HomeMy WebLinkAbout2024.06.27_CCOA.p2.c.v_LT Remedy PMP Report No 5_Q1 2024Geosyntec
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CFR Long -Term Remedy Performance
Monitoring Report #5
January — March 2024
Chemours Fayetteville Works
Prepared for
The Chemours Company FC, LLC
22828 NC Highway 87
Fayetteville, NC 28306
Prepared by
Geosyntec Consultants of NC P.C.
2501 Blue Ridge Road, Suite 430
Raleigh, NC 27607
Project Number TR0795
June 27, 2024
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Geosyntec Consultants of NC, P.C.
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EXECUTIVE SUMMARY
This CFR Long -Term Remedy Performance Monitoring Report #5 ("Report") has been prepared
for the Q1 2024 period of January 1 through March 31, 2024 and documents the operation of the
interim seep Flow -Through Cells (FTCs), the ex -situ seeps and weeps capture systems ("Ex -Situ
Capture Systems"), the groundwater extraction and conveyance system (GWEC), and the
groundwater treatment plant (GWTP). The table below summarizes the flow capture in millions
of gallons (MG) and the per- and polyfluoroalkyl substances (PFAS) removal (Table 3+ [17
compounds]) in pounds (lbs) for each remedy element.
Report Period (Jan — Mar 2024)
Cumulative through Mar 2024*
Remedy Element
Flow Captured/
Mass Removed
Flow Captured/
Mass Removed
Treated (MG)
(lbs)
Treated (MG)
(lbs)
Interim FTCs
10.1
3.0
428.4
551.1
004 Treatment Plant
47.8
50.5
245.0
302.9
Ex -Situ Capture
5.9
Included in 004
17.4
Included in 004
Systems
GWEC
44.4
Included in 004
233.3
Included in 004
Total**
57.9
53.5
673.4
854.0
(Interim FTCs + 004)
*Cumulative values reflect the lifetime operation of each remedy component (e.g., since
December 2020 for Interim FTC Seep Q.
**Differences inflow totals are attributable to the measurement resolution offlow meters on the
different remedy systems as well as storage time in the surge pond, break tank, and other
components. The calculated total influent of the Ex -Situ Capture Systems and GWEC system
above is 50.3 MG for Q1 2024. The total influent as measured by Veolia's flow meter was 49.1
MG. The total effluent as measured by Veolia's flow meter was 47.8 MG as shown.
Flow into the interim FTCs has decreased significantly since the completion of the barrier wall
and implementation of the Ex -Situ Capture Systems and GWEC system. Between July 2021 and
June 2023, the interim FTCs collectively processed 14.8 MG per month on average. Between July
2023 and March 2024, the average monthly volume was 2.6 MG. Batch mode processing has been
necessary in order to maintain treatment efficiency at the reduced flow rates. During dry weather,
with the FTCs offline, the impoundment elevations at the FTCs either remain stagnant or decrease,
indicating that the long-term remedy components have eliminated the seep baseflow. As the FTCs
now treat predominately rainwater mixed with stagnant residual groundwater, the concentration of
PFAS in the influent has also decreased. Between July 2021 and June 2023, the average influent
PFAS concentration (Total Table 3+, 17 compounds) across the four FTCs was approximately
150,300 ng/L; between July 2023 and March 2024, it was 35,200 ng/L. Overall, the combination
of significantly reduced flow and concentration has resulted in a mass discharge into the FTCs that
TR0795 — CFR Long -Term Remedy Performance Monitoring Report #5 ES-1 June 2024
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is approximately 96% reduced from baseline conditions, and an asymptotic PFAS mass removal
trend.
The GWEC system has been operating at a steady-state cumulative extraction rate since
approximately September 2023, after the extraction well startup in March 2023 resulted in initial
declines in the Black Creek aquifer water levels. The average pumping rate in Q1 2024 was 337
gallons per minute. The Ex -Situ Capture systems flow trends are dependent on weather conditions
and are therefore more variable. The 004 GWTP removed greater than 99% of PFAS 1 from the
combined flow of the GWEC and Ex -Situ Capture Systems.
Performance monitoring activities, including hydraulic head monitoring and surface water
sampling, are also documented in this Report. Similar to the previous reporting period,
performance monitoring indicates that the GWEC system has resulted in a reduction in gradient
between the barrier wall and the Cape Fear River, thus reducing groundwater PFAS flux to the
Cape Fear River. This reduction in HAS mass discharge is evident in the diminished flows into
the FTCs and is also documented in a report for the Mass Loading Model (MLM) program,
submitted for the same reporting period concurrent to this Report (Geosyntec, 2024a).
Collectively, the Willis Creek EWs are exerting drawdown of the Black Creek aquifer along the
length of the alignment, particularly in the midsection, with nearly 8 feet of groundwater elevation
reduction observed in monitoring wells. Drawdown along the alignment has also resulted in four
EWs with insufficient water to pump, as compared to startup, demonstrating overlapping influence
within the EWs from the collective pumping. The extensive drawdown is a line of evidence of
hydraulic control. Additionally, a reduction in Willis Creek mass discharges has been observed.
At sampling locations WC-2 (upstream) and WC-1 (downstream near the confluence with the Cape
Fear River), the post -startup mass discharge to Willis Creek along this reach is estimated to be
approximately 60% less than pre -startup.
' As measured by indicator parameters hexafluoropropylene oxide dimer (HFPO-DA), perfluoromethoxypropyl
carboxylic acid (PMPA), and perfluoro-2-methoxyaceticacid (PFMOAA)
TR0795 — CFR Long -Term Remedy Performance Monitoring Report #5 ES-2 June 2024
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TABLE OF CONTENTS
EXECUTIVE SUMMARY.......................................................................................................ES-1
1 INTRODUCTION..................................................................................................................1
1.1
Data Validation............................................................................................................1
1.2
Laboratory Analyses....................................................................................................2
2 IN -SITU SEEP FLOW -THROUGH CELLS.........................................................................4
2.1
Inspections, Operation, and Maintenance....................................................................4
2.1.1 Inspections....................................................................................................4
2.1.2 Duty Cycling.................................................................................................4
2.1.3 FTC Management During River Flooding....................................................4
2.1.4 Material Changeouts.....................................................................................5
2.1.5 Issue Resolution and System Optimization..................................................5
2.2
Data Collected..............................................................................................................5
2.3
Results..........................................................................................................................6
2.3.1 System Flowrates and Operational Periods..................................................7
2.3.2 Performance Monitoring Analytical Results.................................................8
2.3.3 System Effectiveness....................................................................................9
2.3.4 River Elevation and Precipitation.................................................................9
2.3.5 Water Quality................................................................................................9
3 EX -SITU SEEPS AND WEEPS CAPTURE.......................................................................11
3.1
Operation and Maintenance.......................................................................................11
3.2
Data Collected............................................................................................................11
3.3
Results........................................................................................................................11
4 GROUNDWATER EXTRACTION AND CONVEYANCE..............................................12
4.1
Operation and Maintenance.......................................................................................12
4.2
Data Collected............................................................................................................12
4.2.1 Extraction Well Operational Data...............................................................12
4.2.2 PFAS Data...................................................................................................12
4.3
Results........................................................................................................................13
4.3.1 Groundwater Extraction..............................................................................13
5 004
TREATMENT PLANT.................................................................................................14
5.1
Data Collected............................................................................................................14
5.1.1 Flow Rates...................................................................................................14
5.1.2 PFAS Influent and Effluent.........................................................................14
5.2
Results........................................................................................................................14
5.2.1 Flow Rates...................................................................................................14
TR0795 — CFR Long -Term Remedy Performance Monitoring Report #5 i June 2024
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5.2.2
Analytical Results.......................................................................................15
5.2.3
PFAS Mass Removal..................................................................................15
6 PERFORMANCE MONITORING EVALUATION...........................................................16
6.1 Data Collected
............................................................................................................16
6.1.1
Hydraulic Head and Surface Water Elevation............................................16
6.1.2
PFAS Concentrations in Groundwater and Surface Water
.........................16
6.1.3
Passive Flux Meters....................................................................................17
6.2 Results........................................................................................................................18
6.2.1
Hydraulic Head and Surface Water Elevation............................................18
6.2.2
PFAS Concentrations and Mass Discharge in Groundwater and Surface
Water...........................................................................................................22
7 SUMMARY.........................................................................................................................24
8 REFERENCES
.....................................................................................................................26
LIST OF TABLES
Table 1-1 Summary of Sampling and Monitoring Activities
Table 2-1A-D FTC Operations and Maintenance Summary
Table 2-2 Cape Fear River Elevation and Local Precipitation Statistics
Table 2-3A-D FTC Sampling Summary
Table 2-4A-D FTC Performance Monitoring Analytical Results
Table 2-5A-D FTC Water Quality Data
Table 3-1 Ex -Situ Seeps and Weeps Flow Data
Table 4-1 Extraction and Observation Well Construction Details
Table 4-2 Summary of GWEC Flow Data
Table 4-3 Extraction Well Flow Data
Table 5-1 004 Treatment Plant Flow Data
Table 5-2 004 Treatment Plant PFAS Analytical Results
Table 6-1 Summary of Groundwater Level Information
Table 6-2 PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Table 6-3 Willis Creek PFAS Analytical Results
TR0795 — CFR Long -Term Remedy Performance Monitoring Report #5 ll June 2024
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Table 6-4 Willis Creek PFAS Mass Discharge
LIST OF FIGURES
Figure 1-1 Remedy Layout Overview
Figure 2-IA-D River Level During Reporting Period & FTC As -Built Elevations
Figure 2-2A-D FTC Discharge Flowrate (Jan — Mar 2024)
Figure 2-3 FTC Monthly Total Discharge Volumes (July 2021 — March 2024)
Figure 24A-D FTC Influent Water Elevation (Jan — Mar 2024)
Figure 2-5A-D FTC Staff Gauge Water Elevation (Jan — Mar 2024)
Figure 2-6 FTC Influent PFAS Concentrations
Figure 2-7 FTC Mass Removal Curve (July 2021 — March 2024)
Figure 6-1 Hydraulic Head Evaluation Network for Groundwater Remedy
Figure 6-2A-D Southern Alignment — Downgradient Groundwater Transects
Figure 6-3A-C Southern Alignment — Dampening Analysis Transects
Figure 64A-C Willis Creek Extraction Well Flood Response
Figure 6-5A-C Northern Alignment — January 2023 — January/February/March 2024
Elevation Difference
Figure 6-6A-C Northern Alignment — Potentiometric Map — January 2023 -
January/February/March 2024
Figure 6-7A-C PFAS Analytical Results
Figure 6-8 Willis Creek PFAS Concentrations and Water Elevation
Figure 6-9 Cape Fear River Transect Sampling Locations and PFAS Analytical Results in
Groundwater
Figure 6-10 Indicator PFAS Concentrations Across Cape Fear River Transects (March
2024)
Figure 6-11 Total Table 3+ (17 Compounds) Concentrations, Mass Discharge and Daily
Flow at Tar Heel Ferry Road Bridge
TR0795 — CFR Long -Term Remedy Performance Monitoring Report #5 iii June 2024
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LIST OF APPENDICES
Appendix A Laboratory Analytical Data Review Narratives
Appendix B FTC Transducer Data Reduction
Appendix C Corrected PFPrA Concentrations for Previously Reported Results
Appendix D Updated PFPrA Calculation Discussion and Table of Previously Reported
Results Along with Revised, Corrected Results, Chemours Fayetteville
Works, Fayetteville, NC
TR0795 — CFR Long -Term Remedy Performance Monitoring Report #5 iv June 2024
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LIST OF ACRONYMS AND ABBREVIATIONS
COA
Addendum to Consent Order Paragraph 12
DO
Dissolved Oxygen
DQO
Data Quality Objectives
DVM
Data Verification Module
eDMR
Electronic Discharge Monitoring Reports
EIM
Environmental Information Management
EPA
Environmental Protection Agency
EW
Extraction Well
gpm
gallons per minute
FTC
flow -through cells
GAC
Granular Activated Carbon
GWEC
Groundwater Extraction and Conveyance
GWTP
Groundwater Treatment Plant
HFPO-DA
hexafluoropropylene oxide-dimer acid
lbs
pounds
MG
million gallons
mg/L
milligram per liter
µS/cm
microsiemens per centimeter
MLM
Mass Loading Model
NCDEQ North Carolina Department of Environmental Quality
NAVD88 North American Vertical Datum of 1988
ng/L
nanograms per liter
NPDES
National Pollutant Discharge Elimination System
NTU
nephelometric turbidity units
OM&M
Operations, Maintenance, and Monitoring
OW
Observation Well
PFAS
per- and polyfluoroalkyl substances
PFM
Passive Flux Meter
PFMOAA
perfluoro-2-methoxyacetic acid
TR0795 — CFR Long -Term Remedy Performance Monitoring Report #5 v June 2024
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PFPrA
perfluoropropanoic acid
PMP
Performance Monitoring Plan
PMPA
perfluoro-2-methoxypropionic acid
QA/QC
Quality Assurance/Quality Control
RPD
Relative Percent Difference
SU
Standard Units
USGS
United States Geological Survey
TR0795 — CFR Long -Term Remedy Performance Monitoring Report #5 V i June 2024
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1 INTRODUCTION
Geosyntec Consultants of NC, P.C. (Geosyntec) has prepared this CFR Long -Term Remedy
Performance Monitoring Report #5 ("Report") on behalf of The Chemours Company FC, LLC
(Chemours) to provide a summary report of Operations, Maintenance, and Monitoring (OM&M)
for the groundwater and seep remedies installed at the Chemours Fayetteville Works Site (the Site)
pursuant to the Addendum to the Consent Order Paragraph 12 [COA] Paragraph 2.c.v.
This Report has been prepared for the period of January 1 through March 31, 2024 (Q1 2024). The
remedy components consist of the interim in -situ flow -through cells (FTCs), groundwater
extraction and conveyance (GWEC) system, the Ex -Situ Seeps and Weeps capture systems ("Ex -
Situ Capture Systems"), and the groundwater treatment plant (GWTP). The components of the
remedies are shown in an overview layout in Figure 1-1. Various monitoring and sampling
activities were conducted during the reporting period as summarized in Table 1-1.
1.1 Data Validation
Laboratory analytical data for the samples collected during the Q 1 2024 reporting period were
reviewed using the Data Verification Module (DVM) within the LocusTM Environmental
Information Management (EIM) system, a commercial data management software program.
Following the DVM process, a manual review of the data was conducted. The DVM and the
manual review results were combined in a DVM narrative report for each set of sample results
which is consistent with Stage 2b of the USEPA Guidance for Labeling Externally Validated
Laboratory Analytical Data for Superfund Use (USEPA, 2009). The DVM narrative report
summarizes which samples were qualified (if any), the specific reasons for the qualification, and
any potential bias in reported results. The data usability, in view of the project's data quality
objectives (DQOs), was assessed, and the data were entered into the EIM system.
The data were evaluated by the DVM against the following data usability checks:
• Hold time criteria
• Field and laboratory blank contamination
• Completeness of QA/QC samples
• Matrix spike/matrix spike duplicate recoveries and the relative percent differences (RPDs)
between these spikes
• Laboratory control sample/control sample duplicate recoveries and the RPD between these
spikes
• Surrogate spike recoveries for organic analyses
TR0795 — CFR Long -Term Remedy Performance Monitoring Report #5 1 June 2024
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• RPD between field duplicate sample pairs
A manual review of the data was also conducted, which included visual inspection of sample
chromatograms for appropriate integration and retention time, verification that detections in field
or equipment blanks have been applied to all applicable samples, and review of temperature
requirements for sample preservation during storage and shipping. Based on the results of the
DVM plus manual review, the following data evaluation qualifiers were applied to the analytical
results as required:
• J - Analyte present, reported value may not be accurate or precise.
• UJ - Analyte not present above the reporting limit, reporting limit may not be accurate or
precise.
• B - Analyte present in a blank sample, reported value may have a high bias.
The DVM narrative reports are provided in Appendix A. Overall, the DQOs were met for accuracy
and precision. During this sampling event, all samples were within the acceptable temperature
requirements for preservation during storage and shipping (i.e., between not frozen to 6°C with a
target of 4°C) as outlined in the Chemours PFAS Program QAPP (AECOM, 2018). The data
collected are believed to be complete, representative, and comparable, with the exception of R-
PSDA, Hydrolyzed PSDA, and R-EVE; matrix interference studies have shown that quantitation
these compounds is inaccurate due to interferences by the sample matrix (Geosyntec, 2020).
Results for these three analytes are J-qualified as estimated.
1.2 Laboratory Analyses
Groundwater and surface water samples collected in Q 12024 were analyzed for 21 Table 3+ PFAS
and 35 other PFAS compounds by Method 537MM. Matrix interference studies have shown that
quantitation of three of the compounds included in the Table 3+ PFAS group, R-PSDA,
Hydrolyzed PSDA, and R-EVE111 is inaccurate due to interferences by the sample matrix
(Geosyntec, 2020a). Groundwater and surface water results for Table 3+ PFAS compounds are
presented in report tables as three PFAS groupings:
• Total Table 3+ (21 compounds), which is the sum of all Table 3+ PFAS compounds.
• Total Table 3+ (18 compounds), which excludes R-PSDA, Hydrolyzed PSDA, and R-EVE
due to the matrix interferences noted above.
2,2,3,3,4,5,5,5-octafluoro-4-(1,1,2,2-tetrafluoro-2-sulfoethoxy)-pentanoic acid (R-PSDA), 2-fluoro-2-[l,1,2,3,3,3-
hexafluoro-2-(1,1,2,2-tetrafluoro-2-sulfoethoxy)propoxy]-acetic acid, (Hydrolyzed PSDA), and 4-(2-carboxy-
1,1,2,2-tetrafluoroethoxy)-2,2,3,3,4,5,5,5-octafluoro-pentanoic acid (R-EVE)
TR0795 — CFR Long -Term Remedy Performance Monitoring Report #5 2 June 2024
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• Total Table 3+ (17 compounds), which additionally excludes perfluoropropanoic acid
(PFPrA), to allow for a direct comparison of results to prior years and to discuss mass
removal of remedial components. Although the report tables include results for the three
groupings above, the text and figures of this report focus on the Total Table 3+ (17
compounds) HAS grouping.
1.2.1 Correction of PFPrA Concentrations
On April 23, 2024, Eurofins-Sacramento informed Chemours via email that a calculation error had
been incorporated into the preparation of calibration standards for PFPrA under the laboratory's
537 Mod Max methodology. The error resulted in a 36% low bias in PFPrA concentrations. The
error affected Chemours samples collected on behalf of the Fayetteville Works Site between June
2023 and April 2024. Chemours informed NCDEQ of the PFPrA calculation error via telephone
on May 15, 2024, and provided NCDEQ with Eurofins-Sacramento's memo describing their root
cause analysis of the PFPrA calculation error on May 22, 2024.
PFPrA results that were calculated incorrectly have been corrected by Eurofins-Sacramento and
provided to Chemours. These results fall into two categories: 1) results that were corrected before
being reported to NCDEQ, and 2) results that were reported to NCDEQ before being corrected.
The PFPrA results for Q 12024 provided in this report fall into category 1). They are being reported
here for the first time. PFPrA results from July 2023 to November 2023 that have been provided
in previous reports in this sampling program fall into category 2). Appendix C of this report
provides a table of the results in category 2) with corrected PFPrA concentration values.
Additional detail is provided in a letter submitted to NCDEQ by Chemours on June 18, 2024,
which is provided in Appendix D.
TR0795 — CFR Long -Term Remedy Performance Monitoring Report #5 3 June 2024
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2 IN -SITU SEEP FLOW -THROUGH CELLS
The in -situ FTC remedies have been in operation since December 2020 beginning with Seep C.
Detailed information on the hydraulic mechanics of the FTC system, flood management practices,
data collection methodology and reduction process, and flow calculation formulas is presented in
previous Seeps O&M reports. As a simplifying step for presentation clarity, at various sections in
this report, reference is made to these details within Seeps O&M Report #14 (Geosyntec, 2023a),
the last of the bimonthly Seeps O&M Reports.
2.1 Inspections, Operation, and Maintenance
The following sections describe the inspections, operation, and maintenance activities completed
at the four FTCs during the current reporting period.
2.1.1 Inspections
Routine inspections occurred on a weekly basis (at a minimum), and also occurred within a 24-hour
period after rain events of 0.5 inches or greater. An Inspection Form was filled out by O&M
personnel during each inspection. A summary of the inspection and maintenance events completed
during this reporting period is provided in Tables 2-1A-D for Seeps A-D, respectively.
2.1.2 Duty Cycling
Tables 2-IA-D detail the filter bed configurations for Seeps A, B, C, and D over the reporting
period of January 1 through March 31, 2024. The table below summarizes the approximate number
of days in the reporting period each FTC was either in batch mode operation (i.e., the FTC closed
to flow); or if in operation, which filter bed was in lead.
Seep
FTC Closed to
Flow in Batch
Mode (days)
FBI Lead (days)
FB2 Lead (days)
Total Uptime in
Reporting Period
(days)
A
31
0
60
91
B
41
32
18
91
C
24
7.5
59.5
91
D
40
27
24
91
2.1.3 FTC Management During River Flooding
During the reporting period, the Cape Fear River rose above the action leve12 from January 10
through January 18, 2024, and from March 29 through March 31, 2024. Cape Fear River elevation
2 See Section 2.3 of Seeps O&M Report #14 for details regarding the action level that was established to protect the
electronic components of the autosamplers from flood events.
TR0795 — CFR Long -Term Remedy Performance Monitoring Report #5 4 June 2024
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data are described in Section 2.3.5. Cape Fear River elevation statistics are presented in Table 2-2,
and elevation changes during the reporting period are shown on Figures 2-1A through D.
2.1.4 Material Changeouts
The table below summarizes the material changeouts through this reporting period:
Seep
Filter Bed
GAC Changeouts
Date
GAC Age/Lead Days
GAC Removed
(lbs)
C
FBI
1/4/2024
196/92.5
9,000
D
F132
2/2/2024
344/181
27,000
B
FBI
2/22/2024
231/111
27,000
Total
63,000
2.1.5 Issue Resolution and System Optimization
As described in CFR Long -Term Remedy Performance Monitoring Report #4, flow was observed
from the bluff face in the vicinity of the Outfall 002 discharge pipe and entered the Seep C FTC
during dry weather in November 2023. Subsequent investigations indicated a potential leak in the
Outfall 002 discharge pipe. A joint sealing remedy was applied to the discharge pipe in December
2023. Following the remedy, flowrate at the bluff face appeared to be reduced and O&M personnel
observed continued decline through December 2023.
During the current reporting period (January 1 to March 31, 2024), Site operations personnel
gauged the piezometers monthly and observed further declines and ultimately stabilization in water
levels. Additionally, water levels in the Seep C impoundment were stable or declined during dry
periods when the FTC was in batch mode (closed to flow) from February 2 to February 9,
February 16 to February 22, and March 16 to March 22, 2024 indicating no further additions to
seep flow from the potential leak.
2.2 Data Collected
Details regarding the procedures for each type of data collected, including pressure transducer
management and data processing, rainfall and river stage data collation, and sample collection can
be found in Seeps O&M Report #14. An overview is provided in the table below. The transducer
data reduction process for the current reporting period is provided in Appendix B.
s The Outfall 002 discharge pipe contains treated water from the 004 GWTP, and treated wastewater and non -
contact cooling water from the facility.
TR0795 — CFR Long -Term Remedy Performance Monitoring Report #5 5 June 2024
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Data Type
Monitoring During Q1 2024
Monitored every 15-minutes using pressure transducers in the influent
Impoundment Elevation
stilling basins, and with daily observation of the staff gauges in the
impoundments.
Monitored for flow every 15-minutes using pressure transducers during
Flowrate Measurements
passive flow operation; or measured with a flowmeter when directly
pumped from the impoundment into the lead filter bed.
Rainfall and River Stage
Monitored every 15 minutes using data from the W.O. Huske Dam
(gauge 02105500).
Sampling is only able to be performed when the FTCs are not closed to
flow in batch mode. After sufficient rainfall has raised the impoundment
level, an FTC is opened to flow and a 24-hour composite sample is
collected. As dry weather flow has terminated and the FTCs are treating
predominately rainwater, in some cases rainwater that has accumulated
over multiple rain events and periods of days or weeks, it is no longer
practical to collect cotemporaneous wet weather monitoring samples.
Performance Monitoring and
Therefore, moving forward, all FTC samples will be designed
Water Quality Measurements
performance monitoring samples. During this reporting period, twelve
sets of performance monitoring samples each were collected from Seeps
A, B, and D. Thirteen sets of performance monitoring samples were
collected from Seep C. There were no deviations in the reporting period.
Dates of composite periods for each sample are listed in Tables 2-3A-
D.
Water quality in the Inlet Chamber and Effluent Stilling Basin at Seeps
A-D was monitored at the same frequency as performance monitoring.
Grab samples were collected from the Inlet Chamber, Transfer Basin,
and Effluent Stilling Basin at Seeps A-D for evaluation of system
performance and the need for GAC changeouts. Seven sets of
Breakthrough Monitoring
breakthrough monitoring samples were collected from Seep A, five sets
of breakthrough monitoring samples were collected from Seep B and D,
and eight sets of breakthrough monitoring samples were collected from
Seep C during this reporting period (25 total).
2.3 Results
The results for each type of data collected are described in detail in the following subsections.
Laboratory analytical results are compiled in Appendix A. An overview of the results is as follows:
TR0795 — CFR Long -Term Remedy Performance Monitoring Report #5 6 June 2024
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Reporting Period Metric
Seep A
Seep B
Seep C
Seep D
Total
Rainfall, Actual (inches)
9.49 (January I —March 31, 2024)
Rainfall, Historical
7.96 (January I —March 31, 2004-2020)
Average (inches)
River Above Spillway
5.6
5.1
5.2
5.6
N/A
(days) '
Median Flow Rate over
full reporting period (gpm)
22
0
20
0
42
2
Median Flow Rate (gpm)
39
36
28
14
117
when in operation'
Seep Volume Treated
3.5
2.7
2.9
1.0
10.1
(MG)
PFAS Removed (lbs) 4
1.49
0.66
0.7
0.18
3.03
I - Seeps A and D are approximately I ft lower in elevation than Seeps B and C.
2 — Median flow rate calculated during entire reporting period, including during batch mode operations
when cells are closed to flow.
3 — Median flow rate calculated when FTCs were processing flow (i.e., not in batch mode).
4 — Total PFAS calculations are based on the total Table 3+ (17 compounds) presented in Table 2-4A-D.
2.3.1 System Flowrates and Operational Periods
System Flowrates
Figures 2-2A-D show the measurable flowrates through the FTC over the reporting period for
Seeps A-D, respectively. As shown in Figure 2-3, total volume discharged by the FTCs has
decreased dramatically. The reductions in flow are attributed to the barrier wall and the operation
of the groundwater extraction system and Ex -Situ Capture Systems.
Instances of Bypass
The influent water level elevation and occurrences of bypass flow (if applicable) for Seeps A-D
for the reporting period are shown in Figures 2-4A-D. The total rainfall received in the reporting
period is shown below. The few instances of bypass were resolved with maintenance events
lowering the impoundment below the spillway, similar to previous reporting periods.
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Period
Rainfall
(inches)
Historical Rainfall
(inches)
% Change Compared to
Historical
January 2024
3.43
2.28
+50%
February 2024
1.89
2.89
-35%
March 2024
4.17
2.79
+50%
Q 1 2024
9.49
7.96
+20%
Long -Term Remedy Impacts on Baseflow
Figures 2-4A-D depict the elevation of the influent pond at Seeps A-D and instances of batch mode
processing. Figures 2-5A-D depict the impoundment elevation at Seeps A-D and instances of batch
mode processing. As shown, even with the FTCs turned off, the impoundment elevation generally
appears to respond only during rainfall events, indicating that the long-term remedy components
have eliminated the Seep baseflow.
2.3.2 Performance Monitoring Analytical Results
As noted in Section 2.2, after sufficient rainfall has raised the impoundment level, an FTC is
opened to flow and a 24-hour composite sample is collected. As dry weather flow has terminated
and the FTCs are treating predominately rainwater, in some cases rainwater that has accumulated
over multiple rain events and periods of days or weeks, it is no longer practical to collect
cotemporaneous wet weather monitoring samples. Therefore, moving forward, all FTC samples
will be designed performance monitoring samples.
Analytical results for the composite performance monitoring samples are provided in
Tables 24A-D and summarized below. Figure 2-6 shows that the influent concentration of total
Table 3+ PFAS (17 compounds) into the FTCs. For data up through December 2022
(approximately the time when barrier wall test panel installation began), the average influent
concentration into FTCs A-D ranged from 102,000 to 236,000 nanograms per liter (ng/L). As
shown below, the average influent concentration into the FTCs in Q1 2024 ranged from 21,633 to
52,750 ng/L. This reduction in concentration is attributed to the barrier wall cutting off upgradient
groundwater flow, and the overall contribution of water balance into the FTCs becoming more
dominated by wet weather, rainfall derived flow. The combination of significantly reduced flow
and concentration has resulted in an asymptotic HAS mass removal trend as shown in Figure 2-
7.
Implementation of batch mode, in which the impoundment levels are managed such that
accumulated water in the basin is processed at flow rates more typical of the historical operation,
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appear to be increasing the removal efficiencies to the same level (i.e., >99%) as previous reporting
periods.
Analytical Results — Performance
Seep A
Seep B
Seep C
Seep D
Monitoring
Average Influent Total Table 3+ PFAS, 17
52,750
29,000
28,923
21,633
compounds (ng/L)
Average Effluent Total Table 3+ PFAS, 17
44
136
82
40
compounds (ng/L)
Average Removal Efficiency (%)
>99.9
99.5
99.7
99.8
2.3.3 System Effectiveness
System effectiveness calculation procedures are presented Seeps O&M Report #14. Based on the
system flowrate data and the performance monitoring composite sample data of the three indicator
compounds, the system effectiveness for Seeps A-D was calculated as follows.
System Effectiveness (%)
Seep A
Seep B
Seep C
Seep D
January
99.8
99.4
99.5
99.7
February
>99.9
99.3
99.8
99.8
March
99.9
99.4
99.6
99.8
Overall Average
99.7
2.3.4 River Elevation and Precipitation
On January 10, the Cape Fear River rose above the elevation of the discharge weir and bypass
spillway at all four FTCs and receded below these features by January 18. On March 29, the river
rose above the discharge weir (but not the bypass spillway or top of wall) at all four FTCs and
receded below these features by March 31. The changes in elevation of the Cape Fear River during
the reporting period (January 1 through March 31, 2024) are shown in Figures 2-IA through D.
Table 2-2 presents the percent of time the elevation of the Cape Fear River has exceeded these key
elevations over the lifetime of operation at each Seep FTC. As shown, the amount of time the river
has been above the FTC features is similar to the historical record.
2.3.5 Water Quality
The water quality measurements collected during the reporting period are provided in
Tables 2-5A-D and described below:
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• Dissolved Oxygen (DO): No significant differences were observed in the fluctuations of
DO between influent and effluent locations at all four Seeps. On a median basis, the DO
changed by 1 milligram per liter (mg/L) or less. Aerobic (>2 mg/L) conditions were
consistently observed during the reporting period.
• Temperature: At all four Seeps, the median temperature of the effluent was within 1.2°C
of the median temperature of the influent during this reporting period.
• Specific Conductance: For all four Seeps, the difference in median specific conductance
across influent and effluent locations ranged between -74 and 13 microSiemens per
centimeter (µS/cm). During normal hydraulic conditions, the FTC is expected to have little
effect on the anion/cation content of the seep baseflow.
• pH: The median influent pH at the four Seeps ranged from 5.1 to 7.3, and the median
effluent pH ranged from 5.5 to 7.48 standard units (SU) in this reporting period. From the
Inlet Chamber to the Effluent Stilling Basin, the median pH of treated water at Seeps A, B,
C, and D changed by 0.4, 0.7, 0.2, and 0.2 SU, respectively.
• Turbidity: The median turbidity of the influent water at Seeps A-D ranged from 13 to
121 nephelometric turbidity units (NTU). The FTCs significantly decreased the turbidity
of the influent water. The median turbidity of the effluent water at Seeps A-D ranged from
2 to 30 NTU.
• TSS: The median influent TSS at Seeps A-D ranged from 7 to 38 mg/L. Median effluent
TSS at Seeps A-D was detected in minimal concentrations (5 mg/L or lower). As was the
case with turbidity, the FTCs generally decreased the TSS in the influent water.
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3 EX -SITU SEEPS AND WEEPS CAPTURE
Section 3 summarizes the operation, maintenance, and monitoring activities performed by
GEOServices, LLC as the operator of the Ex -Situ Capture Systems. This remedy consists of four
seep capture locations (Willis Creek Tributary, Seep A, Seep A Tributary, and Seep B), and three
dedicated weep capture locations (Weep 1, Weep 3, and Weep 4). Additionally, at seep capture
location Seep A, the nearby Weep 7 is tied into the basin and is included in this system's capture.
At seep capture location Seep A Tributary, the nearby weeps 9, 10, and 11 are tied into the wet
well and are included in this system's capture. The 004 GWTP pad is connected to Weep 4 and
includes its capture. Finally, the Weep 1 capture system pumps captured water directly into the
GWEC force main.
The seep capture locations are required to capture dry weather flows and stormwater flows from
rainfall events up to 0.5 inches over 24 hours. Through the ex -situ force main, the captured water
is pumped to a lined surge pond, which the GWTP periodically withdraws for treatment.
3.1 Operation and Maintenance
The Ex -Situ Capture Systems have been operating since April 20, 2023. Pumping of captured
water from ex -situ seep and weep locations to the surge pond continued during this reporting
period. The 004 GWTP treated the captured water after periodically withdrawing from the surge
pond. Routine operations and maintenance were performed on the capture systems per
GEOServices' O&M Plan.
3.2 Data Collected
The Ex -Situ Capture System telemetry network transmits the flow data from totalizers at Seep A,
Seep A Tributary, Seep B, Willis Creek Tributary, and Weep 3 on a 15-minute frequency. Veolia
records the volume conveyed from the surge pond to the 004 GWTP on a daily basis.
3.3 Results
Table 3-1 shows the daily volume conveyed from the surge pond to the 004 GWTP and totalizer
volumes conveyed from Seep A, Seep A Tributary, Seep B, Willis Creek Tributary, and Weep 3.
During this reporting period, approximately 5.9 MG of captured water was pumped from the seep
and weep capture locations to the surge pond and approximately 5.9 MG was conveyed from the
surge pond to the 004 GWTP. The captured water in Q 1 2024 is 64% higher than Q4 2023 (5.9
MG vs 3.6 MG). This increase is attributed to the wetter conditions in Q 12024.
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4 GROUNDWATER EXTRACTION AND CONVEYANCE
Section 4 describes the GWEC operation, maintenance, and monitoring activities that were
conducted by Geosyntec as the operator of the system and provides a summary of the critical
operational data that were collected and discusses the monitoring results from extraction well
sampling activities during the reporting period. Construction details for the extraction wells are
provided in Table 4-1.
4.1 Operation and Maintenance
The GWEC system has been operating since March 14, 2023. The performance of the individual
components of the GWEC system, on a well -by -well basis, are recorded via a telemetry network.
System alerts and alarms have been programmed and are generated when a GWEC component is
underperforming or not functioning. In such cases, Geosyntec leads the OM&M response, and
performs the required corrective measures. On a minimum monthly basis, preventative
maintenance and inspection is performed, in which extraction well components, control panels,
and forcemain air release valves are individually checked.
4.2 Data Collected
4.2.1 Extraction Well Operational Data
Table 4-2 provides a summary of flow data (daily average flow rate and daily cumulative volume)
for the GWEC system (combined flow from all wells). Table 4-3 provides a summary of flow data
for each extraction well during the reporting period (average monthly flow rate, and total
cumulative volume by month).
4.2.2 PFAS Data
The previous extraction well sampling events occurred in the pre -startup commissioning phase,
from January 24 through March 14, 2023; and on April 12, 2023, approximately one month after
full startup. The extraction wells were sampled most recently in April 15-16, 2024. These results
will be presented in the subsequent CFR Long -Term Remedy Performance Monitoring Report #6
documenting the Q2 2024 period.
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4.3 Results
4.3.1 Groundwater Extraction
The GWEC system extracted approximately 44.4 MG during the reporting period, with
approximately 5.1 MG from surficial aquifer wells and 39.3 MG from Black Creek aquifer wells.
The average extraction rate during the Q1 2024 reporting period was approximately 337 gallons
per minute (gpm), which is similar to the extraction rate of 332 gpm in the previous reporting
period (Q4 2023), and similar to the extraction rate in September 2023 (336 gpm) when this steady-
state extraction flow rate was first reached. From March 2023 through August 2023, extraction
rates gradually declined from a peak of 540 gpm in the initial operating period. This is attributed
to the established declines seen in water levels in the Black Creek aquifer upgradient of the remedy.
Section 6.2.1 describes the reduction in groundwater elevation upgradient of the barrier wall
stabilized since the completion of the barrier wall and the implementation of the long-term remedy
components.
As shown in Table 4-3, the flow rates in the Willis Creek (Northern Alignment) are lower than the
Barrier Wall (Southern Alignment) (in March, the average Willis Creek EW pumped about 3.7
gpm, whereas the average EW in the Southern Alignment pumped about 5.1 gpm). This is
consistent with previous work at the site (Geosyntec, 2021 and Geosyntec, 2022) which indicates
that the aquifer sands in this area are generally much thinner, less connected, and less transmissive
than aquifer sands in the Southern Alignment.
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5 004 TREATMENT PLANT
Section 5 provides GWTP operational data collected by Veolia as the operator of the treatment
system and discusses the performance of the treatment relative to the design objectives and the
COA, which requires that extracted groundwater is treated to remove PFAS compounds4 by at
least 99%. As with the GWEC system, the 004 GWTP has been operating since March 14, 2023.
Chemours reports various GWTP performance data in electronic Discharge Monitoring Reports
(eDMRs) per the National Pollutant Discharge Elimination System (NPDES) permit NC0090042,
and additionally provides laboratory reports and an analysis of the treatment efficiency (in percent
removal of the indicator compounds HFPO-DA, PMPA, and PFMOAA) in a data transmittal
process to North Carolina Department of Environmental Quality (NCDEQ). This Report does not
reproduce that effort, and only reports on the flow and treatment aspects to comply with COA
Paragraph 2.c.v. The following data are consistent with the eDMRs and data transmittals.
5.1 Data Collected
5.1.1 Flow Rates
Veolia measures flow at the combined influent and effluent monitoring locations as required by
the NPDES permit. Flow measurements are collected by the meters at a 15-minute frequency.
5.1.2 PFAS Influent and Effluent
Veolia collects weekly (at a minimum) samples of the total influent and effluent per NPDES
reporting requirements. Once per month, the samples are analyzed for Table 3+ PFAS, and once
per quarter, the samples are analyzed for Table 3+ and EPA Method 537 MOD. The remaining
weekly samples are analyzed for indicator compounds HFPO-DA, PFMOAA, and PMPA. All
samples were analyzed by Eurofins TestAmerica Laboratories.
5.2 Results
5.2.1 Flow Rates
The daily total influent volume, the volume treated and discharged, and the average daily discharge
flow rate, are provided in Table 5-1. As shown, the GWTP treated and discharged a total volume
of 47.8 MG over the reporting period. The average daily flow rate for this duration was 365 gpm.
This is 6% higher in comparison to the previous period (344 gpm in Q4 2023).
4 As measured by indicator parameters hexafluoropropylene oxide dimer (HFPO-DA), perfluoromethoxypropyl
carboxylic acid (PMPA), and perfluoro-2-methoxyaceticacid (PFMOAA)
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5.2.2 Analytical Results
The laboratory analytical results for the influent and effluent samples are shown in Table 5-2.
Laboratory analytical reports for 004 samples are compiled in Appendix A. As shown, the total
Table 3+ (17 compounds) PFAS concentration in the influent ranged from 110,000 to
140,000 ng/L. The Table 3+ (17 compounds) PFAS analytes were not detected above laboratory
reporting limits in effluent samples, indicating at least 99% removal as documented in data
transmittals from Chemours to NCDEQ.
5.2.3 PFAS Mass Removal
The flow rate data (monthly totals) and PFAS concentration data (monthly representative
concentration per the monthly or quarterly samples, which in this reporting period were collected
on January 2, February 12, and March 11) were used to calculate Table 3+ PFAS mass removal.
As shown below, the total Table 3+ PFAS mass removed (17 compounds) by the GWTP in the
reporting period (Q 1 2024) was 50.5 lbs. Through the end of the previous period (Q4 2023), 252.4
lbs of PFAS was removed. Therefore, the amount of PFAS removed from commissioning through
March 31, 2024 is 302.9 lbs.
Total Table 3+ (17
Reporting
Total Volume
Compounds) PFAS
Table 3+ (17 Compounds)
Month
T
Treated by
Concentration per
PFAS Mass Removed (lbs)
GWTP (MG)
Monthly/Quarterly Sample
(ng/L)
January
16.9
140,000
19.8
February
14.6
130,000
15.8
March
16.3
110,000
14.9
Q1 2024 Total
47.8
N/A
50.5
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6 PERFORMANCE MONITORING EVALUATION
A Performance Monitoring Plan (PMP) was prepared to address long-term groundwater remedial
action effectiveness. The PMP proposed to evaluate the effectiveness of the remedy with multiple
lines of evidence, which are listed below and discussed in more detail in this section:
• Hydraulic head both along the barrier wall alignment and downgradient of the barrier wall
between the wall and the Cape Fear River, to assess groundwater capture and the reduction
in hydraulic gradient downgradient of the remedy alignment;
• Passive flux meters (PFMs), to evaluate downgradient groundwater Darcy flux;
• Surface water samples at Willis Creek, to evaluate reduction in PFAS loading to Willis
Creek;
• Surface water samples at Tar Heel Ferry Road, to evaluate PFAS concentrations and mass
loads in the well -mixed Cape Fear River downstream of the facility; and
• Groundwater sampling at extraction and monitoring wells between the groundwater
remedy and the Cape Fear River or Willis Creek.
6.1 Data Collected
6.1.1 Hydraulic Head and Surface Water Elevation
Monthly gauging events of 83 observation wells (OWs) was performed on January 31, February
27, and March 27, 2024. The hydraulic head monitoring network is shown in Figure 6-1. In
addition to these manual gauging events, transducers were also deployed in a network of 16 wells
that comprise 6 transects that span across the barrier wall alignment. These transducers were
deployed on March 8, 2023, during the final GWEC commissioning and about one week prior to
the March 14, 2023 operational startup. The transducers record groundwater elevation every 15
minutes and are downloaded monthly. Finally, data is incorporated from three transducer stilling
wells that were installed at Willis Creek between September 20 and October 6, 2023.
6.1.2 PFAS Concentrations in Groundwater and Surface Water
Downgradient Groundwater
PMP wells, to be sampled on a semi-annual basis (Q1 and Q3), were sampled between January 17
and February 6, 2024. Out of the 20 PMP wells, 18 were sampled in Q 12024. PIW-1 OS and PIW-
5SR were not sampled because these wells have become consistently dry due to the long-term
remedy. The 20 PMP wells are OW-4R, OW-30, OW-32, OW-37, OW-40, OW-51, OW-54, OW-
TR0795 — CFR Long -Term Remedy Performance Monitoring Report #5 16 June 2024
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55, OW-56, OW-57, PIW-4D, PIW-5SR, PIW-6S, PIW-8D, PIW-IODR, PIW-IOS, PIW-11, PIW-
15, PW-IORR, and PW-11.
Mass Loading Model (MLM) wells are sampled quarterly. A total of 14 MLM monitoring wells
are downgradient of the long-term remedy and are therefore potentially viable data points for
effectiveness monitoring (OW-28, OW-33, LTW-01, LTW-02, LTW-03, LTW-04, LTW-05,
PIW-1S, PIW-1D, PIW-3D, PIW-7S, PIW-7D, PZ-22, and SMW-12). These MLM wells were
sampled from January 15 through 31, 2024. The collected samples were sent to Eurofins
TestAmerica Laboratories for analysis by Table 3+ and EPA Method 537 MOD.
Willis Creek Surface Water
At three locations within Willis Creek (WC), routine quarterly sampling was performed to evaluate
potential long-term reductions in concentration (reductions in the short-term are not necessarily
anticipated). The sampling procedures were in accordance with the Cape Fear River PFAS Mass
Loading Assessment Report series (Geosyntec, 2024b). WC-1, WC-2, and WC-3 were sampled
on February 22, 2024. The collected samples were sent to Eurofins TestAmerica Laboratories for
analysis by Table 3+ and EPA Method 537 MOD.
Cape Fear River Surface Water
Surface water grab samples were collected on March 12, 2024 at four transects along the Cape
Fear River. Each transect consisted of three sampling locations, for a total of 12 sampling points.
The sampling program was in accordance with the Final National Pollutant Discharge Elimination
System (NPDES) Permit for Outfall 004 (Permit: NC0090042). The collected samples were sent
to Eurofins TestAmerica Laboratories for analysis by Table 3+. From March 2020 through
December 2023, sampling under this permit was performed on a monthly basis. Starting Q1 2024,
samples are to be collected quarterly (i.e., six months after the completion of the barrier wall as
per the Permit requirements).
Since March 2020, routine sampling of the Cape Fear River has been performed at Tar Heel Ferry
Road Bridge (or Tar Heel, approximately 7 miles downstream of the Site). The sampling program
was in accordance with the Paragraphs 1(a) and 1(b) of the Addendum to Consent Order
paragraph 12 (CO Addendum). Composite samples were collected generally twice per week using
an autosampler. Grab samples were collected when the composite sampling program was
temporarily interrupted due to various factors such as vandalism, equipment malfunction, or high
river stages which may flood the autosampler. The collected samples were sent to Eurofins
TestAmerica Laboratories for analysis by Table 3+.
6.1.3 Passive Flux Meters
The first post -startup deployment of PFMs was conducted in August 2023 and its results were
discussed in CFR Long -Term Remedy Performance Monitoring Report #3 (Geosyntec, 2023d).
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The next post -startup deployment is planned for June 2024, and results will be presented in CFR
Long -Term Remedy Performance Monitoring Report #6 documenting the Q2 2024 period.
6.2 Results
6.2.1 Hydraulic Head and Surface Water Elevation
This section discusses hydraulic head which is a critical line of evidence for evaluating hydraulic
containment of groundwater. This section is developed in the following sequence:
1. As the Cape Fear River can influence some wells screened in the Black Creek aquifer,
this section will first discuss the river conditions during each gauging event. Notably,
during high river stages (flooding), this can exert a pressure response on the confined
aquifer that has connectivity to the river.
2. The results in the Southern Alignment (Barrier Wall portion) are discussed next, which
includes discussion of both the Black Creek aquifer and the surficial aquifer.
3. Last, the results in the Northern Alignment (Willis Creek area) are evaluated separately
from the Southern Alignment.
1. River Stage During Gauging Events
Hydraulic connectivity between the Black Creek aquifer and the Cape Fear River was discussed
in CFR Long -Term Remedy Performance Monitoring Report #1 (Geosyntec, 2023b). As before,
river levels for each gauging event in this reporting period were obtained from the USGS Huske
station 02105500. The average river elevation for the duration of the gauging event (e.g., from
8AM to 4PM) was calculated from the 15-minute frequency data available from USGS. These
average levels were compared to the available historical dataset (2007 to 2020) to calculate the
corresponding percentile values, to show whether those gauging events were performed on
relatively high or low river conditions. As shown below, the three gauging events in this period
included a high -river event in January (89d' percentile) and two near -average events in February
and March (51" and 63rd percentile).
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Date
Type
Average River Level
During Gauging Event
(ft NAVD88)
Percentile (Gauging Event
River Level compared to
Historical Dataset)
8/4/2022
Baseline (dry summer)
30.38
52%
8/17/2022
Baseline (dry summer)
29.80
37%
1/30/2023
Baseline (wet winter)
32.50
79%
1 /31 /2024
Post -Startup (Q 1 2024)
34.30
89%
2/27/2024
Post -Startup (Q1 2024)
30.33
51%
3/27/2024
Post -Startup (Q1 2024)
30.98
63%
2. Southern Alignment (Barrier Wall)
2a. Reduction in Groundwater Flux Downgradient of Barrier Wall
Table 6-1 provides groundwater elevation data for the Southern Alignment that is additionally
delineated based on location relative to the barrier wall (upgradient or downgradient). Antecedent
rainfall data for the previous three days are also included. Similar to the previous CFR Long -Term
Remedy Performance Monitoring reports, Table 6-1 shows widespread drawdown in the Black
Creek aquifer since the January 2023 baseline, and stabilized mounding of the surficial aquifer
upgradient of the barrier wall.
As shown in Figures 6-2A-D, the groundwater elevation data from Table 6-1 has been used to
generate 11 gradient maps downgradient of the wall, with plots of the baseline data (August 17,
2022 and January 30, 2023 in greyscale5) compared to the January, February, and March gauging
events (in green, blue, and red, respectively). Consistent with previous reports, the data for the
three events demonstrate that the gradients in these downgradient sections have reduced (i.e.,
flattened) significantly:
• Transects la, 2, 5, 7, and 8 indicate an essentially flat gradient. At the distal end (i.e., the
most downgradient and closest to the Cape Fear River) of some of these transects, there is
an apparent slight inward gradient. This is attributed to the demonstrated effect of increases
5 Transects la/lb and 2 at the southern end of the alignment were added to Report #3 per NCDEQ request. These
transects include wells that were not accessible to install until after the barrier wall was complete, therefore
baseline data is not available in all cases. For OW-39 in particular which is used in both Transects la and lb,
the nearest available baseline data in EWs 63, 64, and 65, as well as PIW-1ODR to the east, indicate the baseline
groundwater elevation in this vicinity ranged from approximately 59-64 ft NAVD88, which is substantially
greater than the values measured in Q1 2024 (around 40.7 ft NAVD88), indicating a significant reduction in
gradient in this area.
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in river elevation causing a corresponding increase in groundwater levels in monitoring
wells screened within the Black Creek Aquifer, particularly in locations closest to the river.
• Transects lb, 3, 4, 6a, and 9 indicate that the average Q1 2024 gradient was approximately
72% less than baseline, which is similar to previous reporting periods.
o Transect 6b gradient comparisons cannot be performed because baseline elevation
data for OW-52 and OW-53 are not available, as well construction for these wells
was initially conflicted by barrier wall installation.
• Despite the January gauging event being affected by the river flood event (i.e., generally
increasing groundwater elevations in the downgradient area), the overall reduction in
gradient is consistent with the relatively drier February and March events. The long-term
remedy reduces groundwater flux beyond the barrier wall in both low and high river
conditions.
2b) Hydraulic Separation of Barrier Wall
In CFR Long -Term Remedy Performance Monitoring Report #2, transducer data were used to
illustrate the separation of the Black Creek aquifer by the barrier wall, as the April 2023 flood
event (with a peak river elevation of approximately 45 ft NAVD88) caused a clear effect on
groundwater elevations downgradient of where the barrier wall had been constructed, but no
discernible effect on groundwater elevations upgradient of the partially constructed wall. Where
this effect was demonstrated (Transects 4, 5, and 6) the upgradient transducers were redeployed to
downgradient areas, to monitor the downgradient area over the long-term. Where this effect was
not able to be demonstrated yet, the transducers were not moved.
As discussed in CFR Long -Term Remedy Performance Monitoring Report #4, in late December
2023, the Cape Fear River flooded for the first time since April 2023, but to a less significant
extent, with a peak river elevation of approximately 39.5 ft NAVD88. In mid -January 2024, the
Cape Fear River flooded again, reaching a peak river elevation close to 45 ft NAVD88. Figures 6-
3A-C show the transect plots of the transducer data for Q1 2024 above the Cape Fear River
hydrograph. Transects 1, 2, and 3 demonstrate the hydraulic separation of the barrier wall, with an
increase in groundwater elevation in the downgradient wells (green colors) and no discernible
effect on the upgradient wells (orange). Since this separation has now been demonstrated across
all transects in the wall alignment, the upgradient transducers were redeployed in late April 2024.
3. Northern Alignment (Willis Creek)
3a. Flood Response in Willis Creek Extraction Wells
The river flooding event in January 2024 was also observed in the Willis Creek EWs,
demonstrating Black Creek aquifer connectivity to surface water as noted for April and December
TR0795 — CFR Long -Term Remedy Performance Monitoring Report #5 20 June 2024
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NC License No.: C-3500 and C-295
2023 flood events discussed in previous reports. The Willis Creek elevation (shown in thick blue
line) is compared to the 15 Willis Creek EWs in Figures 6-4A-C (five wells per chart for clarity):
• In EWs that were pumping continuously prior to the flood event and therefore at a relatively
stable water level (EW-01, 02, 05, 06 and 14), the rising river elevation that began on
January 10 caused a subsequent rise in water levels in the wells.
• In EWs that were pumping intermittently prior to the flood, the rising water levels generally
caused the pumps to be able to run continuously, or at a much higher frequency (EW-03,
04, 06, 07, 08, 10, 12, and 13). At EW-03 for example, the oscillating water level trend
prior to the flood is clearly stabilized during the surge response from the river flood and
remained so through January. The flow totals for the week prior to the flood and the week
after the flood are shown in each figure to demonstrate the effect the rising water levels
had on increasing yield from these wells.
• In EWs that were water -limited prior to the flood, the rising water levels in one case
allowed the pump to activate in an intermittent mode (EW-11). In other cases, the flood
caused a water level increase in the well, but not sufficient to activate the pump level switch
(EW-09 and 15).
Overall, as a consequence of flooding, the increase in groundwater elevation in the Willis Creek
EWs temporarily increases pumping yields until groundwater elevations decline to pre -flood
conditions. This indicates the capability of the Willis Creek extraction well pumps to withdraw
groundwater yields, and the overall limited amount of transmissivity of the aquifer material in non -
flood steady-state conditions.
3b. Hydraulic Containment of Willis Creek Black Creek Aquifer
Groundwater elevation differences relative to January 2023 are shown for the January, February,
and March gauging events in Figures 6-5A-C. Consistent with previous reports, the largest
reduction of groundwater elevation relative to January 2023 occurred in the midsection of the
Northern Alignment between EW-05 and EW-06.
In January 2024, this elevation difference was not as significant as February and March 2024 due
to the flood event, but the pattern of drawdown was still similar, and nearly 6 ft of drawdown was
still observed around EW-05 and EW-06.
Laterally along the alignment north of EW-05 and south of EW-06, elevation reductions between
about 2 ft and 7 ft were observed from proximity of OW-14 (near the beginning of the barrier wall
at EW-14) to OW-41 (in between EW-01 and EW-02). Drawdown along the alignment has also
resulted in four EWs with insufficient water to pump, as compared to startup, demonstrating
overlapping influence within the EWs from the collective pumping. The extensive drawdown is a
line of evidence of hydraulic control.
TR0795 — CFR Long -Term Remedy Performance Monitoring Report #5 21 June 2024
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consultants
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NC License No.: C-3500 and C-295
Potentiometric contour maps are provided for gauging events from January through March 2024
in Figures 6-6A-C. The January 2023 contours are shown in each figure as magenta solid lines. In
January 2023, groundwater generally flows from SMW-03B (near the facility) in a northeastern
direction towards the alignment. The January 2023 groundwater elevations around EW-01 and
EW-02 are higher than the remainder of the alignment (on average approximately 45 ft NAVD88,
as compared to approximately 30 ft NAVD88 from EW-03 to EW-15) which results in an eastward
gradient towards EW-03, which is consistent with previous observations and reports for the Site
(e.g., the Mass Loading Model reports).
Figures 6-6A-C also provide surface water elevation at Willis Creek locations where stilling wells
SW-01 through SW-05 have been installed, providing a comparison between groundwater and
surface water elevations. Based on the available Q1 2024 gauging data, at SW-01 and SW-04,
surface water elevations were within a few ft of groundwater elevations along Willis Creek.
Surface water elevation was higher at SW-03 (33.28 ft and 33.35 ft) than elevations at nearby wells
i.e., PIW-12 through PIW-14 (26.73 ft to 30.99 ft). Surface water elevation at SW-05 (35.99 ft to
36.86 ft) was lower than the nearby OW-57 (43.87 ft to 44.04 ft). However, this staff gauge is
hundreds of ft away from the alignment where there is a clear hydraulic gradient of groundwater
heading east toward the productive pumping areas between EW-03 and EW-08.
6.2.2 PFAS Concentrations and Mass Discharge in Groundwater and Surface Water
Downgradient Groundwater PFAS Concentrations
Results for the PMP and MLM wells sampled in Q 12024 that are downgradient of the long-term
remedy (32 total) are provided in Table 6-2 and shown in Figure 6-7A-C. Laboratory analytical
reports for the downgradient groundwater samples are compiled in Appendix A. The long-term
remedy is not anticipated to have immediate impact on the downgradient PFAS concentrations, as
the hydraulic remedy was designed to reduce the flux of groundwater to the river. Future reports
will continue to evaluate potential long-term impacts to PFAS concentrations, if observed.
However, when evaluated in conjunction with the reduced hydraulic gradients in the downgradient
area, a reduction in PFAS mass discharge to the river is evident. This reduction in mass discharge
is evaluated in the MLM quarterly report for this same reporting period, submitted concurrently
with this report (Geosyntec, 2024c).
Willis Creek Surface Water — Concentration and Mass Discharge
Results for the Willis Creek surface water PFAS samples collected in Q 1 2024 are shown in
Table 6-3, and also presented in Figure 6-7A-C (along with the downgradient groundwater PFAS
data). Willis Creek PFAS trends since July 2022 are shown along with the Willis Creek hydrograph
data from stilling well location WC-1 in Figure 6-8. Laboratory analytical reports for Willis Creek
are compiled in Appendix A.
TR0795 — CFR Long -Term Remedy Performance Monitoring Report #5 22 June 2024
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consultants
Geosyntec Consultants of NC, P.C.
NC License No.: C-3500 and C-295
A mass discharge analysis of Willis Creek was performed to evaluate if declines have begun to be
observed. Table 6-4 shows the PFAS mass discharged at location WC-2 (upstream of remedy) and
at location WC-1 (downstream of remedy). As shown, prior to startup in March 2023, the mass
discharge at upstream location WC-2 ranged from 0.18 to 0.32 mg/s and the mass discharge at
downstream location WC-1 ranged from 0.45 to 0.52 mg/s. The delta between the two locations is
shown, and on average, the pre -startup change in mass loading is approximately 0.23 mg/s (a range
of 0.16 to 0.31 mg/s). The February 2024 result of 0.11 mg/s is similar to the May 2023 and July
2023 results of 0.11 and 0.06 mg/s, respectively. Overall, the post -startup values on average (0.09
mg/s) indicate an approximate 60% mass discharge decline post-startup6. This apparent reduction
effect will continue to be evaluated in future reports.
Cape Fear River Surface Water — Concentration and Mass Discharge
The Cape Fear River transect sampling locations are shown in Figure 6-9. The results of the three
indicator compounds (HFPO-DA, PFMOAA, and PMPA) are shown in Figures 6-10. The transects
for March 2024 were collected during periods of relatively high -river flow with flows ranging
between 9,630 to 10,200 cubic feet per second (cfs). PFMOAA was observed in one sampling
location of Transect 4. No other indicator compounds were observed. As described previously,
inflows (e.g. offsite groundwater, Willis Creek, Lock and Dam seeps, the downstream offsite
seeps, etc.) of Table 3+ PFAS into the Cape Fear River are not fully mixed at the transect locations
and therefore concentration profiles along the transect are not necessarily homogeneous. In
contrast, the mass discharge plots for the samples collected at Tar Heel (Figure 6-11) provide a
mixed river location and take both flow and concentration into account. As shown, the mass
discharges have decreased and remain lower than the mass discharges before Q3 2021, which
corresponds to the time when the FTCs, 003 and groundwater extraction and barrier wall remedies
and were installed and operating.
6 Including the November 2023 event in this comparison would have yielded an even greater mass discharge decline (80%),
however it was excluded as a precaution as there was a slightly higher river stage during the event which may have caused
backflowing river water into WC-1, contributing to a lower concentration at WC-1 than WC-2.
TR0795 — CFR Long -Term Remedy Performance Monitoring Report #5 23 June 2024
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consultants
Geosyntec Consultants of NC, P.C.
NC License No.: C-3500 and C-295
7 SUMMARY
This reporting period (January 1 to March 31, 2024) included the operation of the interim Flow -
Through Cells, Ex -Situ Capture Systems, GWEC, and GWTP remedy components. The table
below summarizes the flow capture and the Table 3+ (17 compounds) PFAS removal for each
remedy element.
Report Period (Jan — Mar 2024)
Cumulative through Mar 2024*
Remedy Element
Flow Captured/
Mass Removed
Flow Captured/
Mass Removed
Treated (MG)
(lbs)
Treated (MG)
(lbs)
Interim FTCs
10.1
3.0
428.4
551.1
004 Treatment Plant
47.8
50.5
245.0
302.9
Ex -Situ Capture
5.9
Included in 004
17.4
Included in 004
Systems
GWEC
44.4
Included in 004
233.3
Included in 004
Total"
57.9
53.5
673.4
854.0
(Interim FTCs + 004)
*Cumulative values reflect the lifetime operation of each remedy component (e.g., since
December 2020 for Interim FTC Seep Q. Please note that some previous reports have reported
the total mass removed of 20 Compounds. Mass removal in this report for all remedy
components is reported as 17 Compounds.
**Differences inflow totals are attributable to the measurement resolution offlow meters on the
different remedy systems as well as storage time in the surge pond, break tank, and other
components. The calculated total influent of the Ex -Situ Capture Systems and GWEC system
above is 50.3 MG for Q1 2024. The total influent as measured by Veolia's flow meter was 49.1
MG. The total effluent as measured by Veolia's flow meter was 47.8 MG as shown.
Flow into the interim FTCs has decreased significantly since the completion of the barrier wall
and implementation of the Ex -Situ Capture Systems and GWEC system. Between July 2021 and
June 2023, the interim FTCs collectively processed 14.8 MG per month on average. Between July
2023 and March 2024, the average monthly volume was 2.6 MG. Batch mode processing has been
necessary in order to maintain treatment efficiency at the reduced flow rates. During dry weather,
with the FTCs offline, the impoundment elevations at the FTCs either remain stagnant or decrease,
indicating that the long-term remedy components have eliminated the seep baseflow. As the FTCs
now treat predominately rainwater mixed with stagnant residual groundwater, the concentration of
PFAS in the influent has also decreased. Between July 2021 and June 2023, the average influent
PFAS concentration (Total Table 3+, 17 compounds) across the four FTCs was approximately
150,300 ng/L; between July 2023 and March 2024, it was 35,200 ng/L. Overall, the combination
of significantly reduced flow and concentration has resulted in a mass discharge into the FTCs that
is approximately 96% reduced from baseline conditions, and an asymptotic PFAS mass removal
trend.
TR0795 — CFR Long -Term Remedy Performance Monitoring Report #5 24 June 2024
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consultants
Geosyntec Consultants of NC, P.C.
NC License No.: C-3500 and C-295
The GWEC system has been operating at a steady-state cumulative extraction rate since
approximately September 2023, after the extraction well startup in March 2023 resulted in initial
declines in the Black Creek aquifer water levels. The average pumping rate in Q1 2024 was 337
gallons per minute. The Ex -Situ Capture systems flow trends are dependent on weather conditions
and are therefore more variable. The 004 GWTP removed greater than 99% of PFAS7 from the
combined flow of the GWEC and Ex -Situ Capture Systems.
Performance monitoring activities, including hydraulic head monitoring and surface water
sampling, are also documented in this Report. Similar to the previous reporting period,
performance monitoring indicates that the GWEC system has resulted in a reduction in gradient
between the barrier wall and the Cape Fear River, thus reducing groundwater PFAS flux to the
Cape Fear River. This reduction in PFAS mass discharge is evident in the diminished flows into
the FTCs and is also documented in a report for the Mass Loading Model (MLM) program,
submitted for the same reporting period concurrent to this Report (Geosyntec, 2024a).
Collectively, the Willis Creek EWs are exerting drawdown of the Black Creek aquifer along the
length of the alignment, particularly in the midsection, with nearly 8 feet of groundwater elevation
reduction observed in monitoring wells. Drawdown along the alignment has also resulted in four
EWs with insufficient water to pump, as compared to startup, demonstrating overlapping influence
within the EWs from the collective pumping. The extensive drawdown is a line of evidence of
hydraulic control. Additionally, a reduction in Willis Creek mass discharges has been observed.
At sampling locations WC-2 (upstream) and WC-1 (downstream near the confluence with the Cape
Fear River), the post -startup mass discharge to Willis Creek along this reach is estimated to be
approximately 60% less than pre -startup.
7 As measured by indicator parameters hexafluoropropylene oxide dimer (HFPO-DA), perfluoromethoxypropyl
carboxylic acid (PMPA), and perfluoro-2-methoxyaceticacid (PFMOAA)
TR0795 — CFR Long -Term Remedy Performance Monitoring Report #5 25 June 2024
Geosyntec
consultants
Geosyntec Consultants of NC, P.C.
NC License No.: C-3500 and C-295
8 REFERENCES
AECOM, 2018. Poly and Perfluoroalkyl Substance Quality Assurance Project Plan For the
Chemours Corporate Remediation Group. August 2018.
Geosyntec, 2020a. Matrix Interference During Analysis of Table 3+ Compounds. Chemours
Fayetteville Works. June 30, 2020.
Geosyntec, 2020b. Interim Seep Remediation System Plan. Chemours Fayetteville Works. August
31, 2020.
Geosyntec, 2021. Pre -Design Investigation Summary (Version 2). Chemours Fayetteville Works.
June 29, 2021.
Geosyntec, 2022. Groundwater and Seeps Remedy 90% Design Submittal. Chemours Fayetteville
Works. March 25, 2022.
Geosyntec, 2023a. Interim Seep Remediation Operation and Maintenance Report #14. Chemours
Fayetteville Works. May 31, 2023.
Geosyntec, 2023b. CFR Long -Term Remedy Performance Monitoring Report # 1 (previously titled
as Groundwater and Seeps Remediation Report #1). Chemours Fayetteville Works. June 29,
2023.
Geosyntec, 2023c. CFR Long -Term Remedy Performance Monitoring Report #2. Chemours
Fayetteville Works. September 29, 2023.
Geosyntec, 2023d. CFR Long -Term Remedy Performance Monitoring Report #3. Chemours
Fayetteville Works. December 22, 2023.
Geosyntec, 2024a. CFR Long -Term Remedy Performance Monitoring Report #4. Chemours
Fayetteville Works. March 28, 2024.
Geosyntec, 2024b. Cape Fear River PFAS Mass Loading Assessment - Fourth Quarter 2023
Report. Chemours Fayetteville Works. March 28, 2024.
Geosyntec, 2024c. Cape Fear River HAS Mass Loading Assessment - First Quarter 2024 Report.
Chemours Fayetteville Works. June 27, 2024.
USEPA, 2009. USEPA Guidance for Labeling Externally Validated Laboratory Analytical Data
for Superfund Use. USEPA-540-R-08-005. OSWER 9200.1-85. Office of Solid Waste and
Emergency Response, United States Environmental Protection Agency. January 13, 2009.
TR0795 - CFR Long -Term Remedy Performance Monitoring Report #5 26 June 2024
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consultants
Tables
Geosyntec Consultants of NC, P.C.
NC License No.: C-3500 and C-295
TR0795C
Table 1-1
Summary of Sampling and Monitoring Activities
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Remedy Component
Sampling and Monitoring Activities in Reporting Period (Jan -Mar)
In -Situ Seep Flow-
During prolonged no -flow conditions, the FTCs were generally operated in batch mode (closed to flow) and thus there is no process flow to sample. The FTCs were opened to
Through Cells (FTCs)
flow as needed to manage accumulated water in the impoundments. When open to flow, 24-hour composite samples were collected for performance monitoring; water quality was
monitored and sampled in the same 24-hour period as the performance monitoring interval; and weekly grab samples for breakthrough monitoring were collected.
Ex -Situ Seeps and
Weeps Capture
•Flow rates and totalized flow every 15 minutes from each capture system
Groundwater
Extraction
■ Extraction Well Operational Data (flow, pressure, motor speed, and water level) every 15 minutes
■ Weekly grab sampling of Effluent for PFAS indicator compounds HFPO-DA, PFMOAA, and PMPA
004 Treatment Plant
• Monthly grab sampling of Influent and Effluent for Table 3+
■ Quarterly grab sampling of Influent and Effluent for Table 3+ and EPA Method 537 MOD
■ Various other parameters required per the NPDES permit and reported in the eDMR, but not reproduced here
■ Monthly water level gauging (January 31, February 27, and March 27, 2024)
Performance
■ Quarterly surface water PFAS sampling at four transects of the Cape Fear River (March 12, 2024)
Evaluation
■ Quarterly PFAS sampling of Willis Creek (WC) stations WC-1, 2, 3 (February 22, 2024)
■ PFAS sampling of downgradient monitoring wells under the MLM (quarterly) and PMP (semi-annually) sampling programs (January 15 to February 6, 2024)
Notes:
1 - Additional sampling details (e.g., Sample IDs, composite periods, etc.) are provided in subsequent tables.
PFAS - per- and polyfluoroalkyl substances HFPO-DA - hexafluoropropylene oxide-dimer acid
PFMOAA - perfluoro-2-methoxyacetic acid PMPA - perfluoro-2-methoxypropionic acid
EPA - Environmental Protection Agency NPDES - National Pollutant Discharge Elimination System
PMP - Performance Monitoring Plan
eDMR - electronic Discharge Monitoring Report
MLM - Mass Loading Model
TR0795C Page 1 of 1 June 2024
Table 2-1A
FTC Operations and Maintenance Summary - Seep A
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Date
Days Since
Start=
Bypass
Spillway
Flow?
Sampling Performed
Operational Mode
Transducers
Downloaded
Maintenance Activities Completed
Breakthrough
Monitorin
Performance
Monitorin
Wet Weather
Monitoring
Arrival
Departure
FB1
FB2
FBI
FB2
01/02/2024
980
No
Series
Batch Mode
X
Closed inlet and mid valves.
01/03/2024
981
No
Batch Mode
Batch Mode
N/A
01/04/2024
982
No
Batch Mode
Batch Mode
N/A
01/05/2024
983
No
Batch Mode
Series
Opened inlet and mid valves.
01/06/2024
984
--
X
Series
Series
N/A
01/07/2024
985
No
Series
Series
N/A
01/08/2024
986
No
X
Series
Series
X
N/A
01/09/2024
987
Yes
Series
Series
N/A
01/10/2024
988
Yes
X
Series
Parallel
N/A
01/16/2024
994
Yes
Parallel
Parallel
X
N/A
01/17/2024
995
No
Parallel
Parallel
N/A
01/18/2024
996
No
Parallel
Series
Skimmed and fluffed FBI and FB2.
01/19/2024
997
No
Series
Series
N/A
01/20/2024
998
--
X
Series
Series
N/A
01/22/2024
1,000
No
X
Series
Series
X
N/A
01/23/2024
1,001
No
Series
Series
N/A
01/24/2024
1,002
No
Series
Series
N/A
01/25/2024
1,003
No
Series
Series
N/A
01/26/2024
1,004
No
Series
Series
N/A
01/29/2024
1,007
No
X
Series
Series
X
N/A
01/30/2024
1,008
No
Series
Series
N/A
01/31/2024
1,009
No
X
Series
Series
N/A
02/01/2024
1,010
No
X
X
Series
Series
N/A
02/02/2024
1,011
No
Series
Batch Mode
Closed inlet and mid valves.
02/05/2024
1,014
No
Batch Mode
Batch Mode
X
N/A
02/06/2024
1,015
No
Batch Mode
Batch Mode
N/A
02/07/2024
1,016
No
Batch Mode
Batch Mode
N/A
02/08/2024
1,017
No
Batch Mode
Batch Mode
N/A
02/09/2024
1,018
No
Batch Mode
Series
Opened inlet and mid valves.
02/12/2024
1,021
No
Series
Series
X
N/A
02/13/2024
1,022
No
X
Series
Series
N/A
02/14/2024
1,023
No
X
Series
Series
N/A
02/15/2024
1,024
No
Series
Series
N/A
02/16/2024
1,025
No
Series
Series
Skimmed and fluffed FB2.
02/19/2024
1,028
No
Series
Batch Mode
X
Closed inlet and mid valves.
02/20/2024
1,029
No
Batch Mode
Batch Mode
N/A
02/21/2024
1,030
No
Batch Mode
Batch Mode
N/A
02/22/2024
1,031
No
Batch Mode
Batch Mode
N/A
02/23/2024
1,032
No
Batch Mode
Batch Mode
N/A
02/26/2024
1,035
No
Batch Mode
Batch Mode
X
N/A
02/27/2024
1,036
No
Batch Mode
Batch Mode
N/A
02/28/2024
1,037
No
Batch Mode
Batch Mode
N/A
02/29/2024
1,038
1 No
Batch Mode
Batch Mode
N/A
TR0795C Pagel of 8 June 2024
Table 2-1A
FTC Operations and Maintenance Summary - Seep A
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Date
Days Since
Start=
Bypass
Spillway
Flow?
Sampling Performed
Operational Mode
Transducers
Downloaded
Maintenance Activities Completed
Breakthrough
Monitorin
Performance
Monitorin
Wet Weather
Monitoring
Arrival
Departure
FB1
FB2
FBI
FB2
03/01/2024
1,039
No
X
Batch Mode
Series
Opened inlet and mid valves.
03/02/2024
1,040
No
X
Series
Series
N/A
03/04/2024
1,042
No
Series
Series
X
N/A
03/05/2024
1,043
No
Series
Series
N/A
03/06/2024
1,044
No
Series
Closed Lead
N/A
03/07/2024
1,045
Yes
X
Closed
I Lead
Parallel
N/A
03/08/2024
1,046
No
Parallel
Series
Skimmed and fluffed FBI and FB2.
03/10/2024
1,048
No
Series
Series
N/A
03/11/2024
1,049
No
X
X
Series
Closed
Lead
X
N/A
03/12/2024
1,050
No
Closed
Lead
Closed
I Lead
N/A
03/13/2024
1,051
No
Closed
Lead
Series
Pumped water into cell. Skimmed and fluffed FB2.
03/14/2024
1,052
No
Series
Batch Mode
Closed inlet and mid valves.
03/15/2024
1,053
No
Batch Mode
Batch Mode
Pumped water into cell.
03/18/2024
1,056
No
X
Batch Mode
Batch Mode
X
N/A
03/19/2024
1,057
No
Batch Mode
Batch Mode
N/A
03/20/2024
1,058
No
Batch Mode
Batch Mode
N/A
03/21/2024
1,059
No
Batch Mode
Batch Mode
N/A
03/22/2024
1,060
No
Batch Mode
Series
Opened inlet and mid valves.
03/23/2024
1,061
--
X
Series
Series
N/A
03/25/2024
1,063
No
Series
Series
X
N/A
03/26/2024
1,064
No
Series
Series
N/A
03/27/2024
1,065
No
Series
Series
N/A
03/28/2024
1,066
No
X
Series
Series
N/A
03/29/2024
1,067
No
Series
Batch Mode
Closed inlet and mid valves.
Notes:
1 - Batch Mode indicates the inlet and transfer basin valves were closed and the flow -through cell experienced no flow.
2 - The "Notes" column that previously documented instances of flow and amount of freeboard observed has been replaced by Figures 2-2A-D and Figures 2-5A-D, showing discharge flow rates and staff gauge data at FTCs A-D.
FBI - Filter Bed 1
FB2 - Filter Bed 2
N/A - Not Applicable
TR0795C Page 2 of 8 June 2024
Table 2-1B
FTC Operations and Maintenance Summary - Seep B
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Date
Days Since
Start=
Bypass
Spillway
Flow?
Sampling Performed
Operational Mode
Transducers
Downloaded
Maintenance Activities Completed
Breakthrough
Monitorin
Performance
Monitorin
Wet Weather
Monitoring
Arrival
Departure
FB1
FB2
FBI
FB2
01/02/2024
939
No
Series
Batch Mode
X
Closed inlet and mid valves.
01/03/2024
940
No
Batch Mode
Batch Mode
N/A
01/04/2024
941
No
Batch Mode
Batch Mode
N/A
01/05/2024
942
No
Batch Mode
Batch Mode
N/A
01/07/2024
944
No
Batch Mode
Batch Mode
N/A
01/08/2024
945
No
Batch Mode
Batch Mode
X
N/A
01/09/2024
946
No
Batch Mode
Series
Opened inlet and mid valves.
01/10/2024
947
No
X
Series
Series
N/A
01/16/2024
953
No
Series
Series
X
N/A
01/17/2024
954
No
Series
Series
N/A
01/18/2024
955
No
Series
Series
N/A
01/19/2024
956
No
Series
Series
Skimmed and fluffed FBI and FB2 and replaced fabric.
01/20/2024
957
--
X
Series
Series
N/A
01/22/2024
959
No
X
Series
Series
X
N/A
01/23/2024
960
No
Series
Series
N/A
01/24/2024
961
No
Series
Series
N/A
01/25/2024
962
No
X
Series
Series
N/A
01/26/2024
963
No
Series
Series
N/A
01/29/2024
966
No
X
Series
Series
X
N/A
01/30/2024
967
No
Series
Series
N/A
01/31/2024
968
No
X
Series
Series
N/A
02/01/2024
969
No
X
X
Series
Batch Mode
Closed inlet and mid valves.
02/02/2024
970
No
Batch Mode
Batch Mode
N/A
02/05/2024
973
No
Batch Mode
Batch Mode
X
N/A
02/06/2024
974
No
Batch Mode
Batch Mode
N/A
02/07/2024
975
No
Batch Mode
Batch Mode
N/A
02/08/2024
976
No
Batch Mode
Batch Mode
N/A
02/09/2024
977
No
Batch Mode
Series
Opened inlet and mid valves.
02/12/2024
980
No
Series
Series
X
N/A
02/13/2024
981
No
X
Series
Series
N/A
02/14/2024
982
No
X
Series
Series
N/A
02/15/2024
983
No
Series
Series
N/A
02/16/2024
984
No
Series
Batch Mode
Closed inlet and mid valves.
02/19/2024
987
No
Batch Mode
Batch Mode
X
N/A
02/20/2024
988
No
Batch Mode
Batch Mode
N/A
02/21/2024
989
No
Batch Mode
Closed I Batch Mode
N/A
02/22/2024
990
No
Changeout I Batch Mode
Batch Mode
Carbon changeout FBI.
02/23/2024
991
No
Batch Mode
Batch Mode
N/A
02/26/2024
994
No
Batch Mode
Batch Mode
X
N/A
02/27/2024
995
No
Batch Mode
Batch Mode
N/A
02/28/2024
996
No
Batch Mode
Batch Mode
N/A
02/29/2024
997
No
Batch Mode
Batch Mode
N/A
TR0795C Page 3 of 8 June 2024
Table 2-1B
FTC Operations and Maintenance Summary - Seep B
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Date
Days Since
Start=
Bypass
Spillway
Flow?
Sampling Performed
Operational Mode
Transducers
Downloaded
Maintenance Activities Completed
Breakthrough
Monitorin
Performance
Monitorin
Wet Weather
Monitoring
Arrival
Departure
FB1
FB2
FBI
FB2
03/O1/2024
998
No
X
Batch Mode
Series
Opened inlet and mid valves.
03/02/2024
999
No
X
Series
Series
N/A
03/04/2024
1,001
No
Series
Series
X
N/A
03/05/2024
1,002
No
Series
Series
N/A
03/06/2024
1,003
No
Series
Series
N/A
03/07/2024
1,004
No
X
Series
Series
N/A
03/08/2024
1,005
No
Series
Series
N/A
03/10/2024
1,007
No
Series
Series
N/A
03/11/2024
1,008
No
X
X
Series
Series
X
N/A
03/12/2024
1,009
No
Series
Batch Mode
Closed inlet and mid valves.
03/13/2024
1,010
No
Batch Mode
Batch Mode
N/A
03/14/2024
1,011
No
Batch Mode
Batch Mode
N/A
03/15/2024
1,012
No
Batch Mode
Batch Mode
N/A
03/18/2024
1,015
No
Batch Mode
Batch Mode
X
N/A
03/19/2024
1,016
No
Batch Mode
Batch Mode
N/A
03/20/2024
1,017
No
Batch Mode
Batch Mode
N/A
03/21/2024
1,018
No
Batch Mode
Batch Mode
N/A
03/22/2024
1,019
No
Batch Mode
Series
Opened inlet and mid valves.
03/23/2024
1,020
--
X
Series
Series
N/A
03/25/2024
1,022
No
Series
Series
X
N/A
03/26/2024
1,023
No
Series
Series
N/A
03/27/2024
1,024
No
Series
Series
N/A
03/28/2024
1,025
No
X
Series
Series
N/A
03/29/2024
1,026
No
Series
Batch Mode
Closed inlet and mid valves.
Notes:
1 - Batch Mode indicates the inlet and transfer basin valves were closed and the flow -through cell experienced no flow.
2 - The "Notes" column that previously documented instances of flow and amount of freeboard observed has been replaced by Figures 2-2A-D and Figures 2-5A-D, showing discharge flow rates and staff gauge data at FTCs A-D.
FBI - Filter Bed 1
FB2 - Filter Bed 2
N/A - Not Applicable
TR0795C Page 4 of 8 June 2024
Table 2-1C
FTC Operations and Maintenance Summary - Seep C
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Days Since
Startup
Bypass
Spillway
Flow?
Sampling Performed
Operational Mode
Transducers
Downloaded
Maintenance Activities Completed
Breakthrough
Monitoring
Performance
Monitoring
Wet Weather
Monitoring
Arrival
Departure
FB1
FB2
FBI ITFB2
01/02/2024
1,113
No
X
Series
Series
X
N/A
01/03/2024
1,114
No
Series
Series
N/A
01/04/2024
1,115
No
Changeout I Lead
Series
Carbon changeout FBI.
01/05/2024
1,116
No
Series
Series
N/A
01/06/2024
1,117
-
X
Series
Series
N/A
01/07/2024
1,118
No
Series
Closed I Lead
FB2 run in sole.
01/08/2024
1,119
No
X
Series
Parallel
X
N/A
01/09/2024
1,120
No
Parallel
Parallel
N/A
01/10/2024
1,121
No
X
Parallel
Parallel
N/A
01/16/2024
1,127
Yes
Parallel
Parallel
X
N/A
01/17/2024
1,128
No
Parallel
Lag F Lead
Skimmed and fluffed FBI and FB2.
01/18/2024
1,129
No
Series
Series
N/A
01/19/2024
1,130
No
Series
Series
N/A
01/20/2024
1,131
--
X
Series
Series
N/A
01/22/2024
1,133
No
X
Series
Series
X
N/A
01/23/2024
1,134
No
Series
Series
N/A
01/24/2024
1,135
No
Series
Series
N/A
01/25/2024
1,136
No
Series
Series
N/A
01/26/2024
1,137
No
Series
Series
N/A
01/29/2024
1,140
No
X
Series
Series
X
N/A
01/30/2024
1,141
No
Series
Series
N/A
01/31/2024
1,142
No
X
Series
Series
N/A
02/01/2024
1,143
No
X
X
Series
Series
N/A
02/02/2024
1,144
No
Series
Batch Mode
Closed inlet and mid valves.
02/05/2024
1,147
No
Batch Mode
Batch Mode
X
N/A
02/06/2024
1,148
No
Batch Mode
Batch Mode
N/A
02/07/2024
1,149
No
Batch Mode
Batch Mode
N/A
02/08/2024
1,150
No
Batch Mode
Batch Mode
N/A
02/09/2024
1,151
No
Batch Mode
Series
Opened inlet and mid valves.
02/12/2024
1,154
No
Series
Closed
Lead
X
Placed FB2 in sole processing.
02/13/2024
1,155
No
X
Closed
Lead
Closed
Lead
N/A
02/14/2024
1,156
No
X
Closed
Lead
Series
Skimmed and fluffed F132.
02/15/2024
1,157
No
Series
Series
N/A
02/16/2024
1,158
No
Series
Batch Mode
Closed inlet and mid valves.
02/19/2024
1,161
No
Batch Mode
Batch Mode
X
N/A
02/20/2024
1,162
No
Batch Mode
Batch Mode
N/A
02/21/2024
1,163
No
Batch Mode
Batch Mode
N/A
02/22/2024
1,164
No
Batch Mode
Series
Opened inlet and mid valves.
02/23/2024
1,165
No
Series
Series
N/A
02/24/2024
1,166
--
X
Series
Series
N/A
02/26/2024
1,168
No
Series
Batch Mode
X
Closed inlet and mid valves.
02/27/2024
1,169
No
Batch Mode
Batch Mode
N/A
02/28/2024
1,170
No
Batch Mode
Batch Mode
N/A
02/29/2024
1,171
No
Batch Mode
Batch Mode
N/A
TR0795C Page 5 of 8 June 2024
Table 2-1C
FTC Operations and Maintenance Summary - Seep C
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
k03/01/2024
Days Since
Startup
Bypass
Spillway
Flow?
Sampling Performed
Operational Mode
Transducers
Downloaded
Maintenance Activities Completed
Breakthrough
Monitoring
Performance
Monitoring
Wet Weather
Monitoring
Arrival
Departure
FB1
FB2
FBI ITFB2
1,172
No
X
Batch Mode
Series
Opened inlet and mid valves.
03/02/2024
1,173
No
X
Series
Closed
Lead
Placed FB2 in sole processing.
03/04/2024
1,175
No
Closed I Lead
Series
X
N/A
03/05/2024
1,176
No
Series
Series
Skimmed and fluffed FB2.
03/06/2024
1,177
Yes
Series
Closed
Lead
N/A
03/07/2024
1,178
No
X
Closed
Lead
Closed
Lead
N/A
03/08/2024
1,179
No
Closed
Lead
Series
Skimmed and fluffed FB2.
03/10/2024
1,181
No
Series
Series
N/A
03/11/2024
1,182
No
X
X
Series
Series
X
N/A
03/12/2024
1,183
No
Series
Series
N/A
03/13/2024
1,184
No
Series
Series
N/A
03/14/2024
1,185
No
Series
Series
N/A
03/15/2024
1,186
No
Series
Batch Mode
Closed inlet and mid valves. Pumped water into cell.
03/18/2024
1,189
No
X
Batch Mode
Batch Mode
X
Skimmed and fluffed FB2.
03/19/2024
1,190
No
Batch Mode
Batch Mode
N/A
03/20/2024
1,191
No
Batch Mode
Batch Mode
Pumped water into cell.
03/21/2024
1,192
No
Batch Mode
Batch Mode
N/A
03/22/2024
1,193
No
Batch Mode
Series
Opened inlet and mid valves.
03/23/2024
1,194
--
X
Series
Series
N/A
03/25/2024
1,196
No
Series
Series
X
N/A
03/26/2024
1,197
No
Series
Series
N/A
03/27/2024
1,198
No
Series
Series
N/A
03/28/2024
1,199
Yes
X
Series
Series
N/A
03/29/2024
1,200
No
Series
Series
Skimmed and fluffed FB2.
Notes:
1 - Batch Mode indicates the inlet and transfer basin valves were closed and the flow -through cell experienced no flow.
2 - The "Notes" column that previously documented instances of flow and amount of freeboard observed has been replaced by Figures 2-2A-D and Figures 2-5A-D, showing discharge flow rates and staff gauge data at FTCs A-D.
FBI - Filter Bed 1
FB2 - Filter Bed 2
N/A - Not Applicable
TR0795C Page 6 of 8 June 2024
Table 2-1D
FTC Operations and Maintenance Summary - Seep D
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Date
Days Since
Startu
Bypass
Spillway
Flow?
Sampling Performed
Operational Mode
Transducers
Downloaded
Maintenance Activities Completed
Breakthrough
Monitoring
Performance
Monitoring
Wet Weather
Monitoring
Arrival
Departure
FB1
FB2
FB1
FB2
01/02/2024
923
No
Series
Batch Mode
X
Closed inlet and mid valves.
01/03/2024
924
No
Batch Mode
Batch Mode
N/A
01/04/2024
925
No
Batch Mode
Batch Mode
N/A
01/05/2024
926
No
Batch Mode
Batch Mode
N/A
01/07/2024
928
No
Batch Mode
Batch Mode
N/A
01/08/2024
929
No
Batch Mode
Batch Mode
X
N/A
01/09/2024
930
No
Batch Mode
Series
Opened inlet and mid valves.
01/10/2024
931
No
X
Series
Series
N/A
01/16/2024
937
Yes
Series
Series
X
N/A
01/17/2024
938
No
Series
Series
N/A
01/18/2024
939
No
Series
Series
Skimmed and fluffed FBI and FB2.
01/19/2024
940
No
Series
Series
N/A
01/20/2024
941
--
X
Series
Series
N/A
01/22/2024
943
No
X
Series
Series
X
Backflushed FB2.
01/23/2024
944
No
Series
Series
Skimmed and fluffed F132.
01/24/2024
945
No
Series
Series
N/A
01/25/2024
946
No
X
Series
Series
N/A
01/26/2024
947
No
Series
Series
N/A
01/29/2024
950
No
X
Series
Series
X
N/A
01/30/2024
951
No
Series
Series
N/A
01/31/2024
952
No
X
Series
Lead
Closed
N/A
02/01/2024
953
No
X
X
Lead
Closed
Lead
I Closed
Removed carbon at FB2.
02/02/2024
954
No
Lead
Changeout
Batch Mode
Carbon changeout at FB2. Closed inlet and mid valves.
02/05/2024
957
No
Batch Mode
Batch Mode
X
N/A
02/06/2024
958
No
Batch Mode
Batch Mode
N/A
02/07/2024
959
No
Batch Mode
Batch Mode
N/A
02/08/2024
960
No
Batch Mode
Batch Mode
N/A
02/09/2024
961
No
Batch Mode
Series
Opened inlet and mid valves.
02/12/2024
964
No
Series
Series
X
N/A
02/13/2024
965
No
X
Series
Series
N/A
02/14/2024
966
No
X
Series
Series
N/A
02/15/2024
967
No
Series
Series
N/A
02/16/2024
968
No
Series
Batch Mode
Closed inlet and mid valves.
02/19/2024
971
No
Batch Mode
Batch Mode
X
N/A
02/20/2024
972
No
Batch Mode
Batch Mode
N/A
02/21/2024
973
No
Batch Mode
Batch Mode
N/A
02/22/2024
974
No
Batch Mode
Batch Mode
N/A
02/23/2024
975
No
Batch Mode
Batch Mode
N/A
02/26/2024
978
No
Batch Mode
Batch Mode
X
N/A
02/27/2024
979
No
Batch Mode
Batch Mode
N/A
02/28/2024
980
No
Batch Mode
Batch Mode
N/A
02/29/2024
981
No
Batch Mode
Batch Mode
N/A
TR0795C Page 7 of 8 June 2024
Table 2-1D
FTC Operations and Maintenance Summary - Seep D
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Date
Days Since
Start=
Bypass
Spillway
Flow?
Sampling Performed
Operational Mode
Transducers
Downloaded
Maintenance Activities Completed
Breakthrough
Monitorin
Performance
Monitorin
Wet Weather
Monitoring
Arrival
Departure
FB1
FB2
FBI
FB2
982
No
X
Batch Mode
Series
Opened inlet and mid valves.
03/02/2024
983
No
X
Series
Series
N/A
03/04/2024
985
No
Series
Series
X
N/A
03/05/2024
986
No
Series
Series
N/A
03/06/2024
987
No
Series
Series
N/A
03/07/2024
988
No
X
Series
Series
N/A
03/08/2024
989
No
Series
Series
N/A
03/10/2024
991
No
Series
Series
N/A
03/11/2024
992
No
X
X
Series
Series
X
N/A
03/12/2024
993
No
Series
Batch Mode
Closed inlet and mid valves.
03/13/2024
994
No
Batch Mode
Batch Mode
N/A
03/14/2024
995
No
Batch Mode
Batch Mode
N/A
03/15/2024
996
No
Batch Mode
Batch Mode
N/A
03/18/2024
999
No
Batch Mode
Batch Mode
X
N/A
03/19/2024
1,000
No
Batch Mode
Batch Mode
N/A
03/20/2024
1,001
No
Batch Mode
Batch Mode
N/A
03/21/2024
1,002
No
Batch Mode
Batch Mode
N/A
03/22/2024
1,003
No
Batch Mode
Series
Opened inlet and mid valves.
03/23/2024
1,004
--
X
Series
Series
N/A
03/25/2024
1,006
No
Series
Series
X
N/A
03/26/2024
1,007
No
Series
Series
Skimmed and fluffed FBI.
03/27/2024
1,008
No
Series
Series
N/A
03/28/2024
1,009
No
X
Series
Series
N/A
03/29/2024
1,010
No
Series
Batch Mode
Closed inlet and mid valves.
Notes:
1 - Batch Mode indicates the inlet and transfer basin valves were closed and the flow -through cell experienced no flow.
2 - The "Notes" column that previously documented instances of flow and amount of freeboard observed has been replaced by Figures 2-2A-D and Figures 2-5A-D, showing discharge flow rates and staff gauge data at FTCs A-D.
FBI - Filter Bed 1
FB2 - Filter Bed 2
N/A - Not Applicable
TR0795C Page 8 of 8 June 2024
Table 2-2
Cape Fear River Elevation and Local Precipitation Statistics
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
Seep
# of Days of
Operation on Record
Percent of Operation Over Lifetime of System[21
River Above FTC
Wall Elevation
River Above Bypass
Spillway Elevation
River Above GAC
Elevation
River Above Discharge
Pipe Invert Elevation
C
1,202
1.7%
2.2%
3.9%
9.8%
A
1,069
1.0%
1.2%
2.2%
6.4%
B
1,028
0.8%
1.1%
1.7%
4.5%
D
1,012
1.1%
1.2%
2.4%
6.8%
Historical Annual Average (2007-2020) E3'41
1.7%
2.2%
3.7%
9.6%
Precipitation (inches)
Current Reporting Period (January - March 2024)
9.49
Current Reporting Period Historical Average (January - March 2004-2020) "'
7.96
2024 Year -to -Date
9.49
Historical Year -to -Date Average (2004-2020) [5]
7.96
Historical Annual Average (2004-2020) E51
43.44
Notes:
1 - River elevation and precipitation data obtained from the USGS gauge #02105500 at the William O. Huske Lock and Dam.
2 - Operational period for river flooding statistics includes the entire lifetime of the system for each seep.
3 - Seeps A and D are approximately 1 foot lower in elevation than Seeps B and C.
4 - For clarity of presentation, historical river flooding averages based on Seep C elevations only.
5 - The historical average was calculated using available data when the Huske rain gauge was operable.
TR0795C Pagel of 1 June 2024
Table 2-3A
FTC Sampling Summary - Seep A
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Performance Monitoring Composite Samples
Sample ID
Composite Period
Sample Date
SEEP-A-INFLUENT-24-010624
January 6, 2024
January 6, 2024
SEEP-A-EFFLUENT-24-010624
SEEP-A-INFLUENT-24-011024
January 9 - January 10, 2024
January 10, 2024
SEEP-A-EFFLUENT-24-011024
SEEP-A-INFLUENT-24-012024
January 20, 2024
January 20, 2024
SEEP-A-EFFLUENT-24-012024
SEEP-A-INFLUENT-24-013124
January 30 - January 31, 2024
January 31, 2024
SEEP-A-EFFLUENT-24-013124
SEEP-A-INFLUENT-24-020124
January 31 - February 1, 2024
February 1, 2024
SEEP-A-EFFLUENT-24-020124
SEEP-A-INFLUENT-24-021324
February 12 - February 13, 2024
February 13, 2024
SEEP-A-EFFLUENT-24-021324
SEEP-A-INFLUENT-24-021424
February 13 - February 14, 2024
February 14, 2024
SEEP-A-EFFLUENT-24-021424
SEEP-A-INFLUENT-24-030224
March 1 - March 2, 2024
March 2, 2024
SEEP-A-EFFLUENT-24-030224
SEEP-A-INFLUENT-24-030724
March 6 - March 7, 2024
March 7, 2024
SEEP-A-EFFLUENT-24-030724
SEEP-A-INFLUENT-24-031124
March 10 - March 11, 2024
March 11, 2024
SEEP-A-EFFLUENT-24-031124
SEEP-A-INFLUENT-24-032324
March 23, 2024
March 23, 2024
SEEP-A-EFFLUENT-24-032324
SEEP-A-INFLUENT-24-032824
March 27 - March 28, 2024
March 28, 2024
SEEP-A-EFFLUENT-24-032824
Notes:
I- Sample Identification Label Key: "Seep -[A, B, C, or D] -[Sample Location Inside FTC] - [# of Aliquots in Composite Sample] - [MMDDYY]"
2 - The FTC was operating under batch mode for part of January, February, and March 2024. Performance samples were not collected while the FTC was
closed.
TR0795C Page 1 of 4 June 2024
Table 2-3B
FTC Sampling Summary - Seep B
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Performance Monitoring Composite Samples
Sample ID
Composite Period
Sample Date
SEEP-B-INFLUENT-24-011024
January 9 - January 10, 2024
January 10, 2024
SEEP-B-EFFLUENT-24-011024
SEEP-B-INFLUENT-24-012024
January 20, 2024
January 20, 2024
SEEP-B-EFFLUENT-24-012024
SEEP-B-INFLUENT-24-012524
January 24 - January 25, 2024
January 25, 2024
SEEP-B-EFFLUENT-24-012524
SEEP-B-INFLUENT-24-013124
January 30 - January 31, 2024
January 31, 2024
SEEP-B-EFFLUENT-24-013124
SEEP-B-INFLUENT-24-020124
January 31 - February 1, 2024
February 1, 2024
SEEP-B-EFFLUENT-24-020124
SEEP-B-INFLUENT-24-021324
February 12 - February 13, 2024
February 13, 2024
SEEP-B-EFFLUENT-24-021324
SEEP-B-INFLUENT-24-021424
February 13 - February 14, 2024
February 14, 2024
SEEP-B-EFFLUENT-24-021424
SEEP-B-INFLUENT-24-030224
March 1 - March 2, 2024
March 2, 2024
SEEP-B-EFFLUENT-24-030224
SEEP-B-INFLUENT-24-030724
March 6 - March 7, 2024
March 7, 2024
SEEP-B-EFFLUENT-24-030724
SEEP-B-INFLUENT-24-031124
March 10 - March 11, 2024
March 11, 2024
SEEP-B-EFFLUENT-24-031124
SEEP-B-INFLUENT-24-032324
March 23, 2024
March 23, 2024
SEEP-B-EFFLUENT-24-032324
SEEP-B-INFLUENT-24-032824
March 27 - March 28, 2024
March 28, 2024
SEEP-B-EFFLUENT-24-032824
Notes:
I- Sample Identification Label Key: "Seep -[A, B, C, or D] -[Sample Location Inside FTC] - [# of Aliquots in Composite Sample] - [MMDDYY]"
2 - The FTC was operating under batch mode for part of January, February, and March 2024. Performance samples were not collected while the FTC was
closed.
TR0795C Page 2 of 4 June 2024
Table 2-3C
FTC Sampling Summary - Seep C
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Performance Monitoring Composite Samples
Sample ID
Composite Period
Sample Date
SEEP-C-INFLUENT-24-010624
January 6, 2024
January 6, 2024
SEEP-C-EFFLUENT-24-010624
SEEP-C-INFLUENT-24-011024
January 9 - January 10, 2024
January 10, 2024
SEEP-C-EFFLUENT-24-011024
SEEP-C-INFLUENT-24-012024
January 20, 2024
January 20, 2024
SEEP-C-EFFLUENT-24-012024
SEEP-C-INFLUENT-24-013124
January 30 - January 31, 2024
January 31, 2024
SEEP-C-EFFLUENT-24-013124
SEEP-C-INFLUENT-24-020124
January 31 - February 1, 2024
February 1, 2024
SEEP-C-EFFLUENT-24-020124
SEEP-C-INFLUENT-24-021324
February 12 - February 13, 2024
February 13, 2024
SEEP-C-EFFLUENT-24-021324
SEEP-C-INFLUENT-24-021424
February 13 - February 14, 2024
February 14, 2024
SEEP-C-EFFLUENT-24-021424
SEEP-C-INFLUENT-24-022424
February 23 - February 24, 2024
February 24, 2024
SEEP-C-EFFLUENT-24-022424
SEEP-C-INFLUENT-24-030224
March 1 - March 2, 2024
March 2, 2024
SEEP-C-EFFLUENT-24-030224
SEEP-C-INFLUENT-24-030724
March 6 - March 7, 2024
March 7, 2024
SEEP-C-EFFLUENT-24-030724
SEEP-C-INFLUENT-24-031124
March 10 - March 11, 2024
March 11, 2024
SEEP-C-EFFLUENT-24-031124
SEEP-C-INFLUENT-24-032324
March 23, 2024
March 23, 2024
SEEP-C-EFFLUENT-24-032324
SEEP-C-INFLUENT-24-032824
March 27 - March 28, 2024
March 28, 2024
SEEP-C-EFFLUENT-24-032824
Notes:
I- Sample Identification Label Key: "Seep -[A, B, C, or D] -[Sample Location Inside FTC] - [# of Aliquots in Composite Sample] - [MMDDYY]"
2 - The FTC was operating under batch mode for part of February and March 2024. Performance samples were not collected while the FTC was closed.
TR0795C Page 3 of 4 June 2024
Table 2-3D
FTC Sampling Summary - Seep D
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Performance Monitoring Composite Samples
Sample ID
Composite Period
Sample Date
EEP-D-INFLUENT-24-011024
!SEEP-D-EFFLUENT-24-011024
January 9 - January 10, 2024
January 10, 2024
SEEP-D-INFLUENT-24-012024
January 20, 2024
January 20, 2024
SEEP-D-EFFLUENT-24-012024
SEEP-D-INFLUENT-24-012524
January 24 - January 25, 2024
January 25, 2024
SEEP-D-EFFLUENT-24-012524
SEEP-D-INFLUENT-24-013124
January 30 - January 31, 2024
January 31, 2024
SEEP-D-EFFLUENT-24-013124
SEEP-D-INFLUENT-24-020124
January 31 - February 1, 2024
February 1, 2024
SEEP-D-EFFLUENT-24-020124
SEEP-D-INFLUENT-24-021324
February 12 - February 13, 2024
February 13, 2024
SEEP-D-EFFLUENT-24-021324
SEEP-D-INFLUENT-24-021424
February 13 - February 14, 2024
February 14, 2024
SEEP-D-EFFLUENT-24-021424
SEEP-D-INFLUENT-24-030224
March 1 - March 2, 2024
March 2, 2024
SEEP-D-EFFLUENT-24-030224
SEEP-D-INFLUENT-24-030724
March 6 - March 7, 2024
March 7, 2024
SEEP-D-EFFLUENT-24-030724
SEEP-D-INFLUENT-24-031124
March 10 - March 11, 2024
March 11, 2024
SEEP-D-EFFLUENT-24-031124
SEEP-D-INFLUENT-24-032324
March 23, 2024
March 23, 2024
SEEP-D-EFFLUENT-24-032324
SEEP-D-INFLUENT-24-032824
March 27 - March 28, 2024
March 28, 2024
SEEP-D-EFFLUENT-24-032824
Notes:
I- Sample Identification Label Key: "Seep -[A, B, C, or D] -[Sample Location Inside FTC] - [# of Aliquots in Composite Sample] - [MMDDYY]"
2 - The FTC was operating under batch mode for part of January, February, and March 2024. Performance samples were not collected while the FTC was
closed.
TR0795C Page 4 of 4 June 2024
Table 2-4A
FTC Performance Monitoring Analytical Results - Seep A
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
Table 3 +SOP (n /L)
SEEP -A -INFLUENT
24-010624
Sample Date:
6-Jan-24
SEEP -A -EFFLUENT.
24-010624
Sample Date:
6-Jan-24
Percent Removal
SEEP -A -INFLUENT-
24-011024
Sample Date:
10-Jan-24
SEEP -A -EFFLUENT
24-011024
Sample Date:
10-Jan-24
Percent Removal
SEEP -A -INFLUENT
24-012024
Sample Date:
20-Jan-24
SEEP -A -EFFLUENT.
24-012024
Sample Date:
20-Jan-24
Percent Removal
SEEP -A -INFLUENT-
24-013124
Sample Date:
31-Jan-24
SEEP -A -EFFLUENT
24-013124
Sample Date:
31-Jan-24
Percent Removal
Hfpo Dimer Acid
7,100
6.1
99.9%
4,900
2.5
>99.9%
6,400
<2.0
>99.9%
7,700
2.9
>99.9%
PFMOAA
21,000
75
99.6%
12,000
43
99.6%
12,000
16
99.9%
18,000
36
99.8%
PFO2HxA
13,000
20
99.8%
9,100
5.6
99.9%
8,500
2.1
>99.9%
12,000
6.8
99.9%
PFO3OA
3,600
5.6
99.8%
2,900
<2.0
>99.9%
2,400
<2.0
>99.9%
3,500
<2.0
>99.9%
PFO4DA
1,500
<2.0
>99.9%
1,500
<2.0
>99.9%
920
<2.0
>99.9%
1,600
<2.0
>99.9%
PFO5DA
710
<2.0
>99.9%
760
<2.0
>99.9%
330
<2.0
>99.9%
730
<2.0
>99.9%
PMPA
7,100
20
99.7%
4,100
13
99.7%
4,600
<10
>99.9%
6,400
14
99.8%
PEPA
2,500
<20
>99.9%
1,400
<20
>99.9%
1,800
<20
>99.9%
2,600
<20
>99.9%
PS Acid
<20
<2.0
>99.9%
200
<2.0
>99.9%
<20
<2.0
>99.9%
<20
<2.0
>99.9%
Hydro -PS Acid
220
<2.0
>99.9%
210
<2.0
>99.9%
140
<2.0
>99.9%
290
<2.0
>99.9%
R-PSDA
530 J
<2.0
>99.9%
460 J
<2.0
>99.9%
640 J
<2.0
>99.9%
570 J
<2.0
>99.9%
Hydrolyzed PSDA
1,800 J
<2.0
>99.9%
1,200 J
<2.0
>99.9%
870 J
<2.0
>99.9%
1,800 J
<2.0
>99.9%
R-PSDCA
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<17
<2.0
>99.9%
NVHOS, Acid Form
280
<2.0
>99.9%
190
<2.0
>99.9%
200
<2.0
>99.9%
350
<2.0
>99.9%
EVE Acid
<17
<2.0
>99.9%
84
<2.0
>99.9%
<17
<2.0
>99.9%
<17
<2.0
>99.9%
Hydro -EVE Acid
230
<2.0
>99.9%
220
<2.0
>99.9%
140
<2.0
>99.9%
260
<2.0
>99.9%
R-EVE
290 J
<2.0
>99.9%
180 J
<2.0
>99.9%
300 J
<2.0
>99.9%
300 J
<2.0
>99.9%
Perfluoro(2-ethoxyethane)sulfonic Acid
<6.7
<2.0
>99.9%
<6.7
<2.0
>99.9%
<6.7
<2.0
>99.9%
<6.7
<2.0
>99.9%
PFECA B
<27
<2.0
>99.9%
<27
<2.0
>99.9%
<27
<2.0
>99.9%
<27
<2.0
>99.9%
PFECA-G
1 <48
1 <2.0
1 >99.90/,
<48
<2.0
>99.9%
<48
<2.0
>99.9%
<48
<2.0
>99.9%
Total Table 3+ (17 compounds) 1 2
57,000
0
38,000
99.8%
37,000
>99.9%
53,000
99.9%
Notes:
1 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to two significant figures.
2 - Total Table 3+ (17 Compounds) does not include R-PSDA, Hydrolyzed PSDA and R-EVE.
3 - Sample Identification Label Key: "Seep - [A, B, C, or D] - [Sample Location Inside FTC] - [# of Aliquots in Composite Sample] - [MMDDYY]"
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
FTC - flow through cell
SOP - standard operating procedure
< - Analyte not detected above associated reporting limit.
TR0795C Page 1 of 13 June 2024
Table 2-4A
FTC Performance Monitoring Analytical Results - Seep A
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
Table 3 +SOP (n /L)
SEEP -A -INFLUENT
24-020124
Sample Date:
O1-Feb-24
SEEP -A -EFFLUENT.
24-020124
Sample Date:
01-Feb-24
Percent Removal
SEEP -A -INFLUENT-
24-021324
Sample Date:
13-Feb-24
SEEP -A -EFFLUENT
24-021324
Sample Date:
13-Feb-24
Percent Removal
SEEP -A -INFLUENT
24-021424
Sample Date:
14-Feb-24
SEEP -A -EFFLUENT.
24-021424
Sample Date:
14-Feb-24
Percent Removal
SEEP -A -INFLUENT-
24-030224
Sample Date:
2-Mar-24
SEEP -A -EFFLUENT
24-030224
Sample Date:
2-Mar-24
Percent Removal
Hfpo Dimer Acid
7,800
2.8
>99.9%
8,400
2.0
>99.9%
8,900
<2.0
>99.9%
12,000
2.0
>99.9%
PFMOAA
20,000
37
99.8%
20,000
23 J
99.9%
21,000
16
99.9%
23,000
18
99.9%
PFO2HxA
13,000
7.5
99.9%
13,000
4.8
>99.9%
12,000
4.5
>99.9%
17,000
2.2
>99.9%
PFO3OA
3,800
<2.0
>99.9%
3,600
<2.0
>99.9%
3,200
<2.0
>99.9%
4,600
<2.0
>99.9%
PFO4DA
1,700
<2.0
>99.9%
1,300
<2.0
>99.9%
1,300
<2.0
>99.9%
1,700
<2.0
>99.9%
PFO5DA
840
<2.0
>99.9%
690
<2.0
>99.9%
550
<2.0
>99.9%
690
<2.0
>99.9%
PMPA
6,900
15
99.8%
6,800
12
99.8%
6,500
<10
>99.9%
9,200
<10
>99.9%
PEPA
2,700
<20
>99.9%
2,800
<20
>99.9%
2,700
<20
>99.9%
3,600
<10
>99.9%
PS Acid
<20
<2.0
>99.9%
<20
<2.0
>99.9%
<20
<2.0
>99.9%
<50
<2.0
>99.9%
Hydro -PS Acid
310
<2.0
>99.9%
270
<2.0
>99.9%
220
<2.0
>99.9%
290
<2.0
>99.9%
R-PSDA
600 J
<2.0
>99.9%
620 J
<2.0
>99.9%
810 J
<2.0
>99.9%
830 J
<2.0
>99.9%
Hydrolyzed PSDA
2,000 J
<2.0
>99.9%
1,900 J
<2.0
>99.9%
2,000 J
<2.0
>99.9%
2,300 J
<2.0
>99.9%
R-PSDCA
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<50
<2.0
>99.9%
NVHOS, Acid Form
370
<2.0
>99.9%
360
<2.0
>99.9%
350
<2.0
>99.9%
420
<2.0
>99.9%
EVE Acid
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<50
<2.0
>99.9%
Hydro -EVE Acid
280
<2.0
>99.9%
270
<2.0
>99.9%
240
<2.0
>99.9%
280
<2.0
>99.9%
R-EVE
320 J
<2.0
>99.9%
320 J
<2.0
>99.9%
390 J
<2.0
>99.9%
470 J
<2.0
>99.9%
Perfluoro(2-ethoxyethane)sulfonic Acid
<6.7
<2.0
>99.9%
<6.7
<2.0
>99.9%
<6.7
<2.0
>99.9%
<50
<2.0
>99.9%
PFECA B
<27
<2.0
>99.9%
<27
<2.0
>99.9%
<27 UJ
<2.0
>99.9%
<50
<2.0
>99.9%
PFECA-G
1 <48
<2.0
1 >99.9%
1 <48
1 <2.0
1 >99.9%
1 <48
1 <2.0
1 >99.9%
<50
<2.0
>99.9%
Total Table 3+ (17 compounds)"
I1
99.9%
1 57,000
99.9%
1 E
111111=
1 >99.9%
73,000
>99.9%
Notes:
1 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to two significant figures.
2 - Total Table 3+ (17 Compounds) does not include R-PSDA, Hydrolyzed PSDA and R-EVE.
3 - Sample Identification Label Key: "Seep - [A, B, C, or D] - [Sample Location Inside FTC] - [# of Aliquots in Composite Sample] - [MMDDYY]"
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
ng/L - nanograms per liter
FTC - flow through cell
SOP - standard operating procedure
< - Analyte not detected above associated reporting limit.
TR0795C Page 2 of 13 June 2024
Table 2-4A
FTC Performance Monitoring Analytical Results - Seep A
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
Table 3 +SOP (n /L)
SEEP -A -INFLUENT
24-030724
Sample Date:
7-Mar-24
SEEP -A -EFFLUENT.
24-030724
Sample Date:
7-Mar-24
Percent Removal
SEEP -A -INFLUENT-
24-031124
Sample Date:
11-Mar-24
SEEP -A -EFFLUENT
24-031124
Sample Date:
11-Mar-24
Percent Removal
SEEP -A -INFLUENT
24-032324
Sample Date:
23-Mar-24
SEEP -A -EFFLUENT.
24-032324
Sample Date:
23-Mar-24
Percent Removal
SEEP -A -INFLUENT-
24-032824
Sample Date:
28-Mar-24
SEEP -A -EFFLUENT
24-032824
Sample Date:
28-Mar-24
Percent Removal
Hfpo Dimer Acid
9,200
<2.0
>99.9%
8,100
<2.0
>99.9%
9,100
<2.0
>99.9%
9,600
<2.0
>99.9%
PFMOAA
12,000 J
13
99.9%
11,000
18
99.8%
18,000
36
99.8%
19,000 J
31
99.8%
PFO2HxA
11,000
2.7
>99.9%
10,000
3.2
>99.9%
13,000
3.3
>99.9%
13,000
3.8
>99.9%
PFO3OA
2,800
<2.0
>99.9%
3,100
<2.0
>99.9%
4,000
<2.0
>99.9%
3,700
<2.0
>99.9%
PFO4DA
1,300
<2.0
>99.9%
1,200
<2.0
>99.9%
1,500
<2.0
>99.9%
1,400
<2.0
>99.9%
PFO5DA
530
<2.0
>99.9%
610
<2.0
>99.9%
880
<2.0
>99.9%
580
<2.0
>99.9%
PMPA
5,700
<10
>99.9%
4,700
<10
>99.9%
7,100
<10
>99.9%
7,800
<10
>99.9%
PEPA
2,100
<10
>99.9%
2,000
<10
>99.9%
2,700
<10
>99.9%
3,100
<10
>99.9%
PS Acid
67
<2.0
>99.9%
140
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
Hydro -PS Acid
230
<2.0
>99.9%
230
<2.0
>99.9%
310
<2.0
>99.9%
240
<2.0
>99.9%
R-PSDA
570 J
<2.0
>99.9%
880 J
<2.0
>99.9%
870 J
<2.0
>99.9%
750 J
<2.0
>99.9%
Hydrolyzed PSDA
1,200 J
<2.0
>99.9%
1,300 J
<2.0
>99.9%
1,700 J
<2.0
>99.9%
1,600 J
<2.0
>99.9%
R-PSDCA
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
NVHOS, Acid Form
240
<2.0
>99.9%
230
<2.0
>99.9%
310
<2.0
>99.9%
330
<2.0
>99.9%
EVE Acid
<50
<2.0
>99.9%
57
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
Hydro -EVE Acid
180
<2.0
>99.9%
200
<2.0
>99.9%
290
<2.0
>99.9%
230
<2.0
>99.9%
R-EVE
280 J
<2.0
>99.9%
370 J
<2.0
>99.9%
400 J
<2.0
>99.9%
380 J
<2.0
>99.9%
Perfluoro(2-ethoxyethane)sulfonic Acid
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
PFECA B
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
PFECA-G
<50
<2.0
>99.9%
1 <50
1 <2.0
1 >99.9%
1 <50
1 <2.0
1 >99.9%
<50
<2.0
>99.9%
Total Table 3+ (17 compounds)" III
>99.9%
42,000
1
1 >99.9%
99.9%
59,000
99.9%
Notes:
1 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to two significant figures.
2 - Total Table 3+ (17 Compounds) does not include R-PSDA, Hydrolyzed PSDA and R-EVE.
3 - Sample Identification Label Key: "Seep - [A, B, C, or D] - [Sample Location Inside FTC] - [# of Aliquots in Composite Sample] - [MMDDYY]"
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
FTC - flow through cell
SOP - standard operating procedure
< - Analyte not detected above associated reporting limit.
TR0795C Page 3 of 13 June 2024
Table 2-4B
FTC Performance Monitoring Analytical Results - Seep B
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
Table 3 + SOP (n /L)
SEEP-B-INFLUENT
24-011024
Sample Date:
10-Jan-24
SEEP-B-EFFLUENT.
24-011024
Sample Date:
10-Jan-24
Percent Removal
SEEP-B-INFLUENT-
24-012024
Sample Date:
20-Jan-24
SEEP-B-EFFLUENT
24-012024
Sample Date:
20-Jan-24
Percent Removal
SEEP-B-INFLUENT
24-012524
Sample Date:
25-Jan-24
SEEP-B-EFFLUENT.
24-012524
Sample Date:
25-Jan-24
Percent Removal
SEEP-B-INFLUENT-
24-013124
Sample Date:
31-Jan-24
SEEP-B-EFFLUENT
24-013124
Sample Date:
31-Jan-24
Percent Removal
Hfpo Dimer Acid
3,300
<2.0
>99.9%
3,400
<2.0
>99.9%
3,300
4.9
99.9%
3,400
11
99.7%
PFMOAA
8,600
23
99.7%
5,700
14
99.8%
5,500
51
99.1 %
5,700
140
97.5%
PFO2HxA
4,400
3.4
99.9%
3,700
2.1
99.9%
3,700
7.1
99.8%
3,800
19
99.5%
PFO3OA
960
<2.0
>99.9%
880
<2.0
>99.9%
770
<2.0
>99.9%
900
<2.0
>99.9%
PFO4DA
320
<2.0
>99.90
210
<2.0
>99.9%
200
<2.0
>99.9%
220
<2.0
>99.9%
PFO5DA
98
<2.0
>99.9%
<78
<2.0
>99.9%
<78
<2.0
>99.9%
<78
<2.0
>99.9%
PMPA
4,600
<10
>99.9%
3,600
<10
>99.9%
3,500
17
99.5%
3,600
40
98.9%
PEPA
1,700
<20
>99.9%
1,500
<20
>99.9%
1,400
<20
>99.9%
1,700
<20
>99.9%
PS Acid
130
<2.0
>99.9%
46
<2.0
>99.9%
36
<2.0
>99.9%
46
<2.0
>99.9%
Hydro -PS Acid
130
<2.0
>99.9%
81
<2.0
>99.9%
78
<2.0
>99.9%
120
<2.0
>99.9%
R-PSDA
270 J
<2.0
>99.9%
430 J
<2.0
>99.9%
370 J
<2.0
>99.9%
290 J
<2.0
>99.9%
Hydrolyzed PSDA
910 J
<2.0
>99.9%
940 J
<2.0
>99.9%
940 J
<2.0
>99.9%
1,100 J
4.9 J
99.6%
R-PSDCA
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<17
<2.0
>99.9%
NVHOS, Acid Form
170
<2.0
>99.9%
160
<2.0
>99.9%
160
<2.0
>99.9%
220
<2.0
>99.9%
EVE Acid
150
<2.0
>99.9%
42
<2.0
>99.9%
30
<2.0
>99.9%
33
<2.0
>99.9%
Hydro -EVE Acid
210
<2.0
>99.9%
120
<2.0
>99.9%
120
<2.0
>99.9%
150
<2.0
>99.9%
R-EVE
210 J
<2.0
>99.9%
280 J
<2.0
>99.9%
260 J
<2.0
>99.9%
210 J
<2.0
>99.9%
Perfluoro(2-ethoxyethane)sulfonic Acid
<6.7
<2.0
>99.9%
<6.7
<2.0
>99.9%
<6.7
<2.0
>99.9%
<6.7
<2.0
>99.9%
PFECA B
<27
<2.0
>99.9%
<27
<2.0
>99.9%
<27
<2.0
>99.9%
<27
<2.0
>99.9%
PFECA-G
1 <48
1 <2.0
1 >99.9%
1 <48
1 <2.0
1 >99.9%
1 <48
1 <2.0
1 >99.9%
1 <48
1 <2.0
1 >99.9%
Total Table 3+ (17 compounds) 121
25,000
26
1 99.9%
1 19,000
1
1 99.9%
19,000
80
1 99.6%
1 20,000
1 1
1 99.00%
Notes:
1 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to two significant figures.
2 - Total Table 3+ (17 Compounds) does not include R-PSDA, Hydrolyzed PSDA and R-EVE.
3 - Sample Identification Label Key: "Seep - [A, B, C, or D] - [Sample Location Inside FTC] - [# of Aliquots in Composite Sample] - [MMDDYY]"
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
FTC - flow through cell
SOP - standard operating procedure
< - Analyte not detected above associated reporting limit.
TR0795C Page 4 of 13 June 2024
Table 2-4B
FTC Performance Monitoring Analytical Results - Seep B
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
Table 3 + SOP (n /L)
SEEP-B-INFLUENT
24-020124
Sample Date:
O1-Feb-24
SEEP-B-EFFLUENT.
24-020124
Sample Date:
01-Feb-24
Percent Removal
SEEP-B-INFLUENT-
24-021324
Sample Date:
13-Feb-24
SEEP-B-EFFLUENT
24-021324
Sample Date:
13-Feb-24
Percent Removal
SEEP-B-INFLUENT
24-021424
Sample Date:
14-Feb-24
SEEP-B-EFFLUENT.
24-021424
Sample Date:
14-Feb-24
Percent Removal
SEEP-B-INFLUENT-
24-030224
Sample Date:
2-Mar-24
SEEP-B-EFFLUENT
24-030224
Sample Date:
2-Mar-24
Percent Removal
Hfpo Dimer Acid
3,300
11
99.7%
4,400
15
99.7%
4,900
3.0
99.9%
6,800
9.9
99.9%
PFMOAA
5,900
150
97.5%
7,200
160
97.8%
10,000
21
99.8%
12,000
120
99.0%
PFO2HxA
3,800
21
99.4%
4,400
32
99.3%
5,300
8.8
99.8%
7,300
16
99.8%
PFO3OA
910
2.0
99.8%
1,100
2.2
99.8%
1,100
<2.0
>99.9%
1,700
<2.0
>99.9%
PFO4DA
220
<2.0
>99.9%
210
<2.0
>99.9%
260
<2.0
>99.9%
360
<2.0
>99.9%
PFO5DA
<78
<2.0
>99.9%
<78
<2.0
>99.9%
<78
<2.0
>99.9%
88
<2.0
>99.9%
PMPA
3,600
43
98.8%
4,000
58
98.6%
5,200
12
99.8%
7,000
45
99.4%
PEPA
1,600
<20
>99.9%
1,900
<20
>99.9%
2,200
<20
>99.9%
3,000
11
99.6%
PS Acid
51
<2.0
>99.9%
36
<2.0
>99.9%
<20
<2.0
>99.9%
<50
<2.0
>99.9%
Hydro -PS Acid
120
<2.0
>99.9%
110
<2.0
>99.9%
120
<2.0
>99.9%
180
<2.0
>99.9%
R-PSDA
280 J
<2.0
>99.9%
360 J
2.4 J
99.3%
470 J
<2.0
>99.9%
570 J
<2.0
>99.9%
Hydrolyzed PSDA
1,100 J
5.3 J
99.5%
1,400 J
7.2 J
99.5%
940 J
<2.0
>99.9%
1,700 J
3.6 J
99.8%
R-PSDCA
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<50
<2.0
>99.9%
NVHOS, Acid Form
230
<2.0
>99.9%
330
2.2
99.3%
260
<2.0
>99.9%
310
<2.0
>99.9%
EVE Acid
30
<2.0
>99.9%
23
<2.0
>99.9%
<17
<2.0
>99.9%
<50
<2.0
>99.9%
Hydro -EVE Acid
150
<2.0
>99.9%
150
<2.0
>99.9%
170
<2.0
>99.9%
200
<2.0
>99.9%
R-EVE
210 J
<2.0
>99.9%
240 J
<2.0
>99.9%
280 J
<2.0
>99.9%
370 J
<2.0
>99.9%
Perfluoro(2-ethoxyethane)sulfonic Acid
<6.7
<2.0
>99.9%
<6.7
<2.0
>99.9%
<6.7
<2.0
>99.9%
<50
<2.0
>99.9%
PFECA B
<27
<2.0
>99.9%
<27
<2.0
>99.9%
<27
<2.0
>99.9%
<50
<2.0
>99.9%
PFECA-G
1 <48
1 <2.0
1 >99.9%
<48
<2.0
>99.9%
<48
<2.0
>99.9%
<50
<2.0
>99.9%
Total Table 3+ (17 compounds)�'�
230
98.9%
24,000
98.9%
0,000
45
1 99.9%
1 39,000
99.5%
Notes:
1 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to two significant figures.
2 - Total Table 3+ (17 Compounds) does not include R-PSDA, Hydrolyzed PSDA and R-EVE.
3 - Sample Identification Label Key: "Seep - [A, B, C, or D] - [Sample Location Inside FTC] - [# of Aliquots in Composite Sample] - [MMDDYY]"
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
FTC - flow through cell
SOP - standard operating procedure
< - Analyte not detected above associated reporting limit.
TR0795C Page 5 of 13 June 2024
Table 2-4B
FTC Performance Monitoring Analytical Results - Seep B
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
Table 3 + SOP (n /L)
SEEP-B-INFLUENT
24-030724
Sample Date:
7-Mar-24
SEEP-B-EFFLUENT.
24-030724
Sample Date:
7-Mar-24
Percent Removal
SEEP-B-INFLUENT-
24-031124
Sample Date:
11-Mar-24
SEEP-B-EFFLUENT
24-031124
Sample Date:
11-Mar-24
Percent Removal
SEEP-B-INFLUENT
24-032324
Sample Date:
23-Mar-24
SEEP-B-EFFLUENT.
24-032324
Sample Date:
23-Mar-24
Percent Removal
SEEP-B-INFLUENT-
24-032824
Sample Date:
28-Mar-24
SEEP-B-EFFLUENT
24-032824
Sample Date:
28-Mar-24
Percent Removal
Hfpo Dimer Acid
4,000
2.5
99.9%
6,600
2.7
>99.9%
7,900
5.8
99.93%
8,200
9.2
99.9%
PFMOAA
4,800
39
99.2%
9,400
24
99.7%
16,000
120
99.25%
14,000
190
98.6%
PFO2HxA
3,800
5.8
99.8%
7,200
3.5
>99.9%
9,700
12
99.88%
9,400
23
99.8%
PFO3OA
750
<2.0
>99.9%
1,800
<2.0
>99.9%
2,300
<2.0
>99.9%
2,300
<2.0
>99.9%
PFO4DA
270
<2.0
>99.9%
450
<2.0
>99.9%
590
<2.0
>99.9%
500
<2.0
>99.9%
PFO5DA
<78
<2.0
>99.9%
110
<2.0
>99.9%
150
<2.0
>99.9%
130
<2.0
>99.9%
PMPA
3,600
12
99.7%
6,300
10
99.8%
8,800
35
99.60%
8,900
56
99.4%
PEPA
1,400
<10
>99.9%
2,600
<10
>99.9%
3,600
<10
>99.9%
3,400
10
99.7%
PS Acid
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
Hydro -PS Acid
110
<2.0
>99.9%
190
<2.0
>99.9%
250
<2.0
>99.9%
250
<2.0
>99.9%
R-PSDA
260 J
<2.0
>99.9%
590 J
<2.0
>99.9%
780 J
<2.0
>99.9%
740 J
<2.0
>99.9%
Hydrolyzed PSDA
440 J
<2.0
>99.9%
760 J
<2.0
>99.9%
1,900 J
4.7 J
99.75%
1,600 J
5.9 J
99.6%
R-PSDCA
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
NVHOS, Acid Form
120
<2.0
>99.9%
240
<2.0
>99.9%
380
<2.0
>99.9%
350
<2.0
>99.9%
EVE Acid
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
Hydro -EVE Acid
110
<2.0
>99.9%
200
<2.0
>99.9%
280
<2.0
>99.9%
280
<2.0
>99.9%
R-EVE
190 J
<2.0
>99.9%
350 J
<2.0
>99.9%
540 J
<2.0
>99.9%
540 J
<2.0
>99.9%
Perfluoro(2-ethoxyethane)sulfonic Acid
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
PFECA B
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
PFECA-G
1 <50
1 <2.0
1 >99.9%
<50
<2.0
>99.90/.
<50
<2.0
>99.9%
<50
<2.0
>99.9 0
Total Table 3+ (17 compounds)
19,000
59
99.7%
35,000
99.9%
,000
99.7%
48,000
99.4%
Notes:
1 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to two significant figures.
2 - Total Table 3+ (17 Compounds) does not include R-PSDA, Hydrolyzed PSDA and R-EVE.
3 - Sample Identification Label Key: "Seep - [A, B, C, or D] - [Sample Location Inside FTC] - [# of Aliquots in Composite Sample] - [MMDDYY]"
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
FTC - flow through cell
SOP - standard operating procedure
< - Analyte not detected above associated reporting limit.
TR0795C Page 6 of 13 June 2024
Table 2-4C
FTC Performance Monitoring Analytical Results - Seep C
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
Table 3 +SOP n /L
SEEP-C-INFLUENT
24-010624
Sample Date:
6-Jan-24
SEEP-C-EFFLUENT.
24-010624
Sample Date:
6-Jan-24
Percent Removal
SEEP-C-INFLUENT-
24-011024
Sample Date:
10-Jan-24
SEEP-C-EFFLUENT
24-011024
Sample Date:
10-Jan-24
Percent Removal
SEEP-C-INFLUENT
24-012024
Sample Date:
20-Jan-24
SEEP-C-EFFLUENT
24-012024
Sample Date:
20-Jan-24
Percent Removal
SEEP-C-INFLUENT-
24-013124
Sample Date:
31-Jan-24
SEEP-C-EFFLUENT
24-013124
Sample Date:
31-Jan-24
Percent Removal
Hfpo Dimer Acid
7,100
10
99.9%
3,900
18
99.5%
6,200
7.5
99.9%
4,900
9.2
99.8%
PFMOAA
13,000
71
99.5%
8,300
32
99.6%
10,000
45
99.6%
9,500
68
99.3%
PFO2HxA
8,700
22
99.7%
5,100
11
99.8%
6,700
9.3
99.9%
6,100
14
99.8%
PFO3OA
3,200
4.9
99.8%
1,800
3.0
99.8%
2,700
2.1
99.9%
2,300
3.3
99.9%
PFO4DA
1,300
<2.0
>99.9%
840
<2.0
>99.9%
980
<2.0
>99.9%
870
<2.0
>99.9%
PFO5DA
<78
<2.0
>99.9%
<78
<2.0
>99.9%
<78
<2.0
>99.9%
<78
<2.0
>99.9%
PMPA
3,600
17
99.5%
2,200
15
99.3%
2,700
16
99.4%
2,300
19
99.2%
PEPA
1,300
<20
>99.9%
720
<20
>99.9%
940
<20
>99.9%
920
<20
>99.9%
PS Acid
<20
<2.0
>99.9%
<20
<2.0
>99.9%
<20
<2.0
>99.9%
<20
<2.0
>99.9%
Hydro -PS Acid
190
<2.0
>99.9%
120
<2.0
>99.9%
140
<2.0
>99.9%
170
<2.0
>99.9%
R-PSDA
290 J
<2.0
>99.9%
180 J
<2.0
>99.9%
430 J
<2.0
>99.9%
240 J
<2.0
>99.9%
Hydrolyzed PSDA
<38
<2.0
>99.9%
<38
<2.0
>99.9%
<38
<2.0
>99.9%
<38
<2.0
>99.9%
R-PSDCA
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<17
<2.0
>99.9%
NVHOS, Acid Form
240
<2.0
>99.9%
140
<2.0
>99.9%
180
<2.0
>99.9%
250
<2.0
>99.9%
EVE Acid
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<17
<2.0
>99.9%
Hydro -EVE Acid
640
<2.0
>99.9%
410
<2.0
>99.9%
500
<2.0
>99.9%
470
<2.0
>99.9%
R-EVE
300 J
<2.0
>99.9%
150 J
<2.0
>99.9%
390 J
<2.0
>99.9%
220 J
<2.0
>99.9%
Perfluoro(2-ethoxyethane)sulfonic Acid
<6.7
<2.0
>99.9%
<6.7
<2.0
>99.9%
<6.7
<2.0
>99.9%
<6.7
<2.0
>99.9%
PFECA B
<27
<2.0
>99.9%
<27
<2.0
>99.9%
<27
<2.0
>99.9%
<27
<2.0
>99.9%
PFECA-G
1 <48
1 <2.0
1 >99.9%
<48
<2.0
>99.9%
<48
<2.0
>99.90/,
<48
<2.0
>99.9%
Total Table 3+ (17 compounds) 12
39,000
0
99.7%
99.7%
31,000
0
99.7%
99.6%
Notes:
1 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to two significant figures.
2 - Total Table 3+ (17 Compounds) does not include R-PSDA, Hydrolyzed PSDA and R-EVE.
3 - Sample Identification Label Key: "Seep - [A, B, C, or D] - [Sample Location Inside FTC] - [# of Aliquots in Composite Sample] - [MMDDYY]"
4 - Percent removal is not calculated, since, for unknown reasons, the analyte was not detected in the influent.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
FTC - flow through cell
SOP - standard operating procedure
< - Analyte not detected above associated reporting limit.
TR0795C Page 7 of 13 June 2024
Table 2-4C
FTC Performance Monitoring Analytical Results - Seep C
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
Table 3 +SOP n /L
SEEP-C-INFLUENT
24-020124
Sample Date:
O1-Feb-24
SEEP-C-EFFLUENT.
24-020124
Sample Date:
01-Feb-24
Percent Removal
SEEP-C-INFLUENT-
24-021324
Sample Date:
13-Feb-24
SEEP-C-EFFLUENT
24-021324
Sample Date:
13-Feb-24
Percent Removal
SEEP-C-INFLUENT
24-021424
Sample Date:
14-Feb-24
SEEP-C-EFFLUENT
24-021424
Sample Date:
14-Feb-24
Percent Removal
SEEP-C-INFLUENT-
24-022424
Sample Date:
24-Feb-24
SEEP-C-EFFLUENT
24-022424
Sample Date:
24-Feb-24
Percent Removal
Hfpo Dimer Acid
5,000
8.0
99.8%
5,200
10
99.8%
3,300
7.7
99.8%
5,600
8.4
99.9%
PFMOAA
9,500
61
99.4%
9,500
31
99.7%
6,400
4.5
99.9%
8,100
6.8
99.9%
PFO2HxA
6,000
12
99.8%
5,900
14
99.8%
3,700
4.1
99.9%
6,100
12
99.8%
PFO3OA
2,400
2.7
99.9%
2,500
3.3
99.9%
1,200
<2.0
>99.9%
2,500
3.1
99.9%
PFO4DA
860
<2.0
>99.9%
800
<2.0
>99.9%
520
<2.0
>99.9%
850
<2.0
>99.9%
PFO5DA
<78
<2.0
>99.9%
<78
<2.0
>99.9%
<78
<2.0
>99.9%
<78
<2.0
>99.9%
PMPA
2,300
17
99.3%
2,400
13
99.5%
1,400
<10
>99.9%
2,100
<10
>99.9%
PEPA
880
<20
>99.9%
890
<20
>99.9%
520
<20
>99.9%
900
<20
>99.9%
PS Acid
<20
<2.0
>99.9%
<20
<2.0
>99.9%
<20
<2.0
>99.9%
<20
<2.0
>99.9%
Hydro -PS Acid
180
<2.0
>99.9%
160
<2.0
>99.9%
110
<2.0
>99.9%
180
<2.0
>99.9%
R-PSDA
260 J
<2.0
>99.9%
250 J
<2.0
>99.9%
230 J
<2.0
>99.9%
300 J
<2.0
>99.9%
Hydrolyzed PSDA
<38
<2.0
>99.9%
<38
<2.0
>99.9%
<38
<2.0
>99.9%
41 J
<2.0
>99.9%
R-PSDCA
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<17
<2.0
>99.9%
NVHOS, Acid Form
220
<2.0
>99.9%
280
<2.0
>99.9%
160
<2.0
>99.9%
200
<2.0
>99.9%
EVE Acid
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<17
<2.0
>99.9%
Hydro -EVE Acid
480
<2.0
>99.9%
480
<2.0
>99.9%
260
<2.0
>99.9%
440
<2.0
>99.9%
R-EVE
250 J
<2.0
>99.9%
230 J
<2.0
>99.9%
170 J
<2.0
>99.9%
250 J
<2.0
>99.9%
Perfluoro(2-ethoxyethane)sulfonic Acid
<6.7
<2.0
>99.9%
<6.7
<2.0
>99.9%
<6.7
<2.0
>99.9%
<6.7
<2.0
>99.9%
PFECA B
<27
<2.0
>99.9%
<27
<2.0
>99.9%
<27
<2.0
>99.9%
<27
<2.0
>99.9%
PFECA-G
<48
<2.0
>99.90/,
<48
<2.0
>99.9%
1 <48
1 <2.0
1 >99.9%
<48
<2.0
>99.9%
Total Table 3+ (17 compounds)" 2
28,000
0
99.7%
18,000
=6
99.9%
Aiiiii
99.9%
Notes:
1 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to two significant figures.
2 - Total Table 3+ (17 Compounds) does not include R-PSDA, Hydrolyzed PSDA and R-EVE.
3 - Sample Identification Label Key: "Seep - [A, B, C, or D] - [Sample Location Inside FTC] - [# of Aliquots in Composite Sample] - [MMDDYY]"
4 - Percent removal is not calculated, since, for unknown reasons, the analyte was not detected in the influent.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
FTC - flow through cell
SOP - standard operating procedure
< - Analyte not detected above associated reporting limit.
TR0795C Page 8 of 13 June 2024
Table 2-4C
FTC Performance Monitoring Analytical Results - Seep C
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
Table 3 +SOP n /L
SEEP-C-INFLUENT
24-030224
Sample Date:
2-Mar-24
SEEP-C-EFFLUENT.
24-030224
Sample Date:
2-Mar-24
Percent Removal
SEEP-C-INFLUENT-
24-030724
Sample Date:
7-Mar-24
SEEP-C-EFFLUENT
24-030724
Sample Date:
7-Mar-24
Percent Removal
SEEP-C-INFLUENT
24-031124
Sample Date:
II-Mar-24
SEEP-C-EFFLUENT
24-031124
Sample Date:
II-Mar-24
Percent Removal
SEEP-C-INFLUENT-
24-032324
Sample Date:
23-Mar-24
SEEP-C-EFFLUENT
24-032324
Sample Date:
23-Mar-24
Percent Removal
Hfpo Dimer Acid
5,700
7.8
99.9%
4,600
19
99.6%
6,800
3.3
>99.9%
7,200
19
99.7%
PFMOAA
9,300
25
99.7%
4,800
20
99.6%
9,000
30
99.7%
12,000
120
99.0%
PFO2HxA
6,500
5.2
99.9%
4,000
9.9
99.8%
6,800
3.8
99.9%
8,100
55
99.3%
PFO3OA
2,500
<2.0
>99.9%
1,500
2.2
99.9%
2,700
<2.0
>99.9%
3,400
16
99.5%
PFO4DA
940
<2.0
>99.9%
700
<2.0
>99.9%
1,000
<2.0
>99.9%
1,300
5.0
99.6%
PFO5DA
<78
<2.0
>99.9%
<78
<2.0
>99.9%
<78
<2.0
>99.9%
<78
2.3
[41
PMPA
2,600
<10
>99.9%
1,600
<10
>99.9%
2,700
<10
>99.9%
3,300
20
99.4%
PEPA
900
<10
>99.9%
590
<10
>99.9%
950
<10
>99.9%
1,100
<10
>99.9%
PS Acid
<50
<2.0
>99.90 0
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
Hydro -PS Acid
200
<2.0
>99.9%
140
<2.0
>99.9%
210
<2.0
>99.9%
280
<2.0
>99.9%
R-PSDA
350 J
<2.0
>99.9%
200 J
<2.0
>99.9%
480 J
<2.0
>99.9%
480 J
4.3 J
99.1%
Hydrolyzed PSDA
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
4.7 J
[41
R-PSDCA
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
NVHOS, Acid Form
190
<2.0
>99.9%
96
<2.0
>99.9%
180
<2.0
>99.9%
240
<2.0
>99.9%
EVE Acid
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
Hydro -EVE Acid
490
<2.0
>99.9%
400
<2.0
>99.9%
630
<2.0
>99.9%
770
<2.0
>99.9%
R-EVE
290 J
<2.0
>99.9%
160 J
<2.0
>99.9%
390 J
<2.0
>99.9%
430 J
<2.0
>99.9%
Perfluoro(2-ethoxyethane)sulfonic Acid
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
PFECA B
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
PFECA-G
<50
<2.0
>99.9%
1 <50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
Total Table 3+ (17 compounds)"
29,000
1 M8
99.9%
99.7%
99.9%
38,000
99.4%
Notes:
1 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to two significant figures.
2 - Total Table 3+ (17 Compounds) does not include R-PSDA, Hydrolyzed PSDA and R-EVE.
3 - Sample Identification Label Key: "Seep - [A, B, C, or D] - [Sample Location Inside FTC] - [# of Aliquots in Composite Sample] - [MMDDYY]"
4 - Percent removal is not calculated, since, for unknown reasons, the analyte was not detected in the influent.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
FTC - flow through cell
SOP - standard operating procedure
< - Analyte not detected above associated reporting limit.
TR0795C Page 9 of 13 June 2024
Table 2-4C
FTC Performance Monitoring Analytical Results - Seep C
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
Table 3 +SOP n /L
SEEP-C-INFLUENT
24-032824
Sample Date:
28-Mar-24
SEEP-C-EFFLUENT.
24-032824
Sample Date:
28-Mar-24
Percent Removal
Hfpo Dimer Acid
7,100
5.9
99.9%
PFMOAA
12,000
64
99.5%
PFO2HxA
7,800
11
99.9%
PFO3OA
3,100
<2.0
>99.9%
PFO4DA
1,200
<2.0
>99.9%
PFO5DA
<78
<2.0
>99.9%
PMPA
3,200
12
99.6%
PEPA
1,100
<10
>99.9%
PS Acid
<50
<2.0
>99.9%
Hydro -PS Acid
240
<2.0
>99.9%
R-PSDA
440 J
<2.0
>99.9%
Hydrolyzed PSDA
<50
<2.0
>99.9%
R-PSDCA
<50
<2.0
>99.9%
NVHOS, Acid Form
230
<2.0
>99.9%
EVE Acid
<50
<2.0
>99.9%
Hydro -EVE Acid
750
<2.0
>99.9%
R-EVE
360 J
<2.0
>99.9%
Perfluoro(2-ethoxyethane)sulfonic Acid
<50
<2.0
>99.9%
PFECA B
<50
<2.0
>99.9%
PFECA-G
<50
<2.0
>99.9%
Total Table 3+ (17 compounds) 12
37,000
99.7%
Notes:
1 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to two significant figures.
2 - Total Table 3+ (17 Compounds) does not include R-PSDA, Hydrolyzed PSDA and R-EVE.
3 - Sample Identification Label Key: "Seep - [A, B, C, or D] - [Sample Location Inside FTC] - [# of Aliquots in Composite Sample] - [MMDDYY]"
4 - Percent removal is not calculated, since, for unknown reasons, the analyte was not detected in the influent.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
FTC - flow through cell
SOP - standard operating procedure
< - Analyte not detected above associated reporting limit.
TR0795C Page 10 of 13 June 2024
Table 2-4D
FTC Performance Monitoring Analytical Results - Seep D
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
Table 3 +SOP (n /L)
SEEP-D-INFLUENT
24-011024
Sample Date:
10-Jan-24
SEEP-D-EFFLUENT.
24-011024
Sample Date:
10-Jan-24
Percent Removal
SEEP-D-INFLUENT-
24-012024
Sample Date:
20-Jan-24
SEEP-D-EFFLUENT
24-012024
Sample Date:
20-Jan-24
Percent Removal
SEEP-D-INFLUENT
24-012524
Sample Date:
25-Jan-24
SEEP-D-EFFLUENT.
24-012524
Sample Date:
25-Jan-24
Percent Removal
SEEP-D-INFLUENT-
24-013124
Sample Date:
31-Jan-24
SEEP-D-EFFLUENT
24-013124
Sample Date:
31-Jan-24
Percent Removal
Hfpo Dimer Acid
2,600
<2.0
>99.9%
1,100
<2.0
>99.9%
1,300
<2.0
>99.9%
1,400
<2.0
>99.9%
PFMOAA
15,000
55
99.6%
4,600
13
99.7%
4,800
16
99.7%
5,400
40
99.3%
PFO2HxA
5,400
4.1
99.9%
1,900
<2.0
>99.9%
2,200
<2.0
>99.9%
2,500
4.5
99.8%
PFO3OA
1,500
<2.0
>99.9%
540
<2.0
>99.9%
570
<2.0
>99.9%
760
<2.0
>99.9%
PFO4DA
550
<2.0
>99.9%
170
<2.0
>99.9%
200
<2.0
>99.9%
250
<2.0
>99.9%
PFO5DA
<78
<2.0
>99.9%
<78
<2.0
>99.9%
<78
<2.0
>99.9%
<78
<2.0
>99.9%
PMPA
1,900
<10
>99.9%
<620
<10
>99.9%
770
<10
>99.9%
880
<10
>99.9%
PEPA
600
<20
>99.9%
210
<20
>99.9%
280
<20
>99.9%
340
<20
>99.9%
PS Acid
<20
<2.0
>99.9%
<20
<2.0
>99.9%
<20
<2.0
>99.9%
<20
<2.0
>99.9%
Hydro -PS Acid
87
<2.0
>99.9%
27
<2.0
>99.9%
34
<2.0
>99.9%
59
<2.0
>99.9%
R-PSDA
140 J
<2.0
>99.9%
100 J
<2.0
>99.9%
120 J
<2.0
>99.9%
110 J
<2.0
>99.9%
Hydrolyzed PSDA
190 J
<2.0
>99.9%
62 J
<2.0
>99.9%
69 J
<2.0
>99.9%
88 J
<2.0
>99.9%
R-PSDCA
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<17
<2.0
>99.9%
NVHOS, Acid Form
130
<2.0
>99.9%
<15
<2.0
>99.9%
84
<2.0
>99.9%
130
<2.0
>99.9%
EVE Acid
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<17
<2.0
>99.9%
Hydro -EVE Acid
200
<2.0
>99.9%
62
<2.0
>99.9%
61
<2.0
>99.9%
89
<2.0
>99.9%
R-EVE
130 J
<2.0
>99.9%
73 J
<2.0
>99.9%
86 J
<2.0
>99.9%
77 J
<2.0
>99.9%
Perfluoro(2-ethoxyethane)sulfonic Acid
<6.7
<2.0
>99.9%
<6.7
<2.0
>99.9%
<6.7
<2.0
>99.9%
<6.7
<2.0
>99.9%
PFECA B
<27
<2.0
>99.9%
<27
<2.0
>99.9%
<27
<2.0
>99.9%
<27
<2.0
>99.9%
PFECA-G
<48
<2.0
>99.9%
<48
<2.0
>99.9%
<48
<2.0
>99.9%
<48
<2.0
>99.9%
Total Table 3+ (17 compounds)"
28,
9IN
99.8%
99.8%
12,000
99.6%
Notes:
1 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to two significant figures.
2 - Total Table 3+ (17 Compounds) does not include R-PSDA, Hydrolyzed PSDA and R-EVE.
3 - Sample Identification Label Key: "Seep - [A, B, C, or D] - [Sample Location Inside FTC] - [# of Aliquots in Composite Sample] - [MMDDYY]"
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
FTC - flow through cell
SOP - standard operating procedure
< - Analyte not detected above associated reporting limit.
TR0795C Page 11 of 13 June 2024
Table 2-4D
FTC Performance Monitoring Analytical Results - Seep D
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
Table 3 +SOP (n /L)
SEEP-D-INFLUENT
24-020124
Sample Date:
O1-Feb-24
SEEP-D-EFFLUENT.
24-020124
Sample Date:
01-Feb-24
Percent Removal
SEEP-D-INFLUENT-
24-021324
Sample Date:
13-Feb-24
SEEP-D-EFFLUENT
24-021324
Sample Date:
13-Feb-24
Percent Removal
SEEP-D-INFLUENT
24-021424
Sample Date:
14-Feb-24
SEEP-D-EFFLUENT.
24-021424
Sample Date:
14-Feb-24
Percent Removal
SEEP-D-INFLUENT-
24-030224
Sample Date:
2-Mar-24
SEEP-D-EFFLUENT
24-030224
Sample Date:
2-Mar-24
Percent Removal
Hfpo Dimer Acid
1,500
<2.0
>99.9%
2,400
<2.0
>99.9%
2,500
3.0
99.9%
4,100
<2.0
>99.9%
PFMOAA
5,800
11
99.8%
7,400
26
99.6%
8,600
49
99.4%
11,000
9.9
99.9%
PFO2HxA
2,600
<2.0
>99.9%
3,300
6.9
99.8%
3,600
20
99.4%
5,600
2.4
>99.9%
PFO3OA
810
<2.0
>99.9%
900
<2.0
>99.9%
890
<2.0
>99.9%
1,600
<2.0
>99.9%
PFO4DA
280
<2.0
>99.9%
330
<2.0
>99.9%
350
<2.0
>99.9%
510
<2.0
>99.9%
PFO5DA
<78
<2.0
>99.9%
<78
<2.0
>99.9%
<78
<2.0
>99.9%
<78
<2.0
>99.9%
PMPA
930
<10
>99.9%
1,500
<10
>99.9%
1,300
<10
>99.9%
2,400
<10
>99.9%
PEPA
360
<20
>99.9%
590
<20
>99.9%
540
<20
>99.9%
850
<10
>99.9%
PS Acid
<20
<2.0
>99.9%
<20
<2.0
>99.9%
<20
<2.0
>99.9%
<50
<2.0
>99.9%
Hydro -PS Acid
63
<2.0
>99.9%
70
<2.0
>99.9%
69
<2.0
>99.9%
100
<2.0
>99.9%
R-PSDA
120 J
<2.0
>99.9%
170 J
<2.0
>99.9%
200 J
<2.0
>99.9%
290 J
<2.0
>99.9%
Hydrolyzed PSDA
90 J
<2.0
>99.9%
120 J
<2.0
>99.9%
160 J
<2.0
>99.9%
260 J
<2.0
>99.9%
R-PSDCA
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<50
<2.0
>99.9%
NVHOS, Acid Form
130
<2.0
>99.9%
200
<2.0
>99.9%
<15
<2.0
>99.9%
150
<2.0
>99.9%
EVE Acid
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<17
<2.0
>99.9%
<50
<2.0
>99.9%
Hydro -EVE Acid
110
<2.0
>99.9%
120
<2.0
>99.9%
140
<2.0
>99.9%
210
<2.0
>99.9%
R-EVE
<72
<2.0
>99.9%
100 J
<2.0
>99.9%
130 J
<2.0
>99.9%
190 J
<2.0
>99.9%
Perfluoro(2-ethoxyethane)sulfonic Acid
<6.7
<2.0
>99.9%
<6.7
<2.0
>99.9%
<6.7
<2.0
>99.9%
<50
<2.0
>99.9%
PFECA B
<27
<2.0
>99.9%
<27
<2.0
>99.9%
<27
<2.0
>99.9%
<50
<2.0
>99.9%
PFECA-G
1 <48
<2.0
>99.90/,
<48
<2.0
>99.9%
<48
<2.0
>99.9%
<50
<2.0
>99.9%
Total Table 3+ (17 compounds)"
1
17,000
99.8%
99.6%
27,000
>99.9%
Notes:
1 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to two significant figures.
2 - Total Table 3+ (17 Compounds) does not include R-PSDA, Hydrolyzed PSDA and R-EVE.
3 - Sample Identification Label Key: "Seep - [A, B, C, or D] - [Sample Location Inside FTC] - [# of Aliquots in Composite Sample] - [MMDDYY]"
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
FTC - flow through cell
SOP - standard operating procedure
< - Analyte not detected above associated reporting limit.
TR0795C Page 12 of 13 June 2024
Table 2-4D
FTC Performance Monitoring Analytical Results - Seep D
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
Table 3 +SOP (n /L)
SEEP-D-INFLUENT
24-030724
Sample Date:
7-Mar-24
SEEP-D-EFFLUENT.
24-030724
Sample Date:
7-Mar-24
Percent Removal
SEEP-D-INFLUENT-
24-031124
Sample Date:
11-Mar-24
SEEP-D-EFFLUENT
24-031124
Sample Date:
11-Mar-24
Percent Removal
SEEP-D-INFLUENT
24-032324
Sample Date:
23-Mar-24
SEEP-D-EFFLUENT.
24-032324
Sample Date:
23-Mar-24
Percent Removal
SEEP-D-INFLUENT-
24-032824
Sample Date:
28-Mar-24
SEEP-D-EFFLUENT
24-032824
Sample Date:
28-Mar-24
Percent Removal
Hfpo Dimer Acid
3,900
2.6
99.9%
4,400
5.3
99.9%
4,300
2.8
99.9%
4,500
<2.0
>99.9%
PFMOAA
8,200
26
99.7%
11,000
67
99.4%
14,000
58
99.6%
15,000
12
99.9%
PFO2HxA
4,500
8.3
99.8%
5,700
19
99.7%
6,300
10
99.8%
6,500
2.0
>99.9%
PFO3OA
1,100
<2.0
>99.9%
1,700
<2.0
>99.9%
1,800
<2.0
>99.9%
1,800
<2.0
>99.9%
PFO4DA
470
<2.0
>99.9%
550
<2.0
>99.9%
600
<2.0
>99.9%
600
<2.0
>99.9%
PFO5DA
<78
<2.0
>99.9%
<78
<2.0
>99.9%
<78
<2.0
>99.9%
<78
<2.0
>99.9%
PMPA
2,000
<10
>99.9%
2,400
<10
>99.9%
2,900
<10
>99.9%
3,000
<10
>99.9%
PEPA
710
<10
>99.9%
850
<10
>99.9%
990
<10
>99.9%
1,000
<10
>99.9%
PS Acid
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
Hydro -PS Acid
81
<2.0
>99.9%
100
<2.0
>99.9%
120
<2.0
>99.9%
120
<2.0
>99.9%
R-PSDA
220 J
<2.0
>99.9%
360 J
<2.0
>99.9%
330 J
<2.0
>99.9%
330 J
<2.0
>99.9%
Hydrolyzed PSDA
220 J
<2.0
>99.9%
330 J
<2.0
>99.9%
300 J
<2.0
>99.9%
290 J
<2.0
>99.9%
R-PSDCA
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
NVHOS, Acid Form
120
<2.0
>99.9%
150
<2.0
>99.9%
170
<2.0
>99.9%
180
<2.0
>99.9%
EVE Acid
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
Hydro -EVE Acid
170
<2.0
>99.9%
220
<2.0
>99.9%
230
<2.0
>99.9%
250
<2.0
>99.9%
R-EVE
160 J
<2.0
>99.9%
270 J
<2.0
>99.9%
220 J
<2.0
>99.9%
230 J
<2.0
>99.9%
Perfluoro(2-ethoxyethane)sulfonic Acid
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
PFECA B
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
PFECA-G
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
<50
<2.0
>99.9%
Total Table 3+ (17 compounds)"
7
27,000
99.7%
99.8%
33,000
>99.9%
Notes:
1 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to two significant figures.
2 - Total Table 3+ (17 Compounds) does not include R-PSDA, Hydrolyzed PSDA and R-EVE.
3 - Sample Identification Label Key: "Seep - [A, B, C, or D] - [Sample Location Inside FTC] - [# of Aliquots in Composite Sample] - [MMDDYY]"
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
FTC - flow through cell
SOP - standard operating procedure
< - Analyte not detected above associated reporting limit.
TR0795C Page 13 of 13 June 2024
Table 2-5A
FTC Water Quality Data - Seep A
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Date
DO
(mg/L)
Influent Effluent Difference
pH
(SU)
Influent Effluent Difference
Specific Conductance
(AS/cm)
Influent Effluent Difference
Temperature
(°C)
Influent Effluent Difference
Turbidity
(NTU)
Influent Effluent Difference
TSS''
(mg/L)
Influent Effluent Difference[21
1/6/2024
10.21
6.46
-3.75
4.85
7.65
2.80
0.08
458.86
458.78
9.51
9.22
-0.29
0
0
0
11
<1
-11
1/10/2024
9.23
9.99
0.76
5.39
5.9
0.5
253.3
211.43
-41.9
7.2
6.22
-1.0
51.59
86.7
35.1
68
<1
-68
1/20/2024
5.88
3.73
-2.15
4.58
6.55
1.97
413.07
301.57
-111.50
15.04
13.6
-1.4
12.8
1.24
-11.6
9.9
<1
-9.9
1/31/2024
3.07
6.43
3.36
5.64
7.34
1.70
429.54
322.89
-106.65
15.36
15.48
0.12
26.4
2.51
-23.9
13
<1
-13
2/1/2024
2.36
7.18
4.82
7.13
7.5
0.4
813.45
499.27
-314.18
16.14
14.35
-1.79
21.6
1.83
-19.8
NS
NS
--
2/13/2024
7.86
9.28
1.42
6.54
5.38
-1.16
625.3
408.7
-216.6
18.36
16.06
-2.30
19.77
0.93
-18.84
3.5
2.1 J
-1.4
2/14/2024
10.44
11.84
1.40
5.38
5.62
0.24
590
360
-230
10.34
8.12
-2.22
2.33
0.53
-1.80
3.6
11
-3
3/2/2024
9.34
8.86
-0.48
4.8
5.08
0.3
140.44
101.21
-39.23
10.64
9.52
-1.12
4.75
2.14
-2.61
7.7
1.5 J
-6.2
3/7/2024
9.17
8.44
-0.73
4.86
4.81
-0.05
100.51
85.74
-14.77
10.11
9.6
-0.5
30.81
1.94
-28.87
70
2 J
-68
3/11/2024
8.6
8.56
0.0
6.86
5.22
-1.64
351.57
274.83
-76.74
14.46
14.62
0.16
27.25
0
-27
NS
NS
--
3/23/2024
9.82
9.73
-0.09
4.12
4.5
0.4
399.76
338.39
-61.37
19.16
18.88
-0.28
1.05
2.19
1.14
18
1.3 J
-17
3/28/2024
8.84
8.52
-0.32
4.11
4.58
0.47
403.53
336.26
-67.27
16.55
15.95
-0.60
8.37
0
-8
3
2.6 J
0
Average
7.9
8.15
0.3
5.4
5.8
0.4
411
308
-103
13.6
12.6
-0.9
19
9
-10
21
1
-20
Median
9.0
8.54
-0.5
5.1
5.5
0.4
1 404
330
-74
14.8
14.0
-0.8
20
2
-18
10
1
-9
Notes:
1 - TSS was measured by laboratory method SM 2540 D from grab samples collected concurrent with the performance samples.
2 - Non -detect influent and effluent TSS sample results were assigned a value of zero for statistical calculations.
3 - Influent specific conductance and turbidity measurements from 1/6/2024 are considerably lower than expected and have been excluded from statistical calculations.
4 - Specific conductance recorded on 2/14/24 was inadvertently recorded in mS/cm and has been converted to PS/cm.
J - Analyte detected. Reported value may not be accurate or precise.
°C - degrees Celsius
DO - dissolved oxygen
FTC - flow through cell
mg/L - milligrams per liter
mS/cm - milliSiemens per centimeter
NTU - nephelometric turbidity units
SU - standard units
TSS - total suspended solids
µS/cm - microSiemens per centimeter
NS - Sample not collected. Performance samples on 2/1/2024 and 3/11/2024 were inadvertently collected as wet weather samples, and concurrent TSS samples were not collected.
TR0795C Page 1 of 4 June 2024
Table 2-5B
FTC Water Quality Data - Seep B
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Date
DO
(mg/L)
Influent Effluent Difference
pH
(SU)
Influent Effluent Difference
Specific Conductance
(AS/cm)
Influent Effluent Difference
Temperature
(°C)
Influent Effluent Difference
Turbidity
(NTU)
Influent Effluent Difference
TSS''
(mg/L)
Influent Effluent Difference[21
1/10/2024
9.91
10.23
0.32
6.42
7.28
0.86
142.61
135.36
-7.25
5.2
4.76
-0.4
375.39
266.29
-109.10
71
29
-42
1/20/2024
6.82
7.54
0.72
6.59
7.18
0.59
163.64
42.1
-121.5
13.02
12.44
-0.58
41.2
50
9
24
5.9
-18
1/25/2024
9.85
10.46
0.61
7.12
7.07
-0.05
148.99
128.75
-20.24
13.34
13.25
-0.09
3.19
38.9
35.7
11
3.6
-7
1/31/2024
7.64
7.44
-0.20
7.56
7.82
0.26
131.37
106.08
-25.29
14.51
14.51
0.00
37.6
33.1
-4.5
13
4.9
-8
2/l/2024
7.42
8.24
0.82
8.19
8.35
0.16
329.06
151.32
-177.74
13.7
14.76
1.1
27.1
29.3
2.2
NS
NS
--
2/13/2024
9.97
9.82
-0.15
6.39
6.91
0.52
228.23
246.94
18.71
15.64
15.04
-0.60
29.27
11.13
-18.14
12
1.2 J
-11
2/14/2024
12.36
12.17
-0.19
6.13
6.42
0.29
180
230
50
7.65
8.41
0.76
40.88
9.37
-31.51
11
1.2 J
-10
3/2/2024
9.03
9.98
0.95
5.81
6.54
0.73
54.18
56.26
2.08
10.07
8.9
-1.2
91.56
30.39
-61.17
27
1.6 J
-25
3/7/2024
8.66
9.37
0.71
5.92
6.5
0.6
41.05
47.24
6.19
9.34
9.21
-0.13
445.94
277.83
-168.11
110
34
-76
3/11/2024
8.57
8
-1
6.07
6.96
0.89
188.35
196.99
8.64
14.08
14.3
0.2
87.56
30.29
-57.27
NS
NS
--
3/23/2024
9.81
8.21
-1.60
6.14
7.07
0.93
219.15
245.54
26.39
18.8
18.54
-0.3
8.6
0.02
-8.6
17
<1
-17
3/28/2024
9.65
8.11
-1.54
6.55
7.5
1.0
208.91
227.43
18.52
16.06
15.66
-0.40
9.75
0
-10
8.7
<1
-8.7
Average
9.14
9
0
6.57
7.1
0.6
170
151
-18
12.6
12.5
-0.1
99.8
65
-35
30
8
-22
Median
9.34
9
-1
6.41
7.1
0.7
172
143
-28
1 13.5
13.8
0.3
39.2
30
-9
15
3
-12
Notes:
1 - TSS was measured by laboratory method SM 2540 D from grab samples collected concurrent with the performance samples.
2 - Non -detect influent and effluent TSS sample results were assigned a value of zero for statistical calculations.
3 - Specific conductance recorded on 2/14/24 was inadvertently recorded in mS/cm and has been converted to PS/cm.
J - Analyte detected. Reported value may not be accurate or precise.
°C - degrees Celsius
DO - dissolved oxygen
FTC - flow through cell
mg/L - milligrams per liter
mS/cm - milliSiemens per centimeter
NTU - nephelometric turbidity units
SU - standard units
TSS - total suspended solids
µS/cm - microSiemens per centimeter
NS - Sample not collected. Performance samples on 2/1/2024 and 3/11/2024 were inadvertently collected as wet weather samples, and concurrent TSS samples were not collected.
TR0795C Page 2 of 4 June 2024
Table 2-5C
FTC Water Quality Data - Seep C
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Date
DO
(mg/L)
Influent Effluent Difference
pH
(SU)
Influent Effluent Difference
Specific Conductance
(AS/cm)
Influent Effluent Difference
Temperature
(°C)
Influent Effluent Difference
Turbidity
(NTU)
Influent Effluent Difference
TSS''
(mg/L)
Influent Effluent Difference [21
1/6/2024
8.8
9.31
0.5
7.62
7.54
-0.08
283.65
243.19
-40.46
9.65
9.85
0.20
197.63
39.42
-158.21
52 J
6.2
-46
1/10/2024
10.61
10.4
-0.2
7.52
8.21
0.69
180.82
175.32
-5.50
5.06
6.06
1.00
373.23
183.79
-189.44
100
30
-70
1/20/2024
7.79
4.81
-2.98
7.11
7.43
0.32
202.8
211.02
8.2
12.17
13.13
0.96
34.1
9.31
-24.8
21
<1
-21
1/31/2024
7.67
7.48
-0.19
8.1
8.13
7.95
-0.1
214.69
217.64
2.95
15.37
15.88
0.51
31
3.46
-28
18
<1
-18
2/l/2024
8.27
8.12
-0.15
8.19
0.06
276.17
271.46
-4.71
13.41
13.29
-0.12
25.8
2.67
-23.1
NS
NS
--
2/13/2024
10.16
9.55
-0.61
7.07
6.98
-0.09
246.1
257.81
11.7
15.56
15.97
0.41
236.39
100.42
-135.97
50
6.6
-43
2/14/2024
12.19
12.12
-0.07
6.55
6.75
0.20
260
290
30
7.92
7.22
-0.70
121.12
52.06
-69.06
42
6.5
-36
2/24/2024
6.69
7.29
0.60
8.05
8.17
0.12
304.53
313.67
9.14
21.09
20.25
-0.84
31
2.6
-28
NS
NS
--
3/2/2024
9.71
10.15
0.44
6.8
6.76
-0.04
75.06
72.34
-2.72
9.07
8.69
-0.38
167.68
44.81
-122.87
34
3
-31
3/7/2024
9.5
9.32
-0.2
6.63
6.77
0.14
54.37
54.88
0.51
9.38
9.22
-0.16
671.67
289.11
-382.56
120
33
-87
3/11/2024
9.02
8.07
-0.9
7.03
7.21
0.18
238.34
294.36
56.02
14.37
14.67
0.30
256.8
23.56
-233.2
NS
NS
--
3/23/2024
9.91
10.2
0.3
7.21
7.38
0.17
279.45
290.96
11.51
18.63
18.55
-0.08
34.7
0.15
-34.6
13
<1
-13
3/28/2024
8.78
8.43
-0.35
7.5
7.46
0.0
262.53
278.09
15.56
16.02
15.95
-0.07
42.98
0.14
-42.84
21
<1
-21
Average
9.2
8.9
-0.3
7.3
7.4
0.1
221
229
7
12.90
12.98
0.10
171
57.8
-113
47
9
-39
Median
9.0
9.3
0.3
7.2
7.4
0.2
246
258
12
13.41
13.29
-0.10
121
23.6
-98
38
5
-33
Notes:
1 - TSS was measured by laboratory method SM 2540 D from grab samples collected concurrent with the performance samples.
2 - Non -detect influent and effluent TSS sample results were assigned a value of zero for statistical calculations.
3 - Specific conductance recorded on 2/14/24 was inadvertently recorded in mS/cm and has been converted to PS/cm.
J - Analyte detected. Reported value may not be accurate or precise.
°C - degrees Celsius
DO - dissolved oxygen
FTC - flow through cell
mg/L - milligrams per liter
mS/cm - milliSiemens per centimeter
NTU - nephelometric turbidity units
SU - standard units
TSS - total suspended solids
µS/cm - microSiemens per centimeter
NS - Sample not collected. Performance samples on 2/l/2024, 2/24/2024, and 3/11/2024 were inadvertently collected as wet weather samples, and concurrent TSS samples were not collected.
TR0795C Page 3 of 4 June 2024
Table 2-5D
FTC Water Quality Data - Seep D
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Date
DO
(mg/L)
Influent Effluent Difference
pH
(SU)
Influent Effluent Difference
Specific Conductance
(AS/cm)
Influent Effluent Difference
Temperature
(°C)
Influent Effluent Difference
Turbidity
(NTU)
Influent Effluent Difference
TSS''
(mg/L)
Influent Effluent Difference[21
1/10/2024
9.96
10.55
0.59
8.11
7.88
-0.23
190.56
239.71
49.15
7.3
6.01
-1.3
57.87
2
-56
24
1.2 J
-23
1/20/2024
7.56
5.6
-2.0
7.4
7.38
0.0
119
113.39
-6
12.31
12.75
0.44
13
5.61
-7
3.9
1.5 J
-2.4
1/25/2024
9.46
11.45
1.99
7.26
7.46
0.20
123.5
154.49
31.0
14.78
16.9
2.1
13.3
7.58
-5.7
<1
4.6
4.6
1/31/2024
7.81
6.05
-1.76
7.98
7.88
-0.10
102.18
94.8
-7.4
16.68
16.7
0.0
14.3
8.63
-5.7
15
2.3 J
-13
2/l/2024
8.15
7.99
-0.16
8.32
7.57
-0.75
158.46
98.4
-60.1
13.52
15.95
2.43
13.4
6.43
-7.0
NS
NS
--
2/13/2024
10.06
10.05
-0.01
7.03
7.17
0.14
126.94
169.41
42.47
15.88
15.64
-0.24
26.72
1.62
-25.10
7.8
1.9 J
-5.9
2/14/2024
12.2
12.74
0.5
6.94
7.14
0.20
150
170
20
7.29
8.46
1.17
8.3
0.85
-7.5
6.6
<1
-6.6
3/2/2024
9.76
10.15
0.39
6.79
7.06
0.27
47.87
50.83
2.96
9.7
9.8
0.1
10.75
0.16
-10.59
6.2
<1
-6.2
3/7/2024
9.15
8.4
-0.8
6.8
7.03
0.2
40.36
43.93
3.57
9.67
9.98
0.31
32.86
2.81
-30.05
11
<1
-11
3/11/2024
8.72
9.22
0.50
7.28
7.52
0.24
174.36
174.22
-0.14
14.58
14.88
0.30
7.8
0
-8
NS
NS
--
3/23/2024
10.01
8.17
-1.84
7.37
7.49
0.12
157.64
180.49
22.85
18.89
18.9
0.0
0.54
0
-1
3.9
<1
-3.9
3/28/2024
9.32
7.74
-1.58
7.44
7.53
0.09
144.55
143.03
-1.52
16.01
15.84
-0.17
8.15
0
-8
17
<1
-17
Average
9.3
9.0
-0.3
7.4
7.43
0.0
128
136
8
13.1
13.5
0.4
17
3
-14
10
1
-8
Median
9.4
8.8
-0.6
7.3
7.48
0.2
136
149
13
14.1
15.3
1.2
13
1 2
-11
1 7
1
-7
Notes:
1 - TSS was measured by laboratory method SM 2540 D from grab samples collected concurrent with the performance samples.
2 - Non -detect influent and effluent TSS sample results were assigned a value of zero for statistical calculations.
3 - Specific conductance recorded on 2/14/24 was inadvertently recorded in mS/cm and has been converted to PS/cm.
J - Analyte detected. Reported value may not be accurate or precise.
°C - degrees Celsius
DO - dissolved oxygen
FTC - flow through cell
mg/L - milligrams per liter
mS/cm - milliSiemens per centimeter
NTU - nephelometric turbidity units
SU - standard units
TSS - total suspended solids
µS/cm - microSiemens per centimeter
NS - Sample not collected. Performance samples on 2/1/2024 and 3/11/2024 were inadvertently collected as wet weather samples, and concurrent TSS samples were not collected.
TR0795C Page 4 of 4 June 2024
Table 3-1
Ex -Situ Seeps and Weeps Flow Data
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
qr
Flow Totalizer Data from Seeps and Weeps Capture Systems Operated by GEOServices (gallons)
Surge Pond Flow to 004 GWTP Operated by Veolia
Date
Seep A Totalizer
(Cumulative)
Seep Tributary
Totalizerr (Cumulative)
Seep B Totalizer
(Cumulative)
Willis Creek Tributary
Totalizer (Cumulative)
Weep 3 Totalizer
(Cumulative)
Cumulative Volume
Calculated from Capture
System Totalizers
Daily Volume Conveyed from
Surge Pond to 004 Treatment
Plant (gallons)
Cumulative Volume Conveyed
from Surge Pond to 004
Treatment Plant (gallons)
Prior Total
5,964,450
1,228,013
3,361,104
528,576
404,083
11,486,226
12,029,484
1/1/2024
5,980,309
1,231,023
3,374,581
530,228
404,475
11,520,616
31,812
12,061,296
1/2/2024
5,993,858
1,233,839
3,390,023
531,658
404,802
11,554,180
30,520
12,091,817
1/3/2024
6,008,649
1,236,112
3,401,525
533,059
405,084
11,584,429
27,022
12,118,838
1/4/2024
6,023,169
1,238,791
3,415,545
534,684
405,373
11,617,562
28,220
12,147,059
1/5/2024
6,037,226
1,241,171
3,427,311
536,091
405,576
11,647,375
27,036
12,174,095
1/6/2024
6,128,889
1,257,803
3,439,909
537,471
413,834
11,777,906
32,194
12,206,290
1/7/2024
6,145,703
1,261,056
3,535,978
543,585
415,810
11,902,132
128,678
12,334,967
1/8/2024
6,162,930
1,264,268
3,555,969
545,898
416,916
11,945,981
131,030
12,465,997
1/9/2024
6,216,435
1,317,642
3,571,782
547,246
445,328
12,098,433
89,495
12,555,492
1/10/2024
6,371,098
1,336,364
3,759,007
554,555
456,376
12,477,400
127,791
12,683,284
1/11/2024
6,432,282
1,342,167
3,818,406
556,806
462,305
12,611,966
132,630
12,815,914
1/12/2024
6,455,531
1,363,769
3,852,073
559,118
477,629
12,708,120
133,314
12,949,228
1/13/2024
6,574,188
1,371,011
3,954,390
565,332
494,578
12,959,499
132,328
13,081,556
1/14/2024
6,598,579
1,376,893
3,990,872
567,928
499,600
13,033,872
135,167
13,216,724
1/15/2024
6,618,534
1,382,286
4,021,499
570,203
502,127
13,094,649
134,534
13,351,258
1/16/2024
6,636,946
1,387,739
4,053,266
572,200
505,165
13,155,316
132,987
13,484,244
1/17/2024
6,655,696
1,391,871
4,081,857
574,024
507,958
13,211,406
134,008
13,618,252
1/18/2024
6,671,785
1,395,893
4,104,740
575,694
511,170
13,259,282
133,681
13,751,933
1/19/2024
6,689,554
1,399,954
4,126,536
577,377
514,878
13,308,299
130,802
13,882,735
1/20/2024
6,706,560
1,403,941
4,151,422
579,007
520,695
13,361,625
132,288
14,015,023
1/21/2024
6,720,456
1,407,634
4,170,180
580,362
521,893
13,400,525
127,240
14,142,264
1/22/2024
6,737,065
1,411,281
4,195,277
581,705
522,832
13,448,160
127,104
14,269,368
1/23/2024
6,752,521
1,414,993
4,211,161
583,273
524,546
13,486,494
86,332
14,355,700
1/24/2024
6,769,344
1,418,362
4,233,025
584,679
526,308
13,531,718
39,752
14,395,452
1/25/2024
6,785,414
1,422,062
4,252,634
586,253
530,832
13,577,195
43,072
14,438,524
1/26/2024
6,802,564
1,425,603
4,278,320
587,666
540,821
13,634,974
50,782
14,489,306
1/27/2024
6,816,998
1,428,894
4,298,163
589,220
547,892
13,681,167
44,230
14,533,536
1/28/2024
6,833,132
1,432,099
4,318,960
590,742
550,658
13,725,591
38,935
14,572,471
1/29/2024
6,847,105
1,434,845
4,335,496
592,026
552,146
13,761,618
35,304
14,607,775
1/30/2024
6,861,676
1,437,694
4,351,041
593,259
553,441
13,797,111
28,823
14,636,597
1/31/2024
6,878,047
1,441,521
4,369,610
594,696
555,293
13,839,167
39,271
14,675,869
January Total
913,597
213,508
1,008,506
66,120
151,210
2,352,941
2,646,385
TR0795C Page 1 of 3 June 2024
Table 3-1
Ex -Situ Seeps and Weeps Flow Data
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
qr
Flow Totalizer Data from Seeps and Weeps Capture Systems Operated by GEOServices (gallons)
Surge Pond Flow to 004 GWTP Operated by Veolia
Date
Seep A Totalizer
(Cumulative)
Seep Tributary
Totalizerr (Cumulative)
Seep B Totalizer
(Cumulative)
Willis Creek Tributary
Totalizer (Cumulative)
Weep 3 Totalizer
(Cumulative)
Cumulative Volume
Calculated from Capture
System Totalizers
Daily Volume Conveyed from
Surge Pond to 004 Treatment
Plant (gallons)
Cumulative Volume Conveyed
from Surge Pond to 004
Treatment Plant (gallons)
2/1/2024
6,893,134
1,444,194
4,391,098
596,212
557,136
13,881,774
8,432
14,684,301
2/2/2024
6,907,235
1,447,106
4,406,243
597,216
558,566
13,916,366
22
14,684,324
2/3/2024
6,922,481
1,449,839
4,422,581
598,491
559,836
13,953,228
0
14,684,324
2/4/2024
6,936,228
1,452,314
4,435,930
599,653
561,215
13,985,340
0
14,684,324
2/5/2024
6,951,094
1,454,935
4,451,403
600,798
562,605
14,020,835
0
14,684,324
2/6/2024
6,964,536
1,457,298
4,464,165
601,919
566,403
14,054,321
0
14,684,324
2/7/2024
6,979,018
1,459,666
4,477,349
603,016
572,904
14,091,953
0
14,684,324
2/8/2024
6,992,529
1,461,533
4,489,153
604,120
574,549
14,121,884
4,342
14,688,666
2/9/2024
7,006,736
1,463,001
4,501,725
604,668
575,369
14,151,499
21,663
14,710,329
2/10/2024
7,020,713
1,464,227
4,513,244
604,991
576,173
14,179,348
106,590
14,816,918
2/11/2024
7,036,454
1,465,684
4,526,505
605,428
577,042
14,211,113
107,533
14,924,451
2/12/2024
7,099,832
1,478,265
4,542,817
605,753
588,972
14,315,639
108,225
15,032,676
2/13/2024
7,127,604
1,483,765
4,637,387
609,391
594,543
14,452,690
108,512
15,141,188
2/14/2024
7,142,776
1,485,510
4,653,793
610,116
596,462
14,488,657
110,248
15,251,436
2/15/2024
7,157,346
1,487,182
4,670,435
610,524
598,471
14,523,958
108,987
15,360,422
2/16/2024
7,173,003
1,488,609
4,683,907
610,836
600,969
14,557,324
92,150
15,452,573
2/17/2024
7,186,529
1,490,215
4,698,936
611,179
603,068
14,589,927
35,249
15,487,822
2/18/2024
7,200,968
1,491,431
4,710,669
611,481
605,653
14,620,202
26,613
15,514,435
2/19/2024
7,214,759
1,492,725
4,723,528
611,771
613,264
14,656,047
25,299
15,539,735
2/20/2024
7,229,431
1,493,894
4,733,948
612,057
621,837
14,691,167
24,811
15,564,546
2/21/2024
7,242,493
1,495,201
4,745,999
612,331
624,942
14,720,966
21,058
15,585,604
2/22/2024
7,259,099
1,496,449
4,756,456
612,608
626,053
14,750,665
22,799
15,608,403
2/23/2024
7,282,830
1,500,529
4,769,522
612,897
628,393
14,794,171
31,825
15,640,228
2/24/2024
7,296,813
1,502,101
4,798,430
614,131
629,672
14,841,147
42,378
15,682,605
2/25/2024
7,310,626
1,503,068
4,811,570
614,463
630,512
14,870,239
37,148
15,719,754
2/26/2024
7,325,324
1,504,356
4,822,003
614,746
631,488
14,897,917
19,558
15,739,312
2/27/2024
7,339,468
1,505,452
4,833,462
615,080
632,405
14,925,867
14,751
15,754,063
2/28/2024
7,354,695
1,506,813
4,844,320
615,394
634,873
14,956,095
16,201
15,770,264
2/29/2024
7,388,581
1,512,880
4,874,909
616,881
637,125
15,030 376
16,647
15,786,911
FebruaryTotal
S1Q534
71,359
505,299
22,185
81,832
1,191,209
1,111,042
TR0795C Page 2 of 3 June 2024
Table 3-1
Ex -Situ Seeps and Weeps Flow Data
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
qr
Flow Totalizer Data from Seeps and Weeps Capture Systems Operated by GEOServices (gallons)
Surge Pond Flow to 004 GWTP Operated by Veolia
Date
Seep A Totalizer
(Cumulative)
Seep Tributary
Totalizerr (Cumulative)
Seep B Totalizer
(Cumulative)
Willis Creek Tributary
Totalizer (Cumulative)
Weep 3 Totalizer
(Cumulative)
Cumulative Volume
Calculated from Capture
System Totalizers
Daily Volume Conveyed from
Surge Pond to 004 Treatment
Plant (gallons)
Cumulative Volume Conveyed
from Surge Pond to 004
Treatment Plant (gallons)
3/l/2024
7,402,029
1,514,576
4,886,429
617,261
641,116
15,061,411
17,245
15,804,156
3/2/2024
7,489,262
1,531,305
4,985,929
621,275
668,176
15,295,947
17,560
15,821,716
3/3/2024
7,513,440
1,533,855
5,011,819
623,140
672,416
15,354,670
17,945
15,839,660
3/4/2024
7,528,150
1,535,776
5,034,428
623,664
677,852
15,399,870
18,380
15,858,040
3/5/2024
7,544,394
1,537,939
5,051,750
624,075
678,884
15,437,042
18,592
15,876,633
3/6/2024
7,699,057
1,583,476
5,068,900
624,441
697,402
15,673,276
27,984
15,904,616
3/7/2024
7,782,972
1,590,649
5,256,125
630,495
706,202
15,966,443
72,532
15,977,148
3/8/2024
7,805,602
1,594,149
5,299,594
632,130
711,335
16,042,810
73,920
16,051,068
3/9/2024
7,857,432
1,604,379
5,345,754
632,743
719,883
16,160,191
74,346
16,125,414
3/10/2024
7,879,754
1,607,958
5,399,176
636,405
722,340
16,245,633
74,535
16,199,949
3/11/2024
7,895,379
1,607,958
5,429,496
637,499
724,155
16,294,487
72,247
16,272,197
3/12/2024
7,910,891
1,608,008
5,438,674
638,061
726,520
16,322,154
81,705
16,353,902
3/13/2024
7,927,096
1,610,644
5,483,227
638,538
728,770
16,388,275
80,191
16,434,092
3/14/2024
7,979,875
1,613,077
5,490,116
638,987
730,708
16,452,763
115,952
16,550,045
3/15/2024
7,993,979
1,615,561
5,490,749
639,405
733,170
16,472,864
115,216
16,665,261
3/16/2024
8,007,804
1,617,855
5,506,378
639,830
735,424
16,507,291
115,356
16,780,616
3/17/2024
8,022,901
1,620,070
5,526,912
640,234
737,762
16,547,879
115,413
16,896,029
3/18/2024
8,036,595
1,621,944
5,543,845
640,815
739,902
16,583,101
115,204
17,011,233
3/19/2024
8,050,940
1,623,944
5,561,103
641,121
741,693
16,618,801
109,383
17,120,616
3/20/2024
8,064,244
1,625,767
5,575,544
641,452
743,273
16,650,280
69,429
17,190,045
3/21/2024
8,078,816
1,627,553
5,591,513
641,986
744,619
16,684,487
68,745
17,258,790
3/22/2024
8,092,467
1,629,413
5,605,164
642,293
746,198
16,715,535
45,806
17,304,596
3/23/2024
8,112,576
1,634,064
5,639,231
643,245
748,645
16,777,761
42,432
17,347,029
3/24/2024
8,125,663
1,635,565
5,658,539
644,141
749,921
16,813,829
42,647
17,389,676
3/25/2024
8,139,764
1,637,340
5,673,738
644,399
751,566
16,846,807
42,209
17,431,884
3/26/2024
8,153,538
1,638,836
5,687,644
644,700
753,067
16,877,785
42,308
17,474,192
3/27/2024
8,168,769
1,640,887
5,703,704
645,218
759,491
16,918,069
42,814
17,517,007
3/28/2024
8,268,358
1,656,793
5,794,854
650,037
782,885
17,152,927
42,189
17,559,196
3/29/2024
8,283,123
1,658,934
5,846,661
652,306
815,805
17,256,829
134,316
17,693,512
3/30/2024
8,298,571
1,660,832
5,866,649
653,657
818,640
17,298,349
142,411
17,835,923
3/31/2024
8,312,979
1,662,642
5,886,153
654,716
849,827
17,366,317
142,117
17,978,040
March Total
924,398
149,762
1,011,244
37,835
212,702
2,335,941
2,191,129
Reporting Period Total
2,348,529
434,629
2,525,049
126,140
445,744
5,880,091
5,948,556
Notes:
1 - Flow data from the Surge Pond through the 004 ground water treatment plant (GWTP) is collected and managed by Veolia.
2 - The daily volume conveyed from surge pond to 004 Treatment Plant is recorded on a 24-hour basis, ending daily at 1 pm. For simplicity, the volume totaled through 1 pm is shown as the daily total in this table.
TR0795C Page 3 of 3 June 2024
Table 4-1
Extraction and Observation Well Construction Details
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
WELL ID
TARGET AQUIFER
NORTHING
(FT, NAD83)
EASTING
(FT, NAD83)
TOP OF
CASING
ELEVATION
(FT, NAVD88)
WELL
DIAMETER
(INCHES)
WELL
DEPTH
(FT, BGS)
WELL
SCREEN
INTERVAL
(FT, BGS)
BCA-01
Black Creek Aquifer
399779.96
2050662.48
146.25
2
101
91-101
BCA-02
Black Creek Aquifer
396242.02
2051062.07
148.37
2
102
92-102
EW-01
Black Creek Aquifer
401683.69
2049951.04
92.04
6
85
60-80
EW-02
Black Creek Aquifer
401683.61
2050289.26
87.97
6
65
40-60
EW-03
Black Creek Aquifer
401723.50
2050594.78
84.67
6
72
57-67
EW-04
Black Creek Aquifer
401714.92
2050848.03
80.00
6
65
50-60
EW-05
Black Creek Aquifer
401654.63
2051059.46
82.93
6
78
63-73
EW-06
Black Creek Aquifer
401489.44
2051117.72
83.58
6
75
50-70
EW-07
Black Creek Aquifer
401350.61
2051160.78
86.45
6
68
53-63
EW-08
Black Creek Aquifer
401184.55
2051164.30
89.05
6
73
58-68
EW-09
Black Creek Aquifer
401008.87
2051129.57
81.08
6
65
40-60
EW-10
Black Creek Aquifer
400870.94
2051128.67
74.12
6
55
30-50
EW-11
Black Creek Aquifer
400683.82
2051280.71
93.12
6
75
60-70
EW-12
Black Creek Aquifer
400591.86
2051415.21
92.10
6
75
50-70
EW-13
Black Creek Aquifer
400527.75
2051513.14
87.95
6
79
54-74
EW-14
Black Creek Aquifer
400375.11
2051570.80
82.23
6
62
47-57
EW-15
Black Creek Aquifer
400223.63
2051556.86
77.23
6
53
38-48
EW-16
Black Creek Aquifer
400042.92
2051489.09
88.11
6
65
50-60
EW-17
Black Creek Aquifer
399975.22
2051517.08
87.84
6
65
40-60
EW-18
Surficial Aquifer
399828.16
2051586.65
74.56
6
30
15-25
EW-19
Black Creek Aquifer
399819.25
2051590.67
74.65
6
51
36-46
EW-20
Surficial Aquifer
399696.08
2051667.78
78.48
6
30
15-25
EW-21
Black Creek Aquifer
399549.59
2051687.61
84.66
6
62
47-57
EW-22
Surficial Aquifer
399298.40
2051754.69
82.54
6
37
22-32
EW-23
Black Creek Aquifer
399289.65
2051759.07
83.05
6
70
45-65
EW-24
Surficial Aquifer
399105.96
2051845.20
83.63
6
31
16-26
EW-25
Black Creek Aquifer
399097.14
2051848.27
83.44
6
75
60-70
EW-26S
Surficial Aquifer
398992.13
2051869.73
83.50
6
30
15-25
EW-27
Surficial Aquifer
398883.14
2051881.19
85.81
6
33
18-28
EW-28
Black Creek Aquifer
398873.71
2051882.01
85.83
6
55
40-50
EW-29
Surficial Aquifer
398743.82
2051874.08
80.62
6
34
19-29
EW-30
Black Creek Aquifer
398733.15
2051872.90
82.01
6
80
55-75
EW-31
Surficial Aquifer
398619.06
2051860.80
80.84
6
33
18-28
EW-32
Black Creek Aquifer
398606.76
2051858.39
81.55
6
53
38-48
EW-33
Surficial Aquifer
398413.39
2051843.45
78.32
6
25
10-20
EW-34
Black Creek Aquifer
398403.44
2051844.29
77.11
6
75
40-70
EW-35
Surficial Aquifer
398342.37
2051862.99
74.44
6
18
8-13
EW-36
Black Creek Aquifer
398333.72
2051867.55
73.98
6
73
38-48,58-68
EW-37
Surficial Aquifer
398234.57
2051923.02
74.03
6
54
39-49
EW-38
Black Creek Aquifer
398229.45
2051926.24
74.19
6
80
55-75
EW-39
Surficial Aquifer
398113.89
2051992.69
77.19
6
21
6-16
EW-40
Black Creek Aquifer
398104.84
2051997.57
77.00
6
85
60-80
TR0795C Page 1 of 4 June 2024
Table 4-1
Extraction and Observation Well Construction Details
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
WELL ID
TARGET AQUIFER
NORTHING
(FT, NAD83)
EASTING
(FT, NAD83)
TOP OF
CASING
ELEVATION
(FT, NAVD88)
WELL
DIAMETER
(INCHES)
WELL
DEPTH
(FT, BGS)
WELL
SCREEN
INTERVAL
(FT, BGS)
EW-41
Black Creek Aquifer
397944.33
2052019.70
84.99
6
75
50-70
EW-42
Black Creek Aquifer
397792.20
2052011.87
81.93
6
74
49-69
EW-43
Black Creek Aquifer
397657.42
2052005.16
81.80
6
76
51-71
EW-44
Surficial Aquifer
397520.77
2051997.72
75.22
6
18
8-13
EW-45
Black Creek Aquifer
397511.10
2051997.30
75.33
6
71
46-66
EW-46
Surficial Aquifer
397374.10
2051993.17
74.94
6
32
17-27
EW-47
Black Creek Aquifer
397364.92
2051992.87
75.02
6
68
43-63
EW-48
Surficial Aquifer
397290.64
2052028.52
79.87
6
31
16-26
EW-49
Black Creek Aquifer
397282.27
2052032.79
79.65
6
79
54-74
EW-50
Surficial Aquifer
397105.59
2052107.53
77.80
6
30
15-25
EW-51
Black Creek Aquifer
397096.10
2052109.76
78.36
6
70
45-65
EW-52
Black Creek Aquifer
396902.85
2052151.05
75.84
6
70
45-65
EW-53
Black Creek Aquifer
396713.03
2052190.03
76.33
6
67
42-62
EW-54
Black Creek Aquifer
396559.35
2052223.00
75.31
6
65
40-60
EW-55
Black Creek Aquifer
396358.87
2052225.92
86.59
6
80
55-75
EW-56
Black Creek Aquifer
396173.96
2052249.38
79.69
6
71
46-66
EW-57
Black Creek Aquifer
395992.47
2052247.52
84.92
6
70
45-65
EW-58
Black Creek Aquifer
395810.15
2052290.53
74.69
6
65
40-60
EW-60
Black Creek Aquifer
395425.21
2052313.29
77.65
6
68
43-63
EW-61
Black Creek Aquifer
395283.80
2052271.16
78.46
6
75
50-70
EW-62
Black Creek Aquifer
395170.54
2052195.07
83.12
6
65
40-60
EW-63
Black Creek Aquifer
395055.17
2052033.12
122.53
6
103
88-98
EW-64
Black Creek Aquifer
394924.16
2051976.78
121.67
6
85
60-80
EW-65
Black Creek Aquifer
394819.93
2051918.54
116.36
6
75
50-70
EW-66
Black Creek Aquifer
394823.51
2051780.19
115.77
6
101
76-96
EW-67
Black Creek Aquifer
394780.57
2051655.69
103.22
6
98
73-93
EW-68
Black Creek Aquifer
394728.65
2051563.34
96.82
6
92
67-87
EW-69
Black Creek Aquifer
394649.04
2051478.42
87.55
6
85
60-80
LTW-02
Black Creek Aquifer
398847.57
2052355.48
51.39
2
38
28-38
LTW-03
Floodplain Deposits
398114.45
2052558.35
51.75
2
30
15-30
LTW-04
Floodplain Deposits
397279.61
2052584.95
50.66
2
27
12-27
LTW-05
Black Creek Aquifer
396430.31
2052740.40
50.94
2
44
29-44
NAF-11B
Surficial Aquifer
398911.13
2050995.88
140.74
2
44
33.5-43.5
OW-02
Black Creek Aquifer
398572.28
2051801.62
84.37
2
73
63-73
OW-03
Black Creek Aquifer
398601.08
2051812.32
84.64
2
73
63-73
OW-04
Black Creek Aquifer
395049.16
2052210.81
80.85
2
57
47-57
OW-04R
Black Creek Aquifer
394990.53
2052236.29
80.03
2
61
51-61
OW-07
Black Creek Aquifer
397180.06
2052052.69
81.45
2
67
57-67
OW-08
Black Creek Aquifer
397202.33
2052041.98
82.30
2
67
57-67
OW-09
Black Creek Aquifer
395075.14
2052211.07
79.78
2
64
54-64
OW-09R
Black Creek Aquifer
395001.93
2052252.38
78.53
2
65
55-65
OW-11
Black Creek Aquifer
401683.39
2049913.61
94.92
1
84
74-84
OW-12
Black Creek Aquifer
401731.33
2050721.09
83.65
1
60
50-60
OW-13
Black Creek Aquifer
400769.33
2051210.62
85.12
1
60
50-60
OW-14
Black Creek Aquifer
400311.42
2051608.03
80.67
1
56
46-56
TR0795C Page 2 of 4 June 2024
Table 4-1
Extraction and Observation Well Construction Details
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
WELL ID
TARGET AQUIFER
NORTHING
(FT, NAD83)
EASTING
(FT, NAD83)
TOP OF
CASING
ELEVATION
(FT, NAVD88)
WELL
DIAMETER
(INCHES)
WELL
DEPTH
(FT, BGS)
WELL
SCREEN
INTERVAL
(FT, BGS)
OW-15
Black Creek Aquifer
399719.91
2051608.62
87.86
1
44
34-44
OW-16
Black Creek Aquifer
399828.66
2051993.25
52.94
1
25
15-25
OW-17
Black Creek Aquifer
399433.03
2051661.47
89.67
1
68
58-68
OW-18
Black Creek Aquifer
398846.69
2051836.19
90.88
1
55
45-55
OW-19
Black Creek Aquifer
398067.23
2051976.50
86.68
1
80
70-80
OW-20
Black Creek Aquifer
398229.85
2052080.86
69.59
1
58
48-58
OW-21
Black Creek Aquifer
397521.83
2051950.75
80.85
1
67
57-67
OW-22
Black Creek Aquifer
397325.34
2052218.74
66.63
1
53
43-53
OW-23
Black Creek Aquifer
396776.73
2052355.66
67.83
1
55
45-55
OW-24
Black Creek Aquifer
396677.42
2052158.17
78.67
1
60
50-60
OW-25
Black Creek Aquifer
396182.38
2052428.46
70.91
1
55
45-55
OW-26
Black Creek Aquifer
395503.74
2052268.81
80.85
1
60
50-60
OW-27
Black Creek Aquifer
395555.17
2052622.16
55.6
1
43
33-43
OW-28
Black Creek Aquifer
395570.57
2052838.21
48.49
2
30
20-30
OW-29
Black Creek Aquifer
395193.45
2052143.81
85.67
1
52
42-52
OW-30
Black Creek Aquifer
394988.72
2052537.53
70.92
2
59
49-59
OW-31
Black Creek Aquifer
394812.07
2051595.90
106.1
1
95
85-95
OW-32
Black Creek Aquifer
394563.76
2051792.16
85.05
2
72
62-72
OW-33
Black Creek Aquifer
395116.90
2052806.54
48.59
2
29
19-29
OW-34
Surficial Aquifer
398593.54
2051813.31
83.76
1
33
23-33
OW-35
Surficial Aquifer
398060.78
2051977.75
87.45
1
30
20-30
OW-36
Surficial Aquifer
397257.46
2051997.45
80.61
1
21
11-21
OW-37
Surficial Aquifer
396154.99
2052264.10
77.82
2
35
25-35
OW-38
Black Creek Aquifer
394885.22
2051883.97
123.7
1
70
60-70
OW-39
Black Creek Aquifer
394728.70
2052105.68
92.07
2
78
68-78
OW-40
Black Creek Aquifer
394588.05
2052521.39
72.88
2
59
49-59
OW-41
Black Creek Aquifer
401683.74
2050119.92
93.66
1
92
82-92
OW-42
Black Creek Aquifer
401696.05
2050448.24
87.37
1
68
58-68
OW-43
Black Creek Aquifer
400937.73
2051116.17
76.94
1
50
40-50
OW-44
Black Creek Aquifer
399741.48
2051736.45
73.18
1
44
34-44
OW-45
Black Creek Aquifer
398836.07
2051955.99
77.1
1
60
50-60
OW-46
Black Creek Aquifer
398164.94
2052050.69
72.05
1
69
59-69
OW-47
Black Creek Aquifer
397243.89
2052136.32
71.47
1
59
49-59
OW-48
Black Creek Aquifer
396698.39
2052275.93
69.54
1
52
42-52
OW-49
Black Creek Aquifer
396180.56
2052348.51
79.56
1
63
53-63
OW-50
Black Creek Aquifer
395529.59
2052379.97
71.53
1
53
43-53
OW-51
Black Creek Aquifer
396166.08
2052262.14
77.72
2
66
56-66
OW-52
Black Creek Aquifer
397562.30
2052151.03
60.66
2
47
37-47
OW-53
Black Creek Aquifer
397530.83
2052055.05
75.16
2
68
56-66
OW-54
Black Creek Aquifer
401068.86
2051275.96
47.42
2
12
7-12
OW-55
Black Creek Aquifer
401761.92
2050875.02
75.45
2
58
43-58
OW-56
Black Creek Aquifer
401983.45
2050634.71
44.69
2
12
7-12
OW-57
Black Creek Aquifer
401781.20
2050174.65
68.87
2
43
33-43
PIW-10DR
Black Creek Aquifer
395093.99
2052297.30
75.91
2
58
53-58
PIW-11
Black Creek Aquifer
401911.03
2050416.29
67.02
2
57
47-57
TR0795C Page 3 of 4 June 2024
Table 4-1
Extraction and Observation Well Construction Details
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
WELL ID
TARGET AQUIFER
NORTHING
(FT, NAD83)
EASTING
(FT, NAD83)
TOP OF
CASING
ELEVATION
(FT, NAVD88)
WELL
DIAMETER
(INCHES)
WELL
DEPTH
(FT, BGS)
WELL
SCREEN
INTERVAL
(FT, BGS)
PIW-12
Black Creek Aquifer
401703.10
2051025.77
83.78
2
74
64-74
PIW-13
Black Creek Aquifer
401464.29
2051122.60
83.18
2
64
54-64
PIW-14
Black Creek Aquifer
401163.98
2051186.57
87.43
2
66
56-66
PIW-15
Black Creek Aquifer
400706.51
2051532.80
67.85
2
44
34-44
PIW-1D
Black Creek Aquifer
400548.00
2051801.28
52.16
2
30
24.5-29.5
PIW-2D
Black Creek Aquifer
399925.40
2051315.80
96.19
2
50
40-50
PIW-3D
Black Creek Aquifer
399711.25
2052086.94
53.42
2
24
19-24
PIW-4D
Black Creek Aquifer
398816.52
2052101.94
52.85
2
37
32.3-37.3
PIW-5S
Surficial Aquifer
398519.70
2051950.49
75.02
2
19.8
9.8-19.8
PIW-5SR
Surficial Aquifer
398545.03
2051977.42
79.60
2
25
15-25
PIW-6S
Floodplain Deposits
398117.93
2052539.79
53.40
2
28
18-28
PIW-7D
Black Creek Aquifer
396787.77
2052595.65
48.93
2
34
29-34
PIW-7S
Floodplain Deposits
396786.97
2052589.10
47.97
2
17
7-17
PIW-8D
Black Creek Aquifer
396403.37
2052682.10
48.66
2
40
35-40
PW-02
Surficial Aquifer
399779.06
2050649.47
146.43
2
60
50-60
PW-03
Surficial Aquifer
397339.81
2050765.32
147.97
2
45
35-45
PW-04
Surficial Aquifer
394659.55
2050940.66
97.75
2
27
17-27
PW-1 OR
Black Creek Aquifer
398516.12
2051936.59
75.90
2
67
57-67
PW-IORR
Black Creek Aquifer
398532.53
2051965.93
79.97
2
71
61-71
PW-11
Black Creek Aquifer
394354.36
2052226.72
73.26
2
64
53-63
PW-14
Black Creek Aquifer
397325.65
2050766.36
147.97
2
146
136-146
PW-15R
Black Creek Aquifer
398900.88
2051011.75
136.14
2
120
110-120
PZ-22
Black Creek Aquifer
397271.94
2052585.34
50.70
1
48
42.5-47.5
SMW-03B
Black Creek Aquifer
399785.75
2049421.54
150.43
2
82
72-82
SMW-09
Surficial Aquifer
401076.89
2050017.41
141.43
2
62
52-62
SMW-12
Black Creek Aquifer
401314.20
2051007.22
118.22
2
98
88-98
Notes:
1 - This table provides well construction details for the wells included under the Performance Monitoring Plan (PMP). It is not comprehensive
to the entire well network at the Site.
2 - At one drilling location, EW-59, Black Creek aquifer material was not encountered, therefore there was not a suitable interval to install the
well screen. This borehole was abandoned prior to well installation.
BGS - below ground surface
EW - extraction well
NAD83 - North American Datum of 1983
NAVD88 - North American Vertical Datum of 1988
OW - observation well
TR0795C Page 4 of 4 June 2024
Table 4-2
Summary of GWEC Flow Data
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Date
Average Extraction Flow
Rate (gpm)
Cumulative Volume
Extracted (gallons)
Prior Total
N/A
188,853,643
1/1/2024
346
189,353,371
1/2/2024
341
189,851,019
l /3/2024
345
190,350,859
1 /4/2024
338
190,840,139
1/5/2024
327
191,314,171
1 /6/2024
340
191,807,195
1 /7/2024
335
192,292,491
1/8/2024
324
192,762,171
1/9/2024
331
193,252,283
1/10/2024
328
193,731,387
1/11/2024
337
194,217,467
1/12/2024
338
194,707,467
1/13/2024
340
195,199,659
1/14/2024
341
195,693,067
1/15/2024
336
196,178,011
1/16/2024
337
196,673,723
1/17/2024
339
197,164,859
1/18/2024
354
197,676,795
1/19/2024
352
198,186,011
1/20/2024
348
198,688,667
1/21/2024
345
199,191,323
1/22/2024
342
199,694,539
1/23/2024
342
200,187,483
1/24/2024
340
200,680,635
1/25/2024
340
201,173,035
1/26/2024
338
201,661,291
1/27/2024
334
202,144,843
1/28/2024
334
202,629,995
1/29/2024
333
203,111,787
1/30/2024
346
203,609,708
1/31/2024
351
204,114,139
January Total
N/A
15,260,496
TR0795C Page 1 of 3 June 2024
Table 4-2
Summary of GWEC Flow Data
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Date
Average Extraction Flow
Rate (gpm)
Cumulative Volume
Extracted (gallons)
2/1/2024
349
204,619,115
2/2/2024
348
205,124,123
2/3/2024
344
205,621,611
2/4/2024
345
206,120,715
2/5/2024
344
206,618,667
2/6/2024
340
207,111,611
2/7/2024
343
207,608,123
2/8/2024
346
208,109,435
2/9/2024
346
208,610,971
2/10/2024
347
209,111,771
2/11/2024
345
209,611,995
2/12/2024
346
210,114,411
2/13/2024
341
210,608,347
2/14/2024
341
211,100,635
2/15/2024
324
211,569,867
2/16/2024
344
212,067,915
2/17/2024
346
212,568,539
2/18/2024
345
213,067,867
2/19/2024
343
213,565,723
2/20/2024
340
214,058,187
2/21/2024
318
214,525,419
2/22/2024
294
214,949,835
2/23/2024
339
215,447,515
2/24/2024
344
215,943,947
2/25/2024
343
216,439,035
2/26/2024
345
216,938,795
2/27/2024
344
217,437,083
2/28/2024
339
217,928,459
2/29/2024
337
218,416,891
February Total
N/A
14,302,752
TR0795C Page 2 of 3 June 2024
Table 4-2
Summary of GWEC Flow Data
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Date
Average Extraction Flow
Rate (gpm)
Cumulative Volume
Extracted (gallons)
3/1/2024
342
218,911,195
3/2/2024
343
219,408,459
3/3/2024
343
219,904,491
3/4/2024
346
220,405,243
3/5/2024
344
220,902,747
3/6/2024
345
221,402,763
3/7/2024
340
221,894,347
3/8/2024
338
222,383,963
3/9/2024
342
222,878,939
3/10/2024
338
223,348,395
3/11/2024
337
223,835,963
3/12/2024
295
224,263,387
3/13/2024
266
224,651,339
3/14/2024
326
225,128,635
3/15/2024
332
225,610,347
3/16/2024
334
226,092,939
3/17/2024
333
226,574,267
3/18/2024
331
227,053,211
3/19/2024
327
227,526,315
3/20/2024
323
227,995,035
3/21/2024
301
228,430,971
3/22/2024
333
228,909,830
3/23/2024
335
229,392,611
3/24/2024
330
229,867,288
3/25/2024
325
230,335,968
3/26/2024
334
230,817,011
3/27/2024
332
231,294,397
3/28/2024
331
231,771,480
3/29/2024
330
232,247,068
3/30/2024
333
232,726,081
3/31/2024
333
233,205,457
March Total
I N/A
14,788,566
Reporting Period Total
44,351,814
Notes:
1 - Flow rate measurements are collected by the manifold flow meter every 15 minutes.
2 - The cumulative volume extracted is recorded by the GWEC system flow totalizer.
3 - The monthly and reporting period totals are not applicable (N/A) for flow rate values.
GWEC - Groundwater Extraction and Conveyance
gpm - gallons per minute
TR0795C Page 3 of 3 June 2024
Table 4-3
Extraction Well Flow Data
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Average Extraction Flow Rate (gpm)
Total Volume (gal)
Well ID
January
February
March
January
February
March
Total Reporting
Period
Willis Creek (Northern Alinment)
EW-01
12.84
12.12
12.93
573,193
506,287
576,979
1,656,459
EW-02
5.83
5.57
5.96
260,442
232,749
266,189
759,381
EW-03
2.38
2.34
2.49
106,131
97,916
111,014
315,061
EW-04
1.01
0.75
0.55
45,055
31,470
24,717
101,241
EW-05
13.88
12.93
13.75
619,474
540,113
613,978
1,773,565
EW-06
7.93
7.50
7.86
353,906
313,348
350,861
1,018,115
EW-07
2.27
1.87
0.68
101,142
78,245
30,294
209,681
EW-08
4.28
4.21
4.08
191,060
175,812
182,078
548,949
EW-09
0.03
0.01
0.00
1,416
601
145
2,162
EW-10
1.15
0.77
0.57
51,262
32,285
25,288
108,835
EW-11
1.64
0.54
0.26
73,402
22,537
11,770
107,710
EW-12
1.32
0.86
1.06
58,919
35,778
47,193
141,890
EW-13
0.80
0.67
0.61
35,867
28,150
27,343
91,359
EW-14
4.46
4.45
4.40
199,131
185,883
196,611
581,625
EW-15
0.00
0.00
0.00
0
0
0
0
Average Northern
Alignment EW
3.99
3.64
3.68
N/A
N/A
N/A
N/A
Barrier Wall (Southern Alignment) AM
EW-16
0.00
0.00
0.00
0
0
0
0
EW-17
0.01
0.01
0.19
580
615
8,526
9,720
EW-18
1.00
0.67
0.75
44,774
28,061
33,348
106,183
EW-19
1.04
2.17
2.45
46,570
90,410
109,555
246,535
EW-20
0.23
0.25
0.30
10,318
10,413
13,344
34,075
EW-21
0.00
0.00
0.00
0
0
0
0
EW-22
6.94
6.92
6.98
309,793
289,128
311,430
910,351
EW-23
0.00
0.00
0.00
0
0
0
0
EW-24
2.97
2.97
2.99
132,769
123,901
133,484
1 390,154
EW-25
1.42
1.73
1.60
63,488
72,305
71,463
207,256
EW-26S
0.76
0.71
0.80
33,839
29,539
35,642
99,020
EW-27
4.96
4.94
4.98
221,311
206,447
222,477
650,234
EW-28
0.74
0.71
0.74
32,919
29,787
33,029
95,734
EW-29
4.46
4.45
4.49
199,181
185,808
200,229
585,219
EW-30
3.96
3.95
3.99
176,997
165,153
177,955
520,105
EW-31
7.93
7.91
7.97
354,031
330,301
355,921
1 1,040,254
EW-32
0.68
0.47
1.13
30,561
19,482
50,441
100,484
EW-33
1.46
1.63
1.65
65,168
68,105
73,714
206,987
EW-34
5.16
5.94
4.99
230,336
247,871
222,583
700,791
EW-35
0.00
0.00
0.00
0
0
4
4
EW-36
7.80
7.91
7.97
348,320
330,335
355,928
1,034,584
EW-37
4.46
4.45
4.49
199,190
185,770
200,243
585,202
EW-38
16.77
16.68
16.94
748,710
696,735
756,382
2,201,828
EW-39
1.37
1.41
1.46
60,952
58,963
65,039
184,953
EW40
19.83
19.78
19.93
885,010
826,006
889,836
2,600,851
EW-41
5.95
5.92
4.04
265,423
247,186
180,360
692,968
EW42
3.96
3.95
3.98
176,926
165,121
177,871
519,918
EW-43
4.95
4.91
4.98
220,925
204,966
222,451
648,343
EW44
0.00
0.00
0.00
0
0
0
0
EW-45
2.96
3.18
3.99
132,037
132,852
177,903
442,792
EW46
0.00
0.00
0.00
0
0
0
0
EW47
3.73
3.96
3.99
166,624
165,226
177,917
509,767
EW48
0.68
0.76
0.87
30,523
31,717
38,637
100,877
EW49
5.90
5.93
5.98
263,383
247,742
267,123
778,248
EW-50
1.98
1.98
1.99
88,402
82,503
88,962
259,867
EW-51
3.86
3.95
3.99
172,193
165,137
178,059
1 515,389
EW-52
3.86
5.93
5.98
172,152
247,801
267,140
687,093
EW-53
4.30
4.45
4.49
191,901
185,869
200,399
578,170
EW-54
2.60
2.97
2.99
115,933
123,911
133,431
373,275
EW-55
3.24
3.47
3.49
144,623
145,029
155,620
445,273
EW-56
5.92
5.92
5.98
264,121
247,297
266,871
778,289
EW-57
0.00
0.00
0.00
0
0
0
0
EW-58
1 1.48
1 1.46
1 1.61
1 66,014
1 60,790
72,090
198,893
EW-60
1 0.24
1 0.21
1 0.01
1 10,758
1 8,614
641
20,012
TR0795C Page 1 of 2 June 2024
Table 4-3
Extraction Well Flow Data
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Average Extraction Flow Rate (gpm)
Total Volume (gal)
Well ID
January
February
March
January
February
March
Total Reporting
Period
EW-61
2.08
2.06
2.23
93,021
86,048
99,624
278,693
EW-62
1.57
1.84
2.16
69,968
76,772
96,642
243,382
EW-63
10.85
10.79
10.95
484,311
450,736
488,673
1,423,720
EW-64
0.00
0.00
0.00
0
0
0
0
EW-65
0.84
1.24
1.31
37,309
51,592
58,648
147,549
EW-66
11.88
11.78
11.95
530,284
491,987
533,341
1,555,612
EW-67
31.72
1 31.65
1 31.86
1,415,999
1,321,605
1 1,422,148
1 4,159,752
EW-68
27.75
27.69
27.87
1,238,702
1,156,354
1,244,330
3,639,386
EW-69
27.74
27.58
27.88
1,238,131
1,151,841
1,244,354
3,634,326
Average Southern
Alignment EW
4.98
1
5.08
5.12
N/A
N/A
N/A
N/A
Notes:
1 - Each well's flowmeter records flow rate every 15 minutes, including instances of no flow for pumps that are cycling as opposed to operating continuously. The calculated
monthly average accounts for these instances of no flow. The values above are therefore not necessarily representative of the target flow rate setpoint for each well.
gpm - gallons per minute
gal - gallons
TR0795C Page 2 of 2 June 2024
Table 5-1
004 Treatment Plant Flow Data
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Date
Daily Volume Influent
(gallons)
Cumulative Volume
Inflaent (gallons)
Average Discharge
Flow Rate
(gpm)
Daily Volume Treated
and Discharged
(gallons)
Cumulative Volume Treated
and Discharged
(gallons)
Prior Total
193,886,310
N/A
196,690,733
1/l/2024
517,798
194,404,108
353
508,195
197,198,928
1/2/2024
514,440
194,918,548
349
502,725
197,701,653
1/3/2024
507,935
195,426,483
341
491,278
198,192,931
1/4/2024
508,858
195,935,341
338
486,708
198,679,639
1/5/2024
483,832
196,419,173
331
476,231
199,155,870
1/6/2024
503,990
196,923,163
344
495,699
199,651,569
1/7/2024
603,452
197,526,615
406
584,249
200,235,818
1/8/2024
582,894
198,109,509
400
576,521
200,812,339
1/9/2024
550,896
198,660,405
376
541,185
201,353,524
1/10/2024
590,004
199,250,409
401
577,470
201,930,994
1/11/2024
598,861
199,849,270
404
582,384
202,513,378
1/12/2024
596,982
200,446,252
406
585,324
203,098,702
1/13/2024
608,322
201,054,574
416
598,686
203,697,388
1/14/2024
606,900
201,661,474
411
592,010
204,289,398
1/15/2024
604,734
202,266,208
407
585,363
204,874,761
1/16/2024
610,525
202,876,733
413
595,378
205,470,139
1/17/2024
605,970
203,482,703
413
595,392
206,065,531
1/18/2024
619,788
204,102,491
401
577,967
206,643,498
1/19/2024
620,171
204,722,662
409
589,000
207,232,498
1/20/2024
643,320
205,365,982
443
637,281
207,869,779
1/21/2024
581,084
205,947,066
397
572,260
208,442,039
1/22/2024
614,183
206,561,249
415
597,478
209,039,517
1/23/2024
566,155
207,127,404
382
549,644
209,589,161
1/24/2024
523,011
207,650,415
356
512,090
210,101,251
1/25/2024
519,568
208,169,983
353
508,116
210,609,367
1/26/2024
532,392
208,702,375
363
522,174
211,131,541
1/27/2024
510,276
209,212,651
346
498,492
211,630,033
1/28/2024
508230
209,720,881
343
493573
212,123,606
1/29/2024
509,050
210,229,931
345
496,158
212,619,764
1/30/2024
493,548
210,723,479
332
478,354
213,098,118
1/31/2024
529,135
211,252,614
354
510,104
213,608,222
January Total
17,366,304
N/A
16,917,489
TR0795C Page 1 of 3 June 2024
Table 5-1
004 Treatment Plant Flow Data
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
e
Daily Volume Influent
(gallons)
Cumulative Volume
Inflaent (gallons)
Average Discharge
Flow Rate
(gpm)
Daily Volume Treated
and Discharged
(gallons)
Cumulative Volume Treated
and Discharged
(gallons)
2/1/2024
498,309
211,750,923
341
491,424
214,099,646
2/2/2024
487,063
212,237,986
324
466,579
214,566,225
2/3/2024
474,005
212,711,991
322
463,915
215,030,140
2/4/2024
483,588
213,195,579
328
472,394
215,502,534
2/5/2024
476,726
213,672,305
321
462,862
215,965,396
2/6/2024
471,496
214,143,801
318
457,473
216,422,869
2/7/2024
492,925
214,636,726
342
492,863
216,915,732
2/8/2024
461,128
215,097,854
324
465,987
217,381,719
2/9/2024
497,573
215,595,427
343
493,403
217,875,122
2/10/2024
577,047
216,172,474
394
567,804
218,442,926
2/11/2024
603,682
216,776,156
414
596,386
219,039,312
2/12/2024
585,852
217,362,008
400
576,590
219,615,902
2/13/2024
587,064
217,949,072
400
575,682
220,191,584
2/14/2024
586,430
218,535,502
396
570,400
220,761,984
2/15/2024
551,759
219,087,261
379
546,276
221,308,260
2/16/2024
573,514
219,660,775
388
559,297
221,867,557
2/17/2024
520,738
220,181,513
351
504,812
222,372,369
2/18/2024
512,240
220,693,753
346
497,891
222,870,260
2/19/2024
505,793
221,199,546
340
489,935
223,360,195
2/20/2024
509,974
221,709,520
343
493,862
223,854,057
2/21/2024
496,409
222,205,929
336
483,764
224,337,821
2/22/2024
442,976
222,648,905
297
428,079
224,765,900
2/23/2024
470,093
223,118,998
313
450,958
225,216,858
2/24/2024
521,879
223,640,877
339
488,190
225,705,048
2/25/2024
524,532
224,165,409
355
511,771
226,216,819
2/26/2024
505,890
224,671,299
356
512,387
226,729,206
2/27/2024
500,454
225,171,753
341
1 490,530
227,219,736
2/28/2024
494,224
225,665,977
334
480,729
227,700,465
2/29/2024
491,983
226,157,960
334
480,590
228,181,055
February Total
14,905,346
14,572,833
TR0795C Page 2 of 3 June 2024
Table 5-1
004 Treatment Plant Flow Data
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
e
Daily Volume Influent
(gallons)
Cumulative Volume
Inflaent (gallons)
Average Discharge
Flow Rate
(gpm)
Daily Volume Treated
and Discharged
(gallons)
Cumulative Volume Treated
and Discharged
(gallons)
3/1/2024
488,325
226,646,285
327
471,090
228,652,145
3/2/2024
502,819
227,149,104
336
483,399
229,135,544
3/3/2024
492,191
227,641,295
345
497,094
229,632,638
3/4/2024
501,594
228,142,889
340
489,279
230,121,917
3/5/2024
501,769
228,644,658
325
468,385
230,590,302
3/6/2024
497,782
229,142,440
324
466,429
231,056,731
3/7/2024
560,516
229,702,956
347
499,082
231,555,813
3/8/2024
543,484
230,246,440
395
569,447
232,125,260
3/9/2024
560,433
230,806,873
387
557,326
232,682,586
3/10/2024
551,008
231,357,881
371
534,181
233,216,767
3/11/2024
535,963
231,893,844
361
520,458
233,737,225
3/12/2024
524,107
232,417,951
356
512,146
234,249,371
3/13/2024
488,618
232,906,569
330
474,776
234,724,147
3/14/2024
547,151
233,453,720
365
525,443
235,249,590
3/15/2024
589,009
234,042,729
404
581,456
235,831,046
3/16/2024
602,567
234,645,296
408
588,085
236,419,131
3/17/2024
595,998
235,241,294
408
587,087
237,006,218
3/18/2024
594,441
235,835,735
404
581,748
237,587,966
3/19/2024
583,880
236,419,615
395
568,862
238,156,828
3/20/2024
542,202
236,961,817
360
518,047
238,674,875
3/21/2024
505,600
237,467,417
316
455,102
239,129,977
3/22/2024
524,085
237,991,502
352
507,368
239,637,345
3/23/2024
537,363
238,528,865
355
511,667
240,149,012
3/24/2024
523,771
239,052,636
362
521,088
240,670,100
3/25/2024
513,653
239,566,289
345
496,134
241,166,234
3/26/2024
517,588
240,083,877
332
478,760
241,644,994
3/27/2024
527,641
240,611,518
353
507,965
242,152,959
3/28/2024
521,052
241,132,570
338
486,165
242,639,124
3/29/2024
606,743
241,739,313
427
614,670
243,253,794
3/30/2024
610,341
242,349,654
417
601,128
243,854,922
3/31/2024
614,603
242,964,257
420
604,402
1 244,459,324
March Total
16,806,297
N/A
16,278,269
Reporting Period Total
49,077,947
47,768,591
Notes:
1 - The 004 Treatment Plant operational data is collected and managed by Veolia.
2 - The monthly and reporting period totals are not applicable (N/A) for flow rate values.
3 - The daily influent volume and volume treated and discharged is recorded on a 24-hour basis, ending daily at 1 pm. For simplicity, the volume totaled through 1 pm is shown as the daily
total in this table.
4 - Differences in daily and cumulative volumes between influent and discharged are attributable to the measurement resolution of the flow meters at the influent and effluent locations.
TR0795C Page 3 of 3 June 2024
Table 5-2
004 Treatment Plant PFAS Analytical Results
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
Table 3+ SOP
(ng/L)
004 Influent
004-INF-0124-2
Sample Date:
2-Jan-24
004 Effluent
004-EFF-0124-2
Sample Date:
2-Jan-24
004 Influent
004-INF-0124-2A
Sample Date:
8-Jan-24
004 Effluent
004-EFF-0124-2A
Sample Date:
8-Jan-24
004 Influent
004-INF-0124-3
Sample Date:
15-Jan-24
004 Effluent
004-EFF-0124-3
Sample Date:
15-Jan-24
004 Influent
004-INF-0124-4
Sample Date:
22-Jan-24
004 Effluent
004-EFF-0124-4
Sample Date:
22-Jan-24
004 Influent
004-INF-0124-5
Sample Date:
29-Jan-24
004 Effluent
004-EFF-0124-5
Sample Date:
29-Jan-24
Hfpo Dimer Acid
14,000
<2.0
20,000
<2.0
14,000
<2.0
17,000
<2.0
12,000
<2.0
PFMOAA
69,000
<2.0 UJ
56,000
<2.0 UJ
63,000
<2.0
57,000
<2.0
56,000
<2.0
PFO2HxA
26,000
<2.0
--
--
--
--
--
--
--
--
PFO3OA
7,500
<2.0
--
--
--
--
--
--
--
--
PFO4DA
1,900
<2.0
--
--
--
--
--
--
--
--
PFO5DA
640
<2.0
--
--
--
--
--
--
--
--
PMPA
10,000
<10
18,000
<10
11,000
<10
16,000
<10
9,300
<10
PEPA
3,200
<20
--
--
--
--
--
--
--
--
PS Acid
760
<2.0
--
--
--
--
--
--
--
--
Hydro-PS Acid
300
<2.0 UJ
--
--
--
--
--
--
--
--
R-PSDA
940 J
<2.0
--
--
--
--
--
--
--
--
Hydrolyzed PSDA
6,800 J
<2.0 UJ
--
--
--
--
--
--
--
--
R-PSDCA
24
<2.0
--
--
--
--
--
--
--
--
NVHOS, Acid Form
980
<2.0
--
--
--
--
--
--
--
--
EVE Acid
170
<2.0
--
--
--
--
--
--
--
--
Hydro-EVE Acid
890
<2.0
--
--
--
--
--
--
--
--
R-EVE
530 J
<2.0
--
--
--
--
--
--
--
--
Perfluoro(2-ethoxyethane)sulfonic Acid
<6.7
<2.0
--
--
--
--
--
--
--
--
PFECA B
<27
<2.0
--
--
--
--
--
--
--
--
PFECA-G
<48
<2.0
--
--
--
--
--
--
--
--
Total Table 3+ (17 compounds)"2'3
140,000
--
--
--
Notes:
1 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to two significant figures.
2 - Total Table 3+ (17 Compounds) does not include R-PSDA, Hydrolyzed PSDA and R-EVE.
3 - Total Table 3+ (17 Compounds) is not applicable for the weekly sampling for only PFAS indicator compounds (HFPO-DA, PFMOAA, and PMPA).
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
UJ — Analyte not detected. Reporting limit may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
ND - No Table 3+ compounds were detected above their associated reporting limits.
TR0795C Page 1 of 4 June 2024
Table 5-2
004 Treatment Plant PFAS Analytical Results
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
Table 3+ SOP
(ng/L)
004 Influent
004-INF-0224
Sample Date:
5-Feb-24
004 Effluent
004-EFF-0224
Sample Date:
5-Feb-24
004 Influent
004-INF-0224-2
Sample Date:
12-Feb-24
004 Effluent
004-EFF-0224-2
Sample Date:
12-Feb-24
004 Influent
004-INF-0224-3
Sample Date:
19-Feb-24
004 Effluent
004-EFF-0224-3
Sample Date:
19-Feb-24
004 Influent
004-INF-0224-4
Sample Date:
26-Feb-24
004 Effluent
004-EFF-0224-4
Sample Date:
26-Feb-24
Hfpo Dimer Acid
11,000
<2.0
17,000
<2.0
11,000
<2.0
14,000
<2.0
PFMOAA
71,000
<2.0
59,000
<2.0
74,000
<2.0 UJ
62,000
<2.0 UJ
PFO2HxA
--
--
23,000
<2.0
--
--
--
--
PFO3OA
--
--
6,400
<2.0
--
--
--
--
PFO4DA
--
--
1,600
<2.0
--
--
--
--
PFO5DA
--
--
470
<2.0
--
--
--
--
PMPA
10,000
<10
14,000
<10
10,000
<10
10,000
<10 UJ
PEPA
--
--
6,000
<20
--
--
--
--
PS Acid
--
--
1,600
<2.0
--
--
--
--
Hydro-PS Acid
--
--
620
<2.0
--
--
--
--
R-PSDA
--
--
1,800 J
<2.0
--
--
--
--
Hydrolyzed PSDA
--
--
16,000 J
<2.0
--
--
--
--
R-PSDCA
--
--
33
<2.0
--
--
--
--
NVHOS, Acid Form
--
--
1,200
<2.0
--
--
--
--
EVE Acid
--
--
1,200
<2.0
--
--
--
--
Hydro-EVE Acid
--
--
1,200
<2.0
--
--
--
--
R-EVE
--
--
930 J
<2.0
--
--
--
--
Perfluoro(2-ethoxyethane)sulfonic Acid
--
--
5.3
<2.0
--
--
--
--
PFECA B
--
--
<13
<2.0
--
--
--
--
PFECA-G
--
--
<24
<2.0
--
--
--
--
Total Table 3+ (17 compounds)" '3
130,000
--
--
--
--
Notes:
1 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to two significant figures.
2 - Total Table 3+ (17 Compounds) does not include R-PSDA, Hydrolyzed PSDA and R-EVE.
3 - Total Table 3+ (17 Compounds) is not applicable for the weekly sampling for only PFAS indicator compounds (HFPO-DA, PFMOAA, and PMPA).
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
UJ — Analyte not detected. Reporting limit may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
ND - No Table 3+ compounds were detected above their associated reporting limits.
TR0795C Page 2 of 4 June 2024
Table 5-2
004 Treatment Plant PFAS Analytical Results
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
Table 3+ SOP
(ng/L)
004 Influent
004-INF-0324
Sample Date:
4-Mar-24
004 Effluent
004-EFF-0324
Sample Date:
4-Mar-24
004 Influent
004-INF-0324-2
Sample Date:
11-Mar-24
004 Effluent
004-EFF-0324-2
Sample Date:
11-Mar-24
004 Influent
004-INF-0324-3
Sample Date:
18-Mar-24
004 Effluent
004-EFF-0324-3
Sample Date:
18-Mar-24
004 Influent
004-INF-0324-4
Sample Date:
25-Mar-24
004 Effluent
004-EFF-0324-4
Sample Date:
25-Mar-24
Hfpo Dimer Acid
12,000
<2.0
16,000
<2.0
15,000
<2.0
14,000
<2.0
PFMOAA
62,000
<2.0
46,000
<2.0
53,000
<2.0
62,000
<2.0
PFO2HxA
--
--
21,000
<2.0
--
--
--
--
PFO3OA
--
--
5,200
<2.0
--
--
--
--
PFO4DA
--
--
1,600
<2.0
--
--
--
--
PFO5DA
--
--
510
<2.0
--
--
--
--
PMPA
10,000
<10
10,000
<10
13,000
<10
10,000
<10
PEPA
--
--
3,600
<10
--
--
--
--
PS Acid
--
--
1,100
<2.0
--
--
--
--
Hydro-PS Acid
--
--
560
<2.0
--
--
--
--
R-P D
--
--
1300 J
,
<2.0
--
--
--
--
Hydrolyzed PSDA
--
--
12,000 J
<2.0
--
--
--
--
R-PSDCA
--
--
<25
<2.0
--
--
--
--
NVHOS, Acid Form
--
--
830
<2.0
--
--
--
--
EVE Acid
--
--
570
<2.0
--
--
--
--
Hydro-EVE Acid
--
--
840
<2.0
--
--
--
--
R-EVE
--
--
500 J
<2.0
--
--
--
--
Perfluoro(2-ethoxyethane)sulfonic Acid
--
--
<25
<2.0
--
--
PFECA B
--
--
<25
<2.0
--
--
--
--
PFECA-G
--
--
<25
<2.0
--
--
--
--
Total Table 3+ (17 compounds)" '3
110,000
--
--
--
--
Notes:
1 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to two significant figures.
2 - Total Table 3+ (17 Compounds) does not include R-PSDA, Hydrolyzed PSDA and R-EVE.
3 - Total Table 3+ (17 Compounds) is not applicable for the weekly sampling for only PFAS indicator compounds (HFPO-DA, PFMOAA, and PMPA).
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
ND - No Table 3+ compounds were detected above their associated reporting limits.
TR0795C Page 3 of 4 June 2024
Table 5-2
004 Treatment Plant PFAS Analytical Results
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537 MOD SOP COMPOUNDS LIST 1,2
(ng2)
004 Influent
004-INF-0224-2
Sample Date:
12-Feb-24
004 Effluent
004-EFF-0224
Sample Date:
12-Feb-24
10:2 Fluorotelomer sulfonate
<2.0
<2.0
l l Cl-PF3OUdS
<2.0
<2.0
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
<2.0
<2.0
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
<2.0
<2.0
2-(N-ethyl perfluoro-l-octanesulfonamido)-ethanol
<2.0
<2.0
2-(N-methyl perfluoro-l-octanesulfonamido)-ethanol
<4.0
<4.0
6:2 Fluorotelomer sulfonate
<5.0
<5.0
9C1-PF3ONS
<2.0
<2.0
DONA
<2.0
<2.0
N-Ethyl Perfluorooctane Sulfonamidoacetic Acid
<5.0
<5.0
N-ethylperfluoro-l-octanesulfonamide
<2.0
<2.0
N-methyl perfluoro-l-octanesulfonamide
<2.0
<2.0
N-Methyl Perfluorooctane Sulfonamidoacetic Acid
<5.0
<5.0
Perfluorobutane Sulfonic Acid
<2.0
<2.0
Perfluorobutanoic Acid
250
<5.0
Perfluorodecane Sulfonic Acid
<2.0
<2.0
Perfluorodecanoic Acid
<2.0
<2.0
Perfluorododecane Sulfonic Acid (PFDoS)
<2.0
<2.0
Perfluorododecanoic Acid
<2.0
<2.0
Perfluoroheptane Sulfonic Acid (PFHpS)
<2.0
<2.0
Perfluoroheptanoic Acid
99
<2.0
Perfluorohexadecanoic Acid (PFHxDA)
<2.0
<2.0
Perfluorohexane Sulfonic Acid
<2.0
<2.0
Perfluorohexanoic Acid
35
<2.0
Perfluorononanesulfonic Acid
<2.0
<2.0
Perfluorononanoic Acid
8.2
<2.0
Perfluorooctadecanoic Acid
<2.0 UJ
<2.0 UJ
Perfluorooctane Sulfonamide
<2.0
<2.0
Perfluoropentane Sulfonic Acid (PFPeS)
<2.0
<2.0
Perfluoropentanoic Acid
810
<2.0
Perfluorotetradecanoic Acid
<2.0
<2.0
Perfluorotridecanoic Acid
<2.0
<2.0
Perfluoroundecanoic Acid
<2.0
<2.0
PFOA
23
<2.0
PFOS
<2.0
<2.0
Notes.-
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds.
2 - Sample analysis under EPA Method 537 MOD SOP is required one time per quarter.
Bold - Analyte detected above associated reporting limit.
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
< - Analyte not detected above associated reporting limit.
TR0795C Page 4 of 4 June 2024
Table 6-1
Summary of Groundwater Level Information
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Aug 1 (0.00)
Aug 14 (0.41)
Jan 27 (0.00)
Feb 25 (0.07)
Mar 26 (0.45)
April 17 (0.00)
May 20 (0.00)
Jun 18 (0.00)
Jul 17 (0.00)
Aug. 15 (0.09)
Antecedent Daily Total Rainfall (inches):
Aug 2 (0.00)
Aug 15 (0.09)
Jan 28 (0.00)
Feb 26 (0.00)
Mar 27 (0.63)
Apr 18 (0.00)
May 21 (0.00)
Jun 19 (0.16)
Jul 18 (0.00)
Aug. 16 (0.00)
Aug 3 (0.00)
Aug 16 (0.00)
Jan 29 (0.08)
Feb 27 (0.00)
Mar 28 (0.28)
Apr 19 (0.00)
May 22 (0.00)
Jun 20 (1.11)
Jul 19 (0.00)
Aug. 17 (0.00)
Groundwater Elevation from Water Level Gauging Events (feet, NAVD88)
Well ID
Aquifer
Baseline
Mid -Commissioning
Post -Startup
Monthly O&M
Monthly O&M
Monthly O&M
Monthly O&M
Monthly O&M
August 4, 2022 August 17, 2022 January 30, 2023
February 28, 2023
March 29, 2023
April 20, 2023
May 23, 2023
June 21, 2023
July 20, 2023
August 18, 2023
Willis Creek Observation Wells (Northern Alignment): 18 Wells
OW-11
Black Creek Aquifer
49.63
49.57
49.02
48.39
46.58
46.62
48.25
46.16
45.98
45.89
OW-12
Black Creek Aquifer
34.08
34.08
34.81
31.61
29.71
30.26
29.32
29.15
29.08
28.95
OW-13
Black Creek Aquifer
34.10
34.05
34.42
33.63
32.32
33.61
32.02
31.43
31.50
31.20
OW-14
Black Creek Aquifer
33.62
33.47
34.67
34.09
33.11
36.60
32.97
32.08
32.76
32.05
OW-41
Black Creek Aquifer
49.13
49.12
48.33
47.66
46.46
46.51
46.11
45.97
45.78
45.69
OW42
Black Creek Aquifer
47.89
47.86
47.42
46.81
45.90
45.94
45.52
45.47
45.27
45.15
OW43
Black Creek Aquifer
34.49
34.42
34.62
33.64
32.04
33.09
31.76
31.20
31.13
31.14
OW-54
Black Creek Aquifer
Well Installed January 24, 2023
35.87
35.00
33.45
35.90
36.19
Dry
Dry
Dry
OW-55
Black Creek Aquifer
Well Installed January 18, 2023
34.77
32.06
28.43
29.75
28.30
28.07
27.97
27.80
OW-56
Black Creek Aquifer
Well Installed January 24, 2023
36.92
36.50
36.63
37.17
35.99
36.18
35.89
35.74
OW-57
Black Creek Aquifer
Well Installed January 17, 2023
45.75
45.24
44.58
44.62
44.27
44.22
44.07
43.92
PIW-lD
Black Creek Aquifer
32.59
32.47
33.95
33.15
32.25
35.09
31.96
31.25
32.06
31.27
PIW-11
Black Creek Aquifer
43.28
43.24
43.89
43.62
43.14
43.65
42.87
42.61
43.10
42.70
PIW-12
Black Creek Aquifer
33.74
33.69
34.39
31.90
26.64
28.38
26.68
26.43
26.36
26.17
PIW-13
Black Creek Aquifer
33.66
33.60
34.20
30.68
24.95
28.16
25.74
25.00
25.21
25.38
PIW-14
Black Creek Aquifer
34.05
34.00
34.44
32.47
29.90
31.36
29.80
29.20
28.98
29.45
PIW-15
Black Creek Aquifer
32.74
32.65
33.54
32.88
32.00
33.87
31.69
31.10
31.50
31.01
SMW-12
Black Creek Aquifer
33.03
33.03
33.52
31.19
29.17
30.17
28.82
28.23
27.97
Not Gauged
Median (Black Creek Aquifer wells)
34.07
34.03
34.72
33.64
32.29
34.48
31.99
31.25
31.50
31.24
Observation Wells <200 ft Upgradient of Barrier Wall: 19 Wells
OW-02
Black Creek Aquifer
48.82
48.72
49.79
44.34
39.18
42.55
34.58
32.97
32.29
33.10
OW-03
Black Creek Aquifer
49.52
49.44
49.60
44.06
38.43
42.24
34.14
32.57
32.56
32.79
OW-07
Black Creek Aquifer
44.87
44.75
45.36
41.10
37.61
35.00
29.91
27.90
25.40
25.73
OW-08
Black Creek Aquifer
44.12
43.98
44.60
40.37
36.86
34.14
29.09
27.05
25.50
24.85
OW-15
Black Creek Aquifer
Well Installed September 22, 2022
56.91
56.50
57.53
57.66
57.21
57.16
57.14
57.23
OW-17
Black Creek Aquifer
44.87
44.82
43.53
39.81
34.88
32.77
32.96
32.87
32.90
32.87
OW-18
Black Creek Aquifer
47.17
47.37
48.61
48.79
47.95
46.93
46.58
46.44
46.42
46.44
OW-19
Black Creek Aquifer
46.36
46.23
46.68
41.42
37.73
38.50
30.38
28.05
26.48
25.83
OW-21
Black Creek Aquifer
45.13
45.00
45.51
41.70
37.87
35.40
30.65
28.15
26.50
25.75
OW-24
Black Creek Aquifer
43.17
43.15
43.73
38.94
36.23
34.77
30.02
28.27
26.97
26.15
OW-26
Black Creek Aquifer
55.22
55.16
54.84
53.79
45.67
44.05
42.50
40.15
39.08
40.15
OW-29
Black Creek Aquifer
59.58
59.54
59.14
58.57
51.34
49.72
47.54
45.62
44.64
43.90
OW-31
Black Creek Aquifer
60.44
60.41
60.07
59.43
47.00
50.58
42.85
41.55
40.60
39.98
OW-34
Surficial Aquifer
62.98
62.81
62.03
64.53
66.36
67.30
67.50
67.41
67.45
67.36
OW-35
Surficial Aquifer
66.33
66.10
65.67
65.71
65.45
68.18
68.35
68.35
68.73
68.55
OW-36
Surficial Aquifer
62.72
62.61
62.07
61.85
61.64
61.48
61.51
61.52
61.51
61.71
OW-37
Surficial Aquifer
Well Installed June 21, 2023
57.38
57.27
OW-38
Black Creek Aquifer
Well Installed September 22, 2022 61.93 61.94 61.64 61.60 61.45 61.40
61.22
61.28
OW-51
Black Creek Aquifer
Well Installed June 20, 2023
26.21
25.17
Median (Black Creek Aquifer wells)
46.77
46.80
48.70
44.20
38.81
42.40
34.36
32.92
32.56
32.87
Median (Surficial Aquifer wells)
62.98
62.81
62.07
64.53
65.45
67.30
67.50
67.41
64.48
64.54
TR0795C Page 1 of 6 June 2024
Table 6-1
Summary of Groundwater Level Information
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Antecedent Daily Total Rainfall (inches):
Sep. 18 (0.00)
Oct 27 (0.00)
Nov. 25 (0.00)
Dec. 17 (3.34)
Jan. 28 (0.02)
Feb. 24 (0.01)
Mar. 24 (0.00)
Most Recent Calculated Head
Differential
(feet, positive value indicates drawdown)
Change in Magnitude of Head
Differential
Sept. 19 (0.00)
Oct 28. (0.00)
Nov. 26 (0.06)
Dec. 18 (0.04)
Jan. 29 (0.00)
Feb. 25 (0.00)
Mar. 25 (0.00)
Sept. 20 (0.00)
Oct 29 (0.00)
Nov. 27 (0.03)
Dec. 19 (0.00)
Jan. 30 (0.00)
Feb. 26 (0.01)
Mar. 26 (0.00)
Well ID
Aquifer
Groundwater Elevation from Water Level Gauging Events (feet, NAVD88)
Monthly O&M
Monthly O&M
Monthly O&M
Monthly O&M
Monthly O&M
Monthly O&M
Monthly O&M
September 21, 2023
October 30, 2023
November 28, 2023
December 20, 2023
January 31, 2024
February 27, 2024
March 27, 2024
March 27, 2024 vs. January 30, 2023
March 27 vs February 27, 2024
Willis Creek Observation Wells (Northern Alignment): 18 Wells
OW-11
Black Creek Aquifer
45.82
45.80
45.63
46.82
45.92
45.72
45.72
3.30
0.00
OW-12
Black Creek Aquifer
29.39
29.10
29.19
31.32
30.65
29.17
28.94
5.87
0.23
OW-13
Black Creek Aquifer
31.54
31.32
31.04
32.25
32.92
31.98
31.77
2.65
0.21
OW-14
Black Creek Aquifer
32.22
31.59
31.36
32.42
34.77
33.07
33.10
1.57
0.03
OW41
Black Creek Aquifer
45.64
45.66
45.45
45.59
45.79
45.57
45.57
2.76
0.00
OW-42
Black Creek Aquifer
45.16
45.12
44.95
45.17
45.25
45.03
45.02
2.40
0.01
OW-43
Black Creek Aquifer
31.49
31.55
31.44
31.69
32.69
32.04
31.95
2.67
0.09
OW-54
Black Creek Aquifer
Dry
Dry
Dry
Dry
35.87
33.37
33.21
2.66
0.16
OW-55
Black Creek Aquifer
28.60
28.05
28.20
28.12
29.65
28.44
28.16
6.61
0.28
OW-56
Black Creek Aquifer
36.01
35.89
36.09
Not Gauged
36.99
35.99
36.46
0.46
0.47
OW-57
Black Creek Aquifer
43.95
43.92
43.78
44.12
44.04
43.87
43.87
1.88
0.00
PIW-lD
Black Creek Aquifer
31.51
30.96
30.75
32.07
34.31
32.18
32.25
1.70
0.07
PIW-11
Black Creek Aquifer
42.96
42.57
42.61
43.34
43.40
43.44
43.72
0.17
0.28
PIW-12
Black Creek Aquifer
27.27
26.54
26.73
28.96
28.20
27.05
26.73
7.66
0.32
PIW-13
Black Creek Aquifer
26.70
26.48
26.70
27.26
28.70
27.68
27.28
6.92
0.40
PIW-14
Black Creek Aquifer
30.02
29.98
29.93
30.10
30.99
30.07
29.94
4.50
0.13
PIW-15
Black Creek Aquifer
31.29
30.85
30.59
32.85
33.55
31.80
31.68
1.86
0.12
SMW-12
Black Creek Aquifer
Not Gauged
28.42
28.64
28.70
28.78
29.10
28.87
4.65
0.23
Median (Black Creek Aquifer wells)
31.53
31.32
31.04
32.16
33.93
32.11
32.10
2.67
0.21
Observation Wells <200 ft Upgradient of Barrier Wall: 19 Wells
OW-02
Black Creek Aquifer
33.95
34.55
34.62
34.25
34.92
35.07
35.07
13.72
0.00
OW-03
Black Creek Aquifer
33.62
34.29
34.34
33.94
34.69
34.79
34.84
14.76
0.05
OW-07
Black Creek Aquifer
28.39
29.50
29.80
29.90
31.00
31.25
31.55
13.81
0.30
OW-08
Black Creek Aquifer
27.61
28.75
29.06
29.14
30.25
30.40
30.80
13.80
0.40
OW-15
Black Creek Aquifer
57.21
57.31
57.28
57.06
57.13
57.73
57.91
-1.00
0.18
OW-17
Black Creek Aquifer
32.90
33.17
32.82
32.72
33.22
32.96
33.06
10.47
0.10
OW-18
Black Creek Aquifer
46.56
46.43
46.25
46.71
46.33
46.12
46.63
1.98
0.51
OW-19
Black Creek Aquifer
28.36
29.53
29.78
29.67
30.57
30.73
31.26
15.42
0.53
OW-21
Black Creek Aquifer
28.68
30.08
30.43
30.51
31.45
31.57
32.01
13.50
0.44
OW-24
Black Creek Aquifer
27.54
28.27
28.43
28.54
29.63
29.77
30.35
13.38
0.58
OW-26
Black Creek Aquifer
41.05
42.33
42.07
41.99
41.98
42.00
42.17
12.67
0.17
OW-29
Black Creek Aquifer
43.68
44.69
44.43
44.27
44.44
44.55
44.65
14.49
0.10
OW-31
Black Creek Aquifer
40.08
40.55
40.02
39.79
40.02
41.05
41.10
18.97
0.05
OW-34
Surficial Aquifer
67.57
67.82
67.64
67.53
67.71
67.61
67.70
-5.67
0.09
OW-35
Surficial Aquifer
68.58
68.40
68.32
68.34
68.64
68.65
68.75
-3.08
0.10
OW-36
Surficial Aquifer
61.66
62.01
61.91
62.01
62.29
62.31
62.24
-0.17
0.07
OW-37
Surficial Aquifer
57.30
57.02
56.61
56.79
56.42
56.24
56.46
N/A
0.22
OW-38
Black Creek Aquifer
61.45
61.82
61.89
61.90
62.38
62.72
62.80
-0.87
0.08
OW-51
Black Creek Aquifer
26.36
27.14
27.45
27.61
28.52
28.77
29.14
N/A
0.37
Median (Black Creek Aquifer wells)
33.62
34.29
34.34
33.94
34.69
34.79
34.84
13.61
0.24
Median (Surficial Aquifer wells)
64.62
64.92
64.78
64.77
65.00
64.96
64.97
-3.08
0.10
TR0795C Page 2 of 6 June 2024
Table 6-1
Summary of Groundwater Level Information
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Aug 1 (0.00)
Aug 14 (0.41)
Jan 27 (0.00)
Feb 25 (0.07)
Mar 26 (0.45)
April 17 (0.00)
May 20 (0.00)
Jun 18 (0.00)
Jul 17 (0.00)
Aug. 15 (0.09)
Antecedent Daily Total Rainfall (inches):
Aug 2 (0.00)
Aug 15 (0.09)
Jan 28 (0.00)
Feb 26 (0.00)
Mar 27 (0.63)
Apr 18 (0.00)
May 21 (0.00)
Jun 19 (0.16)
Jul 18 (0.00)
Aug. 16 (0.00)
Aug 3 (0.00)
Aug 16 (0.00)
Jan 29 (0.08)
Feb 27 (0.00)
Mar 28 (0.28)
Apr 19 (0.00)
May 22 (0.00)
Jun 20 (1.11)
Jul 19 (0.00)
Aug. 17 (0.00)
Groundwater Elevation from Water Level Gauging Events (feet, NAVD88)
Well ID
Aquifer
Baseline
Mid -Commissioning
Post -Startup
Monthly O&M
Monthly O&M
Monthly O&M
Monthly O&M
Monthly O&M
August 4, 2022 August 17, 2022 January 30, 2023
February 28, 2023
March 29, 2023
April 20, 2023
May 23, 2023
June 21, 2023
July 20, 2023
August 18, 2023
Observation Wells <200 it Downgradient of Barrier Wall: 21 Wells
OW-04/04R
Black Creek Aquifer
59.45
59.42
Well Abandoned; Replacement Well Installed July 31, 2023 Replaced July 31, 2023
52.03
OW-09/09R
Black Creek Aquifer
59.61
59.57
Well Abandoned; Replacement Well Installed August 1, 2023 Replaced August 1, 2023
40.33
OW-20
Black Creek Aquifer
46.34
46.24
46.53
41.54
39.35
37.91
38.39
38.49
39.03
38.44
OW-22
Black Creek Aquifer
43.95
43.89
44.50
40.94
37.53
37.36
38.41
38.55
39.08
38.58
OW-23
Black Creek Aquifer
43.27
43.18
43.86
39.75
36.73
35.88
38.31
38.36
38.80
38.28
OW-25
Black Creek Aquifer
41.95
41.90
42.52
39.00
36.50
35.77
38.62
38.36
38.36
37.89
OW-32
Black Creek Aquifer
Well Installed August 2, 2023
Replaced August 2, 2023
38.45
OW-39
Black Creek Aquifer
Well Installed August 1, 2023
Replaced August 1, 2023
40.36
OW-44
Black Creek Aquifer
36.51
36.31
36.28
36.94
36.34
37.41
36.06
35.28
35.38
34.63
OW45
Black Creek Aquifer
44.39
44.20
44.78
45.24
40.05
39.93
39.10
38.82
39.78
38.50
OW46
Black Creek Aquifer
46.28
46.20
46.59
41.41
38.85
37.88
38.35
38.50
39.03
38.42
OW-47
Black Creek Aquifer
43.84
43.72
44.33
40.45
36.98
37.05
38.18
38.32
38.87
38.32
OW-48
Black Creek Aquifer
43.11
43.06
43.69
39.33
36.40
35.29
38.24
38.27
38.64
38.13
OW-49
Black Creek Aquifer
42.13
42.06
42.67
38.83
36.23
35.42
38.43
38.34
38.36
37.88
OW-50
Black Creek Aquifer
41.42
41.35
42.01
41.78
35.37
36.17
39.50
39.33
39.48
39.00
OW-52
Black Creek Aquifer
Well Installed August 2, 2023
Replaced August 2, 2023
38.01
OW-53
Black Creek Aquifer
Well Installed October 11, 2023
PIW-41)
Black Creek Aquifer
43.59
43.45
43.90
46.26
39.89
39.88
38.90
38.65
39.64
38.30
PIW-5S/5SR
Surficial Aquifer
59.70
59.52
58.82
56.31
Replaced on April 12, 2023
54.13
53.15
53.37
53.54
53.25
PW-10R/lORR
Black Creek Aquifer
47.78
47.62
47.99
42.18
Replaced on April 12, 2023
41.20
38.52
38.39
39.19
38.32
PIW-IODR
Black Creek Aquifer
Not Gauged (Interim Remedy Location; Pump Removed by August 23, 2023)
Not Gauged (Interim Pumping)
41.50
Median (Black Creek Aquifer wells)
43.84 43.72 43.90 40.94 36.86 37.36 38.41 38.39
39.03
38.42
Observation Wells >200 ft Downgradient of Barrier Wall: 14 Wells
LTW-02
Black Creek Aquifer
42.97
42.80
43.50
45.36
40.01
39.97
38.94
38.71
39.67
38.31
LTW-03
Floodplain
38.05
37.93
39.27
38.48
36.95
37.85
36.70
36.40
36.53
36.05
LTW-05
Black Creek Aquifer
41.24
41.20
41.93
38.69
36.30
35.71
37.89
37.86
38.02
37.46
OW-16
Black Creek Aquifer
35.39
35.24
36.69
36.49
35.86
37.27
35.34
34.59
34.94
34.17
OW-27
Black Creek Aquifer
41.16
41.12
41.70
41.36
36.09
36.80
39.35
39.21
39.32
38.85
OW-28
Black Creek Aquifer
40.04
40.01
40.63
40.43
38.16
38.86
39.04
39.00
38.99
38.99
OW-30
Black Creek Aquifer
40.38
40.33
40.98
39.55
36.80
37.91
38.94
38.95
39.17
Not Gauged
OW-33
Black Creek Aquifer
40.42
40.39
41.07
39.89
37.45
38.32
39.29
39.34
39.44
Not Gauged
OW-40
Black Creek Aquifer
40.58
40.53
40.66
40.68
40.09
40.86
40.13
40.15
40.23
Not Gauged
PIW-3D
Black Creek Aquifer
35.39
35.26
36.61
36.39
35.97
37.14
35.36
34.67
35.07
34.32
PIW-7S
Floodplain
42.28
42.16
43.03
39.55
36.56
35.79
37.74
37.80
38.28
37.61
PIW-7D
Black Creek Aquifer
43.18
43.10
43.78
39.98
36.96
36.36
38.38
38.45
38.88
38.33
PW-11
Black Creek Aquifer
Not Gauged (Interim Remedy Location; Pump Removed by August 23, 2023) Not Gauged (Interim Pumping)
PZ-22
Black Creek Aquifer
43.24
43.15
43.81
40.36
37.28
36.89
38.21
38.37
38.85
38.33
Median (Black Creek Aquifer wells)
40.58
40.53
41.07
39.98
36.96
37.27
38.94
38.71
38.99
38.32
TR0795C Page 3 of 6 June 2024
Table 6-1
Summary of Groundwater Level Information
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Antecedent Daily Total Rainfall (inches):
Sep. 18 (0.00)
Oct 27 (0.00)
Nov. 25 (0.00)
Dec. 17 (3.34)
Jan. 28 (0.02)
Feb. 24 (0.01)
Mar. 24 (0.00)
Most Recent Calculated Head
Differential
(feet, positive value indicates drawdown)
Change in Magnitude of Head
Differential
Sept. 19 (0.00)
Oct 28. (0.00)
Nov. 26 (0.06)
Dec. 18 (0.04)
Jan. 29 (0.00)
Feb. 25 (0.00)
Mar. 25 (0.00)
Sept. 20 (0.00)
Oct 29 (0.00)
Nov. 27 (0.03)
Dec. 19 (0.00)
Jan. 30 (0.00)
Feb. 26 (0.01)
Mar. 26 (0.00)
Well ID
Aquifer
Groundwater Elevation from Water Level Gauging Events (feet, NAVD88)
Monthly O&M
Monthly O&M
Monthly O&M
Monthly O&M
Monthly O&M
Monthly O&M
Monthly O&M
September 21, 2023
October 30, 2023
November 28, 2023
December 20, 2023
January 31, 2024
February 27, 2024
March 27, 2024
March 27, 2024 vs. January 30, 2023
March 27 vs February 27, 2024
Observation Wells <200 It Downgradient of Barrier Wall: 21 Wells
OW-04/04R
Black Creek Aquifer
40.33
40.27
40.12
40.28
40.97
40.52
40.53
N/A
0.01
OW-09/09R
Black Creek Aquifer
40.33
40.27
40.12
40.28
40.95
40.53
40.53
N/A
0.00
OW-20
Black Creek Aquifer
38.57
38.04
37.75
38.23
39.54
39.31
39.73
6.80
0.42
OW-22
Black Creek Aquifer
38.63
38.12
37.83
38.23
39.61
39.35
39.78
4.72
0.43
OW-23
Black Creek Aquifer
38.33
37.83
37.64
38.19
39.38
39.06
39.41
4.45
0.35
OW-25
Black Creek Aquifer
37.99
37.61
37.54
38.47
39.06
38.61
38.84
3.68
0.23
OW-32
Black Creek Aquifer
38.75
39.03
38.49
38.27
38.49
38.50
38.70
N/A
0.20
OW-39
Black Creek Aquifer
40.42
40.32
40.20
40.35
40.89
40.57
40.57
N/A
0.00
OW-44
Black Creek Aquifer
34.18
33.79
33.58
33.69
36.23
36.02
36.20
0.08
0.18
OW-45
Black Creek Aquifer
38.85
38.07
38.01
39.10
40.20
40.01
40.22
4.56
0.21
OW-46
Black Creek Aquifer
38.55
37.95
37.75
38.22
39.53
39.33
39.74
6.85
0.41
OW47
Black Creek Aquifer
38.38
37.87
37.58
37.99
39.39
39.12
39.53
4.80
0.41
OW48
Black Creek Aquifer
38.17
37.74
37.55
38.12
39.26
38.89
39.24
4.45
0.35
OW-49
Black Creek Aquifer
37.99
37.61
37.54
38.43
39.04
38.61
38.84
3.83
0.23
OW-50
Black Creek Aquifer
39.13
38.75
38.60
39.20
40.53
39.73
40.11
1.90
0.38
OW-52
Black Creek Aquifer
38.06
37.56
37.26
37.69
39.05
38.79
39.24
N/A
0.45
OW-53
Black Creek Aquifer
Well Installed October 11, 2023
37.96
37.74
38.08
39.48
39.25
39.66
N/A
0.41
PIW-413
Black Creek Aquifer
38.67
37.85
37.83
38.95
40.01
39.82
40.05
3.85
0.23
PIW-5S/5SR
Surficial Aquifer
53.30
Dry
Dry
Dry
Dry
Dry
Dry
N/A
N/A
PW-10R/lORR
Black Creek Aquifer
38.52
35.00
37.82
38.57
39.79
39.56
39.92
8.07
0.36
PIW-10DR
Black Creek Aquifer
41.31
41.05
40.62
40.45
41.53
40.89
41.04
N/A
0.15
Median (Black Creek Aquifer wells)
38.57
37.96
37.79
38.35
39.54
39.32
39.74
4.45
0.35
Observation Wells >200 ft Downgradient of Barrier Wall: 14 Wells
LTW-02
Black Creek Aquifer
38.71
37.89
37.89
39.13
40.07
39.88
40.09
3.41
0.21
LTW-03
Floodplain
35.91
35.80
35.55
36.03
37.98
37.63
38.25
1.02
0.62
LTW-05
Black Creek Aquifer
37.57
37.22
37.14
38.39
38.76
38.26
38.47
3.46
0.21
OW-16
Black Creek Aquifer
33.79
33.41
33.06
33.68
36.32
35.50
35.71
0.98
0.21
OW-27
Black Creek Aquifer
38.94
38.62
38.49
39.05
40.32
39.60
39.88
1.82
0.28
OW-28
Black Creek Aquifer
38.69
38.32
38.26
39.08
39.99
39.29
39.58
1.05
0.29
OW-30
Black Creek Aquifer
38.87
38.64
38.52
Not Gauged
40.15
39.32
39.57
1.41
0.25
OW-33
Black Creek Aquifer
39.17
38.97
38.87
Not Gauged
40.42
39.64
39.87
1.20
0.23
OW-40
Black Creek Aquifer
40.08
40.00
39.88
Not Gauged
40.87
40.30
40.35
0.31
0.05
PIW-313
Black Creek Aquifer
33.97
33.53
33.25
33.95
36.45
35.62
35.82
0.79
0.20
PIW-7S
Floodplain
37.77
37.22
37.10
37.79
38.82
38.52
38.82
4.21
0.30
PIW-713
Black Creek Aquifer
38.42
37.95
37.73
38.31
39.46
39.13
39.48
4.30
0.35
PW-1 l
Black Creek Aquifer
40.61
40.51
40.37
40.56
41.13
41.28
40.75
N/A
0.53
PZ-22
Black Creek Aquifer
38.43
37.85
37.65
38.12
39.40
39.11
39.50
4.31
0.39
Median (Black Creek Aquifer wells)
38.70
38.14
38.08
38.39
40.03
39.31
39.58
1.41
0.24
TR0795C Page 4 of 6 June 2024
Table 6-1
Summary of Groundwater Level Information
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Aug 1 (0.00)
Aug 14 (0.41)
Jan 27 (0.00)
Feb 25 (0.07)
Mar 26 (0.45)
April 17 (0.00)
May 20 (0.00)
Jun 18 (0.00)
Jul 17 (0.00)
Aug. 15 (0.09)
Antecedent Daily Total Rainfall (inches):
Aug 2 (0.00)
Aug 15 (0.09)
Jan 28 (0.00)
Feb 26 (0.00)
Mar 27 (0.63)
Apr 18 (0.00)
May 21 (0.00)
Jun 19 (0.16)
Jul 18 (0.00)
Aug. 16 (0.00)
Aug 3 (0.00)
Aug 16 (0.00)
Jan 29 (0.08)
Feb 27 (0.00)
Mar 28 (0.28)
Apr 19 (0.00)
May 22 (0.00)
Jun 20 (1.11)
Jul 19 (0.00)
Aug. 17 (0.00)
Groundwater Elevation from Water Level Gauging Events (feet, NAVD88)
Well ID
Aquifer
Baseline
Mid -Commissioning
Post -Startup
Monthly O&M
Monthly O&M
Monthly O&M
Monthly O&M
Monthly O&M
August 4, 2022 August 17, 2022 January 30. 2023
February 28, 2023
March 29, 2023
April 20, 2023
May 23, 2023
June 21, 2023
July 20, 2023
August 18, 2023
Observation Wells >200 ft Upgradient of Barrier Wall/Willis Creek Alignments: 11 Wells
BCA-01
Black Creek Aquifer
Not Gauged (Interim Remedy Location; Pump Removed by August 23, 2023)
Not Gauged (Interim Pumping)
BCA-02
Black Creek Aquifer
Not Gauged (Interim Remedy Location; Pump Removed by August 23, 2023)
Not Gauged (Interim Pumping)
NAF-1113
Surficial Aquifer
Not Gauged (Interim Remedy Location; Pump Removed by August 23, 2023)
Not Gauged (Interim Pumping)
PIW-21)
Black Creek Aquifer
58.08
57.94
57.64
57.59
57.67
57.74
57.64
57.42
57.34
57.29
PW-02
Surficial Aquifer
87.27
87.00
85.32
85.09
84.85
84.73
84.40
83.13
83.93
83.71
PW-03
Surficial Aquifer
104.95
104.87
104.39
104.45
104.24
104.33
104.42
104.38
104.35
102.09
PW-04
Surficial Aquifer
68.40
68.33
67.49
68.36
68.55
68.55
68.72
68.43
69.13
69.45
PW-14
Black Creek Aquifer
Not Gauged (Interim Remedy Location; Pump Removed by August 23, 2023)
Not Gauged (Interim Pumping)
PW-15R
Black Creek Aquifer
Not Gauged (Interim Remedy Location; Pump Removed by August 23, 2023)
Not Gauged (Interim Pumping)
SMW-03B
Black Creek Aquifer
89.92
89.71
87.73
87.47
87.19
87.03
86.79
86.60
86.35
86.23
SMW-09
Surficial Aquifer
82.14
82.03
80.43
80.26
80.12
79.20
79.71
79.93
79.75
79.75
Median (Surficial Aquifer wells)
84.71
84.52
82.88
82.68
82.49
81.97
82.06
81.53
81.84
81.73
Median (Black Creek Aquifer wells)
74.00
73.83
72.69
72.53
72.43
72.39
72.22
72.01
71.85
71.76
TR0795C Page 5 of 6 June 2024
Table 6-1
Summary of Groundwater Level Information
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, North Carolina
Antecedent Daily Total Rainfall (inches):
Sep. 18 (0.00)
Oct 27 (0.00)
Nov. 25 (0.00)
Dec. 17 (3.34)
Jan. 28 (0.02)
Feb. 24 (0.01)
Mar. 24 (0.00)
Most Recent Calculated Head
Differential
(feet, positive value indicates drawdown)
Change in Magnitude of Head
Differential
Sept. 19 (0.00)
Oct 28. (0.00)
Nov. 26 (0.06)
Dec. 18 (0.04)
Jan. 29 (0.00)
Feb. 25 (0.00)
Mar. 25 (0.00)
Sept. 20 (0.00)
Oct 29 (0.00)
Nov. 27 (0.03)
Dec. 19 (0.00)
Jan. 30 (0.00)
Feb. 26 (0.01)
Mar. 26 (0.00)
Well ID
Aquifer
Groundwater Elevation from Water Level Gauging Events (feet, NAVD88)
Monthly O&M
Monthly O&M
Monthly O&M
Monthly O&M
Monthly O&M
Monthly O&M
Monthly O&M
September 21, 2023
October 30, 2023
November 28, 2023
December 20, 2023
January 31, 2024
February 27, 2024
March 27, 2024
March 27, 2024 vs. January 30, 2023
March 27 vs February 27, 2024
Observation Wells >200 ft Upgradient of Barrier Wall/Willis Creek Alignments: 11 Wells
BCA-01
Black Creek Aquifer
80.01
79.65
79.77
79.63
79.56
79.95
79.45
N/A
0.50
BCA-02
Black Creek Aquifer
Not Gauged
70.63
70.35
69.96
70.28
70.17
70.27
N/A
0.10
NAF-11B
Surficial Aquifer
Dry
Dry
Dry
Dry
Dry
Dry
Dry
N/A
N/A
PlW-2D
Black Creek Aquifer
57.19
56.94
56.78
57.04
57.41
56.99
57.04
0.60
0.05
PW-02
Surficial Aquifer
83.53
83.41
83.38
83.34
83.33
83.88
83.30
2.02
0.58
PW-03
Surficial Aquifer
Not Gauged
104.38
104.08
103.66
104.20
104.22
104.48
-0.09
0.26
PW-04
Surficial Aquifer
70.79
70.10
69.28
68.77
69.30
69.33
69.43
-1.94
0.10
PW-14
Black Creek Aquifer
Not Gauged
81.55
81.42
81.25
81.26
81.27
81.19
N/A
0.08
PW-15R
Black Creek Aquifer
68.92
68.57
68.84
68.76
69.34
69.63
68.93
N/A
0.70
SMW-03B
Black Creek Aquifer
86.05
85.90
85.75
85.57
85.38
85.71
85.25
2.48
0.46
SMW-09
Surficial Aquifer
79.68
79.45
79.55
79.45
80.20
79.35
79.28
1.15
0.07
Median (Surficial Aquifer wells)
79.68
81.43
81.47
81.40
81.77
81.62
81.29
0.53
0.18
Median (Black Creek Aquifer wells)
74.47
75.14
75.06
74.80
74.92
75.06
74.86
1.54
0.28
Notes:
1 - For comparison and calculation of head differentials, elevation data for replacement wells (OW-04R, OW-09R, PlW-SSR, and PW-IORR) has been merged with the corresponding original wells. Since the replacement wells were not installed in exactly the same location as the originals, some spatial variation might exist.
TR0795C Page 6 of 6 June 2024
Table 6-2
PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537 MOD SOP COMPOUNDS LIST'
(ng/L)
Mass Loading Model Sampling Program (Quarterly)
LTW-01
LTW-02
CAP1Q23-LTW-01-
021623
Sample Date:
16-Feb-23
CAP2Q23-LTW-01-
051723
Sample Date:
17-May-23
CAP3Q23-LTW-01-
071323
Sample Date:
13-Jul-23
CAP4Q23-LTW-01-
110323
Sample Date:
3-Nov-23
CAP1Q24-LTW-01-
011724
Sample Date:
17-Jan-24
CAP1Q23-LTW-02-
021623
Sample Date:
16-Feb-23
CAP2Q23-LTW-02-
051723
Sample Date:
17-May-23
CAP3Q23-LTW-02-
071223
Sample Date:
12-Jul-23
CAP4Q23-LTW-02-
110323
Sample Date:
3-Nov-23
CAP1Q24-LTW-02-
011724
Sample Date:
17-Jan-24
Hfpo Dimer Acid
18,000
18 000
8,500
15 000
15,000
2 800
7,000
6 800 J
9,800
12 000
PFMOAA
23,000
21,000
27,000
24,000
12,000
9,300
17,000
31,000
27,000
32,000
PF02HxA
23,000
21,000
28,000
25,000
17,000
4,800
10,000
22,000
21,000
28,000
PF030A
5,700
5,300
6,400
5,700
3,300
1 100
1,900
3 700
4,100
5 200
PF04DA
1,300
1,500
1,600
1,300
950
86
120
180
160
200
PF05DA
170
170
200
210
140
<78
<78
<2.0
<100
<130
PMPA
16,000
16,000
19,000
18,000
15,000
1 800
5,700
11 000
11,000
14,000
PEPA
5,900
5 700
7,200
6,200
6,800
580
1,800
3,600
3 500
5,100
PS Acid
<20
<20
<2.0
<40
<50
<20
<20
<2.0
<40
<50
Hydro -PS Acid
310
300
280
280
200
<6.1
15
17
<44
<55
R-PSDA
960 J
<71
940 J
790 J
830 J
<71
<71
620 J
520 J
780 J
Hydrolyzed PSDA
560 J
690 J
760 J
590 J
83 J
270 J
<38
1300 J
1 500 J
1,800 J
R-PSDCA
<17
<17
6.9
<140
<180
<17
<17
<3.0
<140
<180
NVHOS, Acid Form
390
440
320
430
270
160
300
320
410
450
EVE Acid
<17
<17
<2.0
<40
<50
<17
<17
<2.0
<40
<50
Hydro -EVE Acid
160
140
150
140
51
<14
38
39
42
<30
R-EVE
550 J
580 J
560 J
530 J
310 J
<72
<72
260 J
410 J
440 J
Perfluoro 2-ethox ethane sulfonic Acid
<6.7
<6.7
<2.0
<29
<36
<6.7
<6.7
<2.0
<29
<36
PFECA B
<27
<27
<2.0
<62
<78
<27
<27
<2.0
<62
<78
PFECA-G
<48
<48
<2.0
<29
<36
<48
<48
<2.0
<29
<36
PFPrA
22,000
24,000
15,000
16,000
21,000
23,000
Total Table 3+ (17 compounds) 2,3
93,90
,600
98,700
96,300
70,700
20,600
43,900
78,700
77,000
97,000
Total Table 3+ (18 compounds) 2,4
--
121,000
120,000
85,700
1 94,700
98,000
1201000
Total Table 3+ (21 compounds) 2,5
123,000
122,000
86,900
96,800
1 100,000
123,000
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the 3Q 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
2 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to three significant figures.
3 - Total Table 3+ (17 compounds) does not include R-PSDA, Hydrolyzed PSDA, R-EVE, and PFPrA.
4 - Total Table 3+ (18 compounds) does not include R-PSDA, Hydrolyzed PSDA, and R-EVE.
5 - Total Table 3+ (21 compounds) is the sum of all Table 3+ PFAS compounds.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 1 of 24 June 2024
Table 6-2
PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537 MOD SOP COMPOUNDS LIST'
(ng/L)
Mass Loading Model Sampling Program (Quarterly)
LTW-03
LTW-04
CAP1Q23-LTW-03-
022123
Sample Date:
21-Feb-23
CAP2Q23-LTW-03-
052323
Sample Date:
23-May-23
CAP3Q23-LTW-03-
071223
Sample Date:
12-Jul-23
CAP4Q23-LTW-03-
111323
Sample Date:
13-Nov-23
CAP1Q24-LTW-03-
013124
Sample Date:
31-Jan-24
CAP1Q23-LTW-04-
021723
Sample Date:
17-Feb-23
CAP2Q23-LTW-04-
052323
Sample Date:
23-May-23
CAP3Q23-LTW-04-
071123
Sample Date:
11-Jul-23
CAP4Q23-LTW-04-
110223
Sample Date:
2-Nov-23
CAP1Q24-LTW-04-
011624
Sample Date:
16-Jan-24
Hfpo Dimer Acid
11,000
10,000
8,600
5,800 J
7 800
18,000
19 000
9,800 J
17 000
17,000
PFMOAA
120,000
120,000
140,000 J
110,000 J
86,000
55,000
55,000
57,000 J
61 000
55 000
PF02HxA
34,000
41,000
49,000 J
24,000 J
28,000
23 000
28,000
29,000
26,000
26,000
PF030A
5,800
6,700
7,600
5,900
3,800
4,400
5 200
5,200
5,300
5,100
PF04DA
200
220
230
240
150
630
620
780
650
560
PF05DA
<78
<78
<2.0
<2.0
<130
<78
<78
26
<100
<130
PMPA
14,000
15,000
16,000
18,000
11 000
17,000
16,000
20 000
17,000
16,000
PEPA
3,400
3,500
3 600
3,700
2,200
6,400
6,000
6,900
6100
5,500
PS Acid
<20
<20
<2.0
<2.0
<50 UJ
<20
<20
5
<40
<50
Hydro -PS Acid
<6.1
28
26
26
<55
170
210
190
180
150
R-PSDA
1,000 J
950 J
900 J
870 J
770 J
2,000 J
1,700 J
1,700 J
1,700 J
1,400 J
Hydrolyzed PSDA
7,100 J
5,800 J
5,900 J
6,500 J
5,300 J
4,200 J
2,300 J
3 000 J
3,800 J
2 800 J
R-PSDCA
<17
<17
<3.0
<3.0
<180
<17
<17
12
<140
<180
NVHOS, Acid Form
1300
1300
1,900
1,400
1 100
1300
1200
1,400
1 100
1,200
EVE Acid
<17
<17
<2.0
<2.0
<50 UJ
<17
<17
<2.0
<40
<50
Hydro -EVE Acid
71
64
63
56
42
500
390
540
470
370
R-EVE
520 J
430 J
150 J
180 J
320 J
2,000 J
1,500 J
1,300 J
1,700 J
1,100 J
Perfluoro 2-ethox ethane sulfonic Acid
<6.7
<6.7
6.1
6
<36
<6.7
<6.7
8.2
<29
<36
PFECA B
<27
<27
<2.0
<2.0
<78
<27
<27
<2.0
<62
<78
PFECA-G
<48
<48
<2.0
<2.0
<36
<48
<48
<2.0
<29
<36
PFPrA
62,000 J
61,000 J
47,000
53,000
48,000
43,000 J
Total Table 3+ (17 compounds) 2,3
190,000
227,000
169,000
140,000
126,000
1
131,000
135,000
127,000
Total Table 3+ (18 compounds) 2,4
--
289,000
230,000
1 187,000
--
-
184,000
183,000
170,000
Total Table 3+ (21 compounds) 2,5
296,000
238,000
1 193,000
1--
-
190,000
190,000
175,000
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the 3Q 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
2 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to three significant figures.
3 - Total Table 3+ (17 compounds) does not include R-PSDA, Hydrolyzed PSDA, R-EVE, and PFPrA.
4 - Total Table 3+ (18 compounds) does not include R-PSDA, Hydrolyzed PSDA, and R-EVE.
5 - Total Table 3+ (21 compounds) is the sum of all Table 3+ PFAS compounds.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 2 of 24 June 2024
Table 6-2
PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537 MOD SOP COMPOUNDS
LIST I
(ng/L)
Mass Loading Model Sampling Program (Quarterly)
LTW-05
OW-28
CAP1Q23-LTW-05-
021523
Sample Date:
15-Feb-23
CAP2Q23-LTW-05-
052223
Sample Date:
22-May-23
CAP3Q23-LTW-05-
071123
Sample Date:
11-Jul-23
CAP4Q23-LTW-05-
110223
Sample Date:
2-Nov-23
CAP1Q24-LTW-05-
011524
Sample Date:
15-Jan-24
CAP1Q23-OW-28-
022023
Sample Date:
20-Feb-23
CAP2Q23-OW-28-
052523
Sample Date:
25-May-23
CAP3Q23-OW-28-
071123
Sample Date:
11-Jul-23
CAP4Q23-OW-28-
110223
Sample Date:
2-Nov-23
CAP1Q24-OW-28-
011824
Sample Date:
18-Jan-24
Hf o Dimer Acid
18,000
19 000 J
9 000
18 000
31,000
4 800
4,800
4 400
4,400
3 800
PFMOAA
120,000
130,000 J
120,000 J
170,000
200,000
1,500
1,900
1,600
1,600
1,600
PF02HxA
36,000
48,000 J
41,000 J
58,000
68,000
2,500
3,500
3 400
3,100
3 300
PF030A
8,300
11 000 J
9,500
14 000
21,000
510
670
550
680
620
PF04DA
2,100
2,100 J
2,000
1,900
2,300
110
83
94
120
85
PF05DA
<78
<78 UJ
<2.0
<100
<130
<78
<78
<2.0
<100
<130
PMPA
4,000
4 600 J
4,200
5 500
9,200
5 000
6,400
5,200
6 000
5,700
PEPA
620
530 J
440
510
1,800
1,900
2 500
1,800
2,200
2,800
PS Acid
<20
<20 UJ
<2.0
<40
<50
<20
<20
<2.0
<40
<50
Hydro -PS Acid
190
190 J
200
200
330
75
74
75
75
84
R-PSDA
490 J
670 J
500 J
950 J
1,300 J
340 J
310 J
250 J
230 J
280 J
Hydrolyzed PSDA
880 J
1,100 J
950 J
1,900 J
2 600 J
<38
<38
2.2 J
<27 UJ
<34
R-PSDCA
19
<17 UJ
17
<140
<180
<17
<17
<3.0
<140
<180
NVHOS, Acid Form
1,100
1 300 J
1,000
1 500
2,100
110
<15
31
<130
<160
EVE Acid
<17
<17 UJ
<2.0
<40
<50
<17
<17
<2.0
<40
<50
Hydro -EVE Acid
750
720 J
720
770
1300
<14
<14
14
<24
<30
R-EVE
610 J
760 J
610 J
1,200 J
1,500 J
190 J
180 J
380 J
140 J
120 J
Perfluoro 2-ethox ethane sulfonic Acid
<6.7
<6.7 UJ
11
<29
<36
<6.7
<6.7
<2.0
<29
<36
PFECA B
<27
<27 UJ
<2.0
<62
<78
<27
<27
<2.0
<62
<78
PFECA-G
<48
<48 UJ
<2.0
<29
<36
<48
<48
<2.0
<29
<36
PFPrA
83,000 J
120 000
120,000
5,200
5,500
6 500
Total Table 3+ (17 compounds) 2,3
191,000
188,000
270,000
337,000
16,500
19,900
17,200
18,200
18,000
Total Table 3+ (18 compounds) 2,4
--
NJ
271,000
390,000
457,000
--
--
22,400
23,700
24,500
Total Table 3+ (21 com ounds)2,5
--
--
1
273,000
394,000
462,000
--
--
23,000
24,000
24,900
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the 3Q 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
2 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to three significant figures.
3 - Total Table 3+ (17 compounds) does not include R-PSDA, Hydrolyzed PSDA, R-EVE, and PFPrA.
4 - Total Table 3+ (18 compounds) does not include R-PSDA, Hydrolyzed PSDA, and R-EVE.
5 - Total Table 3+ (21 compounds) is the sum of all Table 3+ PFAS compounds.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 3 of 24 June 2024
Table 6-2
PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537 MOD SOP COMPOUNDS
LIST I
(ng/L)
Mass Loading Model Sampling Program (Quarterly)
OW-33
PIW-1D
CAP1Q23-OW-33-
021423
Sample Date:
14-Feb-23
CAP2Q23-OW-33-
051823
Sample Date:
18-May-23
CAP3Q23-OW-33-
071223
Sample Date:
12-Jul-23
CAP4Q23-OW-33-
110223
Sample Date:
2-Nov-23
CAP1Q24-OW-33-
013024
Sample Date:
30-Jan-24
CAP1Q23-PIW-1D-
021623
Sample Date:
16-Feb-23
CAP2Q23-PIW-1D-
052323
Sample Date:
23-May-23
CAP3Q23-PIW-1D-
080223
Sample Date:
2-Aug-23
CAP4Q23-PIW-1D-
110723
Sample Date:
7-Nov-23
CAP1Q24-PIW-1D-
012224
Sample Date:
22-Jan-24
Hf o Dimer Acid
5,300
5 000
4,000
4 900
4,400
9 800
9 900
9 200 J
8,800
8 600
PFMOAA
7,900
8,400
11,000
9,800
7,700
12,000
12,000
11,000 J
9,900
10,000
PF02HxA
4,700
4 300
6,500
5,900
3,800
8 800
11,000
9 900 J
12,000
9 800
PF030A
810
840
1,100
1,100
560
1,500
1,700
1 600
1,700
1 900
PF04DA
<59
<59
71
66
<50
430
440
410
430
250
PF05DA
<78
<78
<2.0
<100
<130
<78
<78
<100
<100
<130
PMPA
4,800
5 200
6100
6 000
4,500
7 800
9,000
9 600 J
8,600
9 800
PEPA
2,000
1,800
2,300
2 200
1300
2 600
3,000
3 200
3,100
3 700
PS Acid
<20
<20
8
<40
<50 UJ
<20
<20
<40
<40
<50
Hydro -PS Acid
29
53
43
<44
<55
87
98
86
76
95
R-PSDA
280 J
<71
290 J
250 J
210 J
330 J
380 J
370 J
320 J
380 J
Hydrolyzed PSDA
<38
<38
58 J
61 J
38 J
<38
<38
<27
<27
<34
R-PSDCA
<17
<17
<3.0
<140
<180
<17
<17
<140
<140
<180
NVHOS, Acid Form
170
240
130
140
<160
190
160
150 J
140
<160
EVE Acid
<17
<17
<2.0
<40
<50 UJ
<17
<17
<40
<40
<50
Hydro -EVE Acid
<14
<14
14
<24
<30
31
<14
29
28
32
R-EVE
130 J
<72
220 J
170 J
140 J
190 J
200 J
280 J
220 J
180 J
Perfluoro 2-ethox ethane sulfonic Acid
<6.7
<6.7
<2.0
<29
<36
<6.7
<6.7
<29
<29
<36
PFECA B
<27
<27
<2.0
<62
<78
<27
<27
<62
<62
<78
PFECA-G
<48
<48
<2.0
<29
<36
<48
<48
<29
<29
<36
PFPrA
9,900
9 400
7,300
12,000 J
12,000
11,000
Total Table 3+ (17 compounds) 2,3
25,700
25,800
31,300
30,100
22,300
43,200
47,300
45,200
44,800
44,200
Total Table 3+ (18 compounds) 2,4
--
--
41,200
39,500
29,600
--
--
57,200
1 56,800
1 55,200
Total Table 3+ (21 compounds) 2,5
--
--M
1 41,700
40,000
29,900
--
--
57,800
1 57,300
1 55,700
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the 3Q 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
2 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to three significant figures.
3 - Total Table 3+ (17 compounds) does not include R-PSDA, Hydrolyzed PSDA, R-EVE, and PFPrA.
4 - Total Table 3+ (18 compounds) does not include R-PSDA, Hydrolyzed PSDA, and R-EVE.
5 - Total Table 3+ (21 compounds) is the sum of all Table 3+ PFAS compounds.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 4 of 24 June 2024
Table 6-2
PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537 MOD SOP COMPOUNDS
I
ft/L)
Mass Loading Model Sampling Program (Quarterly)
PIW-1S
PIW-31)
CAP1Q23-PIW-1S-
021623
Sample Date:
16-Feb-23
Not Sampled in 2Q 2023
(Dry)
Not Sampled in 3Q 2023
(Dry)
Not Sampled in 4Q 2023
(Dry)LIST
CAP1Q24-PIW-1S-
011624
Sample Date:
16-Jan-24
CAP1Q23-PIW-3D-
021623
Sample Date:
16-Feb-23
CAP2Q23-PIW-3D-
051723
Sample Date:
17-May-23
CAP3Q23-PIW-3D-
071323
Sample Date:
13-Jul-23
CAP4Q23-PIW-3D-
110323
Sample Date:
3-Nov-23
CAP1Q24-PIW-3D-
011824
Sample Date:
18-Jan-24
Hf o Dimer Acid
7,400
--
--
--
1,400
12,000
12 000
9,700
12 000
15,000
PFMOAA
2,000
--
--
--
390 J
9,400
8,500
13,000
19,000
25,000
PF02HxA
4,700
--
--
--
1,200
12,000
10,000
16,000
19,000
27,000
PF030A
900
--
--
--
240
2,200
2 100
3,100
4 000
5,600
PF04DA
440
110
940
800
890
1,20
1,800
PF05DA
<78
--
--
--
<130
130
<78
160
200
380
PMPA
4,400
--
--
--
1,100
9,500
8 800
12,000
13,000
16,000
PEPA
1,900
--
--
--
330
3,700
3,400
4,500
4 700
6,100
PS Acid
<20
--
--
--
<50
<20
<20
<2.0
<40
<50
Hydro -PS Acid
210
--
--
--
230
240
200
240
290
340
R-PSDA
<71
--
--
--
110 J
520 J
<71
610 J
750 J
780 J
Hydrolyzed PSDA
<38
--
--
--
<34
<38
<38
15 J
300 J
470 J
R-PSDCA
<17
--
--
--
<180
<17
<17
4.7
<140
<180
NVHOS, Acid Form
<15
--
--
--
<160
190
290
170
310
360
EVE Acid
<17
--
--
--
<50
<17
<17
<2.0
<40
<50
Hydro -EVE Acid
62
--
--
--
30
72
70
74
100
100
R-EVE
180 J
--
--
--
<39
220 J
<72
280 J
420 J
390 J
Perfluoro 2-ethox ethane sulfonic Acid
<6.7
--
--
--
<36
<6.7
<6.7
<2.0
<29
<36
PFECA B
<27
--
--
--
<78
<27
<27
<2.0
<62
<78
PFECA-G
<48
--
--
--
<36
<48
<48
<2.0
<29
<36
PFPrA
--
1,300 J
19,000
21,000
22,000
Total Table 3+ (17 compounds) 2,3
22,000
--IME
IMIN--IME
MEMEL.
1 5,030
50,400
46,200
59,800
73,800
97,700
Total Table 3+ (18 compounds) 2,4
--
--
--
6,330
1 78,800
94,800
1 120,000
Total Table 3+ (21 compounds) 2,5
--
--
--
6,440
1 79,700
96,300
1 121,000
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the 3Q 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
2 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to three significant figures.
3 - Total Table 3+ (17 compounds) does not include R-PSDA, Hydrolyzed PSDA, R-EVE, and PFPrA.
4 - Total Table 3+ (18 compounds) does not include R-PSDA, Hydrolyzed PSDA, and R-EVE.
5 - Total Table 3+ (21 compounds) is the sum of all Table 3+ PFAS compounds.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 5 of 24 June 2024
Table 6-2
PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537 MOD SOP COMPOUNDS
LIST I
(ng/L)
Mass Loading Model Sampling Program (Quarterly)
PIW-71)
PIW-7S
CAP1Q23-PIW-7D-
021523
Sample Date:
15-Feb-23
CAP2Q23-PIW-7D-
052223
Sample Date:
22-May-23
CAP3Q23-PIW-7D-
071123
Sample Date:
11-Jul-23
CAP4Q23-PIW-7D-
110223
Sample Date:
2-Nov-23
CAP1Q24-PIW-7D-
011524
Sample Date:
15-Jan-24
CAP1Q23-PIW-7S-
021523
Sample Date:
15-Feb-23
CAP2Q23-PIW-7S-
052223
Sample Date:
22-May-23
CAP3Q23-PIW-7S-
071123
Sample Date:
11-Jul-23
CAP4Q23-PIW-7S-
110223
Sample Date:
2-Nov-23
CAP1Q24-PIW-7S-
011524
Sample Date:
15-Jan-24
Hf o Dimer Acid
17,000
8 800 J
9,600 J
13,000
14,000
15,000
12,000 J
8,000
12,000
13,000
PFMOAA
140,000
130,000 J
140,000 J
150,000
150,000
18,000
16 000 J
15,000
17 000
17,000
PF02HxA
47,000
37,000 J
42,000 J
43,000
38,000
13,000
12,000 J
11 000
12,000
13,000
PF030A
9,200
5 900 J
6,800
6 100
6,500
5 100
3,800 J
2,800
4 300
3,800
PF04DA
1,700
1,100 J
890
1,000
870
660
440 J
350
420
400
PF05DA
<78
<78 UJ
<2.0
<100
<130
<78
<78 UJ
19
<100
<130
PMPA
5,100
4 500 J
4,300
5200
5,600
11 000
7,900 J
6 900
9,200
9 500
PEPA
1,100
950 J
950
1,000
1,100
4,500
3,300 J
2,500
3,400
3 800
PS Acid
<20
<20 UJ
<2.0
<40
<50
<20
<20 UJ
<2.0
<40
<50
Hydro -PS Acid
180
98 J
110
110
110
340
270 J
220
250
230
R-PSDA
710 J
470 J
460 J
510 J
570 J
1,200 J
960 J
710 J
910 J
790 J
Hydrolyzed PSDA
1,200 J
740 J
890 J
1,100 J
1,100 J
<38
63 J
110 J
60 J
45 J
R-PSDCA
<17
<17 UJ
7.3
<140
<180
<17
<17 UJ
5.4
<140
<180
NVHOS, Acid Form
1,200
990 J
1,100
1,200
1300
830
630 J
520
690
680
EVE Acid
<17
<17 UJ
<2.0
<40
<50
<17
<17 UJ
<2.0
<40
<50
Hydro -EVE Acid
610
330 J
360
360
320
650
460 J
360
430
360
R-EVE
870 J
550 J
560 J
680 J
540 J
1,400 J
1,000 J
820 J
1,200 J
880 J
Perfluoro 2-ethox ethane sulfonic Acid
12
<6.7 UJ
8.5
<29
<36
<6.7
<6.7 UJ
3.3
<29
<36
PFECA B
<27
<27 UJ
<2.0
<62
<78
<27
<27 UJ
<2.0
<62
<78
PFECA-G
<48
<48 UJ
<2.0
<29
<36
<48
<48 UJ
<2.0
<29
<36
PFPrA
79,000 J
86,000
71,000 J
14,000
18,000
17 000 J
Total Table 3+ (17 compounds) 2,3
223,000 a
190,000
206,000
221,000
218,000
69,100
56,800
47,700
59,700
61,800
Total Table 3+ (18 compounds) 2,4
--
--1
285,000
1 307,000
1 289,000
--
--
61,700
77,700
1 78,800
Total Table 3+ (21 compounds) 2,5
--
--1
287,000
It 309,000
1 291,000
1--
--1
63,300
79,900
1 80,500
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the 3Q 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
2 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to three significant figures.
3 - Total Table 3+ (17 compounds) does not include R-PSDA, Hydrolyzed PSDA, R-EVE, and PFPrA.
4 - Total Table 3+ (18 compounds) does not include R-PSDA, Hydrolyzed PSDA, and R-EVE.
5 - Total Table 3+ (21 compounds) is the sum of all Table 3+ PFAS compounds.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 6 of 24 June 2024
Table 6-2
PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537 MOD SOP COMPOUNDS
LIST I
(ng/L)
Mass Loading Model Sampling Program (Quarterly)
PW-04
PZ-22
CAP1Q23-PW-04-
022323
Sample Date:
23-Feb-23
CAP2Q23-PW-04-
052523
Sample Date:
25-May-23
CAP3Q23-PW-04-
072823
Sample Date:
28-Jul-23
CAP4Q23-PW-04-
110923
Sample Date:
9-Nov-23
CAP1Q24-PW-04-
011724
Sample Date:
17-Jan-24
CAP1Q23-PZ-22-022023
Sample Date:
20-Feb-23
CAP2Q23-PZ-22-052323
Sample Date:
23-May-23
CAP3Q-PZ-22-071123
Sample Date:
11-Jul-23
CAP4Q23-PZ-22-110223
Sample Date:
2-Nov-23
CAP1Q24-PZ-22-011624
Sample Date:
16-Jan-24
Hfpo Dimer Acid
730
980
950
670
1,000
13,000
12,000
7,300 J
11,000
11,000
PFMOAA
300
490
380
300
370
140,000
150,000
140,000
170 000
150,000
PF02HxA
640
1,100
1,000
930
1,000
38,000
49,000
50,000
47,000
42,000
PF030A
330
520
520
340
450
3,600
5,400
4,800
5 400
5,100
PF04DA
63
95
120
100
110
120
270
240
210
220
PF05DA
<78
<78
<100
<100
<130
<78
<78
<2.0
<100
<130
PMPA
860
1,200
1,200
950
1,400
5 000
6 200
6,100
6 700
6,300
PEPA
330
440
480
320
590
1,200
1,500
1,600
1,500
1 400
PS Acid
<20
<20
<40
<40
<50
<20
<20
3.1
<40
<50
Hydro -PS Acid
22
<6.1
<44
<44
<55
28
36
35
<44
<55
R-PSDA
160 J
150 J
78 J
<28
130 J
540 J
560 J
540 J
510 J
440 J
Hydrolyzed PSDA
<38
<38
<27
<27
<34
890 J
1,000 J
1,100 J
1,600 J
1,100 J
R-PSDCA
<17
<17
<140
<140
<180
<17
<17
3.2
<140
<180
NVHOS, Acid Form
<15
<15
<130
<130
<160
1,100
1300
1,500
1,200
1300
EVE Acid
<17
<17
<40
<40
<50
<17
<17
<2.0
<40
<50
Hydro -EVE Acid
<14
<14
<24
<24
<30
46
84
79
73
73
R-EVE
<72
86 J
49 J
66 J
66 J
450 J
430 J
220 J
420 J
300 J
Perfluoro 2-ethox ethane sulfonic Acid
<6.7
<6.7
<29
<29
<36
<6.7
<6.7
6.3
<29
<36
PFECA B
<27
<27
<62
<62
<78
<27
<27
<2.0
<62
<78
PFECA-G
<48
<48
<29
<29
<36
<48
<48
<2.0
<29
<36
PFPrA
1,400
1,500
1,400
76,000
84,000
72 000 J
Total Table 3+ (17 compounds) 2,3
3,280
4,650
3,610
4,920
202,000
226,000
212,000
243,000
217,000
Total Table 3+ (18 compounds) 2,4
--
--
6,050
5,110
6,320
--
--
288,000
327,000
289,000
Total Table 3+ (21 compounds) 2,5
--
--
6,180
5,180
6,520
--
290,000
330,000
291,000
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the 3Q 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
2 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to three significant figures.
3 - Total Table 3+ (17 compounds) does not include R-PSDA, Hydrolyzed PSDA, R-EVE, and PFPrA.
4 - Total Table 3+ (18 compounds) does not include R-PSDA, Hydrolyzed PSDA, and R-EVE.
5 - Total Table 3+ (21 compounds) is the sum of all Table 3+ PFAS compounds.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 7 of 24 June 2024
Table 6-2
PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537 MOD SOP COMPOUNDS
LIST I
(ng/L)
Mass Loading Model Sampling Program (Quarterly)
Performance Monitoring Plan Sampling Program (Semi -Annually)
SMW-12
OW-411
OW-30
CAP1Q23-SMW-12-
022323
Sample Date:
23-Feb-23
CAP2Q23-SMW-12-
051723
Sample Date:
17-May-23
CAP3Q23-SMW-12-
071823
Sample Date:
18-Jul-23
CAP4Q23-SMW-12-
110823
Sample Date:
8-Nov-23
CAP1Q24-SMW-12-
011624
Sample Date:
16-Jan-24
CAP3Q23-OW-4R-
080423
Sample Date:
4-Aug-23
CAP1Q24-OW-4R-
012924
Sample Date:
29-Jan-24
CAP1Q23-OW-30-
021523
Sample Date:
15-Feb-23
CAP3Q23-OW-30-
071323
Sample Date:
13-Jul-23
CAP1Q24-OW-30-
013024
Sample Date:
30-Jan-24
Hf o Dimer Acid
1,500
1900
2,200
1900
1,900
11 000
9,400
9 500
6,200
5 900
PFMOAA
2,900
5,100
5,800
8,300
9,600
42,000
35,000
32,000
27,000
21,000
PF02HxA
1,200
1 900
3,500
4,200
3,200
17,000
13,000
12,000
11,000
8,300
PF030A
78
150
230
420
490
5,400
3 100
2,100
1 700
1300
PF04DA
<59
<59
<36
<40
<50
1,800
1,200
<59
8.9
<50
PF05DA
<78
<78
<91
<100
<130
<100
<130
<78
<2.0
<130
PMPA
2,300
2 900
2,600
1 700
1,900
8 600
5,700
4 300
4,400
3,200
PEPA
460
550
620
340
300
2,700
1,900
1300
1300
900
PS Acid
<20
<20
<36
<40
<50
<40
<50 UJ
<20
<2.0
<50 UJ
Hydro -PS Acid
<6.1
<6.1
<40
<44
<55
290
250
<6.1
<2.0
<55
R-PSDA
150 J
<71
87 J
76 B
65 J
760 J
570 J
460 J
330 J
340 J
Hydrolyzed PSDA
<38
<38
<25
<27
<34
3,100 J
2 300 J
760 J
570 J
520 J
R-PSDCA
<17
<17
<130
<140
<180
<140
<180
<17
<3.0
<180
NVHOS, Acid Form
48
<15
<120
<130
<160
580
480
370
220
270
EVE Acid
<17
<17
<36
<40
<50
<40
<50 UJ
<17
<2.0
<50 UJ
Hydro -EVE Acid
<14
<14
<22
<24
<30
1,100
890
24
12
<30
R-EVE
97 J
<72
69 J
67 J
45 J
630 J
390 J
410 J
290 J
270 J
Perfluoro 2-ethox ethane sulfonic Acid
<6.7
<6.7
<26
<29
<36
<29
<36
<6.7
<2.0
<36
PFECA B
<27
<27
<56
<62
<78
<62
<78
<27
<2.0
<78
PFECA-G
<48
<48
<26
<29
<36
<29
<36
<48
<2.0
<36
PFPrA
5,900
7 000
6,400 J
25,000
21,000
19,000
16,000
Total Table 3+ (17 compounds) 2,3
12,500
15,000
16,900
17,400
90,500
70,900
61,600
51,800
40,900
Total Table 3+ (18 compounds) 2,4
--
--
20,900
23,900
23,800
115,000
91,900
70,800
56,900
Total Table 3+ (21 compounds)
--
--
21,000
24,000
23,900
120,000
95,200
72,000
58,000
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the 3Q 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
2 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to three significant figures.
3 - Total Table 3+ (17 compounds) does not include R-PSDA, Hydrolyzed PSDA, R-EVE, and PFPrA.
4 - Total Table 3+ (18 compounds) does not include R-PSDA, Hydrolyzed PSDA, and R-EVE.
5 - Total Table 3+ (21 compounds) is the sum of all Table 3+ PFAS compounds.
Wells OW-4R, OW-32, OW-37, and OW-51 were installed between late June 2023 and August 2023, so were unavailable for sampling before 3Q 2023.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 8 of 24 June 2024
Table 6-2
PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537 MOD SOP COMPOUNDS
LIST I
(ng/L)
Performance Monitoring Plan Sampling Program (Semi -Annually)
OW-32
OW-37
OW-40
OW-51
OW-54
CAP3Q23-OW-32-
090823
Sample Date:
8-Sep-23
CAP1Q24-OW-32-
012924
Sample Date:
29-Jan-24
CAP3Q23-OW-37-
081023
Sample Date:
10-Aug-23
CAP1Q24-OW-37-
011724
Sample Date:
17-Jan-24
CAP1Q23-OW-40-
021523
Sample Date:
15-Feb-23
CAP3Q23-OW-40-
071323
Sample Date:
13-Jul-23
CAP1Q24-OW-40-
013024
Sample Date:
30-Jan-24
CAP3Q23-OW-51-
080323
Sample Date:
3-Aug-23
CAP1Q24-OW-51-
013124
Sample Date:
31-Jan-24
CAP1Q23-OW-54-
021623
Sample Date:
16-Feb-23
Not Sampled in 3Q
2023 (Dry)
CAP1Q24-OW-54-
020624
Sample Date:
6-Feb-24
Hf o Dimer Acid
580
3,200
4,000 J
290
5,200
3 300
3 400
33,000
11,000
4,500
--
740
PFMOAA
1,800
14,000
15 000 J
1,100
6,900
7 000
6,100
140,000
43,000
360
--
250
PF02HxA
790
4,500
5,900 J
690
4,200
4,700
3200
64,000
19 000
2 600
--
690
PF030A
130
1,200
2,600 J
260
1,100
1 400
650
23,000
6,500
410
--
<110
PF04DA
<40
100
3,900 J
140
130
170
130
4,800
1,10
230
--
110
PF05DA
<100
<130
140 J
420
<78
<2.0
<130
<100
<130
<78
--
<130
PMPA
260
1,800
2 000 J
200
4,300
4,400
3 700
9,400
3 200
2 600
--
760
PEPA
83
460
580 J
79
1,600
1 900
1,100
1,900
720
1,000
--
200
PS Acid
<40
<50 UJ
<40 UJ
<50
<20
<2.0
<50 UJ
<40
<50 UJ
<20
--
<50 UJ
Hydro -PS Acid
<44
<55
370 J
110
35
44
<55
660
150
120
--
<55
R-PSDA
44 J
220 J
1,500 J
100 J
<71
200 J
200 J
1,900 J
650 J
<71
--
78 J
Hydrolyzed PSDA
100 J
650 J
1,200 J
83 J
160 J
130 J
65 J
4,300 J
1 400 J
<38
--
<34
R-PSDCA
<140
<180
<140 UJ
<180
<17
<3.0
<180
<140
<180
<17
--
<180
NVHOS, Acid Form
<130
220
170 J
<160
130
90
<160
1,800
620
<15
--
<160
EVE Acid
<40
<50 UJ
<40 UJ
<50
<17
<2.0
<50 UJ
<40
<50 UJ
<17
--
<50 UJ
Hydro -EVE Acid
<24
70
120 J
<30
94
99
67
2,400
550
<14
--
<30
R-EVE
36 J
140 J
390 J
<39
170 J
240 J
100 J
2,600 J
700 J
<72
--
42 J
Perfluoro 2-ethox ethane sulfonic Acid
<29
<36
<29 UJ
<36
<6.7
<2.0
<36
<29
<36
<6.7
--
<36
PFECA B
<62
<78
<62 UJ
<78
<27
<2.0
<78
<62
<78
<27
--
<78
PFECA-G
<29
<36
<29 UJ
<36
<48
<2.0
<36
<29
<36
<48
--
<36
PFPrA
990
7,200
8,200 J
1 800
5,700
5 400
92,000
31,000
1,400
Total Table 3+ (17 compounds) 2,3
3,640
25,600
34,800
3,290
23,700
23,100
18,300
281,000
85,800
11,800
--
2,750
Total Table 3+ (18 compounds) 2,4
4,630
1 32,800
43,000
1 5,090
1 28,800
1 23,700
373,000
117,000
--
--
4,150
Total Table 3+ (21 compounds) 2,5
4,810
33,800
46,100
5,270
--
29,400
24,100
382,000
120,000
--
--
4,270
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the 3Q 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
2 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to three significant figures.
3 - Total Table 3+ (17 compounds) does not include R-PSDA, Hydrolyzed PSDA, R-EVE, and PFPrA.
4 - Total Table 3+ (18 compounds) does not include R-PSDA, Hydrolyzed PSDA, and R-EVE.
5 - Total Table 3+ (21 compounds) is the sum of all Table 3+ PFAS compounds.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 9 of 24 June 2024
Table 6-2
PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537 MOD SOP COMPOUNDS
LIST I
(ng/L)
Performance Monitoring Plan Sampling Program (Semi -Annually)
OW-55
OW-56
OW-57
PIW-41)
CAP1Q23-OW-55-
021623
Sample Date:
16-Feb-23
CAP3Q23-OW-55-
072523
Sample Date:
25-Jul-23
CAP1Q24-OW-55-
020524
Sample Date:
5-Feb-24
CAP1Q23-OW-56-
022123
Sample Date:
21-Feb-23
CAP3Q23-OW-56-
073123
Sample Date:
31-Jul-23
CAP1Q24-OW-56-
020124
Sample Date:
1-Feb-24
CAP1Q23-OW-57-
021523
Sample Date:
15-Feb-23
CAP3Q23-OW-57-
073123
Sample Date:
31-Jul-23
CAP1Q24-OW-57-
020624
Sample Date:
6-Feb-24
CAP3Q23-PIW-4D-
071323
Sample Date:
13-Jul-23
CAP1Q24-PIW-4D-
012224
Sample Date:
22-Jan-24
Hfpo Dimer Acid
1,800
1 800
1,600
4,200
3 300
2,200
11,000
11,000
11,000
140
320
PFMOAA
220
300
550
350
520
420
130,000
130,000
130,000
1 300
1,900
PF02HxA
690
940
820
1,800
2,100
1,300
36,000
37,000
37,000
470
1,100
PF030A
58
<89
<110
200
260
220
8,600
7 700
6 700
47
110
PF04DA
<59
<40
<50
<59
<40
<50
1,100
1,000
1,000
<2.0
5.3
PF05DA
<78
<100
<130
<78
<100
<130
<78
<100
<130
<2.0
<2.0
PMPA
2,800
3 800
1,800
2,600
2 800
1,500
22 000
21,000
16,000
150
290
PEPA
740
890
470
990
1,100
530
5,100
4 700
3,800
37
71
PS Acid
<20
<40
<50 UJ
<20
<40
<50 UJ
770
360
330 J
<2.0
<2.0
Hydro -PS Acid
<6.1
<44
<55
120
150
100
220
260
240
<2.0
<2.0
R-PSDA
<71
140 J
100 J
310 J
150 J
140 J
970 J
1,200 J
1,200 J
8.9 J
20 J
Hydrolyzed PSDA
<38
<27
<34
<38
<27
<34
16,000 J
14,000 J
15,000 J
25 J
801
R-PSDCA
<17
<140
<180
<17
<140
<180
17
<140
<180
<3.0
<3.0
NVHOS, Acid Form
<15
<130
<160
110
<130
<160
2,000
2 400
2,200
11
19
EVE Acid
<17
<40
<50 UJ
<17
<40
<50 UJ
<17
<40
<50 UJ
<2.0
<2.0
Hydro -EVE Acid
<14
<24
<30
<14
<24
<30
200
210
180
<2.0
<2.0
R-EVE
160J
180J
85J
1901
120J
1101
240J
180J
210J
6.2J
12J
Perfluoro 2-ethox ethane sulfonic Acid
<6.7
<29
<36
<6.7
<29
<36
<6.7
<29
<36
<2.0
<2.0
PFECA B
<27
<62
<78
<27
<62
<78
<27
<62
<78
<2.0
<2.0
PFECA-G
<48
<29
<36
<48
<29
<36
<48
<29
<36
<2.0
<2.0
PFPrA
2,900
1 700
2,200
1,500
44,000
48 000
880
1,300
Total Table 3+ (17 compounds) 2,3
6,310
7,730
5,240
10,400
10,200
6,270
217,000
216,000
208,000
2,160
3,820
Total Table 3+ (18 compounds) 2,4
--1
10,600
1 6,940
--
12,400
7,770
--
260,000
256,000
3,040
5,120
Total Table 3+ (21 compounds) 2,5
--
11,000 M
7,130
12,700
8,020
--
275,000
273,000
3,080
5,230
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the 3Q 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
2 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to three significant figures.
3 - Total Table 3+ (17 compounds) does not include R-PSDA, Hydrolyzed PSDA, R-EVE, and PFPrA.
4 - Total Table 3+ (18 compounds) does not include R-PSDA, Hydrolyzed PSDA, and R-EVE.
5 - Total Table 3+ (21 compounds) is the sum of all Table 3+ PFAS compounds.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 10 of 24 June 2024
Table 6-2
PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537 MOD SOP COMPOUNDS
LIST'
(ng/L)
Performance Monitoring Plan Sampling Program (Semi -Annually)
PIW-5SR
PIW-6S
PIW-81)
PIW-IODR
PIW-10S
PIW-11
CAP3Q23-PIW-5SR-
080423
Sample Date:
4-Aug-23
Not Sampled in 1Q
2024 (Dry)
CAP3Q23-PIW-6S-
071223
Sample Date:
12-Jul-23
CAP1Q24-PIW-6S-
013124
Sample Date:
31-Jan-24
CAP3Q23-PIW-8D-
071123
Sample Date:
11-Jul-23
CAP1Q24-PIW-8D-
012224
Sample Date:
22-Jan-24
CAP3Q23-PIW-
10DR-071423
Sample Date:
14-Jul-23
CAP1Q24-PIW-
10DR-012224
Sample Date:
22-Jan-24
CAP3Q23-PIW-I0S-
071323
Sample Date:
13-Jul-23
Not Sampled in 1Q
2024 (Dry)
CAP3Q23-PIW-11-
073123
Sample Date:
31-Jul-23
CAP1Q24-PIW-11-
020124
Sample Date:
1-Feb-24
Hf o Dimer Acid
24,000
--
8,400
9 500
12,000 J
46,000
6 600
8,300
3,800
--
3 500
1 400
PFMOAA
44,000
--
150,000 J
100,000
72,000 J
190,000
51,000 J
31,000
3 700
--
1,600
2,100
PF02HxA
28,000
--
61,000 J
29,000
34,000 J
110 000
19,000
14 000
4,400
--
2,600
1,000
PF030A
7,000
--
5,500
4,100
14,000
43,000
5 800
4,800
800
--
420
230
PF04DA
2,200
--
200
180
2,300
5,300
1,500
930
340
--
46
<50
PF05DA
690
--
<2.0
<130
<2.0
<130
4
<130
6.8
--
<100
<130
PMPA
32,000
--
16,000
11,000
8 600
19,000
6,600
6,700
4 500
--
3,100
1 400
PEPA
15,000
--
3 400
2 300
2 500
5,500
2,400
2,300
2 100
--
1,000
320
PS Acid
40
--
<2.0
<50 UJ
<2.0
<50
<2.0
<50
<2.0
--
<40
<50 UJ
Hydro -PS Acid
140
--
25
<55
350
1,200
210
200
67
--
<44
<55
R-PSDA
1,600 J
--
820 J
730 J
1,000 J
2,600 J
690 J
610 J
160 J
--
240 J
230 J
Hydrolyzed PSDA
1,700 J
--
4,100 J
4,300 J
2,600 J
5 300 J
2 700 J
2,300 J
<2.0
--
1,500 J
2,800 J
R-PSDCA
<140
--
<3.0
<180
25
<180
9.9
<180
<3.0
--
<140
<180
NVHOS, Acid Form
640
--
1,800
1300
1 100
2,500
390
390
62
--
<130
<160
EVE Acid
<40
--
<2.0
<50 UJ
<2.0
<50
<2.0
<50
<2.0
--
<40
<50 UJ
Hydro -EVE Acid
190
--
54
40
1,200
3,500
910
640
14
--
<24
<30
R-EVE
1,300 J
--
230 J
360 J
1,300 J
2 300 J
250 J
400 J
230 J
--
130 J
77 J
Perfluoro 2-ethox ethane sulfonic Acid
<29
--
7.1
<36
13
<36
3.9
<36
<2.0
--
<29
<36
PFECA B
<62
--
<2.0
<78
<2.0
<78
<2.0
<78
<2.0
<62
<78
PFECA-G
<29
--
<2.0
<36
<2.0
<36
<2.0
<36
<2.0
<29
<36
PFPrA
44,000
64,000 J
54,000
57,000
120,000
26,000
18,000
5,300
3,400
2,200
Total Table 3+ (17 compounds) 2,3
154,000
-
246,000
157,000
148,000
426,000
94,400
69,300
19,800
12,300
6,450
Total Table 3+ (18 compounds) 2,4
198,000
-
310,000
211,000
205,000
546,000
120,000
87,300
25,100
15,700
8,650
Total Table 3+ (21 compounds) 2,5
203,000
-
316,000
217,000
210,000
556,000
1 124,000
90,600
1 25,500
17,500
11,800
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the 3Q 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
2 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to three significant figures.
3 - Total Table 3+ (17 compounds) does not include R-PSDA, Hydrolyzed PSDA, R-EVE, and PFPrA.
4 - Total Table 3+ (18 compounds) does not include R-PSDA, Hydrolyzed PSDA, and R-EVE.
5 - Total Table 3+ (21 compounds) is the sum of all Table 3+ PFAS compounds.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 11 of 24 June 2024
Table 6-2
PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537 MOD SOP COMPOUNDS
LIST I
(ng/L)
Performance Monitoring Plan Sampling Program (Semi -Annually)
Corrective Action Plan Sampling Program (Annually)
PIW-15
PW-10RR
PW-11
PIW-12
PIW-13
PIW-14
CAP3Q23-PIW-15-
072523
Sample Date:
25-Jul-23
CAP1Q24-PIW-15-
020524
Sample Date:
5-Feb-24
CAP3Q23-PW-IORR-
080323
Sample Date:
3-Aug-23
CAP1Q24-PW-IORR-
013124
Sample Date:
31-Jan-24
CAP3Q23-PW-11-070723
Sample Date:
7-Jul-23
CAP1Q24-PW-11-013124
Sample Date:
31-Jan-24
CAP3Q23-PIW-12-
072423
Sample Date:
24-Jul-23
CAP3Q23-PIW-13-
072423
Sample Date:
24-Jul-23
CAP3Q23-PIW-14-
072423
Sample Date:
24-Jul-23
Hf o Dimer Acid
7,800
8 200
6,700
4 000
6,900
6 800
1,800
3100
6,200
PFMOAA
8,700
9,200
93,000
59,000
54,000 J
29,000
490
520
1,000
PF02HxA
7,000
6 800
26,000
14,000
28,000
11,000
1,200
2,100
3,800
PF030A
1,200
1300
1300
410
7,300
5 000
190
250
520
PF04DA
65
100
<40
<50
4,500
4 200
41
<40
160
PF05DA
<100
<130
<100
<130
1,600
1300
<100
<100
<100
PMPA
8,400
6 300
4,400
2 200
7,800
3 000
2,300
4 200
5,000
PEPA
2,400
1,900
590
150
2,200
910
640
1,100
1,600
PS Acid
<40
<50 UJ
<40
<50 UJ
1,400
97 J
<40
<40
<40
Hydro -PS Acid
<44
<55
<44
<55
840
440
<44
<44
<44
R-PSDA
250 J
190 J
180 J
84 J
850 J
300 J
130 J
260 J
310 J
Hydrolyzed PSDA
<27
<34
220 J
84 J
7,900 J
850 J
<27
<27
<27
R-PSDCA
<140
<180
<140
<180
24
<180
<140
<140
<140
NVHOS, Acid Form
130
<160
850
510
850
510
<130
<130
<130
EVE Acid
<40
<50 UJ
<40
<50 UJ
47
<50 UJ
<40
<40
<40
Hydro -EVE Acid
<24
<30
<24
<30
620
240
<24
<24
<24
R-EVE
200 J
130 J
240 J
120 J
360 J
110 J
130 J
260 J
230 J
Perfluoro 2-ethox ethane sulfonic Acid
<29
<36
<29
<36
<2.0
<36
<29
<29
<29
PFECA B
<62
<78
<62
<78
<2.0
<78
<62
<62
<62
PFECA-G
<29
<36
<29
<36
<2.0
<36
<29
<29
<29
PFPrA
14,000
10,000
60,000
41,000
25,000
14,000
2,800
4,600
6,700
Total Table 3+ (17 compounds) 2,3
35,700
33,800
133,000
80,300
116,000
62,500
6,660
11,300
18,300
Total Table 3+ (18 compounds) 2,4
499700
43,800
193,000
121,000
141,000
769500
9,460
15,900
259000
Total Table 3+ (21 compounds) 2,5
50,100 in
44,100
193,000
122,000
150,000
779800
9,720
16,400
259500
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the 3Q 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
2 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to three significant figures.
3 - Total Table 3+ (17 compounds) does not include R-PSDA, Hydrolyzed PSDA, R-EVE, and PFPrA.
4 - Total Table 3+ (18 compounds) does not include R-PSDA, Hydrolyzed PSDA, and R-EVE.
5 - Total Table 3+ (21 compounds) is the sum of all Table 3+ PFAS compounds.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 12 of 24 June 2024
Table 6-2
PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537 MOD SOP COMP0l7NDs LIST'
(ng/L)
Mass Loading Model Sampling Program (Quarterly)
LTW-01
LTW-02
CAP1Q23-LTW-01-
021623
Sample Date:
CAP2Q23-LTW-01-
051723
Sample Date:
CAP3Q23-LTW-01-
071323
Sample Date:
CAP4Q23-LTW-01-
110323
Sample Date:
CAP1Q24-LTW-01-
011724
Sample Date:
CAP1Q23-LTW-02-
021623
Sample Date:
CAP2Q23-LTW-02-
051723
Sample Date:
CAP3Q23-LTW-02-
071223
Sample Date:
CAP4Q23-LTW-02-
110323
Sample Date:
CAP1Q24-LTW-02-
011724
Sample Date:
10:2 Fluorotelomer sulfonate
<2.0
<2.0 UJ
<2.0
<67
<84
<2.0
<2.0 UJ
<2.0
<67
<84
11Cl-PF3OUdS
<2.0
<2.0 UJ
<2.0
<32
<40
<2.0
<2.0 UJ
<2.0
<32
<40
11-1,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
<2.0
<2.0 UJ
<2.0
<46
<58
<2.0
<2.0 UJ
<2.0
<46
<58
1H, I H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
<2.0
<2.0 UJ
<2.0
<24
<30
<2.0
<2.0 UJ
<2.0
<24
<30
2-(N-ethyl perfluoro-l-octanesulfonamido)-ethanol
<2.0
<2.0 UJ
<2.0
<85
<110
<2.0
<2.0 UJ
<2.0
<85
<110
2-(N-methyl perfluoro-l-octanesulfonamido)-ethanol
<4.0
<4.0 UJ
<4.0
<140
<180
<4.0
<4.0 UJ
<4.0
<140
<180
6:2 Fluorotelomer sulfonate
<5.0
<5.0 UJ
<5.0
<250
<310
<5.0
<5.0 UJ
<5.0
<250
<310
9CI-PF30NS
<2.0
<2.0 UJ
<2.0
<24
<30
<2.0
<2.0 UJ
<2.0
<24
<30
DONA
<2.0
<2.0 UJ
<2.0
<40
<50
<2.0
<2.0 UJ
<2.0
<40
<50
N-EthylPerfluorooctane Sulfonamidoacetic Acid
<5.0
<5.0 UJ
<5.0
<130
<160
<5.0
<5.0 UJ
<5.0
<130
<160
N-ethylperfluoro- I -octanesulfonamide
<2.0
<2.0 UJ
<2.0
<87
<110
<2.0
<2.0 UJ
<2.0
<87
<110
N-methyl perfluoro- I -octanesulfonamide
<2.0
<2.0 UJ
<2.0
<43
<54
<2.0
<2.0 UJ
<2.0
<43
<54
N-MethylPerfluorooctane Sulfonamidoacetic Acid
<5.0
<5.0 UJ
<5.0
<120
<150
<5.0
<5.0 UJ
<5.0
<120
<150
Perfluorobutane Sulfonic Acid
4.2
4.7 J
3.6
<20
<25
<2.0
<2.0 UJ
<2.0
<20
<25
Perfluorobutanoic Acid
170
1101
120
<240
<300
30
61 J
86
<240
<300
Perfluorodecane Sulfonic Acid
<2.0
<2.0 UJ
<2.0
<32
<40
<2.0
<2.0 UJ
<2.0
<32
<40
Perfluorodecanoic Acid
<2.0
<2.0 UJ
<2.0
<31
<39
<2.0
<2.0 UJ
<2.0
<31
<39
Perfluorododecane Sulfonic Acid (PFDoS)
<2.0
<2.0 UJ
<2.0
<97
<120
<2.0
<2.0 UJ
<2.0
<97
<120
Perfluorododecanoic Acid
<2.0
<2.0 UJ
<2.0
<55
<69
<2.0
<2.0 UJ
<2.0
<55
<69
Perfluoroheptane Sulfonic Acid (PFHpS)
<2.0
<2.0 UJ
<2.0
<19
<24
<2.0
<2.0 UJ
<2.0
<19
<24
Perfluoroheptanoic Acid
46
48 J
44
47 J
40
4.7
Ili
11
<25
<31
Perfluorohexadecanoic Acid (PFHxDA)
<2.0
<2.0 UJ
<2.0
<89
<110
<2.0
<2.0 UJ
<2.0
<89
<110
Perfluorohexane Sulfonic Acid
6
6.3 J
5.2
<57
<71
<2.0
<2.0 UJ
<2.0
<57
<71
Perfluorohexanoic Acid
22
23 J
23
<58
<73
3.3
8.4 J
11
<58
<73
Perfluorononanesulfonic Acid
<2.0
<2.0 UJ
<2.0
<37
<46
<2.0
<2.0 UJ
<2.0
<37
<46
Perfluorononanoic Acid
<2.0
2.3 J
<2.0
<27
<34
<2.0
<2.0 UJ
<2.0
<27
<34
Perfluorooctadecanoic Acid
<2.0
<2.0 UJ
<2.0
<94
<120
<2.0
<2.0 UJ
<2.0
<94
<120
Perfluorooctane Sulfonamide
<2.0
<2.0 UJ
<2.0
<98
<120
<2.0
<2.0 UJ
<2.0
<98
<120
Perfluoropentane Sulfonic Acid (PFPeS)
<2.0
<2.0 UJ
<2.0
<30
<38
<2.0
<2.0 UJ
<2.0
<30
<38
Perfluoropentanoic Acid
320
250 J
260
330
220
99
190 J
250
300
320
Perfluorotetradecanoic Acid
<2.0
<2.0 UJ
<2.0
<73
<91
<2.0
<2.0 UJ
<2.0
<73
<91
Perfluorotridecanoic Acid
<2.0
<2.0 UJ
<2.0
<130
<160
<2.0
<2.0 UJ
<2.0
<130
<160
Perfluoroundecanoic Acid
<2.0
<2.0 UJ
<2.0
<110
<140
<2.0
<2.0 UJ
<2.0
<110
<140
PFOA
41
49 J
39
<85
<110
<2.0
<2.0 UJ
<2.0
<85
<110
PFOS
9.9 J
22 J
Ili
<54
<68
<2.0
<2.0 UJ
<2.0
<54
<68
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the 3Q 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 13 of 24 June 2024
Table 6-2
PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537 MOD SOP COMP017NDs LIST'
(ng/L)
Mass Loading Model Sampling Program (Quarterly)
LTW-03
LTW-04
CAP1Q23-LTW-03-
022123
Sample Date:
CAP2Q23-LTW-03-
052323
Sample Date:
CAP3Q23-LTW-03-
071223
Sample Date:
CAP4Q23-LTW-03-
111323
Sample Date:
CAP1Q24-LTW-03-
013124
Sample Date:
CAP1Q23-LTW-04-
021723
Sample Date:
CAP2Q23-LTW-04-
052323
Sample Date:
CAP3Q23-LTW-04-
071123
Sample Date:
CAP4Q23-LTW-04-
110223
Sample Date:
CAP1Q24-LTW-04-
011624
Sample Date:
10:2 Fluorotelomer sulfonate
<2.0
<2.0
<2.0
<2.0
<84
<2.0
<2.0
<2.0
<67
<84
11C1-PF3OUdS
<2.0
<2.0
<2.0
<2.0
<40
<2.0
<2.0
<2.0
<32
<40
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
<2.0
<2.0
<2.0
<2.0
<58
<2.0
<2.0
<2.0
<46
<58
1H,1H,2H,2H-perfluorohexanesulfonate(4:2FTS)
<2.0
<2.0
<2.0
<2.0
<30
<2.0
<2.0
<2.0
<24
<30
2-(N-ethyl perfluoro-l-octanesulfonamido)-ethanol
<2.0
<2.0
<2.0
<2.0
<110
<2.0
<2.0
<2.0
<85
<110
2-(N-methyl perfluoro-l-octanesulfonamido)-ethanol
<4.0
<4.0
<4.0
<4.0
<180
<4.0
<4.0
<4.0
<140
<180
6:2 Fluorotelomer sulfonate
<5.0
<5.0
<5.0
<5.0
<310
<5.0
<5.0
<5.0
<250
<310
9C1-PF30NS
<2.0
<2.0
<2.0
<2.0
<30
<2.0
<2.0
<2.0
<24
<30
DONA
<2.0
<2.0
<2.0
<2.0
<50
<2.0
<2.0
<2.0
<40
<50
N-Ethyl Perfluorooctane Sulfonamidoacetic Acid
<5.0
<5.0
<5.0
<5.0
<160
<5.0
<5.0
<5.0
<130
<160
N-ethylperfluoro-l-octanesulfonamide
<2.0
<2.0
<2.0
<2.0
<110
<2.0
<2.0
<2.0
<87
<110
N-methyl perfluoro-l-octanesulfonamide
<2.0
<2.0
<2.0
<2.0
<54
<2.0
<2.0
<2.0
<43
<54
N-Methyl Perfluorooctane Sulfonamidoacetic Acid
<5.0
<5.0
<5.0
<5.0
<150
<5.0
<5.0
<5.0
<120
<150
Perfluorobutane Sulfonic Acid
<2.0
<2.0
<2.0
<2.0
<25
<2.0
2.2
<2.0
<20
<25
Perfluorobutanoic Acid
130
120
130
120
<300
310
230
290
330
<300
Perfluorodecane Sulfonic Acid
<2.0
<2.0
<2.0
<2.0
<40
<2.0
<2.0
<2.0
<32
<40
Perfluorodecanoic Acid
<2.0
<2.0
<2.0
<2.0
<39
<2.0
<2.0
<2.0
<31
<39
Perfluorododecane Sulfonic Acid (PFDoS)
<2.0
<2.0
<2.0
<2.0
<120
<2.0
<2.0
<2.0
<97
<120
Perfluorododecanoic Acid
<2.0
<2.0
<2.0
<2.0
<69
<2.0
<2.0
<2.0
<55
<69
Perfluoroheptane Sulfonic Acid (PFHpS)
<2.0
<2.0
<2.0
<2.0
<24
<2.0
<2.0
<2.0
<19
<24
Perfluoroheptanoic Acid
26
28
25
24
<31
66
52
60
60
68
Perfluorohexadecanoic Acid (PFHxDA)
<2.0
<2.0
<2.0
<2.0
<110
<2.0
<2.0
<2.0
<89
<110
Perfluorohexane Sulfonic Acid
<2.0
<2.0
<2.0
<2.0
<71
<2.0
3.3
<2.0
<57
<71
Perfluorohexanoic Acid
16
17
16
17
<73
35
33
34
<58
<73
Perfluorononanesulfonic Acid
<2.0
<2.0
<2.0
<2.0
<46
<2.0
<2.0
<2.0
<37
<46
Perfluorononanoic Acid
<2.0
<2.0
<2.0
<2.0
<34
<2.0
<2.0
<2.0
<27
<34
Perfluorooctadecanoic Acid
<2.0
<2.0
<2.0
<120 UJ
<120
<2.0
<2.0
<2.0
<94
<120
Perfluorooctane Sulfonamide
<2.0
<2.0
<2.0
<2.0
<120
<2.0
<2.0
<2.0
<98
<120
Perfluoropentane Sulfonic Acid (PFPeS)
<2.0
<2.0
<2.0
<2.0
<38
<2.0
<2.0
<2.0
<30
<38
Perfluoropentanoic Acid
600
690
750
610
560 J
1,200
1,100
1,400
1,200
1,100
Perfluorotetradecanoic Acid
<2.0
<2.0
<2.0
<2.0
<91
<2.0
<2.0
<2.0
<73
<91
Perfluorotridecanoic Acid
<2.0
<2.0
<2.0
<2.0
<160
<2.0
<2.0
<2.0
<130
<160
Perfluoroundecanoic Acid
<2.0
<2.0
<2.0
<2.0
<140
<2.0
<2.0
<2.0
<110
<140
PFOA
<2.0
<2.0
<2.0
<2.0
<110
10
11
10
<85
<110
PFOS
<2.0
<2.0
<2.0
<2.0
<68
<2.0
<2.0
<2.0
<54
<68
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the 3Q 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 14 of 24 June 2024
Table 6-2
PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537 MOD SOP COMPOl7NDs LIST'
(ng/L)
Mass Loading Model Sampling Program (Quarterly)
LTW-05
OW-28
CAP1Q23-LTW-05-
021523
Sample Date:
CAP2Q23-LTW-05-
052223
Sample Date:
CAP3Q23-LTW-05-
071123
Sample Date:
CAP4Q23-LTW-05-
110223
Sample Date:
CAP1Q24-LTW-05-
011524
Sample Date:
CAP1Q23-OW-28-
022023
Sample Date:
CAP2Q23-OW-28-
052523
Sample Date:
CAP3Q23-OW-28-
071123
Sample Date:
CAP4Q23-OW-28-
110223
Sample Date:
CAP4Q23-OW-28-
011824
Sample Date:
10:2 Fluorotelomer sulfonate
<2.0
<2.0
<2.0
<67
<84
<2.0
<2.0
<2.0
<67
<84
11C1-PF3OUdS
<2.0
<2.0
<2.0
<32
<40
<2.0
<2.0
<2.0
<32
<40
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
<2.0
<2.0
<2.0
<46
<58
<2.0
<2.0
<2.0
<46
<58
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
<2.0
<2.0
<2.0
<24
<30
<2.0
<2.0
<2.0
<24
<30
2-(N-ethyl perfluoro-l-octanesulfonamido)-ethanol
<2.0
<2.0
<2.0
<85
<110
<2.0
<2.0
<2.0
<85
<110
2-(N-methyl perfluoro-l-octanesulfonamido)-ethanol
<4.0
<4.0
<4.0
<140
<180
<4.0
<4.0
<4.0
<140
<180
6:2 Fluorotelomer sulfonate
<5.0
<5.0
<5.0
<250
<310
<5.0
<5.0
<5.0
<250
880
9C1-PF30NS
<2.0
<2.0
<2.0
<24
<30
<2.0
<2.0
<2.0
<24
<30
DONA
<2.0
<2.0
<2.0
<40
<50
<2.0
<2.0
<2.0
<40
<50
N-Ethyl Perfluorooctane Sulfonamidoacetic Acid
<5.0
<5.0
<5.0
<130
<160
<5.0
<5.0
<5.0
<130
<160
N-ethylperfluoro-l-octanesulfonamide
<2.0
<2.0
<2.0
<87
<110
<2.0
<2.0
<2.0
<87
<110
N-methyl perfluoro-l-octanesulfonamide
<2.0
<2.0
<2.0
<43
<54
<2.0
<2.0
<2.0
<43
<54
N-Methyl Perfluorooctane Sulfonamidoacetic Acid
<5.0
<5.0
<5.0
<120
<150
<5.0
<5.0
<5.0
<120
<150
Perfluorobutane Sulfonic Acid
<2.0
<2.0
<2.0
<20
<25
<2.0
2
<2.0
<20
<25
Perfluorobutanoic Acid
230
170
170
270
420
51
51
46
<240
<300
Perfluorodecane Sulfonic Acid
<2.0
<2.0
<2.0
<32
<40
<2.0
<2.0
<2.0
<32
<40
Perfluorodecanoic Acid
<2.0
<2.0
<2.0
<31
<39
<2.0
<2.0
<2.0
<31
<39
Perfluorododecane Sulfonic Acid (PFDoS)
<2.0
<2.0
<2.0
<97
<120
<2.0
<2.0
<2.0
<97
<120
Perfluorododecanoic Acid
<2.0
<2.0
<2.0
<55
<69
<2.0
<2.0
<2.0
<55
<69
Perfluoroheptane Sulfonic Acid (PFHpS)
<2.0
<2.0
<2.0
<19
<24
<2.0
<2.0
<2.0
<19
<24
Perfluoroheptanoic Acid
210
200
210
250
310
7.2
7.3
6.5
<25
<31
Perfluorohexadecanoic Acid (PFHxDA)
<2.0
<2.0
<2.0
<89
<110
<2.0
<2.0
<2.0
<89
<110
Perfluorohexane Sulfonic Acid
<2.0
<2.0
<2.0
<57
<71
<2.0
<2.0
<2.0
<57
<71
Perfluorohexanoic Acid
38
52
43
66
99
9.9
12
9.1
<58
<73
Perfluorononanesulfonic Acid
<2.0
<2.0
<2.0
<37
<46
<2.0
<2.0
<2.0
<37
<46
Perfluorononanoic Acid
<2.0
<2.0
<2.0
<27
<34
<2.0
<2.0
<2.0
<27
<34
Perfluorooctadecanoic Acid
<2.0
<2.0
<2.0
<94
<120
<2.0
<2.0
<2.0
<94
<120
Perfluorooctane Sulfonamide
<2.0
<2.0
<2.0
<98
<120
<2.0
<2.0
<2.0
<98
<120
Perfluoropentane Sulfonic Acid (PFPeS)
<2.0
<2.0
<2.0
<30
<38
<2.0
<2.0
<2.0
<30
<38
Perfluoropentanoic Acid
1,300
1,700
1,600
2,300
2,700
68
75
73
49
69
Perfluorotetradecanoic Acid
<2.0
<2.0
<2.0
<73
<91
<2.0
<2.0
<2.0
<73
<91
Perfluorotridecanoic Acid
<2.0
<2.0
<2.0
<130
<160
<2.0
<2.0
<2.0
<130
<160
Perfluoroundecanoic Acid
<2.0
<2.0
<2.0
<110
<140
<2.0
<2.0
<2.0
<110
<140
PFOA
4.1
4.1
2.1
<85
<110
4.3
4
3.3
<85
<110
PFOS
<2.0
<2.0
<2.0
<54
<68
<2.0
<2.0
<2.0
<54
<68
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the 3Q 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 15 of 24 June 2024
Table 6-2
PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537 MOD SOP COMP0I7NDs LIST'
(ng/L)
Mass Loading Model Sampling Program (Quarterly)
OW-33
PIW-11)
CAP1Q23-OW-33-
021423
Sample Date:
CAP2Q23-OW-33-
051823
Sample Date:
CAP3Q23-OW-33-
071223
Sample Date:
CAP4Q23-OW-33-
110223
Sample Date:
CAP1Q24-OW-33-
013024
Sample Date:
CAP1Q23-PIW-1D-
021623
Sample Date:
CAP2Q23-PIW-1D-
052323
Sample Date:
CAP3Q23-PIW-1D-
080223
Sample Date:
CAP4Q23-PIW-1D-
110723
Sample Date:
CAP1Q24-PIW-1D-
012224
Sample Date:
10:2 Fluorotelomer sulfonate
<2.0
<2.0 UJ
<2.0
<67
<84
<2.0
<2.0
<67
<67
<84
11C1-PF3OUdS
<2.0
<2.0 UJ
<2.0
<32
<40
<2.0
<2.0
<32
<32
<40
IH,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
<2.0
<2.0 UJ
<2.0
<46
<58
<2.0
<2.0
<46
<46
<58
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
<2.0
<2.0 UJ
<2.0
<24
<30
<2.0
<2.0
<24 UJ
<24
<30
2-(N-ethyl perfluoro-l-octanesulfonamido)-ethanol
<2.0
<2.0 UJ
<2.0
<85
<110
<2.0
<2.0
<85
<85
<110
2-(N-methyl perfluoro-l-octanesulfonamido)-ethanol
<4.0
<4.0 UJ
<4.0
<140
<180
<4.0
<4.0
<140
<140
<180
6:2 Fluorotelomer sulfonate
<5.0
<5.0 UJ
<5.0
<250
<310
<5.0
<5.0
<250
<250
1,200
9C1-PF30NS
<2.0
<2.0 UJ
<2.0
<24
<30
<2.0
<2.0
<24
<24
<30
DONA
<2.0
<2.0 UJ
<2.0
<40
<50
<2.0
<2.0
<40
<40
<50
N-Ethyl Perfluorooctane Sulfonamidoacetic Acid
<5.0
<5.0 UJ
<5.0
<130
<160
<5.0
<5.0
<130
<130
<160
N-ethylperfluoro-l-octanesulfonamide
<2.0
<2.0 UJ
<2.0
<87
<110
<2.0
<2.0
<87 UJ
<87
<110
N-methyl perfluoro-l-octanesulfonamide
<2.0
<2.0 UJ
<2.0
<43
<54
<2.0
<2.0
<43
<43
<54
N-Methyl Perfluorooctane Sulfonamidoacetic Acid
<5.0
<5.0 UJ
<5.0
<120
<150
<5.0
<5.0
<120
<120
<150
Perfluorobutane Sulfonic Acid
<2.0
<2.0 UJ
<2.0
<20
<25
<2.0
<2.0
<20
<20
<25
Perfluorobutanoic Acid
45
60 J
62
<240
<300
83
59
<240
<240
<300
Perfluorodecane Sulfonic Acid
<2.0
<2.0 UJ
<2.0
<32
<40
<2.0
<2.0
<32
<32
<40
Perfluorodecanoic Acid
<2.0
<2.0 UJ
<2.0
<31
<39
<2.0
<2.0
<31
<31
<39
Perfluorododecane Sulfonic Acid (PFDoS)
<2.0
<2.0 UJ
<2.0
<97
<120
<2.0
<2.0
<97
<97
<120
Perfluorododecanoic Acid
<2.0
<2.0 UJ
<2.0
<55
<69
<2.0
<2.0
<55
<55
<69
Perfluoroheptane Sulfonic Acid (PFHpS)
<2.0
<2.0 UJ
<2.0
<19
<24
<2.0
<2.0
<19
<19
<24
Perfluoroheptanoic Acid
5.6
7.6 J
7.1
<25
<31
16
19
<25
<25
<31
Perfluorohexadecanoic Acid (PFHxDA)
<2.0
<2.0 UJ
<2.0
<89
<110
<2.0
<2.0
<89
<89
<110
Perfluorohexane Sulfonic Acid
<2.0
<2.0 UJ
<2.0
<57
<71
<2.0
<2.0
<57
<57
<71
Perfluorohexanoic Acid
7.8
10.1
10
<58
<73
9.5
11
<58
<58
<73
Perfluorononanesulfonic Acid
<2.0
<2.0 UJ
<2.0
<37
<46
<2.0
<2.0
<37
<37
<46
Perfluorononanoic Acid
<2.0
<2.0 UJ
<2.0
<27
<34
<2.0
<2.0
<27
<27
<34
Perfluorooctadecanoic Acid
<2.0
<2.0 UJ
<2.0
<94 UJ
<120
<2.0
<2.0
<94
<94
<120
Perfluorooctane Sulfonamide
<2.0
<2.0 UJ
<2.0
<98
<120
<2.0
<2.0
<98
<98
<120
Perfluoropentane Sulfonic Acid (PFPeS)
<2.0
<2.0 UJ
<2.0
<30
<38
<2.0
<2.0
<30
<30
<38
Perfluoropentanoic Acid
93
120 J
130
14
1120 J
150
140
160
150
150
Perfluorotetradecanoic Acid
<2.0
<2.0 UJ
<2.0
<73
<91
<2.0
<2.0
<73
<73
<91
Perfluorotridecanoic Acid
<2.0
<2.0 UJ
<2.0
<130
<160
<2.0
<2.0
<130
<130
<160
Perfluoroundecanoic Acid
<2.0
<2.0 UJ
<2.0
<110
<140
<2.0
<2.0
<110
<110
<140
PFOA
<2.0
2.2 J
<2.0
<85
<110
18
19
<85
<85
<110
PFOS
<2.0
<2.0 UJ
<2.0
<54
<68
<2.0
<2.0
<54
<54
<68
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the 3Q 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 16 of 24 June 2024
Table 6-2
PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537MOD SOP COMPOUNDS LIST'
(ng/L)
Mass Loading Model Sampling Program (Quarterly)
PIW-lS
PIW-3D
CAP1Q23-PIW-1S-
021623
Sample Date:
Not Sampled in 2Q 2023
(Dry)
Not Sampled in 3Q 2023
(Dry)
Not Sampled in 4Q 2023
(Dry)
CAP1Q24-PIW-1S-
011624
Sample Date:
CAP1Q23-PIW-3D-
021623
Sample Date:
CAP2Q23-PIW-3D-
051723
Sample Date:
CAP3Q23-PIW-3D-
071323
Sample Date:
CAP4Q23-PIW-3D-
110323
Sample Date:
CAP1Q24-PIW-3D-
011824
Sample Date:
10:2 Fluorotelomer sulfonate
<2.0
<84
<2.0
<2.0 UJ
<2.0
<67
<84
11C1-PF3OUdS
<2.0
<40
<2.0
<2.0 UJ
<2.0
<32
<40
III, 1H,2H,2H-perfluorodecanesulfonate(8:2FTS)
<2.0
<58
<2.0
<2.0 UJ
<2.0
<46
<58
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
<2.0
<30
<2.0
<2.0 UJ
<2.0
<24
<30
2-(N-ethyl perfluoro-l-octanesulfonamido)-ethanol
<2.0
<110
<2.0
<2.0 UJ
<2.0
<85
<110
2-(N-methyl perfluoro-l-octanesulfonamido)-ethanol
<4.0
<180
<4.0
<4.0 UJ
<4.0
<140
<180
6:2 Fluorotelomer sulfonate
<5.0
<310
<5.0
<5.0 UJ
<5.0
<250
<310
9C1-PF30NS
<2.0
<30
<2.0
<2.0 UJ
<2.0
<24
<30
DONA
<2.0
<50
<2.0
<2.0 UJ
<2.0
<40
<50
N-Ethyl Perfluorooctane Sulfonamidoacetic Acid
<5.0
<160
<5.0
<5.0 UJ
<5.0
<130
<160
N-ethylperfluoro-l-octanesulfonamide
<2.0
<110
<2.0
<2.0 UJ
<2.0
<87
<110
N-methyl perfluoro- I -octanesulfonamide
<2.0
<54
<2.0
<2.0 UJ
<2.0
<43
<54
N-Methyl Perfluorooctane Sulfonamidoacetic Acid
<5.0
<150
<5.0
<5.0 UJ
<5.0
<120
<150
Perfluorobutane Sulfonic Acid
<2.0
<25
2.2
2.1 J
2.3
<20
<25
Perfluorobutanoic Acid
51
<300
110
73 J
79
<240
<300
Perfluorodecane Sulfonic Acid
<2.0
<40
<2.0
<2.0 UJ
<2.0
<32
<40
Perfluorodecanoic Acid
<2.0
<39
<2.0
<2.0 UJ
<2.0
<31
<39
Perfluorododecane Sulfonic Acid (PFDoS)
<2.0
<120
<2.0
<2.0 UJ
<2.0
<97
<120
Perfluorododecanoic Acid
<2.0
<69
<2.0
<2.0 UJ
<2.0
<55
<69
Perfluoroheptane Sulfonic Acid (PFHpS)
<2.0
<24
<2.0
<2.0 UJ
<2.0
<19
<24
Perfluoroheptanoic Acid
18
<31
32
32 J
33
49
44
Perfluorohexadecanoic Acid (PFHxDA)
<2.0
<110
<2.0
<2.0 UJ
<2.0
<89
<110
Perfluorohexane Sulfonic Acid
8.6
<71
3.4
3.5 J
3.7
<57
<71
Perfluorohexanoic Acid
7.7
<73
15
14 J
16
<58
<73
Perfluorononanesulfonic Acid
<2.0
<46
<2.0
<2.0 UJ
<2.0
<37
<46
Perfluorononanoic Acid
4.1
<34
5.2
4.8 J
5
<27
<34
Perfluorooctadecanoic Acid
<2.0
<120
<2.0
<2.0 UJ
<2.0
<94
<120
Perfluorooctane Sulfonamide
<2.0
<120
<2.0
<2.0 UJ
<2.0
<98
<120
Perfluoropentane Sulfonic Acid (PFPeS)
<2.0
<38
<2.0
<2.0 UJ
<2.0
<30
<38
Perfluoropentanoic Acid
78
<61
150
150 J
150
190
250
Perfluorotetradecanoic Acid
<2.0
<91
<2.0
<2.0 UJ
<2.0
<73
<91
Perfluorotridecanoic Acid
<2.0
<160
<2.0
<2.0 UJ
<2.0
<130
<160
Perfluoroundecanoic Acid
<2.0
<140
<2.0
<2.0 UJ
<2.0
<110
<140
PFOA
69
<110
44
43 J
42
<85
<110
PFOS
22
<68
15
14 J
14
<54
<68
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the 3Q 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 17 of 24 June 2024
Table 6-2
PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537 MOD SOP COMP0l7NDs LIST'
(ng/L)
Mass Loading Model Sampling Program (Quarterly)
PIW-71)
PIW-7S
CAP1Q23-PIW-7D-
021523
Sample Date:
CAP2Q23-PIW-7D-
052223
Sample Date:
CAP3Q23-PIW-7D-
071123
Sample Date:
CAP4Q23-PIW-7D-
110223
Sample Date:
CAP1Q24-PIW-7D-
011524
Sample Date:
CAP1Q23-PIW-7S-
021523
Sample Date:
CAP2Q23-PIW-7S-
052223
Sample Date:
CAP3Q23-PIW-7S-
071123
Sample Date:
CAP4Q23-PIW-7S-
110223
Sample Date:
CAP1Q24-PIW-7S-
011524
Sample Date:
10:2 Fluorotelomer sulfonate
<2.0
<2.0
<2.0
<67
<84
<2.0
<2.0
<2.0
<67
<84
11C1-PF30UdS
<2.0
<2.0
<2.0
<32
<40
<2.0
<2.0
<2.0
<32
<40
11-1,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
<2.0
<2.0
<2.0
<46
<58
<2.0
<2.0
<2.0
<46
<58
11-1,11-1,21-1,21-1-perfluorohexanesulfonate (4:2 FTS)
<2.0
<2.0
<2.0
<24
<30
<2.0
<2.0
<2.0
<24
<30
2-(N-ethylperfluoro-l-octanesulfonamido)-ethanol
<2.0
<2.0
<2.0
<85
<110
<2.0
<2.0
<2.0
<85
<110
2-(N-methyl perfluoro-l-octanesulfonamido)-ethanol
<4.0
<4.0
<4.0
<140
<180
<4.0
<4.0
<4.0
<140
<180
6:2 Fluorotelomer sulfonate
<5.0
<5.0
<5.0
<250
<310
<5.0
<5.0
<5.0
<250
<310
9C1-PF30NS
<2.0
<2.0
<2.0
<24
<30
<2.0
<2.0
<2.0
<24
<30
DONA
<2.0
<2.0
<2.0
<40
<50
<2.0
<2.0
<2.0
<40
<50
N-Ethyl Perfluorooctane Sulfonamidoacetic Acid
<5.0
<5.0
<5.0
<130
<160
<5.0
<5.0
<5.0
<130
<160
N-ethylperfluoro-l-octanesulfonamide
<2.0
<2.0
<2.0
<87
<110
<2.0
<2.0
<2.0
<87
<110
N-methyl perfluoro-I-octanesulfonamide
<2.0
<2.0
<2.0
<43
<54
<2.0
<2.0
<2.0
<43
<54
N-Methyl Perfluorooctane Sulfonamidoacetic Acid
<5.0
<5.0
<5.0
<120
<150
<5.0
<5.0
<5.0
<120
<150
Perfluorobutane Sulfonic Acid
<2.0
<2.0
<2.0
<20
<25
3.6
2.8
2.5
<20
<25
Perfluorobutanoic Acid
290
150
160
<240
<300
210
120
100
<240
<300
Perfluorodecane Sulfonic Acid
<2.0
<2.0
<2.0
<32
<40
<2.0
<2.0
<2.0
<32
<40
Perfluorodecanoic Acid
<2.0
<2.0
<2.0
<31
<39
<2.0
<2.0
<2.0
<31
<39
Perfluorododecane Sulfonic Acid (PFDoS)
<2.0
<2.0
<2.0
<97
<120
<2.0
<2.0
<2.0
<97
<120
Perfluorododecanoic Acid
<2.0
<2.0
<2.0
<55
<69
<2.0
<2.0
<2.0
<55
<69
Perfluoroheptane Sulfonic Acid (PFHpS)
<2.0
<2.0
<2.0
<19
<24
<2.0
<2.0
<2.0
<19
<24
Perfluoroheptanoic Acid
140
81
85
97
100
71
52
41
61
56
Perfluorohexadecanoic Acid (PFHxDA)
<2.0
<2.0
<2.0
<89
<110
<2.0
<2.0
<2.0
<89
<110
Perfluorohexane Sulfonic Acid
<2.0
<2.0
<2.0
<57
<71
4.1
3.5
3
<57
<71
Perfluorohexanoic Acid
49
33
30
<58
<73
30
26
19
<58
<73
Perfluorononanesulfonic Acid
<2.0
<2.0
<2.0
<37
<46
<2.0
<2.0
<2.0
<37
<46
Perfluorononanoic Acid
<2.0
<2.0
<2.0
<27
<34
<2.0
<2.0
<2.0
<27
<34
Perfluorooctadecanoic Acid
<2.0
<2.0
<2.0
<94
<120
<2.0
<2.0
<2.0
<94
<120
Perfluorooctane Sulfonamide
<2.0
<2.0
<2.0
<98
<120
<2.0
<2.0
<2.0
<98
<120
Perfluoropentane Sulfonic Acid (PFPeS)
<2.0
<2.0
<2.0
<30
<38
<2.0
<2.0
<2.0
<30
<38
Perfluoropentanoic Acid
1,500
1,300
1,400
1,500
1,300
630
530
470
620
580
Perfluorotetradecanoic Acid
<2.0
<2.0
<2.0
<73
<91
<2.0
<2.0
<2.0
<73
<91
Perfluorotridecanoic Acid
<2.0
<2.0
<2.0
<130
<160
<2.0
<2.0
<2.0
<130
<160
Perfluoroundecanoic Acid
<2.0
<2.0
<2.0
<110
<140
<2.0
<2.0
<2.0
<110
<140
PFOA
4.5
2.9
2
<85
<110
17
14
9.6
<85
<110
PFOS
<2.0
<2.0
<2.0
<54
<68
6.4 J
5.4 .J
<2.0
<54
<68
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the 3Q 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 18 of 24 June 2024
Table 6-2
PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537 MOD SOP COMPOUNDS LIST'
(ng/L)
Mass Loading Model Sampling Program (Quarterly)
PW-04
PZ-22
CAP1Q23-PW-04-
022323
Sample Date:
CAP2Q23-PW-04-
052523
Sample Date:
CAP3Q23-PW-04-
072823
Sample Date:
CAP4Q23-PW-04-
110923
Sample Date:
CAP1Q24-PW-04-
011724
Sample Date:
CAP1Q23-PZ-22-022023
Sample Date:
CAP2Q23-PZ-22-052323
Sample Date:
CAP3Q-PZ-22-071123
Sample Date:
CAP4Q23-PZ-22-110223
Sample Date:
CAP1Q24-PZ-22-011624
Sample Date:
10:2 Fluorotelomer sulfonate
<2.0
<2.0
<67
<67
<84
<2.0
<2.0
<2.0
<67
<84
11C1-PF3OUdS
<2.0
<2.0
<32
<32
<40
<2.0
<2.0
<2.0
<32
<40
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
<2.0
<2.0
<46
<46
<58
<2.0
<2.0
<2.0
<46
<58
1H,1H,2H,2H-perfluorohexanesulfonate(4:2FTS)
<2.0
<2.0
<24
<24
<30
<2.0
<2.0
<2.0
<24
<30
2-(N-ethyl perfluoro-l-octanesulfonamido)-ethanol
<2.0
<2.0
<85
<85
<110
<2.0
<2.0
<2.0
<85
<110
2-(N-methyl perfluoro-l-octanesulfonamido)-ethanol
<4.0
<4.0
<140
<140
<180
<4.0
<4.0
<4.0
<140
<180
6:2 Fluorotelomer sulfonate
<5.0
<5.0
<250
<250
<310
<5.0
<5.0
<5.0
<250
<310 UJ
9C1-PF30NS
<2.0
<2.0
<24
<24
<30
<2.0
<2.0
<2.0
<24
<30
DONA
<2.0
<2.0
<40
<40
<50
<2.0
<2.0
<2.0
<40
<50
N-Ethyl Perfluorooctane Sulfonamidoacetic Acid
<5.0
<5.0
<130
<130
<160
<5.0
<5.0
<5.0
<130
<160
N-ethylperfluoro-l-octanesulfonamide
<2.0
<2.0
<87
<87
<110
<2.0
<2.0
<2.0
<87
<110
N-methyl perfluoro-l-octanesulfonamide
<2.0
<2.0
<43
<43
<54
<2.0
<2.0
<2.0
<43
<54
N-Methyl Perfluorooctane Sulfonamidoacetic Acid
<5.0
<5.0
<120
<120
<150
<5.0
<5.0
<5.0
<120
<150
Perfluorobutane Sulfonic Acid
<2.0
<2.0
32
<20
<25
<2.0
<2.0
<2.0
<20
<25
Perfluorobutanoic Acid
8.3
10
<240
<240
<300
120
110
120
<240
<300
Perfluorodecane Sulfonic Acid
<2.0
<2.0
<32
<32
<40
<2.0
<2.0
<2.0
<32
<40
Perfluorodecanoic Acid
<2.0
<2.0
<31
<31
<39
<2.0
<2.0
<2.0
<31
<39
Perfluorododecane Sulfonic Acid (PFDoS)
<2.0
<2.0
<97
<97
<120
<2.0
<2.0
<2.0
<97
<120
Perfluorododecanoic Acid
<2.0
<2.0
<55
<55
<69
<2.0
<2.0
<2.0
<55
<69
Perfluoroheptane Sulfonic Acid (PFHpS)
<2.0
<2.0
<19
<19
<24
<2.0
<2.0
<2.0
<19
<24
Perfluoroheptanoic Acid
6.6
8.8
<25
<25
<31
20
34
30
31
36
Perfluorohexadecanoic Acid (PFHxDA)
<2.0
<2.0
<89
<89
<110
<2.0
<2.0
<2.0
<89
<110
Perfluorohexane Sulfonic Acid
<2.0
<2.0
<57
<57
<71
<2.0
<2.0
<2.0
<57
<71
Perfluorohexanoic Acid
2.7
3.5
<58
<58
<73
17
19
18
<58
<73
Perfluorononanesulfonic Acid
<2.0
<2.0
<37
<37
<46
<2.0
<2.0
<2.0
<37
<46
Perfluorononanoic Acid
<2.0
<2.0
<27
<27
<34
<2.0
<2.0
<2.0
<27
<34
Perfluorooctadecanoic Acid
<2.0
<2.0
<94
<94
<120
<2.0
<2.0
<2.0
<94
<120
Perfluorooctane Sulfonamide
<2.0
<2.0
<98
<98
<120
<2.0
<2.0
<2.0
<98
<120
Perfluoropentane Sulfonic Acid (PFPeS)
<2.0
<2.0
<30
<30
<38
<2.0
<2.0
<2.0
<30
<38
Perfluoropentanoic Acid
18
21
<49
<49
<61
820
930
1,100
1,100
880
Perfluormetradecanoic Acid
<2.0
<2.0
<73
<73
<91
<2.0
<2.0
<2.0
<73
<91
Perfluorotridecanoic Acid
<2.0
<2.0
<130
<130
<160
<2.0
<2.0
<2.0
<130
<160
Perfluoroundecanoic Acid
<2.0
<2.0
<110
<110
<140
<2.0
<2.0
<2.0
<110
<140
PFOA
<2.0
<2.0
<85
<85
<110
<2.0
<2.0
<2.0
<85
<110
PFOS
<2.0
<2.0
<54
<54
<68
<2.0
<2.0
<2.0
<54
<68
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the 3Q 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 19 of 24 June 2024
Table 6-2
PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537 MOD SOP COMPO(7NDs LIST'
(ng/L)
Mass Loading Model Sampling Program (Quarterly)
Performance Monitoring Plan Sampling Program (Semi -Annually)
SMW-12
OW-411
OW-30
CAP1Q23-SMW-12-
022323
Sample Date:
CAP2Q23-SMW-12-
051723
Sample Date:
CAP3Q23-SMW-12-
071823
Sample Date:
CAP4Q23-SMW-12-
110823
Sample Date:
CAP1Q24-SMW-12-
011624
Sample Date:
CAP3Q23-OW-4R-
080423
Sample Date:
CAP1Q24-OW-4R-
012924
Sample Date:
CAP1Q23-OW-30-
021523
Sample Date:
CAP3Q23-OW-30-
071323
Sample Date:
CAP1Q24-OW-30-
013024
Sample Date:
10:2 Fluorotelomer sulfonate
<2.0
<2.0 UJ
<61
<67
<84
<67
<84
<2.0
<2.0
<84
11C1-PF3OUdS
<2.0
<2.0 UJ
<29
<32
<40
<32
<40
<2.0
<2.0
<40
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
<2.0
<2.0 UJ
<42
<46
<58
<46
<58
<2.0
<2.0
<58
IH,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
<2.0
<2.0 UJ
<22
<24
<30
<24
<30
<2.0
<2.0
<30
2-(N-ethyl perfluoro-l-octanesulfonamido)-ethanol
<2.0
<2.0 UJ
<77
<85
<110
<85
<110
<2.0
<2.0
<110
2-(N-methylperfluoro-l-octanesulfonamido)-ethanol
<4.0
<4.0 UJ
<130
<140
<180
<140
<180
<4.0
<4.0
<180
6:2 Fluorotelomer sulfonate
<5.0
<5.0 UJ
<230
<250
<310
<250
<310
<5.0
<5.0
<310
9C1-PF30NS
<2.0
<2.0 UJ
<22
<24
<30
<24
<30
<2.0
<2.0
<30
DONA
<2.0
<2.0 UJ
<36
<40
<50
<40
<50
<2.0
<2.0
<50
N-Ethyl Perfluorooctane Sulfonamidoacetic Acid
<5.0
<5.0 UJ
<120
<130
<160
<130
<160
<5.0
<5.0
<160
N-ethylperfluoro-l-octanesulfonamide
<2.0
<2.0 UJ
<79
<87
<110
<87
<110
<2.0
<2.0
<110
N-methylperfluoro-l-octanesulfonamide
<2.0
<2.0 UJ
<39
<43
<54
<43
<54
<2.0
<2.0
<54
N-Methyl Perfluorooctane Sulfonamidoacetic Acid
<5.0
<5.0 UJ
<110
<120
<150
<120
<150
<5.0
<5.0
<150
Perfluorobutane Sulfonic Acid
<2.0
<2.0 UJ
<18
<20
<25
<20
<25
<2.0
<2.0
<25
Perfluorobutanoic Acid
19
25 J
<220
<240
<300
<240
<300
150
95
<300
Perfluorodecane Sulfonic Acid
<2.0
<2.0 UJ
<29
<32
<40
<32
<40
<2.0
<2.0
<40
Perfluorodecanoic Acid
<2.0
<2.0 UJ
<28
<31
<39
<31
<39
<2.0
<2.0
<39
Perfluorododecane Sulfonic Acid (PFDoS)
<2.0
<2.0 UJ
<88
<97
<120
<97
<120
<2.0
<2.0
<120
Perfluorododecanoic Acid
<2.0
<2.0 UJ
<50
<55
<69
<55
<69
<2.0
<2.0
<69
Perfluoroheptane Sulfonic Acid (PFHpS)
<2.0
<2.0 UJ
<17
<19
<24
<19
<24
<2.0
<2.0
<24
Perfluoroheptanoic Acid
<2.0
<2.0 UJ
<23
<25
<31
90
77
12
7
<31
Perfluorohexadecanoic Acid (PFHxDA)
<2.0
<2.0 UJ
<81
<89
<110
<89
<110
<2.0
<2.0
<110
Perfluorohexane Sulfonic Acid
<2.0
<2.0 UJ
<52
<57
<71
<57
<71
<2.0
<2.0
<71
Perfluorohexanoic Acid
<2.0
2.5 J
<53
<58
<73
<58
<73
16
13
<73
Perfluorononanesulfonic Acid
<2.0
<2.0 UJ
<34
<37
<46
<37
<46
<2.0
<2.0
<46
Perfluorononanoic Acid
<2.0
<2.0 UJ
<25
<27
<34
<27
<34
<2.0
<2.0
<34
Perfluorooctadecanoic Acid
<2.0
<2.0 UJ
<86
<94
<120
<94
<120
<2.0
<2.0
<120
Perfluorooctane Sulfonamide
<2.0
<2.0 UJ
<89
<98
<120
<98
<120
<2.0
<2.0
<120
Perfluoropentane Sulfonic Acid (PFPeS)
<2.0
<2.0 UJ
<27
<30
<38
<30
<38
<2.0
<2.0
<38
Perfluoropentanoic Acid
43
62 J
73
92
83
480
390
530
340
460 J
Perfluorotetradecanoic Acid
<2.0
<2.0 UJ
<67
<73
<91
<73
<91
<2.0
<2.0
<91
Perfluorotridecanoic Acid
<2.0
<2.0 UJ
<120
<130
<160
<130
<160
<2.0
<2.0
<160
Perfluoroundecanoic Acid
<2.0
<2.0 UJ
<100
<110
<140
<110
<140
<2.0
<2.0
<140
PFOA
<2.0
<2.0 UJ
<77
<85
<110
<85
<110
<2.0
<2.0
<110
PFOS
<2.0
17 J
<49
<54
<68
<54
<68
<2.0
<2.0
<68
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the 3Q 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
Wells OW-4R, OW-32, OW-37, and OW-51 were installed between late June 2023 and August 2023, so were unavailable for sampling before 3Q 2023.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 20 of 24 June 2024
Table 6-2
PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537 MOD SOP COMPOUNDS LIST'
(ng/L)
Performance Monitoring Plan Sampling Program (Semi -Annually)
OW-32
OW-37
OW40
OW-51
OW-54
CAP3Q23-OW-32-
090823
Sample Date:
CAP1Q24-OW-32-
012924
Sample Date:
CAP3Q23-OW-37-
081023
Sample Date:
CAP1Q24-OW-37-
011724
Sample Date:
CAP1Q23-OW-40-
021523
Sample Date:
CAP3Q23-OW-40-
071323
Sample Date:
CAP1Q24-OW-40-
013024
Sample Date:
CAP3Q23-OW-51-
080323
Sample Date:
CAP1Q24-OW-51-
013124
Sample Date:
CAP1Q23-OW-54-
021623
Sample Date:
Not Sampled in 3Q
2023 (Dry)
CAP1Q24-OW-54-
020624
Sample Date:
10:2 Fluorotelomer sulfonate
<67
<84
<67 UJ
<84
<2.0
<2.0
<84
<67
<84
<2.0
<84
11C1-PF3OUdS
<32
<40
<32 UJ
<40
<2.0
<2.0
<40
<32
<40
<2.0
<40
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
<46
<58
<46 UJ
<58
<2.0
<2.0
<58
<46
<58
<2.0
<58
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
<24
<30
<24 UJ
<30
<2.0
<2.0
<30
<24
<30
<2.0
<30
2-(N-ethyl perfluoro-l-octanesulfonamido)-ethanol
<85
<110
<85 UJ
<110
<2.0
<2.0
<110
<85
<110
<2.0
<110
2-(N-methyl perfluoro-l-octanesulfonamido)-ethanol
<140
<180
<140 UJ
<180
<4.0
<4.0
<180
<140
<180
<4.0
<180
6:2 Fluorotelomer sulfonate
<250
<310
<250 UJ
<310
<5.0
<5.0
<310
<250
<310
<5.0
<310
9C1-PF30NS
<24
<30
<24 UJ
<30
<2.0
<2.0
<30
<24
<30
<2.0
<30
DONA
<40
<50
<40 UJ
<50
<2.0
<2.0
<50
<40
<50
<2.0
<50
N-Ethyl Perfluorooctane Sulfonamidoacetic Acid
<130
<160
<130 UJ
<160
<5.0
<5.0
<160
<130
<160
<5.0
<160
N-ethylperfluoro-l-octanesulfonamide
<87
<110
<87 UJ
<110
<2.0
<2.0
<110
<87
<110
<2.0
<110
N-methylperfluoro-l-octanesulfonamide
<43
<54
<43 UJ
<54
<2.0
<2.0
<54
<43
<54
<2.0
<54
N-Methyl Perfluorooctane Sulfonamidoacetic Acid
<120
<150
<120 UJ
<150
<5.0
<5.0
<150
<120
<150
<5.0
<150
Perfluorobutane Sulfonic Acid
<20
<25
<20 UJ
<25
<2.0
<2.0
<25
<20
<25
2.3
<25
Perfluorobutanoic Acid
<240
<300
<240 UJ
<300
60
43
<300
530
<300
23
<300
Perfluorodecane Sulfonic Acid
<32
<40
<32 UJ
<40
<2.0
<2.0
<40
<32
<40
<2.0
<40
Perfluorodecanoic Acid
<31
<39
<31 UJ
<39
<2.0
<2.0
<39
<31
<39
<2.0
<39
Perfluorododecane Sulfonic Acid (PFDoS)
<97
<120
<97 UJ
<120
<2.0
<2.0
<120
<97
<120
<2.0
<120
Perfluorododecanoic Acid
<55
<69
<55 UJ
<69
<2.0
<2.0
<69
<55
<69
<2.0
<69
Perfluoroheptane Sulfonic Acid (PFHpS)
<19
<24
<19 UJ
<24
<2.0
<2.0
<24
<19
<24
<2.0
<24
Perfluoroheptanoic Acid
<25
<31
<25 UJ
<31
16
18
<31
400
200 J
9.3
<31
Perfluorohexadecanoic Acid (PFHxDA)
<89
<110
<89 UJ
<110
<2.0
<2.0
<110
<89
<110
<2.0
<110
Perfluorohexane Sulfonic Acid
<57
<71
<57 UJ
<71
<2.0
<2.0
<71
<57
<71
<2.0
<71
Perfluorohexanoic Acid
<58
<73
<58 UJ
<73
11
11
<73
140
<73
5.3
<73
Perfluorononanesulfonic Acid
<37
<46
<37 UJ
<46
<2.0
<2.0
<46
<37
<46
<2.0
<46
Perfluorononanoic Acid
<27
<34 UJ
<27 UJ
<34
<2.0
<2.0
<34
<27
<34
<2.0
<34
Perfluorooctadecanoic Acid
<94
<120
<94 UJ
<120
<2.0
<2.0
<120
<94
<120
<2.0
<120
Perfluorooctane Sulfonamide
<98
<120
<98 UJ
<120
<2.0
<2.0
<120
<98
<120
<2.0
<120
Perfluoropentane Sulfonic Acid (PFPeS)
<30
<38
<30 UJ
<38
<2.0
<2.0
<38
<30
<38
<2.0
<38
Perfluoropentanoic Acid
<49
120
55 J
--61
120
74
75 J
2,700
1,400 J
40
<61
Perfluorotetradecanoic Acid
<73
<91
<73 UJ
<91
<2.0
<2.0
<91
<73
<91
<2.0
<91
Perflumotridecanoic Acid
<130
<160
<130 UJ
<160
<2.0
<2.0
<160
<130
<160
<2.0
<160
Perfluoroundecanoic Acid
<110
<140
<110 UJ
<140
<2.0
<2.0
<140
<110
<140
<2.0
<140
PFOA
<85
<110
<85 UJ
<110
2.3
<2.0
<110
<85
<110
17
<110
PFOS
<54
<68
<54 UJ
<68
<2.0
<2.0
<68
<54
<68
<2.0
<68
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the 3Q 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 21 of 24 June 2024
Table 6-2
PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537 MOD SOP COMPOUNDS LIST'
(ng/L)
Performance Monitoring Plan Sampling Program (Semi -Annually)
OW-55
OW-56
OW-57
PIW-41)
CAP1Q23-OW-55-
021623
Sample Date:
CAP3Q23-OW-55-
072523
Sample Date:
CAP1Q24-OW-55-
020524
Sample Date:
CAP1Q23-OW-56-
022123
Sample Date:
CAP3Q23-OW-56-
073123
Sample Date:
CAP1Q24-OW-56-
020124
Sample Date:
CAP1Q23-OW-57-
021523
Sample Date:
CAP3Q23-OW-57-
073123
Sample Date:
CAP1Q24-OW-57-
020624
Sample Date:
CAP3Q23-PIW-4D-
071323
Sample Date:
CAP1Q24-PIW-4D-
012224
Sample Date:
10:2 Fluorotelomer sulfonate
<2.0
<67
<84
<2.0
<67
<84
<2.0
<67
<84
<2.0
<2.0
11C1-PF3OUdS
<2.0
<32
<40
<2.0
<32
<40
<2.0
<32
<40
<2.0
<2.0
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
<2.0
<46
<58
<2.0
<46
<58
<2.0
<46
<58
<2.0
<2.0
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
<2.0
<24
<30
<2.0
<24
<30
<2.0
<24
<30
<2.0
<2.0
2-(N-ethyl perfluoro-l-octanesulfonamido)-ethanol
<2.0
<85
<110
<2.0
<85
<110
<2.0
<85
<110
<2.0
<2.0
2-(N-methyl perfluoro-l-octanesulfonamido)-ethanol
<4.0
<140
<180
<4.0
<140
<180
<4.0
<140
<180
<4.0
<4.0
6:2 Fluorotelomer sulfonate
<5.0
<250
<310
<5.0
<250
<310
<5.0
<250
<310
<5.0
<5.0
9C1-PF30NS
<2.0
<24
<30
<2.0
<24
<30
<2.0
<24
<30
<2.0
<2.0
DONA
<2.0
<40
<50
<2.0
<40
<50
<2.0
<40
<50
<2.0
<2.0
N-Ethyl Perfluorooctane Sulfonamidoacetic Acid
<5.0
<130
<160
<5.0
<130
<160
<5.0
<130
<160
<5.0
<5.0
N-ethylperfluoro-l-octanesulfonamide
<2.0
<87
<110
<2.0
<87
<110
<2.0
<87
<110
<2.0
<2.0
N-methyl perfluoro-l-octanesulfonamide
<2.0
<43
<54
<2.0
<43
<54
<2.0
<43
<54
<2.0
<2.0
N-Methyl Perfluorooctane Sulfonamidoacetic Acid
<5.0
<120
<150
<5.0
<120
<150
<5.0
<120
<150
<5.0
<5.0
Perfluorobutane Sulfonic Acid
<2.0
<20
<25
2.5
33
<25
4.1
33
<25
<2.0
<2.0
Perfluorobuanoic Acid
18
<240
<300
22
<240
<300
140
<240
<300
<5.0
<5.0
Perfluorodecane Sulfonic Acid
<2.0
<32
<40
<2.0
<32
<40
<2.0
<32
<40
<2.0
<2.0
Perfluorodecanoic Acid
<2.0
<31
<39
<2.0
<31
<39
<2.0
<31
<39
<2.0
<2.0
Perfluorododecane Sulfonic Acid (PFDoS)
<2.0
<97
<120
<2.0
<97
<120
<2.0
<97
<120
<2.0
<2.0
Perfluorododecanoic Acid
<2.0
<55
<69
<2.0
<55
<69
<2.0
<55
<69
<2.0
<2.0
Perfluoroheptane Sulfonic Acid (PFHpS)
<2.0
<19
<24
<2.0
<19
<24
<2.0
<19
<24
<2.0
<2.0
Perfluoroheptanoic Acid
<2.0
<25
<31
3.5
<25
<31
71
86
87
<2.0
<2.0
Perfluorohexadecanoic Acid (PFHxDA)
<2.0
<89
<110
<2.0
<89
<110
<2.0
<89
<110
<2.0
<2.0
Perfluorohexane Sulfonic Acid
<2.0
<57
<71
<2.0
<57
<71
2.3
<57
<71
<2.0
<2.0
Perfluorohexanoic Acid
2.6
<58
<73
6.7
<58
<73
63
97
84
<2.0
<2.0
Perfluorononanesulfonic Acid
<2.0
<37
<46
<2.0
<37
<46
<2.0
<37
<46
<2.0
<2.0
Perfluorononanoic Acid
<2.0
<27
<34
<2.0
<27
<34
<2.0
<27
<34
<2.0
<2.0
Perfluorooctadecanoic Acid
<2.0
<94
<120
<2.0
<94
<120
<2.0
<94
<120
<2.0
<2.0
Perfluorooctane Sulfonamide
<2.0
<98
<120
<2.0
<98
<120
<2.0
<98
<120
<2.0
<2.0
Perfluoropentane Sulfonic Acid (PFPeS)
<2.0
<30
<38
<2.0
<30
<38
<2.0
<30
<38
<2.0
<2.0
Perfluoropentanoic Acid
27
<49
<61
44
56
<61
320
380
310
11
14
Perfluorotetradecanoic Acid
<2.0
<73
<91
<2.0
<73
<91
<2.0
<73
<91
<2.0
<2.0
Perfluorotridecanoic Acid
<2.0
<130
<160
<2.0
<130
<160
<2.0
<130
<160
<2.0
<2.0
Perfluoroundecanoic Acid
<2.0
<110
<140
<2.0
<110
<140
<2.0
<110
<140
<2.0
<2.0
PFOA
<2.0
<85
<110
2.7
<85
<110
750
1,000
930
<2.0
<2.0
PFOS
<2.0
<54
<68
<2.0
<54
<68
<2.0
<54
<68
<2.0
<2.0
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the 3Q 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
UJ-Analyte not detected. Reporting limit may not be accurate or precise.
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 22 of 24 June 2024
Table 6-2
PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537MOD SOP COMPOUNDS LIST'
(ng/L)
Performance Monitoring Plan Sampling Program (Semi -Annually)
PIW-5SR
PIW-6S
PIW-81)
PIW-10DR
PIW-10S
PIW-11
CAP3Q23-PIW-5SR-
080423
Sample Date:
Not Sampled in 1Q
2024 (Dry)
CAP3Q23-PIW-6S-
071223
Sample Date:
CAP1Q24-PIW-6S-
013124
Sample Date:
CAP3Q23-PIW-8D-
071123
Sample Date:
CAP1Q24-PIW-8D-
012224
Sample Date:
CAP3Q23-PIW-
IODR-071423
Sample Date:
CAP1Q24-PIW-
10DR-012224
Sample Date:
CAP3Q23-PIW-10S-
071323
Sample Date:
Not Sampled in 1Q
2024 (Dry)
CAP3Q23-PIW-11-
073123
Sample Date:
CAP1Q24-PIW-11-
020124
Sample Date:
10:2 Fluorotelomer sulfonate
<67
<2.0
<84
<2.0
<84
<2.0
<84
<2.0
<67
<84
11C1-PF30UdS
<32
<2.0
<40
<2.0
<40
<2.0
<40
<2.0
<32
<40
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
<46
<2.0
<58
<2.0
<58
<2.0
<58
<2.0
<46
<58
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
<24
<2.0
<30
<2.0
<30
<2.0
<30
<2.0
<24
<30
2-(N-ethyl perfluoro-l-octanesulfonamido)-ethanol
<85
<2.0
<110
<2.0
<110
<2.0
<110
<2.0
<85
<110
2-(N-methylperfluoro-l-octanesulfonamido)-ethanol
<140
<4.0
<180
<4.0
<180
<4.0
<180
<4.0
<140
<180
6:2 Fluorotelomer sulfonate
<250
<5.0
<310
9.4
<310
<5.0
<310
<5.0
<250
<310
9C1-PF30NS
<24
<2.0
<30
<2.0
<30
<2.0
<30
<2.0
<24
<30
DONA
<40
<2.0
<50
<2.0
<50
<2.0
<50
<2.0
<40
<50
N-Ethyl Perfluorooctane Sulfonamidoacetic Acid
<130
<5.0
<160
<5.0
<160
<5.0
<160
<5.0
<130
<160
N-ethylperfluoro-l-octanesulfonamide
<87
<2.0
<110
<2.0
<110
<2.0
<110
<2.0
<87
<110
N-methylperfluoro-l-octanesulfonamide
<43
<2.0
<54
<2.0
<54
<2.0
<54
<2.0
<43
<54
N-MethylPerfluorooctane Sulfonamidoacetic Acid
<120
<5.0
<150
<5.0
<150
<5.0
<150
<5.0
<120
<150
Perfluorobutane Sulfonic Acid
<20
<2.0
<25
<2.0
<25
<2.0
<25
<2.0
29
<25
Perfluorobutanoic Acid
780
150
<300
310
660
130
<300
47
<240
<300
Perfluorodecane Sulfonic Acid
<32
<2.0
<40
<2.0
<40
<2.0
<40
<2.0
<32
<40
Perfluorodecanoic Acid
<31
<2.0
<39
<2.0
<39
<2.0
<39
<2.0
<31
<39
Perfluorododecane Sulfonic Acid (PFDoS)
<97
<2.0
<120
<2.0
<120
<2.0
<120
<2.0
<97
<120
Perfluorododecanoic Acid
<55
<2.0
<69
<2.0
<69
<2.0
<69
<2.0
<55
<69
Perfluoroheptane Sulfonic Acid (PFHpS)
<19
<2.0
<24
<2.0
<24
<2.0
<24
<2.0
<19
<24
Perfluoroheptanoic Acid
80
23
<31
250
760
76
80
11
<25
<31
Perfluorohexadecanoic Acid (PFHxDA)
<89
<2.0
<110
<2.0
<110
<2.0
<110
<2.0
<89
<110
Perfluorohexane Sulfonic Acid
<57
<2.0
<71
<2.0
<71
<2.0
<71
<2.0
<57
<71
Perfluorohexanoic Acid
<58
17
<73
75
210
29
<73
8.6
<58
<73
Perfluorononanesulfonic Acid
<37
<2.0
<46
<2.0
<46
<2.0
<46
<2.0
<37
<46
Perfluorononanoic Acid
<27
<2.0
<34
<2.0
<34
<2.0
<34
<2.0
<27
<34
Perfluorooctadecanoic Acid
<94
<2.0
<120
<2.0
<120
<2.0
<120
<2.0
<94
<120
Perfluomoctane Sulfonamide
<98
<2.0
<120
<2.0
<120
<2.0
<120
<2.0
<98
<120
Perfluoropentane Sulfonic Acid (PFPeS)
<30
<2.0
<38
<2.0
<38
<2.0
<38
<2.0
<30
<38
Perfluoropentanoic Acid
1,100
820
760 J
1,700
3,500
350
400
59
63
<61
Perfluorotetradecanoic Acid
<73
<2.0
<91
<2.0
<91
<2.0
<91
<2.0
<73
<91
Perfluorotridecanoic Acid
<130
<2.0
<160
<2.0
<160
<2.0
<160
<2.0
<130
<160
Perfluoroundecanoic Acid
<110
<2.0
<140
<2.0
<140
<2.0
<140
<2.0
<110
<140
PFOA
<85
<2.0
<110
2.5
<110
4.1
<110
9.1
<85
<110
PFOS
<54
<2.0
<68
<2.0
<68
<2.0
<68
<2.0
<54
<68
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the 3Q 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 23 of 24 June 2024
Table 6-2
PFAS Concentrations in Downgradient Groundwater Monitoring Wells
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
METHOD 537 MOD SOP COMPOUNDS LIST'
(ng/L)
Performance Monitoring Plan Sampling Program (Semi -Annually)
Corrective Action Plan Sampling Program (Annually)
PIW-15
PW-IORR
PW-11
PIW-12
PIW-13
PIW-14
CAP3Q23-PIW-15-
072523
Sample Date:
CAP1Q24-PIW-15-
020524
Sample Date:
CAP3Q23-PW-10RR-
080323
Sample Date:
CAP1Q24-PW-IORR-
013124
Sample Date:
CAP3Q23-PW-11-070723
Sample Date:
CAP1Q24-PW-11-013124
Sample Date:
CAP3Q23-PIW-12-
072423
Sample Date:
CAP3Q23-PIW-13-
072423
Sample Date:
CAP3Q23-PIW-14-
072423
Sample Date:
10:2 Fluorotelomer sulfonate
<67
<84
<67
<84
<2.0
<84
<67
<67
<67
11Cl-PF30UdS
<32
<40
<32
<40
<2.0
<40
<32
<32
<32
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
<46
<58
<46
<58
<2.0
<58
<46
<46
<46
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
<24
<30
<24
<30
<2.0
<30
<24
<24
<24
2-(N-ethylperfluoro-l-octanesulfonamido)-ethanol
<85
<110
<85
<110
<2.0
<110
<85
<85
<85
2-(N-methylperfluoro-l-octanesulfonamido)-ethanol
<140
<180
<140
<180
<4.0
<180
<140
<140
<140
6:2 Fluorotelomer sulfonate
<250
<310
<250
<310
<5.0
<310
<250
<250
<250
9C1-PF30NS
<24
<30
<24
<30
<2.0
<30
<24
<24
<24
DONA
<40
<50
<40
<50
<2.0
<50
<40
<40
<40
N-Ethyl Perfluorooctane Sulfonamidoacetic Acid
<130
<160
<130
<160
<5.0
<160
<130
<130
<130
N-ethylperfluoro-l-octanesulfonamide
<87
<110
<87
<110
<2.0
<110
<87
<87
<87
N-methylperfluoro-l-octanesulfonamide
<43
<54
<43
<54
<2.0
<54
<43
<43
<43
N-MethylPerfluorooctane Sulfonamidoacetic Acid
<120
<150
<120
<150
<5.0
<150
<120
<120
<120
Perfluorobutane Sulfonic Acid
<20
<25
<20
<25
2.1
<25
<20
<20
<20
Perfluorobutanoic Acid
<240
<300
<240
<300
100
<300
<240
<240
<240
Perfluorodecane Sulfonic Acid
<32
<40
<32
<40
<2.0
<40
<32
<32
<32
Perfluorodecanoic Acid
<31
<39
<31
<39
<2.0
<39
<31
<31
<31
Perfluorododecane Sulfonic Acid (PFDoS)
<97
<120
<97
<120
<2.0
<120
<97
<97
<97
Perfluorododecanoic Acid
<55
<69
<55
<69
<2.0
<69
<55
<55
<55
Perfluoroheptane Sulfonic Acid (PFHpS)
<19
<24
<19
<24
<2.0
<24
<19
<19
<19
Perfluoroheptanoic Acid
<25
<31
<25
<31
100
1101
<25
<25
<25
Perfluorohexadecanoic Acid (PFHxDA)
<89
<110
<89
<110
<2.0
<110
<89
<89
<89
Perfluorohexane Sulfonic Acid
<57
<71
<57
<71
2.8
<71
<57
<57
<57
Perfluorohexanoic Acid
<58
<73
<58
<73
26
<73
<58
<58
<58
Perfluorononanesulfonic Acid
<37
<46
<37
<46
<2.0
<46
<37
<37
<37
Perfluorononanoic Acid
<27
<34
<27
<34
22
<34
<27
<27
<27
Perfluorooctadecanoic Acid
<94
<120
<94
<120
<2.0
<120
<94
<94
<94
Perfluorooctane Sulfonamide
<98
<120
<98
<120
<2.0
<120
<98
<98
<98
Perfluoropentane Sulfonic Acid (PFPeS)
<30
<38
<30
<38
<2.0
<38
<30
<30
<30
Perfluoropentanoic Acid
140
120
710
520 J
420
230 J
<49
<49
80
Perfluorotetradecanoic Acid
<73
<91
<73
<91
<2.0
<91
<73
<73
<73
Perfluorotridecanoic Acid
<130
<160
<130
<160
<2.0
<160
<130
<130
<130
Perfluoroundecanoic Acid
<110
<140
<110
<140
<2.0
<140
<110
<110
<110
PFOA
<85
<110
<85
<110
42
<110
<85
<85
<85
PFOS
<54
<68
<54
<68
4.7
<68
<54
<54
<54
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the 3Q 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
UJ — Analyte not detected. Reporting limit may not be accurate or precise.
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 24 of 24 June 2024
Table 6-3
Willis Creek PFAS Analytical Results
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
Jul 18 (0.00)
Nov 6 (0.00)
Feb 22 (0.00)
May 9 (0.00)
Jul 24 (0.20)
Nov 20 (0.00)
Feb 19 (0.00)
Jul 18 (0.00)
Nov 6 (0.00)
Feb 22 (0.00)
May 9 (0.00)
Jul 24 (0.20)
Nov 20 (0.00)
Feb 19 (0.00)
dent Daily Total Rainfall (inches):
Jul 19 (0.10)
Nov 7 (0.00)
Feb 23 (0.00)
May 10 (0.00)
Jul 25 (0.00)
Nov 21(0.41)
Feb 20 (0.00)
Jul 19 (0.10)
Nov 7 (0.00)
Feb 23 (0.00)
May 10 (0.00)
Ju125 (0.00)
Nov 21(0.41)
Feb 20 (0.00)
Jul 20 (0.47)
Nov 8 (0.00)
Feb 24 (0.01)
May 11 (0.00)
Jul 26 (0.00)
Nov 22 (1.26)
Feb 21 (0.00)
Jul 20 (0.47)
Nov 8 (0.00)
Feb 24 (0.01)
May 11(0.00)
Jul 26 (0.00)
Nov 22 (1.26)
Feb 21(0.00)
D 537 MOD SOP COMPOUNDS LIST'
(aglE)
(7FMOAA
WC-1
WC-2
CAP3Q22-WC-1-24-
072122
Sample Date:
21-Jul-22
CAP4Q22-WC-1-24-
110922
Sample Date:
9-Nov-22
CAP1Q23-WC-1-24-
022523
Sample Date:
25-Feb-23
CAP2Q23-WC-1-24-
051223
Sample Date:
12-May-23
CAP3Q23-WC-1-24-
072723
Sample Date:
27-Jul-23
CAP4Q23-WC-1-
112323
Sample Date:
23-Nov-23
CAP1Q24-WC-1-24-
022224
Sample Date:
22-Feb-24
CAP3Q22-WC-2-24-
072122
Sample Date:
21-Jul-22
CAP4Q22-WC-2-22-
110922
Sample Date:
9-Nov-22
CAP1Q23-WC-2-24-
022523
Sample Date:
25-Feb-23
CAP2Q23-WC-2-24-
051223
Sample Date:
12-May-23
CAP3Q23-WC-2-24-
072723
Sample Date:
27-Jul-23
CAP4Q23-WC-2-
112323
Sample Date:
23-Nov-23
CAP1Q24-WC-2-24-
022224
Sample Date:
22-Feb-24
560
580
310
430
360
89 J
240
320
490
180
290
260
120
160
1,300
1,900
480
830
970
200
420
250
1,000
300
360
610
290 J
250
650
960
280
500
500
150
310
250
640
160
280
350
190 J
180
PFO3OA
130
160
45
90
87
23 J
57
40
89
21
42
55
27
25
PFO4DA
25
29
10
15
16
5.4 J
9.4
12
17
4.5
8.2
10
5.3
4.8
PFO5DA
<3.9
<7.8
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
PMPA
640
790
340
430
490
170
290
330
570
240
310
410
230 J
200
PEPA
150
200
74
120
120
45
72
70
150
52
86
92
48 J
41
PS Acid
<2.0
2.6
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
Hydro -PS Acid
14
14
8
11
12
5.2
7.3
12
11
7.2
8.2
9.5
6.1
6.6
R-PSDA
42J
36J
30J
86J
170J
111
36J
26J
31J
181
49J
96J
9.4J
12J
Hydrolyzed PSDA
230 J
230 J
190 J
380 J
290 J
28 J
160 J
44 J
130 J
28 J
44 J
75 J
20 J
14 J
R-PSDCA
<2.0
<2.0
<2.0
<2.0
<3.0
<3.0
<3.0
<2.0
<2.0
<2.0
<2.0
<3.0
<3.0
<3.0
NVHOS, Acid Form
21
30
14
20
25
3.8
15
8.3
19
5.7
8.6
16
5.7 J
5.7
EVE Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
Hydro -EVE Acid
9.9
13
5.1
6.7
7.4
<2.0
4
4.5
12
<2.0
3.1
2.2
2.2
2.1
R-EVE
24J
16J
14J
38J
59J
5.9J
18J
9.4J
191
9.6J
28J
41J
7.4J
7.7J
Perfluoro(2-ethoxyethane)sulfonic Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0 UJ
<2.0
PFECA B
<2.0
<2.7
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
PFECA-G
<2.4
<4.8
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
PFPrA
770
250
530
570
340 J
320
Total Table 3+ (17 compounds)2,3 it
3,500
4,680
1,570
2,450
2,590
691
1,420
1,300
3,000
970
1,400
1,810
9
875
Total Table 3+ (18 compounds)""
-
-
-
-
3,360
941
1,950
-
-
-
-
2,380
1,260
1,200
Total Table 3+ (21 compounds)"' mom-
-
-
-
3,880
1986
12,170
1-
-
-
-
2,600
11,300
11,230
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the July 27, 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
2 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to three significant figures.
3 - Total Table 3+ (17 Compounds) does not include R-PSDA, Hydrolyzed PSDA, R-EVE, and PFPrA.
4 - Total Table 3+ (18 compounds) does not include R-PSDA, Hydrolyzed PSDA, and R-EVE.
5 - Total Table 3+ (21 compounds) is the sum of all Table 3+ PFAS compounds.
Precipitation data obtained from USGS gauge #02105500 at the William O. Huske Lock and Dam.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 1 of 4 June 2024
Table 6-3
Willis Creek PFAS Analytical Results
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
Antecedent Daily Total Rainfall (inches):
Jul 18 (0.00)
Nov 6 (0.00)
Feb 22 (0.00)
May 9 (0.00)
Jul 24 (0.20)
Nov 20 (0.00)
Feb 19 (0.00)
Jul 19 (0.10)
Nov 7 (0.00)
Feb 23 (0.00)
May 10 (0.00)
Jul25 (0.00)
Nov 21(0.41)
Feb 20 (0.00)
Jul 20 (0.47)
Nov 8 (0.00)
Feb 24 (0.01)
May 11(0.00)
Jul 26 (0.00)
Nov 22 (1.26)
Feb 21(0.00)
METHOD 537 MOD SOP COMPOUNDS LIST'
(aglE)
WC-3
CAP3Q22-WC-3-24-
072122
Sample Date:
21-Jul-22
CAP4Q22-WC-3-24-
110922
Sample Date:
9-Nov-22
CAP1Q23-WC-3-24-
022523
Sample Date:
25-Feb-23
CAP2Q23-WC-3-24-
051223
Sample Date:
12-May-23
CAP3Q23-WC-3-24-
072723
Sample Date:
27-Jul-23
CAP4Q23-WC-3-
112323
Sample Date:
23-Nov-23
CAP1Q24-WC-3-24-
022224
Sample Date:
22-Feb-24
Hfpo Dimer Acid
180
190
100
150
130
49
50 J
PFM0,
45
72
35
55
58
25
22 J
PFO2HxA
140
190
74
130
140
61
44 J
PFO3OA
19
21
8.7
16
19
7.6
<8.9
PFO4DA
5.3
4.8
2.1
3.5
5.1
2.2
<4.0
PFO5DA
<2.0
<2.0
<2.0
<2.0
2.1
<2.0
<10
PMPA
230
260
160
190
200
120
83 J
PEPA
45
70
32
53
50
24
31
PS Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<4.0
Hydro -PS Acid
9.3
7.8
6.5
6.8
7.8
4.2
<4.4
R-PSDA
<2.0
12J
151
32J
65J
4.3J
3.3J
Hydrolyzed PSDA
<2.0
<2.0
<2.0
<2.0
7.6 J
<2.0
<2.7
R-PSDCA
<2.0
<2.0
<2.0
<2.0
<3.0
<3.0
<14
NVHOS, Acid Form
4.6
3.2
2.5
2.8
<3.0
<3.0
<13
EVE Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<4.0
Hydro -EVE Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.4
R-EVE
5.6J
6.1J
7.5J
16J
23J
2.7J
<3.1
Perfluoro(2-ethoxyethane)sulfomc Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.9
PFECA B
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<6.2
PFECA-G
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.9
PFPrA
-
-
-
280
150
210
Total Table 3+ (17 compounds)2,3
678
819
612
293
230
Total Table 3+ (18 compounds)2'0
-
-
-
-
892
443
440
Total Table 3+ (21 compounds)a's
-
-
-
-
988
450
443
Notes:
1 - The EPA Method 537 was modified to incorporate the Table 3+ compounds. Beginning with the July 27, 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
2 - Total Table 3+ was calculated including J qualified data but not non -detect data. The total Table 3+ sum is rounded to three significant figures.
3 - Total Table 3+ (17 Compounds) does not include R-PSDA, Hydrolyzed PSDA, R-EVE, and PFPrA.
4 - Total Table 3+ (18 compounds) does not include R-PSDA, Hydrolyzed PSDA, and R-EVE.
5 - Total Table 3+ (21 compounds) is the sum of all Table 3+ PFAS compounds.
Precipitation data obtained from USGS gauge #02105500 at the William O. Huske Lock and Dam.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
TR0795C Page 2 of 4 June 2024
Table 6-3
Willis Creek PFAS Analytical Results
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
Jul18 (0.00)
Nov 6 (0.00)
Feb 22 (0.00)
May 9 (0.00)
Jul 24 (0.20)
Nov 20 (0.00)
Feb 19 (0.00)
Jul 18 (0.00)
Nov 6 (0.00)
Feb 22 (0.00)
May 9 (0.00)
Ju124 (0.20)
Nov 20 (0.00)
Feb 19 (0.00)
Antecedent Daily Total Rainfall (inches):
Jul 19 (0.10)
Nov 7 (0.00)
Feb 23 (0.00)
May 10 (0.00)
Jul25 (0.00)
Nov 21 (0.41)
Feb 20 (0.00)
Jul 19 (0.10)
Nov 7 (0.00)
Feb 23 (0.00)
May 10 (0.00)
Jul25 (0.00)
Nov 21 (0.41)
Feb 20 (0.00)
Jul 20 (0.47)
Nov 8 (0.00)
Feb 24 (0.01)
May 11 (0.00)
Jul 26 (0.00)
Nov 22 (1.26)
Feb 21 (0.00)
Jul 20 (0.47)
Nov 8 (0.00)
Feb 24 (0.01)
May 11 (0.00)
Jul 26 (0.00)
Nov 22 (1.26)
Feb 21 (0.00)
METHOD 537MOD SOP COMPOUNDS LIST'
(ng,E)
WC-1
WC-2
CAP3Q22-WC-1-24-
072122
Sample Date:
21-Jul-22
CAP4Q22-WC-1-24-
110922
Sample Date:
9-Nov-22
CAP1Q23-WC-1-24-
022523
Sample Date:
25-Feb-23
CAP2Q23-WC-1-24-
051223
Sample Date:
12-May-23
CAP3Q23-WC-1-24-
072723
Sample Date:
27-Jul-23
CAP4Q23-WC-1-
112323
Sample Date:
23-Nov-23
CAP1Q24-WC-1-24-
022224
Sample Date:
22-Feb-24
CAP3Q22-WC-2-24-
072122
Sample Date:
21-Jul-22
CAP4Q22-WC-2-22-
110922
Sample Date:
9-Nov-22
CAP1Q23-WC-2-24-
022523
Sample Date:
25-Feb-23
CAP2Q23-WC-2-24-
051223
Sample Date:
12-May-23
CAP3Q23-WC-2-24-
072723
Sample Date:
27-Jul-23
CAP4Q23-WC-2-
112323
Sample Date:
23-Nov-23
CAP1Q24-WC-2-24-
022224
Sample Date:
22-Feb-24
10:2 Fluorotelomer sulfonate
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0 UJ
<2.0
11C1-PF3OUdS
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0 UJ
<2.0
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
1H,1H 2H,2H-perfluorohexanesulfonate (4:2 FTS)
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
2-(N-ethyl perfluoro-l-octanesulfonamido)-ethanol
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
2-(N-methylperfluoro-l-octanesulfonamido)-ethanol
<4.0
<4.0
<4.0
<4.0
<4.0
<4.0
<4.0
<4.0
<4.0
<4.0
<4.0
<4.0
<4.0
<4.0
6:2 Fluorotelomer sultanate
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
9C1-PF3ONS
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0 UJ
<2.0
DONA
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0 UJ
<2.0
N-Ethyl Perfluorooctane Sulfonamidoacetic Acid
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0 UJ
<5.0
N-ethylperfluoro-l-octanesulfonamide
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
N-methyl perfluoro-l-octanesulfonamide
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
N-Methyl Perfluorooctane Sulfonamidoacetic Acid
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0 UJ
<5.0
Perfluorobutane Sulfonic Acid
4.6
3.9
4.4
4.6
4.9
3.7
5.7
4.4
3.6
4.5
4.6
4.6
4.7 J
6.2
Perfluorobutanoic Acid
6.6
9.1
7
6.3
9
<5.0
5.2
<5.0
10.0
<5.0
<5.0
7.6
<5.0 UJ
<5.0
Perfluorodecane Sulfonic Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0 UJ
<2.0
Perfluorodecanoic Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0 UJ
<2.0
Perfluorododecane Sulfonic Acid (PFDoS)
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0 UJ
<2.0
Perfluorododecanoic Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0 UJ
<2.0
Perfluoroheptane Sulfonic Acid (PFHpS)
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
Perfluoroheptanoic Acid
2.4
2.9
<2.0
2.4
2.4
<2.0
<2.0
<2.0
2.4
<2.0
<2.0
2.0
<2.0
<2.0
Perfluorohexadecanoic Acid (PFHxDA)
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<8.9
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<8.9
Perfluorohexane Sulfonic Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
Perfluorohexanoic Acid
3.5
4.1
2.8
3.7
4.3
<2.0
3.1
3.0
3.9
2.6
3.1
3.8
2.3
2.8
Perfluorononanesulfonic Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0 UJ
<2.0
Perfluorononanoic Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
Perfluomoctadecanoic Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<9.4
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<9.4
Perfluorooctane Sulfonamide
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
Perfluoropentane Sulfonic Acid (PFPeS)
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0 UJ
<2.0
Perfluoropentanoic Acid
13
13
7.8
11
9.9
3.4
6.7
8.8
13.0
5.0
7.3
8.1
5.1 J
4.7
Perfluorotetradecanoic Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0 UJ
<2.0
Perfluorotridecanoic Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0 UJ
<2.0
Perfluoroundecanoic Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0 UJ
<2.0
PFOA
9.7
10
5.8
7.7
7.2
2.1
5.1
3.4
5.1
2.8
3.1
5.6
2.3
2.7
PFOS
2.5
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
2.0 J
<2.0
Notes:
1 - The EPA Method 537 was modified to incorporate the Table3+ compounds. Beginning with the July 27, 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
Precipitation data obtained from USGS gauge #02105500 at the William 0. Huske Lock and Dam.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
<- Analyte not detected above associated reporting limit.
TR0795C Page 3 of 4 June 2024
Table 6-3
Willis Creek PFAS Analytical Results
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
Antecedent Daily Total Rainfall (inches):
Jul18 (0.00)
Nov 6 (0.00)
Feb 22 (0.00)
May 9 (0.00)
Jul 24 (0.20)
Nov 20 (0.00)
Feb 19 (0.00)
Jul19 (0.10)
Nov 7 (0.00)
Feb 23 (0.00)
May 10 (0.00)
Jul25 (0.00)
Nov 21 (0.41)
Feb 20 (0.00)
Jul 20 (0.47)
Nov 8 (0.00)
Feb 24 (0.01)
May 11 (0.00)
Jul 26 (0.00)
Nov 22 (1.26)
Feb 21 (0.00)
METHOD 537MOD SOP COMPOUND, LIST'
(nglL)
WC-3
CAP3Q22-WC-3-24-
072122
Sample Date:
21-Jul-22
CAP4Q22-WC-3-24-
110922
Sample Date:
9-Nov-22
CAP1Q23-WC-3-24-
022523
Sample Date:
25-Feb-23
CAP2Q23-WC-3-24-
051223
Sample Date:
12-May-23
CAP3Q23-WC-3-24-
072723
Sample Date:
27-Jul-23
CAP4Q23-WC-3-
112323
Sample Date:
23-Nov-23
CAP1Q24-WC-3-24-
022224
Sample Date:
22-Feb-24
10:2 Fluorotelomer sulfonate
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<6.7
11C1-PF3OUdS
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<3.2
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<4.6
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.4
2-(N-ethyl perfluoro-l-octanesulfonamido)-ethanol
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<8.5
2-(N-methyl perfluoro-l-octanesulfonamido)-ethanol
<4.0
<4.0
<4.0
<4.0
<4.0
<4.0
<14
6:2 Fluorotelomer sulfonate
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<25
9Cl-PF3ONS
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.4
DONA
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<4.0
N-Ethyl Perfluorooctane Sulfonamidoacetic Acid
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0 UJ
<13
N-ethylperfluoro-l-octanesulfonamide
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<8.7
N-methylperfluoro-l-octanesulfonamide
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<4.3
N-Methyl Perfluorooctane Sulfonamidoacetic Acid
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<12
Perfluorobutane Sulfonic Acid
4.7
3.1
4.6
4.3
4.6
3.5
4.3 J
Perfluorobutanoic Acid
<5.0
<5.0
<5.0
<5.0
5.8
<5.0
<24
Perfluorodecane Sulfonic Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<3.2
Perfluorodecanoic Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<3.1
Perfluorododecane Sulfonic Acid (PFDoS)
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<9.7
Perfluorododecanoic Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<5.5
Perfluoroheptane Sulfonic Acid (PFHpS)
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
Perfluorohepanoic Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.5
Perfluorohexadecanoic Acid (PFHxDA)
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<8.9
Perfluorohexane Sulfonic Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<5.7
Perfluorohexanoic Acid
2.6
2.3
2.1
2.7
3.0
<2.0
<5.8
Perfluorononanesulfonic Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<3.7
Perfluorononanoic Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.7
Perfluorooctadecanoic Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<9.4
Perfluorooctane Sulfonamide
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<9.8
Perfluoropentane Sulf ntic Acid (PFPeS)
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<3.0
Perfluoropentanoic Acid
5.5
4.5
3.6
5.1
4.9
2.6
<4.9
Perfluorotetradecanoic Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<7.3
Perfluorotridecanoic Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<13
Perfluoroundecanoic Acid
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<11
PFOA
2.4
<2.0
<2.0
<2.0
2.1
<2.0
<8.5
PFOS
2.3
<2.0
<2.0
<2.0
<2.0
<2.0
<5.4
Notes:
1 - The EPA Method 537 was modified to incorporate the Table3+ compounds. Beginning with the July 27, 2023 sampling, perfluoropropionic acid (PFPrA) was added to the compounds list.
Precipitation data obtained from USGS gauge 902105500 at the William O. Huske Lock and Dam.
Bold - Analyte detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or precise.
UJ - Analyte not detected. Reporting limit may not be accurate or precise.
ng/L - nanograms per liter
SOP - standard operating procedure
<- Analyte not detected above associated reporting limit.
TR0795C Page 4 of 4 June 2024
Table 6-4
Willis Creek PFAS Mass Discharge
Quarterly Report #5 (Jan - Mar 2024)
Chemours Fayetteville Works
Fayetteville, NC
Sample Date
Willis Creek
Flow
(ft3/sec)
Total Table 3+ Concentration
(17 compounds)
(ng/L)
PFAS Mass Discharge
(Total Table 3+ 17 compounds)
(mg/sec)
A PFAS Mass Discharge
(Total Table 3+ 17 compounds)
(mg/sec)
WC-2
WC-1
WC-2
WC-1
A WC-2 TO WC-1
21-Jul-22
5.0
1,300
3,500
0.18
0.49
0.31
9-Nov-22
3.4
3,000
4,700
0.29
0.45
0.16
25-Feb-23
11.5
970
1,600
0.32
0.52
0.21
14-Mar-23 Startup of the Groundwater Extraction and Conveyance (GWEC) System
12-May-23
3.5
1,400
2,500
0.14
0.25
0.11
27-Jul-23
2.8
1,800
2,600
0.14
0.20
0.06
23-Nov-23
15.5
920
690
0.40
0.30
-0.10
22-Feb-24
7.3
875
1,420
0.18
0.29
0.11
Notes:
1 - Willis Creek (WC) flow was measured using the Marsh-McBirney method. Flow measurements were made at location WC-1 on the same day as analytical
sampling, except for the February 25, 2023 and February 22, 2024 sampling events. For the February 25, 2023 event, flow was measured at WC-6 on February 13,
2023. For the February 22, 2024 event, flow was measured at WC-1 on February 21, 2024, a day earlier than analytical sampling.
2 - The total Table 3+ concentration (17 compounds) is rounded to two significant figures. Presented values of flow and mass discharge are limited to 1 and 2
decimal places, respectively.
3 - WC-2 is located approximately at the upgradient end of the long-term remedy alignment, and WC-1 is located approximately near the confluence with the
Cape Fear River.
ft3/sec - cubic foot per second
A - delta or change
ng/L - nanograms per liter
mg/sec - milligrams per second
TR0795C Page 1 of 1 June 2024
Geosyntec
consultants
Figures
Geosyntec Consultants of NC, P.C.
NC License No.: C-3500 and C-295
TR0795C
River Elevation During First Quarter (01/01/2024 through 03/31/2024) - Seep A
55
50
00
00
0
a
z
45
a�
v
NTop
of Wall
a 40
Spillway
O
Top of GAC
ca
+,
--------------------------------------- Discharge
v
Weir
35
Discharge
0
Invert
r6
v
w
30
25
1/1/2024 1/16/2024 1/31/2024 2/15/2024 3/1/2024 3/16/2024 3/31/2024
Legend
River
...... GAC Changeout
River Level During Reporting Period & FTC
As -Built Elevations - Seep A
Notes: Chemours Fayetteville Works
As -built survey information for Seep A from Donaldson Garrett & Associates July 2021. Fayetteville, North Carolina
River elevation from USGS Huske Lock and Dam site 02105500, converted to NAVD88. Figure
FB1/FB2 = Filter Bed 1/Filter Bed 2 Geosyntec° co.ea„rs of NC, PC
NC WCense No C3500—C 295
GAC = Granular Activated Carbon consultants
FTC = Flow -Through Cell 2-1A
Raleigh, NC June 2024
55
50
00
00
0
a
z
45
a�
v
a
N
a 40
O
ca
a�
v
35
0
r6
v
w
30
River Elevation During First Quarter (01/01/2024 through 03/31/2024) - Seep 6
Seep B - FB1
Top of Wall
----------------------------------------------------------------------------------.---------------------------------------------- Spillway
Top of GAC
Discharge
Weir
Discharge
Invert
25 1
1/1/2024
Legend
River
...... GAC Changeout
1/16/2024
1/31/2024
Notes:
As -built survey information for Seep B from Donaldson Garrett & Associates July 2021.
River elevation from USGS Huske Lock and Dam site 02105500, converted to NAVD88.
FB1/FB2 = Filter Bed 1/Filter Bed 2
GAC = Granular Activated Carbon
FTC = Flow -Through Cell
2/15/2024
3/1/2024
3/16/2024
3/31/2024
55
50
00
00
0
a
z
45
a�
v
a
N
a 40
O
ca
a�
v
35
O
r6
N
w
30
25
River Elevation During First Quarter (01/01/2024 through 03/31/2024) - Seep C
Seep C - F131
Top of Wall
-----•----------------------------------------------------------------------------------------------------------------------------------------------- Spillway
Top of GAC
------------------------------------- Discharge
Weir
Discharge
Invert
1/1/2024
Legend
River
...... GAC Changeout
1/16/2024
1/31/2024
Notes:
As -built survey information for Seep C from RMA Surveying October 2020.
River elevation from USGS Huske Lock and Dam site 02105500, converted to NAVD88.
FB1/FB2 = Filter Bed 1/Filter Bed 2
GAC = Granular Activated Carbon
FTC = Flow -Through Cell
2/15/2024
3/1/2024
3/16/2024
3/31/2024
55
50
00
00
0
a
z
45
a�
v
a
N
a 40
O
ca
a�
35
O
r6
v
w
30
25 1
1/1/2024
Legend
River
...... GAC Changeout
1/16/2024
River Elevation During First Quarter (01/01/2024 through 03/31/2024) - Seep D
. Seep D - FB2
1/31/2024
Notes:
As -built survey information for Seep D from Donaldson Garrett & Associates July 2021.
River elevation from USGS Huske Lock and Dam site 02105500, converted to NAVD88.
FB1/FB2 = Filter Bed 1/Filter Bed 2
GAC = Granular Activated Carbon
FTC = Flow -Through Cell
2/15/2024
3/1/2024
3/16/2024
Top of Wall
Spillway
Top of GAC
Discharge
Weir
Discharge
Invert
3/31/2024
i
i
600
500
E
400
a)
c�
0
`L 300
200
100 LAI
0
LN I I 1 11 1
It �t �t t �t �t
N N N N N N N N r N N N N N N N N N N N N N
-i LLn (n M N .\-I Lf Q\1 N W O 0000 N W c\-I LL l O\1 M n -i L 1 M
N N N \ \ -I c-I -i N N \ \ \ -i c-I N N N
\ \ \ \ \ N N \ \ \ \ \ M M M \ \ \ \ \
N N N N N M M M M M
Legend
Measured Discharge Flowrate 0 Pumping Flowrate
0 FTC off, no flow
0 Cape Fear River Above Discharge Weir Elevation
FTC Discharge Flowrate
Notes: (Jan - Mar 2024) - Seep A
gpm - gallons per minute Chemours Fayetteville Works
Batch mode (in which the FTC is closed to flow due to dry conditions) is designated with orange shading. Fayetteville, North Carolina
This figure depicts two types of processing: (1) Passive flow through the system is calculated using the Effluent Stilling Basin transducer data (solid green). (2) Periodically during batch mode, the
impoundment was pumped into the filter beds through a flowmeter skid; the approximate flow rate during intermittent pumping is shown with blue diamond symbols. GeosynCeCC GeoVntecConsultantsofNC,P.C. Figure
From Jan. 10 to 18 and March 29 to 31, 2024, the Cape Fear River rose above the elevation of the discharge weir (W3), and head differentials throughout the flow -through cell were reduced and consultants NC License No.: C 3500 and C 295
flow through the system was hindered (pink shading). See section 2.3.5 for more details. 2-2A
FTC - Flow -Through Cell Raleigh, NC June 2024
600
500
E
400
a)
c�
0
`L 300
200
100 LAI
0
LN I I 1 11 1
It �t �t t �t �t
N N N N N N N N r N N N N N N N N N N N N N
-i LLn (n M N .\-I Lf Q\1 N W O 0000 N W c\-I LL l O\1 M n -i L 1 M
N N N \ \ -I c-I -i N N \ \ \ -i c-I N N N
\ \ \ \ \ N N \ \ \ \ \ M M M \ \ \ \ \
N N N N N M M M M M
Legend
Measured Discharge Flowrate 0 Pumping Flowrate
0 FTC off, no flow
0 Cape Fear River Above Discharge Weir Elevation
FTC Discharge Flowrate
Notes: (Jan - Mar 2024) - Seep A
gpm - gallons per minute Chemours Fayetteville Works
Batch mode (in which the FTC is closed to flow due to dry conditions) is designated with orange shading. Fayetteville, North Carolina
This figure depicts two types of processing: (1) Passive flow through the system is calculated using the Effluent Stilling Basin transducer data (solid green). (2) Periodically during batch mode, the
impoundment was pumped into the filter beds through a flowmeter skid; the approximate flow rate during intermittent pumping is shown with blue diamond symbols. GeosynCeCC GeoVntecConsultantsofNC,P.C. Figure
From Jan. 10 to 18 and March 29 to 31, 2024, the Cape Fear River rose above the elevation of the discharge weir (W3), and head differentials throughout the flow -through cell were reduced and consultants NC License No.: C 3500 and C 295
flow through the system was hindered (pink shading). See section 2.3.5 for more details. 2-2A
FTC - Flow -Through Cell Raleigh, NC June 2024
600
-
500
400
v
c�
L
_0
`_ 300
TIM
200
100
I
0
N N N N N (14 N N N N N N N N N N N
N N
N N N N
a 1 U) Q\1 M -i Lr a) N lOO O 1;t 0000 N Q0 -i Lr)r)
Q\1 M
� 1 Lr a)
\ \ \ -i -i N N N \ \ . 1 rA rA N N \ \
N N \ \ \ \ \ M M
\ rA
M \
-i N N N
\ \ \ \
c-I r-I r-I r-I r-I N N N N N
M
M M M M
Legend
Measured Discharge Flowrate
p FTC off, no flow
p Cape Fear River Above Discharge Weir Elevation
Notes:
FTC Discharge Flowrate
gpm - gallons per minute
(Jan - Mar 2024) - Seep B
Batch mode (in which the FTC is closed to flow due to dry conditions) is designated with orange shading.
Chemours Fayetteville works
This figure depicts the measured discharge flowrate (solid green) of water processed through the filter beds calculated using the Effluent Stilling Basin transducer data.
Fayetteville, North Carolina
From Jan. 10 to 17 and March 29 to 31, 2024, the Cape Fear River rose above the elevation of the discharge weir (W3), and head differentials throughout the flow -through cell were
reduced and
Figure
flow through the system was hindered (pink shading). See section 2.3.5 for more details.
Geosyntec° Geusym[ecCunsul[zntsufNC,PC.
NC License No.: C 3500 and C 295
FTC - Flow -Through Cell
consultants
2-2B
Raleigh, NC June 2024
500
450
400
350
I
Q
300
a�
Ica
�
0 250
—
I
—
200
—
150
100
—
—
50
0
0
-
N N N N N N N N N N N N N N N N N N
N
N N N N
c\-I LLn m M .\-I LLn a N L\D O 00 N �.O\-I LLn a)
M
�\-I LLn 01
N N N \ \ c-I rl r-i N N \ \ \
\ \ \ \ \ N N \ \ \ \ \ M M M
c 1
\
c-I N N N
\ \ \ \
rl ci ci c-I c-I N N N N N
M
M M M M
Legend
Measured Discharge Flowrate Pumping Flowrate
p FTC off, no flow
0 Cape Fear River Above Discharge Weir
Notes:
FTC Discharge Flowrate
gpm - gallons per minute
(Jan - Mar 2024) - Seep C
Batch mode (in which the FTC is closed to flow due to dry conditions) is designated with orange shading.
Chemours Fayetteville works
This figure depicts two types of processing: (1) Passive flow through the system is calculated using the Effluent Stilling Basin transducer data (solid green). (2) Periodically during batch mode, the
Fayetteville, North Carolina
impoundment was pumped into the filter beds through a flowmeter skid; the approximate flow rate during intermittent pumping is shown with blue diamond symbols.
Geosynt onsultants of NC, P.C. Figure
CNo.:C3500andC295
From Jan. 10 to 17 and March 30 to 31, 2024, the Cape Fear River rose above the elevation of the discharge weir (W3), and head differentials throughout the flow -through cell were reduced
NCL nsetec
and flow through the system was hindered (pink shading). See section 2.3.5 for more details.
consultants nts
2-2C
FTC - Flow -Through Cell
Raleigh, NC June 2024
200
180 -
160 -
140
a
120 —
a-
cv
L
0 100
LL N
80 PI
60
40
20 — —
0
N rV fV N N N N N N N N N N N N N N N N N N N N
\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \
rl Ln Ol M r" ri Ln a) rV l0 O 00 N l0 r-I Ln Ol M Ln 61
\ \ \ r I c I N N (V \ \ c I c I r N N \ \ \ r-I —I N N N
N N \ \ \ \ \ M M M \ \ \ \ \
r-I r-I ri r-I r-I N N N N N M M M M M
Legend
Measured Discharge Flowrate
p FTC off, no flow
p Cape Fear River Above Discharge Weir Elevation
Notes: FTC Discharge Flowrate
gpm - gallons per minute (Jan - Mar 2024) - Seep D
Batch mode (in which the FTC is closed to flow due to dry conditions) is designated with orange shading. Chemours Fayetteville works
This figure depicts the measured discharge flowrate (solid green) of water processed through the filter beds calculated using the Effluent Stilling Basin transducer data. Fayetteville, North Carolina
From Jan. 10 to 18 and March 29 to 31, 2024 the Cape Fear River rose above the elevation of the discharge weir (W3), and head differentials throughout the flow -through cell were reduced
and flow through the system was hindered (pink shading). See section 2.3.5 for more details. GeOonsuIt nts NCLimseNo, C[3500 �dC25 Figure
FTC - Flow -Through Cell consultants
2-2D
Raleigh, NC June 2024
25 1 9
20
0
0
N
N
N
N
N
N
O
O
O
O
O
O
N
N
N
N
N
N
�
-0
-0
-0
-0
9
E
E
Q
4-U
O
>
U
Q
O
a)
O
Z
Ln
N
N
N
N
N N
N
N
N
N
N N
O
O
O
O
O O
N
N
N
N
N N
L
Z3
L
:3
U
L
a
f0 C
LL
Legend
Monthly Total Volume Treated by the Flow -Through Cells (FTCs)
N
N
N
N
N
N
N
N
N
N
N
N
O
O
O
O
O
O
N
N
N
rq
N
N
-0
-0
-0
-0
tto
E
9
E
E
Q
U
a
>
U
O
O
O
Z
0
Ln
USGS Precipitation (monthly totals)
M
M
M
M
M
M
N
N
N
N
N
N
O
O
O
O
O
O
N
N
N
N
N
N
a
LL
Notes:
The FTCs at Seeps A, B, C, and D became operational by late June 2021. This figure represents the monthly total volume treated by the FTCs beginning July 2021.
Precipitation data obtained from USGS gauge #02105500 at the William O. Huske Lock and Dam.
The barrier wall test panel was installed December 2022, and the remainder of the wall was installed from February through June 2023.
M
M
M
M
M
M
N
N
N
N
N
N
O
O
O
O
O
O
N
N
N
N
N
N
-0
-0
-0
tto
9
E
E
Q
U
4-
O
>
U
Q
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O
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N N N
O O O
N N N
L L
io fB L
LL
IV
7
V
5 �
ti
2
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47
46
-
45
-
-
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00 44
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-
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C: 42
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LJ1
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.
. ....
. .......n
. .
........
. .............
. .
.....
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............
......
. .
.....
...
................... .
. . .
........ ........
..
. .............
.
............ ..
... .
40
-
39
38
v v v v v v v v
N N N N N N N N N N N N N N N N N N N
N N N N
r\-I Ln M M l" a\ -I Ln M N � O 00 N l\D .\-1 Ln M M
r" a\ -I M Ql
\ \ \ 1-1
\ \ \ \ \ N N \ \ \ \ \ M M M \
-1 N N N
\ \ \ \
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M
M M M M
2
v 1.5
— —
—
c
0
a 1
'v
v 0.5
n
�
0
-
Legend
Influent Chamber/Impoundment Water Elevation 0 USGS Precipitation (daily totals)
Impoundment Water Elevation Above Bypass Spillway 0 FTC Off, no flow
Bypass Spillway Elevation 0 Cape Fear River Above Spillway
FTC Influent Water Elevation
Notes:
(Jan - Mar 2024) - Seep A
Batch mode (in which the FTC is closed to flow due to dry conditions) is designated with orange shading.
Chemours Fayetteville works
This figure depicts the influent transducer data that was collected during the reporting period (blue line). Instances of impoundment bypass flow are shown as an orange line.
Fayetteville, North Carolina
Between Jan. 11 and Jan. 16, 2024, the Cape Fear River rose above the elevation of Bypass Spillway, causing the influent and effluent water elevations to be equal, and consequently
ceasing any
flow through the system (pink shading). See section 2.3.5 for more details regarding impacts of river flooding.
GeOSynteCD GeosyntecConsultantsofNC,P.C. Figure
Precipitation data obtained from USGS gauge #02105500 at the William O. Huske Lock and Dam.
consultants NC license No.: C 3500 and C 295
FTC - Flow -Through Cell
2-4A
Raleigh, NC June 2024
47
46
45
00
00
0
Q
44
z
43
c
0
42
w
41
40
39
.. ..............
I _
.. .......................................................
I
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...................
...................
.
.............
v
It
v
ItT
'
'T
Kt
'T
�t
Kt
Kt
�t
�t
Kt
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v
v
qzt
IZT
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
\-I
Lr)
O\1
M
N
-1
Y)
Ql
N
l\O
O
0000
N
kD
—i
Ln
O\1
M
N
c\-I
u\i
Ol
N
N
N
\
\
i--I
c-I
1
N
N
\
\
\
1
1
N
N
N
\
\
\
\
\
N
N
\
\
\
\
\
m
m
M
\
\
\
\
\
c-I
c-I
c-I
c-I
rl
N
N
N
N
N
M
M
M
M
M
2
1.5
o_
}'
1
.Q
0.5
a
0
Legend
Influent Chamber/Impoundment Water Elevation USGS Precipitation (daily totals)
Impoundment Water Elevation Above Bypass Spillway p FTC Off, no flow
••• Bypass Spillway Elevation 0 Cape Fear River Above Spillway
Notes:
Batch mode (in which the FTC is closed to flow due to dry conditions) is designated with orange shading.
This figure shows the influent transducer data that was collected during the reporting period (blue line). Instances of impoundment bypass flow are shown as an orange line.
Between Jan. 11 and Jan. 16, 2024, the Cape Fear River rose above the elevation of the Bypass Spillway, causing the influent water elevations to be equal, and consequently ceasing any flow through the
system (pink shading). See section 2.3.5 for more details regarding impacts of river flooding.
Precipitation data obtained from USGS gauge #02105500 at the William O. Huske Lock and Dam.
FTC - Flow -Through Cell
M
49
47
00
45
a
z
43
c
O
+1
ca
a, 41
w
39
37
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
-1
Ln
Ql
M
r,
c\-I
Ln
M
N
l\D
O
00
N
l\D
1
Ln
Ql
M
-1
Ln
Ol
N
N
N
\
\
r-I
r-I
r-I
N
N
\
\
\
i i
-I
N
N
N
N
N
\
\
\
\
\
M
M
f"n
\
\
\
\
\
r-I
r-I
r-I
r-I
r-I
N
N
N
N
N
M
M
M
M
M
Legend
Influent Chamber/Impoundment Water Elevation p USGS Precipitation (daily totals)
Impoundment Water Elevation Above Bypass Spillway p FTC Off, no flow
••• Bypass Spillway Elevation p Cape Fear River Above Spillway
Notes:
Batch mode (in which the FTC is closed to flow due to dry conditions) is designated with orange shading.
This figure shows the influent transducer data that was collected during the reporting period (blue line). Instances of impoundment bypass flow are shown as an orange line.
Between Jan. 11 and Jan. 16, 2024, the Cape Fear River rose above the elevation of the Bypass Spillway, causing the influent and effluent water elevations to be equal, consequently ceasing any
flows through the system (pink shading). See Section 2.3.5 for more details regarding impacts of river flooding.
Precipitation data obtained from USGS gauge# 02105500 at the William O. Huske Lock and Dam.
FTC - Flow -Through Cell
46
45
44
e0
00
0 43
Q
z
,} 42
c
O
41
a�
w
40
39
38
. . . . . . . . . . . . . . . . . . . . . . . . . . . . V* ............ ........ *- .............. 1 ..................... .........
TT
1�11
Itt
v
IZT
I:t
1:t
v
�t
't
�t
1:T
�t
IZT
Zt
Ict
1:t
N
N
N
N
N
N
N
[V
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
c\i
u'1
M
M
n
.\-I
Ln
01
N
l\o
O
00
N
to
M
M
M
.\-I
Ln
O1
\
\
\
I
I
N
N
N
\
\
I
cI
I
N
N
\
\
\
I
I
N
N
N
I
I
I
I
I
N
N
N
N
N
M
M
M
M
M
Legend
Influent Chamber/Impoundment Water Elevation USGS Precipitation (daily totals)
Impoundment Water Elevation Above Bypass Spillway p FTC Off, no flow
••• Bypass Spillway Elevation 0 Cape Fear River Above Spillway
Notes:
Batch mode (in which the FTC is closed to flow due to dry conditions) is designated with orange shading.
This figure shows the influent transducer data that was collected during the reporting period (blue line). Instances of impoundment bypass flow are shown as an orange line.
Between Jan. 11 and Jan. 16, 2024, the Cape Fear River rose above the elevation of the Bypass Spillway, causing the influent and effluent water elevations to be equal, and consequently, ceasing any flow through
the system (pink shading). See Section 2.3.5 for more details regarding impacts of river flooding.
Precipitation data obtained from USGS gauge# 02105500 at the William O. Huske Lock and Dam.
FTC - Flow -Through Cell
43
42
00 41
00
Q
Z 40
0
39
a�
w
38
37
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ....... ] ..................... ..... .... 1.
---------------------- ----- t --------------- P ----- I ----- T -------
fV
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
rV
N
N
N
N
N
N
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
rl
Ln
O1
M
r"
c-I
Ln
Ol
N
l0
O
00
N
LO
rl
Ln
Q1
M
Ln
Ql
N
N
N
\
\
-I
-I
r-I
N
N
\
\
\
r-I
r-I
N
N
N
\
\
\
\
\
N
N
\
\
\
\
\
M
M
M
\
\
\
\
\
ci
ci
ci
c-I
r-I
N
N
N
N
N
M
M
M
M
M
2
1.5
0
Q
v o.s n n
IIII
0
Legend
Staff Gauge Water Elevation 0 USGS Precipitation (daily totals)
Inlet Weir Elevation p FTC Off, no flow
••• Bypass Spillway Elevation 0 Staff Gauge Inundated
Notes:
Batch mode (in which the FTC is closed to flow due to dry conditions) is designated with orange shading.
This figure shows the daily staff gauge water elevation that was collected during the reporting period (green line). The staff gauge was inundated during elevated water levels in January and
March (pink shading).
Precipitation data obtained from USGS gauge #02105500 at the William O. Huske Lock and Dam.
FTC - Flow -Through Cell
43
42
00
41
Q
z
e 40
C
0
+1
> 39
aJ
w
38
A"*"** ... 1 **"****l***************.*********** .... F, ... ""*'***'I***"*""'* -*I"**"** ... * ... .... 1.1 1
37
. 1
..
N
N
N
N
fV
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
c\i
Ln
Ql
M
c\-I
Ln
M
N
l0
O
00
N
c\-I
Ln
01
M
c\-I
L!
Q1
\
\
\
.-I
rI
N
N
N
\
\
rI
I
rI
N
N
\
\
\
rI
. I
N
N
N
\
\
\
\
\
N
N
\
\
\
\
\
M
M
M
\
\
\
\
\
c-I
ci
ri
-1
-1
N
N
N
N
N
M
M
M
M
M
2
1.5
c
0
}'
ca
1
.Q
U
0.5
a
0
Legend
Staff Gauge Water Elevation p USGS Precipitation (daily totals)
Inlet Weir Elevation = FTC Off, no flow
••• Bypass Spillway Elevation 0 Staff Gauge Inundated
Notes:
Batch mode (in which the FTC is closed to flow due to dry conditions) is designated with orange shading.
This figure shows the daily staff gauge water elevation data that was collected during the reporting period (green line). The staff gauge was inundated during elevated water levels in
January (pink shading), and water elevations could not be collected.
Precipitation data obtained from USGS gauge #02105500 at the William O. Huske Lock and Dam.
FTC - Flow -Through Cell
43
42
00 ...... .... .. ........... ............................. ........... ...... ... .......... ..... ..... ... ... ........... ........... ....... ........ .. .. . . . . . . . .. .. .. . . . . . . .. . . . .
00
41
a \z
40 — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — r — — — — — — — — — — — — — —
0
w
39
38 - —
37
N N N N N N N N N N N N N N N N N N N N N N N
\-I Ln a) M r, c\-I Ln al N l\O O 00 N l\D c 1 Ln a) M I� c\-I Ln Ol
N N \ \ r-I r-I r-I N N \ \ \ i i -I N N N
N N \ \ \ \ \ M M f"n \ \ \ \ \
r-I r-I r-I r-I r-I N N N N N M M M M M
2
C
1.5 — — --
c
0
}' 1 — — —
CU
.Q
0.5 — --
a
n
Legend
Staff Gauge Water Elevation p USGS Precipitation (daily totals)
Inlet Weir Elevation p FTC Off, no flow
••• Bypass Spillway Elevation 0 Staff Gauge Inundated
Notes:
Batch mode (in which the FTC is closed to flow due to dry conditions) is designated with orange shading.
This figure shows the daily staff gauge water elevation data that was collected during the reporting period (green line). The staff gauge was inundated during elevated water levels in January
and March (pink shading), and water elevations could not be collected.
Precipitation data obtained from USGS gauge# 02105500 at the William 0. Huske Lock and Dam.
FTC - Flow -Through Cell
43
42
41
00
\o
z 40
0 39
c�
a�
w
38
37
I . • •1 • • • • • • • • • • • • • I 1 • • • • • • • • • • • P •1, • .1 . • • • • • • • • • • • • • • • • • • • • • • • • • • • • . . . . . . . . . . . . . . M • • • • • • • • • • • • .1 • • • • • • • • • • • • • • • • • • • • • • • • • • •1• • • • • • • • • • • • • • • • • • • • • 4 • • • • • • • • • • • • • • • • • • •1• • • • • • • • • • • • • 4 • • • • •1
ICT
It
It
It
1;T
1:T
171-
'T
'T
It
�t
It
It
t
K
�t
It
It
It
It
N
N
N
fV
fV
N
N
N
N
N
N
/V
(V
N
[V
N
N
N
N
N
N
N
N
LLn
Ol
M
N
.\-I
Ln
a)
N
l\O
O
0000
N
l.D
.\I
Lf
M
M
N
c\-I
LLn
Ol
\
\
\
cI
I
N
N
N
\
\
I
I
cI
N
N
\
\
\
-1
I
N
N
N
\
\
\
\
\
N
N
\
\
\
\
\
M
M
M
\
\
\
\
\
N
N
N
N
N
M
M
M
M
M
Legend
Staff Gauge Water Elevation
-- Inlet Weir Elevation
••• Bypass Spillway Elevation
USGS Precipitation (daily totals)
p FTC Off, no flow
p Staff Gauge Inundated
Notes:
Batch mode (in which the FTC is closed to flow due to dry conditions) is designated with orange shading.
This figure shows the daily staff gauge water elevation data that was collected during the reporting period (green line). The staff gauge was inundated during elevated water levels in January
(pink shading), and water elevations could not be collected.
Precipitation data obtained from USGS gauge# 02105500 at the William 0. Huske Lock and Dam.
FTC - Flow -Through Cell
500,000
450,000
-
400,000
-
350,000
J
dA
300,000
—
0
250,000
U
C
0
U
a 200,000Va..
'
�
a
+�
` J
V
(D 150,000
100,000
50,000
0
O . -I
N N
r-I r-I r-I r-1 r 1 N N N N
N N N N N N N N N
N N M M M
N N N N N
M
N
M M R
N N N N
N
f
O
0
0
Q 1..L Q
0 1..L
Q
Legend
Seep A Influent
Seep B Influent Seep C Influent _ Seep D Influent -••
Monthly Average of Seep A, B, C, and D Influent
Notes:
FTC Influent PFAS Concentrations
The FTCs at Seeps A, B, C, and D all became operational by late June 2021. This figure represents the monthly influent concentration of Total
Table 3+ PFAS (17+ compounds).
The barrier wall test panel was installed December 2022, and the remainder of the wall was installed from February through June 2023.
Chemours Fayetteville works
FTC - flow through cell
Fayetteville, North Carolina
GeosyntecO Geosynt ..ad,ann,d. , z Figure
COr1Sl11t3TItS NCLicense Nn:C 3500 and 295
2-6
Raleigh, NC June 2024
.11
500
400
a)
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v
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a
a)
�a
200
E
Z)
U
100
M
c-I
i -I
r -I
r -I
r -I
�I
N
N
N
N
N
N
N
N
N
N
N
N
M
M
M
M
M
M
M
M
M
M
M
M
d'
Itt Itt
N
N
cV
fV
N
N
N
N
N
cV
N
N
N
N
N
N
N
N
N
N
N
(N
N
N
N
N
N
(N
N
N
cV
fV N
O
O
O
O
O
O
O
O
O
O
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O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
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N
fV
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
fV
N
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N
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N
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v
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L
a
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ca
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z
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z
v;
z
Legend
Cumulative PFAS Removed (Ibs)
Notes:
The FTCs at Seeps A, B, C, and D became operational by late June 2021. This figure presents the cumulative pounds (Ibs) of PFAS removed by the FTCs beginning July 2021.
Total Ibs of PFAS removed is calculated for Total Table 3+ (17 Compounds).
The barrier wall test panel was installed December 2022, and the remainder of the wall was installed from February through June 2023.
NO
rol
Legend
$
Surficial Aquifer
Floodplain Deposits
Black Creek Aquifer
Black Creek Aquifer
Extraction Well
Surficial Aquifer Extraction
Well
Surficial and Black Creek
Aquifer Extraction Well
0
Willis Creek Stilling Well
OW-31
OW-32
OW-38
, A�4
OW-39 0-51
OW-29 OW-37 \` O
O.Ws26
OW-4R 1 OW-49
OW-50 OW-25
OW-40
OW-9R
ow-28 �r
OW-33
00
Hydraulic Head
Observation (Existing Well)
Hydraulic Head
O Observation (New
Observation Well - Black
Creek Aquifer)
Hydraulic Head
Observation (New
Observation Well - Surficial
Aquifer)
Site Boundary
Forcemain
Barrier Wall; approximate surface
elevation at 72 ft NAVD88
®Groundwater Treatment
Pad
Ground Surface Elevation Contour
(ft NAVD88) - 10 feet interval
— — — Seep
Nearby Tributary
Nearby Tributary to River
Cape Fear River
MEN
OF WAIL
OW-53 ■.�
1 ;■ pl
OW-46 `
OW-20 pIW-5SR
OW-22 OW-52 PW-10RR �;
OW-47 � V
Notes:
ft NAVD88 - feet North American Vertical Datum 1988.
1. Some wells have been offset for visibility. Therefore, the placement of wells on this map do not
reflect their true geographic coordinates.
2. Ground surface elevation contours are based on 20-foot DEM grid cells generated from LiDAR.
Data from NC OneMap (https://assets.nconemap.gov/pages/hub/ncom-contours-dd.htm).
3. The outline of Cape Fear River is approximate and is based on open data from ArcGIS
Online and North Carolina Department of Environmental Quality Online GIS
(MajorHydro shapefile).
4. Basemap source: Esri, Maxar, Earthstar Geographics, and the GIS User Community
M&M
1,000
OW-42
OW-56
OW-12
OW-55
500 0
o b O
1,000 Feet
Hydraulic Head Evaluation Network
for Groundwater Remedy
Chemours Fayetteville Works, North Carolina
Ge o syn to c l�-' Geosyntec Consultants of NC, P.C. consultants Figure
NC License No.: C-3500 and C-295
6-1
Raleigh, NC June 2024
I—P
1
Transect la Transect 1b
44 44
61
56
42 42
51
• 46
40 OW-39 PW-11 40 OW-39
{ OW-40
38
0 100 200 300
f 1/31/2024 --6-2/27/2024
400
--0-3/27/2024
38 L
500 0
1a
f+ �iL• PW-11
.r
Legend
Black Creek Aquifer Well
Forcemain
Completed Barrier Wall (as of June 11, 2023)
Site Boundary
Seep
Nearby Tributary to River
Hydraulic Gradient Transect
® Groundwater Treatment Pad
Cape Fear River
1b
100 200 300 400 500
1/31/2024 2/27/2024 3/27/2024
OW-38
OW-39
0
W-30
Transect 2
PIW-10DR
OW-30 OW-33
36 L
0 100 200 300 400 500 600
600
Baseline Dry Baseline Wet --0--1/31/2024 t2/27/2024 --*--3/27/2024
Charts Legend
48
i"
46
Q
Z
w 44
v
0 42
w 40
!% 38
v
3 36
0
34
z
P
0 100 200 300 400 500
OW-26
Distance from Remedy
Gauging Event Date
Notes:
OW=50.
1. Elevation data from the gauging events of August 17, 2022 and January 30,
2023 are represented in the charts as Baseline Dry and Baseline Wet, respectively.
Only for PIW-10DR, elevation data from gauging event of August 4, 2022 is
considered as Baseline Dry.
2. Baseline data are not available for OW-39 and OW-40 due to the installation of
the barrier wall, and in PW-11 due to pumping as ppart of the interim groundwater
remedy. The nearest available baseline data m EWs 63-65 as well as PIW-10DR to
the east indicate the baseline elevation in this vicinity ranged from -59-64 feet
NAVD88.
3. Some observation wells have been offset for visibility. Therefore, the placement
of these wells on this map do not reflect their true geographic coordinates.
4. The outline of Cape Fear River is approximate and is based on open data from
ArcGIS Online and North Carolina Department of Environmental Quality Online GIS
(MajorHydro shapefile).
5. Basemap sources: Esri, Maxar, Earthstar Geographics, and the GIS User
_ OW 27
Community.
200 100 0 200 Feet
i Southern Alignment -
I Downgradient Groundwater Transects
OW-28 Chemours Fayetteville Works, North Carolina
Ge o synte c O Geosyntec Consultants of NC, P.C. consultants Figure
NC License No.: C-3500 and C-295
Fear Riuer 6-2A
Raleigh, NC June 2024
-- , • — Z
Transect 3 Transect 4 Transect 5
46 46 46
44 44 44
i
42 42 42 07
40 40 40
OW-50 OW-27 `
OW-28
OW-49 OW-25 38 OW-48 OW-23 PIW-7D
38 38
LTW-05
36 36 36
0 100 200 300 400 500 0 100 200 300 400 500 0 100 200 300 400 500
Baseline Dry Baseline Wet --o-1/31/2024 t2/27/2024 t3/27/2024 Baseline Dry Baseline Wet —0-1/31/2024 —0-2/27/2024 t3/27/2024 Baseline Dry Baseline Wet t1/31/2024 --*--2/27/2024 --*--3/27/2024
1 i- I J
Charts Legend
OW-38 _
h 48
Y T � 46
! J Q
Z
w 44
w
Z 42
0
■;k1 a�i 40 —�
rw
t i � 38
3
v
36
OW-29 h ' � - -
OW-24 34
0 100 200 300 400 500
Y Distance from Remedy
}� _ , `� - tGauging Event Date ,
OW-26 OW-48
PIW-10DR
Notes:
1. Elevation data from the gauging events of August 17, 2022 and
- OW-49 Nt pyy-23 January 30, 2023 are represented in the charts as Baseline Dry and
OW-50 Baseline Wet, respectively.
2. Some observation wells have been offset for visibility. Therefore, the
placement of these wells on this map do not reflect their true geographic
OW-25 5 coordinates.
3. The outline of Cape Fear River is approximate and is based on open
' data from ArcGIS Online and North Carolina Department of
Environmental Quality Online GIS (MajorHydro shapefile).
4. Basemap sources: Esri, Maxar, Earthstar Geographics, and the GIS
OW-30 ❑ User Community.
3 4=
- PIW-7D
OW-27 200 100 0 200 Feet
Legend
Black Creek Aquifer Well
Forcemain Southern Alignment -
Completed Barrier Wall (as of June 11, 2023) LTW-05 Downgradient Groundwater Transects
� Site Boundary
Chemours Fayetteville Works, North Carolina
Seep
Hydraulic Gradient Transect OW-28
® Groundwater Treatment Pad Geosyntec
Cape Fear River _ ape Fear River consultants GeosyntecConsultantsofNC,P.C.
NC License No.: C-3500 and C-295 Figure
C
- 6-2B
Raleigh, NC I June 2024
Transect 6a
46 46
r
44 44
42 42
40 — 40
OW-47 OW-22 PZ-22
38 38
36 36
0 100 200 300 400 500 0
2
Baseline Dry Baseline Wet --*--1/31/2024 --0--2/27/2024 t3/27/2024
t
OW-8 hh
OW-7 Y*
i
OW-24
� OW-23
Legend
Black Creek Aquifer Well
Forcemain
Completed Barrier Wall (as of June 11, 2023)
Site Boundary
Seep
Hydraulic Gradient Transect
® Groundwater Treatment Pad
Cape Fear River.4
100
1/31/2024
1
OW-21
OW-53
Transect 6b
200 300 400
--*-2/27/2024 --0-3/27/2024
— — r z
Transect 7
48
46
44
42
OW-46 OW-20
40 �♦
38
36
500 0 100 200 300 400 500
Baseline Dry Baseline Wet --0--1/31/2024 --0-2/27/2024 --0-3/27/2024
Charts Legend
�v
9
48
46
Q
Z
w 44
v
0 42
w 40
38
3
v
3 36
0
34
I AF 0 100 200 300 400 500
Distance from Remedy
OW-46 --*--Gauging Event Date
Notes:
1. Elevation data from the gauging events of August 17, 2022 and
t
January 30, 2023 are represented in the charts as Baseline Dry and
F
Baseline Wet, respectively.
2. Some observation wells have been offset for visibility. Therefore, the
placement of these wells on this map do not reflect their true geographic
coordinates.
0
3. The outline of Cape Fear River is approximate and is based on open
data from ArcGIS Online and North Carolina Department of
Environmental Quality Online GIS (MajorHydro shapefile).
4. Basemap sources: Esri, Maxar, Earthstar Geographics, and the GIS
P ,
User Community.
t
200 100 0 200 Feet
Southern Alignment -
Downgradient Groundwater Transects
Chemours Fayetteville Works, North Carolina
- G e o syn to c l�- Geosyntec Consultants of NC, P.C. Figure
consultants F In u re
NC License No.: C-3500 and C-295 y
6-2C
Raleigh, NC June 2024
Transect 8
48
46
44
42
40
OW-45 PI W-4D LTW-02
38
36
0 100 200 300 400 500
Baseline Dry Baseline Wet t1/31/2024 t2/27/2024 --0-3/27/2024
OW-2 OW-3
OW-18
•
* 19 PW-10RR--'OW-45` �
OW-� ,
.OW-46
Legend
Black Creek Aquifer Well
Forcemain
Completed Barrier Wall (as of June 11, 2023)
Site Boundary
Seep
Hydraulic Gradient Transect
Cape Fear River
1 11 1 — I . U.I*
- w _,Mir Z
f.Z {
Transect 9 - �► 1
—�
OW 44
OW-16
0 100 200 300 400 500
—Baseline Dry Baseline Wet --*--1/31/2024 --*--2/27/2024 t3/27/2024
PIW-2D
O14-15,-.Wr
T
OW-16
i s i J #
OL
' r
■ ,
a F 1
OW-43
OW-13
- . 1
Charts Legend
48
i"
Q 46
Q
Z
w 44
v
0 42
w 40
38
4 3
3 36
0
34
0 100 200 300 400 500
Distance from Remedy
t Gauging Event Date
Notes:
1. Elevation data from the gauging events of August 17, 2022 and
January 30, 2023 are represented in the charts as Baseline Dry and
Baseline Wet, respectively.
2. Some observation wells have been offset for visibility. Therefore, the
placement of these wells on this map do not reflect their true geographic
coordinates.
3. The outline of Cape Fear River is approximate and is based on open
data from ArcGIS Online and North Carolina Department of
Environmental Quality Online GIS (MajorHydro shapefile).
4. Basemap sources: Esri, Maxar, Earthstar Geographics, and the GIS
User Community.
200 100 0 200 Feet
FM
Southern Alignment -
Downgradient Groundwater Transects
Chemours Fayetteville Works, North Carolina
Ge o syn to c l�-' Geosyntec Consultants of NC, P.C.
consultants Figure
NC License No.: C-3500 and C-295
6-2D
Raleigh, NC June 2024
Transect 1 Transect 2
—OW-26 —OW-50 —OW-27 —OW-24 —OW-48 —OW-23
44
43
00
p 42
a
Z 41
4 40
v 3
v 9
38
37
41
39
0 37
Z 35
c 33
0
> 31
v
UJ
29
ti 27
i
1/1/2024 1/11/2024 1/21/2024 1/31/2024 2/10/2024 2/20/2024 3/1/2024 3/11/2024 3/21/2024 3/31/2024 L 25
1/1/2024 1/11/2024 1/21/2024 1/31/2024 2/10/2024 2/20/2024 3/1/2024 3/11/2024 3/21/2024 3/31/2024
46
46
44
p 42
Q 40
Z 38
36
34
> 32
N
ai 30
28
44
o az
Q 40
z 38
36
34
M
N32'] *' 1111111111''. ''. .............
a 30
28
1/1/2024 1/11/2024 1/21/2024 1/31/2024 2/10/2024 2/20/2024 3/1/2024 3/11/2024 3/21/2024 3/31/2024 1/1/2024 1/11/2024 1/21/2024 1/31/2024 2/10/2024 2/20/2024 3/1/2024 3/11/2024 3/21/2024 3/31/2024
—Cape Fear River —Cape Fear River
Legend
Black Creek Aquifer Well
Forcemain
Completed Barrier Wall (as of June 11, 2023)
Site Boundary
— •
Seep
Nearby Tributary to River
Dampening Analysis Transect
®
Groundwater Treatment Pad
Cape Fear River
s. OW-7 Notes:
_ 1. Gap in elevation data for OW-23 is due to malfunctioning of the
installed transducer.
OW-29 2. Groundwater elevation in observations wells downgradient of the
OVV-24 barrier wall is susceptible to fluctuations in Cape Fear River
elevation, thereby influencing the downgradient groundwater
I n transects.
3. Some observation wells have been offset for visibility. Therefore,
OW-26 the placement of these wells on this map do not reflect their true
OW-48 geographic coordinates.
- 2 4. The outline of Cape Fear River is approximate and is based on
OW-49 open data from ArcGIS Online and North Carolina Department of
11111111111 } 4 r 0W-23 Environmental Quality Online GIS (MajorHydro shapefile).
h W 50 - 5. Basesources: Esri, Maxar, Earthstar Geographics, and the
OW-25 GIS Userr Community.
JAW
` 1 all 250 125 0 250 Feet
OW-30
PIW-7U
oW-27 Southern Alignment -
Dampening Analysis Transects
- LTW-05 Chemours Fayetteville Works, North Carolina
Ge o syn to cl�-' Geosyntec Consultants of NC, P.C. Figure
consultants F i g u re
NC License No.: C-3500 and C-295
6-3A
Raleigh, NC I June 2024
Transect 3 Transect 4
—OW-7 —OW-47 —OW-22 — OW-46 —OW-20
41
39
00
00
0
Q 37
Z
35
O
N 33
ai
31
29 r=
1/1/2024 1/11/2024 1/21/2024 1/31/2024 2/10/2024 2/20/2024 3/1/2024 3/11/2024 3/21/2024 3/31/2024
46
44 n - -
00
00 42
Q 4°
Z 38
36
E O
34
_v 32
a 30
28
1/1/2024 1/11/2024 1/21/2024 1/31/2024 2/10/2024 2/20/2024 3/1/2024 3/11/2024 3/21/2024 3/31/2024
—Cape Fear River
•ti
it
91AV
y
4
t
OW-7
r • � � 5 ,
r .�
41
40.5
oo 40
00
0
Q 39.5
Z
39
O
38.5
v 38
37.5 -
37
1/1/2024 1/11/2024 1/21/2024 1/31/2024 2/10/2024 2/20/2024 3/1/2024 3/11/2024 3/21/2024 3/31/2024
46
44
00 42 -
0
Q 40
Z 38
36
O
34
' 32
6
30
28
1/1/2024 1/11/2024 1/21/2024 1/31/2024 2/10/2024 2/20/2024 3/1/2024 3/11/2024 3/21/2024 3/31/2024
—Cape Fear River
00,
CO)
�t* OW-3
IF 0—W-21
OW-19 PW-10RR
OW-8 1
- 3 '
OW-47 Ar
OW-2,
ih
Ae
1-00
OW 46 y
OW-20OP I
�
"I _
. Y'U. 7W
Legend
Black Creek Aquifer Well
Forcemain
Completed Barrier Wall (as of June 11, 2023)
Site Boundary
• Seep
Dampening Analysis Transect
■ Cape Fear River
Notes:
1. Groundwater elevation in observations wells downgradient of the
barrier wall is susceptible to fluctuations in Cape Fear River
elevation, thereby influencing the downgradient groundwater
transects.
2. Some observation wells have been offset for visibility. Therefore,
the placement of these wells on this map do not reflect their true
geographic coordinates.
3. The outline of Cape Fear River is approximate and is based on
open data from ArcGIS Online and North Carolina Department of
Environmental Quality Online GIS (MajorHydro shapefile).
4. Basemap sources: Esri, Maxar, Earthstar Geographics, and the
GIS User Community.
250 125 0 250 Feet
Southern Alignment -
Dampening Analysis Transects
Chemours Fayetteville Works, North Carolina
Ge o syn to c l> Geosyntec Consultants of NC, P.C. Figure
nsultants
NC License No.: C-3500 and C-295
o
#FearRiver RCal,igh, NC June 2024 6-3B
rn� Z
Transect 5
—OW-45 —PIW-4D LTW-02
43
42
oo
a
Q 41 -
. Z
c 40
0
a� 39
38
- 37
1/1/2024 1/11/2024 1/21/2024 1/31/2024 2/10/2024 2/20/2024 3/1/2024 3/11/2024 3/21/2024 3/31/2024
44
42
00
0 40
Q 38
Z
36
c
34
v 32
v
30
28
1/1/2024 1/11/2024 1/21/2024 1/31/2024 2/10/2024 2/20/2024 3/1/2024 3/11/2024 3/21/2024 3/31/2024
—Cape Fear River
Transect 6
—OW-44 —OW-16
38
37
00
0 36
Q
a
w 35
c
O
> 34
N I
N
33
32
1/1/2024 1/11/2024 1/21/2024 1/31/2024 2/10/2024 2/20/2024 3/1/2024 3/11/2024 3/21/2024 3/31/2024
46
44
oo 42
0
Q 40
z 38
c 36
O
Z 34
a 32
a
30
28
1/1/2024 1/11/2024 1/21/2024 1/31/2024 2/10/2024 2/20/2024 3/1/2024 3/11/2024 3/21/2024 3/31/2024
—Cape Fear River
PIW-2D
MW
- 0 - OW-15
x - f' #. OW-17
jo
OW-44
4
�+ OW-2
OW-3
hOW-18 -
Y 6
hPW-10RR
Y
ar
4
Legend
Black Creek Aquifer Well
Forcemain
Completed Barrier Wall (as of June 11, 2023)
Site Boundary
• Seep
Dampening Analysis Transect
Cape Fear River
Notes:
1. Gap in elevation data for OW-45 is due to malfunctioning of the
installed transducer.
2. Groundwater elevation in observations wells downgradient of the
barrier wall is susceptible to fluctuations in Cape Fear River
elevation, thereby influencing the downgradient groundwater
transects.
3. Some observation wells have been offset for visibility. Therefore,
the placement of these wells on this map do not reflect their true
geographic coordinates.
4. The outline of Cape Fear River is approximate and is based on
open data from ArcGIS Online and North Carolina Department of
Environmental Quality Online GIS (MajorHydro shapefile).
5. Basemap sources: Esri, Maxar, Earthstar Geographics, and the
GIS User Community.
250 125 0 250 Feet
r Southern Alignment -
Dampening Analysis Transects
Chemours Fayetteville Works, North Carolina
Ge o syn to c'% Geosyntec Consultants of NC, P.C. consultants Figure
NC license No.: C-3500 and C-295
6-3C
Raleigh, NC I June 2024
50
45
40
--
Willis Creek Flood
0
35
Q
z
s=
30
-
0
(10
>
a�
WON"
w
25
-
20
Pumping Mode
D_A -7oing Blade
Flamm Total �gal)
Flow Total (gal)
Well la
Pre -Flood
past-=1aad
Jan 3-9
Jan 10-16
55
Pumping lVlade pumping Mode
--,t-%r Total (gal)
Flow Total (gal)
50
45
00
00
0
a
40
z
°
Willis Creek Flood
a',
35
WAt
"Poo
30
TFIVII
AL
AL
IT1111"W)"ryll
lll.
lulh Il II J ,�IWII All ki 1,I�J 1016 n.
25
20
1/1/2024
1/6/2024 1/11/2024
1/16/2024
1/21/2024
1/26/2024 1/31/2024
Willis Creek Extraction Well Flood
Response: EW-06 through EW-10
Notes:
Chemours Fayetteville Works
Willis Creek elevation
data is from a transducer deployed in a locally installed stilling well,
converted to NAVD88.
Fayetteville, North Carolina
Extraction Well
(EW) level data is from transducer deployed in each well, converted to NAVD88.
Figure
Willis Creek and EW data both recorded at 15 minute frequency intervals.
Geosyntec° �osY��e��o�.w;.��o��C.PC
NC L;ce�se Na: C—.andC-
consultants
6-4B
Raleigh, NC June 2024
Well ID
Pre -Flood
post -Flood
=
Jan 3-9
Jan 10-16
EW-06
Continuous
Continuous
7�,513
79.53�
EW-07
Cycling i;�Q`j
Cycling � 61`J
14.787
��.9��
EVtif-OS
Cycling i; 78`J
Continuous
35,117
4�.015
Etiltif-09
Water Limited I;0`j
Water Limited 1;1`�
39
179
Etiltif-10
Cycling (9`j
Cycling l;�`�
�,�39
13r7
55
Pumping Mode Pumping Mode
FIo4f,+ Total (gal)
Flow Total (gal)
-Yrl;
:;',j
Legend
Black Creek Aquifer
Staff Gauge
Stilling Well
Extraction Well
R lA
OW-14
0.1
OW-41 \ OW-57
-2.54 -1.71
SW-5
1
1
N - PIW-11
1
1
0.49
- -2.17 \t
1
1
% \
1
% \
1
%` `
`
OW-56
\
0.07
1
\
0W-12 % % \
-o- SV\
1
-4.16 % 1
SG-4
1
% 1
\
1 J#
EW-04 % 1
1 � �
i
�
1
;'So
1
'SMW-12
� OW-55
1
1 ,
-4.74
-5.12
1 i
OW-43 \ PIW-13
1 1.93
-6.19
\ EW-09 '-5.5
w ub/
•
OW-13,
-1.5
/EW-10
EW 11 PIW-14 \ -
do
{�} \ J# -3.45 1
OW-54
SW-3E SG 3
�0
EW 12 e�
tvv-i4 j
PIW-1D•
0.36 I __/ Ca,
Notes:
January 2024 Elevation —Site Boundary 1. Elevation difference = monthly elevation - January 2023 elevation
Difference — 2. Elevation difference not calculated at locations where monthly
— Seep elevation or baseline January 2023 not available
Barrier Wall — Nearby Tributary 3. OW-54 dry in January 2024. Water assumed at bottom of screen in «� Z
Forcemain elevation difference calculation
Cape Fear River 4. Antecedent daily total rainfall (January 28-30): 0.02 inches
0 250
Feet
A
Northern Alignment
January 2023 - January 2024
Elevation Difference
Chemours Fayetteville Works, North Carolina
Ge o sMte c l> Geosyntec Consultants of NC, P.C. Figure
consultants NC License No.: C-3500 and C-295
6-5A
Raleigh, NC I April 2024
A-1
a
1
/
0
n
Legend
P. Black Creek Aquifer
Extraction Well
Staff Gauge
Stilling Well
s
a
2-ft January 2024 GW
- - Elevation
10-ft January 2024 GW
Elevation
Barrier Wall
4
' EW-02
' bW-42
i
,gyp ppt EWR
40
SOW-12 `
00,
EW.0,1 OV1
5'� PIW-1 =0
3ti 3
A OW=43
EW-10 EW-08 1 PIW-13 EW=06
' EW-0,
PIW-14
PIW-21D �' ,' f OW-13/' OW-54 �' / Sw-03
�.. , SW-02 SG-03
EW-12
/ SG-01
' EW-13
{ SW-01
I EW-141/%�, M�. PIW-15
�OW_14
2-ft January 2023 GW
Elevation
10-ft January 2023 GW
Elevation
Forcemain
0 250
Feet z
Site Boundary Notes:
Seep
Nearby Tributary 1. Antecedent daily total rainfall (January 28-30): 0.02
Inches
Cape Fear River 2. Surficial elevations at staff gauges and stilling wells
shown but not used for contouring of groundwater (GW)
elevations
Northern Alignment
Potentiometric Map
January 2023 - January 2024
Chemours Fayetteville Works, North Carolina
GeosyntecGeosyntecConsultants ofNC.P.C. Figure
consultants NC License No.: C-3500 and C-295
6-6A
Raleigh, NC April 2024
LI
t
Legend
P. Black Creek Aquifer
Extraction Well
Staff Gauge
Stilling Well
s
a
�E
OW-. 1
a6 EV 021 11
OW-42 ;
EW-03
-38- — — , — — -OW-5
OW-12
' Ao- OW-55
3� SMW-12, ' PIW-12
08 11 PIW 1
W-EW-06 EW-05
PIW=14 EW-07
SW-03
33.28
V-54 s�-os
-A:-4.
2-ft February 2024 GW
- - Elevation
10-ft February 2024 GW
Elevation
Barrier Wall
2-ft January 2023 GW
Elevation
10-ft January 2023 GW
Elevation
Forcemain
0 250
Feet z
Site Boundary Notes:
Seep
Nearby Tributary 1. Antecedent daily total rainfall (February 24-26): 0.02
inches
Cape Fear River 2. Surficial elevations at staff gauges and stilling wells
shown but not used for contouring of groundwater (GW)
elevations
Northern Alignment
Potentiometric Map
January 2023 - February 2024
Chemours Fayetteville Works, North Carolina
GeosyntecGeosyntecConsultants ofNC.P.C. Figure
consultants NC License No.: C-3500 and C-295
6-6B
Raleigh, NC April 2024
1.
1
40 /
E
J
0 / v
0
w`
N
Legend
P. $ Black Creek Aquifer
4 Extraction Well
Staff Gauge
Stilling Well
s
a
4
1
O '
,
' EWE03
-38
34
_. •� O
2-ft March 2024 GW
- - Elevation
10-ft March 2024 GW
Elevation
Barrier Wall
V
OW-12
PIW12,
EW-0`
/ OW=43 ' PIW-13
/ / / • EW=10/ EW-08 i > EW= 6
EW-09
�O/W--13 . — PIW=14 EWv.07 sw o3 -
PIW-21D ' / / / / �/ EW-1,1 SW-02 33.35
SG-02 " OW-54 SG-03
/
EW-12
// SG-01
SW-01
PIW-15
2-ft January 2023 GW
Elevation
10-ft January 2023 GW
Elevation
Forcemain
0 250
Feet z
Site Boundary Notes:
Seep
Nearby Tributary 1. Antecedent daily total rainfall (March 24-26): 0.00 inches
2. Surficial elevations at staff gauges and stilling wells
Cape Fear River shown but not used for contouring of groundwater (GW)
elevations
Northern Alignment
Potentiometric Map
January 2023 - March 2024
Chemours Fayetteville Works, North Carolina
GeosyntecGeosyntecConsultants ofNC.P.C. Figure
consultants NC License No.: C-3500 and C-295
6-6C
Raleigh, NC April 2024
EW-46 EW-45 EW-43 EW-42
EW-47 _
EW48 EW-44
EW-49
0
° SPW-10RR EW-37 4P��80,300 PIW-5SR
-39 154,000,
z
a�
—EW-28 EW-26S
0
2,000 1,000 0
EW-19
EW-21 W
-20
V. , EW 22` � r-•
223
4
i
20 � z
kz
2,000 Feet
EW-16
EW-171
�E-W=1'8
All
I�
Legend
PFAS Sampling Location
❑
Surficial Aquifer
❑
Floodplain Deposits
0
Black Creek Aquifer
❑
Surface Water
Total Table 3+ PFAS, 17 Compounds (ng/L)
A
ND
A
<10
10 - 100
0
100 - 1,000
0
1,000 - 10,000
Q
10,000 - 100,000
-
100,000 - 1,000,000
-
> 1,000,000
Black Creek Aquifer Extraction Well
Surficial Aquifer Extraction Well
Site Boundary
Forcemain
Barrier Wall; approximate surface
elevation at 72 feet NAVD88
— — —
Seep
Cape Fear River
Notes:
1. This figure shows Total Table 3+ PFAS (17 Compounds)
concentrations in near remedy and downgradient
monitoring/observation wells (MWs/OWs), and Willis Creek (WC)
stations. PFAS results for the collection of MWs/OWs are from the
Q3 2023 and Q1 2024 sampling performed during July 13 to
August 8, 2023 (in blue) and January 15 to February 6, 2024
(in black), respectively. WC PFAS results are from the Q1 2024
sampling (in black) performed on February 22, 2024.
2. The outline of Cape Fear River is approximate and is based on open
data from ArcGIS Online and North Carolina Department of
Environmental Quality Online GIS (MajorHydro shapefile).
3. Basemap source: Esri, Maxar, Earthstar Geographics, and the GIS
User Community.
250 125 0 250 Feet
PFAS Analytical Results
Chemours Fayetteville Works, North Carolina
Geosptec'% Geosyntec Consultants of NC, P.C.
NC License No.: C 3500 and C 295 Figure
consultants
6-7 B
Raleigh, NC I June 2024
Z
EW-10 EW
PIW=1'
EW1-11
t.. j� C
EW �•2 PIUV-15 , 2
EW-16
SEW-17 EW-13 33,800
EW-19 EV1/-18EW=14 WC-1
EW�2,1 EW-15 1,420
�•EW-20
RIII W;i1S 44,200
�♦ 5,030
EW-7T vv MW-5
FEW -fa
Legend
PFAS Sampling Location
❑
Surficial Aquifer
❑
Floodplain Deposits
0
Black Creek Aquifer
❑
Surface Water
Total Table 3+ PFAS, 17 Compounds (ng/L)
A
ND
A
<10
10 - 100
0
100 - 1,000
0
1,000 - 10,000
10,000 - 100,000
-
100,000 - 1,000,000
-
> 1,000,000
Black Creek Aquifer Extraction Well
Surficial Aquifer Extraction Well
Site Boundary
Forcemain
Barrier Wall; approximate surface
elevation at 72 feet NAVD88
— — —
Seep
Nearby Tributary to River
Cape Fear River
Notes:
1. This figure shows Total Table 3+ PFAS (17 Compounds)
concentrations in near remedy and downgradient
monitoring/observation wells (MWs/OWs), and Willis Creek (WC)
stations. PFAS results for the collection of MWs/OWs are from the
Q3 2023 and Q1 2024 sampling performed during July 13 to
August 8, 2023 (in blue) and January 15 to February 6, 2024
(in black), respectively. WC PFAS results are from the Q1 2024
sampling (in black) performed on February 22, 2024.
2. The outline of Cape Fear River is approximate and is based on open
data from ArcGIS Online and North Carolina Department of
Environmental Quality Online GIS (MajorHydro shapefile).
3. Basemap source: Esri, Maxar, Earthstar Geographics, and the GIS
User Community.
250 125 0 250 Feet
PFAS Analytical Results
Chemours Fayetteville Works, North Carolina
Geosyntec'% Geosyntec Consultants of NC, P.C.
consultants NC License No.: C-3500 and C-295 Figure
6-7C
Raleigh, NC I June 2024
5,000
4,500
J
4,000
c
3,500
3,000
0
E 2,500
0
2,000
M 1,500
aU
-0 1,000
9
—ru 500
12 0
00
00
Q
z
0
a�
w
a�
a�
U
Ln
7/1/2022
47
45
43
41
39
37
35
33
31
29
1
I
I
1
I
1
1
I
1
1
1
I
1
I
I
1
I
I T-
9/19/2022 12/8/2022
2/26/2023 5/17/2023
8/5/2023
10/24/2023 1/12/2024
t WC-1 PFAS Sample Location
WC-2 PFAS Sample Location f WC-3
PFAS Sample Location
- - - Extraction Well Startup
7/1/2022 9/19/2022 12/8/2022 2/26/2023 5/17/2023 8/5/2023 10/24/2023
Cape Fear River Elevation Willis Creek Stilling Well 1
Notes:
Stilling Wells were installed in Willis Creek (WC) in October 2023. For clarity, only WC-1 location is shown. Trends at WC-2 and WC-3 are similar.
Prior to October 2023, Cape Fear River elevation are available from the USGS Huske Lock and Dam.
4/1/2024
1/12/2024 4/1/2024
30
25
0, 20
c
c
0
15
c
a�
U
0 10
ME
5
ND
30
25
20
c
c
0
15
c
m
U
0 10
5
ND
Transect 1 - North of Willis Creek
Flow: 9,630 cfs
Gage Height: 5.37 ft
West Sample Center Sample East Sample
(T1-101) (T1-102) (T1-103)
Transect 3 - Between W.O. Huske Dam and Outfall 002
Flow: 10,100 cfs
Gage Height: 5.53 ft
West Sample Center Sample East Sample
(T3-301) (T3-302) (T3-303)
Legend:
■ H FPO-DA
Notes:
cfs - cubic feet per second
11,000
• PFMOAA
ft - feet
ND - non -detect (see note 2)
A PMPA
ng/L - nanograms per liter
10,000
HFPO-DA - Hexafluoropropylene oxide dimer acid
PFMOAA - Perfluoro-2-methoxyacetic acid V
PMPA - Perfluoro-2-methoxypropionic acid
9,000
1. All samples along the river transacts were collected at the middle depth of the river. 0
2. The reporting detection limits are: HFPO-DA: 2 ng/L; PFMOAA: 2 ng/L; and PMPA: 10 ng/L. ILL
3. Gage height, total precipitation, and flow data are from the USGS gauging station #02105500 located at
8,000
the W.O. Huske Dam.
4. The gage height and flow posted on each graph corresponds to the sampling date and time that the center
sample was collected. The total precipitation represents the total from the start date and time to the end date
7 000
30
25
20
c
A
5
ND
30
25
20
c
5
►1OM
Transect 1
West Sample Center Sample East Sample
(T2-201) (T2-202) (T2-203)
Transect 4 - Downstream of Outfall 003 and Georgia Branch Creek
Flow: 10,200 cfs
Gage Height: 5.58 ft
r-,
u
West Sample Center Sample East Sample
(T4-401) (T4-402) (T4-403)
Transect 4
Transect 2 �- Transect 3
and time of the sampling event. 3/12/2024 0:00 3/12/2024 6:00 3/12/2024 12:00 3/12/2024 18:00 3/13/2024 0:00
Date and Time
Total Precipitation: 0 inchesl
Outfall 003 Treatment
System
400
Seep C FTC Seep B FTC Seep D FTC GWEC Fully Operational BW Completed
\ Seep A FTC -,\\ � � Outfall 002 SWTS BW Construction Started /
350
U)
c
300
.-.
0 J
o -S 250
O f
U c
� o
cu 200
O ❑ El
+
M o
o
150
�O 000
O
0
�U
9 O ❑
OD
O
50
C�-. �
Ib'b'Trl❑
I
50
0
C
E E 40
0 0
U
L
30
+ U
co
_(D l)
20
H 10
ME
Q
0:
O
!Cop V o
C)
V.Mq kJ
•
O ❑ •
O ❑ O • • ::
O ❑ O ::
000 60S°0 C)
1 I�
�® ❑�❑
0 CD
X
35,000
U)
30,000_
U)
25,000 0
20,000 >_
15,000
U_
m
10,000
U
5,000
0
7
�Ti III
a�
I U
i I I I I I I I F 5.E
3�
2 0
00' 00' Off' 00' 00' 00' 00' 00' 00' 00' Off' Off' 00' 00' 00' 00' 00' 00' 00' 00' 00' Off' 00' 00' 00' Off' 00' 00' 00' 00' 00' 00' 00' Off' 00' 00' 00' 00' 00' 00' Off' 00' Off' Off' Off' 00' 00' 00' 00'
Total Daily Precipitation O Composite Sample
Cape Fear River Flow ❑ Grab Sample Total Table 3+ (17 Compounds) Concen
Notes:
A concentration of 0 ng/L and mass discharge of 0 mg/s indicate that all the compounds were not detected above the reporting limit.
Flow and precipitation data are from the USGS gauging station #02105500 located at the W.O. Huske Dam.
PFAS concentrations calculated by summing over Attachment C compounds and Table 3+ (21 compounds) are provided in Appendix B.
Abbrevations:
BW - Barrier Wall mg/s - milligrams per second
W/s - cubic feet per second ng/L - nanograms per liter
FTC - Flow -through cell SWTS - Stormwater treatment system
GWEC - Groundwater extraction and conveyance system
Geosyntec
consultants
Geosyntec Consultants of NC, P.C.
NC License No.: C-3500 and C-295
Appendix A
Laboratory Analytical Data Review
Narratives
(Full lab reports to be uploaded to OneDrlve and
EQuZS)
TR0795C
ADQM Data Review
Site: Chemours Fayetteville
Protect: CAP 1 Q24 Sampling (selected lots)
Project Reviewer: Bridget Gavaghan
Sample Summary
Field Sample ID
Lab Sample ID
Sample
Matrix
Filtered
Sample
Date
Sample
Time
Sample Purpose
CAP 1 Q24-P IW-7D-0 11524
320-108762-1
Groundwater
N
01/15/2024
13:11
FS
CAP1 Q24-B LADE N-1 DR-01 1524
320-108762-10
Groundwater
N
01/15/2024
10:25
FS
CAP1Q24-EQBLK-PP-011724
320-108762-11
Blank Water
N
01/17/2024
13:00
EB
CAP1Q24-PIW-7D-011524-D
320-108762-2
Groundwater
N
01/15/2024
13:11
DUP
CAP1Q24-PIW-7S-011524
320-108762-3
Groundwater
N
01/15/2024
15:20
FS
CAP1 Q24-SMW-1 2-011624
320-108762-4
Groundwater
N
01/16/2024
15:06
FS
CAP1Q24-LTW-04-011624
320-108762-5
Groundwater
N
01/16/2024
13:05
FS
CAP1Q24-PZ-22-011624
320-108762-6
Groundwater
N
01/16/2024
15:20
FS
CAP1Q24-PIW-1S-011624
320-108762-7
Groundwater
N
01/16/2024
15:47
FS
CAP1Q24-PW-06-011524
320-108762-8
Groundwater
N
01/15/2024
14:35
FS
CAP1Q24-LTW-05-011524
320-108762-9
Groundwater
N
01/15/2024
12:05
FS
CAP1 Q24-PIW-1 D-01 2224
320-109019-1
Groundwater
N
01/22/2024
12:04
FS
CAP1Q24-PIW-10DR-012224
320-109019-2
Groundwater
N
01/22/2024
11:00
FS
CAP1 Q24-PIW-4D-01 2224
320-109019-3
Groundwater
N
01/22/2024
14:45
FS
CAP1 Q24-PIW-8D-01 2224
320-109019-4
Groundwater
N
01/22/2024
13:10
FS
CAP1 Q24-EQBLK-DV-01 2224
320-109019-5
Blank Water
N
01/22/2024
16:05
EB
CAP1Q24-EQBLK-BAILER-
012224
320-109019-6
Blank Water
N
01/22/2024
16:20
EB
CAP1Q24-EQBLK-BAILER-
012224-Z
320-109019-7
Blank Water
Y
01/22/2024
16:25
EB
CAP1 Q24-LTW-01 -011724
320-109020-1
Groundwater
N
01/17/2024
13:40
FS
CAP1Q24-LTW-02-011724
320-109020-2
Groundwater
N
01/17/2024
12:40
FS
CAP1Q24-OW-37-011724
320-109020-3
Groundwater
N
01/17/2024
10:15
FS
CAP1 Q24-SMW-1 0-011724
320-109020-4
Groundwater
N
01/17/2024
14:39
FS
CAP1Q24-PW-04-011724
320-109020-5
Groundwater
N
01/17/2024
15:55
FS
CAP1Q24-PW-04-011724-Z
320-109020-6
Groundwater
Y
01/17/2024
15:55
FS
CAP1Q24-PIW-3D-011824
320-109020-7
Groundwater
N
01/18/2024
13:21
FS
CAP1Q24-SMW-11-011824
320-109020-8
Groundwater
N
01/18/2024
15:25
FS
CAP4Q23-OW-28-011824
320-109020-9
Groundwater
N
01/18/2024
12:06
FS
CAP1Q24-OW-32-012924
320-109381-1
Groundwater
N
01/29/2024
14:45
FS
CAP1Q24-OW-4R-012924
320-109381-2
Groundwater
N
01/29/2024
11:00
FS
CAP1Q24-OW30-013024
320-109381-3
Groundwater
N
01/30/2024
15:15
FS
CAP1Q24-OW-40-013024
320-109381-4
Groundwater
N
01/30/2024
13:45
FS
CAP1Q24-OW-33-013024
320-109381-5
Groundwater
N
01/30/2024
12:14
FS
CAP1Q24-PW-10RR-013124
320-109381-6
Groundwater
N
01/31/2024
12:35
FS
CAP1Q24-LTW-03-013124
320-109381-7
Groundwater
N
01/31/2024
11:05
FS
CAP1 Q24-PIW-6S-01 3124
320-109381-8
Groundwater
N
01/31/2024
12:47
FS
CAP1Q24-OW-51-013124
320-109381-9
Groundwater
N
01/31/2024
12:32
FS
CAP1Q24-OW-56-020124
320-109475-1
Groundwater
N
02/01/2024
15:00
FS
CAP1 Q24-PIW-1 1-020124
320-109475-2
Groundwater
N
02/01/2024
11:45
FS
CAP1Q24-EQBLK-BP-020224
320-109475-3
Blank Water
N
02/02/2024
10:50
EB
CAP1Q24-OW-55-020524
320-109475-4
Groundwater
N
02/05/2024
12:30
FS
CAP1 Q24-PIW-1 5-020524
320-109475-5
Groundwater
N
02/05/2024
15:10
FS
CAP1Q24-OW-54-020624
320-109475-6
Groundwater
N
02/06/2024
11:50
FS
CAP1Q24-OW-57-020624
320-109475-7
Groundwater
N
02/06/2024
13:25
FS
CAP1Q24-WC-1-24-022224
320-109943-1
Surface
N
02/22/2024
09:06
FS
Water
CAP1Q24-WC-2-24-022224
320-109943-2
Surface
N
02/22/2024
08:50
FS
Water
CAP1Q24-WC-3-24-022224
320-109943-3
Surface
N
02/22/2024
08:27
FS
Water
CAP1Q24-WC-3-24-022224-D
320-109943-4
Surface
N
02/22/2024
08:27
DUP
Water
CAP1Q24-EQBLK-IS-022224
320-109943-5
Blank Water
N
02/22/2024
15:30
EB
* FS=Field Sample
DUP=Field Duplicate
FB=Field Blank
EB=Equipment Blank
TB=Trip Blank
Analytical Protocol
Lab Name
Lab Method
Parameter Category
Sampling Program
Eurofins Environ Testing
537
Per- and Polyfluorinated Alkyl Substances
CAP GW Sampling
Northern Cali
Modified
PFAS
1Q24
Eurofins Environ Testing
537
Per- and Polyfluorinated Alkyl Substances
CAP SW Sampling
Northern Cali
Modified
PFAS
1 Q24
ADQM Data Review Checklist
DVM
Laboratory
Exception
Item
Description
Yes
No*
Narrative
Report
Report (ER)
Report
#
Did samples meet laboratory acceptability
A
requirements upon receipt (i.e., intact, within
X
temperature, properly preserved, and no
heads ace where applicable)?
B
Were samples received by the laboratory in
X
X
agreement with the associated chain of custody?
C
Was the chain of custody properly completed by
X
the laboratory and/or field team?
D
Were samples prepped/analyzed by the laboratory
X
X
X
within method holding times?
Were data review criteria met for method blanks,
LCSs/LCSDs, MSs/MSDs, PDSs, SDs, replicates,
E
surrogates, sample results within calibration range,
X
X
X
total/dissolved samples, field duplicates,
field/equipment/trip blanks?
F
Were all data usable and not R qualified?
X
ER#
Description
Other QA/QC Items to Note:
See DVM Narrative Report, Laboratory Report, and/or ER # for further details as indicated.
The electronic data submitted for this project were reviewed via the Data Verification Module (DVM)
process. Overall, the data are acceptable for use without qualification, except as noted on the attached
DVM Narrative Report.
The lab reports due to a large page count are stored on a network shared drive and are available to be
posted on external shared drives, or on a flash drive.
Data Verification Module (DVM)
The DVM is an internal review process used by the ADQM group to assist with the determination of data
usability. The electronic data deliverables received from the laboratory are loaded into the Locus ElMTM
database and processed through a series of data quality checks, which are a combination of software,
Locus EIMTm database Data Verification Module (DVM), and manual reviewer evaluations. The data are
evaluated against the following data usability checks:
• Field and laboratory blank contamination
• US EPA hold time criteria
• Missing Quality Control (QC) samples
• Matrix spike (MS)/matrix spike duplicate (MSD) recoveries and the relative percent differences
(RPDs) between these spikes
• Laboratory control sample (LCS)/laboratory control sample duplicate (LCSD) recoveries and the
RPD between these spikes
• Surrogate spike recoveries for organic analyses
• Difference/RPD between field duplicate sample pairs
• RPD between laboratory replicates for inorganic analyses
• Difference/percent difference between total and dissolved sample pairs
There are two qualifier fields in EIM:
Laboratory Qualifier is the qualifier assigned by the laboratory and may not reflect the usability of
the data. This qualifier may have many different meanings and can vary between labs and over time
within the same lab. Please refer to the laboratory report for a description of the laboratory qualifiers.
As they are laboratory descriptors they are not to be used when evaluating the data.
Validation Qualifier is the 3rd party formal validation qualifier if this was performed. Otherwise this
field contains the qualifier resulting from the ADQM DVM review process. This qualifier assesses the
usability of the data and may not equal the laboratory qualifier. The DVM applies the following data
evaluation qualifiers to analysis results, as warranted:
Qualifier
Definition
B
Not detected substantially above the level reported in the laboratory or field
blanks.
R
Unusable result. Anal to may or may not be present in the sample.
J
An to resent. Reported value may not be accurate or precise.
UJ
Not detected. Reporting limit may not be accurate or precise.
The Validation Status Code field is set to "DVM" if the ADQM DVM process has been performed. If the
DVM has not been run, the field will be blank.
If the DVM has been run (Validation Status Code equals "DVM"), use the Validation Qualifier.
If the data have been validated by a third party, the field "Validated By" will be set to the validator (e.g.,
ESI for Environmental Standards, Inc.)
DVM Narrative Report
Site: Fayetteville Sampling Program: CAP GW Sampling 1Q24 Validation Options: LABSTATS
Validation Reason Code: The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.
Date
Validation
Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result
Units
Type
MDL PQL
Qualifier
Method
CAP1Q24-EQBLK-BP-
02/02/2024 320-109475-3
Perfluorooctadecanoic
0.0020
ug/L
PQL
0.0020
UJ
537 Modified
020224
Acid
CAP1Q24-EQBLK-BP-
02/02/2024 320-109475-3
Perfluorooctadecanoic
0.0020
ug/L
PQL
0.0020
UJ
537 Modified
020224
Acid
CAP1Q24-EQBLK-BP-
02/02/2024 320-109475-3
PS Acid
0.0020
UG/L
PQL
0.0020
UJ
537 Modified
020224
CAP1Q24-EQBLK-BP-
02/02/2024 320-109475-3
PS Acid
0.0020
UG/L
PQL
0.0020
UJ
537 Modified
020224
CAP1Q24-EQBLK-BP-
02/02/2024 320-109475-3
EVE Acid
0.0020
UG/L
PQL
0.0020
UJ
537 Modified
020224
CAP1Q24-EQBLK-BP-
02/02/2024 320-109475-3
EVE Acid
0.0020
UG/L
PQL
0.0020
UJ
537 Modified
020224
CAP1Q24-EQBLK-IS-
02/22/2024 320-109943-5
Perfluorooctadecanoic
0.0020
ug/L
PQL
0.0020
UJ
537 Modified
022224
Acid
CAP 1Q24-LTW-03-013124
01/31/2024 320-109381-7
PS Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP 1Q24-LTW-03-013124
01/31/2024 320-109381-7
EVE Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1Q24-OW-32-012924
01/29/2024 320-109381-1
PS Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1Q24-OW-32-012924
01/29/2024 320-109381-1
EVE Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1Q24-OW-33-013024
01/30/2024 320-109381-5
PS Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1Q24-OW-33-013024
01/30/2024 320-109381-5
EVE Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1Q24-OW-40-013024
01/30/2024 320-109381-4
PS Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1Q24-OW-40-013024
01/30/2024 320-109381-4
EVE Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1Q24-OW-4R-012924
01/29/2024 320-109381-2
PS Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1Q24-OW-4R-012924
01/29/2024 320-109381-2
EVE Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1Q24-OW-51-013124
01/31/2024 320-109381-9
PS Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1Q24-OW-51-013124
01/31/2024 320-109381-9
EVE Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1Q24-OW-54-020624
02/06/2024 320-109475-6
PS Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1Q24-OW-54-020624
02/06/2024 320-109475-6
EVE Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1Q24-OW-56-020124
02/01/2024 320-109475-1
PS Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
Pre -prep
Prep
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
Page 1 of 16
Site: Fayetteville
Validation Reason Code
Sampling Program: CAP GW Sampling 1Q24 Validation Options: LABSTATS
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.
Date
Validation
Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result
Units
Type
MDL PQL
Qualifier
Method
CAP1Q24-OW-56-020124
02/01/2024 320-109475-1
EVE Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1Q24-OW-55-020524
02/05/2024 320-109475-4
PS Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1Q24-OW-55-020524
02/05/2024 320-109475-4
EVE Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1Q24-OW-57-020624
02/06/2024 320-109475-7
EVE Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1Q24-OW30-013024
01/30/2024 320-109381-3
PS Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1Q24-OW30-013024
01/30/2024 320-109381-3
EVE Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1 Q24-PIW-1 1-020124
02/01/2024 320-109475-2
PS Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1 Q24-PIW-1 1-020124
02/01/2024 320-109475-2
EVE Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1 Q24-PIW-1 5-020524
02/05/2024 320-109475-5
PS Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1 Q24-PIW-1 5-020524
02/05/2024 320-109475-5
EVE Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1Q24-PIW-6S-013124
01/31/2024 320-109381-8
PS Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1Q24-PIW-6S-013124
01/31/2024 320-109381-8
EVE Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1Q24-PW-11-013124
01/31/2024 320-109381-10
EVE Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
CAP1Q24-PW-10RR-
01/31/2024 320-109381-6
PS Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
013124
CAP1Q24-PW-10RR-
01/31/2024 320-109381-6
EVE Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
013124
Pre -prep
Prep
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
Page 2 of 16
Site: Fayetteville
Sampling Program:
CAP GW Sampling 1Q24
Validation Options: LABSTATS
Validation Reason Code: Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit but above the rejection limit. The reported result may be
biased low.
Date
Validation Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result Units Type MDL
PQL Qualifier Method Pre -prep Prep
CAP1Q24-OW-56-020124
02/01/2024 320-109475-1
PS Acid
0.050 UG/L PQL
0.050 UJ 537 Modified 3535
CAP1Q24-OW-56-020124
02/01/2024 320-109475-1
EVE Acid
0.050 UG/L PQL
0.050 UJ 537 Modified 3535
Page 3 of 16
Site: Fayetteville
Sampling Program:
CAP GW Sampling 1Q24
Validation Options: LABSTATS
Validation Reason Code: Associated LCS and/or LCSD analysis had relative
percent recovery (RPR) values less than the lower control limit
but above 10%. The actual detection limits may be higher
than reported.
Date
Validation
Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result
Units
Type MDL
PQL
Qualifier
Method Pre -prep
Prep
CAP1Q24-EQBLK-BP-
02/02/2024 320-109475-3
Perfluorooctadecanoic
0.0020
ug/L
PQL
0.0020
UJ
537 Modified
3535
020224
Acid
CAP1Q24-EQBLK-BP-
02/02/2024 320-109475-3
PS Acid
0.0020
UG/L
PQL
0.0020
UJ
537 Modified
3535
020224
CAP1Q24-EQBLK-BP-
02/02/2024 320-109475-3
EVE Acid
0.0020
UG/L
PQL
0.0020
UJ
537 Modified
3535
020224
CAP1Q24-OW-54-020624
02/06/2024 320-109475-6
PS Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
3535
CAP1Q24-OW-54-020624
02/06/2024 320-109475-6
EVE Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
3535
CAP1Q24-OW-55-020524
02/05/2024 320-109475-4
PS Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
3535
CAP1Q24-OW-55-020524
02/05/2024 320-109475-4
EVE Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
3535
CAP1Q24-OW-57-020624
02/06/2024 320-109475-7
EVE Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
3535
CAP1 Q24-PIW-1 1-020124
02/01/2024 320-109475-2
PS Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
3535
CAP1 Q24-PIW-1 1-020124
02/01/2024 320-109475-2
EVE Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
3535
CAP1 Q24-PIW-1 5-020524
02/05/2024 320-109475-5
PS Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
3535
CAP1 Q24-PIW-1 5-020524
02/05/2024 320-109475-5
EVE Acid
0.050
UG/L
PQL
0.050
UJ
537 Modified
3535
Page 4 of 16
Site: Fayetteville
Validation Reason Code
Sampling Program: CAP GW Sampling 1Q24 Validation Options: LABSTATS
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit. The actual detection limits may be higher than reported.
Date
Field Sample ID Sampled Lab Sample ID
CAP1Q24-OW-32-012924 01/29/2024 320-109381-1
Validation Analytical
Analyte Result Units Type MDL PQL Qualifier Method Pre -prep
Perfluorononanoic 0.034 UG/L PQL 0.034 UJ 537 Modified
Acid
Prep
3535
Page 5 of 16
Site: Fayetteville Sampling Program: CAP GW Sampling 1Q24 Validation Options
Validation Reason Code: The preparation hold time for this sample was exceeded. The reporting limit may be biased low.
Date
Validation
Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result
Units
Type
MDL PQL
Qualifier
Method
CAP1Q24-BLADEN-1DR-
01/15/2024 320-108762-10
PPF Acid
0.31
UG/L
PQL
0.31
UJ
537 Modified
011524
CAP1Q24-BLADEN-1DR-
01/15/2024 320-108762-10
PPF Acid
0.31
UG/L
PQL
0.31
UJ
537 Modified
011524
CAP1Q24-PZ-22-011624
01/16/2024 320-108762-6
6:2 Fluorotelomer
0.31
ug/L
PQL
0.31
UJ
537 Modified
sulfonate
CAP1Q24-PIW-7D-011524- 01/15/2024 320-108762-2
6:2 Fluorotelomer
0.31
ug/L
PQL
0.31
UJ
537 Modified
D
sulfonate
CAP1Q24-PW-06-011524
01/15/2024 320-108762-8
6:2 Fluorotelomer
0.31
ug/L
PQL
0.31
UJ
537 Modified
sulfonate
LABSTATS
Pre -prep
Prep
3535
3535
3535
3535
3535
Page 6 of 16
Site: Fayetteville
Validation Reason Code
Sampling Program: CAP SW Sampling 1Q24 Validation Options: LABSTATS
High relative percent difference (RPD) observed between field duplicate and parent sample. The reported result may be imprecise.
Date
Validation
Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result
Units
Type
MDL PQL
Qualifier
Method
CAP1Q24-WC-3-24-
02/22/2024 320-109943-3
PMPA
0.083
UG/L
PQL
0.0034
J
537 Modified
022224
CAP1Q24-WC-3-24-
02/22/2024 320-109943-3
Hfpo Dimer Acid
0.050
UG/L
PQL
0.015
J
537 Modified
022224
CAP1Q24-WC-3-24-
02/22/2024 320-109943-3
R-PSDA
0.0033
UG/L
PQL
0.0028
J
537 Modified
022224
CAP1Q24-WC-3-24-
02/22/2024 320-109943-3
Perfluorobutane
0.0043
UG/L
PQL
0.0020
J
537 Modified
022224
Sulfonic Acid
CAP1Q24-WC-3-24-
02/22/2024 320-109943-3
PF02HxA
0.044
ug/L
PQL
0.0055
J
537 Modified
022224
CAP1Q24-WC-3-24-
02/22/2024 320-109943-3
PFMOAA
0.022
ug/L
PQL
0.0041
J
537 Modified
022224
CAP1Q24-WC-3-24-
02/22/2024 320-109943-4
PMPA
0.14
UG/L
PQL
0.0020
J
537 Modified
022224-D
CAP1Q24-WC-3-24-
02/22/2024 320-109943-4
Hfpo Dimer Acid
0.094
UG/L
PQL
0.0040
J
537 Modified
022224-D
CAP1Q24-WC-3-24-
02/22/2024 320-109943-4
R-PSDA
0.0092
UG/L
PQL
0.0020
J
537 Modified
022224-D
CAP1Q24-WC-3-24-
02/22/2024 320-109943-4
Perfluorobutane
0.0064
UG/L
PQL
0.0020
J
537 Modified
022224-D
Sulfonic Acid
CAP1Q24-WC-3-24-
02/22/2024 320-109943-4
PF02HxA
0.086
ug/L
PQL
0.0020
J
537 Modified
022224-D
CAP1Q24-WC-3-24-
02/22/2024 320-109943-4
PFMOAA
0.038
ug/L
PQL
0.0020
J
537 Modified
022224-D
Pre -prep
Prep
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
Page 7 of 16
Site: Fayetteville
Validation Reason Code
Sampling Program: CAP GW Sampling 1Q24 Validation Options: LABSTATS
High relative percent difference (RPD) observed between LCS and LCSD samples. The reported result may be imprecise.
Date Validation Analytical
Field Sample ID Sampled Lab Sample ID Analyte Result Units Type MDL PQL Qualifier Method
CAP1Q24-PIW-7D-011524- 01/15/2024 320-108762-2 PPF Acid 73 UG/L PQL 0.31 J 537 Modified
D
CAP1Q24-PZ-22-011624 01/16/2024 320-108762-6 PPF Acid 72 UG/L PQL 0.31 J 537 Modified
CAP1Q24-PIW-7D-011524 01/15/2024 320-108762-1 PPF Acid 71 UG/L PQL 0.31 J 537 Modified
Pre -prep
Prep
3535
3535
3535
Page 8 of 16
Site: Fayetteville
Sampling Program:
CAP GW Sampling 1Q24
Validation Options:
LABSTATS
Validation Reason Code: Uncertainty around the analysis of R-PSDA, Hydrolyzed
PSDA and R-EVE; J-qualifier added to all detects in the data set, even if there was no matrix spike analyzed for that
particular sample.
Date
Validation
Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result
Units
Type MDL
PQL
Qualifier
Method
Pre -prep Prep
CAP1Q24-PW-11-013124
01/31/2024 320-109381-10
R-PSDA
0.30
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-PW-11-013124
01/31/2024 320-109381-10
Hydrolyzed PSDA
0.85
UG/L
PQL
0.034
J
537 Modified
3535
CAP1Q24-PW-11-013124
01/31/2024 320-109381-10
R-EVE
0.11
UG/L
PQL
0.039
J
537 Modified
3535
CAP1Q24-SMW-11-
01/18/2024 320-109020-8
R-PSDA
0.12
UG/L
PQL
0.035
J
537 Modified
3535
011824
CAP1Q24-SMW-11-
01/18/2024 320-109020-8
R-PSDA
0.12
UG/L
PQL
0.035
J
537 Modified
3535
011824
CAP1Q24-SMW-11-
01/18/2024 320-109020-8
Hydrolyzed PSDA
0.088
UG/L
PQL
0.034
J
537 Modified
3535
011824
CAP1Q24-SMW-11-
01/18/2024 320-109020-8
Hydrolyzed PSDA
0.088
UG/L
PQL
0.034
J
537 Modified
3535
011824
CAP1Q24-SMW-11-
01/18/2024 320-109020-8
R-EVE
0.088
UG/L
PQL
0.039
J
537 Modified
3535
011824
CAP1Q24-SMW-11-
01/18/2024 320-109020-8
R-EVE
0.088
UG/L
PQL
0.039
J
537 Modified
3535
011824
CAP1Q24-WC-1-24-
02/22/2024 320-109943-1
R-PSDA
0.036
UG/L
PQL
0.0020
J
537 Modified
3535
022224
CAP1Q24-WC-1-24-
02/22/2024 320-109943-1
Hydrolyzed PSDA
0.16
UG/L
PQL
0.0020
J
537 Modified
3535
022224
CAP1Q24-WC-1-24-
02/22/2024 320-109943-1
R-EVE
0.018
UG/L
PQL
0.0020
J
537 Modified
3535
022224
CAP1Q24-WC-2-24-
02/22/2024 320-109943-2
R-PSDA
0.012
UG/L
PQL
0.0020
J
537 Modified
3535
022224
CAP1Q24-WC-2-24-
02/22/2024 320-109943-2
Hydrolyzed PSDA
0.014
UG/L
PQL
0.0020
J
537 Modified
3535
022224
CAP1Q24-WC-2-24-
02/22/2024 320-109943-2
R-EVE
0.0077
UG/L
PQL
0.0020
J
537 Modified
3535
022224
CAP1Q24-WC-3-24-
02/22/2024 320-109943-4
R-EVE
0.0046
UG/L
PQL
0.0020
J
537 Modified
3535
022224-D
CAP1Q24-PW-04-011724
01/17/2024 320-109020-5
R-PSDA
0.13
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-PW-04-011724
01/17/2024 320-109020-5
R-PSDA
0.13
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-PW-04-011724
01/17/2024 320-109020-5
R-EVE
0.066
UG/L
PQL
0.039
J
537 Modified
3535
CAP1Q24-PW-04-011724
01/17/2024 320-109020-5
R-EVE
0.066
UG/L
PQL
0.039
J
537 Modified
3535
CAP 1Q24-PW-04-011724-
01/17/2024 320-109020-6
R-PSDA
0.13
UG/L
PQL
0.035
J
537 Modified
3535
Z
CAP 1Q24-PW-04-011724-
01/17/2024 320-109020-6
R-PSDA
0.13
UG/L
PQL
0.035
J
537 Modified
3535
Z
CAP 1Q24-PW-04-011724-
01/17/2024 320-109020-6
R-EVE
0.065
UG/L
PQL
0.039
J
537 Modified
3535
Z
Page 9 of 16
Site: Fayetteville Sampling Program: CAP GW Sampling 1Q24 Validation Options: LABSTATS
Validation Reason Code: Uncertainty around the analysis of R-PSDA, Hydrolyzed PSDA and R-EVE; J-qualifier added to all detects in the data set, even if there was no matrix spike analyzed for that
particular sample.
Date
Validation
Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result
Units
Type MDL
PQL
Qualifier
Method Pre -prep
Prep
CAP 1Q24-PW-04-011724-
01/17/2024 320-109020-6
R-EVE
0.065
UG/L
PQL
0.039
J
537 Modified
3535
Z
CAP1Q24-PW-10RR-
01/31/2024 320-109381-6
R-PSDA
0.084
UG/L
PQL
0.035
J
537 Modified
3535
013124
CAP1Q24-PW-10RR-
01/31/2024 320-109381-6
Hydrolyzed PSDA
0.084
UG/L
PQL
0.034
J
537 Modified
3535
013124
CAP1Q24-PW-10RR-
01/31/2024 320-109381-6
R-EVE
0.12
UG/L
PQL
0.039
J
537 Modified
3535
013124
CAP1Q24-PIW-3D-011824
01/18/2024 320-109020-7
R-PSDA
0.78
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-PIW-3D-011824
01/18/2024 320-109020-7
R-PSDA
0.78
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-PIW-3D-011824
01/18/2024 320-109020-7
Hydrolyzed PSDA
0.47
UG/L
PQL
0.034
J
537 Modified
3535
CAP1Q24-PIW-3D-011824
01/18/2024 320-109020-7
Hydrolyzed PSDA
0.47
UG/L
PQL
0.034
J
537 Modified
3535
CAP1Q24-PIW-3D-011824
01/18/2024 320-109020-7
R-EVE
0.39
UG/L
PQL
0.039
J
537 Modified
3535
CAP1Q24-PIW-3D-011824
01/18/2024 320-109020-7
R-EVE
0.39
UG/L
PQL
0.039
J
537 Modified
3535
CAP1Q24-PIW-6S-013124
01/31/2024 320-109381-8
R-PSDA
0.73
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-PIW-6S-013124
01/31/2024 320-109381-8
Hydrolyzed PSDA
4.3
UG/L
PQL
0.034
J
537 Modified
3535
CAP1Q24-PIW-6S-013124
01/31/2024 320-109381-8
R-EVE
0.36
UG/L
PQL
0.039
J
537 Modified
3535
CAP1 Q24-PIW-1 5-020524
02/05/2024 320-109475-5
R-PSDA
0.19
UG/L
PQL
0.035
J
537 Modified
3535
CAP1 Q24-PIW-1 5-020524
02/05/2024 320-109475-5
R-EVE
0.13
UG/L
PQL
0.039
J
537 Modified
3535
CAP1 Q24-PIW-1 1-020124
02/01/2024 320-109475-2
R-PSDA
0.23
UG/L
PQL
0.035
J
537 Modified
3535
CAP1 Q24-PIW-1 1-020124
02/01/2024 320-109475-2
Hydrolyzed PSDA
2.8
UG/L
PQL
0.034
J
537 Modified
3535
CAP1 Q24-PIW-1 1-020124
02/01/2024 320-109475-2
R-EVE
0.077
UG/L
PQL
0.039
J
537 Modified
3535
CAP1Q24-OW30-013024
01/30/2024 320-109381-3
R-PSDA
0.34
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-OW30-013024
01/30/2024 320-109381-3
Hydrolyzed PSDA
0.52
UG/L
PQL
0.034
J
537 Modified
3535
CAP1Q24-OW30-013024
01/30/2024 320-109381-3
R-EVE
0.27
UG/L
PQL
0.039
J
537 Modified
3535
CAP1Q24-OW-56-020124
02/01/2024 320-109475-1
R-PSDA
0.14
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-OW-56-020124
02/01/2024 320-109475-1
R-EVE
0.11
UG/L
PQL
0.039
J
537 Modified
3535
Page 10 of 16
Site: Fayetteville Sampling Program: CAP GW Sampling 1Q24 Validation Options: LABSTATS
Validation Reason Code: Uncertainty around the analysis of R-PSDA, Hydrolyzed PSDA and R-EVE; J-qualifier added to all detects in the data set, even if there was no matrix spike analyzed for that
particular sample.
Date
Validation
Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result
Units
Type MDL
PQL
Qualifier
Method Pre -prep
Prep
CAP1Q24-OW-57-020624
02/06/2024 320-109475-7
R-PSDA
1.2
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-OW-57-020624
02/06/2024 320-109475-7
Hydrolyzed PSDA
15
UG/L
PQL
0.034
J
537 Modified
3535
CAP1Q24-OW-57-020624
02/06/2024 320-109475-7
R-EVE
0.21
UG/L
PQL
0.039
J
537 Modified
3535
CAP1Q24-OW-55-020524
02/05/2024 320-109475-4
R-PSDA
0.10
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-OW-55-020524
02/05/2024 320-109475-4
R-EVE
0.085
UG/L
PQL
0.039
J
537 Modified
3535
CAP1Q24-OW-54-020624
02/06/2024 320-109475-6
R-PSDA
0.078
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-OW-54-020624
02/06/2024 320-109475-6
R-EVE
0.042
UG/L
PQL
0.039
J
537 Modified
3535
CAP1Q24-OW-51-013124
01/31/2024 320-109381-9
R-PSDA
0.65
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-OW-51-013124
01/31/2024 320-109381-9
Hydrolyzed PSDA
1.4
UG/L
PQL
0.034
J
537 Modified
3535
CAP1Q24-OW-51-013124
01/31/2024 320-109381-9
R-EVE
0.70
UG/L
PQL
0.039
J
537 Modified
3535
CAP1Q24-OW-4R-012924
01/29/2024 320-109381-2
R-PSDA
0.57
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-OW-4R-012924
01/29/2024 320-109381-2
Hydrolyzed PSDA
2.3
UG/L
PQL
0.034
J
537 Modified
3535
CAP1Q24-OW-4R-012924
01/29/2024 320-109381-2
R-EVE
0.39
UG/L
PQL
0.039
J
537 Modified
3535
CAP1Q24-OW-37-011724
01/17/2024 320-109020-3
R-PSDA
0.10
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-OW-37-011724
01/17/2024 320-109020-3
R-PSDA
0.10
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-OW-37-011724
01/17/2024 320-109020-3
Hydrolyzed PSDA
0.083
UG/L
PQL
0.034
J
537 Modified
3535
CAP1Q24-OW-37-011724
01/17/2024 320-109020-3
Hydrolyzed PSDA
0.083
UG/L
PQL
0.034
J
537 Modified
3535
CAP1Q24-OW-40-013024
01/30/2024 320-109381-4
R-PSDA
0.20
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-OW-40-013024
01/30/2024 320-109381-4
Hydrolyzed PSDA
0.065
UG/L
PQL
0.034
J
537 Modified
3535
CAP1Q24-OW-40-013024
01/30/2024 320-109381-4
R-EVE
0.10
UG/L
PQL
0.039
J
537 Modified
3535
CAP1Q24-OW-33-013024
01/30/2024 320-109381-5
R-PSDA
0.21
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-OW-33-013024
01/30/2024 320-109381-5
Hydrolyzed PSDA
0.038
UG/L
PQL
0.034
J
537 Modified
3535
CAP1Q24-OW-33-013024
01/30/2024 320-109381-5
R-EVE
0.14
UG/L
PQL
0.039
J
537 Modified
3535
Page 11 of 16
Site: Fayetteville
Sampling Program:
CAP GW Sampling 1Q24
Validation Options: LABSTATS
Validation Reason Code: Uncertainty around the analysis of R-PSDA, Hydrolyzed
PSDA and R-EVE; J-qualifier added to all detects in the data set, even if there was no matrix spike
analyzed for that
particular sample.
Date
Validation
Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result
Units
Type MDL
PQL
Qualifier
Method Pre -prep
Prep
CAP1Q24-PZ-22-011624
01/16/2024 320-108762-6
R-PSDA
0.44
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-PZ-22-011624
01/16/2024 320-108762-6
Hydrolyzed PSDA
1.1
UG/L
PQL
0.034
J
537 Modified
3535
CAP1Q24-PZ-22-011624
01/16/2024 320-108762-6
R-EVE
0.30
UG/L
PQL
0.039
J
537 Modified
3535
CAP1Q24-OW-28-011824
01/18/2024 320-109020-9
R-PSDA
0.28
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-OW-28-011824
01/18/2024 320-109020-9
R-PSDA
0.28
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-OW-28-011824
01/18/2024 320-109020-9
R-EVE
0.12
UG/L
PQL
0.039
J
537 Modified
3535
CAP1Q24-OW-28-011824
01/18/2024 320-109020-9
R-EVE
0.12
UG/L
PQL
0.039
J
537 Modified
3535
CAP1Q24-OW-32-012924
01/29/2024 320-109381-1
R-PSDA
0.22
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-OW-32-012924
01/29/2024 320-109381-1
Hydrolyzed PSDA
0.65
UG/L
PQL
0.034
J
537 Modified
3535
CAP1Q24-OW-32-012924
01/29/2024 320-109381-1
R-EVE
0.14
UG/L
PQL
0.039
J
537 Modified
3535
CAP 1Q24-LTW-03-013124
01/31/2024 320-109381-7
R-PSDA
0.77
UG/L
PQL
0.035
J
537 Modified
3535
CAP 1Q24-LTW-03-013124
01/31/2024 320-109381-7
Hydrolyzed PSDA
5.3
UG/L
PQL
0.034
J
537 Modified
3535
CAP 1Q24-LTW-03-013124
01/31/2024 320-109381-7
R-EVE
0.32
UG/L
PQL
0.039
J
537 Modified
3535
CAP1Q24-PIW-7S-011524
01/15/2024 320-108762-3
R-PSDA
0.79
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-PIW-7S-011524
01/15/2024 320-108762-3
Hydrolyzed PSDA
0.045
UG/L
PQL
0.034
J
537 Modified
3535
CAP1Q24-PIW-7S-011524
01/15/2024 320-108762-3
R-EVE
0.88
UG/L
PQL
0.039
J
537 Modified
3535
CAP1Q24-PW-06-011524
01/15/2024 320-108762-8
R-PSDA
0.042
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-SMW-12-
01/16/2024 320-108762-4
R-PSDA
0.065
UG/L
PQL
0.035
J
537 Modified
3535
011624
CAP1Q24-SMW-12-
01/16/2024 320-108762-4
R-EVE
0.045
UG/L
PQL
0.039
J
537 Modified
3535
011624
CAP1Q24-PIW-10DR-
01/22/2024 320-109019-2
R-PSDA
0.61
UG/L
PQL
0.035
J
537 Modified
3535
012224
CAP1Q24-PIW-10DR-
01/22/2024 320-109019-2
Hydrolyzed PSDA
2.3
UG/L
PQL
0.034
J
537 Modified
3535
012224
CAP1Q24-PIW-10DR-
01/22/2024 320-109019-2
R-EVE
0.40
UG/L
PQL
0.039
J
537 Modified
3535
012224
CAP1Q24-PIW-1D-012224
01/22/2024 320-109019-1
R-PSDA
0.38
UG/L
PQL
0.035
J
537 Modified
3535
Page 12 of 16
Site: Fayetteville Sampling Program: CAP GW Sampling 1Q24 Validation Options: LABSTATS
Validation Reason Code: Uncertainty around the analysis of R-PSDA, Hydrolyzed PSDA and R-EVE; J-qualifier added to all detects in the data set, even if there was no matrix spike analyzed for that
particular sample.
Date
Validation
Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result
Units
Type MDL
PQL
Qualifier
Method Pre -prep
Prep
CAP1Q24-PIW-1D-012224
01/22/2024 320-109019-1
R-EVE
0.18
UG/L
PQL
0.039
J
537 Modified
3535
CAP1Q24-PIW-4D-012224
01/22/2024 320-109019-3
R-PSDA
0.020
UG/L
PQL
0.0020
J
537 Modified
3535
CAP1Q24-PIW-4D-012224
01/22/2024 320-109019-3
Hydrolyzed PSDA
0.080
UG/L
PQL
0.0020
J
537 Modified
3535
CAP1Q24-PIW-4D-012224
01/22/2024 320-109019-3
R-EVE
0.012
UG/L
PQL
0.0020
J
537 Modified
3535
CAP1Q24-PIW-8D-012224
01/22/2024 320-109019-4
R-PSDA
2.6
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-PIW-8D-012224
01/22/2024 320-109019-4
Hydrolyzed PSDA
5.3
UG/L
PQL
0.034
J
537 Modified
3535
CAP1Q24-PIW-8D-012224
01/22/2024 320-109019-4
R-EVE
2.3
UG/L
PQL
0.039
J
537 Modified
3535
CAP1Q24-LTW-01-011724
01/17/2024 320-109020-1
R-PSDA
0.83
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-LTW-01-011724
01/17/2024 320-109020-1
R-PSDA
0.83
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-LTW-01-011724
01/17/2024 320-109020-1
Hydrolyzed PSDA
0.083
UG/L
PQL
0.034
J
537 Modified
3535
CAP1Q24-LTW-01-011724
01/17/2024 320-109020-1
Hydrolyzed PSDA
0.083
UG/L
PQL
0.034
J
537 Modified
3535
CAP1Q24-LTW-01-011724
01/17/2024 320-109020-1
R-EVE
0.31
UG/L
PQL
0.039
J
537 Modified
3535
CAP1Q24-LTW-01-011724
01/17/2024 320-109020-1
R-EVE
0.31
UG/L
PQL
0.039
J
537 Modified
3535
CAP 1Q24-LTW-02-011724
01/17/2024 320-109020-2
R-PSDA
0.78
UG/L
PQL
0.035
J
537 Modified
3535
CAP 1Q24-LTW-02-011724
01/17/2024 320-109020-2
R-PSDA
0.78
UG/L
PQL
0.035
J
537 Modified
3535
CAP 1Q24-LTW-02-011724
01/17/2024 320-109020-2
Hydrolyzed PSDA
1.8
UG/L
PQL
0.034
J
537 Modified
3535
CAP 1Q24-LTW-02-011724
01/17/2024 320-109020-2
Hydrolyzed PSDA
1.8
UG/L
PQL
0.034
J
537 Modified
3535
CAP 1Q24-LTW-02-011724
01/17/2024 320-109020-2
R-EVE
0.44
UG/L
PQL
0.039
J
537 Modified
3535
CAP 1Q24-LTW-02-011724
01/17/2024 320-109020-2
R-EVE
0.44
UG/L
PQL
0.039
J
537 Modified
3535
CAP 1Q24-LTW-04-011624
01/16/2024 320-108762-5
R-PSDA
1.4
UG/L
PQL
0.035
J
537 Modified
3535
CAP 1Q24-LTW-04-011624
01/16/2024 320-108762-5
Hydrolyzed PSDA
2.8
UG/L
PQL
0.034
J
537 Modified
3535
CAP 1Q24-LTW-04-011624
01/16/2024 320-108762-5
R-EVE
1.1
UG/L
PQL
0.039
J
537 Modified
3535
CAP 1Q24-LTW-05-011524
01/15/2024 320-108762-9
R-PSDA
1.3
UG/L
PQL
0.035
J
537 Modified
3535
Page 13 of 16
Site: Fayetteville
Sampling Program:
CAP GW Sampling 1Q24
Validation Options: LABSTATS
Validation Reason Code: Uncertainty around the analysis of R-PSDA, Hydrolyzed
PSDA and R-EVE; J-qualifier added to all detects in the data set, even if there was no matrix spike
analyzed for that
particular sample.
Date
Validation
Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result
Units
Type MDL
PQL
Qualifier
Method Pre -prep
Prep
CAP 1Q24-LTW-05-011524
01/15/2024 320-108762-9
Hydrolyzed PSDA
2.6
UG/L
PQL
0.034
J
537 Modified
3535
CAP 1Q24-LTW-05-011524
01/15/2024 320-108762-9
R-EVE
1.5
UG/L
PQL
0.039
J
537 Modified
3535
CAP1Q24-PIW-IS-011624
01/16/2024 320-108762-7
R-PSDA
0.11
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-PIW-7D-011524
01/15/2024 320-108762-1
R-PSDA
0.57
UG/L
PQL
0.035
J
537 Modified
3535
CAP1Q24-PIW-7D-011524
01/15/2024 320-108762-1
Hydrolyzed PSDA
1.1
UG/L
PQL
0.034
J
537 Modified
3535
CAP1Q24-PIW-7D-011524
01/15/2024 320-108762-1
R-EVE
0.54
UG/L
PQL
0.039
J
537 Modified
3535
CAP1Q24-PIW-7D-011524-
01/15/2024 320-108762-2
R-PSDA
0.56
UG/L
PQL
0.035
J
537 Modified
3535
D
CAP1Q24-PIW-7D-011524-
01/15/2024 320-108762-2
Hydrolyzed PSDA
1.1
UG/L
PQL
0.034
J
537 Modified
3535
D
CAP1Q24-PIW-7D-011524-
01/15/2024 320-108762-2
R-EVE
0.60
UG/L
PQL
0.039
J
537 Modified
3535
D
Page 14 of 16
Site: Fayetteville
Validation Reason Code
Sampling Program: CAP GW Sampling 1Q24 Validation Options: LABSTATS
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.
Date
Validation
Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result
Units
Type
MDL PQL
Qualifier
Method
CAP1Q24-PW-11-013124
01/31/2024 320-109381-10
Perfluoropentanoic
0.23
UG/L
PQL
0.061
J
537 Modified
Acid
CAP1Q24-PW-11-013124
01/31/2024 320-109381-10
PS Acid
0.097
UG/L
PQL
0.050
J
537 Modified
CAP1Q24-PW-11-013124
01/31/2024 320-109381-10
Perfluoroheptanoic
0.11
UG/L
PQL
0.031
J
537 Modified
Acid
CAP1Q24-PW-10RR-
01/31/2024 320-109381-6
Perfluoropentanoic
0.52
UG/L
PQL
0.061
J
537 Modified
013124
Acid
CAP1Q24-PIW-6S-013124
01/31/2024 320-109381-8
Perfluoropentanoic
0.76
UG/L
PQL
0.061
J
537 Modified
Acid
CAP1Q24-OW30-013024
01/30/2024 320-109381-3
Perfluoropentanoic
0.46
UG/L
PQL
0.061
J
537 Modified
Acid
CAP1Q24-OW-57-020624
02/06/2024 320-109475-7
PS Acid
0.33
UG/L
PQL
0.050
J
537 Modified
CAP1Q24-OW-51-013124
01/31/2024 320-109381-9
Perfluoroheptanoic
0.20
UG/L
PQL
0.031
J
537 Modified
Acid
CAP1Q24-OW-51-013124
01/31/2024 320-109381-9
Perfluoropentanoic
1.4
UG/L
PQL
0.061
J
537 Modified
Acid
CAP1Q24-OW-40-013024
01/30/2024 320-109381-4
Perfluoropentanoic
0.075
UG/L
PQL
0.061
J
537 Modified
Acid
CAP1Q24-OW-33-013024
01/30/2024 320-109381-5
Perfluoropentanoic
0.12
UG/L
PQL
0.061
J
537 Modified
Acid
CAP 1Q24-LTW-03-013124
01/31/2024 320-109381-7
Perfluoropentanoic
0.56
UG/L
PQL
0.061
J
537 Modified
Acid
Pre -prep
Prep
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
Page 15 of 16
Site: Fayetteville Sampling Program: CAP GW Sampling 1Q24 Validation Options
Validation Reason Code: The preparation hold time for this sample was exceeded. The reported result may be biased low.
Date
Validation
Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result
Units
Type
MDL PQL
Qualifier
Method
CAP1Q24-PW-06-011524
01/15/2024 320-108762-8
PPF Acid
0.95
UG/L
PQL
0.31
J
537 Modified
CAP1Q24-PW-06-011524
01/15/2024 320-108762-8
PPF Acid
0.59
UG/L
PQL
0.31
J
537 Modified
CAP1Q24-PW-06-011524
01/15/2024 320-108762-8
PFMOAA
0.13
ug/L
PQL
0.051
J
537 Modified
CAP1Q24-PIW-7S-011524
01/15/2024 320-108762-3
PPF Acid
17
UG/L
PQL
0.31
J
537 Modified
CAP1Q24-PIW-7S-011524
01/15/2024 320-108762-3
PPF Acid
11
UG/L
PQL
0.31
J
537 Modified
CAP1Q24-SMW-12-
01/16/2024 320-108762-4
PPF Acid
6.4
UG/L
PQL
0.31
J
537 Modified
011624
CAP1Q24-SMW-12-
01/16/2024 320-108762-4
PPF Acid
4.0
UG/L
PQL
0.31
J
537 Modified
011624
CAP 1Q24-LTW-04-011624
01/16/2024 320-108762-5
PPF Acid
43
UG/L
PQL
0.31
J
537 Modified
CAP 1Q24-LTW-04-011624
01/16/2024 320-108762-5
PPF Acid
28
UG/L
PQL
0.31
J
537 Modified
CAP1Q24-PIW-1S-011624
01/16/2024 320-108762-7
PPF Acid
1.3
UG/L
PQL
0.31
J
537 Modified
CAP1Q24-PIW-1S-011624
01/16/2024 320-108762-7
PPF Acid
0.79
UG/L
PQL
0.31
J
537 Modified
CAP1Q24-PIW-IS-011624
01/16/2024 320-108762-7
PFMOAA
0.39
ug/L
PQL
0.051
J
537 Modified
LABSTATS
Pre -prep
Prep
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
3535
Page 16 of 16
ADQM Data Review
Site: Chemours Fayetteville
Protect: Seep Flow Through Sampling 1 Q24 (update 3)
Project Reviewer: Bridget Gavaghan & Michael Aucoin
Sample Summary
Field Sample ID
Lab Sample ID
Sample
Filtered
Sample
Sample
Sample Purpose
Matrix
Date
Time
SEEP-A-INFLUENT-24-
Surface
320-108586-1
N
01/06/2024
23:00
FS
010624
Water
SEEP-C-INFLUENT-TSS-
320-108586-10
Surface
N
01/08/2024
10:50
FS
010824
Water
SEEP-C-EFFLUENT-TSS-
Surface
010824
320-108586-11
Water
N
01/08/2024
10:55
FS
SEEP-A-INFLUENT-24-
320-108586-2
Surface
N
01/06/2024
23:00
DUP
010624-D
Water
SEEP-A-EFFLUENT-24-
Surface
010624
320-108586-3
Water
N
01/06/2024
23:00
FS
SEEP-C-INFLUENT-24-
320-108586-4
Surface
N
01/06/2024
23:00
FS
010624
Water
SEEP-C-EFFLUENT-24-
320-108586-5
Surface
N
01/06/2024
23:00
FS
010624
Water
SEEP-EB-010824
320-108586-6
Blank Water
N
01/08/2024
09:50
EB
SEEP-FB-010824
320-108586-7
Blank Water
N
01/08/2024
09:55
FB
SEEP-A-INFLUENT-TSS-
Surface
320-108586-8
N
01/08/2024
11:35
FS
010824
Water
SEEP-A-EFFLUENT-TSS-
320-108586-9
Surface
N
01/08/2024
11:40
FS
010824
Water
SEEP-A-INFLUENT-24-
Surface
011024
320-108628-1
Water
N
01/10/2024
12:00
FS
SEEP-A-EFFLUENT-24-
Surface
320-108628-2
N
01/10/2024
12:00
FS
011024
Water
SEEP-B-INFLUENT-24-
Surface
320-108628-3
N
01/10/2024
12:00
FS
011024
Water
SEEP-B-EFFLUENT-24-
320-108628-4
Surface
N
01/10/2024
12:00
FS
011024
Water
SEEP-C-INFLUENT-24-
Surface
320-108628-5
N
01/10/2024
12:00
FS
011024
Water
SEEP-C-EFFLUENT-24-
320-108628-6
Surface
N
01/10/2024
12:00
FS
011024
Water
SEEP-D-INFLUENT-24-
320-108628-7
Surface
N
01/10/2024
12:00
FS
011024
Water
SEEP-D-EFFLUENT-24-
Surface
320-108628-8
N
01/10/2024
12:00
FS
011024
Water
SEEP-A-INFLUENT-TSS-
Surface
011024
320-108630-1
Water
N
01/10/2024
12:10
FS
SEEP-A-EFFLUENT-TSS-
Surface
320-108630-2
N
01/10/2024
12:15
FS
011024
Water
SEEP-B-INFLUENT-TSS-
320-108630-3
Surface
N
01/10/2024
12:40
FS
011024
Water
SEEP-B-EFFLUENT-TSS-
Surface
011024
320-108630-4
Water
N
01/10/2024
12:45
FS
SEEP-C-INFLUENT-TSS-
320-108630-5
Surface
N
01/10/2024
13:20
FS
011024
Water
SEEP-C-EFFLUENT-TSS-
Surface
011024
320-108630-6
Water
N
01/10/2024
13:25
FS
SEEP-D-INFLUENT-TSS-
320-108630-7
Surface
N
01/10/2024
13:40
FS
011024
Water
SEEP-D-EFFLUENT-TSS-
Surface
011024
320-108630-8
Water
N
01/10/2024
13:45
FS
SEEP-A-INFLUENT-24-
320-108999-1
Surface
N
01/20/2024
23:00
FS
012024
Water
SEEP-A-EFFLUENT-24-
Surface
012024
320-108999-2
Water
N
01/20/2024
23:00
FS
SEEP-B-INFLUENT-24-
320-108999-3
Surface
N
01/20/2024
23:00
FS
012024
Water
SEEP-B-EFFLUENT-24-
Surface
012024
320-108999-4
Water
N
01/20/2024
23:00
FS
Field Sample ID
Lab Sample ID
Sample
Filtered
Sample
Sample
Sample Purpose
Matrix
Date
Time
SEEP-C-INFLUENT-24-
Surface
012024
320-108999-5
Water
N
01/20/2024
23:00
FS
SEEP-C-EFFLUENT-24-
320-108999-6
Surface
N
01/20/2024
23:00
FS
012024
Water
SEEP-D-INFLUENT-24-
Surface
320-108999-7
N
01/20/2024
23:00
FS
012024
Water
SEEP- D-EFFLU ENT-24-
320-108999-8
Surface
N
01/20/2024
23:00
FS
012024
Water
SEEP-A-INFLUENT-TSS-
Surface
012324
320-109093-1
Water
N
01/23/2024
09:20
FS
SEEP-B-INFLUENT-TSS-
320-109093-2
Surface
N
01/23/2024
09:40
FS
012324
Water
SEEP-C-INFLUENT-TSS-
Surface
320-109093-3
N
01/23/2024
10:05
FS
012324
Water
SEEP-D-INFLUENT-TSS-
320-109093-4
Surface
N
01/23/2024
10:25
FS
012324
Water
SEEP-A-EFFLUENT-TSS-
320-109093-5
Surface
N
01/23/2024
09:25
FS
012324
Water
SEEP-B-EFFLUENT-TSS-
320-109093-6
Surface
N
01/23/2024
09:45
FS
012324
Water
SEEP-C-EFFLUENT-TSS-
320-109093-7
Surface
N
01/23/2024
10:10
FS
012324
Water
SEEP-D-EFFLUENT-TSS-
Surface
320-109093-8
N
01/23/2024
10:20
FS
012324
Water
SEEP-B-INFLUENT-24-
Surface
012524
320-109165-1
Water
N
01/25/2024
09:00
FS
SEEP-B-EFFLUENT-24-
Surface
012524
320-109165-2
Water
N
01/25/2024
09:00
FS
SEEP-D-INFLUENT-24-
320-109165-3
Surface
N
01/25/2024
09:00
FS
012524
Water
SEEP-D-EFFLUENT-24-
Surface
320-109165-4
N
01/25/2024
09:00
FS
012524
Water
SEEP-B-INFLUENT-TSS-
320-109165-5
Surface
N
01/25/2024
11:10
FS
012524
Water
SEEP-B-EFFLUENT-TSS-
Surface
320-109165-6
N
01/25/2024
11:15
FS
012524
Water
SEEP-D-INFLUENT-TSS-
320-109165-7
Surface
N
01/25/2024
10:40
FS
012524
Water
SEEP-D-EFFLUENT-TSS-
Surface
012524
320-109165-8
Water
N
01/25/2024
10:45
FS
SEEP-A-INFLUENT-24-
320-109311-1
Surface
N
01/31/2024
07:30
FS
013124
Water
SEEP-A-EFFLUENT-24-
Surface
013124
320-109311-2
Water
N
01/31/2024
07:30
FS
SEEP-B-INFLUENT-24-
320-109311-3
Surface
N
01/31/2024
07:30
FS
013124
Water
SEEP-B-EFFLUENT-24-
320-109311-4
Surface
N
01/31/2024
07:30
FS
013124
Water
SEEP-C-INFLUENT-24-
320-109311-5
Surface
N
01/31/2024
07:30
FS
013124
Water
SEEP-C-EFFLUENT-24-
320-109311-6
Surface
N
01/31/2024
07:30
FS
013124
Water
SEEP-D-INFLUENT-24-
Surface
013124
320-109311-7
Water
N
01/31/2024
07:30
FS
SEEP-D-EFFLUENT-24-
320-109311-8
Surface
N
01/31/2024
07:30
FS
013124
Water
SEEP-A-INFLUENT-TSS-
Surface
013124
320-109313-1
Water
N
01/31/2024
08:40
FS
SEEP-B-INFLUENT-TSS-
320-109313-2
Surface
N
01/31/2024
11:50
FS
013124
Water
SEEP-C-INFLUENT-TSS-
Surface
013124
320-109313-3
Water
N
01/31/2024
12:00
FS
SEEP-D-INFLUENT-TSS-
320-109313-4
Surface
N
01/31/2024
09:35
FS
013124
Water
Field Sample ID
Lab Sample ID
Sample
Filtered
Sample
Sample
Sample Purpose
Matrix
Date
Time
SEEP-A-EFFLUENT-TSS-
Surface
320-109313-5
N
01/31/2024
08:45
FS
013124
Water
SEEP-B-EFFLUENT-TSS-
320-109313-6
Surface
N
01/31/2024
11:55
FS
013124
Water
SEEP-C-EFFLUENT-TSS-
Surface
320-109313-7
N
01/31/2024
12:05
FS
013124
Water
SEEP- D-EFFLUENT-TSS-
320-109313-8
Surface
N
01/31/2024
09:40
FS
013124
Water
SEEP-A-INFLUENT-24-
Surface
320-109349-1
N
02/01/2024
07:38
FS
020124
Water
SEEP-A-EFFLUENT-24-
320-109349-2
Surface
N
02/01/2024
07:40
FS
020124
Water
SEEP-B-INFLUENT-24-
Surface
320-109349-3
N
02/01/2024
07:15
FS
020124
Water
SEEP-B-EFFLUENT-24-
320-109349-4
Surface
N
02/01/2024
07:12
FS
020124
Water
SEEP-C-INFLUENT-24-
320-109349-5
Surface
N
02/01/2024
06:58
FS
020124
Water
SEEP-C-EFFLUENT-24-
320-109349-6
Surface
N
02/01/2024
07:04
FS
020124
Water
SEEP-D-INFLUENT-24-
320-109349-7
Surface
N
02/01/2024
06:47
FS
020124
Water
SEEP-D-EFFLUENT-24-
320-109349-8
Surface
N
02/01/2024
06:46
FS
020124
Water
SEEP-A-INFLUENT-TSS-
320-109661-1
Surface
N
02/13/2024
09:50
FS
021324
Water
SEEP-B-INFLUENT-TSS-
Surface
320-109661-2
N
02/13/2024
10:30
FS
021324
Water
SEEP-C-INFLUENT-TSS-
320-109661-3
Surface
N
02/13/2024
10:40
FS
021324
Water
SEEP-D-INFLUENT-TSS-
Surface
021324
320-109661-4
Water
N
02/13/2024
11:00
FS
SEEP-A-EFFLUENT-TSS-
320-109661-5
Surface
N
02/13/2024
09:55
FS
021324
Water
SEEP-B-EFFLUENT-TSS-
Surface
021324
320-109661-6
Water
N
02/13/2024
10:35
FS
SEEP-C-EFFLUENT-TSS-
320-109661-7
Surface
N
02/13/2024
10:45
FS
021324
Water
SEEP-D-EFFLUENT-TSS-
Surface
021324
320-109661-8
Water
N
02/13/2024
11:05
FS
SEEP-A-INFLUENT-24-
320-109662-1
Surface
N
02/13/2024
00:44
FS
021324
Water
SEEP-FB-021324
320-109662-10
Blank Water
N
02/13/2024
09:40
FB
SEEP-EB-021324
320-109662-11
Blank Water
N
02/13/2024
09:45
EB
SEEP-A-EFFLUENT-24-
320-109662-2
Surface
N
02/13/2024
01:07
FS
021324
Water
SEEP-A-EFFLUENT-24-
Surface
021324-D
320-109662-3
Water
N
02/13/2024
01:07
DUP
SEEP-B-INFLUENT-24-
320-109662-4
Water
N
02/13/2024
00:26
FS
021324
SEEP-B-EFFLUENT-24-
021324
320-109662-5
Water
N
02/13/2024
00:56
FS
SEEP-C-INFLUENT-24-
320-109662-6
Surface
N
02/13/2024
01:00
FS
021324
Water
SEEP-C-EFFLUENT-24-
Surface
021324
320-109662-7
Water
N
02/13/2024
01:02
FS
SEEP-D-INFLUENT-24-
320-109662-8
Water
N
02/13/2024
01:17
FS
021324
SEEP-D-EFFLUENT-24-
021324
320-109662-9
Water
N
02/13/2024
01:43
FS
SEEP-A-INFLUENT-TSS-
320-109793-1
Surface
N
02/15/2024
12:30
FS
021524
Water
SEEP-B-INFLUENT-TSS-
Surface
021524
320-109793-2
Water
N
02/15/2024
12:50
FS
Field Sample ID
Lab Sample ID
Sample
Filtered
Sample
Sample
Sample Purpose
Matrix
Date
Time
SEEP-C-INFLUENT-TSS-
Surface
320-109793-3
N
02/15/2024
13:00
FS
021524
Water
SEEP-D-INFLUENT-TSS-
320-109793-4
Surface
N
02/15/2024
13:10
FS
021524
Water
SEEP-A-EFFLUENT-TSS-
Surface
320-109793-5
N
02/15/2024
12:35
FS
021524
Water
SEEP-B-EFFLUENT-TSS-
320-109793-6
Surface
N
02/15/2024
12:55
FS
021524
Water
SEEP-C-EFFLUENT-TSS-
Surface
320-109793-7
N
02/15/2024
13:05
FS
021524
Water
SEEP-D-EFFLUENT-TSS-
320-109793-8
Surface
N
02/15/2024
13:15
FS
021524
Water
SEEP-A-INFLUENT-24-
Surface
320-109798-1
N
02/14/2024
12:00
FS
021424
Water
SEEP-A-EFFLUENT-24-
320-109798-2
Surface
N
02/14/2024
12:00
FS
021424
Water
SEEP-B-INFLUENT-24-
320-109798-3
Surface
N
02/14/2024
12:00
FS
021424
Water
SEEP-B-EFFLUENT-24-
320-109798-4
Surface
N
02/14/2024
12:00
FS
021424
Water
SEEP-C-INFLUENT-24-
320-109798-5
Surface
N
02/14/2024
12:00
FS
021424
Water
SEEP-C-EFFLUENT-24-
320-109798-6
Surface
N
02/14/2024
12:00
FS
021424
Water
SEEP-D-INFLUENT-24-
320-109798-7
Surface
N
02/14/2024
12:00
FS
021424
Water
SEEP-D-EFFLUENT-24-
Surface
320-109798-8
N
02/14/2024
12:00
FS
021424
Water
SEEP-C-INFLUENT-24-
320-110063-1
Surface
N
02/24/2024
05:23
FS
022424
Water
SEEP-C-EFFLUENT-24-
Surface
022424
320-110063-2
Water
N
02/24/2024
05:33
FS
SEEP-A-INFLUENT-TSS-
320-110219-1
Surface
N
03/04/2024
08:20
FS
030424
Water
SEEP-B-INFLUENT-TSS-
Surface
030424
320-110219-2
Water
N
03/04/2024
08:55
FS
SEEP-C-INFLUENT-TSS-
320-110219-3
Surface
N
03/04/2024
09:25
FS
030424
Water
SEEP-D-INFLUENT-TSS-
Surface
030424
320-110219-4
Water
N
03/04/2024
09:50
FS
SEEP-A-EFFLUENT-TSS-
320-110219-5
Surface
N
03/04/2024
08:25
FS
030424
Water
SEEP-B-EFFLUENT-TSS-
Surface
030424
320-110219-6
Water
N
03/04/2024
09:00
FS
SEEP-C-EFFLUENT-TSS-
320-110219-7
Surface
N
03/04/2024
09:30
FS
030424
Water
SEEP-D-EFFLUENT-TSS-
320-110219-8
Surface
N
03/04/2024
09:55
FS
030424
Water
SEEP-A-INFLUENT-24-
320-110221-1
Surface
N
03/02/2024
18:03
FS
030224
Water
SEEP-FB-030424
320-110221-10
Blank Water
N
03/04/2024
08:20
FB
SEEP-EB-030424
320-110221-11
Blank Water
N
03/04/2024
08:25
EB
SEEP-A-INFLUENT-24-
320-110221-2
Surface
N
03/02/2024
18:03
DUP
030224-D
Water
SEEP-A-EFFLUENT-24-
Surface
030224
320-110221-3
Water
N
03/02/2024
18:45
FS
SEEP-B-INFLUENT-24-
320-110221-4
Surface
N
03/02/2024
16:20
FS
030224
Water
SEEP-B-EFFLUENT-24-
Surface
030224
320-110221-5
Water
N
03/02/2024
18:10
FS
SEEP-C-INFLUENT-24-
320-110221-6
Surface
N
03/02/2024
18:00
FS
030224
Water
SEEP-C-EFFLUENT-24-
Surface
030224
320-110221-7
Water
N
03/02/2024
18:06
FS
Field Sample ID
Lab Sample ID
Sample
Filtered
Sample
Sample
Sample Purpose
Matrix
Date
Time
SEEP-D-INFLUENT-24-
Surface
030224
320-110221-8
Water
N
03/02/2024
18:03
FS
SEEP-D-EFFLUENT-24-
320-110221-9
Surface
N
03/02/2024
18:18
FS
030224
Water
SEEP-A-INFLUENT-24-
Surface
030724
320-110365-1
Water
N
03/07/2024
09:50
FS
SEEP-A-EFFLUENT-24-
320-110365-2
Surface
N
03/07/2024
09:54
FS
030724
Water
SEEP-B-INFLUENT-24-
Surface
030724
320-110365-3
Water
N
03/07/2024
09:42
FS
SEEP-B-EFFLUENT-24-
320-110365-4
Surface
N
03/07/2024
09:54
FS
030724
Water
SEEP-C-INFLUENT-24-
Surface
320-110365-5
N
03/07/2024
09:46
FS
030724
Water
SEEP-C-EFFLUENT-24-
320-110365-6
Surface
N
03/07/2024
09:45
FS
030724
Water
SEEP-D-INFLUENT-24-
320-110365-7
Surface
N
03/07/2024
09:55
FS
030724
Water
SEEP-D-EFFLUENT-24-
320-110365-8
Surface
N
03/07/2024
09:59
FS
030724
Water
SEEP-A-INFLUENT-TSS-
320-110385-1
Surface
N
03/07/2024
10:25
FS
030724
Water
SEEP-B-INFLUENT-TSS-
Surface
320-110385-2
N
03/07/2024
11:00
FS
030724
Water
SEEP-C-INFLUENT-TSS-
Surface
030724
320-110385-3
Water
N
03/07/2024
11:10
FS
SEEP-D-INFLUENT-TSS-
Surface
030724
320-110385-4
Water
N
03/07/2024
11:20
FS
SEEP-A-EFFLUENT-TSS-
320-110385-5
Surface
N
03/07/2024
10:30
FS
030724
Water
SEEP-B-EFFLUENT-TSS-
Surface
320-110385-6
N
03/07/2024
11:05
FS
030724
Water
SEEP-C-EFFLUENT-TSS-
320-110385-7
Surface
N
03/07/2024
11:15
FS
030724
Water
SEEP-D-EFFLUENT-TSS-
Surface
320-110385-8
N
03/07/2024
11:25
FS
030724
Water
SEEP-A-INFLUENT-24-
Surface
320-110423-1
N
03/11/2024
07:24
FS
031124
Water
SEEP-A-EFFLUENT-24-
Surface
031124
320-110423-2
Water
N
03/11/2024
07:23
FS
SEEP-B-INFLUENT-24-
320-110423-3
Surface
N
03/11/2024
07:37
FS
031124
Water
SEEP-B-EFFLUENT-24-
Surface
031124
320-110423-4
Water
N
03/11/2024
07:35
FS
SEEP-C-INFLUENT-24-
320-110423-5
Surface
N
03/11/2024
07:35
FS
031124
Water
SEEP-C-EFFLUENT-24-
320-110423-6
Surface
N
03/11/2024
07:41
FS
031124
Water
SEEP-D-INFLUENT-24-
320-110423-7
Surface
N
03/11/2024
07:44
FS
031124
Water
SEEP-D-EFFLUENT-24-
320-110423-8
Surface
N
03/11/2024
07:45
FS
031124
Water
SEEP-A-INFLUENT-24-
Surface
032324
320-110828-1
Water
N
03/23/2024
23:00
FS
SEEP-A-EFFLUENT-24-
320-110828-2
Surface
N
03/23/2024
23:00
FS
032324
Water
SEEP-B-INFLUENT-24-
Surface
032324
320-110828-3
Water
N
03/23/2024
23:00
FS
SEEP-B-EFFLUENT-24-
320-110828-4
Surface
N
03/23/2024
23:00
FS
032324
Water
SEEP-C-INFLUENT-24-
Surface
03,
320-110828-5
Water
N
03/23/2024
23:00
FS
SEEP-C-EFFLUENT-24-
320-110828-6
Surface
N
03/23/2024
23:00
FS
032324
Water
Field Sample ID
Lab Sample ID
Sample
Filtered
Sample
Sample
Sample Purpose
Matrix
Date
Time
SEEP-D-INFLUENT-24-
Surface
032324
320-110828-7
Water
N
03/23/2024
23:00
FS
SEEP-D-EFFLUENT-24-
320-110828-8
Surface
N
03/23/2024
23:00
FS
032324
Water
SEEP-A-INFLUENT-TSS-
Surface
320-110831-1
N
03/25/2024
09:30
FS
032524
Water
SEEP- B-INFLU ENT-TSS-
320-110831-2
Surface
N
03/25/2024
08:45
FS
032524
Water
SEEP-C-INFLUENT-TSS-
Surface
032524
320-110831-3
Water
N
03/25/2024
08:25
FS
SEEP-D-INFLUENT-TSS-
320-110831-4
Surface
N
03/25/2024
08:00
FS
032524
Water
SEEP-A-EFFLUENT-TSS-
Surface
032524
320-110831-5
Water
N
03/25/2024
09:35
FS
SEEP-B-EFFLUENT-TSS-
320-110831-6
Surface
N
03/25/2024
08:50
FS
032524
Water
SEEP-C-EFFLUENT-TSS-
320-110831-7
Surface
N
03/25/2024
08:30
FS
032524
Water
SEEP- D-EFFLUENT-TSS-
320-110831-8
Surface
N
03/25/2024
08:05
FS
032524
Water
SEEP-A-INFLUENT-TSS-
320-111002-1
Surface
N
03/28/2024
12:10
FS
032824
Water
SEEP-B-INFLUENT-TSS-
Surface
320-111002-2
N
03/28/2024
12:30
FS
032824
Water
SEEP-C-INFLUENT-TSS-
Surface
032824
320-111002-3
Water
N
03/28/2024
12:45
FS
SEEP-D-INFLUENT-TSS-
Surface
032824
320-111002-4
Water
N
03/28/2024
13:00
FS
SEEP-A-EFFLUENT-TSS-
320-111002-5
Surface
N
03/28/2024
12:15
FS
032824
Water
SEEP-B-EFFLUENT-TSS-
Surface
320-111002-6
N
03/28/2024
12:35
FS
032824
Water
SEEP-C-EFFLUENT-TSS-
320-111002-7
Surface
N
03/28/2024
12:50
FS
032824
Water
SEEP-D-EFFLUENT-TSS-
Surface
320-111002-8
N
03/28/2024
13:05
FS
032824
Water
SEEP-A-INFLUENT-24-
320-111004-1
Surface
N
03/28/2024
12:00
FS
032824
Water
SEEP-A-EFFLUENT-24-
Surface
032824
320-111004-2
Water
N
03/28/2024
12:00
FS
SEEP-B-INFLUENT-24-
320-111004-3
Surface
N
03/28/2024
12:00
FS
032824
Water
SEEP-B-EFFLUENT-24-
Surface
032824
320-111004-4
Water
N
03/28/2024
12:00
FS
SEEP-C-INFLUENT-24-
320-111004-5
Surface
N
03/28/2024
12:00
FS
032824
Water
SEEP-C-EFFLUENT-24-
320-111004-6
Surface
N
03/28/2024
12:00
FS
032824
Water
SEEP-D-INFLUENT-24-
320-111004-7
Surface
N
03/28/2024
12:00
FS
032824
Water
SEEP-D-EFFLUENT-24-
320-111004-8
Surface
N
03/28/2024
12:00
FS
032824
Water
* FS=Field Sample
DUP=Field Duplicate
FB=Field Blank
EB=Equipment Blank
TB=Trip Blank
Analytical Protocol
Lab Name
Lab Method
Parameter Category
Sampling Program
Eurofins Environ
CI. Spec. Table 3
Per- and Polyfluorinated
Seep Flow Through Cell Sampling 2024
Testing Northern Cali
Compound SOP
Alkyl Substances PFAS
Eurofins Environ
Testing Northern Cali
SM 2540 D-2015
Total Suspended Solids
Seep Flow Through Cell Sampling 2024
ADQM Data Review Checklist
DVM
Laboratory
Exception
Item
Description
Yes
No*
Narrative
Report
Report (ER)
Report
#
Did samples meet laboratory acceptability
A
requirements upon receipt (i.e., intact, within
X
temperature, properly preserved, and no
heads ace where applicable)?
B
Were samples received by the laboratory in
X
agreement with the associated chain of custody?
C
Was the chain of custody properly completed by
X
the laboratory and/or field team?
D
Were samples prepped/analyzed by the laboratory
X
within method holding times?
Were data review criteria met for method blanks,
LCSs/LCSDs, MSs/MSDs, PDSs, SDs, replicates,
E
surrogates, sample results within calibration range,
X
X
X
total/dissolved samples, field duplicates,
field/equipment/trip blanks?
F
Were all data usable and not R qualified?
X
ER#
Description
Other QA/QC Items to Note:
See DVM Narrative Report, Laboratory Report, and/or ER # for further details as indicated.
The electronic data submitted for this project were reviewed via the Data Verification Module (DVM)
process. Overall, the data are acceptable for use without qualification, except as noted on the attached
DVM Narrative Report.
The lab reports due to a large page count are stored on a network shared drive and are available to be
posted on external shared drives, or on a flash drive.
Data Verification Module (DVM)
The DVM is an internal review process used by the ADQM group to assist with the determination of data
usability. The electronic data deliverables received from the laboratory are loaded into the Locus ElMTM
database and processed through a series of data quality checks, which are a combination of software,
Locus EIMTm database Data Verification Module (DVM), and manual reviewer evaluations. The data are
evaluated against the following data usability checks:
• Field and laboratory blank contamination
• US EPA hold time criteria
• Missing Quality Control (QC) samples
• Matrix spike (MS)/matrix spike duplicate (MSD) recoveries and the relative percent differences
(RPDs) between these spikes
• Laboratory control sample (LCS)/laboratory control sample duplicate (LCSD) recoveries and
the RPD between these spikes
• Surrogate spike recoveries for organic analyses
• Difference/RPD between field duplicate sample pairs
• RPD between laboratory replicates for inorganic analyses
• Difference/percent difference between total and dissolved sample pairs
• Temperature upon laboratory receipt meets the range of not frozen to 6 deg. C with a target of
4 deg. C (manual check)
There are two qualifier fields in EIM:
Laboratory Qualifier is the qualifier assigned by the laboratory and may not reflect the usability of
the data. This qualifier may have many different meanings and can vary between labs and over time
within the same lab. Please refer to the laboratory report for a description of the laboratory qualifiers.
As they are laboratory descriptors they are not to be used when evaluating the data.
Validation Qualifier is the 3rd party formal validation qualifier if this was performed. Otherwise this
field contains the qualifier resulting from the ADQM DVM review process. This qualifier assesses the
usability of the data and may not equal the laboratory qualifier. The DVM applies the following data
evaluation qualifiers to analysis results, as warranted:
Qualifier
Definition
B
Not detected substantially above the level reported in the laboratory or field
blanks.
R
Unusable result. Anal to may or may not be present in the sample.
J
Anal to present. Reported value may not be accurate or precise.
UJ
Not detected. Reporting limit may not be accurate or precise.
The Validation Status Code field is set to "DVM" if the ADQM DVM process has been performed. If the
DVM has not been run, the field will be blank.
If the DVM has been run (Validation Status Code equals "DVM"), use the Validation Qualifier.
If the data have been validated by a third party, the field "Validated By" will be set to the validator (e.g.,
ESI for Environmental Standards, Inc.)
DVM Narrative Report
Site: Fayetteville Sampling Program: Seep Flow Through Cell Sampling 2024 Validation Options: LABSTATS
Validation Reason Code: Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit. The actual detection limits may be higher than reported.
Date Validation Analytical
Field Sample ID Sampled Lab Sample ID Analyte Result Units Type MDL PQL Qualifier Method Pre -prep Prep
SEEP-A-INFLUENT-24- 02/14/2024 320-109798-1 PFECA B 0.027 UG/L PQL 0.027 UJ Cl. Spec. Table 3 PFAS_DI_Prep
021424 Compound SOP
Page 1 of 12
Site: Fayetteville
Validation Reason Code
Sampling Program: Seep Flow Through Cell Sampling 2024 Validation Options: LABSTATS
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biased high.
Date Validation Analytical
Field Sample ID Sampled Lab Sample ID Analyte Result Units Type MDL PQL Qualifier Method Pre -prep Prep
SEEP-A-INFLUENT-24- 03/28/2024 320-111004-1 PFMOAA 19 ug/L PQL 0.080 J Cl. Spec. Table 3 PFAS_DI_Prep
032824 Compound SOP
Page 2 of 12
Site: Fayetteville Sampling Program: Seep Flow Through Cell Sampling 2024 Validation Options: LABSTATS
Validation Reason Code: Quality review criteria exceeded between the REP (laboratory replicate) and parent sample. The reported result may be imprecise.
Date
Field Sample ID Sampled Lab Sample ID Analyte
SEEP-C-INFLUENT-TSS- 01/08/2024 320-108586-10 Total Suspended
010824 Solids
Result Units Type MDL
52 MG/L MDL 4.4
Validation
PQL Qualifier
13 J
Analytical
Method
SM 2540 D-2015
Pre -prep Prep
Page 3 of 12
Site: Fayetteville
Sampling Program:
Seep Flow Through Cell Sampling 2024
Validation Options:
LABSTATS
Validation Reason Code: Uncertainty around the analysis of R-PSDA, Hydrolyzed
PSDA and R-EVE; J-qualifier added to all detects in the data
set, even if there was no matrix spike analyzed for that
particular sample.
Date
Validation
Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result
Units
Type
MDL PQL
Qualifier
Method
Pre -prep Prep
SEEP-A-INFLUENT-24-
02/14/2024 320-109798-1
R-PSDA
0.81
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
021424
Compound SOP
SEEP-A-INFLUENT-24-
02/14/2024 320-109798-1
Hydrolyzed PSDA
2.0
UG/L
PQL
0.038
J
Cl. Spec. Table 3
PFAS_DI_Prep
021424
Compound SOP
SEEP-A-INFLUENT-24-
02/14/2024 320-109798-1
R-EVE
0.39
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
021424
Compound SOP
SEEP-A-INFLUENT-24-
03/02/2024 320-110221-1
R-PSDA
0.83
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
030224
Compound SOP
SEEP-A-INFLUENT-24-
03/02/2024 320-110221-1
Hydrolyzed PSDA
2.3
UG/L
PQL
0.050
J
Cl. Spec. Table 3
PFAS_DI_Prep
030224
Compound SOP
SEEP-A-INFLUENT-24-
03/02/2024 320-110221-1
R-EVE
0.47
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
030224
Compound SOP
SEEP-A-INFLUENT-24-
03/02/2024 320-110221-2
R-PSDA
0.86
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
030224-D
Compound SOP
SEEP-A-INFLUENT-24-
03/02/2024 320-110221-2
Hydrolyzed PSDA
2.3
UG/L
PQL
0.050
J
Cl. Spec. Table 3
PFAS_DI_Prep
030224-D
Compound SOP
SEEP-A-INFLUENT-24-
03/02/2024 320-110221-2
R-EVE
0.42
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
030224-D
Compound SOP
SEEP-A-INFLUENT-24-
03/07/2024 320-110365-1
R-PSDA
0.57
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
030724
Compound SOP
SEEP-A-INFLUENT-24-
03/07/2024 320-110365-1
Hydrolyzed PSDA
1.2
UG/L
PQL
0.050
J
Cl. Spec. Table 3
PFAS_DI_Prep
030724
Compound SOP
SEEP-A-INFLUENT-24-
03/07/2024 320-110365-1
R-EVE
0.28
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
030724
Compound SOP
SEEP-A-INFLUENT-24-
03/11/2024 320-110423-1
R-PSDA
0.88
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
031124
Compound SOP
SEEP-A-INFLUENT-24-
03/11/2024 320-110423-1
Hydrolyzed PSDA
1.3
UG/L
PQL
0.050
J
Cl. Spec. Table 3
PFAS_DI_Prep
031124
Compound SOP
SEEP-A-INFLUENT-24-
03/11/2024 320-110423-1
R-EVE
0.37
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
031124
Compound SOP
SEEP-A-INFLUENT-24-
03/23/2024 320-110828-1
R-PSDA
0.87
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
032324
Compound SOP
SEEP-A-INFLUENT-24-
03/23/2024 320-110828-1
Hydrolyzed PSDA
1.7
UG/L
PQL
0.050
J
Cl. Spec. Table 3
PFAS_DI_Prep
032324
Compound SOP
SEEP-A-INFLUENT-24-
03/23/2024 320-110828-1
R-EVE
0.40
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
032324
Compound SOP
SEEP-A-INFLUENT-24-
03/28/2024 320-111004-1
R-PSDA
0.75
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
032824
Compound SOP
SEEP-A-INFLUENT-24-
03/28/2024 320-111004-1
Hydrolyzed PSDA
1.6
UG/L
PQL
0.050
J
Cl. Spec. Table 3
PFAS_DI_Prep
032824
Compound SOP
SEEP-A-INFLUENT-24-
03/28/2024 320-111004-1
R-EVE
0.38
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
032824
Compound SOP
SEEP-B-EFFLUENT-24-
01/31/2024 320-109311-4
Hydrolyzed PSDA
0.0049
UG/L
PQL
0.0020
J
Cl. Spec. Table 3
PFAS_DI_Prep
013124
Compound SOP
SEEP-B-EFFLUENT-24-
02/01/2024 320-109349-4
Hydrolyzed PSDA
0.0053
UG/L
PQL
0.0020
J
Cl. Spec. Table 3
PFAS_DI_Prep
020124
Compound SOP
Page 4 of 12
Site: Fayetteville
Sampling Program:
Seep Flow Through Cell Sampling 2024
Validation Options:
LABSTATS
Validation Reason Code: Uncertainty around the analysis of R-PSDA, Hydrolyzed
PSDA and R-EVE; J-qualifier added to all detects in the data
set, even if there was no matrix spike analyzed for that
particular sample.
Date
Validation
Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result
Units
Type
MDL PQL
Qualifier
Method
Pre -prep Prep
SEEP-B-EFFLUENT-24-
02/13/2024 320-109662-5
R-PSDA
0.0024
UG/L
PQL
0.0020
J
Cl. Spec. Table 3
PFAS_DI_Prep
021324
Compound SOP
SEEP-B-EFFLUENT-24-
02/13/2024 320-109662-5
Hydrolyzed PSDA
0.0072
UG/L
PQL
0.0020
J
Cl. Spec. Table 3
PFAS_DI_Prep
021324
Compound SOP
SEEP-B-EFFLUENT-24-
03/02/2024 320-110221-5
Hydrolyzed PSDA
0.0036
UG/L
PQL
0.0020
J
Cl. Spec. Table 3
PFAS_DI_Prep
030224
Compound SOP
SEEP-B-EFFLUENT-24-
03/23/2024 320-110828-4
Hydrolyzed PSDA
0.0047
UG/L
PQL
0.0020
J
Cl. Spec. Table 3
PFAS_DI_Prep
032324
Compound SOP
SEEP-B-EFFLUENT-24-
03/28/2024 320-111004-4
Hydrolyzed PSDA
0.0059
UG/L
PQL
0.0020
J
Cl. Spec. Table 3
PFAS_DI_Prep
032824
Compound SOP
SEEP-D-INFLUENT-24-
01/10/2024 320-108628-7
R-PSDA
0.14
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
011024
Compound SOP
SEEP-D-INFLUENT-24-
01/10/2024 320-108628-7
Hydrolyzed PSDA
0.19
UG/L
PQL
0.038
J
Cl. Spec. Table 3
PFAS_DI_Prep
011024
Compound SOP
SEEP-D-INFLUENT-24-
01/10/2024 320-108628-7
R-EVE
0.13
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
011024
Compound SOP
SEEP-D-INFLUENT-24-
01/20/2024 320-108999-7
R-PSDA
0.10
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
012024
Compound SOP
SEEP-D-INFLUENT-24-
01/20/2024 320-108999-7
Hydrolyzed PSDA
0.062
UG/L
PQL
0.038
J
Cl. Spec. Table 3
PFAS_DI_Prep
012024
Compound SOP
SEEP-D-INFLUENT-24-
01/20/2024 320-108999-7
R-EVE
0.073
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
012024
Compound SOP
SEEP-D-INFLUENT-24-
01/25/2024 320-109165-3
R-PSDA
0.12
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
012524
Compound SOP
SEEP-D-INFLUENT-24-
01/25/2024 320-109165-3
Hydrolyzed PSDA
0.069
UG/L
PQL
0.038
J
Cl. Spec. Table 3
PFAS_DI_Prep
012524
Compound SOP
SEEP-D-INFLUENT-24-
01/25/2024 320-109165-3
R-EVE
0.086
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
012524
Compound SOP
SEEP-D-INFLUENT-24-
01/31/2024 320-109311-7
R-PSDA
0.11
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
013124
Compound SOP
SEEP-D-INFLUENT-24-
01/31/2024 320-109311-7
Hydrolyzed PSDA
0.088
UG/L
PQL
0.038
J
Cl. Spec. Table 3
PFAS_DI_Prep
013124
Compound SOP
SEEP-D-INFLUENT-24-
01/31/2024 320-109311-7
R-EVE
0.077
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
013124
Compound SOP
SEEP-D-INFLUENT-24-
02/01/2024 320-109349-7
R-PSDA
0.12
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
020124
Compound SOP
SEEP-D-INFLUENT-24-
02/01/2024 320-109349-7
Hydrolyzed PSDA
0.090
UG/L
PQL
0.038
J
Cl. Spec. Table 3
PFAS_DI_Prep
020124
Compound SOP
SEEP-D-INFLUENT-24-
02/13/2024 320-109662-8
R-PSDA
0.17
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
021324
Compound SOP
SEEP-D-INFLUENT-24-
02/13/2024 320-109662-8
Hydrolyzed PSDA
0.12
UG/L
PQL
0.038
J
Cl. Spec. Table 3
PFAS_DI_Prep
021324
Compound SOP
SEEP-D-INFLUENT-24-
02/13/2024 320-109662-8
R-EVE
0.10
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
021324
Compound SOP
SEEP-D-INFLUENT-24-
02/14/2024 320-109798-7
R-PSDA
0.20
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
021424
Compound SOP
Page 5 of 12
Site: Fayetteville
Sampling Program:
Seep Flow Through Cell Sampling 2024
Validation Options:
LABSTATS
Validation Reason Code: Uncertainty around the analysis of R-PSDA, Hydrolyzed
PSDA and R-EVE; J-qualifier added to all detects in the data
set, even if there was no matrix spike analyzed for that
particular sample.
Date
Validation
Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result
Units
Type
MDL PQL
Qualifier
Method
Pre -prep Prep
SEEP-D-INFLUENT-24-
02/14/2024 320-109798-7
Hydrolyzed PSDA
0.16
UG/L
PQL
0.038
J
Cl. Spec. Table 3
PFAS_DI_Prep
021424
Compound SOP
SEEP-D-INFLUENT-24-
02/14/2024 320-109798-7
R-EVE
0.13
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
021424
Compound SOP
SEEP-D-INFLUENT-24-
03/02/2024 320-110221-8
R-PSDA
0.29
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
030224
Compound SOP
SEEP-D-INFLUENT-24-
03/02/2024 320-110221-8
Hydrolyzed PSDA
0.26
UG/L
PQL
0.050
J
Cl. Spec. Table 3
PFAS_DI_Prep
030224
Compound SOP
SEEP-D-INFLUENT-24-
03/02/2024 320-110221-8
R-EVE
0.19
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
030224
Compound SOP
SEEP-D-INFLUENT-24-
03/07/2024 320-110365-7
R-PSDA
0.22
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
030724
Compound SOP
SEEP-D-INFLUENT-24-
03/07/2024 320-110365-7
Hydrolyzed PSDA
0.22
UG/L
PQL
0.050
J
Cl. Spec. Table 3
PFAS_DI_Prep
030724
Compound SOP
SEEP-D-INFLUENT-24-
03/07/2024 320-110365-7
R-EVE
0.16
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
030724
Compound SOP
SEEP-D-INFLUENT-24-
03/11/2024 320-110423-7
R-PSDA
0.36
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
031124
Compound SOP
SEEP-D-INFLUENT-24-
03/11/2024 320-110423-7
Hydrolyzed PSDA
0.33
UG/L
PQL
0.050
J
Cl. Spec. Table 3
PFAS_DI_Prep
031124
Compound SOP
SEEP-D-INFLUENT-24-
03/11/2024 320-110423-7
R-EVE
0.27
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
031124
Compound SOP
SEEP-D-INFLUENT-24-
03/23/2024 320-110828-7
R-PSDA
0.33
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
032324
Compound SOP
SEEP-D-INFLUENT-24-
03/23/2024 320-110828-7
Hydrolyzed PSDA
0.30
UG/L
PQL
0.050
J
Cl. Spec. Table 3
PFAS_DI_Prep
032324
Compound SOP
SEEP-D-INFLUENT-24-
03/23/2024 320-110828-7
R-EVE
0.22
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
032324
Compound SOP
SEEP-D-INFLUENT-24-
03/28/2024 320-111004-7
R-PSDA
0.33
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
032824
Compound SOP
SEEP-D-INFLUENT-24-
03/28/2024 320-111004-7
Hydrolyzed PSDA
0.29
UG/L
PQL
0.050
J
Cl. Spec. Table 3
PFAS_DI_Prep
032824
Compound SOP
SEEP-D-INFLUENT-24-
03/28/2024 320-111004-7
R-EVE
0.23
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
032824
Compound SOP
SEEP-B-INFLUENT-24-
01/10/2024 320-108628-3
R-PSDA
0.27
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
011024
Compound SOP
SEEP-B-INFLUENT-24-
01/10/2024 320-108628-3
Hydrolyzed PSDA
0.91
UG/L
PQL
0.038
J
Cl. Spec. Table 3
PFAS_DI_Prep
011024
Compound SOP
SEEP-B-INFLUENT-24-
01/10/2024 320-108628-3
R-EVE
0.21
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
011024
Compound SOP
SEEP-B-INFLUENT-24-
01/20/2024 320-108999-3
R-PSDA
0.43
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
012024
Compound SOP
SEEP-B-INFLUENT-24-
01/20/2024 320-108999-3
Hydrolyzed PSDA
0.94
UG/L
PQL
0.038
J
Cl. Spec. Table 3
PFAS_DI_Prep
012024
Compound SOP
SEEP-B-INFLUENT-24-
01/20/2024 320-108999-3
R-EVE
0.28
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
012024
Compound SOP
Page 6 of 12
Site: Fayetteville
Sampling Program:
Seep Flow Through Cell Sampling 2024
Validation Options:
LABSTATS
Validation Reason Code: Uncertainty around the analysis of R-PSDA, Hydrolyzed
PSDA and R-EVE; J-qualifier added to all detects in the data
set, even if there was no matrix spike analyzed for that
particular sample.
Date
Validation
Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result
Units
Type
MDL PQL
Qualifier
Method
Pre -prep Prep
SEEP-B-INFLUENT-24-
01/25/2024 320-109165-1
R-PSDA
0.37
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
012524
Compound SOP
SEEP-B-INFLUENT-24-
01/25/2024 320-109165-1
Hydrolyzed PSDA
0.94
UG/L
PQL
0.038
J
Cl. Spec. Table 3
PFAS_DI_Prep
012524
Compound SOP
SEEP-B-INFLUENT-24-
01/25/2024 320-109165-1
R-EVE
0.26
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
012524
Compound SOP
SEEP-B-INFLUENT-24-
01/31/2024 320-109311-3
R-PSDA
0.29
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
013124
Compound SOP
SEEP-B-INFLUENT-24-
01/31/2024 320-109311-3
Hydrolyzed PSDA
1.1
UG/L
PQL
0.038
J
Cl. Spec. Table 3
PFAS_DI_Prep
013124
Compound SOP
SEEP-B-INFLUENT-24-
01/31/2024 320-109311-3
R-EVE
0.21
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
013124
Compound SOP
SEEP-B-INFLUENT-24-
02/01/2024 320-109349-3
R-PSDA
0.28
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
020124
Compound SOP
SEEP-B-INFLUENT-24-
02/01/2024 320-109349-3
Hydrolyzed PSDA
1.1
UG/L
PQL
0.038
J
Cl. Spec. Table 3
PFAS_DI_Prep
020124
Compound SOP
SEEP-B-INFLUENT-24-
02/01/2024 320-109349-3
R-EVE
0.21
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
020124
Compound SOP
SEEP-B-INFLUENT-24-
02/13/2024 320-109662-4
R-PSDA
0.36
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
021324
Compound SOP
SEEP-B-INFLUENT-24-
02/13/2024 320-109662-4
Hydrolyzed PSDA
1.4
UG/L
PQL
0.038
J
Cl. Spec. Table 3
PFAS_DI_Prep
021324
Compound SOP
SEEP-B-INFLUENT-24-
02/13/2024 320-109662-4
R-EVE
0.24
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
021324
Compound SOP
SEEP-B-INFLUENT-24-
02/14/2024 320-109798-3
R-PSDA
0.47
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
021424
Compound SOP
SEEP-B-INFLUENT-24-
02/14/2024 320-109798-3
Hydrolyzed PSDA
0.94
UG/L
PQL
0.038
J
Cl. Spec. Table 3
PFAS_DI_Prep
021424
Compound SOP
SEEP-B-INFLUENT-24-
02/14/2024 320-109798-3
R-EVE
0.28
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
021424
Compound SOP
SEEP-B-INFLUENT-24-
03/02/2024 320-110221-4
R-PSDA
0.57
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
030224
Compound SOP
SEEP-B-INFLUENT-24-
03/02/2024 320-110221-4
Hydrolyzed PSDA
1.7
UG/L
PQL
0.050
J
Cl. Spec. Table 3
PFAS_DI_Prep
030224
Compound SOP
SEEP-B-INFLUENT-24-
03/02/2024 320-110221-4
R-EVE
0.37
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
030224
Compound SOP
SEEP-B-INFLUENT-24-
03/07/2024 320-110365-3
R-PSDA
0.26
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
030724
Compound SOP
SEEP-B-INFLUENT-24-
03/07/2024 320-110365-3
Hydrolyzed PSDA
0.44
UG/L
PQL
0.050
J
Cl. Spec. Table 3
PFAS_DI_Prep
030724
Compound SOP
SEEP-B-INFLUENT-24-
03/07/2024 320-110365-3
R-EVE
0.19
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
030724
Compound SOP
SEEP-B-INFLUENT-24-
03/11/2024 320-110423-3
R-PSDA
0.59
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
031124
Compound SOP
SEEP-B-INFLUENT-24-
03/11/2024 320-110423-3
Hydrolyzed PSDA
0.76
UG/L
PQL
0.050
J
Cl. Spec. Table 3
PFAS_DI_Prep
031124
Compound SOP
Page 7 of 12
Site: Fayetteville
Sampling Program:
Seep Flow Through Cell Sampling 2024
Validation Options:
LABSTATS
Validation Reason Code: Uncertainty around the analysis of R-PSDA, Hydrolyzed
PSDA and R-EVE; J-qualifier added to all detects in the data
set, even if there was no matrix spike analyzed for that
particular sample.
Date
Validation
Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result
Units
Type
MDL PQL
Qualifier
Method
Pre -prep Prep
SEEP-B-INFLUENT-24-
03/11/2024 320-110423-3
R-EVE
0.35
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
031124
Compound SOP
SEEP-B-INFLUENT-24-
03/23/2024 320-110828-3
R-PSDA
0.78
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
032324
Compound SOP
SEEP-B-INFLUENT-24-
03/23/2024 320-110828-3
Hydrolyzed PSDA
1.9
UG/L
PQL
0.050
J
Cl. Spec. Table 3
PFAS_DI_Prep
032324
Compound SOP
SEEP-B-INFLUENT-24-
03/23/2024 320-110828-3
R-EVE
0.54
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
032324
Compound SOP
SEEP-B-INFLUENT-24-
03/28/2024 320-111004-3
R-PSDA
0.74
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
032824
Compound SOP
SEEP-B-INFLUENT-24-
03/28/2024 320-111004-3
Hydrolyzed PSDA
1.6
UG/L
PQL
0.050
J
Cl. Spec. Table 3
PFAS_DI_Prep
032824
Compound SOP
SEEP-B-INFLUENT-24-
03/28/2024 320-111004-3
R-EVE
0.54
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
032824
Compound SOP
SEEP-C-EFFLUENT-24-
03/23/2024 320-110828-6
R-PSDA
0.0043
UG/L
PQL
0.0020
J
Cl. Spec. Table 3
PFAS_DI_Prep
032324
Compound SOP
SEEP-C-EFFLUENT-24-
03/23/2024 320-110828-6
Hydrolyzed PSDA
0.0047
UG/L
PQL
0.0020
J
Cl. Spec. Table 3
PFAS_DI_Prep
032324
Compound SOP
SEEP-C-INFLUENT-24-
01/06/2024 320-108586-4
R-PSDA
0.29
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
010624
Compound SOP
SEEP-C-INFLUENT-24-
01/06/2024 320-108586-4
R-EVE
0.30
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
010624
Compound SOP
SEEP-C-INFLUENT-24-
01/10/2024 320-108628-5
R-PSDA
0.18
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
011024
Compound SOP
SEEP-C-INFLUENT-24-
01/10/2024 320-108628-5
R-EVE
0.15
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
011024
Compound SOP
SEEP-C-INFLUENT-24-
01/20/2024 320-108999-5
R-PSDA
0.43
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
012024
Compound SOP
SEEP-C-INFLUENT-24-
01/20/2024 320-108999-5
R-EVE
0.39
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
012024
Compound SOP
SEEP-C-INFLUENT-24-
01/31/2024 320-109311-5
R-PSDA
0.24
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
013124
Compound SOP
SEEP-C-INFLUENT-24-
01/31/2024 320-109311-5
R-EVE
0.22
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
013124
Compound SOP
SEEP-C-INFLUENT-24-
02/01/2024 320-109349-5
R-PSDA
0.26
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
020124
Compound SOP
SEEP-C-INFLUENT-24-
02/01/2024 320-109349-5
R-EVE
0.25
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
020124
Compound SOP
SEEP-C-INFLUENT-24-
02/13/2024 320-109662-6
R-PSDA
0.25
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
021324
Compound SOP
SEEP-C-INFLUENT-24-
02/13/2024 320-109662-6
R-EVE
0.23
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
021324
Compound SOP
SEEP-C-INFLUENT-24-
02/14/2024 320-109798-5
R-PSDA
0.23
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
021424
Compound SOP
SEEP-C-INFLUENT-24-
02/14/2024 320-109798-5
R-EVE
0.17
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
021424
Compound SOP
Page 8 of 12
Site: Fayetteville
Sampling Program:
Seep Flow Through Cell Sampling 2024
Validation Options:
LABSTATS
Validation Reason Code: Uncertainty around the analysis of R-PSDA, Hydrolyzed
PSDA and R-EVE; J-qualifier added to all detects in the data
set, even if there was no matrix spike analyzed for that
particular sample.
Date
Validation
Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result
Units
Type
MDL PQL
Qualifier
Method
Pre -prep Prep
SEEP-C-INFLUENT-24-
02/24/2024 320-110063-1
R-PSDA
0.30
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
022424
Compound SOP
SEEP-C-INFLUENT-24-
02/24/2024 320-110063-1
Hydrolyzed PSDA
0.041
UG/L
PQL
0.038
J
Cl. Spec. Table 3
PFAS_DI_Prep
022424
Compound SOP
SEEP-C-INFLUENT-24-
02/24/2024 320-110063-1
R-EVE
0.25
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
022424
Compound SOP
SEEP-C-INFLUENT-24-
03/02/2024 320-110221-6
R-PSDA
0.35
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
030224
Compound SOP
SEEP-C-INFLUENT-24-
03/02/2024 320-110221-6
R-EVE
0.29
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
030224
Compound SOP
SEEP-C-INFLUENT-24-
03/07/2024 320-110365-5
R-PSDA
0.20
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
030724
Compound SOP
SEEP-C-INFLUENT-24-
03/07/2024 320-110365-5
R-EVE
0.16
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
030724
Compound SOP
SEEP-C-INFLUENT-24-
03/11/2024 320-110423-5
R-PSDA
0.48
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
031124
Compound SOP
SEEP-C-INFLUENT-24-
03/11/2024 320-110423-5
R-EVE
0.39
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
031124
Compound SOP
SEEP-C-INFLUENT-24-
03/23/2024 320-110828-5
R-PSDA
0.48
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
032324
Compound SOP
SEEP-C-INFLUENT-24-
03/23/2024 320-110828-5
R-EVE
0.43
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
032324
Compound SOP
SEEP-C-INFLUENT-24-
03/28/2024 320-111004-5
R-PSDA
0.44
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
032824
Compound SOP
SEEP-C-INFLUENT-24-
03/28/2024 320-111004-5
R-EVE
0.36
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
032824
Compound SOP
SEEP-A-INFLUENT-24-
01/06/2024 320-108586-1
R-PSDA
0.53
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
010624
Compound SOP
SEEP-A-INFLUENT-24-
01/06/2024 320-108586-1
Hydrolyzed PSDA
1.8
UG/L
PQL
0.038
J
Cl. Spec. Table 3
PFAS_DI_Prep
010624
Compound SOP
SEEP-A-INFLUENT-24-
01/06/2024 320-108586-1
R-EVE
0.29
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
010624
Compound SOP
SEEP-A-INFLUENT-24-
01/06/2024 320-108586-2
R-PSDA
0.58
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
010624-D
Compound SOP
SEEP-A-INFLUENT-24-
01/06/2024 320-108586-2
Hydrolyzed PSDA
1.7
UG/L
PQL
0.038
J
Cl. Spec. Table 3
PFAS_DI_Prep
010624-D
Compound SOP
SEEP-A-INFLUENT-24-
01/06/2024 320-108586-2
R-EVE
0.26
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
010624-D
Compound SOP
SEEP-A-INFLUENT-24-
01/10/2024 320-108628-1
R-PSDA
0.46
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
011024
Compound SOP
SEEP-A-INFLUENT-24-
01/10/2024 320-108628-1
Hydrolyzed PSDA
1.2
UG/L
PQL
0.038
J
Cl. Spec. Table 3
PFAS_DI_Prep
011024
Compound SOP
SEEP-A-INFLUENT-24-
01/10/2024 320-108628-1
R-EVE
0.18
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
011024
Compound SOP
SEEP-A-INFLUENT-24-
01/20/2024 320-108999-1
R-PSDA
0.64
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
012024
Compound SOP
Page 9 of 12
Site: Fayetteville
Sampling Program:
Seep Flow Through Cell Sampling 2024
Validation Options: LABSTATS
Validation Reason Code: Uncertainty around the analysis of R-PSDA, Hydrolyzed
PSDA and R-EVE; J-qualifier added to all detects in the data
set, even if there was no matrix spike
analyzed for that
particular sample.
Date
Validation
Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result
Units
Type
MDL PQL
Qualifier
Method Pre -prep
Prep
SEEP-A-INFLUENT-24-
01/20/2024 320-108999-1
Hydrolyzed PSDA
0.87
UG/L
PQL
0.038
J
Cl. Spec. Table 3
PFAS_DI_Prep
012024
Compound SOP
SEEP-A-INFLUENT-24-
01/20/2024 320-108999-1
R-EVE
0.30
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
012024
Compound SOP
SEEP-A-INFLUENT-24-
01/31/2024 320-109311-1
R-PSDA
0.57
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
013124
Compound SOP
SEEP-A-INFLUENT-24-
01/31/2024 320-109311-1
Hydrolyzed PSDA
1.8
UG/L
PQL
0.038
J
Cl. Spec. Table 3
PFAS_DI_Prep
013124
Compound SOP
SEEP-A-INFLUENT-24-
01/31/2024 320-109311-1
R-EVE
0.30
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
013124
Compound SOP
SEEP-A-INFLUENT-24-
02/01/2024 320-109349-1
R-PSDA
0.60
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
020124
Compound SOP
SEEP-A-INFLUENT-24-
02/01/2024 320-109349-1
Hydrolyzed PSDA
2.0
UG/L
PQL
0.038
J
Cl. Spec. Table 3
PFAS_DI_Prep
020124
Compound SOP
SEEP-A-INFLUENT-24-
02/01/2024 320-109349-1
R-EVE
0.32
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
020124
Compound SOP
SEEP-A-INFLUENT-24-
02/13/2024 320-109662-1
R-PSDA
0.62
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
021324
Compound SOP
SEEP-A-INFLUENT-24-
02/13/2024 320-109662-1
Hydrolyzed PSDA
1.9
UG/L
PQL
0.038
J
Cl. Spec. Table 3
PFAS_DI_Prep
021324
Compound SOP
SEEP-A-INFLUENT-24-
02/13/2024 320-109662-1
R-EVE
0.32
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
021324
Compound SOP
Page 10 of 12
Site: Fayetteville
Sampling Program:
Seep Flow Through Cell Sampling 2024
Validation Options: LABSTATS
Validation Reason Code: Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower
control limit but above the rejection limit. The reported result may be
biased low.
Date
Validation Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result Units Type MDL PQL
Qualifier Method Pre -prep Prep
SEEP-A-INFLUENT-24-
03/07/2024 320-110365-1
PFMOAA
12 ug/L PQL 0.080
J Cl. Spec. Table 3 PFAS_DI_Prep
030724
Compound SOP
SEEP-A-EFFLUENT-24-
02/13/2024 320-109662-2
PFMOAA
0.023 ug/L PQL 0.0020
J Cl. Spec. Table 3 PFAS_DI_Prep
021324
Compound SOP
Page 11 of 12
Site: Fayetteville
Validation Reason Code
Sampling Program: Seep Flow Through Cell Sampling 2024 Validation Options: LABSTATS
The result is estimated since the concentration is between the method detection limit and practical quantitation limit.
Date
Validation
Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result
Units
Type
MDL
PQL
Qualifier
Method
SEEP-A-EFFLUENT-TSS-
02/13/2024 320-109661-5
Total Suspended
2.1
MG/L
MDL
1.0
3.0
J
SM 2540 D-2015
021324
Solids
SEEP-A-EFFLUENT-TSS-
02/15/2024 320-109793-5
Total Suspended
1.0
MG/L
MDL
1.0
3.0
J
SM 2540 D-2015
021524
Solids
SEEP-A-EFFLUENT-TSS-
03/04/2024 320-110219-5
Total Suspended
1.5
MG/L
MDL
1.0
3.0
J
SM 2540 D-2015
030424
Solids
SEEP-A-EFFLUENT-TSS-
03/07/2024 320-110385-5
Total Suspended
2.0
MG/L
MDL
1.0
3.0
J
SM 2540 D-2015
030724
Solids
SEEP-A-EFFLUENT-TSS-
03/25/2024 320-110831-5
Total Suspended
1.3
MG/L
MDL
1.0
3.0
J
SM 2540 D-2015
032524
Solids
SEEP-A-EFFLUENT-TSS-
03/28/2024 320-111002-5
Total Suspended
2.6
MG/L
MDL
1.0
3.0
J
SM 2540 D-2015
032824
Solids
SEEP-D-EFFLUENT-TSS-
01/10/2024 320-108630-8
Total Suspended
1.2
MG/L
MDL
1.0
3.0
J
SM 2540 D-2015
011024
Solids
SEEP-D-EFFLUENT-TSS-
01/23/2024 320-109093-8
Total Suspended
1.5
MG/L
MDL
1.0
3.0
J
SM 2540 D-2015
012324
Solids
SEEP-D-EFFLUENT-TSS-
01/31/2024 320-109313-8
Total Suspended
2.3
MG/L
MDL
1.0
3.0
J
SM 2540 D-2015
013124
Solids
SEEP-D-EFFLUENT-TSS-
02/13/2024 320-109661-8
Total Suspended
1.9
MG/L
MDL
1.0
3.0
J
SM 2540 D-2015
021324
Solids
SEEP-B-EFFLUENT-TSS-
02/13/2024 320-109661-6
Total Suspended
1.2
MG/L
MDL
1.0
3.0
J
SM 2540 D-2015
021324
Solids
SEEP-B-EFFLUENT-TSS-
02/15/2024 320-109793-6
Total Suspended
1.2
MG/L
MDL
1.0
3.0
J
SM 2540 D-2015
021524
Solids
SEEP-B-EFFLUENT-TSS-
03/04/2024 320-110219-6
Total Suspended
1.6
MG/L
MDL
1.0
3.0
J
SM 2540 D-2015
030424
Solids
Pre -prep Prep
Page 12 of 12
ADQM Data Review
Site: Chemours Fayetteville
Protect: 004 NPDES Sampling 01/24, 02/24, 03/24
Project Reviewer: Bridget Gavaghan
Sample Summary
Field Sample ID
Lab Sample
ID
Sample
Matrix
Filtered
Sample
Date
Sample
Time
Sample
Purpose
004-INF-0124-2
320-108480-1
Other Liquid
N
01/02/2024
08:00
FS
004-EFF-0124-2
320-108480-2
Other Liquid
N
01/02/2024
08:00
FS
004-INF-0124-
2A
320-108578-1
Other Liquid
N
01/08/2024
08:00
FS
004-EFF-0124-
2A
320-108578-2
Other Liquid
N
01/08/2024
08:00
FS
004-INF-0124-3
320-108740-1
Other Liquid
N
01/15/2024
07:30
FS
004-EFF-0124-3
320-108740-2
Other Liquid
N
01/15/2024
07:30
FS
004-INF-0124-4
320-109025-1
Other Liquid
N
01/22/2024
07:30
FS
004-EFF-0124-4
320-109025-2
Other Liquid
N
01/22/2024
07:30
FS
004-FBLK-0124
320-109211-1
Blank Water
N
01/29/2024
07:30
FB
004-INF-0124-5
320-109212-1
Other Liquid
N
01/29/2024
07:30
FS
004-EFF-0124-5
320-109212-2
Other Liquid
N
01/29/2024
07:30
FS
004-INF-0224
320-109451-1
Other Liquid
N
02/05/2024
07:30
FS
004-EFF-0224
320-109451-2
Other Liquid
N
02/05/2024
07:30
FS
004-INF-0224-2
320-109597-1
Other Liquid
N
02/12/2024
07:45
FS
004-EFF-0224-2
320-109597-2
Other Liquid
N
02/12/2024
07:45
FS
004-FBLK-0224
320-109597-3
Blank Water
N
02/12/2024
07:45
FB
004-INF-0224-3
320-109834-1
Other Liquid
N
02/19/2024
07:30
FS
004-EFF-0224-3
320-109834-2
Other Liquid
N
02/19/2024
07:30
FS
004-INF-0224-4
320-110019-1
Other Liquid
N
02/26/2024
07:30
FS
004-EFF-0224-4
320-110019-2
Other Liquid
N
02/26/2024
07:30
FS
004-INF-0324
320-110235-1
Other Liquid
N
03/04/2024
09:00
FS
004-EFF-0324
320-110235-2
Other Liquid
N
03/04/2024
09:00
FS
004-INF-0324-2
320-110437-1
Other Liquid
N
03/11/2024
08:30
FS
004-EFF-0324-2
320-110437-2
Other Liquid
N
03/11/2024
08:30
FS
004-FBLK-0324
320-110437-3
Blank Water
N
03/11/2024
08:30
FB
004-INF-0324-3
320-110619-1
Other Liquid
N
03/18/2024
08:00
FS
004-EFF-0324-3
320-110619-2
Other Liquid
N
03/18/2024
08:00
FS
004-INF-0324-4
320-110822-1
Other Liquid
N
03/25/2024
07:30
FS
004-EFF-0324-4
320-110822-2
Other Liquid
N
03/25/2024
07:30
FS
* FS=Field Sample
DUP=Field Duplicate
FB=Field Blank
EB=Equipment Blank
TB=Trip Blank
Analytical Protocol
Lab Name
Lab Method
Parameter Category
Sampling Program
Eurofins Environ
537 Modified
Per- and Polyfluorinated Alkyl
004 NPDES Sampling 2/24
Testing Northern Cali
Substances PFAS
Eurofins Environ
Cl. Spec. Table 3
Per- and Polyfluorinated Alkyl
004 NPDES Sampling 1/24
Testing Northern Cali
Compound SOP
Substances PFAS
Eurofins Environ
Cl. Spec. Table 3
Per- and Polyfluorinated Alkyl
004 NPDES Sampling 2/24
Testing Northern Cali
Compound SOP
Substances PFAS)
Eurofins Environ
Cl. Spec. Table 3
Per- and Polyfluorinated Alkyl
004 NPDES Sampling 3/24
Testing Northern Cali
Compound SOP
Substances PFAS
ADQM Data Review Checklist
DVM
Laboratory
Exception
Item
Description
Yes
No*
Narrative
Report
Report (ER)
Report
#
Did samples meet laboratory acceptability
A
requirements upon receipt (i.e., intact, within
X
temperature, properly preserved, and no
heads ace where applicable)?
B
Were samples received by the laboratory in
X
X
agreement with the associated chain of custody?
C
Was the chain of custody properly completed by
X
the laboratory and/or field team?
D
Were samples prepped/analyzed by the laboratory
X
within method holding times?
Were data review criteria met for method blanks,
LCSs/LCSDs, MSs/MSDs, PDSs, SDs, replicates,
E
surrogates, sample results within calibration range,
X
X
X
total/dissolved samples, field duplicates,
field/equipment/trip blanks?
F
Were all data usable and not R qualified?
X
ER#
Description
Other QA/QC Items to Note:
See DVM Narrative Report, Laboratory Report, and/or ER # for further details as indicated.
The electronic data submitted for this project were reviewed via the Data Verification Module (DVM)
process. Overall, the data are acceptable for use without qualification, except as noted on the attached
DVM Narrative Report.
The lab reports due to a large page count are stored on a network shared drive and are available to be
posted on external shared drives, or on a flash drive.
Data Verification Module (DVM)
The DVM is an internal review process used by the ADQM group to assist with the determination of data
usability. The electronic data deliverables received from the laboratory are loaded into the Locus ElMTM
database and processed through a series of data quality checks, which are a combination of software,
Locus EIMTm database Data Verification Module (DVM), and manual reviewer evaluations. The data are
evaluated against the following data usability checks:
• Field and laboratory blank contamination
• US EPA hold time criteria
• Missing Quality Control (QC) samples
• Matrix spike (MS)/matrix spike duplicate (MSD) recoveries and the relative percent differences
(RPDs) between these spikes
• Laboratory control sample (LCS)/laboratory control sample duplicate (LCSD) recoveries and the
RPD between these spikes
• Surrogate spike recoveries for organic analyses
• Difference/RPD between field duplicate sample pairs
• RPD between laboratory replicates for inorganic analyses
• Difference/percent difference between total and dissolved sample pairs
There are two qualifier fields in EIM:
Laboratory Qualifier is the qualifier assigned by the laboratory and may not reflect the usability of
the data. This qualifier may have many different meanings and can vary between labs and over time
within the same lab. Please refer to the laboratory report for a description of the laboratory qualifiers.
As they are laboratory descriptors they are not to be used when evaluating the data.
Validation Qualifier is the 3rd party formal validation qualifier if this was performed. Otherwise this
field contains the qualifier resulting from the ADQM DVM review process. This qualifier assesses the
usability of the data and may not equal the laboratory qualifier. The DVM applies the following data
evaluation qualifiers to analysis results, as warranted:
Qualifier
Definition
B
Not detected substantially above the level reported in the laboratory or field
blanks.
R
Unusable result. Anal to may or may not be present in the sample.
J
An to resent. Reported value may not be accurate or precise.
UJ
Not detected. Reporting limit may not be accurate or precise.
The Validation Status Code field is set to "DVM" if the ADQM DVM process has been performed. If the
DVM has not been run, the field will be blank.
If the DVM has been run (Validation Status Code equals "DVM"), use the Validation Qualifier.
If the data have been validated by a third party, the field "Validated By" will be set to the validator (e.g.,
ESI for Environmental Standards, Inc.)
DVM Narrative Report
Site: Fayetteville Sampling Program: 004 NPDES Sampling 2/24 Validation Options: LABSTATS
Validation Reason Code: Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values less than the lower control limit but above 10%. The actual detection limits may be higher
than reported.
Date
Validation
Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result Units
Type
MDL PQL
Qualifier
Method Pre -prep
004-EFF-0224-2
02/12/2024 320-109597-2
Perfluorooctadecanoic
0.0020 ug/L
PQL
0.0020
UJ
537 Modified
Acid
004-FBLK-0224
02/12/2024 320-109597-3
Perfluorooctadecanoic
0.0020 ug/L
PQL
0.0020
UJ
537 Modified
Acid
004-INF-0224-2
02/12/2024 320-109597-1
Perfluorooctadecanoic
0.0020 ug/L
PQL
0.0020
UJ
537 Modified
Acid
Prep
3535
3535
3535
Page 1 of 3
Site: Fayetteville Sampling Program: 004 NPDES Sampling 1/24 Validation Options: LABSTATS
Validation Reason Code: Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit. The actual detection limits may be higher than reported.
Date
Validation
Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result
Units
Type
MDL PQL
Qualifier
Method
004-EFF-0124-2
01/02/2024 320-108480-2
Hydrolyzed PSDA
0.0020
UG/L
PQL
0.0020
UJ
Cl. Spec. Table 3
Compound SOP
004-EFF-0124-2
01/02/2024 320-108480-2
PFMOAA
0.0020
ug/L
PQL
0.0020
UJ
Cl. Spec. Table 3
Compound SOP
004-EFF-0124-2
01/02/2024 320-108480-2
Hydro -PS Acid
0.0020
ug/L
PQL
0.0020
UJ
Cl. Spec. Table 3
Compound SOP
004-EFF-0124-2A
01/08/2024 320-108578-2
PFMOAA
0.0020
ug/L
PQL
0.0020
UJ
Cl. Spec. Table 3
Compound SOP
004-EFF-0224-3
02/19/2024 320-109834-2
PFMOAA
0.0020
ug/L
PQL
0.0020
UJ
Cl. Spec. Table 3
Compound SOP
004-EFF-0224-4
02/26/2024 320-110019-2
PMPA
0.010
UG/L
PQL
0.010
UJ
Cl. Spec. Table 3
Compound SOP
004-EFF-0224-4
02/26/2024 320-110019-2
PFMOAA
0.0020
ug/L
PQL
0.0020
UJ
Cl. Spec. Table 3
Compound SOP
Pre -prep
Prep
PFAS_DI_Prep
PFAS_DI_Prep
PFAS_DI_Prep
PFAS_DI_Prep
PFAS_DI_Prep
PFAS_DI_Prep
PFAS_DI_Prep
Page 2 of 3
Site: Fayetteville Sampling Program: 004 NPDES Sampling 2/24 Validation Options: LABSTATS
Validation Reason Code: Uncertainty around the analysis of R-PSDA, Hydrolyzed PSDA and R-EVE; J-qualifier added to all detects in the data set, even if there was no matrix spike analyzed for that
particular sample.
Date
Validation
Analytical
Field Sample ID
Sampled Lab Sample ID
Analyte
Result
Units
Type MDL
PQL
Qualifier
Method Pre -prep
Prep
004-INF-0224-2
02/12/2024 320-109597-1
R-PSDA
1.8
UG/L
PQL
0.035
J
Cl. Spec. Table 3
PFAS_DI_Prep
Compound SOP
004-INF-0224-2
02/12/2024 320-109597-1
Hydrolyzed PSDA
16
UG/L
PQL
0.019
J
Cl. Spec. Table 3
PFAS_DI_Prep
Compound SOP
004-INF-0224-2
02/12/2024 320-109597-1
R-EVE
0.93
UG/L
PQL
0.036
J
Cl. Spec. Table 3
PFAS_DI_Prep
Compound SOP
004-INF-0324-2
03/11/2024 320-110437-1
R-PSDA
1.3
UG/L
PQL
0.035
J
Cl. Spec. Table 3
PFAS_DI_Prep
Compound SOP
004-INF-0324-2
03/11/2024 320-110437-1
Hydrolyzed PSDA
12
UG/L
PQL
0.025
J
Cl. Spec. Table 3
PFAS_DI_Prep
Compound SOP
004-INF-0324-2
03/11/2024 320-110437-1
R-EVE
0.50
UG/L
PQL
0.036
J
Cl. Spec. Table 3
PFAS_DI_Prep
Compound SOP
004-INF-0124-2
01/02/2024 320-108480-1
R-PSDA
0.94
UG/L
PQL
0.071
J
Cl. Spec. Table 3
PFAS_DI_Prep
Compound SOP
004-INF-0124-2
01/02/2024 320-108480-1
Hydrolyzed PSDA
6.8
UG/L
PQL
0.038
J
Cl. Spec. Table 3
PFAS_DI_Prep
Compound SOP
004-INF-0124-2
01/02/2024 320-108480-1
R-EVE
0.53
UG/L
PQL
0.072
J
Cl. Spec. Table 3
PFAS_DI_Prep
Compound SOP
Page 3 of 3
Geosyntec
consultants
Geosyntec Consultants of NC, P.C.
NC License No.: C-3500 and C-295
Appendix B
FTC Transducer Data Reduction
TR0795C
46
45
44
43
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> 42
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41
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40
39
38
37
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i
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IZT
It
It
't
't
IZT
�T
It
�t
t
It
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
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0)
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N
N
\
\
\
\
\
\
\
N
N
\
\
\
\
\
M
M
c-I
N
N
N
N
N
Legend
Discharge Basin Elevation
Weir 3 Elevation
GAC Elevation
Notes:
GAC - granular activated carbon
Figure B1-A shows the discharge basin transducer data that was collected during the reporting period.
N
N
N
N
N
N
a)
M
r-
c\I
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0)
M
M
M
M
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45
43
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00
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0 35
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w 33
31
29
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
r\-I
L 1
al
M
r\-I
II
a)
N
ED
O
qt
0000
N
l\D
.\I
11
M
M
r\
r\I
I1
0\1
\
\
\
I
I
N
N
N
\
\
r-I
I
r-I
N
N
\
\
\
r -I
-1
N
N
N
\
\
\
\
\
N
N
\
\
\
\
\
M
M
M
\
\
\
\
\
r-I
r-I
ri
r-I
r-I
N
N
N
N
f V
M
M
M
M
M
Legend
Discharge Basin Water Elevation
River Stage
Weir 3 Elevation
0 USGS Precipitation (daily totals)
Notes:
As water can flow through the flow -through cell both as a result of wet weather inflow and elevated river levels from flooding, Figure 132-A compares the available transducer data to precipitation and river stage
elevation data available from the USGS Huske Lock and Dam.
46
45
0000 43
0
Q
z
42
c
0
v
LU 41
40
39
38
�t
�t
-t
-t
N
N
N
N
N
N
fV
N
N
N
N
N
N
N
N
N
N
N
N
N
c-I
Ln
Ql
M
r,
-I
L n
M
N
l\O
O
00
N
l\O
.\-I
Lf
a)
M
I�
\
r-I
r-I
-I
N
N
\
\
N
N
\
\
\
\
\
M
M
M
\
\
ri
ri
ri
-I
-I
N
N
N
N
N
M
M
Legend
— Influent Chamber/Impoundment Elevation
Notes:
Figure 133-A shows the influent transducer data that was collected during the reporting period.
N
fV
N
-i
LI
01
\
\
\
M
M
M
45
43
41
00
0
> 39
Q
Z
37
c
0
35
a�
w
33
31
29
......... .. .............
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
r\-I
if
a)
M
n
r\-I
Lf
Ol
N
koo
O
00
N
l\o
c\-I
U
Ql
M
n
r\-I
L\n
Ql
N
N
N
\
\
r-I
-I
c-I
N
N
\
\
\
c-I
r-I
N
N
N
\
\
\
\
\
N
N
\
\
\
\
\
M
M
M
\
\
\
\
\
ri
ri
rl
.--I
r-I
N
N
N
N
N
M
M
M
M
M
2
C
1.5
c
0
m 1
.Q
.0
v 0.5
a
n
Legend
— Inlet Chamber Water Elevation USGS Precipitation (daily totals)
— River Stage
••• Bypass Spillway Elevation
Notes:
As water can flow through the Bypass Spillway both as a result of wet weather inflow and elevated river levels from flooding, Figure 134-A compares the available transducer data to precipitation and river stage
elevation data available from the USGS Huske Lock and Dam.
46
45
44
43
00
0
42
z
c
0
> 41
v
w
40
39
38
N N N N
[V N N N N N N N cV N N (Iq N N [V N N N N
c\I Ln 01 M
r- \-I Ln C) N lDD O 0000 N l\D r\-I Ln Ol M r- \-I in m
\
N \ \ I I r-I N N \ \ \ r-I c-I N N N
\ \ \ \ N N \ \ \ \ \ M M M \ \ \ \ \
c-I
rl r-I c-I c-I
N N N N N M M M M M
Legend
Discharge Basin Elevation
Weir 3 Elevation
GAC Elevation
Discharge Basin Water Elevation -
Notes:
Seep B
GAC - granular activated carbon
Chemours Fayetteville Works
Figure BI-B shows the discharge basin transducer data
that was collected during the reporting period.
Fayetteville, North Carolina
Geosyntecc Geosyntec ConsultantsoFNC, P.C.
Figure
consultants NC License No.: C3500 and C-295
B1-B
Raleigh, NC June 2024
i
i
t
i
i
1
i
I I
i
�1
40
44
42
40
00
38
Q
Z
36
34
c0
v
w 32
30
28
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
r\-I
L 1
al
M
r\i
II
a)
N
ED
O
qt
0000
N
l\D
.\I
11
M
M
r\
r\I
I1
M
\
\
\
I
I
N
N
N
\
\
r-I
I
r-I
N
N
\
\
\
r -I
-1
N
N
N
\
\
\
\
\
N
N
\
\
\
\
\
M
M
M
\
\
\
\
\
r-I
r-I
ri
r-I
r-I
N
N
N
N
f V
M
M
M
M
M
2
C
_— 1.5
C
0
� 1
Q
U
2- 0.5
a
0
Legend
Discharge Basin Water Elevation USGS Precipitation (daily totals)
River Stage
Weir 3 Elevation
n
Notes:
As water can flow through the flow -through cell both as a result of wet weather inflow and elevated river levels from flooding, Figure 132-13 compares the available transducer data to precipitation and river stage
elevation data available from the USGS Huske Lock and Dam.
46
45
IM11111111111
43
00
Q
42
0
41
+j
a�
w
.M
39
38
'
N
N
N
N
fV
N
(V
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
.\I
L n
00)
M
r"\-I
LO
01
N
(,\D
O
0000
N
�.o
c\-1
Ln
00)
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r-
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N
N
N
\
\
c I
I
r-I
N
N
\
\
\
c-I
c-
N
N
N
rl
r 1
rl
N
[V
N
cV
N
M
M
M
M
M
Legend
— Influent Chamber/Impoundment Elevation
Notes:
Figure 133-13 shows the influent transducer data that was collected during the reporting period.
45
43
41
00
39
Q
Z
37
0
4� 35
c6
aU
LU 33
31
29
.............. ..�...........I.......III ..................................................................................................................................
I I
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
rq
N
N
N
N
N
N
N
rl
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61
c 7
N\-I
L1
a)
N
l\O
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qt
00
N
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.\-I
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.\-I
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N
N
N
\
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�1
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N
N
\
\
\
I
r-I
N
N
N
\
\
\
\
\
N
N
\
\
\
\
\
M
M
M
\
\
\
\
\
N
N
N
N
N
M
M
M
M
M
Legend
— Inlet Chamber Water Elevation 0 USGS Precipitation (daily totals)
— River Stage
••• Bypass Spillway Elevation
Notes:
As water can flow through the Bypass Spillway both as a result of wet weather inflow and elevated river levels from flooding, Figure B4-B compares the available transducer data to precipitation and river stage
elevation data available from the USGS Huske Lock and Dam.
46
45
44
43
00 42
0
Q
z
41
0
"' 40
39
38
37
N N N N [V N N N N N N N cV N N (Iq N N [V N N N N
c\I Ln 01 M r" \-I Ln C) N l\D O 0000 N l\O r\-I Ln Ol M r- \-I in m
N \ \ -I -I r-I N N \ \ \ r-I c-I N N N
\ \ \ \ \ N N \ \ \ \ \ M M M \ \ \ \ \
c-I rl r-I c-I c-I
N N N N N M M M M M
Legend
Discharge Basin Elevation
Weir 3 Elevation
GAC Elevation
Discharge Basin Water Elevation -
Notes:
Seep C
GAC - granular activated carbon
Chemours Fayetteville Works
Figure B1-C shows the discharge basin transducer data that was collected during the reporting period.
Fayetteville, North Carolina
Geosyntecc Geosyntec ConsultantsoFNC, P.C. Figure
consultants NC License No.: C3500 and C-295
B1-C
Raleigh, NC June 2024
t
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45
43
41
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Legend
Discharge Basin Water Elevation
River Stage
Weir 3 Elevation
USGS Precipitation (daily totals)
Notes:
As water can flow through the flow -through cell both as a result of wet weather inflow and elevated river levels from flooding, Figure 132-C compares the available transducer data to precipitation and river stage
elevation data available from the USGS Huske Lock and Dam.
46
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Legend
Influent Chamber/Impoundment Elevation
GAC Changeout
Inlet Chamber Water Elevation -
Notes:
Seep C
Figure 133-C shows the influent transducer data that was collected during the reporting period. Chemours Fayetteville works
Fayetteville, North Carolina
Geosyntec" Figure
consultants NC U—, N— C 3500 and C 295
B3-C
Raleigh, NC June 2024
45
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Legend
— Inlet Chamber Water Elevation 0 USGS Precipitation (daily totals)
— River Stage
••• Bypass Spillway Elevation
Notes:
As water can flow through the Bypass Spillway both as a result of wet weather inflow and elevated river levels from flooding, Figure B4-C compares the available transducer data to precipitation and river stage
elevation data available from the USGS Huske Lock and Dam.
46
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Legend
Discharge Basin Elevation
Weir 3 Elevation
GAC Elevation
Discharge Basin Water Elevation -
Notes:
Seep D
GAC - granular activated carbon Chemours Fayetteville Works
Figure BI-D shows the discharge basin transducer data that was collected during the reporting period. Fayetteville, North Carolina
Geosyntecc Geosyntec ConsultantsoFNC, P.C. Figure
consultants NC License No.: C3500 and C-295
B1-D
Raleigh, NC June 2024
t
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Legend
Discharge Basin Water Elevation
River Stage
Weir 3 Elevation
USGS Precipitation (daily totals)
Notes:
As water can flow through the flow -through cell both as a result of wet weather inflow and elevated river levels from flooding, Figure 132-D compares the available transducer data to precipitation and river stage
elevation data available from the USGS Huske Lock and Dam.
46
45
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43
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Legend
Influent Chamber/Impoundment Elevation
Inlet Chamber Water Elevation -
Notes:
Seep D
Figure 133-1) shows the influent transducer data that was collected during the reporting period. Chemours Fayetteville works
Fayetteville, North Carolina
Geosyntec" Figure
NC U—, N— C 3500 C 295
and
consultants
B3-D
Raleigh, NC June 2024
i
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45
43
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N
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Legend
— Inlet Chamber Water Elevation USGS Precipitation (daily totals)
— River Stage
••• Bypass Spillway Elevation
Notes:
As water can flow through the Bypass Spillway both as a result of wet weather inflow and elevated river levels from flooding, Figure B4-D compares the available transducer data to precipitation and river stage
elevation data available from the USGS Huske Lock and Dam.
Geosyntec
consultants
Geosyntec Consultants of NC, P.C.
NC License No.: C-3500 and C-295
Appendix C
Corrected PFPrA Concentration for
Previously Reported Results
TR0795C
Appendix C
Corrected PFPrA Concentrations for Previously Reported Results
July 2023 to November 2023
Chemours Fayetteville Works
Fayetteville, North Carolina
Sampling Program
Location ID
Sample ID
Sample Date
PFPrA Concentration (ng/L)
Corrected
Original
CAP MW Sampling 3Q23
LTW-01
CAP3Q23-LTW-01-071323
7/13/2023
22,000
14,000
CAP GW Sampling 4Q23
LTW-01
CAP4Q23-LTW-0 1- 110323
11/3/2023
24,000
14,000
CAP MW Sampling 3Q23
LTW-02
CAP3Q23-LTW-02-071223
7/12/2023
16,000
11,000
CAP GW Sampling 4Q23
LTW-02
CAP4Q23-LTW-02-110323
11/3/2023
21,000
13,000
CAP MW Sampling 3Q23
LTW-03
CAP3Q23-LTW-03-071223
7/12/2023
62,000 J
37,000
CAP MW Sampling 4Q23
LTW-03
CAP4Q23-LTW-03-111323
11/13/2023
61,000 J
38,000 J
CAP MW Sampling 3Q23
LTW-04
CAP3Q23-LTW-04-071123
7/11/2023
53,000
29,000
CAP GW Sampling 4Q23
LTW-04
CAP4Q23-LTW-04-110223
11/2/2023
48,000
30,000
CAP MW Sampling 3Q23
LTW-05
CAP3Q23-LTW-05-071123
7/11/2023
83,000 J
52,000 J
CAP GW Sampling 4Q23
LTW-05
CAP4Q23-LTW-05-110223
11/2/2023
120,000
68,000
CAP MW Sampling 3Q23
OW-28
CAP3Q23-OW-28-071123
7/11/2023
5,200
3,500
CAP GW Sampling 4Q23
OW-28
CAP4Q23-OW-28-110223
11/2/2023
5,500
3,500
CAP MW Sampling 3Q23
OW-33
CAP3Q23-OW-33-071223
7/12/2023
9,900
5,400
CAP GW Sampling 4Q23
OW-33
CAP4Q23-OW-33-110223
11/2/2023
9,400
6,000
CAP MW Sampling 3Q23
PIW-11)
CAP3Q23-PIW-1D-080223
8/2/2023
12,000 J
7,800
CAP GW Sampling 4Q23
PIW-11)
CAP4Q23-PIW-ID-110723
11/7/2023
12,000
7,500
CAP MW Sampling 3Q23
PIW-31)
CAP3Q23-PIW-3D-071323
7/13/2023
19,000
11,000
CAP GW Sampling 4Q23
PIW-31)
CAP4Q23-PIW-3D-110323
11/3/2023
21,000
13,000
CAP MW Sampling 3Q23
PIW-71)
CAP3Q23-PIW-7D-071123
7/11/2023
79,000 J
49,000 J
CAP GW Sampling 4Q23
PIW-71)
CAP4Q23-PIW-7D-110223
11/2/2023
86,000
52,000
CAP MW Sampling 3Q23
PIW-7S
CAP3Q23-PIW-7S-071123
7/11/2023
14,000
9,700
CAP GW Sampling 4Q23
PIW-7S
CAP4Q23-PIW-7S-110223
11/2/2023
18,000
12,000
CAP MW Sampling 3Q23
PW-04
CAP3Q23-PW-04-072823
7/28/2023
1,400
900
CAP MW Sampling 4Q23
PW-04
CAP4Q23-PW-04-110923
11/9/2023
1,500
960
CAP MW Sampling 3Q23
PZ-22
CAP3Q-PZ-22-071123
7/11/2023
76,000
48,000
CAP GW Sampling 4Q23
PZ-22
CAP4Q23-PZ-22-110223
11/2/2023
84,000
51,000
CAP MW Sampling 3Q23
SMW-12
CAP3Q23-SMW-12-071823
7/18/2023
5,900
3,900
CAP MW Sampling 4Q23
SMW-12
CAP4Q23-SMW-12-110823
11/8/2023
7,000
4,600
CAP MW Sampling 3Q23
OW-4R
CAP3Q23-OW-4R-080423
8/4/2023
25,000
17,000
CAP MW Sampling 3Q23
OW-30
CAP3Q23-OW-30-071323
7/13/2023
19,000
12,000
CAP MW Sampling 3Q23
OW-32
CAP3Q23-OW-32-090823
9/8/2023
990
640
CAP MW Sampling 3Q23
OW-37
CAP3Q23-OW-37-081023
8/10/2023
8,200 J
5,200 J
CAP MW Sampling 3Q23
OW-40
CAP3Q23-OW-40-071323
7/13/2023
5,700
3,700
CAP MW Sampling 3Q23
OW-51
CAP3Q23-OW-51-080323
8/3/2023
92,000
60,000
CAP GW Sampling 3Q23
OW-55
CAP3Q23-OW-55-072523
7/25/2023
2,900
11800
CAP MW Sampling 3Q23
OW-56
CAP3Q23-OW-56-073123
7/31/2023
2,200
1,400
CAP MW Sampling 3Q23
OW-57
CAP3Q23-OW-57-073123
7/31/2023
44,000
28,000
CAP MW Sampling 3Q23
PIW-41)
CAP3Q23-PIW-4D-071323
7/13/2023
880
550
CAP MW Sampling 3Q23
PIW-5SR
CAP3Q23-PIW-5SR-080423
8/4/2023
44,000
29,000
CAP MW Sampling 3Q23
PIW-6S
CAP3Q23-PIW-6S-071223
7/12/2023
64,000 J
50,000 J
TR0795C Page 1 of 2 June 2024
Appendix C
Corrected PFPrA Concentrations for Previously Reported Results
July 2023 to November 2023
Chemours Fayetteville Works
Fayetteville, North Carolina
Sampling Program
Location ID
Sample ID
Sample Date
PFPrA Concentration (ng/L)
Corrected
Original
CAP MW Sampling 3Q23
PIW-81)
CAP3Q23-PIW-8D-07l l23
7/11/2023
57,000
34,000
CAP MW Sampling 3Q23
PIW-IODR
CAP3Q23-PIW-IODR-071423
7/14/2023
26,000
17,000
CAP MW Sampling 3Q23
PIW-lOS
CAP3Q23-PIW-lOS-071323
7/13/2023
5,300
3,100
CAP MW Sampling 3Q23
PIW-I I
CAP3Q23-PIW-11-073123
7/31/2023
3,400
2,000
CAP GW Sampling 3Q23
PIW-15
CAP3Q23-PIW-15-072523
7/25/2023
14,000
9,000
CAP MW Sampling 3Q23
PW-IORR
CAP3Q23-PW-IORR-080323
8/3/2023
60,000
39,000
CAP MW Sampling 3Q23
PW-11
CAP3Q23-PW-11-070723
7/7/2023
25,000
17,000
CAP GW Sampling 3Q23
PIW-12
CAP3Q23-PIW-12-072423
7/24/2023
2,800
1,700
CAP GW Sampling 3Q23
PIW-13
CAP3Q23-PIW-13-072423
7/24/2023
4,600
2,800
CAP GW Sampling 3Q23
PIW-14
CAP3Q23-PIW-14-072423
7/24/2023
6,700
4,300
CAP SW Sampling 3Q23
WC-1
CAP3Q23-WC-1-24-072723
7/27/2023
770
500
CAP SW Sampling 4Q23
WC-1
CAP4Q23-WC-1-112323
11/23/2023
250
170
CAP SW Sampling 3Q23
WC-2
CAP3Q23-WC-2-24-072723
7/27/2023
570
360
CAP SW Sampling 4Q23
WC-2
CAP4Q23-WC-2-112323
11/23/2023
340 J
220 J
CAP SW Sampling 3Q23
WC-3
CAP3Q23-WC-3-24-072723
7/27/2023
280
180
CAP SW Sampling 4Q23
WC-3
CAP4Q23-WC-3-112323
11/23/2023
150
96
Notes:
1 - PFPrA concentrations were revised following the discovery of a calculation error by the analytical laboratory.
J - Analyte detected. Reported value may not be accurate or precise.
ng/L - nanograms per liter
PFPrA - perfluoropropanoic acid
TR0795C Page 2 of 2 June 2024
Geosyntec
consultants
Geosyntec Consultants of NC, P.C.
NC License No.: C-3500 and C-295
Appendix D
Updated PFPrA Calculation Discussion and
Table of Previously Reported Results Along
with Revised, Corrected Results, Chemours
Fayetteville Works, Fayetteville, NC
TR0795C
9 Chemours-
June 18, 2024
The Chemours Company
Fayetteville Works
22828 NC Highway 87 W
Fayetteville, NC 28306
Updated PFPrA Calculation Discussion and Table of Previously Reported Results Along
with Revised, Corrected Results, Chemours Fayetteville Works, Fayetteville, NC
Perfluoropropanoic acid (PFPrA) is a Table 3+ compound that was added to the Fayetteville Works
commercial analytical suite in June 2023. It is considered an "early eluter" because it is a small
compound (with a three -carbon backbone) that is not retained well on chromatographic columns
and is subject to interferences from the sample matrix, which makes it difficult to analyze.
Analytical improvements such as better sample cleanup using solid -phase extraction cartridges
have made it possible for PFPrA to be analyzed by commercial analytical laboratories Method
537Mod Max.
Certified PFPrA standards did not become available until July 2023. Prior to July 2023,
commercial analytical laboratories were creating their own PFPrA standards from neat liquid
PFPrA. It should be noted that when commercially prepared dilutions of PFPrA were first offered
as certified solutions in July 2023, it was unclear if the solutions were correctly preserved to
prevent esterification (short -chain fluorinated acids were believed to be prone to conversion to the
methyl ester when prepared as methanolic solutions). One of Chemours' commercial analytical
laboratories, Eurofins-Sacramento, conducted an internal comparative investigation in Q1 2024 to
assess the validity of commercial standards. PFPrA standards were purchased from 3 vendors and
compared to a standard correctly prepared at Eurofins- Sacramento. The comparative investigation
indicated that the commercial standards were acceptable, and their use has now been implemented.
On April 23, 2024, Eurofins-Sacramento, informed Chemours via email that a calculation error
had been incorporated into the preparation of calibration standards for PFPrA under the
laboratory's 537 Mod Max methodology. This error occurred when PFPrA standard solutions
prepared at Eurofins-Sacramento did not correctly incorporate the density of neat liquid PFPrA
when adding a known volume of neat liquid PFPrA to water, resulting in the incorrect calculation
of the concentration of the standards. The density of PFPrA was assumed to be 1.0 grams per
milliliter (g/ml), but the true density of liquid PFPrA is 1.56 g/ml. The neat liquid PFPrA was
purchased from Sigma -Aldrich and was 97% pure (see Attachment 1 for Certificate of Analysis).
This level of purity is acceptable under Eurofins-Sacramento's Standard Operating Procedure, and
is slightly purer than the purity of 96% allowed when making standards under EPA Method 537,
from which Eurofins-Sacramento derives its Method 537 Mod Max.
For example, a standard solution created by adding 1.0 milliliters of PFPrA liquid to 1.0 liters of
water was incorrectly determined to have a PFPrA concentration of 1.0 grams per liter (1.0 g/L),
and the correct PFPrA concentration was 1.56 g/L.
The error resulted in a 36% low bias (36% = 100*[1.56 — 1.0]/1.56) in PFPrA concentrations
reported for approximately 550 Chemours samples collected at and in the vicinity of the
Fayetteville Works Site and reported between June 2023 and April 2024. Eurofins-Sacramento is
now using the newly available commercially available certified standards to prepare calibration
curves for PFPrA. Consequently, this error will not be repeated in the future. Chemours informed
the North Carolina Department of Environmental Quality (NCDEQ) of the PFPrA calculation error
via telephone on May 15, 2024, and provided NCDEQ with Eurofins-Sacramento's memo
describing their root cause analysis of the PFPrA calculation error on May 22, 2024 (Attachment
2). PFPrA results that were incorrectly calculated have been corrected by Eurofins-Sacramento
and revised PFPrA results have been provided to Chemours (Table 1).
Due to the requirement for fully defensible Level 4 data for PFPrA, the existing PFPrA results
were not simply multiplied by 1.56 to correct for the low bias, but rather the laboratory generated
the revised PFPrA data through their laboratory information management system (LIMS). Once
reported, the original quantitative data becomes a permanent record in the LIMS, which
necessitates regenerating the quantitative data in order to incorporate a fundamental change in the
calculation basis, such as updated concentrations of calibration standards, and reporting of revised
results. Re -generation of quantitative data includes re -integration of all analyte responses as well
as generation of new calibration response factors and associated calculations of analyte
concentrations. Note that this is a necessary process for many commercial analytical laboratories
when regeneration of results from raw data is required.
Re -integrating chromatographic peaks in both standards and samples may yield different
integrated areas than were originally generated. The different integrated areas in turn yield
different concentrations than expected. A change in concentration due to re -integration can occur
with either automated or manual re -integration but is more likely to occur with manual re-
integration because manual integrations are more subjective than automated integrations. In the
current case, the revised PFPrA concentrations were expected to increase by a factor of 1.56, but
this was not always observed (Table 1). When the PFPrA (or the associated isotope dilution analyte
(IDA)) concentration is low or is impacted by chromatographic interferences, small changes in
integrations may have a significant effect on the results, as described below:
• Samples that contain very small amounts of PFPrA (i.e., the signal-to-noise ratio is large)
- small changes in integration of the PFPrA results in changes to the revised PFPrA
concentration that vary from the factor of 1.56;
• Samples with low IDA response due to extract dilutions necessitated by high target analyte
concentrations - small changes in integration of the IDA results in changes to the revised
PFPrA concentration that vary from the factor of 1.56. Chemours maintains an inventory
of dilutions required for specific sampling locations, so when these locations are sampled
in the future the expected concentrations can be addressed without adverse impacts on the
IDA response; and
• Samples with significant effects from the matrix - the presence of chromatographic
interferences means that the signal-to-noise ratio is large, whether or not the PFPrA or IDA
2
concentrations are small (although matrix effects tend to be more significant at lower
PFPrA or IDA concentrations), which makes integration of the PFPrA and/or the IDA more
variable.
Consequently, each revised PFPrA concentration may not show an increase of exactly 1.56 over
the original concentration (in a few cases, the revised PFPrA concentration is actually lower than
the initial PFPrA concentration). However, the revised PFPrA concentrations increased by an
average factor of 1.57 over the original concentrations, which is close to the expected increase of
1.56. The range in the factor was 0.81 to 2.56, with a standard deviation of 0.14. Ninety-two
percent of the factors fall within one standard deviation of the average (i.e., 92 % of the factors are
between 1.43 and 1.71).
For upcoming Q1 2024 reports due on June 30, 2024, the PFPrA results will be corrected before
they are submitted to NCDEQ. These reports will also include an appendix that provides corrected
PFPrA results for samples collected between June 2023 to December 2023 that were previously
submitted to NCDEQ. Revised lab reports for these 2023 samples will be uploaded to the shared
OneDrive folder at the same time as the lab reports associated with the Q 12024 reports.
Chemours is committed to producing good quality analytical data and will continue to work with
its commercial analytical laboratories to monitor analytical data quality, implement improvements
to analytical methods and communicate with NCDEQ regarding analytical issues.
Enclosures
Table 1 - Revised and Original PFPrA Concentrations
Attachment 1 — Sigma Aldrich Certificate of Analysis for Pentafluoropropionic Acid
Attachment 2 - RE: Investigation and Corrective Action for PFPrA Error
TABLE 1
REVISED AND ORIGINAL PFPRA CONCENTRATIONS
Chemours Fayetteville Works, North Carolina
Sampling Program
Sample ID
Sample Date
Sample Delivery
Group
Laboratory
Sample ID
PFPrA Concentration (ng/L)
Factor
(revised
concentration /
original
concentration)
Revised
Concentration*
Original
Concentration
2023 Perched Zone Sampling
FAY-D-EB-092023
20-Sep-23
320-105128-1
320-105128-1
<5
<5
2023 Perched Zone Sampling
FAY-D-EB-122023
20-Dec-23
320-108308-1
320-108308-1
<5
<5
2023 Perched Zone Sampling
FAY-D-MW-24-092023
20-Sep-23
320-105128-1
320-105128-5
300,000
200,000
1.50
2023 Perched Zone Sampling
FAY-D-MW-24-122023
20-Dec-23
320-108308-1
320-108308-5
150,000 J
170,000 J
0.88
2023 Perched Zone Sampling
FAY-D-NAF-03-092023
20-Sep-23
320-105128-1
320-105128-4
360,000
220,000
1.64
2023 Perched Zone Sampling
FAY-D-NAF-03-122023
20-Dec-23
320-108308-1
320-108308-3
320,000J
370,000J
0.86
2023 Perched Zone Sampling
FAY-D-NAF-03-122023-D
20-Dec-23
320-108308-1
320-108308-4
250,000J
220,000J
1.14
2023 Perched Zone Sampling
FAY-D-NAF-12-092023
20-Sep-23
320-105128-1
320-105128-2
150,000
93,000
1.61
2023 Perched Zone Sampling
FAY-D-NAF-12-092023-D
20-Sep-23
320-105128-1
320-105128-3
190,000
120,000
1.58
2023 Perched Zone Sampling
FAY-D-NAF-12-122023
20-Dec-23
320-108308-1
320-108308-2
350,000J
430,000J
0.81
CAP GW Sampling 3 23
CAPS 23-BCA-04-072023
20-Jul-23
320-102901-1
320-102901-5
79
51
1.55
CAP GW Sampling 3 23
CAPS 23-MW-17D-072023
20-Jul-23
320-102901-1
320-102901-6
1,400
900
1.56
CAP GW Sampling 3 23
CAPS 23-NAF-01-072123
21-Jul-23
320-102898-1
320-102898-1
350,000
220,000
1.59
CAP GW Sampling 3 23
CAPS 23-NAF-02-072023
20-Jul-23
320-102901-1
320-102901-9
1,100,000
660,000
1.67
CAP GW Sampling 3 23
CAPS 23-NAF-03-072023
20-Jul-23
320-102901-1
320-102901-10
58,000 J
37,000 J
1.57
CAP GW Sampling 3 23
CAPS 23-NAF-09-072023
20-Jul-23
320-102901-1
320-102901-1
67,000
42,000
1.60
CAP GW Sampling 3 23
CAPS 23-NAF-10-072023
20-Jul-23
320-102901-1
1 320-102901-2
4,900
3,100
1.58
CAP GW Sampling 3 23
CAPS 23-OW-55-072523
25-Jul-23
320-102898-1
320-102898-7
2,900
1,800
1.61
CAP GW Sampling 3 23
CAPS 23-PIW-12-072423
24-Jul-23
320-102898-1
320-102898-5
2,800
1,700
1.65
CAP GW Sampling 3 23
CAPS 23-PIW-13-072423
24-Jul-23
320-102898-1
320-102898-6
4,600
2,800
1.64
CAP GW Sampling 3 23
CAPS 23-PIW-14-072423
24-Jul-23
320-102898-1
320-102898-4
6,700
4,300
1.56
CAP GW Sampfing 3 23
CAP3 23-PIW-15-072523
25-Jul-23
320-102898-1
320-102898-8
14,000
9,000
1.56
CAP GW Sampling 3 23
CAPS 23-PIW-2D-072023
20-Jul-23
320-102901-1
320-102901-7
18,000
12,000
1.50
CAP GW Sampling 3023
CAPS 23-PW-05-072023
20-Jul-23
320-102901-1
320-102901-4
1,100
790
1.39
CAP GW Sampling 3 23
CAPS 23-PZ-13-072023
20-Jul-23
320-102901-1
320-102901-3
51,000
33,000
1.55
CAP GW Sampling 3 23
CAPS 23-PZ-14-072123
21-Jul-23
320-102898-1
320-102898-2
13,000
7,900
1.65
CAP GW Sarnpling 3 23
CAPS 23-SMW-04B-072023
20-Jul-23
320-102901-1
320-102901-8
3,800
2,400
1.58
CAP GW Sarnpling 3 23
CAPS 23-SMW-05PR-072123
21-Jul-23
320-102898-1
320-102898-3
23,000
15,000
1.53
CAP GW Saxnpling 4 23
CAP4 23-BLADEN-IDR-010424
04-Jan-24
320-108551-1
320-108551-1
200
130
1.54
CAP GW Sampling 4 23
CAP4 23-E BLK-DV-110823
08-Nov-23
320-106887-1
320-106887-6
<5
<5
CAP GW Sampling 4023
CAP4 23-E BLK-DV-110823-Z
08-Nov-23
320-106887-1
320-106887-5
<5
<5
CAP GW Sampling 4 23
CAP4 23-E BLK-PP-010424
04-Jan-24
320-108551-1
320-108551-2
<5
<5
CAP GW Sampling 4 23
CAP4 23-E BLK-PP-110823
08-Nov-23
320-106887-1
320-106887-9
<5
<5
CAP GW Sampling 4 23
CAP4 23-E BLK-PP-110823-Z
08-Nov-23
320-106887-1
320-106887-8
<5
<5
CAP GW Sampling 4 23
CAP4 23-LTW-01-110323
03-Nov-23
320-106773-1
320-106773-1
24,000
14,000
1.71
CAP GW Sampling 4 23
CAP4 23-LTW-02-110323
03-Nov-23
320-106772-1
320-106772-7
21,000
13,000
1.62
CAP GW Sampling 4 23
CAP4 23-LTW-04-110223
02-Nov-23
320-106772-1
320-106772-5
48,000
30,000
1.60
CAP GW Sampling 4023
CAP4 23-LTW-05-110223
02-Nov-23
320-106772-1
320-106772-1
120,000
68,000
1.76
CAP GW Sampling 4 23
CAP4 23-OW-28-110223
02-Nov-23
320-106772-1
320-106772-6
5,500
3,500
1.57
CAP GW Sampling 4 23
CAP4 23-OW-33-110223
02-Nov-23
320-106773-1
320-106773-3
9,400
6,000
1.57
CAP GW Sampling 4 23
CAP4 23-OW-33-110223-D
02-Nov-23
320-106773-1
320-106773-4
9,000
5,900
1.53
CAP GW Sampling 4 23
CAP4 23-PIW-1D-110723
07-Nov-23
320-106887-1
320-106887-1
12,000
7,500
1.60
CAP GW Sampling 4 23
CAP4 23-PIW-1D-110723-Z
07-Nov-23
320-106887-1
320-106887-2
12,000
7,700
1.56
CAP GW Sampling 4 23
CAP4 23-PIW-3D-110323
03-Nov-23
320-106773-1
320-106773-2
21,000
13,000
1.62
CAP GW SamDling 4023
CAP4 23-PIW-7D-110223
02-Nov-23
320-106772-1
320-106772-3
86,000
52,000
1.65
CAP GW Sampling 4 23
CAP4 23-PIW-7S-110223
02-Nov-23
320-106772-1
320-106772-2
18,000
12,000
1.50
CAP GW Sampling 4 23
CAP4 23-PW-06-110623
06-Nov-23
320-106773-1
320-106773-5
840
520
1.62
CAP GW Sampling 4 23
CAP4 23-PW-09-110823
08-Nov-23
320-106887-1
320-106887-4
<5 UJ
<5 UJ
CAP GW Sampling 4 23
CAP4 23-PW-09-110823-Z
08-Nov-23
320-106887-1
320-106887-7
<5 UJ
<5 UJ
CAP GW Sampling 4 23
CAP4 23-PZ-22-110223
02-Nov-23
320-106772-1
320-106772-4
84,000
51,000
1.65
CAP GW Sampling 4 23
CAP4 23-SMW-11-110723
07-Nov-23
320-106887-1
320-106887-3
6,100
3,800
1.61
CAP MW Sampling 3 23
CAPS 23-BCA-01-070723
07-Jul-23
320-102399-1
320-102399-1
34,000
18,000
1.89
CAP MW Sampling 3 23
CAPS 23-BCA-02-070723
07-Jul-23
320-102399-1
1 320-102399-2
13,000
7,300
1.78
CAP MW Sampling 3 23
CAPS 23-BCA-03R-071123
I I-Jul-23
320-102509-1
320-102509-9
110,000 J
69,000 J
1.59
CAP MW Sampling 3 23
CAPS 23-BLADEN-IDR-071223
12-Jul-23
320-102527-1
320-102527-9
240
160
1.50
CAP MW Sampling 3 23
CAPS 23-BLADEN-2D-080223
02-Aug-23
320-103526-1
320-103526-3
<5
<5
CAP MW Sampling 3 23
CAPS 23-BLADEN-2S-080123
01-Aug-23
320-103526-1
320-103526-2
77
48
1.60
CAP MW Sampling 3 23
CAPS 23-BLADEN-3D-082323
23-Aug-23
320-104207-1
320-104207-1
<5
<5
CAP MW Sampling 3 23
CAPS 23-BLADEN-3S-082223
22-Aug-23
320-104225-1
320-104225-5
80
49
1.63
CAP MW Sampling 3 23
CAPS 23-BLADEN-4D-082323
23-Aug-23
320-104207-1
320-104207-2
<5
<5
CAP MW Sampling 3 23
CAPS 23-BLADEN-4S-082323
23-Aug-23
320-104225-1
320-104225-7
16
10
1.60
CAP MW Sampling 3 23
CAPS 23-BLADEN-4S-082323-Z
23-Aug-23
320-104225-1
320-104225-8
16
9.9
1.62
CAP MW Sampling 3 23
CAPS 23-CUMBERLAND-1D-072823
28-Jul-23
320-103202-1
320-103202-2
39
24
1.63
CAP MW Sampling 3 23
CAPS 23-CUMBERLAND-1S-072723
27-Jul-23
320-103202-1
320-103202-1
37
23
1.61
CAP MW Sampling 3 23
CAPS 23-CUMBERLAND-2D-072823
28-Jul-23
320-103202-1
320-1032024
5.7 B
<5
CAP MW Sampling 3023
CAPS 23-CUMBERLAND-2S-072823
28-Jul-23
320-103202-1
320-103202-3
39
23
1.70
CAP MW Sampling 3 23
CAPS 23-CUMBERLAND-3D-082223
22-Aug-23
320-104207-1
320-104207-4
<5
<5
CAP MW Sampling 3 23
CAPS 23-CUMBERLAND-3S-082223
22-Aug-23
320-104207-1
320-104207-6
27
17
1.59
CAP MW Sampling 3 23
CAPS 23-CUMBERLAND-4D-082223
22-Aug-23
320-104225-1
320-104225-4
<5
<5
CAP MW Sampling 3 23
CAPS 23-CUMBERLAND-4S-082223
22-Aug-23
320-104225-1
320-104225-6
96
62
1.55
CAP MW Sampling 3 23
CAPS 23-CUMBERLAND-5DR-082423
24-Aug-23
320-104225-1
320-104225-3
<5
<5
CAP MW Sampling 3 23
CAPS 23-CUMBERLAND-5S-082423
24-Aug-23
320-104225-1
320-104225-10
22
13
1.69
CAP MW Sampling 3 23
CAP3 23-E BLK-BAILER-102423
24-Oct-23
320-106378-1
320-106378-1
<5
<5
CAP MW Sampling 3 23
CAPS 23-E BLK-BAILER-102423-Z
24-Oct-23
320-106378-1
320-106378-2
<5
<5
CAP MW Sampling 3 23
CAPS 23-E BLK-BP-071123
11-Jul-23
320-102509-1
320-102509-10
<5
<5
CAP MW Saxapling 3 23
CAPS 23-E BLK-DV-071223
12-Jul-23
320-102509-1
320-102509-11
<5
<5
CAP MW Sampling 3 23
CAPS 23-E BLK-DV-081623
16-Aug-23
320-104043-1
320-104043-6
<5
<5
CAP MW Sampling 3 23
CAP3 23-E BLK-FILTER-071423
14-Jul-23
320-102718-1
320-102718-11
<5
<5
Page 1 of 5 June 2024
TABLE 1
REVISED AND ORIGINAL PFPRA CONCENTRATIONS
Chemours Fayetteville Works, North Carolina
Sampling Program
Sample ID
Sample Date
Sample Delivery
Group
Laboratory
Sample ID
PFPrA Concentration (ng/L)
Factor
(revised
concentration /
original
concentration)
Revised
Concentration*
Original
Concentration
CAP MW Sampling 3 23
CAPS 23-E BLK-PP-071223
12-Jul-23
320-102527-1
320-102527-10
<5
<5
CAP MW Sampling 3 23
CAPS 23-E BLK-PP-071723
17-Jul-23
320-102718-1
320-102718-10
<5
<5
CAP MW Sampling 3 23
CAPS 23-E BLK-PP-080423
04-Aug-23
320-104043-1
320-104043-4
<5 UJ
<5 UJ
CAP MW Sampling 3 23
CAPS 23-E BLK-PP-081823
18-Aug-23
320-104043-1
320-104043-5
<5
<5
CAP MW Sampling 3 23
CAPS 23-E BLK-PP-102423
24-Oct-23
320-106378-1
320-106378-3
<5
<5
CAP MW Sampling 3 23
CAPS 23-E BLK-PP-102423-Z
24-Oct-23
320-106378-1
320-106378-4
<5
<5
CAP MW Sampling 3 23
CAPS 23-FTA-01-071923
19-Jul-23
320-102791-1
320-102791-1
280
180
1.56
CAP MW Sampling 3 23
CAPS 23-FTA-02-071923
19-Jul-23
320-102791-1
320-102791-2
21,000
14,000
1.50
CAP MW Sampling 3 23
CAPS 23-FTA-02-071923-D
19-Jul-23
320-102791-1
320-102791-3
21,000
13,000
1.62
CAP MW Sampling 3 23
CAPS 23-FTA-03-071923
19-Jul-23
320-102791-1
320-102791-4
14,000
8,600
1.63
CAP MW Sarapling 3 23
CAPS 23-INSITU-01-071323
13-Jul-23
320-102712-1
320-102712-8
850
530
1.60
CAP MW Sarapling 3 23
CAPS 23-LTW-Ol-071323
13-Jul-23
320-102712-1
320-102712-2
22,000
14,000
1.57
CAP MW Sarapling 3 23
CAPS 23-LTW-02-071223
12-Jul-23
320-102527-1
320-102527-8
16,000
11,000
1.45
CAP MW Sarapling 3 23
CAPS 23-LTW-03-071223
12-Jul-23
320-102527-1
320-102527-5
62,000 J
37,000
1.68
CAP MW Sarapling 3 23
CAPS 23-LTW-04-071123
11-Jul-23
320-102527-1
320-102527-1
53,000
29,000
1.83
CAP MW Sanapling 3 23
CAPS 23-LTW-05-071123
11-Jul-23
320-102509-1
320-102509-6
83,000 J
52,000 J
1.60
CAP MW Sanapling 3023
CAPS 23-MW-24-071823
18-Jul-23
320-102688-1
320-102688-1
240,000
150,000
1.60
CAP MW Sanapling 3 23
CAPS 23-MW-13D-071023
10-Jul-23
320-102399-1
320-102399-9
61,000 J
39,000 J
1.56
CAP MW Sampling 3 23
CAPS 23-MW-14D-071323
13-Jul-23
320-102716-1
320-102716-2
130,000
83,000
1.57
CAP MW Sampling 3 23
CAPS 23-MW-15DRR-071123
11-Jul-23
320-102509-1
320-102509-1
8,800
5,300
1.66
CAP MW Sampling 3 23
CAPS 23-MW-16D-071223
12-Jul-23
320-102527-1
320-102527-7
1,000
630
1.59
CAP MW Sampling 3 23
CAPS 23-MW-18D-071723
17-Jul-23
320-102716-1
320-102716-6
680
430
1.58
CAP MW Sampling 3 23
CAP3 23-MW-19D-071023
10-Jul-23
320-102399-1
320-102399-10
960
640
1.50
CAP MW Sampling 3 23
CAPS 23-MW-12S-071823
18-Jul-23
320-102688-1
320-102688-2
6,600
4,300
1.53
CAP MW Sampling 3 23
CAPS 23-MW-20D-071123
11-Jul-23
320-102509-1
320-102509-7
4,900
3,300
1.48
CAP MW Sampling 3 23
CAPS 23-MW-20D-071123-D
11-Jul-23
320-102509-1
320-102509-8
5,300
3,300
1.61
CAP MW Sampling 3 23
CAPS 23-MW-21D-071423
14-Jul-23
320-102716-1
320-102716-4
800
500
1.60
CAP MW Sampling 3 23
CAPS 23-MW-22D-071223
12-Jul-23
320-102527-1
320-102527-4
970
580
1.67
CAP MW Sarapling 3 23
CAPS 23-MW-23-071723
17-Jul-23
320-102718-1
320-102718-2
2,500
1,400
1.79
CAP MW Sarapling 3 23
CAPS 23-MW-1S-071823
18-Jul-23
320-102688-1
320-102688-3
11,000
6,600
1.67
CAP MW Sampling 3 23
CAPS 23-MW-25-071823
18-Jul-23
320-102718-1
320-102718-7
10,000
6,700
1.49
CAP MW Sampling 3 23
CAPS 23-MW-27-071323
13-Jul-23
320-102712-1
320-102712-7
40,000
26,000
1.54
CAP MW Sampling 3 23
CAPS 23-MW-28-071323
13-Jul-23
320-102712-1
320-102712-4
730
460
1.59
CAP MW Sanapling 3 23
CAPS 23-MW-30-071823
18-Jul-23
320-102718-1
320-102718-5
7,000
4,700
1.49
CAP MW Sanapling 3 23
CAPS 23-MW-7S-071823
18-Jul-23
320-102718-1
320-102718-6
5,700
3,900
1.46
CAP MW Sampling 3 23
CAPS 23-MW-9S-071823
18-Jul-23
320-102718-1
320-102718-9
2,900
1,800
1.61
CAP MW Sampling 3 23
CAPS 23-NAF-04-081723
17-Aug-23
320-104207-1
320-104207-7
160,000
100,000
1.60
CAP MW Sampling 3 23
CAPS 23-NAF-05A-102423
24-Oct-23
320-106358-1
320-106358-1
240,000
150,000
1.60
CAP MW Sampling 3 23
CAPS 23-NAF-05A-102423-D
24-Oct-23
320-106358-1
320-106358-2
240,000
150,000
1.60
CAP MW Sampling 3 23
CAPS 23-NAF-05A-102423-D-Z
24-Oct-23
320-106358-1
320-106358-4
240,000
150,000
1.60
CAP MW Sampling 3 23
CAPS 23-NAF-05A-102423-Z
24-Oct-23
320-106358-1
320-106358-3
190,000
120,000
1.58
CAP MW Sampling 3 23
CAPS 23-NAF-06-071923
19-Jul-23
320-102796-1
320-102796-1
380,000
240,000
1.58
CAP MW Sampling 3 23
CAPS 23-NAF-06-071923-Z
19-Jul-23
320-102796-1
320-102796-2
410,000
250,000
1.64
CAP MW Sampling 3 23
CAPS 23-NAF-07-071923
19-Jul-23
320-102796-1
320-102796-3
3,600
2,100
1.71
CAP MW Sarapling 3 23
CAPS 23-NAF-08A-081723
17-Aug-23
320-104225-1
320-104225-2
41,000
26,000
1.58
CAP MW Sampling 3 23
CAPS 23-NAF-11A-071923
19-Jul-23
320-102796-1
320-102796-4
15,000
9,400
1.60
CAP MW Sampling 3 23
CAPS 23-NAF-12-081723
17-Aug-23
320-104225-1
320-104225-1
200,000
130,000
1.54
CAP MW Sampling 3 23
CAPS 23-NAF-13-102423
24-Oct-23
320-106358-1
320-106358-5
10,000
6,600
1.52
CAP MW Sampling 3 23
CAPS 23-NAF-13-102423-Z
24-Oct-23
320-106358-1
320-106358-6
10,000
6,600
1.52
CAP MW Sampling 3 23
CAP3 23-OW-28-071123
11-Jul-23
320-102509-1
320-102509-5
5,200
3,500
1.49
CAP MW Sarnpling 3 23
CAPS 23-OW-30-071323
13-Jul-23
320-102712-1
320-102712-10
19,000
12,000
1.58
CAP MW Sampling 3023
CAPS 23-OW-30-071323-Z
13-Jul-23
320-102712-1
320-102712-11
19,000
12,000
1.58
CAP MW Sampling 3 23
CAPS 23-OW-32-090823
08-Sep-23
320-104780-1
320-104780-1
990
640
1.55
CAP MW Sampling 3 23
CAPS 23-OW-32-090823-D
08-Sep-23
320-104780-1
320-104780-2
970
620
1.56
CAP MW Sampling 3 23
CAP3 23-OW-32-090823-D-Z
08-Sep-23
320-104780-1
320-104780-4
930
620
1.50
CAP MW Sampling 3 23
CAPS 23-OW-32-090823-Z
08-Sep-23
320-104780-1
320-104780-3
1,000
650
1.54
CAP MW Sampling 3 23
CAPS 23-OW-33-071223
12-Jul-23
320-102527-1
320-102527-3
9,900
5,400
1.83
CAP MW Sampling 3 23
CAP3 23-OW-37-081023
10-Aug-23
320-104266-1
320-104266-3
8,200 J
5,200 J
1.58
CAP MW Sampling 3 23
CAPS 23-OW-40-071323
13-Jul-23
320-102712-1
320-102712-9
5,700
3,700
1.54
CAP MW Sampling 3 23
CAPS 23-OW-4R-080423
04-Aug-23
320-103526-1
320-103526-7
25,000
17,000
1.47
CAP MW Sarapling 3 23
CAPS 23-OW-51-080323
03-Aug-23
320-103526-1
320-103526-6
92,000
60,000
1.53
CAP MW Sampling 3 23
CAPS 23-OW-56-073123
31-Jul-23
320-103202-1
320-103202-9
2,200
1,400
1.57
CAP MW Sampling 3 23
CAPS 23-OW-57-073123
31-Jul-23
320-103202-1
320-103202-10
44,000
28,000
1.57
CAP MW Sampling 3 23
CAPS 23-PIW-IODR-071423
14-Jul-23
320-102716-1
320-102716-5
26,000
17,000
1.53
CAP MW Sampling 3 23
CAPS 23-PIW-lOS-071323
13-Jul-23
320-102712-1
320-102712-5
5,300
3,100
1.71
CAP MW SarnDlina 3023
CAPS 23-PIW-11-073123
31-Jul-23
320-103202-1
320-103202-8
3,400
2,000
1.70
CAP MW Sampling 3 23
CAPS 23-PIW-16D-071423
14-Jul-23
320-102716-1
320-102716-3
<5
<5
CAP MW Sampling 3 23
CAPS 23-PIW-16S-071023
10-Jul-23
320-102399-1
320-102399-7
1,100
770
1.43
CAP MW Sampling 3 23
CAP3 23-PIW-1D-080223
02-Aug-23
320-103526-1
320-103526-4
12,000 J
7,800
1.54
CAP MW Sampling 3 23
CAPS 23-PIW-3D-071323
13-Jul-23
320-102712-1
320-102712-1
19,000
11,000
1.73
CAP MW Sampling 3 23
CAPS 23-PIW-4D-071323
13-Jul-23
320-102712-1
320-102712-3
880
550
1.60
CAP MW Sampling 3 23
CAPS 23-PIW-5SR-080423
04-Aug-23
320-103526-1
320-103526-8
44,000
29,000
1.52
CAP MW Sampling 3 23
CAP3 23-PIW-5SR-080423-Z
04-Aug-23
320-103526-1
320-103526-9
40,000
26,000
1.54
CAP MW Sampling 3 23
CAPS 23-PIW-6S-071223
12-Jul-23
320-102527-1
320-102527-6
64,000 J
50,000 J
1.28
CAP MW Sampling 3 23
CAPS 23-PIW-7D-071123
11-Jul-23
320-102509-1
320-102509-3
79,000 J
49,000 J
1.61
CAP MW Sampling 3 23
CAP3 23-PIW-7S-071123
11-Jul-23
320-102509-1
320-102509-2
14,000
9,700
1.44
CAP MW Sampling 3 23
CAPS 23-PIW-8D-071123
11-Jul-23
320-102509-1
320-102509-4
57,000
34,000
1.68
CAP MW Sampling 3 23
CAP3 23-PW-01-071723
17-Jul-23
320-102716-1
320-102716-10
48,000
33,000
1.45
Page 2 of 5 June 2024
TABLE 1
REVISED AND ORIGINAL PFPRA CONCENTRATIONS
Chemours Fayetteville Works, North Carolina
Sampling Program
Sample ID
Sample Date
Sample Delivery
Group
Laboratory
Sample ID
PFPrA Concentration (ng/L)
Factor
(revised
concentration /
original
concentration)
Revised
Concentration*
Original
Concentration
CAP MW Sampling 3 23
CAPS 23-PW-02-071923
19-Jul-23
320-102796-1
320-102796-5
6,400
4,000
1.60
CAP MW Sampling 3 23
CAPS 23-PW-02-071923-Z
19-Jul-23
320-102796-1
320-102796-6
6,600
4,300
1.53
CAP MW Sampling 3 23
CAPS 23-PW-03-071923
19-Jul-23
320-102796-1
320-102796-7
76,000
47,000
1.62
CAP MW Sampling 3 23
CAPS 23-PW-04-072823
28-Jul-23
320-103202-1
320-103202-5
1,400
900
1.56
CAP MW Sampling 3 23
CAPS 23-PW-04-072823-Z
28-Jul-23
320-103202-1
320-103202-6
1,600
890
1.80
CAP MW Sampling 3 23
CAPS 23-PW-06-071023
10-Jul-23
320-102399-1
320-102399-11
920
620
1.48
CAP MW Sampling 3 23
CAPS 23-PW-09-081023
10-Aug-23
320-104266-1
320-104266-1
<5 UJ
<5 UJ
CAP MW Sampling 3 23
CAPS 23-PW-09-081023-Z
10-Aug-23
320-104266-1
320-104266-2
<5 UJ
<5 UJ
CAP MW Sampling 3 23
CAPS 23-PW-IORR-080323
03-Aug-23
320-103526-1
320-103526-5
60,000
39,000
1.54
CAP MW Sampling 3 23
CAPS 23-PW-11-070723
07-Jul-23
320-102399-1
320-102399-3
25,000
17,000
1.47
CAP MW Sarapling 3 23
CAPS 23-PW-12-071723
17-Jul-23
320-102716-1
320-102716-7
22
14
1.57
CAP MW Sarapling 3 23
CAPS 23-PW-13-071323
13-Jul-23
320-102716-1
320-102716-1
<5
<5
CAP MW Sarapling 3 23
CAPS 23-PW-14-070723
07-Jul-23
320-102399-1
320-102399-4
35,000
24,000
1.46
CAP MW Sarapling 3 23
CAPS 23-PW-14-070723-D
07-Jul-23
320-102399-1
320-102399-5
36,000
24,000
1.50
CAP MW Sarapling 3 23
CAPS 23-PW-15R-070723
07-Jul-23
320-102399-1
320-102399-6
91,000 J
58,000 J
1.57
CAP MW Sanapling 3 23
CAPS 23-PZ-11-071723
17-Jul-23
320-102716-1
320-102716-8
2,700
1,500
1.80
CAP MW Sanapling 3023
CAP3 23-PZ-15-071823
18-Jul-23
320-102718-1
320-102718-8
4,500
3,000
1.50
CAP MW Sanapling 3 23
CAP3 23-PZ-19R-081523
15-Aug-23
320-104207-1
320-104207-3
14,000
8,900
1.57
CAP MW Sampling 3 23
CAPS 23-PZ-20R-081523
15-Aug-23
320-104207-1
320-104207-5
13,000
8,200
1.59
CAP MW Sampling 3 23
CAPS 23-PZ-21R-081523
15-Aug-23
320-104225-1
320-104225-9
4,700
2,900
1.62
CAP MW Sampling 3 23
CAPS 23-PZ-24-071723
17-Jul-23
320-102718-1
320-102718-4
2,900
1,700
1.71
CAP MW Sampling 3 23
CAPS 23-PZ-26-071723
17-Jul-23
320-102718-1
320-102718-1
130
91
1.43
CAP MW Sampling 3 23
CAPS 23-PZ-27-071323
13-Jul-23
320-102712-1
320-102712-6
350
230
1.52
CAP MW Sampling 3 23
CAPS 23-PZ-28-071723
17-Jul-23
320-102718-1
320-102718-3
440
310
1.42
CAP MW Sampling 3 23
CAPS 23-PZ-35-082123
21-Aug-23
320-104266-1
320-104266-4
8,700
5,400
1.61
CAP MW Sampling 3 23
CAPS 23-PZ-35-082123-D
21-Aug-23
320-104266-1
320-104266-5
8,600
5,400
1.59
CAP MW Sarapling 3 23
CAPS 23-ROBESON-1D-072823
28-Jul-23
320-103202-1
320-103202-7
23 B
13
1.77
CAP MW Sarapling 3 23
CAPS 23-ROBESON-1S-080123
01-Aug-23
320-103526-1
320-103526-1
39
26
1.50
CAP MW Sampling 3 23
CAPS 23-SMW-Ol-071023
10-Jul-23
320-102399-1
320-102399-8
610
400
1.53
CAP MW Sampling 3 23
CAPS 23-SMW-03B-071923
19-Jul-23
320-102791-1
320-102791-5
150,000
95,000
1.58
CAP MW Sampling 3023
CAPS 23-SMW-06B-081623
16-Aug-23
320-104043-1
320-104043-1
260,000
170,000
1.53
CAP MW Sampling 3 23
CAPS 23-SMW-07-071823
18-Jul-23
320-102688-1
320-102688-4
1,000
500
2.00
CAP MW Sampling 3 23
CAPS 23-SMW-08B-081623
16-Aug-23
320-104043-1
320-104043-2
31,000
20,000
1.55
CAP MW Sampling 3 23
CAPS 23-SMW-08B-081623-D
16-Aug-23
320-104043-1
320-104043-3
31,000
20,000
1.55
CAP MW Sampling 3 23
CAPS 23-SMW-09-071923
19-Jul-23
320-102791-1
320-102791-6
4,800
3,100
1.55
CAP MW Sampling 3 23
CAPS 23-SMW-10-071723
17-Jul-23
320-102716-1
320-102716-9
210
130
1.62
CAP MW Sampling 3 23
CAPS 23-SMW-11-071723
17-Jul-23
320-102716-1
320-102716-11
4,500
3,000
1.50
CAP MW Sampling 3 23
CAPS 23-SMW-12-071823
18-Jul-23
320-102688-1
320-102688-5
5,900
3,900
1.51
CAP MW Sampling 3 23
CAPS-PZ-22-071123
II-Jul-23
320-102527-1
320-102527-2
76,000
48,000
1.58
CAP MW Sampling 4 23
CAP4 23-E BLK-BAILER-110923
09-Nov-23
320-107233-1
320-107233-6
<5
<5
CAP MW Sampling 4 23
CAP4 23-E BLK-BAILER-110923-Z
09-Nov-23
320-107233-1
320-107233-7
<5
<5
CAP MW Sampling 4 23
CAP4 23-LTW-03-111323
13-Nov-23
320-107233-1
320-107233-3
61,000 J
38,000 J
1.61
CAP MW Sampling 4 23
CAP4 23-PW-04-110923
09-Nov-23
320-107233-1
320-107233-1
1,500
960
1.56
CAP MW Sarapling 4 23
CAP4 23-PW-04-110923-Z
09-Nov-23
320-107233-1
320-107233-2
1,500
980
1.53
CAP MW Sampling 4023
CAP4 23-SMW-10-111623
16-Nov-23
320-107233-1
320-107233-5
230
160
1.44
CAP MW Sampling 4 23
CAP4 23-SMW-12-110823
08-Nov-23
320-107233-1
320-107233-4
7,000
4,600
1.52
CAP SW Sampling 3 23
CAPS 23-CFR-BLADEN-072623
26-Jul-23
320-103017-1
320-103017-5
44
26
1.69
CAP SW Sampling 3 23
CAPS 23-CFR-KINGS-080123
01-Aug-23
320-103199-1
320-103199-2
32
21
1.52
CAP SW Sampling 3 23
CAPS 23-CFR-RM-76-072623
26-Jul-23
320-103017-1
320-103017-1
27
17
1.59
CAP SW Sampling 3 23
CAPS 23-CFR-TARHEEL-072723
27-Jul-23
320-103017-1
320-103017-6
44
26
1.69
CAP SW Sampling 3 23
CAPS 23-CFR-TARHEEL-6-072723
27-Jul-23
320-103199-1
320-103199-1
32
20
1.60
CAP SW Sampling 3 23
CAP3 23-E BLK-IS-072723
27-Jul-23
320-103017-1
320-103017-7
<5
<5
CAP SW Sampling 3 23
CAPS 23-E BLK-PP-072723
27-Jul-23
320-103017-1
320-103017-8
<5
<5
CAP SW Sampling 3 23
CAPS 23-GBC-1-072623
26-Jul-23
320-103017-1
320-103017-2
540
330
1.64
CAP SW Sampling 3 23
CAPS 23-LOCK-DAM-NORTH-072623
26-Jul-23
320-103017-1
320-103017-4
5,500
3,300
1.67
CAP SW Sampling 3 23
CAPS 23-LOCK-DAM-SEEP-072623
26-Jul-23
320-103017-1
320-103017-3
22,000
13,000
1.69
CAP SW Sampling 3 23
CAPS 23-OLDOF-1-24-072723
27-Jul-23
320-103013-1
320-103013-6
1,400
920
1.52
CAP SW Sampling 3 23
CAPS 23-OUTFALL-002-24-072723
27-Jul-23
320-103016-1
320-103016-4
730
460
1.59
CAP SW Sampling 3023
CAPS 23-SEEP-A-EFF-24-072723
27-Jul-23
320-103013-2
320-103013-1
3,700 J
2,300 J
1.61
CAP SW Sampling 3 23
CAPS 23-SEEP-B-EFF-24-072723
27-Jul-23
320-103013-2
320-103013-2
1,700 J
1,100 J
1.55
CAP SW Sampling 3 23
CAPS 23-SEEP-C-EFF-24-072723
27-Jul-23
320-103013-2
320-103013-3
330 J
200 J
1.65
CAP SW Sampling 3 23
CAPS 23-SEEP-D-EFF-24-072723
27-Jul-23
320-103013-1
320-103013-4
370
240
1.54
CAP SW Sampling 3 23
CAPS 23-WC-1-24-072723
27-Jul-23
320-103016-1
320-103016-1
770
500
1.54
CAP SW Sampling 3 23
CAPS 23-WC-2-24-072723
27-Jul-23
320-103016-1
320-103016-2
570
360
1.58
CAP SW Sampling 3 23
CAPS 23-WC-3-24-072723
27-Jul-23
320-103016-1
320-103016-3
280
180
1.56
CAP SW Sampling 3023
OUTFALL-002-24-072723-D
27-Jul-23
320-103016-1
320-103016-5
730
480
1.52
CAP SW Sampling 3 23
RIVER-WATER-INTAKE2-072623
26-Jul-23
320-103013-1
320-103013-5
1 1,100
680
1.62
CAP SW Sampling 3 23
RNER-WATER-INTAKE2-24-072823
28-Jul-23
320-103199-1
320-103199-3
210
130
1.62
CAP SW Sampling 4 23
CAP4 23-CFR-BLADEN-120623
06-Dec-23
320-107896-1
320-107896-1
49
31
1.58
CAP SW Sampling 4 23
CAP4 23-CFR-KINGS-121423
14-Dec-23
320-108081-1
320-108081-1
44 J
28 J
1.57
CAP SW Sampling 4 23
CAP4 23-CFR-RM-76-112223
22-Nov-23
320-107648-1
320-107648-1
20
11
1.82
CAP SW Sampling 4 23
CAP4 23-CFR-TARHEEL-120623
06-Dec-23
320-107896-1
320-107896-2
50
32
1.56
CAP SW Sampling 4023
CAP4 23-GBC-1-112223
22-Nov-23
320-107648-1
320-107648-2
680
410
1.66
CAP SW Sampling 4 23
CAP4 23-LOCK-DAM-NORTH-112223
22-Nov-23
320-107648-1
320-107648-5
4,800
3,000
1.60
CAP SW Sampling 4 23
CAP4 23-LOCK-DAM-SEEP-112223
22-Nov-23
320-107648-1
320-107648-3
9,000 J
5,600 J
1.61
CAP SW Sampling 4 23
CAP4 23-LOCK-DAM-SEEP-112223-D
22-Nov-23
0-1077
0-107648-4
600
1,,000 J
0.86
CAP SW Sampling 4 23
2-Nov-2
0-10
320-9
1,600J
1000
1.60480-1
CAP SW Sampling 4 23
CAP4 23-OUTFALL-002-112323
23-Nov-23
320-107480-1
320-107480-6
230
150
1.53
Page 3 of 5 June 2024
TABLE 1
REVISED AND ORIGINAL PFPRA CONCENTRATIONS
Chemours Fayetteville Works, North Carolina
Sampling Program
Sample ID
Sample Date
Sample Delivery
Group
Laboratory
Sample ID
PFPrA Concentration (ng/L)
Factor
(revised
concentration /
original
concentration)
Revised
Concentration*
Original
Concentration
CAP SW Sampling 4 23
CAP4 23-SEEP-C-112323
23-Nov-23
320-107480-1
320-107480-4
22
14
1.57
CAP SW Sampling 4 23
CAP4 23-TARHEEL-24-112423
24-Nov-23
320-107480-1
320-107480-8
37
25
1.48
CAP SW Sawlina 4023
CAP4 23-WC-1-112323
23-Nov-23
320-107480-1
320-107480-1
250
170
1.47
CAP SW Sampling 4 23
CAP4 23-WC-1-112323-D
23-Nov-23
320-107480-1
320-107480-7
330
210
1.57
CAP SW Sampling 4 23
CAP4 23-WC-2-112323
23-Nov-23
320-107480-1
320-107480-2
340 J
220 J
1.55
CAP SW Sampling 4 23
CAP4 23-WC-3-112323
23-Nov-23
320-107480-1
320-107480-3
150
96
1.56
CAP SW Sampling 4 23
RIVER-WATER-INTAKE2-24-112323
23-Nov-23
320-107480-1
320-107480-5
1,800
1,200
1.50
PI Dry Sampling 11/23
DITrailerOutlet-112823
28-Nov-23
320-107660-1
320-107660-3
<5
<5
PII Dry Sampling 11/23
STW-LOC-16-112823
28-Nov-23
320-107660-1
320-107660-4
150,000
95,000
1.58
P I I Dry Sam lin 11/23
STW-LOC-18-4-112823
28-Nov-23
320-107656-1
320-107656-2
43 J
<25 UJ
PII Dry Sampling 11/23
STW-LOC-19A-112823
28-Nov-23
320-107660-1
320-107660-1
46
29
1.59
PI Dry Sampling 11/23
STW-LOC-19B-112823
28-Nov-23
320-107660-1
320-107660-5
25
16
1.56
PI Dry Sampling 11/23
STW-LOC-22-4-112823
28-Nov-23
320-107656-1
320-107656-3
250
160
1.56
P11 Dry Sampling 11/23
STW-LOC-22-4-112823-D
28-Nov-23
320-107656-1
320-107656-4
270
170
1.59
P11 Dry Sampling 11/23
STW-LOC-23C-1-4-112823
28-Nov-23
320-107656-1
320-107656-5
170
120
1.42
PI Dry Sampling 11/23
STW-LOC-23C-2-4-112823
28-Nov-23
320-107656-1
320-107656-6
54
35
1.54
P I I Dry Sam lin 11/23
STW-LOC-23C-3-4-112823
28-Nov-23
320-107656-1
320-107656-7
20
13
1.54
PI Dry Sampling 11/23
STW-LOC-8-4-112823
28-Nov-23
320-107656-1
320-107656-1
870
570
1.53
PI Dry Sampling 11/23
STW-LOC-9A-112823
28-Nov-23
320-107660-1
320-107660-2
110
69
1.59
PI Dry Sampling 11/23
STW-LOC-EB-DR-112823
28-Nov-23
320-107660-1
320-107660-6
<5
<5
PII Dry Sampling 11/23
STW-LOC-EB-IS-112823
28-Nov-23
320-107660-1
320-107660-8
<5
<5
PI Dry Sampling 11/23
STW-LOC-FB-112823
28-Nov-23
320-107660-1
320-107660-7
<5
<5
P I I Dry Sampling 8/23
STW-LOC-l0A-4-080423
04-Aug-23
320-103457-1
320-103457-2
820
540
1.52
P I I Dry Sam lin 8/23
STW-LOC-11-3.66-080423
04-Aug-23
320-103457-1
320-103457-3
230
150
1.53
P I I Dry Sampling 8/23
STW-LOC-12-4-080423
04-Aug-23
320-103457-1
320-103457-4
150
95
1.58
P I I Dry Sampling 8/23
STW-LOC-13-4-080423
04-Aug-23
320-103457-1
320-103457-5
110
68
1.62
P I I Dry Sampling 8/23
STW-LOC-1-4-080423
04-Aug-23
320-103460-1
320-103460-1
150
94
1.60
P I I Dry Sampling 8/23
STW-LOC-14-4-080423
04-Aug-23
320-103457-1
320-103457-6
110
66
1.67
P I I Dry Sampling 8/23
STW-LOC-15-4-080423
04-Aug-23
320-103457-1
320-103457-7
930
610
1.52
P I I Dry Sampling 8/23
STW-LOC-16-080723
07-Aug-23
320-103451-1
320-103451-4
1,400,000
490,000
2.86
PH DrvSamD1inR 8/23
STW-LOC-18-4-080723
07-Aug-23
320-103461-1
320-103461-6
250
160
1.56
P I I Dry Sampling 8/23
STW-LOC-18-4-080723-D
07-Aug-23
320-103461-1
320-103461-7
250
160
1 1.56
P I I Dry Sampling 8/23
STW-LOC-19A-080723
07-Aug-23
320-103451-1
320-103451-1
99
64
1.55
PI Dry Sampling 8/23
STW-LOC-19B-080723
07-Aug-23
320-103451-1
320-103451-2
72
46
1.57
PI Dry Sampling 8/23
STW-LOC-20-4-080423
04-Aug-23
320-103457-1
320-103457-8
470
310
1.52
P I I Dry Sampling 8/23
STW-LOC-21A-080423
04-Aug-23
320-103457-1
320-103457-9
280
180
1.56
P I I Dry Sampling 8/23
STW-LOC-22-4-080723
07-Aug-23
320-103461-1
320-103461-1
140 J
911
1.54
P I I Dry Sam hn 8/23
STW-LOC-23C-1-4-080723
07-Aug-23
320-103461-1
320-103461-3
330
200
1.65
P I I Dry Sampling 8/23
STW-LOC-23C-2-2-080723
07-Aug-23
320-103461-1
320-103461-4
70
44
1.59
P I I Dry Sampling 8/23
STW-LOC-23C-3-4-080723
07-Aug-23
320-103461-1
320-103461-5
210
130
1.62
P I I Dry Sampling 8/23
STW-LOC-2-4-080423
04-Aug-23
320-103460-1
320-103460-2
120
80
1.50
P I I Dry Sampling 8/23
STW-LOC-3-4-080423
04-Aug-23
320-103460-1
320-103460-3
330
190
1.74
P I I Dry Sampling 8/23
STW-LOC-4-4-080423
04-Aug-23
320-103460-1
320-103460-4
130
78
1.67
P I I Dry Sampling 8/23
STW-LOC-5-3-080423
04-Aug-23
320-103460-1
320-103460-5
50
26
1.92
P I I Dry Sam lin 8/23
STW-LOC-7A-4-080423
04-Aug-23
320-103460-1
320-103460-6
140
91
1.54
P I I Dry Sampling 8/23
STW-LOC-7A-4-080423-D
04-Aug-23
320-103460-1
320-103460-7
150
95
1.58
P I I Dry Sampling 8/23
STW-LOC-7B-4-080423
04-Aug-23
320-103460-1
320-103460-8
170
110
1.55
P I I Dry Sampling 8/23
STW-LOC-7C-4-080423
04-Aug-23
320-103460-1
320-103460-9
180
120
1.50
P I I Dry Sampling 8/23
STW-LOC-8-3-080723
07-Aug-23
320-103461-1
320-103461-2
150
93
1.61
P I I Dry Sampling 8/23
STW-LOC-9-4-080423
04-Aug-23
320-103457-1
320-103457-1
750
490
1.53
PI Dry Sampling 8/23
STW-LOC-9A-080723
07-Aug-23
320-103451-1
320-103451-3
460
290
1.59
PI I Dry Sam lin 8/23
STW-LOC-DITrailerOutlet-080823
08-Aug-23
320-103451-1
320-103451-5
<5
<5
P I I Dry Sampling 8/23
STW-LOC-EB-DR-080723
07-Aug-23
320-103451-1
320-103451-9
<5
<5
P I I Dry Sampling 8/23
STW-LOC-EB-IS-080423
04-Aug-23
320-103451-1
320-103451-7
<5
<5
P I I Dry Sampling 8/23
STW-LOC-EB-IS-080723
07-Aug-23
320-103451-1
320-103451-8
<5
<5
P I I Dry Sampling 8/23
STW-LOC-FB-080423
04-Aug-23
320-103451-1
320-103451-6
<5
<5
P I I Dry Sampling 8/23
STW-LOC-FB-080723
07-Aug-23
320-103451-1
320-103451-10
<5
<5
PII Full Sampling 11/23
STW-LOC-1-4-112123
21-Nov-23
320-107670-1
320-107670-1
120 J
76
1.58
PI Full Sampling 11/23
STW-LOC-11-2.66-112223
22-Nov-23
320-107659-1
320-107659-1
220
140
1.57
PI Full Sampling 11/23
STW-LOC-12-4-112223
22-Nov-23
320-107659-1
320-107659-2
120
74
1.62
PI Full Sampling 11/23
STW-LOC-13-4-112223
22-Nov-23
320-107659-1
320-107659-3
170
110
1.55
PI Full Sampling 11/23
STW-LOC-l0A-4-112123
21-Nov-23
320-107670-1
320-107670-10
340
210
1.62
PI Full Sampling 11/23
STW-LOC-14-4-112123
21-Nov-23
320-107659-1
320-1076594
87
54
1.61
PI Full Sampling 11/23
STW-LOC-14-4-112123-D
21-Nov-23
320-107659-1
320-107659-5
88
55
1.60
PI Full Sampling 11/23
STW-LOC-15-4-112123
21-Nov-23
320-107659-1
320-107659-6
340
220
1.55
PI Full Sampling 11/23
STW-LOC-20-4-112123
21-Nov-23
320-107659-1
320-107659-7
240
150
1.60
PI Full Sampling 11/23
STW-LOC-21B-112223
22-Nov-23
320-107659-1
320-107659-8
120
72
1.67
PI I Full Sampling 11/23
STW-LOC-EB-IS-112223
22-Nov-23
320-107670-1
320-107670-11
<5
<5
PI I Full Sampling 11/23
STW-LOC-2-4-112223
22-Nov-23
320-107670-1
320-107670-2
96
63
1.52
PI Full Sampling 11/23
STW-LOC-3-3.66-112223
22-Nov-23
320-107670-1
320-107670-3
280
190
1.47
PI Full Sampling 11/23
STW-LOC-44-112223
22-Nov-23
320-107670-1
320-107670-4
73
48
1.52
PI Full Sampling 11/23
STW-LOC-5-4-112223
22-Nov-23
320-107670-1
320-107670-5
54
36
1.50
PI Full Sampling 11/23
STW-LOC-7A-4-112123
21-Nov-23
320-107670-1
320-107670-6
130J
82
1.59
PI Full Sampling 11/23
STW-LOC-7B-4-112123
21-Nov-23
320-107670-1
320-107670-7
1901
120
1.58
PI Full Sampling 11/23
STW-LOC-7C-4-112123
21-Nov-23
320-107670-1
320-107670-8
1801
110
1.64
PI Full Sampling 11/23
STW-LOC-9-4-112123
21-Nov-23
320-107670-1
320-107670-9
290
180
1.61
PI Full Sampling 11/23
STW-LOC-FB-112223
22-Nov-23
320-107659-1
320-107659-9
<5
<5
PI I Sampling 9/23
DITrailerOutlet-092523
26-Sep-23
320-105406-1
320-105406-10
75
75
Page 4 of 5 June 2024
TABLE 1
REVISED AND ORIGINAL PFPRA CONCENTRATIONS
Chemours Fayetteville Works, North Carolina
Sampling Program
Sample ID
Sample Date
Sample Delivery
Group
Laboratory
Sample ID
PFPrA Concentration (ng/L)
Factor
(revised
concentration /
original
concentration)
Revised
Concentration*
Original
Concentration
P I I Sampling 9/23
STW-LOC-l0A-4-092223
22-Sep-23
320-105437-1
320-105437-2
900
640
1.41
PH Sampling 9/23
STW-LOC-12-092523
25-Sep-23
320-105437-1
320-105437-3
86
55
1.56
Pll Sampling 9/23
STW-LOC-13-4-092223
22-Sep-23
320-105437-1
320-105437-4
170
110
1.55
PH Sampling 9/23
STW-LOC-14-092623
26-Sep-23
320-105410-1
320-105410-1
110
69
1.59
Pll Sampling 9/23
STW-LOC-14-4-092223
22-Sep-23
320-105437-1
320-105437-5
78
49
1.59
PH Sampling 9/23
STW-LOC-16-092523
25-Sep-23
320-105406-1
320-105406-8
120,000 J
79,000 J
1.52
P I I Sampling 9/23
STW-LOC-18-4-092523
25-Sep-23
320-105406-1
320-105406-2
54
34
1.59
P I I Sampling 9/23
STW-LOC-19B-092523
25-Sep-23
320-105406-1
320-105406-9
46
29
1.59
PH Sampling 9/23
STW-LOC-20-4-092223
22-Sep-23
320-105437-1
320-105437-6
180
120
1.50
PH Sampling 9/23
STW-LOC-21B-092523
25-Sep-23
320-105437-1
320-105437-7
290
200
1.45
P I I Sampling 9/23
STW-LOC-22-4-092523
25-Sep-23
320-105406-1
320-105406-3
920J
560J
1.64
P I I Sampling 9/23
STW-LOC-23C-1-4-092523
25-Sep-23
320-105406-1
320-1054064
43
1 27
1.59
P I I Sampling 9/23
STW-LOC-23C-14-092523-D
25-Sep-23
320-105406-1
320-105406-5
40
25
1.60
PH Sampling 9/23
STW-LOC-23C-2-4-092523
25-Sep-23
320-105406-1
320-105406-6
48
31
1.55
PH Sampling 9/23
STW-LOC-2-4-092323
23-Sep-23
320-105410-1
320-105410-2
60
38
1.58
PH Sampling 9/23
STW-LOC-3-4-092323
23-Sep-23
320-105410-1
320-105410-3
150
95
1.58
P11 Sampling 9/23
STW-LOC-4-4-092323
23-Sep-23
320-105410-1
320-105410-4
78
50
1.56
PH Sampling 9/23
STW-LOC-5-4-092323
23-Sep-23
320-105410-1
320-105410-5
37
24
1.54
PH Sampling 9/23
STW-LOC-7A-080423
25-Sep-23
320-105410-1
320-105410-6
290
210
1.38
Pll Sampling 9/23
STW-LOC-7B-4-092223
22-Sep-23
320-105410-1
320-105410-7
310
200
1.55
Pll Sampling 9/23
STW-LOC-7114-092323-13
22-Sep-23
320-105410-1
320-105410-8
320
210
1.52
P I I Sampling 9/23
STW-LOC-7C-4-092223
22-Sep-23
320-105410-1
320-105410-9
340
230
1.48
P I I Sampling 9/23
STW-LOC-8-4-092523
25-Sep-23
320-105406-1
320-105406-1
1,600
970
1.65
PH Sampling 9/23
STW-LOC-9-4-092223
22-Sep-23
320-105437-1
1 320-105437-1
920
650
1.42
P I I Sampling 9/23
STW-LOC-9A-092523
25-Sep-23
320-105406-1
320-105406-7
510
330
1.55
P I I Sampling 9/23
STW-LOC-EB-DR-092523
25-Sep-23
320-105437-1
320-105437-12
<5
<5
PH Sampling 9/23
STW-LOC-EB-IS-092223
22-Sep-23
320-105437-1
320-105437-10
<5
<5
P I I Sampling 9/23
STW-LOC-EB-IS-092523
25-Sep-23
320-105437-1
320-105437-11
<5
<5
P I I Sampling 9/23
STW-LOC-FB-092223
22-Sep-23
320-105437-1
320-105437-8
<5
<5
PH Sampling 9/23
STW-LOC-FB-092523
25-Sep-23
320-105437-1
320-105437-9
<5
<5
Tarheel Sampling
CFR-TARHEEL-121823
18-Dec-23
320-108237-1
320-108237-2
37 J
24 J
1.54
Tarheel Sampling
CFR-TARHEEL-121923
19-Dec-23
320-108237-1
1 320-108237-3
<5
<5
Tarheel Sampling
CFR-TARHEEL-24-100523
05-Oct-23
320-105969-1
320-105969-1
40
26
1.54
Tarheel Sampling
CFR-TARHEEL-24-101023
10-Oct-23
320-105969-1
320-105969-2
40
26
1.54
Tarheel Sampling
CFR-TARHEEL-24-101023-D
10-Oct-23
320-105969-1
320-105969-3
40
27
1.48
Tarheel Sampling
CFR-TARHEEL-24-101223
12-Oct-23
320-106157-1
320-106157-1
38
25
1.52
Tarheel Sampling
CFR-TARHEEL-24-101623
16-Oct-23
320-106157-1
320-106157-2
55
36
1.53
Tarheel Sampling
CFR-TARHEEL-24-101923
19-Oct-23
320-106379-1
320-106379-1
42
26
1.62
Tarheel Sampling
CFR-TARHEEL-24-102323
23-Oct-23
320-106379-1
320-106379-2
41
26
1.58
Tarheel Sampling
CFR-TARHEEL-24-102623
26-Oct-23
320-106734-1
1 320-106734-1
26
17
1.53
Tarheel Sampling
CFR-TARHEEL-24-103023
30-Oct-23
320-106734-1
320-106734-2
29J
191
1.53
Tarheel Sampling
CFR-TARHEEL-24-110223
02-Nov-23
320-106957-1
320-106957-1
55
34
1.62
Tarheel Sampling
CFR-TARHEEL-24-110623
06-Nov-23
320-106957-1
320-106957-2
35
23
1.52
Tarheel Sampling
CFR-TARHEEL-24-110923
09-Nov-23
320-107164-1
320-107164-1
37
24
1.54
TarheelSampling
CFR-TARHEEL-24-111323
13-Nov-23
320-107164-1
320-107164-2
40
27
1.48
Tarheel Sampling
CFR-TARHEEL-24-111323-D
13-Nov-23
320-107164-1
320-107164-3
41
27
1.52
Tarheel Sampling
CFR-TARHEEL-24-111623
16-Nov-23
320-107540-1
320-107540-1
45
30
1.50
Tarheel Sampling
CFR-TARIIEEL-24-112023
20-Nov-23
320-107540-1
1 320-107540-2
65
44
1.48
Tarheel Sampling
CFR-TARIIEEL-24-112123
21-Nov-23
320-107540-1
320-107540-3
47
31
1.52
Tarheel Sampling
CFR-TARHEEL-24-112223
22-Nov-23
320-107540-1
320-107540-4
41
27
1.52
TarheelSampling
CFR-TARHEEL-24-112723
27-Nov-23
320-107657-1
320-107657-1
52 J
33 J
1.58
Tarheel Sampling
CFR-TARHEEL-24-113023
30-Nov-23
320-107657-1
320-107657-2
50 J
32 J
1.56
Tarheel Sampling
CFR-TARHEEL-24-120423
04-Dec-23
320-107894-1
320-107894-1
50
31
1.61
Tarheel Sampling
CFR-TARHEEL-24-120723
07-Dec-23
320-107894-1
320-107894-2
46
29
1.59
Tarheel Sampling
CFR-TARHEEL-24-121123
II-Dec-23
320-108044-1
320-108044-1
41
26
1.58
Tarheel Sampling
CFR-TARHEEL-24-121223
12-Dec-23
320-108044-1
1 320-108044-2
38
24
1.58
Tarheel Sampling
CFR-TARHEEL-24-121223-D
12-Dec-23
320-108044-1
320-108044-3
47
30
1.57
Tarheel Sampling
CFR-TARHEEL-24-121723
17-Dec-23
320-108237-1
320-108237-1
24J
15J
1.60
TazheelSam lin
CFR-TARHEEL-24-122523
25-Dec-23
320-108425-1
320-108425-1
15
9.8
1.53
Tarheel Sam lin
CFR-TARHEEL-24-122723
27-Dec-23
320-108425-1
320-108425-2
17
11
1.55
Notes:
* - PFPrA concentrations were revised following the discovery of a calculation error by the analytical laboratory
-- - revised and/or original concentration is non -detect; factor not calculated
B - analyte detected in associated method blank
J - analyte detected; reported value may not be accurate or precise
ng/L - nanograms per liter
PFPrA - perfluoropropanoic acid
UJ - analyte not detected; reporting limit may not be accurate or precise
< - analyte not detected above associated reporting limit
Minimum factor = 0.81
Average factor = 1.57
Ma imam factor 2.86
Standard deviation = 0.14
Page 5 of 5 June 2024
IIII II IIII INIIIIII III III
3780325
ID: ProplonicAcd_00004
Eq).W1729 Prpd: Opn:0411824
PENTAFLUOROPROPIONIC ACID
3050 Spruce Street, Saint Louis, MO 63103, USA
Website: www.sigmaaldrich.com
Email USA: techserv@sial.com
Outside USA: eurtechserv@sial.com
Product Name: Certificate of Analysis
Pentaffuoroprop(onic acid - 97%
Product Number:
245917
Batch Number:
MKCV1747
Brand:
ALDRICH
CAS Number:
422-64-0
MDL Number:
MFCD00004170
Formula:
C3 HF5O2
Formula Weight:
164.03 g/mol
Quality Release Date:
06 OCT 2023
Test
Appearance (Color)
Appearance (Form)
Infrared Spectrum
Titration with NaOH
GC (area %)
Larry Coers, Director
Quality Control
Milwaukee, WI US
0
F3C OH
F F
Specification Result
Colorless to Faint Yellow and Colorless
Colorless to Faint Orange
Liquid Liquid
Conforms to Structure Conforms
96.5-103.5% 99.7%
> 96.5 % 100.0 %
Sigma -Aldrich warrants, that at the time of the quality release or subsequent retest date this product conformed to the information
contained in this publication. The current Specification sheet may be available at Sigma-Aldrich.com. For further inquiries, please contact
Technical Service. Purchaser must determine the suitability of the product for its particular use. See reverse side of invoice or packing
slip for additional terms and conditions of sale.
Version Number: 1 Page 1 of 1
tiff eurofins
May 22, 2024
Environment Testing
TestAmerica
The Chemours Company
1007 Market Street
Wilmington, DE 19801
Attn: Michael Aucoin, Corporate Remediation Group
RE: Investigation and Corrective Action for PFPrA Error
Dear Mr. Aucoin,
It is the policy of Eurofins Sacramento to conduct its business with honesty and integrity, to
produce accurate and useable environmental analytical test results and related services, and to
provide the best possible service to our clients. As such, we routinely conduct internal data
reviews to assess our adherence to method requirements and Quality Assurance protocols. If
any issues are noted during these reviews that impact the quality of data, we will notify affected
clients and correct the issue.
Eurofins Sacramento recently identified a calculation error that was incorporated into the
preparation of calibration standards for target analyte Perfluoropropanoic Acid (PFPrA) under
the laboratory's 537M methodology. The calculation error yielded an assigned concentration for
calibration standards that was 36% lower than the actual concentration of PFPrA. Use of these
standards to quantitate PFPrA in client samples (including Chemours) has imparted a low bias
of the same magnitude to results for this analyte reported between May, 2023 and April, 2024.
Root Cause Analysis -
The laboratory conducted a root cause investigation and determined that the incorrect
concentration of PFPrA was assigned to calibration standards when the standards preparation
chemist did not incorporate the density of the pure liquid PFPrA source material (1.56 g/ml) into
the calculated concentration of the initial intermediate dilution prepared from this neat material.
The incorrect assigned concentration for the initial dilution of the PFPrA source material was
then propagated into all `daughter' solutions prepared from the initial dilution, including
calibration solutions.
The laboratory further concluded that the primary root cause of the lapse was insufficient
training of the standards preparation chemist regarding correct preparation of calibration
solutions from neat materials.
Corrective Actions -
The laboratory's standards preparation SOP has been updated to specifically emphasize
density corrections when preparing intermediate solutions volumetrically from neat source
materials, and all standards preparation chemists have been re-trained regarding the content of
the updated SOP.
Eurofins TestAmerica 880 Riverside Parkway T 1 916-373-5600
West Sacramento, CA 95605 www.TestAmericalne.com
Additionally, the laboratory has secured commercially prepared/vendor-certified solutions of
PFPrA for use in the preparation of calibration standards and fortification solutions. Use of the
commercial solutions with certified concentrations of PFPrA will preclude the need to dilute neat
liquid reference materials in the future, and associated corrections for density will no longer be
required. Vendor -certified solutions of PFPrA are now available from several commercial
suppliers, which will facilitate the use of these solutions to provide independent `second -source'
verification of calibration standards.
Eurofins Sacramento prides itself on supplying its clients with reliable quality data, and we have
applied the utmost diligence to our root cause investigation and corrective actions. We are
confident the corrective actions described above and summarized below will prevent recurrence
of any similar error. In summary, these corrective actions include the following:
1) Updated standards preparation SOP emphasizing correct use of density in standards
preparation.
2) Additional training of standards preparation chemists.
3) Use of vendor -certified solutions as the primary source for calibration standards in lieu of
neat liquid PFPrA source materials.
4) Use of second -source vendor -certified solutions (alternate supplier) to verify primary
standards.
Please do not hesitate to contact us if you have additional questions.
Sincerely,
Eric Redman
VP of Technical Services
Eurofins Environment Testing Northern California
Cc: Lam Leung (Chemours)
Sathya Yalvigi (Chemours)
Kevin Garon (Chemours)