92544
Matrix: Aqueous
Sample ID: MW-9
Sampled: 5/2/2024 11:00
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Methyl methanesulfonate
<0.746
Ng/L
0.746
5.00
1
05/08/24 20:59
SMB
L749499
2-Methylnaphthalene
<0.569
ug/L
0.569
2.00
1
05/08/24 20:59
SMB
L749499
2-Methylphenol
<0.449
Ng/L
0.449
5.00
1
05/08/24 20:59
SMB
L749499
3&4 Methylphenol
<0.453
ug/L
0.453
5.00
1
05/08/24 20:59
SMB
L749499
Naphthalene
<1.70
Ng/L
1.70
2.00
1
05/08/24 20:59
SMB
L749499
2-Nitroaniline
<0.766
ug/L
0.766
5.00
1
05/08/24 20:59
SMB
L749499
3-Nitroaniline
<0.912
Ng/L
0.912
10.0
1
05/08/24 20:59
SMB
L749499
4-Nitroaniline
<12.5
ug/L
12.5
20.0
1
05/08/24 20:59
SMB
L749499
Nitrobenzene
<0.715
Ng/L
0.715
5.00
1
05/08/24 20:59
SMB
L749499
2-Nitrophenol
<0.728
ug/L
0.728
5.00
1
05/08/24 20:59
SMB
L749499
4-Nitrophenol
<1.94
Ng/L
1.94
10.0
1
05/08/24 20:59
SMB
L749499
N-Nitrosodimethylamine
<0.295
ug/L
0.295
5.00
1
05/08/24 20:59
SMB
L749499
N-Nitrosodiphenylamine
<0.487
Ng/L
0.487
10.0
1
05/08/24 20:59
SMB
L749499
N-Nitrosodiethylamine
<0.535
ug/L
0.535
5.00
1
05/08/24 20:59
SMB
L749499
N-Nitroso-di-n-butylamine
<0.699
Ng/L
0.699
5.00
1
05/08/24 20:59
SMB
L749499
N-Nitroso-di-n-propylamine
<0.678
ug/L
0.678
5.00
1
05/08/24 20:59
SMB
L749499
Pentachlorobenzene
<0.574
Ng/L
0.574
10.0
1
05/08/24 20:59
SMB
L749499
Pentachloronitrobenzene
<0.569
ug/L
0.569
5.00
1
05/08/24 20:59
SMB
L749499
Pentachlorophenol
<1.23
Ng/L
1.23
10.0
1
05/08/24 20:59
SMB
L749499
Phenacetin
<0.693
ug/L
0.693
5.00
1
05/08/24 20:59
SMB
L749499
Phenanthrene
<0.582
Ng/L
0.582
2.00
1
05/08/24 20:59
SMB
L749499
Phenol
<0.258
ug/L
0.258
5.00
1
05/08/24 20:59
SMB
L749499
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 44 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
01186
Smith & Gardner, Inc.
Project
Seth C. Rickerts
14 N. Boylan Avenue
Information
Raleigh , NC 27603
Report Number : 24-124-0102
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Surry County C&D/MSW Spring
REPORT OF ANAL YSIS
Report Date : 05/31/2024
Received : 05/03/2024
Lab No : 92544 Matrix: Aqueous
Sample ID: MW-9 Sampled: 5/2/2024 11:00
Analytical Method: 8270D
Prep Method: 3510C
Test Results
Pyrene
<0.680
1,2,4,5-Tetrachlorobenzene
<0.463
2,3,4,6-Tetrachlorophenol
<0.570
1,2,4-Trichlorobenzene
<0.433
2,4,5-Trichlorophenol
<0.611
2,4,6-Trichlorophenol
<0.539
Surrogate: 2-Fluorobiphenyl
Surrogate: 2-Fluorophenol
Surrogate: Nitrobenzene-d5
Surrogate: Phenol-d6
Surrogate: 4-Terphenyl-d 14
Surrogate: 2,4,6-Tribromophenol
Prep Batch(es): L749275 05/08/24 12:10
Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.680 2.00
Pg/L
0.463 5.00
Ng/L
0.570 5.00
ug/L
0.433 5.00
Ng/L
0.611 5.00
Pg/L
0.539 5.00
59.1
Limits: 24-93%
31.3
Limits: 10-44%
52.7
Limits: 20-91%
21.9
Limits: 7-32%
64.2
Limits: 35-126%
70.3
Limits: 39-110%
1 05/08/24 20:59 SMB
L749499
1 05/08/24 20:59 SMB
L749499
1 05/08/24 20:59 SMB
L749499
1 05/08/24 20:59 SMB
L749499
1 05/08/24 20:59 SMB
L749499
1 05/08/24 20:59 SMB
L749499
1 05/08/24 20:59 SMB
L749499
1 05/08/24 20:59 SMB
L749499
1 05/08/24 20:59 SMB
L749499
1 05/08/24 20:59 SMB
L749499
1 05/08/24 20:59 SMB
L749499
1 05/08/24 20:59 SMB
L749499
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor H Beyond holding time
J Estimated value M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 45 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92545
Sample ID: SW-2
Matrix: Aqueous
Sampled: 5/2/2024 10:15
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
1,4-Dioxane
2.27
Ng/L
0.139
2.00
1
05/06/24 21:05
TBL
8260D SIM
Antimony
<0.618
ug/L
0.618
1.00
1
05/10/24 22:03
TJS
6020B
Arsenic
0.4393
Ng/L
0.297
1.00
1
05/10/24 22:03
TJS
6020E
Barium
26.7
ug/L
0.453
1.00
1
05/10/24 22:03
TJS
6020B
Beryllium
<0.102
Ng/L
0.102
1.00
1
05/10/24 22:03
TJS
6020E
Cadmium
<0.350
ug/L
0.350
1.00
1
05/10/24 22:03
TJS
6020B
Chromium
0.5603
Ng/L
0.346
1.00
1
05/10/24 22:03
TJS
6020E
Cobalt
31.2
ug/L
0.060
1.00
1
05/10/24 22:03
TJS
6020B
Copper
0.4893
Ng/L
0.489
1.00
1
05/10/24 22:03
TJS
6020E
Lead
<0.264
ug/L
0.264
1.00
1
05/10/24 22:03
TJS
6020B
Nickel
1.11
Ng/L
0.182
1.00
1
05/10/24 22:03
TJS
6020E
Selenium
<0.703
ug/L
0.703
1.00
1
05/10/24 22:03
TJS
6020B
Silver
<0.0570
Ng/L
0.0570
1.00
1
05/10/24 22:03
TJS
6020E
Thallium
<0.0610
ug/L
0.0610
1.00
1
05/10/24 22:03
TJS
6020B
Vanadium
1.50 JB
Ng/L
0.767
5.00
1
05/10/24 22:03
TJS
6020B
Zinc
5.11 J
ug/L
4.67
10.0
1
05/10/24 22:03
TJS
6020B
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor H Beyond holding time
J Estimated value M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 46 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92545
Matrix: Aqueous
Sample ID: SW-2
Sampled: 5/2/2024 10:15
Analytical Method: 8260D
Prep Batch(es):
V47200
05/09/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
2.903
Ng/L
1.80
5.00
1
05/10/24 08:04
MSA
V47202
Acrylonitrile
<0.230
ug/L
0.230
5.00
1
05/10/24 08:04
MSA
V47202
Benzene
<0.180
Ng/L
0.180
0.500
1
05/10/24 08:04
MSA
V47202
Bromochloromethane
<0.420
ug/L
0.420
1.00
1
05/10/24 08:04
MSA
V47202
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
05/10/24 08:04
MSA
V47202
Bromoform
<1.50
ug/L
1.50
5.00
1
05/10/24 08:04
MSA
V47202
Bromomethane
<0.280
Ng/L
0.280
1.00
1
05/10/24 08:04
MSA
V47202
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
05/10/24 08:04
MSA
V47202
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
05/10/24 08:04
MSA
V47202
Chlorobenzene
<0.190
ug/L
0.190
0.500
1
05/10/24 08:04
MSA
V47202
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
05/10/24 08:04
MSA
V47202
Chloroethane
<0.430
ug/L
0.430
1.00
1
05/10/24 08:04
MSA
V47202
Chloroform
<0.220
Ng/L
0.220
0.500
1
05/10/24 08:04
MSA
V47202
Chloromethane
<0.220
ug/L
0.220
0.500
1
05/10/24 08:04
MSA
V47202
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
05/10/24 08:04
MSA
V47202
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
05/10/24 08:04
MSA
V47202
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
05/10/24 08:04
MSA
V47202
Dibromomethane
<0.230
ug/L
0.230
0.500
1
05/10/24 08:04
MSA
V47202
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
05/10/24 08:04
MSA
V47202
1,2-Dichlorobenzene
<0.220
ug/L
0.220
0.500
1
05/10/24 08:04
MSA
V47202
1,4-Dichlorobenzene
0.2963
Ng/L
0.210
0.500
1
05/10/24 08:04
MSA
V47202
Dichlorodifluoromethane
<1.20
ug/L
1.20
5.00
1
05/10/24 08:04
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 47 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92545
Matrix: Aqueous
Sample ID: SW-2
Sampled: 5/2/2024 10:15
Analytical Method: 8260D
Prep Batch(es):
V47200
05/09/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
05/10/24 08:04
MSA
V47202
1,2-Dichloroethane
<0.150
ug/L
0.150
0.500
1
05/10/24 08:04
MSA
V47202
1,1-Dichloroethene
<0.150
Ng/L
0.150
0.500
1
05/10/24 08:04
MSA
V47202
cis- 1,2-Dich loroethene
2.47
ug/L
0.200
0.500
1
05/10/24 08:04
MSA
V47202
trans-1,2-Dichloroethene
<0.180
Ng/L
0.180
0.500
1
05/10/24 08:04
MSA
V47202
1,2-Dichloropropane
<0.190
ug/L
0.190
0.500
1
05/10/24 08:04
MSA
V47202
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
05/10/24 08:04
MSA
V47202
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
05/10/24 08:04
MSA
V47202
1,4-Dioxane
<16.0
Ng/L
16.0
150
1
05/10/24 08:04
MSA
V47202
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
05/10/24 08:04
MSA
V47202
2-Hexanone
<0.380
Ng/L
0.380
5.00
1
05/10/24 08:04
MSA
V47202
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
05/10/24 08:04
MSA
V47202
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
05/10/24 08:04
MSA
V47202
Methylene Chloride
<0.330
ug/L
0.330
1.00
1
05/10/24 08:04
MSA
V47202
Styrene
<0.220
Ng/L
0.220
0.500
1
05/10/24 08:04
MSA
V47202
1,1,1,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
05/10/24 08:04
MSA
V47202
1,1,2,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
05/10/24 08:04
MSA
V47202
Tetrachloroethene
<0.220
ug/L
0.220
0.500
1
05/10/24 08:04
MSA
V47202
Tetrahydrofuran
<1.50
Ng/L
1.50
10.0
1
05/10/24 08:04
MSA
V47202
Toluene
<0.220
ug/L
0.220
0.500
1
05/10/24 08:04
MSA
V47202
1,1,1-Trichloroethane
<0.160
Ng/L
0.160
0.500
1
05/10/24 08:04
MSA
V47202
1,1,2-Trichloroethane
<0.096
ug/L
0.096
0.500
1
05/10/24 08:04
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 48 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
01186
Smith & Gardner, Inc.
Project
Seth C. Rickerts
14 N. Boylan Avenue
Information
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Surry County C&D/MSW Spring
Report Date : 05/31/2024
Received : 05/03/2024
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92545 Matrix: Aqueous
Sample ID: SW-2 Sampled: 5/2/2024 10:15
Analytical Method: 8260D
Prep Method: 5030E
Test Results
Trichloroethene
<0.180
Trichlorofluoromethane
<0.180
1,2,3-Trichloropropane
<0.270
Vinyl Acetate
<1.00 M
Vinyl Chloride
0.776
o-Xylene
<0.210
m,p-Xylene
<0.420
Xylene (Total)
<0.21
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Prep Batch(es): V47200 05/09/24 14:00
Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.180 0.500
Pg/L
0.180 0.500
Ng/L
0.270 1.00
Pg/L
1.00 2.00
Ng/L
0.170 0.500
Pg/L
0.210 0.500
Ng/L
0.420 1.00
Pg/L
0.210 0.500
101
Limits: 80-124%
102
Limits: 75-129%
100
Limits: 63-136%
99.6
Limits: 77-123%
1 05/10/24 08:04 MSA V47202
1 05/10/24 08:04 MSA V47202
1 05/10/24 08:04 MSA V47202
1 05/10/24 08:04 MSA V47202
1 05/10/24 08:04 MSA V47202
1 05/10/24 08:04 MSA V47202
1 05/10/24 08:04 MSA V47202
1 05/10/24 08:04 KCC V47202
1 05/10/24 08:04 MSA V47202
1 05/10/24 08:04 MSA V47202
1 05/10/24 08:04 MSA V47202
1 05/10/24 08:04 MSA V47202
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor H Beyond holding time
J Estimated value M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 49 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102
REPOR T OF A NA L YSIS
Lab No : 92546
Matrix: Aqueous
Sample ID: MW-1
Sampled: 5/2/2024 12:30
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Sulfate
10900
Ng/L
600
2000
1
05/03/2416:53
NDL
9056A
Ferrous Iron
<0.05 H
mg/L
0.05
0.20
1
05/03/24 13:40
GOB
SM-3500-Fe-B
Ethane
<2.67
Ng/L
2.67
10.0
1
05/06/24 13:38
TBL
RSK-175
Ethene
<2.28
ug/L
2.28
10.0
1
05/06/24 13:38
TBL
RSK-175
Hydrogen
<10.0
Ng/L
10.0
1
05/14/24 14:47
ADO
RSK-175
Methane
<2.51
ug/L
2.51
10.0
1
05/06/24 13:38
TBL
RSK-175
1,4-Dioxane
<0.139
Ng/L
0.139
2.00
1
05/06/24 21:30
TBL
8260D SIM
1,4-Naphthoquinone
<10.1 M
ug/L
10.1
10.1
1
05/08/24 21:20
SMB
8270D
1-Naphthylamine
<10.1
Ng/L
10.1
10.1
1
05/08/24 21:20
SMB
8270D
2-Acetylaminofluorene
<10.1
ug/L
10.1
10.1
1
05/08/24 21:20
SMB
8270D
2-Naphthylamine
<10.1
Ng/L
10.1
10.1
1
05/08/24 21:20
SMB
8270D
3-Methylcholanthrene
<10.1
ug/L
10.1
10.1
1
05/08/24 21:20
SMB
8270D
4-Aminobiphenyl
<10.1
Ng/L
10.1
10.1
1
05/08/24 21:20
SMB
8270D
5-Nitro-o-toluidine
<10.1
ug/L
10.1
10.1
1
05/08/24 21:20
SMB
8270D
7,12-Dimethyl benz(a)anth racene <10.1
Ng/L
10.1
10.1
1
05/08/24 21:20
SMB
8270D
Diallate
<10.1
ug/L
10.1
10.1
1
05/08/24 21:20
SMB
8270D
Hexachloropropene
<10.1
Ng/L
10.1
10.1
1
05/08/24 21:20
SMB
8270D
Isosafrole
<10.1
ug/L
10.1
10.1
1
05/08/24 21:20
SMB
8270D
Methapyrilene
<10.1
Ng/L
10.1
20.2
1
05/08/24 21:20
SMB
8270D
N-Nitrosomethylethylamine
<10.1
ug/L
10.1
10.1
1
05/08/24 21:20
SMB
8270D
N-Nitrosomorpholine
<10.1
Ng/L
10.1
10.1
1
05/08/24 21:20
SMB
8270D
N-Nitrosopyrrolidine
<10.1
ug/L
10.1
10.1
1
05/08/24 21:20
SMB
8270D
N-Nitrosopiperidine
<10.1
Ng/L
10.1
10.1
1
05/08/24 21:20
SMB
8270D
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum
value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 50 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102
REPOR T OF A NA L YSIS
Lab No : 92546
Matrix: Aqueous
Sample ID: MW-1
Sampled: 5/2/2024 12:30
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
0,0,0-Triethyl Phosphorothioate
<0.333
Ng/L
0.333
1.01
1
05/08/24 19:59
SMB
8270C
o-Toluidine
<10.1
ug/L
10.1
10.1
1
05/08/24 21:20
SMB
8270D
p-Dimethylaminoazobenzene
<10.1
Ng/L
10.1
10.1
1
05/08/24 21:20
SMB
8270D
p-Phenylenediamine
<10.1 M
ug/L
10.1
10.1
1
05/08/24 21:20
SMB
8270D
Pronamide
<10.1
Ng/L
10.1
10.1
1
05/08/24 21:20
SMB
8270D
Safrole
<10.1
ug/L
10.1
10.1
1
05/08/24 21:20
SMB
8270D
Thionazine
<0.333
Ng/L
0.333
1.01
1
05/08/2419:59
SMB
8270C
Alkalinity (as CaCO3)
26000
u9/L
800
5000
1
05/08/24 15:40
RLW
2320B-2011
Biochemical Oxygen Demand (5-day)
<2000
N9/L
2000
2000
1
05/03/24 10:39
MLW
521OB-2015
Chloride
3010
u9/L
500
1000
1
05/03/2416:53
NDL
9056A
Cyanide, Total
<12.0
Ng/L
12.0
25.0
1
05/14/24 14:05
RLW
9014
COD (Chemical Oxygen Demand)
16000 J
u9/L
15000
30000
1
05/09/24 11:25
SLO
5220D-2011
Nitrate (NO3-N)
1130
N9/L
50.0
100
1
05/03/24 16:53
NDL
9056A
TOC
1040
u9/L
720
1000
1
05/09/24 03:16
AT
531OC-2011
Sulfide
<830
N9/L
830
2000
1
05/06/2414:53
GOB
4500S2F-2011
Antimony
<0.618
u9/L
0.618
1.00
1
05/10/24 22:06
TJS
6020B
Arsenic
0.552 J
N9/L
0.297
1.00
1
05/10/24 22:06
TJS
6020B
Barium
57.0
u9/L
0.453
1.00
1
05/10/24 22:06
TJS
6020B
Beryllium
<0.102
N9/L
0.102
1.00
1
05/10/24 22:06
TJS
6020B
Cadmium
<0.350
u9/L
0.350
1.00
1
05/10/24 22:06
TJS
6020B
Chromium
0.748 J
N9/L
0.346
1.00
1
05/10/24 22:06
TJS
6020B
Cobalt
1.71
u9/L
0.060
1.00
1
05/10/24 22:06
TJS
6020B
Copper
1.24
N9/L
0.489
1.00
1
05/10/24 22:06
TJS
6020B
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum
value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 51 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92546
Sample ID: MW-1
Matrix: Aqueous
Sampled: 5/2/2024 12:30
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Lead
<0.264
Ng/L
0.264
1.00
1
05/10/24 22:06
TJS
6020E
Mercury (Total)
<0.100
ug/L
0.100
0.200
1
05/13/24 14:50
FDS
7470A
Nickel
1.90
Ng/L
0.182
1.00
1
05/10/24 22:06
TJS
6020E
Selenium
<0.703
ug/L
0.703
1.00
1
05/10/24 22:06
TJS
6020B
Silver
<0.0570
Ng/L
0.0570
1.00
1
05/10/24 22:06
TJS
6020E
Tin
<1.44
ug/L
1.44
5.00
1
05/13/2416:48
TJS
6020B
Thallium
<0.0610
Ng/L
0.0610
1.00
1
05/10/24 22:06
TJS
6020B
Vanadium
2.64 JB
ug/L
0.767
5.00
1
05/10/24 22:06
TJS
6020B
Zinc
10.8
Ng/L
4.67
10.0
1
05/10/24 22:06
TJS
6020B
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor H Beyond holding time
J Estimated value M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 52 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92546
Matrix: Aqueous
Sample ID: MW-1
Sampled: 5/2/2024 12:30
Analytical Method:
8081B
Prep Batch(es):
V46914
05/07/24 10:07
Prep Method:
3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Aldrin
<0.0152
Ng/L
0.0152
0.0500
1
05/16/24 01:14
TJW
V47319
alpha-BHC
<0.0063
ug/L
0.0063
0.0500
1
05/16/24 01:14
TJW
V47319
beta-BHC
<0.0111
Ng/L
0.0111
0.0500
1
05/16/24 01:14
TJW
V47319
delta-BHC
<0.0082
ug/L
0.0082
0.0500
1
05/16/24 01:14
TJW
V47319
Chlordane
<0.180
Ng/L
0.180
0.500
1
05/16/24 01:14
TJW
V47319
alpha -Chlordane
<0.0186
ug/L
0.0186
0.100
1
05/16/24 01:14
TJW
V47319
gamma -Chlordane
<0.0231
Ng/L
0.0231
0.100
1
05/16/24 01:14
TJW
V47319
4,4'-DDD
<0.0265
ug/L
0.0265
0.100
1
05/16/24 01:14
TJW
V47319
4,4'-DDE
<0.0218
Ng/L
0.0218
0.100
1
05/16/24 01:14
TJW
V47319
4,4'-DDT
<0.0176
ug/L
0.0176
0.100
1
05/16/24 01:14
TJW
V47319
Dieldrin
<0.0137
Ng/L
0.0137
0.0500
1
05/16/24 01:14
TJW
V47319
EndosulfanI
<0.0160
ug/L
0.0160
0.0500
1
05/16/24 01:14
TJW
V47319
Endosulfan II
<0.0121
Ng/L
0.0121
0.0500
1
05/16/24 01:14
TJW
V47319
Endosulfan Sulfate
<0.0165
ug/L
0.0165
0.0500
1
05/16/24 01:14
TJW
V47319
Endrin
<0.0136
Ng/L
0.0136
0.0500
1
05/16/24 01:14
TJW
V47319
Endrin Aldehyde
<0.0158
ug/L
0.0158
0.0500
1
05/16/24 01:14
TJW
V47319
Endrin Ketone
<0.0181
Ng/L
0.0181
0.100
1
05/16/24 01:14
TJW
V47319
gamma-BHC
<0.0061
ug/L
0.0061
0.0500
1
05/16/24 01:14
TJW
V47319
Heptachlor
<0.0130
Ng/L
0.0130
0.0500
1
05/16/24 01:14
TJW
V47319
Heptachlor Epoxide
<0.0224
ug/L
0.0224
0.100
1
05/16/24 01:14
TJW
V47319
Methoxychlor
<0.0179
Ng/L
0.0179
0.100
1
05/16/24 01:14
TJW
V47319
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 53 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102
REPOR T OF A NA L YSIS
Lab No : 92546
Matrix: Aqueous
Sample ID: MW-1
Sampled: 5/2/2024
12:30
Analytical Method: 8081B
Prep Batch(es):
V46914
05/07/24 10:07
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF Date / Time By
Analytical
Analyzed
Batch
Toxaphene
<0.350
Ng/L
0.350
1.00
1 05/16/24 01:14 TJW
V47319
Surrogate: Decachlorobiphenyl
89.2
Limits:
13-186%
1 05/16/24 01:14 TJW
V47319
Surrogate: Tetrachloro-m-xylene
107
Limits:
40-134%
1 05/16/24 01:14 TJW
V47319
Analytical Method: 8082A
Prep Batch(es):
V46915
05/07/24 10:07
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF Date / Time By
Analytical
Analyzed
Batch
Aroclor 1016
<0.210
ug/L
0.210
0.500
1 05/16/24 18:31 TJW
V47358
Aroclor1221
<0.110
Ng/L
0.110
1.00
1 05/16/24 18:31 TJW
V47358
Aroclor1232
<0.160
ug/L
0.160
0.500
1 05/16/24 18:31 TJW
V47358
Aroclor1242
<0.140
Ng/L
0.140
0.500
1 05/16/24 18:31 TJW
V47358
Aroclor1248
<0.140
ug/L
0.140
0.500
1 05/16/24 18:31 TJW
V47358
Aroclor1254
<0.160
Ng/L
0.160
0.500
1 05/16/24 18:31 TJW
V47358
Aroclor 1260
<0.495
ug/L
0.495
1.00
1 05/16/24 18:31 TJW
V47358
Surrogate: Decachlorobiphenyl
98.3
Limits:
32-178%
1 05/16/24 18:31 TJW
8082A
Surrogate: Tetrachloro-m-xylene
79.7
Limits:
30-161%
1 05/16/24 18:31 TJW
8082A
Analytical Method: 8151A
Prep Batch(es):
L749619
05/09/24 13:10
Prep Method: 8151A
Test
Results
Units
MDL
MQL
DF Date / Time By
Analytical
Analyzed
Batch
2,4-D
<0.2078
ug/L
0.2078
0.2500
1 05/14/24 23:17 SWB
L750458
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 54 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92546
Matrix: Aqueous
Sample ID: MW-1
Sampled: 5/2/2024
12:30
Analytical Method:
8151A
Prep Batch(es):
L749619
05/09/24 13:10
Prep Method:
8151A
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Dalapon
<0.5149
Ng/L
0.5149
0.5500
1
05/14/24 23:17
SWB
L750458
2,4-DB
<0.1364
ug/L
0.1364
0.2500
1
05/14/24 23:17
SWB
L750458
Dicamba
<0.05700
Ng/L
0.05700
0.1000
1
05/14/24 23:17
SWB
L750458
Dichlorprop
<0.07959
ug/L
0.07959
0.1000
1
05/14/24 23:17
SWB
L750458
Dinoseb
<0.02698
Ng/L
0.02698
0.1000
1
05/14/24 23:17
SWB
L750458
MCPA
<18.98
ug/L
18.98
50.00
1
05/14/24 23:17
SWB
L750458
MCPP
<11.75
Ng/L
11.75
50.00
1
05/14/24 23:17
SWB
L750458
Picloram
<0.04528
ug/L
0.04528
0.1000
1
05/14/24 23:17
SWB
L750458
2,4,5-T
<0.1002
Ng/L
0.1002
0.1250
1
05/14/24 23:17
SWB
L750458
2,4,5-TP (Silvex)
<0.01634
ug/L
0.01634
0.1000
1
05/14/24 23:17
SWB
L750458
Surrogate: DCAA
142.3
Limits:
20-150%
1 05/14/24 23:17 SWB
L750458
Analytical Method:
8260D
Prep Batch(es):
V47200
05/09/24 14:00
V47336
05/14/24 14:00
Prep Method:
5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
2.443
ug/L
1.80
5.00
1
05/10/24 08:29
MSA
V47202
Acetonitrile
<10.0
Ng/L
10.0
10.0
1
05/15/2415:40
MSA
V47337
Acrolein
<2.00
ug/L
2.00
5.00
1
05/10/24 08:29
MSA
V47202
Acrylonitrile
<0.230
Ng/L
0.230
5.00
1
05/10/24 08:29
MSA
V47202
Allyl Chloride
<0.579
ug/L
0.579
10.0
1
05/15/24 15:40
MSA
V47337
Benzene
<0.180
Ng/L
0.180
0.500
1
05/10/24 08:29
MSA
V47202
Bromochloromethane
<0.420
ug/L
0.420
1.00
1
05/10/24 08:29
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 55 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92546
Matrix: Aqueous
Sample ID: MW-1
Sampled: 5/2/2024 12:30
Analytical Method: 8260D
Prep Batch(es):
V47200
05/09/24 14:00
V47336
05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
05/10/24 08:29
MSA
V47202
Bromoform
<1.50
ug/L
1.50
5.00
1
05/10/24 08:29
MSA
V47202
Bromomethane
<0.280
Ng/L
0.280
1.00
1
05/10/24 08:29
MSA
V47202
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
05/10/24 08:29
MSA
V47202
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
05/10/24 08:29
MSA
V47202
Chlorobenzene
<0.190
ug/L
0.190
0.500
1
05/10/24 08:29
MSA
V47202
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
05/10/24 08:29
MSA
V47202
Chloroethane
<0.430
ug/L
0.430
1.00
1
05/10/24 08:29
MSA
V47202
Chloroform
<0.220
Ng/L
0.220
0.500
1
05/10/24 08:29
MSA
V47202
Chloromethane
<0.220
ug/L
0.220
0.500
1
05/10/24 08:29
MSA
V47202
Chloroprene
<0.450
Ng/L
0.450
10.0
1
05/15/24 15:40
MSA
V47337
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
05/10/24 08:29
MSA
V47202
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
05/10/24 08:29
MSA
V47202
Dibromomethane
<0.230
ug/L
0.230
0.500
1
05/10/24 08:29
MSA
V47202
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
05/10/24 08:29
MSA
V47202
1,2-Dichlorobenzene
<0.220
ug/L
0.220
0.500
1
05/10/24 08:29
MSA
V47202
1,3-Dichlorobenzene
<0.190
Ng/L
0.190
0.500
1
05/10/24 08:29
MSA
V47202
1,4-Dichlorobenzene
<0.210
ug/L
0.210
0.500
1
05/10/24 08:29
MSA
V47202
Dichlorodifluoromethane
<1.20
Ng/L
1.20
5.00
1
05/10/24 08:29
MSA
V47202
1,1-Dichloroethane
<0.240
ug/L
0.240
0.500
1
05/10/24 08:29
MSA
V47202
1,2-Dichloroethane
<0.150
Ng/L
0.150
0.500
1
05/10/24 08:29
MSA
V47202
1,1-Dichloroethene
<0.150
ug/L
0.150
0.500
1
05/10/24 08:29
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 56 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92546
Matrix: Aqueous
Sample ID: MW-1
Sampled: 5/2/2024 12:30
Analytical Method: 8260D
Prep Batch(es):
V47200
05/09/24 14:00
V47336
05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
cis- 1,2-Dich loroethene
<0.200
Ng/L
0.200
0.500
1
05/10/24 08:29
MSA
V47202
trans- 1.2-Dichloroethene
<0.180
ug/L
0.180
0.500
1
05/10/24 08:29
MSA
V47202
1,2-Dichloropropane
<0.190
Ng/L
0.190
0.500
1
05/10/24 08:29
MSA
V47202
1,3-Dichloropropane
<0.130
ug/L
0.130
0.500
1
05/10/24 08:29
MSA
V47202
2,2-Dichloropropane
<0.210
Ng/L
0.210
2.00
1
05/10/24 08:29
MSA
V47202
1,1-Dichloropropene
<0.200
ug/L
0.200
0.500
1
05/10/24 08:29
MSA
V47202
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
05/10/24 08:29
MSA
V47202
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
05/10/24 08:29
MSA
V47202
Ethyl Methacrylate
<1.62
Ng/L
1.62
10.0
1
05/15/24 15:40
MSA
V47337
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
05/10/24 08:29
MSA
V47202
Hexachlorobutadiene
<0.350
Ng/L
0.350
2.00
1
05/10/24 08:29
MSA
V47202
2-Hexanone
<0.380
ug/L
0.380
5.00
1
05/10/24 08:29
MSA
V47202
Iodomethane
<0.054
Ng/L
0.054
0.500
1
05/10/24 08:29
MSA
V47202
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
05/10/24 08:29
MSA
V47202
Methacrylonitrile
<10.0
Ng/L
10.0
10.0
1
05/15/2415:40
MSA
V47337
4-Methyl-2-Pentanone
<1.00
ug/L
1.00
5.00
1
05/10/24 08:29
MSA
V47202
Methylene Chloride
<0.330
Ng/L
0.330
1.00
1
05/10/24 08:29
MSA
V47202
Naphthalene
<0.470
ug/L
0.470
1.00
1
05/10/24 08:29
MSA
V47202
Propionitrile
<10.0
Ng/L
10.0
10.0
1
05/15/2415:40
MSA
V47337
Styrene
<0.220
ug/L
0.220
0.500
1
05/10/24 08:29
MSA
V47202
1,1,1,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
05/10/24 08:29
MSA
V47202
1,1,2,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
05/10/24 08:29
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 57 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92546
Matrix: Aqueous
Sample ID: MW-1
Sampled: 5/2/2024
12:30
Analytical Method: 8260D
Prep Batch(es):
V47200 05/09/24 14:00
V47336 05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Tetrachloroethene
<0.220
Ng/L
0.220 0.500
1
05/10/24 08:29 MSA
V47202
Tetrahydrofuran
24.0
ug/L
1.50 10.0
1
05/10/24 08:29 MSA
V47202
Toluene
<0.220
Ng/L
0.220 0.500
1
05/10/24 08:29 MSA
V47202
1,2,4-Trichlorobenzene
<0.310
ug/L
0.310 1.00
1
05/10/24 08:29 MSA
V47202
1,1,1-Trichloroethane
<0.160
Ng/L
0.160 0.500
1
05/10/24 08:29 MSA
V47202
1,1,2-Trichloroethane
<0.096
ug/L
0.096 0.500
1
05/10/24 08:29 MSA
V47202
Trichloroethene
<0.180
Ng/L
0.180 0.500
1
05/10/24 08:29 MSA
V47202
Trichlorofluoromethane
<0.180
ug/L
0.180 0.500
1
05/10/24 08:29 MSA
V47202
1,2,3-Trichloropropane
<0.270
Ng/L
0.270 1.00
1
05/10/24 08:29 MSA
V47202
Vinyl Acetate
<1.00 M
ug/L
1.00 2.00
1
05/10/24 08:29 MSA
V47202
Vinyl Chloride
<0.170
Ng/L
0.170 0.500
1
05/10/24 08:29 MSA
V47202
o-Xylene
<0.210
ug/L
0.210 0.500
1
05/10/24 08:29 MSA
V47202
m,p-Xylene
<0.420
Ng/L
0.420 1.00
1
05/10/24 08:29 MSA
V47202
Xylene (Total)
<0.21
ug/L
0.210 0.500
1
05/10/24 08:29 KCC
V47202
Surrogate: 4-Bromofluorobenzene
101
Limits: 80-124%
1 05/10/24 08:29 MSA
V47202
Surrogate: Dibromofluoromethane
101
Limits: 75-129%
1 05/10/24 08:29 MSA
V47202
Surrogate: 1,2-Dichloroethane - d4
99.8
Limits: 63-136%
1 05/10/24 08:29 MSA
V47202
Surrogate: Toluene-d8
101
Limits: 77-123%
1 05/10/24 08:29 MSA
V47202
Surrogate:4-Bromofluorobenzene
101
Limits:80-124%
1 05/15/24 15:40 MSA
V47337
Surrogate: Dibromofluoromethane
103
Limits: 75-129%
1 05/15/24 15:40 MSA
V47337
Surrogate: 1,2-Dichloroethane - d4
106
Limits: 63-136%
1 05/15/24 15:40 MSA
V47337
Surrogate: Toluene-d8
107
Limits: 77-123%
1 05/15/24 15:40 MSA
V47337
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 58 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
01186
Smith & Gardner, Inc.
Project
Seth C. Rickerts
14 N. Boylan Avenue
Information
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Surry County C&D/MSW Spring
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Report Date : 05/31/2024
Received : 05/03/2024
Lab No : 92546 Matrix: Aqueous
Sample ID: MW-1 Sampled: 5/2/2024 12:30
Analytical Method: 8270C Prep Batch(es): L749277 05/08/24 12:10
Prep Method: 3510C
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Dimethoate
<0.720
Ng/L
0.720
1.01
1
05/08/24 19:59
SMB
L749502
Disulfoton
<0.470
ug/L
0.470
1.01
1
05/08/24 19:59
SMB
L749502
Ethyl Parathion
<0.573
Ng/L
0.573
1.01
1
05/08/24 19:59
SMB
L749502
Famphur
<0.517
ug/L
0.517
1.01
1
05/08/24 19:59
SMB
L749502
Methyl Parathion
<0.813
Ng/L
0.813
1.01
1
05/08/24 19:59
SMB
L749502
Phorate
<0.665
ug/L
0.665
1.01
1
05/08/24 19:59
SMB
L749502
Surrogate: Tributyl phosphate
82.2
Limits:
50-150%
1 05/08/24 19:59 SMB
8270C
Surrogate: Triphenyl phosphate
98.0
Limits:
50-150%
1 05/08/24 19:59 SMB
8270C
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,3-Dinitrobenzene
<0.904
ug/L
0.904
10.0
1
05/08/24 21:20
SMB
L749499
1,3,5-Trinitrobenzene
<10.1
Ng/L
10.1
10.1
1
05/08/24 21:20
SMB
L749501
Acenaphthene
<0.563
ug/L
0.563
2.00
1
05/08/24 21:20
SMB
L749499
Acenaphthylene
<0.562
Ng/L
0.562
2.00
1
05/08/24 21:20
SMB
L749499
Acetophenone
<0.689
ug/L
0.689
5.00
1
05/08/24 21:20
SMB
L749499
Anthracene
<0.536
Ng/L
0.536
2.00
1
05/08/24 21:20
SMB
L749499
Benzo(a)anthracene
<0.520
ug/L
0.520
2.00
1
05/08/24 21:20
SMB
L749499
Benzo(a)pyrene
<0.511
Ng/L
0.511
2.00
1
05/08/24 21:20
SMB
L749499
Benzo(b)fluoranthene
<0.631
ug/L
0.631
2.00
1
05/08/24 21:20
SMB
L749499
Benzo(g,h,i)perylene
<0.507
Ng/L
0.507
2.00
1
05/08/24 21:20
SMB
L749499
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 59 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92546
Matrix: Aqueous
Sample ID: MW-1
Sampled: 5/2/2024 12:30
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Benzo(k)fluoranthene
<0.575
Ng/L
0.575
2.00
1
05/08/24 21:20
SMB
L749499
Benzyl alcohol
<1.02
ug/L
1.02
10.0
1
05/08/24 21:20
SMB
L749499
Bis(2-Chloroethoxy)methane
<0.592
Ng/L
0.592
5.00
1
05/08/24 21:20
SMB
L749499
Bis(2-Chloroethyl)ether
<0.627
ug/L
0.627
5.00
1
05/08/24 21:20
SMB
L749499
Bis(2-Chloroisopropyl)ether
<0.656
Ng/L
0.656
5.00
1
05/08/24 21:20
SMB
L749499
Bis(2-ethylhexyl)phthalate
<0.796
ug/L
0.796
5.00
1
05/08/24 21:20
SMB
L749499
4-Bromophenyl phenyl ether
<0.567
Ng/L
0.567
5.00
1
05/08/24 21:20
SMB
L749499
Butyl benzyl phthalate
<0.756
ug/L
0.756
5.00
1
05/08/24 21:20
SMB
L749499
4-Chloro-3-methylphenol
<0.550
Ng/L
0.550
5.00
1
05/08/24 21:20
SMB
L749499
4-Chloroaniline
<0.530
ug/L
0.530
5.00
1
05/08/24 21:20
SMB
L749499
Chlorobenzilate
<0.999
Ng/L
0.999
5.00
1
05/08/24 21:20
SMB
L749499
2-Chloronaphthalene
<0.560
ug/L
0.560
5.00
1
05/08/24 21:20
SMB
L749499
2-Chlorophenol
<0.457
Ng/L
0.457
5.00
1
05/08/24 21:20
SMB
L749499
4-Chlorophenyl phenyl ether
<0.615
ug/L
0.615
5.00
1
05/08/24 21:20
SMB
L749499
Chrysene
<0.550
Ng/L
0.550
2.00
1
05/08/24 21:20
SMB
L749499
Dibenz(a,h)anthracene
<0.460
ug/L
0.460
2.00
1
05/08/24 21:20
SMB
L749499
Dibenzofuran
<0.584
Ng/L
0.584
5.00
1
05/08/24 21:20
SMB
L749499
1,2-Dichlorobenzene
<0.466
ug/L
0.466
5.00
1
05/08/24 21:20
SMB
L749499
1,3-Dichlorobenzene
<0.436
Ng/L
0.436
5.00
1
05/08/24 21:20
SMB
L749499
1,4-Dichlorobenzene
<0.405
ug/L
0.405
5.00
1
05/08/24 21:20
SMB
L749499
3,3'-Dichlorobenzidine
<10.3
Ng/L
10.3
20.0
1
05/08/24 21:20
SMB
L749499
2,4-Dichlorophenol
<0.606
ug/L
0.606
5.00
1
05/08/24 21:20
SMB
L749499
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 60 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92546
Matrix: Aqueous
Sample ID: MW-1
Sampled: 5/2/2024 12:30
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
2,6-Dichlorophenol
<0.655
Ng/L
0.655
5.00
1
05/08/24 21:20
SMB
L749499
Diethyl phthalate
<0.686
ug/L
0.686
5.00
1
05/08/24 21:20
SMB
L749499
Dimethyl phthalate
<0.652
Ng/L
0.652
5.00
1
05/08/24 21:20
SMB
L749499
3,3' Dimethylbenzidine
<9.01
ug/L
9.01
10.0
1
05/08/24 21:20
SMB
L749499
2,4-Dimethyl phenol
<0.620
Ng/L
0.620
5.00
1
05/08/24 21:20
SMB
L749499
Di-n-butyl phthalate
<0.740
ug/L
0.740
5.00
1
05/08/24 21:20
SMB
L749499
4,6-Dinitro-2- methyl phenol
<6.08
Ng/L
6.08
10.0
1
05/08/24 21:20
SMB
L749499
2,4-Dinitrophenol
<18.9
ug/L
18.9
20.0
1
05/08/24 21:20
SMB
L749499
2,4-Dinitrotoluene
<0.911
Ng/L
0.911
5.00
1
05/08/24 21:20
SMB
L749499
2,6-Dinitrotoluene
<0.734
ug/L
0.734
5.00
1
05/08/24 21:20
SMB
L749499
Di-n-Octyl Phthalate
<1.32
Ng/L
1.32
5.00
1
05/08/24 21:20
SMB
L749499
Ethyl methanesulfonate
<0.660
ug/L
0.660
5.00
1
05/08/24 21:20
SMB
L749499
Fluoranthene
<0.583
Ng/L
0.583
2.00
1
05/08/24 21:20
SMB
L749499
Fluorene
<0.617
ug/L
0.617
2.00
1
05/08/24 21:20
SMB
L749499
Hexachlorobenzene
<0.537
Ng/L
0.537
5.00
1
05/08/24 21:20
SMB
L749499
Hexachlorobutadiene
<0.411
ug/L
0.411
5.00
1
05/08/24 21:20
SMB
L749499
Hexachlorocyclopentadiene
<0.889
Ng/L
0.889
5.00
1
05/08/24 21:20
SMB
L749499
Hexachloroethane
<0.482
ug/L
0.482
5.00
1
05/08/24 21:20
SMB
L749499
Indeno(1,2,3-cd)pyrene
<0.490
Ng/L
0.490
2.00
1
05/08/24 21:20
SMB
L749499
Isodrin
<10.1
ug/L
10.1
10.1
1
05/08/24 21:20
SMB
L749501
Isophorone
<0.591
Ng/L
0.591
5.00
1
05/08/24 21:20
SMB
L749499
Kepone
<10.1 M
ug/L
10.1
10.1
1
05/08/24 21:20
SMB
L749501
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 61 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92546
Matrix: Aqueous
Sample ID: MW-1
Sampled: 5/2/2024 12:30
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Methyl methanesulfonate
<0.746
Ng/L
0.746
5.00
1
05/08/24 21:20
SMB
L749499
2-Methylnaphthalene
<0.569
ug/L
0.569
2.00
1
05/08/24 21:20
SMB
L749499
2-Methylphenol
<0.449
Ng/L
0.449
5.00
1
05/08/24 21:20
SMB
L749499
3&4 Methylphenol
<0.453
ug/L
0.453
5.00
1
05/08/24 21:20
SMB
L749499
Naphthalene
<1.70
Ng/L
1.70
2.00
1
05/08/24 21:20
SMB
L749499
2-Nitroaniline
<0.766
ug/L
0.766
5.00
1
05/08/24 21:20
SMB
L749499
3-Nitroaniline
<0.912
Ng/L
0.912
10.0
1
05/08/24 21:20
SMB
L749499
4-Nitroaniline
<12.5
ug/L
12.5
20.0
1
05/08/24 21:20
SMB
L749499
Nitrobenzene
<0.715
Ng/L
0.715
5.00
1
05/08/24 21:20
SMB
L749499
2-Nitrophenol
<0.728
ug/L
0.728
5.00
1
05/08/24 21:20
SMB
L749499
4-Nitrophenol
<1.94
Ng/L
1.94
10.0
1
05/08/24 21:20
SMB
L749499
N-Nitrosodimethylamine
<0.295
ug/L
0.295
5.00
1
05/08/24 21:20
SMB
L749499
N-Nitrosodiphenylamine
<0.487
Ng/L
0.487
10.0
1
05/08/24 21:20
SMB
L749499
N-Nitrosodiethylamine
<0.535
ug/L
0.535
5.00
1
05/08/24 21:20
SMB
L749499
N-Nitroso-di-n-butylamine
<0.699
Ng/L
0.699
5.00
1
05/08/24 21:20
SMB
L749499
N-Nitroso-di-n-propylamine
<0.678
ug/L
0.678
5.00
1
05/08/24 21:20
SMB
L749499
Pentachlorobenzene
<0.574
Ng/L
0.574
10.0
1
05/08/24 21:20
SMB
L749499
Pentachloronitrobenzene
<0.569
ug/L
0.569
5.00
1
05/08/24 21:20
SMB
L749499
Pentachlorophenol
<1.23
Ng/L
1.23
10.0
1
05/08/24 21:20
SMB
L749499
Phenacetin
<0.693
ug/L
0.693
5.00
1
05/08/24 21:20
SMB
L749499
Phenanthrene
<0.582
Ng/L
0.582
2.00
1
05/08/24 21:20
SMB
L749499
Phenol
<0.258
ug/L
0.258
5.00
1
05/08/24 21:20
SMB
L749499
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 62 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
01186
Smith & Gardner, Inc.
Project
Seth C. Rickerts
14 N. Boylan Avenue
Information
Raleigh , NC 27603
Report Number : 24-124-0102
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Surry County C&D/MSW Spring
REPORT OF ANAL YSIS
Report Date : 05/31/2024
Received : 05/03/2024
Lab No : 92546 Matrix: Aqueous
Sample ID: MW-1 Sampled: 5/2/2024 12:30
Analytical Method: 8270D
Prep Method: 3510C
Test Results
Pyrene
<0.680
1,2,4,5-Tetrachlorobenzene
<0.463
2,3,4,6-Tetrachlorophenol
<0.570
1,2,4-Trichlorobenzene
<0.433
2,4,5-Trichlorophenol
<0.611
2,4,6-Trichlorophenol
<0.539
Surrogate: 2-Fluorobiphenyl
Surrogate: 2-Fluorophenol
Surrogate: Nitrobenzene-d5
Surrogate: Phenol-d6
Surrogate: 4-Terphenyl-d 14
Surrogate: 2,4,6-Tribromophenol
Prep Batch(es): L749275 05/08/24 12:10
Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.680 2.00
Pg/L
0.463 5.00
Ng/L
0.570 5.00
ug/L
0.433 5.00
Ng/L
0.611 5.00
Pg/L
0.539 5.00
63.2
Limits: 24-93%
34.2
Limits: 10-44%
57.9
Limits: 20-91%
25.1
Limits: 7-32%
70.2
Limits: 35-126%
67.4
Limits: 39-110%
1 05/08/24 21:20 SMB
L749499
1 05/08/24 21:20 SMB
L749499
1 05/08/24 21:20 SMB
L749499
1 05/08/24 21:20 SMB
L749499
1 05/08/24 21:20 SMB
L749499
1 05/08/24 21:20 SMB
L749499
1 05/08/24 21:20 SMB
L749499
1 05/08/24 21:20 SMB
L749499
1 05/08/24 21:20 SMB
L749499
1 05/08/24 21:20 SMB
L749499
1 05/08/24 21:20 SMB
L749499
1 05/08/24 21:20 SMB
L749499
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor H Beyond holding time
J Estimated value M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 63 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102
REPOR T OF A NA L YSIS
Lab No : 92547
Matrix: Aqueous
Sample ID: MW-11
Sampled: 5/2/2024 13:30
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Sulfate
28600
Ng/L
600
2000
1
05/03/2417:18
NDL
9056A
Ferrous Iron
0.22 H
mg/L
0.05
0.20
1
05/03/24 13:40
GOB
SM-3500-Fe-B
Ethane
<2.67
Ng/L
2.67
10.0
1
05/06/24 13:51
TBL
RSK-175
Ethene
<2.28
ug/L
2.28
10.0
1
05/06/24 13:51
TBL
RSK-175
Hydrogen
<10.0
Ng/L
10.0
1
05/14/24 14:58
ADO
RSK-175
Methane
413
ug/L
2.51
10.0
1
05/06/24 13:51
TBL
RSK-175
1,4-Dioxane
<0.139
Ng/L
0.139
2.00
1
05/07/24 09:53
TBL
8260D SIM
1,4-Naphthoquinone
<10.2 M
ug/L
10.2
10.2
1
05/08/24 21:41
SMB
8270D
1-Naphthylamine
<10.2
Ng/L
10.2
10.2
1
05/08/24 21:41
SMB
8270D
2-Acetylaminofluorene
<10.2
ug/L
10.2
10.2
1
05/08/24 21:41
SMB
8270D
2-Naphthylamine
<10.2
Ng/L
10.2
10.2
1
05/08/24 21:41
SMB
8270D
3-Methylcholanthrene
<10.2
ug/L
10.2
10.2
1
05/08/24 21:41
SMB
8270D
4-Aminobiphenyl
<10.2
Ng/L
10.2
10.2
1
05/08/24 21:41
SMB
8270D
5-Nitro-o-toluidine
<10.2
ug/L
10.2
10.2
1
05/08/24 21:41
SMB
8270D
7,12-Dimethyl benz(a)anth racene <10.2
Ng/L
10.2
10.2
1
05/08/24 21:41
SMB
8270D
Diallate
<10.2
ug/L
10.2
10.2
1
05/08/24 21:41
SMB
8270D
Hexachloropropene
<10.2
Ng/L
10.2
10.2
1
05/08/24 21:41
SMB
8270D
Isosafrole
<10.2
ug/L
10.2
10.2
1
05/08/24 21:41
SMB
8270D
Methapyrilene
<10.2
Ng/L
10.2
20.4
1
05/08/24 21:41
SMB
8270D
N-Nitrosomethylethylamine
<10.2
ug/L
10.2
10.2
1
05/08/24 21:41
SMB
8270D
N-Nitrosomorpholine
<10.2
Ng/L
10.2
10.2
1
05/08/24 21:41
SMB
8270D
N-Nitrosopyrrolidine
<10.2
ug/L
10.2
10.2
1
05/08/24 21:41
SMB
8270D
N-Nitrosopiperidine
<10.2
Ng/L
10.2
10.2
1
05/08/24 21:41
SMB
8270D
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum
value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 64 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102
REPOR T OF A NA L YSIS
Lab No : 92547
Matrix: Aqueous
Sample ID: MW-11
Sampled: 5/2/2024 13:30
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
0,0,0-Triethyl Phosphorothioate
<0.336
Ng/L
0.336
1.02
1
05/08/24 20:13
SMB
8270C
o-Toluidine
<10.2
ug/L
10.2
10.2
1
05/08/24 21:41
SMB
8270D
p-Dimethylaminoazobenzene
<10.2
Ng/L
10.2
10.2
1
05/08/24 21:41
SMB
8270D
p-Phenylenediamine
<10.2 M
ug/L
10.2
10.2
1
05/08/24 21:41
SMB
8270D
Pronamide
<10.2
Ng/L
10.2
10.2
1
05/08/24 21:41
SMB
8270D
Safrole
<10.2
ug/L
10.2
10.2
1
05/08/24 21:41
SMB
8270D
Thionazine
<0.336
Ng/L
0.336
1.02
1
05/08/24 20:13
SMB
8270C
Alkalinity (as CaCO3)
34000
u9/L
800
5000
1
05/08/24 15:40
RLW
2320B-2011
Biochemical Oxygen Demand (5-day)
<2000
N9/L
2000
2000
1
05/03/24 10:39
MLW
521OB-2015
Chloride
5970
u9/L
500
1000
1
05/03/2417:18
NDL
9056A
Cyanide, Total
<12.0
N9/L
12.0
25.0
1
05/14/24 14:05
RLW
9014
COD (Chemical Oxygen Demand)
<15000
u9/L
15000
30000
1
05/09/24 11:25
SLO
5220D-2011
Nitrate (NO3-N)
128
N9/L
50.0
100
1
05/03/24 17:18
NDL
9056A
TOC
2490
u9/L
720
1000
1
05/09/24 03:54
AT
531OC-2011
Sulfide
<830
N9/L
830
2000
1
05/06/2414:53
GOB
4500S2F-2011
Antimony
<0.618
u9/L
0.618
1.00
1
05/14/24 00:35
TJS
6020B
Arsenic
<0.297
N9/L
0.297
1.00
1
05/14/24 00:35
TJS
6020B
Barium
34.4
u9/L
0.453
1.00
1
05/14/24 00:35
TJS
6020B
Beryllium
<0.102
N9/L
0.102
1.00
1
05/14/24 00:35
TJS
6020B
Cadmium
<0.350
u9/L
0.350
1.00
1
05/14/2419:26
CPW
6020B
Chromium
0.8513
N9/L
0.346
1.00
1
05/14/2419:26
CPW
6020B
Cobalt
48.4
u9/L
0.060
1.00
1
05/14/24 00:35
TJS
6020B
Copper
1.15
N9/L
0.489
1.00
1
05/14/24 00:35
TJS
6020B
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum
value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 65 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92547
Sample ID: MW-11
Matrix: Aqueous
Sampled: 5/2/2024 13:30
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Lead
<0.264
Ng/L
0.264
1.00
1
05/14/24 00:35
TJS
6020E
Mercury (Total)
<0.100
ug/L
0.100
0.200
1
05/13/24 14:52
FDS
7470A
Nickel
3.95
Ng/L
0.182
1.00
1
05/14/24 19:26
CPW
6020E
Selenium
<0.703
ug/L
0.703
1.00
1
05/14/24 00:35
TJS
6020B
Silver
<0.0570
Ng/L
0.0570
1.00
1
05/14/2419:26
CPW
6020E
Tin
<1.44
ug/L
1.44
5.00
1
05/14/24 00:35
TJS
6020B
Thallium
0.1103
Ng/L
0.0610
1.00
1
05/14/24 00:35
TJS
6020B
Vanadium
<0.767
ug/L
0.767
5.00
1
05/14/24 00:35
TJS
6020B
Zinc
<10.0
Ng/L
4.67
10.0
1
05/14/24 00:35
TJS
6020B
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor H Beyond holding time
J Estimated value M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 66 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92547
Matrix: Aqueous
Sample ID: MW-11
Sampled: 5/2/2024 13:30
Analytical Method:
8081B
Prep Batch(es):
V46914
05/07/24 10:07
Prep Method:
3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Aldrin
<0.0152
Ng/L
0.0152
0.0500
1
05/16/24 01:28
TJW
V47319
alpha-BHC
<0.0063
ug/L
0.0063
0.0500
1
05/16/24 01:28
TJW
V47319
beta-BHC
<0.0111
Ng/L
0.0111
0.0500
1
05/16/24 01:28
TJW
V47319
delta-BHC
<0.0082
ug/L
0.0082
0.0500
1
05/16/24 01:28
TJW
V47319
Chlordane
<0.180
Ng/L
0.180
0.500
1
05/16/24 01:28
TJW
V47319
alpha -Chlordane
<0.0186
ug/L
0.0186
0.100
1
05/16/24 01:28
TJW
V47319
gamma -Chlordane
<0.0231
Ng/L
0.0231
0.100
1
05/16/24 01:28
TJW
V47319
4,4'-DDD
<0.0265
ug/L
0.0265
0.100
1
05/16/24 01:28
TJW
V47319
4,4'-DDE
<0.0218
Ng/L
0.0218
0.100
1
05/16/24 01:28
TJW
V47319
4,4'-DDT
<0.0176
ug/L
0.0176
0.100
1
05/16/24 01:28
TJW
V47319
Dieldrin
<0.0137
Ng/L
0.0137
0.0500
1
05/16/24 01:28
TJW
V47319
EndosulfanI
<0.0160
ug/L
0.0160
0.0500
1
05/16/24 01:28
TJW
V47319
Endosulfan II
<0.0121
Ng/L
0.0121
0.0500
1
05/16/24 01:28
TJW
V47319
Endosulfan Sulfate
<0.0165
ug/L
0.0165
0.0500
1
05/16/24 01:28
TJW
V47319
Endrin
<0.0136
Ng/L
0.0136
0.0500
1
05/16/24 01:28
TJW
V47319
Endrin Aldehyde
<0.0158
ug/L
0.0158
0.0500
1
05/16/24 01:28
TJW
V47319
Endrin Ketone
<0.0181
Ng/L
0.0181
0.100
1
05/16/24 01:28
TJW
V47319
gamma-BHC
<0.0061
ug/L
0.0061
0.0500
1
05/16/24 01:28
TJW
V47319
Heptachlor
<0.0130
Ng/L
0.0130
0.0500
1
05/16/24 01:28
TJW
V47319
Heptachlor Epoxide
<0.0224
ug/L
0.0224
0.100
1
05/16/24 01:28
TJW
V47319
Methoxychlor
<0.0179
Ng/L
0.0179
0.100
1
05/16/24 01:28
TJW
V47319
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 67 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102
REPOR T OF A NA L YSIS
Lab No : 92547
Matrix: Aqueous
Sample ID: MW-11
Sampled: 5/2/2024
13:30
Analytical Method: 8081B
Prep Batch(es):
V46914
05/07/24 10:07
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF Date / Time By
Analytical
Analyzed
Batch
Toxaphene
<0.350
Ng/L
0.350
1.00
1 05/16/24 01:28 TJW
V47319
Surrogate: Decachlorobiphenyl
102
Limits:
13-186%
1 05/16/24 01:28 TJW
V47319
Surrogate: Tetrachloro-m-xylene
115
Limits:
40-134%
1 05/16/24 01:28 TJW
V47319
Analytical Method: 8082A
Prep Batch(es):
V46915
05/07/24 10:07
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF Date / Time By
Analytical
Analyzed
Batch
Aroclor 1016
<0.210
u9/L
0.210
0.500
1 05/16/24 18:45 TJW
V47358
Aroclor1221
<0.110
Ng/L
0.110
1.00
1 05/16/24 18:45 TJW
V47358
Aroclor1232
<0.160
u9/L
0.160
0.500
1 05/16/24 18:45 TJW
V47358
Aroclor1242
<0.140
Ng/L
0.140
0.500
1 05/16/24 18:45 TJW
V47358
Aroclor1248
<0.140
u9/L
0.140
0.500
1 05/16/24 18:45 TJW
V47358
Aroclor1254
<0.160
Ng/L
0.160
0.500
1 05/16/24 18:45 TJW
V47358
Aroclor 1260
<0.495
u9/L
0.495
1.00
1 05/16/24 18:45 TJW
V47358
Surrogate: Decachlorobiphenyl
107
Limits:
32-178%
1 05/16/24 18:45 TJW
8082A
Surrogate: Tetrachloro-m-xylene
89.3
Limits:
30-161%
1 05/16/24 18:45 TJW
8082A
Analytical Method: 8151A
Prep Batch(es):
L749619
05/09/24 13:10
Prep Method: 8151A
Test
Results
Units
MDL
MQL
DF Date / Time By
Analytical
Analyzed
Batch
2,4-D
<0.2120
ug/L
0.2120
0.2551
1 05/14/24 23:42 SWB
L750458
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 68 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
01186
Smith & Gardner, Inc.
Project
Seth C. Rickerts
14 N. Boylan Avenue
Information
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Surry County C&D/MSW Spring
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Report Date : 05/31/2024
Received : 05/03/2024
Lab No : 92547 Matrix: Aqueous
Sample ID: MW-11 Sampled: 5/2/2024 13:30
Analytical Method: 8151A Prep Batch(es): L749619 05/09/24 13:10
Prep Method: 8151A
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Dalapon
<0.5254
Ng/L
0.5254
0.5612
1
05/14/24 23:42
SWB
L750458
2,4-DB
<0.1392
ug/L
0.1392
0.2551
1
05/14/24 23:42
SWB
L750458
Dicamba
<0.05814
Ng/L
0.05814
0.1020
1
05/14/24 23:42
SWB
L750458
Dichlorprop
<0.08118
pg/L
0.08118
0.1020
1
05/14/24 23:42
SWB
L750458
Dinoseb
<0.02751
Ng/L
0.02751
0.1020
1
05/14/24 23:42
SWB
L750458
MCPA
<19.37
pg/L
19.37
51.02
1
05/14/24 23:42
SWB
L750458
MCPP
<11.99
Ng/L
11.99
51.02
1
05/14/24 23:42
SWB
L750458
Picloram
0.06644 JQ
pg/L
0.04618
0.1020
1
05/14/24 23:42
SWB
L750458
2,4,5-T
<0.1023
Ng/L
0.1023
0.1276
1
05/14/24 23:42
SWB
L750458
2,4,5-TP (Silvex)
<0.01666
ug/L
0.01666
0.1020
1
05/14/24 23:42
SWB
L750458
Surrogate: DCAA
142.5
Limits: 20-150%
1 05/14/24 23:42 SWB
L750458
Analytical Method: 8260D
Prep Batch(es):
V47200
05/09/24 14:00
V47336
05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
1.913
ug/L
1.80
5.00
1 05/10/24 08:54 MSA
V47202
Acetonitrile
<10.0
Ng/L
10.0
10.0
1 05/15/2416:05 MSA
V47337
Acrolein
<2.00
ug/L
2.00
5.00
1 05/10/24 08:54 MSA
V47202
Acrylonitrile
<0.230
Ng/L
0.230
5.00
1 05/10/24 08:54 MSA
V47202
Allyl Chloride
<0.579
ug/L
0.579
10.0
1 05/15/24 16:05 MSA
V47337
Benzene
0.2873
Ng/L
0.180
0.500
1 05/10/24 08:54 MSA
V47202
Bromochloromethane
<0.420
ug/L
0.420
1.00
1 05/10/24 08:54 MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 69 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92547
Matrix: Aqueous
Sample ID: MW-11
Sampled: 5/2/2024 13:30
Analytical Method: 8260D
Prep Batch(es):
V47200
05/09/24 14:00
V47336
05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
05/10/24 08:54
MSA
V47202
Bromoform
<1.50
ug/L
1.50
5.00
1
05/10/24 08:54
MSA
V47202
Bromomethane
<0.280
Ng/L
0.280
1.00
1
05/10/24 08:54
MSA
V47202
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
05/10/24 08:54
MSA
V47202
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
05/10/24 08:54
MSA
V47202
Chlorobenzene
1.60
ug/L
0.190
0.500
1
05/10/24 08:54
MSA
V47202
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
05/10/24 08:54
MSA
V47202
Chloroethane
<0.430
ug/L
0.430
1.00
1
05/10/24 08:54
MSA
V47202
Chloroform
<0.220
Ng/L
0.220
0.500
1
05/10/24 08:54
MSA
V47202
Chloromethane
<0.220
ug/L
0.220
0.500
1
05/10/24 08:54
MSA
V47202
Chloroprene
<0.450
Ng/L
0.450
10.0
1
05/15/24 16:05
MSA
V47337
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
05/10/24 08:54
MSA
V47202
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
05/10/24 08:54
MSA
V47202
Dibromomethane
<0.230
ug/L
0.230
0.500
1
05/10/24 08:54
MSA
V47202
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
05/10/24 08:54
MSA
V47202
1,2-Dichlorobenzene
<0.220
ug/L
0.220
0.500
1
05/10/24 08:54
MSA
V47202
1,3-Dichlorobenzene
<0.190
Ng/L
0.190
0.500
1
05/10/24 08:54
MSA
V47202
1,4-Dichlorobenzene
2.00
ug/L
0.210
0.500
1
05/10/24 08:54
MSA
V47202
Dichlorodifluoromethane
<1.20
Ng/L
1.20
5.00
1
05/10/24 08:54
MSA
V47202
1,1-Dichloroethane
<0.240
ug/L
0.240
0.500
1
05/10/24 08:54
MSA
V47202
1,2-Dichloroethane
<0.150
Ng/L
0.150
0.500
1
05/10/24 08:54
MSA
V47202
1,1-Dichloroethene
<0.150
ug/L
0.150
0.500
1
05/10/24 08:54
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 70 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92547
Matrix: Aqueous
Sample ID: MW-11
Sampled: 5/2/2024 13:30
Analytical Method: 8260D
Prep Batch(es):
V47200
05/09/24 14:00
V47336
05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
cis- 1,2-Dich loroethene
0.2463
Ng/L
0.200
0.500
1
05/10/24 08:54
MSA
V47202
trans- 1.2-Dichloroethene
<0.180
ug/L
0.180
0.500
1
05/10/24 08:54
MSA
V47202
1,2-Dichloropropane
0.3283
Ng/L
0.190
0.500
1
05/10/24 08:54
MSA
V47202
1,3-Dichloropropane
<0.130
ug/L
0.130
0.500
1
05/10/24 08:54
MSA
V47202
2,2-Dichloropropane
<0.210
Ng/L
0.210
2.00
1
05/10/24 08:54
MSA
V47202
1,1-Dichloropropene
<0.200
ug/L
0.200
0.500
1
05/10/24 08:54
MSA
V47202
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
05/10/24 08:54
MSA
V47202
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
05/10/24 08:54
MSA
V47202
Ethyl Methacrylate
<1.62
Ng/L
1.62
10.0
1
05/15/24 16:05
MSA
V47337
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
05/10/24 08:54
MSA
V47202
Hexachlorobutadiene
<0.350
Ng/L
0.350
2.00
1
05/10/24 08:54
MSA
V47202
2-Hexanone
<0.380
ug/L
0.380
5.00
1
05/10/24 08:54
MSA
V47202
Iodomethane
<0.054
Ng/L
0.054
0.500
1
05/10/24 08:54
MSA
V47202
Methyl Ethyl Ketone (MEK)
<0.710
pg/L
0.710
5.00
1
05/10/24 08:54
MSA
V47202
Methacrylonitrile
<10.0
Ng/L
10.0
10.0
1
05/15/2416:05
MSA
V47337
4-Methyl-2-Pentanone
<1.00
ug/L
1.00
5.00
1
05/10/24 08:54
MSA
V47202
Methylene Chloride
<0.330
Ng/L
0.330
1.00
1
05/10/24 08:54
MSA
V47202
Naphthalene
<0.470
pg/L
0.470
1.00
1
05/10/24 08:54
MSA
V47202
Propionitrile
<10.0
Ng/L
10.0
10.0
1
05/15/2416:05
MSA
V47337
Styrene
<0.220
pg/L
0.220
0.500
1
05/10/24 08:54
MSA
V47202
1,1,1,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
05/10/24 08:54
MSA
V47202
1,1,2,2-Tetrachloroethane
<0.160
pg/L
0.160
0.500
1
05/10/24 08:54
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 71 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92547
Matrix: Aqueous
Sample ID: MW-11
Sampled: 5/2/2024
13:30
Analytical Method: 8260D
Prep Batch(es):
V47200 05/09/24 14:00
V47336 05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Tetrachloroethene
<0.220
Ng/L
0.220 0.500
1
05/10/24 08:54 MSA
V47202
Tetrahydrofuran
<1.50
ug/L
1.50 10.0
1
05/10/24 08:54 MSA
V47202
Toluene
<0.220
Ng/L
0.220 0.500
1
05/10/24 08:54 MSA
V47202
1,2,4-Trichlorobenzene
<0.310
ug/L
0.310 1.00
1
05/10/24 08:54 MSA
V47202
1,1,1-Trichloroethane
<0.160
Ng/L
0.160 0.500
1
05/10/24 08:54 MSA
V47202
1,1,2-Trichloroethane
<0.096
ug/L
0.096 0.500
1
05/10/24 08:54 MSA
V47202
Trichloroethene
<0.180
Ng/L
0.180 0.500
1
05/10/24 08:54 MSA
V47202
Trichlorofluoromethane
<0.180
ug/L
0.180 0.500
1
05/10/24 08:54 MSA
V47202
1,2,3-Trichloropropane
<0.270
Ng/L
0.270 1.00
1
05/10/24 08:54 MSA
V47202
Vinyl Acetate
<1.00 M
ug/L
1.00 2.00
1
05/10/24 08:54 MSA
V47202
Vinyl Chloride
<0.170
Ng/L
0.170 0.500
1
05/10/24 08:54 MSA
V47202
o-Xylene
<0.210
ug/L
0.210 0.500
1
05/10/24 08:54 MSA
V47202
m,p-Xylene
<0.420
Ng/L
0.420 1.00
1
05/10/24 08:54 MSA
V47202
Xylene (Total)
<0.21
ug/L
0.210 0.500
1
05/10/24 08:54 KCC
V47202
Surrogate: 4-Bromofluorobenzene
102
Limits: 80-124%
1 05/10/24 08:54 MSA
V47202
Surrogate: Dibromofluoromethane
103
Limits: 75-129%
1 05/10/24 08:54 MSA
V47202
Surrogate: 1,2-Dichloroethane - d4
99.4
Limits: 63-136%
1 05/10/24 08:54 MSA
V47202
Surrogate: Toluene-d8
99.6
Limits: 77-123%
1 05/10/24 08:54 MSA
V47202
Surrogate:4-Bromofluorobenzene
99.2
Limits:80-124%
1 05/15/24 16:05 MSA
V47337
Surrogate: Dibromofluoromethane
105
Limits: 75-129%
1 05/15/24 16:05 MSA
V47337
Surrogate: 1,2-Dichloroethane - d4
106
Limits: 63-136%
1 05/15/24 16:05 MSA
V47337
Surrogate: Toluene-d8
106
Limits: 77-123%
1 05/15/24 16:05 MSA
V47337
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 72 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
01186
Smith & Gardner, Inc.
Project
Seth C. Rickerts
14 N. Boylan Avenue
Information
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Surry County C&D/MSW Spring
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Report Date : 05/31/2024
Received : 05/03/2024
Lab No : 92547 Matrix: Aqueous
Sample ID: MW-11 Sampled: 5/2/2024 13:30
Analytical Method: 8270C Prep Batch(es): L749277 05/08/24 12:10
Prep Method: 3510C
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Dimethoate
<0.727
Ng/L
0.727
1.02
1
05/08/24 20:13
SMB
L749502
Disulfoton
<0.475
ug/L
0.475
1.02
1
05/08/24 20:13
SMB
L749502
Ethyl Parathion
<0.579
Ng/L
0.579
1.02
1
05/08/24 20:13
SMB
L749502
Famphur
<0.522
ug/L
0.522
1.02
1
05/08/24 20:13
SMB
L749502
Methyl Parathion
<0.821
Ng/L
0.821
1.02
1
05/08/24 20:13
SMB
L749502
Phorate
<0.672
ug/L
0.672
1.02
1
05/08/24 20:13
SMB
L749502
Surrogate: Tributyl phosphate
76.0
Limits:
50-150%
1 05/08/24 20:13 SMB
8270C
Surrogate: Triphenyl phosphate
93.6
Limits:
50-150%
1 05/08/24 20:13 SMB
8270C
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,3-Dinitrobenzene
<0.904
ug/L
0.904
10.0
1
05/08/24 21:41
SMB
L749499
1,3,5-Trinitrobenzene
<10.2
Ng/L
10.2
10.2
1
05/08/24 21:41
SMB
L749501
Acenaphthene
<0.563
ug/L
0.563
2.00
1
05/08/24 21:41
SMB
L749499
Acenaphthylene
<0.562
Ng/L
0.562
2.00
1
05/08/24 21:41
SMB
L749499
Acetophenone
<0.689
ug/L
0.689
5.00
1
05/08/24 21:41
SMB
L749499
Anthracene
<0.536
Ng/L
0.536
2.00
1
05/08/24 21:41
SMB
L749499
Benzo(a)anthracene
<0.520
ug/L
0.520
2.00
1
05/08/24 21:41
SMB
L749499
Benzo(a)pyrene
<0.511
Ng/L
0.511
2.00
1
05/08/24 21:41
SMB
L749499
Benzo(b)fluoranthene
<0.631
ug/L
0.631
2.00
1
05/08/24 21:41
SMB
L749499
Benzo(g,h,i)perylene
<0.507
Ng/L
0.507
2.00
1
05/08/24 21:41
SMB
L749499
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 73 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92547
Matrix: Aqueous
Sample ID: MW-11
Sampled: 5/2/2024 13:30
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Benzo(k)fluoranthene
<0.575
Ng/L
0.575
2.00
1
05/08/24 21:41
SMB
L749499
Benzyl alcohol
<1.02
ug/L
1.02
10.0
1
05/08/24 21:41
SMB
L749499
Bis(2-Chloroethoxy)methane
<0.592
Ng/L
0.592
5.00
1
05/08/24 21:41
SMB
L749499
Bis(2-Chloroethyl)ether
<0.627
ug/L
0.627
5.00
1
05/08/24 21:41
SMB
L749499
Bis(2-Chloroisopropyl)ether
<0.656
Ng/L
0.656
5.00
1
05/08/24 21:41
SMB
L749499
Bis(2-ethylhexyl)phthalate
<0.796
ug/L
0.796
5.00
1
05/08/24 21:41
SMB
L749499
4-Bromophenyl phenyl ether
<0.567
Ng/L
0.567
5.00
1
05/08/24 21:41
SMB
L749499
Butyl benzyl phthalate
<0.756
ug/L
0.756
5.00
1
05/08/24 21:41
SMB
L749499
4-Chloro-3-methylphenol
<0.550
Ng/L
0.550
5.00
1
05/08/24 21:41
SMB
L749499
4-Chloroaniline
<0.530
ug/L
0.530
5.00
1
05/08/24 21:41
SMB
L749499
Chlorobenzilate
<0.999
Ng/L
0.999
5.00
1
05/08/24 21:41
SMB
L749499
2-Chloronaphthalene
<0.560
ug/L
0.560
5.00
1
05/08/24 21:41
SMB
L749499
2-Chlorophenol
<0.457
Ng/L
0.457
5.00
1
05/08/24 21:41
SMB
L749499
4-Chlorophenyl phenyl ether
<0.615
ug/L
0.615
5.00
1
05/08/24 21:41
SMB
L749499
Chrysene
<0.550
Ng/L
0.550
2.00
1
05/08/24 21:41
SMB
L749499
Dibenz(a,h)anthracene
<0.460
ug/L
0.460
2.00
1
05/08/24 21:41
SMB
L749499
Dibenzofuran
<0.584
Ng/L
0.584
5.00
1
05/08/24 21:41
SMB
L749499
1,2-Dichlorobenzene
<0.466
ug/L
0.466
5.00
1
05/08/24 21:41
SMB
L749499
1,3-Dichlorobenzene
<0.436
Ng/L
0.436
5.00
1
05/08/24 21:41
SMB
L749499
1,4-Dichlorobenzene
1.11 ]
ug/L
0.405
5.00
1
05/08/24 21:41
SMB
L749499
3,3'-Dichlorobenzidine
<10.3
Ng/L
10.3
20.0
1
05/08/24 21:41
SMB
L749499
2,4-Dichlorophenol
<0.606
ug/L
0.606
5.00
1
05/08/24 21:41
SMB
L749499
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 74 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92547
Matrix: Aqueous
Sample ID: MW-11
Sampled: 5/2/2024 13:30
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
2,6-Dichlorophenol
<0.655
Ng/L
0.655
5.00
1
05/08/24 21:41
SMB
L749499
Diethyl phthalate
<0.686
ug/L
0.686
5.00
1
05/08/24 21:41
SMB
L749499
Dimethyl phthalate
<0.652
Ng/L
0.652
5.00
1
05/08/24 21:41
SMB
L749499
3,3' Dimethylbenzidine
<9.01
ug/L
9.01
10.0
1
05/08/24 21:41
SMB
L749499
2,4-Dimethyl phenol
<0.620
Ng/L
0.620
5.00
1
05/08/24 21:41
SMB
L749499
Di-n-butyl phthalate
<0.740
ug/L
0.740
5.00
1
05/08/24 21:41
SMB
L749499
4,6-Dinitro-2- methyl phenol
<6.08
Ng/L
6.08
10.0
1
05/08/24 21:41
SMB
L749499
2,4-Dinitrophenol
<18.9
ug/L
18.9
20.0
1
05/08/24 21:41
SMB
L749499
2,4-Dinitrotoluene
<0.911
Ng/L
0.911
5.00
1
05/08/24 21:41
SMB
L749499
2,6-Dinitrotoluene
<0.734
ug/L
0.734
5.00
1
05/08/24 21:41
SMB
L749499
Di-n-Octyl Phthalate
<1.32
Ng/L
1.32
5.00
1
05/08/24 21:41
SMB
L749499
Ethyl methanesulfonate
<0.660
ug/L
0.660
5.00
1
05/08/24 21:41
SMB
L749499
Fluoranthene
<0.583
Ng/L
0.583
2.00
1
05/08/24 21:41
SMB
L749499
Fluorene
<0.617
ug/L
0.617
2.00
1
05/08/24 21:41
SMB
L749499
Hexachlorobenzene
<0.537
Ng/L
0.537
5.00
1
05/08/24 21:41
SMB
L749499
Hexachlorobutadiene
<0.411
ug/L
0.411
5.00
1
05/08/24 21:41
SMB
L749499
Hexachlorocyclopentadiene
<0.889
Ng/L
0.889
5.00
1
05/08/24 21:41
SMB
L749499
Hexachloroethane
<0.482
ug/L
0.482
5.00
1
05/08/24 21:41
SMB
L749499
Indeno(1,2,3-cd)pyrene
<0.490
Ng/L
0.490
2.00
1
05/08/24 21:41
SMB
L749499
Isodrin
<10.2
ug/L
10.2
10.2
1
05/08/24 21:41
SMB
L749501
Isophorone
<0.591
Ng/L
0.591
5.00
1
05/08/24 21:41
SMB
L749499
Kepone
<10.2 M
ug/L
10.2
10.2
1
05/08/24 21:41
SMB
L749501
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 75 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92547
Matrix: Aqueous
Sample ID: MW-11
Sampled: 5/2/2024 13:30
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Methyl methanesulfonate
<0.746
Ng/L
0.746
5.00
1
05/08/24 21:41
SMB
L749499
2-Methylnaphthalene
<0.569
ug/L
0.569
2.00
1
05/08/24 21:41
SMB
L749499
2-Methylphenol
<0.449
Ng/L
0.449
5.00
1
05/08/24 21:41
SMB
L749499
3&4 Methylphenol
<0.453
ug/L
0.453
5.00
1
05/08/24 21:41
SMB
L749499
Naphthalene
<1.70
Ng/L
1.70
2.00
1
05/08/24 21:41
SMB
L749499
2-Nitroaniline
<0.766
ug/L
0.766
5.00
1
05/08/24 21:41
SMB
L749499
3-Nitroaniline
<0.912
Ng/L
0.912
10.0
1
05/08/24 21:41
SMB
L749499
4-Nitroaniline
<12.5
ug/L
12.5
20.0
1
05/08/24 21:41
SMB
L749499
Nitrobenzene
<0.715
Ng/L
0.715
5.00
1
05/08/24 21:41
SMB
L749499
2-Nitrophenol
<0.728
ug/L
0.728
5.00
1
05/08/24 21:41
SMB
L749499
4-Nitrophenol
<1.94
Ng/L
1.94
10.0
1
05/08/24 21:41
SMB
L749499
N-Nitrosodimethylamine
<0.295
ug/L
0.295
5.00
1
05/08/24 21:41
SMB
L749499
N-Nitrosodiphenylamine
<0.487
Ng/L
0.487
10.0
1
05/08/24 21:41
SMB
L749499
N-Nitrosodiethylamine
<0.535
ug/L
0.535
5.00
1
05/08/24 21:41
SMB
L749499
N-Nitroso-di-n-butylamine
<0.699
Ng/L
0.699
5.00
1
05/08/24 21:41
SMB
L749499
N-Nitroso-di-n-propylamine
<0.678
ug/L
0.678
5.00
1
05/08/24 21:41
SMB
L749499
Pentachlorobenzene
<0.574
Ng/L
0.574
10.0
1
05/08/24 21:41
SMB
L749499
Pentachloronitrobenzene
<0.569
ug/L
0.569
5.00
1
05/08/24 21:41
SMB
L749499
Pentachlorophenol
<1.23
Ng/L
1.23
10.0
1
05/08/24 21:41
SMB
L749499
Phenacetin
<0.693
ug/L
0.693
5.00
1
05/08/24 21:41
SMB
L749499
Phenanthrene
<0.582
Ng/L
0.582
2.00
1
05/08/24 21:41
SMB
L749499
Phenol
<0.258
ug/L
0.258
5.00
1
05/08/24 21:41
SMB
L749499
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 76 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
01186
Smith & Gardner, Inc.
Project
Seth C. Rickerts
14 N. Boylan Avenue
Information
Raleigh , NC 27603
Report Number : 24-124-0102
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Surry County C&D/MSW Spring
REPORT OF ANAL YSIS
Report Date : 05/31/2024
Received : 05/03/2024
Lab No : 92547 Matrix: Aqueous
Sample ID: MW-11 Sampled: 5/2/2024 13:30
Analytical Method: 8270D
Prep Method: 3510C
Test Results
Pyrene
<0.680
1,2,4,5-Tetrachlorobenzene
<0.463
2,3,4,6-Tetrachlorophenol
<0.570
1,2,4-Trichlorobenzene
<0.433
2,4,5-Trichlorophenol
<0.611
2,4,6-Trichlorophenol
<0.539
Surrogate: 2-Fluorobiphenyl
Surrogate: 2-Fluorophenol
Surrogate: Nitrobenzene-d5
Surrogate: Phenol-d6
Surrogate: 4-Terphenyl-d 14
Surrogate: 2,4,6-Tribromophenol
Prep Batch(es): L749275 05/08/24 12:10
Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.680 2.00
Pg/L
0.463 5.00
Ng/L
0.570 5.00
ug/L
0.433 5.00
Ng/L
0.611 5.00
Pg/L
0.539 5.00
54.9
Limits: 24-93%
30.3
Limits: 10-44%
52.8
Limits: 20-91%
22.5
Limits: 7-32%
64.8
Limits: 35-126%
68.2
Limits: 39-110%
1 05/08/24 21:41 SMB
L749499
1 05/08/24 21:41 SMB
L749499
1 05/08/24 21:41 SMB
L749499
1 05/08/24 21:41 SMB
L749499
1 05/08/24 21:41 SMB
L749499
1 05/08/24 21:41 SMB
L749499
1 05/08/24 21:41 SMB
L749499
1 05/08/24 21:41 SMB
L749499
1 05/08/24 21:41 SMB
L749499
1 05/08/24 21:41 SMB
L749499
1 05/08/24 21:41 SMB
L749499
1 05/08/24 21:41 SMB
L749499
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor H Beyond holding time
J Estimated value M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 77 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102
REPOR T OF A NA L YSIS
Lab No : 92548
Matrix: Aqueous
Sample ID: MW-16
Sampled: 5/2/2024 14:45
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Sulfate
7930
Ng/L
600
2000
1
05/03/2417:55
NDL
9056A
Ferrous Iron
49.9 H
mg/L
1.25
5.00
1
05/03/24 13:40
GOB
SM-3500-Fe-B
Ethane
<2.67
Ng/L
2.67
10.0
1
05/06/24 14:04
TBL
RSK-175
Ethene
<2.28
ug/L
2.28
10.0
1
05/06/24 14:04
TBL
RSK-175
Methane
173
Ng/L
2.51
10.0
1
05/06/24 14:04
TBL
RSK-175
1,4-Dioxane
2.29
ug/L
0.139
2.00
1
05/07/24 11:35
TBL
8260D SIM
1,4-Naphthoquinone
<10.1 M
Ng/L
10.1
10.1
1
05/08/24 22:02
SMB
8270D
1-Naphthylamine
<10.1
ug/L
10.1
10.1
1
05/08/24 22:02
SMB
8270D
2-Acetylaminofluorene
<10.1
Ng/L
10.1
10.1
1
05/08/24 22:02
SMB
8270D
2-Naphthylamine
<10.1
ug/L
10.1
10.1
1
05/08/24 22:02
SMB
8270D
3-Methylcholanthrene
<10.1
Ng/L
10.1
10.1
1
05/08/24 22:02
SMB
8270D
4-Aminobiphenyl
<10.1
ug/L
10.1
10.1
1
05/08/24 22:02
SMB
8270D
5-Nitro-o-toluidine
<10.1
Ng/L
10.1
10.1
1
05/08/24 22:02
SMB
8270D
7,12-Di methyl benz(a)anth racene
<10.1
ug/L
10.1
10.1
1
05/08/24 22:02
SMB
8270D
Diallate
<10.1
Ng/L
10.1
10.1
1
05/08/24 22:02
SMB
8270D
Hexachloropropene
<10.1
ug/L
10.1
10.1
1
05/08/24 22:02
SMB
8270D
Isosafrole
<10.1
Ng/L
10.1
10.1
1
05/08/24 22:02
SMB
8270D
Methapyrilene
<10.1
ug/L
10.1
20.2
1
05/08/24 22:02
SMB
8270D
N-Nitrosomethylethylamine
<10.1
Ng/L
10.1
10.1
1
05/08/24 22:02
SMB
8270D
N-Nitrosomorpholine
<10.1
ug/L
10.1
10.1
1
05/08/24 22:02
SMB
8270D
N-Nitrosopyrrolidine
<10.1
Ng/L
10.1
10.1
1
05/08/24 22:02
SMB
8270D
N-Nitrosopiperidine
<10.1
ug/L
10.1
10.1
1
05/08/24 22:02
SMB
8270D
0,0,0-Triethyl Phosphorothioate
<0.333
Ng/L
0.333
1.01
1
05/08/24 20:26
SMB
8270C
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum
value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 78 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102
REPOR T OF A NA L YSIS
Lab No : 92548
Matrix: Aqueous
Sample ID: MW-16
Sampled: 5/2/2024 14:45
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
o-Toluidine
<10.1
Ng/L
10.1
10.1
1
05/08/24 22:02
SMB
8270D
p-Dimethylaminoazobenzene
<10.1
ug/L
10.1
10.1
1
05/08/24 22:02
SMB
8270D
p-Phenylenediamine
<10.1 M
Ng/L
10.1
10.1
1
05/08/24 22:02
SMB
8270D
Pronamide
<10.1
ug/L
10.1
10.1
1
05/08/24 22:02
SMB
8270D
Safrole
<10.1
Ng/L
10.1
10.1
1
05/08/24 22:02
SMB
8270D
Thionazine
<0.333
ug/L
0.333
1.01
1
05/08/24 20:26
SMB
8270C
Alkalinity (as CaCO3)
155000
Ng/L
1000
10000
1
05/08/24 15:40
RLW
2320B-2011
Biochemical Oxygen Demand
(5-day) <2000
ug/L
2000
2000
1
05/03/24 10:39
MLW
521OB-2015
Chloride
41000
Ng/L
500
1000
1
05/03/2417:55
NDL
9056A
Cyanide, Total
<12.0
ug/L
12.0
25.0
1
05/15/24 10:52
RLW
9014
COD (Chemical Oxygen Demand) <15000
Ng/L
15000
30000
1
05/09/24 11:25
SLO
5220D-2011
Nitrate (NO3-N)
75.0 J
ug/L
50.0
100
1
05/03/24 17:55
NDL
9056A
TOC
3800
Ng/L
720
1000
1
05/09/24 04:32
AT
531OC-2011
Sulfide
<830 M
ug/L
830
2000
1
05/06/24 14:53
GOB
4500S2F-2011
Antimony
<0.618
Ng/L
0.618
1.00
1
05/14/24 00:50
TJS
6020B
Arsenic
0.3363
ug/L
0.297
1.00
1
05/14/24 00:50
TJS
6020B
Barium
106
Ng/L
0.453
1.00
1
05/14/24 00:50
TJS
6020B
Beryllium
0.281 J
ug/L
0.102
1.00
1
05/14/24 00:50
TJS
6020B
Cadmium
<0.350
Ng/L
0.350
1.00
1
05/14/2419:31
CPW
6020B
Chromium
1.67
ug/L
0.346
1.00
1
05/14/24 00:50
CPW
6020B
Cobalt
270
Ng/L
0.060
1.00
1
05/14/24 00:50
TJS
6020B
Copper
9.34
ug/L
0.489
1.00
1
05/14/24 00:50
TJS
6020B
Lead
0.808 J
Ng/L
0.264
1.00
1
05/14/24 00:50
TJS
6020B
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum
value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 79 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92548
Sample ID: MW-16
Matrix: Aqueous
Sampled: 5/2/2024 14:45
Test
Results
Units
MDL
MQL
DF
Date / Time By Analytical
Analyzed Method
Mercury (Total)
0.1003
Ng/L
0.100
0.200
1
05/13/24 14:53 FDS 7470A
Nickel
13.6
ug/L
0.182
1.00
1
05/14/24 00:50 CPW 6020B
Selenium
<0.703
Ng/L
0.703
1.00
1
05/14/24 00:50 TJS 6020E
Silver
0.08043
ug/L
0.0570
1.00
1
05/14/24 19:31 CPW 6020B
Tin
5.55 B
Ng/L
1.44
5.00
1
05/14/24 00:50 TJS 6020B
Thallium
0.2933
ug/L
0.0610
1.00
1
05/14/24 00:50 TJS 6020B
Vanadium
<0.767
Ng/L
0.767
5.00
1
05/14/24 00:50 TJS 6020B
Zinc
14.3
ug/L
4.67
10.0
1
05/14/2419:31 CPW 6020B
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor H Beyond holding time
J Estimated value M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 80 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92548
Matrix: Aqueous
Sample ID: MW-16
Sampled: 5/2/2024 14:45
Analytical Method:
8081B
Prep Batch(es):
V46914
05/07/24 10:07
Prep Method:
3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Aldrin
<0.0152
Ng/L
0.0152
0.0500
1
05/16/24 02:22
TJW
V47319
alpha-BHC
<0.0063
ug/L
0.0063
0.0500
1
05/16/24 02:22
TJW
V47319
beta-BHC
<0.0111
Ng/L
0.0111
0.0500
1
05/16/24 02:22
TJW
V47319
delta-BHC
<0.0082
ug/L
0.0082
0.0500
1
05/16/24 02:22
TJW
V47319
Chlordane
<0.180
Ng/L
0.180
0.500
1
05/16/24 02:22
TJW
V47319
alpha -Chlordane
<0.0186
ug/L
0.0186
0.100
1
05/16/24 02:22
TJW
V47319
gamma -Chlordane
<0.0231
Ng/L
0.0231
0.100
1
05/16/24 02:22
TJW
V47319
4,4'-DDD
<0.0265
ug/L
0.0265
0.100
1
05/16/24 02:22
TJW
V47319
4,4'-DDE
<0.0218
Ng/L
0.0218
0.100
1
05/16/24 02:22
TJW
V47319
4,4'-DDT
<0.0176
ug/L
0.0176
0.100
1
05/16/24 02:22
TJW
V47319
Dieldrin
<0.0137
Ng/L
0.0137
0.0500
1
05/16/24 02:22
TJW
V47319
EndosulfanI
<0.0160
ug/L
0.0160
0.0500
1
05/16/24 02:22
TJW
V47319
Endosulfan II
<0.0121
Ng/L
0.0121
0.0500
1
05/16/24 02:22
TJW
V47319
Endosulfan Sulfate
<0.0165
ug/L
0.0165
0.0500
1
05/16/24 02:22
TJW
V47319
Endrin
<0.0136
Ng/L
0.0136
0.0500
1
05/16/24 02:22
TJW
V47319
Endrin Aldehyde
<0.0158
ug/L
0.0158
0.0500
1
05/16/24 02:22
TJW
V47319
Endrin Ketone
<0.0181
Ng/L
0.0181
0.100
1
05/16/24 02:22
TJW
V47319
gamma-BHC
<0.0061
ug/L
0.0061
0.0500
1
05/16/24 02:22
TJW
V47319
Heptachlor
<0.0130
Ng/L
0.0130
0.0500
1
05/16/24 02:22
TJW
V47319
Heptachlor Epoxide
<0.0224
ug/L
0.0224
0.100
1
05/16/24 02:22
TJW
V47319
Methoxychlor
<0.0179
Ng/L
0.0179
0.100
1
05/16/24 02:22
TJW
V47319
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 81 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102
REPOR T OF A NA L YSIS
Lab No : 92548
Matrix: Aqueous
Sample ID: MW-16
Sampled: 5/2/2024
14:45
Analytical Method: 8081B
Prep Batch(es):
V46914
05/07/24 10:07
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF Date / Time By
Analytical
Analyzed
Batch
Toxaphene
<0.350
Ng/L
0.350
1.00
1 05/16/24 02:22 TJW
V47319
Surrogate: Decachlorobiphenyl
74.3
Limits:
13-186%
1 05/16/24 02:22 TJW
V47319
Surrogate: Tetrachloro-m-xylene
89.1
Limits:
40-134%
1 05/16/24 02:22 TJW
V47319
Analytical Method: 8082A
Prep Batch(es):
V46915
05/07/24 10:07
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF Date / Time By
Analytical
Analyzed
Batch
Aroclor 1016
<0.210
u9/L
0.210
0.500
1 05/16/24 18:58 TJW
V47358
Aroclor1221
<0.110
Ng/L
0.110
1.00
1 05/16/24 18:58 TJW
V47358
Aroclor1232
<0.160
u9/L
0.160
0.500
1 05/16/24 18:58 TJW
V47358
Aroclor1242
<0.140
Ng/L
0.140
0.500
1 05/16/24 18:58 TJW
V47358
Aroclor 1248
<0.140
u9/L
0.140
0.500
1 05/16/24 18:58 TJW
V47358
Aroclor1254
<0.160
Ng/L
0.160
0.500
1 05/16/24 18:58 TJW
V47358
Aroclor 1260
<0.495
u9/L
0.495
1.00
1 05/16/24 18:58 TJW
V47358
Surrogate: Decachlorobiphenyl
81.6
Limits:
32-178%
1 05/16/24 18:58 TJW
8082A
Surrogate: Tetrachloro-m-xylene
65.1
Limits:
30-161%
1 05/16/24 18:58 TJW
8082A
Analytical Method: 8151A
Prep Batch(es):
L749619
05/09/24 13:10
Prep Method: 8151A
Test
Results
Units
MDL
MQL
DF Date / Time By
Analytical
Analyzed
Batch
2,4-D
<0.2120
u9/L
0.2120
0.2551
1 05/15/24 00:07 SWB
L750458
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 82 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92548
Matrix: Aqueous
Sample ID: MW-16
Sampled: 5/2/2024
14:45
Analytical Method:
8151A
Prep Batch(es):
L749619
05/09/24 13:10
Prep Method:
8151A
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Dalapon
<0.5254
Ng/L
0.5254
0.5612
1
05/15/24 00:07
SWB
L750458
2,4-DB
<0.1392
ug/L
0.1392
0.2551
1
05/15/24 00:07
SWB
L750458
Dicamba
<0.05814
Ng/L
0.05814
0.1020
1
05/15/24 00:07
SWB
L750458
Dichlorprop
<0.08118
ug/L
0.08118
0.1020
1
05/15/24 00:07
SWB
L750458
Dinoseb
<0.02751
Ng/L
0.02751
0.1020
1
05/15/24 00:07
SWB
L750458
MCPA
<19.37
ug/L
19.37
51.02
1
05/15/24 00:07
SWB
L750458
MCPP
<11.99
Ng/L
11.99
51.02
1
05/15/24 00:07
SWB
L750458
Picloram
<0.04618
ug/L
0.04618
0.1020
1
05/15/24 00:07
SWB
L750458
2,4,5-T
<0.1023
Ng/L
0.1023
0.1276
1
05/15/24 00:07
SWB
L750458
2,4,5-TP (Silvex)
<0.01666
ug/L
0.01666
0.1020
1
05/15/24 00:07
SWB
L750458
Surrogate: DCAA
94.12
Limits:
20-150%
1 05/15/24 00:07 SWB
L750458
Analytical Method:
8260D
Prep Batch(es):
V47200
05/09/24 14:00
V47336
05/14/24 14:00
Prep Method:
5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
2.833
ug/L
1.80
5.00
1
05/10/24 09:19
MSA
V47202
Acetonitrile
<10.0
Ng/L
10.0
10.0
1
05/15/2416:30
MSA
V47337
Acrolein
<2.00
ug/L
2.00
5.00
1
05/10/24 09:19
MSA
V47202
Acrylonitrile
<0.230
Ng/L
0.230
5.00
1
05/10/24 09:19
MSA
V47202
Allyl Chloride
<0.579
ug/L
0.579
10.0
1
05/15/24 16:30
MSA
V47337
Benzene
0.663
Ng/L
0.180
0.500
1
05/10/24 09:19
MSA
V47202
Bromochloromethane
<0.420
ug/L
0.420
1.00
1
05/10/24 09:19
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 83 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92548
Matrix: Aqueous
Sample ID: MW-16
Sampled: 5/2/2024 14:45
Analytical Method: 8260D
Prep Batch(es):
V47200
05/09/24 14:00
V47336
05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
05/10/24 09:19
MSA
V47202
Bromoform
<1.50
ug/L
1.50
5.00
1
05/10/24 09:19
MSA
V47202
Bromomethane
<0.280
Ng/L
0.280
1.00
1
05/10/24 09:19
MSA
V47202
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
05/10/24 09:19
MSA
V47202
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
05/10/24 09:19
MSA
V47202
Chlorobenzene
3.36
ug/L
0.190
0.500
1
05/10/24 09:19
MSA
V47202
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
05/10/24 09:19
MSA
V47202
Chloroethane
<0.430
ug/L
0.430
1.00
1
05/10/24 09:19
MSA
V47202
Chloroform
<0.220
Ng/L
0.220
0.500
1
05/10/24 09:19
MSA
V47202
Chloromethane
<0.220
ug/L
0.220
0.500
1
05/10/24 09:19
MSA
V47202
Chloroprene
<0.450
Ng/L
0.450
10.0
1
05/15/24 16:30
MSA
V47337
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
05/10/24 09:19
MSA
V47202
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
05/10/24 09:19
MSA
V47202
Dibromomethane
<0.230
ug/L
0.230
0.500
1
05/10/24 09:19
MSA
V47202
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
05/10/24 09:19
MSA
V47202
1,2-Dichlorobenzene
0.4283
ug/L
0.220
0.500
1
05/10/24 09:19
MSA
V47202
1,3-Dichlorobenzene
<0.190
Ng/L
0.190
0.500
1
05/10/24 09:19
MSA
V47202
1,4-Dichlorobenzene
7.28
ug/L
0.210
0.500
1
05/10/24 09:19
MSA
V47202
Dichlorodifluoromethane
<1.20
Ng/L
1.20
5.00
1
05/10/24 09:19
MSA
V47202
1,1-Dichloroethane
0.3661
ug/L
0.240
0.500
1
05/10/24 09:19
MSA
V47202
1,2-Dichloroethane
1.18
Ng/L
0.150
0.500
1
05/10/24 09:19
MSA
V47202
1,1-Dichloroethene
<0.150
ug/L
0.150
0.500
1
05/10/24 09:19
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 84 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92548
Matrix: Aqueous
Sample ID: MW-16
Sampled: 5/2/2024 14:45
Analytical Method: 8260D
Prep Batch(es):
V47200
05/09/24 14:00
V47336
05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
cis- 1,2-Dich loroethene
10.1
Ng/L
0.200
0.500
1
05/10/24 09:19
MSA
V47202
trans- 1.2-Dichloroethene
<0.180
ug/L
0.180
0.500
1
05/10/24 09:19
MSA
V47202
1,2-Dichloropropane
0.682
Ng/L
0.190
0.500
1
05/10/24 09:19
MSA
V47202
1,3-Dichloropropane
<0.130
ug/L
0.130
0.500
1
05/10/24 09:19
MSA
V47202
2,2-Dichloropropane
<0.210
Ng/L
0.210
2.00
1
05/10/24 09:19
MSA
V47202
1,1-Dichloropropene
<0.200
ug/L
0.200
0.500
1
05/10/24 09:19
MSA
V47202
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
05/10/24 09:19
MSA
V47202
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
05/10/24 09:19
MSA
V47202
Ethyl Methacrylate
<1.62
Ng/L
1.62
10.0
1
05/15/24 16:30
MSA
V47337
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
05/10/24 09:19
MSA
V47202
Hexachlorobutadiene
<0.350
Ng/L
0.350
2.00
1
05/10/24 09:19
MSA
V47202
2-Hexanone
<0.380
ug/L
0.380
5.00
1
05/10/24 09:19
MSA
V47202
Iodomethane
<0.054
Ng/L
0.054
0.500
1
05/10/24 09:19
MSA
V47202
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
05/10/24 09:19
MSA
V47202
Methacrylonitrile
<10.0
Ng/L
10.0
10.0
1
05/15/2416:30
MSA
V47337
4-Methyl-2-Pentanone
<1.00
ug/L
1.00
5.00
1
05/10/24 09:19
MSA
V47202
Methylene Chloride
<0.330
Ng/L
0.330
1.00
1
05/10/24 09:19
MSA
V47202
Naphthalene
<0.470
ug/L
0.470
1.00
1
05/10/24 09:19
MSA
V47202
Propionitrile
<10.0
Ng/L
10.0
10.0
1
05/15/2416:30
MSA
V47337
Styrene
<0.220
ug/L
0.220
0.500
1
05/10/24 09:19
MSA
V47202
1,1,1,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
05/10/24 09:19
MSA
V47202
1,1,2,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
05/10/24 09:19
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 85 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92548
Matrix: Aqueous
Sample ID: MW-16
Sampled: 5/2/2024
14:45
Analytical Method: 8260D
Prep Batch(es):
V47200 05/09/24 14:00
V47336 05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Tetrachloroethene
<0.220
Ng/L
0.220 0.500
1
05/10/24 09:19 MSA
V47202
Tetrahydrofuran
<1.50
ug/L
1.50 10.0
1
05/10/24 09:19 MSA
V47202
Toluene
<0.220
Ng/L
0.220 0.500
1
05/10/24 09:19 MSA
V47202
1,2,4-Trichlorobenzene
0.3803
ug/L
0.310 1.00
1
05/10/24 09:19 MSA
V47202
1,1,1-Trichloroethane
<0.160
Ng/L
0.160 0.500
1
05/10/24 09:19 MSA
V47202
1,1,2-Trichloroethane
<0.096
ug/L
0.096 0.500
1
05/10/24 09:19 MSA
V47202
Trichloroethene
<0.180
Ng/L
0.180 0.500
1
05/10/24 09:19 MSA
V47202
Trichlorofluoromethane
<0.180
ug/L
0.180 0.500
1
05/10/24 09:19 MSA
V47202
1,2,3-Trichloropropane
<0.270
Ng/L
0.270 1.00
1
05/10/24 09:19 MSA
V47202
Vinyl Acetate
<1.00 M
ug/L
1.00 2.00
1
05/10/24 09:19 MSA
V47202
Vinyl Chloride
2.09
Ng/L
0.170 0.500
1
05/10/24 09:19 MSA
V47202
o-Xylene
<0.210
ug/L
0.210 0.500
1
05/10/24 09:19 MSA
V47202
m,p-Xylene
<0.420
Ng/L
0.420 1.00
1
05/10/24 09:19 MSA
V47202
Xylene (Total)
<0.21
ug/L
0.210 0.500
1
05/10/24 09:19
V47202
Surrogate: 4-Bromofluorobenzene
102
Limits: 80-124%
1 05/10/24 09:19 MSA
V47202
Surrogate: Dibromofluoromethane
101
Limits: 75-129%
1 05/10/24 09:19 MSA
V47202
Surrogate: 1,2-Dichloroethane - d4
100
Limits: 63-136%
1 05/10/24 09:19 MSA
V47202
Surrogate: Toluene-d8
101
Limits: 77-123%
1 05/10/24 09:19 MSA
V47202
Surrogate:4-Bromofluorobenzene
99.4
Limits:80-124%
1 05/15/24 16:30 MSA
V47337
Surrogate: Dibromofluoromethane
104
Limits: 75-129%
1 05/15/24 16:30 MSA
V47337
Surrogate: 1,2-Dichloroethane - d4
105
Limits: 63-136%
1 05/15/24 16:30 MSA
V47337
Surrogate: Toluene-d8
106
Limits: 77-123%
1 05/15/24 16:30 MSA
V47337
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 86 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
01186
Smith & Gardner, Inc.
Project
Seth C. Rickerts
14 N. Boylan Avenue
Information
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Surry County C&D/MSW Spring
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Report Date : 05/31/2024
Received : 05/03/2024
Lab No : 92548 Matrix: Aqueous
Sample ID: MW-16 Sampled: 5/2/2024 14:45
Analytical Method: 8270C Prep Batch(es): L749277 05/08/24 12:10
Prep Method: 3510C
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Dimethoate
<0.720
Ng/L
0.720
1.01
1
05/08/24 20:26
SMB
L749502
Disulfoton
<0.470
ug/L
0.470
1.01
1
05/08/24 20:26
SMB
L749502
Ethyl Parathion
<0.573
Ng/L
0.573
1.01
1
05/08/24 20:26
SMB
L749502
Famphur
<0.517
ug/L
0.517
1.01
1
05/08/24 20:26
SMB
L749502
Methyl Parathion
<0.813
Ng/L
0.813
1.01
1
05/08/24 20:26
SMB
L749502
Phorate
<0.665
ug/L
0.665
1.01
1
05/08/24 20:26
SMB
L749502
Surrogate: Tributyl phosphate
75.2
Limits:
50-150%
1 05/08/24 20:26 SMB
8270C
Surrogate: Triphenyl phosphate
89.6
Limits:
50-150%
1 05/08/24 20:26 SMB
8270C
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,3-Dinitrobenzene
<0.904
ug/L
0.904
10.0
1
05/08/24 22:02
SMB
L749499
1,3,5-Trinitrobenzene
<10.1
Ng/L
10.1
10.1
1
05/08/24 22:02
SMB
L749501
Acenaphthene
<0.563
ug/L
0.563
2.00
1
05/08/24 22:02
SMB
L749499
Acenaphthylene
<0.562
Ng/L
0.562
2.00
1
05/08/24 22:02
SMB
L749499
Acetophenone
<0.689
ug/L
0.689
5.00
1
05/08/24 22:02
SMB
L749499
Anthracene
<0.536
Ng/L
0.536
2.00
1
05/08/24 22:02
SMB
L749499
Benzo(a)anthracene
<0.520
ug/L
0.520
2.00
1
05/08/24 22:02
SMB
L749499
Benzo(a)pyrene
<0.511
Ng/L
0.511
2.00
1
05/08/24 22:02
SMB
L749499
Benzo(b)fluoranthene
<0.631
ug/L
0.631
2.00
1
05/08/24 22:02
SMB
L749499
Benzo(g,h,i)perylene
<0.507
Ng/L
0.507
2.00
1
05/08/24 22:02
SMB
L749499
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 87 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92548
Matrix: Aqueous
Sample ID: MW-16
Sampled: 5/2/2024 14:45
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Benzo(k)fluoranthene
<0.575
Ng/L
0.575
2.00
1
05/08/24 22:02
SMB
L749499
Benzyl alcohol
<1.02
ug/L
1.02
10.0
1
05/08/24 22:02
SMB
L749499
Bis(2-Chloroethoxy)methane
<0.592
Ng/L
0.592
5.00
1
05/08/24 22:02
SMB
L749499
Bis(2-Chloroethyl)ether
<0.627
ug/L
0.627
5.00
1
05/08/24 22:02
SMB
L749499
Bis(2-Chloroisopropyl)ether
<0.656
Ng/L
0.656
5.00
1
05/08/24 22:02
SMB
L749499
Bis(2-ethylhexyl)phthalate
<0.796
ug/L
0.796
5.00
1
05/08/24 22:02
SMB
L749499
4-Bromophenyl phenyl ether
<0.567
Ng/L
0.567
5.00
1
05/08/24 22:02
SMB
L749499
Butyl benzyl phthalate
<0.756
ug/L
0.756
5.00
1
05/08/24 22:02
SMB
L749499
4-Chloro-3-methylphenol
<0.550
Ng/L
0.550
5.00
1
05/08/24 22:02
SMB
L749499
4-Chloroaniline
<0.530
ug/L
0.530
5.00
1
05/08/24 22:02
SMB
L749499
Chlorobenzilate
<0.999
Ng/L
0.999
5.00
1
05/08/24 22:02
SMB
L749499
2-Chloronaphthalene
<0.560
ug/L
0.560
5.00
1
05/08/24 22:02
SMB
L749499
2-Chlorophenol
<0.457
Ng/L
0.457
5.00
1
05/08/24 22:02
SMB
L749499
4-Chlorophenyl phenyl ether
<0.615
ug/L
0.615
5.00
1
05/08/24 22:02
SMB
L749499
Chrysene
<0.550
Ng/L
0.550
2.00
1
05/08/24 22:02
SMB
L749499
Dibenz(a,h)anthracene
<0.460
ug/L
0.460
2.00
1
05/08/24 22:02
SMB
L749499
Dibenzofuran
<0.584
Ng/L
0.584
5.00
1
05/08/24 22:02
SMB
L749499
1,2-Dichlorobenzene
<0.466
ug/L
0.466
5.00
1
05/08/24 22:02
SMB
L749499
1,3-Dichlorobenzene
<0.436
Ng/L
0.436
5.00
1
05/08/24 22:02
SMB
L749499
1,4-Dichlorobenzene
4.683
ug/L
0.405
5.00
1
05/08/24 22:02
SMB
L749499
3,3'-Dichlorobenzidine
<10.3
Ng/L
10.3
20.0
1
05/08/24 22:02
SMB
L749499
2,4-Dichlorophenol
<0.606
ug/L
0.606
5.00
1
05/08/24 22:02
SMB
L749499
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 88 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92548
Matrix: Aqueous
Sample ID: MW-16
Sampled: 5/2/2024 14:45
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
2,6-Dichlorophenol
<0.655
Ng/L
0.655
5.00
1
05/08/24 22:02
SMB
L749499
Diethyl phthalate
<0.686
ug/L
0.686
5.00
1
05/08/24 22:02
SMB
L749499
Dimethyl phthalate
<0.652
Ng/L
0.652
5.00
1
05/08/24 22:02
SMB
L749499
3,3' Dimethylbenzidine
<9.01
ug/L
9.01
10.0
1
05/08/24 22:02
SMB
L749499
2,4-Dimethyl phenol
<0.620
Ng/L
0.620
5.00
1
05/08/24 22:02
SMB
L749499
Di-n-butyl phthalate
<0.740
ug/L
0.740
5.00
1
05/08/24 22:02
SMB
L749499
4,6-Dinitro-2- methyl phenol
<6.08
Ng/L
6.08
10.0
1
05/08/24 22:02
SMB
L749499
2,4-Dinitrophenol
<18.9
ug/L
18.9
20.0
1
05/08/24 22:02
SMB
L749499
2,4-Dinitrotoluene
<0.911
Ng/L
0.911
5.00
1
05/08/24 22:02
SMB
L749499
2,6-Dinitrotoluene
<0.734
ug/L
0.734
5.00
1
05/08/24 22:02
SMB
L749499
Di-n-Octyl Phthalate
<1.32
Ng/L
1.32
5.00
1
05/08/24 22:02
SMB
L749499
Ethyl methanesulfonate
<0.660
ug/L
0.660
5.00
1
05/08/24 22:02
SMB
L749499
Fluoranthene
<0.583
Ng/L
0.583
2.00
1
05/08/24 22:02
SMB
L749499
Fluorene
<0.617
ug/L
0.617
2.00
1
05/08/24 22:02
SMB
L749499
Hexachlorobenzene
<0.537
Ng/L
0.537
5.00
1
05/08/24 22:02
SMB
L749499
Hexachlorobutadiene
<0.411
ug/L
0.411
5.00
1
05/08/24 22:02
SMB
L749499
Hexachlorocyclopentadiene
<0.889
Ng/L
0.889
5.00
1
05/08/24 22:02
SMB
L749499
Hexachloroethane
<0.482
ug/L
0.482
5.00
1
05/08/24 22:02
SMB
L749499
Indeno(1,2,3-cd)pyrene
<0.490
Ng/L
0.490
2.00
1
05/08/24 22:02
SMB
L749499
Isodrin
<10.1
ug/L
10.1
10.1
1
05/08/24 22:02
SMB
L749501
Isophorone
<0.591
Ng/L
0.591
5.00
1
05/08/24 22:02
SMB
L749499
Kepone
<10.1 M
ug/L
10.1
10.1
1
05/08/24 22:02
SMB
L749501
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 89 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92548
Matrix: Aqueous
Sample ID: MW-16
Sampled: 5/2/2024 14:45
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Methyl methanesulfonate
<0.746
Ng/L
0.746
5.00
1
05/08/24 22:02
SMB
L749499
2-Methylnaphthalene
<0.569
ug/L
0.569
2.00
1
05/08/24 22:02
SMB
L749499
2-Methylphenol
<0.449
Ng/L
0.449
5.00
1
05/08/24 22:02
SMB
L749499
3&4 Methylphenol
<0.453
ug/L
0.453
5.00
1
05/08/24 22:02
SMB
L749499
Naphthalene
<1.70
Ng/L
1.70
2.00
1
05/08/24 22:02
SMB
L749499
2-Nitroaniline
<0.766
ug/L
0.766
5.00
1
05/08/24 22:02
SMB
L749499
3-Nitroaniline
<0.912
Ng/L
0.912
10.0
1
05/08/24 22:02
SMB
L749499
4-Nitroaniline
<12.5
ug/L
12.5
20.0
1
05/08/24 22:02
SMB
L749499
Nitrobenzene
<0.715
Ng/L
0.715
5.00
1
05/08/24 22:02
SMB
L749499
2-Nitrophenol
<0.728
ug/L
0.728
5.00
1
05/08/24 22:02
SMB
L749499
4-Nitrophenol
<1.94
Ng/L
1.94
10.0
1
05/08/24 22:02
SMB
L749499
N-Nitrosodimethylamine
<0.295
ug/L
0.295
5.00
1
05/08/24 22:02
SMB
L749499
N-Nitrosodiphenylamine
<0.487
Ng/L
0.487
10.0
1
05/08/24 22:02
SMB
L749499
N-Nitrosodiethylamine
<0.535
ug/L
0.535
5.00
1
05/08/24 22:02
SMB
L749499
N-Nitroso-di-n-butylamine
<0.699
Ng/L
0.699
5.00
1
05/08/24 22:02
SMB
L749499
N-Nitroso-di-n-propylamine
<0.678
ug/L
0.678
5.00
1
05/08/24 22:02
SMB
L749499
Pentachlorobenzene
<0.574
Ng/L
0.574
10.0
1
05/08/24 22:02
SMB
L749499
Pentachloronitrobenzene
<0.569
ug/L
0.569
5.00
1
05/08/24 22:02
SMB
L749499
Pentachlorophenol
<1.23
Ng/L
1.23
10.0
1
05/08/24 22:02
SMB
L749499
Phenacetin
<0.693
ug/L
0.693
5.00
1
05/08/24 22:02
SMB
L749499
Phenanthrene
<0.582
Ng/L
0.582
2.00
1
05/08/24 22:02
SMB
L749499
Phenol
<0.258
ug/L
0.258
5.00
1
05/08/24 22:02
SMB
L749499
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 90 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
01186
Smith & Gardner, Inc.
Project
Seth C. Rickerts
14 N. Boylan Avenue
Information
Raleigh , NC 27603
Report Number : 24-124-0102
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Surry County C&D/MSW Spring
REPORT OF ANAL YSIS
Report Date : 05/31/2024
Received : 05/03/2024
Lab No : 92548 Matrix: Aqueous
Sample ID: MW-16 Sampled: 5/2/2024 14:45
Analytical Method: 8270D
Prep Method: 3510C
Test Results
Pyrene
<0.680
1,2,4,5-Tetrachlorobenzene
<0.463
2,3,4,6-Tetrachlorophenol
<0.570
1,2,4-Trichlorobenzene
<0.433
2,4,5-Trichlorophenol
<0.611
2,4,6-Trichlorophenol
<0.539
Surrogate: 2-Fluorobiphenyl
Surrogate: 2-Fluorophenol
Surrogate: Nitrobenzene-d5
Surrogate: Phenol-d6
Surrogate: 4-Terphenyl-d 14
Surrogate: 2,4,6-Tribromophenol
Prep Batch(es): L749275 05/08/24 12:10
Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.680 2.00
Pg/L
0.463 5.00
Ng/L
0.570 5.00
ug/L
0.433 5.00
Ng/L
0.611 5.00
Pg/L
0.539 5.00
59.1
Limits: 24-93%
31.3
Limits: 10-44%
56.5
Limits: 20-91%
23.4
Limits: 7-32%
71.0
Limits: 35-126%
70.3
Limits: 39-110%
1 05/08/24 22:02 SMB
L749499
1 05/08/24 22:02 SMB
L749499
1 05/08/24 22:02 SMB
L749499
1 05/08/24 22:02 SMB
L749499
1 05/08/24 22:02 SMB
L749499
1 05/08/24 22:02 SMB
L749499
1 05/08/24 22:02 SMB
L749499
1 05/08/24 22:02 SMB
L749499
1 05/08/24 22:02 SMB
L749499
1 05/08/24 22:02 SMB
L749499
1 05/08/24 22:02 SMB
L749499
1 05/08/24 22:02 SMB
L749499
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor H Beyond holding time
J Estimated value M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 91 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102
REPOR T OF A NA L YSIS
Lab No : 92549
Matrix: Aqueous
Sample ID: MW-15
Sampled: 5/2/2024 14:15
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Sulfate
3510
Ng/L
600
2000
1
05/03/2417:43
NDL
9056A
Ferrous Iron
1.81 H
mg/L
0.05
0.20
1
05/03/24 13:40
GOB
SM-3500-Fe-B
Ethane
<2.67
Ng/L
2.67
10.0
1
05/06/24 14:17
TBL
RSK-175
Ethene
<2.28
ug/L
2.28
10.0
1
05/06/24 14:17
TBL
RSK-175
Methane
978
Ng/L
2.51
10.0
1
05/06/24 14:17
TBL
RSK-175
1,4-Dioxane
<0.139
ug/L
0.139
2.00
1
05/07/24 10:18
TBL
8260D SIM
1,4-Naphthoquinone
<10.3 M
Ng/L
10.3
10.3
1
05/08/24 22:23
SMB
8270D
1-Naphthylamine
<10.3
ug/L
10.3
10.3
1
05/08/24 22:23
SMB
8270D
2-Acetylaminofluorene
<10.3
Ng/L
10.3
10.3
1
05/08/24 22:23
SMB
8270D
2-Naphthylamine
<10.3
ug/L
10.3
10.3
1
05/08/24 22:23
SMB
8270D
3-Methylcholanthrene
<10.3
Ng/L
10.3
10.3
1
05/08/24 22:23
SMB
8270D
4-Aminobiphenyl
<10.3
ug/L
10.3
10.3
1
05/08/24 22:23
SMB
8270D
5-Nitro-o-toluidine
<10.3
Ng/L
10.3
10.3
1
05/08/24 22:23
SMB
8270D
7,12-Di methyl benz(a)anth racene
<10.3
ug/L
10.3
10.3
1
05/08/24 22:23
SMB
8270D
Diallate
<10.3
Ng/L
10.3
10.3
1
05/08/24 22:23
SMB
8270D
Hexachloropropene
<10.3
ug/L
10.3
10.3
1
05/08/24 22:23
SMB
8270D
Isosafrole
<10.3
Ng/L
10.3
10.3
1
05/08/24 22:23
SMB
8270D
Methapyrilene
<10.3
ug/L
10.3
20.6
1
05/08/24 22:23
SMB
8270D
N-Nitrosomethylethylamine
<10.3
Ng/L
10.3
10.3
1
05/08/24 22:23
SMB
8270D
N-Nitrosomorpholine
<10.3
ug/L
10.3
10.3
1
05/08/24 22:23
SMB
8270D
N-Nitrosopyrrolidine
<10.3
Ng/L
10.3
10.3
1
05/08/24 22:23
SMB
8270D
N-Nitrosopiperidine
<10.3
ug/L
10.3
10.3
1
05/08/24 22:23
SMB
8270D
0,0,0-Triethyl Phosphorothioate
<0.339
Ng/L
0.339
1.03
1
05/08/24 20:40
SMB
8270C
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum
value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 92 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102
REPOR T OF A NA L YSIS
Lab No : 92549
Matrix: Aqueous
Sample ID: MW-15
Sampled: 5/2/2024 14:15
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
o-Toluidine
<10.3
Ng/L
10.3
10.3
1
05/08/24 22:23
SMB
8270D
p-Dimethylaminoazobenzene
<10.3
ug/L
10.3
10.3
1
05/08/24 22:23
SMB
8270D
p-Phenylenediamine
<10.3 M
Ng/L
10.3
10.3
1
05/08/24 22:23
SMB
8270D
Pronamide
<10.3
ug/L
10.3
10.3
1
05/08/24 22:23
SMB
8270D
Safrole
<10.3
Ng/L
10.3
10.3
1
05/08/24 22:23
SMB
8270D
Thionazine
<0.339
ug/L
0.339
1.03
1
05/08/24 20:40
SMB
8270C
Alkalinity (as CaCO3)
45000
Ng/L
800
5000
1
05/08/24 15:40
RLW
2320B-2011
Biochemical Oxygen Demand (5-day)
<2000
ug/L
2000
2000
1
05/03/24 10:39
MLW
521OB-2015
Chloride
1490
Ng/L
500
1000
1
05/03/2417:43
NDL
9056A
Cyanide, Total
<12.0
ug/L
12.0
25.0
1
05/15/24 10:52
RLW
9014
COD (Chemical Oxygen Demand)
210003
Ng/L
15000
30000
1
05/09/24 11:25
SLO
5220D-2011
Nitrate (NO3-N)
67.03
ug/L
50.0
100
1
05/03/24 17:43
NDL
9056A
TOC
1040
Ng/L
720
1000
1
05/09/24 06:27
AT
531OC-2011
Sulfide
<830
ug/L
830
2000
1
05/06/2414:53
GOB
4500S2F-2011
Antimony
<0.618
Ng/L
0.618
1.00
1
05/14/24 00:54
TJS
6020B
Arsenic
0.3283
ug/L
0.297
1.00
1
05/14/24 00:54
TJS
6020B
Barium
241
Ng/L
0.453
1.00
1
05/14/24 00:54
TJS
6020B
Beryllium
1.86
ug/L
0.102
1.00
1
05/14/24 00:54
TJS
6020B
Cadmium
0.5093
Ng/L
0.350
1.00
1
05/14/24 19:45
CPW
6020B
Chromium
43.9
ug/L
0.346
1.00
1
05/14/24 00:54
CPW
6020B
Cobalt
8.10
Ng/L
0.060
1.00
1
05/14/24 00:54
TJS
6020B
Copper
17.8
ug/L
0.489
1.00
1
05/14/24 00:54
TJS
6020B
Lead
9.96
Ng/L
0.264
1.00
1
05/14/24 00:54
TJS
6020B
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum
value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 93 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92549
Sample ID: MW-15
Matrix: Aqueous
Sampled: 5/2/2024 14:15
Test
Results
Units
MDL
MQL
DF
Date / Time By Analytical
Analyzed Method
Mercury (Total)
<0.100
Ng/L
0.100
0.200
1
05/13/24 14:55 FDS 7470A
Nickel
16.2
ug/L
0.182
1.00
1
05/14/24 00:54 CPW 6020B
Selenium
0.7313
Ng/L
0.703
1.00
1
05/14/24 00:54 TJS 6020E
Silver
0.0657 J
ug/L
0.0570
1.00
1
05/14/24 19:45 CPW 6020B
Tin
3.29 JB
Ng/L
1.44
5.00
1
05/14/24 00:54 TJS 6020B
Thallium
0.5773
ug/L
0.0610
1.00
1
05/14/24 00:54 TJS 6020B
Vanadium
59.5
Ng/L
0.767
5.00
1
05/14/24 00:54 TJS 6020B
Zinc
108
ug/L
4.67
10.0
1
05/14/24 19:45 CPW 6020B
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor H Beyond holding time
J Estimated value M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 94 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92549
Matrix: Aqueous
Sample ID: MW-15
Sampled: 5/2/2024 14:15
Analytical Method:
8081B
Prep Batch(es):
V46914
05/07/24 10:07
Prep Method:
3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Aldrin
<0.0152
Ng/L
0.0152
0.0500
1
05/16/24 02:36
TJW
V47319
alpha-BHC
<0.0063
ug/L
0.0063
0.0500
1
05/16/24 02:36
TJW
V47319
beta-BHC
<0.0111
Ng/L
0.0111
0.0500
1
05/16/24 02:36
TJW
V47319
delta-BHC
<0.0082
ug/L
0.0082
0.0500
1
05/16/24 02:36
TJW
V47319
Chlordane
<0.180
Ng/L
0.180
0.500
1
05/16/24 02:36
TJW
V47319
alpha -Chlordane
<0.0186
ug/L
0.0186
0.100
1
05/16/24 02:36
TJW
V47319
gamma -Chlordane
<0.0231
Ng/L
0.0231
0.100
1
05/16/24 02:36
TJW
V47319
4,4'-DDD
<0.0265
ug/L
0.0265
0.100
1
05/16/24 02:36
TJW
V47319
4,4'-DDE
<0.0218
Ng/L
0.0218
0.100
1
05/16/24 02:36
TJW
V47319
4,4'-DDT
<0.0176
ug/L
0.0176
0.100
1
05/16/24 02:36
TJW
V47319
Dieldrin
<0.0137
Ng/L
0.0137
0.0500
1
05/16/24 02:36
TJW
V47319
EndosulfanI
<0.0160
ug/L
0.0160
0.0500
1
05/16/24 02:36
TJW
V47319
Endosulfan II
<0.0121
Ng/L
0.0121
0.0500
1
05/16/24 02:36
TJW
V47319
Endosulfan Sulfate
<0.0165
ug/L
0.0165
0.0500
1
05/16/24 02:36
TJW
V47319
Endrin
<0.0136
Ng/L
0.0136
0.0500
1
05/16/24 02:36
TJW
V47319
Endrin Aldehyde
<0.0158
ug/L
0.0158
0.0500
1
05/16/24 02:36
TJW
V47319
Endrin Ketone
<0.0181
Ng/L
0.0181
0.100
1
05/16/24 02:36
TJW
V47319
gamma-BHC
<0.0061
ug/L
0.0061
0.0500
1
05/16/24 02:36
TJW
V47319
Heptachlor
<0.0130
Ng/L
0.0130
0.0500
1
05/16/24 02:36
TJW
V47319
Heptachlor Epoxide
<0.0224
ug/L
0.0224
0.100
1
05/16/24 02:36
TJW
V47319
Methoxychlor
<0.0179
Ng/L
0.0179
0.100
1
05/16/24 02:36
TJW
V47319
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 95 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102
REPOR T OF A NA L YSIS
Lab No : 92549
Matrix: Aqueous
Sample ID: MW-15
Sampled: 5/2/2024
14:15
Analytical Method: 8081B
Prep Batch(es):
V46914
05/07/24 10:07
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF Date / Time By
Analytical
Analyzed
Batch
Toxaphene
<0.350
Ng/L
0.350
1.00
1 05/16/24 02:36 TJW
V47319
Surrogate: Decachlorobiphenyl
88.6
Limits:
13-186%
1 05/16/24 02:36 TJW
V47319
Surrogate: Tetrachloro-m-xylene
116
Limits:
40-134%
1 05/16/24 02:36 TJW
V47319
Analytical Method: 8082A
Prep Batch(es):
V46915
05/07/24 10:07
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF Date / Time By
Analytical
Analyzed
Batch
Aroclor 1016
<0.210
u9/L
0.210
0.500
1 05/16/24 19:12 TJW
V47358
Aroclor1221
<0.110
Ng/L
0.110
1.00
1 05/16/24 19:12 TJW
V47358
Aroclor1232
<0.160
u9/L
0.160
0.500
1 05/16/24 19:12 TJW
V47358
Aroclor1242
<0.140
Ng/L
0.140
0.500
1 05/16/24 19:12 TJW
V47358
Aroclor 1248
<0.140
u9/L
0.140
0.500
1 05/16/24 19:12 TJW
V47358
Aroclor1254
<0.160
Ng/L
0.160
0.500
1 05/16/24 19:12 TJW
V47358
Aroclor 1260
<0.495
u9/L
0.495
1.00
1 05/16/24 19:12 TJW
V47358
Surrogate: Decachlorobiphenyl
108
Limits:
32-178%
1 05/16/24 19:12 TJW
8082A
Surrogate: Tetrachloro-m-xylene
80.4
Limits:
30-161%
1 05/16/24 19:12 TJW
8082A
Analytical Method: 8151A
Prep Batch(es):
L749619
05/09/24 13:10
Prep Method: 8151A
Test
Results
Units
MDL
MQL
DF Date / Time By
Analytical
Analyzed
Batch
2,4-D
<0.2120
u9/L
0.2120
0.2551
1 05/15/24 00:31 SWB
L750458
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 96 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92549
Matrix: Aqueous
Sample ID: MW-15
Sampled: 5/2/2024
14:15
Analytical Method:
8151A
Prep Batch(es):
L749619
05/09/24 13:10
Prep Method:
8151A
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Dalapon
<0.5254
Ng/L
0.5254
0.5612
1
05/15/24 00:31
SWB
L750458
2,4-DB
<0.1392
ug/L
0.1392
0.2551
1
05/15/24 00:31
SWB
L750458
Dicamba
<0.05814
Ng/L
0.05814
0.1020
1
05/15/24 00:31
SWB
L750458
Dichlorprop
<0.08118
ug/L
0.08118
0.1020
1
05/15/24 00:31
SWB
L750458
Dinoseb
<0.02751
Ng/L
0.02751
0.1020
1
05/15/24 00:31
SWB
L750458
MCPA
<19.37
ug/L
19.37
51.02
1
05/15/24 00:31
SWB
L750458
MCPP
<11.99
Ng/L
11.99
51.02
1
05/15/24 00:31
SWB
L750458
Picloram
<0.04618
ug/L
0.04618
0.1020
1
05/15/24 00:31
SWB
L750458
2,4,5-T
<0.1023
Ng/L
0.1023
0.1276
1
05/15/24 00:31
SWB
L750458
2,4,5-TP (Silvex)
<0.01666
ug/L
0.01666
0.1020
1
05/15/24 00:31
SWB
L750458
Surrogate: DCAA
137.9
Limits:
20-150%
1 05/15/24 00:31
SWB
L750458
Analytical Method:
8260D
Prep Batch(es):
V47200
05/09/24 14:00
V47336
05/14/24 14:00
Prep Method:
5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
ug/L
1.80
5.00
1
05/10/24 09:45
MSA
V47202
Acetonitrile
<10.0
Ng/L
10.0
10.0
1
05/15/2416:55
MSA
V47337
Acrolein
<2.00
ug/L
2.00
5.00
1
05/10/24 09:45
MSA
V47202
Acrylonitrile
<0.230
Ng/L
0.230
5.00
1
05/10/24 09:45
MSA
V47202
Allyl Chloride
<0.579
ug/L
0.579
10.0
1
05/15/24 16:55
MSA
V47337
Benzene
0.3533
Ng/L
0.180
0.500
1
05/10/24 09:45
MSA
V47202
Bromochloromethane
<0.420
ug/L
0.420
1.00
1
05/10/24 09:45
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 97 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92549
Matrix: Aqueous
Sample ID: MW-15
Sampled: 5/2/2024 14:15
Analytical Method: 8260D
Prep Batch(es):
V47200
05/09/24 14:00
V47336
05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
05/10/24 09:45
MSA
V47202
Bromoform
<1.50
ug/L
1.50
5.00
1
05/10/24 09:45
MSA
V47202
Bromomethane
<0.280
Ng/L
0.280
1.00
1
05/10/24 09:45
MSA
V47202
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
05/10/24 09:45
MSA
V47202
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
05/10/24 09:45
MSA
V47202
Chlorobenzene
3.62
ug/L
0.190
0.500
1
05/10/24 09:45
MSA
V47202
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
05/10/24 09:45
MSA
V47202
Chloroethane
0.4683
ug/L
0.430
1.00
1
05/10/24 09:45
MSA
V47202
Chloroform
<0.220
Ng/L
0.220
0.500
1
05/10/24 09:45
MSA
V47202
Chloromethane
<0.220
ug/L
0.220
0.500
1
05/10/24 09:45
MSA
V47202
Chloroprene
<0.450
Ng/L
0.450
10.0
1
05/15/24 16:55
MSA
V47337
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
05/10/24 09:45
MSA
V47202
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
05/10/24 09:45
MSA
V47202
Dibromomethane
<0.230
ug/L
0.230
0.500
1
05/10/24 09:45
MSA
V47202
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
05/10/24 09:45
MSA
V47202
1,2-Dichlorobenzene
0.2783
ug/L
0.220
0.500
1
05/10/24 09:45
MSA
V47202
1,3-Dichlorobenzene
<0.190
Ng/L
0.190
0.500
1
05/10/24 09:45
MSA
V47202
1,4-Dichlorobenzene
5.75
ug/L
0.210
0.500
1
05/10/24 09:45
MSA
V47202
Dichlorodifluoromethane
<1.20
Ng/L
1.20
5.00
1
05/10/24 09:45
MSA
V47202
1,1-Dichloroethane
4.63
ug/L
0.240
0.500
1
05/10/24 09:45
MSA
V47202
1,2-Dichloroethane
0.956
Ng/L
0.150
0.500
1
05/10/24 09:45
MSA
V47202
1,1-Dichloroethene
<0.150
ug/L
0.150
0.500
1
05/10/24 09:45
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 98 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92549
Matrix: Aqueous
Sample ID: MW-15
Sampled: 5/2/2024 14:15
Analytical Method: 8260D
Prep Batch(es):
V47200
05/09/24 14:00
V47336
05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
cis- 1,2-Dich loroethene
27.9
Ng/L
0.200
0.500
1
05/10/24 09:45
MSA
V47202
trans- 1.2-Dichloroethene
0.4863
ug/L
0.180
0.500
1
05/10/24 09:45
MSA
V47202
1,2-Dichloropropane
0.2423
Ng/L
0.190
0.500
1
05/10/24 09:45
MSA
V47202
1,3-Dichloropropane
<0.130
ug/L
0.130
0.500
1
05/10/24 09:45
MSA
V47202
2,2-Dichloropropane
<0.210
Ng/L
0.210
2.00
1
05/10/24 09:45
MSA
V47202
1,1-Dichloropropene
<0.200
ug/L
0.200
0.500
1
05/10/24 09:45
MSA
V47202
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
05/10/24 09:45
MSA
V47202
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
05/10/24 09:45
MSA
V47202
Ethyl Methacrylate
<1.62
Ng/L
1.62
10.0
1
05/15/24 16:55
MSA
V47337
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
05/10/24 09:45
MSA
V47202
Hexachlorobutadiene
<0.350
Ng/L
0.350
2.00
1
05/10/24 09:45
MSA
V47202
2-Hexanone
<0.380
ug/L
0.380
5.00
1
05/10/24 09:45
MSA
V47202
Iodomethane
<0.054
Ng/L
0.054
0.500
1
05/10/24 09:45
MSA
V47202
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
05/10/24 09:45
MSA
V47202
Methacrylonitrile
<10.0
Ng/L
10.0
10.0
1
05/15/2416:55
MSA
V47337
4-Methyl-2-Pentanone
<1.00
ug/L
1.00
5.00
1
05/10/24 09:45
MSA
V47202
Methylene Chloride
<0.330
Ng/L
0.330
1.00
1
05/10/24 09:45
MSA
V47202
Naphthalene
<0.470
ug/L
0.470
1.00
1
05/10/24 09:45
MSA
V47202
Propionitrile
<10.0
Ng/L
10.0
10.0
1
05/15/2416:55
MSA
V47337
Styrene
<0.220
ug/L
0.220
0.500
1
05/10/24 09:45
MSA
V47202
1,1,1,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
05/10/24 09:45
MSA
V47202
1,1,2,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
05/10/24 09:45
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 99 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92549
Matrix: Aqueous
Sample ID: MW-15
Sampled: 5/2/2024
14:15
Analytical Method: 8260D
Prep Batch(es):
V47200 05/09/24 14:00
V47336 05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Tetrachloroethene
<0.220
Ng/L
0.220 0.500
1
05/10/24 09:45 MSA
V47202
Tetrahydrofuran
<1.50
ug/L
1.50 10.0
1
05/10/24 09:45 MSA
V47202
Toluene
<0.220
Ng/L
0.220 0.500
1
05/10/24 09:45 MSA
V47202
1,2,4-Trichlorobenzene
<0.310
ug/L
0.310 1.00
1
05/10/24 09:45 MSA
V47202
1,1,1-Trichloroethane
<0.160
Ng/L
0.160 0.500
1
05/10/24 09:45 MSA
V47202
1,1,2-Trichloroethane
<0.096
ug/L
0.096 0.500
1
05/10/24 09:45 MSA
V47202
Trichloroethene
2.23
Ng/L
0.180 0.500
1
05/10/24 09:45 MSA
V47202
Trichlorofluoromethane
<0.180
ug/L
0.180 0.500
1
05/10/24 09:45 MSA
V47202
1,2,3-Trichloropropane
<0.270
Ng/L
0.270 1.00
1
05/10/24 09:45 MSA
V47202
Vinyl Acetate
<1.00 M
ug/L
1.00 2.00
1
05/10/24 09:45 MSA
V47202
Vinyl Chloride
3.83
Ng/L
0.170 0.500
1
05/10/24 09:45 MSA
V47202
o-Xylene
<0.210
ug/L
0.210 0.500
1
05/10/24 09:45 MSA
V47202
m,p-Xylene
<0.420
Ng/L
0.420 1.00
1
05/10/24 09:45 MSA
V47202
Xylene (Total)
<0.21
ug/L
0.210 0.500
1
05/10/24 09:45
V47202
Surrogate: 4-Bromofluorobenzene
101
Limits: 80-124%
1 05/10/24 09:45 MSA
V47202
Surrogate: Dibromofluoromethane
101
Limits: 75-129%
1 05/10/24 09:45 MSA
V47202
Surrogate: 1,2-Dichloroethane - d4
99.4
Limits: 63-136%
1 05/10/24 09:45 MSA
V47202
Surrogate: Toluene-d8
101
Limits: 77-123%
1 05/10/24 09:45 MSA
V47202
Surrogate:4-Bromofluorobenzene
100
Limits:80-124%
1 05/15/24 16:55 MSA
V47337
Surrogate: Dibromofluoromethane
104
Limits: 75-129%
1 05/15/24 16:55 MSA
V47337
Surrogate: 1,2-Dichloroethane - d4
107
Limits: 63-136%
1 05/15/24 16:55 MSA
V47337
Surrogate: Toluene-d8
107
Limits: 77-123%
1 05/15/24 16:55 MSA
V47337
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 100 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
01186
Smith & Gardner, Inc.
Project
Seth C. Rickerts
14 N. Boylan Avenue
Information
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Surry County C&D/MSW Spring
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Report Date : 05/31/2024
Received : 05/03/2024
Lab No : 92549 Matrix: Aqueous
Sample ID: MW-15 Sampled: 5/2/2024 14:15
Analytical Method: 8270C Prep Batch(es): L749277 05/08/24 12:10
Prep Method: 3510C
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Dimethoate
<0.734
Ng/L
0.734
1.03
1
05/08/24 20:40
SMB
L749502
Disulfoton
<0.479
ug/L
0.479
1.03
1
05/08/24 20:40
SMB
L749502
Ethyl Parathion
<0.585
Ng/L
0.585
1.03
1
05/08/24 20:40
SMB
L749502
Famphur
<0.527
ug/L
0.527
1.03
1
05/08/24 20:40
SMB
L749502
Methyl Parathion
<0.829
Ng/L
0.829
1.03
1
05/08/24 20:40
SMB
L749502
Phorate
<0.678
ug/L
0.678
1.03
1
05/08/24 20:40
SMB
L749502
Surrogate: Tributyl phosphate
79.1
Limits:
50-150%
1 05/08/24 20:40 SMB
8270C
Surrogate: Triphenyl phosphate
96.6
Limits:
50-150%
1 05/08/24 20:40 SMB
8270C
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,3-Dinitrobenzene
<0.904
ug/L
0.904
10.0
1
05/08/24 22:23
SMB
L749499
1,3,5-Trinitrobenzene
<10.3
Ng/L
10.3
10.3
1
05/08/24 22:23
SMB
L749501
Acenaphthene
<0.563
ug/L
0.563
2.00
1
05/08/24 22:23
SMB
L749499
Acenaphthylene
<0.562
Ng/L
0.562
2.00
1
05/08/24 22:23
SMB
L749499
Acetophenone
<0.689
ug/L
0.689
5.00
1
05/08/24 22:23
SMB
L749499
Anthracene
<0.536
Ng/L
0.536
2.00
1
05/08/24 22:23
SMB
L749499
Benzo(a)anthracene
<0.520
ug/L
0.520
2.00
1
05/08/24 22:23
SMB
L749499
Benzo(a)pyrene
<0.511
Ng/L
0.511
2.00
1
05/08/24 22:23
SMB
L749499
Benzo(b)fluoranthene
<0.631
ug/L
0.631
2.00
1
05/08/24 22:23
SMB
L749499
Benzo(g,h,i)perylene
<0.507
Ng/L
0.507
2.00
1
05/08/24 22:23
SMB
L749499
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 101 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92549
Matrix: Aqueous
Sample ID: MW-15
Sampled: 5/2/2024 14:15
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Benzo(k)fluoranthene
<0.575
Ng/L
0.575
2.00
1
05/08/24 22:23
SMB
L749499
Benzyl alcohol
<1.02
ug/L
1.02
10.0
1
05/08/24 22:23
SMB
L749499
Bis(2-Chloroethoxy)methane
<0.592
Ng/L
0.592
5.00
1
05/08/24 22:23
SMB
L749499
Bis(2-Chloroethyl)ether
<0.627
ug/L
0.627
5.00
1
05/08/24 22:23
SMB
L749499
Bis(2-Chloroisopropyl)ether
<0.656
Ng/L
0.656
5.00
1
05/08/24 22:23
SMB
L749499
Bis(2-ethylhexyl)phthalate
<0.796
ug/L
0.796
5.00
1
05/08/24 22:23
SMB
L749499
4-Bromophenyl phenyl ether
<0.567
Ng/L
0.567
5.00
1
05/08/24 22:23
SMB
L749499
Butyl benzyl phthalate
<0.756
ug/L
0.756
5.00
1
05/08/24 22:23
SMB
L749499
4-Chloro-3-methylphenol
<0.550
Ng/L
0.550
5.00
1
05/08/24 22:23
SMB
L749499
4-Chloroaniline
<0.530
ug/L
0.530
5.00
1
05/08/24 22:23
SMB
L749499
Chlorobenzilate
<0.999
Ng/L
0.999
5.00
1
05/08/24 22:23
SMB
L749499
2-Chloronaphthalene
<0.560
ug/L
0.560
5.00
1
05/08/24 22:23
SMB
L749499
2-Chlorophenol
<0.457
Ng/L
0.457
5.00
1
05/08/24 22:23
SMB
L749499
4-Chlorophenyl phenyl ether
<0.615
ug/L
0.615
5.00
1
05/08/24 22:23
SMB
L749499
Chrysene
<0.550
Ng/L
0.550
2.00
1
05/08/24 22:23
SMB
L749499
Dibenz(a,h)anthracene
<0.460
ug/L
0.460
2.00
1
05/08/24 22:23
SMB
L749499
Dibenzofuran
<0.584
Ng/L
0.584
5.00
1
05/08/24 22:23
SMB
L749499
1,2-Dichlorobenzene
<0.466
ug/L
0.466
5.00
1
05/08/24 22:23
SMB
L749499
1,3-Dichlorobenzene
<0.436
Ng/L
0.436
5.00
1
05/08/24 22:23
SMB
L749499
1,4-Dichlorobenzene
3.20 J
ug/L
0.405
5.00
1
05/08/24 22:23
SMB
L749499
3,3'-Dichlorobenzidine
<10.3
Ng/L
10.3
20.0
1
05/08/24 22:23
SMB
L749499
2,4-Dichlorophenol
<0.606
ug/L
0.606
5.00
1
05/08/24 22:23
SMB
L749499
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 102 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92549
Matrix: Aqueous
Sample ID: MW-15
Sampled: 5/2/2024 14:15
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
2,6-Dichlorophenol
<0.655
Ng/L
0.655
5.00
1
05/08/24 22:23
SMB
L749499
Diethyl phthalate
<0.686
ug/L
0.686
5.00
1
05/08/24 22:23
SMB
L749499
Dimethyl phthalate
<0.652
Ng/L
0.652
5.00
1
05/08/24 22:23
SMB
L749499
3,3' Dimethylbenzidine
<9.01
ug/L
9.01
10.0
1
05/08/24 22:23
SMB
L749499
2,4-Dimethyl phenol
<0.620
Ng/L
0.620
5.00
1
05/08/24 22:23
SMB
L749499
Di-n-butyl phthalate
<0.740
ug/L
0.740
5.00
1
05/08/24 22:23
SMB
L749499
4,6-Dinitro-2- methyl phenol
<6.08
Ng/L
6.08
10.0
1
05/08/24 22:23
SMB
L749499
2,4-Dinitrophenol
<18.9
ug/L
18.9
20.0
1
05/08/24 22:23
SMB
L749499
2,4-Dinitrotoluene
<0.911
Ng/L
0.911
5.00
1
05/08/24 22:23
SMB
L749499
2,6-Dinitrotoluene
<0.734
ug/L
0.734
5.00
1
05/08/24 22:23
SMB
L749499
Di-n-Octyl Phthalate
<1.32
Ng/L
1.32
5.00
1
05/08/24 22:23
SMB
L749499
Ethyl methanesulfonate
<0.660
ug/L
0.660
5.00
1
05/08/24 22:23
SMB
L749499
Fluoranthene
<0.583
Ng/L
0.583
2.00
1
05/08/24 22:23
SMB
L749499
Fluorene
<0.617
ug/L
0.617
2.00
1
05/08/24 22:23
SMB
L749499
Hexachlorobenzene
<0.537
Ng/L
0.537
5.00
1
05/08/24 22:23
SMB
L749499
Hexachlorobutadiene
<0.411
ug/L
0.411
5.00
1
05/08/24 22:23
SMB
L749499
Hexachlorocyclopentadiene
<0.889
Ng/L
0.889
5.00
1
05/08/24 22:23
SMB
L749499
Hexachloroethane
<0.482
ug/L
0.482
5.00
1
05/08/24 22:23
SMB
L749499
Indeno(1,2,3-cd)pyrene
<0.490
Ng/L
0.490
2.00
1
05/08/24 22:23
SMB
L749499
Isodrin
<10.3
ug/L
10.3
10.3
1
05/08/24 22:23
SMB
L749501
Isophorone
<0.591
Ng/L
0.591
5.00
1
05/08/24 22:23
SMB
L749499
Kepone
<10.3 M
u9/L
10.3
10.3
1
05/08/24 22:23
SMB
L749501
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 103 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92549
Matrix: Aqueous
Sample ID: MW-15
Sampled: 5/2/2024 14:15
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Methyl methanesulfonate
<0.746
Ng/L
0.746
5.00
1
05/08/24 22:23
SMB
L749499
2-Methylnaphthalene
<0.569
ug/L
0.569
2.00
1
05/08/24 22:23
SMB
L749499
2-Methylphenol
<0.449
Ng/L
0.449
5.00
1
05/08/24 22:23
SMB
L749499
3&4 Methylphenol
<0.453
ug/L
0.453
5.00
1
05/08/24 22:23
SMB
L749499
Naphthalene
<1.70
Ng/L
1.70
2.00
1
05/08/24 22:23
SMB
L749499
2-Nitroaniline
<0.766
ug/L
0.766
5.00
1
05/08/24 22:23
SMB
L749499
3-Nitroaniline
<0.912
Ng/L
0.912
10.0
1
05/08/24 22:23
SMB
L749499
4-Nitroaniline
<12.5
ug/L
12.5
20.0
1
05/08/24 22:23
SMB
L749499
Nitrobenzene
<0.715
Ng/L
0.715
5.00
1
05/08/24 22:23
SMB
L749499
2-Nitrophenol
<0.728
ug/L
0.728
5.00
1
05/08/24 22:23
SMB
L749499
4-Nitrophenol
<1.94
Ng/L
1.94
10.0
1
05/08/24 22:23
SMB
L749499
N-Nitrosodimethylamine
<0.295
ug/L
0.295
5.00
1
05/08/24 22:23
SMB
L749499
N-Nitrosodiphenylamine
<0.487
Ng/L
0.487
10.0
1
05/08/24 22:23
SMB
L749499
N-Nitrosodiethylamine
<0.535
ug/L
0.535
5.00
1
05/08/24 22:23
SMB
L749499
N-Nitroso-di-n-butylamine
<0.699
Ng/L
0.699
5.00
1
05/08/24 22:23
SMB
L749499
N-Nitroso-di-n-propylamine
<0.678
ug/L
0.678
5.00
1
05/08/24 22:23
SMB
L749499
Pentachlorobenzene
<0.574
Ng/L
0.574
10.0
1
05/08/24 22:23
SMB
L749499
Pentachloronitrobenzene
<0.569
ug/L
0.569
5.00
1
05/08/24 22:23
SMB
L749499
Pentachlorophenol
<1.23
Ng/L
1.23
10.0
1
05/08/24 22:23
SMB
L749499
Phenacetin
<0.693
ug/L
0.693
5.00
1
05/08/24 22:23
SMB
L749499
Phenanthrene
<0.582
Ng/L
0.582
2.00
1
05/08/24 22:23
SMB
L749499
Phenol
<0.258
ug/L
0.258
5.00
1
05/08/24 22:23
SMB
L749499
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 104 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
01186
Smith & Gardner, Inc.
Project
Seth C. Rickerts
14 N. Boylan Avenue
Information
Raleigh , NC 27603
Report Number : 24-124-0102
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Surry County C&D/MSW Spring
REPORT OF ANAL YSIS
Report Date : 05/31/2024
Received : 05/03/2024
Lab No : 92549 Matrix: Aqueous
Sample ID: MW-15 Sampled: 5/2/2024 14:15
Analytical Method: 8270D
Prep Method: 3510C
Test Results
Pyrene
<0.680
1,2,4,5-Tetrachlorobenzene
<0.463
2,3,4,6-Tetrachlorophenol
<0.570
1,2,4-Trichlorobenzene
<0.433
2,4,5-Trichlorophenol
<0.611
2,4,6-Trichlorophenol
<0.539
Surrogate: 2-Fluorobiphenyl
Surrogate: 2-Fluorophenol
Surrogate: Nitrobenzene-d5
Surrogate: Phenol-d6
Surrogate: 4-Terphenyl-d 14
Surrogate: 2,4,6-Tribromophenol
Prep Batch(es): L749275 05/08/24 12:10
Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.680 2.00
Pg/L
0.463 5.00
Ng/L
0.570 5.00
ug/L
0.433 5.00
Ng/L
0.611 5.00
Pg/L
0.539 5.00
58.4
Limits: 24-93%
33.8
Limits: 10-44%
57.9
Limits: 20-91%
23.2
Limits: 7-32%
67.1
Limits: 35-126%
68.8
Limits: 39-110%
1 05/08/24 22:23 SMB
L749499
1 05/08/24 22:23 SMB
L749499
1 05/08/24 22:23 SMB
L749499
1 05/08/24 22:23 SMB
L749499
1 05/08/24 22:23 SMB
L749499
1 05/08/24 22:23 SMB
L749499
1 05/08/24 22:23 SMB
L749499
1 05/08/24 22:23 SMB
L749499
1 05/08/24 22:23 SMB
L749499
1 05/08/24 22:23 SMB
L749499
1 05/08/24 22:23 SMB
L749499
1 05/08/24 22:23 SMB
L749499
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor H Beyond holding time
J Estimated value M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 105 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102
REPOR T OF A NA L YSIS
Lab No : 92550
Matrix: Aqueous
Sample ID: MW-14
Sampled: 5/2/2024 14:30
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Sulfate
4510
Ng/L
600
2000
1
05/03/2417:31
NDL
9056A
Ferrous Iron
<0.05 H
mg/L
0.05
0.20
1
05/03/24 13:40
GOB
SM-3500-Fe-B
Ethane
<2.67
Ng/L
2.67
10.0
1
05/06/24 14:30
TBL
RSK-175
Ethene
<2.28
ug/L
2.28
10.0
1
05/06/24 14:30
TBL
RSK-175
Methane
6.083
Ng/L
2.51
10.0
1
05/06/24 14:30
TBL
RSK-175
1,4-Dioxane
<0.139
ug/L
0.139
2.00
1
05/07/24 10:43
TBL
8260D SIM
1,4-Naphthoquinone
<10.3 M
Ng/L
10.3
10.3
1
05/08/24 22:43
SMB
8270D
1-Naphthylamine
<10.3
ug/L
10.3
10.3
1
05/08/24 22:43
SMB
8270D
2-Acetylaminofluorene
<10.3
Ng/L
10.3
10.3
1
05/08/24 22:43
SMB
8270D
2-Naphthylamine
<10.3
ug/L
10.3
10.3
1
05/08/24 22:43
SMB
8270D
3-Methylcholanthrene
<10.3
Ng/L
10.3
10.3
1
05/08/24 22:43
SMB
8270D
4-Aminobiphenyl
<10.3
ug/L
10.3
10.3
1
05/08/24 22:43
SMB
8270D
5-Nitro-o-toluidine
<10.3
Ng/L
10.3
10.3
1
05/08/24 22:43
SMB
8270D
7,12-Di methyl benz(a)anth racene
<10.3
ug/L
10.3
10.3
1
05/08/24 22:43
SMB
8270D
Diallate
<10.3
Ng/L
10.3
10.3
1
05/08/24 22:43
SMB
8270D
Hexachloropropene
<10.3
ug/L
10.3
10.3
1
05/08/24 22:43
SMB
8270D
Isosafrole
<10.3
Ng/L
10.3
10.3
1
05/08/24 22:43
SMB
8270D
Methapyrilene
<10.3
ug/L
10.3
20.6
1
05/08/24 22:43
SMB
8270D
N-Nitrosomethylethylamine
<10.3
Ng/L
10.3
10.3
1
05/08/24 22:43
SMB
8270D
N-Nitrosomorpholine
<10.3
ug/L
10.3
10.3
1
05/08/24 22:43
SMB
8270D
N-Nitrosopyrrolidine
<10.3
Ng/L
10.3
10.3
1
05/08/24 22:43
SMB
8270D
N-Nitrosopiperidine
<10.3
ug/L
10.3
10.3
1
05/08/24 22:43
SMB
8270D
0,0,0-Triethyl Phosphorothioate
<0.339
Ng/L
0.339
1.03
1
05/08/24 20:53
SMB
8270C
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum
value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 106 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102
REPOR T OF A NA L YSIS
Lab No : 92550
Matrix: Aqueous
Sample ID: MW-14
Sampled: 5/2/2024 14:30
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
o-Toluidine
<10.3
Ng/L
10.3
10.3
1
05/08/24 22:43
SMB
8270D
p-Dimethylaminoazobenzene
<10.3
ug/L
10.3
10.3
1
05/08/24 22:43
SMB
8270D
p-Phenylenediamine
<10.3 M
Ng/L
10.3
10.3
1
05/08/24 22:43
SMB
8270D
Pronamide
<10.3
ug/L
10.3
10.3
1
05/08/24 22:43
SMB
8270D
Safrole
<10.3
Ng/L
10.3
10.3
1
05/08/24 22:43
SMB
8270D
Thionazine
<0.339
ug/L
0.339
1.03
1
05/08/24 20:53
SMB
8270C
Alkalinity (as CaCO3)
32000
Ng/L
800
5000
1
05/08/24 15:40
RLW
2320B-2011
Biochemical Oxygen Demand (5-day)
<2000
ug/L
2000
2000
1
05/03/24 10:39
MLW
521OB-2015
Chloride
3630
Ng/L
500
1000
1
05/03/2417:31
NDL
9056A
Cyanide, Total
<12.0
ug/L
12.0
25.0
1
05/15/24 10:52
RLW
9014
COD (Chemical Oxygen Demand)
<15000
Ng/L
15000
30000
1
05/09/24 11:25
SLO
5220D-2011
Nitrate (NO3-N)
70.0 J
ug/L
50.0
100
1
05/03/24 17:31
NDL
9056A
TOC
<720
Ng/L
720
1000
1
05/09/24 07:05
AT
531OC-2011
Sulfide
<830
ug/L
830
2000
1
05/06/2414:53
GOB
4500S2F-2011
Antimony
<0.618
Ng/L
0.618
1.00
1
05/14/24 00:59
TJS
6020B
Arsenic
0.516 J
ug/L
0.297
1.00
1
05/14/24 00:59
TJS
6020B
Barium
107
Ng/L
0.453
1.00
1
05/14/24 00:59
TJS
6020B
Beryllium
1.32
ug/L
0.102
1.00
1
05/14/24 00:59
TJS
6020B
Cadmium
<0.350
Ng/L
0.350
1.00
1
05/14/2419:51
CPW
6020B
Chromium
17.1
ug/L
0.346
1.00
1
05/14/24 00:59
CPW
6020B
Cobalt
25.5
Ng/L
0.060
1.00
1
05/14/24 00:59
TJS
6020B
Copper
10.7
ug/L
0.489
1.00
1
05/14/24 00:59
TJS
6020B
Lead
4.23
Ng/L
0.264
1.00
1
05/14/24 00:59
TJS
6020B
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum
value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 107 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92550
Sample ID: MW-14
Matrix: Aqueous
Sampled: 5/2/2024 14:30
Test
Results
Units
MDL
MQL
DF
Date / Time By Analytical
Analyzed Method
Mercury (Total)
<0.100
Ng/L
0.100
0.200
1
05/13/24 14:56 FDS 7470A
Nickel
13.1
ug/L
0.182
1.00
1
05/14/24 00:59 CPW 6020B
Selenium
<0.703
Ng/L
0.703
1.00
1
05/14/24 00:59 TJS 6020E
Silver
0.528 J
ug/L
0.0570
1.00
1
05/14/24 19:51 CPW 6020B
Tin
1.87 JB
Ng/L
1.44
5.00
1
05/14/24 00:59 TJS 6020B
Thallium
0.2783
ug/L
0.0610
1.00
1
05/14/24 00:59 TJS 6020B
Vanadium
26.3
Ng/L
0.767
5.00
1
05/14/24 00:59 TJS 6020B
Zinc
47.3
ug/L
4.67
10.0
1
05/14/24 19:51 CPW 6020B
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor H Beyond holding time
J Estimated value M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 108 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92550
Matrix: Aqueous
Sample ID: MW-14
Sampled: 5/2/2024 14:30
Analytical Method:
8081B
Prep Batch(es):
V46914
05/07/24 10:07
Prep Method:
3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Aldrin
<0.0152
Ng/L
0.0152
0.0500
1
05/16/24 02:49
TJW
V47319
alpha-BHC
<0.0063
ug/L
0.0063
0.0500
1
05/16/24 02:49
TJW
V47319
beta-BHC
<0.0111
Ng/L
0.0111
0.0500
1
05/16/24 02:49
TJW
V47319
delta-BHC
<0.0082
ug/L
0.0082
0.0500
1
05/16/24 02:49
TJW
V47319
Chlordane
<0.180
Ng/L
0.180
0.500
1
05/16/24 02:49
TJW
V47319
alpha -Chlordane
<0.0186
ug/L
0.0186
0.100
1
05/16/24 02:49
TJW
V47319
gamma -Chlordane
<0.0231
Ng/L
0.0231
0.100
1
05/16/24 02:49
TJW
V47319
4,4'-DDD
<0.0265
ug/L
0.0265
0.100
1
05/16/24 02:49
TJW
V47319
4,4'-DDE
<0.0218
Ng/L
0.0218
0.100
1
05/16/24 02:49
TJW
V47319
4,4'-DDT
<0.0176
ug/L
0.0176
0.100
1
05/16/24 02:49
TJW
V47319
Dieldrin
<0.0137
Ng/L
0.0137
0.0500
1
05/16/24 02:49
TJW
V47319
EndosulfanI
<0.0160
ug/L
0.0160
0.0500
1
05/16/24 02:49
TJW
V47319
Endosulfan II
<0.0121
Ng/L
0.0121
0.0500
1
05/16/24 02:49
TJW
V47319
Endosulfan Sulfate
<0.0165
ug/L
0.0165
0.0500
1
05/16/24 02:49
TJW
V47319
Endrin
<0.0136
Ng/L
0.0136
0.0500
1
05/16/24 02:49
TJW
V47319
Endrin Aldehyde
<0.0158
ug/L
0.0158
0.0500
1
05/16/24 02:49
TJW
V47319
Endrin Ketone
<0.0181
Ng/L
0.0181
0.100
1
05/16/24 02:49
TJW
V47319
gamma-BHC
<0.0061
ug/L
0.0061
0.0500
1
05/16/24 02:49
TJW
V47319
Heptachlor
<0.0130
Ng/L
0.0130
0.0500
1
05/16/24 02:49
TJW
V47319
Heptachlor Epoxide
<0.0224
ug/L
0.0224
0.100
1
05/16/24 02:49
TJW
V47319
Methoxychlor
<0.0179
Ng/L
0.0179
0.100
1
05/16/24 02:49
TJW
V47319
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 109 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102
REPOR T OF A NA L YSIS
Lab No : 92550
Matrix: Aqueous
Sample ID: MW-14
Sampled: 5/2/2024
14:30
Analytical Method: 8081B
Prep Batch(es):
V46914
05/07/24 10:07
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF Date / Time By
Analytical
Analyzed
Batch
Toxaphene
<0.350
Ng/L
0.350
1.00
1 05/16/24 02:49 TJW
V47319
Surrogate: Decachlorobiphenyl
99.4
Limits:
13-186%
1 05/16/24 02:49 TJW
V47319
Surrogate: Tetrachloro-m-xylene
107
Limits:
40-134%
1 05/16/24 02:49 TJW
V47319
Analytical Method: 8082A
Prep Batch(es):
V46915
05/07/24 10:07
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF Date / Time By
Analytical
Analyzed
Batch
Aroclor 1016
<0.210
u9/L
0.210
0.500
1 05/16/24 19:25 TJW
V47358
Aroclor1221
<0.110
Ng/L
0.110
1.00
1 05/16/24 19:25 TJW
V47358
Aroclor1232
<0.160
u9/L
0.160
0.500
1 05/16/24 19:25 TJW
V47358
Aroclor1242
<0.140
Ng/L
0.140
0.500
1 05/16/24 19:25 TJW
V47358
Aroclor1248
<0.140
u9/L
0.140
0.500
1 05/16/24 19:25 TJW
V47358
Aroclor1254
<0.160
Ng/L
0.160
0.500
1 05/16/24 19:25 TJW
V47358
Aroclor 1260
<0.495
u9/L
0.495
1.00
1 05/16/24 19:25 TJW
V47358
Surrogate: Decachlorobiphenyl
109
Limits:
32-178%
1 05/16/24 19:25 TJW
8082A
Surrogate: Tetrachloro-m-xylene
73.4
Limits:
30-161%
1 05/16/24 19:25 TJW
8082A
Analytical Method: 8151A
Prep Batch(es):
L749619
05/09/24 13:10
Prep Method: 8151A
Test
Results
Units
MDL
MQL
DF Date / Time By
Analytical
Analyzed
Batch
2,4-D
<0.2078
ug/L
0.2078
0.2500
1 05/15/24 00:57 SWB
L750458
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 110 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92550
Matrix: Aqueous
Sample ID: MW-14
Sampled: 5/2/2024
14:30
Analytical Method:
8151A
Prep Batch(es):
L749619
05/09/24 13:10
Prep Method:
8151A
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Dalapon
<0.5149
Ng/L
0.5149
0.5500
1
05/15/24 00:57
SWB
L750458
2,4-DB
<0.1364
ug/L
0.1364
0.2500
1
05/15/24 00:57
SWB
L750458
Dicamba
<0.05700
Ng/L
0.05700
0.1000
1
05/15/24 00:57
SWB
L750458
Dichlorprop
<0.07959
ug/L
0.07959
0.1000
1
05/15/24 00:57
SWB
L750458
Dinoseb
<0.02698
Ng/L
0.02698
0.1000
1
05/15/24 00:57
SWB
L750458
MCPA
<18.98
ug/L
18.98
50.00
1
05/15/24 00:57
SWB
L750458
MCPP
<11.75
Ng/L
11.75
50.00
1
05/15/24 00:57
SWB
L750458
Picloram
<0.04528
ug/L
0.04528
0.1000
1
05/15/24 00:57
SWB
L750458
2,4,5-T
<0.1002
Ng/L
0.1002
0.1250
1
05/15/24 00:57
SWB
L750458
2,4,5-TP (Silvex)
<0.01634
ug/L
0.01634
0.1000
1
05/15/24 00:57
SWB
L750458
Surrogate: DCAA
134.6
Limits:
20-150%
1 05/15/24 00:57 SWB
L750458
Analytical Method:
8260D
Prep Batch(es):
V47200
05/09/24 14:00
V47336
05/14/24 14:00
Prep Method:
5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
ug/L
1.80
5.00
1
05/10/24 10:10
MSA
V47202
Acetonitrile
<10.0
Ng/L
10.0
10.0
1
05/15/2417:21
MSA
V47337
Acrolein
<2.00
ug/L
2.00
5.00
1
05/10/24 10:10
MSA
V47202
Acrylonitrile
<0.230
Ng/L
0.230
5.00
1
05/10/24 10:10
MSA
V47202
Allyl Chloride
<0.579
ug/L
0.579
10.0
1
05/15/24 17:21
MSA
V47337
Benzene
<0.180
Ng/L
0.180
0.500
1
05/10/24 10:10
MSA
V47202
Bromochloromethane
<0.420
ug/L
0.420
1.00
1
05/10/24 10:10
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 111 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92550
Matrix: Aqueous
Sample ID: MW-14
Sampled: 5/2/2024 14:30
Analytical Method: 8260D
Prep Batch(es):
V47200
05/09/24 14:00
V47336
05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
05/10/24 10:10
MSA
V47202
Bromoform
<1.50
ug/L
1.50
5.00
1
05/10/24 10:10
MSA
V47202
Bromomethane
<0.280
Ng/L
0.280
1.00
1
05/10/24 10:10
MSA
V47202
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
05/10/24 10:10
MSA
V47202
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
05/10/24 10:10
MSA
V47202
Chlorobenzene
<0.190
ug/L
0.190
0.500
1
05/10/24 10:10
MSA
V47202
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
05/10/24 10:10
MSA
V47202
Chloroethane
<0.430
ug/L
0.430
1.00
1
05/10/24 10:10
MSA
V47202
Chloroform
<0.220
Ng/L
0.220
0.500
1
05/10/24 10:10
MSA
V47202
Chloromethane
<0.220
ug/L
0.220
0.500
1
05/10/24 10:10
MSA
V47202
Chloroprene
<0.450
Ng/L
0.450
10.0
1
05/15/24 17:21
MSA
V47337
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
05/10/24 10:10
MSA
V47202
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
05/10/24 10:10
MSA
V47202
Dibromomethane
<0.230
ug/L
0.230
0.500
1
05/10/24 10:10
MSA
V47202
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
05/10/24 10:10
MSA
V47202
1,2-Dichlorobenzene
<0.220
ug/L
0.220
0.500
1
05/10/24 10:10
MSA
V47202
1,3-Dichlorobenzene
<0.190
Ng/L
0.190
0.500
1
05/10/24 10:10
MSA
V47202
1,4-Dichlorobenzene
<0.210
ug/L
0.210
0.500
1
05/10/24 10:10
MSA
V47202
Dichlorodifluoromethane
<1.20
Ng/L
1.20
5.00
1
05/10/24 10:10
MSA
V47202
1,1-Dichloroethane
1.84
ug/L
0.240
0.500
1
05/10/24 10:10
MSA
V47202
1,2-Dichloroethane
<0.150
Ng/L
0.150
0.500
1
05/10/24 10:10
MSA
V47202
1,1-Dichloroethene
<0.150
ug/L
0.150
0.500
1
05/10/24 10:10
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 112 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92550
Matrix: Aqueous
Sample ID: MW-14
Sampled: 5/2/2024 14:30
Analytical Method: 8260D
Prep Batch(es):
V47200
05/09/24 14:00
V47336
05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
cis- 1,2-Dich loroethene
5.73
Ng/L
0.200
0.500
1
05/10/24 10:10
MSA
V47202
trans- 1.2-Dichloroethene
<0.180
ug/L
0.180
0.500
1
05/10/24 10:10
MSA
V47202
1,2-Dichloropropane
<0.190
Ng/L
0.190
0.500
1
05/10/24 10:10
MSA
V47202
1,3-Dichloropropane
<0.130
ug/L
0.130
0.500
1
05/10/24 10:10
MSA
V47202
2,2-Dichloropropane
<0.210
Ng/L
0.210
2.00
1
05/10/24 10:10
MSA
V47202
1,1-Dichloropropene
<0.200
ug/L
0.200
0.500
1
05/10/24 10:10
MSA
V47202
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
05/10/24 10:10
MSA
V47202
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
05/10/24 10:10
MSA
V47202
Ethyl Methacrylate
<1.62
Ng/L
1.62
10.0
1
05/15/24 17:21
MSA
V47337
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
05/10/24 10:10
MSA
V47202
Hexachlorobutadiene
<0.350
Ng/L
0.350
2.00
1
05/10/24 10:10
MSA
V47202
2-Hexanone
<0.380
ug/L
0.380
5.00
1
05/10/24 10:10
MSA
V47202
Iodomethane
<0.054
Ng/L
0.054
0.500
1
05/10/24 10:10
MSA
V47202
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
05/10/24 10:10
MSA
V47202
Methacrylonitrile
<10.0
Ng/L
10.0
10.0
1
05/15/2417:21
MSA
V47337
4-Methyl-2-Pentanone
<1.00
ug/L
1.00
5.00
1
05/10/24 10:10
MSA
V47202
Methylene Chloride
<0.330
Ng/L
0.330
1.00
1
05/10/24 10:10
MSA
V47202
Naphthalene
<0.470
ug/L
0.470
1.00
1
05/10/24 10:10
MSA
V47202
Propionitrile
<10.0
Ng/L
10.0
10.0
1
05/15/2417:21
MSA
V47337
Styrene
<0.220
ug/L
0.220
0.500
1
05/10/24 10:10
MSA
V47202
1,1,1,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
05/10/24 10:10
MSA
V47202
1,1,2,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
05/10/24 10:10
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 113 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92550
Matrix: Aqueous
Sample ID: MW-14
Sampled: 5/2/2024
14:30
Analytical Method: 8260D
Prep Batch(es):
V47200 05/09/24 14:00
V47336 05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Tetrachloroethene
0.2873
Ng/L
0.220 0.500
1
05/10/24 10:10 MSA
V47202
Tetrahydrofuran
<1.50
ug/L
1.50 10.0
1
05/10/24 10:10 MSA
V47202
Toluene
<0.220
Ng/L
0.220 0.500
1
05/10/24 10:10 MSA
V47202
1,2,4-Trichlorobenzene
<0.310
ug/L
0.310 1.00
1
05/10/24 10:10 MSA
V47202
1,1,1-Trichloroethane
<0.160
Ng/L
0.160 0.500
1
05/10/24 10:10 MSA
V47202
1,1,2-Trichloroethane
<0.096
ug/L
0.096 0.500
1
05/10/24 10:10 MSA
V47202
Trichloroethene
0.4843
Ng/L
0.180 0.500
1
05/10/24 10:10 MSA
V47202
Trichlorofluoromethane
<0.180
ug/L
0.180 0.500
1
05/10/24 10:10 MSA
V47202
1,2,3-Trichloropropane
<0.270
Ng/L
0.270 1.00
1
05/10/24 10:10 MSA
V47202
Vinyl Acetate
<1.00 M
ug/L
1.00 2.00
1
05/10/24 10:10 MSA
V47202
Vinyl Chloride
<0.170
Ng/L
0.170 0.500
1
05/10/24 10:10 MSA
V47202
o-Xylene
<0.210
ug/L
0.210 0.500
1
05/10/24 10:10 MSA
V47202
m,p-Xylene
<0.420
Ng/L
0.420 1.00
1
05/10/24 10:10 MSA
V47202
Xylene (Total)
<0.21
ug/L
0.210 0.500
1
05/10/24 10:10
V47202
Surrogate:4-Bromofluorobenzene
102
Limits:80-124%
1 05/10/24 10:10 MSA
V47202
Surrogate: Dibromofluoromethane
102
Limits: 75-129%
1 05/10/24 10:10 MSA
V47202
Surrogate: 1,2-Dichloroethane - d4
100
Limits: 63-136%
1 05/10/24 10:10 MSA
V47202
Surrogate: Toluene-d8
99.6
Limits: 77-123%
1 05/10/24 10:10 MSA
V47202
Surrogate:4-Bromofluorobenzene
100
Limits:80-124%
1 05/15/24 17:21 MSA
V47337
Surrogate: Dibromofluoromethane
102
Limits: 75-129%
1 05/15/24 17:21 MSA
V47337
Surrogate: 1,2-Dichloroethane - d4
106
Limits: 63-136%
1 05/15/24 17:21 MSA
V47337
Surrogate: Toluene-d8
106
Limits: 77-123%
1 05/15/24 17:21 MSA
V47337
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 114 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
01186
Smith & Gardner, Inc.
Project
Seth C. Rickerts
14 N. Boylan Avenue
Information
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Surry County C&D/MSW Spring
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Report Date : 05/31/2024
Received : 05/03/2024
Lab No : 92550 Matrix: Aqueous
Sample ID: MW-14 Sampled: 5/2/2024 14:30
Analytical Method: 8270C Prep Batch(es): L749277 05/08/24 12:10
Prep Method: 3510C
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Dimethoate
<0.734
Ng/L
0.734
1.03
1
05/08/24 20:53
SMB
L749502
Disulfoton
<0.479
ug/L
0.479
1.03
1
05/08/24 20:53
SMB
L749502
Ethyl Parathion
<0.585
Ng/L
0.585
1.03
1
05/08/24 20:53
SMB
L749502
Famphur
<0.527
ug/L
0.527
1.03
1
05/08/24 20:53
SMB
L749502
Methyl Parathion
<0.829
Ng/L
0.829
1.03
1
05/08/24 20:53
SMB
L749502
Phorate
<0.678
ug/L
0.678
1.03
1
05/08/24 20:53
SMB
L749502
Surrogate: Tributyl phosphate
74.8
Limits:
50-150%
1 05/08/24 20:53 SMB
8270C
Surrogate: Triphenyl phosphate
95.1
Limits:
50-150%
1 05/08/24 20:53 SMB
8270C
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,3-Dinitrobenzene
<0.904
ug/L
0.904
10.0
1
05/08/24 22:43
SMB
L749499
1,3,5-Trinitrobenzene
<10.3
Ng/L
10.3
10.3
1
05/08/24 22:43
SMB
L749501
Acenaphthene
<0.563
ug/L
0.563
2.00
1
05/08/24 22:43
SMB
L749499
Acenaphthylene
<0.562
Ng/L
0.562
2.00
1
05/08/24 22:43
SMB
L749499
Acetophenone
<0.689
ug/L
0.689
5.00
1
05/08/24 22:43
SMB
L749499
Anthracene
<0.536
Ng/L
0.536
2.00
1
05/08/24 22:43
SMB
L749499
Benzo(a)anthracene
<0.520
ug/L
0.520
2.00
1
05/08/24 22:43
SMB
L749499
Benzo(a)pyrene
<0.511
Ng/L
0.511
2.00
1
05/08/24 22:43
SMB
L749499
Benzo(b)fluoranthene
<0.631
ug/L
0.631
2.00
1
05/08/24 22:43
SMB
L749499
Benzo(g,h,i)perylene
<0.507
Ng/L
0.507
2.00
1
05/08/24 22:43
SMB
L749499
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
H
Beyond holding time
J Estimated value
M
Minimum value
MQL Method Quantitation Limit
Q
RPD >40% dual column results
Page 115 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92550
Matrix: Aqueous
Sample ID: MW-14
Sampled: 5/2/2024 14:30
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Benzo(k)fluoranthene
<0.575
Ng/L
0.575
2.00
1
05/08/24 22:43
SMB
L749499
Benzyl alcohol
<1.02
ug/L
1.02
10.0
1
05/08/24 22:43
SMB
L749499
Bis(2-Chloroethoxy)methane
<0.592
Ng/L
0.592
5.00
1
05/08/24 22:43
SMB
L749499
Bis(2-Chloroethyl)ether
<0.627
ug/L
0.627
5.00
1
05/08/24 22:43
SMB
L749499
Bis(2-Chloroisopropyl)ether
<0.656
Ng/L
0.656
5.00
1
05/08/24 22:43
SMB
L749499
Bis(2-ethylhexyl)phthalate
<0.796
ug/L
0.796
5.00
1
05/08/24 22:43
SMB
L749499
4-Bromophenyl phenyl ether
<0.567
Ng/L
0.567
5.00
1
05/08/24 22:43
SMB
L749499
Butyl benzyl phthalate
<0.756
ug/L
0.756
5.00
1
05/08/24 22:43
SMB
L749499
4-Chloro-3-methylphenol
<0.550
Ng/L
0.550
5.00
1
05/08/24 22:43
SMB
L749499
4-Chloroaniline
<0.530
ug/L
0.530
5.00
1
05/08/24 22:43
SMB
L749499
Chlorobenzilate
<0.999
Ng/L
0.999
5.00
1
05/08/24 22:43
SMB
L749499
2-Chloronaphthalene
<0.560
ug/L
0.560
5.00
1
05/08/24 22:43
SMB
L749499
2-Chlorophenol
<0.457
Ng/L
0.457
5.00
1
05/08/24 22:43
SMB
L749499
4-Chlorophenyl phenyl ether
<0.615
ug/L
0.615
5.00
1
05/08/24 22:43
SMB
L749499
Chrysene
<0.550
Ng/L
0.550
2.00
1
05/08/24 22:43
SMB
L749499
Dibenz(a,h)anthracene
<0.460
ug/L
0.460
2.00
1
05/08/24 22:43
SMB
L749499
Dibenzofuran
<0.584
Ng/L
0.584
5.00
1
05/08/24 22:43
SMB
L749499
1,2-Dichlorobenzene
<0.466
ug/L
0.466
5.00
1
05/08/24 22:43
SMB
L749499
1,3-Dichlorobenzene
<0.436
Ng/L
0.436
5.00
1
05/08/24 22:43
SMB
L749499
1,4-Dichlorobenzene
<0.405
ug/L
0.405
5.00
1
05/08/24 22:43
SMB
L749499
3,3'-Dichlorobenzidine
<10.3
Ng/L
10.3
20.0
1
05/08/24 22:43
SMB
L749499
2,4-Dichlorophenol
<0.606
ug/L
0.606
5.00
1
05/08/24 22:43
SMB
L749499
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 116 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92550
Matrix: Aqueous
Sample ID: MW-14
Sampled: 5/2/2024 14:30
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
2,6-Dichlorophenol
<0.655
Ng/L
0.655
5.00
1
05/08/24 22:43
SMB
L749499
Diethyl phthalate
<0.686
ug/L
0.686
5.00
1
05/08/24 22:43
SMB
L749499
Dimethyl phthalate
<0.652
Ng/L
0.652
5.00
1
05/08/24 22:43
SMB
L749499
3,3' Dimethylbenzidine
<9.01
ug/L
9.01
10.0
1
05/08/24 22:43
SMB
L749499
2,4-Dimethyl phenol
<0.620
Ng/L
0.620
5.00
1
05/08/24 22:43
SMB
L749499
Di-n-butyl phthalate
<0.740
ug/L
0.740
5.00
1
05/08/24 22:43
SMB
L749499
4,6-Dinitro-2- methyl phenol
<6.08
Ng/L
6.08
10.0
1
05/08/24 22:43
SMB
L749499
2,4-Dinitrophenol
<18.9
ug/L
18.9
20.0
1
05/08/24 22:43
SMB
L749499
2,4-Dinitrotoluene
<0.911
Ng/L
0.911
5.00
1
05/08/24 22:43
SMB
L749499
2,6-Dinitrotoluene
<0.734
ug/L
0.734
5.00
1
05/08/24 22:43
SMB
L749499
Di-n-Octyl Phthalate
<1.32
Ng/L
1.32
5.00
1
05/08/24 22:43
SMB
L749499
Ethyl methanesulfonate
<0.660
ug/L
0.660
5.00
1
05/08/24 22:43
SMB
L749499
Fluoranthene
<0.583
Ng/L
0.583
2.00
1
05/08/24 22:43
SMB
L749499
Fluorene
<0.617
ug/L
0.617
2.00
1
05/08/24 22:43
SMB
L749499
Hexachlorobenzene
<0.537
Ng/L
0.537
5.00
1
05/08/24 22:43
SMB
L749499
Hexachlorobutadiene
<0.411
ug/L
0.411
5.00
1
05/08/24 22:43
SMB
L749499
Hexachlorocyclopentadiene
<0.889
Ng/L
0.889
5.00
1
05/08/24 22:43
SMB
L749499
Hexachloroethane
<0.482
ug/L
0.482
5.00
1
05/08/24 22:43
SMB
L749499
Indeno(1,2,3-cd)pyrene
<0.490
Ng/L
0.490
2.00
1
05/08/24 22:43
SMB
L749499
Isodrin
<10.3
ug/L
10.3
10.3
1
05/08/24 22:43
SMB
L749501
Isophorone
<0.591
Ng/L
0.591
5.00
1
05/08/24 22:43
SMB
L749499
Kepone
<10.3 M
u9/L
10.3
10.3
1
05/08/24 22:43
SMB
L749501
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 117 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92550
Matrix: Aqueous
Sample ID: MW-14
Sampled: 5/2/2024 14:30
Analytical Method: 8270D
Prep Batch(es):
L749275
05/08/24 12:10
Prep Method: 3510C
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Methyl methanesulfonate
<0.746
Ng/L
0.746
5.00
1
05/08/24 22:43
SMB
L749499
2-Methylnaphthalene
<0.569
ug/L
0.569
2.00
1
05/08/24 22:43
SMB
L749499
2-Methylphenol
<0.449
Ng/L
0.449
5.00
1
05/08/24 22:43
SMB
L749499
3&4 Methylphenol
<0.453
ug/L
0.453
5.00
1
05/08/24 22:43
SMB
L749499
Naphthalene
<1.70
Ng/L
1.70
2.00
1
05/08/24 22:43
SMB
L749499
2-Nitroaniline
<0.766
ug/L
0.766
5.00
1
05/08/24 22:43
SMB
L749499
3-Nitroaniline
<0.912
Ng/L
0.912
10.0
1
05/08/24 22:43
SMB
L749499
4-Nitroaniline
<12.5
ug/L
12.5
20.0
1
05/08/24 22:43
SMB
L749499
Nitrobenzene
<0.715
Ng/L
0.715
5.00
1
05/08/24 22:43
SMB
L749499
2-Nitrophenol
<0.728
ug/L
0.728
5.00
1
05/08/24 22:43
SMB
L749499
4-Nitrophenol
<1.94
Ng/L
1.94
10.0
1
05/08/24 22:43
SMB
L749499
N-Nitrosodimethylamine
<0.295
ug/L
0.295
5.00
1
05/08/24 22:43
SMB
L749499
N-Nitrosodiphenylamine
<0.487
Ng/L
0.487
10.0
1
05/08/24 22:43
SMB
L749499
N-Nitrosodiethylamine
<0.535
ug/L
0.535
5.00
1
05/08/24 22:43
SMB
L749499
N-Nitroso-di-n-butylamine
<0.699
Ng/L
0.699
5.00
1
05/08/24 22:43
SMB
L749499
N-Nitroso-di-n-propylamine
<0.678
ug/L
0.678
5.00
1
05/08/24 22:43
SMB
L749499
Pentachlorobenzene
<0.574
Ng/L
0.574
10.0
1
05/08/24 22:43
SMB
L749499
Pentachloronitrobenzene
<0.569
ug/L
0.569
5.00
1
05/08/24 22:43
SMB
L749499
Pentachlorophenol
<1.23
Ng/L
1.23
10.0
1
05/08/24 22:43
SMB
L749499
Phenacetin
<0.693
ug/L
0.693
5.00
1
05/08/24 22:43
SMB
L749499
Phenanthrene
<0.582
Ng/L
0.582
2.00
1
05/08/24 22:43
SMB
L749499
Phenol
<0.258
ug/L
0.258
5.00
1
05/08/24 22:43
SMB
L749499
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 118 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
01186
Smith & Gardner, Inc.
Project
Seth C. Rickerts
14 N. Boylan Avenue
Information
Raleigh , NC 27603
Report Number : 24-124-0102
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Surry County C&D/MSW Spring
REPORT OF ANAL YSIS
Report Date : 05/31/2024
Received : 05/03/2024
Lab No : 92550 Matrix: Aqueous
Sample ID: MW-14 Sampled: 5/2/2024 14:30
Analytical Method: 8270D
Prep Method: 3510C
Test Results
Pyrene
<0.680
1,2,4,5-Tetrachlorobenzene
<0.463
2,3,4,6-Tetrachlorophenol
<0.570
1,2,4-Trichlorobenzene
<0.433
2,4,5-Trichlorophenol
<0.611
2,4,6-Trichlorophenol
<0.539
Surrogate: 2-Fluorobiphenyl
Surrogate: 2-Fluorophenol
Surrogate: Nitrobenzene-d5
Surrogate: Phenol-d6
Surrogate: 4-Terphenyl-d 14
Surrogate: 2,4,6-Tribromophenol
Prep Batch(es): L749275 05/08/24 12:10
Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.680 2.00
Pg/L
0.463 5.00
Ng/L
0.570 5.00
ug/L
0.433 5.00
Ng/L
0.611 5.00
Pg/L
0.539 5.00
54.0
Limits: 24-93%
27.2
Limits: 10-44%
49.3
Limits: 20-91%
19.7
Limits: 7-32%
78.6
Limits: 35-126%
70.1
Limits: 39-110%
1 05/08/24 22:43 SMB
L749499
1 05/08/24 22:43 SMB
L749499
1 05/08/24 22:43 SMB
L749499
1 05/08/24 22:43 SMB
L749499
1 05/08/24 22:43 SMB
L749499
1 05/08/24 22:43 SMB
L749499
1 05/08/24 22:43 SMB
L749499
1 05/08/24 22:43 SMB
L749499
1 05/08/24 22:43 SMB
L749499
1 05/08/24 22:43 SMB
L749499
1 05/08/24 22:43 SMB
L749499
1 05/08/24 22:43 SMB
L749499
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor H Beyond holding time
J Estimated value M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 119 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92551
Sample ID: SW-3
Matrix: Aqueous
Sampled: 5/2/2024 15:50
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
1,4-Dioxane
5.67
Ng/L
0.139
2.00
1
05/07/24 11:08
TBL
8260D SIM
Antimony
<0.618
ug/L
0.618
1.00
1
05/14/24 01:04
TJS
6020B
Arsenic
<0.297
Ng/L
0.297
1.00
1
05/14/24 01:04
TJS
6020E
Barium
41.9
ug/L
0.453
1.00
1
05/14/24 01:04
TJS
6020B
Beryllium
<0.102
Ng/L
0.102
1.00
1
05/14/24 01:04
TJS
6020E
Cadmium
<0.350
ug/L
0.350
1.00
1
05/14/2419:55
CPW
6020B
Chromium
0.8663
Ng/L
0.346
1.00
1
05/14/24 01:04
CPW
6020E
Cobalt
22.2
ug/L
0.060
1.00
1
05/14/24 01:04
TJS
6020B
Copper
0.6933
Ng/L
0.489
1.00
1
05/14/24 01:04
TJS
6020B
Lead
<0.264
ug/L
0.264
1.00
1
05/14/24 01:04
TJS
6020B
Nickel
2.13
Ng/L
0.182
1.00
1
05/14/24 01:04
CPW
6020B
Selenium
<0.703
ug/L
0.703
1.00
1
05/14/24 01:04
TJS
6020B
Silver
<0.0570
Ng/L
0.0570
1.00
1
05/14/2419:55
CPW
6020B
Thallium
0.1233
ug/L
0.0610
1.00
1
05/14/24 01:04
TJS
6020B
Vanadium
<0.767
Ng/L
0.767
5.00
1
05/14/24 01:04
TJS
6020B
Zinc
<4.67
ug/L
4.67
10.0
1
05/14/24 19:55
CPW
6020B
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor H Beyond holding time
J Estimated value M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 120 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92551
Matrix: Aqueous
Sample ID: SW-3
Sampled: 5/2/2024 15:50
Analytical Method: 8260D
Prep Batch(es):
V47200
05/09/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
2.703
Ng/L
1.80
5.00
1
05/10/24 10:35
MSA
V47202
Acrylonitrile
<0.230
ug/L
0.230
5.00
1
05/10/24 10:35
MSA
V47202
Benzene
<0.180
Ng/L
0.180
0.500
1
05/10/24 10:35
MSA
V47202
Bromochloromethane
<0.420
ug/L
0.420
1.00
1
05/10/24 10:35
MSA
V47202
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
05/10/24 10:35
MSA
V47202
Bromoform
<1.50
ug/L
1.50
5.00
1
05/10/24 10:35
MSA
V47202
Bromomethane
<0.280
Ng/L
0.280
1.00
1
05/10/24 10:35
MSA
V47202
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
05/10/24 10:35
MSA
V47202
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
05/10/24 10:35
MSA
V47202
Chlorobenzene
<0.190
ug/L
0.190
0.500
1
05/10/24 10:35
MSA
V47202
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
05/10/24 10:35
MSA
V47202
Chloroethane
<0.430
ug/L
0.430
1.00
1
05/10/24 10:35
MSA
V47202
Chloroform
<0.220
Ng/L
0.220
0.500
1
05/10/24 10:35
MSA
V47202
Chloromethane
<0.220
ug/L
0.220
0.500
1
05/10/24 10:35
MSA
V47202
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
05/10/24 10:35
MSA
V47202
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
05/10/24 10:35
MSA
V47202
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
05/10/24 10:35
MSA
V47202
Dibromomethane
<0.230
ug/L
0.230
0.500
1
05/10/24 10:35
MSA
V47202
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
05/10/24 10:35
MSA
V47202
1,2-Dichlorobenzene
<0.220
ug/L
0.220
0.500
1
05/10/24 10:35
MSA
V47202
1,4-Dichlorobenzene
<0.210
Ng/L
0.210
0.500
1
05/10/24 10:35
MSA
V47202
Dichlorodifluoromethane
<1.20
ug/L
1.20
5.00
1
05/10/24 10:35
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 121 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92551
Matrix: Aqueous
Sample ID: SW-3
Sampled: 5/2/2024 15:50
Analytical Method: 8260D
Prep Batch(es):
V47200
05/09/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
05/10/24 10:35
MSA
V47202
1,2-Dichloroethane
<0.150
ug/L
0.150
0.500
1
05/10/24 10:35
MSA
V47202
1,1-Dichloroethene
<0.150
Ng/L
0.150
0.500
1
05/10/24 10:35
MSA
V47202
cis- 1,2-Dich loroethene
<0.200
ug/L
0.200
0.500
1
05/10/24 10:35
MSA
V47202
trans-1,2-Dichloroethene
<0.180
Ng/L
0.180
0.500
1
05/10/24 10:35
MSA
V47202
1,2-Dichloropropane
<0.190
ug/L
0.190
0.500
1
05/10/24 10:35
MSA
V47202
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
05/10/24 10:35
MSA
V47202
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
05/10/24 10:35
MSA
V47202
1,4-Dioxane
<16.0
Ng/L
16.0
150
1
05/10/24 10:35
MSA
V47202
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
05/10/24 10:35
MSA
V47202
2-Hexanone
<0.380
Ng/L
0.380
5.00
1
05/10/24 10:35
MSA
V47202
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
05/10/24 10:35
MSA
V47202
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
05/10/24 10:35
MSA
V47202
Methylene Chloride
<0.330
ug/L
0.330
1.00
1
05/10/24 10:35
MSA
V47202
Styrene
<0.220
Ng/L
0.220
0.500
1
05/10/24 10:35
MSA
V47202
1,1,1,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
05/10/24 10:35
MSA
V47202
1,1,2,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
05/10/24 10:35
MSA
V47202
Tetrachloroethene
<0.220
ug/L
0.220
0.500
1
05/10/24 10:35
MSA
V47202
Tetrahydrofuran
1.553
Ng/L
1.50
10.0
1
05/10/24 10:35
MSA
V47202
Toluene
<0.220
ug/L
0.220
0.500
1
05/10/24 10:35
MSA
V47202
1,1,1-Trichloroethane
<0.160
Ng/L
0.160
0.500
1
05/10/24 10:35
MSA
V47202
1,1,2-Trichloroethane
<0.096
ug/L
0.096
0.500
1
05/10/24 10:35
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 122 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
01186
Smith & Gardner, Inc.
Project
Seth C. Rickerts
14 N. Boylan Avenue
Information
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Surry County C&D/MSW Spring
Report Date : 05/31/2024
Received : 05/03/2024
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92551 Matrix: Aqueous
Sample ID: SW-3 Sampled: 5/2/2024 15:50
Analytical Method: 8260D
Prep Method: 5030E
Test Results
Trichloroethene
<0.180
Trichlorofluoromethane
<0.180
1,2,3-Trichloropropane
<0.270
Vinyl Acetate
<1.00 M
Vinyl Chloride
<0.170
o-Xylene
<0.210
m,p-Xylene
<0.420
Xylene (Total)
<0.21
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Prep Batch(es): V47200 05/09/24 14:00
Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.180 0.500
Pg/L
0.180 0.500
Ng/L
0.270 1.00
Pg/L
1.00 2.00
Ng/L
0.170 0.500
Pg/L
0.210 0.500
Ng/L
0.420 1.00
Pg/L
0.210 0.500
102
Limits: 80-124%
102
Limits: 75-129%
99.2
Limits: 63-136%
100
Limits: 77-123%
1 05/10/24 10:35 MSA V47202
1 05/10/24 10:35 MSA V47202
1 05/10/24 10:35 MSA V47202
1 05/10/24 10:35 MSA V47202
1 05/10/24 10:35 MSA V47202
1 05/10/24 10:35 MSA V47202
1 05/10/24 10:35 MSA V47202
1 05/10/24 10:35 V47202
1 05/10/24 10:35 MSA V47202
1 05/10/24 10:35 MSA V47202
1 05/10/24 10:35 MSA V47202
1 05/10/24 10:35 MSA V47202
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor H Beyond holding time
J Estimated value M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 123 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92552 Matrix: Aqueous
Sample ID : Trip Blank Sampled: 5/1/2024 0:00
Analytical Method: 8260D Prep Batch(es): V47200 05/09/24 14:00 V47336 05/14/24 14:00
Prep Method: 5030E
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Acetone
2.233
Ng/L
1.80
5.00
1
05/10/24 06:23
MSA
V47202
Acetonitrile
<10.0
u9/L
10.0
10.0
1
05/15/2410:13
MSA
V47337
Acrolein
<2.00
N9/L
2.00
5.00
1
05/10/24 06:23
MSA
V47202
Acrylonitrile
<0.230
u9/L
0.230
5.00
1
05/10/24 06:23
MSA
V47202
Allyl Chloride
<0.579
Ng/L
0.579
10.0
1
05/15/24 10:13
MSA
V47337
Benzene
<0.180
ug/L
0.180
0.500
1
05/10/24 06:23
MSA
V47202
Bromochloromethane
<0.420
N9/L
0.420
1.00
1
05/10/24 06:23
MSA
V47202
Bromodichloromethane
<0.160
ug/L
0.160
0.500
1
05/10/24 06:23
MSA
V47202
Bromoform
<1.50
N9/L
1.50
5.00
1
05/10/24 06:23
MSA
V47202
Bromomethane
<0.280
ug/L
0.280
1.00
1
05/10/24 06:23
MSA
V47202
Carbon Disulfide
<0.150
N9/L
0.150
5.00
1
05/10/24 06:23
MSA
V47202
Carbon Tetrachloride
<0.180
ug/L
0.180
0.500
1
05/10/24 06:23
MSA
V47202
Chlorobenzene
<0.190
N9/L
0.190
0.500
1
05/10/24 06:23
MSA
V47202
Chlorodibromomethane
<0.190
pg/L
0.190
0.500
1
05/10/24 06:23
MSA
V47202
Chloroethane
<0.430
N9/L
0.430
1.00
1
05/10/24 06:23
MSA
V47202
Chloroform
<0.220
ug/L
0.220
0.500
1
05/10/24 06:23
MSA
V47202
Chloromethane
<0.220
N9/L
0.220
0.500
1
05/10/24 06:23
MSA
V47202
Chloroprene
<0.450
ug/L
0.450
10.0
1
05/15/2410:13
MSA
V47337
1,2-Dibromo-3-Chloropropane
<1.10
N9/L
1.10
2.00
1
05/10/24 06:23
MSA
V47202
1,2-Dibromoethane
<0.200
pg/L
0.200
0.500
1
05/10/24 06:23
MSA
V47202
Dibromomethane
<0.230
N9/L
0.230
0.500
1
05/10/24 06:23
MSA
V47202
trans-1,4-Dichloro-2-butene
<1.30
pg/L
1.30
10.0
1
05/10/24 06:23
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum
value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 124 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92552
Matrix: Aqueous
Sample ID : Trip Blank
Sampled: 5/1/2024 0:00
Analytical Method: 8260D
Prep Batch(es):
V47200
05/09/24 14:00
V47336
05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,2-Dichlorobenzene
<0.220
Ng/L
0.220
0.500
1
05/10/24 06:23
MSA
V47202
1,3-Dichlorobenzene
<0.190
ug/L
0.190
0.500
1
05/10/24 06:23
MSA
V47202
1,4-Dichlorobenzene
<0.210
Ng/L
0.210
0.500
1
05/10/24 06:23
MSA
V47202
Dichlorodifluoromethane
<1.20
ug/L
1.20
5.00
1
05/10/24 06:23
MSA
V47202
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
05/10/24 06:23
MSA
V47202
1,2-Dichloroethane
<0.150
ug/L
0.150
0.500
1
05/10/24 06:23
MSA
V47202
1,1-Dichloroethene
<0.150
Ng/L
0.150
0.500
1
05/10/24 06:23
MSA
V47202
cis- 1,2-Dich loroethene
<0.200
ug/L
0.200
0.500
1
05/10/24 06:23
MSA
V47202
trans-1,2-Dichloroethene
<0.180
Ng/L
0.180
0.500
1
05/10/24 06:23
MSA
V47202
1,2-Dichloropropane
<0.190
ug/L
0.190
0.500
1
05/10/24 06:23
MSA
V47202
1,3-Dichloropropane
<0.130
Ng/L
0.130
0.500
1
05/10/24 06:23
MSA
V47202
2,2-Dichloropropane
<0.210
ug/L
0.210
2.00
1
05/10/24 06:23
MSA
V47202
1,1-Dichloropropene
<0.200
Ng/L
0.200
0.500
1
05/10/24 06:23
MSA
V47202
cis- 1,3-Dich loropropene
<0.210
ug/L
0.210
0.500
1
05/10/24 06:23
MSA
V47202
trans-1,3-Dichloropropene
<0.150
Ng/L
0.150
0.500
1
05/10/24 06:23
MSA
V47202
Ethyl Methacrylate
<1.62
ug/L
1.62
10.0
1
05/15/24 10:13
MSA
V47337
Ethylbenzene
<0.170
Ng/L
0.170
0.500
1
05/10/24 06:23
MSA
V47202
Hexachlorobutadiene
<0.350
ug/L
0.350
2.00
1
05/10/24 06:23
MSA
V47202
2-Hexanone
<0.380
Ng/L
0.380
5.00
1
05/10/24 06:23
MSA
V47202
Iodomethane
<0.054
ug/L
0.054
0.500
1
05/10/24 06:23
MSA
V47202
Methyl Ethyl Ketone (MEK)
<0.710
Ng/L
0.710
5.00
1
05/10/24 06:23
MSA
V47202
Methacrylonitrile
<10.0
ug/L
10.0
10.0
1
05/15/2410:13
MSA
V47337
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 125 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County C&D/MSW Spring
Seth C. Rickerts Report Date : 05/31/2024
14 N. Boylan Avenue Information : Received : 05/03/2024
Raleigh , NC 27603
Report Number : 24-124-0102 REPOR T OF A NA L YSIS
Lab No : 92552
Matrix: Aqueous
Sample ID : Trip Blank
Sampled: 5/1/2024 0:00
Analytical Method: 8260D
Prep Batch(es):
V47200
05/09/24 14:00
V47336
05/14/24 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
05/10/24 06:23
MSA
V47202
Methylene Chloride
<0.330
ug/L
0.330
1.00
1
05/10/24 06:23
MSA
V47202
Naphthalene
<0.470
Ng/L
0.470
1.00
1
05/10/24 06:23
MSA
V47202
Propionitrile
<10.0
ug/L
10.0
10.0
1
05/15/2410:13
MSA
V47337
Styrene
<0.220
Ng/L
0.220
0.500
1
05/10/24 06:23
MSA
V47202
1,1,1,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
05/10/24 06:23
MSA
V47202
1,1,2,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
05/10/24 06:23
MSA
V47202
Tetrachloroethene
<0.220
ug/L
0.220
0.500
1
05/10/24 06:23
MSA
V47202
Tetrahydrofuran
<1.50
Ng/L
1.50
10.0
1
05/10/24 06:23
MSA
V47202
Toluene
<0.220
ug/L
0.220
0.500
1
05/10/24 06:23
MSA
V47202
1,2,4-Trichlorobenzene
<0.310
Ng/L
0.310
1.00
1
05/10/24 06:23
MSA
V47202
1,1,1-Trichloroethane
<0.160
ug/L
0.160
0.500
1
05/10/24 06:23
MSA
V47202
1,1,2-Trichloroethane
<0.096
Ng/L
0.096
0.500
1
05/10/24 06:23
MSA
V47202
Trichloroethene
<0.180
ug/L
0.180
0.500
1
05/10/24 06:23
MSA
V47202
Trichlorofluoromethane
<0.180
Ng/L
0.180
0.500
1
05/10/24 06:23
MSA
V47202
1,2,3-Trichloropropane
<0.270
ug/L
0.270
1.00
1
05/10/24 06:23
MSA
V47202
Vinyl Acetate
<1.00 M
Ng/L
1.00
2.00
1
05/10/24 06:23
MSA
V47202
Vinyl Chloride
<0.170
ug/L
0.170
0.500
1
05/10/24 06:23
MSA
V47202
o-Xylene
<0.210
Ng/L
0.210
0.500
1
05/10/24 06:23
MSA
V47202
m,p-Xylene
<0.420
ug/L
0.420
1.00
1
05/10/24 06:23
MSA
V47202
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
H
Beyond holding time
J
Estimated value
M
Minimum value
MQL
Method Quantitation Limit
Q
RPD >40% dual column results
Page 126 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
01186
Smith & Gardner, Inc.
Project
Seth C. Rickerts
14 N. Boylan Avenue
Information
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Surry County C&D/MSW Spring
Report Date : 05/31/2024
Received : 05/03/2024
Report Number : 24-124-0102
Lab No : 92552
Sample ID : Trip Blank
REPOR T OF A NA L YSIS
Matrix: Aqueous
Sampled: 5/1/2024 0:00
Analytical Method: 8260D
Prep Batch(es):
V47200 05/09/24 14:00
V47336
05/14/24 14:00
Prep Method: 5030E
Test
Results Units
MDL MQL DF
Date / Time By Analytical
Analyzed
Batch
Xylene (Total)
<0.21 Ng/L
0.210 0.500 1
05/10/24 06:23
V47202
Surrogate: 4-Bromofluorobenzene
101
Limits: 80-124%
1 05/10/24 06:23
MSA V47202
Surrogate: Dibromofluoromethane
101
Limits: 75-129%
1 05/10/24 06:23
MSA V47202
Surrogate: 1,2-Dichloroethane - d4
99.2
Limits: 63-136%
1 05/10/24 06:23
MSA V47202
Surrogate: Toluene-d8
100
Limits: 77-123%
1 05/10/24 06:23
MSA V47202
Surrogate:4-Bromofluorobenzene
99.4
Limits:80-124%
1 05/15/24 10:13
MSA V47337
Surrogate: Dibromofluoromethane
102
Limits: 75-129%
1 05/15/24 10:13
MSA V47337
Surrogate: 1,2-Dichloroethane - d4
104
Limits: 63-136%
1 05/15/24 10:13
MSA V47337
Surrogate: Toluene-d8
106
Limits: 77-123%
1 05/15/24 10:13
MSA V47337
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor H Beyond holding time
J Estimated value M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 127 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
(--Pace,
May 10, 2024
Angela Martin
Access Analytical
15 Thames Valley Rd
Irmo, SC 29063
RE: Project: 24-124-0102/Waypoint
Pace Project No.: 20316400
Dear Angela Martin:
Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
(225) 769-4900
Enclosed are the analytical results for sample(s) received by the laboratory on May 07, 2024. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Baton Rouge
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Devin McDougal
devin.mcdougal@pacelabs.com
(225) 769-4900
Project Manager
Enclosures
cc: Ashley Amick, Access Analytical
Angela Overcash, Waypoint Analytical
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
e
Page 128 of 200
Page 1 of 20
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
(--Pace,
Project: 24-124-0102/Waypo i nt
Pace Project No.: 20316400
Pace Analytical Services Baton Rouge
7979 Innovation Park Drive Ste A, Baton Rouge, LA
70820-7402
Louisiana Dept of Enviromental Quality (NELAC/LELAP):
01979
Florida Dept of Health (NELAC/FELAP): E87854
DoD ELAP (A2LA) #: 6429.01
Alabama DEM #: 41900
Alaska DEC-DW M LA00024
Alaska DEC CS -LAP #: 21-001
Arkansas DEQ #: 88-0655
California ELAP #: 3063
Georgia DPD M C050
Hawaii DOH State Laboratories Division
Illinois EPA#: 200048
Kansas DoHE #: E-10354
Kentucky DEP UST Branch M 123054
Louisiana DOH M LA036
Minnesota DOH #: 2233799
Mississippi State Dept of Health
Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
(225) 769-4900
CERTIFICATIONS
Montana Department of Environmental Quality
Nebraska DHHS #: NE-OS-35.21
Nevada DCNR DEP #: LA00024
New York DOH #: 12149
North Carolina DEQ - WW & GW #: 618
North Dakota DEQ #: R195
Ohio EPA#: 87782
Oklahoma Dept of Environmental Quality #: 9403
Oregon ELAP M 4168
Pennsylvania Dept of Environmental Protection #: 68-
05973
South Carolina DHEC #: 73006001
Texas CEQ #: T104704178-23-15
Utah DOH M LA00024
Virginia DCLS #: 6460215
Washington Dept of Ecology #: C929
Wisconsin DNR #: 399139510
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 129 of 200
Page 2 of 20
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
(--Pace,
SAMPLE SUMMARY
Project: 24-124-0102/Waypo i nt
Pace Project No.: 20316400
Lab ID
Sample ID
Matrix
Date Collected
Date Received
20316400001
MW-21
Water
05/01/24 15:45
05/07/24 09:40
20316400002
MW-9
Water
05/02/24 11:00
05/07/24 09:40
20316400003
MW-1
Water
05/02/24 12:30
05/07/24 09:40
20316400004
MW-11
Water
05/02/24 13:30
05/07/24 09:40
20316400005
MW-16
Water
05/02/24 14:45
05/07/24 09:40
20316400006
MW-15
Water
05/02/24 14:15
05/07/24 09:40
20316400007
MW-14
Water
05/02/24 14:30
05/07/24 09:40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
(225) 769-4900
Page 3 of 20
Page 130 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
(--Pace,
SAMPLE ANALYTE COUNT
Project: 24-124-0102/Waypo i nt
Pace Project No.: 20316400
Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
(225) 769-4900
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
20316400001
MW-21
RSK175
LHM
1
Pace ENV-SOP-BTRO-0042
VAM
10
20316400002
MW-9
RSK175
LHM
1
Pace ENV-SOP-BTRO-0042
VAM
10
20316400003
MW-1
RSK175
LIMB
1
Pace ENV-SOP-BTRO-0042
VAM
10
20316400004
MW-11
RSK175
LIMB
1
Pace ENV-SOP-BTRO-0042
VAM
10
20316400005
MW-16
RSK175
LIMB
1
Pace ENV-SOP-BTRO-0042
VAM
10
20316400006
MW-15
RSK175
LIMB
1
Pace ENV-SOP-BTRO-0042
VAM
10
20316400007
MW-14
RSK175
LIMB
1
Pace ENV-SOP-BTRO-0042
VAM
10
PASI-BR = Pace Analytical Services - Baton Rouge
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 131 of 200
Page 4 of 20
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
(--Pace,
PROJECT NARRATIVE
Project: 24-124-0102/Waypo i nt
Pace Project No.: 20316400
Method: RSK175
Description: BR RSK175 CO2 in Headspace
Client: WAYPOINTANALYTICAL NC
Date: May 10, 2024
Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
(225) 769-4900
General Information:
7 samples were analyzed for RSK175 by Pace Analytical Services Baton Rouge. All samples were received in acceptable condition
with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end
of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 132 of 200
Page 5 of 20
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
(--Pace,
PROJECT NARRATIVE
Project: 24-124-0102/Waypo i nt
Pace Project No.: 20316400
Method: Pace ENV-SOP-BTRO-0042
Description: BR AM23G Low Level VFA
Client: WAYPOINT ANALYTICALNC
Date: May 10, 2024
Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
(225) 769-4900
General Information:
7 samples were analyzed for Pace ENV-SOP-BTRO-0042 by Pace Analytical Services Baton Rouge. All samples were received in
acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR)
attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: 328117
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
• MW-1 (Lab ID: 20316400003)
• Lactic Acid
• MW-11 (Lab ID: 20316400004)
• Lactic Acid
• MW-14 (Lab ID: 20316400007)
• Lactic Acid
• MW-15 (Lab ID: 20316400006)
• Lactic Acid
• MW-16 (Lab ID: 20316400005)
• Lactic Acid
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 133 of 200
Page 6 of 20
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
(--Pace,
PROJECT NARRATIVE
Project: 24-124-0102/Waypo i nt
Pace Project No.: 20316400
Method: Pace ENV-SOP-BTRO-0042
Description: BR AM23G Low Level VFA
Client: WAYPOINT ANALYTICALNC
Date: May 10, 2024
Analyte Comments:
QC Batch: 328117
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
• MW-21 (Lab ID: 20316400001)
• Lactic Acid
• MW-9 (Lab ID: 20316400002)
• Lactic Acid
Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
(225) 769-4900
N2: The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A complete
list of accreditations/certifications is available upon request.
• BLANK (Lab ID: 1573299)
• Hexanoic Acid
• i-Hexanoic Acid
• i-Pentanoic Acid
• Pentanoic Acid
• LCS (Lab ID: 1573300)
• Hexanoic Acid
• i-Hexanoic Acid
• i-Pentanoic Acid
• Pentanoic Acid
• MS (Lab ID: 1573467)
• Hexanoic Acid
• i-Hexanoic Acid
• i-Pentanoic Acid
• Pentanoic Acid
• MSD (Lab ID: 1573468)
• Hexanoic Acid
• i-Hexanoic Acid
• i-Pentanoic Acid
• Pentanoic Acid
• MW-1 (Lab ID: 20316400003)
• Hexanoic Acid
• i-Hexanoic Acid
• i-Pentanoic Acid
• Pentanoic Acid
• MW-11 (Lab ID: 20316400004)
• Hexanoic Acid
• i-Hexanoic Acid
• i-Pentanoic Acid
• Pentanoic Acid
• MW-14 (Lab ID: 20316400007)
• Hexanoic Acid
• i-Hexanoic Acid
• i-Pentanoic Acid
• Pentanoic Acid
• MW-15 (Lab ID: 20316400006)
• Hexanoic Acid
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 134 of 200
Page 7 of 20
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
(--Pace,
PROJECT NARRATIVE
Project: 24-124-0102/Waypo i nt
Pace Project No.: 20316400
Method: Pace ENV-SOP-BTRO-0042
Description: BR AM23G Low Level VFA
Client: WAYPOINT ANALYTICALNC
Date: May 10, 2024
Analyte Comments:
QC Batch: 328117
Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
(225) 769-4900
N2: The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A complete
list of accreditations/certifications is available upon request.
• MW-15 (Lab ID: 20316400006)
• i-Hexanoic Acid
• i-Pentanoic Acid
• Pentanoic Acid
• MW-16 (Lab ID: 20316400005)
• Hexanoic Acid
• i-Hexanoic Acid
• i-Pentanoic Acid
• Pentanoic Acid
• MW-21 (Lab ID: 20316400001)
• Hexanoic Acid
• i-Hexanoic Acid
• i-Pentanoic Acid
• Pentanoic Acid
• MW-9 (Lab ID: 20316400002)
• Hexanoic Acid
• i-Hexanoic Acid
• i-Pentanoic Acid
• Pentanoic Acid
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 135 of 200
Page 8 of 20
Docusign Envelope ID: 889599EA-C817-4865-93DD-1 B8535D719AE Pace Analytical Services, LLC
mac7979 Innovation Park Drive
Q Baton Rouge, LA 70820
(225) 769-4900
ANALYTICAL RESULTS
Project: 24-124-0102/Waypo i nt
Pace Project No.: 20316400
Sample: MW-21 Lab ID: 20316400001 Collected: 05/01/24 15:45 Received: 05/07/24 09:40 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
BR RSK175 CO2 in Headspace
Analytical Method: RSK175
Pace Analytical Services - Baton Rouge
Carbon dioxide
259000 ug/L 1200
1
05/09/24 10:19
124-38-9
BR AM23G Low Level VFA
Analytical Method: Pace ENV-SOP-BTRO-0042
Pace Analytical Services - Baton Rouge
Pentanoic Acid
ND mg/L 5.0
10
05/08/24 16:19
109-52-4
N2
Acetic Acid
ND mg/L 5.0
10
05/08/24 16:19
64-19-7
Butyric Acid
ND mg/L 5.0
10
05/08/24 16:19
107-92-6
Formic acid
ND mg/L 5.0
10
05/08/24 16:19
64-18-6
Hexanoic Acid
ND mg/L 5.0
10
05/08/24 16:19
142-62-1
N2
i-Hexanoic Acid
ND mg/L 5.0
10
05/08/24 16:19
646-07-1
N2
Lactic Acid
ND mg/L 5.0
10
05/08/24 16:19
50-21-5
D3
i-Pentanoic Acid
ND mg/L 5.0
10
05/08/24 16:19
503-74-2
N2
Propionic Acid
ND mg/L 5.0
10
05/08/24 16:19
79-09-4
Pyruvic Acid
ND mg/L 5.0
10
05/08/24 16:19
127-17-3
Sample: MW-9
Lab ID: 20316400002 Collected: 05/02/24 11:00
Received: 05/07/24 09:40 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No.
Qual
BR RSK175 CO2 in Headspace
Analytical Method: RSK175
Pace Analytical Services - Baton Rouge
Carbon dioxide
164000 ug/L 1200
1
05/09/24 10:35
124-38-9
BR AM23G Low Level VFA
Analytical Method: Pace ENV-SOP-BTRO-0042
Pace Analytical Services - Baton Rouge
Pentanoic Acid
ND mg/L 10.0
20
05/08/24 17:42
109-52-4
N2
Acetic Acid
ND mg/L 10.0
20
05/08/24 17:42
64-19-7
Butyric Acid
ND mg/L 10.0
20
05/08/24 17:42
107-92-6
Formic acid
ND mg/L 10.0
20
05/08/24 17:42
64-18-6
Hexanoic Acid
ND mg/L 10.0
20
05/08/24 17:42
142-62-1
N2
i-Hexanoic Acid
ND mg/L 10.0
20
05/08/24 17:42
646-07-1
N2
Lactic Acid
ND mg/L 10.0
20
05/08/24 17:42
50-21-5
D3
i-Pentanoic Acid
ND mg/L 10.0
20
05/08/24 17:42
503-74-2
N2
Propionic Acid
ND mg/L 10.0
20
05/08/24 17:42
79-09-4
Pyruvic Acid
ND mg/L 10.0
20
05/08/24 17:42
127-17-3
Sample: MW-1
Lab ID: 20316400003 Collected: 05/02/24
12:30
Received: 05/07/24 09:40 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No.
Qual
BR RSK175 CO2 in Headspace Analytical Method: RSK175
Pace Analytical Services - Baton Rouge
Carbon dioxide 58000 ug/L 1200 1 05/09/24 10:51 124-38-9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/10/2024 09:48 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 20
Page 136 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1 B8535D719AE Pace Analytical Services, LLC
mac7979 Innovation Park Drive
Q Baton Rouge, LA 70820
(225) 769-4900
ANALYTICAL RESULTS
Project: 24-124-0102/Waypo i nt
Pace Project No.: 20316400
Sample: MW-1
Lab ID: 20316400003
Collected: 05/02/24
12:30
Received: 05/07/24 09:40 Matrix: Water
Parameters
Results Units
Report Limit
DF
Prepared Analyzed
CAS No.
Qual
BR AM23G Low Level VFA
Analytical Method: Pace ENV-SOP-BTRO-0042
Pace Analytical Services -
Baton Rouge
Pentanoic Acid
ND mg/L
1.0
2
05/08/24 18:07
109-52-4
N2
Acetic Acid
ND mg/L
1.0
2
05/08/24 18:07
64-19-7
Butyric Acid
ND mg/L
1.0
2
05/08/24 18:07
107-92-6
Formic acid
ND mg/L
1.0
2
05/08/24 18:07
64-18-6
Hexanoic Acid
ND mg/L
1.0
2
05/08/24 18:07
142-62-1
N2
i-Hexanoic Acid
ND mg/L
1.0
2
05/08/24 18:07
646-07-1
N2
Lactic Acid
ND mg/L
1.0
2
05/08/24 18:07
50-21-5
D3
i-Pentanoic Acid
ND mg/L
1.0
2
05/08/24 18:07
503-74-2
N2
Propionic Acid
ND mg/L
1.0
2
05/08/24 18:07
79-09-4
Pyruvic Acid
ND mg/L
1.0
2
05/08/24 18:07
127-17-3
Sample: MW-11 Lab ID: 20316400004 Collected: 05/02/24 13:30 Received: 05/07/24 09:40 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
BR RSK175 CO2 in Headspace
Analytical Method: RSK175
Pace Analytical Services - Baton Rouge
Carbon dioxide
226000 ug/L 1200
1
05/09/24 11:07
124-38-9
BR AM23G Low Level VFA
Analytical Method: Pace ENV-SOP-BTRO-0042
Pace Analytical Services - Baton Rouge
Pentanoic Acid
ND mg/L 1.0
2
05/08/24 18:31
109-52-4
N2
Acetic Acid
ND mg/L 1.0
2
05/08/24 18:31
64-19-7
Butyric Acid
ND mg/L 1.0
2
05/08/24 18:31
107-92-6
Formic acid
ND mg/L 1.0
2
05/08/24 18:31
64-18-6
Hexanoic Acid
ND mg/L 1.0
2
05/08/24 18:31
142-62-1
N2
i-Hexanoic Acid
ND mg/L 1.0
2
05/08/24 18:31
646-07-1
N2
Lactic Acid
ND mg/L 1.0
2
05/08/24 18:31
50-21-5
D3
i-Pentanoic Acid
ND mg/L 1.0
2
05/08/24 18:31
503-74-2
N2
Propionic Acid
ND mg/L 1.0
2
05/08/24 18:31
79-09-4
Pyruvic Acid
ND mg/L 1.0
2
05/08/24 18:31
127-17-3
Sample: MW-16
Lab ID: 20316400005 Collected: 05/02/24 14:45 Received:
05/07/24 09:40 Matrix: Water
Parameters
Results Units Report Limit
DF Prepared
Analyzed
CAS No.
Qual
BR RSK175 CO2 in Headspace
Analytical Method: RSK175
Pace Analytical Services - Baton Rouge
Carbon dioxide
357000 ug/L 1200
1
05/09/24 11:23
124-38-9
BR AM23G Low Level VFA
Analytical Method: Pace ENV-SOP-BTRO-0042
Pace Analytical Services - Baton Rouge
Pentanoic Acid
ND mg/L 5.0
10
05/08/2418:56
109-52-4
N2
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/10/2024 09:48 AM
without the written consent of Pace Analytical Services, LLC.
Page 10 of 20
Page 137 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1 B8535D719AE Pace Analytical Services, LLC
mac7979 Innovation Park Drive
Q Baton Rouge, LA 70820
(225) 769-4900
ANALYTICAL RESULTS
Project: 24-124-0102/Waypo i nt
Pace Project No.: 20316400
Sample: MW-16
Lab ID: 20316400005
Collected: 05/02/24
14:45
Received:
05/07/24 09:40 Matrix: Water
Parameters
Results Units
Report Limit
DF
Prepared
Analyzed
CAS No.
Qual
BR AM23G Low Level VFA
Analytical Method: Pace ENV-SOP-BTRO-0042
Pace Analytical Services -
Baton Rouge
Acetic Acid
ND mg/L
5.0
10
05/08/24 18:56
64-19-7
Butyric Acid
ND mg/L
5.0
10
05/08/24 18:56
107-92-6
Formic acid
ND mg/L
5.0
10
05/08/24 18:56
64-18-6
Hexanoic Acid
ND mg/L
5.0
10
05/08/24 18:56
142-62-1
N2
i-Hexanoic Acid
ND mg/L
5.0
10
05/08/24 18:56
646-07-1
N2
Lactic Acid
ND mg/L
5.0
10
05/08/24 18:56
50-21-5
D3
i-Pentanoic Acid
ND mg/L
5.0
10
05/08/24 18:56
503-74-2
N2
Propionic Acid
ND mg/L
5.0
10
05/08/24 18:56
79-09-4
Pyruvic Acid
ND mg/L
5.0
10
05/08/24 18:56
127-17-3
Sample: MW-15
Lab ID: 20316400006
Collected: 05/02/24 14:15
Received:
05/07/24 09:40 Matrix: Water
Parameters
Results Units
Report Limit
DF
Prepared
Analyzed
CAS No.
Qual
BR RSK175 CO2 in Headspace
Analytical Method: RSK175
Pace Analytical Services - Baton Rouge
Carbon dioxide
290000 ug/L 1200
1
05/09/24 11:39
124-38-9
BR AM23G Low Level VFA
Analytical Method: Pace ENV-SOP-BTRO-0042
Pace Analytical Services - Baton Rouge
Pentanoic Acid
ND mg/L 1.0
2
05/08/24 19:21
109-52-4
N2
Acetic Acid
ND mg/L 1.0
2
05/08/24 19:21
64-19-7
Butyric Acid
ND mg/L 1.0
2
05/08/24 19:21
107-92-6
Formic acid
ND mg/L 1.0
2
05/08/24 19:21
64-18-6
Hexanoic Acid
ND mg/L 1.0
2
05/08/24 19:21
142-62-1
N2
i-Hexanoic Acid
ND mg/L 1.0
2
05/08/24 19:21
646-07-1
N2
Lactic Acid
ND mg/L 1.0
2
05/08/24 19:21
50-21-5
D3
i-Pentanoic Acid
ND mg/L 1.0
2
05/08/24 19:21
503-74-2
N2
Propionic Acid
ND mg/L 1.0
2
05/08/24 19:21
79-09-4
Pyruvic Acid
ND mg/L 1.0
2
05/08/24 19:21
127-17-3
Sample: MW-14
Lab ID: 20316400007 Collected: 05/02/24 14:30
Received: 05/07/24 09:40 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No.
Qual
BR RSK175 CO2 in Headspace Analytical Method: RSK175
Pace Analytical Services - Baton Rouge
Carbon dioxide 149000 ug/L 1200 1 05/09/24 11:55 124-38-9
BR AM23G Low Level VFA Analytical Method: Pace ENV-SOP-BTRO-0042
Pace Analytical Services - Baton Rouge
Pentanoic Acid ND mg/L 1.0 2 05/08/2419:45 109-52-4 N2
Acetic Acid ND mg/L 1.0 2 05/08/2419:45 64-19-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/10/2024 09:48 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 20
Page 138 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1 B8535D719AE Pace Analytical Services, LLC
mac7979 Innovation Park Drive
Q Baton Rouge, LA 70820
(225) 769-4900
ANALYTICAL RESULTS
Project: 24-124-0102/Waypo i nt
Pace Project No.: 20316400
Sample: MW-14
Lab ID: 20316400007
Collected: 05/02/24
14:30
Received: 05/07/24 09:40 Matrix: Water
Parameters
Results Units
Report Limit
DF
Prepared Analyzed
CAS No.
Qual
BR AM23G Low Level VFA
Analytical Method: Pace ENV-SOP-BTRO-0042
Pace Analytical Services -
Baton Rouge
Butyric Acid
ND mg/L
1.0
2
05/08/24 19:45
107-92-6
Formic acid
ND mg/L
1.0
2
05/08/24 19:45
64-18-6
Hexanoic Acid
ND mg/L
1.0
2
05/08/24 19:45
142-62-1
N2
i-Hexanoic Acid
ND mg/L
1.0
2
05/08/24 19:45
646-07-1
N2
Lactic Acid
ND mg/L
1.0
2
05/08/24 19:45
50-21-5
D3
i-Pentanoic Acid
ND mg/L
1.0
2
05/08/24 19:45
503-74-2
N2
Propionic Acid
ND mg/L
1.0
2
05/08/24 19:45
79-09-4
Pyruvic Acid
ND mg/L
1.0
2
05/08/24 19:45
127-17-3
REPORT OF LABORATORY ANALYSIS
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Date: 05/10/2024 09:48 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 20
Page 139 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1 B8535D719AE Pace Analytical Services, LLC
mac7979 Innovation Park Drive
Q Baton Rouge, LA 70820
(225) 769-4900
QUALITY CONTROL DATA
Project: 24-124-0102/Waypo i nt
Pace Project No.: 20316400
QC Batch: 328294 Analysis Method: RSK175
QC Batch Method: RSK175 Analysis Description: BR RSK175 CO2 in Headspace
Laboratory: Pace Analytical Services - Baton Rouge
Associated Lab Samples: 20316400001, 20316400002, 20316400003, 20316400004, 20316400005, 20316400006, 20316400007
METHOD BLANK: 1574292 Matrix: Water
Associated Lab Samples: 20316400001, 20316400002, 20316400003, 20316400004, 20316400005, 20316400006, 20316400007
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Carbon dioxide ug/L ND 1200 05/09/24 09:52
LABORATORY CONTROL SAMPLE & LCSD: 1574293 1574294
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers
Carbon dioxide ug/L 33800 28100 28100 83 83 70-130 0 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/10/2024 09:48 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 20
Page 140 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1 B8535D719AE Pace Analytical Services, LLC
mac7979 Innovation Park Drive
Q Baton Rouge, LA 70820
(225) 769-4900
QUALITY CONTROL DATA
Project: 24-124-0102/Waypo i nt
Pace Project No.: 20316400
QC Batch: 328117 Analysis Method: Pace ENV-SOP-BTRO-0042
QC Batch Method: Pace ENV-SOP-BTRO-0042 Analysis Description: BRAM23G Low Level VFA
Laboratory: Pace Analytical Services - Baton Rouge
Associated Lab Samples: 20316400001, 20316400002, 20316400003, 20316400004, 20316400005, 20316400006, 20316400007
METHOD BLANK: 1573299
Matrix:
Water
Associated Lab Samples:
20316400001, 20316400002, 20316400003, 20316400004, 20316400005,
20316400006,
20316400007
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
Acetic Acid
mg/L
ND
0.50
05/08/24 15:30
Butyric Acid
mg/L
ND
0.50
05/08/24 15:30
Formic acid
mg/L
ND
0.50
05/08/24 15:30
Hexanoic Acid
mg/L
ND
0.50
05/08/24 15:30
N2
i-Hexanoic Acid
mg/L
ND
0.50
05/08/24 15:30
N2
i-Pentanoic Acid
mg/L
ND
0.50
05/08/24 15:30
N2
Lactic Acid
mg/L
ND
0.50
05/08/24 15:30
Pentanoic Acid
mg/L
ND
0.50
05/08/24 15:30
N2
Propionic Acid
mg/L
ND
0.50
05/08/24 15:30
Pyruvic Acid
mg/L
ND
0.50
05/08/24 15:30
LABORATORY CONTROL SAMPLE:
Parameter
1573300
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Acetic Acid
mg/L
2
1.8
91
70-130
Butyric Acid
mg/L
2
1.6
81
70-130
Formic acid
mg/L
2
1.8
92
70-130
Hexanoic Acid
mg/L
2
1.5
75
39-114 N2
i-Hexanoic Acid
mg/L
2
1.6
78
39-114 N2
i-Pentanoic Acid
mg/L
2
2.0
101
59-121 N2
Lactic Acid
mg/L
2
1.9
95
70-130
Pentanoic Acid
mg/L
2
1.8
89
59-121 N2
Propionic Acid
mg/L
2
1.7
87
70-130
Pyruvic Acid
mg/L
2
1.7
83
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1573467
MS
20316400001
Spike
Parameter
Units
Result
Conc.
Acetic Acid
mg/L
ND
20
Butyric Acid
mg/L
ND
20
Formic acid
mg/L
ND
20
Hexanoic Acid
mg/L
ND
20
i-Hexanoic Acid
mg/L
ND
20
i-Pentanoic Acid
mg/L
ND
20
Lactic Acid
mg/L
ND
20
Pentanoic Acid
mg/L
ND
20
1573468
MSD
Spike
MS
MSD
MS
MSD
% Rec
Max
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
20
18.5
18.1
89
87
70-130
2
30
20
17.7
15.5
88
78
70-130
13
30
20
20.4
18.4
102
92
70-130
10
30
20
15.0
14.8
75
74
39-114
2
30 N2
20
14.5
14.8
73
74
39-114
2
30 N2
20
18.9
20.3
95
101
59-121
7
30 N2
20
18.6
18.6
90
90
70-130
0
30
20
17.7
17.7
88
89
59-121
0
30 N2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/10/2024 09:48 AM without the written consent of Pace Analytical Services, LLC.
Page 14 of 20
Page 141 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1 B8535D719AE Pace Analytical Services, LLC
mac7979 Innovation Park Drive
Q Baton Rouge, LA 70820
(225) 769-4900
QUALITY CONTROL DATA
Project: 24-124-0102/Waypo i nt
Pace Project No.: 20316400
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1573467
1573468
MS
MSD
20316400001 Spike
Spike MS
MSD MS
MSD % Rec
Max
Parameter
Units
Result Conc.
Conc. Result
Result % Rec
% Rec Limits
RPD RPD Qual
Propionic Acid
mg/L
ND 20
20 21.4
16.9 107
84 70-130
24 30
Pyruvic Acid
mg/L
ND 20
20 17.1
16.4 85
82 70-130
4 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/10/2024 09:48 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 20
Page 142 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
(--Pace,
QUALIFIERS
Project: 24-124-0102/Waypo i nt
Pace Project No.: 20316400
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
(225) 769-4900
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
INC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The Nelac Institute
ANALYTE QUALIFIERS
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
N2 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/10/2024 09:48 AM without the written consent of Pace Analytical Services, LLC.
Page 16 of 20
Page 143 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
(--Pace,
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: 24-124-0102/Waypo i nt
Pace Project No.: 20316400
Lab ID Sample ID QC Batch Method QC Batch
20316400001
MW-21
RSK175
328294
20316400002
MW-9
RSK175
328294
20316400003
MW-1
RSK175
328294
20316400004
MW-11
RSK175
328294
20316400005
MW-16
RSK175
328294
20316400006
MW-15
RSK175
328294
20316400007
MW-14
RSK175
328294
20316400001
MW-21
Pace ENV-SOP-BTRO-
328117
0042
20316400002
MW-9
Pace ENV-SOP-BTRO-
328117
0042
20316400003
MW-1
Pace ENV-SOP-BTRO-
328117
0042
20316400004
MW-11
Pace ENV-SOP-BTRO-
328117
0042
20316400005
MW-16
Pace ENV-SOP-BTRO-
328117
0042
20316400006
MW-15
Pace ENV-SOP-BTRO-
328117
0042
20316400007
MW-14
Pace ENV-SOP-BTRO-
328117
0042
Date: 05/10/2024 09:48 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
(225) 769-4900
Analytical Method
Analytical
Batch
Page 17 of 20
Page 144 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
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Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
WO#:20316400
PM: DRM Cue Catet O5/21/24
f ice Sample Condition Upa� CLIENT: BR-WAYPOI_NC
'l 0rxor®er ;;:
7979 Innovation Park dr. Baton Rouge, L4 70806
Cooler Inspected bV/date: W / L
Me of receipt: Pace LICliepit LJUPS edEx Other:
Yes
❑ No
Were c stady seals present on the Cooler?
Yes
I ❑ No 10 NA
I If Custody seals were present, were they lntac[ and unbroken?
Method: LiTernpera ture Blank gaIrst Bottles I Gun ID:
1R Gun Correction actor. °C
Cooler #1 Cooler Temp `C-- (ACual�True)
Samples on ice 7pH Strip Lot#
Cooler #2 Cooler Temp °C: (Actual/7rue)
es ❑ No
Cooler #3 Cooler Temp -C: (A=airrruej
Method coolant:
(--1 RA r-1., Tame 'r• (Artt iai/Tm Po
r ' lira P.,&. M r7n, Ira ❑ M-0
Tracfcing#' 776 Z- C 7
05'Yes
❑ No
❑ NA
is a temperature blank present?
�ZrYes 1
❑ No
❑ NA
Was o chain of custody (COC) recieved?
❑ Yes
No
❑ NA
Was the line and profile number listed on the COC?
I Y5es
❑ No
El NA
Weie ail coolers received at or helow 5.TV If no, notify
Project Mana er ratified via email.
Yes
❑ No
Were proper custody procedures (relinquished/received)
failawed?
❑ Yes
oNo
❑ NA I
Is the sampler name and signature an tfse COC?
Q—Yes
El No
Were sample IOs listed on the COC and all sample
containers?
Yes
❑ No
was coileCGan date $dime listed on the COC and all sample
Containers?
Yes
❑ Na7
Did all container label Irrformation (ID, date, time! agree with
the COC1
; -Yes
❑ No
Were tests to he performed listed on the COO
❑id ail samples arrive in the proper containers for each test
Yes
Cl No
and/or in good condition
[unbroken, lids on, erC.}?
iff Yes
❑ No
Was adequate sample volume available?
Yes
❑ No
Were all samples received within h the holding time or 48
hours, whichever comes first?
❑ Yes
Were all samples containers accounted for? (No missing
excess)
Were VOA, 8015C (GRO/VPH), and IRS K-7.75 samples free of
P"I'as1
❑ No
❑ NA
k]ubhias � "pea size" (1/4" ar 6mm in diameter) in any of the
VGA vials?
Cl Yes
No
❑ NA
Trip blank present?
❑ Yes
❑ No
�NA
Fi tered volume recerve rot issc ve tests.
1 n list ecreti am le s in common below.
❑ Yes
E] No
?�'NA
Were all rnanIs/nutriant samples received at a of c 2?
if No, was preservative added? ❑Yes ❑No
pH
If added, record lots. Dispenser/pipette lot#:
HNO, _ HsSOa NaOH
❑ Yes
❑ No
NA
P
Were ail cyanide samples received at a pH > 12 and sulfde
I
samples received at a pH a 9?
Date: rime;
Conmments-
4
0
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ca
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E feedve pate: 07ltgl23 Ne%t Revi_w Dace: 67/19j?a Page 2 or 1
Page 147 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
Page 1 of 4
R050801
ECHNOLGGY
Laboratories, Inc.
May 29, 2024
Waypoint Analytical, LLC
ATTN: Angela Overcash
449 Springbrook Rd..
Charlotte. NC 28217
LABORATORY TEST RESULTS
Project Number: 24-124-0102
Lab Number: R050801-01104
LA Cert #04140
EPA Merhoos T05 TOI4A, To15. 25CISC
ASTM 01946 RSft1T5
TX Cert T104704450-14-6
EPA Melhvds TOI4A T015
L T Cert CAO133332015-3
EPA Methods T03, T014A, T015. RSK-175
Enclosed are results for sample(s) received 5i08124 by Air Technology Laboratories.
Samples were received intact. Analyses were performed according to specifications on
the chain of custody provided with the samples).
Report Narrative:
Unless otherwise noted in the report, sample analyses were performed within
method performance criteria and meet all requirements of the TNI Standards.
The enclosed results relate only to the sample(s).
ATL appreciates the opportunity to provide testing services to your company. If you
have any questions regarding these results, please call me at (626) 964-4032.
Sincerely,
>) - i
Mark Johnson
Operations Manager
MJohnson@Ai rTec hL abs. c om
Note: The cover letter is an integral part of this analytical report.
18501 E. Gale Avenue, Suite 130 ♦ City of Industry, CA 91748 0 Ph: (626) 964-4032 • Fx: (626) 964-5832
Page 148 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
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Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
Page 3 of 4
R050801
Client:
Waypoint Analytical, LLC
Attn:
Angela Overeaslt
Project Name:
NA
Project No.:
24-124-0102
Date Received:
05/08/24
Matrix:
Water
Reporting units:
uglL
RSK175
Lab No.:
R050801-01
R050801-02
R050801-03
R050801-04
Client Sample I.D,;
MW-21 (92542)
MW-9 (92544)
MW-1 (92546)
MW-11 (92547)
Date/Tine Sampled:
5I1124 15:45
512l24 11:00
512124 12:30
512124 13:30
Date/Time Analyzed:
5J14/24 14:27
5/14/24 14:37
5/14/24 14:47
5114l24 14:58
QC Batch No.:
240514GC8AI
240514GC8A1
240514GC8A1
240514GCSAI
Analyst Initials:
AS
AS
AS
AS
Dilution Factor:
Lo
1.0
1.0
1.0
ANALYTE
Result
uglL
RL
uglL
Result
uglL
RL
uglL
Result
ugll,
RL
uglL
Result
ng/L
RL
uglL
ti�dro en
NO
10
NO
10
NO
Iil
ND
10
NO = Not detected (below RL)
RL = Reporting Limit
Reviewe&Approved By: ASpate
AK Johnson
Operations Manager
The cover Inter is an integral part ofthis analytical report
'o
-LAA AirTECHNOLOGY Laboratories, Inc. oage 1 of 1
18501 E. Gale Avenue, Suite 130 t City of Industry, CA 91748 * Ph: (626) 964-4032 * Fx: (626) 964-5832
Page 150 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
Page 4 of 4
R050801
QC Ratcit No: 240514GC8A1
Matrix: Water
Reporting Units: uglL
RSK 175
LABORATORY CONTROL SAMPLE SUMMARY
Lab No.:
METHOD BLANK
LCS
L,CSD
Litnit�
Date/Time Analyzed:
5/14/24 11:12
5/14/24 9:46
5114124 10:05
Analyst Initials:
AS
A5
AS
Dilution Factor:
1.0
1.0
1.0
ANALYTE
Result
uglL
RL
ug/L
MIKE
AM'1.
ugll
Result
ug/L
% Ree.
Result
ug/L
I% Rec.
RPD
%
Low
%Rec
Hi h
g
'%Ree
Max.
RPD
Hydrogen
ND
10
92
109
118
109
111)
(i.2
"11
130
31)
ND = Not Detected (helon RL)
RL = Reporting limit
Date -
Mark
Re,dewed/A roved r-w3 hA rf�
PP BY '
Minson
Operations Manager
The cover letter is an inteb*ral part of this analytical report
J�U--A AirTECHHOLOGY Laboratories, Inc. page 1 of i
I B501 E. Gate Avenue, Suite 130 ♦ City of industry, CA 91748 • Ph: (626) 984-4032 a Fx: (628) 964-5832
Page 151 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
• i
Way po�nt ^ 449 Springl,rQok Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
Quality Control Data
Client ID:
Smith & Gardner, Inc.
Project Description:
Surry County C&D/MSW Spring
Report No:
24-124-0102
QC Analytical Batch:
V46999
Analysis Method:
2320B-2011
Analysis Description:
Alkalinity
Lab Reagent Blank
LRB
Matrix: AQU
Associated Lab Samples:
92542, 92544, 92546, 92547, 92548, 92549, 92550
Blank MDL
MQL
Analyzed
Parameter
Units Result
Alkalinity (as CaCO3)
pg/L <800 800
5000
05/08/24 15:40
Laboratory Control Sample LCS
Spike
LCS
LCS %Rec % Rec
Parameter
Units Conc.
Result
Limits
Alkalinity (as CaCO3)
pg/L 250000
246000
98.0 90-110
Duplicate
V 92548-DUP
Result DUP
RPD Max RPD
Analyzed
Parameter
Units Result
Alkalinity (as CaCO3)
pg/L 155000 160000
3.1 20
05/08/24 15:40
Date: 05/31/2024 01:51 PM Page 1 of 46
Page 152 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Analytical Batch: V46900
Analysis Method: 4500S2F-2011
Analysis Description: Sulfide
Lab Reagent Blank LRB Matrix: AQU
Associated Lab Samples: 92542, 92544, 92546, 92547, 92548, 92549, 92550
Blank MDL MQL Analyzed
Parameter Units Result
Sulfide pg/L <830 830 2000 05/06/2414:53
Laboratory Control Sample & LCSD LCS LCSD
Spike
Parameter Units Conc.
Sulfide
pg/L 10000
LCS LCSD LCS LCSD % Rec
Result Result %Rec % Rec Limits RPD Max
RPD
9100 8300 91.0 83.0 70-122 9.1 10
Date: 05/31/2024 01:51 PM Page 2 of 46
Page 153 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Analytical Batch: V47033
Analysis Method: 5210B-2015
Analysis Description: Biochemical Oxygen Demand (BOD)
Glucose-Glutamic Acid GGA
Result Range Analyzed
Parameter Units
Biochemical Oxygen Demand (5-day) pg/L 190 167.5-228.E 05/03/24 10:39
Duplicate V 92625-DUP
Result DUP RPD Max RPD Analyzed
Parameter Units Result
Biochemical Oxygen Demand (5-day) pg/L 316000 321000 1.5 30 05/03/24 10:39
Date: 05/31/2024 01:51 PM Page 3 of 46
Page 154 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
• i
Way po�nt ^ 449 SpringttrQok Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Analytical Batch: V47070
Analysis Method: 5220D-2011
Analysis Description: Chemical Oxygen Demand (COD)
Lab Reagent Blank LRB
Matrix: AQU
Associated Lab Samples: 92542, 92544, 92546, 92547, 92548, 92549, 92550
Blank MDL
MQL
Analyzed
Parameter Units Result
COD (Chemical Oxygen Demand) pg/L <15000 15000
30000
05/09/24 11:25
Laboratory Control Sample & LCSD LCS LCSD
Spike
LCS LCSD
LCS
LCSD
% Rec
Parameter Units Conc.
Result Result
%Rec
a/o Rec
Limits
RPD Max
RPD
COD (Chemical Oxygen Demand) pg/L 50000
47000 47000
94.0
94.0
90-110
0.0 20
Matrix Spike & Matrix Spike Duplicate V 92861-MS V 92861-MSD
MS Spike
MSD MS Result
MSD
MS
MSD
%Rec Max
Parameter Units Result Conc.
Spike
Result
%Rec
%Rec
Limits RPD RPD
Conc.
COD (Chemical Oxygen Demand) pg/L <15000 50000
50000 69000
61000
138*
122*
80-120 12.3 20
* QC Fail Date: 05/31/2024 01:51 PM Page 4 of 46
Page 155 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
i
Way o�nt
449 Spring#�rQok Rd, Charlotte, NC 28217
p
^
Main 704.529.6364
ANALYTICAL
www.waypoi ntana lytica l.com
Quality
Control Data
Client ID:
Smith & Gardner, Inc.
Project Description:
Surry County C&D/MSW Spring
Report No:
24-124-0102
QC Prep:
L749521
QC Analytical Batch(es): L749571
QC Prep Batch Method:
5310C-2011
Analysis Method:
5310C-2011
Analysis Description:
Total Organic Carbon
Lab Reagent Blank
LRB-L749521
Matrix: AQU
Associated Lab Samples:
92542, 92544, 92546
Blank MDL
MQL
Analyzed
Parameter
Units
Result
TOC
pg/L
<720 720
1000
05/08/2413:15
Laboratory Control Sample
LCS-L749521
Spike
LCS
LCS %Rec % Rec
Parameter
Units
Conc.
Result
Limits
TOC
pg/L
1000
1080
108 50-150
Duplicate
Q 94513-DUP-L749521
Result DUP
RPD Max RPD
Analyzed
Parameter
Units
Result
TOC
pg/L
1730 1640
5.3 15
05/08/24 20:54
Matrix Spike
Q 94512-MS-L749521
MS Spike
MSD MS Result
MSD MS %Rec Max
Parameter
Units
Result Conc.
Spike
Result %Rec Limits RPD
Conc.
TOC
pg/L
2400 5260
7830
103 85-115
Date: 05/31/2024 01:51 PM Page 5 of 46
Page 156 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Prep: L749524 QC Analytical Batch(es): L749571
QC Prep Batch Method: 5310C-2011 Analysis Method: 5310C-2011
Analysis Description: Total Organic Carbon
Lab Reagent Blank LRB-L749524 Matrix: AQU
Associated Lab Samples: 92547, 92548, 92549, 92550
Blank MDL MQL Analyzed
Parameter Units Result
TOC pg/L <720 720 1000 05/08/24 21:32
Laboratory Control Sample & LCSD LCS-L749524 LCSD-L749524
Spike LCS LCSD LCS LCSD % Rec
Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max
RPD
TOC pg/L 1000 1140 1190 114 119 50-150 4.2 20
Date: 05/31/2024 01:51 PM Page 6 of 46
Page 157 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Prep: L749613
QC Analytical Batch(es): L750031,L750215
QC Prep Batch Method: 3005A
Analysis Method:
6020B
Analysis Description:
Metals Analyses
Lab Reagent Blank
LRB-L749613
Matrix: AQU
Associated Lab Samples: 92542, 92543, 92544,
92545,
92546
Blank
MDL
MQL
Analyzed
Parameter
Units
Result
Antimony
pg/L
<0.618
0.618
1.00
05/10/24 20:38
Arsenic
pg/L
<0.297
0.297
1.00
05/10/24 20:38
Barium
pg/L
<0.453
0.453
1.00
05/10/24 20:38
Beryllium
pg/L
<0.102
0.102
1.00
05/10/24 20:38
Cadmium
pg/L
<0.350
0.350
1.00
05/10/24 20:38
Chromium
pg/L
<0.346
0.346
1.00
05/10/24 20:38
Cobalt
pg/L
<0.060
0.060
1.00
05/10/24 20:38
Copper
pg/L
<0.489
0.489
1.00
05/10/24 20:38
Lead
pg/L
<0.264
0.264
1.00
05/10/24 20:38
Nickel
pg/L
<0.182
0.182
1.00
05/10/24 20:38
Selenium
pg/L
<0.703
0.703
1.00
05/10/24 20:38
Silver
pg/L
<0.0570
0.0570
1.00
05/10/24 20:38
Tin
pg/L
1.47
1.44
5.00
05/13/2415:37
Thallium
pg/L
<0.0610
0.0610
1.00
05/10/24 20:38
Vanadium
pg/L
0.806
0.767
5.00
05/10/24 20:38
Zinc
pg/L
<4.67
4.67
10.0
05/10/24 20:38
Laboratory Control Sample
LCS-L749613
Spike
LCS
LCS %Rec
% Rec
Parameter
Units
Conc.
Result
Limits
Antimony
pg/L
100
98.1
98.0
80-120
Arsenic
pg/L
50.0
50.4
101
80-120
Barium
pg/L
100
92.3
92.0
80-120
Beryllium
pg/L
50.0
50.3
101
80-120
Cadmium
pg/L
10.0
9.84
98.0
80-120
Chromium
pg/L
100
99.2
99.0
80-120
Cobalt
pg/L
100
95.9
96.0
80-120
Date: 05/31/2024 01:51 PM Page 7 of 46
Page 158 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Prep: L749613 QC Analytical Batch(es): L750031,L750215
QC Prep Batch Method: 3005A Analysis Method: 6020B
Analysis Description: Metals Analyses
Laboratory Control Sample LCS-L749613
Parameter
Units
Spike
Conc.
LCS
Result
LCS %Rec
% Rec
Limits
Copper
pg/L
50.0
50.0
100
80-120
Lead
pg/L
50.0
49.0
98.0
80-120
Nickel
pg/L
50.0
51.2
102
80-120
Selenium
pg/L
100
104
104
80-120
Silver
pg/L
10.0
9.65
97.0
80-120
Tin
pg/L
500
512
102
80-120
Thallium
pg/L
10.0
9.74
97.0
80-120
Vanadium
pg/L
500
496
99.0
80-120
Zinc
pg/L
500
499
100
80-120
Matrix Spike & Matrix Spike Duplicate
Parameter Units
V 92546-MS-L749613
MS Spike
Result Conc.
V 92546-MSD-L749613
MSD MS Result MSD
Spike Result
Conc.
MS
%Rec
MSD
%Rec
%Rec
Limits
RPD
Max
RPD
Antimony
pg/L
< 0.618
100
100
96.5
96.6
97.0
97.0
75-125
0.1
20.0
Arsenic
pg/L
0.552
50.0
50.0
50.2
49.9
99.0
99.0
75-125
0.5
20.0
Barium
pg/L
57.0
100
100
184
183
127*
126*
75-125
0.5
20.0
Beryllium
pg/L
< 0.102
50.0
50.0
49.7
49.7
99.0
99.0
75-125
0.0
20.0
Cadmium
pg/L
< 0.350
10.0
10.0
10.1
10.1
101
101
75-125
0.0
20.0
Chromium
pg/L
0.748
100
100
99.3
100
99.0
99.0
75-125
0.7
20.0
Cobalt
pg/L
1.71
100
100
98.7
98.2
97.0
96.0
75-125
0.5
20.0
Copper
pg/L
1.24
50.0
50.0
51.4
51.2
100
100
75-125
0.3
20.0
Lead
pg/L
< 0.264
50.0
50.0
49.4
49.7
99.0
99.0
75-125
0.6
20.0
Nickel
pg/L
1.90
50.0
50.0
53.3
52.7
103
102
75-125
1.1
20.0
Selenium
pg/L
< 0.703
100
100
99.3
102
99.0
102
75-125
2.6
20.0
Silver
pg/L
< 0.0570
10.0
10.0
9.61
9.69
96.0
97.0
75-125
0.8
20.0
Tin
pg/L
< 1.44
500
500
539
540
108
108
75-125
0.1
20.0
* QC Fail Date: 05/31/2024 01:51 PM Page 8 of 46
Page 159 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
• i
Way po�nt ^ 449 SpringttrQok Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
Quality Control Data
Client ID:
Smith & Gardner, Inc.
Project Description:
Surry County C&D/MSW Spring
Report No:
24-124-0102
QC Prep:
L749613
QC Analytical Batch(es): L750031,L750215
QC Prep Batch Method:
3005A
Analysis Method:
6020B
Analysis Description:
Metals Analyses
Matrix Spike & Matrix Spike
Duplicate
V 92546-MS-L749613 V 92546-MSD-L749613
MS Spike
MSD MS Result
MSD MS
MSD %Rec Max
Parameter
Units
Result Conc.
Spike
Result %Rec
%Rec Limits RPD RPD
Conc.
Thallium
pg/L
< 0.0610 10.0
10.0 9.97
10.1 100
101 75-125 1.2 20.0
Vanadium
pg/L
2.64 500
500 491
498 98.0
99.0 75-125 1.4 20.0
Zinc
pg/L
10.8 500
500 511
505 100
99.0 75-125 1.1 20.0
Post Digestion Spike
V 92546-PDS-L749613
PDS
%
Analyzed
Parameter
Units
Result
Recovery
Antimony
pg/L
34.0
68.0*
05/10/24 22:20
Arsenic
pg/L
18.2
72.0*
05/10/24 22:20
Barium
pg/L
41.1
52.0*
05/10/24 22:20
Beryllium
pg/L
18.5
74.0*
05/10/24 22:20
Cadmium
pg/L
3.66
73.0*
05/10/24 22:20
Chromium
pg/L
35.7
71.0*
05/10/24 22:20
Cobalt
pg/L
36.2
71.0*
05/10/24 22:20
Copper
pg/L
18.6
72.0*
05/10/24 22:20
Lead
pg/L
18.1
72.0*
05/10/24 22:20
Nickel
pg/L
19.0
73.0*
05/10/24 22:20
Selenium
pg/L
36.7
73.0*
05/10/24 22:20
Silver
pg/L
3.51
70.0*
05/10/24 22:20
Tin
pg/L
283
113
05/13/24 17:01
Thallium
pg/L
3.70
74.0*
05/10/24 22:20
Vanadium
pg/L
151
60.0*
05/10/24 22:20
Zinc
pg/L
191
75.0
05/10/24 22:20
* QC Fail Date: 05/31/2024 01:51 PM Page 9 of 46
Page 160 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Prep: L749864
QC Analytical Batch(es): L750216,L750450
QC Prep Batch Method: 3005A
Analysis Method:
6020B
Analysis Description:
Metals Analyses
Lab Reagent Blank
LRB-L749864
Matrix: AQU
Associated Lab Samples: 92547, 92548, 92549,
92550,
92551
Blank
MDL
MQL
Analyzed
Parameter
Units
Result
Antimony
pg/L
<0.618
0.618
1.00
05/13/24 23:58
Arsenic
pg/L
<0.297
0.297
1.00
05/13/24 23:58
Barium
pg/L
<0.453
0.453
1.00
05/13/24 23:58
Beryllium
pg/L
<0.102
0.102
1.00
05/13/24 23:58
Cadmium
pg/L
<0.350
0.350
1.00
05/14/2419:16
Chromium
pg/L
<0.346
0.346
1.00
05/14/2419:16
Cobalt
pg/L
<0.060
0.060
1.00
05/13/24 23:58
Copper
pg/L
<0.489
0.489
1.00
05/13/24 23:58
Lead
pg/L
<0.264
0.264
1.00
05/13/24 23:58
Nickel
pg/L
<0.182
0.182
1.00
05/14/2419:16
Selenium
pg/L
<0.703
0.703
1.00
05/13/24 23:58
Silver
pg/L
<0.0570
0.0570
1.00
05/14/2419:16
Tin
pg/L
1.50
1.44
5.00
05/13/24 23:58
Thallium
pg/L
<0.0610
0.0610
1.00
05/13/24 23:58
Vanadium
pg/L
<0.767
0.767
5.00
05/13/24 23:58
Zinc
pg/L
<4.67
4.67
10.0
05/13/24 23:58
Laboratory Control Sample
LCS-L749864
Spike
LCS
LCS %Rec
% Rec
Parameter
Units
Conc.
Result
Limits
Antimony
pg/L
100
97.7
98.0
80-120
Arsenic
pg/L
50.0
44.7
89.0
80-120
Barium
pg/L
100
99.5
100
80-120
Beryllium
pg/L
50.0
49.2
98.0
80-120
Cadmium
pg/L
10.0
9.43
94.0
80-120
Chromium
pg/L
100
95.9
96.0
80-120
Cobalt
pg/L
100
94.1
94.0
80-120
Date: 05/31/2024 01:51 PM Page 10 of 46
Page 161 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Prep: L749864 QC Analytical Batch(es): L750216,L750450
QC Prep Batch Method: 3005A Analysis Method: 6020B
Analysis Description: Metals Analyses
Laboratory Control Sample LCS-L749864
Parameter
Units
Spike
Conc.
LCS
Result
LCS %Rec
% Rec
Limits
Copper
pg/L
50.0
46.3
93.0
80-120
Lead
pg/L
50.0
43.8
88.0
80-120
Nickel
pg/L
50.0
47.5
95.0
80-120
Selenium
pg/L
100
92.9
93.0
80-120
Silver
pg/L
10.0
9.18
92.0
80-120
Tin
pg/L
500
520
104
80-120
Thallium
pg/L
10.0
9.08
91.0
80-120
Vanadium
pg/L
500
500
100
80-120
Zinc
pg/L
500
453
91.0
80-120
Matrix Spike & Matrix Spike Duplicate
Parameter Units
L 88989-MS-L749864
MS Spike
Result Conc.
L 88989-MSD-L749864
MSD MS Result MSD
Spike Result
Conc.
MS
%Rec
MSD
%Rec
%Rec
Limits
RPD
Max
RPD
Antimony
pg/L
< 0.618
100
100
101
101
101
101
75-125
0.0
20.0
Arsenic
pg/L
0.449
50.0
50.0
47.3
46.2
94.0
92.0
75-125
2.3
20.0
Barium
pg/L
82.6
100
100
180
183
97.0
100
75-125
1.6
20.0
Beryllium
pg/L
< 0.102
50.0
50.0
50.8
49.7
102
99.0
75-125
2.1
20.0
Cadmium
pg/L
0.422
10.0
10.0
10.1
10.2
97.0
98.0
75-125
0.9
20.0
Chromium
pg/L
1.59
100
100
104
104
102
102
75-125
0.0
20.0
Cobalt
pg/L
1.37
100
100
101
100
100
99.0
75-125
0.9
20.0
Copper
pg/L
4.95
50.0
50.0
52.5
51.2
95.0
93.0
75-125
2.5
20.0
Lead
pg/L
1.02
50.0
50.0
46.2
47.5
90.0
93.0
75-125
2.7
20.0
Nickel
pg/L
2.61
50.0
50.0
52.8
52.5
100
100
75-125
0.5
20.0
Selenium
pg/L
< 0.703
100
100
96.9
96.5
97.0
97.0
75-125
0.4
20.0
Silver
pg/L
< 0.0570
10.0
10.0
9.46
9.52
95.0
95.0
75-125
0.6
20.0
Tin
pg/L
1.56
500
500
547
544
109
108
75-125
0.5
20.0
Date: 05/31/2024 01:51 PM Page 11 of 46
Page 162 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
• i
Way po�nt ^ 449 SpringttrQok Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
Quality Control Data
Client ID:
Smith & Gardner, Inc.
Project Description:
Surry County C&D/MSW Spring
Report No:
24-124-0102
QC Prep:
L749864
QC Analytical Batch(es): L750216,L750450
QC Prep Batch Method:
3005A
Analysis Method:
6020B
Analysis Description:
Metals Analyses
Matrix Spike & Matrix Spike
Duplicate
L 88989-MS-L749864 L 88989-MSD-L749864
MS Spike
MSD MS Result
MSD MS
MSD %Rec Max
Parameter
Units
Result Conc.
Spike
Result %Rec
%Rec Limits RPD RPD
Conc.
Thallium
pg/L
0.0661 10.0
10.0 9.48
9.71 94.0
96.0 75-125 2.3 20.0
Vanadium
pg/L
< 0.767 500
500 522
527 104
105 75-125 0.9 20.0
Zinc
pg/L
11.8 500
500 479
478 93.0
93.0 75-125 0.2 20.0
Post Digestion Spike
L 88989-PDS-L749864
PDS
%
Analyzed
Parameter
Units
Result
Recovery
Antimony
pg/L
51.4
103
05/14/24 02:04
Arsenic
pg/L
23.4
93.0
05/14/24 02:04
Barium
pg/L
91.6
100
05/14/24 02:04
Beryllium
pg/L
25.2
101
05/14/24 02:04
Cadmium
pg/L
5.12
98.0
05/14/24 21:03
Chromium
pg/L
46.5
92.0
05/14/24 02:04
Cobalt
pg/L
46.7
92.0
05/14/24 02:04
Copper
pg/L
25.4
92.0
05/14/24 02:04
Lead
pg/L
24.0
94.0
05/14/24 02:04
Nickel
pg/L
26.0
99.0
05/14/24 21:03
Selenium
pg/L
48.1
96.0
05/14/24 02:04
Silver
pg/L
4.87
97.0
05/14/24 21:03
Tin
pg/L
266
106
05/14/24 02:04
Thallium
pg/L
4.79
95.0
05/14/24 02:04
Vanadium
pg/L
263
105
05/14/24 02:04
Zinc
pg/L
242
95.0
05/14/24 21:03
Date: 05/31/2024 01:51 PM Page 12 of 46
Page 163 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
i
Way o�nt
449 SpringttrQok Rd, Charlotte, NC 28217
p
^
Main 704.529.6364
ANALYTICAL
www.waypoi ntana lytica l.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Prep: L749704
QC Analytical Batch(es): L749834
QC Prep Batch Method: 7470A
Analysis Method:
7470A
Analysis Description:
Total Aqueous Mercury Analysis - CVAA
Lab Reagent Blank
LRB-L749704
Matrix: AQU
Associated Lab Samples: 92542
Blank MDL
MQL
Analyzed
Parameter Units
Result
Mercury (Total) pg/L
<0.100 0.100
0.200
05/10/24 13:48
Laboratory Control Sample
LCS-L749704
Spike
LCS
LCS %Rec % Rec
Parameter Units
Conc.
Result
Limits
Mercury (Total) pg/L
4.00
3.84
96.0 80-120
Matrix Spike & Matrix Spike Duplicate
V 92542-MS-L749704 V 92542-MSD-L749704
MS Spike
MSD MS Result
MSD MS MSD %Rec Max
Parameter Units
Result Conc.
Spike
Result %Rec %Rec Limits RPD RPD
Conc.
Mercury (Total) pg/L
<0.100 4.00
4.00 2.89
2.88 72.0* 72.0* 80-120 0.3 20
Post Digestion Spike
V 92542-PDS-L749704
PDS
%
Analyzed
Parameter Units
Result
Recovery
Mercury (Total) pg/L
4.81
96.0
05/10/24 14:30
* QC Fail Date: 05/31/2024 01:51 PM Page 13 of 46
Page 164 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
i
Way o�nt
449 SpringttrQok Rd, Charlotte, NC 28217
p
^
Main 704.529.6364
ANALYTICAL
www.waypoi ntana lytica l.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Prep: L749975
QC Analytical Batch(es): L750164
QC Prep Batch Method: 7470A
Analysis Method:
7470A
Analysis Description:
Total Aqueous Mercury Analysis - CVAA
Lab Reagent Blank
LRB-L749975
Matrix: AQU
Associated Lab Samples: 92544, 92546, 92547, 92548, 92549, 92550
Blank MDL
MQL
Analyzed
Parameter Units
Result
Mercury (Total) pg/L
<0.100 0.100
0.200
05/13/24 14:44
Laboratory Control Sample
LCS-L749975
Spike
LCS
LCS %Rec % Rec
Parameter Units
Conc.
Result
Limits
Mercury (Total) pg/L
4.00
4.17
104 80-120
Matrix Spike & Matrix Spike Duplicate
L 88989-MS-L749975
L 88989-MSD-L749975
MS Spike
MSD MS Result
MSD MS MSD %Rec Max
Parameter Units
Result Conc.
Spike
Result %Rec %Rec Limits RPD RPD
Conc.
Mercury (Total) pg/L
<0.100 4.00
4.00 3.97
4.01 99.0 100 80-120 1.0 20
Post Digestion Spike
L 88989-PDS-L749975
PDS
%
Analyzed
Parameter Units
Result
Recovery
Mercury (Total) pg/L
5.10
102
05/13/24 15:12
Date: 05/31/2024 01:51 PM Page 14 of 46
Page 165 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
Client ID:
Project Description:
Report No:
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Smith & Gardner, Inc.
Surry County C&D/MSW Spring
24-124-0102
QC Prep: V46914
QC Prep Batch Method: 3510C
QC Analytical Batch(es): V47319
Analysis Method: 8081B
Analysis Description: Organochlorine Pesticides by GC
Lab Reagent Blank LRB-V46914 Matrix: AQU
Associated Lab Samples: 92542, 92544, 92546, 92547, 92548, 92549, 92550
Parameter
Units
Blank
Result
MDL
MQL
Analyzed
% % Rec
Recovery Limits
Aldrin
pg/L
<0.0152
0.0152
0.0500
05/15/24 17:46
alpha-BHC
pg/L
<0.0063
0.0063
0.0500
05/15/24 17:46
beta-BHC
pg/L
<0.0111
0.0111
0.0500
05/15/24 17:46
delta-BHC
pg/L
<0.0082
0.0082
0.0500
05/15/24 17:46
Chlordane
pg/L
<0.180
0.180
0.500
05/15/24 17:46
alpha -Chlordane
pg/L
<0.0186
0.0186
0.100
05/15/24 17:46
gamma -Chlordane
pg/L
<0.0231
0.0231
0.100
05/15/24 17:46
4,4'-DDD
pg/L
<0.0265
0.0265
0.100
05/15/24 17:46
4,4'-DDE
pg/L
<0.0218
0.0218
0.100
05/15/24 17:46
4,4'-DDT
pg/L
<0.0176
0.0176
0.100
05/15/24 17:46
Dieldrin
pg/L
<0.0137
0.0137
0.0500
05/15/24 17:46
EndosulfanI
pg/L
<0.0160
0.0160
0.0500
05/15/24 17:46
Endosulfan II
pg/L
<0.0121
0.0121
0.0500
05/15/24 17:46
Endosulfan Sulfate
pg/L
<0.0165
0.0165
0.0500
05/15/24 17:46
Endrin
pg/L
<0.0136
0.0136
0.0500
05/15/24 17:46
Endrin Aldehyde
pg/L
<0.0158
0.0158
0.0500
05/15/24 17:46
Endrin Ketone
pg/L
<0.0181
0.0181
0.100
05/15/24 17:46
gamma-BHC
pg/L
<0.0061
0.0061
0.0500
05/15/24 17:46
Heptachlor
pg/L
<0.0130
0.0130
0.0500
05/15/24 17:46
Heptachlor Epoxide
pg/L
<0.0224
0.0224
0.100
05/15/24 17:46
Methoxychlor
pg/L
<0.0179
0.0179
0.100
05/15/24 17:46
Toxaphene
pg/L
<0.350
0.350
1.00
05/15/24 17:46
Decachlorobiphenyl (S)
05/15/24 17:46
129 13-186
Tetrachloro-m-xylene (S)
05/15/24 17:46
87.8 40-134
Date: 05/31/2024 01:51 PM Page 15 of 46
Page 166 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Prep: V46914
QC Prep Batch Method: 3510C
Laboratory Control Sample LCS-V46914
QC Analytical Batch(es): V47319
Analysis Method: 8081B
Analysis Description: Organochlorine Pesticides by GC
Spike
LCS
LCS %Rec % Rec
Parameter Units
Conc.
Result
Limits
Chlordane pg/L
10.0
8.17
81.7 62-140
Toxaphene pg/L
10.0
8.26
82.6 33-134
Laboratory Control Sample & LCSD
Parameter Units
LCS-V46914
Spike
Conc.
LCSD-V46914
LCS
Result
LCSD
Result
LCS
%Rec
LCSD
a/o Rec
% Rec
Limits
RPD
Max
RPD
Aldrin
pg/L
1.00
0.604
0.669
60.4
66.9
45-134
10.2
30.0
alpha-BHC
pg/L
1.00
0.732
0.828
73.2
82.8
54-138
12.3
30.0
beta-BHC
pg/L
1.00
0.693
0.771
69.3
77.1
56-136
10.6
30.0
delta-BHC
pg/L
1.00
0.641
0.711
64.1
71.1
52-142
10.3
30.0
alpha -Chlordane
pg/L
1.00
0.713
0.775
71.3
77.5
60-129
8.3
30.0
gamma -Chlordane
pg/L
1.00
0.715
0.768
71.5
76.8
56-136
7.1
30.0
4,4'-DDD
pg/L
1.00
0.814
0.893
81.4
89.3
56-143
9.2
30.0
4,4'-DDE
pg/L
1.00
0.758
0.827
75.8
82.7
57-135
8.7
30.0
4,4'-DDT
pg/L
1.00
0.792
0.863
79.2
86.3
51-143
8.5
30.0
Dieldrin
pg/L
1.00
0.774
0.851
77.4
85.1
60-136
9.4
30.0
Endosulfan I
pg/L
1.00
0.738
0.814
73.8
81.4
62-126
9.7
30.0
Endosulfan II
pg/L
1.00
0.774
0.845
77.4
84.5
52-135
8.7
30.0
Endosulfan Sulfate
pg/L
1.00
0.756
0.826
75.6
82.6
62-133
8.8
30.0
Endrin
pg/L
1.00
0.846
0.930
84.6
93.0
60-138
9.4
30.0
Endrin Aldehyde
pg/L
1.00
0.807
0.880
80.7
88.0
51-132
8.6
30.0
Endrin Ketone
pg/L
1.00
0.758
0.830
75.8
83.0
58-134
9.0
30.0
gamma-BHC
pg/L
1.00
0.717
0.807
71.7
80.7
59-134
11.8
30.0
Heptachlor
pg/L
1.00
0.631
0.687
63.1
68.7
54-130
8.4
30.0
Heptachlor Epoxide
pg/L
1.00
0.767
0.847
76.7
84.7
61-133
9.9
30.0
Methoxychlor
pg/L
1.00
0.749
0.819
74.9
81.9
54-145
8.9
30.0
Date: 05/31/2024 01:51 PM Page 16 of 46
Page 167 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Prep: V46914
QC Analytical Batch(es): V47319
QC Prep Batch Method: 3510C
Analysis Method:
8081B
Analysis Description:
Organochlorine Pesticides by GC
Laboratory Control Sample & LCSD
LCS-V46914 LCSD-V46914
Spike LCS LCSD
LCS
LCSD
% Rec
Parameter Units
Conc. Result Result
%Rec
% Rec
Limits RPD
Decachlorobiphenyl (S)
107
115
13-186
Tetrachloro-m-xylene (S)
89.7
100
40-134
Date: 05/31/2024 01:51 PM Page 17 of 46
Page 168 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
• i
Way po�nt ^ 449 Spring#�rQok Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
Quality Control Data
Client ID:
Smith & Gardner, Inc.
Project Description:
Surry County C&D/MSW Spring
Report No:
24-124-0102
QC Prep:
V46915
QC Analytical Batch(es): V47358
QC Prep Batch Method:
3510C
Analysis Method:
8082A
Analysis Description:
Polychlorinated Biphenyls
(PCB's)
Lab Reagent Blank
LRB-V46915
Matrix: AQU
Associated Lab Samples:
92542, 92544, 92546, 92547, 92548, 92549,
92550
Blank MDL
MQL
Analyzed
%
% Rec
Parameter
Units
Result
Recovery
Limits
Aroclor 1016
pg/L
<0.210 0.210
0.500
05/16/24 15:07
Aroclor 1221
pg/L
<0.110 0.110
1.00
05/16/24 15:07
Aroclor 1232
pg/L
<0.160 0.160
0.500
05/16/24 15:07
Aroclor 1242
pg/L
<0.140 0.140
0.500
05/16/24 15:07
Aroclor 1248
pg/L
<0.140 0.140
0.500
05/16/24 15:07
Aroclor 1254
pg/L
<0.160 0.160
0.500
05/16/24 15:07
Aroclor 1260
pg/L
<0.495 0.495
1.00
05/16/24 15:07
Decachlorobiphenyl (S)
05/16/24 15:07
103
32-178
Tetrachloro-m-xylene (S)
05/16/24 15:07
62.4
30-161
Laboratory Control Sample & LCSD
LCS-V46915 LCSD-V46915
Spike
LCS LCSD
LCS LCSD
% Rec
Parameter
Units
Conc.
Result Result
%Rec a/o Rec
Limits
RPD Max
RPD
Aroclor 1016
pg/L
10.0
8.78 8.16
87.8 81.6
50-114
7.3 50.0
Aroclor 1260
pg/L
10.0
7.35 7.07
73.5 70.7
20-127
3.8 50.0
Decachlorobiphenyl(S)
79.2 64.4
32-178
Tetrachloro-m-xylene (S)
73.6 62.0
30-161
Date: 05/31/2024 01:51 PM Page 18 of 46
Page 169 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Prep: L749368 QC Analytical Batch(es): L750463
QC Prep Batch Method: 8151A Analysis Method: 8151A
Analysis Description: Phenoxy Acid Herbicides - GC/ECD
Lab Reagent Blank LRB-L749368 Matrix: AQU
Associated Lab Samples: 92542
Parameter
Units
Blank
Result
MDL
MQL
Analyzed % % Rec
Recovery Limits
2,4-D
pg/L
<0.2078
0.2078
0.2500
05/15/24 01:22
Dalapon
pg/L
<0.5149
0.5149
0.5500
05/15/24 01:22
2,4-DB
pg/L
<0.1364
0.1364
0.2500
05/15/24 01:22
Dicamba
pg/L
<0.05700
0.05700
0.1000
05/15/24 01:22
Dichlorprop
pg/L
<0.07959
0.07959
0.1000
05/15/24 01:22
Dinoseb
pg/L
<0.02698
0.02698
0.1000
05/15/24 01:22
MCPA
pg/L
<18.98
18.98
50.00
05/15/24 01:22
MCPP
pg/L
<11.75
11.75
50.00
05/15/24 01:22
Picloram
pg/L
<0.04528
0.04528
0.1000
05/15/24 01:22
2,4,5-T
pg/L
<0.1002
0.1002
0.1250
05/15/24 01:22
2,4,5-TP(Silvex)
pg/L
<0.01634
0.01634
0.1000
05/15/24 01:22
DCAA (S)
05/15/24 01:22 I 20-150
Laboratory Control Sample & LCSD LCS-L749368 LCSD-L749368
Parameter
Units
Spike
Conc.
LCS
Result
LCSD
Result
LCS
%Rec
LCSD
a/o Rec
% Rec
Limits
RPD
Max
RPD
2,4-D
pg/L
5.000
2.465
1.966
49.3
39.3
20-120
22.5*
20.00
Dalapon
pg/L
12.50
3.021
5.174
24.1
41.3
20-120
52.5*
20.00
2,4-DB
pg/L
5.000
2.481
1.966
49.6
39.3
20-120
23.1*
20.00
Dicamba
pg/L
0.5000
0.2302
0.1844
46.0
36.8
20-120
22.0*
20.00
Dichlorprop
pg/L
5.000
2.820
2.242
56.4
44.8
20-120
22.8*
20.00
Dinoseb
pg/L
2.500
1.270
1.037
50.8
41.4
20-120
20.1*
20.00
MCPA
pg/L
500.0
274.9
219.1
54.9
43.8
20-120
22.5*
20.00
MCPP
pg/L
500.0
249.1
196.8
49.8
39.3
20-120
23.4*
20.00
Picloram
pg/L
1.250
0.5257
0.4546
42.0
36.3
20-120
14.5
20.00
2,4,5-T
pg/L
0.5000
0.2384
0.1994
47.6
39.8
20-120
17.8
20.00
* QC Fail Date: 05/31/2024 01:51 PM Page 19 of 46
Page 170 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
• i
Way po�nt ^ 449 Spring#�rQok Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
Quality Control Data
Client ID:
Smith & Gardner, Inc.
Project Description:
Surry County C&D/MSW Spring
Report No:
24-124-0102
QC Prep:
L749368
QC Analytical Batch(es): L750463
QC Prep Batch Method:
8151A
Analysis Method:
8151A
Analysis Description:
Phenoxy Acid Herbicides - GC/ECD
Laboratory Control Sample
& LCSD LCS-L749368
LCSD-L749368
Spike
LCS LCSD
LCS LCSD
% Rec
Parameter
Units Conc.
Result Result
%Rec % Rec
Limits RPD Max
RPD
2,4,5-TP (Silvex)
ug/L 0.5000
0.2833 0.2331
56.6 46.6
20-120 19.4 20.00
DCAA (S)
57.2 46.2
20-150
Date: 05/31/2024 01:51 PM Page 20 of 46
Page 171 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
• i
Way po�nt ^ 449 Spring#�rQok Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
Quality Control Data
Client ID:
Smith & Gardner, Inc.
Project Description:
Surry County C&D/MSW Spring
Report No:
24-124-0102
QC Prep:
L749619
QC Analytical Batch(es): L750458
QC Prep Batch Method:
8151A
Analysis Method:
8151A
Analysis Description:
Phenoxy Acid Herbicides - GC/ECD
Lab Reagent Blank
LRB-L749619
Matrix: AQU
Associated Lab Samples:
92544, 92546, 92547, 92548,
92549, 92550
Blank
MDL
MQL
Analyzed % % Rec
Parameter
Units
Result
Recovery Limits
2,4-D
pg/L
<0.2078
0.2078
0.2500
05/14/24 20:48
Dalapon
pg/L
<0.5149
0.5149
0.5500
05/14/24 20:48
2,4-DB
pg/L
<0.1364
0.1364
0.2500
05/14/24 20:48
Dicamba
pg/L
<0.05700
0.05700
0.1000
05/14/24 20:48
Dichlorprop
pg/L
<0.07959
0.07959
0.1000
05/14/24 20:48
Dinoseb
pg/L
<0.02698
0.02698
0.1000
05/14/24 20:48
MCPA
pg/L
<18.98
18.98
50.00
05/14/24 20:48
MCPP
pg/L
<11.75
11.75
50.00
05/14/24 20:48
Picloram
pg/L
<0.04528
0.04528
0.1000
05/14/24 20:48
2,4,5-T
pg/L
<0.1002
0.1002
0.1250
05/14/24 20:48
2,4,5-TP(Silvex)
pg/L
<0.01634
0.01634
0.1000
05/14/24 20:48
DCAA (S)
05/14/24 20:48 72.9 20-150
Laboratory Control Sample & LCSD LCS-L749619 LCSD-L749619
Parameter
Units
Spike
Conc.
LCS
Result
LCSD
Result
LCS
%Rec
LCSD
a/o Rec
% Rec
Limits
RPD
Max
RPD
2,4-D
pg/L
5.000
3.212
2.554
64.2
51.0
20-120
22.8*
20.00
Dalapon
pg/L
12.50
7.782
5.646
62.2
45.1
20-120
31.8*
20.00
2,4-DB
pg/L
5.000
3.201
2.538
64.0
50.7
20-120
23.1*
20.00
Dicamba
pg/L
0.5000
0.2901
0.2339
58.0
46.7
20-120
21.4*
20.00
Dichlorprop
pg/L
5.000
3.573
2.843
71.4
56.8
20-120
22.7*
20.00
Dinoseb
pg/L
2.500
1.547
1.272
61.8
50.8
20-120
19.5
20.00
MCPA
pg/L
500.0
343.3
275.9
68.6
55.1
20-120
21.7*
20.00
MCPP
pg/L
500.0
307.2
255.7
61.4
51.1
20-120
18.2
20.00
Picloram
pg/L
1.250
0.7248
0.5588
57.9
44.7
20-120
25.8*
20.00
2,4,5-T
pg/L
0.5000
0.3025
0.2333
60.5
46.6
20-120
25.8*
20.00
* QC Fail Date: 05/31/2024 01:51 PM Page 21 of 46
Page 172 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
• i
Way po�nt ^ 449 Spring#�rQok Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
Quality Control Data
Client ID:
Smith & Gardner, Inc.
Project Description:
Surry County C&D/MSW Spring
Report No:
24-124-0102
QC Prep:
L749619
QC Analytical Batch(es): L750458
QC Prep Batch Method:
8151A
Analysis Method:
8151A
Analysis Description:
Phenoxy Acid Herbicides - GC/ECD
Laboratory Control Sample
& LCSD LCS-L749619
LCSD-L749619
Spike
LCS LCSD
LCS LCSD
% Rec
Parameter
Units Conc.
Result Result
%Rec % Rec
Limits
RPD Max
RPD
2,4,5-TP (Silvex)
ug/L 0.5000
0.3565 0.2824
71.3 56.4
20-120
23.1* 20.00
DCAA (S)
72.0 54.8
20-150
* QC Fail
Date:
05/31/2024 01:51 PM
Page 22 of 46
Page 173 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Prep: V46881 QC Analytical Batch(es): V46882
QC Prep Batch Method: 5030B Analysis Method: 8260D SIM
Analysis Description: Volatile Organic Compounds - GC/MS
Lab Reagent Blank LRB-V46881 Matrix: AQU
Associated Lab Samples: 92542, 92543, 92544, 92545, 92546
Blank MDL MQL Analyzed % % Rec
Parameter Units Result Recovery Limits
1,4-Dioxane pg/L <0.139 0.139 2.00 05/06/2413:07
4-Bromofluorobenzene (S) 05/06/24 13:07 127 70-130
Laboratory Control Sample LCS-V46881
Spike LCS LCS %Rec % Rec
Parameter Units Conc. Result Limits
1,4-Dioxane pg/L
50.0 41.2
82.4
70-130
4-Bromofluorobenzene (S)
81.4
70-130
Matrix Spike & Matrix Spike Duplicate
V 92546-MS-V46881 V 92546-MSD-V46881
MS Spike MSD MS Result
MSD
MS MSD %Rec Max
Parameter Units
Result Conc. Spike
Result
%Rec %Rec Limits RPD RPD
Conc.
1,4-Dioxane pg/L < 0.139 50.0 50.0 52.4 52.5 105 105 70-130 0.1 20.0
4-Bromofluorobenzene (S) 91.4 92.6 70-130
Date: 05/31/2024 01:51 PM Page 23 of 46
Page 174 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Prep: V46940 QC Analytical Batch(es): V46941
QC Prep Batch Method: 5030B Analysis Method: 8260D SIM
Analysis Description: Volatile Organic Compounds - GC/MS
Lab Reagent Blank LRB-V46940 Matrix: AQU
Associated Lab Samples: 92547, 92548, 92549, 92550, 92551
Blank MDL MQL Analyzed % % Rec
Parameter Units Result Recovery Limits
1,4-Dioxane pg/L <0.139 0.139 2.00 05/07/24 09:28
4-Bromofluorobenzene (S) 05/07/24 09:28 108 70-130
Laboratory Control Sample LCS-V46940
Spike LCS LCS %Rec % Rec
Parameter Units Conc. Result Limits
1,4-Dioxane pg/L
50.0 46.7
93.4
70-130
4-Bromofluorobenzene (S)
86.8
70-130
Matrix Spike & Matrix Spike Duplicate
V 92551-MS-V46940 V 92551-MSD-V46940
MS Spike MSD MS Result
MSD
MS MSD %Rec Max
Parameter Units
Result Conc. Spike
Result
%Rec %Rec Limits RPD RPD
Conc.
1,4-Dioxane pg/L 5.67 50.0 50.0 48.7 51.5 86.0 91.6 70-130 5.5 20.0
4-Bromofluorobenzene (S) 107 86.0 70-130
Date: 05/31/2024 01:51 PM Page 24 of 46
Page 175 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
Client ID:
Project Description:
Report No:
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Smith & Gardner, Inc.
Surry County C&D/MSW Spring
24-124-0102
QC Prep: V47200
QC Prep Batch Method: 5030B
QC Analytical Batch(es): V47202
Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Lab Reagent Blank LRB-V47200 Matrix: AQU
Associated Lab Samples: 92542, 92543, 92544, 92545, 92546, 92547, 92548, 92549, 92550, 92551, 92552
Blank MDL MQL Analyzed
Parameter Units Result
Acetone
pg/L
<1.80
1.80
5.00
05/10/24 05:33
Acrolein
pg/L
<2.00
2.00
5.00
05/10/24 05:33
Acrylonitrile
pg/L
<0.230
0.230
5.00
05/10/24 05:33
Benzene
pg/L
<0.180
0.180
0.500
05/10/24 05:33
Bromochloromethane
pg/L
<0.420
0.420
1.00
05/10/24 05:33
Bromodichloromethane
pg/L
<0.160
0.160
0.500
05/10/24 05:33
Bromoform
pg/L
<1.50
1.50
5.00
05/10/24 05:33
Bromomethane
pg/L
<0.280
0.280
1.00
05/10/24 05:33
Carbon Disulfide
pg/L
<0.150
0.150
5.00
05/10/24 05:33
Carbon Tetrachloride
pg/L
<0.180
0.180
0.500
05/10/24 05:33
Chlorobenzene
pg/L
<0.190
0.190
0.500
05/10/24 05:33
Chlorodibromomethane
pg/L
<0.190
0.190
0.500
05/10/24 05:33
Chloroethane
pg/L
<0.430
0.430
1.00
05/10/24 05:33
Chloroform
pg/L
<0.220
0.220
0.500
05/10/24 05:33
Chloromethane
pg/L
<0.220
0.220
0.500
05/10/24 05:33
Di -Isopropyl Ether (DIPE)
pg/L
<0.960
0.960
5.00
05/10/24 05:33
1,2-Dibromo-3-Chloropropane
pg/L
<1.10
1.10
2.00
05/10/24 05:33
1,2-Dibromoethane
pg/L
<0.200
0.200
0.500
05/10/24 05:33
Dibromomethane
pg/L
<0.230
0.230
0.500
05/10/24 05:33
trans-1,4-Dichloro-2-butene
pg/L
< 1.30
1.30
10.0
05/10/24 05:33
1,2-Dichlorobenzene
pg/L
<0.220
0.220
0.500
05/10/24 05:33
1,3-Dichlorobenzene
pg/L
<0.190
0.190
0.500
05/10/24 05:33
1,4-Dichlorobenzene
pg/L
<0.210
0.210
0.500
05/10/24 05:33
Dichlorodifluoromethane
pg/L
<1.20
1.20
5.00
05/10/24 05:33
1,1-Dichloroethane
pg/L
<0.240
0.240
0.500
05/10/24 05:33
1,2-Dichloroethane
pg/L
<0.150
0.150
0.500
05/10/24 05:33
1,1-Dichloroethene
pg/L
<0.150
0.150
0.500
05/10/24 05:33
% % Rec
Recovery Limits
Date: 05/31/2024 01:51 PM
Page 176 of 200
Page 25 of 46
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
Client ID:
Project Description:
Report No:
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Smith & Gardner, Inc.
Surry County C&D/MSW Spring
24-124-0102
QC Prep: V47200
QC Prep Batch Method: 5030B
QC Analytical Batch(es): V47202
Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Lab Reagent Blank LRB-V47200 Matrix: AQU
Associated Lab Samples: 92542, 92543, 92544, 92545, 92546, 92547, 92548, 92549, 92550, 92551, 92552
Blank MDL MQL Analyzed
Parameter Units Result
cis-1,2-Dichloroethene
pg/L
<0.200
0.200
0.500
05/10/24 05:33
trans-1,2-Dichloroethene
pg/L
<0.180
0.180
0.500
05/10/24 05:33
1,2-Dichloropropane
pg/L
<0.190
0.190
0.500
05/10/24 05:33
1,3-Dichloropropane
pg/L
<0.130
0.130
0.500
05/10/24 05:33
2,2-Dichloropropane
pg/L
<0.210
0.210
2.00
05/10/24 05:33
1,1-Dichloropropene
pg/L
<0.200
0.200
0.500
05/10/24 05:33
cis-1,3-Dichloropropene
pg/L
<0.210
0.210
0.500
05/10/24 05:33
trans-1,3-Dichloropropene
pg/L
<0.150
0.150
0.500
05/10/24 05:33
1,4-Dioxane
pg/L
<16.0
16.0
150
05/10/24 05:33
Ethylbenzene
pg/L
<0.170
0.170
0.500
05/10/24 05:33
Hexachlorobutadiene
pg/L
<0.350
0.350
2.00
05/10/24 05:33
2-Hexanone
pg/L
<0.380
0.380
5.00
05/10/24 05:33
Iodomethane
pg/L
<0.054
0.054
0.500
05/10/24 05:33
Methyl Ethyl Ketone (MEK)
pg/L
<0.710
0.710
5.00
05/10/24 05:33
4-Methyl-2-Pentanone
pg/L
<1.00
1.00
5.00
05/10/24 05:33
Methylene Chloride
pg/L
<0.330
0.330
1.00
05/10/24 05:33
Naphthalene
pg/L
<0.470
0.470
1.00
05/10/24 05:33
Styrene
pg/L
<0.220
0.220
0.500
05/10/24 05:33
1,1,1,2-Tetrachloroethane
pg/L
<0.160
0.160
0.500
05/10/24 05:33
1,1,2,2-Tetrachloroethane
pg/L
<0.160
0.160
0.500
05/10/24 05:33
Tetrachloroethene
pg/L
<0.220
0.220
0.500
05/10/24 05:33
Tetrahydrofuran
pg/L
<1.50
1.50
10.0
05/10/24 05:33
Toluene
pg/L
<0.220
0.220
0.500
05/10/24 05:33
1,2,4-Trichlorobenzene
pg/L
<0.310
0.310
1.00
05/10/24 05:33
1,1,1-Trichloroethane
pg/L
<0.160
0.160
0.500
05/10/24 05:33
1,1,2-Trichloroethane
pg/L
<0.096
0.096
0.500
05/10/24 05:33
Trichloroethene
pg/L
<0.180
0.180
0.500
05/10/24 05:33
% % Rec
Recovery Limits
Date: 05/31/2024 01:51 PM
Page 177 of 200
Page 26 of 46
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
• i
Way po�nt ^ 449 Spring#�rQok Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
Quality Control Data
Client ID:
Smith & Gardner, Inc.
Project Description:
Surry County C&D/MSW Spring
Report No:
24-124-0102
QC Prep:
V47200
QC Analytical Batch(es): V47202
QC Prep Batch Method:
5030B
Analysis Method:
8260D
Analysis Description:
Volatile Organic
Compounds - GC/MS
Lab Reagent Blank
LRB-V47200
Matrix: AQU
Associated Lab Samples:
92542, 92543, 92544, 92545, 92546, 92547, 92548, 92549, 92550,
92551, 92552
Blank MDL
MQL
Analyzed
%
% Rec
Parameter
Units
Result
Recovery
Limits
Trichlorofluoromethane
pg/L
<0.180 0.180
0.500
05/10/24 05:33
1,2,3-Trichloropropane
pg/L
<0.270 0.270
1.00
05/10/24 05:33
Vinyl Acetate
pg/L
<1.00 1.00
2.00
05/10/24 05:33
Vinyl Chloride
pg/L
<0.170 0.170
0.500
05/10/24 05:33
o-Xylene
pg/L
<0.210 0.210
0.500
05/10/24 05:33
m,p-Xylene
pg/L
<0.420 0.420
1.00
05/10/24 05:33
4-Bromofluorobenzene (S)
05/10/24 05:33
101
80-124
Dibromofluoromethane (S)
05/10/24 05:33
102
75-129
1,2-Dichloroethane - d4 (S)
05/10/24 05:33
99.0
63-136
Toluene-d8 (S)
05/10/24 05:33
99.8
77-123
Laboratory Control Sample & LCSD
Parameter Units
LCS-V47200
Spike
Conc.
LCSD-V47200
LCS
Result
LCSD
Result
LCS
%Rec
LCSD
% Rec
% Rec
Limits
RPD
Max
RPD
Acetone
pg/L
40.0
52.2
55.8
131
140
40-166
6.6
20.0
Acrolein
pg/L
40.0
38.4
37.6
96.0
94.0
70-130
2.1
20.0
Acrylonitrile
pg/L
40.0
42.1
42.2
105
106
81-127
0.2
20.0
Benzene
pg/L
20.0
21.1
20.7
106
104
77-128
1.9
20.0
Bromochloromethane
pg/L
20.0
21.3
20.8
107
104
78-135
2.3
20.0
Bromodichloromethane
pg/L
20.0
20.3
20.7
102
104
76-138
1.9
20.0
Bromoform
pg/L
20.0
18.3
18.9
91.5
94.5
71-135
3.2
20.0
Bromomethane
pg/L
20.0
22.1
21.0
111
105
41-168
5.1
20.0
Carbon Disulfide
pg/L
20.0
21.2
20.8
106
104
59-135
1.9
20.0
Carbon Tetrachloride
pg/L
20.0
21.1
20.8
106
104
72-142
1.4
20.0
Chlorobenzene
pg/L
20.0
20.4
19.9
102
99.5
78-119
2.4
20.0
Chlorodibromomethane
pg/L
20.0
20.5
20.5
103
103
75-134
0.0
20.0
Date: 05/31/2024 01:51 PM Page 27 of 46
Page 178 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Prep: V47200 QC Analytical Batch(es): V47202
QC Prep Batch Method: 5030B Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Laboratory Control Sample & LCSD LCS-V47200 LCSD-V47200
Parameter
Units
Spike
Conc.
LCS
Result
LCSD
Result
LCS
%Rec
LCSD
% Rec
% Rec
Limits
RPD
Max
RPD
Chloroethane
pg/L
20.0
26.9
24.6
135
123
57-142
8.9
20.0
Chloroform
pg/L
20.0
21.1
20.6
106
103
77-130
2.3
20.0
Chloromethane
pg/L
20.0
23.6
22.6
118
113
47-145
4.3
20.0
Di -Isopropyl Ether (DIPE)
pg/L
20.0
22.1
21.9
111
110
60-154
0.9
20.0
1,2-Dibromo-3-Chloropropane
pg/L
20.0
21.5
21.8
108
109
63-134
1.3
20.0
1,2-Dibromoethane
pg/L
20.0
20.4
20.5
102
103
77-135
0.4
20.0
Dibromomethane
pg/L
20.0
20.5
20.8
103
104
76-138
1.4
20.0
trans-1,4-Dichloro-2-butene
pg/L
20.0
17.5
17.8
87.5
89.0
70-130
1.6
20.0
1,2-Dichlorobenzene
pg/L
20.0
20.4
20.7
102
104
78-128
1.4
20.0
1,3-Dichlorobenzene
pg/L
20.0
20.5
20.5
103
103
77-125
0.0
20.0
1,4-Dichlorobenzene
pg/L
20.0
20.5
20.3
103
102
75-126
0.9
20.0
Dichlorodifluoromethane
pg/L
20.0
28.6
26.7
143
134
28-163
6.8
20.0
1,1-Dichloroethane
pg/L
20.0
21.4
21.1
107
106
70-130
1.4
20.0
1,2-Dichloroethane
pg/L
20.0
20.2
19.9
101
99.5
68-131
1.4
20.0
1,1-Dichloroethene
pg/L
20.0
21.5
20.5
108
103
70-154
4.7
20.0
cis-1,2-Dichloroethene
pg/L
20.0
20.8
20.5
104
103
76-141
1.4
20.0
trans-1,2-Dichloroethene
pg/L
20.0
20.8
21.1
104
106
76-135
1.4
20.0
1,2-Dichloropropane
pg/L
20.0
21.0
21.1
105
106
77-130
0.4
20.0
1,3-Dichloropropane
pg/L
20.0
20.0
20.0
100
100
76-132
0.0
20.0
2,2-Dichloropropane
pg/L
20.0
17.4
17.1
87.0
85.5
29-149
1.7
20.0
1,1-Dichloropropene
pg/L
20.0
20.5
20.6
103
103
71-136
0.4
20.0
cis-1,3-Dichloropropene
pg/L
20.0
19.7
19.5
98.5
97.5
65-140
1.0
20.0
trans-1,3-Dichloropropene
pg/L
20.0
19.9
19.7
99.5
98.5
67-140
1.0
20.0
1,4-Dioxane
pg/L
200
210
214
105
107
70-130
1.8
20.0
Ethylbenzene
pg/L
20.0
19.6
19.1
98.0
95.5
80-127
2.5
20.0
Hexachlorobutadiene
pg/L
20.0
20.6
20.9
103
105
61-134
1.4
20.0
Date: 05/31/2024 01:51 PM Page 28 of 46
Page 179 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Prep: V47200 QC Analytical Batch(es): V47202
QC Prep Batch Method: 5030B Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Laboratory Control Sample & LCSD LCS-V47200 LCSD-V47200
Parameter
Units
Spike
Conc.
LCS
Result
LCSD
Result
LCS
%Rec
LCSD
% Rec
% Rec
Limits
RPD
Max
RPD
2-Hexanone
pg/L
20.0
21.0
22.3
105
112
64-137
6.0
20.0
Iodomethane
pg/L
20.0
18.2
16.7
91.0
83.5
70-130
8.5
20.0
Methyl Ethyl Ketone (MEK)
pg/L
20.0
23.3
25.4
117
127
71-134
8.6
20.0
4-Methyl-2-Pentanone
pg/L
20.0
20.5
19.5
103
97.5
69-134
5.0
20.0
Methylene Chloride
pg/L
20.0
20.8
20.2
104
101
73-131
2.9
20.0
Naphthalene
pg/L
20.0
19.5
19.3
97.5
96.5
64-136
1.0
20.0
Styrene
pg/L
20.0
20.1
19.8
101
99.0
78-129
1.5
20.0
1,1,1,2-Tetrachloroethane
pg/L
20.0
20.3
20.0
102
100
79-134
1.4
20.0
1,1,2,2-Tetrachloroethane
pg/L
20.0
19.3
19.3
96.5
96.5
62-127
0.0
20.0
Tetrachloroethene
pg/L
20.0
19.4
19.8
97.0
99.0
80-129
2.0
20.0
Tetrahydrofuran
pg/L
20.0
21.7
21.5
109
108
70-130
0.9
20.0
Toluene
pg/L
20.0
20.6
20.3
103
102
76-131
1.4
20.0
1,2,4-Trichlorobenzene
pg/L
20.0
20.6
20.5
103
103
66-139
0.4
20.0
1,1,1-Trichloroethane
pg/L
20.0
19.9
20.2
99.5
101
75-135
1.4
20.0
1,1,2-Trichloroethane
pg/L
20.0
19.8
20.2
99.0
101
70-140
2.0
20.0
Trichloroethene
pg/L
20.0
21.9
21.7
110
109
77-133
0.9
20.0
Trichlorofluoromethane
pg/L
20.0
22.9
20.1
115
101
62-148
13.0
20.0
1,2,3-Trichloropropane
pg/L
20.0
20.8
20.7
104
104
71-127
0.4
20.0
Vinyl Acetate
pg/L
20.0
17.1
13.2
85.5
66.0
34-167
25.7*
20.0
Vinyl Chloride
pg/L
20.0
23.8
22.3
119
112
57-141
6.5
20.0
o-Xylene
pg/L
20.0
20.4
20.1
102
101
78-128
1.4
20.0
m,p-Xylene
pg/L
40.0
41.8
41.2
105
103
77-133
1.4
20.0
4-Bromofluorobenzene (S)
99.8
99.4
80-124
Dibromofluoromethane (S)
99.2
100
75-129
1,2-Dichloroethane - d4 (S)
98.4
97.2
63-136
* QC Fail Date: 05/31/2024 01:51 PM Page 29 of 46
Page 180 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Prep: V47200 QC Analytical Batch(es): V47202
QC Prep Batch Method: 5030B Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Laboratory Control Sample & LCSD LCS-V47200 LCSD-V47200
Spike LCS LCSD LCS LCSD % Rec
Parameter Units Conc. Result Result %Rec % Rec Limits RPD
Toluene-d8(S) 100 100 77-123
Date: 05/31/2024 01:51 PM Page 30 of 46
Page 181 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Prep:
V47336
QC Analytical Batch(es): V47337
QC Prep Batch Method:
5030B
Analysis Method:
8260D
Analysis Description:
Volatile Organic Compounds - GC/MS
Lab Reagent Blank
LRB-V47336
Matrix: AQU
Associated Lab Samples:
92542, 92544, 92546, 92547,
92548, 92549, 92550, 92552
Blank
MDL
MQL
Analyzed % % Rec
Parameter
Units
Result
Recovery Limits
Acetonitrile
pg/L
<10.0
10.0
10.0
05/15/24 08:57
Allyl Chloride
pg/L
<0.579
0.579
10.0
05/15/24 08:57
Chloroprene
pg/L
<0.450
0.450
10.0
05/15/24 08:57
Ethyl Methacrylate
pg/L
<1.62
1.62
10.0
05/15/24 08:57
Methacrylonitrile
pg/L
<10.0
10.0
10.0
05/15/24 08:57
Propionitrile
pg/L
<10.0
10.0
10.0
05/15/24 08:57
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
1,2-Dichloroethane - d4 (S)
Toluene-d8(S)
05/15/24 08:57
05/15/24 08:57
05/15/24 08:57
05/15/24 08:57
100
103
105
106
80-124
75-129
63-136
77-123
Laboratory Control Sample & LCSD
LCS-V47336
LCSD-V47336
Spike
LCS
LCSD
LCS LCSD
% Rec
Parameter Units
Conc.
Result
Result
%Rec % Rec
Limits
RPD
Max
RPD
Acetonitrile
pg/L
20.0
28.4
22.3
142 112
40-160
24.0*
20.0
Allyl Chloride
pg/L
20.0
21.6
17.8
108 89.0
40-160
19.2
20.0
Chloroprene
pg/L
20.0
23.6
20.2
118 101
40-160
15.5
20.0
Ethyl Methacrylate
pg/L
20.0
22.8
19.9
114 99.5
40-160
13.5
20.0
Methacrylonitrile
pg/L
20.0
24.9
21.1
125 106
40-160
16.5
20.0
Propionitrile
pg/L
20.0
28.3
23.3
142 117
40-160
19.3
20.0
4-Bromofluorobenzene (S)
98.2 98.6
80-124
Dibromofluoromethane (S)
102 102
75-129
1,2-Dichloroethane - d4 (S)
104 104
63-136
Toluene-d8(S)
107 107
77-123
* QC Fail Date: 05/31/2024 01:51 PM Page 31 of 46
Page 182 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
• i
Way po�nt ^ 449 Spring#�rQok Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
Quality Control Data
Client ID:
Smith & Gardner, Inc.
Project Description:
Surry County C&D/MSW Spring
Report No:
24-124-0102
QC Prep:
L749277
QC Analytical Batch(es): L749502
QC Prep Batch Method:
3510C
Analysis Method:
8270C
Analysis Description:
Organophosphorus Pesticides by GC/MS
Lab Reagent Blank
LRB-L749277
Matrix: AQU
Associated Lab Samples:
92542, 92544, 92546, 92547, 92548, 92549,
92550
Blank MDL
MQL
Analyzed
%
% Rec
Parameter
Units
Result
Recovery
Limits
Dimethoate
pg/L
<0.713 0.713
1.00
05/08/24 17:17
Disulfoton
pg/L
<0.466 0.466
1.00
05/08/24 17:17
Ethyl Parathion
pg/L
<0.568 0.568
1.00
05/08/24 17:17
Famphur
pg/L
<0.512 0.512
1.00
05/08/24 17:17
Methyl Parathion
pg/L
<0.805 0.805
1.00
05/08/24 17:17
Phorate
pg/L
<0.659 0.659
1.00
05/08/24 17:17
0,0,0-Triethyl Phosphorothioate
pg/L
<0.330 0.330
1.00
05/08/24 17:17
Tributyl phosphate (S)
05/08/24 17:17
63.5
50-150
Triphenyl phosphate (S)
05/08/24 17:17
81.0
50-150
Laboratory Control Sample & LCSD
LCS-L749277 LCSD-L749277
Spike
LCS
LCSD
LCS LCSD
% Rec
Parameter
Units
Conc.
Result
Result
%Rec % Rec
Limits
RPD
Max
RPD
Dimethoate
pg/L
20.0
12.2
10.4
61.0 52.0
40-140
15.9
20.0
Disulfoton
pg/L
20.0
14.6
13.1
73.0 65.5
40-140
10.8
20.0
Ethyl Parathion
pg/L
20.0
17.1
15.2
85.5 76.0
40-140
11.7
20.0
Famphur
pg/L
20.0
17.5
15.3
87.5 76.5
40-140
13.4
20.0
Methyl Parathion
pg/L
20.0
16.7
14.8
83.5 74.0
40-140
12.0
20.0
Phorate
pg/L
20.0
14.4
12.9
72.0 64.5
40-140
10.9
20.0
0,0,0-Triethyl Phosphorothioate
pg/L
20.0
13.1
12.6
65.5 63.0
40-140
3.8
20.0
Tributyl phosphate (S)
77.0 74.5
50-150
Triphenyl phosphate (S)
98.0 93.0
50-150
Date: 05/31/2024 01:51 PM Page 32 of 46
Page 183 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
Client ID:
Project Description:
Report No:
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Smith & Gardner, Inc.
Surry County C&D/MSW Spring
24-124-0102
QC Prep: L749275
QC Prep Batch Method: 3510C
QC Analytical Batch(es): L749499
Analysis Method: 8270D
Analysis Description: Semivolatile Organic Compounds - GC/MS
Lab Reagent Blank LRB-L749275 Matrix: AQU
Associated Lab Samples: 92542, 92544, 92546, 92547, 92548, 92549, 92550
Blank MDL MQL Analyzed % % Rec
Parameter Units Result Recovery Limits
1,3-Dinitrobenzene
pg/L
<0.904
0.904
10.0
05/08/24 15:59
Acenaphthene
pg/L
<0.563
0.563
2.00
05/08/24 15:59
Acenaphthylene
pg/L
<0.562
0.562
2.00
05/08/24 15:59
Acetophenone
pg/L
<0.689
0.689
5.00
05/08/24 15:59
Anthracene
pg/L
<0.536
0.536
2.00
05/08/24 15:59
Benzo(a)anthracene
pg/L
<0.520
0.520
2.00
05/08/24 15:59
Benzo(a)pyrene
pg/L
<0.511
0.511
2.00
05/08/24 15:59
Benzo(b)fluoranthene
pg/L
<0.631
0.631
2.00
05/08/24 15:59
Benzo(g,h,i)perylene
pg/L
<0.507
0.507
2.00
05/08/24 15:59
Benzo(k)fluoranthene
pg/L
<0.575
0.575
2.00
05/08/24 15:59
Benzyl alcohol
pg/L
<1.02
1.02
10.0
05/08/24 15:59
Bis(2-Chloroethoxy)methane
pg/L
<0.592
0.592
5.00
05/08/24 15:59
Bis(2-Chloroethyl)ether
pg/L
<0.627
0.627
5.00
05/08/24 15:59
Bis(2-Chloroisopropyl)ether
pg/L
<0.656
0.656
5.00
05/08/24 15:59
Bis(2-ethylhexyl)phthalate
pg/L
<0.796
0.796
5.00
05/08/24 15:59
4-Bromophenyl phenyl ether
pg/L
<0.567
0.567
5.00
05/08/24 15:59
Butyl benzyl phthalate
pg/L
<0.756
0.756
5.00
05/08/24 15:59
4-Chloro-3-methylphenol
pg/L
<0.550
0.550
5.00
05/08/24 15:59
4-Chloroaniline
pg/L
<0.530
0.530
5.00
05/08/24 15:59
Chlorobenzilate
pg/L
<0.999
0.999
5.00
05/08/24 15:59
2-Chloronaphthalene
pg/L
<0.560
0.560
5.00
05/08/24 15:59
2-Chlorophenol
pg/L
<0.457
0.457
5.00
05/08/24 15:59
4-Chlorophenyl phenyl ether
pg/L
<0.615
0.615
5.00
05/08/24 15:59
Chrysene
pg/L
<0.550
0.550
2.00
05/08/24 15:59
Dibenz(a,h)anthracene
pg/L
<0.460
0.460
2.00
05/08/24 15:59
Dibenzofuran
pg/L
<0.584
0.584
5.00
05/08/24 15:59
1,2-Dichlorobenzene
pg/L
<0.466
0.466
5.00
05/08/24 15:59
Date:
05/31/2024 01:51 PM
Page 33 of 46
Page 184 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
Client ID:
Project Description:
Report No:
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Smith & Gardner, Inc.
Surry County C&D/MSW Spring
24-124-0102
QC Prep: L749275
QC Prep Batch Method: 3510C
QC Analytical Batch(es): L749499
Analysis Method: 8270D
Analysis Description: Semivolatile Organic Compounds - GC/MS
Lab Reagent Blank LRB-L749275 Matrix: AQU
Associated Lab Samples: 92542, 92544, 92546, 92547, 92548, 92549, 92550
Blank MDL MQL Analyzed % % Rec
Parameter Units Result Recovery Limits
1,3-Dichlorobenzene
pg/L
<0.436
0.436
5.00
05/08/24 15:59
1,4-Dichlorobenzene
pg/L
<0.405
0.405
5.00
05/08/24 15:59
3,3'-Dichlorobenzidine
pg/L
< 10.3
10.3
20.0
05/08/24 15:59
2,4-Dichlorophenol
pg/L
<0.606
0.606
5.00
05/08/24 15:59
2,6-Dichlorophenol
pg/L
<0.655
0.655
5.00
05/08/24 15:59
Diethyl phthalate
pg/L
<0.686
0.686
5.00
05/08/24 15:59
Dimethyl phthalate
pg/L
<0.652
0.652
5.00
05/08/24 15:59
3,3' Dimethylbenzidine
pg/L
<9.01
9.01
10.0
05/08/24 15:59
2,4-Dimethylphenol
pg/L
<0.620
0.620
5.00
05/08/24 15:59
Di-n-butyl phthalate
pg/L
<0.740
0.740
5.00
05/08/24 15:59
4,6- Din itro-2-methylphenol
pg/L
<6.08
6.08
10.0
05/08/24 15:59
2,4-Dinitrophenol
pg/L
<18.9
18.9
20.0
05/08/24 15:59
2,4-Dinitrotoluene
pg/L
<0.911
0.911
5.00
05/08/24 15:59
2,6-Dinitrotoluene
pg/L
<0.734
0.734
5.00
05/08/24 15:59
Di-n-Octyl Phthalate
pg/L
<1.32
1.32
5.00
05/08/24 15:59
Ethyl methanesulfonate
pg/L
<0.660
0.660
5.00
05/08/24 15:59
Fluoranthene
pg/L
<0.583
0.583
2.00
05/08/24 15:59
Fluorene
pg/L
<0.617
0.617
2.00
05/08/24 15:59
Hexachlorobenzene
pg/L
<0.537
0.537
5.00
05/08/24 15:59
Hexachlorobutadiene
pg/L
<0.411
0.411
5.00
05/08/24 15:59
Hexachlorocyclopentadiene
pg/L
<0.889
0.889
5.00
05/08/24 15:59
Hexachloroethane
pg/L
<0.482
0.482
5.00
05/08/24 15:59
Indeno(1,2,3-cd)pyrene
pg/L
<0.490
0.490
2.00
05/08/24 15:59
Isophorone
pg/L
<0.591
0.591
5.00
05/08/24 15:59
Methyl methanesulfonate
pg/L
<0.746
0.746
5.00
05/08/24 15:59
2-Methylnaphthalene
pg/L
<0.569
0.569
2.00
05/08/24 15:59
2-Methylphenol
pg/L
<0.449
0.449
5.00
05/08/24 15:59
Date:
05/31/2024 01:51 PM
Page 34 of 46
Page 185 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
Client ID:
Project Description:
Report No:
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Smith & Gardner, Inc.
Surry County C&D/MSW Spring
24-124-0102
QC Prep: L749275
QC Prep Batch Method: 3510C
QC Analytical Batch(es): L749499
Analysis Method: 8270D
Analysis Description: Semivolatile Organic Compounds - GC/MS
Lab Reagent Blank LRB-L749275 Matrix: AQU
Associated Lab Samples: 92542, 92544, 92546, 92547, 92548, 92549, 92550
Blank
MDL
MQL
Analyzed
% % Rec
Parameter
Units
Result
Recovery Limits
3&4 Methylphenol
pg/L
<0.453
0.453
5.00
05/08/24 15:59
Naphthalene
pg/L
<1.70
1.70
2.00
05/08/24 15:59
2-Nitroaniline
pg/L
<0.766
0.766
5.00
05/08/24 15:59
3-Nitroaniline
pg/L
<0.912
0.912
10.0
05/08/24 15:59
4-Nitroaniline
pg/L
<12.5
12.5
20.0
05/08/24 15:59
Nitrobenzene
pg/L
<0.715
0.715
5.00
05/08/24 15:59
2-Nitrophenol
pg/L
<0.728
0.728
5.00
05/08/24 15:59
4-Nitrophenol
pg/L
<1.94
1.94
10.0
05/08/24 15:59
N-N itrosod imethylamine
pg/L
<0.295
0.295
5.00
05/08/24 15:59
N-N itrosod iphenylamine
pg/L
<0.487
0.487
10.0
05/08/24 15:59
N-N itrosod iethylamine
pg/L
<0.535
0.535
5.00
05/08/24 15:59
N-Nitroso-di-n-butylamine
pg/L
<0.699
0.699
5.00
05/08/24 15:59
N-Nitroso-di-n-propylamine
pg/L
<0.678
0.678
5.00
05/08/24 15:59
Pentachlorobenzene
pg/L
<0.574
0.574
10.0
05/08/24 15:59
Pentachloronitrobenzene
pg/L
<0.569
0.569
5.00
05/08/24 15:59
Pentachlorophenol
pg/L
<1.23
1.23
10.0
05/08/24 15:59
Phenacetin
pg/L
<0.693
0.693
5.00
05/08/24 15:59
Phenanthrene
pg/L
<0.582
0.582
2.00
05/08/24 15:59
Phenol
pg/L
<0.258
0.258
5.00
05/08/24 15:59
Pyrene
pg/L
<0.680
0.680
2.00
05/08/24 15:59
1,2,4,5-Tetrachlorobenzene
pg/L
<0.463
0.463
5.00
05/08/24 15:59
2,3,4,6-Tetrachlorophenol
pg/L
<0.570
0.570
5.00
05/08/24 15:59
1,2,4-Trichlorobenzene
pg/L
<0.433
0.433
5.00
05/08/24 15:59
2,4,5-Trichlorophenol
pg/L
<0.611
0.611
5.00
05/08/24 15:59
2,4,6-Trichlorophenol
pg/L
<0.539
0.539
5.00
05/08/24 15:59
2-Fluorobiphenyl(S)
05/08/24 15:59
69.3 24-93
2-Fluorophenol (S)
05/08/24 15:59
21.2 10-44
Date:
05/31/2024 01:51 PM
Page 35 of 46
Page 186 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
• i
Way po�nt ^ 449 Spring#�rQok Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
Quality Control Data
Client ID:
Smith & Gardner, Inc.
Project Description:
Surry County C&D/MSW Spring
Report No:
24-124-0102
QC Prep:
L749275
QC Analytical Batch(es): L749499
QC Prep Batch Method:
3510C
Analysis Method: 8270D
Analysis Description: Semivolatile Organic Compounds -
GC/MS
Lab Reagent Blank
LRB-L749275
Matrix: AQU
Associated Lab Samples:
92542, 92544, 92546, 92547, 92548, 92549, 92550
Blank MDL
MQL Analyzed
%
% Rec
Parameter
Units Result
Recovery
Limits
Nitrobenzene-d5 (S)
05/08/24 15:59
62.7
20-91
Phenol-d6(S)
05/08/24 15:59
12.8
7-32
4-Terphenyl-d14 (S)
05/08/24 15:59
78.0
35-126
2,4,6-Tribromophenol(S)
05/08/24 15:59
66.8
39-110
Laboratory Control Sample & LCSD LCS-1-749275 LCSD-L749275
Parameter
Units
Spike
Conc.
LCS
Result
LCSD
Result
LCS
%Rec
LCSD
% Rec
% Rec
Limits
RPD
Max
RPD
1,3-Dinitrobenzene
pg/L
50.0
45.5
44.4
91.0
88.8
45-135
2.4
20.0
Acenaphthene
pg/L
50.0
35.6
35.4
71.2
70.8
38-117
0.5
20.0
Acenaphthylene
pg/L
50.0
37.9
37.7
75.8
75.4
37-114
0.5
20.0
Acetophenone
pg/L
50.0
36.6
35.6
73.2
71.2
25-108
2.7
20.0
Anthracene
pg/L
50.0
41.2
40.4
82.4
80.8
34-128
1.9
20.0
Benzo(a)anthracene
pg/L
50.0
41.1
40.4
82.2
80.8
36-127
1.7
20.0
Benzo(a)pyrene
pg/L
50.0
40.1
39.8
80.2
79.6
34-131
0.7
20.0
Benzo(b)fluoranthene
pg/L
50.0
37.9
41.2
75.8
82.4
36-131
8.3
20.0
Benzo(g,h,i)perylene
pg/L
50.0
51.9
47.4
104
94.8
26-123
9.0
20.0
Benzo(k)fluoranthene
pg/L
50.0
41.6
39.7
83.2
79.4
32-132
4.6
20.0
Benzyl alcohol
pg/L
50.0
22.8
22.3
45.6
44.6
20-109
2.2
20.0
Bis(2-Chloroethoxy)methane
pg/L
50.0
34.9
34.3
69.8
68.6
20-126
1.7
20.0
Bis(2-Chloroethyl)ether
pg/L
50.0
31.4
31.2
62.8
62.4
16-122
0.6
20.0
Bis(2-Chloroisopropyl)ether
pg/L
50.0
25.4
24.6
50.8
49.2
28-108
3.2
20.0
Bis(2-ethylhexyl)phthalate
pg/L
50.0
46.7
43.3
93.4
86.6
21-162
7.5
20.0
4-Bromophenyl phenyl ether
pg/L
50.0
39.8
38.3
79.6
76.6
31-124
3.8
20.0
Butyl benzyl phthalate
pg/L
50.0
43.0
40.7
86.0
81.4
33-142
5.4
20.0
4-Chloro-3-methyl phenol
pg/L
50.0
35.0
34.2
70.0
68.4
35-117
2.3
20.0
Date: 05/31/2024 01:51 PM Page 36 of 46
Page 187 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Prep: L749275 QC Analytical Batch(es): L749499
QC Prep Batch Method: 3510C Analysis Method: 8270D
Analysis Description: Semivolatile Organic Compounds - GC/MS
Laboratory Control Sample & LCSD LCS-L749275 LCSD-L749275
Parameter
Units
Spike
Conc.
LCS
Result
LCSD
Result
LCS
%Rec
LCSD
% Rec
% Rec
Limits
RPD
Max
RPD
4-Chloroaniline
pg/L
50.0
32.0
35.2
64.0
70.4
24-127
9.5
20.0
Chlorobenzilate
pg/L
50.0
48.2
43.2
96.4
86.4
35-118
10.9
20.0
2-Chloronaphthalene
pg/L
50.0
34.5
34.1
69.0
68.2
29-137
1.1
20.0
2-Chlorophenol
pg/L
50.0
26.4
26.2
52.8
52.4
27-102
0.7
20.0
4-Chlorophenyl phenyl ether
pg/L
50.0
39.1
39.6
78.2
79.2
39-110
1.2
20.0
Chrysene
pg/L
50.0
40.0
39.5
80.0
79.0
30-124
1.2
20.0
Dibenz(a,h)anthracene
pg/L
50.0
52.7
47.1
105
94.2
27-124
11.2
20.0
Dibenzofuran
pg/L
50.0
40.9
41.1
81.8
82.2
40-108
0.4
20.0
1,2-Dichlorobenzene
pg/L
50.0
29.9
29.1
59.8
58.2
26-100
2.7
20.0
1,3-Dichlorobenzene
pg/L
50.0
28.3
28.0
56.6
56.0
21-102
1.0
20.0
1,4-Dichlorobenzene
pg/L
50.0
29.7
29.1
59.4
58.2
24-99
2.0
20.0
3,3'-Dichlorobenzidine
pg/L
100
89.0
87.7
89.0
87.7
6-192
1.4
20.0
2,4-Dichlorophenol
pg/L
50.0
28.0
28.4
56.0
56.8
32-110
1.4
20.0
2,6-Dichlorophenol
pg/L
50.0
39.6
38.2
79.2
76.4
25-112
3.5
20.0
Diethyl phthalate
pg/L
50.0
41.3
42.3
82.6
84.6
36-130
2.3
20.0
Dimethyl phthalate
pg/L
50.0
40.5
40.3
81.0
80.6
34-123
0.4
20.0
3,3' Dimethylbenzidine
pg/L
150
63.6
94.3
42.4
62.8
6-192
38.8*
20.0
2,4-Dimethylphenol
pg/L
50.0
40.9
39.8
81.8
79.6
34-105
2.7
20.0
Di-n-butyl phthalate
pg/L
50.0
40.1
39.5
80.2
79.0
19-158
1.5
20.0
4,6- Din itro-2-methylphenol
pg/L
50.0
49.8
50.8
99.6
102
27-128
1.9
20.0
2,4-Dinitrophenol
pg/L
150
111
115
74.0
76.6
10-132
3.5
20.0
2,4-Dinitrotoluene
pg/L
50.0
41.5
40.9
83.0
81.8
24-147
1.4
20.0
2,6-Dinitrotoluene
pg/L
50.0
44.5
44.2
89.0
88.4
36-125
0.6
20.0
Di-n-Octyl Phthalate
pg/L
50.0
39.5
41.8
79.0
83.6
29-136
5.6
20.0
Ethyl methanesulfonate
pg/L
50.0
31.0
31.9
62.0
63.8
20-121
2.8
20.0
Fluoranthene
pg/L
50.0
41.4
44.8
82.8
89.6
28-127
7.8
20.0
* QC Fail Date: 05/31/2024 01:51 PM Page 37 of 46
Page 188 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Prep: L749275 QC Analytical Batch(es): L749499
QC Prep Batch Method: 3510C Analysis Method: 8270D
Analysis Description: Semivolatile Organic Compounds - GC/MS
Laboratory Control Sample & LCSD LCS-L749275 LCSD-L749275
Parameter
Units
Spike
Conc.
LCS
Result
LCSD
Result
LCS
%Rec
LCSD
% Rec
% Rec
Limits
RPD
Max
RPD
Fluorene
pg/L
50.0
39.2
40.1
78.4
80.2
41-116
2.2
20.0
Hexachlorobenzene
pg/L
50.0
38.9
37.6
77.8
75.2
18-136
3.3
20.0
Hexachlorobutadiene
pg/L
50.0
29.8
29.4
59.6
58.8
22-109
1.3
20.0
Hexachlorocyclopentadiene
pg/L
50.0
30.5
33.2
61.0
66.4
10-102
8.4
20.0
Hexachloroethane
pg/L
50.0
28.7
28.0
57.4
56.0
16-107
2.4
20.0
Indeno(1,2,3-cd)pyrene
pg/L
50.0
49.3
44.5
98.6
89.0
22-126
10.2
20.0
Isophorone
pg/L
50.0
22.9
22.6
45.8
45.2
31-116
1.3
20.0
Methyl methanesulfonate
pg/L
50.0
18.8
18.6
37.6
37.2
15-82
1.0
20.0
2-Methylnaphthalene
pg/L
50.0
38.0
37.2
76.0
74.4
34-108
2.1
20.0
2-Methylphenol
pg/L
50.0
22.6
23.2
45.2
46.4
22-97
2.6
20.0
3&4 Methylphenol
pg/L
50.0
22.5
22.5
45.0
45.0
21-96
0.0
20.0
Naphthalene
pg/L
50.0
31.2
31.0
62.4
62.0
33-108
0.6
20.0
2-Nitroaniline
pg/L
50.0
43.1
42.3
86.2
84.6
32-127
1.8
20.0
3-Nitroaniline
pg/L
50.0
45.7
46.4
91.4
92.8
28-142
1.5
20.0
4-Nitroaniline
pg/L
50.0
93.6
101
187*
202*
23-139
7.6
20.0
Nitrobenzene
pg/L
50.0
31.7
29.9
63.4
59.8
27-117
5.8
20.0
2-Nitrophenol
pg/L
50.0
35.2
34.7
70.4
69.4
25-114
1.4
20.0
4-Nitrophenol
pg/L
50.0
20.3
20.7
40.6
41.4
1-76
1.9
20.0
N-Nitrosodimethylamine
pg/L
50.0
15.0
14.6
30.0
29.2
14-84
2.7
20.0
N-Nitrosodiphenylamine
pg/L
50.0
35.8
34.9
71.6
69.8
45-135
2.5
20.0
N-Nitrosodiethylamine
pg/L
50.0
32.9
32.4
65.8
64.8
25-107
1.5
20.0
N-Nitroso-di-n-butylamine
pg/L
50.0
32.0
31.6
64.0
63.2
25-126
1.2
20.0
N-Nitroso-di-n-propylamine
pg/L
50.0
32.4
31.6
64.8
63.2
29-114
2.5
20.0
Pentachlorobenzene
pg/L
50.0
39.0
38.4
78.0
76.8
34-135
1.5
20.0
Pentachloronitrobenzene
pg/L
50.0
41.5
40.7
83.0
81.4
34-135
1.9
20.0
Pentachlorophenol
pg/L
50.0
45.4
44.4
90.8
88.8
17-142
2.2
20.0
* QC Fail Date: 05/31/2024 01:51 PM Page 38 of 46
Page 189 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Prep: L749275 QC Analytical Batch(es): L749499
QC Prep Batch Method: 3510C Analysis Method: 8270D
Analysis Description: Semivolatile Organic Compounds - GC/MS
Laboratory Control Sample & LCSD LCS-L749275 LCSD-L749275
Spike LCS LCSD LCS LCSD % Rec
Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max
RPD
Phenacetin
pg/L
50.0
46.1
45.3
92.2
90.6
29-141
1.7
20.0
Phenanthrene
pg/L
50.0
40.4
39.9
80.8
79.8
40-120
1.2
20.0
Phenol
pg/L
50.0
9.57
9.53
19.1
19.0
11-55
0.4
20.0
Pyrene
pg/L
50.0
44.5
39.0
89.0
78.0
20-154
13.1
20.0
1,2,4,5-Tetrachlorobenzene
pg/L
50.0
33.5
33.6
67.0
67.2
28-110
0.2
20.0
2,3,4,6-Tetrachlorophenol
pg/L
50.0
41.5
41.8
83.0
83.6
28-118
0.7
20.0
1,2,4-Trichlorobenzene
pg/L
50.0
31.4
31.3
62.8
62.6
23-106
0.3
20.0
2,4,5-Trichlorophenol
pg/L
50.0
41.8
40.0
83.6
80.0
26-118
4.4
20.0
2,4,6-Trichlorophenol
pg/L
50.0
40.4
39.1
80.8
78.2
26-115
3.2
20.0
2-Fluorobiphenyl (S)
65.5
62.8
24-93
2-Fluorophenol (S)
20.7
20.0
10-44
Nitrobenzene-d5 (S)
62.7
60.0
20-91
Phenol-d6 (S)
14.3
13.7
7-32
4-Terphenyl-d14 (S)
86.0
71.6
35-126
2,4,6-Tribromophenol (S)
78.8
75.7
39-110
Date: 05/31/2024 01:51 PM Page 39 of 46
Page 190 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Prep: L749276 QC Analytical Batch(es): L749501
QC Prep Batch Method: 3510C Analysis Method: 8270D
Analysis Description: 8270 Extended List
Lab Reagent Blank LRB-L749276 Matrix: AQU
Associated Lab Samples: 92542, 92544, 92546, 92547, 92548, 92549, 92550
Blank MDL MQL Analyzed
Parameter Units Result
1,3,5-Trinitrobenzene
pg/L
<10.0
10.0
10.0
05/08/24 15:59
Isodrin
pg/L
<10.0
10.0
10.0
05/08/24 15:59
Kepone
pg/L
<10.0
10.0
10.0
05/08/24 15:59
1,4-Naphthoquinone
pg/L
<10.0
10.0
10.0
05/08/24 15:59
1-Naphthylamine
pg/L
<10.0
10.0
10.0
05/08/24 15:59
2-Acetylaminofluorene
pg/L
<10.0
10.0
10.0
05/08/24 15:59
2-Naphthylamine
pg/L
<10.0
10.0
10.0
05/08/24 15:59
3-Methylcholanthrene
pg/L
<10.0
10.0
10.0
05/08/24 15:59
4-Aminobiphenyl
pg/L
<10.0
10.0
10.0
05/08/24 15:59
5-Nitro-o-toluidine
pg/L
<10.0
10.0
10.0
05/08/24 15:59
7,12-Di methyl benz(a)anth racene
pg/L
<10.0
10.0
10.0
05/08/24 15:59
Diallate
pg/L
<10.0
10.0
10.0
05/08/24 15:59
Hexachloropropene
pg/L
<10.0
10.0
10.0
05/08/24 15:59
Isosafrole
pg/L
<10.0
10.0
10.0
05/08/24 15:59
Methapyrilene
pg/L
<10.0
10.0
20.0
05/08/24 15:59
N-Nitrosomethylethylamine
pg/L
<10.0
10.0
10.0
05/08/24 15:59
N-Nitrosomorpholine
pg/L
<10.0
10.0
10.0
05/08/24 15:59
N-Nitrosopiperidine
pg/L
<10.0
10.0
10.0
05/08/24 15:59
N-Nitrosopyrrolidine
pg/L
<10.0
10.0
10.0
05/08/24 15:59
o-Toluidine
pg/L
<10.0
10.0
10.0
05/08/24 15:59
p-Dimethylaminoazobenzene
pg/L
<10.0
10.0
10.0
05/08/24 15:59
p-Phenylenediamine
pg/L
<10.0
10.0
10.0
05/08/24 15:59
Pronamide
pg/L
<10.0
10.0
10.0
05/08/24 15:59
Safrole
pg/L
<10.0
10.0
10.0
05/08/24 15:59
Date: 05/31/2024 01:51 PM Page 40 of 46
Page 191 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Prep: L749276 QC Analytical Batch(es): L749501
QC Prep Batch Method: 3510C Analysis Method: 8270D
Analysis Description: 8270 Extended List
Laboratory Control Sample & LCSD LCS-L749276 LCSD-L749276
Parameter
Units
Spike
Conc.
LCS
Result
LCSD
Result
LCS
%Rec
LCSD
% Rec
% Rec
Limits
RPD
Max
RPD
1,3,5-Trinitrobenzene
pg/L
50.0
33.8
32.6
67.6
65.2
20-120
3.6
20.0
Isodrin
pg/L
50.0
33.1
29.2
66.2
58.4
20-120
12.5
20.0
Kepone
pg/L
50.0
<10.0
<10.0
0.0*
0.0*
20-120
0.0
20.0
1,4-Naphthoquinone
pg/L
50.0
<10.0
<10.0
0.0*
0.0*
20-120
0.0
20.0
1-Naphthylamine
pg/L
50.0
32.7
31.0
65.4
62.0
20-120
5.3
20.0
2-Acetylaminofluorene
pg/L
50.0
38.5
33.8
77.0
67.6
20-120
13.0
20.0
2-Naphthylamine
pg/L
50.0
38.7
36.6
77.4
73.2
20-120
5.5
20.0
3-Methylcholanthrene
pg/L
50.0
36.2
29.9
72.4
59.8
20-120
19.0
20.0
4-Aminobiphenyl
pg/L
50.0
47.2
43.6
94.4
87.2
20-120
7.9
20.0
5-Nitro-o-toluidine
pg/L
50.0
34.3
31.8
68.6
63.6
20-120
7.5
20.0
7,12-Di methyl benz(a)anth racene
pg/L
50.0
31.9
26.3
63.8
52.6
20-120
19.2
20.0
Diallate
pg/L
50.0
33.0
29.1
66.0
58.2
20-120
12.5
20.0
Hexachloropropene
pg/L
50.0
24.6
24.3
49.2
48.6
20-120
1.2
20.0
Isosafrole
pg/L
50.0
37.1
33.9
74.2
67.8
20-120
9.0
20.0
Methapyrilene
pg/L
50.0
39.8
30.5
79.6
61.0
20-120
26.4*
20.0
N-Nitrosomethylethylamine
pg/L
50.0
14.8
14.7
29.6
29.4
20-120
0.6
20.0
N-Nitrosomorpholine
pg/L
50.0
15.7
14.8
31.4
29.6
20-120
5.9
20.0
N-Nitrosopiperidine
pg/L
50.0
22.8
21.6
45.6
43.2
20-120
5.4
20.0
N-Nitrosopyrrolidine
pg/L
50.0
18.6
17.8
37.2
35.6
20-120
4.3
20.0
o-Toluidine
pg/L
50.0
28.2
26.4
56.4
52.8
20-120
6.5
20.0
p-Dimethylaminoazobenzene
pg/L
50.0
37.4
31.6
74.8
63.2
20-120
16.8
20.0
p-Phenylenediamine
pg/L
50.0
<10.0
<10.0
0.0*
0.0*
20-120
0.0
20.0
Pronamide
pg/L
50.0
35.8
31.9
71.6
63.8
20-120
11.5
20.0
Safrole
pg/L
50.0
28.3
26.5
56.6
53.0
20-120
6.5
20.0
* QC Fail Date: 05/31/2024 01:51 PM Page 41 of 46
Page 192 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Analytical Batch: V47232
Analysis Method: 9014
Analysis Description: Total Cyanide
Lab Reagent Blank LRB Matrix: AQU
Associated Lab Samples: 92542, 92544, 92546, 92547
Blank MDL MQL Analyzed
Parameter Units Result
Cyanide, Total pg/L <12.0 12.0 25.0 05/14/24 14:05
Laboratory Control Sample & LCSD LCS LCSD
Spike LCS LCSD LCS LCSD % Rec
Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max
RPD
Cyanide, Total pg/L 100 85.0 99.0 85.0 99.0 85-115 15.2 20
Date: 05/31/2024 01:51 PM Page 42 of 46
Page 193 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
• i
Way po�nt ^ 449 Spring#�rQok Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
Quality Control Data
Client ID:
Smith & Gardner, Inc.
Project Description:
Surry County C&D/MSW Spring
Report No:
24-124-0102
QC Analytical Batch:
V47261
Analysis Method:
9014
Analysis Description:
Total Cyanide
Lab Reagent Blank
LRB
Matrix: AQU
Associated Lab Samples:
92548, 92549, 92550
Blank MDL
MQL
Analyzed
Parameter
Units Result
Cyanide, Total
pg/L <12.0 12.0
25.0
05/15/24 10:52
Laboratory Control Sample LCS
Spike
LCS
LCS %Rec
% Rec
Parameter
Units Conc.
Result
Limits
Cyanide, Total
pg/L 100
87.0
87.0
85-115
Matrix Spike & Matrix Spike Duplicate V 92550-MS V 92550-MSD
MS Spike
MSD MS Result
MSD MS
MSD %Rec Max
Parameter
Units Result Conc.
Spike
Result %Rec
%Rec Limits RPD RPD
Conc.
Cyanide, Total
pg/L <12.0 100
100 82.0
89.0 82.0
89.0 80-120 8.1 20
Date: 05/31/2024 01:51 PM Page 43 of 46
Page 194 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Prep:
V47209
QC Analytical Batch(es): V47210
QC Prep Batch Method:
SW-9056A (PREP)
Analysis Method:
9056A
Analysis Description:
Anions by Ion Chromatography
Lab Reagent Blank
LRB-V47209
Matrix: AQU
Associated Lab Samples:
92542, 92544, 92546, 92547, 92548, 92549, 92550
Blank MDL
MQL
Analyzed
Parameter
Units
Result
Chloride
pg/L
<500 500
1000
05/03/24 13:40
Nitrate (NO3-N)
pg/L
<50.0 50.0
100
05/03/24 13:40
Sulfate
pg/L
<600 600
2000
05/03/24 13:40
Laboratory Control Sample
LCS-V47209
Spike
LCS
LCS %Rec
% Rec
Parameter
Units
Conc.
Result
Limits
Chloride
pg/L
40000
40100
100
80-120
Nitrate (NO3-N)
pg/L
4000
3890
97.0
80-120
Sulfate
pg/L
40000
38500
96.0
80-120
Matrix Spike & Matrix Spike Duplicate
V 92621-MS-V47209
V 92621-MSD-V47209
MS Spike
MSD
MS Result
MSD
MS
MSD
%Rec
Max
Parameter
Units
Result
Conc.
Spike
Result
%Rec
%Rec
Limits
RPD
RPD
Conc.
Chloride
pg/L
7270
40000
40000
49500
49600
106
106
80-120
0.2
20
Nitrate(NO3-N)
pg/L
2050
4000
4000
6170
6180
103
103
80-120
0.1
20
Sulfate
pg/L
929
40000
40000
42900
42400
105
104
80-120
1.1
20
Date: 05/31/2024 01:51 PM Page 44 of 46
Page 195 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Smith & Gardner, Inc.
Project Description: Surry County C&D/MSW Spring
Report No: 24-124-0102
QC Prep:
V46866
QC Analytical Batch(es): V46867
QC Prep Batch Method:
RSK-175 (Prep)
Analysis Method:
RSK-175
Analysis Description:
RSK-175
Lab Reagent Blank
LRB-V46866
Matrix: AQU
Associated Lab Samples:
92542, 92544, 92546, 92547, 92548, 92549, 92550
Blank MDL
MQL
Analyzed
Parameter
Units
Result
Ethane
pg/L
<2.67 2.67
10.0
05/06/24 12:33
Ethene
pg/L
<2.28 2.28
10.0
05/06/24 12:33
Methane
pg/L
<2.51 2.51
10.0
05/06/24 12:33
Laboratory Control Sample
LCS-V46866
Spike
LCS
LCS %Rec
% Rec
Parameter
Units
Conc.
Result
Limits
Ethane
pg/L
293
280
95.5
85-115
Ethene
pg/L
273
271
99.2
85-115
Methane
pg/L
156
173
111
85-115
Duplicate
V 92542-DUP-V46866
Result DUP
RPD
Max RPD
Analyzed
Parameter
Units
Result
Ethane
pg/L
< 10.0 <10.0
0.0
20.0
05/06/24 15:35
Ethene
pg/L
< 10.0 <10.0
0.0
20.0
05/06/24 15:35
Methane
pg/L
< 10.0 <10.0
0.0
20.0
05/06/24 15:35
Date: 05/31/2024 01:51 PM Page 45 of 46
Page 196 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
• i
Way po�nt ^ 449 Spring#�rQok Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
Quality Control Data
Client ID:
Smith & Gardner, Inc.
Project Description:
Surry County C&D/MSW Spring
Report No:
24-124-0102
QC Analytical Batch:
V46836
Analysis Method:
SM-3500-Fe-13
Analysis Description:
Ferrous Iron
Lab Reagent Blank
LRB
Matrix: AQU
Associated Lab Samples:
92542, 92544, 92546, 92547, 92548, 92549, 92550
Blank MDL
MQL
Analyzed
Parameter
Units
Result
Ferrous Iron
mg/L
<0.05 0.05
0.20
05/03/24 13:40
Laboratory Control Sample
LCS
Spike
LCS
LCS %Rec
% Rec
Parameter
Units
Conc.
Result
Limits
Ferrous Iron
mg/L
2.00
1.95
98.0
90-110
Matrix Spike & Matrix Spike Duplicate
V 92550-MS V 92550-MSD
MS Spike
MSD MS Result
MSD MS
MSD %Rec Max
Parameter
Units
Result Conc.
Spike
Result %Rec
%Rec Limits RPD RPD
Conc.
Ferrous Iron
mg/L
< 0.05 2.00
2.00 2.10
2.10 105
105 80-120 0.0 20.0
Date: 05/31/2024 01:51 PM Page 46 of 46
Page 197 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
WayPAo0nt..
NALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.wa y p of n to na lyti ca I.c om
Shipment Receipt Form
Customer Number: 01186
Customer Name: Smith & Gardner, Inc.
Report Number: 24-124-0102
Shipping Method
0 Fed Ex 0 US Postal # Lab 0 Other
0 UPS 0 Client 0 Courier Thermometer ID: IRT15 0.7C
Shipping container/cooler uncompromised?
0 Yes
0 No
Number of coolers/boxes received
8
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
* Yes
0 No
COC agrees with sample label(s)?
0 Yes
0 No
COC properly completed
Yes
0 No
Samples in proper containers?
Yes
0 No
Sample containers intact?
0 Yes
0 No
Sufficient sample volume for indicated test(s)?
Yes
0 No
All samples received within holding time?
Yes
0 No
Cooler temperature in compliance?
0 Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes
0 No
Water - Sample containers properly preserved
Yes
0 No
0 N/A
Water - VOA vials free of headspace
Yes
0 No
0 N/A
Trip Blanks received with VOAs
Yes
0 No
0 N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F High concentration container (48 hr) F_ Low concentration EnCore samplers (48 hr)
F_ High concentration pre -weighed (methanol -14 d) Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included?
0 Yes
0 No
Comments
Signature: Angela D Overcash Date & Time: 05/03/2024 15:53:18
Page 198 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
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Page 199 of 200
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
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Page 200 of 200
U
Y
C
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
Waypoint
ANALYTICAL
5/14/2024
Smith & Gardner, Inc.
Seth C. Rickerts
14 N. Boylan Avenue
Raleigh, NC, 27603
Ref: Analytical Testing
Lab Report Number: 24-123-0100
Client Project Description: Surry County MSW
Site: 86-02
Dear Seth C. Rickerts:
449 5pringbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Waypoint Analytical, LLC (Charlotte) received sample(s) on 5/2/2024 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2021) unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
a'-1
Angela D Overcash
Senior Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Charlotte, NC 28217
Waypoint, 449 Springbrook Rd, Ch
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State
Program
Lab ID
Expiration Date
North Carolina
State Program
37735
07/31/2024
North Carolina
State Program
402
12/31/2024
South Carolina
State Program
99012
07/31/2024
South Carolina
State Program
99012
12/31/2024
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2025
Arkansas
State Program
88-0650
02/07/2025
California
State Program
2904
06/30/2024
Florida
State Program - NELAP
E871157
06/30/2024
Georgia
State Program
C044
11/14/2025
Georgia
State Program
04015
06/30/2024
Illinois
State Program - NELAP
200078
10/31/2024
Kentucky
State Program
80215
06/30/2024
Kentucky
State Program
KY90047
12/31/2024
Louisiana
State Program - NELAP
LA037
12/31/2024
Louisiana
State Program - NELAP
04015
06/30/2024
Mississippi
State Program
MS
11/14/2025
North Carolina
State Program
47701
07/31/2024
North Carolina
State Program
415
12/31/2024
Pennsylvania
State Program - NELAP
68-03195
05/31/2024
South Carolina
State Program
84002
06/30/2024
Tennessee
State Program
02027
11/14/2025
Texas
State Program - NELAP
T104704180
09/30/2024
Virginia
State Program
00106
06/30/2024
Virginia
State Program - NELAP
460181
09/14/2024
Page 1 of 1 00016/24-123-0100
Page 2 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
(2)
Charlotte, NC 28217
Waypoint. 449 Springbrook Rd, Ch
Main 704.529.6364
ANALYTICAL www.waypointana lyti ca Isom
Sample Summary Table
Report Number:
Client Project Description:
24-123-0100
Surry County MSW
Lab No
Client Sample ID
Matrix
Date Collected
Date Received
Method
Lab ID
92443
MW-7
Aqueous
04/30/2024 13:45
05/02/2024 11:00
92443
MW-7
Aqueous
04/30/2024 13:45
05/02/2024 11:00
6020B
WP MTN
92444
MW-6
Aqueous
04/30/2024 14:00
05/02/2024 11:00
92444
MW-6
Aqueous
04/30/2024 14:00
05/02/2024 11:00
6020E
WP MTN
92445
MW-12S
Aqueous
04/30/2024 14:15
05/02/2024 11:00
92445
MW-12S
Aqueous
04/30/2024 14:15
05/02/2024 11:00
6020E
WP MTN
92446
MW-13
Aqueous
04/30/2024 14:30
05/02/2024 11:00
92446
MW-13
Aqueous
04/30/2024 14:30
05/02/2024 11:00
6020E
WP MTN
92447
MW-23
Aqueous
04/30/2024 14:45
05/02/2024 11:00
92447
MW-23
Aqueous
04/30/2024 14:45
05/02/2024 11:00
6020E
WP MTN
92448
MW-19
Aqueous
04/30/2024 15:00
05/02/2024 11:00
92448
MW-19
Aqueous
04/30/2024 15:00
05/02/2024 11:00
6020E
WP MTN
92449
MW-22
Aqueous
04/30/2024 15:15
05/02/2024 11:00
92449
MW-22
Aqueous
04/30/2024 15:15
05/02/2024 11:00
6020E
WP MTN
92450
MW-17
Aqueous
04/30/2024 15:30
05/02/2024 11:00
92450
MW-17
Aqueous
04/30/2024 15:30
05/02/2024 11:00
6020E
WP MTN
92451
MW-3R
Aqueous
04/30/2024 15:45
05/02/2024 11:00
92451
MW-3R
Aqueous
04/30/2024 15:45
05/02/2024 11:00
6020E
WP MTN
92452
MW-20
Aqueous
04/30/2024 16:00
05/02/2024 11:00
92452
MW-20
Aqueous
04/30/2024 16:00
05/02/2024 11:00
6020E
WP MTN
92453
SW-4
Aqueous
04/30/2024 16:15
05/02/2024 11:00
92453
SW-4
Aqueous
04/30/2024 16:15
05/02/2024 11:00
6020E
WP MTN
92454
WSW-2
Aqueous
04/30/2024 17:00
05/02/2024 11:00
92454
WSW-2
Aqueous
04/30/2024 17:00
05/02/2024 11:00
6020E
WP MTN
92455
Trip Blank
Aqueous
04/30/2024
05/02/2024 11:00
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 3 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
'p W
= 1
Main 704.529.6364
Waypoint, 449 Springbrook Rd, Charlotte, 28217
ANALYTICAL www.waypointanalytical.com
Project:
Report Number:
Surry County MSW
24-123-0100
Summary of Detected Analytes
Client Sample ID
Lab Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
MW-7
V 92443
6020B
Barium
62.7
pg/L
0.453
05/09/202417:08
6020E
Beryllium
0.109
pg/L
0.102
05/09/202417:08
J
6020E
Chromium
2.83
pg/L
0.346
05/09/202417:08
B
6020E
Cobalt
91.8
pg/L
0.060
05/09/202417:08
6020E
Copper
1.13
pg/L
0.489
05/09/202417:08
6020E
Lead
0.286
pg/L
0.264
05/09/202417:08
J
6020E
Nickel
3.55
pg/L
0.182
05/09/202417:08
6020E
Selenium
1.14
pg/L
0.703
05/09/202417:08
6020E
Thallium
0.289
pg/L
0.0610
05/09/202417:08
J
6020E
Vanadium
0.854
pg/L
0.767
05/10/202418:10
J
6020B
Zinc
9.87
pg/L
4.67
05/09/202417:08
J
8260D SIM
1,4-Dioxane
1.76
pg/L
0.139
05/02/2024 16:38
J
MW-6
V 92444
6020B
Barium
63.0
pg/L
0.453
05/09/202417:13
6020B
Chromium
2.26
pg/L
0.346
05/09/202417:13
B
6020E
Cobalt
27.2
pg/L
0.060
05/09/202417:13
6020B
Copper
0.508
pg/L
0.489
05/09/202417:13
J
6020B
Nickel
2.18
pg/L
0.182
05/09/202417:13
6020B
Thallium
0.610
pg/L
0.0610
05/09/202417:13
J
6020B
Zinc
14.0
pg/L
4.67
05/09/202417:13
MW-12S
V 92445
6020B
Barium
19.6
pg/L
0.453
05/09/202417:17
6020B
Chromium
3.11
pg/L
0.346
05/09/202417:17
B
6020E
Cobalt
1.05
pg/L
0.060
05/09/202417:17
6020B
Copper
1.70
pg/L
0.489
05/09/202417:17
6020B
Lead
0.635
pg/L
0.264
05/09/202417:17
J
6020B
Nickel
2.62
pg/L
0.182
05/09/202417:17
6020B
Vanadium
2.29
pg/L
0.767
05/10/202418:29
J
6020B
Zinc
6.82
pg/L
4.67
05/09/202417:17
J
MW-13
V 92446
6020B
Arsenic
0.582
pg/L
0.297
05/09/202417:21
J
6020B
Barium
173
pg/L
0.453
05/09/202417:21
6020B
Beryllium
1.05
pg/L
0.102
05/09/202417:21
6020B
Chromium
12.7
pg/L
0.346
05/09/202417:21
6020B
Cobalt
22.8
pg/L
0.060
05/09/202417:21
Page 4 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
'p W
= 1
Main 704.529.6364
Waypoint, 449 Springbrook Rd, Charlotte, 28217
ANALYTICAL www.waypointanalytical.com
Project:
Report Number:
Surry County MSW
24-123-0100
Summary of Detected Analytes
Client Sample ID
Lab Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
MW-13
V 92446
6020B
Copper
6.17
pg/L
0.489
05/09/202417:21
6020E
Lead
6.75
pg/L
0.264
05/09/202417:21
6020E
Nickel
7.67
pg/L
0.182
05/09/202417:21
6020E
Selenium
1.16
pg/L
0.703
05/09/202417:21
6020E
Silver
0.229
pg/L
0.0570
05/09/202417:21
1
6020E
Thallium
0.280
pg/L
0.0610
05/09/202417:21
1
6020E
Vanadium
12.5
pg/L
0.767
05/10/202418:34
6020E
Zinc
37.1
pg/L
4.67
05/09/202417:21
8260D
1,1-Dichloroethane
0.498
pg/L
0.240
05/07/202417:37
1
8260D
cis- 1,2-Dichloroethene
7.40
pg/L
0.200
05/07/202417:37
8260D SIM
1,4-Dioxane
7.08
pg/L
0.139
05/02/2024 17:53
MW-23
V 92447
6020B
Barium
181
pg/L
0.453
05/09/202417:26
6020E
Beryllium
0.784
pg/L
0.102
05/09/202417:26
1
6020B
Chromium
14.4
pg/L
0.346
05/09/202417:26
6020E
Cobalt
4.35
pg/L
0.060
05/09/202417:26
6020B
Copper
4.47
pg/L
0.489
05/09/202417:26
6020B
Lead
6.19
pg/L
0.264
05/09/202417:26
6020B
Nickel
6.16
pg/L
0.182
05/09/202417:26
6020B
Selenium
1.37
pg/L
0.703
05/09/202417:26
6020B
Thallium
0.117
pg/L
0.0610
05/09/202417:26
1
6020B
Vanadium
19.4
pg/L
0.767
05/10/202418:38
6020B
Zinc
26.9
pg/L
4.67
05/09/202417:26
MW-19
V 92448
6020B
Arsenic
0.755
pg/L
0.297
05/09/202417:30
1
6020B
Barium
276
pg/L
0.453
05/09/202417:30
6020B
Beryllium
2.37
pg/L
0.102
05/09/202417:30
6020B
Chromium
45.0
pg/L
0.346
05/09/202417:30
6020B
Cobalt
15.4
pg/L
0.060
05/09/202417:30
6020B
Copper
24.3
pg/L
0.489
05/09/202417:30
6020E
Lead
10.6
pg/L
0.264
05/09/202417:30
6020B
Nickel
15.7
pg/L
0.182
05/09/202417:30
6020E
Selenium
1.71
pg/L
0.703
05/09/202417:30
6020B
Silver
0.0890
pg/L
0.0570
05/09/202417:30
1
6020E
Thallium
0.572
pg/L
0.0610
05/09/202417:30
1
6020B
Vanadium
55.9
pg/L
0.767
05/10/202418:43
Page 5 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
(2)
Charlotte, NC 28217
Waypoint, 449 Springbrook Rd, Ch
Main 704.529.6364
ANALYTICAL www.waypointanalyticaI -co m
Summary of Detected Analytes
Project:
Surry County MSW
Report Number:
24-123-0100
Client Sample ID
Lab Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
MW-19
V 92448
6020B
Zinc
95.4
pq/L
4.67
05/09/202417:30
8260D
1,1-Dichloroethane
0.353
pg/L
0.240
05/07/202418:26
J
8260D
cis-1,2-Dichloroethene
0.838
pq/L
0.200
05/07/202418:26
MW-22
V 92449
6020B
Barium
41.9
pg/L
0.453
05/09/202417:36
6020B
Chromium
2.51
pq/L
0.346
05/09/202417:36
B
6020B
Cobalt
3.55
pg/L
0.060
05/09/202417:36
6020B
Copper
2.14
pq/L
0.489
05/09/202417:36
6020B
Nickel
1.62
pg/L
0.182
05/09/202417:36
6020B
Selenium
1.12
pq/L
0.703
05/09/202417:36
6020B
Thallium
0.0999
pg/L
0.0610
05/09/202417:36
J
6020B
Zinc
6.36
pq/L
4.67
05/09/202417:36
J
MW-17
V 92450
6020B
Arsenic
0.402
pg/L
0.297
05/09/202417:50
J
6020B
Barium
45.1
pq/L
0.453
05/10/202418:52
6020B
Beryllium
0.689
pg/L
0.102
05/09/202417:50
J
6020B
Cadmium
1.48
pq/L
0.350
05/09/202417:50
6020B
Chromium
7.99
pg/L
0.346
05/09/202417:50
B
6020B
Cobalt
17.8
pq/L
0.060
05/09/202417:50
6020B
Copper
3.91
pg/L
0.489
05/09/202417:50
6020B
Lead
1.73
pq/L
0.264
05/09/202417:50
6020B
Nickel
6.82
pg/L
0.182
05/09/202417:50
6020B
Selenium
1.11
pq/L
0.703
05/10/202418:52
6020B
Thallium
0.0908
pg/L
0.0610
05/09/202417:50
J
6020B
Vanadium
6.92
pq/L
0.767
05/10/202418:52
6020B
Zinc
17.6
pg/L
4.67
05/09/202417:50
8260D SIM
1,4-Dioxane
8.19
pg/L
0.139
05/02/2024 19:34
MW-3R
V 92451
6020B
Arsenic
0.857
pg/L
0.297
05/09/202417:55
J
6020B
Barium
126
pq/L
0.453
05/10/202418:57
6020B
Chromium
4.41
pg/L
0.346
05/09/202417:55
B
6020B
Cobalt
246
pq/L
0.060
05/09/202417:55
6020B
Copper
2.65
pg/L
0.489
05/09/202417:55
6020B
Lead
1.07
pq/L
0.264
05/09/202417:55
6020B
Nickel
25.0
pg/L
0.182
05/09/202417:55
Page 6 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
(2)
Charlotte, NC 28217
Waypoint, 449 Springbrook Rd, Ch
Main 704.529.6364
ANALYTICAL www.way po i nta n a lyti c a I -co m
Summary of Detected Analytes
Project:
Surry County MSW
Report Number:
24-123-0100
Client Sample ID
Lab Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
MW-3R
V 92451
6020B
Zinc
14.2
pq/L
4.67
05/09/202417:55
8260D
Benzene
1.33
Ng/L
0.180
05/07/202419:40
8260D
Chlorobenzene
5.63
pq/L
0.190
05/07/202419:40
8260D
1,1-Dichloroethane
0.816
pg/L
0.240
05/07/202419:40
8260D
1,2-Dichloroethane
1.92
pq/L
0.150
05/07/202419:40
8260D
cis- 1,2-Dichloroethene
11.0
pg/L
0.200
05/07/202419:40
8260D
Toluene
0.463
pq/L
0.220
05/07/202419:40
J
8260D
Vinyl Chloride
5.91
pg/L
0.170
05/07/2024 19:40
8260D SIM
1,4-Dioxane
2.43
pg/L
0.139
05/02/2024 19:59
MW-20
V 92452
6020B
Barium
105
Ng/L
0.453
05/10/202419:01
6020B
Beryllium
0.739
pq/L
0.102
05/09/202417:59
J
6020B
Chromium
10.0
Ng/L
0.346
05/09/202417:59
6020B
Cobalt
201
pq/L
0.060
05/09/202417:59
6020B
Copper
3.56
Ng/L
0.489
05/09/202417:59
6020B
Lead
3.28
pq/L
0.264
05/09/202417:59
6020B
Nickel
12.3
Ng/L
0.182
05/09/202417:59
6020B
Silver
0.0795
pq/L
0.0570
05/09/202417:59
J
6020B
Thallium
1.55
Ng/L
0.0610
05/09/202417:59
6020B
Vanadium
9.42
pq/L
0.767
05/10/202419:01
6020B
Zinc
39.7
Ng/L
4.67
05/09/202417:59
8260D
Benzene
1.53
pq/L
0.180
05/07/2024 20:05
8260D
Chlorobenzene
1.80
Ng/L
0.190
05/07/2024 20:05
8260D
1,2-Dichlorobenzene
1.49
pq/L
0.220
05/07/2024 20:05
8260D
1,1-Dichloroethane
1.35
Ng/L
0.240
05/07/2024 20:05
8260D
cis- 1,2-Dichloroethene
11.7
pq/L
0.200
05/07/2024 20:05
8260D
Tetrahydrofuran
7.59
Ng/L
1.50
05/07/2024 20:05
J
8260D
Vinyl Chloride
6.63
pq/L
0.170
05/07/2024 20:05
8260D SIM
1,4-Dioxane
2.74
Ng/L
0.139
05/02/2024 20:24
SW-4
V 92453
6020B
Barium
16.2
pq/L
0.453
05/10/202419:06
6020B
Chromium
1.09
pg/L
0.346
05/09/202418:03
B
6020B
Cobalt
1.26
pq/L
0.060
05/09/202418:03
6020B
Copper
0.615
Ng/L
0.489
05/09/202418:03
J
6020B
Nickel
0.192
pq/L
0.182
05/09/202418:03
J
Page 7 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypoint'(2)
ANALYTICAL
Project: Surry County MSW
Report Number: 24-123-0100
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lytica Isom
Summary of Detected
Client Sample ID Lab Sample ID
Method Parameters Result Units Report Limit Analyzed Qualifiers
WSW-2
V 92454
6020B
Barium
2.99
6020B
Chromium
2.11
6020B
Copper
0.825
6020B
Nickel
0.479
pq/L
0.453
05/10/202419:10
Ng/L
0.346
05/09/202418:08
B
pq/L
0.489
05/09/202418:08
J
pg/L
0.182
05/09/202418:08
J
Page 8 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypoint
ANALYTICAL
Client: Smith & Gardner, Inc.
Project: Surry County MSW
Lab Report Number: 24-123-0100
Date: 5/14/2024
449 5pringbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
CASE NARRATIVE
Metals Analyses Method 6020B
Sample 92443 (MW-7)
Analyte: Chromium
QC Batch No: 1-749687/1-749369
Target analyte(s) was identified in the method blank associated with this project, below the Method Quantitation
Limit. Per laboratory protocol any associated affected sample result is flagged "B" to indicate that it was detected
in the method blank.
Sample 92444 (MW-6)
Analyte: Chromium
QC Batch No: 1-749687/1-749369
Target analyte(s) was identified in the method blank associated with this project, below the Method Quantitation
Limit. Per laboratory protocol any associated affected sample result is flagged "B" to indicate that it was detected
in the method blank.
Sample 92445 (MW-12S)
Analyte: Chromium
QC Batch No: 1-749687/1-749369
Target analyte(s) was identified in the method blank associated with this project, below the Method Quantitation
Limit. Per laboratory protocol any associated affected sample result is flagged "B" to indicate that it was detected
in the method blank.
Sample 92449 (MW-22)
Analyte: Chromium
QC Batch No: 1-749687/1-749369
Target analyte(s) was identified in the method blank associated with this project, below the Method Quantitation
Limit. Per laboratory protocol any associated affected sample result is flagged "B" to indicate that it was detected
in the method blank.
Sample 92450 (MW-17)
Analyte: Chromium
QC Batch No: 1-749687/1-749369
Target analyte(s) was identified in the method blank associated with this project, below the Method Quantitation
Limit. Per laboratory protocol any associated affected sample result is flagged "B" to indicate that it was detected
in the method blank.
Sample 92451 (MW-3R)
Analyte: Chromium
QC Batch No: 1-749687/1-749369
Target analyte(s) was identified in the method blank associated with this project, below the Method Quantitation
Limit. Per laboratory protocol any associated affected sample result is flagged "B" to indicate that it was detected
in the method blank.
Sample 92453 (SW-4)
Analyte: Chromium
Page 9 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypoint 449 5pringhraok Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
QC Batch No: L749687/L749369
Target analyte(s) was identified in the method blank associated with this project, below the Method Quantitation
Limit. Per laboratory protocol any associated affected sample result is flagged "B" to indicate that it was detected
in the method blank.
Sample 92454 (WSW-2)
Analyte: Chromium
QC Batch No: L749687/L749369
Target analyte(s) was identified in the method blank associated with this project, below the Method Quantitation
Limit. Per laboratory protocol any associated affected sample result is flagged "B" to indicate that it was detected
in the method blank.
Sample 92458 (MW-4S)
Analyte: Chromium
QC Batch No: L749687/L749369
Target analyte(s) was identified in the method blank associated with this project, below the Method Quantitation
Limit. Per laboratory protocol any associated affected sample result is flagged "B" to indicate that it was detected
in the method blank.
Volatile Organic Compounds - GUMS Method 8260D
Analyte: 1,4-Dioxane
QC Batch No: V47047/V47029
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: 2-Butanone
QC Batch No: V47047/V47029
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Acetone
QC Batch No: V47047/V47029
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: 1,2-Dibromo-3-chloropropane
QC Batch No: V47047/V47029
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Tetrahydrofuran
QC Batch No: V47047/V47029
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Volatile Organic Compounds - GUMS Method 8260D SIM
Sample 92451 (MW-3R)
Analyte: 4-Bromofluorobenzene
QC Batch No: V46804/V46801
Surrogate(s) was flagged for recovery outside QC limits in this project sample. This sample was re -analyzed for
verification, and/or dilution of target analytes. Batch QC samples (method blank and laboratory control samples)
all showed surrogates within QC limits.
Page 10 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
WavDdibnto
ANALYTICAL
01186
Smith & Gardner, Inc.
Seth C. Rickerts
14 N. Boylan Avenue
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Project Surry County MSW
Information :
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Report Date : 05/14/2024
Received : 05/02/2024
Lab No : 92443
Sample ID: MW-7
Matrix: Aqueous
Sampled: 4/30/2024 13:45
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
1,4-Dioxane
1.763
Ng/L
0.139
2.00
1
05/02/24 16:38
TBL
8260D SIM
Antimony
<1.00
u9/L
0.618
1.00
1
05/09/24 17:08
CPW
6020B
Arsenic
<0.297
N9/L
0.297
1.00
1
05/09/24 17:08
CPW
6020B
Barium
62.7
u9/L
0.453
1.00
1
05/09/24 17:08
CPW
6020B
Beryllium
0.1093
N9/L
0.102
1.00
1
05/09/24 17:08
CPW
6020B
Cadmium
<0.350
u9/L
0.350
1.00
1
05/09/24 17:08
CPW
6020B
Chromium
2.83 B
N9/L
0.346
1.00
1
05/09/24 17:08
CPW
6020B
Cobalt
91.8
u9/L
0.060
1.00
1
05/09/24 17:08
CPW
6020B
Copper
1.13
N9/L
0.489
1.00
1
05/09/24 17:08
CPW
6020B
Lead
0.2863
u9/L
0.264
1.00
1
05/09/24 17:08
CPW
6020B
Nickel
3.55
N9/L
0.182
1.00
1
05/09/24 17:08
CPW
6020B
Selenium
1.14
u9/L
0.703
1.00
1
05/09/24 17:08
TJS
6020B
Silver
<0.0570
N9/L
0.0570
1.00
1
05/09/24 17:08
CPW
6020B
Thallium
0.2893
u9/L
0.0610
1.00
1
05/09/24 17:08
CPW
6020B
Vanadium
0.8543
N9/L
0.767
5.00
1
05/10/24 18:10
TJS
6020B
Zinc
9.87 J
u9/L
4.67
10.0
1
05/09/24 17:08
CPW
6020B
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor J Estimated value
MQL Method Quantitation Limit
Page 11 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92443
Matrix: Aqueous
Sample ID: MW-7
Sampled:
4/30/2024
13:45
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
Ng/L
1.80
5.00
1
05/07/24 16:23
ENM
V47047
Acrylonitrile
<0.230
ug/L
0.230
5.00
1
05/07/24 16:23
ENM
V47047
Benzene
<0.180
Ng/L
0.180
0.500
1
05/07/24 16:23
ENM
V47047
Bromochloromethane
<0.420
ug/L
0.420
1.00
1
05/07/24 16:23
ENM
V47047
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 16:23
ENM
V47047
Bromoform
<1.50
ug/L
1.50
5.00
1
05/07/24 16:23
ENM
V47047
Bromomethane
<0.280
Ng/L
0.280
1.00
1
05/07/24 16:23
ENM
V47047
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
05/07/24 16:23
ENM
V47047
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
05/07/24 16:23
ENM
V47047
Chlorobenzene
<0.190
ug/L
0.190
0.500
1
05/07/24 16:23
ENM
V47047
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
05/07/24 16:23
ENM
V47047
Chloroethane
<0.430
ug/L
0.430
1.00
1
05/07/24 16:23
ENM
V47047
Chloroform
<0.220
Ng/L
0.220
0.500
1
05/07/24 16:23
ENM
V47047
Chloromethane
<0.220
ug/L
0.220
0.500
1
05/07/24 16:23
ENM
V47047
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
05/07/24 16:23
ENM
V47047
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
05/07/24 16:23
ENM
V47047
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
05/07/24 16:23
ENM
V47047
Dibromomethane
<0.230
ug/L
0.230
0.500
1
05/07/24 16:23
ENM
V47047
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
05/07/24 16:23
ENM
V47047
1,2-Dichlorobenzene
<0.220
ug/L
0.220
0.500
1
05/07/24 16:23
ENM
V47047
1,4-Dichlorobenzene
<0.210
Ng/L
0.210
0.500
1
05/07/24 16:23
ENM
V47047
Dichlorodifluoromethane
<1.20
ug/L
1.20
5.00
1
05/07/24 16:23
ENM
V47047
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
J
Estimated value
MQL Method Quantitation Limit
Page 12 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92443
Matrix: Aqueous
Sample ID: MW-7
Sampled:
4/30/2024
13:45
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
05/07/24 16:23
ENM
V47047
1,2-Dichloroethane
<0.150
ug/L
0.150
0.500
1
05/07/24 16:23
ENM
V47047
1,1-Dichloroethene
<0.150
Ng/L
0.150
0.500
1
05/07/24 16:23
ENM
V47047
cis- 1,2-Dich loroethene
<0.200
ug/L
0.200
0.500
1
05/07/24 16:23
ENM
V47047
trans-1,2-Dichloroethene
<0.180
Ng/L
0.180
0.500
1
05/07/24 16:23
ENM
V47047
1,2-Dichloropropane
<0.190
ug/L
0.190
0.500
1
05/07/24 16:23
ENM
V47047
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
05/07/24 16:23
ENM
V47047
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
05/07/24 16:23
ENM
V47047
1,4-Dioxane
<16.0
Ng/L
16.0
150
1
05/07/24 16:23
ENM
V47047
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
05/07/24 16:23
ENM
V47047
2-Hexanone
<0.380
Ng/L
0.380
5.00
1
05/07/24 16:23
ENM
V47047
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
05/07/24 16:23
ENM
V47047
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
05/07/24 16:23
ENM
V47047
Methylene Chloride
<0.330
ug/L
0.330
1.00
1
05/07/24 16:23
ENM
V47047
Styrene
<0.220
Ng/L
0.220
0.500
1
05/07/24 16:23
ENM
V47047
1,1,1,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
05/07/24 16:23
ENM
V47047
1,1,2,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 16:23
ENM
V47047
Tetrachloroethene
<0.220
ug/L
0.220
0.500
1
05/07/24 16:23
ENM
V47047
Tetrahydrofuran
<1.50
Ng/L
1.50
10.0
1
05/07/24 16:23
ENM
V47047
Toluene
<0.220
ug/L
0.220
0.500
1
05/07/24 16:23
ENM
V47047
1,1,1-Trichloroethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 16:23
ENM
V47047
1,1,2-Trichloroethane
<0.096
ug/L
0.096
0.500
1
05/07/24 16:23
ENM
V47047
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
J
Estimated value
MQL
Method Quantitation Limit
Page 13 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100
Lab No : 92443
Sample ID: MW-7
REPOR T OF A NA L YSIS
Matrix: Aqueous
Sampled: 4/30/2024 13:45
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Trichloroethene
<0.180
Ng/L
0.180
0.500
1
05/07/24 16:23 ENM
V47047
Trichlorofluoromethane
<0.180
ug/L
0.180
0.500
1
05/07/24 16:23 ENM
V47047
1,2,3-Trichloropropane
<0.270
Ng/L
0.270
1.00
1
05/07/24 16:23 ENM
V47047
Vinyl Acetate
<1.00
ug/L
1.00
2.00
1
05/07/24 16:23 ENM
V47047
Vinyl Chloride
<0.170
Ng/L
0.170
0.500
1
05/07/24 16:23 ENM
V47047
o-Xylene
<0.210
ug/L
0.210
0.500
1
05/07/24 16:23 ENM
V47047
m,p-Xylene
<0.420
Ng/L
0.420
1.00
1
05/07/24 16:23 ENM
V47047
Xylene (Total)
<0.21
ug/L
0.210
0.500
1
05/07/24 16:23
V47047
Surrogate:4-Bromofluorobenzene
95.2
Limits:80-124%
1 05/07/24 16:23 ENM
V47047
Surrogate: Dibromofluoromethane
95.6
Limits:
75-129%
1 05/07/24 16:23 ENM
V47047
Surrogate: 1,2-Dichloroethane - d4
92.8
Limits:
63-136%
1 05/07/24 16:23 ENM
V47047
Surrogate: Toluene-d8
102
Limits:
77-123%
1 05/07/24 16:23 ENM
V47047
Qualifiers/ * Outside QC Limit
Definitions DF Dilution Factor
MQL Method Quantitation Limit
B Analyte detected in blank
J Estimated value
Page 14 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
WavDdibnto
ANALYTICAL
01186
Smith & Gardner, Inc.
Seth C. Rickerts
14 N. Boylan Avenue
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Project Surry County MSW
Information :
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Report Date : 05/14/2024
Received : 05/02/2024
Lab No : 92444
Sample ID: MW-6
Matrix: Aqueous
Sampled: 4/30/2024 14:00
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
1,4-Dioxane
<0.139
Ng/L
0.139
2.00
1
05/02/24 17:03
TBL
8260D SIM
Antimony
<1.00
pg/L
0.618
1.00
1
05/09/24 17:13
CPW
6020B
Arsenic
<0.297
N9/L
0.297
1.00
1
05/09/24 17:13
CPW
6020B
Barium
63.0
u9/L
0.453
1.00
1
05/09/24 17:13
CPW
6020B
Beryllium
<0.102
N9/L
0.102
1.00
1
05/09/24 17:13
CPW
6020B
Cadmium
<0.350
u9/L
0.350
1.00
1
05/09/24 17:13
CPW
6020B
Chromium
2.26 B
N9/L
0.346
1.00
1
05/09/24 17:13
CPW
6020B
Cobalt
27.2
u9/L
0.060
1.00
1
05/09/24 17:13
CPW
6020B
Copper
0.5083
N9/L
0.489
1.00
1
05/09/24 17:13
CPW
6020B
Lead
<0.264
u9/L
0.264
1.00
1
05/09/24 17:13
CPW
6020B
Nickel
2.18
N9/L
0.182
1.00
1
05/09/24 17:13
CPW
6020B
Selenium
<1.00
u9/L
0.703
1.00
1
05/09/24 17:13
TJS
6020B
Silver
<0.0570
N9/L
0.0570
1.00
1
05/09/24 17:13
CPW
6020B
Thallium
0.6103
u9/L
0.0610
1.00
1
05/09/24 17:13
CPW
6020B
Vanadium
<0.767
N9/L
0.767
5.00
1
05/10/2418:14
TJS
6020B
Zinc
14.0
u9/L
4.67
10.0
1
05/09/24 17:13
CPW
6020B
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor J Estimated value
MQL Method Quantitation Limit
Page 15 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92444
Matrix: Aqueous
Sample ID: MW-6
Sampled:
4/30/2024
14:00
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
Ng/L
1.80
5.00
1
05/07/24 16:48
ENM
V47047
Acrylonitrile
<0.230
ug/L
0.230
5.00
1
05/07/24 16:48
ENM
V47047
Benzene
<0.180
Ng/L
0.180
0.500
1
05/07/24 16:48
ENM
V47047
Bromochloromethane
<0.420
ug/L
0.420
1.00
1
05/07/24 16:48
ENM
V47047
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 16:48
ENM
V47047
Bromoform
<1.50
ug/L
1.50
5.00
1
05/07/24 16:48
ENM
V47047
Bromomethane
<0.280
Ng/L
0.280
1.00
1
05/07/24 16:48
ENM
V47047
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
05/07/24 16:48
ENM
V47047
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
05/07/24 16:48
ENM
V47047
Chlorobenzene
<0.190
ug/L
0.190
0.500
1
05/07/24 16:48
ENM
V47047
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
05/07/24 16:48
ENM
V47047
Chloroethane
<0.430
ug/L
0.430
1.00
1
05/07/24 16:48
ENM
V47047
Chloroform
<0.220
Ng/L
0.220
0.500
1
05/07/24 16:48
ENM
V47047
Chloromethane
<0.220
ug/L
0.220
0.500
1
05/07/24 16:48
ENM
V47047
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
05/07/24 16:48
ENM
V47047
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
05/07/24 16:48
ENM
V47047
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
05/07/24 16:48
ENM
V47047
Dibromomethane
<0.230
ug/L
0.230
0.500
1
05/07/24 16:48
ENM
V47047
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
05/07/24 16:48
ENM
V47047
1,2-Dichlorobenzene
<0.220
ug/L
0.220
0.500
1
05/07/24 16:48
ENM
V47047
1,4-Dichlorobenzene
<0.210
Ng/L
0.210
0.500
1
05/07/24 16:48
ENM
V47047
Dichlorodifluoromethane
<1.20
ug/L
1.20
5.00
1
05/07/24 16:48
ENM
V47047
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
J
Estimated value
MQL Method Quantitation Limit
Page 16 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92444
Matrix: Aqueous
Sample ID: MW-6
Sampled:
4/30/2024
14:00
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
05/07/24 16:48
ENM
V47047
1,2-Dichloroethane
<0.150
ug/L
0.150
0.500
1
05/07/24 16:48
ENM
V47047
1,1-Dichloroethene
<0.150
Ng/L
0.150
0.500
1
05/07/24 16:48
ENM
V47047
cis- 1,2-Dich loroethene
<0.200
ug/L
0.200
0.500
1
05/07/24 16:48
ENM
V47047
trans-1,2-Dichloroethene
<0.180
Ng/L
0.180
0.500
1
05/07/24 16:48
ENM
V47047
1,2-Dichloropropane
<0.190
ug/L
0.190
0.500
1
05/07/24 16:48
ENM
V47047
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
05/07/24 16:48
ENM
V47047
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
05/07/24 16:48
ENM
V47047
1,4-Dioxane
<16.0
Ng/L
16.0
150
1
05/07/24 16:48
ENM
V47047
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
05/07/24 16:48
ENM
V47047
2-Hexanone
<0.380
Ng/L
0.380
5.00
1
05/07/24 16:48
ENM
V47047
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
05/07/24 16:48
ENM
V47047
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
05/07/24 16:48
ENM
V47047
Methylene Chloride
<0.330
ug/L
0.330
1.00
1
05/07/24 16:48
ENM
V47047
Styrene
<0.220
Ng/L
0.220
0.500
1
05/07/24 16:48
ENM
V47047
1,1,1,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
05/07/24 16:48
ENM
V47047
1,1,2,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 16:48
ENM
V47047
Tetrachloroethene
<0.220
ug/L
0.220
0.500
1
05/07/24 16:48
ENM
V47047
Tetrahydrofuran
<1.50
Ng/L
1.50
10.0
1
05/07/24 16:48
ENM
V47047
Toluene
<0.220
ug/L
0.220
0.500
1
05/07/24 16:48
ENM
V47047
1,1,1-Trichloroethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 16:48
ENM
V47047
1,1,2-Trichloroethane
<0.096
ug/L
0.096
0.500
1
05/07/24 16:48
ENM
V47047
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
J
Estimated value
MQL
Method Quantitation Limit
Page 17 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100
Lab No : 92444
Sample ID: MW-6
REPOR T OF A NA L YSIS
Matrix: Aqueous
Sampled: 4/30/2024 14:00
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Trichloroethene
<0.180
Ng/L
0.180
0.500
1
05/07/24 16:48 ENM
V47047
Trichlorofluoromethane
<0.180
ug/L
0.180
0.500
1
05/07/24 16:48 ENM
V47047
1,2,3-Trichloropropane
<0.270
Ng/L
0.270
1.00
1
05/07/24 16:48 ENM
V47047
Vinyl Acetate
<1.00
ug/L
1.00
2.00
1
05/07/24 16:48 ENM
V47047
Vinyl Chloride
<0.170
Ng/L
0.170
0.500
1
05/07/24 16:48 ENM
V47047
o-Xylene
<0.210
ug/L
0.210
0.500
1
05/07/24 16:48 ENM
V47047
m,p-Xylene
<0.420
Ng/L
0.420
1.00
1
05/07/24 16:48 ENM
V47047
Xylene (Total)
<0.21
ug/L
0.210
0.500
1
05/07/24 16:48
V47047
Surrogate:4-Bromofluorobenzene
93.0
Limits:80-124%
1 05/07/24 16:48 ENM
V47047
Surrogate: Dibromofluoromethane
99.4
Limits:
75-129%
1 05/07/24 16:48 ENM
V47047
Surrogate: 1,2-Dichloroethane - d4
92.6
Limits:
63-136%
1 05/07/24 16:48 ENM
V47047
Surrogate: Toluene-d8
102
Limits:
77-123%
1 05/07/24 16:48 ENM
V47047
Qualifiers/ * Outside QC Limit
Definitions DF Dilution Factor
MQL Method Quantitation Limit
B Analyte detected in blank
J Estimated value
Page 18 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
WavDdibnto
ANALYTICAL
01186
Smith & Gardner, Inc.
Seth C. Rickerts
14 N. Boylan Avenue
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Project Surry County MSW
Information :
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Report Date : 05/14/2024
Received : 05/02/2024
Lab No : 92445
Sample ID: MW-12S
Matrix: Aqueous
Sampled: 4/30/2024 14:15
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
1,4-Dioxane
<0.139
Ng/L
0.139
2.00
1
05/02/24 17:28
TBL
8260D SIM
Antimony
<1.00
pg/L
0.618
1.00
1
05/09/24 17:17
CPW
6020B
Arsenic
<0.297
N9/L
0.297
1.00
1
05/09/24 17:17
CPW
6020B
Barium
19.6
u9/L
0.453
1.00
1
05/09/24 17:17
CPW
6020B
Beryllium
<0.102
N9/L
0.102
1.00
1
05/09/24 17:17
CPW
6020B
Cadmium
<0.350
u9/L
0.350
1.00
1
05/09/24 17:17
CPW
6020B
Chromium
3.11 B
N9/L
0.346
1.00
1
05/09/24 17:17
CPW
6020B
Cobalt
1.05
u9/L
0.060
1.00
1
05/09/24 17:17
CPW
6020B
Copper
1.70
N9/L
0.489
1.00
1
05/09/24 17:17
CPW
6020B
Lead
0.635 J
u9/L
0.264
1.00
1
05/09/24 17:17
CPW
6020B
Nickel
2.62
N9/L
0.182
1.00
1
05/09/24 17:17
CPW
6020B
Selenium
<1.00
u9/L
0.703
1.00
1
05/09/24 17:17
TJS
6020B
Silver
<0.0570
N9/L
0.0570
1.00
1
05/09/24 17:17
CPW
6020B
Thallium
<0.0610
u9/L
0.0610
1.00
1
05/09/24 17:17
CPW
6020B
Vanadium
2.29 J
N9/L
0.767
5.00
1
05/10/24 18:29
TJS
6020B
Zinc
6.82 J
ug/L
4.67
10.0
1
05/09/24 17:17
CPW
6020B
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor J Estimated value
MQL Method Quantitation Limit
Page 19 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92445
Matrix: Aqueous
Sample ID: MW-12S
Sampled:
4/30/2024
14:15
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
Ng/L
1.80
5.00
1
05/07/24 17:12
ENM
V47047
Acrylonitrile
<0.230
ug/L
0.230
5.00
1
05/07/24 17:12
ENM
V47047
Benzene
<0.180
Ng/L
0.180
0.500
1
05/07/24 17:12
ENM
V47047
Bromochloromethane
<0.420
ug/L
0.420
1.00
1
05/07/24 17:12
ENM
V47047
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 17:12
ENM
V47047
Bromoform
<1.50
ug/L
1.50
5.00
1
05/07/24 17:12
ENM
V47047
Bromomethane
<0.280
Ng/L
0.280
1.00
1
05/07/24 17:12
ENM
V47047
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
05/07/24 17:12
ENM
V47047
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
05/07/24 17:12
ENM
V47047
Chlorobenzene
<0.190
ug/L
0.190
0.500
1
05/07/24 17:12
ENM
V47047
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
05/07/24 17:12
ENM
V47047
Chloroethane
<0.430
ug/L
0.430
1.00
1
05/07/24 17:12
ENM
V47047
Chloroform
<0.220
Ng/L
0.220
0.500
1
05/07/24 17:12
ENM
V47047
Chloromethane
<0.220
ug/L
0.220
0.500
1
05/07/24 17:12
ENM
V47047
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
05/07/24 17:12
ENM
V47047
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
05/07/24 17:12
ENM
V47047
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
05/07/24 17:12
ENM
V47047
Dibromomethane
<0.230
ug/L
0.230
0.500
1
05/07/24 17:12
ENM
V47047
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
05/07/24 17:12
ENM
V47047
1,2-Dichlorobenzene
<0.220
ug/L
0.220
0.500
1
05/07/24 17:12
ENM
V47047
1,4-Dichlorobenzene
<0.210
Ng/L
0.210
0.500
1
05/07/24 17:12
ENM
V47047
Dichlorodifluoromethane
<1.20
ug/L
1.20
5.00
1
05/07/24 17:12
ENM
V47047
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
J
Estimated value
MQL Method Quantitation Limit
Page 20 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92445
Matrix: Aqueous
Sample ID: MW-12S
Sampled:
4/30/2024
14:15
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
05/07/24 17:12
ENM
V47047
1,2-Dichloroethane
<0.150
ug/L
0.150
0.500
1
05/07/24 17:12
ENM
V47047
1,1-Dichloroethene
<0.150
Ng/L
0.150
0.500
1
05/07/24 17:12
ENM
V47047
cis- 1,2-Dich loroethene
<0.200
ug/L
0.200
0.500
1
05/07/24 17:12
ENM
V47047
trans-1,2-Dichloroethene
<0.180
Ng/L
0.180
0.500
1
05/07/24 17:12
ENM
V47047
1,2-Dichloropropane
<0.190
ug/L
0.190
0.500
1
05/07/24 17:12
ENM
V47047
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
05/07/24 17:12
ENM
V47047
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
05/07/24 17:12
ENM
V47047
1,4-Dioxane
<16.0
Ng/L
16.0
150
1
05/07/24 17:12
ENM
V47047
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
05/07/24 17:12
ENM
V47047
2-Hexanone
<0.380
Ng/L
0.380
5.00
1
05/07/24 17:12
ENM
V47047
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
05/07/24 17:12
ENM
V47047
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
05/07/24 17:12
ENM
V47047
Methylene Chloride
<0.330
ug/L
0.330
1.00
1
05/07/24 17:12
ENM
V47047
Styrene
<0.220
Ng/L
0.220
0.500
1
05/07/24 17:12
ENM
V47047
1,1,1,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
05/07/24 17:12
ENM
V47047
1,1,2,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 17:12
ENM
V47047
Tetrachloroethene
<0.220
ug/L
0.220
0.500
1
05/07/24 17:12
ENM
V47047
Tetrahydrofuran
<1.50
Ng/L
1.50
10.0
1
05/07/24 17:12
ENM
V47047
Toluene
<0.220
ug/L
0.220
0.500
1
05/07/24 17:12
ENM
V47047
1,1,1-Trichloroethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 17:12
ENM
V47047
1,1,2-Trichloroethane
<0.096
ug/L
0.096
0.500
1
05/07/24 17:12
ENM
V47047
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
J
Estimated value
MQL
Method Quantitation Limit
Page 21 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100
Lab No : 92445
Sample ID: MW-12S
REPOR T OF A NA L YSIS
Matrix: Aqueous
Sampled: 4/30/2024 14:15
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Trichloroethene
<0.180
Ng/L
0.180
0.500
1
05/07/24 17:12 ENM
V47047
Trichlorofluoromethane
<0.180
ug/L
0.180
0.500
1
05/07/24 17:12 ENM
V47047
1,2,3-Trichloropropane
<0.270
Ng/L
0.270
1.00
1
05/07/24 17:12 ENM
V47047
Vinyl Acetate
<1.00
ug/L
1.00
2.00
1
05/07/24 17:12 ENM
V47047
Vinyl Chloride
<0.170
Ng/L
0.170
0.500
1
05/07/24 17:12 ENM
V47047
o-Xylene
<0.210
ug/L
0.210
0.500
1
05/07/24 17:12 ENM
V47047
m,p-Xylene
<0.420
Ng/L
0.420
1.00
1
05/07/24 17:12 ENM
V47047
Xylene (Total)
<0.21
ug/L
0.210
0.500
1
05/07/24 17:12
V47047
Surrogate:4-Bromofluorobenzene
92.6
Limits:80-124%
1 05/07/24 17:12 ENM
V47047
Surrogate: Dibromofluoromethane
96.8
Limits:
75-129%
1 05/07/24 17:12 ENM
V47047
Surrogate: 1,2-Dichloroethane - d4
91.8
Limits:
63-136%
1 05/07/24 17:12 ENM
V47047
Surrogate: Toluene-d8
102
Limits:
77-123%
1 05/07/24 17:12 ENM
V47047
Qualifiers/ * Outside QC Limit
Definitions DF Dilution Factor
MQL Method Quantitation Limit
B Analyte detected in blank
J Estimated value
Page 22 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
WavDdibnto
ANALYTICAL
01186
Smith & Gardner, Inc.
Seth C. Rickerts
14 N. Boylan Avenue
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Project Surry County MSW
Information :
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Report Date : 05/14/2024
Received : 05/02/2024
Lab No : 92446
Sample ID: MW-13
Matrix: Aqueous
Sampled: 4/30/2024 14:30
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
1,4-Dioxane
7.08
Ng/L
0.139
2.00
1
05/02/24 17:53
TBL
8260D SIM
Antimony
<1.00
ug/L
0.618
1.00
1
05/09/24 17:21
CPW
6020B
Arsenic
0.5823
Ng/L
0.297
1.00
1
05/09/24 17:21
CPW
6020B
Barium
173
ug/L
0.453
1.00
1
05/09/24 17:21
CPW
6020B
Beryllium
1.05
Ng/L
0.102
1.00
1
05/09/24 17:21
CPW
6020B
Cadmium
<0.350
ug/L
0.350
1.00
1
05/09/24 17:21
CPW
6020B
Chromium
12.7
Ng/L
0.346
1.00
1
05/09/24 17:21
CPW
6020B
Cobalt
22.8
ug/L
0.060
1.00
1
05/09/24 17:21
CPW
6020B
Copper
6.17
Ng/L
0.489
1.00
1
05/09/24 17:21
CPW
6020B
Lead
6.75
ug/L
0.264
1.00
1
05/09/24 17:21
CPW
6020B
Nickel
7.67
Ng/L
0.182
1.00
1
05/09/24 17:21
CPW
6020B
Selenium
1.16
ug/L
0.703
1.00
1
05/09/24 17:21
TJS
6020B
Silver
0.2293
Ng/L
0.0570
1.00
1
05/09/24 17:21
CPW
6020B
Thallium
0.2801
ug/L
0.0610
1.00
1
05/09/24 17:21
CPW
6020B
Vanadium
12.5
Ng/L
0.767
5.00
1
05/10/2418:34
TJS
6020B
Zinc
37.1
ug/L
4.67
10.0
1
05/09/24 17:21
CPW
6020B
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor J Estimated value
MQL Method Quantitation Limit
Page 23 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92446
Matrix: Aqueous
Sample ID: MW-13
Sampled:
4/30/2024
14:30
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
Ng/L
1.80
5.00
1
05/07/24 17:37
ENM
V47047
Acrylonitrile
<0.230
ug/L
0.230
5.00
1
05/07/24 17:37
ENM
V47047
Benzene
<0.180
Ng/L
0.180
0.500
1
05/07/24 17:37
ENM
V47047
Bromochloromethane
<0.420
ug/L
0.420
1.00
1
05/07/24 17:37
ENM
V47047
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 17:37
ENM
V47047
Bromoform
<1.50
ug/L
1.50
5.00
1
05/07/24 17:37
ENM
V47047
Bromomethane
<0.280
Ng/L
0.280
1.00
1
05/07/24 17:37
ENM
V47047
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
05/07/24 17:37
ENM
V47047
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
05/07/24 17:37
ENM
V47047
Chlorobenzene
<0.190
ug/L
0.190
0.500
1
05/07/24 17:37
ENM
V47047
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
05/07/24 17:37
ENM
V47047
Chloroethane
<0.430
ug/L
0.430
1.00
1
05/07/24 17:37
ENM
V47047
Chloroform
<0.220
Ng/L
0.220
0.500
1
05/07/24 17:37
ENM
V47047
Chloromethane
<0.220
ug/L
0.220
0.500
1
05/07/24 17:37
ENM
V47047
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
05/07/24 17:37
ENM
V47047
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
05/07/24 17:37
ENM
V47047
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
05/07/24 17:37
ENM
V47047
Dibromomethane
<0.230
ug/L
0.230
0.500
1
05/07/24 17:37
ENM
V47047
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
05/07/24 17:37
ENM
V47047
1,2-Dichlorobenzene
<0.220
ug/L
0.220
0.500
1
05/07/24 17:37
ENM
V47047
1,4-Dichlorobenzene
<0.210
Ng/L
0.210
0.500
1
05/07/24 17:37
ENM
V47047
Dichlorodifluoromethane
<1.20
ug/L
1.20
5.00
1
05/07/24 17:37
ENM
V47047
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
J
Estimated value
MQL Method Quantitation Limit
Page 24 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92446
Matrix: Aqueous
Sample ID: MW-13
Sampled:
4/30/2024
14:30
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
0.4983
Ng/L
0.240
0.500
1
05/07/24 17:37
ENM
V47047
1,2-Dichloroethane
<0.150
ug/L
0.150
0.500
1
05/07/24 17:37
ENM
V47047
1,1-Dichloroethene
<0.150
Ng/L
0.150
0.500
1
05/07/24 17:37
ENM
V47047
cis- 1,2-Dich loroethene
7.40
ug/L
0.200
0.500
1
05/07/24 17:37
ENM
V47047
trans-1,2-Dichloroethene
<0.180
Ng/L
0.180
0.500
1
05/07/24 17:37
ENM
V47047
1,2-Dichloropropane
<0.190
ug/L
0.190
0.500
1
05/07/24 17:37
ENM
V47047
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
05/07/24 17:37
ENM
V47047
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
05/07/24 17:37
ENM
V47047
1,4-Dioxane
<16.0
Ng/L
16.0
150
1
05/07/24 17:37
ENM
V47047
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
05/07/24 17:37
ENM
V47047
2-Hexanone
<0.380
Ng/L
0.380
5.00
1
05/07/24 17:37
ENM
V47047
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
05/07/24 17:37
ENM
V47047
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
05/07/24 17:37
ENM
V47047
Methylene Chloride
<0.330
ug/L
0.330
1.00
1
05/07/24 17:37
ENM
V47047
Styrene
<0.220
Ng/L
0.220
0.500
1
05/07/24 17:37
ENM
V47047
1,1,1,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
05/07/24 17:37
ENM
V47047
1,1,2,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 17:37
ENM
V47047
Tetrachloroethene
<0.220
ug/L
0.220
0.500
1
05/07/24 17:37
ENM
V47047
Tetrahydrofuran
<1.50
Ng/L
1.50
10.0
1
05/07/24 17:37
ENM
V47047
Toluene
<0.220
ug/L
0.220
0.500
1
05/07/24 17:37
ENM
V47047
1,1,1-Trichloroethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 17:37
ENM
V47047
1,1,2-Trichloroethane
<0.096
ug/L
0.096
0.500
1
05/07/24 17:37
ENM
V47047
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
J
Estimated value
MQL
Method Quantitation Limit
Page 25 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100
Lab No : 92446
Sample ID: MW-13
REPOR T OF A NA L YSIS
Matrix: Aqueous
Sampled: 4/30/2024 14:30
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Trichloroethene
<0.180
Ng/L
0.180
0.500
1
05/07/24 17:37 ENM
V47047
Trichlorofluoromethane
<0.180
ug/L
0.180
0.500
1
05/07/24 17:37 ENM
V47047
1,2,3-Trichloropropane
<0.270
Ng/L
0.270
1.00
1
05/07/24 17:37 ENM
V47047
Vinyl Acetate
<1.00
ug/L
1.00
2.00
1
05/07/24 17:37 ENM
V47047
Vinyl Chloride
<0.170
Ng/L
0.170
0.500
1
05/07/24 17:37 ENM
V47047
o-Xylene
<0.210
ug/L
0.210
0.500
1
05/07/24 17:37 ENM
V47047
m,p-Xylene
<0.420
Ng/L
0.420
1.00
1
05/07/24 17:37 ENM
V47047
Xylene (Total)
<0.21
ug/L
0.210
0.500
1
05/07/24 17:37
V47047
Surrogate:4-Bromofluorobenzene
93.4
Limits:80-124%
1 05/07/24 17:37 ENM
V47047
Surrogate: Dibromofluoromethane
98.2
Limits:
75-129%
1 05/07/24 17:37 ENM
V47047
Surrogate: 1,2-Dichloroethane - d4
92.2
Limits:
63-136%
1 05/07/24 17:37 ENM
V47047
Surrogate: Toluene-d8
102
Limits:
77-123%
1 05/07/24 17:37 ENM
V47047
Qualifiers/ * Outside QC Limit
Definitions DF Dilution Factor
MQL Method Quantitation Limit
B Analyte detected in blank
J Estimated value
Page 26 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
WavDdibnto
ANALYTICAL
01186
Smith & Gardner, Inc.
Seth C. Rickerts
14 N. Boylan Avenue
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Project Surry County MSW
Information :
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Report Date : 05/14/2024
Received : 05/02/2024
Lab No : 92447
Sample ID: MW-23
Matrix: Aqueous
Sampled: 4/30/2024 14:45
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
1,4-Dioxane
<0.139
Ng/L
0.139
2.00
1
05/02/24 18:18
TBL
8260D SIM
Antimony
<1.00
pg/L
0.618
1.00
1
05/09/24 17:26
CPW
6020B
Arsenic
<0.297
N9/L
0.297
1.00
1
05/09/24 17:26
CPW
6020B
Barium
181
u9/L
0.453
1.00
1
05/09/24 17:26
CPW
6020B
Beryllium
0.7843
N9/L
0.102
1.00
1
05/09/24 17:26
CPW
6020B
Cadmium
<0.350
u9/L
0.350
1.00
1
05/09/24 17:26
CPW
6020B
Chromium
14.4
N9/L
0.346
1.00
1
05/09/24 17:26
CPW
6020B
Cobalt
4.35
u9/L
0.060
1.00
1
05/09/24 17:26
CPW
6020B
Copper
4.47
N9/L
0.489
1.00
1
05/09/24 17:26
CPW
6020B
Lead
6.19
u9/L
0.264
1.00
1
05/09/24 17:26
CPW
6020B
Nickel
6.16
N9/L
0.182
1.00
1
05/09/24 17:26
CPW
6020B
Selenium
1.37
u9/L
0.703
1.00
1
05/09/24 17:26
TJS
6020B
Silver
<0.0570
N9/L
0.0570
1.00
1
05/09/24 17:26
CPW
6020B
Thallium
0.1171
u9/L
0.0610
1.00
1
05/09/24 17:26
CPW
6020B
Vanadium
19.4
N9/L
0.767
5.00
1
05/10/2418:38
TJS
6020B
Zinc
26.9
u9/L
4.67
10.0
1
05/09/24 17:26
CPW
6020B
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor J Estimated value
MQL Method Quantitation Limit
Page 27 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92447
Matrix: Aqueous
Sample ID: MW-23
Sampled:
4/30/2024
14:45
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
Ng/L
1.80
5.00
1
05/07/24 18:01
ENM
V47047
Acrylonitrile
<0.230
ug/L
0.230
5.00
1
05/07/24 18:01
ENM
V47047
Benzene
<0.180
Ng/L
0.180
0.500
1
05/07/24 18:01
ENM
V47047
Bromochloromethane
<0.420
ug/L
0.420
1.00
1
05/07/24 18:01
ENM
V47047
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 18:01
ENM
V47047
Bromoform
<1.50
ug/L
1.50
5.00
1
05/07/24 18:01
ENM
V47047
Bromomethane
<0.280
Ng/L
0.280
1.00
1
05/07/24 18:01
ENM
V47047
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
05/07/24 18:01
ENM
V47047
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
05/07/24 18:01
ENM
V47047
Chlorobenzene
<0.190
ug/L
0.190
0.500
1
05/07/24 18:01
ENM
V47047
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
05/07/24 18:01
ENM
V47047
Chloroethane
<0.430
ug/L
0.430
1.00
1
05/07/24 18:01
ENM
V47047
Chloroform
<0.220
Ng/L
0.220
0.500
1
05/07/24 18:01
ENM
V47047
Chloromethane
<0.220
ug/L
0.220
0.500
1
05/07/24 18:01
ENM
V47047
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
05/07/24 18:01
ENM
V47047
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
05/07/24 18:01
ENM
V47047
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
05/07/24 18:01
ENM
V47047
Dibromomethane
<0.230
ug/L
0.230
0.500
1
05/07/24 18:01
ENM
V47047
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
05/07/24 18:01
ENM
V47047
1,2-Dichlorobenzene
<0.220
ug/L
0.220
0.500
1
05/07/24 18:01
ENM
V47047
1,4-Dichlorobenzene
<0.210
Ng/L
0.210
0.500
1
05/07/24 18:01
ENM
V47047
Dichlorodifluoromethane
<1.20
ug/L
1.20
5.00
1
05/07/24 18:01
ENM
V47047
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
J
Estimated value
MQL Method Quantitation Limit
Page 28 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92447
Matrix: Aqueous
Sample ID: MW-23
Sampled:
4/30/2024
14:45
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
05/07/24 18:01
ENM
V47047
1,2-Dichloroethane
<0.150
ug/L
0.150
0.500
1
05/07/24 18:01
ENM
V47047
1,1-Dichloroethene
<0.150
Ng/L
0.150
0.500
1
05/07/24 18:01
ENM
V47047
cis- 1,2-Dich loroethene
<0.200
ug/L
0.200
0.500
1
05/07/24 18:01
ENM
V47047
trans-1,2-Dichloroethene
<0.180
Ng/L
0.180
0.500
1
05/07/24 18:01
ENM
V47047
1,2-Dichloropropane
<0.190
ug/L
0.190
0.500
1
05/07/24 18:01
ENM
V47047
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
05/07/24 18:01
ENM
V47047
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
05/07/24 18:01
ENM
V47047
1,4-Dioxane
<16.0
Ng/L
16.0
150
1
05/07/24 18:01
ENM
V47047
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
05/07/24 18:01
ENM
V47047
2-Hexanone
<0.380
Ng/L
0.380
5.00
1
05/07/24 18:01
ENM
V47047
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
05/07/24 18:01
ENM
V47047
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
05/07/24 18:01
ENM
V47047
Methylene Chloride
<0.330
ug/L
0.330
1.00
1
05/07/24 18:01
ENM
V47047
Styrene
<0.220
Ng/L
0.220
0.500
1
05/07/24 18:01
ENM
V47047
1,1,1,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
05/07/24 18:01
ENM
V47047
1,1,2,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 18:01
ENM
V47047
Tetrachloroethene
<0.220
ug/L
0.220
0.500
1
05/07/24 18:01
ENM
V47047
Tetrahydrofuran
<1.50
Ng/L
1.50
10.0
1
05/07/24 18:01
ENM
V47047
Toluene
<0.220
ug/L
0.220
0.500
1
05/07/24 18:01
ENM
V47047
1,1,1-Trichloroethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 18:01
ENM
V47047
1,1,2-Trichloroethane
<0.096
ug/L
0.096
0.500
1
05/07/24 18:01
ENM
V47047
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
J
Estimated value
MQL
Method Quantitation Limit
Page 29 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100
Lab No : 92447
Sample ID: MW-23
REPOR T OF A NA L YSIS
Matrix: Aqueous
Sampled: 4/30/2024 14:45
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Trichloroethene
<0.180
Ng/L
0.180
0.500
1
05/07/24 18:01 ENM
V47047
Trichlorofluoromethane
<0.180
ug/L
0.180
0.500
1
05/07/24 18:01 ENM
V47047
1,2,3-Trichloropropane
<0.270
Ng/L
0.270
1.00
1
05/07/24 18:01 ENM
V47047
Vinyl Acetate
<1.00
ug/L
1.00
2.00
1
05/07/24 18:01 ENM
V47047
Vinyl Chloride
<0.170
Ng/L
0.170
0.500
1
05/07/24 18:01 ENM
V47047
o-Xylene
<0.210
ug/L
0.210
0.500
1
05/07/24 18:01 ENM
V47047
m,p-Xylene
<0.420
Ng/L
0.420
1.00
1
05/07/24 18:01 ENM
V47047
Xylene (Total)
<0.21
ug/L
0.210
0.500
1
05/07/24 18:01
V47047
Surrogate:4-Bromofluorobenzene
94.0
Limits:80-124%
1 05/07/24 18:01 ENM
V47047
Surrogate: Dibromofluoromethane
97.6
Limits:
75-129%
1 05/07/24 18:01 ENM
V47047
Surrogate: 1,2-Dichloroethane - d4
92.8
Limits:
63-136%
1 05/07/24 18:01 ENM
V47047
Surrogate: Toluene-d8
103
Limits:
77-123%
1 05/07/24 18:01 ENM
V47047
Qualifiers/ * Outside QC Limit
Definitions DF Dilution Factor
MQL Method Quantitation Limit
B Analyte detected in blank
J Estimated value
Page 30 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
WavDdibnto
ANALYTICAL
01186
Smith & Gardner, Inc.
Seth C. Rickerts
14 N. Boylan Avenue
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Project Surry County MSW
Information :
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Report Date : 05/14/2024
Received : 05/02/2024
Lab No : 92448
Sample ID: MW-19
Matrix: Aqueous
Sampled: 4/30/2024 15:00
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
1,4-Dioxane
<0.139
Ng/L
0.139
2.00
1
05/02/24 18:44
TBL
8260D SIM
Antimony
<1.00
pg/L
0.618
1.00
1
05/09/24 17:30
CPW
6020B
Arsenic
0.7553
N9/L
0.297
1.00
1
05/09/24 17:30
CPW
6020B
Barium
276
u9/L
0.453
1.00
1
05/09/24 17:30
CPW
6020B
Beryllium
2.37
N9/L
0.102
1.00
1
05/09/24 17:30
CPW
6020B
Cadmium
<0.350
u9/L
0.350
1.00
1
05/09/24 17:30
CPW
6020B
Chromium
45.0
N9/L
0.346
1.00
1
05/09/24 17:30
CPW
6020B
Cobalt
15.4
u9/L
0.060
1.00
1
05/09/24 17:30
CPW
6020B
Copper
24.3
N9/L
0.489
1.00
1
05/09/24 17:30
CPW
6020B
Lead
10.6
u9/L
0.264
1.00
1
05/09/24 17:30
CPW
6020B
Nickel
15.7
N9/L
0.182
1.00
1
05/09/24 17:30
CPW
6020B
Selenium
1.71
u9/L
0.703
1.00
1
05/09/24 17:30
TJS
6020B
Silver
0.08903
N9/L
0.0570
1.00
1
05/09/24 17:30
CPW
6020B
Thallium
0.5721
u9/L
0.0610
1.00
1
05/09/24 17:30
CPW
6020B
Vanadium
55.9
N9/L
0.767
5.00
1
05/10/2418:43
TJS
6020B
Zinc
95.4
u9/L
4.67
10.0
1
05/09/24 17:30
CPW
6020B
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor J Estimated value
MQL Method Quantitation Limit
Page 31 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92448
Matrix: Aqueous
Sample ID: MW-19
Sampled:
4/30/2024
15:00
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
Ng/L
1.80
5.00
1
05/07/24 18:26
ENM
V47047
Acrylonitrile
<0.230
ug/L
0.230
5.00
1
05/07/24 18:26
ENM
V47047
Benzene
<0.180
Ng/L
0.180
0.500
1
05/07/24 18:26
ENM
V47047
Bromochloromethane
<0.420
ug/L
0.420
1.00
1
05/07/24 18:26
ENM
V47047
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 18:26
ENM
V47047
Bromoform
<1.50
ug/L
1.50
5.00
1
05/07/24 18:26
ENM
V47047
Bromomethane
<0.280
Ng/L
0.280
1.00
1
05/07/24 18:26
ENM
V47047
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
05/07/24 18:26
ENM
V47047
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
05/07/24 18:26
ENM
V47047
Chlorobenzene
<0.190
ug/L
0.190
0.500
1
05/07/24 18:26
ENM
V47047
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
05/07/24 18:26
ENM
V47047
Chloroethane
<0.430
ug/L
0.430
1.00
1
05/07/24 18:26
ENM
V47047
Chloroform
<0.220
Ng/L
0.220
0.500
1
05/07/24 18:26
ENM
V47047
Chloromethane
<0.220
ug/L
0.220
0.500
1
05/07/24 18:26
ENM
V47047
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
05/07/24 18:26
ENM
V47047
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
05/07/24 18:26
ENM
V47047
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
05/07/24 18:26
ENM
V47047
Dibromomethane
<0.230
ug/L
0.230
0.500
1
05/07/24 18:26
ENM
V47047
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
05/07/24 18:26
ENM
V47047
1,2-Dichlorobenzene
<0.220
ug/L
0.220
0.500
1
05/07/24 18:26
ENM
V47047
1,4-Dichlorobenzene
<0.210
Ng/L
0.210
0.500
1
05/07/24 18:26
ENM
V47047
Dichlorodifluoromethane
<1.20
ug/L
1.20
5.00
1
05/07/24 18:26
ENM
V47047
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
J
Estimated value
MQL Method Quantitation Limit
Page 32 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92448
Matrix: Aqueous
Sample ID: MW-19
Sampled:
4/30/2024
15:00
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
0.3533
Ng/L
0.240
0.500
1
05/07/24 18:26
ENM
V47047
1,2-Dichloroethane
<0.150
ug/L
0.150
0.500
1
05/07/24 18:26
ENM
V47047
1,1-Dichloroethene
<0.150
Ng/L
0.150
0.500
1
05/07/24 18:26
ENM
V47047
cis- 1,2-Dich loroethene
0.838
ug/L
0.200
0.500
1
05/07/24 18:26
ENM
V47047
trans-1,2-Dichloroethene
<0.180
Ng/L
0.180
0.500
1
05/07/24 18:26
ENM
V47047
1,2-Dichloropropane
<0.190
ug/L
0.190
0.500
1
05/07/24 18:26
ENM
V47047
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
05/07/24 18:26
ENM
V47047
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
05/07/24 18:26
ENM
V47047
1,4-Dioxane
<16.0
Ng/L
16.0
150
1
05/07/24 18:26
ENM
V47047
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
05/07/24 18:26
ENM
V47047
2-Hexanone
<0.380
Ng/L
0.380
5.00
1
05/07/24 18:26
ENM
V47047
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
05/07/24 18:26
ENM
V47047
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
05/07/24 18:26
ENM
V47047
Methylene Chloride
<0.330
ug/L
0.330
1.00
1
05/07/24 18:26
ENM
V47047
Styrene
<0.220
Ng/L
0.220
0.500
1
05/07/24 18:26
ENM
V47047
1,1,1,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
05/07/24 18:26
ENM
V47047
1,1,2,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 18:26
ENM
V47047
Tetrachloroethene
<0.220
ug/L
0.220
0.500
1
05/07/24 18:26
ENM
V47047
Tetrahydrofuran
<1.50
Ng/L
1.50
10.0
1
05/07/24 18:26
ENM
V47047
Toluene
<0.220
ug/L
0.220
0.500
1
05/07/24 18:26
ENM
V47047
1,1,1-Trichloroethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 18:26
ENM
V47047
1,1,2-Trichloroethane
<0.096
ug/L
0.096
0.500
1
05/07/24 18:26
ENM
V47047
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
J
Estimated value
MQL
Method Quantitation Limit
Page 33 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100
Lab No : 92448
Sample ID: MW-19
REPOR T OF A NA L YSIS
Matrix: Aqueous
Sampled: 4/30/2024 15:00
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Trichloroethene
<0.180
Ng/L
0.180
0.500
1
05/07/24 18:26 ENM
V47047
Trichlorofluoromethane
<0.180
ug/L
0.180
0.500
1
05/07/24 18:26 ENM
V47047
1,2,3-Trichloropropane
<0.270
Ng/L
0.270
1.00
1
05/07/24 18:26 ENM
V47047
Vinyl Acetate
<1.00
ug/L
1.00
2.00
1
05/07/24 18:26 ENM
V47047
Vinyl Chloride
<0.170
Ng/L
0.170
0.500
1
05/07/24 18:26 ENM
V47047
o-Xylene
<0.210
ug/L
0.210
0.500
1
05/07/24 18:26 ENM
V47047
m,p-Xylene
<0.420
Ng/L
0.420
1.00
1
05/07/24 18:26 ENM
V47047
Xylene (Total)
<0.21
ug/L
0.210
0.500
1
05/07/24 18:26
V47047
Surrogate:4-Bromofluorobenzene
93.8
Limits:80-124%
1 05/07/24 18:26 ENM
V47047
Surrogate: Dibromofluoromethane
98.8
Limits:
75-129%
1 05/07/24 18:26 ENM
V47047
Surrogate: 1,2-Dichloroethane - d4
88.8
Limits:
63-136%
1 05/07/24 18:26 ENM
V47047
Surrogate: Toluene-d8
103
Limits:
77-123%
1 05/07/24 18:26 ENM
V47047
Qualifiers/ * Outside QC Limit
Definitions DF Dilution Factor
MQL Method Quantitation Limit
B Analyte detected in blank
J Estimated value
Page 34 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
WavDdibnto
ANALYTICAL
01186
Smith & Gardner, Inc.
Seth C. Rickerts
14 N. Boylan Avenue
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Project Surry County MSW
Information :
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Report Date : 05/14/2024
Received : 05/02/2024
Lab No : 92449
Sample ID: MW-22
Matrix: Aqueous
Sampled: 4/30/2024 15:15
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
1,4-Dioxane
<0.139
Ng/L
0.139
2.00
1
05/02/24 19:09
TBL
8260D SIM
Antimony
<1.00
pg/L
0.618
1.00
1
05/09/24 17:36
CPW
6020B
Arsenic
<0.297
N9/L
0.297
1.00
1
05/09/24 17:36
CPW
6020B
Barium
41.9
u9/L
0.453
1.00
1
05/09/24 17:36
CPW
6020B
Beryllium
<0.102
N9/L
0.102
1.00
1
05/09/24 17:36
CPW
6020B
Cadmium
<0.350
u9/L
0.350
1.00
1
05/09/24 17:36
CPW
6020B
Chromium
2.51 B
N9/L
0.346
1.00
1
05/09/24 17:36
CPW
6020B
Cobalt
3.55
u9/L
0.060
1.00
1
05/09/24 17:36
CPW
6020B
Copper
2.14
N9/L
0.489
1.00
1
05/09/24 17:36
CPW
6020B
Lead
<0.264
u9/L
0.264
1.00
1
05/09/24 17:36
CPW
6020B
Nickel
1.62
N9/L
0.182
1.00
1
05/09/24 17:36
CPW
6020B
Selenium
1.12
u9/L
0.703
1.00
1
05/09/24 17:36
TJS
6020B
Silver
<0.0570
N9/L
0.0570
1.00
1
05/09/24 17:36
CPW
6020B
Thallium
0.09993
u9/L
0.0610
1.00
1
05/09/24 17:36
CPW
6020B
Vanadium
<0.767
N9/L
0.767
5.00
1
05/10/2418:48
TJS
6020B
Zinc
6.36 J
u9/L
4.67
10.0
1
05/09/24 17:36
CPW
6020B
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor J Estimated value
MQL Method Quantitation Limit
Page 35 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92449
Matrix: Aqueous
Sample ID: MW-22
Sampled:
4/30/2024
15:15
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
Ng/L
1.80
5.00
1
05/07/24 18:51
ENM
V47047
Acrylonitrile
<0.230
ug/L
0.230
5.00
1
05/07/24 18:51
ENM
V47047
Benzene
<0.180
Ng/L
0.180
0.500
1
05/07/24 18:51
ENM
V47047
Bromochloromethane
<0.420
ug/L
0.420
1.00
1
05/07/24 18:51
ENM
V47047
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 18:51
ENM
V47047
Bromoform
<1.50
ug/L
1.50
5.00
1
05/07/24 18:51
ENM
V47047
Bromomethane
<0.280
Ng/L
0.280
1.00
1
05/07/24 18:51
ENM
V47047
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
05/07/24 18:51
ENM
V47047
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
05/07/24 18:51
ENM
V47047
Chlorobenzene
<0.190
ug/L
0.190
0.500
1
05/07/24 18:51
ENM
V47047
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
05/07/24 18:51
ENM
V47047
Chloroethane
<0.430
ug/L
0.430
1.00
1
05/07/24 18:51
ENM
V47047
Chloroform
<0.220
Ng/L
0.220
0.500
1
05/07/24 18:51
ENM
V47047
Chloromethane
<0.220
ug/L
0.220
0.500
1
05/07/24 18:51
ENM
V47047
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
05/07/24 18:51
ENM
V47047
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
05/07/24 18:51
ENM
V47047
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
05/07/24 18:51
ENM
V47047
Dibromomethane
<0.230
ug/L
0.230
0.500
1
05/07/24 18:51
ENM
V47047
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
05/07/24 18:51
ENM
V47047
1,2-Dichlorobenzene
<0.220
ug/L
0.220
0.500
1
05/07/24 18:51
ENM
V47047
1,4-Dichlorobenzene
<0.210
Ng/L
0.210
0.500
1
05/07/24 18:51
ENM
V47047
Dichlorodifluoromethane
<1.20
ug/L
1.20
5.00
1
05/07/24 18:51
ENM
V47047
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
J
Estimated value
MQL Method Quantitation Limit
Page 36 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92449
Matrix: Aqueous
Sample ID: MW-22
Sampled:
4/30/2024
15:15
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
05/07/24 18:51
ENM
V47047
1,2-Dichloroethane
<0.150
ug/L
0.150
0.500
1
05/07/24 18:51
ENM
V47047
1,1-Dichloroethene
<0.150
Ng/L
0.150
0.500
1
05/07/24 18:51
ENM
V47047
cis- 1,2-Dich loroethene
<0.200
ug/L
0.200
0.500
1
05/07/24 18:51
ENM
V47047
trans-1,2-Dichloroethene
<0.180
Ng/L
0.180
0.500
1
05/07/24 18:51
ENM
V47047
1,2-Dichloropropane
<0.190
ug/L
0.190
0.500
1
05/07/24 18:51
ENM
V47047
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
05/07/24 18:51
ENM
V47047
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
05/07/24 18:51
ENM
V47047
1,4-Dioxane
<16.0
Ng/L
16.0
150
1
05/07/24 18:51
ENM
V47047
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
05/07/24 18:51
ENM
V47047
2-Hexanone
<0.380
Ng/L
0.380
5.00
1
05/07/24 18:51
ENM
V47047
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
05/07/24 18:51
ENM
V47047
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
05/07/24 18:51
ENM
V47047
Methylene Chloride
<0.330
ug/L
0.330
1.00
1
05/07/24 18:51
ENM
V47047
Styrene
<0.220
Ng/L
0.220
0.500
1
05/07/24 18:51
ENM
V47047
1,1,1,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
05/07/24 18:51
ENM
V47047
1,1,2,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 18:51
ENM
V47047
Tetrachloroethene
<0.220
ug/L
0.220
0.500
1
05/07/24 18:51
ENM
V47047
Tetrahydrofuran
<1.50
Ng/L
1.50
10.0
1
05/07/24 18:51
ENM
V47047
Toluene
<0.220
ug/L
0.220
0.500
1
05/07/24 18:51
ENM
V47047
1,1,1-Trichloroethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 18:51
ENM
V47047
1,1,2-Trichloroethane
<0.096
ug/L
0.096
0.500
1
05/07/24 18:51
ENM
V47047
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
J
Estimated value
MQL
Method Quantitation Limit
Page 37 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100
Lab No : 92449
Sample ID: MW-22
REPOR T OF A NA L YSIS
Matrix: Aqueous
Sampled: 4/30/2024 15:15
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Trichloroethene
<0.180
Ng/L
0.180
0.500
1
05/07/24 18:51 ENM
V47047
Trichlorofluoromethane
<0.180
ug/L
0.180
0.500
1
05/07/24 18:51 ENM
V47047
1,2,3-Trichloropropane
<0.270
Ng/L
0.270
1.00
1
05/07/24 18:51 ENM
V47047
Vinyl Acetate
<1.00
ug/L
1.00
2.00
1
05/07/24 18:51 ENM
V47047
Vinyl Chloride
<0.170
Ng/L
0.170
0.500
1
05/07/24 18:51 ENM
V47047
o-Xylene
<0.210
ug/L
0.210
0.500
1
05/07/24 18:51 ENM
V47047
m,p-Xylene
<0.420
Ng/L
0.420
1.00
1
05/07/24 18:51 ENM
V47047
Xylene (Total)
<0.21
ug/L
0.210
0.500
1
05/07/24 18:51
V47047
Surrogate:4-Bromofluorobenzene
96.4
Limits:80-124%
1 05/07/24 18:51 ENM
V47047
Surrogate: Dibromofluoromethane
98.6
Limits:
75-129%
1 05/07/24 18:51 ENM
V47047
Surrogate: 1,2-Dichloroethane - d4
91.0
Limits:
63-136%
1 05/07/24 18:51 ENM
V47047
Surrogate: Toluene-d8
102
Limits:
77-123%
1 05/07/24 18:51 ENM
V47047
Qualifiers/ * Outside QC Limit
Definitions DF Dilution Factor
MQL Method Quantitation Limit
B Analyte detected in blank
J Estimated value
Page 38 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
WavDdibnto
ANALYTICAL
01186
Smith & Gardner, Inc.
Seth C. Rickerts
14 N. Boylan Avenue
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Project Surry County MSW
Information :
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Report Date : 05/14/2024
Received : 05/02/2024
Lab No : 92450
Sample ID: MW-17
Matrix: Aqueous
Sampled: 4/30/2024 15:30
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
1,4-Dioxane
8.19
Ng/L
0.139
2.00
1
05/02/24 19:34
TBL
8260D SIM
Antimony
<1.00
u9/L
0.618
1.00
1
05/09/24 17:50
CPW
6020B
Arsenic
0.4023
N9/L
0.297
1.00
1
05/09/24 17:50
CPW
6020B
Barium
45.1
u9/L
0.453
1.00
1
05/10/2418:52
CPW
6020B
Beryllium
0.6893
N9/L
0.102
1.00
1
05/09/24 17:50
CPW
6020B
Cadmium
1.48
u9/L
0.350
1.00
1
05/09/24 17:50
CPW
6020B
Chromium
7.99 B
N9/L
0.346
1.00
1
05/09/24 17:50
CPW
6020B
Cobalt
17.8
u9/L
0.060
1.00
1
05/09/24 17:50
CPW
6020B
Copper
3.91
N9/L
0.489
1.00
1
05/09/24 17:50
CPW
6020B
Lead
1.73
u9/L
0.264
1.00
1
05/09/24 17:50
CPW
6020B
Nickel
6.82
N9/L
0.182
1.00
1
05/09/24 17:50
CPW
6020B
Selenium
1.11
u9/L
0.703
1.00
1
05/10/2418:52
CPW
6020B
Silver
<0.0570
N9/L
0.0570
1.00
1
05/09/24 17:50
CPW
6020B
Thallium
0.09081
u9/L
0.0610
1.00
1
05/09/24 17:50
CPW
6020B
Vanadium
6.92
N9/L
0.767
5.00
1
05/10/2418:52
TJS
6020B
Zinc
17.6
u9/L
4.67
10.0
1
05/09/24 17:50
CPW
6020B
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor J Estimated value
MQL Method Quantitation Limit
Page 39 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92450
Matrix: Aqueous
Sample ID: MW-17
Sampled:
4/30/2024
15:30
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
N9/L
1.80
5.00
1
05/07/24 19:15
ENM
V47047
Acrylonitrile
<0.230
u9/L
0.230
5.00
1
05/07/24 19:15
ENM
V47047
Benzene
<0.180
N9/L
0.180
0.500
1
05/07/24 19:15
ENM
V47047
Bromochloromethane
<0.420
u9/L
0.420
1.00
1
05/07/24 19:15
ENM
V47047
Bromodichloromethane
<0.160
N9/L
0.160
0.500
1
05/07/24 19:15
ENM
V47047
Bromoform
<1.50
u9/L
1.50
5.00
1
05/07/24 19:15
ENM
V47047
Bromomethane
<0.280
N9/L
0.280
1.00
1
05/07/24 19:15
ENM
V47047
Carbon Disulfide
<0.150
u9/L
0.150
5.00
1
05/07/24 19:15
ENM
V47047
Carbon Tetrachloride
<0.180
N9/L
0.180
0.500
1
05/07/24 19:15
ENM
V47047
Chlorobenzene
<0.190
u9/L
0.190
0.500
1
05/07/24 19:15
ENM
V47047
Chlorodibromomethane
<0.190
N9/L
0.190
0.500
1
05/07/24 19:15
ENM
V47047
Chloroethane
<0.430
u9/L
0.430
1.00
1
05/07/24 19:15
ENM
V47047
Chloroform
<0.220
N9/L
0.220
0.500
1
05/07/24 19:15
ENM
V47047
Chloromethane
<0.220
u9/L
0.220
0.500
1
05/07/24 19:15
ENM
V47047
Di -Isopropyl Ether (DIPE)
<0.960
N9/L
0.960
5.00
1
05/07/24 19:15
ENM
V47047
1,2-Dibromo-3-Chloropropane
<1.10
u9/L
1.10
2.00
1
05/07/24 19:15
ENM
V47047
1,2-Dibromoethane
<0.200
N9/L
0.200
0.500
1
05/07/24 19:15
ENM
V47047
Dibromomethane
<0.230
u9/L
0.230
0.500
1
05/07/24 19:15
ENM
V47047
trans-1,4-Dichloro-2-butene
<1.30
N9/L
1.30
10.0
1
05/07/24 19:15
ENM
V47047
1,2-Dichlorobenzene
<0.220
u9/L
0.220
0.500
1
05/07/24 19:15
ENM
V47047
1,4-Dichlorobenzene
<0.210
N9/L
0.210
0.500
1
05/07/24 19:15
ENM
V47047
Dichlorodifluoromethane
<1.20
u9/L
1.20
5.00
1
05/07/24 19:15
ENM
V47047
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
J
Estimated value
MQL Method Quantitation Limit
Page 40 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92450
Matrix: Aqueous
Sample ID: MW-17
Sampled:
4/30/2024
15:30
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
05/07/24 19:15
ENM
V47047
1,2-Dichloroethane
<0.150
u9/L
0.150
0.500
1
05/07/24 19:15
ENM
V47047
1,1-Dichloroethene
<0.150
N9/L
0.150
0.500
1
05/07/24 19:15
ENM
V47047
cis- 1,2-Dich loroethene
<0.200
u9/L
0.200
0.500
1
05/07/24 19:15
ENM
V47047
trans-1,2-Dichloroethene
<0.180
N9/L
0.180
0.500
1
05/07/24 19:15
ENM
V47047
1,2-Dichloropropane
<0.190
u9/L
0.190
0.500
1
05/07/24 19:15
ENM
V47047
cis- 1,3-Dich loropropene
<0.210
N9/L
0.210
0.500
1
05/07/24 19:15
ENM
V47047
trans-1,3-Dichloropropene
<0.150
u9/L
0.150
0.500
1
05/07/24 19:15
ENM
V47047
1,4-Dioxane
<16.0
N9/L
16.0
150
1
05/07/24 19:15
ENM
V47047
Ethylbenzene
<0.170
u9/L
0.170
0.500
1
05/07/24 19:15
ENM
V47047
2-Hexanone
<0.380
N9/L
0.380
5.00
1
05/07/24 19:15
ENM
V47047
Methyl Ethyl Ketone (MEK)
<0.710
u9/L
0.710
5.00
1
05/07/24 19:15
ENM
V47047
4-Methyl-2-Pentanone
<1.00
N9/L
1.00
5.00
1
05/07/24 19:15
ENM
V47047
Methylene Chloride
<0.330
u9/L
0.330
1.00
1
05/07/24 19:15
ENM
V47047
Styrene
<0.220
N9/L
0.220
0.500
1
05/07/24 19:15
ENM
V47047
1,1,1,2-Tetrachloroethane
<0.160
u9/L
0.160
0.500
1
05/07/24 19:15
ENM
V47047
1,1,2,2-Tetrachloroethane
<0.160
N9/L
0.160
0.500
1
05/07/24 19:15
ENM
V47047
Tetrachloroethene
<0.220
u9/L
0.220
0.500
1
05/07/24 19:15
ENM
V47047
Tetrahydrofuran
<1.50
N9/L
1.50
10.0
1
05/07/24 19:15
ENM
V47047
Toluene
<0.220
u9/L
0.220
0.500
1
05/07/24 19:15
ENM
V47047
1,1,1-Trichloroethane
<0.160
N9/L
0.160
0.500
1
05/07/24 19:15
ENM
V47047
1,1,2-Trichloroethane
<0.096
u9/L
0.096
0.500
1
05/07/24 19:15
ENM
V47047
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
J
Estimated value
MQL
Method Quantitation Limit
Page 41 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100
Lab No : 92450
Sample ID: MW-17
REPOR T OF A NA L YSIS
Matrix: Aqueous
Sampled: 4/30/2024 15:30
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Trichloroethene
<0.180
Ng/L
0.180
0.500
1
05/07/24 19:15 ENM
V47047
Trichlorofluoromethane
<0.180
ug/L
0.180
0.500
1
05/07/24 19:15 ENM
V47047
1,2,3-Trichloropropane
<0.270
Ng/L
0.270
1.00
1
05/07/24 19:15 ENM
V47047
Vinyl Acetate
<1.00
ug/L
1.00
2.00
1
05/07/24 19:15 ENM
V47047
Vinyl Chloride
<0.170
Ng/L
0.170
0.500
1
05/07/24 19:15 ENM
V47047
o-Xylene
<0.210
ug/L
0.210
0.500
1
05/07/24 19:15 ENM
V47047
m,p-Xylene
<0.420
Ng/L
0.420
1.00
1
05/07/24 19:15 ENM
V47047
Xylene (Total)
<0.21
ug/L
0.210
0.500
1
05/07/24 19:15
V47047
Surrogate:4-Bromofluorobenzene
93.6
Limits:80-124%
1 05/07/24 19:15 ENM
V47047
Surrogate: Dibromofluoromethane
96.0
Limits:
75-129%
1 05/07/24 19:15 ENM
V47047
Surrogate: 1,2-Dichloroethane - d4
88.6
Limits:
63-136%
1 05/07/24 19:15 ENM
V47047
Surrogate: Toluene-d8
102
Limits:
77-123%
1 05/07/24 19:15 ENM
V47047
Qualifiers/ * Outside QC Limit
Definitions DF Dilution Factor
MQL Method Quantitation Limit
B Analyte detected in blank
J Estimated value
Page 42 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
WavDdibnto
ANALYTICAL
01186
Smith & Gardner, Inc.
Seth C. Rickerts
14 N. Boylan Avenue
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Project Surry County MSW
Information :
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Report Date : 05/14/2024
Received : 05/02/2024
Lab No : 92451
Sample ID: MW-3R
Matrix: Aqueous
Sampled: 4/30/2024 15:45
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
1,4-Dioxane
2.43
Ng/L
0.139
2.00
1
05/02/24 19:59
TBL
8260D SIM
Antimony
<1.00
u9/L
0.618
1.00
1
05/09/24 17:55
CPW
6020B
Arsenic
0.8573
N9/L
0.297
1.00
1
05/09/24 17:55
CPW
6020B
Barium
126
u9/L
0.453
1.00
1
05/10/2418:57
CPW
6020B
Beryllium
<0.102
N9/L
0.102
1.00
1
05/09/24 17:55
CPW
6020B
Cadmium
<0.350
u9/L
0.350
1.00
1
05/09/24 17:55
CPW
6020B
Chromium
4.41 B
N9/L
0.346
1.00
1
05/09/24 17:55
CPW
6020B
Cobalt
246
u9/L
0.060
1.00
1
05/09/24 17:55
CPW
6020B
Copper
2.65
N9/L
0.489
1.00
1
05/09/24 17:55
CPW
6020B
Lead
1.07
u9/L
0.264
1.00
1
05/09/24 17:55
CPW
6020B
Nickel
25.0
N9/L
0.182
1.00
1
05/09/24 17:55
CPW
6020B
Selenium
<0.703
u9/L
0.703
1.00
1
05/10/2418:57
CPW
6020B
Silver
<0.0570
N9/L
0.0570
1.00
1
05/09/24 17:55
CPW
6020B
Thallium
<0.0610
u9/L
0.0610
1.00
1
05/09/24 17:55
CPW
6020B
Vanadium
<0.767
N9/L
0.767
5.00
1
05/10/2418:57
TJS
6020B
Zinc
14.2
ug/L
4.67
10.0
1
05/09/24 17:55
CPW
6020B
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor J Estimated value
MQL Method Quantitation Limit
Page 43 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92451
Matrix: Aqueous
Sample ID: MW-3R
Sampled:
4/30/2024
15:45
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
N9/L
1.80
5.00
1
05/07/24 19:40
ENM
V47047
Acrylonitrile
<0.230
u9/L
0.230
5.00
1
05/07/24 19:40
ENM
V47047
Benzene
1.33
N9/L
0.180
0.500
1
05/07/24 19:40
ENM
V47047
Bromochloromethane
<0.420
u9/L
0.420
1.00
1
05/07/24 19:40
ENM
V47047
Bromodichloromethane
<0.160
N9/L
0.160
0.500
1
05/07/24 19:40
ENM
V47047
Bromoform
<1.50
u9/L
1.50
5.00
1
05/07/24 19:40
ENM
V47047
Bromomethane
<0.280
N9/L
0.280
1.00
1
05/07/24 19:40
ENM
V47047
Carbon Disulfide
<0.150
u9/L
0.150
5.00
1
05/07/24 19:40
ENM
V47047
Carbon Tetrachloride
<0.180
N9/L
0.180
0.500
1
05/07/24 19:40
ENM
V47047
Chlorobenzene
5.63
u9/L
0.190
0.500
1
05/07/24 19:40
ENM
V47047
Chlorodibromomethane
<0.190
N9/L
0.190
0.500
1
05/07/24 19:40
ENM
V47047
Chloroethane
<0.430
u9/L
0.430
1.00
1
05/07/24 19:40
ENM
V47047
Chloroform
<0.220
N9/L
0.220
0.500
1
05/07/24 19:40
ENM
V47047
Chloromethane
<0.220
u9/L
0.220
0.500
1
05/07/24 19:40
ENM
V47047
Di -Isopropyl Ether (DIPE)
<0.960
N9/L
0.960
5.00
1
05/07/24 19:40
ENM
V47047
1,2-Dibromo-3-Chloropropane
<1.10
u9/L
1.10
2.00
1
05/07/24 19:40
ENM
V47047
1,2-Dibromoethane
<0.200
N9/L
0.200
0.500
1
05/07/24 19:40
ENM
V47047
Dibromomethane
<0.230
u9/L
0.230
0.500
1
05/07/24 19:40
ENM
V47047
trans-1,4-Dichloro-2-butene
<1.30
N9/L
1.30
10.0
1
05/07/24 19:40
ENM
V47047
1,2-Dichlorobenzene
<0.220
u9/L
0.220
0.500
1
05/07/24 19:40
ENM
V47047
1,4-Dichlorobenzene
<0.210
N9/L
0.210
0.500
1
05/07/24 19:40
ENM
V47047
Dichlorodifluoromethane
<1.20
u9/L
1.20
5.00
1
05/07/24 19:40
ENM
V47047
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
J
Estimated value
MQL Method Quantitation Limit
Page 44 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92451
Matrix: Aqueous
Sample ID: MW-3R
Sampled:
4/30/2024
15:45
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
0.816
N9/L
0.240
0.500
1
05/07/24 19:40
ENM
V47047
1,2-Dichloroethane
1.92
ug/L
0.150
0.500
1
05/07/24 19:40
ENM
V47047
1,1-Dichloroethene
<0.150
N9/L
0.150
0.500
1
05/07/24 19:40
ENM
V47047
cis- 1,2-Dich loroethene
11.0
u9/L
0.200
0.500
1
05/07/24 19:40
ENM
V47047
trans-1,2-Dichloroethene
<0.180
N9/L
0.180
0.500
1
05/07/24 19:40
ENM
V47047
1,2-Dichloropropane
<0.190
u9/L
0.190
0.500
1
05/07/24 19:40
ENM
V47047
cis- 1,3-Dich loropropene
<0.210
N9/L
0.210
0.500
1
05/07/24 19:40
ENM
V47047
trans-1,3-Dichloropropene
<0.150
u9/L
0.150
0.500
1
05/07/24 19:40
ENM
V47047
1,4-Dioxane
<16.0
N9/L
16.0
150
1
05/07/24 19:40
ENM
V47047
Ethylbenzene
<0.170
u9/L
0.170
0.500
1
05/07/24 19:40
ENM
V47047
2-Hexanone
<0.380
N9/L
0.380
5.00
1
05/07/24 19:40
ENM
V47047
Methyl Ethyl Ketone (MEK)
<0.710
u9/L
0.710
5.00
1
05/07/24 19:40
ENM
V47047
4-Methyl-2-Pentanone
<1.00
N9/L
1.00
5.00
1
05/07/24 19:40
ENM
V47047
Methylene Chloride
<0.330
ug/L
0.330
1.00
1
05/07/24 19:40
ENM
V47047
Styrene
<0.220
N9/L
0.220
0.500
1
05/07/24 19:40
ENM
V47047
1,1,1,2-Tetrachloroethane
<0.160
u9/L
0.160
0.500
1
05/07/24 19:40
ENM
V47047
1,1,2,2-Tetrachloroethane
<0.160
N9/L
0.160
0.500
1
05/07/24 19:40
ENM
V47047
Tetrachloroethene
<0.220
u9/L
0.220
0.500
1
05/07/24 19:40
ENM
V47047
Tetrahydrofuran
<1.50
N9/L
1.50
10.0
1
05/07/24 19:40
ENM
V47047
Toluene
0.463 J
ug/L
0.220
0.500
1
05/07/24 19:40
ENM
V47047
1,1,1-Trichloroethane
<0.160
N9/L
0.160
0.500
1
05/07/24 19:40
ENM
V47047
1,1,2-Trichloroethane
<0.096
u9/L
0.096
0.500
1
05/07/24 19:40
ENM
V47047
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
J
Estimated value
MQL
Method Quantitation Limit
Page 45 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100
Lab No : 92451
Sample ID: MW-3R
REPOR T OF A NA L YSIS
Matrix: Aqueous
Sampled: 4/30/2024 15:45
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Trichloroethene
<0.180
Ng/L
0.180
0.500
1
05/07/24 19:40 ENM
V47047
Trichlorofluoromethane
<0.180
ug/L
0.180
0.500
1
05/07/24 19:40 ENM
V47047
1,2,3-Trichloropropane
<0.270
Ng/L
0.270
1.00
1
05/07/24 19:40 ENM
V47047
Vinyl Acetate
<1.00
ug/L
1.00
2.00
1
05/07/24 19:40 ENM
V47047
Vinyl Chloride
5.91
Ng/L
0.170
0.500
1
05/07/24 19:40 ENM
V47047
o-Xylene
<0.210
ug/L
0.210
0.500
1
05/07/24 19:40 ENM
V47047
m,p-Xylene
<0.420
Ng/L
0.420
1.00
1
05/07/24 19:40 ENM
V47047
Xylene (Total)
<0.21
ug/L
0.210
0.500
1
05/07/24 19:40
V47047
Surrogate:4-Bromofluorobenzene
94.4
Limits:80-124%
1 05/07/24 19:40 ENM
V47047
Surrogate: Dibromofluoromethane
97.6
Limits:
75-129%
1 05/07/24 19:40 ENM
V47047
Surrogate: 1,2-Dichloroethane - d4
89.6
Limits:
63-136%
1 05/07/24 19:40 ENM
V47047
Surrogate: Toluene-d8
102
Limits:
77-123%
1 05/07/24 19:40 ENM
V47047
Qualifiers/ * Outside QC Limit
Definitions DF Dilution Factor
MQL Method Quantitation Limit
B Analyte detected in blank
J Estimated value
Page 46 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
WavDdibnto
ANALYTICAL
01186
Smith & Gardner, Inc.
Seth C. Rickerts
14 N. Boylan Avenue
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Project Surry County MSW
Information :
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Report Date : 05/14/2024
Received : 05/02/2024
Lab No : 92452
Sample ID: MW-20
Matrix: Aqueous
Sampled: 4/30/2024 16:00
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
1,4-Dioxane
2.74
Ng/L
0.139
2.00
1
05/02/24 20:24
TBL
8260D SIM
Antimony
<1.00
u9/L
0.618
1.00
1
05/09/24 17:59
CPW
6020B
Arsenic
<0.297
N9/L
0.297
1.00
1
05/09/24 17:59
CPW
6020B
Barium
105
u9/L
0.453
1.00
1
05/10/2419:01
CPW
6020B
Beryllium
0.7393
N9/L
0.102
1.00
1
05/09/24 17:59
CPW
6020B
Cadmium
<0.350
u9/L
0.350
1.00
1
05/09/24 17:59
CPW
6020B
Chromium
10.0
N9/L
0.346
1.00
1
05/09/24 17:59
CPW
6020B
Cobalt
201
u9/L
0.060
1.00
1
05/09/24 17:59
CPW
6020B
Copper
3.56
N9/L
0.489
1.00
1
05/09/24 17:59
CPW
6020B
Lead
3.28
u9/L
0.264
1.00
1
05/09/24 17:59
CPW
6020B
Nickel
12.3
N9/L
0.182
1.00
1
05/09/24 17:59
CPW
6020B
Selenium
<0.703
u9/L
0.703
1.00
1
05/10/2419:01
CPW
6020B
Silver
0.07953
N9/L
0.0570
1.00
1
05/09/24 17:59
CPW
6020B
Thallium
1.55
u9/L
0.0610
1.00
1
05/09/24 17:59
CPW
6020B
Vanadium
9.42
N9/L
0.767
5.00
1
05/10/2419:01
TJS
6020B
Zinc
39.7
u9/L
4.67
10.0
1
05/09/24 17:59
CPW
6020B
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor J Estimated value
MQL Method Quantitation Limit
Page 47 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92452
Matrix: Aqueous
Sample ID: MW-20
Sampled:
4/30/2024
16:00
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
Ng/L
1.80
5.00
1
05/07/24 20:05
ENM
V47047
Acrylonitrile
<0.230
ug/L
0.230
5.00
1
05/07/24 20:05
ENM
V47047
Benzene
1.53
Ng/L
0.180
0.500
1
05/07/24 20:05
ENM
V47047
Bromochloromethane
<0.420
ug/L
0.420
1.00
1
05/07/24 20:05
ENM
V47047
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 20:05
ENM
V47047
Bromoform
<1.50
ug/L
1.50
5.00
1
05/07/24 20:05
ENM
V47047
Bromomethane
<0.280
Ng/L
0.280
1.00
1
05/07/24 20:05
ENM
V47047
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
05/07/24 20:05
ENM
V47047
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
05/07/24 20:05
ENM
V47047
Chlorobenzene
1.80
ug/L
0.190
0.500
1
05/07/24 20:05
ENM
V47047
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
05/07/24 20:05
ENM
V47047
Chloroethane
<0.430
ug/L
0.430
1.00
1
05/07/24 20:05
ENM
V47047
Chloroform
<0.220
Ng/L
0.220
0.500
1
05/07/24 20:05
ENM
V47047
Chloromethane
<0.220
ug/L
0.220
0.500
1
05/07/24 20:05
ENM
V47047
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
05/07/24 20:05
ENM
V47047
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
05/07/24 20:05
ENM
V47047
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
05/07/24 20:05
ENM
V47047
Dibromomethane
<0.230
ug/L
0.230
0.500
1
05/07/24 20:05
ENM
V47047
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
05/07/24 20:05
ENM
V47047
1,2-Dichlorobenzene
1.49
ug/L
0.220
0.500
1
05/07/24 20:05
ENM
V47047
1,4-Dichlorobenzene
<0.210
Ng/L
0.210
0.500
1
05/07/24 20:05
ENM
V47047
Dichlorodifluoromethane
<1.20
ug/L
1.20
5.00
1
05/07/24 20:05
ENM
V47047
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
J
Estimated value
MQL Method Quantitation Limit
Page 48 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92452 Matrix: Aqueous
Sample ID: MW-20 Sampled: 4/30/2024 16:00
Analytical Method: 8260D Prep Batch(es): V47029 05/07/24 12:42
Prep Method: 5030E
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
1,1-Dichloroethane
1.35
Ng/L
0.240
0.500
1
05/07/24 20:05
ENM
V47047
1,2-Dichloroethane
<0.150
ug/L
0.150
0.500
1
05/07/24 20:05
ENM
V47047
1,1-Dichloroethene
<0.150
Ng/L
0.150
0.500
1
05/07/24 20:05
ENM
V47047
cis- 1,2-Dich loroethene
11.7
ug/L
0.200
0.500
1
05/07/24 20:05
ENM
V47047
trans-1,2-Dichloroethene
<0.180
Ng/L
0.180
0.500
1
05/07/24 20:05
ENM
V47047
1,2-Dichloropropane
<0.190
ug/L
0.190
0.500
1
05/07/24 20:05
ENM
V47047
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
05/07/24 20:05
ENM
V47047
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
05/07/24 20:05
ENM
V47047
1,4-Dioxane
<16.0
Ng/L
16.0
150
1
05/07/24 20:05
ENM
V47047
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
05/07/24 20:05
ENM
V47047
2-Hexanone
<0.380
Ng/L
0.380
5.00
1
05/07/24 20:05
ENM
V47047
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
05/07/24 20:05
ENM
V47047
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
05/07/24 20:05
ENM
V47047
Methylene Chloride
<0.330
ug/L
0.330
1.00
1
05/07/24 20:05
ENM
V47047
Styrene
<0.220
Ng/L
0.220
0.500
1
05/07/24 20:05
ENM
V47047
1,1,1,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
05/07/24 20:05
ENM
V47047
1,1,2,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 20:05
ENM
V47047
Tetrachloroethene
<0.220
ug/L
0.220
0.500
1
05/07/24 20:05
ENM
V47047
Tetrahydrofuran
7.593
Ng/L
1.50
10.0
1
05/07/24 20:05
ENM
V47047
Toluene
<0.220
ug/L
0.220
0.500
1
05/07/24 20:05
ENM
V47047
1,1,1-Trichloroethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 20:05
ENM
V47047
1,1,2-Trichloroethane
<0.096
ug/L
0.096
0.500
1
05/07/24 20:05
ENM
V47047
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
J
Estimated value
MQL
Method Quantitation Limit
Page 49 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100
Lab No : 92452
Sample ID: MW-20
REPOR T OF A NA L YSIS
Matrix: Aqueous
Sampled: 4/30/2024 16:00
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Trichloroethene
<0.180
Ng/L
0.180
0.500
1
05/07/24 20:05 ENM
V47047
Trichlorofluoromethane
<0.180
ug/L
0.180
0.500
1
05/07/24 20:05 ENM
V47047
1,2,3-Trichloropropane
<0.270
Ng/L
0.270
1.00
1
05/07/24 20:05 ENM
V47047
Vinyl Acetate
<1.00
ug/L
1.00
2.00
1
05/07/24 20:05 ENM
V47047
Vinyl Chloride
6.63
Ng/L
0.170
0.500
1
05/07/24 20:05 ENM
V47047
o-Xylene
<0.210
ug/L
0.210
0.500
1
05/07/24 20:05 ENM
V47047
m,p-Xylene
<0.420
Ng/L
0.420
1.00
1
05/07/24 20:05 ENM
V47047
Xylene (Total)
<0.21
ug/L
0.210
0.500
1
05/07/24 20:05
V47047
Surrogate: 4-Bromofluorobenzene
95.6
Limits:
80-124%
1 05/07/24 20:05 ENM
V47047
Surrogate: Dibromofluoromethane
98.6
Limits:
75-129%
1 05/07/24 20:05 ENM
V47047
Surrogate: 1,2-Dichloroethane - d4
90.6
Limits:
63-136%
1 05/07/24 20:05 ENM
V47047
Surrogate: Toluene-d8
103
Limits:
77-123%
1 05/07/24 20:05 ENM
V47047
Qualifiers/ * Outside QC Limit
Definitions DF Dilution Factor
MQL Method Quantitation Limit
B Analyte detected in blank
J Estimated value
Page 50 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
WavDdibnto
ANALYTICAL
01186
Smith & Gardner, Inc.
Seth C. Rickerts
14 N. Boylan Avenue
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Project Surry County MSW
Information :
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Report Date : 05/14/2024
Received : 05/02/2024
Lab No : 92453
Sample ID: SW-4
Matrix: Aqueous
Sampled: 4/30/2024 16:15
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
1,4-Dioxane
<0.139
Ng/L
0.139
2.00
1
05/02/24 20:49
TBL
8260D SIM
Antimony
<1.00
pg/L
0.618
1.00
1
05/09/24 18:03
CPW
6020B
Arsenic
<0.297
N9/L
0.297
1.00
1
05/09/24 18:03
CPW
6020B
Barium
16.2
u9/L
0.453
1.00
1
05/10/2419:06
CPW
6020B
Beryllium
<0.102
N9/L
0.102
1.00
1
05/09/24 18:03
CPW
6020B
Cadmium
<0.350
u9/L
0.350
1.00
1
05/09/24 18:03
CPW
6020B
Chromium
1.09 B
N9/L
0.346
1.00
1
05/09/24 18:03
CPW
6020B
Cobalt
1.26
u9/L
0.060
1.00
1
05/09/24 18:03
CPW
6020B
Copper
0.6153
N9/L
0.489
1.00
1
05/09/24 18:03
CPW
6020B
Lead
<0.264
u9/L
0.264
1.00
1
05/09/24 18:03
CPW
6020B
Nickel
0.1923
N9/L
0.182
1.00
1
05/09/24 18:03
CPW
6020B
Selenium
<0.703
u9/L
0.703
1.00
1
05/10/2419:06
CPW
6020B
Silver
<0.0570
N9/L
0.0570
1.00
1
05/09/24 18:03
CPW
6020B
Thallium
<0.0610
u9/L
0.0610
1.00
1
05/09/24 18:03
CPW
6020B
Vanadium
<0.767
N9/L
0.767
5.00
1
05/10/2419:06
TJS
6020B
Zinc
<4.67
u9/L
4.67
10.0
1
05/09/24 18:03
CPW
6020B
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor J Estimated value
MQL Method Quantitation Limit
Page 51 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92453
Matrix: Aqueous
Sample ID: SW-4
Sampled:
4/30/2024
16:15
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
N9/L
1.80
5.00
1
05/07/24 20:29
ENM
V47047
Acrylonitrile
<0.230
u9/L
0.230
5.00
1
05/07/24 20:29
ENM
V47047
Benzene
<0.180
N9/L
0.180
0.500
1
05/07/24 20:29
ENM
V47047
Bromochloromethane
<0.420
u9/L
0.420
1.00
1
05/07/24 20:29
ENM
V47047
Bromodichloromethane
<0.160
N9/L
0.160
0.500
1
05/07/24 20:29
ENM
V47047
Bromoform
<1.50
u9/L
1.50
5.00
1
05/07/24 20:29
ENM
V47047
Bromomethane
<0.280
N9/L
0.280
1.00
1
05/07/24 20:29
ENM
V47047
Carbon Disulfide
<0.150
u9/L
0.150
5.00
1
05/07/24 20:29
ENM
V47047
Carbon Tetrachloride
<0.180
N9/L
0.180
0.500
1
05/07/24 20:29
ENM
V47047
Chlorobenzene
<0.190
u9/L
0.190
0.500
1
05/07/24 20:29
ENM
V47047
Chlorodibromomethane
<0.190
N9/L
0.190
0.500
1
05/07/24 20:29
ENM
V47047
Chloroethane
<0.430
u9/L
0.430
1.00
1
05/07/24 20:29
ENM
V47047
Chloroform
<0.220
N9/L
0.220
0.500
1
05/07/24 20:29
ENM
V47047
Chloromethane
<0.220
u9/L
0.220
0.500
1
05/07/24 20:29
ENM
V47047
Di -Isopropyl Ether (DIPE)
<0.960
N9/L
0.960
5.00
1
05/07/24 20:29
ENM
V47047
1,2-Dibromo-3-Chloropropane
<1.10
u9/L
1.10
2.00
1
05/07/24 20:29
ENM
V47047
1,2-Dibromoethane
<0.200
N9/L
0.200
0.500
1
05/07/24 20:29
ENM
V47047
Dibromomethane
<0.230
u9/L
0.230
0.500
1
05/07/24 20:29
ENM
V47047
trans-1,4-Dichloro-2-butene
<1.30
N9/L
1.30
10.0
1
05/07/24 20:29
ENM
V47047
1,2-Dichlorobenzene
<0.220
u9/L
0.220
0.500
1
05/07/24 20:29
ENM
V47047
1,4-Dichlorobenzene
<0.210
N9/L
0.210
0.500
1
05/07/24 20:29
ENM
V47047
Dichlorodifluoromethane
<1.20
u9/L
1.20
5.00
1
05/07/24 20:29
ENM
V47047
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
J
Estimated value
MQL Method Quantitation Limit
Page 52 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92453
Matrix: Aqueous
Sample ID: SW-4
Sampled:
4/30/2024
16:15
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
05/07/24 20:29
ENM
V47047
1,2-Dichloroethane
<0.150
u9/L
0.150
0.500
1
05/07/24 20:29
ENM
V47047
1,1-Dichloroethene
<0.150
N9/L
0.150
0.500
1
05/07/24 20:29
ENM
V47047
cis- 1,2-Dich loroethene
<0.200
u9/L
0.200
0.500
1
05/07/24 20:29
ENM
V47047
trans-1,2-Dichloroethene
<0.180
N9/L
0.180
0.500
1
05/07/24 20:29
ENM
V47047
1,2-Dichloropropane
<0.190
u9/L
0.190
0.500
1
05/07/24 20:29
ENM
V47047
cis- 1,3-Dich loropropene
<0.210
N9/L
0.210
0.500
1
05/07/24 20:29
ENM
V47047
trans-1,3-Dichloropropene
<0.150
u9/L
0.150
0.500
1
05/07/24 20:29
ENM
V47047
1,4-Dioxane
<16.0
N9/L
16.0
150
1
05/07/24 20:29
ENM
V47047
Ethylbenzene
<0.170
u9/L
0.170
0.500
1
05/07/24 20:29
ENM
V47047
2-Hexanone
<0.380
N9/L
0.380
5.00
1
05/07/24 20:29
ENM
V47047
Methyl Ethyl Ketone (MEK)
<0.710
u9/L
0.710
5.00
1
05/07/24 20:29
ENM
V47047
4-Methyl-2-Pentanone
<1.00
N9/L
1.00
5.00
1
05/07/24 20:29
ENM
V47047
Methylene Chloride
<0.330
u9/L
0.330
1.00
1
05/07/24 20:29
ENM
V47047
Styrene
<0.220
N9/L
0.220
0.500
1
05/07/24 20:29
ENM
V47047
1,1,1,2-Tetrachloroethane
<0.160
u9/L
0.160
0.500
1
05/07/24 20:29
ENM
V47047
1,1,2,2-Tetrachloroethane
<0.160
N9/L
0.160
0.500
1
05/07/24 20:29
ENM
V47047
Tetrachloroethene
<0.220
u9/L
0.220
0.500
1
05/07/24 20:29
ENM
V47047
Tetrahydrofuran
<1.50
N9/L
1.50
10.0
1
05/07/24 20:29
ENM
V47047
Toluene
<0.220
u9/L
0.220
0.500
1
05/07/24 20:29
ENM
V47047
1,1,1-Trichloroethane
<0.160
N9/L
0.160
0.500
1
05/07/24 20:29
ENM
V47047
1,1,2-Trichloroethane
<0.096
u9/L
0.096
0.500
1
05/07/24 20:29
ENM
V47047
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
J
Estimated value
MQL
Method Quantitation Limit
Page 53 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100
Lab No : 92453
Sample ID: SW-4
REPOR T OF A NA L YSIS
Matrix: Aqueous
Sampled: 4/30/2024 16:15
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Trichloroethene
<0.180
Ng/L
0.180
0.500
1
05/07/24 20:29 ENM
V47047
Trichlorofluoromethane
<0.180
ug/L
0.180
0.500
1
05/07/24 20:29 ENM
V47047
1,2,3-Trichloropropane
<0.270
Ng/L
0.270
1.00
1
05/07/24 20:29 ENM
V47047
Vinyl Acetate
<1.00
ug/L
1.00
2.00
1
05/07/24 20:29 ENM
V47047
Vinyl Chloride
<0.170
Ng/L
0.170
0.500
1
05/07/24 20:29 ENM
V47047
o-Xylene
<0.210
ug/L
0.210
0.500
1
05/07/24 20:29 ENM
V47047
m,p-Xylene
<0.420
Ng/L
0.420
1.00
1
05/07/24 20:29 ENM
V47047
Xylene (Total)
<0.21
ug/L
0.210
0.500
1
05/07/24 20:29
V47047
Surrogate: 4-Bromofluorobenzene
96.4
Limits:
80-124%
1 05/07/24 20:29 ENM
V47047
Surrogate: Dibromofluoromethane
97.4
Limits:
75-129%
1 05/07/24 20:29 ENM
V47047
Surrogate: 1,2-Dichloroethane - d4
91.6
Limits:
63-136%
1 05/07/24 20:29 ENM
V47047
Surrogate: Toluene-d8
103
Limits:
77-123%
1 05/07/24 20:29 ENM
V47047
Qualifiers/ * Outside QC Limit
Definitions DF Dilution Factor
MQL Method Quantitation Limit
B Analyte detected in blank
J Estimated value
Page 54 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
WavDdibnto
ANALYTICAL
01186
Smith & Gardner, Inc.
Seth C. Rickerts
14 N. Boylan Avenue
Raleigh , NC 27603
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Project Surry County MSW
Information :
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Report Date : 05/14/2024
Received : 05/02/2024
Lab No : 92454
Sample ID: WSW-2
Matrix: Aqueous
Sampled: 4/30/2024 17:00
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
1,4-Dioxane
<0.139
Ng/L
0.139
2.00
1
05/02/24 21:14
TBL
8260D SIM
Antimony
<1.00
pg/L
0.618
1.00
1
05/09/24 18:08
CPW
6020B
Arsenic
<0.297
N9/L
0.297
1.00
1
05/09/24 18:08
CPW
6020B
Barium
2.99
u9/L
0.453
1.00
1
05/10/2419:10
CPW
6020B
Beryllium
<0.102
N9/L
0.102
1.00
1
05/09/24 18:08
CPW
6020B
Cadmium
<0.350
u9/L
0.350
1.00
1
05/09/24 18:08
CPW
6020B
Chromium
2.11 B
N9/L
0.346
1.00
1
05/09/24 18:08
CPW
6020B
Cobalt
<0.060
u9/L
0.060
1.00
1
05/09/24 18:08
CPW
6020B
Copper
0.8253
N9/L
0.489
1.00
1
05/09/24 18:08
CPW
6020B
Lead
<0.264
u9/L
0.264
1.00
1
05/09/24 18:08
CPW
6020B
Nickel
0.4793
N9/L
0.182
1.00
1
05/09/24 18:08
CPW
6020B
Selenium
<0.703
u9/L
0.703
1.00
1
05/10/2419:10
CPW
6020B
Silver
<0.0570
N9/L
0.0570
1.00
1
05/09/24 18:08
CPW
6020B
Thallium
<0.0610
u9/L
0.0610
1.00
1
05/09/24 18:08
CPW
6020B
Vanadium
<0.767
N9/L
0.767
5.00
1
05/10/2419:10
TJS
6020B
Zinc
<4.67
u9/L
4.67
10.0
1
05/09/24 18:08
CPW
6020B
Qualifiers/ * Outside QC Limit B Analyte detected in blank
Definitions DF Dilution Factor J Estimated value
MQL Method Quantitation Limit
Page 55 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92454
Matrix: Aqueous
Sample ID: WSW-2
Sampled:
4/30/2024
17:00
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
Ng/L
1.80
5.00
1
05/07/24 20:54
ENM
V47047
Acrylonitrile
<0.230
ug/L
0.230
5.00
1
05/07/24 20:54
ENM
V47047
Benzene
<0.180
Ng/L
0.180
0.500
1
05/07/24 20:54
ENM
V47047
Bromochloromethane
<0.420
ug/L
0.420
1.00
1
05/07/24 20:54
ENM
V47047
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 20:54
ENM
V47047
Bromoform
<1.50
ug/L
1.50
5.00
1
05/07/24 20:54
ENM
V47047
Bromomethane
<0.280
Ng/L
0.280
1.00
1
05/07/24 20:54
ENM
V47047
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
05/07/24 20:54
ENM
V47047
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
05/07/24 20:54
ENM
V47047
Chlorobenzene
<0.190
ug/L
0.190
0.500
1
05/07/24 20:54
ENM
V47047
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
05/07/24 20:54
ENM
V47047
Chloroethane
<0.430
ug/L
0.430
1.00
1
05/07/24 20:54
ENM
V47047
Chloroform
<0.220
Ng/L
0.220
0.500
1
05/07/24 20:54
ENM
V47047
Chloromethane
<0.220
ug/L
0.220
0.500
1
05/07/24 20:54
ENM
V47047
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
05/07/24 20:54
ENM
V47047
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
05/07/24 20:54
ENM
V47047
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
05/07/24 20:54
ENM
V47047
Dibromomethane
<0.230
ug/L
0.230
0.500
1
05/07/24 20:54
ENM
V47047
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
05/07/24 20:54
ENM
V47047
1,2-Dichlorobenzene
<0.220
ug/L
0.220
0.500
1
05/07/24 20:54
ENM
V47047
1,4-Dichlorobenzene
<0.210
Ng/L
0.210
0.500
1
05/07/24 20:54
ENM
V47047
Dichlorodifluoromethane
<1.20
ug/L
1.20
5.00
1
05/07/24 20:54
ENM
V47047
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
J
Estimated value
MQL Method Quantitation Limit
Page 56 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92454
Matrix: Aqueous
Sample ID: WSW-2
Sampled:
4/30/2024
17:00
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
05/07/24 20:54
ENM
V47047
1,2-Dichloroethane
<0.150
ug/L
0.150
0.500
1
05/07/24 20:54
ENM
V47047
1,1-Dichloroethene
<0.150
Ng/L
0.150
0.500
1
05/07/24 20:54
ENM
V47047
cis- 1,2-Dich loroethene
<0.200
ug/L
0.200
0.500
1
05/07/24 20:54
ENM
V47047
trans-1,2-Dichloroethene
<0.180
Ng/L
0.180
0.500
1
05/07/24 20:54
ENM
V47047
1,2-Dichloropropane
<0.190
ug/L
0.190
0.500
1
05/07/24 20:54
ENM
V47047
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
05/07/24 20:54
ENM
V47047
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
05/07/24 20:54
ENM
V47047
1,4-Dioxane
<16.0
Ng/L
16.0
150
1
05/07/24 20:54
ENM
V47047
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
05/07/24 20:54
ENM
V47047
2-Hexanone
<0.380
Ng/L
0.380
5.00
1
05/07/24 20:54
ENM
V47047
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
05/07/24 20:54
ENM
V47047
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
05/07/24 20:54
ENM
V47047
Methylene Chloride
<0.330
ug/L
0.330
1.00
1
05/07/24 20:54
ENM
V47047
Styrene
<0.220
Ng/L
0.220
0.500
1
05/07/24 20:54
ENM
V47047
1,1,1,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
05/07/24 20:54
ENM
V47047
1,1,2,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 20:54
ENM
V47047
Tetrachloroethene
<0.220
ug/L
0.220
0.500
1
05/07/24 20:54
ENM
V47047
Tetrahydrofuran
<1.50
Ng/L
1.50
10.0
1
05/07/24 20:54
ENM
V47047
Toluene
<0.220
ug/L
0.220
0.500
1
05/07/24 20:54
ENM
V47047
1,1,1-Trichloroethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 20:54
ENM
V47047
1,1,2-Trichloroethane
<0.096
ug/L
0.096
0.500
1
05/07/24 20:54
ENM
V47047
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
J
Estimated value
MQL
Method Quantitation Limit
Page 57 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100
Lab No : 92454
Sample ID: WSW-2
REPOR T OF A NA L YSIS
Matrix: Aqueous
Sampled: 4/30/2024 17:00
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Trichloroethene
<0.180
Ng/L
0.180
0.500
1
05/07/24 20:54 ENM
V47047
Trichlorofluoromethane
<0.180
ug/L
0.180
0.500
1
05/07/24 20:54 ENM
V47047
1,2,3-Trichloropropane
<0.270
Ng/L
0.270
1.00
1
05/07/24 20:54 ENM
V47047
Vinyl Acetate
<1.00
ug/L
1.00
2.00
1
05/07/24 20:54 ENM
V47047
Vinyl Chloride
<0.170
Ng/L
0.170
0.500
1
05/07/24 20:54 ENM
V47047
o-Xylene
<0.210
ug/L
0.210
0.500
1
05/07/24 20:54 ENM
V47047
m,p-Xylene
<0.420
Ng/L
0.420
1.00
1
05/07/24 20:54 ENM
V47047
Xylene (Total)
<0.21
ug/L
0.210
0.500
1
05/07/24 20:54
V47047
Surrogate: 4-Bromofluorobenzene
94.6
Limits:
80-124%
1 05/07/24 20:54 ENM
V47047
Surrogate: Dibromofluoromethane
98.8
Limits:
75-129%
1 05/07/24 20:54 ENM
V47047
Surrogate: 1,2-Dichloroethane - d4
91.2
Limits:
63-136%
1 05/07/24 20:54 ENM
V47047
Surrogate: Toluene-d8
103
Limits:
77-123%
1 05/07/24 20:54 ENM
V47047
Qualifiers/ * Outside QC Limit
Definitions DF Dilution Factor
MQL Method Quantitation Limit
B Analyte detected in blank
J Estimated value
Page 58 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92455
Matrix: Aqueous
Sample ID : Trip Blank
Sampled:
4/30/2024
0:00
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
Ng/L
1.80
5.00
1
05/07/24 15:34
ENM
V47047
Acrylonitrile
<0.230
ug/L
0.230
5.00
1
05/07/24 15:34
ENM
V47047
Benzene
<0.180
Ng/L
0.180
0.500
1
05/07/24 15:34
ENM
V47047
Bromochloromethane
<0.420
ug/L
0.420
1.00
1
05/07/24 15:34
ENM
V47047
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 15:34
ENM
V47047
Bromoform
<1.50
ug/L
1.50
5.00
1
05/07/24 15:34
ENM
V47047
Bromomethane
<0.280
Ng/L
0.280
1.00
1
05/07/24 15:34
ENM
V47047
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
05/07/24 15:34
ENM
V47047
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
05/07/24 15:34
ENM
V47047
Chlorobenzene
<0.190
ug/L
0.190
0.500
1
05/07/24 15:34
ENM
V47047
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
05/07/24 15:34
ENM
V47047
Chloroethane
<0.430
ug/L
0.430
1.00
1
05/07/24 15:34
ENM
V47047
Chloroform
<0.220
Ng/L
0.220
0.500
1
05/07/24 15:34
ENM
V47047
Chloromethane
<0.220
ug/L
0.220
0.500
1
05/07/24 15:34
ENM
V47047
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
05/07/24 15:34
ENM
V47047
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
05/07/24 15:34
ENM
V47047
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
05/07/24 15:34
ENM
V47047
Dibromomethane
<0.230
ug/L
0.230
0.500
1
05/07/24 15:34
ENM
V47047
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
05/07/24 15:34
ENM
V47047
1,2-Dichlorobenzene
<0.220
ug/L
0.220
0.500
1
05/07/24 15:34
ENM
V47047
1,4-Dichlorobenzene
<0.210
Ng/L
0.210
0.500
1
05/07/24 15:34
ENM
V47047
Dichlorodifluoromethane
<1.20
ug/L
1.20
5.00
1
05/07/24 15:34
ENM
V47047
Qualifiers/ * Outside QC Limit
B
Analyte detected in blank
Definitions DF Dilution Factor
J
Estimated value
MQL Method Quantitation Limit
Page 59 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100 REPOR T OF A NA L YSIS
Lab No : 92455
Matrix: Aqueous
Sample ID : Trip Blank
Sampled:
4/30/2024
0:00
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
05/07/24 15:34
ENM
V47047
1,2-Dichloroethane
<0.150
ug/L
0.150
0.500
1
05/07/24 15:34
ENM
V47047
1,1-Dichloroethene
<0.150
Ng/L
0.150
0.500
1
05/07/24 15:34
ENM
V47047
cis- 1,2-Dich loroethene
<0.200
ug/L
0.200
0.500
1
05/07/24 15:34
ENM
V47047
trans-1,2-Dichloroethene
<0.180
Ng/L
0.180
0.500
1
05/07/24 15:34
ENM
V47047
1,2-Dichloropropane
<0.190
ug/L
0.190
0.500
1
05/07/24 15:34
ENM
V47047
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
05/07/24 15:34
ENM
V47047
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
05/07/24 15:34
ENM
V47047
1,4-Dioxane
<16.0
Ng/L
16.0
150
1
05/07/24 15:34
ENM
V47047
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
05/07/24 15:34
ENM
V47047
2-Hexanone
<0.380
Ng/L
0.380
5.00
1
05/07/24 15:34
ENM
V47047
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
05/07/24 15:34
ENM
V47047
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
05/07/24 15:34
ENM
V47047
Methylene Chloride
<0.330
ug/L
0.330
1.00
1
05/07/24 15:34
ENM
V47047
Styrene
<0.220
Ng/L
0.220
0.500
1
05/07/24 15:34
ENM
V47047
1,1,1,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
05/07/24 15:34
ENM
V47047
1,1,2,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 15:34
ENM
V47047
Tetrachloroethene
<0.220
ug/L
0.220
0.500
1
05/07/24 15:34
ENM
V47047
Tetrahydrofuran
<1.50
Ng/L
1.50
10.0
1
05/07/24 15:34
ENM
V47047
Toluene
<0.220
ug/L
0.220
0.500
1
05/07/24 15:34
ENM
V47047
1,1,1-Trichloroethane
<0.160
Ng/L
0.160
0.500
1
05/07/24 15:34
ENM
V47047
1,1,2-Trichloroethane
<0.096
ug/L
0.096
0.500
1
05/07/24 15:34
ENM
V47047
Qualifiers/ *
Outside QC Limit
B
Analyte detected in blank
Definitions DF
Dilution Factor
J
Estimated value
MQL
Method Quantitation Limit
Page 60 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
•
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01186
Smith & Gardner, Inc. Project Surry County MSW
Seth C. Rickerts Report Date : 05/14/2024
14 N. Boylan Avenue Information : Received : 05/02/2024
Raleigh , NC 27603
Report Number : 24-123-0100
Lab No : 92455
Sample ID : Trip Blank
REPOR T OF A NA L YSIS
Matrix: Aqueous
Sampled: 4/30/2024 0:00
Analytical Method: 8260D
Prep Batch(es):
V47029
05/07/24 12:42
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Trichloroethene
<0.180
Ng/L
0.180
0.500
1
05/07/24 15:34 ENM
V47047
Trichlorofluoromethane
<0.180
ug/L
0.180
0.500
1
05/07/24 15:34 ENM
V47047
1,2,3-Trichloropropane
<0.270
Ng/L
0.270
1.00
1
05/07/24 15:34 ENM
V47047
Vinyl Acetate
<1.00
ug/L
1.00
2.00
1
05/07/24 15:34 ENM
V47047
Vinyl Chloride
<0.170
Ng/L
0.170
0.500
1
05/07/24 15:34 ENM
V47047
o-Xylene
<0.210
ug/L
0.210
0.500
1
05/07/24 15:34 ENM
V47047
m,p-Xylene
<0.420
Ng/L
0.420
1.00
1
05/07/24 15:34 ENM
V47047
Xylene (Total)
<0.21
ug/L
0.210
0.500
1
05/07/24 15:34
V47047
Surrogate:4-Bromofluorobenzene
96.6
Limits:80-124%
1 05/07/24 15:34 ENM
V47047
Surrogate: Dibromofluoromethane
96.0
Limits:
75-129%
1 05/07/24 15:34 ENM
V47047
Surrogate: 1,2-Dichloroethane - d4
89.2
Limits:
63-136%
1 05/07/24 15:34 ENM
V47047
Surrogate: Toluene-d8
102
Limits:
77-123%
1 05/07/24 15:34 ENM
V47047
Qualifiers/ * Outside QC Limit
Definitions DF Dilution Factor
MQL Method Quantitation Limit
B Analyte detected in blank
J Estimated value
Page 61 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
Client ID:
Project Description:
Report No:
Smith & Gardner, Inc.
Surry County MSW
24-123-0100
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
QC Prep:
L749369
QC Analytical Batch(es): L749687,L749989,L750215
QC Prep Batch Method:
3005A
Analysis Method:
6020B
Analysis Description:
Metals Analyses
Lab Reagent Blank
LRB-L749369
Matrix: AQU
Associated Lab Samples:
92443, 92444, 92445,
92446,
92447, 92448, 92449, 92450, 92451,
92452, 92453, 92454
Blank
MDL
MQL
Analyzed
Parameter
Units
Result
Antimony
pg/L
<0.618
0.618
1.00
05/09/24 16:23
Arsenic
pg/L
<0.297
0.297
1.00
05/09/24 16:23
Barium
pg/L
<0.453
0.453
1.00
05/09/24 16:23
Beryllium
pg/L
<0.102
0.102
1.00
05/09/24 16:23
Cadmium
pg/L
<0.350
0.350
1.00
05/09/24 16:23
Chromium
pg/L
0.945
0.346
1.00
05/09/24 16:23
Cobalt
pg/L
<0.060
0.060
1.00
05/09/24 16:23
Copper
pg/L
<0.489
0.489
1.00
05/09/24 16:23
Lead
pg/L
<0.264
0.264
1.00
05/09/24 16:23
Nickel
pg/L
<0.182
0.182
1.00
05/09/24 16:23
Selenium
pg/L
<0.703
0.703
1.00
05/09/24 16:23
Silver
pg/L
<0.0570
0.0570
1.00
05/09/24 16:23
Thallium
pg/L
<0.0610
0.0610
1.00
05/09/24 16:23
Vanadium
pg/L
<0.767
0.767
5.00
05/13/24 14:30
Zinc
pg/L
<4.67
4.67
10.0
05/09/24 16:23
Laboratory Control Sample LCS-L749369
Spike LCS LCS %Rec % Rec
Parameter Units Conc. Result Limits
Antimony
pg/L
100
103
103
80-120
Arsenic
pg/L
50.0
50.3
101
80-120
Barium
pg/L
100
104
104
80-120
Beryllium
pg/L
50.0
52.7
105
80-120
Cadmium
pg/L
10.0
9.89
99.0
80-120
Chromium
pg/L
100
110
110
80-120
Cobalt
pg/L
100
101
101
80-120
Copper
pg/L
50.0
54.0
108
80-120
Date: 05/14/2024 05:41 PM Page 1 of 9
Page 62 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
Client ID: Smith & Gardner, Inc.
Project Description: Surry County MSW
Report No: 24-123-0100
QC Prep: L749369
QC Prep Batch Method: 3005A
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Laboratory Control Sample LCS-L749369
QC Analytical Batch(es): L749687,L749989,L750215
Analysis Method: 6020B
Analysis Description: Metals Analyses
Parameter
Units
Spike
Conc.
LCS
Result
LCS %Rec
% Rec
Limits
Lead
pg/L
50.0
50.3
101
80-120
Nickel
pg/L
50.0
54.3
109
80-120
Selenium
pg/L
100
102
102
80-120
Silver
pg/L
10.0
9.56
96.0
80-120
Thallium
pg/L
10.0
10.2
102
80-120
Vanadium
pg/L
500
524
105
80-120
Zinc
pg/L
500
519
104
80-120
Matrix Spike & Matrix Spike Duplicate
Parameter Units
V 92458-MS-L749369
MS Spike
Result Conc.
V 92458-MSD-L749369
MSD MS Result MSD
Spike Result
Conc.
MS
%Rec
MSD
%Rec
%Rec
Limits
RPD
Max
RPD
Antimony
pg/L
< 0.618
100
100
90.1
90.3
90.0
90.0
75-125
0.2
20.0
Arsenic
pg/L
< 0.297
50.0
50.0
49.8
49.6
100
99.0
75-125
0.4
20.0
Barium
pg/L
88.7
100
100
186
181
97.0
92.0
75-125
2.7
20.0
Beryllium
pg/L
0.288
50.0
50.0
52.9
51.9
105
103
75-125
1.9
20.0
Cadmium
pg/L
< 0.350
10.0
10.0
10.4
9.90
104
99.0
75-125
4.9
20.0
Chromium
pg/L
6.99
100
100
121
117
114
110
75-125
3.3
20.0
Cobalt
pg/L
3.16
100
100
108
103
105
100
75-125
4.7
20.0
Copper
pg/L
3.89
50.0
50.0
59.0
56.4
110
105
75-125
4.5
20.0
Lead
pg/L
1.38
50.0
50.0
49.8
49.5
97.0
96.0
75-125
0.6
20.0
Nickel
pg/L
4.13
50.0
50.0
60.3
57.6
112
107
75-125
4.5
20.0
Selenium
pg/L
< 0.703
100
100
93.9
92.8
94.0
93.0
75-125
1.1
20.0
Silver
pg/L
< 0.0570
10.0
10.0
10.1
9.81
101
98.0
75-125
2.9
20.0
Thallium
pg/L
0.112
10.0
10.0
10.2
10.0
101
99.0
75-125
1.9
20.0
Vanadium
pg/L
5.55
500
500
510
519
101
103
75-125
1.7
20.0
Zinc
pg/L
15.1
500
500
544
513
106
100
75-125
5.8
20.0
Date: 05/14/2024 05:41 PM Page 2 of 9
Page 63 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
Client ID: Smith & Gardner, Inc.
Project Description: Surry County MSW
Report No: 24-123-0100
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
QC Prep: L749369 QC Analytical Batch(es): L749687,L749989,L750215
QC Prep Batch Method: 3005A Analysis Method: 6020B
Analysis Description: Metals Analyses
Post Digestion Spike V 92458-PDS-L749369
Parameter
Units
PDS
Result
%
Recovery
Analyzed
Antimony
pg/L
48.0
96.0
05/10/24 19:49
Arsenic
pg/L
24.0
96.0
05/09/24 18:49
Barium
pg/L
95.4
101
05/10/2419:49
Beryllium
pg/L
25.4
101
05/09/24 18:49
Cadmium
Ng/L
5.00
100
05/09/24 18:49
Chromium
Ng/L
56.3
105
05/09/24 18:49
Cobalt
pg/L
51.6
100
05/09/24 18:49
Copper
pg/L
27.5
102
05/09/24 18:49
Lead
pg/L
26.1
102
05/09/24 18:49
Nickel
pg/L
27.6
102
05/09/24 18:49
Selenium
pg/L
45.8
92.0
05/10/2419:49
Silver
pg/L
4.99
100
05/09/24 18:49
Thallium
pg/L
5.19
103
05/09/24 18:49
Vanadium
pg/L
246
97.0
05/10/2419:49
Zinc
pg/L
263
102
05/09/24 18:49
Date: 05/14/2024 05:41 PM Page 3 of 9
Page 64 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
• i
Way po�nt ^ 449 Spring#�rQok Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
Quality Control Data
Client ID:
Smith & Gardner, Inc.
Project Description:
Surry County MSW
Report No:
24-123-0100
QC Prep:
V46801
QC Analytical Batch(es): V46804
QC Prep Batch Method:
5030B
Analysis Method: 8260D SIM
Analysis Description: Volatile Organic Compounds - GC/MS
Lab Reagent Blank
LRB-V46801
Matrix: AQU
Associated Lab Samples:
92443, 92444, 92445, 92446, 92447, 92448,
92449, 92450, 92451, 92452, 92453, 92454
Blank MDL
MQL Analyzed % % Rec
Parameter
Units Result
Recovery Limits
1,4-Dioxane
pg/L <0.139 0.139
2.00 05/02/2416:13
4-Bromofluorobenzene (S)
05/02/24 16:13 103 70-130
Laboratory Control Sample LCS-V46801
Spike
LCS LCS %Rec % Rec
Parameter
Units Conc.
Result Limits
1,4-Dioxane pg/L
50.0 45.6
91.2
70-130
4-Bromofluorobenzene (S)
86.2
70-130
Matrix Spike & Matrix Spike Duplicate
V 92463-MS-V46801 V 92463-MSD-V46801
MS Spike MSD MS Result
MSD
MS MSD %Rec Max
Parameter Units
Result Conc. Spike
Result
%Rec %Rec Limits RPD RPD
Conc.
1,4-Dioxane pg/L < 0.139 50.0 50.0 46.7 50.4 93.4 101 70-130 7.6 20.0
4-Bromofluorobenzene (S) 106 97.8 70-130
Date: 05/14/2024 05:41 PM Page 4 of 9
Page 65 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
Client ID:
Project Description:
Report No:
Smith & Gardner, Inc.
Surry County MSW
24-123-0100
QC Prep: V47029
QC Prep Batch Method: 5030B
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
QC Analytical Batch(es): V47047
Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Lab Reagent Blank LRB-V47029 Matrix: AQU
Associated Lab Samples: 92443, 92444, 92445, 92446, 92447, 92448, 92449, 92450, 92451, 92452, 92453, 92454, 92455
Blank MDL MQL Analyzed % % Rec
Parameter Units Result Recovery Limits
Acetone
pg/L
<1.80
1.80
5.00
05/07/24 15:10
Acrylonitrile
pg/L
<0.230
0.230
5.00
05/07/24 15:10
Benzene
pg/L
<0.180
0.180
0.500
05/07/24 15:10
Bromochloromethane
pg/L
<0.420
0.420
1.00
05/07/24 15:10
Bromodichloromethane
pg/L
<0.160
0.160
0.500
05/07/24 15:10
Bromoform
pg/L
<1.50
1.50
5.00
05/07/24 15:10
Bromomethane
pg/L
<0.280
0.280
1.00
05/07/24 15:10
Carbon Disulfide
pg/L
<0.150
0.150
5.00
05/07/24 15:10
Carbon Tetrachloride
pg/L
<0.180
0.180
0.500
05/07/24 15:10
Chlorobenzene
pg/L
<0.190
0.190
0.500
05/07/24 15:10
Chlorodibromomethane
pg/L
<0.190
0.190
0.500
05/07/24 15:10
Chloroethane
pg/L
<0.430
0.430
1.00
05/07/24 15:10
Chloroform
pg/L
<0.220
0.220
0.500
05/07/24 15:10
Chloromethane
pg/L
<0.220
0.220
0.500
05/07/24 15:10
Di -Isopropyl Ether (DIPE)
pg/L
<0.960
0.960
5.00
05/07/24 15:10
1,2-Dibromo-3-Chloropropane
pg/L
< 1.10
1.10
2.00
05/07/24 15:10
1,2-Dibromoethane
pg/L
<0.200
0.200
0.500
05/07/24 15:10
Dibromomethane
pg/L
<0.230
0.230
0.500
05/07/24 15:10
trans-1,4-Dichloro-2-butene
pg/L
< 1.30
1.30
10.0
05/07/24 15:10
1,2-Dichlorobenzene
pg/L
<0.220
0.220
0.500
05/07/24 15:10
1,4-Dichlorobenzene
pg/L
<0.210
0.210
0.500
05/07/24 15:10
Dichlorodifluoromethane
pg/L
<1.20
1.20
5.00
05/07/24 15:10
1,1-Dichloroethane
pg/L
<0.240
0.240
0.500
05/07/24 15:10
1,2-Dichloroethane
pg/L
<0.150
0.150
0.500
05/07/24 15:10
1,1-Dichloroethene
pg/L
<0.150
0.150
0.500
05/07/24 15:10
cis-1,2-Dichloroethene
pg/L
<0.200
0.200
0.500
05/07/24 15:10
trans-1,2-Dichloroethene
pg/L
<0.180
0.180
0.500
05/07/24 15:10
Date:
05/14/2024 05:41 PM
Page 5 of 9
Page 66 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
Client ID:
Project Description:
Report No:
Smith & Gardner, Inc.
Surry County MSW
24-123-0100
QC Prep: V47029
QC Prep Batch Method: 5030B
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
QC Analytical Batch(es): V47047
Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Lab Reagent Blank LRB-V47029 Matrix: AQU
Associated Lab Samples: 92443, 92444, 92445, 92446, 92447, 92448, 92449, 92450, 92451, 92452, 92453, 92454, 92455
Blank
MDL
MQL
Analyzed
% % Rec
Parameter
Units
Result
Recovery Limits
1,2-Dichloropropane
pg/L
<0.190
0.190
0.500
05/07/24 15:10
cis-1,3-Dichloropropene
pg/L
<0.210
0.210
0.500
05/07/24 15:10
trans-1,3-Dichloropropene
pg/L
<0.150
0.150
0.500
05/07/24 15:10
1,4-Dioxane
pg/L
<16.0
16.0
150
05/07/24 15:10
Ethylbenzene
pg/L
<0.170
0.170
0.500
05/07/24 15:10
2-Hexanone
pg/L
<0.380
0.380
5.00
05/07/24 15:10
Methyl Ethyl Ketone (MEK)
pg/L
<0.710
0.710
5.00
05/07/24 15:10
4-Methyl-2-Pentanone
pg/L
<1.00
1.00
5.00
05/07/24 15:10
Methylene Chloride
pg/L
<0.330
0.330
1.00
05/07/24 15:10
Styrene
pg/L
<0.220
0.220
0.500
05/07/24 15:10
1,1,1,2-Tetrachloroethane
pg/L
<0.160
0.160
0.500
05/07/24 15:10
1,1,2,2-Tetrachloroethane
pg/L
<0.160
0.160
0.500
05/07/24 15:10
Tetrachloroethene
pg/L
<0.220
0.220
0.500
05/07/24 15:10
Tetrahydrofuran
pg/L
<1.50
1.50
10.0
05/07/24 15:10
Toluene
pg/L
<0.220
0.220
0.500
05/07/24 15:10
1,1,1-Trichloroethane
pg/L
<0.160
0.160
0.500
05/07/24 15:10
1,1,2-Trichloroethane
pg/L
<0.096
0.096
0.500
05/07/24 15:10
Trichloroethene
pg/L
<0.180
0.180
0.500
05/07/24 15:10
Trichlorofluoromethane
pg/L
<0.180
0.180
0.500
05/07/24 15:10
1,2,3-Trichloropropane
pg/L
<0.270
0.270
1.00
05/07/24 15:10
Vinyl Acetate
pg/L
<1.00
1.00
2.00
05/07/24 15:10
Vinyl Chloride
pg/L
<0.170
0.170
0.500
05/07/24 15:10
o-Xylene
pg/L
<0.210
0.210
0.500
05/07/24 15:10
m,p-Xylene
pg/L
<0.420
0.420
1.00
05/07/24 15:10
4-Bromofluorobenzene (S)
05/07/24 15:10
95.2 80-124
Dibromofluoromethane (S)
05/07/24 15:10
97.0 75-129
1,2-Dichloroethane - d4 (S)
05/07/24 15:10
91.2 63-136
Date:
05/14/2024 05:41 PM
Page 6 of 9
Page 67 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
Client ID:
Project Description:
Report No:
Smith & Gardner, Inc.
Surry County MSW
24-123-0100
QC Prep: V47029
QC Prep Batch Method: 5030B
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
QC Analytical Batch(es): V47047
Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Lab Reagent Blank LRB-V47029 Matrix: AQU
Associated Lab Samples: 92443, 92444, 92445, 92446, 92447, 92448, 92449, 92450, 92451, 92452, 92453, 92454, 92455
Blank MDL MQL Analyzed % % Rec
Parameter Units Result Recovery Limits
Toluene-d8(S) 05/07/24 15:10 102 77-123
Laboratory Control Sample & LCSD
Parameter Units
LCS-V47029
Spike
Conc.
LCSD-V47029
LCS
Result
LCSD
Result
LCS
%Rec
LCSD
a/o Rec
% Rec
Limits
RPD
Max
RPD
Acetone
pg/L
40.0
39.7
57.7
99.2
144
40-166
36.9*
20.0
Acrylonitrile
pg/L
40.0
38.1
31.6
95.2
79.0*
81-127
18.6
20.0
Benzene
pg/L
20.0
22.5
20.9
113
105
77-128
7.3
20.0
Bromochloromethane
pg/L
20.0
20.6
19.2
103
96.0
78-135
7.0
20.0
Bromodichloromethane
pg/L
20.0
20.8
18.8
104
94.0
76-138
10.1
20.0
Bromoform
pg/L
20.0
20.1
17.3
101
86.5
71-135
14.9
20.0
Bromomethane
pg/L
20.0
24.4
24.1
122
121
41-168
1.2
20.0
Carbon Disulfide
pg/L
20.0
23.1
21.8
116
109
59-135
5.7
20.0
Carbon Tetrachloride
pg/L
20.0
20.9
19.8
105
99.0
72-142
5.4
20.0
Chlorobenzene
pg/L
20.0
22.8
21.3
114
107
78-119
6.8
20.0
Chlorodibromomethane
pg/L
20.0
21.3
20.1
107
101
75-134
5.7
20.0
Chloroethane
pg/L
20.0
25.5
24.3
128
122
57-142
4.8
20.0
Chloroform
pg/L
20.0
21.2
20.2
106
101
77-130
4.8
20.0
Chloromethane
pg/L
20.0
23.3
21.8
117
109
47-145
6.6
20.0
Di -Isopropyl Ether (DIPE)
pg/L
20.0
22.4
21.0
112
105
60-154
6.4
20.0
1,2-Dibromo-3-Chloropropane
pg/L
20.0
20.8
16.6
104
83.0
63-134
22.4*
20.0
1,2-Dibromoethane
pg/L
20.0
21.1
19.6
106
98.0
77-135
7.3
20.0
Dibromomethane
pg/L
20.0
21.6
19.4
108
97.0
76-138
10.7
20.0
trans-1,4-Dichloro-2-butene
pg/L
20.0
14.1
12.4
70.5
62.0*
70-130
12.8
20.0
1,2-Dichlorobenzene
pg/L
20.0
22.1
20.7
111
104
78-128
6.5
20.0
1,4-Dichlorobenzene
pg/L
20.0
22.3
20.6
112
103
75-126
7.9
20.0
* QC Fail Date: 05/14/2024 05:41 PM Page 7 of 9
Page 68 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Waypointo
ANALYTICAL
Client ID:
Project Description:
Report No:
Smith & Gardner, Inc.
Surry County MSW
24-123-0100
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
QC Prep: V47029 QC Analytical Batch(es): V47047
QC Prep Batch Method: 5030B Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Laboratory Control Sample & LCSD LCS-V47029 LCSD-V47029
Parameter
Units
Spike
Conc.
LCS
Result
LCSD
Result
LCS
%Rec
LCSD
% Rec
% Rec
Limits
RPD
Max
RPD
Dichlorodifluoromethane
pg/L
20.0
25.7
24.7
129
124
28-163
3.9
20.0
1,1-Dichloroethane
pg/L
20.0
22.0
20.7
110
104
70-130
6.0
20.0
1,2-Dichloroethane
pg/L
20.0
20.0
19.0
100
95.0
68-131
5.1
20.0
1,1-Dichloroethene
pg/L
20.0
22.7
21.3
114
107
70-154
6.3
20.0
cis-1,2-Dichloroethene
pg/L
20.0
21.4
19.9
107
99.5
76-141
7.2
20.0
trans-1,2-Dichloroethene
pg/L
20.0
22.0
19.7
110
98.5
76-135
11.0
20.0
1,2-Dichloropropane
pg/L
20.0
21.9
20.9
110
105
77-130
4.6
20.0
cis-1,3-Dichloropropene
pg/L
20.0
21.2
19.4
106
97.0
65-140
8.8
20.0
trans-1,3-Dichloropropene
pg/L
20.0
20.5
18.8
103
94.0
67-140
8.6
20.0
1,4-Dioxane
pg/L
200
225
169
113
84.5
70-130
28.4*
20.0
Ethylbenzene
pg/L
20.0
22.4
21.0
112
105
80-127
6.4
20.0
2-Hexanone
pg/L
20.0
25.1
20.6
126
103
64-137
19.6
20.0
Methyl Ethyl Ketone (MEK)
pg/L
20.0
25.3
20.0
127
100
71-134
23.3*
20.0
4-Methyl-2-Pentanone
pg/L
20.0
19.8
16.4
99.0
82.0
69-134
18.7
20.0
Methylene Chloride
pg/L
20.0
21.7
20.1
109
101
73-131
7.6
20.0
Styrene
pg/L
20.0
22.4
21.0
112
105
78-129
6.4
20.0
1,1,1,2-Tetrachloroethane
pg/L
20.0
21.2
20.3
106
102
79-134
4.3
20.0
1,1,2,2-Tetrachloroethane
pg/L
20.0
20.5
19.0
103
95.0
62-127
7.5
20.0
Tetrachloroethene
pg/L
20.0
22.1
20.5
111
103
80-129
7.5
20.0
Tetrahydrofuran
pg/L
20.0
21.3
17.2
107
86.0
70-130
21.2*
20.0
Toluene
pg/L
20.0
22.2
20.7
111
104
76-131
6.9
20.0
1,1,1-Trichloroethane
pg/L
20.0
20.8
19.1
104
95.5
75-135
8.5
20.0
1,1,2-Trichloroethane
pg/L
20.0
21.1
18.5
106
92.5
70-140
13.1
20.0
Trichloroethene
pg/L
20.0
21.6
20.6
108
103
77-133
4.7
20.0
Trichlorofluoromethane
pg/L
20.0
19.8
19.4
99.0
97.0
62-148
2.0
20.0
1,2,3-Trichloropropane
pg/L
20.0
22.1
19.6
111
98.0
71-127
11.9
20.0
* QC Fail Date: 05/14/2024 05:41 PM Page 8 of 9
Page 69 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
• i
Way po�nt ^ 449 Spring#�rQok Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
Quality Control Data
Client ID:
Smith & Gardner, Inc.
Project Description:
Surry County MSW
Report No:
24-123-0100
QC Prep:
V47029
QC Analytical Batch(es): V47047
QC Prep Batch Method:
5030B
Analysis Method:
8260D
Analysis Description:
Volatile Organic Compounds - GC/MS
Laboratory Control Sample
& LCSD
LCS-V47029
LCSD-V47029
Spike
LCS LCSD
LCS
LCSD
% Rec
Parameter
Units
Conc.
Result Result
%Rec
% Rec
Limits
RPD
Max
RPD
Vinyl Acetate
pg/L
20.0
20.1 17.6
101
88.0
34-167
13.2
20.0
Vinyl Chloride
pg/L
20.0
23.0 21.2
115
106
57-141
8.1
20.0
o-Xylene
pg/L
20.0
22.4 21.2
112
106
78-128
5.5
20.0
m,p-Xylene
pg/L
40.0
47.3 44.5
118
111
77-133
6.1
20.0
4-Bromofluorobenzene (S)
96.4
96.2
80-124
Dibromofluoromethane (S)
97.6
96.6
75-129
1,2-Dichloroethane - d4 (S)
93.6
90.2
63-136
Toluene-d8(S)
104
103
77-123
Date: 05/14/2024 05:41 PM Page 9 of 9
Page 70 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
WayPAo0nt..
NALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.wa y p of n to na lyti ca I.c om
Shipment Receipt Form
Customer Number: 01186
Customer Name: Smith & Gardner, Inc.
Report Number: 24-123-0100
Shipping Method
0 Fed Ex 0 US Postal 0 Lab 0 Other:
0 UPS 0 Client # Courier Thermometer ID: IRT15 1.0C
Shipping container/cooler uncompromised?
0 Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
(*� Yes
0 No
0 Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
Yes
0 No
COC agrees with sample label(s)?
Yes
0 No
COC properly completed
Yes
0 No
Samples in proper containers?
Yes
0 No
Sample containers intact?
0 Yes
0 No
Sufficient sample volume for indicated test(s)?
Yes
0 No
All samples received within holding time?
Yes
0 No
Cooler temperature in compliance?
0 Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes
0 No
Water - Sample containers properly preserved
Yes
0 No
0 N/A
Water - VOA vials free of headspace
Yes
0 No
0 N/A
Trip Blanks received with VOAs
Yes
0 No
0 N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F High concentration container (48 hr) F_ Low concentration EnCore samplers (48 hr)
F_ High concentration pre -weighed (methanol -14 d) Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included?
0 Yes
0 No
Comments
Signature: Angela D Overcash Date & Time: 05/02/2024 11:54:48
Page 71 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
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Page 73 of 73
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
eurofins
Environment Testing
I ANALYTICAL REPORT C
PREPARED FOR
Attn: Daniel Pantaleo
Smith Gardner Inc
14 N Boylan Avenue C
Raleigh, North Carolina 27603
Generated 5/22/2024 5:13:22 PM
JOB DESCRIPTION
Surry C&D/MSW (Permit 8602)
6 JOB NUMBER
752-19362-1
I
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
This report may not be reproduced except in full, and with written approval from the laboratory. The results relate only to the
samples tested. For questions please contact the Project Manager at the e-mail address or telephone number listed on this
page.
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the
methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written
approval of the laboratory. All questions should be directed to the Eurofins Environment Testing Southeast, LLC Project
Manager.
Generated
YAA�� 5/22/2024 5:13:22 PM
Authorized for release by
John Andros, Project Manager I
John.AndrosCa).et.eurofinsus.com
Designee for
Heather Trotter, Project Manager
Heather.TrotterCa_)et.eurofinsus.com
(912)354-7858
Eurofins Raleigh is a laboratory within Eurofins Environment Testing Southeast, LLC, a company within Eurofins Environment Testing Group of Companies
Page 2 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Table of Contents
Laboratory Job ID: 752-19362-1
Cover Page ..............................................
1
Table of Contents .........................................
3
Definitions/Glossary.......................................
4 L
Case Narrative ...........................................
5
Detection Summary ........................................
6
Client Sample Results ......................................
11
Isotope Dilution Summary ...................................
51
E:
QC Sample Results ........................................
55
QC Association Summary ...................................
79 F
Lab Chronicle ............................................
81
Certification Summary ......................................
85
Method Summary .........................................
87
Sample Summary .........................................
88
Chain of Custody ..........................................
89
E:
Receipt Checklists .........................................
91
Eurofins Raleigh
Page 3 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Definitions/Glossary
Client: Smith Gardner Inc Job ID: 752-19362-1
Project/Site: Surry
C&D/MSW (Permit 8602)
Qualifiers
LCMS
Qualifier
Qualifier Description
LCS and/or LCSD is outside acceptance limits, low biased.
*+
LCS and/or LCSD is outside acceptance limits, high biased.
*1
LCS/LCSD RPD exceeds control limits.
*5-
Isotope dilution analyte is outside acceptance limits, low biased.
*5+
Isotope dilution analyte is outside acceptance limits, high biased.
B
Compound was found in the blank and sample.
I
Value is EMPC (estimated maximum possible concentration).
J
Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Glossary
Abbreviation These commonly used abbreviations may or may not be present in this report.
c Listed under the "D" column to designate that the result is reported on a dry weight basis
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
oil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Lever'
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
MIL Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRIES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins Raleigh
Page 4 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Case Narrative
Client: Smith Gardner Inc Job ID: 752-19362-1
Project: Surry C&D/MSW (Permit 8602)
Job ID: 752-19362-1 Eurofins Raleigh
Job Narrative
752-19362-1 '
Receipt
The samples were received on 5/3/2024 9:50 AM. Unless otherwise noted below, the samples arrived in good condition, and,
where required, properly preserved and on ice. The temperature of the cooler at receipt time was 3.0°C.
Receipt Exceptions
The lab didn't receive MW-16, SW-3, and MW-15. The lab received a sample that wasn't on the COC, MW-14. Date and time came
from the containers for MW-14
PFAS
Method 1633: The following samples were diluted due to the nature of the sample matrix: MW-23 (752-19362-5), MW-19
(752-19362-6), MW-3R (752-19362-9), MW-20 (752-19362-11) and MW-9 (752-19362-14). Elevated reporting limits (RLs) are
provided.
Method 1633: Isotope Dilution Analyte (IDA) recovery is above the method recommended limit for the following samples: MW-21
(752-19362-12) and MW-9 (752-19362-14). Quantitation by isotope dilution generally precludes any adverse effect on data quality
due to elevated IDA recoveries.
Method 1633: The laboratory control sample duplicate (LCSD) for preparation batch 680-837934 and analytical batch 680-838185
recovered outside control limits for the following analytes: Perfluorododecanesulfonic acid (PFDoS). A low-level LCS (LLCS),
spiked at the reporting limit (RL), was prepared with this batch. The affected target analytes recovered within acceptance limits;
therefore, the LLCS demonstrates the analytical system had sufficient sensitivity to detect the compounds had they been present.
Since the affected target compounds were not detected in the samples, the data have been reported and qualified.
Method 1633: The laboratory control sample (LCS) and / or laboratory control sample duplicate (LCSD) for preparation batch
680-837934 and analytical batch 680-838185 recovered outside control limits for the following analytes: Perfluorodecanoic acid
(PFDA). These analytes were biased high in the LCS and were not detected in the associated samples; therefore, the data have
been reported.
Method 1633: The low level laboratory control sample (LLCS) for preparation batch 680-837934 and analytical batch 680-838185
recovered outside control limits for the following analytes: Perfluorodecanoic acid (PFDA). These analytes were biased high in the
LLCS and were not detected in the associated samples; therefore, the data have been reported.
Method 1633: The laboratory control sample, duplicate, and low level (LCS/LCSD/LLCS) for preparation batch 680-837934 and
analytical batch 680-838185 recovered outside control limits for the following analytes: Perfluorooctanesulfonic acid (PFOS).
These analytes were biased high in the LCS and were not detected in the associated samples; therefore, the data have been
reported.
Method 1633: The method blank for preparation batch 680-837934 contained Perfluorooctanesulfonic acid (PFOS) above the
reporting limit (RL). None of the samples associated with this method blank contained the target compound; therefore, re -
extraction and/or re -analysis of samples were not performed.
Method 1633: The laboratory control sample (LCS) for preparation batch 680-838358 and analytical batch 680-838415 recovered
outside control limits for the following analytes: Perfluorododecanesulfonic acid (PFDoS). A low-level LCS (LLCS), spiked at the
reporting limit (RL), was prepared with this batch. The affected target analytes recovered within acceptance limits; therefore, the
LLCS demonstrates the analytical system had sufficient sensitivity to detect the compounds had they been present. Since the
affected target compounds were not detected in the samples, the data have been reported and qualified.
Method 1633: Isotope Dilution Analyte (IDA) recovery is above the method recommended limit for the following samples: MW-1
(752-19362-16), MW-11 (752-19362-17) and MW-14 (752-19362-23). Quantitation by isotope dilution generally precludes any
adverse effect on data quality due to elevated IDA recoveries.
Method 1633: The Isotope Dilution Analyte (IDA) recovery associated with the following sample is below the method recommended
limit: MW-17 (752-19362-8). Generally, data quality is not considered affected if the IDA signal-to-noise ratio is greater than 10:1,
which is achieved for all IDA in the sample(s).
No additional analytical or quality issues were noted, other than those described above or in the Definitions/ Glossary page.
Eurofins Raleigh
Page 5 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Detection Summary
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Client Sample ID: MW-7
Analyte
Perfluorobutanoic acid (PFBA)
Perfluoropentanoic acid (PFPeA)
Perfluorohexanoic acid (PFHxA)
Perfluoroheptanoic acid (PFHpA)
Perfluorooctanoic acid (PFDA)
Perfluorononanoic acid (PFNA)
Perfluorodecanoic acid (PFDA)
Perfluorobutanesulfonic acid (PFBS)
Perfluoropentanesulfonic acid
(PFPeS)
Perfluorohexanesulfonic acid (PFHxS)
Perfluoroheptanesulfonic acid
(PFHpS)
Perfluorooctanesulfonic acid (PFOS)
1 H,1 H,2H,2H-Perfluorooctane sulfonic
acid (6:2 FTS)
N-methylperfl uorooctanesu Ifonamidoa
cetic acid (NMeFOSAA)
N-ethyl perfluorooctanesulfonamidoac
etic acid (NEtFOSAA)
Result
Qualifier
RL
MDL
Unit
32
2.8
0.71
ng/L
72
1.4
0.35
ng/L
75
1.4
0.071
ng/L
45
1.4
0.35
ng/L
110
1.4
0.35
ng/L
2.8
1.4
0.071
ng/L
0.57
J .+
1.4
0.071
ng/L
11
1.4
0.35
ng/L
9.4
1.4
0.071
ng/L
31
1.4
0.35
ng/L
1.1
J
1.4
0.071
ng/L
25
1.4
0.34
ng/L
4.4
2.8
0.35
ng/L
0.83
J
1.4
0.35
ng/L
0.80
J
1.4
0.35
ng/L
Client Sample ID: MW-6
Analyte
Result Qualifier
Perfluorobutanoic acid (PFBA)
13
Perfluoropentanoic acid (PFPeA)
26
Perfluorohexanoic acid (PFHxA)
29
Perfluoroheptanoic acid (PFHpA)
16
Perfluorooctanoic acid (PFDA)
38
Perfluorononanoic acid (PFNA)
1.1 J
Perfluorobutanesulfonic acid (PFBS)
8.4
Perfluoropentanesulfonic acid
5.6
(PFPeS)
Perfluorohexanesulfonic acid (PFHxS)
25
Perfluorooctanesulfonic acid (PFOS)
11
1H,1H,2H,2H-PerFluorooctanesulfonic
1.7 J
acid (6:2 FTS)
Client Sample ID: MW-12S
F
Job ID: 752-19362-1
Lab Sample ID: 752-19362-1
Dil Fac D
Method
Prep Type
1
1633
Total/NA
1
1633
Total/NA
1
1633
Total/NA
1
1633
Total/NA
1
1633
Total/NA
1
1633
Total/NA
1
1633
Total/NA
1
1633
Total/NA
1
1633
Total/NA
1
1633
Total/NA
1
1633
Total/NA
1
1633
Total/NA
1
1633
Total/NA
1 1633 Total/NA
1 1633 Total/NA
Lab Sample ID: 752-19362-2
RL
MDL
Unit
oil Fac D
Method
Prep Type
3.7
0.92
ng/L
1
1633
Total/NA
1.8
0.46
ng/L
1
1633
Total/NA 7
1.8
0.092
ng/L
1
1633
Total/NA
1.8
0.46
ng/L
1
1633
Total/NA
1.8
0.46
ng/L
1
1633
Total/NA
1.8
0.092
ng/L
1
1633
Total/NA
1.8
0.46
ng/L
1
1633
Total/NA
1.8
0.092
ng/L
1
1633
Total/NA
1.8
0.46
ng/L
1
1633
Total/NA
1.4
0.35
ng/L
1
1633
Total/NA
3.7
0.46
ng/L
1
1633
Total/NA
Lab Sample ID: 752-19362-3
Analyte
Result Qualifier
RL
MDL
Unit
Dil Fac D
Method
Prep Type
Perfluorobutanoic acid (PFBA)
8.4
2.8
0.71
ng/L
1
1633
Total/NA
Perfluoropentanoic acid (PFPeA)
4.6
1.4
0.35
ng/L
1
1633
Total/NA
Perfluorohexanoic acid (PFHxA)
6.5
1.4
0.071
ng/L
1
1633
Total/NA
Perfluoroheptanoic acid (PFHpA)
1.8
1.4
0.35
ng/L
1
1633
Total/NA
Perfluorooctanoic acid (PFDA)
1.9
1.4
0.35
ng/L
1
1633
Total/NA
Perfluorobutanesulfonic acid (PFBS)
1.9
1.4
0.35
ng/L
1
1633
Total/NA
Perfluoropentanesulfonic acid
0.37 J
1.4
0.071
ng/L
1
1633
Total/NA
(PFPeS)
Perfluorohexanesulfonic acid (PFHxS)
1.5
1.4
0.35
ng/L
1
1633
Total/NA
Perfluorooctanesulfonic acid (PFOS)
0.85 J
1.4
0.35
ng/L
1
1633
Total/NA
This Detection Summary does not include radiochemical test results.
Page 6 of 92
Eurofins Raleigh
5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Detection Summary
Client: Smith Gardner Inc
Job ID: 752-19362-1
Project/Site: Surry C&D/MSW (Permit 8602)
Client Sample ID: MW-13
Lab Sample ID: 752-19362-4
Analyte
Result
Qualifier
RL
MDL
Unit
Dil Fac D Method Prep Type
Perfluorobutanoic acid (PFBA)
29
2.8
0.70
ng/L
1 1633 Total/NA
Perfluoropentanoic acid (PFPeA)
47
1.4
0.35
ng/L
1 1633 Total/NA
Perfluorohexanoic acid (PFHxA)
130
1.4
0.070
ng/L
1 1633 Total/NA
Perfluoroheptanoic acid (PFHpA)
17
1.4
0.35
ng/L
1 1633 Total/NA
Perfluorooctanoic acid (PFOA)
17
1.4
0.35
ng/L
1 1633 Total/NA
Perfluorobutanesulfonic acid (PFBS)
6.1
1.4
0.35
ng/L
1 1633 Total/NA
Perfluoropentanesulfonic acid
1.4
1.4
0.070
ng/L
1 1633 Total/NA
(PFPeS)
Perfluorohexanesulfonic acid (PFHxS)
9.2
1.4
0.35
ng/L
1 1633 Total/NA
1H,1H,2H,2H-Perfluorooctanesulfonic
1.0
J
2.8
0.35
ng/L
1 1633 Total/NA
acid (6:2 FTS)
Client Sample ID: MW-23
Lab Sample ID: 752-19362-5
Cmalyte
Result
Qualifier
RL
MDL
Unit
Dil Fac D Method Prep Type
Perfluorohexanoic acid (PFHxA)
6.4
J
19
0.95
ng/L
1 1633 Total/NA
Client Sample ID: MW-19
Lab Sample ID: 752-19362-6
Analyte
Result
Qualifier
RL
MDL
Unit
oil Fac D Method Prep Type
Perfluorohexanoic acid (PFHxA)
6.7
4.1
0.20
ng/L
1 1633 Total/NA
Client Sample ID: MW-22
Lab Sample ID: 752-19362-7
Analyte
Result
Qualifier
RL
MDL
Unit
Dil Fac D Method Prep Type I
Perfluorobutanoic acid (PFBA)
5.4
2.8
0.71
ng/L
1 1633 Total/NA
Perfluorohexanoic acid (PFHxA)
16
1.4
0.071
ng/L
1 1633 Total/NA
Perfluoroheptanoic acid (PFHpA)
1.8
1.4
0.35
ng/L
1 1633 Total/NA
Perfluorooctanoic acid (PFOA)
3.6
1.4
0.35
ng/L
1 1633 Total/NA
Perfluorobutanesulfonic acid (PFBS)
1.1
J
1.4
0.35
ng/L
1 1633 Total/NA
Perfluoropentanesulfonic acid
0.41
J
1.4
0.071
ng/L
1 1633 Total/NA
(PFPeS)
Perfluorohexanesulfonic acid (PFHxS)
0.95
J
1.4
0.35
ng/L
1 1633 Total/NA
Perfluorooctanesulfonic acid (PFOS)
0.61
J <+ B
1.4
0.35
ng/L
1 1633 Total/NA
Client Sample ID: MW-17
Lab Sample ID: 752-19362-8
Analyte
Result
Qualifier
RL
MDL
Unit
oil Fac D Method Prep Type
Perfluorobutanoic acid (PFBA)
21
2.7
0.68
ng/L
1 1633 Total/NA
Perfluoropentanoic acid (PFPeA)
27
1.4
0.34
ng/L
1 1633 Total/NA
Perfluorohexanoic acid (PFHxA)
59
1.4
0.068
ng/L
1 1633 Total/NA
Perfluoroheptanoic acid (PFHpA)
15
1.4
0.34
ng/L
1 1633 Total/NA
Perfluorooctanoic acid (PFOA)
19
1.4
0.34
ng/L
1 1633 Total/NA
Perfluorononanoic acid (PFNA)
0.39
J
1.4
0.068
ng/L
1 1633 Total/NA
Perfluorobutanesulfonic acid (PFBS)
14
1.4
0.34
ng/L
1 1633 Total/NA
Perfluoropentanesulfonic acid
9.4
1.4
0.068
ng/L
1 1633 Total/NA
(PFPeS)
Perfluorohexanesulfonic acid (PFHxS)
39
1.4
0.34
ng/L
1 1633 Total/NA
Perfluorooctanesulfonic acid (PFOS)
39
1.4
0.34
ng/L
1 1633 Total/NA
Client Sample ID: MW-3R
Lab Sample ID: 752-19362-9
Analyte
Result
Qualifier
RL
MDL
Unit
oil Fac D Method Prep Type
Perfluorobutanoic acid (PFBA)
29
J
40
10
ng/L
1 1633 Total/NA
This Detection Summary does not include radiochemical test results.
Eurofins Raleigh
Page 7 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Detection Summary
Client: Smith Gardner Inc
Job ID: 752-19362-1
Project/Site: Surry C&D/MSW (Permit 8602)
Client Sample ID: MW-3R (Continued)
Lab Sample
ID: 752-19362-9
Analyte
Result
Qualifier
RL
MDL
Unit
oil Fac
D Method
Prep Type
Perfluorohexanoic acid (PFHxA)
67
20
1.0
ng/L
1
1633
Total/NA
Perfluoroheptanoic acid (PFHpA)
16
J
20
5.0
ng/L
1
1633
Total/NA
Perfluorooctanoic acid (PFOA)
25
20
5.0
ng/L
1
1633
Total/NA
Perfluoropentanesulfonic acid
2.1
J
20
1.0
ng/L
1
1633
Total/NA
(PFPeS)
Perfluorohexanesulfonic acid (PFHxS)
22
20
5.0
ng/L
1
1633
Total/NA
Client Sample ID: SW-4
Lab Sample
ID: 752-19362-10
Analyte
Result
Qualifier
RL
MDL
Unit
oil Fac
D Method
Prep Type
Perfluorobutanoic acid (PFBA)
2.0
J
2.8
0.71
ng/L
1
1633
Total/NA
Perfluoropentanoic acid (PFPeA)
3.0
1.4
0.36
ng/L
1
1633
Total/NA
Perfluorohexanoic acid (PFHxA)
3.8
1.4
0.071
ng/L
1
1633
Total/NA
Perfluoroheptanoic acid (PFHpA)
1.4
1.4
0.36
ng/L
1
1633
Total/NA
Perfluorooctanoic acid (PFOA)
2.3
1.4
0.36
ng/L
1
1633
Total/NA
Perfluorononanoic acid (PFNA)
0.12
J
1.4
0.071
ng/L
1
1633
Total/NA
Perfluorobutanesulfonic acid (PFBS)
1.2
J
1.4
0.36
ng/L
1
1633
Total/NA
Perfluoropentanesulfonic acid
0.62
J
1.4
0.071
ng/L
1
1633
Total/NA
(PFPeS)
Perfluorohexanesulfonic acid (PFHxS)
2.4
1.4
0.36
ng/L
1
1633
Total/NA
Perfluorooctanesulfonic acid (PFOS)
2.3
1.4
0.35
ng/L
1
1633
Total/NA
Client Sample ID: MW-20
Lab Sample ID: 752-19362-11
Analyte
Result
Qualifier
RL
MDL
Unit
Dill Fac
D Method
Prep Type
Perfluorobutanoic acid (PFBA)
11
8.1
2.0
ng/L
1
1633
Total/NA
Perfluorohexanoic acid (PFHxA)
11
4.0
0.20
ng/L
1
1633
Total/NA
Perfluoroheptanoic acid (PFHpA)
3.9
J
4.0
1.0
ng/L
1
1633
Total/NA
Perfluorooctanoic acid (PFOA)
3.9
J
4.0
1.0
ng/L
1
1633
Total/NA
Perfluorobutanesulfonic acid (PFBS)
1.6
J
4.0
1.0
ng/L
1
1633
Total/NA
Perfluoropentanesulfonic acid
0.83
J
4.0
0.20
ng/L
1
1633
Total/NA
(PFPeS)
Perfluorohexanesulfonic acid (PFHxS)
1.1
J
4.0
1.0
ng/L
1
1633
Total/NA
Client Sample ID: MW-21
Lab Sample
ID: 752-19362-12
Analyte
Result
Qualifier
RL
MDL
Unit
Dill Fac
D Method
Prep Type
Perfluorobutanoic acid (PFBA)
24
2.8
0.71
ng/L
1
1633
Total/NA
Perfluoropentanoic acid (PFPeA)
42
1.4
0.35
ng/L
1
1633
Total/NA
Perfluorohexanoic acid (PFHxA)
120
1.4
0.071
ng/L
1
1633
Total/NA
Perfluoroheptanoic acid (PFHpA)
15
1.4
0.35
ng/L
1
1633
Total/NA
Perfluorooctanoic acid (PFOA)
13
1.4
0.35
ng/L
1
1633
Total/NA
Perfluoropentanesulfonic acid
1.6
1.4
0.071
ng/L
1
1633
Total/NA
(PFPeS)
Perfluorohexanesulfonic acid (PFHxS)
8.2
1.4
0.35
ng/L
1
1633
Total/NA
1H,1H,2H,2H-Periluorooctanesulfonic
0.90
J
2.8
0.35
ng/L
1
1633
Total/NA
acid (6:2 FTS)
Client Sample ID: SW-1
Lab Sample
ID: 752-19362-13
Analyte
Result
Qualifier
RL
MDL
Unit
Dil Fac
D Method
Prep Type
Perfluorobutanoic acid (PFBA)
1.2
J
2.9
0.72
ng/L
1
1633
Total/NA
Perfluorohexanoic acid (PFHxA)
3.7
1.4
0.072
ng/L
1
1633
Total/NA
Perfluoroheptanoic acid (PFHpA)
0.55
J
1.4
0.36
ng/L
1
1633
Total/NA
This Detection Summary does not include radiochemical test results.
Eurofins Raleigh
Page 8 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Detection Summary
Client: Smith Gardner Inc
Job ID: 752-19362-1
Project/Site: Surry C&D/MSW (Permit 8602)
Client Sample ID: SW-1 (Continued)
Lab Sample
ID: 752-19362-13
Analyte
Result
Qualifier
RL
MDL
Unit
Dil Fac
D Method
Prep Type
Perfluorooctanoic acid (PFOA)
0.89
J
1.4
0.36
ng/L
1
1633
Total/NA
Perfluorobutanesulfonic acid (PFBS)
1.1
J
1.4
0.36
ng/L
1
1633
Total/NA
Perfluoropentanesulfonic acid
0.16
J
1.4
0.072
ng/L
1
1633
Total/NA
(PFPeS)
Perfluorohexanesulfonic acid (PFHxS)
0.72
J
1.4
0.36
ng/L
1
1633
Total/NA
Client Sample ID: MW-9
Lab Sample
ID: 752-19362-14
Analyte
Result
Qualifier
RL
MDL
Unit
Dil Fac
D Method
Prep Type
Perfluorobutanoic acid (PFBA)
16
8.0
2.0
ng/L
1
1633
Total/NA
Perfluorohexanoic acid (PFHxA)
17
4.0
0.20
ng/L
1
1633
Total/NA
Perfluoroheptanoic acid (PFHpA)
6.5
4.0
1.0
ng/L
1
1633
Total/NA
Perfluorooctanoic acid (PFOA)
6.4
4.0
1.0
ng/L
1
1633
Total/NA
Perfluorohexanesulfonic acid (PFHxS)
1.8
J
4.0
1.0
ng/L
1
1633
Total/NA
Client Sample ID: SW-2
Lab Sample
ID: 752-19362-15
Analyte
Result
Qualifier
RL
MDL
Unit
Dil Fac
D Method
Prep Type
Perfluorobutanoic acid (PFBA)
6.1
3.5
0.87
ng/L
1
1633
Total/NA
Perfluorohexanoic acid (PFHxA)
3.3
1.7
0.087
ng/L
1
1633
Total/NA
Perfluoroheptanoic acid (PFHpA)
1.7
1.7
0.43
ng/L
1
1633
Total/NA
Perfluorooctanoic acid (PFOA)
1.3
J
1.7
0.43
ng/L
1
1633
Total/NA
Perfluorobutanesulfonic acid (PFBS)
0.78
J
1.7
0.43
ng/L
1
1633
Total/NA
Perfluoropentanesulfonic acid
0.31
J
1.7
0.087
ng/L
1
1633
Total/NA
(PFPeS)
Perfluorohexanesulfonic acid (PFHxS)
0.54
J
1.7
0.43
ng/L
1
1633
Total/NA
Client Sample ID: MW-1
Lab Sample
ID: 752-19362-16
Analyte
Result
Qualifier
RL
MDL
Unit
Dil Fac
D Method
Prep Type
Perfluorobutanoic acid (PFBA)
4.7
2.7
0.68
ng/L
1
1633
Total/NA
Perfluorohexanoic acid (PFHxA)
1.8
1.4
0.068
ng/L
1
1633
Total/NA
Perfluoroheptanoic acid (PFHpA)
1.7
1
1.4
0.34
ng/L
1
1633
Total/NA
Perfluorooctanoic acid (PFOA)
4.4
1.4
0.34
ng/L
1
1633
Total/NA
Perfluorobutanesulfonic acid (PFBS)
1.9
1.4
0.34
ng/L
1
1633
Total/NA
Perfluoropentanesulfonic acid
0.40
J
1.4
0.068
ng/L
1
1633
Total/NA
(PFPeS)
Perfluorohexanesulfonic acid (PFHxS)
1.9
1.4
0.34
ng/L
1
1633
Total/NA
Client Sample ID: MW-11
Lab Sample ID: 752-19362-17
Analyte
Result
Qualifier
RL
MDL
Unit
oil Fac
D Method
Prep Type
Perfluorobutanoic acid (PFBA)
14
2.8
0.71
ng/L
1
1633
Total/NA
Perfluorohexanoic acid (PFHxA)
4.7
1.4
0.071
ng/L
1
1633
Total/NA
Perfluoroheptanoic acid (PFHpA)
3.0
1.4
0.36
ng/L
1
1633
Total/NA
Perfluorooctanoic acid (PFOA)
5.0
1.4
0.36
ng/L
1
1633
Total/NA
Perfluorobutanesulfonic acid (PFBS)
1.5
1.4
0.36
ng/L
1
1633
Total/NA
Client Sample ID: WSW-2
Lab Sample
ID: 752-19362-20
C[Analyte
Result
Qualifier
RL
MDL
Unit
Dil Fac
D Method
Prep Type
Perfluorohexanoic acid (PFHxA)
0.18
J
1.4
0.072
ng/L
1
1633
Total/NA
This Detection Summary does not include radiochemical test results.
Page 9 of 92
Eurofins Raleigh
5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Detection
Summary
C
Client: Smith Gardner Inc
Job ID: 752-19362-1
Project/Site: Surry C&D/MSW (Permit 8602)
Client Sample ID: Field Blank
Lab Sample
ID: 752-19362-21
Analyte
Result Qualifier
RL
MDL
Unit
Dil Fac
D Method
Prep Type
Perfluorohexanoic acid (PFHxA)
0.12 J
1.5
0.073
ng/L
1
1633
Total/NA
Client Sample ID: MW-14
Lab Sample
ID: 752-19362-23
Analyte
Result Qualifier
RL
MDL
Unit
Dill Fac
D Method
Prep Type
Perfluorobutanoic acid (PFBA)
3.5
3.1
0.78
ng/L
1
1633
Total/NA
Perfluorohexanoic acid (PFHxA)
14
1.6
0.078
ng/L
1
1633
Total/NA
Perfluoroheptanoic acid (PFHpA)
2.3 1
1.6
0.39
ng/L
1
1633
Total/NA
Perfluorooctanoic acid (PFOA)
1.9
1.6
0.39
ng/L
1
1633
Total/NA
Perfluorobutanesulfonic acid (PFBS)
0.61 J
1.6
0.39
ng/L
1
1633
Total/NA
Perfluorohexanesulfonic acid (PFHxS)
0.94 J
1.6
0.39
ng/L
1
1633
Total/NA
F
This Detection Summary does not include radiochemical
test results.
Eurofins Raleigh
Page 10 of 92
5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Job ID: 752-19362-1
Client Sample ID: MW-7 Lab Sample ID: 752-19362-1
Date Collected: 04/29/24 13:45 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Analyte Result Qualifier RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Perfluorobutanoic acid (PFBA)
32
2.8
0.71
ng/L
05/14/24 13:53
05/15/24 19:50
1
Perfluoropentanoic acid (PFPeA)
72
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 19:50
1
Perfluorohexanoic acid (PFHxA)
75
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 19:50
1
Perfluoroheptanoic acid (PFHpA)
45
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 19:50
1
Perfluorooctanoic acid (PFOA)
110
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 19:50
1
Perfluorononanoic acid (PFNA)
2.8
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 19:50
1
Perfluorodecanoic acid (PFDA)
0.57 J *+
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 19:50
1
Perfluoroundecanoic acid (PFUnA)
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 19:50
1
Perfluorododecanoic acid (PFDoA)
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 19:50
1
Perfluorotridecanoic acid (PFTrDA)
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 19:50
1
Perfluorotetradecanoic acid (PFTA)
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 19:50
1
Perfluorobutanesulfonic acid
11
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 19:50
1
(PFBS)
Perfluoropentanesulfonic acid
9.4
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 19:50
1
(PFPeS)
Perfluorohexanesulfonic acid
31
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 19:50
1
(PFHxS)
Perfluoroheptanesulfonic acid
1.1 J
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 19:50
1
(PFHpS)
Perfluorooctanesulfonic acid
25
1.4
0.34
ng/L
05/20/24 14:57
05/21/24 15:43
1
(PFOS)
Perfluorononanesulfonic acid (PFNS)
<0.071
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 19:50
1
Perfluorododecanesulfonic acid
<0.35 `-
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 19:50
1
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
<0.35
2.8
0.35
ng/L
05/14/24 13:53
05/15/24 19:50
1
sulfonic acid (4:2 FTS)
1 H,1 H,2H,2H-Perfluorooctane
4.4
2.8
0.35
ng/L
05/14/24 13:53
05/15/24 19:50
1
sulfonic acid (6:2 FTS)
1 H,1 H,2H,2H-Perfluorodecane
<0.35
2.8
0.35
ng/L
05/14/24 13:53
05/15/24 19:50
1
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.071
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 19:50
1
N-methylperfluorooctane sulfonamide
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 19:50
1
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 19:50
1
(N EtFOSA)
N-methylperfluorooctanesulfona
0.83 J
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 19:50
1
midoacetic acid (NMeFOSAA)
N-ethyl perfluorooctanesulfonami
0.80 J
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 19:50
1
doacetic acid (NEtFOSAA)
N-methylperfluorooctane
<1.4
7.1
1.4
ng/L
05/14/24 13:53
05/15/24 19:50
1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<1.4
7.1
1.4
ng/L
05/14/24 13:53
05/15/24 19:50
1
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide Dimer
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 19:50
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 19:50
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 19:50
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 19:50
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 19:50
1
e-1-sulfonic acid (9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<0.53
1.4
0.53
ng/L
05/14/24 13:53
05/15/24 19:50
1
e-1-sulfonic acid (11Cl-PF30UdS)
Eurofins Raleigh
Page 11 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Client Sample ID: MW-7 Lab Sample ID: 752-19362-1
Date Collected: 04/29/24 13:45 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Analyte
Result Qualifier
RL
MDL
Unit
Perfluoro (2-ethoxyethane) sulfonic
<0.35
1.4
0.35
ng/L
acid (PFEESA)
3-Perfluoropropylpropanoic acid (3:3
<0.71
2.8
0.71
ng/L
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<1.9
7.1
1.9
ng/L
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<1.9
7.1
1.9
ng/L
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.071
1.4
0.071
ng/L
Perfluoro-3-methoxypropanoic acid
<0.35
1.4
0.35
ng/L
(PFMPA)
Isotope Dilution
%Recovery Qualifier
Limits
13C4 PFBA
70.4
5 - 130
13C5 PFPeA
62.4
40 - 130
13C5 PFHxA
77.9
40 - 130
13C4 PFHpA
79.2
40 - 130
13C8 PFOA
77.9
40 - 130
13C9 PFNA
102
40 - 130
13C6 PFDA
64.0
40 - 130
13C7 PFUnA
59.2
30 - 130
13C2 PFDoA
48.0
10 - 130
13C2 PFTeDA
40.7
10 - 130
13C3 PFBS
78.9
40 - 135
13C3 PFHxS
74.7
40 - 130
13C8 PFOS
89.3
40 - 130
13C8 PFOS
81.2
40 - 130
13C8 FOSA
64.1
40 - 130
d3-NMeFOSAA
91.6
40 - 170
d5-NEtFOSAA
89.2
25 - 135
M2-4:2 FTS
176
40 - 200
M2-6:2 FTS
132
40 - 200
M2-8:2 FTS
85.7
40 - 300
13C3 HFPO-DA
70.9
40 - 130
d7-N-McFOSE-M
77.1
10 - 130
d9-N-EtFOSE-M
72.9
10 - 130
d5-NEtPFOSA
80.6
10 - 130
d3-NMePFOSA
69.7
10 - 130
D Prepared Analyzed Dil Fac
05/14/2413:53 05/15/2419:50 1
05/14/2413:53 05/15/2419:50 1
05/14/2413:53 05/15/2419:50
05/14/2413:53 05/15/2419:50
05/14/2413:53 05/15/2419:50
05/14/2413:53 05/15/2419:50
Prepared
Analyzed
05114124 13:53
05115124 19:50
05114124 13:53
05115124 19:50
05114124 13:53
05115124 19:50
05114124 13:53
05115124 19:50
05114124 13:53
05115124 19:50
05114124 13:53
05115124 19:50
05114124 13:53
05115124 19:50
05114124 13:53
05115124 19:50
05114124 13:53
05115124 19:50
05114124 13:53
05115124 19:50
05114124 13:53
05115124 19:50
05114124 13:53
05115124 19:50
05114124 13:53
05115124 19:50
05120124 14:57
05121124 15:43
05114124 13:53
05115124 19:50
05114124 13:53
05115124 19:50
05114124 13:53
05115124 19:50
05114124 13:53
05115124 19:50
05114124 13:53
05115124 19:50
05114124 13:53
05115124 19:50
05114124 13:53
05115124 19:50
05114124 13:53
05115124 19:50
05114124 13:53
05115124 19:50
05114124 13:53
05115124 19:50
05114124 13:53
05115124 19:50
Eurofins Raleigh
Page 12 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Job ID: 752-19362-1
Client Sample ID: MW-6 Lab Sample ID: 752-19362-2
Date Collected: 04/29/24 14:00 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Analyte Result Qualifier RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Perfluorobutanoic acid (PFBA)
13
3.7
0.92
ng/L
05/14/24 13:53
05/15/24 20:05
1
Perfluoropentanoic acid (PFPeA)
26
1.8
0.46
ng/L
05/14/24 13:53
05/15/24 20:05
1
Perfluorohexanoic acid (PFHxA)
29
1.8
0.092
ng/L
05/14/24 13:53
05/15/24 20:05
1
Perfluoroheptanoic acid (PFHpA)
16
1.8
0.46
ng/L
05/14/24 13:53
05/15/24 20:05
1
Perfluorooctanoic acid (PFOA)
38
1.8
0.46
ng/L
05/14/24 13:53
05/15/24 20:05
1
Perfluorononanoic acid (PFNA)
1.1 J
1.8
0.092
ng/L
05/14/24 13:53
05/15/24 20:05
1
Perfluorodecanoic acid (PFDA)
<0.092 ,+
1.8
0.092
ng/L
05/14/24 13:53
05/15/24 20:05
1
Perfluoroundecanoic acid (PFUnA)
<0.46
1.8
0.46
ng/L
05/14/24 13:53
05/15/24 20:05
1
Perfluorododecanoic acid (PFDoA)
<0.46
1.8
0.46
ng/L
05/14/24 13:53
05/15/24 20:05
1
Perfluorotridecanoic acid (PFTrDA)
<0.46
1.8
0.46
ng/L
05/14/24 13:53
05/15/24 20:05
1
Perfluorotetradecanoic acid (PFTA)
<0.46
1.8
0.46
ng/L
05/14/24 13:53
05/15/24 20:05
1
Perfluorobutanesulfonic acid
8.4
1.8
0.46
ng/L
05/14/24 13:53
05/15/24 20:05
1
(PFBS)
Perfluoropentanesulfonic acid
5.6
1.8
0.092
ng/L
05/14/24 13:53
05/15/24 20:05
1
(PFPeS)
Perfluorohexanesulfonic acid
25
1.8
0.46
ng/L
05/14/24 13:53
05/15/24 20:05
1
(PFHxS)
Perfluoroheptanesulfonic acid
<0.092
1.8
0.092
ng/L
05/14/24 13:53
05/15/24 20:05
1
(PFHpS)
Perfluorooctanesulfonic acid
11
1.4
0.35
ng/L
05/20/24 14:57
05/21/24 15:58
1
(PFOS)
Perfluorononanesulfonic acid (PFNS)
<0.092
1.8
0.092
ng/L
05/14/24 13:53
05/15/24 20:05
1
Perfluorododecanesulfonic acid
<0.46 `-
1.8
0.46
ng/L
05/14/24 13:53
05/15/24 20:05
1
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
<0.46
3.7
0.46
ng/L
05/14/24 13:53
05/15/24 20:05
1
sulfonic acid (4:2 FTS)
1 H,1 H,2H,2H-Perfluorooctane
1.7 J
3.7
0.46
ng/L
05/14/24 13:53
05/15/24 20:05
1
sulfonic acid (6:2 FTS)
1 H,1 H,2H,2H-Perfluorodecane
<0.46
3.7
0.46
ng/L
05/14/24 13:53
05/15/24 20:05
1
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.092
1.8
0.092
ng/L
05/14/24 13:53
05/15/24 20:05
1
N-methylperfluorooctane sulfonamide
<0.46
1.8
0.46
ng/L
05/14/24 13:53
05/15/24 20:05
1
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<0.46
1.8
0.46
ng/L
05/14/24 13:53
05/15/24 20:05
1
(NETOSA)
N-methylperfluorooctanesulfonamidoa
<0.46
1.8
0.46
ng/L
05/14/24 13:53
05/15/24 20:05
1
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<0.46
1.8
0.46
ng/L
05/14/24 13:53
05/15/24 20:05
1
etic acid (NEtFOSAA)
N-methylperfluorooctane
<1.8
9.2
1.8
ng/L
05/14/24 13:53
05/15/24 20:05
1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<1.8
9.2
1.8
ng/L
05/14/24 13:53
05/15/24 20:05
1
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide Dimer
<0.46
1.8
0.46
ng/L
05/14/24 13:53
05/15/24 20:05
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<0.46
1.8
0.46
ng/L
05/14/24 13:53
05/15/24 20:05
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<0.46
1.8
0.46
ng/L
05/14/24 13:53
05/15/24 20:05
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<0.46
1.8
0.46
ng/L
05/14/24 13:53
05/15/24 20:05
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<0.46
1.8
0.46
ng/L
05/14/24 13:53
05/15/24 20:05
1
e-1-sulfonic acid (9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<0.69
1.8
0.69
ng/L
05/14/24 13:53
05/15/24 20:05
1
e-1-sulfonic acid (11Cl-PF30UdS)
Eurofins Raleigh
Page 13 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Client Sample ID: MW-6 Lab Sample ID: 752-19362-2
Date Collected: 04/29/24 14:00 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Analyte
Result Qualifier
RL
MDL
Unit
Perfluoro (2-ethoxyethane) sulfonic
<0.46
1.8
0.46
ng/L
acid (PFEESA)
3-Perfluoropropylpropanoic acid (3:3
<0.92
3.7
0.92
ng/L
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<2.5
9.2
2.5
ng/L
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<2.5
9.2
2.5
ng/L
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.092
1.8
0.092
ng/L
Perfluoro-3-methoxypropanoic acid
<0.46
1.8
0.46
ng/L
(PFMPA)
Isotope Dilution
%Recovery Qualifier
Limits
13C4 PFBA
68.3
5 - 130
13C5 PFPeA
65.9
40 - 130
13C5 PFHxA
73.0
40 - 130
13C4 PFHpA
69.3
40 - 130
13C8 PFOA
73.5
40 - 130
13C9 PFNA
94.8
40 - 130
13C6 PFDA
64.5
40 - 130
13C7 PFUnA
59.6
30 - 130
13C2 PFDoA
51.9
10 - 130
13C2 PFTeDA
52.1
10 - 130
13C3 PFBS
79.5
40 - 135
13C3 PFHxS
73.4
40 - 130
13C8 PFOS
88.9
40 - 130
13C8 PFOS
54.6
40 - 130
13C8 FOSA
69.7
40 - 130
d3-NMeFOSAA
85.1
40 - 170
d5-NEtFOSAA
83.7
25 - 135
M2-4:2 FTS
156
40 - 200
M2-6:2 FTS
90.5
40 - 200
M2-8:2 FTS
73.7
40 - 300
13C3 HFPO-DA
68.0
40 - 130
d7-N-McFOSE-M
89.3
10 - 130
d9-N-EtFOSE-M
90.2
10 - 130
d5-NEtPFOSA
98.5
10 - 130
d3-NMePFOSA
83.1
10 - 130
D Prepared Analyzed Dil Fac
nF/1 A19A 12•F'I nF/1119A 9n•nF 1
05/14/24 13:53 05/15/24 20:05
05/14/24 13:53 05/15/24 20:05
05/14/24 13:53 05/15/24 20:05
05/14/24 13:53 05/15/24 20:05
05/14/24 13:53 05/15/24 20:05
Prepared
Analyzed
05114124 13:53
05115124 20:05
05114124 13:53
05115124 20:05
05114124 13:53
05115124 20:05
05114124 13:53
05115124 20:05
05114124 13:53
05115124 20:05
05114124 13:53
05115124 20:05
05114124 13:53
05115124 20:05
05114124 13:53
05115124 20:05
05114124 13:53
05115124 20:05
05114124 13:53
05115124 20:05
05114124 13:53
05115124 20:05
05114124 13:53
05115124 20:05
05114124 13:53
05115124 20:05
05120124 14:57
05121124 15:58
05114124 13:53
05115124 20:05
05114124 13:53
05115124 20:05
05114124 13:53
05115124 20:05
05114124 13:53
05115124 20:05
05114124 13:53
05115124 20:05
05114124 13:53
05115124 20:05
05114124 13:53
05115124 20:05
05114124 13:53
05115124 20:05
05114124 13:53
05115124 20:05
05114124 13:53
05115124 20:05
05114124 13:53
05115124 20:05
Eurofins Raleigh
Page 14 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Job ID: 752-19362-1
Client Sample ID: MW-12S Lab Sample ID: 752-19362-3
Date Collected: 04/29/24 14:15 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Analyte Result Qualifier RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Perfluorobutanoic acid (PFBA)
8.4
2.8
0.71
ng/L
05/14/24 13:53
05/15/24 20:21
1
Perfluoropentanoic acid (PFPeA)
4.6
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:21
1
Perfluorohexanoic acid (PFHxA)
6.5
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 20:21
1
Perfluoroheptanoic acid (PFHpA)
1.8
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:21
1
Perfluorooctanoic acid (PFOA)
1.9
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:21
1
Perfluorononanoic acid (PFNA)
<0.071
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 20:21
1
Perfluorodecanoic acid (PFDA)
<0.071 ,+
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 20:21
1
Perfluoroundecanoic acid (PFUnA)
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:21
1
Perfluorododecanoic acid (PFDoA)
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:21
1
Perfluorotridecanoic acid (PFTrDA)
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:21
1
Perfluorotetradecanoic acid (PFTA)
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:21
1
Perfluorobutanesulfonic acid
1.9
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:21
1
(PFBS)
Perfluoropentanesulfonic acid
0.37 J
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 20:21
1
(PFPeS)
Perfluorohexanesulfonic acid
1.5
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:21
1
(PFHxS)
Perfluoroheptanesulfonic acid
<0.071
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 20:21
1
(PFHpS)
Perfluorooctanesulfonic acid
0.85 J
1.4
0.35
ng/L
05/20/24 14:57
05/21/24 16:14
1
(PFOS)
Perfluorononanesulfonic acid (PFNS)
<0.071
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 20:21
1
Perfluorododecanesulfonic acid
<0.35 `-
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:21
1
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
<0.35
2.8
0.35
ng/L
05/14/24 13:53
05/15/24 20:21
1
sulfonic acid (4:2 FTS)
1 H,1 1-1,2H,21-1-Perfluorooctane sulfonic
<0.35
2.8
0.35
ng/L
05/14/24 13:53
05/15/24 20:21
1
acid (6:2 FTS)
11-1,11-1,2H,21-1-Perfluorodecane
<0.35
2.8
0.35
ng/L
05/14/24 13:53
05/15/24 20:21
1
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.071
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 20:21
1
N-methylperfluorooctane sulfonamide
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:21
1
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:21
1
(NETOSA)
N-methylperfluorooctanesulfonamidoa
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:21
1
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:21
1
etic acid (NEtFOSAA)
N-methylperfluorooctane
<1.4
7.1
1.4
ng/L
05/14/24 13:53
05/15/24 20:21
1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<1.4
7.1
1.4
ng/L
05/14/24 13:53
05/15/24 20:21
1
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide Dimer
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:21
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:21
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:21
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:21
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:21
1
e-1-sulfonic acid (9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<0.53
1.4
0.53
ng/L
05/14/24 13:53
05/15/24 20:21
1
e-1-sulfonic acid (11Cl-PF30UdS)
Eurofins Raleigh
Page 15 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Client Sample ID: MW-12S Lab Sample ID: 752-19362-3
Date Collected: 04/29/24 14:15 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Analyte
Result Qualifier
RL
MDL Unit
D Prepared
Analyzed
Perfluoro (2-ethoxyethane) sulfonic
<0.35
1.4
0.35 ng/L
05/14/24 13:53
05/15/24 20:21
acid (PFEESA)
3-Perfluoropropylpropanoic acid (3:3
<0.71
2.8
0.71 ng/L
05/14/24 13:53
05/15/24 20:21
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<1.9
7.1
1.9 ng/L
05/14/24 13:53
05/15/24 20:21
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<1.9
7.1
1.9 ng/L
05/14/24 13:53
05/15/24 20:21
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.071
1.4
0.071 ng/L
05/14/24 13:53
05/15/24 20:21
Perfluoro-3-methoxypropanoic acid
<0.35
1.4
0.35 ng/L
05/14/24 13:53
05/15/24 20:21
(PFMPA)
Isotope Dilution
%Recovery Qualifier
Limits
Prepared
Analyzed
13C4 PFBA
64.1
5 - 130
05114124 13:53
05115124 20:21
13C5 PFPeA
67.2
40 - 130
05114124 13:53
05115124 20:21
13C5 PFHxA
70.9
40 - 130
05114124 13:53
05115124 20:21
13C4 PFHpA
68.2
40 - 130
05114124 13:53
05115124 20:21
13C8 PFOA
72.9
40 - 130
05114124 13:53
05115124 20:21
13C9 PFNA
89.3
40 - 130
05114124 13:53
05115124 20:21
13C6 PFDA
59.1
40 - 130
05114124 13:53
05115124 20:21
13C7 PFUnA
53.2
30 - 130
05114124 13:53
05115124 20:21
13C2 PFDoA
44.7
10 - 130
05114124 13:53
05115124 20:21
13C2 PFTeDA
43.0
10 - 130
05114124 13:53
05115124 20:21
13C3 PFBS
73.1
40 - 135
05114124 13:53
05115124 20:21
13C3 PFHxS
70.3
40 - 130
05114124 13:53
05115124 20:21
13C8 PFOS
84.5
40 - 130
05114124 13:53
05115124 20:21
13C8 PFOS
89.4
40 - 130
05120124 14:57
05121124 16:14
13C8 FOSA
71.6
40 - 130
05114124 13:53
05115124 20:21
d3-NMeFOSAA
80.1
40 - 170
05114124 13:53
05115124 20:21
d5-NEtFOSAA
76.6
25 - 135
05114124 13:53
05115124 20:21
M2-4:2 FTS
97.3
40 - 200
05114124 13:53
05115124 20:21
M2-6:2 FTS
76.2
40 - 200
05114124 13:53
05115124 20:21
M2-8:2 FTS
68.8
40 - 300
05114124 13:53
05115124 20:21
13C3 HFPO-DA
68.0
40 - 130
05114124 13:53
05115124 20:21
d7-N-McFOSE-M
80.9
10 - 130
05114124 13:53
05115124 20:21
d9-N-EtFOSE-M
81.2
10 - 130
05114124 13:53
05115124 20:21
d5-NEtPFOSA
91.8
10 - 130
05114124 13:53
05115124 20:21
d3-NMePFOSA
80.5
10 - 130
05114124 13:53
05115124 20:21
Eurofins Raleigh
Page 16 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Job ID: 752-19362-1
Client Sample ID: MW-13 Lab Sample ID: 752-19362-4
Date Collected: 04/29/24 14:30 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Analyte Result Qualifier RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Perfluorobutanoic acid (PFBA)
29
2.8
0.70
ng/L
05/14/24 13:53
05/15/24 20:36
1
Perfluoropentanoic acid (PFPeA)
47
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:36
1
Perfluorohexanoic acid (PFHxA)
130
1.4
0.070
ng/L
05/14/24 13:53
05/15/24 20:36
1
Perfluoroheptanoic acid (PFHpA)
17
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:36
1
Perfluorooctanoic acid (PFOA)
17
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:36
1
Perfluorononanoic acid (PFNA)
<0.070
1.4
0.070
ng/L
05/14/24 13:53
05/15/24 20:36
1
Perfluorodecanoic acid (PFDA)
<0.070 *+
1.4
0.070
ng/L
05/14/24 13:53
05/15/24 20:36
1
Perfluoroundecanoic acid (PFUnA)
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:36
1
Perfluorododecanoic acid (PFDoA)
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:36
1
Perfluorotridecanoic acid (PFTrDA)
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:36
1
Perfluorotetradecanoic acid (PFTA)
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:36
1
Perfluorobutanesulfonic acid
6.1
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:36
1
(PFBS)
Perfluoropentanesulfonic acid
1.4
1.4
0.070
ng/L
05/14/24 13:53
05/15/24 20:36
1
(PFPeS)
Perfluorohexanesulfonic acid
9.2
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:36
1
(PFHxS)
Perfluoroheptanesulfonic acid
<0.070
1.4
0.070
ng/L
05/14/24 13:53
05/15/24 20:36
1
(PFHpS)
Perfluorooctanesulfonic acid (PFOS)
<0.35 *+
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:36
1
Perfluorononanesulfonic acid (PFNS)
<0.070
1.4
0.070
ng/L
05/14/24 13:53
05/15/24 20:36
1
Perfluorododecanesulfonic acid
<0.35 *-
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:36
1
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
<0.35
2.8
0.35
ng/L
05/14/24 13:53
05/15/24 20:36
1
sulfonic acid (4:2 FTS)
1 H,1 H,2H,2H-Perfluorooctane
1.0 J
2.8
0.35
ng/L
05/14/24 13:53
05/15/24 20:36
1
sulfonic acid (6:2 FTS)
1 H,1 H,2H,2H-Perfluorodecane
<0.35
2.8
0.35
ng/L
05/14/24 13:53
05/15/24 20:36
1
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.070
1.4
0.070
ng/L
05/14/24 13:53
05/15/24 20:36
1
N-methylperfluorooctane sulfonamide
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:36
1
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:36
1
(NEtFOSA)
N-methylperfluorooctanesulfonamidoa
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:36
1
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:36
1
etic acid (NEtFOSAA)
N-methylperfluorooctane
<1.4
7.0
1.4
ng/L
05/14/24 13:53
05/15/24 20:36
1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<1.4
7.0
1.4
ng/L
05/14/24 13:53
05/15/24 20:36
1
sulfonamidoethanol (NETOSE)
Hexafluoropropylene Oxide Dimer
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:36
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:36
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:36
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:36
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 20:36
1
e-1-sulfonic acid (9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<0.52
1.4
0.52
ng/L
05/14/24 13:53
05/15/24 20:36
1
e-1-sulfonic acid (11Cl-PF30UdS)
Eurofins Raleigh
Page 17 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Client Sample ID: MW-13 Lab Sample ID: 752-19362-4
Date Collected: 04/29/24 14:30 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Analyte
Result Qualifier
RL
MDL
Unit
Perfluoro (2-ethoxyethane) sulfonic
<0.35
1.4
0.35
ng/L
acid (PFEESA)
3-Perfluoropropylpropanoic acid (3:3
<0.70
2.8
0.70
ng/L
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<1.9
7.0
1.9
ng/L
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<1.9
7.0
1.9
ng/L
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.070
1.4
0.070
ng/L
Perfluoro-3-methoxypropanoic acid
<0.35
1.4
0.35
ng/L
(PFMPA)
Isotope Dilution
%Recovery Qualifier
Limits
13C4 PFBA
64.1
5 - 130
13C5 PFPeA
65.6
40 - 130
13C5 PFHxA
71.4
40 - 130
13C4 PFHpA
70.7
40 - 130
13C8 PFOA
71.2
40 - 130
13C9 PFNA
91.3
40 - 130
13C6 PFDA
61.5
40 - 130
13C7 PFUnA
57.2
30 - 130
13C2 PFDoA
47.8
10 - 130
13C2 PFTeDA
43.7
10 - 130
13C3 PFBS
71.1
40 - 135
13C3 PFHxS
69.3
40 - 130
13C8 PFOS
82.5
40 - 130
13C8 FOSA
64.1
40 - 130
d3-NMeFOSAA
78.2
40 - 170
d5-NEtFOSAA
77.9
25 - 135
M2-4:2 FTS
116
40 - 200
M2-6:2 FTS
85.8
40 - 200
M2-8:2 FTS
67.6
40 - 300
13C3 HFPO-DA
70.5
40 - 130
d7-N-McFOSE-M
80.4
10 - 130
d9-N-EtFOSE-M
77.1
10 - 130
d5-NEtPFOSA
89.6
10 - 130
d3-NMePFOSA
76.1
10 - 130
D Prepared Analyzed Dil Fac
05/14/24 13:53 05/15/24 20:36 1
05/14/24 13:53 05/15/24 20:36 1
05/14/24 13:53 05/15/24 20:36
05/14/24 13:53 05/15/24 20:36
05/14/24 13:53 05/15/24 20:36
05/14/24 13:53 05/15/24 20:36
Prepared
Analyzed
05114124 13:53
05115124 20.36
05114124 13:53
05115124 20:36
05114124 13:53
05115124 20:36
05114124 13:53
05115124 20:36
05114124 13:53
05115124 20:36
05114124 13:53
05115124 20:36
05114124 13:53
05115124 20:36
05114124 13:53
05115124 20:36
05114124 13:53
05115124 20:36
05114124 13:53
05115124 20:36
05114124 13:53
05115124 20:36
05114124 13:53
05115124 20:36
05114124 13:53
05115124 20:36
05114124 13:53
05115124 20:36
05114124 13:53
05115124 20:36
05114124 13:53
05115124 20:36
05114124 13:53
05115124 20:36
05114124 13:53
05115124 20:36
05114124 13:53
05115124 20:36
05114124 13:53
05115124 20:36
05114124 13:53
05115124 20:36
05114124 13:53
05115124 20:36
05114124 13:53
05115124 20:36
05114124 13:53
05115124 20:36
Eurofins Raleigh
Page 18 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Client Sample ID: MW-23
Date Collected: 04/29/24 14:45
Date Received: 05/03/24 09:50
F
Job ID: 752-19362-1
Lab Sample ID: 752-19362-5
Matrix: Water
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Analyte Result Qualifier RL
MDL
Unit
D Prepared
Analyzed
Perfluorobutanoic acid (PFBA)
<9.5
38
9.5
ng/L
05/14/24 13:53
05/15/24 20:51
Perfluoropentanoic acid (PFPeA)
<4.7
19
4.7
ng/L
05/14/24 13:53
05/15/24 20:51
Perfluorohexanoic acid (PFHxA)
6.4 J
19
0.95
ng/L
05/14/24 13:53
05/15/24 20:51
Perfluoroheptanoic acid (PFHpA)
<4.7
19
4.7
ng/L
05/14/24 13:53
05/15/24 20:51
Perfluorooctanoic acid (PFOA)
<4.7
19
4.7
ng/L
05/14/24 13:53
05/15/24 20:51
Perfluorononanoic acid (PFNA)
<0.95
19
0.95
ng/L
05/14/24 13:53
05/15/24 20:51
Perfluorodecanoic acid (PFDA)
<0.95 '+
19
0.95
ng/L
05/14/24 13:53
05/15/24 20:51
Perfluoroundecanoic acid (PFUnA)
<4.7
19
4.7
ng/L
05/14/24 13:53
05/15/24 20:51
Perfluorododecanoic acid (PFDoA)
<4.7
19
4.7
ng/L
05/14/24 13:53
05/15/24 20:51
Perfluorotridecanoic acid (PFTrDA)
<4.7
19
4.7
ng/L
05/14/24 13:53
05/15/24 20:51
Perfluorotetradecanoic acid (PFTA)
<4.7
19
4.7
ng/L
05/14/24 13:53
05/15/24 20:51
Perfluorobutanesulfonic acid (PFBS)
<4.7
19
4.7
ng/L
05/14/24 13:53
05/15/24 20:51
Perfluoropentanesulfonic acid
<0.95
19
0.95
ng/L
05/14/24 13:53
05/15/24 20:51
(PFPeS)
Perfluorohexanesulfonic acid (PFHxS)
<4.7
19
4.7
ng/L
05/14/24 13:53
05/15/24 20:51
Perfluoroheptanesulfonic acid
<0.95
19
0.95
ng/L
05/14/24 13:53
05/15/24 20:51
(PFHpS)
Perfluorooctanesulfonic acid (PFOS)
<4.7 .+
19
4.7
ng/L
05/14/24 13:53
05/15/24 20:51
Perfluorononanesulfonic acid (PFNS)
<0.95
19
0.95
ng/L
05/14/24 13:53
05/15/24 20:51
Perfluorododecanesulfonic acid
<4.7 "-
19
4.7
ng/L
05/14/24 13:53
05/15/24 20:51
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
<4.7
38
4.7
ng/L
05/14/24 13:53
05/15/24 20:51
sulfonic acid (4:2 FTS)
1H,1H,2H,2H-Perfluorooctanesulfonic
<4.7
38
4.7
ng/L
05/14/24 13:53
05/15/24 20:51
acid (6:2 FTS)
1 H,1 H,2H,2H-Perfluorodecane
<4.7
38
4.7
ng/L
05/14/24 13:53
05/15/24 20:51
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.95
19
0.95
ng/L
05/14/24 13:53
05/15/24 20:51
N-methylperfluorooctane sulfonamide
<4.7
19
4.7
ng/L
05/14/24 13:53
05/15/24 20:51
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<4.7
19
4.7
ng/L
05/14/24 13:53
05/15/24 20:51
(NEtFOSA)
N-methylperfluorooctanesulfonamidoa
<4.7
19
4.7
ng/L
05/14/24 13:53
05/15/24 20:51
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<4.7
19
4.7
ng/L
05/14/24 13:53
05/15/24 20:51
etic acid (NEtFOSAA)
N-methylperfluorooctane
<19
95
19
ng/L
05/14/24 13:53
05/15/24 20:51
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<19
95
19
ng/L
05/14/24 13:53
05/15/24 20:51
sulfonamidoethanol (NETOSE)
Hexafluoropropylene Oxide Dimer
<4.7
19
4.7
ng/L
05/14/24 13:53
05/15/24 20:51
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<4.7
19
4.7
ng/L
05/14/24 13:53
05/15/24 20:51
(ADONA)
Perfluoro-4-methoxybutanoic acid
<4.7
19
4.7
ng/L
05/14/24 13:53
05/15/24 20:51
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<4.7
19
4.7
ng/L
05/14/24 13:53
05/15/24 20:51
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<4.7
19
4.7
ng/L
05/14/24 13:53
05/15/24 20:51
e-1-sulfonic acid(9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<7.1
19
7.1
ng/L
05/14/24 13:53
05/15/24 20:51
e-1-sulfonic acid (11CI-PF30UdS)
Perfluoro (2-ethoxyethane) sulfonic
<4.7
19
4.7
ng/L
05/14/24 13:53
05/15/24 20:51
acid (PFEESA)
Eurofins Raleigh
Page 19 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Client Sample ID: MW-23 Lab Sample ID: 752-19362-5
Date Collected: 04/29/24 14:45 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Analyte
Result Qualifier
RL
MDL Unit
D Prepared
Analyzed
3-Perfluoropropylpropanoic acid (3:3
<9.5
38
9.5 ng/L
05/14/24 13:53
05/15/24 20:51
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<26
95
26 ng/L
05/14/24 13:53
05/15/24 20:51
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<26
95
26 ng/L
05/14/24 13:53
05/15/24 20:51
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.95
19
0.95 ng/L
05/14/24 13:53
05/15/24 20:51
Perfluoro-3-methoxypropanoic acid
<4.7
19
4.7 ng/L
05/14/24 13:53
05/15/24 20:51
(PFMPA)
Isotope Dilution
%Recovery Qualifier
Limits
Prepared
Analyzed
13C4 PFBA
65.3
5 - 130
05114124 13:53
05115124 20:51
13C5 PFPeA
67.7
40 - 130
05114124 13:53
05115124 20:51
13C5 PFHxA
73.2
40 - 130
05114124 13:53
05115124 20:51
13C4 PFHpA
70.0
40 - 130
05114124 13:53
05115124 20:51
13C8 PFOA
71.6
40 - 130
05114124 13:53
05115124 20:51
13C9 PFNA
95.9
40 - 130
05114124 13:53
05115124 20:51
13C6 PFDA
63.8
40 - 130
05114124 13:53
05/15/24 20:51
13C7 PFUnA
59.8
30 - 130
05114124 13:53
05/15/24 20:51
13C2 PFDoA
51.4
10 - 130
05114124 13:53
05115124 20:51
13C2 PFTeDA
45.2
10 - 130
05114124 13:53
05115124 20:51
13C3 PFBS
77.1
40 - 135
05114124 13:53
05115124 20:51
13C3 PFHxS
71.9
40 - 130
05114124 13:53
05115124 20:51
13C8 PFOS
88.9
40 - 130
05114124 13:53
05115124 20:51
13C8 FOSA
70.0
40 - 130
05114124 13:53
05115124 20:51
d3-NMeFOSAA
83.0
40 - 170
05114124 13:53
05115124 20:51
d5-NEtFOSAA
81.6
25 - 135
05114124 13:53
05115124 20:51
M2-4:2 FTS
88.2
40 - 200
05114124 13:53
05115124 20:51
M2-6:2 FTS
80.7
40 - 200
05114124 13:53
05115124 20:51
M2-8:2 FTS
77.1
40 - 300
05114124 13:53
05115124 20:51
13C3 HFPO-DA
72.6
40 - 130
05114124 13:53
05115124 20:51
d7-N-McFOSE-M
94.3
10 - 130
05114124 13:53
05115124 20:51
d9-N-EtFOSE-M
97.9
10 - 130
05114124 13:53
05/15/24 20:51
d5-NEtPFOSA
101
10 - 130
05114124 13:53
05/15/24 20:51
d3-NMePFOSA
80.8
10 - 130
05114124 13:53
05/15/24 20:51
Eurofins Raleigh
Page 20 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Client Sample ID: MW-19
Date Collected: 04/29/24 15:00
Date Received: 05/03/24 09:50
F
Job ID: 752-19362-1
Lab Sample ID: 752-19362-6
Matrix: Water
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Analyte Result Qualifier RL
MDL
Unit
D Prepared
Analyzed
Perfluorobutanoic acid (PFBA)
<2.0
8.2
2.0
ng/L
05/14/24 13:53
05/15/24 21:07
Perfluoropentanoic acid (PFPeA)
<1.0
4.1
1.0
ng/L
05/14/24 13:53
05/15/24 21:07
Perfluorohexanoic acid (PFHxA)
6.7
4.1
0.20
ng/L
05/14/24 13:53
05/15/24 21:07
Perfluoroheptanoic acid (PFHpA)
<1.0
4.1
1.0
ng/L
05/14/24 13:53
05/15/24 21:07
Perfluorooctanoic acid (PFOA)
<1.0
4.1
1.0
ng/L
05/14/24 13:53
05/15/24 21:07
Perfluorononanoic acid (PFNA)
<0.20
4.1
0.20
ng/L
05/14/24 13:53
05/15/24 21:07
Perfluorodecanoic acid (PFDA)
<0.20 .+
4.1
0.20
ng/L
05/14/24 13:53
05/15/24 21:07
Perfluoroundecanoic acid (PFUnA)
<1.0
4.1
1.0
ng/L
05/14/24 13:53
05/15/24 21:07
Perfluorododecanoic acid (PFDoA)
<1.0
4.1
1.0
ng/L
05/14/24 13:53
05/15/24 21:07
Perfluorotridecanoic acid (PFTrDA)
<1.0
4.1
1.0
ng/L
05/14/24 13:53
05/15/24 21:07
Perfluorotetradecanoic acid (PFTA)
<1.0
4.1
1.0
ng/L
05/14/24 13:53
05/15/24 21:07
Perfluorobutanesulfonic acid (PFBS)
<1.0
4.1
1.0
ng/L
05/14/24 13:53
05/15/24 21:07
Perfluoropentanesulfonic acid
<0.20
4.1
0.20
ng/L
05/14/24 13:53
05/15/24 21:07
(PFPeS)
Perfluorohexanesulfonic acid (PFHxS)
<1.0
4.1
1.0
ng/L
05/14/24 13:53
05/15/24 21:07
Perfluoroheptanesulfonic acid
<0.20
4.1
0.20
ng/L
05/14/24 13:53
05/15/24 21:07
(PFHpS)
Perfluorooctanesulfonic acid (PFOS)
<1.0 .+
4.1
1.0
ng/L
05/14/24 13:53
05/15/24 21:07
Perfluorononanesulfonic acid (PFNS)
<0.20
4.1
0.20
ng/L
05/14/24 13:53
05/15/24 21:07
Perfluorododecanesulfonic acid
<1.0 "-
4.1
1.0
ng/L
05/14/24 13:53
05/15/24 21:07
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
<1.0
8.2
1.0
ng/L
05/14/24 13:53
05/15/24 21:07
sulfonic acid (4:2 FTS)
1H,1H,2H,2H-Perfluorooctanesulfonic
<1.0
8.2
1.0
ng/L
05/14/24 13:53
05/15/24 21:07
acid (6:2 FTS)
1 H,1 H,2H,2H-Perfluorodecane
<1.0
8.2
1.0
ng/L
05/14/24 13:53
05/15/24 21:07
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.20
4.1
0.20
ng/L
05/14/24 13:53
05/15/24 21:07
N-methylperfluorooctane sulfonamide
<1.0
4.1
1.0
ng/L
05/14/24 13:53
05/15/24 21:07
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<1.0
4.1
1.0
ng/L
05/14/24 13:53
05/15/24 21:07
(NEtFOSA)
N-methylperfluorooctanesulfonamidoa
<1.0
4.1
1.0
ng/L
05/14/24 13:53
05/15/24 21:07
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<1.0
4.1
1.0
ng/L
05/14/24 13:53
05/15/24 21:07
etic acid (NEtFOSAA)
N-methylperfluorooctane
<4.1
20
4.1
ng/L
05/14/24 13:53
05/15/24 21:07
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<4.1
20
4.1
ng/L
05/14/24 13:53
05/15/24 21:07
sulfonamidoethanol (NETOSE)
Hexafluoropropylene Oxide Dimer
<1.0
4.1
1.0
ng/L
05/14/24 13:53
05/15/24 21:07
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<1.0
4.1
1.0
ng/L
05/14/24 13:53
05/15/24 21:07
(ADONA)
Perfluoro-4-methoxybutanoic acid
<1.0
4.1
1.0
ng/L
05/14/24 13:53
05/15/24 21:07
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<1.0
4.1
1.0
ng/L
05/14/24 13:53
05/15/24 21:07
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<1.0
4.1
1.0
ng/L
05/14/24 13:53
05/15/24 21:07
e-1-sulfonic acid(9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<1.5
4.1
1.5
ng/L
05/14/24 13:53
05/15/24 21:07
e-1-sulfonic acid (11CI-PF30UdS)
Perfluoro (2-ethoxyethane) sulfonic
<1.0
4.1
1.0
ng/L
05/14/24 13:53
05/15/24 21:07
acid (PFEESA)
Eurofins Raleigh
Page 21 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Client Sample ID: MW-19 Lab Sample ID: 752-19362-6
Date Collected: 04/29/24 15:00 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Analyte
Result Qualifier
RL
MDL
Unit
3-Perfluoropropylpropanoic acid (3:3
<2.0
8.2
2.0
ng/L
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<5.5
20
5.5
ng/L
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<5.5
20
5.5
ng/L
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.20
4.1
0.20
ng/L
Perfluoro-3-methoxypropanoic acid
<1.0
4.1
1.0
ng/L
(PFMPA)
Isotope Dilution
%Recovery Qualifier
Limits
13C4 PFBA
65.9
5 - 130
13C5 PFPeA
68.2
40 - 130
13C5 PFHxA
73.7
40 - 130
13C4 PFHpA
70.8
40 - 130
13C8 PFOA
74.9
40 - 130
13C9 PFNA
94.5
40 - 130
13C6 PFDA
63.4
40 - 130
13C7 PFUnA
57.6
30 - 130
13C2 PFDoA
50.4
10 - 130
13C2 PFTeDA
42.4
10 - 130
13C3 PFBS
77.5
40 - 135
13C3 PFHxS
72.6
40 - 130
13C8 PFOS
88.4
40 - 130
13C8 FOSA
67.6
40 - 130
d3-NMeFOSAA
80.5
40 - 170
d5-NEtFOSAA
78.0
25 - 135
M2-4:2 FTS
76.2
40 - 200
M2-6:2 FTS
78.8
40 - 200
M2-8:2 FTS
74.9
40 - 300
13C3 HFPO-DA
76.0
40 - 130
d7-N-McFOSE-M
90.2
10 - 130
d9-N-EtFOSE-M
89.3
10 - 130
d5-NEtPFOSA
96.4
10 - 130
d3-NMePFOSA
78.3
10 - 130
D Prepared Analyzed Dil Fac
05/14/24 13:53 05/15/24 21:07 1
•
05/14/24 13:53 05/15/24 21:07 1
05/14/24 13:53 05/15/24 21:07
05/14/24 13:53 05/15/24 21:07
05/14/24 13:53 05/15/24 21:07
Prepared
Analyzed
05114124 13:53
05115124 21:07
05114124 13:53
05115124 21:07
05114124 13:53
05115124 21:07
05114124 13:53
05115124 21:07
05114124 13:53
05115124 21:07
05114124 13:53
05115124 21:07
05114124 13:53
05/15/24 21:07
05114124 13:53
05/15/24 21:07
05114124 13:53
05115124 21:07
05114124 13:53
05115124 21:07
05114124 13:53
05115124 21:07
05114124 13:53
05115124 21:07
05114124 13:53
05115124 21:07
05114124 13:53
05115124 21:07
05114124 13:53
05115124 21:07
05114124 13:53
05115124 21:07
05114124 13:53
05115124 21:07
05114124 13:53
05115124 21:07
05114124 13:53
05115124 21:07
05114124 13:53
05115124 21:07
05114124 13:53
05115124 21:07
05114124 13:53
05/15/24 21:07
05114124 13:53
05/15/24 21:07
05114124 13:53
05/15/24 21:07
Eurofins Raleigh
Page 22 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Job ID: 752-19362-1
Client Sample ID: MW-22 Lab Sample ID: 752-19362-7
Date Collected: 04/29/24 15:15 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Analyte Result Qualifier RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Perfluorobutanoic acid (PFBA)
5.4
2.8
0.71
ng/L
05/14/24 13:53
05/15/24 21:22
1
Perfluoropentanoic acid (PFPeA)
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 21:22
1
Perfluorohexanoic acid (PFHxA)
16
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 21:22
1
Perfluoroheptanoic acid (PFHpA)
1.8
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 21:22
1
Perfluorooctanoic acid (PFOA)
3.6
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 21:22
1
Perfluorononanoic acid (PFNA)
<0.071
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 21:22
1
Perfluorodecanoic acid (PFDA)
<0.071 *+
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 21:22
1
Perfluoroundecanoic acid (PFUnA)
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 21:22
1
Perfluorododecanoic acid (PFDoA)
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 21:22
1
Perfluorotridecanoic acid (PFTrDA)
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 21:22
1
Perfluorotetradecanoic acid (PFTA)
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 21:22
1
Perfluorobutanesulfonic acid
1.1 J
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 21:22
1
(PFBS)
Perfluoropentanesulfonic acid
0.41 J
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 21:22
1
(PFPeS)
Perfluorohexanesulfonic acid
0.95 J
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 21:22
1
(PFHxS)
Perfluoroheptanesulfonic acid
<0.071
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 21:22
1
(PFHpS)
Perfluorooctanesulfonic acid
0.61 J *+ B
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 21:22
1
(PFOS)
Perfluorononanesulfonic acid (PFNS)
<0.071
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 21:22
1
Perfluorododecanesulfonic acid
<0.35 `-
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 21:22
1
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
<0.35
2.8
0.35
ng/L
05/14/24 13:53
05/15/24 21:22
1
sulfonic acid (4:2 FTS)
1 H,1 1-1,2H,21-1-Perfluorooctane sulfonic
<0.35
2.8
0.35
ng/L
05/14/24 13:53
05/15/24 21:22
1
acid (6:2 FTS)
11-1,11-1,2H,21-1-Perfluorodecane
<0.35
2.8
0.35
ng/L
05/14/24 13:53
05/15/24 21:22
1
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.071
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 21:22
1
N-methylperfluorooctane sulfonamide
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 21:22
1
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 21:22
1
(NETOSA)
N-methylperfluorooctanesulfonamidoa
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 21:22
1
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 21:22
1
etic acid (NEtFOSAA)
N-methylperfluorooctane
<1.4
7.1
1.4
ng/L
05/14/24 13:53
05/15/24 21:22
1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<1.4
7.1
1.4
ng/L
05/14/24 13:53
05/15/24 21:22
1
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide Dimer
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 21:22
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 21:22
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 21:22
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 21:22
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 21:22
1
e-1-sulfonic acid (9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<0.53
1.4
0.53
ng/L
05/14/24 13:53
05/15/24 21:22
1
e-1-sulfonic acid (11Cl-PF30UdS)
Eurofins Raleigh
Page 23 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Client Sample ID: MW-22 Lab Sample ID: 752-19362-7
Date Collected: 04/29/24 15:15 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Analyte
Result Qualifier
RL
MDL
Unit
Perfluoro (2-ethoxyethane) sulfonic
<0.35
1.4
0.35
ng/L
acid (PFEESA)
3-Perfluoropropylpropanoic acid (3:3
<0.71
2.8
0.71
ng/L
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<1.9
7.1
1.9
ng/L
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<1.9
7.1
1.9
ng/L
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.071
1.4
0.071
ng/L
Perfluoro-3-methoxypropanoic acid
<0.35
1.4
0.35
ng/L
(PFMPA)
Isotope Dilution
%Recovery Qualifier
Limits
13C4 PFBA
68.0
5 - 130
13C5 PFPeA
69.9
40 - 130
13C5 PFHxA
77.5
40 - 130
13C4 PFHpA
74.7
40 - 130
13C8 PFOA
77.4
40 - 130
13C9 PFNA
99.6
40 - 130
13C6 PFDA
63.9
40 - 130
13C7 PFUnA
57.0
30 - 130
13C2 PFDoA
47.7
10 - 130
13C2 PFTeDA
47.5
10 - 130
13C3 PFBS
79.8
40 - 135
13C3 PFHxS
74.4
40 - 130
13C8 PFOS
88.5
40 - 130
13C8 FOSA
66.2
40 - 130
d3-NMeFOSAA
83.0
40 - 170
d5-NEtFOSAA
80.2
25 - 135
M2-4:2 FTS
160
40 - 200
M2-6:2 FTS
96.3
40 - 200
M2-8:2 FTS
75.1
40 - 300
13C3 HFPO-DA
74.6
40 - 130
d7-N-McFOSE-M
85.1
10 - 130
d9-N-EtFOSE-M
83.4
10 - 130
d5-NEtPFOSA
94.8
10 - 130
d3-NMePFOSA
78.9
10 - 130
D Prepared Analyzed Dil Fac
05/14/24 13:53 05/15/24 21:22 1
05/14/24 13:53 05/15/24 21:22 1
05/14/24 13:53 05/15/24 21:22
05/14/24 13:53 05/15/24 21:22
05/14/24 13:53 05/15/24 21:22
05/14/24 13:53 05/15/24 21:22
Prepared
Analyzed
05114124 13:53
05/15/24 21:22
05114124 13:53
05/15/24 21:22
05114124 13:53
05115124 21:22
05114124 13:53
05115124 21:22
05114124 13:53
05115124 21:22
05114124 13:53
05115124 21:22
05114124 13:53
05115124 21:22
05114124 13:53
05115124 21:22
05114124 13:53
05115124 21:22
05114124 13:53
05115124 21:22
05114124 13:53
05115124 21:22
05114124 13:53
05115124 21:22
05114124 13:53
05115124 21:22
05114124 13:53
05115124 21:22
05114124 13:53
05115124 21:22
05114124 13:53
05115124 21:22
05114124 13:53
05115124 21:22
05114124 13:53
05115124 21:22
05114124 13:53
05115124 21:22
05114124 13:53
05115124 21:22
05114124 13:53
05115124 21:22
05114124 13:53
05115124 21:22
05114124 13:53
05115124 21:22
05114124 13:53
05115124 21:22
Eurofins Raleigh
Page 24 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Job ID: 752-19362-1
Client Sample ID: MW-17 Lab Sample ID: 752-19362-8
Date Collected: 04/29/24 15:30 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Analyte Result Qualifier RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Perfluorobutanoic acid (PFBA)
21
2.7
0.68
ng/L
05/14/24 13:53
05/15/24 21:37
1
Perfluoropentanoic acid (PFPeA)
27
1.4
0.34
ng/L
05/14/24 13:53
05/15/24 21:37
1
Perfluorohexanoic acid (PFHxA)
59
1.4
0.068
ng/L
05/14/24 13:53
05/15/24 21:37
1
Perfluoroheptanoic acid (PFHpA)
15
1.4
0.34
ng/L
05/14/24 13:53
05/15/24 21:37
1
Perfluorooctanoic acid (PFOA)
19
1.4
0.34
ng/L
05/14/24 13:53
05/15/24 21:37
1
Perfluorononanoic acid (PFNA)
0.39 J
1.4
0.068
ng/L
05/14/24 13:53
05/15/24 21:37
1
Perfluorodecanoic acid (PFDA)
<0.068 ,+
1.4
0.068
ng/L
05/14/24 13:53
05/15/24 21:37
1
Perfluoroundecanoic acid (PFUnA)
<0.34
1.4
0.34
ng/L
05/14/24 13:53
05/15/24 21:37
1
Perfluorododecanoic acid (PFDoA)
<0.34
1.4
0.34
ng/L
05/14/24 13:53
05/15/24 21:37
1
Perfluorotridecanoic acid (PFTrDA)
<0.34
1.4
0.34
ng/L
05/14/24 13:53
05/15/24 21:37
1
Perfluorotetradecanoic acid (PFTA)
<0.34
1.4
0.34
ng/L
05/14/24 13:53
05/15/24 21:37
1
Perfluorobutanesulfonic acid
14
1.4
0.34
ng/L
05/14/24 13:53
05/15/24 21:37
1
(PFBS)
Perfluoropentanesulfonic acid
9.4
1.4
0.068
ng/L
05/14/24 13:53
05/15/24 21:37
1
(PFPeS)
Perfluorohexanesulfonic acid
39
1.4
0.34
ng/L
05/14/24 13:53
05/15/24 21:37
1
(PFHxS)
Perfluoroheptanesulfonic acid
<0.068
1.4
0.068
ng/L
05/14/24 13:53
05/15/24 21:37
1
(PFHpS)
Perfluorooctanesulfonic acid
39
1.4
0.34
ng/L
05/20/24 14:57
05/21/24 16:29
1
(PFOS)
Perfluorononanesulfonic acid (PFNS)
<0.068
1.4
0.068
ng/L
05/14/24 13:53
05/15/24 21:37
1
Perfluorododecanesulfonic acid
<0.34 '-
1.4
0.34
ng/L
05/14/24 13:53
05/15/24 21:37
1
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
<0.34
2.7
0.34
ng/L
05/14/24 13:53
05/15/24 21:37
1
sulfonic acid (4:2 FTS)
1 H,1 1-1,2H,21-1-Perfluorooctane sulfonic
<0.34
2.7
0.34
ng/L
05/14/24 13:53
05/15/24 21:37
1
acid (6:2 FTS)
11-1,11-1,2H,21-1-Perfluorodecane
<0.34
2.7
0.34
ng/L
05/14/24 13:53
05/15/24 21:37
1
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.068
1.4
0.068
ng/L
05/14/24 13:53
05/15/24 21:37
1
N-methylperfluorooctane sulfonamide
<0.34
1.4
0.34
ng/L
05/14/24 13:53
05/15/24 21:37
1
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<0.34
1.4
0.34
ng/L
05/14/24 13:53
05/15/24 21:37
1
(NETOSA)
N-methylperfluorooctanesulfonamidoa
<0.34
1.4
0.34
ng/L
05/14/24 13:53
05/15/24 21:37
1
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<0.34
1.4
0.34
ng/L
05/14/24 13:53
05/15/24 21:37
1
etic acid (NEtFOSAA)
N-methylperfluorooctane
<1.4
6.8
1.4
ng/L
05/14/24 13:53
05/15/24 21:37
1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<1.4
6.8
1.4
ng/L
05/14/24 13:53
05/15/24 21:37
1
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide Dimer
<0.34
1.4
0.34
ng/L
05/14/24 13:53
05/15/24 21:37
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<0.34
1.4
0.34
ng/L
05/14/24 13:53
05/15/24 21:37
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<0.34
1.4
0.34
ng/L
05/14/24 13:53
05/15/24 21:37
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<0.34
1.4
0.34
ng/L
05/14/24 13:53
05/15/24 21:37
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<0.34
1.4
0.34
ng/L
05/14/24 13:53
05/15/24 21:37
1
e-1-sulfonic acid (9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<0.51
1.4
0.51
ng/L
05/14/24 13:53
05/15/24 21:37
1
e-1-sulfonic acid (11Cl-PF30UdS)
Eurofins Raleigh
Page 25 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Client Sample ID: MW-17 Lab Sample ID: 752-19362-8
Date Collected: 04/29/24 15:30 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Analyte
Result Qualifier
RL
MDL
Unit
Perfluoro (2-ethoxyethane) sulfonic
<0.34
1.4
0.34
ng/L
acid (PFEESA)
3-Perfluoropropylpropanoic acid (3:3
<0.68
2.7
0.68
ng/L
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<1.8
6.8
1.8
ng/L
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<1.8
6.8
1.8
ng/L
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.068
1.4
0.068
ng/L
Perfluoro-3-methoxypropanoic acid
<0.34
1.4
0.34
ng/L
(PFMPA)
Isotope Dilution
%Recovery Qualifier
Limits
13C4 PFBA
66.9
5 - 130
13C5 PFPeA
67.0
40 - 130
13C5 PFHxA
72.6
40 - 130
13C4 PFHpA
70.2
40 - 130
13C8 PFOA
75.0
40 - 130
13C9 PFNA
96.3
40 - 130
13C6 PFDA
60.8
40 - 130
13C7 PFUnA
52.9
30 - 130
13C2 PFDoA
42.4
10 - 130
13C2 PFTeDA
39.1
10 - 130
13C3 PFBS
80.4
40 - 135
13C3 PFHxS
75.3
40 - 130
13C8 PFOS
81.9
40 - 130
13C8 PFOS
30.0 *5-
40 - 130
13C8 FOSA
59.0
40 - 130
d3-NMeFOSAA
75.9
40 - 170
d5-NEtFOSAA
69.6
25 - 135
M2-4:2 FTS
140
40 - 200
M2-6:2 FTS
82.2
40 - 200
M2-8:2 FTS
68.3
40 - 300
13C3 HFPO-DA
72.3
40 - 130
d7-N-McFOSE-M
71.4
10 - 130
d9-N-EtFOSE-M
67.8
10 - 130
d5-NEtPFOSA
75.2
10 - 130
d3-NMePFOSA
63.6
10 - 130
D Prepared Analyzed Dil Fac
05/14/24 13:53 05/15/24 21:37 1
05/14/24 13:53 05/15/24 21:37 1
05/14/24 13:53 05/15/24 21:37
05/14/24 13:53 05/15/24 21:37
05/14/24 13:53 05/15/24 21:37
05/14/24 13:53 05/15/24 21:37
Prepared
Analyzed
05114124 13:53
05/15/24 21:37
05114124 13:53
05/15/24 21:37
05114124 13:53
05115124 21:37
05114124 13:53
05115124 21:37
05114124 13:53
05115124 21:37
05114124 13:53
05115124 21:37
05114124 13:53
05115124 21:37
05114124 13:53
05115124 21:37
05114124 13:53
05115124 21:37
05114124 13:53
05115124 21:37
05114124 13:53
05115124 21:37
05114124 13:53
05115124 21:37
05114124 13:53
05115124 21:37
05120124 14:57
05121124 16:29
05114124 13:53
05115124 21:37
05114124 13:53
05115124 21:37
05114124 13:53
05115124 21:37
05114124 13:53
05115124 21:37
05114124 13:53
05115124 21:37
05114124 13:53
05115124 21:37
05114124 13:53
05115124 21:37
05114124 13:53
05115124 21:37
05114124 13:53
05115124 21:37
05114124 13:53
05115124 21:37
05114124 13:53
05115124 21:37
Eurofins Raleigh
Page 26 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Job ID: 752-19362-1
Client Sample ID: MW-3R Lab Sample ID: 752-19362-9
Date Collected: 04/29/24 15:45 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Analyte Result Qualifier RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Perfluorobutanoic acid (PFBA)
29 J
40
10
ng/L
05/14/24 13:53
05/15/24 22:24
1
Perfluoropentanoic acid (PFPeA)
<5.0
20
5.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
Perfluorohexanoic acid (PFHxA)
67
20
1.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
Perfluoroheptanoic acid (PFHpA)
16 J
20
5.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
Perfluorooctanoic acid (PFOA)
25
20
5.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
Perfluoronenanoic acid (PFNA)
<1.0
20
1.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
Perfluorodecanoic acid (PFDA)
<1.0 ,+
20
1.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
Perfluoroundecanoic acid (PFUnA)
<5.0
20
5.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
Perfluorododecanoic acid (PFDoA)
<5.0
20
5.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
Perfluorotridecanoic acid (PFTrDA)
<5.0
20
5.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
Perfluorotetradecanoic acid (PFTA)
<5.0
20
5.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
Perfluorooutanesulfonic acid (PFBS)
<5.0
20
5.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
Perfluoropentanesulfonic acid
2.1 J
20
1.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
(PFPeS)
Perfluorohexanesulfonic acid
22
20
5.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
(PFHxS)
Perfluoroheptanesulfonic acid
<1.0
20
1.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
(PFHpS)
Perfluorooctanesulfonic acid (PFOS)
<5.0 ,+
20
5.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
Perfluorononanesulfonic acid (PFNS)
<1.0
20
1.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
Perfluorododecanesulfonic acid
<5.0 "-
20
5.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
<5.0
40
5.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
sulfonic acid (4:2 FTS)
1 H,1 H,2H,2H-Perfluorooctane sulfonic
<5.0
40
5.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
acid (6:2 FTS)
11-1,11-1,2H,21-1-Perfluorodecane
<5.0
40
5.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<1.0
20
1.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
N-methylperfluorooctane sulfonamide
<5.0
20
5.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<5.0
20
5.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
(N EtFOSA)
N-methylperfluorooctanesulfonamidoa
<5.0
20
5.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<5.0
20
5.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
etic acid (NEtFOSAA)
N-methylperfluorooctane
<20
100
20
ng/L
05/14/24 13:53
05/15/24 22:24
1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<20
100
20
ng/L
05/14/24 13:53
05/15/24 22:24
1
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide Dimer
<5.0
20
5.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<5.0
20
5.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<5.0
20
5.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<5.0
20
5.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<5.0
20
5.0
ng/L
05/14/24 13:53
05/15/24 22:24
1
e-1-sulfonic acid(9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<7.6
20
7.6
ng/L
05/14/24 13:53
05/15/24 22:24
1
e-1-sulfonic acid (11 CI-PF30UdS)
Eurofins Raleigh
Page 27 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Client Sample ID: MW-3R Lab Sample ID: 752-19362-9
Date Collected: 04/29/24 15:45 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Analyte
Result Qualifier
RL
MDL
Unit
Perfluoro (2-ethoxyethane) sulfonic
<5.0
20
5.0
ng/L
acid (PFEESA)
3-Perfluoropropylpropanoic acid (3:3
<10
40
10
ng/L
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<27
100
27
ng/L
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<27
100
27
ng/L
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<1.0
20
1.0
ng/L
Perfluoro-3-methoxypropanoic acid
<5.0
20
5.0
ng/L
(PFMPA)
Isotope Dilution
%Recovery Qualifier
Limits
13C4 PFBA
69.1
5 - 130
13C5 PFPeA
68.6
40 - 130
13C5 PFHxA
75.4
40 - 130
13C4 PFHpA
72.5
40 - 130
13C8 PFOA
72.9
40 - 130
13C9 PFNA
99.4
40 - 130
13C6 PFDA
64.9
40 - 130
13C7 PFUnA
58.1
30 - 130
13C2 PFDoA
51.1
10 - 130
13C2 PFTeDA
49.7
10 - 130
13C3 PFBS
79.8
40 - 135
13C3 PFHxS
73.9
40 - 130
13C8 PFOS
92.1
40 - 130
13C8 FOSA
67.9
40 - 130
d3-NMeFOSAA
82.8
40 - 170
d5-NEtFOSAA
78.8
25 - 135
M2-4:2 FTS
109
40 - 200
M2-6:2 FTS
81.9
40 - 200
M2-8:2 FTS
75.5
40 - 300
13C3 HFPO-DA
76.0
40 - 130
d7-N-McFOSE-M
90.3
10 - 130
d9-N-EtFOSE-M
89.1
10 - 130
d5-NEtPFOSA
98.1
10 - 130
d3-NMePFOSA
80.3
10 - 130
D Prepared Analyzed Dil Fac
05/14/24 13:53 05/15/24 22:24 1
05/14/24 13:53 05/15/24 22:24 1
05/14/24 13:53 05/15/24 22:24
05/14/24 13:53 05/15/24 22:24
05/14/24 13:53 05/15/24 22:24
05/14/24 13:53 05/15/24 22:24
Prepared
Analyzed
05114124 13:53
05115124 22:24
05114124 13:53
05/15/24 22:24
05114124 13:53
05115124 22:24
05114124 13:53
05115124 22:24
05114124 13:53
05115124 22:24
05114124 13:53
05115124 22:24
05114124 13:53
05115124 22:24
05114124 13:53
05115124 22:24
05114124 13:53
05115124 22:24
05114124 13:53
05115124 22:24
05114124 13:53
05115124 22:24
05114124 13:53
05115124 22:24
05114124 13:53
05115124 22:24
05114124 13:53
05115124 22:24
05114124 13:53
05115124 22:24
05114124 13:53
05115124 22:24
05114124 13:53
05115124 22:24
05114124 13:53
05115124 22:24
05114124 13:53
05115124 22:24
05114124 13:53
05115124 22:24
05114124 13:53
05115124 22:24
05114124 13:53
05115124 22:24
05114124 13:53
05115124 22:24
05114124 13:53
05115124 22:24
Eurofins Raleigh
Page 28 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Job ID: 752-19362-1
Client Sample ID: SW-4 Lab Sample ID: 752-19362-10
Date Collected: 04/29/24 16:15 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Analyte Result Qualifier RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Perfluorobutanoic acid (PFBA)
2.0 J
2.8
0.71
ng/L
05/14/24 13:53
05/15/24 22:39
1
Perfluoropentanoic acid (PFPeA)
3.0
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 22:39
1
Perfluorohexanoic acid (PFHxA)
3.8
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 22:39
1
Perfluoroheptanoic acid (PFHpA)
1.4
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 22:39
1
Perfluorooctanoic acid (PFOA)
2.3
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 22:39
1
Perfluorononanoic acid (PFNA)
0.12 J
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 22:39
1
Perfluorodecanoic acid (PFDA)
<0.071 *+
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 22:39
1
Perfluoroundecanoic acid (PFUnA)
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 22:39
1
Perfluorododecanoic acid (PFDoA)
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 22:39
1
Perfluorotridecanoic acid (PFTrDA)
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 22:39
1
Perfluorotetradecanoic acid (PFTA)
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 22:39
1
Perfluorobutanesulfonic acid
1.2 J
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 22:39
1
(PFBS)
Perfluoropentanesulfonic acid
0.62 J
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 22:39
1
(PFPeS)
Perfluorohexanesulfonic acid
2.4
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 22:39
1
(PFHxS)
Perfluoroheptanesulfonic acid
<0.071
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 22:39
1
(PFHpS)
Perfluorooctanesulfonic acid
2.3
1.4
0.35
ng/L
05/20/24 14:57
05/21/24 16:45
1
(PFOS)
Perfluorononanesulfonic acid (PFNS)
<0.071
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 22:39
1
Perfluorododecanesulfonic acid
<0.36 `-
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 22:39
1
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
<0.36
2.8
0.36
ng/L
05/14/24 13:53
05/15/24 22:39
1
sulfonic acid (4:2 FTS)
1 H,1 1-1,2H,21-1-Perfluorooctane sulfonic
<0.36
2.8
0.36
ng/L
05/14/24 13:53
05/15/24 22:39
1
acid (6:2 FTS)
11-1,11-1,2H,21-1-Perfluorodecane
<0.36
2.8
0.36
ng/L
05/14/24 13:53
05/15/24 22:39
1
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.071
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 22:39
1
N-methylperfluorooctane sulfonamide
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 22:39
1
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 22:39
1
(NETOSA)
N-methylperfluorooctanesulfonamidoa
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 22:39
1
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 22:39
1
etic acid (NEtFOSAA)
N-methylperfluorooctane
<1.4
7.1
1.4
ng/L
05/14/24 13:53
05/15/24 22:39
1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<1.4
7.1
1.4
ng/L
05/14/24 13:53
05/15/24 22:39
1
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide Dimer
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 22:39
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 22:39
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 22:39
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 22:39
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 22:39
1
e-1-sulfonic acid (9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<0.53
1.4
0.53
ng/L
05/14/24 13:53
05/15/24 22:39
1
e-1-sulfonic acid (11Cl-PF30UdS)
Eurofins Raleigh
Page 29 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Client Sample ID: SW-4 Lab Sample ID: 752-19362-10
Date Collected: 04/29/24 16:15 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Analyte
Result Qualifier
RL
MDL
Unit
Perfluoro (2-ethoxyethane) sulfonic
<0.36
1.4
0.36
ng/L
acid (PFEESA)
3-Perfluoropropylpropanoic acid (3:3
<0.71
2.8
0.71
ng/L
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<1.9
7.1
1.9
ng/L
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<1.9
7.1
1.9
ng/L
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.071
1.4
0.071
ng/L
Perfluoro-3-methoxypropanoic acid
<0.36
1.4
0.36
ng/L
(PFMPA)
Isotope Dilution
%Recovery Qualifier
Limits
13C4 PFBA
71.7
5 - 130
13C5 PFPeA
72.5
40 - 130
13C5 PFHxA
78.4
40 - 130
13C4 PFHpA
75.0
40 - 130
13C8 PFOA
80.5
40 - 130
13C9 PFNA
102
40 - 130
13C6 PFDA
67.9
40 - 130
13C7 PFUnA
60.5
30 - 130
13C2 PFDoA
50.3
10 - 130
13C2 PFTeDA
47.5
10 - 130
13C3 PFBS
83.7
40 - 135
13C3 PFHxS
79.8
40 - 130
13C8 PFOS
94.7
40 - 130
13C8 PFOS
57.4
40 - 130
13C8 FOSA
72.9
40 - 130
d3-NMeFOSAA
84.9
40 - 170
d5-NEtFOSAA
80.1
25 - 135
M2-4:2 FTS
89.1
40 - 200
M2-6:2 FTS
79.2
40 - 200
M2-8:2 FTS
75.0
40 - 300
13C3 HFPO-DA
81.3
40 - 130
d7-N-McFOSE-M
84.4
10 - 130
d9-N-EtFOSE-M
81.2
10 - 130
d5-NEtPFOSA
82.4
10 - 130
d3-NMePFOSA
73.2
10 - 130
D Prepared Analyzed Dil Fac
05/14/24 13:53 05/15/24 22:39
05/14/24 13:53 05/15/24 22:39
05/14/24 13:53 05/15/24 22:39
05/14/24 13:53 05/15/24 22:39
05/14/24 13:53 05/15/24 22:39
Prepared
Analyzed
05114124 13:53
05115124 22.39
05114124 13:53
05/15/24 22:39
05114124 13:53
05115124 22:39
05114124 13:53
05115124 22:39
05114124 13:53
05115124 22:39
05114124 13:53
05115124 22:39
05114124 13:53
05115124 22:39
05114124 13:53
05115124 22:39
05114124 13:53
05115124 22:39
05114124 13:53
05115124 22:39
05114124 13:53
05115124 22:39
05114124 13:53
05115124 22:39
05114124 13:53
05115124 22:39
05120124 14:57
05121124 16:45
05114124 13:53
05115124 22:39
05114124 13:53
05115124 22:39
05114124 13:53
05115124 22:39
05114124 13:53
05115124 22:39
05114124 13:53
05115124 22:39
05114124 13:53
05115124 22:39
05114124 13:53
05115124 22:39
05114124 13:53
05115124 22:39
05114124 13:53
05115124 22:39
05114124 13:53
05115124 22:39
05114124 13:53
05115124 22:39
Eurofins Raleigh
Page 30 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Job ID: 752-19362-1
Client Sample ID: MW-20 Lab Sample ID: 752-19362-11
Date Collected: 04/29/24 16:00 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Analyte Result Qualifier RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Perfluorobutanoic acid (PFBA)
11
8.1
2.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
Perfluoropentanoic acid (PFPeA)
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
Perfluorohexanoic acid (PFHxA)
11
4.0
0.20
ng/L
05/14/24 13:53
05/15/24 22:54
1
Perfluoroheptanoic acid (PFHpA)
3.9 J
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
Perfluorooctanoic acid (PFOA)
3.9 J
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
Perfluorononanoic acid (PFNA)
<0.20
4.0
0.20
ng/L
05/14/24 13:53
05/15/24 22:54
1
Perfluorodecanoic acid (PFDA)
<0.20 *+
4.0
0.20
ng/L
05/14/24 13:53
05/15/24 22:54
1
Perfluoroundecanoic acid (PFUnA)
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
Perfluorododecanoic acid (PFDoA)
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
Perfluorotridecanoic acid (PFTrDA)
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
Perfluorotetradecanoic acid (PFTA)
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
Perfluorobutanesulfonic acid
1.6 J
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
(PFBS)
Perfluoropentanesulfonic acid
0.83 J
4.0
0.20
ng/L
05/14/24 13:53
05/15/24 22:54
1
(PFPeS)
Perfluorohexanesulfonic acid
1.1 J
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
(PFHxS)
Perfluoroheptanesulfonic acid
<0.20
4.0
0.20
ng/L
05/14/24 13:53
05/15/24 22:54
1
(PFHpS)
Perfluorooctanesulfonic acid (PFOS)
<1.0 *+
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
Perfluorononanesulfonic acid (PFNS)
<0.20
4.0
0.20
ng/L
05/14/24 13:53
05/15/24 22:54
1
Perfluorododecanesulfonic acid
<1.0 *-
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
(PFDoS)
1H,11-1,21-1,21-1-Perfluorohexane
<1.0
8.1
1.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
sulfonic acid (4:2 FTS)
1 H,1 1-1,2H,21-1-Perfluorooctane sulfonic
<1.0
8.1
1.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
acid (6:2 FTS)
11-1,11-1,2H,21-1-Perfluorodecane
<1.0
8.1
1.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.20
4.0
0.20
ng/L
05/14/24 13:53
05/15/24 22:54
1
N-methylperfluorooctane sulfonamide
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
(NEtFOSA)
N-methylperfluorooctanesulfonamidoa
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
etic acid (NEtFOSAA)
N-methylperfluorooctane
<4.0
20
4.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<4.0
20
4.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
sulfonamidoethanol (NETOSE)
Hexafluoropropylene Oxide Dimer
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 22:54
1
e-1-sulfonic acid (9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<1.5
4.0
1.5
ng/L
05/14/24 13:53
05/15/24 22:54
1
e-1-sulfonic acid (11Cl-PF30UdS)
Eurofins Raleigh
Page 31 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Client Sample ID: MW-20 Lab Sample ID: 752-19362-11
Date Collected: 04/29/24 16:00 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Analyte
Result Qualifier
RL
MDL
Unit
Perfluoro (2-ethoxyethane) sulfonic
<1.0
4.0
1.0
ng/L
acid (PFEESA)
3-Perfluoropropylpropanoic acid (3:3
<2.0
8.1
2.0
ng/L
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<5.5
20
5.5
ng/L
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<5.5
20
5.5
ng/L
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.20
4.0
0.20
ng/L
Perfluoro-3-methoxypropanoic acid
<1.0
4.0
1.0
ng/L
(PFMPA)
Isotope Dilution
%Recovery Qualifier
Limits
13C4 PFBA
72.2
5 - 130
13C5 PFPeA
73.8
40 - 130
13C5 PFHxA
80.5
40 - 130
13C4 PFHpA
76.0
40 - 130
13C8 PFOA
80.8
40 - 130
13C9 PFNA
105
40 - 130
13C6 PFDA
71.2
40 - 130
13C7 PFUnA
67.3
30 - 130
13C2 PFDoA
59.3
10 - 130
13C2 PFTeDA
56.3
10 - 130
13C3 PFBS
88.3
40 - 135
13C3 PFHxS
79.6
40 - 130
13C8 PFOS
99.9
40 - 130
13C8 FOSA
78.5
40 - 130
d3-NMeFOSAA
92.8
40 - 170
d5-NEtFOSAA
92.7
25 - 135
M2-4:2 FTS
92.6
40 - 200
M2-6:2 FTS
79.7
40 - 200
M2-8:2 FTS
81.3
40 - 300
13C3 HFPO-DA
82.3
40 - 130
d7-N-McFOSE-M
101
10 - 130
d9-N-EtFOSE-M
97.5
10 - 130
d5-NEtPFOSA
103
10 - 130
d3-NMePFOSA
85.3
10 - 130
D Prepared Analyzed Dil Fac
05/14/24 13:53 05/15/24 22:54 1
05/14/24 13:53 05/15/24 22:54 1 •
05/14/24 13:53 05/15/24 22:54
05/14/24 13:53 05/15/24 22:54
05/14/24 13:53 05/15/24 22:54
05/14/24 13:53 05/15/24 22:54
Prepared
Analyzed
05114124 13:53
05115124 22:54
05114124 13:53
05/15/24 22:54
05114124 13:53
05115124 22:54
05114124 13:53
05115124 22:54
05114124 13:53
05115124 22:54
05114124 13:53
05115124 22:54
05114124 13:53
05115124 22:54
05114124 13:53
05115124 22:54
05114124 13:53
05115124 22:54
05114124 13:53
05115124 22:54
05114124 13:53
05115124 22:54
05114124 13:53
05115124 22:54
05114124 13:53
05115124 22:54
05114124 13:53
05115124 22:54
05114124 13:53
05115124 22:54
05114124 13:53
05115124 22:54
05114124 13:53
05115124 22:54
05114124 13:53
05115124 22:54
05114124 13:53
05115124 22:54
05114124 13:53
05115124 22:54
05114124 13:53
05115124 22:54
05114124 13:53
05115124 22:54
05114124 13:53
05115124 22:54
05114124 13:53
05115124 22:54
Eurofins Raleigh
Page 32 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Job ID: 752-19362-1
Client Sample ID: MW-21 Lab Sample ID: 752-19362-12
Date Collected: 05/01/24 15:45 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Analyte Result Qualifier RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Perfluorobutanoic acid (PFBA)
24
2.8
0.71
ng/L
05/14/24 13:53
05/15/24 23:10
1
Perfluoropentanoic acid (PFPeA)
42
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 23:10
1
Perfluorohexanoic acid (PFHxA)
120
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 23:10
1
Perfluoroheptanoic acid (PFHpA)
15
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 23:10
1
Perfluorooctanoic acid (PFOA)
13
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 23:10
1
Perfluoronenanoic acid (PFNA)
<0.071
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 23:10
1
Perfluorodecanoic acid (PFDA)
<0.071 ,+
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 23:10
1
Perfluoroundecanoic acid (PFUnA)
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 23:10
1
Perfluorododecanoic acid (PFDoA)
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 23:10
1
Perfluorotridecanoic acid (PFTrDA)
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 23:10
1
Perfluorotetradecanoic acid (PFTA)
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 23:10
1
Perfluorooutanesulfonic acid (PFBS)
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 23:10
1
Perfluoropentanesulfonic acid
1.6
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 23:10
1
(PFPeS)
Perfluorohexanesulfonic acid
8.2
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 23:10
1
(PFHxS)
Perfluoroheptanesulfonic acid
<0.071
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 23:10
1
(PFHpS)
Perfluorooctanesulfonic acid (PFOS)
<0.35 ,+
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 23:10
1
Perfluorononanesulfonic acid (PFNS)
<0.071
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 23:10
1
Perfluorododecanesulfonic acid
<0.35 '-
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 23:10
1
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
<0.35
2.8
0.35
ng/L
05/14/24 13:53
05/15/24 23:10
1
sulfonic acid (4:2 FTS)
1 H,1 H,2H,2H-Perfluorooctane
0.90 J
2.8
0.35
ng/L
05/14/24 13:53
05/15/24 23:10
1
sulfonic acid (6:2 FTS)
1 H,1 H,2H,2H-Perfluorodecane
<0.35
2.8
0.35
ng/L
05/14/24 13:53
05/15/24 23:10
1
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.071
1.4
0.071
ng/L
05/14/24 13:53
05/15/24 23:10
1
N-methylperfluorooctane sulfonamide
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 23:10
1
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 23:10
1
(N EtFOSA)
N-methylperfluorooctanesulfonamidoa
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 23:10
1
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 23:10
1
etic acid (NEtFOSAA)
N-methylperfluorooctane
<1.4
7.1
1.4
ng/L
05/14/24 13:53
05/15/24 23:10
1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<1.4
7.1
1.4
ng/L
05/14/24 13:53
05/15/24 23:10
1
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide Dimer
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 23:10
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 23:10
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 23:10
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 23:10
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<0.35
1.4
0.35
ng/L
05/14/24 13:53
05/15/24 23:10
1
e-1-sulfonic acid(9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<0.53
1.4
0.53
ng/L
05/14/24 13:53
05/15/24 23:10
1
e-1-sulfonic acid (11 CI-PF30UdS)
Eurofins Raleigh
Page 33 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Client Sample ID: MW-21 Lab Sample ID: 752-19362-12
Date Collected: 05/01/24 15:45 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Analyte
Result Qualifier
RL
MDL
Unit
Perfluoro (2-ethoxyethane) sulfonic
<0.35
1.4
0.35
ng/L
acid (PFEESA)
3-Perfluoropropylpropanoic acid (3:3
<0.71
2.8
0.71
ng/L
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<1.9
7.1
1.9
ng/L
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<1.9
7.1
1.9
ng/L
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.071
1.4
0.071
ng/L
Perfluoro-3-methoxypropanoic acid
<0.35
1.4
0.35
ng/L
(PFMPA)
Isotope Dilution
%Recovery Qualifier
Limits
13C4 PFBA
76.3
5 - 130
13C5 PFPeA
74.8
40 - 130
13C5 PFHxA
80.4
40 - 130
13C4 PFHpA
79.8
40 - 130
13C8 PFOA
86.8
40 - 130
13C9 PFNA
109
40 - 130
13C6 PFDA
73.9
40 - 130
13C7 PFUnA
70.2
30 - 130
13C2 PFDoA
61.2
10 - 130
13C2 PFTeDA
60.6
10 - 130
13C3 PFBS
86.0
40 - 135
13C3 PFHxS
81.9
40 - 130
13C8 PFOS
106
40 - 130
13C8 FOSA
83.2
40 - 130
d3-NMeFOSAA
99.9
40 - 170
d5-NEtFOSAA
102
25 - 135
M2-4:2 FTS
227 `5+
40 - 200
M2-6:2 FTS
91.5
40 - 200
M2-8:2 FTS
81.0
40 - 300
13C3 HFPO-DA
83.5
40 - 130
d7-N-McFOSE-M
106
10 - 130
d9-N-EtFOSE-M
103
10 - 130
d5-NEtPFOSA
111
10 - 130
d3-NMePFOSA
94.7
10 - 130
D Prepared Analyzed Dil Fac
05/14/24 13:53 05/15/24 23:10 1
05/14/24 13:53 05/15/24 23:10 1
05/14/24 13:53 05/15/24 23:10
05/14/24 13:53 05/15/24 23:10
05/14/24 13:53 05/15/24 23:10
05/14/24 13:53 05/15/24 23:10
Prepared
Analyzed
05114124 13:53
05/15/24 23:10
05114124 13:53
05/15/24 23:10
05114124 13:53
05115124 23:10
05114124 13:53
05115124 23:10
05114124 13:53
05115124 23:10
05114124 13:53
05115124 23:10
05114124 13:53
05115124 23:10
05114124 13:53
05115124 23:10
05114124 13:53
05115124 23:10
05114124 13:53
05115124 23:10
05114124 13:53
05115124 23:10
05114124 13:53
05115124 23:10
05114124 13:53
05115124 23:10
05114124 13:53
05115124 23:10
05114124 13:53
05115124 23:10
05114124 13:53
05115124 23:10
05114124 13:53
05115124 23:10
05114124 13:53
05115124 23:10
05114124 13:53
05115124 23:10
05114124 13:53
05115124 23:10
05114124 13:53
05115124 23:10
05114124 13:53
05115124 23:10
05114124 13:53
05115124 23:10
05114124 13:53
05115124 23:10
Eurofins Raleigh
Page 34 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Client Sample ID: SW-1 Lab Sample ID: 752-19362-13
Date Collected: 05/01/24 12:30
Date Received: 05/03/24 09:50
Matrix: Water
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Analyte
Result Qualifier
RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Perfluorobutanoic acid (PFBA)
1.2 J
2.9
0.72
ng/L
05/14/24 13:53
05/15/24 23:25
1
Perfluoropentanoic acid (PFPeA)
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 23:25
1
Perfluorohexanoic acid (PFHxA)
3.7
1.4
0.072
ng/L
05/14/24 13:53
05/15/24 23:25
1
Perfluoroheptanoic acid (PFHpA)
0.55 J
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 23:25
1
Perfluorooctanoic acid (PFOA)
0.89 J
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 23:25
1
Perfluorononanoic acid (PFNA)
<0.072
1.4
0.072
ng/L
05/14/24 13:53
05/15/24 23:25
1
Perfluorodecanoic acid (PFDA)
<0.072 *+
1.4
0.072
ng/L
05/14/24 13:53
05/15/24 23:25
1
Perfluoroundecanoic acid (PFUnA)
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 23:25
1
Perfluorododecanoic acid (PFDoA)
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 23:25
1
Perfluorotridecanoic acid (PFTrDA)
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 23:25
1
Perfluorotetradecanoic acid (PFTA)
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 23:25
1
Perfluorobutanesulfonic acid
1.1 J
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 23:25
1
(PFBS)
Perfluoropentanesulfonic acid
0.16 J
1.4
0.072
ng/L
05/14/24 13:53
05/15/24 23:25
1
(PFPeS)
Perfluorohexanesulfonic acid
0.72 J
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 23:25
1
(PFHxS)
Perfluoroheptanesulfonic acid
<0.072
1.4
0.072
ng/L
05/14/24 13:53
05/15/24 23:25
1
(PFHpS)
Perfluorooctanesulfonic acid (PFOS)
<0.36 *+
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 23:25
1
Perfluorononanesulfonic acid (PFNS)
<0.072
1.4
0.072
ng/L
05/14/24 13:53
05/15/24 23:25
1
Perfluorododecanesulfonic acid
<0.36 *-
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 23:25
1
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
<0.36
2.9
0.36
ng/L
05/14/24 13:53
05/15/24 23:25
1
sulfonic acid (4:2 FTS)
1H,1H,2H,2H-Perfluorooctanesulfonic
<0.36
2.9
0.36
ng/L
05/14/24 13:53
05/15/24 23:25
1
acid (6:2 FTS)
1 H,1 H,2H,2H-Perfluorodecane
<0.36
2.9
0.36
ng/L
05/14/24 13:53
05/15/24 23:25
1
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.072
1.4
0.072
ng/L
05/14/24 13:53
05/15/24 23:25
1
N-methylperfluorooctane sulfonamide
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 23:25
1
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 23:25
1
(NEtFOSA)
N-methylperfluorooctanesulfonamidoa
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 23:25
1
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 23:25
1
etic acid (NEtFOSAA)
N-methylperfluorooctane
<1.4
7.2
1.4
ng/L
05/14/24 13:53
05/15/24 23:25
1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<1.4
7.2
1.4
ng/L
05/14/24 13:53
05/15/24 23:25
1
sulfonamidoethanol (NETOSE)
Hexafluoropropylene Oxide Dimer
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 23:25
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 23:25
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 23:25
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 23:25
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/15/24 23:25
1
e-1-sulfonic acid(9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<0.54
1.4
0.54
ng/L
05/14/24 13:53
05/15/24 23:25
1
e-1-sulfonic acid (11Cl-PF30UdS)
Eurofins Raleigh
Page 35 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Client Sample ID: SW-1 Lab Sample ID: 752-19362-13
Date Collected: 05/01/24 12:30 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Analyte
Result Qualifier
RL
MDL
Unit
Perfluoro (2-ethoxyethane) sulfonic
<0.36
1.4
0.36
ng/L
acid (PFEESA)
3-Perfluoropropylpropanoic acid (3:3
<0.72
2.9
0.72
ng/L
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<2.0
7.2
2.0
ng/L
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<2.0
7.2
2.0
ng/L
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.072
1.4
0.072
ng/L
Perfluoro-3-methoxypropanoic acid
<0.36
1.4
0.36
ng/L
(PFMPA)
Isotope Dilution
%Recovery Qualifier
Limits
13C4 PFBA
71.1
5 - 130
13C5 PFPeA
70.9
40 - 130
13C5 PFHxA
76.7
40 - 130
13C4 PFHpA
74.3
40 - 130
13C8 PFOA
82.1
40 - 130
13C9 PFNA
102
40 - 130
13C6 PFDA
67.6
40 - 130
13C7 PFUnA
62.2
30 - 130
13C2 PFDoA
52.9
10 - 130
13C2 PFTeDA
49.6
10 - 130
13C3 PFBS
82.4
40 - 135
13C3 PFHxS
77.0
40 - 130
13C8 PFOS
94.1
40 - 130
13C8 FOSA
77.7
40 - 130
d3-NMeFOSAA
90.3
40 - 170
d5-NEtFOSAA
86.4
25 - 135
M2-4:2 FTS
79.0
40 - 200
M2-6:2 FTS
79.7
40 - 200
M2-8:2 FTS
76.7
40 - 300
13C3 HFPO-DA
80.0
40 - 130
d7-N-McFOSE-M
92.6
10 - 130
d9-N-EtFOSE-M
89.0
10 - 130
d5-NEtPFOSA
92.3
10 - 130
d3-NMePFOSA
79.2
10 - 130
D Prepared Analyzed Dil Fac
05/14/24 13:53 05/15/24 23:25 1
05/14/24 13:53 05/15/24 23:25 1
05/14/24 13:53 05/15/24 23:25
05/14/24 13:53 05/15/24 23:25
05/14/24 13:53 05/15/24 23:25
05/14/24 13:53 05/15/24 23:25
Prepared
Analyzed
05114124 13:53
05/15/24 23:25
05114124 13:53
05/15/24 23:25
05114124 13:53
05115124 23:25
05114124 13:53
05115124 23:25
05114124 13:53
05115124 23:25
05114124 13:53
05115124 23:25
05114124 13:53
05115124 23:25
05114124 13:53
05115124 23:25
05114124 13:53
05115124 23:25
05114124 13:53
05115124 23:25
05114124 13:53
05115124 23:25
05114124 13:53
05115124 23:25
05114124 13:53
05115124 23:25
05114124 13:53
05115124 23:25
05114124 13:53
05115124 23:25
05114124 13:53
05115124 23:25
05114124 13:53
05115124 23:25
05114124 13:53
05115124 23:25
05114124 13:53
05115124 23:25
05114124 13:53
05115124 23:25
05114124 13:53
05115124 23:25
05114124 13:53
05115124 23:25
05114124 13:53
05115124 23:25
05114124 13:53
05115124 23:25
Eurofins Raleigh
Page 36 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Job ID: 752-19362-1
Client Sample ID: MW-9 Lab Sample ID: 752-19362-14
Date Collected: 05/02/24 11:00 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Analyte Result Qualifier RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Perfluorobutanoic acid (PFBA)
16
8.0
2.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
Perfluoropentanoic acid (PFPeA)
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
Perfluorohexanoic acid (PFHxA)
17
4.0
0.20
ng/L
05/14/24 13:53
05/15/24 23:40
1
Perfluoroheptanoic acid (PFHpA)
6.5
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
Perfluorooctanoic acid (PFOA)
6.4
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
Perfluoronenanoic acid (PFNA)
<0.20
4.0
0.20
ng/L
05/14/24 13:53
05/15/24 23:40
1
Perfluorodecanoic acid (PFDA)
<0.20 ,+
4.0
0.20
ng/L
05/14/24 13:53
05/15/24 23:40
1
Perfluoroundecanoic acid (PFUnA)
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
Perfluorododecanoic acid (PFDoA)
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
Perfluorotridecanoic acid (PFTrDA)
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
Perfluorotetradecanoic acid (PFTA)
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
Perfluorooutanesulfonic acid (PFBS)
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
Perfluoropentanesulfonic acid
<0.20
4.0
0.20
ng/L
05/14/24 13:53
05/15/24 23:40
1
(PFPeS)
Perfluorohexanesulfonic acid
1.8 J
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
(PFHxS)
Perfluoroheptanesulfonic acid
<0.20
4.0
0.20
ng/L
05/14/24 13:53
05/15/24 23:40
1
(PFHpS)
Perfluorooctanesulfonic acid (PFOS)
<1.0 ,+
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
Perfluorononanesulfonic acid (PFNS)
<0.20
4.0
0.20
ng/L
05/14/24 13:53
05/15/24 23:40
1
Perfluorododecanesulfonic acid
<1.0 "-
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
<1.0
8.0
1.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
sulfonic acid (4:2 FTS)
1 H,1 H,2H,2H-Perfluorooctane sulfonic
<1.0
8.0
1.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
acid (6:2 FTS)
11-1,11-1,2H,21-1-Perfluorodecane
<1.0
8.0
1.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.20
4.0
0.20
ng/L
05/14/24 13:53
05/15/24 23:40
1
N-methylperfluorooctane sulfonamide
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
(N EtFOSA)
N-methylperfluorooctanesulfonamidoa
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
etic acid (NEtFOSAA)
N-methylperfluorooctane
<4.0
20
4.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<4.0
20
4.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide Dimer
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 23:40
1
e-1-sulfonic acid(9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<1.5
4.0
1.5
ng/L
05/14/24 13:53
05/15/24 23:40
1
e-1-sulfonic acid (11 CI-PF30UdS)
Eurofins Raleigh
Page 37 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Client Sample ID: MW-9 Lab Sample ID: 752-19362-14
Date Collected: 05/02/24 11:00 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Analyte
Result Qualifier
RL
MDL
Unit
Perfluoro (2-ethoxyethane) sulfonic
<1.0
4.0
1.0
ng/L
acid (PFEESA)
3-Perfluoropropylpropanoic acid (3:3
<2.0
8.0
2.0
ng/L
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<5.4
20
5.4
ng/L
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<5.4
20
5.4
ng/L
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.20
4.0
0.20
ng/L
Perfluoro-3-methoxypropanoic acid
<1.0
4.0
1.0
ng/L
(PFMPA)
Isotope Dilution
%Recovery Qualifier
Limits
13C4 PFBA
70.2
5 - 130
13C5 PFPeA
67.1
40 - 130
13C5 PFHxA
75.7
40 - 130
13C4 PFHpA
71.2
40 - 130
13C8 PFOA
81.0
40 - 130
13C9 PFNA
106
40 - 130
13C6 PFDA
70.1
40 - 130
13C7 PFUnA
70.5
30 - 130
13C2 PFDoA
58.3
10 - 130
13C2 PFTeDA
59.5
10 - 130
13C3 PFBS
87.9
40 - 135
13C3 PFHxS
79.7
40 - 130
13C8 PFOS
95.5
40 - 130
13C8 FOSA
70.2
40 - 130
d3-NMeFOSAA
98.2
40 - 170
d5-NEtFOSAA
95.2
25 - 135
M2-4:2 FTS
260 `5+
40 - 200
M2-6:2 FTS
127
40 - 200
M2-8:2 FTS
93.7
40 - 300
13C3 HFPO-DA
70.7
40 - 130
d7-N-McFOSE-M
102
10 - 130
d9-N-EtFOSE-M
107
10 - 130
d5-NEtPFOSA
104
10 - 130
d3-NMePFOSA
85.2
10 - 130
D Prepared Analyzed Dil Fac
05/14/24 13:53 05/15/24 23:40 1
05/14/24 13:53 05/15/24 23:40 1 •
05/14/24 13:53 05/15/24 23:40
05/14/24 13:53 05/15/24 23:40
05/14/24 13:53 05/15/24 23:40
05/14/24 13:53 05/15/24 23:40
Prepared
Analyzed
05114124 13:53
05/15/24 23:40
05114124 13:53
05/15/24 23:40
05114124 13:53
05115124 23:40
05114124 13:53
05115124 23:40
05114124 13:53
05115124 23:40
05114124 13:53
05115124 23:40
05114124 13:53
05115124 23:40
05114124 13:53
05115124 23:40
05114124 13:53
05115124 23:40
05114124 13:53
05115124 23:40
05114124 13:53
05115124 23:40
05114124 13:53
05115124 23:40
05114124 13:53
05115124 23:40
05114124 13:53
05115124 23:40
05114124 13:53
05115124 23:40
05114124 13:53
05115124 23:40
05114124 13:53
05115124 23:40
05114124 13:53
05115124 23:40
05114124 13:53
05115124 23:40
05114124 13:53
05115124 23:40
05114124 13:53
05115124 23:40
05114124 13:53
05115124 23:40
05114124 13:53
05115124 23:40
05114124 13:53
05115124 23:40
Eurofins Raleigh
Page 38 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Job ID: 752-19362-1
Client Sample ID: SW-2 Lab Sample ID: 752-19362-15
Date Collected: 05/02/24 10:15 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Analyte Result Qualifier RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Perfluorobutanoic acid (PFBA)
6.1
3.5
0.87
ng/L
05/14/24 13:53
05/15/24 23:56
1
Perfluoropentanoic acid (PFPeA)
<0.43
1.7
0.43
ng/L
05/14/24 13:53
05/15/24 23:56
1
Perfluorohexanoic acid (PFHxA)
3.3
1.7
0.087
ng/L
05/14/24 13:53
05/15/24 23:56
1
Perfluoroheptanoic acid (PFHpA)
1.7
1.7
0.43
ng/L
05/14/24 13:53
05/15/24 23:56
1
Perfluorooctanoic acid (PFOA)
1.3 J
1.7
0.43
ng/L
05/14/24 13:53
05/15/24 23:56
1
Perfluorononanoic acid (PFNA)
<0.087
1.7
0.087
ng/L
05/14/24 13:53
05/15/24 23:56
1
Perfluorodecanoic acid (PFDA)
<0.087 *+
1.7
0.087
ng/L
05/14/24 13:53
05/15/24 23:56
1
Perfluoroundecanoic acid (PFUnA)
<0.43
1.7
0.43
ng/L
05/14/24 13:53
05/15/24 23:56
1
Perfluorododecanoic acid (PFDoA)
<0.43
1.7
0.43
ng/L
05/14/24 13:53
05/15/24 23:56
1
Perfluorotridecanoic acid (PFTrDA)
<0.43
1.7
0.43
ng/L
05/14/24 13:53
05/15/24 23:56
1
Perfluorotetradecanoic acid (PFTA)
<0.43
1.7
0.43
ng/L
05/14/24 13:53
05/15/24 23:56
1
Perfluorobutanesulfonic acid
0.78 J
1.7
0.43
ng/L
05/14/24 13:53
05/15/24 23:56
1
(PFBS)
Perfluoropentanesulfonic acid
0.31 J
1.7
0.087
ng/L
05/14/24 13:53
05/15/24 23:56
1
(PFPeS)
Perfluorohexanesulfonic acid
0.54 J
1.7
0.43
ng/L
05/14/24 13:53
05/15/24 23:56
1
(PFHxS)
Perfluoroheptanesulfonic acid
<0.087
1.7
0.087
ng/L
05/14/24 13:53
05/15/24 23:56
1
(PFHpS)
Perfluorooctanesulfonic acid (PFOS)
<0.43 *+
1.7
0.43
ng/L
05/14/24 13:53
05/15/24 23:56
1
Perfluorononanesulfonic acid (PFNS)
<0.087
1.7
0.087
ng/L
05/14/24 13:53
05/15/24 23:56
1
Perfluorododecanesulfonic acid
<0.43 *-
1.7
0.43
ng/L
05/14/24 13:53
05/15/24 23:56
1
(PFDoS)
1H,11-1,21-1,21-1-Perfluorohexane
<0.43
3.5
0.43
ng/L
05/14/24 13:53
05/15/24 23:56
1
sulfonic acid (4:2 FTS)
1 H,1 1-1,2H,21-1-Perfluorooctane sulfonic
<0.43
3.5
0.43
ng/L
05/14/24 13:53
05/15/24 23:56
1
acid (6:2 FTS)
11-1,11-1,2H,21-1-Perfluorodecane
<0.43
3.5
0.43
ng/L
05/14/24 13:53
05/15/24 23:56
1
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.087
1.7
0.087
ng/L
05/14/24 13:53
05/15/24 23:56
1
N-methylperfluorooctane sulfonamide
<0.43
1.7
0.43
ng/L
05/14/24 13:53
05/15/24 23:56
1
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<0.43
1.7
0.43
ng/L
05/14/24 13:53
05/15/24 23:56
1
(NEtFOSA)
N-methylperfluorooctanesulfonamidoa
<0.43
1.7
0.43
ng/L
05/14/24 13:53
05/15/24 23:56
1
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<0.43
1.7
0.43
ng/L
05/14/24 13:53
05/15/24 23:56
1
etic acid (NEtFOSAA)
N-methylperfluorooctane
<1.7
8.7
1.7
ng/L
05/14/24 13:53
05/15/24 23:56
1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<1.7
8.7
1.7
ng/L
05/14/24 13:53
05/15/24 23:56
1
sulfonamidoethanol (NETOSE)
Hexafluoropropylene Oxide Dimer
<0.43
1.7
0.43
ng/L
05/14/24 13:53
05/15/24 23:56
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<0.43
1.7
0.43
ng/L
05/14/24 13:53
05/15/24 23:56
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<0.43
1.7
0.43
ng/L
05/14/24 13:53
05/15/24 23:56
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<0.43
1.7
0.43
ng/L
05/14/24 13:53
05/15/24 23:56
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<0.43
1.7
0.43
ng/L
05/14/24 13:53
05/15/24 23:56
1
e-1-sulfonic acid (9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<0.65
1.7
0.65
ng/L
05/14/24 13:53
05/15/24 23:56
1
e-1-sulfonic acid (11Cl-PF30UdS)
Eurofins Raleigh
Page 39 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Client Sample ID: SW-2 Lab Sample ID: 752-19362-15
Date Collected: 05/02/24 10:15 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Analyte
Result Qualifier
RL
MDL
Unit
Perfluoro (2-ethoxyethane) sulfonic
<0.43
1.7
0.43
ng/L
acid (PFEESA)
3-Perfluoropropylpropanoic acid (3:3
<0.87
3.5
0.87
ng/L
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<2.3
8.7
2.3
ng/L
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<2.3
8.7
2.3
ng/L
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.087
1.7
0.087
ng/L
Perfluoro-3-methoxypropanoic acid
<0.43
1.7
0.43
ng/L
(PFMPA)
Isotope Dilution
%Recovery Qualifier
Limits
13C4 PFBA
71.6
5 - 130
13C5 PFPeA
70.2
40 - 130
13C5 PFHxA
77.2
40 - 130
13C4 PFHpA
74.0
40 - 130
13C8 PFOA
82.9
40 - 130
13C9 PFNA
103
40 - 130
13C6 PFDA
69.2
40 - 130
13C7 PFUnA
65.4
30 - 130
13C2 PFDoA
56.4
10 - 130
13C2 PFTeDA
55.9
10 - 130
13C3 PFBS
83.1
40 - 135
13C3 PFHxS
78.1
40 - 130
13C8 PFOS
93.3
40 - 130
13C8 FOSA
76.6
40 - 130
d3-NMeFOSAA
92.1
40 - 170
d5-NEtFOSAA
87.8
25 - 135
M2-4:2 FTS
95.8
40 - 200
M2-6:2 FTS
86.6
40 - 200
M2-8:2 FTS
78.4
40 - 300
13C3 HFPO-DA
80.1
40 - 130
d7-N-McFOSE-M
97.9
10 - 130
d9-N-EtFOSE-M
96.7
10 - 130
d5-NEtPFOSA
102
10 - 130
d3-NMePFOSA
86.8
10 - 130
D Prepared Analyzed Dil Fac
05/14/24 13:53 05/15/24 23:56 1
05/14/24 13:53 05/15/24 23:56 1
05/14/24 13:53 05/15/24 23:56
05/14/24 13:53 05/15/24 23:56
05/14/24 13:53 05/15/24 23:56
05/14/24 13:53 05/15/24 23:56
Prepared
Analyzed
05114124 13:53
05/15/24 23:56
05114124 13:53
05/15/24 23:56
05114124 13:53
05115124 23:56
05114124 13:53
05115124 23:56
05114124 13:53
05115124 23:56
05114124 13:53
05115124 23:56
05114124 13:53
05115124 23:56
05114124 13:53
05115124 23:56
05114124 13:53
05115124 23:56
05114124 13:53
05115124 23:56
05114124 13:53
05115124 23:56
05114124 13:53
05115124 23:56
05114124 13:53
05115124 23:56
05114124 13:53
05115124 23:56
05114124 13:53
05115124 23:56
05114124 13:53
05115124 23:56
05114124 13:53
05115124 23:56
05114124 13:53
05115124 23:56
05114124 13:53
05115124 23:56
05114124 13:53
05115124 23:56
05114124 13:53
05115124 23:56
05114124 13:53
05115124 23:56
05114124 13:53
05115124 23:56
05114124 13:53
05115124 23:56
Eurofins Raleigh
Page 40 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Job ID: 752-19362-1
Client Sample ID: MW-1 Lab Sample ID: 752-19362-16
Date Collected: 05/02/24 12:30 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Analyte Result Qualifier RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Perfluorobutanoic acid (PFBA)
4.7
2.7
0.68
ng/L
05/16/24 11:26
05/16/24 17:50
1
Perfluoropentanoic acid (PFPeA)
<0.34
1.4
0.34
ng/L
05/16/24 11:26
05/16/24 17:50
1
Perfluorohexanoic acid (PFHxA)
1.8
1.4
0.068
ng/L
05/16/24 11:26
05/16/24 17:50
1
Perfluoroheptanoic acid (PFHpA)
1.7 1
1.4
0.34
ng/L
05/16/24 11:26
05/16/24 17:50
1
Perfluorooctanoic acid (PFOA)
4.4
1.4
0.34
ng/L
05/16/24 11:26
05/16/24 17:50
1
Perfluorononanoic acid (PFNA)
<0.068
1.4
0.068
ng/L
05/16/24 11:26
05/16/24 17:50
1
Perfluorodecanoic acid (PFDA)
<0.068
1.4
0.068
ng/L
05/16/24 11:26
05/16/24 17:50
1
Perfluoroundecanoic acid (PFUnA)
<0.34
1.4
0.34
ng/L
05/16/24 11:26
05/16/24 17:50
1
Perfluorododecanoic acid (PFDoA)
<0.34
1.4
0.34
ng/L
05/16/24 11:26
05/16/24 17:50
1
Perfluorotridecanoic acid (PFTrDA)
<0.34
1.4
0.34
ng/L
05/16/24 11:26
05/16/24 17:50
1
Perfluorotetradecanoic acid (PFTA)
<0.34
1.4
0.34
ng/L
05/16/24 11:26
05/16/24 17:50
1
Perfluorobutanesulfonic acid
1.9
1.4
0.34
ng/L
05/16/24 11:26
05/16/24 17:50
1
(PFBS)
Perfluoropentanesulfonic acid
0.40 J
1.4
0.068
ng/L
05/16/24 11:26
05/16/24 17:50
1
(PFPeS)
Perfluorohexanesulfonic acid
1.9
1.4
0.34
ng/L
05/16/24 11:26
05/16/24 17:50
1
(PFHxS)
Perfluoroheptanesulfonic acid
<0.068
1.4
0.068
ng/L
05/16/24 11:26
05/16/24 17:50
1
(PFHpS)
Perfluorooctanesulfonic acid (PFOS)
<0.34
1.4
0.34
ng/L
05/16/24 11:26
05/16/24 17:50
1
Perfluorononanesulfonic acid (PFNS)
<0.068
1.4
0.068
ng/L
05/16/24 11:26
05/16/24 17:50
1
Perfluorododecanesulfonic acid
<0.34 *- *1
1.4
0.34
ng/L
05/16/24 11:26
05/16/24 17:50
1
(PFDoS)
11-1,11-1,21-1,21-1-Perfluorohexane
<0.34
2.7
0.34
ng/L
05/16/24 11:26
05/16/24 17:50
1
sulfonic acid (4:2 FTS)
1H,1H,2H,2H-Perfluorooctanesulfonic
<0.34
2.7
0.34
ng/L
05/16/24 11:26
05/16/24 17:50
1
acid (6:2 FTS)
11-1,11-1,2H,21-1-Perfluorodecane
<0.34
2.7
0.34
ng/L
05/16/24 11:26
05/16/24 17:50
1
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.068
1.4
0.068
ng/L
05/16/24 11:26
05/16/24 17:50
1
N-methylperfluorooctane sulfonamide
<0.34
1.4
0.34
ng/L
05/16/24 11:26
05/16/24 17:50
1
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<0.34
1.4
0.34
ng/L
05/16/24 11:26
05/16/24 17:50
1
(NEtFOSA)
N-methylperfluorooctanesulfonamidoa
<0.34
1.4
0.34
ng/L
05/16/24 11:26
05/16/24 17:50
1
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<0.34
1.4
0.34
ng/L
05/16/24 11:26
05/16/24 17:50
1
etic acid (NEtFOSAA)
N-methylperfluorooctane
<1.4
6.8
1.4
ng/L
05/16/24 11:26
05/16/24 17:50
1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<1.4
6.8
1.4
ng/L
05/16/24 11:26
05/16/24 17:50
1
sulfonamidoethanol (NETOSE)
Hexafluoropropylene Oxide Dimer
<0.34
1.4
0.34
ng/L
05/16/24 11:26
05/16/24 17:50
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<0.34
1.4
0.34
ng/L
05/16/24 11:26
05/16/24 17:50
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<0.34
1.4
0.34
ng/L
05/16/24 11:26
05/16/24 17:50
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<0.34
1.4
0.34
ng/L
05/16/24 11:26
05/16/24 17:50
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<0.34
1.4
0.34
ng/L
05/16/24 11:26
05/16/24 17:50
1
e-1-sulfonic acid (9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<0.51
1.4
0.51
ng/L
05/16/24 11:26
05/16/24 17:50
1
e-1-sulfonic acid (11Cl-PF30UdS)
Eurofins Raleigh
Page 41 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Client Sample ID: MW-1 Lab Sample ID: 752-19362-16
Date Collected: 05/02/24 12:30 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Analyte
Result Qualifier
RL
MDL
Unit
Perfluoro (2-ethoxyethane) sulfonic
<0.34
1.4
0.34
ng/L
acid (PFEESA)
3-Perfluoropropylpropanoic acid (3:3
<0.68
2.7
0.68
ng/L
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<1.8
6.8
1.8
ng/L
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<1.8
6.8
1.8
ng/L
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.068
1.4
0.068
ng/L
Perfluoro-3-methoxypropanoic acid
<0.34
1.4
0.34
ng/L
(PFMPA)
Isotope Dilution
%Recovery Qualifier
Limits
13C4 PFBA
64.9
5 - 130
13C5 PFPeA
53.8
40 - 130
13C5 PFHxA
69.7
40 - 130
13C4 PFHpA
59.0
40 - 130
13C8 PFOA
73.5
40 - 130
13C9 PFNA
70.0
40 - 130
13C6 PFDA
65.0
40 - 130
13C7 PFUnA
58.7
30 - 130
13C2 PFDoA
43.2
10 - 130
13C2 PFTeDA
27.6
10 - 130
13C3 PFBS
77.8
40 - 135
13C3 PFHxS
63.6
40 - 130
13C8 PFOS
61.8
40 - 130
13C8 FOSA
51.0
40 - 130
d3-NMeFOSAA
93.7
40 - 170
d5-NEtFOSAA
79.7
25 - 135
M2-4:2 FTS
227 `5+
40 - 200
M2-6:2 FTS
361 `5+
40 - 200
M2-8:2 FTS
85.3
40 - 300
13C3 HFPO-DA
56.0
40 - 130
d7-N-McFOSE-M
72.4
10 - 130
d9-N-EtFOSE-M
61.0
10 - 130
d5-NEtPFOSA
73.1
10 - 130
d3-NMePFOSA
63.9
10 - 130
D Prepared Analyzed Dil Fac
05/16/2411:26 05/16/2417:50 1 w
05/16/2411:26 05/16/2417:50 1 r
05/16/2411:26 05/16/2417:50
05/16/2411:26 05/16/2417:50
05/16/2411:26 05/16/2417:50
05/16/2411:26 05/16/2417:50
Prepared
Analyzed
0511612411:26
0511612417.50
0511612411:26
0511612417:50
0511612411:26
0511612417:50
0511612411:26
0511612417:50
0511612411:26
0511612417:50
0511612411:26
0511612417:50
0511612411:26
0511612417:50
0511612411:26
0511612417:50
0511612411:26
0511612417:50
0511612411:26
0511612417:50
0511612411:26
0511612417:50
0511612411:26
0511612417:50
0511612411:26
0511612417.50
0511612411:26
0511612417.50
0511612411:26
0511612417.50
0511612411:26
0511612417:50
0511612411:26
0511612417:50
0511612411:26
0511612417:50
0511612411:26
0511612417:50
0511612411:26
0511612417:50
0511612411:26
0511612417:50
0511612411:26
0511612417:50
0511612411:26
0511612417:50
0511612411:26
0511612417:50
Eurofins Raleigh
Page 42 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Job ID: 752-19362-1
Client Sample ID: MW-11 Lab Sample ID: 752-19362-17
Date Collected: 05/02/24 13:30 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Analyte Result Qualifier RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Perfluorobutanoic acid (PFBA)
14
2.8
0.71
ng/L
05/16/24 11:26
05/16/24 18:06
1
Perfluoropentanoic acid (PFPeA)
<0.36
1.4
0.36
ng/L
05/16/24 11:26
05/16/24 18:06
1
Perfluorohexanoic acid (PFHxA)
4.7
1.4
0.071
ng/L
05/16/24 11:26
05/16/24 18:06
1
Perfluoroheptanoic acid (PFHpA)
3.0
1.4
0.36
ng/L
05/16/24 11:26
05/16/24 18:06
1
Perfluorooctanoic acid (PFOA)
5.0
1.4
0.36
ng/L
05/16/24 11:26
05/16/24 18:06
1
Perfluoronenanoic acid (PFNA)
<0.071
1.4
0.071
ng/L
05/16/24 11:26
05/16/24 18:06
1
Perfluorodecanoic acid (PFDA)
<0.071
1.4
0.071
ng/L
05/16/24 11:26
05/16/24 18:06
1
Perfluoroundecanoic acid (PFUnA)
<0.36
1.4
0.36
ng/L
05/16/24 11:26
05/16/24 18:06
1
Perfluorododecanoic acid (PFDoA)
<0.36
1.4
0.36
ng/L
05/16/24 11:26
05/16/24 18:06
1
Perfluorotridecanoic acid (PFTrDA)
<0.36
1.4
0.36
ng/L
05/16/24 11:26
05/16/24 18:06
1
Perfluorotetradecanoic acid (PFTA)
<0.36
1.4
0.36
ng/L
05/16/24 11:26
05/16/24 18:06
1
Perfluorobutanesulfonic acid
1.5
1.4
0.36
ng/L
05/16/24 11:26
05/16/24 18:06
1
(PFBS)
Perfluoropentanesulfonic acid
<0.071
1.4
0.071
ng/L
05/16/24 11:26
05/16/24 18:06
1
(PFPeS)
Perfluorohexanesulfonic acid (PFHxS)
<0.36
1.4
0.36
ng/L
05/16/24 11:26
05/16/24 18:06
1
Perfluoroheptanesulfonic acid
<0.071
1.4
0.071
ng/L
05/16/24 11:26
05/16/24 18:06
1
(PFHpS)
Perfluorooctanesulfonic acid (PFOS)
<0.36
1.4
0.36
ng/L
05/16/24 11:26
05/16/24 18:06
1
Perfluorononanesulfonic acid (PFNS)
<0.071
1.4
0.071
ng/L
05/16/24 11:26
05/16/24 18:06
1
Perfluorododecanesulfonic acid
<0.36 '- *1
1.4
0.36
ng/L
05/16/24 11:26
05/16/24 18:06
1
(PFDoS)
1H,1H,2H,2H-Perfluorohexane
<0.36
2.8
0.36
ng/L
05/16/24 11:26
05/16/24 18:06
1
sulfonic acid (4:2 FTS)
1H,1H,2H,2H-Perfluorooctanesulfonic
<0.36
2.8
0.36
ng/L
05/16/24 11:26
05/16/24 18:06
1
acid (6:2 FTS)
11-1,11-1,2H,21-1-Perfluorodecane
<0.36
2.8
0.36
ng/L
05/16/24 11:26
05/16/24 18:06
1
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.071
1.4
0.071
ng/L
05/16/24 11:26
05/16/24 18:06
1
N-methylperfluorooctane sulfonamide
<0.36
1.4
0.36
ng/L
05/16/24 11:26
05/16/24 18:06
1
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<0.36
1.4
0.36
ng/L
05/16/24 11:26
05/16/24 18:06
1
(N EtFOSA)
N-methylperfluorooctanesulfonamidoa
<0.36
1.4
0.36
ng/L
05/16/24 11:26
05/16/24 18:06
1
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<0.36
1.4
0.36
ng/L
05/16/24 11:26
05/16/24 18:06
1
etic acid (NEtFOSAA)
N-methylperfluorooctane
<1.4
7.1
1.4
ng/L
05/16/24 11:26
05/16/24 18:06
1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<1.4
7.1
1.4
ng/L
05/16/24 11:26
05/16/24 18:06
1
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide Dimer
<0.36
1.4
0.36
ng/L
05/16/24 11:26
05/16/24 18:06
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<0.36
1.4
0.36
ng/L
05/16/24 11:26
05/16/24 18:06
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<0.36
1.4
0.36
ng/L
05/16/24 11:26
05/16/24 18:06
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<0.36
1.4
0.36
ng/L
05/16/24 11:26
05/16/24 18:06
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<0.36
1.4
0.36
ng/L
05/16/24 11:26
05/16/24 18:06
1
e-1-sulfonic acid(9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<0.53
1.4
0.53
ng/L
05/16/24 11:26
05/16/24 18:06
1
e-1-sulfonic acid (11 CI-PF30UdS)
Eurofins Raleigh
Page 43 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Client Sample ID: MW-11 Lab Sample ID: 752-19362-17
Date Collected: 05/02/24 13:30 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Analyte
Result Qualifier
RL
MDL
Unit
Perfluoro (2-ethoxyethane) sulfonic
<0.36
1.4
0.36
ng/L
acid (PFEESA)
3-Perfluoropropylpropanoic acid (3:3
<0.71
2.8
0.71
ng/L
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<1.9
7.1
1.9
ng/L
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<1.9
7.1
1.9
ng/L
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.071
1.4
0.071
ng/L
Perfluoro-3-methoxypropanoic acid
<0.36
1.4
0.36
ng/L
(PFMPA)
Isotope Dilution
%Recovery Qualifier
Limits
13C4 PFBA
70.2
5 - 130
13C5 PFPeA
51.5
40 - 130
13C5 PFHxA
72.1
40 - 130
13C4 PFHpA
64.3
40 - 130
13C8 PFOA
83.2
40 - 130
13C9 PFNA
78.1
40 - 130
13C6 PFDA
73.0
40 - 130
13C7 PFUnA
67.7
30 - 130
13C2 PFDoA
50.1
10 - 130
13C2 PFTeDA
43.3
10 - 130
13C3 PFBS
85.4
40 - 135
13C3 PFHxS
67.7
40 - 130
13C8 PFOS
65.7
40 - 130
13C8 FOSA
54.4
40 - 130
d3-NMeFOSAA
125
40 - 170
d5-NEtFOSAA
100
25 - 135
M2-4:2 FTS
292 `5+
40 - 200
M2-6:2 FTS
430 `5+
40 - 200
M2-8:2 FTS
159
40 - 300
13C3 HFPO-DA
57.0
40 - 130
d7-N-McFOSE-M
82.4
10 - 130
d9-N-EtFOSE-M
69.2
10 - 130
d5-NEtPFOSA
83.5
10 - 130
d3-NMePFOSA
69.6
10 - 130
D Prepared Analyzed Dil Fac
05/16/2411:26 05/16/2418:06 1
05/16/2411:26 05/16/2418:06 1 •
05/16/2411:26 05/16/2418:06
05/16/2411:26 05/16/2418:06
05/16/2411:26 05/16/2418:06
05/16/2411:26 05/16/2418:06
Prepared
Analyzed
0511612411:26
0511612418:06
0511612411:26
0511612418:06
0511612411:26
0511612418:06
0511612411:26
0511612418:06
0511612411:26
0511612418:06
0511612411:26
0511612418:06
0511612411:26
0511612418:06
0511612411:26
0511612418:06
0511612411:26
0511612418:06
0511612411:26
0511612418:06
0511612411:26
0511612418:06
0511612411:26
0511612418:06
0511612411:26
0511612418:06
0511612411:26
0511612418:06
0511612411:26
0511612418:06
0511612411:26
0511612418:06
0511612411:26
0511612418:06
0511612411:26
0511612418:06
0511612411:26
0511612418:06
0511612411:26
0511612418:06
0511612411:26
0511612418:06
0511612411:26
0511612418:06
0511612411:26
0511612418:06
0511612411:26
0511612418:06
Eurofins Raleigh
Page 44 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Client Sample ID: WSW-2
Date Collected: 05/01/24 17:00
Date Received: 05/03/24 09:50
F
Job ID: 752-19362-1
Lab Sample ID: 752-19362-20
Matrix: Water
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Analyte Result Qualifier RL
MDL
Unit
D Prepared
Analyzed
Perfluorobutanoic acid (PFBA)
<0.72
2.9
0.72
ng/L
05/14/24 13:53
05/16/24 00:11
Perfluoropentanoic acid (PFPeA)
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/16/24 00:11
Perfluorohexanoic acid (PFHxA)
0.18 J
1.4
0.072
ng/L
05/14/24 13:53
05/16/24 00:11
Perfluoroheptanoic acid (PFHpA)
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/16/24 00:11
Perfluorooctanoic acid (PFOA)
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/16/24 00:11
Perfluorononanoic acid (PFNA)
<0.072
1.4
0.072
ng/L
05/14/24 13:53
05/16/24 00:11
Perfluorodecanoic acid (PFDA)
<0.072 *+
1.4
0.072
ng/L
05/14/24 13:53
05/16/24 00:11
Perfluoroundecanoic acid (PFUnA)
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/16/24 00:11
Perfluorododecanoic acid (PFDoA)
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/16/24 00:11
Perfluorotridecanoic acid (PFTrDA)
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/16/24 00:11
Perfluorotetradecanoic acid (PFTA)
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/16/24 00:11
Perfluorobutanesulfonic acid (PFBS)
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/16/24 00:11
Perfluoropentanesulfonic acid
<0.072
1.4
0.072
ng/L
05/14/24 13:53
05/16/24 00:11
(PFPeS)
Perfluorohexanesulfonic acid (PFHxS)
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/16/24 00:11
Perfluoroheptanesulfonic acid
<0.072
1.4
0.072
ng/L
05/14/24 13:53
05/16/24 00:11
(PFHpS)
Perfluorooctanesulfonic acid (PFOS)
<0.36 *+
1.4
0.36
ng/L
05/14/24 13:53
05/16/24 00:11
Perfluorononanesulfonic acid (PFNS)
<0.072
1.4
0.072
ng/L
05/14/24 13:53
05/16/24 00:11
Perfluorododecanesulfonic acid
<0.36 *-
1.4
0.36
ng/L
05/14/24 13:53
05/16/24 00:11
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
<0.36
2.9
0.36
ng/L
05/14/24 13:53
05/16/24 00:11
sulfonic acid (4:2 FTS)
1H,1H,2H,2H-Perfluorooctanesulfonic
<0.36
2.9
0.36
ng/L
05/14/24 13:53
05/16/24 00:11
acid (6:2 FTS)
1 H,1 H,2H,2H-Perfluorodecane
<0.36
2.9
0.36
ng/L
05/14/24 13:53
05/16/24 00:11
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.072
1.4
0.072
ng/L
05/14/24 13:53
05/16/24 00:11
N-methylperfluorooctane sulfonamide
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/16/24 00:11
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/16/24 00:11
(NEtFOSA)
N-methylperfluorooctanesulfonamidoa
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/16/24 00:11
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/16/24 00:11
etic acid (NEtFOSAA)
N-methylperfluorooctane
<1.4
7.2
1.4
ng/L
05/14/24 13:53
05/16/24 00:11
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<1.4
7.2
1.4
ng/L
05/14/24 13:53
05/16/24 00:11
sulfonamidoethanol (NETOSE)
Hexafluoropropylene Oxide Dimer
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/16/24 00:11
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/16/24 00:11
(ADONA)
Perfluoro-4-methoxybutanoic acid
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/16/24 00:11
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/16/24 00:11
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/16/24 00:11
e-1-sulfonic acid(9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<0.54
1.4
0.54
ng/L
05/14/24 13:53
05/16/24 00:11
e-1-sulfonic acid (11CI-PF3OUdS)
Perfluoro (2-ethoxyethane) sulfonic
<0.36
1.4
0.36
ng/L
05/14/24 13:53
05/16/24 00:11
acid (PFEESA)
Eurofins Raleigh
Page 45 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Client Sample ID: WSW-2 Lab Sample ID: 752-19362-20
Date Collected: 05/01/24 17:00 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Analyte
Result Qualifier
RL
MDL Unit
D Prepared
Analyzed
3-Perfluoropropylpropanoic acid (3:3
<0.72
2.9
0.72 ng/L
05/14/24 13:53
05/16/24 00:11
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<1.9
7.2
1.9 ng/L
05/14/24 13:53
05/16/24 00:11
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<1.9
7.2
1.9 ng/L
05/14/24 13:53
05/16/24 00:11
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.072
1.4
0.072 ng/L
05/14/24 13:53
05/16/24 00:11
Perfluoro-3-methoxypropanoic acid
<0.36
1.4
0.36 ng/L
05/14/24 13:53
05/16/24 00:11
(PFMPA)
Isotope Dilution
%Recovery Qualifier
Limits
Prepared
Analyzed
13C4 PFBA
65.0
5 - 130
05114124 13:53
05116124 00:11
13C5 PFPeA
65.4
40 - 130
05114124 13:53
05116124 00:11
13C5 PFHxA
71.4
40 - 130
05114124 13:53
05116124 00:11
13C4 PFHpA
68.1
40 - 130
05114124 13:53
05116124 00:11
13C8 PFOA
69.5
40 - 130
05114124 13:53
05116124 00:11
13C9 PFNA
90.6
40 - 130
05114124 13:53
05116124 00:11
13C6 PFDA
63.4
40 - 130
05114124 13:53
05/16/24 00:11
13C7 PFUnA
60.0
30 - 130
05114124 13:53
05/16/24 00:11
13C2 PFDoA
50.7
10 - 130
05114124 13:53
05/16/24 00:11
13C2 PFTeDA
42.3
10 - 130
05114124 13:53
05116124 00:11
13C3 PFBS
73.5
40 - 135
05114124 13:53
05116124 00:11
13C3 PFHxS
66.8
40 - 130
05114124 13:53
05116124 00:11
13C8 PFOS
87.6
40 - 130
05114124 13:53
05116124 00:11
13C8 FOSA
72.7
40 - 130
05114124 13:53
05116124 00:11
d3-NMeFOSAA
84.9
40 - 170
05114124 13:53
05116124 00:11
d5-NEtFOSAA
79.2
25 - 135
05114124 13:53
05116124 00:11
M2-4:2 FTS
79.5
40 - 200
05114124 13:53
05116124 00:11
M2-6:2 FTS
77.2
40 - 200
05114124 13:53
05116124 00:11
M2-8:2 FTS
75.1
40 - 300
05114124 13:53
05116124 00:11
13C3 HFPO-DA
75.9
40 - 130
05114124 13:53
05116124 00:11
d7-N-McFOSE-M
94.1
10 - 130
05114124 13:53
05116124 00:11
d9-N-EtFOSE-M
89.5
10 - 130
05114124 13:53
05/16/24 00:11
d5-NEtPFOSA
87.9
10 - 130
05114124 13:53
05/16/24 00:11
d3-NMePFOSA
80.7
10 - 130
05114124 13:53
05/16/24 00:11
Eurofins Raleigh
Page 46 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Job ID: 752-19362-1
Client Sample ID: Field Blank Lab Sample ID: 752-19362-21
Date Collected: 05/02/24 12:30 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Analyte Result Qualifier RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Perfluorobutanoic acid (PFBA)
<0.73
2.9
0.73
ng/L
05/16/24 11:26
05/16/24 18:21
1
Perfluoropentanoic acid (PFPeA)
<0.36
1.5
0.36
ng/L
05/16/24 11:26
05/16/24 18:21
1
Perfluorohexanoic acid (PFHxA)
0.12 J
1.5
0.073
ng/L
05/16/24 11:26
05/16/24 18:21
1
Perfluoroheptanoic acid (PFHpA)
<0.36
1.5
0.36
ng/L
05/16/24 11:26
05/16/24 18:21
1
Perfluorooctanoic acid (PFOA)
<0.36
1.5
0.36
ng/L
05/16/24 11:26
05/16/24 18:21
1
Perfluorononanoic acid (PFNA)
<0.073
1.5
0.073
ng/L
05/16/24 11:26
05/16/24 18:21
1
Perfluorodecanoic acid (PFDA)
<0.073
1.5
0.073
ng/L
05/16/24 11:26
05/16/24 18:21
1
Perfluoroundecanoic acid (PFUnA)
<0.36
1.5
0.36
ng/L
05/16/24 11:26
05/16/24 18:21
1
Perfluorododecanoic acid (PFDoA)
<0.36
1.5
0.36
ng/L
05/16/24 11:26
05/16/24 18:21
1
Perfluorotridecanoic acid (PFTrDA)
<0.36
1.5
0.36
ng/L
05/16/24 11:26
05/16/24 18:21
1
Perfluorotetradecanoic acid (PFTA)
<0.36
1.5
0.36
ng/L
05/16/24 11:26
05/16/24 18:21
1
Perfluorooutanesulfonic acid (PFBS)
<0.36
1.5
0.36
ng/L
05/16/24 11:26
05/16/24 18:21
1
Perfluoropentanesulfonic acid
<0.073
1.5
0.073
ng/L
05/16/24 11:26
05/16/24 18:21
1
(PFPeS)
Perfluorohexanesulfonic acid (PFHxS)
<0.36
1.5
0.36
ng/L
05/16/24 11:26
05/16/24 18:21
1
Perfluoroheptanesulfonic acid
<0.073
1.5
0.073
ng/L
05/16/24 11:26
05/16/24 18:21
1
(PFHpS)
Perfluorooctanesulfonic acid (PFOS)
<0.36
1.5
0.36
ng/L
05/16/24 11:26
05/16/24 18:21
1
Perfluorononanesulfonic acid (PFNS)
<0.073
1.5
0.073
ng/L
05/16/24 11:26
05/16/24 18:21
1
Perfluorododecanesulfonic acid
<0.36 *- *1
1.5
0.36
ng/L
05/16/24 11:26
05/16/24 18:21
1
(PFDoS)
11-1,11-1,2H,21-1-Perfluorohexane
<0.36
2.9
0.36
ng/L
05/16/24 11:26
05/16/24 18:21
1
sulfonic acid (4:2 FTS)
1H,1H,2H,2H-Perfluorooctanesulfonic
<0.36
2.9
0.36
ng/L
05/16/24 11:26
05/16/24 18:21
1
acid (6:2 FTS)
11-1,11-1,2H,21-1-Perfluorodecane
<0.36
2.9
0.36
ng/L
05/16/24 11:26
05/16/24 18:21
1
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.073
1.5
0.073
ng/L
05/16/24 11:26
05/16/24 18:21
1
N-methylperfluorooctane sulfonamide
<0.36
1.5
0.36
ng/L
05/16/24 11:26
05/16/24 18:21
1
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<0.36
1.5
0.36
ng/L
05/16/24 11:26
05/16/24 18:21
1
(N EtFOSA)
N-methylperfluorooctanesulfonamidoa
<0.36
1.5
0.36
ng/L
05/16/24 11:26
05/16/24 18:21
1
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<0.36
1.5
0.36
ng/L
05/16/24 11:26
05/16/24 18:21
1
etic acid (NEtFOSAA)
N-methylperfluorooctane
<1.5
7.3
1.5
ng/L
05/16/24 11:26
05/16/24 18:21
1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<1.5
7.3
1.5
ng/L
05/16/24 11:26
05/16/24 18:21
1
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide Dimer
<0.36
1.5
0.36
ng/L
05/16/24 11:26
05/16/24 18:21
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<0.36
1.5
0.36
ng/L
05/16/24 11:26
05/16/24 18:21
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<0.36
1.5
0.36
ng/L
05/16/24 11:26
05/16/24 18:21
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<0.36
1.5
0.36
ng/L
05/16/24 11:26
05/16/24 18:21
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<0.36
1.5
0.36
ng/L
05/16/24 11:26
05/16/24 18:21
1
e-1-sulfonic acid(9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<0.55
1.5
0.55
ng/L
05/16/24 11:26
05/16/24 18:21
1
e-1-sulfonic acid (11Cl-PF30UdS)
Perfluoro (2-ethoxyethane) sulfonic
<0.36
1.5
0.36
ng/L
05/16/24 11:26
05/16/24 18:21
1
acid (PFEESA)
Eurofins Raleigh
Page 47 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Client Sample ID: Field Blank Lab Sample ID: 752-19362-21
Date Collected: 05/02/24 12:30 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Analyte
Result Qualifier
RL
MDL Unit
D Prepared
Analyzed
3-Perfluoropropylpropanoic acid (3:3
<0.73
2.9
0.73 ng/L
05/16/24 11:26
05/16/24 18:21
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<2.0
7.3
2.0 ng/L
05/16/24 11:26
05/16/24 18:21
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<2.0
7.3
2.0 ng/L
05/16/24 11:26
05/16/24 18:21
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.073
1.5
0.073 ng/L
05/16/24 11:26
05/16/24 18:21
Perfluoro-3-methoxypropanoic acid
<0.36
1.5
0.36 ng/L
05/16/24 11:26
05/16/24 18:21
(PFMPA)
Isotope Dilution
%Recovery Qualifier
Limits
Prepared
Analyzed
13C4 PFBA
73.1
5 - 130
05116124 11:26
05116124 18:21
13C5 PFPeA
64.8
40 - 130
05116124 11:26
05116124 18:21
13C5 PFHxA
74.6
40 - 130
05116124 11:26
05116124 18:21
13C4 PFHpA
66.0
40 - 130
05116124 11:26
05116124 18:21
13C8 PFOA
82.1
40 - 130
05116124 11:26
05116124 18:21
13C9 PFNA
80.7
40 - 130
05116124 11:26
05116124 18:21
13C6 PFDA
81.3
40 - 130
05/16/24 11:26
05116124 18:21
13C7 PFUnA
76.0
30 - 130
05/16/24 11:26
05116124 18:21
13C2 PFDoA
60.7
10 - 130
05/16/24 11:26
05116124 18:21
13C2 PFTeDA
46.1
10 - 130
05116124 11:26
05116124 18:21
13C3 PFBS
80.3
40 - 135
05116124 11:26
05116124 18:21
13C3 PFHxS
75.2
40 - 130
05116124 11:26
05116124 18:21
13C8 PFOS
91.3
40 - 130
05116124 11:26
05116124 18:21
13C8 FOSA
69.0
40 - 130
05116124 11:26
05116124 18:21
d3-NMeFOSAA
102
40 - 170
05116124 11:26
05116124 18:21
d5-NEtFOSAA
86.3
25 - 135
05116124 11:26
05116124 18:21
M2-4:2 FTS
79.0
40 - 200
05116124 11:26
05116124 18:21
M2-6:2 FTS
85.9
40 - 200
05116124 11:26
05116124 18:21
M2-8:2 FTS
85.1
40 - 300
05116124 11:26
05116124 18:21
13C3 HFPO-DA
70.6
40 - 130
05116124 11:26
05116124 18:21
d7-N-McFOSE-M
90.1
10 - 130
05116124 11:26
05116124 18:21
d9-N-EtFOSE-M
77.6
10 - 130
05/16/24 11:26
05116124 18:21
d5-NEtPFOSA
93.0
10 - 130
05/16/24 11:26
05116124 18:21
d3-NMePFOSA
80.6
10 - 130
05/16/24 11:26
05116124 18:21
Eurofins Raleigh
Page 48 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Job ID: 752-19362-1
Client Sample ID: MW-14 Lab Sample ID: 752-19362-23
Date Collected: 05/02/24 14:30 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Analyte Result Qualifier RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Perfluorobutanoic acid (PFBA)
3.5
3.1
0.78
ng/L
05/16/24 11:26
05/16/24 18:36
1
Perfluoropentanoic acid (PFPeA)
<0.39
1.6
0.39
ng/L
05/16/24 11:26
05/16/24 18:36
1
Perfluorohexanoic acid (PFHxA)
14
1.6
0.078
ng/L
05/16/24 11:26
05/16/24 18:36
1
Perfluoroheptanoic acid (PFHpA)
2.3 1
1.6
0.39
ng/L
05/16/24 11:26
05/16/24 18:36
1
Perfluorooctanoic acid (PFOA)
1.9
1.6
0.39
ng/L
05/16/24 11:26
05/16/24 18:36
1
Perfluorononanoic acid (PFNA)
<0.078
1.6
0.078
ng/L
05/16/24 11:26
05/16/24 18:36
1
Perfluorodecanoic acid (PFDA)
<0.078
1.6
0.078
ng/L
05/16/24 11:26
05/16/24 18:36
1
Perfluoroundecanoic acid (PFUnA)
<0.39
1.6
0.39
ng/L
05/16/24 11:26
05/16/24 18:36
1
Perfluorododecanoic acid (PFDoA)
<0.39
1.6
0.39
ng/L
05/16/24 11:26
05/16/24 18:36
1
Perfluorotridecanoic acid (PFTrDA)
<0.39
1.6
0.39
ng/L
05/16/24 11:26
05/16/24 18:36
1
Perfluorotetradecanoic acid (PFTA)
<0.39
1.6
0.39
ng/L
05/16/24 11:26
05/16/24 18:36
1
Perfluorobutanesulfonic acid
0.61 J
1.6
0.39
ng/L
05/16/24 11:26
05/16/24 18:36
1
(PFBS)
Perfluoropentanesulfonic acid
<0.078
1.6
0.078
ng/L
05/16/24 11:26
05/16/24 18:36
1
(PFPeS)
Perfluorohexanesulfonic acid
0.94 J
1.6
0.39
ng/L
05/16/24 11:26
05/16/24 18:36
1
(PFHxS)
Perfluoroheptanesulfonic acid
<0.078
1.6
0.078
ng/L
05/16/24 11:26
05/16/24 18:36
1
(PFHpS)
Perfluorooctanesulfonic acid (PFOS)
<0.39
1.6
0.39
ng/L
05/16/24 11:26
05/16/24 18:36
1
Perfluorononanesulfonic acid (PFNS)
<0.078
1.6
0.078
ng/L
05/16/24 11:26
05/16/24 18:36
1
Perfluorododecanesulfonic acid
<0.39 *- *1
1.6
0.39
ng/L
05/16/24 11:26
05/16/24 18:36
1
(PFDoS)
11-1,11-1,21-1,21-1-Perfluorohexane
<0.39
3.1
0.39
ng/L
05/16/24 11:26
05/16/24 18:36
1
sulfonic acid (4:2 FTS)
1H,1H,2H,2H-Perfluorooctanesulfonic
<0.39
3.1
0.39
ng/L
05/16/24 11:26
05/16/24 18:36
1
acid (6:2 FTS)
11-1,11-1,2H,21-1-Perfluorodecane
<0.39
3.1
0.39
ng/L
05/16/24 11:26
05/16/24 18:36
1
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.078
1.6
0.078
ng/L
05/16/24 11:26
05/16/24 18:36
1
N-methylperfluorooctane sulfonamide
<0.39
1.6
0.39
ng/L
05/16/24 11:26
05/16/24 18:36
1
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<0.39
1.6
0.39
ng/L
05/16/24 11:26
05/16/24 18:36
1
(NEtFOSA)
N-methylperfluorooctanesulfonamidoa
<0.39
1.6
0.39
ng/L
05/16/24 11:26
05/16/24 18:36
1
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<0.39
1.6
0.39
ng/L
05/16/24 11:26
05/16/24 18:36
1
etic acid (NEtFOSAA)
N-methylperfluorooctane
<1.6
7.8
1.6
ng/L
05/16/24 11:26
05/16/24 18:36
1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<1.6
7.8
1.6
ng/L
05/16/24 11:26
05/16/24 18:36
1
sulfonamidoethanol (NETOSE)
Hexafluoropropylene Oxide Dimer
<0.39
1.6
0.39
ng/L
05/16/24 11:26
05/16/24 18:36
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<0.39
1.6
0.39
ng/L
05/16/24 11:26
05/16/24 18:36
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<0.39
1.6
0.39
ng/L
05/16/24 11:26
05/16/24 18:36
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<0.39
1.6
0.39
ng/L
05/16/24 11:26
05/16/24 18:36
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<0.39
1.6
0.39
ng/L
05/16/24 11:26
05/16/24 18:36
1
e-1-sulfonic acid (9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<0.58
1.6
0.58
ng/L
05/16/24 11:26
05/16/24 18:36
1
e-1-sulfonic acid (11Cl-PF30UdS)
Eurofins Raleigh
Page 49 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
Client Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Client Sample ID: MW-14 Lab Sample ID: 752-19362-23
Date Collected: 05/02/24 14:30 Matrix: Water
Date Received: 05/03/24 09:50
Method: EPA 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Analyte
Result Qualifier
RL
MDL
Unit
Perfluoro (2-ethoxyethane) sulfonic
<0.39
1.6
0.39
ng/L
acid (PFEESA)
3-Perfluoropropylpropanoic acid (3:3
<0.78
3.1
0.78
ng/L
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<2.1
7.8
2.1
ng/L
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<2.1
7.8
2.1
ng/L
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.078
1.6
0.078
ng/L
Perfluoro-3-methoxypropanoic acid
<0.39
1.6
0.39
ng/L
(PFMPA)
Isotope Dilution
%Recovery Qualifier
Limits
13C4 PFBA
73.3
5 - 130
13C5 PFPeA
61.4
40 - 130
13C5 PFHxA
75.3
40 - 130
13C4 PFHpA
65.4
40 - 130
13C8 PFOA
88.4
40 - 130
13C9 PFNA
87.1
40 - 130
13C6 PFDA
88.1
40 - 130
13C7 PFUnA
85.2
30 - 130
13C2 PFDoA
64.1
10 - 130
13C2 PFTeDA
49.3
10 - 130
13C3 PFBS
87.8
40 - 135
13C3 PFHxS
78.8
40 - 130
13C8 PFOS
90.7
40 - 130
13C8 FOSA
66.8
40 - 130
d3-NMeFOSAA
110
40 - 170
d5-NEtFOSAA
94.6
25 - 135
M2-4:2 FTS
159
40 - 200
M2-6:2 FTS
242 `5+
40 - 200
M2-8:2 FTS
93.1
40 - 300
13C3 HFPO-DA
68.8
40 - 130
d7-N-McFOSE-M
91.5
10 - 130
d9-N-EtFOSE-M
79.8
10 - 130
d5-NEtPFOSA
97.9
10 - 130
d3-NMePFOSA
81.9
10 - 130
D Prepared Analyzed Dil Fac
05/16/2411:26 05/16/2418:36 1
05/16/2411:26 05/16/2418:36 1
05/16/2411:26 05/16/2418:36
05/16/2411:26 05/16/2418:36
05/16/2411:26 05/16/2418:36
05/16/2411:26 05/16/2418:36
Prepared
Analyzed
0511612411:26
0511612418:36
0511612411:26
0511612418:36
0511612411:26
0511612418:36
0511612411:26
0511612418:36
0511612411:26
0511612418:36
0511612411:26
0511612418:36
0511612411:26
0511612418:36
0511612411:26
0511612418:36
0511612411:26
0511612418:36
0511612411:26
0511612418:36
0511612411:26
0511612418:36
0511612411:26
0511612418:36
0511612411:26
0511612418.36
0511612411:26
0511612418:36
0511612411:26
0511612418:36
0511612411:26
0511612418:36
0511612411:26
0511612418:36
0511612411:26
0511612418:36
0511612411:26
0511612418:36
0511612411:26
0511612418:36
0511612411:26
0511612418:36
0511612411:26
0511612418:36
0511612411:26
0511612418:36
0511612411:26
0511612418:36
Eurofins Raleigh
Page 50 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Isotope Dilution Summary
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Matrix: Water Prep Tvr)e: Total/NA
Lab Sample ID
752-19362-1
752-19362-1
752-19362-2
752-19362-2
752-19362-3
752-19362-3
752-19362-4
752-19362-5
752-19362-6
752-19362-7
752-19362-8
752-19362-8
752-19362-9
752-19362-10
752-19362-10
752-19362-11
752-19362-12
752-19362-13
752-19362-14
752-19362-15
752-19362-16
752-19362-17
752-19362-20
752-19362-21
752-19362-23
LCS 680-837934/2-A
LCS 680-838358/2-A
LCS 680-838897/2-A
LCSD 680-837934/3-A
LCSD 680-838358/3-A
LCSD 680-838897/3-A
MB 680-837934/1-A
MB 680-838358/1-A
MB 680-838897/1-A
Lab Sample ID
752-19362-1
752-19362-1
752-19362-2
752-19362-2
752-19362-3
752-19362-3
752-19362-4
752-19362-5
752-19362-6
752-19362-7
752-19362-8
752-19362-8
Client Sample ID
MW-7
MW-7
MW-6
MW-6
MW-12S
MW-12S
MW-13
MW-23
MW-19
MW-22
MW-17
MW-17
MW-3R
SW-4
SW-4
MW-20
MW-21
SW-1
MW-9
SW-2
MW-1
MW-11
WSW-2
Field Blank
MW-14
Lab Control Sample
Lab Control Sample
Lab Control Sample
Lab Control Sample Dup
Lab Control Sample Dup
Lab Control Sample Dup
Method Blank
Method Blank
Method Blank
Client Sample ID
MW-7
MW-7
MW-6
MW-6
MW-12S
MW-12S
MW-13
MW-23
MW-19
MW-22
MW-17
MW-17
Percent Isotope Dilution Recovery (Acceptance Limits)
PFBA
PFPeA
13C5PHA
C4PFHA
C8PFOA
C9PFNA
C6PFDA
13C7PUA
(5-130)
(40-130)
(40-130)
(40-130)
(40-130)
(40-130)
(40-130)
(30-130)
70.4
62.4
77.9
79.2
77.9
102
64.0
59.2
68.3
65.9
73.0
69.3
73.5
94.8
64.5
59.6
64.1
67.2
70.9
68.2
72.9
89.3
59.1
53.2
64.1
65.6
71.4
70.7
71.2
91.3
61.5
57.2
65.3
67.7
73.2
70.0
71.6
95.9
63.8
59.8
65.9
68.2
73.7
70.8
74.9
94.5
63.4
57.6
68.0
69.9
77.5
74.7
77.4
99.6
63.9
57.0
66.9
67.0
72.6
70.2
75.0
96.3
60.8
52.9
69.1
68.6
75.4
72.5
72.9
99.4
64.9
58.1
71.7
72.5
78.4
75.0
80.5
102
67.9
60.5
72.2
73.8
80.5
76.0
80.8
105
71.2
67.3
76.3
74.8
80.4
79.8
86.8
109
73.9
70.2
71.1
70.9
76.7
74.3
82.1
102
67.6
62.2
70.2
67.1
75.7
71.2
81.0
106
70.1
70.5
71.6
70.2
77.2
74.0
82.9
103
69.2
65.4
64.9
53.8
69.7
59.0
73.5
70.0
65.0
58.7
70.2
51.5
72.1
64.3
83.2
78.1
73.0
67.7
65.0
65.4
71.4
68.1
69.5
90.6
63.4
60.0
73.1
64.8
74.6
66.0
82.1
80.7
81.3
76.0
73.3
61.4
75.3
65.4
88.4
87.1
88.1
85.2
66.1
70.7
73.7
71.4
72.7
97.4
67.9
65.4
72.0
68.4
78.3
69.2
81.5
93.9
81.4
80.5
59.1
62.9
67.5
63.8
64.6
86.0
62.3
59.2
69.3
72.0
76.7
74.4
76.4
101
71.0
67.5
71.8
65.7
77.7
67.2
86.9
90.7
79.1
80.5
56.3
59.8
64.8
60.3
61.6
82.6
56.9
53.9
68.9
69.9
76.1
73.5
73.2
99.1
67.5
63.1
75.7
70.2
81.1
70.7
91.6
97.4
85.3
88.1
59.8
62.3
66.5
63.4
67.0
87.0
61.5
56.8
Percent Isotope Dilution Recovery
(Acceptance Limits)
PFDoA
PFTDA
C3PFBS
C3PFHS
C8PFOS
PFOSA
d3NMFOS
d5NEFOS
(10-130)
(10-130)
(40-135)
(40-130)
(40-130)
(40-130)
(40-170)
(25-135)
48.0
40.7
78.9
74.7
89.3
64.1
91.6
89.2
81.2
51.9
52.1
79.5
73.4
88.9
69.7
85.1
83.7
54.6
44.7
43.0
73.1
70.3
84.5
71.6
80.1
76.6
89.4
47.8
43.7
71.1
69.3
82.5
64.1
78.2
77.9
51.4
45.2
77.1
71.9
88.9
70.0
83.0
81.6
50.4
42.4
77.5
72.6
88.4
67.6
80.5
78.0
47.7
47.5
79.8
74.4
88.5
66.2
83.0
80.2
42.4
39.1
80.4
75.3
81.9
59.0
75.9
69.6
30.0 '5-
Eurofins Raleigh
Page 51 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Isotope Dilution Summary C
Client: Smith Gardner Inc Job ID: 752-19362-1
Project/Site: Surry C&D/MSW (Permit 8602)
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Matrix: Water Prep Type: Total/NA
Lab Sample ID
Client Sample ID
752-19362-9
MW-3R
752-19362-10
SW-4
752-19362-10
SW-4
752-19362-11
MW-20
752-19362-12
MW-21
752-19362-13
SW-1
752-19362-14
MW-9
752-19362-15
SW-2
752-19362-16
MW-1
752-19362-17
MW-11
752-19362-20
WSW-2
752-19362-21
Field Blank
752-19362-23
MW-14
LCS 680-837934/2-A
Lab Control Sample
LCS 680-838358/2-A
Lab Control Sample
LCS 680-838897/2-A
Lab Control Sample
LCSD 680-837934/3-A
Lab Control Sample
Dup
LCSD 680-838358/3-A
Lab Control Sample
Dup
LCSD 680-838897/3-A
Lab Control Sample
Dup
MB 680-837934/1-A
Method Blank
MB 680-838358/1-A
Method Blank
MB 680-838897/1-A
Method Blank
Lab Sample ID
Client Sample ID
752-19362-1
MW-7
752-19362-1
MW-7
752-19362-2
MW-6
752-19362-2
MW-6
752-19362-3
MW-12S
752-19362-3
MW-12S
752-19362-4
MW-13
752-19362-5
MW-23
752-19362-6
MW-19
752-19362-7
MW-22
752-19362-8
MW-17
752-19362-8
MW-17
752-19362-9
MW-3R
752-19362-10
SW4
752-19362-10
SW4
752-19362-11
MW-20
752-19362-12
MW-21
752-19362-13
SW-1
752-19362-14
MW-9
752-19362-15
SW-2
752-19362-16
MW-1
752-19362-17
MW-11
752-19362-20
WSW-2
752-19362-21
Field Blank
752-19362-23
MW-14
PFDoA
(10-130)
PFTDA
(10-130)
Percent Isotope Dilution Recovery (Acceptance Limits)
C3PFBS C3PFHS C8PFOS PFOSA d3NMFOS
(40-135) (40-130) (40-130) (40-130) (40-170)
d5NEFOS
(25-135)
51.1
49.7
79.8
73.9
92.1
67.9
82.8
78.8
50.3
47.5
83.7
79.8
94.7
72.9
84.9
80.1
57.4
59.3
56.3
88.3
79.6
99.9
78.5
92.8
92.7
61.2
60.6
86.0
81.9
106
83.2
99.9
102
52.9
49.6
82.4
77.0
94.1
77.7
90.3
86.4
58.3
59.5
87.9
79.7
95.5
70.2
98.2
95.2
56.4
55.9
83.1
78.1
93.3
76.6
92.1
87.8
43.2
27.6
77.8
63.6
61.8
51.0
93.7
79.7
50.1
43.3
85.4
67.7
65.7
54.4
125
100
50.7
42.3
73.5
66.8
87.6
72.7
84.9
79.2
60.7
46.1
80.3
75.2
91.3
69.0
102
86.3
64.1
49.3
87.8
78.8
90.7
66.8
110
94.6
55.0
46.2
75.6
72.6
90.0
70.6
94.3
89.3
63.4
41.7
81.2
77.0
91.7
71.1
104
89.0
49.8
39.5
68.7
65.3
81.9
63.5
84.1
75.9
57.2
43.9
82.6
76.1
94.4
75.1
93.9
89.1
63.3
47.7
77.51
75.7
94.2
71.8
101
89.2
46.5
39.7
67.9
63.1
80.7
60.8
79.4
74.6
53.5
44.8
78.9
73.9
91.5
72.2
91.1
86.3
70.2
55.0
84.5
82.8
101
75.4
110
97.3
48.1
39.8
70.7
66.6
82.0
64.3
84.5
78.2
Percent Isotope Dilution Recovery (Acceptance Limits)
M242FTS
M262FTS M282FTS
HFPODA
NMFM
NEFM
d5NPFSA
d3NMFSA
(40-200)
(40-200)
(40-300)
(40-130)
(10-130)
(10-130)
(10-130)
(10.130)
176
132
85.7
70.9
77.1
72.9
80.6
69.7
156
90.5
73.7
68.0
89.3
90.2
98.5
83.1
97.3
76.2
68.8
68.0
80.9
81.2
91.8
80.5
116
85.8
67.6
70.5
80.4
77.1
89.6
76.1
88.2
80.7
77.1
72.6
94.3
97.9
101
80.8
76.2
78.8
74.9
76.0
90.2
89.3
96.4
78.3
160
96.3
75.1
74.6
85.1
83.4
94.8
78.9
140
82.2
68.3
72.3
71.4
67.8
75.2
63.6
109
81.9
75.5
76.0
90.3
89.1
98.1
80.3
89.1
79.2
75.0
81.3
84.4
81.2
82.4
73.2
92.6
79.7
81.3
82.3
101
97.5
103
85.3
227 *5+
91.5
81.0
83.5
106
103
111
94.7
79.0
79.7
76.7
80.0
92.6
89.0
92.3
79.2
260 *5+
127
93.7
70.7
102
107
104
85.2
95.8
86.6
78.4
80.1
97.9
96.7
102
86.8
227 *5+
361 *5+
85.3
56.0
72.4
61.0
73.1
63.9
292 *5+
430 *5+
159
57.0
82.4
69.2
83.5
69.6
79.5
77.2
75.1
75.9
94.1
89.5
87.9
80.7
79.0
85.9
85.1
70.6
90.1
77.6
93.0
80.6
159
242 *5+
93.1
68.8
91.5
79.8
97.9
81.9
Page 52 of 92
Eurofins Raleigh
5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Isotope Dilution Summary
Client: Smith Gardner Inc Job ID: 752-19362-1
Project/Site: Surry C&D/MSW (Permit 8602)
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Matrix: Water Prep Type: Total/NA
Lab Sample ID
Client Sample ID
M242FTS
(40-200)
M262FTS
(40-200)
Percent Isotope Dilution Recovery (Acceptance Limits)
M282FTS HFPODA NMFM NEFM d5NPFSA
(40-300) (40-130) (10-130) (10-130) (10-130)
LCS 680-83793412-A
Lab Control Sample
80.6
83.1
82.0
79.7
94.8
94.8
93.2
LCS 680-83835812-A
Lab Control Sample
82.9
88.4
79.7
74.0
91.0
82.4
94.1
LCS 680-838897/2-A
Lab Control Sample
78.0
76.4
73.2
73.1
83.0
85.6
93.5
LCSD 680-837934/3-A
Lab Control Sample Dup
88.7
88.0
91.5
81.5
101
102
95.1
LCSD 680-838358/3-A
Lab Control Sample Dup
78.4
80.8
76.7
72.0
91.9
83.7
97.4
LCSD 680-838897/3-A
Lab Control Sample Dup
75.0
71.8
66.0
69.6
81.9
83.0
89.9
MB 680-837934/1-A
Method Blank
86.5
87.0
82.9
80.1
99.4
97.5
101
MB 680-838358/1-A
Method Blank
84.5
89.2
86.2
77.9
93.6
86.8
102
MB 680-838897/1-A
Method Blank
80.6
77.6
73.7
73.5
83.8
85.5
96.9
Surrogate Legend
PFBA = 13C4 PFBA
PFPeA= 13C5 PFPeA
13C5PHA = 13C5 PFHxA
C4PFHA = 13C4 PFHpA
C8PFOA = 13C8 PFOA
C9PFNA = 13C9 PFNA
C6PFDA = 13C6 PFDA
13C7PUA = 13C7 PFUnA
PFDoA = 13C2 PFDoA
PFTDA= 13C2 PFTeDA
C3PFBS = 13C3 PFBS
C3PFHS = 13C3 PFHxS
C8PFOS = 13C8 PFOS
PFOSA = 13C8 FOSA
d3NMFOS = d3-NMeFOSAA
d5NEFOS = d5-NEtFOSAA
M242FTS = M2-4:2 FTS
M262FTS = M2-6:2 FTS
M282FTS = M2-8:2 FTS
HFPODA= 13C3 HFPO-DA
NMFM = d7-N-McFOSE-M
NEFM = d9-N-EtFOSE-M
d5NPFSA = d5-NEtPFOSA
d3NMFSA = d3-NMePFOSA
d3NMFSA
(10-130)
79.0
80.0
77.2
80.3
79.9
72.1
83.6
86.8
77.1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Matrix: Water Prep TVDe: Total/NA
Lab Sample ID
LLCS 680-837934/4-A
LLCS 680-838358/4-A
LLCS 680-838897/4-A
Lab Sample ID
LLCS 680-837934/4-A
LLCS 680-838358/4-A
LLCS 680-838897/4-A
Client Sample ID
Lab Control Sample
Lab Control Sample
Lab Control Sample
Client Sample ID
Lab Control Sample
Lab Control Sample
Lab Control Sample
Percent Isotope Dilution Recovery (Acceptance Limits)
PFBA
PFPeA
13C5PHA
C4PFHA
C8PFOA
C9PFNA
C6PFDA
13C7PUA
(25-130)
(40-130)
(40-130)
(40-130)
(40-130)
(40-130)
(40-130)
(30-130)
66.6
70.1
74.1
71.3
73.2
94.7
67.0
63.2
73.1
67.5
77.2
68.7
89.6
93.9
83.8
83.8
65.3
66.8
71.3
69.0
71.1
93.9
66.4
61.0
Percent Isotope Dilution Recovery
(Acceptance Limits)
PFDoA
PFTDA
C3PFBS
C3PFHS
C8PFOS
PFOSA
d3NMFOS
d5NEFOS
(10-130)
(10-130)
(40-135)
(40-130)
(40-130)
(40-130)
(40-170)
(25-135)
54.1
41.9
73.6
67.2
85.9
71.4
91.7
84.9
66.5
51.8
86.0
78.6
95.5
71.1
102
89.8
49.0
36.6
73.6
68.6
88.9
68.6
95.0
84.6
Page 53 of 92
Eurofins Raleigh
5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Isotope Dilution Summary
Client: Smith Gardner Inc Job ID: 752-19362-1
Project/Site: Surry C&D/MSW (Permit 8602)
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
Matrix: Water Prep Type: Total/NA
Lab Sample ID Client Sample ID
LLCS 680-837934/4-A Lab Control Sample
LLCS 680-838358/4-A Lab Control Sample
LLCS 680-838897/4-A Lab Control Sample
Surrogate Legend
PFBA = 13C4 PFBA
PFPeA= 13C5 PFPeA
13C5PHA = 13C5 PFHxA
C4PFHA = 13C4 PFHpA
C8PFOA = 13C8 PFOA
C9PFNA = 13C9 PFNA
C6PFDA = 13C6 PFDA
13C7PUA = 13C7 PFUnA
PFDoA = 13C2 PFDoA
PFTDA= 13C2 PFTeDA
C3PFBS = 13C3 PFBS
C3PFHS = 13C3 PFHxS
C8PFOS = 13C8 PFOS
PFOSA = 13C8 FOSA
d3NMFOS = d3-NMeFOSAA
d5NEFOS = d5-NEtFOSAA
M242FTS = M2-4:2 FTS
M262FTS = M2-6:2 FTS
M282FTS = M2-8:2 FTS
HFPODA= 13C3 HFPO-DA
NMFM = d7-N-McFOSE-M
NEFM = d9-N-EtFOSE-M
d5NPFSA = d5-NEtPFOSA
d3NMFSA = d3-NMePFOSA
Percent Isotope Dilution Recovery (Acceptance Limits)
M242FTS
M262FTS
M282FTS
HFPODA
NMFM
NEFM
d5NPFSA
d3NMFSA
(40-200)
(40-200)
(40-300)
(40-130)
(10-130)
(10-130)
(10-130)
(10-130)
86.0
82.8
83.2
77.4
94.6
94.2
89.3
79.3
83.5
84.2
81.1
72.0
91.5
85.1
97.3
80.4
89.0
87.7
82.7
79.1
89.7
89.1
92.9
77.8
Page 54 of 92
Eurofins Raleigh
5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS
C
Job ID: 752-19362-1
FLab Sample ID: MB 680-837934/1-A
Client Sample ID: Method
Blank
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 838185
Prep Batch:
837934
MB
MB
Analyte
Result
Qualifier RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Perfluorobutanoic acid (PFBA)
<1.0
4.0
1.0
ng/L
05/14/24 13:53
05/15/24 17:01
1
Perfluoropentanoic acid (PFPeA)
<0.50
2.0
0.50
ng/L
05/14/24 13:53
05/15/24 17:01
1
Perfluorohexanoic acid (PFHxA)
<0.10
2.0
0.10
ng/L
05/14/24 13:53
05/15/24 17:01
1
Perfluoroheptanoic acid (PFHpA)
<0.50
2.0
0.50
ng/L
05/14/24 13:53
05/15/24 17:01
1
Perfluorooctanoic acid (PFOA)
<0.50
2.0
0.50
ng/L
05/14/24 13:53
05/15/24 17:01
1
•
Perfluorononanoic acid (PFNA)
<0.10
2.0
0.10
ng/L
05/14/24 13:53
05/15/24 17:01
1
Perfluorodecanoic acid (PFDA)
<0.10
2.0
0.10
ng/L
05/14/24 13:53
05/15/24 17:01
1
Perfluoroundecanoic acid (PFUnA)
<0.50
2.0
0.50
ng/L
05/14/24 13:53
05/15/24 17:01
1
Perfluorododecanoic acid (PFDoA)
<0.50
2.0
0.50
ng/L
05/14/24 13:53
05/15/24 17:01
1
Perfluorotridecanoic acid (PFTrDA)
<0.50
2.0
0.50
ng/L
05/14/24 13:53
05/15/24 17:01
1
Perfluorotetradecanoic acid (PFTA)
<0.50
2.0
0.50
ng/L
05/14/24 13:53
05/15/24 17:01
1
Perfluorobutanesulfonic acid (PFBS)
<0.50
2.0
0.50
ng/L
05/14/24 13:53
05/15/24 17:01
1
Perfluoropentanesulfonic acid
<0.10
2.0
0.10
ng/L
05/14/24 13:53
05/15/24 17:01
1
(PFPeS)
Perfluorohexanesulfonic acid (PFHxS)
<0.50
2.0
0.50
ng/L
05/14/24 13:53
05/15/24 17:01
1
Perfluoroheptanesulfonic acid
<0.10
2.0
0.10
ng/L
05/14/24 13:53
05/15/24 17:01
1
(PFHpS)
Perfluorooctanesulfonic acid (PFOS)
6.14
2.0
0.50
ng/L
05/14/24 13:53
05/15/24 17:01
1
Perfluorononanesulfonic acid (PFNS)
<0.10
2.0
0.10
ng/L
05/14/24 13:53
05/15/24 17:01
1
Perfluorododecanesulfonic acid
<0.50
2.0
0.50
ng/L
05/14/24 13:53
05/15/24 17:01
1
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
<0.50
4.0
0.50
ng/L
05/14/24 13:53
05/15/24 17:01
1
sulfonic acid (4:2 FTS)
1H,1H,2H,2H-Perfluorooctanesulfonic
<0.50
4.0
0.50
ng/L
05/14/24 13:53
05/15/24 17:01
1
acid (6:2 FTS)
1H,1H,2H,2H-Perfluorodecane
<0.50
4.0
0.50
ng/L
05/14/24 13:53
05/15/24 17:01
1
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.10
2.0
0.10
ng/L
05/14/24 13:53
05/15/24 17:01
1
N-methylperfluorooctane sulfonamide
<0.50
2.0
0.50
ng/L
05/14/24 13:53
05/15/24 17:01
1
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<0.50
2.0
0.50
ng/L
05/14/24 13:53
05/15/24 17:01
1
(NEtFOSA)
N-methylperfluorooctanesulfonamidoa
<0.50
2.0
0.50
ng/L
05/14/24 13:53
05/15/24 17:01
1
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<0.50
2.0
0.50
ng/L
05/14/24 13:53
05/15/24 17:01
1
etic acid (NEtFOSAA)
N-methylperfluorooctane
<2.0
10
2.0
ng/L
05/14/24 13:53
05/15/24 17:01
1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<2.0
10
2.0
ng/L
05/14/24 13:53
05/15/24 17:01
1
sulfonamidoethanol (NETOSE)
Hexafluoropropylene Oxide Dimer
<0.50
2.0
0.50
ng/L
05/14/24 13:53
05/15/24 17:01
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<0.50
2.0
0.50
ng/L
05/14/24 13:53
05/15/24 17:01
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<0.50
2.0
0.50
ng/L
05/14/24 13:53
05/15/24 17:01
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<0.50
2.0
0.50
ng/L
05/14/24 13:53
05/15/24 17:01
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<0.50
2.0
0.50
ng/L
05/14/24 13:53
05/15/24 17:01
1
e-1-sulfonic acid(9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<0.75
2.0
0.75
ng/L
05/14/24 13:53
05/15/24 17:01
1
e-1-sulfonic acid (110-PF30WS)
Eurofins Raleigh
Page 55 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
QC Sample Results
Client: Smith Gardner Inc
Job ID: 752-19362-1
Project/Site: Surry C&D/MSW (Permit 8602)
Method: 1633 - Per- and Polyfluoroalkyl Substances
by LC/MS/MS (Continued)
Lab Sample ID: MB 680-837934/1-A
Client Sample ID: Method Blank
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 838185
Prep Batch: 837934
MB
MB
Analyte
Result
Qualifier
RL
MDL Unit
D Prepared
Analyzed Dil Fac
Perfluoro (2-ethoxyethane) sulfonic
<0.50
2.0
0.50 ng/L
05/14/24 13:53
05/15/24 17:01 1
acid (PFEESA)
3-Perfluoropropylpropanoic acid (3:3
<1.0
4.0
1.0 ng/L
05/14/24 13:53
05/15/24 17:01 1
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<2.7
10
2.7 ng/L
05/14/24 13:53
05/15/24 17:01 1
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<2.7
10
2.7 ng/L
05/14/24 13:53
05/15/24 17:01 1
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.10
2.0
0.10 ng/L
05/14/24 13:53
05/15/24 17:01 1
Perfluoro-3-methoxypropanoic acid
<0.50
2.0
0.50 ng/L
05/14/24 13:53
05/15/24 17:01 1
(PFMPA)
MB
MB
Isotope Dilution %Recovery
Qualifier
Limits
Prepared
Analyzed Dil Fac
13C4 PFBA
68.9
5 - 130
05114124 13:53
05115124 17:01 1
13C5 PFPeA
69.9
40 - 130
05114124 13:53
05115124 17:01 1
13C5 PFHxA
76.1
40 - 130
05114124 13:53
05115124 17:01 1
13C4 PFHpA
73.5
40 - 130
05114124 13:53
05115124 17:01 1
13C8 PFOA
73.2
40 - 130
05114124 13:53
05115124 17:01 1
13C9 PFNA
99.1
40 - 130
05114124 13:53
05/15/24 17:01 1
13C6 PFDA
67.5
40 - 130
05114124 13:53
05/15/24 17:01 1
13C7 PFUnA
63.1
30 - 130
05114124 13:53
05/15/24 17:01 1
13C2 PFDoA
53.5
10 - 130
05114124 13:53
05/15/24 17:01 1
13C2 PFTeDA
44.8
10 - 130
05114124 13:53
05115124 17:01 1
13C3 PFBS
78.9
40 - 135
05114124 13:53
05115124 17:01 1
13C3 PFHxS
73.9
40 - 130
05114124 13:53
05115124 17:01 1
13C8 PFOS
91.5
40 - 130
05114124 13:53
05115124 17:01 1
13C8 FOSA
72.2
40 - 130
05114124 13:53
05115124 17:01 1
d3-NMeFOSAA
91.1
40 - 170
05114124 13:53
05115124 17:01 1
d5-NEtFOSAA
86.3
25 - 135
05114124 13:53
05115124 17:01 1
M2-4:2 FTS
86.5
40 - 200
05114124 13:53
05115124 17:01 1
M2-6:2 FTS
87.0
40 - 200
05114124 13:53
05115124 17:01 1
M2-8:2 FTS
82.9
40 - 300
05/14/24 13:53
05/15/24 17:01 1
13C3 HFPO-DA
80.1
40 - 130
05/14/24 13:53
05/15/24 17:01 1
d7-N-McFOSE-M
99.4
10 - 130
05/14/24 13:53
05/15/24 17:01 1
d9-N-EtFOSE-M
97.5
10 - 130
05114124 13:53
05/15/24 17:01 1
d5-NEtPFOSA
101
10 - 130
05114124 13:53
05/15/24 17:01 1
d3-NMePFOSA
83.6
10 - 130
05114124 13:53
05/15/24 17:01 1
Lab Sample ID: LCS 680-837934/2-A
Client Sample ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 838185
Prep Batch: 837934
Spike
LCS LCS
%Rec
Analyte
Added
Result Qualifier Unit
D %Rec
Limits
Perfluorobutanoic acid (PFBA)
51.2
48.5 ng/L
95
70 - 140
Perfluoropentanoic acid (PFPeA)
25.6
25.3 ng/L
99
65 - 135
Perfluorohexanoic acid (PFHxA)
12.8
12.3 ng/L
97
70 - 145
Perfluoroheptanoic acid (PFHpA)
12.8
13.4 ng/L
105
70 - 150
Perfluorooctanoic acid (PFOA)
12.8
12.1 ng/L
95
70 - 150
Perfluorononanoic acid (PFNA)
12.8
12.0 ng/L
94
70 - 150
Perfluorodecanoic acid (PFDA)
12.8
17.2 ng/L
134
70 - 140
Eurofins Raleigh
Page 56 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LCS 680-837934/2-A
Client Sample
ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 838185
Prep Batch: 837934
Spike
LCS LCS
%Rec
Analyte
Added
Result Qualifier
Unit
D %Rec
Limits
Perfluoroundecanoic acid
12.8
12.8
ng/L
100
70 - 145
(PFUnA)
Perfluorododecanoic acid
12.8
12.4
ng/L
97
70 - 140
(PFDoA)
Perfluorotridecanoic acid
12.8
13.4
ng/L
105
65 - 140
(PFTrDA)
Perfluorotetradecanoic acid
12.8
11.7
ng/L
92
60 - 140
(PFTA)
Perfluorobutanesulfonic acid
11.3
10.7
ng/L
94
60 - 145
(PFBS)
Perfluoropentanesulfonic acid
12.0
11.4
ng/L
95
65 - 140
(PFPeS)
Perfluorohexanesulfonic acid
11.7
13.3
ng/L
114
65 - 145
(PFHxS)
Perfluoroheptanesulfonic acid
12.2
13.1
ng/L
108
70 - 150
(PFHpS)
Perfluorooctanesulfonic acid
11.8
20.3 .+
ng/L
172
55 - 150
(PFOS)
Perfluorononanesulfonic acid
12.3
10.8
ng/L
88
65 - 145
(PFNS)
Perfluorododecanesulfonic acid
12.4
7.67
ng/L
62
50 - 145
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
48.0
45.1
ng/L
94
70-145
sulfonic acid (4:2 FTS)
1H,1H,21H,21H-Perfluorooctane
48.7
43.8
ng/L
90
65-155
sulfonic acid (6:2 FTS)
1 H,1 H,2H,2H-Perfluorodecane
49.1
46.0
ng/L
94
60-150
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide
12.8
14.1
ng/L
110
70 - 145
(PFOSA)
N-methylperfluorooctane
12.8
14.2
ng/L
111
60 - 150
sulfonamide (NMeFOSA)
N-ethylperfluorooctane
12.8
11.5
ng/L
90
65 - 145
sulfonamide (NEtFOSA)
N-methylperfluorooctanesulfona
12.8
13.4
ng/L
105
50 - 140
midoacetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonami
12.8
11.4
ng/L
89
70 - 145
doacetic acid (NEtFOSAA)
N-methylperfluorooctane
128
110
ng/L
86
70 - 145
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
128
119
ng/L
93
70 - 135
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide
51.2
50.1
ng/L
98
70 - 140
DimerAcid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic
48.4
49.1
ng/L
101
65 - 145
acid (ADONA)
Perfluoro-4-methoxybutanoic
25.6
24.9
ng/L
97
60 - 150
acid (PFMBA)
Nonafluoro-3,6-dioxaheptanoic
25.6
25.6
ng/L
100
50 - 150
acid (NFDHA)
9-Chlorohexadecafluoro-3-oxan
47.8
38.0
ng/L
79
70 - 155
onane-1-sulfonic
acid(9CI-PHONS)
11-Chloroeicosafluoro-3-oxaund
48.3
31.2
ng/L
65
55-160
ecane-1-sulfonic acid
(11 CI-PHOWS)
Eurofins Raleigh
Page 57 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LCS 680-837934/2-A
Client Sample
ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 838185
Prep Batch: 837934
Spike
LCS
LCS
%Rec
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits
Perfluoro (2-ethoxyethane)
22.8
21.6
ng/L
95
70 - 140
sulfonic acid (PFEESA)
3-Perfluoropropylpropanoic acid
64.0
64.6
ng/L
101
65 - 130
(3:3 FTCA)
3-Perfluoropentylpropanoic acid
320
264
ng/L
83
70 - 135
(5:3 FTCA)
3-Perfluoroheptylpropanoic acid
320
231
ng/L
72
50 - 145
(7:3 FTCA)
Perfluorodecanesulfonic acid
12.3
11.2
ng/L
91
60 - 145
(PFDS)
Perfluoro-3-methoxypropanoic
25.6
24.1
ng/L
94
55 - 140
acid (PFMPA)
LCS LCS
Isotope Dilution %Recovery Qualifier
Limits
13C4 PFBA
66.1
5 - 130
13C5 PFPeA
70.7
40 - 130
13C5 PFHxA
73.7
40 - 130
13C4 PFHpA
71.4
40 - 130
13C8 PFOA
72.7
40 - 130
13C9 PFNA
97.4
40 - 130
13C6 PFDA
67.9
40 - 130
13C7 PFUnA
65.4
30 - 130
13C2 PFDoA
55.0
10 - 130
13C2 PFTeDA
46.2
10 - 130
13C3 PFBS
75.6
40 - 135
13C3 PFHxS
72.6
40 - 130
13C8 PFOS
90.0
40 - 130
13C8 FOSA
70.6
40 - 130
d3-NMeFOSAA
94.3
40 - 170
d5-NEtFOSAA
89.3
25 - 135
M2-4:2 FTS
80.6
40 - 200
M2-6:2 FTS
83.1
40 - 200
M2-8:2 FTS
82.0
40 - 300
13C3 HFPO-DA
79.7
40 - 130
d7-N-McFOSE-M
94.8
10 - 130
d9-N-EtFOSE-M
94.8
10 - 130
d5-NEtPFOSA
93.2
10 - 130
d3-NMePFOSA
79.0
10 - 130
Lab Sample ID: LCSD 680-837934/3-A
Client
Sample ID: Lab Control Sample Dup
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 838185
Prep Batch: 837934
Spike
LCSD
LCSD
%Rec RPD
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits RPD Limit
Perfluorobutanoic acid (PFBA)
51.2
50.0
ng/L
98
70 - 140 3 30
Perfluoropentanoic acid (PFPeA)
25.6
25.9
ng/L
101
65 - 135 2 30
Perfluorohexanoic acid (PFHxA)
12.8
12.5
ng/L
98
70 - 145 1 30
Perfluoroheptanoic acid (PFHpA)
12.8
13.6
ng/L
106
70 - 150 1 30
Perfluorooctanoic acid (PFOA)
12.8
12.2
ng/L
95
70 - 150 0 30
Perfluorononanoic acid (PFNA)
12.8
12.0
ng/L
94
70 - 150 0 30
Eurofins Raleigh
Page 58 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LCSD 680-837934/3-A
Client Sample ID: Lab Control
Sample Dup
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 838185
Prep Batch: 837934
Spike
LCSD LCSD
%Rec
RPD
Analyte
Added
Result Qualifier
Unit
D %Rec
Limits
RPD
Limit
Perfluorodecanoic acid (PFDA)
12.8
18.4 *+
ng/L
144
70 - 140
7
30
Perfluoroundecanoic acid
12.8
13.0
ng/L
101
70 - 145
1
30
(PFUnA)
Perfluorododecanoic acid
12.8
12.7
ng/L
100
70 - 140
2
30
(PFDoA)
Perfluorotrdecanoic acid
12.8
14.7
ng/L
115
65 - 140
10
30 �
(PFTrDA)
Perfluorotetradecanoic acid
12.8
12.5
ng/L
98
60 - 140
7
30
(PFTA)
Perfluorobutanesulfonic acid
11.3
10.7
ng/L
94
60 - 145
0
30
(PFBS)
Perfluoropentanesulfonic acid
12.0
11.7
ng/L
98
65 - 140
3
30
(PFPeS)
Perfluorohexanesulfonic acid
11.7
13.8
ng/L
119
65 - 145
4
30
(PFHxS)
Perfluoroheptanesulfonic acid
12.2
12.7
ng/L
104
70 _ 150
3
30
(PFHpS)
Perfluorooctanesulfonic acid
11.8
24.9 *+
ng/L
210
55 - 150
20
30
(PFOS)
Perfluorononanesulfonic acid
12.3
9.85
ng/L
80
65 - 145
9
30
(PFNS)
Perfluorododecanesulfonic acid
12.4
6.09 *-
ng/L
49
50 - 145
23
30
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
48.0
44.9
ng/L
94
70-145
0
30
sulfonic acid (4:2 FTS)
1H,11-1,2H,21-1-Perfluorooctane
48.7
45.4
ng/L
93
65-155
4
30
sulfonic acid (6:2 FTS)
1 H,1 H,2H,2H-Perfluorodecane
49.1
43.8
ng/L
89
60-150
5
30
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide
12.8
14.6
ng/L
114
70 - 145
3
30
(PFOSA)
N-methylperfluorooctane
12.8
14.5
ng/L
113
60 - 150
2
30
sulfonamide (NMeFOSA)
N-ethylperfluorooctane
12.8
11.5
ng/L
90
65 - 145
0
30
sulfonamide (NEtFOSA)
N-methylperfluorooctanesulfona
12.8
13.1
ng/L
103
50 - 140
2
30
midoacetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonami
12.8
12.1
ng/L
95
70 - 145
6
30
doacetic acid (NEtFOSAA)
N-methylperfluorooctane
128
111
ng/L
87
70 - 145
1
30
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
128
119
ng/L
93
70 - 135
0
30
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide
51.2
51.4
ng/L
100
70 - 140
3
30
DimerAcid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic
48.4
50.1
ng/L
103
65 - 145
2
30
acid (ADONA)
Perfluoro-4-methoxybutanoic
25.6
25.8
ng/L
101
60 - 150
4
30
acid (PFMBA)
Nonafluoro-3,6-dioxaheptanoic
25.6
26.4
ng/L
103
50 - 150
3
30
acid (NFDHA)
9-Chlorohexadecafluoro-3-oxan
47.8
37.0
ng/L
77
70 - 155
3
30
onane-1-sulfonic
acid(9CI-PF30NS)
Eurofins Raleigh
Page 59 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LCSD 680-837934/3-A
Client
Sample ID: Lab Control Sample Dup
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 838185
Prep Batch: 837934
Spike
LCSD
LCSD
%Rec RPD
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits RPD Limit
11-Chloroeicosafluoro-3-oxaund
48.3
29.7
ng/L
61
55-160 5 30
ecane-1-sulfonic acid
(11 CI-PF3OUdS)
Perfluoro (2-ethoxyethane)
22.8
21.4
ng/L
94
70 - 140 1 30
sulfonic acid (PFEESA)
3-Perfluoropropylpropanoic acid
64.0
68.4
ng/L
107
65 - 130 6 30 •
(3:3 FTCA)
3-Perfluoropentylpropanoic acid
320
269
ng/L
84
70 - 135 2 30
(5:3 FTCA)
3-Perfluoroheptylpropanoic acid
320
228
ng/L
71
50 - 145 2 30
(7:3 FTCA)
Perfluorodecanesulfonic acid
12.3
10.3
ng/L
83
60 - 145 9 30
(PFDS)
Perfluoro-3-methoxypropanoic
25.6
25.3
ng/L
99
55 - 140 5 30
acid (PFMPA)
LCSD LCSD
Isotope Dilution %Recovery Qualifier
Limits
13C4 PFBA
69.3
5 - 130
13C5 PFPeA
72.0
40 - 130
13C5 PFHxA
76.7
40 - 130
13C4 PFHpA
74.4
40 - 130
13C8 PFOA
76.4
40 - 130
13C9 PFNA
101
40 - 130
13C6 PFDA
71.0
40 - 130
13C7 PFUnA
67.5
30 - 130
13C2 PFDoA
57.2
10 - 130
13C2 PFTeDA
43.9
10 - 130
13C3 PFBS
82.6
40 - 135
13C3 PFHxS
76.1
40 - 130
13C8 PFOS
94.4
40 - 130
13C8 FOSA
75.1
40 - 130
d3-NMeFOSAA
93.9
40 - 170
d5-NEtFOSAA
89.1
25 - 135
M2-4:2 FTS
88.7
40 - 200
M2-6:2 FTS
88.0
40 - 200
M2-8:2 FTS
91.5
40 - 300
13C3 HFPO-DA
81.5
40 - 130
d7-N-McFOSE-M
101
10-130
d9-N-EtFOSE-M
102
10 - 130
d5-NEtPFOSA
95.1
10 - 130
d3-NMePFOSA
80.3
10 - 130
Lab Sample ID: LLCS 680-837934/4-A
Client Sample
ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 838185
Prep Batch: 837934
Spike
LLCS
LLCS
%Rec
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits
Perfluorobutanoic acid (PFBA)
5.12
5.26
ng/L
103
70 - 140
Perfluoropentanoic acid (PFPeA)
2.56
2.59
ng/L
101
65 - 135
Perfluorohexanoic acid (PFHxA)
1.28
1.39
J
ng/L
109
70 - 145
Perfluoroheptanoic acid (PFHpA)
1.28
1.42
J
ng/L
ill
70 - 150
Eurofins Raleigh
Page 60 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LLCS 680-837934/4-A
Client Sample
ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 838185
Prep Batch: 837934
Spike
LLCS
LLCS
%Rec
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits
Perfluorooctanoic acid (PFOA)
1.28
1.45
J
ng/L
114
70 - 150
Perfluorononanoic acid (PFNA)
1.28
1.31
J
ng/L
103
70 - 150
Perfluorodecanoic acid (PFDA)
1.28
2.00
*+
ng/L
157
70 - 140
Perfluoroundecanoic acid
1.28
1.25
J
ng/L
98
70 - 145
(PFUnA)
Perfluorododecanoic acid
1.28
1.29
J
ng/L
101
70 - 140 •
(PFDoA)
Perfluorotridecanoic acid
1.28
1.56
J
ng/L
122
65 - 140
(PFTrDA)
Perfluorotetradecanoic acid
1.28
1.35
J
ng/L
106
60 - 140
(PFTA)
Perfluorobutanesulfonic acid
1.13
1.07
J
ng/L
95
60 - 145
(PFBS)
Perfluoropentanesulfonic acid
1.20
1.24
J
ng/L
103
65 - 140
(PFPeS)
Perfluorohexanesulfonic acid
1.17
1.68
J
ng/L
144
65 - 145
(PFHxS)
Perfluoroheptanesulfonic acid
1.22
1.39
J
ng/L
114
70 - 150
(PFHpS)
Perfluorooctanesulfonic acid
1.18
18.9
*+
ng/L
1592
55 - 150
(PFOS)
Perfluorononanesulfonic acid
1.23
1.04
J
ng/L
84
65 - 145
(PFNS)
Perfluorododecanesulfonic acid
1.24
0.673
J
ng/L
54
50 - 145
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
4.80
4.58
ng/L
95
70-145
sulfonic acid (4:2 FTS)
1H,11-1,2H,21-1-Perfluorooctane
4.87
5.10
ng/L
105
65-155
sulfonic acid (6:2 FTS)
1 H,1 H,2H,2H-Perfluorodecane
4.91
5.00
ng/L
102
60-150
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide
1.28
1.46
J
ng/L
114
70 - 145
(PFOSA)
N-methylperfluorooctane
1.28
1.35
J
ng/L
105
60 - 150
sulfonamide (NMeFOSA)
N-ethylperfluorooctane
1.28
1.18
J
ng/L
92
65 - 145
sulfonamide (NEtFOSA)
N-methylper luorooctanesulfona
1.28
1.29
J
ng/L
101
50 - 140
midoacetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonami
1.28
1.23
J
ng/L
96
70 - 145
doacetic acid (NEtFOSAA)
N-methylperfluorooctane
12.8
11.3
ng/L
88
70 - 145
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
12.8
11.9
ng/L
93
70 - 135
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide
5.12
5.22
ng/L
102
70 - 140
DimerAcid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic
4.84
5.19
ng/L
107
65 - 145
acid (ADONA)
Perfluoro-4-methoxybutanoic
2.56
2.56
ng/L
100
60 - 150
acid (PFMBA)
Nonafluoro-3,6-dioxaheptanoic
2.56
2.51
ng/L
98
50 - 150
acid (NFDHA)
Eurofins Raleigh
Page 61 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Job ID: 752-19362-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by
LC/MS/MS (Continued)
Lab Sample ID: LLCS 680-837934/4-A
Client Sample ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 838185
Prep Batch: 837934
Spike
LLCS
LLCS
%Rec
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits
9-Chlorohexadecafluoro-3-oxan
4.78
3.62
ng/L
76
70 - 155
onane-1-sulfonic
acid (9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaund
4.83
3.04
ng/L
63
55-160
ecane-1-sulfonic acid
(11 CI-PF3OUdS)
Perfluoro (2-ethoxyethane)
2.28
2.21
ng/L
97
70 - 140
sulfonic acid (PFEESA)
3-Perfluoropropylpropanoic acid
6.40
6.34
ng/L
99
65 - 130
(3:3 FTCA)
3-Perfluoropentylpropanoic acid
32.0
26.8
ng/L
84
70 - 135
(5:3 FTCA)
3-Perfluoroheptylpropanoic acid
32.0
24.0
ng/L
75
50 - 145
(7:3 FTCA)
Perfluorodecanesulfonic acid
1.23
1.08
J
ng/L
88
60 - 145
(PFDS)
Perfluoro-3-methoxypropanoic
2.56
2.51
ng/L
98
55 - 140
acid (PFMPA)
LLCS LLCS
Isotope Dilution %Recovery Qualifier
Limits
13C4 PFBA
66.6
25 - 130
13C5 PFPeA
70.1
40 - 130
13C5 PFHxA
74.1
40 - 130
13C4 PFHpA
71.3
40 - 130
13C8 PFOA
73.2
40 - 130
13C9 PFNA
94.7
40 - 130
13C6 PFDA
67.0
40 - 130
13C7 PFUnA
63.2
30 - 130
13C2 PFDoA
54.1
10 - 130
13C2 PFTeDA
41.9
10 - 130
13C3 PFBS
73.6
40 - 135
13C3 PFHxS
67.2
40 - 130
13C8 PFOS
85.9
40 - 130
13C8 FOSA
71.4
40 - 130
d3-NMeFOSAA
91.7
40 - 170
d5-NEtFOSAA
84.9
25 - 135
M2-4:2 FTS
86.0
40 - 200
M2-6:2 FTS
82.8
40 - 200
M2-8:2 FTS
83.2
40 - 300
13C3 HFPO-DA
77.4
40 - 130
d7-N-McFOSE-M
94.6
10 - 130
d9-N-EtFOSE-M
94.2
10 - 130
d5-NEtPFOSA
89.3
10 - 130
d3-NMePFOSA
79.3
10 - 130
Lab Sample ID: MB 680-838358/1-A
Client Sample ID: Method Blank
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 838415
Prep Batch: 838358
MB MB
Analyte
Result Qualifier
RL
MDL Unit
D Prepared
Analyzed Dil Fac
Perfluorobutanoic acid (PFBA)
<1.0
4.0
1.0 ng/L
05/16/24 11:26
05/16/24 16:33 1
Eurofins Raleigh
Page 62 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: MB 680-838358/1-A
Client Sample ID: Method
Blank
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 838415
Prep Batch:
838358
MB MB
Analyte
Result Qualifier
RL
MDL
unit
D Prepared
Analyzed
Dill Fac
Perfluoropentanoic acid (PFPeA)
<0.50
2.0
0.50
ng/L
05/16/24 11:26
05/16/24 16:33
1
Perfluorohexanoic acid (PFHxA)
<0.10
2.0
0.10
ng/L
05/16/24 11:26
05/16/24 16:33
1
Perfluoroheptanoic acid (PFHpA)
<0.50
2.0
0.50
ng/L
05/16/24 11:26
05/16/24 16:33
1
Perfluorooctanoic acid (PFOA)
<0.50
2.0
0.50
ng/L
05/16/24 11:26
05/16/24 16:33
1
Perfluorononanoic acid (PFNA)
<0.10
2.0
0.10
ng/L
05/16/24 11:26
05/16/24 16:33
1
Perfluorodecanoic acid (PFDA)
<0.10
2.0
0.10
ng/L
05/16/24 11:26
05/16/24 16:33
1
Perfluoroundecanoic acid (PFUnA)
<0.50
2.0
0.50
ng/L
05/16/24 11:26
05/16/24 16:33
1
Perfluorododecanoic acid (PFDoA)
<0.50
2.0
0.50
ng/L
05/16/24 11:26
05/16/24 16:33
1
Perfluorotridecanoic acid (PFTrDA)
<0.50
2.0
0.50
ng/L
05/16/24 11:26
05/16/24 16:33
1
Perfluorotetradecanoic acid (PFTA)
<0.50
2.0
0.50
ng/L
05/16/24 11:26
05/16/24 16:33
1
Perfluorobutanesulfonic acid (PFBS)
<0.50
2.0
0.50
ng/L
05/16/24 11:26
05/16/24 16:33
1
Perfluoropentanesulfonic acid
<0.10
2.0
0.10
ng/L
05/16/24 11:26
05/16/24 16:33
1
(PFPeS)
Perfluorohexanesulfonic acid (PFHxS)
<0.50
2.0
0.50
ng/L
05/16/24 11:26
05/16/24 16:33
1
Perfluoroheptanesulfonic acid
<0.10
2.0
0.10
ng/L
05/16/24 11:26
05/16/24 16:33
1
(PFHpS)
Perfluorooctanesulfonic acid (PFOS)
<0.50
2.0
0.50
ng/L
05/16/24 11:26
05/16/24 16:33
1
Perfluorononanesulfonic acid (PFNS)
<0.10
2.0
0.10
ng/L
05/16/24 11:26
05/16/24 16:33
1
Perfluorododecanesulfonic acid
<0.50
2.0
0.50
ng/L
05/16/24 11:26
05/16/24 16:33
1
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
<0.50
4.0
0.50
ng/L
05/16/24 11:26
05/16/24 16:33
1
sulfonic acid (4:2 FTS)
1H,1H,2H,2H-Perfluorooctanesulfonic
<0.50
4.0
0.50
ng/L
05/16/24 11:26
05/16/24 16:33
1
acid (6:2 FTS)
1H,1H,2H,2H-Perfluorodecane
<0.50
4.0
0.50
ng/L
05/16/24 11:26
05/16/24 16:33
1
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.10
2.0
0.10
ng/L
05/16/24 11:26
05/16/24 16:33
1
N-methylperfluorooctane sulfonamide
<0.50
2.0
0.50
ng/L
05/16/24 11:26
05/16/24 16:33
1
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<0.50
2.0
0.50
ng/L
05/16/24 11:26
05/16/24 16:33
1
(NEtFOSA)
N-methylperfluorooctanesulfonamidoa
<0.50
2.0
0.50
ng/L
05/16/24 11:26
05/16/24 16:33
1
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<0.50
2.0
0.50
ng/L
05/16/24 11:26
05/16/24 16:33
1
etic acid (NEtFOSAA)
N-methylperfluorooctane
<2.0
10
2.0
ng/L
05/16/24 11:26
05/16/24 16:33
1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<2.0
10
2.0
ng/L
05/16/24 11:26
05/16/24 16:33
1
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide Dimer
<0.50
2.0
0.50
ng/L
05/16/24 11:26
05/16/24 16:33
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<0.50
2.0
0.50
ng/L
05/16/24 11:26
05/16/24 16:33
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<0.50
2.0
0.50
ng/L
05/16/24 11:26
05/16/24 16:33
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<0.50
2.0
0.50
ng/L
05/16/24 11:26
05/16/24 16:33
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<0.50
2.0
0.50
ng/L
05/16/24 11:26
05/16/24 16:33
1
e-1-sulfonic acid(9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<0.75
2.0
0.75
ng/L
05/16/24 11:26
05/16/24 16:33
1
e-1-sulfonic acid (110-MOWS)
Perfluoro (2-ethoxyethane) sulfonic
<0.50
2.0
0.50
ng/L
05/16/24 11:26
05/16/24 16:33
1
acid (PFEESA)
Eurofins Raleigh
Page 63 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Job ID: 752-19362-1
Method: 1633 - Per- and Polyfluoroalkyl Substances
by LC/MS/MS (Continued)
Lab Sample ID: MB 680-838358/1-A
Client Sample ID: Method Blank
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 838415
Prep Batch: 838358
MB
MB
Analyte
Result
Qualifier
RL
MDL Unit
D Prepared
Analyzed Dil Fac
3-Perfluoropropylpropanoic acid (3:3
<1.0
4.0
1.0 ng/L
05/16/24 11:26
05/16/24 16:33 1
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<2.7
10
2.7 ng/L
05/16/24 11:26
05/16/24 16:33 1
FTCA)
3-Perfluoroheptylpropanoic acid (7:3
<2.7
10
2.7 ng/L
05/16/24 11:26
05/16/24 16:33 1
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.10
2.0
0.10 ng/L
05/16/24 11:26
05/16/24 16:33 1
Perfluoro-3-methoxypropanoic acid
<0.50
2.0
0.50 ng/L
05/16/24 11:26
05/16/24 16:33 1
(PFMPA)
MB
MB
Isotope Dilution %Recovery
Qualifier
Limits
Prepared
Analyzed Dil Fac
13C4 PFBA
75.7
5 - 130
05116124 11:26
05116124 16:33 1
13C5 PFPeA
70.2
40 - 130
05116124 11:26
05116124 16:33 1
13C5 PFHxA
81.1
40 - 130
05/16/24 11:26
05116124 16:33 1
13C4 PFHpA
70.7
40 - 130
05116124 11:26
05116124 16:33 1
13C8 PFOA
91.6
40 - 130
05/16/24 11:26
05116124 16:33 1
13C9 PFNA
97.4
40 - 130
05/16/24 11:26
05116124 16:33 1
13C6 PFDA
85.3
40 - 130
05116124 11:26
05116124 16:33 1
13C7 PFUnA
88.1
30 - 130
05116124 11:26
05116124 16:33 1
13C2 PFDoA
70.2
10 - 130
05116124 11:26
05116124 16:33 1
13C2 PFTeDA
55.0
10 - 130
05116124 11:26
05116124 16:33 1
13C3 PFBS
84.5
40 - 135
05116124 11:26
05116124 16:33 1
13C3 PFHxS
82.8
40 - 130
05116124 11:26
05116124 16:33 1
13C8 PFOS
101
40 - 130
05116124 11:26
05116124 16:33 1
13C8 FOSA
75.4
40 - 130
05116124 11:26
05116124 16:33 1
d3-NMeFOSAA
110
40 - 170
05116124 11:26
05116124 16:33 1
d5-NEtFOSAA
97.3
25 - 135
05/16/24 11:26
05/16/24 16:33 1
M2-4:2 FTS
84.5
40 - 200
05/16/24 11:26
05/16/24 16:33 1
M2-6:2 FTS
89.2
40 - 200
05/16/24 11:26
05116124 16:33 1
M2-8:2 FTS
86.2
40 - 300
05/16/24 11:26
05116124 16:33 1
13C3 HFPO-DA
77.9
40 - 130
05116124 11:26
05116124 16:33 1
d7-N-McFOSE-M
93.6
10 - 130
05116124 11:26
05116124 16:33 1
d9-N-EtFOSE-M
86.8
10 - 130
05116124 11:26
05116124 16:33 1
d5-NEtPFOSA
102
10 - 130
05116124 11:26
05116124 16:33 1
d3-NMePFOSA
86.8
10 - 130
05116124 11:26
05116124 16:33 1
Lab Sample ID: LCS 680-838358/2-A
Client Sample ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 838415
Prep Batch: 838358
Spike
LCS LCS
%Rec
Analyte
Added
Result Qualifier Unit
D %Rec
Limits
Perfluorobutanoic acid (PFBA)
51.2
44.2 ng/L
86
70 - 140
Perfluoropentanoic acid (PFPeA)
25.6
24.9 ng/L
98
65 - 135
Perfluorohexanoic acid (PFHxA)
12.8
11.4 ng/L
90
70 - 145
Perfluoroheptanoic acid (PFHpA)
12.8
14.2 ng/L
ill
70 - 150
Perfluorooctanoic acid (PFOA)
12.8
10.6 ng/L
83
70 - 150
Perfluorononanoic acid (PFNA)
12.8
11.4 ng/L
90
70 - 150
Perfluorodecanoic acid (PFDA)
12.8
15.4 ng/L
120
70 - 140
Perfluoroundecanoic acid
12.8
10.9 ng/L
85
70 - 145
(PFUnA)
Eurofins Raleigh
Page 64 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LCS 680-838358/2-A
Client Sample
ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 838415
Prep Batch: 838358
Spike
LCS LCS
%Rec
Analyte
Added
Result Qualifier
Unit
D %Rec
Limits
Perfluorododecanoic acid
12.8
13.0
ng/L
102
70 - 140
(PFDoA)
Perfluorotridecanoic acid
12.8
16.2
ng/L
127
65 - 140
(PFTrDA)
Perfluorotetradecanoic acid
12.8
11.9
ng/L
93
60 - 140
(PFTA)
Perfluorobutanesulfonic acid
11.3
9.63
ng/L
85
60 - 145
(PFBS)
Perfluoropentanesulfonic acid
12.0
10.6
ng/L
89
65 - 140
(PFPeS)
Perfluorohexanesulfonic acid
11.7
12.3
ng/L
105
65 - 145
(PFHxS)
Perfluoroheptanesulfonic acid
12.2
12.4
ng/L
102
70 - 150
(PFHpS)
Perfluorooctanesulfonic acid
11.8
11.2
ng/L
95
55 - 150
(PFOS)
Perfluorononanesulfonic acid
12.3
10.5
ng/L
85
65 - 145
(PFNS)
Perfluorododecanesulfonic acid
12.4
4.41 *-
ng/L
36
50 - 145
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
48.0
44.3
ng/L
92
70-145
sulfonic acid (4:2 FTS)
1 H,1 H,2H,2H-Perfluorooctane
48.7
41.9
ng/L
86
65-155
sulfonic acid (6:2 FTS)
1 H,1 H,2H,2H-Perfluorodecane
49.1
44.1
ng/L
90
60-150
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide
12.8
13.7
ng/L
107
70 - 145
(PFOSA)
N-methylperfluorooctane
12.8
13.1
ng/L
102
60 - 150
sulfonamide (NMeFOSA)
N-ethylperfluorooctane
12.8
10.9
ng/L
85
65 - 145
sulfonamide (NEtFOSA)
N-methylperfluorooctanesulfona
12.8
10.3
ng/L
80
50 - 140
midoacetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonami
12.8
11.6
ng/L
91
70 - 145
doacetic acid (NEtFOSAA)
N-methylperfluorooctane
128
111
ng/L
86
70 - 145
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
128
118
ng/L
92
70 - 135
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide
51.2
48.5
ng/L
95
70 - 140
DimerAcid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic
48.4
54.8
ng/L
113
65 - 145
acid (ADONA)
Perfluoro-4-methoxybutanoic
25.6
25.5
ng/L
100
60 - 150
acid (PFMBA)
Nonafluoro-3,6-dioxaheptanoic
25.6
22.6
ng/L
88
50 - 150
acid (NFDHA)
9-Chlorohexadecafluoro-3-oxan
47.8
35.6
ng/L
75
70 - 155
onane-1-sulfonic
acid (9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaund
48.3
32.7
ng/L
68
55-160
ecane-1-sulfonic acid
(11 CI-PF3OUdS)
Perfluoro (2-ethoxyethane)
22.8
23.0
ng/L
101
70 - 140
sulfonic acid (PFEESA)
Eurofins Raleigh
Page 65 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
QC Sample Results
Client: Smith Gardner Inc
Job ID: 752-19362-1
Project/Site: Surry C&D/MSW (Permit 8602)
Method: 1633 - Per- and Polyfluoroalkyl
Substances by LC/MS/MS (Continued)
Lab Sample ID: LCS 680-838358/2-A
Client Sample
ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 838415
Prep Batch: 838358
Spike
LCS
LCS
%Rec
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits
3-Perfluoropropylpropanoic acid
64.0
54.2
ng/L
85
65 - 130
(3:3 FTCA)
3-Perfluoropentylpropanoic acid
320
231
ng/L
72
70 - 135
(5:3 FTCA)
3-Perfluoroheptylpropanoic acid
320
204
ng/L
64
50 - 145
(7:3 FTCA)
Perfluorodecanesulfonic acid
12.3
8.87
ng/L
72
60 - 145
(PFDS)
Perfluoro-3-methoxypropanoic
25.6
23.8
ng/L
93
55 - 140
acid (PFMPA)
LCS LCS
Isotope Dilution %Recovery Qualifier
Limits
13C4 PFBA
72.0
5 - 130
13C5 PFPeA
68.4
40 - 130
13C5 PFHxA
78.3
40 - 130
13C4 PFHpA
69.2
40 - 130
13C8 PFOA
81.5
40 - 130
13C9 PFNA
93.9
40 - 130
13C6 PFDA
81.4
40 - 130
13C7 PFUnA
80.5
30 - 130
13C2 PFDoA
63.4
10 - 130
13C2 PFTeDA
41.7
10 - 130
13C3 PFBS
81.2
40 - 135
13C3 PFHxS
77.0
40 - 130
13C8 PFOS
91.7
40 - 130
13C8 FOSA
71.1
40 - 130
d3-NMeFOSAA
104
40 - 170
d5-NEtFOSAA
89.0
25 - 135
M2-4:2 FTS
82.9
40 - 200
M2-6:2 FTS
88.4
40 - 200
M2-8:2 FTS
79.7
40 - 300
13C3 HFPO-DA
74.0
40 - 130
d7-N-McFOSE-M
91.0
10 - 130
d9-N-EtFOSE-M
82.4
10 - 130
d5-NEtPFOSA
94.1
10 - 130
d3-NMePFOSA
80.0
10 - 130
Lab Sample ID: LCSD 680-838358/3-A
Client
Sample ID: Lab Control Sample Dup
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 838415
Prep Batch: 838358
Spike
LCSD
LCSD
%Rec RPD
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits RPD Limit
Perfluorobutanoic acid (PFBA)
51.2
47.2
ng/L
92
70 - 140 6 30
Perfluoropentanoic acid (PFPeA)
25.6
26.5
ng/L
103
65 - 135 6 30
Perfluorohexanoic acid (PFHxA)
12.8
11.9
ng/L
93
70 - 145 4 30
Perfluoroheptanoic acid (PFHpA)
12.8
14.9
ng/L
116
70 - 150 5 30
Perfluorooctanoic acid (PFOA)
12.8
9.77
ng/L
76
70 - 150 8 30
Perfluorononanoic acid (PFNA)
12.8
12.7
ng/L
100
70 - 150 10 30
Perfluorodecanoic acid (PFDA)
12.8
17.6
ng/L
138
70 - 140 14 30
Eurofins Raleigh
Page 66 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
QC Sample Results
Client: Smith Gardner Inc Job ID: 752-19362-1
Project/Site: Surry C&D/MSW (Permit 8602)
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LCSD 680-838358/3-A
Client Sample ID: Lab Control
Sample Dup
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 838415
Prep Batch: 838358
Spike
LCSD LCSD
%Rec
RPD
Analyte
Added
Result Qualifier
Unit
D %Rec
Limits
RPD
Limit
Perfluoroundecanoic acid
12.8
10.9
ng/L
85
70 - 145
0
30
(PFUnA)
Perfluorododecanoic acid
12.8
13.8
ng/L
108
70 - 140
6
30
(PFDoA)
Perfluorotridecanoic acid
12.8
15.5
ng/L
122
65 - 140
4
30
(PFTrDA)
Perfluorotetradecanoic acid
12.8
12.3
ng/L
96
60 - 140
4
30
(PFTA)
Perfluorobutanesulfonic acid
11.3
10.3
ng/L
91
60 - 145
6
30
(PFBS)
Perfluoropentanesulfonic acid
12.0
12.1
ng/L
101
65 - 140
13
30
(PFPeS)
Perfluorohexanesulfonic acid
11.7
12.9
ng/L
111
65 - 145
5
30
(PFHxS)
Perfluoroheptanesulfonic acid
12.2
12.4
ng/L
102
70 - 150
1
30
(PFHpS)
Perfluorooctanesulfonic acid
11.8
12.4
ng/L
105
55 - 150
10
30
(PFOS)
Perfluorononanesulfonic acid
12.3
11.1
ng/L
90
65 - 145
5
30
(PFNS)
Perfluorododecanesulfonic acid
12.4
6.22 *1
ng/L
50
50 - 145
34
30
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
48.0
49.3
ng/L
103
70-145
11
30
sulfonic acid (4:2 FTS)
1H,1H,21H,21H-Perfluorooctane
48.7
51.8
ng/L
106
65-155
21
30
sulfonic acid (6:2 FTS)
1 H,1 H,2H,2H-Perfluorodecane
49.1
51.2
ng/L
104
60-150
15
30
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide
12.8
14.1
ng/L
111
70 - 145
3
30
(PFOSA)
N-methylperfluorooctane
12.8
14.4
ng/L
112
60 - 150
9
30
sulfonamide (NMeFOSA)
N-ethylperfluorooctane
12.8
11.8
ng/L
92
65 - 145
7
30
sulfonamide (NEtFOSA)
N-methylperfluorooctanesulfona
12.8
11.4
ng/L
89
50 - 140
10
30
midoacetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonami
12.8
13.1
ng/L
102
70 - 145
12
30
doacetic acid (NEtFOSAA)
N-methylperfluorooctane
128
117
ng/L
91
70 - 145
5
30
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
128
122
ng/L
96
70 - 135
4
30
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide
51.2
54.4
ng/L
106
70 - 140
11
30
DimerAcid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic
48.4
57.3
ng/L
118
65 - 145
5
30
acid (ADONA)
Perfluoro-4-methoxybutanoic
25.6
27.7
ng/L
108
60 - 150
8
30
acid (PFMBA)
Nonafluoro-3,6-dioxaheptanoic
25.6
22.4
ng/L
87
50 - 150
1
30
acid (NFDHA)
9-Chlorohexadecafluoro-3-oxan
47.8
39.3
ng/L
82
70 - 155
10
30
onane-1-sulfonic
acid(9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaund
48.3
40.7
ng/L
84
55-160
22
30
ecane-1-sulfonic acid
(11 CI-PHOWS)
Eurofins Raleigh
Page 67 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LCSD 680-838358/3-A
Client
Sample ID: Lab Control Sample Dup
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 838415
Prep Batch: 838358
Spike
LCSD
LCSD
%Rec RPD
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits RPD Limit
Perfluoro (2-ethoxyethane)
22.8
24.4
ng/L
107
70 - 140 6 30
sulfonic acid (PFEESA)
3-Perfluoropropylpropanoic acid
64.0
57.1
ng/L
89
65 - 130 5 30
(3:3 FTCA)
3-Perfluoropentylpropanoic acid
320
248
ng/L
77
70 - 135 7 30
(5:3 FTCA)
3-Perfluoroheptylpropanoic acid
320
219
ng/L
68
50 - 145 7 30
(7:3 FTCA)
Perfluorodecanesulfonic acid
12.3
10.8
ng/L
88
60 - 145 20 30
(PFDS)
Perfluoro-3-methoxypropanoic
25.6
25.8
ng/L
101
55 - 140 8 30
acid (PFMPA)
LCSD LCSD
Isotope Dilution %Recovery Qualifier
Limits
13C4 PFBA
71.8
5 - 130
13C5 PFPeA
65.7
40 - 130
13C5 PFHxA
77.7
40 - 130
13C4 PFHpA
67.2
40 - 130
13C8 PFOA
86.9
40 - 130
13C9 PFNA
90.7
40 - 130
13C6 PFDA
79.1
40 - 130
13C7 PFUnA
80.5
30 - 130
13C2 PFDoA
63.3
10 - 130
13C2 PFTeDA
47.7
10 - 130
13C3 PFBS
77.5 1
40 - 135
13C3 PFHxS
75.7
40 - 130
13C8 PFOS
94.2
40 - 130
13C8 FOSA
71.8
40 - 130
d3-NMeFOSAA
101
40 - 170
d5-NEtFOSAA
89.2
25 - 135
M2-4:2 FTS
78.4
40 - 200
M2-6:2 FTS
80.8
40 - 200
M2-8:2 FTS
76.7
40 - 300
13C3 HFPO-DA
72.0
40 - 130
d7-N-McFOSE-M
91.9
10 - 130
d9-N-EtFOSE-M
83.7
10 - 130
d5-NEtPFOSA
97.4
10 - 130
d3-NMePFOSA
79.9
10 - 130
Lab Sample ID: LLCS 680-838358/4-A
Client Sample
ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 838415
Prep Batch: 838358
Spike
LLCS
LLCS
%Rec
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits
Perfluorobutanoic acid (PFBA)
5.12
4.62
ng/L
90
70 - 140
Perfluoropentanoic acid (PFPeA)
2.56
2.55
ng/L
100
65 - 135
Perfluorohexanoic acid (PFHxA)
1.28
1.30
J
ng/L
102
70 - 145
Perfluoroheptanoic acid (PFHpA)
1.28
1.53
J I
ng/L
120
70 - 150
Perfluorooctanoic acid (PFOA)
1.28
1.24
J
ng/L
97
70 - 150
Perfluorononanoic acid (PFNA)
1.28
1.20
J
ng/L
94
70 - 150
Eurofins Raleigh
Page 68 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LLCS 680-838358/4-A
Client Sample
ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 838415
Prep Batch: 838358
Spike
LLCS
LLCS
%Rec
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits
Perfluorodecanoic acid (PFDA)
1.28
1.67
J
ng/L
131
70 - 140
Perfluoroundecanoic acid
1.28
1.07
J
ng/L
84
70 - 145
(PFUnA)
Perfluorododecanoic acid
1.28
1.42
J
ng/L
111
70 - 140
(PFDoA)
Perfluorotrdecanoic acid
1.28
1.45
J
ng/L
113
65 - 140 �
(PFTrDA)
Perfluorotetradecanoic acid
1.28
1.19
J
ng/L
93
60 - 140
(PFTA)
Perfluorobutanesulfonic acid
1.13
0.980
J
ng/L
86
60 - 145
(PFBS)
Perfluoropentanesulfonic acid
1.20
1.10
J
ng/L
92
65 - 140
(PFPeS)
Perfluorohexanesulfonic acid
1.17
1.44
J
ng/L
124
65 - 145
(PFHxS)
Perfluoroheptanesulfonic acid
1.22
1.20
J
ng/L
99
70. 150
(PFHpS)
Perfluorooctanesulfonic acid
1.18
1.16
J
ng/L
98
55 - 150
(PFOS)
Perfluorononanesulfonic acid
1.23
0.971
J
ng/L
79
65 - 145
(PFNS)
Perfluorododecanesulfonic acid
1.24
0.634
J
ng/L
51
50 - 145
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
4.80
4.63
ng/L
97
70-145
sulfonic acid (4:2 FTS)
1H,11-1,2H,21-1-Perfluorooctane
4.87
4.88
ng/L
100
65-155
sulfonic acid (6:2 FTS)
1 H,1 H,2H,2H-Perfluorodecane
4.91
4.59
ng/L
93
60-150
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide
1.28
1.37
J
ng/L
108
70 - 145
(PFOSA)
N-methylperfluorooctane
1.28
1.46
J
ng/L
114
60 - 150
sulfonamide (NMeFOSA)
N-ethylperfluorooctane
1.28
1.22
J
ng/L
96
65 - 145
sulfonamide (NEtFOSA)
N-methylperfluorooctanesulfona
1.28
1.03
J
ng/L
81
50 - 140
midoacetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonami
1.28
0.930
J
ng/L
73
70 - 145
doacetic acid (NEtFOSAA)
N-methylperfluorooctane
12.8
11.1
ng/L
87
70 - 145
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
12.8
11.6
ng/L
91
70 - 135
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide
5.12
4.93
ng/L
96
70 - 140
DimerAcid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic
4.84
5.69
ng/L
118
65 - 145
acid (ADONA)
Perfluoro-4-methoxybutanoic
2.56
2.61
ng/L
102
60 - 150
acid (PFMBA)
Nonafluoro-3,6-dioxaheptanoic
2.56
2.41
ng/L
94
50 - 150
acid (NFDHA)
9-Chlorohexadecafluoro-3-oxan
4.78
4.06
ng/L
85
70-155
onane-1-sulfonic
acid(9CI-PF30NS)
Eurofins Raleigh
Page 69 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LLCS 680-838358/4-A
Client Sample ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 838415
Prep Batch: 838358
Spike
LLCS
LLCS
%Rec
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits
11-Chloroeicosafluoro-3-oxaund
4.83
3.87
ng/L
80
55-160
ecane-1-sulfonic acid
(11 CI-PF3OUdS)
Perfluoro (2-ethoxyethane)
2.28
2.16
ng/L
95
70 - 140
sulfonic acid (PFEESA)
3-Perfluoropropylpropanoic acid
6.40
4.89
ng/L
76
65 - 130
(3:3 FTCA)
3-Perfluoropentylpropanoic acid
32.0
25.3
ng/L
79
70 - 135
(5:3 FTCA)
3-Perfluoroheptylpropanoic acid
32.0
21.7
ng/L
68
50 - 145
(7:3 FTCA)
Perfluorodecanesulfonic acid
1.23
0.950
J
ng/L
77
60 - 145
(PFDS)
Perfluoro-3-methoxypropanoic
2.56
2.44
ng/L
95
55 - 140
acid (PFMPA)
LLCS LLCS
Isotope Dilution %Recovery
Qualifier
Limits
13C4 PFBA
73.1
25 - 130
13C5 PFPeA
67.5
40 - 130
13C5 PFHxA
77.2
40 - 130
13C4 PFHpA
68.7
40 - 130
13C8 PFOA
89.6
40 - 130
13C9 PFNA
93.9
40 - 130
13C6 PFDA
83.8
40 - 130
13C7 PFUnA
83.8
30 - 130
13C2 PFDoA
66.5
10 - 130
13C2 PFTeDA
51.8
10 - 130
13C3 PFBS
86.0
40 - 135
13C3 PFHxS
78.6
40 - 130
13C8 PFOS
95.5
40 - 130
13C8 FOSA
71.1
40 - 130
d3-NMeFOSAA
102
40 - 170
d5-NEtFOSAA
89.8
25 - 135
M2-4:2 FTS
83.5
40 - 200
M2-6:2 FTS
84.2
40 - 200
M2-8:2 FTS
81.1
40 - 300
13C3 HFPO-DA
72.0
40 - 130
d7-N-McFOSE-M
91.5
10 - 130
d9-N-EtFOSE-M
85.1
10 - 130
d5-NEtPFOSA
97.3
10 - 130
d3-NMePFOSA
80.4
10 - 130
Lab Sample ID: MB 680-838897/1-A
Client Sample ID: Method Blank
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 839063
Prep Batch: 838897
MB MB
Analyte
Result Qualifier
RL
MDL Unit
D Prepared
Analyzed Dil Fac
Perfluorobutanoic acid (PFBA)
<1.0
4.0
1.0 ng/L
05/20/24 14:56
05/21/24 11:37 1
Perfluoropentanoic acid (PFPeA)
<0.50
2.0
0.50 ng/L
05/20/24 14:56
05/21/24 11:37 1
Perfluorohexanoic acid (PFHxA)
<0.10
2.0
0.10 ng/L
05/20/24 14:56
05/21/24 11:37 1
Perfluoroheptanoic acid (PFHpA)
<0.50
2.0
0.50 ng/L
05/20/24 14:56
05/21/24 11:37 1
Eurofins Raleigh
Page 70 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: MB 680-838897/1-A
Client Sample ID: Method
Blank
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 839063
Prep Batch:
838897
MB MB
Analyte
Result Qualifier
RL
MDL
unit
D Prepared
Analyzed
Dill Fac
Perfluorooctanoic acid (PFOA)
<0.50
2.0
0.50
ng/L
05/20/24 14:56
05/21/24 11:37
1
Perfluorononanoic acid (PFNA)
<0.10
2.0
0.10
ng/L
05/20/24 14:56
05/21/24 11:37
1
Perfluorodecanoic acid (PFDA)
<0.10
2.0
0.10
ng/L
05/20/24 14:56
05/21/24 11:37
1
Perfluoroundecanoic acid (PFUnA)
<0.50
2.0
0.50
ng/L
05/20/24 14:56
05/21/24 11:37
1
Perfluorododecanoic acid (PFDoA)
<0.50
2.0
0.50
ng/L
05/20/24 14:56
05/21/24 11:37
1
Perfluorotridecanoic acid (PFTrDA)
<0.50
2.0
0.50
ng/L
05/20/24 14:56
05/21/24 11:37
1
Perfluorotetradecanoic acid (PFTA)
<0.50
2.0
0.50
ng/L
05/20/24 14:56
05/21/24 11:37
1
Perfluorobutanesulfonic acid (PFBS)
<0.50
2.0
0.50
ng/L
05/20/24 14:56
05/21/24 11:37
1
Perfluoropentanesulfonic acid
<0.10
2.0
0.10
ng/L
05/20/24 14:56
05/21/24 11:37
1
(PFPeS)
Perfluorohexanesulfonic acid (PFHxS)
<0.50
2.0
0.50
ng/L
05/20/24 14:56
05/21/24 11:37
1
Perfluoroheptanesulfonic acid
<0.10
2.0
0.10
ng/L
05/20/24 14:56
05/21/24 11:37
1
(PFHpS)
Perfluorooctanesulfonic acid (PFOS)
<0.50
2.0
0.50
ng/L
05/20/24 14:56
05/21/24 11:37
1
Perfluorononanesulfonic acid (PFNS)
<0.10
2.0
0.10
ng/L
05/20/24 14:56
05/21/24 11:37
1
Perfluorododecanesulfonic acid
<0.50
2.0
0.50
ng/L
05/20/24 14:56
05/21/24 11:37
1
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
<0.50
4.0
0.50
ng/L
05/20/24 14:56
05/21/24 11:37
1
sulfonic acid (4:2 FTS)
1H,1H,2H,2H-Perfluorooctanesulfonic
<0.50
4.0
0.50
ng/L
05/20/24 14:56
05/21/24 11:37
1
acid (6:2 FTS)
1H,1H,2H,2H-Perfluorodecane
<0.50
4.0
0.50
ng/L
05/20/24 14:56
05/21/24 11:37
1
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide (PFOSA)
<0.10
2.0
0.10
ng/L
05/20/24 14:56
05/21/24 11:37
1
N-methylperfluorooctane sulfonamide
<0.50
2.0
0.50
ng/L
05/20/24 14:56
05/21/24 11:37
1
(NMeFOSA)
N-ethylperfluorooctane sulfonamide
<0.50
2.0
0.50
ng/L
05/20/24 14:56
05/21/24 11:37
1
(NEtFOSA)
N-methylperfluorooctanesulfonamidoa
<0.50
2.0
0.50
ng/L
05/20/24 14:56
05/21/24 11:37
1
cetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonamidoac
<0.50
2.0
0.50
ng/L
05/20/24 14:56
05/21/24 11:37
1
etic acid (NEtFOSAA)
N-methylperfluorooctane
<2.0
10
2.0
ng/L
05/20/24 14:56
05/21/24 11:37
1
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
<2.0
10
2.0
ng/L
05/20/24 14:56
05/21/24 11:37
1
sulfonamidoethanol (NETOSE)
Hexafluoropropylene Oxide Dimer
<0.50
2.0
0.50
ng/L
05/20/24 14:56
05/21/24 11:37
1
Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic acid
<0.50
2.0
0.50
ng/L
05/20/24 14:56
05/21/24 11:37
1
(ADONA)
Perfluoro-4-methoxybutanoic acid
<0.50
2.0
0.50
ng/L
05/20/24 14:56
05/21/24 11:37
1
(PFMBA)
Nonafluoro-3,6-dioxaheptanoic acid
<0.50
2.0
0.50
ng/L
05/20/24 14:56
05/21/24 11:37
1
(NFDHA)
9-Chlorohexadecafluoro-3-oxanonan
<0.50
2.0
0.50
ng/L
05/20/24 14:56
05/21/24 11:37
1
e-1-sulfonic acid(9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaundecan
<0.75
2.0
0.75
ng/L
05/20/24 14:56
05/21/24 11:37
1
e-1-sulfonic acid (11CI-PF30UdS)
Perfluoro (2-ethoxyethane) sulfonic
<0.50
2.0
0.50
ng/L
05/20/24 14:56
05/21/24 11:37
1
acid (PFEESA)
3-Perfluoropropylpropanoic acid (3:3
<1.0
4.0
1.0
ng/L
05/20/24 14:56
05/21/24 11:37
1
FTCA)
3-Perfluoropentylpropanoic acid (5:3
<2.7
10
2.7
ng/L
05/20/24 14:56
05/21/24 11:37
1
FTCA)
Eurofins Raleigh
Page 71 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
QC Sample Results
Client: Smith Gardner Inc
Job ID: 752-19362-1
Project/Site: Surry C&D/MSW (Permit 8602)
Method: 1633 - Per- and Polyfluoroalkyl Substances
by LC/MS/MS (Continued)
Lab Sample ID: MB 680-838897/1-A
Client Sample ID: Method Blank
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 839063
Prep Batch: 838897
MB
MB
Analyte
Result
Qualifier
RL
MDL Unit
D Prepared
Analyzed Dil Fac
3-Perfluoroheptylpropanoic acid (7:3
<2.7
10
2.7 ng/L
05/20/24 14:56
05/21/24 11:37 1
FTCA)
Perfluorodecanesulfonic acid (PFDS)
<0.10
2.0
0.10 ng/L
05/20/24 14:56
05/21/24 11:37 1
Perfluoro-3-methoxypropanoic acid
<0.50
2.0
0.50 ng/L
05/20/24 14:56
05/21/24 11:37 1
(PFMPA)
MB
MB
Isotope Dilution %Recovery
Qualifier
Limits
Prepared
Analyzed Dil Fac
13C4 PFBA
59.8
5 - 130
05120124 14:56
05121124 11:37 1
13C5 PFPeA
62.3
40 - 130
05120124 14:56
05121124 11:37 1
13C5 PFHxA
66.5
40 - 130
05120124 14:56
05121124 11:37 1
13C4 PFHpA
63.4
40 - 130
05120124 14:56
05121124 11:37 1
13C8 PFOA
67.0
40 - 130
05120124 14:56
05121124 11:37 1
13C9 PFNA
87.0
40 - 130
05120124 14:56
05121124 11:37 1
13C6 PFDA
61.5
40 - 130
05120124 14:56
05121124 11:37 1
13C7 PFUnA
56.8
30 - 130
05120124 14:56
05121124 11:37 1
13C2 PFDoA
48.1
10 - 130
05120124 14:56
05121124 11:37 1
13C2 PFTeDA
39.8
10 - 130
05120124 14:56
05121124 11:37 1
13C3 PFBS
70.7
40 - 135
05120124 14:56
05121124 11:37 1
13C3 PFHxS
66.6
40 - 130
05120124 14:56
05121124 11:37 1
13C8 PFOS
82.0
40 - 130
05120124 14:56
05121124 11:37 1
13C8 FOSA
64.3
40 - 130
05120124 14:56
05121124 11:37 1
d3-NMeFOSAA
84.5
40 - 170
05120124 14:56
05121124 11:37 1
d5-NEtFOSAA
78.2
25 - 135
05120124 14:56
05121124 11:37 1
M2-4:2 FTS
80.6
40 - 200
05120124 14:56
05121124 11:37 1
M2-6:2 FTS
77.6
40 - 200
05120124 14:56
05121124 11:37 1
M2-8:2 FTS
73.7
40 - 300
05120124 14:56
05121124 11:37 1
13C3 HFPO-DA
73.5
40 - 130
05120124 14:56
05121124 11:37 1
d7-N-McFOSE-M
83.8
10 - 130
05120124 14:56
05121124 11:37 1
d9-N-EtFOSE-M
85.5
10 - 130
05120124 14:56
05121124 11:37 1
d5-NEtPFOSA
96.9
10 - 130
05120124 14:56
05121124 11:37 1
d3-NMePFOSA
77.1
10 - 130
05120124 14:56
05121124 11:37 1
Lab Sample ID: LCS 680-838897/2-A
Client Sample ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 839063
Prep Batch: 838897
Spike
LCS LCS
%Rec
Analyte
Added
Result Qualifier
Unit
D %Rec
Limits
Perfluorobutanoic acid (PFBA)
51.2
51.1
ng/L
100
70 - 140
Perfluoropentanoic acid (PFPeA)
25.6
27.3
ng/L
107
65 - 135
Perfluorohexanoic acid (PFHxA)
12.8
13.2
ng/L
103
70 - 145
Perfluoroheptanoic acid (PFHpA)
12.8
14.2
ng/L
ill
70 - 150
Perfluorooctanoic acid (PFOA)
12.8
12.6
ng/L
99
70 - 150
Perfluorononanoic acid (PFNA)
12.8
12.5
ng/L
98
70 - 150
Perfluorodecanoic acid (PFDA)
12.8
18.8 .+
ng/L
148
70 - 140
Perfluoroundecanoic acid
12.8
12.7
ng/L
100
70 - 145
(PFUnA)
Perfluorododecanoic acid
12.8
13.3
ng/L
104
70 - 140
(PFDoA)
Perfluorotridecanoic acid
12.8
13.8
ng/L
108
65 - 140
(PFTrDA)
Eurofins Raleigh
Page 72 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LCS 680-838897/2-A
Client Sample
ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 839063
Prep Batch: 838897
Spike
LCS LCS
%Rec
Analyte
Added
Result Qualifier
Unit
D %Rec
Limits
Perfluorotetradecanoic acid
12.8
12.6
ng/L
98
60 - 140
(PFTA)
Perfluorobutanesulfonic acid
11.3
11.4
ng/L
101
60 - 145
(PFBS)
Perfluoropentanesulfonic acid
12.0
12.2
ng/L
101
65 - 140
(PFPeS)
Perfluorohexanesulfonic acid
11.7
14.1
ng/L
121
65 - 145
(PFHxS)
Perfluoroheptanesulfonic acid
12.2
12.8
ng/L
105
70 - 150
(PFHpS)
Perfluorooctanesulfonic acid
11.8
11.1
ng/L
94
55 - 150
(PFOS)
Perfluorononanesulfonic acid
12.3
10.8
ng/L
88
65 - 145
(PFNS)
Perfluorododecanesulfonic acid
12.4
7.74
ng/L
62
50 - 145
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
48.0
47.0
ng/L
98
70-145
sulfonic acid (4:2 FTS)
1 H,1 H,2H,2H-Perfluorooctane
48.7
49.0
ng/L
101
65-155
sulfonic acid (6:2 FTS)
1 H,1 H,2H,2H-Perfluorodecane
49.1
46.9
ng/L
95
60-150
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide
12.8
14.4
ng/L
113
70 - 145
(PFOSA)
N-methylperfluorooctane
12.8
14.6
ng/L
114
60 - 150
sulfonamide (NMeFOSA)
N-ethylperfluorooctane
12.8
11.5
ng/L
90
65 - 145
sulfonamide (NEtFOSA)
N-methylperfluorooctanesulfona
12.8
13.6
ng/L
107
50 - 140
midoacetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonami
12.8
11.6
ng/L
91
70 - 145
doacetic acid (NEtFOSAA)
N-methylperfluorooctane
128
117
ng/L
91
70 - 145
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
128
124
ng/L
97
70 - 135
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide
51.2
52.9
ng/L
103
70 - 140
Dimer Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic
48.4
51.5
ng/L
107
65 - 145
acid (ADONA)
Perfluoro-4-methoxybutanoic
25.6
26.9
ng/L
105
60 - 150
acid (PFMBA)
Nonafluoro-3,6-dioxaheptanoic
25.6
27.2
ng/L
106
50 - 150
acid (NFDHA)
9-Chlorohexadecafluoro-3-oxan
47.8
37.3
ng/L
78
70 - 155
onane-1-sulfonic
acid (9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaund
48.3
32.1
ng/L
66
55.160
ecane-1-sulfonic acid
(11 CI-PF30UdS)
Perfluoro (2-ethoxyethane)
22.8
21.3
ng/L
93
70 - 140
sulfonic acid (PFEESA)
3-Perfluoropropylpropanoic acid
64.0
66.4
ng/L
104
65 - 130
(3:3 FTCA)
3-Perfluoropentylpropanoic acid
320
274
ng/L
86
70 - 135
(5:3 FTCA)
Eurofins Raleigh
Page 73 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LCS 680-838897/2-A
Client Sample
ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 839063
Prep Batch: 838897
Spike
LCS LCS
%Rec
Analyte
Added
Result Qualifier
Unit
D %Rec
Limits
3-Perfluoroheptylpropanoic acid
320
239
ng/L
75
50 - 145
(7:3 FTCA)
Perfluorodecanesulfonic acid
12.3
11.1
ng/L
90
60 - 145
(PFDS)
Perfluoro-3-methoxypropanoic
25.6
27.9
ng/L
109
55 - 140
acid (PFMPA)
LCS LCS
Isotope Dilution %Recovery Qualifier
Limits
13C4 PFBA
59.1
5 - 130
13C5 PFPeA
62.9
40 - 130
13C5 PFHxA
67.5
40 - 130
13C4 PFHpA
63.8
40 - 130
13CB PFOA
64.6
40 - 130
13C9 PFNA
86.0
40 - 130
13C6 PFDA
62.3
40 - 130
13C7 PFUnA
59.2
30 - 130
13C2 PFDoA
49.8
10 - 130
13C2 PFTeDA
39.5
10 - 130
13C3 PFBS
68.7
40 - 135
13C3 PFHxS
65.3
40 - 130
13C8 PFOS
81.9
40 - 130
13C8 FOSA
63.5
40 - 130
d3-NMeFOSAA
84.1
40 - 170
d5-NEtFOSAA
75.9
25 - 135
M2-4:2 FTS
78.0
40 - 200
M2-6:2 FTS
76.4
40 - 200
M2-8:2 FTS
73.2
40 - 300
13C3 HFPO-DA
73.1
40 - 130
d7-N-McFOSE-M
83.0
10 - 130
d9-N-EtFOSE-M
85.6
10 - 130
d5-NEtPFOSA
93.5
10 - 130
d3-NMePFOSA
77.2
10 - 130
Lab Sample ID: LCSD 680-838897/3-A
Client
Sample ID: Lab Control Sample Dup
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 839063
Prep Batch: 838897
Spike
LCSD LCSD
%Rec RPD
Analyte
Added
Result Qualifier
Unit
D %Rec
Limits RPD Limit
Perfluorobutanoic acid (PFBA)
51.2
53.7
ng/L
105
70 - 140 5 30
Perfluoropentanoic acid (PFPeA)
25.6
28.6
ng/L
112
65 - 135 4 30
Perfluorohexanoic acid (PFHxA)
12.8
13.8
ng/L
108
70 - 145 5 30
Perfluoroheptanoic acid (PFHpA)
12.8
14.8
ng/L
116
70 - 150 4 30
Perfluorooctanoic acid (PFOA)
12.8
13.2
ng/L
104
70 - 150 5 30
Perfluorononanoic acid (PFNA)
12.8
13.0
ng/L
102
70 - 150 4 30
Perfluorodecanoic acid (PFDA)
12.8
19.8 *+
ng/L
155
70 - 140 5 30
Perfluoroundecanoic acid
12.8
14.1
ng/L
110
70 - 145 10 30
(PFUnA)
Perfluorodndecanoic acid
12.8
14.1
ng/L
110
70 - 140 5 30
(PFDoA)
Eurofins Raleigh
Page 74 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
QC Sample Results
Client: Smith Gardner Inc Job ID: 752-19362-1
Project/Site: Surry C&D/MSW (Permit 8602)
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LCSD 680-838897/3-A
Client Sample ID: Lab Control
Sample Dup
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 839063
Prep Batch: 838897
Spike
LCSD LCSD
%Rec
RPD
Analyte
Added
Result Qualifier
Unit
D %Rec
Limits
RPD
Limit
Perfluorotridecanoic acid
12.8
13.9
ng/L
109
65 - 140
1
30
(PFTrDA)
Perfluorotetradecanoic acid
12.8
13.0
ng/L
102
60 - 140
3
30
(PFTA)
Perfluorobutanesulfonic acid
11.3
11.6
ng/L
102
60 - 145
2
30
(PFBS)
Perfluoropentanesulfonic acid
12.0
12.9
ng/L
107
65 - 140
6
30
(PFPeS)
Perfluorohexanesulfonic acid
11.7
15.1
ng/L
130
65 - 145
7
30
(PFHxS)
Perfluoroheptanesulfonic acid
12.2
13.4
ng/L
110
70 - 150
5
30
(PFHpS)
Perfluorooctanesulfonic acid
11.8
11.4
ng/L
97
55 - 150
3
30
(PFOS)
Perfluorononanesulfonic acid
12.3
11.4
ng/L
93
65 - 145
6
30
(PFNS)
Perfluorododecanesulfonic acid
12.4
9.02
ng/L
73
50 - 145
15
30
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
48.0
49.5
ng/L
103
70-145
5
30
sulfonic acid (4:2 FTS)
1 H,1 H,2H,2H-Perfluorooctane
48.7
51.5
ng/L
106
65-155
5
30
sulfonic acid (6:2 FTS)
1 H,1 H,2H,2H-Perfluorodecane
49.1
51.9
ng/L
106
60-150
10
30
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide
12.8
14.9
ng/L
117
70 - 145
4
30
(PFOSA)
N-methylperfluorooctane
12.8
15.4
ng/L
120
60 - 150
5
30
sulfonamide (NMeFOSA)
N-ethylperfluorooctane
12.8
12.1
ng/L
94
65 - 145
5
30
sulfonamide (NEtFOSA)
N-methylperfluorooctanesulfona
12.8
14.2
ng/L
111
50 - 140
4
30
midoacetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonami
12.8
12.0
ng/L
94
70 - 145
4
30
doacetic acid (NEtFOSAA)
N-methylperfluorooctane
128
119
ng/L
93
70 - 145
2
30
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
128
132
ng/L
103
70 - 135
6
30
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide
51.2
55.2
ng/L
108
70 - 140
4
30
Dimer Acid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic
48.4
54.0
ng/L
112
65 - 145
5
30
acid (ADONA)
Perfluoro-4-methoxybutanoic
25.6
28.1
ng/L
110
60 - 150
4
30
acid (PFMBA)
Nonafluoro-3,6-dioxaheptanoic
25.6
28.3
ng/L
110
50 - 150
4
30
acid (NFDHA)
9-Chlorohexadecafluoro-3-oxan
47.8
39.0
ng/L
82
70. 155
5
30
onane-1-sulfonic
acid (9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaund
48.3
34.6
ng/L
72
55-160
8
30
ecane-1-sulfonic acid
(11 CI-PF3OUdS)
Perfluoro (2-ethoxyethane)
22.8
22.1
ng/L
97
70 - 140
4
30
sulfonic acid (PFEESA)
3-Perfluoropropylpropanoic acid
64.0
67.8
ng/L
106
65 - 130
2
30
(3:3 FTCA)
Eurofins Raleigh
Page 75 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LCSD 680-838897/3-A
Client
Sample ID: Lab Control Sample Dup
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 839063
Prep Batch: 838897
Spike
LCSD
LCSD
%Rec RPD
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits RPD Limit
3-Perfluoropentylpropanoic acid
320
278
ng/L
87
70 - 135 1 30
(5:3 FTCA)
3-Perfluoroheptylpropanoic acid
320
242
ng/L
76
50 - 145 1 30
(7:3 FTCA)
Perfluorodecanesulfonic acid
12.3
11.8
ng/L
96
60 - 145 6 30
(PFDS)
Perfluoro-3-methoxypropanoic
25.6
28.9
ng/L
113
55 - 140 3 30
acid (PFMPA)
LCSD LCSD
Isotope Dilution %Recovery Qualifier
Limits
13C4 PFBA
56.3
5 - 130
13C5 PFPeA
59.8
40 - 130
13C5 PFHxA
64.8
40 - 130
13C4 PFHpA
60.3
40 - 130
13CB PFOA
61.6
40 - 130
13C9 PFNA
82.6
40 - 130
13C6 PFDA
56.9
40 - 130
13C7 PFUnA
53.9
30 - 130
13C2 PFDoA
46.5
10 - 130
13C2 PFTeDA
39.7
10 - 130
13C3 PFBS
67.9
40 - 135
13C3 PFHxS
63.1
40 - 130
13C8 PFOS
80.7
40 - 130
13C8 FOSA
60.8
40 - 130
d3-NMeFOSAA
79.4
40 - 170
d5-NEtFOSAA
74.6
25 - 135
M2-4:2 FTS
75.0
40 - 200
M2-6:2 FTS
71.8
40 - 200
M2-8:2 FTS
66.0
40 - 300
13C3 HFPO-DA
69.6
40 - 130
d7-N-McFOSE-M
81.9
10 - 130
d9-N-EtFOSE-M
83.0
10 - 130
d5-NEtPFOSA
89.9
10 - 130
d3-NMePFOSA
72.1
10 - 130
Lab Sample ID: LLCS 680-838897/4-A
Client Sample
ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 839063
Prep Batch: 838897
Spike
LLCS
LLCS
%Rec
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits
Perfluorobutanoic acid (PFBA)
5.12
4.87
ng/L
95
70 - 140
Perfluoropentanoic acid (PFPeA)
2.56
2.67
ng/L
105
65 - 135
Perfluorohexanoic acid (PFHxA)
1.28
1.33
J
ng/L
104
70 - 145
Perfluoroheptanoic acid (PFHpA)
1.28
1.41
J
ng/L
110
70 - 150
Perfluorooctanoic acid (PFOA)
1.28
1.12
J
ng/L
88
70 - 150
Perfluorononanoic acid (PFNA)
1.28
1.29
J
ng/L
101
70 - 150
Perfluorodecanoic acid (PFDA)
1.28
1.70
J
ng/L
133
70 - 140
Perfluoroundecanoic acid
1.28
1.26
J
ng/L
99
70 - 145
(PFUnA)
Eurofins Raleigh
Page 76 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LLCS 680-838897/4-A
Client Sample
ID: Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 839063
Prep Batch: 838897
Spike
LLCS
LLCS
%Rec
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits
Perfluorododecanoic acid
1.28
1.14
J
ng/L
89
70 - 140
(PFDoA)
Perfluorotridecanoic acid
1.28
1.31
J
ng/L
103
65 - 140
(PFTrDA)
Perfluorotetradecanoic acid
1.28
1.19
J
ng/L
93
60 - 140
(PFTA)
Perfluorobutanesulfonic acid
1.13
1.11
J
ng/L
98
60 - 145
(PFBS)
Perfluoropentanesulfonic acid
1.20
1.19
J
ng/L
99
65 - 140
(PFPeS)
Perfluorohexanesulfonic acid
1.17
1.51
J
ng/L
130
65 - 145
(PFHxS)
Perfluoroheptanesulfonic acid
1.22
1.16
J
ng/L
96
70 - 150
(PFHpS)
Perfluorooctanesulfonic acid
1.18
1.20
J
ng/L
101
55 - 150
(PFOS)
Perfluorononanesulfonic acid
1.23
0.895
J
ng/L
73
65 - 145
(PFNS)
Perfluorododecanesulfonic acid
1.24
0.616
J
ng/L
50
50 - 145
(PFDoS)
1 H,1 H,2H,2H-Perfluorohexane
4.80
4.58
ng/L
95
70-145
sulfonic acid (4:2 FTS)
1 H,1 H,2H,2H-Perfluorooctane
4.87
4.73
ng/L
97
65-155
sulfonic acid (6:2 FTS)
1 H,1 H,2H,2H-Perfluorodecane
4.91
4.64
ng/L
94
60-150
sulfonic acid (8:2 FTS)
Perfluorooctanesulfonamide
1.28
1.38
J
ng/L
108
70 - 145
(PFOSA)
N-methylperfluorooctane
1.28
1.58
J
ng/L
124
60 - 150
sulfonamide (NMeFOSA)
N-ethylperfluorooctane
1.28
1.14
J
ng/L
89
65 - 145
sulfonamide (NEtFOSA)
N-methylperfluorooctanesulfona
1.28
1.27
J
ng/L
100
50 - 140
midoacetic acid (NMeFOSAA)
N-ethylperfluorooctanesulfonami
1.28
1.09
J
ng/L
86
70 - 145
doacetic acid (NEtFOSAA)
N-methylperfluorooctane
12.8
10.8
ng/L
85
70 - 145
sulfonamidoethanol (NMeFOSE)
N-ethylperfluorooctane
12.8
12.0
ng/L
94
70 - 135
sulfonamidoethanol (NEtFOSE)
Hexafluoropropylene Oxide
5.12
5.22
ng/L
102
70 - 140
DimerAcid (HFPO-DA)
4,8-Dioxa-3H-perfluorononanoic
4.84
4.86
ng/L
100
65 - 145
acid (ADONA)
Perfluoro-4-methoxybutanoic
2.56
2.66
ng/L
104
60 - 150
acid (PFMBA)
Nonafluoro-3,6-dioxaheptanoic
2.56
2.51
ng/L
98
50 - 150
acid (NFDHA)
9-Chlorohexadecafluoro-3-oxan
4.78
3.15
*-
ng/L
66
70 - 155
onane-1-sulfonic
acid (9CI-PF30NS)
11-Chloroeicosafluoro-3-oxaund
4.83
2.42
*-
ng/L
50
55-160
ecane-1-sulfonic acid
(11 CI-PF3OUdS)
Perfluoro (2-ethoxyethane)
2.28
2.05
ng/L
90
70 - 140
sulfonic acid (PFEESA)
Eurofins Raleigh
Page 77 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
QC Sample Results
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Method: 1633 - Per- and Polyfluoroalkyl Substances by LC/MS/MS (Continued)
Lab Sample ID: LLCS 680-838897/4-A
Matrix: Water
Analysis Batch: 839063
Spike
LLCS LLCS
Analyte
Added
Result Qualifier
Unit
3-Perfluoropropylpropanoic acid
6.40
6.58
ng/L
(3:3 FTCA)
3-Perfluoropentylpropanoic acid
32.0
25.8
ng/L
(5:3 FTCA)
3-Perfluoroheptylpropanoic acid
32.0
22.9
ng/L
(7:3 FTCA)
Perfluorodecanesulfonic acid
1.23
0.905 J
ng/L
(PFDS)
Perfluoro-3-methoxypropanoic
2.56
2.69
ng/L
acid (PFMPA)
LLCS LLCS
Isotope Dilution
%Recovery Qualifier
Limits
13C4 PFBA
65.3
25 - 130
13C5 PFPeA
66.8
40 - 130
13C5 PFHxA
71.3
40 - 130
13C4 PFHpA
69.0
40 - 130
13C8 PFOA
71.1
40 - 130
13C9 PFNA
93.9
40 - 130
13C6 PFDA
66.4
40 - 130
13C7 PFUnA
61.0
30 - 130
13C2 PFDoA
49.0
10 - 130
13C2 PFTeDA
36.6
10 - 130
13C3 PFBS
73.6
40 - 135
13C3 PFHxS
68.6
40 - 130
13C8 PFOS
88.9
40 - 130
13C8 FOSA
68.6
40 - 130
d3-NMeFOSAA
95.0
40 - 170
d5-NEtFOSAA
84.6
25 - 135
M2-4:2 FTS
89.0
40 - 200
M2-6:2 FTS
87.7
40 - 200
M2-8:2 FTS
82.7
40 - 300
13C3 HFPO-DA
79.1
40 - 130
d7-N-McFOSE-M
89.7
10 - 130
d9-N-EtFOSE-M
89.1
10 - 130
d5-NEtPFOSA
92.9
10 - 130
d3-NMePFOSA
77.8
10 - 130
F
Job ID: 752-19362-1
Client Sample ID: Lab Control Sample
Prep Type: Total/NA
Prep Batch: 838897
%Rec
D %Rec
Limits
103
65-130
81
70 - 135
72
50 - 145
73
60 - 145 •
105
55-140
Eurofins Raleigh
Page 78 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
QC Association Summary
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
LCMS
Job ID: 752-19362-1
Prep Batch: 837934
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method Prep Batch
752-19362-1
MW-7
Total/NA
Water
1633
752-19362-2
MW-6
Total/NA
Water
1633
752-19362-3
MW-12S
Total/NA
Water
1633
752-19362-4
MW-13
Total/NA
Water
1633
752-19362-5
MW-23
Total/NA
Water
1633
752-19362-6
MW-19
Total/NA
Water
1633
752-19362-7
MW-22
Total/NA
Water
1633
752-19362-8
MW-17
Total/NA
Water
1633
752-19362-9
MW-3R
Total/NA
Water
1633
752-19362-10
SW4
Total/NA
Water
1633
752-19362-11
MW-20
Total/NA
Water
1633
752-19362-12
MW-21
Total/NA
Water
1633
752-19362-13
SW-1
Total/NA
Water
1633
752-19362-14
MW-9
Total/NA
Water
1633
752-19362-15
SW-2
Total/NA
Water
1633
752-19362-20
WSW-2
Total/NA
Water
1633
MB 680-837934/1-A
Method Blank
Total/NA
Water
1633
-CS 680-837934/2-A
Lab Control Sample
Total/NA
Water
1633
LCSD 680-837934/3-A
Lab Control Sample Dup
Total/NA
Water
1633
LLCS 680-837934/4-A
Lab Control Sample
Total/NA
Water
1633
Analysis Batch: 838185
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
752-19362-1
MW-7
Total/NA
Water
1633
837934
752-19362-2
MW-6
Total/NA
Water
1633
837934
752-19362-3
MW-12S
Total/NA
Water
1633
837934
752-19362-4
MW-13
Total/NA
Water
1633
837934
752-19362-5
MW-23
Total/NA
Water
1633
837934
752-19362-6
MW-19
Total/NA
Water
1633
837934
752-19362-7
MW-22
Total/NA
Water
1633
837934
752-19362-8
MW-17
Total/NA
Water
1633
837934
752-19362-9
MW-3R
Total/NA
Water
1633
837934
752-19362-10
SW-4
Total/NA
Water
1633
837934
752-19362-11
MW-20
Total/NA
Water
1633
837934
752-19362-12
MW-21
Total/NA
Water
1633
837934
752-19362-13
SW-1
Total/NA
Water
1633
837934
752-19362-14
MW-9
Total/NA
Water
1633
837934
752-19362-15
SW-2
Total/NA
Water
1633
837934
752-19362-20
WSW-2
Total/NA
Water
1633
837934
MB 680-837934/1-A
Method Blank
Total/NA
Water
1633
837934
LCS 680-837934/2-A
Lab Control Sample
Total/NA
Water
1633
837934
LCSD 680-837934/3-A
Lab Control Sample Dup
Total/NA
Water
1633
837934
LLCS 680-837934/4-A
Lab Control Sample
Total/NA
Water
1633
837934
Prep Batch: 838358
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
752-19362-16
WW-1
Total/NA
Water
1633
752-19362-17
MW-11
Total/NA
Water
1633
752-19362-21
Field Blank
Total/NA
Water
1633
752-19362-23
MW-14
Total/NA
Water
1633
MB 680-838358/1-A
Method Blank
Total/NA
Water
1633
E
Eurofins Raleigh
Page 79 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
QC Association Summary
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
LCMS (Continued)
Prep Batch: 838358 (Continued)
Lab Sample ID
Client Sample ID
LCS 680-838358/2-A
Lab Control Sample
LCSD 680-838358/3-A
Lab Control Sample Dup
LLCS 680-838358/4-A
Lab Control Sample
Analysis Batch: 838415
Lab Sample ID
Client Sample ID
752-19362-16
MW-1
752-19362-17
MW-11
752-19362-21
Field Blank
752-19362-23
MW-14
MB 680-838358/1-A
Method Blank
LCS 680-838358/2-A
Lab Control Sample
LCSD 680-838358/3-A
Lab Control Sample Dup
LLCS 680-838358/4-A
Lab Control Sample
Prep Batch: 838897
Lab Sample ID
Client Sample ID
752-19362-1
MW-7
752-19362-2
MW-6
752-19362-3
MW-12S
752-19362-8
MW-17
752-19362-10
SW4
MB 680-838897/1-A
Method Blank
LCS 680-838897/2-A
Lab Control Sample
LCSD 680-838897/3-A
Lab Control Sample Dup
LLCS 680-838897/4-A
Lab Control Sample
Analysis Batch: 839063
FLab Sample ID
752-19362-1
752-19362-2
752-19362-3
752-19362-8
752-19362-10
MB 680-838897/1-A
LCS 680-838897/2-A
LCSD 680-838897/3-A
LLCS 680-838897/4-A
Job ID: 752-19362-1
Prep Type
Matrix
Method
Prep Batch
Total/NA
Water
1633
Total/NA
Water
1633
Total/NA
Water
1633
Prep Type
Matrix
Method
Prep Batch
Total/NA
Water
1633
838358
Total/NA
Water
1633
838358
Total/NA
Water
1633
838358
Total/NA
Water
1633
838358
Total/NA
Water
1633
838358
Total/NA
Water
1633
838358
Total/NA
Water
1633
838358
Total/NA
Water
1633
838358
Prep Type
Matrix
Method
Prep Batch
Total/NA
Water
1633
Total/NA
Water
1633
Total/NA
Water
1633
Total/NA
Water
1633
Total/NA
Water
1633
Total/NA
Water
1633
Total/NA
Water
1633
Total/NA
Water
1633
Total/NA
Water
1633
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
MW-7
Total/NA
Water
1633
838897
MW-6
Total/NA
Water
1633
838897
MW-12S
Total/NA
Water
1633
838897
MW-17
Total/NA
Water
1633
838897
SW4
Total/NA
Water
1633
838897
Method Blank
Total/NA
Water
1633
838897
Lab Control Sample
Total/NA
Water
1633
838897
Lab Control Sample Dup
Total/NA
Water
1633
838897
Lab Control Sample
Total/NA
Water
1633
838897
Page 80 of 92
Eurofins Raleigh
5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Lab Chronicle
F
Client: Smith Gardner Inc
Job ID: 752-19362-1
Project/Site: Surry C&D/MSW (Permit 8602)
Client Sample ID: MW-7
Lab Sample ID: 752-19362-1
Date Collected: 04/29/24 13:45
Matrix: Water
Date Received: 05/03/24 09:50
Batch
Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type
Method
Run
Factor
Amount
Amount
Number
or Analyzed
Analyst Lab
Total/NA Prep
1633
176.4 mL
5 mL
837934
05/14/24 13:53
NG EET SAV
Total/NA Analysis
1633
1
1 mL
1 mL
838185
05/15/24 19:50
SW EET SAV
Total/NA Prep
1633
182.4 mL
5 mL
838897
05/20/24 14:57
NG EET SAV
Total/NA Analysis
1633
1
1 mL
1 mL
839063
05/21/24 15:43
SW EET SAV
Client Sample ID: MW-6
Lab Sample ID: 752-19362-2
F
Date Collected: 04/29/24 14:00
Matrix: Water
Date Received: 05/03/24 09:50
F
Batch
Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type
Method
Run
Factor
Amount
Amount
Number
or Analyzed
Analyst Lab
ED
Total/NA Prep
1633
135.2 mL
5 mL
837934
05/14/24 13:53
NG EET SAV
Total/NA Analysis
1633
1
1 mL
1 mL
838185
05/15/24 20:05
SW EET SAV
Total/NA Prep
1633
180.2 mL
5 mL
838897
05/20/24 14:57
NG EET SAV
Total/NA Analysis
1633
1
1 mL
1 mL
839063
05/21/24 15:58
SW EET SAV
Client Sample ID: MW-12S
Lab Sample ID: 752-19362-3
Date Collected: 04/29/24 14:15
Matrix: Water
L
Date Received: 05/03/24 09:50
Batch
Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type
Method
Run
Factor
Amount
Amount
Number
or Analyzed
Analyst Lab
Total/NA Prep
1633
176.3 mL
5 mL
837934
05/14/24 13:53
NG EET SAV
Total/NA Analysis
1633
1
1 mL
1 mL
838185
05/15/24 20:21
SW EET SAV
Total/NA Prep
1633
180.9 mL
5 mL
838897
05/20/24 14:57
NG EET SAV
Total/NA Analysis
1633
1
1 mL
1 mL
839063
05/21/24 16:14
SW EET SAV
Client Sample ID: MW-13
Lab Sample ID: 752-19362-4
Date Collected: 04/29/24 14:30
Matrix: Water
Date Received: 05/03/24 09:50
Batch
Batch
oil
Initial
Final
Batch
Prepared
Prep Type Type
Method
Run
Factor
Amount
Amount
Number
or Analyzed
Analyst Lab
Total/NA Prep
1633
178.7 mL
5 mL
837934
05/14/24 13:53
NG EET SAV
Total/NA Analysis
1633
1
1 mL
1 mL
838185
05/15/24 20:36
SW EET SAV
Client Sample ID: MW-23
Lab Sample ID: 752-19362-5
Date Collected: 04/29/24 14:45
Matrix: Water
Date Received: 05/03/24 09:50
Batch
Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type
Method
Run
Factor
Amount
Amount
Number
or Analyzed
Analyst Lab
Total/NA Prep
1633
13.2046 mL
5 mL
837934
05/14/24 13:53
NG EET SAV
Total/NA Analysis
1633
1
1 mL
1 mL
838185
05/15/24 20:51
SW EET SAV
Page 81 of 92
Eurofins Raleigh
5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-lB8535D719AE
Lab Chronicle
C
Client: Smith Gardner Inc
Job ID: 752-19362-1
Project/Site: Surry C&D/MSW (Permit
8602)
Client Sample ID: MW-19
Lab Sample ID: 752-19362-6
Date Collected: 04/29/24 15:00
Matrix: Water
Date Received: 05/03/24 09:50
Batch
Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type
Method
Run
Factor
Amount
Amount
Number
or Analyzed Analyst Lab
Total/NA Prep
1633
61.1782 mL
5 mL
837934
05/14/24 13:53 NG EET SAV
Total/NA Analysis
1633
1
1 mL
1 mL
838185
05/15/24 21:07 SW EET SAV
Client Sample ID: MW-22
Lab Sample ID: 752-19362-7
Date Collected: 04/29/24 15:15
Matrix: Water
Date Received: 05/03/24 09:50
Batch
Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type
Method
Run
Factor
Amount
Amount
Number
or Analyzed Analyst Lab
Total/NA Prep
1633
177.1 mL
5 mL
837934
05/14/24 13:53 NG EET SAV
Total/NA Analysis
1633
1
1 mL
1 mL
838185
05/15/24 21:22 SW EET SAV
m
Client Sample ID: MW-17
Lab Sample ID: 752-19362-8
Date Collected: 04/29/24 15:30
Matrix: Water
Date Received: 05/03/24 09:50
Batch
Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type
Method
Run
Factor
Amount
Amount
Number
or Analyzed Analyst Lab
Total/NA Prep
1633
183.9 mL
5 mL
837934
05/14/24 13:53 NG EET SAV
Total/NA Analysis
1633
1
1 mL
1 mL
838185
05/15/24 21:37 SW EET SAV
Total/NA Prep
1633
182.6 mL
5 mL
838897
05/20/24 14:57 NG EET SAV
Total/NA Analysis
1633
1
1 mL
1 mL
839063
05/21/24 16:29 SW EET SAV
Client Sample ID: MW-3R
Lab Sample ID: 752-19362-9
Date Collected: 04/29/24 15:45
Matrix: Water
Date Received: 05/03/24 09:50
Batch
Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type
Method
Run
Factor
Amount
Amount
Number
or Analyzed Analyst Lab
Total/NA Prep
1633
12.4050 mL
5 mL
837934
05/14/24 13:53 NG EET SAV
Total/NA Analysis
1633
1
1 mL
1 mL
838185
05/15/24 22:24 SW EET SAV
Client Sample ID: SW-4
Lab Sample ID: 752-19362-10
Date Collected: 04/29/24 16:15
Matrix: Water
Date Received: 05/03/24 09:50
F
Batch
Batch
oil
Initial
Final
Batch
Prepared
Prep Type Type
Method
Run
Factor
Amount
Amount
Number
or Analyzed Analyst Lab
Total/NA Prep
1633
175.7 mL
5 mL
837934
05/14/24 13:53 NG EET SAV
Total/NA Analysis
1633
1
1 mL
1 mL
838185
05/15/24 22:39 SW EET SAV
Total/NA Prep
1633
179 mL
5 mL
838897
05/20/24 14:57 NG EET SAV
Total/NA Analysis
1633
1
1 mL
1 mL
839063
05/21/24 16:45 SW EET SAV
Client Sample ID: MW-20
Lab Sample ID: 752-19362-11
Date Collected: 04/29/24 16:00
Matrix: Water
Date Received: 05/03/24 09:50
Batch
Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type
Method
Run
Factor
Amount
Amount
Number
or Analyzed Analyst Lab
Total/NA Prep
1633
61.8507 mL
5 mL
837934
05/14/24 13:53 NG EET SAV
Total/NA Analysis
1633
1
1 mL
1 mL
838185
05/15/24 22:54 SW EET SAV
Page 82 of 92
Eurofins Raleigh
5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Lab Chronicle
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Client Sample ID: MW-21
Date Collected: 05/01/24 15:45
Date Received: 05/03/24 09:50
F
Job ID: 752-19362-1
Lab Sample ID: 752-19362-12
Matrix: Water
Batch
Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type
Method
Run
Factor
Amount
Amount
Number
or Analyzed Analyst Lab
Total/NA Prep
1633
177 mL
5 mL
837934
05/14/24 13:53 NG EET SAV
Total/NA Analysis
1633
1
1 mL
1 mL
838185
05/15/24 23:10 SW EET SAV
Client Sample ID: SW-1
Lab Sample ID: 752-19362-13
Date Collected: 05/01/24 12:30
Matrix: Water
Date Received: 05/03/24 09:50
Batch
Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type
Method
Run
Factor
Amount
Amount
Number
or Analyzed Analyst Lab
Total/NA Prep
1633
172.6 mL
5 mL
837934
05/14/24 13:53 NG EET SAV
Total/NA Analysis
1633
1
1 mL
1 mL
838185
05/15/24 23:25 SW EET SAV
m
Client Sample ID: MW-9
Lab Sample ID: 752-19362-14
Date Collected: 05/02/24 11:00
Matrix: Water
Date Received: 05/03/24 09:50
Batch
Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type
Method
Run
Factor
Amount
Amount
Number
or Analyzed Analyst Lab
Total/NA Prep
1633
62.4580 mL
5 mL
837934
05/14/24 13:53 NG EET SAV
Total/NA Analysis 1633 1 1 mL 1 mL 838185
05/15/24 23:40 SW EET SAV
Client Sample ID: SW-2
Lab Sample ID: 752-19362-15
Date Collected: 05/02/24 10:15
Matrix: Water
Date Received: 05/03/24 09:50
Batch
Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type
Method
Run
Factor
Amount
Amount
Number
or Analyzed Analyst Lab
Total/NA Prep
1633
143.7 mL
5 mL
837934
05/14/24 13:53 NG EET SAV
Total/NA Analysis
1633
1
1 mL
1 mL
838185
05/15/24 23:56 SW EET SAV
Client Sample ID: MW-1
Lab Sample ID: 752-19362-16
Date Collected: 05/02/24 12:30
Matrix: Water
Date Received: 05/03/24 09:50
Batch
Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type
Method
Run
Factor
Amount
Amount
Number
or Analyzed Analyst Lab
Total/NA Prep
1633
184.2 mL
5 mL
838358
05/16/24 11:26 EO EET SAV
Total/NA Analysis
1633
1
1 mL
1 mL
838415
05/16/24 17:50 SW EET SAV
Client Sample ID: MW-11
Lab Sample ID: 752-19362-17
Date Collected: 05/02/24 13:30
Matrix: Water
Date Received: 05/03/24 09:50
Batch
Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type
Method
Run
Factor
Amount
Amount
Number
or Analyzed Analyst Lab
Total/NA Prep
1633
175.9 mL
5 mL
838358
05/16/24 11:26 EO EET SAV
Total/NA Analysis
1633
1
1 mL
1 mL
838415
05/16/24 18:06 SW EET SAV
Page 83 of 92
Eurofins Raleigh
5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Lab Chronicle
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Client Sample ID: WSW-2
Lab Sample ID: 752-19362-20
Date Collected: 05/01/24 17:00
Matrix: Water
Date Received: 05/03/24 09:50
Batch
Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type
Method
Run Factor
Amount
Amount
Number
or Analyzed Analyst Lab
Total/NA Prep
1633
173.9 mL
5 mL
837934
05/14/24 13:53 NG EET SAV
Total/NA Analysis
1633
1
1 mL
1 mL
838185
05/16/24 00:11 SW EET SAV
Client Sample ID: Field Blank
Lab Sample ID: 752-19362-21
Date Collected: 05/02/24 12:30
Matrix: Water
Date Received: 05/03/24 09:50
Batch
Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type
Method
Run Factor
Amount
Amount
Number
or Analyzed Analyst Lab
Total/NA Prep
1633
172 mL
5 mL
838358
05/16/24 11:26 EO EET SAV
Total/NA Analysis
1633
1
1 mL
1 mL
838415
05/16/24 18:21 SW EET SAV
m
Client Sample ID: MW-14
Lab Sample ID: 752-19362-23
Date Collected: 05/02/24 14:30
Matrix: Water
Date Received: 05/03/24 09:50
Batch
Batch
Dil Initial
Prep Type
Type
Method
Run Factor Amount
Total/NA
Prep
1633
160.9 mL
Total/NA
Analysis
1633
1 1 mL
Laboratory References:
EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL (912)354-7858
Final
Batch
Prepared
Amount
Number
or Analyzed
Analyst Lab
5 mL
838358
05/16/24 11:26
EO EET SAV
1 mL
838415
05/16/24 18:36
SW EET SAV
Page 84 of 92
Eurofins Raleigh
5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Accreditation/Certification Summary
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
Laboratory: Eurofins Savannah
Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.
Authority
Program
Identification Number Expiration Date
North Carolina (WW/SW)
State
269 12-31-24
The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes
for which the agency does not offer certification.
Analysis Method
Prep Method
Matrix
Analyte
1633
1633
Water
11-Chloroeicosafluoro-3-oxaundecane-1-s
ulfonic acid (11Cl-PF30UdS)
1633
1633
Water
1 H,1 H,2H,2H-Perfluorodecane sulfonic
acid (8:2 FTS)
1633
1633
Water
1 H,1 H,2H,2H-Perfluorohexane sulfonic
acid (4:2 FTS)
1633
1633
Water
1 H,1 H,2H,2H-Perfluorooctane sulfonic acid
(6:2 FTS)
1633
1633
Water
3-Perfluoroheptylpropanoic acid (7:3
FTCA)
1633
1633
Water
3-Perfluoropentylpropanoic acid (5:3
FTCA)
1633
1633
Water
3-Perfluoropropylpropanoic acid (3:3
FTCA)
1633
1633
Water
4,8-Dioxa-3H-perfluorononanoic acid
(ADONA)
1633
1633
Water
9-Chlorohexadecafluoro-3-oxanonane-1-s
ulfonic acid(9CI-PF30NS)
1633
1633
Water
Hexafluoropropylene Oxide Dimer Acid
(HFPO-DA)
1633
1633
Water
N-ethylperfluorooctane sulfonamide
(NEtFOSA)
1633
1633
Water
N-ethylperfluorooctane sulfonamidoethanol
(NEtFOSE)
1633
1633
Water
N-ethylperfluorooctanesulfonamidoacetic
acid (NEtFOSAA)
1633
1633
Water
N-methylperfluorooctane sulfonamide
(NMeFOSA)
1633
1633
Water
N-methylperfluorooctane
sulfonamidoethanol (NMeFOSE)
1633
1633
Water
N-methylperfluorooctanesulfonamidoacetic
acid (NMeFOSAA)
1633
1633
Water
Nonafluoro-3,6-dioxaheptanoic acid
(NFDHA)
1633
1633
Water
Perfluoro (2-ethoxyethane) sulfonic acid
(PFEESA)
1633
1633
Water
Perfluoro-3-methoxypropanoic acid
(PFMPA)
1633
1633
Water
Perfluoro-4-methoxybutanoic acid
(PFMBA)
1633
1633
Water
Perfluorobutanesulfonic acid (PFBS)
1633
1633
Water
Perfluorobutanoic acid (PFBA)
1633
1633
Water
Perfluorodecanesulfonic acid (PFDS)
1633
1633
Water
Perfluorodecanoic acid (PFDA)
1633
1633
Water
Perfluorododecanesulfonic acid (PFDoS)
1633
1633
Water
Perfluorododecanoic acid (PFDoA)
1633
1633
Water
Perfluoroheptanesulfonic acid (PFHpS)
1633
1633
Water
Perfluoroheptanoic acid (PFHpA)
1633
1633
Water
Perfluorohexanesulfonic acid (PFHxS)
1633
1633
Water
Perfluorohexanoic acid (PFHxA)
F
Job ID: 752-19362-1
Eurofins Raleigh
Page 85 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Accreditation/Certification Summary C
Client: Smith Gardner Inc Job ID: 752-19362-1
Project/Site: Surry C&D/MSW (Permit 8602)
Laboratory: Eurofins Savannah (Continued)
Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.
Authority Program Identification Number Expiration Date
The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes
for which the agency does not offer certification.
Analysis Method
Prep Method
Matrix
Analyte
1633
1633
Water
Perfluorononanesulfonic acid (PFNS)
1633
1633
Water
Perfluorononanoic acid (PFNA)
1633
1633
Water
Perfluorooctanesulfonamide (PFOSA)
1633
1633
Water
Perfluorooctanesulfonic acid (PFOS)
1633
1633
Water
Perfluorooctanoic acid (PFOA)
1633
1633
Water
Perfluoropentanesulfonic acid (PFPeS)
1633
1633
Water
Perfluoropentanoic acid (PFPeA)
1633
1633
Water
Perfluorotetradecanoic acid (PFTA)
1633
1633
Water
Perfluorotridecanoic acid (PFTrDA)
1633
1633
Water
Perfluoroundecanoic acid (PFUnA)
Eurofins Raleigh
Page 86 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Method Summary
Client: Smith Gardner Inc
Project/Site: Surry C&D/MSW (Permit 8602)
F
Job ID: 752-19362-1
Method
Method Description
Protocol
Laboratory
1633
1633
Per- and Polyfluoroalkyl Substances by LC/MS/MS
Solid -Phase Extraction (SPE)
EPA
EPA
EET SAV
EET SAV
Protocol References:
EPA = US Environmental Protection Agency
Laboratory References:
EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL (912)354-7858
Eurofins Raleigh
Page 87 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Sample Summary
Client: Smith Gardner Inc Job ID: 752-19362-1
Project/Site: Surry C&D/MSW (Permit 8602)
Lab Sample ID
Client Sample ID
Matrix
Collected
Received
752-19362-1
MW-7
Water
04/29/24 13:45
05/03/24 09:50
752-19362-2
MW-6
Water
04/29/24 14:00
05/03/24 09:50
752-19362-3
MW-12S
Water
04/29/24 14:15
05/03/24 09:50
752-19362-4
MW-13
Water
04/29/24 14:30
05/03/24 09:50
752-19362-5
MW-23
Water
04/29/24 14:45
05/03/24 09:50
752-19362-6
MW-19
Water
04/29/24 15:00
05/03/24 09:50
752-19362-7
MW-22
Water
04/29/24 15:15
05/03/24 09:50
752-19362-8
MW-17
Water
04/29/24 15:30
05/03/24 09:50
752-19362-9
MW-3R
Water
04/29/24 15:45
05/03/24 09:50
752-19362-10
SW-4
Water
04/29/24 16:15
05/03/24 09:50
752-19362-11
MW-20
Water
04/29/24 16:00
05/03/24 09:50
752-19362-12
MW-21
Water
05/01/24 15:45
05/03/24 09:50
752-19362-13
SW-1
Water
05/01/24 12:30
05/03/24 09:50
752-19362-14
MW-9
Water
05/02/24 11:00
05/03/24 09:50
752-19362-15
SW-2
Water
05/02/24 10:15
05/03/24 09:50
752-19362-16
MW-1
Water
05/02/24 12:30
05/03/24 09:50
752-19362-17
MW-11
Water
05/02/24 13:30
05/03/24 09:50
752-19362-20
WSW-2
Water
05/01/24 17:00
05/03/24 09:50
752-19362-21
Field Blank
Water
05/02/24 12:30
05/03/24 09:50
752-19362-23
MW-14
Water
05/02/24 14:30
05/03/24 09:50
Eurofins Raleigh
Page 88 of 92 5/22/20 g4
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
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Page 90 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client: Smith Gardner Inc
Login Number: 19362
List Number: 1
Creator: Yonish, Rachel
Question
Login Sample Receipt Checklist
Answer Comment
Radioactivity wasn't checked or is </= background as measured by a survey
N/A
meter.
The cooler's custody seal, if present, is intact.
True
Sample custody seals, if present, are intact.
True
The cooler or samples do not appear to have been compromised or
True
tampered with.
Samples were received on ice.
True
Cooler Temperature is acceptable.
True
Cooler Temperature is recorded.
True
COC is present.
True
COC is filled out in ink and legible.
True
COC is filled out with all pertinent information.
True
Is the Field Sampler's name present on COC?
True
There are no discrepancies between the containers received and the COC.
True
Samples are received within Holding Time (excluding tests with immediate
True
HTs)
Sample containers have legible labels.
True
Containers are not broken or leaking.
True
Sample collection date/times are provided.
True
Appropriate sample containers are used.
True
Sample bottles are completely filled.
True
Sample Preservation Verified.
N/A
There is sufficient vol. for all requested analyses, incl. any requested
True
MS/MSDs
Containers requiring zero headspace have no headspace or bubble is
N/A
<6mm (1/4").
Multiphasic samples are not present.
True
Samples do not require splitting or compositing.
True
Residual Chlorine Checked.
N/A
Job Number: 752-19362-1
List Source: Eurofins Raleigh
L
Eurofins Raleigh
Page 91 of 92 5/22/2024
Docusign Envelope ID: 889599EA-C817-4865-93DD-1B8535D719AE
Client: Smith Gardner Inc
Login Number: 19362
List Number: 2
Creator: Watters, David
Question
Login Sample Receipt Checklist
Answer Comment
Radioactivity wasn't checked or is </= background as measured by a survey
N/A
meter.
The cooler's custody seal, if present, is intact.
True
Sample custody seals, if present, are intact.
True
The cooler or samples do not appear to have been compromised or
True
tampered with.
Samples were received on ice.
True
Cooler Temperature is acceptable.
True
Cooler Temperature is recorded.
True
COC is present.
True
COC is filled out in ink and legible.
True
COC is filled out with all pertinent information.
True
Is the Field Sampler's name present on COC?
N/A
There are no discrepancies between the containers received and the COC.
True
Samples are received within Holding Time (excluding tests with immediate
True
HTs)
Sample containers have legible labels.
True
Containers are not broken or leaking.
True
Sample collection date/times are provided.
True
Appropriate sample containers are used.
True
Sample bottles are completely filled.
True
Sample Preservation Verified.
N/A
There is sufficient vol. for all requested analyses, incl. any requested
True
MS/MSDs
Containers requiring zero headspace have no headspace or bubble is
N/A
<6mm (1/4").
Multiphasic samples are not present.
True
Samples do not require splitting or compositing.
True
Residual Chlorine Checked.
N/A
Job Number: 752-19362-1
List Source: Eurofins Savannah
List Creation: 05/04/24 11:23 AM
Eurofins Raleigh
Page 92 of 92 5/22/2024