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1403_Caldwell_Foothills_MSWLF_May24GW_FID1894785_20240830
DENR USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR I IEnvironmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Jett Environmental Consulting, PLLC Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Steve Jett E-mail: steve.jett@jettenviro.com Phone: (314) 496-4654 NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Foothills Regional Landfill 2800 Cheraw Road 14-03 .0500 May 5-6, 2024 Lenoir, NC 28645 Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑ Detection Monitoring ❑X Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Groundwater monitoring data from private water supply wells ❑ Leachate monitoring data El water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Steve Jett Owner (314) 496-4654 Facility Representative Name (Print) f/j A a Title (Area Code) Telephone Number Signature 8/30/2024 Date Jett Environmental Consulting, PLLC, 18 Lexington Oaks Court, Foristell, MO 63348 Facility Representative Address NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 Affix NC Licensed/ Professional Geologist Seal JETT ENVIRONMENTAL C O N S U L T I N G August 30, 2024 Ms. Jaclynne Drummond Hydrogeologist Solid Waste Section Division of Waste Management North Carolina Department of Environmental Quality 2090 US Highway 70 Swannanoa, North Carolina 28778 RE: First Semi -Annual Water Quality Monitoring Report of 2024 Foothills Regional Landfill, Permit No. 14-03 Caldwell County, North Carolina Dear Ms. Drummond: Submitted Electronically On behalf of Foothills Regional Landfill, Jett Environmental Consulting is submitting the First Semi -Annual Water Quality Monitoring Report of 2024 and Environmental Monitoring Reporting Form in electronic format. The report completes the First Semi -Annual compliance monitoring event of 2024 for the Foothills Regional Landfill, Permit No. 14-03, as required by the North Carolina Division of Waste Management, Solid Waste Section. If you have any questions or comments, please contact me at steve.jett@jettenviro.com or 314-496-4654. Sincerely, Steve Jett, P.G. #1825 Travis Doll Owner Senior Geologist Jett Environmental Consulting, PLLC (C-517) Attachment: First Semi -Annual Water Quality Monitoring Report of 2024 cc: Stephen Hunter, Foothills Regional Landfill, Republic Services (Hardcopy) Stoddard Pickrell, Republic Services (PDF via Email) Victoria Warren, Republic Services (PDF via Email) 18 Lexington Oaks Court 314-496-4654 Foristell, MO 63348 www.jettenviro.com Groundwater Statistical Analysis Report First Semi -Annual 2024 Sampling Event Foothills Regional Landfill Caldwell County, North Carolina August 2024 Prepared by: JETT ENVIRONMLN IHL C O N S U L T I N G 18 Lexington Oaks Court 314-496-4654 Foristell, MO 63348 www.jettenviro.com TABLE OF CONTENTS 1.0 INTRODUCTION.............................................................................1 2.0 SITE BACKGROUND AND MONITORING NETWORK................1 3.0 SITE HYDROGEOLOGY................................................................2 4.0 DATA EVALUATION......................................................................3 5.0 STATISTICAL PROCEDURES.......................................................3 5.1 Outlier Analysis...........................................................................3 5.2 Inter -Well Prediction Intervals....................................................4 5.3 Intra-Well Confidence Limits......................................................4 5.4 Statistical Results Summary.......................................................5 6.0 CONCLUSIONS..............................................................................5 7.0 RECOMMENDATIONS...................................................................6 TABLES Table 1 Groundwater Monitoring Program Table 2 Groundwater Analytical Data Summary Table 3 Surface Water Analytical Data Summary Table 4 Underdrain Analytical Data Summary Table 5 Leachate Analytical Data Summary APPENDICES Appendix A Potentiometric Surface Map Appendix B Statistical Evaluations Appendix C Laboratory Analytical Reports & Field Sampling Forms Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 1 1.0 INTRODUCTION On behalf of Foothills Regional Landfill, Jett Environmental Consulting statistically evaluated the First Semi - Annual 2024 water quality monitoring data. Groundwater, surface water, underdrain, and leachate sampling were completed by Environmental Sampling & Services, Inc. (ES&S) on May 5-6, 2024 and analytical testing was performed by Pace Analytical Services, LLC. The statistical analysis software package utilized, Sanitasr', follows a documented decision logic that incorporates the following applicable document: USEPA "Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified Guidance" (March 2009). 2.0 SITE BACKGROUND AND MONITORING NETWORK In compliance with North Carolina Department of Environmental Quality (DEQ) Solid Waste Management Regulations, Section .1600 "Requirements for Municipal Solid Waste Landfill Facilities," Jett Environmental Consulting statistically evaluated parameters from the First Semi -Annual 2024 event using inter -well prediction interval analysis. Prediction intervals are considered a powerful tool for groundwater statistical analysis, when feasible, due to their inherent low false negative and false positive rates utilizing confirmatory resampling, if necessary. The facility's monitoring network is comprised of twelve monitoring wells: MW-1 R2 (background), MW-2R, MW-3R2, MW-4, MW-5, MW-6, MW-7, MW-8, MW-9, MW-10, MW-11, and MW-12, which monitor the uppermost aquifer beneath the facility. The monitoring wells are sampled on a semi-annual basis, with the groundwater samples submitted to a qualified laboratory for required analyses in accordance with the facility's environmental monitoring program and permit requirements. The monitoring wells are equipped with dedicated bladder pumps and were purged and sampled via the low -flow method. Table 1 lists the groundwater monitoring wells for the site. Each of the wells was sampled during the First Semi -Annual 2024 event. Groundwater monitoring was initiated in August 1998. Statistical background is defined as samples collected from former upgradient well MW-1, former upgradient well MW-1 R, and current upgradient well MW-1 R2 from 1998 through the current event. The parameters subject to statistical evaluation during detection monitoring are noted in DEQ Section .1633 as constituents listed in Appendix I of 40 CFR Part 258 "Constituents for Detection Monitoring". The following is a chronology of well replacement and abandonment. Well MW-3R2 was added to the monitoring well network on August 17, 2006 as a replacement well for MW-3 and MW-3R. Monitoring wells MW-3 and MW-3R remain for water level data collection purposes only. Monitoring well MW-7 was installed in April 2010 to monitor groundwater beneath Cell 4, which began receiving waste in September 2010. MW-8 was installed in April 2013 to monitor Cell 8A, which was constructed in January 2013. MW-10 was installed in October 2015 to monitor Cell 5A. The former background well MW-1 was abandoned in preparation for construction of Cell 5A and the new background well, MW-1 R, was installed in October 2015. MW-9 was installed June 2016 to monitor Cell 5A. Soil and bedrock removal in the Northern Borrow Area rendered well MW-1 R dry and inaccessible. Therefore, a replacement monitoring well (MW-1 R2) was installed in September 2018. Well MW-11 was installed in September 2018 as part of the Cell No. 5B construction. New well MW-12 was installed in November 2023 as part of the Cell No. 6B construction. Well MW-12 was able to be sampled for the first time on January 3, 2024 as part of the Second Semi - Annual 2023 event. Well MW-12 is currently in the process of having four rounds of background sampling completed. The site has a surface water monitoring network consisting of one upstream surface water sampling point (SW-1) and four downstream points (SW-2, SW-3, SW-4, and SW-5). These points are sampled semi- annually for the 40 CFR Part 258 Appendix I list in conjunction with the groundwater monitoring wells. Each surface water monitoring point was sampled during the First Semi -Annual 2024 event. Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 2 A sample point from the underdrain for Cell 1 (UD-1) was added to the monitoring program prior to the January 2008 sampling event. A sample point from the underdrain for Cells 4 and 8A (UD-2) was added to the monitoring program prior to the January 2014 sampling event. The underdrains are to be sampled semi-annually (contingent on flow availability) for the 40 CFR Part 258 Appendix I list. Both underdrains were able to be sampled during the First Semi -Annual 2024 event. A leachate sample is also routinely collected for analysis. The leachate sample was analyzed for the 40 CFR Part 258 Appendix I list, biochemical oxygen demand, chemical oxygen demand, nitrate as N, nitrite as N, phosphorus, and sulfate. In accordance with a November 28, 2018 DEQ letter, 1,4-dioxane is no longer required to be analyzed for the groundwater and surface water samples; however, will be analyzed annually for the leachate sample. The leachate was sampled and analyzed for 1,4-dioxane during the First Semi -Annual 2024 event. The facility was in an Assessment Monitoring Program in 2006. An Alternate Source Demonstration (ASD) for volatile organic compounds (VOCs) detected in wells MW-3 and MW-3R was approved by DEQ on December 14, 2006, and the facility reverted to a Detection Monitoring Program. An ASD for benzene and vinyl chloride at MW-2R was submitted to DEQ in June 2017; however, it was not approved in a letter from DEQ dated October 11, 2017 and Assessment Monitoring was initiated. Therefore, during the First Semi -Annual 2018 event, the initial Appendix II Assessment constituent list was sampled at each well. The constituents detected at quantifiable concentrations (barium, benzene, and cobalt) were consistent with past events and also on the Appendix I Detection Monitoring list. On May 18, 2018, the site requested deleting all non -Appendix I monitoring from future sampling events, with the exception of well MW-2R, which will continue with annual Appendix II monitoring. In correspondence dated July 9, 2018, DEQ approved the request to only include MW-2R for future annual Appendix II monitoring. The annual Appendix II monitoring for MW-2R was performed during the First Semi -Annual 2024 event. 3.0 SITE HYDROGEOLOGY The following site hydrogeology summary was taken from the Second Semi -Annual Water Quality Monitoring Report of 2017, dated November 17, 2017 by Joyce Engineering. Geologically, the facility is located in the northwestern portion of the Inner Piedmont Belt of the Piedmont Physiographic Province, approximately 20 miles east of the thrust belt (Brevard Shear Zone) delineating the boundary between the westerly Blue Ridge Belt and the easterly Inner Piedmont Belt. The metamorphic rocks of the Inner Piedmont Belt generally group within the sillimanite facies of the amphibolite metamorphic sequence. Locally, the bedrock underlying the facility has been mapped as migmatitic granitic gneiss of the Ordovician and older Cambrian Periods. These rocks are described as ranging in composition from granitic to quartz dioritic with smaller biotite gneiss and amphibolite facies present locally. The unit as a whole exhibits a variable massive to foliated fabric. The uppermost aquifer beneath the facility is present within weathered bedrock saprolite and fractured bedrock. The saprolite ranges in texture from clayey silt in the upper, most weathered sections to micaceous sandy silt in the lower sections. Immediately above the competent bedrock surface, a variable thickness transitional zone composed of highly weathered and degraded friable bedrock is present. The uppermost aquifer is laterally continuous across the site, with depth to water ranging from less than 31 feet in low-lying areas to greater than 77 feet beneath topographic highs. Groundwater in the uppermost aquifer generally flows from recharge areas associated with broad gently sloping topographic areas towards topographically lower areas that are generally delineated by the presence of stream channels, some of which are perennial receiving streams (groundwater discharge areas) and others of which are intermittent discharging streams. In the vicinity of the facility, the general groundwater flow direction is towards the south and west. Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 3 Appendix A provides a potentiometric surface map utilizing groundwater level data from the First Semi - Annual 2024 event. Groundwater flow direction for the First Semi -Annual 2024 event was to the southwest, which is consistent with previous interpretations for this facility. Groundwater flow rate for the First Semi - Annual 2024 event was estimated at 161 feet/year, consistent with past events. Flow rate calculations are available in Appendix A. 4.0 DATA EVALUATION Appendix C contains a copy of the laboratory analytical report and field sampling forms for the First Semi - Annual 2024 groundwater, surface water, underdrain, and leachate sampling event. The analytical results for the First Semi -Annual 2024 event for the groundwater, surface water, underdrain, and leachate samples are summarized on Tables 2, 3, 4, and 5, respectively. Two VOCs were detected at a quantified concentration at or above a PQL in groundwater: 1,4-dichlorobenzene and benzene at MW- 2R. The trace level VOC detections are typical for the site. As shown on Table 2, two Appendix I inorganic constituents (barium at MW-2R, MW-5, MW-6, and MW- 11; and cobalt at MW-4) were detected at quantified concentrations in groundwater. Two Appendix I constituents (benzene at MW-2R and cobalt at MW-4) were detected above an NC 2L Standard during the First Semi -Annual 2024 sampling event, which is consistent with recent events. Per 15A NCAC 02L .0202(b)(1), for the NC 2L Standards, only detections of a substance at or above the PQL can constitute a violation of the standard. Therefore, estimated values below the PQL are not considered a violation of a NC 2L Rule standard. No Appendix II constituents, not also on the Appendix I list, were detected at MW-2R above their respective PQLs during the First Semi -Annual 2024 event. As shown on Table 3, during the First Semi -Annual 2024 event, no inorganics were detected in surface water samples at quantified concentrations above a respective NC 2B Surface Water Standard. No VOCs were detected in surface water samples at quantified concentrations above their respective PQLs during the First Semi -Annual 2024 event. During the First Semi -Annual 2024 event, no VOCs were detected in the underdrain samples at quantified concentrations above their respective PQLs (see Table 4). The constituents detected in the leachate sample collected during the First Semi -Annual 2024 event were typical for leachate at this facility (see Table 5). 5.0 STATISTICAL PROCEDURES Statistical analyses (i.e., inter -well prediction limits) were performed to establish background concentrations and determine if the 2L Standard value -to -value exceedances for cobalt exhibited a statistically significant increase (SSI). Statistical analyses (i.e., lower confidence limits) were performed to determine if the 2L Standard value -to -value exceedance for benzene statistically exceeded the 2L Standard. 5.1 Outlier Analysis The background data were evaluated for the presence of statistical outliers. Methodologies for determining a statistical outlier are defined in the USEPA Unified Guidance. Any statistical outliers that were determined were removed from the background data set prior to performing prediction interval statistical analysis. According to the USEPA Unified Guidance above, data that are not normally or log -normally distributed are not recommended for evaluation of outliers. In cases where the data were not normally or log -normally Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 4 distributed, outliers were not removed from the data set. Background outliers flagged for removal are identified on the statistical plots provided in Appendix B. 5.2 Inter -Well Prediction Intervals The prediction interval is a statistical method used to compare a single observation to a group of observations. The prediction interval is calculated to include observations from the same population with a specified confidence. In groundwater monitoring, a prediction interval approach may be used to make comparisons between background and compliance data. The interval is developed to contain all future observations, within a certain probability. For the site, inter -well prediction intervals have been developed based on a 99% confidence that future observations will fall within the range. If any future observation exceeds the prediction interval, this is considered statistically significant evidence that the observation is not representative of the background group. During parametric prediction interval analysis, the mean and the standard deviation are calculated for the raw or transformed background data. The number of comparison observations, K, is defined to be included in the interval. If less than 15% of the background observations are non -detects, the non -detects are replaced with one half of the reporting limit prior to performing the analysis. If more than 15% but less than 50% of the background data are below the reporting limit, the data's sample mean and standard deviation are adjusted according to the Kaplan -Meier method. However, when the background data are not transformed -normal or contain greater than 50% observations below the reporting limit, SanitasTm automatically constructs a non -parametric prediction interval. During non -parametric analysis, the highest value from the background data is used to set the upper limit of the prediction interval. Due to the wide range of laboratory reporting limits utilized over time, the historical reporting limits were conservatively replaced with the current event reporting limit prior to performing statistical analyses. Summary tables and graphs for the inter -well prediction interval analysis are available in Appendix B. Included in Appendix B are time series plots for each of the inorganic constituents. For the First Semi -Annual 2024 event, one inorganic SSI was exhibited for cobalt at MW-4. The First Semi - Annual 2024 concentration of total cobalt at MW-4 (15.6 ug/L) was above the background inter -well prediction limit based on pooled data from upgradient wells MW-1, MW-1 R, and MW-1 R2 (10 ug/L, which is equal to the PQL). 5.3 Intra-Well Confidence Limits Per DEQ Regulation .1634(H), GWPSs are equal to the National Primary Drinking Water Standard - Maximum Contaminant Level (MCL) or North Carolina 15A NCAC 2L Water Quality Standard, whichever is lower. In instances where an MCL or 2L Standard are not established, the GWPSs were derived from the DEQ-Solid Waste Section published GWPSs. In order to determine if the groundwater concentrations exhibit a statistical exceedance of the GWPS, a statistical comparison was made to the GWPSs to determine if further action is warranted. The following text outlines the procedures that were used to statistically compare concentrations to GWPSs. Per the USEPA Unified Guidance, a Confidence Interval is constructed from sample data and is designed to contain the mean concentration of a well analyte in groundwater monitoring, with a designated level of confidence. A confidence interval generally is used when samples are being compared to a GWPS, which is typically the MCL or alternate limit (i.e., 2L Standard). A lower confidence interval analysis was used to statistically compare to GWPSs. The method constructs a normal confidence interval on the mean concentration of a constituent incorporating, at a minimum, the four most recent measurements. The lower confidence interval on the mean was compared to the GWPS to determine whether the mean concentration exceeded its GWPS. If the lower confidence interval on the Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 5 mean exceeds the GWPS then there is statistically significant evidence that the mean concentration of that constituent exceeds the GWPS. The distribution of the data is evaluated by applying the Shapiro -Wilk or Shapiro -Francis test for normality to the raw data or, when applicable, transformed data. If less than 15 percent of the observations are non - detects, the non -detects will be replaced with one half the reporting limit prior to performing the normality test and constructing the confidence limit. Per .1634(g)(5), if background (statistical limit based on upgradient well data) is higher than the 2L Standard, then background may be utilized as the GWPS. Background for organics is considered the non - detect level (equivalent to the PQL). Organic concentrations detected above PQLs and GWPSs (See Table 2) were statistically compared to their respective GWPSs utilizing intra-well lower confidence limits. As provided in Appendix B, benzene at MW-2R statistically exceeded the GWPS for the First Semi -Annual 2024 event, consistent with recent events. Time series graphs for VOC detections during recent events are provided in Appendix B. 5.4 Statistical Results Summary For the First Semi -Annual 2024 event, one inorganic SSI was exhibited for cobalt at MW-4. The First Semi - Annual 2024 concentration of total cobalt at MW-4 (15.6 ug/L) was above the background inter -well prediction limit based on pooled data from upgradient wells MW-1, MW-1 R, and MW-1 R2 (10 ug/L, which is equal to the PQL). However, cobalt concentrations at MW-4 have been decreasing since the July 2012 event (25.4 ug/L). Intra-well lower confidence limits determined benzene at MW-2R (3.5 ug/L) statistically exceeded the GWPS (1.0 ug/L) for the First Semi -Annual 2024 event, consistent with recent events. Benzene concentrations at MW-2R have been reported at varying low levels (1.0 to 3.5 ug/L) since the July 2016 event. 6.0 CONCLUSIONS For the First Semi -Annual 2024 event, one inorganic SSI was confirmed exhibited for cobalt at MW-4, consistent with recent events. One Appendix I VOC (benzene at MW-2R) was confirmed detected above an NC 2L Standard during the First Semi -Annual 2024 sampling event. Intra-well lower confidence limits determined benzene at MW-2R statistically exceeded the GWPS for the First Semi -Annual 2024 event, consistent with recent events. Benzene concentrations at MW-2R have been reported at varying low levels (1.0 to 3.5 ug/L) since the July 2016 event. During the First Semi -Annual 2024 event, no Appendix I VOCs were confirmed detected in surface water and underdrain samples at quantifiable concentrations. No inorganics were confirmed detected in surface water samples at quantified concentrations above a respective NC 2B Surface Water Standard during the First Semi -Annual 2024 event. No Appendix II constituents, not also on the Appendix I list, were detected at MW-2R above their respective PQLs during the First Semi -Annual 2024 event. The Foothills Regional Landfill will continue monitoring in accordance with the requirements for Detection and Assessment Monitoring as outlined in Title 15A NCAC 13B .1633 and .1634, respectively. The next semi-annual event is scheduled for November 2024. Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 6 7.0 RECOMMENDATIONS Wells in the proximity of MW-2R exist directly upgradient (MW-9) and directly downgradient (MW-3R2). No VOCs have not been confirmed detected at quantified concentrations at MW-9 or MW-3R2; therefore, the extent of quantified VOC detections (i.e., 1,4-dichlorobenzene and benzene) have been defined to only MW-2R. As described in the site's June 2017 ASD for benzene/vinyl chloride at MW-2R, the VOCs appear to be related to landfill gas. Wells MW-9, MW-2R, and MW-3R2 would effectively cover the exterior perimeter of the cell (Cell 1A) suspected as the source of potential gas migration. The site implemented landfill gas extraction and collection upgrades in the Cell 1A area in late 2017 and installed a horizontal active landfill gas collection/mitigation trench in the vicinity of MW-2R in Fall 2018 (see map in Appendix A). According to site personnel, landfill gas expansion projects for 2024 were completed in July. By the end of Third Quarter 2024, the facility plans installation of additional landfill gas extraction points to assist the mitigation trench in the removal of landfill gas, which should help decrease VOC concentrations in the vicinity of MW- 2R. Additional groundwater monitoring events are recommended before any further actions are considered to determine if benzene levels at MW-2R (3.5 ug/L) decrease to levels below the lab PQL (1.0 ug/L) as a result of the landfill gas system upgrades. It is recommended that well MW-4 continues in Detection Monitoring. The decrease in concentration of cobalt at MW-4 from 25.4 ug/L in July 2012 to 15.6 ug/L during the First Semi -Annual 2024 event indicates a decreasing trend near the laboratory PQL (10 ug/L). Since the landfill is lined, it is unlikely the cobalt detections are related to a landfill release. The lack of receptors of water use in this shallow aquifer, which would not feasibly produce a well with sufficient yield for potable use, is evidence of a lack of risk associated with this level of detection. Cobalt is naturally occurring at the site, evident by the historical cobalt detections in various wells across this site and is a common element occurring naturally in minerals commonly found in the bedrock, soil, and sediments in the North Carolina Piedmont. According to A Geochemical Atlas of North Carolina (by Jeffery C. Reid, dated 1993 in the North Carolina Geological Survey's Bulletin 93), which displays the distribution of cobalt in stream sediments across the state, Caldwell County has been highlighted. Cobalt was found at concentrations as high as 10 mg/kg throughout Caldwell County; with a significant amount of variability. Metals in the soil and bedrock can easily leach into the groundwater, especially if the groundwater is acidic (pH < 7.0). The pH of groundwater samples from the Foothills Regional Landfill during the First Semi -Annual 2024 sampling event ranged from 4.13 to 8.30 SU. The pH of the sample from MW-4, which had the highest cobalt concentration, was 4.13 SU. Review of leachate data for the last 14 years indicates cobalt has ranged from J 7.3 to 52.1 ug/L, with an average concentration of 25.8 ug/L. The occurrence and levels of cobalt at the site has no indication of being related to a release from the waste unit. The site recommends utilizing the upcoming Second Semi -Annual 2024 (November 2024) event to continue to verify the downward trends of cobalt levels at MW-4, since levels are approaching the laboratory PQL of 10 ug/L. The additional time will also provide more insight on whether the additional landfill gas collection vacuum in the mitigation trench helps decrease VOC concentrations (i.e., benzene) in the vicinity of MW- 2R. The proposed actions are protective of human health and the environment and the values at this time do not further action, especially for a naturally occurring element (cobalt). 8.0 PFAS SAMPLING In a March 13, 2023 Memorandum (Memo) from DEQ, requirements for per- and polyfluoroalkyl substances (PFAS) monitoring were outlined. Following discussions with DEQ, the Carolinas Chapter of NWRA and North Carolina Chapter of SWANA provided an April 28, 2023 recommended Sampling and Analysis Guidance. This included a recommendation that a subset of representative sample points should be used to fulfill DEQ's site screening objectives. In a subsequent July 17, 2023 Memo from DEQ, clarification was Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 7 provided regarding the PFAS monitoring. The July 17, 2023 Memo specified PFAS samples should be collected from each monitoring location for two consecutive events based on a facility's current water quality monitoring schedule. Per the July 17, 2023 Memo, facilities with groundwater assessment or corrective action wells could propose to sample a representative subset of assessment/corrective action wells for Section review and approval. In addition, the July 17, 2023 Memo stated facilities may propose to collect samples from a subset of the current surface water sampling locations, comprising at least one upstream and one downstream location. In correspondence dated October 2, 2023, the site requested that of the five surface water sampling points, only upstream sample location SW-1 and downstream sample location SW-2 would be analyzed for PFAS. In correspondence dated October 16, 2023, DEQ denied the request and stated surface water monitoring locations and groundwater monitoring wells that are sampled are required to have two PFAS sampling events (initial and confirmatory). During the First Semi -Annual 2024 event, the site collected PFAS samples at each groundwater monitoring well, surface water monitoring point, underdrain monitoring point, and the leachate system. Samples have been analyzed by the laboratory, and the PFAS results will be submitted to DEQ in a timely manner upon review. TABLES TABLE 1 GROUNDWATER MONITORING PROGRAM FIRST SEMI-ANNUAL 2024 EVENT FOOTHILLS REGIONAL LANDFILL UPGRADIENT WELLS DOWNGRADIENT WELLS MW-1 R2 I MW-2R, MW-3R2, MW-4, MW-5, MW-6, MW-7, MW-8, MW-9, MW-10, MW-11, MW-12 TABLE 2 GROUNDWATER ANALYTICAL DATA SUMMARY FIRST SEMI-ANNUAL 2024 EVENT FOOTHILLS REGIONAL LANDFILL Constituent Units 2LStd MDL PQL MWAR2 MW-2R MW-3112 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-12 Antimony Total u /L 1 0.54 6 <6 <6 0.61 J <6 <6 <6 0.55 J <6 <6 <6 <6 <6 Arsenic Total u /L 10 0.84 10 <10 <10 <10 <10 1.0 J <10 <10 <10 1.6 J <10 0.92 J <10 Barium Total u /L 700 0.47 100 48.3 J 403 4.9 J 47.1 J 149 140 24.6 J 68.1 J 8.3 J 33.3 J 124 24.4 J Beryllium Total u /L 4 0.094 1 <1 0.18 J <1 <1 <1 0.29 J 0.10 J <1 <1 <1 <1 <1 Cadmium Total u /L 2 0.1 1 1 <1 <1 <1 <1 <1 0.13 J <1 <1 <1 <1 <1 <1 Chromium Total u /L 10 1.9 10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 Cobalt Total u /L 1 0.32 10 <10 <10 <10 15.6 <10 5.4 J <10 <10 0.36 J <10 <10 <10 Copper Total u /L 1,000 0.43 10 <10 0.44 J <10 <10 <10 <10 <10 <10 <10 <10 0.43 J <10 Cyanide Total m /L 70 0.006 0.008 NS <0.008 NS NS NS NS NS NS NS NS NS NS Lead Total u /L 15 0.16 10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 Mercury Total u /L 1 0.13 0.2 NS <0.2 NS NS NS NS NS NS NS NS NS NS Nickel Total u /L 100 2.1 50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 Selenium Total u /L 20 0.96 10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 Silver Total u /L 20 0.31 10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 Sulfide Total m /L NE 0.022 0.1 NS <0.1 NS NS NS NS NS NS NS NS NS NS Thallium Total u /L 2 0.38 5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 Tin Total u /L 2000 1.2 20 NS <20 NS NS NS NS NS NS NS NS NS NS Vanadium Total u /L 7 0.75 25 <25 <25 1.1 J <25 3.5 J <25 1.5 J 1.2 J 2.1 J 5.6 J 1.6 J 1.7 J Zinc Total ug/L 1,000 2.4 10 <10 <10 <10 2.4 J <10 <10 <10 <10 <10 <10 <10 <10 Field Dissolved Oxygen m /L NE NE NE 2.31 2.15 3.46 1.95 2.73 2.80 4.05 2.09 3.12 4.42 2.03 2.05 Field pH SU NE NE NE 6.26 5.35 8.30 4.13 5.05 4.65 4.98 5.61 5.18 5.43 4.91 4.52 Field Redox mV NE NE NE 47.4 92.1 -81.3 141.6 92.7 113.4 95.8 79.8 85.0 71.4 98.9 119.7 Field Specific Conductance umhos/cm NE NE NE 75.1 182.1 198.6 39.9 209.0 132.7 93.4 90.2 188.8 66.8 89.9 89.3 Field Temperature °C NE NE NE 15.2 17.9 18.6 19.3 19.2 18.4 17.7 15.0 18.0 16.2 15.6 16.5 Field Turbidity NTU NE NE NE 1.02 0.46 0.62 0.85 0.50 1.06 2.06 1.82 1.26 1.27 0.22 0.50 1,4-Dichlorobenzene u /L 6 0.33 1 <1 2.8 <1 <1 0.36 J <1 <1 <1 <1 <1 <1 <1 Benzene ug/L 1 0.34 1 <1 3.5 <1 <1 0.82 J <1 <1 <1 <1 <1 <1 <1 For VOCs, only constituents with one or more detections above a PQL are included on table. NE: Denotes a NC 2L Standard is not established. J: Denotes Sample result above the MDL but below the PQL; estimated value; val t be accurate. Denotes a concentration at or above a PQL is also above a NC 2L Standard: Denotes a concentration is above a NC 2L Standard, but below the PQL: NS: Denotes not required to be sampled. TABLE 3 SURFACE WATER ANALYTICAL DATA SUMMARY FIRST SEMI-ANNUAL 2024 EVENT FOOTHILLS REGIONAL LANDFILL Constituent Units NC 2B Std MDL PQL SW-1 SW-2 SW-3 SW-4 SW-5 Antimony Total ug/L 640 0.54 6 <6 <6 <6 1.3 J <6 Arsenic Total ug/L 10 0.84 10 <10 <10 <10 <10 <10 Barium Total ug/L 21,000 0.47 100 27 J 34.2 J 30.4 J 47.4 J 26.7 J Beryllium Total ug/L 6.5 0.094 1 0.17 J 0.23 J 0.13 J 0.37 J 0.17 J Cadmium Total ug/L NE 0.1 1 <1 <1 <1 <1 <1 Chromium Total ug/L NE 1.9 10 2.6 J 3.3 J 3.5 J 5.9 J 2.5 J Cobalt Total ug/L 4 0.32 10 1.1 J 1.4 J 1.2 J 2.4 J 1.1 J Copper Total ug/L NE 0.43 10 2.2 J 2.9 J 2.7 J 5.9 J 2.2 J Lead Total ug/L NE 0.16 10 1.6 J 2.1 J 1.5 J 3.4 J 1.6 J Nickel Total ug/L NE 2.1 50 <50 <50 <50 2.7 J <50 Selenium Total ug/L 5 0.96 10 <10 <10 <10 <10 <10 Silver Total ug/L 0.06 0.31 10 <10 <10 <10 <10 <10 Thallium Total ug/L 0.47 0.38 5.5 <5.5 <5.5 <5.5 <5.5 <5.5 Vanadium Total ug/L NE 0.75 25 6.9 J 8.4 J 8.3 J 13.9 J 5.6 J Zinc Total ug/L NE 2.4 10 4.2 J 5.1 J 5.1 J 13.1 3.8 J Field Dissolved Oxygen mg/L NE NE NE 3.75 3.96 5.26 5.18 4.12 Field pH SU NE NE NE 5.90 6.21 6.89 7.04 6.08 Field Redox mV NE NE NE 63.6 31.3 -6.2 -14.0 50.6 Field Specific Conductance umhos/cm NE NE NE 66.2 71.3 51.0 53.9 140.2 Field Temperature °C NE NE NE 19.1 20.2 18.5 18.8 18.5 Field Turbidity NTU NE NE NE 44.9 55.4 60.3 89.2 36.2 J: Denotes sample result above the MDL but below the PQL; estimated value; value may not be accurate. NE: Denotes a NC 2B Standard is not established. No VOCs detected above a PQL, therefore not included on this table. Denotes a concentration is above the NC 2B Standard, but but below the PQL: Denotes a concentration at or above a PQL is also above a NC 2B Standard: TABLE 4 UNDERDRAIN ANALYTICAL DATA SUMMARY FIRST SEMI-ANNUAL 2024 EVENT FOOTHILLS REGIONAL LANDFILL Constituent Units MDL PQL UD-1 UD-2 Antimony Total ug/L 0.54 6 <6 <6 Arsenic Total ug/L 0.84 10 0.86 J 1.1 J Barium Total ug/L 0.47 100 73.4 J 58.2 J Beryllium Total ug/L 0.094 1 <1 <1 Cadmium Total ug/L 0.1 1 <1 <1 Chromium Total ug/L 1.9 10 <10 <10 Cobalt Total ug/L 0.32 10 8.1 J 6.2 J Copper Total ug/L 0.43 10 <10 0.62 J Lead Total ug/L 0.16 10 0.28 J 0.33 J Nickel Total ug/L 2.1 50 <50 <50 Selenium Total ug/L 0.96 10 <10 <10 Silver Total ug/L 0.31 10 <10 <10 Thallium Total ug/L 0.38 5.5 <5.5 <5.5 Vanadium Total ug/L 0.75 25 2.5 J 3.5 J Zinc Total ug/L 2.4 10 <10 2.5 J Field Dissolved Oxygen mg/L NE NE 3.66 3.42 Field pH SU NE NE 5.18 5.49 Field Redox mV NE NE 86.6 70.9 Field Specific Conductance umhos/cm NE NE 222 208 Field Temperature °C NE NE 18.1 17.9 Field Turbidity NTU NE NE 8.57 7.02 J: Denotes sample result above the MDL but below the PQL; estimated value; value may not be accurate. NE: Not established. TABLE 5 LEACHATE ANALYTICAL DATA SUMMARY FIRST SEMI-ANNUAL 2024 EVENT FOOTHILLS REGIONAL LANDFILL Indicator Parameters Units MDL PQL Leachate Antimony, Total u /L 2.7 30 95.9 Arsenic, Total ug/L 4.2 50 176 Barium, Total u /L 2.3 500 558 Beryllium, Total ug/L 0.47 5 <5 Biochemical Oxygen Demand, 5-Da u /L 2000 2000 2620000 Cadmium, Total ug/L 0.51 5 <5 Chemical Oxygen Demand u /L 25000 50000 5290000 Chromium, Total ug/L 9.4 50 337 Cobalt, Total u /L 1.6 50 39.7 J Copper, Total ug/L 2.1 50 20 J Lead, Total u /L 0.82 50 2.1 J Nickel, Total ug/L 10.3 250 175 J Nitrogen, Nitrate u /L 3.9 20 5 J Nitrogen, Nitrite ug/L 1.2 20 37.9 Phosphorus, Total u /L 7.5 150 7740 Selenium, Total ug/L 4.8 50 8.1 J Silver, Total u /L 1.5 50 <50 Sulfate u /L 10000 20000 <20000 Thallium, Total u /L 1.9 27.5 <27.5 Vanadium, Total ug/L 3.8 125 60.9 J Zinc, Total u /L 12 50 148 Field pH SU NE NE 7.37 Field Specific Conductance umhos/cm NE NE 17,210 Field Temperature °C NE NE 22.1 Field Turbidity NTU NE NE 68.20 1,4-Dioxane (p-Dioxane) ug/L 4.3 10 150 2-Butanone u /L 198 5000 7300 Acetone ug/L 256 5000 12400 Eth (benzene u /L 15.2 50 54.1 For Organics, only constituents with detections above a PQL are included on table. J: Denotes Sample result above the MDL but below the PQL; estimated value; value may not be accurate. APPENDICES APPENDIX A POTENTIOMETRIC SURFACE MAP &SW-1 MW-8 `-8 167.48 \ IIII\MW-7� 1153.90 �--� .fir UD-2 MW-6 1133.93 o I MW-5 1127.68— a rmw-4 1129.99 UD-1 M A�?" STING ` NO. 8A 0 �p0-' `EXISTING O x�,ELL NO. o ,. iv 6O �310 11250 � XG ELL NO. 1 B 3B 1188.21-- / 2.00 —� BMW-3R2 0 �1200.63 m MW-3R 1183.88� �� 2J \ 0 121p &SW-3 1 / \_ f NORTH 0 100 200 400 800 Scale in Feet Graphic Scale: 1 inch = 400 feet �S\� 1492.0 450 MW-12 1360.67 J 13� N L LL 6 _: V'\'N MW-11 1318.33 EXISTI CELL NO. 5 (UNDE ) STRUC ION)NW-10 1279.18 IN 1 Cr_`Cnln Ila 1 SMW-7 Monitoring Well Location L) SUD-1 Underdrain Location 1153.90 Groundwater Elevation (fmsl) —1300— Potentiometric Surface Contour (fmsl) 1111 Hydraulic Gradient & Inferred - om8i Groundwater Flow Direction SW-1 Surface Water Sampling Location (Approx) Landfill Cell Boundary ftIIIIIII,ftw0000 LFG Trench (Approx) Water levels collected by Environmental Sampling & Services, Inc. on May 6, 2024. Basemap provided by Joyce Engineering, with topographic survey completed by Cooper Aerial Surveys Co., date of Photography is January 20, 2014. JETT Figure 1 SSLexingt31 Oaks Court First Semi -Annual 2024 Event Potentiometric Surface Map Forlstell, MO 63348 314 nviro. om J '4'0" E OVNRUwY►fYtl J IrN� www.jettenvlro.com Foothills Regional Landfill, Caldwell County, North Carolina Groundwater Elevation Summary Table Foothills Regional Landfill Well Top of PVC Casing Elevation (fmsl)' 2 Depth to Water (ft) Groundwater Elevation (fmsl) MW-1 R2 1516.22 24.18 1492.04 MW-2R 1253.36 51.69 1201.67 MW-3 1241.95 53.74 1188.21 MW-3R 1242.69 58.81 1183.88 MW-3R2 1240.83 40.20 1200.63 MW-4 1171.18 41.19 1129.99 MW-5 1175.07 47.39 1127.68 MW-6 1176.82 42.89 1133.93 MW-7 1183.13 29.23 1153.90 MW-8 1195.18 27.70 1167.48 MW-9 1290.79 70.70 1220.09 MW-10 1358.53 79.35 1279.18 MW-11 1401.71 83.38 1318.33 MW-12 1459.23 98.56 1360.67 Note 1: Top of PVC Casing Elevations from Table 1 of the Water Quality Monitoring Plan dated March 20, 2019 by BLE, with exception of MW-12, which was provided in the MW-12 Well Installation Report dated November 15, 2023 by BLE. Note 2: Depth to water measured by Environmental Sampling & Services, Inc. on May 6, 2024. Groundwater Flow Velocity Calculations Foothills Regional Landfill First Semi -Annual 2024 Event Velocity V = [(k)(i)]/(n) V = [(0.374 ft/day)(0.1181 ft/ft)] / 0.1 V = 0.442 ft/day V = 161 ft/year Where, Hydraulic conductivity (k) and effective porosity (n) values from the following document: Table 2 of the Second Semi -Annual Water Quality Monitoring Report of 2017, dated November 17, 2017 by Joyce Engineering. Gradient (i) is from the average gradient at site using the potentiometric surface map from Point A to Point B. Gradient (i) = Change in Groundwater Elevation along Flow Path is From Point A (1450 contour) to Point 8 (1150 contour) = 300 ft / 2,541 ft = 0.1181 ft/ft APPENDIX B STATISTICAL EVALUATIONS Prediction Limit Foothills Client: RSI Data: Foothills Printed 8/8/2024, 9:51 AM Constituent Well Uooer Lim. Lower Lim. Date Observ. Sig. Ba N Ba Mean Std. Dev. % NDs ND Ad. Transform Alpha Method Cobalt Total (ug/L) MW-4 10.0 n/a 5/6/2024 15.6 Yes 55 n/a n/a 94.55 n/a n/a 0.0006217 NP Inter (NDs) 1 of 2 Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Exceeds Limit: MW-4 30 24 18 12 A 0 4- 7/19/99 Prediction Limit Interwell Non -parametric 7/3/04 6/19/09 6/4/14 5/21 /19 5/6/24 ♦ MW-4 Limit = 10.0 Non -parametric test used in lieu of parametric prediction limit because censored data exceeded 50%. Limit is highest of 55 background values. 94.55% NDs. Annual per -constituent alpha = 0.01359. Individual comparison alpha = 0.0006217 (1 of 2). Assumes 10 future values. After outlier removal distribution was non -normal, so outlier results were invalidated. Constituent: Cobalt Total Analysis Run 8/8/2024 9:50 AM View: PL Foothills Client: RSI Data: Foothills Confidence Interval Foothills Client: RSI Data: Foothills Printed 8/8/2024, 9:59 AM Constituent Well Upper Lim. Lower Lim. Compliance Sic. N Mean Std. Dev. %NDs ND Adm. Transform Alpha Method Benzene (ug/L) MW-2R 3.927 2.623 1 Yes 4 3.275 0.2872 0 None No 0.01 Param. Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Parametric Confidence Interval Compliance limit is exceeded. Per -well alpha = 0.01. Normality Test: Shapiro Wilk, alpha based on n. 5 4 3 2 J � 1 [II Constituent: Benzene Analysis Run 8/8/2024 9:58 AM View: Cl Foothills Client: RSI Data: Foothills Confidence Interval Constituent: Benzene (ug/L) Analysis Run 8/8/2024 10:09 AM View: CI Foothills Client: RSI Data: Foothills MW-2R 7/28/2016 1 1 /26/2017 1.6 2/28/2017 1.6 5/23/2017 1.7 7/27/2017 1.9 1/29/2018 2.6 7/23/2018 2 10/8/2018 2.1 1 /28/2019 1.6 7/25/2019 1.8 1/27/2020 2.2 7/27/2020 2.1 2/1/2021 2 7/26/2021 2.5 1/26/2022 2.4 7/26/2022 3.2 2/6/2023 2.9 11/27/2023 3.5 5/6/2024 3.5 Mean 2.221 Std. Dev. 0.6779 Upper Lim. 2.618 Lower Lim. 1.824 TIME SERIES TREND ANALYSIS Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 6 4.8 3.6 J 0) Z3 2.4 1.2 0 1 /6/09 Time Series MW-1 (bg) MW-10 MW-1 R (bg) IVI VV-/-M MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) MW-12 1 /30/12 2/23/15 3/19/18 4/12/21 5/6/24 Constituent: Antimony Total Analysis Run 8/8/2024 10:07 AM View: TS Metals Foothills Client: RSI Data: Foothills Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 20 16 12 J 8 4 0 kx7 F7 1 ` 8/10/98 10/3/03 11 /25/08 1 /18/14 3/13/19 5/6/24 MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) IVI VV-/-M MW-3R2 MW-4 ♦ MW-5 ■ MW-6 MW-7 MW-8 MW-11 ♦ MW-1 R2 (bg) MW-12 Constituent: Arsenic Total Analysis Run 8/8/2024 10:07 AM View: TS Metals Foothills Client: RSI Data: Foothills Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 700 560 420 J a 280 140 Time Series 10/3/03 11/25/08 1/18/14 3/13/19 5/6/24 Constituent: Barium Total Analysis Run 8/8/2024 10:07 AM View: TS Metals Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) IVI VV-/-M MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) MW-12 Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 8/10/98 Time Series 10/3/03 11 /25/08 1 /18/14 3/13/19 5/6/24 MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) IVI VV-/-M MW-3R2 MW-4 ♦ MW-5 ■ MW-6 MW-7 MW-8 MW-11 ♦ MW-1 R2 (bg) MW-12 Constituent: Beryllium Total Analysis Run 8/8/2024 10:07 AM View: TS Metals Foothills Client: RSI Data: Foothills Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 5 4 3 J 2 1NIX 0 8/10/98 10/3/03 11 /25/08 1 /18/14 3/13/19 5/6/24 MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) IVI VV-/-M MW-3R2 MW-4 ♦ MW-5 ■ MW-6 MW-7 MW-8 MW-11 ♦ MW-1 R2 (bg) MW-12 Constituent: Cadmium Total Analysis Run 8/8/2024 10:07 AM View: TS Metals Foothills Client: RSI Data: Foothills Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 40 32 24 J a� 16 8 Un a JI! ■ 8/10/98 10/3/03 11 /25/08 1 /18/14 3/13/19 5/6/24 Constituent: Chromium Total Analysis Run 8/8/2024 10:07 AM View: TS Metals Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) IVI VV-/-M MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) MW-12 Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 30 24 18 J a� 12 6 Time Series 10/3/03 11 /25/08 1 /18/14 3/13/19 5/6/24 Constituent: Cobalt Total Analysis Run 8/8/2024 10:07 AM View: TS Metals Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) IVI VV-/-M MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) MW-12 Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 500 400 300 J 0) Z3 200 100 Time Series 10/3/03 11 /25/08 1 /18/14 3/13/19 5/6/24 Constituent: Copper Total Analysis Run 8/8/2024 10:08 AM View: TS Metals Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) IVI VV-/-M MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) MW-12 Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 30 24 18 J a� 12 6 Time Series 10/3/03 11 /25/08 1 /18/14 3/13/19 5/6/24 Constituent: Lead Total Analysis Run 8/8/2024 10:08 AM View: TS Metals Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) IVI VV-/-M MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) MW-12 Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 50 40 30 - J 20 10 0 8/10/98 10/3/03 11 /25/08 1 /18/14 3/13/19 5/6/24 ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) IVI VV-/-M MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 MW-7 MW-8 ♦ MW-11 ♦ MW-1 R2 (bg) MW-12 Constituent: Nickel Total Analysis Run 8/8/2024 10:08 AM View: TS Metals Foothills Client: RSI Data: Foothills Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 30 24 18 J a� 12 6 Time Series 8/10/98 10/3/03 11 /25/08 1 /18/14 3/13/19 5/6/24 Constituent: Selenium Total Analysis Run 8/8/2024 10:08 AM View: TS Metals Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) IVI VV-/-M MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) MW-12 Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 50 40 30 J a 20 10 Time Series MW-1 (bg) MW-10 MW-1 R (bg) ivM MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) MW-12 8/10/98 10/3/03 11 /25/08 1 /18/14 3/13/19 5/6/24 Constituent: Silver Total Analysis Run 8/8/2024 10:08 AM View: TS Metals Foothills Client: RSI Data: Foothills Sanitas'" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 1 •. Time Series 10/3/03 11 /25/08 1 /18/14 3/13/19 5/6/24 MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) IVI VV-/-M MW-3R2 MW-4 ♦ MW-5 ■ MW-6 MW-7 ♦ MW-8 MW-11 ♦ MW-1 R2 (bg) MW-12 Constituent: Thallium Total Analysis Run 8/8/2024 10:08 AM View: TS Metals Foothills Client: RSI Data: Foothills Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 60 48 36 J a� 24 12 Time Series 10/3/03 11 /25/08 1 /18/14 3/13/19 5/6/24 Constituent: Vanadium Total Analysis Run 8/8/2024 10:08 AM View: TS Metals Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) IVI VV-/-M MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) MW-12 Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 200 160 120 J 80 40 Time Series MW-1 (bg) MW-10 MW-1 R (bg) IVI VV-/-M MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) MW-12 8/10/98 10/3/03 11 /25/08 1 /18/14 3/13/19 5/6/24 Constituent: Zinc Total Analysis Run 8/8/2024 10:08 AM View: TS Metals Foothills Client: RSI Data: Foothills Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 5 4 3 J a� 2 1 0 1 /6/09 Time Series 1 /30/12 2/23/15 3/19/18 4/12/21 5/6/24 Constituent: 11-Dichloroethane Analysis Run 8/8/2024 10:05 AM View: TS VOCs Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) IVI VV-/-M MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) MW-12 Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 10 8 6 J a� 4 2 '-XDOCH" il, 0 1 /6/09 1 /30/12 2/23/15 3/19/18 4/12/21 5/6/24 MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) IVI VV-/-M MW-3R2 MW-4 ♦ MW-5 ■ MW-6 MW-7 MW-8 MW-11 ♦ MW-1 R2 (bg) MW-12 Constituent: 14-Dichlorobenzene Analysis Run 8/8/2024 10:05 AM View: TS VOCs Foothills Client: RSI Data: Foothills Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 5 4 3 J 2 1 � r� 0 8/10/98 10/3/03 11 /25/08 1 /18/14 3/13/19 5/6/24 MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) IVI VV-/-M MW-3R2 MW-4 ♦ MW-5 ■ MW-6 MW-7 ♦ MW-8 MW-11 ♦ MW-1 R2 (bg) MW-12 Constituent: Benzene Analysis Run 8/8/2024 10:05 AM View: TS VOCs Foothills Client: RSI Data: Foothills Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 3 2.4 1.8 J 0) 1.2 0.6 0 1 /6/09 1 /30/12 2/23/15 3/19/18 4/12/21 5/6/24 MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) IVI VV-/-M MW-3R2 MW-4 ♦ MW-5 ■ MW-6 MW-7 ♦ MW-8 MW-11 ♦ MW-1 R2 (bg) MW-12 Constituent: Chlorobenzene Analysis Run 8/8/2024 10:05 AM View: TS VOCs Foothills Client: RSI Data: Foothills Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 5 4 3 J a� 2 1 0 1 /6/09 Time Series 1 /30/12 2/23/15 3/19/18 4/12/21 5/6/24 MW-1 (bg) MW-10 MW-1 R (bg) IVI VV-/-M MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) MW-12 Constituent: cis- 1 2-Dichloroethene Analysis Run 8/8/2024 10:05 AM View: TS VOCs Foothills Client: RSI Data: Foothills Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 5 4--7 3 J 2 1 :r� 0 8/10/98 10/3/03 11 /25/08 1 /18/14 3/13/19 5/6/24 MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) IVI VV-/-M MW-3R2 MW-4 ♦ MW-5 ■ MW-6 MW-7 MW-8 MW-11 ♦ MW-1 R2 (bg) MW-12 Constituent: Tetrachloroethene Analysis Run 8/8/2024 10:05 AM View: TS VOCs Foothills Client: RSI Data: Foothills Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 0 4- 1 /6/09 Time Series 1 /30/12 2/23/15 3/19/18 4/12/21 5/6/24 MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) IVI VV-/-M MW-3R2 MW-4 ♦ MW-5 ■ MW-6 MW-7 MW-8 MW-11 ♦ MW-1 R2 (bg) MW-12 Constituent: Toluene Analysis Run 8/8/2024 10:05 AM View: TS VOCs Foothills Client: RSI Data: Foothills Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 M W-4 MW-5 MW-6 MW-7 M W-8 MW-11 MW-1 R2 (bg) MW-12 0 4- 1 /6/09 1 /30/12 2/23/15 3/19/18 4/12/21 5/6/24 Constituent: Trichloroethene Analysis Run 8/8/2024 10:05 AM View: TS VOCs Foothills Client: RSI Data: Foothills Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series MW-1 (bg) MW-10 MW-1 R (bg) IVI VV-/-M MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) MW-12 0 4- 1 /6/09 1 /30/12 2/23/15 3/19/18 4/12/21 5/6/24 Constituent: Vinyl chloride Analysis Run 8/8/2024 10:05 AM View: TS VOCs Foothills Client: RSI Data: Foothills Sanitas" v.10.0.20 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 4 3 J a� 2 1 0 1 /6/09 1 /30/12 2/23/15 3/19/18 4/12/21 5/6/24 MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) IVI VV-/-M MW-3R2 MW-4 ♦ MW-5 ■ MW-6 MW-7 ♦ MW-8 MW-11 ♦ MW-1 R2 (bg) MW-12 Constituent: Xylenes [Total] Analysis Run 8/8/2024 10:05 AM View: TS VOCs Foothills Client: RSI Data: Foothills APPENDIX C LABORATORY ANALYTICAL REPORTS FIELD SAMPLING FORMS ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 May 21, 2024 Environmental Manager Foothills Environmental Landfill 2800 Cheraw Road Lenoir, NC 28645 RE: Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Dear Environmental Manager: Enclosed are the analytical results for sample(s) received by the laboratory on May 07, 2024. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Charlotte • Pace Analytical Services - Peachtree Corners, GA If you have any questions concerning this report, please feel free to contact me. Sincerely, 01A-i'l -�--� Maiya Parks maiya.parks@pacelabs.com 770-734-4205 Project Manager Enclosures cc: Data Manager, TriHydro Corporation REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 99 Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Peachtree Corners 110 Technology Pkwy, Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 North Carolina Certification #: 381 South Carolina Certification #: 98011001 Virginia Certification #: 460204 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Lab ID Sample ID Matrix Date Collected Date Received 92729146001 1403-MW-1 R2 Water 05/06/24 07:30 05/07/24 09:57 92729146002 1403-MW-3R2 Water 05/06/24 14:10 05/07/24 09:57 92729146003 1403-MW-4 Water 05/06/24 13:17 05/07/24 09:57 92729146004 1403-DUP@MW-4 Water 05/06/24 13:19 05/07/24 09:57 92729146005 1403-MW-5 Water 05/06/24 12:29 05/07/24 09:57 92729146006 1403-MW-6 Water 05/06/24 11:41 05/07/24 09:57 92729146007 1403-MW-7 Water 05/06/24 10:52 05/07/24 09:57 92729146008 1403-MW-8 Water 05/06/24 10:04 05/07/24 09:57 92729146009 1403-MW-9 Water 05/06/24 09:13 05/07/24 09:57 92729146010 1403-MW-10 Water 05/06/24 08:25 05/07/24 09:57 92729146011 1403-MW-11 Water 05/06/24 06:34 05/07/24 09:57 92729146012 1403-MW-12 Water 05/06/24 05:46 05/07/24 09:57 92729146013 1403-Field Blank Water 05/05/24 15:32 05/07/24 09:57 92729146014 1403-SW1 Water 05/05/24 15:38 05/07/24 09:57 92729146015 1403-SW2 Water 05/05/24 16:35 05/07/24 09:57 92729146016 1403-SW3 (MS/MSD) Water 05/05/24 17:40 05/07/24 09:57 92729146017 1403-SW4 Water 05/05/24 17:18 05/07/24 09:57 92729146018 1403-SW5 Water 05/05/24 16:54 05/07/24 09:57 92729146019 1403-UD1 Water 05/05/24 16:17 05/07/24 09:57 92729146020 1403-UD2 Water 05/05/24 15:58 05/07/24 09:57 92729146021 1403-Trip Blank Water 05/05/24 15:34 05/07/24 09:57 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Foothills LF/Semi-Annual 92729146 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92729146001 1403-MW-1 R2 EPA 6020E MT1 15 PASI-GA EPA 8260D JJK 50 PASI-C 92729146002 1403-MW-3R2 EPA 6020E MT1 15 PASI-GA EPA 8260D JJK 50 PASI-C 92729146003 1403-MW-4 EPA 6020E MT1 15 PASI-GA EPA 8260D JJK 50 PASI-C 92729146004 1403-DUP@MW-4 EPA 6020E MT1 15 PASI-GA EPA 8260D JJK 50 PASI-C 92729146005 1403-MW-5 EPA 6020E MT1 15 PASI-GA EPA 8260D JJK 50 PASI-C 92729146006 1403-MW-6 EPA 6020E MT1 15 PASI-GA EPA 8260D JJK 50 PASI-C 92729146007 1403-MW-7 EPA 6020E MT1 15 PASI-GA EPA 8260D JJK 50 PASI-C 92729146008 1403-MW-8 EPA 6020E MT1 15 PASI-GA EPA 8260D JJK 50 PASI-C 92729146009 1403-MW-9 EPA 6020E MT1 15 PASI-GA EPA 8260D JJK 50 PASI-C 92729146010 1403-MW-10 EPA 6020E MT1 15 PASI-GA EPA 8260D JJK 50 PASI-C 92729146011 1403-MW-11 EPA 6020E MT1 15 PASI-GA EPA 8260D JJK 50 PASI-C 92729146012 1403-MW-12 EPA 6020E MT1 15 PASI-GA EPA 8260D JJK 50 PASI-C 92729146013 1403-Field Blank EPA 6020E MT1 15 PASI-GA EPA 8260D JJK 50 PASI-C 92729146014 1403-SW1 EPA 6020E MT1 15 PASI-GA EPA 8260D JJK 50 PASI-C 92729146015 1403-SW2 EPA 6020E MT1 15 PASI-GA EPA 8260D JJK 50 PASI-C 92729146016 1403-SW3 (MS/MSD) EPA 6020E MT1 15 PASI-GA EPA 8260D TMH 50 PASI-C 92729146017 1403-SW4 EPA 6020E MT1 15 PASI-GA EPA 8260D TMH 50 PASI-C 92729146018 1403-SW5 EPA 6020E MT1 15 PASI-GA EPA 8260D TMH 50 PASI-C 92729146019 1403-UD1 EPA 6020E MT1 15 PASI-GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Foothills LF/Semi-Annual 92729146 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 8260D TMH 50 PASI-C 92729146020 1403-UD2 EPA 6020E MT1 15 PASI-GA EPA 8260D TMH 50 PASI-C 92729146021 1403-Trip Blank EPA 8260D TMH 50 PASI-C PASI-C = Pace Analytical Services - Charlotte PASI-GA = Pace Analytical Services - Peachtree Corners, GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: Foothills LF/Semi-Annual 92729146 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92729146001 1403-MW-1 R2 Performed by ES&S 05/06/24 07:30 pH 6.26 Std. Units 05/06/24 07:30 Temperature 15.2 deg C 05/06/24 07:30 Static Water Level 24.30 feet 05/06/24 07:30 Specific Conductance 75.1 umhos/cm 05/06/24 07:30 Oxidation Potential 47.4 mV 05/06/24 07:30 Oxygen, Dissolved 2.31 mg/L 05/06/24 07:30 Total Well Depth 43.34 feet 05/06/24 07:30 Turbidity 1.02 NTU 05/06/24 07:30 EPA 6020B Barium 48.3J ug/L 100 05/14/24 16:30 92729146002 1403-MW-3R2 Performed by ES&S 05/06/24 14:10 pH 8.30 Std. Units 05/06/24 14:10 Temperature 18.6 deg C 05/06/24 14:10 Static Water Level 40.36 feet 05/06/24 14:10 Specific Conductance 198.6 umhos/cm 05/06/24 14:10 Oxidation Potential -81.3 mV 05/06/24 14:10 Oxygen, Dissolved 3.46 mg/L 05/06/24 14:10 Total Well Depth 73.91 feet 05/06/24 14:10 Turbidity 0.62 NTU 05/06/24 14:10 EPA 6020B Antimony 0.61 J ug/L 6.0 05/14/24 16:34 EPA 6020B Barium 4.9J ug/L 100 05/14/24 16:34 EPA 6020B Vanadium 1.1 J ug/L 25.0 05/14/24 16:34 92729146003 1403-MW-4 Performed by ES&S 05/06/24 13:17 pH 4.13 Std. Units 05/06/24 13:17 Temperature 19.3 deg C 05/06/24 13:17 Static Water Level 41.30 feet 05/06/24 13:17 Specific Conductance 39.9 umhos/cm 05/06/24 13:17 Oxidation Potential 141.6 mV 05/06/24 13:17 Oxygen, Dissolved 1.95 mg/L 05/06/24 13:17 Total Well Depth 52.20 feet 05/06/24 13:17 Turbidity 0.85 NTU 05/06/24 13:17 EPA 6020B Barium 47.1 J ug/L 100 05/14/24 16:38 EPA 6020B Cobalt 15.6 ug/L 10.0 05/14/24 16:38 EPA 6020B Zinc 2AJ ug/L 10.0 05/14/24 16:38 92729146004 1403-DUP@MW-4 EPA 6020B Barium 46.8J ug/L 100 05/14/24 16:41 EPA 6020B Cobalt 15.4 ug/L 10.0 05/14/24 16:41 EPA 6020B Zinc 2.5J ug/L 10.0 05/14/24 16:41 92729146005 1403-MW-5 Performed by ES&S 05/06/24 12:29 pH 5.05 Std. Units 05/06/24 12:29 Temperature 19.2 deg C 05/06/24 12:29 Static Water Level 47.50 feet 05/06/24 12:29 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92729146005 1403-MW-5 Specific Conductance 209 umhos/cm 05/06/24 12:29 Oxidation Potential 92.7 mV 05/06/24 12:29 Oxygen, Dissolved 2.73 mg/L 05/06/24 12:29 Total Well Depth 54.50 feet 05/06/24 12:29 Turbidity 0.50 NTU 05/06/24 12:29 EPA 6020B Arsenic 1.0J ug/L 10.0 05/14/24 16:45 EPA 6020B Barium 149 ug/L 100 05/14/24 16:45 EPA 6020B Vanadium 3.5J ug/L 25.0 05/14/24 16:45 EPA 8260D Benzene 0.82J ug/L 1.0 05/09/24 05:50 EPA 8260D 1,4-Dichlorobenzene 0.36J ug/L 1.0 05/09/24 05:50 EPA 8260D cis-1,2-Dichloroethene 2.OJ ug/L 5.0 05/09/24 05:50 92729146006 1403-MW-6 Performed by ES&S 05/06/24 11:41 pH 4.65 Std. Units 05/06/24 11:41 Temperature 18.4 deg C 05/06/24 11:41 Static Water Level 43.01 feet 05/06/24 11:41 Specific Conductance 132.7 umhos/cm 05/06/24 11:41 Oxidation Potential 113.4 mV 05/06/24 11:41 Oxygen, Dissolved 2.80 mg/L 05/06/24 11:41 Total Well Depth 50.55 feet 05/06/24 11:41 Turbidity 1.06 NTU 05/06/24 11:41 EPA 6020B Barium 140 ug/L 100 05/14/24 16:49 EPA 6020B Beryllium 0.29J ug/L 1.0 05/14/24 16:49 EPA 6020B Cadmium 0.13J ug/L 1.0 05/14/24 16:49 EPA 6020B Cobalt 5AJ ug/L 10.0 05/14/24 16:49 92729146007 1403-MW-7 Performed by ES&S 05/06/24 10:52 pH 4.98 Std. Units 05/06/24 10:52 Temperature 17.7 deg C 05/06/24 10:52 Static Water Level 29.35 feet 05/06/24 10:52 Specific Conductance 93.4 umhos/cm 05/06/24 10:52 Oxidation Potential 95.8 mV 05/06/24 10:52 Oxygen, Dissolved 4.05 mg/L 05/06/24 10:52 Total Well Depth 40.13 feet 05/06/24 10:52 Turbidity 2.06 NTU 05/06/24 10:52 EPA 6020B Antimony 0.55J ug/L 6.0 05/14/24 16:52 EPA 6020B Barium 24.6J ug/L 100 05/14/24 16:52 EPA 6020B Beryllium 0.10J ug/L 1.0 05/14/24 16:52 EPA 6020B Vanadium 1.5J ug/L 25.0 05/14/24 16:52 92729146008 1403-MW-8 Performed by ES&S 05/06/24 10:04 pH 5.61 Std. Units 05/06/24 10:04 Temperature 15.0 deg C 05/06/24 10:04 Static Water Level 27.84 feet 05/06/24 10:04 Specific Conductance 90.2 umhos/cm 05/06/24 10:04 Oxidation Potential 79.8 mV 05/06/24 10:04 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: Foothills LF/Semi-Annual 92729146 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92729146008 1403-MW-8 Oxygen, Dissolved 2.09 mg/L 05/06/24 10:04 Total Well Depth 49.56 feet 05/06/24 10:04 Turbidity 1.82 NTU 05/06/24 10:04 EPA 6020B Barium 68.1 J ug/L 100 05/14/24 16:56 EPA 6020B Vanadium 1.2J ug/L 25.0 05/14/24 16:56 92729146009 1403-MW-9 Performed by ES&S 05/06/24 09:13 pH 5.18 Std. Units 05/06/24 09:13 Temperature 18.0 deg C 05/06/24 09:13 Static Water Level 70.83 feet 05/06/24 09:13 Specific Conductance 188.8 umhos/cm 05/06/24 09:13 Oxidation Potential 85.0 mV 05/06/24 09:13 Oxygen, Dissolved 3.12 mg/L 05/06/24 09:13 Total Well Depth 73.40 feet 05/06/24 09:13 Turbidity 1.26 NTU 05/06/24 09:13 EPA 6020B Arsenic 1.6J ug/L 10.0 05/14/24 17:10 EPA 6020B Barium 8.3J ug/L 100 05/14/24 17:10 EPA 6020B Cobalt 0.36J ug/L 10.0 05/14/24 17:10 EPA 6020B Vanadium 2.1 J ug/L 25.0 05/14/24 17:10 92729146010 1403-MW-10 Performed by ES&S 05/06/24 08:25 pH 5.43 Std. Units 05/06/24 08:25 Temperature 16.2 deg C 05/06/24 08:25 Static Water Level 79.47 feet 05/06/24 08:25 Specific Conductance 66.8 umhos/cm 05/06/24 08:25 Oxidation Potential 71.4 mV 05/06/24 08:25 Oxygen, Dissolved 4.42 mg/L 05/06/24 08:25 Total Well Depth 88.21 feet 05/06/24 08:25 Turbidity 1.27 NTU 05/06/24 08:25 EPA 6020B Barium 33.3J ug/L 100 05/14/24 17:14 EPA 6020B Vanadium 5.6J ug/L 25.0 05/14/24 17:14 92729146011 1403-MW-11 Performed by ES&S 05/06/24 06:34 pH 4.91 Std. Units 05/06/24 06:34 Temperature 15.6 deg C 05/06/24 06:34 Static Water Level 83.52 feet 05/06/24 06:34 Specific Conductance 89.9 umhos/cm 05/06/24 06:34 Oxidation Potential 98.9 mV 05/06/24 06:34 Oxygen, Dissolved 2.03 mg/L 05/06/24 06:34 Total Well Depth 108.40 feet 05/06/24 06:34 Turbidity 0.22 NTU 05/06/24 06:34 EPA 6020B Arsenic 0.92J ug/L 10.0 05/14/24 17:17 EPA 6020B Barium 124 ug/L 100 05/14/24 17:17 EPA 6020B Copper 0.43J ug/L 10.0 05/14/24 17:17 EPA 6020B Vanadium 1.6J ug/L 25.0 05/14/24 17:17 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92729146012 1403-MW-12 Performed by ES&S 05/06/24 05:46 pH 4.52 Std. Units 05/06/24 05:46 Temperature 16.5 deg C 05/06/24 05:46 Static Water Level 98.70 feet 05/06/24 05:46 Specific Conductance 89.3 umhos/cm 05/06/24 05:46 Oxidation Potential 119.7 mV 05/06/24 05:46 Oxygen, Dissolved 2.05 mg/L 05/06/24 05:46 Total Well Depth 131.65 feet 05/06/24 05:46 Turbidity 0.50 NTU 05/06/24 05:46 EPA 6020B Barium 24AJ ug/L 100 05/14/24 17:21 EPA 6020B Vanadium 1.7J ug/L 25.0 05/14/24 17:21 92729146013 1403-Field Blank EPA 6020B Vanadium 1.5J ug/L 25.0 05/14/24 17:25 92729146014 1403-SW1 Performed by ES&S 05/06/24 15:38 pH 5.90 Std. Units 05/06/24 15:38 Temperature 19.1 deg C 05/06/24 15:38 Specific Conductance 66.2 umhos/cm 05/06/24 15:38 Oxidation Potential 63.6 mV 05/06/24 15:38 Oxygen, Dissolved 3.75 mg/L 05/06/24 15:38 Turbidity 44.90 NTU 05/06/24 15:38 EPA 6020B Barium 27.OJ ug/L 100 05/14/24 17:28 EPA 6020B Beryllium 0.17J ug/L 1.0 05/14/24 17:28 EPA 6020B Chromium 2.6J ug/L 10.0 05/14/24 17:28 EPA 6020B Cobalt 1.1 J ug/L 10.0 05/14/24 17:28 EPA 6020B Copper 2.2J ug/L 10.0 05/14/24 17:28 EPA 6020B Lead 1.6J ug/L 10.0 05/14/24 17:28 EPA 6020B Vanadium 6.9J ug/L 25.0 05/14/24 17:28 EPA 6020B Zinc 4.2J ug/L 10.0 05/14/24 17:28 92729146015 1403-SW2 Performed by ES&S 05/06/24 16:35 pH 6.21 Std. Units 05/06/24 16:35 Temperature 20.2 deg C 05/06/24 16:35 Specific Conductance 71.3 umhos/cm 05/06/24 16:35 Oxidation Potential 31.3 mV 05/06/24 16:35 Oxygen, Dissolved 3.96 mg/L 05/06/24 16:35 Turbidity 55.40 NTU 05/06/24 16:35 EPA 6020B Barium 34.2J ug/L 100 05/14/24 17:32 EPA 6020B Beryllium 0.23J ug/L 1.0 05/14/24 17:32 EPA 6020B Chromium 3.3J ug/L 10.0 05/14/24 17:32 EPA 6020B Cobalt 1 AJ ug/L 10.0 05/14/24 17:32 EPA 6020B Copper 2.9J ug/L 10.0 05/14/24 17:32 EPA 6020B Lead 2.1 J ug/L 10.0 05/14/24 17:32 EPA 6020B Vanadium 8AJ ug/L 25.0 05/14/24 17:32 EPA 6020B Zinc 5.1 J ug/L 10.0 05/14/24 17:32 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92729146016 1403-SW3 (MS/MSD) Performed by ES&S 05/06/24 17:40 pH 6.89 Std. Units 05/06/24 17:40 Temperature 18.5 deg C 05/06/24 17:40 Specific Conductance 51.0 umhos/cm 05/06/24 17:40 Oxidation Potential -6.2 mV 05/06/24 17:40 Oxygen, Dissolved 5.26 mg/L 05/06/24 17:40 Turbidity 60.30 NTU 05/06/24 17:40 EPA 6020B Barium 30AJ ug/L 100 05/14/24 17:36 EPA 6020B Beryllium 0.13J ug/L 1.0 05/14/24 17:36 EPA 6020B Chromium 3.5J ug/L 10.0 05/14/24 17:36 EPA 6020B Cobalt 1.2J ug/L 10.0 05/14/24 17:36 EPA 6020B Copper 2.7J ug/L 10.0 05/14/24 17:36 EPA 6020B Lead 1.5J ug/L 10.0 05/14/24 17:36 EPA 6020B Vanadium 8.3J ug/L 25.0 05/14/24 17:36 EPA 6020B Zinc 5.1 J ug/L 10.0 05/14/24 17:36 92729146017 1403-SW4 Performed by ES&S 05/06/24 17:18 pH 7.04 Std. Units 05/06/24 17:18 Temperature 18.8 deg C 05/06/24 17:18 Specific Conductance 53.9 umhos/cm 05/06/24 17:18 Oxidation Potential -14.0 mV 05/06/24 17:18 Oxygen, Dissolved 5.18 mg/L 05/06/24 17:18 Turbidity 89.20 NTU 05/06/24 17:18 EPA 6020B Antimony 1.3J ug/L 6.0 05/14/24 18:06 EPA 6020B Barium 47AJ ug/L 100 05/14/24 18:06 EPA 6020B Beryllium 0.37J ug/L 1.0 05/14/24 18:06 EPA 6020B Chromium 5.9J ug/L 10.0 05/14/24 18:06 EPA 6020B Cobalt 2AJ ug/L 10.0 05/14/24 18:06 EPA 6020B Copper 5.9J ug/L 10.0 05/14/24 18:06 EPA 6020B Lead 3AJ ug/L 10.0 05/14/24 18:06 EPA 6020B Nickel 2.7J ug/L 50.0 05/14/24 18:06 EPA 6020B Vanadium 13.9J ug/L 25.0 05/14/24 18:06 EPA 6020B Zinc 13.1 ug/L 10.0 05/14/24 18:06 92729146018 1403-SW5 Performed by ES&S 05/06/24 16:54 pH 6.08 Std. Units 05/06/24 16:54 Temperature 18.5 deg C 05/06/24 16:54 Specific Conductance 140.2 umhos/cm 05/06/24 16:54 Oxidation Potential 50.6 mV 05/06/24 16:54 Oxygen, Dissolved 4.12 mg/L 05/06/24 16:54 Turbidity 36.20 NTU 05/06/24 16:54 EPA 6020B Barium 26.7J ug/L 100 05/14/24 18:09 EPA 6020B Beryllium 0.17J ug/L 1.0 05/14/24 18:09 EPA 6020B Chromium 2.5J ug/L 10.0 05/14/24 18:09 EPA 6020B Cobalt 1.1 J ug/L 10.0 05/14/24 18:09 EPA 6020B Copper 2.2J ug/L 10.0 05/14/24 18:09 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Lab Sample ID Method 92729146018 EPA 6020B EPA 6020B EPA 6020B 92729146019 EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B 92729146020 EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B Client Sample ID Parameters 1403-SW5 Lead Vanadium Zinc 1403-UD1 Performed by pH Temperature Specific Conductance Oxidation Potential Oxygen, Dissolved Turbidity Arsenic Barium Cobalt Lead Vanadium 1403-U D2 Performed by pH Temperature Specific Conductance Oxidation Potential Oxygen, Dissolved Turbidity Arsenic Barium Cobalt Copper Lead Vanadium Zinc SUMMARY OF DETECTION Result Units 1.6J ug/L 5.6J ug/L 3.8J ug/L ES&S 5.18 Std. Units 18.1 deg C 222 umhos/cm 86.6 mV 3.66 mg/L 8.57 NTU 0.86J ug/L 73AJ ug/L 8.1J ug/L 0.28J ug/L 2.5J ug/L ES&S 5.49 Std. Units 17.9 deg C 208 umhos/cm 70.9 mV 3.42 mg/L 7.02 NTU 1.1J ug/L 58.2J ug/L 6.2J ug/L 0.62J ug/L 0.33J ug/L 3.5J ug/L 2.5J ug/L REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Report Limit Analyzed 10.0 05/14/2418:09 25.0 05/14/2418:09 10.0 05/14/2418:09 05/06/24 16:17 05/06/24 16:17 05/06/24 16:17 05/06/24 16:17 05/06/24 16:17 05/06/24 16:17 05/06/24 16:17 10.0 05/14/2418:13 100 05/14/2418:13 10.0 05/14/2418:13 10.0 05/14/2418:13 25.0 05/14/2418:13 05/06/24 15:58 05/06/24 15:58 05/06/24 15:58 05/06/24 15:58 05/06/24 15:58 05/06/24 15:58 05/06/24 15:58 10.0 05/14/2418:17 100 05/14/2418:17 10.0 05/14/2418:17 10.0 05/14/2418:17 10.0 05/14/2418:17 25.0 05/14/2418:17 10.0 05/14/2418:17 Qualifiers Page 11 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Date: May 21,2024 Neat Confirmation: 92729146-017 (1403-SW4) - Zn (13.1 ppb) was confirmed neat 17.1 ppb. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-MW-1 R2 Lab ID: 92729146001 Collected: 05/06/24 07:30 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 05/06/24 07:30 pH 6.26 Std. Units 1 05/06/24 07:30 Temperature 15.2 deg C 1 05/06/24 07:30 Static Water Level 24.30 feet 1 05/06/24 07:30 Specific Conductance 75.1 umhos/c 1 05/06/24 07:30 m Oxidation Potential 47.4 mV 1 05/06/24 07:30 Oxygen, Dissolved 2.31 mg/L 1 05/06/24 07:30 7782-44-7 Total Well Depth 43.34 feet 1 05/06/24 07:30 Turbidity 1.02 NTU 1 05/06/24 07:30 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.54 1 05/09/2414:06 05/14/2416:30 7440-36-0 Arsenic ND ug/L 10.0 0.84 1 05/09/2414:06 05/14/2416:30 7440-38-2 Barium 48.3J ug/L 100 0.47 1 05/09/2414:06 05/14/2416:30 7440-39-3 Beryllium ND ug/L 1.0 0.094 1 05/09/2414:06 05/14/2416:30 7440-41-7 Cadmium ND ug/L 1.0 0.10 1 05/09/2414:06 05/14/2416:30 7440-43-9 Chromium ND ug/L 10.0 1.9 1 05/09/2414:06 05/14/2416:30 7440-47-3 Cobalt ND ug/L 10.0 0.32 1 05/09/2414:06 05/14/2416:30 7440-48-4 Copper ND ug/L 10.0 0.43 1 05/09/2414:06 05/14/2416:30 7440-50-8 Lead ND ug/L 10.0 0.16 1 05/09/2414:06 05/14/2416:30 7439-92-1 Nickel ND ug/L 50.0 2.1 1 05/09/2414:06 05/14/2416:30 7440-02-0 Selenium ND ug/L 10.0 0.96 1 05/09/2414:06 05/14/2416:30 7782-49-2 Silver ND ug/L 10.0 0.31 1 05/09/2414:06 05/14/2416:30 7440-22-4 Thallium ND ug/L 5.5 0.38 1 05/09/2414:06 05/14/2416:30 7440-28-0 Vanadium ND ug/L 25.0 0.75 1 05/09/2414:06 05/14/2416:30 7440-62-2 Zinc ND ug/L 10.0 2.4 1 05/09/2414:06 05/14/2416:30 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 05/09/24 04:38 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 05/09/24 04:38 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/09/24 04:38 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 05/09/24 04:38 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/09/24 04:38 75-27-4 Bromoform ND ug/L 3.0 0.34 1 05/09/24 04:38 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 05/09/24 04:38 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 05/09/24 04:38 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 05/09/24 04:38 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/09/24 04:38 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 05/09/24 04:38 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 05/09/24 04:38 75-00-3 Chloroform ND ug/L 5.0 0.43 1 05/09/24 04:38 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/09/24 04:38 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-MW-1 R2 Lab ID: 92729146001 Collected: 05/06/24 07:30 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2024 04:04 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.24 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 96 % 70-130 97 % 70-130 103 % 70-130 1 05/09/24 04:38 96-12-8 1 05/09/24 04:38 124-48-1 1 05/09/24 04:38 106-93-4 1 05/09/24 04:38 74-95-3 1 05/09/24 04:38 95-50-1 1 05/09/24 04:38 106-46-7 1 05/09/24 04:38 110-57-6 v2 1 05/09/24 04:38 75-34-3 1 05/09/24 04:38 107-06-2 1 05/09/24 04:38 75-35-4 1 05/09/24 04:38 156-59-2 1 05/09/24 04:38 156-60-5 1 05/09/24 04:38 78-87-5 1 05/09/24 04:38 10061-01-5 1 05/09/24 04:38 10061-02-6 1 05/09/24 04:38 100-41-4 1 05/09/24 04:38 591-78-6 1 05/09/24 04:38 74-88-4 1 05/09/24 04:38 75-09-2 1 05/09/24 04:38 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/09/24 04:38 100-42-5 05/09/24 04:38 630-20-6 05/09/24 04:38 79-34-5 05/09/24 04:38 127-18-4 05/09/24 04:38 108-88-3 05/09/24 04:38 71-55-6 05/09/24 04:38 79-00-5 05/09/24 04:38 79-01-6 05/09/24 04:38 75-69-4 05/09/24 04:38 96-18-4 05/09/24 04:38 108-05-4 05/09/24 04:38 75-01-4 05/09/24 04:38 1330-20-7 05/09/24 04:38 460-00-4 05/09/24 04:38 17060-07-0 05/09/24 04:38 2037-26-5 Page 14 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-MW-3R2 Lab ID: 92729146002 Collected: 05/06/24 14:10 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 05/06/24 14:10 pH 8.30 Std. Units 1 05/06/24 14:10 Temperature 18.6 deg C 1 05/06/24 14:10 Static Water Level 40.36 feet 1 05/06/24 14:10 Specific Conductance 198.6 umhos/c 1 05/06/24 14:10 m Oxidation Potential -81.3 mV 1 05/06/24 14:10 Oxygen, Dissolved 3.46 mg/L 1 05/06/24 14:10 7782-44-7 Total Well Depth 73.91 feet 1 05/06/24 14:10 Turbidity 0.62 NTU 1 05/06/24 14:10 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony 0.61J ug/L 6.0 0.54 1 05/09/2414:06 05/14/2416:34 7440-36-0 Arsenic ND ug/L 10.0 0.84 1 05/09/2414:06 05/14/2416:34 7440-38-2 Barium 4.9J ug/L 100 0.47 1 05/09/2414:06 05/14/2416:34 7440-39-3 Beryllium ND ug/L 1.0 0.094 1 05/09/2414:06 05/14/2416:34 7440-41-7 Cadmium ND ug/L 1.0 0.10 1 05/09/2414:06 05/14/2416:34 7440-43-9 Chromium ND ug/L 10.0 1.9 1 05/09/2414:06 05/14/2416:34 7440-47-3 Cobalt ND ug/L 10.0 0.32 1 05/09/2414:06 05/14/2416:34 7440-48-4 Copper ND ug/L 10.0 0.43 1 05/09/2414:06 05/14/2416:34 7440-50-8 Lead ND ug/L 10.0 0.16 1 05/09/2414:06 05/14/2416:34 7439-92-1 Nickel ND ug/L 50.0 2.1 1 05/09/2414:06 05/14/2416:34 7440-02-0 Selenium ND ug/L 10.0 0.96 1 05/09/2414:06 05/14/2416:34 7782-49-2 Silver ND ug/L 10.0 0.31 1 05/09/2414:06 05/14/2416:34 7440-22-4 Thallium ND ug/L 5.5 0.38 1 05/09/2414:06 05/14/2416:34 7440-28-0 Vanadium 1.1J ug/L 25.0 0.75 1 05/09/2414:06 05/14/2416:34 7440-62-2 Zinc ND ug/L 10.0 2.4 1 05/09/2414:06 05/14/2416:34 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 05/09/24 04:56 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 05/09/24 04:56 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/09/24 04:56 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 05/09/24 04:56 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/09/24 04:56 75-27-4 Bromoform ND ug/L 3.0 0.34 1 05/09/24 04:56 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 05/09/24 04:56 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 05/09/24 04:56 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 05/09/24 04:56 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/09/24 04:56 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 05/09/24 04:56 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 05/09/24 04:56 75-00-3 Chloroform ND ug/L 5.0 0.43 1 05/09/24 04:56 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/09/24 04:56 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-MW-3R2 Lab ID: 92729146002 Collected: 05/06/24 14:10 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2024 04:04 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.24 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 96 % 70-130 100 % 70-130 102 % 70-130 1 05/09/24 04:56 96-12-8 1 05/09/24 04:56 124-48-1 1 05/09/24 04:56 106-93-4 1 05/09/24 04:56 74-95-3 1 05/09/24 04:56 95-50-1 1 05/09/24 04:56 106-46-7 1 05/09/24 04:56 110-57-6 v2 1 05/09/24 04:56 75-34-3 1 05/09/24 04:56 107-06-2 1 05/09/24 04:56 75-35-4 1 05/09/24 04:56 156-59-2 1 05/09/24 04:56 156-60-5 1 05/09/24 04:56 78-87-5 1 05/09/24 04:56 10061-01-5 1 05/09/24 04:56 10061-02-6 1 05/09/24 04:56 100-41-4 1 05/09/24 04:56 591-78-6 1 05/09/24 04:56 74-88-4 1 05/09/24 04:56 75-09-2 1 05/09/24 04:56 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/09/24 04:56 100-42-5 05/09/24 04:56 630-20-6 05/09/24 04:56 79-34-5 05/09/24 04:56 127-18-4 05/09/24 04:56 108-88-3 05/09/24 04:56 71-55-6 05/09/24 04:56 79-00-5 05/09/24 04:56 79-01-6 05/09/24 04:56 75-69-4 05/09/24 04:56 96-18-4 05/09/24 04:56 108-05-4 05/09/24 04:56 75-01-4 05/09/24 04:56 1330-20-7 05/09/24 04:56 460-00-4 05/09/24 04:56 17060-07-0 05/09/24 04:56 2037-26-5 Page 16 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-MW-4 Lab ID: 92729146003 Collected: 05/06/24 13:17 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 05/06/24 13:17 pH 4.13 Std. Units 1 05/06/24 13:17 Temperature 19.3 deg C 1 05/06/24 13:17 Static Water Level 41.30 feet 1 05/06/24 13:17 Specific Conductance 39.9 umhos/c 1 05/06/24 13:17 m Oxidation Potential 141.6 mV 1 05/06/24 13:17 Oxygen, Dissolved 1.95 mg/L 1 05/06/24 13:17 7782-44-7 Total Well Depth 52.20 feet 1 05/06/24 13:17 Turbidity 0.85 NTU 1 05/06/24 13:17 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.54 1 05/09/2414:06 05/14/2416:38 7440-36-0 Arsenic ND ug/L 10.0 0.84 1 05/09/2414:06 05/14/2416:38 7440-38-2 Barium 47.1J ug/L 100 0.47 1 05/09/2414:06 05/14/2416:38 7440-39-3 Beryllium ND ug/L 1.0 0.094 1 05/09/2414:06 05/14/2416:38 7440-41-7 Cadmium ND ug/L 1.0 0.10 1 05/09/2414:06 05/14/2416:38 7440-43-9 Chromium ND ug/L 10.0 1.9 1 05/09/2414:06 05/14/2416:38 7440-47-3 Cobalt 15.6 ug/L 10.0 0.32 1 05/09/2414:06 05/14/2416:38 7440-48-4 Copper ND ug/L 10.0 0.43 1 05/09/2414:06 05/14/2416:38 7440-50-8 Lead ND ug/L 10.0 0.16 1 05/09/2414:06 05/14/2416:38 7439-92-1 Nickel ND ug/L 50.0 2.1 1 05/09/2414:06 05/14/2416:38 7440-02-0 Selenium ND ug/L 10.0 0.96 1 05/09/2414:06 05/14/2416:38 7782-49-2 Silver ND ug/L 10.0 0.31 1 05/09/2414:06 05/14/2416:38 7440-22-4 Thallium ND ug/L 5.5 0.38 1 05/09/2414:06 05/14/2416:38 7440-28-0 Vanadium ND ug/L 25.0 0.75 1 05/09/2414:06 05/14/2416:38 7440-62-2 Zinc 2.4J ug/L 10.0 2.4 1 05/09/2414:06 05/14/2416:38 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 05/09/24 05:14 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 05/09/24 05:14 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/09/24 05:14 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 05/09/24 05:14 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/09/24 05:14 75-27-4 Bromoform ND ug/L 3.0 0.34 1 05/09/24 05:14 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 05/09/24 05:14 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 05/09/24 05:14 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 05/09/24 05:14 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/09/24 05:14 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 05/09/24 05:14 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 05/09/24 05:14 75-00-3 Chloroform ND ug/L 5.0 0.43 1 05/09/24 05:14 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/09/24 05:14 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-MW-4 Lab ID: 92729146003 Collected: 05/06/24 13:17 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2024 04:04 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.24 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 94 % 70-130 98 % 70-130 101 % 70-130 1 05/09/24 05:14 96-12-8 1 05/09/24 05:14 124-48-1 1 05/09/24 05:14 106-93-4 1 05/09/24 05:14 74-95-3 1 05/09/24 05:14 95-50-1 1 05/09/24 05:14 106-46-7 1 05/09/24 05:14 110-57-6 v2 1 05/09/24 05:14 75-34-3 1 05/09/24 05:14 107-06-2 1 05/09/24 05:14 75-35-4 1 05/09/24 05:14 156-59-2 1 05/09/24 05:14 156-60-5 1 05/09/24 05:14 78-87-5 1 05/09/24 05:14 10061-01-5 1 05/09/24 05:14 10061-02-6 1 05/09/24 05:14 100-41-4 1 05/09/24 05:14 591-78-6 1 05/09/24 05:14 74-88-4 1 05/09/24 05:14 75-09-2 1 05/09/24 05:14 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/09/24 05:14 100-42-5 05/09/24 05:14 630-20-6 05/09/24 05:14 79-34-5 05/09/24 05:14 127-18-4 05/09/24 05:14 108-88-3 05/09/24 05:14 71-55-6 05/09/24 05:14 79-00-5 05/09/24 05:14 79-01-6 05/09/24 05:14 75-69-4 05/09/24 05:14 96-18-4 05/09/24 05:14 108-05-4 05/09/24 05:14 75-01-4 05/09/24 05:14 1330-20-7 05/09/24 05:14 460-00-4 05/09/24 05:14 17060-07-0 05/09/24 05:14 2037-26-5 Page 18 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-DUP@MW-4 Lab ID: 92729146004 Collected: 05/06/24 13:19 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.54 1 05/09/2414:06 05/14/2416:41 7440-36-0 Arsenic ND ug/L 10.0 0.84 1 05/09/2414:06 05/14/2416:41 7440-38-2 Barium 46.8J ug/L 100 0.47 1 05/09/2414:06 05/14/2416:41 7440-39-3 Beryllium ND ug/L 1.0 0.094 1 05/09/2414:06 05/14/2416:41 7440-41-7 Cadmium ND ug/L 1.0 0.10 1 05/09/2414:06 05/14/2416:41 7440-43-9 Chromium ND ug/L 10.0 1.9 1 05/09/2414:06 05/14/2416:41 7440-47-3 Cobalt 15.4 ug/L 10.0 0.32 1 05/09/2414:06 05/14/2416:41 7440-48-4 Copper ND ug/L 10.0 0.43 1 05/09/2414:06 05/14/2416:41 7440-50-8 Lead ND ug/L 10.0 0.16 1 05/09/2414:06 05/14/2416:41 7439-92-1 Nickel ND ug/L 50.0 2.1 1 05/09/2414:06 05/14/2416:41 7440-02-0 Selenium ND ug/L 10.0 0.96 1 05/09/2414:06 05/14/2416:41 7782-49-2 Silver ND ug/L 10.0 0.31 1 05/09/2414:06 05/14/2416:41 7440-22-4 Thallium ND ug/L 5.5 0.38 1 05/09/2414:06 05/14/2416:41 7440-28-0 Vanadium ND ug/L 25.0 0.75 1 05/09/2414:06 05/14/2416:41 7440-62-2 Zinc 2.5J ug/L 10.0 2.4 1 05/09/2414:06 05/14/2416:41 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 05/09/24 05:32 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 05/09/24 05:32 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/09/24 05:32 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 05/09/24 05:32 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/09/24 05:32 75-27-4 Bromoform ND ug/L 3.0 0.34 1 05/09/24 05:32 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 05/09/24 05:32 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 05/09/24 05:32 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 05/09/24 05:32 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/09/24 05:32 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 05/09/24 05:32 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 05/09/24 05:32 75-00-3 Chloroform ND ug/L 5.0 0.43 1 05/09/24 05:32 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/09/24 05:32 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.34 1 05/09/24 05:32 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.36 1 05/09/24 05:32 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.27 1 05/09/24 05:32 106-93-4 Dibromomethane ND ug/L 10.0 0.39 1 05/09/24 05:32 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.34 1 05/09/24 05:32 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 05/09/24 05:32 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 0.56 1 05/09/24 05:32 110-57-6 v2 butene 1,1-Dichloroethane ND ug/L 5.0 0.37 1 05/09/24 05:32 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 05/09/24 05:32 107-06-2 1,1-Dichloroethene ND ug/L 5.0 0.35 1 05/09/24 05:32 75-35-4 cis-1,2-Dichloroethene ND ug/L 5.0 0.38 1 05/09/24 05:32 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-DUP@MW-4 Lab ID: 92729146004 Collected: 05/06/24 13:19 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2024 04:04 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 5.0 0.40 1 05/09/24 05:32 156-60-5 ND ug/L 1.0 0.36 1 05/09/24 05:32 78-87-5 ND ug/L 1.0 0.36 1 05/09/24 05:32 10061-01-5 ND ug/L 1.0 0.36 1 05/09/24 05:32 10061-02-6 ND ug/L 1.0 0.30 1 05/09/24 05:32 100-41-4 ND ug/L 50.0 0.48 1 05/09/24 05:32 591-78-6 ND ug/L 20.0 9.7 1 05/09/24 05:32 74-88-4 ND ug/L 5.0 2.0 1 05/09/24 05:32 75-09-2 ND ug/L 100 2.7 1 05/09/24 05:32 108-10-1 ND ug/L 1.0 0.29 1 05/09/24 05:32 100-42-5 ND ug/L 5.0 0.31 1 05/09/24 05:32 630-20-6 ND ug/L 3.0 0.22 1 05/09/24 05:32 79-34-5 ND ug/L 1.0 0.29 1 05/09/24 05:32 127-18-4 ND ug/L 1.0 0.24 1 05/09/24 05:32 108-88-3 ND ug/L 1.0 0.33 1 05/09/24 05:32 71-55-6 ND ug/L 1.0 0.32 1 05/09/24 05:32 79-00-5 ND ug/L 1.0 0.38 1 05/09/24 05:32 79-01-6 ND ug/L 1.0 0.30 1 05/09/24 05:32 75-69-4 ND ug/L 1.0 0.26 1 05/09/24 05:32 96-18-4 ND ug/L 50.0 1.3 1 05/09/24 05:32 108-05-4 ND ug/L 1.0 0.39 1 05/09/24 05:32 75-01-4 ND ug/L 5.0 0.34 1 05/09/24 05:32 1330-20-7 96 % 70-130 1 05/09/24 05:32 460-00-4 98 % 70-130 1 05/09/24 05:32 17060-07-0 102 % 70-130 1 05/09/24 05:32 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-MW-5 Lab ID: 92729146005 Collected: 05/06/24 12:29 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 05/06/24 12:29 pH 5.05 Std. Units 1 05/06/24 12:29 Temperature 19.2 deg C 1 05/06/24 12:29 Static Water Level 47.50 feet 1 05/06/24 12:29 Specific Conductance 209 umhos/c 1 05/06/24 12:29 m Oxidation Potential 92.7 mV 1 05/06/24 12:29 Oxygen, Dissolved 2.73 mg/L 1 05/06/24 12:29 7782-44-7 Total Well Depth 54.50 feet 1 05/06/24 12:29 Turbidity 0.50 NTU 1 05/06/24 12:29 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.54 1 05/09/2414:06 05/14/2416:45 7440-36-0 Arsenic 1.OJ ug/L 10.0 0.84 1 05/09/2414:06 05/14/2416:45 7440-38-2 Barium 149 ug/L 100 0.47 1 05/09/2414:06 05/14/2416:45 7440-39-3 Beryllium ND ug/L 1.0 0.094 1 05/09/2414:06 05/14/2416:45 7440-41-7 Cadmium ND ug/L 1.0 0.10 1 05/09/2414:06 05/14/2416:45 7440-43-9 Chromium ND ug/L 10.0 1.9 1 05/09/2414:06 05/14/2416:45 7440-47-3 Cobalt ND ug/L 10.0 0.32 1 05/09/2414:06 05/14/2416:45 7440-48-4 Copper ND ug/L 10.0 0.43 1 05/09/2414:06 05/14/2416:45 7440-50-8 Lead ND ug/L 10.0 0.16 1 05/09/2414:06 05/14/2416:45 7439-92-1 Nickel ND ug/L 50.0 2.1 1 05/09/2414:06 05/14/2416:45 7440-02-0 Selenium ND ug/L 10.0 0.96 1 05/09/2414:06 05/14/2416:45 7782-49-2 Silver ND ug/L 10.0 0.31 1 05/09/2414:06 05/14/2416:45 7440-22-4 Thallium ND ug/L 5.5 0.38 1 05/09/2414:06 05/14/2416:45 7440-28-0 Vanadium 3.5J ug/L 25.0 0.75 1 05/09/2414:06 05/14/2416:45 7440-62-2 Zinc ND ug/L 10.0 2.4 1 05/09/2414:06 05/14/2416:45 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 05/09/24 05:50 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 05/09/24 05:50 107-13-1 Benzene 0.82J ug/L 1.0 0.34 1 05/09/24 05:50 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 05/09/24 05:50 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/09/24 05:50 75-27-4 Bromoform ND ug/L 3.0 0.34 1 05/09/24 05:50 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 05/09/24 05:50 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 05/09/24 05:50 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 05/09/24 05:50 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/09/24 05:50 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 05/09/24 05:50 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 05/09/24 05:50 75-00-3 Chloroform ND ug/L 5.0 0.43 1 05/09/24 05:50 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/09/24 05:50 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-MW-5 Lab ID: 92729146005 Collected: 05/06/24 12:29 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2024 04:04 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 1 05/09/24 05:50 96-12-8 ND ug/L 3.0 0.36 1 05/09/24 05:50 124-48-1 ND ug/L 2.0 0.27 1 05/09/24 05:50 106-93-4 ND ug/L 10.0 0.39 1 05/09/24 05:50 74-95-3 ND ug/L 5.0 0.34 1 05/09/24 05:50 95-50-1 0.36J ug/L 1.0 0.33 1 05/09/24 05:50 106-46-7 ND ug/L 100 0.56 1 05/09/24 05:50 110-57-6 v2 ND ug/L 5.0 0.37 1 05/09/24 05:50 75-34-3 ND ug/L 1.0 0.32 1 05/09/24 05:50 107-06-2 ND ug/L 5.0 0.35 1 05/09/24 05:50 75-35-4 2.OJ ug/L 5.0 0.38 1 05/09/24 05:50 156-59-2 ND ug/L 5.0 0.40 1 05/09/24 05:50 156-60-5 ND ug/L 1.0 0.36 1 05/09/24 05:50 78-87-5 ND ug/L 1.0 0.36 1 05/09/24 05:50 10061-01-5 ND ug/L 1.0 0.36 1 05/09/24 05:50 10061-02-6 ND ug/L 1.0 0.30 1 05/09/24 05:50 100-41-4 ND ug/L 50.0 0.48 1 05/09/24 05:50 591-78-6 ND ug/L 20.0 9.7 1 05/09/24 05:50 74-88-4 ND ug/L 5.0 2.0 1 05/09/24 05:50 75-09-2 ND ug/L 100 2.7 1 05/09/24 05:50 108-10-1 ND ug/L 1.0 0.29 1 05/09/24 05:50 100-42-5 ND ug/L 5.0 0.31 1 05/09/24 05:50 630-20-6 ND ug/L 3.0 0.22 1 05/09/24 05:50 79-34-5 ND ug/L 1.0 0.29 1 05/09/24 05:50 127-18-4 ND ug/L 1.0 0.24 1 05/09/24 05:50 108-88-3 ND ug/L 1.0 0.33 1 05/09/24 05:50 71-55-6 ND ug/L 1.0 0.32 1 05/09/24 05:50 79-00-5 ND ug/L 1.0 0.38 1 05/09/24 05:50 79-01-6 ND ug/L 1.0 0.30 1 05/09/24 05:50 75-69-4 ND ug/L 1.0 0.26 1 05/09/24 05:50 96-18-4 ND ug/L 50.0 1.3 1 05/09/24 05:50 108-05-4 ND ug/L 1.0 0.39 1 05/09/24 05:50 75-01-4 ND ug/L 5.0 0.34 1 05/09/24 05:50 1330-20-7 96 % 70-130 1 05/09/24 05:50 460-00-4 CO 99 % 70-130 1 05/09/24 05:50 17060-07-0 101 % 70-130 1 05/09/24 05:50 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-MW-6 Lab ID: 92729146006 Collected: 05/06/24 11:41 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 05/06/24 11:41 pH 4.65 Std. Units 1 05/06/24 11:41 Temperature 18.4 deg C 1 05/06/24 11:41 Static Water Level 43.01 feet 1 05/06/24 11:41 Specific Conductance 132.7 umhos/c 1 05/06/24 11:41 m Oxidation Potential 113.4 mV 1 05/06/24 11:41 Oxygen, Dissolved 2.80 mg/L 1 05/06/24 11:41 7782-44-7 Total Well Depth 50.55 feet 1 05/06/24 11:41 Turbidity 1.06 NTU 1 05/06/24 11:41 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.54 1 05/09/2414:06 05/14/2416:49 7440-36-0 Arsenic ND ug/L 10.0 0.84 1 05/09/2414:06 05/14/2416:49 7440-38-2 Barium 140 ug/L 100 0.47 1 05/09/2414:06 05/14/2416:49 7440-39-3 Beryllium 0.29J ug/L 1.0 0.094 1 05/09/2414:06 05/14/2416:49 7440-41-7 Cadmium 0.13J ug/L 1.0 0.10 1 05/09/2414:06 05/14/2416:49 7440-43-9 Chromium ND ug/L 10.0 1.9 1 05/09/2414:06 05/14/2416:49 7440-47-3 Cobalt 5.4J ug/L 10.0 0.32 1 05/09/2414:06 05/14/2416:49 7440-48-4 Copper ND ug/L 10.0 0.43 1 05/09/2414:06 05/14/2416:49 7440-50-8 Lead ND ug/L 10.0 0.16 1 05/09/2414:06 05/14/2416:49 7439-92-1 Nickel ND ug/L 50.0 2.1 1 05/09/2414:06 05/14/2416:49 7440-02-0 Selenium ND ug/L 10.0 0.96 1 05/09/2414:06 05/14/2416:49 7782-49-2 Silver ND ug/L 10.0 0.31 1 05/09/2414:06 05/14/2416:49 7440-22-4 Thallium ND ug/L 5.5 0.38 1 05/09/2414:06 05/14/2416:49 7440-28-0 Vanadium ND ug/L 25.0 0.75 1 05/09/2414:06 05/14/2416:49 7440-62-2 Zinc ND ug/L 10.0 2.4 1 05/09/2414:06 05/14/2416:49 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 05/09/24 06:08 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 05/09/24 06:08 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/09/24 06:08 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 05/09/24 06:08 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/09/24 06:08 75-27-4 Bromoform ND ug/L 3.0 0.34 1 05/09/24 06:08 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 05/09/24 06:08 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 05/09/24 06:08 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 05/09/24 06:08 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/09/24 06:08 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 05/09/24 06:08 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 05/09/24 06:08 75-00-3 Chloroform ND ug/L 5.0 0.43 1 05/09/24 06:08 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/09/24 06:08 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-MW-6 Lab ID: 92729146006 Collected: 05/06/24 11:41 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2024 04:04 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.24 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 95 % 70-130 99 % 70-130 102 % 70-130 1 05/09/24 06:08 96-12-8 1 05/09/24 06:08 124-48-1 1 05/09/24 06:08 106-93-4 1 05/09/24 06:08 74-95-3 1 05/09/24 06:08 95-50-1 1 05/09/24 06:08 106-46-7 1 05/09/24 06:08 110-57-6 v2 1 05/09/24 06:08 75-34-3 1 05/09/24 06:08 107-06-2 1 05/09/24 06:08 75-35-4 1 05/09/24 06:08 156-59-2 1 05/09/24 06:08 156-60-5 1 05/09/24 06:08 78-87-5 1 05/09/24 06:08 10061-01-5 1 05/09/24 06:08 10061-02-6 1 05/09/24 06:08 100-41-4 1 05/09/24 06:08 591-78-6 1 05/09/24 06:08 74-88-4 1 05/09/24 06:08 75-09-2 1 05/09/24 06:08 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/09/24 06:08 100-42-5 05/09/24 06:08 630-20-6 05/09/24 06:08 79-34-5 05/09/24 06:08 127-18-4 05/09/24 06:08 108-88-3 05/09/24 06:08 71-55-6 05/09/24 06:08 79-00-5 05/09/24 06:08 79-01-6 05/09/24 06:08 75-69-4 05/09/24 06:08 96-18-4 05/09/24 06:08 108-05-4 05/09/24 06:08 75-01-4 05/09/24 06:08 1330-20-7 05/09/24 06:08 460-00-4 05/09/24 06:08 17060-07-0 05/09/24 06:08 2037-26-5 Page 24 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-MW-7 Lab ID: 92729146007 Collected: 05/06/24 10:52 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 05/06/24 10:52 pH 4.98 Std. Units 1 05/06/24 10:52 Temperature 17.7 deg C 1 05/06/24 10:52 Static Water Level 29.35 feet 1 05/06/24 10:52 Specific Conductance 93.4 umhos/c 1 05/06/24 10:52 m Oxidation Potential 95.8 mV 1 05/06/24 10:52 Oxygen, Dissolved 4.05 mg/L 1 05/06/24 10:52 7782-44-7 Total Well Depth 40.13 feet 1 05/06/24 10:52 Turbidity 2.06 NTU 1 05/06/24 10:52 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony 0.55J ug/L 6.0 0.54 1 05/09/2414:06 05/14/2416:52 7440-36-0 Arsenic ND ug/L 10.0 0.84 1 05/09/2414:06 05/14/2416:52 7440-38-2 Barium 24.6J ug/L 100 0.47 1 05/09/2414:06 05/14/2416:52 7440-39-3 Beryllium 0.10J ug/L 1.0 0.094 1 05/09/2414:06 05/14/2416:52 7440-41-7 Cadmium ND ug/L 1.0 0.10 1 05/09/2414:06 05/14/2416:52 7440-43-9 Chromium ND ug/L 10.0 1.9 1 05/09/2414:06 05/14/2416:52 7440-47-3 Cobalt ND ug/L 10.0 0.32 1 05/09/2414:06 05/14/2416:52 7440-48-4 Copper ND ug/L 10.0 0.43 1 05/09/2414:06 05/14/2416:52 7440-50-8 Lead ND ug/L 10.0 0.16 1 05/09/2414:06 05/14/2416:52 7439-92-1 Nickel ND ug/L 50.0 2.1 1 05/09/2414:06 05/14/2416:52 7440-02-0 Selenium ND ug/L 10.0 0.96 1 05/09/2414:06 05/14/2416:52 7782-49-2 Silver ND ug/L 10.0 0.31 1 05/09/2414:06 05/14/2416:52 7440-22-4 Thallium ND ug/L 5.5 0.38 1 05/09/2414:06 05/14/2416:52 7440-28-0 Vanadium 1.5J ug/L 25.0 0.75 1 05/09/2414:06 05/14/2416:52 7440-62-2 Zinc ND ug/L 10.0 2.4 1 05/09/2414:06 05/14/2416:52 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 05/09/24 06:27 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 05/09/24 06:27 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/09/24 06:27 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 05/09/24 06:27 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/09/24 06:27 75-27-4 Bromoform ND ug/L 3.0 0.34 1 05/09/24 06:27 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 05/09/24 06:27 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 05/09/24 06:27 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 05/09/24 06:27 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/09/24 06:27 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 05/09/24 06:27 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 05/09/24 06:27 75-00-3 Chloroform ND ug/L 5.0 0.43 1 05/09/24 06:27 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/09/24 06:27 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-MW-7 Lab ID: 92729146007 Collected: 05/06/24 10:52 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2024 04:04 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.24 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 96 % 70-130 102 % 70-130 103 % 70-130 1 05/09/24 06:27 96-12-8 1 05/09/24 06:27 124-48-1 1 05/09/24 06:27 106-93-4 1 05/09/24 06:27 74-95-3 1 05/09/24 06:27 95-50-1 1 05/09/24 06:27 106-46-7 1 05/09/24 06:27 110-57-6 v2 1 05/09/24 06:27 75-34-3 1 05/09/24 06:27 107-06-2 1 05/09/24 06:27 75-35-4 1 05/09/24 06:27 156-59-2 1 05/09/24 06:27 156-60-5 1 05/09/24 06:27 78-87-5 1 05/09/24 06:27 10061-01-5 1 05/09/24 06:27 10061-02-6 1 05/09/24 06:27 100-41-4 1 05/09/24 06:27 591-78-6 1 05/09/24 06:27 74-88-4 1 05/09/24 06:27 75-09-2 1 05/09/24 06:27 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/09/24 06:27 100-42-5 05/09/24 06:27 630-20-6 05/09/24 06:27 79-34-5 05/09/24 06:27 127-18-4 05/09/24 06:27 108-88-3 05/09/24 06:27 71-55-6 05/09/24 06:27 79-00-5 05/09/24 06:27 79-01-6 05/09/24 06:27 75-69-4 05/09/24 06:27 96-18-4 05/09/24 06:27 108-05-4 05/09/24 06:27 75-01-4 05/09/24 06:27 1330-20-7 05/09/24 06:27 460-00-4 05/09/24 06:27 17060-07-0 05/09/24 06:27 2037-26-5 Page 26 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-MW-8 Lab ID: 92729146008 Collected: 05/06/24 10:04 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 05/06/24 10:04 pH 5.61 Std. Units 1 05/06/24 10:04 Temperature 15.0 deg C 1 05/06/24 10:04 Static Water Level 27.84 feet 1 05/06/24 10:04 Specific Conductance 90.2 umhos/c 1 05/06/24 10:04 m Oxidation Potential 79.8 mV 1 05/06/24 10:04 Oxygen, Dissolved 2.09 mg/L 1 05/06/24 10:04 7782-44-7 Total Well Depth 49.56 feet 1 05/06/24 10:04 Turbidity 1.82 NTU 1 05/06/24 10:04 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.54 1 05/09/2414:06 05/14/2416:56 7440-36-0 Arsenic ND ug/L 10.0 0.84 1 05/09/2414:06 05/14/2416:56 7440-38-2 Barium 68.1J ug/L 100 0.47 1 05/09/2414:06 05/14/2416:56 7440-39-3 Beryllium ND ug/L 1.0 0.094 1 05/09/2414:06 05/14/2416:56 7440-41-7 Cadmium ND ug/L 1.0 0.10 1 05/09/2414:06 05/14/2416:56 7440-43-9 Chromium ND ug/L 10.0 1.9 1 05/09/2414:06 05/14/2416:56 7440-47-3 Cobalt ND ug/L 10.0 0.32 1 05/09/2414:06 05/14/2416:56 7440-48-4 Copper ND ug/L 10.0 0.43 1 05/09/2414:06 05/14/2416:56 7440-50-8 Lead ND ug/L 10.0 0.16 1 05/09/2414:06 05/14/2416:56 7439-92-1 Nickel ND ug/L 50.0 2.1 1 05/09/2414:06 05/14/2416:56 7440-02-0 Selenium ND ug/L 10.0 0.96 1 05/09/2414:06 05/14/2416:56 7782-49-2 Silver ND ug/L 10.0 0.31 1 05/09/2414:06 05/14/2416:56 7440-22-4 Thallium ND ug/L 5.5 0.38 1 05/09/2414:06 05/14/2416:56 7440-28-0 Vanadium 1.2J ug/L 25.0 0.75 1 05/09/2414:06 05/14/2416:56 7440-62-2 Zinc ND ug/L 10.0 2.4 1 05/09/2414:06 05/14/2416:56 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 05/09/24 06:45 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 05/09/24 06:45 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/09/24 06:45 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 05/09/24 06:45 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/09/24 06:45 75-27-4 Bromoform ND ug/L 3.0 0.34 1 05/09/24 06:45 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 05/09/24 06:45 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 05/09/24 06:45 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 05/09/24 06:45 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/09/24 06:45 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 05/09/24 06:45 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 05/09/24 06:45 75-00-3 Chloroform ND ug/L 5.0 0.43 1 05/09/24 06:45 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/09/24 06:45 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-MW-8 Lab ID: 92729146008 Collected: 05/06/24 10:04 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2024 04:04 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.24 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 96 % 70-130 100 % 70-130 101 % 70-130 1 05/09/24 06:45 96-12-8 1 05/09/24 06:45 124-48-1 1 05/09/24 06:45 106-93-4 1 05/09/24 06:45 74-95-3 1 05/09/24 06:45 95-50-1 1 05/09/24 06:45 106-46-7 1 05/09/24 06:45 110-57-6 v2 1 05/09/24 06:45 75-34-3 1 05/09/24 06:45 107-06-2 1 05/09/24 06:45 75-35-4 1 05/09/24 06:45 156-59-2 1 05/09/24 06:45 156-60-5 1 05/09/24 06:45 78-87-5 1 05/09/24 06:45 10061-01-5 1 05/09/24 06:45 10061-02-6 1 05/09/24 06:45 100-41-4 1 05/09/24 06:45 591-78-6 1 05/09/24 06:45 74-88-4 1 05/09/24 06:45 75-09-2 1 05/09/24 06:45 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/09/24 06:45 100-42-5 05/09/24 06:45 630-20-6 05/09/24 06:45 79-34-5 05/09/24 06:45 127-18-4 05/09/24 06:45 108-88-3 05/09/24 06:45 71-55-6 05/09/24 06:45 79-00-5 05/09/24 06:45 79-01-6 05/09/24 06:45 75-69-4 05/09/24 06:45 96-18-4 05/09/24 06:45 108-05-4 05/09/24 06:45 75-01-4 05/09/24 06:45 1330-20-7 05/09/24 06:45 460-00-4 05/09/24 06:45 17060-07-0 05/09/24 06:45 2037-26-5 Page 28 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-MW-9 Lab ID: 92729146009 Collected: 05/06/24 09:13 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 05/06/24 09:13 pH 5.18 Std. Units 1 05/06/24 09:13 Temperature 18.0 deg C 1 05/06/24 09:13 Static Water Level 70.83 feet 1 05/06/24 09:13 Specific Conductance 188.8 umhos/c 1 05/06/24 09:13 m Oxidation Potential 85.0 mV 1 05/06/24 09:13 Oxygen, Dissolved 3.12 mg/L 1 05/06/24 09:13 7782-44-7 Total Well Depth 73.40 feet 1 05/06/24 09:13 Turbidity 1.26 NTU 1 05/06/24 09:13 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.54 1 05/09/2414:06 05/14/2417:10 7440-36-0 Arsenic 1.6J ug/L 10.0 0.84 1 05/09/2414:06 05/14/2417:10 7440-38-2 Barium 8.3J ug/L 100 0.47 1 05/09/2414:06 05/14/2417:10 7440-39-3 Beryllium ND ug/L 1.0 0.094 1 05/09/2414:06 05/14/2417:10 7440-41-7 Cadmium ND ug/L 1.0 0.10 1 05/09/2414:06 05/14/2417:10 7440-43-9 Chromium ND ug/L 10.0 1.9 1 05/09/2414:06 05/14/2417:10 7440-47-3 Cobalt 0.36J ug/L 10.0 0.32 1 05/09/2414:06 05/14/2417:10 7440-48-4 Copper ND ug/L 10.0 0.43 1 05/09/2414:06 05/14/2417:10 7440-50-8 Lead ND ug/L 10.0 0.16 1 05/09/2414:06 05/14/2417:10 7439-92-1 Nickel ND ug/L 50.0 2.1 1 05/09/2414:06 05/14/2417:10 7440-02-0 Selenium ND ug/L 10.0 0.96 1 05/09/2414:06 05/14/2417:10 7782-49-2 Silver ND ug/L 10.0 0.31 1 05/09/2414:06 05/14/2417:10 7440-22-4 Thallium ND ug/L 5.5 0.38 1 05/09/2414:06 05/14/2417:10 7440-28-0 Vanadium 2.1J ug/L 25.0 0.75 1 05/09/2414:06 05/14/2417:10 7440-62-2 Zinc ND ug/L 10.0 2.4 1 05/09/2414:06 05/14/2417:10 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 05/09/24 07:03 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 05/09/24 07:03 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/09/24 07:03 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 05/09/24 07:03 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/09/24 07:03 75-27-4 Bromoform ND ug/L 3.0 0.34 1 05/09/24 07:03 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 05/09/24 07:03 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 05/09/24 07:03 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 05/09/24 07:03 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/09/24 07:03 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 05/09/24 07:03 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 05/09/24 07:03 75-00-3 Chloroform ND ug/L 5.0 0.43 1 05/09/24 07:03 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/09/24 07:03 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-MW-9 Lab ID: 92729146009 Collected: 05/06/24 09:13 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2024 04:04 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.24 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 95 % 70-130 101 % 70-130 103 % 70-130 1 05/09/24 07:03 96-12-8 1 05/09/24 07:03 124-48-1 1 05/09/24 07:03 106-93-4 1 05/09/24 07:03 74-95-3 1 05/09/24 07:03 95-50-1 1 05/09/24 07:03 106-46-7 1 05/09/24 07:03 110-57-6 v2 1 05/09/24 07:03 75-34-3 1 05/09/24 07:03 107-06-2 1 05/09/24 07:03 75-35-4 1 05/09/24 07:03 156-59-2 1 05/09/24 07:03 156-60-5 1 05/09/24 07:03 78-87-5 1 05/09/24 07:03 10061-01-5 1 05/09/24 07:03 10061-02-6 1 05/09/24 07:03 100-41-4 1 05/09/24 07:03 591-78-6 1 05/09/24 07:03 74-88-4 1 05/09/24 07:03 75-09-2 1 05/09/24 07:03 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/09/24 07:03 100-42-5 05/09/24 07:03 630-20-6 05/09/24 07:03 79-34-5 05/09/24 07:03 127-18-4 05/09/24 07:03 108-88-3 05/09/24 07:03 71-55-6 05/09/24 07:03 79-00-5 05/09/24 07:03 79-01-6 05/09/24 07:03 75-69-4 05/09/24 07:03 96-18-4 05/09/24 07:03 108-05-4 05/09/24 07:03 75-01-4 05/09/24 07:03 1330-20-7 05/09/24 07:03 460-00-4 05/09/24 07:03 17060-07-0 05/09/24 07:03 2037-26-5 Page 30 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-MW-10 Lab ID: 92729146010 Collected: 05/06/24 08:25 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 05/06/24 08:25 pH 5.43 Std. Units 1 05/06/24 08:25 Temperature 16.2 deg C 1 05/06/24 08:25 Static Water Level 79.47 feet 1 05/06/24 08:25 Specific Conductance 66.8 umhos/c 1 05/06/24 08:25 m Oxidation Potential 71.4 mV 1 05/06/24 08:25 Oxygen, Dissolved 4.42 mg/L 1 05/06/24 08:25 7782-44-7 Total Well Depth 88.21 feet 1 05/06/24 08:25 Turbidity 1.27 NTU 1 05/06/24 08:25 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.54 1 05/09/2414:06 05/14/2417:14 7440-36-0 Arsenic ND ug/L 10.0 0.84 1 05/09/2414:06 05/14/2417:14 7440-38-2 Barium 33.3J ug/L 100 0.47 1 05/09/2414:06 05/14/2417:14 7440-39-3 Beryllium ND ug/L 1.0 0.094 1 05/09/2414:06 05/14/2417:14 7440-41-7 Cadmium ND ug/L 1.0 0.10 1 05/09/2414:06 05/14/2417:14 7440-43-9 Chromium ND ug/L 10.0 1.9 1 05/09/2414:06 05/14/2417:14 7440-47-3 Cobalt ND ug/L 10.0 0.32 1 05/09/2414:06 05/14/2417:14 7440-48-4 Copper ND ug/L 10.0 0.43 1 05/09/2414:06 05/14/2417:14 7440-50-8 Lead ND ug/L 10.0 0.16 1 05/09/2414:06 05/14/2417:14 7439-92-1 Nickel ND ug/L 50.0 2.1 1 05/09/2414:06 05/14/2417:14 7440-02-0 Selenium ND ug/L 10.0 0.96 1 05/09/2414:06 05/14/2417:14 7782-49-2 Silver ND ug/L 10.0 0.31 1 05/09/2414:06 05/14/2417:14 7440-22-4 Thallium ND ug/L 5.5 0.38 1 05/09/2414:06 05/14/2417:14 7440-28-0 Vanadium 5.6J ug/L 25.0 0.75 1 05/09/2414:06 05/14/2417:14 7440-62-2 Zinc ND ug/L 10.0 2.4 1 05/09/2414:06 05/14/2417:14 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 05/09/24 07:21 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 05/09/24 07:21 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/09/24 07:21 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 05/09/24 07:21 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/09/24 07:21 75-27-4 Bromoform ND ug/L 3.0 0.34 1 05/09/24 07:21 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 05/09/24 07:21 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 05/09/24 07:21 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 05/09/24 07:21 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/09/24 07:21 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 05/09/24 07:21 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 05/09/24 07:21 75-00-3 Chloroform ND ug/L 5.0 0.43 1 05/09/24 07:21 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/09/24 07:21 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-MW-10 Lab ID: 92729146010 Collected: 05/06/24 08:25 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2024 04:04 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.24 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 95 % 70-130 98 % 70-130 102 % 70-130 1 05/09/24 07:21 96-12-8 1 05/09/24 07:21 124-48-1 1 05/09/24 07:21 106-93-4 1 05/09/24 07:21 74-95-3 1 05/09/24 07:21 95-50-1 1 05/09/24 07:21 106-46-7 1 05/09/24 07:21 110-57-6 v2 1 05/09/24 07:21 75-34-3 1 05/09/24 07:21 107-06-2 1 05/09/24 07:21 75-35-4 1 05/09/24 07:21 156-59-2 1 05/09/24 07:21 156-60-5 1 05/09/24 07:21 78-87-5 1 05/09/24 07:21 10061-01-5 1 05/09/24 07:21 10061-02-6 1 05/09/24 07:21 100-41-4 1 05/09/24 07:21 591-78-6 1 05/09/24 07:21 74-88-4 1 05/09/24 07:21 75-09-2 1 05/09/24 07:21 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/09/24 07:21 100-42-5 05/09/24 07:21 630-20-6 05/09/24 07:21 79-34-5 05/09/24 07:21 127-18-4 05/09/24 07:21 108-88-3 05/09/24 07:21 71-55-6 05/09/24 07:21 79-00-5 05/09/24 07:21 79-01-6 05/09/24 07:21 75-69-4 05/09/24 07:21 96-18-4 05/09/24 07:21 108-05-4 05/09/24 07:21 75-01-4 05/09/24 07:21 1330-20-7 05/09/24 07:21 460-00-4 05/09/24 07:21 17060-07-0 05/09/24 07:21 2037-26-5 Page 32 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-MW-11 Lab ID: 92729146011 Collected: 05/06/24 06:34 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 05/06/24 06:34 pH 4.91 Std. Units 1 05/06/24 06:34 Temperature 15.6 deg C 1 05/06/24 06:34 Static Water Level 83.52 feet 1 05/06/24 06:34 Specific Conductance 89.9 umhos/c 1 05/06/24 06:34 m Oxidation Potential 98.9 mV 1 05/06/24 06:34 Oxygen, Dissolved 2.03 mg/L 1 05/06/24 06:34 7782-44-7 Total Well Depth 108.40 feet 1 05/06/24 06:34 Turbidity 0.22 NTU 1 05/06/24 06:34 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.54 1 05/09/2414:06 05/14/2417:17 7440-36-0 Arsenic 0.92J ug/L 10.0 0.84 1 05/09/2414:06 05/14/2417:17 7440-38-2 Barium 124 ug/L 100 0.47 1 05/09/2414:06 05/14/2417:17 7440-39-3 Beryllium ND ug/L 1.0 0.094 1 05/09/2414:06 05/14/2417:17 7440-41-7 Cadmium ND ug/L 1.0 0.10 1 05/09/2414:06 05/14/2417:17 7440-43-9 Chromium ND ug/L 10.0 1.9 1 05/09/2414:06 05/14/2417:17 7440-47-3 Cobalt ND ug/L 10.0 0.32 1 05/09/2414:06 05/14/2417:17 7440-48-4 Copper 0.43J ug/L 10.0 0.43 1 05/09/2414:06 05/14/2417:17 7440-50-8 Lead ND ug/L 10.0 0.16 1 05/09/2414:06 05/14/2417:17 7439-92-1 Nickel ND ug/L 50.0 2.1 1 05/09/2414:06 05/14/2417:17 7440-02-0 Selenium ND ug/L 10.0 0.96 1 05/09/2414:06 05/14/2417:17 7782-49-2 Silver ND ug/L 10.0 0.31 1 05/09/2414:06 05/14/2417:17 7440-22-4 Thallium ND ug/L 5.5 0.38 1 05/09/2414:06 05/14/2417:17 7440-28-0 Vanadium 1.6J ug/L 25.0 0.75 1 05/09/2414:06 05/14/2417:17 7440-62-2 Zinc ND ug/L 10.0 2.4 1 05/09/2414:06 05/14/2417:17 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 05/09/24 07:39 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 05/09/24 07:39 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/09/24 07:39 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 05/09/24 07:39 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/09/24 07:39 75-27-4 Bromoform ND ug/L 3.0 0.34 1 05/09/24 07:39 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 05/09/24 07:39 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 05/09/24 07:39 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 05/09/24 07:39 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/09/24 07:39 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 05/09/24 07:39 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 05/09/24 07:39 75-00-3 Chloroform ND ug/L 5.0 0.43 1 05/09/24 07:39 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/09/24 07:39 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-MW-11 Lab ID: 92729146011 Collected: 05/06/24 06:34 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2024 04:04 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.24 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 96 % 70-130 100 % 70-130 103 % 70-130 1 05/09/24 07:39 96-12-8 1 05/09/24 07:39 124-48-1 1 05/09/24 07:39 106-93-4 1 05/09/24 07:39 74-95-3 1 05/09/24 07:39 95-50-1 1 05/09/24 07:39 106-46-7 1 05/09/24 07:39 110-57-6 v2 1 05/09/24 07:39 75-34-3 1 05/09/24 07:39 107-06-2 1 05/09/24 07:39 75-35-4 1 05/09/24 07:39 156-59-2 1 05/09/24 07:39 156-60-5 1 05/09/24 07:39 78-87-5 1 05/09/24 07:39 10061-01-5 1 05/09/24 07:39 10061-02-6 1 05/09/24 07:39 100-41-4 1 05/09/24 07:39 591-78-6 1 05/09/24 07:39 74-88-4 1 05/09/24 07:39 75-09-2 1 05/09/24 07:39 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/09/24 07:39 100-42-5 05/09/24 07:39 630-20-6 05/09/24 07:39 79-34-5 05/09/24 07:39 127-18-4 05/09/24 07:39 108-88-3 05/09/24 07:39 71-55-6 05/09/24 07:39 79-00-5 05/09/24 07:39 79-01-6 05/09/24 07:39 75-69-4 05/09/24 07:39 96-18-4 05/09/24 07:39 108-05-4 05/09/24 07:39 75-01-4 05/09/24 07:39 1330-20-7 05/09/24 07:39 460-00-4 05/09/24 07:39 17060-07-0 05/09/24 07:39 2037-26-5 Page 34 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-MW-12 Lab ID: 92729146012 Collected: 05/06/24 05:46 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 05/06/24 05:46 pH 4.52 Std. Units 1 05/06/24 05:46 Temperature 16.5 deg C 1 05/06/24 05:46 Static Water Level 98.70 feet 1 05/06/24 05:46 Specific Conductance 89.3 umhos/c 1 05/06/24 05:46 m Oxidation Potential 119.7 mV 1 05/06/24 05:46 Oxygen, Dissolved 2.05 mg/L 1 05/06/24 05:46 7782-44-7 Total Well Depth 131.65 feet 1 05/06/24 05:46 Turbidity 0.50 NTU 1 05/06/24 05:46 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.54 1 05/09/2414:06 05/14/2417:21 7440-36-0 Arsenic ND ug/L 10.0 0.84 1 05/09/2414:06 05/14/2417:21 7440-38-2 Barium 24.4J ug/L 100 0.47 1 05/09/2414:06 05/14/2417:21 7440-39-3 Beryllium ND ug/L 1.0 0.094 1 05/09/2414:06 05/14/2417:21 7440-41-7 Cadmium ND ug/L 1.0 0.10 1 05/09/2414:06 05/14/2417:21 7440-43-9 Chromium ND ug/L 10.0 1.9 1 05/09/2414:06 05/14/2417:21 7440-47-3 Cobalt ND ug/L 10.0 0.32 1 05/09/2414:06 05/14/2417:21 7440-48-4 Copper ND ug/L 10.0 0.43 1 05/09/2414:06 05/14/2417:21 7440-50-8 Lead ND ug/L 10.0 0.16 1 05/09/2414:06 05/14/2417:21 7439-92-1 Nickel ND ug/L 50.0 2.1 1 05/09/2414:06 05/14/2417:21 7440-02-0 Selenium ND ug/L 10.0 0.96 1 05/09/2414:06 05/14/2417:21 7782-49-2 Silver ND ug/L 10.0 0.31 1 05/09/2414:06 05/14/2417:21 7440-22-4 Thallium ND ug/L 5.5 0.38 1 05/09/2414:06 05/14/2417:21 7440-28-0 Vanadium 1.7J ug/L 25.0 0.75 1 05/09/2414:06 05/14/2417:21 7440-62-2 Zinc ND ug/L 10.0 2.4 1 05/09/2414:06 05/14/2417:21 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 05/09/24 08:34 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 05/09/24 08:34 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/09/24 08:34 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 05/09/24 08:34 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/09/24 08:34 75-27-4 Bromoform ND ug/L 3.0 0.34 1 05/09/24 08:34 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 05/09/24 08:34 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 05/09/24 08:34 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 05/09/24 08:34 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/09/24 08:34 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 05/09/24 08:34 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 05/09/24 08:34 75-00-3 Chloroform ND ug/L 5.0 0.43 1 05/09/24 08:34 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/09/24 08:34 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-MW-12 Lab ID: 92729146012 Collected: 05/06/24 05:46 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2024 04:04 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.24 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 95 % 70-130 102 % 70-130 103 % 70-130 1 05/09/24 08:34 96-12-8 1 05/09/24 08:34 124-48-1 1 05/09/24 08:34 106-93-4 1 05/09/24 08:34 74-95-3 1 05/09/24 08:34 95-50-1 1 05/09/24 08:34 106-46-7 1 05/09/24 08:34 110-57-6 v2 1 05/09/24 08:34 75-34-3 1 05/09/24 08:34 107-06-2 1 05/09/24 08:34 75-35-4 1 05/09/24 08:34 156-59-2 1 05/09/24 08:34 156-60-5 1 05/09/24 08:34 78-87-5 1 05/09/24 08:34 10061-01-5 1 05/09/24 08:34 10061-02-6 1 05/09/24 08:34 100-41-4 1 05/09/24 08:34 591-78-6 1 05/09/24 08:34 74-88-4 1 05/09/24 08:34 75-09-2 1 05/09/24 08:34 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/09/24 08:34 100-42-5 05/09/24 08:34 630-20-6 05/09/24 08:34 79-34-5 05/09/24 08:34 127-18-4 05/09/24 08:34 108-88-3 05/09/24 08:34 71-55-6 05/09/24 08:34 79-00-5 05/09/24 08:34 79-01-6 05/09/24 08:34 75-69-4 05/09/24 08:34 96-18-4 05/09/24 08:34 108-05-4 05/09/24 08:34 75-01-4 05/09/24 08:34 1330-20-7 05/09/24 08:34 460-00-4 05/09/24 08:34 17060-07-0 05/09/24 08:34 2037-26-5 Page 36 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-Field Blank Lab ID: 92729146013 Collected: 05/05/24 15:32 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.54 1 05/09/2414:06 05/14/2417:25 7440-36-0 Arsenic ND ug/L 10.0 0.84 1 05/09/2414:06 05/14/2417:25 7440-38-2 Barium ND ug/L 100 0.47 1 05/09/2414:06 05/14/2417:25 7440-39-3 Beryllium ND ug/L 1.0 0.094 1 05/09/2414:06 05/14/2417:25 7440-41-7 Cadmium ND ug/L 1.0 0.10 1 05/09/2414:06 05/14/2417:25 7440-43-9 Chromium ND ug/L 10.0 1.9 1 05/09/2414:06 05/14/2417:25 7440-47-3 Cobalt ND ug/L 10.0 0.32 1 05/09/2414:06 05/14/2417:25 7440-48-4 Copper ND ug/L 10.0 0.43 1 05/09/2414:06 05/14/2417:25 7440-50-8 Lead ND ug/L 10.0 0.16 1 05/09/2414:06 05/14/2417:25 7439-92-1 Nickel ND ug/L 50.0 2.1 1 05/09/2414:06 05/14/2417:25 7440-02-0 Selenium ND ug/L 10.0 0.96 1 05/09/2414:06 05/14/2417:25 7782-49-2 Silver ND ug/L 10.0 0.31 1 05/09/2414:06 05/14/2417:25 7440-22-4 Thallium ND ug/L 5.5 0.38 1 05/09/2414:06 05/14/2417:25 7440-28-0 Vanadium 1.5J ug/L 25.0 0.75 1 05/09/2414:06 05/14/2417:25 7440-62-2 Zinc ND ug/L 10.0 2.4 1 05/09/2414:06 05/14/2417:25 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 05/09/24 03:25 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 05/09/24 03:25 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/09/24 03:25 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 05/09/24 03:25 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/09/24 03:25 75-27-4 Bromoform ND ug/L 3.0 0.34 1 05/09/24 03:25 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 05/09/24 03:25 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 05/09/24 03:25 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 05/09/24 03:25 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/09/24 03:25 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 05/09/24 03:25 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 05/09/24 03:25 75-00-3 Chloroform ND ug/L 5.0 0.43 1 05/09/24 03:25 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/09/24 03:25 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.34 1 05/09/24 03:25 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.36 1 05/09/24 03:25 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.27 1 05/09/24 03:25 106-93-4 Dibromomethane ND ug/L 10.0 0.39 1 05/09/24 03:25 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.34 1 05/09/24 03:25 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 05/09/24 03:25 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 0.56 1 05/09/24 03:25 110-57-6 v2 butene 1,1-Dichloroethane ND ug/L 5.0 0.37 1 05/09/24 03:25 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 05/09/24 03:25 107-06-2 1,1-Dichloroethene ND ug/L 5.0 0.35 1 05/09/24 03:25 75-35-4 cis-1,2-Dichloroethene ND ug/L 5.0 0.38 1 05/09/24 03:25 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-Field Blank Lab ID: 92729146013 Collected: 05/05/24 15:32 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2024 04:04 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 5.0 0.40 1 05/09/24 03:25 156-60-5 ND ug/L 1.0 0.36 1 05/09/24 03:25 78-87-5 ND ug/L 1.0 0.36 1 05/09/24 03:25 10061-01-5 ND ug/L 1.0 0.36 1 05/09/24 03:25 10061-02-6 ND ug/L 1.0 0.30 1 05/09/24 03:25 100-41-4 ND ug/L 50.0 0.48 1 05/09/24 03:25 591-78-6 ND ug/L 20.0 9.7 1 05/09/24 03:25 74-88-4 ND ug/L 5.0 2.0 1 05/09/24 03:25 75-09-2 ND ug/L 100 2.7 1 05/09/24 03:25 108-10-1 ND ug/L 1.0 0.29 1 05/09/24 03:25 100-42-5 ND ug/L 5.0 0.31 1 05/09/24 03:25 630-20-6 ND ug/L 3.0 0.22 1 05/09/24 03:25 79-34-5 ND ug/L 1.0 0.29 1 05/09/24 03:25 127-18-4 ND ug/L 1.0 0.24 1 05/09/24 03:25 108-88-3 ND ug/L 1.0 0.33 1 05/09/24 03:25 71-55-6 ND ug/L 1.0 0.32 1 05/09/24 03:25 79-00-5 ND ug/L 1.0 0.38 1 05/09/24 03:25 79-01-6 ND ug/L 1.0 0.30 1 05/09/24 03:25 75-69-4 ND ug/L 1.0 0.26 1 05/09/24 03:25 96-18-4 ND ug/L 50.0 1.3 1 05/09/24 03:25 108-05-4 ND ug/L 1.0 0.39 1 05/09/24 03:25 75-01-4 ND ug/L 5.0 0.34 1 05/09/24 03:25 1330-20-7 97 % 70-130 1 05/09/24 03:25 460-00-4 97 % 70-130 1 05/09/24 03:25 17060-07-0 101 % 70-130 1 05/09/24 03:25 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 38 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-SW1 Lab ID: 92729146014 Collected: 05/05/24 15:38 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 05/06/24 15:38 pH 5.90 Std. Units 1 05/06/24 15:38 Temperature 19.1 deg C 1 05/06/24 15:38 Specific Conductance 66.2 umhos/c 1 05/06/24 15:38 m Oxidation Potential 63.6 mV 1 05/06/24 15:38 Oxygen, Dissolved 3.75 mg/L 1 05/06/24 15:38 7782-44-7 Turbidity 44.90 NTU 1 05/06/24 15:38 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.54 1 05/09/2414:06 05/14/2417:28 7440-36-0 Arsenic ND ug/L 10.0 0.84 1 05/09/2414:06 05/14/2417:28 7440-38-2 Barium 27.OJ ug/L 100 0.47 1 05/09/2414:06 05/14/2417:28 7440-39-3 Beryllium 0.17J ug/L 1.0 0.094 1 05/09/2414:06 05/14/2417:28 7440-41-7 Cadmium ND ug/L 1.0 0.10 1 05/09/2414:06 05/14/2417:28 7440-43-9 Chromium 2.6J ug/L 10.0 1.9 1 05/09/2414:06 05/14/2417:28 7440-47-3 Cobalt 1.1J ug/L 10.0 0.32 1 05/09/2414:06 05/14/2417:28 7440-48-4 Copper 2.2J ug/L 10.0 0.43 1 05/09/2414:06 05/14/2417:28 7440-50-8 Lead 1.6J ug/L 10.0 0.16 1 05/09/2414:06 05/14/2417:28 7439-92-1 Nickel ND ug/L 50.0 2.1 1 05/09/2414:06 05/14/2417:28 7440-02-0 Selenium ND ug/L 10.0 0.96 1 05/09/2414:06 05/14/2417:28 7782-49-2 Silver ND ug/L 10.0 0.31 1 05/09/2414:06 05/14/2417:28 7440-22-4 Thallium ND ug/L 5.5 0.38 1 05/09/2414:06 05/14/2417:28 7440-28-0 Vanadium 6.9J ug/L 25.0 0.75 1 05/09/2414:06 05/14/2417:28 7440-62-2 Zinc 4.2J ug/L 10.0 2.4 1 05/09/2414:06 05/14/2417:28 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 05/09/24 07:57 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 05/09/24 07:57 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/09/24 07:57 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 05/09/24 07:57 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/09/24 07:57 75-27-4 Bromoform ND ug/L 3.0 0.34 1 05/09/24 07:57 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 05/09/24 07:57 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 05/09/24 07:57 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 05/09/24 07:57 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/09/24 07:57 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 05/09/24 07:57 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 05/09/24 07:57 75-00-3 Chloroform ND ug/L 5.0 0.43 1 05/09/24 07:57 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/09/24 07:57 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.34 1 05/09/24 07:57 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 39 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-SW1 Lab ID: 92729146014 Collected: 05/05/24 15:38 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2024 04:04 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.36 1 05/09/24 07:57 124-48-1 ND ug/L 2.0 0.27 1 05/09/24 07:57 106-93-4 ND ug/L 10.0 0.39 1 05/09/24 07:57 74-95-3 ND ug/L 5.0 0.34 1 05/09/24 07:57 95-50-1 ND ug/L 1.0 0.33 1 05/09/24 07:57 106-46-7 ND ug/L 100 0.56 1 05/09/24 07:57 110-57-6 ND ug/L 5.0 0.37 1 05/09/24 07:57 75-34-3 ND ug/L 1.0 0.32 1 05/09/24 07:57 107-06-2 ND ug/L 5.0 0.35 1 05/09/24 07:57 75-35-4 ND ug/L 5.0 0.38 1 05/09/24 07:57 156-59-2 ND ug/L 5.0 0.40 1 05/09/24 07:57 156-60-5 ND ug/L 1.0 0.36 1 05/09/24 07:57 78-87-5 ND ug/L 1.0 0.36 1 05/09/24 07:57 10061-01-5 ND ug/L 1.0 0.36 1 05/09/24 07:57 10061-02-6 ND ug/L 1.0 0.30 1 05/09/24 07:57 100-41-4 ND ug/L 50.0 0.48 1 05/09/24 07:57 591-78-6 ND ug/L 20.0 9.7 1 05/09/24 07:57 74-88-4 ND ug/L 5.0 2.0 1 05/09/24 07:57 75-09-2 ND ug/L 100 2.7 1 05/09/24 07:57 108-10-1 ND ug/L 1.0 0.29 1 05/09/24 07:57 100-42-5 ND ug/L 5.0 0.31 1 05/09/24 07:57 630-20-6 ND ug/L 3.0 0.22 1 05/09/24 07:57 79-34-5 ND ug/L 1.0 0.29 1 05/09/24 07:57 127-18-4 ND ug/L 1.0 0.24 1 05/09/24 07:57 108-88-3 ND ug/L 1.0 0.33 1 05/09/24 07:57 71-55-6 ND ug/L 1.0 0.32 1 05/09/24 07:57 79-00-5 ND ug/L 1.0 0.38 1 05/09/24 07:57 79-01-6 ND ug/L 1.0 0.30 1 05/09/24 07:57 75-69-4 ND ug/L 1.0 0.26 1 05/09/24 07:57 96-18-4 ND ug/L 50.0 1.3 1 05/09/24 07:57 108-05-4 ND ug/L 1.0 0.39 1 05/09/24 07:57 75-01-4 ND ug/L 5.0 0.34 1 05/09/24 07:57 1330-20-7 98 % 70-130 1 05/09/24 07:57 460-00-4 103 % 70-130 1 05/09/24 07:57 17060-07-0 102 % 70-130 1 05/09/24 07:57 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 40 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-SW2 Lab ID: 92729146015 Collected: 05/05/24 16:35 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 05/06/24 16:35 pH 6.21 Std. Units 1 05/06/24 16:35 Temperature 20.2 deg C 1 05/06/24 16:35 Specific Conductance 71.3 umhos/c 1 05/06/24 16:35 m Oxidation Potential 31.3 mV 1 05/06/24 16:35 Oxygen, Dissolved 3.96 mg/L 1 05/06/24 16:35 7782-44-7 Turbidity 55.40 NTU 1 05/06/24 16:35 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.54 1 05/09/2414:06 05/14/2417:32 7440-36-0 Arsenic ND ug/L 10.0 0.84 1 05/09/2414:06 05/14/2417:32 7440-38-2 Barium 34.2J ug/L 100 0.47 1 05/09/2414:06 05/14/2417:32 7440-39-3 Beryllium 0.23J ug/L 1.0 0.094 1 05/09/2414:06 05/14/2417:32 7440-41-7 Cadmium ND ug/L 1.0 0.10 1 05/09/2414:06 05/14/2417:32 7440-43-9 Chromium 3.3J ug/L 10.0 1.9 1 05/09/2414:06 05/14/2417:32 7440-47-3 Cobalt 1.4J ug/L 10.0 0.32 1 05/09/2414:06 05/14/2417:32 7440-48-4 Copper 2.9J ug/L 10.0 0.43 1 05/09/2414:06 05/14/2417:32 7440-50-8 Lead 2.1J ug/L 10.0 0.16 1 05/09/2414:06 05/14/2417:32 7439-92-1 Nickel ND ug/L 50.0 2.1 1 05/09/2414:06 05/14/2417:32 7440-02-0 Selenium ND ug/L 10.0 0.96 1 05/09/2414:06 05/14/2417:32 7782-49-2 Silver ND ug/L 10.0 0.31 1 05/09/2414:06 05/14/2417:32 7440-22-4 Thallium ND ug/L 5.5 0.38 1 05/09/2414:06 05/14/2417:32 7440-28-0 Vanadium 8.4J ug/L 25.0 0.75 1 05/09/2414:06 05/14/2417:32 7440-62-2 Zinc 5.1J ug/L 10.0 2.4 1 05/09/2414:06 05/14/2417:32 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 05/09/24 08:16 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 05/09/24 08:16 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/09/24 08:16 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 05/09/24 08:16 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/09/24 08:16 75-27-4 Bromoform ND ug/L 3.0 0.34 1 05/09/24 08:16 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 05/09/24 08:16 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 05/09/24 08:16 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 05/09/24 08:16 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/09/24 08:16 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 05/09/24 08:16 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 05/09/24 08:16 75-00-3 Chloroform ND ug/L 5.0 0.43 1 05/09/24 08:16 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/09/24 08:16 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.34 1 05/09/24 08:16 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-SW2 Lab ID: 92729146015 Collected: 05/05/24 16:35 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2024 04:04 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.36 1 05/09/24 08:16 124-48-1 ND ug/L 2.0 0.27 1 05/09/24 08:16 106-93-4 ND ug/L 10.0 0.39 1 05/09/24 08:16 74-95-3 ND ug/L 5.0 0.34 1 05/09/24 08:16 95-50-1 ND ug/L 1.0 0.33 1 05/09/24 08:16 106-46-7 ND ug/L 100 0.56 1 05/09/24 08:16 110-57-6 ND ug/L 5.0 0.37 1 05/09/24 08:16 75-34-3 ND ug/L 1.0 0.32 1 05/09/24 08:16 107-06-2 ND ug/L 5.0 0.35 1 05/09/24 08:16 75-35-4 ND ug/L 5.0 0.38 1 05/09/24 08:16 156-59-2 ND ug/L 5.0 0.40 1 05/09/24 08:16 156-60-5 ND ug/L 1.0 0.36 1 05/09/24 08:16 78-87-5 ND ug/L 1.0 0.36 1 05/09/24 08:16 10061-01-5 ND ug/L 1.0 0.36 1 05/09/24 08:16 10061-02-6 ND ug/L 1.0 0.30 1 05/09/24 08:16 100-41-4 ND ug/L 50.0 0.48 1 05/09/24 08:16 591-78-6 ND ug/L 20.0 9.7 1 05/09/24 08:16 74-88-4 ND ug/L 5.0 2.0 1 05/09/24 08:16 75-09-2 ND ug/L 100 2.7 1 05/09/24 08:16 108-10-1 ND ug/L 1.0 0.29 1 05/09/24 08:16 100-42-5 ND ug/L 5.0 0.31 1 05/09/24 08:16 630-20-6 ND ug/L 3.0 0.22 1 05/09/24 08:16 79-34-5 ND ug/L 1.0 0.29 1 05/09/24 08:16 127-18-4 ND ug/L 1.0 0.24 1 05/09/24 08:16 108-88-3 ND ug/L 1.0 0.33 1 05/09/24 08:16 71-55-6 ND ug/L 1.0 0.32 1 05/09/24 08:16 79-00-5 ND ug/L 1.0 0.38 1 05/09/24 08:16 79-01-6 ND ug/L 1.0 0.30 1 05/09/24 08:16 75-69-4 ND ug/L 1.0 0.26 1 05/09/24 08:16 96-18-4 ND ug/L 50.0 1.3 1 05/09/24 08:16 108-05-4 ND ug/L 1.0 0.39 1 05/09/24 08:16 75-01-4 ND ug/L 5.0 0.34 1 05/09/24 08:16 1330-20-7 95 % 70-130 1 05/09/24 08:16 460-00-4 104 % 70-130 1 05/09/24 08:16 17060-07-0 103 % 70-130 1 05/09/24 08:16 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 42 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-SW3 (MS/MSD) Lab ID: 92729146016 Collected: 05/05/24 17:40 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 05/06/24 17:40 pH 6.89 Std. Units 1 05/06/24 17:40 Temperature 18.5 deg C 1 05/06/24 17:40 Specific Conductance 51.0 umhos/c 1 05/06/24 17:40 m Oxidation Potential -6.2 mV 1 05/06/24 17:40 Oxygen, Dissolved 5.26 mg/L 1 05/06/24 17:40 7782-44-7 Turbidity 60.30 NTU 1 05/06/24 17:40 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.54 1 05/09/2414:06 05/14/2417:36 7440-36-0 Arsenic ND ug/L 10.0 0.84 1 05/09/2414:06 05/14/2417:36 7440-38-2 Barium 30.4J ug/L 100 0.47 1 05/09/2414:06 05/14/2417:36 7440-39-3 Beryllium 0.13J ug/L 1.0 0.094 1 05/09/2414:06 05/14/2417:36 7440-41-7 Cadmium ND ug/L 1.0 0.10 1 05/09/2414:06 05/14/2417:36 7440-43-9 Chromium 3.5J ug/L 10.0 1.9 1 05/09/2414:06 05/14/2417:36 7440-47-3 Cobalt 1.2J ug/L 10.0 0.32 1 05/09/2414:06 05/14/2417:36 7440-48-4 Copper 2.7J ug/L 10.0 0.43 1 05/09/2414:06 05/14/2417:36 7440-50-8 Lead 1.5J ug/L 10.0 0.16 1 05/09/2414:06 05/14/2417:36 7439-92-1 Nickel ND ug/L 50.0 2.1 1 05/09/2414:06 05/14/2417:36 7440-02-0 Selenium ND ug/L 10.0 0.96 1 05/09/2414:06 05/14/2417:36 7782-49-2 Silver ND ug/L 10.0 0.31 1 05/09/2414:06 05/14/2417:36 7440-22-4 Thallium ND ug/L 5.5 0.38 1 05/09/2414:06 05/14/2417:36 7440-28-0 Vanadium 8.3J ug/L 25.0 0.75 1 05/09/2414:06 05/14/2417:36 7440-62-2 Zinc 5.1J ug/L 10.0 2.4 1 05/09/2414:06 05/14/2417:36 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 05/09/24 14:54 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 05/09/24 14:54 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/09/24 14:54 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 05/09/24 14:54 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/09/24 14:54 75-27-4 Bromoform ND ug/L 3.0 0.34 1 05/09/24 14:54 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 05/09/24 14:54 74-83-9 IH,M1, v1 2-Butanone (MEK) ND ug/L 100 4.0 1 05/09/24 14:54 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 05/09/24 14:54 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/09/24 14:54 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 05/09/24 14:54 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 05/09/24 14:54 75-00-3 v1 Chloroform ND ug/L 5.0 0.43 1 05/09/24 14:54 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/09/24 14:54 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.34 1 05/09/24 14:54 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 43 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-SW3 (MS/MSD) Lab ID: 92729146016 Collected: 05/05/24 17:40 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2024 04:04 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.36 1 05/09/24 14:54 124-48-1 ND ug/L 2.0 0.27 1 05/09/24 14:54 106-93-4 ND ug/L 10.0 0.39 1 05/09/24 14:54 74-95-3 ND ug/L 5.0 0.34 1 05/09/24 14:54 95-50-1 ND ug/L 1.0 0.33 1 05/09/24 14:54 106-46-7 ND ug/L 100 0.56 1 05/09/24 14:54 110-57-6 ND ug/L 5.0 0.37 1 05/09/24 14:54 75-34-3 ND ug/L 1.0 0.32 1 05/09/24 14:54 107-06-2 ND ug/L 5.0 0.35 1 05/09/24 14:54 75-35-4 ND ug/L 5.0 0.38 1 05/09/24 14:54 156-59-2 ND ug/L 5.0 0.40 1 05/09/24 14:54 156-60-5 ND ug/L 1.0 0.36 1 05/09/24 14:54 78-87-5 ND ug/L 1.0 0.36 1 05/09/24 14:54 10061-01-5 ND ug/L 1.0 0.36 1 05/09/24 14:54 10061-02-6 ND ug/L 1.0 0.30 1 05/09/24 14:54 100-41-4 ND ug/L 50.0 0.48 1 05/09/24 14:54 591-78-6 ND ug/L 20.0 9.7 1 05/09/24 14:54 74-88-4 ND ug/L 5.0 2.0 1 05/09/24 14:54 75-09-2 ND ug/L 100 2.7 1 05/09/24 14:54 108-10-1 ND ug/L 1.0 0.29 1 05/09/24 14:54 100-42-5 ND ug/L 5.0 0.31 1 05/09/24 14:54 630-20-6 ND ug/L 3.0 0.22 1 05/09/24 14:54 79-34-5 ND ug/L 1.0 0.29 1 05/09/24 14:54 127-18-4 ND ug/L 1.0 0.24 1 05/09/24 14:54 108-88-3 ND ug/L 1.0 0.33 1 05/09/24 14:54 71-55-6 ND ug/L 1.0 0.32 1 05/09/24 14:54 79-00-5 ND ug/L 1.0 0.38 1 05/09/24 14:54 79-01-6 ND ug/L 1.0 0.30 1 05/09/24 14:54 75-69-4 ND ug/L 1.0 0.26 1 05/09/24 14:54 96-18-4 ND ug/L 50.0 1.3 1 05/09/24 14:54 108-05-4 ND ug/L 1.0 0.39 1 05/09/24 14:54 75-01-4 ND ug/L 5.0 0.34 1 05/09/24 14:54 1330-20-7 100 % 70-130 1 05/09/24 14:54 460-00-4 105 % 70-130 1 05/09/24 14:54 17060-07-0 105 % 70-130 1 05/09/24 14:54 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 44 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-SW4 Lab ID: 92729146017 Collected: 05/05/24 17:18 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 05/06/24 17:18 pH 7.04 Std. Units 1 05/06/24 17:18 Temperature 18.8 deg C 1 05/06/24 17:18 Specific Conductance 53.9 umhos/c 1 05/06/24 17:18 m Oxidation Potential -14.0 mV 1 05/06/24 17:18 Oxygen, Dissolved 5.18 mg/L 1 05/06/24 17:18 7782-44-7 Turbidity 89.20 NTU 1 05/06/24 17:18 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony 1.3J ug/L 6.0 0.54 1 05/09/2414:06 05/14/2418:06 7440-36-0 Arsenic ND ug/L 10.0 0.84 1 05/09/2414:06 05/14/2418:06 7440-38-2 Barium 47.4J ug/L 100 0.47 1 05/09/2414:06 05/14/2418:06 7440-39-3 Beryllium 0.37J ug/L 1.0 0.094 1 05/09/2414:06 05/14/2418:06 7440-41-7 Cadmium ND ug/L 1.0 0.10 1 05/09/2414:06 05/14/2418:06 7440-43-9 Chromium 5.9J ug/L 10.0 1.9 1 05/09/2414:06 05/14/2418:06 7440-47-3 Cobalt 2.4J ug/L 10.0 0.32 1 05/09/2414:06 05/14/2418:06 7440-48-4 Copper 5.9J ug/L 10.0 0.43 1 05/09/2414:06 05/14/2418:06 7440-50-8 Lead 3.4J ug/L 10.0 0.16 1 05/09/2414:06 05/14/2418:06 7439-92-1 Nickel 2.7J ug/L 50.0 2.1 1 05/09/2414:06 05/14/2418:06 7440-02-0 Selenium ND ug/L 10.0 0.96 1 05/09/2414:06 05/14/2418:06 7782-49-2 Silver ND ug/L 10.0 0.31 1 05/09/2414:06 05/14/2418:06 7440-22-4 Thallium ND ug/L 5.5 0.38 1 05/09/2414:06 05/14/2418:06 7440-28-0 Vanadium 13.9J ug/L 25.0 0.75 1 05/09/2414:06 05/14/2418:06 7440-62-2 Zinc 13.1 ug/L 10.0 2.4 1 05/09/2414:06 05/14/2418:06 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 05/09/24 11:47 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 05/09/24 11:47 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/09/24 11:47 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 05/09/24 11:47 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/09/24 11:47 75-27-4 Bromoform ND ug/L 3.0 0.34 1 05/09/24 11:47 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 05/09/24 11:47 74-83-9 IH,v1 2-Butanone (MEK) ND ug/L 100 4.0 1 05/09/24 11:47 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 05/09/24 11:47 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/09/24 11:47 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 05/09/24 11:47 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 05/09/24 11:47 75-00-3 v1 Chloroform ND ug/L 5.0 0.43 1 05/09/24 11:47 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/09/24 11:47 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.34 1 05/09/24 11:47 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-SW4 Lab ID: 92729146017 Collected: 05/05/24 17:18 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2024 04:04 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.36 1 05/09/24 11:47 124-48-1 ND ug/L 2.0 0.27 1 05/09/24 11:47 106-93-4 ND ug/L 10.0 0.39 1 05/09/24 11:47 74-95-3 ND ug/L 5.0 0.34 1 05/09/24 11:47 95-50-1 ND ug/L 1.0 0.33 1 05/09/24 11:47 106-46-7 ND ug/L 100 0.56 1 05/09/24 11:47 110-57-6 ND ug/L 5.0 0.37 1 05/09/24 11:47 75-34-3 ND ug/L 1.0 0.32 1 05/09/24 11:47 107-06-2 ND ug/L 5.0 0.35 1 05/09/24 11:47 75-35-4 ND ug/L 5.0 0.38 1 05/09/24 11:47 156-59-2 ND ug/L 5.0 0.40 1 05/09/24 11:47 156-60-5 ND ug/L 1.0 0.36 1 05/09/24 11:47 78-87-5 ND ug/L 1.0 0.36 1 05/09/24 11:47 10061-01-5 ND ug/L 1.0 0.36 1 05/09/24 11:47 10061-02-6 ND ug/L 1.0 0.30 1 05/09/24 11:47 100-41-4 ND ug/L 50.0 0.48 1 05/09/24 11:47 591-78-6 ND ug/L 20.0 9.7 1 05/09/24 11:47 74-88-4 ND ug/L 5.0 2.0 1 05/09/24 11:47 75-09-2 ND ug/L 100 2.7 1 05/09/24 11:47 108-10-1 ND ug/L 1.0 0.29 1 05/09/24 11:47 100-42-5 ND ug/L 5.0 0.31 1 05/09/24 11:47 630-20-6 ND ug/L 3.0 0.22 1 05/09/24 11:47 79-34-5 ND ug/L 1.0 0.29 1 05/09/24 11:47 127-18-4 ND ug/L 1.0 0.24 1 05/09/24 11:47 108-88-3 ND ug/L 1.0 0.33 1 05/09/24 11:47 71-55-6 ND ug/L 1.0 0.32 1 05/09/24 11:47 79-00-5 ND ug/L 1.0 0.38 1 05/09/24 11:47 79-01-6 ND ug/L 1.0 0.30 1 05/09/24 11:47 75-69-4 ND ug/L 1.0 0.26 1 05/09/24 11:47 96-18-4 ND ug/L 50.0 1.3 1 05/09/24 11:47 108-05-4 ND ug/L 1.0 0.39 1 05/09/24 11:47 75-01-4 ND ug/L 5.0 0.34 1 05/09/24 11:47 1330-20-7 99 % 70-130 1 05/09/24 11:47 460-00-4 109 % 70-130 1 05/09/24 11:47 17060-07-0 102 % 70-130 1 05/09/24 11:47 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 46 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-SW5 Lab ID: 92729146018 Collected: 05/05/24 16:54 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 05/06/24 16:54 pH 6.08 Std. Units 1 05/06/24 16:54 Temperature 18.5 deg C 1 05/06/24 16:54 Specific Conductance 140.2 umhos/c 1 05/06/24 16:54 m Oxidation Potential 50.6 mV 1 05/06/24 16:54 Oxygen, Dissolved 4.12 mg/L 1 05/06/24 16:54 7782-44-7 Turbidity 36.20 NTU 1 05/06/24 16:54 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.54 1 05/09/2414:06 05/14/2418:09 7440-36-0 Arsenic ND ug/L 10.0 0.84 1 05/09/2414:06 05/14/2418:09 7440-38-2 Barium 26.7J ug/L 100 0.47 1 05/09/2414:06 05/14/2418:09 7440-39-3 Beryllium 0.17J ug/L 1.0 0.094 1 05/09/2414:06 05/14/2418:09 7440-41-7 Cadmium ND ug/L 1.0 0.10 1 05/09/2414:06 05/14/2418:09 7440-43-9 Chromium 2.5J ug/L 10.0 1.9 1 05/09/2414:06 05/14/2418:09 7440-47-3 Cobalt 1.1J ug/L 10.0 0.32 1 05/09/2414:06 05/14/2418:09 7440-48-4 Copper 2.2J ug/L 10.0 0.43 1 05/09/2414:06 05/14/2418:09 7440-50-8 Lead 1.6J ug/L 10.0 0.16 1 05/09/2414:06 05/14/2418:09 7439-92-1 Nickel ND ug/L 50.0 2.1 1 05/09/2414:06 05/14/2418:09 7440-02-0 Selenium ND ug/L 10.0 0.96 1 05/09/2414:06 05/14/2418:09 7782-49-2 Silver ND ug/L 10.0 0.31 1 05/09/2414:06 05/14/2418:09 7440-22-4 Thallium ND ug/L 5.5 0.38 1 05/09/2414:06 05/14/2418:09 7440-28-0 Vanadium 5.6J ug/L 25.0 0.75 1 05/09/2414:06 05/14/2418:09 7440-62-2 Zinc 3.8J ug/L 10.0 2.4 1 05/09/2414:06 05/14/2418:09 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 05/09/24 12:06 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 05/09/24 12:06 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/09/24 12:06 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 05/09/24 12:06 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/09/24 12:06 75-27-4 Bromoform ND ug/L 3.0 0.34 1 05/09/24 12:06 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 05/09/24 12:06 74-83-9 IH,v1 2-Butanone (MEK) ND ug/L 100 4.0 1 05/09/24 12:06 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 05/09/24 12:06 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/09/24 12:06 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 05/09/24 12:06 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 05/09/24 12:06 75-00-3 v1 Chloroform ND ug/L 5.0 0.43 1 05/09/24 12:06 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/09/24 12:06 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.34 1 05/09/24 12:06 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 47 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-SW5 Lab ID: 92729146018 Collected: 05/05/24 16:54 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2024 04:04 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.36 1 05/09/24 12:06 124-48-1 ND ug/L 2.0 0.27 1 05/09/24 12:06 106-93-4 ND ug/L 10.0 0.39 1 05/09/24 12:06 74-95-3 ND ug/L 5.0 0.34 1 05/09/24 12:06 95-50-1 ND ug/L 1.0 0.33 1 05/09/24 12:06 106-46-7 ND ug/L 100 0.56 1 05/09/24 12:06 110-57-6 ND ug/L 5.0 0.37 1 05/09/24 12:06 75-34-3 ND ug/L 1.0 0.32 1 05/09/24 12:06 107-06-2 ND ug/L 5.0 0.35 1 05/09/24 12:06 75-35-4 ND ug/L 5.0 0.38 1 05/09/24 12:06 156-59-2 ND ug/L 5.0 0.40 1 05/09/24 12:06 156-60-5 ND ug/L 1.0 0.36 1 05/09/24 12:06 78-87-5 ND ug/L 1.0 0.36 1 05/09/24 12:06 10061-01-5 ND ug/L 1.0 0.36 1 05/09/24 12:06 10061-02-6 ND ug/L 1.0 0.30 1 05/09/24 12:06 100-41-4 ND ug/L 50.0 0.48 1 05/09/24 12:06 591-78-6 ND ug/L 20.0 9.7 1 05/09/24 12:06 74-88-4 ND ug/L 5.0 2.0 1 05/09/24 12:06 75-09-2 ND ug/L 100 2.7 1 05/09/24 12:06 108-10-1 ND ug/L 1.0 0.29 1 05/09/24 12:06 100-42-5 ND ug/L 5.0 0.31 1 05/09/24 12:06 630-20-6 ND ug/L 3.0 0.22 1 05/09/24 12:06 79-34-5 ND ug/L 1.0 0.29 1 05/09/24 12:06 127-18-4 ND ug/L 1.0 0.24 1 05/09/24 12:06 108-88-3 ND ug/L 1.0 0.33 1 05/09/24 12:06 71-55-6 ND ug/L 1.0 0.32 1 05/09/24 12:06 79-00-5 ND ug/L 1.0 0.38 1 05/09/24 12:06 79-01-6 ND ug/L 1.0 0.30 1 05/09/24 12:06 75-69-4 ND ug/L 1.0 0.26 1 05/09/24 12:06 96-18-4 ND ug/L 50.0 1.3 1 05/09/24 12:06 108-05-4 ND ug/L 1.0 0.39 1 05/09/24 12:06 75-01-4 ND ug/L 5.0 0.34 1 05/09/24 12:06 1330-20-7 99 % 70-130 1 05/09/24 12:06 460-00-4 106 % 70-130 1 05/09/24 12:06 17060-07-0 105 % 70-130 1 05/09/24 12:06 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 48 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-UD1 Lab ID: 92729146019 Collected: 05/05/24 16:17 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 05/06/24 16:17 pH 5.18 Std. Units 1 05/06/24 16:17 Temperature 18.1 deg C 1 05/06/24 16:17 Specific Conductance 222 umhos/c 1 05/06/24 16:17 m Oxidation Potential 86.6 mV 1 05/06/24 16:17 Oxygen, Dissolved 3.66 mg/L 1 05/06/24 16:17 7782-44-7 Turbidity 8.57 NTU 1 05/06/24 16:17 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.54 1 05/09/2414:06 05/14/2418:13 7440-36-0 Arsenic 0.86J ug/L 10.0 0.84 1 05/09/2414:06 05/14/2418:13 7440-38-2 Barium 73.4J ug/L 100 0.47 1 05/09/2414:06 05/14/2418:13 7440-39-3 Beryllium ND ug/L 1.0 0.094 1 05/09/2414:06 05/14/2418:13 7440-41-7 Cadmium ND ug/L 1.0 0.10 1 05/09/2414:06 05/14/2418:13 7440-43-9 Chromium ND ug/L 10.0 1.9 1 05/09/2414:06 05/14/2418:13 7440-47-3 Cobalt 8.1J ug/L 10.0 0.32 1 05/09/2414:06 05/14/2418:13 7440-48-4 Copper ND ug/L 10.0 0.43 1 05/09/2414:06 05/14/2418:13 7440-50-8 Lead 0.28J ug/L 10.0 0.16 1 05/09/2414:06 05/14/2418:13 7439-92-1 Nickel ND ug/L 50.0 2.1 1 05/09/2414:06 05/14/2418:13 7440-02-0 Selenium ND ug/L 10.0 0.96 1 05/09/2414:06 05/14/2418:13 7782-49-2 Silver ND ug/L 10.0 0.31 1 05/09/2414:06 05/14/2418:13 7440-22-4 Thallium ND ug/L 5.5 0.38 1 05/09/2414:06 05/14/2418:13 7440-28-0 Vanadium 2.5J ug/L 25.0 0.75 1 05/09/2414:06 05/14/2418:13 7440-62-2 Zinc ND ug/L 10.0 2.4 1 05/09/2414:06 05/14/2418:13 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 05/09/24 12:24 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 05/09/24 12:24 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/09/24 12:24 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 05/09/24 12:24 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/09/24 12:24 75-27-4 Bromoform ND ug/L 3.0 0.34 1 05/09/24 12:24 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 05/09/24 12:24 74-83-9 IH,v1 2-Butanone (MEK) ND ug/L 100 4.0 1 05/09/24 12:24 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 05/09/24 12:24 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/09/24 12:24 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 05/09/24 12:24 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 05/09/24 12:24 75-00-3 v1 Chloroform ND ug/L 5.0 0.43 1 05/09/24 12:24 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/09/24 12:24 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.34 1 05/09/24 12:24 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 49 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-UD1 Lab ID: 92729146019 Collected: 05/05/24 16:17 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2024 04:04 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.36 1 05/09/24 12:24 124-48-1 ND ug/L 2.0 0.27 1 05/09/24 12:24 106-93-4 ND ug/L 10.0 0.39 1 05/09/24 12:24 74-95-3 ND ug/L 5.0 0.34 1 05/09/24 12:24 95-50-1 ND ug/L 1.0 0.33 1 05/09/24 12:24 106-46-7 ND ug/L 100 0.56 1 05/09/24 12:24 110-57-6 ND ug/L 5.0 0.37 1 05/09/24 12:24 75-34-3 ND ug/L 1.0 0.32 1 05/09/24 12:24 107-06-2 ND ug/L 5.0 0.35 1 05/09/24 12:24 75-35-4 ND ug/L 5.0 0.38 1 05/09/24 12:24 156-59-2 ND ug/L 5.0 0.40 1 05/09/24 12:24 156-60-5 ND ug/L 1.0 0.36 1 05/09/24 12:24 78-87-5 ND ug/L 1.0 0.36 1 05/09/24 12:24 10061-01-5 ND ug/L 1.0 0.36 1 05/09/24 12:24 10061-02-6 ND ug/L 1.0 0.30 1 05/09/24 12:24 100-41-4 ND ug/L 50.0 0.48 1 05/09/24 12:24 591-78-6 ND ug/L 20.0 9.7 1 05/09/24 12:24 74-88-4 ND ug/L 5.0 2.0 1 05/09/24 12:24 75-09-2 ND ug/L 100 2.7 1 05/09/24 12:24 108-10-1 ND ug/L 1.0 0.29 1 05/09/24 12:24 100-42-5 ND ug/L 5.0 0.31 1 05/09/24 12:24 630-20-6 ND ug/L 3.0 0.22 1 05/09/24 12:24 79-34-5 ND ug/L 1.0 0.29 1 05/09/24 12:24 127-18-4 ND ug/L 1.0 0.24 1 05/09/24 12:24 108-88-3 ND ug/L 1.0 0.33 1 05/09/24 12:24 71-55-6 ND ug/L 1.0 0.32 1 05/09/24 12:24 79-00-5 ND ug/L 1.0 0.38 1 05/09/24 12:24 79-01-6 ND ug/L 1.0 0.30 1 05/09/24 12:24 75-69-4 ND ug/L 1.0 0.26 1 05/09/24 12:24 96-18-4 ND ug/L 50.0 1.3 1 05/09/24 12:24 108-05-4 ND ug/L 1.0 0.39 1 05/09/24 12:24 75-01-4 ND ug/L 5.0 0.34 1 05/09/24 12:24 1330-20-7 98 % 70-130 1 05/09/24 12:24 460-00-4 103 % 70-130 1 05/09/24 12:24 17060-07-0 103 % 70-130 1 05/09/24 12:24 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 50 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-UD2 Lab ID: 92729146020 Collected: 05/05/24 15:58 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 05/06/24 15:58 pH 5.49 Std. Units 1 05/06/24 15:58 Temperature 17.9 deg C 1 05/06/24 15:58 Specific Conductance 208 umhos/c 1 05/06/24 15:58 m Oxidation Potential 70.9 mV 1 05/06/24 15:58 Oxygen, Dissolved 3.42 mg/L 1 05/06/24 15:58 7782-44-7 Turbidity 7.02 NTU 1 05/06/24 15:58 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.54 1 05/09/2414:06 05/14/2418:17 7440-36-0 Arsenic 1.1J ug/L 10.0 0.84 1 05/09/2414:06 05/14/2418:17 7440-38-2 Barium 58.2J ug/L 100 0.47 1 05/09/2414:06 05/14/2418:17 7440-39-3 Beryllium ND ug/L 1.0 0.094 1 05/09/2414:06 05/14/2418:17 7440-41-7 Cadmium ND ug/L 1.0 0.10 1 05/09/2414:06 05/14/2418:17 7440-43-9 Chromium ND ug/L 10.0 1.9 1 05/09/2414:06 05/14/2418:17 7440-47-3 Cobalt 6.2J ug/L 10.0 0.32 1 05/09/2414:06 05/14/2418:17 7440-48-4 Copper 0.62J ug/L 10.0 0.43 1 05/09/2414:06 05/14/2418:17 7440-50-8 Lead 0.33J ug/L 10.0 0.16 1 05/09/2414:06 05/14/2418:17 7439-92-1 Nickel ND ug/L 50.0 2.1 1 05/09/2414:06 05/14/2418:17 7440-02-0 Selenium ND ug/L 10.0 0.96 1 05/09/2414:06 05/14/2418:17 7782-49-2 Silver ND ug/L 10.0 0.31 1 05/09/2414:06 05/14/2418:17 7440-22-4 Thallium ND ug/L 5.5 0.38 1 05/09/2414:06 05/14/2418:17 7440-28-0 Vanadium 3.5J ug/L 25.0 0.75 1 05/09/2414:06 05/14/2418:17 7440-62-2 Zinc 2.5J ug/L 10.0 2.4 1 05/09/2414:06 05/14/2418:17 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 05/09/24 12:43 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 05/09/24 12:43 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/09/24 12:43 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 05/09/24 12:43 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/09/24 12:43 75-27-4 Bromoform ND ug/L 3.0 0.34 1 05/09/24 12:43 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 05/09/24 12:43 74-83-9 IH,v1 2-Butanone (MEK) ND ug/L 100 4.0 1 05/09/24 12:43 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 05/09/24 12:43 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/09/24 12:43 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 05/09/24 12:43 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 05/09/24 12:43 75-00-3 v1 Chloroform ND ug/L 5.0 0.43 1 05/09/24 12:43 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/09/24 12:43 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.34 1 05/09/24 12:43 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 51 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-UD2 Lab ID: 92729146020 Collected: 05/05/24 15:58 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2024 04:04 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.36 1 05/09/2412:43 124-48-1 ND ug/L 2.0 0.27 1 05/09/2412:43 106-93-4 ND ug/L 10.0 0.39 1 05/09/2412:43 74-95-3 ND ug/L 5.0 0.34 1 05/09/2412:43 95-50-1 ND ug/L 1.0 0.33 1 05/09/2412:43 106-46-7 ND ug/L 100 0.56 1 05/09/2412:43 110-57-6 ND ug/L 5.0 0.37 1 05/09/2412:43 75-34-3 ND ug/L 1.0 0.32 1 05/09/2412:43 107-06-2 ND ug/L 5.0 0.35 1 05/09/2412:43 75-35-4 ND ug/L 5.0 0.38 1 05/09/2412:43 156-59-2 ND ug/L 5.0 0.40 1 05/09/2412:43 156-60-5 ND ug/L 1.0 0.36 1 05/09/2412:43 78-87-5 ND ug/L 1.0 0.36 1 05/09/2412:43 10061-01-5 ND ug/L 1.0 0.36 1 05/09/2412:43 10061-02-6 ND ug/L 1.0 0.30 1 05/09/2412:43 100-41-4 ND ug/L 50.0 0.48 1 05/09/2412:43 591-78-6 ND ug/L 20.0 9.7 1 05/09/2412:43 74-88-4 ND ug/L 5.0 2.0 1 05/09/2412:43 75-09-2 ND ug/L 100 2.7 1 05/09/2412:43 108-10-1 ND ug/L 1.0 0.29 1 05/09/2412:43 100-42-5 ND ug/L 5.0 0.31 1 05/09/2412:43 630-20-6 ND ug/L 3.0 0.22 1 05/09/2412:43 79-34-5 ND ug/L 1.0 0.29 1 05/09/2412:43 127-18-4 ND ug/L 1.0 0.24 1 05/09/2412:43 108-88-3 ND ug/L 1.0 0.33 1 05/09/2412:43 71-55-6 ND ug/L 1.0 0.32 1 05/09/2412:43 79-00-5 ND ug/L 1.0 0.38 1 05/09/2412:43 79-01-6 ND ug/L 1.0 0.30 1 05/09/2412:43 75-69-4 ND ug/L 1.0 0.26 1 05/09/2412:43 96-18-4 ND ug/L 50.0 1.3 1 05/09/2412:43 108-05-4 ND ug/L 1.0 0.39 1 05/09/2412:43 75-01-4 ND ug/L 5.0 0.34 1 05/09/2412:43 1330-20-7 96 % 70-130 1 05/09/2412:43 460-00-4 107 % 70-130 1 05/09/2412:43 17060-07-0 104 % 70-130 1 05/09/2412:43 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 52 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-Trip Blank Lab ID: 92729146021 Collected: 05/05/24 15:34 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrach loroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane Date: 05/21 /2024 04:04 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 100 5.1 1 05/09/24 08:40 67-64-1 ND ug/L 200 1.8 1 05/09/24 08:40 107-13-1 ND ug/L 1.0 0.34 1 05/09/24 08:40 71-43-2 ND ug/L 3.0 0.47 1 05/09/24 08:40 74-97-5 ND ug/L 1.0 0.31 1 05/09/24 08:40 75-27-4 ND ug/L 3.0 0.34 1 05/09/24 08:40 75-25-2 ND ug/L 10.0 1.7 1 05/09/24 08:40 74-83-9 ND ug/L 100 4.0 1 05/09/24 08:40 78-93-3 ND ug/L 100 0.36 1 05/09/24 08:40 75-15-0 ND ug/L 1.0 0.33 1 05/09/24 08:40 56-23-5 ND ug/L 3.0 0.28 1 05/09/24 08:40 108-90-7 ND ug/L 10.0 0.65 1 05/09/24 08:40 75-00-3 ND ug/L 5.0 0.43 1 05/09/24 08:40 67-66-3 ND ug/L 1.0 0.54 1 05/09/24 08:40 74-87-3 ND ug/L 13.0 0.34 1 05/09/24 08:40 96-12-8 ND ug/L 3.0 0.36 1 05/09/24 08:40 124-48-1 ND ug/L 2.0 0.27 1 05/09/24 08:40 106-93-4 ND ug/L 10.0 0.39 1 05/09/24 08:40 74-95-3 ND ug/L 5.0 0.34 1 05/09/24 08:40 95-50-1 ND ug/L 1.0 0.33 1 05/09/24 08:40 106-46-7 ND ug/L 100 0.56 1 05/09/24 08:40 110-57-6 ND ug/L 5.0 0.37 1 05/09/24 08:40 75-34-3 ND ug/L 1.0 0.32 1 05/09/24 08:40 107-06-2 ND ug/L 5.0 0.35 1 05/09/24 08:40 75-35-4 ND ug/L 5.0 0.38 1 05/09/24 08:40 156-59-2 ND ug/L 5.0 0.40 1 05/09/24 08:40 156-60-5 ND ug/L 1.0 0.36 1 05/09/24 08:40 78-87-5 ND ug/L 1.0 0.36 1 05/09/24 08:40 10061-01-5 ND ug/L 1.0 0.36 1 05/09/24 08:40 10061-02-6 ND ug/L 1.0 0.30 1 05/09/24 08:40 100-41-4 ND ug/L 50.0 0.48 1 05/09/24 08:40 591-78-6 ND ug/L 20.0 9.7 1 05/09/24 08:40 74-88-4 ND ug/L 5.0 2.0 1 05/09/24 08:40 75-09-2 ND ug/L 100 2.7 1 05/09/24 08:40 108-10-1 ND ug/L 1.0 0.29 1 05/09/24 08:40 100-42-5 ND ug/L 5.0 0.31 1 05/09/24 08:40 630-20-6 ND ug/L 3.0 0.22 1 05/09/24 08:40 79-34-5 ND ug/L 1.0 0.29 1 05/09/24 08:40 127-18-4 ND ug/L 1.0 0.24 1 05/09/24 08:40 108-88-3 ND ug/L 1.0 0.33 1 05/09/24 08:40 71-55-6 ND ug/L 1.0 0.32 1 05/09/24 08:40 79-00-5 ND ug/L 1.0 0.38 1 05/09/24 08:40 79-01-6 ND ug/L 1.0 0.30 1 05/09/24 08:40 75-69-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IH.v1 v1 Page 53 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Sample: 1403-Trip Blank Lab ID: 92729146021 Collected: 05/05/24 15:34 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2024 04:04 PM ND ug/L 1.0 0.26 1 05/09/24 08:40 96-18-4 ND ug/L 50.0 1.3 1 05/09/24 08:40 108-05-4 ND ug/L 1.0 0.39 1 05/09/24 08:40 75-01-4 ND ug/L 5.0 0.34 1 05/09/24 08:40 1330-20-7 98 % 70-130 1 05/09/24 08:40 460-00-4 105 % 70-130 1 05/09/24 08:40 17060-07-0 106 % 70-130 1 05/09/24 08:40 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 54 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 QC Batch: 853390 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020 MET Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92729146001, 92729146002, 92729146003, 92729146004, 92729146005, 92729146006, 92729146007, 92729146008,92729146009,92729146010,92729146011,92729146012,92729146013,92729146014, 92729146015,92729146016,92729146017,92729146018,92729146019,92729146020 METHOD BLANK: 4403761 Matrix: Water Associated Lab Samples: 92729146001, 92729146002, 92729146003, 92729146004, 92729146005, 92729146006, 92729146007, 92729146008,92729146009,92729146010,92729146011,92729146012,92729146013,92729146014, 92729146015,92729146016,92729146017,92729146018,92729146019,92729146020 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 6.0 0.54 05/14/2416:23 Arsenic ug/L ND 10.0 0.84 05/14/2416:23 Barium ug/L ND 100 0.47 05/14/2416:23 Beryllium ug/L ND 1.0 0.094 05/14/2416:23 Cadmium ug/L ND 1.0 0.10 05/14/2416:23 Chromium ug/L ND 10.0 1.9 05/14/2416:23 Cobalt ug/L ND 10.0 0.32 05/14/2416:23 Copper ug/L ND 10.0 0.43 05/14/2416:23 Lead ug/L ND 10.0 0.16 05/14/2416:23 Nickel ug/L ND 50.0 2.1 05/14/2416:23 Selenium ug/L ND 10.0 0.96 05/14/2416:23 Silver ug/L ND 10.0 0.31 05/14/2416:23 Thallium ug/L ND 5.5 0.38 05/14/2416:23 Vanadium ug/L ND 25.0 0.75 05/14/2416:23 Zinc ug/L ND 10.0 2.4 05/14/2416:23 LABORATORY CONTROL SAMPLE: Parameter 4403762 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 100 107 107 80-120 Arsenic ug/L 100 101 101 80-120 Barium ug/L 100 101 101 80-120 Beryllium ug/L 100 104 104 80-120 Cadmium ug/L 100 102 102 80-120 Chromium ug/L 100 103 103 80-120 Cobalt ug/L 100 102 102 80-120 Copper ug/L 100 102 102 80-120 Lead ug/L 100 102 102 80-120 Nickel ug/L 100 101 101 80-120 Selenium ug/L 100 101 101 80-120 Silver ug/L 100 104 104 80-120 Thallium ug/L 100 98.9 99 80-120 Vanadium ug/L 100 103 103 80-120 Zinc ug/L 100 102 102 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 55 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Foothills LF/Semi-Annual 92729146 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4403763 4403764 MS MSD 92729146016 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 97.9 99.5 98 99 75-125 2 20 Arsenic ug/L ND 100 100 96.1 97.7 96 97 75-125 2 20 Barium ug/L 30AJ 100 100 127 129 96 99 75-125 2 20 Beryllium ug/L 0.13J 100 100 98.3 99.1 98 99 75-125 1 20 Cadmium ug/L ND 100 100 98.8 98.4 99 98 75-125 0 20 Chromium ug/L 3.5J 100 100 103 103 99 99 75-125 0 20 Cobalt ug/L 1.2J 100 100 98.3 99.1 97 98 75-125 1 20 Copper ug/L 2.7J 100 100 101 103 98 100 75-125 3 20 Lead ug/L 1.5J 100 100 96.4 95.7 95 94 75-125 1 20 Nickel ug/L ND 100 100 100 104 99 102 75-125 3 20 Selenium ug/L ND 100 100 94.3 97.7 94 98 75-125 4 20 Silver ug/L ND 100 100 97.7 98.4 98 98 75-125 1 20 Thallium ug/L ND 100 100 93.3 94.1 93 94 75-125 1 20 Vanadium ug/L 8.3J 100 100 108 108 100 100 75-125 0 20 Zinc ug/L 5.1J 100 100 104 106 98 101 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 56 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 QC Batch: 853049 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92729146001, 92729146002, 92729146003, 92729146004, 92729146005, 92729146006, 92729146007, 92729146008,92729146009,92729146010,92729146011,92729146012,92729146013,92729146014, 92729146015 METHOD BLANK: 4402148 Matrix: Water Associated Lab Samples: 92729146001, 92729146002, 92729146003, 92729146004, 92729146005, 92729146006, 92729146007, 92729146008,92729146009,92729146010,92729146011,92729146012,92729146013,92729146014, 92729146015 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.31 05/09/24 01:55 1,1,1-Trichloroethane ug/L ND 1.0 0.33 05/09/24 01:55 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.22 05/09/24 01:55 1,1,2-Trichloroethane ug/L ND 1.0 0.32 05/09/24 01:55 1,1-Dichloroethane ug/L ND 5.0 0.37 05/09/24 01:55 1,1-Dichloroethene ug/L ND 5.0 0.35 05/09/24 01:55 1,2,3-Trichloropropane ug/L ND 1.0 0.26 05/09/24 01:55 1,2-Dibromo-3-chloropropane ug/L ND 13.0 0.34 05/09/24 01:55 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.27 05/09/24 01:55 1,2-Dichlorobenzene ug/L ND 5.0 0.34 05/09/24 01:55 1,2-Dichloroethane ug/L ND 1.0 0.32 05/09/24 01:55 1,2-Dichloropropane ug/L ND 1.0 0.36 05/09/24 01:55 1,4-Dichlorobenzene ug/L ND 1.0 0.33 05/09/24 01:55 2-Butanone (MEK) ug/L ND 100 4.0 05/09/24 01:55 2-Hexanone ug/L ND 50.0 0.48 05/09/24 01:55 4-Methyl-2-pentanone (MIBK) ug/L ND 100 2.7 05/09/24 01:55 Acetone ug/L ND 100 5.1 05/09/24 01:55 Acrylonitrile ug/L ND 200 1.8 05/09/24 01:55 Benzene ug/L ND 1.0 0.34 05/09/24 01:55 Bromochloromethane ug/L ND 3.0 0.47 05/09/24 01:55 Bromodichloromethane ug/L ND 1.0 0.31 05/09/24 01:55 Bromoform ug/L ND 3.0 0.34 05/09/24 01:55 Bromomethane ug/L ND 10.0 1.7 05/09/24 01:55 Carbon disulfide ug/L ND 100 0.36 05/09/24 01:55 Carbon tetrachloride ug/L ND 1.0 0.33 05/09/24 01:55 Chlorobenzene ug/L ND 3.0 0.28 05/09/24 01:55 Chloroethane ug/L ND 10.0 0.65 05/09/24 01:55 Chloroform ug/L ND 5.0 0.43 05/09/24 01:55 Chloromethane ug/L ND 1.0 0.54 05/09/24 01:55 cis-1,2-Dichloroethene ug/L ND 5.0 0.38 05/09/24 01:55 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 05/09/24 01:55 Dibromochloromethane ug/L ND 3.0 0.36 05/09/24 01:55 Dibromomethane ug/L ND 10.0 0.39 05/09/24 01:55 Ethylbenzene ug/L ND 1.0 0.30 05/09/24 01:55 lodomethane ug/L ND 20.0 9.7 05/09/24 01:55 Methylene Chloride ug/L ND 5.0 2.0 05/09/24 01:55 Styrene ug/L ND 1.0 0.29 05/09/24 01:55 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 57 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 METHOD BLANK: 4402148 Matrix: Water Associated Lab Samples: 92729146001, 92729146002, 92729146003, 92729146004, 92729146005, 92729146006, 92729146007, 92729146008,92729146009,92729146010,92729146011,92729146012,92729146013,92729146014, 92729146015 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Tetrachloroethene ug/L ND 1.0 0.29 05/09/24 01:55 Toluene ug/L ND 1.0 0.24 05/09/24 01:55 trans-1,2-Dichloroethene ug/L ND 5.0 0.40 05/09/24 01:55 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 05/09/24 01:55 trans-1,4-Dichloro-2-butene ug/L ND 100 0.56 05/09/24 01:55 v2 Trichloroethene ug/L ND 1.0 0.38 05/09/24 01:55 Trichlorofluoromethane ug/L ND 1.0 0.30 05/09/24 01:55 Vinyl acetate ug/L ND 50.0 1.3 05/09/24 01:55 Vinyl chloride ug/L ND 1.0 0.39 05/09/24 01:55 Xylene (Total) ug/L ND 5.0 0.34 05/09/24 01:55 1,2-Dichloroethane-d4 (S) % 98 70-130 05/09/24 01:55 4-Bromofluorobenzene (S) % 96 70-130 05/09/24 01:55 Toluene-d8 (S) % 102 70-130 05/09/24 01:55 LABORATORY CONTROL SAMPLE: 4402149 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 20 20.5 102 70-130 1,1,1-Trichloroethane ug/L 20 19.9 100 70-130 1,1,2,2-Tetrachloroethane ug/L 20 19.7 99 70-130 1,1,2-Trichloroethane ug/L 20 20.5 103 70-130 1,1-Dichloroethane ug/L 20 19.6 98 70-130 1,1-Dichloroethene ug/L 20 19.4 97 69-131 1,2,3-Trichloropropane ug/L 20 20.5 102 70-130 1,2-Dibromo-3-chloropropane ug/L 20 18.8 94 70-130 1,2-Dibromoethane (EDB) ug/L 20 21.4 107 70-130 1,2-Dichlorobenzene ug/L 20 20.5 102 70-130 1,2-Dichloroethane ug/L 20 19.8 99 70-130 1,2-Dichloropropane ug/L 20 20.3 101 70-130 1,4-Dichlorobenzene ug/L 20 20.4 102 70-130 2-Butanone (MEK) ug/L 40 34.7J 87 67-133 2-Hexanone ug/L 40 40.6J 102 70-133 4-Methyl-2-pentanone (MIBK) ug/L 40 40.6J 102 70-130 Acetone ug/L 40 37AJ 93 67-130 Acrylonitrile ug/L 100 91.6J 92 70-130 Benzene ug/L 20 20.4 102 70-130 Bromochloromethane ug/L 20 20.6 103 70-130 Bromodichloromethane ug/L 20 20.3 102 70-130 Bromoform ug/L 20 19.9 100 70-133 Bromomethane ug/L 20 19.4 97 41-148 Carbon disulfide ug/L 20 18.7J 94 70-131 Carbon tetrachloride ug/L 20 20.4 102 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 58 of 99 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 aceo Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 LABORATORY CONTROL SAMPLE: Parameter 4402149 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Chlorobenzene ug/L 20 20.4 102 70-130 Chloroethane ug/L 20 20.3 101 41-157 Chloroform ug/L 20 19.6 98 70-130 Chloromethane ug/L 20 19.3 97 59-141 cis-1,2-Dichloroethene ug/L 20 19.1 96 70-130 cis-1,3-Dichloropropene ug/L 20 20.5 103 70-130 Dibromochloromethane ug/L 20 20.9 104 70-130 Dibromomethane ug/L 20 21.3 106 70-130 Ethylbenzene ug/L 20 20.6 103 70-130 lodomethane ug/L 40 32.8 82 57-140 Methylene Chloride ug/L 20 18.9 94 62-130 Styrene ug/L 20 21.4 107 70-130 Tetrachloroethene ug/L 20 21.4 107 70-130 Toluene ug/L 20 20.3 102 70-130 trans-1,2-Dichloroethene ug/L 20 19.1 96 70-130 trans- 1,3-Dichloropropene ug/L 20 20.7 103 70-130 trans-1,4-Dichloro-2-butene ug/L 20 11.7J 59 57-149 v3 Trichloroethene ug/L 20 20.9 104 70-130 Trichlorofluoromethane ug/L 20 20.0 100 57-130 Vinyl acetate ug/L 40 41.1J 103 70-141 Vinyl chloride ug/L 20 20.4 102 66-140 Xylene (Total) ug/L 60 63.0 105 70-130 1,2-Dichloroethane-d4 (S) % 100 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 100 70-130 MATRIX SPIKE SAMPLE: Parameter 4402150 Units 92729087017 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 23.0 115 70-146 1,1,1-Trichloroethane ug/L ND 20 23.4 117 70-150 1,1,2,2-Tetrachloroethane ug/L ND 20 22.0 110 66-144 1,1,2-Trichloroethane ug/L ND 20 22.5 112 70-142 1,1-Dichloroethane ug/L ND 20 22.8 114 68-150 1,1-Dichloroethene ug/L ND 20 23.0 115 64-162 1,2,3-Trichloropropane ug/L ND 20 22.4 112 66-144 1,2-Dibromo-3-chloropropane ug/L ND 20 20.0 100 62-146 1,2-Dibromoethane (EDB) ug/L ND 20 23.3 116 70-143 1,2-Dichlorobenzene ug/L ND 20 21.8 109 70-142 1,2-Dichloroethane ug/L ND 20 23.2 116 68-145 1,2-Dichloropropane ug/L ND 20 23.2 116 70-144 1,4-Dichlorobenzene ug/L ND 20 22.2 111 70-140 2-Butanone (MEK) ug/L ND 40 41.3J 103 57-156 2-Hexanone ug/L ND 40 44.1J 110 62-153 4-Methyl-2-pentanone (MIBK) ug/L ND 40 44.9J 112 65-144 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 59 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 MATRIX SPIKE SAMPLE: 4402150 92729087017 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Acetone ug/L ND 40 43.1J 108 49-162 Acrylonitrile ug/L ND 100 102J 102 59-155 Benzene ug/L ND 20 23.2 116 68-144 Bromochloromethane ug/L ND 20 22.7 114 70-148 Bromodichloromethane ug/L ND 20 22.9 115 70-141 Bromoform ug/L ND 20 21.7 108 59-144 Bromomethane ug/L ND 20 24.0 120 23-190 Carbon disulfide ug/L ND 20 21.9J 110 64-160 Carbon tetrachloride ug/L ND 20 23.9 119 70-147 Chlorobenzene ug/L ND 20 22.4 112 70-143 Chloroethane ug/L ND 20 24.4 122 55-190 Chloroform ug/L ND 20 22.2 111 67-148 Chloromethane ug/L ND 20 22.4 112 38-180 cis-1,2-Dichloroethene ug/L ND 20 22.0 110 67-151 cis-1,3-Dichloropropene ug/L ND 20 21.7 108 70-142 Dibromochloromethane ug/L ND 20 23.0 115 68-140 Dibromomethane ug/L ND 20 23.0 115 70-142 Ethylbenzene ug/L ND 20 22.8 114 70-145 lodomethane ug/L ND 40 34.8 87 37-160 v3 Methylene Chloride ug/L ND 20 21.6 108 54-149 Styrene ug/L ND 20 22.9 115 70-147 Tetrachloroethene ug/L ND 20 22.3 111 70-145 Toluene ug/L ND 20 22.7 113 65-146 trans-1,2-Dichloroethene ug/L ND 20 23.3 116 69-155 trans- 1,3-Dichloropropene ug/L ND 20 22.9 115 70-142 trans-1,4-Dichloro-2-butene ug/L ND 20 13.3J 66 39-149 v3 Trichloroethene ug/L ND 20 23.2 116 70-152 Trichlorofluoromethane ug/L ND 20 24.7 124 60-158 Vinyl acetate ug/L ND 40 45.3J 113 56-157 Vinyl chloride ug/L ND 20 24.1 120 51-178 Xylene (Total) ug/L ND 60 68.3 114 70-146 1,2-Dichloroethane-d4 (S) % 106 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 98 70-130 SAMPLE DUPLICATE: 4402151 92729087018 Dup Max Parameter Units Result Result RPD RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 60 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 SAMPLE DUPLICATE: 4402151 Parameter Units 92729087018 Result Dup Result RPD Max RPD 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Acrylonitrile ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 30 Carbon disulfide ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 30 Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 cis-1,2-Dichloroethene ug/L ND ND 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 lodomethane ug/L ND ND 30 v2 Methylene Chloride ug/L ND ND 30 Styrene ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans- 1,3-Dichloropropene ug/L ND ND 30 trans-1,4-Dichloro-2-butene ug/L ND ND 30 v2 Trichloroethene ug/L ND ND 30 Trichlorofluoromethane ug/L ND ND 30 Vinyl acetate ug/L ND ND 30 Vinyl chloride ug/L ND ND 30 Xylene (Total) ug/L ND ND 30 1,2-Dichloroethane-d4 (S) % 97 104 4-Bromofluorobenzene (S) % 95 95 Toluene-d8 (S) % 102 102 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 61 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 QC Batch: 853210 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92729146017, 92729146018, 92729146019, 92729146020, 92729146021 METHOD BLANK: 4403001 Matrix: Water Associated Lab Samples: 92729146017, 92729146018, 92729146019, 92729146020, 92729146021 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.31 05/09/24 07:44 1,1,1-Trichloroethane ug/L ND 1.0 0.33 05/09/24 07:44 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.22 05/09/24 07:44 1,1,2-Trichloroethane ug/L ND 1.0 0.32 05/09/24 07:44 1,1-Dichloroethane ug/L ND 5.0 0.37 05/09/24 07:44 1,1-Dichloroethene ug/L ND 5.0 0.35 05/09/24 07:44 1,2,3-Trichloropropane ug/L ND 1.0 0.26 05/09/24 07:44 1,2-Dibromo-3-chloropropane ug/L ND 13.0 0.34 05/09/24 07:44 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.27 05/09/24 07:44 1,2-Dichlorobenzene ug/L ND 5.0 0.34 05/09/24 07:44 1,2-Dichloroethane ug/L ND 1.0 0.32 05/09/24 07:44 1,2-Dichloropropane ug/L ND 1.0 0.36 05/09/24 07:44 1,4-Dichlorobenzene ug/L ND 1.0 0.33 05/09/24 07:44 2-Butanone (MEK) ug/L ND 100 4.0 05/09/24 07:44 2-Hexanone ug/L ND 50.0 0.48 05/09/24 07:44 4-Methyl-2-pentanone (MIBK) ug/L ND 100 2.7 05/09/24 07:44 Acetone ug/L ND 100 5.1 05/09/24 07:44 Acrylonitrile ug/L ND 200 1.8 05/09/24 07:44 Benzene ug/L ND 1.0 0.34 05/09/24 07:44 Bromochloromethane ug/L ND 3.0 0.47 05/09/24 07:44 Bromodichloromethane ug/L ND 1.0 0.31 05/09/24 07:44 Bromoform ug/L ND 3.0 0.34 05/09/24 07:44 Bromomethane ug/L ND 10.0 1.7 05/09/24 07:44 Carbon disulfide ug/L ND 100 0.36 05/09/24 07:44 Carbon tetrachloride ug/L ND 1.0 0.33 05/09/24 07:44 Chlorobenzene ug/L ND 3.0 0.28 05/09/24 07:44 Chloroethane ug/L ND 10.0 0.65 05/09/24 07:44 Chloroform ug/L ND 5.0 0.43 05/09/24 07:44 Chloromethane ug/L ND 1.0 0.54 05/09/24 07:44 cis-1,2-Dichloroethene ug/L ND 5.0 0.38 05/09/24 07:44 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 05/09/24 07:44 Dibromochloromethane ug/L ND 3.0 0.36 05/09/24 07:44 Dibromomethane ug/L ND 10.0 0.39 05/09/24 07:44 Ethylbenzene ug/L ND 1.0 0.30 05/09/24 07:44 lodomethane ug/L ND 20.0 9.7 05/09/24 07:44 Methylene Chloride ug/L ND 5.0 2.0 05/09/24 07:44 Styrene ug/L ND 1.0 0.29 05/09/24 07:44 Tetrachloroethene ug/L ND 1.0 0.29 05/09/24 07:44 Toluene ug/L ND 1.0 0.24 05/09/24 07:44 trans-1,2-Dichloroethene ug/L ND 5.0 0.40 05/09/24 07:44 Qualifiers IH.v1 v1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 62 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 METHOD BLANK: 4403001 Matrix: Water Associated Lab Samples: 92729146017, 92729146018, 92729146019, 92729146020, 92729146021 Blank Reporting Parameter Units Result Limit MDL Analyzed trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 05/09/24 07:44 trans-1,4-Dichloro-2-butene ug/L ND 100 0.56 05/09/24 07:44 Trichloroethene ug/L ND 1.0 0.38 05/09/24 07:44 Trichlorofluoromethane ug/L ND 1.0 0.30 05/09/24 07:44 Vinyl acetate ug/L ND 50.0 1.3 05/09/24 07:44 Vinyl chloride ug/L ND 1.0 0.39 05/09/24 07:44 Xylene (Total) ug/L ND 5.0 0.34 05/09/24 07:44 1,2-Dichloroethane-d4 (S) % 106 70-130 05/09/24 07:44 4-Bromofluorobenzene (S) % 96 70-130 05/09/24 07:44 Toluene-d8 (S) % 105 70-130 05/09/24 07:44 LABORATORY CONTROL SAMPLE: 4403002 Parameter Qualifiers Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 20 21.0 105 70-130 1,1,1-Trichloroethane ug/L 20 20.2 101 70-130 1,1,2,2-Tetrachloroethane ug/L 20 19.7 99 70-130 1,1,2-Trichloroethane ug/L 20 21.0 105 70-130 1,1-Dichloroethane ug/L 20 21.3 107 70-130 1,1-Dichloroethene ug/L 20 22.0 110 69-131 1,2,3-Trichloropropane ug/L 20 19.5 97 70-130 1,2-Dibromo-3-chloropropane ug/L 20 19.1 95 70-130 1,2-Dibromoethane (EDB) ug/L 20 20.7 103 70-130 1,2-Dichlorobenzene ug/L 20 21.3 106 70-130 1,2-Dichloroethane ug/L 20 21.7 108 70-130 1,2-Dichloropropane ug/L 20 20.9 105 70-130 1,4-Dichlorobenzene ug/L 20 20.4 102 70-130 2-Butanone (MEK) ug/L 40 41.7J 104 67-133 2-Hexanone ug/L 40 41AJ 104 70-133 4-Methyl-2-pentanone (MIBK) ug/L 40 38.8J 97 70-130 Acetone ug/L 40 39.9J 100 67-130 Acrylonitrile ug/L 100 102J 102 70-130 Benzene ug/L 20 21.1 106 70-130 Bromochloromethane ug/L 20 22.6 113 70-130 Bromodichloromethane ug/L 20 21.1 106 70-130 Bromoform ug/L 20 21.1 106 70-133 Bromomethane ug/L 20 28.4 142 41-148lH,v1 Carbon disulfide ug/L 20 21 AJ 107 70-131 Carbon tetrachloride ug/L 20 19.7 99 70-130 Chlorobenzene ug/L 20 20.6 103 70-130 Chloroethane ug/L 20 22.8 114 41-157 v1 Chloroform ug/L 20 22.7 113 70-130 Chloromethane ug/L 20 23.7 119 59-141 cis-1,2-Dichloroethene ug/L 20 21.0 105 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 63 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 LABORATORY CONTROL SAMPLE: Parameter 4403002 Units Spike Conc. LCS Result LCS % Rec % Rec Limits cis-1,3-Dichloropropene ug/L 20 21.8 109 70-130 Dibromochloromethane ug/L 20 20.8 104 70-130 Dibromomethane ug/L 20 19.7 99 70-130 Ethylbenzene ug/L 20 20.7 103 70-130 lodomethane ug/L 40 41.1 103 57-140 Methylene Chloride ug/L 20 20.4 102 62-130 Styrene ug/L 20 21.0 105 70-130 Tetrachloroethene ug/L 20 19.0 95 70-130 Toluene ug/L 20 20.4 102 70-130 trans-1,2-Dichloroethene ug/L 20 21.4 107 70-130 trans- 1,3-Dichloropropene ug/L 20 21.4 107 70-130 trans-1,4-Dichloro-2-butene ug/L 20 21.6J 108 57-149 Trichloroethene ug/L 20 21.5 108 70-130 Trichlorofluoromethane ug/L 20 20.1 100 57-130 Vinyl acetate ug/L 40 45.8J 114 70-141 Vinyl chloride ug/L 20 23.2 116 66-140 Xylene (Total) ug/L 60 64.0 107 70-130 1,2-Dichloroethane-d4 (S) % 100 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 100 70-130 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4403003 MS 92729715001 Spike Parameter Units Result Conc. MSD Spike Conc. 4403004 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 22.1 20.9 111 104 70-146 6 30 1,1,1-Trichloroethane ug/L ND 20 20 25.0 21.7 125 109 70-150 14 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 22.2 20.4 111 102 66-144 8 30 1,1,2-Trichloroethane ug/L ND 20 20 22.5 20.1 112 101 70-142 11 30 1,1-Dichloroethane ug/L ND 20 20 25.4 22.1 127 111 68-150 14 30 1,1-Dichloroethene ug/L ND 20 20 26.2 23.3 131 117 64-162 11 30 1,2,3-Trichloropropane ug/L ND 20 20 22.0 20.7 110 103 66-144 6 30 1,2-Dibromo-3- ug/L ND 20 20 20.5 18.1 103 90 62-146 13 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 21.7 21.0 108 105 70-143 3 30 1,2-Dichlorobenzene ug/L ND 20 20 22.7 20.6 114 103 70-142 10 30 1,2-Dichloroethane ug/L ND 20 20 25.4 22.4 127 112 68-145 13 30 1,2-Dichloropropane ug/L ND 20 20 23.6 21.3 118 107 70-144 10 30 1,4-Dichlorobenzene ug/L ND 20 20 22.1 21.2 110 106 70-140 4 30 2-Butanone (MEK) ug/L ND 40 40 47.8J 39.8J 120 99 57-156 18 30 2-Hexanone ug/L ND 40 40 45.3J 41.9J 113 105 62-153 8 30 4-Methyl-2-pentanone ug/L ND 40 40 42.8J 39.3J 107 98 65-144 9 30 (MIBK) Acetone ug/L ND 40 40 45AJ 40.5J 114 101 49-162 12 30 Acrylonitrile ug/L ND 100 100 1111 98.8J 111 99 59-155 12 30 Benzene ug/L ND 20 20 23.8 21.7 119 109 68-144 9 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 64 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4403003 MS 92729715001 Spike Parameter Units Result Conc. MSD Spike Conc. 4403004 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Bromochloromethane ug/L ND 20 20 23.0 21.1 115 105 70-148 9 30 Bromodichloromethane ug/L ND 20 20 22.5 21.0 113 105 70-141 7 30 Bromoform ug/L ND 20 20 20.4 18.9 102 94 59-144 7 30 Bromomethane ug/L ND 20 20 36.1 34.0 181 170 23-190 6 30 IH Carbon disulfide ug/L ND 20 20 24.8J 23.1J 124 116 64-160 7 30 Carbon tetrachloride ug/L ND 20 20 23.3 21.3 117 107 70-147 9 30 Chlorobenzene ug/L ND 20 20 21.7 20.9 108 105 70-143 4 30 Chloroethane ug/L ND 20 20 31.3 28.2 157 141 55-190 10 30 v1 Chloroform ug/L ND 20 20 25.9 21.5 130 107 67-148 19 30 Chloromethane ug/L ND 20 20 26.2 23.7 131 118 38-180 10 30 cis-1,2-Dichloroethene ug/L ND 20 20 25.3 22.1 126 111 67-151 13 30 cis-1,3-Dichloropropene ug/L ND 20 20 24.8 22.1 124 111 70-142 11 30 Dibromochloromethane ug/L ND 20 20 21.3 20.0 106 100 68-140 6 30 Dibromomethane ug/L ND 20 20 20.4 20.6 102 103 70-142 1 30 Ethylbenzene ug/L ND 20 20 23.4 21.8 117 109 70-145 7 30 lodomethane ug/L ND 40 40 43.5 41.7 109 104 37-160 4 30 Methylene Chloride ug/L ND 20 20 21.8 19.5 109 98 54-149 11 30 Styrene ug/L ND 20 20 22.6 21.2 113 106 70-147 6 30 Tetrachloroethene ug/L ND 20 20 22.2 20.1 111 101 70-145 10 30 Toluene ug/L ND 20 20 23.0 21.2 115 106 65-146 8 30 trans-1,2-Dichloroethene ug/L ND 20 20 25.8 22.7 129 114 69-155 13 30 trans-1,3-Dichloropropene ug/L ND 20 20 25.2 22.8 126 114 70-142 10 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 24.OJ 23.5J 120 118 39-149 2 30 Trichloroethene ug/L ND 20 20 23.0 20.2 115 101 70-152 13 30 Trichlorofluoromethane ug/L ND 20 20 26.2 24.2 131 121 60-158 8 30 Vinyl acetate ug/L ND 40 40 52.2 46.2J 131 116 56-157 12 30 Vinyl chloride ug/L ND 20 20 27.5 24.6 138 123 51-178 11 30 Xylene (Total) ug/L ND 60 60 70.4 66.3 117 110 70-146 6 30 1,2-Dichloroethane-d4 (S) % 115 113 70-130 4-Bromofluorobenzene (S) % 101 105 70-130 Toluene-d8 (S) % 100 101 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 65 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 QC Batch: 853211 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92729146016 METHOD BLANK: 4403007 Associated Lab Samples: 92729146016 Parameter Units 1,1,1,2-Tetrachloroethane ug/L 1,1,1-Trichloroethane ug/L 1,1,2,2-Tetrachloroethane ug/L 1,1,2-Trichloroethane ug/L 1,1-Dichloroethane ug/L 1,1-Dichloroethene ug/L 1,2,3-Trichloropropane ug/L 1,2-Dibromo-3-chloropropane ug/L 1,2-Dibromoethane (EDB) ug/L 1,2-Dichlorobenzene ug/L 1,2-Dichloroethane ug/L 1,2-Dichloropropane ug/L 1,4-Dichlorobenzene ug/L 2-Butanone (MEK) ug/L 2-Hexanone ug/L 4-Methyl-2-pentanone (MIBK) ug/L Acetone ug/L Acrylonitrile ug/L Benzene ug/L Bromochloromethane ug/L Bromodichloromethane ug/L Bromoform ug/L Bromomethane ug/L Carbon disulfide ug/L Carbon tetrachloride ug/L Chlorobenzene ug/L Chloroethane ug/L Chloroform ug/L Chloromethane ug/L cis-1,2-Dichloroethene ug/L cis-1,3-Dichloropropene ug/L Dibromochloromethane ug/L Dibromomethane ug/L Ethylbenzene ug/L lodomethane ug/L Methylene Chloride ug/L Styrene ug/L Tetrachloroethene ug/L Toluene ug/L trans-1,2-Dichloroethene ug/L Matrix: Water Blank Result Reporting Limit MDL Analyzed Qualifiers ND 5.0 0.31 05/09/24 08:03 ND 1.0 0.33 05/09/24 08:03 ND 3.0 0.22 05/09/24 08:03 ND 1.0 0.32 05/09/24 08:03 ND 5.0 0.37 05/09/24 08:03 ND 5.0 0.35 05/09/24 08:03 ND 1.0 0.26 05/09/24 08:03 ND 13.0 0.34 05/09/24 08:03 ND 2.0 0.27 05/09/24 08:03 ND 5.0 0.34 05/09/24 08:03 ND 1.0 0.32 05/09/24 08:03 ND 1.0 0.36 05/09/24 08:03 ND 1.0 0.33 05/09/24 08:03 ND 100 4.0 05/09/24 08:03 ND 50.0 0.48 05/09/24 08:03 ND 100 2.7 05/09/24 08:03 ND 100 5.1 05/09/24 08:03 ND 200 1.8 05/09/24 08:03 ND 1.0 0.34 05/09/24 08:03 ND 3.0 0.47 05/09/24 08:03 ND 1.0 0.31 05/09/24 08:03 ND 3.0 0.34 05/09/24 08:03 ND 10.0 1.7 05/09/24 08:03 IH,v1 ND 100 0.36 05/09/24 08:03 ND 1.0 0.33 05/09/24 08:03 ND 3.0 0.28 05/09/24 08:03 ND 10.0 0.65 05/09/24 08:03 v1 ND 5.0 0.43 05/09/24 08:03 ND 1.0 0.54 05/09/24 08:03 ND 5.0 0.38 05/09/24 08:03 ND 1.0 0.36 05/09/24 08:03 ND 3.0 0.36 05/09/24 08:03 ND 10.0 0.39 05/09/24 08:03 ND 1.0 0.30 05/09/24 08:03 ND 20.0 9.7 05/09/24 08:03 ND 5.0 2.0 05/09/24 08:03 ND 1.0 0.29 05/09/24 08:03 ND 1.0 0.29 05/09/24 08:03 ND 1.0 0.24 05/09/24 08:03 ND 5.0 0.40 05/09/24 08:03 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 66 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 METHOD BLANK: 4403007 Associated Lab Samples: 92729146016 Parameter Units trans- 1,3-Dichloropropene ug/L trans-1,4-Dichloro-2-butene ug/L Trichloroethene ug/L Trichlorofluoromethane ug/L Vinyl acetate ug/L Vinyl chloride ug/L Xylene (Total) ug/L 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % LABORATORY CONTROL SAMPLE: 4403008 Parameter QUALITY CONTROL DATA Matrix: Water Blank Result Reporting Limit ND 1.0 ND 100 ND 1.0 ND 1.0 ND 50.0 ND 1.0 ND 5.0 104 70-130 100 70-130 102 70-130 MDL Analyzed 0.36 05/09/24 08:03 0.56 05/09/24 08:03 0.38 05/09/24 08:03 0.30 05/09/24 08:03 1.3 05/09/24 08:03 0.39 05/09/24 08:03 0.34 05/09/24 08:03 05/09/24 08:03 05/09/24 08:03 05/09/24 08:03 Qualifiers Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 20 19.5 98 70-130 1,1,1-Trichloroethane ug/L 20 19.4 97 70-130 1,1,2,2-Tetrachloroethane ug/L 20 19.1 96 70-130 1,1,2-Trichloroethane ug/L 20 21.4 107 70-130 1,1-Dichloroethane ug/L 20 20.2 101 70-130 1,1-Dichloroethene ug/L 20 19.9 100 69-131 1,2,3-Trichloropropane ug/L 20 18.8 94 70-130 1,2-Dibromo-3-chloropropane ug/L 20 19.0 95 70-130 1,2-Dibromoethane (EDB) ug/L 20 20.3 102 70-130 1,2-Dichlorobenzene ug/L 20 20.2 101 70-130 1,2-Dichloroethane ug/L 20 21.1 106 70-130 1,2-Dichloropropane ug/L 20 20.7 103 70-130 1,4-Dichlorobenzene ug/L 20 20.8 104 70-130 2-Butanone (MEK) ug/L 40 38.5J 96 67-133 2-Hexanone ug/L 40 39.9J 100 70-133 4-Methyl-2-pentanone (MIBK) ug/L 40 40.8J 102 70-130 Acetone ug/L 40 38.1 J 95 67-130 Acrylonitrile ug/L 100 94.5J 94 70-130 Benzene ug/L 20 21.1 106 70-130 Bromochloromethane ug/L 20 21.0 105 70-130 Bromodichloromethane ug/L 20 20.5 103 70-130 Bromoform ug/L 20 20.0 100 70-133 Bromomethane ug/L 20 25.6 128 41-148lH,v1 Carbon disulfide ug/L 20 19.8J 99 70-131 Carbon tetrachloride ug/L 20 20.4 102 70-130 Chlorobenzene ug/L 20 19.9 100 70-130 Chloroethane ug/L 20 21.2 106 41-157 v1 Chloroform ug/L 20 20.8 104 70-130 Chloromethane ug/L 20 22.1 110 59-141 cis-1,2-Dichloroethene ug/L 20 19.8 99 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 67 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 LABORATORY CONTROL SAMPLE: Parameter 4403008 Units Spike Conc. LCS Result LCS % Rec % Rec Limits cis-1,3-Dichloropropene ug/L 20 21.5 108 70-130 Dibromochloromethane ug/L 20 20.4 102 70-130 Dibromomethane ug/L 20 20.5 103 70-130 Ethylbenzene ug/L 20 19.4 97 70-130 lodomethane ug/L 40 38.8 97 57-140 Methylene Chloride ug/L 20 19.3 96 62-130 Styrene ug/L 20 20.2 101 70-130 Tetrachloroethene ug/L 20 18.5 92 70-130 Toluene ug/L 20 20.3 102 70-130 trans-1,2-Dichloroethene ug/L 20 20.3 102 70-130 trans- 1,3-Dichloropropene ug/L 20 21.8 109 70-130 trans-1,4-Dichloro-2-butene ug/L 20 21.8J 109 57-149 Trichloroethene ug/L 20 20.9 105 70-130 Trichlorofluoromethane ug/L 20 18.8 94 57-130 Vinyl acetate ug/L 40 42.3J 106 70-141 Vinyl chloride ug/L 20 21.6 108 66-140 Xylene (Total) ug/L 60 61.0 102 70-130 1,2-Dichloroethane-d4 (S) % 96 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8 (S) % 102 70-130 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4403009 MS 92729146016 Spike Parameter Units Result Conc. MSD Spike Conc. 4403010 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 21.3 23.1 106 115 70-146 8 30 1,1,1-Trichloroethane ug/L ND 20 20 24.0 26.0 120 130 70-150 8 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 21.5 22.9 107 115 66-144 7 30 1,1,2-Trichloroethane ug/L ND 20 20 21.2 23.8 106 119 70-142 12 30 1,1-Dichloroethane ug/L ND 20 20 24.6 27.1 123 135 68-150 10 30 1,1-Dichloroethene ug/L ND 20 20 25.2 27.3 126 137 64-162 8 30 1,2,3-Trichloropropane ug/L ND 20 20 21.5 22.8 107 114 66-144 6 30 1,2-Dibromo-3- ug/L ND 20 20 19.2 20.9 96 104 62-146 9 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 20.4 23.5 102 117 70-143 14 30 1,2-Dichlorobenzene ug/L ND 20 20 21.2 23.6 106 118 70-142 11 30 1,2-Dichloroethane ug/L ND 20 20 24.9 26.4 124 132 68-145 6 30 1,2-Dichloropropane ug/L ND 20 20 22.5 25.4 112 127 70-144 12 30 1,4-Dichlorobenzene ug/L ND 20 20 20.4 24.0 102 120 70-140 16 30 2-Butanone (MEK) ug/L ND 40 40 44.8J 51.91 112 130 57-156 15 30 2-Hexanone ug/L ND 40 40 44.6J 49.2J 111 123 62-153 10 30 4-Methyl-2-pentanone ug/L ND 40 40 40.8J 45.OJ 102 113 65-144 10 30 (MIBK) Acetone ug/L ND 40 40 45AJ 52.1J 114 130 49-162 14 30 Acrylonitrile ug/L ND 100 100 105J 121J 105 121 59-155 15 30 Benzene ug/L ND 20 20 22.3 25.1 111 126 68-144 12 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 68 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4403009 MS 92729146016 Spike Parameter Units Result Conc. MSD Spike Conc. 4403010 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Bromochloromethane ug/L ND 20 20 23.4 25.1 117 125 70-148 7 30 Bromodichloromethane ug/L ND 20 20 21.5 24.4 108 122 70-141 13 30 Bromoform ug/L ND 20 20 19.9 20.8 100 104 59-144 4 30 Bromomethane ug/L ND 20 20 36.0 41.9 180 209 23-190 15 30 IH,M1 Carbon disulfide ug/L ND 20 20 24.2J 26.8J 121 134 64-160 10 30 Carbon tetrachloride ug/L ND 20 20 23.8 25.0 119 125 70-147 5 30 Chlorobenzene ug/L ND 20 20 21.9 23.7 109 119 70-143 8 30 Chloroethane ug/L ND 20 20 30.0 33.7 150 169 55-190 12 30 v1 Chloroform ug/L ND 20 20 24.0 24.4 120 122 67-148 1 30 Chloromethane ug/L ND 20 20 27.1 28.4 135 142 38-180 5 30 cis-1,2-Dichloroethene ug/L ND 20 20 23.7 26.6 118 133 67-151 12 30 cis-1,3-Dichloropropene ug/L ND 20 20 22.7 24.7 114 124 70-142 9 30 Dibromochloromethane ug/L ND 20 20 21.5 22.5 108 113 68-140 5 30 Dibromomethane ug/L ND 20 20 19.4 22.2 97 111 70-142 13 30 Ethylbenzene ug/L ND 20 20 22.7 24.7 113 123 70-145 9 30 lodomethane ug/L ND 40 40 41.3 45.9 103 115 37-160 11 30 Methylene Chloride ug/L ND 20 20 21.1 23.7 105 119 54-149 12 30 Styrene ug/L ND 20 20 22.1 23.7 111 118 70-147 7 30 Tetrachloroethene ug/L ND 20 20 20.7 22.5 103 112 70-145 8 30 Toluene ug/L ND 20 20 21.5 24.3 107 122 65-146 12 30 trans-1,2-Dichloroethene ug/L ND 20 20 24.4 27.1 122 136 69-155 11 30 trans-1,3-Dichloropropene ug/L ND 20 20 23.0 26.1 115 130 70-142 12 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 24.5J 24.OJ 123 120 39-149 2 30 Trichloroethene ug/L ND 20 20 22.3 24.3 112 121 70-152 8 30 Trichlorofluoromethane ug/L ND 20 20 25.4 27.5 127 137 60-158 8 30 Vinyl acetate ug/L ND 40 40 46.7J 50.3 117 126 56-157 8 30 Vinyl chloride ug/L ND 20 20 26.2 29.2 131 146 51-178 11 30 Xylene (Total) ug/L ND 60 60 69.0 74.9 115 125 70-146 8 30 1,2-Dichloroethane-d4 (S) % 115 115 70-130 4-Bromofluorobenzene (S) % 106 104 70-130 Toluene-d8 (S) % 100 97 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 69 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS CO Result confirmed by second analysis. IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be considered an estimated value. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 70 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92729146001 1403-MW-1R2 855406 92729146002 1403-MW-3R2 855406 92729146003 1403-MW-4 855406 92729146005 1403-MW-5 855406 92729146006 1403-MW-6 855406 92729146007 1403-MW-7 855406 92729146008 1403-MW-8 855406 92729146009 1403-MW-9 855406 92729146010 1403-MW-10 855406 92729146011 1403-MW-11 855406 92729146012 1403-MW-12 855406 92729146014 1403-SW1 855406 92729146015 1403-SW2 855406 92729146016 1403-SW3 (MS/MSD) 855406 92729146017 1403-SW4 855406 92729146018 1403-SW5 855406 92729146019 1403-U D1 855406 92729146020 1403-U D2 855406 92729146001 1403-MW-1R2 EPA 3005A 853390 EPA 6020B 853530 92729146002 1403-MW-3R2 EPA 3005A 853390 EPA 6020B 853530 92729146003 1403-MW-4 EPA 3005A 853390 EPA 6020B 853530 92729146004 1403-DUP@MW-4 EPA 3005A 853390 EPA 6020B 853530 92729146005 1403-MW-5 EPA 3005A 853390 EPA 6020B 853530 92729146006 1403-MW-6 EPA 3005A 853390 EPA 6020B 853530 92729146007 1403-MW-7 EPA 3005A 853390 EPA 6020B 853530 92729146008 1403-MW-8 EPA 3005A 853390 EPA 6020B 853530 92729146009 1403-MW-9 EPA 3005A 853390 EPA 6020B 853530 92729146010 1403-MW-10 EPA 3005A 853390 EPA 6020B 853530 92729146011 1403-MW-11 EPA 3005A 853390 EPA 6020B 853530 92729146012 1403-MW-12 EPA 3005A 853390 EPA 6020B 853530 92729146013 1403-Field Blank EPA 3005A 853390 EPA 6020B 853530 92729146014 1403-SW1 EPA 3005A 853390 EPA 6020B 853530 92729146015 1403-SW2 EPA 3005A 853390 EPA 6020B 853530 92729146016 1403-SW3 (MS/MSD) EPA 3005A 853390 EPA 6020B 853530 92729146017 1403-SW4 EPA 3005A 853390 EPA 6020B 853530 92729146018 1403-SW5 EPA 3005A 853390 EPA 6020B 853530 92729146019 1403-U D1 EPA 3005A 853390 EPA 6020B 853530 92729146020 1403-U D2 EPA 3005A 853390 EPA 6020B 853530 92729146001 1403-MW-1R2 EPA 8260D 853049 92729146002 1403-MW-3R2 EPA 8260D 853049 92729146003 1403-MW-4 EPA 8260D 853049 92729146004 1403-DUP@MW-4 EPA 8260D 853049 92729146005 1403-MW-5 EPA 8260D 853049 92729146006 1403-MW-6 EPA 8260D 853049 92729146007 1403-MW-7 EPA 8260D 853049 92729146008 1403-MW-8 EPA 8260D 853049 92729146009 1403-MW-9 EPA 8260D 853049 92729146010 1403-MW-10 EPA 8260D 853049 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2024 04:04 PM without the written consent of Pace Analytical Services, LLC. Page 71 of 99 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Foothills LF/Semi-Annual Pace Project No.: 92729146 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92729146011 1403-MW-11 EPA 8260D 853049 92729146012 1403-MW-12 EPA 8260D 853049 92729146013 1403-Field Blank EPA 8260D 853049 92729146014 1403-SW1 EPA 8260D 853049 92729146015 1403-SW2 EPA 8260D 853049 92729146016 1403-SW3 (MS/MSD) EPA 8260D 853211 92729146017 1403-SW4 EPA 8260D 853210 92729146018 1403-SW5 EPA 8260D 853210 92729146019 1403-UD1 EPA 8260D 853210 92729146020 1403-UD2 EPA 8260D 853210 92729146021 1403-Trip Blank EPA 8260D 853210 Date: 05/21 /2024 04:04 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 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Z M z �rDfn(nU7 ,lmi) in Z ZZ22 2 O �fJ��C� �' OOz� n < 0 000 I a � 00c 0vr � in � 3 0 0 1 n m - O o, IA 0 0 Z O a 9 0 o d z n A Pa 0 j x H m C� � n W cn O to -! 1�t ') t1� '1 v) t►1 -1 V► -1 lJ� -1 -o O -o O � p m C) m c) m m `ht fll m r- ci m 1 t1w _ 1 1 1/� 1 H 1 1 ( 0 m n m m n m CO 1 D 1 z �•• O O S0 COp 1 1 1 1 1 1 1 C Z m O O D CD co i t N C-im N 1 W 9 n m !" o Z •C ..NC 1 i S m W z n n �' o n 0 =O .... .� .... m m z Cn (/) O D z W _ 1 W W ._ W .. S m v y < m z C: .i QQ -C oQ p V% aQ O = > m m m r r CO r --i yno X y CC CC CC CC CC CC CC O D G G G G C G G G mx � Z � m o ' Co v900 Z m �y C > � W_ X X X X X X X X X X 'm >MG) -a 'p V =i m �� �. .p O O CA)D � � N m m \g m m W p -P -Ph, -Ph, m N .� O CD O— m O W _G n m m r w �' m J C C Cn C/) U) CA (A 0 p m y c D o)? n ro� K Z N C)1 W N Z Z G z n /TT K /-' 90 S c 0 C(' .ZI z .Z7 TU N -4 � P � -4 -4 � -P itm rn m z — D z O 0>_ ° m ism m g m co)= fJ c a Ric m X X X X X X X X >C X APPENDIX I- VOC BY 8260 < '= m mo m m :z a v 00 < D y X X 1>< X >C X X X X APPENDIX I- METALS w ro CO X X X X X X >C X PFAS -1633 -4-0 N o ;u 8 m jo a n a c m m � m 0 m\� m m 3 J. d N O CO 00 -I O (31 � GJ ~- m 0° 3 c z o— oo D r Z m �cncn0�o O (n < 0 D D A g D D 0 c 0 D -1 O O cn Z rmr m m> r W D m c ;u zm� cn S CA�fOrlp�Z y m 0 0 n v D m CO c m N G 11 D D D CO O X X mCD T4h r cn r D O f J M CT A W N m m N, 0 �fcJ�0 0 n O O O N 40h 3 Op 00 O D p a:_ IA' _I D n m -1 p1 7 m IA o 0 °' O z _ w O z o> n 6A, n IA O Pa a (� DC#_Title: ENV-FRM-HUN1-0083 v03_Sample Condition Upon Receipt Effective Date: 12/01/2023 aboratory receiving samples: od ❑ Huntersville ❑ Raleigh❑ Mech sville❑ Atlanta0"' ❑ Kernersville Asheville ❑ Eden❑ Greenwo Clien0ame: �. Project WV# . 92729146 29146 _ Due Date: 05/16/24 USPS ❑Client PH- MP Courier: E! - UPS ❑ GARepNC ❑ Commercial ❑face ❑Other: CLIENT Custody Seal Present? ❑Yes ❑No Seals Intact? ❑Yes [:]No [:]N/A Date/Initials Person Examining Contents:. Biological Tissue Frozen? Packing Material: ❑Bubble wrap ubble Bags ❑None ❑ Other ❑Yes g❑No ❑N'I%— Thermomete ' IR Gun ID:' Type of Ice: ' Wet ❑Blue Correction Factor: �! Add/Subtract (.0 , Cooler Temp: - Cooler Temp Corrected ('C): _ USDA Regulated Soil (❑ N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? ❑Yes ❑No — T Chain of custody Present? cT5s ❑No ❑N/A 1 Samples Arrived within Hold Time? Yes ONO ❑NIA 2. Short Hold Time Analysis (¢72 hr.)? I]Ye IJs 'N° ❑NIA 3. Rush Turn Around Time Re uested? ❑Yes ©No ❑N/A 4• Sufficient Volume? F%S7 ❑NO ❑N/A S Correct Containers Used? OyesNo ❑ ❑N/A 6- -Pace Containers Used? ❑Y�s es ❑No ❑N/A Containers Intact? ❑Yes ❑No ❑NIR 7. Dissolved analysis: Samples Field Filtered? ❑Yes ❑No ❑N/A 8. Sample Labels Match COC? Yes ON. ❑N/A 9. -Includes Date/T`ime/ID/Analysis Matrix: t Headspace in VOA Vials (a5-6mm)? Oyes ElNo ❑N/A 10. Trip Blank Present? [aY� ❑ No ❑NIA 11. ❑Yes ❑No ❑N/A Trip Blank Custody Seals Present? -OMMENTS/SAMPLE DISCREPANCY LIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: ❑None Temp should be above freezing to 6-C ❑Samples out of temp criteria. Samples on ice, cooling process has begun Did samples originate from a foreign source (internationally, including Hawaii and Puerto Rico)? Oyes ❑No PI Lot ID of split containers: Date/Time. — Date: Date: Ji' Field Data bI L' l ? ❑Yes Page 1 of 2 Page 75 of 99 �ualtrax ID: 69614 DC# Title: ENV-FRM-HUN1-0083 v03_Sample Condition Upon Receipt (C6 u+Aura:«cvC-s Effective Date: 12/01/2023 *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottles ***Check all unpreserved Nitrates for chlorine WOO:927Z9146 4 Project #05/16/2 PM- MP Due Date CLIENT GARePNC :M W U Z N C/ al Q. u m a J E Ln N a-1 a m Z U/ Ol w CL C V m a J E 0 N a CM Z W G/ a C u m a J E O 111 cN. to Z a U N m d y O a co _ N y d O 2 V a E Ln VI a In N y tZ rl O Z 2 u m a J E 0 N Z n In o Z W f0 u Q N U ^ 12 E N -4-4 N a m iz ^ !Z 2 O Z V a J E N -4 m a m > v j m ("� L 3 o E v e=i O 3 U a N v Q E Q °= _ .--I N 0 a N y a 2 E Q ? — c-1 N tv a U Q > a C = E ¢ J E O i N M 0 a y t2 V 0) 2 n E Q `w •� — a--1 ch 0 a V 2 O N 2 d E ¢ J E o N N In W a U Q Z U = Z N a E ¢ E O T l7 o Q Z z; = Q 0 > E 0 61 C7 o Q O N m Z ¢`w O > E O V 61 l7 > z W > O/ c 0 > J E 0 O� l7 > ¢ Z V O M 2 0 > J E V CA t7 o a ? > N C � U a J E O 7 n Y Q a+ m CJ 2 > Y Y a 1A m > V Y > Z Z' 10 a N n J E Ln N � r a CA Z N T a O/ n J E o In N F- a W)m Ol O 0 N = Z Y f6 a J of N cc a Q z N Ul O w Q ¢ E o 0 ci O a < \ c O — Z Ln J E 0 N O W of > Ol o C E Q J E 0 V � m o 2 3 4 5 6 7 8 9 101\1 I I N \1\1\I I I\1 I\ \1\13 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative Lot # added Vote: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DENR Certification Office (i.e. Dut of hold, incorrect preservative, out of temp, incorrect containers. Page 76 of 99 ualtrax ID: 69614 Paae 2 of 2 DC# Title: ENV-FRM-HUN1-0083 v03_Sample Condition Upon Receipt aye Effective Date: 12/01/2023 140# : 92729146 *Check mark top half of box if pH and/or dechlorination is verified and Project # PM: MP within the acceptance range for preservation samples. Due Date: 05/16/24 Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg CLIENT: GARepNC **Bottom half of box is to list number of bottles ***Check all unpreserved Nitrates for chlorine U Q Z Gl > Q Z O/ %. Q Z Gl Q Z 'U U N V N V O Z U cN-1 n v C = U Q Z W U Z 'O > Gl N V R v = Q U Q^ Z _ Q Z Q Z ,..� W Q Q Z y % Q Z �+ Y f0 M I Q Z -0 I Q Z n M Ln v Z W >' Z Z m j -0 j G/ O/ N ❑. Cr O U ` O/ W Q. C U N (l O_ C 0 u c: O N 2 U M Z _ U u Z N U 2 Z U N (9 � N L W C Z) n V a U S n O_ �- V O, N = V O N = W �� 0 = Z Q\ Z U = M 0 ,N N N Z � vOi E O_ C 0 Z 0 d M S N C 0 U " _ Y u �n t0 N Y �n 10 a Ul N N Z u �, m C Gl — E: j C O a+ = N O_ C N a E LA N a E O N aIn E O O N a`, _ E V1 N J E O N E N N m J E ul o E v E Q a`i _ ; Q a`i = E Q J E u01 E Q --' c-1 E Q J E N s E a E O V Q o > J O V Q 0 > E O V a 0 J O V Q 0 J O V J Cl E lA a VI m .M.. a`i :, J E N ; J E a J of N a E J E N E Q J E V E _ ,r a m M a m N M m e-1 n m a m M a to�m et a a m 3 e=-i C7 a -4-4 (7 a rn fo a l7 a M (D a CA C7 o M (7 o M l7 > M l7 > M (7 r, n Y (7 > > Ln a N a '^ M m C7 Q U > Ol s 4 V 1 C r I {r 5 \ i I I ✓ J 6 7 8 V 9 10 NN \s 11 12 \ [�N pH Adjustment Log for Preserved Samples Sample ID f Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservatve Lot # I I adjusted added Vote: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DENR Certification Office (i.e. Dut of hold, incorrect preservative, out of temp, incorrect containers. ualtrax ID: 69614 Paae 2 of 2 Page 77 of 99 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIVE: E S & S - B.CHIODO SAMPLE MATRIX: DEIONIZED WATER LAB SAMPLE / PROJECT #: NA INITIAL WATEREVEL (FT) ELEV., MEAS. PT. (MSL): DATE METHOD OF EVACUATION: ( } PVC BAILER ( ) S.S. BAILER ( ) S.S. BAILER ( ) QED PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA ( ) GRUNDFO: ( ) OTHER ( ) 3 ( ) 4 DEPTH TO BOTTOM (FT) ELEVATION, G/W (MSL): TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: UMP ( ) YES ( ) NO ( ) 6 ( THER WAS WELL PURGE�TY WATER LEVEL END PURGE FINISH ESS ( )YES( ) NO TIME PURGE RATE ( DTW (FT) CUMULATIVE VOLUME TEMP. C pH Std.Units) CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV SAMPLING INFORMATION DATE / TIME . 5- / 1.51.32 METHOD OF SAMPLING: ( ) PVC BAILER ( ) S.S. BAILER ( ) S.S. BAILER ( ) QED PUMP SAMPLING FIELD MEASUREMENT DATA DEPTH TO GROUNDWATER (FT) NA SAMPLING EQUIPMENT DEDICATED: ( ) GRUNDFOS PUMP ( ) YES ( ) OTHER ( ) NO TIME pH Std.Units TEMP. C CONDUCT. umhos/cm TURBIDITY (NTU) OTHER eh (mV) ]PPM DISS.OXY. OTHER NA NA NA NA NA NA NA NA GENERAL INFORMATION vie WEATHER CONDITIONS AT TIME OF SAMPLING: w lv! SAMPLE CHARACTERISTICS: - COMMENTS: APPENDIX I LIST + PFAS SAMPLE COLLECTION NUMBER Page 78 of 99 SITE NAME: FOOTHILLS LF POINT ID: TRIP BLANK LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIVE: SAMPLE MATRIX: DEIONIZED WATER LAB SAMPLE / PROJECT #: INITIAL VVATgR LEVEL (FT) ELEV., MEAS. PT. (M METHOD OF EVACUATION: ( ) PVC BAILER ( ) S.S. BAILER ( ) S.S. BAILER ( ) QED PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS: START E1h4CUAI QN STABILIZATION DATA DEPTH TO BOTTOM (FT) ELEVATION, G/W (MSL): E S & S - B.CHIODO TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( ) GRUN S PUMP ( ) YES ( ) NO ( ) OTHER ( ) 3 ( ) 4 ( ) 6 OTHER WAS WELL PURGED DRYNESS( )YES( ) NO WATER LEVEL END PURGE FINISH TIME PURGEPATa m/htz DTW F CUMULATIVE OLUME TEMP. C) pH Std.Units CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV SAMPLING INFORMATION DATE/TIME / 1 METHOD OF SAMPLING: DEPTH TO GROUNDWATER (FT) NA SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP ( ) YES ( ) S.S. BAILER ( ) QED PUMP ( ) OTHER ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME pH (Std.Units) TEMP. (C CONDUCT. (umhos/cm) TURBIDITY (NTU OTHER eh (mV) DISS.OXY. (PPM OTHER NA NA NA NA NA NA NA NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: a SAMPLE CHARACTERISTICS: COMMENTS: VOA ONLY A Pe A?P 1 o,t 1 SAMPLE COLLECTION NUMBER Page 79 of 99 SITE NAME: FOOTHILLS LF POINT ID: Sw - 1 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER Rk INITIAL WATER`1=E L (FEET) NA ELEVATION, MEAS.PT.(MSL): NA DATE METHOD OF EVACUATION: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT M NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH 1 EVACUATION EQUIPMENT DEDICATED: ( ) CONTINUO ( ) YES ( ) NO PUMPING WELL ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DR WATER LEVEL AFTER PURGE (FT.) FINISH ( ) YES ( ) NO TIME PURGE RAT m/htz LATIVE VOLUME TEMP. pH Std.Units) SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME s o / WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.0nits) SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh (mV) DISS.OXY. (PPM OTHER S;a p 16). Ll 44. 9O + 3,7.57NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: o� SAMPLE CHARACTERISTICS: - - �- COMMENTS: APPENDIX I LIST + PFAS Page 80 of 99 SAMPLE COLLECTION NUMBER 15 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: UNDERDRAIN WATER EVAGUATION INFORMATION INITIAL WA' VEL (FEET) NA ELEVATION, MEAS.PT.(MSL): NA DATE METHOD OF EVACUATION: FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH / ( ) PVC BAILER ( ) WELL WIZARD ( ) CONTINUOUS ( ) S.S. BAILER ( ) GRUNDFOS PUMP PUMPING WELL EVACUATION EQUIPMENT DEDICATED: ( ) YES ( ) NO WELL RISER DIAMETER (IN.): ( ) 2 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA WAS WELL PURGED TO DRYN ( ) YES ( ) NO WATER LEVEL AFTER PURGE (FT.) FINISH TIME PURGE RATE m/htz C LNTT� VOLUME TEMP. C pH nits SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME f g4 / 15*59 METHOD OF SAMPLING: WATER LEVEL PRIOR TO SAMLING (FT.) NA SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( } NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.0nits) SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh (mV) DISS.OXY. (PPM OTHER 1 �"Ob . 0 4 7 C1, NA GENERAL INFORMATION 7.5. a r WEATHER CONDITIONS AT TIME OF SAMPLING: trt asi SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST + PFAS Page 81 of 99 SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: EVACUATION INFO UNDERDRAIN WATER INITIAL WATER4..EVEW L�(F�EET) NA ELEVATION, MEAS.PT.(MSL): NA DATE METHOD OF EVACUATION: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA POINT ID: UD - 1 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( ) CONTINUOUS ( ) YES ( ) NO PUMPING WELL ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNES WATER LEVEL AFTER PURGE (FT.) FINISH YES ( ) NO TIME PURGE RATE m/htz CU VOLUME TEMP. C pH t SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME . .. 2 / I V 17 WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.Units SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh (mV) DISS.OXY. (PPM OTHER 16:1 M J ft. NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: &4 SAMPLE CHARACTERISTICS: (' COMMENTS: APPENDIX I LIST + PFAS Page 82 of 99 SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF LOCATION: LENO|R N(]RTHCAROL|NA SAMPLE MATRIX: EVQQJATUON lNP SURFACE WATER 'INITIAL WA71ER�L �VEL (FEET) NA ELEVATION, MEAS.PT.(MSL): NA DATE METHOD OF EVACUATION: ( ) PVC BAILER ( ) WELL WIZARD ( S.S. BAILER ( >GRUNDFOGPUMP WELL RISER DIAMETER (IN.): ( )2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURG|NG8: START EVACUATION STABILIZATION DATA POINT ID: SW-2 FIELD REPRESENTATIVE; ES&S-B.CH|ODO LAB SAMPLE/PROJECT#: NA DEPTH TO BOTTOM (FE ELE\A\T|[JN.G/VV (K8SL): NA EVACUATION EQUIPMENT DEDICATED: CONTINUOUS YES NO PUMPING WELL ( )4 ( )G ( )OTHER_____ -~~� WAS WELL PURGED TO DRYNES YES ( )NO WATER LEVEL AFTER PURGE (FT.) FINISH PURGE R -GUMU� �TIVE TEMP. pH SPEC. CONDUCT. TURBIDITY OTHER NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME H- VV/QlER LEVEL PR|ORTOSAMUNG (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( > VVATERRAPUKUP (X) YES S.S. BAILER GRUNDFOS PUMP (X) DIP BOTTLE NO SAMPLING FIELD MEASUREMENT DATA pH SPEC. CONDUCT. TEMP. TURBIDITY REDOX DISS. OXY. OTHER GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: L4 s-4 COMMENTS: APPENDIX | LIST +PFAG �^ ��mm� SAMPLE COLLECTION NUMBER �� SITE NAME: FOOTHILLS LF POINT ID: sw - 5 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER INITIAL WA` EVEL (FEET) NA ELEVATION, MEAS.PT.(MS NA DATE lkytl_c00M[*I_Dxojm m0911�yI& in, ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( ) CONTINUO ( ) YES ( ) NO PUMPING WELL ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNE WATER LEVEL AFTER PURGE (FT.) FINISH ) YES ( ) NO TIME PURGE RA m/htz UMULAT_ IVE VOLUME TEMP. C pH td.Units SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME / H 4 METHOD OF SAMPLING: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP SAMPLING FIELD MEASUREMENT DATA WATER LEVEL PRIOR TO SAMLING (FT.) NA SAMPLING EQUIPMENT DEDICATED: ( ) WATERRA PUMP (X) YES (X) DIP BOTTLE ( ) NO TIME pH Std.Units SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh mV DISS.OXY. PPM OTHER 1 ;t' d C0. a O 450.(. , / NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: t� SAMPLE CHARACTERISTICS: ., , COMMENTS: APPENDIX I LIST Page 84 of 99 SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER INITIAL WATER -LEVEL FEET) NA ELEVATION, MEAS.PT.(MSL): NA DATE METHOD OF EVACUATION: POINT ID: SW-4 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH / ( ) PVC BAILER ( ) WELL WIZARD ( ) CONTINUOUS ( ) S.S. BAILER ( ) GRUNDFOS PUMP PUMPING WELL WELL RISER DIAMETER (IN.): ( ) 2 ( ) 4 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA EVACUATION EQUIPMENT DEDICATED: ( ) YES ( ) NO ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNES WATER LEVEL AFTER PURGE (FT.) FINISH YES ( ) NO TIME PURGE RATE m/htz CUMU AT VOLUME TEMP. C pH td-Units SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME 5,5,aLi / 1?:18 WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.Units SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh mV DISS.OXY. PPM OTHER GENERAL INFORMATION ar WEATHER CONDITIONS AT TIME OF SAMPLING: r�# SAMPLE CHARACTERISTICS: IL41Z 0 - t COMMENTS: APPENDIX I LIST Page 85 of 99 SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER EVA=ATION INFORMATION INITIAL WA EVE��L--��(..F��EET) NA ELEVATION, MEAS.PT.(MSL� NA DATE METHOD OF EVACUATION: POINT ID: SW - 3 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( )PVC BAILER ( WELL WIZARD ( )CONTINUOUS ) YES ( ) NO ( ) S.S. BAILER ( ) GRUNDFOS PUMP PUMPING WELL WELL RISER DIAMETER (IN.): ( ) 2 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) WAS WELL PURGED TO DRYNESS ( S ( )NCO TOTAL VOLUME EVACUATED (GAL) WATER LEVEL AFTER PURGE (FT.) TURBIDITY OF PURGINGS : START FINISH EVACUATION STABILIZATION DATA TIME PURGE RATEMCVMUL&TIVE m/htz VOLUME TEMP. pH Std.Units SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME - r 4 / 1 , VO WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( } NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.Units SPEC. CONDUCT. umhos/cm TEMP. C 1 TURBIDITY NTU REDOX eh (mV) DISS.OXY. (PPM OTHER 1'7,' ).O ) 's- 60. 30 NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: �+t SAMPLE CHARACTERISTICS: C — l COMMENTS: APPENDIX I LIST s / W SAMPLE COLLECTION NUMBER 9 * / Page 86 of 99 SITE NAME FOOTHILLS LF POINT ID: MW - 12 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT):_ ELEV., MEAS. PT. (MSL): DATE -(® %I FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: 1 DEPTH TO BOTTOM (FT): IN ELEVATION, G/W (MSL): _ 7 TIME: START/FINISH / �- METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) . Off' WATER LEVEL END PURGE (FT) TURBIDITY OF PURGINGS: START FINISH CLSQ- EVACUATION STABILIZATION DATA - �� - • • • -: 109• • r pis f. * � ,�. /j SAMPLING INFORMATION DATE / TIME ® G - JZ %-f / DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING SAMPLE CHARACTERISTICS: C SAMPLING EQUIPMENT DEDICATED: (X) YES ( ) NO CL0lso0E- COMMENTS: APPENDIX I LIST + PFAS SAMPLE COLLECTION NUMBER I 1 Page 87 of 99 SITE NAME FOOTHILLS LF POINT ID: IV w -11 LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIVE: E S & S - B.CHIODO SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSL): 1 Lia DATE " '' 14 LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FT): a 0 ELEVATION, G/W (MSL): TIME: START/FINISH ; to / METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) 11.0o WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) 0,00 WATER LEVEL END PURGE (FT) TURBIDITY OF PURGINGS: START FINISH C EVACUATION STABILIZATION DATA P -RAT URGE RATGOMMI pH .-' SAMPLING INFORMATION r DATE / TIME - 24 / DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION 09, WEATHER CONDITIONS AT TIME OF SAMPLING: WA 0 SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST + PFAS Page 88 of 99 SAMPLE COLLECTION NUMBER + SITE NAME FOOTHILLS LF POINT ID: MW - 7 R LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT): ELEV., MEAS. PT. (MSL): 1 ELEVATION, G/W (MSL): DATE - 6 TIME: START/FINISH METHOD OF EVACUATION: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER NA 0 L{ / 730 EVACUATION EQUIPMENT DEDICATED: (X) YES ( ) NO WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) - WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) . 00 WATER LEVEL END PURGE (FT) 2q, 30 TURBIDITY OF PURGINGS: START C U14L FINISH C EVACUATION STABILIZATION DATA ME PURGE RATIM1115470M • pH • • TllRBIDITT w Will le i ®� ■ t � IPA �� SAMPLING INFORMATION DATE/TIME .- b ® / 71f, DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER SAMPLING EQUIPMENT DEDICATED: (X) YES ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: L-0 t>t �i SAMPLE CHARACTERISTICS: C' COMMENTS: APPENDIX I LIST + PFAS SAMPLE COLLECTION NUMBER 13 Page 89 of 99 SITE NAME FOOTHILLS LF .� 1-11 f, LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIVE: E S & S - B.CHIODO SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT): iull ELEV., MEAS. PT. (MSL): 135-8r. 53 ELEVATION, G/W (MSL): 1219-18 DATE ' ( � aLf TIME: START/FINISH T53/ METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) , 00 WATER LEVEL END PURGE (FT) TURBIDITY OF PURGINGS: START FINISH EVACUATION STABILIZATION DATA PURGE RAT all pH rereliffiblZill p r� SAMPLING INFORMATION DATE /TIME '^ 6 - 14 / ' :2 5 DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: C COMMENTS: APPENDIX I LIST + PFAS SAMPLE COLLECTION NUMBER Page 90 of 99 SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINPOINT ID: ml W. 9 — FIELD REPRESENTATIVE: E S & S - B.CHInn ............. ........ . . . SAMPLE MATRIX: GROUNDWATER LAB SAMPLE / PROJECT #: EVACUATION INFgp itnA-ro-h- NA INITIAL WATER LEVEL (FT):DEPTH P-1 — TO BOTTOM (FT): 73, If 0 ELEV., MEAS. PT. (MSL): GtIO. 71 ------------ — DATE /W ELEVATION, G(MS Q: ---- I 1 ?-0- 01 METHOD OF EVACUATION: TIME: START/FINISH VL"4 I / q 113 PVC BAILER ( ) S.S. BAILER GRUNDFOS PUMP S.S. BAILER (X)QED WWPUMP( EVACUATION EQUIPMENT DEDICATED: (X) YES OTHER NO 'YELL RISER DIAMETER (IN.): (X) 2 3 ) 4 )NE (1) RISER VOLUME (GAL) 6,43 6 OTHER OTAL VOL. EVACUATED (GAL) WAS WELL PURGED TO DRYNESS( )YES(X)NO URBIDITY OF PURGINGS: START CifQ_ WATER LEVEL END PURGE (FT) 76. t3 VAC JATION STABILIZATION DATA FINISH TIME PURGE RATE DTW FT CUMUL. TEMP. VOL GAL) pH CONDUCT. TURBIDITY REDOX D. O. 250 70.1710 0 C I-Z -7 (Std.Units 51, 2 u umhos/6m) `7 Lt. (NTU eh mV MG/L 250 '70,'Al 1 '2-09 4-00-8 0.25 20 1 i 250 q0-79 0.50 17 5717 250 710. 0.75 I-Z 6- 47. 1 bla 250 740, 1.00 lk7,Z 250 a.71 1.25 14T 1 k7' S- /6 250 70f&- 1 :01 1.5 0 1 -7 + sry' -7 250 70 1rz 1.75 G 250 7093 2.00 2w fl-c� IPLING INFORMATION E/TIME 9-6-ZV / 6) '0 13 'HOD DEPTH TO GROUNDWATER (FT) 47 (9, S' ? OF SAMPLING: PVC BAILER S.S. BAILER GRUNDFOS PUMP SAMPLING EQUIPMENT DEDICATED- S.S. BAILER (X)QED WWPUMp OTHER (X) YES NO ERAL INFORMATION — ER 6— �AT TIME OF SAMPLING: C-Lo C4 b.. r10 00 LE CHARACTERISTICS: Q V.At MENTS: APPENDIX I LIST + PFAS SAMPLE COLLECTION NUMBER 157 Page 91 of 99 POINT ID: MW - 8 SITE NAME FOOTHILLS LF FIELD REPRESENTATIVE: E S & S — B.CHIODO LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT): ELEV., MEAS. PT. (MSL): ,10 ELEVATION, G/W (MSL): 1 1 DATE TIME: START/FINISH / f 0 g METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) 9 WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) R. 00 WATER LEVEL END PURGE (FT) TURBIDITY OF PURGINGS: START CFINISH EVACUATION STABILIZATION DATA 22 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): PURGE RATjM pH 0 0 �► � �® III + ,,..,� IIII � .; �",� ,e.- .,,, �; m _- SAMPLING INFORMATION DATE / TIME �-� - Z / 8 DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: . COMMENTS: APPENDIX I LIST + PFAS Page 92 of 99 SAMPLE COLLECTION NUMBER SITE NAME FOOTHILLS LF POINT ID: MW - 7 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT):_ ELEV., MEAS. PT. (MSL): DATE - 6 - 2 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT): 0 ELEVATION, G/W (MSL): TIME: START/FINISH / ()0 / /0,572 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) �. `% WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) WATER LEVEL END PURGE (FT) 9. 3r TURBIDITY OF PURGINGS: START L r-WZ FINISH c - EVACUATION STABILIZATION DATA SAMPLING INFORMATION DATE/TIME DEPTH TO GROUNDWATER (FT) 2 5,3-5' METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION OF WEATHER CONDITIONS AT TIME OF SAMPLING: CL. 0 SAMPLE CHARACTERISTICS: C US A2- COMMENTS: APPENDIX I LIST + PFAS SAMPLE COLLECTION NUMBER 1 P7 Page 93 of 99 SITE NAME FOOTHILLS L.F POINT ID: MW - 6 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSL): DATE 9-6 - Z FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FT): SO.SS ELEVATION, G/W (MSL): TIME: START/FINISH 1 1: O IVY/ METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ONE (1) RISER VOLUME (GAL) I• TOTAL VOL. EVACUATED (GAL) 00 ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS ( ) YES (X) NO WATER LEVEL END PURGE (FT) . 0 / TURBIDITY OF PURGINGS: START C FINISH EVACUATION STABILIZATION DATA PURGE RATE 19MMI •� pH ml mom NAMES SAMPLING INFORMATION DATE / TIME I DEPTH TO GROUNDWATER (FT) ° METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: �..C.� SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST + PFAS SAMPLE COLLECTION NUMBER 18 Page 94 of 99 SITE NAME FOOTHILLS LF POINT ID: mw - 5 LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIVE: E S & S - B.CHIODO SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSL): I 1 DATE - LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT) NA ELEVATION, G/W (MSL). t TIME: START/FINISH / 1 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) .Ott WATER LEVEL END PURGE (FT)q7 5-0 TURBIDITY OF PURGINGS: START CLgAR, FINISH C LEAF - EVACUATION STABILIZATION DATA PURGE RAT (ML MIN) im • - •• (St • -: - O• • SAMPLING INFORMATION DATE / TIME - _ Z/ DEPTH TO GROUNDWATER (FT) D METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: el C- 0tA b SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST + PFAS SAMPLE COLLECTION NUMBER 19 Page 95 of 99 SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT):_ FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT): Em ELEV., MEAS. PT. (MSL): r7 1. 19 ELEVATION, G/W (MSL): l DATE a - TIME: START/FINISH Q ,,/ METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) W7 G WAS WELL PURGED TO DRYNESS( )YES(X)NO TOTAL VOL. EVACUATED (GAL) Q, 0 0 WATER LEVEL END PURGE (FT) 411.30 TURBIDITY OF PURGINGS: START CFINISH C LS4 Az EVACUATION STABILIZATION DATA PURGE RATE pH ff IM, ITS In :a ■� „®k' 3 MWE SAMPLING INFORMATION DATE / TIME - / ' f °�" DEPTH TO GROUNDWATER (FT) Zil. 70 METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION 0-0 WEATHER CONDITIONS AT TIME OF SAMPLING: L O IA bil, o SAMPLE CHARACTERISTICS: C COMMENTS: APPENDIX I LIST + PFAS b q i? -7-A KF--j� •`! �� t Page 96 of 99 SAMPLE COLLECTION NUMBER SITE NAME FOOTHILLS LF POINT ID: MW - 3112 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: ELEV., MEAS. PT. (MSQ: DATE - 6 - METHOD OF EVACUATION: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN_): (X) 2 ( ) 3 ( ) 4 NA DEPTH TO BOTTOM (FT): "731 ELEVATION, G/W (MSL): t ®' VIE: START/FINISH t `. 39 / .% EVACUATION EQUIPMENT DEDICATED: (X) YES ( ) NO ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) WATER LEVEL END PURGE (FT) TURBIDITY OF PURGINGS: START FINISH EVACUATION STABILIZATION DATA PURGE RATE (ML MW)__ Mm��M—(Std. pH Units) • 1. 1 !u. !! " . m SAMPLING INFORMATION DATE/TIME - � - 2 / DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION F WEATHER CONDITIONS AT TIME OF SAMPLING: o SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST + PFAS SAMPLE COLLECTION NUMBER Page 97 of 99 SITE NAME FOOTHILLS LF POINT ID: MW - 2R LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ) a FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT) ELEV., MEAS. PT. (MSL}: ELEVATION, G/W (MSL): l DATE TIME: START/FINISH o METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( } S.S. BAILER (X) QED WW PUMP ( ) OTHER NA WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) 1.411 WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) o WATER LEVEL END PURGE (FT) 1, TURBIDITY OF PURGINGS: START FINISH EVACUATION STABILIZATION DATA • SAMPLING INFORMATION DATE / TIME - / I DEPTH TO GROUNDWATER (FT) 1> METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: 7o SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX II LIST + PFAS SAMPLE COLLECTION NUMBER Page 98 of 99 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: LEACHATE EVAQUATION INFORMATION INITIAL WA-I-ER-LEva (FEET) NA ELEVATION, MEAS.PT.(MSL):-----" NA DATE METHOD OF EVACUATION: PVC BAILER WELL WIZARD S.S. BAILER GRUNDFOS PUMP WELL RISER DIAMETER (IN.): 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA POINT ID: LEACHATE FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE/ PROJECT NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH EVAC UATION EQUIPMENT DEDICATED: CONTINUOUS YES NO PUMPING WELL ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO:"DRYNE ) �YES ( )NO WATER LEVEL AFTER PURGE (FT.) FINISH TIME PURGE RATE (gpm/htz) C0MDtATAlF- VOLUME TEMP. C pH td.Units) SPEC. CONDUCT. (umhos/cm) TURBIDITY (NTU) OTHER eh MY) L NA 0 NA NA NA SAMPLING INFORMATION yy DATE/ TIME 5 ZLf / 1'395. METHOD OF SAMPLING: PVC BAILER WELL WIZARD S.S. BAILER GRUNDFOS PUMP SAMPLING FIELD MEASUREMENT DATA WATER LEVEL PRIOR TO SAMLING (FT.) WATERRA PUMP (X) SAMPLE PORT OA SAMPLING EQUIPMENT DEDICATED: (X) YES ( ) NO TIME pH (Std. U nits) SPEC. CONDUCT. (umhos/cm) TEMP. (C) 1 TURBIDITY (NTU) REDOX eh (mV) DISS. OXY. (PPM) OTHER 15'37 r-1 3 7 '/. I r7alo ;a 1 6k.;X0 '32.3 NA NA GENERAL INFORMATION OP WEATHER CONDITIONS AT TIME OF SAMPLING: cl- v 76 SAMPLE CHARACTERISTICS: I Z)- 67L4 Cc COMMENTS: Page 99 of 99 SAMPLE COLLECTION NUMBER ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 May 20, 2024 Environmental Manager Foothills Environmental Landfill 2800 Cheraw Road Lenoir, NC 28645 RE: Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 Dear Environmental Manager: Enclosed are the analytical results for sample(s) received by the laboratory on May 07, 2024. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace National - Mt. Juliet • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte • Pace Analytical Services - Peachtree Corners, GA If you have any questions concerning this report, please feel free to contact me. Sincerely, &,I 0j, Maiya Parks maiya.parks@pacelabs.com 770-734-4205 Project Manager Enclosures cc: Data Manager, TriHydro Corporation REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 44 Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 Pace Analytical Services National 12065 Lebanon Road, Mt. Juliet, TN 37122 Alabama Certification #: 40660 Alaska Certification 17-026 Arizona Certification #: AZ0612 Arkansas Certification #: 88-0469 California Certification #: 2932 Canada Certification #: 1461.01 Colorado Certification #: TN00003 Connecticut Certification #: PH-0197 DOD Certification: #1461.01 EPA# TN00003 Florida Certification #: E87487 Georgia DW Certification #: 923 Georgia Certification: NELAP Idaho Certification #: TN00003 Illinois Certification #: 200008 Indiana Certification #: C-TN-01 Iowa Certification #: 364 Kansas Certification #: E-10277 Kentucky UST Certification #: 16 Kentucky Certification #: 90010 Louisiana Certification #: A130792 Louisiana DW Certification #: LA180010 Maine Certification #: TN0002 Maryland Certification #: 324 Massachusetts Certification #: M-TNO03 Michigan Certification #: 9958 Minnesota Certification #: 047-999-395 Mississippi Certification #: TN00003 Missouri Certification #: 340 Montana Certification M CERT0086 Nebraska Certification #: NE-OS-15-05 Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 Pace Analytical Services Peachtree Corners 110 Technology Pkwy, Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 CERTIFICATIONS Nevada Certification #: TN-03-2002-34 New Hampshire Certification #: 2975 New Jersey Certification #: TNO02 New Mexico DW Certification New York Certification #: 11742 North Carolina Aquatic Toxicity Certification #: 41 North Carolina Drinking Water Certification #: 21704 North Carolina Environmental Certificate #: 375 North Dakota Certification #: R-140 Ohio VAP Certification #: CL0069 Oklahoma Certification #: 9915 Oregon Certification #: TN200002 Pennsylvania Certification #: 68-02979 Rhode Island Certification #: LA000356 South Carolina Certification #: 84004 South Dakota Certification Tennessee DW/Chem/Micro Certification #: 2006 Texas Certification #: T 104704245-17-14 Texas Mold Certification #: LAB0152 USDA Soil Permit #: P330-15-00234 Utah Certification #: TN00003 Virginia Certification #: VT2006 Vermont Dept. of Health: ID# VT-2006 Virginia Certification #: 460132 Washington Certification #: C847 West Virginia Certification #: 233 Wisconsin Certification #: 998093910 Wyoming UST Certification #: via A21-A 2926.01 A21-A-ISO 17025 Certification #: 1461.01 A21-A-ISO 17025 Certification #: 1461.02 AIHA-LAP/LLC EMLAP Certification #:100789 South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 North Carolina Certification #: 381 South Carolina Certification #: 98011001 Virginia Certification #: 460204 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 Lab ID Sample ID Matrix Date Collected Date Received 92729134001 92729134002 1403-MW-2R 1403-Trip Blank Water Water 05/06/24 15:12 05/05/24 15:34 05/07/24 09:57 05/07/24 09:57 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Foothills LF/Semi-Annual 92729134 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92729134001 1403-MW-2R EPA 8151 JMB 5 PAN EPA8011 HH 3 PASI-C EPA 8081 B SEM 21 PASI-C EPA 8082A SEM 8 PASI-C EPA 6020E MT1 16 PASI-GA EPA 7470A VB 1 PASI-GA EPA 8270E ICO 118 PASI-C EPA 8260D JJK 62 PASI-C SM 4500-S2D-2011 JP1 1 PASI-A SM 4500-CN-E-2016 MMA 1 PASI-A 92729134002 1403-Trip Blank EPA8011 HH 3 PASI-C EPA 8260D JJK 62 PASI-C PAN = Pace National - Mt. Juliet PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte PASI-GA = Pace Analytical Services - Peachtree Corners, GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 Lab Sample ID Method Client Sample ID Parameters 92729134001 1403-MW-2R Performed by pH Temperature Static Water Level Specific Conductance Oxidation Potential Oxygen, Dissolved Total Well Depth Turbidity EPA 6020B Barium EPA 6020B Beryllium EPA 6020B Copper EPA 8270E 1,4-Dichlorobenzene EPA 8260D Benzene EPA 8260D Chlorobenzene EPA 8260D 1,4-Dichlorobenzene EPA 8260D 1,1-Dichloroethane EPA 8260D cis-1,2-Dichloroethene EPA 8260D Vinyl chloride EPA 8260D Xylene (Total) SUMMARY OF DETECTION Result Units Report Limit Analyzed ES&S 05/06/24 15:12 5.35 Std. Units 05/06/24 15:12 17.9 deg C 05/06/24 15:12 51.82 feet 05/06/24 15:12 182.1 umhos/cm 05/06/24 15:12 92.1 mV 05/06/24 15:12 2.15 mg/L 05/06/24 15:12 63.60 feet 05/06/24 15:12 0.46 NTU 05/06/24 15:12 403 ug/L 100 05/13/2418:54 0.18J ug/L 1.0 05/13/2418:54 0.44J ug/L 10.0 05/13/2418:54 1.7J ug/L 8.3 05/09/2413:25 3.5 ug/L 1.0 05/09/24 04:20 0.49J ug/L 3.0 05/09/24 04:20 2.8 ug/L 1.0 05/09/24 04:20 0.801 ug/L 5.0 05/09/24 04:20 4.OJ ug/L 5.0 05/09/24 04:20 0.63J ug/L 1.0 05/09/24 04:20 4.3J ug/L 5.0 05/09/24 04:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Qualifiers Page 5 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 Sample: 1403-MW-2R Lab ID: 92729134001 Collected: 05/06/24 15:12 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 05/06/24 15:12 pH 5.35 Std. Units 1 05/06/24 15:12 Temperature 17.9 deg C 1 05/06/24 15:12 Static Water Level 51.82 feet 1 05/06/24 15:12 Specific Conductance 182.1 umhos/c 1 05/06/24 15:12 m Oxidation Potential 92.1 my 1 05/06/24 15:12 Oxygen, Dissolved 2.15 mg/L 1 05/06/24 15:12 7782-44-7 Total Well Depth 63.60 feet 1 05/06/24 15:12 Turbidity 0.46 NTU 1 05/06/24 15:12 Chlorinated Herb. (GC) 8151 Analytical Method: EPA8151 Preparation Method: 8151A Pace National - Mt. Juliet 2,4-D ND mg/L 0.00200 0.000547 1 05/09/24 01:21 05/14/24 01:12 94-75-7 Dinoseb ND mg/L 0.00200 0.000250 1 05/09/24 01:21 05/14/24 01:12 88-85-7 2,4,5-T ND mg/L 0.00200 0.000258 1 05/09/24 01:21 05/14/24 01:12 93-76-5 2,4,5-TP (Silvex) ND mg/L 0.00200 0.000335 1 05/09/24 01:21 05/14/24 01:12 93-72-1 Surrogates 2,4-DCAA (S) 87.7 % 14.0- 1 05/09/24 01:21 05/14/24 01:12 19719-28-9 158 8011 GCS EDB and DBCP Analytical Method: EPA 8011 Preparation Method: EPA 8011 Pace Analytical Services - Charlotte 1,2-Dibromo-3- ND ug/L 0.20 0.0041 1 05/14/24 09:31 05/14/24 20:44 96-12-8 chloropropane 1,2-Dibromoethane (EDB) ND ug/L 0.050 0.0076 1 05/14/24 09:31 05/14/24 20:44 106-93-4 Surrogates 1-Chloro-2-bromopropane 101 % 60-140 1 05/14/24 09:31 05/14/24 20:44 301-79-56 (S) 8081 OC Pesticides RVE Analytical Method: EPA 8081 B Preparation Method: EPA 3510C Pace Analytical Services - Charlotte Aldrin ND ug/L 0.042 0.012 1 05/09/24 04:10 05/09/24 17:54 309-00-2 alpha-BHC ND ug/L 0.042 0.010 1 05/09/24 04:10 05/09/24 17:54 319-84-6 beta-BHC ND ug/L 0.042 0.041 1 05/09/24 04:10 05/09/24 17:54 319-85-7 delta-BHC ND ug/L 0.042 0.012 1 05/09/24 04:10 05/09/24 17:54 319-86-8 gamma-BHC (Lindane) ND ug/L 0.042 0.010 1 05/09/24 04:10 05/09/24 17:54 58-89-9 Chlordane (Technical) ND ug/L 0.42 0.13 1 05/09/24 04:10 05/09/24 17:54 57-74-9 4,4'-DDD ND ug/L 0.042 0.014 1 05/09/24 04:10 05/09/24 17:54 72-54-8 4,4'-DDE ND ug/L 0.042 0.020 1 05/09/24 04:10 05/09/24 17:54 72-55-9 4,4'-DDT ND ug/L 0.042 0.022 1 05/09/24 04:10 05/09/24 17:54 50-29-3 Dieldrin ND ug/L 0.042 0.012 1 05/09/24 04:10 05/09/24 17:54 60-57-1 Endosulfan I ND ug/L 0.042 0.014 1 05/09/24 04:10 05/09/24 17:54 959-98-8 Endosulfan II ND ug/L 0.042 0.013 1 05/09/24 04:10 05/09/24 17:54 33213-65-9 Endosulfan sulfate ND ug/L 0.042 0.012 1 05/09/24 04:10 05/09/24 17:54 1031-07-8 Endrin ND ug/L 0.042 0.015 1 05/09/24 04:10 05/09/24 17:54 72-20-8 Date: 05/20/2024 04:49 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 Page 6 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 Sample: 1403-MW-2R Lab ID: 92729134001 Collected: 05/06/24 15:12 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8081 OC Pesticides RVE Analytical Method: EPA 8081 B Preparation Method: EPA 3510C Pace Analytical Services - Charlotte Endrin aldehyde ND ug/L 0.042 0.014 1 05/09/24 04:10 05/09/24 17:54 7421-93-4 Heptachlor ND ug/L 0.042 0.016 1 05/09/24 04:10 05/09/24 17:54 76-44-8 Heptachlor epoxide ND ug/L 0.042 0.024 1 05/09/24 04:10 05/09/24 17:54 1024-57-3 Methoxychlor ND ug/L 0.12 0.035 1 05/09/24 04:10 05/09/24 17:54 72-43-5 Toxaphene ND ug/L 0.42 0.18 1 05/09/24 04:10 05/09/24 17:54 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 78 % 10-137 1 05/09/24 04:10 05/09/24 17:54 877-09-8 Decachlorobiphenyl (S) 110 % 19-200 1 05/09/24 04:10 05/09/24 17:54 2051-24-3 8082 GCS PCB RVE Analytical Method: EPA 8082A Preparation Method: EPA 3510C Pace Analytical Services - Charlotte PCB-1016 (Aroclor 1016) ND ug/L 0.42 0.18 1 05/08/24 22:41 05/10/24 00:58 12674-11-2 PCB-1221 (Aroclor 1221) ND ug/L 0.42 0.19 1 05/08/24 22:41 05/10/24 00:58 11104-28-2 PCB-1232 (Aroclor 1232) ND ug/L 0.42 0.19 1 05/08/24 22:41 05/10/24 00:58 11141-16-5 PCB-1242 (Aroclor 1242) ND ug/L 0.42 0.21 1 05/08/24 22:41 05/10/24 00:58 53469-21-9 PCB-1248 (Aroclor 1248) ND ug/L 0.42 0.24 1 05/08/24 22:41 05/10/24 00:58 12672-29-6 PCB-1254 (Aroclor 1254) ND ug/L 0.42 0.18 1 05/08/24 22:41 05/10/24 00:58 11097-69-1 PCB-1260 (Aroclor 1260) ND ug/L 0.42 0.13 1 05/08/24 22:41 05/10/24 00:58 11096-82-5 R1 Surrogates Decachlorobiphenyl (S) 116 % 10-193 1 05/08/24 22:41 05/10/24 00:58 2051-24-3 6020 MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.54 1 05/09/2413:41 05/13/2418:54 7440-36-0 Arsenic ND ug/L 10.0 0.84 1 05/09/2413:41 05/13/2418:54 7440-38-2 Barium 403 ug/L 100 0.47 1 05/09/2413:41 05/13/2418:54 7440-39-3 Beryllium 0.18J ug/L 1.0 0.094 1 05/09/2413:41 05/13/2418:54 7440-41-7 Cadmium ND ug/L 1.0 0.10 1 05/09/2413:41 05/13/2418:54 7440-43-9 Chromium ND ug/L 10.0 1.9 1 05/09/2413:41 05/13/2418:54 7440-47-3 Cobalt ND ug/L 10.0 0.32 1 05/09/2413:41 05/13/2418:54 7440-48-4 Copper 0.44J ug/L 10.0 0.43 1 05/09/2413:41 05/13/2418:54 7440-50-8 Lead ND ug/L 10.0 0.16 1 05/09/2413:41 05/13/2418:54 7439-92-1 Nickel ND ug/L 50.0 2.1 1 05/09/2413:41 05/13/2418:54 7440-02-0 Selenium ND ug/L 10.0 0.96 1 05/09/2413:41 05/13/2418:54 7782-49-2 Silver ND ug/L 10.0 0.31 1 05/09/2413:41 05/13/2418:54 7440-22-4 Thallium ND ug/L 5.5 0.38 1 05/09/2413:41 05/13/2418:54 7440-28-0 Tin ND ug/L 20.0 1.2 1 05/09/2413:41 05/13/2418:54 7440-31-5 Vanadium ND ug/L 25.0 0.75 1 05/09/2413:41 05/13/2418:54 7440-62-2 Zinc ND ug/L 10.0 2.4 1 05/09/2413:41 05/13/2418:54 7440-66-6 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services - Peachtree Corners, GA Mercury ND ug/L 0.20 0.13 1 05/13/2411:20 05/13/2415:49 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 Sample: 1403-MW-2R Lab ID: 92729134001 Collected: 05/06/24 15:12 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte Acenaphthene ND ug/L 8.3 1.7 1 05/08/24 22:36 05/09/24 13:25 83-32-9 Acenaphthylene ND ug/L 8.3 1.6 1 05/08/24 22:36 05/09/24 13:25 208-96-8 Acetophenone ND ug/L 8.3 1.2 1 05/08/24 22:36 05/09/24 13:25 98-86-2 2-Acetylaminofluorene ND ug/L 8.3 3.4 1 05/08/24 22:36 05/09/24 13:25 53-96-3 4-Aminobiphenyl ND ug/L 8.3 4.0 1 05/08/24 22:36 05/09/24 13:25 92-67-1 Anthracene ND ug/L 8.3 1.9 1 05/08/24 22:36 05/09/24 13:25 120-12-7 Benzo(a)anthracene ND ug/L 8.3 2.2 1 05/08/24 22:36 05/09/24 13:25 56-55-3 Benzo(a)pyrene ND ug/L 8.3 2.3 1 05/08/24 22:36 05/09/24 13:25 50-32-8 Benzo(b)fluoranthene ND ug/L 8.3 2.2 1 05/08/24 22:36 05/09/24 13:25 205-99-2 Benzo(g,h,i)perylene ND ug/L 8.3 2.4 1 05/08/24 22:36 05/09/24 13:25 191-24-2 Benzo(k)fluoranthene ND ug/L 8.3 2.3 1 05/08/24 22:36 05/09/24 13:25 207-08-9 Benzoic Acid ND ug/L 41.7 18.3 1 05/08/24 22:36 05/09/24 13:25 65-85-0 v1 Benzyl alcohol ND ug/L 16.7 2.4 1 05/08/24 22:36 05/09/24 13:25 100-51-6 4-Bromophenylphenyl ND ug/L 8.3 1.5 1 05/08/24 22:36 05/09/24 13:25 101-55-3 ether Butylbenzylphthalate ND ug/L 8.3 2.6 1 05/08/24 22:36 05/09/24 13:25 85-68-7 Carbazole ND ug/L 8.3 2.0 1 05/08/24 22:36 05/09/24 13:25 86-74-8 4-ChIoro-3-methyl phenol ND ug/L 8.3 2.8 1 05/08/24 22:36 05/09/24 13:25 59-50-7 4-Chloroaniline ND ug/L 16.7 3.0 1 05/08/24 22:36 05/09/24 13:25 106-47-8 Chlorobenzilate ND ug/L 8.3 3.2 1 05/08/24 22:36 05/09/24 13:25 510-15-6 bis(2- ND ug/L 8.3 1.5 1 05/08/24 22:36 05/09/24 13:25 111-91-1 Chloroethoxy)methane bis(2-Chloroethyl) ether ND ug/L 8.3 1.6 1 05/08/24 22:36 05/09/24 13:25 111-44-4 2-Chloronaphthalene ND ug/L 8.3 1.4 1 05/08/24 22:36 05/09/24 13:25 91-58-7 2-Chlorophenol ND ug/L 8.3 1.0 1 05/08/24 22:36 05/09/24 13:25 95-57-8 4-Chlorophenylphenyl ND ug/L 8.3 1.7 1 05/08/24 22:36 05/09/24 13:25 7005-72-3 ether Chrysene ND ug/L 8.3 2.3 1 05/08/24 22:36 05/09/24 13:25 218-01-9 Diallate ND ug/L 8.3 2.8 1 05/08/24 22:36 05/09/24 13:25 2303-16-4 Dibenz(a,h)anthracene ND ug/L 8.3 2.5 1 05/08/24 22:36 05/09/24 13:25 53-70-3 Dibenzofuran ND ug/L 8.3 1.8 1 05/08/24 22:36 05/09/24 13:25 132-64-9 1,2-Dichlorobenzene ND ug/L 8.3 1.5 1 05/08/24 22:36 05/09/24 13:25 95-50-1 1,3-Dichlorobenzene ND ug/L 8.3 1.3 1 05/08/24 22:36 05/09/24 13:25 541-73-1 1,4-Dichlorobenzene 1.7J ug/L 8.3 1.4 1 05/08/24 22:36 05/09/24 13:25 106-46-7 3,3'-Dichlorobenzidine ND ug/L 16.7 6.8 1 05/08/24 22:36 05/09/24 13:25 91-94-1 2,4-Dichlorophenol ND ug/L 8.3 1.2 1 05/08/24 22:36 05/09/24 13:25 120-83-2 Diethylphthalate ND ug/L 8.3 1.7 1 05/08/24 22:36 05/09/24 13:25 84-66-2 Dimethoate ND ug/L 8.3 3.0 1 05/08/24 22:36 05/09/24 13:25 60-51-5 P- ND ug/L 4.2 2.0 1 05/08/24 22:36 05/09/24 13:25 60-11-7 Dimethylaminoazobenzen e 7,12- ND ug/L 8.3 2.5 1 05/08/24 22:36 05/09/24 13:25 57-97-6 Dimethylbenz(a)anthracen e 3,3'-Dimethylbenzidine ND ug/L 41.7 25.9 1 05/08/24 22:36 05/09/24 13:25 119-93-7 2,4-Dimethylphenol ND ug/L 8.3 1.4 1 05/08/24 22:36 05/09/24 13:25 105-67-9 Dimethylphthalate ND ug/L 8.3 1.8 1 05/08/24 22:36 05/09/24 13:25 131-11-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 Sample: 1403-MW-2R Lab ID: 92729134001 Collected: 05/06/24 15:12 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8270E APP9 RV Di-n-butylphthalate 4,6-Dinitro-2-methyl phenol 1,3-Dinitrobenzene 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene Di-n-octylphthalate bis(2- Ethyl hexyl)phthalate Ethyl methanesulfonate Famphur Fluoranthene Fluorene Hexachloro-1,3-butadiene Hexachlorobenzene Hexachlorocyclopentadien e Hexachloroethane Hexachloropropene Indeno(1,2,3-cd)pyrene Isodrin Isophorone Isosafrole Kepone Methapyrilene 3-Methylcholanthrene Methyl methanesulfonate 2-Methylnaphthalene Methyl parathion 2-Methylphenol(o-Cresol) 3&4-Methyl phenol (m&p Cresol) 1-Naphthalenamine 2-Naphthalenamine Naphthalene 1,4-Naphthoquinone 2-Nitroaniline 3-Nitroaniline 4-Nitroaniline Nitrobenzene 2-Nitrophenol 4-Nitrophenol 5-Nitro-o-toluidine N-Nitrosodiethylamine N-Nitrosodimethylamine N-Nitroso-di-n-butylamine Date: 05/20/2024 04:49 PM Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte ND ug/L 8.3 1.8 1 05/08/24 22:36 05/09/24 13:25 84-74-2 ND ug/L 16.7 6.5 1 05/08/24 22:36 05/09/24 13:25 534-52-1 ND ug/L 8.3 3.1 1 05/08/24 22:36 05/09/24 13:25 99-65-0 ND ug/L 41.7 21.7 1 05/08/24 22:36 05/09/24 13:25 51-28-5 ND ug/L 8.3 1.4 1 05/08/24 22:36 05/09/24 13:25 121-14-2 ND ug/L 8.3 1.4 1 05/08/24 22:36 05/09/24 13:25 606-20-2 ND ug/L 8.3 3.3 1 05/08/24 22:36 05/09/24 13:25 117-84-0 ND ug/L 5.0 3.1 1 05/08/24 22:36 05/09/24 13:25 117-81-7 ND ug/L 16.7 2.5 1 05/08/24 22:36 05/09/24 13:25 62-50-0 ND ug/L 8.3 5.1 1 05/08/24 22:36 05/09/24 13:25 52-85-7 ND ug/L 8.3 1.8 1 05/08/24 22:36 05/09/24 13:25 206-44-0 ND ug/L 8.3 1.7 1 05/08/24 22:36 05/09/24 13:25 86-73-7 ND ug/L 8.3 1.5 1 05/08/24 22:36 05/09/24 13:25 87-68-3 ND ug/L 8.3 1.8 1 05/08/24 22:36 05/09/24 13:25 118-74-1 ND ug/L 8.3 1.3 1 05/08/24 22:36 05/09/24 13:25 77-47-4 ND ug/L 8.3 1.2 1 05/08/24 22:36 05/09/24 13:25 67-72-1 ND ug/L 8.3 2.2 1 05/08/24 22:36 05/09/24 13:25 1888-71-7 ND ug/L 8.3 2.4 1 05/08/24 22:36 05/09/24 13:25 193-39-5 ND ug/L 8.3 2.3 1 05/08/24 22:36 05/09/24 13:25 465-73-6 ND ug/L 8.3 1.4 1 05/08/24 22:36 05/09/24 13:25 78-59-1 ND ug/L 8.3 2.1 1 05/08/24 22:36 05/09/24 13:25 120-58-1 ND ug/L 16.7 11.8 1 05/08/24 22:36 05/09/24 13:25 143-50-0 ND ug/L 41.7 14.2 1 05/08/24 22:36 05/09/24 13:25 91-80-5 ND ug/L 8.3 3.1 1 05/08/24 22:36 05/09/24 13:25 56-49-5 ND ug/L 4.2 2.6 1 05/08/24 22:36 05/09/24 13:25 66-27-3 ND ug/L 8.3 1.6 1 05/08/24 22:36 05/09/24 13:25 91-57-6 ND ug/L 8.3 3.1 1 05/08/24 22:36 05/09/24 13:25 298-00-0 ND ug/L 8.3 1.6 1 05/08/24 22:36 05/09/24 13:25 95-48-7 ND ug/L 8.3 1.0 1 05/08/24 22:36 05/09/24 13:25 15831-10-4 ND ug/L 8.3 5.0 1 05/08/24 22:36 05/09/24 13:25 134-32-7 ND ug/L 8.3 4.5 1 05/08/24 22:36 05/09/24 13:25 91-59-8 ND ug/L 8.3 1.7 1 05/08/24 22:36 05/09/24 13:25 91-20-3 ND ug/L 4.2 3.7 1 05/08/24 22:36 05/09/24 13:25 130-15-4 ND ug/L 16.7 2.5 1 05/08/24 22:36 05/09/24 13:25 88-74-4 ND ug/L 16.7 3.1 1 05/08/24 22:36 05/09/24 13:25 99-09-2 ND ug/L 16.7 4.2 1 05/08/24 22:36 05/09/24 13:25 100-01-6 ND ug/L 8.3 1.6 1 05/08/24 22:36 05/09/24 13:25 98-95-3 ND ug/L 8.3 1.2 1 05/08/24 22:36 05/09/24 13:25 88-75-5 ND ug/L 41.7 5.5 1 05/08/24 22:36 05/09/24 13:25 100-02-7 ND ug/L 8.3 3.2 1 05/08/24 22:36 05/09/24 13:25 99-55-8 ND ug/L 8.3 1.9 1 05/08/24 22:36 05/09/24 13:25 55-18-5 ND ug/L 8.3 1.6 1 05/08/24 22:36 05/09/24 13:25 62-75-9 ND ug/L 8.3 1.6 1 05/08/24 22:36 05/09/24 13:25 924-16-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v1 Page 9 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 Sample: 1403-MW-2R Lab ID: 92729134001 Collected: 05/06/24 15:12 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8270E APP9 RV N-Nitroso-di-n- propylamine N-Nitrosodiphenylamine N- Nitrosomethylethylamine N-Nitrosomorpholine N-Nitrosopiperidine N-Nitrosopyrrolidine O,O,O- Tri ethyl phosphorothioate 2,2'-Oxybis(1- chloropropane) Parathion (Ethyl parathion) Pentachlorobenzene Pentachloronitrobenzene Pentachlorophenol Phenacetin Phenanthrene Phenol p-Phenylenediamine Phorate Pronamide Pyrene Pyridine Safrole 1,2,4,5- Tetrachlorobenzene 2,3,4,6-Tetrachlorophenol Thionazin O-Toluidine 1,2,4-Trichlorobenzene 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol 1,3,5-Trinitrobenzene Surrogates Nitrobenzene-d5 (S) 2-Fluorobiphenyl (S) Terphenyl-d14 (S) Phenol-d6 (S) 2-Fluorophenol (S) 2,4,6-Tribromophenol (S) 8260D MSV Low Level Landfill Acetone Acetonitrile Date: 05/20/2024 04:49 PM Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte ND ug/L 8.3 1.1 1 05/08/24 22:36 05/09/24 13:25 621-64-7 ND ug/L 8.3 2.5 1 05/08/24 22:36 05/09/24 13:25 86-30-6 ND ug/L 8.3 6.2 1 05/08/24 22:36 05/09/24 13:25 10595-95-6 ND ug/L 8.3 3.5 1 05/08/24 22:36 05/09/24 13:25 59-89-2 ND ug/L 8.3 2.1 1 05/08/24 22:36 05/09/24 13:25 100-75-4 ND ug/L 8.3 2.6 1 05/08/24 22:36 05/09/24 13:25 930-55-2 ND ug/L 8.3 2.1 1 05/08/24 22:36 05/09/24 13:25 126-68-1 ND ug/L 8.3 0.96 1 05/08/24 22:36 05/09/24 13:25 108-60-1 ND ug/L 8.3 3.2 1 05/08/24 22:36 05/09/24 13:25 56-38-2 ND ug/L 8.3 2.8 1 05/08/24 22:36 05/09/24 13:25 608-93-5 ND ug/L 8.3 2.7 1 05/08/24 22:36 05/09/24 13:25 82-68-8 ND ug/L 16.7 3.1 1 05/08/24 22:36 05/09/24 13:25 87-86-5 ND ug/L 8.3 3.0 1 05/08/24 22:36 05/09/24 13:25 62-44-2 ND ug/L 8.3 1.7 1 05/08/24 22:36 05/09/24 13:25 85-01-8 ND ug/L 8.3 1.1 1 05/08/24 22:36 05/09/24 13:25 108-95-2 ND ug/L 8.3 8.3 1 05/08/24 22:36 05/09/24 13:25 106-50-3 ND ug/L 8.3 3.0 1 05/08/24 22:36 05/09/24 13:25 298-02-2 ND ug/L 8.3 2.6 1 05/08/24 22:36 05/09/24 13:25 23950-58-5 ND ug/L 8.3 1.8 1 05/08/24 22:36 05/09/24 13:25 129-00-0 ND ug/L 8.3 2.2 1 05/08/24 22:36 05/09/24 13:25 110-86-1 ND ug/L 8.3 1.9 1 05/08/24 22:36 05/09/24 13:25 94-59-7 ND ug/L 8.3 3.7 1 05/08/24 22:36 05/09/24 13:25 95-94-3 ND ug/L 8.3 1.3 1 05/08/24 22:36 05/09/24 13:25 58-90-2 ND ug/L 8.3 2.4 1 05/08/24 22:36 05/09/24 13:25 297-97-2 ND ug/L 8.3 2.2 1 05/08/24 22:36 05/09/24 13:25 95-53-4 ND ug/L 8.3 1.4 1 05/08/24 22:36 05/09/24 13:25 120-82-1 ND ug/L 8.3 1.2 1 05/08/24 22:36 05/09/24 13:25 95-95-4 ND ug/L 8.3 1.3 1 05/08/24 22:36 05/09/24 13:25 88-06-2 ND ug/L 8.3 4.6 1 05/08/24 22:36 05/09/24 13:25 99-35-4 111 % 10-133 1 05/08/24 22:36 05/09/24 13:25 4165-60-0 91 % 10-130 1 05/08/24 22:36 05/09/24 13:25 321-60-8 132 % 10-193 1 05/08/24 22:36 05/09/24 13:25 1718-51-0 59 % 10-130 1 05/08/24 22:36 05/09/24 13:25 13127-88-3 80 % 10-130 1 05/08/24 22:36 05/09/24 13:25 367-12-4 110 % 10-166 1 05/08/24 22:36 05/09/24 13:25 118-79-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 100 5.1 1 05/09/24 04:20 67-64-1 ND ug/L 50.0 24.8 1 05/09/24 04:20 75-05-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v1 v1 v1 Page 10 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 Sample: 1403-MW-2R Lab ID: 92729134001 Collected: 05/06/24 15:12 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acrolein Acrylonitrile Allyl chloride Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Chloroprene Dibromochloromethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene Ethyl methacrylate 2-Hexanone lodomethane Isobutanol Methacrylonitrile Methylene Chloride Methyl methacrylate 4-Methyl-2-pe n to n o n e (MIBK) Propionitrile Date: 05/20/2024 04:49 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 50.0 8.5 1 05/09/24 04:20 107-02-8 ND ug/L 200 1.8 1 05/09/24 04:20 107-13-1 ND ug/L 10.0 0.50 1 05/09/24 04:20 107-05-1 3.5 ug/L 1.0 0.34 1 05/09/24 04:20 71-43-2 ND ug/L 3.0 0.47 1 05/09/24 04:20 74-97-5 ND ug/L 1.0 0.31 1 05/09/24 04:20 75-27-4 ND ug/L 3.0 0.34 1 05/09/24 04:20 75-25-2 ND ug/L 10.0 1.7 1 05/09/24 04:20 74-83-9 ND ug/L 100 4.0 1 05/09/24 04:20 78-93-3 ND ug/L 100 0.36 1 05/09/24 04:20 75-15-0 ND ug/L 1.0 0.33 1 05/09/24 04:20 56-23-5 0.49J ug/L 3.0 0.28 1 05/09/24 04:20 108-90-7 ND ug/L 10.0 0.65 1 05/09/24 04:20 75-00-3 ND ug/L 5.0 0.43 1 05/09/24 04:20 67-66-3 ND ug/L 1.0 0.54 1 05/09/24 04:20 74-87-3 ND ug/L 10.0 1.6 1 05/09/24 04:20 126-99-8 ND ug/L 3.0 0.36 1 05/09/24 04:20 124-48-1 ND ug/L 10.0 0.39 1 05/09/24 04:20 74-95-3 ND ug/L 5.0 0.34 1 05/09/24 04:20 95-50-1 ND ug/L 1.0 0.34 1 05/09/24 04:20 541-73-1 2.8 ug/L 1.0 0.33 1 05/09/24 04:20 106-46-7 ND ug/L 100 0.56 1 05/09/24 04:20 110-57-6 ND ug/L 1.0 0.35 1 05/09/24 04:20 75-71-8 0.80J ug/L 5.0 0.37 1 05/09/24 04:20 75-34-3 ND ug/L 1.0 0.32 1 05/09/24 04:20 107-06-2 ND ug/L 5.0 0.35 1 05/09/24 04:20 75-35-4 4.OJ ug/L 5.0 0.38 1 05/09/24 04:20 156-59-2 ND ug/L 5.0 0.40 1 05/09/24 04:20 156-60-5 ND ug/L 1.0 0.36 1 05/09/24 04:20 78-87-5 ND ug/L 1.0 0.28 1 05/09/24 04:20 142-28-9 ND ug/L 1.0 0.39 1 05/09/24 04:20 594-20-7 ND ug/L 1.0 0.43 1 05/09/24 04:20 563-58-6 ND ug/L 1.0 0.36 1 05/09/24 04:20 10061-01-5 ND ug/L 1.0 0.36 1 05/09/24 04:20 10061-02-6 ND ug/L 1.0 0.30 1 05/09/24 04:20 100-41-4 ND ug/L 10.0 0.28 1 05/09/24 04:20 97-63-2 ND ug/L 50.0 0.48 1 05/09/24 04:20 591-78-6 ND ug/L 20.0 9.7 1 05/09/24 04:20 74-88-4 ND ug/L 100 52.3 1 05/09/24 04:20 78-83-1 ND ug/L 10.0 4.2 1 05/09/24 04:20 126-98-7 ND ug/L 5.0 2.0 1 05/09/24 04:20 75-09-2 ND ug/L 10.0 0.32 1 05/09/24 04:20 80-62-6 ND ug/L 100 2.7 1 05/09/24 04:20 108-10-1 ND ug/L 20.0 3.6 1 05/09/24 04:20 107-12-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 11 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 Sample: 1403-MW-2R Lab ID: 92729134001 Collected: 05/06/24 15:12 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Styrene ND ug/L 1.0 0.29 1 05/09/24 04:20 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 5.0 0.31 1 05/09/24 04:20 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 3.0 0.22 1 05/09/24 04:20 79-34-5 Tetrachloroethene ND ug/L 1.0 0.29 1 05/09/24 04:20 127-18-4 Toluene ND ug/L 1.0 0.24 1 05/09/24 04:20 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.33 1 05/09/24 04:20 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.32 1 05/09/24 04:20 79-00-5 Trichloroethene ND ug/L 1.0 0.38 1 05/09/24 04:20 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.30 1 05/09/24 04:20 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.26 1 05/09/24 04:20 96-18-4 Vinyl acetate ND ug/L 50.0 1.3 1 05/09/24 04:20 108-05-4 Vinyl chloride 0.63J ug/L 1.0 0.39 1 05/09/24 04:20 75-01-4 Xylene (Total) 4.3J ug/L 5.0 0.34 1 05/09/24 04:20 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 98 % 70-130 1 05/09/24 04:20 460-00-4 1,2-Dichloroethane-d4 (S) 97 % 70-130 1 05/09/24 04:20 17060-07-0 Toluene-d8 (S) 102 % 70-130 1 05/09/24 04:20 2037-26-5 4500S2D Sulfide Water Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville Sulfide ND mg/L 0.10 0.022 1 05/09/24 04:51 18496-25-8 4500CNE Cyanide, Total Analytical Method: SM 4500-CN-E-2016 Preparation Method: SM 4500-CN-E-2016 Pace Analytical Services -Asheville Cyanide ND mg/L 0.0080 0.0060 1 05/13/24 21:00 05/14/24 17:34 57-12-5 Date: 05/20/2024 04:49 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. CO Page 12 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 Sample: 1403-Trip Blank Lab ID: 92729134002 Collected: 05/05/24 15:34 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8011 GCS EDB and DBCP 1,2-Dibromo-3- chloropropane 1,2-Dibromoethane (EDB) Surrogates 1-Chloro-2-bromopropane (S) 8260D MSV Low Level Landfill Acetone Acetonitrile Acrolein Acrylonitrile Allyl chloride Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Chloroprene Dibromochloromethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Date: 05/20/2024 04:49 PM Analytical Method: EPA 8011 Preparation Method: EPA 8011 Pace Analytical Services - Charlotte ND ug/L 0.20 0.0040 1 05/14/24 09:31 05/14/24 20:55 96-12-8 ND ug/L 0.049 0.0074 1 05/14/24 09:31 05/14/24 20:55 106-93-4 102 % 60-140 1 05/14/24 09:31 05/14/24 20:55 301-79-56 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 100 5.1 1 05/09/24 03:07 67-64-1 ND ug/L 50.0 24.8 1 05/09/24 03:07 75-05-8 ND ug/L 50.0 8.5 1 05/09/24 03:07 107-02-8 ND ug/L 200 1.8 1 05/09/24 03:07 107-13-1 ND ug/L 10.0 0.50 1 05/09/24 03:07 107-05-1 ND ug/L 1.0 0.34 1 05/09/24 03:07 71-43-2 ND ug/L 3.0 0.47 1 05/09/24 03:07 74-97-5 ND ug/L 1.0 0.31 1 05/09/24 03:07 75-27-4 ND ug/L 3.0 0.34 1 05/09/24 03:07 75-25-2 ND ug/L 10.0 1.7 1 05/09/24 03:07 74-83-9 ND ug/L 100 4.0 1 05/09/24 03:07 78-93-3 ND ug/L 100 0.36 1 05/09/24 03:07 75-15-0 ND ug/L 1.0 0.33 1 05/09/24 03:07 56-23-5 ND ug/L 3.0 0.28 1 05/09/24 03:07 108-90-7 ND ug/L 10.0 0.65 1 05/09/24 03:07 75-00-3 ND ug/L 5.0 0.43 1 05/09/24 03:07 67-66-3 ND ug/L 1.0 0.54 1 05/09/24 03:07 74-87-3 ND ug/L 10.0 1.6 1 05/09/24 03:07 126-99-8 ND ug/L 3.0 0.36 1 05/09/24 03:07 124-48-1 ND ug/L 10.0 0.39 1 05/09/24 03:07 74-95-3 ND ug/L 5.0 0.34 1 05/09/24 03:07 95-50-1 ND ug/L 1.0 0.34 1 05/09/24 03:07 541-73-1 ND ug/L 1.0 0.33 1 05/09/24 03:07 106-46-7 ND ug/L 100 0.56 1 05/09/24 03:07 110-57-6 ND ug/L 1.0 0.35 1 05/09/24 03:07 75-71-8 ND ug/L 5.0 0.37 1 05/09/24 03:07 75-34-3 ND ug/L 1.0 0.32 1 05/09/24 03:07 107-06-2 ND ug/L 5.0 0.35 1 05/09/24 03:07 75-35-4 ND ug/L 5.0 0.38 1 05/09/24 03:07 156-59-2 ND ug/L 5.0 0.40 1 05/09/24 03:07 156-60-5 ND ug/L 1.0 0.36 1 05/09/24 03:07 78-87-5 ND ug/L 1.0 0.28 1 05/09/24 03:07 142-28-9 ND ug/L 1.0 0.39 1 05/09/24 03:07 594-20-7 ND ug/L 1.0 0.43 1 05/09/24 03:07 563-58-6 ND ug/L 1.0 0.36 1 05/09/24 03:07 10061-01-5 ND ug/L 1.0 0.36 1 05/09/24 03:07 10061-02-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 13 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 Sample: 1403-Trip Blank Lab ID: 92729134002 Collected: 05/05/24 15:34 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Ethylbenzene Ethyl methacrylate 2-Hexanone lodomethane Isobutanol Methacrylonitrile Methylene Chloride Methyl methacrylate 4-Methyl-2-pe n to n o n e (MIBK) Propionitrile Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/20/2024 04:49 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.30 1 05/09/24 03:07 100-41-4 ND ug/L 10.0 0.28 1 05/09/24 03:07 97-63-2 ND ug/L 50.0 0.48 1 05/09/24 03:07 591-78-6 ND ug/L 20.0 9.7 1 05/09/24 03:07 74-88-4 ND ug/L 100 52.3 1 05/09/24 03:07 78-83-1 ND ug/L 10.0 4.2 1 05/09/24 03:07 126-98-7 ND ug/L 5.0 2.0 1 05/09/24 03:07 75-09-2 ND ug/L 10.0 0.32 1 05/09/24 03:07 80-62-6 ND ug/L 100 2.7 1 05/09/24 03:07 108-10-1 ND ug/L 20.0 3.6 1 05/09/24 03:07 107-12-0 ND ug/L 1.0 0.29 1 05/09/24 03:07 100-42-5 ND ug/L 5.0 0.31 1 05/09/24 03:07 630-20-6 ND ug/L 3.0 0.22 1 05/09/24 03:07 79-34-5 ND ug/L 1.0 0.29 1 05/09/24 03:07 127-18-4 ND ug/L 1.0 0.24 1 05/09/24 03:07 108-88-3 ND ug/L 1.0 0.33 1 05/09/24 03:07 71-55-6 ND ug/L 1.0 0.32 1 05/09/24 03:07 79-00-5 ND ug/L 1.0 0.38 1 05/09/24 03:07 79-01-6 ND ug/L 1.0 0.30 1 05/09/24 03:07 75-69-4 ND ug/L 1.0 0.26 1 05/09/24 03:07 96-18-4 ND ug/L 50.0 1.3 1 05/09/24 03:07 108-05-4 ND ug/L 1.0 0.39 1 05/09/24 03:07 75-01-4 ND ug/L 5.0 0.34 1 05/09/24 03:07 1330-20-7 95 % 70-130 1 05/09/24 03:07 460-00-4 97 % 70-130 1 05/09/24 03:07 17060-07-0 102 % 70-130 1 05/09/24 03:07 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 QC Batch: 2282658 Analysis Method: EPA 8151 QC Batch Method: 8151A Analysis Description: Chlorinated Herb. (GC) 8151 Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92729134001 METHOD BLANK: R4069518-1 Matrix: Water Associated Lab Samples: 92729134001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 2,4-D mg/L ND 0.00200 0.000547 05/14/24 00:10 Dinoseb mg/L ND 0.00200 0.000250 05/14/24 00:10 2,4,5-T mg/L ND 0.00200 0.000258 05/14/24 00:10 2,4,5-TP (Silvex) mg/L ND 0.00200 0.000335 05/14/24 00:10 2,4-DCAA (S) % 74.8 14.0-158 05/14/24 00:10 LABORATORY CONTROL SAMPLE & LCSD: R4069518-2 R4069518-3 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 2,4-D mg/L 0.00250 0.00244 0.00245 97.6 98.0 50.0-120 0.409 20 Dinoseb mg/L 0.00250 0.00235 0.00236 94.0 94.4 36.0-134 0.425 20 2,4,5-T mg/L 0.00250 0.00240 0.00241 96.0 96.4 54.0-120 0.416 20 2,4,5-TP (Silvex) mg/L 0.00250 0.00226 0.00226 90.4 90.4 50.0-125 0.00 20 2,4-DCAA (S) % 89.8 87.8 14.0-158 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 QC Batch: 853375 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020 MET Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92729134001 METHOD BLANK: 4403689 Associated Lab Samples: 92729134001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 6.0 0.54 05/13/2417:52 Arsenic ug/L ND 10.0 0.84 05/13/2417:52 Barium ug/L ND 100 0.47 05/13/2417:52 Beryllium ug/L ND 1.0 0.094 05/13/2417:52 Cadmium ug/L ND 1.0 0.10 05/13/2417:52 Chromium ug/L ND 10.0 1.9 05/13/2417:52 Cobalt ug/L ND 10.0 0.32 05/13/2417:52 Copper ug/L ND 10.0 0.43 05/13/2417:52 Lead ug/L ND 10.0 0.16 05/13/2417:52 Nickel ug/L ND 50.0 2.1 05/13/2417:52 Selenium ug/L ND 10.0 0.96 05/13/2417:52 Silver ug/L ND 10.0 0.31 05/13/2417:52 Thallium ug/L ND 5.5 0.38 05/13/2417:52 Tin ug/L ND 20.0 1.2 05/13/2417:52 Vanadium ug/L ND 25.0 0.75 05/13/2417:52 Zinc ug/L ND 10.0 2.4 05/13/2417:52 LABORATORY CONTROL SAMPLE: Parameter 4403690 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 100 114 114 80-120 Arsenic ug/L 100 103 103 80-120 Barium ug/L 100 106 106 80-120 Beryllium ug/L 100 109 109 80-120 Cadmium ug/L 100 103 103 80-120 Chromium ug/L 100 105 105 80-120 Cobalt ug/L 100 101 101 80-120 Copper ug/L 100 101 101 80-120 Lead ug/L 100 108 108 80-120 Nickel ug/L 100 102 102 80-120 Selenium ug/L 100 104 104 80-120 Silver ug/L 100 103 103 80-120 Thallium ug/L 100 99.6 100 80-120 Tin ug/L 100 104 104 80-120 Vanadium ug/L 100 107 107 80-120 Zinc ug/L 100 104 104 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Foothills LF/Semi-Annual 92729134 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4403750 4403751 MS MSD 92729503007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 106 102 106 102 75-125 4 20 Arsenic ug/L 2.7J 100 100 103 105 100 102 75-125 2 20 Barium ug/L 60.9J 100 100 179 178 118 117 75-125 1 20 Beryllium ug/L 0.24J 100 100 110 107 110 107 75-125 3 20 Cadmium ug/L ND 100 100 108 110 108 110 75-125 1 20 Chromium ug/L 9.8J 100 100 121 119 112 109 75-125 2 20 Cobalt ug/L 3.6J 100 100 108 107 104 103 75-125 1 20 Copper ug/L 9.6J 100 100 116 114 106 104 75-125 2 20 Lead ug/L 3.6J 100 100 110 108 107 104 75-125 2 20 Nickel ug/L 4.2J 100 100 108 110 104 106 75-125 2 20 Selenium ug/L ND 100 100 101 101 101 101 75-125 0 20 Silver ug/L ND 100 100 103 100 103 100 75-125 2 20 Thallium ug/L ND 100 100 103 99.6 103 100 75-125 3 20 Tin ug/L ND 100 100 107 102 106 102 75-125 5 20 Vanadium ug/L 16.OJ 100 100 126 126 110 110 75-125 0 20 Zinc ug/L 19.5 100 100 130 132 110 113 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 QC Batch: 853706 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92729134001 METHOD BLANK: 4405413 Matrix: Water Associated Lab Samples: 92729134001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.20 0.13 05/13/2414:24 LABORATORY CONTROL SAMPLE: 4405414 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.4 95 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4405415 4405416 MS MSD 92728914001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.4 2.4 95 94 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 QC Batch: 853049 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92729134001, 92729134002 METHOD BLANK: 4402148 Associated Lab Samples: 92729134001, 92729134002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.31 05/09/24 01:55 1,1,1-Trichloroethane ug/L ND 1.0 0.33 05/09/24 01:55 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.22 05/09/24 01:55 1,1,2-Trichloroethane ug/L ND 1.0 0.32 05/09/24 01:55 1,1-Dichloroethane ug/L ND 5.0 0.37 05/09/24 01:55 1,1-Dichloroethene ug/L ND 5.0 0.35 05/09/24 01:55 1,1-Dichloropropene ug/L ND 1.0 0.43 05/09/24 01:55 1,2,3-Trichloropropane ug/L ND 1.0 0.26 05/09/24 01:55 1,2-Dichlorobenzene ug/L ND 5.0 0.34 05/09/24 01:55 1,2-Dichloroethane ug/L ND 1.0 0.32 05/09/24 01:55 1,2-Dichloropropane ug/L ND 1.0 0.36 05/09/24 01:55 1,3-Dichlorobenzene ug/L ND 1.0 0.34 05/09/24 01:55 1,3-Dichloropropane ug/L ND 1.0 0.28 05/09/24 01:55 1,4-Dichlorobenzene ug/L ND 1.0 0.33 05/09/24 01:55 2,2-Dichloropropane ug/L ND 1.0 0.39 05/09/24 01:55 2-Butanone (MEK) ug/L ND 100 4.0 05/09/24 01:55 2-Hexanone ug/L ND 50.0 0.48 05/09/24 01:55 4-Methyl-2-pentanone (MIBK) ug/L ND 100 2.7 05/09/24 01:55 Acetone ug/L ND 100 5.1 05/09/24 01:55 Acetonitrile ug/L ND 50.0 24.8 05/09/24 01:55 Acrolein ug/L ND 50.0 8.5 05/09/24 01:55 Acrylonitrile ug/L ND 200 1.8 05/09/24 01:55 Allyl chloride ug/L ND 10.0 0.50 05/09/24 01:55 Benzene ug/L ND 1.0 0.34 05/09/24 01:55 Bromochloromethane ug/L ND 3.0 0.47 05/09/24 01:55 Bromodichloromethane ug/L ND 1.0 0.31 05/09/24 01:55 Bromoform ug/L ND 3.0 0.34 05/09/24 01:55 Bromomethane ug/L ND 10.0 1.7 05/09/24 01:55 Carbon disulfide ug/L ND 100 0.36 05/09/24 01:55 Carbon tetrachloride ug/L ND 1.0 0.33 05/09/24 01:55 Chlorobenzene ug/L ND 3.0 0.28 05/09/24 01:55 Chloroethane ug/L ND 10.0 0.65 05/09/24 01:55 Chloroform ug/L ND 5.0 0.43 05/09/24 01:55 Chloromethane ug/L ND 1.0 0.54 05/09/24 01:55 Chloroprene ug/L ND 10.0 1.6 05/09/24 01:55 cis-1,2-Dichloroethene ug/L ND 5.0 0.38 05/09/24 01:55 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 05/09/24 01:55 Dibromochloromethane ug/L ND 3.0 0.36 05/09/24 01:55 Dibromomethane ug/L ND 10.0 0.39 05/09/24 01:55 Dichlorodifluoromethane ug/L ND 1.0 0.35 05/09/24 01:55 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 METHOD BLANK: 4402148 Associated Lab Samples: 92729134001, 92729134002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Ethyl methacrylate ug/L ND 10.0 0.28 05/09/24 01:55 Ethylbenzene ug/L ND 1.0 0.30 05/09/24 01:55 lodomethane ug/L ND 20.0 9.7 05/09/24 01:55 Isobutanol ug/L ND 100 52.3 05/09/24 01:55 Methacrylonitrile ug/L ND 10.0 4.2 05/09/24 01:55 Methyl methacrylate ug/L ND 10.0 0.32 05/09/24 01:55 Methylene Chloride ug/L ND 5.0 2.0 05/09/24 01:55 Propionitrile ug/L ND 20.0 3.6 05/09/24 01:55 Styrene ug/L ND 1.0 0.29 05/09/24 01:55 Tetrachloroethene ug/L ND 1.0 0.29 05/09/24 01:55 Toluene ug/L ND 1.0 0.24 05/09/24 01:55 trans-1,2-Dichloroethene ug/L ND 5.0 0.40 05/09/24 01:55 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 05/09/24 01:55 trans-1,4-Dichloro-2-butene ug/L ND 100 0.56 05/09/24 01:55 Trichloroethene ug/L ND 1.0 0.38 05/09/24 01:55 Trichlorofluoromethane ug/L ND 1.0 0.30 05/09/24 01:55 Vinyl acetate ug/L ND 50.0 1.3 05/09/24 01:55 Vinyl chloride ug/L ND 1.0 0.39 05/09/24 01:55 Xylene (Total) ug/L ND 5.0 0.34 05/09/24 01:55 1,2-Dichloroethane-d4 (S) % 98 70-130 05/09/24 01:55 4-Bromofluorobenzene (S) % 96 70-130 05/09/24 01:55 Toluene-d8 (S) % 102 70-130 05/09/24 01:55 LABORATORY CONTROL SAMPLE: Parameter 4402149 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 20 20.5 102 70-130 1,1,1-Trichloroethane ug/L 20 19.9 100 70-130 1,1,2,2-Tetrachloroethane ug/L 20 19.7 99 70-130 1,1,2-Trichloroethane ug/L 20 20.5 103 70-130 1,1-Dichloroethane ug/L 20 19.6 98 70-130 1,1-Dichloroethene ug/L 20 19.4 97 69-131 1,1-Dichloropropene ug/L 20 19.9 100 70-132 1,2,3-Trichloropropane ug/L 20 20.5 102 70-130 1,2-Dichlorobenzene ug/L 20 20.5 102 70-130 1,2-Dichloroethane ug/L 20 19.8 99 70-130 1,2-Dichloropropane ug/L 20 20.3 101 70-130 1,3-Dichlorobenzene ug/L 20 20.7 103 70-130 1,3-Dichloropropane ug/L 20 20.3 102 70-130 1,4-Dichlorobenzene ug/L 20 20.4 102 70-130 2,2-Dichloropropane ug/L 20 18.7 94 69-130 2-Butanone (MEK) ug/L 40 34.7J 87 67-133 2-Hexanone ug/L 40 40.6J 102 70-133 4-Methyl-2-pentanone (MIBK) ug/L 40 40.6J 102 70-130 Qualifiers v2 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 44 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 aceo Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 LABORATORY CONTROL SAMPLE: Parameter 4402149 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Acetone ug/L 40 37AJ 93 67-130 Acetonitrile ug/L 200 188 94 70-130 Acrolein ug/L 100 80.4 80 53-166 Acrylonitrile ug/L 100 91.6J 92 70-130 Allyl chloride ug/L 20 19.7 99 69-130 Benzene ug/L 20 20.4 102 70-130 Bromochloromethane ug/L 20 20.6 103 70-130 Bromodichloromethane ug/L 20 20.3 102 70-130 Bromoform ug/L 20 19.9 100 70-133 Bromomethane ug/L 20 19.4 97 41-148 Carbon disulfide ug/L 20 18.7J 94 70-131 Carbon tetrachloride ug/L 20 20.4 102 70-130 Chlorobenzene ug/L 20 20.4 102 70-130 Chloroethane ug/L 20 20.3 101 41-157 Chloroform ug/L 20 19.6 98 70-130 Chloromethane ug/L 20 19.3 97 59-141 Chloroprene ug/L 20 19.1 96 70-130 cis-1,2-Dichloroethene ug/L 20 19.1 96 70-130 cis-1,3-Dichloropropene ug/L 20 20.5 103 70-130 Dibromochloromethane ug/L 20 20.9 104 70-130 Dibromomethane ug/L 20 21.3 106 70-130 Dichlorodifluoromethane ug/L 20 22.1 111 54-147 Ethyl methacrylate ug/L 20 17.5 88 70-130 Ethylbenzene ug/L 20 20.6 103 70-130 lodomethane ug/L 40 32.8 82 57-140 Isobutanol ug/L 400 370 93 67-136 Methacrylonitrile ug/L 200 193 96 70-130 Methyl methacrylate ug/L 20 17.6 88 70-130 Methylene Chloride ug/L 20 18.9 94 62-130 Propionitrile ug/L 200 198 99 70-130 Styrene ug/L 20 21.4 107 70-130 Tetrachloroethene ug/L 20 21.4 107 70-130 Toluene ug/L 20 20.3 102 70-130 trans-1,2-Dichloroethene ug/L 20 19.1 96 70-130 trans- 1,3-Dichloropropene ug/L 20 20.7 103 70-130 trans-1,4-Dichloro-2-butene ug/L 20 11.7J 59 57-149 v3 Trichloroethene ug/L 20 20.9 104 70-130 Trichlorofluoromethane ug/L 20 20.0 100 57-130 Vinyl acetate ug/L 40 41.1J 103 70-141 Vinyl chloride ug/L 20 20.4 102 66-140 Xylene (Total) ug/L 60 63.0 105 70-130 1,2-Dichloroethane-d4 (S) % 100 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 MATRIX SPIKE SAMPLE: Parameter 1,1,1,2-Tetrachloroethane 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,1-Dichloropropene 1,2,3-Trichloropropane 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,3-Dichlorobenzene 1,3-Dichloropropane 1,4-Dichlorobenzene 2,2-Dichloropropane 2-Butanone (MEK) 2-Hexanone 4-Methyl-2-pentanone (MIBK) Acetone Acetonitrile Acrolein Acrylonitrile Allyl chloride Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Chloroprene cis-1,2-Dichloroethene cis-1,3-Dichloropropene Dibromochloromethane Dibromomethane Dichlorodifluoromethane Ethyl methacrylate Ethylbenzene lodomethane Isobutanol Methacrylonitrile Methyl methacrylate Methylene Chloride 4402150 Units ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L QUALITY CONTROL DATA 92729087017 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 20 23.0 115 70-146 ND 20 23.4 117 70-150 ND 20 22.0 110 66-144 ND 20 22.5 112 70-142 ND 20 22.8 114 68-150 ND 20 23.0 115 64-162 ND 20 23.3 117 70-160 ND 20 22.4 112 66-144 ND 20 21.8 109 70-142 ND 20 23.2 116 68-145 ND 20 23.2 116 70-144 ND 20 22.2 111 70-142 ND 20 22.6 113 70-141 ND 20 22.2 111 70-140 ND 20 22.9 114 58-160 ND 40 41.3J 103 57-156 ND 40 44.1J 110 62-153 ND 40 44.9J 112 65-144 ND 40 43.1 J 108 49-162 ND 200 215 108 69-145 ND 100 84.0 84 10-200 v3 ND 100 102J 102 59-155 ND 20 22.8 114 70-146 ND 20 23.2 116 68-144 ND 20 22.7 114 70-148 ND 20 22.9 115 70-141 ND 20 21.7 108 59-144 ND 20 24.0 120 23-190 ND 20 21.9J 110 64-160 ND 20 23.9 119 70-147 ND 20 22.4 112 70-143 ND 20 24.4 122 55-190 ND 20 22.2 111 67-148 ND 20 22.4 112 38-180 ND 20 22.4 112 70-148 ND 20 22.0 110 67-151 ND 20 21.7 108 70-142 ND 20 23.0 115 68-140 ND 20 23.0 115 70-142 ND 20 26.4 132 15-200 ND 20 19.5 98 68-139 ND 20 22.8 114 70-145 ND 40 34.8 87 37-160 v3 ND 400 406 101 53-152 ND 200 223 112 70-137 ND 20 19.5 97 69-134 ND 20 21.6 108 54-149 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 MATRIX SPIKE SAMPLE: Parameter 4402150 Units 92729087017 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers Propionitrile ug/L ND 200 219 110 70-136 Styrene ug/L ND 20 22.9 115 70-147 Tetrachloroethene ug/L ND 20 22.3 111 70-145 Toluene ug/L ND 20 22.7 113 65-146 trans-1,2-Dichloroethene ug/L ND 20 23.3 116 69-155 trans- 1,3-Dichloropropene ug/L ND 20 22.9 115 70-142 trans-1,4-Dichloro-2-butene ug/L ND 20 13.3J 66 39-149 v3 Trichloroethene ug/L ND 20 23.2 116 70-152 Trichlorofluoromethane ug/L ND 20 24.7 124 60-158 Vinyl acetate ug/L ND 40 45.3J 113 56-157 Vinyl chloride ug/L ND 20 24.1 120 51-178 Xylene (Total) ug/L ND 60 68.3 114 70-146 1,2-Dichloroethane-d4 (S) % 106 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 98 70-130 SAMPLE DUPLICATE: 4402151 Parameter Units 92729087018 Result Dup Result RPD Max RPD 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,1-Dichloropropene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,3-Dichlorobenzene ug/L ND ND 30 1,3-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 2,2-Dichloropropane ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Acetonitrile ug/L ND ND 30 Acrolein ug/L ND ND 30 v2 Acrylonitrile ug/L ND ND 30 Allyl chloride ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 SAMPLE DUPLICATE: 4402151 Parameter Units 92729087018 Result Dup Result Bromoform ug/L ND ND Bromomethane ug/L ND ND Carbon disulfide ug/L ND ND Carbon tetrachloride ug/L ND ND Chlorobenzene ug/L ND ND Chloroethane ug/L ND ND Chloroform ug/L ND ND Chloromethane ug/L ND ND Chloroprene ug/L ND ND cis-1,2-Dichloroethene ug/L ND ND cis-1,3-Dichloropropene ug/L ND ND Dibromochloromethane ug/L ND ND Dibromomethane ug/L ND ND Dichlorodifluoromethane ug/L ND ND Ethyl methacrylate ug/L ND ND Ethylbenzene ug/L ND ND lodomethane ug/L ND ND Isobutanol ug/L ND ND Methacrylonitrile ug/L ND ND Methyl methacrylate ug/L ND ND Methylene Chloride ug/L ND ND Propionitrile ug/L ND ND Styrene ug/L ND ND Tetrachloroethene ug/L ND ND Toluene ug/L ND ND trans-1,2-Dichloroethene ug/L ND ND trans- 1,3-Dichloropropene ug/L ND ND trans-1,4-Dichloro-2-butene ug/L ND ND Trichloroethene ug/L ND ND Trichlorofluoromethane ug/L ND ND Vinyl acetate ug/L ND ND Vinyl chloride ug/L ND ND Xylene (Total) ug/L ND ND 1,2-Dichloroethane-d4 (S) % 97 104 4-Bromofluorobenzene (S) % 95 95 Toluene-d8 (S) % 102 102 Max RPD RPD Qualifiers 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 v2 30 30 30 30 30 30 30 30 30 30 30 v2 30 30 30 30 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 QC Batch: 854267 Analysis Method: EPA 8011 QC Batch Method: EPA 8011 Analysis Description: GCS 8011 EDB DBCP Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92729134001, 92729134002 METHOD BLANK: 4407842 Matrix: Water Associated Lab Samples: 92729134001, 92729134002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,2-Dibromo-3-chloropropane ug/L ND 0.20 0.0041 05/14/24 17:00 1,2-Dibromoethane (EDB) ug/L ND 0.050 0.0074 05/14/24 17:00 1-Chloro-2-bromopropane (S) % 106 60-140 05/14/24 17:00 LABORATORY CONTROL SAMPLE & LCSD: 4407843 4407844 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 1,2-Dibromo-3-chloropropane ug/L 0.25 0.26 0.26 104 105 60-140 1 20 1,2-Dibromoethane (EDB) ug/L 0.25 0.30 0.28 119 112 60-140 6 20 1-Chloro-2-bromopropane (S) % 104 102 60-140 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4407846 4407847 MS MSD 92728815008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,2-Dibromo-3- ug/L ND 0.25 0.25 0.37 0.34 149 135 60-140 9 20 M1 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 0.25 0.25 0.37 0.35 146 141 60-140 4 20 M1 1-Chloro-2-bromopropane % 128 123 60-140 (S) SAMPLE DUPLICATE: 4407845 92728815007 Dup Max Parameter Units Result Result RPD RPD Qualifiers 1,2-Dibromo-3-chloropropane ug/L ND ND 20 1,2-Dibromoethane (EDB) ug/L ND ND 20 1-Chloro-2-bromopropane (S) % 112 110 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 QC Batch: 853232 Analysis Method: EPA 8081 B QC Batch Method: EPA 3510C Analysis Description: 8081 OC Pesticides Red Vol Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92729134001 METHOD BLANK: 4403078 Associated Lab Samples: 92729134001 Parameter 4,4'-DDD 4,4'-DDE 4,4'-DDT Aldrin alpha-BHC beta-BHC Chlordane (Technical) delta-BHC Dieldrin Endosulfan I Endosulfan 11 Endosulfan sulfate Endrin Endrin aldehyde gamma-BHC (Lindane) Heptachlor Heptachlor epoxide Methoxychlor Toxaphene Decachlorobiphenyl (S) Tetrachloro-m-xylene (S) Matrix: Water Units Blank Result Reporting Limit MDL Analyzed ug/L ND 0.050 0.017 05/09/24 19:17 ug/L ND 0.050 0.024 05/09/24 19:17 ug/L ND 0.050 0.026 05/09/24 19:17 ug/L ND 0.050 0.014 05/09/24 19:17 ug/L ND 0.050 0.012 05/09/24 19:17 ug/L ND 0.050 0.049 05/09/24 19:17 ug/L ND 0.50 0.16 05/09/24 19:17 ug/L ND 0.050 0.014 05/09/24 19:17 ug/L ND 0.050 0.015 05/09/24 19:17 ug/L ND 0.050 0.017 05/09/24 19:17 ug/L ND 0.050 0.016 05/09/24 19:17 ug/L ND 0.050 0.015 05/09/24 19:17 ug/L ND 0.050 0.018 05/09/24 19:17 ug/L ND 0.050 0.016 05/09/24 19:17 ug/L ND 0.050 0.012 05/09/24 19:17 ug/L ND 0.050 0.020 05/09/24 19:17 ug/L ND 0.050 0.028 05/09/24 19:17 ug/L ND 0.15 0.042 05/09/24 19:17 ug/L ND 0.50 0.22 05/09/24 19:17 % 123 19-200 05/09/24 19:17 % 106 10-137 05/09/24 19:17 LABORATORY CONTROL SAMPLE: 4403079 Qualifiers Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 4,4'-DDD ug/L 0.25 0.29 115 27-195 4,4'-DDE ug/L 0.25 0.33 132 24-178 4,4'-DDT ug/L 0.25 0.33 130 25-200 Aldrin ug/L 0.25 0.23 91 14-135 alpha-BHC ug/L 0.25 0.38 153 30-146 L1 beta-BHC ug/L 0.25 0.32 127 38-158 delta-BHC ug/L 0.25 0.27 107 10-185 Dieldrin ug/L 0.25 0.27 109 26-180 Endosulfan I ug/L 0.25 0.25 99 36-154 Endosulfan II ug/L 0.25 0.32 129 38-155 Endosulfan sulfate ug/L 0.25 0.33 130 42-170 Endrin ug/L 0.25 0.30 119 33-190 Endrin aldehyde ug/L 0.25 0.35 139 33-153 gamma-BHC (Lindane) ug/L 0.25 0.28 112 32-148 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 LABORATORY CONTROL SAMPLE: 4403079 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Heptachlor ug/L 0.25 0.28 112 32-149 Heptachlor epoxide ug/L 0.25 0.28 112 37-149 Methoxychlor ug/L 0.75 1.0 137 35-171 Decachlorobiphenyl (S) % 127 19-200 Tetrachloro-m-xylene (S) % 105 10-137 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4403080 4403081 MS MSD 92729715001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 4,4'-DDD ug/L ND 0.42 0.42 0.48 0.46 115 111 10-200 3 30 4,4'-DDE ug/L ND 0.42 0.42 0.57 0.55 136 131 10-188 3 30 4,4'-DDT ug/L ND 0.42 0.42 0.54 0.48 129 115 10-200 11 30 Aldrin ug/L ND 0.42 0.42 0.36 0.37 87 88 10-144 1 30 alpha-BHC ug/L ND 0.42 0.42 0.64 0.59 153 142 21-151 8 30 MO beta-BHC ug/L ND 0.42 0.42 0.57 0.49 137 117 21-175 15 30 delta-BHC ug/L ND 0.42 0.42 0.46 0.39 110 94 15-163 16 30 Dieldrin ug/L ND 0.42 0.42 0.48 0.43 115 104 10-184 10 30 Endosulfan I ug/L ND 0.42 0.42 0.45 0.42 108 100 11-180 8 30 Endosulfan II ug/L ND 0.42 0.42 0.56 0.51 135 121 13-174 10 30 Endosulfan sulfate ug/L ND 0.42 0.42 0.60 0.52 143 125 25-182 13 30 Endrin ug/L ND 0.42 0.42 0.52 0.49 126 118 10-200 7 30 Endrin aldehyde ug/L ND 0.42 0.42 0.60 0.54 143 130 10-167 10 30 gamma-BHC (Lindane) ug/L ND 0.42 0.42 0.49 0.42 117 101 13-163 14 30 Heptachlor ug/L ND 0.42 0.42 0.47 0.44 113 106 10-172 7 30 Heptachlor epoxide ug/L ND 0.42 0.42 0.49 0.44 117 106 10-168 10 30 Methoxychlor ug/L ND 1.2 1.2 1.8 1.6 145 132 13-183 10 30 Decachlorobiphenyl (S) % 119 140 19-200 Tetrachloro-m-xylene (S) % 99 99 10-137 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 QC Batch: 853097 Analysis Method: EPA 8082A QC Batch Method: EPA 3510C Analysis Description: 8082 GCS PCB Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92729134001 METHOD BLANK: 4402466 Matrix: Water Associated Lab Samples: 92729134001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers PCB-1016 (Aroclor 1016) ug/L ND 0.50 0.21 05/10/24 04:10 PCB-1221 (Aroclor 1221) ug/L ND 0.50 0.23 05/10/24 04:10 PCB-1232 (Aroclor 1232) ug/L ND 0.50 0.23 05/10/24 04:10 PCB-1242 (Aroclor 1242) ug/L ND 0.50 0.25 05/10/24 04:10 PCB-1248 (Aroclor 1248) ug/L ND 0.50 0.29 05/10/24 04:10 PCB-1254 (Aroclor 1254) ug/L ND 0.50 0.21 05/10/24 04:10 PCB-1260 (Aroclor 1260) ug/L ND 0.50 0.16 05/10/24 04:10 Decachlorobiphenyl (S) % 166 10-193 05/10/24 04:10 LABORATORY CONTROL SAMPLE: 4402467 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers PCB-1016 (Aroclor 1016) ug/L 5 4.4 89 34-137 PCB-1260 (Aroclor 1260) ug/L 5 4.1 82 39-145 Decachlorobiphenyl (S) % 136 10-193 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4402468 4402469 MS MSD 92729134001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual PCB-1016 (Aroclor 1016) ug/L ND 8.3 8.3 8.7 7.2 104 86 10-153 19 30 PCB-1260 (Aroclor 1260) ug/L ND 8.3 8.3 8.9 6.3 107 76 10-156 34 30 R1 Decachlorobiphenyl (S) % 170 126 10-193 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 QC Batch: 853102 Analysis Method: EPA 8270E QC Batch Method: EPA 3510C Analysis Description: 8270E Water APP9 RV MSSV Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92729134001 METHOD BLANK: 4402483 Associated Lab Samples: 92729134001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,2,4,5-Tetrachlorobenzene ug/L ND 10.0 4.5 05/09/24 12:59 1,2,4-Trichlorobenzene ug/L ND 10.0 1.7 05/09/24 12:59 1,2-Dichlorobenzene ug/L ND 10.0 1.8 05/09/24 12:59 1,3,5-Trinitrobenzene ug/L ND 10.0 5.5 05/09/24 12:59 1,3-Dichlorobenzene ug/L ND 10.0 1.6 05/09/24 12:59 1,3-Dinitrobenzene ug/L ND 10.0 3.8 05/09/24 12:59 1,4-Dichlorobenzene ug/L ND 10.0 1.7 05/09/24 12:59 1,4-Naphthoquinone ug/L ND 5.0 4.4 05/09/24 12:59 1-Naphthalenamine ug/L ND 10.0 6.0 05/09/24 12:59 2,2'-Oxybis(1-chloropropane) ug/L ND 10.0 1.2 05/09/24 12:59 2,3,4,6-Tetrachlorophenol ug/L ND 10.0 1.5 05/09/24 12:59 2,4,5-Trichlorophenol ug/L ND 10.0 1.4 05/09/24 12:59 2,4,6-Trichlorophenol ug/L ND 10.0 1.6 05/09/24 12:59 2,4-Dichlorophenol ug/L ND 10.0 1.4 05/09/24 12:59 2,4-Dimethylphenol ug/L ND 10.0 1.7 05/09/24 12:59 2,4-Dinitrophenol ug/L ND 50.0 26.0 05/09/24 12:59 2,4-Dinitrotoluene ug/L ND 10.0 1.6 05/09/24 12:59 2,6-Dinitrotoluene ug/L ND 10.0 1.7 05/09/24 12:59 2-Acetylaminofluorene ug/L ND 10.0 4.1 05/09/24 12:59 2-Chloronaphthalene ug/L ND 10.0 1.7 05/09/24 12:59 2-Chlorophenol ug/L ND 10.0 1.2 05/09/24 12:59 2-Methylnaphthalene ug/L ND 10.0 1.9 05/09/24 12:59 2-Methylphenol(o-Cresol) ug/L ND 10.0 1.9 05/09/24 12:59 2-Naphthalenamine ug/L ND 10.0 5.4 05/09/24 12:59 2-Nitroaniline ug/L ND 20.0 3.0 05/09/24 12:59 2-Nitrophenol ug/L ND 10.0 1.4 05/09/24 12:59 3&4-Methyl phenol (m&p Cresol) ug/L ND 10.0 1.2 05/09/24 12:59 3,3'-Dichlorobenzidine ug/L ND 20.0 8.1 05/09/24 12:59 3,3'-Dimethylbenzidine ug/L ND 50.0 31.1 05/09/24 12:59 3-Methylcholanthrene ug/L ND 10.0 3.7 05/09/24 12:59 3-Nitroaniline ug/L ND 20.0 3.8 05/09/24 12:59 4,6-Dinitro-2-methyl phenol ug/L ND 20.0 7.8 05/09/24 12:59 4-Aminobiphenyl ug/L ND 10.0 4.7 05/09/24 12:59 4-Bromophenylphenyl ether ug/L ND 10.0 1.8 05/09/24 12:59 4-ChIoro-3-methyl phenol ug/L ND 10.0 3.3 05/09/24 12:59 4-Chloroaniline ug/L ND 20.0 3.6 05/09/24 12:59 4-Chlorophenylphenyl ether ug/L ND 10.0 2.0 05/09/24 12:59 4-Nitroaniline ug/L ND 20.0 5.1 05/09/24 12:59 4-Nitrophenol ug/L ND 50.0 6.6 05/09/24 12:59 5-Nitro-o-toluidine ug/L ND 10.0 3.8 05/09/24 12:59 v1 v1 v1 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 METHOD BLANK: 4402483 Associated Lab Samples: 92729134001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 7,12-Dimethylbenz(a)anthracene ug/L ND 10.0 3.0 05/09/24 12:59 Acenaphthene ug/L ND 10.0 2.0 05/09/24 12:59 Acenaphthylene ug/L ND 10.0 2.0 05/09/24 12:59 Acetophenone ug/L ND 10.0 1.5 05/09/24 12:59 Anthracene ug/L ND 10.0 2.3 05/09/24 12:59 Benzo(a)anthracene ug/L ND 10.0 2.7 05/09/24 12:59 Benzo(a)pyrene ug/L ND 10.0 2.8 05/09/24 12:59 Benzo(b)fluoranthene ug/L ND 10.0 2.6 05/09/24 12:59 Benzo(g,h,i)perylene ug/L ND 10.0 2.8 05/09/24 12:59 Benzo(k)fluoranthene ug/L ND 10.0 2.7 05/09/24 12:59 Benzoic Acid ug/L ND 50.0 22.0 05/09/24 12:59 Benzyl alcohol ug/L ND 20.0 2.9 05/09/24 12:59 bis(2-Chloroethoxy)methane ug/L ND 10.0 1.8 05/09/24 12:59 bis(2-Chloroethyl) ether ug/L ND 10.0 1.9 05/09/24 12:59 bis(2-Ethylhexyl)phthalate ug/L ND 6.0 3.7 05/09/24 12:59 Butylbenzylphthalate ug/L ND 10.0 3.1 05/09/24 12:59 Carbazole ug/L ND 10.0 2.4 05/09/24 12:59 Chlorobenzilate ug/L ND 10.0 3.8 05/09/24 12:59 Chrysene ug/L ND 10.0 2.8 05/09/24 12:59 Di-n-butylphthalate ug/L ND 10.0 2.2 05/09/24 12:59 Di-n-octylphthalate ug/L ND 10.0 3.9 05/09/24 12:59 Diallate ug/L ND 10.0 3.4 05/09/24 12:59 Dibenz(a,h)anthracene ug/L ND 10.0 3.0 05/09/24 12:59 Dibenzofuran ug/L ND 10.0 2.1 05/09/24 12:59 Diethylphthalate ug/L ND 10.0 2.0 05/09/24 12:59 Dimethoate ug/L ND 10.0 3.7 05/09/24 12:59 Dimethylphthalate ug/L ND 10.0 2.1 05/09/24 12:59 Ethyl methanesulfonate ug/L ND 20.0 3.0 05/09/24 12:59 Famphur ug/L ND 10.0 6.1 05/09/24 12:59 Fluoranthene ug/L ND 10.0 2.2 05/09/24 12:59 Fluorene ug/L ND 10.0 2.1 05/09/24 12:59 Hexachloro-1,3-butadiene ug/L ND 10.0 1.8 05/09/24 12:59 Hexachlorobenzene ug/L ND 10.0 2.2 05/09/24 12:59 Hexachlorocyclopentadiene ug/L ND 10.0 1.6 05/09/24 12:59 Hexachloroethane ug/L ND 10.0 1.4 05/09/24 12:59 Hexachloropropene ug/L ND 10.0 2.7 05/09/24 12:59 Indeno(1,2,3-cd)pyrene ug/L ND 10.0 2.9 05/09/24 12:59 Isodrin ug/L ND 10.0 2.8 05/09/24 12:59 Isophorone ug/L ND 10.0 1.7 05/09/24 12:59 Isosafrole ug/L ND 10.0 2.5 05/09/24 12:59 Kepone ug/L ND 20.0 14.1 05/09/24 12:59 Methapyrilene ug/L ND 50.0 17.0 05/09/24 12:59 Methyl methanesulfonate ug/L ND 5.0 3.1 05/09/24 12:59 Methyl parathion ug/L ND 10.0 3.7 05/09/24 12:59 N-Nitroso-di-n-butylamine ug/L ND 10.0 2.0 05/09/24 12:59 v1 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 METHOD BLANK: 4402483 Associated Lab Samples: 92729134001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed N-Nitroso-di-n-propylamine ug/L ND 10.0 1.3 05/09/24 12:59 N-Nitrosodiethylamine ug/L ND 10.0 2.3 05/09/24 12:59 N-Nitrosodimethylamine ug/L ND 10.0 1.9 05/09/24 12:59 N-Nitrosodiphenylamine ug/L ND 10.0 3.0 05/09/24 12:59 N-Nitrosomethylethylamine ug/L ND 10.0 7.5 05/09/24 12:59 N-Nitrosomorpholine ug/L ND 10.0 4.2 05/09/24 12:59 N-Nitrosopiperidine ug/L ND 10.0 2.5 05/09/24 12:59 N-Nitrosopyrrolidine ug/L ND 10.0 3.1 05/09/24 12:59 Naphthalene ug/L ND 10.0 2.1 05/09/24 12:59 Nitrobenzene ug/L ND 10.0 1.9 05/09/24 12:59 O,O,O-Triethylphosphorothioate ug/L ND 10.0 2.6 05/09/24 12:59 O-Toluidine ug/L ND 10.0 2.6 05/09/24 12:59 P-Dimethylaminoazobenzene ug/L ND 5.0 2.4 05/09/24 12:59 p-Phenylenediamine ug/L ND 10.0 10.0 05/09/24 12:59 Parathion (Ethyl parathion) ug/L ND 10.0 3.9 05/09/24 12:59 Pentachlorobenzene ug/L ND 10.0 3.4 05/09/24 12:59 Pentachloronitrobenzene ug/L ND 10.0 3.3 05/09/24 12:59 Pentachlorophenol ug/L ND 20.0 3.8 05/09/24 12:59 Phenacetin ug/L ND 10.0 3.6 05/09/24 12:59 Phenanthrene ug/L ND 10.0 2.0 05/09/24 12:59 Phenol ug/L ND 10.0 1.4 05/09/24 12:59 Phorate ug/L ND 10.0 3.6 05/09/24 12:59 Pronamide ug/L ND 10.0 3.1 05/09/24 12:59 Pyrene ug/L ND 10.0 2.2 05/09/24 12:59 Pyridine ug/L ND 10.0 2.6 05/09/24 12:59 Safrole ug/L ND 10.0 2.3 05/09/24 12:59 Thionazin ug/L ND 10.0 2.9 05/09/24 12:59 2,4,6-Tribromophenol (S) % 89 10-166 05/09/24 12:59 2-Fluorobiphenyl (S) % 88 10-130 05/09/24 12:59 2-Fluorophenol (S) % 71 10-130 05/09/24 12:59 Nitrobenzene-d5 (S) % 92 10-133 05/09/24 12:59 Phenol-d6 (S) % 53 10-130 05/09/24 12:59 Terphenyl-d14 (S) % 104 10-193 05/09/24 12:59 v1 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 4402484 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,2,4,5-Tetrachlorobenzene ug/L 50 26.2 52 18-130 1,2,4-Trichlorobenzene ug/L 50 20.4 41 14-130 1,2-Dichlorobenzene ug/L 50 22.0 44 10-130 1,3,5-Trinitrobenzene ug/L 50 82.7 165 59-200 v1 1,3-Dichlorobenzene ug/L 50 19.3 39 10-130 1,3-Dinitrobenzene ug/L 50 60.9 122 51-170 1,4-Dichlorobenzene ug/L 50 20.3 41 10-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 LABORATORY CONTROL SAMPLE: Parameter 4402484 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,4-Naphthoquinone ug/L 50 54.9 110 32-132 1-Naphthalenamine ug/L 50 31.9 64 35-140 2,2'-Oxybis(1-chloropropane) ug/L 50 55.2 110 23-130 v1 2,3,4,6-Tetrachlorophenol ug/L 50 43.7 87 38-154 2,4,5-Trichlorophenol ug/L 50 48.3 97 36-150 2,4,6-Trichlorophenol ug/L 50 48.0 96 30-151 2,4-Dichlorophenol ug/L 50 46.2 92 36-140 2,4-Dimethylphenol ug/L 50 54.4 109 36-155 2,4-Dinitrophenol ug/L 250 278 111 10-169 v1 2,4-Dinitrotoluene ug/L 50 51.3 103 46-160 v1 2,6-Dinitrotoluene ug/L 50 51.8 104 47-161 2-Acetylaminofluorene ug/L 50 54.3 109 39-184 2-Chloronaphthalene ug/L 50 30.4 61 29-134 2-Chlorophenol ug/L 50 44.0 88 29-130 2-Methylnaphthalene ug/L 50 28.0 56 26-130 2-Methylphenol(o-Cresol) ug/L 50 43.6 87 32-130 2-Naphthalenamine ug/L 50 35.9 72 23-145 2-Nitroaniline ug/L 100 93.8 94 41-150 2-Nitrophenol ug/L 50 47.5 95 31-145 3&4-Methyl phenol (m&p Cresol) ug/L 50 43.5 87 29-130 3,3'-Dichlorobenzidine ug/L 100 97.0 97 46-153 3,3'-Dimethylbenzidine ug/L 100 71.9 72 24-200 3-Methylcholanthrene ug/L 50 51.0 102 31-195 3-Nitroaniline ug/L 100 93.4 93 47-156 4,6-Dinitro-2-methyl phenol ug/L 100 108 108 23-161 v1 4-Aminobiphenyl ug/L 50 31.9 64 26-151 4-Bromophenylphenyl ether ug/L 50 47.8 96 45-143 4-Chloro-3-methylphenol ug/L 100 97.6 98 42-143 4-Chloroaniline ug/L 100 89.1 89 37-135 4-Chlorophenylphenyl ether ug/L 50 48.2 96 43-140 4-Nitroaniline ug/L 100 94.3 94 47-157 4-Nitrophenol ug/L 250 135 54 10-130 5-Nitro-o-toluidine ug/L 50 53.8 108 54-170 7,12-Dimethylbenz(a)anthracene ug/L 50 50.1 100 29-176 Acenaphthene ug/L 50 40.9 82 38-138 Acenaphthylene ug/L 50 41.1 82 39-139 Acetophenone ug/L 50 46.9 94 34-135 Anthracene ug/L 50 47.9 96 45-136 Benzo(a)anthracene ug/L 50 48.8 98 52-151 Benzo(a)pyrene ug/L 50 48.6 97 46-165 Benzo(b)fluoranthene ug/L 50 53.5 107 44-170 Benzo(g,h,i)perylene ug/L 50 48.0 96 39-171 Benzo(k)fluoranthene ug/L 50 49.8 100 43-168 Benzoic Acid ug/L 250 162 65 10-130 v1 Benzyl alcohol ug/L 100 84.4 84 33-134 bis(2-Chloroethoxy)methane ug/L 50 47.8 96 37-140 bis(2-Chloroethyl) ether ug/L 50 47.8 96 33-136 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 LABORATORY CONTROL SAMPLE: Parameter 4402484 Units Spike Conc. LCS Result LCS % Rec % Rec Limits bis(2-Ethylhexyl)phthalate ug/L 50 52.5 105 50-169 Butylbenzylphthalate ug/L 50 52.6 105 50-174 Carbazole ug/L 50 47.2 94 52-151 Chlorobenzilate ug/L 50 52.8 106 46-167 Chrysene ug/L 50 49.1 98 52-148 Di-n-butylphthalate ug/L 50 49.9 100 51-154 Di-n-octylphthalate ug/L 50 53.8 108 44-170 Diallate ug/L 50 51.3 103 49-147 Dibenz(a,h)anthracene ug/L 50 47.7 95 41-171 Dibenzofuran ug/L 50 42.2 84 42-157 Diethylphthalate ug/L 50 48.7 97 50-149 Dimethoate ug/L 50 49.8 100 52-169 Dimethylphthalate ug/L 50 48.6 97 47-146 Ethyl methanesulfonate ug/L 50 48.8 98 27-146 Famphur ug/L 50 34.1 68 13-130 Fluoranthene ug/L 50 49.2 98 51-152 Fluorene ug/L 50 47.2 94 46-143 Hexachloro-1,3-butadiene ug/L 50 17.9 36 10-130 Hexachlorobenzene ug/L 50 45.9 92 40-139 Hexachlorocyclopentadiene ug/L 50 16.6 33 10-130 Hexachloroethane ug/L 50 16.8 34 10-130 Hexachloropropene ug/L 50 21.4 43 10-130 Indeno(1,2,3-cd)pyrene ug/L 50 46.0 92 40-172 Isodrin ug/L 50 51.8 104 50-150 Isophorone ug/L 50 50.3 101 37-143 Isosafrole ug/L 50 39.8 80 35-130 Kepone ug/L 100 77.9 78 12-130 Methapyrilene ug/L 50 ND 19 10-188 Methyl methanesulfonate ug/L 50 37.1 74 24-135 Methyl parathion ug/L 50 57.0 114 59-174 N-Nitroso-di-n-butylamine ug/L 50 37.2 74 33-130 N-Nitroso-di-n-propylamine ug/L 50 53.7 107 38-145 N-Nitrosodiethylamine ug/L 50 45.7 91 26-145 N-Nitrosodimethylamine ug/L 50 41.9 84 30-130 N-Nitrosodiphenylamine ug/L 50 47.6 95 46-144 N-Nitrosomethylethylamine ug/L 50 45.1 90 19-138 N-Nitrosomorpholine ug/L 50 59.2 118 20-164 N-Nitrosopiperidine ug/L 50 48.3 97 35-147 N-Nitrosopyrrolidine ug/L 50 47.6 95 31-142 Naphthalene ug/L 50 28.8 58 21-130 Nitrobenzene ug/L 50 43.8 88 33-136 O,O,O-Triethylphosphorothioate ug/L 50 45.3 91 27-136 O-Toluidine ug/L 50 43.3 87 27-140 P-Dimethylaminoazobenzene ug/L 100 48.3 48 23-130 p-Phenylenediamine ug/L ND Parathion (Ethyl parathion) ug/L 50 58.8 118 59-171 Pentachlorobenzene ug/L 50 42.9 86 42-138 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 44 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 aceo Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 LABORATORY CONTROL SAMPLE: Parameter 4402484 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Pentachloronitrobenzene ug/L 50 58.3 117 64-185 Pentachlorophenol ug/L 100 90.7 91 19-156 Phenacetin ug/L 50 52.2 104 57-174 Phenanthrene ug/L 50 47.4 95 49-143 Phenol ug/L 50 26.8 54 18-130 Phorate ug/L 50 69.0 138 41-200 v1 Pronamide ug/L 50 53.3 107 59-174 Pyrene ug/L 50 49.2 98 48-156 Pyridine ug/L 50 15.2 30 10-130 Safrole ug/L 50 38.3 77 31-136 Thionazin ug/L 50 50.4 101 52-151 2,4,6-Tribromophenol (S) % 91 10-166 2-Fluorobiphenyl (S) % 67 10-130 2-Fluorophenol(S) % 64 10-130 Nitrobenzene-d5 (S) % 85 10-133 Phenol-d6 (S) % 52 10-130 Terphenyl-d14 (S) % 95 10-193 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4403011 MS 92729715001 Spike Parameter Units Result Conc. MSD Spike Conc. 4403012 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,2,4,5-Tetrachlorobenzene ug/L ND 41.7 83.3 31.4 69.1 75 83 10-136 75 30 R1 1,2,4-Trichlorobenzene ug/L ND 41.7 83.3 25.9 56.6 62 68 10-130 75 30 R1 1,2-Dichlorobenzene ug/L ND 41.7 83.3 22.8 52.8 55 63 10-130 79 30 R1 1,3,5-Trinitrobenzene ug/L ND 41.7 83.3 58.8 134 141 161 32-200 78 30 R1,v1 1,3-Dichlorobenzene ug/L ND 41.7 83.3 21.5 49.3 52 59 10-130 79 30 R1 1,3-Dinitrobenzene ug/L ND 41.7 83.3 42.3 90.2 101 108 30-173 72 30 R1 1,4-Dichlorobenzene ug/L ND 41.7 83.3 22.2 51.2 53 61 10-130 79 30 R1 1,4-Naphthoquinone ug/L ND 41.7 83.3 41.7 110 100 132 10-144 90 30 R1 1-Naphthalenamine ug/L ND 41.7 83.3 28.1 14.8J 67 18 10-156 30 2,2'-Oxybis(1- ug/L ND 41.7 83.3 41.3 87.0 99 104 10-132 71 30 R1,v1 chloropropane) 2,3,4,6-Tetrachlorophenol ug/L ND 41.7 83.3 1.5J 68.5 4 82 10-185 30 M1 2,4,5-Trichlorophenol ug/L ND 41.7 83.3 7.OJ 75.3 17 90 10-174 30 2,4,6-Trichlorophenol ug/L ND 41.7 83.3 2.5J 72.8 6 87 10-173 30 M1 2,4-Dichlorophenol ug/L ND 41.7 83.3 10.3 69.4 25 83 10-153 148 30 R1 2,4-Dimethylphenol ug/L ND 41.7 83.3 37.9 67.4 91 81 12-157 56 30 R1 2,4-Dinitrophenol ug/L ND 208 417 ND 435 0 104 10-165 30 M1,v1 2,4-Dinitrotoluene ug/L ND 41.7 83.3 37.2 80.1 89 96 29-168 73 30 R1,v1 2,6-Dinitrotoluene ug/L ND 41.7 83.3 38.5 81.5 93 98 28-168 72 30 R1 2-Acetylam inofl uorene ug/L ND 41.7 83.3 35.7 83.7 86 100 20-194 80 30 R1 2-Chloronaphthalene ug/L ND 41.7 83.3 29.7 66.4 71 80 11-136 76 30 R1 2-Chlorophenol ug/L ND 41.7 83.3 10 68.7 24 82 10-134 149 30 R1 2-Methyl naphthalene ug/L ND 41.7 83.3 32.0 71.4 77 86 10-131 76 30 R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4403011 MS 92729715001 Spike Parameter Units Result Conc. MSD Spike Conc. 4403012 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 2-Methyl phenol(o-Cresol) ug/L ND 41.7 83.3 28.5 56.2 69 67 10-130 65 30 R1 2-Naphthalenamine ug/L ND 41.7 83.3 28.3 ND 68 0 10-147 30 M1 2-Nitroaniline ug/L ND 83.3 167 68.4 147 82 88 19-156 73 30 R1 2-Nitrophenol ug/L ND 41.7 83.3 7.7J 76.3 19 92 10-160 30 3&4-Methylphenol(m&p ug/L ND 41.7 83.3 26.3 60.5 63 73 10-132 79 30 R1 Cresol) 3,3'-Dichlorobenzidine ug/L ND 83.3 167 71.8 107 86 64 10-173 40 30 R1 3,3'-Dimethylbenzidine ug/L ND 83.3 167 64.4 ND 77 23 10-200 30 3-Methylcholanthrene ug/L ND 41.7 83.3 38.8 77.6 93 93 10-200 67 30 R1 3-Nitroaniline ug/L ND 83.3 167 70.9 148 85 89 19-169 70 30 R1 4,6-Dinitro-2-methylphenol ug/L ND 83.3 167 ND 162 0 97 10-178 30 M1,v1 4-Aminobiphenyl ug/L ND 41.7 83.3 31.6 37.8 76 45 10-170 18 30 4-Bromophenylphenyl ether ug/L ND 41.7 83.3 34.5 70.9 83 85 28-149 69 30 R1 4-Chloro-3-methylphenol ug/L ND 83.3 167 59.1 141 71 85 18-148 82 30 R1 4-Chloroaniline ug/L ND 83.3 167 68.9 133 83 80 10-141 63 30 R1 4-Chlorophenylphenyl ether ug/L ND 41.7 83.3 36.0 75.9 86 91 24-144 71 30 R1 4-Nitroaniline ug/L ND 83.3 167 67.9 142 82 85 18-170 71 30 R1 4-Nitrophenol ug/L ND 208 417 ND 225 0 54 10-130 30 M1 5-Nitro-o-toluidine ug/L ND 41.7 83.3 39.9 86.5 96 104 38-167 74 30 R1 7,12- ug/L ND 41.7 83.3 37.7 78.3 90 94 10-182 70 30 R1 Dimethylbenz(a)anthracene Acenaphthene ug/L ND 41.7 83.3 34.1 73.4 82 88 18-142 73 30 R1 Acenaphthylene ug/L ND 41.7 83.3 34.3 73.5 82 88 18-143 73 30 R1 Acetophenone ug/L ND 41.7 83.3 34.1 76.6 82 92 10-142 77 30 R1 Anthracene ug/L ND 41.7 83.3 34.9 74.2 84 89 32-138 72 30 R1 Benzo(a)anth race ne ug/L ND 41.7 83.3 36.0 77.4 87 93 41-155 73 30 R1 Benzo(a)pyrene ug/L ND 41.7 83.3 36.4 75.9 87 91 10-167 70 30 R1 Benzo(b)fluoranthene ug/L ND 41.7 83.3 40.6 84.3 97 101 31-172 70 30 R1 Benzo(g,h,i)perylene ug/L ND 41.7 83.3 36.3 73.4 87 88 26-177 68 30 R1 Benzo(k)fluoranthene ug/L ND 41.7 83.3 36.5 76.9 87 92 31-168 71 30 R1 Benzoic Acid ug/L ND 208 417 ND 259 0 62 10-130 30 M1,v1 Benzyl alcohol ug/L ND 83.3 167 62.0 138 74 83 10-136 76 30 R1 bis(2- ug/L ND 41.7 83.3 35.7 76.0 86 91 12-143 72 30 R1 Chloroethoxy)methane bis(2-Chloroethyl) ether ug/L ND 41.7 83.3 34.7 76.9 83 92 10-139 76 30 R1 bis(2- Ethyl hexyl)phthalate ug/L ND 41.7 83.3 37.9 82.6 91 99 41-173 74 30 R1 Butylbenzylphthalate ug/L ND 41.7 83.3 38.1 82.3 92 99 38-182 73 30 R1 Carbazole ug/L ND 41.7 83.3 35.9 76.5 86 92 51-149 72 30 R1 Chlorobenzilate ug/L ND 41.7 83.3 38.7 81.5 93 98 33-175 71 30 R1 Chrysene ug/L ND 41.7 83.3 36.1 78.2 87 94 41-152 74 30 R1 Di-n-butylphthalate ug/L ND 41.7 83.3 36.7 78.1 88 94 37-162 72 30 R1 Di-n-octylphthalate ug/L ND 41.7 83.3 39.6 86.6 95 104 36-176 74 30 R1 Diallate ug/L ND 41.7 83.3 36.8 76.2 88 91 26-155 70 30 R1 Dibenz(a,h)anthracene ug/L ND 41.7 83.3 36.8 75.2 88 90 29-175 69 30 R1 Dibenzofuran ug/L ND 41.7 83.3 33.6 71.1 81 85 23-144 72 30 R1 Diethylphthalate ug/L ND 41.7 83.3 37.1 76.6 89 92 33-154 69 30 R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4403011 MS 92729715001 Spike Parameter Units Result Conc. Dimethoate Dimethylphthalate Ethyl methanesulfonate Famphur Fluoranthene Fluorene Hexachloro-1,3-butadiene Hexachlorobenzene Hexachlorocyclopentadiene Hexachloroethane Hexachloropropene Indeno(1,2,3-cd)pyrene Isodrin Isophorone Isosafrole Kepone Methapyrilene Methyl methanesulfonate Methyl parathion N-Nitroso-di-n-butylamine N-Nitroso-di-n-propylamine N-Nitrosodiethylamine N-Nitrosodimethylamine N-Nitrosodiphenylamine N-Nitrosomethylethylamine N-Nitrosomorpholine N-Nitrosopiperidine N-Nitrosopyrrolidine Naphthalene Nitrobenzene O,O,O- Triethylphosphorothioate O-Toluidine P- Dimethylaminoazobenzene p-Phenylenediamine Parathion (Ethyl parathion) Pentachlorobenzene Pentachloronitrobenzene Pentachlorophenol Phenacetin Phenanthrene Phenol Phorate Pronamide Pyrene 4403012 MSD Spike MS MSD MS MSD % Rec Conc. Result Result % Rec % Rec Limits ug/L ND 41.7 83.3 36.9 81.9 89 98 41-169 ug/L ND 41.7 83.3 36.2 76.1 87 91 29-150 ug/L ND 41.7 83.3 35.8 79.1 86 95 10-147 ug/L ND 41.7 83.3 19.7 60.6 47 73 10-130 ug/L ND 41.7 83.3 37.1 78.9 89 95 40-156 ug/L ND 41.7 83.3 36.3 75.8 87 91 26-148 ug/L ND 41.7 83.3 25.1 55.2 60 66 10-130 ug/L ND 41.7 83.3 33.1 70.0 80 84 27-145 ug/L ND 41.7 83.3 25.1 58.0 60 70 10-130 ug/L ND 41.7 83.3 21.0 46.7 50 56 10-130 ug/L ND 41.7 83.3 25.2 56.4 60 68 10-130 ug/L ND 41.7 83.3 35.1 73.2 84 88 28-176 ug/L ND 41.7 83.3 38.0 79.5 91 95 33-153 ug/L ND 41.7 83.3 36.3 77.1 87 93 14-145 ug/L ND 41.7 83.3 32.8 69.3 79 83 13-136 ug/L ND 83.3 167 34.8 141 42 84 10-130 ug/L ND 41.7 83.3 18.7J ND 45 22 10-200 ug/L ND 41.7 83.3 26.9 58.7 65 70 10-138 ug/L ND 41.7 83.3 40.9 90.5 98 109 44-177 ug/L ND 41.7 83.3 31.8 63.6 76 76 14-133 ug/L ND 41.7 83.3 38.2 84.0 92 101 12-149 ug/L ND 41.7 83.3 33.7 74.9 81 90 10-148 ug/L ND 41.7 83.3 29.5 65.8 71 79 10-130 ug/L ND 41.7 83.3 33.8 64.2 81 77 29-149 ug/L ND 41.7 83.3 31.5 80.8 76 97 10-139 ug/L ND 41.7 83.3 42.3 90.7 102 109 10-159 ug/L ND 41.7 83.3 36.0 74.2 86 89 14-151 ug/L ND 41.7 83.3 33.4 74.9 80 90 14-143 ug/L ND 41.7 83.3 28.9 62.8 69 75 10-130 ug/L ND 41.7 83.3 31.9 68.8 77 83 10-145 ug/L ND 41.7 83.3 36.6 74.7 88 90 10-142 Max RPD RPD Qual 76 30 R1 71 30 R1 75 30 R1 102 30 R1 72 30 R1 70 30 R1 75 30 R1 71 30 R1 79 30 R1 76 30 R1 77 30 R1 70 30 R1 70 30 R1 72 30 R1 71 30 R1 121 30 R1 30 74 30 R1 75 30 R1 67 30 R1 75 30 R1 76 30 R1 76 30 R1 62 30 R1 88 30 R1 73 30 R1 69 30 R1 77 30 R1 74 30 R1 73 30 R1 68 30 R1 ug/L ND 41.7 83.3 32.5 44.8 78 54 10-137 32 30 R1 ug/L ND 83.3 167 36.0 73.6 43 44 17-130 69 30 R1 ug/L ND ND ND 30 ug/L ND 41.7 83.3 43.8 93.8 105 113 45-174 73 30 R1 ug/L ND 41.7 83.3 34.4 72.2 83 87 20-143 71 30 R1 ug/L ND 41.7 83.3 38.5 90.7 92 109 39-186 81 30 R1 ug/L ND 83.3 167 ND 133 2 80 10-178 30 M1 ug/L ND 41.7 83.3 38.3 83.6 92 100 36-185 74 30 R1 ug/L ND 41.7 83.3 34.6 72.4 83 87 36-146 71 30 R1 ug/L ND 41.7 83.3 11.6 30.2 28 36 10-130 89 30 R1 ug/L ND 41.7 83.3 49.7 105 119 125 26-200 71 30 R1,v1 ug/L ND 41.7 83.3 40.1 84.4 96 101 40-181 71 30 R1 ug/L ND 41.7 83.3 36.3 77.5 87 93 42-156 72 30 R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4403011 MS 92729715001 Spike Parameter Units Result Conc. MSD Spike Conc. 4403012 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Pyridine ug/L ND 41.7 83.3 25.3 39.4 61 47 10-130 44 30 R1 Safrole ug/L ND 41.7 83.3 36.6 76.0 88 91 10-142 70 30 R1 Thionazin ug/L ND 41.7 83.3 36.7 78.4 88 94 31-159 73 30 R1 2,4,6-Tribromophenol (S) % 18 82 10-166 2-Fluorobiphenyl (S) % 95 83 10-130 2-Fluorophenol (S) % 8 53 10-130 SO Nitrobenzene-d5 (S) % 102 89 10-133 Phenol-d6 (S) % 28 38 10-130 Terphenyl-d14(S) % 104 92 10-193 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 QC Batch: 853221 Analysis Method: SM 4500-S2D-2011 QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92729134001 METHOD BLANK: 4403056 Matrix: Water Associated Lab Samples: 92729134001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfide mg/L ND 0.10 0.022 05/09/24 04:40 LABORATORY CONTROL SAMPLE: 4403057 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide mg/L 0.5 0.54 109 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4403058 4403059 MS MSD 92728841007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide mg/L ND 0.5 0.5 0.55 0.56 109 113 80-120 3 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4403060 4403061 MS MSD 92728860002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide mg/L ND 0.5 0.5 0.46 0.52 92 104 80-120 12 10 R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 QC Batch: 854048 Analysis Method: SM 4500-CN-E-2016 QC Batch Method: SM 4500-CN-E-2016 Analysis Description: 450OCNE Cyanide, Total Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92729134001 METHOD BLANK: 4406811 Matrix: Water Associated Lab Samples: 92729134001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Cyanide mg/L ND 0.0080 0.0060 05/14/2417:23 LABORATORY CONTROL SAMPLE: 4406812 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Cyanide mg/L 0.1 0.093 93 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4406816 4406817 MS MSD 92728574002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Cyanide mg/L ND 0.1 0.1 0.085 0.085 84 84 80-120 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 39 of 44 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 aceo Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Foothills LF/Semi-Annual Pace Project No.: 92729134 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS CO Result confirmed by second analysis. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. SO Surrogate recovery outside laboratory control limits. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 44 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Foothills LF/Semi-Annual 92729134 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92729134001 1403-MW-2R 855406 92729134001 1403-MW-2R 8151A 2282658 EPA8151 2282658 92729134001 1403-MW-2R EPA 8011 854267 EPA 8011 854330 92729134002 1403-Trip Blank EPA 8011 854267 EPA 8011 854330 92729134001 1403-MW-2R EPA 3510C 853232 EPA 8081 B 853350 92729134001 1403-MW-2R EPA 3510C 853097 EPA 8082A 853351 92729134001 1403-MW-2R EPA 3005A 853375 EPA 6020B 853528 92729134001 1403-MW-2R EPA 7470A 853706 EPA 7470A 854074 92729134001 1403-MW-2R EPA 3510C 853102 EPA 8270E 853269 92729134001 1403-MW-2R EPA 8260D 853049 92729134002 1403-Trip Blank EPA 8260D 853049 92729134001 1403-MW-2R SM 4500-S2D-2011 853221 92729134001 1403-MW-2R SM 4500-CN-E-2016 854048 SM 4500-CN-E-2016 854236 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:49 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 44 < x n ;u p ;u m W - `� C L- m m O z z r I `� 1 S` 0 p n cc Cmn D Z o O 0 S 0 v 1 m # C Z m O 0 0 D g Q> N N K n m m O z �( m n & O c is ;D W 0 m m Q D z < . W^ .� m = o 0 D m c co /„ { m m m r cn n z _ oD m r - m Z o X W � 9 0 O Z m C D 0vi W X x cu > ;u 0 D 0 CD m �cvm mIV m ' r y a7 m� C W a O NN n z W� N Z D 0 ,ti r c) m Oz CD T� W ,a j cv) �> X m. r N � �--- 0;umz—D� z O o e m o Z .` ,m m a 0) r m -„ p c _ Fn m m X X APP.II - VOLATILES - 8260 , < c z < X APP.II - METALS W y X APP. II - CYANIDE _0 cn >< APP. II - SULFIDE m >< JAPP.11-13N/A 8270,HERB 8151 0 rn c c m >� APP. II - PEST 8081/8082 -4 D m � 0 X APP. II - PCB 8081/8082 m >X >X APP.II - VOLATILES - 8011 < 1 m,c m > >C PFAS -1633 -4 < -Nir N Xmw3cz 0- ar n r- F— o W � ME,fn G) i7 -�I O O cn<G)D Z �� •• QD m -� --jc0>0 -0rm91 � z D T, � 0 A 0 co Z 2 m D m W U m moDc-�j5 m<�m� EENj�K0Zmz mDG) n r�G) N D Dm�DG) , cn m f� ° �DmX-1 �� m ~ 0 z X m x /-♦ r cn cn 0 rn Gnaw 00 O I I. . I rDcnccn — i0) m m d Z= n � �rL) 0 c 0 ri in OOpco —< E O C D O r " 2 2- p0 In c D O n m o.� IA � n Z o IAd Z (� N n Irn ri Pag O n (D �m> n N Z':53. c00 �o� T�CD Dm c�0 cm �D of m _ 0 a� o Z Ejm w 0 0 cfl N 42 c f 44 DC# Title: ENV-FRM-HUNT-0083 03_Sample Condition Upon Receipt Effective Date: 12/01/2023 Iboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑ AtlantaFj"-�Kernersvillen • Client Name: Wa# : 927Z9 1 34 i Project #: a;J G V b e �ii ' PM: MP Due Oate: 05/16/24 2ourier: red Ex j OUPS ❑LISPS []client CLIENT: GARepNC ] Commercial ❑Pace ❑Other:__ _ -ustody Seal Present? ❑Yes ENO Seals Intact? ❑Yes ❑No ❑N/A Sacking Material: ❑Bubble Wrap ❑Bubble Bags ❑None ❑ Other Thermometer. �J ' R Gun ID: Type of Ice: []Wet [-]Blue Correction Factor: % -ooler Temp:` Add/Subtract ("C)t:� =ooler Temp Corrected ('C): ~ i JSDA Regulated Soil (❑ N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC Chain of Custody Present? Samples Arrived within Hold Time? Short Hold Time Analysis (<72 hr.)? Rush Turn Around Time Requested? Sufficient Volume? Correct Containers Used? _ -Pace Containers Used? Containers Intact? Dissolved analysis: Samples Field Filtered? Sample Labels Match COC? -Includes Datefl-ime/ID/Analysis Headspace in VOA Vials (a5-6mm)? Trip Blank Present? Trip Blank Custody Seals Present? )MMENTS/SAMPLE DISCREPANCY _ L ENT NOTIFICATION/RESOLUTION zrson contacted: Project Manager SCURF Review: Project Manager SRF Review: ❑No ❑N/A 1. ❑No ❑NIA 2. []No ❑N/A 3. Na ❑NIA 4. ❑No []NIA 5. ❑No ❑N/A 6. Q'fes ❑No ❑NIA 7. ❑Yes ONO NIA 8. l]Yes [:]No []N/A 9. I j rye• 4 ❑Yes ❑No ❑N/A 10. ❑Yes [:]No []N/A 11. ❑Yes ❑No ❑N/A Date/Initials Person Examining Contents: Biological Tissue F�ra�x `? ❑Yes ONO .❑ /N A ❑None Temp should be above freezing to 6`C ❑Samples out of temp criteria. Samples on ice, cooling process has begun Did samples originate from a foreign source (internationally, including Hawaii and Puerto Rico)? ❑Yes [:]No Lot ID of split containers: Date/Time: Date: Date: Field Data Required? ❑Yes ❑No Page 43 of 44 ialtrax ID: 69614 Page 1 of 2 DC# Title: ENV-FRM-HUN1-0083 v03_Sample Condition Upon Receipt Effective Date: 12/01/2023 *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottles ***Check all unpreserved Nitrates for chlorine E v i z 3 4 5 6 7 8 9 10 11 12 -WO:92729134 Project # PM: MP Due Date: 05/16/24 CLIENT: GARepNC Q Z Q Z '6 Q Z Q Z U V V O Z OS U N /, w Q Q Z -O _ Z > V Iry V �' U Q Q Z Q Z Q Z Y m Q m Q n `n rn 4 Z a > a Z io > Ol >CD Gl O/ Q C > Ol OJ Q C U > Ul Cl Q C U w N d Q C M d' In O N = 2 Q M O Z 2 U 10 N u Q Z N 2 Q v 2 O N Z co^ m 0 d > p� v Q C N V Q _� U _ ai Q C N 2 Q V 0, N = Q 0 N = ¢ Z u � 2 Z _ a Z v U Z �..� M O ry M N a > O1 �n Q C Q ? 0 d M > W Q C a = d > Z "'� Y t0 d Z 10 d O N N ? Y N N 01 C N —�' M > O N w W C U E U E V E ;, V E E V E V E L o v E a`, = E Q a`, E Q E n E v U/ E a E O EoOo a = Q J> E z J E = p J E V J E Y Q vl m J E Ul J E O a E Ln a J E E O J E O Ol Em QEQ J E O N 1-1 O a m Ul N a- m O Ln C4 0. m — '-1 O a m Ln ry VI a m O N N Z a m M N ..� N a m Ln N -4 m a t=i O 3 ci 'i l9 a — a--1 ri O a N N M U) a ~ a--1 eNi O a lA N M U a O - al t7 o O � 0% O o O V M O > M O > M 0 a O In !� a Y V > N .-i N M In lfl N N IL N M o_ c-I O t7 N (' M O \ oy ,L �m /\� � \\\ pH Adjustment Log for Preserved samples _ Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation + Amount of Preservative adjusted I added I f � Lot # Vote: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DENR Certification Office (i.e. Jut of hold, incorrect preservative, out of temp, incorrect containers. Page 44 of 44 ualtrax ID: 69614 Paae 2 of 2 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 May 20, 2024 Environmental Manager Foothills Environmental Landfill 2800 Cheraw Road Lenoir, NC 28645 RE: Project: Foothills LF/Leachate Pace Project No.: 92729130 Dear Environmental Manager: Enclosed are the analytical results for sample(s) received by the laboratory on May 07, 2024. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte • Pace Analytical Services - Peachtree Corners, GA If you have any questions concerning this report, please feel free to contact me. Sincerely, "Ai� 5 Maiya Parks maiya.parks@pacelabs.com 770-734-4205 Project Manager Enclosures cc: Data Manager, TriHydro Corporation REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 32 Project: Foothills LF/Leachate Pace Project No.: 92729130 Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 Pace Analytical Services Peachtree Corners 110 Technology Pkwy, Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 North Carolina Certification #: 381 South Carolina Certification #: 98011001 Virginia Certification #: 460204 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Foothills LF/Leachate Pace Project No.: 92729130 Lab ID Sample ID SAMPLE SUMMARY Matrix Date Collected Date Received 92729130001 1403-Leachate Water 05/06/24 15:35 05/07/24 09:57 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Foothills LF/Leachate Pace Project No.: 92729130 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92729130001 1403-Leachate EPA 6020E MT1 15 PASI-GA EPA 7470A VB 1 PASI-GA SM 2540C-2015 DL1 1 PASI-GA SM 2540D-2015 LAB 1 PASI-GA EPA410.4 TBM 1 PASI-GA SM 4500-H+B-2011 MDM1 1 PASI-GA SM 521OB-2016 TBM 1 PASI-GA EPA 8260D TMH 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C EPA 350.1 Rev 2.0 1993 SSW 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 2 PASI-A EPA 365.1 Rev 2.0 1993 NCF 1 PASI-A EPA 9056A CDC 1 PASI-A PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte PASI-GA = Pace Analytical Services - Peachtree Corners, GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Foothills LF/Leachate Pace Project No.: 92729130 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed 92729130001 1403-Leachate Performed by ES&S 05/06/24 15:35 pH 7.37 Std. Units 05/06/24 15:35 Temperature 22.1 deg C 05/06/24 15:35 Specific Conductance 17,210 umhos/cm 05/06/24 15:35 Turbidity 68.20 NTU 05/06/24 15:35 EPA 6020B Antimony 95.9 ug/L 30.0 05/13/24 18:50 EPA 6020B Arsenic 176 ug/L 50.0 05/13/24 18:50 EPA 6020B Barium 558 ug/L 500 05/13/24 18:50 EPA 6020B Chromium 337 ug/L 50.0 05/13/24 18:50 EPA 6020B Cobalt 39.7J ug/L 50.0 05/13/24 18:50 EPA 6020B Copper 20.OJ ug/L 50.0 05/13/24 18:50 EPA 6020B Lead 2.1 J ug/L 50.0 05/13/24 18:50 EPA 6020B Nickel 175J ug/L 250 05/13/24 18:50 EPA 6020B Selenium 8.1 J ug/L 50.0 05/13/24 18:50 EPA 6020B Vanadium 60.9J ug/L 125 05/13/24 18:50 EPA 6020B Zinc 148 ug/L 50.0 05/15/24 16:13 SM 2540C-2015 Total Dissolved Solids 7860000 ug/L 500000 05/07/24 15:11 SM 2540D-2015 Total Suspended Solids 124000 ug/L 27200 05/07/24 16:09 EPA 410.4 Chemical Oxygen Demand 5290000 ug/L 50000 05/09/24 17:08 SM 4500-H+B-2011 pH at 25 Degrees C 7.6 Std. Units 0.10 05/08/24 13:23 SM 5210B-2016 BOD, 5 day 2620000 ug/L 2000 05/13/24 13:37 EPA 8260D Acetone 12400 ug/L 5000 05/11/24 00:41 EPA 8260D 2-Butanone (MEK) 7300 ug/L 5000 05/11/24 00:41 EPA 8260D 1,4-Dichlorobenzene 23.7J ug/L 50.0 05/11/24 00:41 EPA 8260D Ethylbenzene 54.1 ug/L 50.0 05/11/24 00:41 EPA 8260D Toluene 48.1J ug/L 50.0 05/11/24 00:41 EPA 8260D Xylene (Total) 148J ug/L 250 05/11/24 00:41 EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 150 ug/L 10.0 05/08/24 15:15 EPA 350.1 Rev 2.0 1993 Nitrogen, Ammonia 1170000 ug/L 100000 05/16/24 21:29 EPA 351.2 Rev 2.0 1993 Nitrogen, Kjeldahl, Total 1380000 ug/L 50000 05/16/24 07:28 EPA 353.2 Rev 2.0 1993 Nitrogen, Nitrate 5.OJ ug/L 20.0 05/08/24 01:50 EPA 353.2 Rev 2.0 1993 Nitrogen, Nitrite 37.9 ug/L 20.0 05/08/24 01:50 EPA 365.1 Rev 2.0 1993 Phosphorus 7740 ug/L 150 05/14/24 15:38 REPORT OF LABORATORY ANALYSIS P4 D3 D3 D3 D3 D3 D3 H3 Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Leachate Pace Project No.: 92729130 Sample: 1403-Leachate Lab ID: 92729130001 Collected: 05/06/24 15:35 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 05/06/24 15:35 pH 7.37 Std. Units 1 05/06/24 15:35 Temperature 22.1 deg C 1 05/06/24 15:35 Specific Conductance 17,210 umhos/c 1 05/06/24 15:35 m Turbidity 68.20 NTU 1 05/06/24 15:35 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony 95.9 ug/L 30.0 2.7 1 05/09/2413:41 05/13/2418:50 7440-36-0 P4 Arsenic 176 ug/L 50.0 4.2 1 05/09/2413:41 05/13/2418:50 7440-38-2 Barium 558 ug/L 500 2.3 1 05/09/2413:41 05/13/2418:50 7440-39-3 Beryllium ND ug/L 5.0 0.47 1 05/09/2413:41 05/13/2418:50 7440-41-7 D3 Cadmium ND ug/L 5.0 0.51 1 05/09/2413:41 05/13/2418:50 7440-43-9 D3 Chromium 337 ug/L 50.0 9.4 1 05/09/2413:41 05/13/2418:50 7440-47-3 Cobalt 39.7J ug/L 50.0 1.6 1 05/09/2413:41 05/13/2418:50 7440-48-4 D3 Copper 20.OJ ug/L 50.0 2.1 1 05/09/2413:41 05/13/2418:50 7440-50-8 D3 Lead 2.1J ug/L 50.0 0.82 1 05/09/2413:41 05/13/2418:50 7439-92-1 D3 Nickel 175J ug/L 250 10.3 1 05/09/2413:41 05/13/2418:50 7440-02-0 D3 Selenium 8.1J ug/L 50.0 4.8 1 05/09/2413:41 05/13/2418:50 7782-49-2 D3 Silver ND ug/L 50.0 1.5 1 05/09/2413:41 05/13/2418:50 7440-22-4 D3 Thallium ND ug/L 27.5 1.9 1 05/09/2413:41 05/13/2418:50 7440-28-0 D3 Vanadium 60.9J ug/L 125 3.8 1 05/09/2413:41 05/13/2418:50 7440-62-2 D3 Zinc 148 ug/L 50.0 12.0 1 05/09/2413:41 05/15/2416:13 7440-66-6 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services - Peachtree Corners, GA Mercury ND ug/L 0.20 0.13 1 05/13/2411:20 05/13/2415:46 7439-97-6 P4 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services - Peachtree Corners, GA Total Dissolved Solids 7860000 ug/L 500000 500000 1 05/07/24 15:11 2540D Total Suspended Solids Analytical Method: SM 2540D-2015 Pace Analytical Services - Peachtree Corners, GA Total Suspended Solids 124000 ug/L 27200 27200 1 05/07/24 16:09 410.4 COD Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 Pace Analytical Services - Peachtree Corners, GA Chemical Oxygen 5290000 ug/L 50000 25000 1 05/09/2413:05 05/09/2417:08 Demand 4500H+ pH, Electrometric ATL Analytical Method: SM 4500-H+B-2011 Pace Analytical Services - Peachtree Corners, GA pH at 25 Degrees C 7.6 Std. Units 0.10 0.10 1 05/08/24 13:23 H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Leachate Pace Project No.: 92729130 Sample: 1403-Leachate Lab ID: 92729130001 Collected: 05/06/24 15:35 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 5210B BOD, 5 day BOD, 5 day 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene Date: 05/20/2024 04:48 PM Analytical Method: SM 521OB-2016 Preparation Method: SM 521OB-2016 Pace Analytical Services - Peachtree Corners, GA 2620000 ug/L 2000 2000 1 05/08/2410:17 05/13/2413:37 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 12400 ug/L 5000 256 50 05/11/24 00:41 67-64-1 ND ug/L 10000 92.5 50 05/11/24 00:41 107-13-1 ND ug/L 50.0 17.2 50 05/11/24 00:41 71-43-2 ND ug/L 150 23.4 50 05/11/24 00:41 74-97-5 ND ug/L 50.0 15.4 50 05/11/24 00:41 75-27-4 ND ug/L 150 17.0 50 05/11/24 00:41 75-25-2 ND ug/L 500 83.0 50 05/11/24 00:41 74-83-9 7300 ug/L 5000 198 50 05/11/24 00:41 78-93-3 ND ug/L 5000 17.8 50 05/11/24 00:41 75-15-0 ND ug/L 50.0 16.6 50 05/11/24 00:41 56-23-5 ND ug/L 150 14.2 50 05/11/24 00:41 108-90-7 ND ug/L 500 32.4 50 05/11/24 00:41 75-00-3 ND ug/L 250 21.5 50 05/11/24 00:41 67-66-3 ND ug/L 50.0 27.0 50 05/11/24 00:41 74-87-3 ND ug/L 650 17.0 50 05/11/24 00:41 96-12-8 IH,v1 v1 ND ug/L 150 18.0 50 05/11/24 00:41 124-48-1 ND ug/L 100 13.6 50 05/11/24 00:41 106-93-4 ND ug/L 500 19.7 50 05/11/24 00:41 74-95-3 ND ug/L 250 17.0 50 05/11/24 00:41 95-50-1 23.7J ug/L 50.0 16.6 50 05/11/24 00:41 106-46-7 ND ug/L 5000 27.8 50 05/11/24 00:41 110-57-6 v1 ND ug/L 250 18.4 50 05/11/24 00:41 75-34-3 ND ug/L 50.0 16.1 50 05/11/24 00:41 107-06-2 ND ug/L 250 17.4 50 05/11/24 00:41 75-35-4 ND ug/L 250 19.2 50 05/11/24 00:41 156-59-2 ND ug/L 250 19.8 50 05/11/24 00:41 156-60-5 ND ug/L 50.0 17.8 50 05/11/24 00:41 78-87-5 ND ug/L 50.0 18.2 50 05/11/24 00:41 10061-01-5 ND ug/L 50.0 18.2 50 05/11/24 00:41 10061-02-6 54.1 ug/L 50.0 15.2 50 05/11/24 00:41 100-41-4 ND ug/L 2500 23.8 50 05/11/24 00:41 591-78-6 ND ug/L 1000 486 50 05/11/24 00:41 74-88-4 ND ug/L 250 97.5 50 05/11/24 00:41 75-09-2 ND ug/L 5000 136 50 05/11/24 00:41 108-10-1 ND ug/L 50.0 14.6 50 05/11/24 00:41 100-42-5 ND ug/L 250 15.6 50 05/11/24 00:41 630-20-6 ND ug/L 150 11.2 50 05/11/24 00:41 79-34-5 ND ug/L 50.0 14.6 50 05/11/24 00:41 127-18-4 48.1J ug/L 50.0 12.0 50 05/11/24 00:41 108-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Leachate Pace Project No.: 92729130 Sample: 1403-Leachate Lab ID: 92729130001 Collected: 05/06/24 15:35 Received: 05/07/24 09:57 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 1,1,1-Trichloroethane ND ug/L 50.0 16.6 50 05/11/24 00:41 71-55-6 1,1,2-Trichloroethane ND ug/L 50.0 16.2 50 05/11/24 00:41 79-00-5 Trichloroethene ND ug/L 50.0 19.2 50 05/11/24 00:41 79-01-6 Trichlorofluoromethane ND ug/L 50.0 14.9 50 05/11/24 00:41 75-69-4 1,2,3-Trichloropropane ND ug/L 50.0 13.0 50 05/11/24 00:41 96-18-4 Vinyl acetate ND ug/L 2500 65.5 50 05/11/24 00:41 108-05-4 Vinyl chloride ND ug/L 50.0 19.3 50 05/11/24 00:41 75-01-4 Xylene (Total) 148J ug/L 250 16.9 50 05/11/24 00:41 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 50 05/11/24 00:41 460-00-4 CO 1,2-Dichloroethane-d4 (S) 106 % 70-130 50 05/11/24 00:41 17060-07-0 Toluene-d8 (S) 105 % 70-130 50 05/11/24 00:41 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) 150 ug/L 10.0 4.3 5 05/08/24 15:15 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 112 % 67-130 5 05/08/24 15:15 17060-07-0 CO3F1 Toluene-d8 (S) 89 % 70-130 5 05/08/24 15:15 2037-26-5 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia 1170000 ug/L 100000 31000 1000 05/16/24 21:29 7664-41-7 351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Kjeldahl, Total 1380000 ug/L 50000 25000 10 05/15/24 18:27 05/16/24 07:28 7727-37-9 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 5.OJ ug/L 20.0 3.9 1 05/08/24 01:50 14797-55-8 Nitrogen, Nitrite 37.9 ug/L 20.0 1.2 1 05/08/24 01:50 14797-65-0 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus 7740 ug/L 150 7.5 3 05/13/24 20:52 05/14/24 15:38 7723-14-0 9056 IC anions 28 Days Analytical Method: EPA 9056A Pace Analytical Services -Asheville Sulfate ND ug/L 20000 10000 20 05/09/24 22:09 14808-79-8 D3 Date: 05/20/2024 04:48 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92729130 QC Batch: 853375 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020 MET Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92729130001 METHOD BLANK: 4403689 Associated Lab Samples: 92729130001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 6.0 0.54 05/13/2417:52 Arsenic ug/L ND 10.0 0.84 05/13/2417:52 Barium ug/L ND 100 0.47 05/13/2417:52 Beryllium ug/L ND 1.0 0.094 05/13/2417:52 Cadmium ug/L ND 1.0 0.10 05/13/2417:52 Chromium ug/L ND 10.0 1.9 05/13/2417:52 Cobalt ug/L ND 10.0 0.32 05/13/2417:52 Copper ug/L ND 10.0 0.43 05/13/2417:52 Lead ug/L ND 10.0 0.16 05/13/2417:52 Nickel ug/L ND 50.0 2.1 05/13/2417:52 Selenium ug/L ND 10.0 0.96 05/13/2417:52 Silver ug/L ND 10.0 0.31 05/13/2417:52 Thallium ug/L ND 5.5 0.38 05/13/2417:52 Vanadium ug/L ND 25.0 0.75 05/13/2417:52 Zinc ug/L ND 10.0 2.4 05/13/2417:52 LABORATORY CONTROL SAMPLE: Parameter 4403690 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 100 114 114 80-120 Arsenic ug/L 100 103 103 80-120 Barium ug/L 100 106 106 80-120 Beryllium ug/L 100 109 109 80-120 Cadmium ug/L 100 103 103 80-120 Chromium ug/L 100 105 105 80-120 Cobalt ug/L 100 101 101 80-120 Copper ug/L 100 101 101 80-120 Lead ug/L 100 108 108 80-120 Nickel ug/L 100 102 102 80-120 Selenium ug/L 100 104 104 80-120 Silver ug/L 100 103 103 80-120 Thallium ug/L 100 99.6 100 80-120 Vanadium ug/L 100 107 107 80-120 Zinc ug/L 100 104 104 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Foothills LF/Leachate 92729130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4403750 4403751 MS MSD 92729503007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 106 102 106 102 75-125 4 20 Arsenic ug/L 2.7J 100 100 103 105 100 102 75-125 2 20 Barium ug/L 60.9J 100 100 179 178 118 117 75-125 1 20 Beryllium ug/L 0.24J 100 100 110 107 110 107 75-125 3 20 Cadmium ug/L ND 100 100 108 110 108 110 75-125 1 20 Chromium ug/L 9.8J 100 100 121 119 112 109 75-125 2 20 Cobalt ug/L 3.6J 100 100 108 107 104 103 75-125 1 20 Copper ug/L 9.6J 100 100 116 114 106 104 75-125 2 20 Lead ug/L 3.6J 100 100 110 108 107 104 75-125 2 20 Nickel ug/L 4.2J 100 100 108 110 104 106 75-125 2 20 Selenium ug/L ND 100 100 101 101 101 101 75-125 0 20 Silver ug/L ND 100 100 103 100 103 100 75-125 2 20 Thallium ug/L ND 100 100 103 99.6 103 100 75-125 3 20 Vanadium ug/L 16.OJ 100 100 126 126 110 110 75-125 0 20 Zinc ug/L 19.5 100 100 130 132 110 113 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92729130 QC Batch: 853706 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92729130001 METHOD BLANK: 4405413 Matrix: Water Associated Lab Samples: 92729130001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.20 0.13 05/13/2414:24 LABORATORY CONTROL SAMPLE: 4405414 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.4 95 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4405415 4405416 MS MSD 92728914001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.4 2.4 95 94 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92729130 QC Batch: 852645 Analysis Method: SM 2540C-2015 QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92729130001 METHOD BLANK: 4400016 Matrix: Water Associated Lab Samples: 92729130001 Blank Reporting Parameter Units Result Limit Total Dissolved Solids ug/L ND 25000 LABORATORY CONTROL SAMPLE: 4400017 Spike LCS Parameter Units Conc. Result Total Dissolved Solids ug/L 400000 385000 SAMPLE DUPLICATE: 4400018 92729044001 Dup Parameter Units Result Result Total Dissolved Solids ug/L 931 mg/L 901000 MDL Analyzed Qualifiers 25000 05/07/2411:56 LCS % Rec % Rec Limits Qualifiers 96 80-120 Max RPD RPD Qualifiers 3 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92729130 QC Batch: 852723 Analysis Method: SM 2540D-2015 QC Batch Method: SM 2540D-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92729130001 METHOD BLANK: 4400511 Matrix: Water Associated Lab Samples: 92729130001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Suspended Solids ug/L ND 5000 5000 05/07/24 15:58 LABORATORY CONTROL SAMPLE: 4400512 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids ug/L 100000 104000 104 90-110 SAMPLE DUPLICATE: 4400692 92729060001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids ug/L <5.0 mg/L ND 10 SAMPLE DUPLICATE: 4400693 92729065001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids ug/L ND ND 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92729130 QC Batch: 853321 Analysis Method: EPA 410.4 QC Batch Method: EPA 410.4 Analysis Description: 410.4 COD Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92729130001 METHOD BLANK: 4403397 Matrix: Water Associated Lab Samples: 92729130001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chemical Oxygen Demand ug/L ND 10000 5000 05/09/24 16:59 LABORATORY CONTROL SAMPLE: 4403398 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 200000 187000 93 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4403399 4403400 MS MSD 92729063001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 99.8 mg/L 200000 200000 283000 287000 91 94 90-110 1 10 MATRIX SPIKE SAMPLE: 4403403 92729144001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 10.5 mg/L 200000 208000 99 90-110 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92729130 QC Batch: 852983 Analysis Method: SM 4500-H+B-2011 QC Batch Method: SM 4500-H+B-2011 Analysis Description: 4500H+B pH ATL Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92729130001 SAMPLE DUPLICATE: 4401699 92729078001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 12.2 12.2 0 10 H3,PO Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92729130 QC Batch: 852777 Analysis Method: SM 521 OB-2016 QC Batch Method: SM 521OB-2016 Analysis Description: 5210E BOD, 5 day Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92729130001 METHOD BLANK: 4400910 Matrix: Water Associated Lab Samples: 92729130001 Blank Reporting Parameter Units Result Limit BOD, 5 day ug/L ND 2000 LABORATORY CONTROL SAMPLE: 4400911 Spike LCS Parameter Units Conc. Result BOD, 5 day ug/L 198000 213000 SAMPLE DUPLICATE: 4400913 92728869001 Dup Parameter Units Result Result BOD, 5 day ug/L 1300 mg/L 1570000 MDL Analyzed Qualifiers 2000 05/13/2413:13 LCS % Rec % Rec Limits Qualifiers 108 84.6-115 Max RPD RPD Qualifiers 19 25 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92729130 QC Batch: 853748 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92729130001 METHOD BLANK: 4405722 Associated Lab Samples: 92729130001 Parameter Units 1,1,1,2-Tetrachloroethane ug/L 1,1,1-Trichloroethane ug/L 1,1,2,2-Tetrachloroethane ug/L 1,1,2-Trichloroethane ug/L 1,1-Dichloroethane ug/L 1,1-Dichloroethene ug/L 1,2,3-Trichloropropane ug/L 1,2-Dibromo-3-chloropropane ug/L 1,2-Dibromoethane (EDB) ug/L 1,2-Dichlorobenzene ug/L 1,2-Dichloroethane ug/L 1,2-Dichloropropane ug/L 1,4-Dichlorobenzene ug/L 2-Butanone (MEK) ug/L 2-Hexanone ug/L 4-Methyl-2-pentanone (MIBK) ug/L Acetone ug/L Acrylonitrile ug/L Benzene ug/L Bromochloromethane ug/L Bromodichloromethane ug/L Bromoform ug/L Bromomethane ug/L Carbon disulfide ug/L Carbon tetrachloride ug/L Chlorobenzene ug/L Chloroethane ug/L Chloroform ug/L Chloromethane ug/L cis-1,2-Dichloroethene ug/L cis-1,3-Dichloropropene ug/L Dibromochloromethane ug/L Dibromomethane ug/L Ethylbenzene ug/L lodomethane ug/L Methylene Chloride ug/L Styrene ug/L Tetrachloroethene ug/L Toluene ug/L trans-1,2-Dichloroethene ug/L Matrix: Water Blank Result Reporting Limit MDL Analyzed Qualifiers ND 5.0 0.31 05/10/2419:43 ND 1.0 0.33 05/10/2419:43 ND 3.0 0.22 05/10/2419:43 ND 1.0 0.32 05/10/2419:43 ND 5.0 0.37 05/10/2419:43 ND 5.0 0.35 05/10/2419:43 ND 1.0 0.26 05/10/2419:43 ND 13.0 0.34 05/10/2419:43 ND 2.0 0.27 05/10/2419:43 ND 5.0 0.34 05/10/2419:43 ND 1.0 0.32 05/10/2419:43 ND 1.0 0.36 05/10/2419:43 ND 1.0 0.33 05/10/2419:43 ND 100 4.0 05/10/2419:43 ND 50.0 0.48 05/10/2419:43 ND 100 2.7 05/10/2419:43 ND 100 5.1 05/10/2419:43 ND 200 1.8 05/10/2419:43 ND 1.0 0.34 05/10/2419:43 ND 3.0 0.47 05/10/2419:43 ND 1.0 0.31 05/10/2419:43 ND 3.0 0.34 05/10/2419:43 ND 10.0 1.7 05/10/2419:43 IH,v1 ND 100 0.36 05/10/2419:43 ND 1.0 0.33 05/10/2419:43 ND 3.0 0.28 05/10/2419:43 ND 10.0 0.65 05/10/2419:43 v1 ND 5.0 0.43 05/10/2419:43 ND 1.0 0.54 05/10/2419:43 ND 5.0 0.38 05/10/2419:43 ND 1.0 0.36 05/10/2419:43 ND 3.0 0.36 05/10/2419:43 ND 10.0 0.39 05/10/2419:43 ND 1.0 0.30 05/10/2419:43 ND 20.0 9.7 05/10/2419:43 ND 5.0 2.0 05/10/2419:43 ND 1.0 0.29 05/10/2419:43 ND 1.0 0.29 05/10/2419:43 ND 1.0 0.24 05/10/2419:43 ND 5.0 0.40 05/10/2419:43 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92729130 METHOD BLANK: 4405722 Associated Lab Samples: 92729130001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 05/10/24 19:43 trans-1,4-Dichloro-2-butene ug/L ND 100 0.56 05/10/24 19:43 v1 Trichloroethene ug/L ND 1.0 0.38 05/10/24 19:43 Trichlorofluoromethane ug/L ND 1.0 0.30 05/10/24 19:43 Vinyl acetate ug/L ND 50.0 1.3 05/10/24 19:43 Vinyl chloride ug/L ND 1.0 0.39 05/10/24 19:43 Xylene (Total) ug/L ND 5.0 0.34 05/10/24 19:43 1,2-Dichloroethane-d4 (S) % 108 70-130 05/10/24 19:43 4-Bromofluorobenzene (S) % 99 70-130 05/10/24 19:43 Toluene-d8 (S) % 106 70-130 05/10/24 19:43 LABORATORY CONTROL SAMPLE: Parameter 4405723 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 20 19.9 99 70-130 1,1,1-Trichloroethane ug/L 20 19.2 96 70-130 1,1,2,2-Tetrachloroethane ug/L 20 20.8 104 70-130 1,1,2-Trichloroethane ug/L 20 20.6 103 70-130 1,1-Dichloroethane ug/L 20 21.2 106 70-130 1,1-Dichloroethene ug/L 20 20.7 103 69-131 1,2,3-Trichloropropane ug/L 20 21.6 108 70-130 1,2-Dibromo-3-chloropropane ug/L 20 18.0 90 70-130 1,2-Dibromoethane (EDB) ug/L 20 20.4 102 70-130 1,2-Dichlorobenzene ug/L 20 21.0 105 70-130 1,2-Dichloroethane ug/L 20 21.8 109 70-130 1,2-Dichloropropane ug/L 20 21.0 105 70-130 1,4-Dichlorobenzene ug/L 20 21.0 105 70-130 2-Butanone (MEK) ug/L 40 40.7J 102 67-133 2-Hexanone ug/L 40 42.1 J 105 70-133 4-Methyl-2-pentanone (MIBK) ug/L 40 38.7J 97 70-130 Acetone ug/L 40 42.OJ 105 67-130 Acrylonitrile ug/L 100 106J 106 70-130 Benzene ug/L 20 21.2 106 70-130 Bromochloromethane ug/L 20 21.9 110 70-130 Bromodichloromethane ug/L 20 20.2 101 70-130 Bromoform ug/L 20 19.6 98 70-133 Bromomethane ug/L 20 26.6 133 41-148lH Carbon disulfide ug/L 20 20.1J 100 70-131 Carbon tetrachloride ug/L 20 19.2 96 70-130 Chlorobenzene ug/L 20 20.7 104 70-130 Chloroethane ug/L 20 24.9 124 41-157 v1 Chloroform ug/L 20 21.7 109 70-130 Chloromethane ug/L 20 19.9 99 59-141 cis-1,2-Dichloroethene ug/L 20 21.3 107 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 32 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 aceo Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92729130 LABORATORY CONTROL SAMPLE: Parameter 4405723 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 20 21.6 108 70-130 Dibromochloromethane ug/L 20 21.3 106 70-130 Dibromomethane ug/L 20 19.8 99 70-130 Ethylbenzene ug/L 20 21.1 105 70-130 lodomethane ug/L 40 38.4 96 57-140 Methylene Chloride ug/L 20 20.0 100 62-130 Styrene ug/L 20 21.9 109 70-130 Tetrachloroethene ug/L 20 20.1 100 70-130 Toluene ug/L 20 19.9 100 70-130 trans-1,2-Dichloroethene ug/L 20 21.7 108 70-130 trans- 1,3-Dichloropropene ug/L 20 22.3 112 70-130 trans-1,4-Dichloro-2-butene ug/L 20 25.9J 130 57-149 v1 Trichloroethene ug/L 20 19.7 98 70-130 Trichlorofluoromethane ug/L 20 19.0 95 57-130 Vinyl acetate ug/L 40 45.9J 115 70-141 Vinyl chloride ug/L 20 20.5 102 66-140 Xylene (Total) ug/L 60 64.0 107 70-130 1,2-Dichloroethane-d4 (S) % 103 70-130 4-Bromofluorobenzene (S) % 105 70-130 Toluene-d8(S) % 101 70-130 MATRIX SPIKE SAMPLE: Parameter 4405724 Units 92730084001 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 19.6 98 70-146 1,1,1-Trichloroethane ug/L ND 20 20.5 102 70-150 1,1,2,2-Tetrachloroethane ug/L ND 20 17.8 89 66-144 1,1,2-Trichloroethane ug/L ND 20 19.2 96 70-142 1,1-Dichloroethane ug/L ND 20 20.8 104 68-150 1,1-Dichloroethene ug/L ND 20 21.3 106 64-162 1,2,3-Trichloropropane ug/L ND 20 17.8 89 66-144 1,2-Dibromo-3-chloropropane ug/L ND 20 17.7 89 62-146 1,2-Dibromoethane (EDB) ug/L ND 20 19.4 97 70-143 1,2-Dichlorobenzene ug/L ND 20 19.7 99 70-142 1,2-Dichloroethane ug/L ND 20 19.8 99 68-145 1,2-Dichloropropene ug/L ND 20 20.5 103 70-144 1,4-Dichlorobenzene ug/L ND 20 19.8 99 70-140 2-Butanone (MEK) ug/L ND 40 37.9J 95 57-156 2-Hexanone ug/L ND 40 35.5J 89 62-153 4-Methyl-2-pentanone (MIBK) ug/L ND 40 33.6J 84 65-144 Acetone ug/L ND 40 35.8J 89 49-162 Acrylonitrile ug/L ND 100 95.7J 96 59-155 Benzene ug/L ND 20 20.4 102 68-144 Bromochloromethane ug/L ND 20 22.3 112 70-148 Bromodichloromethane ug/L ND 20 19.0 95 70-141 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92729130 MATRIX SPIKE SAMPLE: Parameter 4405724 Units 92730084001 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers Bromoform ug/L ND 20 19.0 95 59-144 Bromomethane ug/L ND 20 29.1 145 23-1901H Carbon disulfide ug/L ND 20 22.OJ 110 64-160 Carbon tetrachloride ug/L ND 20 22.1 111 70-147 Chlorobenzene ug/L ND 20 20.2 101 70-143 Chloroethane ug/L ND 20 25.0 125 55-190 Chloroform ug/L ND 20 21.4 107 67-148 Chloromethane ug/L ND 20 21.8 109 38-180 cis-1,2-Dichloroethene ug/L ND 20 20.4 102 67-151 cis-1,3-Dichloropropene ug/L ND 20 19.7 98 70-142 Dibromochloromethane ug/L ND 20 19.0 95 68-140 Dibromomethane ug/L ND 20 20.2 101 70-142 Ethylbenzene ug/L ND 20 20.0 100 70-145 lodomethane ug/L ND 40 41.8 105 37-160 Methylene Chloride ug/L ND 20 19.2 96 54-149 Styrene ug/L ND 20 20.0 100 70-147 Tetrachloroethene ug/L ND 20 20.6 103 70-145 Toluene ug/L ND 20 19.9 100 65-146 trans-1,2-Dichloroethene ug/L ND 20 21.3 107 69-155 trans- 1,3-Dichloropropene ug/L ND 20 20.7 104 70-142 trans-1,4-Dichloro-2-butene ug/L ND 20 18.0J 90 39-149 Trichloroethene ug/L ND 20 21.6 108 70-152 Trichlorofluoromethane ug/L ND 20 24.7 124 60-158 Vinyl acetate ug/L ND 40 38.7J 97 56-157 Vinyl chloride ug/L ND 20 25.1 125 51-178 Xylene (Total) ug/L ND 60 62.0 103 70-146 1,2-Dichloroethane-d4 (S) % 100 70-130 4-Bromofluorobenzene (S) % 102 70-130 Toluene-d8(S) % 101 70-130 SAMPLE DUPLICATE: 4405725 Parameter Units 92730084002 Result Dup Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92729130 SAMPLE DUPLICATE: 4405725 Parameter Units 92730084002 Result Dup Result RPD Max RPD 1,4-Dichlorobenzene ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Acrylonitrile ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 301H Carbon disulfide ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 30 Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 cis-1,2-Dichloroethene ug/L ND ND 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 lodomethane ug/L ND ND 30 Methylene Chloride ug/L ND ND 30 Styrene ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans- 1,3-Dichloropropene ug/L ND ND 30 trans-1,4-Dichloro-2-butene ug/L ND ND 30 Trichloroethene ug/L ND ND 30 Trichlorofluoromethane ug/L ND ND 30 Vinyl acetate ug/L ND ND 30 Vinyl chloride ug/L ND ND 30 Xylene (Total) ug/L ND ND 30 1,2-Dichloroethane-d4 (S) % 116 102 4-Bromofluorobenzene (S) % 97 98 Toluene-d8 (S) % 107 103 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92729130 QC Batch: 853062 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92729130001 METHOD BLANK: 4402207 Matrix: Water Associated Lab Samples: 92729130001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 05/08/24 14:56 1,2-Dichloroethane-d4 (S) % 103 67-130 05/08/24 14:56 Toluene-d8 (S) % 93 70-130 05/08/24 14:56 LABORATORY CONTROL SAMPLE: 4402208 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 16.7 83 70-130 1,2-Dichloroethane-d4 (S) % 100 67-130 Toluene-d8 (S) % 93 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4402209 4402210 MS MSD 92729425001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 15.9 16.4 80 82 55-137 3 30 1,2-Dichloroethane-d4 (S) % 100 98 67-130 30 Toluene-d8 (S) % 95 94 70-130 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92729130 QC Batch: 854783 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92729130001 METHOD BLANK: 4410361 Associated Lab Samples: 92729130001 Parameter Units Nitrogen, Ammonia ug/L LABORATORY CONTROL SAMPLE: 4410362 Parameter Units Nitrogen, Ammonia ug/L Matrix: Water Blank Reporting Result Limit ND 100 Spike LCS Conc. Result 5000 5320 MDL Analyzed Qualifiers 31.0 05/16/24 20:18 LCS % Rec % Rec Limits Qualifiers 106 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4410363 4410364 MS MSD 92728843001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Ammonia ug/L 0.36 mg/L 5000 5000 5950 5920 112 111 90-110 1 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4410365 4410366 MS MSD 92728850001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Ammonia ug/L 7.1 mg/L 5000 5000 14500 14000 147 137 90-110 4 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92729130 QC Batch: 854748 Analysis Method: EPA 351.2 Rev 2.0 1993 QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92729130001 METHOD BLANK: 4410137 Associated Lab Samples: 92729130001 Parameter Units Nitrogen, Kjeldahl, Total ug/L LABORATORY CONTROL SAMPLE: 4410138 Parameter Units Nitrogen, Kjeldahl, Total ug/L Matrix: Water Blank Reporting Result Limit ND 500 Spike LCS Conc. Result 10000 9490 MDL Analyzed Qualifiers 250 05/16/24 05:58 LCS % Rec % Rec Limits Qualifiers 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4410139 4410140 MS MSD 92729557004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Kjeldahl, Total ug/L 32.7 mg/L 10000 10000 49000 42100 163 94 90-110 15 10 M1,R1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4410141 4410142 MS MSD 92729557008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Kjeldahl, Total ug/L 39.7 mg/L 10000 10000 44800 48100 51 84 90-110 7 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92729130 QC Batch: 852856 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92729130001 METHOD BLANK: 4401202 Matrix: Water Associated Lab Samples: 92729130001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Nitrate ug/L ND 20.0 3.9 05/08/24 01:36 Nitrogen, Nitrite ug/L ND 20.0 1.2 05/08/24 01:36 LABORATORY CONTROL SAMPLE: 4401203 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate ug/L 1500 1590 106 90-110 Nitrogen, Nitrite ug/L 1000 1040 104 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4401204 4401205 MS MSD 92729194004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate ug/L 0.14 mg/L 1500 1500 1650 1650 100 100 90-110 0 10 Nitrogen, Nitrite ug/L ND 1000 1000 1090 1090 109 109 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4401206 4401207 MS MSD 92729242001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate ug/L 48.6 mg/L 1500 1500 47600 41500 -65 -471 90-110 14 10 Nitrogen, Nitrite ug/L ND 1000 1000 1080 1080 107 107 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92729130 QC Batch: 854119 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92729130001 METHOD BLANK: 4407124 Associated Lab Samples: 92729130001 Parameter Units Phosphorus ug/L LABORATORY CONTROL SAMPLE: 4407125 Parameter Units Phosphorus ug/L Matrix: Water Blank Reporting Result Limit 4.2J 50.0 Spike LCS Conc. Result 2500 2520 MDL Analyzed Qualifiers 2.5 05/14/2415:10 LCS % Rec % Rec Limits Qualifiers 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4407131 4407132 MS MSD 92728705001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phosphorus ug/L 2.3 mg/L 2500 2500 4750 4710 98 96 90-110 1 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4407133 4407134 MS MSD 92729867001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phosphorus ug/L 1.0 mg/L 2500 2500 3500 3450 100 98 90-110 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92729130 QC Batch: 853260 Analysis Method: EPA 9056A QC Batch Method: EPA 9056A Analysis Description: 9056 IC anions 28 Days Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92729130001 METHOD BLANK: 4403137 Matrix: Water Associated Lab Samples: 92729130001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfate ug/L ND 1000 500 05/09/2418:55 LABORATORY CONTROL SAMPLE: 4403138 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate ug/L 50000 52100 104 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4403139 4403140 MS MSD 92729461006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L 11.7 mg/L 50000 50000 64300 65100 105 107 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 32 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 aceo Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Foothills LF/Leachate Pace Project No.: 92729130 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS CO Result confirmed by second analysis. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. F1 The sample was analyzed at a dilution due to foaming of the sample in the purge vessel. H3 Sample was received or analysis requested beyond the recognized method holding time. IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be considered an estimated value. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. P4 Sample field preservation does not meet EPA or method recommendations for this analysis. PO The reported result is outside the range of the pH buffer solutions used to check the calibration of the pH meter. R1 RPD value was outside control limits. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2024 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 32 ceo Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Foothills LF/Leachate Pace Project No.: 92729130 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92729130001 1403-Leachate 855406 92729130001 1403-Leachate EPA 3005A 853375 EPA 6020B 853528 92729130001 1403-Leachate EPA 7470A 853706 EPA 7470A 854074 92729130001 1403-Leachate SM 2540C-2015 852645 92729130001 1403-Leachate SM 2540D-2015 852723 92729130001 1403-Leachate EPA 410.4 853321 EPA 410.4 853495 92729130001 1403-Leachate SM 4500-H+B-2011 852983 92729130001 1403-Leachate SM 5210B-2016 852777 SM 5210B-2016 854106 92729130001 1403-Leachate EPA 8260D 853748 92729130001 1403-Leachate EPA 8260D Mod. 853062 92729130001 1403-Leachate EPA 350.1 Rev 2.0 1993 854783 92729130001 1403-Leachate EPA 351.2 Rev 2.0 1993 854748 EPA 351.2 Rev 2.0 1993 854962 92729130001 1403-Leachate EPA 353.2 Rev 2.0 1993 852856 92729130001 1403-Leachate EPA 365.1 Rev 2.0 1993 854119 EPA 365.1 Rev 2.0 1993 854412 92729130001 1403-Leachate EPA 9056A 853260 Date: 05/20/2024 04:48 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 29 of 32 y z Z _ y Z D mm ( O 0 m O u� p cry =r O 'O COO X O O cO m m m mO C Dm 0 X N m � -1D O 0 ;a D m 2 nm r r N -n * X v 9 O 0 Z WDX 0 O � m v 0 CA m m F. mr m z mm Om090mm w 2p -Dn X m m W m C= r O > 0 m C o O N� w n ' z z w ^ y j y 0- w J = m oi t O D D 0 CD n 6 Z c m w '= v a m m � Cn �- CO)N a m Z- D -� z O n m ZVq 7 m m O c m Im m ad „� i; ; X APPENDIX I - VOC BY 8260 -4 < o' m z CD 75 >C APPENDIX I- METALS w y � D � -U rco >G BOD w cn � o N X NITRATE, NITRITE cn w 0 >C COD N m rn >C PHOSPHORUS En N -0 a o g VI >C SULFATE w ti x PFAS -1633 z � V 0' .� 4— �m033cz v — W D r r 0 W (n O D O c7 O cnGG)D � z A♦ ic D�C�y� O Cn<C�D � D �0K 5. m !7! D �O�Ocnz x mD m � � ; D Z m G) � ; m��G) N n �Mc D 0 COD U m v m D D M D O X m X Z 0 r vrDO�C. 0 _0O c. Z Cn m TO Xp�0r-0 O F 1 . n Z a; ti C) . . . . Cl) Z Z 2 2 2 m m m Z� C� G O000 c E: 3 0 0 o Cn in m 0 . 1 in in n 0 Z O N �rn n 0 0 Z j 0 Irn - 0 Page DC# Title: ENV-FRM-HUN1-0083 v03_Sample Condition Upon Receipt �2Ta.t Effective Date: 12/01/2023 -aboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑ Atlanta® Kernersville❑ • Client Name: Project i O# : 2Q 92%13 _ #: w 1 �/ UP Fluent MP Due Dale: 05/16/24 Courier: ed Ex ❑UPS ❑USPS ❑ Commercial ❑Pace ❑Other: CLIENT: GARepNC Custody Seal Present? ❑Yes No Seals Intact? ❑Yes ❑No [_N/A C terlts'�,� Packing Material: ❑Bubble Wrap ❑Bubble Bags ❑None ❑ Other Thermometer/ /,0�j ��R Gun ID: V`� / _ Type of Ice: ❑Wet ❑Blue 2-1. Correction Factor: f/ Cooler Temp. ` . Add/subtract (`C) Cooler Temp Corrected (°C): USDA Regulated Soil (❑ N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? ❑Yes []No Chain of Custody Present? Samples Arrived within Hold Time? Short Hold Time Analysis (¢72 hr.)? Rush Turn Around Time Requested? Sufficient Volume? Correct Containers Used? -Pace Containers Used? Containers Intact? Dissolved analysis: Samples Field Filtered? Sample Labels Match COC? -Includes Date�me/10/Analysis Matrix: Headspace in VOA Vials (a5-6mm)? Trip Blank Present? Trip Blank Custody Seals Present? COMMENTS/SAMPLE DISCREPANCY �i�f � 1 ��1r , LIENT NOTIFICATION/RESOLUTION Person contacted. Project Manager SCURF Review: Project Manager SRF Review: )ualtrax ID: 69614 Date/Inidals Person Examining on Biological Tissue Fra ? ❑Yes ❑N❑ /A ❑None Temp should be above freezing to 6'C ❑Samples out of temp criteria. samples on ice, cooling process has begun Did samples originate from a foreign source (internationally, including. Hawaii and Puerto Rico)? ❑Yes []No MY —es ❑No ❑N/A 1. es ❑No ❑N/A 2. es ❑No ❑N/A 3. []Yes No ❑N/A 4. Yes ON. ❑N/A 5• [J'Y'ej ❑No ❑N/A 6. ❑No ❑N/A es ❑No ❑N/A 7. Oyes LINO IA 8. 9. 'T 50)1 C /+ o t4t�f i4 10�/ C 9 Yes ❑No ❑N/A VI/ ❑Yes r ❑No ❑N/A 10. — Oyes o ❑N/A 1 11. No 0,fT71A Field Data Required? ❑Yes ❑No > ` k-I Lot ID of split containers: Date/Time: Date: Date: Page 1 of 2 Page 31 of 32 DC#_Title: ENV-FRM-HUN1-0083 v03_Sample Condition Upon Receipt ee MIA, LY7':a: ucnes Effective Date: 12/01/2023 *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottles ***Check all unpreserved Nitrates for chlorine Project # 0#• 9z PM: MP GARdPNC l CLIENT a Z v a Z v Z v z a u N v N v o Z o8 w A v n O M a Z `--' ` N z L N N v 2 N v - Q U : _ Q Z Q Z -v a1 _ Q a Z -- y > a Z a! H fa co Q Z a m Q Z O1 n1 O z > v z z > > N G/ Q V 41 d V U/ i1 O u N C °—' d O 1-42 V Q O U N u Q N U Q = O Z U m V w t as C O a V n _v U S a H a C d v O' N 2 O N S N Z U V = Z ¢ Z U = p N V1 R Z ` ar N 2 r O tr1 S Q C U (J d Y H d N `m Y a C1 = Z �, m N C ? E C O = Q O1 _ d J E N _ d J E V1 M R J E O �' �o d �, _ d J E N a J E 0 NN _ d J E d J E " o E E Q °: E Q • E Q J E o -0 E Q m a1 E a J E N a E Q J E Q O > J E Q O > J E QVVlfl Q O > J E Q O > J E m a- J E o o_ H - �n J E - v vl J E a J E o to N Q .E E o O u J E N E Q J E 1 V =� d _ .1 a m N O a m V 6 a m n. m ; a m Z a- m c N a m h a m e=i 3 .4 O a i .-4 O a M en O a VI c4 (7 a VI rn Q a v M 0 o = M O o F-- M l7 > > 01 C7 > > 61 O o > a Y `e -- > F' a H J1 a IA a m p (9 a = ut > Ol F7 o 2 , 3 4 5 `� \NS 6 7 8 9 10 11 12 pH Adjustment Log for Preserved Samples Sample ID Type ofpPrresservative pH u— pon receipt Date preservation adjusted Time preservation 1,,[I1 Amount of Preservative 4� 1 .04% Lot # Vote: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DENR Certification Office (i.e. Dut of hold, incorrect preservative, out of temp, incorrect containers. Page 32 of 32 ualtrax ID: 69614 Paae 2 of 2 FOOTHILLS LANDFILL MAY 612024 SAMPLE ID # DEPTH TO WATER (FT.) * RISER ELEV. (FT.) * WATER ELEV. (FT.) * MW-1 R2 24.18 1516.22 1492.04 MW-2R 51.69 1253.36 1201.67 MW-3 53.74 1241.95 1188.21 MW-3R 58.81 1242.69 1183.88 MW-3R2 40.20 1240.83 1200.63 MW-4 41.19 1171.18 1129.99 MW-5 47.39 1175.07 1127.68 MW-6 42.89 1176.82 1133.93 MW-7 29.23 1183.13 1153.90 MW-8 27.70 1195.18 1167.48 MW-9 70.70 1290.79 1220.09 MW-10 79.35 1358.53 1279.18 MW-11 83.38 1401.71 1318.33 MW-12 98.56 1459.23 1360.67 * FROM THE TOP OF RISER SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIVE: E S & S - B.CHIODO SAMPLE MATRIX: DEIONIZED WATER LAB SAMPLE / PROJECT #: NA INITIAL WATEREVEL (FT) ELEV., MEAS. PT. (MSL): DATE METHOD OF EVACUATION: ( } PVC BAILER ( ) S.S. BAILER ( ) S.S. BAILER ( ) QED PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA ( ) GRUNDFO: ( ) OTHER ( ) 3 ( ) 4 DEPTH TO BOTTOM (FT) ELEVATION, G/W (MSL): TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: UMP ( ) YES ( ) NO ( ) 6 ( THER WAS WELL PURGE�TY WATER LEVEL END PURGE FINISH ESS ( )YES( ) NO TIME PURGE RATE ( DTW (FT) CUMULATIVE VOLUME TEMP. C pH Std.Units) CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV SAMPLING INFORMATION DATE / TIME . 5- / 1.51.32 METHOD OF SAMPLING: ( ) PVC BAILER ( ) S.S. BAILER ( ) S.S. BAILER ( ) QED PUMP SAMPLING FIELD MEASUREMENT DATA DEPTH TO GROUNDWATER (FT) NA SAMPLING EQUIPMENT DEDICATED: ( ) GRUNDFOS PUMP ( ) YES ( ) OTHER ( ) NO TIME pH Std.Units TEMP. C CONDUCT. umhos/cm TURBIDITY (NTU) OTHER eh (mV) ]PPM DISS.OXY. OTHER NA NA NA NA NA NA NA NA GENERAL INFORMATION vie WEATHER CONDITIONS AT TIME OF SAMPLING: w lv! SAMPLE CHARACTERISTICS: - COMMENTS: APPENDIX I LIST + PFAS SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF POINT ID: TRIP BLANK LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIVE: SAMPLE MATRIX: DEIONIZED WATER LAB SAMPLE / PROJECT #: INITIAL VVATgR LEVEL (FT) ELEV., MEAS. PT. (M METHOD OF EVACUATION: ( ) PVC BAILER ( ) S.S. BAILER ( ) S.S. BAILER ( ) QED PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS: START E1h4CUAI QN STABILIZATION DATA DEPTH TO BOTTOM (FT) ELEVATION, G/W (MSL): E S & S - B.CHIODO TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( ) GRUN S PUMP ( ) YES ( ) NO ( ) OTHER ( ) 3 ( ) 4 ( ) 6 OTHER WAS WELL PURGED DRYNESS( )YES( ) NO WATER LEVEL END PURGE FINISH TIME PURGEPATa m/htz DTW F CUMULATIVE OLUME TEMP. C) pH Std.Units CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV SAMPLING INFORMATION DATE/TIME / 1 METHOD OF SAMPLING: DEPTH TO GROUNDWATER (FT) NA SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP ( ) YES ( ) S.S. BAILER ( ) QED PUMP ( ) OTHER ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME pH (Std.Units) TEMP. (C CONDUCT. (umhos/cm) TURBIDITY (NTU OTHER eh (mV) DISS.OXY. (PPM OTHER NA NA NA NA NA NA NA NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: a SAMPLE CHARACTERISTICS: COMMENTS: VOA ONLY A Pe = 11 A Pr 1 o,t 1 SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF POINT ID: Sw - 1 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER Rk INITIAL WATER`1=E L (FEET) NA ELEVATION, MEAS.PT.(MSL): NA DATE METHOD OF EVACUATION: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT M NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH 1 EVACUATION EQUIPMENT DEDICATED: ( ) CONTINUO ( ) YES ( ) NO PUMPING WELL ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DR WATER LEVEL AFTER PURGE (FT.) FINISH ( ) YES ( ) NO TIME PURGE RAT m/htz LATIVE VOLUME TEMP. pH Std.Units) SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME s o / WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.0nits) SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh (mV) DISS.OXY. (PPM OTHER S;a p 16). Lf 44. 9O + 3,7.57NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: o� SAMPLE CHARACTERISTICS: - - �- COMMENTS: APPENDIX I LIST + PFAS SAMPLE COLLECTION NUMBER 15 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: UNDERDRAIN WATER EVAGUATION INFORMATION INITIAL WA' VEL (FEET) NA ELEVATION, MEAS.PT.(MSL): NA DATE METHOD OF EVACUATION: FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH / ( ) PVC BAILER ( ) WELL WIZARD ( ) CONTINUOUS ( ) S.S. BAILER ( ) GRUNDFOS PUMP PUMPING WELL EVACUATION EQUIPMENT DEDICATED: ( ) YES ( ) NO WELL RISER DIAMETER (IN.): ( ) 2 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA WAS WELL PURGED TO DRYN ( ) YES ( ) NO WATER LEVEL AFTER PURGE (FT.) FINISH TIME PURGE RATE m/htz C LNTT� VOLUME TEMP. C pH nits SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME f g4 / 15*59 METHOD OF SAMPLING: WATER LEVEL PRIOR TO SAMLING (FT.) NA SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( } NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.0nits) SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh (mV) DISS.OXY. (PPM OTHER 1 �"ob . 0 4 7 C1, NA GENERAL INFORMATION 7.5. a r WEATHER CONDITIONS AT TIME OF SAMPLING: trt asi SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST + PFAS SAMPLE COLLECTION NUMBER 11 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: EVACUATION INFO UNDERDRAIN WATER INITIAL WATER4..EVEW L�(F�EET) NA ELEVATION, MEAS.PT.(MSL): NA DATE METHOD OF EVACUATION: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA POINT ID: UD - 1 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( ) CONTINUOUS ( ) YES ( ) NO PUMPING WELL ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNES WATER LEVEL AFTER PURGE (FT.) FINISH YES ( ) NO TIME PURGE RATE m/htz CU VOLUME TEMP. C pH t SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME . .. 2 / I V 17 WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.Units SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh (mV) DISS.OXY. (PPM OTHER 16:1 M J ft. NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: &4 SAMPLE CHARACTERISTICS: (' COMMENTS: APPENDIX I LIST + PFAS SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF LOCATION: LENO|R N(]RTHCAROL|NA SAMPLE MATRIX: EVQQJATUON lNP SURFACE WATER 'INITIAL WA71ER�L �VEL (FEET) NA ELEVATION, MEAS.PT.(MSL): NA DATE METHOD OF EVACUATION: ( ) PVC BAILER ( ) WELL WIZARD ( S.S. BAILER ( >GRUNDFOGPUMP WELL RISER DIAMETER (IN.): ( )2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURG|NG8: START EVACUATION STABILIZATION DATA POINT ID: SW-2 FIELD REPRESENTATIVE; ES&S-B.CH|ODO LAB SAMPLE/PROJECT#: NA DEPTH TO BOTTOM (FE ELE\A\T|[JN.G/VV (K8SL): NA EVACUATION EQUIPMENT DEDICATED: CONTINUOUS YES NO PUMPING WELL ( )4 ( )G ( )OTHER_____ -~~� WAS WELL PURGED TO DRYNES YES ( )NO WATER LEVEL AFTER PURGE (FT.) FINISH PURGE R -GUMU� �TIVE TEMP. pH SPEC. CONDUCT. TURBIDITY OTHER NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME H- VV/QlER LEVEL PR|ORTOSAMUNG (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( > VVATERRAPUKUP (X) YES S.S. BAILER GRUNDFOS PUMP (X) DIP BOTTLE NO SAMPLING FIELD MEASUREMENT DATA pH SPEC. CONDUCT. TEMP. TURBIDITY REDOX DISS. OXY. OTHER GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: L4 s-4 COMMENTS: APPENDIX | LIST +PFAG �� SAMPLE COLLECTION NUMBER �o SITE NAME: FOOTHILLS LF POINT ID: sw - 5 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER INITIAL WA` EVEL (FEET) NA ELEVATION, MEAS.PT.(MS NA DATE lkytl_c00M[*I_Dxojm m0911�yI& in, ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( ) CONTINUO ( ) YES ( ) NO PUMPING WELL ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNE WATER LEVEL AFTER PURGE (FT.) FINISH ) YES ( ) NO TIME PURGE RA m/htz UMULAT_ IVE VOLUME TEMP. C pH td.Units SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME / H 4 METHOD OF SAMPLING: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP SAMPLING FIELD MEASUREMENT DATA WATER LEVEL PRIOR TO SAMLING (FT.) NA SAMPLING EQUIPMENT DEDICATED: ( ) WATERRA PUMP (X) YES (X) DIP BOTTLE ( ) NO TIME pH Std.Units SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh mV DISS.OXY. PPM OTHER 1 ;t' d C0. a O 450.(. , / NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: t� SAMPLE CHARACTERISTICS: ., , COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER INITIAL WATER -LEVEL FEET) NA ELEVATION, MEAS.PT.(MSL): NA DATE METHOD OF EVACUATION: POINT ID: SW-4 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH / ( ) PVC BAILER ( ) WELL WIZARD ( ) CONTINUOUS ( ) S.S. BAILER ( ) GRUNDFOS PUMP PUMPING WELL WELL RISER DIAMETER (IN.): ( ) 2 ( ) 4 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA EVACUATION EQUIPMENT DEDICATED: ( ) YES ( ) NO ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNES WATER LEVEL AFTER PURGE (FT.) FINISH YES ( ) NO TIME PURGE RATE m/htz CUMU AT VOLUME TEMP. C pH td-Units SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME 5,5,aLi / l?:18 WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.Units SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh mV DISS.OXY. PPM OTHER GENERAL INFORMATION ar WEATHER CONDITIONS AT TIME OF SAMPLING: r�# SAMPLE CHARACTERISTICS: I L41Z 0t COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER EVA=ATION INFORMATION INITIAL WA EVE��L--��(..F��EET) NA ELEVATION, MEAS.PT.(MSL� NA DATE METHOD OF EVACUATION: POINT ID: SW - 3 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( )PVC BAILER ( WELL WIZARD ( )CONTINUOUS ) YES ( ) NO ( ) S.S. BAILER ( ) GRUNDFOS PUMP PUMPING WELL WELL RISER DIAMETER (IN.): ( ) 2 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) WAS WELL PURGED TO DRYNESS ( S ( )NCO TOTAL VOLUME EVACUATED (GAL) WATER LEVEL AFTER PURGE (FT.) TURBIDITY OF PURGINGS : START FINISH EVACUATION STABILIZATION DATA TIME PURGE RATEMCVMUL&TIVE m/htz VOLUME TEMP. pH Std.Units SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME - r 4 / 1 , VO WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( } NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.Units SPEC. CONDUCT. umhos/cm TEMP. C 1 TURBIDITY NTU REDOX eh (mV) DISS.OXY. (PPM OTHER 1'7,' ).O ) 's- 60. 30 NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: �+t SAMPLE CHARACTERISTICS: C — l COMMENTS: APPENDIX I LIST s / W SAMPLE COLLECTION NUMBER 9 * 1 SITE NAME FOOTHILLS LF POINT ID: MW - 12 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT):_ ELEV., MEAS. PT. (MSL): DATE -(® %I FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: 1 DEPTH TO BOTTOM (FT): IN ELEVATION, G/W (MSL): _ 7 TIME: START/FINISH I / �- METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) . Off' WATER LEVEL END PURGE (FT) TURBIDITY OF PURGINGS: START FINISH CLSQ- EVACUATION STABILIZATION DATA PU - • �� - • • • -: MEMO • r pis f. * � ,�. /j SAMPLING INFORMATION DATE / TIME ® G - JZ %-f / DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING SAMPLE CHARACTERISTICS: C SAMPLING EQUIPMENT DEDICATED: (X) YES ( ) NO CL0lsooF- COMMENTS: APPENDIX I LIST + PFAS SAMPLE COLLECTION NUMBER I 1 SITE NAME FOOTHILLS LF POINT ID: MW -11 LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIVE: E S & S - B.CHIODO SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSL): 1 LiI a DATE " '' 14 LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FT): a Yo ELEVATION, G/W (MSL): TIME: START/FINISH ; to / METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) 11.0o WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) 0,00 WATER LEVEL END PURGE (FT) TURBIDITY OF PURGINGS: START FINISH C EVACUATION STABILIZATION DATA P -RAT URGE RATGOMMI pH � � I .-' SAMPLING INFORMATION r DATE / TIME - 24 / DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION 09, WEATHER CONDITIONS AT TIME OF SAMPLING: WA 0 SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST + PFAS SAMPLE COLLECTION NUMBER t SITE NAME FOOTHILLS LF POINT ID: MW - 7 R LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT): ELEV., MEAS. PT. (MSL): 1 ELEVATION, G/W (MSL): DATE - 6 TIME: START/FINISH METHOD OF EVACUATION: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER NA 0 L{ / 730 EVACUATION EQUIPMENT DEDICATED: (X) YES ( ) NO WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) - WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) . 00 WATER LEVEL END PURGE (FT) 2q, 30 TURBIDITY OF PURGINGS: START C U14L FINISH C EVACUATION STABILIZATION DATA ME PURGE RATIM1115470M • pH • • TllRBIDITT w Will le i ® ' . ■ I!" III SAMPLING INFORMATION DATE/TIME .- b ® / 71f, DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER SAMPLING EQUIPMENT DEDICATED: (X) YES ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: L-0 t>t D SAMPLE CHARACTERISTICS: C' COMMENTS: APPENDIX I LIST + PFAS SAMPLE COLLECTION NUMBER 13 SITE NAME FOOTHILLS LF .� 1-11 f, LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIVE: E S & S - B.CHIODO SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT): iull ELEV., MEAS. PT. (MSL): I ELEVATION, G/W (MSL): 1219-18 DATE ' ( � aLf TIME: START/FINISH T53/ METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) , 00 WATER LEVEL END PURGE (FT) TURBIDITY OF PURGINGS: START FINISH EVACUATION STABILIZATION DATA PURGE RAT all pH rereliffiblZill p � �� �� A III J1 III _IIIII r� SAMPLING INFORMATION DATE /TIME '^ 6 - 14 / ' :2 5 DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: C COMMENTS: APPENDIX I LIST + PFAS SAMPLE COLLECTION NUMBER Pi SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINPOINT ID: ml W. 9 — FIELD REPRESENTATIVE: E S & S - B.CHInn ............. ........ . . . SAMPLE MATRIX: GROUNDWATER LAB SAMPLE / PROJECT #: EVACUATION IMPgo itnA-ro-h- NA INITIAL WATER LEVEL (FT): DEPTH TO BOTTOM (FT): 73, If 0 ELEV., MEAS. PT. (MSL): IIB, DATE ELEVATION, G/W (MS Q: ®1 ,METHOD OF EVACUATION: TIME: START/FINISH VL"4 PVC BAILER ( ) S.S. BAILER GRUNDFOS PUMP EVACUATION EQUIPMENT DEDICATED: S.S. BAILER (X)QED WWPUMP( (X) YES OTHER NO 'YELL RISER DIAMETER (IN.): (X) 2 3 ) 4 )NE (1) RISER VOLUME (GAL) 6,43 6 OTHER OTAL VOL. EVACUATED (GAL) -2,00 WAS WELL PURGED TO DRYNESS( )YES(X)NO URBIDITY OF PURGINGS: START CifQ_ WATER LEVEL END PURGE (FT) 76. t3 VAC JATION STABILIZATION DATAFINISH TIME PURGE RATE DTW FT CUMUL. TEMP. VOL GAL) pH CONDUCT. TURBIDITY REDOX D.O. 250 70.1710 0 C I-Z -7 (Std.Units umhos/6m) `7 Lt. (NTU eh mV MG/L) 250 '70,1k, 1 —5, ;2�09 4-00.8 730 0.25 1-7,7 '70 -5-120 1 1 tz. /,Is- 250 - 79 0.50 17 5717 250 710. 0.75 I'Zs- 47. 1 bla 250 740, 1.00 1-7, 8'0lk7,Z 250 a.71 1.25 rAg' I k7' S- /6 250 70fk 1 1.5 0 :oi 1 250 7olrz 1.75 + 250 7093 2.00 2w 2---go IPLING INFORMATION E/TIME 9-6-ZV 13 'HOD DEPTH TO GROUNDWATER (FT) 70. OF SAMPLING: PVC BAILER S.S. BAILER GRUNDFOS SAMPLING EQUIPMENT PUMP DEDICATED- S.S. BAILER (X)QED WWPUMp OTHER (X) YES NO ERAL INFORMATION — — �—�j TH ER CONDITIONS T IME OF SAMPLING: C4 bw r10 'LE CHARACTERISTICS: V.At I MENTS: APPENDIX I LIST + PFAS SAMPLE COLLECTION NUMBER 157 POINT ID: MW - 8 SITE NAME FOOTHILLS LF FIELD REPRESENTATIVE: E S & S — B.CHIODO LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT): ELEV., MEAS. PT. (MSL): ,10 ELEVATION, G/W (MSL): 1 1 DATE TIME: START/FINISH / f 0 g METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) 9 WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) R. 00 WATER LEVEL END PURGE (FT) TURBIDITY OF PURGINGS: START CFINISH EVACUATION STABILIZATION DATA 22 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): PURGE RATjM pH 0 0 �► � �® III + ,,..,� IIII � .; �",� ,e.- .,,, �; m _- SAMPLING INFORMATION DATE / TIME �-� - Z / 8 DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: . COMMENTS: APPENDIX I LIST + PFAS SAMPLE COLLECTION NUMBER SITE NAME FOOTHILLS LF POINT ID: MW - 7 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT):_ ELEV., MEAS. PT. (MSL): DATE - 6 - 2 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT): 0 ELEVATION, G/W (MSL): TIME: START/FINISH / ()0 / /0,572 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) �. `% WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) WATER LEVEL END PURGE (FT) 9. 3r TURBIDITY OF PURGINGS: START L r-WZ FINISH c - EVACUATION STABILIZATION DATA SAMPLING INFORMATION DATE/TIME DEPTH TO GROUNDWATER (FT) 2 5,3-5' METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION OF WEATHER CONDITIONS AT TIME OF SAMPLING: CL. 0 SAMPLE CHARACTERISTICS: C US A2- COMMENTS: APPENDIX I LIST + PFAS SAMPLE COLLECTION NUMBER SITE NAME FOOTHILLS LF POINT ID: MW - 6 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSL): DATE 9-6 - Z FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FT): so.ss ELEVATION, G/W (MSL): TIME: START/FINISH 1 1: O / V Y/ METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ONE (1) RISER VOLUME (GAL) I• TOTAL VOL. EVACUATED (GAL) 00 ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS ( ) YES (X) NO WATER LEVEL END PURGE (FT) . o l TURBIDITY OF PURGINGS: START C FINISH EVACUATION STABILIZATION DATA PURGE RATE 19MMI •� pH ml mom NAMES SAMPLING INFORMATION DATE / TIME DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: �..C.� SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST + PFAS SAMPLE COLLECTION NUMBER 18 SITE NAME FOOTHILLS LF POINT ID: mw - 5 LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIVE: E S & S - B.CHIODO SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSL): I I DATE - LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT) NA ELEVATION, G/W (MSL). t TIME: START/FINISH / 1 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) .Ott WATER LEVEL END PURGE (FT)q7 5-0 TURBIDITY OF PURGINGS: START CLgAR, FINISH C LEAF - EVACUATION STABILIZATION DATA PURGE RAT (ML MIN) im • - •• (St • -: - O• • SAMPLING INFORMATION DATE / TIME - _ Z/ DEPTH TO GROUNDWATER (FT) D METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: el C- 0tA b SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST + PFAS SAMPLE COLLECTION NUMBER 19 SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT):_ FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT): Em ELEV., MEAS. PT. (MSL): r7 1. 19 ELEVATION, G/W (MSL): l DATE a - TIME: START/FINISH Q ,,/ METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) I e WAS WELL PURGED TO DRYNESS( )YES(X)NO TOTAL VOL. EVACUATED (GAL) Q, o o WATER LEVEL END PURGE (FT) 411.30 TURBIDITY OF PURGINGS: START CFINISH C LS4 Az EVACUATION STABILIZATION DATA PURGE RATE pH ff IM, ITS In :a ■� „®k' 3 MWE SAMPLING INFORMATION DATE / TIME - / ' f °�" DEPTH TO GROUNDWATER (FT) Zil. 70 METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION 0-0 WEATHER CONDITIONS AT TIME OF SAMPLING: L O IA bil, o SAMPLE CHARACTERISTICS: C COMMENTS: APPENDIX I LIST + PFAS b q i? -7-A KF--j� •`! SAMPLE COLLECTION NUMBER 12�'�' t SITE NAME FOOTHILLS LF POINT ID: MW - 3112 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: ELEV., MEAS. PT. (MSQ: DATE - 6 - METHOD OF EVACUATION: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN_): (X) 2 ( ) 3 ( ) 4 NA DEPTH TO BOTTOM (FT): "731 ELEVATION, G/W (MSL): t ®' VIE: START/FINISH t `. 39 / .% EVACUATION EQUIPMENT DEDICATED: (X) YES ( ) NO ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) WATER LEVEL END PURGE (FT) TURBIDITY OF PURGINGS: START FINISH EVACUATION STABILIZATION DATA PURGE RATE (ML MW)__ Mm��M—(Std. pH Units) • 1. 1 !u. !! " . m SAMPLING INFORMATION DATE/TIME - � - 2 / DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION F WEATHER CONDITIONS AT TIME OF SAMPLING: o SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST + PFAS SAMPLE COLLECTION NUMBER SITE NAME FOOTHILLS LF POINT ID: MW - 2R LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ) a FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT) ELEV., MEAS. PT. (MSL}: ELEVATION, G/W (MSL): l DATE TIME: START/FINISH o METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( } S.S. BAILER (X) QED WW PUMP ( ) OTHER NA WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) 1.411 WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) o WATER LEVEL END PURGE (FT) 1, TURBIDITY OF PURGINGS: START FINISH EVACUATION STABILIZATION DATA • SAMPLING INFORMATION DATE / TIME - / I DEPTH TO GROUNDWATER (FT) 1> METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: 7o SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX II LIST + PFAS SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: LEACHATE EVAQUATION INFORMATION INITIAL WA-I-ER-LEva (FEET) NA ELEVATION, MEAS.PT.(MSL):-----" NA DATE METHOD OF EVACUATION: PVC BAILER WELL WIZARD S.S. BAILER GRUNDFOS PUMP WELL RISER DIAMETER (IN.): 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA POINT ID: LEACHATE FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE/ PROJECT NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH EVAC UATION EQUIPMENT DEDICATED: CONTINUOUS YES NO PUMPING WELL ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO:"DRYNE ) �YES ( )NO WATER LEVEL AFTER PURGE (FT.) FINISH TIME PURGE RATE (gpm/htz) C0MDtATAlF- VOLUME TEMP. C pH td.Units) SPEC. CONDUCT. (umhos/cm) TURBIDITY (NTU) OTHER eh MY) L NA 0 NA NA NA SAMPLING INFORMATION yy DATE/ TIME 5 ZLf / 1'395. METHOD OF SAMPLING: PVC BAILER WELL WIZARD S.S. BAILER GRUNDFOS PUMP SAMPLING FIELD MEASUREMENT DATA WATER LEVEL PRIOR TO SAMLING (FT.) WATERRA PUMP (X) SAMPLE PORT OA SAMPLING EQUIPMENT DEDICATED: (X) YES ( ) NO TIME pH (Std. U nits) SPEC. CONDUCT. (umhos/cm) TEMP. (C) 1 TURBIDITY (NTU) REDOX eh (mV) DISS. OXY. (PPM) OTHER 15'37 r-1 3 7 '/. I r7alo ;a 1 6g.;Xo '32.3 NA NA GENERAL INFORMATION op WEATHER CONDITIONS AT TIME OF SAMPLING: cl- Lo 76 SAMPLE CHARACTERISTICS: I COMMENTS: SAMPLE COLLECTION NUMBER C2 41