1117_Buncombe_GARAA_Q2_2024_GWMR_FID_2024067

DENR USE ONLY []Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #:
NC DENR I I Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are 'Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
• Prepare one form for each individually monitored unit.
• Please type or print legibly.
• Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition,
etc.).
• Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
• Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
• Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
SynTerra Corporation (Consultant)
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Craig D. Eady Phone: [phone]
E-mail: ceady(a)svnterracoro.com
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Duke Energy Progress Greater
Asheville Regional Airport 61 Terminal Drive #1 L
7-STRUC-2020 .0500 April 1-2, 2024
Authority Fletcher, North Carolina
Structural Fills — Areas 1, 3,& 4
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring ❑X Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells ❑
Leachate monitoring data
Surface water monitoring data ❑
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
Notification attached?
® No. No groundwater or surface water standards were exceeded.
Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Craig D. Eady
Senior Geologist
Facility Replisentative N e (Print) Title
Signature r
148 River Street, Suite 220, Greenville, SC't9601
Facility Representative Address
C-1478 / North Carolina Geological Corporation Number C-387
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009
6/3/2024
Date
[phone]
(Area Code) Telephone Numbcr
Affix NC Licensed/ Professional Geologist Seal
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REPORT VERIFICATION
PROJECT: QUARTERLY WATER QUALITY MONITORING REPORT
APRIL 2024 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
STRUCTURAL FILL —AREAS 1, 3, & 4
PERMIT NO. 1117-STRUC-2020
TITLE: QUARTERLY WATER QUALITY MONITORING REPORT
This document has been reviewed for accuracy and quality commensurate with the intended
application.
Prepared by: Date
1
Approved by: Date
Project Geologist: Craig D. Eady, NC L.G. #1599
6/3/2024
6/3/2024
Licensed Geologist Seal:
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SynTerra
148 River Street, Suite 220
Greenville, SC 29601
North Carolina Geological Corporation Number C-387

Science & Engineering Consultants
synterracorp.com
QUARTERLY WATER QUALITY
MONITORING REPORT
APRIL 2024 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
STRUCTURAL FILL —AREAS 1, 3, AND 4
PERMIT NO. 1117-STRUC-2020
61 TERMINAL DRIVE #1
FLETCHER, NORTH CAROLINA
JUNE 2024
PREPARED FOR
DUKE
ENERGY
PROGRESS
DUKE ENERGY PROGRESS, LLC
Kathryn W. Webb
Kelly Ferri
Senior Peer Review CAR ��,
Project Manager
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Craig D. Eady, NC L.G. 1599
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Senior Geologist

Quarterly Water Quality Monitoring Report — April 2024 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
TABLE OF CONTENTS
SECTION PAGE
1.0 BACKGROUND............................................................................................................1-1
2.0 MONITORING NETWORK............................................................................................ 2-1
2.1 Groundwater..............................................................................................................2-1
2.2 Surface Water............................................................................................................2-2
2.3 Fill Material Water.....................................................................................................2-2
3.0 SAMPLING ANALYSIS AND METHODS......................................................................... 3-1
3.1 Groundwater..............................................................................................................3-1
3.2 Surface Water............................................................................................................3-1
4.0 STATEMENT OF WORK............................................................................................... 4-1
5.0 AREA 1 RESULTS......................................................................................................... 5-1
5.1 Groundwater Flow.....................................................................................................5-1
5.2 Groundwater Analytical Results.................................................................................5-1
5.3 Surface Water Analytical Results................................................................................5-1
5.4 Piezometer Water Levels............................................................................................5-3
6.0 AREA 3 RESULTS......................................................................................................... 6-1
6.1 Groundwater Flow.....................................................................................................6-1
6.2 Groundwater Analytical Results.................................................................................6-1
7.0 AREA 4 RESULTS......................................................................................................... 7-1
7.1 Groundwater Flow.....................................................................................................7-1
7.2 Groundwater Analytical Results.................................................................................7-1
8.0 REFERENCES...............................................................................................................8-1
June 2024
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Quarterly Water Quality Monitoring Report — April 2024 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
LIST OF FIGURES
Figure 1
USGS Site Location Map
Figure 2
Groundwater Sample Location Map (Structural Fill Areas 1, 3, and 4)
Figure 3
Surface Water Sample Location Map (Structural Fill Area 1)
Figure 4
Piezometer Location Map (Structural Fill Area 1)
Figure 5
Groundwater Contour Map (Structural Fill Area 1)
Figure 6
Groundwater Contour Map (Structural Fill Area 3)
Figure 7
Groundwater Contour Map (Structural Fill Area 4)
LIST OF TABLES
Table 1
Monitoring Well Construction Information — Structural Fill Areas 1, 3, and 4
Table 2
Groundwater Elevation — Structural Fill Areas 1, 3, and 4
Table 3
Groundwater Flow Velocities — Structural Fill Areas 1, 3, and 4
Table 4
Groundwater Field and Analytical Results — Structural Fill Areas 1, 3, and 4
Table 5
Field and Analytical Results Greater than or Equal to Groundwater Quality
Standards — Structural Fill Area 1, 3, 4
Table 6
Surface Water Field and Analytical Results — Structural Fill Area 1
Table 7
Field and Analytical Results Greater than or Equal to Surface Water Quality
Standards — Structural Fill Area 1
Table 8
Piezometer Water Levels — Structural Fill Area 1
LIST OF APPENDICES
Appendix A
Groundwater Sampling Logs
Appendix B
Groundwater Laboratory Analytical Reports
Appendix C
Surface Water Sampling Logs
Appendix D
Surface Water Laboratory Analytical Reports
June 2024
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Quarterly Water Quality Monitoring Report — April 2024 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
LIST OF ACRONYMS AND ABBREVIATIONS
02B standard Title 15A NCAC 02B .0200, Surface Water and Wetland Standards
02L standard Title 15A NCAC 02L .0202(g), Groundwater Quality Standards
CCP
coal combustion products
CCR
coal combustion residuals
Duke Energy
Duke Energy Progress, LLC
DWM
Division of Waste Management
EDD
electronic data deliverable
GARAA
Greater Asheville Regional Airport Authority
ISTV
in -stream target value
mg/L
milligrams per liter
NCAC
North Carolina Administrative Code
NCDEQ
North Carolina Department of Environmental Quality
NOAA
National Oceanic and Atmospheric Administration
NRWQC
National Recommended Water Quality Criteria
ORP
oxidation-reduction potential
Q2
second quarter
Q4
fourth quarter
Site
Greater Asheville Regional Airport Authority
SM
Standard Method
SW
Solid Waste
SWS
Solid Waste Section
TDS
total dissolved solids
TOC
total organic carbon
TSS
total suspended solids
USEPA
U.S. Environmental Protection Agency
WQMR
Water Quality Monitoring Report
WQMRP
Water Quality Monitoring and Reporting Plan
June 2024
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Quarterly Water Quality Monitoring Report — April 2024 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
1.0 BACKGROUND
This Quarterly Water Quality Monitoring Report (WQMR), prepared to satisfy the reporting
requirements of permit No. 1117-STRUC-2020, summarizes the April 2024 groundwater and
surface water quality sampling activities and results at the Greater Asheville Regional Airport
Authority (GARAA or Site). The Site is located in Fletcher, Buncombe County, North Carolina,
approximately 13 miles south of Asheville, North Carolina (Figure 1). Three separate structural
fill areas (Areas 1, 3, and 4) were constructed at the Site from the beneficial reuse of coal
combustion products (CCP) material. That material was sourced from the nearby Asheville
Steam Electric Plant, owned and operated by Duke Energy Progress, LLC (Duke Energy).
Groundwater monitoring results from the April 2024 sampling event show that groundwater
constituents greater than comparison criteria are within background concentration ranges
except for one monitoring well (MW-8-Al) in Area 1 and one monitoring well (MW-7-A4) in
Area 4. Area 1 surface water monitoring results from the April 2024 sampling event show that
surface water constituents greater than comparison criteria are within the range of background
concentrations for surface water.
The Water Quality Monitoring and Reporting Plan — Structural Fill Areas 1, 3, & 4 (WQMRP)
(SynTerra, 2020) pertaining to the structural fill areas was submitted to the North Carolina
Department of Environmental Quality (NCDEQ) Division of Waste Management (DWM) Solid
Waste Section (SWS) in December 2020. The WQMRP established procedures for monitoring
groundwater in the surficial flow zone (saprolite and partially weathered rock) beneath Areas 1,
3, and 4 and surface waters adjacent to Area 1 during operational and post -closure periods.
Such procedures are established to satisfy requirements in Title 15A of the North Carolina
Administrative Code (NCAC) 13B .0504(1)(g)(iv). Subsequent to approval of the WQMRP,
NCDEQ DWM SWS issued water quality monitoring and reporting permit number 1117-STRUC-
2020 on December 14, 2020.
June 2024
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Quarterly Water Quality Monitoring Report — April 2024 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
t.0 MONITORING NETWORK
2.1 Groundwater
Monitoring well locations of the three structural fill areas are provided on Figure 2, and
monitoring well construction details are presented in Table 1. Boring logs and well
abandonment records are included in the WQMRP and have been provided to NCDEQ DWM
SWS. A brief description of the monitoring network for each structural fill area is provided
below:
Area 1
The existing groundwater quality monitoring network for Area 1 consists of two background
wells and six review boundary wells (Figure 2). Four of the monitoring wells (MW-1A-A1,
MW-2A-Al, MW-4A-Al, and MW-5-Al) were installed in 2009. The remaining four
monitoring wells (MW-6-Al, MW-7-Al, MW-8-Al, and MW-9-Al) were installed in 2018.
Wells MW-4A-A1 and MW-9-Al, located upgradient of Area 1, serve as background wells.
The remaining wells were installed either side -gradient or downgradient from Area 1 at the
approximate review boundary (Figure 2). One additional well (MW-1-Al) located north and
downgradient of Area 1 beyond the review boundary is designated to be used only for
water -level measurements, as per the WQMRP.
Construction to upgrade the Area 1 cover system with a geomembrane liner began in June
2022 and was completed in May 2023. In August 2022, monitoring well MW-2A-A1 was
abandoned to support construction for the Area 1 cover project; a replacement well
(MW-2B-Al) was installed in October 2022. The well abandonment record for MW-2A-A1
was included in the Q3 2022 WQMR, submitted in October 2022. A well construction record
for MW-2B-A1 was included in the Q4 2022 WQMR, submitted in March 2023. A boring log
for MW-2B-A1 will be included in the WQMRP update, anticipated to be completed in 2024.
Area 3
The existing groundwater monitoring well network for Area 3 consists of seven
downgradient review boundary wells (MW-1-A3, MW-2-A3, MW-3-A3, MW-4-A3,
MW-5-A3, MW-6-A3, and MW-7-A3) (Figure 2). The monitoring wells were installed in
December 2013.
Area 4
The existing groundwater monitoring well network for Area 4 consists of one background
well and six downgradient review boundary wells (Figure 2). Wells MW-2-A4 and MW-5-A4
were installed in 2009, wells MW-6-A4 and MW-7-A4 were installed in 2010, and wells
MW-1A-A4, MW-5D-A4, and MW-9-A4 were installed in 2012. The top of casing for well
MW-9-A4 was extended vertically in September 2014 to accommodate final surface grade
of the GARAA taxiway project. Well MW-1A-A4 was initially installed upgradient of Area 4 as
a background well but was abandoned because of the taxiway project. Replacement
June 2024
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Quarterly Water Quality Monitoring Report — April 2024 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
background well MW-IAR-A4 was installed in September 2015 (Figure 2). MW-1A-A4 was
properly abandoned in October 2015.
A new Area 4 background well (MW-IAR-A4R) was installed in June 2022 and MW-IAR-A4
was abandoned in August 2022, in preparation for a new airport control tower project. The
new background well (MW-IAR-A4R) was installed and screened within the same flow zone.
Construction details for background monitoring well MW-IAR-A4R are presented in Table 1,
and the location of the well is shown on Figure 2. The well abandonment record for
MW-IAR-A4 and the well construction record for MW-AIR-A4R were included in the Q3
WQMR 2022, submitted in October 2022. A boring log for MW-IAR-A4R will be included in
the WQMRP update, anticipated to be completed in 2024.
2.2 Surface Water
The eight surface water sample locations designated for Area 1 at the time the WQMRP was
submitted include SW-2-Al, SW-3-Al, SW-46-Al, SW-4C-Al, SW-5-Al, SW-6-Al, SW-8-Al, and
SW-9-Al (Figure 3). SW-2-Al, located near the southern portion of Area 1, serves as a
background surface water monitoring location. SW-3-Al, located north of Area 1, is the farthest
downgradient surface water sample location and receives flow from the remaining Area 1
surface water locations prior to migrating off -Site.
A Site walk with NCDEQ occurred on September 22, 2023, to identify the remaining surface
water sample locations still present after the Area 1 cover project was completed. Surface
water sample locations SW-6-Al and SW-8-Al were destroyed because of construction
activities. A new sample location (SW-10-Al) was identified and will be sampled to represent
surface water quality at SW-413-Al and SW-4C-AI. Surface water locations SW-413-Al and
SW-4C-Al will be observed during quarterly sampling events. Any changes observed would be
noted in quarterly WQMRs.
2.3 Fill Material Water
A total of nine piezometers were installed in Area 1; six are used to monitor pore water within
the fill material, two were installed beneath the geosynthetic clay liner (PZ-2 and PZ-31D)
(Figure 4) to monitor groundwater levels, and one (PZ-7) was installed outside the CCP limits in
the soil -only corridor. Six piezometers (PZ-1, PZ-2, PZ-3, PZ-4, PZ-5, and PZ-6) were installed in
November 2017, and three piezometers (PZ-2S, PZ-31D, and PZ-7) were installed in August 2018.
Those piezometers are designated to be used only for water -level measurements, as per the
WQMRP.
June 2024
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Quarterly Water Quality Monitoring Report — April 2024 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
3.0 SAMPLING ANALYSIS AND METHODS
3.1 Groundwater
Duke Energy personnel performed sampling in accordance with the WQMRP and NCDEQ DWM
SWS guidelines. Field parameters [i.e., pH, temperature, dissolved oxygen, specific
conductance, oxidation-reduction potential (ORP), and turbidity] were measured and recorded
prior to collection of groundwater samples. Groundwater samples were collected on April 1-2,
2024. Copies of groundwater field sampling logs are included in Appendix A.
The parameters and constituents reported were defined by the NCDEQ DWM SWS, listed within
the WQMRP, and analyzed by Duke Energy Analytical Laboratory (North Carolina Laboratory
Certification #248). Groundwater analytical laboratory reports and chain -of -custody forms are
included in Appendix B.
Groundwater samples were analyzed for the following constituents:
• Aluminum, barium, boron, calcium, copper, iron, magnesium, manganese, potassium,
sodium, strontium, and zinc using U.S. Environmental Protection Agency (USEPA) Solid
Waste (SW) Method 6010D
• Antimony, arsenic, beryllium, cadmium, chromium, cobalt, lead, molybdenum, nickel,
selenium, thallium, and vanadium using USEPA SW Method 6020B
• Chloride and sulfate using USEPA Method 9056A
• Mercury using USEPA Method 7470A
• Alkalinity, bicarbonate, and carbonate using Standard Method (SM) 2320B
• Total dissolved solids (TDS) using SM 2540C and total suspended solids (TSS) using
SM 2540D
3.2 Surface Water
Surface water sampling of Area 1 was conducted in accordance with the Internal Technical
Guidance: Evaluating Impact to Surface Water from Discharging Groundwater Plumes (NCDEQ,
2017). Surface water samples were collected during the second quarter (Q2) of 2024 at
locations with sufficient flow to sample. Samples were collected as single -grab samples on April
1, 2024. Surface water downgradient of Area 1 flows northward toward the French Broad River
and is not classified. The French Broad River has a Class B surface water classification in the
vicinity of the Site. Therefore, analytical results for surface water collected at Area 1 are
compared with applicable Class B 02B standards.
June 2024
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Quarterly Water Quality Monitoring Report — April 2024 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
Surface water samples were collected at each location during low or base flow conditions.
According to review of the U.S. Department of Commerce National Oceanic and Atmospheric
Administration (NOAA) record of climatological observations for the Asheville Airport Weather
Station (USW00003812), the last significant recorded precipitation event prior to the April 1,
2024, sampling event was recorded on March 26, 2024, at 0.56 inches. Surface water samples
were not collected from locations where dry or stagnant conditions, insufficient flow, or other
observed conditions that would preclude the ability to collect a valid, representative sample
were encountered. Field parameters [i.e., pH, temperature, dissolved oxygen, specific
conductance, ORP, and turbidity] were measured and recorded prior to collection of surface
water samples. Copies of surface water field sampling logs are included in Appendix C.
Surface water sample location SW-5-Al was not sampled during the April 2024 sampling event
because of dry conditions. Surface water sample locations SW-6-Al and SW-8-Al were
destroyed because of construction activities for the Area 1 cover project and were not sampled
during the April 2024 sampling event.
Duke Energy Analytical Laboratory (North Carolina Laboratory Certification #248) analyzed
surface water samples for total and dissolved phase metals, alkalinity, chloride, sulfate, cations,
anions, and other parameters, including TDS, total organic carbon (TOC), and TSS. Surface water
analytical laboratory reports, including analytical methods and constituent detection limits, and
chain -of -custody forms are provided in Appendix D.
June 2024 Page 3-2
Project: 00.0059.53.02

Quarterly Water Quality Monitoring Report — April 2024 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
4.0 STATEMENT OF WORK
The following tasks occurred during the second quarter (Q2) of 2024:
• Duke Energy personnel collected semiannual groundwater samples from Areas 1, 3, and
4 on April 1-2, 2024.
• Duke Energy personnel collected quarterly surface water samples from Area 1 on
April 1, 2024.
• Duke Energy personnel measured depth -to -groundwater in each monitoring well during
the April 2024 semiannual groundwater sampling events. Depth -to -water
measurements in monitoring wells were collected prior to purging and sample
collection.
• SynTerra personnel measured depth -to -water in each piezometer in Area 1 on
April 18, 2024.
• SynTerra personnel reviewed laboratory groundwater and surface water analytical
results for samples listed above.
• SynTerra personnel developed generalized groundwater surface contour maps using
groundwater elevation data supplied by Duke Energy.
• SynTerra personnel reviewed the laboratory analytical results pertaining to the
parameters listed in the WQMRP. The electronic data deliverable (EDD) provided by
Duke Energy was adapted to conform to the format requirements of the NCDEQ EQUIS
EDD template.
• SynTerra personnel prepared and submitted this Quarterly Water Quality Monitoring
Report to Duke Energy.
June 2024
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Quarterly Water Quality Monitoring Report — April 2024 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
5.0 AREA 1 RESULTS
5.1 Groundwater Flow
Generalized groundwater elevation contours and groundwater flow direction arrows pertaining
to Area 1 are shown on Figure S. Those contours were developed by calculating groundwater
elevations in each well using the depth -to -water -level measurements taken during the April
2024 quarterly sampling event (Table 2). Calculated groundwater flow rates for Area 1 based on
April 2024 groundwater elevations are included in Table 3. Groundwater flow at Area 1 is
generally north—northwest, consistent with topographical features and similar to historical
observations.
5.2 Groundwater Analytical Results
A summary of the groundwater field parameters and analytical results from the Area 1 April
2024 quarterly groundwater monitoring event is presented in Table 4. The analytical results for
those samples are compared with the groundwater standards established in Title 15A NCAC 02L
.0202(g), Groundwater Quality Standards (02L standards). Concentrations equal to or greater
than the 02L standard are noted in Table 4 in bold font. A summary of the groundwater field
and analytical results equal to or greater than the 02L standard and a preliminary analysis of
the cause and significance of those concentrations are presented in Table 5.
Review of April 2024 analytical results for Area 1 downgradient monitoring wells indicates
several constituents were detected at concentrations greater than (or less than for pH) 02L
standards. Those constituents and sampling locations include:
• Cobalt— MW-6-Al and MW-8-Al
• Iron — MW-6-Al
• Manganese — MW-5-Al and MW-8-Al
• pH — MW-1A-A1, MW-213-A1, MW-5-Al, MW-6-Al, MW-7-Al, and MW-8-Al
The constituents listed above are within the background data set range for the Site, except for
pH in MW-8-Al. MW-8-Al is generally side -gradient of Area 1, and the most mobile constituent
indicative of coal combustion residuals (CCR), boron, was not detected. Therefore, it is unlikely
that the pH level represents a release from the structural fill.
5.3 Surface Water Analytical Results
A summary of the surface water field parameters and analytical results (total and dissolved)
from the April 2024 quarterly surface water sampling event is presented in Table 6. Surface
water samples are compared to applicable 02B standards, in -stream target values, and USEPA
National Recommended Water Quality Criteria (NRWQC) for Aquatic Life and Human Health.
Duke Energy provides comparisons against in -stream target values with the qualification that
constituent concentrations greater than the published value are not necessarily a violation of
the water quality standard for toxicity. As stated by the USEPA, NRWQC standards do not
June 2024
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Quarterly Water Quality Monitoring Report — April 2024 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
constitute regulations or impose a legally binding requirement. Therefore, comparisons with
those criteria are for information purposes only. An in -stream hardness of 25 milligrams per
liter (mg/L) is assumed for hardness -dependent metal standards and provided for screening
purposes only.
Surface water samples were collected using the grab sample method and compared to
applicable 02B standards. Several 02B standards require sampling methods specific to acute or
chronic concentrations and are not applicable to the grab sample method. Chronic standards
are included for screening purposes only. Hardness -dependent standards require sampling
methods specific to acute or chronic concentrations and are not applicable to the grab sample
method. The surface water standards used for comparison and screening purposes will be
updated in the updated WQMRP anticipated to be completed in 2024. Updated comparison
criteria will include 02B standards, in -stream target values, and USEPA National Recommended
Water Quality Criteria (NRWQC) for Aquatic Life and Human Health.
A summary of surface water field and analytical results equal to or greater than the 02B
standard and a preliminary analysis of the cause and significance of the exceedances is
presented in Table 7. Evaluation of the Area 1 surface water analytical results indicate
constituent concentrations are within applicable 02B standards for Class B surface waters,
except for the constituents listed below:
• pH — SW-413-A1, SW-9-Al, and SW-10-Al
The pH levels in sample locations identified above are within the range of background surface
water concentrations during the April 2024 sampling event. No other constituents were
detected at concentrations greater than applicable 02B standards for Class B surface waters.
It is important to note that several constituents were identified at concentrations greater than
the screening value [in -stream target value (ISTV) or NRWQC] in background surface water
sample location SW-2-Al located upgradient of Area 1, indicating natural variation or a
potential other source of constituents to surface water. The constituents are identified below:
• Cobalt
• Dissolved copper
• Iron
• Manganese
• Dissolved nickel
• Dissolved zinc
June 2024
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Project: 00.0059.53.02

Quarterly Water Quality Monitoring Report — April 2024 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
As a result of elevated concentrations in background surface water location SW-2-Al, several
downgradient sample locations (SW-3-Al, SW-413-A1, and SW-9-Al) have those same
constituents at concentrations greater than screening values.
5.4 Piezometer Water Levels
Water -level data were collected from the nine piezometers (PZ-1, PZ-2/2S, PZ-3/31D, PZ-4, PZ-5,
PZ-6, and PZ-7) in Area 1 (Figure 4) on April 18, 2024. Depth -to -water -level measurements are
presented in Table 8.
June 2024
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Project: 00.0059.53.02

Quarterly Water Quality Monitoring Report — April 2024 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
6.0 AREA 3 RESULTS
6.1 Groundwater Flow
Generalized groundwater elevation contours and groundwater flow direction arrows pertaining
to Area 3 are shown on Figure 6. Those contours were developed by calculating groundwater
elevations in each well using the depth -to -water -level measurements taken during the April
2024 quarterly sampling event (Table 2). Calculated groundwater flow rates for Area 3 based on
April 2024 groundwater elevations are included in Table 3. Groundwater flow at Area 3 is
generally northwestward, consistent with topographical features, and similar to historical
observations.
6.2 Groundwater Analytical Results
A summary of the groundwater field parameters and analytical results from the Area 3 April
2024 quarterly groundwater monitoring event is presented in Table 4. The analytical results for
those samples are compared with 02L standards. Concentrations equal to or greater than the
02L standard are noted in Table 4 in bold font. A summary of the groundwater field and
analytical results equal to or greater than the 02L standard and a preliminary analysis of the
cause and significance of those concentrations are presented in Table 5.
Review of the April 2024 analytical results for Area 3 downgradient monitoring wells indicates
several constituents were detected at concentrations greater than (or less than for pH) 02L
standards. Those constituents and sampling locations include:
• Cobalt — MW-1-A3
• Iron — MW-1-A3 and MW-3-A3
• Manganese— MW-1-A3
• pH — MW-1-A3, MW-2-A3, MW-3-A3, MW-4-A3, MW-5-A3, MW-6-A3, and MW-7-A3
Upon further review, the constituents listed above are within the background data set range for
the Site.
June 2024
Page 6-1
Project: 00.0059.53.02

Quarterly Water Quality Monitoring Report — April 2024 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
7.0 AREA 4 RESULTS
7.1 Groundwater Flow
Generalized groundwater elevation contours and groundwater flow direction arrows pertaining
to Area 4 are shown on Figure 7. Those contours were developed by calculating groundwater
elevations in each well using the depth -to -water -level measurements taken during the April
2024 quarterly sampling event (Table 2). Calculated groundwater flow rates for Area 4 based on
groundwater elevations from the April 2024 sampling event are included in Table 3.
Groundwater flow at Area 4 is generally southwestward, consistent with topographical
features, and similar to historical observations.
7.2 Groundwater Analytical Results
A summary of the groundwater field parameters and analytical results from the Area 4 April
2024 quarterly groundwater monitoring event is presented in Table 4. The analytical results for
those samples are compared with 02L standards. Concentrations equal to or greater than the
02L standard are noted in Table 4 by bold font. A summary of the groundwater field and
analytical results equal to or greater than the 02L standard and a preliminary analysis of the
cause and significance of those concentrations are presented in Table 5.
Review of the April 2024 analytical results from Area 4 downgradient monitoring wells indicates
several constituents were detected at concentrations greater than (or less than for pH) 02L
standards. Those constituents and sampling locations include:
• Arsenic — MW-7-A4
• Cadmium — MW-7-A4
• Cobalt — MW-7-A4
• Manganese — MW-7-A4
• Nickel — MW-7-A4
• pH — MW-2-A4, MW-5-A4, MW-5D-A4, MW-6-A4, MW-7-A4, and MW-9-A4
• Sulfate — MW-7-A4
• TDS — MW-7-A4
Upon further review, the pH levels in the monitoring wells listed above are within the
background data set range for the Site (except for MW-7-A4). Constituents detected in MW-7-
A4 at concentrations greater than the 02L standard and the background data set range include
arsenic, cadmium, cobalt, manganese, nickel, sulfate, and TDS. However, boron, a mobile
constituent and lead indicator of potential CCR constituent migration, continues to be non -
detectable. Groundwater in MW-7-A4 will continue to be monitored.
June 2024
Page 7-1
Project: 00.0059.53.02

Quarterly Water Quality Monitoring Report — April 2024 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
8.0 REFERENCES
NCDEQ. (2017). Internal Technical Guidance: Evaluating Impact to Surface Water from
Discharging Groundwater Plume. N.C. Division of Water Resources. Raleigh, N.C.: N.C.
Department of Environmental Quality. Retrieved March 4, 2021, from
https://files.nc.gov/ncdeq/Sampl ing%20of%20SW%20for%2002L%20171031%20FI NAL_
O.pdf
SynTerra. (2020). Water Quality Monitoring and Reporting Plan — Structural Fill Areas 1, 3, & 4 -
Greater Asheville Regional Airport Authority. November 2020.
June 2024
Page 8-1
Project: 00.0059.53.02

Quarterly Water Quality Monitoring Report — April 2024 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
FIGURES
L7
symTerra
Science & Engineering Consultants

z
( p �
TPA
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r
o
FOVaJDERS ! ✓AY
mT
9
Z
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-_._. _.--- .--- ---- .------- __BUNCOMBE COUP_
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GREATER
ASHEVILLE REGIONAL
AIRPORT AUTHORITY
PROPERTY BOUNDARI
F ♦ A
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R
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PRODUCT LIMITS
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� \ � UNCµOMQE ��� � � • � ■ � � -
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NOTES:
1. ALL BOUNDARIES ARE APPROXIMATE.
2. USGS TOPOGRAPHIC MAP, OBTAINED FROM ESRI AND THE NATIONAL
MAP (TNM), LAST UPDATED JUNE 2023.
t� DUKE
FIGURE 1
USGS SITE LOCATION MAP
STRUCTURAL FILLAREAS 1T 3, AND 4
ENERGY
BUNCOMBE
COUNTY wNsrorvsaEM
QUARTERLY WATER QUALITY MONITORING REPORT
PROGRESS
APRIL 2024 SAMPLING EVENT
GREATER ASHEVILLE REGIONALAIRPORT AUTHORITY
FLETCHER, NORTH CAROLINA
ASkEV1LLE GHARCOTTE
DRAWN BY. C. WYATT DATE. 06/08/2022
GRAPHIC SCALE
REVISED BY L FOREMAN DATE. 05/23/2024
i o00 o L o00 2,00a
CHECKED BY. C. MCCLUSK EY DATE 0523/2024
FEET)
synTerra
APPROVED DY K. FERRI GATE 05/23/2024
WWW SVFItP.FFACOFCl Cn171
PROJECT MANAGER_ K-FERRI
(IN

LI JIM JO LN MW-2B Al pr 1R a y" r •.
MW-6-A3 MW t 1 r ce' ii
q ■ MW-5-A3 MW-6-A1 NIW-`A AI ,
c MW-lA-Al_
w AT VIew OR` MW-7-A1
DETENTION 1 `� MW-5-A1 i4
POND !� • • MW-8-A1 .
u, -4-A3 � i�
ffff ♦ �,
BRAN RICKLN ♦ MW-9-Al
NIVV-3-A3 ♦ „ a ♦� /
♦ ` MW-4A-Al a
ra
+,
MW-2-A3 I
� ��1! ■sue ��
♦ 4.. .` ��
c + ♦ MW-1-A3
1
LEGEND
0 BACKGROUND MONITORING WELL
REVIEW BOUNDARY MONITORING WELL , A`
•.- .-
MONITORING WELL -WATER LEVEL ONLY �
t E
WELLABANDONED♦
}. ; &
STRUCTURAL FILL AREA 1rs` '>,� : m4
STRUCTURAL FILL AREA 3
_J STRUCTURAL FILL AREA 4 iN-1ri444ft
MW-1AP-P
REVIEW BOUNDARY ,..4
■ COMPLIANCE BOUNDARY
•- - — COAL COMBUSTION PRODUCT LIMITS ` `•, PµN1NG floc �tU
O BOUNDARY (APPROXIMATE) ' •' — - PROPERTY B NDARY (A PR XIMATE) � ♦
SURFACE WATER FLOW DIRECTION ; ♦ ,. `,i+ n
i
ores: MW-2-A4 ♦ '„� ��; ,�,,,,
THE LOCATION OF WELL MW-26-Al IS APPROXIMATE. LOCATION OF , ♦' i.
(ELL MVV1 Al TAKEN FROM GEOSYNTEC DRAWING ♦ l m
INSTRUMENTATION AND MONITORING WELL LOCATIONS", MAY 2020). ♦ o {— tr -
THEIR WELL LOCATIONS, COAL COMBUSTION PRODUCTS LIMITS,-
EVIEW BOUNDARY AND COMPLIANCE BOUNDARY TAKEN FROM SBME M W-5D-A4 M W-5-A4 N m f
RAWING ('GROUNDWATER FLOW MAP STRUCTURAL FILL', DECEMBER o""'"�•T` i r' , tt
2, 2010).
-MONITORING WELL WAS ABANDONED IN AUGUST 2022 AND �! -� M W-6-A4
EPLACED WITH MW-2B-Al. � • _ �
^- MONITORING WELL WAS ABANDONED IN AUGUST 2022 AND ` y ♦+ Al
EPLACED WITH MW-IAR-A4R. - �.._ f, i
., - IIff
• M W-7-A4
GROUNDWATER FLOW MAP STRUCTURAL FILL", DECEMBER 12, 2010)
COAL COMBUSTION PRODUCTS LIMITS, REVIEW BOUNDARY AND • - '� , i ♦ s :� �^ P A'"' 'TF
OMPLIANCE BOUNDARY TAKEN FROM S&ME DRAWING
REAS 3 AND 4 BASED ON DRAWING BY FRANKLIN S. CRAIG, P.E. OF '�- ` ♦ is !
ASTONIA, NORTH CAROLINA ("AREA #4 -ALL PHASES ENGINEERED FILL -A ., '• -
ESIGN", SHEET E-1, JUNE 30, 2011). R.
ALL BOUNDARIES ARE APPROXIMATE. An ,MW-9-A4 - '
ILAERIAL IMAGERY OBTAINED FROM USGS VIA EARTH EXPLORER, • �• T DETENTION
O EPTEM 5 '� '• POND - -
LLECTED S BER 1 , 2022.
DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA�a - "x---
TATE PLANE COORDINATE SYSTEM FIPS 3200 (NAD83).
41 GRAPHIC SCALE
sso o sso 1.300 FIGURE 2
GROUNDWATER SAMPLE LOCATION MAP
symTerra (IN FEET) STRUCTURAL FILL AREAS 1, 3, AND 4
DRAWN BY. C. WYATT DATE: 06/08/2022 QUARTERLY WATER QUALITY MONITORING REPORT
DUKE REVI5EDBY. E.FOREMAN DATE:05/23/2024 APRIL 2024 SAMPLING EVENT
�
CHECKED BY. C.. FERRI KEY DATE. 05/23/2024 GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY ' ENERGY APPROVED BY. K. FERRI DATE.05/23/2024
PROJECT MANAGER. K. FERRI FLETCHER, NORTH CAROLINA
PROGRESS ........ -._. __-----.- _--

CONCRETE HEADWALL
2a
CULVERT
SW-5-Al
EXISTING WETLANDS
SW-10-A1 SW-4C-Al CONCRETE HEADWALL'- i
�M• 4 4�
SW-9-Al
♦ 1 1 �
♦ 15" RCP
4 4
1
4 1 1 4
It
4 �
1 �
4 1
1 1
4
1
41
r I �
LEGEND
O BACKGROUND SURFACE WATER SAMPLE LOCATION
INACTIVE SURFACE WATER SAMPLE LOCATION
O SURFACE WATER SAMPLE LOCATION
REVIEW BOUNDARY
■ ■ COMPLIANCE BOUNDARY
PROPERTY BOUNDARY (APPROXIMATE)
COAL COMBUSTION PRODUCT LIMITS
NOTES:
1. SURFACE WATER SAMPLE LOCATIONS SW-6-Al AND SW-8-Ai ARE INACTIVE DUE TO
CONSTRUCTION ACTIVITIES FOR THE COVER PROJECT.
2. ALL BOUNDARIES ARE APPROXIMATE.
3. AERIAL IMAGERY OBTAINED FROM USGS VIA EARTH EXPLORER, COLLECTED SEPTEMBER 15,
2022.
4. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE
COORDINATE SYSTEM FIPS 3200 (NAD83).
fi
16,
synTerra
�DUKE
ENERGY
PROGRESS
11
GRAPHIC SCALE
125 0 125 250
(IN FEET)
DRAWN BY C- WYATT DATE = 06/08/2022
REVISED BY L FOREMAN DATE=05/28/2024
CHECKED BY C-MCCLUSKEY DATE=05/28/2024
APPROVED BY K- FERRI DATE = 05/28/2024
PROJECT MANAGER_K-FERRI
FIGURE 3
SURFACE WATER SAMPLE LOCATION MAP
STRUCTURAL FILL AREA 1
QUARTERLY WATER QUALITY MONITORING REPORT
APRIL 2024 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
FLETCHER, NORTH CAROLINA

EXISTING WETLANDS _l� PZ-6
OF {
CONCRETE HEADWALL
4 - PZ5 PZ4
r15" RCP k PZ-3
1 1 { PZ-3D"
r ,
I {
PZ-1 1 s
+ PZ-7 ♦
{
PZ-2S
{ PZ-2'
{1
1
` 1
■
on
v
A*#
•41 ■�•��
LEGEND
C PIEZOMETER
REVIEW BOUNDARY
■ COMPLIANCE BOUNDARY
- — COAL COMBUSTION PRODUCT LIMITS
• PROPERTY BOUNDARY (APPROXIMATE)
NOTES:
1. COAL COMBUSTION PRODUCTS LIMITS, REVIEW BOUNDARY AND COMPLIANCE BOUNDARY
TAKEN FROM SBME DRAWING ( "GROUNDWATER FLOW MAP STRUCTURAL FILL", DECEMBER 12,
2010),
2.'- PIEZOMETERS ARE SCREENED BELOW THE GEOSYNTHETIC CLAY LINER TO MONITOR
GROUNDWATER LEVELS.
3. ALL BOUNDARIES ARE APPROXIMATE.
4. AERIAL IMAGERY OBTAINED FROM USGS VIA EARTH EXPLORER, COLLECTED SEPTEMBER 15,
2022.
5, DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE
COORDINATE SYSTEM RES 3200 (NAD83).
synTerra
/' DUKE
ENERGY
PROGRESS
0
1�
Not
{I
y
■
rr-
GRAPHIC SCALE
125 0 125 250
(IN FEET)
DRAWN BY C- WYATT DATE = 06/08/2022
REVISED BY L FOREMAN DATE=05/28/2024
CHECKED BY C-MCCLUSKEY DATE=05/28/2024
APPROVED BY K- FERRI DATE = 05/28/2024
PROJECT MANAGER_K-FERRI
FIGURE 4
PIEZOMETER LOCATION MAP
STRUCTURAL FILL AREA 1
QUARTERLY WATER QUALITY MONITORING REPORT
APRIL 2024 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
FLETCHER, NORTH CAROLINA

CONCRETE HEADWAL
CULVERT
EXISTING WETLANDS
Z10p , u
♦ �I
•- MW-5-Al
J" 2114.73
•
i
t
1 ► Zti,
1
1
1
■
I
1�
I Ff;FNn
MW-4A-Al
2133.35
BACKGROUND MONITORING WELL
REVIEW BOUNDARY MONITORING WELL
MONITORING WELL - WATER LEVEL ONLY
C PIEZOMETER
INFERRED GROUNDWATER LEVEL CONTOUR
GROUNDWATER FLOW DIRECTION
REVIEW BOUNDARY
COMPLIANCE BOUNDARY
COAL COMBUSTION PRODUCT LIMITS
PROPERTY BOUNDARY (APPROXIMATE)
2089.59
MW-6-A1
MW-1A-A1 2096.18
2093.10
EA
NOTES:
1. GROUNDWATER ELEVATIONS ARE BASED ON WATER LEVELS COLLECTED
APRIL 1 AND 2, 2024.
2. THE LOCATION OF WELL MW-2B-A1 IS APPROXIMATE. LOCATION OF WELL MW-1-A1 TAKEN FROM
GEOSYNTEC DRAWING ("INSTRUMENTATION AND MONITORING WELL LOCATIONS", MAY 2020). OTHER
WELL LOCATIONS, COAL COMBUSTION PRODUCTS LIMITS, REVIEW BOUNDARY AND COMPLIANCE
BOUNDARY TAKEN FROM S&ME DRAWING (-GROUNDWATER FLOW MAP STRUCTURAL FILL",
DECEMBER 12, 2010).
3, ALL BOUNDARIES ARE APPROXIMATE.
4. AERIAL IMAGERY OBTAINED FROM USGS VIA EARTH EXPLORER, COLLECTED SEPTEMBER 15, 2022.
5. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE
SYSTEM RIPS 3200 (NAD83).
MW-2B-A1 amAN ANP
2104.18 v
a �
Y� N
s
MW-7-Al
1 ♦ 2118.90
t
PZ-3D ♦ `
2114.57
�♦
rr r
MW-8-Al
♦ 2130.83
♦ `
PZ-2D
2115.10 t. -
/ �I
60" RCP r `
i!
/ `
/ of
+ 1 ♦J MW-9-A1
2141.13 '
g �� ryao 1
' 1
r
GRAPHIC SCALE
10
125 0 125 250
synTerra
(IN FLEE)
DRAWN BY C_ WATT
REVISED BY L FOREMAN
CHECKED BY C_MCCLUSKEY
APPROVED BY_K_FERRI
PROJECT MANAGER K FERRI
DATE = 06/09/2022
DATE 05/28/2024
DATE_05/28/2024
DATE=05/28/2024
/' DUKE
ENERGY
PROGRESS
FIGURE 5
GROUNDWATER CONTOUR MAP
STRUCTURAL FILL AREA 1
QUARTERLY WATER QUALITY MONITORING REPORT
APRIL 2024 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
FLETCHER, NORTH CAROLINA

PONDS
1'
LEGEND
DETENTION
BORROW
REVIEW BOUNDARY MONITORING WELL
-- INFERRED GROUNDWATER LEVEL CONTOUR
GROUNDWATER FLOW DIRECTION
- REVIEW BOUNDARY
■ COMPLIANCE BOUNDARY
COAL COMBUSTION PRODUCT LIMITS
■ PROPERTY BOUNDARY (APPROXIMATE)
.82
MW-6-A3
♦ 2095.32 i Y
M W-5-A3 +
2098.16 \;
� 1 1
• ♦ 1 "� 1 AREA
♦ •
• I
% ♦ 1 It 1
\ MW-3-A3 �, ♦ i 1 { { 1
2109.38 �` ♦ } +
:
\ \� _GREATERASHEVILLE REGIONAL • ��
1001` AIRPORT AUTHORITY ' ^ `-
tip
GRAPHIC SCALE
300 0 300 600
symTerra
,IN FEEf,
DRAWN BY C_ WYATT
REVISED BY L FOREMAN
CHECKED BY C. MCCWSKEY
APPROVED BY K_ FERRI
PROJECTMANAGER K FERRI
DATE_ 06/09/2022
DATE 05/23/2024
DATE 05/23/2024
DATE = 05/23/2024
/' DUKE
ENERGY
PROGRESS
NOTES: FIGURE 6
1. GROUNDWATER ELEVATIONS ARE BASED ON WATER LEVELS COLLECTED
APRIL I AND 2, 2024. GROUNDWATER CONTOUR MAP
2. COAL COMBUSTION PRODUCTS LIMITS, REVIEW BOUNDARYAND COMPLIANCE BOUNDARY STRUCTURAL FILL AREA 3
BASED ON DRAWING BY FRANKLIN S. CRAIG, P.E. OF GASTONIA, NORTH CAROLINA ("AREA#4-
ALL PHASES ENGINEERED FILL DESIGN", SHEET E-1, JUNE 30, 2011). QUARTERLY WATER QUALITY MONITORING REPORT
3. ALL BOUNDARIES AREAPPROXIMATE. APRIL 2024 SAMPLING EVENT
20AERIAL IMAGERY OBTAINED FROM USGS VIA EARTH EXPLORER, COLLECTED SEPTEMBER 15, GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
5. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE FLETCH ER, NORTH CAROLINA
COORDINATE SYSTEM RIPS 320D (NAD83).

_ MW-IAR-A4R r �
e 2113.19 ♦r -
a`1,,J _I� .. ♦r
■
M W-2-A
2059.45
I FGFNn
♦
r_,Ioo
. ♦ 4 ,-ss M��a�
j \ GREATERASHEVILLE REGIONAL:'
• �N AIRPORT AUTHORITY
�,J
logo ',.4
15 k
r a.
}
r
1
MW-5-A4 1 ■
2058-36
1
2056.13
BACKGROUND MONITORING WELL
REVIEW BOUNDARY MONITORING WELL
-- INFERRED GROUNDWATER LEVEL CONTOUR
GROUNDWATER FLOW DIRECTION
REVIEW BOUNDARY
■ - COMPLIANCE BOUNDARY
- - - COAL COMBUSTION PRODUCT LIMITS
— - PROPERTY BOUNDARY (APPROXIMATE)
MW-6-A4 ! ► r
2056.40 i
1
s
\ 1 ■
` y M W-7-A4 1 ■
?(r, 2051.69 y
.204081
r ■ �' �i DETENTION POND #
NOTES:
1. GROUNDWATER ELEVATIONS ARE BASED ON WATER LEVELS COLLECTED
APRIL 1 AND 2, 2024.
2. COAL COMBUSTION PRODUCTS LIMITS, REVIEW BOUNDARYAND COMPLIANCE BOUNDARY
BASED ON DRAWING BY FRANKLIN S. CRAIG, P.E. OF GASTONIA, NORTH CAROLINA ("AREA#4 -ALL
PHASES ENGINEERED FILL DESIGN", SHEET E-1, JUNE 30, 2011),
3. ALL BOUNDARIES ARE APPROXIMATE.
4. AERIAL IMAGERY OBTAINED FROM USGS VIA EARTH EXPLORER, COLLECTED SEPTEMBER 15,
2022.
5. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE
SYSTEM FIRS 3200 (NAD83).
nTerra
DUKE
ENERGY
PROGRESS
GRAPHIC SCALE
300 0 300 600
,IN FEEf)
DRAWN BY C- WYATT DATE_ 06/09/2022
REVISED BY L FOREMAN DATE_ 05/23/2024
CHECKED BY C. MCCWSKEY DATE = 05/23/2024
APPROVED BY K- FERRI DATE = 05/23/2024
PROJECT MANAGER_ K. FERRI
FIGURE 7
GROUNDWATER CONTOUR MAP
STRUCTURAL FILL AREA 4
QUARTERLY WATER QUALITY MONITORING REPORT
APRIL 2024 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
FLETCHER, NORTH CAROLINA

Quarterly Water Quality Monitoring Report — April 2024 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
TABLES
L7
symTerra
Science & Engineering Consultants

TABLE 1
MONITORING WELL CONSTRUCTION INFORMATION
STRUCTURAL FILL AREAS 1, 3, AND 4
QUARTERLY WATER QUALITY MONITORING REPORT
APRIL 2024 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLETCHER, NC
Well Name
Date
Installed
Casing
Diameter
(inches)
Northing
Easting
Ground
Elevation
Top Of Casing
Elevation
Total Depth
of Well (bgs)
Length
of Screen (feet)
Screened Interval
(NAND 88)
Lithology of
Screened Interval
(NAD 83)
(NAVD 88)
from
to
MW-1-Al*
1/4/2008
6.5
636742.78
945061.99
2,096.50
2098.94
23
15
2,089
2,074
Saprolite
MW-1A-A1
10/6/2009
2
636559.68
944943.83
2,097.70
2,100.40
20
15
2,093
2,078
Saprolite
MW-2A-Al#
10/6/2009
2
636617.12
945291.16
2,099.90
2,102.71
15
10
2,095
2,085
Saprolite
MW-26-Al
10/6/2022
2
636656.42
945306.39
2,109.32
2,112.08
25
10
2,094
2,084
Saprolite
MW-4A-Al
10/7/2009
2
635188.59
944975.13
2,149.10
2,151.55
45
15
2,119
2,104
Saprolite/PWR
MW-5-Al
10/7/2009
2
636320.32
944677.45
2,152.00
2,153.86
57
15
2,110
2,095
Saprolite
MW-6-Al
8/14/2018
2
636581.93
945096.41
2,102.83
2,103.13
20
10
2,093
2,083
Saprolite
MW-7-Al
8/14/2018
2
636504.84
945718.42
2,123.33
2,123.62
20
10
2,113
2,103
Saprolite
MW-8-Al
8/14/2018
2
636237.93
945850.91
2,142.29
2,142.59
25
10
2,127
2,117
Saprolite
MW-9-Al
8/14/2018
2
635681.19
946058.68
2,163.20
2,163.53
32
10
2,142
2,132
Saprolite
MW-1-A3
11/25/2013
2
634037.84
943846.89
2,159.54
2,162.42
58
15
2,117
2,102
PWR
MW-2-A3
12/11/2013
2
634848.88
943520.52
2,144.60
2,147.13
63
15
2,097
2,082
Saprolite/PWR
MW-3-A3
12/2/2013
2
635548.38
943337.34
2,138.00
2,140.98
65
15
2,088
2,073
Saprolite/PWR
MW-4-A3
12/13/2013
2
636014.40
943105.17
2,115.40
2,117.64
34
10
2,092
2,082
Saprolite/PWR
MW-5-A3
12/3/2013
2
636531.67
943234.27
2,120.60
2,123.16
62
15
2,073
2,058
Saprolite/PWR
MW-6-A3
12/4/2013
2
636734.52
943257.50
2,127.80
2,130.44
67
15
2,076
2,061
Saprolite/PWR
MW-7-A3
12/2/2013
2
637022.38
943192.53
2,119.00
2,121.54
68
15
2,067
2,052
Saprolite/PWR
MW-IAR-A4A
9/18/2015
2
631447.90
944679.90
2,131.20
2,133.72
60
10
2,081
2,071
PWR
MW-1AR-A411
6/21/2022
2
631602.17
944673.98
2,136.65
2,136.59
33
10
2,114
2,104
PWR
MW-2-A4
12/8/2009
2
629920.28
944436.90
2,074.60
2,076.56
30
20
2,065
2,045
Saprolite
MW-5-A4
12/8/2009
2
629395.45
944832.59
2,066.30
2,068.31
25
15
2,056
2,041
Saprolite
MW-5D-A4
4/2/2012
2
629386.39
944842.05
2,067.10
2,071.47
72
10
21006
1,996
PWR
MW-6-A4
7/2/2010
2
628967.08
945202.85
2,071.00
2,074.01
30
15
2,056
2,041
Saprolite
MW-7-A4
7/2/2010
2
628489.87
945512.01
2,068.40
2,071.37
30
15
2,053
1 2,038
Saprolite
MW-9-A4
3/29/2012
2
627830.32
945932.12
2,065.00
2,069.01
105
10
1,972
1 1,962
PWR
Notes:
* - Monitoring well used for water level measurements only.
A - Monitoring well was abandoned in August 2022 and replaced with MW-IAR-A4R.
- Monitoring well was abandoned in August 2022 and replaced with MW-213-A1.
NAD 83 - North American Datum of 1983
NAVD 88 - North American Vertical Datum of 1988
bgs - below ground surface
PWR - partially weathered rock
Information on this table provided by Duke Energy Progress, LLC., except for survey data from replacement wells MW-213-A1 and MW-IAR-A41R.
Prepared by: CSM Checked by: KHF
Page 1 of 1

TABLE 2
GROUNDWATER ELEVATION
STRUCTURAL FILL AREAS 1, 3, AND 4
QUARTERLY WATER QUALITY MONITORING REPORT
APRIL 2024 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLETCHER, NC
Well ID
Associated
Unit
Top of Casing
Elevation
(ft-NAND 88)
Ground Surface
Elevation
(ft-NAND 88)
April 2024
Depth to
Groundwater
(ft-BTOC)
Groundwater
Elevation
(ft-NAVD 88)
MW-1-Al
Area 1
2,098.94
2,096.50
9.35
2,089.59
MW-IA-Al
Area 1
2,100.40
2,097.70
7.30
2,093.10
MW-213-A1
Area 1
2,112.08
2,109.32
7.90
2,104.18
MW-4A-Al
Area 1
2,151.55
2,149.10
18.20
2,133.35
MW-5-Al
Area 1
2,153.86
2,152.00
39.13
2,114.73
MW-6-Al
Area 1
2,103.13
2,102.83
6.95
2,096.18
MW-7-Al
Area 1
2,123.62
2,123.33
4.72
2,118.90
MW-8-Al
Area 1
2,142.59
2,142.29
11.76
2,130.83
MW-9-Al
Area 1
2,163.53
2,163.20
22.40
2,141.13
MW-1-A3
Area 3
2,162.42
2,159.54
33.10
2,129.32
MW-2-A3
Area 3
2,147.13
2,144.60
23.25
2,123.88
MW-3-A3
Area 3
2,140.98
2,138.00
31.60
2,109.38
MW-4-A3
Area 3
2,117.64
2,115.40
18.75
2,098.89
MW-5-A3
Area 3
2,123.16
2,120.60
25.00
2,098.16
MW-6-A3
Area 3
2,130.44
2,127.80
35.12
2,095.32
MW-7-A3
Area 3
2,121.54
2,119.00
28.72
2,092.82
MW-IAR-A4R
Area 4
2,136.59
2,131.20
23.40
2,113.19
MW-2-A4
Area 4
2,076.56
2,074.60
17.11
2,059.45
MW-5-A4
Area 4
2,068.31
2,066.30
9.95
2,058.36
MW-5D-A4
Area 4
2,071.47
2,067.10
15.34
2,056.13
MW-6-A4
Area 4
2,074.01
2,071.00
17.61
2,056.40
MW-7-A4
Area 4
2,071.37
2,068.40
19.68
2,051.69
MW-9-A4
Area 4
2,069.01
2,065.00
28.20
2,040.81
Notes:
Water level measurements were collected April 1 and 2, 2024.
BTCC - below top of casing
Elevations are reported in NAVD 88.
ft - feet
NAVD 88 - North American Vertical Datum of 1988
Prepared by: CSM Checked by: CS
Page 1 of 1

TABLE 3
GROUNDWATER FLOW VELOCITIES
STRUCTURAL FILL AREAS 1, 3, AND 4
QUARTERLY WATER QUALITY MONITORING REPORT
APRIL 2024 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLETCHER, NC
AREA 1 MONITORING WELLS
Upgradient
Downgradient
Linear Distance
Hydraulic
Hydraulic
Effective
Groundwater
Groundwater
Between
Groundwater
WeIIIDs
1
Elevation
1
Elevation
Elevations
Gradient
Conductivity2
Porosity3
Velocity (ft/day)
(ft/ft)
(ft/day)
(%/100)
(ft - NAVD 88)
(ft - NAVD 88)
(ft)
MW-9-Al to MW-6-Al
2,141.13
2,096.18
1,350
0.033
0.91
0.3
0.101
MW-9-Al to MW-8-Al
2,141.13
2,130.83
609
0.017
0.91
0.3
0.051
MW-8-Al to MW-6-Al
2,130.83
2,096.18
847
0.041
0.91
0.3
0.124
AREA 3 MONITORING WELLS
Upgradient
Downgradient
Linear Distance
Hydraulic
Hydraulic
Effective
Groundwater
Groundwater
Between
Groundwater
WeIIIDs
1
Elevation
1
Elevation
Elevations
Gradient
Conductivity2
Porosity3
Velocity (ft/day)
(ft/ft)
(ft/day)
(%/100)
(ft - NAVD 88)
(ft - NAVD 88)
(ft)
MW-1-A3 to MW-3-A3
2,129.32
2,109.38
1,626
0.012
2.25
0.3
0.092
MW-1-A3 to MW-2-A3
2,129.32
2,123.88
893
0.006
2.25
0.3
0.046
MW-2-A3 to MW-5-A3
2,123.88
2,098.16
662*
0.039
2.25
0.3
0.291
Page 1 of 2

TABLE 3
GROUNDWATER FLOW VELOCITIES
STRUCTURAL FILL AREAS 1, 3, AND 4
QUARTERLY WATER QUALITY MONITORING REPORT
APRIL 2024 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLETCHER, NC
AREA 4 MONITORING WELLS
Upgradient
Downgradient
Linear Distance
Hydraulic
Hydraulic
Effective
Groundwater
Groundwater
Between
Groundwater
WeIIIDs
1
1
Gradient
ConductivityZ
Porosity3
Elevation
Elevation
Elevations
Velocity (ft/day)
ft ft
( / )
(ft/day)
(%/100)
(ft - NAVD 88)
(ft - NAVD 88)
(ft)
MW-IAR-A4R to MW-2-A4
2,113.19
2,059.45
1,550
0.035
1.67
0.3
0.193
MW-6-A4 to MW-7-A4
2,056.40
2,051.69
198*
0.024
1.67
0.3
0.133
MW-6-A4 to MW-9-A4
2,056.40
2,040.81
277*
0.056
1.67
0.3
0.314
Notes:
1 Upgradient and downgradient groundwater elevations correspond to water levels collected during the April 2024 sampling event.
Z Hydraulic conductivity values represent area -specific geometric mean.
3 Effective porosity value sourced from Updated Groundwater Flow and Transport Modeling Report for the Asheville Steam Electric Plant - September, 2022.
* Based on inferred contour linear distance drawn parallel to groundwater flow
Elevations are reported in NAVD 88 - North American Vertical Datum 1988.
Hydraulic gradients, effective porosity, and groundwater velocities are approximate
% - percent
ft - feet
ft/ft - feet per foot
Prepared by: CSM Checked by: CS
Page 2 of 2

TABLE 4
GROUNDWATER FIELD AND ANALYTICAL RESULTS
STRUCTURAL FILL AREAS 1, 3, AND 4
QUARTERLY WATER QUALITY MONITORING REPORT
APRIL 2024 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLETCHER NC
Parameter
SWS ID
Units
15A NCAC 02L
Standard'
Area 1 Monitoring Wells
Area 3 Monitoring Wells
MW-1A-A1
MW-2B-A1
MW-4A-A1�
MW-5-Al
MW-6-Al
MW-7-Al
MW-8-Al
MW-9-A1^
MW-1-A3
MW-2-A3
MW-3-A3
MW-4-A3
pH
320
S.U.
6.5 - 8.5
5.7
5.1
5.3
4.3
4.7
4.7
4.0
6.0
4.8
4.4
4.7
4.5
Temperature
325
°C
NE
16
16
17
14
16
13
14
17
16
18
16
17
Specific Conductance
323
µmhos/cm
NE
65
92
90
23
109
35
211
142
41
19
13
20
Dissolved Oxygen
---
mg/L
NE
3.83
1.78
0.7
1.52
0.33
4.23
0.58
3.46
3.87
4.3
7.21
2.23
Oxidation Reduction Potential
336
mV
NE
573
565
388
497
424
467
760
360
437
483
564
487
Turbidity
330
NTUs
NE
3.5
7.2
9.2
1.9
5.1
3.2
3
1.9
62.8
4.5
27.2
3.9
Alkalinity
337
mg/L
NE
17.9
15.2
32.4
3.5 J
6.83
5.39
< 1.7
60.6
8.17
5.7
3.89 J
7.22
Aluminum
---
µg/L
NE
393 B2
84 B2
132 B2
37 B2
75 B2
52 B2
830 B2
173 B2
2940 B2
21 B2
1090 B2
33 B2
Antimony
13
µg/L
1
< 0.104
< 0.104
< 0.104
< 0.104
< 0.104
< 0.104
< 0.104
< 0.104
< 0.104
< 0.104
< 0.104
< 0.104
Arsenic
14
µg/L
10
< 0.111
< 0.111
0.292 J
< 0.111
< 0.111
< 0.111
0.502 J
< 0.111
0.201 J
< 0.111
0.126 J
< 0.111
Barium
15
µg/L
700
30
55
15
24
68
24
680
21
53
13
17
22
Beryllium
23
µg/L
4
< 0.249
< 0.249
< 0.249
< 0.249
0.552 J
0.291 J
0.676 J
< 0.249
< 0.249
< 0.249
< 0.249
< 0.249
Bicarbonate Alkalinity
347
mg/L
NE
17.9
15.2
32.4
3.5 J
6.83
5.39
< 1.7
60.6
8.17
5.7
3.89 J
7.22
Boron
428
µg/L
700
28J
<5
12J
6J
<5
<5
7J
<5
<5
<5
<5
<5
Cadmium
34
µg/L
2
0.037 J
0.048 J
0.859 J
0.036 J
0.034 J
< 0.032
0.231 J
< 0.032
0.043 J
< 0.032
< 0.032
< 0.032
Calcium
375
mg/L
NE
4.92
8.20
6.01
0.334
6.40
1.07
2.02
4.85
3.03
0.197
0.482
0.753
Carbonate Alkalinity
348
mg/L
NE
< 1.7
< 1.7
< 1.7
< 1.7
< 1.7
< 1.7
< 1.7
< 1.7
< 1.7
< 1.7
< 1.7
< 1.7
Chloride
301
mg/L
250
4.7
16
1.3
3.1
26
8.5
81
10
2.5
0.97
0.62
0.9
Chromium
51
µg/L
10
1.60
0.304 J
0.25 J
0.263 J
0.255 J
0.48 J
0.288 J
0.559 J
1.89
< 0.185
1.15
0.264 J
Cobalt
53
µg/L
1
0.151 J
0.541 J
14.0
0.722 J
1.03
0.164 J
18.2
0.183 J
2.74
0.172 J
0.457 J
< 0.077
Copper
54
µg/L
1,000
3 J
< 1
4 J
2 J
< 1
11
5
< 1
4 J
11
4 J
< 1
Iron
340
µg/L
300
252
77
821
16
1530
45
61
163
2940
< 4
1110
5J
Lead
131
µg/L
15
0.243 J
0.074 J
0.176 J
0.11
< 0.037
0.064 J
0.161 J
0.072 J
0.779 J
< 0.037
0.282 J
0.05 J
Magnesium
376
mg/L
NE
2.85
3.17
1.12
0.699
3.24
1.03
4.01
1.89
1.99
0.455
0.845
1.18
Manganese
342
µg/L
50
12
40
461
51
27
18
1440
68
193
14
27
10
Mercury
132
µg/L
1
<0.01
<0.01
<0.01
0.09
<0.01
<0.01
0.34
<0.01
<0.01
<0.01
<0.01
<0.01
Molybdenum
397
µg/L
NE
<0.18
<0.18
<0.18
<0.18
<0.18
<0.18
<0.18
0.424J
<0.18
<0.18
<0.18
<0.18
Nickel
152
µg/L
100
< 0.256
0.799 J
0.966 J
0.72 J
1.95
0.754 J
8.01
< 0.256
2.68
1.37
1.09
1.08
Potassium
377
mg/L
NE
1
1.48
1.97
0.62
1.17
0.624
3.1
5.77
2.43
0.47
0.892
0.872
Selenium
183
µg/L
20
1.23
< 0.193
< 0.193
< 0.193
< 0.193
< 0.193
< 0.193
< 0.193
< 0.193
< 0.193
< 0.193
< 0.193
Page 1 of 4

TABLE 4
GROUNDWATER FIELD AND ANALYTICAL RESULTS
STRUCTURAL FILL AREAS 1, 3, AND 4
QUARTERLY WATER QUALITY MONITORING REPORT
APRIL 2024 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLETCHER NC
Parameter
SWS ID
Units
15A NCAC 02L
1
Standard
Area 3 Monitoring Wells (Continued)
Area 4 Monitoring Wells
MDL
SWS
GWPS
MW-5-A3
MW-6-A3
MW-7-A3
MW-IAR-A4R^
MW-2-A4
MW-5-A4
MW-5D-A4
MW-6-A4
MW-7-A4
MW-9-A4
pH
320
S.U.
6.5 - 8.5
4.6
5.1
4.7
5.3
4.8
4.8
5.6
4.9
3.5
5.5
NE
NE
Temperature
325
°C
NE
16
16
13
15
14
16
15
15
17
17
NE
NE
Specific Conductance
323
µmhos/cm
NE
19
22
13
18
22
69
55
50
1135
78
NE
NE
Dissolved Oxygen
---
mg/L
NE
4.75
6.76
7.52
7.34
4.59
3.41
4.56
3.59
4.4
3.67
NE
NE
Oxidation Reduction Potential
336
mV
NE
455
460
427
413
413
390
374
432
499
415
NE
NE
Turbidity
330
NTUs
NE
1.7
1.1
1.8
7
3.2
2.8
2.9
1.9
3
0.9
NE
NE
Alkalinity
337
mg/L
NE
7.45
9.08
7.25
11.7
9.36
11.2
39.1
11.1
< 1.7
39.9
1.7
NE
Aluminum
---
µg/L
NE
118 B2
15 B2
17 B2
1360 B2
39
103
22
8 J
47
23
0.003
NE
Antimony
13
µg/L
1
< 0.104
< 0.104
0.243 J
< 0.104
< 0.104
< 0.104
< 0.104
< 0.104
< 0.104
< 0.104
0.104
NE
Arsenic
14
µg/L
10
<0.111
<0.111
<0.111
0.116J
<0.111
<0.111
<0.111
<0.111
162
<0.111
0.111
NE
Barium
15
µg/L
700
13
7
11
24
18
92
24
50
11
7
2
NE
Beryllium
23
µg/L
4
< 0.249
< 0.249
< 0.249
< 0.249
< 0.249
< 0.249 U
< 0.249 U
< 0.249
3.33
< 0.249
0.249
NE
Bicarbonate Alkalinity
347
mg/L
NE
7.45
9.08
7.25
11.7
9.36
11.2
39.1
11.1
< 1.7
39.9
1.7
NE
Boron
428
µg/L
700
< 5
< 5
11
< 5
7 J
38 J
14 J
12 J
8 J
6 J
5
NE
Cadmium
34
µg/L
2
< 0.032
< 0.032
0.09 J
0.044 J
< 0.032
0.032 U
0.033 J
0.034 J
2.22
< 0.032
0.032
NE
Calcium
375
mg/L
NE
1.31
1.82
1.44
3.09
1.61
12.7
8.36
6.41
260
7.28
0.012
NE
Carbonate Alkalinity
348
mg/L
NE
< 1.7
< 1.7
< 1.7
< 1.7
< 1.7
< 1.7
< 1.7
< 1.7
< 1.7
< 1.7
1.7
NE
Chloride
301
mg/L
250
0.91
0.55
0.84
1.1
2.3
2.6
0.82
2.9
5.4
0.72
0.0154
NE
Chromium
51
µg/L
10
0.619 J
0.654 J
0.357 J
1.68
0.397 J
0.351 J
0.399 J
1.08
2.52
1
0.185
NE
Cobalt
53
µg/L
1
0.093 J
< 0.077
< 0.077
0.861 J
0.219 J
0.108 J
< 0.077
0.351 J
684
< 0.077
0.077
NE
Copper
54
µg/L
1,000
< 1
< 1
2 J
2 J
11
2 J
5 J
< 1
5 J
< 1
0.787
NE
Iron
340
µg/L
300
74
4 J
4 J
1500
23
288
29
4 J
10 J
10 J
4
NE
Lead
131
µg/L
15
0.05 J
< 0.037
< 0.037
0.523 J
< 0.037
0.126 J
0.313 J
< 0.037
0.147 J
0.077 J
0.037
NE
Magnesium
376
mg/L
NE
1.09
0.978
1.04
1.15
1.3
2.8
1.88
2.50
65
1.98
0.008
NE
Manganese
342
µg/L
50
15
4 J
3 J
252
15
23
2 J
12
10700
3 J
1
NE
Mercury
132
µg/L
1
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
0.03J
0.02J
<0.01
0.01
NE
Molybdenum
397
µg/L
NE
< 0.18
< 0.18
1.06
0.561 J
< 0.18
< 0.18
< 0.18
< 0.18
< 0.18
< 0.18
0.18
NE
Nickel
152
µg/L
100
1.04
0.341 J
0.95 J
1.64
0.466 J
0.449 J
0.276 J
< 0.256
973
< 0.256
0.256
NE
Potassium
377
mg/L
NE
0.631
0.517
0.887
2.33
0.824
2.61
1.46
1.33
2.64
1.64
0.031
NE
Selenium
183
µg/L
20
< 0.193
< 0.193
0.299 J
< 0.193
< 0.193
< 0.193
< 0.193
0.655 J
2.52
< 0.193
0.193
NE
Page 2 of 4

TABLE 4
GROUNDWATER FIELD AND ANALYTICAL RESULTS
STRUCTURAL FILL AREAS 1, 3, AND 4
QUARTERLY WATER QUALITY MONITORING REPORT
APRIL 2024 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLETCHER NC
Parameter
SWS ID
Units
15A NCAC 02L
Standard'
Area 1 Monitoring Wells
Area 3 Monitoring Wells
MW-1A-A1
MW-26-Al
MW-4A-A1�
MW-5-Al
MW-6-Al
MW-7-Al
MW-8-Al
MW-9-A1^
MW-1-A3
MW-2-A3
MW-3-A3
MW-4-A3
Sodium
322
mg/L
NE
3.21
3.57
6.5
3.7
6.43
5.76
40.7
22.5
2.47
2.9
1.22
1.2
Strontium
---
µg/L
2000
57
98
13
5 J
88
17
41
46
35
2 J
7
7
Sulfate
315
mg/L
250
1.0
0.14 J
1.3
0.05 J
0.18
< 0.0428
0.07 J
7.9
1.2
0.2
0.09 J
< 0.0428
Thallium
194
µg/L
2
0.041 J
< 0.041
0.107 J
< 0.041
< 0.041
< 0.041
0.141 J
0.075 J
0.088 J
< 0.041
< 0.041
< 0.041
Total Dissolved Solids
311
mg/L
500
43
69
46
< 25
80
30
145
109
30
< 25
< 25
< 25
Total Suspended Solids
343
mg/L
NE
7
< 5
< 5
< 5
< 5
< 5
< 5
11
49
< 5
58
< 5
Vanadium
209
µg/L
7
0.299 J
0.151 J
0.27 J
< 0.114
< 0.114
< 0.114
< 0.114
0.322
2.64
< 0.114
0.873
< 0.114
Zinc
213
µg/L
1,000
22
8 J
374
11
12 J
< 4
66
< 4
67
10 J
8 J
7 J
Notes:
Analytical data presented in this table reflect the Duke Energy Biological Analytical Data Storage System (BASS) as of 04/02/2024.
Bold concentrations are equal to or greater than the 15A NCAC 02L Standard (for pH bold indicates a measurement less than or greater than the indicated range).
No applicable SWS ID.
15A NCAC 02L Standards for Groundwater - North Carolina Groundwater Quality Standards (effective June 1, 2022).
Background monitoring well
< - Concentration not detected at or greater than the adjusted reporting limit.
°C - degrees Celsius
µg/L- micrograms per liter
µmhos/cm - micromhos per centimeter
B2 - Target analyte was detected in blank(s) at a concentration greater than half the reporting limit but less than the reporting limit.
J - Estimated concentrations equal to or greater than the MDL but less than the laboratory's method reporting limit (MRL).
MDL - laboratory method detection limit; MDL values presented are for samples not diluted by the laboratory during analysis.
mg/L - milligrams per liter
my - millivolts
NCAC - North Carolina Administrative Code
NE - not established
S.U. - standard units
Samples were collected in April 2024.
SW GWPS - Solid Waste Groundwater Protection Standard
SWS ID - Solid Waste Section Identification Number
U - Analyte was analyzed for, but not detected above the minimum detectable concentration (MDC) or method detection limit (MDL).
Page 3 of 4

TABLE 4
GROUNDWATER FIELD AND ANALYTICAL RESULTS
STRUCTURAL FILL AREAS 1, 3, AND 4
QUARTERLY WATER QUALITY MONITORING REPORT
APRIL 2024 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLETCHER NC
Parameter
SWS ID
Units
15A NCAC 02L
1
Standard
Area 3 Monitoring Wells (Continued)
Area 4 Monitoring Wells
MDL
SWS
GWPS
MW-5-A3
MW-6-A3
MW-7-A3
MW-IAR-A4R^
MW-2-A4
MW-5-A4
MW-5D-A4
MW-6-A4
MW-7-A4
MW-9-A4
Sodium
322
mg/L
NE
1.14
0.971
1.43
2.03
1.97
2.89
6.57
4.03
9.62
6.49
0.017
20,000
Strontium
---
µg/L
2000
9
12
9
25
15
52
102
62
6
74
1
NE
Sulfate
315
mg/L
250
0.08 J
0.06 J
0.43
0.47
0.28
23
0.13
17
1000
0.09 J
0.0428
NE
Thallium
194
µg/L
2
< 0.041
< 0.041
< 0.041
0.045 J
< 0.041
< 0.041
< 0.041
< 0.041
0.124 J
< 0.041
0.041
NE
Total Dissolved Solids
311
mg/L
500
< 25
< 25
< 25
27
< 25
67
59
41
1380
67
25
NE
Total Suspended Solids
343
mg/L
NE
< 5
< 5
< 5
14
< 5
< 5
< 5
< 5
< 5
< 5
5
NE
Vanadium
209
µg/L
7
< 0.114
< 0.114
< 0.114
1.26
< 0.114
0.161 J
0.544
0.145 J
< 0.114
0.412
0.114
NE
Zinc
213
µg/L
1,000
9 J
< 4
14 J
10 J
7 J
5 J
11 J
< 4
675
< 4
4
NE
Notes:
Analytical data presented in this table reflect the Duke Energy Biological Analytical Data Storage System (BASS) as of 04/02/2024.
Bold concentrations are equal to or greater than the 15A NCAC 02L Standard (for pH bold indicates a measurement less than or greater than the indicated range).
No applicable SWS ID.
15A NCAC 02L Standards for Groundwater - North Carolina Groundwater Quality Standards (effective June 1, 2022).
Background monitoring well
< - Concentration not detected at or greater than the adjusted reporting limit.
°C - degrees Celsius
µg/L- micrograms per liter
µmhos/cm - micromhos per centimeter
B2 - Target analyte was detected in blank(s) at a concentration greater than half the reporting limit but less than the reporting limit.
J - Estimated concentrations equal to or greater than the MDL but less than the laboratory's method reporting limit (MRL).
MDL - laboratory method detection limit; MDL values presented are for samples not diluted by the laboratory during analysis.
mg/L - milligrams per liter
my - millivolts
NCAC - North Carolina Administrative Code
NE - not established
S.U. - standard units
Samples were collected in April 2024.
SW GWPS - Solid Waste Groundwater Protection Standard
SWS ID - Solid Waste Section Identification Number
U - Analyte was analyzed for, but not detected above the minimum detectable concentration (MDC) or method detection limit (MDL).
Prepared by: CS Checked by: ADW
Page 4 of 4

TABLE 5
FIELD AND ANALYTICAL RESULTS GREATER THAN OR EQUAL TO GROUNDWATER QUALITY STANDARDS
STRUCTURAL FILL AREAS 1, 3, AND 4
QUARTERLY WATER QUALITY MONITORING REPORT
APRIL 2024 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLETCHER, NC
Parameter
Sample ID
Result
Units
15A NCAC 02L
Standard
Site Background1 Z
Concentration Range
Cause and Significance
Area 1
Field pH
MW-1A-A1
5.7
S.U.
6.5 - 8.5
4.3 - 7.8
Within Site background concentration range - naturally occurring
MW-2B-A1
5.1
Within Site background concentration range - naturally occurring
MW-4A-A1
5.3
Area 1 Background well - Naturally occurring
MW-5-Al
4.3
Within Site background concentration range - naturally occurring
MW-6-Al
4.7
Within Site background concentration range - naturally occurring
MW-7-Al
4.7
Within Site background concentration range - naturally occurring
MW-8-Al
4.0
Only slightly less than background range for pH; continue monitoring.
MW-9-Al
6.0
Area 1 Background well - Naturally occurring
Cobalt
MW-4A-A1
14.0
µg/L
1
< 0.1 - 37.7
Area 1 Background well - naturally occurring
MW-6-Al
1.03
Within Site background concentration range - naturally occurring
MW-8-Al
18.2
Within Site background concentration range - naturally occurring
Iron
MW-4A-A1
821
µg/L
300
28.2 - 4400
Area 1 Background well - naturally occurring
MW-6-Al
1530
Within Site background concentration range - naturally occurring
Manganese
MW-4A-A1
461
µg/L
50
16.6 8080
Area 1 Background well - naturally occurring
MW-5-Al
51
Within Site background concentration range - naturally occurring
MW-8-Al
1440
Within Site background concentration range - naturally occurring
MW-9-Al
68
Area 1 Background well - naturally occurring
Area 3
Field pH
MW-1-A3
4.8
S.U.
6.5 - 8.5
4.3 - 7.8
Within Site background concentration range - naturally occurring
MW-2-A3
4.4
Within Site background concentration range - naturally occurring
MW-3-A3
4.7
Within Site background concentration range - naturally occurring
MW-4-A3
4.5
Within Site background concentration range - naturally occurring
MW-5-A3
4.6
Within Site background concentration range - naturally occurring
MW-6-A3
5.1
Within Site background concentration range - naturally occurring
MW-7-A3
4.7
Within Site background concentration range - naturally occurring
Cobalt
MW-1-A3
2.74
µg/L
1
< 0.1- 37.7
Within Site background concentration range - naturally occurring
Iron
MW-1-A3
2940
µg/L
300
28.2 - 4400
Within Site background concentration range - naturally occurring
MW-3-A3
1110
Within Site background concentration range - naturally occurring
Manganese
MW-1-A3
193
µg/L
50
16.6 - 8080
Within Site background concentration range - naturally occurring
Page 1 of 2

TABLE 5
FIELD AND ANALYTICAL RESULTS GREATER THAN OR EQUAL TO GROUNDWATER QUALITY STANDARDS
STRUCTURAL FILL AREAS 1, 3, AND 4
QUARTERLY WATER QUALITY MONITORING REPORT
APRIL 2024 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLETCHER, NC
Parameter
Sample ID
Result
Units
15A NCAC 02L
Standard
Site Background1 Z
Concentration Range
Cause and Significance
Area 4
Field pH
MW-IAR-A4R
5.3
S.U.
6.5 - 8.5
4.3 - 7.8
Area 4 background well - naturally occurring
MW-2-A4
4.8
Within Site background concentration range - naturally occurring
MW-5-A4
4.8
Within Site background concentration range - naturally occurring
MW-5D-A4
5.6
Within Site background concentration range - naturally occurring
MW-6-A4
4.9
Within Site background concentration range - naturally occurring
MW-7-A4
3.5
Value is less than 15A NCAC 021-Standard minimum for pH since November 2019
MW-9-A4
5.5
Within Site background concentration range - naturally occurring
Arsenic
MW-7-A4
162
µg/L
10
< 0.1 - < 5
Concentrations greater than 15A NCAC 02L Standard since November 2019
Cadmium
MW-7-A4
2.22
µg/L
2
< 0.08 - 1.77
Concentrations greater than 15A NCAC 02L Standard since November 2019
Cobalt
MW-7-A4
684
µg/L
1
< 0.1 - 37.7
Concentrations greater than 15A NCAC 02L Standard since November 2019
Iron
MW-IAR-A4R
1500
µg/L
300
28.2 - 4400
Area 4 background well - naturally occurring
Manganese
MW-IAR-A4R
252
µg/L
50
16.6 - 8080
Area 4 background well - naturally occurring
MW-7-A4
10700
Concentrations greater than 15A NCAC 02L Standard since November 2019
Nickel
MW-7-A4
973
µg/L
100
< 0.256 - 10
Concentrations greater than 15A NCAC 02L Standard since November 2019
Sulfate
MW-7-A4
1000
mg/L
250
0.38 - 44.2
Concentrations greater than 15A NCAC 02L Standard since November 2019
Total Dissolved Solids
MW-7-A4
1380
mg/L
500
< 5 - 178
Concentrations greater than 15A NCAC 02L Standard since November 2019
Notes:
Analytical data presented in this table reflect the Duke Energy Biological Analytical Data Storage System (BASS) as of 04/02/2024.
1 - 15A NCAC 02L Standards for Groundwater - North Carolina Groundwater Quality Standards (effective June 1, 2022).
Z- Site background concentration ranges are based on data from approved background groundwater monitoring wells (MW-4A-Al, MW-9-Al, and MW-IAR-A4) through April 2024.
< - Concentration not detected at or greater than the adjusted reporting limit.
µg/L - micrograms per liter
mg/L - milligrams per liter
NCAC - North Carolina Administrative Code
S.U. - standard units
Prepared by: CS Checked by: ADW
Page 2 of 2

TABLE 6
SURFACE WATER FIELD AND ANALYTICAL RESULTS
STRUCTURAL FILL AREA 1
QUARTERLY WATER QUALITY MONITORING REPORT
APRIL 2024 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLETCHER, NC
Parameter
SWS ID
Units
Area 1 Surface Water Sample Locations
MDL
15A NCAC 02B
Standard (Class 13)3
SW-2-Al1
SW-3-Al
SW-4B-A1
SW-4C-Al2
SW-5-Al2
SW-6-Al2
SW-8-Al2
SW-9-Al
SW-10-Al
pH
320
S.U.
4.2
6.1
5.9
NS
NS
NS
NS
5.6
5.6
NE
6.0 - 9.0
Temperature
325
Deg C
20
15
14
NS
NS
NS
NS
15
14
NE
<_ 29
Specific Conductance
323
µmhos/cm
269
237
79
NS
NS
NS
NS
191
208
NE
NE
Dissolved Oxygen
---
mg/L
7.81
9.19
7.28
NS
NS
NS
NS
8.17
8.84
NE
>_ 4
Oxidation Reduction Potential
336
mV
465
345
319
NS
NS
NS
NS
346
322
NE
NE
Turbidity
330
NTUs
5.2
10.7
12.4
NS
NS
NS
NS
5.0
8.8
NE
<_ 50
Total Alkalinity
337
mg/L (CaCO3)
< 1.7
7.93
28.3
NS
NS
NS
NS
12.6
25.4
1.7
NE
Aluminum
---
µg/L
6100
1660
1700
NS
NS
NS
NS
2310
187
0.003
NE
Aluminum (Dissolved)
---
µg/L
3890
179
82
NS
NS
NS
NS
163
23
0.003
NE
Antimony
13
µg/L
0.223 J
< 0.104
0.114 J
NS
NS
NS
NS
< 0.104
< 0.104
0.104
5,300#
Antimony (Dissolved)
---
µg/L
0.269 J
0.111
0.123 J
NS
NS
NS
NS
0.159 J
< 0.104
0.104
NE
Arsenic
14
µg/L
3.22
1.59
1.17
NS
NS
NS
NS
1.55
0.141 J
0.111
10
Arsenic (Dissolved)
---
µg/L
3.38
1.43
0.553 J
NS
NS
NS
NS
1.31
0.126 J
0.111
340^
Barium
15
µg/L
60
60
50
NS
NS
NS
NS
59
35
2
21,000$
Barium (Dissolved)
---
µg/L
60
57
42
NS
NS
NS
NS
57
34
2
NE
Beryllium
23
µg/L
0.287 J
< 0.249
< 0.249
NS
NS
NS
NS
< 0.249
< 0.249
0.249
NE
Beryllium (Dissolved)
---
µg/L
< 0.249
< 0.249
< 0.249
NS
NS
NS
NS
< 0.249
< 0.249
0.249
65^
Bicarbonate Alkalinity
347
mg/L
< 1.7
7.93
28.3
NS
NS
NS
NS
12.6
25.4
1.7
NE
Boron
428
µg/L
8 J
32 J
71
NS
NS
NS
NS
32 J
139
5
34,000#
Boron (Dissolved)
---
µg/L
8 J
27 J
100
NS
NS
NS
NS
29 J
144
5
NE
Cadmium
34
µg/L
0.149 J
0.087 J
0.069 J
NS
NS
NS
NS
0.082 J
< 0.032
0.032
NE
Cadmium (Dissolved)
---
µg/L
0.184 J
0.092 J
0.037 J
NS
NS
NS
NS
0.075 J
< 0.032
0.032
0.75"'
Calcium
375
mg/L
13.9
28.6
20.7
NS
NS
NS
NS
26.2
11.7
0.012
NE
Calcium (Dissolved)
348
mg/L
13.9
27.4
16.8
NS
NS
NS
NS
26.2
11.1
0.012
NE
Carbonate Alkalinity
301
mg/L
< 1.7
< 1.7
< 1.7
NS
NS
NS
NS
< 1.7
< 1.7
1.7
NE
Chloride
51
mg/L
17
16
9.1
NS
NS
NS
NS
17
11
0.0154
230
Chromium
53
µg/L
1.08
0.355 J
0.373 J
NS
NS
NS
NS
0.538 J
0.297 J
0.185
NE
Chromium (Dissolved)
---
µg/L
0.595 J
< 0.185
< 0.185
NS
NS
NS
NS
< 0.185
0.265 J
0.185
180^' x
Cobalt
54
µg/L
140
68.6
39.7
NS
NS
NS
NS
58.2
3.57
0.077
4$
Page 1 of 3

TABLE 6
SURFACE WATER FIELD AND ANALYTICAL RESULTS
STRUCTURAL FILL AREA 1
QUARTERLY WATER QUALITY MONITORING REPORT
APRIL 2024 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLETCHER, NC
Parameter
SWS ID
Units
Area 1 Surface Water Sample Locations
MDL
15A NCAC 02B
Standard (Class B)3
SW-2-Al1
SW-3-Al
SW-46-Al
SW-4C-Al2
SW-5-Al2
SW-6-Al2
SW-8-Al2
SW-9-Al
SW-10-Al
Cobalt (Dissolved)
---
µg/L
148
70.2
25.9
NS
NS
NS
NS
64.0
1.95
0.077
NE
Copper
---
µg/L
6
3 J
3 J
NS
NS
NS
NS
4 J
11
1
NE
Copper (Dissolved)
---
µg/L
6
2 J
2 J
NS
NS
NS
NS
3 J
11
1
3.6^'t
Fluoride
---
mg/L
0.30
0.11
0.06 J
NS
NS
NS
NS
0.08 J
0.06 J
0.0479
1.8
Total Hardness
340
mg/L (CaCO3)
79.2
131
87.7
NS
NS
NS
NS
110
48.7
NE
NE
Iron
131
µg/L
1040
741
1590
NS
NS
NS
NS
955
827
4
11000*
Iron (Dissolved)
---
µg/L
973
573
649
NS
NS
NS
NS
594
443
4
NE
Lead
376
µg/L
0.111
0.616 J
0.1011
NS
NS
NS
NS
0.162 J
< 0.037
0.037
NE
Lead (Dissolved)
---
µg/L
0.106 J
0.061 J
0.057 J
NS
NS
NS
NS
0.056 J
< 0.037
0.037
14^'t
Magnesium
342
mg/L
10.8
14.4
8.75
NS
NS
NS
NS
10.9
4.73
0.008
NE
Magnesium (Dissolved)
---
mg/L
10.9
13.9
7.07
NS
NS
NS
NS
11.6
4.48
0.008
NE
Manganese
132
µg/L
931
1240
921
NS
NS
NS
NS
1190
261
1
100*
Manganese (Dissolved)
335
µg/L
953
1200
687
NS
NS
NS
NS
1200
227
1
NE
Mercury
397
µg/L
< 0.01
< 0.01
< 0.01
NS
NS
NS
NS
< 0.01
< 0.01
0.01
0.012
Mercury (Dissolved)
---
µg/L
< 0.01
< 0.01
< 0.01
NS
NS
NS
NS
< 0.01
< 0.01
0.01
NE
Molybdenum
152
µg/L
< 0.18
< 0.18
< 0.18
NS
NS
NS
NS
< 0.18
< 0.18
0.18
2,000$
Molybdenum (Dissolved)
---
µg/L
< 0.18
0.769 J
< 0.18
NS
NS
NS
NS
< 0.18
< 0.18
0.18
NE
Nickel
377
µg/L
309
193
99.9
NS
NS
NS
NS
149
8.25
0.256
NE
Nickel (Dissolved)
---
µg/L
328
198
65.2
NS
NS
NS
NS
167
4.34
0.256
140^'t
Potassium
183
mg/L
2.03
3.96
2.75
NS
NS
NS
NS
3.52
1.40
0.031
NE
Potassium (Dissolved)
---
mg/L
2.03
3.86
2.18
NS
NS
NS
NS
3.62
1.35
0.031
NE
Selenium
322
µg/L
< 0.193
0.314 J
0.647 J
NS
NS
NS
NS
< 0.193
2.36
0.193
NE
Selenium (Dissolved)
---
µg/L
0.227 J
0.287 J
1.28
NS
NS
NS
NS
0.264 J
2.56
0.193
3.1&
Sodium
---
mg/L
7.79
7.43
5.88
NS
NS
NS
NS
7.19
3.55
0.017
NE
Sodium (Dissolved)
---
mg/L
7.70
7.23
4.82
NS
NS
NS
NS
7.24
3.40
0.017
NE
Strontium
315
µg/L
74
135
104
NS
NS
NS
NS
110
102
1
NE
Strontium (Dissolved)
---
µg/L
74
130
100
NS
NS
NS
NS
113
101
1
NE
Sulfate
194
mg/L
85
110
38
NS
NS
NS
NS
86
44
0.0428
NE
Thallium
311
µg/L
< 0.041
< 0.041
< 0.041
NS
NS
NS
NS
< 0.041
< 0.041
0.041
2$
Page 2 of 3

TABLE 6
SURFACE WATER FIELD AND ANALYTICAL RESULTS
STRUCTURAL FILL AREA 1
QUARTERLY WATER QUALITY MONITORING REPORT
APRIL 2024 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLETCHER, NC
Parameter
SWS ID
Units
Area 1 Surface Water Sample Locations
MDL
15A NCAC 02B
Standard (Class 13)3
SW-2-Al1
SW-3-Al
SW-46-Al
SW-4C-Al2
SW-5-Al2
SW-6-Al2
SW-8-Al2
SW-9-Al
SW-10-Al
Thallium (Dissolved)
---
µg/L
< 0.041
< 0.041
< 0.041
NS
NS
NS
NS
< 0.041
< 0.041
0.041
NE
Total Dissolved Solids
343
mg/L
159
212
145
NS
NS
NS
NS
192
68.0
25
NE
Total Suspended Solids
209
mg/L
7
6
10
NS
NS
NS
NS
14
< 5
5
NE
Vanadium
213
µg/L
< 0.114
< 0.114
0.125 J
NS
NS
NS
NS
0.204 J
< 0.114
0.114
NE
Vanadium (Dissolved)
---
µg/L
< 0.114
< 0.114
< 0.114
NS
NS
NS
NS
< 0.114
< 0.114
0.114
NE
Zinc
---
µg/L
135
62
39
NS
NS
NS
NS
55
8J
4
NE
Zinc (Dissolved)
---
µg/L
138
58
26
NS
NS
NS
NS
56
6 J
4
36^'t
Notes:
Analytical data presented in this table reflect the Duke Energy Biological Analytical Data Storage System (BASS) as of 04/02/2024.
Samples collected April 1, 2024.
Bold concentrations are equal to or greater than the 15A NCAC 02B Standard (for pH bold indicates a measurement less than or greater than the indicated range).
1- Surface water sample location SW-2-Al is an approved background monitoring location.
Z - Surface water sample locations SW-6-Al and SW-8-Al are inactive and were not sampled. SW-4C-A1 and SW-5-Al were not sampled due to insufficient flow.
a - 15A NCAC 02B Standards for Surface Water - 15A NCAC 02B Standards for Class C surface waters. North Carolina surface water and wetland standards (effective September 1, 2022).
April 2024 data represent a one-time, single sample; therefore, compliance with either the acute or chronic 02B standards for dissolved constituents presented in 15A NCAC 02B .0211 (11)(e) cannot be determined
For 15A NCAC 02B Standards and ISTVs with acute and chronic criteria, the acute criteria are considered more applicable to grab sampling; therefore, those values are presented.
ISTV for Surface Water - In -stream target values established per 15A NCAC 02B .0202 and .0208.
USEPA Criteria for Surface Water - U.S. Environmental Protection Agency National Recommended Water Quality Criteria
The laboratory reporting limit for mercury is greater than the 02B standard.
$ - An exceedance of a published ISTV is not automatically a violation of the water quality standard for toxicity. Comparison value presented is the lesser of the Aquatic Life & Secondary Recreation or Fish Consumption value.
- ISTV is based on acute sampling method described in 15A NCAC 02B (11)(e). Compliance with acute instream standard is not applicable to sampling method. An exceedance of a published ISTV is not automatically a violation of the water quality standard for toxicity.
&- Selenium standard for lotic water based on a 30-dayaverage. Not applicable to the sampling method and provided for screening purposes only.
USEPA National Recommended Water Quality Criteria are not a regulation, nor do they impose a legally -binding requirement. Therefore, comparisons with these criteria are for situational context.
Comparison criteria based on acute sampling method described in 15A NCAC 02B (11)(e). Compliance with acute instream standard is not applicable to sampling method and provided for screening purposes only.
< - Concentration not detected at or greater than the adjusted reporting limit.
t - Hardness -dependent standard calculated using 25 mg/L hardness and not actual in -stream hardness value. Provided for screening purposes only.
x - Hardness -dependent standard for chromium III calculated using 25 mg/L hardness and not actual in -stream hardness value. Provided for screening purposes only.
--- - no applicable SWS ID
µg/L - micrograms per liter
µmhos/cm - micro -ohms per centimeter
Deg C - Degrees Celsius
1 - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
MDL - Laboratory Method Detection Limit; MDL values presented are for samples not diluted by the laboratory during analysis.
mg/L - milligrams per liter
mV - millivolts
NCAC - North Carolina Administrative Code
NE - not established
NS - not sampled
NTU - nephelometric turbidity units
S.U. - standard units
SWS ID - Solid Waste Section Identification Number
USEPA - United States Environmental Protection Agency
Prepared by: CS Checked by: ADW
Page 3 of 3

TABLE 7
FIELD AND ANALYTICAL RESULTS GREATER THAN OR EQUAL TO SURFACE WATER QUALITY STANDARDS
STRUCTURAL FILL AREA 1
QUARTERLY WATER QUALITY MONITORING REPORT
APRIL 2024 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLETCHER, NC
Site
15A NCAC
Background
Parameter
Sample ID
Result
Units
02B
Cause and Significance
Concentration
Standard
Ranger
SW-2-Al
4.2
Background surface water sample location; naturally occurring.
SW-4B-A1
5.9
Within background pH range; naturally occurring.
pH
S.U.
6.0-9.0
4.2-6.8
SW-9-Al
5.6
Within background pH range; naturally occurring.
SW-10-Al
1 5.6
Within background pH range; naturally occurring.
Notes:
Analytical data presented in this table reflect the Duke Energy Biological Analytical Data Storage System (BASS) as of April 4, 2024.
15A NCAC 02B Standards for Class B surface waters - North Carolina surface water and wetland standards (effective September 1, 2022).
- Background ranges are based on data from approved background surface water monitoring location SW-2-Al through April 2024.
NCAC - North Carolina Administrative Code
S.U. - standard units
Prepared by: CS Checked by: ADW
Page 1 of 1

TABLE 8
PIEZOMETER WATER LEVELS
STRUCTURAL FILL AREA 1
QUARTERLY WATER QUALITY MONITORING REPORT
APRIL 2024 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLETCHER, NC
Well ID
Date
TOC Elevation
(NAVD 88)
Depth to Water
(Ft-BTOC)
Groundwater Elevation
(NAVD 88)
PZ-1
4/18/2024
2,143.72
31.95
2,111.77
PZ-2*
4/18/2024
2,148.35
33.25
2,115.10
PZ-2S
4/18/2024
2,148.28
51.88
2,096.40
PZ-3
4/18/2024
2,145.42
32.49
2,112.93
PZ-3D*
4/18/2024
2,144.60
30.03
2,114.57
PZ-4
4/18/2024
2,148.33
30.35
2,117.98
PZ-5
4/18/2024
2,121.94
10.94
2,111.00
PZ-6
4/18/2024
2,125.23
10.88
2,114.35
PZ-7^
4/18/2024
2,146.72
32.80
2,113.92
Notes:
* - Piezometers are screened below the geosynthetic clay liner to monitor groundwater levels.
A - Piezometer is located outside the coal combustion product limits in the soil only corridor.
ft - feet
BTOC - below top of casing
TOC - top of casing
NAVD 88 - North American Vertical Datum of 1988
Prepared by: KHF Checked by: CS CSM
Page 1 of 1

Quarterly Water Quality Monitoring Report — April 2024 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
APPENDIX A
GROUNDWATER SAMPLING LOGS
L7
synTerra
Science & Engineering Consultants

❑CAMA ❑CCR❑Landfill ❑NPDES ❑ DGW❑ASW ❑LRB❑ SPECIAL STUDY
FIELD SAMPLING LOG DUKE
0' E R'
ete4 5 elll ID. Ih'i 1 v -- 7f Date:
V jUKOUNDWiYATER SAMPLEuSURFACE WATER SAMPLE ❑LEACMATE SAMPLE ❑WLO ❑ WELL DEVELOPMENT
FIELD STAFF: WEATHER: _�19IINNY ❑ PARTLY CLOUDY ❑ OVERCAST ❑ RAIN S QWiil AIR TEMP: 'P
COMPANY: UKE ENERGY FIELD METER TYPE/ SERIALLJ #: �(� �G�
OTHER: TURQIDIMETER TYPE/ SERIAL a: �-
START PURGE TIME: SAMPLE COLLECTION TIME:
PUMPITUBING INTAKE DEPTH:—) 4 0 (ft) DEPTH TO WATER: 7, (ft) MULT FACTOR*• 0.163 I1radiu3112j2B,14-7
WELL DIAMETER: in) HEIGHT OF WC: (ft) WELL VOLUME:
--
WELL (ft} TOTAL VOLUME PURGED: ' ,
TYPE OF PUMP: Bladder Peristaltic 12 Volt I
Grundfos
Other {
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING: p
❑ ubin Pump Inspected L"� {� cs Low FfoWv Sampling Stahifizatian Criteria
oadutring Bad ❑Pump Bad ChangedlCleaned [-]Correct Next Even# • pH 0.1 standard unit
Additional Motes: • SpecNic Conductance :k 5% in VS/cm
00 t 02 mWL or 10% saturation
= Turbidity loss than 1 n tart re
IS REDEVELOPMENT NEEDED M.0 NTUS)? ❑ YESO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? 23YES ❑ 0
IS A TURBIDITY METER DUPLICATE REQUIRED? []YES NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? ❑ YES 7NO
IS. THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE (NTU) DUPLICATE 2 TU}
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR None H2S: Petroleum Earthy Musty Undetermined
ODOR STRENGTH one. Minor Strong
ADDITIONAL NOTES: APPEARANCE a Cloudy Turbid Redllmn Film an Surface Sheen Fines Floe
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
SAD
NONE
GOOD
1 BAD
NONE
GOOD
BAD.
NONE
GOOD
BAD
NONE
Version 1.2 KBVISea 09129/2022 HFB

E]CAMA ]CCR ❑Landfill []NPDES ❑ DGWE]ASW ] LRB ❑ SPECIAL STUDY
SAMPLE
FIELD SAMPLING 10_.
Well/SW ID:
®ate: L-111
WATER SAMPLE []LEACHATESAMPLE F-�WLD
WELL DEVELOPME
FIELD STAFF: fy ilv) Nr
COMPANY: DUKE ENERGY WEATHER: SUNNY [PARTLY CLOUDY ❑OVERCAST ❑
FIELD METER TYPEI SERIAL#:IN -( `R S TE}P:-F
❑ OTHER:
TYPE/SERIAL; - - <
START PURGE TIME: SAMPLE COLLECTION TIME: - L
PUMPITUSING INTAKE DEPTH: (it}
DEPTH TO WATER: 2,{ft) WELL DIAMETER: MULT FACTOR ": 0-163 I {rsdius112}s•8.14•T.48J
(in)
HEIGHT OF WC: (R} WELL VOLUME:
WELL DEPTH: =�� -(2 (g) (
gal
TOTAL VOLUME PURGE
TYPE OF PUMP: Bladder
PURGE METHOD: Peristaltic 12 Volt. Grundfos.
Other( �
SAMPLING METHOD:
PUMP SETTING: R D
❑ Tubin ump Inspected WSo (see) (said
Tubing Bad ]Pump Bad ChangedtCieaned[]Correct Next �.—
E]GOodvent
Additional Notes-
- "'ww VOLUME
TIME LEVEL RATE REMOVED TEMPERATURE
(FT) (mL/min) (gallons OR mL) (°C)
jXxx) (x) (x.xx)
IS REDEVELOPMENT NEEDED NO NTUS)?
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES ZO:
IS THE TURBIDITY METER. DUPLICATE TAKEN YES 7 O
WITHIN
FINAL SAMPLE OBSERVATIONS: N 15°�6❑YES QNE
DETECTED ODOR
one H25
ODOR STRENGTH
o Minor
ADDITIONAL MOTES: PPEA CE Isar rlmflrl.
Low Flow Sam Iin
Stabilization Criteria
• pH
COnductance
t 0.1 standard unit
t 5% In }iS1Cm
SSPOCMC
• Tutbldfly
t 0.2 mg/L or saturation
less than 10 NTUs
PH I ORP I TURBIDITY
WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? YES ❑ NO
IS THE LOCATION FIELD VEHICLE ACCESSIBLE? 0 YES Q NO
DUPLICATE 1 _ _{►BTU) DUPLICATE 2 (NTU)
Petroleum
Strong
Tr .i.i1
Earthy
Musty Undetermined
version 1.2 Revised 09/29/2022 HPB
Floc

jCAMA 1CCR Landfill DNPDES DGW�ASVII ❑LRED SPECIAL STUDY
FIELD SAMPLING LOG
Site: Well/SW ID: _
I�GROUNDWATER SAMPLE❑SURFACE WATER SAMPLE LEACH ASETA MPLE
—�__ ❑
FIELD 5TAF — -
DUKE
ENERC
Date:
WLO WELL DEVELOPMENT
F' WEATHER: 0SUNNY PARTLY CLOUDY r�a-yyOVERCAST
COMPANY: DUKE ENERGY SKRAIN 0SNOW ❑ i J`-F
R TEMP:
FIELD METER TYPE/ SERIAL #; OTHER: TURBIDIMETER TYPE/ SERIAL #:_ Cf ��
START PURGE TIME:
PUMPITU13ING INTAKE DEPTH: U SAMPLE COLLECTION TIME:
(ft) DEPTH TO WATER: �' MULT FACTOR I'rraausnz z�.ia�.aal
WELL DIAMETER: � O (�) •_• 0.183 }
(in) HEIGHT OF WC: ��
WELL DEPTH: (n) � (�) WELL VOLUME:
TYPE OF PUMP:
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
Bladder Peristaltic 12 Volt
TubIN ump Inspected Ipsfr rSB�r rSB��
oodTubing Bad Pump Bad Changed/Cleaned Correct Next Event
Additional Notes:
TOTAL VOLUME PURGED: d • (gal
Grundfos j Other(
Low Efovu Samplin StafJilizati)n Criteria
PH t 0.1 standard unit
Specific Conductance t S% in IJS/cm
DO n __
IS REDEVELOPMENT NEEDED M0 NTUS)? ❑
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
YE5
NO
IS A TURBIDITY METER DUPLICATE REQUIRED? El YE
O WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? EKES NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? YES IS THE NO DUPLICATE CATEATION FIELD VEHICLE ACCESSIBLE?�YES ❑ NO
FINAL SAMPLE OBSERVATIONS: (NTu) D LICATE 2 - (NTu)
DETECTED ODOR on H2S Petroleum
ODOR STRENGTH
Minor Strong
ADDITIONAL NOTES: APPEARANCE Cloudy Turbid
WELL TAG PROTECTIVE CASING LOCK
GOOD BAD NONE GOOD BAD NONE GOOD BAD NONE
Earthy Musty Undetermined
Red/iron Film On Surface Sheen Fines FI
DUST CAP CONCRETE PAD
50D BAD NONE GOOD BAD NONE
Version 1.2 Revised 09/29/2022 HPB

[:]LAMA ❑CCR Landfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY.
Site: A54
FIELD SAMPLING LOG
Well/SW ID: NJW45- o (
Date: Y-1-6'y
V ot DUKE
ENERM
ElGROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑WLO. [:]WELL DEVELOPMENT
FIELD STAFF: ffL WEATHER: ❑SUNNY []PARTLYCLOUDY ❑ OVERCAST ❑RAIN []SNOW AIR TEMP: 'F
COMPANY: ® DUKE ENERGY FIELD METER. TYPE/ SERIAL #: -?519g
❑ OTHER: TURBIDIMETER TYPE/ SERIAL #: oi(n
START PURGE TIME: I rl3a SAMPLE COLLECTION TIME: I qSJ
5 R DEPTH TO WATER: 37413 (ft) MULT FACTOR *: 0.163 I"(radius112)2.'3.14.7.4el
PUMP/TUBING INTAKE DEPTH: _
WELL DIAMETER: ZU (in) HEIGHT OF WC. r-%.`D-) 00 WELL VOLUME: Z.G{ 1 (gal)
WELL DEPTH: TOTAL VOLUME PURGED: (" i (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
r
e
o
0 Tubin /Pump Inspected I [ten I o--) I [5!!I Low viow Sam in nl atauzauon k raer,a
❑Good [Tubing Bad []Pump Bad ❑Changed/Clean.ed []Correct Next Event PH d: 0.1 standard unit
• Specific Conductance f 5°k: In NSfcm
Additional Notes: DO t 0.2 mgtL or 10%4 saturation
Turbidity less than 10 NTUs
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
TIME
(FT)
(x.xx)
(mLlntin)
(x)
(gallons OR nnL)
(x:xx)
('C)
(x)
(mg/L)
(x.xx)
(NSIcm)
(z)
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
to �I S
-t &0
2
L435
312
250
b.Sv
I S1.
1 L
aqZ
`1, 2fi Y
Sc
Z. I
[a5�
39.95
210
G7v
i5
1<5�
zb
z�
usb
.�
tltt
3 Vt S
M
1.53
zq
Lt•2l
k70
2.2.
IiwA
19.`i4
zlw
1- 15
14
1.50
vt
q,U
qa1
14
ttw'►
3h.g5
�u�
r•5
t�l
r.$2
23
Y.
[q�
�•"t
PLLASt KLFtK l V r tit bAUK Vr i r115 antr i kr ( rrC lrrlmrc r HDVyr— r.7 r•V LL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? DYES ENO
IS ATURBIDITY METER DUPLICATE REQUIRED? ❑YES — NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?❑YES ❑ NO
IS THE TURBIDITY METER DUPLICATE.TAKEN, WITHIN 15%? ❑ YES []NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR on H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH Minor Strong
ADDITIONAL NOTES: APPEARANCE CI r Cloudy Turbid Redllron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
version i.z McVisea umicW/V4Z nrD

❑CAMA [JCCR❑Landfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY
FIELD SAMPLING L �E
.:
E
Se e: eHI I®: Date:
GROUNDWATER SAMPLE❑SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑WLO ❑ WELL DEVELOPMENT
FIELD STAFF:_ A? WEATHER: ..SUNNY ❑ PARTL CLOUDY ❑ OVERCAST ❑ RAIN SNOW AIR TEMP. F
COMPANY: DUKE ENERGY FIELD METER TYPE/ SERIAL A. Z . 3rO
❑ OTHER: TURBIDIMETER TYPE/ SERIAL #: -
START PURGE TIME: 3
SAMPLE COLLECTION
TIME:
PUMP/TUBING INTAKE. DEPTH:
(ft) DEPTH TO WATER: - L 5 (ft)
MULT FACTOR': 0.163
WELL DIAMETER: 2_
Cn)
['01dhW12)2'3A47.4E)
HEIGHT OF WC:
WELL VOLUME:
(gat)
WELL DEPTH:
(ft)
TOTAL VOLUME PURGED: / (gal}
TYPE OF PUMP:
Bladder Peristaltic 12 Volt. Grundfos
Other { }
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
El TubingtPump Inspected
9 i i cs«i
Low Flow Samplinq
Stabilization Criteria
©Good LITubing Bad ❑Pump Bad
Changed/Cleaned []Correct Next Event
pH
* 0.1 standard unit
Additional Notes:
Specit(c Conductance
t 5% In pS/cm
D
t 0.2mg1L or 10°% saturation
•
Turbidity
less than 10 NTUs
WATER FLOW
LEVEL RATE
TIME
VOLUME SPECIFIC
REMOVED TEMPERATURE DO CONDUCTANCE PH
ORP TURBIDITY
(FT) (mL/min)
(gallons OR mL) (°C) (Mg►L)
(PS/cm) (su)
(mv) (NTU)
(x.xx) W
(x;xx) (x) (x.xx)
W (x.xx)
($) (x.x)
017 � 7 -
--31
Lj >
s� c/
C 'i
IV-4 52-5
)`
Ll.
E-7E
PLEASE REFER TO THE BACK OF TH15 S E IF THE CHART ABC' --
IS REDEVELOPMENT NEEDED NO NTUS)? U YES 4 NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15 %? ❑ YES [] NC
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR. fie H2S
ODOR STRENGTH one Minor
ADDITIONAL NOTES: APPEARANCE ear Cloudy
WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? ES NO
IS THE LOCATION FIELD VEHICLE ACCESSIBLE?DY[IES ❑ NO
DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
Petroleum
Strong
Turbid
Earthy Musty Undetermined
Red/Iran Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised 09129/2022 HPB

❑CAMA ❑CCR ELandtill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY,
FIELD SAMPLING LOG
Site: A54 Well/SW ID: Mw"7 _ t "
Date:
�DUKE
ENERGY
112-1 GROUNDWATER SAMPLE [—]SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: G3 Z WEATHER: ❑SUNNY ❑ PARTLY CLOUDY ❑ OVERCAST ❑ RAIN ❑SNOW AIR TEMP: •F
COMPANY: Q DUKE ENERGY FIELD METER TYPE/ SERIAL #: ff0d
❑OTHER: TURBIDIMETER TYPE//SERIAL #: 01V&
START PURGE TIME: 1 `III SAMPLE COLLECTION TIME: (` 2-5
PUMPITUBING INTAKE DEPTH: rs (ft) DEPTH TO WATER: '72 (ft) MULT FACTOR •..0,1es Nradiusl12)2.114"7;48I
WELL DIAMETER: 20 (in) HEIGHT OF WC: I (ft) WELL VOLUME: 2.1,11 (gal)
WELL DEPTH: Z v.s7 (ft) TOTAL VOLUME PURGED: �'Sti (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt.
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
P
A
D
❑ Tubin !Pump Inspected
(- isec) mq) Low Flow Sampling Stabilization Criteria
_
❑Good L fubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event PH f 0.1 standard unit
Additional Notes: Specific Conductance 5% In ps/cm o
• DO t 0.2 mg/L or 10.E saturation
• Turbidity less than 10 NTUs
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
TIME
(FT)
(x.xx)
(mUrnin)
(x)
(gallons OR mL)
(x.xx).
VC)
(x)
(mg/L)
(x.xx)
(PS/Cm)
(z)
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
I H!
5.u-L
a''`'
O.0
( `[
K r2
31i
Lt 73
Y8 3
8. �.
140
S.tp
v,yp
13
`i•!IS
3.1
q.70
K7Z
3,:1
ty
I
0,6b
t3
it.2l
35
Y•6,1
17D
3.G
14Z>s..IU
2r,V
O,o
13
K.Z�
3�
N,b
Y67
3•'L
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? []YES [INO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES ❑ NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?[j YES ❑.NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR a H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH one Minor Strong
ADDITIONAL NOTES: APPEARANCE CI ar Cloudy Turbid Red/Iron Film on. Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

❑CAMA ❑CCR❑Landfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY
Site: &14
FIELD SAMPLING LOG
WeIIISW ID: /AW- 9' 4 1
Date:
GROUNDWATER SAMPLE❑SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑WLO ❑ WELL DEVELOPMENT
FIELD STAFF: �� WEATHER: []SUNNY [I PARTLY CLOUDY ❑OVERCAST ❑RAINJ❑OW AIR TEMP: •F
COMPANY: 0 DUKE ENERGY FIELD METER TYPE/ SERIAL#: SCC��I
❑ OTHER: TURBIDIMETER TYPE/ SERIAL #:ycyi.
START PURGE TIME: 1 33L SAMPLE COLLECTION TIME. I3 SO
PUMP/TUBING INTAKE DEPTH: Z' (M. DEPTH TO WATER: tl, 7t (h) MULT FACTOR *• C063 I•jraatusHz]2 3.fd`7.4e]
WELL DIAMETER: ;?-° (in) HEIGHT OF WC: t�,2q (ft) WELL VOLUME: Z,16 (gal)
WELL DEPTH: {ft) TOTAL VOLUME PURGED: U.°(y (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:.
P
H
6
(ps] (sec) (sec) LOW t'IOW Sampling JiaDnlZaiioui uriterla
❑ Tub' !Pump Inspected
❑Good [Tubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event pH 0:1 standard unit
Additional Notes: Specific Conductance t.5% in pSlcm
• DO f 0.2. mgtL or 104/4 Saturation
• Turbidity less than 10 NTUs,
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
TIME
(FT)
(x.xx)
(mLlmin)
(x)
(gallons OR mL)
(x.xx)
VC)
W
(mglL)
(x.xx)
(PS/CM)
W
(Su)
(x.xx)
(rnv)
W
(NTU)
(x:x)
t33b
(l, `0
150
a•W
1
j.t,
2t1
j.°t0
7a`I
q(
0.35
14
b,q ]
216
3,14
74o
1� !
0•5S
14
0,71
2Iq(
.q7
751
3.o
IVA-)
iG8(0
i$t?
6.7;
0.65
2rZ.
13,011
75b
3.1
i35u
YL r-A.JC m=r r-m i i rar- om%,n %rr 1 rna any= �r n= v
IS REDEVELOPMENT NEEDED (>10 NTUS)?
❑ YES Q
NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? F1YES
❑NO
IS A TURBIDITY METER DUPLICATE REQUIRED?
❑ YES
NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?
YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN
15%?
❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2
(NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR
E�fo e
H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH
o e
Minor Strong
ADDITIONAL NOTES: APPEARANCE
ar
Cloudy Turbid Red/Iron Film on Surface Sheen
Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
uc1awiE 1.c ncviacu wg,4Q —.'. -

CAMA ❑CCR❑Landfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY,
FIELD SAMPLING LOG
Site: OS 4 Well/SW ID: Nlw-�-A I
Date: --
� KE
ENERGY
❑GROUNDWATER SAMPLE❑SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑WLO ❑ WELL DEVELOPMENT
FIELD STAFF: 92. WEATHER: ❑SUNNY ❑PARTLY CLOUDY ❑ OVERCAST ❑RAIN ❑SNOW AIR TEMP: "F
COMPANY: ❑i DUKE ENERGY FIELD METER TYPE/ SERIAL #: 95rs8L
❑ OTHER: TURBIDIMETER TYPE/ SERIAL M grun
START PURGE TIME: ►3uU SAMPLE COLLECTION TIME: t 320
PUMP/TUBING INTAKE DEPTH:
ZL 4 (61 DEPTH TO WATER: 7-Z, 4u (ft) MULT FACTOR*• 0-163 ]*(radius/l2)2.3.147.48]
WELL DIAMETER: 2.0 (in) HEIGHT OF WC: f C (A). WELL VOLUME: L'tc (gal)
WELL DEPTH: 3 1 • S () TOTAL VOLUME PURGED: 6.9 S (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( ]
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
P
R
u
❑ Tubin m !Pup Inspected cPs� (Se`r (see)
❑Good.HTubing Bad []Pump Bad ❑Changed/Cleaned ❑Correct Next Event
Additional Notes:
Low Flow Sampling Stabilization Criteria
• pH t 0.1 standard unit
• Specific Conductance f 5% In NSlcm
• DO ± 0.2 mg/L or 10% saturation
• Turbidity less than 1.0 NTUs
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
TIME
(FT)
(x.xx)
(mL/min)
(x)
(gallons OR mL)
(x.xx)
VC)
(x)
(mg/L)
(x.xx)
(PS/CM)
(x]
(su)
(x.xx)
(inv)
W
(NTU)
(x.x)
f 3a %
Z7. be
O/L5
it
K `t'
13 i
5.9 Z
3 r'7
Z K
13�1
21.�5
0.50
17
3.55
l3$
S``tq
940
r 1
0. 7o
I'?
;. $
1110
6.01
36'
?,o
17
3A
1q-L
6.03
3 a
t'I
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE 1S FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES 0 NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES?]YES [:]NO
IS A. TURBIDITY METER DUPLICATE REQUIRED? ❑YES LINO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? ❑ YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR N9Dg H2S Petroleum
ODOR STRENGTH q.le/ Minor Strong
ADDITIONAL NOTES: APPEARANCE er Cloudy Turbid
Earthy Musty Undetermined
Redliron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD.
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

❑CAMA ❑CCR❑Landfill ❑NPDES ❑ DGWOASW ❑LRB ❑ SPECIAL STUDY
IELD L, SAMPLING G `'
Site:Well/SW®. 1�''� _ j Date.
❑GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE WLO
_ ❑ ❑WELL DEVELOPMENT
FIELD STAFF: t M WEATHER; ❑SUNidY �PEIRTLY CLOUDY ❑ OVERCAST
COMPANY: DUKE ENERGY ❑RAIN SNOW AIR TEMP:tO •F
FIELD METER TYPE! SERIAL M
❑ OTHER: TURBIDIME'TER TYPE/ SERIAL5-
START PURGE TIME: —�t
PUMPITUBING INTAKE DEPTH: (ft)
WELL DIAMETER: {n)
WELL DEPTH: (f
TYPE OF PUMP:
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
-i-- SAMPLE COLLECTION TIME:
DEPTH TO WATER: (ft) MULT FACTOR. *: 0.103 r(radkW12)23.14-7.481
HEIGHT OF WC: r (ft} WELL VOLUME:
(gal)
TOTAL VOLUME PURGED: r {gaq
Peristaltic Volt Grundfos Other(
El Tublawpump Ins, ted +�7 c9e�7 isec�
[/]Good ❑ ubing Bad ❑Pump Bad Change&Cfeaned ❑Correct Next Event
Additional Notes:
IS REDEVELOPMENT NEEDED (>10 NTUS)? ZYES4 NO
IS A TURBIDITY METER DUPLICATE REQUIRED? EYES. lej NO
1S THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ N
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR. H25
ODOR STRENGTH one Minor
ADDITIONAL NOTES: APPE6RANCE Clear lou'zld,
LL TAG
BAD T
BAD
Low Fiow Samnlina Stabi6zatlan Criteria
PH t 0.1 standard unit
DOInC ConduClance t 5% In pStcm
02 m9k or 10% saturation
Turbidity less than 10 NTUs
DO
SPECIFIC
CONDUCTANCE
PH
ORP
TURBIDITY
(m91L)
(PS/cm}
(su)
R T TH
BACK F THIS $HEFT
fF THE
CHART Ai3OlIt= 1±9 t:i it r
WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES?YES ❑NO
IS THE LOCATION FIELD VEHICLE ACCESSIBLE? YES ❑ NO
DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
Petroleum Earthy Musty Undetermined
Strong
Turbid Redllron Film on Surface Sheen Flnes Floc
DUST CAP CONCRETE PAD
NONE GOOD BAD NONE GOOD BAD NONE.
Version 1.2 Revised 09/29/2022 HPB

❑LAMA ❑CCR []Landfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY
FIELD SAMPLING LOG � E
E RG'
Site:Well/SW 1. - ®ate:
0GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE ❑WLO ❑ WELL DEVELOPMENT
FIELD STAFF: v -f WEATHER: jjti1NNY ❑ PARTLY CLOUDY ❑ OVERCAST
COMPANY: DUKE ENERGY FIELD METER TYPEI SERIAL
�INQS OW AIR TEMP.—"_,)
❑ OTHER: �—�
TURBIDIMETER TYPE/ SERIAL :
START PURGE TIME: � SAMPLE COLLECTION TIME:
PUMPITUBING INTAKE DEPTH:_4 DEPTH TO HHATEI?: .,
�ft) MULT FACTOR . 0.163 I-(radkW12)2.3.147.481
WELL DIAMETER: _ _.� , (") HEIGHT OF WC: (�) WELL VOLUME:
WELL DEPTH: �—� (gat)
(�) TOTAL VOLUME PURGED: D. tiS (gal)
TYPE OF PUMP: Bladder
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING: R
12 Volt I Grundfos I Other (
�TUbIR urnp Inspected F)TCjh_,_n_g_,
NBC) (� Low Flow Sarrtnlin4 Stabilization Criteria
Good [Tltbing Bad ❑Pump BaddlCieaned ❑CorreCf Next Event PH f 0.1 standard unit
Additional Notes: - Spech1c Conductance t 5%.In WS/cm
DQ f 13.2 mg1L or 10% saturation
• TurbldW 6Woa than -In NTl In
15 REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES 21 NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑ YES NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 150A? ❑ YES [] N
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR one H2S
ODOR STRENGTH ne. Minor
ADDITIONAL NOTES: APPEARAIILCE r Cloudy
O
WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES?EVYES O
IS THE LOCATION FIELD VEHICLE ACCESSIBLE? ❑ YES.0 NO
DUPLICATE 1 (NTU) DUPLICATE 2 ( U)
Petroleum
Strong
Turbid
Earthy Musty Undetermined
Redllron Film on Surface Sheen Fines
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB
Floc

134
❑CAMA ❑CCR ❑Landfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY
FIELD SAMPLING LOG �r" DUKE
ENERGI
Site: ISE Well/SW ID: \N -3- 4�3 Date: Z
®GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑ WLO [:]WELL DEVELOPMENT
FIELD STAFF:
COMPANY: }� DUKE ENERGY
rL�J OTHER:
WEATHER: SUNNY [—IPARTLYCLOUDY ❑OVERCAST ❑RAIN L]SNOW AIRTEMP:_]457_-F
FIELD METER TYPE/ SERIAL #: -)(o �& L q
TURBIDIMETER TYPE! SERIAL #: G
START PURGE TIME:
t SAMPLE COLLECTION TIME: _ kS,
PUMPITUBING INTAKE DEPTH: U (�O (g) DEPTH TO WATER: -10 (n) MULT FACTOR *: 0.163 ['(radius112)2-3.14`7.48]
WELL DIAMETER: (in) HEIGHT OF WC: o (ft) WELL VOLUME: _� (gar)
WELL DEPTH: L {t) TOTAL VOLUME PURGED: IQ, 6 & (gal)
TYPE OF PUMP:
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
Tubll /Pup Inspected
ood [mTubing Bad ❑Pumps Bad
Additional Notes:
Bladder I Peristaltic j 12 Volt
0
Grundfos I Other ( }
(Psi) (sec) I (sec) Low Flaw Sampling Stabilization Criteria
❑Changed/Cleaned ❑Correct Next Event pH i U.1 standard unit
• Specific Conductance t 5% In NSIcm
• DO t 0.2 mglL or 10% saturation
• Turbidity less than 10 NTUs
WATER FLOW VOLUME
LEVEL RATE REMOVED TEMPERATURE
SPECIFIC
DO pH ORP TURBIDITY
TIME
CONDUCTANCE
(FT) {mUmin) (gallons OR mL) (°C}
(mg/L) (PS/GM) (su) (mv) (NTU)
(x.xx) (x (x.xx) (x)
(x.xx) W (x.xx) {x) (x.x)
I{ G O
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES ❑ NO
WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? YES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑ YES ❑ NO
IS THE LOCATION FIELD VEHICLE ACCESSIBLE?&YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 �� (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR H2S
Petroleum Earthy Musty Undetermined
ODOR STRENGTH Minor
Strong
ADDITIONAL NOTES: APPEARANCE e Cloudy
Turbid Redliron Film on Surface Sheen Fines Floc
WELL TAG PROTECTIVE CASING LOCK
DUST CAP CONCRETE PAD
GOOD BAD NONE GOOD BAD NONE GOOD BAD
NONE GOOD BAD NONE GOOD BAD NONE
Version 1.2 Revised 09/29/2022 HPB

❑CAMA ❑CCR ❑Landfli1 ❑NPDES ❑ DGW❑ASW ❑ LRB ❑ SPECIAL STUDY
FIELD SAMPLING LOG
Site: - ENER�
ef11 ID:
' 1 ®ate. �r` i �
GROUNDW,�1TEla SAMPLE ❑SIiRFACE WATER SAMPLE ❑LEACFIATE SAMPLE W���O
p} ❑PMENT
FIELD STAFF: / "` WEATHER: �UNNY ❑PARTLY CLOUDY .❑ OVERCAST
COIIRPANY aDUKE ENERGY ❑RAIN SN01A1 AIR TEMP: •F
❑
FIELD METER TYPE/ SERIAL:
OTHER: `%,, n
T.URBIDIMETER TYPE/ SERIAL 9:_
START PURGE TIME:
PUMPITUBING INT7MtEi0n)
ft} SAMPLE COLLECTION TIME: _
DEPTH TO WATER: F �7 = � (rt}
WELL DIAMETER: MULT FACTOR.": 0.16$ Tk147.481
HEIGHT OF WC: C (8) WELL VOLUME:
WELL DEPTH: �(a)
TYPE OF PUMP:
PURGE METHOD:
SAMPLING.METHOD.
PUMP SETTING:
Bladder f Peristatiic
Ej Tubin lamp Inspected ffCla�ng�ed/Clea�nedr_IC,,.,4
0Good Tubing Bad ❑pump Bad Next Event
Additional Notes:
. VOLUME
TIME LEVEL RATE REMOVED TEMPERATURE 1?O
(FT) (mL/min) (gallons OR mL) (C)
(x.xx) fx1 r.. __% _ {m9R)
LL
IS REDEVELOPMENT NEEDED NO NTUS)?
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES NO
IS THE TURBIDITY METER DUPLICATE TAKEN., WITHIN YES NO
❑YES ❑ NC
SAMPLE OBSERVATIONS:
DETECTED ODOR H2S
ODOR STRENGTH
Minor
ADDITIONAL NOTES: APPEIRANDE Cle� Cloudy
(gaf}
TOTAL VOLUME PURGED: (gaq
-��
12 Volt I Grundfos Other (
Law Flow Sam tin
Stabilization Criteria
• PH
Dfl 1Mc Conductance
t 0.1 standard unit
t 5% In ps/cm
• Turbidity
0.2 Mg& or 10% saturation
teas than to NTus
CONDUCTANCE I PH + ORP I TURBIDITY
4
WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? YENO
IS THE LOCATION FIELD VEHICLE ACCESSIBLE?VS ❑YES ❑ NO
DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
Petroleum
Strong
Turbid
Easy Musty Undetermined
Redllron Film on Surface Sheen Fines Floe
DUST CAP CONCRETE PAD
DOD aAD NONE GOOD BAD NONE
Version 1.2 Revised 09/29/2022 HPB

CAMA �;ICCR Di andfiA NPpES ❑ DGW�IASW ❑LRg[] SPECIAL STUDY
Site:A1L-----
DWATER SAMPLE
/%, DUKE
W �-S_ '� ENERG
Well/SW ID:
_ Date:
URFACE WATER SAMPLE __
�LEACHATE SAMPLE �WLO L DEVELOPMENT
ENT
FIELD STAFF: --' WEATHER:
COMPANY: DUKE ENERGY WEATHER. ❑SUNNYVPARTLYCLOUDY ❑OVERCAST
❑ OTHER:
FIELD METER TYpEISERIA�I �j�jZ SNO AIR TEMP.110 ^F
TURBIDIMETER TYPE/ SERIAL #:
START PURGE TIME:
BING INTAKE DEPTH: SAMPLE COLLECTION TIME:PUMPlTU
(h) DEPTH TO WATER: Z Ui1 (n) ��
WELL DIAMETER: {in} MOLT FACTOR': 0.163 Nradius/12)2.114.7.481
WELL DEPTH;
HEIGHT OF WC: (h) WELL VOLUME: -`
(ft)
(gal)
TOTAL VOLUME PURGED: (gal)
TYPE OF PUMP: Bladder
PURGE METHOD: Peristaltic 12 VOlt
Grundfos Other( )
SAMPLING METHOD. -
PUMP SETTING: P w o
Tubin /Pump Inspected �57 csaoi [sect' Low Flow Sam lin Stabilization Criteria
Good [Tubing Bad Pump Bad []Changed/Cleaned []Correct Next Event
dditional Nates: PH f 0.1 standard unit
Specific Conductance f 5% In VS/cm
DC ;k 0.2 mgrL or 10% saturation
R FLOW VOLUME Turbidity less than 14 NTUs
WATE
REMOVED D
LEVEL RATE TEMPERATURE DO SPECIFIC
(FT1 (mL/min} (gallons OR mL) ('C CONDUCTANCE pH ORP TURBIDITY
1 (x.xx) (xj (x.xx ) (mg/L) (pS/cm) su
o ` ) (x) (x.xx) ( ) (m) (NTU}
. C/ (x) (x.xx} (x(x.x)
•W D Q
� y Z
C/ ' q 4
0 �' �54_
FIELD SAMPLING LOG
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
15 REDEVELOPMENT NEEDED (>10 NTUS}? ❑YES NO
RED? YES � NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? YES ❑ NO
IS A TURBIDITY METER DUPLICATE TUS)
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ NO YES IS THE LOCATION FIELD VEHICLE ACCES51$LE?ES ❑ NO
FINAL SAMPLE 013SERVATIONS: DUPLICATE 1 �---fNTU) DUPLICATE 2 �
on Minor Strong)
DETECTED ODOR No e
H25 Petroleum Earthy Mus
ODOR STRENGTH ty Undetermined
ADDITIONAL NOTES: '°'PPEARANCE ar
Cloudy Turbid Reddron Film on Surface
WELL TAG PROTECTIVE cecu�n _ - - Sheen Fines Floc
GOOD BAD I NONE I GOOD BAD
GOOD BAD NONE
'T CAP CONCRETE PAD
BAD NONE GOOD I BAD I NON
�j (1-L
Version 1.2 Revised 09/29/2022 HPB

__j'CAMA ❑CCR L]Landfiill L__)NPDES ! DGW ]ASW ❑LRB L] SPECIAL STUDY
FIELD SAMPLING LOG tom, DUKE
Site: �" ENERG
Well/SW ID: imYU b- rj Date: 2
=TGFRZO617ND`WATER SAMPLE ❑SURFACE R SAMPLE
�LEACHATE SAMPLE WLO DWELL DEVELOPMENT
FIELD STAFFOD
— - —
COMPANY:E ENERGY WEATHER: ❑SUNNY PARTLYCLOUDY❑OVERGAST RAIN t�l W AIR TEINP:aS °FER: FIELD METER TYPE/ SERIAL
TURBIDIMETER TYPE/ SERIAL #: Cj �~
START PURGE TIME: ff��
PUMP/TUBING INTAKE DEPTH: SAMPLE COLLECTION TIME:
,tJ1/
{ft) DEPTH TO WATER: 35.WELL DIAMETER: (in) MULT FACTOR *: 0.163 r(redlus/12)z•3.W7.gsl
WELL DEPTH:
i O HEIGHT OF WC: (ft) WELL VOLUME:
(ft)
(gal)
TOTAL VOLUME PURGED: Q - 1ga1)
TYPE OF PUMP:
jrETHOD:
METHOD:
IPUMPTING:ump Inspected I�5„ubing Bad Pump Bad
dditional Motes:
WATER FLOW
TIME LEVEL
RATE
(FT)
(mL/mir
(x.xx)
(x]
Bladder Peristaltic
y 12 Volt Grundfos Other( }
(sec) {sec)
Inged/Cleaned ElCorrect Next Event
VOLUME TEMPERATURE
REMOVED
(gallons OR ML) (°C)
(x.xx) (x)
RZ
M1
am
Low Flow Sam lin Stabilization Criteria
• pH f 0.1 standard unit
• Specific Conductance t 5% in pS/crn
• DO � 0.2 mg/L or 10% saturation
Turbidity less than 10 NTUs
SPECIFIC
CONDUCTANCE
PH
(Ns/cm)
(su)
(x)
(x.xx
%Z
Z7i
'�,?2
ORP TURBIDITY
(mv) (NTU)
a%IC[0.1mC�
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE i5 FULL
IS REDEVELOPMENT NEEDED 0 NTUS}? ❑YES N NO
�YES O WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES?
IS A TURBIDITY METER DUPLICATE REQUIRED? _YES DNO
IS THE LOC
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? YES ❑ NO D PLICATEATION FIELD VEHICLE AGCESSBLE?[}YES Q NO
FINAL SAMPLE OBSERVATIONS: �(NTU r't7TiPLiCATE 2}
DETECTED ODOR 1-12S Petroleum Earthy Musty 0
ODOR STRENGTH Undetermined
Minor Strong
ADDITIONAL NOTES: APPEARANCE le
Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG PROTECTIVE CASING
GOOD BAD NONE GOOD BAD NONE GOOD BAD
DUST CAP 7
GOOD
Version 1.2 Revised 09/29/2022 HPB

❑LAMA ❑CCR❑Landfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY,
FIELD SAMPLING LOG
Site: _ qs4 WeII1SW ID: N W - 7- P
Date: '(-Z Z
.,(!� DUKE
le ENERM
[]GROUNDWATER SAMPLE [:]SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑ WLO [:]WELL DEVELOPMENT
FIELD STAFF. CY1
COMPANY: Q DUKE ENERGY
❑ OTHER:
WEATHER: []SUNNY ❑PARTLYCLOUDY ❑OVERCAST []RAIN EISNOW AIRTEMP: °F
FIELD METER TYPE/ SERIAL #: %O
TURBIDIMETER TYPE/ SERIAL #: v"ul
START PURGE TIME: QCU+� SAMPLE COLLECTION TIME: (jg YU
PUMPITUBING INTAKE DEPTH: (). DEPTH TO WATER: Z& 72 (fi) MULT FACTOR *: 0.163 [`(radius/12)2'3.14'7.48]
WELL DIAMETER: 7 ° (in) HEIGHT OF WC: uo.�la (n) WELL VOLUME:. _ b 6 (gal)
WELL DEPTH: 61,56 (ft) TOTAL VOLUME PURGED: 10-0 (gal)
TYPE OF PUMP..
Bladder
Peristaltic.
12 Volt
Grundfos
Other( )
PURGE METHOD:
SAMPLING METHOD:
r
PUMP SETTING:
e
o
bac/n
❑ Tobin/Pump Inspected L (Ps 1 i'e.) I t..) I Low Flow Sampling Stabilization Criteria
C]Good LjTubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event PH f 0.1 standard unit
Additional Notes: r IvF Specific Conductance f 5% In PS/cm; o
JS��' ep (� �1"$f K-� ,tvE�j DO 1-0.2mg1Lor10f�saturation
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mLlmin)
(x)
(gallons OR mL)
(x.xx)
(°C)
(x)
(mg/L)
(x.xx)
(PS/cm)
(x)
(su)
(x.xx)
(mV)
(x)
(NTU)
(x.x)
ar4(5
2S.91
zCA�'
0.55
(K
Iq
6,66
93Z
35
og2v
Z
2Gi)
0,10
1
16
S•vG
ti37
0-2-
2-�13
7
`t 7t.,
I
U�t 3 6
I
1- 6v
I
-7. S0
I ?�
v_ 7 `{
q Z.q
. o
09 -i
Zs-61q
?w
d�Su
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES Q NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? ❑YES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑ YES ❑'NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?[-] YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR 91.,
H2S Petroleum. Earthy Musty Undetermined
ODOR STRENGTH Minor Strong
AD❑ITIONAL NOTES: APPEARANCE Cloudy Turbid Redllron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

❑CAMA ❑CCR❑Lan dfill ❑NPDES ❑ DGW❑ASW ❑LRB❑ SPECIAL STUDY
DU KE
FIELD SAMPLING LOG ENERGY
Site. A99 WeI I1SW I D: M �- _ `� Date:
❑GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: D-L WEATHER: ❑SUNNY ❑PARTLYCLOUDY ❑OVERCAST []RAIN ❑SNOW AIRTEMP: "F
COMPANY: 0 DUKE ENERGY FIELD METER TYPE/ SERIAL #: 95-1 e1 E
❑ OTHER: TURBIDIMETER TYPE/ SERIAL #: VIVA,
START PURGETIME: '()to SAMPLE COLLECTION TIME: to IS
PUMPITUBING INTAKE DEPTH: � 3V (ft) DEPTH TO WATER: 23.40 (ft) MULT FACTOR*: 0.163 (•(radius112)23.14.7.481
WELL DIAMETER: ?.c (in) HEIGHT OF WC: q• 6o (ft) WELL VOLUME: 1. 5 & (gag)
WELL DEPTH; 53.0 (ft) TOTAL VOLUME PURGED (gaI)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Gruncifos
Other ( )
PURGE METHOD:
1
SAMPLING, METHOD:
PUMP SETTING:
A
°
0 Tubin !Pump Inspected I 1PSy I "') I (sec) Low Flow Samplinca Stabilization Criteria
❑Good [Tubing Bad ❑Pump Bad ❑Changed/Cleaned []Correct Next Event PH * 0.1 standard unit
Additional Notes: Specific Conductance * 5% In uS1cm
WL �c�5n� S i I�z • DO t 0..2mgtL or 10% saturation
• Turbldity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pFi
ORP
TURBIDITY
(FT)
(x:xx)
(mUmin)
W
(gallons OR ml-)
(x.xx)
(°C)
W.
(rng/L)
(x.xx)
(PS/CM)
W
(su)
(x.xx)
(mV.)
W
(NTU)
(x.x)
Iofs
Z3.gl
IUD
6110
7p
,i b
z t
32-S
(o-D
2K.Ji,
Ida
C--15
I
7 So
Za
S.�
cicu
2I,L(
1033
Z tW
•5S
tla
78-)
117
5.7-1
r/oZ
t-1.a
to-17
xk>$I
0,65
15
7q0
1i,
S.Z+i
t/08
lN.B
g c 3,1
•1, � 4
0,75
1
'?, 3 L
19
5. Z i.
LI 1 1
t 7.
tall
29.ST
v, 85
IS
2,29
Ira
5.3D
Efli'
f1.1
ZS.ry
tVa
a'tS
IS
1$
` f
70
Z-9 � ( i
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE 15 FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? [:]YES[—] NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? DYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑ YES — NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?© YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR 1 n0 H25 Petroleum Earthy Musty Undetermined
ODOR STRENGTH ere Minor Strang
ADDITIONAL NOTES: APPEARANCE &r Cloudy Turbid Red/Iron Film on Surface Sheen Firo Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
-Ftu&h Version 1.2 Revised 09129/2022 HPB

❑ CAMA ❑ CCR � Landf ill ❑NPDES ❑ DGW❑ ASW ❑ LRB ❑ SPECIAL STUDY
FIELD SAMPLING LOG
Site: A5A- Well/SW ID: Mw-Z- A4l
Date: 112-�?V
� DUKE
GROUNDWATER SAMPLE [:]SURFACE WATER SAMPLE❑LEACHATE SAMPLE ❑WLO ❑ WELL DEVELOPMENT
FIELD STAFF: (1,
COMPANY: Q DUKE ENERGY
❑ OTHER:
WEATHER: []SUNNY ❑PARTLYCLOUDY ❑OVERCAST ❑RAIN ❑SNOW AIRTEMP: 'F
FIELD METER TYPE/ SERIAL # 9Stkb�
TURBIDIMETER TYPE/SERIAL #:
START PURGE TIME: t tb5 SAMPLE COLLECTION TIME: 112 n
PUMP/TUBING INTAKE DEPTH: Z.S (ft). DEPTH TO WATER: 17 II (ft) MULT FACTOR ": 0.103 [•(raQiusJ12)2 3.t4•i.48]
WELL DIAMETER: (in) HEIGHT OF WC: 12, sct (ft) WELL VOLUME: Z-1 U (gal)
WELL DEPTH:_ 3�. _(it) TOTAL VOLUME PURGED: 1,00 (gat)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
P
A
°
❑ Tubing/Pump Inspected (u%) tse`� tse°y
Good. ]Tubing Bad ❑Pump Bad ❑Changed/Cleaned [—]Correct Next Event
Additional Notes:
LOW rloW barnpling Stabilization Criteria
pH :L 0.1 standard unit
Specific Conductance * 50% In pSlcm
DO t 0.2 mg/L or 10% saturation
Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(X.xx)
(mUmin)
(x)
(gallons OR mL)
(x.XX)
VC)
(x)
(mg/L)
(X.XX)
(PS/Cm)
(x)
(su)
(X.XX)
(mv)
(X)
(NTU)
(X.x)
ito7
17.E
20
6.40
ig
H•°iS
t t4:
`1,�-5
`)Is
4�L
Z.0
t
ZI
�7/
�c r
tti
(7.?,L
rL=m,3m merr-rt t v i rle mAw% uF t HIJ SHtt-_I IF THL CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? []YES S NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? AYES El No
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑ YES Q NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?M`rES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN; WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR e H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH APPEARANCE a Minor Strong
ADDITIONAL NOTES: e r Cloudy Turbid Red/Iran Film on Surface Sheen Fines Floc
WELLTAG
PROTECTIVE CASING
-LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
I BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
l
Version 1.2 Revised 09/29/2022 HPB

❑ CAMA ❑ CCR [,—]Landfill ❑ NPDES ❑ DGW❑ ASW ❑ LRB ❑ SPECIAL. STUDY.
FIELD SAMPLING LOG
Site: A54 Well/SW ID: Myi-5-.A,,(.
Date: Y-Z-zq
� KE
ENERGY
nGROUNDWATER SAMPLE❑SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑WLO [:]WELL DEVELOPMENT
FIELD STAFF: C)'L
COMPANY: /❑ DUKE ENERGY
❑ OTHER:
WEATHER: ❑SUNNY ❑ PARTLY CLOUDY ❑ OVERCAST ❑ RAIN ❑SNOW AIR TEMP: °F
FIELD METER TYPE/ SERIAL M qS 096
TURBIDIMETER TYPE/ SERIAL#: GrrTL
START PURGE TIME: f 538 SAMPLE COLLECTION TIME: I t{ck)
PUMPrrUBING INTAKE DEPTH: 27-c1P� 02 DEPTH TO WATER: ?V (ft) MULT FACTOR*:,0.163 [*(radius112)2'3.147.461
WELL DIAMETER: 10 (in) HEIGHT OF WC: (ft) WELL VOLUME: - Zql; (gal)
WELL DEPTH: 7 S 0 (ft) TOTAL VOLUME PURGED: I'°o (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other( )
PURGE METHOD:
1
SAMPLING METHOD:
1
PUMP SETTING:
a
A
o
❑ Tubing/Pump inspected
{Psq (Sec) I (sec) LUV4 r-lUW 0,211112 1IU aunl&auv v..w.—
_
❑Good ]Tubing Bad ❑Pump Bad ❑Changed/Cleaned [:]Correct Next Event PH * 01 standard unit
• Specr€cConductance t 5% In NS/cm.
Additional Notes: DO t 0.2 mg(L or 10% saturation
• Turbidity less than 10 NTUs
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE-
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
TIME
(FT}
(x.xx)
(mIJi 1n)
N
(gallons OR mL)
(x.xx)
(°C)
(x)
(mglL)
(x:xx)
(NSlcm)
(x)
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
t17.o6
o.zo
Z Z
y,w
5X r
Vo-f
7,7
t3•l�i
to.tz
0.qc?
t
3, 5�
(,:5
�1. �(I
3ti —
1
o-bo
13s
ro.13
A MT
ADr%%IC IC CI 11 1
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES NO
IS ATURBIDITY METER DUPLICATE REQUIRED? ❑YES NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ N
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR No a H2S
ODOR STRENGTH fte Minor
A nnivirW A I Kan-rr-Q- APPEARANCE l"ir Cloudy
O
WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? ❑YES ❑ NO
IS THE LOCATION FIELD VEHICLE ACCESSIBLE?,❑ YES ❑ NO
DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
Petroleum Earthy Musty Undetermined
Strong
Turbid Red0ron Film on Surface. Sheen Fines Floc
WELL TAG
PROTECTIVE CASING v
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOdD7
BAD
NONE
GOOD
BAD
NONE

❑CAMA ❑CCR ❑i Landfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL. STUDY,
Site: 45A
FIELD SAMPLING LOG
Well/SW ID: rAw"S`�,-A"[
Date: `/-Z z-i
.,C DUKE
'V ENERGY'
❑- GROUNDWATER SAMPLE❑SURFACE WATER SAMPLE❑LEACHATE SAMPLE ❑WLO ❑ WELL DEVELOPMENT
FIELD STAFF:7<
COMPANY: 0 DUKE ENERGY
❑ OTHER:
WEATHER: ❑SUNNY ❑PARTLY CLOUDY ❑OVERCAST ❑RAIN []SNOW AIR TEMP: °F
FIELD METER TYPE/ SERIAL #: '7250
TURBIDIMETER TYPE/ SERIAL #: 6116-2-
START PURGE TIME: 130G SAMPLE COLLECTION TIME: 132S
PUMPITUBING INTAKE DEPTH: [7�'� (n). DEPTH TO WATER: 15-) l (h) MU LT FACTOR *: 0.163 ['(radiust72)2*3.14'T48]
WELL DIAMETER: ZiD (in) HEIGHT OF WC: 5t7.t (h) WELL VOLUME: 5,15 (gal)
WELL DEPTH: 7(- 5 U (0) TOTAL VOLUME PURGED: 1' Zv (gal)
TYPE OF PUMP-
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
1
SAMPLING METHOD:
l
PUMP SETTING:
p
R
p
El Tubin (Pump Inspected I {�� tse" I �se�) I Low rlow oam un ataon¢anU.n U11MIla
DGood ]Tubing Bad [:]Pump Bail ❑Changed/Cleaned ❑Correct Next Event pH tstandard unit
Specific Conductance t 5%In )tSlcm
Additional Notes;
• DO f 0.2 rn / or 1094. saturation
Turbidity less than 10 NTUs
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
TIME
(FT)
(x.xx)
(mLlmin)
W
(gallons OR mL)
(x.xx)
VC)
(x)
(mg/L)
(x.xx)
(PS/CM)
(x)
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
4�jri8
l .�l?
�GL7;
G•n
S,f °l
q-7
5--70
q I
'4
!7.;o
1
q46
5.6
38 (
P
I
�. &5
7 E
k v
1 :Z�
2A0
[.
l
`I.5�
5
S,IIA
2
15►#b
zoo
I. a
is
.rLr,,HJC m=rr-m 1 tJ 1 n= ona..r% yr
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? YES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES ❑ NO IS. THE LOCATION FIELD VEHICLE ACCESSIBLE?�n YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR on H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH P1111
Minor Strong
AnnITIONAL NOTES.- APPEARANCE Cloudy Turbid Red/iron Film on Sur.face Sheen Fines. Flec
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD 1
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
SAD
NONE
GOOD
BAD
NONE
'
r
v C171V1f I— —1— poi c1-- ... —

❑LAMA ❑CCR ELandfiEl []NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY
Site: 4 S A
FIELD SAMPLING LOG
WeII1SW ID: M k)- �- M
Date: '-i- z:• 7K
� DU
KE
RGY
/❑GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: cy-
COMPANY: ❑i DUKE ENERGY
❑ OTHER:
WEATHER: ❑SUNNY ❑PARTLYCLOUDY ❑OVERCAST ❑RAIN ❑SNOW AIRTEMP: °F
FIELD METER TYPE/ SERIAL M 29 ` t6
TURBIDIMETER TYPE/ SERIAL #. G1
START PURGE TIME: I I3S SAMPLE COLLECTION TIME: _ j 1 S()
PUMPTTUBING INTAKE DEPTH: 2 (ft) DEPTH TO WATER: f ). St (ft) MULT FACTOR *: 0.163 ("(radius112)2 3.W7..48I
WELL DIAMETER: (in) HEIGHT OF WC: _ i K3 (ft) WELL VOLUME: (gal)
WELL DEPTH: 3i.Sg_ (ft) TOTAL VOLUME PURGED: G-7S (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
I
SAMPLING METHOD:
/
PUMP SETTING:
R
o
(Psp (sec) (sec) LUw r ww oani�u+ia�. LOUIIa,akw„
❑ Tubin (Pump Inspected
❑Good Tubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event pH � 0.1 standard unit
Additional Notes: • Specific Conductance ± 56% in pSlcm
DO f 0.2:mg/L or 10% saturation
tj Turbidity less than .10 NTUs
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
TIME
(FT)
( C.xx)
(mUmin)
(x)
(gallons OR mL)
(x.xx)
(°C)
(X)
(mg/L)
(x.xx)
(pSlcm)
(X)
(su)
(x.xx).
(mv)
(x)
(NTU)
(X.x)
1138
t?.,t�
I°��
o,2j
Ib
Lj.2v
`f�
tC.fs5
`1(>`
3.$
Is�ll
I�.C60
v-�(o
l5
3 6v
`f
-pia
`f�[o
z.Z.
11�M
(?,`op
v 5
t5
3.62
-c12
q
I-zs
1l47
���
i160
i,.7
)
S�
Sc�
_�,'s
g3L'
f,
YLCHJC mr-rCR 1w +nCy---
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? DYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES ❑ NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?DYES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑NO. DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR on H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH one Minor Strong
nnrwrinmai NnTFc, APPEARANCE 6t j Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOO❑
BAD
I NONE
GOOD
BAD
NONE
i

[:]LAMA ❑CCR[-�Landfill ❑NP.DES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY.
Site: 456
FIELD SAMPLING LOG
Well/SW ID:
�,6 DUKE
ENERG)
Date:
GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑ LEACHAT.E SAMPLE ❑tWLO ❑ WELL DEVELOPMENT
FIELD STAFF: CIJti
COMPANY: f DUKE ENERGY
❑ OTHER:
WEATHER: []SUNNY ❑PARTLYCLOUDY ❑OVERCAST []RAIN []SNOW AIRTEMP: °F
FIELD METER TYPE/ SERIAL M q K
TURBIDIMETER TYPE/ SERIAL M a t n
START PURGE TIME: 12W SAMPLE COLLECTION TIME: 1 7,2S
PUMPITUBING INTAKE DEPTH: (ft} DEPTH TO WATER: 1 G"b (h} MULT FACTOR *• 0.163 (*(radiusJ12J2*3A4*7,481
WELL DIAMETER: x ° (in) HEIGHT OF WC: ft
() WELL VOLUME: (gal)
WELL DEPTH: _ _5� . 6 S (ft} TOTAL VOLUME PURGED: so (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other { }
PURGE METHOD:
SAMPLING METHOD:
J
PUMP SETTING:
P
A
°
❑ Tubing/Pump /Pump Inspected 05] (sec) (see)
[-]GoodL]Tubing Bad ❑Pump Bad ❑Changed/Cfeened ❑Correct Next Event
Additional Notes:
Low Flow Sampling Stabilization Criteria
• PH
• Specific Conductance
• DO
• Turbidity
* 0.1 standard unit
:k 5% In VS/cm
f 0.2 mglL or 100,19 saturation
less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
FT ( )
(x.xx)
(mLlmin)
{x)
(gallons .ORmL)
(x.xx)
(C)
M
(mglL)
(x.xx)
{NSlcm}
W
(su)
(x.xx)
(mv)
N
(NTU)
(x.x)
1213
15-SO
ZLO
p>aR
I$
%t.rl-�
llgt
3.
-o
1211
t-1,v
I
r[.3'
('-Lz-Z
1 l-vc
7cn
G.so
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? [:]YES 0 NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? [ YES ENO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES Q NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?[] YES[:] NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR None. H2S Petroleum Earthy Musty undetermined
ODOR STRENGTH a Minor Strong
ADDITIONAL NOTES: APPEARANCE Ct r Cloudy Turbid Redliron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

`,I CAMA L, CCR DLandfill DNPDES ❑ DGW L—� ASW ❑ LRB ��
�I SPECIAL STUDY
FIELD SAMPLING LOG
Site: Well/SW ID: Vq "
UKOUNDWATER SAMPLE
FIELD STAFF:
COMPANY: W DUKE ENERGY
❑ OTHER;
WATER SAMPLE ❑LEACHATE SAMPLE
/w,, DUKE
'I. ' ENERG
Date: !Z
rrLu 1 i wFl I near...
❑SUNNY g PARTLY CLOUDY ❑OVERCAST EIRAIN
FIELD METER TYPE/ SERIAL #: ❑SNO AIR TEMP;_F
TURBIDIMETER TYPE/ SERIAL #:
START PURGE TIME;
PUMPITU13ING INTAKE DEPTH: LECTION TIME: r
WELL DIAMETER: .0 DEPTH TO WAT7tm
MULT FACTOR P(radfus/12 23 14-7 48J
�• 13,i63
{HEIGHT OF WC: 1'1WELL DEPTH: L • {ft} WELL VOLUME: -L L {r
TYPE OF PUMP:
PURGE METHOD:
�jr
SAMPLING METHOD:
PUMP SETTING:
Tubi7 ump inspected
oodTubing Bad Pump Bad
Additional Notes:
WEATHER:
Bladder
Peristaltic
❑Correct Next Event
12 Volt
TOTAL VOLUME PURGED.
{gal}
Grundfos Other~
Low Flow Sam lin Stabilization Criteria
PH f 0.1 standard unit
SPeciftc Conductance t 5% In PS/cm
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART A80VE 15 FULL
15 REDEVELOPMENT NEEDED (>10 NTUS)? Ej YES NO IS A TURBIDITY METER DUPLICATE REQUIRED? WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 5%? NOTES NO DUPLICATE 1� (14TU) DUPLICATE 2 �U O
IS THE LOCATION FIELD VEHICLE ACCESSIBLE. YES ❑ NO
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR Non
H2S Petroleum Earthy Mug
ODOR STRENGTH iY Undetermined
on Minor Strong
ADDITIONAL NOTES: APPE'°'l�,gHCE Clea Cloud
WELL TAG y Turbid Redllron Film on Surface Sheen
PROTECTIVE CASING Fines Floc
GOOD BAD LOCK DUST CAP
NONE GOOD BAD NONE GOO CONrRr=Te
n� n
BAD NONE GOOD BAD NONE GOOD BAD
Version 1.2 Revised 04/29/20 22 HPB

Quarterly Water Quality Monitoring Report — April 2024 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
APPENDIX B
GROUNDWATER LABORATORY ANALYTICAL REPORTS
L7
synTerra
Science & Engineering Consultants

DUKE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J24030520
Project Name: ASHEVILLE AIRPORT - AIRPORT FILL AREA IV - (IN-HOUSE)
Task Code: STRFL
Customer Name(s): John Toepfer, B Moeller, Josh Stowe, C Zahora
Customer Address: Asheville Airport
Lab Contact: Peggy Kendall r Phone: [phone]
Report Authorized By: pate: 4/17/2024
(Signature)
egg endall
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
Page 1 of 36
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
Collected By Sample Description
Page 2 of 36
2024007460
Asheville
Airport
02-Apr-24
10:45
AM
Connor Zahora
ASA_MW-1AR-A4R
2024007461
Asheville
Airport
02-Apr-24
11:20
AM
Connor Zahora
ASA_MW-2-A4
2024007462
Asheville
Airport
02-Apr-24
2:00
PM
Connor Zahora
ASA_MW-5-A4
2024007463
Asheville
Airport
02-Apr-24
1:25
PM
Connor Zahora
ASA_MW-5D-A4
2024007464
Asheville
Airport
02-Apr-24
11:50
AM
Connor Zahora
ASA_MW-6-A4
2024007465
Asheville
Airport
02-Apr-24
12:25
PM
Connor Zahora
ASA_MW-7-A4
2024007466
Asheville
Airport
02-Apr-24
11:29
AM
Haley Seaton
ASA_MW-9-A4
2024007467
Asheville
Airport
02-Apr-24
Connor Zahora
ASA_FD-20240402-1
2024007468
Asheville
Airport
02-Apr-24
3:00
PM
Connor Zahora
ASA_Fl3
-20240402-1500
9 Total Samples

Page 3 of 36
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals❑ Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
❑d Job Summary Report
❑d Sample Identification
❑� Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
❑� Analytical Laboratory QC Report
❑ Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑� Chain of Custody
❑� Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 4/17/2024

Certificate of Laboratory Analysis Page 4 of 36
This report shall not be reproduced, except in full.
Order # J24030520
Site: ASA MW-1AR-A4R Sample #: 2024007460
Collection Date: 04/02/2024 10:45 AM Loc code: ASA MW-lAR-A4R Matrix: GW RCRA
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q24040145
Alkalinity, Bicarbonate
11.7
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:57
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:57
SNEGLIA
Total Alkalinity as CaCO3
11.7
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:57
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24040077
Chloride
1.1
mg/L
0.1
0.0154
1
EPA 9056A
04/04/2024 18:43
BGN9034
Sulfate
0.47
mg/L
0.1
0.0428
1
EPA 9056A
04/04/2024 18:43
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040169
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/11/2024 09:31
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24040064
Aluminum (AI)
1.36
mg/L B2
0.01
0.003
1
SW 6010D
04/08/2024 11:57
CELLI06
Barium (Ba)
0.024
mg/L
0.005
0.002
1
SW 601OD
04/08/2024 11:57
CELLI06
Boron (B)
0.005 U
mg/L
0.05
0.005
1
SW 6010D
04/08/2024 11:57
CELLI06
Calcium (Ca)
3.09
mg/L
0.05
0.012
1
SW 601OD
04/08/2024 11:57
CELLI06
Copper (Cu)
0.002 J
mg/L
0.005
0.001
1
SW 6010D
04/08/2024 11:57
CELLI06
Iron (Fe)
1.50
mg/L
0.01
0.004
1
SW 601OD
04/08/2024 11:57
CELL106
Magnesium (Mg)
1.15
mg/L
0.02
0.008
1
SW 6010D
04/08/2024 11:57
CELLI06
Manganese (Mn)
0.252
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 11:57
CELLI06
Potassium (K)
2.33
mg/L
0.1
0.031
1
SW 6010D
04/08/2024 11:57
CELLI06
Sodium (Na)
2.03
mg/L
0.05
0.017
1
SW 601OD
04/08/2024 11:57
CELLI06
Strontium (Sr)
0.025
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 11:57
CELLI06
Zinc (Zn)
0.01 J
mg/L
0.015
0.004
1
SW 6010D
04/08/2024 11:57
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040070
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
04/08/2024 15:37
MHALL3
Arsenic (As)
0.116 J
ug/L
1
0.111
1
SW 6020B
04/08/2024 15:37
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
04/08/2024 15:37
MHALL3
Cadmium (Cd)
0.044 J
ug/L
1
0.032
1
SW 6020E
04/08/2024 15:37
MHALL3
Chromium (Cr)
1.68
ug/L
1
0.185
1
SW 6020B
04/08/2024 15:37
MHALL3
Cobalt (Co)
0.861 J
ug/L
1
0.077
1
SW 6020E
04/08/2024 15:37
MHALL3
Lead (Pb)
0.523 J
ug/L
1
0.037
1
SW 6020B
04/08/2024 15:37
MHALL3
Molybdenum (Mo)
0.561 J
ug/L
1
0.18
1
SW 6020E
04/08/2024 15:37
MHALL3
Nickel (Ni)
1.64
ug/L
1
0.256
1
SW 6020E
04/08/2024 15:37
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
04/08/2024 15:37
MHALL3
Thallium (TI) Low Level
0.045 J
ug/L
0.2
0.041
1
SW 6020B
04/08/2024 15:37
MHALL3
Vanadium (V) Low Level
1.26
ug/L
0.3
0.114
1
SW 6020E
04/08/2024 15:37
MHALL3
TOTAL DISSOLVED SOLIDS - Q24040060
TDS
27.0
mg/L
25
25
1
SM2540C
04/04/202412:35
HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030520
Site: ASA MW-1AR-A4R
Collection Date: 04/02/2024 10:45 AM Loc code: ASA MW-lAR-A4R
Analyte Result Units Qualifiers RDL MDL DF
TOTAL SUSPENDED SOLIDS - Q24040056
TSS 14 mg/L 5 5 1
Sample #: 2024007460
Matrix: GW RCRA
Page 5 of 36
Method Analysis Date/Time Analyst
SM2540D 04/04/2024 07:33 HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030520
Site: ASA MW-2-A4
Collection Date: 04/02/2024 11:20 AM Loc code: ASA MW-2-A4
Sample #: 2024007461
Matrix: GW RCRA
Page 6 of 36
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q24040145
Alkalinity, Bicarbonate
9.36
mg/L
5
1.7
1
SM 2320134d
04/09/2024 11:03
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/09/2024 11:03
SNEGLIA
Total Alkalinity as CaCO3
9.36
mg/L
5
1.7
1
SM 2320134d
04/09/2024 11:03
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24040077
Chloride
2.3
mg/L
0.1
0.0154
1
EPA 9056A
04/04/2024 19:03
BGN9034
Sulfate
0.28
mg/L
0.1
0.0428
1
EPA 9056A
04/04/2024 19:03
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040169
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/11/2024 09:38
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24040084
Aluminum (AI)
0.039
mg/L
0.01
0.003
1
SW 6010D
04/08/2024 13:20
CELLI06
Barium (Ba)
0.018
mg/L
0.005
0.002
1
SW 601OD
04/08/2024 13:20
CELLI06
Boron (B)
0.007 J
mg/L
0.05
0.005
1
SW 6010D
04/08/2024 13:20
CELLI06
Calcium (Ca)
1.61
mg/L
0.05
0.012
1
SW 601OD
04/08/2024 13:20
CELLI06
Copper (Cu)
0.001 J
mg/L
0.005
0.001
1
SW 6010D
04/08/2024 13:20
CELLI06
Iron (Fe)
0.023
mg/L
0.01
0.004
1
SW 601OD
04/08/2024 13:20
CELL106
Magnesium (Mg)
1.30
mg/L
0.02
0.008
1
SW 6010D
04/08/2024 13:20
CELLI06
Manganese (Mn)
0.015
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 13:20
CELLI06
Potassium (K)
0.824
mg/L
0.1
0.031
1
SW 6010D
04/08/2024 13:20
CELLI06
Sodium (Na)
1.97
mg/L
0.05
0.017
1
SW 601OD
04/08/2024 13:20
CELLI06
Strontium (Sr)
0.015
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 13:20
CELLI06
Zinc (Zn)
0.007 J
mg/L
0.015
0.004
1
SW 6010D
04/08/2024 13:20
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040089
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
04/08/2024 19:34
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
04/08/2024 19:34
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
04/08/2024 19:34
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020E
04/08/2024 19:34
MHALL3
Chromium (Cr)
0.397 J
ug/L
1
0.185
1
SW 6020B
04/08/2024 19:34
MHALL3
Cobalt (Co)
0.219 J
ug/L
1
0.077
1
SW 6020E
04/08/2024 19:34
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
04/08/2024 19:34
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020E
04/08/2024 19:34
MHALL3
Nickel (Ni)
0.466 J
ug/L
1
0.256
1
SW 6020E
04/08/2024 19:34
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
04/08/2024 19:34
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
04/08/2024 19:34
MHALL3
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
SW 6020E
04/08/2024 19:34
MHALL3
TOTAL DISSOLVED SOLIDS - Q24040060
TDS
25 U
mg/L
25
25
1
SM2540C
04/04/2024 12:35
HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030520
Site: ASA MW-2-A4
Collection Date: 04/02/2024 11:20 AM Loc code: ASA MW-2-A4
Analyte Result Units Qualifiers RDL MDL DF
TOTAL SUSPENDED SOLIDS - Q24040056
TSS 5 U mg/L 5 5 1
Sample #: 2024007461
Matrix: GW RCRA
Page 7 of 36
Method Analysis Date/Time Analyst
SM2540D 04/04/2024 07:33 HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030520
Site: ASA MW-5-A4
Collection Date: 04/02/2024 02:00 PM Loc code: ASA MW-5-A4
Sample #: 2024007462
Matrix: GW RCRA
Page 8 of 36
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q24040145
Alkalinity, Bicarbonate
11.2
mg/L
5
1.7
1
SM 2320134d
04/09/2024 11:10
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/09/2024 11:10
SNEGLIA
Total Alkalinity as CaCO3
11.2
mg/L
5
1.7
1
SM 2320134d
04/09/2024 11:10
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24040077
Chloride
2.6
mg/L
0.1
0.0154
1
EPA 9056A
04/05/2024 13:10
BGN9034
Sulfate
23
mg/L
0.5
0.0428
5
EPA 9056A
04/05/2024 13:10
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040169
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/11/2024 09:46
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24040084
Aluminum (AI)
0.103
mg/L
0.01
0.003
1
SW 6010D
04/08/2024 14:26
CELLI06
Barium (Ba)
0.092
mg/L
0.005
0.002
1
SW 601OD
04/08/2024 14:26
CELLI06
Boron (B)
0.038 J
mg/L
0.05
0.005
1
SW 6010D
04/08/2024 14:26
CELLI06
Calcium (Ca)
12.7
mg/L
0.05
0.012
1
SW 601OD
04/08/2024 14:26
CELLI06
Copper (Cu)
0.002 J
mg/L
0.005
0.001
1
SW 6010D
04/08/2024 14:26
CELLI06
Iron (Fe)
0.288
mg/L
0.01
0.004
1
SW 601OD
04/08/2024 14:26
CELL106
Magnesium (Mg)
2.80
mg/L
0.02
0.008
1
SW 6010D
04/08/2024 14:26
CELLI06
Manganese (Mn)
0.023
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 14:26
CELLI06
Potassium (K)
2.61
mg/L
0.1
0.031
1
SW 6010D
04/08/2024 14:26
CELLI06
Sodium (Na)
2.89
mg/L
0.05
0.017
1
SW 601OD
04/08/2024 14:26
CELLI06
Strontium (Sr)
0.052
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 14:26
CELLI06
Zinc (Zn)
0.005 J
mg/L
0.015
0.004
1
SW 6010D
04/08/2024 14:26
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040089
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
04/08/2024 16:45
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
04/08/2024 16:45
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
04/08/2024 16:45
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020E
04/08/2024 16:45
MHALL3
Chromium (Cr)
0.351 J
ug/L
1
0.185
1
SW 6020B
04/08/2024 16:45
MHALL3
Cobalt (Co)
0.108 J
ug/L
1
0.077
1
SW 6020E
04/08/2024 16:45
MHALL3
Lead (Pb)
0.126 J
ug/L
1
0.037
1
SW 6020B
04/08/2024 16:45
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020E
04/08/2024 16:45
MHALL3
Nickel (Ni)
0.449 J
ug/L
1
0.256
1
SW 6020E
04/08/2024 16:45
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
04/08/2024 16:45
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
04/08/2024 16:45
MHALL3
Vanadium (V) Low Level
0.161 J
ug/L
0.3
0.114
1
SW 6020E
04/08/2024 16:45
MHALL3
TOTAL DISSOLVED SOLIDS - Q24040060
TDS
67.0
mg/L
25
25
1
SM2540C
04/04/202412:35
HHOOGKA

Certificate of Laboratory Analysis Page 9 of 36
This report shall not be reproduced, except in full.
Order # J24030520
Site: ASA MW-5-A4 Sample #: 2024007462
Collection Date: 04/02/2024 02:00 PM Loc code: ASA MW-5-A4 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
TOTAL SUSPENDED SOLIDS - Q24040056
TSS 5 U mg/L 5 5 1 SM2540D 04/04/2024 07:33 HHOOGKA

Certificate of Laboratory Analysis Page 10 of 36
This report shall not be reproduced, except in full.
Order # J24030520
Site: ASA MW-5D-A4
Sample #: 2024007463
Collection Date: 04/02/2024 01:25 PM
Loc code: ASA MW-5D-A4
Matrix: GW
RCRA
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL ALKALINITY - Q24040074
Total Alkalinity as CaCO3
39.1
mg/L
5
1.7
1
SM 2320B-2011
04/04/2024 09:53
SNEGLIA
(CaCO3)
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320B-2011
04/04/2024 09:53
SNEGLIA
Alkalinity, Bicarbonate
39.1
mg/L
5
1.7
1
SM 2320B-2011
04/04/2024 09:53
SNEGLIA
INORGANIC IONS BY IC - Q24040077
Chloride
0.82
mg/L
0.1
0.0154
1
EPA 9056A
04/04/2024 19:42
BGN9034
Sulfate
0.13
mg/L
0.1
0.0428
1
EPA 9056A
04/04/2024 19:42
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040169
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/11/2024 09:48
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24040084
Aluminum (AI)
0.022
mg/L
0.01
0.003
1
SW 6010D
04/08/2024 14:30
CELLI06
Barium (Ba)
0.024
mg/L
0.005
0.002
1
SW 601OD
04/08/2024 14:30
CELLI06
Boron (B)
0.014 J
mg/L
0.05
0.005
1
SW 6010D
04/08/2024 14:30
CELLI06
Calcium (Ca)
8.36
mg/L
0.05
0.012
1
SW 601OD
04/08/2024 14:30
CELLI06
Copper (Cu)
0.005 J
mg/L
0.005
0.001
1
SW 6010D
04/08/2024 14:30
CELLI06
Iron (Fe)
0.029
mg/L
0.01
0.004
1
SW 601OD
04/08/2024 14:30
CELL106
Magnesium (Mg)
1.88
mg/L
0.02
0.008
1
SW 6010D
04/08/2024 14:30
CELLI06
Manganese (Mn)
0.002 J
mg/L
0.005
0.001
1
SW 601 OD
04/08/2024 14:30
CELLI06
Potassium (K)
1.46
mg/L
0.1
0.031
1
SW 6010D
04/08/2024 14:30
CELLI06
Sodium (Na)
6.57
mg/L
0.05
0.017
1
SW 601OD
04/08/2024 14:30
CELLI06
Strontium (Sr)
0.102
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 14:30
CELLI06
Zinc (Zn)
0.011 J
mg/L
0.015
0.004
1
SW 6010D
04/08/2024 14:30
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040089
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
04/08/2024 19:43
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
04/08/2024 19:43
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
04/08/2024 19:43
MHALL3
Cadmium (Cd)
0.033 J
ug/L
1
0.032
1
SW 6020E
04/08/2024 19:43
MHALL3
Chromium (Cr)
0.399 J
ug/L
1
0.185
1
SW 6020B
04/08/2024 19:43
MHALL3
Cobalt (Co)
0.077 U
ug/L
1
0.077
1
SW 6020E
04/08/2024 19:43
MHALL3
Lead (Pb)
0.313 J
ug/L
1
0.037
1
SW 6020B
04/08/2024 19:43
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020E
04/08/2024 19:43
MHALL3
Nickel (Ni)
0.276 J
ug/L
1
0.256
1
SW 6020E
04/08/2024 19:43
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
04/08/2024 19:43
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
04/08/2024 19:43
MHALL3
Vanadium (V) Low Level
0.544
ug/L
0.3
0.114
1
SW 6020E
04/08/2024 19:43
MHALL3
TOTAL DISSOLVED SOLIDS - Q24040060
TDS
59.0
mg/L
25
25
1
SM2540C
04/04/202412:35
HHOOGKA

Certificate of Laboratory Analysis Page 11 of36
This report shall not be reproduced, except in full.
Order # J24030520
Site: ASA MW-5D-A4 Sample #: 2024007463
Collection Date: 04/02/2024 01:25 PM Loc code: ASA MW-5D-A4 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
TOTAL SUSPENDED SOLIDS - Q24040056
TSS 5 U mg/L 5 5 1 SM2540D 04/04/2024 07:33 HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030520
Site: ASA MW-6-A4
Collection Date: 04/02/2024 11:50 AM Loc code: ASA MW-6-A4
Sample #: 2024007464
Matrix: GW RCRA
Page 12 of 36
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q24040145
Alkalinity, Bicarbonate
11.1
mg/L
5
1.7
1
SM 2320134d
04/09/2024 11:16
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/09/2024 11:16
SNEGLIA
Total Alkalinity as CaCO3
11.1
mg/L
5
1.7
1
SM 2320134d
04/09/2024 11:16
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24040077
Chloride
2.9
mg/L
0.5
0.0154
5
EPA 9056A
04/04/2024 20:02
BGN9034
Sulfate
17
mg/L
0.5
0.0428
5
EPA 9056A
04/04/2024 20:02
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040169
Mercury (Hg)
0.03 J
ug/L
0.05
0.01
1
EPA 7470A
04/11/2024 09:50
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24040084
Aluminum (AI)
0.008 J
mg/L
0.01
0.003
1
SW 6010D
04/08/2024 14:34
CELLI06
Barium (Ba)
0.050
mg/L
0.005
0.002
1
SW 601OD
04/08/2024 14:34
CELLI06
Boron (B)
0.012 J
mg/L
0.05
0.005
1
SW 6010D
04/08/2024 14:34
CELLI06
Calcium (Ca)
6.41
mg/L
0.05
0.012
1
SW 601OD
04/08/2024 14:34
CELLI06
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
04/08/2024 14:34
CELLI06
Iron (Fe)
0.004 J
mg/L
0.01
0.004
1
SW 601 OD
04/08/2024 14:34
CELL106
Magnesium (Mg)
2.50
mg/L
0.02
0.008
1
SW 6010D
04/08/2024 14:34
CELLI06
Manganese (Mn)
0.012
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 14:34
CELLI06
Potassium (K)
1.33
mg/L
0.1
0.031
1
SW 6010D
04/08/2024 14:34
CELLI06
Sodium (Na)
4.03
mg/L
0.05
0.017
1
SW 601OD
04/08/2024 14:34
CELLI06
Strontium (Sr)
0.062
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 14:34
CELLI06
Zinc (Zn)
0.004 U
mg/L
0.015
0.004
1
SW 6010D
04/08/2024 14:34
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040089
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
04/08/2024 19:51
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
04/08/2024 19:51
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
04/08/2024 19:51
MHALL3
Cadmium (Cd)
0.034 J
ug/L
1
0.032
1
SW 6020E
04/08/2024 19:51
MHALL3
Chromium (Cr)
1.08
ug/L
1
0.185
1
SW 6020B
04/08/2024 19:51
MHALL3
Cobalt (Co)
0.351 J
ug/L
1
0.077
1
SW 6020E
04/08/2024 19:51
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
04/08/2024 19:51
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020E
04/08/2024 19:51
MHALL3
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
SW 6020E
04/08/2024 19:51
MHALL3
Selenium (Se)
0.655 J
ug/L
1
0.193
1
SW 6020B
04/08/2024 19:51
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
04/08/2024 19:51
MHALL3
Vanadium (V) Low Level
0.145 J
ug/L
0.3
0.114
1
SW 6020E
04/08/2024 19:51
MHALL3
TOTAL DISSOLVED SOLIDS - Q24040060
TDS
41.0
mg/L
25
25
1
SM2540C
04/04/202412:35
HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030520
Site: ASA MW-6-A4
Collection Date: 04/02/2024 11:50 AM Loc code: ASA MW-6-A4
Analyte Result Units Qualifiers RDL MDL DF
TOTAL SUSPENDED SOLIDS - Q24040056
TSS 5 U mg/L 5 5 1
Sample #: 2024007464
Matrix: GW RCRA
Page 13 of 36
Method Analysis Date/Time Analyst
SM2540D 04/04/2024 07:33 HHOOGKA

Certificate of Laboratory Analysis Page 14 of 36
This report shall not be reproduced, except in full.
Order # J24030520
Site: ASA MW-7-A4 Sample #: 2024007465
Collection Date: 04/02/2024 12:25 PM Loc code: ASA MW-7-A4 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL
LOW LEVEL ALKALINITY (FIXED END POINT) - Q24040145
Alkalinity, Bicarbonate 1.7 U mg/L 5
Alkalinity, Carbonate 1.7 U mg/L 5
Total Alkalinity as CaCO3 1.7 U mg/L 5
(CaCO3)
INORGANIC IONS BY IC - Q24040077
Chloride 5.4 mg/L
Sulfate 1000 mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040169
Mercury (Hg) 0.02 J ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040084
Aluminum (AI)
47.0
mg/L
Barium (Ba)
0.011
mg/L
Boron (B)
0.008 J
mg/L
Calcium (Ca)
260
mg/L
Copper (Cu)
0.005 J
mg/L
Iron (Fe)
0.01 J
mg/L
Magnesium (Mg)
65.0
mg/L
Manganese (Mn)
10.7
mg/L
Potassium (K)
2.64
mg/L
Sodium (Na)
9.62
mg/L
Strontium (Sr)
0.006
mg/L
Zinc (Zn)
0.675
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040089
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
162
ug/L
Beryllium (Be)
3.33
ug/L
Cadmium (Cd)
2.22
ug/L
Chromium (Cr)
2.52
ug/L
Cobalt (Co)
684
ug/L
Lead (Pb)
0.147 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
973
ug/L
Selenium (Se)
2.52
ug/L
Thallium (TI) Low Level
0.124 J
ug/L
Vanadium (V) Low Level
0.114 U
ug/L
TOTAL DISSOLVED SOLIDS - Q24040060
TDS
1380
mg/L
MDL
DF
Method
Analysis Date/Time
Analyst
1.7
1
SM 2320134d
04/09/2024 11:23
SNEGLIA
1.7
1
SM 2320134d
04/09/2024 11:23
SNEGLIA
1.7
1
SM 2320134d
04/09/2024 11:23
SNEGLIA
5
0.0154
50
EPA 9056A
04/04/2024 21:40
BGN9034
50
0.0428
500
EPA 9056A
04/04/2024 21:40
BGN9034
0.05
0.01
1
EPA 7470A
04/11/2024 09:53
SNEGLIA
0.1
0.003
10
SW 601OD
04/08/2024 14:37
CELL106
0.005
0.002
1
SW 601OD
04/08/2024 14:37
CELL106
0.05
0.005
1
SW 601OD
04/08/2024 14:37
CELL106
0.5
0.012
10
SW 601OD
04/08/2024 14:37
CELL106
0.005
0.001
1
SW 601OD
04/08/2024 14:37
CELL106
0.01
0.004
1
SW 601OD
04/08/2024 14:37
CELL106
0.02
0.008
1
SW 601OD
04/08/2024 14:37
CELL106
0.005
0.001
1
SW 601OD
04/08/2024 14:37
CELL106
0.1
0.031
1
SW 601OD
04/08/2024 14:37
CELL106
0.05
0.017
1
SW 601OD
04/08/2024 14:37
CELL106
0.005
0.001
1
SW 601OD
04/08/2024 14:37
CELL106
0.015
0.004
1
SW 601OD
04/08/2024 14:37
CELL106
1
0.104
1
SW 6020B
04/09/2024 22:22
MHALL3
1
0.111
1
SW 6020B
04/09/2024 22:22
MHALL3
1
0.249
1
SW 6020B
04/09/2024 22:22
MHALL3
1
0.032
1
SW 6020E
04/09/2024 22:22
MHALL3
1
0.185
1
SW 6020B
04/09/2024 22:22
MHALL3
100
0.077
100
SW 6020E
04/09/2024 22:22
MHALL3
1
0.037
1
SW 6020B
04/09/2024 22:22
MHALL3
1
0.18
1
SW 6020E
04/09/2024 22:22
MHALL3
100
0.256
100
SW 6020E
04/09/2024 22:22
MHALL3
1
0.193
1
SW 6020B
04/09/2024 22:22
MHALL3
0.2
0.041
1
SW 6020B
04/09/2024 22:22
MHALL3
0.3
0.114
1
SW 6020E
04/09/2024 22:22
MHALL3
100
25
1
SM2540C
04/04/202412:35
HHOOGKA

Certificate of Laboratory Analysis Page 15 of 36
This report shall not be reproduced, except in full.
Order # J24030520
Site: ASA MW-7-A4 Sample #: 2024007465
Collection Date: 04/02/2024 12:25 PM Loc code: ASA MW-7-A4 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
TOTAL SUSPENDED SOLIDS - Q24040056
TSS 5 U mg/L 5 5 1 SM2540D 04/04/2024 07:33 HHOOGKA

Certificate of Laboratory Analysis Page 16 of 36
This report shall not be reproduced, except in full.
Order # J24030520
Site: ASA MW-9-A4
Sample #: 2024007466
Collection Date: 04/02/2024 11:29 AM
Loc code: ASA MW-9-A4
Matrix: GW
RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL ALKALINITY - Q24040074
Total Alkalinity as CaCO3
39.9
mg/L
5
1.7
1
SM 2320B-2011
04/04/2024 10:02
SNEGLIA
(CaCO3)
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320B-2011
04/04/2024 10:02
SNEGLIA
Alkalinity, Bicarbonate
39.9
mg/L
5
1.7
1
SM 2320B-2011
04/04/2024 10:02
SNEGLIA
INORGANIC IONS BY IC - Q24040077
Chloride
0.72
mg/L
0.1
0.0154
1
EPA 9056A
04/04/2024 20:41
BGN9034
Sulfate
0.09 J
mg/L
0.1
0.0428
1
EPA 9056A
04/04/2024 20:41
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040169
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/11/2024 09:55
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24040084
Aluminum (AI)
0.023
mg/L
0.01
0.003
1
SW 6010D
04/08/2024 14:41
CELLI06
Barium (Ba)
0.007
mg/L
0.005
0.002
1
SW 601OD
04/08/2024 14:41
CELLI06
Boron (B)
0.006 J
mg/L
0.05
0.005
1
SW 6010D
04/08/2024 14:41
CELLI06
Calcium (Ca)
7.28
mg/L
0.05
0.012
1
SW 601OD
04/08/2024 14:41
CELLI06
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
04/08/2024 14:41
CELLI06
Iron (Fe)
0.01 J
mg/L
0.01
0.004
1
SW 601OD
04/08/2024 14:41
CELL106
Magnesium (Mg)
1.98
mg/L
0.02
0.008
1
SW 6010D
04/08/2024 14:41
CELLI06
Manganese (Mn)
0.003 J
mg/L
0.005
0.001
1
SW 601 OD
04/08/2024 14:41
CELLI06
Potassium (K)
1.64
mg/L
0.1
0.031
1
SW 6010D
04/08/2024 14:41
CELLI06
Sodium (Na)
6.49
mg/L
0.05
0.017
1
SW 601OD
04/08/2024 14:41
CELLI06
Strontium (Sr)
0.074
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 14:41
CELLI06
Zinc (Zn)
0.004 U
mg/L
0.015
0.004
1
SW 6010D
04/08/2024 14:41
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040089
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
04/09/2024 16:03
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
04/09/2024 16:03
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
04/09/2024 16:03
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020E
04/09/2024 16:03
MHALL3
Chromium (Cr)
1.00
ug/L
1
0.185
1
SW 6020B
04/09/2024 16:03
MHALL3
Cobalt (Co)
0.077 U
ug/L
1
0.077
1
SW 6020E
04/09/2024 16:03
MHALL3
Lead (Pb)
0.077 J
ug/L
1
0.037
1
SW 6020B
04/09/2024 16:03
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020E
04/09/2024 16:03
MHALL3
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
SW 6020E
04/09/2024 16:03
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
04/09/2024 16:03
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
04/09/2024 16:03
MHALL3
Vanadium (V) Low Level
0.412
ug/L
0.3
0.114
1
SW 6020E
04/09/2024 16:03
MHALL3
TOTAL DISSOLVED SOLIDS - Q24040060
TDS
67.0
mg/L
25
25
1
SM2540C
04/04/202412:35
HHOOGKA

Certificate of Laboratory Analysis Page 17 of 36
This report shall not be reproduced, except in full.
Order # J24030520
Site: ASA MW-9-A4 Sample #: 2024007466
Collection Date: 04/02/2024 11:29 AM Loc code: ASA MW-9-A4 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
TOTAL SUSPENDED SOLIDS - Q24040056
TSS 5 U mg/L 5 5 1 SM2540D 04/04/2024 07:33 HHOOGKA

Certificate of Laboratory Analysis Page 18 of 36
This report shall not be reproduced, except in full.
Order # J24030520
Site: ASA FD-20240402-1
Duplicate
Sample #: 2024007467
Collection Date: 04/02/2024
Loc code: ASA FD
Matrix: GW
RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q24040145
Alkalinity, Bicarbonate
10.8
mg/L
5
1.7
1
SM 2320134d
04/09/2024 11:26
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/09/2024 11:26
SNEGLIA
Total Alkalinity as CaCO3
10.8
mg/L
5
1.7
1
SM 2320134d
04/09/2024 11:26
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24040077
Chloride 2.9 mg/L
Sulfate 16 mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040169
Mercury (Hg) 0.03 J ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040084
Aluminum (AI)
0.014
mg/L
Barium (Ba)
0.049
mg/L
Boron (B)
0.005 J
mg/L
Calcium (Ca)
6.34
mg/L
Copper (Cu)
0.001 U
mg/L
Iron (Fe)
0.008 J
mg/L
Magnesium (Mg)
2.48
mg/L
Manganese (Mn)
0.012
mg/L
Potassium (K)
1.32
mg/L
Sodium (Na)
3.97
mg/L
Strontium (Sr)
0.061
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040089
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.041 J
ug/L
Chromium (Cr)
1.03
ug/L
Cobalt (Co)
0.389 J
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.256 U
ug/L
Selenium (Se)
0.524 J
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
0.158 J
ug/L
TOTAL DISSOLVED SOLIDS - Q24040060
TDS
48.0
mg/L
0.5
0.0154
5
EPA 9056A
04/04/2024 21:00
BGN9034
0.5
0.0428
5
EPA 9056A
04/04/2024 21:00
BGN9034
0.05
0.01
1
EPA 7470A
04/11/2024 09:57
SNEGLIA
0.01
0.003
1
SW 6010D
04/08/2024 14:45
CELL106
0.005
0.002
1
SW 6010D
04/08/2024 14:45
CELL106
0.05
0.005
1
SW 6010D
04/08/2024 14:45
CELL106
0.05
0.012
1
SW 6010D
04/08/2024 14:45
CELL106
0.005
0.001
1
SW 6010D
04/08/2024 14:45
CELL106
0.01
0.004
1
SW 601OD
04/08/2024 14:45
CELL106
0.02
0.008
1
SW 6010D
04/08/2024 14:45
CELL106
0.005
0.001
1
SW 6010D
04/08/2024 14:45
CELL106
0.1
0.031
1
SW 6010D
04/08/2024 14:45
CELL106
0.05
0.017
1
SW 6010D
04/08/2024 14:45
CELL106
0.005
0.001
1
SW 6010D
04/08/2024 14:45
CELL106
0.015
0.004
1
SW 6010D
04/08/2024 14:45
CELL106
1
0.104
1
SW 6020B
04/08/2024 20:16
MHALL3
1
0.111
1
SW 6020B
04/08/2024 20:16
MHALL3
1
0.249
1
SW 6020B
04/08/2024 20:16
MHALL3
1
0.032
1
SW 6020E
04/08/2024 20:16
MHALL3
1
0.185
1
SW 6020B
04/08/2024 20:16
MHALL3
1
0.077
1
SW 6020E
04/08/2024 20:16
MHALL3
1
0.037
1
SW 6020B
04/08/2024 20:16
MHALL3
1
0.18
1
SW 6020E
04/08/2024 20:16
MHALL3
1
0.256
1
SW 6020E
04/08/2024 20:16
MHALL3
1
0.193
1
SW 6020B
04/08/2024 20:16
MHALL3
0.2
0.041
1
SW 6020B
04/08/2024 20:16
MHALL3
0.3
0.114
1
SW 6020E
04/08/2024 20:16
MHALL3
25
25
1
SM2540C
04/04/202412:35
HHOOGKA

Certificate of Laboratory Analysis Page 19 of 36
This report shall not be reproduced, except in full.
Order # J24030520
Site: ASA FD-20240402-1 Duplicate Sample #: 2024007467
Collection Date: 04/02/2024 Loc code: ASA FD Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
TOTAL SUSPENDED SOLIDS - Q24040056
TSS 5 U mg/L 5 5 1 SM2540D 04/04/2024 07:33 HHOOGKA

Certificate of Laboratory Analysis Page 20 of 36
This report shall not be reproduced, except in full.
Order # J24030520
Site: ASA FB-20240402-1500 Field Blank Sample #: 2024007468
Collection Date: 04/02/2024 03:00 PM Loc code: ASA FB Matrix: GW RCRA
Analyte Result Units Qualifiers RDL
LOW LEVEL ALKALINITY (FIXED END POINT) - Q24040145
Alkalinity, Bicarbonate 1.7 U mg/L 5
Alkalinity, Carbonate 1.7 U mg/L 5
Total Alkalinity as CaCO3 1.7 U mg/L 5
(CaCO3)
INORGANIC IONS BY IC - Q24040077
Chloride 0.0154 U mg/L
Sulfate 0.0428 U mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040169
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040084
Aluminum (AI)
0.023
mg/L
Barium (Ba)
0.002 U
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
0.012 U
mg/L
Copper (Cu)
0.001 J
mg/L
Iron (Fe)
0.004 U
mg/L
Magnesium (Mg)
0.01 J
mg/L
Manganese (Mn)
0.001 U
mg/L
Potassium (K)
0.031 U
mg/L
Sodium (Na)
0.017 U
mg/L
Strontium (Sr)
0.001 U
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040089
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.185 U
ug/L
Cobalt (Co)
0.077 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.256 U
ug/L
Selenium (Se)
0.193 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
0.114 U
ug/L
MDL
DF
Method
Analysis Date/Time
Analyst
1.7
1
SM 2320134d
04/09/2024 11:32
SNEGLIA
1.7
1
SM 2320134d
04/09/2024 11:32
SNEGLIA
1.7
1
SM 2320134d
04/09/2024 11:32
SNEGLIA
0.1
0.0154
1
EPA 9056A
04/04/2024 21:20
BGN9034
0.1
0.0428
1
EPA 9056A
04/04/2024 21:20
BGN9034
0.05
0.01
1
EPA 7470A
04/11/2024 10:00
SNEGLIA
0.01
0.003
1
SW 601OD
04/08/2024 14:49
CELL106
0.005
0.002
1
SW 601OD
04/08/2024 14:49
CELL106
0.05
0.005
1
SW 601OD
04/08/2024 14:49
CELL106
0.05
0.012
1
SW 601OD
04/08/2024 14:49
CELL106
0.005
0.001
1
SW 601OD
04/08/2024 14:49
CELL106
0.01
0.004
1
SW 601OD
04/08/2024 14:49
CELL106
0.02
0.008
1
SW 601OD
04/08/2024 14:49
CELL106
0.005
0.001
1
SW 601OD
04/08/2024 14:49
CELL106
0.1
0.031
1
SW 601OD
04/08/2024 14:49
CELL106
0.05
0.017
1
SW 601OD
04/08/2024 14:49
CELL106
0.005
0.001
1
SW 601OD
04/08/2024 14:49
CELL106
0.015
0.004
1
SW 601OD
04/08/2024 14:49
CELL106
1
0.104
1
SW 6020B
04/08/2024 20:24
MHALL3
1
0.111
1
SW 6020B
04/08/2024 20:24
MHALL3
1
0.249
1
SW 6020B
04/08/2024 20:24
MHALL3
1
0.032
1
SW 6020E
04/08/2024 20:24
MHALL3
1
0.185
1
SW 6020B
04/08/2024 20:24
MHALL3
1
0.077
1
SW 6020E
04/08/2024 20:24
MHALL3
1
0.037
1
SW 6020B
04/08/2024 20:24
MHALL3
1
0.18
1
SW 6020E
04/08/2024 20:24
MHALL3
1
0.256
1
SW 6020E
04/08/2024 20:24
MHALL3
1
0.193
1
SW 6020B
04/08/2024 20:24
MHALL3
0.2
0.041
1
SW 6020B
04/08/2024 20:24
MHALL3
0.3
0.114
1
SW 6020E
04/08/2024 20:24
MHALL3

Certificate of Laboratory Analysis Page 21 of 36
This report shall not be reproduced, except in full.
Order # J24030520
Qualifiers:
B2 Target analyte was detected in Method/Prep Blank(s) at a concentration greater than % the reporting limit but less than the
reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an estimate.

Certificate of Laboratory Analysis Page 22 of 36
This report shall not be reproduced, except in full.
Order # J24030520
Level II QC Summary
Q24040074 ALK CarbBicarb TOTAL ALKALINITY
Duplicate # I
Parameter
Measured
Final
Alkalinity, Bicarbonate
81.1
Alkalinity, Carbonate
0
Total Alkalinity as CaCO3
81.1
Duplicate # 2
Parameter
Measured
Final
Alkalinity, Bicarbonate
75.7
Alkalinity, Carbonate
0
Total Alkalinity as CaCO3
75.7
Duplicate # 3
Parameter
Measured
Final
Alkalinity, Bicarbonate
31.7
Alkalinity, Carbonate
0
Total Alkalinity as CaCO3
31.7
LCS # I
Parameter
Measured
Final
Total Alkalinity as CaCO3
78.3
LCS # 2
Parameter
Measured
Final
Total Alkalinity as CaCO3
79.7
LCS # 3
Parameter
Measured
Final
Total Alkalinity as CaCO3
79.3
Parent Sample:
J24030604 -- 2024007765
Units
Dil
MDL
RPD
Qualifier
mg/L
1
1.7
2.93
mg/L
1
1.7
0
mg/L
1
1.7
2.93
Parent Sample:
J24030604 -- 2024007766
Units
Dil
MDL
RPD
Qualifier
mg/L
1
1.7
1.81
mg/L
1
1.7
0
mg/L
1
1.7
1.81
Parent Sample:
J24030517 -- 2024007430
Units
Dil
MDL
RPD
Qualifier
mg/L
1
1.7
2.03
mg/L
1
1.7
0
mg/L
1
1.7
2.03
Units
Dil
MDL
Spike
% Recover v
LCL UCL
Qualifier
mg/L
1
1.7
77.9
101
85 115
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
mg/L
1
1.7
77.9
102
85 115
Units
Dil
MDL
Spike
% Recover v
LCL UCL
Qualifier
mg/L
1
1.7
77.9
102
85 115

Certificate of Laboratory Analysis Page 23 of 36
This report shall not be reproduced, except in full.
Order # J24030520
Level II QC Summary
Q24040145 ALK LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Duplicate # 1
Parent Sample:
J24030519 -- 2024007451
Parameter Measured
Final
Units
Dil
MDL
RPD Qualifier
Alkalinity, Bicarbonate
8.27
mg/L
1
1.7
1.22
Alkalinity, Carbonate
0
mg/L
1
1.7
0
Total Alkalinity as CaCO3
8.27
mg/L
1
1.7
1.22
LCS # 1
Parameter Measured
Final
Units
Dil
MDL S ike % Recovery
LCL UCL Qualifier
Total Alkalinity as CaCO3
72.4
mg/L
1
1.7 77.9 93
85 115
(CaCO3)

Certificate of Laboratory Analysis Page 24 of 36
This report shall not be reproduced, except in full.
Order # J24030520
Level II QC Summary
Q24040077 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Sulfate
0
0
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S Ike
% Recovery
LCL
UCL
Chloride
5.15
5.15
mg/L
1
0.0154
5
103
80
120
Sulfate
5.21
5.21
mg/L
1
0.0428
5
104
80
120
MS # 1
Parent Sample:
J24030519 -- 2024007451
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Chloride
7.48
7.48
mg/L
1
0.0154
5
99.8
80
120
Sulfate
6.25
6.25
mg/L
1
0.0428
5
101
80
120
MSD # 1
Parent Sample:
J24030519 -- 2024007451
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Chloride
7.47
7.47
mg/L
1
0.0154
5
99.7
80
120 0.12
Sulfate
6.28
6.28
mg/L
1
0.0428
5
102
80
120 0.532
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 25 of 36
This report shall not be reproduced, except in full.
Order # J24030520
Level II QC Summary
Q24040169 HG 7470 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Mercury (Hg)
-0.006
-0.006
Blank # 2
Parameter
Measured
Final
Mercury (Hg)
-0.004
-0.004
LCS # 1
MS # 1
MSD # 1
MS # 2
MSD # 2
Parameter Measured Final
Mercury (Hg) 1.98 1.98
Parameter Measured Final
Mercury (Hg) 0.985 0.985
Parameter Measured Final
Mercury (Hg) 1 1
Parameter Measured Final
Mercury (Hg) 1 1
Parameter Measured Final
Mercury (Hg) 1.01 1.01
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
ug/L
1
0.01
0.05
< MDL
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
ug/L
1
0.01
0.05
< MDL
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
ug/L
1
0.01
2
98.8
85 115
Parent Sample:
J24030519 -- 2024007451
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
ug/L
1
0.01
1
98.5
75 125
Parent Sample:
J24030519 -- 2024007451
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
ug/L
1
0.01
1
100
75 125 1.91
Parent Sample:
J24030520 -- 2024007461
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
ug/L
1
0.01
1
100
75 125
Parent Sample:
J24030520 -- 2024007461
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
ug/L
1
0.01
1
101
75 125 0.797

Certificate of Laboratory Analysis Page 26 of 36
This report shall not be reproduced, except in full.
Order # J24030520
Level II QC Summary
Q24040064 ICP_TRM TOTAL RECOVERABLE METALS BY 1CP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration Qualifier
Aluminum (AI)
0.00704
0.00704
mg/L
1
0.003
0.01
> MDL B2
Barium (Ba)
0.000176
0.000176
mg/L
1
0.002
0.005
< MDL
Boron (B)
0.00515
0.00515
mg/L
1
0.005
0.05
> MDL
Calcium (Ca)
0.00835
0.00835
mg/L
1
0.012
0.05
< MDL
Copper (Cu)
0.000453
0.000453
mg/L
1
0.001
0.005
< MDL
Iron (Fe)
0.00321
0.00321
mg/L
1
0.004
0.01
< MDL
Magnesium (Mg)
0.0099
0.0099
mg/L
1
0.008
0.02
> MDL
Manganese (Mn)
0.000346
0.000346
mg/L
1
0.001
0.005
< MDL
Potassium (K)
-0.0148
-0.0148
mg/L
1
0.031
0.1
< MDL
Sodium (Na)
-0.000749
-0.000749
mg/L
1
0.017
0.05
< MDL
Strontium (Sr)
0.000173
0.000173
mg/L
1
0.001
0.005
< MDL
Zinc (Zn)
0.000838
0.000838
mg/L
1
0.004
0.015
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL Qualifier
Aluminum (AI)
5.14
5.14
mg/L
1
0.003
5
103
80
120
Barium (Ba)
5.1
5.1
mg/L
1
0.002
5
102
80
120
Boron (B)
5
5
mg/L
1
0.005
5
100
80
120
Calcium (Ca)
5.13
5.13
mg/L
1
0.012
5
103
80
120
Copper (Cu)
5.08
5.08
mg/L
1
0.001
5
102
80
120
Iron (Fe)
5.14
5.14
mg/L
1
0.004
5
103
80
120
Magnesium (Mg)
5.14
5.14
mg/L
1
0.008
5
103
80
120
Manganese (Mn)
5.09
5.09
mg/L
1
0.001
5
102
80
120
Potassium (K)
5.14
5.14
mg/L
1
0.031
5
103
80
120
Sodium (Na)
5.13
5.13
mg/L
1
0.017
5
103
80
120
Strontium (Sr)
5.05
5.05
mg/L
1
0.001
5
101
80
120
Zinc (Zn)
5.09
5.09
mg/L
1
0.004
5
102
80
120
MS # 1
Parent Sample:
J24030517
-- 2024007428
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL Qualifier
Aluminum (AI)
6.04
6.04
mg/L
1
0.003
5
113
75
125
Barium (Ba)
5.18
5.18
mg/L
1
0.002
5
103
75
125
Boron (B)
5.06
5.06
mg/L
1
0.005
5
101
75
125
Calcium (Ca)
10.1
10.1
mg/L
1
0.012
5
104
75
125
Copper (Cu)
5.1
5.1
mg/L
1
0.001
5
102
75
125
Iron (Fe)
5.48
5.48
mg/L
1
0.004
5
105
75
125
Magnesium (Mg)
8.07
8.07
mg/L
1
0.008
5
104
75
125
Manganese (Mn)
5.15
5.15
mg/L
1
0.001
5
103
75
125
Potassium (K)
6.21
6.21
mg/L
1
0.031
5
104
75
125
Sodium (Na)
8.4
8.4
mg/L
1
0.017
5
104
75
125

Certificate of Laboratory Analysis Page 27 of 36
This report shall not be reproduced, except in full.
Order # J24030520
Level II QC Summary
Q24040064 ICP_TRM TOTAL RECOVERABLE METALS BY 1CP
MS # 1
Parameter
Measured
Final
Strontium (Sr)
5.13
5.13
Zinc (Zn)
5.12
5.12
MSD # 1
Parameter
Measured
Final
Aluminum (AI)
5.95
5.95
Barium (Ba)
5.21
5.21
Boron (B)
5.07
5.07
Calcium (Ca)
10.1
10.1
Copper (Cu)
5.13
5.13
Iron (Fe)
5.51
5.51
Magnesium (Mg)
8.06
8.06
Manganese (Mn)
5.18
5.18
Potassium (K)
6.25
6.25
Sodium (Na)
8.41
8.41
Strontium (Sr)
5.2
5.2
Zinc (Zn)
5.15
5.15
Parent Sample:
J24030517 -- 2024007428
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
mg/L
1
0.001
5
101
75
125
mg/L
1
0.004
5
102
75
125
Parent Sample:
J24030517
-- 2024007428
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
mg/L
1
0.003
5
111
75
125
1.5
mg/L
1
0.002
5
104
75
125
0.577
mg/L
1
0.005
5
101
75
125
0.197
mg/L
1
0.012
5
104
75
125
0
mg/L
1
0.001
5
103
75
125
0.587
mg/L
1
0.004
5
105
75
125
0.546
mg/L
1
0.008
5
104
75
125
0.124
mg/L
1
0.001
5
103
75
125
0.581
mg/L
1
0.031
5
105
75
125
0.642
mg/L
1
0.017
5
104
75
125
0.119
mg/L
1
0.001
5
103
75
125
1.36
mg/L
1
0.004
5
103
75
125
0.584
Qualifiers:
B2 Target analyte was detected in Method/Prep Blank(s) at a concentration greater than '/2 the reporting limit but
less than the reporting limit. Analyte concentration in sample is valid and may be used for compliance
purposes.
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030520
Level II QC Summary
Q24040084 ICP_TRM TOTAL RECOVERABLE METALS BY iCP
Blank # 1
Page 28 of 36
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Aluminum (AI)
0.00296
0.00296
mg/L
1
0.003
0.01
< MDL
Barium (Ba)
-0.000082
-0.000082
mg/L
1
0.002
0.005
< MDL
Boron (B)
0.00331
0.00331
mg/L
1
0.005
0.05
< MDL
Calcium (Ca)
0.00344
0.00344
mg/L
1
0.012
0.05
< MDL
Copper (Cu)
0.000936
0.000936
mg/L
1
0.001
0.005
< MDL
Iron (Fe)
-0.000218
-0.000218
mg/L
1
0.004
0.01
< MDL
Magnesium (Mg)
0.00731
0.00731
mg/L
1
0.008
0.02
< MDL
Manganese (Mn)
0.000058
0.000058
mg/L
1
0.001
0.005
< MDL
Potassium (K)
-0.011
-0.011
mg/L
1
0.031
0.1
< MDL
Sodium (Na)
0.0025
0.0025
mg/L
1
0.017
0.05
< MDL
Strontium (Sr)
0.000016
0.000016
mg/L
1
0.001
0.005
< MDL
Zinc (Zn)
0.000509
0.000509
mg/L
1
0.004
0.015
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Aluminum (AI)
5.06
5.06
mg/L
1
0.003
5
101
80
120
Barium (Ba)
5
5
mg/L
1
0.002
5
100
80
120
Boron (B)
4.92
4.92
mg/L
1
0.005
5
98.4
80
120
Calcium (Ca)
5.07
5.07
mg/L
1
0.012
5
101
80
120
Copper (Cu)
5.02
5.02
mg/L
1
0.001
5
100
80
120
Iron (Fe)
5.06
5.06
mg/L
1
0.004
5
101
80
120
Magnesium (Mg)
5.08
5.08
mg/L
1
0.008
5
102
80
120
Manganese (Mn)
5.01
5.01
mg/L
1
0.001
5
100
80
120
Potassium (K)
5.09
5.09
mg/L
1
0.031
5
102
80
120
Sodium (Na)
5.07
5.07
mg/L
1
0.017
5
101
80
120
Strontium (Sr)
5.03
5.03
mg/L
1
0.001
5
101
80
120
Zinc (Zn)
5.04
5.04
mg/L
1
0.004
5
101
80
120
MS # 1
Parent Sample:
J24030520 -- 2024007461
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Aluminum (AI)
5.19
5.19
mg/L
1
0.003
5
103
75
125
Barium (Ba)
5.1
5.1
mg/L
1
0.002
5
102
75
125
Boron (B)
4.98
4.98
mg/L
1
0.005
5
99.5
75
125
Calcium (Ca)
6.75
6.75
mg/L
1
0.012
5
103
75
125
Copper (Cu)
5.09
5.09
mg/L
1
0.001
5
102
75
125
Iron (Fe)
5.15
5.15
mg/L
1
0.004
5
103
75
125
Magnesium (Mg)
6.41
6.41
mg/L
1
0.008
5
102
75
125
Manganese (Mn)
5.1
5.1
mg/L
1
0.001
5
102
75
125
Potassium (K)
5.98
5.98
mg/L
1
0.031
5
103
75
125
Sodium (Na)
7.11
7.11
mg/L
1
0.017
5
103
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 29 of 36
This report shall not be reproduced, except in full.
Order # J24030520
Level II QC Summary
Q24040084 ICP_TRM TOTAL RECOVERABLE METALS BY 1CP
MS # 1
Parameter
Measured
Final
Strontium (Sr)
5.07
5.07
Zinc (Zn)
5.1
5.1
MSD # 1
Parameter
Measured
Final
Aluminum (AI)
5.14
5.14
Barium (Ba)
5.05
5.05
Boron (B)
4.98
4.98
Calcium (Ca)
6.71
6.71
Copper (Cu)
5.07
5.07
Iron (Fe)
5.12
5.12
Magnesium (Mg)
6.4
6.4
Manganese (Mn)
5.06
5.06
Potassium (K)
5.95
5.95
Sodium (Na)
7.09
7.09
Strontium (Sr)
5.04
5.04
Zinc (Zn)
5.09
5.09
Parent Sample:
J24030520 -- 2024007461
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
mg/L
1
0.001
5
101
75
125
mg/L
1
0.004
5
102
75
125
Parent Sample:
J24030520
-- 2024007461
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
mg/L
1
0.003
5
102
75
125
0.968
mg/L
1
0.002
5
101
75
125
0.985
mg/L
1
0.005
5
99.5
75
125
0
mg/L
1
0.012
5
102
75
125
0.594
mg/L
1
0.001
5
101
75
125
0.394
mg/L
1
0.004
5
102
75
125
0.584
mg/L
1
0.008
5
102
75
125
0.156
mg/L
1
0.001
5
101
75
125
0.787
mg/L
1
0.031
5
103
75
125
0.503
mg/L
1
0.017
5
102
75
125
0.282
mg/L
1
0.001
5
101
75
125
0.593
mg/L
1
0.004
5
102
75
125
0.196
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030520
Level II QC Summary
Q24040070 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Page 30 of 36
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
0.003
0.003
ug/L
1
0.104
1
< MDL
Arsenic (As)
0.004
0.004
ug/L
1
0.111
1
< MDL
Beryllium (Be)
0.015
0.015
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0.006
0.006
ug/L
1
0.032
1
< MDL
Chromium (Cr)
0.047
0.047
ug/L
1
0.185
1
< MDL
Cobalt (Co)
-0.003
-0.003
ug/L
1
0.077
1
< MDL
Lead (Pb)
0.009
0.009
ug/L
1
0.037
1
< MDL
Molybdenum (Mo)
0.008
0.008
ug/L
1
0.18
1
< MDL
Nickel (Ni)
0.022
0.022
ug/L
1
0.256
1
< MDL
Selenium (Se)
0.178
0.178
ug/L
1
0.193
1
< MDL
Thallium (TI) Low Level
-0.008
-0.008
ug/L
1
0.041
0.2
< MDL
Vanadium (V) Low Level
0.041
0.041
ug/L
1
0.114
0.3
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
48.6
48.6
ug/L
1
0.104
50
97.2
80
120
Arsenic (As)
49.1
49.1
ug/L
1
0.111
50
98.2
80
120
Beryllium (Be)
47.9
47.9
ug/L
1
0.249
50
95.8
80
120
Cadmium (Cd)
48.8
48.8
ug/L
1
0.032
50
97.6
80
120
Chromium (Cr)
48.3
48.3
ug/L
1
0.185
50
96.7
80
120
Cobalt (Co)
49.1
49.1
ug/L
1
0.077
50
98.1
80
120
Lead (Pb)
49
49
ug/L
1
0.037
50
98
80
120
Molybdenum (Mo)
49.1
49.1
ug/L
1
0.18
50
98.3
80
120
Nickel (Ni)
48.7
48.7
ug/L
1
0.256
50
97.5
80
120
Selenium (Se)
48.2
48.2
ug/L
1
0.193
50
96.4
80
120
Thallium (TI) Low Level
48.6
48.6
ug/L
1
0.041
50
97.3
80
120
Vanadium (V) Low Level
48.4
48.4
ug/L
1
0.114
50
96.8
80
120
MS # 1
Parent Sample:
J24030517 -- 2024007430
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
48.9
48.9
ug/L
1
0.104
50
97.7
75
125
Arsenic (As)
49.3
49.3
ug/L
1
0.111
50
98
75
125
Beryllium (Be)
47.8
47.8
ug/L
1
0.249
50
95.5
75
125
Cadmium (Cd)
49.3
49.3
ug/L
1
0.032
50
97
75
125
Chromium (Cr)
49.1
49.1
ug/L
1
0.185
50
97.6
75
125
Cobalt (Co)
62.6
62.6
ug/L
1
0.077
50
97.2
75
125
Lead (Pb)
49.6
49.6
ug/L
1
0.037
50
98.9
75
125
Molybdenum (Mo)
49.6
49.6
ug/L
1
0.18
50
99.1
75
125
Nickel (Ni)
49.7
49.7
ug/L
1
0.256
50
97.4
75
125
Selenium (Se)
48.2
48.2
ug/L
1
0.193
50
96.1
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 31 of 36
This report shall not be reproduced, except in full.
Order # J24030520
Level II QC Summary
Q24040070 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 1
Parameter
Measured
Final
Units
Thallium (TI) Low Level
49.2
49.2
ug/L
Vanadium (V) Low Level
48.8
48.8
ug/L
MSD # 1
Parameter
Measured
Final
Units
Antimony (Sb)
48.9
48.9
ug/L
Arsenic (As)
48.9
48.9
ug/L
Beryllium (Be)
50.2
50.2
ug/L
Cadmium (Cd)
49.4
49.4
ug/L
Chromium (Cr)
49.2
49.2
ug/L
Cobalt (Co)
62
62
ug/L
Lead (Pb)
49.2
49.2
ug/L
Molybdenum (Mo)
49.4
49.4
ug/L
Nickel (Ni)
49.8
49.8
ug/L
Selenium (Se)
46.7
46.7
ug/L
Thallium (TI) Low Level
49.2
49.2
ug/L
Vanadium (V) Low Level
48.9
48.9
ug/L
Parent Sample:
J24030517 -- 2024007430
Dil
MDL
Spike
% Recovery
LCL
UCL
1
0.041
50
98.2
75
125
1
0.114
50
97
75
125
Parent Sample:
J24030517
-- 2024007430
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
1
0.104
50
97.7
75
125
0.0225
1
0.111
50
97.2
75
125
0.838
1
0.249
50
100
75
125
4.85
1
0.032
50
97.1
75
125
0.136
1
0.185
50
98
75
125
0.354
1
0.077
50
96
75
125
1.19
1
0.037
50
98.1
75
125
0.829
1
0.18
50
98.7
75
125
0.38
1
0.256
50
97.7
75
125
0.246
1
0.193
50
93
75
125
3.24
1
0.041
50
98.1
75
125
0.0571
1
0.114
50
97.3
75
125
0.296
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030520
Level II QC Summary
Q24040089 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Page 32 of 36
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
-0.015
-0.015
ug/L
1
0.104
1
< MDL
Arsenic (As)
-0.003
-0.003
ug/L
1
0.111
1
< MDL
Beryllium (Be)
0
0
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0.001
0.001
ug/L
1
0.032
1
< MDL
Chromium (Cr)
0.007
0.007
ug/L
1
0.185
1
< MDL
Cobalt (Co)
-0.006
-0.006
ug/L
1
0.077
1
< MDL
Lead (Pb)
0.007
0.007
ug/L
1
0.037
1
< MDL
Molybdenum (Mo)
0.007
0.007
ug/L
1
0.18
1
< MDL
Nickel (Ni)
0.013
0.013
ug/L
1
0.256
1
< MDL
Selenium (Se)
0.005
0.005
ug/L
1
0.193
1
< MDL
Thallium (TI) Low Level
-0.007
-0.007
ug/L
1
0.041
0.2
< MDL
Vanadium (V) Low Level
0.005
0.005
ug/L
1
0.114
0.3
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
49.6
49.6
ug/L
1
0.104
50
99.1
80
120
Arsenic (As)
48
48
ug/L
1
0.111
50
96.1
80
120
Beryllium (Be)
48.6
48.6
ug/L
1
0.249
50
97.1
80
120
Cadmium (Cd)
49.7
49.7
ug/L
1
0.032
50
99.4
80
120
Chromium (Cr)
49.9
49.9
ug/L
1
0.185
50
99.8
80
120
Cobalt (Co)
49.3
49.3
ug/L
1
0.077
50
98.6
80
120
Lead (Pb)
50
50
ug/L
1
0.037
50
99.9
80
120
Molybdenum (Mo)
50.5
50.5
ug/L
1
0.18
50
101
80
120
Nickel (Ni)
49.6
49.6
ug/L
1
0.256
50
99.2
80
120
Selenium (Se)
46.9
46.9
ug/L
1
0.193
50
93.7
80
120
Thallium (TI) Low Level
49.7
49.7
ug/L
1
0.041
50
99.4
80
120
Vanadium (V) Low Level
49.5
49.5
ug/L
1
0.114
50
98.9
80
120
MS # 1
Parent Sample:
J24030520 -- 2024007462
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
49.7
49.7
ug/L
1
0.104
50
99.5
75
125
Arsenic (As)
48.4
48.4
ug/L
1
0.111
50
96.6
75
125
Beryllium (Be)
49
49
ug/L
1
0.249
50
97.6
75
125
Cadmium (Cd)
49.8
49.8
ug/L
1
0.032
50
99.5
75
125
Chromium (Cr)
50.2
50.2
ug/L
1
0.185
50
99.6
75
125
Cobalt (Co)
48.7
48.7
ug/L
1
0.077
50
97.1
75
125
Lead (Pb)
49.7
49.7
ug/L
1
0.037
50
99.1
75
125
Molybdenum (Mo)
50.6
50.6
ug/L
1
0.18
50
101
75
125
Nickel (Ni)
48.5
48.5
ug/L
1
0.256
50
96.2
75
125
Selenium (Se)
47.4
47.4
ug/L
1
0.193
50
94.4
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 33 of 36
This report shall not be reproduced, except in full.
Order # J24030520
Level II QC Summary
Q24040089 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 1
Parameter
Measured
Final
Units
Thallium (TI) Low Level
49.6
49.6
ug/L
Vanadium (V) Low Level
50.1
50.1
ug/L
MSD # 1
Parameter
Measured
Final
Units
Antimony (Sb)
49.7
49.7
ug/L
Arsenic (As)
48.1
48.1
ug/L
Beryllium (Be)
48.8
48.8
ug/L
Cadmium (Cd)
49.5
49.5
ug/L
Chromium (Cr)
50
50
ug/L
Cobalt (Co)
48.6
48.6
ug/L
Lead (Pb)
49.8
49.8
ug/L
Molybdenum (Mo)
50.7
50.7
ug/L
Nickel (Ni)
49.4
49.4
ug/L
Selenium (Se)
46.3
46.3
ug/L
Thallium (TI) Low Level
49.7
49.7
ug/L
Vanadium (V) Low Level
49.7
49.7
ug/L
Parent Sample:
J24030520 -- 2024007462
Dil
MDL
Spike
% Recovery
LCL
UCL
1
0.041
50
99.2
75
125
1
0.114
50
100
75
125
Parent Sample:
J24030520
-- 2024007462
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
1
0.104
50
99.4
75
125
0.0624
1
0.111
50
96
75
125
0.553
1
0.249
50
97.2
75
125
0.439
1
0.032
50
99
75
125
0.52
1
0.185
50
99.4
75
125
0.245
1
0.077
50
97
75
125
0.0845
1
0.037
50
99.4
75
125
0.341
1
0.18
50
101
75
125
0.239
1
0.256
50
97.9
75
125
1.81
1
0.193
50
92.2
75
125
2.38
1
0.041
50
99.3
75
125
0.0967
1
0.114
50
99.1
75
125
0.826
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 34 of 36
This report shall not be reproduced, except in full.
Order # J24030520
Level II QC Summary
Q24040060 TDS TOTAL DISSOLVED SOLIDS
Blank # 1
Blank # 2
Parameter Measured Final
TDS -0.5
Parameter Measured Final
TDS -0.3
Duplicate # 1
Parameter Measured Final
TDS 187
Duplicate # 2
Parameter Measured Final
TDS 18
LCS # 1
LCS # 2
Parameter Measured Final
TDS 493
Parameter Measured Final
TDS 488
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
25
25
< MDL
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
25
25
< MDL
Parent Sample:
J24030005 -- 2024004977
Units
Dil
MDL
RPD
Qualifier
mg/L
1
25
1.06
Parent Sample:
J24030520 -- 2024007461
Units
Dil
MDL
RPD
Qualifier
mg/L
1
25
0
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
25
500
98.6
90
110
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
25
500
97.6
90
110

Certificate of Laboratory Analysis Page 35 of 36
This report shall not be reproduced, except in full.
Order # J24030520
Level II QC Summary
Q24040056 TSS TOTAL SUSPENDED SOLIDS
Blank # 1
Parameter Measured Final
TSS 0
Blank # 2
Parameter Measured Final
TSS -0.1
Duplicate # 1
Parameter Measured Final
TSS 56.8
Duplicate # 2
Parameter Measured Final
TSS 11.2
LCS # 1
LCS # 2
Parameter Measured Final
TSS 94.8
Parameter Measured Final
TSS 96
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
5
5
< MDL
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
5
5
< MDL
Parent Sample:
J24030519 -- 2024007451
Units
Dil
MDL
RPD
Qualifier
mg/L
1
5
14.3
R1
Parent Sample:
J24040156 -- 2024008360
Units
Dil
MDL
RPD
Qualifier
mg/L
1
5
1.77
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
5
100
94.8
90
110
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
5
100
96
90
110
Qualifiers:
R1 Relative Percent Difference exceeded method acceptance limits.

Duke Energy Analytical Laboratory
DUKE/r Mall Cede MGO]A2'ROM11e 14e11
mry RdENERGY+ Hurt —Or. N.
C. 2Bo18
'.'.4.62C5
Fax;(Tel1 A73ZC39
Project Name
Ph.". M°:
ABHEVILLE AIRPORT FILL AREA IV
Client JOHN TOEPFER, BRYAN MOELLER,
DEE O'BRIEN, JOSH STOWE, CONNOR ZAHORA
Operating Unit: AE00
Process: BENVWS
Account:
Project:
Aetivtty ID:
Facility 10: ABA
Program 1 E00S Task code: Sub PragramlTask Code:
coMPLIANCEMTRFL
Sample Description or ID
I W-1 AR-A4R
D-A4
CHAIN OF CUSTODY RECORD AND ANALYSIS_ REQUEST FORM
-....._._._.........._...._._._._._._._._.-.
....... ._.�.-.-._._._._._.-Anal ical Laborato Use Onl.-------------------------------------------
._._-_-_.-._._._._...._-...�._1
Page 36 of 36
ter#
f) Matrix WATER
Nc )_
i Page _1Jofi_
.]+�.
s,m,�so,�gm,���sF*gym
sc_
E DISTRIBUTION
ged 9y
a a r e
41 -017
SAMPLE PROGRAM
ORIGINAL to LAB, COPY to CLIENT
4vi
Ground Water X NPDES
i
dor
l
Drinking Water_ UST_
,cooler Tamp_lFl.._.._
RCRA Waste
._.._.._.._.._.._.._.._.._. _.._.._.._.._.._ ._.._.._.._.._..-..-..-..-..
a
1 Filtration (0.45 um)
b Unfiltered
a Filtered
Preservative
ICE ICE
.. _.. _.. _.-_.. _.. _.. _.. _.. _.. _.. _.. _.. _.................
Container Volume (mL►
300
500
2000
Container Type
PET
HDPE
PET
ff
UO
ICPTRM (6010D);AI,
Be, B, Ca, Cu, Fe, Mg,
iv
0
Customer to complete aff approprfare non -shaded areas.
C m
iii w
Mn,H, Na, Sr, Zn
2
@ p
QidAs,
Q Z
Y
IMS TRM (50203): Sb,
Be, Cd, Cr, Co, Pb,
Mo, NI, Se 71(LLj, V(LL)
Hg 7470A
C
p
o
2
Collection Information
Time
Printed Name
Signature
U
0
4
rI�
F-
4-Z-ZN Ilogs
[61~ 7A1 uQA
x
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tlu
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dS4 FR -107'0 tia2- 15U0 1 i $pp X1 1 1 1 1 2
I I I I I TOTAL 9 CONTAINERS I I 1 0 1 0 1 9 1 9 1 0 1 8 1 0 1 0 1 0 1 0 1 0 1 0 1 o I 26 1
Relinquished By
Daterrime
I/- t,.t
Accepted By: /�
Datp.(Time
a
Requested Turnaround
'rZ
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21 Days
Relinquished By Daterrime
Accepted By: telTime
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Accepted By: DatelTime
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14 Days
SeaALocked By DatefTTme
Sealedfl-ock Opened By Daterrime
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'7 Days
Comments
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NOTE: NCDEQ EDD and EQUIS REQUIRED
• Add_ Cost Will Apply
U
Total E

DUKE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J24030519
Project Name: ASHEVILLE AIRPORT - AIRPORT FILL AREA III - (IN-HOUSE)
Task Code: STRFL
Customer Name(s): John Toepfer, B Moeller, Josh Stowe, C Zahora
Customer Address: Asheville Airport
Lab Contact: Peggy Kendall Phone: [phone]
Report Authorized By: pate: 4/17/2024
(Signature) _�+{
c Kendall
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
Page 1 of 31
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
Collected By Sample Description
Page 2 of 31
2024007451
Asheville Airport
02-Apr-24
10:55 AM
Mack Morrison
ASA_MW-1-A3
2024007452
Asheville Airport
02-Apr-24
11:35 AM
Mack Morrison
ASA_MW-2-A3
2024007453
Asheville Airport
02-Apr-24
1:50 PM
Haley Seaton
ASA_MW-3-A3
2024007454
Asheville Airport
02-Apr-24
12:40 PM
Mack Morrison
ASA_MW-4-A3
2024007455
Asheville Airport
02-Apr-24
10:25 AM
Haley Seaton
ASA_MW-5-A3
2024007456
Asheville Airport
02-Apr-24
9:29 AM
Haley Seaton
ASA_MW-6-A3
2024007457
Asheville Airport
02-Apr-24
9:40 AM
Connor Zahora
ASA_MW-7-A3
2024007458
Asheville Airport
02-Apr-24
Mack Morrison
ASA_FD-20240402-2
2024007459
Asheville Airport
02-Apr-24
10:00 AM
Connor Zahora
ASA_FB-20240402-1000
9 Total Samples

Page 3 of 31
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals❑ Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
❑d Job Summary Report
❑d Sample Identification
❑� Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
❑� Analytical Laboratory QC Report
❑ Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑� Chain of Custody
❑� Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 4/17/2024

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030519
Site: ASA MW-1-A3
Collection Date: 04/02/2024 10:55 AM Loc code: ASA MW-1-A3
Sample #: 2024007451
Matrix: GW RCRA
Page 4 of 31
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q24040145
Alkalinity, Bicarbonate
8.17
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:02
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:02
SNEGLIA
Total Alkalinity as CaCO3
8.17
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:02
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24040077
Chloride
2.5
mg/L
0.1
0.0154
1
EPA 9056A
04/04/2024 14:09
BGN9034
Sulfate
1.2
mg/L
0.1
0.0428
1
EPA 9056A
04/04/2024 14:09
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040169
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/11/2024 09:05
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24040064
Aluminum (AI)
2.94
mg/L B2
0.01
0.003
1
SW 6010D
04/08/2024 11:15
CELLI06
Barium (Ba)
0.053
mg/L
0.005
0.002
1
SW 601OD
04/08/2024 11:15
CELLI06
Boron (B)
0.005 U
mg/L
0.05
0.005
1
SW 6010D
04/08/2024 11:15
CELLI06
Calcium (Ca)
3.03
mg/L
0.05
0.012
1
SW 601OD
04/08/2024 11:15
CELLI06
Copper (Cu)
0.004 J
mg/L
0.005
0.001
1
SW 6010D
04/08/2024 11:15
CELLI06
Iron (Fe)
2.94
mg/L
0.01
0.004
1
SW 601OD
04/08/2024 11:15
CELL106
Magnesium (Mg)
1.99
mg/L
0.02
0.008
1
SW 6010D
04/08/2024 11:15
CELLI06
Manganese (Mn)
0.193
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 11:15
CELLI06
Potassium (K)
2.43
mg/L
0.1
0.031
1
SW 6010D
04/08/2024 11:15
CELLI06
Sodium (Na)
2.47
mg/L
0.05
0.017
1
SW 601OD
04/08/2024 11:15
CELLI06
Strontium (Sr)
0.035
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 11:15
CELLI06
Zinc (Zn)
0.067
mg/L
0.015
0.004
1
SW 6010D
04/08/2024 11:15
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040070
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
04/08/2024 13:57
MHALL3
Arsenic (As)
0.201 J
ug/L
1
0.111
1
SW 6020B
04/08/2024 13:57
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
04/08/2024 13:57
MHALL3
Cadmium (Cd)
0.043 J
ug/L
1
0.032
1
SW 6020E
04/08/2024 13:57
MHALL3
Chromium (Cr)
1.89
ug/L
1
0.185
1
SW 6020B
04/08/2024 13:57
MHALL3
Cobalt (Co)
2.74
ug/L
1
0.077
1
SW 6020E
04/08/2024 13:57
MHALL3
Lead (Pb)
0.779 J
ug/L
1
0.037
1
SW 6020B
04/08/2024 13:57
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020E
04/08/2024 13:57
MHALL3
Nickel (Ni)
2.68
ug/L
1
0.256
1
SW 6020E
04/08/2024 13:57
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
04/08/2024 13:57
MHALL3
Thallium (TI) Low Level
0.088 J
ug/L
0.2
0.041
1
SW 6020B
04/08/2024 13:57
MHALL3
Vanadium (V) Low Level
2.64
ug/L
0.3
0.114
1
SW 6020E
04/08/2024 13:57
MHALL3
TOTAL DISSOLVED SOLIDS - Q24040060
TDS
30.0
mg/L
25
25
1
SM2540C
04/04/202412:35
HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030519
Site: ASA MW-1-A3
Collection Date: 04/02/2024 10:55 AM Loc code: ASA MW-1-A3
Analyte Result Units Qualifiers RDL MDL DF
TOTAL SUSPENDED SOLIDS - Q24040056
TSS 49 mg/L 5 5 1
Sample #: 2024007451
Matrix: GW RCRA
Page 5 of 31
Method Analysis Date/Time Analyst
SM2540D 04/04/2024 07:33 HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030519
Site: ASA MW-2-A3
Collection Date: 04/02/2024 11:35 AM Loc code: ASA MW-2-A3
Sample #: 2024007452
Matrix: GW RCRA
Page 6 of 31
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q24040145
Alkalinity, Bicarbonate
5.70
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:08
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:08
SNEGLIA
Total Alkalinity as CaCO3
5.70
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:08
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24040077
Chloride
0.97
mg/L
0.1
0.0154
1
EPA 9056A
04/04/2024 15:08
BGN9034
Sulfate
0.20
mg/L
0.1
0.0428
1
EPA 9056A
04/04/2024 15:08
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040169
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/11/2024 09:12
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24040064
Aluminum (AI)
0.021
mg/L B2
0.01
0.003
1
SW 6010D
04/08/2024 11:26
CELLI06
Barium (Ba)
0.013
mg/L
0.005
0.002
1
SW 601OD
04/08/2024 11:26
CELLI06
Boron (B)
0.005 U
mg/L
0.05
0.005
1
SW 6010D
04/08/2024 11:26
CELLI06
Calcium (Ca)
0.197
mg/L
0.05
0.012
1
SW 601OD
04/08/2024 11:26
CELLI06
Copper (Cu)
0.001 J
mg/L
0.005
0.001
1
SW 6010D
04/08/2024 11:26
CELLI06
Iron (Fe)
0.004 U
mg/L
0.01
0.004
1
SW 601OD
04/08/2024 11:26
CELL106
Magnesium (Mg)
0.455
mg/L
0.02
0.008
1
SW 6010D
04/08/2024 11:26
CELLI06
Manganese (Mn)
0.014
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 11:26
CELLI06
Potassium (K)
0.470
mg/L
0.1
0.031
1
SW 6010D
04/08/2024 11:26
CELLI06
Sodium (Na)
2.90
mg/L
0.05
0.017
1
SW 601OD
04/08/2024 11:26
CELLI06
Strontium (Sr)
0.002 J
mg/L
0.005
0.001
1
SW 601 OD
04/08/2024 11:26
CELLI06
Zinc (Zn)
0.01 J
mg/L
0.015
0.004
1
SW 6010D
04/08/2024 11:26
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040070
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
04/08/2024 14:30
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
04/08/2024 14:30
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
04/08/2024 14:30
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020E
04/08/2024 14:30
MHALL3
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
SW 6020B
04/08/2024 14:30
MHALL3
Cobalt (Co)
0.172 J
ug/L
1
0.077
1
SW 6020E
04/08/2024 14:30
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
04/08/2024 14:30
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020E
04/08/2024 14:30
MHALL3
Nickel (Ni)
1.37
ug/L
1
0.256
1
SW 6020E
04/08/2024 14:30
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
04/08/2024 14:30
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
04/08/2024 14:30
MHALL3
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
SW 6020E
04/08/2024 14:30
MHALL3
TOTAL DISSOLVED SOLIDS - Q24040060
TDS
25 U
mg/L
25
25
1
SM2540C
04/04/2024 12:35
HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030519
Site: ASA MW-2-A3
Collection Date: 04/02/2024 11:35 AM Loc code: ASA MW-2-A3
Analyte Result Units Qualifiers RDL MDL DF
TOTAL SUSPENDED SOLIDS - Q24040056
TSS 5 U mg/L 5 5 1
Sample #: 2024007452
Matrix: GW RCRA
Page 7 of 31
Method Analysis Date/Time Analyst
SM2540D 04/04/2024 07:33 HHOOGKA

Certificate of Laboratory Analysis Page 8 of 31
This report shall not be reproduced, except in full.
Order # J24030519
Site: ASA MW-3-A3
Sample #: 2024007453
Collection Date: 04/02/2024 01:50 PM
Loc code:
ASA MW-3-A3
Matrix: GW
RCRA
Analyte Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q24040145
Alkalinity, Bicarbonate 3.89 J
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:14
SNEGLIA
Alkalinity, Carbonate 1.7 U
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:14
SNEGLIA
Total Alkalinity as CaCO3 3.89 J
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:14
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24040077
Chloride 0.62 mg/L
Sulfate 0.09 J mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040169
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040064
Aluminum (AI)
1.09
mg/L
Barium (Ba)
0.017
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
0.482
mg/L
Copper (Cu)
0.004 J
mg/L
Iron (Fe)
1.11
mg/L
Magnesium (Mg)
0.845
mg/L
Manganese (Mn)
0.027
mg/L
Potassium (K)
0.892
mg/L
Sodium (Na)
1.22
mg/L
Strontium (Sr)
0.007
mg/L
Zinc (Zn)
0.008 J
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040070
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.126 J
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
1.15
ug/L
Cobalt (Co)
0.457 J
ug/L
Lead (Pb)
0.282 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
1.09
ug/L
Selenium (Se)
0.193 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
0.873
ug/L
TOTAL DISSOLVED SOLIDS - Q24040060
TDS
25 U
mg/L
0.1
0.0154
1
EPA 9056A
04/04/2024 15:27
BGN9034
0.1
0.0428
1
EPA 9056A
04/04/2024 15:27
BGN9034
0.05
0.01
1
EPA 7470A
04/11/2024 09:15
SNEGLIA
B2 0.01
0.003
1
SW 6010D
04/08/2024 11:30
CELL106
0.005
0.002
1
SW 601OD
04/08/2024 11:30
CELL106
0.05
0.005
1
SW 6010D
04/08/2024 11:30
CELL106
0.05
0.012
1
SW 601OD
04/08/2024 11:30
CELL106
0.005
0.001
1
SW 6010D
04/08/2024 11:30
CELL106
0.01
0.004
1
SW 601OD
04/08/2024 11:30
CELL106
0.02
0.008
1
SW 6010D
04/08/2024 11:30
CELL106
0.005
0.001
1
SW 601OD
04/08/2024 11:30
CELL106
0.1
0.031
1
SW 6010D
04/08/2024 11:30
CELL106
0.05
0.017
1
SW 601OD
04/08/2024 11:30
CELL106
0.005
0.001
1
SW 601OD
04/08/2024 11:30
CELL106
0.015
0.004
1
SW 6010D
04/08/2024 11:30
CELL106
1
0.104
1
SW 6020B
04/08/2024 14:39
MHALL3
1
0.111
1
SW 6020B
04/08/2024 14:39
MHALL3
1
0.249
1
SW 6020B
04/08/2024 14:39
MHALL3
1
0.032
1
SW 6020E
04/08/2024 14:39
MHALL3
1
0.185
1
SW 6020B
04/08/2024 14:39
MHALL3
1
0.077
1
SW 6020E
04/08/2024 14:39
MHALL3
1
0.037
1
SW 6020B
04/08/2024 14:39
MHALL3
1
0.18
1
SW 6020E
04/08/2024 14:39
MHALL3
1
0.256
1
SW 6020E
04/08/2024 14:39
MHALL3
1
0.193
1
SW 6020B
04/08/2024 14:39
MHALL3
0.2
0.041
1
SW 6020B
04/08/2024 14:39
MHALL3
0.3
0.114
1
SW 6020E
04/08/2024 14:39
MHALL3
25
25
1
SM2540C
04/04/202412:35
HHOOGKA

Certificate of Laboratory Analysis Page 9 of 31
This report shall not be reproduced, except in full.
Order # J24030519
Site: ASA MW-3-A3 Sample #: 2024007453
Collection Date: 04/02/2024 01:50 PM Loc code: ASA MW-3-A3 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
TOTAL SUSPENDED SOLIDS - Q24040056
TSS 58 mg/L 5 5 1 SM2540D 04/04/2024 07:33 HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030519
Site: ASA MW-4-A3
Collection Date: 04/02/2024 12:40 PM Loc code: ASA MW-4-A3
Sample #: 2024007454
Matrix: GW RCRA
Page 10 of 31
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q24040145
Alkalinity, Bicarbonate
7.22
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:20
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:20
SNEGLIA
Total Alkalinity as CaCO3
7.22
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:20
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24040077
Chloride
0.90
mg/L
0.1
0.0154
1
EPA 9056A
04/04/2024 15:47
BGN9034
Sulfate
0.0428 U
mg/L
0.1
0.0428
1
EPA 9056A
04/04/2024 15:47
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040169
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/11/2024 09:17
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24040064
Aluminum (AI)
0.033
mg/L B2
0.01
0.003
1
SW 6010D
04/08/2024 11:34
CELLI06
Barium (Ba)
0.022
mg/L
0.005
0.002
1
SW 601OD
04/08/2024 11:34
CELLI06
Boron (B)
0.005 U
mg/L
0.05
0.005
1
SW 6010D
04/08/2024 11:34
CELLI06
Calcium (Ca)
0.753
mg/L
0.05
0.012
1
SW 601OD
04/08/2024 11:34
CELLI06
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
04/08/2024 11:34
CELLI06
Iron (Fe)
0.005 J
mg/L
0.01
0.004
1
SW 601 OD
04/08/2024 11:34
CELL106
Magnesium (Mg)
1.18
mg/L
0.02
0.008
1
SW 6010D
04/08/2024 11:34
CELLI06
Manganese (Mn)
0.010
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 11:34
CELLI06
Potassium (K)
0.872
mg/L
0.1
0.031
1
SW 6010D
04/08/2024 11:34
CELLI06
Sodium (Na)
1.20
mg/L
0.05
0.017
1
SW 601OD
04/08/2024 11:34
CELLI06
Strontium (Sr)
0.007
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 11:34
CELLI06
Zinc (Zn)
0.007 J
mg/L
0.015
0.004
1
SW 6010D
04/08/2024 11:34
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040070
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
04/08/2024 14:47
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
04/08/2024 14:47
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
04/08/2024 14:47
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020E
04/08/2024 14:47
MHALL3
Chromium (Cr)
0.264 J
ug/L
1
0.185
1
SW 6020B
04/08/2024 14:47
MHALL3
Cobalt (Co)
0.077 U
ug/L
1
0.077
1
SW 6020E
04/08/2024 14:47
MHALL3
Lead (Pb)
0.05 J
ug/L
1
0.037
1
SW 6020B
04/08/2024 14:47
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020E
04/08/2024 14:47
MHALL3
Nickel (Ni)
1.08
ug/L
1
0.256
1
SW 6020E
04/08/2024 14:47
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
04/08/2024 14:47
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
04/08/2024 14:47
MHALL3
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
SW 6020E
04/08/2024 14:47
MHALL3
TOTAL DISSOLVED SOLIDS - Q24040060
TDS
25 U
mg/L
25
25
1
SM2540C
04/04/2024 12:35
HHOOGKA

Certificate of Laboratory Analysis Page 11 of31
This report shall not be reproduced, except in full.
Order # J24030519
Site: ASA MW-4-A3 Sample #: 2024007454
Collection Date: 04/02/2024 12:40 PM Loc code: ASA MW-4-A3 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
TOTAL SUSPENDED SOLIDS - Q24040056
TSS 5 U mg/L 5 5 1 SM2540D 04/04/2024 07:33 HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030519
Site: ASA MW-5-A3
Collection Date: 04/02/2024 10:25 AM Loc code: ASA MW-5-A3
Sample #: 2024007455
Matrix: GW RCRA
Page 12 of 31
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q24040145
Alkalinity, Bicarbonate
7.45
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:26
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:26
SNEGLIA
Total Alkalinity as CaCO3
7.45
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:26
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24040077
Chloride
0.91
mg/L
0.1
0.0154
1
EPA 9056A
04/04/2024 16:07
BGN9034
Sulfate
0.08 J
mg/L
0.1
0.0428
1
EPA 9056A
04/04/2024 16:07
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040169
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/11/2024 09:19
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24040064
Aluminum (AI)
0.118
mg/L B2
0.01
0.003
1
SW 6010D
04/08/2024 11:38
CELLI06
Barium (Ba)
0.013
mg/L
0.005
0.002
1
SW 601OD
04/08/2024 11:38
CELLI06
Boron (B)
0.005 U
mg/L
0.05
0.005
1
SW 6010D
04/08/2024 11:38
CELLI06
Calcium (Ca)
1.31
mg/L
0.05
0.012
1
SW 601OD
04/08/2024 11:38
CELLI06
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
04/08/2024 11:38
CELLI06
Iron (Fe)
0.074
mg/L
0.01
0.004
1
SW 601OD
04/08/2024 11:38
CELL106
Magnesium (Mg)
1.09
mg/L
0.02
0.008
1
SW 6010D
04/08/2024 11:38
CELLI06
Manganese (Mn)
0.015
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 11:38
CELLI06
Potassium (K)
0.631
mg/L
0.1
0.031
1
SW 6010D
04/08/2024 11:38
CELLI06
Sodium (Na)
1.14
mg/L
0.05
0.017
1
SW 601OD
04/08/2024 11:38
CELLI06
Strontium (Sr)
0.009
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 11:38
CELLI06
Zinc (Zn)
0.009 J
mg/L
0.015
0.004
1
SW 6010D
04/08/2024 11:38
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040070
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
04/08/2024 14:56
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
04/08/2024 14:56
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
04/08/2024 14:56
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020E
04/08/2024 14:56
MHALL3
Chromium (Cr)
0.619 J
ug/L
1
0.185
1
SW 6020B
04/08/2024 14:56
MHALL3
Cobalt (Co)
0.093 J
ug/L
1
0.077
1
SW 6020E
04/08/2024 14:56
MHALL3
Lead (Pb)
0.05 J
ug/L
1
0.037
1
SW 6020B
04/08/2024 14:56
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020E
04/08/2024 14:56
MHALL3
Nickel (Ni)
1.04
ug/L
1
0.256
1
SW 6020E
04/08/2024 14:56
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
04/08/2024 14:56
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
04/08/2024 14:56
MHALL3
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
SW 6020E
04/08/2024 14:56
MHALL3
TOTAL DISSOLVED SOLIDS - Q24040060
TDS
25 U
mg/L
25
25
1
SM2540C
04/04/2024 12:35
HHOOGKA

Certificate of Laboratory Analysis Page 13 of 31
This report shall not be reproduced, except in full.
Order # J24030519
Site: ASA MW-5-A3 Sample #: 2024007455
Collection Date: 04/02/2024 10:25 AM Loc code: ASA MW-5-A3 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
TOTAL SUSPENDED SOLIDS - Q24040056
TSS 5 U mg/L 5 5 1 SM2540D 04/04/2024 07:33 HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030519
Site: ASA MW-6-A3
Collection Date: 04/02/2024 09:29 AM Loc code: ASA MW-6-A3
Sample #: 2024007456
Matrix: GW RCRA
Page 14 of 31
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q24040145
Alkalinity, Bicarbonate
9.08
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:33
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:33
SNEGLIA
Total Alkalinity as CaCO3
9.08
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:33
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24040077
Chloride
0.55
mg/L
0.1
0.0154
1
EPA 9056A
04/04/2024 16:27
BGN9034
Sulfate
0.06 J
mg/L
0.1
0.0428
1
EPA 9056A
04/04/2024 16:27
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040169
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/11/2024 09:22
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24040064
Aluminum (AI)
0.015
mg/L B2
0.01
0.003
1
SW 6010D
04/08/2024 11:42
CELLI06
Barium (Ba)
0.007
mg/L
0.005
0.002
1
SW 601 OD
04/08/2024 11:42
CELLI06
Boron (B)
0.005 U
mg/L
0.05
0.005
1
SW 6010D
04/08/2024 11:42
CELLI06
Calcium (Ca)
1.82
mg/L
0.05
0.012
1
SW 601 OD
04/08/2024 11:42
CELLI06
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
04/08/2024 11:42
CELLI06
Iron (Fe)
0.004 J
mg/L
0.01
0.004
1
SW 601 OD
04/08/2024 11:42
CELL106
Magnesium (Mg)
0.978
mg/L
0.02
0.008
1
SW 6010D
04/08/2024 11:42
CELLI06
Manganese (Mn)
0.004 J
mg/L
0.005
0.001
1
SW 601 OD
04/08/2024 11:42
CELLI06
Potassium (K)
0.517
mg/L
0.1
0.031
1
SW 6010D
04/08/2024 11:42
CELLI06
Sodium (Na)
0.971
mg/L
0.05
0.017
1
SW 601 OD
04/08/2024 11:42
CELLI06
Strontium (Sr)
0.012
mg/L
0.005
0.001
1
SW 601 OD
04/08/2024 11:42
CELLI06
Zinc (Zn)
0.004 U
mg/L
0.015
0.004
1
SW 6010D
04/08/2024 11:42
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040070
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
04/08/2024 15:04
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
04/08/2024 15:04
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
04/08/2024 15:04
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020E
04/08/2024 15:04
MHALL3
Chromium (Cr)
0.654 J
ug/L
1
0.185
1
SW 6020B
04/08/2024 15:04
MHALL3
Cobalt (Co)
0.077 U
ug/L
1
0.077
1
SW 6020E
04/08/2024 15:04
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
04/08/2024 15:04
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020E
04/08/2024 15:04
MHALL3
Nickel (Ni)
0.341 J
ug/L
1
0.256
1
SW 6020E
04/08/2024 15:04
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
04/08/2024 15:04
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
04/08/2024 15:04
MHALL3
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
SW 6020E
04/08/2024 15:04
MHALL3
TOTAL DISSOLVED SOLIDS - Q24040060
TDS
25 U
mg/L
25
25
1
SM2540C
04/04/2024 12:35
HHOOGKA

Certificate of Laboratory Analysis Page 15 of 31
This report shall not be reproduced, except in full.
Order # J24030519
Site: ASA MW-6-A3 Sample #: 2024007456
Collection Date: 04/02/2024 09:29 AM Loc code: ASA MW-6-A3 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
TOTAL SUSPENDED SOLIDS - Q24040056
TSS 5 U mg/L 5 5 1 SM2540D 04/04/2024 07:33 HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030519
Site: ASA MW-7-A3
Collection Date: 04/02/2024 09:40 AM Loc code: ASA MW-7-A3
Sample #: 2024007457
Matrix: GW RCRA
Page 16 of 31
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q24040145
Alkalinity, Bicarbonate
7.25
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:39
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:39
SNEGLIA
Total Alkalinity as CaCO3
7.25
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:39
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24040077
Chloride
0.84
mg/L
0.1
0.0154
1
EPA 9056A
04/04/2024 16:46
BGN9034
Sulfate
0.43
mg/L
0.1
0.0428
1
EPA 9056A
04/04/2024 16:46
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040169
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/11/2024 09:24
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24040064
Aluminum (AI)
0.017
mg/L B2
0.01
0.003
1
SW 6010D
04/08/2024 11:46
CELLI06
Barium (Ba)
0.011
mg/L
0.005
0.002
1
SW 601 OD
04/08/2024 11:46
CELLI06
Boron (B)
0.01 J
mg/L
0.05
0.005
1
SW 6010D
04/08/2024 11:46
CELLI06
Calcium (Ca)
1.44
mg/L
0.05
0.012
1
SW 601 OD
04/08/2024 11:46
CELLI06
Copper (Cu)
0.002 J
mg/L
0.005
0.001
1
SW 6010D
04/08/2024 11:46
CELLI06
Iron (Fe)
0.004 J
mg/L
0.01
0.004
1
SW 601 OD
04/08/2024 11:46
CELL106
Magnesium (Mg)
1.04
mg/L
0.02
0.008
1
SW 6010D
04/08/2024 11:46
CELLI06
Manganese (Mn)
0.003 J
mg/L
0.005
0.001
1
SW 601 OD
04/08/2024 11:46
CELLI06
Potassium (K)
0.887
mg/L
0.1
0.031
1
SW 6010D
04/08/2024 11:46
CELLI06
Sodium (Na)
1.43
mg/L
0.05
0.017
1
SW 601 OD
04/08/2024 11:46
CELLI06
Strontium (Sr)
0.009
mg/L
0.005
0.001
1
SW 601 OD
04/08/2024 11:46
CELLI06
Zinc (Zn)
0.014 J
mg/L
0.015
0.004
1
SW 6010D
04/08/2024 11:46
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040070
Antimony (Sb)
0.243 J
ug/L
1
0.104
1
SW 6020B
04/08/2024 15:12
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
04/08/2024 15:12
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
04/08/2024 15:12
MHALL3
Cadmium (Cd)
0.09 J
ug/L
1
0.032
1
SW 6020E
04/08/2024 15:12
MHALL3
Chromium (Cr)
0.357 J
ug/L
1
0.185
1
SW 6020B
04/08/2024 15:12
MHALL3
Cobalt (Co)
0.077 U
ug/L
1
0.077
1
SW 6020E
04/08/2024 15:12
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
04/08/2024 15:12
MHALL3
Molybdenum (Mo)
1.06
ug/L
1
0.18
1
SW 6020E
04/08/2024 15:12
MHALL3
Nickel (Ni)
0.95 J
ug/L
1
0.256
1
SW 6020E
04/08/2024 15:12
MHALL3
Selenium (Se)
0.299 J
ug/L
1
0.193
1
SW 6020B
04/08/2024 15:12
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
04/08/2024 15:12
MHALL3
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
SW 6020E
04/08/2024 15:12
MHALL3
TOTAL DISSOLVED SOLIDS - Q24040060
TDS
25 U
mg/L
25
25
1
SM2540C
04/04/2024 12:35
HHOOGKA

Certificate of Laboratory Analysis Page 17 of 31
This report shall not be reproduced, except in full.
Order # J24030519
Site: ASA MW-7-A3 Sample #: 2024007457
Collection Date: 04/02/2024 09:40 AM Loc code: ASA MW-7-A3 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
TOTAL SUSPENDED SOLIDS - Q24040056
TSS 5 U mg/L 5 5 1 SM2540D 04/04/2024 07:33 HHOOGKA

Certificate of Laboratory Analysis Page 18 of 31
This report shall not be reproduced, except in full.
Order # J24030519
Site: ASA FD-20240402-2
Duplicate
Sample #: 2024007458
Collection Date: 04/02/2024
Loc code: ASA FD
Matrix: GW
RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q24040145
Alkalinity, Bicarbonate
7.91
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:45
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:45
SNEGLIA
Total Alkalinity as CaCO3
7.91
mg/L
5
1.7
1
SM 2320134d
04/09/2024 10:45
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24040077
Chloride 0.91 mg/L
Sulfate 0.0428 U mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040169
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040064
Aluminum (AI)
0.028
mg/L
Barium (Ba)
0.021
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
0.927
mg/L
Copper (Cu)
0.001 U
mg/L
Iron (Fe)
0.004 U
mg/L
Magnesium (Mg)
1.21
mg/L
Manganese (Mn)
0.009
mg/L
Potassium (K)
0.879
mg/L
Sodium (Na)
1.24
mg/L
Strontium (Sr)
0.008
mg/L
Zinc (Zn)
0.006 J
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040070
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.267 J
ug/L
Cobalt (Co)
0.077 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.916 J
ug/L
Selenium (Se)
0.193 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
0.114 U
ug/L
TOTAL DISSOLVED SOLIDS - Q24040060
TDS
25 U
mg/L
0.1
0.0154
1
EPA 9056A
04/04/2024 17:06
BGN9034
0.1
0.0428
1
EPA 9056A
04/04/2024 17:06
BGN9034
0.05
0.01
1
EPA 7470A
04/11/2024 09:26
SNEGLIA
B2 0.01
0.003
1
SW 6010D
04/08/2024 11:50
CELL106
0.005
0.002
1
SW 6010D
04/08/2024 11:50
CELL106
0.05
0.005
1
SW 6010D
04/08/2024 11:50
CELL106
0.05
0.012
1
SW 6010D
04/08/2024 11:50
CELL106
0.005
0.001
1
SW 6010D
04/08/2024 11:50
CELL106
0.01
0.004
1
SW 601OD
04/08/2024 11:50
CELL106
0.02
0.008
1
SW 6010D
04/08/2024 11:50
CELL106
0.005
0.001
1
SW 6010D
04/08/2024 11:50
CELL106
0.1
0.031
1
SW 6010D
04/08/2024 11:50
CELL106
0.05
0.017
1
SW 6010D
04/08/2024 11:50
CELL106
0.005
0.001
1
SW 6010D
04/08/2024 11:50
CELL106
0.015
0.004
1
SW 6010D
04/08/2024 11:50
CELL106
1
0.104
1
SW 6020B
04/08/2024 15:21
MHALL3
1
0.111
1
SW 6020B
04/08/2024 15:21
MHALL3
1
0.249
1
SW 6020B
04/08/2024 15:21
MHALL3
1
0.032
1
SW 6020E
04/08/2024 15:21
MHALL3
1
0.185
1
SW 6020B
04/08/2024 15:21
MHALL3
1
0.077
1
SW 6020E
04/08/2024 15:21
MHALL3
1
0.037
1
SW 6020B
04/08/2024 15:21
MHALL3
1
0.18
1
SW 6020E
04/08/2024 15:21
MHALL3
1
0.256
1
SW 6020E
04/08/2024 15:21
MHALL3
1
0.193
1
SW 6020B
04/08/2024 15:21
MHALL3
0.2
0.041
1
SW 6020B
04/08/2024 15:21
MHALL3
0.3
0.114
1
SW 6020E
04/08/2024 15:21
MHALL3
25
25
1
SM2540C
04/04/202412:35
HHOOGKA

Certificate of Laboratory Analysis Page 19 of 31
This report shall not be reproduced, except in full.
Order # J24030519
Site: ASA FD-20240402-2 Duplicate Sample #: 2024007458
Collection Date: 04/02/2024 Loc code: ASA FD Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
TOTAL SUSPENDED SOLIDS - Q24040056
TSS 5 U mg/L 5 5 1 SM2540D 04/04/2024 07:33 HHOOGKA

Certificate of Laboratory Analysis Page 20 of 31
This report shall not be reproduced, except in full.
Order # J24030519
Site: ASA FB-20240402-1000 Field Blank Sample #: 2024007459
Collection Date: 04/02/2024 10:00 AM Loc code: ASA FB Matrix: GW RCRA
Analyte Result Units Qualifiers RDL
LOW LEVEL ALKALINITY (FIXED END POINT) - Q24040145
Alkalinity, Bicarbonate 1.7 U mg/L 5
Alkalinity, Carbonate 1.7 U mg/L 5
Total Alkalinity as CaCO3 1.7 U mg/L 5
(CaCO3)
INORGANIC IONS BY IC - Q24040077
Chloride 0.03 J mg/L
Sulfate 0.0428 U mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040169
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040064
Aluminum (AI)
0.003 U
mg/L
Barium (Ba)
0.002 U
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
0.012 U
mg/L
Copper (Cu)
0.001 U
mg/L
Iron (Fe)
0.004 U
mg/L
Magnesium (Mg)
0.008 U
mg/L
Manganese (Mn)
0.001 U
mg/L
Potassium (K)
0.031 U
mg/L
Sodium (Na)
0.017 U
mg/L
Strontium (Sr)
0.001 U
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040070
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.185 U
ug/L
Cobalt (Co)
0.077 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.256 U
ug/L
Selenium (Se)
0.193 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
0.114 U
ug/L
MDL
DF
Method
Analysis Date/Time
Analyst
1.7
1
SM 2320134d
04/09/2024 10:52
SNEGLIA
1.7
1
SM 2320134d
04/09/2024 10:52
SNEGLIA
1.7
1
SM 2320134d
04/09/2024 10:52
SNEGLIA
0.1
0.0154
1
EPA 9056A
04/04/2024 17:26
BGN9034
0.1
0.0428
1
EPA 9056A
04/04/2024 17:26
BGN9034
0.05
0.01
1
EPA 7470A
04/11/2024 09:29
SNEGLIA
B2 0.01
0.003
1
SW 601OD
04/08/2024 11:54
CELL106
0.005
0.002
1
SW 601OD
04/08/2024 11:54
CELL106
0.05
0.005
1
SW 601OD
04/08/2024 11:54
CELL106
0.05
0.012
1
SW 601OD
04/08/2024 11:54
CELL106
0.005
0.001
1
SW 601OD
04/08/2024 11:54
CELL106
0.01
0.004
1
SW 601OD
04/08/2024 11:54
CELL106
0.02
0.008
1
SW 601OD
04/08/2024 11:54
CELL106
0.005
0.001
1
SW 601OD
04/08/2024 11:54
CELL106
0.1
0.031
1
SW 601OD
04/08/2024 11:54
CELL106
0.05
0.017
1
SW 601OD
04/08/2024 11:54
CELL106
0.005
0.001
1
SW 601OD
04/08/2024 11:54
CELL106
0.015
0.004
1
SW 601OD
04/08/2024 11:54
CELL106
1
0.104
1
SW 6020B
04/08/2024 15:29
MHALL3
1
0.111
1
SW 6020B
04/08/2024 15:29
MHALL3
1
0.249
1
SW 6020B
04/08/2024 15:29
MHALL3
1
0.032
1
SW 6020E
04/08/2024 15:29
MHALL3
1
0.185
1
SW 6020B
04/08/2024 15:29
MHALL3
1
0.077
1
SW 6020E
04/08/2024 15:29
MHALL3
1
0.037
1
SW 6020B
04/08/2024 15:29
MHALL3
1
0.18
1
SW 6020E
04/08/2024 15:29
MHALL3
1
0.256
1
SW 6020E
04/08/2024 15:29
MHALL3
1
0.193
1
SW 6020B
04/08/2024 15:29
MHALL3
0.2
0.041
1
SW 6020B
04/08/2024 15:29
MHALL3
0.3
0.114
1
SW 6020E
04/08/2024 15:29
MHALL3

Certificate of Laboratory Analysis Page 21 of 31
This report shall not be reproduced, except in full.
Order # J24030519
Qualifiers:
B2 Target analyte was detected in Method/Prep Blank(s) at a concentration greater than % the reporting limit but less than the
reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an estimate.

Certificate of Laboratory Analysis Page 22 of 31
This report shall not be reproduced, except in full.
Order # J24030519
Level II QC Summary
Q24040145 ALK LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Duplicate # 1
Parent Sample:
J24030519 -- 2024007451
Parameter Measured
Final
Units
Dil
MDL
RPD Qualifier
Alkalinity, Bicarbonate
8.27
mg/L
1
1.7
1.22
Alkalinity, Carbonate
0
mg/L
1
1.7
0
Total Alkalinity as CaCO3
8.27
mg/L
1
1.7
1.22
LCS # 1
Parameter Measured
Final
Units
Dil
MDL S ike % Recovery
LCL UCL Qualifier
Total Alkalinity as CaCO3
72.4
mg/L
1
1.7 77.9 93
85 115
(CaCO3)

Certificate of Laboratory Analysis Page 23 of 31
This report shall not be reproduced, except in full.
Order # J24030519
Level II QC Summary
Q24040077 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Sulfate
0
0
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S Ike
% Recovery
LCL
UCL
Chloride
5.15
5.15
mg/L
1
0.0154
5
103
80
120
Sulfate
5.21
5.21
mg/L
1
0.0428
5
104
80
120
MS # 1
Parent Sample:
J24030519 -- 2024007451
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Chloride
7.48
7.48
mg/L
1
0.0154
5
99.8
80
120
Sulfate
6.25
6.25
mg/L
1
0.0428
5
101
80
120
MSD # 1
Parent Sample:
J24030519 -- 2024007451
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Chloride
7.47
7.47
mg/L
1
0.0154
5
99.7
80
120 0.12
Sulfate
6.28
6.28
mg/L
1
0.0428
5
102
80
120 0.532
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 24 of 31
This report shall not be reproduced, except in full.
Order # J24030519
Level II QC Summary
Q24040169 HG 7470 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Mercury (Hg)
-0.006
-0.006
Blank # 2
Parameter
Measured
Final
Mercury (Hg)
-0.004
-0.004
LCS # 1
MS # 1
MSD # 1
MS # 2
MSD # 2
Parameter Measured Final
Mercury (Hg) 1.98 1.98
Parameter Measured Final
Mercury (Hg) 0.985 0.985
Parameter Measured Final
Mercury (Hg) 1 1
Parameter Measured Final
Mercury (Hg) 1 1
Parameter Measured Final
Mercury (Hg) 1.01 1.01
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
ug/L
1
0.01
0.05
< MDL
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
ug/L
1
0.01
0.05
< MDL
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
ug/L
1
0.01
2
98.8
85 115
Parent Sample:
J24030519 -- 2024007451
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
ug/L
1
0.01
1
98.5
75 125
Parent Sample:
J24030519 -- 2024007451
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
ug/L
1
0.01
1
100
75 125 1.91
Parent Sample:
J24030520 -- 2024007461
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
ug/L
1
0.01
1
100
75 125
Parent Sample:
J24030520 -- 2024007461
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
ug/L
1
0.01
1
101
75 125 0.797

Certificate of Laboratory Analysis Page 25 of 31
This report shall not be reproduced, except in full.
Order # J24030519
Level II QC Summary
Q24040064 ICP_TRM TOTAL RECOVERABLE METALS BY iCP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration Qualifier
Aluminum (AI)
0.00704
0.00704
mg/L
1
0.003
0.01
> MDL B2
Barium (Ba)
0.000176
0.000176
mg/L
1
0.002
0.005
< MDL
Boron (B)
0.00515
0.00515
mg/L
1
0.005
0.05
> MDL
Calcium (Ca)
0.00835
0.00835
mg/L
1
0.012
0.05
< MDL
Copper (Cu)
0.000453
0.000453
mg/L
1
0.001
0.005
< MDL
Iron (Fe)
0.00321
0.00321
mg/L
1
0.004
0.01
< MDL
Magnesium (Mg)
0.0099
0.0099
mg/L
1
0.008
0.02
> MDL
Manganese (Mn)
0.000346
0.000346
mg/L
1
0.001
0.005
< MDL
Potassium (K)
-0.0148
-0.0148
mg/L
1
0.031
0.1
< MDL
Sodium (Na)
-0.000749
-0.000749
mg/L
1
0.017
0.05
< MDL
Strontium (Sr)
0.000173
0.000173
mg/L
1
0.001
0.005
< MDL
Zinc (Zn)
0.000838
0.000838
mg/L
1
0.004
0.015
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL Qualifier
Aluminum (AI)
5.14
5.14
mg/L
1
0.003
5
103
80
120
Barium (Ba)
5.1
5.1
mg/L
1
0.002
5
102
80
120
Boron (B)
5
5
mg/L
1
0.005
5
100
80
120
Calcium (Ca)
5.13
5.13
mg/L
1
0.012
5
103
80
120
Copper (Cu)
5.08
5.08
mg/L
1
0.001
5
102
80
120
Iron (Fe)
5.14
5.14
mg/L
1
0.004
5
103
80
120
Magnesium (Mg)
5.14
5.14
mg/L
1
0.008
5
103
80
120
Manganese (Mn)
5.09
5.09
mg/L
1
0.001
5
102
80
120
Potassium (K)
5.14
5.14
mg/L
1
0.031
5
103
80
120
Sodium (Na)
5.13
5.13
mg/L
1
0.017
5
103
80
120
Strontium (Sr)
5.05
5.05
mg/L
1
0.001
5
101
80
120
Zinc (Zn)
5.09
5.09
mg/L
1
0.004
5
102
80
120
MS # 1
Parent Sample:
J24030517
-- 2024007428
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL Qualifier
Aluminum (AI)
6.04
6.04
mg/L
1
0.003
5
113
75
125
Barium (Ba)
5.18
5.18
mg/L
1
0.002
5
103
75
125
Boron (B)
5.06
5.06
mg/L
1
0.005
5
101
75
125
Calcium (Ca)
10.1
10.1
mg/L
1
0.012
5
104
75
125
Copper (Cu)
5.1
5.1
mg/L
1
0.001
5
102
75
125
Iron (Fe)
5.48
5.48
mg/L
1
0.004
5
105
75
125
Magnesium (Mg)
8.07
8.07
mg/L
1
0.008
5
104
75
125
Manganese (Mn)
5.15
5.15
mg/L
1
0.001
5
103
75
125
Potassium (K)
6.21
6.21
mg/L
1
0.031
5
104
75
125
Sodium (Na)
8.4
8.4
mg/L
1
0.017
5
104
75
125

Certificate of Laboratory Analysis Page 26 of 31
This report shall not be reproduced, except in full.
Order # J24030519
Level II QC Summary
Q24040064 ICP_TRM TOTAL RECOVERABLE METALS BY 1CP
MS # 1
Parameter
Measured
Final
Strontium (Sr)
5.13
5.13
Zinc (Zn)
5.12
5.12
MSD # 1
Parameter
Measured
Final
Aluminum (AI)
5.95
5.95
Barium (Ba)
5.21
5.21
Boron (B)
5.07
5.07
Calcium (Ca)
10.1
10.1
Copper (Cu)
5.13
5.13
Iron (Fe)
5.51
5.51
Magnesium (Mg)
8.06
8.06
Manganese (Mn)
5.18
5.18
Potassium (K)
6.25
6.25
Sodium (Na)
8.41
8.41
Strontium (Sr)
5.2
5.2
Zinc (Zn)
5.15
5.15
Parent Sample:
J24030517 -- 2024007428
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
mg/L
1
0.001
5
101
75
125
mg/L
1
0.004
5
102
75
125
Parent Sample:
J24030517
-- 2024007428
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
mg/L
1
0.003
5
111
75
125
1.5
mg/L
1
0.002
5
104
75
125
0.577
mg/L
1
0.005
5
101
75
125
0.197
mg/L
1
0.012
5
104
75
125
0
mg/L
1
0.001
5
103
75
125
0.587
mg/L
1
0.004
5
105
75
125
0.546
mg/L
1
0.008
5
104
75
125
0.124
mg/L
1
0.001
5
103
75
125
0.581
mg/L
1
0.031
5
105
75
125
0.642
mg/L
1
0.017
5
104
75
125
0.119
mg/L
1
0.001
5
103
75
125
1.36
mg/L
1
0.004
5
103
75
125
0.584
Qualifiers:
B2 Target analyte was detected in Method/Prep Blank(s) at a concentration greater than '/2 the reporting limit but
less than the reporting limit. Analyte concentration in sample is valid and may be used for compliance
purposes.
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030519
Level II QC Summary
Q24040070 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Page 27 of 31
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
0.003
0.003
ug/L
1
0.104
1
< MDL
Arsenic (As)
0.004
0.004
ug/L
1
0.111
1
< MDL
Beryllium (Be)
0.015
0.015
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0.006
0.006
ug/L
1
0.032
1
< MDL
Chromium (Cr)
0.047
0.047
ug/L
1
0.185
1
< MDL
Cobalt (Co)
-0.003
-0.003
ug/L
1
0.077
1
< MDL
Lead (Pb)
0.009
0.009
ug/L
1
0.037
1
< MDL
Molybdenum (Mo)
0.008
0.008
ug/L
1
0.18
1
< MDL
Nickel (Ni)
0.022
0.022
ug/L
1
0.256
1
< MDL
Selenium (Se)
0.178
0.178
ug/L
1
0.193
1
< MDL
Thallium (TI) Low Level
-0.008
-0.008
ug/L
1
0.041
0.2
< MDL
Vanadium (V) Low Level
0.041
0.041
ug/L
1
0.114
0.3
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
48.6
48.6
ug/L
1
0.104
50
97.2
80
120
Arsenic (As)
49.1
49.1
ug/L
1
0.111
50
98.2
80
120
Beryllium (Be)
47.9
47.9
ug/L
1
0.249
50
95.8
80
120
Cadmium (Cd)
48.8
48.8
ug/L
1
0.032
50
97.6
80
120
Chromium (Cr)
48.3
48.3
ug/L
1
0.185
50
96.7
80
120
Cobalt (Co)
49.1
49.1
ug/L
1
0.077
50
98.1
80
120
Lead (Pb)
49
49
ug/L
1
0.037
50
98
80
120
Molybdenum (Mo)
49.1
49.1
ug/L
1
0.18
50
98.3
80
120
Nickel (Ni)
48.7
48.7
ug/L
1
0.256
50
97.5
80
120
Selenium (Se)
48.2
48.2
ug/L
1
0.193
50
96.4
80
120
Thallium (TI) Low Level
48.6
48.6
ug/L
1
0.041
50
97.3
80
120
Vanadium (V) Low Level
48.4
48.4
ug/L
1
0.114
50
96.8
80
120
MS # 1
Parent Sample:
J24030517 -- 2024007430
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
48.9
48.9
ug/L
1
0.104
50
97.7
75
125
Arsenic (As)
49.3
49.3
ug/L
1
0.111
50
98
75
125
Beryllium (Be)
47.8
47.8
ug/L
1
0.249
50
95.5
75
125
Cadmium (Cd)
49.3
49.3
ug/L
1
0.032
50
97
75
125
Chromium (Cr)
49.1
49.1
ug/L
1
0.185
50
97.6
75
125
Cobalt (Co)
62.6
62.6
ug/L
1
0.077
50
97.2
75
125
Lead (Pb)
49.6
49.6
ug/L
1
0.037
50
98.9
75
125
Molybdenum (Mo)
49.6
49.6
ug/L
1
0.18
50
99.1
75
125
Nickel (Ni)
49.7
49.7
ug/L
1
0.256
50
97.4
75
125
Selenium (Se)
48.2
48.2
ug/L
1
0.193
50
96.1
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 28 of 31
This report shall not be reproduced, except in full.
Order # J24030519
Level II QC Summary
Q24040070 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 1
Parameter
Measured
Final
Units
Thallium (TI) Low Level
49.2
49.2
ug/L
Vanadium (V) Low Level
48.8
48.8
ug/L
MSD # 1
Parameter
Measured
Final
Units
Antimony (Sb)
48.9
48.9
ug/L
Arsenic (As)
48.9
48.9
ug/L
Beryllium (Be)
50.2
50.2
ug/L
Cadmium (Cd)
49.4
49.4
ug/L
Chromium (Cr)
49.2
49.2
ug/L
Cobalt (Co)
62
62
ug/L
Lead (Pb)
49.2
49.2
ug/L
Molybdenum (Mo)
49.4
49.4
ug/L
Nickel (Ni)
49.8
49.8
ug/L
Selenium (Se)
46.7
46.7
ug/L
Thallium (TI) Low Level
49.2
49.2
ug/L
Vanadium (V) Low Level
48.9
48.9
ug/L
Parent Sample:
J24030517 -- 2024007430
Dil
MDL
Spike
% Recovery
LCL
UCL
1
0.041
50
98.2
75
125
1
0.114
50
97
75
125
Parent Sample:
J24030517
-- 2024007430
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
1
0.104
50
97.7
75
125
0.0225
1
0.111
50
97.2
75
125
0.838
1
0.249
50
100
75
125
4.85
1
0.032
50
97.1
75
125
0.136
1
0.185
50
98
75
125
0.354
1
0.077
50
96
75
125
1.19
1
0.037
50
98.1
75
125
0.829
1
0.18
50
98.7
75
125
0.38
1
0.256
50
97.7
75
125
0.246
1
0.193
50
93
75
125
3.24
1
0.041
50
98.1
75
125
0.0571
1
0.114
50
97.3
75
125
0.296
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 29 of 31
This report shall not be reproduced, except in full.
Order # J24030519
Level II QC Summary
Q24040060 TDS TOTAL DISSOLVED SOLIDS
Blank # 1
Blank # 2
Parameter Measured Final
TDS -0.5
Parameter Measured Final
TDS -0.3
Duplicate # 1
Parameter Measured Final
TDS 187
Duplicate # 2
Parameter Measured Final
TDS 18
LCS # 1
LCS # 2
Parameter Measured Final
TDS 493
Parameter Measured Final
TDS 488
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
25
25
< MDL
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
25
25
< MDL
Parent Sample:
J24030005 -- 2024004977
Units
Dil
MDL
RPD
Qualifier
mg/L
1
25
1.06
Parent Sample:
J24030520 -- 2024007461
Units
Dil
MDL
RPD
Qualifier
mg/L
1
25
0
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
25
500
98.6
90
110
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
25
500
97.6
90
110

Certificate of Laboratory Analysis Page 30 of 31
This report shall not be reproduced, except in full.
Order # J24030519
Level II QC Summary
Q24040056 TSS TOTAL SUSPENDED SOLIDS
Blank # 1
Parameter Measured Final
TSS 0
Blank # 2
Parameter Measured Final
TSS -0.1
Duplicate # 1
Parameter Measured Final
TSS 56.8
Duplicate # 2
Parameter Measured Final
TSS 11.2
LCS # 1
LCS # 2
Parameter Measured Final
TSS 94.8
Parameter Measured Final
TSS 96
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
5
5
< MDL
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
5
5
< MDL
Parent Sample:
J24030519 -- 2024007451
Units
Dil
MDL
RPD
Qualifier
mg/L
1
5
14.3
R1
Parent Sample:
J24040156 -- 2024008360
Units
Dil
MDL
RPD
Qualifier
mg/L
1
5
1.77
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
5
100
94.8
90
110
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
5
100
96
90
110
Qualifiers:
R1 Relative Percent Difference exceeded method acceptance limits.

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
Duke Energy Analytical Laboratory - �---_---_'--------------- — Analytical LaboratoryUse Only---------------------------------------3 Nage 31 oT 31
i
DUKE Mail Cod, MGd3A2 (Building740P i Order it r /1�/Jy 7� / Q Matrix WATER ,,, pl,,Orb3�r<�ngrr,m NC x Pa9e_1_of_1_
ENERGY 13339HagereFerryRtl i I ] V �]p so_ DISTRIBUTION
4n Ramer:�m�, x. c. 2eoie i i�g� ey to li e ! ORIGINAL to LA8, COPY to GLIENT
I7MI a73.& SAMPLE PROGRAM
_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Fa-:.L 41a7ssaga._,_ _ _,_, j i gl Ground Water X NPDES _ i
Proect Name 'Phone No: !Vendor / Dfnking Water UST_
j ASHEVILLE AIRPORT FILL AREA III E (- RCRA Waste
' .._.._.._.._ ._.._. cooler T:JOp_[�2.._.._ ._.._.._.._.._.._.._.._.._._.._.._.._.._..—._.._.._.._.._.._.._.._.._..
Client JOHN TOEPFER, BRYAN MOELLER, ::Polls
DEE O'BRTEN, JOSH STOWE, CONNOR ZAHORA i Filtration (0.45 um) n Unfiltered 4 Filtered
Operating Unit: AE00 Process: BENVWS Account:
i i Preservative ICE ICE
Project: Activity 1D: Facility ID: ASA Container Volume l 300 Soo 2000
Program l EQulS Task Code: Suh-ProgramRask Code:
COMPL€ANCEISTRPL Container Type PET HOPE PET
z ICP TRN (80100): Al.
a Ba. 9, Ca, Cull, Fe, Mg,
Customer io complete all apprapriaie "on -shaded areas. c m N Mn,K, Na, Sr, Zn
to _.._.._.._.._.._ Sam le Description or ID U IMS TRM {80206): Sb. m
_ P P Aa, Be, Cd, Cr, Co, Fb.
I i Coltection Information 4
SAMPLE ID O 0 Ma, Ni, 5e T!(LL). V{LL{ t=
NUMBER ! e R Hg 7470A N
Date Time Printed Name signature U 0 4 4 f
@
w
c
U
o
�
-' '
�':
ASA MW-1-A3
ASA_MW-2-A3
la 55
illrvwcal9uni
x
t
t
1
3
1t35
x
1
t
1
3
ASA MW-3-A3
FIRLCI( 5eA101V
x
1
1
1
3
ASA MW-4-A3
[2KD
MacK MOM%l7ou
x
t
t
1
3
ASA_MW-5-A3
le tS
t tfll+� SEA Ionr
x
t
1
1
3
j 7
ASA _MW-6-A3
010°
x
t
t
3
ASA_MW-7-A3
OgKO
CiDlui R 7At-lV A
x
1
1
1
3
i
0
0
• �!
ASA FD-2nz4DKoQ- 2
�FB
MACt< A'IoP.tt"t51IJ
x
1
1
1
3
r7 is
ASA - 2aZ404102- land
re„o
cu vwo e zkuw,4-
x
t
1
2
0
0
i
Q
i
Q
i
0
i i
g
0
TOTAL 9 CONTAINERS
0
0
9
9
0
8
0
6
0
0
0
0
Q
26
Relinquished By
DatelTime
Accepted By:
DatelTime
a
5
°' a
A �
a o
Requested Turnaround
21 Days
Relinquished By DatelTime
27-
, .Ji
Accepted By:� � �afT�� /
M
Relinquished By DatelTime I
Accepted By: DatelTime
y
14 Days
c a
o a
Seatll-ocketl By DatelTime
Sealedfl-ock Opened By DatelTime
.y
_ m
�a
a
E
`7 Days
Comments
NOTE: NCDEQ EDD and EQUIS REQUIRED
�
'Other
*Add Cast Will Apply
U
Total E

DUKE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J24030517
Project Name: ASHEVILLE AIRPORT - AIRPORT FILL AREA I - (IN-HOUSE)
Task Code: STRFL
Customer Name(s): John Toepfer, B Moeller, Josh Stowe, C Zahora
Customer Address: Asheville Airport
Lab Contact: Peggy Kendall Phone: [phone]
Report Authorized By: l� pate: 4/17/2024
(Signature) F{
Kendall
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
Page 1 of 33
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
Collected By Sample Description
Page 2 of 33
2024007428
Asheville Airport
01-Apr-24
1:10 PM
Mack Morrison
ASA_MW-1A-A1
2024007430
Asheville Airport
01-Apr-24
2:14 PM
Haley Seaton
ASA_MW-4A-A1
2024007431
Asheville Airport
01-Apr-24
2:50 PM
Connor Zahora
ASA_MW-5-A1
2024007432
Asheville Airport
01-Apr-24
2:05 PM
Mack Morrison
ASA_MW-6-A1
2024007433
Asheville Airport
01-Apr-24
2:25 PM
Connor Zahora
ASA_MW-7-A1
2024007434
Asheville Airport
01-Apr-24
1:50 PM
Connor Zahora
ASA_MW-8-A1
2024007435
Asheville Airport
01-Apr-24
1:20 PM
Connor Zahora
ASA_MW-9-A1
2024007436
Asheville Airport
01-Apr-24
Mack Morrison
ASA_FD-20240401-1
2024007437
Asheville Airport
01-Apr-24
3:00 PM
Mack Morrison
ASA_Fl3 -20240401-1500
2024008254
Asheville Airport
01-Apr-24
2:45 PM
Mack Morrison
ASA_MW-213-A1
10 Total Samples

Page 3 of 33
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals❑ Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
❑d Job Summary Report
❑d Sample Identification
❑� Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
❑� Analytical Laboratory QC Report
❑ Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑� Chain of Custody
❑� Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 4/17/2024

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030517
Site: ASA MW-1A-A1
Collection Date: 04/01/2024 01:10 PM Loc code: ASA MW-1A-A1
Sample #: 2024007428
Matrix: GW RCRA
Page 4 of 33
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q24040131
Alkalinity, Bicarbonate
17.9
mg/L
5
1.7
1
SM 2320134d
04/08/2024 11:50
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/08/2024 11:50
SNEGLIA
Total Alkalinity as CaCO3
17.9
mg/L
5
1.7
1
SM 2320134d
04/08/2024 11:50
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24040046
Chloride
4.7
mg/L
0.1
0.0154
1
EPA 9056A
04/03/2024 21:08
BGN9034
Sulfate
1.0
mg/L
0.1
0.0428
1
EPA 9056A
04/03/2024 21:08
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040058
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/04/2024 10:06
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24040064
Aluminum (AI)
0.393
mg/L B2
0.01
0.003
1
SW 6010D
04/08/2024 10:32
CELLI06
Barium (Ba)
0.030
mg/L
0.005
0.002
1
SW 601OD
04/08/2024 10:32
CELLI06
Boron (B)
0.028 J
mg/L
0.05
0.005
1
SW 6010D
04/08/2024 10:32
CELLI06
Calcium (Ca)
4.92
mg/L
0.05
0.012
1
SW 601OD
04/08/2024 10:32
CELLI06
Copper (Cu)
0.003 J
mg/L
0.005
0.001
1
SW 6010D
04/08/2024 10:32
CELLI06
Iron (Fe)
0.252
mg/L
0.01
0.004
1
SW 601OD
04/08/2024 10:32
CELL106
Magnesium (Mg)
2.85
mg/L
0.02
0.008
1
SW 6010D
04/08/2024 10:32
CELLI06
Manganese (Mn)
0.012
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 10:32
CELLI06
Potassium (K)
1.00
mg/L
0.1
0.031
1
SW 6010D
04/08/2024 10:32
CELLI06
Sodium (Na)
3.21
mg/L
0.05
0.017
1
SW 601OD
04/08/2024 10:32
CELLI06
Strontium (Sr)
0.057
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 10:32
CELLI06
Zinc (Zn)
0.022
mg/L
0.015
0.004
1
SW 6010D
04/08/2024 10:32
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040070
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
04/08/2024 12:50
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
04/08/2024 12:50
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
04/08/2024 12:50
MHALL3
Cadmium (Cd)
0.037 J
ug/L
1
0.032
1
SW 6020E
04/08/2024 12:50
MHALL3
Chromium (Cr)
1.60
ug/L
1
0.185
1
SW 6020B
04/08/2024 12:50
MHALL3
Cobalt (Co)
0.151 J
ug/L
1
0.077
1
SW 6020E
04/08/2024 12:50
MHALL3
Lead (Pb)
0.243 J
ug/L
1
0.037
1
SW 6020B
04/08/2024 12:50
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020E
04/08/2024 12:50
MHALL3
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
SW 6020E
04/08/2024 12:50
MHALL3
Selenium (Se)
1.23
ug/L
1
0.193
1
SW 6020B
04/08/2024 12:50
MHALL3
Thallium (TI) Low Level
0.041 J
ug/L
0.2
0.041
1
SW 6020B
04/08/2024 12:50
MHALL3
Vanadium (V) Low Level
0.299 J
ug/L
0.3
0.114
1
SW 6020E
04/08/2024 12:50
MHALL3
TOTAL DISSOLVED SOLIDS - Q24040038
TDS
43.0
mg/L
25
25
1
SM2540C
04/02/202413:16
SNEGLIA

Certificate of Laboratory Analysis Page 5 of 33
This report shall not be reproduced, except in full.
Order # J24030517
Site: ASA MW-1A-A1 Sample #: 2024007428
Collection Date: 04/01/2024 01:10 PM Loc code: ASA MW-1A-A1 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
TOTAL SUSPENDED SOLIDS - Q24040028
TSS 7 mg/L 5 5 1 SM2540D 04/02/202410:28 HHOOGKA

Certificate of Laboratory Analysis Page 6 of 33
This report shall not be reproduced, except in full.
Order # J24030517
Site: ASA MW-4A-A1
Sample #: 2024007430
Collection Date: 04/01/2024 02:14 PM
Loc code: ASA MW-4A-A1
Matrix: GW
RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL ALKALINITY - Q24040074
Total Alkalinity as CaCO3
32.4
mg/L
5
1.7
1
SM 2320B-2011
04/04/2024 06:50
SNEGLIA
(CaCO3)
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320B-2011
04/04/2024 06:50
SNEGLIA
Alkalinity, Bicarbonate
32.4
mg/L
5
1.7
1
SM 2320B-2011
04/04/2024 06:50
SNEGLIA
INORGANIC IONS BY IC - Q24040046
Chloride
1.3
mg/L
0.5
0.0154
5
EPA 9056A
04/03/2024 18:13
BGN9034
Sulfate
1.3
mg/L
0.1
0.0428
1
EPA 9056A
04/03/2024 18:13
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040058
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/04/2024 10:12
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24040064
Aluminum (AI)
0.132
mg/L
B2 0.01
0.003
1
SW 6010D
04/08/2024 10:44
CELLI06
Barium (Ba)
0.015
mg/L
0.005
0.002
1
SW 601OD
04/08/2024 10:44
CELLI06
Boron (B)
0.012 J
mg/L
0.05
0.005
1
SW 6010D
04/08/2024 10:44
CELLI06
Calcium (Ca)
6.01
mg/L
0.05
0.012
1
SW 601OD
04/08/2024 10:44
CELLI06
Copper (Cu)
0.004 J
mg/L
0.005
0.001
1
SW 6010D
04/08/2024 10:44
CELLI06
Iron (Fe)
0.821
mg/L
0.01
0.004
1
SW 601OD
04/08/2024 10:44
CELL106
Magnesium (Mg)
1.12
mg/L
0.02
0.008
1
SW 6010D
04/08/2024 10:44
CELLI06
Manganese (Mn)
0.461
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 10:44
CELLI06
Potassium (K)
1.97
mg/L
0.1
0.031
1
SW 6010D
04/08/2024 10:44
CELLI06
Sodium (Na)
6.50
mg/L
0.05
0.017
1
SW 601OD
04/08/2024 10:44
CELLI06
Strontium (Sr)
0.013
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 10:44
CELLI06
Zinc (Zn)
0.374
mg/L
0.015
0.004
1
SW 6010D
04/08/2024 10:44
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040070
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
04/08/2024 12:07
MHALL3
Arsenic (As)
0.292 J
ug/L
1
0.111
1
SW 6020B
04/08/2024 12:07
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
04/08/2024 12:07
MHALL3
Cadmium (Cd)
0.859 J
ug/L
1
0.032
1
SW 6020E
04/08/2024 12:07
MHALL3
Chromium (Cr)
0.25 J
ug/L
1
0.185
1
SW 6020B
04/08/2024 12:07
MHALL3
Cobalt (Co)
14.0
ug/L
1
0.077
1
SW 6020E
04/08/2024 12:07
MHALL3
Lead (Pb)
0.176 J
ug/L
1
0.037
1
SW 6020B
04/08/2024 12:07
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020E
04/08/2024 12:07
MHALL3
Nickel (Ni)
0.966 J
ug/L
1
0.256
1
SW 6020E
04/08/2024 12:07
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
04/08/2024 12:07
MHALL3
Thallium (TI) Low Level
0.107 J
ug/L
0.2
0.041
1
SW 6020B
04/08/2024 12:07
MHALL3
Vanadium (V) Low Level
0.27 J
ug/L
0.3
0.114
1
SW 6020E
04/08/2024 12:07
MHALL3
TOTAL DISSOLVED SOLIDS - Q24040038
TDS
46.0
mg/L
25
25
1
SM2540C
04/02/202413:16
SNEGLIA

Certificate of Laboratory Analysis Page 7 of 33
This report shall not be reproduced, except in full.
Order # J24030517
Site: ASA MW-4A-A1 Sample #: 2024007430
Collection Date: 04/01/2024 02:14 PM Loc code: ASA MW-4A-A1 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
TOTAL SUSPENDED SOLIDS - Q24040028
TSS 5 U mg/L 5 5 1 SM2540D 04/02/2024 10:28 HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030517
Site: ASA MW-5-A1
Collection Date: 04/01/2024 02:50 PM Loc code: ASA MW-5-A1
Sample #: 2024007431
Matrix: GW RCRA
Page 8 of 33
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q24040131
Alkalinity, Bicarbonate
3.5 J
mg/L
5
1.7
1
SM 2320134d
04/08/2024 11:58
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/08/2024 11:58
SNEGLIA
Total Alkalinity as CaCO3
3.5 J
mg/L
5
1.7
1
SM 2320134d
04/08/2024 11:58
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24040046
Chloride
3.1
mg/L
0.1
0.0154
1
EPA 9056A
04/03/2024 18:33
BGN9034
Sulfate
0.05 J
mg/L
0.1
0.0428
1
EPA 9056A
04/03/2024 18:33
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040058
Mercury (Hg)
0.09
ug/L
0.05
0.01
1
EPA 7470A
04/04/2024 10:14
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24040064
Aluminum (AI)
0.037
mg/L B2
0.01
0.003
1
SW 6010D
04/08/2024 10:48
CELLI06
Barium (Ba)
0.024
mg/L
0.005
0.002
1
SW 601OD
04/08/2024 10:48
CELLI06
Boron (B)
0.006 J
mg/L
0.05
0.005
1
SW 6010D
04/08/2024 10:48
CELLI06
Calcium (Ca)
0.334
mg/L
0.05
0.012
1
SW 601OD
04/08/2024 10:48
CELLI06
Copper (Cu)
0.002 J
mg/L
0.005
0.001
1
SW 6010D
04/08/2024 10:48
CELLI06
Iron (Fe)
0.016
mg/L
0.01
0.004
1
SW 601OD
04/08/2024 10:48
CELL106
Magnesium (Mg)
0.699
mg/L
0.02
0.008
1
SW 6010D
04/08/2024 10:48
CELLI06
Manganese (Mn)
0.051
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 10:48
CELLI06
Potassium (K)
0.620
mg/L
0.1
0.031
1
SW 6010D
04/08/2024 10:48
CELLI06
Sodium (Na)
3.70
mg/L
0.05
0.017
1
SW 601OD
04/08/2024 10:48
CELLI06
Strontium (Sr)
0.005 J
mg/L
0.005
0.001
1
SW 601 OD
04/08/2024 10:48
CELLI06
Zinc (Zn)
0.01 J
mg/L
0.015
0.004
1
SW 6010D
04/08/2024 10:48
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040070
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
04/08/2024 12:58
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
04/08/2024 12:58
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
04/08/2024 12:58
MHALL3
Cadmium (Cd)
0.036 J
ug/L
1
0.032
1
SW 6020E
04/08/2024 12:58
MHALL3
Chromium (Cr)
0.263 J
ug/L
1
0.185
1
SW 6020B
04/08/2024 12:58
MHALL3
Cobalt (Co)
0.722 J
ug/L
1
0.077
1
SW 6020E
04/08/2024 12:58
MHALL3
Lead (Pb)
0.1 J
ug/L
1
0.037
1
SW 6020B
04/08/2024 12:58
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020E
04/08/2024 12:58
MHALL3
Nickel (Ni)
0.72 J
ug/L
1
0.256
1
SW 6020E
04/08/2024 12:58
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
04/08/2024 12:58
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
04/08/2024 12:58
MHALL3
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
SW 6020E
04/08/2024 12:58
MHALL3
TOTAL DISSOLVED SOLIDS - Q24040038
TDS
25 U
mg/L
25
25
1
SM2540C
04/02/2024 13:16
SNEGLIA

Certificate of Laboratory Analysis Page 9 of 33
This report shall not be reproduced, except in full.
Order # J24030517
Site: ASA MW-5-A1 Sample #: 2024007431
Collection Date: 04/01/2024 02:50 PM Loc code: ASA MW-5-A1 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
TOTAL SUSPENDED SOLIDS - Q24040028
TSS 5 U mg/L 5 5 1 SM2540D 04/02/2024 10:28 HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030517
Site: ASA MW-6-A1
Collection Date: 04/01/2024 02:05 PM Loc code: ASA MW-6-A1
Sample #: 2024007432
Matrix: GW RCRA
Page 10 of 33
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q24040131
Alkalinity, Bicarbonate
6.83
mg/L
5
1.7
1
SM 2320134d
04/08/2024 12:04
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/08/2024 12:04
SNEGLIA
Total Alkalinity as CaCO3
6.83
mg/L
5
1.7
1
SM 2320134d
04/08/2024 12:04
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24040046
Chloride
26
mg/L
0.5
0.0154
5
EPA 9056A
04/03/2024 21:28
BGN9034
Sulfate
0.18
mg/L
0.1
0.0428
1
EPA 9056A
04/03/2024 21:28
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040058
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/04/2024 10:17
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24040064
Aluminum (AI)
0.075
mg/L B2
0.01
0.003
1
SW 6010D
04/08/2024 10:52
CELLI06
Barium (Ba)
0.068
mg/L
0.005
0.002
1
SW 601OD
04/08/2024 10:52
CELLI06
Boron (B)
0.005 U
mg/L
0.05
0.005
1
SW 6010D
04/08/2024 10:52
CELLI06
Calcium (Ca)
6.40
mg/L
0.05
0.012
1
SW 601OD
04/08/2024 10:52
CELLI06
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
04/08/2024 10:52
CELLI06
Iron (Fe)
1.53
mg/L
0.01
0.004
1
SW 601OD
04/08/2024 10:52
CELL106
Magnesium (Mg)
3.24
mg/L
0.02
0.008
1
SW 6010D
04/08/2024 10:52
CELLI06
Manganese (Mn)
0.027
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 10:52
CELLI06
Potassium (K)
1.17
mg/L
0.1
0.031
1
SW 6010D
04/08/2024 10:52
CELLI06
Sodium (Na)
6.43
mg/L
0.05
0.017
1
SW 601OD
04/08/2024 10:52
CELLI06
Strontium (Sr)
0.088
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 10:52
CELLI06
Zinc (Zn)
0.012 J
mg/L
0.015
0.004
1
SW 6010D
04/08/2024 10:52
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040070
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
04/08/2024 13:07
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
04/08/2024 13:07
MHALL3
Beryllium (Be)
0.552 J
ug/L
1
0.249
1
SW 6020B
04/08/2024 13:07
MHALL3
Cadmium (Cd)
0.034 J
ug/L
1
0.032
1
SW 6020E
04/08/2024 13:07
MHALL3
Chromium (Cr)
0.255 J
ug/L
1
0.185
1
SW 6020B
04/08/2024 13:07
MHALL3
Cobalt (Co)
1.03
ug/L
1
0.077
1
SW 6020E
04/08/2024 13:07
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
04/08/2024 13:07
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020E
04/08/2024 13:07
MHALL3
Nickel (Ni)
1.95
ug/L
1
0.256
1
SW 6020E
04/08/2024 13:07
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
04/08/2024 13:07
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
04/08/2024 13:07
MHALL3
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
SW 6020E
04/08/2024 13:07
MHALL3
TOTAL DISSOLVED SOLIDS - Q24040038
TDS
80.0
mg/L
25
25
1
SM2540C
04/02/202413:16
SNEGLIA

Certificate of Laboratory Analysis Page 11 of33
This report shall not be reproduced, except in full.
Order # J24030517
Site: ASA MW-6-A1 Sample #: 2024007432
Collection Date: 04/01/2024 02:05 PM Loc code: ASA MW-6-A1 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
TOTAL SUSPENDED SOLIDS - Q24040028
TSS 5 U mg/L 5 5 1 SM2540D 04/02/2024 10:28 HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030517
Site: ASA MW-7-A1
Collection Date: 04/01/2024 02:25 PM Loc code: ASA MW-7-A1
Sample #: 2024007433
Matrix: GW RCRA
Page 12 of 33
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q24040131
Alkalinity, Bicarbonate
5.39
mg/L
5
1.7
1
SM 2320134d
04/08/2024 12:11
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/08/2024 12:11
SNEGLIA
Total Alkalinity as CaCO3
5.39
mg/L
5
1.7
1
SM 2320134d
04/08/2024 12:11
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24040046
Chloride
8.5
mg/L
0.2
0.0154
2
EPA 9056A
04/03/2024 19:12
BGN9034
Sulfate
0.0428 U
mg/L
0.2
0.0428
2
EPA 9056A
04/03/2024 19:12
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040058
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/04/2024 10:19
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24040064
Aluminum (AI)
0.052
mg/L B2
0.01
0.003
1
SW 6010D
04/08/2024 10:55
CELLI06
Barium (Ba)
0.024
mg/L
0.005
0.002
1
SW 601OD
04/08/2024 10:55
CELLI06
Boron (B)
0.005 U
mg/L
0.05
0.005
1
SW 6010D
04/08/2024 10:55
CELLI06
Calcium (Ca)
1.07
mg/L
0.05
0.012
1
SW 601OD
04/08/2024 10:55
CELLI06
Copper (Cu)
0.001 J
mg/L
0.005
0.001
1
SW 6010D
04/08/2024 10:55
CELLI06
Iron (Fe)
0.045
mg/L
0.01
0.004
1
SW 601OD
04/08/2024 10:55
CELL106
Magnesium (Mg)
1.03
mg/L
0.02
0.008
1
SW 6010D
04/08/2024 10:55
CELLI06
Manganese (Mn)
0.018
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 10:55
CELLI06
Potassium (K)
0.624
mg/L
0.1
0.031
1
SW 6010D
04/08/2024 10:55
CELLI06
Sodium (Na)
5.76
mg/L
0.05
0.017
1
SW 601OD
04/08/2024 10:55
CELLI06
Strontium (Sr)
0.017
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 10:55
CELLI06
Zinc (Zn)
0.004 U
mg/L
0.015
0.004
1
SW 6010D
04/08/2024 10:55
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040070
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
04/08/2024 13:15
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
04/08/2024 13:15
MHALL3
Beryllium (Be)
0.291 J
ug/L
1
0.249
1
SW 6020B
04/08/2024 13:15
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020E
04/08/2024 13:15
MHALL3
Chromium (Cr)
0.48 J
ug/L
1
0.185
1
SW 6020B
04/08/2024 13:15
MHALL3
Cobalt (Co)
0.164 J
ug/L
1
0.077
1
SW 6020E
04/08/2024 13:15
MHALL3
Lead (Pb)
0.064 J
ug/L
1
0.037
1
SW 6020B
04/08/2024 13:15
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020E
04/08/2024 13:15
MHALL3
Nickel (Ni)
0.754 J
ug/L
1
0.256
1
SW 6020E
04/08/2024 13:15
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
04/08/2024 13:15
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
04/08/2024 13:15
MHALL3
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
SW 6020E
04/08/2024 13:15
MHALL3
TOTAL DISSOLVED SOLIDS - Q24040038
TDS
30.0
mg/L
25
25
1
SM2540C
04/02/202413:16
SNEGLIA

Certificate of Laboratory Analysis Page 13 of 33
This report shall not be reproduced, except in full.
Order # J24030517
Site: ASA MW-7-A1 Sample #: 2024007433
Collection Date: 04/01/2024 02:25 PM Loc code: ASA MW-7-A1 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
TOTAL SUSPENDED SOLIDS - Q24040028
TSS 5 U mg/L 5 5 1 SM2540D 04/02/2024 10:28 HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030517
Site: ASA MW-8-A1
Collection Date: 04/01/2024 01:50 PM Loc code: ASA MW-8-A1
Sample #: 2024007434
Matrix: GW RCRA
Page 14 of 33
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q24040131
Alkalinity, Bicarbonate
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/08/2024 12:17
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/08/2024 12:17
SNEGLIA
Total Alkalinity as CaCO3
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/08/2024 12:17
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24040046
Chloride
81
mg/L
2
0.0154
20
EPA 9056A
04/03/2024 21:48
BGN9034
Sulfate
0.07 J
mg/L
0.2
0.0428
2
EPA 9056A
04/03/2024 21:48
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040058
Mercury (Hg)
0.34
ug/L
0.05
0.01
1
EPA 7470A
04/04/2024 10:21
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24040064
Aluminum (AI)
0.830
mg/L B2
0.01
0.003
1
SW 6010D
04/08/2024 10:59
CELLI06
Barium (Ba)
0.680
mg/L
0.005
0.002
1
SW 601OD
04/08/2024 10:59
CELLI06
Boron (B)
0.007 J
mg/L
0.05
0.005
1
SW 6010D
04/08/2024 10:59
CELLI06
Calcium (Ca)
2.02
mg/L
0.05
0.012
1
SW 601OD
04/08/2024 10:59
CELLI06
Copper (Cu)
0.005
mg/L
0.005
0.001
1
SW 6010D
04/08/2024 10:59
CELLI06
Iron (Fe)
0.061
mg/L
0.01
0.004
1
SW 601OD
04/08/2024 10:59
CELL106
Magnesium (Mg)
4.01
mg/L
0.02
0.008
1
SW 6010D
04/08/2024 10:59
CELLI06
Manganese (Mn)
1.44
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 10:59
CELLI06
Potassium (K)
3.10
mg/L
0.1
0.031
1
SW 6010D
04/08/2024 10:59
CELLI06
Sodium (Na)
40.7
mg/L
0.05
0.017
1
SW 601OD
04/08/2024 10:59
CELLI06
Strontium (Sr)
0.041
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 10:59
CELLI06
Zinc (Zn)
0.066
mg/L
0.015
0.004
1
SW 6010D
04/08/2024 10:59
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040070
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
04/08/2024 13:23
MHALL3
Arsenic (As)
0.502 J
ug/L
1
0.111
1
SW 6020B
04/08/2024 13:23
MHALL3
Beryllium (Be)
0.676 J
ug/L
1
0.249
1
SW 6020B
04/08/2024 13:23
MHALL3
Cadmium (Cd)
0.231 J
ug/L
1
0.032
1
SW 6020E
04/08/2024 13:23
MHALL3
Chromium (Cr)
0.288 J
ug/L
1
0.185
1
SW 6020B
04/08/2024 13:23
MHALL3
Cobalt (Co)
18.2
ug/L
1
0.077
1
SW 6020E
04/08/2024 13:23
MHALL3
Lead (Pb)
0.161 J
ug/L
1
0.037
1
SW 6020B
04/08/2024 13:23
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020E
04/08/2024 13:23
MHALL3
Nickel (Ni)
8.01
ug/L
1
0.256
1
SW 6020E
04/08/2024 13:23
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
04/08/2024 13:23
MHALL3
Thallium (TI) Low Level
0.141 J
ug/L
0.2
0.041
1
SW 6020B
04/08/2024 13:23
MHALL3
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
SW 6020E
04/08/2024 13:23
MHALL3
TOTAL DISSOLVED SOLIDS - Q24040038
TDS
145
mg/L
25
25
1
SM2540C
04/02/202413:16
SNEGLIA

Certificate of Laboratory Analysis Page 15 of 33
This report shall not be reproduced, except in full.
Order # J24030517
Site: ASA MW-8-A1 Sample #: 2024007434
Collection Date: 04/01/2024 01:50 PM Loc code: ASA MW-8-A1 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
TOTAL SUSPENDED SOLIDS - Q24040028
TSS 5 U mg/L 5 5 1 SM2540D 04/02/2024 10:28 HHOOGKA

Certificate of Laboratory Analysis Page 16 of 33
This report shall not be reproduced, except in full.
Order # J24030517
Site: ASA MW-9-A1
Sample #: 2024007435
Collection Date: 04/01/2024 01:20 PM
Loc code: ASA MW-9-A1
Matrix: GW
RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL ALKALINITY - Q24040074
Total Alkalinity as CaCO3
60.6
mg/L
5
1.7
1
SM 2320B-2011
04/04/2024 07:07
SNEGLIA
(CaCO3)
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320B-2011
04/04/2024 07:07
SNEGLIA
Alkalinity, Bicarbonate
60.6
mg/L
5
1.7
1
SM 2320B-2011
04/04/2024 07:07
SNEGLIA
INORGANIC IONS BY IC - Q24040046
Chloride
10
mg/L
0.5
0.0154
5
EPA 9056A
04/03/2024 19:51
BGN9034
Sulfate
7.9
mg/L
0.5
0.0428
5
EPA 9056A
04/03/2024 19:51
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040058
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/04/2024 10:24
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24040064
Aluminum (AI)
0.173
mg/L
B2 0.01
0.003
1
SW 6010D
04/08/2024 11:03
CELLI06
Barium (Ba)
0.021
mg/L
0.005
0.002
1
SW 601OD
04/08/2024 11:03
CELLI06
Boron (B)
0.005 U
mg/L
0.05
0.005
1
SW 6010D
04/08/2024 11:03
CELLI06
Calcium (Ca)
4.85
mg/L
0.05
0.012
1
SW 601OD
04/08/2024 11:03
CELLI06
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
04/08/2024 11:03
CELLI06
Iron (Fe)
0.163
mg/L
0.01
0.004
1
SW 601OD
04/08/2024 11:03
CELL106
Magnesium (Mg)
1.89
mg/L
0.02
0.008
1
SW 6010D
04/08/2024 11:03
CELLI06
Manganese (Mn)
0.068
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 11:03
CELLI06
Potassium (K)
5.77
mg/L
0.1
0.031
1
SW 6010D
04/08/2024 11:03
CELLI06
Sodium (Na)
22.5
mg/L
0.05
0.017
1
SW 601OD
04/08/2024 11:03
CELLI06
Strontium (Sr)
0.046
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 11:03
CELLI06
Zinc (Zn)
0.004 U
mg/L
0.015
0.004
1
SW 6010D
04/08/2024 11:03
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040070
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
04/08/2024 13:32
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
04/08/2024 13:32
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
04/08/2024 13:32
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020E
04/08/2024 13:32
MHALL3
Chromium (Cr)
0.559 J
ug/L
1
0.185
1
SW 6020B
04/08/2024 13:32
MHALL3
Cobalt (Co)
0.183 J
ug/L
1
0.077
1
SW 6020E
04/08/2024 13:32
MHALL3
Lead (Pb)
0.072 J
ug/L
1
0.037
1
SW 6020B
04/08/2024 13:32
MHALL3
Molybdenum (Mo)
0.424 J
ug/L
1
0.18
1
SW 6020E
04/08/2024 13:32
MHALL3
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
SW 6020E
04/08/2024 13:32
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
04/08/2024 13:32
MHALL3
Thallium (TI) Low Level
0.075 J
ug/L
0.2
0.041
1
SW 6020B
04/08/2024 13:32
MHALL3
Vanadium (V) Low Level
0.322
ug/L
0.3
0.114
1
SW 6020E
04/08/2024 13:32
MHALL3
TOTAL DISSOLVED SOLIDS - Q24040038
TDS
109
mg/L
25
25
1
SM2540C
04/02/202413:16
SNEGLIA

Certificate of Laboratory Analysis Page 17 of 33
This report shall not be reproduced, except in full.
Order # J24030517
Site: ASA MW-9-A1 Sample #: 2024007435
Collection Date: 04/01/2024 01:20 PM Loc code: ASA MW-9-A1 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
TOTAL SUSPENDED SOLIDS - Q24040028
TSS 11 mg/L 5 5 1 SM2540D 04/02/202410:28 HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030517
Site: ASA FD-20240401-1 Duplicate
Collection Date: 04/01/2024 Loc code: ASA FD
Sample #: 2024007436
Matrix: GW RCRA
Page 18 of 33
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q24040131
Alkalinity, Bicarbonate
15.2
mg/L
5
1.7
1
SM 2320134d
04/08/2024 12:23
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/08/2024 12:23
SNEGLIA
Total Alkalinity as CaCO3
15.2
mg/L
5
1.7
1
SM 2320134d
04/08/2024 12:23
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24040046
Chloride
16
mg/L
1
0.0154
10
EPA 9056A
04/03/2024 22:07
BGN9034
Sulfate
0.14
mg/L
0.1
0.0428
1
EPA 9056A
04/03/2024 22:07
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040058
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/04/2024 10:26
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24040064
Aluminum (AI)
0.040
mg/L B2
0.01
0.003
1
SW 6010D
04/08/2024 11:07
CELLI06
Barium (Ba)
0.056
mg/L
0.005
0.002
1
SW 601OD
04/08/2024 11:07
CELLI06
Boron (B)
0.005 U
mg/L
0.05
0.005
1
SW 6010D
04/08/2024 11:07
CELLI06
Calcium (Ca)
8.46
mg/L
0.05
0.012
1
SW 601OD
04/08/2024 11:07
CELLI06
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
04/08/2024 11:07
CELLI06
Iron (Fe)
0.028
mg/L
0.01
0.004
1
SW 6010D
04/08/2024 11:07
CELL106
Magnesium (Mg)
3.22
mg/L
0.02
0.008
1
SW 6010D
04/08/2024 11:07
CELLI06
Manganese (Mn)
0.039
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 11:07
CELLI06
Potassium (K)
1.51
mg/L
0.1
0.031
1
SW 6010D
04/08/2024 11:07
CELLI06
Sodium (Na)
3.94
mg/L
0.05
0.017
1
SW 601OD
04/08/2024 11:07
CELLI06
Strontium (Sr)
0.102
mg/L
0.005
0.001
1
SW 601OD
04/08/2024 11:07
CELLI06
Zinc (Zn)
0.009 J
mg/L
0.015
0.004
1
SW 6010D
04/08/2024 11:07
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040070
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
04/08/2024 13:40
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
04/08/2024 13:40
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
04/08/2024 13:40
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020E
04/08/2024 13:40
MHALL3
Chromium (Cr)
0.289 J
ug/L
1
0.185
1
SW 6020B
04/08/2024 13:40
MHALL3
Cobalt (Co)
0.407 J
ug/L
1
0.077
1
SW 6020E
04/08/2024 13:40
MHALL3
Lead (Pb)
0.044 J
ug/L
1
0.037
1
SW 6020B
04/08/2024 13:40
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020E
04/08/2024 13:40
MHALL3
Nickel (Ni)
0.778 J
ug/L
1
0.256
1
SW 6020E
04/08/2024 13:40
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
04/08/2024 13:40
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
04/08/2024 13:40
MHALL3
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
SW 6020E
04/08/2024 13:40
MHALL3
TOTAL DISSOLVED SOLIDS - Q24040038
TDS
70.0
mg/L
25
25
1
SM2540C
04/02/202413:16
SNEGLIA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030517
Site: ASA FD-20240401-1 Duplicate
Collection Date: 04/01/2024 Loc code: ASA FD
Analyte Result Units Qualifiers RDL MDL DF
TOTAL SUSPENDED SOLIDS - Q24040028
TSS 5 U mg/L 5 5 1
Sample #: 2024007436
Matrix: GW RCRA
Page 19 of 33
Method Analysis Date/Time Analyst
SM2540D 04/02/202410:28 HHOOGKA

Certificate of Laboratory Analysis Page 20 of 33
This report shall not be reproduced, except in full.
Order # J24030517
Site: ASA FB-20240401-1500 Field Blank Sample #: 2024007437
Collection Date: 04/01/2024 03:00 PM Loc code: ASA FB Matrix: GW RCRA
Analyte Result Units Qualifiers RDL
LOW LEVEL ALKALINITY (FIXED END POINT) - Q24040131
Alkalinity, Bicarbonate 1.7 U mg/L 5
Alkalinity, Carbonate 1.7 U mg/L 5
Total Alkalinity as CaCO3 1.7 U mg/L 5
(CaCO3)
INORGANIC IONS BY IC - Q24040046
Chloride 0.0154 U mg/L
Sulfate 0.0428 U mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040058
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040064
Aluminum (AI)
0.003 U
mg/L
Barium (Ba)
0.002 U
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
0.012 U
mg/L
Copper (Cu)
0.001 U
mg/L
Iron (Fe)
0.004 U
mg/L
Magnesium (Mg)
0.008 U
mg/L
Manganese (Mn)
0.001 U
mg/L
Potassium (K)
0.031 U
mg/L
Sodium (Na)
0.017 U
mg/L
Strontium (Sr)
0.001 U
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040070
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.185 U
ug/L
Cobalt (Co)
0.077 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.256 U
ug/L
Selenium (Se)
0.193 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
0.114 U
ug/L
MDL
DF
Method
Analysis Date/Time
Analyst
1.7
1
SM 2320134d
04/08/2024 12:30
SNEGLIA
1.7
1
SM 2320134d
04/08/2024 12:30
SNEGLIA
1.7
1
SM 2320134d
04/08/2024 12:30
SNEGLIA
0.1
0.0154
1
EPA 9056A
04/03/2024 20:29
BGN9034
0.1
0.0428
1
EPA 9056A
04/03/2024 20:29
BGN9034
0.05
0.01
1
EPA 7470A
04/04/2024 10:28
SNEGLIA
B2 0.01
0.003
1
SW 601OD
04/08/2024 11:11
CELL106
0.005
0.002
1
SW 601OD
04/08/2024 11:11
CELL106
0.05
0.005
1
SW 601OD
04/08/2024 11:11
CELL106
0.05
0.012
1
SW 601OD
04/08/2024 11:11
CELL106
0.005
0.001
1
SW 601OD
04/08/2024 11:11
CELL106
0.01
0.004
1
SW 601OD
04/08/2024 11:11
CELL106
0.02
0.008
1
SW 601OD
04/08/2024 11:11
CELL106
0.005
0.001
1
SW 601OD
04/08/2024 11:11
CELL106
0.1
0.031
1
SW 601OD
04/08/2024 11:11
CELL106
0.05
0.017
1
SW 601OD
04/08/2024 11:11
CELL106
0.005
0.001
1
SW 601OD
04/08/2024 11:11
CELL106
0.015
0.004
1
SW 601OD
04/08/2024 11:11
CELL106
1
0.104
1
SW 6020B
04/08/2024 13:48
MHALL3
1
0.111
1
SW 6020B
04/08/2024 13:48
MHALL3
1
0.249
1
SW 6020B
04/08/2024 13:48
MHALL3
1
0.032
1
SW 6020E
04/08/2024 13:48
MHALL3
1
0.185
1
SW 6020B
04/08/2024 13:48
MHALL3
1
0.077
1
SW 6020E
04/08/2024 13:48
MHALL3
1
0.037
1
SW 6020B
04/08/2024 13:48
MHALL3
1
0.18
1
SW 6020E
04/08/2024 13:48
MHALL3
1
0.256
1
SW 6020E
04/08/2024 13:48
MHALL3
1
0.193
1
SW 6020B
04/08/2024 13:48
MHALL3
0.2
0.041
1
SW 6020B
04/08/2024 13:48
MHALL3
0.3
0.114
1
SW 6020E
04/08/2024 13:48
MHALL3

Certificate of Laboratory Analysis Page 21 of 33
This report shall not be reproduced, except in full.
Order # J24030517
Site: ASA MW-2B-A1
Sample #: 2024008254
Collection Date: 04/01/2024 02:45 PM
Loc code: ASA MW-2B-A1
Matrix: GW
RCRA
Analyte Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q24040131
Alkalinity, Bicarbonate 15.2
mg/L
5
1.7
1
SM 2320134d
04/08/2024 12:35
SNEGLIA
Alkalinity, Carbonate 1.7 U
mg/L
5
1.7
1
SM 2320134d
04/08/2024 12:35
SNEGLIA
Total Alkalinity as CaCO3 15.2
mg/L
5
1.7
1
SM 2320134d
04/08/2024 12:35
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24040046
Chloride 16 mg/L
Sulfate 0.14 J mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040058
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040064
Aluminum (AI)
0.084
mg/L
Barium (Ba)
0.055
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
8.20
mg/L
Copper (Cu)
0.001 U
mg/L
Iron (Fe)
0.077
mg/L
Magnesium (Mg)
3.17
mg/L
Manganese (Mn)
0.040
mg/L
Potassium (K)
1.48
mg/L
Sodium (Na)
3.57
mg/L
Strontium (Sr)
0.098
mg/L
Zinc (Zn)
0.008 J
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040070
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.048 J
ug/L
Chromium (Cr)
0.304 J
ug/L
Cobalt (Co)
0.541 J
ug/L
Lead (Pb)
0.074 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.799 J
ug/L
Selenium (Se)
0.193 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
0.151 J
ug/L
TOTAL DISSOLVED SOLIDS - Q24040038
TDS
69.0
mg/L
0.5
0.0154
5
EPA 9056A
04/03/2024 20:49
BGN9034
0.5
0.0428
5
EPA 9056A
04/03/2024 20:49
BGN9034
0.05
0.01
1
EPA 7470A
04/04/2024 10:30
SNEGLIA
B2 0.01
0.003
1
SW 6010D
04/08/2024 12:01
CELL106
0.005
0.002
1
SW 601OD
04/08/2024 12:01
CELL106
0.05
0.005
1
SW 6010D
04/08/2024 12:01
CELL106
0.05
0.012
1
SW 601OD
04/08/2024 12:01
CELL106
0.005
0.001
1
SW 6010D
04/08/2024 12:01
CELL106
0.01
0.004
1
SW 601OD
04/08/2024 12:01
CELL106
0.02
0.008
1
SW 6010D
04/08/2024 12:01
CELL106
0.005
0.001
1
SW 601OD
04/08/2024 12:01
CELL106
0.1
0.031
1
SW 6010D
04/08/2024 12:01
CELL106
0.05
0.017
1
SW 601OD
04/08/2024 12:01
CELL106
0.005
0.001
1
SW 601OD
04/08/2024 12:01
CELL106
0.015
0.004
1
SW 6010D
04/08/2024 12:01
CELL106
1
0.104
1
SW 6020B
04/08/2024 15:46
MHALL3
1
0.111
1
SW 6020B
04/08/2024 15:46
MHALL3
1
0.249
1
SW 6020B
04/08/2024 15:46
MHALL3
1
0.032
1
SW 6020E
04/08/2024 15:46
MHALL3
1
0.185
1
SW 6020B
04/08/2024 15:46
MHALL3
1
0.077
1
SW 6020E
04/08/2024 15:46
MHALL3
1
0.037
1
SW 6020B
04/08/2024 15:46
MHALL3
1
0.18
1
SW 6020E
04/08/2024 15:46
MHALL3
1
0.256
1
SW 6020E
04/08/2024 15:46
MHALL3
1
0.193
1
SW 6020B
04/08/2024 15:46
MHALL3
0.2
0.041
1
SW 6020B
04/08/2024 15:46
MHALL3
0.3
0.114
1
SW 6020E
04/08/2024 15:46
MHALL3
25
25
1
SM2540C
04/02/202413:16
SNEGLIA

Certificate of Laboratory Analysis Page 22 of 33
This report shall not be reproduced, except in full.
Order # J24030517
Site: ASA MW-2B-A1 Sample #: 2024008254
Collection Date: 04/01/2024 02:45 PM Loc code: ASA MW-2B-A1 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
TOTAL SUSPENDED SOLIDS - Q24040028
TSS 5 U mg/L 5 5 1 SM2540D 04/02/2024 10:28 HHOOGKA
Qualifiers:
B2 Target analyte was detected in Method/Prep Blank(s) at a concentration greater than '/2 the reporting limit but less than the
reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an estimate.

Certificate of Laboratory Analysis Page 23 of 33
This report shall not be reproduced, except in full.
Order # J24030517
Level II QC Summary
Q24040074 ALK CarbBicarb TOTAL ALKALINITY
Duplicate # I
Parameter
Measured
Final
Alkalinity, Bicarbonate
81.1
Alkalinity, Carbonate
0
Total Alkalinity as CaCO3
81.1
Duplicate # 2
Parameter
Measured
Final
Alkalinity, Bicarbonate
75.7
Alkalinity, Carbonate
0
Total Alkalinity as CaCO3
75.7
Duplicate # 3
Parameter
Measured
Final
Alkalinity, Bicarbonate
31.7
Alkalinity, Carbonate
0
Total Alkalinity as CaCO3
31.7
LCS # I
Parameter
Measured
Final
Total Alkalinity as CaCO3
78.3
LCS # 2
Parameter
Measured
Final
Total Alkalinity as CaCO3
79.7
LCS # 3
Parameter
Measured
Final
Total Alkalinity as CaCO3
79.3
Parent Sample:
J24030604 -- 2024007765
Units
Dil
MDL
RPD
Qualifier
mg/L
1
1.7
2.93
mg/L
1
1.7
0
mg/L
1
1.7
2.93
Parent Sample:
J24030604 -- 2024007766
Units
Dil
MDL
RPD
Qualifier
mg/L
1
1.7
1.81
mg/L
1
1.7
0
mg/L
1
1.7
1.81
Parent Sample:
J24030517 -- 2024007430
Units
Dil
MDL
RPD
Qualifier
mg/L
1
1.7
2.03
mg/L
1
1.7
0
mg/L
1
1.7
2.03
Units
Dil
MDL
Spike
% Recover v
LCL UCL
Qualifier
mg/L
1
1.7
77.9
101
85 115
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
mg/L
1
1.7
77.9
102
85 115
Units
Dil
MDL
Spike
% Recover v
LCL UCL
Qualifier
mg/L
1
1.7
77.9
102
85 115

Certificate of Laboratory Analysis Page 24 of 33
This report shall not be reproduced, except in full.
Order # J24030517
Level II QC Summary
Q24040131 ALK LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
LCS # 1
Parameter Measured Final
Total Alkalinity as CaCO3 74.5
Units Dil MDL Spike % Recovery LCL UCL
mg/L 1 1.7 77.9 95.7 85 115
(CaCO3)
Qualifier
LCSD # 1
Parameter Measured Final Units Dil MDL Spike % Recovery LCL UCL RPD Qualifier
Total Alkalinity as CaCO3 73.2 mg/L 1 1.7 77.9 94 85 115 1.76
(CaCO3)

Certificate of Laboratory Analysis Page 25 of 33
This report shall not be reproduced, except in full.
Order # J24030517
Level II QC Summary
Q24040046 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Sulfate
0
0
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S Ike
% Recovery
LCL
UCL
Chloride
5.08
5.08
mg/L
1
0.0154
5
102
80
120
Sulfate
5.13
5.13
mg/L
1
0.0428
5
103
80
120
MS # 1
Parent Sample:
J24030518 -- 2024007439
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Chloride
4.32
21.6
mg/L
5
0.0154
5
99.5
80
120
Sulfate
6.01
90.1
mg/L
15
0.0428
5
111
80
120
MSD # 1
Parent Sample:
J24030518 -- 2024007439
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Chloride
4.31
21.6
mg/L
5
0.0154
5
99.1
80
120 0.403
Sulfate
6
90
mg/L
15
0.0428
5
110
80
120 0.812
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 26 of 33
This report shall not be reproduced, except in full.
Order # J24030517
Level II QC Summary
Q24040058 HG 7470 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Mercury (Hg)
-0.005
-0.005
Blank # 2
Parameter
Measured
Final
Mercury (Hg)
-0.005
-0.005
LCS # 1
MS # 1
MSD # 1
MS # 2
MSD # 2
Parameter Measured Final
Mercury (Hg) 2.01 2.01
Parameter Measured Final
Mercury (Hg) 0.998 0.998
Parameter Measured Final
Mercury (Hg) 1 1
Parameter Measured Final
Mercury (Hg) 0.991 0.991
Parameter Measured Final
Mercury (Hg) 1 1
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
ug/L
1
0.01
0.05
< MDL
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
ug/L
1
0.01
0.05
< MDL
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
ug/L
1
0.01
2
101
85 115
Parent Sample:
J24030517 -- 2024007428
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
ug/L
1
0.01
1
99.5
75 125
Parent Sample:
J24030517 -- 2024007428
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
ug/L
1
0.01
1
99.8
75 125 0.301
Parent Sample:
J24030518 -- 2024007439
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
ug/L
1
0.01
1
98.8
75 125
Parent Sample:
J24030518 -- 2024007439
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
ug/L
1
0.01
1
100
75 125 1.41

Certificate of Laboratory Analysis Page 27 of 33
This report shall not be reproduced, except in full.
Order # J24030517
Level II QC Summary
Q24040064 ICP_TRM TOTAL RECOVERABLE METALS BY 1CP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration Qualifier
Aluminum (AI)
0.00704
0.00704
mg/L
1
0.003
0.01
> MDL B2
Barium (Ba)
0.000176
0.000176
mg/L
1
0.002
0.005
< MDL
Boron (B)
0.00515
0.00515
mg/L
1
0.005
0.05
> MDL
Calcium (Ca)
0.00835
0.00835
mg/L
1
0.012
0.05
< MDL
Copper (Cu)
0.000453
0.000453
mg/L
1
0.001
0.005
< MDL
Iron (Fe)
0.00321
0.00321
mg/L
1
0.004
0.01
< MDL
Magnesium (Mg)
0.0099
0.0099
mg/L
1
0.008
0.02
> MDL
Manganese (Mn)
0.000346
0.000346
mg/L
1
0.001
0.005
< MDL
Potassium (K)
-0.0148
-0.0148
mg/L
1
0.031
0.1
< MDL
Sodium (Na)
-0.000749
-0.000749
mg/L
1
0.017
0.05
< MDL
Strontium (Sr)
0.000173
0.000173
mg/L
1
0.001
0.005
< MDL
Zinc (Zn)
0.000838
0.000838
mg/L
1
0.004
0.015
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL Qualifier
Aluminum (AI)
5.14
5.14
mg/L
1
0.003
5
103
80
120
Barium (Ba)
5.1
5.1
mg/L
1
0.002
5
102
80
120
Boron (B)
5
5
mg/L
1
0.005
5
100
80
120
Calcium (Ca)
5.13
5.13
mg/L
1
0.012
5
103
80
120
Copper (Cu)
5.08
5.08
mg/L
1
0.001
5
102
80
120
Iron (Fe)
5.14
5.14
mg/L
1
0.004
5
103
80
120
Magnesium (Mg)
5.14
5.14
mg/L
1
0.008
5
103
80
120
Manganese (Mn)
5.09
5.09
mg/L
1
0.001
5
102
80
120
Potassium (K)
5.14
5.14
mg/L
1
0.031
5
103
80
120
Sodium (Na)
5.13
5.13
mg/L
1
0.017
5
103
80
120
Strontium (Sr)
5.05
5.05
mg/L
1
0.001
5
101
80
120
Zinc (Zn)
5.09
5.09
mg/L
1
0.004
5
102
80
120
MS # 1
Parent Sample:
J24030517
-- 2024007428
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL Qualifier
Aluminum (AI)
6.04
6.04
mg/L
1
0.003
5
113
75
125
Barium (Ba)
5.18
5.18
mg/L
1
0.002
5
103
75
125
Boron (B)
5.06
5.06
mg/L
1
0.005
5
101
75
125
Calcium (Ca)
10.1
10.1
mg/L
1
0.012
5
104
75
125
Copper (Cu)
5.1
5.1
mg/L
1
0.001
5
102
75
125
Iron (Fe)
5.48
5.48
mg/L
1
0.004
5
105
75
125
Magnesium (Mg)
8.07
8.07
mg/L
1
0.008
5
104
75
125
Manganese (Mn)
5.15
5.15
mg/L
1
0.001
5
103
75
125
Potassium (K)
6.21
6.21
mg/L
1
0.031
5
104
75
125
Sodium (Na)
8.4
8.4
mg/L
1
0.017
5
104
75
125

Certificate of Laboratory Analysis Page 28 of 33
This report shall not be reproduced, except in full.
Order # J24030517
Level II QC Summary
Q24040064 ICP_TRM TOTAL RECOVERABLE METALS BY 1CP
MS # 1
Parameter
Measured
Final
Strontium (Sr)
5.13
5.13
Zinc (Zn)
5.12
5.12
MSD # 1
Parameter
Measured
Final
Aluminum (AI)
5.95
5.95
Barium (Ba)
5.21
5.21
Boron (B)
5.07
5.07
Calcium (Ca)
10.1
10.1
Copper (Cu)
5.13
5.13
Iron (Fe)
5.51
5.51
Magnesium (Mg)
8.06
8.06
Manganese (Mn)
5.18
5.18
Potassium (K)
6.25
6.25
Sodium (Na)
8.41
8.41
Strontium (Sr)
5.2
5.2
Zinc (Zn)
5.15
5.15
Parent Sample:
J24030517 -- 2024007428
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
mg/L
1
0.001
5
101
75
125
mg/L
1
0.004
5
102
75
125
Parent Sample:
J24030517
-- 2024007428
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
mg/L
1
0.003
5
111
75
125
1.5
mg/L
1
0.002
5
104
75
125
0.577
mg/L
1
0.005
5
101
75
125
0.197
mg/L
1
0.012
5
104
75
125
0
mg/L
1
0.001
5
103
75
125
0.587
mg/L
1
0.004
5
105
75
125
0.546
mg/L
1
0.008
5
104
75
125
0.124
mg/L
1
0.001
5
103
75
125
0.581
mg/L
1
0.031
5
105
75
125
0.642
mg/L
1
0.017
5
104
75
125
0.119
mg/L
1
0.001
5
103
75
125
1.36
mg/L
1
0.004
5
103
75
125
0.584
Qualifiers:
B2 Target analyte was detected in Method/Prep Blank(s) at a concentration greater than '/2 the reporting limit but
less than the reporting limit. Analyte concentration in sample is valid and may be used for compliance
purposes.
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030517
Level II QC Summary
Q24040070 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Page 29 of 33
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
0.003
0.003
ug/L
1
0.104
1
< MDL
Arsenic (As)
0.004
0.004
ug/L
1
0.111
1
< MDL
Beryllium (Be)
0.015
0.015
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0.006
0.006
ug/L
1
0.032
1
< MDL
Chromium (Cr)
0.047
0.047
ug/L
1
0.185
1
< MDL
Cobalt (Co)
-0.003
-0.003
ug/L
1
0.077
1
< MDL
Lead (Pb)
0.009
0.009
ug/L
1
0.037
1
< MDL
Molybdenum (Mo)
0.008
0.008
ug/L
1
0.18
1
< MDL
Nickel (Ni)
0.022
0.022
ug/L
1
0.256
1
< MDL
Selenium (Se)
0.178
0.178
ug/L
1
0.193
1
< MDL
Thallium (TI) Low Level
-0.008
-0.008
ug/L
1
0.041
0.2
< MDL
Vanadium (V) Low Level
0.041
0.041
ug/L
1
0.114
0.3
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
48.6
48.6
ug/L
1
0.104
50
97.2
80
120
Arsenic (As)
49.1
49.1
ug/L
1
0.111
50
98.2
80
120
Beryllium (Be)
47.9
47.9
ug/L
1
0.249
50
95.8
80
120
Cadmium (Cd)
48.8
48.8
ug/L
1
0.032
50
97.6
80
120
Chromium (Cr)
48.3
48.3
ug/L
1
0.185
50
96.7
80
120
Cobalt (Co)
49.1
49.1
ug/L
1
0.077
50
98.1
80
120
Lead (Pb)
49
49
ug/L
1
0.037
50
98
80
120
Molybdenum (Mo)
49.1
49.1
ug/L
1
0.18
50
98.3
80
120
Nickel (Ni)
48.7
48.7
ug/L
1
0.256
50
97.5
80
120
Selenium (Se)
48.2
48.2
ug/L
1
0.193
50
96.4
80
120
Thallium (TI) Low Level
48.6
48.6
ug/L
1
0.041
50
97.3
80
120
Vanadium (V) Low Level
48.4
48.4
ug/L
1
0.114
50
96.8
80
120
MS # 1
Parent Sample:
J24030517 -- 2024007430
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
48.9
48.9
ug/L
1
0.104
50
97.7
75
125
Arsenic (As)
49.3
49.3
ug/L
1
0.111
50
98
75
125
Beryllium (Be)
47.8
47.8
ug/L
1
0.249
50
95.5
75
125
Cadmium (Cd)
49.3
49.3
ug/L
1
0.032
50
97
75
125
Chromium (Cr)
49.1
49.1
ug/L
1
0.185
50
97.6
75
125
Cobalt (Co)
62.6
62.6
ug/L
1
0.077
50
97.2
75
125
Lead (Pb)
49.6
49.6
ug/L
1
0.037
50
98.9
75
125
Molybdenum (Mo)
49.6
49.6
ug/L
1
0.18
50
99.1
75
125
Nickel (Ni)
49.7
49.7
ug/L
1
0.256
50
97.4
75
125
Selenium (Se)
48.2
48.2
ug/L
1
0.193
50
96.1
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 30 of 33
This report shall not be reproduced, except in full.
Order # J24030517
Level II QC Summary
Q24040070 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 1
Parameter
Measured
Final
Units
Thallium (TI) Low Level
49.2
49.2
ug/L
Vanadium (V) Low Level
48.8
48.8
ug/L
MSD # 1
Parameter
Measured
Final
Units
Antimony (Sb)
48.9
48.9
ug/L
Arsenic (As)
48.9
48.9
ug/L
Beryllium (Be)
50.2
50.2
ug/L
Cadmium (Cd)
49.4
49.4
ug/L
Chromium (Cr)
49.2
49.2
ug/L
Cobalt (Co)
62
62
ug/L
Lead (Pb)
49.2
49.2
ug/L
Molybdenum (Mo)
49.4
49.4
ug/L
Nickel (Ni)
49.8
49.8
ug/L
Selenium (Se)
46.7
46.7
ug/L
Thallium (TI) Low Level
49.2
49.2
ug/L
Vanadium (V) Low Level
48.9
48.9
ug/L
Parent Sample:
J24030517 -- 2024007430
Dil
MDL
Spike
% Recovery
LCL
UCL
1
0.041
50
98.2
75
125
1
0.114
50
97
75
125
Parent Sample:
J24030517
-- 2024007430
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
1
0.104
50
97.7
75
125
0.0225
1
0.111
50
97.2
75
125
0.838
1
0.249
50
100
75
125
4.85
1
0.032
50
97.1
75
125
0.136
1
0.185
50
98
75
125
0.354
1
0.077
50
96
75
125
1.19
1
0.037
50
98.1
75
125
0.829
1
0.18
50
98.7
75
125
0.38
1
0.256
50
97.7
75
125
0.246
1
0.193
50
93
75
125
3.24
1
0.041
50
98.1
75
125
0.0571
1
0.114
50
97.3
75
125
0.296
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 31 of 33
This report shall not be reproduced, except in full.
Order # J24030517
Level II QC Summary
Q24040038 TDS TOTAL DISSOLVED SOLIDS
Blank # 1
Parameter Measured Final
TDS -0.5
Duplicate # 1
Parameter Measured Final
TDS 51
LCS # 1
Parameter Measured Final
TDS 503
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
25
25
< MDL
Parent Sample: J24030517 -- 2024007428
Units
Dil
MDL
RPD
Qualifier
mg/L
1
25
17
R1
Units
Dil
MDL
Spike
% Recovery LCL UCL
Qualifier
mg/L
1
25
500
101 90 110
Qualifiers:
R1 Relative Percent Difference exceeded method acceptance limits.

Certificate of Laboratory Analysis Page 32 of 33
This report shall not be reproduced, except in full.
Order # J24030517
Level II QC Summary
Q24040028 TSS TOTAL SUSPENDED SOLIDS
Blank # 1
Parameter Measured Final
TSS 0.1
Duplicate # 1
Parameter Measured Final
TSS 6.8
LCS # 1
Parameter Measured Final
TSS 97.6
Units
Dil
MDL
RDL
Relative Concentration
mg/L
1
5
5
< MDL
Parent Sample: J24030518 -- 2024007439
Units
Dil
MDL
RPD
mg/L
1
5
0
Units
Dil
MDL
Spike
% Recovery LCL UCL
mg/L
1
5
100
97.6 90 110
Qualifier
Qualifier
Qualifier

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
I.
Duke Energy Analytical Lahoratery
DUKE Mall CotleMGO]AI 1191 Elne74e51 i iDrd
^y 1JJ79 HaQera Feny Rtl
EN�1\�Yn Nunlersnllle, N.C. 1a67fi L ed B
(7841 a753145 j j �g y -C
Fax: "N1875-5N,
Project Name Phone No:
pSHEVILLE AIRPORT FILL AREA I
Client JOHN TOEPFER, BRYAN MOELLER,
DEE O'BRIEN, JOSH STOWE, CONNOR ZAHORA
Operating Unit: AEOO
Pracese; BENVWS
Account;
Project:
Activity ID:
Facility ID: ASA
Program I EQu1S Task Code: SuH-ProgramfTask Code:
COMPLIANCFJSTRFL
_.._.._.._.._.._.._..,
' SAMPLE ID '
NUMBER
Sample Description or ID
i
IZo2`i0t14`42$ ;
ASA_MWAA-A1
`/3Q •.
ASA MW-4A-Al
ASA_MW-6-A1
i 932 I
ASA_MW-6-A1
11133 I
ASA_MW-7-A1
� I
43L�,
ASA_MW-8-A4
`f35
ASA_MW-9-A1
• &t36 •.
ASA _FD-zo-14611 a
i I-3q'
ASA F13-Zuz-40gGl ISbo
i `f3F i
f4&fr Ri� crl
1
u—i mat FoliIn & date below
Relinquished By Date/Time
Relinquished By Date/Time
5r
Relinquished By Date/Time
NOTE: NCDEQ EDD and EQUIS REQUIRED
An!Vtical
I.ahorafory Use Only
Matrix
i�
WATER
NC X
s.n,p11e. o.ieir.tina nom 3C�
Data &Tim t Z Q933
-1
SAMPLE PROGRAM
Ground Water_X_ NPDES_
Clinking Water_ UST_
RCRA Waste
------._.._.._.._..-..._.._................. - .................
2.1
Filtration (0.45 unt(
b Unfiltered
Preservative
ICE
ICE
Container Volume (mL)
300
600
2000
Container Type
PET
HOPE
PET
Customer to compleN all eppmprlate non -shaded areas.
Collection Information
Date
Time
Printed Name
Sign
4-1-2K
13to
,AnCk momisom
4-t-Z4
Nm
HALtyr.EA1W
INSo
LaMrt,a ytxv�
iKos
IAACV- AUW-C SWV
/
I A15
c onL u, tkou
1,150
IN U
t945
Atit9[u ,aoWsory
ISuo
C.VV"--M11-fA
GL,
TOTAL p CONTAINERS
(Y
ICP TRM (6010D); AI,
UO
Ha,H,Ca, Cu,Fe, Mg,
in w
Mn.K.Na. Sr, Zn
m u
IMS TRM 1602019}: S6,
4 rri
Aa, Be, Cd, Cr, Co, Ph,
O
V ZO
Mo, RI, Se TILL}, v(LL)
Hg 1470A
r
f!7
a a'
1
1
1
1`
4-
1 0 0 1 11
Data/Time
4;-1 ; /Z u
DatelTime
`I b 'Z N UlocM
DatelThrie
DatelTime
Page 33 of 33
PRge _1_ of _i_
DISTRIBUTION
ORIGINAL to LAB. COPY to CLIENT
3
Filtered
3
11 0 9 0 0 1 0 1 0 0 0 0 31
A Requested Turnaround Total 31
c
w 9 21 Days
a°
14 Days
c E
�a
E �+
7 Days
i b
o -Other
*Add Cost Will Apply
U

Quarterly Water Quality Monitoring Report — April 2024 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
APPENDIX C
SURFACE WATER SAMPLING LOGS
L7
synTerra
Science & Engineering Consultants

❑CAMA ❑CCR []Landfill ❑NPDES ❑ DGW❑ ASW ❑LRB ❑ SPECIAL STUDY
Site: �5�
FIELD SAMPLING LOG
Well/SW ID: 6 W- Z. A j
�•� DUKE
�C ENERGI
Date: H
❑GROUNDWATER SAMPLE SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑WLO ❑ WELL DEVELOPMENT
FIELD STAFF: J 1
COMPANY: DUKE ENERGY
❑ OTHER:
WEATHER: ❑SUNNY ❑PARTLYCLOUDY C40VERCAST ❑RAIN ESNOW AIRTEMPq.L-_°F
FIELD METER TYPE/ SERIAL #: Cti k �—
TURBIDIMETER TYPE/ SERIAL #: G I S A
START PURGE TIME: SAMPLE COLLECTION TIME:
PUMPITUBING INTAKE DEPTH: ` (ft) DEPTH TO WATER: (ft) MOLT FACTOR ": 0.163 i•(radiu5r12)2* 14•7 481
WELL DIAMETER: (In) HEIGHT OF WC: (ft) WELL VOLUME: — (gal)
WELL DEPTH: (ft) TOTAL VOLUME PURGED: (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
P
R
6
❑ Tubin m (Pup Inspected I i'� I (sec) I rsee) I
❑Good [Tubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event
Additional Notes:
Low Flow Sampling Stabilization Criteria
pH
Specific Conductance
DO
Turbidity
t 0.1 standard unit
f 5% In pS/cm
f 0.2 mg1L or 10% saturation
less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mUrnin)
(x)
(gallons OR mL)
(x.xx)
VC)
(x)
(mg1L)
(x.xx)
(NSIcm)
(x)
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
Zz
fa el
Hbs
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES ❑ NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES?.YES [-]NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑ El NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 DU�LTG�ATE 2 ' (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR on 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH a ' Minor Strong
ADDITIONAL NOTES: APPEARANCE e Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised Uy12*312U22 HFIIJ

❑CAMA ❑CCR Landfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY.
Site: A5A
FIELD SAMPLING LOG
Well/SW ID SQ - 3- A I
Date: y-r-21
L❑GROUMWATER SAMPLEESURFACE WATER SAMPLE❑LEACHATE SAMPLE ❑WLO [:]WELL DEVELOPMENT
FIELD STAFF. GiL WEATHER: ❑SUNNY ❑PARTLY CLOUDY ❑OVERCAST ❑RAIN ]SNOW AIRTEMP: 'F
COMPANY: ❑ DUKE ENERGY FIELD METER TYPE/ SERIAL #: R 1 6
❑ OTHER: TURBIDIMETER TYPE/ SERIAL #: vraU
START PURGE TIME: II o SAMPLE COLLECTION TIME: III()
PUMP/TUBING INTAKE DEPTH: (ft) DEPTH TO WATER: (ft) MULT FACTOR *• 0.163 l•(radius112)2*3.14"7.451
WELL DIAMETER: (in) HEIGHT OF WC: (it) WELL VOLUME: (gal)
WELL DEPTH: J (ft) TOTAL VOLUME PURGED: �IK..: ��. (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other { )
PURGE METHOD:
SAMPLING METHOD:
i
PUMP SETTING:
P
R
&�43
❑ Tubin /Pump Inspected (PSO I (w) I 'sec) I Low Flow Sampling Stabilization Criteria
[]Good [Tubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event pH t 0.1 standard unit
Additional Notes:. Specific Conductance t 5% in PS/cm
• DO t 0.2 mg1L or 10% saturation
• 'Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
PH
QRP
TURBIDITY
(FT)
(x:xx)
(mLlmin)
N.
(gallons OR mL)
(x.xx)
VC)
(x)
(mg/Li
(x.xx)
(PS/cm)
W
(su)
(x.xx)
(mri)
(x)
(NTU)
(x.x)
1 i�4
—
lS
9 t'I
z37
b.a�
31(5
'0..•7
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABQVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES ❑ NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? [ YES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES ❑ NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?❑YES NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH a Minor Strong
ADDITIONAL NOTES: APPEARANCE Gearr Cloudy Turbid RediIron Film on Surface Sheen ("to Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

❑CAMA ❑CCR�Landfiil ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY
FIELD SAMPLING LOG
Site: Al )q Well/SW ID: 5W - ',& - � i
❑GROUNDWATER SAMPLE.[�]SURFACE WATER SAMPLE, ❑LEACHATE SAMPLE
FIELD STAFF: (71-
COMPANY: Q DUKE ENERGY
❑ OTHER:
Date:
WLO ❑ WELL DEVELOPMENT
WEATHER:. ❑SUNNY ❑PARTLYCLOUDY .❑OVERCAST DRAIN ❑SNOW AIRTEMP: "F
FIELD METER TYPE/ SERIAL M 5 ficid
TURBIDIMETER TYPE/ SERIAL #: otv-L
START PURGE TIME:• 17,3S SAMPLE COLLECTION TIME: 1240
P.UMP)TUBING INTAKE DEPTH: (ft) DEPTH TO WATER: (ft) MULT FACTOR * o.1fi3 ('(radEus112)2`3,14'7.g8]
WELL DIAMETER: (in) HEIGHT OF WC: (ft) WELL VOLUME: — (gal)
WELL DEPTH: (ft) TOTAL VOLUME PURGED- (gat)
TYPE OF PUMP: Bladder Peristaltic 12 Volt Grundfos Other (64Z4-3 }
PURGE METHOD;
SAMPLING METHOD; /
PUMP SETTING: ` R
❑ Tubin /Pump In t°5' ls�i t5e�� Low Flow Sampling Stabilization Criteria
❑Good -Tubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next. Event PH :k 0.1 standard unit
Additional Notes: Specific Conductance f 5% in VS/cm
DO 10.2 mg)L or 10% saturation
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
PH
ORP
TURBIDITY
(FT)
(x.xx)
{mLlmin)
{x)
(gallons OR mL)
(X.kx)
VC)
(x)
{mg/L)
(x-xx
(Alc.m)
7{x}
{su}
(x.xx)
5.ab
(mv)
{x}
3o
(N7U)
(x-x)
I2�
PLEASE REFER
TO THE
BACK OF THIS SHEET
IF THE:
CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES .. NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? DYES ❑NO.
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YESNO IS THE LOCATfON FIELD VEHICLE ACCESSIBLE?❑ -YES ❑ NO
IS THE. TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 7 (NTUj DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS;
DETECTED ODOR H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH a Minor Strong
APPEARANCE
ADDITIONAL NOTES: 4 51�r Cloudy Turbid Redllron Film on Surface Sheen nes Floc
WELL TAG PROTECTIVE CASING LOCK DUST CAP CONCRETE PAD
GOOD I BAD NONE GOOD BAD NONE I GOODI BAD I NONE GOOD I BAD NONE GOOD BAD I NONE
C
Version 1.2 Revised 09/2912022 HPB

�CAMA ❑CCR Landfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY
FIELD SAMPLING LOG
Site; ASS Well/SW ID: 5W V G - I
Date: Y-wZq
� N RG`
❑GROUNDWATER SAMPLE ESURFACE WATER SAMPLE[:] LEACHATr= SAMPLE. ❑WLO ❑ WELL DEVELOPMENT
FIELD STAFF, lit
COMPANY: Q DUKE ENERGY
❑ OTHER:
WEATHER: ❑SUNNY ❑PARTLY CLOUDY ❑OVERCAST ❑RAIN ❑SNOW AIR TEMP: "F
FIELD METER TYPEI SERIAL M l't &L
TURBIDIMETER TYPE/ SERIAL #: &Wt
START PURGE TIME: 12. SU
PUMPIrUBING INTAKE DEPTH: (ft)
WELL DIAMETER: (in)
WELL DEPTH: (ft)
TYPE OF PUMP:
PURGE METHOD:
SAMPLING METHOD:
i PUMP SETTING:
❑ Tubin /Pump Inspected
❑Good Tubing Bad ❑Pump Bad
Additional Notes:
SAMPLE COLLECTION TIME:
DEPTH TO WATER: L (�) MULT FACTOR *: 0.163 [•(radiustl2)2'3.t4 7.4a)
HEIGHT OF WC: WELL VOLUME: (gal)
TOTAL VOLUME PURGED: (gal)
Bladder Peristaltic 12 Volt Grundfos Other { )
fps} I (Secs I *o I Low Flow SaMplin-q Stabilization Criteria
❑Changed/Cleaned []Correct Next Event - pH 10.1 standard unit
• Specf€Ic Conductance f 5% in PSI cm
DO 4 0.2 mg/L or 10% saturation
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME.
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
PH
ORP
TURBIDITY
{FT)
(x.xx)
{mL/m[n)
(x)
(gallons OR mL)
(x.xx)
("C}
(x)
(mg/L)
(x.xx)
(}JS/cm)
{x)
(Su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
PLEASE REFER
TO THE
BACK OF THIS SHEET
IF THE
CHART ABOVE
IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES ❑ NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? ❑YES []NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES ❑ NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?[] YES ❑-NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%?.❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR. None H28 Petroleum Earthy Musty undetermined
ODOR STRENGTH None Minor Strang.
ADDITIONAL NOTES; APPEARANCE Clear Cloudy Turbid Red/Iron Film an Surface Sheen Fines Floc
WELL TAG
GOOD BAD NONE
PROTECTIVE CASING
GOOD BAD NONE
LOCK
GOOD BAD NONE
DUST CAP
GOOp. BAD NONE
CONCRETE PAD
GOOD BAD NONE
version 'I.Z Revised 09/29/2022 HPB

❑LAMA ❑CCR❑Landfll ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY
Site: A S 4
FIELD SAMPLING LOG
WeII1SW ID: Sw-s-A )
Date: 11 1- Z
� DUKE
ENERGY
uGROUNDWATER SAMPLE 2SURFAC E WATER SAMPLE ❑LEACHATESAMPLE ❑WLO ❑WELL DEVELOPMENT
FIELD STAFF: C-'S1.
COMPANY: Q DUKE ENERGY
❑ OTHER:
WEATHER: ❑SUNNY El PARTLY CLOUDY El OVERCAST [DRAIN []SNOW AIRTEMP: °F
FIELD METER TYPE/ SERIAL #:_ /t/ g(,
TURBID]METER TYPE/ SERIAL #; 00"
START PURGE TIME: IZw SAMPLE COLLECTION TIME:
PUMP/TUBING INTAKE DEPTH: {tt) DEPTH TO WATER: A MULT FACTOR "- 0.163 ['(radius/12)2'3.14"7.481
WELL DIAMETER: (in) HEIGHT OF WC: `— (ft) WELL VOLUME: -- (gat)
WELL DEPTH: () TOTAL VOLUME PURGED: (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( }
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
❑ Tubin /Purrip Inspected (psi) (Sec) (yen)
❑Good �7ub.ing Bad ❑Pump Bad ❑Cttanged/Cleaned ❑Correct Next Event
Additional Notes: r
a
Low Flow Sampling Stabilization Criteria
pH :t 0.1 standard unit
Specific Conductance t 5% in pS/cm
DO t 0.2 mg/L or 10% saturation
Turbidity less then 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mUmin)
(x)
(gallons OR mL)
(x.xx)
VC)
(x)
(mg/L)
(x.xx)
(PS/cm)
{x)
(sti)
(x,xx)
(mv)
(x)
(NTU)
(x.x)
S
rir)t ntr*rm i U i Mr- bAt^ Ur- I HIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES ❑ NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? ❑YES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? El YES ❑ NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? ❑ YES Q NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES [:]NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR None H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH None Minor Strong
ADDITIONAL NOTES: APPEARANCE. Clear Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
I NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

[JCAMA []CCR Landfill RNPDES ❑ DGW❑ASW [—]LRBR SPECIAL STUDY.
FIELD SAMPLING LOG
� DUKE
Site: ASH WeWSW ID W- q- A J Dater y-I-zi
GROUNDWATER SAMPLEE38URFACE WATER SAMPLE RLEACHATE SAMPLE R WLO ❑ WELL DEVELOPMENT
FIELD STAFF: 0-L
COMPANY: 0 DUKE ENERGY
❑ OTHER:
WEATHER: ❑SUNNY ❑PARTLY.CLOUDY ❑OVERCAST ❑RAIN SyOW AIR TEMP: 'F
FIELD METER TYPE/ SERIAL #: r1 l 2
TURBIDIMETER TYPE/ SERIAL #: 01VL
START PURGE TIME: — T 225 SAMPLE COLLECTION TIME: (7-3U
PUMPITUBING INTAKE DEPTH:. — (h) DEPTH TO WATER: — 00 MULT FACTOR *: 0-163 €•(radiuslt2)2-3.147.aal
WELL DIAMETER: — (in) HEIGHT OF WC: fft) WELL VOLUME: (gal)
WELL DEPTH: (M TOTAL VOLUME PURGED; — (gal)
TYPE OF PUMP: Bladder Peristaltic 12 Volt Grundfos Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
❑ Tubin /Pump. Inspected (w) (seak (sec) Low Flow Sampling Stabilization Criteria
❑Good HTubing Bad []Pump BE [:]Changed/Cleaned ❑Correct Next Event PH. f 0.1 standard Unit
Additional Notes: Specific Conductance t 5% In pVcm
DO :0.2 mg/L.or 10% saturation
• Turbidity less than 10 NTUs
TIME-
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
PH
ORP
TURBIDITY
ii26
(FT)
(x.xx)
(m[Jmin)
W
(gallons OR nn
(x.xx)
VC)
(x)
(mg1L)
(x:xx)
(NSlcm)
(x)
(su)
(x.xx)
5.58
(mv)
W
31f1
(NTU)
(x.x)
s:a
PLEASE REFER
TO THE
BACK OF THIS SHEET
IF THE
CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES ❑ NO WERE ALL SAMPLES ON ICE WITHIN 1.5 MINUTES? [3YES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES ❑ NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? R YES Q'NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 150/.? R YES [:]NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR Non H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH a Minor Strong
ADDITIONAL NOTES: APPEARANCE Cie Cloudy Turbid Red/Iron Film on Surface Sheen. Fines Floc
WELL TAG PROTECTIVE CASING
GOOD I BAD I NONE I GOOD I BAD NONE
LOCK DUST CAP
BAD I NONE I GOOD.,, BAD NONE
PAD
NONE
Version 1.2 Revised 09/29/2022

❑CAMA ❑CCR[71Landfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY.
FIELD SAMPLING LOG
Site: ASS Well/SW ID: 5w- f U- /9 ( Date:
N � ERG`
❑GROUNDWATER SAMPLE❑SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE. ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: L WEATHER: ❑SUNNY ❑PARTLYCLOUDY ❑OVERCAST ❑RAIN ❑SNOW AIRTEMP: °F
COMPANY: Z DUKE ENERGY FIELD METER TYPE/ SERIAL #: 25,M4
❑ OTHER: TURBIDIMETER TYPE/ SERIAL #: Olaf
START PURGE TIME,. 17,1,0 SAMPLE COLLECTION TIME: IZ15
PUMP/TUBING INTAKE DEPTH: J (K) DEPTH TO WATER: (0) MULT FACTOR*: 0-163 Mradius/12)2*114"7.481
WELL DIAMETER: (in) HEIGHT OF WC: (tt) WELL VOLUME: (gal)
WELL DEPTH: TOTAL VOLUME PURGED: (gal)
TYPE OF PUMP: Bladder Peristaltic 12 Volt Grundfos Other( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING: r A o
❑ Tuhin IPump Inspected LIT)
Tubing Bad ❑Pump Bad ❑
Additional Notes -
(sec) I (sect
leaned []Correct Next Event
pH
Speciflc Conductance
DO
Turgidity
* 0.1 standard unit
* 5% In pSlcm
* 0.2 mg/L or 10% saturation
less than 10 NTUs
TIME
(ZI
WATER
LEVEL.
(FT)
(x.xx)
FLOW
RATE
(mLlmtn)
(x)
VOLUME
REMOVED
(gallons OR m
(x:xx)
TEMPERATURE
(IC)
(x)
M
DO
(mg/L)
(x.xx)
5J LA
SPECIFIC
CONDUCTANCE
(PS/cm)
(x)
2C1b
pH
(su)
(x.xx)
f G 3
ORP
(mV)
(x)
ZZ
TURBIDITY
(NTU)
(x.x)
a•B'
1 rna arint I it- I HL UHAK I ABOVE 15 FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES ❑ NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? ❑YES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑ YES ❑ NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?❑ -YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR No 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH No Minor Strong
ADDITIONAL_ NOTES: APPEARANCE CI ar Cloudy Turbid Redllron Film on Surface Sheen Ines Floc
WELL TAG
GOOD BAD NONE
PROTECTIVE CASINGx
GOOD BAD NDNE
LOCK
GOOD BAD NONE
DUST CAP
GOOD E3AD NONE
CONCRETE P
GOOD BAD NONE
r
Version 1.2 Revised 09/29/2022 HPB

Quarterly Water Quality Monitoring Report — April 2024 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
APPENDIX D
SURFACE WATER LABORATORY ANALYTICAL REPORTS
L7
synTerra
Science & Engineering Consultants

DUKE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J24030518
Project Name: ASHEVILLE AIRPORT - AIRPORT FILL AREA I SW - (IN-HOUSE)
Task Code: STRFL
Customer Name(s): John Toepfer, B Moeller, Josh Stowe, C Zahora
Customer Address: Asheville Airport
Lab Contact: Peggy Kendall Phone: [phone]
Report Authorized By: pate: 4/17/2024
(Signature)
eg Kendall
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
Page 1 of 40
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
2024007439
2024007440
2024007441
2024007446
2024007447
2024007448
2024007449
2024007450
8 Total Samples
Page 2 of 40
Collected By Sample Description
Asheville Airport
01-Apr-24
2:45 PM
Haley Seaton
ASA_SW-2-A1
Asheville Airport
01-Apr-24
11:40 AM
Connor Zahora
ASA_SW-3-A1
Asheville Airport
01-Apr-24
12:40 PM
Connor Zahora
ASA_SW-4B-A1
Asheville Airport
01-Apr-24
12:30 PM
Connor Zahora
ASA_SW-9-A1
Asheville Airport
01-Apr-24
12:15 PM
Connor Zahora
ASA_SW-10-A1
Asheville Airport
01-Apr-24
11:00 AM
Connor Zahora
ASA_FtB-20240401-1100
Asheville Airport
01-Apr-24
11:05 AM
Connor Zahora
ASA_EB-20240401-1105
Asheville Airport
01-Apr-24
11:10 AM
Connor Zahora
ASA_FB-20240401-1110

Page 3 of 40
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals❑ Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
❑d Job Summary Report
❑d Sample Identification
❑� Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
❑� Analytical Laboratory QC Report
❑ Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑� Chain of Custody
❑� Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 4/17/2024

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030518
Site: ASA SW-2-A1
Collection Date: 04/01/2024 02:45 PM Loc code: ASA SW-2-A1
Sample #: 2024007439
Matrix: GW RCRA
Page 4 of 40
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q24040131
Alkalinity, Bicarbonate
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/08/2024 12:42
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/08/2024 12:42
SNEGLIA
Total Alkalinity as CaCO3
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/08/2024 12:42
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24040046
Chloride
17
mg/L
0.5
0.0154
5
EPA 9056A
04/03/2024 14:38
BGN9034
Fluoride
0.30
mg/L
0.1
0.0479
1
EPA 9056A
04/03/2024 14:38
BGN9034
Sulfate
85
mg/L
1.5
0.0428
15
EPA 9056A
04/03/2024 14:38
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040058
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/04/2024 10:37
SNEGLIA
DISSOLVED MERCURY (COLD VAPOR) IN WATER - Q24040059
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/04/2024 11:57
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED) - Q24040032
Aluminum (AI)
3.89
mg/L
0.01
0.003
1
SW 601 OD
04/03/2024 11:41
CELLI06
Barium (Ba)
0.060
mg/L
0.005
0.002
1
SW 601 OD
04/03/2024 11:41
CELLI06
Boron (B)
0.008 J
mg/L
0.05
0.005
1
SW 601 OD
04/03/2024 11:41
CELLI06
Calcium (Ca)
13.9
mg/L
0.05
0.012
1
SW 601 OD
04/03/2024 11:41
CELLI06
Copper (Cu)
0.006
mg/L
0.005
0.001
1
SW 601 OD
04/03/2024 11:41
CELLI06
Iron (Fe)
0.973
mg/L
0.01
0.004
1
SW 601 OD
04/03/2024 11:41
CELL106
Magnesium (Mg)
10.9
mg/L
0.01
0.008
1
SW 601 OD
04/03/2024 11:41
CELLI06
Manganese (Mn)
0.953
mg/L
0.005
0.001
1
SW 601 OD
04/03/2024 11:41
CELLI06
Potassium (K)
2.03
mg/L
0.1
0.031
1
SW 601 OD
04/03/2024 11:41
CELLI06
Sodium (Na)
7.70
mg/L
0.05
0.017
1
SW 601 OD
04/03/2024 11:41
CELLI06
Strontium (Sr)
0.074
mg/L
0.005
0.001
1
SW 601 OD
04/03/2024 11:41
CELLI06
Zinc (Zn)
0.138
mg/L
0.015
0.004
1
SW 601 OD
04/03/2024 11:41
CELLI06

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030518
Site: ASA SW-2-A1
Collection Date: 04/01/2024 02:45 PM Loc code: ASA SW-2-A1
Analyte
Result
Units Qualifiers
RDL
MDL
TOTAL RECOVERABLE METALS BY ICP - Q24040033
Aluminum (AI)
6.10
mg/L
0.01
0.003
Barium (Ba)
0.060
mg/L
0.005
0.002
Boron (B)
0.008 J
mg/L
0.05
0.005
Calcium (Ca)
13.9
mg/L
0.05
0.012
Copper (Cu)
0.006
mg/L
0.005
0.001
Iron (Fe)
1.04
mg/L
0.01
0.004
Magnesium (Mg)
10.8
mg/L
0.02
0.008
Manganese (Mn)
0.931
mg/L
0.005
0.001
Potassium (K)
2.03
mg/L
0.1
0.031
Sodium (Na)
7.79
mg/L
0.05
0.017
Strontium (Sr)
0.074
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
79.2
mg/L
0.19
(CaCO3)
Zinc (Zn)
0.135
mg/L
0.015
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q24040035
Antimony (Sb)
0.269 J
ug/L
1
0.104
Arsenic (As)
3.38
ug/L
1
0.111
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.184 J
ug/L
1
0.032
Chromium (Cr)
0.595 J
ug/L
1
0.185
Cobalt (Co)
148
ug/L
1
0.077
Lead (Pb)
0.106 J
ug/L
1
0.037
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
Nickel (Ni)
328
ug/L
1
0.256
Selenium (Se)
0.227 J
ug/L
1
0.193
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
Sample #: 2024007439
Matrix: GW RCRA
Page 5 of 40
DF
Method
Analysis Date/Time
Analyst
1
SW 601OD
04/03/2024 12:43
CELL106
1
SW 601OD
04/03/2024 12:43
CELL106
1
SW 601OD
04/03/2024 12:43
CELL106
1
SW 601OD
04/03/2024 12:43
CELL106
1
SW 601OD
04/03/2024 12:43
CELL106
1
SW 601OD
04/03/2024 12:43
CELL106
1
SW 601OD
04/03/2024 12:43
CELL106
1
SW 601OD
04/03/2024 12:43
CELL106
1
SW 601OD
04/03/2024 12:43
CELL106
1
SW 601OD
04/03/2024 12:43
CELL106
1
SW 601OD
04/03/2024 12:43
CELL106
1
SW 6010D
04/03/2024 12:43
CELL106
1
SW 601OD
04/03/2024 12:43
CELL106
1
SW 6020B
04/03/2024 21:01
CELL106
1
SW 6020B
04/03/2024 21:01
CELL106
1
SW 6020E
04/03/2024 21:01
CELL106
1
SW 6020B
04/03/2024 21:01
CELL106
1
SW 6020E
04/03/2024 21:01
CELL106
1
SW 6020B
04/03/2024 21:01
CELL106
1
SW 6020B
04/03/2024 21:01
CELL106
1
SW 6020E
04/03/2024 21:01
CELL106
1
SW 6020B
04/03/2024 21:01
CELL106
1
SW 6020B
04/03/2024 21:01
CELL106
1
SW 6020B
04/03/2024 21:01
CELL106
1
SW 6020B
04/03/2024 21:01
CELL106

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030518
Site: ASA SW-2-A1
Collection Date: 04/01/2024 02:45 PM Loc code: ASA SW-2-A1
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040036
Antimony (Sb)
0.223 J
ug/L
1
0.104
1
Arsenic (As)
3.22
ug/L
1
0.111
1
Beryllium (Be)
0.287 J
ug/L
1
0.249
1
Cadmium (Cd)
0.149 J
ug/L
1
0.032
1
Chromium (Cr)
1.08
ug/L
1
0.185
1
Cobalt (Co)
140
ug/L
1
0.077
1
Lead (Pb)
0.11 J
ug/L
1
0.037
1
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
Nickel (Ni)
309
ug/L
1
0.256
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
TOTAL DISSOLVED SOLIDS - Q24040038
TDS
159
mg/L
25
25
1
TOTAL SUSPENDED SOLIDS - Q24040028
TSS
7
mg/L
5
5
1
Sample #: 2024007439
Matrix: GW RCRA
Page 6 of 40
Method
Analysis Date/Time
Analyst
SW 6020B
04/03/2024 23:32
CELL106
SW 6020B
04/03/2024 23:32
CELL106
SW 6020E
04/03/2024 23:32
CELL106
SW 6020B
04/03/2024 23:32
CELL106
SW 6020B
04/03/2024 23:32
CELL106
SW 6020E
04/03/2024 23:32
CELL106
SW 6020B
04/03/2024 23:32
CELL106
SW 6020E
04/03/2024 23:32
CELL106
SW 6020B
04/03/2024 23:32
CELL106
SW 6020E
04/03/2024 23:32
CELL106
SW 6020B
04/03/2024 23:32
CELL106
SW 6020E
04/03/2024 23:32
CELL106
SM2540C
04/02/202413:16
SNEGLIA
SM2540D
04/02/202410:28
HHOOGKA

Certificate of Laboratory Analysis Page 7 of 40
This report shall not be reproduced, except in full.
Order # J24030518
Site: ASA SW-3-A1
Sample #: 2024007440
Collection Date: 04/01/2024 11:40 AM
Loc code: ASA SW-3-A1
Matrix: GW
RCRA
Analyte Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q24040131
Alkalinity, Bicarbonate 7.93
mg/L
5
1.7
1
SM 2320134d
04/08/2024 12:48
SNEGLIA
Alkalinity, Carbonate 1.7 U
mg/L
5
1.7
1
SM 2320134d
04/08/2024 12:48
SNEGLIA
Total Alkalinity as CaCO3 7.93
mg/L
5
1.7
1
SM 2320134d
04/08/2024 12:48
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24040046
Chloride 16
mg/L
0.5
0.0154
5
EPA 9056A
04/03/2024 15:37
BGN9034
Fluoride 0.11
mg/L
0.1
0.0479
1
EPA 9056A
04/03/2024 15:37
BGN9034
Sulfate 110
mg/L
2
0.0428
20
EPA 9056A
04/03/2024 15:37
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040058
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
DISSOLVED MERCURY (COLD VAPOR) IN WATER - Q24040059
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED) - Q24040032
Aluminum (AI)
0.179
mg/L
0.01
0.003
Barium (Ba)
0.057
mg/L
0.005
0.002
Boron (B)
0.027 J
mg/L
0.05
0.005
Calcium (Ca)
27.4
mg/L
0.05
0.012
Copper (Cu)
0.002 J
mg/L
0.005
0.001
Iron (Fe)
0.573
mg/L
0.01
0.004
Magnesium (Mg)
13.9
mg/L
0.01
0.008
Manganese (Mn)
1.20
mg/L
0.005
0.001
Potassium (K)
3.86
mg/L
0.1
0.031
Sodium (Na)
7.23
mg/L
0.05
0.017
Strontium (Sr)
0.130
mg/L
0.005
0.001
Zinc (Zn)
0.058
mg/L
0.015
0.004
1 EPA 7470A
04/04/2024 10:44
SNEGLIA
1 EPA 7470A
04/04/2024 11:59
SNEGLIA
1 SW 601OD
04/03/2024 11:56
CELL106
1 SW 601OD
04/03/2024 11:56
CELL106
1 SW 601OD
04/03/2024 11:56
CELL106
1 SW 601OD
04/03/2024 11:56
CELL106
1 SW 601OD
04/03/2024 11:56
CELL106
1 SW 601OD
04/03/2024 11:56
CELL106
1 SW 601OD
04/03/2024 11:56
CELL106
1 SW 601OD
04/03/2024 11:56
CELL106
1 SW 601OD
04/03/2024 11:56
CELL106
1 SW 601OD
04/03/2024 11:56
CELL106
1 SW 601OD
04/03/2024 11:56
CELL106
1 SW 601OD
04/03/2024 11:56
CELL106

Certificate of Laboratory Analysis Page 8 of 40
This report shall not be reproduced, except in full.
Order # J24030518
Site: ASA SW-3-A1 Sample #: 2024007440
Collection Date: 04/01/2024 11:40 AM Loc code: ASA SW-3-A1 Matrix: GW RCRA
Analyte
Result
Units Qualifiers
RDL
MDL
TOTAL RECOVERABLE METALS BY ICP - Q24040033
Aluminum (AI)
1.66
mg/L
0.01
0.003
Barium (Ba)
0.060
mg/L
0.005
0.002
Boron (B)
0.032 J
mg/L
0.05
0.005
Calcium (Ca)
28.6
mg/L
0.05
0.012
Copper (Cu)
0.003 J
mg/L
0.005
0.001
Iron (Fe)
0.741
mg/L
0.01
0.004
Magnesium (Mg)
14.4
mg/L
0.02
0.008
Manganese (Mn)
1.24
mg/L
0.005
0.001
Potassium (K)
3.96
mg/L
0.1
0.031
Sodium (Na)
7.43
mg/L
0.05
0.017
Strontium (Sr)
0.135
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
131
mg/L
0.19
(CaCO3)
Zinc (Zn)
0.062
mg/L
0.015
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q24040035
Antimony (Sb)
0.11 J
ug/L
1
0.104
Arsenic (As)
1.43
ug/L
1
0.111
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.092 J
ug/L
1
0.032
Chromium (Cr)
0.185 U
ug/L
1
0.185
Cobalt (Co)
70.2
ug/L
1
0.077
Lead (Pb)
0.061 J
ug/L
1
0.037
Molybdenum (Mo)
0.769 J
ug/L
1
0.18
Nickel (Ni)
198
ug/L
1
0.256
Selenium (Se)
0.287 J
ug/L
1
0.193
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
DF
Method
Analysis Date/Time
Analyst
1
SW 601OD
04/03/2024 12:54
CELL106
1
SW 601OD
04/03/2024 12:54
CELL106
1
SW 601OD
04/03/2024 12:54
CELL106
1
SW 601OD
04/03/2024 12:54
CELL106
1
SW 601OD
04/03/2024 12:54
CELL106
1
SW 601OD
04/03/2024 12:54
CELL106
1
SW 601OD
04/03/2024 12:54
CELL106
1
SW 601OD
04/03/2024 12:54
CELL106
1
SW 601OD
04/03/2024 12:54
CELL106
1
SW 601OD
04/03/2024 12:54
CELL106
1
SW 601OD
04/03/2024 12:54
CELL106
1
SW 6010D
04/03/2024 12:54
CELL106
1
SW 601OD
04/03/2024 12:54
CELL106
1
SW 6020B
04/03/2024 20:11
CELL106
1
SW 6020B
04/03/2024 20:11
CELL106
1
SW 6020E
04/03/2024 20:11
CELL106
1
SW 6020B
04/03/2024 20:11
CELL106
1
SW 6020E
04/03/2024 20:11
CELL106
1
SW 6020B
04/03/2024 20:11
CELL106
1
SW 6020B
04/03/2024 20:11
CELL106
1
SW 6020E
04/03/2024 20:11
CELL106
1
SW 6020B
04/03/2024 20:11
CELL106
1
SW 6020B
04/03/2024 20:11
CELL106
1
SW 6020B
04/03/2024 20:11
CELL106
1
SW 6020B
04/03/2024 20:11
CELL106

Certificate of Laboratory Analysis Page 9 of 40
This report shall not be reproduced, except in full.
Order # J24030518
Site: ASA SW-3-A1
Sample #:
2024007440
Collection Date: 04/01/2024 11:40 AM
Loc code: ASA SW-3-A1
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040036
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
04/03/2024 22:50
CELL106
Arsenic (As)
1.59
ug/L
1
0.111
1
SW 6020B
04/03/2024 22:50
CELL106
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020E
04/03/2024 22:50
CELL106
Cadmium (Cd)
0.087 J
ug/L
1
0.032
1
SW 6020B
04/03/2024 22:50
CELL106
Chromium (Cr)
0.355 J
ug/L
1
0.185
1
SW 6020B
04/03/2024 22:50
CELL106
Cobalt (Co)
68.6
ug/L
1
0.077
1
SW 6020E
04/03/2024 22:50
CELL106
Lead (Pb)
0.616 J
ug/L
1
0.037
1
SW 6020B
04/03/2024 22:50
CELL106
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020E
04/03/2024 22:50
CELL106
Nickel (Ni)
193
ug/L
1
0.256
1
SW 6020B
04/03/2024 22:50
CELL106
Selenium (Se)
0.314 J
ug/L
1
0.193
1
SW 6020E
04/03/2024 22:50
CELL106
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
04/03/2024 22:50
CELL106
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
SW 6020E
04/03/2024 22:50
CELL106
TOTAL DISSOLVED SOLIDS - Q24040038
TDS
212
mg/L
25
25
1
SM2540C
04/02/202413:16
SNEGLIA
TOTAL SUSPENDED SOLIDS - Q24040028
TSS
6
mg/L
5
5
1
SM2540D
04/02/202410:28
HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030518
Site: ASA SW-4B-A1
Collection Date: 04/01/2024 12:40 PM Loc code: ASA SW-4B-A1
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL ALKALINITY - Q24040074
Total Alkalinity as CaCO3
28.3
mg/L
5
1.7
1
(CaCO3)
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
Alkalinity, Bicarbonate
28.3
mg/L
5
1.7
1
INORGANIC IONS BY IC - Q24040046
Chloride
9.1
mg/L
0.1
0.0154
1
Fluoride
0.06 J
mg/L
0.1
0.0479
1
Sulfate
38
mg/L
0.5
0.0428
5
MERCURY (COLD VAPOR) IN WATER - Q24040058
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
DISSOLVED MERCURY (COLD VAPOR) IN WATER - Q24040059
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED) - Q24040032
Aluminum (AI)
0.082
mg/L
0.01
0.003
1
Barium (Ba)
0.042
mg/L
0.005
0.002
1
Boron (B)
0.100
mg/L
0.05
0.005
1
Calcium (Ca)
16.8
mg/L
0.05
0.012
1
Copper (Cu)
0.002 J
mg/L
0.005
0.001
1
Iron (Fe)
0.649
mg/L
0.01
0.004
1
Magnesium (Mg)
7.07
mg/L
0.01
0.008
1
Manganese (Mn)
0.687
mg/L
0.005
0.001
1
Potassium (K)
2.18
mg/L
0.1
0.031
1
Sodium (Na)
4.82
mg/L
0.05
0.017
1
Strontium (Sr)
0.100
mg/L
0.005
0.001
1
Zinc (Zn)
0.026
mg/L
0.015
0.004
1
Sample #: 2024007441
Matrix: GW RCRA
Page 10 of 40
Method Analysis Date/Time Analyst
SM 2320B-2011
04/04/2024 07:25
SNEGLIA
SM 2320B-2011
04/04/2024 07:25
SNEGLIA
SM 2320B-2011
04/04/2024 07:25
SNEGLIA
EPA 9056A
04/03/2024 15:57
BGN9034
EPA 9056A
04/03/2024 15:57
BGN9034
EPA 9056A
04/03/2024 15:57
BGN9034
EPA 7470A
04/04/2024 10:46
SNEGLIA
EPA 7470A
04/04/2024 11:50
SNEGLIA
SW 601OD
04/03/2024 12:00
CELL106
SW 601OD
04/03/2024 12:00
CELL106
SW 601OD
04/03/2024 12:00
CELL106
SW 601OD
04/03/2024 12:00
CELL106
SW 601OD
04/03/2024 12:00
CELL106
SW 601OD
04/03/2024 12:00
CELL106
SW 601OD
04/03/2024 12:00
CELL106
SW 601OD
04/03/2024 12:00
CELL106
SW 601OD
04/03/2024 12:00
CELL106
SW 601OD
04/03/2024 12:00
CELL106
SW 601OD
04/03/2024 12:00
CELL106
SW 601OD
04/03/2024 12:00
CELL106

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030518
Site: ASA SW-4B-A1
Collection Date: 04/01/2024 12:40 PM Loc code: ASA SW-4B-A1
Analyte
Result
Units Qualifiers
RDL
MDL
TOTAL RECOVERABLE METALS BY ICP - Q24040033
Aluminum (AI)
1.70
mg/L
0.01
0.003
Barium (Ba)
0.050
mg/L
0.005
0.002
Boron (B)
0.071
mg/L
0.05
0.005
Calcium (Ca)
20.7
mg/L
0.05
0.012
Copper (Cu)
0.003 J
mg/L
0.005
0.001
Iron (Fe)
1.59
mg/L
0.01
0.004
Magnesium (Mg)
8.75
mg/L
0.02
0.008
Manganese (Mn)
0.921
mg/L
0.005
0.001
Potassium (K)
2.75
mg/L
0.1
0.031
Sodium (Na)
5.88
mg/L
0.05
0.017
Strontium (Sr)
0.104
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
87.7
mg/L
0.19
(CaCO3)
Zinc (Zn)
0.039
mg/L
0.015
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q24040035
Antimony (Sb)
0.123 J
ug/L
1
0.104
Arsenic (As)
0.553 J
ug/L
1
0.111
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.037 J
ug/L
1
0.032
Chromium (Cr)
0.185 U
ug/L
1
0.185
Cobalt (Co)
25.9
ug/L
1
0.077
Lead (Pb)
0.057 J
ug/L
1
0.037
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
Nickel (Ni)
65.2
ug/L
1
0.256
Selenium (Se)
1.28
ug/L
1
0.193
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
Sample #: 2024007441
Matrix: GW RCRA
Page 11 of 40
DF
Method
Analysis Date/Time
Analyst
1
SW 601OD
04/03/2024 12:58
CELL106
1
SW 601OD
04/03/2024 12:58
CELL106
1
SW 601OD
04/03/2024 12:58
CELL106
1
SW 601OD
04/03/2024 12:58
CELL106
1
SW 601OD
04/03/2024 12:58
CELL106
1
SW 601OD
04/03/2024 12:58
CELL106
1
SW 601OD
04/03/2024 12:58
CELL106
1
SW 601OD
04/03/2024 12:58
CELL106
1
SW 601OD
04/03/2024 12:58
CELL106
1
SW 601OD
04/03/2024 12:58
CELL106
1
SW 601OD
04/03/2024 12:58
CELL106
1
SW 6010D
04/03/2024 12:58
CELL106
1
SW 601OD
04/03/2024 12:58
CELL106
1
SW 6020B
04/03/2024 21:10
CELL106
1
SW 6020B
04/03/2024 21:10
CELL106
1
SW 6020E
04/03/2024 21:10
CELL106
1
SW 6020B
04/03/2024 21:10
CELL106
1
SW 6020E
04/03/2024 21:10
CELL106
1
SW 6020B
04/03/2024 21:10
CELL106
1
SW 6020B
04/03/2024 21:10
CELL106
1
SW 6020E
04/03/2024 21:10
CELL106
1
SW 6020B
04/03/2024 21:10
CELL106
1
SW 6020B
04/03/2024 21:10
CELL106
1
SW 6020B
04/03/2024 21:10
CELL106
1
SW 6020B
04/03/2024 21:10
CELL106

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030518
Site: ASA SW-4B-A1
Collection Date: 04/01/2024 12:40 PM Loc code: ASA SW-4B-A1
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040036
Antimony (Sb)
0.114 J
ug/L
1
0.104
1
Arsenic (As)
1.17
ug/L
1
0.111
1
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
Cadmium (Cd)
0.069 J
ug/L
1
0.032
1
Chromium (Cr)
0.373 J
ug/L
1
0.185
1
Cobalt (Co)
39.7
ug/L
1
0.077
1
Lead (Pb)
0.101 J
ug/L
1
0.037
1
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
Nickel (Ni)
99.9
ug/L
1
0.256
1
Selenium (Se)
0.647 J
ug/L
1
0.193
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
Vanadium (V) Low Level
0.125 J
ug/L
0.3
0.114
1
TOTAL DISSOLVED SOLIDS - Q24040038
TDS
145
mg/L
25
25
1
TOTAL SUSPENDED SOLIDS - Q24040028
TSS
10
mg/L
5
5
1
Sample #: 2024007441
Matrix: GW RCRA
Page 12 of 40
Method
Analysis Date/Time
Analyst
SW 6020B
04/03/2024 23:41
CELL106
SW 6020B
04/03/2024 23:41
CELL106
SW 6020E
04/03/2024 23:41
CELL106
SW 6020B
04/03/2024 23:41
CELL106
SW 6020B
04/03/2024 23:41
CELL106
SW 6020E
04/03/2024 23:41
CELL106
SW 6020B
04/03/2024 23:41
CELL106
SW 6020E
04/03/2024 23:41
CELL106
SW 6020B
04/03/2024 23:41
CELL106
SW 6020E
04/03/2024 23:41
CELL106
SW 6020B
04/03/2024 23:41
CELL106
SW 6020E
04/03/2024 23:41
CELL106
SM2540C
04/02/202413:16
SNEGLIA
SM2540D
04/02/202410:28
HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030518
Site: ASA SW-9-A1
Collection Date: 04/01/2024 12:30 PM Loc code: ASA SW-9-A1
Sample #: 2024007446
Matrix: GW RCRA
Page 13 of 40
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q24040131
Alkalinity, Bicarbonate
12.6
mg/L
5
1.7
1
SM 2320134d
04/08/2024 12:54
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/08/2024 12:54
SNEGLIA
Total Alkalinity as CaCO3
12.6
mg/L
5
1.7
1
SM 2320134d
04/08/2024 12:54
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24040046
Chloride
17
mg/L
0.5
0.0154
5
EPA 9056A
04/03/2024 16:16
BGN9034
Fluoride
0.08 J
mg/L
0.1
0.0479
1
EPA 9056A
04/03/2024 16:16
BGN9034
Sulfate
86
mg/L
2
0.0428
20
EPA 9056A
04/03/2024 16:16
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040058
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/04/2024 10:48
SNEGLIA
DISSOLVED MERCURY (COLD VAPOR) IN WATER - Q24040059
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/04/2024 12:01
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED) - Q24040032
Aluminum (AI)
0.163
mg/L
0.01
0.003
1
SW 601 OD
04/03/2024 12:04
CELLI06
Barium (Ba)
0.057
mg/L
0.005
0.002
1
SW 601 OD
04/03/2024 12:04
CELLI06
Boron (B)
0.029 J
mg/L
0.05
0.005
1
SW 601 OD
04/03/2024 12:04
CELLI06
Calcium (Ca)
26.2
mg/L
0.05
0.012
1
SW 601 OD
04/03/2024 12:04
CELLI06
Copper (Cu)
0.003 J
mg/L
0.005
0.001
1
SW 601 OD
04/03/2024 12:04
CELLI06
Iron (Fe)
0.594
mg/L
0.01
0.004
1
SW 601 OD
04/03/2024 12:04
CELL106
Magnesium (Mg)
11.6
mg/L
0.01
0.008
1
SW 601 OD
04/03/2024 12:04
CELLI06
Manganese (Mn)
1.20
mg/L
0.005
0.001
1
SW 601 OD
04/03/2024 12:04
CELLI06
Potassium (K)
3.62
mg/L
0.1
0.031
1
SW 601 OD
04/03/2024 12:04
CELLI06
Sodium (Na)
7.24
mg/L
0.05
0.017
1
SW 601 OD
04/03/2024 12:04
CELLI06
Strontium (Sr)
0.113
mg/L
0.005
0.001
1
SW 601 OD
04/03/2024 12:04
CELLI06
Zinc (Zn)
0.056
mg/L
0.015
0.004
1
SW 601 OD
04/03/2024 12:04
CELLI06

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030518
Site: ASA SW-9-A1
Collection Date: 04/01/2024 12:30 PM Loc code: ASA SW-9-A1
Analyte
Result
Units Qualifiers
RDL
MDL
TOTAL RECOVERABLE METALS BY ICP - Q24040033
Aluminum (AI)
2.31
mg/L
0.01
0.003
Barium (Ba)
0.059
mg/L
0.005
0.002
Boron (B)
0.032 J
mg/L
0.05
0.005
Calcium (Ca)
26.2
mg/L
0.05
0.012
Copper (Cu)
0.004 J
mg/L
0.005
0.001
Iron (Fe)
0.955
mg/L
0.01
0.004
Magnesium (Mg)
10.9
mg/L
0.02
0.008
Manganese (Mn)
1.19
mg/L
0.005
0.001
Potassium (K)
3.52
mg/L
0.1
0.031
Sodium (Na)
7.19
mg/L
0.05
0.017
Strontium (Sr)
0.110
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
110
mg/L
0.19
(CaCO3)
Zinc (Zn)
0.055
mg/L
0.015
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q24040035
Antimony (Sb)
0.159 J
ug/L
1
0.104
Arsenic (As)
1.31
ug/L
1
0.111
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.075 J
ug/L
1
0.032
Chromium (Cr)
0.185 U
ug/L
1
0.185
Cobalt (Co)
64.0
ug/L
1
0.077
Lead (Pb)
0.056 J
ug/L
1
0.037
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
Nickel (Ni)
167
ug/L
1
0.256
Selenium (Se)
0.264 J
ug/L
1
0.193
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
Sample #: 2024007446
Matrix: GW RCRA
Page 14 of 40
DF
Method
Analysis Date/Time
Analyst
1
SW 601OD
04/03/2024 13:02
CELL106
1
SW 601OD
04/03/2024 13:02
CELL106
1
SW 601OD
04/03/2024 13:02
CELL106
1
SW 601OD
04/03/2024 13:02
CELL106
1
SW 601OD
04/03/2024 13:02
CELL106
1
SW 601OD
04/03/2024 13:02
CELL106
1
SW 601OD
04/03/2024 13:02
CELL106
1
SW 601OD
04/03/2024 13:02
CELL106
1
SW 601OD
04/03/2024 13:02
CELL106
1
SW 601OD
04/03/2024 13:02
CELL106
1
SW 601OD
04/03/2024 13:02
CELL106
1
SW 6010D
04/03/2024 13:02
CELL106
1
SW 601OD
04/03/2024 13:02
CELL106
1
SW 6020B
04/03/2024 21:18
CELL106
1
SW 6020B
04/03/2024 21:18
CELL106
1
SW 6020E
04/03/2024 21:18
CELL106
1
SW 6020B
04/03/2024 21:18
CELL106
1
SW 6020E
04/03/2024 21:18
CELL106
1
SW 6020B
04/03/2024 21:18
CELL106
1
SW 6020B
04/03/2024 21:18
CELL106
1
SW 6020E
04/03/2024 21:18
CELL106
1
SW 6020B
04/03/2024 21:18
CELL106
1
SW 6020B
04/03/2024 21:18
CELL106
1
SW 6020B
04/03/2024 21:18
CELL106
1
SW 6020B
04/03/2024 21:18
CELL106

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030518
Site: ASA SW-9-A1
Collection Date: 04/01/2024 12:30 PM Loc code: ASA SW-9-A1
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040036
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
Arsenic (As)
1.55
ug/L
1
0.111
1
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
Cadmium (Cd)
0.082 J
ug/L
1
0.032
1
Chromium (Cr)
0.538 J
ug/L
1
0.185
1
Cobalt (Co)
58.2
ug/L
1
0.077
1
Lead (Pb)
0.162 J
ug/L
1
0.037
1
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
Nickel (Ni)
149
ug/L
1
0.256
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
Vanadium (V) Low Level
0.204 J
ug/L
0.3
0.114
1
TOTAL DISSOLVED SOLIDS - Q24040038
TDS
192
mg/L
25
25
1
TOTAL SUSPENDED SOLIDS - Q24040028
TSS
14
mg/L
5
5
1
Sample #: 2024007446
Matrix: GW RCRA
Page 15 of 40
Method
Analysis Date/Time
Analyst
SW 6020B
04/03/2024 23:49
CELL106
SW 6020B
04/03/2024 23:49
CELL106
SW 6020E
04/03/2024 23:49
CELL106
SW 6020B
04/03/2024 23:49
CELL106
SW 6020B
04/03/2024 23:49
CELL106
SW 6020E
04/03/2024 23:49
CELL106
SW 6020B
04/03/2024 23:49
CELL106
SW 6020E
04/03/2024 23:49
CELL106
SW 6020B
04/03/2024 23:49
CELL106
SW 6020E
04/03/2024 23:49
CELL106
SW 6020B
04/03/2024 23:49
CELL106
SW 6020E
04/03/2024 23:49
CELL106
SM2540C
04/02/202413:16
SNEGLIA
SM2540D
04/02/202410:28
HHOOGKA

Certificate of Laboratory Analysis Page 16of40
This report shall not be reproduced, except in full.
Order # J24030518
Site: ASA SW-10-A1 Sample #: 2024007447
Collection Date: 04/01/2024 12:15 PM Loc code: ASA SW-10-Al Matrix: GW RCRA
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL ALKALINITY - Q24040074
Total Alkalinity as CaCO3
25.4
mg/L
5
1.7
1
(CaCO3)
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
Alkalinity, Bicarbonate
25.4
mg/L
5
1.7
1
INORGANIC IONS BY IC - Q24040046
Chloride
11
mg/L
0.5
0.0154
5
Fluoride
0.06 J
mg/L
0.1
0.0479
1
Sulfate
44
mg/L
0.5
0.0428
5
MERCURY (COLD VAPOR) IN WATER - Q24040058
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
DISSOLVED MERCURY (COLD VAPOR) IN WATER - Q24040059
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED) - Q24040032
Aluminum (AI)
0.023
mg/L
0.01
0.003
1
Barium (Ba)
0.034
mg/L
0.005
0.002
1
Boron (B)
0.144
mg/L
0.05
0.005
1
Calcium (Ca)
11.1
mg/L
0.05
0.012
1
Copper (Cu)
0.001 J
mg/L
0.005
0.001
1
Iron (Fe)
0.443
mg/L
0.01
0.004
1
Magnesium (Mg)
4.48
mg/L
0.01
0.008
1
Manganese (Mn)
0.227
mg/L
0.005
0.001
1
Potassium (K)
1.35
mg/L
0.1
0.031
1
Sodium (Na)
3.40
mg/L
0.05
0.017
1
Strontium (Sr)
0.101
mg/L
0.005
0.001
1
Zinc (Zn)
0.006 J
mg/L
0.015
0.004
1
Method Analysis Date/Time Analyst
SM 2320B-2011
04/04/2024 07:32
SNEGLIA
SM 2320B-2011
04/04/2024 07:32
SNEGLIA
SM 2320B-2011
04/04/2024 07:32
SNEGLIA
EPA 9056A
04/03/2024 16:36
BGN9034
EPA 9056A
04/03/2024 16:36
BGN9034
EPA 9056A
04/03/2024 16:36
BGN9034
EPA 7470A
04/04/2024 10:50
SNEGLIA
EPA 7470A 04/04/2024 12:03 SNEGLIA
SW 601OD
04/03/2024 12:08
CELL106
SW 601OD
04/03/2024 12:08
CELL106
SW 601OD
04/03/2024 12:08
CELL106
SW 601OD
04/03/2024 12:08
CELL106
SW 601OD
04/03/2024 12:08
CELL106
SW 601OD
04/03/2024 12:08
CELL106
SW 601OD
04/03/2024 12:08
CELL106
SW 601OD
04/03/2024 12:08
CELL106
SW 601OD
04/03/2024 12:08
CELL106
SW 601OD
04/03/2024 12:08
CELL106
SW 601OD
04/03/2024 12:08
CELL106
SW 601OD
04/03/2024 12:08
CELL106

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030518
Site: ASA SW-10-A1
Collection Date: 04/01/2024 12:15 PM Loc code: ASA SW-10-Al
Analyte
Result
Units Qualifiers
RDL
MDL
TOTAL RECOVERABLE METALS BY ICP - Q24040033
Aluminum (AI)
0.187
mg/L
0.01
0.003
Barium (Ba)
0.035
mg/L
0.005
0.002
Boron (B)
0.139
mg/L
0.05
0.005
Calcium (Ca)
11.7
mg/L
0.05
0.012
Copper (Cu)
0.001 J
mg/L
0.005
0.001
Iron (Fe)
0.827
mg/L
0.01
0.004
Magnesium (Mg)
4.73
mg/L
0.02
0.008
Manganese (Mn)
0.261
mg/L
0.005
0.001
Potassium (K)
1.40
mg/L
0.1
0.031
Sodium (Na)
3.55
mg/L
0.05
0.017
Strontium (Sr)
0.102
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
48.7
mg/L
0.19
(CaCO3)
Zinc (Zn)
0.008 J
mg/L
0.015
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q24040035
Antimony (Sb)
0.104 U
ug/L
1
0.104
Arsenic (As)
0.126 J
ug/L
1
0.111
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.032 U
ug/L
1
0.032
Chromium (Cr)
0.265 J
ug/L
1
0.185
Cobalt (Co)
1.95
ug/L
1
0.077
Lead (Pb)
0.037 U
ug/L
1
0.037
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
Nickel (Ni)
4.34
ug/L
1
0.256
Selenium (Se)
2.56
ug/L
1
0.193
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
Sample #: 2024007447
Matrix: GW RCRA
Page 17 of 40
DF
Method
Analysis Date/Time
Analyst
1
SW 601OD
04/03/2024 13:06
CELL106
1
SW 601OD
04/03/2024 13:06
CELL106
1
SW 601OD
04/03/2024 13:06
CELL106
1
SW 601OD
04/03/2024 13:06
CELL106
1
SW 601OD
04/03/2024 13:06
CELL106
1
SW 601OD
04/03/2024 13:06
CELL106
1
SW 601OD
04/03/2024 13:06
CELL106
1
SW 601OD
04/03/2024 13:06
CELL106
1
SW 601OD
04/03/2024 13:06
CELL106
1
SW 601OD
04/03/2024 13:06
CELL106
1
SW 601OD
04/03/2024 13:06
CELL106
1
SW 6010D
04/03/2024 13:06
CELL106
1
SW 601OD
04/03/2024 13:06
CELL106
1
SW 6020B
04/03/2024 21:26
CELL106
1
SW 6020B
04/03/2024 21:26
CELL106
1
SW 6020E
04/03/2024 21:26
CELL106
1
SW 6020B
04/03/2024 21:26
CELL106
1
SW 6020E
04/03/2024 21:26
CELL106
1
SW 6020B
04/03/2024 21:26
CELL106
1
SW 6020B
04/03/2024 21:26
CELL106
1
SW 6020E
04/03/2024 21:26
CELL106
1
SW 6020B
04/03/2024 21:26
CELL106
1
SW 6020B
04/03/2024 21:26
CELL106
1
SW 6020B
04/03/2024 21:26
CELL106
1
SW 6020B
04/03/2024 21:26
CELL106

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030518
Site: ASA SW-10-A1
Collection Date: 04/01/2024 12:15 PM Loc code: ASA SW-10-Al
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040036
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
Arsenic (As)
0.141 J
ug/L
1
0.111
1
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.297 J
ug/L
1
0.185
1
Cobalt (Co)
3.57
ug/L
1
0.077
1
Lead (Pb)
0.037 U
ug/L
1
0.037
1
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
Nickel (Ni)
8.25
ug/L
1
0.256
1
Selenium (Se)
2.36
ug/L
1
0.193
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
TOTAL DISSOLVED SOLIDS - Q24040038
TDS
68.0
mg/L
25
25
1
TOTAL SUSPENDED SOLIDS - Q24040028
TSS
5 U
mg/L
5
5
1
Sample #: 2024007447
Matrix: GW RCRA
Page 18 of 40
Method
Analysis Date/Time
Analyst
SW 6020B
04/03/2024 23:57
CELL106
SW 6020B
04/03/2024 23:57
CELL106
SW 6020E
04/03/2024 23:57
CELL106
SW 6020B
04/03/2024 23:57
CELL106
SW 6020B
04/03/2024 23:57
CELL106
SW 6020E
04/03/2024 23:57
CELL106
SW 6020B
04/03/2024 23:57
CELL106
SW 6020E
04/03/2024 23:57
CELL106
SW 6020B
04/03/2024 23:57
CELL106
SW 6020E
04/03/2024 23:57
CELL106
SW 6020B
04/03/2024 23:57
CELL106
SW 6020E
04/03/2024 23:57
CELL106
SM2540C
04/02/202413:16
SNEGLIA
SM2540D
04/02/202410:28
HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030518
Site: ASA FtB-20240401-1100 Filter Blank
Collection Date: 04/01/2024 11:00 AM Loc code: ASA FtB
Analyte Result Units Qualifiers RDL
DISSOLVED MERCURY (COLD VAPOR) IN WATER - Q24040059
Mercury (Hg) 0.01 U ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED) - Q24040032
MDL
0.01
Aluminum (AI)
0.003 U
mg/L
0.01
0.003
Barium (Ba)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.005 U
mg/L
0.05
0.005
Calcium (Ca)
0.014 J
mg/L
0.05
0.012
Copper (Cu)
0.002 J
mg/L
0.005
0.001
Iron (Fe)
0.004 U
mg/L
0.01
0.004
Magnesium (Mg)
0.008 U
mg/L
0.01
0.008
Manganese (Mn)
0.001 U
mg/L
0.005
0.001
Potassium (K)
0.031 U
mg/L
0.1
0.031
Sodium (Na)
0.017 U
mg/L
0.05
0.017
Strontium (Sr)
0.001 U
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.015
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q24040035
Antimony (Sb)
0.104 U
ug/L
1
0.104
Arsenic (As)
0.111 U
ug/L
1
0.111
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.032 U
ug/L
1
0.032
Chromium (Cr)
0.185 U
ug/L
1
0.185
Cobalt (Co)
0.077 U
ug/L
1
0.077
Lead (Pb)
0.037 U
ug/L
1
0.037
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
Nickel (Ni)
0.256 U
ug/L
1
0.256
Selenium (Se)
0.193 U
ug/L
1
0.193
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
Sample #: 2024007448
Matrix: GW RCRA
Page 19 of 40
DF
Method
Analysis Date/Time
Analyst
1
EPA 7470A
04/04/2024 12:06
SNEGLIA
1
SW 601OD
04/03/2024 12:12
CELL106
1
SW 601OD
04/03/2024 12:12
CELL106
1
SW 601OD
04/03/2024 12:12
CELL106
1
SW 601OD
04/03/2024 12:12
CELL106
1
SW 601OD
04/03/2024 12:12
CELL106
1
SW 601OD
04/03/2024 12:12
CELL106
1
SW 601OD
04/03/2024 12:12
CELL106
1
SW 601OD
04/03/2024 12:12
CELL106
1
SW 601OD
04/03/2024 12:12
CELL106
1
SW 601OD
04/03/2024 12:12
CELL106
1
SW 601OD
04/03/2024 12:12
CELL106
1
SW 601OD
04/03/2024 12:12
CELL106
1
SW 6020B
04/03/2024 21:35
CELL106
1
SW 6020B
04/03/2024 21:35
CELL106
1
SW 6020E
04/03/2024 21:35
CELL106
1
SW 6020B
04/03/2024 21:35
CELL106
1
SW 6020E
04/03/2024 21:35
CELL106
1
SW 6020E
04/03/2024 21:35
CELL106
1
SW 6020B
04/03/2024 21:35
CELL106
1
SW 6020E
04/03/2024 21:35
CELL106
1
SW 6020B
04/03/2024 21:35
CELL106
1
SW 6020B
04/03/2024 21:35
CELL106
1
SW 6020B
04/03/2024 21:35
CELL106
1
SW 6020E
04/03/2024 21:35
CELL106

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030518
Site: ASA EB-20240401-1105 Equipment Blank
Collection Date: 04/01/2024 11:05 AM Loc code: ASA EB
Sample #: 2024007449
Matrix: GW RCRA
Page 20 of 40
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q24040131
Alkalinity, Bicarbonate
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/08/2024 13:02
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/08/2024 13:02
SNEGLIA
Total Alkalinity as CaCO3
1.7 U
mg/L
5
1.7
1
SM 2320134d
04/08/2024 13:02
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24040046
Chloride
0.07 J
mg/L
0.1
0.0154
1
EPA 9056A
04/03/2024 12:22
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
04/03/2024 12:22
BGN9034
Sulfate
0.0428 U
mg/L
0.1
0.0428
1
EPA 9056A
04/03/2024 12:22
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040058
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/04/2024 10:53
SNEGLIA
DISSOLVED MERCURY (COLD VAPOR) IN WATER - Q24040059
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/04/2024 12:08
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED) - Q24040032
Aluminum (AI)
0.006 J
mg/L
0.01
0.003
1
SW 6010D
04/03/2024 12:16
CELLI06
Barium (Ba)
0.002 U
mg/L
0.005
0.002
1
SW 6010D
04/03/2024 12:16
CELLI06
Boron (B)
0.005 U
mg/L
0.05
0.005
1
SW 601 OD
04/03/2024 12:16
CELLI06
Calcium (Ca)
0.023 J
mg/L
0.05
0.012
1
SW 6010D
04/03/2024 12:16
CELLI06
Copper (Cu)
0.001 J
mg/L
0.005
0.001
1
SW 601 OD
04/03/2024 12:16
CELLI06
Iron (Fe)
0.004 U
mg/L
0.01
0.004
1
SW 6010D
04/03/2024 12:16
CELL106
Magnesium (Mg)
0.008 U
mg/L
0.01
0.008
1
SW 6010D
04/03/2024 12:16
CELLI06
Manganese (Mn)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
04/03/2024 12:16
CELLI06
Potassium (K)
0.031 U
mg/L
0.1
0.031
1
SW 601 OD
04/03/2024 12:16
CELLI06
Sodium (Na)
0.017 U
mg/L
0.05
0.017
1
SW 6010D
04/03/2024 12:16
CELLI06
Strontium (Sr)
0.001 U
mg/L
0.005
0.001
1
SW 601 OD
04/03/2024 12:16
CELLI06

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030518
Site: ASA EB-20240401-1105 Equipment Blank
Collection Date: 04/01/2024 11:05 AM Loc code: ASA EB
Analyte
Result
Units Qualifiers
RDL
MDL
TOTAL RECOVERABLE METALS BY ICP - Q24040033
Aluminum (AI)
0.005 J
mg/L
0.01
0.003
Barium (Ba)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.005 U
mg/L
0.05
0.005
Calcium (Ca)
0.018 J
mg/L
0.05
0.012
Copper (Cu)
0.001 J
mg/L
0.005
0.001
Iron (Fe)
0.004 U
mg/L
0.01
0.004
Magnesium (Mg)
0.008 U
mg/L
0.02
0.008
Manganese (Mn)
0.001 U
mg/L
0.005
0.001
Potassium (K)
0.031 U
mg/L
0.1
0.031
Sodium (Na)
0.017 U
mg/L
0.05
0.017
Strontium (Sr)
0.001 U
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
< 0.190
mg/L
0.19
(CaCO3)
Zinc (Zn)
0.004 U
mg/L
0.015
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q24040035
Antimony (Sb)
0.104 U
ug/L
1
0.104
Arsenic (As)
0.111 U
ug/L
1
0.111
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.032 U
ug/L
1
0.032
Chromium (Cr)
0.185 U
ug/L
1
0.185
Cobalt (Co)
0.077 U
ug/L
1
0.077
Lead (Pb)
0.037 U
ug/L
1
0.037
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
Nickel (Ni)
0.256 U
ug/L
1
0.256
Selenium (Se)
0.193 U
ug/L
1
0.193
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
Sample #: 2024007449
Matrix: GW RCRA
Page 21 of 40
DF
Method
Analysis Date/Time
Analyst
1
SW 6010D
04/03/2024 13:10
CELL106
1
SW 601OD
04/03/2024 13:10
CELL106
1
SW 6010D
04/03/2024 13:10
CELL106
1
SW 601OD
04/03/2024 13:10
CELL106
1
SW 601OD
04/03/2024 13:10
CELL106
1
SW 6010D
04/03/2024 13:10
CELL106
1
SW 6010D
04/03/2024 13:10
CELL106
1
SW 601OD
04/03/2024 13:10
CELL106
1
SW 6010D
04/03/2024 13:10
CELL106
1
SW 601OD
04/03/2024 13:10
CELL106
1
SW 601OD
04/03/2024 13:10
CELL106
1
SW 6010D
04/03/2024 13:10
CELL106
1
SW 6010D
04/03/2024 13:10
CELL106
1
SW 6020B
04/03/2024 21:43
CELL106
1
SW 6020B
04/03/2024 21:43
CELL106
1
SW 6020E
04/03/2024 21:43
CELL106
1
SW 6020B
04/03/2024 21:43
CELL106
1
SW 6020E
04/03/2024 21:43
CELL106
1
SW 6020B
04/03/2024 21:43
CELL106
1
SW 6020B
04/03/2024 21:43
CELL106
1
SW 6020E
04/03/2024 21:43
CELL106
1
SW 6020B
04/03/2024 21:43
CELL106
1
SW 6020B
04/03/2024 21:43
CELL106
1
SW 6020B
04/03/2024 21:43
CELL106
1
SW 6020B
04/03/2024 21:43
CELL106

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030518
Site: ASA EB-20240401-1105 Equipment Blank
Collection Date: 04/01/2024 11:05 AM Loc code: ASA EB
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040036
Antimony (Sb)
0.113 J
ug/L
1
0.104
1
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
Cobalt (Co)
0.077 U
ug/L
1
0.077
1
Lead (Pb)
0.037 U
ug/L
1
0.037
1
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
Sample #: 2024007449
Matrix: GW RCRA
Page 22 of 40
Method
Analysis Date/Time
Analyst
SW 6020B
04/04/2024 00:06
CELL106
SW 6020B
04/04/2024 00:06
CELL106
SW 6020E
04/04/2024 00:06
CELL106
SW 6020B
04/04/2024 00:06
CELL106
SW 6020B
04/04/2024 00:06
CELL106
SW 6020E
04/04/2024 00:06
CELL106
SW 6020B
04/04/2024 00:06
CELL106
SW 6020E
04/04/2024 00:06
CELL106
SW 6020B
04/04/2024 00:06
CELL106
SW 6020E
04/04/2024 00:06
CELL106
SW 6020B
04/04/2024 00:06
CELL106
SW 6020E
04/04/2024 00:06
CELL106

Certificate of Laboratory Analysis Page 23 of 40
This report shall not be reproduced, except in full.
Order # J24030518
Site: ASA FB-20240401-1110 Field Blank Sample #: 2024007450
Collection Date: 04/01/2024 11:10 AM Loc code: ASA FB Matrix: GW RCRA
Analyte Result Units Qualifiers RDL
LOW LEVEL ALKALINITY (FIXED END POINT) - Q24040131
Alkalinity, Bicarbonate 1.7 U mg/L 5
Alkalinity, Carbonate 1.7 U mg/L 5
Total Alkalinity as CaCO3 1.7 U mg/L 5
(CaCO3)
INORGANIC IONS BY IC - Q24040046
Chloride 0.03 J mg/L
Fluoride 0.0479 U mg/L
Sulfate 0.0428 U mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040058
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040033
Aluminum (AI)
0.004 J
mg/L
Barium (Ba)
0.002 U
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
0.012 U
mg/L
Copper (Cu)
0.001 U
mg/L
Iron (Fe)
0.010
mg/L
Magnesium (Mg)
0.008 U
mg/L
Manganese (Mn)
0.001 U
mg/L
Potassium (K)
0.031 U
mg/L
Sodium (Na)
0.017 U
mg/L
Strontium (Sr)
0.001 U
mg/L
Total Hardness (Ca and Mg)
< 0.190
mg/L
(CaCO3)
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS - Q24040036
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.185 U
ug/L
Cobalt (Co)
0.077 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.256 U
ug/L
Selenium (Se)
0.193 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
0.114 U
ug/L
MDL
DF
Method
Analysis Date/Time
Analyst
1.7
1
SM 2320134d
04/08/2024 13:07
SNEGLIA
1.7
1
SM 2320134d
04/08/2024 13:07
SNEGLIA
1.7
1
SM 2320134d
04/08/2024 13:07
SNEGLIA
0.1
0.0154
1
EPA 9056A
04/03/2024 12:41
BGN9034
0.1
0.0479
1
EPA 9056A
04/03/2024 12:41
BGN9034
0.1
0.0428
1
EPA 9056A
04/03/2024 12:41
BGN9034
0.05
0.01
1
EPA 7470A
04/04/2024 10:55
SNEGLIA
0.01
0.003
1
SW 601OD
04/03/2024 13:14
CELL106
0.005
0.002
1
SW 601OD
04/03/2024 13:14
CELL106
0.05
0.005
1
SW 601OD
04/03/2024 13:14
CELL106
0.05
0.012
1
SW 601OD
04/03/2024 13:14
CELL106
0.005
0.001
1
SW 601OD
04/03/2024 13:14
CELL106
0.01
0.004
1
SW 601OD
04/03/2024 13:14
CELL106
0.02
0.008
1
SW 601OD
04/03/2024 13:14
CELL106
0.005
0.001
1
SW 601OD
04/03/2024 13:14
CELL106
0.1
0.031
1
SW 601OD
04/03/2024 13:14
CELL106
0.05
0.017
1
SW 601OD
04/03/2024 13:14
CELL106
0.005
0.001
1
SW 601OD
04/03/2024 13:14
CELL106
0.19
1
SW 6010D
04/03/2024 13:14
CELL106
0.015
0.004
1
SW 601OD
04/03/2024 13:14
CELL106
1
0.104
1
SW 6020B
04/04/2024 00:14
CELL106
1
0.111
1
SW 6020B
04/04/2024 00:14
CELL106
1
0.249
1
SW 6020B
04/04/2024 00:14
CELL106
1
0.032
1
SW 6020E
04/04/2024 00:14
CELL106
1
0.185
1
SW 6020B
04/04/2024 00:14
CELL106
1
0.077
1
SW 6020B
04/04/2024 00:14
CELL106
1
0.037
1
SW 6020E
04/04/2024 00:14
CELL106
1
0.18
1
SW 6020B
04/04/2024 00:14
CELL106
1
0.256
1
SW 6020E
04/04/2024 00:14
CELL106
1
0.193
1
SW 6020B
04/04/2024 00:14
CELL106
0.2
0.041
1
SW 6020B
04/04/2024 00:14
CELL106
0.3
0.114
1
SW 6020B
04/04/2024 00:14
CELL106

Certificate of Laboratory Analysis Page 24 of 40
This report shall not be reproduced, except in full.
Order # J24030518
Site: ASA FB-20240401-1110 Field Blank Sample #: 2024007450
Collection Date: 04/01/2024 11:10 AM Loc code: ASA FB Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an estimate.

Certificate of Laboratory Analysis Page 25 of 40
This report shall not be reproduced, except in full.
Order # J24030518
Level II QC Summary
Q24040074 ALK CarbBicarb TOTAL ALKALINITY
Duplicate # I
Parameter
Measured
Final
Alkalinity, Bicarbonate
81.1
Alkalinity, Carbonate
0
Total Alkalinity as CaCO3
81.1
Duplicate # 2
Parameter
Measured
Final
Alkalinity, Bicarbonate
75.7
Alkalinity, Carbonate
0
Total Alkalinity as CaCO3
75.7
Duplicate # 3
Parameter
Measured
Final
Alkalinity, Bicarbonate
31.7
Alkalinity, Carbonate
0
Total Alkalinity as CaCO3
31.7
LCS # I
Parameter
Measured
Final
Total Alkalinity as CaCO3
78.3
LCS # 2
Parameter
Measured
Final
Total Alkalinity as CaCO3
79.7
LCS # 3
Parameter
Measured
Final
Total Alkalinity as CaCO3
79.3
Parent Sample:
J24030604 -- 2024007765
Units
Dil
MDL
RPD
Qualifier
mg/L
1
1.7
2.93
mg/L
1
1.7
0
mg/L
1
1.7
2.93
Parent Sample:
J24030604 -- 2024007766
Units
Dil
MDL
RPD
Qualifier
mg/L
1
1.7
1.81
mg/L
1
1.7
0
mg/L
1
1.7
1.81
Parent Sample:
J24030517 -- 2024007430
Units
Dil
MDL
RPD
Qualifier
mg/L
1
1.7
2.03
mg/L
1
1.7
0
mg/L
1
1.7
2.03
Units
Dil
MDL
Spike
% Recover v
LCL UCL
Qualifier
mg/L
1
1.7
77.9
101
85 115
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
mg/L
1
1.7
77.9
102
85 115
Units
Dil
MDL
Spike
% Recover v
LCL UCL
Qualifier
mg/L
1
1.7
77.9
102
85 115

Certificate of Laboratory Analysis Page 26 of 40
This report shall not be reproduced, except in full.
Order # J24030518
Level II QC Summary
Q24040131 ALK LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
LCS # 1
Parameter Measured Final
Total Alkalinity as CaCO3 74.5
Units Dil MDL Spike % Recovery LCL UCL
mg/L 1 1.7 77.9 95.7 85 115
(CaCO3)
Qualifier
LCSD # 1
Parameter Measured Final Units Dil MDL Spike % Recovery LCL UCL RPD Qualifier
Total Alkalinity as CaCO3 73.2 mg/L 1 1.7 77.9 94 85 115 1.76
(CaCO3)

Certificate of Laboratory Analysis Page 27 of 40
This report shall not be reproduced, except in full.
Order # J24030518
Level II QC Summary
Q24040046 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Fluoride
0
0
mg/L
1
0.0479
0.1
< MDL
Sulfate
0
0
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
5.08
5.08
mg/L
1
0.0154
5
102
80
120
Fluoride
4.86
4.86
mg/L
1
0.0479
5
97.1
80
120
Sulfate
5.13
5.13
mg/L
1
0.0428
5
103
80
120
MS # 1
Parent Sample:
J24030518 -- 2024007439
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
4.32
21.6
mg/L
5
0.0154
5
99.5
80
120
Fluoride
4.43
4.43
mg/L
1
0.0479
5
82.7
80
120
Sulfate
6.01
90.1
mg/L
15
0.0428
5
111
80
120
MSD # 1
Parent Sample:
J24030518 -- 2024007439
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Qualifier
Chloride
4.31
21.6
mg/L
5
0.0154
5
99.1
80
120
0.403
Fluoride
4.42
4.42
mg/L
1
0.0479
5
82.4
80
120
0.364
Sulfate
6
90
mg/L
15
0.0428
5
110
80
120
0.812

Certificate of Laboratory Analysis Page 28 of 40
This report shall not be reproduced, except in full.
Order # J24030518
Level II QC Summary
Q24040058 HG 7470 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Mercury (Hg)
-0.005
-0.005
Blank # 2
Parameter
Measured
Final
Mercury (Hg)
-0.005
-0.005
LCS # 1
MS # 1
MSD # 1
MS # 2
MSD # 2
Parameter Measured Final
Mercury (Hg) 2.01 2.01
Parameter Measured Final
Mercury (Hg) 0.998 0.998
Parameter Measured Final
Mercury (Hg) 1 1
Parameter Measured Final
Mercury (Hg) 0.991 0.991
Parameter Measured Final
Mercury (Hg) 1 1
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
ug/L
1
0.01
0.05
< MDL
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
ug/L
1
0.01
0.05
< MDL
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
ug/L
1
0.01
2
101
85 115
Parent Sample:
J24030517 -- 2024007428
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
ug/L
1
0.01
1
99.5
75 125
Parent Sample:
J24030517 -- 2024007428
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
ug/L
1
0.01
1
99.8
75 125 0.301
Parent Sample:
J24030518 -- 2024007439
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
ug/L
1
0.01
1
98.8
75 125
Parent Sample:
J24030518 -- 2024007439
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
ug/L
1
0.01
1
100
75 125 1.41

Certificate of Laboratory Analysis Page 29 of 40
This report shall not be reproduced, except in full.
Order # J24030518
Level II QC Summary
Q24040059 HG 7470_Dissolved DISSOLVED MERCURY (COLD VAPOR) IN WATER
Blank # 1
LCS # 1
MS # 1
MSD # 1
Parameter Measured Final
Mercury (Hg) -0.003 -0.003
Parameter Measured Final
Mercury (Hg) 2 2
Parameter Measured Final
Mercury (Hg) 0.969 0.969
Parameter Measured Final
Mercury (Hg) 0.958 0.958
Units
Dil
MDL
RDL
Relative Concentration
ug/L
1
0.01
0.05
< MDL
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
ug/L
1
0.01
2
100
85
115
Parent Sample:
J24030518 -- 2024007441
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
ug/L
1
0.01
1
96.8
75
125
Parent Sample:
J24030518 -- 2024007441
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
ug/L
1
0.01
1
95.7
75
125 1.14
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030518
Level II QC Summary
Q24040032 ICP_DIS_TRM TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
Blank # 1
Page 30 of 40
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Aluminum (AI)
0.00192
0.00192
mg/L
1
0.003
0.01
< MDL
Barium (Ba)
-0.000052
-0.000052
mg/L
1
0.002
0.005
< MDL
Boron (B)
0.000759
0.000759
mg/L
1
0.005
0.05
< MDL
Calcium (Ca)
0.00419
0.00419
mg/L
1
0.012
0.05
< MDL
Copper (Cu)
0.0011
0.0011
mg/L
1
0.001
0.005
> MDL
Iron (Fe)
0.00259
0.00259
mg/L
1
0.004
0.01
< MDL
Magnesium (Mg)
0.0002
0.0002
mg/L
1
0.008
0.01
< MDL
Manganese (Mn)
0.000318
0.000318
mg/L
1
0.001
0.005
< MDL
Potassium (K)
-0.0374
-0.0374
mg/L
1
0.031
0.1
< MDL
Sodium (Na)
0.000439
0.000439
mg/L
1
0.017
0.05
< MDL
Strontium (Sr)
-0.000089
-0.000089
mg/L
1
0.001
0.005
< MDL
Zinc (Zn)
0.00049
0.00049
mg/L
1
0.004
0.015
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Aluminum (AI)
5.18
5.18
mg/L
1
0.003
5
104
80
120
Barium (Ba)
5.1
5.1
mg/L
1
0.002
5
102
80
120
Boron (B)
5.07
5.07
mg/L
1
0.005
5
101
80
120
Calcium (Ca)
5.22
5.22
mg/L
1
0.012
5
104
80
120
Copper (Cu)
5.15
5.15
mg/L
1
0.001
5
103
80
120
Iron (Fe)
5.18
5.18
mg/L
1
0.004
5
104
80
120
Magnesium (Mg)
5.09
5.09
mg/L
1
0.008
5
102
80
120
Manganese (Mn)
5.12
5.12
mg/L
1
0.001
5
102
80
120
Potassium (K)
5.13
5.13
mg/L
1
0.031
5
103
80
120
Sodium (Na)
5.19
5.19
mg/L
1
0.017
5
104
80
120
Strontium (Sr)
5.15
5.15
mg/L
1
0.001
5
103
80
120
Zinc (Zn)
5.17
5.17
mg/L
1
0.004
5
103
80
120
MS # 1
Parent Sample:
J24030518 -- 2024007439
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Aluminum (AI)
8.99
8.99
mg/L
1
0.003
5
102
70
130
Barium (Ba)
5.18
5.18
mg/L
1
0.002
5
102
70
130
Boron (B)
5.08
5.08
mg/L
1
0.005
5
101
70
130
Calcium (Ca)
19
19
mg/L
1
0.012
5
102
70
130
Copper (Cu)
5.1
5.1
mg/L
1
0.001
5
102
70
130
Iron (Fe)
6.09
6.09
mg/L
1
0.004
5
102
70
130
Magnesium (Mg)
15.4
15.4
mg/L
1
0.008
5
90
70
130
Manganese (Mn)
6.09
6.09
mg/L
1
0.001
5
103
70
130
Potassium (K)
7.15
7.15
mg/L
1
0.031
5
102
70
130
Sodium (Na)
12.9
12.9
mg/L
1
0.017
5
104
70
130
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 31 of40
This report shall not be reproduced, except in full.
Order # J24030518
Level II QC Summary
Q24040032 ICP_DIS_TRM TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
MS # 1
Parameter
Measured
Final
Strontium (Sr)
5.15
5.15
Zinc (Zn)
5.22
5.22
MSD # 1
Parameter
Measured
Final
Aluminum (AI)
8.92
8.92
Barium (Ba)
5.08
5.08
Boron (B)
5.03
5.03
Calcium (Ca)
18.7
18.7
Copper (Cu)
5.05
5.05
Iron (Fe)
6.03
6.03
Magnesium (Mg)
15.4
15.4
Manganese (Mn)
5.96
5.96
Potassium (K)
7.09
7.09
Sodium (Na)
12.7
12.7
Strontium (Sr)
5.16
5.16
Zinc (Zn)
5.17
5.17
Parent Sample:
J24030518 -- 2024007439
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
mg/L
1
0.001
5
102
70
130
mg/L
1
0.004
5
102
70
130
Parent Sample:
J24030518
-- 2024007439
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
mg/L
1
0.003
5
101
70
130
0.782
mg/L
1
0.002
5
100
70
130
1.95
mg/L
1
0.005
5
100
70
130
0.989
mg/L
1
0.012
5
96
70
130
1.59
mg/L
1
0.001
5
101
70
130
0.985
mg/L
1
0.004
5
101
70
130
0.99
mg/L
1
0.008
5
90
70
130
0
mg/L
1
0.001
5
100
70
130
2.16
mg/L
1
0.031
5
101
70
130
0.843
mg/L
1
0.017
5
100
70
130
1.56
mg/L
1
0.001
5
102
70
130
0.194
mg/L
1
0.004
5
101
70
130
0.962
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030518
Level II QC Summary
Q24040033 ICP_TRM TOTAL RECOVERABLE METALS BY iCP
Blank # 1
Page 32 of 40
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Aluminum (AI)
0.000192
0.000192
mg/L
1
0.003
0.01
< MDL
Barium (Ba)
-0.000004
-0.000004
mg/L
1
0.002
0.005
< MDL
Boron (B)
-0.000285
-0.000285
mg/L
1
0.005
0.05
< MDL
Calcium (Ca)
0.0043
0.0043
mg/L
1
0.012
0.05
< MDL
Copper (Cu)
0.0015
0.0015
mg/L
1
0.001
0.005
> MDL
Iron (Fe)
0.000785
0.000785
mg/L
1
0.004
0.01
< MDL
Magnesium (Mg)
0.0001
0.0001
mg/L
1
0.008
0.02
< MDL
Manganese (Mn)
0.000235
0.000235
mg/L
1
0.001
0.005
< MDL
Potassium (K)
-0.0384
-0.0384
mg/L
1
0.031
0.1
< MDL
Sodium (Na)
0.00349
0.00349
mg/L
1
0.017
0.05
< MDL
Strontium (Sr)
-0.000049
-0.000049
mg/L
1
0.001
0.005
< MDL
Zinc (Zn)
0.000719
0.000719
mg/L
1
0.004
0.015
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Aluminum (AI)
5.26
5.26
mg/L
1
0.003
5
105
80
120
Barium (Ba)
5.21
5.21
mg/L
1
0.002
5
104
80
120
Boron (B)
5.17
5.17
mg/L
1
0.005
5
103
80
120
Calcium (Ca)
5.36
5.36
mg/L
1
0.012
5
107
80
120
Copper (Cu)
5.22
5.22
mg/L
1
0.001
5
104
80
120
Iron (Fe)
5.28
5.28
mg/L
1
0.004
5
106
80
120
Magnesium (Mg)
5.24
5.24
mg/L
1
0.008
5
105
80
120
Manganese (Mn)
5.29
5.29
mg/L
1
0.001
5
106
80
120
Potassium (K)
5.18
5.18
mg/L
1
0.031
5
104
80
120
Sodium (Na)
5.26
5.26
mg/L
1
0.017
5
105
80
120
Strontium (Sr)
5.2
5.2
mg/L
1
0.001
5
104
80
120
Zinc (Zn)
5.33
5.33
mg/L
1
0.004
5
107
80
120
MS # 1
Parent Sample:
J24030518 -- 2024007439
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Aluminum (AI)
11.4
11.4
mg/L
1
0.003
5
106
75
125
Barium (Ba)
5.32
5.32
mg/L
1
0.002
5
105
75
125
Boron (B)
5.25
5.25
mg/L
1
0.005
5
105
75
125
Calcium (Ca)
19.2
19.2
mg/L
1
0.012
5
106
75
125
Copper (Cu)
5.27
5.27
mg/L
1
0.001
5
105
75
125
Iron (Fe)
6.38
6.38
mg/L
1
0.004
5
107
75
125
Magnesium (Mg)
15.6
15.6
mg/L
1
0.008
5
96
75
125
Manganese (Mn)
6.23
6.23
mg/L
1
0.001
5
106
75
125
Potassium (K)
7.35
7.35
mg/L
1
0.031
5
106
75
125
Sodium (Na)
13.2
13.2
mg/L
1
0.017
5
108
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 33 of 40
This report shall not be reproduced, except in full.
Order # J24030518
Level II QC Summary
Q24040033 ICP_TRM TOTAL RECOVERABLE METALS BY 1CP
MS # 1
Parameter
Measured
Final
Strontium (Sr)
5.37
5.37
Zinc (Zn)
5.48
5.48
MSD # 1
Parameter
Measured
Final
Aluminum (AI)
11.5
11.5
Barium (Ba)
5.33
5.33
Boron (B)
5.25
5.25
Calcium (Ca)
19.3
19.3
Copper (Cu)
5.26
5.26
Iron (Fe)
6.37
6.37
Magnesium (Mg)
15.7
15.7
Manganese (Mn)
6.25
6.25
Potassium (K)
7.33
7.33
Sodium (Na)
13.2
13.2
Strontium (Sr)
5.41
5.41
Zinc (Zn)
5.46
5.46
Parent Sample:
J24030518 -- 2024007439
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
mg/L
1
0.001
5
106
75
125
mg/L
1
0.004
5
107
75
125
Parent Sample:
J24030518
-- 2024007439
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
mg/L
1
0.003
5
108
75
125
0.873
mg/L
1
0.002
5
105
75
125
0.188
mg/L
1
0.005
5
105
75
125
0
mg/L
1
0.012
5
108
75
125
0.519
mg/L
1
0.001
5
105
75
125
0.19
mg/L
1
0.004
5
107
75
125
0.157
mg/L
1
0.008
5
98
75
125
0.639
mg/L
1
0.001
5
106
75
125
0.321
mg/L
1
0.031
5
106
75
125
0.272
mg/L
1
0.017
5
108
75
125
0
mg/L
1
0.001
5
107
75
125
0.742
mg/L
1
0.004
5
107
75
125
0.366
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030518
Level II QC Summary
Q24040035 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Blank # 1
Page 34 of 40
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
-0.001
-0.001
ug/L
1
0.104
1
< MDL
Arsenic (As)
-0.007
-0.007
ug/L
1
0.111
1
< MDL
Beryllium (Be)
0
0
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0
0
ug/L
1
0.032
1
< MDL
Chromium (Cr)
-0.006
-0.006
ug/L
1
0.185
1
< MDL
Cobalt (Co)
0.003
0.003
ug/L
1
0.077
1
< MDL
Lead (Pb)
0.007
0.007
ug/L
1
0.037
1
< MDL
Molybdenum (Mo)
0.01
0.01
ug/L
1
0.18
1
< MDL
Nickel (Ni)
0.016
0.016
ug/L
1
0.256
1
< MDL
Selenium (Se)
0.14
0.14
ug/L
1
0.193
1
< MDL
Thallium (TI) Low Level
0.001
0.001
ug/L
1
0.041
0.2
< MDL
Vanadium (V) Low Level
-0.014
-0.014
ug/L
1
0.114
0.3
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
49.5
49.5
ug/L
1
0.104
50
99.1
80
120
Arsenic (As)
49.7
49.7
ug/L
1
0.111
50
99.4
80
120
Beryllium (Be)
47.6
47.6
ug/L
1
0.249
50
95.2
80
120
Cadmium (Cd)
49.2
49.2
ug/L
1
0.032
50
98.4
80
120
Chromium (Cr)
50.7
50.7
ug/L
1
0.185
50
101
80
120
Cobalt (Co)
50.1
50.1
ug/L
1
0.077
50
100
80
120
Lead (Pb)
49.8
49.8
ug/L
1
0.037
50
99.6
80
120
Molybdenum (Mo)
51
51
ug/L
1
0.18
50
102
80
120
Nickel (Ni)
50.1
50.1
ug/L
1
0.256
50
100
80
120
Selenium (Se)
47.2
47.2
ug/L
1
0.193
50
94.3
80
120
Thallium (TI) Low Level
49.1
49.1
ug/L
1
0.041
50
98.2
80
120
Vanadium (V) Low Level
49.9
49.9
ug/L
1
0.114
50
99.7
80
120
MS # 1
Parent Sample:
J24030518 -- 2024007440
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
49.5
49.5
ug/L
1
0.104
50
98.9
75
125
Arsenic (As)
50.6
50.6
ug/L
1
0.111
50
98.4
75
125
Beryllium (Be)
47
47
ug/L
1
0.249
50
93.9
75
125
Cadmium (Cd)
48.8
48.8
ug/L
1
0.032
50
97.4
75
125
Chromium (Cr)
49.2
49.2
ug/L
1
0.185
50
98
75
125
Cobalt (Co)
118
118
ug/L
1
0.077
50
95.8
75
125
Lead (Pb)
48.7
48.7
ug/L
1
0.037
50
97.3
75
125
Molybdenum (Mo)
51
51
ug/L
1
0.18
50
100
75
125
Nickel (Ni)
243
243
ug/L
1
0.256
50
89.8
75
125
Selenium (Se)
46.6
46.6
ug/L
1
0.193
50
92.7
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 35 of 40
This report shall not be reproduced, except in full.
Order # J24030518
Level II QC Summary
Q24040035 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
MS # 1
Parameter
Measured
Final
Units
Thallium (TI) Low Level
47.8
47.8
ug/L
Vanadium (V) Low Level
49.3
49.3
ug/L
MSD # 1
Parameter
Measured
Final
Units
Antimony (Sb)
49.9
49.9
ug/L
Arsenic (As)
52
52
ug/L
Beryllium (Be)
49.1
49.1
ug/L
Cadmium (Cd)
49.3
49.3
ug/L
Chromium (Cr)
50.9
50.9
ug/L
Cobalt (Co)
119
119
ug/L
Lead (Pb)
49.7
49.7
ug/L
Molybdenum (Mo)
52
52
ug/L
Nickel (Ni)
245
245
ug/L
Selenium (Se)
47.3
47.3
ug/L
Thallium (TI) Low Level
48.3
48.3
ug/L
Vanadium (V) Low Level
51.2
51.2
ug/L
Parent Sample:
J24030518 -- 2024007440
Dil
MDL
Spike
% Recovery
LCL
UCL
1
0.041
50
95.5
75
125
1
0.114
50
98.6
75
125
Parent Sample:
J24030518
-- 2024007440
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
1
0.104
50
99.7
75
125
0.814
1
0.111
50
101
75
125
2.79
1
0.249
50
98.1
75
125
4.4
1
0.032
50
98.4
75
125
1.04
1
0.185
50
101
75
125
3.42
1
0.077
50
96.6
75
125
0.852
1
0.037
50
99.3
75
125
1.99
1
0.18
50
102
75
125
1.95
1
0.256
50
93.7
75
125
4.26
1
0.193
50
94.1
75
125
1.51
1
0.041
50
96.6
75
125
1.18
1
0.114
50
102
75
125
3.79
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030518
Level II QC Summary
Q24040036 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Page 36 of 40
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
0.064
0.064
ug/L
1
0.104
1
< MDL
Arsenic (As)
0.015
0.015
ug/L
1
0.111
1
< MDL
Beryllium (Be)
0.017
0.017
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0.001
0.001
ug/L
1
0.032
1
< MDL
Chromium (Cr)
0.007
0.007
ug/L
1
0.185
1
< MDL
Cobalt (Co)
0.006
0.006
ug/L
1
0.077
1
< MDL
Lead (Pb)
0.006
0.006
ug/L
1
0.037
1
< MDL
Molybdenum (Mo)
0.013
0.013
ug/L
1
0.18
1
< MDL
Nickel (Ni)
0.008
0.008
ug/L
1
0.256
1
< MDL
Selenium (Se)
0.024
0.024
ug/L
1
0.193
1
< MDL
Thallium (TI) Low Level
-0.001
-0.001
ug/L
1
0.041
0.2
< MDL
Vanadium (V) Low Level
-0.012
-0.012
ug/L
1
0.114
0.3
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
49.4
49.4
ug/L
1
0.104
50
98.7
80
120
Arsenic (As)
49.3
49.3
ug/L
1
0.111
50
98.6
80
120
Beryllium (Be)
49.6
49.6
ug/L
1
0.249
50
99.2
80
120
Cadmium (Cd)
49.2
49.2
ug/L
1
0.032
50
98.3
80
120
Chromium (Cr)
51
51
ug/L
1
0.185
50
102
80
120
Cobalt (Co)
50.1
50.1
ug/L
1
0.077
50
100
80
120
Lead (Pb)
50.1
50.1
ug/L
1
0.037
50
100
80
120
Molybdenum (Mo)
50.5
50.5
ug/L
1
0.18
50
101
80
120
Nickel (Ni)
49.7
49.7
ug/L
1
0.256
50
99.5
80
120
Selenium (Se)
46.6
46.6
ug/L
1
0.193
50
93.2
80
120
Thallium (TI) Low Level
49.6
49.6
ug/L
1
0.041
50
99.2
80
120
Vanadium (V) Low Level
50.3
50.3
ug/L
1
0.114
50
101
80
120
MS # 1
Parent Sample:
J24030518 -- 2024007440
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
49.8
49.8
ug/L
1
0.104
50
99.4
75
125
Arsenic (As)
51.5
51.5
ug/L
1
0.111
50
99.7
75
125
Beryllium (Be)
50.9
50.9
ug/L
1
0.249
50
102
75
125
Cadmium (Cd)
49.1
49.1
ug/L
1
0.032
50
98
75
125
Chromium (Cr)
50
50
ug/L
1
0.185
50
99.3
75
125
Cobalt (Co)
117
117
ug/L
1
0.077
50
97.6
75
125
Lead (Pb)
49.5
49.5
ug/L
1
0.037
50
97.7
75
125
Molybdenum (Mo)
51
51
ug/L
1
0.18
50
102
75
125
Nickel (Ni)
240
240
ug/L
1
0.256
50
93.8
75
125
Selenium (Se)
47.7
47.7
ug/L
1
0.193
50
94.7
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 37 of 40
This report shall not be reproduced, except in full.
Order # J24030518
Level II QC Summary
Q24040036 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 1
Parameter
Measured
Final
Units
Thallium (TI) Low Level
49.2
49.2
ug/L
Vanadium (V) Low Level
49.8
49.8
ug/L
MSD # 1
Parameter
Measured
Final
Units
Antimony (Sb)
49.3
49.3
ug/L
Arsenic (As)
51.6
51.6
ug/L
Beryllium (Be)
48.7
48.7
ug/L
Cadmium (Cd)
48.8
48.8
ug/L
Chromium (Cr)
49.9
49.9
ug/L
Cobalt (Co)
118
118
ug/L
Lead (Pb)
49.5
49.5
ug/L
Molybdenum (Mo)
51.5
51.5
ug/L
Nickel (Ni)
244
244
ug/L
Selenium (Se)
47.4
47.4
ug/L
Thallium (TI) Low Level
49.4
49.4
ug/L
Vanadium (V) Low Level
50.9
50.9
ug/L
Parent Sample:
J24030518 -- 2024007440
Dil
MDL
Spike
% Recovery
LCL
UCL
1
0.041
50
98.3
75
125
1
0.114
50
99.4
75
125
Parent Sample:
J24030518
-- 2024007440
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
1
0.104
50
98.4
75
125
1.03
1
0.111
50
100
75
125
0.338
1
0.249
50
97.2
75
125
4.39
1
0.032
50
97.5
75
125
0.458
1
0.185
50
99
75
125
0.343
1
0.077
50
99.6
75
125
1.99
1
0.037
50
97.9
75
125
0.164
1
0.18
50
103
75
125
1.01
1
0.256
50
102
75
125
7.84
1
0.193
50
94.3
75
125
0.504
1
0.041
50
98.8
75
125
0.524
1
0.114
50
102
75
125
2.28
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 38 of 40
This report shall not be reproduced, except in full.
Order # J24030518
Level II QC Summary
Q24040038 TDS TOTAL DISSOLVED SOLIDS
Blank # 1
Parameter Measured Final
TDS -0.5
Duplicate # 1
Parameter Measured Final
TDS 51
LCS # 1
Parameter Measured Final
TDS 503
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
25
25
< MDL
Parent Sample: J24030517 -- 2024007428
Units
Dil
MDL
RPD
Qualifier
mg/L
1
25
17
R1
Units
Dil
MDL
Spike
% Recovery LCL UCL
Qualifier
mg/L
1
25
500
101 90 110
Qualifiers:
R1 Relative Percent Difference exceeded method acceptance limits.

Certificate of Laboratory Analysis Page 39 of 40
This report shall not be reproduced, except in full.
Order # J24030518
Level II QC Summary
Q24040028 TSS TOTAL SUSPENDED SOLIDS
Blank # 1
Parameter Measured Final
TSS 0.1
Duplicate # 1
Parameter Measured Final
TSS 6.8
LCS # 1
Parameter Measured Final
TSS 97.6
Units
Dil
MDL
RDL
Relative Concentration
mg/L
1
5
5
< MDL
Parent Sample: J24030518 -- 2024007439
Units
Dil
MDL
RPD
mg/L
1
5
0
Units
Dil
MDL
Spike
% Recovery LCL UCL
mg/L
1
5
100
97.6 90 110
Qualifier
Qualifier
Qualifier

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
❑ae Energy Analytical Laboratory !
Analytical Laboratory Use Only
I Page 40 of 40
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